Zn4C27H9O13(CH)9 crystallizes in the monoclinic P2_1 space group. The structure consists of thirty-six 02329_fluka molecules inside a Zn4C27H9O13 framework. In the Zn4C27H9O13 framework, there are eight inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(15), one O(2), and one O(4) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.91 Å. The Zn(1)-O(15) bond length is 1.98 Å. The Zn(1)-O(2) bond length is 1.95 Å. The Zn(1)-O(4) bond length is 1.96 Å. In the second Zn site, Zn(2) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(3), and one O(6) atom. The Zn(2)-O(1) bond length is 2.03 Å. The Zn(2)-O(10) bond length is 2.07 Å. The Zn(2)-O(3) bond length is 2.09 Å. The Zn(2)-O(6) bond length is 2.16 Å. In the third Zn site, Zn(3) is bonded to one O(1), one O(19), one O(5), and one O(7) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(1) bond length is 1.93 Å. The Zn(3)-O(19) bond length is 1.98 Å. The Zn(3)-O(5) bond length is 1.98 Å. The Zn(3)-O(7) bond length is 1.95 Å. In the fourth Zn site, Zn(4) is bonded to one O(1), one O(11), one O(14), and one O(18) atom to form corner-sharing ZnO4 tetrahedra. The Zn(4)-O(1) bond length is 1.92 Å. The Zn(4)-O(11) bond length is 1.95 Å. The Zn(4)-O(14) bond length is 1.98 Å. The Zn(4)-O(18) bond length is 1.94 Å. In the fifth Zn site, Zn(5) is bonded in a rectangular see-saw-like geometry to one O(20), one O(22), one O(24), and one O(25) atom. The Zn(5)-O(20) bond length is 2.07 Å. The Zn(5)-O(22) bond length is 2.02 Å. The Zn(5)-O(24) bond length is 2.22 Å. The Zn(5)-O(25) bond length is 2.10 Å. In the sixth Zn site, Zn(6) is bonded to one O(17), one O(21), one O(22), and one O(8) atom to form corner-sharing ZnO4 tetrahedra. The Zn(6)-O(17) bond length is 1.97 Å. The Zn(6)-O(21) bond length is 1.98 Å. The Zn(6)-O(22) bond length is 1.92 Å. The Zn(6)-O(8) bond length is 1.95 Å. In the seventh Zn site, Zn(7) is bonded to one O(13), one O(22), one O(26), and one O(9) atom to form corner-sharing ZnO4 tetrahedra. The Zn(7)-O(13) bond length is 1.95 Å. The Zn(7)-O(22) bond length is 1.93 Å. The Zn(7)-O(26) bond length is 1.94 Å. The Zn(7)-O(9) bond length is 2.01 Å. In the eighth Zn site, Zn(8) is bonded to one O(12), one O(16), one O(22), and one O(23) atom to form corner-sharing ZnO4 tetrahedra. The Zn(8)-O(12) bond length is 1.97 Å. The Zn(8)-O(16) bond length is 1.95 Å. The Zn(8)-O(22) bond length is 1.92 Å. The Zn(8)-O(23) bond length is 1.92 Å. There are fifty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(3) atom. The C(1)-C(2) bond length is 1.45 Å. The C(1)-O(2) bond length is 1.29 Å. The C(1)-O(3) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(6) bond length is 1.43 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.42 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(12) bond length is 1.48 Å. The C(4)-C(5) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.48 Å. The C(5)-C(7) bond length is 1.41 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(2), and one C(5) atom. The C(6)-C(11) bond length is 1.38 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(7)-H(2) bond length is 0.93 Å. In the eighth C site, C(11) is bonded in a single-bond geometry to one C(6) and one H(6) atom. The C(11)-H(6) bond length is 0.93 Å. In the ninth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(4), and one O(5) atom. The C(12)-O(4) bond length is 1.27 Å. The C(12)-O(5) bond length is 1.25 Å. In the tenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(6), and one O(7) atom. The C(13)-C(14) bond length is 1.49 Å. The C(13)-O(6) bond length is 1.23 Å. The C(13)-O(7) bond length is 1.31 Å. In the eleventh C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(18) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-C(18) bond length is 1.39 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(7) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(7) bond length is 0.93 Å. In the thirteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(24) atom. The C(16)-C(17) bond length is 1.43 Å. The C(16)-C(24) bond length is 1.45 Å. In the fourteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(19) atom. The C(17)-C(18) bond length is 1.50 Å. The C(17)-C(19) bond length is 1.38 Å. In the fifteenth C site, C(18) is bonded in a trigonal planar geometry to one C(14), one C(17), and one C(23) atom. The C(18)-C(23) bond length is 1.42 Å. In the sixteenth C site, C(19) is bonded in a single-bond geometry to one C(17) and one H(8) atom. The C(19)-H(8) bond length is 0.93 Å. In the seventeenth C site, C(23) is bonded in a single-bond geometry to one C(18) and one H(12) atom. The C(23)-H(12) bond length is 0.93 Å. In the eighteenth C site, C(24) is bonded in a bent 120 degrees geometry to one C(16), one O(8), and one O(9) atom. The C(24)-O(8) bond length is 1.30 Å. The C(24)-O(9) bond length is 1.24 Å. In the nineteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(10), and one O(11) atom. The C(25)-C(26) bond length is 1.49 Å. The C(25)-O(10) bond length is 1.25 Å. The C(25)-O(11) bond length is 1.29 Å. In the twentieth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(30) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-C(30) bond length is 1.40 Å. In the twenty-first C site, C(27) is bonded in a distorted single-bond geometry to one C(26), one C(28), and one H(13) atom. The C(27)-C(28) bond length is 1.39 Å. The C(27)-H(13) bond length is 0.93 Å. In the twenty-second C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(36) atom. The C(28)-C(29) bond length is 1.41 Å. The C(28)-C(36) bond length is 1.47 Å. In the twenty-third C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(31) atom. The C(29)-C(30) bond length is 1.47 Å. The C(29)-C(31) bond length is 1.39 Å. In the twenty-fourth C site, C(30) is bonded in a trigonal planar geometry to one C(26), one C(29), and one C(35) atom. The C(30)-C(35) bond length is 1.37 Å. In the twenty-fifth C site, C(31) is bonded in a distorted single-bond geometry to one C(29) and one H(14) atom. The C(31)-H(14) bond length is 0.93 Å. In the twenty-sixth C site, C(35) is bonded in a single-bond geometry to one C(30) and one H(18) atom. The C(35)-H(18) bond length is 0.93 Å. In the twenty-seventh C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(12), and one O(13) atom. The C(36)-O(12) bond length is 1.27 Å. The C(36)-O(13) bond length is 1.27 Å. In the twenty-eighth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(38), one O(14), and one O(15) atom. The C(37)-C(38) bond length is 1.49 Å. The C(37)-O(14) bond length is 1.27 Å. The C(37)-O(15) bond length is 1.25 Å. In the twenty-ninth C site, C(38) is bonded in a trigonal planar geometry to one C(37), one C(39), and one C(42) atom. The C(38)-C(39) bond length is 1.37 Å. The C(38)-C(42) bond length is 1.41 Å. In the thirtieth C site, C(39) is bonded in a distorted single-bond geometry to one C(38), one C(40), and one H(19) atom. The C(39)-C(40) bond length is 1.37 Å. The C(39)-H(19) bond length is 0.93 Å. In the thirty-first C site, C(40) is bonded in a trigonal planar geometry to one C(39), one C(41), and one C(48) atom. The C(40)-C(41) bond length is 1.40 Å. The C(40)-C(48) bond length is 1.46 Å. In the thirty-second C site, C(41) is bonded in a trigonal planar geometry to one C(40), one C(42), and one C(43) atom. The C(41)-C(42) bond length is 1.49 Å. The C(41)-C(43) bond length is 1.38 Å. In the thirty-third C site, C(42) is bonded in a trigonal planar geometry to one C(38), one C(41), and one C(47) atom. The C(42)-C(47) bond length is 1.38 Å. In the thirty-fourth C site, C(43) is bonded in a distorted single-bond geometry to one C(41) and one H(20) atom. The C(43)-H(20) bond length is 0.93 Å. In the thirty-fifth C site, C(47) is bonded in a single-bond geometry to one C(42) and one H(24) atom. The C(47)-H(24) bond length is 0.93 Å. In the thirty-sixth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(40), one O(16), and one O(17) atom. The C(48)-O(16) bond length is 1.28 Å. The C(48)-O(17) bond length is 1.27 Å. In the thirty-seventh C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(50), one O(18), and one O(19) atom. The C(49)-C(50) bond length is 1.48 Å. The C(49)-O(18) bond length is 1.27 Å. The C(49)-O(19) bond length is 1.26 Å. In the thirty-eighth C site, C(50) is bonded in a trigonal planar geometry to one C(49), one C(51), and one C(54) atom. The C(50)-C(51) bond length is 1.40 Å. The C(50)-C(54) bond length is 1.41 Å. In the thirty-ninth C site, C(51) is bonded in a distorted single-bond geometry to one C(50), one C(52), and one H(25) atom. The C(51)-C(52) bond length is 1.38 Å. The C(51)-H(25) bond length is 0.93 Å. In the fortieth C site, C(52) is bonded in a trigonal planar geometry to one C(51), one C(53), and one C(60) atom. The C(52)-C(53) bond length is 1.46 Å. The C(52)-C(60) bond length is 1.46 Å. In the forty-first C site, C(53) is bonded in a distorted bent 120 degrees geometry to one C(52), one O(20), and one O(21) atom. The C(53)-O(20) bond length is 1.24 Å. The C(53)-O(21) bond length is 1.29 Å. In the forty-second C site, C(54) is bonded in a trigonal planar geometry to one C(50), one C(55), and one C(60) atom. The C(54)-C(55) bond length is 1.38 Å. The C(54)-C(60) bond length is 1.48 Å. In the forty-third C site, C(55) is bonded in a distorted single-bond geometry to one C(54) and one H(26) atom. The C(55)-H(26) bond length is 0.93 Å. In the forty-fourth C site, C(59) is bonded in a single-bond geometry to one C(60) and one H(30) atom. The C(59)-C(60) bond length is 1.41 Å. The C(59)-H(30) bond length is 0.93 Å. In the forty-fifth C site, C(60) is bonded in a trigonal planar geometry to one C(52), one C(54), and one C(59) atom. In the forty-sixth C site, C(61) is bonded in a distorted bent 120 degrees geometry to one C(62), one O(23), and one O(24) atom. The C(61)-C(62) bond length is 1.53 Å. The C(61)-O(23) bond length is 1.28 Å. The C(61)-O(24) bond length is 1.26 Å. In the forty-seventh C site, C(62) is bonded in a trigonal planar geometry to one C(61), one C(63), and one C(66) atom. The C(62)-C(63) bond length is 1.34 Å. The C(62)-C(66) bond length is 1.41 Å. In the forty-eighth C site, C(63) is bonded in a distorted single-bond geometry to one C(62), one C(64), and one H(31) atom. The C(63)-C(64) bond length is 1.40 Å. The C(63)-H(31) bond length is 0.93 Å. In the forty-ninth C site, C(64) is bonded in a trigonal planar geometry to one C(63), one C(65), and one C(72) atom. The C(64)-C(65) bond length is 1.38 Å. The C(64)-C(72) bond length is 1.46 Å. In the fiftieth C site, C(65) is bonded in a trigonal planar geometry to one C(64), one C(66), and one C(67) atom. The C(65)-C(66) bond length is 1.49 Å. The C(65)-C(67) bond length is 1.39 Å. In the fifty-first C site, C(66) is bonded in a trigonal planar geometry to one C(62), one C(65), and one C(71) atom. The C(66)-C(71) bond length is 1.40 Å. In the fifty-second C site, C(67) is bonded in a single-bond geometry to one C(65) and one H(32) atom. The C(67)-H(32) bond length is 0.93 Å. In the fifty-third C site, C(71) is bonded in a single-bond geometry to one C(66) and one H(36) atom. The C(71)-H(36) bond length is 0.93 Å. In the fifty-fourth C site, C(72) is bonded in a distorted bent 120 degrees geometry to one C(64), one O(25), and one O(26) atom. The C(72)-O(25) bond length is 1.26 Å. The C(72)-O(26) bond length is 1.27 Å. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(27) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(31) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(35) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(39) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(43) atom. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(47) atom. In the thirteenth H site, H(25) is bonded in a single-bond geometry to one C(51) atom. In the fourteenth H site, H(26) is bonded in a single-bond geometry to one C(55) atom. In the fifteenth H site, H(30) is bonded in a single-bond geometry to one C(59) atom. In the sixteenth H site, H(31) is bonded in a single-bond geometry to one C(63) atom. In the seventeenth H site, H(32) is bonded in a single-bond geometry to one C(67) atom. In the eighteenth H site, H(36) is bonded in a single-bond geometry to one C(71) atom. There are twenty-six inequivalent O sites. In the first O site, O(1) is bonded in a tetrahedral geometry to one Zn(1), one Zn(2), one Zn(3), and one Zn(4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(12) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(12) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(13) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(13) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(24) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(24) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(25) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(25) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(8) and one C(36) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(36) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(37) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(37) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Zn(8) and one C(48) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(48) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(49) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(49) atom. In the twentieth O site, O(20) is bonded in a 2-coordinate geometry to one Zn(5) and one C(53) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(53) atom. In the twenty-second O site, O(22) is bonded in a tetrahedral geometry to one Zn(5), one Zn(6), one Zn(7), and one Zn(8) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Zn(8) and one C(61) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(61) atom. In the twenty-fifth O site, O(25) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(72) atom. In the twenty-sixth O site, O(26) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(72) atom. Linkers: 12 [O]C(=O)c1cc(C([O])=O)c2cccccc1-2. Metal clusters: 4 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: lcy. The MOF has largest included sphere 6.41 A, density 1.19 g/cm3, surface area 3888.49 m2/g, accessible volume 0.48 cm3/g