CuC14H8(NO)4(CH)2 crystallizes in the cubic Fm-3 space group. The structure consists of ninety-six 02329_fluka molecules inside a CuC14H8(NO)4 framework. In the CuC14H8(NO)4 framework, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Cu(1)-O(1) bond lengths are 1.99 Å. Both Cu(1)-O(2) bond lengths are 1.81 Å. There are seven inequivalent C sites. In the first C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(2) atom. The C(8)-C(5) bond length is 1.47 Å. The C(8)-O(1) bond length is 1.19 Å. The C(8)-O(2) bond length is 1.46 Å. In the second C site, C(1) is bonded in a distorted trigonal planar geometry to one N(2) and two equivalent N(1) atoms. The C(1)-N(2) bond length is 1.36 Å. There is one shorter (1.33 Å) and one longer (1.44 Å) C(1)-N(1) bond length. In the third C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one N(2) atom. The C(2)-C(3) bond length is 1.35 Å. The C(2)-N(2) bond length is 1.42 Å. In the fourth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.35 Å. The C(3)-H(2) bond length is 0.94 Å. In the fifth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(3) bond length is 0.94 Å. In the sixth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.31 Å. In the seventh C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(6)-H(4) bond length is 0.94 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one H(1) atom. The N(2)-H(1) bond length is 0.87 Å. In the second N site, N(1) is bonded in a water-like geometry to two equivalent C(1) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(8) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Cu(1) and one C(8) atom. Linkers: 8 [O]C(=O)c1ccc(cc1)NC1=NC(=[N]=C([N]1)Nc1ccc(cc1)C(=O)[O])Nc1ccc(cc1)C(=O)[O]. Metal clusters: 6 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: tbo. The MOF has largest included sphere 28.43 A, density 0.25 g/cm3, surface area 4283.88 m2/g, accessible volume 3.65 cm3/g