SrPtC14H6(NO)4 crystallizes in the triclinic P-1 space group. Sr(1) is bonded in a 7-coordinate geometry to one N(4), one O(3), one O(4), two equivalent O(1), and two equivalent O(2) atoms. The Sr(1)-N(4) bond length is 2.68 Å. The Sr(1)-O(3) bond length is 2.73 Å. The Sr(1)-O(4) bond length is 2.65 Å. There is one shorter (2.56 Å) and one longer (2.77 Å) Sr(1)-O(1) bond length. There is one shorter (2.61 Å) and one longer (2.71 Å) Sr(1)-O(2) bond length. Pt(1) is bonded in a rectangular see-saw-like geometry to one C(13), one C(14), one N(1), and one N(2) atom. The Pt(1)-C(13) bond length is 1.97 Å. The Pt(1)-C(14) bond length is 1.97 Å. The Pt(1)-N(1) bond length is 2.01 Å. The Pt(1)-N(2) bond length is 2.04 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.41 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 0.95 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(11), one C(2), and one C(4) atom. The C(3)-C(11) bond length is 1.54 Å. The C(3)-C(4) bond length is 1.36 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(3) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.42 Å. The C(5)-N(1) bond length is 1.37 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-N(2) bond length is 1.37 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(4) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(4) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.57 Å. The C(8)-C(9) bond length is 1.37 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(9)-H(5) bond length is 0.94 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(10)-N(2) bond length is 1.33 Å. The C(10)-H(6) bond length is 0.94 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(2) atom. The C(11)-O(1) bond length is 1.22 Å. The C(11)-O(2) bond length is 1.22 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(3), and one O(4) atom. The C(12)-O(3) bond length is 1.23 Å. The C(12)-O(4) bond length is 1.26 Å. In the thirteenth C site, C(13) is bonded in a linear geometry to one Pt(1) and one N(3) atom. The C(13)-N(3) bond length is 1.11 Å. In the fourteenth C site, C(14) is bonded in a linear geometry to one Pt(1) and one N(4) atom. The C(14)-N(4) bond length is 1.14 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Pt(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Pt(1), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a single-bond geometry to one C(13) atom. In the fourth N site, N(4) is bonded in a distorted linear geometry to one Sr(1) and one C(14) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one C(11) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one C(11) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Sr(1) and one C(12) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Sr(1) and one C(12) atom. Linkers: 2 [O]C(=O)c1ccnc(-c2cc(C([O])=O)ccn2)c1. Metal clusters: 2 [Sr] ,2 [Pt]. The MOF has largest included sphere 5.16 A, density 2.08 g/cm3, surface area 2813.77 m2/g, accessible volume 0.16 cm3/g