AgCdC26H12I2(NO4)2(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a AgCdC26H12I2(NO4)2 framework. In the AgCdC26H12I2(NO4)2 framework, Ag(1) is bonded in a distorted square pyramidal geometry to one N(1), one N(2), one O(2), one O(5), and one I(1) atom. The Ag(1)-N(1) bond length is 2.29 Å. The Ag(1)-N(2) bond length is 2.37 Å. The Ag(1)-O(2) bond length is 2.70 Å. The Ag(1)-O(5) bond length is 2.52 Å. The Ag(1)-I(1) bond length is 2.76 Å. Cd(1) is bonded in a 7-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), one O(7), and one O(8) atom. The Cd(1)-O(1) bond length is 2.25 Å. The Cd(1)-O(2) bond length is 2.69 Å. The Cd(1)-O(3) bond length is 2.29 Å. The Cd(1)-O(5) bond length is 2.36 Å. The Cd(1)-O(6) bond length is 2.47 Å. The Cd(1)-O(7) bond length is 2.26 Å. The Cd(1)-O(8) bond length is 2.58 Å. There are twenty-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one N(1) atom. The C(1)-C(15) bond length is 1.42 Å. The C(1)-C(17) bond length is 1.41 Å. The C(1)-N(1) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(10) and one H(13) atom. The C(2)-C(10) bond length is 1.40 Å. The C(2)-H(13) bond length is 0.93 Å. In the third C site, C(3) is bonded in a bent 120 degrees geometry to one C(14), one O(2), and one O(7) atom. The C(3)-C(14) bond length is 1.51 Å. The C(3)-O(2) bond length is 1.22 Å. The C(3)-O(7) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(20), one C(23), and one H(2) atom. The C(4)-C(20) bond length is 1.34 Å. The C(4)-C(23) bond length is 1.39 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(5), and one O(6) atom. The C(5)-C(20) bond length is 1.52 Å. The C(5)-O(5) bond length is 1.29 Å. The C(5)-O(6) bond length is 1.21 Å. In the sixth C site, C(6) is bonded in a 2-coordinate geometry to one N(1) and one H(3) atom. The C(6)-N(1) bond length is 1.36 Å. The C(6)-H(3) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(22), and one C(27) atom. The C(7)-C(11) bond length is 1.50 Å. The C(7)-C(22) bond length is 1.40 Å. The C(7)-C(27) bond length is 1.39 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(1), and one O(4) atom. The C(8)-C(16) bond length is 1.52 Å. The C(8)-O(1) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.25 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(15), one C(2), and one C(28) atom. The C(10)-C(15) bond length is 1.41 Å. The C(10)-C(28) bond length is 1.37 Å. In the tenth C site, C(11) is bonded in a bent 120 degrees geometry to one C(7), one O(3), and one O(8) atom. The C(11)-O(3) bond length is 1.28 Å. The C(11)-O(8) bond length is 1.26 Å. In the eleventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(11) atom. The C(12)-N(2) bond length is 1.31 Å. The C(12)-H(11) bond length is 0.93 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one H(8) atom. The C(13)-C(16) bond length is 1.38 Å. The C(13)-C(20) bond length is 1.39 Å. The C(13)-H(8) bond length is 0.93 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(19), one C(27), and one C(3) atom. The C(14)-C(19) bond length is 1.39 Å. The C(14)-C(27) bond length is 1.37 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(1), one C(10), and one N(2) atom. The C(15)-N(2) bond length is 1.38 Å. In the fifteenth C site, C(16) is bonded in a trigonal planar geometry to one C(13), one C(25), and one C(8) atom. The C(16)-C(25) bond length is 1.41 Å. In the sixteenth C site, C(17) is bonded in a trigonal planar geometry to one C(1), one C(21), and one C(26) atom. The C(17)-C(21) bond length is 1.38 Å. The C(17)-C(26) bond length is 1.46 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14), one C(24), and one H(14) atom. The C(19)-C(24) bond length is 1.38 Å. The C(19)-H(14) bond length is 0.93 Å. In the eighteenth C site, C(20) is bonded in a trigonal planar geometry to one C(13), one C(4), and one C(5) atom. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(17) and one H(10) atom. The C(21)-H(10) bond length is 0.93 Å. In the twentieth C site, C(22) is bonded in a single-bond geometry to one C(24), one C(7), and one H(4) atom. The C(22)-C(24) bond length is 1.37 Å. The C(22)-H(4) bond length is 0.93 Å. In the twenty-first C site, C(23) is bonded in a trigonal planar geometry to one C(25), one C(4), and one I(2) atom. The C(23)-C(25) bond length is 1.35 Å. The C(23)-I(2) bond length is 2.14 Å. In the twenty-second C site, C(24) is bonded in a trigonal planar geometry to one C(19), one C(22), and one I(1) atom. The C(24)-I(1) bond length is 2.12 Å. In the twenty-third C site, C(25) is bonded in a distorted single-bond geometry to one C(16), one C(23), and one H(6) atom. The C(25)-H(6) bond length is 0.93 Å. In the twenty-fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(17) and one H(7) atom. The C(26)-H(7) bond length is 0.93 Å. In the twenty-fifth C site, C(27) is bonded in a distorted single-bond geometry to one C(14), one C(7), and one H(12) atom. The C(27)-H(12) bond length is 0.93 Å. In the twenty-sixth C site, C(28) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(28)-H(5) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(6) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(12), and one C(15) atom. There are twelve inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(22) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(28) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(25) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(26) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(27) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(2) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(8) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(1), one Cd(1), and one C(3) atom. In the third O site, O(6) is bonded in a distorted single-bond geometry to one Cd(1) and one C(5) atom. In the fourth O site, O(7) is bonded in a water-like geometry to one Cd(1) and one C(3) atom. In the fifth O site, O(3) is bonded in a water-like geometry to one Cd(1) and one C(11) atom. In the sixth O site, O(4) is bonded in a single-bond geometry to one C(8) atom. In the seventh O site, O(5) is bonded in a distorted single-bond geometry to one Ag(1), one Cd(1), and one C(5) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Cd(1) and one C(11) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a water-like geometry to one Ag(1) and one C(24) atom. In the second I site, I(2) is bonded in a single-bond geometry to one C(23) atom. Linkers: 8 [O]C(=O)c1cc(I)cc(C([O])=O)c1. Metal clusters: 4 O=[C]O[Cd]1(O[C]=O)(O[C]=O)O[C]O1.[Ag]. RCSR code: sql. The MOF has largest included sphere 4.79 A, density 1.73 g/cm3, surface area 3195.89 m2/g, accessible volume 0.27 cm3/g