Cd4C49H32O20(CH)8C9H8O4 is Indium-derived structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules; two 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and two Cd4C49H32O20 clusters. In each Cd4C49H32O20 cluster, Cd(1) is bonded in a 4-coordinate geometry to one O(2), one O(3), one O(5), and one O(6) atom. The Cd(1)-O(2) bond length is 2.34 Å. The Cd(1)-O(3) bond length is 2.31 Å. The Cd(1)-O(5) bond length is 2.27 Å. The Cd(1)-O(6) bond length is 2.44 Å. There are thirteen inequivalent C sites. In the first C site, C(17) is bonded in a tetrahedral geometry to four equivalent C(1) atoms. All C(17)-C(1) bond lengths are 1.52 Å. In the second C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(17); two equivalent H(1,2); and one O(1) atom. Both C(1)-H(1,2) bond lengths are 0.97 Å. The C(1)-O(1) bond length is 1.43 Å. In the third C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one O(1) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.39 Å. The C(2)-O(1) bond length is 1.36 Å. In the fourth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(3)-H(3) bond length is 0.93 Å. In the fifth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(4) bond length is 0.93 Å. In the sixth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.42 Å. The C(5)-C(8) bond length is 1.48 Å. In the seventh C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(5) atom. The C(6)-C(7) bond length is 1.36 Å. The C(6)-H(5) bond length is 0.93 Å. In the eighth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(6) atom. The C(7)-H(6) bond length is 0.93 Å. In the ninth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(2), and one O(3) atom. The C(8)-O(2) bond length is 1.27 Å. The C(8)-O(3) bond length is 1.23 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(12)-C(13) bond length is 1.37 Å. The C(12)-H(10) bond length is 0.93 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.43 Å. The C(13)-C(16) bond length is 1.50 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(14)-H(11) bond length is 0.93 Å. In the thirteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(5), and one O(6) atom. The C(16)-O(5) bond length is 1.27 Å. The C(16)-O(6) bond length is 1.26 Å. There are seven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(8) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(8) atom. In the fourth O site, O(5) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(16) atom. In the fifth O site, O(6) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(16) atom. Linkers: 5 [O]C(=O)c1ccc(OCC(COc2ccc(C([O])=O)cc2)(COc2ccc(C([O])=O)cc2)COc2ccc(C([O])=O)cc2)cc1 ,1 [O]C(=O)c1ccc(OCC(COc2cc[c]cc2)(COc2ccc(C([O])=O)cc2)COc2ccc(C([O])=O)cc2)cc1 ,1 [CH]=[C]OCC([CH2])(COc1ccc(C([O])=O)cc1)COc1ccc(C([O])=O)cc1. Metal clusters: 4 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 4.83 A, density 1.23 g/cm3, surface area 4250.82 m2/g, accessible volume 0.39 cm3/g