Zn3C54H24(N7O6)2 crystallizes in the cubic P4_132 space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal planar geometry to three equivalent O(1) atoms. All Zn(1)-O(1) bond lengths are 1.89 Å. In the second Zn site, Zn(2) is bonded in an octahedral geometry to six equivalent O(2) atoms. All Zn(2)-O(2) bond lengths are 1.85 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.50 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.50 Å. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.34 Å. The C(4)-C(8) bond length is 1.60 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.26 Å. The C(7)-O(2) bond length is 1.38 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one N(2) atom. The C(8)-N(1) bond length is 1.35 Å. The C(8)-N(2) bond length is 1.28 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. The C(9)-N(1) bond length is 1.37 Å. The C(9)-N(2) bond length is 1.37 Å. The C(9)-N(3) bond length is 1.26 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one C(8) and one C(9) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(8) and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to three equivalent C(9) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Zn(1) and one C(7) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(7) atom. Linkers: 7 [O]C(=O)c1ccc(cc1)C1=NC2=NC(=NC3=NC(=[N]=C([N]1)N23)c1ccc(cc1)C(=O)[O])c1ccc(cc1)C(=O)[O] ,1 [O]C(=O)c1ccc(cc1)C1=NC2=NC(=[N]=C3N2C(=[N]=C([N]3)c2ccc(cc2)C(=O)[O])[N]1)c1ccc(cc1)C(=O)[O]. Metal clusters: 4 [C]1O[Zn]2O[C]O[Zn]34(O1)(O[C]O2)O[C]O[Zn](O[C]O3)O[C]O4. The MOF has largest included sphere 19.00 A, density 0.33 g/cm3, surface area 4086.26 m2/g, accessible volume 2.52 cm3/g