ZnC10NH6O4(CH)2C5H5NC4H2O is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight 2-methoxypropene molecules, four C5H5N clusters, and four ZnC10NH6O4 clusters. In each C5H5N cluster, there are five inequivalent C sites. In the first C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(10) atom. The C(16)-C(17) bond length is 1.35 Å. The C(16)-H(10) bond length is 0.93 Å. In the second C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.37 Å. The C(17)-C(20) bond length is 1.47 Å. In the third C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(11) atom. The C(18)-H(11) bond length is 0.93 Å. In the fourth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(17), one C(21), and one N(2) atom. The C(20)-C(21) bond length is 1.48 Å. The C(20)-N(2) bond length is 1.26 Å. In the fifth C site, C(21) is bonded in a trigonal non-coplanar geometry to one C(20), one H(13), one H(14), and one H(15) atom. The C(21)-H(13) bond length is 0.96 Å. The C(21)-H(14) bond length is 0.96 Å. The C(21)-H(15) bond length is 0.96 Å. N(2) is bonded in a distorted bent 120 degrees geometry to one C(20) and one N(2) atom. The N(2)-N(2) bond length is 1.41 Å. There are five inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In each ZnC10NH6O4 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(4), and one O(5) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.03 Å. The Zn(1)-O(4) bond length is 2.04 Å. The Zn(1)-O(5) bond length is 2.04 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.37 Å. The C(10)-H(6) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(14) bond length is 1.47 Å. In the seventh C site, C(12) is bonded in a single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 0.93 Å. In the eighth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(15)-N(1) bond length is 1.32 Å. The C(15)-H(9) bond length is 0.93 Å. In the ninth C site, C(14) is bonded in a bent 120 degrees geometry to one C(11), one O(4), and one O(5) atom. The C(14)-O(4) bond length is 1.24 Å. The C(14)-O(5) bond length is 1.24 Å. In the tenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(12) atom. The C(19)-N(1) bond length is 1.29 Å. The C(19)-H(12) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(19) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. Linkers: 4 C[C]([N][N][C](C)c1ccncc1)c1ccncc1 ,8 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: sql. The MOF has largest included sphere 4.92 A, density 1.17 g/cm3, surface area 4322.18 m2/g, accessible volume 0.43 cm3/g