Ag2C10N5H15SO3CH crystallizes in the orthorhombic Pbca space group. The structure consists of eight 02329_fluka molecules inside a Ag2C10N5H15SO3 framework. In the Ag2C10N5H15SO3 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a trigonal planar geometry to one N(2), one N(4), and one N(5) atom. The Ag(1)-N(2) bond length is 2.42 Å. The Ag(1)-N(4) bond length is 2.38 Å. The Ag(1)-N(5) bond length is 2.40 Å. In the second Ag site, Ag(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one O(3) atom. The Ag(2)-N(1) bond length is 2.28 Å. The Ag(2)-N(3) bond length is 2.30 Å. The Ag(2)-O(3) bond length is 2.39 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(4) bond length is 0.93 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one S(1) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-S(1) bond length is 1.77 Å. In the fourth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 0.93 Å. In the fifth C site, C(9) is bonded to one N(3), one N(5), one H(11), and one H(12) atom to form corner-sharing CH2N2 tetrahedra. The C(9)-N(3) bond length is 1.48 Å. The C(9)-N(5) bond length is 1.47 Å. The C(9)-H(11) bond length is 0.97 Å. The C(9)-H(12) bond length is 0.97 Å. In the sixth C site, C(10) is bonded to one N(4), one N(5), one H(13), and one H(14) atom to form corner-sharing CH2N2 tetrahedra. The C(10)-N(4) bond length is 1.48 Å. The C(10)-N(5) bond length is 1.49 Å. The C(10)-H(13) bond length is 0.97 Å. The C(10)-H(14) bond length is 0.97 Å. In the seventh C site, C(11) is bonded to one N(3), one N(4), one H(15), and one H(16) atom to form corner-sharing CH2N2 tetrahedra. The C(11)-N(3) bond length is 1.48 Å. The C(11)-N(4) bond length is 1.49 Å. The C(11)-H(15) bond length is 0.97 Å. The C(11)-H(16) bond length is 0.97 Å. In the eighth C site, C(6) is bonded to one N(2), one N(3), one H(5), and one H(6) atom to form corner-sharing CH2N2 tetrahedra. The C(6)-N(2) bond length is 1.48 Å. The C(6)-N(3) bond length is 1.48 Å. The C(6)-H(5) bond length is 0.97 Å. The C(6)-H(6) bond length is 0.97 Å. In the ninth C site, C(7) is bonded to one N(2); one N(5); and two equivalent H(7,8) atoms to form corner-sharing CH2N2 tetrahedra. The C(7)-N(2) bond length is 1.48 Å. The C(7)-N(5) bond length is 1.48 Å. Both C(7)-H(7,8) bond lengths are 0.97 Å. In the tenth C site, C(8) is bonded to one N(2); one N(4); and two equivalent H(9,10) atoms to form corner-sharing CH2N2 tetrahedra. The C(8)-N(2) bond length is 1.47 Å. The C(8)-N(4) bond length is 1.49 Å. Both C(8)-H(9,10) bond lengths are 0.97 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(2), one C(1), and one C(5) atom. In the second N site, N(2) is bonded to one Ag(1), one C(6), one C(7), and one C(8) atom to form distorted corner-sharing NAgC3 tetrahedra. In the third N site, N(3) is bonded to one Ag(2), one C(11), one C(6), and one C(9) atom to form corner-sharing NAgC3 tetrahedra. In the fourth N site, N(4) is bonded to one Ag(1), one C(10), one C(11), and one C(8) atom to form distorted corner-sharing NAgC3 tetrahedra. In the fifth N site, N(5) is bonded to one Ag(1), one C(10), one C(7), and one C(9) atom to form distorted corner-sharing NAgC3 tetrahedra. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(11) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.45 Å. The S(1)-O(2) bond length is 1.45 Å. The S(1)-O(3) bond length is 1.45 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(2) and one S(1) atom. Linkers: 8 [O]S([O])([O])c1cccnc1 ,8 C1N2CN3CN1CN(C2)C3. Metal clusters: 8 [Ag] ,4 [O][S@](=O)O[Ag] ,4 [O][S@@](=O)O[Ag]. The MOF has largest included sphere 5.17 A, density 1.57 g/cm3, surface area 3308.30 m2/g, accessible volume 0.33 cm3/g