(Cu(OOCC6H4COO))2(CH)8C9H8O4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules; four 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and four Cu(OOCC6H4COO) clusters. In each Cu(OOCC6H4COO) cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-O(1) bond length is 1.99 Å. The Cu(1)-O(2) bond length is 1.97 Å. The Cu(1)-O(3) bond length is 1.97 Å. The Cu(1)-O(4) bond length is 1.98 Å. There are eight inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(5)-C(2) bond length is 1.49 Å. The C(5)-O(1) bond length is 1.26 Å. The C(5)-O(2) bond length is 1.23 Å. In the second C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(1)-C(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.93 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(5) atom. The C(2)-C(3) bond length is 1.37 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(14) and one H(6) atom. The C(7)-C(14) bond length is 1.41 Å. The C(7)-H(6) bond length is 0.93 Å. In the fifth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 0.93 Å. In the sixth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(13)-C(14) bond length is 1.35 Å. The C(13)-H(11) bond length is 0.93 Å. In the seventh C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(16), and one C(7) atom. The C(14)-C(16) bond length is 1.49 Å. In the eighth C site, C(16) is bonded in a bent 120 degrees geometry to one C(14), one O(3), and one O(4) atom. The C(16)-O(3) bond length is 1.28 Å. The C(16)-O(4) bond length is 1.24 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(5) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(5) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(16) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cu(1) and one C(16) atom. Linkers: 2 [O]C(=O)c1ccc(OCC(COc2ccc(C([O])=O)cc2)(COc2ccc(C([O])=O)cc2)COc2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: pts. The MOF has largest included sphere 7.63 A, density 0.58 g/cm3, surface area 4321.00 m2/g, accessible volume 1.22 cm3/g