W18Cu6C36P2N12H24O47(CH)12 crystallizes in the trigonal R3 space group. The structure consists of thirty-six 02329_fluka molecules inside a W18Cu6C36P2N12H24O47 framework. In the W18Cu6C36P2N12H24O47 framework, there are six inequivalent W sites. In the first W site, W(1) is bonded to one O(1), one O(16), one O(2), and two equivalent O(3) atoms to form distorted WO5 square pyramids that share  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one W(6)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and edges with two equivalent W(1)O5 square pyramids. The W(1)-O(1) bond length is 1.81 Å. The W(1)-O(16) bond length is 2.36 Å. The W(1)-O(2) bond length is 1.96 Å. There is one shorter (1.90 Å) and one longer (1.98 Å) W(1)-O(3) bond length. In the second W site, W(2) is bonded to one O(1), one O(4), one O(5), one O(6), and one O(7) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(1)O5 square pyramid,  a cornercorner with one W(3)O5 square pyramid,  a cornercorner with one W(6)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(6)O5 square pyramid. The W(2)-O(1) bond length is 2.01 Å. The W(2)-O(4) bond length is 2.32 Å. The W(2)-O(5) bond length is 1.86 Å. The W(2)-O(6) bond length is 1.85 Å. The W(2)-O(7) bond length is 1.89 Å. In the third W site, W(3) is bonded to one O(10), one O(11), one O(5), one O(8), and one O(9) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(5)O6 octahedra,  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(5)O6 octahedra. The corner-sharing octahedral tilt angles are 29°. The W(3)-O(10) bond length is 1.91 Å. The W(3)-O(11) bond length is 1.86 Å. The W(3)-O(5) bond length is 1.94 Å. The W(3)-O(8) bond length is 1.86 Å. The W(3)-O(9) bond length is 2.36 Å. In the fourth W site, W(4) is bonded in a 5-coordinate geometry to one O(12), one O(17), one O(8), and two equivalent O(13) atoms. The W(4)-O(12) bond length is 1.86 Å. The W(4)-O(17) bond length is 2.38 Å. The W(4)-O(8) bond length is 1.95 Å. There is one shorter (1.88 Å) and one longer (1.94 Å) W(4)-O(13) bond length. In the fifth W site, W(5) is bonded to one O(10), one O(11), one O(12), one O(14), one O(15), and one O(9) atom to form distorted WO6 octahedra that share  a cornercorner with one W(3)O5 square pyramid,  a cornercorner with one W(6)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(3)O5 square pyramid. The W(5)-O(10) bond length is 1.90 Å. The W(5)-O(11) bond length is 1.94 Å. The W(5)-O(12) bond length is 1.98 Å. The W(5)-O(14) bond length is 1.82 Å. The W(5)-O(15) bond length is 1.73 Å. The W(5)-O(9) bond length is 2.32 Å. In the sixth W site, W(6) is bonded to one O(14), one O(2), one O(4), one O(6), and one O(7) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(5)O6 octahedra,  a cornercorner with one W(1)O5 square pyramid,  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(2)O5 square pyramid. The corner-sharing octahedral tilt angles are 15°. The W(6)-O(14) bond length is 1.97 Å. The W(6)-O(2) bond length is 1.86 Å. The W(6)-O(4) bond length is 2.36 Å. The W(6)-O(6) bond length is 1.92 Å. The W(6)-O(7) bond length is 1.89 Å. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a T-shaped geometry to one N(1), one N(3), and one O(15) atom. The Cu(1)-N(1) bond length is 1.90 Å. The Cu(1)-N(3) bond length is 1.89 Å. The Cu(1)-O(15) bond length is 2.27 Å. In the second Cu site, Cu(2) is bonded in a distorted linear geometry to one N(2) and one N(4) atom. The Cu(2)-N(2) bond length is 1.92 Å. The Cu(2)-N(4) bond length is 1.91 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one C(6) and one N(1) atom. The C(1)-C(6) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.34 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(2) bond length is 0.95 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 0.95 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(4) atom. The C(5)-C(6) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.95 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one N(2) atom. The C(6)-N(2) bond length is 1.36 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one H(5) atom. The C(7)-C(8) bond length is 1.47 Å. The C(7)-N(2) bond length is 1.31 Å. The C(7)-H(5) bond length is 0.95 Å. In the seventh C site, C(8) is bonded in a bent 120 degrees geometry to one C(7), one N(1), and one H(6) atom. The C(8)-N(1) bond length is 1.28 Å. The C(8)-H(6) bond length is 0.95 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(14) and one N(3) atom. The C(9)-C(14) bond length is 1.44 Å. The C(9)-N(3) bond length is 1.37 Å. In the ninth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(10) atom. The C(13)-C(14) bond length is 1.35 Å. The C(13)-H(10) bond length is 0.95 Å. In the tenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one N(4) atom. The C(14)-N(4) bond length is 1.34 Å. In the eleventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one N(4), and one H(11) atom. The C(15)-C(16) bond length is 1.42 Å. The C(15)-N(4) bond length is 1.28 Å. The C(15)-H(11) bond length is 0.95 Å. In the twelfth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(3), and one H(12) atom. The C(16)-N(3) bond length is 1.24 Å. The C(16)-H(12) bond length is 0.95 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(16) and three equivalent O(4) atoms to form PO4 tetrahedra that share corners with three equivalent W(1)O5 square pyramids, corners with three equivalent W(2)O5 square pyramids, and corners with three equivalent W(6)O5 square pyramids. The P(1)-O(16) bond length is 1.61 Å. All P(1)-O(4) bond lengths are 1.53 Å. In the second P site, P(2) is bonded to one O(17) and three equivalent O(9) atoms to form PO4 tetrahedra that share corners with three equivalent W(5)O6 octahedra and corners with three equivalent W(3)O5 square pyramids. The corner-sharing octahedral tilt angles are 51°. The P(2)-O(17) bond length is 1.57 Å. All P(2)-O(9) bond lengths are 1.55 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(6), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(16), and one C(9) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(14), and one C(15) atom. There are eight inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. There are seventeen inequivalent O sites. In the first O site, O(16) is bonded in a distorted single-bond geometry to three equivalent W(1) and one P(1) atom. In the second O site, O(17) is bonded in a distorted single-bond geometry to three equivalent W(4) and one P(2) atom. In the third O site, O(1) is bonded in a bent 150 degrees geometry to one W(1) and one W(2) atom. In the fourth O site, O(2) is bonded in a bent 150 degrees geometry to one W(1) and one W(6) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to two equivalent W(1) atoms. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one W(2), one W(6), and one P(1) atom. In the seventh O site, O(5) is bonded in a linear geometry to one W(2) and one W(3) atom. In the eighth O site, O(6) is bonded in a bent 150 degrees geometry to one W(2) and one W(6) atom. In the ninth O site, O(7) is bonded in a bent 120 degrees geometry to one W(2) and one W(6) atom. In the tenth O site, O(8) is bonded in a bent 150 degrees geometry to one W(3) and one W(4) atom. In the eleventh O site, O(9) is bonded in a distorted single-bond geometry to one W(3), one W(5), and one P(2) atom. In the twelfth O site, O(10) is bonded in a bent 150 degrees geometry to one W(3) and one W(5) atom. In the thirteenth O site, O(11) is bonded in a bent 120 degrees geometry to one W(3) and one W(5) atom. In the fourteenth O site, O(12) is bonded in a bent 150 degrees geometry to one W(4) and one W(5) atom. In the fifteenth O site, O(13) is bonded in a bent 120 degrees geometry to two equivalent W(4) atoms. In the sixteenth O site, O(14) is bonded in a distorted linear geometry to one W(5) and one W(6) atom. In the seventeenth O site, O(15) is bonded in a bent 120 degrees geometry to one W(5) and one Cu(1) atom. Linkers: 18 c1ccc2nccnc2c1. Metal clusters: 3 [Cu]O[W]123O[W@]45O[W]67(O[Cu])O[W@]89O[W]%10%11(O[Cu])O[W@](O1)(O[W@]1(O%10)O[W@](O2)(O4)O[W@](O6)(O8)O1)O[W@@]12O[W@@]4(O3)O[W@@]3(O5)O[W@@]5(O7)O[W@@]6(O9)O[W@@](O%11)(O1)O[W@@]1(O2)O[W@](O4)(O3)O[W@](O5)(O6)O1 ,9 [Cu]. The MOF has largest included sphere 10.49 A, density 1.81 g/cm3, surface area 1678.32 m2/g, accessible volume 0.38 cm3/g