Zn4C24H12O13 is Indium-like structured and crystallizes in the trigonal R-3m space group. The structure is zero-dimensional and consists of twelve Zn4C24H12O13 clusters. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(3), one O(7), and two equivalent O(1) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(3) bond length is 1.95 Å. The Zn(1)-O(7) bond length is 1.96 Å. Both Zn(1)-O(1) bond lengths are 1.94 Å. In the second Zn site, Zn(3) is bonded to one O(7) and three equivalent O(4) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(7) bond length is 1.96 Å. All Zn(3)-O(4) bond lengths are 1.95 Å. There are seven inequivalent C sites. In the first C site, C(2) is bonded in a single-bond geometry to one C(13) and one H(2) atom. The C(2)-C(13) bond length is 1.38 Å. The C(2)-H(2) bond length is 0.93 Å. In the second C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(13) and two equivalent O(1) atoms. The C(14)-C(13) bond length is 1.51 Å. Both C(14)-O(1) bond lengths are 1.26 Å. In the third C site, C(13) is bonded in a trigonal planar geometry to one C(14) and two equivalent C(2) atoms. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(6)-C(9) bond length is 1.36 Å. The C(6)-H(4) bond length is 0.93 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(8)-C(9) bond length is 1.40 Å. The C(8)-H(6) bond length is 0.93 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(6), and one C(8) atom. The C(9)-C(10) bond length is 1.50 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(10)-O(3) bond length is 1.26 Å. The C(10)-O(4) bond length is 1.25 Å. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(8) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(10) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(10) atom. In the fourth O site, O(7) is bonded in a tetrahedral geometry to one Zn(3) and three equivalent Zn(1) atoms. Linkers: 12 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 4 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: pcu. The MOF has largest included sphere 7.96 A, density 1.17 g/cm3, surface area 3715.86 m2/g, accessible volume 0.48 cm3/g