NaZn2C28H26(NO6)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one NaZn2C28H26(NO6)2 cluster. Na(1) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(5) atoms to form NaO6 octahedra that share corners with two equivalent Zn(1)NO3 tetrahedra. Both Na(1)-O(1) bond lengths are 2.33 Å. Both Na(1)-O(3) bond lengths are 2.30 Å. Both Na(1)-O(5) bond lengths are 2.51 Å. Zn(1) is bonded to one N(1), one O(2), one O(4), and one O(5) atom to form ZnNO3 tetrahedra that share  a cornercorner with one Na(1)O6 octahedra,  a cornercorner with one C(13)H3N tetrahedra, and  a cornercorner with one C(14)H3N tetrahedra. The corner-sharing octahedral tilt angles are 86°. The Zn(1)-N(1) bond length is 2.06 Å. The Zn(1)-O(2) bond length is 1.97 Å. The Zn(1)-O(4) bond length is 1.98 Å. The Zn(1)-O(5) bond length is 1.96 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.23 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(4) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(4)-H(3) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(3), and one O(4) atom. The C(5)-C(6) bond length is 1.51 Å. The C(5)-O(3) bond length is 1.23 Å. The C(5)-O(4) bond length is 1.27 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-C(8) bond length is 1.38 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(8)-H(5) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(5), and one O(6) atom. The C(9)-C(10) bond length is 1.51 Å. The C(9)-O(5) bond length is 1.29 Å. The C(9)-O(6) bond length is 1.22 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(12) bond length is 1.39 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(6,7) atom. The C(11)-H(6,7) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one H(6,7) atom. The C(12)-H(6,7) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded to one N(1); one H(10); and two equivalent H(8,9,12) atoms to form CH3N tetrahedra that share  a cornercorner with one Zn(1)NO3 tetrahedra and  a cornercorner with one C(14)H3N tetrahedra. The C(13)-N(1) bond length is 1.47 Å. The C(13)-H(10) bond length is 0.96 Å. Both C(13)-H(8,9,12) bond lengths are 0.96 Å. In the fourteenth C site, C(14) is bonded to one N(1); one H(11); one H(13); and one H(8,9,12) atom to form CH3N tetrahedra that share  a cornercorner with one Zn(1)NO3 tetrahedra and  a cornercorner with one C(13)H3N tetrahedra. The C(14)-N(1) bond length is 1.48 Å. The C(14)-H(11) bond length is 0.96 Å. The C(14)-H(13) bond length is 0.96 Å. The C(14)-H(8,9,12) bond length is 0.96 Å. N(1) is bonded in a distorted single-bond geometry to one Zn(1), one C(13), one C(14), and one H(1) atom. The N(1)-H(1) bond length is 0.86 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6,7) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(8,9,12) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Na(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zn(1) and one C(5) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Na(1), one Zn(1), and one C(9) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(9) atom. Linkers: 4 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 1 [Na] ,2 [Zn]. The MOF has largest included sphere 3.90 A, density 1.37 g/cm3, surface area 4533.84 m2/g, accessible volume 0.33 cm3/g