Cd3C26H26(N5O3)2(CH3)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and four Cd3C26H26(N5O3)2 clusters. In each Cd3C26H26(N5O3)2 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted L-shaped geometry to one O(1) and one O(2) atom. The Cd(1)-O(1) bond length is 2.21 Å. The Cd(1)-O(2) bond length is 2.31 Å. In the second Cd site, Cd(2) is bonded in a distorted pentagonal pyramidal geometry to two equivalent N(5), two equivalent O(2), and two equivalent O(3) atoms. Both Cd(2)-N(5) bond lengths are 2.32 Å. Both Cd(2)-O(2) bond lengths are 2.47 Å. Both Cd(2)-O(3) bond lengths are 2.45 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(3), and one H(1) atom. The C(1)-C(2) bond length is 1.36 Å. The C(1)-N(3) bond length is 1.36 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.45 Å. The C(2)-C(6) bond length is 1.50 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one O(1) atom. The C(3)-C(4) bond length is 1.45 Å. The C(3)-O(1) bond length is 1.25 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(10), one C(3), and one C(5) atom. The C(4)-C(10) bond length is 1.41 Å. The C(4)-C(5) bond length is 1.38 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one N(3) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-N(3) bond length is 1.38 Å. In the sixth C site, C(6) is bonded in a bent 120 degrees geometry to one C(2), one O(2), and one O(3) atom. The C(6)-O(2) bond length is 1.26 Å. The C(6)-O(3) bond length is 1.25 Å. In the seventh C site, C(7) is bonded in a 3-coordinate geometry to one N(3), one H(2), and one H(3) atom. The C(7)-N(3) bond length is 1.48 Å. The C(7)-H(2) bond length is 0.97 Å. The C(7)-H(3) bond length is 0.97 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(7) atom. The C(10)-N(2) bond length is 1.31 Å. The C(10)-H(7) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(4) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-N(2) bond length is 1.36 Å. The C(9)-N(4) bond length is 1.35 Å. In the tenth C site, C(11) is bonded in a 2-coordinate geometry to one N(4), one H(8), and one H(9) atom. The C(11)-N(4) bond length is 1.47 Å. The C(11)-H(8) bond length is 0.85 Å. The C(11)-H(9) bond length is 0.85 Å. In the eleventh C site, C(14) is bonded in a 3-coordinate geometry to one N(4) and two equivalent H(14,15) atoms. The C(14)-N(4) bond length is 1.46 Å. Both C(14)-H(14,15) bond lengths are 0.97 Å. In the twelfth C site, C(12) is bonded in a 3-coordinate geometry to one N(5) and two equivalent H(10,11) atoms. The C(12)-N(5) bond length is 1.48 Å. Both C(12)-H(10,11) bond lengths are 0.97 Å. In the thirteenth C site, C(13) is bonded in a 3-coordinate geometry to one N(5) and two equivalent H(12,13) atoms. The C(13)-N(5) bond length is 1.48 Å. Both C(13)-H(12,13) bond lengths are 0.97 Å. There are five inequivalent N sites. In the first N site, N(5) is bonded in a 1-coordinate geometry to one Cd(2), one C(12), one C(13), and one H(16) atom. The N(5)-H(16) bond length is 0.91 Å. In the second N site, N(1) is bonded in a bent 120 degrees geometry to one C(5) and one C(9) atom. In the third N site, N(2) is bonded in a bent 120 degrees geometry to one C(10) and one C(9) atom. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. In the fifth N site, N(4) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(9) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(14,15) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(10,11) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(12,13) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one N(5) atom. In the eighth H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(3) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(6) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(2) and one C(6) atom. Linkers: 8 CCn1cc(C([O])=O)c(=O)c2cnc(N3CCNCC3)nc21. Metal clusters: 4 [NH][Cd]([NH])(O[C]O[Cd][O])O[C]O[Cd][O]. The MOF has largest included sphere 7.06 A, density 1.09 g/cm3, surface area 3768.37 m2/g, accessible volume 0.47 cm3/g