(Zn4C31H15O13)3Zn8C174H90O25(C7H3)3 is Indium-derived structured and crystallizes in the trigonal P-31c space group. The structure is zero-dimensional and consists of two C7H3 clusters, two Zn4C31H15O13 clusters, and two Zn8C174H90O25 clusters. In each C7H3 cluster, there are six inequivalent C sites. In the first C site, C(35) is bonded in a distorted single-bond geometry to one C(44) and one H(17) atom. The C(35)-C(44) bond length is 1.35 Å. The C(35)-H(17) bond length is 0.96 Å. In the second C site, C(46) is bonded in a linear geometry to one C(45) and one C(47) atom. The C(46)-C(45) bond length is 1.21 Å. The C(46)-C(47) bond length is 1.46 Å. In the third C site, C(44) is bonded in a trigonal planar geometry to one C(45) and two equivalent C(35) atoms. The C(44)-C(45) bond length is 1.45 Å. In the fourth C site, C(45) is bonded in a linear geometry to one C(44) and one C(46) atom. In the fifth C site, C(47) is bonded in a trigonal planar geometry to one C(46) and two equivalent C(54) atoms. Both C(47)-C(54) bond lengths are 1.41 Å. In the sixth C site, C(54) is bonded in a distorted single-bond geometry to two equivalent C(47) and one H(24) atom. The C(54)-H(24) bond length is 0.98 Å. There are two inequivalent H sites. In the first H site, H(17) is bonded in a single-bond geometry to one C(35) atom. In the second H site, H(24) is bonded in a single-bond geometry to one C(54) atom. In each Zn4C31H15O13 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(11), one O(2), one O(3), and one O(7) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(11) bond length is 1.96 Å. The Zn(1)-O(2) bond length is 1.73 Å. The Zn(1)-O(3) bond length is 1.79 Å. The Zn(1)-O(7) bond length is 1.60 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(11), one O(4), and one O(8) atom to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(1) bond length is 1.68 Å. The Zn(2)-O(11) bond length is 1.95 Å. The Zn(2)-O(4) bond length is 1.75 Å. The Zn(2)-O(8) bond length is 1.67 Å. There are twenty inequivalent C sites. In the first C site, C(55) is bonded in a single-bond geometry to two equivalent C(53) and one H(25) atom. Both C(55)-C(53) bond lengths are 1.41 Å. The C(55)-H(25) bond length is 0.95 Å. In the second C site, C(42) is bonded in a bent 120 degrees geometry to one C(43) and two equivalent O(7) atoms. The C(42)-C(43) bond length is 1.50 Å. Both C(42)-O(7) bond lengths are 1.27 Å. In the third C site, C(43) is bonded in a trigonal planar geometry to one C(42) and two equivalent C(34) atoms. Both C(43)-C(34) bond lengths are 1.44 Å. In the fourth C site, C(48) is bonded in a bent 120 degrees geometry to one C(49) and two equivalent O(8) atoms. The C(48)-C(49) bond length is 1.50 Å. Both C(48)-O(8) bond lengths are 1.27 Å. In the fifth C site, C(49) is bonded in a trigonal planar geometry to one C(48) and two equivalent C(36) atoms. Both C(49)-C(36) bond lengths are 1.41 Å. In the sixth C site, C(50) is bonded in a trigonal planar geometry to one C(51) and two equivalent C(37) atoms. The C(50)-C(51) bond length is 1.45 Å. Both C(50)-C(37) bond lengths are 1.40 Å. In the seventh C site, C(51) is bonded in a linear geometry to one C(50) and one C(52) atom. The C(51)-C(52) bond length is 1.21 Å. In the eighth C site, C(52) is bonded in a linear geometry to one C(51) and one C(53) atom. The C(52)-C(53) bond length is 1.45 Å. In the ninth C site, C(53) is bonded in a trigonal planar geometry to one C(52) and two equivalent C(55) atoms. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(5) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-H(5) bond length is 0.96 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(15) atom. The C(12)-C(13) bond length is 1.41 Å. The C(12)-C(15) bond length is 1.50 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(6) atom. The C(13)-H(6) bond length is 0.95 Å. In the thirteenth C site, C(15) is bonded in a bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(15)-O(1) bond length is 1.27 Å. The C(15)-O(2) bond length is 1.27 Å. In the fourteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(9) atom. The C(20)-C(21) bond length is 1.41 Å. The C(20)-H(9) bond length is 0.96 Å. In the fifteenth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(21)-C(22) bond length is 1.41 Å. The C(21)-C(24) bond length is 1.50 Å. In the sixteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(10) atom. The C(22)-H(10) bond length is 0.96 Å. In the seventeenth C site, C(24) is bonded in a bent 120 degrees geometry to one C(21), one O(3), and one O(4) atom. The C(24)-O(3) bond length is 1.27 Å. The C(24)-O(4) bond length is 1.27 Å. In the eighteenth C site, C(34) is bonded in a distorted single-bond geometry to one C(43) and one H(16) atom. The C(34)-H(16) bond length is 0.96 Å. In the nineteenth C site, C(36) is bonded in a distorted single-bond geometry to one C(37), one C(49), and one H(18) atom. The C(36)-C(37) bond length is 1.41 Å. The C(36)-H(18) bond length is 0.98 Å. In the twentieth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(36), one C(50), and one H(19) atom. The C(37)-H(19) bond length is 0.95 Å. There are eight inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(20) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(22) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(34) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(36) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(37) atom. In the eighth H site, H(25) is bonded in a single-bond geometry to one C(55) atom. There are seven inequivalent O sites. In the first O site, O(11) is bonded in a tetrahedral geometry to two equivalent Zn(1) and two equivalent Zn(2) atoms. In the second O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(15) atom. In the third O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(15) atom. In the fourth O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(24) atom. In the fifth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(24) atom. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(42) atom. In the seventh O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(48) atom. In each Zn8C174H90O25 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(3) is bonded to one O(10), one O(12), one O(5), and one O(9) atom to form distorted corner-sharing ZnO4 tetrahedra. The Zn(3)-O(10) bond length is 1.76 Å. The Zn(3)-O(12) bond length is 1.85 Å. The Zn(3)-O(5) bond length is 1.75 Å. The Zn(3)-O(9) bond length is 1.77 Å. In the second Zn site, Zn(4) is bonded to one O(12) and three equivalent O(6) atoms to form distorted corner-sharing ZnO4 tetrahedra. The Zn(4)-O(12) bond length is 1.60 Å. All Zn(4)-O(6) bond lengths are 1.78 Å. There are twenty-nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-C(7) bond length is 1.45 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(1) bond length is 0.95 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(16), one C(2), and one C(4) atom. The C(3)-C(16) bond length is 1.46 Å. The C(3)-C(4) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(2) bond length is 0.96 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(25), one C(4), and one C(6) atom. The C(5)-C(25) bond length is 1.46 Å. The C(5)-C(6) bond length is 1.41 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(3) atom. The C(6)-H(3) bond length is 0.96 Å. In the seventh C site, C(7) is bonded in a linear geometry to one C(1) and one C(8) atom. The C(7)-C(8) bond length is 1.21 Å. In the eighth C site, C(8) is bonded in a linear geometry to one C(7) and one C(9) atom. The C(8)-C(9) bond length is 1.45 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.40 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(10)-H(4) bond length is 0.96 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(7) atom. The C(14)-H(7) bond length is 0.96 Å. In the twelfth C site, C(16) is bonded in a linear geometry to one C(17) and one C(3) atom. The C(16)-C(17) bond length is 1.22 Å. In the thirteenth C site, C(17) is bonded in a linear geometry to one C(16) and one C(18) atom. The C(17)-C(18) bond length is 1.46 Å. In the fourteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(23) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(23) bond length is 1.40 Å. In the fifteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(8) atom. The C(19)-H(8) bond length is 0.95 Å. In the sixteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(11) atom. The C(23)-H(11) bond length is 0.96 Å. In the seventeenth C site, C(25) is bonded in a linear geometry to one C(26) and one C(5) atom. The C(25)-C(26) bond length is 1.22 Å. In the eighteenth C site, C(26) is bonded in a linear geometry to one C(25) and one C(27) atom. The C(26)-C(27) bond length is 1.45 Å. In the nineteenth C site, C(27) is bonded in a 5-coordinate geometry to one C(26), one C(28), one C(32), one C(38), and one C(41) atom. The C(27)-C(28) bond length is 1.49 Å. The C(27)-C(32) bond length is 1.42 Å. The C(27)-C(38) bond length is 1.27 Å. The C(27)-C(41) bond length is 1.44 Å. In the twentieth C site, C(28) is bonded in a 4-coordinate geometry to one C(27), one C(29), one C(38), and one H(12) atom. The C(28)-C(29) bond length is 1.41 Å. The C(28)-C(38) bond length is 1.40 Å. The C(28)-H(12) bond length is 1.16 Å. In the twenty-first C site, C(29) is bonded in a 4-coordinate geometry to one C(28), one C(30), one C(39), and one H(13) atom. The C(29)-C(30) bond length is 1.49 Å. The C(29)-C(39) bond length is 1.46 Å. The C(29)-H(13) bond length is 1.13 Å. In the twenty-second C site, C(30) is bonded in a 5-coordinate geometry to one C(29), one C(31), one C(33), one C(39), and one C(40) atom. The C(30)-C(31) bond length is 1.24 Å. The C(30)-C(33) bond length is 1.50 Å. The C(30)-C(39) bond length is 1.36 Å. The C(30)-C(40) bond length is 1.59 Å. In the twenty-third C site, C(31) is bonded in a 1-coordinate geometry to one C(30) and one H(14) atom. The C(31)-H(14) bond length is 1.14 Å. In the twenty-fourth C site, C(32) is bonded in a distorted single-bond geometry to one C(27), one C(41), and one H(15) atom. The C(32)-C(41) bond length is 1.50 Å. The C(32)-H(15) bond length is 1.14 Å. In the twenty-fifth C site, C(33) is bonded in a 5-coordinate geometry to one C(30), one O(10), one O(5), one O(6), and one O(9) atom. The C(33)-O(10) bond length is 1.34 Å. The C(33)-O(5) bond length is 1.46 Å. The C(33)-O(6) bond length is 1.21 Å. The C(33)-O(9) bond length is 1.10 Å. In the twenty-sixth C site, C(38) is bonded in a 1-coordinate geometry to one C(27), one C(28), and one H(20) atom. The C(38)-H(20) bond length is 1.13 Å. In the twenty-seventh C site, C(39) is bonded in a distorted single-bond geometry to one C(29), one C(30), and one H(21) atom. The C(39)-H(21) bond length is 1.12 Å. In the twenty-eighth C site, C(40) is bonded in a distorted single-bond geometry to one C(30), one C(41), and one H(22) atom. The C(40)-C(41) bond length is 1.40 Å. The C(40)-H(22) bond length is 1.15 Å. In the twenty-ninth C site, C(41) is bonded in a 4-coordinate geometry to one C(27), one C(32), one C(40), and one H(23) atom. The C(41)-H(23) bond length is 1.15 Å. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(23) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(28) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(29) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(31) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(32) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(38) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(39) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(40) atom. In the fifteenth H site, H(23) is bonded in a single-bond geometry to one C(41) atom. There are five inequivalent O sites. In the first O site, O(12) is bonded in a distorted body-centered cubic geometry to two equivalent Zn(4) and six equivalent Zn(3) atoms. In the second O site, O(5) is bonded in a 2-coordinate geometry to one Zn(3) and one C(33) atom. In the third O site, O(6) is bonded in a 2-coordinate geometry to one Zn(4) and one C(33) atom. In the fourth O site, O(9) is bonded in a 2-coordinate geometry to one Zn(3) and one C(33) atom. In the fifth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(33) atom. Linkers: 4 [O]C(=O)c1ccc(C#Cc2cc(C#Cc3ccc(C([O])=O)cc3)cc(C#Cc3ccc(C([O])=O)cc3)c2)cc1 ,5 [O]C(=O)c1ccc(C#Cc2cc(C#Cc3ccc(C([O])=O)cc3)cc(C#C[C@@]34[C@@H]5[C@@H]([CH][C@@H]53)[C]3[C@H]5[C@@H]3[CH][C@H]54)c2)cc1.[O]C1([O])OO1 ,4 [O]C(=O)c1ccc(C#Cc2cc(C#Cc3ccc(C([O])=O)cc3)cc(C#C[C@]34[C@H]5[C@H]([CH][C@H]53)[C]3[C@@H]5[C@H]3[CH][C@@H]54)c2)cc1.[O]C1([O])OO1 ,2 [O]C(=O)c1ccc(C#Cc2cc(C#Cc3ccc(C([O])=O)cc3)cc(C#C[C@]34[C@@H]5[C@H]3[C@H]3[C@@H]5[C@@]35[C@@H]3[C@H]5[CH][C@@H]34)c2)cc1.[O]C1([O])OO1 ,1 [O]C(=O)c1ccc(C#Cc2cc(C#Cc3ccc(C([O])=O)cc3)cc(C#C[C@]34[C@@H]5[C@H]3[C@H]3[C@@H]5[C@@]35[C@@H]3[C@H]4[CH][C@@H]35)c2)cc1.[O]C1([O])OO1. Metal clusters: 6 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4 ,1 O1OO[Zn@]23OOOO[Zn](O1)[Zn@]14OOOO[Zn@]5(OOOO1)[Zn]1O[Zn@@]42[Zn@@]52OOOO[Zn@@]13OOOO2 ,1 O1OO[Zn@]23OOOO[Zn](O1)[Zn@@]14OOOO[Zn@]5(OOOO1)[Zn]1OOOO[Zn@@]2(OOOO1)[Zn]5O[Zn]43. The MOF has largest included sphere 15.41 A, density 0.29 g/cm3, surface area 4209.98 m2/g, accessible volume 2.84 cm3/g