(CdC22N5H18S2)2SC6H4 is Indium-derived structured and crystallizes in the tetragonal P4_12_12 space group. The structure is zero-dimensional and consists of four dii-propenyl sulfide molecules and eight CdC22N5H18S2 clusters. In each CdC22N5H18S2 cluster, Cd(1) is bonded in a square pyramidal geometry to one N(1), one N(2), one N(3), one N(4), and one N(5) atom. The Cd(1)-N(1) bond length is 2.34 Å. The Cd(1)-N(2) bond length is 2.35 Å. The Cd(1)-N(3) bond length is 2.41 Å. The Cd(1)-N(4) bond length is 2.38 Å. The Cd(1)-N(5) bond length is 2.29 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(2), and one H(5) atom. The C(6)-C(7) bond length is 1.37 Å. The C(6)-N(2) bond length is 1.34 Å. The C(6)-H(5) bond length is 0.95 Å. In the fourth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(6) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(6) bond length is 0.95 Å. In the fifth C site, C(8) is bonded in a trigonal planar geometry to one C(7), one C(9), and one S(1) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-S(1) bond length is 1.77 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 0.95 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(10)-N(2) bond length is 1.33 Å. The C(10)-H(8) bond length is 0.95 Å. In the eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(11)-N(3) bond length is 1.34 Å. The C(11)-H(9) bond length is 0.95 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-H(10) bond length is 0.95 Å. In the tenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one S(1) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-S(1) bond length is 1.76 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(14)-H(11) bond length is 0.95 Å. In the twelfth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(12) atom. The C(15)-N(3) bond length is 1.35 Å. The C(15)-H(12) bond length is 0.95 Å. In the thirteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one N(4), and one H(13) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-N(4) bond length is 1.34 Å. The C(16)-H(13) bond length is 0.95 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(14) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(14) bond length is 0.95 Å. In the fifteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one S(2) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-S(2) bond length is 1.77 Å. In the sixteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(15) atom. The C(19)-H(15) bond length is 0.95 Å. In the seventeenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(16) atom. The C(20)-N(4) bond length is 1.34 Å. The C(20)-H(16) bond length is 0.95 Å. In the eighteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(17) atom. The C(21)-N(5) bond length is 1.35 Å. The C(21)-H(17) bond length is 0.95 Å. In the nineteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(18,19) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-H(18,19) bond length is 0.95 Å. In the twentieth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one S(2) atom. The C(23)-C(24) bond length is 1.38 Å. The C(23)-S(2) bond length is 1.76 Å. In the twenty-first C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(18,19) atom. The C(24)-H(18,19) bond length is 0.95 Å. In the twenty-second C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(20) atom. The C(25)-N(5) bond length is 1.34 Å. The C(25)-H(20) bond length is 0.95 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(15) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(16), and one C(20) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cd(1), one C(21), and one C(25) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the sixteenth H site, H(18,19) is bonded in a single-bond geometry to one C(22) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(13) and one C(8) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(18) and one C(23) atom. Linkers: 19 c1cc(Sc2ccncc2)ccn1. Metal clusters: 8 [Cd]. The MOF has largest included sphere 5.45 A, density 0.95 g/cm3, surface area 4621.72 m2/g, accessible volume 0.58 cm3/g