AgC30H36(NS)4 crystallizes in the tetragonal I-42d space group. Ag(1) is bonded in a distorted linear geometry to two equivalent N(2) and two equivalent S(1) atoms. Both Ag(1)-N(2) bond lengths are 2.15 Å. Both Ag(1)-S(1) bond lengths are 3.03 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-S(1) bond length is 1.77 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one S(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-S(2) bond length is 1.76 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one S(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-S(1) bond length is 1.77 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(1) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(1) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(12), one C(4), and one C(6) atom. The C(5)-C(12) bond length is 1.53 Å. The C(5)-C(6) bond length is 1.39 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(2) atom. The C(6)-H(2) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a water-like geometry to two equivalent H(3,4) and one S(2) atom. Both C(7)-H(3,4) bond lengths are 0.99 Å. The C(7)-S(2) bond length is 1.82 Å. In the eighth C site, C(8) is bonded in a 3-coordinate geometry to one N(1) and two equivalent H(5,6) atoms. The C(8)-N(1) bond length is 1.47 Å. Both C(8)-H(5,6) bond lengths are 0.99 Å. In the ninth C site, C(9) is bonded in a 3-coordinate geometry to one C(10), one N(2), and one H(7) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-N(2) bond length is 1.32 Å. The C(9)-H(7) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(8) atom. The C(10)-C(11) bond length is 1.37 Å. The C(10)-H(8) bond length is 0.95 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(9) atom. The C(11)-N(1) bond length is 1.33 Å. The C(11)-H(9) bond length is 0.95 Å. In the twelfth C site, C(12) is bonded in a tetrahedral geometry to one C(13), one C(14), one C(15), and one C(5) atom. The C(12)-C(13) bond length is 1.53 Å. The C(12)-C(14) bond length is 1.55 Å. The C(12)-C(15) bond length is 1.53 Å. In the thirteenth C site, C(13) is bonded in a trigonal non-coplanar geometry to one C(12); one H(11,18); and two equivalent H(10,12,13,14,15,16,17) atoms. The C(13)-H(11,18) bond length is 0.98 Å. Both C(13)-H(10,12,13,14,15,16,17) bond lengths are 0.98 Å. In the fourteenth C site, C(14) is bonded in a trigonal non-coplanar geometry to one C(12) and three equivalent H(10,12,13,14,15,16,17) atoms. All C(14)-H(10,12,13,14,15,16,17) bond lengths are 0.98 Å. In the fifteenth C site, C(15) is bonded in a trigonal non-coplanar geometry to one C(12); one H(11,18); and two equivalent H(10,12,13,14,15,16,17) atoms. The C(15)-H(11,18) bond length is 0.98 Å. Both C(15)-H(10,12,13,14,15,16,17) bond lengths are 0.98 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one C(11), one C(8), and one N(2) atom. The N(1)-N(2) bond length is 1.35 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(9), and one N(1) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10,12,13,14,15,16,17) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(11,18) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one C(1), and one C(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(2) and one C(7) atom. Linkers: 6 CC(C)(C)c1cc2c(SCCn3cccn3)c(c1)Sc1cc(C(C)(C)C)cc(c1SCCn1cccn1)Sc1cc(C(C)(C)C)cc(c1SCCn1cccn1)Sc1cc(C(C)(C)C)cc(c1SCCn1cccn1)S2. Metal clusters: 8 [Ag]. The MOF has largest included sphere 4.75 A, density 1.14 g/cm3, surface area 4839.63 m2/g, accessible volume 0.40 cm3/g