CuH10(C11O2)2 crystallizes in the monoclinic C2/m space group. The structure consists of a CuH10(C11O2)2 framework. There are seven inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(13), one O(19), one O(3), and one O(5) atom. The Cu(1)-O(13) bond length is 2.00 Å. The Cu(1)-O(19) bond length is 2.01 Å. The Cu(1)-O(3) bond length is 1.94 Å. The Cu(1)-O(5) bond length is 1.90 Å. In the second Cu site, Cu(2) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(17), one O(2), and one O(23) atom. The Cu(2)-O(10) bond length is 1.97 Å. The Cu(2)-O(17) bond length is 1.96 Å. The Cu(2)-O(2) bond length is 1.94 Å. The Cu(2)-O(23) bond length is 1.95 Å. In the third Cu site, Cu(3) is bonded in a distorted square co-planar geometry to two equivalent O(12) and two equivalent O(9) atoms. Both Cu(3)-O(12) bond lengths are 1.97 Å. Both Cu(3)-O(9) bond lengths are 1.98 Å. In the fourth Cu site, Cu(4) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(20) atoms. Both Cu(4)-O(1) bond lengths are 1.99 Å. Both Cu(4)-O(20) bond lengths are 1.93 Å. In the fifth Cu site, Cu(5) is bonded in a distorted square co-planar geometry to one O(11), one O(14), one O(16), and one O(22) atom. The Cu(5)-O(11) bond length is 1.95 Å. The Cu(5)-O(14) bond length is 1.96 Å. The Cu(5)-O(16) bond length is 1.91 Å. The Cu(5)-O(22) bond length is 1.98 Å. In the sixth Cu site, Cu(6) is bonded in a distorted rectangular see-saw-like geometry to one O(18), one O(21), one O(4), and one O(6) atom. The Cu(6)-O(18) bond length is 1.95 Å. The Cu(6)-O(21) bond length is 1.99 Å. The Cu(6)-O(4) bond length is 1.95 Å. The Cu(6)-O(6) bond length is 1.99 Å. In the seventh Cu site, Cu(7) is bonded in a distorted rectangular see-saw-like geometry to one O(15), one O(24), one O(7), and one O(8) atom. The Cu(7)-O(15) bond length is 1.95 Å. The Cu(7)-O(24) bond length is 1.89 Å. The Cu(7)-O(7) bond length is 1.96 Å. The Cu(7)-O(8) bond length is 1.94 Å. There are one hundred and forty-six inequivalent C sites. In the first C site, C(76) is bonded in a trigonal planar geometry to one C(111), one C(126), and one C(18) atom. The C(76)-C(111) bond length is 1.43 Å. The C(76)-C(126) bond length is 1.39 Å. The C(76)-C(18) bond length is 1.39 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one C(127), one C(55), and one C(82) atom. The C(1)-C(127) bond length is 1.39 Å. The C(1)-C(55) bond length is 1.40 Å. The C(1)-C(82) bond length is 1.39 Å. In the third C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(69) and two equivalent C(109) atoms. The C(2)-C(69) bond length is 1.35 Å. Both C(2)-C(109) bond lengths are 1.40 Å. In the fourth C site, C(3) is bonded in a distorted single-bond geometry to one C(13), one C(56), and one H(48) atom. The C(3)-C(13) bond length is 1.39 Å. The C(3)-C(56) bond length is 1.39 Å. The C(3)-H(48) bond length is 0.94 Å. In the fifth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(133), one C(32), and one H(3) atom. The C(4)-C(133) bond length is 1.39 Å. The C(4)-C(32) bond length is 1.39 Å. The C(4)-H(3) bond length is 0.94 Å. In the sixth C site, C(5) is bonded in a distorted linear geometry to one C(124) and one C(44) atom. The C(5)-C(124) bond length is 1.30 Å. The C(5)-C(44) bond length is 1.06 Å. In the seventh C site, C(6) is bonded in a trigonal planar geometry to one C(102), one C(37), and one C(39) atom. The C(6)-C(102) bond length is 1.39 Å. The C(6)-C(37) bond length is 1.51 Å. The C(6)-C(39) bond length is 1.39 Å. In the eighth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(52), one C(59), and one H(49) atom. The C(7)-C(52) bond length is 1.39 Å. The C(7)-C(59) bond length is 1.39 Å. The C(7)-H(49) bond length is 0.94 Å. In the ninth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(143), one C(83), and one H(43) atom. The C(8)-C(143) bond length is 1.42 Å. The C(8)-C(83) bond length is 1.35 Å. The C(8)-H(43) bond length is 0.94 Å. In the tenth C site, C(9) is bonded in a trigonal planar geometry to one C(144) and two equivalent C(96) atoms. The C(9)-C(144) bond length is 1.49 Å. Both C(9)-C(96) bond lengths are 1.36 Å. In the eleventh C site, C(10) is bonded in a linear geometry to one C(134) and one C(30) atom. The C(10)-C(134) bond length is 1.47 Å. The C(10)-C(30) bond length is 1.20 Å. In the twelfth C site, C(11) is bonded in a distorted linear geometry to one C(119) and one C(129) atom. The C(11)-C(119) bond length is 1.44 Å. The C(11)-C(129) bond length is 1.18 Å. In the thirteenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(109), one C(145), and one C(15) atom. The C(12)-C(109) bond length is 1.36 Å. The C(12)-C(145) bond length is 1.44 Å. The C(12)-C(15) bond length is 1.53 Å. In the fourteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(3), one C(52), and one H(51) atom. The C(13)-C(52) bond length is 1.39 Å. The C(13)-H(51) bond length is 0.94 Å. In the fifteenth C site, C(14) is bonded in a trigonal planar geometry to one C(40) and two equivalent C(83) atoms. The C(14)-C(40) bond length is 1.55 Å. Both C(14)-C(83) bond lengths are 1.40 Å. In the sixteenth C site, C(15) is bonded in a linear geometry to one C(113) and one C(12) atom. The C(15)-C(113) bond length is 1.15 Å. In the seventeenth C site, C(16) is bonded in a linear geometry to one C(70) and one C(77) atom. The C(16)-C(70) bond length is 1.45 Å. The C(16)-C(77) bond length is 1.19 Å. In the eighteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(112), one C(29), and one H(37) atom. The C(17)-C(112) bond length is 1.39 Å. The C(17)-C(29) bond length is 1.39 Å. The C(17)-H(37) bond length is 0.94 Å. In the nineteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(76), one C(91), and one H(34) atom. The C(18)-C(91) bond length is 1.39 Å. The C(18)-H(34) bond length is 0.94 Å. In the twentieth C site, C(19) is bonded in a bent 120 degrees geometry to one C(23), one O(24), and one O(3) atom. The C(19)-C(23) bond length is 1.45 Å. The C(19)-O(24) bond length is 1.25 Å. The C(19)-O(3) bond length is 1.33 Å. In the twenty-first C site, C(20) is bonded in a trigonal planar geometry to one C(107), one C(27), and one C(89) atom. The C(20)-C(107) bond length is 1.41 Å. The C(20)-C(27) bond length is 1.39 Å. The C(20)-C(89) bond length is 1.39 Å. In the twenty-second C site, C(21) is bonded in a distorted trigonal planar geometry to one C(81), one C(96), and one H(27) atom. The C(21)-C(81) bond length is 1.41 Å. The C(21)-C(96) bond length is 1.35 Å. The C(21)-H(27) bond length is 0.94 Å. In the twenty-third C site, C(22) is bonded in a trigonal planar geometry to one C(75) and two equivalent C(41) atoms. The C(22)-C(75) bond length is 1.51 Å. Both C(22)-C(41) bond lengths are 1.38 Å. In the twenty-fourth C site, C(23) is bonded in a trigonal planar geometry to one C(19), one C(24), and one C(78) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-C(78) bond length is 1.39 Å. In the twenty-fifth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(71), and one H(35) atom. The C(24)-C(71) bond length is 1.39 Å. The C(24)-H(35) bond length is 0.94 Å. In the twenty-sixth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(18), and one O(2) atom. The C(25)-C(29) bond length is 1.53 Å. The C(25)-O(18) bond length is 1.28 Å. The C(25)-O(2) bond length is 1.25 Å. In the twenty-seventh C site, C(26) is bonded in a distorted single-bond geometry to one C(32), one C(63), and one H(56) atom. The C(26)-C(32) bond length is 1.39 Å. The C(26)-C(63) bond length is 1.39 Å. The C(26)-H(56) bond length is 0.94 Å. In the twenty-eighth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(102), one C(20), and one H(44) atom. The C(27)-C(102) bond length is 1.39 Å. The C(27)-H(44) bond length is 0.94 Å. In the twenty-ninth C site, C(28) is bonded in a bent 120 degrees geometry to one C(58), one O(13), and one O(8) atom. The C(28)-C(58) bond length is 1.52 Å. The C(28)-O(13) bond length is 1.33 Å. The C(28)-O(8) bond length is 1.19 Å. In the thirtieth C site, C(29) is bonded in a trigonal planar geometry to one C(17), one C(25), and one C(94) atom. The C(29)-C(94) bond length is 1.39 Å. In the thirty-first C site, C(30) is bonded in a distorted linear geometry to one C(10) and one C(32) atom. The C(30)-C(32) bond length is 1.41 Å. In the thirty-second C site, C(31) is bonded in a distorted trigonal planar geometry to one C(132), one C(98), and one H(39) atom. The C(31)-C(132) bond length is 1.39 Å. The C(31)-C(98) bond length is 1.39 Å. The C(31)-H(39) bond length is 0.94 Å. In the thirty-third C site, C(32) is bonded in a trigonal planar geometry to one C(26), one C(30), and one C(4) atom. In the thirty-fourth C site, C(51) is bonded in a linear geometry to one C(111) and one C(33) atom. The C(51)-C(111) bond length is 1.21 Å. The C(51)-C(33) bond length is 1.46 Å. In the thirty-fifth C site, C(55) is bonded in a linear geometry to one C(1) and one C(99) atom. The C(55)-C(99) bond length is 1.17 Å. In the thirty-sixth C site, C(60) is bonded in a distorted trigonal planar geometry to one C(130), one C(140), and one C(64) atom. The C(60)-C(130) bond length is 1.33 Å. The C(60)-C(140) bond length is 1.48 Å. The C(60)-C(64) bond length is 1.39 Å. In the thirty-seventh C site, C(61) is bonded in a distorted single-bond geometry to one C(114), one C(137), and one H(21) atom. The C(61)-C(114) bond length is 1.39 Å. The C(61)-C(137) bond length is 1.39 Å. The C(61)-H(21) bond length is 0.94 Å. In the thirty-eighth C site, C(63) is bonded in a trigonal planar geometry to one C(141), one C(26), and one C(86) atom. The C(63)-C(141) bond length is 1.41 Å. The C(63)-C(86) bond length is 1.39 Å. In the thirty-ninth C site, C(64) is bonded in a linear geometry to one C(48) and one C(60) atom. The C(64)-C(48) bond length is 1.23 Å. In the fortieth C site, C(65) is bonded in a trigonal planar geometry to one C(120), one C(34), and one C(99) atom. The C(65)-C(120) bond length is 1.39 Å. The C(65)-C(34) bond length is 1.39 Å. The C(65)-C(99) bond length is 1.45 Å. In the forty-first C site, C(66) is bonded in a distorted bent 120 degrees geometry to one C(56), one O(17), and one O(6) atom. The C(66)-C(56) bond length is 1.44 Å. The C(66)-O(17) bond length is 1.23 Å. The C(66)-O(6) bond length is 1.26 Å. In the forty-second C site, C(67) is bonded in a bent 120 degrees geometry to one C(97), one O(1), and one O(9) atom. The C(67)-C(97) bond length is 1.43 Å. The C(67)-O(1) bond length is 1.24 Å. The C(67)-O(9) bond length is 1.27 Å. In the forty-third C site, C(68) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(12), and one O(20) atom. The C(68)-C(35) bond length is 1.48 Å. The C(68)-O(12) bond length is 1.25 Å. The C(68)-O(20) bond length is 1.27 Å. In the forty-fourth C site, C(71) is bonded in a distorted trigonal planar geometry to one C(117), one C(24), and one H(33) atom. The C(71)-C(117) bond length is 1.39 Å. The C(71)-H(33) bond length is 0.94 Å. In the forty-fifth C site, C(73) is bonded in a distorted trigonal planar geometry to one C(134), one C(94), and one H(45) atom. The C(73)-C(134) bond length is 1.39 Å. The C(73)-C(94) bond length is 1.39 Å. The C(73)-H(45) bond length is 0.94 Å. In the forty-sixth C site, C(74) is bonded in a distorted bent 120 degrees geometry to one C(136) and two equivalent O(14) atoms. The C(74)-C(136) bond length is 1.54 Å. Both C(74)-O(14) bond lengths are 1.26 Å. In the forty-seventh C site, C(75) is bonded in a distorted linear geometry to one C(103) and one C(22) atom. The C(75)-C(103) bond length is 1.08 Å. In the forty-eighth C site, C(77) is bonded in a linear geometry to one C(16) and one C(85) atom. The C(77)-C(85) bond length is 1.48 Å. In the forty-ninth C site, C(78) is bonded in a distorted single-bond geometry to one C(106), one C(23), and one H(17) atom. The C(78)-C(106) bond length is 1.39 Å. The C(78)-H(17) bond length is 0.94 Å. In the fiftieth C site, C(79) is bonded in a linear geometry to one C(143) and one C(69) atom. The C(79)-C(143) bond length is 1.52 Å. The C(79)-C(69) bond length is 1.28 Å. In the fifty-first C site, C(80) is bonded in a linear geometry to one C(110) and one C(117) atom. The C(80)-C(110) bond length is 1.31 Å. The C(80)-C(117) bond length is 1.48 Å. In the fifty-second C site, C(81) is bonded in a trigonal planar geometry to one C(44) and two equivalent C(21) atoms. The C(81)-C(44) bond length is 1.41 Å. In the fifty-third C site, C(82) is bonded in a distorted single-bond geometry to one C(1), one C(119), and one H(15) atom. The C(82)-C(119) bond length is 1.39 Å. The C(82)-H(15) bond length is 0.94 Å. In the fifty-fourth C site, C(84) is bonded in a distorted bent 120 degrees geometry to one C(87), one O(10), and one O(21) atom. The C(84)-C(87) bond length is 1.55 Å. The C(84)-O(10) bond length is 1.25 Å. The C(84)-O(21) bond length is 1.28 Å. In the fifty-fifth C site, C(87) is bonded in a trigonal planar geometry to one C(84), one C(88), and one C(91) atom. The C(87)-C(88) bond length is 1.39 Å. The C(87)-C(91) bond length is 1.39 Å. In the fifty-sixth C site, C(88) is bonded in a distorted single-bond geometry to one C(87) and one H(2) atom. The C(88)-H(2) bond length is 0.94 Å. In the fifty-seventh C site, C(89) is bonded in a single-bond geometry to one C(20) and one H(60) atom. The C(89)-H(60) bond length is 0.94 Å. In the fifty-eighth C site, C(90) is bonded in a distorted single-bond geometry to one C(34), one C(97), and one H(8) atom. The C(90)-C(34) bond length is 1.39 Å. The C(90)-C(97) bond length is 1.39 Å. The C(90)-H(8) bond length is 0.94 Å. In the fifty-ninth C site, C(91) is bonded in a distorted single-bond geometry to one C(18), one C(87), and one H(1) atom. The C(91)-H(1) bond length is 0.94 Å. In the sixtieth C site, C(92) is bonded in a distorted single-bond geometry to one C(131) and one H(14) atom. The C(92)-C(131) bond length is 1.39 Å. The C(92)-H(14) bond length is 0.94 Å. In the sixty-first C site, C(93) is bonded in a linear geometry to one C(135) and one C(142) atom. The C(93)-C(135) bond length is 1.33 Å. The C(93)-C(142) bond length is 1.12 Å. In the sixty-second C site, C(94) is bonded in a distorted single-bond geometry to one C(29), one C(73), and one H(12) atom. The C(94)-H(12) bond length is 0.94 Å. In the sixty-third C site, C(95) is bonded in a distorted single-bond geometry to one C(100), one C(125), and one H(19) atom. The C(95)-C(100) bond length is 1.48 Å. The C(95)-C(125) bond length is 1.36 Å. The C(95)-H(19) bond length is 0.94 Å. In the sixty-fourth C site, C(96) is bonded in a distorted single-bond geometry to one C(21), one C(9), and one H(53) atom. The C(96)-H(53) bond length is 0.94 Å. In the sixty-fifth C site, C(97) is bonded in a trigonal planar geometry to one C(54), one C(67), and one C(90) atom. The C(97)-C(54) bond length is 1.39 Å. In the sixty-sixth C site, C(98) is bonded in a distorted single-bond geometry to one C(31), one C(58), and one H(32) atom. The C(98)-C(58) bond length is 1.39 Å. The C(98)-H(32) bond length is 0.94 Å. In the sixty-seventh C site, C(99) is bonded in a linear geometry to one C(55) and one C(65) atom. In the sixty-eighth C site, C(100) is bonded in a distorted single-bond geometry to one C(146), one C(95), and one H(16) atom. The C(100)-C(146) bond length is 1.36 Å. The C(100)-H(16) bond length is 0.94 Å. In the sixty-ninth C site, C(101) is bonded in a trigonal planar geometry to one C(110), one C(127), and one C(47) atom. The C(101)-C(110) bond length is 1.37 Å. The C(101)-C(127) bond length is 1.39 Å. The C(101)-C(47) bond length is 1.39 Å. In the seventieth C site, C(102) is bonded in a distorted single-bond geometry to one C(27), one C(6), and one H(61) atom. The C(102)-H(61) bond length is 0.94 Å. In the seventy-first C site, C(103) is bonded in a linear geometry to one C(138) and one C(75) atom. The C(103)-C(138) bond length is 1.41 Å. In the seventy-second C site, C(104) is bonded in a distorted single-bond geometry to one C(122), one C(58), and one H(42) atom. The C(104)-C(122) bond length is 1.39 Å. The C(104)-C(58) bond length is 1.39 Å. The C(104)-H(42) bond length is 0.94 Å. In the seventy-third C site, C(105) is bonded in a distorted single-bond geometry to two equivalent C(33) and one H(46) atom. Both C(105)-C(33) bond lengths are 1.41 Å. The C(105)-H(46) bond length is 0.94 Å. In the seventy-fourth C site, C(106) is bonded in a distorted trigonal planar geometry to one C(117), one C(78), and one H(11) atom. The C(106)-C(117) bond length is 1.39 Å. The C(106)-H(11) bond length is 0.94 Å. In the seventy-fifth C site, C(107) is bonded in a linear geometry to one C(128) and one C(20) atom. The C(107)-C(128) bond length is 1.20 Å. In the seventy-sixth C site, C(108) is bonded in a distorted single-bond geometry to one C(115) and one H(10) atom. The C(108)-C(115) bond length is 1.39 Å. The C(108)-H(10) bond length is 0.94 Å. In the seventy-seventh C site, C(109) is bonded in a distorted trigonal planar geometry to one C(12), one C(2), and one H(4) atom. The C(109)-H(4) bond length is 0.94 Å. In the seventy-eighth C site, C(110) is bonded in a linear geometry to one C(101) and one C(80) atom. In the seventy-ninth C site, C(111) is bonded in a linear geometry to one C(51) and one C(76) atom. In the eightieth C site, C(112) is bonded in a distorted trigonal planar geometry to one C(134), one C(17), and one H(20) atom. The C(112)-C(134) bond length is 1.39 Å. The C(112)-H(20) bond length is 0.94 Å. In the eighty-first C site, C(113) is bonded in a linear geometry to one C(132) and one C(15) atom. The C(113)-C(132) bond length is 1.40 Å. In the eighty-second C site, C(114) is bonded in a trigonal planar geometry to one C(118), one C(50), and one C(61) atom. The C(114)-C(118) bond length is 1.39 Å. The C(114)-C(50) bond length is 1.58 Å. In the eighty-third C site, C(115) is bonded in a trigonal planar geometry to one C(108), one C(139), and one C(36) atom. The C(115)-C(139) bond length is 1.50 Å. The C(115)-C(36) bond length is 1.39 Å. In the eighty-fourth C site, C(116) is bonded in a distorted trigonal planar geometry to one C(118), one C(38), and one H(47) atom. The C(116)-C(118) bond length is 1.39 Å. The C(116)-C(38) bond length is 1.39 Å. The C(116)-H(47) bond length is 0.94 Å. In the eighty-fifth C site, C(117) is bonded in a trigonal planar geometry to one C(106), one C(71), and one C(80) atom. In the eighty-sixth C site, C(118) is bonded in a distorted single-bond geometry to one C(114), one C(116), and one H(54) atom. The C(118)-H(54) bond length is 0.94 Å. In the eighty-seventh C site, C(119) is bonded in a trigonal planar geometry to one C(11), one C(47), and one C(82) atom. The C(119)-C(47) bond length is 1.39 Å. In the eighty-eighth C site, C(120) is bonded in a distorted trigonal planar geometry to one C(54), one C(65), and one H(59) atom. The C(120)-C(54) bond length is 1.39 Å. The C(120)-H(59) bond length is 0.94 Å. In the eighty-ninth C site, C(121) is bonded in a distorted trigonal planar geometry to one C(62), one C(85), and one H(24) atom. The C(121)-C(62) bond length is 1.39 Å. The C(121)-C(85) bond length is 1.39 Å. The C(121)-H(24) bond length is 0.94 Å. In the ninetieth C site, C(122) is bonded in a distorted trigonal planar geometry to one C(104), one C(132), and one H(25) atom. The C(122)-C(132) bond length is 1.39 Å. The C(122)-H(25) bond length is 0.94 Å. In the ninety-first C site, C(123) is bonded in a distorted bent 120 degrees geometry to one C(131), one O(19), and one O(7) atom. The C(123)-C(131) bond length is 1.49 Å. The C(123)-O(19) bond length is 1.27 Å. The C(123)-O(7) bond length is 1.22 Å. In the ninety-second C site, C(124) is bonded in a trigonal planar geometry to one C(5) and two equivalent C(72) atoms. Both C(124)-C(72) bond lengths are 1.43 Å. In the ninety-third C site, C(125) is bonded in a trigonal planar geometry to one C(49) and two equivalent C(95) atoms. The C(125)-C(49) bond length is 1.47 Å. In the ninety-fourth C site, C(126) is bonded in a distorted single-bond geometry to one C(76) and one H(31) atom. The C(126)-H(31) bond length is 0.94 Å. In the ninety-fifth C site, C(127) is bonded in a distorted single-bond geometry to one C(1), one C(101), and one H(58) atom. The C(127)-H(58) bond length is 0.94 Å. In the ninety-sixth C site, C(128) is bonded in a linear geometry to one C(107) and one C(133) atom. The C(128)-C(133) bond length is 1.48 Å. In the ninety-seventh C site, C(129) is bonded in a single-bond geometry to one C(11) and one C(38) atom. The C(129)-C(38) bond length is 1.44 Å. In the ninety-eighth C site, C(130) is bonded in a distorted trigonal planar geometry to one C(135), one C(60), and one H(40) atom. The C(130)-C(135) bond length is 1.34 Å. The C(130)-H(40) bond length is 0.94 Å. In the ninety-ninth C site, C(131) is bonded in a trigonal planar geometry to one C(123), one C(62), and one C(92) atom. The C(131)-C(62) bond length is 1.39 Å. In the one hundredth C site, C(132) is bonded in a trigonal planar geometry to one C(113), one C(122), and one C(31) atom. In the one hundred and first C site, C(133) is bonded in a trigonal planar geometry to one C(128), one C(4), and one C(86) atom. The C(133)-C(86) bond length is 1.39 Å. In the one hundred and second C site, C(134) is bonded in a trigonal planar geometry to one C(10), one C(112), and one C(73) atom. In the one hundred and third C site, C(135) is bonded in a trigonal planar geometry to one C(93) and two equivalent C(130) atoms. In the one hundred and fourth C site, C(136) is bonded in a trigonal planar geometry to one C(74) and two equivalent C(53) atoms. Both C(136)-C(53) bond lengths are 1.38 Å. In the one hundred and fifth C site, C(137) is bonded in a distorted trigonal planar geometry to one C(38), one C(61), and one H(28) atom. The C(137)-C(38) bond length is 1.39 Å. The C(137)-H(28) bond length is 0.94 Å. In the one hundred and sixth C site, C(138) is bonded in a trigonal planar geometry to one C(103) and two equivalent C(46) atoms. Both C(138)-C(46) bond lengths are 1.44 Å. In the one hundred and seventh C site, C(139) is bonded in a linear geometry to one C(115) and one C(141) atom. The C(139)-C(141) bond length is 1.16 Å. In the one hundred and eighth C site, C(140) is bonded in a trigonal planar geometry to two equivalent C(60) and one H(57) atom. The C(140)-H(57) bond length is 0.94 Å. In the one hundred and ninth C site, C(141) is bonded in a linear geometry to one C(139) and one C(63) atom. In the one hundred and tenth C site, C(83) is bonded in a distorted single-bond geometry to one C(14), one C(8), and one H(50) atom. The C(83)-H(50) bond length is 0.94 Å. In the one hundred and eleventh C site, C(142) is bonded in a linear geometry to one C(146) and one C(93) atom. The C(142)-C(146) bond length is 1.48 Å. In the one hundred and twelfth C site, C(143) is bonded in a trigonal planar geometry to one C(79) and two equivalent C(8) atoms. In the one hundred and thirteenth C site, C(144) is bonded in a bent 120 degrees geometry to one C(9) and two equivalent O(22) atoms. Both C(144)-O(22) bond lengths are 1.30 Å. In the one hundred and fourteenth C site, C(145) is bonded in a trigonal planar geometry to two equivalent C(12) and one H(26) atom. The C(145)-H(26) bond length is 0.94 Å. In the one hundred and fifteenth C site, C(33) is bonded in a trigonal planar geometry to one C(105), one C(51), and one C(72) atom. The C(33)-C(72) bond length is 1.39 Å. In the one hundred and sixteenth C site, C(146) is bonded in a trigonal planar geometry to one C(142) and two equivalent C(100) atoms. In the one hundred and seventeenth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(65), one C(90), and one H(38) atom. The C(34)-H(38) bond length is 0.94 Å. In the one hundred and eighteenth C site, C(35) is bonded in a trigonal planar geometry to one C(45), one C(57), and one C(68) atom. The C(35)-C(45) bond length is 1.39 Å. The C(35)-C(57) bond length is 1.39 Å. In the one hundred and nineteenth C site, C(36) is bonded in a single-bond geometry to one C(115) and one H(36) atom. The C(36)-H(36) bond length is 0.94 Å. In the one hundred and twentieth C site, C(37) is bonded in a bent 120 degrees geometry to one C(6), one O(15), and one O(5) atom. The C(37)-O(15) bond length is 1.28 Å. The C(37)-O(5) bond length is 1.30 Å. In the one hundred and twenty-first C site, C(85) is bonded in a trigonal planar geometry to one C(121), one C(43), and one C(77) atom. The C(85)-C(43) bond length is 1.39 Å. In the one hundred and twenty-second C site, C(38) is bonded in a trigonal planar geometry to one C(116), one C(129), and one C(137) atom. In the one hundred and twenty-third C site, C(39) is bonded in a distorted single-bond geometry to one C(6) and one H(18) atom. The C(39)-H(18) bond length is 0.94 Å. In the one hundred and twenty-fourth C site, C(40) is bonded in a bent 120 degrees geometry to one C(14) and two equivalent O(16) atoms. Both C(40)-O(16) bond lengths are 1.28 Å. In the one hundred and twenty-fifth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(22), one C(70), and one H(7) atom. The C(41)-C(70) bond length is 1.39 Å. The C(41)-H(7) bond length is 0.94 Å. In the one hundred and twenty-sixth C site, C(86) is bonded in a single-bond geometry to one C(133), one C(63), and one H(6) atom. The C(86)-H(6) bond length is 0.94 Å. In the one hundred and twenty-seventh C site, C(42) is bonded in a distorted single-bond geometry to two equivalent C(70) and one H(52) atom. Both C(42)-C(70) bond lengths are 1.39 Å. The C(42)-H(52) bond length is 0.94 Å. In the one hundred and twenty-eighth C site, C(43) is bonded in a single-bond geometry to one C(85) and one H(62) atom. The C(43)-H(62) bond length is 0.94 Å. In the one hundred and twenty-ninth C site, C(44) is bonded in a linear geometry to one C(5) and one C(81) atom. In the one hundred and thirtieth C site, C(45) is bonded in a distorted single-bond geometry to one C(35) and one H(9,30) atom. The C(45)-H(9,30) bond length is 0.94 Å. In the one hundred and thirty-first C site, C(46) is bonded in a distorted trigonal planar geometry to one C(138), one C(53), and one H(29) atom. The C(46)-C(53) bond length is 1.41 Å. The C(46)-H(29) bond length is 0.94 Å. In the one hundred and thirty-second C site, C(47) is bonded in a distorted single-bond geometry to one C(101), one C(119), and one H(55) atom. The C(47)-H(55) bond length is 0.94 Å. In the one hundred and thirty-third C site, C(48) is bonded in a linear geometry to one C(52) and one C(64) atom. The C(48)-C(52) bond length is 1.57 Å. In the one hundred and thirty-fourth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(125) and two equivalent O(11) atoms. Both C(49)-O(11) bond lengths are 1.26 Å. In the one hundred and thirty-fifth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one C(114), one O(23), and one O(4) atom. The C(50)-O(23) bond length is 1.22 Å. The C(50)-O(4) bond length is 1.31 Å. In the one hundred and thirty-sixth C site, C(52) is bonded in a trigonal planar geometry to one C(13), one C(48), and one C(7) atom. In the one hundred and thirty-seventh C site, C(53) is bonded in a distorted single-bond geometry to one C(136), one C(46), and one H(5) atom. The C(53)-H(5) bond length is 0.94 Å. In the one hundred and thirty-eighth C site, C(54) is bonded in a distorted single-bond geometry to one C(120), one C(97), and one H(41) atom. The C(54)-H(41) bond length is 0.94 Å. In the one hundred and thirty-ninth C site, C(56) is bonded in a trigonal planar geometry to one C(3), one C(59), and one C(66) atom. The C(56)-C(59) bond length is 1.39 Å. In the one hundred and fortieth C site, C(57) is bonded in a distorted single-bond geometry to one C(35) and one H(9,30) atom. The C(57)-H(9,30) bond length is 0.94 Å. In the one hundred and forty-first C site, C(58) is bonded in a trigonal planar geometry to one C(104), one C(28), and one C(98) atom. In the one hundred and forty-second C site, C(59) is bonded in a distorted single-bond geometry to one C(56), one C(7), and one H(13) atom. The C(59)-H(13) bond length is 0.94 Å. In the one hundred and forty-third C site, C(62) is bonded in a distorted single-bond geometry to one C(121), one C(131), and one H(22) atom. The C(62)-H(22) bond length is 0.94 Å. In the one hundred and forty-fourth C site, C(69) is bonded in a linear geometry to one C(2) and one C(79) atom. In the one hundred and forty-fifth C site, C(70) is bonded in a trigonal planar geometry to one C(16), one C(41), and one C(42) atom. In the one hundred and forty-sixth C site, C(72) is bonded in a distorted single-bond geometry to one C(124), one C(33), and one H(23) atom. The C(72)-H(23) bond length is 0.94 Å. There are sixty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(91) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(88) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(109) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(53) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(86) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(41) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(90) atom. In the ninth H site, H(9,30) is bonded in a single-bond geometry to one C(57) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(108) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(106) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(94) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(59) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(92) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(82) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(100) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(78) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(39) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(95) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(112) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(61) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(62) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(72) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(121) atom. In the twenty-fifth H site, H(25) is bonded in a single-bond geometry to one C(122) atom. In the twenty-sixth H site, H(26) is bonded in a single-bond geometry to one C(145) atom. In the twenty-seventh H site, H(27) is bonded in a single-bond geometry to one C(21) atom. In the twenty-eighth H site, H(28) is bonded in a single-bond geometry to one C(137) atom. In the twenty-ninth H site, H(29) is bonded in a single-bond geometry to one C(46) atom. In the thirtieth H site, H(31) is bonded in a single-bond geometry to one C(126) atom. In the thirty-first H site, H(32) is bonded in a single-bond geometry to one C(98) atom. In the thirty-second H site, H(33) is bonded in a single-bond geometry to one C(71) atom. In the thirty-third H site, H(34) is bonded in a single-bond geometry to one C(18) atom. In the thirty-fourth H site, H(35) is bonded in a single-bond geometry to one C(24) atom. In the thirty-fifth H site, H(36) is bonded in a single-bond geometry to one C(36) atom. In the thirty-sixth H site, H(37) is bonded in a single-bond geometry to one C(17) atom. In the thirty-seventh H site, H(38) is bonded in a single-bond geometry to one C(34) atom. In the thirty-eighth H site, H(39) is bonded in a single-bond geometry to one C(31) atom. In the thirty-ninth H site, H(40) is bonded in a single-bond geometry to one C(130) atom. In the fortieth H site, H(41) is bonded in a single-bond geometry to one C(54) atom. In the forty-first H site, H(42) is bonded in a single-bond geometry to one C(104) atom. In the forty-second H site, H(43) is bonded in a single-bond geometry to one C(8) atom. In the forty-third H site, H(44) is bonded in a single-bond geometry to one C(27) atom. In the forty-fourth H site, H(45) is bonded in a single-bond geometry to one C(73) atom. In the forty-fifth H site, H(46) is bonded in a single-bond geometry to one C(105) atom. In the forty-sixth H site, H(47) is bonded in a single-bond geometry to one C(116) atom. In the forty-seventh H site, H(48) is bonded in a single-bond geometry to one C(3) atom. In the forty-eighth H site, H(49) is bonded in a single-bond geometry to one C(7) atom. In the forty-ninth H site, H(50) is bonded in a single-bond geometry to one C(83) atom. In the fiftieth H site, H(51) is bonded in a single-bond geometry to one C(13) atom. In the fifty-first H site, H(52) is bonded in a single-bond geometry to one C(42) atom. In the fifty-second H site, H(53) is bonded in a single-bond geometry to one C(96) atom. In the fifty-third H site, H(54) is bonded in a single-bond geometry to one C(118) atom. In the fifty-fourth H site, H(55) is bonded in a single-bond geometry to one C(47) atom. In the fifty-fifth H site, H(56) is bonded in a single-bond geometry to one C(26) atom. In the fifty-sixth H site, H(57) is bonded in a single-bond geometry to one C(140) atom. In the fifty-seventh H site, H(58) is bonded in a single-bond geometry to one C(127) atom. In the fifty-eighth H site, H(59) is bonded in a single-bond geometry to one C(120) atom. In the fifty-ninth H site, H(60) is bonded in a single-bond geometry to one C(89) atom. In the sixtieth H site, H(61) is bonded in a single-bond geometry to one C(102) atom. In the sixty-first H site, H(62) is bonded in a single-bond geometry to one C(43) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one C(67) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(25) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(19) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cu(6) and one C(50) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cu(1) and one C(37) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(6) and one C(66) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Cu(7) and one C(123) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Cu(7) and one C(28) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one C(67) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(84) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Cu(5) and one C(49) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one C(68) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(28) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Cu(5) and one C(74) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Cu(7) and one C(37) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Cu(5) and one C(40) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(66) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Cu(6) and one C(25) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(123) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one C(68) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Cu(6) and one C(84) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Cu(5) and one C(144) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(50) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 120 degrees geometry to one Cu(7) and one C(19) atom. Linkers: 16 [O]C(=O)c1ccc(C#Cc2cc(C#Cc3ccc(C([O])=O)cc3)cc(C#Cc3ccc(C([O])=O)cc3)c2)cc1. Metal clusters: 12 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: tbo. The MOF has largest included sphere 22.00 A, density 0.30 g/cm3, surface area 4843.12 m2/g, accessible volume 2.90 cm3/g