Na2Ag3C17N3H8S3O8CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a Na2Ag3C17N3H8S3O8 framework. In the Na2Ag3C17N3H8S3O8 framework, there are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(7), and two equivalent O(8) atoms. The Na(1)-O(1) bond length is 2.45 Å. The Na(1)-O(7) bond length is 2.34 Å. There is one shorter (2.46 Å) and one longer (2.52 Å) Na(1)-O(8) bond length. In the second Na site, Na(2) is bonded in a distorted trigonal bipyramidal geometry to one O(1), one O(3), one O(5), one O(6), and one O(7) atom. The Na(2)-O(1) bond length is 2.33 Å. The Na(2)-O(3) bond length is 2.39 Å. The Na(2)-O(5) bond length is 2.39 Å. The Na(2)-O(6) bond length is 2.35 Å. The Na(2)-O(7) bond length is 2.43 Å. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal planar geometry to one N(1), one S(2), and one S(3) atom. The Ag(1)-N(1) bond length is 2.29 Å. The Ag(1)-S(2) bond length is 2.47 Å. The Ag(1)-S(3) bond length is 2.48 Å. In the second Ag site, Ag(2) is bonded in a distorted trigonal planar geometry to one N(2), one S(1), and one S(3) atom. The Ag(2)-N(2) bond length is 2.30 Å. The Ag(2)-S(1) bond length is 2.52 Å. The Ag(2)-S(3) bond length is 2.47 Å. In the third Ag site, Ag(3) is bonded in a distorted trigonal planar geometry to one N(3), one S(1), and one S(2) atom. The Ag(3)-N(3) bond length is 2.29 Å. The Ag(3)-S(1) bond length is 2.52 Å. The Ag(3)-S(2) bond length is 2.48 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one S(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-S(1) bond length is 1.77 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.51 Å. The C(2)-C(4) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(3)-O(1) bond length is 1.25 Å. The C(3)-O(2) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(4)-H(1) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(2) atom. The C(5)-C(6) bond length is 1.38 Å. The C(5)-H(2) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(3) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-H(3) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one S(2) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(2) bond length is 1.35 Å. The C(7)-S(2) bond length is 1.76 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.39 Å. The C(8)-C(9) bond length is 1.52 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(3), and one O(4) atom. The C(9)-O(3) bond length is 1.24 Å. The C(9)-O(4) bond length is 1.27 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(4) atom. The C(10)-H(4) bond length is 0.93 Å. In the eleventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(12)-N(2) bond length is 1.34 Å. The C(12)-H(6) bond length is 0.93 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one S(3) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-N(3) bond length is 1.35 Å. The C(13)-S(3) bond length is 1.77 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(16) atom. The C(14)-C(15) bond length is 1.52 Å. The C(14)-C(16) bond length is 1.39 Å. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(5), and one O(6) atom. The C(15)-O(5) bond length is 1.25 Å. The C(15)-O(6) bond length is 1.26 Å. In the fifteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(14) and one H(7) atom. The C(16)-H(7) bond length is 0.93 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(8) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-H(8) bond length is 0.93 Å. In the seventeenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one N(3), and one H(9) atom. The C(18)-N(3) bond length is 1.34 Å. The C(18)-H(9) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(2), one C(12), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(3), one C(13), and one C(18) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(18) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(2), one Ag(3), and one C(1) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(3), and one C(7) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(2), and one C(13) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one Na(2), and one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Na(2) and one C(9) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Na(2) and one C(15) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Na(2) and one C(15) atom. In the seventh O site, O(7) is bonded in an L-shaped geometry to one Na(1) and one Na(2) atom. In the eighth O site, O(8) is bonded in a water-like geometry to two equivalent Na(1) atoms. Linkers: 6 [O]C(=O)[C]1C=CC=NC1=S. Metal clusters: 4 [Na] ,6 [Ag]. The MOF has largest included sphere 5.51 A, density 1.78 g/cm3, surface area 2940.90 m2/g, accessible volume 0.20 cm3/g