Zn23C198H90(N9O20)4(CH)54 crystallizes in the trigonal R-3c space group. The structure consists of two hundred and sixteen 02329_fluka molecules and thirty-six propylene molecules inside a Zn23C198H90(N9O20)4 framework. In the Zn23C198H90(N9O20)4 framework, there are five inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(12), one O(2), one O(4), one O(6), and two equivalent O(11) atoms to form distorted ZnO6 octahedra that share  a cornercorner with one Zn(4)O4 tetrahedra and  an edgeedge with one Zn(1)O6 octahedra. The Zn(1)-O(12) bond length is 2.10 Å. The Zn(1)-O(2) bond length is 2.04 Å. The Zn(1)-O(4) bond length is 2.01 Å. The Zn(1)-O(6) bond length is 2.02 Å. There is one shorter (2.18 Å) and one longer (2.35 Å) Zn(1)-O(11) bond length. In the second Zn site, Zn(2) is bonded in a rectangular see-saw-like geometry to two equivalent O(5) and two equivalent O(6) atoms. Both Zn(2)-O(5) bond lengths are 2.07 Å. Both Zn(2)-O(6) bond lengths are 2.09 Å. In the third Zn site, Zn(3) is bonded to one O(1), one O(10), one O(14), and one O(8) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(1) bond length is 1.93 Å. The Zn(3)-O(10) bond length is 1.97 Å. The Zn(3)-O(14) bond length is 1.93 Å. The Zn(3)-O(8) bond length is 1.90 Å. In the fourth Zn site, Zn(4) is bonded to one O(13), one O(6), one O(7), and one O(9) atom to form corner-sharing ZnO4 tetrahedra. The corner-sharing octahedral tilt angles are 79°. The Zn(4)-O(13) bond length is 1.92 Å. The Zn(4)-O(6) bond length is 1.99 Å. The Zn(4)-O(7) bond length is 1.98 Å. The Zn(4)-O(9) bond length is 1.97 Å. In the fifth Zn site, Zn(5) is bonded to one O(14) and three equivalent O(3) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(5)-O(14) bond length is 1.95 Å. All Zn(5)-O(3) bond lengths are 1.96 Å. There are thirty-three inequivalent C sites. In the first C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(10), and one O(3) atom. The C(19)-C(13) bond length is 1.50 Å. The C(19)-O(10) bond length is 1.25 Å. The C(19)-O(3) bond length is 1.25 Å. In the second C site, C(20) is bonded in a distorted single-bond geometry to one C(34), one C(40), and one H(3) atom. The C(20)-C(34) bond length is 1.36 Å. The C(20)-C(40) bond length is 1.39 Å. The C(20)-H(3) bond length is 0.93 Å. In the third C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(33), one O(13), and one O(5) atom. The C(21)-C(33) bond length is 1.50 Å. The C(21)-O(13) bond length is 1.26 Å. The C(21)-O(5) bond length is 1.24 Å. In the fourth C site, C(23) is bonded in a distorted single-bond geometry to one C(33), one C(5), and one H(20) atom. The C(23)-C(33) bond length is 1.39 Å. The C(23)-C(5) bond length is 1.39 Å. The C(23)-H(20) bond length is 0.93 Å. In the fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(27) and one H(7) atom. The C(25)-C(27) bond length is 1.37 Å. The C(25)-H(7) bond length is 0.93 Å. In the sixth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(28), one C(6), and one N(2) atom. The C(26)-C(28) bond length is 1.39 Å. The C(26)-C(6) bond length is 1.39 Å. The C(26)-N(2) bond length is 1.43 Å. In the seventh C site, C(27) is bonded in a distorted trigonal planar geometry to one C(25), one C(42), and one N(3) atom. The C(27)-C(42) bond length is 1.36 Å. The C(27)-N(3) bond length is 1.44 Å. In the eighth C site, C(28) is bonded in a distorted single-bond geometry to one C(26), one C(5), and one H(4) atom. The C(28)-C(5) bond length is 1.39 Å. The C(28)-H(4) bond length is 0.93 Å. In the ninth C site, C(29) is bonded in a trigonal planar geometry to one C(16), one C(37), and one C(41) atom. The C(29)-C(16) bond length is 1.37 Å. The C(29)-C(37) bond length is 1.40 Å. The C(29)-C(41) bond length is 1.50 Å. In the tenth C site, C(30) is bonded in a distorted single-bond geometry to one C(13), one C(34), and one H(9) atom. The C(30)-C(13) bond length is 1.38 Å. The C(30)-C(34) bond length is 1.39 Å. The C(30)-H(9) bond length is 0.93 Å. In the eleventh C site, C(31) is bonded in a distorted trigonal planar geometry to one C(32), one C(39), and one N(6) atom. The C(31)-C(32) bond length is 1.35 Å. The C(31)-C(39) bond length is 1.38 Å. The C(31)-N(6) bond length is 1.42 Å. In the twelfth C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(2) atom. The C(32)-H(2) bond length is 0.93 Å. In the thirteenth C site, C(33) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(6) atom. The C(33)-C(6) bond length is 1.39 Å. In the fourteenth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(20), one C(30), and one N(5) atom. The C(34)-N(5) bond length is 1.43 Å. In the fifteenth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(16), one C(2), and one N(1) atom. The C(35)-C(16) bond length is 1.40 Å. The C(35)-C(2) bond length is 1.40 Å. The C(35)-N(1) bond length is 1.41 Å. In the sixteenth C site, C(37) is bonded in a distorted single-bond geometry to one C(14), one C(29), and one H(24) atom. The C(37)-C(14) bond length is 1.39 Å. The C(37)-H(24) bond length is 0.93 Å. In the seventeenth C site, C(39) is bonded in a distorted single-bond geometry to one C(31) and one H(21) atom. The C(39)-H(21) bond length is 0.93 Å. In the eighteenth C site, C(40) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(4) atom. The C(40)-C(18) bond length is 1.51 Å. The C(40)-C(4) bond length is 1.40 Å. In the nineteenth C site, C(1) is bonded in a bent 120 degrees geometry to one C(14), one O(11), and one O(12) atom. The C(1)-C(14) bond length is 1.49 Å. The C(1)-O(11) bond length is 1.28 Å. The C(1)-O(12) bond length is 1.25 Å. In the twentieth C site, C(2) is bonded in a distorted single-bond geometry to one C(14), one C(35), and one H(13) atom. The C(2)-C(14) bond length is 1.40 Å. The C(2)-H(13) bond length is 0.93 Å. In the twenty-first C site, C(4) is bonded in a distorted single-bond geometry to one C(13), one C(40), and one H(11) atom. The C(4)-C(13) bond length is 1.38 Å. The C(4)-H(11) bond length is 0.93 Å. In the twenty-second C site, C(5) is bonded in a trigonal planar geometry to one C(11), one C(23), and one C(28) atom. The C(5)-C(11) bond length is 1.51 Å. In the twenty-third C site, C(6) is bonded in a distorted single-bond geometry to one C(26), one C(33), and one H(5) atom. The C(6)-H(5) bond length is 0.93 Å. In the twenty-fourth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(1), and one O(8) atom. The C(41)-O(1) bond length is 1.26 Å. The C(41)-O(8) bond length is 1.28 Å. In the twenty-fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(10), one C(17), and one N(4) atom. The C(7)-C(10) bond length is 1.39 Å. The C(7)-C(17) bond length is 1.39 Å. The C(7)-N(4) bond length is 1.42 Å. In the twenty-sixth C site, C(42) is bonded in a distorted single-bond geometry to one C(27) and one H(14) atom. The C(42)-H(14) bond length is 0.93 Å. In the twenty-seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(7) and one H(12,19) atom. The C(10)-H(12,19) bond length is 0.93 Å. In the twenty-eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(4), and one O(9) atom. The C(11)-O(4) bond length is 1.25 Å. The C(11)-O(9) bond length is 1.25 Å. In the twenty-ninth C site, C(13) is bonded in a trigonal planar geometry to one C(19), one C(30), and one C(4) atom. In the thirtieth C site, C(14) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(37) atom. In the thirty-first C site, C(16) is bonded in a distorted single-bond geometry to one C(29), one C(35), and one H(16) atom. The C(16)-H(16) bond length is 0.93 Å. In the thirty-second C site, C(17) is bonded in a distorted single-bond geometry to one C(7) and one H(12,19) atom. The C(17)-H(12,19) bond length is 0.93 Å. In the thirty-third C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(40), one O(2), and one O(7) atom. The C(18)-O(2) bond length is 1.25 Å. The C(18)-O(7) bond length is 1.26 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one C(35) and one N(6) atom. The N(1)-N(6) bond length is 1.24 Å. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(26) and one N(4) atom. The N(2)-N(4) bond length is 1.23 Å. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one C(27) and one N(5) atom. The N(3)-N(5) bond length is 1.21 Å. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one C(7) and one N(2) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(34) and one N(3) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one C(31) and one N(1) atom. There are fourteen inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(32) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(20) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(28) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(25) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(30) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(12,19) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(2) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(42) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(39) atom. In the fourteenth H site, H(24) is bonded in a single-bond geometry to one C(37) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(41) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(18) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(19) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(11) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(21) atom. In the sixth O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(2), and one Zn(4) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(18) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(41) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(11) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(19) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to two equivalent Zn(1) and one C(1) atom. In the twelfth O site, O(12) is bonded in an L-shaped geometry to one Zn(1) and one C(1) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(21) atom. In the fourteenth O site, O(14) is bonded in a tetrahedral geometry to one Zn(5) and three equivalent Zn(3) atoms. Linkers: 36 [O]C(=O)c1cc([N][N]c2ccccc2)cc(C([O])=O)c1. Metal clusters: 6 [C]1O[Zn]O[C]O[Zn]23O[C]O[Zn]4(O[C]O2)(O[C]O[Zn]25(O[C]O[Zn](O1)(O[C]O2)O5)O[C]O4)O3 ,4 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. The MOF has largest included sphere 8.38 A, density 1.23 g/cm3, surface area 4229.99 m2/g, accessible volume 0.37 cm3/g