(CH2)2CdC14N4H14(OF)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and six CdC14N4H14(OF)2 clusters. In two of the CdC14N4H14(OF)2 clusters, Cd(3) is bonded in a T-shaped geometry to one N(10), one N(12), and one O(5) atom. The Cd(3)-N(10) bond length is 2.29 Å. The Cd(3)-N(12) bond length is 2.22 Å. The Cd(3)-O(5) bond length is 2.33 Å. There are fourteen inequivalent C sites. In the first C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(5), and one O(6) atom. The C(34)-C(35) bond length is 1.53 Å. The C(34)-O(5) bond length is 1.24 Å. The C(34)-O(6) bond length is 1.24 Å. In the second C site, C(35) is bonded in a trigonal planar geometry to one C(34), one C(36), and one C(37) atom. The C(35)-C(36) bond length is 1.37 Å. The C(35)-C(37) bond length is 1.39 Å. In the third C site, C(36) is bonded in a distorted single-bond geometry to one C(35) and one F(5) atom. The C(36)-F(5) bond length is 1.34 Å. In the fourth C site, C(37) is bonded in a distorted single-bond geometry to one C(35) and one F(6) atom. The C(37)-F(6) bond length is 1.36 Å. In the fifth C site, C(38) is bonded in a trigonal non-coplanar geometry to one C(39) and three equivalent H(39,40,41) atoms. The C(38)-C(39) bond length is 1.46 Å. All C(38)-H(39,40,41) bond lengths are 0.96 Å. In the sixth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one N(10), and one N(9) atom. The C(39)-N(10) bond length is 1.30 Å. The C(39)-N(9) bond length is 1.34 Å. In the seventh C site, C(40) is bonded in a 3-coordinate geometry to one C(41), one N(10), and one H(42) atom. The C(40)-C(41) bond length is 1.34 Å. The C(40)-N(10) bond length is 1.42 Å. The C(40)-H(42) bond length is 0.93 Å. In the eighth C site, C(41) is bonded in a 3-coordinate geometry to one C(40), one N(9), and one H(43) atom. The C(41)-N(9) bond length is 1.40 Å. The C(41)-H(43) bond length is 0.93 Å. In the ninth C site, C(42) is bonded in a 3-coordinate geometry to one N(9) and two equivalent H(44,45) atoms. The C(42)-N(9) bond length is 1.46 Å. Both C(42)-H(44,45) bond lengths are 0.97 Å. In the tenth C site, C(44) is bonded in a trigonal non-coplanar geometry to one C(45); one H(49); and two equivalent H(48,50) atoms. The C(44)-C(45) bond length is 1.48 Å. The C(44)-H(49) bond length is 0.96 Å. Both C(44)-H(48,50) bond lengths are 0.96 Å. In the eleventh C site, C(45) is bonded in a distorted trigonal planar geometry to one C(44), one N(11), and one N(12) atom. The C(45)-N(11) bond length is 1.35 Å. The C(45)-N(12) bond length is 1.34 Å. In the twelfth C site, C(46) is bonded in a 2-coordinate geometry to one N(11) and one H(51) atom. The C(46)-N(11) bond length is 1.39 Å. The C(46)-H(51) bond length is 0.93 Å. In the thirteenth C site, C(47) is bonded in a 3-coordinate geometry to one N(11), one H(52), and one H(53) atom. The C(47)-N(11) bond length is 1.47 Å. The C(47)-H(52) bond length is 0.97 Å. The C(47)-H(53) bond length is 0.97 Å. In the fourteenth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one N(12) and one H(54) atom. The C(48)-N(12) bond length is 1.36 Å. The C(48)-H(54) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(9) is bonded in a trigonal planar geometry to one C(39), one C(41), and one C(42) atom. In the second N site, N(10) is bonded in a distorted trigonal planar geometry to one Cd(3), one C(39), and one C(40) atom. In the third N site, N(11) is bonded in a trigonal planar geometry to one C(45), one C(46), and one C(47) atom. In the fourth N site, N(12) is bonded in a distorted trigonal planar geometry to one Cd(3), one C(45), and one C(48) atom. There are ten inequivalent H sites. In the first H site, H(39,40,41) is bonded in a single-bond geometry to one C(38) atom. In the second H site, H(42) is bonded in a single-bond geometry to one C(40) atom. In the third H site, H(43) is bonded in a single-bond geometry to one C(41) atom. In the fourth H site, H(44,45) is bonded in a single-bond geometry to one C(42) atom. In the fifth H site, H(48,50) is bonded in a single-bond geometry to one C(44) atom. In the sixth H site, H(49) is bonded in a single-bond geometry to one C(44) atom. In the seventh H site, H(51) is bonded in a single-bond geometry to one C(46) atom. In the eighth H site, H(52) is bonded in a single-bond geometry to one C(47) atom. In the ninth H site, H(53) is bonded in a single-bond geometry to one C(47) atom. In the tenth H site, H(54) is bonded in a single-bond geometry to one C(48) atom. There are two inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Cd(3) and one C(34) atom. In the second O site, O(6) is bonded in a single-bond geometry to one C(34) atom. There are two inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one C(36) atom. In the second F site, F(6) is bonded in a single-bond geometry to one C(37) atom. In four of the CdC14N4H14(OF)2 clusters, Cd(1) is bonded in a distorted T-shaped geometry to one N(2), one N(4), and one O(1) atom. The Cd(1)-N(2) bond length is 2.32 Å. The Cd(1)-N(4) bond length is 2.25 Å. The Cd(1)-O(1) bond length is 2.28 Å. There are fourteen inequivalent C sites. In the first C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one F(3) atom. The C(15)-C(14) bond length is 1.37 Å. The C(15)-F(3) bond length is 1.36 Å. In the second C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one F(1) atom. The C(19)-C(14) bond length is 1.36 Å. The C(19)-F(1) bond length is 1.36 Å. In the third C site, C(1) is bonded in a trigonal non-coplanar geometry to one C(2) and three equivalent H(1,2,3) atoms. The C(1)-C(2) bond length is 1.50 Å. All C(1)-H(1,2,3) bond lengths are 0.96 Å. In the fourth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one N(2) atom. The C(2)-N(1) bond length is 1.32 Å. The C(2)-N(2) bond length is 1.34 Å. In the fifth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one H(4) atom. The C(3)-C(4) bond length is 1.33 Å. The C(3)-N(2) bond length is 1.38 Å. The C(3)-H(4) bond length is 0.93 Å. In the sixth C site, C(4) is bonded in a 3-coordinate geometry to one C(3), one N(1), and one H(5) atom. The C(4)-N(1) bond length is 1.39 Å. The C(4)-H(5) bond length is 0.93 Å. In the seventh C site, C(5) is bonded in a 3-coordinate geometry to one N(1) and two equivalent H(6,7) atoms. The C(5)-N(1) bond length is 1.46 Å. Both C(5)-H(6,7) bond lengths are 0.97 Å. In the eighth C site, C(7) is bonded in a trigonal non-coplanar geometry to one C(8), one H(10), one H(11), and one H(12) atom. The C(7)-C(8) bond length is 1.46 Å. The C(7)-H(10) bond length is 0.96 Å. The C(7)-H(11) bond length is 0.96 Å. The C(7)-H(12) bond length is 0.96 Å. In the ninth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one N(3), and one N(4) atom. The C(8)-N(3) bond length is 1.36 Å. The C(8)-N(4) bond length is 1.34 Å. In the tenth C site, C(10) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(15,16) atoms. The C(10)-N(3) bond length is 1.46 Å. Both C(10)-H(15,16) bond lengths are 0.97 Å. In the eleventh C site, C(11) is bonded in a 3-coordinate geometry to one C(12), one N(3), and one H(17) atom. The C(11)-C(12) bond length is 1.34 Å. The C(11)-N(3) bond length is 1.37 Å. The C(11)-H(17) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(4), and one H(18) atom. The C(12)-N(4) bond length is 1.38 Å. The C(12)-H(18) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(1), and one O(2) atom. The C(13)-C(14) bond length is 1.52 Å. The C(13)-O(1) bond length is 1.23 Å. The C(13)-O(2) bond length is 1.23 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(19) atom. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(2), and one C(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(8) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(12), and one C(8) atom. There are ten inequivalent H sites. In the first H site, H(1,2,3) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(6,7) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(15,16) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(13) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one C(15) atom. In the second F site, F(1) is bonded in a single-bond geometry to one C(19) atom. Linkers: 3 [O]C(=O)c1c(F)c(F)c(C([O])=O)c(F)c1F ,6 Cc1nccn1CCCCn1ccnc1C. Metal clusters: 6 O=[C]O[Cd]. The MOF has largest included sphere 4.22 A, density 1.27 g/cm3, surface area 4724.96 m2/g, accessible volume 0.41 cm3/g