NdC20N6H12O10Cl(CH)12(CH2)8 is Indium-derived structured and crystallizes in the tetragonal P4_12_12 space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules, thirty-two 02329_fluka molecules, and four NdC20N6H12O10Cl clusters. In each NdC20N6H12O10Cl cluster, Nd(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(4), two equivalent O(5), and one Cl(1) atom. Both Nd(1)-O(1) bond lengths are 2.61 Å. Both Nd(1)-O(2) bond lengths are 2.41 Å. Both Nd(1)-O(4) bond lengths are 2.48 Å. Both Nd(1)-O(5) bond lengths are 2.57 Å. The Nd(1)-Cl(1) bond length is 2.84 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one N(2) and one H(12) atom. The C(1)-N(2) bond length is 1.49 Å. The C(1)-H(12) bond length is 0.98 Å. In the second C site, C(5) is bonded in a 2-coordinate geometry to one N(1) and one H(2) atom. The C(5)-N(1) bond length is 1.46 Å. The C(5)-H(2) bond length is 0.98 Å. In the third C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(1), and one H(14) atom. The C(6)-C(20) bond length is 1.43 Å. The C(6)-N(1) bond length is 1.30 Å. The C(6)-H(14) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(20) and one O(4) atom. The C(7)-C(20) bond length is 1.45 Å. The C(7)-O(4) bond length is 1.29 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(2), and one H(9) atom. The C(8)-C(12) bond length is 1.41 Å. The C(8)-N(2) bond length is 1.30 Å. The C(8)-H(9) bond length is 0.93 Å. In the sixth C site, C(12) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(8) atom. The C(12)-C(17) bond length is 1.42 Å. The C(12)-C(19) bond length is 1.43 Å. In the seventh C site, C(15) is bonded in a distorted single-bond geometry to one C(20) and one H(19) atom. The C(15)-C(20) bond length is 1.41 Å. The C(15)-H(19) bond length is 0.93 Å. In the eighth C site, C(17) is bonded in a distorted single-bond geometry to one C(12) and one H(18) atom. The C(17)-H(18) bond length is 0.93 Å. In the ninth C site, C(19) is bonded in a distorted single-bond geometry to one C(12) and one O(2) atom. The C(19)-O(2) bond length is 1.29 Å. In the tenth C site, C(20) is bonded in a trigonal planar geometry to one C(15), one C(6), and one C(7) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(5) and one C(6) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(1) and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(1), one O(3), and one O(5) atom. The N(3)-O(1) bond length is 1.23 Å. The N(3)-O(3) bond length is 1.34 Å. The N(3)-O(5) bond length is 1.27 Å. There are six inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(15) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Nd(1) and one N(3) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Nd(1) and one C(19) atom. In the third O site, O(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Nd(1) and one C(7) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Nd(1) and one N(3) atom. Cl(1) is bonded in a single-bond geometry to one Nd(1) atom. Linkers: 8 [O]c1ccccc1/C=N/[C@@H]1CCCC[C@H]1/N=C/c1ccccc1[O]. Metal clusters: 4 [Cl].[O][Nd]([O])([O])([O])(O[N+](=O)[O-])O[N+](=O)[O-]. RCSR code: dia. The MOF has largest included sphere 5.30 A, density 1.16 g/cm3, surface area 4634.28 m2/g, accessible volume 0.33 cm3/g