Ga3(PO4)3F crystallizes in the triclinic P-1 space group. There are six inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(1), one O(2), one O(3), one O(4), one F(1), and one F(2) atom to form GaO4F2 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one Ga(3)O4F2 octahedra. The Ga(1)-O(1) bond length is 1.95 Å. The Ga(1)-O(2) bond length is 1.94 Å. The Ga(1)-O(3) bond length is 1.90 Å. The Ga(1)-O(4) bond length is 1.88 Å. The Ga(1)-F(1) bond length is 1.96 Å. The Ga(1)-F(2) bond length is 1.98 Å. In the second Ga site, Ga(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form GaO4 tetrahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The Ga(2)-O(5) bond length is 1.84 Å. The Ga(2)-O(6) bond length is 1.82 Å. The Ga(2)-O(7) bond length is 1.81 Å. The Ga(2)-O(8) bond length is 1.81 Å. In the third Ga site, Ga(3) is bonded to one O(10), one O(11), one O(12), one O(9), one F(1), and one F(2) atom to form GaO4F2 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  an edgeedge with one Ga(1)O4F2 octahedra. The Ga(3)-O(10) bond length is 1.93 Å. The Ga(3)-O(11) bond length is 1.90 Å. The Ga(3)-O(12) bond length is 1.95 Å. The Ga(3)-O(9) bond length is 1.91 Å. The Ga(3)-F(1) bond length is 1.97 Å. The Ga(3)-F(2) bond length is 1.97 Å. In the fourth Ga site, Ga(4) is bonded to one O(13), one O(14), one O(15), and one O(16) atom to form GaO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. The Ga(4)-O(13) bond length is 1.82 Å. The Ga(4)-O(14) bond length is 1.81 Å. The Ga(4)-O(15) bond length is 1.83 Å. The Ga(4)-O(16) bond length is 1.83 Å. In the fifth Ga site, Ga(5) is bonded to one O(17), one O(18), one O(19), and one O(20) atom to form GaO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The Ga(5)-O(17) bond length is 1.80 Å. The Ga(5)-O(18) bond length is 1.82 Å. The Ga(5)-O(19) bond length is 1.82 Å. The Ga(5)-O(20) bond length is 1.82 Å. In the sixth Ga site, Ga(6) is bonded to one O(21), one O(22), one O(23), and one O(24) atom to form GaO4 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The Ga(6)-O(21) bond length is 1.82 Å. The Ga(6)-O(22) bond length is 1.81 Å. The Ga(6)-O(23) bond length is 1.82 Å. The Ga(6)-O(24) bond length is 1.80 Å. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(12), one O(13), one O(2), and one O(23) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(3)O4F2 octahedra,  a cornercorner with one Ga(4)O4 tetrahedra, and  a cornercorner with one Ga(6)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-53°. The P(1)-O(12) bond length is 1.53 Å. The P(1)-O(13) bond length is 1.55 Å. The P(1)-O(2) bond length is 1.52 Å. The P(1)-O(23) bond length is 1.55 Å. In the second P site, P(2) is bonded to one O(14), one O(20), one O(22), and one O(3) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(4)O4 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra, and  a cornercorner with one Ga(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 43°. The P(2)-O(14) bond length is 1.53 Å. The P(2)-O(20) bond length is 1.54 Å. The P(2)-O(22) bond length is 1.55 Å. The P(2)-O(3) bond length is 1.51 Å. In the third P site, P(3) is bonded to one O(1), one O(10), one O(18), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(3)O4F2 octahedra,  a cornercorner with one Ga(2)O4 tetrahedra, and  a cornercorner with one Ga(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 52-53°. The P(3)-O(1) bond length is 1.53 Å. The P(3)-O(10) bond length is 1.52 Å. The P(3)-O(18) bond length is 1.56 Å. The P(3)-O(6) bond length is 1.56 Å. In the fourth P site, P(4) is bonded to one O(15), one O(24), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(2)O4 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra, and  a cornercorner with one Ga(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 33°. The P(4)-O(15) bond length is 1.54 Å. The P(4)-O(24) bond length is 1.52 Å. The P(4)-O(4) bond length is 1.52 Å. The P(4)-O(8) bond length is 1.53 Å. In the fifth P site, P(5) is bonded to one O(16), one O(17), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(3)O4F2 octahedra,  a cornercorner with one Ga(2)O4 tetrahedra,  a cornercorner with one Ga(4)O4 tetrahedra, and  a cornercorner with one Ga(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 48°. The P(5)-O(16) bond length is 1.54 Å. The P(5)-O(17) bond length is 1.52 Å. The P(5)-O(5) bond length is 1.55 Å. The P(5)-O(9) bond length is 1.51 Å. In the sixth P site, P(6) is bonded to one O(11), one O(19), one O(21), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(3)O4F2 octahedra,  a cornercorner with one Ga(2)O4 tetrahedra,  a cornercorner with one Ga(5)O4 tetrahedra, and  a cornercorner with one Ga(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 40°. The P(6)-O(11) bond length is 1.51 Å. The P(6)-O(19) bond length is 1.55 Å. The P(6)-O(21) bond length is 1.54 Å. The P(6)-O(7) bond length is 1.52 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Ga(1) and one P(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Ga(2) and one P(5) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ga(2) and one P(3) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Ga(2) and one P(6) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Ga(2) and one P(4) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Ga(3) and one P(5) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Ga(3) and one P(3) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Ga(3) and one P(6) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Ga(3) and one P(1) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Ga(4) and one P(1) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Ga(4) and one P(2) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Ga(4) and one P(4) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Ga(4) and one P(5) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one Ga(5) and one P(5) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Ga(5) and one P(3) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Ga(5) and one P(6) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Ga(5) and one P(2) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 120 degrees geometry to one Ga(6) and one P(6) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Ga(6) and one P(2) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Ga(6) and one P(1) atom. In the twenty-fourth O site, O(24) is bonded in a bent 150 degrees geometry to one Ga(6) and one P(4) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a water-like geometry to one Ga(1) and one Ga(3) atom. In the second F site, F(2) is bonded in a water-like geometry to one Ga(1) and one Ga(3) atom. Linkers: 12 [O]P([O])([O])=O. Metal clusters: 12 [Ga]. The MOF has largest included sphere 5.88 A, density 2.24 g/cm3, surface area 2060.63 m2/g, accessible volume 0.20 cm3/g