MnC6S2(NO)4(CH)2 crystallizes in the tetragonal I-42d space group. The structure consists of eight 02329_fluka molecules inside a MnC6S2(NO)4 framework. In the MnC6S2(NO)4 framework, Mn(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(1) atoms. All Mn(1)-O(1) bond lengths are 2.19 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one N(1) and one O(1) atom. The C(1)-N(1) bond length is 1.40 Å. The C(1)-O(1) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to two equivalent N(1) and one S(1) atom. Both C(2)-N(1) bond lengths are 1.36 Å. The C(2)-S(1) bond length is 1.64 Å. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. S(1) is bonded in a single-bond geometry to one C(2) atom. O(1) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(1) atom. Linkers: 1 O=C1[CH]C(O[Mn](OC2=NC(=S)[N]C(=O)[CH]2)(OC2=NC(=S)[N]C(=O)[CH]2)OC2=NC(=S)[N]C(=O)[CH]2)=NC(=S)[N]1. Metal clusters: 1 [O][Mn]([O])([O])[O]. RCSR code: dia. The MOF has largest included sphere 4.60 A, density 1.00 g/cm3, surface area 4209.56 m2/g, accessible volume 0.55 cm3/g