Fe3C38N3H62O13Co3C38N3H62O13(C4H3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four isobutylene molecules, two Co3C38N3H62O13 clusters, and two Fe3C38N3H62O13 clusters. In each Co3C38N3H62O13 cluster, there are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(4), one O(14), one O(15), one O(17), one O(21), and one O(24) atom to form corner-sharing CoNO5 octahedra. The corner-sharing octahedral tilt angles range from 59-61°. The Co(1)-N(4) bond length is 2.19 Å. The Co(1)-O(14) bond length is 2.04 Å. The Co(1)-O(15) bond length is 2.05 Å. The Co(1)-O(17) bond length is 2.03 Å. The Co(1)-O(21) bond length is 2.05 Å. The Co(1)-O(24) bond length is 1.88 Å. In the second Co site, Co(2) is bonded to one N(5), one O(16), one O(18), one O(19), one O(24), and one O(26) atom to form corner-sharing CoNO5 octahedra. The corner-sharing octahedral tilt angles are 59°. The Co(2)-N(5) bond length is 2.19 Å. The Co(2)-O(16) bond length is 2.04 Å. The Co(2)-O(18) bond length is 2.03 Å. The Co(2)-O(19) bond length is 2.03 Å. The Co(2)-O(24) bond length is 1.86 Å. The Co(2)-O(26) bond length is 2.05 Å. In the third Co site, Co(3) is bonded to one N(6), one O(20), one O(22), one O(23), one O(24), and one O(25) atom to form corner-sharing CoNO5 octahedra. The corner-sharing octahedral tilt angles range from 59-61°. The Co(3)-N(6) bond length is 2.17 Å. The Co(3)-O(20) bond length is 2.05 Å. The Co(3)-O(22) bond length is 2.07 Å. The Co(3)-O(23) bond length is 2.04 Å. The Co(3)-O(24) bond length is 1.90 Å. The Co(3)-O(25) bond length is 2.05 Å. There are thirty-eight inequivalent C sites. In the first C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(3,68) atom. The C(4)-N(4) bond length is 1.33 Å. The C(4)-H(3,68) bond length is 0.96 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(4,69) atom. The C(5)-N(4) bond length is 1.35 Å. The C(5)-H(4,69) bond length is 1.00 Å. In the third C site, C(22,64) is bonded in a trigonal non-coplanar geometry to one C(13); one H(12,24,26,49,50,77,89,91,114,115); and two equivalent H(13,14,78,79) atoms. The C(22,64)-C(13) bond length is 1.54 Å. The C(22,64)-H(12,24,26,49,50,77,89,91,114,115) bond length is 0.98 Å. Both C(22,64)-H(13,14,78,79) bond lengths are 0.98 Å. In the fourth C site, C(23,65) is bonded in a trigonal non-coplanar geometry to one C(8); one H(17,28,29,52,53,82,93,94,117,118); and two equivalent H(15,16,27,51,80,81,92,116) atoms. The C(23,65)-C(8) bond length is 1.52 Å. The C(23,65)-H(17,28,29,52,53,82,93,94,117,118) bond length is 0.98 Å. Both C(23,65)-H(15,16,27,51,80,81,92,116) bond lengths are 0.98 Å. In the fifth C site, C(25,67) is bonded in a trigonal non-coplanar geometry to one C(20); one H(19,58,59,84,123,124); and two equivalent H(18,20,54,55,56,83,85,119,120,121) atoms. The C(25,67)-C(20) bond length is 1.49 Å. The C(25,67)-H(19,58,59,84,123,124) bond length is 0.98 Å. Both C(25,67)-H(18,20,54,55,56,83,85,119,120,121) bond lengths are 0.98 Å. In the sixth C site, C(26,68) is bonded in a trigonal non-coplanar geometry to one C(19) and three equivalent H(21,22,23,33,35,45,46,47,86,87,88,98,100,110,111,112) atoms. The C(26,68)-C(19) bond length is 1.51 Å. All C(26,68)-H(21,22,23,33,35,45,46,47,86,87,88,98,100,110,111,112) bond lengths are 0.98 Å. In the seventh C site, C(27,69) is bonded in a trigonal non-coplanar geometry to one C(13); one H(25,48,90,113); and two equivalent H(12,24,26,49,50,77,89,91,114,115) atoms. The C(27,69)-C(13) bond length is 1.46 Å. The C(27,69)-H(25,48,90,113) bond length is 0.98 Å. Both C(27,69)-H(12,24,26,49,50,77,89,91,114,115) bond lengths are 0.98 Å. In the eighth C site, C(28,70) is bonded in a trigonal non-coplanar geometry to one C(8); one H(15,16,27,51,80,81,92,116); and two equivalent H(17,28,29,52,53,82,93,94,117,118) atoms. The C(28,70)-C(8) bond length is 1.51 Å. The C(28,70)-H(15,16,27,51,80,81,92,116) bond length is 0.98 Å. Both C(28,70)-H(17,28,29,52,53,82,93,94,117,118) bond lengths are 0.98 Å. In the ninth C site, C(29,71) is bonded in a trigonal non-coplanar geometry to one C(17); one H(30,95); and two equivalent H(31,32,96,97) atoms. The C(29,71)-C(17) bond length is 1.58 Å. The C(29,71)-H(30,95) bond length is 0.98 Å. Both C(29,71)-H(31,32,96,97) bond lengths are 0.98 Å. In the tenth C site, C(31,73) is bonded in a trigonal non-coplanar geometry to one C(19); one H(34,99); and two equivalent H(21,22,23,33,35,45,46,47,86,87,88,98,100,110,111,112) atoms. The C(31,73)-C(19) bond length is 1.51 Å. The C(31,73)-H(34,99) bond length is 0.98 Å. Both C(31,73)-H(21,22,23,33,35,45,46,47,86,87,88,98,100,110,111,112) bond lengths are 0.98 Å. In the eleventh C site, C(32,74) is bonded in a trigonal non-coplanar geometry to one C(17) and three equivalent H(36,37,38,101,102,103) atoms. The C(32,74)-C(17) bond length is 1.45 Å. All C(32,74)-H(36,37,38,101,102,103) bond lengths are 0.98 Å. In the twelfth C site, C(33,75) is bonded in a trigonal non-coplanar geometry to one C(30); one H(39,60,104,125); one H(40,61,105,126); and one H(41,42,43,106,107,108) atom. The C(33,75)-C(30) bond length is 1.50 Å. The C(33,75)-H(39,60,104,125) bond length is 0.98 Å. The C(33,75)-H(40,61,105,126) bond length is 0.98 Å. The C(33,75)-H(41,42,43,106,107,108) bond length is 0.98 Å. In the thirteenth C site, C(34,76) is bonded in a trigonal non-coplanar geometry to one C(30); one H(44,109); and two equivalent H(41,42,43,106,107,108) atoms. The C(34,76)-C(30) bond length is 1.53 Å. The C(34,76)-H(44,109) bond length is 0.98 Å. Both C(34,76)-H(41,42,43,106,107,108) bond lengths are 0.98 Å. In the fourteenth C site, C(35,77) is bonded in a trigonal non-coplanar geometry to one C(19) and three equivalent H(21,22,23,33,35,45,46,47,86,87,88,98,100,110,111,112) atoms. The C(35,77)-C(19) bond length is 1.49 Å. All C(35,77)-H(21,22,23,33,35,45,46,47,86,87,88,98,100,110,111,112) bond lengths are 0.98 Å. In the fifteenth C site, C(36,78) is bonded in a trigonal non-coplanar geometry to one C(13); one H(25,48,90,113); and two equivalent H(12,24,26,49,50,77,89,91,114,115) atoms. The C(36,78)-C(13) bond length is 1.54 Å. The C(36,78)-H(25,48,90,113) bond length is 0.98 Å. Both C(36,78)-H(12,24,26,49,50,77,89,91,114,115) bond lengths are 0.98 Å. In the sixteenth C site, C(37,79) is bonded in a trigonal non-coplanar geometry to one C(8); one H(15,16,27,51,80,81,92,116); and two equivalent H(17,28,29,52,53,82,93,94,117,118) atoms. The C(37,79)-C(8) bond length is 1.53 Å. The C(37,79)-H(15,16,27,51,80,81,92,116) bond length is 0.98 Å. Both C(37,79)-H(17,28,29,52,53,82,93,94,117,118) bond lengths are 0.98 Å. In the seventeenth C site, C(38,80) is bonded in a trigonal non-coplanar geometry to one C(20) and three equivalent H(18,20,54,55,56,83,85,119,120,121) atoms. The C(38,80)-C(20) bond length is 1.55 Å. All C(38,80)-H(18,20,54,55,56,83,85,119,120,121) bond lengths are 0.98 Å. In the eighteenth C site, C(39,81) is bonded in a trigonal non-coplanar geometry to one C(20); one H(57,122); and two equivalent H(19,58,59,84,123,124) atoms. The C(39,81)-C(20) bond length is 1.50 Å. The C(39,81)-H(57,122) bond length is 0.98 Å. Both C(39,81)-H(19,58,59,84,123,124) bond lengths are 0.98 Å. In the nineteenth C site, C(40,82) is bonded in a trigonal non-coplanar geometry to one C(30); one H(39,60,104,125); one H(40,61,105,126); and one H(62,127) atom. The C(40,82)-C(30) bond length is 1.47 Å. The C(40,82)-H(39,60,104,125) bond length is 0.98 Å. The C(40,82)-H(40,61,105,126) bond length is 0.98 Å. The C(40,82)-H(62,127) bond length is 0.98 Å. In the twentieth C site, C(41,83) is bonded in a trigonal non-coplanar geometry to one C(17); one H(63,128); one H(64,129); and one H(65,130) atom. The C(41,83)-C(17) bond length is 1.42 Å. The C(41,83)-H(63,128) bond length is 0.98 Å. The C(41,83)-H(64,129) bond length is 0.98 Å. The C(41,83)-H(65,130) bond length is 0.98 Å. In the twenty-first C site, C(43) is bonded in a distorted bent 120 degrees geometry to one C(59), one O(14), and one O(16) atom. The C(43)-C(59) bond length is 1.53 Å. The C(43)-O(14) bond length is 1.23 Å. The C(43)-O(16) bond length is 1.26 Å. In the twenty-second C site, C(44) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(1,66) atom. The C(44)-N(4) bond length is 1.31 Å. The C(44)-H(1,66) bond length is 1.05 Å. In the twenty-third C site, C(45) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(2,67) atom. The C(45)-N(4) bond length is 1.36 Å. The C(45)-H(2,67) bond length is 0.97 Å. In the twenty-fourth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(72), one O(20), and one O(21) atom. The C(48)-C(72) bond length is 1.55 Å. The C(48)-O(20) bond length is 1.25 Å. The C(48)-O(21) bond length is 1.25 Å. In the twenty-fifth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(70) atom. The C(49)-N(5) bond length is 1.33 Å. The C(49)-H(70) bond length is 0.95 Å. In the twenty-sixth C site, C(50) is bonded in a tetrahedral geometry to one C(23,65); one C(28,70); one C(37,79); and one C(52) atom. The C(50)-C(23,65) bond length is 1.52 Å. The C(50)-C(28,70) bond length is 1.51 Å. The C(50)-C(37,79) bond length is 1.53 Å. The C(50)-C(52) bond length is 1.51 Å. In the twenty-seventh C site, C(51) is bonded in a distorted bent 120 degrees geometry to one C(62), one O(17), and one O(25) atom. The C(51)-C(62) bond length is 1.53 Å. The C(51)-O(17) bond length is 1.25 Å. The C(51)-O(25) bond length is 1.26 Å. In the twenty-eighth C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(50), one O(15), and one O(18) atom. The C(52)-O(15) bond length is 1.26 Å. The C(52)-O(18) bond length is 1.26 Å. In the twenty-ninth C site, C(53) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(71) atom. The C(53)-N(6) bond length is 1.33 Å. The C(53)-H(71) bond length is 0.95 Å. In the thirtieth C site, C(54) is bonded in a distorted bent 120 degrees geometry to one C(55), one O(19), and one O(22) atom. The C(54)-C(55) bond length is 1.52 Å. The C(54)-O(19) bond length is 1.25 Å. The C(54)-O(22) bond length is 1.24 Å. In the thirty-first C site, C(55) is bonded in a tetrahedral geometry to one C(22,64); one C(27,69); one C(36,78); and one C(54) atom. The C(55)-C(22,64) bond length is 1.54 Å. The C(55)-C(27,69) bond length is 1.46 Å. The C(55)-C(36,78) bond length is 1.54 Å. In the thirty-second C site, C(58) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(74) atom. The C(58)-N(6) bond length is 1.33 Å. The C(58)-H(74) bond length is 0.95 Å. In the thirty-third C site, C(59) is bonded in a tetrahedral geometry to one C(29,71); one C(32,74); one C(41,83); and one C(43) atom. The C(59)-C(29,71) bond length is 1.58 Å. The C(59)-C(32,74) bond length is 1.45 Å. The C(59)-C(41,83) bond length is 1.42 Å. In the thirty-fourth C site, C(61) is bonded in a tetrahedral geometry to one C(26,68); one C(31,73); one C(35,77); and one C(66) atom. The C(61)-C(26,68) bond length is 1.51 Å. The C(61)-C(31,73) bond length is 1.51 Å. The C(61)-C(35,77) bond length is 1.49 Å. The C(61)-C(66) bond length is 1.55 Å. In the thirty-fifth C site, C(62) is bonded in a tetrahedral geometry to one C(25,67); one C(38,80); one C(39,81); and one C(51) atom. The C(62)-C(25,67) bond length is 1.49 Å. The C(62)-C(38,80) bond length is 1.55 Å. The C(62)-C(39,81) bond length is 1.50 Å. In the thirty-sixth C site, C(63) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(76) atom. The C(63)-N(5) bond length is 1.34 Å. The C(63)-H(76) bond length is 0.95 Å. In the thirty-seventh C site, C(66) is bonded in a distorted bent 120 degrees geometry to one C(61), one O(23), and one O(26) atom. The C(66)-O(23) bond length is 1.26 Å. The C(66)-O(26) bond length is 1.24 Å. In the thirty-eighth C site, C(72) is bonded in a tetrahedral geometry to one C(33,75); one C(34,76); one C(40,82); and one C(48) atom. The C(72)-C(33,75) bond length is 1.50 Å. The C(72)-C(34,76) bond length is 1.53 Å. The C(72)-C(40,82) bond length is 1.47 Å. There are three inequivalent N sites. In the first N site, N(4) is bonded in a 5-coordinate geometry to one Co(1), one C(4), one C(44), one C(45), and one C(5) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Co(2), one C(49), and one C(63) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Co(3), one C(53), and one C(58) atom. There are twenty-nine inequivalent H sites. In the first H site, H(1,66) is bonded in a single-bond geometry to one C(2) atom. The H(1,66)-C(2) bond length is 1.05 Å. In the second H site, H(2,67) is bonded in a single-bond geometry to one C(3) atom. The H(2,67)-C(3) bond length is 0.97 Å. In the third H site, H(3,68) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4,69) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(12,24,26,49,50,77,89,91,114,115) is bonded in a single-bond geometry to one C(22,64) atom. In the sixth H site, H(13,14,78,79) is bonded in a single-bond geometry to one C(22,64) atom. In the seventh H site, H(15,16,27,51,80,81,92,116) is bonded in a single-bond geometry to one C(23,65) atom. In the eighth H site, H(17,28,29,52,53,82,93,94,117,118) is bonded in a single-bond geometry to one C(23,65) atom. In the ninth H site, H(18,20,54,55,56,83,85,119,120,121) is bonded in a single-bond geometry to one C(25,67) atom. In the tenth H site, H(19,58,59,84,123,124) is bonded in a single-bond geometry to one C(25,67) atom. In the eleventh H site, H(21,22,23,33,35,45,46,47,86,87,88,98,100,110,111,112) is bonded in a single-bond geometry to one C(26,68) atom. In the twelfth H site, H(25,48,90,113) is bonded in a single-bond geometry to one C(27,69) atom. In the thirteenth H site, H(30,95) is bonded in a single-bond geometry to one C(29,71) atom. In the fourteenth H site, H(31,32,96,97) is bonded in a single-bond geometry to one C(29,71) atom. In the fifteenth H site, H(34,99) is bonded in a single-bond geometry to one C(31,73) atom. In the sixteenth H site, H(36,37,38,101,102,103) is bonded in a single-bond geometry to one C(32,74) atom. In the seventeenth H site, H(39,60,104,125) is bonded in a single-bond geometry to one C(33,75) atom. In the eighteenth H site, H(40,61,105,126) is bonded in a single-bond geometry to one C(33,75) atom. In the nineteenth H site, H(41,42,43,106,107,108) is bonded in a single-bond geometry to one C(33,75) atom. In the twentieth H site, H(44,109) is bonded in a single-bond geometry to one C(34,76) atom. In the twenty-first H site, H(57,122) is bonded in a single-bond geometry to one C(39,81) atom. In the twenty-second H site, H(62,127) is bonded in a single-bond geometry to one C(40,82) atom. In the twenty-third H site, H(63,128) is bonded in a single-bond geometry to one C(41,83) atom. In the twenty-fourth H site, H(64,129) is bonded in a single-bond geometry to one C(41,83) atom. In the twenty-fifth H site, H(65,130) is bonded in a single-bond geometry to one C(41,83) atom. In the twenty-sixth H site, H(70) is bonded in a single-bond geometry to one C(49) atom. In the twenty-seventh H site, H(71) is bonded in a single-bond geometry to one C(53) atom. In the twenty-eighth H site, H(74) is bonded in a single-bond geometry to one C(58) atom. In the twenty-ninth H site, H(76) is bonded in a single-bond geometry to one C(63) atom. There are thirteen inequivalent O sites. In the first O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(43) atom. In the second O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(52) atom. In the third O site, O(16) is bonded in a bent 120 degrees geometry to one Co(2) and one C(43) atom. In the fourth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(51) atom. In the fifth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(52) atom. In the sixth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(54) atom. In the seventh O site, O(20) is bonded in a bent 120 degrees geometry to one Co(3) and one C(48) atom. In the eighth O site, O(21) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(48) atom. In the ninth O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Co(3) and one C(54) atom. In the tenth O site, O(23) is bonded in a distorted bent 120 degrees geometry to one Co(3) and one C(66) atom. In the eleventh O site, O(24) is bonded in a trigonal planar geometry to one Co(1), one Co(2), and one Co(3) atom. In the twelfth O site, O(25) is bonded in a distorted bent 120 degrees geometry to one Co(3) and one C(51) atom. In the thirteenth O site, O(26) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(66) atom. In each Fe3C38N3H62O13 cluster, there are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one N(1), one O(1), one O(11), one O(2), one O(4), and one O(8) atom to form corner-sharing FeNO5 octahedra. The corner-sharing octahedral tilt angles range from 59-61°. The Fe(1)-N(1) bond length is 2.19 Å. The Fe(1)-O(1) bond length is 2.04 Å. The Fe(1)-O(11) bond length is 1.88 Å. The Fe(1)-O(2) bond length is 2.05 Å. The Fe(1)-O(4) bond length is 2.03 Å. The Fe(1)-O(8) bond length is 2.05 Å. In the second Fe site, Fe(2) is bonded to one N(2), one O(11), one O(13), one O(3), one O(5), and one O(6) atom to form corner-sharing FeNO5 octahedra. The corner-sharing octahedral tilt angles are 59°. The Fe(2)-N(2) bond length is 2.19 Å. The Fe(2)-O(11) bond length is 1.86 Å. The Fe(2)-O(13) bond length is 2.05 Å. The Fe(2)-O(3) bond length is 2.04 Å. The Fe(2)-O(5) bond length is 2.03 Å. The Fe(2)-O(6) bond length is 2.03 Å. In the third Fe site, Fe(3) is bonded to one N(3), one O(10), one O(11), one O(12), one O(7), and one O(9) atom to form corner-sharing FeNO5 octahedra. The corner-sharing octahedral tilt angles range from 59-61°. The Fe(3)-N(3) bond length is 2.17 Å. The Fe(3)-O(10) bond length is 2.04 Å. The Fe(3)-O(11) bond length is 1.90 Å. The Fe(3)-O(12) bond length is 2.05 Å. The Fe(3)-O(7) bond length is 2.05 Å. The Fe(3)-O(9) bond length is 2.07 Å. There are thirty-eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(1), and one O(3) atom. The C(1)-C(17) bond length is 1.53 Å. The C(1)-O(1) bond length is 1.23 Å. The C(1)-O(3) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,66) atom. The C(2)-N(1) bond length is 1.31 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2,67) atom. The C(3)-N(1) bond length is 1.36 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(7), and one O(8) atom. The C(6)-C(30) bond length is 1.55 Å. The C(6)-O(7) bond length is 1.25 Å. The C(6)-O(8) bond length is 1.25 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5) atom. The C(7)-N(2) bond length is 1.33 Å. The C(7)-H(5) bond length is 0.95 Å. In the sixth C site, C(8) is bonded in a tetrahedral geometry to one C(10); one C(23,65); one C(28,70); and one C(37,79) atom. The C(8)-C(10) bond length is 1.51 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(12), and one O(4) atom. The C(9)-C(20) bond length is 1.53 Å. The C(9)-O(12) bond length is 1.26 Å. The C(9)-O(4) bond length is 1.25 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(2), and one O(5) atom. The C(10)-O(2) bond length is 1.26 Å. The C(10)-O(5) bond length is 1.26 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(6) atom. The C(11)-N(3) bond length is 1.33 Å. The C(11)-H(6) bond length is 0.95 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(6), and one O(9) atom. The C(12)-C(13) bond length is 1.52 Å. The C(12)-O(6) bond length is 1.25 Å. The C(12)-O(9) bond length is 1.24 Å. In the eleventh C site, C(13) is bonded in a tetrahedral geometry to one C(12); one C(22,64); one C(27,69); and one C(36,78) atom. In the twelfth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(16)-N(3) bond length is 1.33 Å. The C(16)-H(9) bond length is 0.95 Å. In the thirteenth C site, C(17) is bonded in a tetrahedral geometry to one C(1); one C(29,71); one C(32,74); and one C(41,83) atom. In the fourteenth C site, C(19) is bonded in a tetrahedral geometry to one C(24); one C(26,68); one C(31,73); and one C(35,77) atom. The C(19)-C(24) bond length is 1.55 Å. In the fifteenth C site, C(20) is bonded in a tetrahedral geometry to one C(25,67); one C(38,80); one C(39,81); and one C(9) atom. In the sixteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(11) atom. The C(21)-N(2) bond length is 1.34 Å. The C(21)-H(11) bond length is 0.95 Å. In the seventeenth C site, C(22,64) is bonded in a trigonal non-coplanar geometry to one C(13); one H(12,24,26,49,50,77,89,91,114,115); and two equivalent H(13,14,78,79) atoms. In the eighteenth C site, C(23,65) is bonded in a trigonal non-coplanar geometry to one C(8); one H(17,28,29,52,53,82,93,94,117,118); and two equivalent H(15,16,27,51,80,81,92,116) atoms. In the nineteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(10), and one O(13) atom. The C(24)-O(10) bond length is 1.26 Å. The C(24)-O(13) bond length is 1.24 Å. In the twentieth C site, C(25,67) is bonded in a trigonal non-coplanar geometry to one C(20); one H(19,58,59,84,123,124); and two equivalent H(18,20,54,55,56,83,85,119,120,121) atoms. In the twenty-first C site, C(26,68) is bonded in a trigonal non-coplanar geometry to one C(19) and three equivalent H(21,22,23,33,35,45,46,47,86,87,88,98,100,110,111,112) atoms. In the twenty-second C site, C(27,69) is bonded in a trigonal non-coplanar geometry to one C(13); one H(25,48,90,113); and two equivalent H(12,24,26,49,50,77,89,91,114,115) atoms. In the twenty-third C site, C(28,70) is bonded in a trigonal non-coplanar geometry to one C(8); one H(15,16,27,51,80,81,92,116); and two equivalent H(17,28,29,52,53,82,93,94,117,118) atoms. In the twenty-fourth C site, C(29,71) is bonded in a trigonal non-coplanar geometry to one C(17); one H(30,95); and two equivalent H(31,32,96,97) atoms. In the twenty-fifth C site, C(30) is bonded in a tetrahedral geometry to one C(33,75); one C(34,76); one C(40,82); and one C(6) atom. In the twenty-sixth C site, C(31,73) is bonded in a trigonal non-coplanar geometry to one C(19); one H(34,99); and two equivalent H(21,22,23,33,35,45,46,47,86,87,88,98,100,110,111,112) atoms. In the twenty-seventh C site, C(32,74) is bonded in a trigonal non-coplanar geometry to one C(17) and three equivalent H(36,37,38,101,102,103) atoms. In the twenty-eighth C site, C(33,75) is bonded in a trigonal non-coplanar geometry to one C(30); one H(39,60,104,125); one H(40,61,105,126); and one H(41,42,43,106,107,108) atom. In the twenty-ninth C site, C(34,76) is bonded in a trigonal non-coplanar geometry to one C(30); one H(44,109); and two equivalent H(41,42,43,106,107,108) atoms. In the thirtieth C site, C(35,77) is bonded in a trigonal non-coplanar geometry to one C(19) and three equivalent H(21,22,23,33,35,45,46,47,86,87,88,98,100,110,111,112) atoms. In the thirty-first C site, C(36,78) is bonded in a trigonal non-coplanar geometry to one C(13); one H(25,48,90,113); and two equivalent H(12,24,26,49,50,77,89,91,114,115) atoms. In the thirty-second C site, C(37,79) is bonded in a trigonal non-coplanar geometry to one C(8); one H(15,16,27,51,80,81,92,116); and two equivalent H(17,28,29,52,53,82,93,94,117,118) atoms. In the thirty-third C site, C(38,80) is bonded in a trigonal non-coplanar geometry to one C(20) and three equivalent H(18,20,54,55,56,83,85,119,120,121) atoms. In the thirty-fourth C site, C(39,81) is bonded in a trigonal non-coplanar geometry to one C(20); one H(57,122); and two equivalent H(19,58,59,84,123,124) atoms. In the thirty-fifth C site, C(40,82) is bonded in a trigonal non-coplanar geometry to one C(30); one H(39,60,104,125); one H(40,61,105,126); and one H(62,127) atom. In the thirty-sixth C site, C(41,83) is bonded in a trigonal non-coplanar geometry to one C(17); one H(63,128); one H(64,129); and one H(65,130) atom. In the thirty-seventh C site, C(46) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3,68) atom. The C(46)-N(1) bond length is 1.33 Å. The C(46)-H(3,68) bond length is 0.96 Å. In the thirty-eighth C site, C(47) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4,69) atom. The C(47)-N(1) bond length is 1.35 Å. The C(47)-H(4,69) bond length is 1.00 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 5-coordinate geometry to one Fe(1), one C(2), one C(3), one C(46), and one C(47) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Fe(2), one C(21), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Fe(3), one C(11), and one C(16) atom. There are twenty-nine inequivalent H sites. In the first H site, H(1,66) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2,67) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3,68) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4,69) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(12,24,26,49,50,77,89,91,114,115) is bonded in a single-bond geometry to one C(22,64) atom. In the tenth H site, H(13,14,78,79) is bonded in a single-bond geometry to one C(22,64) atom. In the eleventh H site, H(15,16,27,51,80,81,92,116) is bonded in a single-bond geometry to one C(23,65) atom. In the twelfth H site, H(17,28,29,52,53,82,93,94,117,118) is bonded in a single-bond geometry to one C(23,65) atom. In the thirteenth H site, H(18,20,54,55,56,83,85,119,120,121) is bonded in a single-bond geometry to one C(25,67) atom. In the fourteenth H site, H(19,58,59,84,123,124) is bonded in a single-bond geometry to one C(25,67) atom. In the fifteenth H site, H(21,22,23,33,35,45,46,47,86,87,88,98,100,110,111,112) is bonded in a single-bond geometry to one C(26,68) atom. In the sixteenth H site, H(25,48,90,113) is bonded in a single-bond geometry to one C(27,69) atom. In the seventeenth H site, H(30,95) is bonded in a single-bond geometry to one C(29,71) atom. In the eighteenth H site, H(31,32,96,97) is bonded in a single-bond geometry to one C(29,71) atom. In the nineteenth H site, H(34,99) is bonded in a single-bond geometry to one C(31,73) atom. In the twentieth H site, H(36,37,38,101,102,103) is bonded in a single-bond geometry to one C(32,74) atom. In the twenty-first H site, H(39,60,104,125) is bonded in a single-bond geometry to one C(33,75) atom. In the twenty-second H site, H(40,61,105,126) is bonded in a single-bond geometry to one C(33,75) atom. In the twenty-third H site, H(41,42,43,106,107,108) is bonded in a single-bond geometry to one C(33,75) atom. In the twenty-fourth H site, H(44,109) is bonded in a single-bond geometry to one C(34,76) atom. In the twenty-fifth H site, H(57,122) is bonded in a single-bond geometry to one C(39,81) atom. In the twenty-sixth H site, H(62,127) is bonded in a single-bond geometry to one C(40,82) atom. In the twenty-seventh H site, H(63,128) is bonded in a single-bond geometry to one C(41,83) atom. In the twenty-eighth H site, H(64,129) is bonded in a single-bond geometry to one C(41,83) atom. In the twenty-ninth H site, H(65,130) is bonded in a single-bond geometry to one C(41,83) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(10) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Fe(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(9) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(10) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(12) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Fe(3) and one C(6) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(6) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Fe(3) and one C(12) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Fe(3) and one C(24) atom. In the eleventh O site, O(11) is bonded in a trigonal planar geometry to one Fe(1), one Fe(2), and one Fe(3) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Fe(3) and one C(9) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(24) atom. Linkers: 4 C(=C/c1ccncc1)\c1ccncc1 ,2 [C@@H]12[C@@H]3[N@@]42[C@@H]2[C@H]4[C@@H]4[N@]5([C@H]1[C@H]35)[C@H]24 ,2 [C@@H]12[C@@H]3[N@@]42[C@H]2[C@@H]4[C@H]4[N@]5([C@H]1[C@H]35)[C@@H]24 ,4 c1cnccn1. Metal clusters: 12 [Fe] ,12 [Co]. The MOF has largest included sphere 5.00 A, density 1.14 g/cm3, surface area 4971.73 m2/g, accessible volume 0.44 cm3/g