CdC27H21(N2O3)2(C3H2)3CH is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules; three 2,3-dimethyl-1,3-butadiene molecules; and two CdC27H21(N2O3)2 clusters. In each CdC27H21(N2O3)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(2), one O(3), one O(4), and one O(5) atom. The Cd(1)-N(1) bond length is 2.38 Å. The Cd(1)-N(2) bond length is 2.37 Å. The Cd(1)-O(2) bond length is 2.72 Å. The Cd(1)-O(3) bond length is 2.27 Å. The Cd(1)-O(4) bond length is 2.35 Å. The Cd(1)-O(5) bond length is 2.42 Å. There are twenty-seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(34) and one H(1) atom. The C(1)-C(34) bond length is 1.37 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(6) atom. The C(2)-C(10) bond length is 1.52 Å. The C(2)-C(11) bond length is 1.38 Å. The C(2)-C(6) bond length is 1.37 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(34), one N(3), and one O(1) atom. The C(3)-C(34) bond length is 1.50 Å. The C(3)-N(3) bond length is 1.35 Å. The C(3)-O(1) bond length is 1.23 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(31), one N(1), and one H(2) atom. The C(4)-C(31) bond length is 1.37 Å. The C(4)-N(1) bond length is 1.33 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(3) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a bent 120 degrees geometry to one C(13), one O(4), and one O(5) atom. The C(7)-C(13) bond length is 1.49 Å. The C(7)-O(4) bond length is 1.24 Å. The C(7)-O(5) bond length is 1.24 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(18), one C(29), and one C(33) atom. The C(9)-C(18) bond length is 1.37 Å. The C(9)-C(29) bond length is 1.51 Å. The C(9)-C(33) bond length is 1.37 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(3) atom. The C(10)-O(2) bond length is 1.25 Å. The C(10)-O(3) bond length is 1.25 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(11)-H(5) bond length is 0.93 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(7) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-C(16) bond length is 1.38 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(7) atom. The C(14)-H(7) bond length is 0.93 Å. In the thirteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(4), and one O(6) atom. The C(15)-C(21) bond length is 1.50 Å. The C(15)-N(4) bond length is 1.34 Å. The C(15)-O(6) bond length is 1.22 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(13) and one H(8) atom. The C(16)-H(8) bond length is 0.93 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(31) and one H(9) atom. The C(17)-C(31) bond length is 1.37 Å. The C(17)-H(9) bond length is 0.93 Å. In the sixteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(2), and one H(10) atom. The C(18)-N(2) bond length is 1.34 Å. The C(18)-H(10) bond length is 0.93 Å. In the seventeenth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(12) atom. The C(20)-C(21) bond length is 1.38 Å. The C(20)-H(12) bond length is 0.93 Å. In the eighteenth C site, C(21) is bonded in a trigonal planar geometry to one C(15), one C(20), and one C(24) atom. The C(21)-C(24) bond length is 1.39 Å. In the nineteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(26) and one H(14) atom. The C(23)-C(26) bond length is 1.37 Å. The C(23)-H(14) bond length is 0.93 Å. In the twentieth C site, C(24) is bonded in a distorted single-bond geometry to one C(21) and one H(15) atom. The C(24)-H(15) bond length is 0.93 Å. In the twenty-first C site, C(26) is bonded in a distorted trigonal planar geometry to one C(23), one N(2), and one H(17) atom. The C(26)-N(2) bond length is 1.32 Å. The C(26)-H(17) bond length is 0.93 Å. In the twenty-second C site, C(27) is bonded in a distorted trigonal non-coplanar geometry to one C(31), one N(4), one H(18), and one H(19) atom. The C(27)-C(31) bond length is 1.51 Å. The C(27)-N(4) bond length is 1.44 Å. The C(27)-H(18) bond length is 0.97 Å. The C(27)-H(19) bond length is 0.97 Å. In the twenty-third C site, C(29) is bonded in a 3-coordinate geometry to one C(9); one N(3); and two equivalent H(21,22) atoms. The C(29)-N(3) bond length is 1.45 Å. Both C(29)-H(21,22) bond lengths are 0.97 Å. In the twenty-fourth C site, C(31) is bonded in a trigonal planar geometry to one C(17), one C(27), and one C(4) atom. In the twenty-fifth C site, C(33) is bonded in a distorted single-bond geometry to one C(9) and one H(23) atom. The C(33)-H(23) bond length is 0.93 Å. In the twenty-sixth C site, C(34) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(36) atom. The C(34)-C(36) bond length is 1.37 Å. In the twenty-seventh C site, C(36) is bonded in a distorted single-bond geometry to one C(34) and one H(25) atom. The C(36)-H(25) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(4), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(18), and one C(26) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one C(15), one C(27), and one H(28) atom. The N(4)-H(28) bond length is 0.86 Å. In the fourth N site, N(3) is bonded in a distorted trigonal planar geometry to one C(29), one C(3), and one H(27) atom. The N(3)-H(27) bond length is 0.86 Å. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(27) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the twelfth H site, H(21,22) is bonded in a single-bond geometry to one C(29) atom. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one C(33) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(24) atom. In the fifteenth H site, H(25) is bonded in a single-bond geometry to one C(36) atom. In the sixteenth H site, H(27) is bonded in a single-bond geometry to one N(3) atom. In the seventeenth H site, H(28) is bonded in a single-bond geometry to one N(4) atom. In the eighteenth H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the nineteenth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the twentieth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. There are six inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Cd(1) and one C(10) atom. In the second O site, O(3) is bonded in a distorted water-like geometry to one Cd(1) and one C(10) atom. In the third O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(15) atom. In the fifth O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(7) atom. In the sixth O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one C(7) atom. Linkers: 1 O=C(NCc1cccnc1)c1ccc(-c2ccc(C(=O)NCc3cccnc3)cc2)cc1 ,2 [O]C(=O)c1ccc(-c2ccc(C(=O)NCc3cccnc3)cc2)cc1 ,1 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 5.07 A, density 1.17 g/cm3, surface area 5043.48 m2/g, accessible volume 0.35 cm3/g