Zn3(CO2)8(CH)4(C2O)2(C4H2O)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four dimethyl ether molecules, four furan molecules, and two Zn3(CO2)8 clusters. In each Zn3(CO2)8 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(10), one O(5), and one O(6) atom to form distorted corner-sharing ZnO4 tetrahedra. The corner-sharing octahedral tilt angles are 78°. The Zn(1)-O(1) bond length is 1.99 Å. The Zn(1)-O(10) bond length is 1.97 Å. The Zn(1)-O(5) bond length is 2.01 Å. The Zn(1)-O(6) bond length is 1.98 Å. In the second Zn site, Zn(2) is bonded to two equivalent O(2), two equivalent O(5), and two equivalent O(7) atoms to form corner-sharing ZnO6 octahedra. Both Zn(2)-O(2) bond lengths are 2.10 Å. Both Zn(2)-O(5) bond lengths are 2.26 Å. Both Zn(2)-O(7) bond lengths are 2.25 Å. There are four inequivalent C sites. In the first C site, C(12) is bonded in a bent 120 degrees geometry to one O(10) and one O(9) atom. The C(12)-O(10) bond length is 1.27 Å. The C(12)-O(9) bond length is 1.23 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.26 Å. In the third C site, C(6) is bonded in a bent 120 degrees geometry to one O(4) and one O(5) atom. The C(6)-O(4) bond length is 1.21 Å. The C(6)-O(5) bond length is 1.30 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(7)-O(6) bond length is 1.29 Å. The C(7)-O(7) bond length is 1.23 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth O site, O(5) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(2), and one C(6) atom. In the fifth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the sixth O site, O(7) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(7) atom. In the seventh O site, O(9) is bonded in a single-bond geometry to one C(12) atom. In the eighth O site, O(10) is bonded in a water-like geometry to one Zn(1) and one C(12) atom. Linkers: 8 [O]C(=O)c1ccc(C([O])=O)o1. Metal clusters: 2 O=[C]O[Zn]1(O[C]=O)O[C]O[Zn]2(O[C]O1)O[C]O[Zn](O[C]=O)(O[C]=O)O[C]O2. RCSR code: pcu. The MOF has largest included sphere 5.75 A, density 1.08 g/cm3, surface area 3890.40 m2/g, accessible volume 0.57 cm3/g