Zn2C32H20(NO3)3(C3H2)2CH is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules; two 2,3-dimethyl-1,3-butadiene molecules; and two Zn2C32H20(NO3)3 clusters. In each Zn2C32H20(NO3)3 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(2), one O(3), one O(6), and one O(7) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-O(2) bond length is 2.02 Å. The Zn(1)-O(3) bond length is 2.08 Å. The Zn(1)-O(6) bond length is 2.03 Å. The Zn(1)-O(7) bond length is 2.05 Å. In the second Zn site, Zn(2) is bonded in a trigonal bipyramidal geometry to one N(3), one O(1), one O(4), one O(5), and one O(8) atom. The Zn(2)-N(3) bond length is 2.02 Å. The Zn(2)-O(1) bond length is 2.07 Å. The Zn(2)-O(4) bond length is 2.02 Å. The Zn(2)-O(5) bond length is 2.03 Å. The Zn(2)-O(8) bond length is 2.06 Å. There are thirty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(2) and one H(1,4) atom. The C(3)-H(1,4) bond length is 0.95 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(1,4) atom. The C(7)-H(1,4) bond length is 0.95 Å. In the fifth C site, C(8) is bonded in a bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(8)-C(9) bond length is 1.50 Å. The C(8)-O(3) bond length is 1.26 Å. The C(8)-O(4) bond length is 1.26 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-C(14) bond length is 1.39 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(10)-H(5) bond length is 0.95 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(6) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-H(6) bond length is 0.95 Å. In the ninth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(26) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-C(26) bond length is 1.49 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(7) atom. The C(13)-H(7) bond length is 0.95 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(14)-H(8) bond length is 0.95 Å. In the twelfth C site, C(15) is bonded in a bent 120 degrees geometry to one C(16), one O(5), and one O(6) atom. The C(15)-C(16) bond length is 1.51 Å. The C(15)-O(5) bond length is 1.26 Å. The C(15)-O(6) bond length is 1.26 Å. In the thirteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-C(21) bond length is 1.40 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(9) atom. The C(17)-H(9) bond length is 0.95 Å. In the fifteenth C site, C(21) is bonded in a single-bond geometry to one C(16) and one H(12) atom. The C(21)-H(12) bond length is 0.95 Å. In the sixteenth C site, C(22) is bonded in a bent 120 degrees geometry to one C(23), one O(7), and one O(8) atom. The C(22)-C(23) bond length is 1.51 Å. The C(22)-O(7) bond length is 1.27 Å. The C(22)-O(8) bond length is 1.25 Å. In the seventeenth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.36 Å. The C(23)-C(28) bond length is 1.37 Å. In the eighteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(13) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(13) bond length is 0.95 Å. In the nineteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one C(26), and one H(14) atom. The C(25)-C(26) bond length is 1.37 Å. The C(25)-H(14) bond length is 0.95 Å. In the twentieth C site, C(26) is bonded in a trigonal planar geometry to one C(12), one C(25), and one C(27) atom. The C(26)-C(27) bond length is 1.38 Å. In the twenty-first C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(15) atom. The C(27)-H(15) bond length is 0.95 Å. In the twenty-second C site, C(28) is bonded in a distorted single-bond geometry to one C(23) and one H(16) atom. The C(28)-H(16) bond length is 0.95 Å. In the twenty-third C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(17,20) atom. The C(29)-N(1) bond length is 1.33 Å. The C(29)-H(17,20) bond length is 0.95 Å. In the twenty-fourth C site, C(30) is bonded in a distorted single-bond geometry to one C(31) and one H(18) atom. The C(30)-C(31) bond length is 1.37 Å. The C(30)-H(18) bond length is 0.95 Å. In the twenty-fifth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(34) atom. The C(31)-C(32) bond length is 1.38 Å. The C(31)-C(34) bond length is 1.53 Å. In the twenty-sixth C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(19) atom. The C(32)-H(19) bond length is 0.95 Å. In the twenty-seventh C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(17,20) atom. The C(33)-N(1) bond length is 1.33 Å. The C(33)-H(17,20) bond length is 0.95 Å. In the twenty-eighth C site, C(34) is bonded in a 3-coordinate geometry to one C(31), one N(2), and one O(9) atom. The C(34)-N(2) bond length is 1.34 Å. The C(34)-O(9) bond length is 1.25 Å. In the twenty-ninth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(21) atom. The C(35)-N(3) bond length is 1.34 Å. The C(35)-H(21) bond length is 0.95 Å. In the thirtieth C site, C(37) is bonded in a distorted single-bond geometry to one C(38) and one N(2) atom. The C(37)-C(38) bond length is 1.35 Å. The C(37)-N(2) bond length is 1.40 Å. In the thirty-first C site, C(38) is bonded in a distorted trigonal planar geometry to one C(37), one C(39), and one H(23) atom. The C(38)-C(39) bond length is 1.38 Å. The C(38)-H(23) bond length is 0.95 Å. In the thirty-second C site, C(39) is bonded in a distorted bent 120 degrees geometry to one C(38), one N(3), and one H(24) atom. The C(39)-N(3) bond length is 1.33 Å. The C(39)-H(24) bond length is 0.95 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(29), and one C(33) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(35), and one C(39) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one C(34), one C(37), and one H(25) atom. The N(2)-H(25) bond length is 0.88 Å. There are eighteen inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(17,20) is bonded in a single-bond geometry to one C(29) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(28) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(25) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(35) atom. In the twelfth H site, H(23) is bonded in a single-bond geometry to one C(38) atom. In the thirteenth H site, H(24) is bonded in a single-bond geometry to one C(39) atom. In the fourteenth H site, H(25) is bonded in a single-bond geometry to one N(2) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(32) atom. In the seventeenth H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the eighteenth H site, H(15) is bonded in a single-bond geometry to one C(27) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(8) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(15) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(15) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(22) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(22) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(34) atom. Linkers: 4 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cc2)cc1 ,2 O=C(Nc1ccncc1)c1ccncc1. Metal clusters: 2 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 8.00 A, density 0.79 g/cm3, surface area 4429.73 m2/g, accessible volume 0.69 cm3/g