CdC10H8(NO)4(CH)2 is Indium-derived structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules and sixteen CdC10H8(NO)4 clusters. In each CdC10H8(NO)4 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.25 Å. The Cd(1)-N(3) bond length is 2.19 Å. The Cd(1)-O(1) bond length is 2.61 Å. The Cd(1)-O(2) bond length is 2.24 Å. The Cd(1)-O(3) bond length is 2.46 Å. The Cd(1)-O(4) bond length is 2.28 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one N(2) atom. The C(1)-C(2) bond length is 1.36 Å. The C(1)-C(4) bond length is 1.43 Å. The C(1)-N(2) bond length is 1.37 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(2) atom. The C(3)-N(1) bond length is 1.32 Å. The C(3)-N(2) bond length is 1.32 Å. The C(3)-H(2) bond length is 0.93 Å. In the third C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one H(1) atom. The C(2)-N(1) bond length is 1.36 Å. The C(2)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(4)-H(3) bond length is 0.93 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one N(4) atom. The C(7)-C(10) bond length is 1.45 Å. The C(7)-C(8) bond length is 1.36 Å. The C(7)-N(4) bond length is 1.38 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one N(3), and one H(5) atom. The C(8)-N(3) bond length is 1.37 Å. The C(8)-H(5) bond length is 0.93 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(6) atom. The C(9)-N(3) bond length is 1.32 Å. The C(9)-N(4) bond length is 1.33 Å. The C(9)-H(6) bond length is 0.93 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(10)-H(7) bond length is 0.93 Å. In the ninth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(6)-O(3) bond length is 1.25 Å. The C(6)-O(4) bond length is 1.30 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(12)-O(1) bond length is 1.23 Å. The C(12)-O(2) bond length is 1.26 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(9) atom. The N(2)-H(9) bond length is 0.86 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(8), and one C(9) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(10) atom. The N(4)-H(10) bond length is 0.86 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one N(2) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one N(4) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(6) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1) and one C(12) atom. In the third O site, O(4) is bonded in an L-shaped geometry to one Cd(1) and one C(6) atom. In the fourth O site, O(1) is bonded in a single-bond geometry to one Cd(1) and one C(12) atom. Linkers: 4 [O]C(=O)/C=C/C1=CN([Cd]2(OC(=O)/C=C/c3cnc[nH]3)(N3[CH]NC(/C=C/C([O])=O)=C3)O[C](/C=C/c3cnc[nH]3)O2)[CH]N1. Metal clusters: 4 O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 7.46 A, density 1.31 g/cm3, surface area 4103.47 m2/g, accessible volume 0.44 cm3/g