(NiC12H8(NO2)2)2(CH)6(C3H2)8C2OC4H2O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules; eight 2,3-dimethyl-1,3-butadiene molecules; two 2-methoxypropene molecules; two dimethyl ether molecules; and three NiC12H8(NO2)2 clusters. In one of the NiC12H8(NO2)2 clusters, Ni(1) is bonded in an octahedral geometry to one N(1), one N(2), one O(2), one O(5), one O(6), and one O(9) atom. The Ni(1)-N(1) bond length is 2.09 Å. The Ni(1)-N(2) bond length is 2.10 Å. The Ni(1)-O(2) bond length is 2.13 Å. The Ni(1)-O(5) bond length is 2.02 Å. The Ni(1)-O(6) bond length is 2.16 Å. The Ni(1)-O(9) bond length is 2.04 Å. There are twelve inequivalent C sites. In the first C site, C(43) is bonded in a trigonal planar geometry to one C(29), one C(30), and one C(54) atom. The C(43)-C(29) bond length is 1.41 Å. The C(43)-C(30) bond length is 1.48 Å. The C(43)-C(54) bond length is 1.38 Å. In the second C site, C(44) is bonded in a distorted single-bond geometry to one C(51) and one H(11) atom. The C(44)-C(51) bond length is 1.38 Å. The C(44)-H(11) bond length is 0.93 Å. In the third C site, C(51) is bonded in a trigonal planar geometry to one C(12), one C(23), and one C(44) atom. The C(51)-C(12) bond length is 1.47 Å. The C(51)-C(23) bond length is 1.37 Å. In the fourth C site, C(54) is bonded in a distorted single-bond geometry to one C(43) and one H(35,37) atom. The C(54)-H(35,37) bond length is 0.93 Å. In the fifth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(36) atom. The C(2)-N(2) bond length is 1.31 Å. The C(2)-H(36) bond length is 0.93 Å. In the sixth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(51), one O(2), and one O(6) atom. The C(12)-O(2) bond length is 1.27 Å. The C(12)-O(6) bond length is 1.27 Å. In the seventh C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(18) atom. The C(16)-N(2) bond length is 1.32 Å. The C(16)-H(18) bond length is 0.93 Å. In the eighth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(27) atom. The C(19)-N(1) bond length is 1.35 Å. The C(19)-H(27) bond length is 0.93 Å. In the ninth C site, C(23) is bonded in a distorted single-bond geometry to one C(51) and one H(28) atom. The C(23)-H(28) bond length is 0.93 Å. In the tenth C site, C(29) is bonded in a single-bond geometry to one C(43) and one H(35,37) atom. The C(29)-H(35,37) bond length is 0.93 Å. In the eleventh C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(43), one O(5), and one O(9) atom. The C(30)-O(5) bond length is 1.28 Å. The C(30)-O(9) bond length is 1.25 Å. In the twelfth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(37)-N(1) bond length is 1.33 Å. The C(37)-H(8) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(19), and one C(37) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ni(1), one C(16), and one C(2) atom. There are seven inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(37) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(44) atom. In the third H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(27) is bonded in a single-bond geometry to one C(19) atom. In the fifth H site, H(28) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(35,37) is bonded in a single-bond geometry to one C(54) atom. In the seventh H site, H(36) is bonded in a single-bond geometry to one C(2) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in an L-shaped geometry to one Ni(1) and one C(12) atom. In the second O site, O(5) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(30) atom. In the third O site, O(6) is bonded in an L-shaped geometry to one Ni(1) and one C(12) atom. In the fourth O site, O(9) is bonded in a linear geometry to one Ni(1) and one C(30) atom. In two of the NiC12H8(NO2)2 clusters, Ni(2) is bonded in a rectangular see-saw-like geometry to one N(3), one N(4), one O(1), and one O(7) atom. The Ni(2)-N(3) bond length is 2.09 Å. The Ni(2)-N(4) bond length is 2.09 Å. The Ni(2)-O(1) bond length is 2.07 Å. The Ni(2)-O(7) bond length is 2.05 Å. There are twelve inequivalent C sites. In the first C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(1), and one O(10) atom. The C(38)-C(14) bond length is 1.52 Å. The C(38)-O(1) bond length is 1.24 Å. The C(38)-O(10) bond length is 1.26 Å. In the second C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(3), and one O(7) atom. The C(40)-C(15) bond length is 1.51 Å. The C(40)-O(3) bond length is 1.27 Å. The C(40)-O(7) bond length is 1.25 Å. In the third C site, C(41) is bonded in a distorted single-bond geometry to one C(14) and one H(2) atom. The C(41)-C(14) bond length is 1.36 Å. The C(41)-H(2) bond length is 0.93 Å. In the fourth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(24) atom. The C(42)-N(4) bond length is 1.34 Å. The C(42)-H(24) bond length is 0.93 Å. In the fifth C site, C(45) is bonded in a distorted single-bond geometry to one C(15) and one H(23) atom. The C(45)-C(15) bond length is 1.37 Å. The C(45)-H(23) bond length is 0.93 Å. In the sixth C site, C(49) is bonded in a 2-coordinate geometry to one N(3) and one H(19) atom. The C(49)-N(3) bond length is 1.33 Å. The C(49)-H(19) bond length is 0.93 Å. In the seventh C site, C(53) is bonded in a distorted single-bond geometry to one C(15) and one H(7) atom. The C(53)-C(15) bond length is 1.37 Å. The C(53)-H(7) bond length is 0.93 Å. In the eighth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(34) atom. The C(6)-N(4) bond length is 1.36 Å. The C(6)-H(34) bond length is 0.93 Å. In the ninth C site, C(14) is bonded in a trigonal planar geometry to one C(25), one C(38), and one C(41) atom. The C(14)-C(25) bond length is 1.34 Å. In the tenth C site, C(15) is bonded in a trigonal planar geometry to one C(40), one C(45), and one C(53) atom. In the eleventh C site, C(25) is bonded in a single-bond geometry to one C(14) and one H(20) atom. The C(25)-H(20) bond length is 0.93 Å. In the twelfth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(5) atom. The C(33)-N(3) bond length is 1.34 Å. The C(33)-H(5) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Ni(2), one C(33), and one C(49) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Ni(2), one C(42), and one C(6) atom. There are eight inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(41) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(33) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(53) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(49) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the sixth H site, H(23) is bonded in a single-bond geometry to one C(45) atom. In the seventh H site, H(24) is bonded in a single-bond geometry to one C(42) atom. In the eighth H site, H(34) is bonded in a single-bond geometry to one C(6) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ni(2) and one C(38) atom. In the second O site, O(3) is bonded in a single-bond geometry to one C(40) atom. In the third O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Ni(2) and one C(40) atom. In the fourth O site, O(10) is bonded in a single-bond geometry to one C(38) atom. Linkers: 1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]#[C].[C]#[C].[C]/[C]=C\[C]=[C].[C]/[C]=[C]\[C]C(=[C])C([C])=[C].[C]=C[C]C1=C[CH]N([Ni@@]([N])(OC(=O)c2ccc(O[C]=[CH])cc2)OC(=O)c2ccc(Oc3ccc(C([O])=O)cc3)cc2)C=C1.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[C][CH].[C]N([CH])[Ni](O[C]=O)O[C]=O.[C][C]=[C].[C][O].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N][Ni].[Ni].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][C]=O ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C]C1=C[CH]N([Ni])C=C1.[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]#[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[C][CH]C=[C].[C]C(=[CH])[O].[C]N([C])[Ni](OC(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1)OC(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1.[C][CH].[C][CH].[C][C]/C=[C]\[C].[C][N][Ni]N=[CH].[C][O].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[Ni].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=C/[C]=[C]/[O].[C]=C[CH].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[CH].[C]C=[CH].[C]N([Ni])[C]=[C].[C]N=[CH].[C]N=[CH].[C][C].[C][C].[C][C].[C][C].[C][C]=[CH].[C][C][C].[C][O].[C][O].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N][Ni]([N])([O])O[C]=O.[Ni].[Ni].[Ni].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O ,1 O=[C]O[Ni].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH][C]=[CH].[CH][C]=[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]=C[CH].[C]=C[C]c1ccncc1.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[C]/[C]=[C]\[CH].[C]C(=[C])[C]=[CH].[C]N([CH])[Ni](OC(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1)OC(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1.[C]N=[C].[C][C]=[C].[C][O].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N][Ni].[Ni].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=N[Ni]([O])[O].[CH]=[C]Oc1ccc(C(=O)O[Ni]([N])([N])OC(=O)c2ccc(Oc3ccc(C([O])=O)cc3)cc2)cc1.[CH]C(=[CH])[C]/[C]=C\[C]C1=C[CH]N([Ni])C=C1.[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]/C=C(\[C])O[C]=[CH].[C]=C[C]=[CH].[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[CH].[C]=[C]C(=[C])[CH].[C]N=[CH].[C][C]C(=[C])[CH].[C][O].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[Ni].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][C]=O. Metal clusters: 1 [C]1O[Ni]2(O1)O[C]O[Ni]1(O[C]O1)O[C]O2. The MOF has largest included sphere 5.36 A, density 1.20 g/cm3, surface area 5000.62 m2/g, accessible volume 0.29 cm3/g