Fe2P3H3(CO8)2 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form FeO6 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The Fe(1)-O(1) bond length is 1.90 Å. The Fe(1)-O(2) bond length is 1.96 Å. The Fe(1)-O(3) bond length is 1.97 Å. The Fe(1)-O(4) bond length is 2.02 Å. The Fe(1)-O(5) bond length is 2.09 Å. The Fe(1)-O(6) bond length is 2.12 Å. In the second Fe site, Fe(2) is bonded to one O(10), one O(11), one O(12), one O(7), one O(8), and one O(9) atom to form FeO6 octahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. The Fe(2)-O(10) bond length is 1.97 Å. The Fe(2)-O(11) bond length is 2.14 Å. The Fe(2)-O(12) bond length is 2.12 Å. The Fe(2)-O(7) bond length is 1.94 Å. The Fe(2)-O(8) bond length is 1.94 Å. The Fe(2)-O(9) bond length is 1.97 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(12) and one O(5) atom. The C(1)-O(12) bond length is 1.24 Å. The C(1)-O(5) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(6) atom. The C(2)-O(11) bond length is 1.25 Å. The C(2)-O(6) bond length is 1.26 Å. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(10), one O(13), one O(4), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Fe(1)O6 octahedra and corners with two equivalent Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 34-41°. The P(1)-O(10) bond length is 1.52 Å. The P(1)-O(13) bond length is 1.59 Å. The P(1)-O(4) bond length is 1.53 Å. The P(1)-O(8) bond length is 1.51 Å. In the second P site, P(2) is bonded to one O(1), one O(14), one O(3), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Fe(2)O6 octahedra and corners with two equivalent Fe(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 11-41°. The P(2)-O(1) bond length is 1.51 Å. The P(2)-O(14) bond length is 1.58 Å. The P(2)-O(3) bond length is 1.52 Å. The P(2)-O(9) bond length is 1.51 Å. In the third P site, P(3) is bonded to one O(15), one O(16), one O(2), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Fe(1)O6 octahedra and  a cornercorner with one Fe(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 22-50°. The P(3)-O(15) bond length is 1.60 Å. The P(3)-O(16) bond length is 1.49 Å. The P(3)-O(2) bond length is 1.54 Å. The P(3)-O(7) bond length is 1.51 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(13) atom. The H(1)-O(13) bond length is 0.82 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(14) atom. The H(2)-O(14) bond length is 0.82 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(15) atom. The H(3)-O(15) bond length is 0.82 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Fe(1) and one P(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Fe(1) and one P(3) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Fe(1) and one P(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Fe(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Fe(1) and one C(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Fe(1) and one C(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Fe(2) and one P(3) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Fe(2) and one P(1) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Fe(2) and one P(2) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Fe(2) and one P(1) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(2) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Fe(2) and one C(1) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one P(1) and one H(1) atom. In the fourteenth O site, O(14) is bonded in a water-like geometry to one P(2) and one H(2) atom. In the fifteenth O site, O(15) is bonded in a water-like geometry to one P(3) and one H(3) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one P(3) atom. Linkers: 4 [O]C(=O)C([O])=O. Metal clusters: 8 [Fe]. The MOF has largest included sphere 4.04 A, density 1.90 g/cm3, surface area 2756.37 m2/g, accessible volume 0.21 cm3/g