Cu2C37H34(NO)11(C3H2)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 2,3-dimethyl-1,3-butadiene molecules and one Cu2C37H34(NO)11 cluster. In the Cu2C37H34(NO)11 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square pyramidal geometry to one O(1), one O(10), one O(2), one O(5), and one O(7) atom. The Cu(1)-O(1) bond length is 1.92 Å. The Cu(1)-O(10) bond length is 2.35 Å. The Cu(1)-O(2) bond length is 1.91 Å. The Cu(1)-O(5) bond length is 1.97 Å. The Cu(1)-O(7) bond length is 1.93 Å. In the second Cu site, Cu(2) is bonded in a square pyramidal geometry to one O(3), one O(4), one O(6), one O(8), and one O(9) atom. The Cu(2)-O(3) bond length is 2.04 Å. The Cu(2)-O(4) bond length is 1.97 Å. The Cu(2)-O(6) bond length is 1.96 Å. The Cu(2)-O(8) bond length is 1.99 Å. The Cu(2)-O(9) bond length is 2.17 Å. There are thirty-seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.31 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.43 Å. The C(2)-H(2) bond length is 0.95 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.35 Å. The C(3)-C(8) bond length is 1.45 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(4) bond length is 0.95 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(2), and one H(5) atom. The C(6)-C(7) bond length is 1.37 Å. The C(6)-N(2) bond length is 1.32 Å. The C(6)-H(5) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(6) atom. The C(7)-C(8) bond length is 1.38 Å. The C(7)-H(6) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.36 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(10)-N(2) bond length is 1.32 Å. The C(10)-H(8) bond length is 0.95 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(11)-N(3) bond length is 1.30 Å. The C(11)-H(9) bond length is 0.95 Å. In the twelfth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(12) atom. The C(15)-N(3) bond length is 1.30 Å. The C(15)-H(12) bond length is 0.95 Å. In the thirteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(13) atom. The C(16)-N(4) bond length is 1.36 Å. The C(16)-H(13) bond length is 0.95 Å. In the fourteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(16) atom. The C(20)-N(4) bond length is 1.30 Å. The C(20)-H(16) bond length is 0.95 Å. In the fifteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(17) atom. The C(21)-N(5) bond length is 1.31 Å. The C(21)-H(17) bond length is 0.95 Å. In the sixteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(20) atom. The C(25)-N(5) bond length is 1.33 Å. The C(25)-H(20) bond length is 0.95 Å. In the seventeenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(21) atom. The C(26)-N(6) bond length is 1.32 Å. The C(26)-H(21) bond length is 0.95 Å. In the eighteenth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(24) atom. The C(30)-N(6) bond length is 1.37 Å. The C(30)-H(24) bond length is 0.95 Å. In the nineteenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(25) atom. The C(31)-N(7) bond length is 1.31 Å. The C(31)-H(25) bond length is 0.95 Å. In the twentieth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(28) atom. The C(35)-N(7) bond length is 1.30 Å. The C(35)-H(28) bond length is 0.95 Å. In the twenty-first C site, C(36) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(29) atom. The C(36)-N(8) bond length is 1.32 Å. The C(36)-H(29) bond length is 0.95 Å. In the twenty-second C site, C(40) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(32) atom. The C(40)-N(8) bond length is 1.30 Å. The C(40)-H(32) bond length is 0.95 Å. In the twenty-third C site, C(41) is bonded in a distorted trigonal planar geometry to one C(42), one N(9), and one H(35) atom. The C(41)-C(42) bond length is 1.35 Å. The C(41)-N(9) bond length is 1.36 Å. The C(41)-H(35) bond length is 0.95 Å. In the twenty-fourth C site, C(42) is bonded in a distorted single-bond geometry to one C(41), one C(43), and one H(36) atom. The C(42)-C(43) bond length is 1.36 Å. The C(42)-H(36) bond length is 0.95 Å. In the twenty-fifth C site, C(43) is bonded in a trigonal planar geometry to one C(42), one C(43), and one C(44) atom. The C(43)-C(43) bond length is 1.65 Å. The C(43)-C(44) bond length is 1.35 Å. In the twenty-sixth C site, C(44) is bonded in a distorted single-bond geometry to one C(43) and one H(37) atom. The C(44)-H(37) bond length is 0.95 Å. In the twenty-seventh C site, C(45) is bonded in a 2-coordinate geometry to one N(9) and one H(38) atom. The C(45)-N(9) bond length is 1.36 Å. The C(45)-H(38) bond length is 0.95 Å. In the twenty-eighth C site, C(46) is bonded in a 4-coordinate geometry to one C(47), one N(10), one H(34), one H(39), and one O(10) atom. The C(46)-C(47) bond length is 1.35 Å. The C(46)-N(10) bond length is 1.35 Å. The C(46)-H(34) bond length is 1.09 Å. The C(46)-H(39) bond length is 0.95 Å. The C(46)-O(10) bond length is 1.15 Å. In the twenty-ninth C site, C(47) is bonded in a 5-coordinate geometry to one C(46), one C(48), one H(33), one H(34), and one H(40) atom. The C(47)-C(48) bond length is 1.36 Å. The C(47)-H(33) bond length is 1.47 Å. The C(47)-H(34) bond length is 1.21 Å. The C(47)-H(40) bond length is 0.95 Å. In the thirtieth C site, C(48) is bonded in a trigonal planar geometry to one C(47), one C(49), and one C(53) atom. The C(48)-C(49) bond length is 1.36 Å. The C(48)-C(53) bond length is 1.46 Å. In the thirty-first C site, C(49) is bonded in a distorted trigonal planar geometry to one C(48), one C(50), and one H(41) atom. The C(49)-C(50) bond length is 1.34 Å. The C(49)-H(41) bond length is 0.95 Å. In the thirty-second C site, C(50) is bonded in a 4-coordinate geometry to one C(49), one N(10), one H(38), and one H(42) atom. The C(50)-N(10) bond length is 1.35 Å. The C(50)-H(38) bond length is 1.21 Å. The C(50)-H(42) bond length is 0.95 Å. In the thirty-third C site, C(51) is bonded in a distorted trigonal planar geometry to one C(52), one N(11), and one H(43) atom. The C(51)-C(52) bond length is 1.35 Å. The C(51)-N(11) bond length is 1.36 Å. The C(51)-H(43) bond length is 0.95 Å. In the thirty-fourth C site, C(52) is bonded in a distorted single-bond geometry to one C(51), one C(53), and one H(44) atom. The C(52)-C(53) bond length is 1.35 Å. The C(52)-H(44) bond length is 0.95 Å. In the thirty-fifth C site, C(53) is bonded in a trigonal planar geometry to one C(48), one C(52), and one C(54) atom. The C(53)-C(54) bond length is 1.36 Å. In the thirty-sixth C site, C(54) is bonded in a distorted single-bond geometry to one C(53), one C(55), and one H(45) atom. The C(54)-C(55) bond length is 1.36 Å. The C(54)-H(45) bond length is 0.95 Å. In the thirty-seventh C site, C(55) is bonded in a distorted trigonal planar geometry to one C(54), one N(11), and one H(46) atom. The C(55)-N(11) bond length is 1.35 Å. The C(55)-H(46) bond length is 0.95 Å. There are eleven inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(5), and one O(1) atom. The N(1)-O(1) bond length is 1.34 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(6), and one O(8) atom. The N(2)-O(8) bond length is 1.28 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(11), one C(15), and one O(2) atom. The N(3)-O(2) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(16), one C(20), and one O(3) atom. The N(4)-O(3) bond length is 1.34 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(21), one C(25), and one O(4) atom. The N(5)-O(4) bond length is 1.33 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(26), one C(30), and one O(5) atom. The N(6)-O(5) bond length is 1.31 Å. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(31), one C(35), and one O(6) atom. The N(7)-O(6) bond length is 1.37 Å. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(36), one C(40), and one O(7) atom. The N(8)-O(7) bond length is 1.37 Å. In the ninth N site, N(9) is bonded in a distorted T-shaped geometry to one C(41), one C(45), and one O(9) atom. The N(9)-O(9) bond length is 1.47 Å. In the tenth N site, N(10) is bonded in a 4-coordinate geometry to one C(46), one C(50), one H(38), and one O(9) atom. The N(10)-H(38) bond length is 1.48 Å. The N(10)-O(9) bond length is 1.45 Å. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one C(51), one C(55), and one O(11) atom. The N(11)-O(11) bond length is 1.35 Å. There are thirty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(24) is bonded in a single-bond geometry to one C(30) atom. In the seventeenth H site, H(25) is bonded in a single-bond geometry to one C(31) atom. In the eighteenth H site, H(28) is bonded in a single-bond geometry to one C(35) atom. In the nineteenth H site, H(29) is bonded in a single-bond geometry to one C(36) atom. In the twentieth H site, H(32) is bonded in a single-bond geometry to one C(40) atom. In the twenty-first H site, H(33) is bonded in a single-bond geometry to one C(47) and one O(10) atom. The H(33)-O(10) bond length is 0.85 Å. In the twenty-second H site, H(34) is bonded in a distorted single-bond geometry to one C(46), one C(47), and one O(10) atom. The H(34)-O(10) bond length is 0.85 Å. In the twenty-third H site, H(35) is bonded in a single-bond geometry to one C(41) atom. In the twenty-fourth H site, H(36) is bonded in a single-bond geometry to one C(42) atom. In the twenty-fifth H site, H(37) is bonded in a single-bond geometry to one C(44) atom. In the twenty-sixth H site, H(38) is bonded in a 3-coordinate geometry to one C(45), one C(50), and one N(10) atom. In the twenty-seventh H site, H(39) is bonded in a 2-coordinate geometry to one C(46) and one O(10) atom. The H(39)-O(10) bond length is 1.09 Å. In the twenty-eighth H site, H(40) is bonded in a single-bond geometry to one C(47) atom. In the twenty-ninth H site, H(41) is bonded in a single-bond geometry to one C(49) atom. In the thirtieth H site, H(42) is bonded in a single-bond geometry to one C(50) atom. In the thirty-first H site, H(43) is bonded in a single-bond geometry to one C(51) atom. In the thirty-second H site, H(44) is bonded in a single-bond geometry to one C(52) atom. In the thirty-third H site, H(45) is bonded in a single-bond geometry to one C(54) atom. In the thirty-fourth H site, H(46) is bonded in a single-bond geometry to one C(55) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one N(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one N(3) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cu(2) and one N(4) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(2) and one N(5) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one N(6) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(2) and one N(7) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one N(8) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Cu(2) and one N(2) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Cu(2), one N(10), and one N(9) atom. In the tenth O site, O(10) is bonded in a distorted water-like geometry to one Cu(1), one C(46), one H(33), one H(34), and one H(39) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one N(11) atom. Linkers: 2 O.O.[CH]=[C]C1=C[CH]N(ON2[CH]C=C(C3=C[CH]N(ON4[CH]C=C(C5=C[CH]N([O])C=C5)C=C4)C=C3)C=C2)C=C1.[O]N1[CH]C=C(C2=C[CH]N(O[Cu](ON3[CH]C=[C]C=C3)(ON3[CH]C=C(c4cc[n+]([O-])cc4)C=C3)ON3[CH]C=C(c4cc[n+]([O-])cc4)C=C3)C=C2)C=C1.[O]N1[CH]C=C(C2=C[CH]N(O[Cu](ON3[CH]C=[C][C]=C3)(ON3[CH]C=C(c4cc[n+]([O-])cc4)C=C3)ON3[CH]C=C(c4cc[n+]([O-])cc4)C=C3)C=C2)C=C1 ,1 O.O.[CH].[CH].[CH]/C(=C\C=N\ON1[CH]C=C(C2=C[CH]N(O/N=C/C=C(\[CH])C3=C[CH]N([O])C=C3)C=C2)C=C1)C1=C[CH]N([O])C=C1.[O]N1[CH]C=C(C2=C[CH]N(O[Cu](ON3[CH]C=C(c4cc[n+]([O-])cc4)C=C3)(ON3[CH]C=C(c4cc[n+]([O-])cc4)C=C3)ON3[CH]C=C(c4cc[n+]([O-])cc4)C=C3)C=C2)C=C1.[O]N1[CH]C=C(C2=C[CH]N(O[Cu](ON3[CH]C=C(c4cc[n+]([O-])cc4)C=C3)(ON3[CH]C=C(c4cc[n+]([O-])cc4)C=C3)ON3[CH]C=C(c4cc[n+]([O-])cc4)C=C3)C=C2)C=C1. Metal clusters: 2 [O][Cu]([O])([O])([O])O. The MOF has largest included sphere 7.56 A, density 0.97 g/cm3, surface area 4531.18 m2/g, accessible volume 0.52 cm3/g