ZnC18H8(NO2)4 crystallizes in the cubic I4_132 space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted tetrahedral geometry to two equivalent O(2) and two equivalent O(6) atoms. Both Zn(1)-O(2) bond lengths are 1.96 Å. Both Zn(1)-O(6) bond lengths are 1.97 Å. In the second Zn site, Zn(2) is bonded in a distorted tetrahedral geometry to two equivalent O(1) and two equivalent O(7) atoms. Both Zn(2)-O(1) bond lengths are 1.95 Å. Both Zn(2)-O(7) bond lengths are 1.91 Å. There are eighteen inequivalent C sites. In the first C site, C(8) is bonded in a trigonal planar geometry to one C(18), one C(2), and one C(5) atom. The C(8)-C(18) bond length is 1.55 Å. The C(8)-C(2) bond length is 1.32 Å. The C(8)-C(5) bond length is 1.40 Å. In the second C site, C(9) is bonded in a distorted trigonal planar geometry to one C(13), one C(7), and one H(6) atom. The C(9)-C(13) bond length is 1.39 Å. The C(9)-C(7) bond length is 1.39 Å. The C(9)-H(6) bond length is 0.93 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one C(16), one C(8), and one H(2) atom. The C(2)-C(16) bond length is 1.40 Å. The C(2)-H(2) bond length is 0.93 Å. In the fourth C site, C(3) is bonded in a bent 120 degrees geometry to one C(16), one O(3), and one O(6) atom. The C(3)-C(16) bond length is 1.49 Å. The C(3)-O(3) bond length is 1.23 Å. The C(3)-O(6) bond length is 1.25 Å. In the fifth C site, C(4) is bonded in a trigonal planar geometry to one N(1) and two equivalent N(3) atoms. The C(4)-N(1) bond length is 1.34 Å. There is one shorter (1.34 Å) and one longer (1.37 Å) C(4)-N(3) bond length. In the sixth C site, C(5) is bonded in a distorted single-bond geometry to one C(1), one C(8), and one H(4) atom. The C(5)-C(1) bond length is 1.39 Å. The C(5)-H(4) bond length is 0.93 Å. In the seventh C site, C(6) is bonded in a single-bond geometry to one C(11) and one H(5) atom. The C(6)-C(11) bond length is 1.34 Å. The C(6)-H(5) bond length is 0.93 Å. In the eighth C site, C(7) is bonded in a distorted single-bond geometry to one C(9) and one N(1) atom. The C(7)-N(1) bond length is 1.37 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(1), one C(16), and one H(7) atom. The C(10)-C(1) bond length is 1.36 Å. The C(10)-C(16) bond length is 1.40 Å. The C(10)-H(7) bond length is 0.93 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one C(12), one C(17), and one C(6) atom. The C(11)-C(12) bond length is 1.42 Å. The C(11)-C(17) bond length is 1.52 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(8) atom. The C(12)-C(13) bond length is 1.34 Å. The C(12)-H(8) bond length is 0.93 Å. In the twelfth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(15), and one C(9) atom. The C(13)-C(15) bond length is 1.45 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one N(4) and two equivalent N(2) atoms. The C(14)-N(4) bond length is 1.34 Å. There is one shorter (1.32 Å) and one longer (1.36 Å) C(14)-N(2) bond length. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(2), and one O(4) atom. The C(15)-O(2) bond length is 1.30 Å. The C(15)-O(4) bond length is 1.24 Å. In the fifteenth C site, C(16) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(3) atom. In the sixteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(1), and one O(5) atom. The C(17)-O(1) bond length is 1.21 Å. The C(17)-O(5) bond length is 1.35 Å. In the seventeenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(7), and one O(8) atom. The C(18)-O(7) bond length is 1.26 Å. The C(18)-O(8) bond length is 1.19 Å. In the eighteenth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(10), one C(5), and one N(4) atom. The C(1)-N(4) bond length is 1.37 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(4), one C(7), and one H(1) atom. The N(1)-H(1) bond length is 0.86 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent C(14) atoms. In the third N site, N(3) is bonded in a bent 120 degrees geometry to two equivalent C(4) atoms. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one C(1), one C(14), and one H(3) atom. The N(4)-H(3) bond length is 0.86 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(17) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(15) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(15) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(17) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(18) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(18) atom. Linkers: 1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C]C([O])=O.[CH]=[C]C([O])=O.[CH]=[C]C([O])=O.[CH][C]=[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]/N=[C]\[N].[C]=C([CH])[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[CH].[C]=[CH].[C]=[C]/C=[C]/[NH].[C]=[C]/[C]=[C]\O[Zn]([O])OC(=O)C(=[C])/[C]=[C]/[N].[C]=[C]C([O])=O.[C]=[C][CH].[C]=[C][C][O].[C]C(=[CH])C([O])=O.[C]C(=[CH])[C]=O.[C]C([O])=O.[C]C([O])=O.[C]N[C].[C][CH].[C][CH]/[C]=[C]/[O].[C][C].[C][C].[C][C]=[CH].[C][C]=[CH].[C][C]=[C].[C][C]C(=O)O[Zn](O/[C]=[C]/[C])OC(=O)[C][C].[C][C][C].[C][C][C].[C][C][C].[C][C][C]=[C].[C][C][O].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N][C]=[N].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N]=[C]N/[C]=[C]/[C]C(=O)O[Zn].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][C]=O.[O][C]=O.[O][C]=O.[Zn].[Zn].[Zn].[Zn] ,6 [O]C(=O)c1cc(NC2=NC(=[N]=C([N]2)Nc2cc(cc(c2)C(=O)[O])C(=O)[O])Nc2cc(cc(c2)C(=O)[O])C(=O)[O])cc(c1)C(=O)[O] ,1 [H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[C]C(=[CH])C(=O)[O].[CH]C(=[C])C(=O)[O].[C]C(=O)[O].[C]C(=O)[O].[C]C(=O)[O].[C]=[C][C]/C(=[NH]\C1=N[C]=N[C]=N1)/[C][C].[C]N/[C]=[C]/[C]C(=O)[O].[C]=C/[C]=[C]\O[Zn](OC(=O)/C(=[C]/[C]=[CH])/[C][C])O[C][C].[C][CH]/[C]=[C]/O[Zn](OC(=O)/[C]=C/[C])[O].[C]=[C][C]/[C]=C\[C]=[C]/O[Zn].[N]=[C][N]/[C]=C/[C].[C][C][C]=[C].[C][C][C]=O.[C][C]C=[C].[C]/N=[C]\[N].[C][C]=[C].[C][C]=[C].[C][C]=[CH].[C]C=[C].[O][C]=O.[O][C]=O.[O][C]=O.[O][C]=O.[O][C]=O.[O][C]=O.[NH][C]=[N].[C][C].[C][C].[C][C].[C]#[C].[C]#[C].[C]#[C].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C][O].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C][CH].[C][CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[Zn].[Zn].[Zn].[Zn].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH] ,1 O=C(c1cc(NC2=NC(=[N]=C([N]2)Nc2cc(cc(c2)C(=O)[O])C(=O)[O])Nc2cc(cc(c2)C(=O)[O])C(=O)[O])cc(c1)C(=O)[O])O[Zn](OC(=O)c1cc(NC2=[N]=C(N=C([N]2)Nc2cc(cc(c2)C(=O)[O])C(=O)[O])Nc2cc(cc(c2)C(=O)[O])C(=O)[O])cc(c1)C(=O)[O])(OC(=O)c1cc(NC2=[N]=C(N=C([N]2)Nc2cc(cc(c2)C(=O)[O])C(=O)[O])Nc2cc(cc(c2)C(=O)[O])C(=O)[O])cc(c1)C(=O)[O])OC(=O)c1cc(NC2=[N]=C(N=C([N]2)Nc2cc(cc(c2)C(=O)[O])C(=O)[O])Nc2cc(cc(c2)C(=O)[O])C(=O)[O])cc(c1)C(=O)[O] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C]C([O])=O.[CH][C]=[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#[C].[C]#[C].[C]/C([CH])=[C]/[O].[C]=C[C]C([O])=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]=[C][CH].[C]C(=[C])[C]=O.[C][CH].[C][C].[C][C]/C=[C]\[CH][C].[C][C]=O.[C][C]=O.[C][C]=O.[C][C]C([O])=O.[C][C]O[Zn].[C][C]O[Zn][O].[C][C][C]=O.[C][C][C]=[C].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[NH].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][C]=O.[O][C]=O.[O][C]=O.[O][C]=O.[O][C]=O.[Zn].[Zn].[Zn].[Zn].[Zn]. Metal clusters: 9 O=[C]O[Zn](O[C]=O)(O[C]=O)O[C]=O ,12 [O][C]O[Zn](O[C][O])(O[C]=O)O[C]=O. The MOF has largest included sphere 12.55 A, density 0.81 g/cm3, surface area 4261.16 m2/g, accessible volume 0.79 cm3/g