CdC24H20(NO)4(CH)3C9H6N is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, four schembl1705614 molecules, and four CdC24H20(NO)4 clusters. In each CdC24H20(NO)4 cluster, Cd(1) is bonded in a distorted pentagonal pyramidal geometry to one N(2), one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(2) bond length is 2.32 Å. The Cd(1)-N(3) bond length is 2.34 Å. The Cd(1)-O(1) bond length is 2.34 Å. The Cd(1)-O(2) bond length is 2.45 Å. The Cd(1)-O(3) bond length is 2.41 Å. The Cd(1)-O(4) bond length is 2.43 Å. There are twenty-four inequivalent C sites. In the first C site, C(17) is bonded in a single-bond geometry to one C(19) and one H(12) atom. The C(17)-C(19) bond length is 1.38 Å. The C(17)-H(12) bond length is 0.93 Å. In the second C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(13) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(13) bond length is 0.93 Å. In the third C site, C(19) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(20) atom. The C(19)-C(20) bond length is 1.51 Å. In the fourth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(3), and one O(4) atom. The C(20)-O(3) bond length is 1.25 Å. The C(20)-O(4) bond length is 1.25 Å. In the fifth C site, C(21) is bonded in a trigonal planar geometry to one C(22), one C(23), and one C(36) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-C(23) bond length is 1.37 Å. The C(21)-C(36) bond length is 1.50 Å. In the sixth C site, C(22) is bonded in a single-bond geometry to one C(21) and one H(14) atom. The C(22)-H(14) bond length is 0.93 Å. In the seventh C site, C(23) is bonded in a single-bond geometry to one C(21) and one H(15) atom. The C(23)-H(15) bond length is 0.93 Å. In the eighth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(16) atom. The C(24)-N(3) bond length is 1.33 Å. The C(24)-H(16) bond length is 0.93 Å. In the ninth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(25)-N(3) bond length is 1.34 Å. The C(25)-H(17) bond length is 0.93 Å. In the tenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(28), one N(2), and one H(18) atom. The C(26)-C(28) bond length is 1.37 Å. The C(26)-N(2) bond length is 1.33 Å. The C(26)-H(18) bond length is 0.93 Å. In the eleventh C site, C(27) is bonded in a distorted trigonal planar geometry to one C(29), one N(2), and one H(19) atom. The C(27)-C(29) bond length is 1.37 Å. The C(27)-N(2) bond length is 1.34 Å. The C(27)-H(19) bond length is 0.93 Å. In the twelfth C site, C(28) is bonded in a distorted single-bond geometry to one C(26), one C(30), and one H(20) atom. The C(28)-C(30) bond length is 1.38 Å. The C(28)-H(20) bond length is 0.93 Å. In the thirteenth C site, C(29) is bonded in a distorted single-bond geometry to one C(27), one C(30), and one H(21) atom. The C(29)-C(30) bond length is 1.38 Å. The C(29)-H(21) bond length is 0.93 Å. In the fourteenth C site, C(30) is bonded in a trigonal planar geometry to one C(28), one C(29), and one C(31) atom. The C(30)-C(31) bond length is 1.50 Å. In the fifteenth C site, C(31) is bonded in a 3-coordinate geometry to one C(30); one N(4); and two equivalent H(22,23) atoms. The C(31)-N(4) bond length is 1.46 Å. Both C(31)-H(22,23) bond lengths are 0.97 Å. In the sixteenth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(34), one N(4), and one H(24) atom. The C(32)-C(34) bond length is 1.48 Å. The C(32)-N(4) bond length is 1.46 Å. The C(32)-H(24) bond length is 0.93 Å. In the seventeenth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(25) atom. The C(33)-N(4) bond length is 1.47 Å. The C(33)-H(25) bond length is 0.93 Å. In the eighteenth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(32), one N(5), and one H(26) atom. The C(34)-N(5) bond length is 1.46 Å. The C(34)-H(26) bond length is 0.93 Å. In the nineteenth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(27) atom. The C(35)-N(5) bond length is 1.46 Å. The C(35)-H(27) bond length is 0.93 Å. In the twentieth C site, C(36) is bonded in a 3-coordinate geometry to one C(21); one N(5); and two equivalent H(28,29) atoms. The C(36)-N(5) bond length is 1.46 Å. Both C(36)-H(28,29) bond lengths are 0.97 Å. In the twenty-first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.25 Å. In the twenty-second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(4) bond length is 1.38 Å. In the twenty-third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the twenty-fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(4)-H(2) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(26), and one C(27) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(24), and one C(25) atom. In the third N site, N(4) is bonded in a trigonal non-coplanar geometry to one C(31), one C(32), and one C(33) atom. In the fourth N site, N(5) is bonded in a trigonal non-coplanar geometry to one C(34), one C(35), and one C(36) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(28) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the thirteenth H site, H(22,23) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(24) is bonded in a single-bond geometry to one C(32) atom. In the fifteenth H site, H(25) is bonded in a single-bond geometry to one C(33) atom. In the sixteenth H site, H(26) is bonded in a single-bond geometry to one C(34) atom. In the seventeenth H site, H(27) is bonded in a single-bond geometry to one C(35) atom. In the eighteenth H site, H(28,29) is bonded in a single-bond geometry to one C(36) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(20) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(20) atom. Linkers: 2 [CH]1[CH]N(Cc2ccncc2)[CH][CH]N1Cc1ccncc1 ,4 [O]C(=O)c1ccc(N(c2ccccc2)c2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 5.67 A, density 1.20 g/cm3, surface area 5006.68 m2/g, accessible volume 0.46 cm3/g