Zn5H28(C26O9)2(C5H3)4(CH3CO)4(CH2CO)6(CH3CHO)2 is Indium-derived structured and crystallizes in the tetragonal P-42_1c space group. The structure is zero-dimensional and consists of eight (3z)-2,3,4,5-tetramethylhexa-1,3,5-triene molecules; eight 1,2-dimethoxyethane molecules; twenty-four dimethyl ether molecules; eight dimethyl ether molecules; and four Zn5H28(C26O9)2 clusters. In each Zn5H28(C26O9)2 cluster, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a rectangular see-saw-like geometry to one O(15), one O(4), one O(5), and one O(8) atom. The Zn(1)-O(15) bond length is 2.13 Å. The Zn(1)-O(4) bond length is 2.08 Å. The Zn(1)-O(5) bond length is 2.27 Å. The Zn(1)-O(8) bond length is 2.03 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(14), one O(6), and one O(8) atom to form corner-sharing ZnO4 tetrahedra. The corner-sharing octahedral tilt angles are 62°. The Zn(2)-O(1) bond length is 1.96 Å. The Zn(2)-O(14) bond length is 1.94 Å. The Zn(2)-O(6) bond length is 1.93 Å. The Zn(2)-O(8) bond length is 1.94 Å. In the third Zn site, Zn(3) is bonded to two equivalent O(5), two equivalent O(7), and two equivalent O(8) atoms to form corner-sharing ZnO6 octahedra. Both Zn(3)-O(5) bond lengths are 2.22 Å. Both Zn(3)-O(7) bond lengths are 2.12 Å. Both Zn(3)-O(8) bond lengths are 2.01 Å. There are twenty-six inequivalent C sites. In the first C site, C(6) is bonded in a bent 120 degrees geometry to one C(46), one O(4), and one O(5) atom. The C(6)-C(46) bond length is 1.49 Å. The C(6)-O(4) bond length is 1.26 Å. The C(6)-O(5) bond length is 1.27 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(20) atom. The C(1)-C(17) bond length is 1.34 Å. The C(1)-C(18) bond length is 1.39 Å. The C(1)-C(20) bond length is 1.52 Å. In the third C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(10) atom. The C(9)-C(10) bond length is 1.36 Å. The C(9)-H(10) bond length is 0.93 Å. In the fourth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(9) atom. The C(10)-C(11) bond length is 1.37 Å. The C(10)-C(13) bond length is 1.52 Å. In the fifth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(11) atom. The C(11)-H(11) bond length is 0.93 Å. In the sixth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(6), and one O(7) atom. The C(13)-O(6) bond length is 1.28 Å. The C(13)-O(7) bond length is 1.22 Å. In the seventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(1), and one O(2) atom. The C(14)-C(15) bond length is 1.52 Å. The C(14)-O(1) bond length is 1.26 Å. The C(14)-O(2) bond length is 1.27 Å. In the eighth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(19) atom. The C(15)-C(16) bond length is 1.37 Å. The C(15)-C(19) bond length is 1.32 Å. In the ninth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(13) atom. The C(16)-H(13) bond length is 0.93 Å. In the tenth C site, C(17) is bonded in a distorted single-bond geometry to one C(1) and one H(14) atom. The C(17)-H(14) bond length is 0.93 Å. In the eleventh C site, C(18) is bonded in a distorted trigonal planar geometry to one C(1), one C(19), and one H(15) atom. The C(18)-C(19) bond length is 1.37 Å. The C(18)-H(15) bond length is 0.93 Å. In the twelfth C site, C(19) is bonded in a distorted single-bond geometry to one C(15), one C(18), and one H(16) atom. The C(19)-H(16) bond length is 0.93 Å. In the thirteenth C site, C(20) is bonded in a trigonal planar geometry to one C(1), one C(21), and one C(25) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-C(25) bond length is 1.35 Å. In the fourteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(17) atom. The C(21)-H(17) bond length is 0.93 Å. In the fifteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(18) atom. The C(24)-C(25) bond length is 1.44 Å. The C(24)-H(18) bond length is 0.93 Å. In the sixteenth C site, C(25) is bonded in a trigonal planar geometry to one C(20), one C(24), and one C(26) atom. The C(25)-C(26) bond length is 1.49 Å. In the seventeenth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(31) atom. The C(26)-C(27) bond length is 1.38 Å. The C(26)-C(31) bond length is 1.37 Å. In the eighteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(19) atom. The C(27)-H(19) bond length is 0.93 Å. In the nineteenth C site, C(28) is bonded in a single-bond geometry to one C(29) and one H(20) atom. The C(28)-C(29) bond length is 1.41 Å. The C(28)-H(20) bond length is 0.93 Å. In the twentieth C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(32) atom. The C(29)-C(30) bond length is 1.38 Å. The C(29)-C(32) bond length is 1.51 Å. In the twenty-first C site, C(31) is bonded in a distorted single-bond geometry to one C(26) and one H(22) atom. The C(31)-H(22) bond length is 0.93 Å. In the twenty-second C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(21) atom. The C(30)-H(21) bond length is 0.93 Å. In the twenty-third C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(14), and one O(15) atom. The C(32)-O(14) bond length is 1.24 Å. The C(32)-O(15) bond length is 1.26 Å. In the twenty-fourth C site, C(45) is bonded in a distorted single-bond geometry to one C(46) and one H(34) atom. The C(45)-C(46) bond length is 1.39 Å. The C(45)-H(34) bond length is 0.93 Å. In the twenty-fifth C site, C(46) is bonded in a trigonal planar geometry to one C(45), one C(47), and one C(6) atom. The C(46)-C(47) bond length is 1.35 Å. In the twenty-sixth C site, C(47) is bonded in a distorted single-bond geometry to one C(46) and one H(35) atom. The C(47)-H(35) bond length is 0.93 Å. There are fourteen inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(28) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(30) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(31) atom. In the thirteenth H site, H(34) is bonded in a single-bond geometry to one C(45) atom. In the fourteenth H site, H(35) is bonded in a single-bond geometry to one C(47) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(14) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(14) atom. In the third O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(6) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(13) atom. In the fifth O site, O(7) is bonded in a bent 150 degrees geometry to one Zn(3) and one C(13) atom. In the sixth O site, O(8) is bonded in a trigonal non-coplanar geometry to one Zn(1), one Zn(2), and one Zn(3) atom. In the seventh O site, O(5) is bonded in a 3-coordinate geometry to one Zn(1), one Zn(3), and one C(6) atom. In the eighth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(32) atom. In the ninth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(32) atom. Linkers: 8 [O]C(=O)c1ccc(-c2cc3c(cc2-c2ccc(C([O])=O)cc2)OCCOCCOc2cc(-c4ccc(C([O])=O)cc4)c(-c4ccc(C([O])=O)cc4)cc2OCCOCCO3)cc1. Metal clusters: 2 O=[C]O[Zn@@]12O[C]O[Zn]O[C]O[Zn]34(O[C]O[Zn]O[C]O[Zn@](O[C]=O)(O[C]O3)O4)(O[C]O1)O2 ,2 O=[C]O[Zn@]12O[C]O[Zn]O[C]O[Zn]34(O[C]O[Zn]O[C]O[Zn@@](O[C]=O)(O[C]O3)O4)(O[C]O1)O2. The MOF has largest included sphere 10.29 A, density 0.91 g/cm3, surface area 4475.00 m2/g, accessible volume 0.60 cm3/g