Zn10C156N12H114O13 crystallizes in the cubic Fd-3 space group. The structure consists of a Zn10C156N12H114O13 framework. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted single-bond geometry to one Zn(1), two equivalent N(1), and two equivalent N(2) atoms. The Zn(1)-Zn(1) bond length is 0.88 Å. There is one shorter (2.12 Å) and one longer (2.20 Å) Zn(1)-N(1) bond length. There is one shorter (2.12 Å) and one longer (2.20 Å) Zn(1)-N(2) bond length. In the second Zn site, Zn(2) is bonded to one O(3) and three equivalent O(1) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(3) bond length is 1.92 Å. All Zn(2)-O(1) bond lengths are 1.92 Å. In the third Zn site, Zn(3) is bonded to one O(4) and three equivalent O(2) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(4) bond length is 1.94 Å. All Zn(3)-O(2) bond lengths are 1.92 Å. There are thirty inequivalent C sites. In the first C site, C(23) is bonded in a trigonal planar geometry to one C(25) and two equivalent C(1) atoms. The C(23)-C(25) bond length is 1.50 Å. Both C(23)-C(1) bond lengths are 1.40 Å. In the second C site, C(24) is bonded in a trigonal planar geometry to one C(28) and two equivalent C(9) atoms. The C(24)-C(28) bond length is 1.50 Å. Both C(24)-C(9) bond lengths are 1.39 Å. In the third C site, C(25) is bonded in a trigonal planar geometry to one C(23) and two equivalent C(10) atoms. Both C(25)-C(10) bond lengths are 1.39 Å. In the fourth C site, C(26) is bonded in a trigonal planar geometry to one C(27) and two equivalent C(11) atoms. The C(26)-C(27) bond length is 1.50 Å. Both C(26)-C(11) bond lengths are 1.38 Å. In the fifth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(23), and one N(1) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-N(1) bond length is 1.42 Å. In the sixth C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.93 Å. In the seventh C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.42 Å. The C(3)-H(2) bond length is 0.93 Å. In the eighth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(1) bond length is 1.42 Å. In the ninth C site, C(5) is bonded in a trigonal planar geometry to one C(14), one C(4), and one C(6) atom. The C(5)-C(14) bond length is 1.50 Å. The C(5)-C(6) bond length is 1.39 Å. In the tenth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.42 Å. The C(6)-N(2) bond length is 1.42 Å. In the eleventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(7)-H(3) bond length is 0.93 Å. In the twelfth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(8)-C(9) bond length is 1.42 Å. The C(8)-H(4) bond length is 0.93 Å. In the thirteenth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(24), one C(8), and one N(2) atom. The C(9)-N(2) bond length is 1.42 Å. In the fourteenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(25), and one H(5) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(5) bond length is 0.93 Å. In the fifteenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(26), and one H(6) atom. The C(11)-H(6) bond length is 0.93 Å. In the sixteenth C site, C(12) is bonded in a distorted single-bond geometry to one C(13), one C(28), and one H(7) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-C(28) bond length is 1.39 Å. The C(12)-H(7) bond length is 0.93 Å. In the seventeenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(29), and one H(8) atom. The C(13)-C(29) bond length is 1.40 Å. The C(13)-H(8) bond length is 0.93 Å. In the eighteenth C site, C(14) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(5) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-C(19) bond length is 1.39 Å. In the nineteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(20) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-C(20) bond length is 1.51 Å. In the twentieth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(9) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(9) bond length is 0.93 Å. In the twenty-first C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(21) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-C(21) bond length is 1.51 Å. In the twenty-second C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(10) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(10) bond length is 0.93 Å. In the twenty-third C site, C(19) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(22) atom. The C(19)-C(22) bond length is 1.51 Å. In the twenty-fourth C site, C(20) is bonded in a trigonal non-coplanar geometry to one C(15), one H(11), one H(12), and one H(13) atom. The C(20)-H(11) bond length is 0.96 Å. The C(20)-H(12) bond length is 0.96 Å. The C(20)-H(13) bond length is 0.96 Å. In the twenty-fifth C site, C(21) is bonded in a trigonal non-coplanar geometry to one C(17), one H(14), one H(15), and one H(16) atom. The C(21)-H(14) bond length is 0.96 Å. The C(21)-H(15) bond length is 0.96 Å. The C(21)-H(16) bond length is 0.96 Å. In the twenty-sixth C site, C(22) is bonded in a trigonal non-coplanar geometry to one C(19); one H(17); and two equivalent H(18,19) atoms. The C(22)-H(17) bond length is 0.96 Å. Both C(22)-H(18,19) bond lengths are 0.96 Å. In the twenty-seventh C site, C(27) is bonded in a bent 120 degrees geometry to one C(26) and two equivalent O(1) atoms. Both C(27)-O(1) bond lengths are 1.25 Å. In the twenty-eighth C site, C(29) is bonded in a trigonal planar geometry to one C(30) and two equivalent C(13) atoms. The C(29)-C(30) bond length is 1.50 Å. In the twenty-ninth C site, C(30) is bonded in a bent 120 degrees geometry to one C(29) and two equivalent O(2) atoms. Both C(30)-O(2) bond lengths are 1.25 Å. In the thirtieth C site, C(28) is bonded in a trigonal planar geometry to one C(24) and two equivalent C(12) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent Zn(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a 4-coordinate geometry to two equivalent Zn(1), one C(6), and one C(9) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(22) atom. In the eighteenth H site, H(18,19) is bonded in a single-bond geometry to one C(22) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(27) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(3) and one C(30) atom. In the third O site, O(3) is bonded in a tetrahedral geometry to four equivalent Zn(2) atoms. In the fourth O site, O(4) is bonded in a tetrahedral geometry to four equivalent Zn(3) atoms. Linkers: 48 Cc1cc(C)c(/C2=C3\C=C/C(=C(\c4ccc(C([O])=O)cc4)C4=N/C(=C(/c5c(C)cc(C)cc5C)C5=CC=C([N]5)/C(c5ccc(C([O])=O)cc5)=C5/C=CC2=N5)C=C4)[N]3)c(C)c1. Metal clusters: 48 [N][Zn]([N])[Zn]([N])[N] ,16 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. The MOF has largest included sphere 12.17 A, density 0.60 g/cm3, surface area 4521.68 m2/g, accessible volume 1.22 cm3/g