ZnC8H4O4H4(C3F2)3 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of four H4(C3F2)3 clusters and two ZnC8H4O4 clusters. In each H4(C3F2)3 cluster, there are nine inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2) bond length is 0.93 Å. In the second C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.54 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the fourth C site, C(8) is bonded in a tetrahedral geometry to one C(10), one C(11), one C(5), and one C(9) atom. The C(8)-C(10) bond length is 1.54 Å. The C(8)-C(11) bond length is 1.56 Å. The C(8)-C(9) bond length is 1.53 Å. In the fifth C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(8), one F(1), one F(2), and one F(3) atom. The C(9)-F(1) bond length is 1.35 Å. The C(9)-F(2) bond length is 1.33 Å. The C(9)-F(3) bond length is 1.34 Å. In the sixth C site, C(10) is bonded in a trigonal non-coplanar geometry to one C(8), one F(4), one F(5), and one F(6) atom. The C(10)-F(4) bond length is 1.34 Å. The C(10)-F(5) bond length is 1.35 Å. The C(10)-F(6) bond length is 1.35 Å. In the seventh C site, C(11) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(8) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(16) bond length is 1.38 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(5) atom. The C(12)-H(5) bond length is 0.93 Å. In the ninth C site, C(16) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(16)-H(8) bond length is 0.93 Å. There are four inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(9) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(9) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one C(10) atom. In each ZnC8H4O4 cluster, Zn(1) is bonded in a distorted square co-planar geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-O(1) bond length is 1.94 Å. The Zn(1)-O(2) bond length is 1.95 Å. The Zn(1)-O(3) bond length is 2.02 Å. The Zn(1)-O(4) bond length is 1.95 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.23 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(6,7) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-H(6,7) bond length is 0.93 Å. In the sixth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.37 Å. The C(14)-C(17) bond length is 1.51 Å. In the seventh C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(6,7) atom. The C(15)-H(6,7) bond length is 0.93 Å. In the eighth C site, C(17) is bonded in a bent 120 degrees geometry to one C(14), one O(3), and one O(4) atom. The C(17)-O(3) bond length is 1.26 Å. The C(17)-O(4) bond length is 1.26 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(6,7) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. Linkers: 4 [O]C(=O)c1ccc(C(c2ccc(C([O])=O)cc2)(C(F)(F)F)C(F)(F)F)cc1. Metal clusters: 2 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 7.56 A, density 1.12 g/cm3, surface area 3866.21 m2/g, accessible volume 0.52 cm3/g