CuC8N2H5I(CH2)2 crystallizes in the tetragonal I4_1/amd space group. The structure consists of thirty-two 02329_fluka molecules inside a CuC8N2H5I framework. In the CuC8N2H5I framework, Cu(1) is bonded to two equivalent N(1) and two equivalent I(1) atoms to form distorted corner-sharing CuI2N2 tetrahedra. Both Cu(1)-N(1) bond lengths are 2.07 Å. Both Cu(1)-I(1) bond lengths are 2.62 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one N(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(3) bond length is 1.49 Å. The C(1)-N(1) bond length is 1.32 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(5) atom. The C(2)-C(2) bond length is 1.41 Å. The C(2)-C(5) bond length is 1.40 Å. In the third C site, C(3) is bonded in a water-like geometry to one C(1), one H(1), and one H(2) atom. The C(3)-H(1) bond length is 0.95 Å. The C(3)-H(2) bond length is 0.95 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(6) and two equivalent C(2) atoms. The C(5)-C(6) bond length is 1.50 Å. In the fifth C site, C(6) is bonded in a single-bond geometry to one C(5) and one H(5) atom. The C(6)-H(5) bond length is 0.95 Å. N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one N(1) atom. The N(1)-N(1) bond length is 1.41 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(3) atom. I(1) is bonded in an L-shaped geometry to two equivalent Cu(1) atoms. Linkers: 4 C1CC2CCc3nnc4c5c6c7c(nnc1c7c2c35)CCC6CC4. Metal clusters: 8 [Cu]. The MOF has largest included sphere 7.88 A, density 1.41 g/cm3, surface area 2923.21 m2/g, accessible volume 0.50 cm3/g