Zn3C30H26(N6O7)2(CH2)6(C2NH2O)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two trimethyl isocyanurate molecules, and one Zn3C30H26(N6O7)2 cluster. In the Zn3C30H26(N6O7)2 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to one N(4), one O(1), one O(2), one O(3), and one O(6) atom. The Zn(1)-N(4) bond length is 2.08 Å. The Zn(1)-O(1) bond length is 2.02 Å. The Zn(1)-O(2) bond length is 2.51 Å. The Zn(1)-O(3) bond length is 1.94 Å. The Zn(1)-O(6) bond length is 1.96 Å. In the second Zn site, Zn(2) is bonded in an octahedral geometry to two equivalent N(7), two equivalent O(10), and two equivalent O(5) atoms. Both Zn(2)-N(7) bond lengths are 2.10 Å. Both Zn(2)-O(10) bond lengths are 2.14 Å. Both Zn(2)-O(5) bond lengths are 2.12 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-H(2) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(4) bond length is 1.48 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a 3-coordinate geometry to one C(2); one N(9); and two equivalent H(4,5) atoms. The C(4)-N(9) bond length is 1.48 Å. Both C(4)-H(4,5) bond lengths are 0.97 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(25) atom. The C(5)-N(7) bond length is 1.36 Å. The C(5)-N(8) bond length is 1.30 Å. The C(5)-H(25) bond length is 1.14 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(6) atom. The C(6)-N(7) bond length is 1.33 Å. The C(6)-N(9) bond length is 1.33 Å. The C(6)-H(6) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(24) atom. The C(7)-N(4) bond length is 1.34 Å. The C(7)-N(5) bond length is 1.32 Å. The C(7)-H(24) bond length is 1.14 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(7) atom. The C(8)-N(4) bond length is 1.31 Å. The C(8)-N(6) bond length is 1.31 Å. The C(8)-H(7) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a 3-coordinate geometry to one C(10); one N(6); and two equivalent H(8,9) atoms. The C(9)-C(10) bond length is 1.51 Å. The C(9)-N(6) bond length is 1.47 Å. Both C(9)-H(8,9) bond lengths are 0.97 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-C(12) bond length is 1.37 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(10) atom. The C(11)-H(10) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one H(11) atom. The C(12)-H(11) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(13)-O(5) bond length is 1.24 Å. The C(13)-O(6) bond length is 1.26 Å. In the fourteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(21)-O(1) bond length is 1.26 Å. The C(21)-O(2) bond length is 1.19 Å. In the fifteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(24)-O(3) bond length is 1.23 Å. The C(24)-O(4) bond length is 1.23 Å. There are six inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(7), and one C(8) atom. In the second N site, N(5) is bonded in a distorted water-like geometry to one C(7) and one N(6) atom. The N(5)-N(6) bond length is 1.35 Å. In the third N site, N(6) is bonded in a distorted trigonal planar geometry to one C(8), one C(9), and one N(5) atom. In the fourth N site, N(7) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(5), and one C(6) atom. In the fifth N site, N(8) is bonded in a distorted water-like geometry to one C(5) and one N(9) atom. The N(8)-N(9) bond length is 1.34 Å. In the sixth N site, N(9) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(8) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(10) atom. The H(1)-O(10) bond length is 0.82 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4,5) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8,9) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(24) is bonded in a single-bond geometry to one C(7) atom. In the eleventh H site, H(25) is bonded in a single-bond geometry to one C(5) atom. There are seven inequivalent O sites. In the first O site, O(10) is bonded in a distorted water-like geometry to one Zn(2) and one H(1) atom. In the second O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(21) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Zn(1) and one C(21) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(24) atom. In the fifth O site, O(4) is bonded in a single-bond geometry to one C(24) atom. In the sixth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(13) atom. In the seventh O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(13) atom. Linkers: 1 [CH]1N=C[N]N1Cc1ccc(CN2[CH]N=C[N]2)cc1 ,2 [O]C(=O)CCn1c(=O)n(CCC([O])=O)c(=O)n(CCC([O])=O)c1=O ,2 [c]1ncn(Cc2ccc(CN3[CH]N=C[N]3)cc2)n1 ,1 [CH]1N=C[N]N1Cc1ccc(Cn2cncn2)cc1. Metal clusters: 1 O=[C]O[Zn](O[C]O[Zn](O)(O)O[C]O[Zn](O[C]=O)O[C]=O)O[C]=O. The MOF has largest included sphere 5.22 A, density 1.40 g/cm3, surface area 4673.65 m2/g, accessible volume 0.21 cm3/g