(CH)2Ag13C26N4H6(OF)12(CF3)4 crystallizes in the monoclinic C2/c space group. The structure consists of eight 02329_fluka molecules and sixteen trifluoromethane molecules inside a Ag13C26N4H6(OF)12 framework. In the Ag13C26N4H6(OF)12 framework, there are seven inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a rectangular see-saw-like geometry to one C(2), one O(1), one O(3), and one O(6) atom. The Ag(1)-C(2) bond length is 2.19 Å. The Ag(1)-O(1) bond length is 2.30 Å. The Ag(1)-O(3) bond length is 2.32 Å. The Ag(1)-O(6) bond length is 2.39 Å. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one C(1), one N(1), one O(2), and one O(5) atom. The Ag(2)-C(1) bond length is 2.22 Å. The Ag(2)-N(1) bond length is 2.18 Å. The Ag(2)-O(2) bond length is 2.58 Å. The Ag(2)-O(5) bond length is 2.76 Å. In the third Ag site, Ag(3) is bonded in a bent 150 degrees geometry to one C(1) and one O(4) atom. The Ag(3)-C(1) bond length is 2.15 Å. The Ag(3)-O(4) bond length is 2.25 Å. In the fourth Ag site, Ag(4) is bonded in a 2-coordinate geometry to one C(1) and one C(2) atom. The Ag(4)-C(1) bond length is 2.54 Å. The Ag(4)-C(2) bond length is 2.42 Å. In the fifth Ag site, Ag(5) is bonded in a 2-coordinate geometry to one C(1), one C(2), and one O(5) atom. The Ag(5)-C(1) bond length is 2.62 Å. The Ag(5)-C(2) bond length is 2.27 Å. The Ag(5)-O(5) bond length is 2.26 Å. In the sixth Ag site, Ag(6) is bonded in a bent 150 degrees geometry to one C(2) and one N(2) atom. The Ag(6)-C(2) bond length is 2.30 Å. The Ag(6)-N(2) bond length is 2.18 Å. In the seventh Ag site, Ag(7) is bonded in a 4-coordinate geometry to two equivalent C(1) and two equivalent O(2) atoms. Both Ag(7)-C(1) bond lengths are 2.42 Å. Both Ag(7)-O(2) bond lengths are 2.40 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a 6-coordinate geometry to one Ag(2), one Ag(3), one Ag(4), one Ag(5), one Ag(7), and one C(2) atom. The C(1)-C(2) bond length is 1.24 Å. In the second C site, C(2) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(4), one Ag(5), one Ag(6), and one C(1) atom. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(3)-O(1) bond length is 1.22 Å. The C(3)-O(2) bond length is 1.25 Å. In the fourth C site, C(5) is bonded in a 2-coordinate geometry to one O(3) and one O(4) atom. The C(5)-O(3) bond length is 1.21 Å. The C(5)-O(4) bond length is 1.24 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one O(5), and one O(6) atom. The C(7)-C(8) bond length is 1.56 Å. The C(7)-O(5) bond length is 1.25 Å. The C(7)-O(6) bond length is 1.22 Å. In the sixth C site, C(8) is bonded in a 6-coordinate geometry to one C(7), one F(10), one F(11), one F(12), one F(7), one F(8), and one F(9) atom. The C(8)-F(10) bond length is 1.39 Å. The C(8)-F(11) bond length is 1.24 Å. The C(8)-F(12) bond length is 1.27 Å. The C(8)-F(7) bond length is 1.31 Å. The C(8)-F(8) bond length is 1.27 Å. The C(8)-F(9) bond length is 1.28 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one N(1) atom. The C(9)-C(10) bond length is 1.44 Å. The C(9)-N(1) bond length is 1.13 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.37 Å. The C(10)-C(15) bond length is 1.38 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(1) atom. The C(11)-H(1) bond length is 0.93 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(3) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-H(3) bond length is 0.93 Å. In the eleventh C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(16) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-C(16) bond length is 1.42 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one H(4) atom. The C(15)-H(4) bond length is 0.93 Å. In the thirteenth C site, C(16) is bonded in a distorted linear geometry to one C(14) and one N(2) atom. The C(16)-N(2) bond length is 1.15 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Ag(2) and one C(9) atom. In the second N site, N(2) is bonded in a linear geometry to one Ag(6) and one C(16) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(15) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ag(1) and one C(3) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(2), one Ag(7), and one C(3) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one Ag(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(3) and one C(5) atom. In the fifth O site, O(5) is bonded in a 1-coordinate geometry to one Ag(2), one Ag(5), and one C(7) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ag(1) and one C(7) atom. There are six inequivalent F sites. In the first F site, F(7) is bonded in a distorted single-bond geometry to one C(8) atom. In the second F site, F(8) is bonded in a single-bond geometry to one C(8) atom. In the third F site, F(9) is bonded in a single-bond geometry to one C(8) atom. In the fourth F site, F(10) is bonded in a distorted single-bond geometry to one C(8) atom. In the fifth F site, F(11) is bonded in a single-bond geometry to one C(8) atom. In the sixth F site, F(12) is bonded in a distorted single-bond geometry to one C(8) atom. Linkers: 8 N#Cc1cccc(C#N)c1 ,16 [O]C(=O)C(F)(F)F ,6 FF.FF.FF.[C]C([O])=O ,2 FF.FF.FF.[C].[O][C]=O. Metal clusters: 52 [Ag]. The MOF has largest included sphere 7.34 A, density 2.04 g/cm3, surface area 2355.75 m2/g, accessible volume 0.26 cm3/g