(CuH12(C5N)3)2(CuH10(C4N)3)2CuH12(C7N2)2CuH20(C13N2)2(C3H2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 2,3-dimethyl-1,3-butadiene molecules; two CuH10(C4N)3 clusters; two CuH12(C5N)3 clusters; two CuH12(C7N2)2 clusters; and two CuH20(C13N2)2 clusters. In each CuH10(C4N)3 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(3) is bonded in a T-shaped geometry to one N(10), one N(12), and one N(14) atom. The Cu(3)-N(10) bond length is 2.02 Å. The Cu(3)-N(12) bond length is 2.05 Å. The Cu(3)-N(14) bond length is 1.99 Å. In the second Cu site, Cu(4) is bonded in a T-shaped geometry to one N(11), one N(18), and one N(9) atom. The Cu(4)-N(11) bond length is 2.05 Å. The Cu(4)-N(18) bond length is 2.01 Å. The Cu(4)-N(9) bond length is 2.02 Å. There are twenty-four inequivalent C sites. In the first C site, C(85) is bonded in a distorted single-bond geometry to one C(55), one C(90), and one H(69) atom. The C(85)-C(55) bond length is 1.34 Å. The C(85)-C(90) bond length is 1.42 Å. The C(85)-H(69) bond length is 0.93 Å. In the second C site, C(88) is bonded in a distorted bent 120 degrees geometry to one C(95), one N(11), and one H(71) atom. The C(88)-C(95) bond length is 1.38 Å. The C(88)-N(11) bond length is 1.31 Å. The C(88)-H(71) bond length is 0.93 Å. In the third C site, C(89) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(72) atom. The C(89)-N(14) bond length is 1.33 Å. The C(89)-H(72) bond length is 0.93 Å. In the fourth C site, C(90) is bonded in a distorted bent 120 degrees geometry to one C(85), one N(10), and one H(73) atom. The C(90)-N(10) bond length is 1.35 Å. The C(90)-H(73) bond length is 0.93 Å. In the fifth C site, C(95) is bonded in a distorted trigonal planar geometry to one C(47), one C(88), and one H(78) atom. The C(95)-C(47) bond length is 1.40 Å. The C(95)-H(78) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(57), one C(61), and one H(8) atom. The C(11)-C(57) bond length is 1.37 Å. The C(11)-C(61) bond length is 1.37 Å. The C(11)-H(8) bond length is 0.93 Å. In the seventh C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(14) atom. The C(17)-N(9) bond length is 1.28 Å. The C(17)-H(14) bond length is 0.93 Å. In the eighth C site, C(20) is bonded in a trigonal planar geometry to one C(34), one C(39), and one C(55) atom. The C(20)-C(34) bond length is 1.41 Å. The C(20)-C(39) bond length is 1.40 Å. The C(20)-C(55) bond length is 1.46 Å. In the ninth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(25) atom. The C(30)-N(10) bond length is 1.32 Å. The C(30)-H(25) bond length is 0.93 Å. In the tenth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(18) and one H(27) atom. The C(32)-N(18) bond length is 1.33 Å. The C(32)-H(27) bond length is 0.93 Å. In the eleventh C site, C(34) is bonded in a distorted single-bond geometry to one C(20) and one H(29) atom. The C(34)-H(29) bond length is 0.93 Å. In the twelfth C site, C(39) is bonded in a distorted single-bond geometry to one C(20) and one H(33) atom. The C(39)-H(33) bond length is 0.93 Å. In the thirteenth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(18) and one H(35) atom. The C(41)-N(18) bond length is 1.31 Å. The C(41)-H(35) bond length is 0.93 Å. In the fourteenth C site, C(44) is bonded in a distorted single-bond geometry to one C(47) and one H(38) atom. The C(44)-C(47) bond length is 1.39 Å. The C(44)-H(38) bond length is 0.93 Å. In the fifteenth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(36) atom. The C(42)-N(9) bond length is 1.38 Å. The C(42)-H(36) bond length is 0.93 Å. In the sixteenth C site, C(46) is bonded in a distorted single-bond geometry to one C(57) and one H(40) atom. The C(46)-C(57) bond length is 1.35 Å. The C(46)-H(40) bond length is 0.93 Å. In the seventeenth C site, C(47) is bonded in a trigonal planar geometry to one C(44), one C(57), and one C(95) atom. The C(47)-C(57) bond length is 1.52 Å. In the eighteenth C site, C(51) is bonded in a distorted bent 120 degrees geometry to one N(12) and one H(42) atom. The C(51)-N(12) bond length is 1.32 Å. The C(51)-H(42) bond length is 0.93 Å. In the nineteenth C site, C(55) is bonded in a trigonal planar geometry to one C(20), one C(77), and one C(85) atom. The C(55)-C(77) bond length is 1.39 Å. In the twentieth C site, C(57) is bonded in a trigonal planar geometry to one C(11), one C(46), and one C(47) atom. In the twenty-first C site, C(61) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(12), and one H(48) atom. The C(61)-N(12) bond length is 1.31 Å. The C(61)-H(48) bond length is 0.93 Å. In the twenty-second C site, C(62) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(49) atom. The C(62)-N(11) bond length is 1.34 Å. The C(62)-H(49) bond length is 0.93 Å. In the twenty-third C site, C(68) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(55) atom. The C(68)-N(14) bond length is 1.32 Å. The C(68)-H(55) bond length is 0.93 Å. In the twenty-fourth C site, C(77) is bonded in a distorted single-bond geometry to one C(55) and one H(62) atom. The C(77)-H(62) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(14) is bonded in a trigonal planar geometry to one Cu(3), one C(68), and one C(89) atom. In the second N site, N(18) is bonded in a trigonal planar geometry to one Cu(4), one C(32), and one C(41) atom. In the third N site, N(9) is bonded in a trigonal planar geometry to one Cu(4), one C(17), and one C(42) atom. In the fourth N site, N(10) is bonded in a trigonal planar geometry to one Cu(3), one C(30), and one C(90) atom. In the fifth N site, N(11) is bonded in a trigonal planar geometry to one Cu(4), one C(62), and one C(88) atom. In the sixth N site, N(12) is bonded in a trigonal planar geometry to one Cu(3), one C(51), and one C(61) atom. There are twenty inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the third H site, H(25) is bonded in a single-bond geometry to one C(30) atom. In the fourth H site, H(27) is bonded in a single-bond geometry to one C(32) atom. In the fifth H site, H(29) is bonded in a single-bond geometry to one C(34) atom. In the sixth H site, H(33) is bonded in a single-bond geometry to one C(39) atom. In the seventh H site, H(35) is bonded in a single-bond geometry to one C(41) atom. In the eighth H site, H(36) is bonded in a single-bond geometry to one C(42) atom. In the ninth H site, H(38) is bonded in a single-bond geometry to one C(44) atom. In the tenth H site, H(40) is bonded in a single-bond geometry to one C(46) atom. In the eleventh H site, H(42) is bonded in a single-bond geometry to one C(51) atom. In the twelfth H site, H(48) is bonded in a single-bond geometry to one C(61) atom. In the thirteenth H site, H(49) is bonded in a single-bond geometry to one C(62) atom. In the fourteenth H site, H(55) is bonded in a single-bond geometry to one C(68) atom. In the fifteenth H site, H(62) is bonded in a single-bond geometry to one C(77) atom. In the sixteenth H site, H(69) is bonded in a single-bond geometry to one C(85) atom. In the seventeenth H site, H(72) is bonded in a single-bond geometry to one C(89) atom. In the eighteenth H site, H(73) is bonded in a single-bond geometry to one C(90) atom. In the nineteenth H site, H(71) is bonded in a single-bond geometry to one C(88) atom. In the twentieth H site, H(78) is bonded in a single-bond geometry to one C(95) atom. In each CuH12(C5N)3 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a T-shaped geometry to one N(2), one N(20), and one N(4) atom. The Cu(1)-N(2) bond length is 1.99 Å. The Cu(1)-N(20) bond length is 1.98 Å. The Cu(1)-N(4) bond length is 1.99 Å. In the second Cu site, Cu(2) is bonded in a T-shaped geometry to one N(1), one N(16), and one N(3) atom. The Cu(2)-N(1) bond length is 2.01 Å. The Cu(2)-N(16) bond length is 1.97 Å. The Cu(2)-N(3) bond length is 2.00 Å. There are thirty inequivalent C sites. In the first C site, C(91) is bonded in a distorted single-bond geometry to one C(60) and one H(74) atom. The C(91)-C(60) bond length is 1.40 Å. The C(91)-H(74) bond length is 0.93 Å. In the second C site, C(93) is bonded in a distorted single-bond geometry to one C(37) and one H(76) atom. The C(93)-C(37) bond length is 1.39 Å. The C(93)-H(76) bond length is 0.93 Å. In the third C site, C(7) is bonded in a bent 120 degrees geometry to one N(20) and one H(6) atom. The C(7)-N(20) bond length is 1.26 Å. The C(7)-H(6) bond length is 0.93 Å. In the fourth C site, C(10) is bonded in a trigonal planar geometry to one C(37), one C(38), and one C(82) atom. The C(10)-C(37) bond length is 1.46 Å. The C(10)-C(38) bond length is 1.43 Å. The C(10)-C(82) bond length is 1.34 Å. In the fifth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(49), one C(59), and one H(10) atom. The C(13)-C(49) bond length is 1.40 Å. The C(13)-C(59) bond length is 1.41 Å. The C(13)-H(10) bond length is 0.93 Å. In the sixth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(16) atom. The C(19)-N(1) bond length is 1.34 Å. The C(19)-H(16) bond length is 0.93 Å. In the seventh C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(83), one N(3), and one H(21) atom. The C(26)-C(83) bond length is 1.38 Å. The C(26)-N(3) bond length is 1.31 Å. The C(26)-H(21) bond length is 0.93 Å. In the eighth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(24) atom. The C(29)-N(4) bond length is 1.40 Å. The C(29)-H(24) bond length is 0.93 Å. In the ninth C site, C(27) is bonded in a distorted single-bond geometry to one C(73) and one H(22) atom. The C(27)-C(73) bond length is 1.38 Å. The C(27)-H(22) bond length is 0.93 Å. In the tenth C site, C(31) is bonded in a distorted single-bond geometry to one C(73) and one H(26) atom. The C(31)-C(73) bond length is 1.37 Å. The C(31)-H(26) bond length is 0.93 Å. In the eleventh C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(70), one N(1), and one H(30) atom. The C(35)-C(70) bond length is 1.42 Å. The C(35)-N(1) bond length is 1.30 Å. The C(35)-H(30) bond length is 0.93 Å. In the twelfth C site, C(37) is bonded in a trigonal planar geometry to one C(10), one C(70), and one C(93) atom. The C(37)-C(70) bond length is 1.34 Å. In the thirteenth C site, C(38) is bonded in a distorted single-bond geometry to one C(10) and one H(32) atom. The C(38)-H(32) bond length is 0.93 Å. In the fourteenth C site, C(49) is bonded in a trigonal planar geometry to one C(13), one C(72), and one C(73) atom. The C(49)-C(72) bond length is 1.35 Å. The C(49)-C(73) bond length is 1.47 Å. In the fifteenth C site, C(56) is bonded in a trigonal planar geometry to one C(60), one C(66), and one C(83) atom. The C(56)-C(60) bond length is 1.47 Å. The C(56)-C(66) bond length is 1.34 Å. The C(56)-C(83) bond length is 1.38 Å. In the sixteenth C site, C(59) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(16), and one H(47) atom. The C(59)-N(16) bond length is 1.29 Å. The C(59)-H(47) bond length is 0.93 Å. In the seventeenth C site, C(60) is bonded in a trigonal planar geometry to one C(56), one C(75), and one C(91) atom. The C(60)-C(75) bond length is 1.35 Å. In the eighteenth C site, C(65) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(52) atom. The C(65)-N(2) bond length is 1.39 Å. The C(65)-H(52) bond length is 0.93 Å. In the nineteenth C site, C(66) is bonded in a distorted single-bond geometry to one C(56) and one H(53) atom. The C(66)-H(53) bond length is 0.93 Å. In the twentieth C site, C(67) is bonded in a distorted bent 120 degrees geometry to one C(82), one N(2), and one H(54) atom. The C(67)-C(82) bond length is 1.40 Å. The C(67)-N(2) bond length is 1.38 Å. The C(67)-H(54) bond length is 0.93 Å. In the twenty-first C site, C(70) is bonded in a distorted trigonal planar geometry to one C(35), one C(37), and one H(57) atom. The C(70)-H(57) bond length is 0.93 Å. In the twenty-second C site, C(71) is bonded in a distorted bent 120 degrees geometry to one N(16) and one H(58) atom. The C(71)-N(16) bond length is 1.34 Å. The C(71)-H(58) bond length is 0.93 Å. In the twenty-third C site, C(72) is bonded in a distorted single-bond geometry to one C(49) and one H(59) atom. The C(72)-H(59) bond length is 0.93 Å. In the twenty-fourth C site, C(73) is bonded in a trigonal planar geometry to one C(27), one C(31), and one C(49) atom. In the twenty-fifth C site, C(78) is bonded in a distorted bent 120 degrees geometry to one N(20) and one H(63) atom. The C(78)-N(20) bond length is 1.32 Å. The C(78)-H(63) bond length is 0.93 Å. In the twenty-sixth C site, C(79) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(64) atom. The C(79)-N(3) bond length is 1.29 Å. The C(79)-H(64) bond length is 0.93 Å. In the twenty-seventh C site, C(75) is bonded in a distorted single-bond geometry to one C(60) and one H(60) atom. The C(75)-H(60) bond length is 0.93 Å. In the twenty-eighth C site, C(82) is bonded in a distorted single-bond geometry to one C(10), one C(67), and one H(66) atom. The C(82)-H(66) bond length is 0.93 Å. In the twenty-ninth C site, C(83) is bonded in a distorted trigonal planar geometry to one C(26), one C(56), and one H(67) atom. The C(83)-H(67) bond length is 0.93 Å. In the thirtieth C site, C(84) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(68) atom. The C(84)-N(4) bond length is 1.33 Å. The C(84)-H(68) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(16) is bonded in a trigonal planar geometry to one Cu(2), one C(59), and one C(71) atom. In the second N site, N(20) is bonded in a trigonal planar geometry to one Cu(1), one C(7), and one C(78) atom. In the third N site, N(1) is bonded in a trigonal planar geometry to one Cu(2), one C(19), and one C(35) atom. In the fourth N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(65), and one C(67) atom. In the fifth N site, N(3) is bonded in a trigonal planar geometry to one Cu(2), one C(26), and one C(79) atom. In the sixth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(29), and one C(84) atom. There are twenty-four inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the fifth H site, H(22) is bonded in a single-bond geometry to one C(27) atom. In the sixth H site, H(24) is bonded in a single-bond geometry to one C(29) atom. In the seventh H site, H(26) is bonded in a single-bond geometry to one C(31) atom. In the eighth H site, H(30) is bonded in a single-bond geometry to one C(35) atom. In the ninth H site, H(32) is bonded in a single-bond geometry to one C(38) atom. In the tenth H site, H(47) is bonded in a single-bond geometry to one C(59) atom. In the eleventh H site, H(52) is bonded in a single-bond geometry to one C(65) atom. In the twelfth H site, H(53) is bonded in a single-bond geometry to one C(66) atom. In the thirteenth H site, H(54) is bonded in a single-bond geometry to one C(67) atom. In the fourteenth H site, H(57) is bonded in a single-bond geometry to one C(70) atom. In the fifteenth H site, H(58) is bonded in a single-bond geometry to one C(71) atom. In the sixteenth H site, H(59) is bonded in a single-bond geometry to one C(72) atom. In the seventeenth H site, H(63) is bonded in a single-bond geometry to one C(78) atom. In the eighteenth H site, H(64) is bonded in a single-bond geometry to one C(79) atom. In the nineteenth H site, H(66) is bonded in a single-bond geometry to one C(82) atom. In the twentieth H site, H(68) is bonded in a single-bond geometry to one C(84) atom. In the twenty-first H site, H(67) is bonded in a single-bond geometry to one C(83) atom. In the twenty-second H site, H(74) is bonded in a single-bond geometry to one C(91) atom. In the twenty-third H site, H(76) is bonded in a single-bond geometry to one C(93) atom. In the twenty-fourth H site, H(60) is bonded in a single-bond geometry to one C(75) atom. In each CuH12(C7N2)2 cluster, Cu(5) is bonded in a rectangular see-saw-like geometry to one N(13), one N(15), one N(5), and one N(7) atom. The Cu(5)-N(13) bond length is 1.97 Å. The Cu(5)-N(15) bond length is 1.99 Å. The Cu(5)-N(5) bond length is 1.98 Å. The Cu(5)-N(7) bond length is 2.02 Å. There are fourteen inequivalent C sites. In the first C site, C(98) is bonded in a trigonal planar geometry to one C(15), one C(76), and one C(99) atom. The C(98)-C(15) bond length is 1.39 Å. The C(98)-C(76) bond length is 1.38 Å. The C(98)-C(99) bond length is 1.50 Å. In the second C site, C(99) is bonded in a trigonal planar geometry to one C(100), one C(80), and one C(98) atom. The C(99)-C(100) bond length is 1.46 Å. The C(99)-C(80) bond length is 1.36 Å. In the third C site, C(100) is bonded in a distorted single-bond geometry to one C(99) and one H(80) atom. The C(100)-H(80) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(15) and one H(4) atom. The C(5)-N(15) bond length is 1.35 Å. The C(5)-H(4) bond length is 0.93 Å. In the fifth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(9) atom. The C(12)-N(5) bond length is 1.29 Å. The C(12)-H(9) bond length is 0.93 Å. In the sixth C site, C(15) is bonded in a distorted single-bond geometry to one C(98) and one H(12) atom. The C(15)-H(12) bond length is 0.93 Å. In the seventh C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(17) atom. The C(21)-N(5) bond length is 1.31 Å. The C(21)-H(17) bond length is 0.93 Å. In the eighth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(20) atom. The C(25)-N(7) bond length is 1.32 Å. The C(25)-H(20) bond length is 0.93 Å. In the ninth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(76), one N(13), and one H(28) atom. The C(33)-C(76) bond length is 1.39 Å. The C(33)-N(13) bond length is 1.34 Å. The C(33)-H(28) bond length is 0.93 Å. In the tenth C site, C(43) is bonded in a distorted bent 120 degrees geometry to one N(13) and one H(37) atom. The C(43)-N(13) bond length is 1.34 Å. The C(43)-H(37) bond length is 0.93 Å. In the eleventh C site, C(45) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(39) atom. The C(45)-N(7) bond length is 1.35 Å. The C(45)-H(39) bond length is 0.93 Å. In the twelfth C site, C(64) is bonded in a distorted bent 120 degrees geometry to one N(15) and one H(51) atom. The C(64)-N(15) bond length is 1.36 Å. The C(64)-H(51) bond length is 0.93 Å. In the thirteenth C site, C(76) is bonded in a distorted single-bond geometry to one C(33), one C(98), and one H(61) atom. The C(76)-H(61) bond length is 0.93 Å. In the fourteenth C site, C(80) is bonded in a distorted single-bond geometry to one C(99) and one H(65) atom. The C(80)-H(65) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(13) is bonded in a trigonal planar geometry to one Cu(5), one C(33), and one C(43) atom. In the second N site, N(15) is bonded in a trigonal planar geometry to one Cu(5), one C(5), and one C(64) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Cu(5), one C(12), and one C(21) atom. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one Cu(5), one C(25), and one C(45) atom. There are twelve inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the sixth H site, H(28) is bonded in a single-bond geometry to one C(33) atom. In the seventh H site, H(37) is bonded in a single-bond geometry to one C(43) atom. In the eighth H site, H(39) is bonded in a single-bond geometry to one C(45) atom. In the ninth H site, H(51) is bonded in a single-bond geometry to one C(64) atom. In the tenth H site, H(61) is bonded in a single-bond geometry to one C(76) atom. In the eleventh H site, H(65) is bonded in a single-bond geometry to one C(80) atom. In the twelfth H site, H(80) is bonded in a single-bond geometry to one C(100) atom. In each CuH20(C13N2)2 cluster, Cu(6) is bonded in a rectangular see-saw-like geometry to one N(17), one N(19), one N(6), and one N(8) atom. The Cu(6)-N(17) bond length is 1.99 Å. The Cu(6)-N(19) bond length is 2.01 Å. The Cu(6)-N(6) bond length is 1.98 Å. The Cu(6)-N(8) bond length is 2.02 Å. There are twenty-six inequivalent C sites. In the first C site, C(86) is bonded in a trigonal planar geometry to one C(2), one C(23), and one C(4) atom. The C(86)-C(2) bond length is 1.39 Å. The C(86)-C(23) bond length is 1.39 Å. The C(86)-C(4) bond length is 1.52 Å. In the second C site, C(87) is bonded in a distorted single-bond geometry to one C(74) and one H(70) atom. The C(87)-C(74) bond length is 1.45 Å. The C(87)-H(70) bond length is 0.93 Å. In the third C site, C(92) is bonded in a distorted single-bond geometry to one C(50) and one H(75) atom. The C(92)-C(50) bond length is 1.36 Å. The C(92)-H(75) bond length is 0.93 Å. In the fourth C site, C(94) is bonded in a distorted bent 120 degrees geometry to one N(19) and one H(77) atom. The C(94)-N(19) bond length is 1.37 Å. The C(94)-H(77) bond length is 0.93 Å. In the fifth C site, C(96) is bonded in a distorted bent 120 degrees geometry to one N(17) and one H(79) atom. The C(96)-N(17) bond length is 1.34 Å. The C(96)-H(79) bond length is 0.93 Å. In the sixth C site, C(1) is bonded in a distorted single-bond geometry to one C(74) and one H(1) atom. The C(1)-C(74) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.93 Å. In the seventh C site, C(2) is bonded in a distorted trigonal planar geometry to one C(36), one C(86), and one H(2) atom. The C(2)-C(36) bond length is 1.41 Å. The C(2)-H(2) bond length is 0.93 Å. In the eighth C site, C(3) is bonded in a bent 120 degrees geometry to one N(6) and one H(3) atom. The C(3)-N(6) bond length is 1.29 Å. The C(3)-H(3) bond length is 0.93 Å. In the ninth C site, C(4) is bonded in a trigonal planar geometry to one C(14), one C(69), and one C(86) atom. The C(4)-C(14) bond length is 1.45 Å. The C(4)-C(69) bond length is 1.35 Å. In the tenth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(5) atom. The C(6)-N(8) bond length is 1.30 Å. The C(6)-H(5) bond length is 0.93 Å. In the eleventh C site, C(8) is bonded in a trigonal planar geometry to one C(50), one C(52), and one C(58) atom. The C(8)-C(50) bond length is 1.48 Å. The C(8)-C(52) bond length is 1.39 Å. The C(8)-C(58) bond length is 1.41 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(4) and one H(11) atom. The C(14)-H(11) bond length is 0.93 Å. In the thirteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(22), one C(81), and one H(15) atom. The C(18)-C(22) bond length is 1.37 Å. The C(18)-C(81) bond length is 1.38 Å. The C(18)-H(15) bond length is 0.93 Å. In the fourteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(8), and one H(18) atom. The C(22)-N(8) bond length is 1.32 Å. The C(22)-H(18) bond length is 0.93 Å. In the fifteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(86) and one H(19) atom. The C(23)-H(19) bond length is 0.93 Å. In the sixteenth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(19), and one H(31) atom. The C(36)-N(19) bond length is 1.34 Å. The C(36)-H(31) bond length is 0.93 Å. In the seventeenth C site, C(48) is bonded in a distorted single-bond geometry to one C(50) and one H(41) atom. The C(48)-C(50) bond length is 1.40 Å. The C(48)-H(41) bond length is 0.93 Å. In the eighteenth C site, C(50) is bonded in a trigonal planar geometry to one C(48), one C(8), and one C(92) atom. In the nineteenth C site, C(52) is bonded in a distorted trigonal planar geometry to one C(53), one C(8), and one H(43) atom. The C(52)-C(53) bond length is 1.34 Å. The C(52)-H(43) bond length is 0.93 Å. In the twentieth C site, C(53) is bonded in a distorted bent 120 degrees geometry to one C(52), one N(17), and one H(44) atom. The C(53)-N(17) bond length is 1.33 Å. The C(53)-H(44) bond length is 0.93 Å. In the twenty-first C site, C(54) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(45) atom. The C(54)-N(6) bond length is 1.35 Å. The C(54)-H(45) bond length is 0.93 Å. In the twenty-second C site, C(58) is bonded in a distorted single-bond geometry to one C(8) and one H(46) atom. The C(58)-H(46) bond length is 0.93 Å. In the twenty-third C site, C(63) is bonded in a distorted single-bond geometry to one C(81) and one H(50) atom. The C(63)-C(81) bond length is 1.38 Å. The C(63)-H(50) bond length is 0.93 Å. In the twenty-fourth C site, C(69) is bonded in a distorted single-bond geometry to one C(4) and one H(56) atom. The C(69)-H(56) bond length is 0.93 Å. In the twenty-fifth C site, C(74) is bonded in a trigonal planar geometry to one C(1), one C(81), and one C(87) atom. The C(74)-C(81) bond length is 1.48 Å. In the twenty-sixth C site, C(81) is bonded in a trigonal planar geometry to one C(18), one C(63), and one C(74) atom. There are four inequivalent N sites. In the first N site, N(17) is bonded in a trigonal planar geometry to one Cu(6), one C(53), and one C(96) atom. In the second N site, N(19) is bonded in a trigonal planar geometry to one Cu(6), one C(36), and one C(94) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Cu(6), one C(3), and one C(54) atom. In the fourth N site, N(8) is bonded in a trigonal planar geometry to one Cu(6), one C(22), and one C(6) atom. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(31) is bonded in a single-bond geometry to one C(36) atom. In the tenth H site, H(41) is bonded in a single-bond geometry to one C(48) atom. In the eleventh H site, H(43) is bonded in a single-bond geometry to one C(52) atom. In the twelfth H site, H(44) is bonded in a single-bond geometry to one C(53) atom. In the thirteenth H site, H(45) is bonded in a single-bond geometry to one C(54) atom. In the fourteenth H site, H(46) is bonded in a single-bond geometry to one C(58) atom. In the fifteenth H site, H(50) is bonded in a single-bond geometry to one C(63) atom. In the sixteenth H site, H(56) is bonded in a single-bond geometry to one C(69) atom. In the seventeenth H site, H(70) is bonded in a single-bond geometry to one C(87) atom. In the eighteenth H site, H(75) is bonded in a single-bond geometry to one C(92) atom. In the nineteenth H site, H(77) is bonded in a single-bond geometry to one C(94) atom. In the twentieth H site, H(79) is bonded in a single-bond geometry to one C(96) atom. Linkers: 20 c1cc(-c2ccncc2)ccn1. Metal clusters: 12 [Cu]. The MOF has largest included sphere 8.35 A, density 0.52 g/cm3, surface area 4927.31 m2/g, accessible volume 1.47 cm3/g