CoZn2C56NH32O13(CH)3 crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and four CoZn2C56NH32O13 clusters. In each CoZn2C56NH32O13 cluster, Co(1) is bonded to one N(1), one O(7), two equivalent O(4), and two equivalent O(6) atoms to form CoNO5 octahedra that share corners with two equivalent Zn(1)O4 tetrahedra. The Co(1)-N(1) bond length is 2.12 Å. The Co(1)-O(7) bond length is 2.12 Å. Both Co(1)-O(4) bond lengths are 2.08 Å. Both Co(1)-O(6) bond lengths are 2.07 Å. Zn(1) is bonded to one O(1), one O(3), one O(5), and one O(7) atom to form ZnO4 tetrahedra that share  a cornercorner with one Co(1)NO5 octahedra and  a cornercorner with one Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 76°. The Zn(1)-O(1) bond length is 1.94 Å. The Zn(1)-O(3) bond length is 1.96 Å. The Zn(1)-O(5) bond length is 1.94 Å. The Zn(1)-O(7) bond length is 2.00 Å. There are twenty-eight inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(1) bond length is 1.49 Å. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(7) bond length is 1.40 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the third C site, C(7) is bonded in a single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(8) bond length is 1.49 Å. In the sixth C site, C(6) is bonded in a single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(5), and one C(9) atom. The C(8)-C(13) bond length is 1.39 Å. The C(8)-C(9) bond length is 1.39 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(5) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(5) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(9) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(14) bond length is 1.48 Å. In the tenth C site, C(11) is bonded in a single-bond geometry to one C(10), one C(12), and one H(6) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(6) bond length is 0.93 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(21) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-C(21) bond length is 1.47 Å. In the twelfth C site, C(13) is bonded in a single-bond geometry to one C(12), one C(8), and one H(7) atom. The C(13)-H(7) bond length is 0.93 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(10), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-C(19) bond length is 1.40 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(8) atom. The C(15)-C(16) bond length is 1.36 Å. The C(15)-H(8) bond length is 0.93 Å. In the fifteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(9) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(9) bond length is 0.93 Å. In the sixteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-C(20) bond length is 1.49 Å. In the seventeenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(10) atom. The C(18)-H(10) bond length is 0.93 Å. In the eighteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(19)-H(11) bond length is 0.93 Å. In the nineteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(3), and one O(4) atom. The C(20)-O(3) bond length is 1.26 Å. The C(20)-O(4) bond length is 1.28 Å. In the twentieth C site, C(21) is bonded in a trigonal planar geometry to one C(12), one C(22), and one C(26) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(26) bond length is 1.40 Å. In the twenty-first C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(12) atom. The C(22)-H(12) bond length is 0.93 Å. In the twenty-second C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(13) atom. The C(23)-C(24) bond length is 1.38 Å. The C(23)-H(13) bond length is 0.93 Å. In the twenty-third C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(27) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-C(27) bond length is 1.49 Å. In the twenty-fourth C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(14) atom. The C(25)-H(14) bond length is 0.93 Å. In the twenty-fifth C site, C(26) is bonded in a distorted single-bond geometry to one C(21) and one H(15) atom. The C(26)-H(15) bond length is 0.93 Å. In the twenty-sixth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(5), and one O(6) atom. The C(27)-O(5) bond length is 1.28 Å. The C(27)-O(6) bond length is 1.25 Å. In the twenty-seventh C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(16) atom. The C(28)-N(1) bond length is 1.34 Å. The C(28)-H(16) bond length is 0.93 Å. In the twenty-eighth C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.24 Å. N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent C(28) atoms. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(28) atom. There are seven inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(20) atom. In the second O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(20) atom. In the third O site, O(7) is bonded in a trigonal non-coplanar geometry to one Co(1) and two equivalent Zn(1) atoms. In the fourth O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the fifth O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the sixth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(27) atom. In the seventh O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(27) atom. Linkers: 8 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C([O])=O)cc3)c2)cc1. Metal clusters: 8 [Zn] ,4 [Co]. The MOF has largest included sphere 10.25 A, density 0.85 g/cm3, surface area 4545.80 m2/g, accessible volume 0.72 cm3/g