Zn4C60O7 crystallizes in the cubic I2_13 space group. The structure consists of a Zn4C60O7 framework. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a single-bond geometry to one O(3) atom. The Zn(1)-O(3) bond length is 1.93 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one O(3) and three equivalent O(1) atoms. The Zn(2)-O(3) bond length is 1.95 Å. All Zn(2)-O(1) bond lengths are 1.94 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(17), one C(2), and one C(6) atom. The C(1)-C(17) bond length is 1.40 Å. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.39 Å. In the second C site, C(2) is bonded in a bent 120 degrees geometry to one C(1) and one C(3) atom. The C(2)-C(3) bond length is 1.39 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(11), one C(2), and one C(4) atom. The C(3)-C(11) bond length is 1.63 Å. The C(3)-C(4) bond length is 1.39 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-C(7) bond length is 1.75 Å. In the fifth C site, C(5) is bonded in a bent 120 degrees geometry to one C(4) and one C(6) atom. The C(5)-C(6) bond length is 1.39 Å. In the sixth C site, C(6) is bonded in a bent 120 degrees geometry to one C(1) and one C(5) atom. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(4) and two equivalent C(9) atoms. There is one shorter (1.33 Å) and one longer (1.34 Å) C(7)-C(9) bond length. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(11) and one C(13) atom. The C(8)-C(11) bond length is 1.64 Å. The C(8)-C(13) bond length is 1.42 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(11) and two equivalent C(7) atoms. The C(9)-C(11) bond length is 1.66 Å. In the tenth C site, C(10) is bonded in a single-bond geometry to one C(11) and one C(12) atom. The C(10)-C(11) bond length is 1.60 Å. The C(10)-C(12) bond length is 1.48 Å. In the eleventh C site, C(11) is bonded in a tetrahedral geometry to one C(10), one C(3), one C(8), and one C(9) atom. In the twelfth C site, C(12) is bonded in a single-bond geometry to one C(10) atom. In the thirteenth C site, C(13) is bonded in a single-bond geometry to one C(8) atom. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(20) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-C(19) bond length is 1.39 Å. The C(14)-C(20) bond length is 1.54 Å. In the fifteenth C site, C(15) is bonded in a bent 120 degrees geometry to one C(14) and one C(16) atom. The C(15)-C(16) bond length is 1.39 Å. In the sixteenth C site, C(16) is bonded in a bent 120 degrees geometry to one C(15) and one C(17) atom. The C(16)-C(17) bond length is 1.39 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(1), one C(16), and one C(18) atom. The C(17)-C(18) bond length is 1.39 Å. In the eighteenth C site, C(18) is bonded in a single-bond geometry to one C(17) atom. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) atom. In the twentieth C site, C(20) is bonded in a 2-coordinate geometry to one C(14), one O(1), and one O(2) atom. The C(20)-O(1) bond length is 1.20 Å. The C(20)-O(2) bond length is 1.23 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(20) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(20) atom. In the third O site, O(3) is bonded in a tetrahedral geometry to one Zn(2) and three equivalent Zn(1) atoms. Linkers: 8 [C][C]C1([C][C])c2[c]c(-c3[c][c]c(C([O])=O)[c][c]3)[c][c]c2-c2c1c1c(c3c2C([C][C])([C][C])c2[c]c(-c4[c][c]c(C([O])=O)[c][c]4)[c][c]c2-3)C([C][C])([C][C])c2[c]c(-c3[c][c]c(C([O])=O)[c][c]3)[c][c]c2-1. Metal clusters: 8 [Zn]O[C]O[Zn]1O[C]O[Zn]O[Zn]O[C]O1. RCSR code: srs. The MOF has largest included sphere 18.71 A, density 0.32 g/cm3, surface area 4695.42 m2/g, accessible volume 2.74 cm3/g