Zn9Si4H64(C55O17)2(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a Zn9Si4H64(C55O17)2 framework. In the Zn9Si4H64(C55O17)2 framework, there are nine inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(14), one O(28), one O(3), and one O(5) atom to form corner-sharing ZnO5 trigonal bipyramids. The Zn(1)-O(1) bond length is 1.95 Å. The Zn(1)-O(14) bond length is 2.21 Å. The Zn(1)-O(28) bond length is 1.93 Å. The Zn(1)-O(3) bond length is 2.05 Å. The Zn(1)-O(5) bond length is 1.93 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(2), one O(32), and one O(34) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(6)O4 tetrahedra and  a cornercorner with one Zn(1)O5 trigonal bipyramid. The Zn(2)-O(1) bond length is 1.94 Å. The Zn(2)-O(2) bond length is 1.95 Å. The Zn(2)-O(32) bond length is 1.95 Å. The Zn(2)-O(34) bond length is 1.93 Å. In the third Zn site, Zn(3) is bonded in a distorted see-saw-like geometry to one O(10), one O(15), one O(19), and one O(4) atom. The Zn(3)-O(10) bond length is 1.99 Å. The Zn(3)-O(15) bond length is 2.17 Å. The Zn(3)-O(19) bond length is 2.00 Å. The Zn(3)-O(4) bond length is 2.09 Å. In the fourth Zn site, Zn(4) is bonded in a distorted see-saw-like geometry to one O(11), one O(20), one O(4), and one O(9) atom. The Zn(4)-O(11) bond length is 2.15 Å. The Zn(4)-O(20) bond length is 2.07 Å. The Zn(4)-O(4) bond length is 2.02 Å. The Zn(4)-O(9) bond length is 1.96 Å. In the fifth Zn site, Zn(5) is bonded in a see-saw-like geometry to one O(1), one O(13), one O(27), and one O(7) atom. The Zn(5)-O(1) bond length is 1.99 Å. The Zn(5)-O(13) bond length is 1.99 Å. The Zn(5)-O(27) bond length is 2.12 Å. The Zn(5)-O(7) bond length is 2.12 Å. In the sixth Zn site, Zn(6) is bonded to one O(1), one O(31), one O(6), and one O(8) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(2)O4 tetrahedra and  a cornercorner with one Zn(1)O5 trigonal bipyramid. The Zn(6)-O(1) bond length is 1.88 Å. The Zn(6)-O(31) bond length is 2.02 Å. The Zn(6)-O(6) bond length is 1.93 Å. The Zn(6)-O(8) bond length is 1.95 Å. In the seventh Zn site, Zn(7) is bonded in a distorted tetrahedral geometry to one H(1), one O(12), one O(16), one O(25), and one O(4) atom. The Zn(7)-H(1) bond length is 2.17 Å. The Zn(7)-O(12) bond length is 1.99 Å. The Zn(7)-O(16) bond length is 1.93 Å. The Zn(7)-O(25) bond length is 1.97 Å. The Zn(7)-O(4) bond length is 1.93 Å. In the eighth Zn site, Zn(8) is bonded in a tetrahedral geometry to one O(18), one O(21), one O(24), and one O(29) atom. The Zn(8)-O(18) bond length is 1.96 Å. The Zn(8)-O(21) bond length is 1.96 Å. The Zn(8)-O(24) bond length is 1.95 Å. The Zn(8)-O(29) bond length is 1.88 Å. In the ninth Zn site, Zn(9) is bonded in a trigonal non-coplanar geometry to one O(17), one O(22), and one O(23) atom. The Zn(9)-O(17) bond length is 1.97 Å. The Zn(9)-O(22) bond length is 1.98 Å. The Zn(9)-O(23) bond length is 1.83 Å. There are four inequivalent Si sites. In the first Si site, Si(1) is bonded in a tetrahedral geometry to one C(12), one C(19), one C(26), and one C(5) atom. The Si(1)-C(12) bond length is 1.88 Å. The Si(1)-C(19) bond length is 1.89 Å. The Si(1)-C(26) bond length is 1.86 Å. The Si(1)-C(5) bond length is 1.88 Å. In the second Si site, Si(2) is bonded in a tetrahedral geometry to one C(33), one C(40), one C(47), and one C(54) atom. The Si(2)-C(33) bond length is 1.92 Å. The Si(2)-C(40) bond length is 1.89 Å. The Si(2)-C(47) bond length is 1.89 Å. The Si(2)-C(54) bond length is 1.85 Å. In the third Si site, Si(3) is bonded in a tetrahedral geometry to one C(61), one C(68), one C(75), and one C(82) atom. The Si(3)-C(61) bond length is 1.89 Å. The Si(3)-C(68) bond length is 1.87 Å. The Si(3)-C(75) bond length is 1.85 Å. The Si(3)-C(82) bond length is 1.84 Å. In the fourth Si site, Si(4) is bonded in a tetrahedral geometry to one C(103), one C(110), one C(89), and one C(96) atom. The Si(4)-C(103) bond length is 1.86 Å. The Si(4)-C(110) bond length is 1.90 Å. The Si(4)-C(89) bond length is 1.88 Å. The Si(4)-C(96) bond length is 1.87 Å. There are one hundred and ten inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(2), and one O(3) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(2) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.23 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(3) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(4) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one Si(1), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.39 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(5) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(5) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(6) atom. The C(7)-H(6) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(5), and one O(6) atom. The C(8)-C(9) bond length is 1.50 Å. The C(8)-O(5) bond length is 1.26 Å. The C(8)-O(6) bond length is 1.30 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(14) bond length is 1.39 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(7) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(7) bond length is 0.95 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(8) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(8) bond length is 0.95 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one Si(1), one C(11), and one C(13) atom. The C(12)-C(13) bond length is 1.39 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(9) atom. The C(13)-H(9) bond length is 0.95 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(10) atom. The C(14)-H(10) bond length is 0.95 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(7), and one O(8) atom. The C(15)-C(16) bond length is 1.51 Å. The C(15)-O(7) bond length is 1.21 Å. The C(15)-O(8) bond length is 1.26 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-C(21) bond length is 1.39 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(11,14,19) atom. The C(17)-H(11,14,19) bond length is 0.95 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(12,13) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(12,13) bond length is 0.95 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one Si(1), one C(18), and one C(20) atom. The C(19)-C(20) bond length is 1.39 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(12,13) atom. The C(20)-H(12,13) bond length is 0.95 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(11,14,19) atom. The C(21)-H(11,14,19) bond length is 0.95 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(10), and one O(9) atom. The C(22)-C(23) bond length is 1.51 Å. The C(22)-O(10) bond length is 1.28 Å. The C(22)-O(9) bond length is 1.28 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-C(28) bond length is 1.39 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(15) atom. The C(24)-H(15) bond length is 0.95 Å. In the twenty-fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(26) and one H(16,17) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-H(16,17) bond length is 0.95 Å. In the twenty-sixth C site, C(26) is bonded in a distorted trigonal planar geometry to one Si(1), one C(25), and one C(27) atom. The C(26)-C(27) bond length is 1.39 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(16,17) atom. The C(27)-H(16,17) bond length is 0.95 Å. In the twenty-eighth C site, C(28) is bonded in a distorted single-bond geometry to one C(23) and one H(18) atom. The C(28)-H(18) bond length is 0.95 Å. In the twenty-ninth C site, C(29) is bonded in a bent 120 degrees geometry to one C(30), one O(11), and one O(12) atom. The C(29)-C(30) bond length is 1.41 Å. The C(29)-O(11) bond length is 1.27 Å. The C(29)-O(12) bond length is 1.24 Å. In the thirtieth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(35) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-C(35) bond length is 1.39 Å. In the thirty-first C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(11,14,19) atom. The C(31)-H(11,14,19) bond length is 0.95 Å. In the thirty-second C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(20,21) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-H(20,21) bond length is 0.95 Å. In the thirty-third C site, C(33) is bonded in a trigonal planar geometry to one Si(2), one C(32), and one C(34) atom. The C(33)-C(34) bond length is 1.39 Å. In the thirty-fourth C site, C(34) is bonded in a distorted single-bond geometry to one C(33) and one H(20,21) atom. The C(34)-H(20,21) bond length is 0.95 Å. In the thirty-fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(30) and one H(22) atom. The C(35)-H(22) bond length is 0.95 Å. In the thirty-sixth C site, C(36) is bonded in a bent 120 degrees geometry to one C(37), one O(13), and one O(14) atom. The C(36)-C(37) bond length is 1.42 Å. The C(36)-O(13) bond length is 1.29 Å. The C(36)-O(14) bond length is 1.23 Å. In the thirty-seventh C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one C(42) atom. The C(37)-C(38) bond length is 1.39 Å. The C(37)-C(42) bond length is 1.39 Å. In the thirty-eighth C site, C(38) is bonded in a distorted single-bond geometry to one C(37) and one H(23,26) atom. The C(38)-H(23,26) bond length is 0.95 Å. In the thirty-ninth C site, C(39) is bonded in a distorted single-bond geometry to one C(40) and one H(24,25) atom. The C(39)-C(40) bond length is 1.39 Å. The C(39)-H(24,25) bond length is 0.95 Å. In the fortieth C site, C(40) is bonded in a trigonal planar geometry to one Si(2), one C(39), and one C(41) atom. The C(40)-C(41) bond length is 1.39 Å. In the forty-first C site, C(41) is bonded in a distorted single-bond geometry to one C(40) and one H(24,25) atom. The C(41)-H(24,25) bond length is 0.95 Å. In the forty-second C site, C(42) is bonded in a distorted single-bond geometry to one C(37) and one H(23,26) atom. The C(42)-H(23,26) bond length is 0.95 Å. In the forty-third C site, C(43) is bonded in a bent 120 degrees geometry to one C(44), one O(15), and one O(16) atom. The C(43)-C(44) bond length is 1.51 Å. The C(43)-O(15) bond length is 1.28 Å. The C(43)-O(16) bond length is 1.27 Å. In the forty-fourth C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(49) atom. The C(44)-C(45) bond length is 1.39 Å. The C(44)-C(49) bond length is 1.39 Å. In the forty-fifth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(44), one C(46), and one H(27) atom. The C(45)-C(46) bond length is 1.39 Å. The C(45)-H(27) bond length is 0.95 Å. In the forty-sixth C site, C(46) is bonded in a distorted single-bond geometry to one C(45), one C(47), and one H(28) atom. The C(46)-C(47) bond length is 1.39 Å. The C(46)-H(28) bond length is 0.95 Å. In the forty-seventh C site, C(47) is bonded in a distorted trigonal planar geometry to one Si(2), one C(46), and one C(48) atom. The C(47)-C(48) bond length is 1.39 Å. In the forty-eighth C site, C(48) is bonded in a distorted single-bond geometry to one C(47), one C(49), and one H(29) atom. The C(48)-C(49) bond length is 1.39 Å. The C(48)-H(29) bond length is 0.95 Å. In the forty-ninth C site, C(49) is bonded in a distorted trigonal planar geometry to one C(44), one C(48), and one H(30) atom. The C(49)-H(30) bond length is 0.95 Å. In the fiftieth C site, C(50) is bonded in a bent 120 degrees geometry to one C(51), one O(17), and one O(18) atom. The C(50)-C(51) bond length is 1.40 Å. The C(50)-O(17) bond length is 1.18 Å. The C(50)-O(18) bond length is 1.30 Å. In the fifty-first C site, C(51) is bonded in a trigonal planar geometry to one C(50), one C(52), and one C(56) atom. The C(51)-C(52) bond length is 1.39 Å. The C(51)-C(56) bond length is 1.39 Å. In the fifty-second C site, C(52) is bonded in a distorted trigonal planar geometry to one C(51), one C(53), and one H(31) atom. The C(52)-C(53) bond length is 1.39 Å. The C(52)-H(31) bond length is 0.95 Å. In the fifty-third C site, C(53) is bonded in a distorted trigonal planar geometry to one C(52), one C(54), and one H(32) atom. The C(53)-C(54) bond length is 1.39 Å. The C(53)-H(32) bond length is 0.95 Å. In the fifty-fourth C site, C(54) is bonded in a trigonal planar geometry to one Si(2), one C(53), and one C(55) atom. The C(54)-C(55) bond length is 1.39 Å. In the fifty-fifth C site, C(55) is bonded in a distorted single-bond geometry to one C(54), one C(56), and one H(33) atom. The C(55)-C(56) bond length is 1.39 Å. The C(55)-H(33) bond length is 0.95 Å. In the fifty-sixth C site, C(56) is bonded in a distorted trigonal planar geometry to one C(51), one C(55), and one H(34) atom. The C(56)-H(34) bond length is 0.95 Å. In the fifty-seventh C site, C(57) is bonded in a distorted bent 120 degrees geometry to one C(58), one O(19), and one O(20) atom. The C(57)-C(58) bond length is 1.54 Å. The C(57)-O(19) bond length is 1.27 Å. The C(57)-O(20) bond length is 1.20 Å. In the fifty-eighth C site, C(58) is bonded in a trigonal planar geometry to one C(57), one C(59), and one C(63) atom. The C(58)-C(59) bond length is 1.39 Å. The C(58)-C(63) bond length is 1.39 Å. In the fifty-ninth C site, C(59) is bonded in a distorted trigonal planar geometry to one C(58), one C(60), and one H(35) atom. The C(59)-C(60) bond length is 1.39 Å. The C(59)-H(35) bond length is 0.95 Å. In the sixtieth C site, C(60) is bonded in a distorted single-bond geometry to one C(59), one C(61), and one H(36) atom. The C(60)-C(61) bond length is 1.39 Å. The C(60)-H(36) bond length is 0.95 Å. In the sixty-first C site, C(61) is bonded in a distorted trigonal planar geometry to one Si(3), one C(60), and one C(62) atom. The C(61)-C(62) bond length is 1.39 Å. In the sixty-second C site, C(62) is bonded in a distorted single-bond geometry to one C(61), one C(63), and one H(37) atom. The C(62)-C(63) bond length is 1.39 Å. The C(62)-H(37) bond length is 0.95 Å. In the sixty-third C site, C(63) is bonded in a distorted trigonal planar geometry to one C(58), one C(62), and one H(38) atom. The C(63)-H(38) bond length is 0.95 Å. In the sixty-fourth C site, C(64) is bonded in a bent 120 degrees geometry to one C(65), one O(21), and one O(22) atom. The C(64)-C(65) bond length is 1.41 Å. The C(64)-O(21) bond length is 1.27 Å. The C(64)-O(22) bond length is 1.22 Å. In the sixty-fifth C site, C(65) is bonded in a trigonal planar geometry to one C(64), one C(66), and one C(70) atom. The C(65)-C(66) bond length is 1.39 Å. The C(65)-C(70) bond length is 1.39 Å. In the sixty-sixth C site, C(66) is bonded in a distorted trigonal planar geometry to one C(65), one C(67), and one H(39) atom. The C(66)-C(67) bond length is 1.39 Å. The C(66)-H(39) bond length is 0.95 Å. In the sixty-seventh C site, C(67) is bonded in a single-bond geometry to one C(66), one C(68), and one H(40) atom. The C(67)-C(68) bond length is 1.39 Å. The C(67)-H(40) bond length is 0.95 Å. In the sixty-eighth C site, C(68) is bonded in a distorted trigonal planar geometry to one Si(3), one C(67), and one C(69) atom. The C(68)-C(69) bond length is 1.39 Å. In the sixty-ninth C site, C(69) is bonded in a distorted trigonal planar geometry to one C(68), one C(70), and one H(41) atom. The C(69)-C(70) bond length is 1.39 Å. The C(69)-H(41) bond length is 0.95 Å. In the seventieth C site, C(70) is bonded in a distorted trigonal planar geometry to one C(65), one C(69), and one H(42) atom. The C(70)-H(42) bond length is 0.95 Å. In the seventy-first C site, C(71) is bonded in a bent 120 degrees geometry to one C(72), one O(23), and one O(24) atom. The C(71)-C(72) bond length is 1.51 Å. The C(71)-O(23) bond length is 1.27 Å. The C(71)-O(24) bond length is 1.27 Å. In the seventy-second C site, C(72) is bonded in a trigonal planar geometry to one C(71), one C(73), and one C(77) atom. The C(72)-C(73) bond length is 1.39 Å. The C(72)-C(77) bond length is 1.39 Å. In the seventy-third C site, C(73) is bonded in a distorted trigonal planar geometry to one C(72), one C(74), and one H(43) atom. The C(73)-C(74) bond length is 1.39 Å. The C(73)-H(43) bond length is 0.95 Å. In the seventy-fourth C site, C(74) is bonded in a single-bond geometry to one C(73), one C(75), and one H(44) atom. The C(74)-C(75) bond length is 1.39 Å. The C(74)-H(44) bond length is 0.95 Å. In the seventy-fifth C site, C(75) is bonded in a distorted trigonal planar geometry to one Si(3), one C(74), and one C(76) atom. The C(75)-C(76) bond length is 1.39 Å. In the seventy-sixth C site, C(76) is bonded in a distorted trigonal planar geometry to one C(75), one C(77), and one H(45) atom. The C(76)-C(77) bond length is 1.39 Å. The C(76)-H(45) bond length is 0.95 Å. In the seventy-seventh C site, C(77) is bonded in a distorted trigonal planar geometry to one C(72), one C(76), and one H(46) atom. The C(77)-H(46) bond length is 0.95 Å. In the seventy-eighth C site, C(78) is bonded in a water-like geometry to one C(79), one O(25), and one O(26) atom. The C(78)-C(79) bond length is 1.51 Å. The C(78)-O(25) bond length is 1.28 Å. The C(78)-O(26) bond length is 1.29 Å. In the seventy-ninth C site, C(79) is bonded in a trigonal planar geometry to one C(78), one C(80), and one C(84) atom. The C(79)-C(80) bond length is 1.39 Å. The C(79)-C(84) bond length is 1.39 Å. In the eightieth C site, C(80) is bonded in a distorted trigonal planar geometry to one C(79), one C(81), and one H(47) atom. The C(80)-C(81) bond length is 1.39 Å. The C(80)-H(47) bond length is 0.95 Å. In the eighty-first C site, C(81) is bonded in a distorted single-bond geometry to one C(80), one C(82), and one H(48) atom. The C(81)-C(82) bond length is 1.39 Å. The C(81)-H(48) bond length is 0.95 Å. In the eighty-second C site, C(82) is bonded in a distorted trigonal planar geometry to one Si(3), one C(81), and one C(83) atom. The C(82)-C(83) bond length is 1.39 Å. In the eighty-third C site, C(83) is bonded in a distorted single-bond geometry to one C(82) and one H(49) atom. The C(83)-H(49) bond length is 0.95 Å. In the eighty-fourth C site, C(84) is bonded in a distorted single-bond geometry to one C(79) and one H(50) atom. The C(84)-H(50) bond length is 0.95 Å. In the eighty-fifth C site, C(85) is bonded in a bent 120 degrees geometry to one C(86), one O(27), and one O(28) atom. The C(85)-C(86) bond length is 1.49 Å. The C(85)-O(27) bond length is 1.17 Å. The C(85)-O(28) bond length is 1.33 Å. In the eighty-sixth C site, C(86) is bonded in a trigonal planar geometry to one C(85), one C(87), and one C(91) atom. The C(86)-C(87) bond length is 1.39 Å. The C(86)-C(91) bond length is 1.39 Å. In the eighty-seventh C site, C(87) is bonded in a distorted trigonal planar geometry to one C(86), one C(88), and one H(51) atom. The C(87)-C(88) bond length is 1.39 Å. The C(87)-H(51) bond length is 0.95 Å. In the eighty-eighth C site, C(88) is bonded in a distorted single-bond geometry to one C(87), one C(89), and one H(52) atom. The C(88)-C(89) bond length is 1.39 Å. The C(88)-H(52) bond length is 0.95 Å. In the eighty-ninth C site, C(89) is bonded in a trigonal planar geometry to one Si(4), one C(88), and one C(90) atom. The C(89)-C(90) bond length is 1.39 Å. In the ninetieth C site, C(90) is bonded in a distorted single-bond geometry to one C(89), one C(91), and one H(53) atom. The C(90)-C(91) bond length is 1.39 Å. The C(90)-H(53) bond length is 0.95 Å. In the ninety-first C site, C(91) is bonded in a distorted trigonal planar geometry to one C(86), one C(90), and one H(54) atom. The C(91)-H(54) bond length is 0.95 Å. In the ninety-second C site, C(92) is bonded in a distorted bent 120 degrees geometry to one C(93), one O(29), and one O(30) atom. The C(92)-C(93) bond length is 1.52 Å. The C(92)-O(29) bond length is 1.19 Å. The C(92)-O(30) bond length is 1.25 Å. In the ninety-third C site, C(93) is bonded in a trigonal planar geometry to one C(92), one C(94), and one C(98) atom. The C(93)-C(94) bond length is 1.39 Å. The C(93)-C(98) bond length is 1.39 Å. In the ninety-fourth C site, C(94) is bonded in a distorted trigonal planar geometry to one C(93), one C(95), and one H(55) atom. The C(94)-C(95) bond length is 1.39 Å. The C(94)-H(55) bond length is 0.95 Å. In the ninety-fifth C site, C(95) is bonded in a distorted single-bond geometry to one C(94), one C(96), and one H(56) atom. The C(95)-C(96) bond length is 1.39 Å. The C(95)-H(56) bond length is 0.95 Å. In the ninety-sixth C site, C(96) is bonded in a distorted trigonal planar geometry to one Si(4), one C(95), and one C(97) atom. The C(96)-C(97) bond length is 1.39 Å. In the ninety-seventh C site, C(97) is bonded in a single-bond geometry to one C(96), one C(98), and one H(57) atom. The C(97)-C(98) bond length is 1.39 Å. The C(97)-H(57) bond length is 0.95 Å. In the ninety-eighth C site, C(98) is bonded in a distorted trigonal planar geometry to one C(93), one C(97), and one H(58) atom. The C(98)-H(58) bond length is 0.95 Å. In the ninety-ninth C site, C(99) is bonded in a bent 120 degrees geometry to one C(100), one O(31), and one O(32) atom. The C(99)-C(100) bond length is 1.48 Å. The C(99)-O(31) bond length is 1.27 Å. The C(99)-O(32) bond length is 1.21 Å. In the one hundredth C site, C(100) is bonded in a trigonal planar geometry to one C(101), one C(105), and one C(99) atom. The C(100)-C(101) bond length is 1.39 Å. The C(100)-C(105) bond length is 1.39 Å. In the one hundred and first C site, C(101) is bonded in a distorted trigonal planar geometry to one C(100), one C(102), and one H(59) atom. The C(101)-C(102) bond length is 1.39 Å. The C(101)-H(59) bond length is 0.95 Å. In the one hundred and second C site, C(102) is bonded in a distorted single-bond geometry to one C(101), one C(103), and one H(60) atom. The C(102)-C(103) bond length is 1.39 Å. The C(102)-H(60) bond length is 0.95 Å. In the one hundred and third C site, C(103) is bonded in a distorted trigonal planar geometry to one Si(4), one C(102), and one C(104) atom. The C(103)-C(104) bond length is 1.39 Å. In the one hundred and fourth C site, C(104) is bonded in a single-bond geometry to one C(103) and one H(61) atom. The C(104)-H(61) bond length is 0.95 Å. In the one hundred and fifth C site, C(105) is bonded in a distorted single-bond geometry to one C(100) and one H(62) atom. The C(105)-H(62) bond length is 0.95 Å. In the one hundred and sixth C site, C(106) is bonded in a bent 120 degrees geometry to one C(107), one O(33), and one O(34) atom. The C(106)-C(107) bond length is 1.51 Å. The C(106)-O(33) bond length is 1.29 Å. The C(106)-O(34) bond length is 1.27 Å. In the one hundred and seventh C site, C(107) is bonded in a trigonal planar geometry to one C(106), one C(108), and one C(112) atom. The C(107)-C(108) bond length is 1.39 Å. The C(107)-C(112) bond length is 1.39 Å. In the one hundred and eighth C site, C(108) is bonded in a distorted single-bond geometry to one C(107) and one H(63) atom. The C(108)-H(63) bond length is 0.95 Å. In the one hundred and ninth C site, C(110) is bonded in a distorted single-bond geometry to one Si(4) atom. In the one hundred and tenth C site, C(112) is bonded in a distorted single-bond geometry to one C(107) and one H(66) atom. The C(112)-H(66) bond length is 0.95 Å. There are fifty-seven inequivalent H sites. In the first H site, H(1) is bonded in a distorted bent 120 degrees geometry to one Zn(7) and one O(26) atom. The H(1)-O(26) bond length is 0.84 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(33) atom. The H(2)-O(33) bond length is 0.84 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(11,14,19) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(12,13) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(16,17) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(28) atom. In the sixteenth H site, H(20,21) is bonded in a single-bond geometry to one C(32) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one C(35) atom. In the eighteenth H site, H(23,26) is bonded in a single-bond geometry to one C(38) atom. In the nineteenth H site, H(24,25) is bonded in a single-bond geometry to one C(39) atom. In the twentieth H site, H(27) is bonded in a single-bond geometry to one C(45) atom. In the twenty-first H site, H(28) is bonded in a single-bond geometry to one C(46) atom. In the twenty-second H site, H(29) is bonded in a single-bond geometry to one C(48) atom. In the twenty-third H site, H(30) is bonded in a single-bond geometry to one C(49) atom. In the twenty-fourth H site, H(31) is bonded in a single-bond geometry to one C(52) atom. In the twenty-fifth H site, H(32) is bonded in a single-bond geometry to one C(53) atom. In the twenty-sixth H site, H(33) is bonded in a single-bond geometry to one C(55) atom. In the twenty-seventh H site, H(34) is bonded in a single-bond geometry to one C(56) atom. In the twenty-eighth H site, H(35) is bonded in a single-bond geometry to one C(59) atom. In the twenty-ninth H site, H(36) is bonded in a single-bond geometry to one C(60) atom. In the thirtieth H site, H(37) is bonded in a single-bond geometry to one C(62) atom. In the thirty-first H site, H(38) is bonded in a single-bond geometry to one C(63) atom. In the thirty-second H site, H(39) is bonded in a single-bond geometry to one C(66) atom. In the thirty-third H site, H(40) is bonded in a single-bond geometry to one C(67) atom. In the thirty-fourth H site, H(41) is bonded in a single-bond geometry to one C(69) atom. In the thirty-fifth H site, H(42) is bonded in a single-bond geometry to one C(70) atom. In the thirty-sixth H site, H(43) is bonded in a single-bond geometry to one C(73) atom. In the thirty-seventh H site, H(44) is bonded in a single-bond geometry to one C(74) atom. In the thirty-eighth H site, H(45) is bonded in a single-bond geometry to one C(76) atom. In the thirty-ninth H site, H(46) is bonded in a single-bond geometry to one C(77) atom. In the fortieth H site, H(47) is bonded in a single-bond geometry to one C(80) atom. In the forty-first H site, H(48) is bonded in a single-bond geometry to one C(81) atom. In the forty-second H site, H(49) is bonded in a single-bond geometry to one C(83) atom. In the forty-third H site, H(50) is bonded in a single-bond geometry to one C(84) atom. In the forty-fourth H site, H(51) is bonded in a single-bond geometry to one C(87) atom. In the forty-fifth H site, H(52) is bonded in a single-bond geometry to one C(88) atom. In the forty-sixth H site, H(53) is bonded in a single-bond geometry to one C(90) atom. In the forty-seventh H site, H(54) is bonded in a single-bond geometry to one C(91) atom. In the forty-eighth H site, H(55) is bonded in a single-bond geometry to one C(94) atom. In the forty-ninth H site, H(56) is bonded in a single-bond geometry to one C(95) atom. In the fiftieth H site, H(57) is bonded in a single-bond geometry to one C(97) atom. In the fifty-first H site, H(58) is bonded in a single-bond geometry to one C(98) atom. In the fifty-second H site, H(59) is bonded in a single-bond geometry to one C(101) atom. In the fifty-third H site, H(60) is bonded in a single-bond geometry to one C(102) atom. In the fifty-fourth H site, H(61) is bonded in a single-bond geometry to one C(104) atom. In the fifty-fifth H site, H(62) is bonded in a single-bond geometry to one C(105) atom. In the fifty-sixth H site, H(63) is bonded in a single-bond geometry to one C(108) atom. In the fifty-seventh H site, H(66) is bonded in a single-bond geometry to one C(112) atom. There are thirty-four inequivalent O sites. In the first O site, O(1) is bonded in a tetrahedral geometry to one Zn(1), one Zn(2), one Zn(5), and one Zn(6) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Zn(3), one Zn(4), and one Zn(7) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(8) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(15) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(15) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(22) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Zn(3) and one C(22) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Zn(4) and one C(29) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(29) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(36) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(36) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(43) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(43) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Zn(9) and one C(50) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one Zn(8) and one C(50) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(57) atom. In the twentieth O site, O(20) is bonded in a 2-coordinate geometry to one Zn(4) and one C(57) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 120 degrees geometry to one Zn(8) and one C(64) atom. In the twenty-second O site, O(22) is bonded in a bent 150 degrees geometry to one Zn(9) and one C(64) atom. In the twenty-third O site, O(23) is bonded in a bent 150 degrees geometry to one Zn(9) and one C(71) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Zn(8) and one C(71) atom. In the twenty-fifth O site, O(25) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(78) atom. In the twenty-sixth O site, O(26) is bonded in a water-like geometry to one C(78) and one H(1) atom. In the twenty-seventh O site, O(27) is bonded in a distorted bent 150 degrees geometry to one Zn(5) and one C(85) atom. In the twenty-eighth O site, O(28) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(85) atom. In the twenty-ninth O site, O(29) is bonded in a bent 120 degrees geometry to one Zn(8) and one C(92) atom. In the thirtieth O site, O(30) is bonded in a single-bond geometry to one C(92) atom. In the thirty-first O site, O(31) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(99) atom. In the thirty-second O site, O(32) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(99) atom. In the thirty-third O site, O(33) is bonded in a water-like geometry to one C(106) and one H(2) atom. In the thirty-fourth O site, O(34) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(106) atom. Linkers: 8 [O]C(=O)c1ccc([Si](c2ccc(C([O])=O)cc2)(c2ccc(C([O])=O)cc2)c2ccc(C(=O)O)cc2)cc1 ,8 [O]C(=O)c1ccc([Si](c2ccc(C([O])=O)cc2)(c2ccc(C([O])=O)cc2)c2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 O[C]O[Zn@]12O[C]O[Zn]34O[C]O[Zn](O[C]O3)O[C]O[Zn@@](O[C]O4)(O[C]O1)O2 ,2 O[C]O[Zn@]12O[C]O[Zn]3O[C]O[Zn](O[C]O3)(O[C]O1)O2 ,4 O=[C]O[Zn]12O[C]O[Zn](O[C]O1)O[C]O2 ,2 O[C]O[Zn@@]12O[C]O[Zn]34O[C]O[Zn](O[C]O3)O[C]O[Zn@](O[C]O4)(O[C]O1)O2 ,2 O[C]O[Zn@@]12O[C]O[Zn]3O[C]O[Zn](O[C]O3)(O[C]O1)O2. The MOF has largest included sphere 11.00 A, density 0.62 g/cm3, surface area 4130.95 m2/g, accessible volume 1.31 cm3/g