Cu2C17H18(NO)6(CH3)2 crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of eight 02329_fluka molecules inside a Cu2C17H18(NO)6 framework. In the Cu2C17H18(NO)6 framework, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square pyramidal geometry to one N(1), one N(2), one O(1), one O(3), and one O(4) atom. The Cu(1)-N(1) bond length is 1.91 Å. The Cu(1)-N(2) bond length is 1.96 Å. The Cu(1)-O(1) bond length is 2.02 Å. The Cu(1)-O(3) bond length is 2.24 Å. The Cu(1)-O(4) bond length is 2.01 Å. In the second Cu site, Cu(2) is bonded in a square pyramidal geometry to one N(3), one N(4), one O(2), one O(5), and one O(6) atom. The Cu(2)-N(3) bond length is 1.99 Å. The Cu(2)-N(4) bond length is 1.92 Å. The Cu(2)-O(2) bond length is 2.00 Å. The Cu(2)-O(5) bond length is 2.03 Å. The Cu(2)-O(6) bond length is 2.27 Å. There are seventeen inequivalent C sites. In the first C site, C(17) is bonded in a trigonal non-coplanar geometry to one C(9) and three equivalent H(3,22,23) atoms. The C(17)-C(9) bond length is 1.53 Å. All C(17)-H(3,22,23) bond lengths are 0.96 Å. In the second C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(4) and one O(1) atom. The C(18)-N(4) bond length is 1.28 Å. The C(18)-O(1) bond length is 1.28 Å. In the third C site, C(19) is bonded in a 2-coordinate geometry to one N(4) and one H(20) atom. The C(19)-N(4) bond length is 1.45 Å. The C(19)-H(20) bond length is 0.98 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(1)-O(2) bond length is 1.29 Å. The C(1)-O(3) bond length is 1.23 Å. In the fifth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(16), one C(3), and one N(3) atom. The C(2)-C(16) bond length is 1.48 Å. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(3) bond length is 1.34 Å. In the sixth C site, C(3) is bonded in a trigonal planar geometry to one C(13), one C(2), and one C(7) atom. The C(3)-C(13) bond length is 1.51 Å. The C(3)-C(7) bond length is 1.37 Å. In the seventh C site, C(4) is bonded in a 2-coordinate geometry to one N(1) and one H(9) atom. The C(4)-N(1) bond length is 1.46 Å. The C(4)-H(9) bond length is 0.98 Å. In the eighth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(5) atom. The C(5)-N(1) bond length is 1.29 Å. The C(5)-O(5) bond length is 1.28 Å. In the ninth C site, C(6) is bonded in a trigonal non-coplanar geometry to one C(10); one H(5); and two equivalent H(8,19) atoms. The C(6)-C(10) bond length is 1.48 Å. The C(6)-H(5) bond length is 0.96 Å. Both C(6)-H(8,19) bond lengths are 0.96 Å. In the tenth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(12), one C(3), and one N(6) atom. The C(7)-C(12) bond length is 1.51 Å. The C(7)-N(6) bond length is 1.35 Å. In the eleventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. The C(8)-O(4) bond length is 1.30 Å. The C(8)-O(6) bond length is 1.23 Å. In the twelfth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(14), one C(17), and one N(5) atom. The C(9)-C(14) bond length is 1.37 Å. The C(9)-N(5) bond length is 1.33 Å. In the thirteenth C site, C(10) is bonded in a 3-coordinate geometry to one C(14), one C(6), and one N(2) atom. The C(10)-C(14) bond length is 1.40 Å. The C(10)-N(2) bond length is 1.34 Å. In the fourteenth C site, C(12) is bonded in a trigonal non-coplanar geometry to one C(7); one H(13); and two equivalent H(2,4) atoms. The C(12)-H(13) bond length is 0.96 Å. Both C(12)-H(2,4) bond lengths are 0.96 Å. In the fifteenth C site, C(13) is bonded in a water-like geometry to one C(14), one C(3), one H(17), and one H(24) atom. The C(13)-C(14) bond length is 1.52 Å. The C(13)-H(17) bond length is 0.97 Å. The C(13)-H(24) bond length is 0.97 Å. In the sixteenth C site, C(14) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(9) atom. In the seventeenth C site, C(16) is bonded in a trigonal non-coplanar geometry to one C(2) and three equivalent H(1,10,11) atoms. All C(16)-H(1,10,11) bond lengths are 0.96 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(4), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(10), and one N(5) atom. The N(2)-N(5) bond length is 1.34 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(2), and one N(6) atom. The N(3)-N(6) bond length is 1.34 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(18), and one C(19) atom. In the fifth N site, N(5) is bonded in a 1-coordinate geometry to one C(9), one N(2), and one H(16) atom. The N(5)-H(16) bond length is 0.86 Å. In the sixth N site, N(6) is bonded in a 1-coordinate geometry to one C(7), one N(3), and one H(15) atom. The N(6)-H(15) bond length is 0.86 Å. There are twelve inequivalent H sites. In the first H site, H(1,10,11) is bonded in a single-bond geometry to one C(16) atom. In the second H site, H(2,4) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(3,22,23) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(8,19) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one N(6) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one N(5) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(13) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(18) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(8) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Cu(2) and one C(5) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(8) atom. Linkers: 4 C[C@H]([N]C(=O)C(=O)[N][C@@H](C)C([O])=O)C([O])=O ,4 Cc1n[nH]c(C)c1Cc1c(C)n[nH]c1C. Metal clusters: 8 [Cu]. The MOF has largest included sphere 5.38 A, density 1.21 g/cm3, surface area 4471.45 m2/g, accessible volume 0.45 cm3/g