Mn2CdH16(C2O)16(H11(C7O)2)4 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two H11(C7O)2 clusters and one Mn2CdH16(C2O)16 cluster. In each H11(C7O)2 cluster, there are twenty-eight inequivalent C sites. In the first C site, C(1,45) is bonded in a trigonal planar geometry to one C(2,46); one C(30,74); and one C(6,50) atom. The C(1,45)-C(2,46) bond length is 1.41 Å. The C(1,45)-C(30,74) bond length is 1.45 Å. The C(1,45)-C(6,50) bond length is 1.43 Å. In the second C site, C(2,46) is bonded in a distorted single-bond geometry to one C(1,45); one C(3,47); and one H(1,31) atom. The C(2,46)-C(3,47) bond length is 1.41 Å. The C(2,46)-H(1,31) bond length is 0.93 Å. In the third C site, C(3,47) is bonded in a trigonal planar geometry to one C(2,46); one C(4,48); and one C(41,85) atom. The C(3,47)-C(4,48) bond length is 1.34 Å. The C(3,47)-C(41,85) bond length is 1.49 Å. In the fourth C site, C(4,48) is bonded in a distorted single-bond geometry to one C(3,47); one C(5,49); and one O(9,21) atom. The C(4,48)-C(5,49) bond length is 1.41 Å. The C(4,48)-O(9,21) bond length is 1.43 Å. In the fifth C site, C(5,49) is bonded in a trigonal planar geometry to one C(11,55); one C(4,48); and one C(6,50) atom. The C(5,49)-C(11,55) bond length is 1.47 Å. The C(5,49)-C(6,50) bond length is 1.41 Å. In the sixth C site, C(6,50) is bonded in a distorted single-bond geometry to one C(1,45); one C(5,49); and one O(10,22) atom. The C(6,50)-O(10,22) bond length is 1.40 Å. In the seventh C site, C(7,51) is bonded in a tetrahedral geometry to one H(2,32); two equivalent H(3,4,33,34); and one O(10,22) atom. The C(7,51)-H(2,32) bond length is 0.96 Å. Both C(7,51)-H(3,4,33,34) bond lengths are 0.96 Å. The C(7,51)-O(10,22) bond length is 1.50 Å. In the eighth C site, C(8,52) is bonded in a tetrahedral geometry to one H(6,36); two equivalent H(5,7,35,37); and one O(9,21) atom. The C(8,52)-H(6,36) bond length is 0.96 Å. Both C(8,52)-H(5,7,35,37) bond lengths are 0.96 Å. The C(8,52)-O(9,21) bond length is 1.37 Å. In the ninth C site, C(9,53) is bonded in a tetrahedral geometry to one H(10,40); one H(8,38); one H(9,39); and one O(11,23) atom. The C(9,53)-H(10,40) bond length is 0.96 Å. The C(9,53)-H(8,38) bond length is 0.96 Å. The C(9,53)-H(9,39) bond length is 0.96 Å. The C(9,53)-O(11,23) bond length is 1.50 Å. In the tenth C site, C(10,54) is bonded in a tetrahedral geometry to one H(13,43); two equivalent H(11,12,41,42); and one O(12,24) atom. The C(10,54)-H(13,43) bond length is 0.96 Å. Both C(10,54)-H(11,12,41,42) bond lengths are 0.96 Å. The C(10,54)-O(12,24) bond length is 1.47 Å. In the eleventh C site, C(11,55) is bonded in a trigonal planar geometry to one C(12,56); one C(16,60); and one C(5,49) atom. The C(11,55)-C(12,56) bond length is 1.43 Å. The C(11,55)-C(16,60) bond length is 1.38 Å. In the twelfth C site, C(12,56) is bonded in a distorted single-bond geometry to one C(11,55); one C(13,57); and one O(12,24) atom. The C(12,56)-C(13,57) bond length is 1.34 Å. The C(12,56)-O(12,24) bond length is 1.47 Å. In the thirteenth C site, C(13,57) is bonded in a trigonal planar geometry to one C(12,56); one C(14,58); and one C(17,61) atom. The C(13,57)-C(14,58) bond length is 1.37 Å. The C(13,57)-C(17,61) bond length is 1.52 Å. In the fourteenth C site, C(14,58) is bonded in a distorted single-bond geometry to one C(13,57); one C(15,59); and one H(14,44) atom. The C(14,58)-C(15,59) bond length is 1.36 Å. The C(14,58)-H(14,44) bond length is 0.93 Å. In the fifteenth C site, C(15,59) is bonded in a trigonal planar geometry to one C(14,58); one C(16,60); and one C(23,67) atom. The C(15,59)-C(16,60) bond length is 1.42 Å. The C(15,59)-C(23,67) bond length is 1.46 Å. In the sixteenth C site, C(16,60) is bonded in a single-bond geometry to one C(11,55); one C(15,59); and one O(11,23) atom. The C(16,60)-O(11,23) bond length is 1.36 Å. In the seventeenth C site, C(17,61) is bonded in a trigonal planar geometry to one C(13,57); one C(18,62); and one C(21,65) atom. The C(17,61)-C(18,62) bond length is 1.40 Å. The C(17,61)-C(21,65) bond length is 1.42 Å. In the eighteenth C site, C(18,62) is bonded in a distorted single-bond geometry to one C(17,61) and one H(15,45) atom. The C(18,62)-H(15,45) bond length is 0.93 Å. In the nineteenth C site, C(21,65) is bonded in a distorted single-bond geometry to one C(17,61) and one H(17,47) atom. The C(21,65)-H(17,47) bond length is 0.93 Å. In the twentieth C site, C(23,67) is bonded in a trigonal planar geometry to one C(15,59); one C(24,68); and one C(28,72) atom. The C(23,67)-C(24,68) bond length is 1.43 Å. The C(23,67)-C(28,72) bond length is 1.38 Å. In the twenty-first C site, C(24,68) is bonded in a distorted single-bond geometry to one C(23,67) and one H(18,48) atom. The C(24,68)-H(18,48) bond length is 0.93 Å. In the twenty-second C site, C(28,72) is bonded in a distorted single-bond geometry to one C(23,67) and one H(21,51) atom. The C(28,72)-H(21,51) bond length is 0.93 Å. In the twenty-third C site, C(30,74) is bonded in a trigonal planar geometry to one C(1,45); one C(31,75); and one C(35,79) atom. The C(30,74)-C(31,75) bond length is 1.40 Å. The C(30,74)-C(35,79) bond length is 1.43 Å. In the twenty-fourth C site, C(31,75) is bonded in a distorted single-bond geometry to one C(30,74) and one H(22,52) atom. The C(31,75)-H(22,52) bond length is 0.93 Å. In the twenty-fifth C site, C(35,79) is bonded in a distorted single-bond geometry to one C(30,74) and one H(25,55) atom. The C(35,79)-H(25,55) bond length is 0.93 Å. In the twenty-sixth C site, C(40,84) is bonded in a distorted single-bond geometry to one C(41,85) and one H(27,57) atom. The C(40,84)-C(41,85) bond length is 1.42 Å. The C(40,84)-H(27,57) bond length is 0.93 Å. In the twenty-seventh C site, C(41,85) is bonded in a trigonal planar geometry to one C(3,47); one C(40,84); and one C(42,86) atom. The C(41,85)-C(42,86) bond length is 1.42 Å. In the twenty-eighth C site, C(42,86) is bonded in a distorted single-bond geometry to one C(41,85) and one H(28,58) atom. The C(42,86)-H(28,58) bond length is 0.93 Å. There are nineteen inequivalent H sites. In the first H site, H(1,31) is bonded in a single-bond geometry to one C(2,46) atom. In the second H site, H(2,32) is bonded in a single-bond geometry to one C(7,51) atom. In the third H site, H(3,4,33,34) is bonded in a single-bond geometry to one C(7,51) atom. In the fourth H site, H(5,7,35,37) is bonded in a single-bond geometry to one C(8,52) atom. In the fifth H site, H(6,36) is bonded in a single-bond geometry to one C(8,52) atom. In the sixth H site, H(8,38) is bonded in a single-bond geometry to one C(9,53) atom. In the seventh H site, H(9,39) is bonded in a single-bond geometry to one C(9,53) atom. In the eighth H site, H(10,40) is bonded in a single-bond geometry to one C(9,53) atom. In the ninth H site, H(11,12,41,42) is bonded in a single-bond geometry to one C(10,54) atom. In the tenth H site, H(13,43) is bonded in a single-bond geometry to one C(10,54) atom. In the eleventh H site, H(14,44) is bonded in a single-bond geometry to one C(14,58) atom. In the twelfth H site, H(15,45) is bonded in a single-bond geometry to one C(18,62) atom. In the thirteenth H site, H(17,47) is bonded in a single-bond geometry to one C(21,65) atom. In the fourteenth H site, H(18,48) is bonded in a single-bond geometry to one C(24,68) atom. In the fifteenth H site, H(21,51) is bonded in a single-bond geometry to one C(28,72) atom. In the sixteenth H site, H(22,52) is bonded in a single-bond geometry to one C(31,75) atom. In the seventeenth H site, H(25,55) is bonded in a single-bond geometry to one C(35,79) atom. In the eighteenth H site, H(27,57) is bonded in a single-bond geometry to one C(40,84) atom. In the nineteenth H site, H(28,58) is bonded in a single-bond geometry to one C(42,86) atom. There are four inequivalent O sites. In the first O site, O(9,21) is bonded in a bent 120 degrees geometry to one C(4,48) and one C(8,52) atom. In the second O site, O(10,22) is bonded in a bent 120 degrees geometry to one C(6,50) and one C(7,51) atom. In the third O site, O(11,23) is bonded in a bent 120 degrees geometry to one C(16,60) and one C(9,53) atom. In the fourth O site, O(12,24) is bonded in a bent 120 degrees geometry to one C(10,54) and one C(12,56) atom. In the Mn2CdH16(C2O)16 cluster, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(6), one O(7), and one O(8) atom to form distorted edge-sharing MnO7 pentagonal bipyramids. The Mn(1)-O(1) bond length is 2.36 Å. The Mn(1)-O(2) bond length is 2.44 Å. The Mn(1)-O(3) bond length is 2.44 Å. The Mn(1)-O(4) bond length is 2.34 Å. The Mn(1)-O(6) bond length is 2.16 Å. The Mn(1)-O(7) bond length is 2.41 Å. The Mn(1)-O(8) bond length is 2.25 Å. In the second Mn site, Mn(2) is bonded to one O(1), one O(13), one O(15), one O(17), one O(3), and one O(5) atom to form MnO6 octahedra that share  an edgeedge with one Mn(1)O7 pentagonal bipyramid and  an edgeedge with one Cd(1)O7 pentagonal bipyramid. The Mn(2)-O(1) bond length is 2.23 Å. The Mn(2)-O(13) bond length is 2.23 Å. The Mn(2)-O(15) bond length is 2.16 Å. The Mn(2)-O(17) bond length is 2.11 Å. The Mn(2)-O(3) bond length is 2.16 Å. The Mn(2)-O(5) bond length is 2.11 Å. Cd(1) is bonded to one O(13), one O(14), one O(15), one O(16), one O(18), one O(19), and one O(20) atom to form distorted CdO7 pentagonal bipyramids that share  an edgeedge with one Mn(2)O6 octahedra. The Cd(1)-O(13) bond length is 2.36 Å. The Cd(1)-O(14) bond length is 2.44 Å. The Cd(1)-O(15) bond length is 2.44 Å. The Cd(1)-O(16) bond length is 2.34 Å. The Cd(1)-O(18) bond length is 2.16 Å. The Cd(1)-O(19) bond length is 2.41 Å. The Cd(1)-O(20) bond length is 2.25 Å. There are twenty-four inequivalent C sites. In the first C site, C(66) is bonded in a distorted bent 120 degrees geometry to one C(63), one O(15), and one O(16) atom. The C(66)-C(63) bond length is 1.41 Å. The C(66)-O(15) bond length is 1.29 Å. The C(66)-O(16) bond length is 1.32 Å. In the second C site, C(70) is bonded in a trigonal planar geometry to one C(25,69); one C(27,71); and one C(73) atom. The C(70)-C(25,69) bond length is 1.35 Å. The C(70)-C(27,71) bond length is 1.40 Å. The C(70)-C(73) bond length is 1.51 Å. In the third C site, C(73) is bonded in a distorted bent 120 degrees geometry to one C(70), one O(17), and one O(18) atom. The C(73)-O(17) bond length is 1.26 Å. The C(73)-O(18) bond length is 1.34 Å. In the fourth C site, C(77) is bonded in a trigonal planar geometry to one C(32,76); one C(34,78); and one C(80) atom. The C(77)-C(32,76) bond length is 1.45 Å. The C(77)-C(34,78) bond length is 1.33 Å. The C(77)-C(80) bond length is 1.46 Å. In the fifth C site, C(80) is bonded in a bent 120 degrees geometry to one C(77), one O(13), and one O(14) atom. The C(80)-O(13) bond length is 1.35 Å. The C(80)-O(14) bond length is 1.28 Å. In the sixth C site, C(81) is bonded in a bent 120 degrees geometry to one C(82), one O(19), and one O(20) atom. The C(81)-C(82) bond length is 1.42 Å. The C(81)-O(19) bond length is 1.28 Å. The C(81)-O(20) bond length is 1.34 Å. In the seventh C site, C(82) is bonded in a trigonal planar geometry to one C(39,83); one C(43,87); and one C(81) atom. The C(82)-C(39,83) bond length is 1.37 Å. The C(82)-C(43,87) bond length is 1.42 Å. In the eighth C site, C(19) is bonded in a trigonal planar geometry to one C(20,64); one C(22); and one C(44,88) atom. The C(19)-C(20,64) bond length is 1.40 Å. The C(19)-C(22) bond length is 1.41 Å. The C(19)-C(44,88) bond length is 1.40 Å. In the ninth C site, C(20,64) is bonded in a distorted single-bond geometry to one C(19) and one H(16,46) atom. The C(20,64)-H(16,46) bond length is 0.93 Å. In the tenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(3), and one O(4) atom. The C(22)-O(3) bond length is 1.29 Å. The C(22)-O(4) bond length is 1.32 Å. In the eleventh C site, C(25,69) is bonded in a distorted single-bond geometry to one C(26) and one H(19,49) atom. The C(25,69)-C(26) bond length is 1.35 Å. The C(25,69)-H(19,49) bond length is 0.93 Å. In the twelfth C site, C(26) is bonded in a trigonal planar geometry to one C(25,69); one C(27,71); and one C(29) atom. The C(26)-C(27,71) bond length is 1.40 Å. The C(26)-C(29) bond length is 1.51 Å. In the thirteenth C site, C(27,71) is bonded in a distorted single-bond geometry to one C(26) and one H(20,50) atom. The C(27,71)-H(20,50) bond length is 0.93 Å. In the fourteenth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(5), and one O(6) atom. The C(29)-O(5) bond length is 1.26 Å. The C(29)-O(6) bond length is 1.34 Å. In the fifteenth C site, C(32,76) is bonded in a distorted single-bond geometry to one C(33) and one H(23,53) atom. The C(32,76)-C(33) bond length is 1.45 Å. The C(32,76)-H(23,53) bond length is 0.93 Å. In the sixteenth C site, C(33) is bonded in a trigonal planar geometry to one C(32,76); one C(34,78); and one C(36) atom. The C(33)-C(34,78) bond length is 1.33 Å. The C(33)-C(36) bond length is 1.46 Å. In the seventeenth C site, C(34,78) is bonded in a distorted single-bond geometry to one C(33) and one H(24,54) atom. The C(34,78)-H(24,54) bond length is 0.93 Å. In the eighteenth C site, C(36) is bonded in a bent 120 degrees geometry to one C(33), one O(1), and one O(2) atom. The C(36)-O(1) bond length is 1.35 Å. The C(36)-O(2) bond length is 1.28 Å. In the nineteenth C site, C(37) is bonded in a bent 120 degrees geometry to one C(38), one O(7), and one O(8) atom. The C(37)-C(38) bond length is 1.42 Å. The C(37)-O(7) bond length is 1.28 Å. The C(37)-O(8) bond length is 1.34 Å. In the twentieth C site, C(38) is bonded in a trigonal planar geometry to one C(37); one C(39,83); and one C(43,87) atom. The C(38)-C(39,83) bond length is 1.37 Å. The C(38)-C(43,87) bond length is 1.42 Å. In the twenty-first C site, C(39,83) is bonded in a distorted single-bond geometry to one C(38) and one H(26,56) atom. The C(39,83)-H(26,56) bond length is 0.93 Å. In the twenty-second C site, C(43,87) is bonded in a distorted single-bond geometry to one C(38) and one H(29,59) atom. The C(43,87)-H(29,59) bond length is 0.93 Å. In the twenty-third C site, C(44,88) is bonded in a single-bond geometry to one C(19) and one H(30,60) atom. The C(44,88)-H(30,60) bond length is 0.93 Å. In the twenty-fourth C site, C(63) is bonded in a trigonal planar geometry to one C(20,64); one C(44,88); and one C(66) atom. The C(63)-C(20,64) bond length is 1.40 Å. The C(63)-C(44,88) bond length is 1.40 Å. There are eight inequivalent H sites. In the first H site, H(16,46) is bonded in a single-bond geometry to one C(20,64) atom. In the second H site, H(19,49) is bonded in a single-bond geometry to one C(25,69) atom. In the third H site, H(20,50) is bonded in a single-bond geometry to one C(27,71) atom. In the fourth H site, H(23,53) is bonded in a single-bond geometry to one C(32,76) atom. In the fifth H site, H(24,54) is bonded in a single-bond geometry to one C(34,78) atom. In the sixth H site, H(26,56) is bonded in a single-bond geometry to one C(39,83) atom. In the seventh H site, H(29,59) is bonded in a single-bond geometry to one C(43,87) atom. In the eighth H site, H(30,60) is bonded in a single-bond geometry to one C(44,88) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Mn(1), one Mn(2), and one C(36) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Mn(1) and one C(36) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Mn(1), one Mn(2), and one C(22) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Mn(1) and one C(22) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Mn(2) and one C(29) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(29) atom. In the seventh O site, O(7) is bonded in an L-shaped geometry to one Mn(1) and one C(37) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Mn(1) and one C(37) atom. In the ninth O site, O(13) is bonded in a distorted T-shaped geometry to one Mn(2), one Cd(1), and one C(80) atom. In the tenth O site, O(15) is bonded in a distorted T-shaped geometry to one Mn(2), one Cd(1), and one C(66) atom. In the eleventh O site, O(14) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(80) atom. In the twelfth O site, O(17) is bonded in a bent 150 degrees geometry to one Mn(2) and one C(73) atom. In the thirteenth O site, O(16) is bonded in a water-like geometry to one Cd(1) and one C(66) atom. In the fourteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(73) atom. In the fifteenth O site, O(19) is bonded in an L-shaped geometry to one Cd(1) and one C(81) atom. In the sixteenth O site, O(20) is bonded in an L-shaped geometry to one Cd(1) and one C(81) atom. Linkers: 2 COc1c(-c2ccc(C([O])=O)cc2)cc(-c2ccc(C([O])=O)cc2)c(OC)c1-c1c(OC)c(-c2ccc(C([O])=O)cc2)cc(-c2ccc(C([O])=O)cc2)c1OC. Metal clusters: 1 [C]1O[Mn]23(O1)O[C]O[Mn]14(O[C]O2)(O[C]O3)O[C]O[Cd]2(O[C]O2)(O[C]O1)O[C]O4. RCSR code: flu. The MOF has largest included sphere 9.06 A, density 0.76 g/cm3, surface area 4557.48 m2/g, accessible volume 0.86 cm3/g