Th3C16N3H14O19(CH2)2(C2NH2O)3 is Indium-derived structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight trimethyl isocyanurate molecules, and four Th3C16N3H14O19 clusters. In each Th3C16N3H14O19 cluster, there are three inequivalent Th sites. In the first Th site, Th(1) is bonded in a 8-coordinate geometry to one O(1), one O(10), one O(14), one O(19), one O(20), one O(21), one O(22), and one O(3) atom. The Th(1)-O(1) bond length is 2.45 Å. The Th(1)-O(10) bond length is 2.44 Å. The Th(1)-O(14) bond length is 2.48 Å. The Th(1)-O(19) bond length is 2.48 Å. The Th(1)-O(20) bond length is 2.39 Å. The Th(1)-O(21) bond length is 2.38 Å. The Th(1)-O(22) bond length is 2.40 Å. The Th(1)-O(3) bond length is 2.49 Å. In the second Th site, Th(2) is bonded in a 8-coordinate geometry to one O(12), one O(19), one O(2), one O(20), one O(21), one O(22), one O(4), and one O(6) atom. The Th(2)-O(12) bond length is 2.43 Å. The Th(2)-O(19) bond length is 2.47 Å. The Th(2)-O(2) bond length is 2.44 Å. The Th(2)-O(20) bond length is 2.38 Å. The Th(2)-O(21) bond length is 2.42 Å. The Th(2)-O(22) bond length is 2.40 Å. The Th(2)-O(4) bond length is 2.48 Å. The Th(2)-O(6) bond length is 2.50 Å. In the third Th site, Th(3) is bonded in a 8-coordinate geometry to one O(11), one O(13), one O(15), one O(19), one O(20), one O(21), one O(22), and one O(5) atom. The Th(3)-O(11) bond length is 2.48 Å. The Th(3)-O(13) bond length is 2.50 Å. The Th(3)-O(15) bond length is 2.48 Å. The Th(3)-O(19) bond length is 2.49 Å. The Th(3)-O(20) bond length is 2.35 Å. The Th(3)-O(21) bond length is 2.45 Å. The Th(3)-O(22) bond length is 2.40 Å. The Th(3)-O(5) bond length is 2.41 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.24 Å. In the second C site, C(2) is bonded in a water-like geometry to one C(1), one C(3), one H(1), and one H(2) atom. The C(2)-C(3) bond length is 1.50 Å. The C(2)-H(1) bond length is 0.99 Å. The C(2)-H(2) bond length is 0.99 Å. In the third C site, C(3) is bonded in a 4-coordinate geometry to one C(2), one N(1), one H(3), and one H(4) atom. The C(3)-N(1) bond length is 1.50 Å. The C(3)-H(3) bond length is 0.99 Å. The C(3)-H(4) bond length is 0.99 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(7) atom. The C(4)-N(1) bond length is 1.38 Å. The C(4)-N(2) bond length is 1.37 Å. The C(4)-O(7) bond length is 1.22 Å. In the fifth C site, C(5) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(5,6) atoms. The C(5)-N(2) bond length is 1.47 Å. Both C(5)-H(5,6) bond lengths are 0.99 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one N(2), one N(3), and one O(8) atom. The C(8)-N(2) bond length is 1.37 Å. The C(8)-N(3) bond length is 1.38 Å. The C(8)-O(8) bond length is 1.23 Å. In the seventh C site, C(9) is bonded in a 3-coordinate geometry to one N(3), one H(10), and one H(9) atom. The C(9)-N(3) bond length is 1.49 Å. The C(9)-H(10) bond length is 0.99 Å. The C(9)-H(9) bond length is 0.99 Å. In the eighth C site, C(12) is bonded in a trigonal planar geometry to one N(1), one N(3), and one O(9) atom. The C(12)-N(1) bond length is 1.36 Å. The C(12)-N(3) bond length is 1.37 Å. The C(12)-O(9) bond length is 1.21 Å. In the ninth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one O(10), and one O(11) atom. The C(13)-C(14) bond length is 1.51 Å. The C(13)-O(10) bond length is 1.27 Å. The C(13)-O(11) bond length is 1.23 Å. In the tenth C site, C(14) is bonded in a water-like geometry to one C(13), one H(13), and one H(14) atom. The C(14)-H(13) bond length is 0.99 Å. The C(14)-H(14) bond length is 0.99 Å. In the eleventh C site, C(7) is bonded in a distorted trigonal planar geometry to one O(3) and one O(4) atom. The C(7)-O(3) bond length is 1.29 Å. The C(7)-O(4) bond length is 1.27 Å. In the twelfth C site, C(10) is bonded in a water-like geometry to one C(11) and two equivalent H(11,12) atoms. The C(10)-C(11) bond length is 1.51 Å. Both C(10)-H(11,12) bond lengths are 0.99 Å. In the thirteenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one O(5), and one O(6) atom. The C(11)-O(5) bond length is 1.27 Å. The C(11)-O(6) bond length is 1.26 Å. In the fourteenth C site, C(18) is bonded in a water-like geometry to one C(19), one H(19), and one H(20) atom. The C(18)-C(19) bond length is 1.49 Å. The C(18)-H(19) bond length is 0.99 Å. The C(18)-H(20) bond length is 0.99 Å. In the fifteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one O(12), and one O(13) atom. The C(19)-O(12) bond length is 1.25 Å. The C(19)-O(13) bond length is 1.26 Å. In the sixteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one O(14) and one O(15) atom. The C(23)-O(14) bond length is 1.24 Å. The C(23)-O(15) bond length is 1.27 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(12), one C(8), and one C(9) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(11,12) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. There are nineteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Th(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Th(2) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Th(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Th(2) and one C(7) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Th(3) and one C(11) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Th(2) and one C(11) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(12) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Th(1) and one C(13) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Th(3) and one C(13) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Th(2) and one C(19) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Th(3) and one C(19) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Th(1) and one C(23) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Th(3) and one C(23) atom. In the sixteenth O site, O(19) is bonded in a trigonal non-coplanar geometry to one Th(1), one Th(2), and one Th(3) atom. In the seventeenth O site, O(20) is bonded in a trigonal non-coplanar geometry to one Th(1), one Th(2), and one Th(3) atom. In the eighteenth O site, O(21) is bonded in a trigonal non-coplanar geometry to one Th(1), one Th(2), and one Th(3) atom. In the nineteenth O site, O(22) is bonded in a trigonal non-coplanar geometry to one Th(1), one Th(2), and one Th(3) atom. Linkers: 16 [O]C(=O)CCn1c(=O)n(CCC([O])=O)c(=O)n(CCC([O])=O)c1=O. Metal clusters: 3 [O][C]=O.[O][C]=O.[O][Th]12(O[C]=O)O[C]O[Th]34(O[C]O[Th](O[C]=O)(O[C]O[Th]567O[C]O[Th]([O])(O[C]=O)(O5)O[Th](O[C]=O)(O[C]O3)(O[C]O6)O7)(O1)O4)O2 ,1 [O][C]=O.[O][C]O[Th]12([O])(O[C]=O)O[C]O[Th]34(O[C]O[Th]56(O[C]=O)O[C]O[Th]7(O[C]O[Th]([O])(O[C]=O)(O7)O5)(O[C]O[Th](O[C]=O)(O[C]O3)(O4)O1)O6)O2. RCSR code: bcu. The MOF has largest included sphere 5.19 A, density 2.07 g/cm3, surface area 2323.66 m2/g, accessible volume 0.23 cm3/g