(AgC20N3H14S)2AgC24H20(NS)2 is Indium-like structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of four AgC20N3H14S clusters and two AgC24H20(NS)2 clusters. In each AgC20N3H14S cluster, Ag(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(3), one N(4), and one S(2) atom. The Ag(1)-N(1) bond length is 2.28 Å. The Ag(1)-N(3) bond length is 2.29 Å. The Ag(1)-N(4) bond length is 2.38 Å. The Ag(1)-S(2) bond length is 2.49 Å. There are nineteen inequivalent C sites. In the first C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(21) atom. The C(27)-C(26) bond length is 1.39 Å. The C(27)-H(21) bond length is 0.95 Å. In the second C site, C(28) is bonded in a distorted single-bond geometry to one C(29) and one H(22) atom. The C(28)-C(29) bond length is 1.38 Å. The C(28)-H(22) bond length is 0.95 Å. In the third C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(32) atom. The C(29)-C(30) bond length is 1.38 Å. The C(29)-C(32) bond length is 1.44 Å. In the fourth C site, C(31) is bonded in a distorted single-bond geometry to one C(26) and one H(24) atom. The C(31)-C(26) bond length is 1.38 Å. The C(31)-H(24) bond length is 0.95 Å. In the fifth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(23) atom. The C(30)-H(23) bond length is 0.95 Å. In the sixth C site, C(32) is bonded in a distorted single-bond geometry to one C(29) and one N(4) atom. The C(32)-N(4) bond length is 1.13 Å. In the seventh C site, C(1) is bonded in a linear geometry to one C(2) and one N(1) atom. The C(1)-C(2) bond length is 1.44 Å. The C(1)-N(1) bond length is 1.13 Å. In the eighth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.38 Å. In the ninth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. In the tenth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.95 Å. In the eleventh C site, C(17) is bonded in a linear geometry to one C(18) and one N(3) atom. The C(17)-C(18) bond length is 1.44 Å. The C(17)-N(3) bond length is 1.13 Å. In the twelfth C site, C(18) is bonded in a trigonal planar geometry to one C(17) and two equivalent C(19,23) atoms. There is one shorter (1.38 Å) and one longer (1.39 Å) C(18)-C(19,23) bond length. In the thirteenth C site, C(19,23) is bonded in a distorted single-bond geometry to one C(18) and one H(13) atom. The C(19,23)-H(13) bond length is 0.95 Å. In the fourteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(14,15) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(14,15) bond length is 0.95 Å. In the fifteenth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-C(24) bond length is 1.50 Å. In the sixteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(14,15) atom. The C(22)-H(14,15) bond length is 0.95 Å. In the seventeenth C site, C(24) is bonded in a water-like geometry to one C(21); two equivalent H(17,18); and one S(2) atom. Both C(24)-H(17,18) bond lengths are 0.99 Å. The C(24)-S(2) bond length is 1.82 Å. In the eighteenth C site, C(25) is bonded in a water-like geometry to one C(26); two equivalent H(19,20); and one S(2) atom. The C(25)-C(26) bond length is 1.50 Å. Both C(25)-H(19,20) bond lengths are 0.99 Å. The C(25)-S(2) bond length is 1.82 Å. In the nineteenth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(31) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Ag(1) and one C(1) atom. In the second N site, N(3) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one C(17) atom. In the third N site, N(4) is bonded in a bent 150 degrees geometry to one Ag(1) and one C(32) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(19,23) atom. In the fourth H site, H(14,15) is bonded in a single-bond geometry to one C(20) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(19,23) atom. The H(16)-C(19,23) bond length is 0.95 Å. In the sixth H site, H(17,18) is bonded in a single-bond geometry to one C(24) atom. In the seventh H site, H(19,20) is bonded in a single-bond geometry to one C(25) atom. In the eighth H site, H(21) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(22) is bonded in a single-bond geometry to one C(28) atom. In the tenth H site, H(23) is bonded in a single-bond geometry to one C(30) atom. In the eleventh H site, H(24) is bonded in a single-bond geometry to one C(31) atom. S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(24), and one C(25) atom. In each AgC24H20(NS)2 cluster, Ag(2) is bonded in a distorted tetrahedral geometry to two equivalent N(2) and two equivalent S(1) atoms. Both Ag(2)-N(2) bond lengths are 2.32 Å. Both Ag(2)-S(1) bond lengths are 2.53 Å. There are twelve inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(2) bond length is 0.95 Å. In the second C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(8) bond length is 1.50 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 0.95 Å. In the fourth C site, C(8) is bonded in a water-like geometry to one C(5); two equivalent H(5,6); and one S(1) atom. Both C(8)-H(5,6) bond lengths are 0.99 Å. The C(8)-S(1) bond length is 1.81 Å. In the fifth C site, C(9) is bonded in a water-like geometry to one C(10); two equivalent H(7,8); and one S(1) atom. The C(9)-C(10) bond length is 1.50 Å. Both C(9)-H(7,8) bond lengths are 0.99 Å. The C(9)-S(1) bond length is 1.83 Å. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(15) bond length is 1.39 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(9,12) atom. The C(11)-H(9,12) bond length is 0.95 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10,11) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(10,11) bond length is 0.95 Å. In the ninth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-C(16) bond length is 1.44 Å. In the tenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(10,11) atom. The C(14)-H(10,11) bond length is 0.95 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one H(9,12) atom. The C(15)-H(9,12) bond length is 0.95 Å. In the twelfth C site, C(16) is bonded in a distorted linear geometry to one C(13) and one N(2) atom. The C(16)-N(2) bond length is 1.13 Å. N(2) is bonded in a linear geometry to one Ag(2) and one C(16) atom. There are six inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(9,12) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(10,11) is bonded in a single-bond geometry to one C(12) atom. S(1) is bonded in a trigonal non-coplanar geometry to one Ag(2), one C(8), and one C(9) atom. Linkers: 8 N#Cc1ccc(CSCc2ccc(C#N)cc2)cc1. Metal clusters: 6 [Ag]. The MOF has largest included sphere 4.93 A, density 1.10 g/cm3, surface area 4838.59 m2/g, accessible volume 0.46 cm3/g