Zn3H28(C8O3)5(CH)11(C5H5O)3 crystallizes in the trigonal R-3c space group. The structure is zero-dimensional and consists of three hundred and ninety-six 02329_fluka molecules, thirty-six schembl9685153 molecules, and thirty-six Zn3H28(C8O3)5 clusters. In each Zn3H28(C8O3)5 cluster, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(14), one O(16), one O(17), and one O(7) atom to form distorted corner-sharing ZnO4 trigonal pyramids. The corner-sharing octahedral tilt angles are 80°. The Zn(1)-O(14) bond length is 1.91 Å. The Zn(1)-O(16) bond length is 2.46 Å. The Zn(1)-O(17) bond length is 2.01 Å. The Zn(1)-O(7) bond length is 1.95 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(15), one O(16), one O(5), one O(6), and one O(9) atom to form corner-sharing ZnO6 octahedra. The Zn(2)-O(1) bond length is 2.27 Å. The Zn(2)-O(15) bond length is 2.03 Å. The Zn(2)-O(16) bond length is 2.06 Å. The Zn(2)-O(5) bond length is 2.09 Å. The Zn(2)-O(6) bond length is 2.07 Å. The Zn(2)-O(9) bond length is 2.06 Å. In the third Zn site, Zn(3) is bonded in a 4-coordinate geometry to one O(1), one O(10), one O(2), and one O(5) atom. The Zn(3)-O(1) bond length is 2.39 Å. The Zn(3)-O(10) bond length is 1.95 Å. The Zn(3)-O(2) bond length is 2.13 Å. The Zn(3)-O(5) bond length is 2.24 Å. There are forty inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.51 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one O(11) atom. The C(5)-O(11) bond length is 1.37 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(6), and one O(7) atom. The C(7)-O(6) bond length is 1.25 Å. The C(7)-O(7) bond length is 1.26 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(14), one C(63), and one C(9) atom. The C(8)-C(14) bond length is 1.52 Å. The C(8)-C(63) bond length is 1.39 Å. The C(8)-C(9) bond length is 1.41 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(16), and one C(8) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(16) bond length is 1.50 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-C(15) bond length is 1.51 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(17), and one C(22) atom. The C(11)-C(17) bond length is 1.40 Å. The C(11)-C(22) bond length is 1.51 Å. In the tenth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(63); two equivalent H(5,6); and one O(11) atom. The C(12)-C(63) bond length is 1.50 Å. Both C(12)-H(5,6) bond lengths are 0.97 Å. The C(12)-O(11) bond length is 1.44 Å. In the eleventh C site, C(13) is bonded in a trigonal non-coplanar geometry to one C(17); one H(9); and two equivalent H(7,8) atoms. The C(13)-C(17) bond length is 1.52 Å. The C(13)-H(9) bond length is 0.96 Å. Both C(13)-H(7,8) bond lengths are 0.96 Å. In the twelfth C site, C(14) is bonded in a trigonal non-coplanar geometry to one C(8), one H(10), one H(11), and one H(12) atom. The C(14)-H(10) bond length is 0.96 Å. The C(14)-H(11) bond length is 0.96 Å. The C(14)-H(12) bond length is 0.96 Å. In the thirteenth C site, C(15) is bonded in a trigonal non-coplanar geometry to one C(10), one H(13), one H(14), and one H(15) atom. The C(15)-H(13) bond length is 0.96 Å. The C(15)-H(14) bond length is 0.96 Å. The C(15)-H(15) bond length is 0.96 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(16), one H(17), and one O(12) atom. The C(16)-H(16) bond length is 0.97 Å. The C(16)-H(17) bond length is 0.97 Å. The C(16)-O(12) bond length is 1.45 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(63) atom. The C(17)-C(63) bond length is 1.39 Å. In the sixteenth C site, C(18) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(64) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-C(21) bond length is 1.48 Å. The C(18)-C(64) bond length is 1.38 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(37), and one H(18) atom. The C(19)-C(37) bond length is 1.38 Å. The C(19)-H(18) bond length is 0.93 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(37) and one H(19) atom. The C(20)-C(37) bond length is 1.39 Å. The C(20)-H(19) bond length is 0.93 Å. In the nineteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(16), and one O(17) atom. The C(21)-O(16) bond length is 1.22 Å. The C(21)-O(17) bond length is 1.26 Å. In the twentieth C site, C(22) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one H(20), one H(21), and one O(13) atom. The C(22)-H(20) bond length is 0.97 Å. The C(22)-H(21) bond length is 0.97 Å. The C(22)-O(13) bond length is 1.45 Å. In the twenty-first C site, C(23) is bonded in a distorted single-bond geometry to one O(13) atom. The C(23)-O(13) bond length is 1.37 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(22) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-H(22) bond length is 0.93 Å. In the twenty-third C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(29) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-C(29) bond length is 1.51 Å. In the twenty-fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(23) atom. The C(26)-H(23) bond length is 0.93 Å. In the twenty-fifth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(14), and one O(15) atom. The C(29)-O(14) bond length is 1.27 Å. The C(29)-O(15) bond length is 1.25 Å. In the twenty-sixth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(10), and one O(9) atom. The C(30)-C(31) bond length is 1.50 Å. The C(30)-O(10) bond length is 1.25 Å. The C(30)-O(9) bond length is 1.25 Å. In the twenty-seventh C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(36) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-C(36) bond length is 1.36 Å. In the twenty-eighth C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(26) atom. The C(32)-H(26) bond length is 0.93 Å. In the twenty-ninth C site, C(36) is bonded in a distorted single-bond geometry to one C(31) and one H(29) atom. The C(36)-H(29) bond length is 0.93 Å. In the thirtieth C site, C(37) is bonded in a distorted single-bond geometry to one C(19), one C(20), and one O(12) atom. The C(37)-O(12) bond length is 1.36 Å. In the thirty-first C site, C(50) is bonded in a distorted single-bond geometry to one C(51) and one H(43) atom. The C(50)-C(51) bond length is 1.37 Å. The C(50)-H(43) bond length is 0.93 Å. In the thirty-second C site, C(51) is bonded in a trigonal planar geometry to one C(50), one C(52), and one C(66) atom. The C(51)-C(52) bond length is 1.38 Å. The C(51)-C(66) bond length is 1.48 Å. In the thirty-third C site, C(52) is bonded in a distorted single-bond geometry to one C(51) and one H(44) atom. The C(52)-H(44) bond length is 0.93 Å. In the thirty-fourth C site, C(55) is bonded in a distorted single-bond geometry to one C(58) and one H(47) atom. The C(55)-C(58) bond length is 1.39 Å. The C(55)-H(47) bond length is 0.93 Å. In the thirty-fifth C site, C(56) is bonded in a distorted single-bond geometry to one C(58) and one H(48) atom. The C(56)-C(58) bond length is 1.34 Å. The C(56)-H(48) bond length is 0.93 Å. In the thirty-sixth C site, C(58) is bonded in a trigonal planar geometry to one C(55), one C(56), and one C(61) atom. The C(58)-C(61) bond length is 1.51 Å. In the thirty-seventh C site, C(61) is bonded in a distorted bent 120 degrees geometry to one C(58), one O(1), and one O(2) atom. The C(61)-O(1) bond length is 1.26 Å. The C(61)-O(2) bond length is 1.23 Å. In the thirty-eighth C site, C(63) is bonded in a trigonal planar geometry to one C(12), one C(17), and one C(8) atom. In the thirty-ninth C site, C(64) is bonded in a distorted single-bond geometry to one C(18) and one H(53) atom. The C(64)-H(53) bond length is 0.93 Å. In the fortieth C site, C(66) is bonded in a distorted bent 120 degrees geometry to one C(51), one O(18), and one O(5) atom. The C(66)-O(18) bond length is 1.22 Å. The C(66)-O(5) bond length is 1.20 Å. There are twenty-six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(22) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(22) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(24) atom. In the nineteenth H site, H(23) is bonded in a single-bond geometry to one C(26) atom. In the twentieth H site, H(26) is bonded in a single-bond geometry to one C(32) atom. In the twenty-first H site, H(29) is bonded in a single-bond geometry to one C(36) atom. In the twenty-second H site, H(43) is bonded in a single-bond geometry to one C(50) atom. In the twenty-third H site, H(44) is bonded in a single-bond geometry to one C(52) atom. In the twenty-fourth H site, H(47) is bonded in a single-bond geometry to one C(55) atom. In the twenty-fifth H site, H(48) is bonded in a single-bond geometry to one C(56) atom. In the twenty-sixth H site, H(53) is bonded in a single-bond geometry to one C(64) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Zn(2), one Zn(3), and one C(61) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Zn(3) and one C(61) atom. In the third O site, O(5) is bonded in a distorted T-shaped geometry to one Zn(2), one Zn(3), and one C(66) atom. In the fourth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(7) atom. In the fifth O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the sixth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(30) atom. In the seventh O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(30) atom. In the eighth O site, O(11) is bonded in a bent 120 degrees geometry to one C(12) and one C(5) atom. In the ninth O site, O(12) is bonded in a bent 120 degrees geometry to one C(16) and one C(37) atom. In the tenth O site, O(13) is bonded in a bent 120 degrees geometry to one C(22) and one C(23) atom. In the eleventh O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(29) atom. In the twelfth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(29) atom. In the thirteenth O site, O(16) is bonded in a 3-coordinate geometry to one Zn(1), one Zn(2), and one C(21) atom. In the fourteenth O site, O(17) is bonded in a water-like geometry to one Zn(1) and one C(21) atom. In the fifteenth O site, O(18) is bonded in a single-bond geometry to one C(66) atom. Linkers: 24 Cc1c(COc2cccc(C([O])=O)c2)c(C)c(COc2cccc(C([O])=O)c2)c(C)c1COc1cccc(C([O])=O)c1. Metal clusters: 12 O=[C]O[Zn]123(O[C]O[Zn]O[C]O1)O[C]O[Zn](O[C]O2)O[C]O3. The MOF has largest included sphere 12.53 A, density 1.01 g/cm3, surface area 4693.16 m2/g, accessible volume 0.48 cm3/g