Cu12C96H49(N24O23)2 crystallizes in the triclinic P1 space group. There are eleven inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to one N(4,8,15,17); one N(6,10,19); and two equivalent N(1,5,16,18,22,23) atoms. The Cu(1)-N(4,8,15,17) bond length is 1.95 Å. The Cu(1)-N(6,10,19) bond length is 1.95 Å. Both Cu(1)-N(1,5,16,18,22,23) bond lengths are 1.95 Å. In the second Cu site, Cu(2) is bonded in a square co-planar geometry to one N(2); one N(4,8,15,17); and two equivalent N(3,7,11,13,20) atoms. The Cu(2)-N(2) bond length is 1.95 Å. The Cu(2)-N(4,8,15,17) bond length is 1.95 Å. Both Cu(2)-N(3,7,11,13,20) bond lengths are 1.95 Å. In the third Cu site, Cu(3) is bonded in a square co-planar geometry to one N(1,5,16,18,22,23); one N(14); and two equivalent N(4,8,15,17) atoms. The Cu(3)-N(1,5,16,18,22,23) bond length is 1.95 Å. The Cu(3)-N(14) bond length is 1.95 Å. Both Cu(3)-N(4,8,15,17) bond lengths are 1.95 Å. In the fourth Cu site, Cu(4) is bonded in a square co-planar geometry to one N(1,5,16,18,22,23); one N(6,10,19); and two equivalent N(3,7,11,13,20) atoms. The Cu(4)-N(1,5,16,18,22,23) bond length is 1.95 Å. The Cu(4)-N(6,10,19) bond length is 1.95 Å. Both Cu(4)-N(3,7,11,13,20) bond lengths are 1.95 Å. In the fifth Cu site, Cu(5) is bonded in a square co-planar geometry to one N(12), one N(21), one N(24), and one N(9) atom. The Cu(5)-N(12) bond length is 1.95 Å. The Cu(5)-N(21) bond length is 1.95 Å. The Cu(5)-N(24) bond length is 1.95 Å. The Cu(5)-N(9) bond length is 1.95 Å. In the sixth Cu site, Cu(6) is bonded in a square co-planar geometry to one N(3,7,11,13,20); one N(6,10,19); and two equivalent N(1,5,16,18,22,23) atoms. The Cu(6)-N(3,7,11,13,20) bond length is 1.95 Å. The Cu(6)-N(6,10,19) bond length is 1.95 Å. Both Cu(6)-N(1,5,16,18,22,23) bond lengths are 1.95 Å. In the seventh Cu site, Cu(7,8) is bonded in a square co-planar geometry to one N(25,26,32,33,40,41); one N(28); one N(29,36,42,45); and one N(30,38,43,48) atom. The Cu(7,8)-N(25,26,32,33,40,41) bond length is 1.95 Å. The Cu(7,8)-N(28) bond length is 1.95 Å. The Cu(7,8)-N(29,36,42,45) bond length is 1.95 Å. The Cu(7,8)-N(30,38,43,48) bond length is 1.95 Å. In the eighth Cu site, Cu(9) is bonded in a square co-planar geometry to one N(25,26,32,33,40,41); one N(29,36,42,45); one N(30,38,43,48); and one N(39) atom. The Cu(9)-N(25,26,32,33,40,41) bond length is 1.95 Å. The Cu(9)-N(29,36,42,45) bond length is 1.95 Å. The Cu(9)-N(30,38,43,48) bond length is 1.95 Å. The Cu(9)-N(39) bond length is 1.95 Å. In the ninth Cu site, Cu(10) is bonded in a square co-planar geometry to one N(25,26,32,33,40,41); one N(27,31,44); one N(30,38,43,48); and one N(37) atom. The Cu(10)-N(25,26,32,33,40,41) bond length is 1.95 Å. The Cu(10)-N(27,31,44) bond length is 1.95 Å. The Cu(10)-N(30,38,43,48) bond length is 1.95 Å. The Cu(10)-N(37) bond length is 1.95 Å. In the tenth Cu site, Cu(11) is bonded in a square co-planar geometry to one N(25,26,32,33,40,41); one N(30,38,43,48); and two equivalent N(29,36,42,45) atoms. The Cu(11)-N(25,26,32,33,40,41) bond length is 1.95 Å. The Cu(11)-N(30,38,43,48) bond length is 1.95 Å. Both Cu(11)-N(29,36,42,45) bond lengths are 1.95 Å. In the eleventh Cu site, Cu(12) is bonded in a square co-planar geometry to one N(34), one N(35), one N(46), and one N(47) atom. The Cu(12)-N(34) bond length is 1.95 Å. The Cu(12)-N(35) bond length is 1.95 Å. The Cu(12)-N(46) bond length is 1.95 Å. The Cu(12)-N(47) bond length is 1.95 Å. There are thirty-three inequivalent C sites. In the first C site, C(1,4,5,8,9,15,16,17,18,22,23) is bonded in a distorted water-like geometry to one C(50,66,80,88,92,94); one N(1,5,16,18,22,23); and one O(1,5,9,15,17,21,22,27,29,33,37,42,46) atom. The C(1,4,5,8,9,15,16,17,18,22,23)-C(50,66,80,88,92,94) bond length is 1.42 Å. The C(1,4,5,8,9,15,16,17,18,22,23)-N(1,5,16,18,22,23) bond length is 1.27 Å. The C(1,4,5,8,9,15,16,17,18,22,23)-O(1,5,9,15,17,21,22,27,29,33,37,42,46) bond length is 1.33 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one C(52), one N(2), and one O(2) atom. The C(2)-C(52) bond length is 1.42 Å. The C(2)-N(2) bond length is 1.27 Å. The C(2)-O(2) bond length is 1.33 Å. In the third C site, C(3,6,7,11,13,19,20,21,24) is bonded in a distorted water-like geometry to one C(54,58,62,70,74,84); one N(3,7,11,13,20); and one O(3,7,11,12,13,19,24,25,31,32,39,40,45) atom. The C(3,6,7,11,13,19,20,21,24)-C(54,58,62,70,74,84) bond length is 1.42 Å. The C(3,6,7,11,13,19,20,21,24)-N(3,7,11,13,20) bond length is 1.27 Å. The C(3,6,7,11,13,19,20,21,24)-O(3,7,11,12,13,19,24,25,31,32,39,40,45) bond length is 1.33 Å. In the fourth C site, C(10) is bonded in a distorted water-like geometry to one C(68); one N(6,10,19); and one O(6,10,18,23,28,35,41,44) atom. The C(10)-C(68) bond length is 1.42 Å. The C(10)-N(6,10,19) bond length is 1.27 Å. The C(10)-O(6,10,18,23,28,35,41,44) bond length is 1.33 Å. In the fifth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(72), one N(12), and one H(1) atom. The C(12)-C(72) bond length is 1.42 Å. The C(12)-N(12) bond length is 1.27 Å. The C(12)-H(1) bond length is 1.14 Å. In the sixth C site, C(14) is bonded in a distorted water-like geometry to one C(76); one N(14); and one O(3,7,11,12,13,19,24,25,31,32,39,40,45) atom. The C(14)-C(76) bond length is 1.42 Å. The C(14)-N(14) bond length is 1.27 Å. The C(14)-O(3,7,11,12,13,19,24,25,31,32,39,40,45) bond length is 1.33 Å. In the seventh C site, C(25,26,29,32,33,36,40,41,42,45) is bonded in a distorted water-like geometry to one C(50,66,80,88,92,94); one N(25,26,32,33,40,41); and one O(3,7,11,12,13,19,24,25,31,32,39,40,45) atom. The C(25,26,29,32,33,36,40,41,42,45)-C(50,66,80,88,92,94) bond length is 1.42 Å. The C(25,26,29,32,33,36,40,41,42,45)-N(25,26,32,33,40,41) bond length is 1.27 Å. The C(25,26,29,32,33,36,40,41,42,45)-O(3,7,11,12,13,19,24,25,31,32,39,40,45) bond length is 1.33 Å. In the eighth C site, C(27,28,30,31,38,43,44,48) is bonded in a distorted water-like geometry to one C(56,60,82,86,96); one N(27,31,44); and one O(4,8,14,16,26,30,43) atom. The C(27,28,30,31,38,43,44,48)-C(56,60,82,86,96) bond length is 1.42 Å. The C(27,28,30,31,38,43,44,48)-N(27,31,44) bond length is 1.27 Å. The C(27,28,30,31,38,43,44,48)-O(4,8,14,16,26,30,43) bond length is 1.33 Å. In the ninth C site, C(34) is bonded in a distorted water-like geometry to one C(54,58,62,70,74,84); one N(34); and one O(1,5,9,15,17,21,22,27,29,33,37,42,46) atom. The C(34)-C(54,58,62,70,74,84) bond length is 1.42 Å. The C(34)-N(34) bond length is 1.27 Å. The C(34)-O(1,5,9,15,17,21,22,27,29,33,37,42,46) bond length is 1.33 Å. In the tenth C site, C(35) is bonded in a distorted water-like geometry to one C(76), one N(35), and one O(34) atom. The C(35)-C(76) bond length is 1.42 Å. The C(35)-N(35) bond length is 1.27 Å. The C(35)-O(34) bond length is 1.33 Å. In the eleventh C site, C(37) is bonded in a distorted water-like geometry to one C(68), one N(37), and one O(36) atom. The C(37)-C(68) bond length is 1.42 Å. The C(37)-N(37) bond length is 1.27 Å. The C(37)-O(36) bond length is 1.33 Å. In the twelfth C site, C(39) is bonded in a distorted water-like geometry to one C(72), one N(39), and one O(38) atom. The C(39)-C(72) bond length is 1.42 Å. The C(39)-N(39) bond length is 1.27 Å. The C(39)-O(38) bond length is 1.33 Å. In the thirteenth C site, C(46) is bonded in a distorted water-like geometry to one C(50,66,80,88,92,94); one N(46); and one O(3,7,11,12,13,19,24,25,31,32,39,40,45) atom. The C(46)-C(50,66,80,88,92,94) bond length is 1.42 Å. The C(46)-N(46) bond length is 1.27 Å. The C(46)-O(3,7,11,12,13,19,24,25,31,32,39,40,45) bond length is 1.33 Å. In the fourteenth C site, C(47) is bonded in a distorted single-bond geometry to one C(52) and one N(47) atom. The C(47)-C(52) bond length is 1.42 Å. The C(47)-N(47) bond length is 1.27 Å. In the fifteenth C site, C(49) is bonded in a trigonal planar geometry to one N(1,5,16,18,22,23); one N(46); and one H(2,6,8,10,12,14,16,18,20,22,26,30,32,34,36,38,40,44,46,48) atom. The C(49)-N(1,5,16,18,22,23) bond length is 1.38 Å. The C(49)-N(46) bond length is 1.38 Å. The C(49)-H(2,6,8,10,12,14,16,18,20,22,26,30,32,34,36,38,40,44,46,48) bond length is 1.14 Å. In the sixteenth C site, C(50,66,80,88,92,94) is bonded in a distorted trigonal planar geometry to one C(1,4,5,8,9,15,16,17,18,22,23); one C(46); and one H(3,7,9,11,13,15,17,19,23,27,29,31,33,35,37,39,41,43,45,47,49) atom. The C(50,66,80,88,92,94)-H(3,7,9,11,13,15,17,19,23,27,29,31,33,35,37,39,41,43,45,47,49) bond length is 1.14 Å. In the seventeenth C site, C(51) is bonded in a trigonal planar geometry to one N(2), one N(47), and one H(4) atom. The C(51)-N(2) bond length is 1.38 Å. The C(51)-N(47) bond length is 1.38 Å. The C(51)-H(4) bond length is 1.14 Å. In the eighteenth C site, C(52) is bonded in a distorted trigonal planar geometry to one C(2), one C(47), and one H(5) atom. The C(52)-H(5) bond length is 1.14 Å. In the nineteenth C site, C(53,69,89,91) is bonded in a trigonal planar geometry to one N(3,7,11,13,20); one N(30,38,43,48); and one H(2,6,8,10,12,14,16,18,20,22,26,30,32,34,36,38,40,44,46,48) atom. The C(53,69,89,91)-N(3,7,11,13,20) bond length is 1.38 Å. The C(53,69,89,91)-N(30,38,43,48) bond length is 1.38 Å. The C(53,69,89,91)-H(2,6,8,10,12,14,16,18,20,22,26,30,32,34,36,38,40,44,46,48) bond length is 1.14 Å. In the twentieth C site, C(54,58,62,70,74,84) is bonded in a distorted trigonal planar geometry to one C(27,28,30,31,38,43,44,48); one C(3,6,7,11,13,19,20,21,24); and one H(3,7,9,11,13,15,17,19,23,27,29,31,33,35,37,39,41,43,45,47,49) atom. The C(54,58,62,70,74,84)-C(27,28,30,31,38,43,44,48) bond length is 1.42 Å. The C(54,58,62,70,74,84)-H(3,7,9,11,13,15,17,19,23,27,29,31,33,35,37,39,41,43,45,47,49) bond length is 1.14 Å. In the twenty-first C site, C(55,59,65,79,81,83) is bonded in a trigonal planar geometry to one N(29,36,42,45); one N(4,8,15,17); and one H(2,6,8,10,12,14,16,18,20,22,26,30,32,34,36,38,40,44,46,48) atom. The C(55,59,65,79,81,83)-N(29,36,42,45) bond length is 1.38 Å. The C(55,59,65,79,81,83)-N(4,8,15,17) bond length is 1.38 Å. The C(55,59,65,79,81,83)-H(2,6,8,10,12,14,16,18,20,22,26,30,32,34,36,38,40,44,46,48) bond length is 1.14 Å. In the twenty-second C site, C(56,60,82,86,96) is bonded in a distorted trigonal planar geometry to one C(1,4,5,8,9,15,16,17,18,22,23); one C(25,26,29,32,33,36,40,41,42,45); and one H(3,7,9,11,13,15,17,19,23,27,29,31,33,35,37,39,41,43,45,47,49) atom. The C(56,60,82,86,96)-C(1,4,5,8,9,15,16,17,18,22,23) bond length is 1.42 Å. The C(56,60,82,86,96)-C(25,26,29,32,33,36,40,41,42,45) bond length is 1.42 Å. The C(56,60,82,86,96)-H(3,7,9,11,13,15,17,19,23,27,29,31,33,35,37,39,41,43,45,47,49) bond length is 1.14 Å. In the twenty-third C site, C(57,61,85) is bonded in a trigonal planar geometry to one N(1,5,16,18,22,23); one N(25,26,32,33,40,41); and one H(2,6,8,10,12,14,16,18,20,22,26,30,32,34,36,38,40,44,46,48) atom. The C(57,61,85)-N(1,5,16,18,22,23) bond length is 1.38 Å. The C(57,61,85)-N(25,26,32,33,40,41) bond length is 1.38 Å. The C(57,61,85)-H(2,6,8,10,12,14,16,18,20,22,26,30,32,34,36,38,40,44,46,48) bond length is 1.14 Å. In the twenty-fourth C site, C(63,77,87,93,95) is bonded in a trigonal planar geometry to one N(29,36,42,45); one N(4,8,15,17); and one H(2,6,8,10,12,14,16,18,20,22,26,30,32,34,36,38,40,44,46,48) atom. The C(63,77,87,93,95)-N(29,36,42,45) bond length is 1.38 Å. The C(63,77,87,93,95)-N(4,8,15,17) bond length is 1.38 Å. The C(63,77,87,93,95)-H(2,6,8,10,12,14,16,18,20,22,26,30,32,34,36,38,40,44,46,48) bond length is 1.14 Å. In the twenty-fifth C site, C(64,78) is bonded in a distorted trigonal planar geometry to one C(1,4,5,8,9,15,16,17,18,22,23); one C(25,26,29,32,33,36,40,41,42,45); and one H(3,7,9,11,13,15,17,19,23,27,29,31,33,35,37,39,41,43,45,47,49) atom. The C(64,78)-C(1,4,5,8,9,15,16,17,18,22,23) bond length is 1.42 Å. The C(64,78)-C(25,26,29,32,33,36,40,41,42,45) bond length is 1.42 Å. The C(64,78)-H(3,7,9,11,13,15,17,19,23,27,29,31,33,35,37,39,41,43,45,47,49) bond length is 1.14 Å. In the twenty-sixth C site, C(67) is bonded in a trigonal planar geometry to one N(37); one N(6,10,19); and one H(2,6,8,10,12,14,16,18,20,22,26,30,32,34,36,38,40,44,46,48) atom. The C(67)-N(37) bond length is 1.38 Å. The C(67)-N(6,10,19) bond length is 1.38 Å. The C(67)-H(2,6,8,10,12,14,16,18,20,22,26,30,32,34,36,38,40,44,46,48) bond length is 1.14 Å. In the twenty-seventh C site, C(68) is bonded in a distorted trigonal planar geometry to one C(10), one C(37), and one H(21) atom. The C(68)-H(21) bond length is 1.14 Å. In the twenty-eighth C site, C(71) is bonded in a trigonal planar geometry to one N(12), one N(39), and one H(24) atom. The C(71)-N(12) bond length is 1.38 Å. The C(71)-N(39) bond length is 1.38 Å. The C(71)-H(24) bond length is 1.14 Å. In the twenty-ninth C site, C(72) is bonded in a distorted trigonal planar geometry to one C(12), one C(39), and one H(25) atom. The C(72)-H(25) bond length is 1.14 Å. In the thirtieth C site, C(73) is bonded in a trigonal planar geometry to one N(3,7,11,13,20); one N(34); and one H(2,6,8,10,12,14,16,18,20,22,26,30,32,34,36,38,40,44,46,48) atom. The C(73)-N(3,7,11,13,20) bond length is 1.38 Å. The C(73)-N(34) bond length is 1.38 Å. The C(73)-H(2,6,8,10,12,14,16,18,20,22,26,30,32,34,36,38,40,44,46,48) bond length is 1.14 Å. In the thirty-first C site, C(75) is bonded in a trigonal planar geometry to one N(14), one N(35), and one H(28) atom. The C(75)-N(14) bond length is 1.38 Å. The C(75)-N(35) bond length is 1.38 Å. The C(75)-H(28) bond length is 1.14 Å. In the thirty-second C site, C(76) is bonded in a distorted trigonal planar geometry to one C(14); one C(35); and one H(3,7,9,11,13,15,17,19,23,27,29,31,33,35,37,39,41,43,45,47,49) atom. The C(76)-H(3,7,9,11,13,15,17,19,23,27,29,31,33,35,37,39,41,43,45,47,49) bond length is 1.14 Å. In the thirty-third C site, C(90) is bonded in a distorted trigonal planar geometry to one C(27,28,30,31,38,43,44,48); one C(3,6,7,11,13,19,20,21,24); and one H(3,7,9,11,13,15,17,19,23,27,29,31,33,35,37,39,41,43,45,47,49) atom. The C(90)-C(27,28,30,31,38,43,44,48) bond length is 1.42 Å. The C(90)-C(3,6,7,11,13,19,20,21,24) bond length is 1.42 Å. The C(90)-H(3,7,9,11,13,15,17,19,23,27,29,31,33,35,37,39,41,43,45,47,49) bond length is 1.14 Å. There are twenty-one inequivalent N sites. In the first N site, N(1,5,16,18,22,23) is bonded in a trigonal planar geometry to one Cu(1); one C(1,4,5,8,9,15,16,17,18,22,23); and one C(49) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(2), and one C(51) atom. In the third N site, N(3,7,11,13,20) is bonded in a trigonal planar geometry to one Cu(2); one C(3,6,7,11,13,19,20,21,24); and one C(53,69,89,91) atom. In the fourth N site, N(4,8,15,17) is bonded in a trigonal planar geometry to one Cu(1); one C(1,4,5,8,9,15,16,17,18,22,23); and one C(55,59,65,79,81,83) atom. The N(4,8,15,17)-C(1,4,5,8,9,15,16,17,18,22,23) bond length is 1.27 Å. In the fifth N site, N(6,10,19) is bonded in a trigonal planar geometry to one Cu(4); one C(3,6,7,11,13,19,20,21,24); and one C(55,59,65,79,81,83) atom. The N(6,10,19)-C(3,6,7,11,13,19,20,21,24) bond length is 1.27 Å. The N(6,10,19)-C(55,59,65,79,81,83) bond length is 1.38 Å. In the sixth N site, N(9) is bonded in a trigonal planar geometry to one Cu(5); one C(1,4,5,8,9,15,16,17,18,22,23); and one C(55,59,65,79,81,83) atom. The N(9)-C(1,4,5,8,9,15,16,17,18,22,23) bond length is 1.27 Å. The N(9)-C(55,59,65,79,81,83) bond length is 1.38 Å. In the seventh N site, N(12) is bonded in a trigonal planar geometry to one Cu(5), one C(12), and one C(71) atom. In the eighth N site, N(14) is bonded in a trigonal planar geometry to one Cu(3), one C(14), and one C(75) atom. In the ninth N site, N(21) is bonded in a trigonal planar geometry to one Cu(5); one C(3,6,7,11,13,19,20,21,24); and one C(53,69,89,91) atom. The N(21)-C(3,6,7,11,13,19,20,21,24) bond length is 1.27 Å. The N(21)-C(53,69,89,91) bond length is 1.38 Å. In the tenth N site, N(24) is bonded in a trigonal planar geometry to one Cu(5); one C(3,6,7,11,13,19,20,21,24); and one C(63,77,87,93,95) atom. The N(24)-C(3,6,7,11,13,19,20,21,24) bond length is 1.27 Å. The N(24)-C(63,77,87,93,95) bond length is 1.38 Å. In the eleventh N site, N(25,26,32,33,40,41) is bonded in a trigonal planar geometry to one Cu(7,8); one C(25,26,29,32,33,36,40,41,42,45); and one C(53,69,89,91) atom. The N(25,26,32,33,40,41)-C(53,69,89,91) bond length is 1.38 Å. In the twelfth N site, N(27,31,44) is bonded in a trigonal planar geometry to one Cu(7,8); one C(27,28,30,31,38,43,44,48); and one C(63,77,87,93,95) atom. The N(27,31,44)-Cu(7,8) bond length is 1.95 Å. The N(27,31,44)-C(63,77,87,93,95) bond length is 1.38 Å. In the thirteenth N site, N(28) is bonded in a trigonal planar geometry to one Cu(7,8); one C(27,28,30,31,38,43,44,48); and one C(53,69,89,91) atom. The N(28)-C(27,28,30,31,38,43,44,48) bond length is 1.27 Å. The N(28)-C(53,69,89,91) bond length is 1.38 Å. In the fourteenth N site, N(29,36,42,45) is bonded in a trigonal planar geometry to one Cu(9); one C(25,26,29,32,33,36,40,41,42,45); and one C(55,59,65,79,81,83) atom. The N(29,36,42,45)-C(25,26,29,32,33,36,40,41,42,45) bond length is 1.27 Å. In the fifteenth N site, N(30,38,43,48) is bonded in a trigonal planar geometry to one Cu(10); one C(27,28,30,31,38,43,44,48); and one C(63,77,87,93,95) atom. The N(30,38,43,48)-C(27,28,30,31,38,43,44,48) bond length is 1.27 Å. The N(30,38,43,48)-C(63,77,87,93,95) bond length is 1.38 Å. In the sixteenth N site, N(34) is bonded in a trigonal planar geometry to one Cu(12), one C(34), and one C(73) atom. In the seventeenth N site, N(35) is bonded in a trigonal planar geometry to one Cu(12), one C(35), and one C(75) atom. In the eighteenth N site, N(37) is bonded in a trigonal planar geometry to one Cu(10), one C(37), and one C(67) atom. In the nineteenth N site, N(39) is bonded in a trigonal planar geometry to one Cu(9), one C(39), and one C(71) atom. In the twentieth N site, N(46) is bonded in a trigonal planar geometry to one Cu(12), one C(46), and one C(49) atom. In the twenty-first N site, N(47) is bonded in a trigonal planar geometry to one Cu(12), one C(47), and one C(51) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(2,6,8,10,12,14,16,18,20,22,26,30,32,34,36,38,40,44,46,48) is bonded in a single-bond geometry to one C(49) atom. In the third H site, H(3,7,9,11,13,15,17,19,23,27,29,31,33,35,37,39,41,43,45,47,49) is bonded in a single-bond geometry to one C(50,66,80,88,92,94) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(51) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(52) atom. In the sixth H site, H(21) is bonded in a single-bond geometry to one C(68) atom. In the seventh H site, H(24) is bonded in a single-bond geometry to one C(71) atom. In the eighth H site, H(25) is bonded in a single-bond geometry to one C(72) atom. In the ninth H site, H(28) is bonded in a single-bond geometry to one C(75) atom. In the tenth H site, H(42) is bonded in a single-bond geometry to one C(53,69,89,91) atom. The H(42)-C(53,69,89,91) bond length is 1.14 Å. There are nine inequivalent O sites. In the first O site, O(1,5,9,15,17,21,22,27,29,33,37,42,46) is bonded in a single-bond geometry to one C(1,4,5,8,9,15,16,17,18,22,23) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3,7,11,12,13,19,24,25,31,32,39,40,45) is bonded in a single-bond geometry to one C(3,6,7,11,13,19,20,21,24) atom. In the fourth O site, O(4,8,14,16,26,30,43) is bonded in a single-bond geometry to one C(1,4,5,8,9,15,16,17,18,22,23) atom. The O(4,8,14,16,26,30,43)-C(1,4,5,8,9,15,16,17,18,22,23) bond length is 1.33 Å. In the fifth O site, O(6,10,18,23,28,35,41,44) is bonded in a single-bond geometry to one C(3,6,7,11,13,19,20,21,24) atom. The O(6,10,18,23,28,35,41,44)-C(3,6,7,11,13,19,20,21,24) bond length is 1.33 Å. In the sixth O site, O(20) is bonded in a single-bond geometry to one C(3,6,7,11,13,19,20,21,24) atom. The O(20)-C(3,6,7,11,13,19,20,21,24) bond length is 1.33 Å. In the seventh O site, O(34) is bonded in a single-bond geometry to one C(35) atom. In the eighth O site, O(36) is bonded in a single-bond geometry to one C(37) atom. In the ninth O site, O(38) is bonded in a single-bond geometry to one C(39) atom. Linkers: 22 O=C1[CH]C(=O)N=C[N]1 ,1 O=C1[CH][C]N=C[N]1 ,1 O=C1[CH][CH]N=C[N]1. Metal clusters: 12 [Cu]. The MOF has largest included sphere 6.17 A, density 1.43 g/cm3, surface area 3910.19 m2/g, accessible volume 0.36 cm3/g