Zn4C24H6S6O13 crystallizes in the triclinic P-1 space group. Zn(1,2,3,4) is bonded to one O(1); one O(2,3,4,5); and two equivalent O(7,9,10,11,12,13) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(1,2,3,4)-O(1) bond length is 1.94 Å. The Zn(1,2,3,4)-O(2,3,4,5) bond length is 1.94 Å. Both Zn(1,2,3,4)-O(7,9,10,11,12,13) bond lengths are 1.94 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(20); one C(8,10); and one H(1,2) atom. The C(1)-C(20) bond length is 1.43 Å. The C(1)-C(8,10) bond length is 1.37 Å. The C(1)-H(1,2) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(19); one C(8,10); and one H(1,2) atom. The C(2)-C(19) bond length is 1.43 Å. The C(2)-C(8,10) bond length is 1.37 Å. The C(2)-H(1,2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(12), one C(21), and one H(3) atom. The C(3)-C(12) bond length is 1.37 Å. The C(3)-C(21) bond length is 1.43 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4,5,6) is bonded in a distorted single-bond geometry to one C(14,16,18); one C(22,23,24); and one H(4,5,6) atom. The C(4,5,6)-C(14,16,18) bond length is 1.37 Å. The C(4,5,6)-C(22,23,24) bond length is 1.43 Å. The C(4,5,6)-H(4,5,6) bond length is 0.93 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8,10) and two equivalent O(2,3,4,5) atoms. The C(7)-C(8,10) bond length is 1.49 Å. Both C(7)-O(2,3,4,5) bond lengths are 1.28 Å. In the sixth C site, C(8,10) is bonded in a distorted trigonal planar geometry to one C(2), one C(7), and one S(1) atom. The C(8,10)-S(1) bond length is 1.37 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8,10) and two equivalent O(2,3,4,5) atoms. The C(9)-C(8,10) bond length is 1.49 Å. Both C(9)-O(2,3,4,5) bond lengths are 1.28 Å. In the eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12) and two equivalent O(6,8) atoms. The C(11)-C(12) bond length is 1.49 Å. Both C(11)-O(6,8) bond lengths are 1.28 Å. In the ninth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(3), and one S(3) atom. The C(12)-S(3) bond length is 1.37 Å. In the tenth C site, C(13,15,17) is bonded in a distorted bent 120 degrees geometry to one C(14,16,18) and two equivalent O(7,9,10,11,12,13) atoms. The C(13,15,17)-C(14,16,18) bond length is 1.49 Å. Both C(13,15,17)-O(7,9,10,11,12,13) bond lengths are 1.28 Å. In the eleventh C site, C(14,16,18) is bonded in a distorted trigonal planar geometry to one C(13,15,17); one C(4,5,6); and one S(4,5,6) atom. The C(14,16,18)-S(4,5,6) bond length is 1.37 Å. In the twelfth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one C(19), one C(2), and one S(1) atom. The C(19)-C(19) bond length is 1.37 Å. The C(19)-S(1) bond length is 1.43 Å. In the thirteenth C site, C(20) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one C(20), and one S(2) atom. The C(20)-C(20) bond length is 1.37 Å. The C(20)-S(2) bond length is 1.43 Å. In the fourteenth C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one C(21), one C(3), and one S(3) atom. The C(21)-C(21) bond length is 1.37 Å. The C(21)-S(3) bond length is 1.43 Å. In the fifteenth C site, C(22,23,24) is bonded in a distorted trigonal non-coplanar geometry to one C(22,23,24); one C(4,5,6); and one S(4,5,6) atom. The C(22,23,24)-C(22,23,24) bond length is 1.37 Å. The C(22,23,24)-S(4,5,6) bond length is 1.43 Å. There are three inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4,5,6) is bonded in a single-bond geometry to one C(4,5,6) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a bent 120 degrees geometry to one C(19) and one C(8,10) atom. In the second S site, S(2) is bonded in a bent 120 degrees geometry to one C(20) and one C(8,10) atom. The S(2)-C(8,10) bond length is 1.37 Å. In the third S site, S(3) is bonded in a bent 120 degrees geometry to one C(12) and one C(21) atom. In the fourth S site, S(4,5,6) is bonded in a bent 120 degrees geometry to one C(14,16,18) and one C(22,23,24) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a tetrahedral geometry to four equivalent Zn(1,2,3,4) atoms. In the second O site, O(2,3,4,5) is bonded in a bent 120 degrees geometry to one Zn(1,2,3,4) and one C(7) atom. In the third O site, O(6,8) is bonded in a bent 120 degrees geometry to one Zn(1,2,3,4) and one C(11) atom. The O(6,8)-Zn(1,2,3,4) bond length is 1.94 Å. In the fourth O site, O(7,9,10,11,12,13) is bonded in a bent 120 degrees geometry to one Zn(1,2,3,4) and one C(13,15,17) atom. Linkers: 6 [O]C(=O)c1cc2sc(C([O])=O)cc2s1. Metal clusters: 2 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: pcu. The MOF has largest included sphere 17.30 A, density 0.51 g/cm3, surface area 3470.92 m2/g, accessible volume 1.68 cm3/g