Cu3C24N2H13O15(CH)3(C3N2H2O)2 is Indium-derived structured and crystallizes in the tetragonal I4/m space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules; thirty-two 1,3-dimethylurea molecules; and two Cu3C24N2H13O15 clusters. In each Cu3C24N2H13O15 cluster, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square pyramidal geometry to one O(1), one O(12), one O(15), one O(3), and one O(4) atom. The Cu(1)-O(1) bond length is 1.95 Å. The Cu(1)-O(12) bond length is 1.98 Å. The Cu(1)-O(15) bond length is 2.21 Å. The Cu(1)-O(3) bond length is 1.98 Å. The Cu(1)-O(4) bond length is 1.97 Å. In the second Cu site, Cu(2) is bonded in a square pyramidal geometry to one O(17), one O(6), one O(7), one O(8), and one O(9) atom. The Cu(2)-O(17) bond length is 2.20 Å. The Cu(2)-O(6) bond length is 1.97 Å. The Cu(2)-O(7) bond length is 1.96 Å. The Cu(2)-O(8) bond length is 1.98 Å. The Cu(2)-O(9) bond length is 1.98 Å. In the third Cu site, Cu(3) is bonded in a distorted square co-planar geometry to two equivalent O(10) and two equivalent O(11) atoms. Both Cu(3)-O(10) bond lengths are 1.97 Å. Both Cu(3)-O(11) bond lengths are 1.93 Å. In the fourth Cu site, Cu(4) is bonded in a distorted square co-planar geometry to two equivalent O(13) and two equivalent O(5) atoms. Both Cu(4)-O(13) bond lengths are 1.97 Å. Both Cu(4)-O(5) bond lengths are 1.96 Å. There are twenty-four inequivalent C sites. In the first C site, C(18) is bonded in a trigonal planar geometry to one C(12), one C(24), and one C(25) atom. The C(18)-C(12) bond length is 1.52 Å. The C(18)-C(24) bond length is 1.38 Å. The C(18)-C(25) bond length is 1.37 Å. In the second C site, C(19) is bonded in a trigonal planar geometry to one C(14), one C(21), and one C(23) atom. The C(19)-C(14) bond length is 1.49 Å. The C(19)-C(21) bond length is 1.40 Å. The C(19)-C(23) bond length is 1.40 Å. In the third C site, C(20) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(20)-C(8) bond length is 1.36 Å. The C(20)-H(6) bond length is 0.93 Å. In the fourth C site, C(21) is bonded in a distorted single-bond geometry to one C(15), one C(19), and one H(9) atom. The C(21)-C(15) bond length is 1.43 Å. The C(21)-H(9) bond length is 0.93 Å. In the fifth C site, C(23) is bonded in a distorted single-bond geometry to one C(19), one C(33), and one H(11) atom. The C(23)-C(33) bond length is 1.32 Å. The C(23)-H(11) bond length is 0.93 Å. In the sixth C site, C(24) is bonded in a distorted single-bond geometry to one C(18), one C(8), and one H(12) atom. The C(24)-C(8) bond length is 1.42 Å. The C(24)-H(12) bond length is 0.93 Å. In the seventh C site, C(25) is bonded in a distorted single-bond geometry to one C(18) and one H(14) atom. The C(25)-H(14) bond length is 0.93 Å. In the eighth C site, C(17) is bonded in a trigonal planar geometry to one C(11), one C(22), and one C(26) atom. The C(17)-C(11) bond length is 1.55 Å. The C(17)-C(22) bond length is 1.40 Å. The C(17)-C(26) bond length is 1.35 Å. In the ninth C site, C(22) is bonded in a distorted single-bond geometry to one C(17) and one H(10) atom. The C(22)-H(10) bond length is 0.93 Å. In the tenth C site, C(26) is bonded in a distorted single-bond geometry to one C(17), one C(7), and one H(15) atom. The C(26)-C(7) bond length is 1.38 Å. The C(26)-H(15) bond length is 0.93 Å. In the eleventh C site, C(29) is bonded in a distorted single-bond geometry to one C(15), one C(33), and one H(18) atom. The C(29)-C(15) bond length is 1.34 Å. The C(29)-C(33) bond length is 1.40 Å. The C(29)-H(18) bond length is 0.93 Å. In the twelfth C site, C(30) is bonded in a distorted single-bond geometry to one C(7) and one H(19) atom. The C(30)-C(7) bond length is 1.47 Å. The C(30)-H(19) bond length is 0.93 Å. In the thirteenth C site, C(32) is bonded in a distorted trigonal planar geometry to one N(4), one N(6), and one O(14) atom. The C(32)-N(4) bond length is 1.39 Å. The C(32)-N(6) bond length is 1.38 Å. The C(32)-O(14) bond length is 1.25 Å. In the fourteenth C site, C(33) is bonded in a trigonal planar geometry to one C(23), one C(29), and one N(4) atom. The C(33)-N(4) bond length is 1.41 Å. In the fifteenth C site, C(3) is bonded in a single-bond geometry to one N(6) atom. The C(3)-N(6) bond length is 1.47 Å. In the sixteenth C site, C(7) is bonded in a trigonal planar geometry to one C(13), one C(26), and one C(30) atom. The C(7)-C(13) bond length is 1.54 Å. In the seventeenth C site, C(8) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(24) atom. The C(8)-C(16) bond length is 1.51 Å. In the eighteenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(3), and one O(7) atom. The C(10)-C(15) bond length is 1.55 Å. The C(10)-O(3) bond length is 1.19 Å. The C(10)-O(7) bond length is 1.25 Å. In the nineteenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(4), and one O(6) atom. The C(11)-O(4) bond length is 1.26 Å. The C(11)-O(6) bond length is 1.22 Å. In the twentieth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(1), and one O(9) atom. The C(12)-O(1) bond length is 1.23 Å. The C(12)-O(9) bond length is 1.28 Å. In the twenty-first C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(12), and one O(8) atom. The C(13)-O(12) bond length is 1.27 Å. The C(13)-O(8) bond length is 1.21 Å. In the twenty-second C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(11), and one O(5) atom. The C(14)-O(11) bond length is 1.29 Å. The C(14)-O(5) bond length is 1.21 Å. In the twenty-third C site, C(15) is bonded in a trigonal planar geometry to one C(10), one C(21), and one C(29) atom. In the twenty-fourth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(10), and one O(13) atom. The C(16)-O(10) bond length is 1.23 Å. The C(16)-O(13) bond length is 1.20 Å. There are two inequivalent N sites. In the first N site, N(6) is bonded in a trigonal planar geometry to one C(3), one C(32), and one H(20) atom. The N(6)-H(20) bond length is 0.86 Å. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(32), one C(33), and one H(13) atom. The N(4)-H(13) bond length is 0.86 Å. There are thirteen inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(20) atom. In the second H site, H(7) is bonded in a single-bond geometry to one O(15) atom. The H(7)-O(15) bond length is 0.82 Å. In the third H site, H(9) is bonded in a single-bond geometry to one C(21) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(22) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(24) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one O(17) atom. The H(17)-O(17) bond length is 0.82 Å. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(30) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one N(6) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(12) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(10) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(11) atom. In the fourth O site, O(5) is bonded in a distorted single-bond geometry to one Cu(4) and one C(14) atom. In the fifth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(11) atom. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(10) atom. In the seventh O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(13) atom. In the eighth O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(12) atom. In the ninth O site, O(10) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(16) atom. In the tenth O site, O(11) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(14) atom. In the eleventh O site, O(12) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(13) atom. In the twelfth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one C(16) atom. In the thirteenth O site, O(14) is bonded in a single-bond geometry to one C(32) atom. In the fourteenth O site, O(15) is bonded in a water-like geometry to one Cu(1) and one H(7) atom. In the fifteenth O site, O(17) is bonded in a water-like geometry to one Cu(2) and one H(17) atom. Linkers: 16 [O]C(=O)c1cc(NC(=O)Nc2cc(NC(=O)Nc3cc(C([O])=O)cc(C([O])=O)c3)cc(NC(=O)Nc3cc(C([O])=O)cc(C([O])=O)c3)c2)cc(C([O])=O)c1. Metal clusters: 16 O[Cu]1234O[C]O[Cu]1(O)(O[C]O2)(O[C]O3)O[C]O4 ,8 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 19.48 A, density 0.59 g/cm3, surface area 3995.64 m2/g, accessible volume 1.26 cm3/g