LaC3(NO4)3(CH3)3(CH2)6(C4NH6)3 is Indium-derived structured and crystallizes in the tetragonal P4_12_12 space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules, twenty-four 02329_fluka molecules, twenty-four methyl(propan-2-ylidene)azanium molecules, and eight LaC3(NO4)3 clusters. In each LaC3(NO4)3 cluster, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. The La(1)-O(1) bond length is 2.50 Å. The La(1)-O(2) bond length is 2.49 Å. The La(1)-O(3) bond length is 2.68 Å. The La(1)-O(4) bond length is 2.68 Å. The La(1)-O(5) bond length is 2.64 Å. The La(1)-O(6) bond length is 2.61 Å. The La(1)-O(7) bond length is 2.65 Å. The La(1)-O(8) bond length is 2.64 Å. The La(1)-O(9) bond length is 2.53 Å. There are three inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one O(1) atom. The C(2)-O(1) bond length is 1.26 Å. In the second C site, C(12) is bonded in a distorted single-bond geometry to one O(2) atom. The C(12)-O(2) bond length is 1.28 Å. In the third C site, C(20) is bonded in a distorted single-bond geometry to one O(9) atom. The C(20)-O(9) bond length is 1.27 Å. There are three inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one O(10), one O(3), and one O(4) atom. The N(3)-O(10) bond length is 1.23 Å. The N(3)-O(3) bond length is 1.26 Å. The N(3)-O(4) bond length is 1.26 Å. In the second N site, N(4) is bonded in a trigonal planar geometry to one O(11), one O(5), and one O(6) atom. The N(4)-O(11) bond length is 1.21 Å. The N(4)-O(5) bond length is 1.25 Å. The N(4)-O(6) bond length is 1.28 Å. In the third N site, N(5) is bonded in a trigonal planar geometry to one O(12), one O(7), and one O(8) atom. The N(5)-O(12) bond length is 1.22 Å. The N(5)-O(7) bond length is 1.28 Å. The N(5)-O(8) bond length is 1.24 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one La(1) and one C(2) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one La(1) and one C(12) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one La(1) and one N(3) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one La(1) and one N(3) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one La(1) and one N(4) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one La(1) and one N(4) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one La(1) and one N(5) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one La(1) and one N(5) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one La(1) and one C(20) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one N(3) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one N(4) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one N(5) atom. Linkers: 12 C/C(=[NH]\[C@H]1CCCC[C@@H]1/[NH]=C(/[CH]C(=O)C)\C)/[CH]C(=O)C. Metal clusters: 8 [La]. RCSR code: srs. The MOF has largest included sphere 4.32 A, density 1.26 g/cm3, surface area 4849.39 m2/g, accessible volume 0.28 cm3/g