ZnC16N2H10O3(CH)2 crystallizes in the triclinic P1 space group. The structure consists of eight 02329_fluka molecules inside a ZnC16N2H10O3 framework. In the ZnC16N2H10O3 framework, there are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(1), one O(1), one O(11), and one O(4) atom to form corner-sharing ZnNO3 tetrahedra. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 1.91 Å. The Zn(1)-O(11) bond length is 1.97 Å. The Zn(1)-O(4) bond length is 1.95 Å. In the second Zn site, Zn(2) is bonded to one N(3), one O(1), one O(4), and one O(8) atom to form corner-sharing ZnNO3 tetrahedra. The Zn(2)-N(3) bond length is 2.03 Å. The Zn(2)-O(1) bond length is 1.95 Å. The Zn(2)-O(4) bond length is 1.91 Å. The Zn(2)-O(8) bond length is 1.97 Å. In the third Zn site, Zn(3) is bonded to one N(5), one O(10), one O(2), and one O(7) atom to form corner-sharing ZnNO3 tetrahedra. The Zn(3)-N(5) bond length is 2.03 Å. The Zn(3)-O(10) bond length is 1.95 Å. The Zn(3)-O(2) bond length is 1.97 Å. The Zn(3)-O(7) bond length is 1.91 Å. In the fourth Zn site, Zn(4) is bonded to one N(7), one O(10), one O(5), and one O(7) atom to form corner-sharing ZnNO3 tetrahedra. The Zn(4)-N(7) bond length is 2.03 Å. The Zn(4)-O(10) bond length is 1.91 Å. The Zn(4)-O(5) bond length is 1.97 Å. The Zn(4)-O(7) bond length is 1.95 Å. There are forty-six inequivalent C sites. In the first C site, C(1,19,37,55) is bonded in a distorted trigonal planar geometry to one C(16,34,52,70); one C(17,35,53,71); and one N(2) atom. The C(1,19,37,55)-C(16,34,52,70) bond length is 1.40 Å. The C(1,19,37,55)-C(17,35,53,71) bond length is 1.38 Å. The C(1,19,37,55)-N(2) bond length is 1.43 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(4); one C(5,23); and one H(1,12,23,34) atom. The C(2)-C(4) bond length is 1.37 Å. The C(2)-C(5,23) bond length is 1.41 Å. The C(2)-H(1,12,23,34) bond length is 0.95 Å. In the third C site, C(3) is bonded in a bent 120 degrees geometry to one C(11), one O(2), and one O(3) atom. The C(3)-C(11) bond length is 1.50 Å. The C(3)-O(2) bond length is 1.27 Å. The C(3)-O(3) bond length is 1.24 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2), one C(8), and one N(2) atom. The C(4)-C(8) bond length is 1.42 Å. The C(4)-N(2) bond length is 1.40 Å. In the fifth C site, C(5,23) is bonded in a trigonal planar geometry to one C(2); one C(6,24,42,60); and one C(9) atom. The C(5,23)-C(6,24,42,60) bond length is 1.43 Å. The C(5,23)-C(9) bond length is 1.44 Å. In the sixth C site, C(6,24,42,60) is bonded in a distorted single-bond geometry to one C(5,23) and one H(2,13,24,35) atom. The C(6,24,42,60)-H(2,13,24,35) bond length is 0.95 Å. In the seventh C site, C(7,25) is bonded in a distorted single-bond geometry to one C(9) and one H(3,14,25,36) atom. The C(7,25)-C(9) bond length is 1.42 Å. The C(7,25)-H(3,14,25,36) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(15), one C(4), and one N(1) atom. The C(8)-C(15) bond length is 1.37 Å. The C(8)-N(1) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(15); one C(5,23); and one C(7,25) atom. The C(9)-C(15) bond length is 1.41 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(4,15,26,37) atom. The C(10)-C(11) bond length is 1.37 Å. The C(10)-H(4,15,26,37) bond length is 0.95 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(3) atom. The C(11)-C(12) bond length is 1.40 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11); one C(17,35,53,71); and one H(5,16,27,38) atom. The C(12)-C(17,35,53,71) bond length is 1.39 Å. The C(12)-H(5,16,27,38) bond length is 0.95 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(6) atom. The C(13)-N(1) bond length is 1.31 Å. The C(13)-N(2) bond length is 1.37 Å. The C(13)-H(6) bond length is 0.95 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(8), one C(9), and one H(8) atom. The C(15)-H(8) bond length is 0.95 Å. In the fifteenth C site, C(16,34,52,70) is bonded in a single-bond geometry to one C(1,19,37,55) and one H(9,20,31,42) atom. The C(16,34,52,70)-H(9,20,31,42) bond length is 0.95 Å. In the sixteenth C site, C(17,35,53,71) is bonded in a distorted single-bond geometry to one C(1,19,37,55); one C(12); and one H(10,21,32,43) atom. The C(17,35,53,71)-H(10,21,32,43) bond length is 0.95 Å. In the seventeenth C site, C(20) is bonded in a distorted single-bond geometry to one C(22); one C(5,23); and one H(1,12,23,34) atom. The C(20)-C(22) bond length is 1.37 Å. The C(20)-C(5,23) bond length is 1.41 Å. The C(20)-H(1,12,23,34) bond length is 0.95 Å. In the eighteenth C site, C(21) is bonded in a bent 120 degrees geometry to one C(29), one O(5), and one O(6) atom. The C(21)-C(29) bond length is 1.50 Å. The C(21)-O(5) bond length is 1.27 Å. The C(21)-O(6) bond length is 1.24 Å. In the nineteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(20), one C(26), and one N(4) atom. The C(22)-C(26) bond length is 1.42 Å. The C(22)-N(4) bond length is 1.40 Å. In the twentieth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(22), one C(33), and one N(3) atom. The C(26)-C(33) bond length is 1.37 Å. The C(26)-N(3) bond length is 1.40 Å. In the twenty-first C site, C(27) is bonded in a trigonal planar geometry to one C(33); one C(5,23); and one C(7,25) atom. The C(27)-C(33) bond length is 1.41 Å. The C(27)-C(5,23) bond length is 1.44 Å. The C(27)-C(7,25) bond length is 1.42 Å. In the twenty-second C site, C(28) is bonded in a distorted single-bond geometry to one C(29) and one H(4,15,26,37) atom. The C(28)-C(29) bond length is 1.37 Å. The C(28)-H(4,15,26,37) bond length is 0.95 Å. In the twenty-third C site, C(29) is bonded in a trigonal planar geometry to one C(21), one C(28), and one C(30) atom. The C(29)-C(30) bond length is 1.40 Å. In the twenty-fourth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(17,35,53,71); one C(29); and one H(5,16,27,38) atom. The C(30)-C(17,35,53,71) bond length is 1.39 Å. The C(30)-H(5,16,27,38) bond length is 0.95 Å. In the twenty-fifth C site, C(31) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(17) atom. The C(31)-N(3) bond length is 1.31 Å. The C(31)-N(4) bond length is 1.37 Å. The C(31)-H(17) bond length is 0.95 Å. In the twenty-sixth C site, C(33) is bonded in a distorted single-bond geometry to one C(26), one C(27), and one H(19) atom. The C(33)-H(19) bond length is 0.95 Å. In the twenty-seventh C site, C(38,56) is bonded in a distorted single-bond geometry to one C(40); one C(41); and one H(1,12,23,34) atom. The C(38,56)-C(40) bond length is 1.37 Å. The C(38,56)-C(41) bond length is 1.41 Å. The C(38,56)-H(1,12,23,34) bond length is 0.95 Å. In the twenty-eighth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one C(47), one O(8), and one O(9) atom. The C(39)-C(47) bond length is 1.50 Å. The C(39)-O(8) bond length is 1.27 Å. The C(39)-O(9) bond length is 1.24 Å. In the twenty-ninth C site, C(40) is bonded in a distorted single-bond geometry to one C(38,56); one C(44); and one N(6) atom. The C(40)-C(44) bond length is 1.42 Å. The C(40)-N(6) bond length is 1.40 Å. In the thirtieth C site, C(41) is bonded in a trigonal planar geometry to one C(38,56); one C(45,63); and one C(6,24,42,60) atom. The C(41)-C(45,63) bond length is 1.44 Å. The C(41)-C(6,24,42,60) bond length is 1.43 Å. In the thirty-first C site, C(43) is bonded in a distorted single-bond geometry to one C(45,63) and one H(3,14,25,36) atom. The C(43)-C(45,63) bond length is 1.42 Å. The C(43)-H(3,14,25,36) bond length is 0.95 Å. In the thirty-second C site, C(44) is bonded in a distorted trigonal planar geometry to one C(40), one C(51), and one N(5) atom. The C(44)-C(51) bond length is 1.37 Å. The C(44)-N(5) bond length is 1.40 Å. In the thirty-third C site, C(45,63) is bonded in a trigonal planar geometry to one C(41), one C(43), and one C(51) atom. The C(45,63)-C(51) bond length is 1.41 Å. In the thirty-fourth C site, C(46,64) is bonded in a distorted single-bond geometry to one C(47) and one H(4,15,26,37) atom. The C(46,64)-C(47) bond length is 1.37 Å. The C(46,64)-H(4,15,26,37) bond length is 0.95 Å. In the thirty-fifth C site, C(47) is bonded in a trigonal planar geometry to one C(39); one C(46,64); and one C(48,66) atom. The C(47)-C(48,66) bond length is 1.40 Å. In the thirty-sixth C site, C(48,66) is bonded in a distorted trigonal planar geometry to one C(17,35,53,71); one C(47); and one H(5,16,27,38) atom. The C(48,66)-C(17,35,53,71) bond length is 1.39 Å. The C(48,66)-H(5,16,27,38) bond length is 0.95 Å. In the thirty-seventh C site, C(49) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(28) atom. The C(49)-N(5) bond length is 1.31 Å. The C(49)-N(6) bond length is 1.37 Å. The C(49)-H(28) bond length is 0.95 Å. In the thirty-eighth C site, C(51) is bonded in a distorted single-bond geometry to one C(44); one C(45,63); and one H(30,41) atom. The C(51)-H(30,41) bond length is 0.95 Å. In the thirty-ninth C site, C(57) is bonded in a distorted bent 120 degrees geometry to one C(65), one O(11), and one O(12) atom. The C(57)-C(65) bond length is 1.50 Å. The C(57)-O(11) bond length is 1.27 Å. The C(57)-O(12) bond length is 1.24 Å. In the fortieth C site, C(58) is bonded in a distorted single-bond geometry to one C(38,56); one C(62); and one N(8) atom. The C(58)-C(38,56) bond length is 1.37 Å. The C(58)-C(62) bond length is 1.42 Å. The C(58)-N(8) bond length is 1.40 Å. In the forty-first C site, C(59) is bonded in a trigonal planar geometry to one C(38,56); one C(45,63); and one C(6,24,42,60) atom. The C(59)-C(38,56) bond length is 1.41 Å. The C(59)-C(45,63) bond length is 1.44 Å. The C(59)-C(6,24,42,60) bond length is 1.43 Å. In the forty-second C site, C(61) is bonded in a distorted single-bond geometry to one C(45,63) and one H(3,14,25,36) atom. The C(61)-C(45,63) bond length is 1.42 Å. The C(61)-H(3,14,25,36) bond length is 0.95 Å. In the forty-third C site, C(62) is bonded in a distorted trigonal planar geometry to one C(58), one C(69), and one N(7) atom. The C(62)-C(69) bond length is 1.37 Å. The C(62)-N(7) bond length is 1.40 Å. In the forty-fourth C site, C(65) is bonded in a trigonal planar geometry to one C(46,64); one C(48,66); and one C(57) atom. The C(65)-C(46,64) bond length is 1.37 Å. The C(65)-C(48,66) bond length is 1.40 Å. In the forty-fifth C site, C(67) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(39) atom. The C(67)-N(7) bond length is 1.31 Å. The C(67)-N(8) bond length is 1.37 Å. The C(67)-H(39) bond length is 0.95 Å. In the forty-sixth C site, C(69) is bonded in a distorted single-bond geometry to one C(45,63); one C(62); and one H(30,41) atom. The C(69)-C(45,63) bond length is 1.41 Å. The C(69)-H(30,41) bond length is 0.95 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1,19,37,55); one C(13); and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(26), and one C(31) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1,19,37,55); one C(22); and one C(31) atom. The N(4)-C(1,19,37,55) bond length is 1.43 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(3), one C(44), and one C(49) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(1,19,37,55); one C(40); and one C(49) atom. The N(6)-C(1,19,37,55) bond length is 1.43 Å. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Zn(4), one C(62), and one C(67) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(1,19,37,55); one C(58); and one C(67) atom. The N(8)-C(1,19,37,55) bond length is 1.43 Å. There are eighteen inequivalent H sites. In the first H site, H(1,12,23,34) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2,13,24,35) is bonded in a single-bond geometry to one C(6,24,42,60) atom. In the third H site, H(3,14,25,36) is bonded in a single-bond geometry to one C(7,25) atom. In the fourth H site, H(4,15,26,37) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(5,16,27,38) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(9,20,31,42) is bonded in a single-bond geometry to one C(16,34,52,70) atom. In the ninth H site, H(10,21,32,43) is bonded in a single-bond geometry to one C(17,35,53,71) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(31) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(33) atom. In the twelfth H site, H(28) is bonded in a single-bond geometry to one C(49) atom. In the thirteenth H site, H(30,41) is bonded in a single-bond geometry to one C(51) atom. In the fourteenth H site, H(39) is bonded in a single-bond geometry to one C(67) atom. In the fifteenth H site, H(45) is bonded in a single-bond geometry to one O(10) atom. The H(45)-O(10) bond length is 1.00 Å. In the sixteenth H site, H(46) is bonded in a single-bond geometry to one O(4) atom. The H(46)-O(4) bond length is 1.13 Å. In the seventeenth H site, H(47) is bonded in a single-bond geometry to one O(1) atom. The H(47)-O(1) bond length is 0.89 Å. In the eighteenth H site, H(48) is bonded in a single-bond geometry to one O(7) atom. The H(48)-O(7) bond length is 1.00 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(2), and one H(47) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(2), and one H(46) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(21) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(21) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Zn(3), one Zn(4), and one H(48) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(39) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(39) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Zn(3), one Zn(4), and one H(45) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(57) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one C(57) atom. Linkers: 4 [O]C(=O)c1ccc(-n2cnc3cc4ccccc4cc32)cc1 ,1 [CH]c1cc2ncn(-c3ccc(C([O])=O)cc3)c2cc1C=[CH] ,1 O=[C]c1ccc(-n2cnc3cc4ccccc4cc32)cc1 ,1 [O]C(=O)c1ccc(-n2cnc3cc4c[c]ccc4cc32)cc1 ,1 [C]N(C=[N])c1ccc(C([O])=O)cc1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 8.23 A, density 1.33 g/cm3, surface area 4532.08 m2/g, accessible volume 0.32 cm3/g