Mn9C157H158(NO3)12(CH2)23 crystallizes in the triclinic P1 space group. The structure consists of twenty-three 02329_fluka molecules inside a Mn9C157H158(NO3)12 framework. In the Mn9C157H158(NO3)12 framework, there are nine inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 5-coordinate geometry to one O(1), one O(12), one O(2), one O(35), and one O(6) atom. The Mn(1)-O(1) bond length is 2.37 Å. The Mn(1)-O(12) bond length is 2.07 Å. The Mn(1)-O(2) bond length is 2.19 Å. The Mn(1)-O(35) bond length is 2.01 Å. The Mn(1)-O(6) bond length is 2.04 Å. In the second Mn site, Mn(2) is bonded in an octahedral geometry to one O(1), one O(11), one O(17), one O(24), one O(30), and one O(5) atom. The Mn(2)-O(1) bond length is 2.24 Å. The Mn(2)-O(11) bond length is 2.13 Å. The Mn(2)-O(17) bond length is 2.19 Å. The Mn(2)-O(24) bond length is 2.16 Å. The Mn(2)-O(30) bond length is 2.13 Å. The Mn(2)-O(5) bond length is 2.16 Å. In the third Mn site, Mn(3) is bonded in a 5-coordinate geometry to one O(17), one O(18), one O(21), one O(23), and one O(29) atom. The Mn(3)-O(17) bond length is 2.40 Å. The Mn(3)-O(18) bond length is 2.16 Å. The Mn(3)-O(21) bond length is 2.03 Å. The Mn(3)-O(23) bond length is 2.07 Å. The Mn(3)-O(29) bond length is 2.01 Å. In the fourth Mn site, Mn(4) is bonded in a square pyramidal geometry to one N(1), one N(2), one O(3), one O(4), and one O(9) atom. The Mn(4)-N(1) bond length is 1.98 Å. The Mn(4)-N(2) bond length is 1.97 Å. The Mn(4)-O(3) bond length is 1.88 Å. The Mn(4)-O(4) bond length is 1.85 Å. The Mn(4)-O(9) bond length is 2.02 Å. In the fifth Mn site, Mn(5) is bonded in a square pyramidal geometry to one N(3), one N(4), one O(16), one O(7), and one O(8) atom. The Mn(5)-N(3) bond length is 1.97 Å. The Mn(5)-N(4) bond length is 1.99 Å. The Mn(5)-O(16) bond length is 2.14 Å. The Mn(5)-O(7) bond length is 1.87 Å. The Mn(5)-O(8) bond length is 1.89 Å. In the sixth Mn site, Mn(6) is bonded in a square pyramidal geometry to one N(5), one N(6), one O(13), one O(14), and one O(33) atom. The Mn(6)-N(5) bond length is 1.96 Å. The Mn(6)-N(6) bond length is 1.94 Å. The Mn(6)-O(13) bond length is 1.88 Å. The Mn(6)-O(14) bond length is 1.89 Å. The Mn(6)-O(33) bond length is 2.20 Å. In the seventh Mn site, Mn(7) is bonded in a square pyramidal geometry to one N(7), one N(8), one O(19), one O(20), and one O(27) atom. The Mn(7)-N(7) bond length is 1.96 Å. The Mn(7)-N(8) bond length is 1.97 Å. The Mn(7)-O(19) bond length is 1.87 Å. The Mn(7)-O(20) bond length is 1.91 Å. The Mn(7)-O(27) bond length is 2.07 Å. In the eighth Mn site, Mn(8) is bonded in a square pyramidal geometry to one N(10), one N(9), one O(25), one O(26), and one O(34) atom. The Mn(8)-N(10) bond length is 1.99 Å. The Mn(8)-N(9) bond length is 1.98 Å. The Mn(8)-O(25) bond length is 1.89 Å. The Mn(8)-O(26) bond length is 1.84 Å. The Mn(8)-O(34) bond length is 2.15 Å. In the ninth Mn site, Mn(9) is bonded in a square pyramidal geometry to one N(11), one N(12), one O(15), one O(31), and one O(32) atom. The Mn(9)-N(11) bond length is 1.96 Å. The Mn(9)-N(12) bond length is 2.00 Å. The Mn(9)-O(15) bond length is 2.22 Å. The Mn(9)-O(31) bond length is 1.82 Å. The Mn(9)-O(32) bond length is 1.88 Å. There are one hundred and fifty-seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(7) bond length is 1.37 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.45 Å. The C(4)-C(8) bond length is 1.52 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one O(3) atom. The C(5)-C(6) bond length is 1.44 Å. The C(5)-O(3) bond length is 1.31 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(12), one C(5), and one C(7) atom. The C(6)-C(12) bond length is 1.42 Å. The C(6)-C(7) bond length is 1.36 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(2) atom. The C(7)-H(2) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a tetrahedral geometry to one C(10), one C(11), one C(4), and one C(9) atom. The C(8)-C(10) bond length is 1.53 Å. The C(8)-C(11) bond length is 1.54 Å. The C(8)-C(9) bond length is 1.52 Å. In the ninth C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(8) and three equivalent H(3,4,5,8,78,79) atoms. All C(9)-H(3,4,5,8,78,79) bond lengths are 0.96 Å. In the tenth C site, C(10) is bonded in a trigonal non-coplanar geometry to one C(8); one H(3,4,5,8,78,79); and two equivalent H(6,7) atoms. The C(10)-H(3,4,5,8,78,79) bond length is 0.96 Å. Both C(10)-H(6,7) bond lengths are 0.96 Å. In the eleventh C site, C(11) is bonded in a trigonal non-coplanar geometry to one C(8), one H(10), one H(11), and one H(9) atom. The C(11)-H(10) bond length is 0.96 Å. The C(11)-H(11) bond length is 0.96 Å. The C(11)-H(9) bond length is 0.96 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one H(12) atom. The C(12)-N(1) bond length is 1.31 Å. The C(12)-H(12) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a 2-coordinate geometry to one N(1) and one H(13) atom. The C(13)-N(1) bond length is 1.50 Å. The C(13)-H(13) bond length is 0.98 Å. In the fourteenth C site, C(18) is bonded in a 2-coordinate geometry to one N(2) and one H(22) atom. The C(18)-N(2) bond length is 1.47 Å. The C(18)-H(22) bond length is 0.98 Å. In the fifteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(2), and one H(23) atom. The C(19)-C(21) bond length is 1.43 Å. The C(19)-N(2) bond length is 1.30 Å. The C(19)-H(23) bond length is 0.93 Å. In the sixteenth C site, C(20) is bonded in a bent 120 degrees geometry to one C(25), one O(35), and one O(36) atom. The C(20)-C(25) bond length is 1.49 Å. The C(20)-O(35) bond length is 1.24 Å. The C(20)-O(36) bond length is 1.22 Å. In the seventeenth C site, C(21) is bonded in a trigonal planar geometry to one C(19), one C(22), and one C(26) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-C(26) bond length is 1.39 Å. In the eighteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one O(4) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-O(4) bond length is 1.36 Å. In the nineteenth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(27) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-C(27) bond length is 1.58 Å. In the twentieth C site, C(24) is bonded in a single-bond geometry to one C(23), one C(25), and one H(24) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(24) bond length is 0.93 Å. In the twenty-first C site, C(25) is bonded in a trigonal planar geometry to one C(20), one C(24), and one C(26) atom. The C(25)-C(26) bond length is 1.39 Å. In the twenty-second C site, C(26) is bonded in a distorted single-bond geometry to one C(21), one C(25), and one H(25) atom. The C(26)-H(25) bond length is 0.93 Å. In the twenty-third C site, C(27) is bonded in a tetrahedral geometry to one C(23), one C(28), one C(29), and one C(30) atom. The C(27)-C(28) bond length is 1.50 Å. The C(27)-C(29) bond length is 1.56 Å. The C(27)-C(30) bond length is 1.56 Å. In the twenty-fourth C site, C(28) is bonded in a trigonal non-coplanar geometry to one C(27) and three equivalent H(26,27,28) atoms. All C(28)-H(26,27,28) bond lengths are 0.96 Å. In the twenty-fifth C site, C(29) is bonded in a trigonal non-coplanar geometry to one C(27); one H(31); and two equivalent H(29,30) atoms. The C(29)-H(31) bond length is 0.96 Å. Both C(29)-H(29,30) bond lengths are 0.96 Å. In the twenty-sixth C site, C(30) is bonded in a trigonal non-coplanar geometry to one C(27) and three equivalent H(32,33,34) atoms. All C(30)-H(32,33,34) bond lengths are 0.96 Å. In the twenty-seventh C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(5), and one O(6) atom. The C(31)-C(32) bond length is 1.47 Å. The C(31)-O(5) bond length is 1.27 Å. The C(31)-O(6) bond length is 1.26 Å. In the twenty-eighth C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(37) atom. The C(32)-C(33) bond length is 1.44 Å. The C(32)-C(37) bond length is 1.36 Å. In the twenty-ninth C site, C(33) is bonded in a single-bond geometry to one C(32), one C(34), and one H(35) atom. The C(33)-C(34) bond length is 1.38 Å. The C(33)-H(35) bond length is 0.93 Å. In the thirtieth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(38) atom. The C(34)-C(35) bond length is 1.46 Å. The C(34)-C(38) bond length is 1.54 Å. In the thirty-first C site, C(35) is bonded in a distorted single-bond geometry to one C(34), one C(36), and one O(7) atom. The C(35)-C(36) bond length is 1.37 Å. The C(35)-O(7) bond length is 1.31 Å. In the thirty-second C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(42) atom. The C(36)-C(37) bond length is 1.37 Å. The C(36)-C(42) bond length is 1.42 Å. In the thirty-third C site, C(37) is bonded in a distorted single-bond geometry to one C(32), one C(36), and one H(36) atom. The C(37)-H(36) bond length is 0.93 Å. In the thirty-fourth C site, C(38) is bonded in a tetrahedral geometry to one C(34), one C(39), one C(40), and one C(41) atom. The C(38)-C(39) bond length is 1.46 Å. The C(38)-C(40) bond length is 1.50 Å. The C(38)-C(41) bond length is 1.56 Å. In the thirty-fifth C site, C(39) is bonded in a trigonal non-coplanar geometry to one C(38) and three equivalent H(37,38,39,40,43,44,45) atoms. All C(39)-H(37,38,39,40,43,44,45) bond lengths are 0.96 Å. In the thirty-sixth C site, C(40) is bonded in a trigonal non-coplanar geometry to one C(38); one H(37,38,39,40,43,44,45); one H(41); and one H(42) atom. The C(40)-H(37,38,39,40,43,44,45) bond length is 0.96 Å. The C(40)-H(41) bond length is 0.96 Å. The C(40)-H(42) bond length is 0.96 Å. In the thirty-seventh C site, C(41) is bonded in a trigonal non-coplanar geometry to one C(38) and three equivalent H(37,38,39,40,43,44,45) atoms. All C(41)-H(37,38,39,40,43,44,45) bond lengths are 0.96 Å. In the thirty-eighth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(36), one N(3), and one H(46) atom. The C(42)-N(3) bond length is 1.31 Å. The C(42)-H(46) bond length is 0.93 Å. In the thirty-ninth C site, C(43) is bonded in a 2-coordinate geometry to one N(3) and one H(47) atom. The C(43)-N(3) bond length is 1.49 Å. The C(43)-H(47) bond length is 0.98 Å. In the fortieth C site, C(48) is bonded in a 2-coordinate geometry to one N(4) and one H(56) atom. The C(48)-N(4) bond length is 1.48 Å. The C(48)-H(56) bond length is 0.98 Å. In the forty-first C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(50), one N(4), and one H(57) atom. The C(49)-C(50) bond length is 1.43 Å. The C(49)-N(4) bond length is 1.27 Å. The C(49)-H(57) bond length is 0.93 Å. In the forty-second C site, C(50) is bonded in a trigonal planar geometry to one C(49), one C(51), and one C(55) atom. The C(50)-C(51) bond length is 1.44 Å. The C(50)-C(55) bond length is 1.42 Å. In the forty-third C site, C(51) is bonded in a distorted single-bond geometry to one C(50), one C(52), and one O(8) atom. The C(51)-C(52) bond length is 1.42 Å. The C(51)-O(8) bond length is 1.28 Å. In the forty-fourth C site, C(52) is bonded in a trigonal planar geometry to one C(51), one C(53), and one C(57) atom. The C(52)-C(53) bond length is 1.40 Å. The C(52)-C(57) bond length is 1.54 Å. In the forty-fifth C site, C(53) is bonded in a distorted single-bond geometry to one C(52), one C(54), and one H(58) atom. The C(53)-C(54) bond length is 1.37 Å. The C(53)-H(58) bond length is 0.93 Å. In the forty-sixth C site, C(54) is bonded in a trigonal planar geometry to one C(53), one C(55), and one C(56) atom. The C(54)-C(55) bond length is 1.36 Å. The C(54)-C(56) bond length is 1.51 Å. In the forty-seventh C site, C(55) is bonded in a single-bond geometry to one C(50), one C(54), and one H(59) atom. The C(55)-H(59) bond length is 0.93 Å. In the forty-eighth C site, C(56) is bonded in a distorted bent 120 degrees geometry to one C(54), one O(10), and one O(9) atom. The C(56)-O(10) bond length is 1.20 Å. The C(56)-O(9) bond length is 1.25 Å. In the forty-ninth C site, C(57) is bonded in a tetrahedral geometry to one C(52), one C(58), one C(59), and one C(60) atom. The C(57)-C(58) bond length is 1.51 Å. The C(57)-C(59) bond length is 1.61 Å. The C(57)-C(60) bond length is 1.52 Å. In the fiftieth C site, C(58) is bonded in a trigonal non-coplanar geometry to one C(57); one H(61,68); and two equivalent H(60,62,63,64,65,66,67) atoms. The C(58)-H(61,68) bond length is 0.96 Å. Both C(58)-H(60,62,63,64,65,66,67) bond lengths are 0.96 Å. In the fifty-first C site, C(59) is bonded in a trigonal non-coplanar geometry to one C(57) and three equivalent H(60,62,63,64,65,66,67) atoms. All C(59)-H(60,62,63,64,65,66,67) bond lengths are 0.96 Å. In the fifty-second C site, C(60) is bonded in a trigonal non-coplanar geometry to one C(57); one H(61,68); and two equivalent H(60,62,63,64,65,66,67) atoms. The C(60)-H(61,68) bond length is 0.96 Å. Both C(60)-H(60,62,63,64,65,66,67) bond lengths are 0.96 Å. In the fifty-third C site, C(61) is bonded in a distorted bent 120 degrees geometry to one C(62), one O(11), and one O(12) atom. The C(61)-C(62) bond length is 1.52 Å. The C(61)-O(11) bond length is 1.24 Å. The C(61)-O(12) bond length is 1.23 Å. In the fifty-fourth C site, C(62) is bonded in a trigonal planar geometry to one C(61), one C(63), and one C(67) atom. The C(62)-C(63) bond length is 1.35 Å. The C(62)-C(67) bond length is 1.42 Å. In the fifty-fifth C site, C(63) is bonded in a distorted single-bond geometry to one C(62), one C(64), and one H(69) atom. The C(63)-C(64) bond length is 1.44 Å. The C(63)-H(69) bond length is 0.93 Å. In the fifty-sixth C site, C(64) is bonded in a trigonal planar geometry to one C(63), one C(65), and one C(72) atom. The C(64)-C(65) bond length is 1.38 Å. The C(64)-C(72) bond length is 1.45 Å. In the fifty-seventh C site, C(65) is bonded in a distorted single-bond geometry to one C(64), one C(66), and one O(13) atom. The C(65)-C(66) bond length is 1.40 Å. The C(65)-O(13) bond length is 1.31 Å. In the fifty-eighth C site, C(66) is bonded in a trigonal planar geometry to one C(65), one C(67), and one C(68) atom. The C(66)-C(67) bond length is 1.38 Å. The C(66)-C(68) bond length is 1.55 Å. In the fifty-ninth C site, C(67) is bonded in a single-bond geometry to one C(62), one C(66), and one H(70) atom. The C(67)-H(70) bond length is 0.93 Å. In the sixtieth C site, C(68) is bonded in a tetrahedral geometry to one C(66), one C(69), one C(70), and one C(71) atom. The C(68)-C(69) bond length is 1.52 Å. The C(68)-C(70) bond length is 1.57 Å. The C(68)-C(71) bond length is 1.57 Å. In the sixty-first C site, C(69) is bonded in a trigonal non-coplanar geometry to one C(68); one H(72); and two equivalent H(71,73,76) atoms. The C(69)-H(72) bond length is 0.96 Å. Both C(69)-H(71,73,76) bond lengths are 0.96 Å. In the sixty-second C site, C(70) is bonded in a trigonal non-coplanar geometry to one C(68); one H(71,73,76); one H(74); and one H(75) atom. The C(70)-H(71,73,76) bond length is 0.96 Å. The C(70)-H(74) bond length is 0.96 Å. The C(70)-H(75) bond length is 0.96 Å. In the sixty-third C site, C(71) is bonded in a trigonal non-coplanar geometry to one C(68); one H(77); and two equivalent H(3,4,5,8,78,79) atoms. The C(71)-H(77) bond length is 0.96 Å. Both C(71)-H(3,4,5,8,78,79) bond lengths are 0.96 Å. In the sixty-fourth C site, C(72) is bonded in a distorted bent 120 degrees geometry to one C(64), one N(5), and one H(80) atom. The C(72)-N(5) bond length is 1.30 Å. The C(72)-H(80) bond length is 0.93 Å. In the sixty-fifth C site, C(73) is bonded in a 2-coordinate geometry to one N(5) and one H(81) atom. The C(73)-N(5) bond length is 1.51 Å. The C(73)-H(81) bond length is 0.98 Å. In the sixty-sixth C site, C(78) is bonded in a 2-coordinate geometry to one N(6) and one H(90) atom. The C(78)-N(6) bond length is 1.49 Å. The C(78)-H(90) bond length is 0.98 Å. In the sixty-seventh C site, C(79) is bonded in a distorted bent 120 degrees geometry to one C(80), one N(6), and one H(91) atom. The C(79)-C(80) bond length is 1.42 Å. The C(79)-N(6) bond length is 1.34 Å. The C(79)-H(91) bond length is 0.93 Å. In the sixty-eighth C site, C(80) is bonded in a trigonal planar geometry to one C(79), one C(81), and one C(85) atom. The C(80)-C(81) bond length is 1.42 Å. The C(80)-C(85) bond length is 1.39 Å. In the sixty-ninth C site, C(81) is bonded in a distorted single-bond geometry to one C(80), one C(82), and one O(14) atom. The C(81)-C(82) bond length is 1.49 Å. The C(81)-O(14) bond length is 1.26 Å. In the seventieth C site, C(82) is bonded in a trigonal planar geometry to one C(81), one C(83), and one C(87) atom. The C(82)-C(83) bond length is 1.37 Å. The C(82)-C(87) bond length is 1.51 Å. In the seventy-first C site, C(83) is bonded in a distorted single-bond geometry to one C(82), one C(84), and one H(92) atom. The C(83)-C(84) bond length is 1.42 Å. The C(83)-H(92) bond length is 0.93 Å. In the seventy-second C site, C(84) is bonded in a trigonal planar geometry to one C(83), one C(85), and one C(86) atom. The C(84)-C(85) bond length is 1.36 Å. The C(84)-C(86) bond length is 1.51 Å. In the seventy-third C site, C(85) is bonded in a distorted single-bond geometry to one C(80), one C(84), and one H(93) atom. The C(85)-H(93) bond length is 0.93 Å. In the seventy-fourth C site, C(86) is bonded in a distorted bent 120 degrees geometry to one C(84), one O(15), and one O(16) atom. The C(86)-O(15) bond length is 1.23 Å. The C(86)-O(16) bond length is 1.27 Å. In the seventy-fifth C site, C(87) is bonded in a tetrahedral geometry to one C(82), one C(88), one C(89), and one C(90) atom. The C(87)-C(88) bond length is 1.49 Å. The C(87)-C(89) bond length is 1.48 Å. The C(87)-C(90) bond length is 1.55 Å. In the seventy-sixth C site, C(88) is bonded in a trigonal non-coplanar geometry to one C(87); one H(94,97,98); one H(95,99); and one H(96) atom. The C(88)-H(94,97,98) bond length is 0.96 Å. The C(88)-H(95,99) bond length is 0.96 Å. The C(88)-H(96) bond length is 0.96 Å. In the seventy-seventh C site, C(89) is bonded in a trigonal non-coplanar geometry to one C(87); one H(95,99); and two equivalent H(94,97,98) atoms. The C(89)-H(95,99) bond length is 0.96 Å. Both C(89)-H(94,97,98) bond lengths are 0.96 Å. In the seventy-eighth C site, C(90) is bonded in a trigonal non-coplanar geometry to one C(87); one H(101); and two equivalent H(100,102) atoms. The C(90)-H(101) bond length is 0.96 Å. Both C(90)-H(100,102) bond lengths are 0.96 Å. In the seventy-ninth C site, C(91) is bonded in a distorted bent 120 degrees geometry to one C(92), one O(17), and one O(18) atom. The C(91)-C(92) bond length is 1.56 Å. The C(91)-O(17) bond length is 1.23 Å. The C(91)-O(18) bond length is 1.24 Å. In the eightieth C site, C(92) is bonded in a trigonal planar geometry to one C(91), one C(93), and one C(97) atom. The C(92)-C(93) bond length is 1.39 Å. The C(92)-C(97) bond length is 1.40 Å. In the eighty-first C site, C(93) is bonded in a distorted single-bond geometry to one C(92), one C(94), and one H(103) atom. The C(93)-C(94) bond length is 1.42 Å. The C(93)-H(103) bond length is 0.93 Å. In the eighty-second C site, C(94) is bonded in a trigonal planar geometry to one C(102), one C(93), and one C(95) atom. The C(94)-C(102) bond length is 1.43 Å. The C(94)-C(95) bond length is 1.40 Å. In the eighty-third C site, C(95) is bonded in a distorted single-bond geometry to one C(94), one C(96), and one O(19) atom. The C(95)-C(96) bond length is 1.40 Å. The C(95)-O(19) bond length is 1.33 Å. In the eighty-fourth C site, C(96) is bonded in a trigonal planar geometry to one C(95), one C(97), and one C(98) atom. The C(96)-C(97) bond length is 1.38 Å. The C(96)-C(98) bond length is 1.55 Å. In the eighty-fifth C site, C(97) is bonded in a distorted single-bond geometry to one C(92), one C(96), and one H(104) atom. The C(97)-H(104) bond length is 0.93 Å. In the eighty-sixth C site, C(98) is bonded in a tetrahedral geometry to one C(100), one C(101), one C(96), and one C(99) atom. The C(98)-C(100) bond length is 1.52 Å. The C(98)-C(101) bond length is 1.54 Å. The C(98)-C(99) bond length is 1.51 Å. In the eighty-seventh C site, C(99) is bonded in a trigonal non-coplanar geometry to one C(98) and three equivalent H(105,106,107) atoms. All C(99)-H(105,106,107) bond lengths are 0.96 Å. In the eighty-eighth C site, C(100) is bonded in a trigonal non-coplanar geometry to one C(98), one H(108), one H(109), and one H(110) atom. The C(100)-H(108) bond length is 0.96 Å. The C(100)-H(109) bond length is 0.96 Å. The C(100)-H(110) bond length is 0.96 Å. In the eighty-ninth C site, C(101) is bonded in a trigonal non-coplanar geometry to one C(98); one H(113); and two equivalent H(111,112) atoms. The C(101)-H(113) bond length is 0.96 Å. Both C(101)-H(111,112) bond lengths are 0.96 Å. In the ninetieth C site, C(102) is bonded in a distorted bent 120 degrees geometry to one C(94), one N(7), and one H(114) atom. The C(102)-N(7) bond length is 1.29 Å. The C(102)-H(114) bond length is 0.93 Å. In the ninety-first C site, C(103) is bonded in a 2-coordinate geometry to one N(7) and one H(115) atom. The C(103)-N(7) bond length is 1.47 Å. The C(103)-H(115) bond length is 0.98 Å. In the ninety-second C site, C(108) is bonded in a 2-coordinate geometry to one N(8) and one H(124) atom. The C(108)-N(8) bond length is 1.49 Å. The C(108)-H(124) bond length is 0.98 Å. In the ninety-third C site, C(109) is bonded in a distorted bent 120 degrees geometry to one C(110), one N(8), and one H(125) atom. The C(109)-C(110) bond length is 1.43 Å. The C(109)-N(8) bond length is 1.27 Å. The C(109)-H(125) bond length is 0.93 Å. In the ninety-fourth C site, C(110) is bonded in a trigonal planar geometry to one C(109), one C(111), and one C(115) atom. The C(110)-C(111) bond length is 1.43 Å. The C(110)-C(115) bond length is 1.44 Å. In the ninety-fifth C site, C(111) is bonded in a single-bond geometry to one C(110), one C(112), and one O(20) atom. The C(111)-C(112) bond length is 1.48 Å. The C(111)-O(20) bond length is 1.27 Å. In the ninety-sixth C site, C(112) is bonded in a trigonal planar geometry to one C(111), one C(113), and one C(117) atom. The C(112)-C(113) bond length is 1.36 Å. The C(112)-C(117) bond length is 1.49 Å. In the ninety-seventh C site, C(113) is bonded in a distorted single-bond geometry to one C(112), one C(114), and one H(126) atom. The C(113)-C(114) bond length is 1.40 Å. The C(113)-H(126) bond length is 0.93 Å. In the ninety-eighth C site, C(114) is bonded in a trigonal planar geometry to one C(113), one C(115), and one C(116) atom. The C(114)-C(115) bond length is 1.35 Å. The C(114)-C(116) bond length is 1.52 Å. In the ninety-ninth C site, C(115) is bonded in a distorted single-bond geometry to one C(110), one C(114), and one H(127) atom. The C(115)-H(127) bond length is 0.93 Å. In the one hundredth C site, C(116) is bonded in a bent 120 degrees geometry to one C(114), one O(21), and one O(22) atom. The C(116)-O(21) bond length is 1.23 Å. The C(116)-O(22) bond length is 1.19 Å. In the one hundred and first C site, C(117) is bonded in a tetrahedral geometry to one C(112), one C(118), one C(119), and one C(120) atom. The C(117)-C(118) bond length is 1.53 Å. The C(117)-C(119) bond length is 1.53 Å. The C(117)-C(120) bond length is 1.51 Å. In the one hundred and second C site, C(118) is bonded in a trigonal non-coplanar geometry to one C(117); one H(130); and two equivalent H(128,129) atoms. The C(118)-H(130) bond length is 0.96 Å. Both C(118)-H(128,129) bond lengths are 0.96 Å. In the one hundred and third C site, C(119) is bonded in a trigonal non-coplanar geometry to one C(117) and three equivalent H(131,132,133,135,136) atoms. All C(119)-H(131,132,133,135,136) bond lengths are 0.96 Å. In the one hundred and fourth C site, C(120) is bonded in a trigonal non-coplanar geometry to one C(117); one H(134); and two equivalent H(131,132,133,135,136) atoms. The C(120)-H(134) bond length is 0.96 Å. Both C(120)-H(131,132,133,135,136) bond lengths are 0.96 Å. In the one hundred and fifth C site, C(121) is bonded in a distorted bent 120 degrees geometry to one C(122), one O(23), and one O(24) atom. The C(121)-C(122) bond length is 1.53 Å. The C(121)-O(23) bond length is 1.26 Å. The C(121)-O(24) bond length is 1.24 Å. In the one hundred and sixth C site, C(122) is bonded in a trigonal planar geometry to one C(121), one C(123), and one C(127) atom. The C(122)-C(123) bond length is 1.38 Å. The C(122)-C(127) bond length is 1.37 Å. In the one hundred and seventh C site, C(123) is bonded in a single-bond geometry to one C(122), one C(124), and one H(137) atom. The C(123)-C(124) bond length is 1.38 Å. The C(123)-H(137) bond length is 0.93 Å. In the one hundred and eighth C site, C(124) is bonded in a trigonal planar geometry to one C(123), one C(125), and one C(128) atom. The C(124)-C(125) bond length is 1.40 Å. The C(124)-C(128) bond length is 1.51 Å. In the one hundred and ninth C site, C(125) is bonded in a distorted single-bond geometry to one C(124), one C(126), and one O(25) atom. The C(125)-C(126) bond length is 1.46 Å. The C(125)-O(25) bond length is 1.32 Å. In the one hundred and tenth C site, C(126) is bonded in a trigonal planar geometry to one C(125), one C(127), and one C(132) atom. The C(126)-C(127) bond length is 1.42 Å. The C(126)-C(132) bond length is 1.43 Å. In the one hundred and eleventh C site, C(127) is bonded in a distorted single-bond geometry to one C(122), one C(126), and one H(138) atom. The C(127)-H(138) bond length is 0.93 Å. In the one hundred and twelfth C site, C(128) is bonded in a tetrahedral geometry to one C(124), one C(129), one C(130), and one C(131) atom. The C(128)-C(129) bond length is 1.52 Å. The C(128)-C(130) bond length is 1.59 Å. The C(128)-C(131) bond length is 1.58 Å. In the one hundred and thirteenth C site, C(129) is bonded in a trigonal non-coplanar geometry to one C(128) and three equivalent H(139,140,141) atoms. All C(129)-H(139,140,141) bond lengths are 0.96 Å. In the one hundred and fourteenth C site, C(130) is bonded in a trigonal non-coplanar geometry to one C(128); one H(144); and two equivalent H(142,143) atoms. The C(130)-H(144) bond length is 0.96 Å. Both C(130)-H(142,143) bond lengths are 0.96 Å. In the one hundred and fifteenth C site, C(131) is bonded in a trigonal non-coplanar geometry to one C(128); one H(145); and two equivalent H(146,147) atoms. The C(131)-H(145) bond length is 0.96 Å. Both C(131)-H(146,147) bond lengths are 0.96 Å. In the one hundred and sixteenth C site, C(132) is bonded in a distorted bent 120 degrees geometry to one C(126), one N(9), and one H(148) atom. The C(132)-N(9) bond length is 1.24 Å. The C(132)-H(148) bond length is 0.93 Å. In the one hundred and seventeenth C site, C(133) is bonded in a 4-coordinate geometry to one C(134), one C(138), one N(9), and one H(149) atom. The C(133)-C(134) bond length is 1.50 Å. The C(133)-C(138) bond length is 1.51 Å. The C(133)-N(9) bond length is 1.53 Å. The C(133)-H(149) bond length is 0.98 Å. In the one hundred and eighteenth C site, C(134) is bonded in a water-like geometry to one C(133), one H(150), and one H(151) atom. The C(134)-H(150) bond length is 0.97 Å. The C(134)-H(151) bond length is 0.97 Å. In the one hundred and nineteenth C site, C(138) is bonded in a 2-coordinate geometry to one C(133), one N(10), and one H(158) atom. The C(138)-N(10) bond length is 1.52 Å. The C(138)-H(158) bond length is 0.98 Å. In the one hundred and twentieth C site, C(139) is bonded in a distorted bent 120 degrees geometry to one C(140), one N(10), and one H(159) atom. The C(139)-C(140) bond length is 1.43 Å. The C(139)-N(10) bond length is 1.27 Å. The C(139)-H(159) bond length is 0.93 Å. In the one hundred and twenty-first C site, C(140) is bonded in a trigonal planar geometry to one C(139), one C(141), and one C(145) atom. The C(140)-C(141) bond length is 1.40 Å. The C(140)-C(145) bond length is 1.40 Å. In the one hundred and twenty-second C site, C(141) is bonded in a distorted single-bond geometry to one C(140), one C(142), and one O(26) atom. The C(141)-C(142) bond length is 1.44 Å. The C(141)-O(26) bond length is 1.36 Å. In the one hundred and twenty-third C site, C(142) is bonded in a trigonal planar geometry to one C(141), one C(143), and one C(147) atom. The C(142)-C(143) bond length is 1.34 Å. The C(142)-C(147) bond length is 1.55 Å. In the one hundred and twenty-fourth C site, C(143) is bonded in a distorted single-bond geometry to one C(142), one C(144), and one H(160) atom. The C(143)-C(144) bond length is 1.44 Å. The C(143)-H(160) bond length is 0.93 Å. In the one hundred and twenty-fifth C site, C(144) is bonded in a trigonal planar geometry to one C(143), one C(145), and one C(146) atom. The C(144)-C(145) bond length is 1.36 Å. The C(144)-C(146) bond length is 1.49 Å. In the one hundred and twenty-sixth C site, C(145) is bonded in a distorted single-bond geometry to one C(140), one C(144), and one H(161) atom. The C(145)-H(161) bond length is 0.93 Å. In the one hundred and twenty-seventh C site, C(146) is bonded in a distorted bent 120 degrees geometry to one C(144), one O(27), and one O(28) atom. The C(146)-O(27) bond length is 1.26 Å. The C(146)-O(28) bond length is 1.24 Å. In the one hundred and twenty-eighth C site, C(147) is bonded in a tetrahedral geometry to one C(142), one C(148), one C(149), and one C(150) atom. The C(147)-C(148) bond length is 1.58 Å. The C(147)-C(149) bond length is 1.44 Å. The C(147)-C(150) bond length is 1.56 Å. In the one hundred and twenty-ninth C site, C(148) is bonded in a trigonal non-coplanar geometry to one C(147), one H(162), one H(163), and one H(164) atom. The C(148)-H(162) bond length is 0.96 Å. The C(148)-H(163) bond length is 0.96 Å. The C(148)-H(164) bond length is 0.96 Å. In the one hundred and thirtieth C site, C(149) is bonded in a trigonal non-coplanar geometry to one C(147) and three equivalent H(165,166,167) atoms. All C(149)-H(165,166,167) bond lengths are 0.96 Å. In the one hundred and thirty-first C site, C(150) is bonded in a trigonal non-coplanar geometry to one C(147) and three equivalent H(168,169,170) atoms. All C(150)-H(168,169,170) bond lengths are 0.96 Å. In the one hundred and thirty-second C site, C(151) is bonded in a distorted bent 120 degrees geometry to one C(152), one O(29), and one O(30) atom. The C(151)-C(152) bond length is 1.47 Å. The C(151)-O(29) bond length is 1.29 Å. The C(151)-O(30) bond length is 1.25 Å. In the one hundred and thirty-third C site, C(152) is bonded in a trigonal planar geometry to one C(151), one C(153), and one C(157) atom. The C(152)-C(153) bond length is 1.38 Å. The C(152)-C(157) bond length is 1.40 Å. In the one hundred and thirty-fourth C site, C(153) is bonded in a single-bond geometry to one C(152), one C(154), and one H(171) atom. The C(153)-C(154) bond length is 1.39 Å. The C(153)-H(171) bond length is 0.93 Å. In the one hundred and thirty-fifth C site, C(154) is bonded in a trigonal planar geometry to one C(153), one C(155), and one C(158) atom. The C(154)-C(155) bond length is 1.46 Å. The C(154)-C(158) bond length is 1.52 Å. In the one hundred and thirty-sixth C site, C(155) is bonded in a distorted single-bond geometry to one C(154), one C(156), and one O(31) atom. The C(155)-C(156) bond length is 1.42 Å. The C(155)-O(31) bond length is 1.32 Å. In the one hundred and thirty-seventh C site, C(156) is bonded in a trigonal planar geometry to one C(155), one C(157), and one C(162) atom. The C(156)-C(157) bond length is 1.40 Å. The C(156)-C(162) bond length is 1.42 Å. In the one hundred and thirty-eighth C site, C(157) is bonded in a distorted single-bond geometry to one C(152), one C(156), and one H(172) atom. The C(157)-H(172) bond length is 0.93 Å. In the one hundred and thirty-ninth C site, C(158) is bonded in a tetrahedral geometry to one C(154), one C(159), one C(160), and one C(161) atom. The C(158)-C(159) bond length is 1.58 Å. The C(158)-C(160) bond length is 1.49 Å. The C(158)-C(161) bond length is 1.49 Å. In the one hundred and fortieth C site, C(159) is bonded in a trigonal non-coplanar geometry to one C(158), one H(173), one H(174), and one H(175) atom. The C(159)-H(173) bond length is 0.96 Å. The C(159)-H(174) bond length is 0.96 Å. The C(159)-H(175) bond length is 0.96 Å. In the one hundred and forty-first C site, C(160) is bonded in a trigonal non-coplanar geometry to one C(158), one H(176), one H(177), and one H(178) atom. The C(160)-H(176) bond length is 0.96 Å. The C(160)-H(177) bond length is 0.96 Å. The C(160)-H(178) bond length is 0.96 Å. In the one hundred and forty-second C site, C(161) is bonded in a trigonal non-coplanar geometry to one C(158), one H(179), one H(180), and one H(181) atom. The C(161)-H(179) bond length is 0.96 Å. The C(161)-H(180) bond length is 0.96 Å. The C(161)-H(181) bond length is 0.96 Å. In the one hundred and forty-third C site, C(162) is bonded in a distorted bent 120 degrees geometry to one C(156), one N(11), and one H(182) atom. The C(162)-N(11) bond length is 1.26 Å. The C(162)-H(182) bond length is 0.93 Å. In the one hundred and forty-fourth C site, C(163) is bonded in a 2-coordinate geometry to one N(11) and one H(183) atom. The C(163)-N(11) bond length is 1.50 Å. The C(163)-H(183) bond length is 0.98 Å. In the one hundred and forty-fifth C site, C(168) is bonded in a 2-coordinate geometry to one N(12) and one H(192) atom. The C(168)-N(12) bond length is 1.48 Å. The C(168)-H(192) bond length is 0.98 Å. In the one hundred and forty-sixth C site, C(169) is bonded in a distorted bent 120 degrees geometry to one C(171), one N(12), and one H(193) atom. The C(169)-C(171) bond length is 1.46 Å. The C(169)-N(12) bond length is 1.25 Å. The C(169)-H(193) bond length is 0.93 Å. In the one hundred and forty-seventh C site, C(170) is bonded in a distorted bent 120 degrees geometry to one C(175), one O(33), and one O(34) atom. The C(170)-C(175) bond length is 1.49 Å. The C(170)-O(33) bond length is 1.31 Å. The C(170)-O(34) bond length is 1.26 Å. In the one hundred and forty-eighth C site, C(171) is bonded in a trigonal planar geometry to one C(169), one C(172), and one C(176) atom. The C(171)-C(172) bond length is 1.39 Å. The C(171)-C(176) bond length is 1.39 Å. In the one hundred and forty-ninth C site, C(172) is bonded in a distorted single-bond geometry to one C(171), one C(173), and one O(32) atom. The C(172)-C(173) bond length is 1.39 Å. The C(172)-O(32) bond length is 1.36 Å. In the one hundred and fiftieth C site, C(173) is bonded in a trigonal planar geometry to one C(172), one C(174), and one C(177) atom. The C(173)-C(174) bond length is 1.39 Å. The C(173)-C(177) bond length is 1.59 Å. In the one hundred and fifty-first C site, C(174) is bonded in a distorted single-bond geometry to one C(173), one C(175), and one H(194) atom. The C(174)-C(175) bond length is 1.39 Å. The C(174)-H(194) bond length is 0.93 Å. In the one hundred and fifty-second C site, C(175) is bonded in a trigonal planar geometry to one C(170), one C(174), and one C(176) atom. The C(175)-C(176) bond length is 1.39 Å. In the one hundred and fifty-third C site, C(176) is bonded in a distorted single-bond geometry to one C(171), one C(175), and one H(195) atom. The C(176)-H(195) bond length is 0.93 Å. In the one hundred and fifty-fourth C site, C(177) is bonded in a tetrahedral geometry to one C(173), one C(178), one C(179), and one C(180) atom. The C(177)-C(178) bond length is 1.56 Å. The C(177)-C(179) bond length is 1.53 Å. The C(177)-C(180) bond length is 1.53 Å. In the one hundred and fifty-fifth C site, C(178) is bonded in a trigonal non-coplanar geometry to one C(177), one H(196), one H(197), and one H(198) atom. The C(178)-H(196) bond length is 0.96 Å. The C(178)-H(197) bond length is 0.96 Å. The C(178)-H(198) bond length is 0.96 Å. In the one hundred and fifty-sixth C site, C(179) is bonded in a trigonal non-coplanar geometry to one C(177) and three equivalent H(199,200,201) atoms. All C(179)-H(199,200,201) bond lengths are 0.96 Å. In the one hundred and fifty-seventh C site, C(180) is bonded in a trigonal non-coplanar geometry to one C(177) and three equivalent H(202,203,204) atoms. All C(180)-H(202,203,204) bond lengths are 0.96 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(4), one C(12), and one C(13) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(4), one C(18), and one C(19) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Mn(5), one C(42), and one C(43) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Mn(5), one C(48), and one C(49) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Mn(6), one C(72), and one C(73) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Mn(6), one C(78), and one C(79) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Mn(7), one C(102), and one C(103) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Mn(7), one C(108), and one C(109) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Mn(8), one C(132), and one C(133) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Mn(8), one C(138), and one C(139) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Mn(9), one C(162), and one C(163) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Mn(9), one C(168), and one C(169) atom. There are one hundred and eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3,4,5,8,78,79) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(6,7) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(23) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(24) atom. In the thirteenth H site, H(25) is bonded in a single-bond geometry to one C(26) atom. In the fourteenth H site, H(26,27,28) is bonded in a single-bond geometry to one C(28) atom. In the fifteenth H site, H(29,30) is bonded in a single-bond geometry to one C(29) atom. In the sixteenth H site, H(31) is bonded in a single-bond geometry to one C(29) atom. In the seventeenth H site, H(32,33,34) is bonded in a single-bond geometry to one C(30) atom. In the eighteenth H site, H(35) is bonded in a single-bond geometry to one C(33) atom. In the nineteenth H site, H(36) is bonded in a single-bond geometry to one C(37) atom. In the twentieth H site, H(37,38,39,40,43,44,45) is bonded in a single-bond geometry to one C(39) atom. In the twenty-first H site, H(41) is bonded in a single-bond geometry to one C(40) atom. In the twenty-second H site, H(42) is bonded in a single-bond geometry to one C(40) atom. In the twenty-third H site, H(46) is bonded in a single-bond geometry to one C(42) atom. In the twenty-fourth H site, H(47) is bonded in a single-bond geometry to one C(43) atom. In the twenty-fifth H site, H(56) is bonded in a single-bond geometry to one C(48) atom. In the twenty-sixth H site, H(57) is bonded in a single-bond geometry to one C(49) atom. In the twenty-seventh H site, H(58) is bonded in a single-bond geometry to one C(53) atom. In the twenty-eighth H site, H(59) is bonded in a single-bond geometry to one C(55) atom. In the twenty-ninth H site, H(60,62,63,64,65,66,67) is bonded in a single-bond geometry to one C(58) atom. In the thirtieth H site, H(61,68) is bonded in a single-bond geometry to one C(58) atom. In the thirty-first H site, H(69) is bonded in a single-bond geometry to one C(63) atom. In the thirty-second H site, H(70) is bonded in a single-bond geometry to one C(67) atom. In the thirty-third H site, H(71,73,76) is bonded in a single-bond geometry to one C(69) atom. In the thirty-fourth H site, H(72) is bonded in a single-bond geometry to one C(69) atom. In the thirty-fifth H site, H(74) is bonded in a single-bond geometry to one C(70) atom. In the thirty-sixth H site, H(75) is bonded in a single-bond geometry to one C(70) atom. In the thirty-seventh H site, H(77) is bonded in a single-bond geometry to one C(71) atom. In the thirty-eighth H site, H(80) is bonded in a single-bond geometry to one C(72) atom. In the thirty-ninth H site, H(81) is bonded in a single-bond geometry to one C(73) atom. In the fortieth H site, H(90) is bonded in a single-bond geometry to one C(78) atom. In the forty-first H site, H(91) is bonded in a single-bond geometry to one C(79) atom. In the forty-second H site, H(92) is bonded in a single-bond geometry to one C(83) atom. In the forty-third H site, H(93) is bonded in a single-bond geometry to one C(85) atom. In the forty-fourth H site, H(94,97,98) is bonded in a single-bond geometry to one C(88) atom. In the forty-fifth H site, H(95,99) is bonded in a single-bond geometry to one C(88) atom. In the forty-sixth H site, H(96) is bonded in a single-bond geometry to one C(88) atom. In the forty-seventh H site, H(100,102) is bonded in a single-bond geometry to one C(90) atom. In the forty-eighth H site, H(101) is bonded in a single-bond geometry to one C(90) atom. In the forty-ninth H site, H(103) is bonded in a single-bond geometry to one C(93) atom. In the fiftieth H site, H(104) is bonded in a single-bond geometry to one C(97) atom. In the fifty-first H site, H(105,106,107) is bonded in a single-bond geometry to one C(99) atom. In the fifty-second H site, H(108) is bonded in a single-bond geometry to one C(100) atom. In the fifty-third H site, H(109) is bonded in a single-bond geometry to one C(100) atom. In the fifty-fourth H site, H(110) is bonded in a single-bond geometry to one C(100) atom. In the fifty-fifth H site, H(111,112) is bonded in a single-bond geometry to one C(101) atom. In the fifty-sixth H site, H(113) is bonded in a single-bond geometry to one C(101) atom. In the fifty-seventh H site, H(114) is bonded in a single-bond geometry to one C(102) atom. In the fifty-eighth H site, H(115) is bonded in a single-bond geometry to one C(103) atom. In the fifty-ninth H site, H(124) is bonded in a single-bond geometry to one C(108) atom. In the sixtieth H site, H(125) is bonded in a single-bond geometry to one C(109) atom. In the sixty-first H site, H(126) is bonded in a single-bond geometry to one C(113) atom. In the sixty-second H site, H(127) is bonded in a single-bond geometry to one C(115) atom. In the sixty-third H site, H(128,129) is bonded in a single-bond geometry to one C(118) atom. In the sixty-fourth H site, H(130) is bonded in a single-bond geometry to one C(118) atom. In the sixty-fifth H site, H(131,132,133,135,136) is bonded in a single-bond geometry to one C(119) atom. In the sixty-sixth H site, H(134) is bonded in a single-bond geometry to one C(120) atom. In the sixty-seventh H site, H(137) is bonded in a single-bond geometry to one C(123) atom. In the sixty-eighth H site, H(138) is bonded in a single-bond geometry to one C(127) atom. In the sixty-ninth H site, H(139,140,141) is bonded in a single-bond geometry to one C(129) atom. In the seventieth H site, H(142,143) is bonded in a single-bond geometry to one C(130) atom. In the seventy-first H site, H(144) is bonded in a single-bond geometry to one C(130) atom. In the seventy-second H site, H(145) is bonded in a single-bond geometry to one C(131) atom. In the seventy-third H site, H(146,147) is bonded in a single-bond geometry to one C(131) atom. In the seventy-fourth H site, H(148) is bonded in a single-bond geometry to one C(132) atom. In the seventy-fifth H site, H(149) is bonded in a single-bond geometry to one C(133) atom. In the seventy-sixth H site, H(150) is bonded in a single-bond geometry to one C(134) atom. In the seventy-seventh H site, H(151) is bonded in a single-bond geometry to one C(134) atom. In the seventy-eighth H site, H(158) is bonded in a single-bond geometry to one C(138) atom. In the seventy-ninth H site, H(159) is bonded in a single-bond geometry to one C(139) atom. In the eightieth H site, H(160) is bonded in a single-bond geometry to one C(143) atom. In the eighty-first H site, H(161) is bonded in a single-bond geometry to one C(145) atom. In the eighty-second H site, H(162) is bonded in a single-bond geometry to one C(148) atom. In the eighty-third H site, H(163) is bonded in a single-bond geometry to one C(148) atom. In the eighty-fourth H site, H(164) is bonded in a single-bond geometry to one C(148) atom. In the eighty-fifth H site, H(165,166,167) is bonded in a single-bond geometry to one C(149) atom. In the eighty-sixth H site, H(168,169,170) is bonded in a single-bond geometry to one C(150) atom. In the eighty-seventh H site, H(171) is bonded in a single-bond geometry to one C(153) atom. In the eighty-eighth H site, H(172) is bonded in a single-bond geometry to one C(157) atom. In the eighty-ninth H site, H(173) is bonded in a single-bond geometry to one C(159) atom. In the ninetieth H site, H(174) is bonded in a single-bond geometry to one C(159) atom. In the ninety-first H site, H(175) is bonded in a single-bond geometry to one C(159) atom. In the ninety-second H site, H(176) is bonded in a single-bond geometry to one C(160) atom. In the ninety-third H site, H(177) is bonded in a single-bond geometry to one C(160) atom. In the ninety-fourth H site, H(178) is bonded in a single-bond geometry to one C(160) atom. In the ninety-fifth H site, H(179) is bonded in a single-bond geometry to one C(161) atom. In the ninety-sixth H site, H(180) is bonded in a single-bond geometry to one C(161) atom. In the ninety-seventh H site, H(181) is bonded in a single-bond geometry to one C(161) atom. In the ninety-eighth H site, H(182) is bonded in a single-bond geometry to one C(162) atom. In the ninety-ninth H site, H(183) is bonded in a single-bond geometry to one C(163) atom. In the one hundredth H site, H(192) is bonded in a single-bond geometry to one C(168) atom. In the one hundred and first H site, H(193) is bonded in a single-bond geometry to one C(169) atom. In the one hundred and second H site, H(194) is bonded in a single-bond geometry to one C(174) atom. In the one hundred and third H site, H(195) is bonded in a single-bond geometry to one C(176) atom. In the one hundred and fourth H site, H(196) is bonded in a single-bond geometry to one C(178) atom. In the one hundred and fifth H site, H(197) is bonded in a single-bond geometry to one C(178) atom. In the one hundred and sixth H site, H(198) is bonded in a single-bond geometry to one C(178) atom. In the one hundred and seventh H site, H(199,200,201) is bonded in a single-bond geometry to one C(179) atom. In the one hundred and eighth H site, H(202,203,204) is bonded in a single-bond geometry to one C(180) atom. There are thirty-six inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Mn(1), one Mn(2), and one C(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Mn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(4) and one C(5) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(4) and one C(22) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Mn(2) and one C(31) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(31) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Mn(5) and one C(35) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Mn(5) and one C(51) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mn(4) and one C(56) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(56) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(61) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(61) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Mn(6) and one C(65) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Mn(6) and one C(81) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Mn(9) and one C(86) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Mn(5) and one C(86) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Mn(2), one Mn(3), and one C(91) atom. In the eighteenth O site, O(18) is bonded in an L-shaped geometry to one Mn(3) and one C(91) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Mn(7) and one C(95) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Mn(7) and one C(111) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 150 degrees geometry to one Mn(3) and one C(116) atom. In the twenty-second O site, O(22) is bonded in a single-bond geometry to one C(116) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(121) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 150 degrees geometry to one Mn(2) and one C(121) atom. In the twenty-fifth O site, O(25) is bonded in a bent 120 degrees geometry to one Mn(8) and one C(125) atom. In the twenty-sixth O site, O(26) is bonded in a bent 120 degrees geometry to one Mn(8) and one C(141) atom. In the twenty-seventh O site, O(27) is bonded in a bent 150 degrees geometry to one Mn(7) and one C(146) atom. In the twenty-eighth O site, O(28) is bonded in a single-bond geometry to one C(146) atom. In the twenty-ninth O site, O(29) is bonded in a distorted bent 120 degrees geometry to one Mn(3) and one C(151) atom. In the thirtieth O site, O(30) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(151) atom. In the thirty-first O site, O(31) is bonded in a bent 120 degrees geometry to one Mn(9) and one C(155) atom. In the thirty-second O site, O(32) is bonded in a distorted bent 120 degrees geometry to one Mn(9) and one C(172) atom. In the thirty-third O site, O(33) is bonded in a distorted bent 120 degrees geometry to one Mn(6) and one C(170) atom. In the thirty-fourth O site, O(34) is bonded in a bent 150 degrees geometry to one Mn(8) and one C(170) atom. In the thirty-fifth O site, O(35) is bonded in a distorted linear geometry to one Mn(1) and one C(20) atom. In the thirty-sixth O site, O(36) is bonded in a single-bond geometry to one C(20) atom. Linkers: 1 CC(C)(C)c1cc(C([O])=O)cc(/C=N/[C@H]2CCCC[C@@H]2/N=C/c2cc(C(=O)O[Mn]345Oc6c(cc(C([O])=O)cc6C(C)(C)C)[CH]N3[C@H]3CCCC[C@@H]3N4[CH]c3cc(C([O])=O)cc(C(C)(C)C)c3O5)cc(C(C)(C)C)c2[O])c1[O] ,2 CC(C)(C)c1cc(C([O])=O)cc(/C=N/[C@H]2CCCC[C@@H]2/N=C/c2cc(C([O])=O)cc(C(C)(C)C)c2[O])c1[O] ,1 CC(C)(C)C1=CC(C([O])=O)=C[C](/C=N/[C@H]2CCCC[C@@H]2/N=C/c2cc(C([O])=O)cc(C(C)(C)C)c2[O])C1=O ,1 CC(C)(C)[C]1C=C(C([O])=O)C=C(/C=N/[C@H]2CCCC[C@@H]2/N=C/c2cc(C([O])=O)cc(C(C)(C)C)c2[O])C1=O. Metal clusters: 1 O=[C]O[Mn]12O[C]O[Mn]34(O[C]O1)(O[C]O2)O[C]O[Mn](O[C]=O)(O[C]O3)O[C]O4 ,1 [O][Mn]([O])O[C]=O ,2 [O][Mn]([O])O[C]O[Mn]([O])[O]. The MOF has largest included sphere 5.60 A, density 1.17 g/cm3, surface area 4784.04 m2/g, accessible volume 0.38 cm3/g