ZnC10NH10O4(CH)6C3H2(C5H5O)3 is Indium-derived structured and crystallizes in the orthorhombic Pbcn space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules, eight propylene molecules, eight schembl9685153 molecules, and eight ZnC10NH10O4 clusters. In each ZnC10NH10O4 cluster, Zn(1) is bonded in a trigonal non-coplanar geometry to one N(1), one O(3), and one O(7) atom. The Zn(1)-N(1) bond length is 2.07 Å. The Zn(1)-O(3) bond length is 1.96 Å. The Zn(1)-O(7) bond length is 1.97 Å. There are ten inequivalent C sites. In the first C site, C(8) is bonded in a distorted single-bond geometry to one C(13) and one H(3,13) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-H(3,13) bond length is 0.93 Å. In the second C site, C(9) is bonded in a bent 120 degrees geometry to one C(13), one O(3), and one O(6) atom. The C(9)-C(13) bond length is 1.49 Å. The C(9)-O(3) bond length is 1.28 Å. The C(9)-O(6) bond length is 1.23 Å. In the third C site, C(13) is bonded in a trigonal planar geometry to one C(17), one C(8), and one C(9) atom. The C(13)-C(17) bond length is 1.40 Å. In the fourth C site, C(17) is bonded in a distorted single-bond geometry to one C(13) and one H(3,13) atom. The C(17)-H(3,13) bond length is 0.93 Å. In the fifth C site, C(19) is bonded in a trigonal planar geometry to one C(20), one C(21), and one C(34) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-C(21) bond length is 1.38 Å. The C(19)-C(34) bond length is 1.50 Å. In the sixth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(15) atom. The C(20)-H(15) bond length is 0.93 Å. In the seventh C site, C(21) is bonded in a single-bond geometry to one C(19) and one H(16) atom. The C(21)-H(16) bond length is 0.93 Å. In the eighth C site, C(26) is bonded to one N(1); one H(25); and two equivalent H(24,26) atoms to form corner-sharing CH3N tetrahedra. The C(26)-N(1) bond length is 1.45 Å. The C(26)-H(25) bond length is 0.96 Å. Both C(26)-H(24,26) bond lengths are 0.96 Å. In the ninth C site, C(29) is bonded to one N(1); one H(28); and two equivalent H(29,30) atoms to form corner-sharing CH3N tetrahedra. The C(29)-N(1) bond length is 1.49 Å. The C(29)-H(28) bond length is 0.96 Å. Both C(29)-H(29,30) bond lengths are 0.96 Å. In the tenth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(5), and one O(7) atom. The C(34)-O(5) bond length is 1.26 Å. The C(34)-O(7) bond length is 1.25 Å. N(1) is bonded in a trigonal non-coplanar geometry to one Zn(1), one C(26), and one C(29) atom. There are seven inequivalent H sites. In the first H site, H(3,13) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the third H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the fourth H site, H(24,26) is bonded in a single-bond geometry to one C(26) atom. In the fifth H site, H(25) is bonded in a single-bond geometry to one C(26) atom. In the sixth H site, H(28) is bonded in a single-bond geometry to one C(29) atom. In the seventh H site, H(29,30) is bonded in a single-bond geometry to one C(29) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(9) atom. In the second O site, O(6) is bonded in a single-bond geometry to one C(9) atom. In the third O site, O(5) is bonded in a single-bond geometry to one C(34) atom. In the fourth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(34) atom. Linkers: 4 Cc1c(COc2cc[c]cc2)c(C)c(COc2ccc(C([O])=O)cc2)c(C)c1COc1ccc(C([O])=O)cc1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 7.85 A, density 0.85 g/cm3, surface area 5487.44 m2/g, accessible volume 0.68 cm3/g