C16H10CdN4O4(CH)2(C5H3)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules; two 1,3,5-triisopropenyl benzene molecules; and three C16H10CdN4O4 clusters. In one of the C16H10CdN4O4 clusters, Cd(2) is bonded in a square co-planar geometry to two equivalent N(3) and two equivalent O(1) atoms. Both Cd(2)-N(3) bond lengths are 2.27 Å. Both Cd(2)-O(1) bond lengths are 2.31 Å. There are eight inequivalent C sites. In the first C site, C(10) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(7) atom. The C(10)-N(3) bond length is 1.30 Å. The C(10)-N(4) bond length is 1.33 Å. The C(10)-H(7) bond length is 0.93 Å. In the second C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(8) atom. The C(11)-N(3) bond length is 1.37 Å. The C(11)-H(8) bond length is 0.93 Å. In the third C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(9) atom. The C(12)-N(4) bond length is 1.36 Å. The C(12)-H(9) bond length is 0.93 Å. In the fourth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(1), and one O(2) atom. The C(16)-C(17) bond length is 1.51 Å. The C(16)-O(1) bond length is 1.27 Å. The C(16)-O(2) bond length is 1.25 Å. In the fifth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(22) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(22) bond length is 1.39 Å. In the sixth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(13) atom. The C(18)-H(13) bond length is 0.93 Å. In the seventh C site, C(22) is bonded in a distorted single-bond geometry to one C(17) and one H(16) atom. The C(22)-H(16) bond length is 0.93 Å. In the eighth C site, C(4) is bonded in a distorted single-bond geometry to one N(4) atom. The C(4)-N(4) bond length is 1.43 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(10), and one C(11) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(4) atom. There are five inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cd(2) and one C(16) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(16) atom. In two of the C16H10CdN4O4 clusters, Cd(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(5), one O(3), one O(4), and one O(6) atom. The Cd(1)-N(1) bond length is 2.24 Å. The Cd(1)-N(5) bond length is 2.31 Å. The Cd(1)-O(3) bond length is 2.30 Å. The Cd(1)-O(4) bond length is 2.57 Å. The Cd(1)-O(6) bond length is 2.22 Å. There are sixteen inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one N(2) atom. The C(2)-N(2) bond length is 1.42 Å. In the second C site, C(6) is bonded in a distorted single-bond geometry to one N(6) atom. The C(6)-N(6) bond length is 1.43 Å. In the third C site, C(7) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(4) atom. The C(7)-N(1) bond length is 1.31 Å. The C(7)-N(2) bond length is 1.35 Å. The C(7)-H(4) bond length is 0.93 Å. In the fourth C site, C(8) is bonded in a 3-coordinate geometry to one C(9), one N(1), and one H(5) atom. The C(8)-C(9) bond length is 1.35 Å. The C(8)-N(1) bond length is 1.38 Å. The C(8)-H(5) bond length is 0.93 Å. In the fifth C site, C(9) is bonded in a 2-coordinate geometry to one C(8), one N(2), and one H(6) atom. The C(9)-N(2) bond length is 1.38 Å. The C(9)-H(6) bond length is 0.93 Å. In the sixth C site, C(13) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(10) atom. The C(13)-N(5) bond length is 1.31 Å. The C(13)-N(6) bond length is 1.36 Å. The C(13)-H(10) bond length is 0.93 Å. In the seventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(5), and one H(11) atom. The C(14)-C(15) bond length is 1.34 Å. The C(14)-N(5) bond length is 1.38 Å. The C(14)-H(11) bond length is 0.93 Å. In the eighth C site, C(15) is bonded in a 3-coordinate geometry to one C(14), one N(6), and one H(12) atom. The C(15)-N(6) bond length is 1.38 Å. The C(15)-H(12) bond length is 0.93 Å. In the ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(21) atom. The C(31)-C(32) bond length is 1.38 Å. The C(31)-H(21) bond length is 0.93 Å. In the tenth C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(35) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-C(35) bond length is 1.51 Å. In the eleventh C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(22) atom. The C(33)-H(22) bond length is 0.93 Å. In the twelfth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(3), and one O(4) atom. The C(35)-O(3) bond length is 1.25 Å. The C(35)-O(4) bond length is 1.25 Å. In the thirteenth C site, C(38) is bonded in a single-bond geometry to one C(39) and one H(25) atom. The C(38)-C(39) bond length is 1.38 Å. The C(38)-H(25) bond length is 0.93 Å. In the fourteenth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(42) atom. The C(39)-C(40) bond length is 1.38 Å. The C(39)-C(42) bond length is 1.51 Å. In the fifteenth C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one H(26) atom. The C(40)-H(26) bond length is 0.93 Å. In the sixteenth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(39), one O(5), and one O(6) atom. The C(42)-O(5) bond length is 1.24 Å. The C(42)-O(6) bond length is 1.25 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(7), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(7), and one C(9) atom. In the third N site, N(5) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(13), and one C(14) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(6) atom. There are ten inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(21) is bonded in a single-bond geometry to one C(31) atom. In the eighth H site, H(22) is bonded in a single-bond geometry to one C(33) atom. In the ninth H site, H(25) is bonded in a single-bond geometry to one C(38) atom. In the tenth H site, H(26) is bonded in a single-bond geometry to one C(40) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted water-like geometry to one Cd(1) and one C(35) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(35) atom. In the third O site, O(5) is bonded in a single-bond geometry to one C(42) atom. In the fourth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(42) atom. Linkers: 2 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C([O])=O)cc3)c2)cc1 ,2 c1cn(-c2cc(-n3ccnc3)cc(-n3ccnc3)c2)cn1. Metal clusters: 3 O=[C]O[Cd]O[C]=O. The MOF has largest included sphere 5.21 A, density 1.14 g/cm3, surface area 4671.19 m2/g, accessible volume 0.47 cm3/g