AgSi2H25(C6N)4AgSiH16(C4N)4SiC8H9(CH3)2(CH2)4 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight 02329_fluka molecules, four dimethyl-bis(prop-1-en-2-yl)silane molecules, four AgSi2H25(C6N)4 clusters, and four AgSiH16(C4N)4 clusters. In each AgSi2H25(C6N)4 cluster, Ag(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Ag(1)-N(1) bond length is 2.27 Å. The Ag(1)-N(2) bond length is 2.28 Å. The Ag(1)-N(3) bond length is 2.43 Å. The Ag(1)-N(4) bond length is 2.35 Å. There are two inequivalent Si sites. In the first Si site, Si(1) is bonded in a tetrahedral geometry to one C(11), one C(13), one C(3), and one C(6) atom. The Si(1)-C(11) bond length is 1.83 Å. The Si(1)-C(13) bond length is 1.84 Å. The Si(1)-C(3) bond length is 1.92 Å. The Si(1)-C(6) bond length is 1.93 Å. In the second Si site, Si(2) is bonded in a tetrahedral geometry to one C(16), one C(19), one C(24), and one C(25) atom. The Si(2)-C(16) bond length is 1.88 Å. The Si(2)-C(19) bond length is 1.88 Å. The Si(2)-C(24) bond length is 1.84 Å. The Si(2)-C(25) bond length is 1.84 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.26 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(4) atom. The C(5)-C(4) bond length is 1.34 Å. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.36 Å. The C(2)-H(2) bond length is 0.95 Å. In the fourth C site, C(3) is bonded in a trigonal planar geometry to one Si(1), one C(2), and one C(4) atom. The C(3)-C(4) bond length is 1.30 Å. In the fifth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(3) atom. The C(4)-H(3) bond length is 0.95 Å. In the sixth C site, C(10) is bonded in a distorted single-bond geometry to one C(6) and one H(8) atom. The C(10)-C(6) bond length is 1.39 Å. The C(10)-H(8) bond length is 0.95 Å. In the seventh C site, C(11) is bonded in a distorted water-like geometry to one Si(1) and two equivalent H(9,10) atoms. Both C(11)-H(9,10) bond lengths are 0.99 Å. In the eighth C site, C(13) is bonded in a distorted tetrahedral geometry to one Si(1); one H(16); and two equivalent H(14,15) atoms. The C(13)-H(16) bond length is 0.98 Å. Both C(13)-H(14,15) bond lengths are 0.98 Å. In the ninth C site, C(6) is bonded in a trigonal planar geometry to one Si(1), one C(10), and one C(7) atom. The C(6)-C(7) bond length is 1.39 Å. In the tenth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 0.95 Å. In the eleventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(14)-N(3) bond length is 1.30 Å. The C(14)-H(17) bond length is 0.95 Å. In the twelfth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(20) atom. The C(18)-N(3) bond length is 1.32 Å. The C(18)-H(20) bond length is 0.95 Å. In the thirteenth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(9)-N(2) bond length is 1.33 Å. The C(9)-H(7) bond length is 0.95 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(18) atom. The C(15)-C(16) bond length is 1.36 Å. The C(15)-H(18) bond length is 0.95 Å. In the fifteenth C site, C(16) is bonded in a trigonal planar geometry to one Si(2), one C(15), and one C(17) atom. The C(16)-C(17) bond length is 1.38 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(19) atom. The C(17)-H(19) bond length is 0.95 Å. In the seventeenth C site, C(19) is bonded in a trigonal planar geometry to one Si(2), one C(20), and one C(23) atom. The C(19)-C(20) bond length is 1.34 Å. The C(19)-C(23) bond length is 1.42 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(21) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(21) bond length is 0.95 Å. In the nineteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one N(4), and one H(22) atom. The C(21)-N(4) bond length is 1.35 Å. The C(21)-H(22) bond length is 0.95 Å. In the twentieth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(8)-N(2) bond length is 1.32 Å. The C(8)-H(6) bond length is 0.95 Å. In the twenty-first C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(23) atom. The C(22)-N(4) bond length is 1.33 Å. The C(22)-H(23) bond length is 0.95 Å. In the twenty-second C site, C(23) is bonded in a distorted single-bond geometry to one C(19) and one H(24) atom. The C(23)-H(24) bond length is 0.95 Å. In the twenty-third C site, C(24) is bonded in a distorted tetrahedral geometry to one Si(2) and two equivalent H(25,26) atoms. Both C(24)-H(25,26) bond lengths are 0.99 Å. In the twenty-fourth C site, C(25) is bonded in a 2-coordinate geometry to one Si(2) and two equivalent H(27,28) atoms. Both C(25)-H(27,28) bond lengths are 0.99 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(8), and one C(9) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(14), and one C(18) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(21), and one C(22) atom. There are twenty-one inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(14,15) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(27,28) is bonded in a single-bond geometry to one C(25) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(15) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the sixteenth H site, H(21) is bonded in a single-bond geometry to one C(20) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one C(21) atom. In the eighteenth H site, H(23) is bonded in a single-bond geometry to one C(22) atom. In the nineteenth H site, H(24) is bonded in a single-bond geometry to one C(23) atom. In the twentieth H site, H(25,26) is bonded in a single-bond geometry to one C(24) atom. In the twenty-first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In each AgSiH16(C4N)4 cluster, Ag(2) is bonded in a tetrahedral geometry to one N(5), one N(6), one N(7), and one N(8) atom. The Ag(2)-N(5) bond length is 2.30 Å. The Ag(2)-N(6) bond length is 2.39 Å. The Ag(2)-N(7) bond length is 2.30 Å. The Ag(2)-N(8) bond length is 2.26 Å. Si(3) is bonded in a tetrahedral geometry to one C(30), one C(33), one C(38), and one C(39) atom. The Si(3)-C(30) bond length is 1.86 Å. The Si(3)-C(33) bond length is 1.88 Å. The Si(3)-C(38) bond length is 1.83 Å. The Si(3)-C(39) bond length is 1.83 Å. There are sixteen inequivalent C sites. In the first C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(33) atom. The C(28)-N(5) bond length is 1.32 Å. The C(28)-H(33) bond length is 0.95 Å. In the second C site, C(29) is bonded in a distorted single-bond geometry to one C(30) and one H(34) atom. The C(29)-C(30) bond length is 1.38 Å. The C(29)-H(34) bond length is 0.95 Å. In the third C site, C(30) is bonded in a trigonal planar geometry to one Si(3), one C(29), and one C(31) atom. The C(30)-C(31) bond length is 1.38 Å. In the fourth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(35) atom. The C(31)-H(35) bond length is 0.95 Å. In the fifth C site, C(33) is bonded in a trigonal planar geometry to one Si(3), one C(34), and one C(37) atom. The C(33)-C(34) bond length is 1.36 Å. The C(33)-C(37) bond length is 1.33 Å. In the sixth C site, C(34) is bonded in a distorted single-bond geometry to one C(33) and one H(37) atom. The C(34)-H(37) bond length is 0.95 Å. In the seventh C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(38) atom. The C(35)-N(6) bond length is 1.32 Å. The C(35)-H(38) bond length is 0.95 Å. In the eighth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(37), one N(6), and one H(39) atom. The C(36)-C(37) bond length is 1.34 Å. The C(36)-N(6) bond length is 1.32 Å. The C(36)-H(39) bond length is 0.95 Å. In the ninth C site, C(37) is bonded in a distorted single-bond geometry to one C(33), one C(36), and one H(40) atom. The C(37)-H(40) bond length is 0.95 Å. In the tenth C site, C(38) is bonded in a 2-coordinate geometry to one Si(3) and two equivalent H(41,42) atoms. Both C(38)-H(41,42) bond lengths are 0.99 Å. In the eleventh C site, C(39) is bonded in a distorted water-like geometry to one Si(3) and two equivalent H(43,44) atoms. Both C(39)-H(43,44) bond lengths are 0.99 Å. In the twelfth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(36) atom. The C(32)-N(5) bond length is 1.34 Å. The C(32)-H(36) bond length is 0.95 Å. In the thirteenth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(49) atom. The C(42)-N(7) bond length is 1.31 Å. The C(42)-H(49) bond length is 0.95 Å. In the fourteenth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(52) atom. The C(46)-N(7) bond length is 1.34 Å. The C(46)-H(52) bond length is 0.95 Å. In the fifteenth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(54) atom. The C(49)-N(8) bond length is 1.29 Å. The C(49)-H(54) bond length is 0.95 Å. In the sixteenth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(55) atom. The C(50)-N(8) bond length is 1.38 Å. The C(50)-H(55) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one Ag(2), one C(28), and one C(32) atom. In the second N site, N(6) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(35), and one C(36) atom. In the third N site, N(7) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(42), and one C(46) atom. In the fourth N site, N(8) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(49), and one C(50) atom. There are fourteen inequivalent H sites. In the first H site, H(33) is bonded in a single-bond geometry to one C(28) atom. In the second H site, H(34) is bonded in a single-bond geometry to one C(29) atom. In the third H site, H(35) is bonded in a single-bond geometry to one C(31) atom. In the fourth H site, H(37) is bonded in a single-bond geometry to one C(34) atom. In the fifth H site, H(38) is bonded in a single-bond geometry to one C(35) atom. In the sixth H site, H(39) is bonded in a single-bond geometry to one C(36) atom. In the seventh H site, H(40) is bonded in a single-bond geometry to one C(37) atom. In the eighth H site, H(41,42) is bonded in a single-bond geometry to one C(38) atom. In the ninth H site, H(43,44) is bonded in a single-bond geometry to one C(39) atom. In the tenth H site, H(36) is bonded in a single-bond geometry to one C(32) atom. In the eleventh H site, H(49) is bonded in a single-bond geometry to one C(42) atom. In the twelfth H site, H(52) is bonded in a single-bond geometry to one C(46) atom. In the thirteenth H site, H(54) is bonded in a single-bond geometry to one C(49) atom. In the fourteenth H site, H(55) is bonded in a single-bond geometry to one C(50) atom. Linkers: 8 CC[Si](C)(c1ccncc1)c1ccncc1 ,8 c1cc([Si]2(c3ccncc3)CCCC2)ccn1. Metal clusters: 8 [Ag]. The MOF has largest included sphere 4.98 A, density 1.14 g/cm3, surface area 5234.20 m2/g, accessible volume 0.42 cm3/g