AgSiH16(C4N)4Si(CH)8(CH2)4 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, eight dimethyl-bis(prop-1-en-2-yl)silane molecules, and eight AgSiH16(C4N)4 clusters. In four of the AgSiH16(C4N)4 clusters, Ag(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Ag(1)-N(1) bond length is 2.29 Å. The Ag(1)-N(2) bond length is 2.41 Å. The Ag(1)-N(3) bond length is 2.31 Å. The Ag(1)-N(4) bond length is 2.28 Å. Si(1) is bonded in a tetrahedral geometry to one C(11), one C(14), one C(3), and one C(8) atom. The Si(1)-C(11) bond length is 1.87 Å. The Si(1)-C(14) bond length is 1.88 Å. The Si(1)-C(3) bond length is 1.88 Å. The Si(1)-C(8) bond length is 1.86 Å. There are sixteen inequivalent C sites. In the first C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5) atom. The C(6)-N(2) bond length is 1.32 Å. The C(6)-H(5) bond length is 0.95 Å. In the second C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-N(1) bond length is 1.36 Å. The C(1)-H(1) bond length is 0.95 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-H(2) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(3) bond length is 1.40 Å. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(3) bond length is 0.95 Å. In the fifth C site, C(3) is bonded in a trigonal planar geometry to one Si(1), one C(2), and one C(4) atom. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-C(8) bond length is 1.39 Å. The C(9)-H(7) bond length is 0.95 Å. In the seventh C site, C(11) is bonded in a distorted water-like geometry to one Si(1) and two equivalent H(9,10,15,16) atoms. Both C(11)-H(9,10,15,16) bond lengths are 0.99 Å. In the eighth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.32 Å. The C(5)-H(4) bond length is 0.95 Å. In the ninth C site, C(14) is bonded in a distorted water-like geometry to one Si(1) and two equivalent H(9,10,15,16) atoms. Both C(14)-H(9,10,15,16) bond lengths are 0.99 Å. In the tenth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(7)-C(8) bond length is 1.37 Å. The C(7)-H(6) bond length is 0.95 Å. In the eleventh C site, C(8) is bonded in a trigonal planar geometry to one Si(1), one C(7), and one C(9) atom. In the twelfth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(15)-N(3) bond length is 1.34 Å. The C(15)-H(17) bond length is 0.95 Å. In the thirteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(20) atom. The C(19)-N(3) bond length is 1.31 Å. The C(19)-H(20) bond length is 0.95 Å. In the fourteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(21) atom. The C(20)-N(4) bond length is 1.33 Å. The C(20)-H(21) bond length is 0.95 Å. In the fifteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(24) atom. The C(24)-N(4) bond length is 1.32 Å. The C(24)-H(24) bond length is 0.95 Å. In the sixteenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(10)-N(2) bond length is 1.32 Å. The C(10)-H(8) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(15), and one C(19) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(1), one C(20), and one C(24) atom. There are thirteen inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9,10,15,16) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(24) atom. In the thirteenth H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In four of the AgSiH16(C4N)4 clusters, Ag(2) is bonded in a tetrahedral geometry to one N(5), one N(6), one N(7), and one N(8) atom. The Ag(2)-N(5) bond length is 2.35 Å. The Ag(2)-N(6) bond length is 2.41 Å. The Ag(2)-N(7) bond length is 2.30 Å. The Ag(2)-N(8) bond length is 2.28 Å. Si(4) is bonded in a tetrahedral geometry to one C(45), one C(50), one C(53), and one C(56) atom. The Si(4)-C(45) bond length is 1.87 Å. The Si(4)-C(50) bond length is 1.87 Å. The Si(4)-C(53) bond length is 1.88 Å. The Si(4)-C(56) bond length is 1.87 Å. There are sixteen inequivalent C sites. In the first C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(33) atom. The C(29)-N(5) bond length is 1.35 Å. The C(29)-H(33) bond length is 0.95 Å. In the second C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(36) atom. The C(33)-N(5) bond length is 1.33 Å. The C(33)-H(36) bond length is 0.95 Å. In the third C site, C(34) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(37) atom. The C(34)-N(6) bond length is 1.35 Å. The C(34)-H(37) bond length is 0.95 Å. In the fourth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(40) atom. The C(38)-N(6) bond length is 1.33 Å. The C(38)-H(40) bond length is 0.95 Å. In the fifth C site, C(43) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(49) atom. The C(43)-N(7) bond length is 1.34 Å. The C(43)-H(49) bond length is 0.95 Å. In the sixth C site, C(44) is bonded in a distorted single-bond geometry to one C(45) and one H(50) atom. The C(44)-C(45) bond length is 1.39 Å. The C(44)-H(50) bond length is 0.95 Å. In the seventh C site, C(45) is bonded in a trigonal planar geometry to one Si(4), one C(44), and one C(46) atom. The C(45)-C(46) bond length is 1.41 Å. In the eighth C site, C(46) is bonded in a distorted single-bond geometry to one C(45) and one H(51) atom. The C(46)-H(51) bond length is 0.95 Å. In the ninth C site, C(47) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(52) atom. The C(47)-N(7) bond length is 1.32 Å. The C(47)-H(52) bond length is 0.95 Å. In the tenth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(53) atom. The C(48)-N(8) bond length is 1.33 Å. The C(48)-H(53) bond length is 0.95 Å. In the eleventh C site, C(49) is bonded in a distorted single-bond geometry to one C(50) and one H(54) atom. The C(49)-C(50) bond length is 1.37 Å. The C(49)-H(54) bond length is 0.95 Å. In the twelfth C site, C(50) is bonded in a distorted trigonal planar geometry to one Si(4), one C(49), and one C(51) atom. The C(50)-C(51) bond length is 1.37 Å. In the thirteenth C site, C(51) is bonded in a distorted trigonal planar geometry to one C(50), one C(52), and one H(55) atom. The C(51)-C(52) bond length is 1.38 Å. The C(51)-H(55) bond length is 0.95 Å. In the fourteenth C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(51), one N(8), and one H(56) atom. The C(52)-N(8) bond length is 1.30 Å. The C(52)-H(56) bond length is 0.95 Å. In the fifteenth C site, C(53) is bonded in a distorted water-like geometry to one Si(4) and two equivalent H(57,58) atoms. Both C(53)-H(57,58) bond lengths are 0.99 Å. In the sixteenth C site, C(56) is bonded in a distorted water-like geometry to one Si(4) and two equivalent H(63,64) atoms. Both C(56)-H(63,64) bond lengths are 0.99 Å. There are four inequivalent N sites. In the first N site, N(5) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(29), and one C(33) atom. In the second N site, N(7) is bonded in a trigonal planar geometry to one Ag(2), one C(43), and one C(47) atom. In the third N site, N(8) is bonded in a trigonal planar geometry to one Ag(2), one C(48), and one C(52) atom. In the fourth N site, N(6) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(34), and one C(38) atom. There are fourteen inequivalent H sites. In the first H site, H(33) is bonded in a single-bond geometry to one C(29) atom. In the second H site, H(36) is bonded in a single-bond geometry to one C(33) atom. In the third H site, H(37) is bonded in a single-bond geometry to one C(34) atom. In the fourth H site, H(40) is bonded in a single-bond geometry to one C(38) atom. In the fifth H site, H(49) is bonded in a single-bond geometry to one C(43) atom. In the sixth H site, H(50) is bonded in a single-bond geometry to one C(44) atom. In the seventh H site, H(51) is bonded in a single-bond geometry to one C(46) atom. In the eighth H site, H(52) is bonded in a single-bond geometry to one C(47) atom. In the ninth H site, H(53) is bonded in a single-bond geometry to one C(48) atom. In the tenth H site, H(54) is bonded in a single-bond geometry to one C(49) atom. In the eleventh H site, H(55) is bonded in a single-bond geometry to one C(51) atom. In the twelfth H site, H(56) is bonded in a single-bond geometry to one C(52) atom. In the thirteenth H site, H(57,58) is bonded in a single-bond geometry to one C(53) atom. In the fourteenth H site, H(63,64) is bonded in a single-bond geometry to one C(56) atom. Linkers: 16 c1cc([Si]2(c3ccncc3)CCCC2)ccn1. Metal clusters: 8 [Ag]. The MOF has largest included sphere 4.97 A, density 1.15 g/cm3, surface area 5215.07 m2/g, accessible volume 0.31 cm3/g