AgP2H16(C9N)2CH2(CH)14C6H5 is Indium-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of one hundred and twenty-eight 02329_fluka molecules; sixteen 02329_fluka molecules; sixteen methane;2-methylbuta-1,3-diene molecules; thirty-two propylene molecules; and sixteen AgP2H16(C9N)2 clusters. In each AgP2H16(C9N)2 cluster, Ag(1) is bonded in a distorted trigonal pyramidal geometry to one P(1), one P(2), one N(1), and one N(2) atom. The Ag(1)-P(1) bond length is 2.44 Å. The Ag(1)-P(2) bond length is 2.45 Å. The Ag(1)-N(1) bond length is 2.43 Å. The Ag(1)-N(2) bond length is 2.37 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one P(2) and two equivalent H(1,2) atoms. The C(1)-P(2) bond length is 1.83 Å. Both C(1)-H(1,2) bond lengths are 0.99 Å. In the second C site, C(3) is bonded in a distorted water-like geometry to one P(1) and two equivalent H(5,6) atoms. The C(3)-P(1) bond length is 1.81 Å. Both C(3)-H(5,6) bond lengths are 0.99 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(7) atom. The C(4)-N(1) bond length is 1.41 Å. The C(4)-H(7) bond length is 0.95 Å. In the fourth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(11) atom. The C(8)-N(1) bond length is 1.34 Å. The C(8)-H(11) bond length is 0.95 Å. In the fifth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(9)-N(2) bond length is 1.27 Å. The C(9)-H(12) bond length is 0.95 Å. In the sixth C site, C(13) is bonded in a 2-coordinate geometry to one N(2) and one H(15) atom. The C(13)-N(2) bond length is 1.36 Å. The C(13)-H(15) bond length is 0.95 Å. In the seventh C site, C(16) is bonded in a trigonal planar geometry to one C(17), one C(21), and one P(2) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-C(21) bond length is 1.39 Å. The C(16)-P(2) bond length is 1.85 Å. In the eighth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(18,22,23) atom. The C(17)-H(18,22,23) bond length is 0.95 Å. In the ninth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(18,22,23) atom. The C(21)-H(18,22,23) bond length is 0.95 Å. In the tenth C site, C(22) is bonded in a trigonal planar geometry to one C(23), one C(27), and one P(1) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-C(27) bond length is 1.39 Å. The C(22)-P(1) bond length is 1.85 Å. In the eleventh C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(18,22,23) atom. The C(23)-H(18,22,23) bond length is 0.95 Å. In the twelfth C site, C(27) is bonded in a distorted single-bond geometry to one C(22) and one H(27) atom. The C(27)-H(27) bond length is 0.95 Å. In the thirteenth C site, C(28) is bonded in a trigonal planar geometry to one C(29), one C(33), and one P(1) atom. The C(28)-C(29) bond length is 1.39 Å. The C(28)-C(33) bond length is 1.39 Å. The C(28)-P(1) bond length is 1.81 Å. In the fourteenth C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(28) atom. The C(29)-H(28) bond length is 0.95 Å. In the fifteenth C site, C(33) is bonded in a distorted single-bond geometry to one C(28) and one H(32) atom. The C(33)-H(32) bond length is 0.95 Å. In the sixteenth C site, C(34) is bonded in a trigonal planar geometry to one C(35), one C(39), and one P(2) atom. The C(34)-C(35) bond length is 1.39 Å. The C(34)-C(39) bond length is 1.39 Å. The C(34)-P(2) bond length is 1.78 Å. In the seventeenth C site, C(35) is bonded in a distorted single-bond geometry to one C(34) and one H(33,37) atom. The C(35)-H(33,37) bond length is 0.95 Å. In the eighteenth C site, C(39) is bonded in a distorted single-bond geometry to one C(34) and one H(33,37) atom. The C(39)-H(33,37) bond length is 0.95 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one Ag(1), one C(22), one C(28), and one C(3) atom to form distorted corner-sharing PAgC3 tetrahedra. In the second P site, P(2) is bonded to one Ag(1), one C(1), one C(16), and one C(34) atom to form distorted corner-sharing PAgC3 tetrahedra. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(4), and one C(8) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(13), and one C(9) atom. There are eleven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(5,6) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(18,22,23) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(27) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(28) is bonded in a single-bond geometry to one C(29) atom. In the tenth H site, H(32) is bonded in a single-bond geometry to one C(33) atom. In the eleventh H site, H(33,37) is bonded in a single-bond geometry to one C(35) atom. Linkers: 16 C=Cc1ccncc1.[c]1ccncc1. Metal clusters: 16 [Ag]. The MOF has largest included sphere 5.39 A, density 1.07 g/cm3, surface area 5376.61 m2/g, accessible volume 0.37 cm3/g