AgH24(C6N)4 is Indium-like structured and crystallizes in the orthorhombic Pnnn space group. The structure is zero-dimensional and consists of two AgH24(C6N)4 clusters. Ag(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. All Ag(1)-N(1) bond lengths are 2.32 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-C(6) bond length is 1.49 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.36 Å. The C(4)-H(3) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.32 Å. The C(5)-H(4) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one C(3), one H(5), and one H(6) atom. The C(6)-H(5) bond length is 0.95 Å. The C(6)-H(6) bond length is 0.90 Å. N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. Linkers: 5 c1cc(CCc2ccncc2)ccn1. Metal clusters: 2 [Ag]. The MOF has largest included sphere 4.94 A, density 1.27 g/cm3, surface area 4820.87 m2/g, accessible volume 0.34 cm3/g