AgZnC29N6H15(CH)3 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules and four AgZnC29N6H15 clusters. In each AgZnC29N6H15 cluster, Ag(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one N(6) atom. The Ag(1)-N(1) bond length is 2.26 Å. The Ag(1)-N(6) bond length is 2.34 Å. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted tetrahedral geometry to two equivalent N(2) and two equivalent N(3) atoms. Both Zn(1)-N(2) bond lengths are 1.98 Å. Both Zn(1)-N(3) bond lengths are 2.00 Å. In the second Zn site, Zn(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent N(4) and two equivalent N(5) atoms. Both Zn(2)-N(4) bond lengths are 2.01 Å. Both Zn(2)-N(5) bond lengths are 1.99 Å. There are twenty-nine inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one C(2) and one N(1) atom. The C(1)-C(2) bond length is 1.43 Å. The C(1)-N(1) bond length is 1.13 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(4) bond length is 1.41 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(5), and one H(1) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(3) atom. The C(5)-C(7) bond length is 1.41 Å. The C(5)-H(3) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a single-bond geometry to one C(7) and one H(4) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(4) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(8) atom. The C(7)-C(8) bond length is 1.49 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.42 Å. The C(8)-C(9) bond length is 1.38 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(11), one C(8), and one N(2) atom. The C(9)-C(11) bond length is 1.44 Å. The C(9)-N(2) bond length is 1.42 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one N(3) atom. The C(10)-N(3) bond length is 1.38 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(11)-H(5) bond length is 0.93 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(14)-N(2) bond length is 1.33 Å. The C(14)-H(8) bond length is 0.93 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(9) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(9) bond length is 0.93 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(18), and one N(3) atom. The C(16)-C(18) bond length is 1.45 Å. The C(16)-N(3) bond length is 1.36 Å. In the fifteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(16), one C(21), and one N(4) atom. The C(18)-C(21) bond length is 1.42 Å. The C(18)-N(4) bond length is 1.35 Å. In the sixteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(22) and one H(11) atom. The C(19)-C(22) bond length is 1.43 Å. The C(19)-H(11) bond length is 0.93 Å. In the seventeenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(12) atom. The C(20)-N(5) bond length is 1.34 Å. The C(20)-H(12) bond length is 0.93 Å. In the eighteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(18) and one H(13) atom. The C(21)-H(13) bond length is 0.93 Å. In the nineteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(19), one C(25), and one N(5) atom. The C(22)-C(25) bond length is 1.41 Å. The C(22)-N(5) bond length is 1.39 Å. In the twentieth C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(14) atom. The C(23)-C(24) bond length is 1.43 Å. The C(23)-H(14) bond length is 0.93 Å. In the twenty-first C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one N(4) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-N(4) bond length is 1.41 Å. In the twenty-second C site, C(25) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(26) atom. The C(25)-C(26) bond length is 1.48 Å. In the twenty-third C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(28) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-C(28) bond length is 1.39 Å. In the twenty-fourth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(15) atom. The C(27)-H(15) bond length is 0.93 Å. In the twenty-fifth C site, C(28) is bonded in a distorted single-bond geometry to one C(26) and one H(16) atom. The C(28)-H(16) bond length is 0.93 Å. In the twenty-sixth C site, C(29) is bonded in a distorted single-bond geometry to one C(31) and one H(17) atom. The C(29)-C(31) bond length is 1.39 Å. The C(29)-H(17) bond length is 0.93 Å. In the twenty-seventh C site, C(30) is bonded in a distorted single-bond geometry to one C(31) and one H(18) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-H(18) bond length is 0.93 Å. In the twenty-eighth C site, C(31) is bonded in a trigonal planar geometry to one C(29), one C(30), and one C(32) atom. The C(31)-C(32) bond length is 1.43 Å. In the twenty-ninth C site, C(32) is bonded in a linear geometry to one C(31) and one N(6) atom. The C(32)-N(6) bond length is 1.16 Å. There are six inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(14), and one C(9) atom. In the second N site, N(1) is bonded in a linear geometry to one Ag(1) and one C(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(16) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(2), one C(18), and one C(24) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(2), one C(20), and one C(22) atom. In the sixth N site, N(6) is bonded in a bent 150 degrees geometry to one Ag(1) and one C(32) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(27) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(28) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(29) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. Linkers: 1 N#Cc1ccc([C](C2=C[CH]C([C]3C=CC(/C(=C4/C=CC=N4)c4ccc(C#N)cc4)=N3)=N2)C2=NC=C[CH]2)cc1 ,1 N#Cc1ccc([C](C2=CC=C(C3=CC=C([C](C4=NC=C[CH]4)c4ccc(C#N)cc4)[N]3)[N]2)C2=C[CH]C=N2)cc1 ,1 N#Cc1ccc([C](C2=CC=C(C3=N[C]([C](C4=NC=C[CH]4)c4ccc(C#N)cc4)C=C3)[N]2)C2=C[CH]C=N2)cc1 ,1 N#Cc1ccc([C](C2=C[CH]C(C3=NC(/C(=C4/C=CC=N4)c4ccc(C#N)cc4)=C[CH]3)=N2)C2=NC=C[CH]2)cc1 ,1 N#Cc1ccc(/C(C2=C[CH]C([C]3C=CC(/C(=C4/C=CC=N4)c4ccc(C#N)cc4)=N3)=N2)=C2\C=CC=N2)cc1 ,1 N#Cc1ccc([C]([C]2C=CC([C]3C=CC([C](C4=N[CH]C=C4)c4ccc(C#N)cc4)=N3)=N2)C2=N[CH]C=C2)cc1 ,1 N#Cc1ccc(/C(C2=NC=C[CH]2)=C2\C=CC([C]3C=CC(/C(=C4/C=CC=N4)c4ccc(C#N)cc4)=N3)=N2)cc1 ,1 N#Cc1ccc([C](C2=CC=C(C3=CC=C([C](C4=N[CH]C=C4)c4ccc(C#N)cc4)[N]3)[N]2)C2=NC=C[CH]2)cc1. Metal clusters: 8 [Zn] ,8 [Ag]. The MOF has largest included sphere 7.21 A, density 0.87 g/cm3, surface area 4209.82 m2/g, accessible volume 0.71 cm3/g