CuC13N12H18CuH16(CN)12CuC10N9H14(CH2)20 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of one hundred and sixty 02329_fluka molecules, eight CuC10N9H14 clusters, eight CuC13N12H18 clusters, and eight CuH16(CN)12 clusters. In each CuC10N9H14 cluster, Cu(3) is bonded in a T-shaped geometry to one N(12), one N(24), and one N(25) atom. The Cu(3)-N(12) bond length is 1.97 Å. The Cu(3)-N(24) bond length is 1.95 Å. The Cu(3)-N(25) bond length is 2.01 Å. There are ten inequivalent C sites. In the first C site, C(41) is bonded in a trigonal planar geometry to one N(25), one N(27), and one H(65) atom. The C(41)-N(25) bond length is 1.35 Å. The C(41)-N(27) bond length is 1.31 Å. The C(41)-H(65) bond length is 0.95 Å. In the second C site, C(42) is bonded in a trigonal planar geometry to one N(25), one N(26), and one H(66) atom. The C(42)-N(25) bond length is 1.32 Å. The C(42)-N(26) bond length is 1.33 Å. The C(42)-H(66) bond length is 0.95 Å. In the third C site, C(43) is bonded in a 3-coordinate geometry to one N(26), one H(67), and one H(68) atom. The C(43)-N(26) bond length is 1.48 Å. The C(43)-H(67) bond length is 0.99 Å. The C(43)-H(68) bond length is 0.99 Å. In the fourth C site, C(17) is bonded in a water-like geometry to one C(18) and two equivalent H(27,28) atoms. The C(17)-C(18) bond length is 1.47 Å. Both C(17)-H(27,28) bond lengths are 0.99 Å. In the fifth C site, C(18) is bonded in a 4-coordinate geometry to one C(17), one N(10), one H(29), and one H(30) atom. The C(18)-N(10) bond length is 1.48 Å. The C(18)-H(29) bond length is 0.99 Å. The C(18)-H(30) bond length is 0.99 Å. In the sixth C site, C(19) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(31) atom. The C(19)-N(10) bond length is 1.29 Å. The C(19)-N(12) bond length is 1.32 Å. The C(19)-H(31) bond length is 0.95 Å. In the seventh C site, C(20) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(32) atom. The C(20)-N(11) bond length is 1.32 Å. The C(20)-N(12) bond length is 1.35 Å. The C(20)-H(32) bond length is 0.95 Å. In the eighth C site, C(38) is bonded in a 3-coordinate geometry to one N(22) and two equivalent H(61,62) atoms. The C(38)-N(22) bond length is 1.44 Å. Both C(38)-H(61,62) bond lengths are 0.99 Å. In the ninth C site, C(39) is bonded in a trigonal planar geometry to one N(23), one N(24), and one H(63) atom. The C(39)-N(23) bond length is 1.25 Å. The C(39)-N(24) bond length is 1.35 Å. The C(39)-H(63) bond length is 0.95 Å. In the tenth C site, C(40) is bonded in a trigonal planar geometry to one N(22), one N(24), and one H(64) atom. The C(40)-N(22) bond length is 1.31 Å. The C(40)-N(24) bond length is 1.32 Å. The C(40)-H(64) bond length is 0.95 Å. There are nine inequivalent N sites. In the first N site, N(10) is bonded in a 3-coordinate geometry to one C(18), one C(19), and one N(11) atom. The N(10)-N(11) bond length is 1.36 Å. In the second N site, N(11) is bonded in a distorted water-like geometry to one C(20) and one N(10) atom. In the third N site, N(12) is bonded in a distorted trigonal planar geometry to one Cu(3), one C(19), and one C(20) atom. In the fourth N site, N(22) is bonded in a distorted bent 120 degrees geometry to one C(38), one C(40), and one N(23) atom. The N(22)-N(23) bond length is 1.35 Å. In the fifth N site, N(23) is bonded in a distorted water-like geometry to one C(39) and one N(22) atom. In the sixth N site, N(24) is bonded in a distorted trigonal planar geometry to one Cu(3), one C(39), and one C(40) atom. In the seventh N site, N(25) is bonded in a distorted trigonal planar geometry to one Cu(3), one C(41), and one C(42) atom. In the eighth N site, N(26) is bonded in a distorted trigonal planar geometry to one C(42), one C(43), and one N(27) atom. The N(26)-N(27) bond length is 1.32 Å. In the ninth N site, N(27) is bonded in a water-like geometry to one C(41) and one N(26) atom. There are twelve inequivalent H sites. In the first H site, H(27,28) is bonded in a single-bond geometry to one C(17) atom. In the second H site, H(29) is bonded in a single-bond geometry to one C(18) atom. In the third H site, H(30) is bonded in a single-bond geometry to one C(18) atom. In the fourth H site, H(31) is bonded in a single-bond geometry to one C(19) atom. In the fifth H site, H(32) is bonded in a single-bond geometry to one C(20) atom. In the sixth H site, H(61,62) is bonded in a single-bond geometry to one C(38) atom. In the seventh H site, H(63) is bonded in a single-bond geometry to one C(39) atom. In the eighth H site, H(64) is bonded in a single-bond geometry to one C(40) atom. In the ninth H site, H(65) is bonded in a single-bond geometry to one C(41) atom. In the tenth H site, H(66) is bonded in a single-bond geometry to one C(42) atom. In the eleventh H site, H(67) is bonded in a single-bond geometry to one C(43) atom. In the twelfth H site, H(68) is bonded in a single-bond geometry to one C(43) atom. In each CuC13N12H18 cluster, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(13), one N(6), and one N(7) atom. The Cu(1)-N(1) bond length is 2.00 Å. The Cu(1)-N(13) bond length is 2.00 Å. The Cu(1)-N(6) bond length is 2.01 Å. The Cu(1)-N(7) bond length is 1.97 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-N(3) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(2) atom. The C(2)-N(1) bond length is 1.29 Å. The C(2)-N(2) bond length is 1.25 Å. The C(2)-H(2) bond length is 0.95 Å. In the third C site, C(3) is bonded in a 3-coordinate geometry to one N(3), one H(3), and one H(4) atom. The C(3)-N(3) bond length is 1.48 Å. The C(3)-H(3) bond length is 0.99 Å. The C(3)-H(4) bond length is 0.99 Å. In the fourth C site, C(8) is bonded in a 3-coordinate geometry to one N(5) and two equivalent H(13,14) atoms. The C(8)-N(5) bond length is 1.45 Å. Both C(8)-H(13,14) bond lengths are 0.99 Å. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(15) atom. The C(9)-N(4) bond length is 1.30 Å. The C(9)-N(6) bond length is 1.35 Å. The C(9)-H(15) bond length is 0.95 Å. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(16) atom. The C(10)-N(5) bond length is 1.31 Å. The C(10)-N(6) bond length is 1.33 Å. The C(10)-H(16) bond length is 0.95 Å. In the seventh C site, C(11) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(17) atom. The C(11)-N(7) bond length is 1.24 Å. The C(11)-N(9) bond length is 1.41 Å. The C(11)-H(17) bond length is 0.95 Å. In the eighth C site, C(12) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(18) atom. The C(12)-N(7) bond length is 1.44 Å. The C(12)-N(8) bond length is 1.33 Å. The C(12)-H(18) bond length is 0.95 Å. In the ninth C site, C(13) is bonded in a 4-coordinate geometry to one C(14), one N(9), one H(19), and one H(20) atom. The C(13)-C(14) bond length is 1.42 Å. The C(13)-N(9) bond length is 1.48 Å. The C(13)-H(19) bond length is 0.99 Å. The C(13)-H(20) bond length is 0.99 Å. In the tenth C site, C(14) is bonded in a distorted water-like geometry to one C(13), one H(21), and one H(22) atom. The C(14)-H(21) bond length is 0.99 Å. The C(14)-H(22) bond length is 0.99 Å. In the eleventh C site, C(21) is bonded in a trigonal planar geometry to one N(13), one N(14), and one H(33) atom. The C(21)-N(13) bond length is 1.42 Å. The C(21)-N(14) bond length is 1.30 Å. The C(21)-H(33) bond length is 0.95 Å. In the twelfth C site, C(22) is bonded in a trigonal planar geometry to one N(13), one N(15), and one H(34) atom. The C(22)-N(13) bond length is 1.32 Å. The C(22)-N(15) bond length is 1.32 Å. The C(22)-H(34) bond length is 0.95 Å. In the thirteenth C site, C(23) is bonded in a 3-coordinate geometry to one N(15) and two equivalent H(35,36) atoms. The C(23)-N(15) bond length is 1.44 Å. Both C(23)-H(35,36) bond lengths are 0.99 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(2) and one N(3) atom. The N(2)-N(3) bond length is 1.36 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one C(1), one C(3), and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted water-like geometry to one C(9) and one N(5) atom. The N(4)-N(5) bond length is 1.38 Å. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one C(10), one C(8), and one N(4) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(10), and one C(9) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(11), and one C(12) atom. In the eighth N site, N(8) is bonded in a water-like geometry to one C(12) and one N(9) atom. The N(8)-N(9) bond length is 1.22 Å. In the ninth N site, N(9) is bonded in a 3-coordinate geometry to one C(11), one C(13), and one N(8) atom. In the tenth N site, N(13) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(21), and one C(22) atom. In the eleventh N site, N(14) is bonded in a water-like geometry to one C(21) and one N(15) atom. The N(14)-N(15) bond length is 1.35 Å. In the twelfth N site, N(15) is bonded in a 2-coordinate geometry to one C(22), one C(23), and one N(14) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(13,14) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(14) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(33) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(34) is bonded in a single-bond geometry to one C(22) atom. In the sixteenth H site, H(35,36) is bonded in a single-bond geometry to one C(23) atom. In each CuH16(CN)12 cluster, Cu(2) is bonded in a rectangular see-saw-like geometry to one N(18), one N(19), one N(29), and one N(31) atom. The Cu(2)-N(18) bond length is 2.01 Å. The Cu(2)-N(19) bond length is 2.02 Å. The Cu(2)-N(29) bond length is 2.00 Å. The Cu(2)-N(31) bond length is 1.99 Å. There are twelve inequivalent C sites. In the first C site, C(48) is bonded in a 3-coordinate geometry to one N(30) and two equivalent H(77,78) atoms. The C(48)-N(30) bond length is 1.48 Å. Both C(48)-H(77,78) bond lengths are 0.99 Å. In the second C site, C(49) is bonded in a trigonal planar geometry to one N(29), one N(30), and one H(79) atom. The C(49)-N(29) bond length is 1.34 Å. The C(49)-N(30) bond length is 1.34 Å. The C(49)-H(79) bond length is 0.95 Å. In the third C site, C(50) is bonded in a trigonal planar geometry to one N(28), one N(29), and one H(80) atom. The C(50)-N(28) bond length is 1.34 Å. The C(50)-N(29) bond length is 1.35 Å. The C(50)-H(80) bond length is 0.95 Å. In the fourth C site, C(51) is bonded in a trigonal planar geometry to one N(31), one N(32), and one H(81) atom. The C(51)-N(31) bond length is 1.39 Å. The C(51)-N(32) bond length is 1.28 Å. The C(51)-H(81) bond length is 0.95 Å. In the fifth C site, C(52) is bonded in a trigonal planar geometry to one N(31), one N(33), and one H(82) atom. The C(52)-N(31) bond length is 1.34 Å. The C(52)-N(33) bond length is 1.32 Å. The C(52)-H(82) bond length is 0.95 Å. In the sixth C site, C(53) is bonded in a 3-coordinate geometry to one N(33) and two equivalent H(83,84) atoms. The C(53)-N(33) bond length is 1.50 Å. Both C(53)-H(83,84) bond lengths are 0.99 Å. In the seventh C site, C(28) is bonded in a 3-coordinate geometry to one N(17), one H(45), and one H(46) atom. The C(28)-N(17) bond length is 1.50 Å. The C(28)-H(45) bond length is 0.99 Å. The C(28)-H(46) bond length is 0.99 Å. In the eighth C site, C(29) is bonded in a trigonal planar geometry to one N(17), one N(18), and one H(47) atom. The C(29)-N(17) bond length is 1.31 Å. The C(29)-N(18) bond length is 1.34 Å. The C(29)-H(47) bond length is 0.95 Å. In the ninth C site, C(30) is bonded in a trigonal planar geometry to one N(16), one N(18), and one H(48) atom. The C(30)-N(16) bond length is 1.35 Å. The C(30)-N(18) bond length is 1.36 Å. The C(30)-H(48) bond length is 0.95 Å. In the tenth C site, C(31) is bonded in a trigonal planar geometry to one N(19), one N(20), and one H(49) atom. The C(31)-N(19) bond length is 1.39 Å. The C(31)-N(20) bond length is 1.28 Å. The C(31)-H(49) bond length is 0.95 Å. In the eleventh C site, C(32) is bonded in a trigonal planar geometry to one N(19), one N(21), and one H(50) atom. The C(32)-N(19) bond length is 1.31 Å. The C(32)-N(21) bond length is 1.34 Å. The C(32)-H(50) bond length is 0.95 Å. In the twelfth C site, C(33) is bonded in a 3-coordinate geometry to one N(21), one H(51), and one H(52) atom. The C(33)-N(21) bond length is 1.49 Å. The C(33)-H(51) bond length is 0.99 Å. The C(33)-H(52) bond length is 0.99 Å. There are twelve inequivalent N sites. In the first N site, N(16) is bonded in a water-like geometry to one C(30) and one N(17) atom. The N(16)-N(17) bond length is 1.32 Å. In the second N site, N(17) is bonded in a distorted trigonal planar geometry to one C(28), one C(29), and one N(16) atom. In the third N site, N(18) is bonded in a trigonal planar geometry to one Cu(2), one C(29), and one C(30) atom. In the fourth N site, N(19) is bonded in a trigonal planar geometry to one Cu(2), one C(31), and one C(32) atom. In the fifth N site, N(20) is bonded in a distorted water-like geometry to one C(31) and one N(21) atom. The N(20)-N(21) bond length is 1.32 Å. In the sixth N site, N(21) is bonded in a 2-coordinate geometry to one C(32), one C(33), and one N(20) atom. In the seventh N site, N(28) is bonded in a water-like geometry to one C(50) and one N(30) atom. The N(28)-N(30) bond length is 1.31 Å. In the eighth N site, N(29) is bonded in a trigonal planar geometry to one Cu(2), one C(49), and one C(50) atom. In the ninth N site, N(30) is bonded in a distorted trigonal planar geometry to one C(48), one C(49), and one N(28) atom. In the tenth N site, N(31) is bonded in a trigonal planar geometry to one Cu(2), one C(51), and one C(52) atom. In the eleventh N site, N(32) is bonded in a distorted water-like geometry to one C(51) and one N(33) atom. The N(32)-N(33) bond length is 1.38 Å. In the twelfth N site, N(33) is bonded in a distorted trigonal planar geometry to one C(52), one C(53), and one N(32) atom. There are fourteen inequivalent H sites. In the first H site, H(45) is bonded in a single-bond geometry to one C(28) atom. In the second H site, H(46) is bonded in a single-bond geometry to one C(28) atom. In the third H site, H(47) is bonded in a single-bond geometry to one C(29) atom. In the fourth H site, H(48) is bonded in a single-bond geometry to one C(30) atom. In the fifth H site, H(49) is bonded in a single-bond geometry to one C(31) atom. In the sixth H site, H(50) is bonded in a single-bond geometry to one C(32) atom. In the seventh H site, H(51) is bonded in a single-bond geometry to one C(33) atom. In the eighth H site, H(52) is bonded in a single-bond geometry to one C(33) atom. In the ninth H site, H(77,78) is bonded in a single-bond geometry to one C(48) atom. In the tenth H site, H(79) is bonded in a single-bond geometry to one C(49) atom. In the eleventh H site, H(80) is bonded in a single-bond geometry to one C(50) atom. In the twelfth H site, H(81) is bonded in a single-bond geometry to one C(51) atom. In the thirteenth H site, H(82) is bonded in a single-bond geometry to one C(52) atom. In the fourteenth H site, H(83,84) is bonded in a single-bond geometry to one C(53) atom. Linkers: 15 [CH]1N=C[N]N1CCCCCCn1cncn1 ,6 [CH]1N=C[N]N1CCCCCCN1[CH]N=C[N]1 ,1 c1ncn(CCCCCCn2cncn2)n1. Metal clusters: 12 [Cu]. The MOF has largest included sphere 10.54 A, density 0.80 g/cm3, surface area 5628.10 m2/g, accessible volume 0.69 cm3/g