CuC7H4(NO)2(C3H2)2(CH3)2 is Indium-derived structured and crystallizes in the tetragonal P4_2/nbc space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules; eight 2,3-dimethyl-1,3-butadiene molecules; and four CuC7H4(NO)2 clusters. In each CuC7H4(NO)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 2.01 Å. Both Cu(1)-O(1) bond lengths are 1.91 Å. There are four inequivalent C sites. In the first C site, C(8) is bonded in a trigonal planar geometry to one C(8) and two equivalent C(6) atoms. The C(8)-C(8) bond length is 1.52 Å. Both C(8)-C(6) bond lengths are 1.38 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.93 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(4) bond length is 0.93 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(8) and one O(1) atom. The C(6)-O(1) bond length is 1.30 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(6) atom. Linkers: 2 C[C]1O[Cu@](N2[CH]C=C(c3c[c]ncc3)C=C2)(N2[CH]C=C(c3ccncc3)C=C2)OC(C)=C1C1=C(C)O[Cu@@](N2[CH]C=C(c3c[c]ncc3)C=C2)(N2[CH]C=C(c3ccncc3)C=C2)O[C]1C ,2 C[C]1O[Cu](N2[CH]C=C(c3ccncc3)C=C2)(N2[CH]C=C(c3ccncc3)C=C2)OC(C)=C1C1=C(C)O[Cu](N2[CH]C=C(c3ccncc3)C=C2)(N2[CH]C=C(c3ccncc3)C=C2)O[C]1C ,2 C[C]1O[Cu@@](N2[CH]C=C(c3c[c]ncc3)C=C2)(N2[CH]C=C(c3ccncc3)C=C2)OC(C)=C1C1=C(C)O[Cu@](N2[CH]C=C(c3c[c]ncc3)C=C2)(N2[CH]C=C(c3ccncc3)C=C2)O[C]1C ,2 C[C]([O])C(=C(/C)[O])/C([C](C)[O])=C(\C)[O]. Metal clusters: 4 [Cu]. The MOF has largest included sphere 5.55 A, density 0.81 g/cm3, surface area 4877.06 m2/g, accessible volume 0.71 cm3/g