WCu6C32H24S4(N6Br)4 crystallizes in the cubic I-43d space group. W(1) is bonded in a 10-coordinate geometry to two equivalent Cu(2), four equivalent Cu(1), and four equivalent S(1) atoms. Both W(1)-Cu(2) bond lengths are 2.67 Å. All W(1)-Cu(1) bond lengths are 2.72 Å. All W(1)-S(1) bond lengths are 2.27 Å. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 4-coordinate geometry to one W(1), one N(1), two equivalent S(1), and one Br(1) atom. The Cu(1)-N(1) bond length is 2.01 Å. There is one shorter (2.30 Å) and one longer (2.33 Å) Cu(1)-S(1) bond length. The Cu(1)-Br(1) bond length is 2.42 Å. In the second Cu site, Cu(2) is bonded to one W(1), two equivalent N(4), and two equivalent S(1) atoms to form distorted CuWS2N2 tetrahedra that share  a cornercorner with one Cu(2)WS2N2 tetrahedra and corners with four equivalent S(1)Cu3W tetrahedra. Both Cu(2)-N(4) bond lengths are 2.07 Å. Both Cu(2)-S(1) bond lengths are 2.32 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(1) bond length is 1.36 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a 3-coordinate geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.37 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(2) and two equivalent N(3) atoms. The C(4)-N(2) bond length is 1.38 Å. There is one shorter (1.30 Å) and one longer (1.40 Å) C(4)-N(3) bond length. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(4) atom. The C(5)-N(4) bond length is 1.29 Å. The C(5)-N(5) bond length is 1.28 Å. The C(5)-H(4) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(4), and one H(5) atom. The C(6)-C(7) bond length is 1.33 Å. The C(6)-N(4) bond length is 1.34 Å. The C(6)-H(5) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one N(5), and one H(6) atom. The C(7)-N(5) bond length is 1.39 Å. The C(7)-H(6) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(5) and two equivalent N(6) atoms. The C(8)-N(5) bond length is 1.39 Å. There is one shorter (1.25 Å) and one longer (1.39 Å) C(8)-N(6) bond length. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to two equivalent C(4) atoms. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(5), and one C(6) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. In the sixth N site, N(6) is bonded in a water-like geometry to two equivalent C(8) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. S(1) is bonded to one W(1), one Cu(2), and two equivalent Cu(1) atoms to form distorted SCu3W tetrahedra that share corners with two equivalent Cu(2)WS2N2 tetrahedra and edges with three equivalent S(1)Cu3W tetrahedra. Br(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 17 n1ccn(c1)C1=NC(=[N]=C([N]1)n1ccnc1)n1ccnc1. Metal clusters: 6 Br[Cu]1[S@]23[Cu](Br)[S@]45[Cu](Br)[S@]67[Cu](Br)[S@@]18[Cu]4[W]6285[Cu]73. The MOF has largest included sphere 8.70 A, density 1.28 g/cm3, surface area 3139.06 m2/g, accessible volume 0.51 cm3/g