Mn3C24H13O13(C6H4SO2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twelve di-isopropenylsulfon molecules and two Mn3C24H13O13 clusters. In each Mn3C24H13O13 cluster, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(3), one O(5), and two equivalent O(4) atoms to form MnO6 octahedra that share corners with two equivalent Mn(2)O6 octahedra,  a cornercorner with one Mn(3)O5 square pyramid, and  an edgeedge with one Mn(1)O6 octahedra. The corner-sharing octahedral tilt angles range from 51-67°. The Mn(1)-O(1) bond length is 2.08 Å. The Mn(1)-O(2) bond length is 2.11 Å. The Mn(1)-O(3) bond length is 2.14 Å. The Mn(1)-O(5) bond length is 2.21 Å. There is one shorter (2.17 Å) and one longer (2.20 Å) Mn(1)-O(4) bond length. In the second Mn site, Mn(2) is bonded to one O(3), one O(5), one O(6), one O(7), one O(8), and one O(9) atom to form distorted MnO6 octahedra that share corners with two equivalent Mn(1)O6 octahedra and  a cornercorner with one Mn(3)O5 square pyramid. The corner-sharing octahedral tilt angles range from 51-67°. The Mn(2)-O(3) bond length is 2.08 Å. The Mn(2)-O(5) bond length is 2.36 Å. The Mn(2)-O(6) bond length is 2.11 Å. The Mn(2)-O(7) bond length is 2.17 Å. The Mn(2)-O(8) bond length is 2.23 Å. The Mn(2)-O(9) bond length is 2.25 Å. In the third Mn site, Mn(3) is bonded to one O(10), one O(11), one O(12), one O(13), and one O(3) atom to form corner-sharing MnO5 square pyramids. The corner-sharing octahedral tilt angles range from 66-67°. The Mn(3)-O(10) bond length is 2.16 Å. The Mn(3)-O(11) bond length is 2.16 Å. The Mn(3)-O(12) bond length is 2.18 Å. The Mn(3)-O(13) bond length is 2.19 Å. The Mn(3)-O(3) bond length is 2.14 Å. There are twenty-four inequivalent C sites. In the first C site, C(17) is bonded in a single-bond geometry to one C(16) and one H(10) atom. The C(17)-C(16) bond length is 1.38 Å. The C(17)-H(10) bond length is 0.93 Å. In the second C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(13) atom. The C(21)-C(16) bond length is 1.40 Å. The C(21)-H(13) bond length is 0.93 Å. In the third C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(15) atom. The C(24)-C(25) bond length is 1.41 Å. The C(24)-H(15) bond length is 0.93 Å. In the fourth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(28) atom. The C(25)-C(26) bond length is 1.38 Å. The C(25)-C(28) bond length is 1.52 Å. In the fifth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(16) atom. The C(26)-H(16) bond length is 0.93 Å. In the sixth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(12), and one O(2) atom. The C(28)-O(12) bond length is 1.25 Å. The C(28)-O(2) bond length is 1.26 Å. In the seventh C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(4), and one O(8) atom. The C(29)-C(30) bond length is 1.51 Å. The C(29)-O(4) bond length is 1.28 Å. The C(29)-O(8) bond length is 1.25 Å. In the eighth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(35) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-C(35) bond length is 1.37 Å. In the ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(18) atom. The C(31)-H(18) bond length is 0.93 Å. In the tenth C site, C(35) is bonded in a distorted single-bond geometry to one C(30) and one H(21) atom. The C(35)-H(21) bond length is 0.93 Å. In the eleventh C site, C(38) is bonded in a distorted single-bond geometry to one C(39) and one H(23) atom. The C(38)-C(39) bond length is 1.38 Å. The C(38)-H(23) bond length is 0.93 Å. In the twelfth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(42) atom. The C(39)-C(40) bond length is 1.38 Å. The C(39)-C(42) bond length is 1.50 Å. In the thirteenth C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one H(24) atom. The C(40)-H(24) bond length is 0.93 Å. In the fourteenth C site, C(42) is bonded in a bent 120 degrees geometry to one C(39), one O(10), and one O(6) atom. The C(42)-O(10) bond length is 1.26 Å. The C(42)-O(6) bond length is 1.26 Å. In the fifteenth C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(5), and one O(9) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(5) bond length is 1.26 Å. The C(1)-O(9) bond length is 1.25 Å. In the sixteenth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(7) bond length is 1.40 Å. In the seventeenth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 0.93 Å. In the eighteenth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(7)-H(5) bond length is 0.93 Å. In the nineteenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(7) bond length is 0.93 Å. In the twentieth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.36 Å. The C(11)-C(14) bond length is 1.52 Å. In the twenty-first C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(12)-H(8) bond length is 0.93 Å. In the twenty-second C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(11), and one O(7) atom. The C(14)-O(11) bond length is 1.25 Å. The C(14)-O(7) bond length is 1.25 Å. In the twenty-third C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(1), and one O(13) atom. The C(15)-C(16) bond length is 1.51 Å. The C(15)-O(1) bond length is 1.26 Å. The C(15)-O(13) bond length is 1.24 Å. In the twenty-fourth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. The H(1)-O(3) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(31) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(35) atom. In the twelfth H site, H(23) is bonded in a single-bond geometry to one C(38) atom. In the thirteenth H site, H(24) is bonded in a single-bond geometry to one C(40) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(15) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(28) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Mn(1), one Mn(2), one Mn(3), and one H(1) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one C(29) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(2), and one C(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(42) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(14) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(29) atom. In the ninth O site, O(9) is bonded in an L-shaped geometry to one Mn(2) and one C(1) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mn(3) and one C(42) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Mn(3) and one C(14) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Mn(3) and one C(28) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Mn(3) and one C(15) atom. Linkers: 12 [O]C(=O)c1ccc(S(=O)(=O)c2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 O[Mn]123O[C]O[Mn]4(O[C]O[Mn]5(O[C]O4)O[C]O[Mn]4(O)(O[C]O5)O[C]O[Mn]5(O[C]O[Mn](O[C]O5)(O[C]O1)O[C]O2)O[C]O4)O[C]O3. RCSR code: pcu. The MOF has largest included sphere 6.21 A, density 1.03 g/cm3, surface area 4127.12 m2/g, accessible volume 0.52 cm3/g