Zn4C54H24O13 crystallizes in the cubic Fm-3m space group. Zn(1) is bonded to one O(1) and three equivalent O(2) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.95 Å. All Zn(1)-O(2) bond lengths are 1.99 Å. There are six inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(1) bond length is 1.40 Å. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.39 Å. In the second C site, C(1) is bonded in a single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(1)-C(4) bond length is 1.40 Å. The C(1)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(5) and two equivalent C(1) atoms. The C(4)-C(5) bond length is 1.34 Å. In the fifth C site, C(5) is bonded in a bent 120 degrees geometry to one C(4) and two equivalent O(2) atoms. Both C(5)-O(2) bond lengths are 1.25 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(6) and two equivalent C(2) atoms. The C(6)-C(6) bond length is 1.32 Å. There are two inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a tetrahedral geometry to four equivalent Zn(1) atoms. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(5) atom. Linkers: 6 [O]C(=O)c1cc2ccc3cc(C([O])=O)cc4ccc(c1)c2c34. Metal clusters: 2 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: pcu. The MOF has largest included sphere 20.93 A, density 0.37 g/cm3, surface area 3980.14 m2/g, accessible volume 2.36 cm3/g