Co5C38H28(N3O7)2(CH)10 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules and one Co5C38H28(N3O7)2 cluster. In the Co5C38H28(N3O7)2 cluster, there are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(3), one O(2), one O(4), one O(5), and one O(7) atom to form CoNO4 square pyramids that share  a cornercorner with one Co(2)N2O4 octahedra and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. The Co(1)-N(3) bond length is 2.15 Å. The Co(1)-O(2) bond length is 2.05 Å. The Co(1)-O(4) bond length is 2.22 Å. The Co(1)-O(5) bond length is 2.16 Å. The Co(1)-O(7) bond length is 2.04 Å. In the second Co site, Co(2) is bonded to one N(1), one N(2), one O(1), one O(3), one O(6), and one O(7) atom to form distorted CoN2O4 octahedra that share  a cornercorner with one Co(1)NO4 square pyramid and  an edgeedge with one Co(3)O6 octahedra. The Co(2)-N(1) bond length is 2.19 Å. The Co(2)-N(2) bond length is 2.13 Å. The Co(2)-O(1) bond length is 2.04 Å. The Co(2)-O(3) bond length is 2.10 Å. The Co(2)-O(6) bond length is 2.28 Å. The Co(2)-O(7) bond length is 2.05 Å. In the third Co site, Co(3) is bonded to two equivalent O(4), two equivalent O(6), and two equivalent O(7) atoms to form CoO6 octahedra that share edges with two equivalent Co(2)N2O4 octahedra and edges with two equivalent Co(1)NO4 square pyramids. Both Co(3)-O(4) bond lengths are 2.13 Å. Both Co(3)-O(6) bond lengths are 2.11 Å. Both Co(3)-O(7) bond lengths are 2.05 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.23 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.46 Å. The C(3)-H(3) bond length is 0.93 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(8) bond length is 1.37 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 0.93 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(7)-N(1) bond length is 1.35 Å. The C(7)-H(6) bond length is 0.93 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(7) atom. The C(8)-N(1) bond length is 1.35 Å. The C(8)-H(7) bond length is 0.93 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(9)-O(3) bond length is 1.26 Å. The C(9)-O(4) bond length is 1.25 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(9) atom. The C(11)-C(12) bond length is 1.47 Å. The C(11)-H(9) bond length is 0.93 Å. In the ninth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(16) atom. The C(12)-C(13) bond length is 1.36 Å. The C(12)-C(16) bond length is 1.39 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(13)-H(10) bond length is 0.93 Å. In the eleventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(15)-N(2) bond length is 1.36 Å. The C(15)-H(12) bond length is 0.93 Å. In the twelfth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(2), and one H(13) atom. The C(16)-N(2) bond length is 1.33 Å. The C(16)-H(13) bond length is 0.93 Å. In the thirteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(17)-O(5) bond length is 1.27 Å. The C(17)-O(6) bond length is 1.26 Å. In the fourteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(14) atom. The C(18)-C(19) bond length is 1.32 Å. The C(18)-H(14) bond length is 0.93 Å. In the fifteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(15) atom. The C(19)-C(20) bond length is 1.46 Å. The C(19)-H(15) bond length is 0.93 Å. In the sixteenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(24) atom. The C(20)-C(21) bond length is 1.38 Å. The C(20)-C(24) bond length is 1.39 Å. In the seventeenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(16) atom. The C(21)-H(16) bond length is 0.93 Å. In the eighteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(18) atom. The C(23)-N(3) bond length is 1.37 Å. The C(23)-H(18) bond length is 0.93 Å. In the nineteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(3), and one H(19) atom. The C(24)-N(3) bond length is 1.33 Å. The C(24)-H(19) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(2), one C(7), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(2), one C(15), and one C(16) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(23), and one C(24) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. The H(1)-O(7) bond length is 0.85 Å. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(24) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(9) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Co(1), one Co(3), and one C(9) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(17) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Co(2), one Co(3), and one C(17) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Co(1), one Co(2), one Co(3), and one H(1) atom. Linkers: 6 [O]C(=O)/C=C/c1cccnc1. Metal clusters: 1 O[Co]1O[C]O[Co]O[C]O[Co]2(O[C]O[Co]O[C]O[Co](O)O[C]O2)O[C]O1. The MOF has largest included sphere 4.91 A, density 1.27 g/cm3, surface area 3918.16 m2/g, accessible volume 0.35 cm3/g