LaW4C6NH2O15CH crystallizes in the orthorhombic Pbca space group. The structure consists of twenty-four 02329_fluka molecules inside a LaW4C6NH2O15 framework. In the LaW4C6NH2O15 framework, there are three inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one N(1), one N(2), one O(10), one O(12), one O(16), one O(32), one O(36), one O(43), and one O(8) atom. The La(1)-N(1) bond length is 2.69 Å. The La(1)-N(2) bond length is 2.63 Å. The La(1)-O(10) bond length is 2.49 Å. The La(1)-O(12) bond length is 2.57 Å. The La(1)-O(16) bond length is 2.84 Å. The La(1)-O(32) bond length is 2.59 Å. The La(1)-O(36) bond length is 2.58 Å. The La(1)-O(43) bond length is 2.49 Å. The La(1)-O(8) bond length is 2.58 Å. In the second La site, La(2) is bonded in a distorted hexagonal planar geometry to one N(3), one O(23), one O(25), one O(29), one O(30), and one O(35) atom. The La(2)-N(3) bond length is 2.68 Å. The La(2)-O(23) bond length is 2.53 Å. The La(2)-O(25) bond length is 2.51 Å. The La(2)-O(29) bond length is 2.46 Å. The La(2)-O(30) bond length is 2.67 Å. The La(2)-O(35) bond length is 2.55 Å. In the third La site, La(3) is bonded in a trigonal planar geometry to one O(26), one O(27), and one O(42) atom. The La(3)-O(26) bond length is 2.53 Å. The La(3)-O(27) bond length is 2.44 Å. The La(3)-O(42) bond length is 2.56 Å. There are twelve inequivalent W sites. In the first W site, W(1) is bonded to one O(14), one O(18), one O(2), one O(26), one O(37), and one O(9) atom to form distorted WO6 octahedra that share  a cornercorner with one W(10)O6 octahedra,  a cornercorner with one W(9)O5 square pyramid,  an edgeedge with one W(2)O5 square pyramid, and  an edgeedge with one W(5)O5 square pyramid. The corner-sharing octahedral tilt angles are 35°. The W(1)-O(14) bond length is 1.85 Å. The W(1)-O(18) bond length is 2.03 Å. The W(1)-O(2) bond length is 2.14 Å. The W(1)-O(26) bond length is 1.75 Å. The W(1)-O(37) bond length is 1.93 Å. The W(1)-O(9) bond length is 1.92 Å. In the second W site, W(2) is bonded to one O(18), one O(2), one O(33), one O(5), and one O(6) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(7)O6 octahedra,  a cornercorner with one W(4)O5 square pyramid,  an edgeedge with one W(1)O6 octahedra, and  an edgeedge with one W(5)O5 square pyramid. The corner-sharing octahedral tilt angles are 32°. The W(2)-O(18) bond length is 1.89 Å. The W(2)-O(2) bond length is 2.24 Å. The W(2)-O(33) bond length is 1.88 Å. The W(2)-O(5) bond length is 2.00 Å. The W(2)-O(6) bond length is 1.98 Å. In the third W site, W(3) is bonded to one O(1), one O(11), one O(3), one O(38), and one O(40) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(6)O6 octahedra,  a cornercorner with one W(8)O5 square pyramid,  an edgeedge with one W(7)O6 octahedra, and  an edgeedge with one W(12)O5 square pyramid. The corner-sharing octahedral tilt angles are 29°. The W(3)-O(1) bond length is 2.25 Å. The W(3)-O(11) bond length is 1.86 Å. The W(3)-O(3) bond length is 1.98 Å. The W(3)-O(38) bond length is 1.93 Å. The W(3)-O(40) bond length is 1.89 Å. In the fourth W site, W(4) is bonded to one O(21), one O(33), one O(39), one O(45), and one O(8) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(7)O6 octahedra,  a cornercorner with one W(2)O5 square pyramid,  an edgeedge with one W(10)O6 octahedra, and  an edgeedge with one W(8)O5 square pyramid. The corner-sharing octahedral tilt angles are 31°. The W(4)-O(21) bond length is 1.93 Å. The W(4)-O(33) bond length is 1.94 Å. The W(4)-O(39) bond length is 2.20 Å. The W(4)-O(45) bond length is 1.97 Å. The W(4)-O(8) bond length is 1.92 Å. In the fifth W site, W(5) is bonded to one O(2), one O(22), one O(24), one O(37), and one O(6) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(11)O6 octahedra,  a cornercorner with one W(12)O5 square pyramid,  an edgeedge with one W(1)O6 octahedra, and  an edgeedge with one W(2)O5 square pyramid. The corner-sharing octahedral tilt angles are 30°. The W(5)-O(2) bond length is 2.26 Å. The W(5)-O(22) bond length is 1.90 Å. The W(5)-O(24) bond length is 1.96 Å. The W(5)-O(37) bond length is 1.93 Å. The W(5)-O(6) bond length is 1.89 Å. In the sixth W site, W(6) is bonded to one O(12), one O(17), one O(3), one O(31), one O(34), and one O(4) atom to form distorted WO6 octahedra that share  a cornercorner with one W(3)O5 square pyramid,  a cornercorner with one W(8)O5 square pyramid,  an edgeedge with one W(11)O6 octahedra, and  an edgeedge with one W(9)O5 square pyramid. The W(6)-O(12) bond length is 1.74 Å. The W(6)-O(17) bond length is 1.93 Å. The W(6)-O(3) bond length is 1.84 Å. The W(6)-O(31) bond length is 2.01 Å. The W(6)-O(34) bond length is 1.92 Å. The W(6)-O(4) bond length is 2.21 Å. In the seventh W site, W(7) is bonded to one O(1), one O(11), one O(13), one O(25), one O(45), and one O(5) atom to form a mixture of distorted edge and corner-sharing WO6 octahedra. The W(7)-O(1) bond length is 2.20 Å. The W(7)-O(11) bond length is 2.00 Å. The W(7)-O(13) bond length is 1.95 Å. The W(7)-O(25) bond length is 1.74 Å. The W(7)-O(45) bond length is 1.86 Å. The W(7)-O(5) bond length is 1.83 Å. In the eighth W site, W(8) is bonded to one O(17), one O(21), one O(39), one O(40), and one O(7) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(6)O6 octahedra,  a cornercorner with one W(3)O5 square pyramid,  an edgeedge with one W(10)O6 octahedra, and  an edgeedge with one W(4)O5 square pyramid. The corner-sharing octahedral tilt angles are 30°. The W(8)-O(17) bond length is 1.90 Å. The W(8)-O(21) bond length is 1.96 Å. The W(8)-O(39) bond length is 2.25 Å. The W(8)-O(40) bond length is 1.95 Å. The W(8)-O(7) bond length is 1.91 Å. In the ninth W site, W(9) is bonded to one O(14), one O(15), one O(20), one O(31), and one O(4) atom to form a mixture of distorted edge and corner-sharing WO5 square pyramids. The corner-sharing octahedral tilt angles range from 27-28°. The W(9)-O(14) bond length is 1.96 Å. The W(9)-O(15) bond length is 1.90 Å. The W(9)-O(20) bond length is 1.96 Å. The W(9)-O(31) bond length is 1.86 Å. The W(9)-O(4) bond length is 2.30 Å. In the tenth W site, W(10) is bonded to one O(16), one O(20), one O(39), one O(7), one O(8), and one O(9) atom to form distorted WO6 octahedra that share  a cornercorner with one W(1)O6 octahedra,  a cornercorner with one W(9)O5 square pyramid,  an edgeedge with one W(4)O5 square pyramid, and  an edgeedge with one W(8)O5 square pyramid. The corner-sharing octahedral tilt angles are 35°. The W(10)-O(16) bond length is 1.75 Å. The W(10)-O(20) bond length is 1.85 Å. The W(10)-O(39) bond length is 2.10 Å. The W(10)-O(7) bond length is 1.96 Å. The W(10)-O(8) bond length is 2.03 Å. The W(10)-O(9) bond length is 1.89 Å. In the eleventh W site, W(11) is bonded to one O(15), one O(19), one O(23), one O(24), one O(34), and one O(4) atom to form distorted WO6 octahedra that share  a cornercorner with one W(12)O5 square pyramid,  a cornercorner with one W(5)O5 square pyramid,  an edgeedge with one W(6)O6 octahedra, and  an edgeedge with one W(9)O5 square pyramid. The W(11)-O(15) bond length is 1.93 Å. The W(11)-O(19) bond length is 1.93 Å. The W(11)-O(23) bond length is 1.72 Å. The W(11)-O(24) bond length is 1.86 Å. The W(11)-O(34) bond length is 1.96 Å. The W(11)-O(4) bond length is 2.20 Å. In the twelfth W site, W(12) is bonded to one O(1), one O(13), one O(19), one O(22), and one O(38) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(11)O6 octahedra,  a cornercorner with one W(5)O5 square pyramid,  an edgeedge with one W(7)O6 octahedra, and  an edgeedge with one W(3)O5 square pyramid. The corner-sharing octahedral tilt angles are 32°. The W(12)-O(1) bond length is 2.25 Å. The W(12)-O(13) bond length is 1.90 Å. The W(12)-O(19) bond length is 1.91 Å. The W(12)-O(22) bond length is 1.92 Å. The W(12)-O(38) bond length is 1.94 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(9) and one H(1) atom. The C(1)-C(9) bond length is 1.37 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(15) and one H(3) atom. The C(3)-C(15) bond length is 1.38 Å. The C(3)-H(3) bond length is 0.93 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(11) and one H(4) atom. The C(4)-C(11) bond length is 1.36 Å. The C(4)-H(4) bond length is 0.93 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(28), and one O(30) atom. The C(6)-C(9) bond length is 1.44 Å. The C(6)-O(28) bond length is 1.31 Å. The C(6)-O(30) bond length is 1.28 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one N(3) atom. The C(8)-N(3) bond length is 1.33 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(1), one C(6), and one N(3) atom. The C(9)-N(3) bond length is 1.29 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(17) and one H(7) atom. The C(10)-C(17) bond length is 1.40 Å. The C(10)-H(7) bond length is 0.93 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(18), one C(4), and one N(1) atom. The C(11)-C(18) bond length is 1.44 Å. The C(11)-N(1) bond length is 1.35 Å. In the ninth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one N(2) atom. The C(12)-C(14) bond length is 1.41 Å. The C(12)-C(16) bond length is 1.48 Å. The C(12)-N(2) bond length is 1.37 Å. In the tenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(10), and one O(29) atom. The C(13)-C(17) bond length is 1.54 Å. The C(13)-O(10) bond length is 1.25 Å. The C(13)-O(29) bond length is 1.22 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. In the twelfth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(21), one C(3), and one H(9) atom. The C(15)-C(21) bond length is 1.34 Å. The C(15)-H(9) bond length is 0.93 Å. In the thirteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(36), and one O(41) atom. The C(16)-O(36) bond length is 1.21 Å. The C(16)-O(41) bond length is 1.29 Å. In the fourteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(10), one C(13), and one N(2) atom. The C(17)-N(2) bond length is 1.32 Å. In the fifteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(32), and one O(44) atom. The C(18)-O(32) bond length is 1.27 Å. The C(18)-O(44) bond length is 1.33 Å. In the sixteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(42) and one O(43) atom. The C(19)-O(42) bond length is 1.26 Å. The C(19)-O(43) bond length is 1.26 Å. In the seventeenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one O(27) and one O(35) atom. The C(20)-O(27) bond length is 1.23 Å. The C(20)-O(35) bond length is 1.23 Å. In the eighteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(15) and one N(1) atom. The C(21)-N(1) bond length is 1.28 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one La(1), one C(11), and one C(21) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one La(1), one C(12), and one C(17) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one La(2), one C(8), and one C(9) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. There are forty-five inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one W(12), one W(3), and one W(7) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one W(1), one W(2), and one W(5) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(3) and one W(6) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one W(11), one W(6), and one W(9) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(2) and one W(7) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one W(2) and one W(5) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one W(10) and one W(8) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one La(1), one W(10), and one W(4) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one W(1) and one W(10) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one La(1) and one C(13) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one W(3) and one W(7) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one La(1) and one W(6) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one W(12) and one W(7) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one W(1) and one W(9) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one W(11) and one W(9) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one La(1) and one W(10) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one W(6) and one W(8) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one W(1) and one W(2) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one W(11) and one W(12) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one W(10) and one W(9) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one W(4) and one W(8) atom. In the twenty-second O site, O(22) is bonded in a bent 150 degrees geometry to one W(12) and one W(5) atom. In the twenty-third O site, O(23) is bonded in a distorted single-bond geometry to one La(2) and one W(11) atom. In the twenty-fourth O site, O(24) is bonded in a bent 150 degrees geometry to one W(11) and one W(5) atom. In the twenty-fifth O site, O(25) is bonded in a distorted single-bond geometry to one La(2) and one W(7) atom. In the twenty-sixth O site, O(26) is bonded in a bent 150 degrees geometry to one La(3) and one W(1) atom. In the twenty-seventh O site, O(27) is bonded in a bent 150 degrees geometry to one La(3) and one C(20) atom. In the twenty-eighth O site, O(28) is bonded in a single-bond geometry to one C(6) atom. In the twenty-ninth O site, O(29) is bonded in a distorted bent 150 degrees geometry to one La(2) and one C(13) atom. In the thirtieth O site, O(30) is bonded in a single-bond geometry to one La(2) and one C(6) atom. In the thirty-first O site, O(31) is bonded in a bent 120 degrees geometry to one W(6) and one W(9) atom. In the thirty-second O site, O(32) is bonded in a distorted single-bond geometry to one La(1) and one C(18) atom. In the thirty-third O site, O(33) is bonded in a bent 150 degrees geometry to one W(2) and one W(4) atom. In the thirty-fourth O site, O(34) is bonded in a bent 120 degrees geometry to one W(11) and one W(6) atom. In the thirty-fifth O site, O(35) is bonded in a distorted single-bond geometry to one La(2) and one C(20) atom. In the thirty-sixth O site, O(36) is bonded in a distorted single-bond geometry to one La(1) and one C(16) atom. In the thirty-seventh O site, O(37) is bonded in a bent 120 degrees geometry to one W(1) and one W(5) atom. In the thirty-eighth O site, O(38) is bonded in a bent 120 degrees geometry to one W(12) and one W(3) atom. In the thirty-ninth O site, O(39) is bonded in a distorted T-shaped geometry to one W(10), one W(4), and one W(8) atom. In the fortieth O site, O(40) is bonded in a bent 150 degrees geometry to one W(3) and one W(8) atom. In the forty-first O site, O(41) is bonded in a single-bond geometry to one C(16) atom. In the forty-second O site, O(42) is bonded in a distorted bent 120 degrees geometry to one La(3) and one C(19) atom. In the forty-third O site, O(43) is bonded in a distorted bent 120 degrees geometry to one La(1) and one C(19) atom. In the forty-fourth O site, O(44) is bonded in a single-bond geometry to one C(18) atom. In the forty-fifth O site, O(45) is bonded in a bent 150 degrees geometry to one W(4) and one W(7) atom. Linkers: 24 [O]C(=O)c1cccc(C([O])=O)n1. Metal clusters: 24 [La] ,96 [W]. The MOF has largest included sphere 5.31 A, density 3.36 g/cm3, surface area 1436.50 m2/g, accessible volume 0.12 cm3/g