Li2C12H24O6Cl is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Li2C12H24O6Cl clusters. Li(1) is bonded to one O(1), one O(2), one O(3), and one Cl(1) atom to form corner-sharing LiClO3 tetrahedra. The Li(1)-O(1) bond length is 1.93 Å. The Li(1)-O(2) bond length is 1.94 Å. The Li(1)-O(3) bond length is 1.95 Å. The Li(1)-Cl(1) bond length is 2.27 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(1,2) and one O(1) atom. Both C(1)-H(1,2) bond lengths are 0.99 Å. The C(1)-O(1) bond length is 1.44 Å. In the second C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(3,4) and one O(1) atom. Both C(2)-H(3,4) bond lengths are 0.99 Å. The C(2)-O(1) bond length is 1.44 Å. In the third C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(11,12) and one O(3) atom. Both C(6)-H(11,12) bond lengths are 0.99 Å. The C(6)-O(3) bond length is 1.43 Å. In the fourth C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(5,6) and one O(2) atom. Both C(3)-H(5,6) bond lengths are 0.99 Å. The C(3)-O(2) bond length is 1.44 Å. In the fifth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one H(7), one H(8), and one O(2) atom. The C(4)-H(7) bond length is 0.99 Å. The C(4)-H(8) bond length is 0.99 Å. The C(4)-O(2) bond length is 1.44 Å. In the sixth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(9,10) and one O(3) atom. Both C(5)-H(9,10) bond lengths are 0.99 Å. The C(5)-O(3) bond length is 1.44 Å. There are seven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(6) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a trigonal planar geometry to one Li(1), one C(1), and one C(2) atom. In the second O site, O(2) is bonded in a trigonal non-coplanar geometry to one Li(1), one C(3), and one C(4) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Li(1), one C(5), and one C(6) atom. Cl(1) is bonded in a linear geometry to two equivalent Li(1) atoms. Linkers: 12 C1COCCO1. Metal clusters: 4 [Li].[Li]Cl. The MOF has largest included sphere 5.94 A, density 0.82 g/cm3, surface area 6015.31 m2/g, accessible volume 0.59 cm3/g