Ag7C31H21(N7O3)2CF6(CF3)2 crystallizes in the triclinic P-1 space group. The structure consists of four trifluoromethane molecules and two CF6 clusters inside a Ag7C31H21(N7O3)2 framework. In each CF6 cluster, C(30) is bonded in a 6-coordinate geometry to one F(1), one F(2), one F(3), one F(4), one F(5), and one F(6) atom. The C(30)-F(1) bond length is 1.31 Å. The C(30)-F(2) bond length is 1.35 Å. The C(30)-F(3) bond length is 1.31 Å. The C(30)-F(4) bond length is 1.31 Å. The C(30)-F(5) bond length is 1.29 Å. The C(30)-F(6) bond length is 1.32 Å. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(30) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(30) atom. In the third F site, F(3) is bonded in a distorted single-bond geometry to one C(30) atom. In the fourth F site, F(4) is bonded in a distorted single-bond geometry to one C(30) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(30) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one C(30) atom. In the Ag7C31H21(N7O3)2 framework, there are seven inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one N(8), and one O(1) atom. The Ag(1)-N(1) bond length is 2.26 Å. The Ag(1)-N(8) bond length is 2.35 Å. The Ag(1)-O(1) bond length is 2.23 Å. In the second Ag site, Ag(2) is bonded in a water-like geometry to one N(2) and one N(3) atom. The Ag(2)-N(2) bond length is 2.40 Å. The Ag(2)-N(3) bond length is 2.28 Å. In the third Ag site, Ag(3) is bonded in a bent 120 degrees geometry to one N(4) and one N(5) atom. The Ag(3)-N(4) bond length is 2.34 Å. The Ag(3)-N(5) bond length is 2.25 Å. In the fourth Ag site, Ag(4) is bonded in a water-like geometry to one N(6) and one N(9) atom. The Ag(4)-N(6) bond length is 2.33 Å. The Ag(4)-N(9) bond length is 2.29 Å. In the fifth Ag site, Ag(5) is bonded in a distorted trigonal non-coplanar geometry to one N(10), one N(11), and one O(3) atom. The Ag(5)-N(10) bond length is 2.39 Å. The Ag(5)-N(11) bond length is 2.32 Å. The Ag(5)-O(3) bond length is 2.35 Å. In the sixth Ag site, Ag(6) is bonded in a distorted rectangular see-saw-like geometry to one N(12), one N(13), one O(4), and one O(5) atom. The Ag(6)-N(12) bond length is 2.46 Å. The Ag(6)-N(13) bond length is 2.27 Å. The Ag(6)-O(4) bond length is 2.33 Å. The Ag(6)-O(5) bond length is 2.36 Å. In the seventh Ag site, Ag(7) is bonded in a distorted tetrahedral geometry to one N(14), one N(7), one O(2), and one O(6) atom. The Ag(7)-N(14) bond length is 2.65 Å. The Ag(7)-N(7) bond length is 2.31 Å. The Ag(7)-O(2) bond length is 2.37 Å. The Ag(7)-O(6) bond length is 2.34 Å. There are thirty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(18), and one C(3) atom. The C(2)-C(18) bond length is 1.49 Å. The C(2)-C(3) bond length is 1.37 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(3) atom. The C(4)-N(2) bond length is 1.31 Å. The C(4)-H(3) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(3), and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-N(3) bond length is 1.31 Å. The C(5)-H(4) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(22), one C(5), and one C(7) atom. The C(6)-C(22) bond length is 1.47 Å. The C(6)-C(7) bond length is 1.37 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(6) atom. The C(8)-N(4) bond length is 1.31 Å. The C(8)-H(6) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(5), and one H(7) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-N(5) bond length is 1.32 Å. The C(9)-H(7) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(9) atom. The C(10)-C(11) bond length is 1.37 Å. The C(10)-C(14) bond length is 1.48 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(11)-H(8) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(9) atom. The C(12)-N(6) bond length is 1.32 Å. The C(12)-H(9) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(7), and one H(10) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-N(7) bond length is 1.32 Å. The C(13)-H(10) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(15) atom. The C(14)-C(15) bond length is 1.36 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(15)-H(11) bond length is 0.93 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(12) atom. The C(16)-N(8) bond length is 1.31 Å. The C(16)-H(12) bond length is 0.93 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(9), and one H(13) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-N(9) bond length is 1.33 Å. The C(17)-H(13) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(2) atom. The C(18)-C(19) bond length is 1.37 Å. In the nineteenth C site, C(19) is bonded in a single-bond geometry to one C(18) and one H(14) atom. The C(19)-H(14) bond length is 0.93 Å. In the twentieth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(15) atom. The C(20)-N(10) bond length is 1.31 Å. The C(20)-H(15) bond length is 0.93 Å. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(11), and one H(16) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-N(11) bond length is 1.32 Å. The C(21)-H(16) bond length is 0.93 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(6) atom. The C(22)-C(23) bond length is 1.37 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(17) atom. The C(23)-H(17) bond length is 0.93 Å. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(12) and one H(18) atom. The C(24)-N(12) bond length is 1.31 Å. The C(24)-H(18) bond length is 0.93 Å. In the twenty-fifth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(13) and one H(19) atom. The C(25)-N(13) bond length is 1.32 Å. The C(25)-H(19) bond length is 0.93 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(27) and one H(20) atom. The C(26)-C(27) bond length is 1.36 Å. The C(26)-H(20) bond length is 0.93 Å. In the twenty-seventh C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(27), and one C(28) atom. The C(27)-C(27) bond length is 1.49 Å. The C(27)-C(28) bond length is 1.40 Å. In the twenty-eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(27), one N(14), and one H(21) atom. The C(28)-N(14) bond length is 1.32 Å. The C(28)-H(21) bond length is 0.93 Å. In the twenty-ninth C site, C(29) is bonded in a distorted trigonal planar geometry to one O(1) and one O(2) atom. The C(29)-O(1) bond length is 1.23 Å. The C(29)-O(2) bond length is 1.22 Å. In the thirtieth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(31)-O(3) bond length is 1.22 Å. The C(31)-O(4) bond length is 1.22 Å. In the thirty-first C site, C(33) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(33)-O(5) bond length is 1.23 Å. The C(33)-O(6) bond length is 1.23 Å. There are fourteen inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(4), and one N(1) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(5), and one N(4) atom. The N(3)-N(4) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(3), one C(8), and one N(3) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Ag(3), one C(9), and one N(6) atom. The N(5)-N(6) bond length is 1.35 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Ag(4), one C(12), and one N(5) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Ag(7), one C(13), and one N(8) atom. The N(7)-N(8) bond length is 1.35 Å. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(16), and one N(7) atom. In the ninth N site, N(9) is bonded in a distorted trigonal planar geometry to one Ag(4), one C(17), and one N(10) atom. The N(9)-N(10) bond length is 1.35 Å. In the tenth N site, N(10) is bonded in a distorted trigonal planar geometry to one Ag(5), one C(20), and one N(9) atom. In the eleventh N site, N(11) is bonded in a distorted trigonal planar geometry to one Ag(5), one C(21), and one N(12) atom. The N(11)-N(12) bond length is 1.35 Å. In the twelfth N site, N(12) is bonded in a distorted trigonal planar geometry to one Ag(6), one C(24), and one N(11) atom. In the thirteenth N site, N(13) is bonded in a distorted trigonal planar geometry to one Ag(6), one C(25), and one N(14) atom. The N(13)-N(14) bond length is 1.35 Å. In the fourteenth N site, N(14) is bonded in a 3-coordinate geometry to one Ag(7), one C(28), and one N(13) atom. There are twenty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(26) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(28) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ag(1) and one C(29) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(7) and one C(29) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(5) and one C(31) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ag(6) and one C(31) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Ag(6) and one C(33) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Ag(7) and one C(33) atom. Linkers: 7 c1cc(-c2ccnnc2)cnn1. Metal clusters: 14 [Ag]. The MOF has largest included sphere 5.38 A, density 1.77 g/cm3, surface area 3060.93 m2/g, accessible volume 0.28 cm3/g