Zn2C9H6(NO6)2(C4H2O)3 is Indium-derived structured and crystallizes in the cubic F4_132 space group. The structure is zero-dimensional and consists of forty-eight furan molecules and eight Zn2C9H6(NO6)2 clusters. In each Zn2C9H6(NO6)2 cluster, Zn(1) is bonded to one N(1) and three equivalent O(1) atoms to form ZnNO3 tetrahedra that share corners with three equivalent C(4)H2N2 tetrahedra. The Zn(1)-N(1) bond length is 2.09 Å. All Zn(1)-O(1) bond lengths are 1.96 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.24 Å. In the second C site, C(4) is bonded to two equivalent N(1) and two equivalent H(2) atoms to form CH2N2 tetrahedra that share corners with two equivalent Zn(1)NO3 tetrahedra and corners with four equivalent C(4)H2N2 tetrahedra. Both C(4)-N(1) bond lengths are 1.49 Å. Both C(4)-H(2) bond lengths are 0.99 Å. N(1) is bonded to one Zn(1) and three equivalent C(4) atoms to form corner-sharing NZnC3 tetrahedra. H(2) is bonded in a single-bond geometry to one C(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Linkers: 4 C1N2CN3CN1CN(C2)C3 ,4 O=C(c1ccc(o1)C(=O)[O])O[Zn]([N@]12C[N@]3(C[N@@](C2)(C[N@@](C1)(C3)[Zn](OC(=O)c1ccc(o1)C(=O)[O])(OC(=O)c1ccc(o1)C(=O)[O])OC(=O)c1ccc(o1)C(=O)[O])[Zn](OC(=O)c1ccc(o1)C(=O)[O])(OC(=O)c1ccc(o1)C(=O)[O])OC(=O)c1ccc(o1)C(=O)[O])[Zn](OC(=O)c1ccc(o1)C(=O)[O])(OC(=O)c1ccc(o1)C(=O)[O])OC(=O)c1ccc(o1)C(=O)[O])(OC(=O)c1ccc(o1)C(=O)[O])OC(=O)c1ccc(o1)C(=O)[O]. Metal clusters: 16 O=[C]O[Zn](O[C]=O)O[C]=O. RCSR code: ttt. The MOF has largest included sphere 11.27 A, density 0.83 g/cm3, surface area 4170.43 m2/g, accessible volume 0.82 cm3/g