AgC14N4H12O is Indium-like structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of two AgC14N4H12O clusters. Ag(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Ag(1)-N(1) bond lengths are 2.47 Å. Both Ag(1)-N(2) bond lengths are 2.29 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.41 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1,4) atom. The C(2)-H(1,4) bond length is 0.95 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-H(2) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(7) bond length is 1.46 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 0.95 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(1,4) atom. The C(6)-H(1,4) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one O(1) atom. The C(7)-N(2) bond length is 1.29 Å. The C(7)-O(1) bond length is 1.36 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one C(1), one H(5), and one H(6) atom. The N(1)-H(5) bond length is 0.80 Å. The N(1)-H(6) bond length is 0.73 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Ag(1), one C(7), and one N(2) atom. The N(2)-N(2) bond length is 1.41 Å. There are five inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one N(1) atom. O(1) is bonded in a water-like geometry to two equivalent C(7) atoms. Linkers: 4 Nc1ccc(-c2nnc(-c3ccc(N)cc3)o2)cc1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 4.58 A, density 1.44 g/cm3, surface area 4262.22 m2/g, accessible volume 0.30 cm3/g