Ag2C6PN3H12S crystallizes in the monoclinic P2_1 space group. There are four inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted T-shaped geometry to one N(4), one S(1), and one S(2) atom. The Ag(1)-N(4) bond length is 2.32 Å. The Ag(1)-S(1) bond length is 2.71 Å. The Ag(1)-S(2) bond length is 2.50 Å. In the second Ag site, Ag(2) is bonded in a bent 150 degrees geometry to one N(2) and one S(1) atom. The Ag(2)-N(2) bond length is 2.39 Å. The Ag(2)-S(1) bond length is 2.47 Å. In the third Ag site, Ag(3) is bonded in a linear geometry to one N(5) and one S(2) atom. The Ag(3)-N(5) bond length is 2.29 Å. The Ag(3)-S(2) bond length is 2.45 Å. In the fourth Ag site, Ag(4) is bonded in a 3-coordinate geometry to one N(3), one S(1), and one S(2) atom. The Ag(4)-N(3) bond length is 2.29 Å. The Ag(4)-S(1) bond length is 2.46 Å. The Ag(4)-S(2) bond length is 3.08 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded to one P(1); one N(1); and two equivalent H(1,2) atoms to form distorted CPH2N tetrahedra that share  a cornercorner with one C(5)H2N2 tetrahedra,  a cornercorner with one C(6)H2N2 tetrahedra,  a cornercorner with one C(2)PH2N tetrahedra,  a cornercorner with one C(3)PH2N tetrahedra, and  a cornercorner with one S(1)Ag3P tetrahedra. The C(1)-P(1) bond length is 1.82 Å. The C(1)-N(1) bond length is 1.48 Å. Both C(1)-H(1,2) bond lengths are 0.99 Å. In the second C site, C(2) is bonded to one P(1); one N(2); and two equivalent H(3,4) atoms to form distorted CPH2N tetrahedra that share  a cornercorner with one C(4)H2N2 tetrahedra,  a cornercorner with one C(6)H2N2 tetrahedra,  a cornercorner with one C(1)PH2N tetrahedra,  a cornercorner with one C(3)PH2N tetrahedra, and  a cornercorner with one S(1)Ag3P tetrahedra. The C(2)-P(1) bond length is 1.83 Å. The C(2)-N(2) bond length is 1.49 Å. Both C(2)-H(3,4) bond lengths are 0.99 Å. In the third C site, C(3) is bonded to one P(1); one N(3); and two equivalent H(5,6) atoms to form distorted CPH2N tetrahedra that share  a cornercorner with one C(4)H2N2 tetrahedra,  a cornercorner with one C(5)H2N2 tetrahedra,  a cornercorner with one C(1)PH2N tetrahedra,  a cornercorner with one C(2)PH2N tetrahedra, and  a cornercorner with one S(1)Ag3P tetrahedra. The C(3)-P(1) bond length is 1.83 Å. The C(3)-N(3) bond length is 1.50 Å. Both C(3)-H(5,6) bond lengths are 0.99 Å. In the fourth C site, C(4) is bonded to one N(2), one N(3), one H(7), and one H(8) atom to form CH2N2 tetrahedra that share  a cornercorner with one C(5)H2N2 tetrahedra,  a cornercorner with one C(6)H2N2 tetrahedra,  a cornercorner with one C(2)PH2N tetrahedra, and  a cornercorner with one C(3)PH2N tetrahedra. The C(4)-N(2) bond length is 1.48 Å. The C(4)-N(3) bond length is 1.49 Å. The C(4)-H(7) bond length is 0.99 Å. The C(4)-H(8) bond length is 0.99 Å. In the fifth C site, C(5) is bonded to one N(1); one N(3); and two equivalent H(9,10) atoms to form CH2N2 tetrahedra that share  a cornercorner with one C(4)H2N2 tetrahedra,  a cornercorner with one C(6)H2N2 tetrahedra,  a cornercorner with one C(1)PH2N tetrahedra, and  a cornercorner with one C(3)PH2N tetrahedra. The C(5)-N(1) bond length is 1.46 Å. The C(5)-N(3) bond length is 1.49 Å. Both C(5)-H(9,10) bond lengths are 0.99 Å. In the sixth C site, C(6) is bonded to one N(1); one N(2); and two equivalent H(11,12) atoms to form CH2N2 tetrahedra that share  a cornercorner with one C(4)H2N2 tetrahedra,  a cornercorner with one C(5)H2N2 tetrahedra,  a cornercorner with one C(1)PH2N tetrahedra, and  a cornercorner with one C(2)PH2N tetrahedra. The C(6)-N(1) bond length is 1.46 Å. The C(6)-N(2) bond length is 1.48 Å. Both C(6)-H(11,12) bond lengths are 0.99 Å. In the seventh C site, C(7) is bonded to one P(2); one N(4); and two equivalent H(13,14) atoms to form distorted CPH2N tetrahedra that share  a cornercorner with one C(10)H2N2 tetrahedra,  a cornercorner with one C(11)H2N2 tetrahedra,  a cornercorner with one C(8)PH2N tetrahedra, and  a cornercorner with one C(9)PH2N tetrahedra. The C(7)-P(2) bond length is 1.82 Å. The C(7)-N(4) bond length is 1.49 Å. Both C(7)-H(13,14) bond lengths are 0.99 Å. In the eighth C site, C(8) is bonded to one P(2); one N(5); and two equivalent H(15,16) atoms to form distorted CPH2N tetrahedra that share  a cornercorner with one C(10)H2N2 tetrahedra,  a cornercorner with one C(12)H2N2 tetrahedra,  a cornercorner with one C(7)PH2N tetrahedra, and  a cornercorner with one C(9)PH2N tetrahedra. The C(8)-P(2) bond length is 1.83 Å. The C(8)-N(5) bond length is 1.50 Å. Both C(8)-H(15,16) bond lengths are 0.99 Å. In the ninth C site, C(9) is bonded to one P(2); one N(6); and two equivalent H(17,18) atoms to form distorted CPH2N tetrahedra that share  a cornercorner with one C(11)H2N2 tetrahedra,  a cornercorner with one C(12)H2N2 tetrahedra,  a cornercorner with one C(7)PH2N tetrahedra, and  a cornercorner with one C(8)PH2N tetrahedra. The C(9)-P(2) bond length is 1.81 Å. The C(9)-N(6) bond length is 1.48 Å. Both C(9)-H(17,18) bond lengths are 0.99 Å. In the tenth C site, C(10) is bonded to one N(4); one N(5); and two equivalent H(19,20) atoms to form CH2N2 tetrahedra that share  a cornercorner with one C(11)H2N2 tetrahedra,  a cornercorner with one C(12)H2N2 tetrahedra,  a cornercorner with one C(7)PH2N tetrahedra, and  a cornercorner with one C(8)PH2N tetrahedra. The C(10)-N(4) bond length is 1.49 Å. The C(10)-N(5) bond length is 1.48 Å. Both C(10)-H(19,20) bond lengths are 0.99 Å. In the eleventh C site, C(11) is bonded to one N(4); one N(6); and two equivalent H(21,22) atoms to form CH2N2 tetrahedra that share  a cornercorner with one C(10)H2N2 tetrahedra,  a cornercorner with one C(12)H2N2 tetrahedra,  a cornercorner with one C(7)PH2N tetrahedra, and  a cornercorner with one C(9)PH2N tetrahedra. The C(11)-N(4) bond length is 1.49 Å. The C(11)-N(6) bond length is 1.46 Å. Both C(11)-H(21,22) bond lengths are 0.99 Å. In the twelfth C site, C(12) is bonded to one N(5); one N(6); and two equivalent H(23,24) atoms to form CH2N2 tetrahedra that share  a cornercorner with one C(10)H2N2 tetrahedra,  a cornercorner with one C(11)H2N2 tetrahedra,  a cornercorner with one C(8)PH2N tetrahedra, and  a cornercorner with one C(9)PH2N tetrahedra. The C(12)-N(5) bond length is 1.49 Å. The C(12)-N(6) bond length is 1.45 Å. Both C(12)-H(23,24) bond lengths are 0.99 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one C(1), one C(2), one C(3), and one S(1) atom to form PC3S tetrahedra that share  a cornercorner with one N(2)AgC3 tetrahedra and  a cornercorner with one N(3)AgC3 tetrahedra. The P(1)-S(1) bond length is 2.01 Å. In the second P site, P(2) is bonded to one C(7), one C(8), one C(9), and one S(2) atom to form PC3S tetrahedra that share  a cornercorner with one N(4)AgC3 tetrahedra and  a cornercorner with one N(5)AgC3 tetrahedra. The P(2)-S(2) bond length is 2.00 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal non-coplanar geometry to one C(1), one C(5), and one C(6) atom. In the second N site, N(2) is bonded to one Ag(2), one C(2), one C(4), and one C(6) atom to form distorted NAgC3 tetrahedra that share  a cornercorner with one P(1)C3S tetrahedra,  a cornercorner with one N(3)AgC3 tetrahedra, and  a cornercorner with one S(1)Ag3P tetrahedra. In the third N site, N(3) is bonded to one Ag(4), one C(3), one C(4), and one C(5) atom to form NAgC3 tetrahedra that share  a cornercorner with one P(1)C3S tetrahedra,  a cornercorner with one N(2)AgC3 tetrahedra, and  a cornercorner with one S(1)Ag3P tetrahedra. In the fourth N site, N(4) is bonded to one Ag(1), one C(10), one C(11), and one C(7) atom to form NAgC3 tetrahedra that share  a cornercorner with one P(2)C3S tetrahedra,  a cornercorner with one N(5)AgC3 tetrahedra, and  a cornercorner with one S(1)Ag3P tetrahedra. In the fifth N site, N(5) is bonded to one Ag(3), one C(10), one C(12), and one C(8) atom to form NAgC3 tetrahedra that share  a cornercorner with one P(2)C3S tetrahedra and  a cornercorner with one N(4)AgC3 tetrahedra. In the sixth N site, N(6) is bonded in a trigonal non-coplanar geometry to one C(11), one C(12), and one C(9) atom. There are thirteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(13,14) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(15,16) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(17,18) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(19,20) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(21,22) is bonded in a single-bond geometry to one C(11) atom. In the thirteenth H site, H(23,24) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one Ag(1), one Ag(2), one Ag(4), and one P(1) atom to form SAg3P tetrahedra that share  a cornercorner with one C(1)PH2N tetrahedra,  a cornercorner with one C(2)PH2N tetrahedra,  a cornercorner with one C(3)PH2N tetrahedra,  a cornercorner with one N(2)AgC3 tetrahedra,  a cornercorner with one N(3)AgC3 tetrahedra, and  a cornercorner with one N(4)AgC3 tetrahedra. In the second S site, S(2) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(3), one Ag(4), and one P(2) atom. Linkers: 3 [S][P@]12C[N@@]3C[N@@](C[N@](C3)C1)C2. Metal clusters: 8 [Ag]. The MOF has largest included sphere 4.19 A, density 1.98 g/cm3, surface area 2757.49 m2/g, accessible volume 0.22 cm3/g