ZnC10NH6O4C13H6(CH)2(C3H2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules; eight 2,3-dimethyl-1,3-butadiene molecules; four C13H6 clusters; and four ZnC10NH6O4 clusters. In each C13H6 cluster, there are twenty-six inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-H(2) bond length is 0.95 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-C(6) bond length is 1.43 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.95 Å. In the fourth C site, C(6) is bonded in a linear geometry to one C(3) and one C(7) atom. The C(6)-C(7) bond length is 1.19 Å. In the fifth C site, C(7) is bonded in a linear geometry to one C(6) and one C(8) atom. The C(7)-C(8) bond length is 1.45 Å. In the sixth C site, C(8) is bonded in a tetrahedral geometry to one C(17), one C(22), one C(7), and one C(9) atom. The C(8)-C(17) bond length is 1.53 Å. The C(8)-C(22) bond length is 1.54 Å. The C(8)-C(9) bond length is 1.53 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-C(14) bond length is 1.40 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(10)-H(5) bond length is 0.95 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(6) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(6) bond length is 0.95 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(7) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(7) bond length is 0.95 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(8) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-H(8) bond length is 0.95 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(9) atom. The C(14)-C(15) bond length is 1.53 Å. In the thirteenth C site, C(15) is bonded in a tetrahedral geometry to one C(14), one C(16), one C(27), and one C(28) atom. The C(15)-C(16) bond length is 1.54 Å. The C(15)-C(27) bond length is 1.54 Å. The C(15)-C(28) bond length is 1.46 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-C(21) bond length is 1.38 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(8) atom. The C(17)-C(18) bond length is 1.38 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(9) atom. The C(18)-H(9) bond length is 0.95 Å. In the seventeenth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(21)-H(12) bond length is 0.95 Å. In the eighteenth C site, C(22) is bonded in a trigonal planar geometry to one C(23), one C(27), and one C(8) atom. The C(22)-C(23) bond length is 1.38 Å. The C(22)-C(27) bond length is 1.39 Å. In the nineteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(13) atom. The C(23)-H(13) bond length is 0.95 Å. In the twentieth C site, C(26) is bonded in a single-bond geometry to one C(27) and one H(16) atom. The C(26)-C(27) bond length is 1.37 Å. The C(26)-H(16) bond length is 0.95 Å. In the twenty-first C site, C(27) is bonded in a trigonal planar geometry to one C(15), one C(22), and one C(26) atom. In the twenty-second C site, C(28) is bonded in a linear geometry to one C(15) and one C(29) atom. The C(28)-C(29) bond length is 1.19 Å. In the twenty-third C site, C(29) is bonded in a linear geometry to one C(28) and one C(30) atom. The C(29)-C(30) bond length is 1.44 Å. In the twenty-fourth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(34) atom. The C(30)-C(31) bond length is 1.38 Å. The C(30)-C(34) bond length is 1.38 Å. In the twenty-fifth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(17) atom. The C(31)-H(17) bond length is 0.95 Å. In the twenty-sixth C site, C(34) is bonded in a distorted single-bond geometry to one C(30) and one H(20) atom. The C(34)-H(20) bond length is 0.95 Å. There are twelve inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(31) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(34) atom. In each ZnC10NH6O4 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one O(1), one O(4), one O(6), and one O(7) atom. The Zn(1)-N(1) bond length is 2.02 Å. The Zn(1)-O(1) bond length is 2.01 Å. The Zn(1)-O(4) bond length is 2.06 Å. The Zn(1)-O(6) bond length is 2.05 Å. The Zn(1)-O(7) bond length is 2.02 Å. In the second Zn site, Zn(2) is bonded in a trigonal bipyramidal geometry to one N(2), one O(2), one O(3), one O(5), and one O(8) atom. The Zn(2)-N(2) bond length is 2.04 Å. The Zn(2)-O(2) bond length is 2.07 Å. The Zn(2)-O(3) bond length is 2.01 Å. The Zn(2)-O(5) bond length is 2.01 Å. The Zn(2)-O(8) bond length is 2.11 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(18) atom. The C(32)-N(2) bond length is 1.33 Å. The C(32)-H(18) bond length is 0.95 Å. In the fourth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(19) atom. The C(33)-N(2) bond length is 1.35 Å. The C(33)-H(19) bond length is 0.95 Å. In the fifth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(36), one O(1), and one O(2) atom. The C(35)-C(36) bond length is 1.50 Å. The C(35)-O(1) bond length is 1.26 Å. The C(35)-O(2) bond length is 1.26 Å. In the sixth C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(41) atom. The C(36)-C(37) bond length is 1.39 Å. The C(36)-C(41) bond length is 1.39 Å. In the seventh C site, C(37) is bonded in a single-bond geometry to one C(36) and one H(21) atom. The C(37)-H(21) bond length is 0.95 Å. In the eighth C site, C(41) is bonded in a distorted single-bond geometry to one C(36) and one H(24) atom. The C(41)-H(24) bond length is 0.95 Å. In the ninth C site, C(44) is bonded in a distorted single-bond geometry to one C(45) and one H(26,27) atom. The C(44)-C(45) bond length is 1.39 Å. The C(44)-H(26,27) bond length is 0.95 Å. In the tenth C site, C(45) is bonded in a trigonal planar geometry to one C(44), one C(46), and one C(48) atom. The C(45)-C(46) bond length is 1.38 Å. The C(45)-C(48) bond length is 1.50 Å. In the eleventh C site, C(46) is bonded in a distorted single-bond geometry to one C(45) and one H(26,27) atom. The C(46)-H(26,27) bond length is 0.95 Å. In the twelfth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(45), one O(3), and one O(4) atom. The C(48)-O(3) bond length is 1.26 Å. The C(48)-O(4) bond length is 1.26 Å. In the thirteenth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(50), one O(5), and one O(6) atom. The C(49)-C(50) bond length is 1.50 Å. The C(49)-O(5) bond length is 1.26 Å. The C(49)-O(6) bond length is 1.25 Å. In the fourteenth C site, C(50) is bonded in a trigonal planar geometry to one C(49), one C(51), and one C(55) atom. The C(50)-C(51) bond length is 1.38 Å. The C(50)-C(55) bond length is 1.39 Å. In the fifteenth C site, C(51) is bonded in a distorted single-bond geometry to one C(50) and one H(29,32) atom. The C(51)-H(29,32) bond length is 0.95 Å. In the sixteenth C site, C(55) is bonded in a distorted single-bond geometry to one C(50) and one H(29,32) atom. The C(55)-H(29,32) bond length is 0.95 Å. In the seventeenth C site, C(58) is bonded in a distorted single-bond geometry to one C(59) and one H(34) atom. The C(58)-C(59) bond length is 1.38 Å. The C(58)-H(34) bond length is 0.95 Å. In the eighteenth C site, C(59) is bonded in a trigonal planar geometry to one C(58), one C(60), and one C(62) atom. The C(59)-C(60) bond length is 1.39 Å. The C(59)-C(62) bond length is 1.50 Å. In the nineteenth C site, C(60) is bonded in a distorted single-bond geometry to one C(59) and one H(35) atom. The C(60)-H(35) bond length is 0.95 Å. In the twentieth C site, C(62) is bonded in a bent 120 degrees geometry to one C(59), one O(7), and one O(8) atom. The C(62)-O(7) bond length is 1.26 Å. The C(62)-O(8) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(32), and one C(33) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(33) atom. In the fourth H site, H(21) is bonded in a single-bond geometry to one C(37) atom. In the fifth H site, H(24) is bonded in a single-bond geometry to one C(41) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(32) atom. In the seventh H site, H(26,27) is bonded in a single-bond geometry to one C(44) atom. In the eighth H site, H(29,32) is bonded in a single-bond geometry to one C(51) atom. In the ninth H site, H(34) is bonded in a single-bond geometry to one C(58) atom. In the tenth H site, H(35) is bonded in a single-bond geometry to one C(60) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(35) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(35) atom. In the third O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(62) atom. In the fourth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(62) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(48) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(48) atom. In the seventh O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(49) atom. In the eighth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(49) atom. Linkers: 8 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cc2)cc1 ,4 C(#C[C@]12c3ccccc3[C@](C#Cc3ccncc3)(c3ccccc31)c1ccccc12)c1ccncc1. Metal clusters: 4 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: sql. The MOF has largest included sphere 4.45 A, density 1.33 g/cm3, surface area 4593.22 m2/g, accessible volume 0.29 cm3/g