(Cu3C6H10O7)2CuC20H20(N3O2)4(CH)4 is Indium-derived structured and crystallizes in the orthorhombic F222 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, four Cu3C6H10O7 clusters, and four CuC20H20(N3O2)4 clusters. In each Cu3C6H10O7 cluster, there are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to two equivalent O(3), two equivalent O(4), and two equivalent O(6) atoms to form edge-sharing CuO6 octahedra. Both Cu(1)-O(3) bond lengths are 1.90 Å. Both Cu(1)-O(4) bond lengths are 2.17 Å. Both Cu(1)-O(6) bond lengths are 2.24 Å. In the second Cu site, Cu(2) is bonded in a rectangular see-saw-like geometry to two equivalent O(2) and two equivalent O(3) atoms. Both Cu(2)-O(2) bond lengths are 1.89 Å. Both Cu(2)-O(3) bond lengths are 1.92 Å. In the third Cu site, Cu(3) is bonded in an L-shaped geometry to two equivalent O(2) atoms. Both Cu(3)-O(2) bond lengths are 1.95 Å. There are three inequivalent C sites. In the first C site, C(2) is bonded in a distorted water-like geometry to one H(3) and one O(2) atom. The C(2)-H(3) bond length is 0.98 Å. The C(2)-O(2) bond length is 1.40 Å. In the second C site, C(3) is bonded in a distorted water-like geometry to one H(4) and one O(3) atom. The C(3)-H(4) bond length is 0.98 Å. The C(3)-O(3) bond length is 1.42 Å. In the third C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(6,7) and one O(4) atom. Both C(5)-H(6,7) bond lengths are 0.97 Å. The C(5)-O(4) bond length is 1.45 Å. There are four inequivalent H sites. In the first H site, H(6,7) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(1) is bonded in a single-bond geometry to one O(6) atom. The H(1)-O(6) bond length is 0.97 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. There are four inequivalent O sites. In the first O site, O(6) is bonded in a distorted water-like geometry to two equivalent Cu(1) and two equivalent H(1) atoms. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Cu(2), one Cu(3), and one C(2) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one Cu(2), and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(5) atom. In each CuC20H20(N3O2)4 cluster, Cu(4) is bonded in a rectangular see-saw-like geometry to four equivalent N(2) atoms. All Cu(4)-N(2) bond lengths are 2.04 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a 3-coordinate geometry to one N(1), one H(2), and one O(1) atom. The C(1)-N(1) bond length is 1.51 Å. The C(1)-H(2) bond length is 0.98 Å. The C(1)-O(1) bond length is 1.42 Å. In the second C site, C(4) is bonded in a distorted water-like geometry to one H(5) and one O(1) atom. The C(4)-H(5) bond length is 0.98 Å. The C(4)-O(1) bond length is 1.42 Å. In the third C site, C(6) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(5) atom. The C(6)-N(1) bond length is 1.36 Å. The C(6)-N(2) bond length is 1.34 Å. The C(6)-O(5) bond length is 1.27 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one N(3) atom. The C(7)-N(2) bond length is 1.35 Å. The C(7)-N(3) bond length is 1.31 Å. In the fifth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(11) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-H(11) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cu(4), one C(6), and one C(7) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(6), and one C(9) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(7) and two equivalent H(8,9) atoms. Both N(3)-H(8,9) bond lengths are 0.86 Å. There are four inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(8,9) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(2) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one C(1) and one C(4) atom. In the second O site, O(5) is bonded in a single-bond geometry to one C(6) atom. Linkers: 4 NC1=C[CH]N([C@@H]2O[C@H](C[O])[C@@H]([O])[C@H]2[O])C(=O)N1[Cu](N1C(=O)N([C@@H]2O[C@H](C[O])[C@@H]([O])[C@H]2[O])[CH]C=C1N)(N1C(=O)N([C@@H]2O[C@H](C[O])[C@@H]([O])[C@H]2[O])[CH]C=C1N)N1C(=O)N([C@@H]2O[C@H](C[O])[C@@H]([O])[C@H]2[O])[CH]C=C1N. Metal clusters: 4 O.O.[CH2]O[Cu]1(O[CH2])O[CH][CH]O[Cu]O[CH][CH]O[Cu](O[CH2])(O[CH2])O[CH][CH]O[Cu]O[CH][CH]O1.[Cu].[Cu]. RCSR code: dia. The MOF has largest included sphere 5.59 A, density 1.22 g/cm3, surface area 3505.93 m2/g, accessible volume 0.49 cm3/g