Co7C45H29(NO6)4(CH)3 crystallizes in the orthorhombic Pba2 space group. The structure consists of six 02329_fluka molecules inside a Co7C45H29(NO6)4 framework. In the Co7C45H29(NO6)4 framework, there are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(2), one O(10), one O(11), one O(4), and one O(8) atom to form a mixture of edge and corner-sharing CoNO4 square pyramids. The corner-sharing octahedral tilt angles are 58°. The Co(1)-N(2) bond length is 2.11 Å. The Co(1)-O(10) bond length is 2.09 Å. The Co(1)-O(11) bond length is 2.21 Å. The Co(1)-O(4) bond length is 2.03 Å. The Co(1)-O(8) bond length is 2.07 Å. In the second Co site, Co(2) is bonded to one O(11), one O(12), one O(2), one O(3), and two equivalent O(4) atoms to form CoO6 octahedra that share  a cornercorner with one Co(3)O6 octahedra,  a cornercorner with one Co(1)NO4 square pyramid,  an edgeedge with one Co(4)NO5 octahedra,  an edgeedge with one Co(2)O6 octahedra, and  an edgeedge with one Co(1)NO4 square pyramid. The corner-sharing octahedral tilt angles are 53°. The Co(2)-O(11) bond length is 2.11 Å. The Co(2)-O(12) bond length is 2.09 Å. The Co(2)-O(2) bond length is 2.13 Å. The Co(2)-O(3) bond length is 2.07 Å. There is one shorter (2.04 Å) and one longer (2.11 Å) Co(2)-O(4) bond length. In the third Co site, Co(3) is bonded to two equivalent O(3), two equivalent O(6), and two equivalent O(9) atoms to form CoO6 octahedra that share corners with two equivalent Co(4)NO5 octahedra and corners with two equivalent Co(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 53-60°. Both Co(3)-O(3) bond lengths are 2.07 Å. Both Co(3)-O(6) bond lengths are 2.11 Å. Both Co(3)-O(9) bond lengths are 2.11 Å. In the fourth Co site, Co(4) is bonded to one N(1), one O(1), one O(2), one O(3), one O(5), and one O(7) atom to form a mixture of edge and corner-sharing CoNO5 octahedra. The corner-sharing octahedral tilt angles are 60°. The Co(4)-N(1) bond length is 2.14 Å. The Co(4)-O(1) bond length is 2.13 Å. The Co(4)-O(2) bond length is 2.22 Å. The Co(4)-O(3) bond length is 2.04 Å. The Co(4)-O(5) bond length is 2.16 Å. The Co(4)-O(7) bond length is 2.05 Å. There are twenty-three inequivalent C sites. In the first C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(2), and one O(8) atom. The C(23)-C(19) bond length is 1.50 Å. The C(23)-O(2) bond length is 1.28 Å. The C(23)-O(8) bond length is 1.25 Å. In the second C site, C(24) is bonded in a distorted single-bond geometry to two equivalent C(21) and one H(10) atom. Both C(24)-C(21) bond lengths are 1.39 Å. The C(24)-H(10) bond length is 0.93 Å. In the third C site, C(1) is bonded in a distorted single-bond geometry to one C(21) and one H(14) atom. The C(1)-C(21) bond length is 1.37 Å. The C(1)-H(14) bond length is 0.93 Å. In the fourth C site, C(2) is bonded in a trigonal planar geometry to one C(13), one C(16), and one C(18) atom. The C(2)-C(13) bond length is 1.53 Å. The C(2)-C(16) bond length is 1.36 Å. The C(2)-C(18) bond length is 1.35 Å. In the fifth C site, C(3) is bonded in a distorted single-bond geometry to one C(17) and one H(7) atom. The C(3)-C(17) bond length is 1.38 Å. The C(3)-H(7) bond length is 0.93 Å. In the sixth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(7), and one O(9) atom. The C(4)-C(17) bond length is 1.53 Å. The C(4)-O(7) bond length is 1.25 Å. The C(4)-O(9) bond length is 1.24 Å. In the seventh C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(5)-N(2) bond length is 1.34 Å. The C(5)-H(9) bond length is 0.93 Å. In the eighth C site, C(6) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(20) atom. The C(6)-C(14) bond length is 1.38 Å. The C(6)-C(15) bond length is 1.51 Å. The C(6)-C(20) bond length is 1.38 Å. In the ninth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(15) atom. The C(7)-C(12) bond length is 1.37 Å. The C(7)-N(2) bond length is 1.33 Å. The C(7)-H(15) bond length is 0.93 Å. In the tenth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(12), and one O(5) atom. The C(9)-C(21) bond length is 1.50 Å. The C(9)-O(12) bond length is 1.24 Å. The C(9)-O(5) bond length is 1.27 Å. In the eleventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(10)-N(1) bond length is 1.31 Å. The C(10)-H(4) bond length is 0.93 Å. In the twelfth C site, C(11) is bonded in a distorted single-bond geometry to one C(19) and one H(5) atom. The C(11)-C(19) bond length is 1.38 Å. The C(11)-H(5) bond length is 0.93 Å. In the thirteenth C site, C(12) is bonded in a single-bond geometry to one C(19), one C(7), and one H(1) atom. The C(12)-C(19) bond length is 1.39 Å. The C(12)-H(1) bond length is 0.93 Å. In the fourteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(6) atom. The C(13)-O(1) bond length is 1.23 Å. The C(13)-O(6) bond length is 1.26 Å. In the fifteenth C site, C(14) is bonded in a single-bond geometry to one C(6) and one H(13) atom. The C(14)-H(13) bond length is 0.93 Å. In the sixteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(10), and one O(11) atom. The C(15)-O(10) bond length is 1.25 Å. The C(15)-O(11) bond length is 1.25 Å. In the seventeenth C site, C(16) is bonded in a distorted single-bond geometry to one C(2) and one H(12) atom. The C(16)-H(12) bond length is 0.93 Å. In the eighteenth C site, C(17) is bonded in a trigonal planar geometry to one C(20), one C(3), and one C(4) atom. The C(17)-C(20) bond length is 1.38 Å. In the nineteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(2) and one H(11) atom. The C(18)-H(11) bond length is 0.93 Å. In the twentieth C site, C(19) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(23) atom. In the twenty-first C site, C(20) is bonded in a distorted single-bond geometry to one C(17), one C(6), and one H(3) atom. The C(20)-H(3) bond length is 0.93 Å. In the twenty-second C site, C(21) is bonded in a trigonal planar geometry to one C(1), one C(24), and one C(9) atom. In the twenty-third C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(22)-N(1) bond length is 1.32 Å. The C(22)-H(8) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(4), one C(10), and one C(22) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(5), and one C(7) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(20) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one O(3) atom. The H(6)-O(3) bond length is 0.98 Å. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(1) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(7) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one O(4) atom. The H(16)-O(4) bond length is 0.98 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Co(4) and one C(13) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Co(2), one Co(4), and one C(23) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Co(2), one Co(3), one Co(4), and one H(6) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Co(1), two equivalent Co(2), and one H(16) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Co(4) and one C(9) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Co(3) and one C(13) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Co(4) and one C(4) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(23) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Co(3) and one C(4) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(15) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Co(1), one Co(2), and one C(15) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Co(2) and one C(9) atom. Linkers: 6 [O]C(=O)c1cccc(C([O])=O)c1 ,8 [O]C(=O)c1ccncc1. Metal clusters: 2 O[Co]1O[C]O[Co]2O[C]O[Co](O)O[C]O[Co](O[C]O1)O[C]O[Co@]1(O)O[C]O[Co]3(O[C]O[Co@@](O)(O[C]O2)O[C]O3)O[C]O1. The MOF has largest included sphere 6.49 A, density 1.34 g/cm3, surface area 3324.21 m2/g, accessible volume 0.34 cm3/g