CuC30H22(N2O)2(CH)4 is Indium-derived structured and crystallizes in the tetragonal P4_222 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and two CuC30H22(N2O)2 clusters. In each CuC30H22(N2O)2 cluster, Cu(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Cu(1)-N(1) bond lengths are 2.02 Å. Both Cu(1)-N(2) bond lengths are 2.02 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(4) bond length is 1.38 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(7) atom. The C(2)-C(2) bond length is 1.46 Å. The C(2)-C(7) bond length is 1.42 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(9) atom. The C(3)-C(4) bond length is 1.48 Å. The C(3)-C(5) bond length is 1.39 Å. The C(3)-C(9) bond length is 1.36 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(8) atom. The C(4)-C(8) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a single-bond geometry to one C(3) and one H(2) atom. The C(5)-H(2) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-H(3) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one O(1) atom. The C(7)-O(1) bond length is 1.36 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(8)-H(4) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(9)-H(5) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(10)-N(1) bond length is 1.32 Å. The C(10)-H(6) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(2), and one H(7) atom. The C(11)-C(12) bond length is 1.36 Å. The C(11)-N(2) bond length is 1.35 Å. The C(11)-H(7) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(17) atom. The C(12)-C(15) bond length is 1.50 Å. The C(12)-C(17) bond length is 1.42 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(14)-N(2) bond length is 1.33 Å. The C(14)-H(9) bond length is 0.93 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one C(12), one H(10), one H(11), and one O(1) atom. The C(15)-H(10) bond length is 0.97 Å. The C(15)-H(11) bond length is 0.97 Å. The C(15)-O(1) bond length is 1.39 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(12) and one H(13) atom. The C(17)-H(13) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(14) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(17) atom. O(1) is bonded in a bent 120 degrees geometry to one C(15) and one C(7) atom. Linkers: 8 [c]1cc(-c2ccc(OCc3cccnc3)c(-c3cc(-c4ccncc4)ccc3OCc3cccnc3)c2)ccn1 ,4 c1cncc(COc2ccc(-c3ccncc3)cc2-c2cc(-c3ccncc3)ccc2OCc2cccnc2)c1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 7.29 A, density 0.85 g/cm3, surface area 4922.79 m2/g, accessible volume 0.64 cm3/g