AgH24(C3N)4 is Indium-like structured and crystallizes in the cubic Fd-3m space group. The structure is zero-dimensional and consists of one hundred and thirty-six AgH24(C3N)4 clusters. Ag(1) is bonded in a tetrahedral geometry to four equivalent N(2) atoms. All Ag(1)-N(2) bond lengths are 2.35 Å. C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent H(1) atoms. The C(7)-N(2) bond length is 1.47 Å. Both C(7)-H(1) bond lengths are 0.99 Å. N(2) is bonded to one Ag(1) and three equivalent C(7) atoms to form corner-sharing NAgC3 tetrahedra. H(1) is bonded in a single-bond geometry to one C(7) atom. Linkers: 272 C1CN2CCN1CC2. Metal clusters: 136 [Ag]. The MOF has largest included sphere 16.94 A, density 0.79 g/cm3, surface area 4488.13 m2/g, accessible volume 0.78 cm3/g