CuC10NH6O4C3H2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 2,3-dimethyl-1,3-butadiene molecules and four CuC10NH6O4 clusters. In each CuC10NH6O4 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square pyramidal geometry to one N(4), one O(1), one O(3), one O(5), and one O(7) atom. The Cu(1)-N(4) bond length is 2.16 Å. The Cu(1)-O(1) bond length is 1.96 Å. The Cu(1)-O(3) bond length is 1.98 Å. The Cu(1)-O(5) bond length is 1.96 Å. The Cu(1)-O(7) bond length is 1.97 Å. In the second Cu site, Cu(2) is bonded in a distorted square pyramidal geometry to one N(1), one O(2), one O(4), one O(6), and one O(8) atom. The Cu(2)-N(1) bond length is 2.18 Å. The Cu(2)-O(2) bond length is 2.00 Å. The Cu(2)-O(4) bond length is 1.95 Å. The Cu(2)-O(6) bond length is 1.99 Å. The Cu(2)-O(8) bond length is 1.94 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(1), and one O(2) atom. The C(1)-C(9) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(3), and one O(4) atom. The C(2)-C(15) bond length is 1.50 Å. The C(2)-O(3) bond length is 1.26 Å. The C(2)-O(4) bond length is 1.26 Å. In the third C site, C(3) is bonded in a bent 120 degrees geometry to one C(21), one O(5), and one O(6) atom. The C(3)-C(21) bond length is 1.49 Å. The C(3)-O(5) bond length is 1.26 Å. The C(3)-O(6) bond length is 1.26 Å. In the fourth C site, C(4) is bonded in a bent 120 degrees geometry to one C(18), one O(7), and one O(8) atom. The C(4)-C(18) bond length is 1.50 Å. The C(4)-O(7) bond length is 1.26 Å. The C(4)-O(8) bond length is 1.26 Å. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(14) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-C(14) bond length is 1.38 Å. In the sixth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(1) atom. The C(10)-H(1) bond length is 0.94 Å. In the seventh C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(14)-H(4) bond length is 0.94 Å. In the eighth C site, C(15) is bonded in a trigonal planar geometry to one C(16), one C(2), and one C(20) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-C(20) bond length is 1.40 Å. In the ninth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(5,8,13) atom. The C(16)-H(5,8,13) bond length is 0.94 Å. In the tenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(6,7) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(6,7) bond length is 0.94 Å. In the eleventh C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(4) atom. The C(18)-C(19) bond length is 1.39 Å. In the twelfth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(6,7) atom. The C(19)-H(6,7) bond length is 0.94 Å. In the thirteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(15) and one H(5,8,13) atom. The C(20)-H(5,8,13) bond length is 0.94 Å. In the fourteenth C site, C(21) is bonded in a trigonal planar geometry to one C(22), one C(26), and one C(3) atom. The C(21)-C(22) bond length is 1.37 Å. The C(21)-C(26) bond length is 1.36 Å. In the fifteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(9) atom. The C(22)-H(9) bond length is 0.94 Å. In the sixteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(21) and one H(12) atom. The C(26)-H(12) bond length is 0.94 Å. In the seventeenth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(17) atom. The C(33)-N(1) bond length is 1.33 Å. The C(33)-H(17) bond length is 0.94 Å. In the eighteenth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(20) atom. The C(37)-N(1) bond length is 1.33 Å. The C(37)-H(20) bond length is 0.94 Å. In the nineteenth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(29) atom. The C(48)-N(4) bond length is 1.33 Å. The C(48)-H(29) bond length is 0.94 Å. In the twentieth C site, C(52) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(32) atom. The C(52)-N(4) bond length is 1.32 Å. The C(52)-H(32) bond length is 0.94 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(2), one C(33), and one C(37) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(48), and one C(52) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(5,8,13) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(6,7) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(22) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(26) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(33) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(37) atom. In the ninth H site, H(29) is bonded in a single-bond geometry to one C(48) atom. In the tenth H site, H(32) is bonded in a single-bond geometry to one C(52) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(3) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(4) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(4) atom. Linkers: 8 [O]C(=O)c1ccc(C([O])=O)cc1 ,4 c1cc(-c2ccncc2)ccn1. Metal clusters: 4 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 5.82 A, density 1.24 g/cm3, surface area 4088.54 m2/g, accessible volume 0.34 cm3/g