CoC19H15(N3O)2(CH2)4C9H6N is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, four schembl1705614 molecules, and four CoC19H15(N3O)2 clusters. In each CoC19H15(N3O)2 cluster, Co(1) is bonded in a distorted square pyramidal geometry to one N(1), one N(3), one N(5), one O(1), and one O(2) atom. The Co(1)-N(1) bond length is 2.07 Å. The Co(1)-N(3) bond length is 2.11 Å. The Co(1)-N(5) bond length is 2.11 Å. The Co(1)-O(1) bond length is 2.13 Å. The Co(1)-O(2) bond length is 2.45 Å. There are nineteen inequivalent C sites. In the first C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(15), and one N(2) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-C(15) bond length is 1.35 Å. The C(10)-N(2) bond length is 1.42 Å. In the second C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(10) atom. The C(11)-H(10) bond length is 0.93 Å. In the third C site, C(9) is bonded in a distorted trigonal planar geometry to one C(8), one N(5), and one H(9) atom. The C(9)-C(8) bond length is 1.38 Å. The C(9)-N(5) bond length is 1.36 Å. The C(9)-H(9) bond length is 0.93 Å. In the fourth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one N(6) atom. The C(19)-C(18) bond length is 1.39 Å. The C(19)-C(20) bond length is 1.39 Å. The C(19)-N(6) bond length is 1.41 Å. In the fifth C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one H(13) atom. The C(15)-H(13) bond length is 0.93 Å. In the sixth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(15,16) atom. The C(18)-H(15,16) bond length is 0.93 Å. In the seventh C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one C(26), and one N(4) atom. The C(25)-C(24) bond length is 1.38 Å. The C(25)-C(26) bond length is 1.38 Å. The C(25)-N(4) bond length is 1.42 Å. In the eighth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(15,16) atom. The C(20)-H(15,16) bond length is 0.93 Å. In the ninth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(19) atom. The C(24)-H(19) bond length is 0.93 Å. In the tenth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(20) atom. The C(26)-H(20) bond length is 0.93 Å. In the eleventh C site, C(28) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(28)-O(1) bond length is 1.26 Å. The C(28)-O(2) bond length is 1.24 Å. In the twelfth C site, C(2) is bonded in a 3-coordinate geometry to one C(1), one N(2), and one H(2) atom. The C(2)-C(1) bond length is 1.34 Å. The C(2)-N(2) bond length is 1.36 Å. The C(2)-H(2) bond length is 0.93 Å. In the thirteenth C site, C(5) is bonded in a 3-coordinate geometry to one C(4), one N(4), and one H(5) atom. The C(5)-C(4) bond length is 1.32 Å. The C(5)-N(4) bond length is 1.36 Å. The C(5)-H(5) bond length is 0.93 Å. In the fourteenth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-H(1) bond length is 0.93 Å. In the fifteenth C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. The C(3)-N(1) bond length is 1.29 Å. The C(3)-N(2) bond length is 1.34 Å. The C(3)-H(3) bond length is 0.93 Å. In the sixteenth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one N(3), and one H(4) atom. The C(4)-N(3) bond length is 1.37 Å. The C(4)-H(4) bond length is 0.93 Å. In the seventeenth C site, C(6) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(6) atom. The C(6)-N(3) bond length is 1.33 Å. The C(6)-N(4) bond length is 1.33 Å. The C(6)-H(6) bond length is 0.93 Å. In the eighteenth C site, C(7) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(7) atom. The C(7)-N(5) bond length is 1.30 Å. The C(7)-N(6) bond length is 1.34 Å. The C(7)-H(7) bond length is 0.93 Å. In the nineteenth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(6), and one H(8) atom. The C(8)-N(6) bond length is 1.37 Å. The C(8)-H(8) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(6) is bonded in a trigonal planar geometry to one C(19), one C(7), and one C(8) atom. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to one Co(1), one C(1), and one C(3) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Co(1), one C(4), and one C(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(25), one C(5), and one C(6) atom. In the fifth N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(3) atom. In the sixth N site, N(5) is bonded in a trigonal planar geometry to one Co(1), one C(7), and one C(9) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(15,16) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(26) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Co(1) and one C(28) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Co(1) and one C(28) atom. Linkers: 1 [O]C(=O)CCCCCCCCC([O])=O. Metal clusters: 2 [Co]. The MOF has largest included sphere 5.05 A, density 1.13 g/cm3, surface area 5128.45 m2/g, accessible volume 0.31 cm3/g