CuC11NH7O3(CH)4 crystallizes in the trigonal R-3 space group. The structure consists of two hundred and eighty-eight 02329_fluka molecules inside a CuC11NH7O3 framework. In the CuC11NH7O3 framework, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one O(1), one O(10), and one O(9) atom. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-O(1) bond length is 1.94 Å. The Cu(1)-O(10) bond length is 1.91 Å. The Cu(1)-O(9) bond length is 1.90 Å. In the second Cu site, Cu(2) is bonded in a rectangular see-saw-like geometry to one N(2), one O(10), one O(7), and one O(9) atom. The Cu(2)-N(2) bond length is 2.01 Å. The Cu(2)-O(10) bond length is 1.92 Å. The Cu(2)-O(7) bond length is 1.93 Å. The Cu(2)-O(9) bond length is 1.90 Å. In the third Cu site, Cu(3) is bonded in a rectangular see-saw-like geometry to one N(3), one O(11), one O(12), and one O(3) atom. The Cu(3)-N(3) bond length is 1.99 Å. The Cu(3)-O(11) bond length is 1.92 Å. The Cu(3)-O(12) bond length is 1.91 Å. The Cu(3)-O(3) bond length is 1.93 Å. In the fourth Cu site, Cu(4) is bonded in a rectangular see-saw-like geometry to one N(4), one O(11), one O(12), and one O(5) atom. The Cu(4)-N(4) bond length is 2.01 Å. The Cu(4)-O(11) bond length is 1.90 Å. The Cu(4)-O(12) bond length is 1.90 Å. The Cu(4)-O(5) bond length is 1.95 Å. There are forty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.43 Å. The C(1)-C(6) bond length is 1.42 Å. The C(1)-N(1) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.43 Å. The C(5)-H(4) bond length is 0.93 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.40 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. The C(7)-C(8) bond length is 1.51 Å. The C(7)-C(9) bond length is 1.41 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(1), and one O(2) atom. The C(8)-O(1) bond length is 1.27 Å. The C(8)-O(2) bond length is 1.21 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(7) atom. The C(9)-C(10) bond length is 1.42 Å. The C(9)-C(14) bond length is 1.43 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(10)-H(5) bond length is 0.93 Å. In the ninth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(8) atom. The C(13)-C(14) bond length is 1.43 Å. The C(13)-H(8) bond length is 0.93 Å. In the tenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(9), and one N(1) atom. The C(14)-N(1) bond length is 1.36 Å. In the eleventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one C(20), and one N(2) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(20) bond length is 1.44 Å. The C(15)-N(2) bond length is 1.35 Å. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(9) atom. The C(16)-H(9) bond length is 0.93 Å. In the thirteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(20) and one H(12) atom. The C(19)-C(20) bond length is 1.43 Å. The C(19)-H(12) bond length is 0.93 Å. In the fourteenth C site, C(20) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(21) atom. The C(20)-C(21) bond length is 1.39 Å. In the fifteenth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(23) atom. The C(21)-C(22) bond length is 1.51 Å. The C(21)-C(23) bond length is 1.40 Å. In the sixteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(3), and one O(4) atom. The C(22)-O(3) bond length is 1.27 Å. The C(22)-O(4) bond length is 1.21 Å. In the seventeenth C site, C(23) is bonded in a trigonal planar geometry to one C(21), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.42 Å. The C(23)-C(28) bond length is 1.43 Å. In the eighteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(13) atom. The C(24)-C(25) bond length is 1.35 Å. The C(24)-H(13) bond length is 0.93 Å. In the nineteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one C(26), and one H(14) atom. The C(25)-C(26) bond length is 1.43 Å. The C(25)-H(14) bond length is 0.93 Å. In the twentieth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(15) atom. The C(26)-H(15) bond length is 0.93 Å. In the twenty-first C site, C(27) is bonded in a distorted single-bond geometry to one C(28) and one H(16) atom. The C(27)-C(28) bond length is 1.42 Å. The C(27)-H(16) bond length is 0.93 Å. In the twenty-second C site, C(28) is bonded in a distorted trigonal planar geometry to one C(23), one C(27), and one N(2) atom. The C(28)-N(2) bond length is 1.35 Å. In the twenty-third C site, C(29) is bonded in a distorted single-bond geometry to one C(34) and one N(3) atom. The C(29)-C(34) bond length is 1.43 Å. The C(29)-N(3) bond length is 1.36 Å. In the twenty-fourth C site, C(33) is bonded in a distorted single-bond geometry to one C(34) and one H(20) atom. The C(33)-C(34) bond length is 1.42 Å. The C(33)-H(20) bond length is 0.93 Å. In the twenty-fifth C site, C(34) is bonded in a trigonal planar geometry to one C(29), one C(33), and one C(35) atom. The C(34)-C(35) bond length is 1.39 Å. In the twenty-sixth C site, C(35) is bonded in a trigonal planar geometry to one C(34), one C(36), and one C(37) atom. The C(35)-C(36) bond length is 1.50 Å. The C(35)-C(37) bond length is 1.40 Å. In the twenty-seventh C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(5), and one O(6) atom. The C(36)-O(5) bond length is 1.27 Å. The C(36)-O(6) bond length is 1.22 Å. In the twenty-eighth C site, C(37) is bonded in a trigonal planar geometry to one C(35), one C(38), and one C(42) atom. The C(37)-C(38) bond length is 1.41 Å. The C(37)-C(42) bond length is 1.42 Å. In the twenty-ninth C site, C(38) is bonded in a distorted single-bond geometry to one C(37) and one H(21) atom. The C(38)-H(21) bond length is 0.93 Å. In the thirtieth C site, C(41) is bonded in a distorted single-bond geometry to one C(42) and one H(24) atom. The C(41)-C(42) bond length is 1.42 Å. The C(41)-H(24) bond length is 0.93 Å. In the thirty-first C site, C(42) is bonded in a distorted trigonal planar geometry to one C(37), one C(41), and one N(3) atom. The C(42)-N(3) bond length is 1.36 Å. In the thirty-second C site, C(43) is bonded in a distorted trigonal planar geometry to one C(44), one C(48), and one N(4) atom. The C(43)-C(44) bond length is 1.42 Å. The C(43)-C(48) bond length is 1.43 Å. The C(43)-N(4) bond length is 1.35 Å. In the thirty-third C site, C(44) is bonded in a distorted single-bond geometry to one C(43) and one H(25) atom. The C(44)-H(25) bond length is 0.93 Å. In the thirty-fourth C site, C(47) is bonded in a distorted single-bond geometry to one C(48) and one H(28) atom. The C(47)-C(48) bond length is 1.42 Å. The C(47)-H(28) bond length is 0.93 Å. In the thirty-fifth C site, C(48) is bonded in a trigonal planar geometry to one C(43), one C(47), and one C(49) atom. The C(48)-C(49) bond length is 1.40 Å. In the thirty-sixth C site, C(49) is bonded in a trigonal planar geometry to one C(48), one C(50), and one C(51) atom. The C(49)-C(50) bond length is 1.51 Å. The C(49)-C(51) bond length is 1.40 Å. In the thirty-seventh C site, C(50) is bonded in a distorted bent 120 degrees geometry to one C(49), one O(7), and one O(8) atom. The C(50)-O(7) bond length is 1.28 Å. The C(50)-O(8) bond length is 1.23 Å. In the thirty-eighth C site, C(51) is bonded in a trigonal planar geometry to one C(49), one C(52), and one C(56) atom. The C(51)-C(52) bond length is 1.43 Å. The C(51)-C(56) bond length is 1.43 Å. In the thirty-ninth C site, C(52) is bonded in a distorted single-bond geometry to one C(51) and one H(29) atom. The C(52)-H(29) bond length is 0.93 Å. In the fortieth C site, C(56) is bonded in a distorted single-bond geometry to one C(51) and one N(4) atom. The C(56)-N(4) bond length is 1.35 Å. In the forty-first C site, C(57) is bonded in a tetrahedral geometry to one H(33), one H(34), one H(35), and one O(9) atom. The C(57)-H(33) bond length is 0.96 Å. The C(57)-H(34) bond length is 0.96 Å. The C(57)-H(35) bond length is 0.96 Å. The C(57)-O(9) bond length is 1.42 Å. In the forty-second C site, C(58) is bonded in a tetrahedral geometry to one H(36); two equivalent H(37,38); and one O(10) atom. The C(58)-H(36) bond length is 0.96 Å. Both C(58)-H(37,38) bond lengths are 0.96 Å. The C(58)-O(10) bond length is 1.39 Å. In the forty-third C site, C(59) is bonded in a tetrahedral geometry to one H(39), one H(40), one H(41), and one O(11) atom. The C(59)-H(39) bond length is 0.96 Å. The C(59)-H(40) bond length is 0.96 Å. The C(59)-H(41) bond length is 0.96 Å. The C(59)-O(11) bond length is 1.40 Å. In the forty-fourth C site, C(60) is bonded in a tetrahedral geometry to one H(42), one H(43), one H(44), and one O(12) atom. The C(60)-H(42) bond length is 0.96 Å. The C(60)-H(43) bond length is 0.96 Å. The C(60)-H(44) bond length is 0.96 Å. The C(60)-O(12) bond length is 1.43 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(14) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(15), and one C(28) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(3), one C(29), and one C(42) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(4), one C(43), and one C(56) atom. There are twenty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(33) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(38) atom. In the thirteenth H site, H(24) is bonded in a single-bond geometry to one C(41) atom. In the fourteenth H site, H(25) is bonded in a single-bond geometry to one C(44) atom. In the fifteenth H site, H(28) is bonded in a single-bond geometry to one C(47) atom. In the sixteenth H site, H(29) is bonded in a single-bond geometry to one C(52) atom. In the seventeenth H site, H(33) is bonded in a single-bond geometry to one C(57) atom. In the eighteenth H site, H(34) is bonded in a single-bond geometry to one C(57) atom. In the nineteenth H site, H(35) is bonded in a single-bond geometry to one C(57) atom. In the twentieth H site, H(36) is bonded in a single-bond geometry to one C(58) atom. In the twenty-first H site, H(37,38) is bonded in a single-bond geometry to one C(58) atom. In the twenty-second H site, H(39) is bonded in a single-bond geometry to one C(59) atom. In the twenty-third H site, H(40) is bonded in a single-bond geometry to one C(59) atom. In the twenty-fourth H site, H(41) is bonded in a single-bond geometry to one C(59) atom. In the twenty-fifth H site, H(42) is bonded in a single-bond geometry to one C(60) atom. In the twenty-sixth H site, H(43) is bonded in a single-bond geometry to one C(60) atom. In the twenty-seventh H site, H(44) is bonded in a single-bond geometry to one C(60) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(8) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(8) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(22) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(22) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(36) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(36) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(50) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(50) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Cu(1), one Cu(2), and one C(57) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Cu(1), one Cu(2), and one C(58) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Cu(3), one Cu(4), and one C(59) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Cu(3), one Cu(4), and one C(60) atom. Linkers: 24 [O]C(=O)c1c2ccccc2nc2ccccc12. Metal clusters: 12 CO[Cu](OC)O[C]=O.O=[C]O[Cu]. The MOF has largest included sphere 5.08 A, density 1.28 g/cm3, surface area 4558.25 m2/g, accessible volume 0.31 cm3/g