KC7PN3H12O8ClCoC42N7H47O(CH2)7CH3(CONH2)3C2NH4OCH2O is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of twenty-eight 02329_fluka molecules, four 02329_fluka molecules, four acetamide molecules, twelve formamide molecules, four methanol molecules, four CoC42N7H47O clusters, and four KC7PN3H12O8Cl clusters. In each CoC42N7H47O cluster, Co(1) is bonded to one C(1), one N(14), one N(2), one N(3), one N(4), and one N(5) atom to form CoCN5 octahedra that share  a cornercorner with one C(2)C3N tetrahedra. The Co(1)-C(1) bond length is 1.87 Å. The Co(1)-N(14) bond length is 2.03 Å. The Co(1)-N(2) bond length is 1.86 Å. The Co(1)-N(3) bond length is 1.90 Å. The Co(1)-N(4) bond length is 1.91 Å. The Co(1)-N(5) bond length is 1.90 Å. There are forty-two inequivalent C sites. In the first C site, C(1) is bonded in a linear geometry to one Co(1) and one N(1) atom. The C(1)-N(1) bond length is 1.14 Å. In the second C site, C(2) is bonded to one C(20), one C(21), one C(3), and one N(2) atom to form distorted CC3N tetrahedra that share  a cornercorner with one Co(1)CN5 octahedra. The corner-sharing octahedral tilt angles are 63°. The C(2)-C(20) bond length is 1.52 Å. The C(2)-C(21) bond length is 1.56 Å. The C(2)-C(3) bond length is 1.57 Å. The C(2)-N(2) bond length is 1.51 Å. In the third C site, C(3) is bonded in a tetrahedral geometry to one C(2), one C(22), one C(23), and one C(4) atom. The C(3)-C(22) bond length is 1.55 Å. The C(3)-C(23) bond length is 1.56 Å. The C(3)-C(4) bond length is 1.56 Å. In the fourth C site, C(4) is bonded in a single-bond geometry to one C(3) and one H(1) atom. The C(4)-H(1) bond length is 1.00 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one N(2) atom. The C(5)-C(6) bond length is 1.43 Å. The C(5)-N(2) bond length is 1.31 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(28), one C(5), and one C(7) atom. The C(6)-C(28) bond length is 1.57 Å. The C(6)-C(7) bond length is 1.34 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(3) atom. The C(7)-C(8) bond length is 1.53 Å. The C(7)-N(3) bond length is 1.44 Å. In the eighth C site, C(8) is bonded in a tetrahedral geometry to one C(29), one C(30), one C(7), and one C(9) atom. The C(8)-C(29) bond length is 1.55 Å. The C(8)-C(30) bond length is 1.56 Å. The C(8)-C(9) bond length is 1.54 Å. In the ninth C site, C(9) is bonded in a single-bond geometry to one C(10), one C(8), and one H(2) atom. The C(9)-C(10) bond length is 1.52 Å. The C(9)-H(2) bond length is 1.00 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one N(3) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-N(3) bond length is 1.33 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(3) atom. The C(11)-C(12) bond length is 1.37 Å. The C(11)-H(3) bond length is 0.95 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one N(4) atom. The C(12)-C(13) bond length is 1.51 Å. The C(12)-N(4) bond length is 1.37 Å. In the thirteenth C site, C(13) is bonded in a tetrahedral geometry to one C(12), one C(14), one C(35), and one C(36) atom. The C(13)-C(14) bond length is 1.55 Å. The C(13)-C(35) bond length is 1.55 Å. The C(13)-C(36) bond length is 1.56 Å. In the fourteenth C site, C(14) is bonded in a single-bond geometry to one C(13), one C(15), and one H(4) atom. The C(14)-C(15) bond length is 1.54 Å. The C(14)-H(4) bond length is 1.00 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one N(4) atom. The C(15)-C(16) bond length is 1.35 Å. The C(15)-N(4) bond length is 1.40 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(40) atom. The C(16)-C(17) bond length is 1.48 Å. The C(16)-C(40) bond length is 1.53 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one N(5) atom. The C(17)-C(18) bond length is 1.53 Å. The C(17)-N(5) bond length is 1.30 Å. In the eighteenth C site, C(18) is bonded in a tetrahedral geometry to one C(17), one C(19), one C(41), and one C(42) atom. The C(18)-C(19) bond length is 1.59 Å. The C(18)-C(41) bond length is 1.55 Å. The C(18)-C(42) bond length is 1.53 Å. In the nineteenth C site, C(19) is bonded in a single-bond geometry to one C(18) and one H(5) atom. The C(19)-H(5) bond length is 1.00 Å. In the twentieth C site, C(20) is bonded in a 2-coordinate geometry to one C(2), one N(5), and one H(6) atom. The C(20)-N(5) bond length is 1.48 Å. The C(20)-H(6) bond length is 1.00 Å. In the twenty-first C site, C(21) is bonded in a trigonal non-coplanar geometry to one C(2); one H(9); and two equivalent H(7,8) atoms. The C(21)-H(9) bond length is 0.98 Å. Both C(21)-H(7,8) bond lengths are 0.98 Å. In the twenty-second C site, C(22) is bonded in a trigonal non-coplanar geometry to one C(3); one H(12); and two equivalent H(10,11) atoms. The C(22)-H(12) bond length is 0.98 Å. Both C(22)-H(10,11) bond lengths are 0.98 Å. In the twenty-third C site, C(23) is bonded in a water-like geometry to one C(3) and two equivalent H(13,14) atoms. Both C(23)-H(13,14) bond lengths are 0.99 Å. In the twenty-fourth C site, C(28) is bonded in a trigonal non-coplanar geometry to one C(6), one H(23), one H(24), and one H(25) atom. The C(28)-H(23) bond length is 0.98 Å. The C(28)-H(24) bond length is 0.98 Å. The C(28)-H(25) bond length is 0.98 Å. In the twenty-fifth C site, C(29) is bonded in a trigonal non-coplanar geometry to one C(8), one H(26), one H(27), and one H(28) atom. The C(29)-H(26) bond length is 0.98 Å. The C(29)-H(27) bond length is 0.98 Å. The C(29)-H(28) bond length is 0.98 Å. In the twenty-sixth C site, C(30) is bonded in a water-like geometry to one C(8) and two equivalent H(29,30) atoms. Both C(30)-H(29,30) bond lengths are 0.99 Å. In the twenty-seventh C site, C(35) is bonded in a trigonal non-coplanar geometry to one C(13); one H(40); and two equivalent H(39,41) atoms. The C(35)-H(40) bond length is 0.98 Å. Both C(35)-H(39,41) bond lengths are 0.98 Å. In the twenty-eighth C site, C(36) is bonded in a trigonal non-coplanar geometry to one C(13); one H(44); and two equivalent H(42,43) atoms. The C(36)-H(44) bond length is 0.98 Å. Both C(36)-H(42,43) bond lengths are 0.98 Å. In the twenty-ninth C site, C(40) is bonded in a trigonal non-coplanar geometry to one C(16); one H(53); and two equivalent H(51,52) atoms. The C(40)-H(53) bond length is 0.98 Å. Both C(40)-H(51,52) bond lengths are 0.98 Å. In the thirtieth C site, C(41) is bonded in a trigonal non-coplanar geometry to one C(18), one H(54), one H(55), and one H(56) atom. The C(41)-H(54) bond length is 0.98 Å. The C(41)-H(55) bond length is 0.98 Å. The C(41)-H(56) bond length is 0.98 Å. In the thirty-first C site, C(42) is bonded in a water-like geometry to one C(18), one H(57), and one H(58) atom. The C(42)-H(57) bond length is 0.99 Å. The C(42)-H(58) bond length is 0.99 Å. In the thirty-second C site, C(50) is bonded in a 3-coordinate geometry to one N(13), one H(72), and one O(12) atom. The C(50)-N(13) bond length is 1.46 Å. The C(50)-H(72) bond length is 1.00 Å. The C(50)-O(12) bond length is 1.42 Å. In the thirty-third C site, C(53) is bonded in a distorted water-like geometry to one H(75) and one O(12) atom. The C(53)-H(75) bond length is 1.00 Å. The C(53)-O(12) bond length is 1.46 Å. In the thirty-fourth C site, C(55) is bonded in a trigonal planar geometry to one N(13), one N(14), and one H(80) atom. The C(55)-N(13) bond length is 1.37 Å. The C(55)-N(14) bond length is 1.30 Å. The C(55)-H(80) bond length is 0.95 Å. In the thirty-fifth C site, C(56) is bonded in a distorted single-bond geometry to one C(57), one C(61), and one H(81) atom. The C(56)-C(57) bond length is 1.37 Å. The C(56)-C(61) bond length is 1.41 Å. The C(56)-H(81) bond length is 0.95 Å. In the thirty-sixth C site, C(57) is bonded in a trigonal planar geometry to one C(56), one C(58), and one C(62) atom. The C(57)-C(58) bond length is 1.44 Å. The C(57)-C(62) bond length is 1.52 Å. In the thirty-seventh C site, C(58) is bonded in a trigonal planar geometry to one C(57), one C(59), and one C(63) atom. The C(58)-C(59) bond length is 1.38 Å. The C(58)-C(63) bond length is 1.51 Å. In the thirty-eighth C site, C(59) is bonded in a distorted single-bond geometry to one C(58), one C(60), and one H(82) atom. The C(59)-C(60) bond length is 1.40 Å. The C(59)-H(82) bond length is 0.95 Å. In the thirty-ninth C site, C(60) is bonded in a distorted single-bond geometry to one C(59), one C(61), and one N(13) atom. The C(60)-C(61) bond length is 1.40 Å. The C(60)-N(13) bond length is 1.37 Å. In the fortieth C site, C(61) is bonded in a distorted single-bond geometry to one C(56), one C(60), and one N(14) atom. The C(61)-N(14) bond length is 1.42 Å. In the forty-first C site, C(62) is bonded in a trigonal non-coplanar geometry to one C(57); one H(84); and two equivalent H(83,85) atoms. The C(62)-H(84) bond length is 0.98 Å. Both C(62)-H(83,85) bond lengths are 0.98 Å. In the forty-second C site, C(63) is bonded in a trigonal non-coplanar geometry to one C(58); one H(88); and two equivalent H(86,87) atoms. The C(63)-H(88) bond length is 0.98 Å. Both C(63)-H(86,87) bond lengths are 0.98 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a single-bond geometry to one C(1) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(2), and one C(5) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(10), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(12), and one C(15) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(1), one C(17), and one C(20) atom. In the sixth N site, N(13) is bonded in a trigonal planar geometry to one C(50), one C(55), and one C(60) atom. In the seventh N site, N(14) is bonded in a distorted trigonal planar geometry to one Co(1), one C(55), and one C(61) atom. There are thirty-eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(7,8) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(10,11) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(13,14) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(23) is bonded in a single-bond geometry to one C(28) atom. In the thirteenth H site, H(24) is bonded in a single-bond geometry to one C(28) atom. In the fourteenth H site, H(25) is bonded in a single-bond geometry to one C(28) atom. In the fifteenth H site, H(26) is bonded in a single-bond geometry to one C(29) atom. In the sixteenth H site, H(27) is bonded in a single-bond geometry to one C(29) atom. In the seventeenth H site, H(28) is bonded in a single-bond geometry to one C(29) atom. In the eighteenth H site, H(29,30) is bonded in a single-bond geometry to one C(30) atom. In the nineteenth H site, H(39,41) is bonded in a single-bond geometry to one C(35) atom. In the twentieth H site, H(40) is bonded in a single-bond geometry to one C(35) atom. In the twenty-first H site, H(42,43) is bonded in a single-bond geometry to one C(36) atom. In the twenty-second H site, H(44) is bonded in a single-bond geometry to one C(36) atom. In the twenty-third H site, H(51,52) is bonded in a single-bond geometry to one C(40) atom. In the twenty-fourth H site, H(53) is bonded in a single-bond geometry to one C(40) atom. In the twenty-fifth H site, H(54) is bonded in a single-bond geometry to one C(41) atom. In the twenty-sixth H site, H(55) is bonded in a single-bond geometry to one C(41) atom. In the twenty-seventh H site, H(56) is bonded in a single-bond geometry to one C(41) atom. In the twenty-eighth H site, H(57) is bonded in a single-bond geometry to one C(42) atom. In the twenty-ninth H site, H(58) is bonded in a single-bond geometry to one C(42) atom. In the thirtieth H site, H(72) is bonded in a single-bond geometry to one C(50) atom. In the thirty-first H site, H(75) is bonded in a single-bond geometry to one C(53) atom. In the thirty-second H site, H(80) is bonded in a single-bond geometry to one C(55) atom. In the thirty-third H site, H(81) is bonded in a single-bond geometry to one C(56) atom. In the thirty-fourth H site, H(82) is bonded in a single-bond geometry to one C(59) atom. In the thirty-fifth H site, H(83,85) is bonded in a single-bond geometry to one C(62) atom. In the thirty-sixth H site, H(84) is bonded in a single-bond geometry to one C(62) atom. In the thirty-seventh H site, H(86,87) is bonded in a single-bond geometry to one C(63) atom. In the thirty-eighth H site, H(88) is bonded in a single-bond geometry to one C(63) atom. O(12) is bonded in a water-like geometry to one C(50) and one C(53) atom. In each KC7PN3H12O8Cl cluster, K(1) is bonded in a 7-coordinate geometry to one H(74), one H(79), one O(10), one O(14), one O(3), one O(7), and one Cl(1) atom. The K(1)-H(74) bond length is 2.81 Å. The K(1)-H(79) bond length is 2.61 Å. The K(1)-O(10) bond length is 2.88 Å. The K(1)-O(14) bond length is 2.66 Å. The K(1)-O(3) bond length is 2.78 Å. The K(1)-O(7) bond length is 2.54 Å. The K(1)-Cl(1) bond length is 3.09 Å. There are seven inequivalent C sites. In the first C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(8) and one O(3) atom. The C(31)-N(8) bond length is 1.29 Å. The C(31)-O(3) bond length is 1.26 Å. In the second C site, C(44) is bonded in a distorted bent 120 degrees geometry to one N(11) and one O(6) atom. The C(44)-N(11) bond length is 1.32 Å. The C(44)-O(6) bond length is 1.26 Å. In the third C site, C(46) is bonded in a distorted bent 120 degrees geometry to one N(12) and one O(7) atom. The C(46)-N(12) bond length is 1.33 Å. The C(46)-O(7) bond length is 1.24 Å. In the fourth C site, C(47) is bonded in a 4-coordinate geometry to one C(48); one N(11); and two equivalent H(66,67) atoms. The C(47)-C(48) bond length is 1.47 Å. The C(47)-N(11) bond length is 1.49 Å. Both C(47)-H(66,67) bond lengths are 0.99 Å. In the fifth C site, C(48) is bonded in a distorted water-like geometry to one C(47), one H(68), and one O(9) atom. The C(48)-H(68) bond length is 1.00 Å. The C(48)-O(9) bond length is 1.45 Å. In the sixth C site, C(52) is bonded in a distorted water-like geometry to one H(74) and one O(8) atom. The C(52)-H(74) bond length is 1.00 Å. The C(52)-O(8) bond length is 1.42 Å. In the seventh C site, C(54) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(76,77) and one O(14) atom. Both C(54)-H(76,77) bond lengths are 0.99 Å. The C(54)-O(14) bond length is 1.40 Å. P(1) is bonded in a tetrahedral geometry to one O(10), one O(11), one O(8), and one O(9) atom. The P(1)-O(10) bond length is 1.49 Å. The P(1)-O(11) bond length is 1.50 Å. The P(1)-O(8) bond length is 1.61 Å. The P(1)-O(9) bond length is 1.57 Å. There are three inequivalent N sites. In the first N site, N(8) is bonded in a trigonal planar geometry to one C(31), one H(31), and one H(32) atom. The N(8)-H(31) bond length is 0.88 Å. The N(8)-H(32) bond length is 0.88 Å. In the second N site, N(11) is bonded in a trigonal planar geometry to one C(44), one C(47), and one H(61) atom. The N(11)-H(61) bond length is 0.88 Å. In the third N site, N(12) is bonded in a trigonal planar geometry to one C(46) and two equivalent H(64,65) atoms. Both N(12)-H(64,65) bond lengths are 0.88 Å. There are nine inequivalent H sites. In the first H site, H(31) is bonded in a single-bond geometry to one N(8) atom. In the second H site, H(32) is bonded in a single-bond geometry to one N(8) atom. In the third H site, H(61) is bonded in a single-bond geometry to one N(11) atom. In the fourth H site, H(64,65) is bonded in a single-bond geometry to one N(12) atom. In the fifth H site, H(66,67) is bonded in a single-bond geometry to one C(47) atom. In the sixth H site, H(68) is bonded in a single-bond geometry to one C(48) atom. In the seventh H site, H(74) is bonded in a single-bond geometry to one K(1) and one C(52) atom. In the eighth H site, H(76,77) is bonded in a single-bond geometry to one C(54) atom. In the ninth H site, H(79) is bonded in a single-bond geometry to one K(1) and one O(14) atom. The H(79)-O(14) bond length is 0.84 Å. There are eight inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one K(1) and one C(31) atom. In the second O site, O(6) is bonded in a single-bond geometry to one C(44) atom. In the third O site, O(8) is bonded in a bent 120 degrees geometry to one C(52) and one P(1) atom. In the fourth O site, O(9) is bonded in a bent 120 degrees geometry to one C(48) and one P(1) atom. In the fifth O site, O(10) is bonded in a distorted single-bond geometry to one K(1) and one P(1) atom. In the sixth O site, O(11) is bonded in a single-bond geometry to one P(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one K(1) and one C(46) atom. In the eighth O site, O(14) is bonded in a water-like geometry to one K(1), one C(54), and one H(79) atom. Cl(1) is bonded in a distorted single-bond geometry to one K(1) atom. Linkers: 2 C/C1=C2/[N][C@](C)([C@H]3[N]/C(=C(/C)[C]4[N][C](/C=C5\[N][C]1[C@](C)(CC(N)=O)[C@H]5CCC(N)=O)C(C)(C)[C@H]4CCC(N)=O)[C@@](C)(CCC(=O)NC[C@H](C)O[P@@]([O])(=O)O[C@@H]1[C@H](O)[C@H](n4cnc5cc(C)c(C)cc54)O[C@H]1C[O])[C@@H]3CC(N)=O)[C@](C)(CC(N)=O)[C@H]2CCC(N)=O ,2 C/C1=C2/[N][C@](C)([C@H]3[N]/C(=C(/C)[C]4[N][C](/C=C5\[N][C]1[C@](C)(CC(N)=O)[C@H]5CCC(N)=O)C(C)(C)[C@H]4CCC(N)=O)[C@@](C)(CCC(=O)NC[C@H](C)O[P@]([O])(=O)O[C@@H]1[C@H](O)[C@H](n4cnc5cc(C)c(C)cc54)O[C@H]1C[O])[C@@H]3CC(N)=O)[C@](C)(CC(N)=O)[C@H]2CCC(N)=O. Metal clusters: 4 N[C]=O.N[C]O[K].[CH3].[Cl].[H].[OH].[O]P=O ,4 [Co]. RCSR code: srs. The MOF has largest included sphere 5.57 A, density 1.18 g/cm3, surface area 4832.82 m2/g, accessible volume 0.30 cm3/g