AgH8(C2N)4AgH8(CS)10 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two AgH8(C2N)4 clusters and one AgH8(CS)10 cluster. In each AgH8(C2N)4 cluster, Ag(2) is bonded in a distorted trigonal pyramidal geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Ag(2)-N(1) bond length is 2.34 Å. The Ag(2)-N(2) bond length is 2.22 Å. The Ag(2)-N(3) bond length is 2.21 Å. The Ag(2)-N(4) bond length is 2.33 Å. There are eight inequivalent C sites. In the first C site, C(5) is bonded in a water-like geometry to one C(6), one H(3), and one H(4) atom. The C(5)-C(6) bond length is 1.46 Å. The C(5)-H(3) bond length is 0.92 Å. The C(5)-H(4) bond length is 0.94 Å. In the second C site, C(6) is bonded in a linear geometry to one C(5) and one N(1) atom. The C(6)-N(1) bond length is 1.14 Å. In the third C site, C(8) is bonded in a water-like geometry to one C(9), one H(7), and one H(8) atom. The C(8)-C(9) bond length is 1.46 Å. The C(8)-H(7) bond length is 0.90 Å. The C(8)-H(8) bond length is 0.95 Å. In the fourth C site, C(9) is bonded in a linear geometry to one C(8) and one N(2) atom. The C(9)-N(2) bond length is 1.13 Å. In the fifth C site, C(14) is bonded in a distorted water-like geometry to one C(15), one H(11), and one H(12) atom. The C(14)-C(15) bond length is 1.47 Å. The C(14)-H(11) bond length is 0.93 Å. The C(14)-H(12) bond length is 0.91 Å. In the sixth C site, C(15) is bonded in a linear geometry to one C(14) and one N(3) atom. The C(15)-N(3) bond length is 1.13 Å. In the seventh C site, C(17) is bonded in a water-like geometry to one C(18), one H(15), and one H(16) atom. The C(17)-C(18) bond length is 1.46 Å. The C(17)-H(15) bond length is 0.92 Å. The C(17)-H(16) bond length is 0.94 Å. In the eighth C site, C(18) is bonded in a linear geometry to one C(17) and one N(4) atom. The C(18)-N(4) bond length is 1.13 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Ag(2) and one C(6) atom. In the second N site, N(2) is bonded in a linear geometry to one Ag(2) and one C(9) atom. In the third N site, N(3) is bonded in a linear geometry to one Ag(2) and one C(15) atom. In the fourth N site, N(4) is bonded in a bent 150 degrees geometry to one Ag(2) and one C(18) atom. There are eight inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the AgH8(CS)10 cluster, Ag(1) is bonded in a 3-coordinate geometry to one S(8) and two equivalent S(3) atoms. The Ag(1)-S(8) bond length is 2.53 Å. There is one shorter (2.65 Å) and one longer (2.73 Å) Ag(1)-S(3) bond length. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one S(1), one S(2), and one S(3) atom. The C(1)-S(1) bond length is 1.70 Å. The C(1)-S(2) bond length is 1.72 Å. The C(1)-S(3) bond length is 1.68 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(3), one S(2), and one S(4) atom. The C(2)-C(3) bond length is 1.36 Å. The C(2)-S(2) bond length is 1.74 Å. The C(2)-S(4) bond length is 1.75 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one S(1), and one S(5) atom. The C(3)-S(1) bond length is 1.74 Å. The C(3)-S(5) bond length is 1.75 Å. In the fourth C site, C(4) is bonded in a water-like geometry to one H(1), one H(2), and one S(4) atom. The C(4)-H(1) bond length is 1.00 Å. The C(4)-H(2) bond length is 0.96 Å. The C(4)-S(4) bond length is 1.81 Å. In the fifth C site, C(7) is bonded in a water-like geometry to one H(5), one H(6), and one S(5) atom. The C(7)-H(5) bond length is 0.95 Å. The C(7)-H(6) bond length is 0.91 Å. The C(7)-S(5) bond length is 1.82 Å. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one S(6), one S(7), and one S(8) atom. The C(10)-S(6) bond length is 1.71 Å. The C(10)-S(7) bond length is 1.72 Å. The C(10)-S(8) bond length is 1.68 Å. In the seventh C site, C(11) is bonded in a trigonal planar geometry to one C(12), one S(7), and one S(9) atom. The C(11)-C(12) bond length is 1.35 Å. The C(11)-S(7) bond length is 1.74 Å. The C(11)-S(9) bond length is 1.76 Å. In the eighth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one S(10), and one S(6) atom. The C(12)-S(10) bond length is 1.75 Å. The C(12)-S(6) bond length is 1.75 Å. In the ninth C site, C(13) is bonded in a distorted water-like geometry to one H(10), one H(9), and one S(9) atom. The C(13)-H(10) bond length is 0.94 Å. The C(13)-H(9) bond length is 0.97 Å. The C(13)-S(9) bond length is 1.82 Å. In the tenth C site, C(16) is bonded in a distorted water-like geometry to one H(13), one H(14), and one S(10) atom. The C(16)-H(13) bond length is 1.04 Å. The C(16)-H(14) bond length is 0.91 Å. The C(16)-S(10) bond length is 1.82 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. There are ten inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(1) and one C(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(1) and one C(2) atom. In the third S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Ag(1) and one C(1) atom. In the fourth S site, S(4) is bonded in a distorted water-like geometry to one C(2) and one C(4) atom. In the fifth S site, S(5) is bonded in a water-like geometry to one C(3) and one C(7) atom. In the sixth S site, S(6) is bonded in a water-like geometry to one C(10) and one C(12) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one C(10) and one C(11) atom. In the eighth S site, S(8) is bonded in a water-like geometry to one Ag(1) and one C(10) atom. In the ninth S site, S(9) is bonded in a water-like geometry to one C(11) and one C(13) atom. In the tenth S site, S(10) is bonded in a water-like geometry to one C(12) and one C(16) atom. Linkers: 4 N#CCCSc1sc(=S)sc1SCCC#N. Metal clusters: 4 [Ag]. The MOF has largest included sphere 5.21 A, density 1.39 g/cm3, surface area 3956.43 m2/g, accessible volume 0.32 cm3/g