Na2Pr4W30C14P5H7(NO49)2(CH)2 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a Na2Pr4W30C14P5H7(NO49)2 framework. In the Na2Pr4W30C14P5H7(NO49)2 framework, there are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a distorted T-shaped geometry to one O(58), one O(89), and one O(98) atom. The Na(1)-O(58) bond length is 2.39 Å. The Na(1)-O(89) bond length is 2.65 Å. The Na(1)-O(98) bond length is 2.39 Å. In the second Na site, Na(2) is bonded in a single-bond geometry to one O(97) atom. The Na(2)-O(97) bond length is 2.62 Å. There are four inequivalent Pr sites. In the first Pr site, Pr(1) is bonded in a 5-coordinate geometry to one N(2), one O(48), one O(88), one O(90), and one O(91) atom. The Pr(1)-N(2) bond length is 2.54 Å. The Pr(1)-O(48) bond length is 2.48 Å. The Pr(1)-O(88) bond length is 2.51 Å. The Pr(1)-O(90) bond length is 2.48 Å. The Pr(1)-O(91) bond length is 2.50 Å. In the second Pr site, Pr(2) is bonded in a distorted pentagonal planar geometry to one O(29), one O(81), one O(87), one O(96), and one O(97) atom. The Pr(2)-O(29) bond length is 2.43 Å. The Pr(2)-O(81) bond length is 2.50 Å. The Pr(2)-O(87) bond length is 2.41 Å. The Pr(2)-O(96) bond length is 2.43 Å. The Pr(2)-O(97) bond length is 2.52 Å. In the third Pr site, Pr(3) is bonded in a 4-coordinate geometry to one O(19), one O(89), one O(92), and one O(98) atom. The Pr(3)-O(19) bond length is 2.60 Å. The Pr(3)-O(89) bond length is 2.45 Å. The Pr(3)-O(92) bond length is 2.48 Å. The Pr(3)-O(98) bond length is 2.67 Å. In the fourth Pr site, Pr(4) is bonded in a 4-coordinate geometry to one N(1), one O(75), one O(93), and one O(94) atom. The Pr(4)-N(1) bond length is 2.56 Å. The Pr(4)-O(75) bond length is 2.44 Å. The Pr(4)-O(93) bond length is 2.41 Å. The Pr(4)-O(94) bond length is 2.42 Å. There are thirty inequivalent W sites. In the first W site, W(1) is bonded to one O(11), one O(37), one O(43), one O(7), and one O(84) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(11)O6 octahedra,  a cornercorner with one W(14)O5 square pyramid,  a cornercorner with one W(2)O5 square pyramid, and  a cornercorner with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 19°. The W(1)-O(11) bond length is 1.93 Å. The W(1)-O(37) bond length is 1.89 Å. The W(1)-O(43) bond length is 1.91 Å. The W(1)-O(7) bond length is 1.94 Å. The W(1)-O(84) bond length is 2.24 Å. In the second W site, W(2) is bonded to one O(21), one O(24), one O(52), one O(7), and one O(83) atom to form WO5 square pyramids that share  a cornercorner with one W(5)O6 octahedra,  a cornercorner with one W(1)O5 square pyramid,  a cornercorner with one W(10)O5 square pyramid,  a cornercorner with one W(15)O5 square pyramid, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 26°. The W(2)-O(21) bond length is 2.22 Å. The W(2)-O(24) bond length is 1.87 Å. The W(2)-O(52) bond length is 1.96 Å. The W(2)-O(7) bond length is 1.84 Å. The W(2)-O(83) bond length is 1.99 Å. In the third W site, W(3) is bonded to one O(22), one O(3), one O(44), one O(47), and one O(56) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(5)O6 octahedra,  a cornercorner with one W(10)O5 square pyramid,  a cornercorner with one P(3)O4 tetrahedra, and  an edgeedge with one W(12)O5 square pyramid. The corner-sharing octahedral tilt angles are 19°. The W(3)-O(22) bond length is 2.04 Å. The W(3)-O(3) bond length is 1.81 Å. The W(3)-O(44) bond length is 1.90 Å. The W(3)-O(47) bond length is 1.92 Å. The W(3)-O(56) bond length is 2.28 Å. In the fourth W site, W(4) is bonded to one O(12), one O(14), one O(39), one O(40), one O(58), and one O(70) atom to form distorted WO6 octahedra that share  a cornercorner with one W(11)O6 octahedra,  a cornercorner with one W(14)O5 square pyramid,  a cornercorner with one W(20)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(22)O5 square pyramid. The corner-sharing octahedral tilt angles are 28°. The W(4)-O(12) bond length is 1.89 Å. The W(4)-O(14) bond length is 2.07 Å. The W(4)-O(39) bond length is 2.26 Å. The W(4)-O(40) bond length is 1.85 Å. The W(4)-O(58) bond length is 1.74 Å. The W(4)-O(70) bond length is 1.96 Å. In the fifth W site, W(5) is bonded to one O(22), one O(41), one O(48), one O(52), one O(73), and one O(8) atom to form distorted WO6 octahedra that share  a cornercorner with one W(15)O5 square pyramid,  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one W(3)O5 square pyramid,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one W(9)O6 octahedra. The W(5)-O(22) bond length is 1.81 Å. The W(5)-O(41) bond length is 1.95 Å. The W(5)-O(48) bond length is 1.76 Å. The W(5)-O(52) bond length is 1.84 Å. The W(5)-O(73) bond length is 2.26 Å. The W(5)-O(8) bond length is 2.06 Å. In the sixth W site, W(6) is bonded in a 5-coordinate geometry to one O(3), one O(30), one O(42), one O(5), and one O(71) atom. The W(6)-O(3) bond length is 2.12 Å. The W(6)-O(30) bond length is 1.89 Å. The W(6)-O(42) bond length is 1.76 Å. The W(6)-O(5) bond length is 1.88 Å. The W(6)-O(71) bond length is 2.28 Å. In the seventh W site, W(7) is bonded in a 5-coordinate geometry to one O(1), one O(37), one O(38), one O(67), and one O(68) atom. The W(7)-O(1) bond length is 1.80 Å. The W(7)-O(37) bond length is 1.89 Å. The W(7)-O(38) bond length is 2.06 Å. The W(7)-O(67) bond length is 1.93 Å. The W(7)-O(68) bond length is 2.25 Å. In the eighth W site, W(8) is bonded in a 5-coordinate geometry to one O(51), one O(54), one O(72), one O(74), and one O(82) atom. The W(8)-O(51) bond length is 2.29 Å. The W(8)-O(54) bond length is 1.77 Å. The W(8)-O(72) bond length is 1.90 Å. The W(8)-O(74) bond length is 2.06 Å. The W(8)-O(82) bond length is 1.87 Å. In the ninth W site, W(9) is bonded to one O(17), one O(41), one O(50), one O(73), one O(81), and one O(9) atom to form distorted WO6 octahedra that share  a cornercorner with one W(12)O5 square pyramid,  a cornercorner with one W(25)O5 square pyramid,  a cornercorner with one W(26)O5 square pyramid,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one W(5)O6 octahedra. The W(9)-O(17) bond length is 1.80 Å. The W(9)-O(41) bond length is 1.90 Å. The W(9)-O(50) bond length is 1.91 Å. The W(9)-O(73) bond length is 2.22 Å. The W(9)-O(81) bond length is 1.70 Å. The W(9)-O(9) bond length is 2.05 Å. In the tenth W site, W(10) is bonded to one O(13), one O(24), one O(25), one O(44), and one O(5) atom to form WO5 square pyramids that share  a cornercorner with one W(18)O5 square pyramid,  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one W(3)O5 square pyramid, and  a cornercorner with one P(3)O4 tetrahedra. The W(10)-O(13) bond length is 2.19 Å. The W(10)-O(24) bond length is 1.88 Å. The W(10)-O(25) bond length is 1.90 Å. The W(10)-O(44) bond length is 1.93 Å. The W(10)-O(5) bond length is 1.88 Å. In the eleventh W site, W(11) is bonded to one O(10), one O(12), one O(29), one O(43), one O(57), and one O(60) atom to form distorted WO6 octahedra that share  a cornercorner with one W(4)O6 octahedra,  a cornercorner with one W(1)O5 square pyramid,  a cornercorner with one W(18)O5 square pyramid,  a cornercorner with one W(20)O5 square pyramid, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 28°. The W(11)-O(10) bond length is 1.88 Å. The W(11)-O(12) bond length is 1.95 Å. The W(11)-O(29) bond length is 1.75 Å. The W(11)-O(43) bond length is 1.86 Å. The W(11)-O(57) bond length is 1.88 Å. The W(11)-O(60) bond length is 2.20 Å. In the twelfth W site, W(12) is bonded to one O(18), one O(26), one O(47), one O(56), and one O(9) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(9)O6 octahedra,  a cornercorner with one W(23)O5 square pyramid,  a cornercorner with one P(3)O4 tetrahedra, and  an edgeedge with one W(3)O5 square pyramid. The corner-sharing octahedral tilt angles are 17°. The W(12)-O(18) bond length is 2.07 Å. The W(12)-O(26) bond length is 1.88 Å. The W(12)-O(47) bond length is 1.93 Å. The W(12)-O(56) bond length is 2.24 Å. The W(12)-O(9) bond length is 1.78 Å. In the thirteenth W site, W(13) is bonded in a 5-coordinate geometry to one O(15), one O(20), one O(26), one O(31), and one O(76) atom. The W(13)-O(15) bond length is 1.87 Å. The W(13)-O(20) bond length is 1.92 Å. The W(13)-O(26) bond length is 1.95 Å. The W(13)-O(31) bond length is 1.90 Å. The W(13)-O(76) bond length is 2.24 Å. In the fourteenth W site, W(14) is bonded to one O(11), one O(38), one O(40), one O(51), and one O(72) atom to form WO5 square pyramids that share  a cornercorner with one W(4)O6 octahedra,  a cornercorner with one W(1)O5 square pyramid, and  a cornercorner with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 19°. The W(14)-O(11) bond length is 1.90 Å. The W(14)-O(38) bond length is 1.82 Å. The W(14)-O(40) bond length is 1.99 Å. The W(14)-O(51) bond length is 2.28 Å. The W(14)-O(72) bond length is 1.95 Å. In the fifteenth W site, W(15) is bonded to one O(1), one O(62), one O(8), one O(83), and one O(85) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(5)O6 octahedra,  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one W(25)O5 square pyramid. The corner-sharing octahedral tilt angles are 33°. The W(15)-O(1) bond length is 2.06 Å. The W(15)-O(62) bond length is 1.88 Å. The W(15)-O(8) bond length is 1.84 Å. The W(15)-O(83) bond length is 1.80 Å. The W(15)-O(85) bond length is 2.26 Å. In the sixteenth W site, W(16) is bonded to one O(2), one O(20), one O(32), one O(55), and one O(65) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(17)O5 square pyramid,  a cornercorner with one W(29)O5 square pyramid, and  a cornercorner with one P(2)O4 tetrahedra. The W(16)-O(2) bond length is 1.88 Å. The W(16)-O(20) bond length is 1.85 Å. The W(16)-O(32) bond length is 1.93 Å. The W(16)-O(55) bond length is 2.16 Å. The W(16)-O(65) bond length is 1.93 Å. In the seventeenth W site, W(17) is bonded to one O(23), one O(32), one O(45), one O(63), and one O(78) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(16)O5 square pyramid,  a cornercorner with one W(23)O5 square pyramid,  a cornercorner with one W(29)O5 square pyramid, and  a cornercorner with one P(2)O4 tetrahedra. The W(17)-O(23) bond length is 1.95 Å. The W(17)-O(32) bond length is 1.87 Å. The W(17)-O(45) bond length is 1.84 Å. The W(17)-O(63) bond length is 2.26 Å. The W(17)-O(78) bond length is 2.09 Å. In the eighteenth W site, W(18) is bonded to one O(10), one O(25), one O(46), one O(49), and one O(80) atom to form WO5 square pyramids that share  a cornercorner with one W(11)O6 octahedra,  a cornercorner with one W(10)O5 square pyramid, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 15°. The W(18)-O(10) bond length is 1.87 Å. The W(18)-O(25) bond length is 1.87 Å. The W(18)-O(46) bond length is 1.92 Å. The W(18)-O(49) bond length is 2.16 Å. The W(18)-O(80) bond length is 1.96 Å. In the nineteenth W site, W(19) is bonded in a 1-coordinate geometry to one O(2), one O(36), and one O(61) atom. The W(19)-O(2) bond length is 1.89 Å. The W(19)-O(36) bond length is 2.17 Å. The W(19)-O(61) bond length is 1.85 Å. In the twentieth W site, W(20) is bonded to one O(14), one O(57), one O(59), one O(64), and one O(66) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(11)O6 octahedra,  a cornercorner with one W(4)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(28)O6 octahedra. The corner-sharing octahedral tilt angles range from 31-32°. The W(20)-O(14) bond length is 1.82 Å. The W(20)-O(57) bond length is 1.90 Å. The W(20)-O(59) bond length is 1.96 Å. The W(20)-O(64) bond length is 2.28 Å. The W(20)-O(66) bond length is 2.06 Å. In the twenty-first W site, W(21) is bonded in a 6-coordinate geometry to one O(16), one O(19), one O(23), one O(42), one O(46), and one O(63) atom. The W(21)-O(16) bond length is 1.77 Å. The W(21)-O(19) bond length is 1.71 Å. The W(21)-O(23) bond length is 1.92 Å. The W(21)-O(42) bond length is 2.09 Å. The W(21)-O(46) bond length is 1.86 Å. The W(21)-O(63) bond length is 2.28 Å. In the twenty-second W site, W(22) is bonded to one O(35), one O(39), one O(54), one O(6), and one O(70) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(28)O6 octahedra,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(4)O6 octahedra. The corner-sharing octahedral tilt angles are 31°. The W(22)-O(35) bond length is 1.80 Å. The W(22)-O(39) bond length is 2.28 Å. The W(22)-O(54) bond length is 2.08 Å. The W(22)-O(6) bond length is 1.88 Å. The W(22)-O(70) bond length is 1.90 Å. In the twenty-third W site, W(23) is bonded to one O(18), one O(30), one O(31), one O(45), and one O(71) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(12)O5 square pyramid,  a cornercorner with one W(17)O5 square pyramid, and  a cornercorner with one P(3)O4 tetrahedra. The W(23)-O(18) bond length is 1.81 Å. The W(23)-O(30) bond length is 1.94 Å. The W(23)-O(31) bond length is 1.90 Å. The W(23)-O(45) bond length is 2.00 Å. The W(23)-O(71) bond length is 2.27 Å. In the twenty-fourth W site, W(24) is bonded to one O(4), one O(53), one O(67), one O(68), and one O(74) atom to form WO5 square pyramids that share  a cornercorner with one W(25)O5 square pyramid,  a cornercorner with one W(27)O5 square pyramid, and  a cornercorner with one P(5)O4 tetrahedra. The W(24)-O(4) bond length is 2.01 Å. The W(24)-O(53) bond length is 1.89 Å. The W(24)-O(67) bond length is 1.90 Å. The W(24)-O(68) bond length is 2.26 Å. The W(24)-O(74) bond length is 1.82 Å. In the twenty-fifth W site, W(25) is bonded to one O(17), one O(27), one O(4), one O(62), and one O(85) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(9)O6 octahedra,  a cornercorner with one W(24)O5 square pyramid,  a cornercorner with one W(26)O5 square pyramid,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one W(15)O5 square pyramid. The corner-sharing octahedral tilt angles are 29°. The W(25)-O(17) bond length is 2.11 Å. The W(25)-O(27) bond length is 1.96 Å. The W(25)-O(4) bond length is 1.82 Å. The W(25)-O(62) bond length is 1.90 Å. The W(25)-O(85) bond length is 2.25 Å. In the twenty-sixth W site, W(26) is bonded to one O(15), one O(27), one O(28), one O(34), and one O(50) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(9)O6 octahedra,  a cornercorner with one W(25)O5 square pyramid,  a cornercorner with one W(27)O5 square pyramid, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 36°. The W(26)-O(15) bond length is 1.92 Å. The W(26)-O(27) bond length is 1.88 Å. The W(26)-O(28) bond length is 2.23 Å. The W(26)-O(34) bond length is 1.89 Å. The W(26)-O(50) bond length is 1.92 Å. In the twenty-seventh W site, W(27) is bonded to one O(33), one O(34), one O(53), one O(61), and one O(82) atom to form WO5 square pyramids that share  a cornercorner with one W(24)O5 square pyramid,  a cornercorner with one W(26)O5 square pyramid, and  a cornercorner with one P(5)O4 tetrahedra. The W(27)-O(33) bond length is 2.19 Å. The W(27)-O(34) bond length is 1.88 Å. The W(27)-O(53) bond length is 1.94 Å. The W(27)-O(61) bond length is 1.94 Å. The W(27)-O(82) bond length is 1.92 Å. In the twenty-eighth W site, W(28) is bonded to one O(35), one O(59), one O(64), one O(75), one O(77), and one O(86) atom to form distorted WO6 octahedra that share  a cornercorner with one W(22)O5 square pyramid,  a cornercorner with one W(29)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(20)O5 square pyramid. The W(28)-O(35) bond length is 2.10 Å. The W(28)-O(59) bond length is 1.91 Å. The W(28)-O(64) bond length is 2.19 Å. The W(28)-O(75) bond length is 1.77 Å. The W(28)-O(77) bond length is 1.82 Å. The W(28)-O(86) bond length is 1.84 Å. In the twenty-ninth W site, W(29) is bonded to one O(65), one O(69), one O(77), one O(78), and one O(79) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(28)O6 octahedra,  a cornercorner with one W(16)O5 square pyramid,  a cornercorner with one W(17)O5 square pyramid, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 21°. The W(29)-O(65) bond length is 1.89 Å. The W(29)-O(69) bond length is 1.97 Å. The W(29)-O(77) bond length is 2.05 Å. The W(29)-O(78) bond length is 1.81 Å. The W(29)-O(79) bond length is 2.29 Å. In the thirtieth W site, W(30) is bonded in a 5-coordinate geometry to one O(16), one O(66), one O(69), one O(79), and one O(80) atom. The W(30)-O(16) bond length is 2.11 Å. The W(30)-O(66) bond length is 1.76 Å. The W(30)-O(69) bond length is 1.94 Å. The W(30)-O(79) bond length is 2.23 Å. The W(30)-O(80) bond length is 1.85 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(7), and one N(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-C(7) bond length is 1.54 Å. The C(1)-N(1) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.95 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-H(3) bond length is 0.95 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.42 Å. The C(5)-N(1) bond length is 1.37 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(89), and one O(94) atom. The C(6)-O(89) bond length is 1.24 Å. The C(6)-O(94) bond length is 1.33 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(93), and one O(95) atom. The C(7)-O(93) bond length is 1.36 Å. The C(7)-O(95) bond length is 1.14 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one N(2) atom. The C(8)-C(13) bond length is 1.46 Å. The C(8)-C(9) bond length is 1.41 Å. The C(8)-N(2) bond length is 1.41 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(4) atom. The C(9)-H(4) bond length is 0.95 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(6) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-H(6) bond length is 0.95 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(14), and one N(2) atom. The C(12)-C(14) bond length is 1.48 Å. The C(12)-N(2) bond length is 1.41 Å. In the eleventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(87), and one O(88) atom. The C(13)-O(87) bond length is 1.21 Å. The C(13)-O(88) bond length is 1.32 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(12), one O(90), and one O(92) atom. The C(14)-O(90) bond length is 1.19 Å. The C(14)-O(92) bond length is 1.25 Å. In the thirteenth C site, C(15) is bonded in a trigonal non-coplanar geometry to one C(16), one H(7), one H(8), and one H(9) atom. The C(15)-C(16) bond length is 1.58 Å. The C(15)-H(7) bond length is 0.98 Å. The C(15)-H(8) bond length is 0.98 Å. The C(15)-H(9) bond length is 0.98 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one O(91), and one O(96) atom. The C(16)-O(91) bond length is 1.22 Å. The C(16)-O(96) bond length is 1.25 Å. There are five inequivalent P sites. In the first P site, P(1) is bonded to one O(36), one O(39), one O(60), and one O(64) atom to form PO4 tetrahedra that share  a cornercorner with one W(11)O6 octahedra,  a cornercorner with one W(28)O6 octahedra,  a cornercorner with one W(4)O6 octahedra,  a cornercorner with one W(20)O5 square pyramid, and  a cornercorner with one W(22)O5 square pyramid. The corner-sharing octahedral tilt angles range from 47-51°. The P(1)-O(36) bond length is 1.49 Å. The P(1)-O(39) bond length is 1.54 Å. The P(1)-O(60) bond length is 1.46 Å. The P(1)-O(64) bond length is 1.59 Å. In the second P site, P(2) is bonded to one O(49), one O(55), one O(63), and one O(79) atom to form PO4 tetrahedra that share  a cornercorner with one W(16)O5 square pyramid,  a cornercorner with one W(17)O5 square pyramid,  a cornercorner with one W(18)O5 square pyramid, and  a cornercorner with one W(29)O5 square pyramid. The P(2)-O(49) bond length is 1.51 Å. The P(2)-O(55) bond length is 1.53 Å. The P(2)-O(63) bond length is 1.53 Å. The P(2)-O(79) bond length is 1.55 Å. In the third P site, P(3) is bonded to one O(13), one O(56), one O(71), and one O(76) atom to form PO4 tetrahedra that share  a cornercorner with one W(10)O5 square pyramid,  a cornercorner with one W(12)O5 square pyramid,  a cornercorner with one W(23)O5 square pyramid, and  a cornercorner with one W(3)O5 square pyramid. The P(3)-O(13) bond length is 1.53 Å. The P(3)-O(56) bond length is 1.56 Å. The P(3)-O(71) bond length is 1.56 Å. The P(3)-O(76) bond length is 1.52 Å. In the fourth P site, P(4) is bonded to one O(21), one O(28), one O(73), and one O(85) atom to form PO4 tetrahedra that share  a cornercorner with one W(5)O6 octahedra,  a cornercorner with one W(9)O6 octahedra,  a cornercorner with one W(15)O5 square pyramid,  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one W(25)O5 square pyramid, and  a cornercorner with one W(26)O5 square pyramid. The corner-sharing octahedral tilt angles range from 51-54°. The P(4)-O(21) bond length is 1.49 Å. The P(4)-O(28) bond length is 1.49 Å. The P(4)-O(73) bond length is 1.55 Å. The P(4)-O(85) bond length is 1.58 Å. In the fifth P site, P(5) is bonded to one O(33), one O(51), one O(68), and one O(84) atom to form PO4 tetrahedra that share  a cornercorner with one W(1)O5 square pyramid,  a cornercorner with one W(14)O5 square pyramid,  a cornercorner with one W(24)O5 square pyramid, and  a cornercorner with one W(27)O5 square pyramid. The P(5)-O(33) bond length is 1.52 Å. The P(5)-O(51) bond length is 1.56 Å. The P(5)-O(68) bond length is 1.57 Å. The P(5)-O(84) bond length is 1.49 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Pr(4), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Pr(1), one C(12), and one C(8) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(15) atom. There are ninety-eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one W(15) and one W(7) atom. In the second O site, O(2) is bonded in a linear geometry to one W(16) and one W(19) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one W(3) and one W(6) atom. In the fourth O site, O(4) is bonded in a linear geometry to one W(24) and one W(25) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one W(10) and one W(6) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one W(22) atom. In the seventh O site, O(7) is bonded in a linear geometry to one W(1) and one W(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one W(15) and one W(5) atom. In the ninth O site, O(9) is bonded in a linear geometry to one W(12) and one W(9) atom. In the tenth O site, O(10) is bonded in a linear geometry to one W(11) and one W(18) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one W(1) and one W(14) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one W(11) and one W(4) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one W(10) and one P(3) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one W(20) and one W(4) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one W(13) and one W(26) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one W(21) and one W(30) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one W(25) and one W(9) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one W(12) and one W(23) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 150 degrees geometry to one Pr(3) and one W(21) atom. In the twentieth O site, O(20) is bonded in a linear geometry to one W(13) and one W(16) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one W(2) and one P(4) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one W(3) and one W(5) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one W(17) and one W(21) atom. In the twenty-fourth O site, O(24) is bonded in a linear geometry to one W(10) and one W(2) atom. In the twenty-fifth O site, O(25) is bonded in a linear geometry to one W(10) and one W(18) atom. In the twenty-sixth O site, O(26) is bonded in a bent 150 degrees geometry to one W(12) and one W(13) atom. In the twenty-seventh O site, O(27) is bonded in a bent 150 degrees geometry to one W(25) and one W(26) atom. In the twenty-eighth O site, O(28) is bonded in a distorted single-bond geometry to one W(26) and one P(4) atom. In the twenty-ninth O site, O(29) is bonded in a distorted single-bond geometry to one Pr(2) and one W(11) atom. In the thirtieth O site, O(30) is bonded in a bent 120 degrees geometry to one W(23) and one W(6) atom. In the thirty-first O site, O(31) is bonded in a bent 150 degrees geometry to one W(13) and one W(23) atom. In the thirty-second O site, O(32) is bonded in a distorted single-bond geometry to one W(16) and one W(17) atom. In the thirty-third O site, O(33) is bonded in a distorted single-bond geometry to one W(27) and one P(5) atom. In the thirty-fourth O site, O(34) is bonded in a bent 150 degrees geometry to one W(26) and one W(27) atom. In the thirty-fifth O site, O(35) is bonded in a bent 150 degrees geometry to one W(22) and one W(28) atom. In the thirty-sixth O site, O(36) is bonded in a distorted single-bond geometry to one W(19) and one P(1) atom. In the thirty-seventh O site, O(37) is bonded in a distorted bent 150 degrees geometry to one W(1) and one W(7) atom. In the thirty-eighth O site, O(38) is bonded in a bent 150 degrees geometry to one W(14) and one W(7) atom. In the thirty-ninth O site, O(39) is bonded in a distorted single-bond geometry to one W(22), one W(4), and one P(1) atom. In the fortieth O site, O(40) is bonded in a distorted bent 150 degrees geometry to one W(14) and one W(4) atom. In the forty-first O site, O(41) is bonded in a bent 120 degrees geometry to one W(5) and one W(9) atom. In the forty-second O site, O(42) is bonded in a bent 150 degrees geometry to one W(21) and one W(6) atom. In the forty-third O site, O(43) is bonded in a distorted bent 150 degrees geometry to one W(1) and one W(11) atom. In the forty-fourth O site, O(44) is bonded in a bent 150 degrees geometry to one W(10) and one W(3) atom. In the forty-fifth O site, O(45) is bonded in a bent 150 degrees geometry to one W(17) and one W(23) atom. In the forty-sixth O site, O(46) is bonded in a bent 150 degrees geometry to one W(18) and one W(21) atom. In the forty-seventh O site, O(47) is bonded in a bent 120 degrees geometry to one W(12) and one W(3) atom. In the forty-eighth O site, O(48) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one W(5) atom. In the forty-ninth O site, O(49) is bonded in a distorted single-bond geometry to one W(18) and one P(2) atom. In the fiftieth O site, O(50) is bonded in a bent 150 degrees geometry to one W(26) and one W(9) atom. In the fifty-first O site, O(51) is bonded in a distorted single-bond geometry to one W(14), one W(8), and one P(5) atom. In the fifty-second O site, O(52) is bonded in a bent 150 degrees geometry to one W(2) and one W(5) atom. In the fifty-third O site, O(53) is bonded in a bent 150 degrees geometry to one W(24) and one W(27) atom. In the fifty-fourth O site, O(54) is bonded in a bent 150 degrees geometry to one W(22) and one W(8) atom. In the fifty-fifth O site, O(55) is bonded in a distorted single-bond geometry to one W(16) and one P(2) atom. In the fifty-sixth O site, O(56) is bonded in a distorted single-bond geometry to one W(12), one W(3), and one P(3) atom. In the fifty-seventh O site, O(57) is bonded in a bent 150 degrees geometry to one W(11) and one W(20) atom. In the fifty-eighth O site, O(58) is bonded in a bent 150 degrees geometry to one Na(1) and one W(4) atom. In the fifty-ninth O site, O(59) is bonded in a distorted bent 120 degrees geometry to one W(20) and one W(28) atom. In the sixtieth O site, O(60) is bonded in a distorted single-bond geometry to one W(11) and one P(1) atom. In the sixty-first O site, O(61) is bonded in a bent 150 degrees geometry to one W(19) and one W(27) atom. In the sixty-second O site, O(62) is bonded in a bent 120 degrees geometry to one W(15) and one W(25) atom. In the sixty-third O site, O(63) is bonded in a distorted single-bond geometry to one W(17), one W(21), and one P(2) atom. In the sixty-fourth O site, O(64) is bonded in a distorted single-bond geometry to one W(20), one W(28), and one P(1) atom. In the sixty-fifth O site, O(65) is bonded in a distorted bent 150 degrees geometry to one W(16) and one W(29) atom. In the sixty-sixth O site, O(66) is bonded in a linear geometry to one W(20) and one W(30) atom. In the sixty-seventh O site, O(67) is bonded in a bent 120 degrees geometry to one W(24) and one W(7) atom. In the sixty-eighth O site, O(68) is bonded in a distorted single-bond geometry to one W(24), one W(7), and one P(5) atom. In the sixty-ninth O site, O(69) is bonded in a bent 120 degrees geometry to one W(29) and one W(30) atom. In the seventieth O site, O(70) is bonded in a bent 120 degrees geometry to one W(22) and one W(4) atom. In the seventy-first O site, O(71) is bonded in a distorted single-bond geometry to one W(23), one W(6), and one P(3) atom. In the seventy-second O site, O(72) is bonded in a bent 120 degrees geometry to one W(14) and one W(8) atom. In the seventy-third O site, O(73) is bonded in a distorted single-bond geometry to one W(5), one W(9), and one P(4) atom. In the seventy-fourth O site, O(74) is bonded in a bent 150 degrees geometry to one W(24) and one W(8) atom. In the seventy-fifth O site, O(75) is bonded in a distorted linear geometry to one Pr(4) and one W(28) atom. In the seventy-sixth O site, O(76) is bonded in a distorted single-bond geometry to one W(13) and one P(3) atom. In the seventy-seventh O site, O(77) is bonded in a distorted bent 150 degrees geometry to one W(28) and one W(29) atom. In the seventy-eighth O site, O(78) is bonded in a bent 150 degrees geometry to one W(17) and one W(29) atom. In the seventy-ninth O site, O(79) is bonded in a distorted single-bond geometry to one W(29), one W(30), and one P(2) atom. In the eightieth O site, O(80) is bonded in a bent 150 degrees geometry to one W(18) and one W(30) atom. In the eighty-first O site, O(81) is bonded in a distorted single-bond geometry to one Pr(2) and one W(9) atom. In the eighty-second O site, O(82) is bonded in a single-bond geometry to one W(27) and one W(8) atom. In the eighty-third O site, O(83) is bonded in a bent 150 degrees geometry to one W(15) and one W(2) atom. In the eighty-fourth O site, O(84) is bonded in a distorted single-bond geometry to one W(1) and one P(5) atom. In the eighty-fifth O site, O(85) is bonded in a distorted single-bond geometry to one W(15), one W(25), and one P(4) atom. In the eighty-sixth O site, O(86) is bonded in a distorted single-bond geometry to one W(28) atom. In the eighty-seventh O site, O(87) is bonded in a distorted single-bond geometry to one Pr(2) and one C(13) atom. In the eighty-eighth O site, O(88) is bonded in a distorted bent 120 degrees geometry to one Pr(1) and one C(13) atom. In the eighty-ninth O site, O(89) is bonded in a distorted single-bond geometry to one Na(1), one Pr(3), and one C(6) atom. In the ninetieth O site, O(90) is bonded in a bent 120 degrees geometry to one Pr(1) and one C(14) atom. In the ninety-first O site, O(91) is bonded in a bent 120 degrees geometry to one Pr(1) and one C(16) atom. In the ninety-second O site, O(92) is bonded in a distorted bent 150 degrees geometry to one Pr(3) and one C(14) atom. In the ninety-third O site, O(93) is bonded in a distorted bent 120 degrees geometry to one Pr(4) and one C(7) atom. In the ninety-fourth O site, O(94) is bonded in a single-bond geometry to one Pr(4) and one C(6) atom. In the ninety-fifth O site, O(95) is bonded in a single-bond geometry to one C(7) atom. In the ninety-sixth O site, O(96) is bonded in a bent 150 degrees geometry to one Pr(2) and one C(16) atom. In the ninety-seventh O site, O(97) is bonded in a bent 120 degrees geometry to one Na(2) and one Pr(2) atom. In the ninety-eighth O site, O(98) is bonded in a water-like geometry to one Na(1) and one Pr(3) atom. Linkers: 4 [O]C(=O)c1cccc(C([O])=O)n1 ,4 [O]P([O])([O])=O ,2 CC([O])=O. Metal clusters: 4 [Na] ,8 [Pr] ,60 [W]. The MOF has largest included sphere 8.10 A, density 3.38 g/cm3, surface area 1187.10 m2/g, accessible volume 0.16 cm3/g