CuH20(C7N6)2CuH16(CN)12(CH2)14 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of fourteen 02329_fluka molecules, one CuH16(CN)12 cluster, and one CuH20(C7N6)2 cluster. In the CuH16(CN)12 cluster, Cu(2) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Cu(2)-N(1) bond lengths are 2.02 Å. Both Cu(2)-N(2) bond lengths are 2.01 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-N(3) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(4), and one H(2) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-N(4) bond length is 1.31 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(2), one N(5), and one H(3) atom. The C(3)-N(2) bond length is 1.32 Å. The C(3)-N(5) bond length is 1.31 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(2), one N(6), and one H(4) atom. The C(4)-N(2) bond length is 1.35 Å. The C(4)-N(6) bond length is 1.30 Å. The C(4)-H(4) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(5,6) atoms. The C(5)-N(3) bond length is 1.46 Å. Both C(5)-H(5,6) bond lengths are 0.97 Å. In the sixth C site, C(6) is bonded in a 3-coordinate geometry to one N(5) and two equivalent H(7,8) atoms. The C(6)-N(5) bond length is 1.46 Å. Both C(6)-H(7,8) bond lengths are 0.97 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(2), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one N(4) atom. The N(3)-N(4) bond length is 1.35 Å. In the fourth N site, N(4) is bonded in a distorted water-like geometry to one C(2) and one N(3) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(3), one C(6), and one N(6) atom. The N(5)-N(6) bond length is 1.35 Å. In the sixth N site, N(6) is bonded in a distorted water-like geometry to one C(4) and one N(5) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(6) atom. In the CuH20(C7N6)2 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(7) and two equivalent N(8) atoms. Both Cu(1)-N(7) bond lengths are 2.02 Å. Both Cu(1)-N(8) bond lengths are 2.04 Å. There are seven inequivalent C sites. In the first C site, C(7) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(9) atom. The C(7)-N(7) bond length is 1.32 Å. The C(7)-N(9) bond length is 1.33 Å. The C(7)-H(9) bond length is 0.93 Å. In the second C site, C(8) is bonded in a trigonal planar geometry to one N(10), one N(7), and one H(10) atom. The C(8)-N(10) bond length is 1.31 Å. The C(8)-N(7) bond length is 1.36 Å. The C(8)-H(10) bond length is 0.93 Å. In the third C site, C(9) is bonded in a trigonal planar geometry to one N(11), one N(8), and one H(11) atom. The C(9)-N(11) bond length is 1.32 Å. The C(9)-N(8) bond length is 1.32 Å. The C(9)-H(11) bond length is 0.93 Å. In the fourth C site, C(10) is bonded in a trigonal planar geometry to one N(12), one N(8), and one H(12) atom. The C(10)-N(12) bond length is 1.32 Å. The C(10)-N(8) bond length is 1.34 Å. The C(10)-H(12) bond length is 0.93 Å. In the fifth C site, C(15) is bonded in a 4-coordinate geometry to one C(18); one N(9); and two equivalent H(21,22) atoms. The C(15)-C(18) bond length is 1.46 Å. The C(15)-N(9) bond length is 1.48 Å. Both C(15)-H(21,22) bond lengths are 0.97 Å. In the sixth C site, C(16) is bonded in a 3-coordinate geometry to one N(11) and two equivalent H(23,24) atoms. The C(16)-N(11) bond length is 1.47 Å. Both C(16)-H(23,24) bond lengths are 0.97 Å. In the seventh C site, C(18) is bonded in a water-like geometry to one C(15) and two equivalent H(27,28) atoms. Both C(18)-H(27,28) bond lengths are 0.97 Å. There are six inequivalent N sites. In the first N site, N(7) is bonded in a trigonal planar geometry to one Cu(1), one C(7), and one C(8) atom. In the second N site, N(8) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(9) atom. In the third N site, N(9) is bonded in a distorted trigonal planar geometry to one C(15), one C(7), and one N(10) atom. The N(9)-N(10) bond length is 1.36 Å. In the fourth N site, N(10) is bonded in a distorted water-like geometry to one C(8) and one N(9) atom. In the fifth N site, N(11) is bonded in a 3-coordinate geometry to one C(16), one C(9), and one N(12) atom. The N(11)-N(12) bond length is 1.36 Å. In the sixth N site, N(12) is bonded in a distorted water-like geometry to one C(10) and one N(11) atom. There are seven inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(21,22) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(23,24) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(27,28) is bonded in a single-bond geometry to one C(18) atom. Linkers: 2 [CH]1N=C[N]N1CCCCCCN1[CH]N=C[N]1 ,2 [c]1ncn(CCCCCCN2[CH]N=C[N]2)n1 ,1 [CH]1N=C[N]N1CCCCCCn1cncn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 6.98 A, density 0.92 g/cm3, surface area 5514.55 m2/g, accessible volume 0.57 cm3/g