CdH8(C5N)2(CH)4(C5H5NO)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight n-(2-methyl-2-propenyl)formamide molecules, and four CdH8(C5N)2 clusters. In each CdH8(C5N)2 cluster, Cd(1) is bonded in an L-shaped geometry to two equivalent N(1) atoms. Both Cd(1)-N(1) bond lengths are 2.33 Å. There are five inequivalent C sites. In the first C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-C(4) bond length is 1.39 Å. The C(5)-H(4) bond length is 0.93 Å. In the second C site, C(6) is bonded in a single-bond geometry to one C(4) and one H(5) atom. The C(6)-C(4) bond length is 1.50 Å. The C(6)-H(5) bond length is 0.98 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.93 Å. In the fourth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(2) atom. The C(2)-C(4) bond length is 1.38 Å. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 0.93 Å. In the fifth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(6) atom. N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. Linkers: 1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/C=C\[C].[C]=O.[C]=O.[C]C(=[C])CNC(=O)[C@H]1[C@@H](c2cccnc2)[C@H](C(=O)NCc2ccc(C[N][C]=O)cc2)[C@@H]1c1cccnc1.[C][CH].[C][N].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[NH].[NH].[N].[N].[N].[O] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/[C]=C\C=[C]\CNC(=O)[C@H]1[C@H](c2cccnc2)[C@H](C(=O)NCC(/C=C\[C])=C/[CH])[C@H]1c1cccnc1.[C]/[C]=N\[C].[C]=O.[C]=O.[C]C(=[C])[CH2].[C][CH].[C][CH].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[NH].[NH].[N].[N].[N].[N].[N].[O].[O] ,1 [CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/C=C\[C].[C]=O.[C]=O.[C]C(=[C])CNC(=O)[C@H]1[C@@H](c2cccnc2)[C@H](C(=O)NC[C]/C=C\[C]=[CH])[C@@H]1c1cccnc1.[C][CH].[C][CH][CH].[C][N][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[NH].[NH].[NH].[N].[N].[N].[O].[O] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]c1cccnc1.[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]=O.[C]N=[CH].[C][C@@H]([C][C]=[CH])[CH]C(=O)NCc1ccc(CNC(=O)[CH][C@@H]([C]=[CH])[CH][CH]c2cccnc2)cc1.[C][C].[C][C].[C][C].[C][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[NH].[NH].[N].[N].[N].[N].[N].[O] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]c1cccnc1.[CH]c1cccnc1.[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/C=C(\C=[C])CNC(=O)[CH][CH].[C]=O.[C]=O.[C]=[CH].[C][CH][CH]C(=O)NC[C](C=[C])C=[C].[C][C]([CH])[C]=[CH].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[NH].[NH].[NH].[N].[N].[N].[N].[N].[O].[O] ,1 [CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]c1cccnc1.[CH]c1cccnc1.[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/[C]=[C]\C=[C].[C]=N.[C]=O.[C]=O.[C][C].[C][C].[C][C].[C][C][CH][CH]C(=O)NCc1ccc(CNC(=O)[CH][CH])cc1.[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[NH].[NH].[N].[N].[N].[N].[N].[O].[O] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C]/C=C\[C]CNC(=O)[C@H]1[C@H](c2cccnc2)[C@H](C(=O)NCc2cc[c]cc2)[C@H]1c1cccnc1.[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/[C]=N\[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]C([C])=[C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[NH].[NH].[N].[N].[N].[N]. Metal clusters: 4 [Cd]. The MOF has largest included sphere 3.92 A, density 1.26 g/cm3, surface area 4635.61 m2/g, accessible volume 0.37 cm3/g