Ni3C36H24O13(C11H8)3 is Indium-derived structured and crystallizes in the hexagonal P6/mmm space group. The structure is zero-dimensional and consists of three C11H8 clusters and two Ni3C36H24O13 clusters. In each C11H8 cluster, there are four inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(7) and one H(2) atom. The C(2)-C(7) bond length is 1.37 Å. The C(2)-H(2) bond length is 0.96 Å. In the second C site, C(7) is bonded in a 5-coordinate geometry to one C(8), two equivalent C(2), and two equivalent C(4) atoms. The C(7)-C(8) bond length is 1.50 Å. Both C(7)-C(4) bond lengths are 1.34 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(4)-H(4) bond length is 0.96 Å. In the fourth C site, C(8) is bonded in a trigonal planar geometry to one C(8) and two equivalent C(7) atoms. The C(8)-C(8) bond length is 1.34 Å. There are two inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In each Ni3C36H24O13 cluster, Ni(1) is bonded to one O(2) and four equivalent O(1) atoms to form corner-sharing NiO5 square pyramids. The Ni(1)-O(2) bond length is 1.97 Å. All Ni(1)-O(1) bond lengths are 2.04 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one H(1) atom. The C(1)-C(6) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.96 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(3)-C(6) bond length is 1.40 Å. The C(3)-H(3) bond length is 0.96 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6) and two equivalent O(1) atoms. The C(5)-C(6) bond length is 1.51 Å. Both C(5)-O(1) bond lengths are 1.24 Å. In the fourth C site, C(6) is bonded in a 5-coordinate geometry to one C(5), two equivalent C(1), and two equivalent C(3) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to three equivalent Ni(1) atoms. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(5) atom. Linkers: 2 [C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@@H]4[C@H]5[C@@H]([C@@H]41)C235.[C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@@H]4[C@H]5[C@@H]([C@@H]41)C235.[C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@H]4[C@@H]5[C@H]([C@H]41)C235.[C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@H]4[C@@H]5[C@H]([C@H]41)C235.[C]#[C].[O][C]=O.[O][C]=O.[O][C]=O.[O][C]=O ,2 [C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@@H]4[C@H]5[C@@H]([C@@H]41)C235.[C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@@H]4[C@H]5[C@@H]([C@@H]41)C235.[C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@@H]4[C@H]5[C@@H]([C@@H]41)C235.[C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@H]4[C@@H]5[C@H]([C@H]41)C235.[C]#[C].[O][C]=O.[O][C]=O.[O][C]=O.[O][C]=O. Metal clusters: 2 [C]1O[Ni]23O[C]O[Ni]45(O1)O[C]O[Ni](O[C]O2)(O[C]O3)(O[C]O4)O5. RCSR code: stp. The MOF has largest included sphere 21.82 A, density 0.62 g/cm3, surface area 3236.58 m2/g, accessible volume 1.15 cm3/g