W30Ni15C16P4H62(N9O52)2(CH2)4(CH3)6(CH)8 crystallizes in the monoclinic C2/c space group. The structure consists of thirty-two 02329_fluka molecules, sixteen 02329_fluka molecules, and twenty-four 02329_fluka molecules inside a W30Ni15C16P4H62(N9O52)2 framework. In the W30Ni15C16P4H62(N9O52)2 framework, there are fifteen inequivalent W sites. In the first W site, W(1) is bonded to one O(12), one O(19), one O(28), one O(29), and one O(37) atom to form distorted WO5 square pyramids that share  a cornercorner with one Ni(2)N2O4 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one W(11)O5 square pyramid,  a cornercorner with one W(3)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(2)O5 square pyramid. The corner-sharing octahedral tilt angles range from 48-51°. The W(1)-O(12) bond length is 1.89 Å. The W(1)-O(19) bond length is 1.93 Å. The W(1)-O(28) bond length is 1.78 Å. The W(1)-O(29) bond length is 2.36 Å. The W(1)-O(37) bond length is 2.05 Å. In the second W site, W(2) is bonded to one O(19), one O(25), one O(29), one O(36), and one O(6) atom to form distorted WO5 square pyramids that share  a cornercorner with one Ni(7)N2O4 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one W(14)O5 square pyramid,  a cornercorner with one W(5)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(1)O5 square pyramid. The corner-sharing octahedral tilt angles range from 47-51°. The W(2)-O(19) bond length is 1.92 Å. The W(2)-O(25) bond length is 1.92 Å. The W(2)-O(29) bond length is 2.36 Å. The W(2)-O(36) bond length is 2.06 Å. The W(2)-O(6) bond length is 1.80 Å. In the third W site, W(3) is bonded to one O(12), one O(17), one O(18), one O(3), and one O(40) atom to form distorted WO5 square pyramids that share  a cornercorner with one Ni(2)N2O4 octahedra,  a cornercorner with one Ni(6)O6 octahedra,  a cornercorner with one W(1)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 43-49°. The W(3)-O(12) bond length is 1.92 Å. The W(3)-O(17) bond length is 2.35 Å. The W(3)-O(18) bond length is 1.79 Å. The W(3)-O(3) bond length is 2.01 Å. The W(3)-O(40) bond length is 1.91 Å. In the fourth W site, W(4) is bonded in a 5-coordinate geometry to one O(11), one O(22), one O(26), one O(34), and one O(52) atom. The W(4)-O(11) bond length is 2.40 Å. The W(4)-O(22) bond length is 1.90 Å. The W(4)-O(26) bond length is 1.80 Å. The W(4)-O(34) bond length is 2.00 Å. The W(4)-O(52) bond length is 1.93 Å. In the fifth W site, W(5) is bonded to one O(2), one O(20), one O(25), one O(39), and one O(41) atom to form distorted WO5 square pyramids that share  a cornercorner with one Ni(7)N2O4 octahedra,  a cornercorner with one Ni(5)O6 octahedra,  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(7)O5 square pyramid. The corner-sharing octahedral tilt angles range from 44-50°. The W(5)-O(2) bond length is 2.01 Å. The W(5)-O(20) bond length is 2.33 Å. The W(5)-O(25) bond length is 1.89 Å. The W(5)-O(39) bond length is 1.94 Å. The W(5)-O(41) bond length is 1.81 Å. In the sixth W site, W(6) is bonded to one O(22), one O(23), one O(31), one O(33), and one O(38) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(7)O5 square pyramid and  a cornercorner with one P(2)O4 tetrahedra. The W(6)-O(22) bond length is 1.89 Å. The W(6)-O(23) bond length is 1.93 Å. The W(6)-O(31) bond length is 2.38 Å. The W(6)-O(33) bond length is 1.98 Å. The W(6)-O(38) bond length is 1.79 Å. In the seventh W site, W(7) is bonded to one O(20), one O(21), one O(38), one O(39), and one O(51) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(9)O6 octahedra,  a cornercorner with one Ni(5)O6 octahedra,  a cornercorner with one W(6)O5 square pyramid,  a cornercorner with one Ni(1)N2O3 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(5)O5 square pyramid. The corner-sharing octahedral tilt angles range from 33-47°. The W(7)-O(20) bond length is 2.37 Å. The W(7)-O(21) bond length is 1.95 Å. The W(7)-O(38) bond length is 2.05 Å. The W(7)-O(39) bond length is 1.92 Å. The W(7)-O(51) bond length is 1.81 Å. In the eighth W site, W(8) is bonded in a 6-coordinate geometry to one O(11), one O(3), one O(30), one O(42), one O(52), and one O(9) atom. The W(8)-O(11) bond length is 2.36 Å. The W(8)-O(3) bond length is 1.82 Å. The W(8)-O(30) bond length is 1.89 Å. The W(8)-O(42) bond length is 1.73 Å. The W(8)-O(52) bond length is 1.89 Å. The W(8)-O(9) bond length is 1.98 Å. In the ninth W site, W(9) is bonded to one O(1), one O(17), one O(21), one O(26), one O(27), and one O(40) atom to form distorted WO6 octahedra that share  a cornercorner with one Ni(6)O6 octahedra,  a cornercorner with one W(7)O5 square pyramid,  a cornercorner with one Ni(1)N2O3 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(3)O5 square pyramid. The corner-sharing octahedral tilt angles are 44°. The W(9)-O(1) bond length is 1.80 Å. The W(9)-O(17) bond length is 2.33 Å. The W(9)-O(21) bond length is 1.86 Å. The W(9)-O(26) bond length is 2.04 Å. The W(9)-O(27) bond length is 1.75 Å. The W(9)-O(40) bond length is 1.93 Å. In the tenth W site, W(10) is bonded in a 6-coordinate geometry to one O(2), one O(23), one O(31), one O(32), one O(46), and one O(50) atom. The W(10)-O(2) bond length is 1.81 Å. The W(10)-O(23) bond length is 1.89 Å. The W(10)-O(31) bond length is 2.37 Å. The W(10)-O(32) bond length is 1.97 Å. The W(10)-O(46) bond length is 1.73 Å. The W(10)-O(50) bond length is 1.92 Å. In the eleventh W site, W(11) is bonded to one O(13), one O(30), one O(35), one O(37), and one O(45) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(1)O5 square pyramid,  a cornercorner with one W(12)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(14)O5 square pyramid. The W(11)-O(13) bond length is 2.33 Å. The W(11)-O(30) bond length is 1.89 Å. The W(11)-O(35) bond length is 2.01 Å. The W(11)-O(37) bond length is 1.81 Å. The W(11)-O(45) bond length is 1.92 Å. In the twelfth W site, W(12) is bonded to one O(15), one O(35), one O(44), one O(8), and one O(9) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(11)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(13)O5 square pyramid. The W(12)-O(15) bond length is 2.39 Å. The W(12)-O(35) bond length is 1.86 Å. The W(12)-O(44) bond length is 1.94 Å. The W(12)-O(8) bond length is 1.94 Å. The W(12)-O(9) bond length is 1.88 Å. In the thirteenth W site, W(13) is bonded to one O(15), one O(16), one O(32), one O(4), and one O(44) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(14)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(12)O5 square pyramid. The W(13)-O(15) bond length is 2.41 Å. The W(13)-O(16) bond length is 1.93 Å. The W(13)-O(32) bond length is 1.88 Å. The W(13)-O(4) bond length is 1.87 Å. The W(13)-O(44) bond length is 1.96 Å. In the fourteenth W site, W(14) is bonded to one O(13), one O(36), one O(4), one O(45), and one O(50) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(13)O5 square pyramid,  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(11)O5 square pyramid. The W(14)-O(13) bond length is 2.32 Å. The W(14)-O(36) bond length is 1.82 Å. The W(14)-O(4) bond length is 2.00 Å. The W(14)-O(45) bond length is 1.91 Å. The W(14)-O(50) bond length is 1.86 Å. In the fifteenth W site, W(15) is bonded in a 6-coordinate geometry to one O(10), one O(15), one O(16), one O(33), one O(34), and one O(8) atom. The W(15)-O(10) bond length is 1.75 Å. The W(15)-O(15) bond length is 2.35 Å. The W(15)-O(16) bond length is 1.95 Å. The W(15)-O(33) bond length is 1.86 Å. The W(15)-O(34) bond length is 1.84 Å. The W(15)-O(8) bond length is 1.94 Å. There are eight inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one N(5), one N(6), one O(1), one O(5), and one O(51) atom to form NiN2O3 square pyramids that share  a cornercorner with one W(9)O6 octahedra,  a cornercorner with one W(7)O5 square pyramid,  an edgeedge with one Ni(5)O6 octahedra, and  an edgeedge with one Ni(6)O6 octahedra. The corner-sharing octahedral tilt angles are 54°. The Ni(1)-N(5) bond length is 2.06 Å. The Ni(1)-N(6) bond length is 2.06 Å. The Ni(1)-O(1) bond length is 2.16 Å. The Ni(1)-O(5) bond length is 1.99 Å. The Ni(1)-O(51) bond length is 2.16 Å. In the second Ni site, Ni(2) is bonded to one N(7), one N(8), one O(18), one O(28), one O(43), and one O(47) atom to form NiN2O4 octahedra that share  a cornercorner with one W(1)O5 square pyramid,  a cornercorner with one W(3)O5 square pyramid,  an edgeedge with one Ni(4)O6 octahedra, and  an edgeedge with one Ni(6)O6 octahedra. The Ni(2)-N(7) bond length is 2.04 Å. The Ni(2)-N(8) bond length is 2.02 Å. The Ni(2)-O(18) bond length is 2.10 Å. The Ni(2)-O(28) bond length is 2.27 Å. The Ni(2)-O(43) bond length is 1.99 Å. The Ni(2)-O(47) bond length is 2.07 Å. In the third Ni site, Ni(3) is bonded in a rectangular see-saw-like geometry to one N(4), one N(9), one O(27), and one O(46) atom. The Ni(3)-N(4) bond length is 2.07 Å. The Ni(3)-N(9) bond length is 2.07 Å. The Ni(3)-O(27) bond length is 2.13 Å. The Ni(3)-O(46) bond length is 2.10 Å. In the fourth Ni site, Ni(4) is bonded to one O(10), one O(14), one O(28), one O(43), one O(6), and one O(7) atom to form NiO6 octahedra that share  a cornercorner with one W(1)O5 square pyramid,  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra,  an edgeedge with one Ni(2)N2O4 octahedra,  an edgeedge with one Ni(7)N2O4 octahedra,  an edgeedge with one Ni(5)O6 octahedra, and  an edgeedge with one Ni(6)O6 octahedra. The Ni(4)-O(10) bond length is 2.09 Å. The Ni(4)-O(14) bond length is 2.02 Å. The Ni(4)-O(28) bond length is 2.09 Å. The Ni(4)-O(43) bond length is 1.99 Å. The Ni(4)-O(6) bond length is 2.07 Å. The Ni(4)-O(7) bond length is 2.14 Å. In the fifth Ni site, Ni(5) is bonded to one O(14), one O(41), one O(49), one O(5), one O(51), and one O(7) atom to form NiO6 octahedra that share  a cornercorner with one W(5)O5 square pyramid,  a cornercorner with one W(7)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra,  an edgeedge with one Ni(7)N2O4 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(6)O6 octahedra, and  an edgeedge with one Ni(1)N2O3 square pyramid. The Ni(5)-O(14) bond length is 1.99 Å. The Ni(5)-O(41) bond length is 2.05 Å. The Ni(5)-O(49) bond length is 2.01 Å. The Ni(5)-O(5) bond length is 2.01 Å. The Ni(5)-O(51) bond length is 2.08 Å. The Ni(5)-O(7) bond length is 2.15 Å. In the sixth Ni site, Ni(6) is bonded to one O(1), one O(18), one O(24), one O(43), one O(5), and one O(7) atom to form NiO6 octahedra that share  a cornercorner with one W(9)O6 octahedra,  a cornercorner with one W(3)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra,  an edgeedge with one Ni(2)N2O4 octahedra,  an edgeedge with one Ni(4)O6 octahedra,  an edgeedge with one Ni(5)O6 octahedra, and  an edgeedge with one Ni(1)N2O3 square pyramid. The corner-sharing octahedral tilt angles are 44°. The Ni(6)-O(1) bond length is 2.07 Å. The Ni(6)-O(18) bond length is 2.06 Å. The Ni(6)-O(24) bond length is 2.03 Å. The Ni(6)-O(43) bond length is 2.00 Å. The Ni(6)-O(5) bond length is 2.02 Å. The Ni(6)-O(7) bond length is 2.13 Å. In the seventh Ni site, Ni(7) is bonded to one N(1), one N(3), one O(14), one O(41), one O(48), and one O(6) atom to form NiN2O4 octahedra that share  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one W(5)O5 square pyramid,  an edgeedge with one Ni(4)O6 octahedra, and  an edgeedge with one Ni(5)O6 octahedra. The Ni(7)-N(1) bond length is 2.03 Å. The Ni(7)-N(3) bond length is 2.07 Å. The Ni(7)-O(14) bond length is 2.00 Å. The Ni(7)-O(41) bond length is 2.08 Å. The Ni(7)-O(48) bond length is 2.04 Å. The Ni(7)-O(6) bond length is 2.23 Å. In the eighth Ni site, Ni(8) is bonded in a rectangular see-saw-like geometry to two equivalent N(2) and two equivalent O(42) atoms. Both Ni(8)-N(2) bond lengths are 2.09 Å. Both Ni(8)-O(42) bond lengths are 2.11 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one O(24), and one O(47) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(24) bond length is 1.26 Å. The C(1)-O(47) bond length is 1.27 Å. In the second C site, C(2) is bonded in a water-like geometry to one C(1), one H(19), and one H(20) atom. The C(2)-H(19) bond length is 0.97 Å. The C(2)-H(20) bond length is 0.97 Å. In the third C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one N(5), one H(23), and one H(24) atom. The C(4)-N(5) bond length is 1.42 Å. The C(4)-H(23) bond length is 0.97 Å. The C(4)-H(24) bond length is 0.97 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(17), one O(48), and one O(49) atom. The C(5)-C(17) bond length is 1.54 Å. The C(5)-O(48) bond length is 1.28 Å. The C(5)-O(49) bond length is 1.32 Å. In the fifth C site, C(6) is bonded in a 4-coordinate geometry to one C(7), one N(8), one H(25), and one H(26) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-N(8) bond length is 1.50 Å. The C(6)-H(25) bond length is 0.97 Å. The C(6)-H(26) bond length is 0.97 Å. In the sixth C site, C(7) is bonded in a 4-coordinate geometry to one C(6); one N(7); and two equivalent H(27,28) atoms. The C(7)-N(7) bond length is 1.48 Å. Both C(7)-H(27,28) bond lengths are 0.97 Å. In the seventh C site, C(13) is bonded in a 3-coordinate geometry to one N(4), one H(39), and one H(40) atom. The C(13)-N(4) bond length is 1.41 Å. The C(13)-H(39) bond length is 0.97 Å. The C(13)-H(40) bond length is 0.97 Å. In the eighth C site, C(17) is bonded in a trigonal non-coplanar geometry to one C(5), one H(46), one H(47), and one H(48) atom. The C(17)-H(46) bond length is 0.96 Å. The C(17)-H(47) bond length is 0.96 Å. The C(17)-H(48) bond length is 0.96 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(17), one O(20), one O(29), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one W(9)O6 octahedra,  a cornercorner with one Ni(4)O6 octahedra,  a cornercorner with one Ni(5)O6 octahedra,  a cornercorner with one Ni(6)O6 octahedra,  a cornercorner with one W(1)O5 square pyramid,  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one W(3)O5 square pyramid,  a cornercorner with one W(5)O5 square pyramid, and  a cornercorner with one W(7)O5 square pyramid. The corner-sharing octahedral tilt angles range from 53-58°. The P(1)-O(17) bond length is 1.55 Å. The P(1)-O(20) bond length is 1.55 Å. The P(1)-O(29) bond length is 1.54 Å. The P(1)-O(7) bond length is 1.56 Å. In the second P site, P(2) is bonded to one O(11), one O(13), one O(15), and one O(31) atom to form PO4 tetrahedra that share  a cornercorner with one W(11)O5 square pyramid,  a cornercorner with one W(12)O5 square pyramid,  a cornercorner with one W(13)O5 square pyramid,  a cornercorner with one W(14)O5 square pyramid, and  a cornercorner with one W(6)O5 square pyramid. The P(2)-O(11) bond length is 1.52 Å. The P(2)-O(13) bond length is 1.57 Å. The P(2)-O(15) bond length is 1.55 Å. The P(2)-O(31) bond length is 1.51 Å. There are nine inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one Ni(7), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 0.90 Å. The N(1)-H(2) bond length is 0.90 Å. In the second N site, N(2) is bonded in a 2-coordinate geometry to one Ni(8) and two equivalent H(3,4) atoms. Both N(2)-H(3,4) bond lengths are 0.90 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one Ni(7), one H(5), and one H(6) atom. The N(3)-H(5) bond length is 0.90 Å. The N(3)-H(6) bond length is 0.90 Å. In the fourth N site, N(4) is bonded in a 4-coordinate geometry to one Ni(3), one C(13), one H(7), and one H(8) atom. The N(4)-H(7) bond length is 0.90 Å. The N(4)-H(8) bond length is 0.90 Å. In the fifth N site, N(5) is bonded in a 2-coordinate geometry to one Ni(1), one C(4), one H(10), and one H(9) atom. The N(5)-H(10) bond length is 0.90 Å. The N(5)-H(9) bond length is 0.90 Å. In the sixth N site, N(6) is bonded in a distorted water-like geometry to one Ni(1), one H(11), and one H(12) atom. The N(6)-H(11) bond length is 0.90 Å. The N(6)-H(12) bond length is 0.90 Å. In the seventh N site, N(7) is bonded in a distorted water-like geometry to one Ni(2); one C(7); and two equivalent H(13,14) atoms. Both N(7)-H(13,14) bond lengths are 0.90 Å. In the eighth N site, N(8) is bonded in a distorted water-like geometry to one Ni(2); one C(6); and two equivalent H(15,16) atoms. Both N(8)-H(15,16) bond lengths are 0.90 Å. In the ninth N site, N(9) is bonded in a 2-coordinate geometry to one Ni(3), one H(17), and one H(18) atom. The N(9)-H(17) bond length is 0.90 Å. The N(9)-H(18) bond length is 0.90 Å. There are twenty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one N(4) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one N(5) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one N(5) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one N(6) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one N(6) atom. In the twelfth H site, H(13,14) is bonded in a single-bond geometry to one N(7) atom. In the thirteenth H site, H(15,16) is bonded in a single-bond geometry to one N(8) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one N(9) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one N(9) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(2) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(2) atom. In the eighteenth H site, H(23) is bonded in a single-bond geometry to one C(4) atom. In the nineteenth H site, H(24) is bonded in a single-bond geometry to one C(4) atom. In the twentieth H site, H(25) is bonded in a single-bond geometry to one C(6) atom. In the twenty-first H site, H(26) is bonded in a single-bond geometry to one C(6) atom. In the twenty-second H site, H(27,28) is bonded in a single-bond geometry to one C(7) atom. In the twenty-third H site, H(39) is bonded in a single-bond geometry to one C(13) atom. In the twenty-fourth H site, H(40) is bonded in a single-bond geometry to one C(13) atom. In the twenty-fifth H site, H(46) is bonded in a single-bond geometry to one C(17) atom. In the twenty-sixth H site, H(47) is bonded in a single-bond geometry to one C(17) atom. In the twenty-seventh H site, H(48) is bonded in a single-bond geometry to one C(17) atom. There are fifty-two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one W(9), one Ni(1), and one Ni(6) atom. In the second O site, O(2) is bonded in a linear geometry to one W(10) and one W(5) atom. In the third O site, O(3) is bonded in a linear geometry to one W(3) and one W(8) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one W(13) and one W(14) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Ni(1), one Ni(5), and one Ni(6) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one W(2), one Ni(4), and one Ni(7) atom. In the seventh O site, O(7) is bonded in a rectangular see-saw-like geometry to one Ni(4), one Ni(5), one Ni(6), and one P(1) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one W(12) and one W(15) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one W(12) and one W(8) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one W(15) and one Ni(4) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one W(4), one W(8), and one P(2) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one W(1) and one W(3) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one W(11), one W(14), and one P(2) atom. In the fourteenth O site, O(14) is bonded in a trigonal non-coplanar geometry to one Ni(4), one Ni(5), and one Ni(7) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one W(12), one W(13), one W(15), and one P(2) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one W(13) and one W(15) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one W(3), one W(9), and one P(1) atom. In the eighteenth O site, O(18) is bonded in a distorted T-shaped geometry to one W(3), one Ni(2), and one Ni(6) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one W(1) and one W(2) atom. In the twentieth O site, O(20) is bonded in a distorted single-bond geometry to one W(5), one W(7), and one P(1) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one W(7) and one W(9) atom. In the twenty-second O site, O(22) is bonded in a bent 150 degrees geometry to one W(4) and one W(6) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one W(10) and one W(6) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Ni(6) and one C(1) atom. In the twenty-fifth O site, O(25) is bonded in a bent 150 degrees geometry to one W(2) and one W(5) atom. In the twenty-sixth O site, O(26) is bonded in a linear geometry to one W(4) and one W(9) atom. In the twenty-seventh O site, O(27) is bonded in a distorted bent 150 degrees geometry to one W(9) and one Ni(3) atom. In the twenty-eighth O site, O(28) is bonded in a distorted trigonal planar geometry to one W(1), one Ni(2), and one Ni(4) atom. In the twenty-ninth O site, O(29) is bonded in a distorted single-bond geometry to one W(1), one W(2), and one P(1) atom. In the thirtieth O site, O(30) is bonded in a bent 150 degrees geometry to one W(11) and one W(8) atom. In the thirty-first O site, O(31) is bonded in a distorted single-bond geometry to one W(10), one W(6), and one P(2) atom. In the thirty-second O site, O(32) is bonded in a bent 150 degrees geometry to one W(10) and one W(13) atom. In the thirty-third O site, O(33) is bonded in a bent 150 degrees geometry to one W(15) and one W(6) atom. In the thirty-fourth O site, O(34) is bonded in a bent 150 degrees geometry to one W(15) and one W(4) atom. In the thirty-fifth O site, O(35) is bonded in a bent 150 degrees geometry to one W(11) and one W(12) atom. In the thirty-sixth O site, O(36) is bonded in a distorted linear geometry to one W(14) and one W(2) atom. In the thirty-seventh O site, O(37) is bonded in a linear geometry to one W(1) and one W(11) atom. In the thirty-eighth O site, O(38) is bonded in a linear geometry to one W(6) and one W(7) atom. In the thirty-ninth O site, O(39) is bonded in a bent 120 degrees geometry to one W(5) and one W(7) atom. In the fortieth O site, O(40) is bonded in a bent 120 degrees geometry to one W(3) and one W(9) atom. In the forty-first O site, O(41) is bonded in a distorted T-shaped geometry to one W(5), one Ni(5), and one Ni(7) atom. In the forty-second O site, O(42) is bonded in a bent 150 degrees geometry to one W(8) and one Ni(8) atom. In the forty-third O site, O(43) is bonded in a trigonal non-coplanar geometry to one Ni(2), one Ni(4), and one Ni(6) atom. In the forty-fourth O site, O(44) is bonded in a bent 120 degrees geometry to one W(12) and one W(13) atom. In the forty-fifth O site, O(45) is bonded in a bent 120 degrees geometry to one W(11) and one W(14) atom. In the forty-sixth O site, O(46) is bonded in a distorted bent 150 degrees geometry to one W(10) and one Ni(3) atom. In the forty-seventh O site, O(47) is bonded in a bent 120 degrees geometry to one Ni(2) and one C(1) atom. In the forty-eighth O site, O(48) is bonded in a bent 120 degrees geometry to one Ni(7) and one C(5) atom. In the forty-ninth O site, O(49) is bonded in a bent 120 degrees geometry to one Ni(5) and one C(5) atom. In the fiftieth O site, O(50) is bonded in a bent 150 degrees geometry to one W(10) and one W(14) atom. In the fifty-first O site, O(51) is bonded in a distorted trigonal planar geometry to one W(7), one Ni(1), and one Ni(5) atom. In the fifty-second O site, O(52) is bonded in a bent 120 degrees geometry to one W(4) and one W(8) atom. Linkers: 4 C[C@@H](N)CN ,4 C[C@H](N)CN ,1 N[C@H]1CC[C@@H]1N ,1 N[C@@H]1CC[C@H]1N ,4 [O]C(=O)CCC([O])=O. Metal clusters: 60 [Ni] ,120 [W]. The MOF has largest included sphere 5.96 A, density 3.11 g/cm3, surface area 1464.08 m2/g, accessible volume 0.13 cm3/g