Cd3C42H26(N5O7)2(CH2)4(CH)2 crystallizes in the cubic P4_132 space group. The structure consists of twenty-four 02329_fluka molecules and forty-eight 02329_fluka molecules inside a Cd3C42H26(N5O7)2 framework. In the Cd3C42H26(N5O7)2 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted octahedral geometry to one N(5), one O(1), one O(3), one O(4), one O(5), and one O(7) atom. The Cd(1)-N(5) bond length is 2.27 Å. The Cd(1)-O(1) bond length is 2.61 Å. The Cd(1)-O(3) bond length is 2.44 Å. The Cd(1)-O(4) bond length is 2.34 Å. The Cd(1)-O(5) bond length is 2.19 Å. The Cd(1)-O(7) bond length is 2.49 Å. In the second Cd site, Cd(2) is bonded in a see-saw-like geometry to two equivalent N(3) and two equivalent O(1) atoms. Both Cd(2)-N(3) bond lengths are 2.25 Å. Both Cd(2)-O(1) bond lengths are 2.19 Å. There are twenty-one inequivalent C sites. In the first C site, C(22) is bonded in a distorted single-bond geometry to two equivalent C(2) and one H(2) atom. There is one shorter (1.37 Å) and one longer (1.39 Å) C(22)-C(2) bond length. The C(22)-H(2) bond length is 0.93 Å. In the second C site, C(23) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(20) atom. The C(23)-C(10) bond length is 1.38 Å. The C(23)-C(13) bond length is 1.31 Å. The C(23)-C(20) bond length is 1.48 Å. In the third C site, C(24) is bonded in a distorted single-bond geometry to one N(2) atom. The C(24)-N(2) bond length is 1.38 Å. In the fourth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(14), one N(5), and one H(11) atom. The C(1)-C(14) bond length is 1.27 Å. The C(1)-N(5) bond length is 1.29 Å. The C(1)-H(11) bond length is 0.93 Å. In the fifth C site, C(2) is bonded in a distorted trigonal planar geometry to two equivalent C(22) and one N(4) atom. The C(2)-N(4) bond length is 1.42 Å. In the sixth C site, C(3) is bonded in a trigonal planar geometry to one C(10), one C(15), and one C(21) atom. The C(3)-C(10) bond length is 1.31 Å. The C(3)-C(15) bond length is 1.53 Å. The C(3)-C(21) bond length is 1.42 Å. In the seventh C site, C(5) is bonded in a distorted trigonal planar geometry to one C(18), one N(2), and one H(17) atom. The C(5)-C(18) bond length is 1.36 Å. The C(5)-N(2) bond length is 1.36 Å. The C(5)-H(17) bond length is 0.93 Å. In the eighth C site, C(6) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(3) atom. The C(6)-N(2) bond length is 1.36 Å. The C(6)-N(3) bond length is 1.33 Å. The C(6)-H(3) bond length is 0.93 Å. In the ninth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(7)-O(1) bond length is 1.25 Å. The C(7)-O(4) bond length is 1.26 Å. In the tenth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(14), and one H(16) atom. The C(8)-N(1) bond length is 1.40 Å. The C(8)-H(14) bond length is 0.97 Å. The C(8)-H(16) bond length is 0.97 Å. In the eleventh C site, C(9) is bonded in a trigonal planar geometry to one C(13), one C(19), and one C(21) atom. The C(9)-C(13) bond length is 1.35 Å. The C(9)-C(19) bond length is 1.53 Å. The C(9)-C(21) bond length is 1.45 Å. In the twelfth C site, C(10) is bonded in a distorted single-bond geometry to one C(23), one C(3), and one H(12) atom. The C(10)-H(12) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(23), one C(9), and one H(4) atom. The C(13)-H(4) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a 3-coordinate geometry to one C(1), one N(4), and one H(6) atom. The C(14)-N(4) bond length is 1.39 Å. The C(14)-H(6) bond length is 0.93 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(7) atom. The C(15)-O(3) bond length is 1.25 Å. The C(15)-O(7) bond length is 1.29 Å. In the sixteenth C site, C(16) is bonded in a 2-coordinate geometry to one N(1) and one H(10) atom. The C(16)-N(1) bond length is 1.44 Å. The C(16)-H(10) bond length is 0.98 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(18) atom. The C(17)-N(4) bond length is 1.39 Å. The C(17)-N(5) bond length is 1.33 Å. The C(17)-H(18) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(3), and one H(13) atom. The C(18)-N(3) bond length is 1.29 Å. The C(18)-H(13) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a 2-coordinate geometry to one C(9), one O(2), and one O(5) atom. The C(19)-O(2) bond length is 1.26 Å. The C(19)-O(5) bond length is 1.16 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(23), one N(1), and one O(6) atom. The C(20)-N(1) bond length is 1.33 Å. The C(20)-O(6) bond length is 1.24 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(3), one C(9), and one H(15) atom. The C(21)-H(15) bond length is 0.93 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(8) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(24), one C(5), and one C(6) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(18), and one C(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(14), one C(17), and one C(2) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(17) atom. There are thirteen inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(22) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(1) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(8) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(5) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(17) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(7) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(19) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Cd(1) and one C(7) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(19) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(20) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(15) atom. Linkers: 16 c1cn(-c2cc(-n3ccnc3)cc(-n3ccnc3)c2)cn1 ,24 [O]C(=O)c1cc(C([O])=O)cc(C(=O)N2CCC[C@H]2C([O])=O)c1. Metal clusters: 12 O=[C]O[Cd]1(O[C]O[Cd]O[C]O[Cd]2(O[C]=O)O[C]O2)O[C]O1. The MOF has largest included sphere 11.67 A, density 1.01 g/cm3, surface area 4014.02 m2/g, accessible volume 0.57 cm3/g