CH3(CH)2Co2C27N6H25O10FCFC4H2OF is Indium-derived structured and crystallizes in the orthorhombic I222 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight 02329_fluka molecules, eight 3-fluoro-2-methylprop-2-en-1-ol molecules, eight fluoromethane molecules, and four Co2C27N6H25O10F clusters. In each Co2C27N6H25O10F cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(2), one O(1), one O(3), one O(5), one O(7), and one O(9) atom to form corner-sharing CoNO5 octahedra. The Co(1)-N(2) bond length is 2.15 Å. The Co(1)-O(1) bond length is 2.08 Å. The Co(1)-O(3) bond length is 2.10 Å. The Co(1)-O(5) bond length is 2.08 Å. The Co(1)-O(7) bond length is 2.10 Å. The Co(1)-O(9) bond length is 2.17 Å. In the second Co site, Co(2) is bonded to one N(6), one O(10), one O(2), one O(4), and one O(9) atom to form corner-sharing CoNO4 square pyramids. The corner-sharing octahedral tilt angles are 67°. The Co(2)-N(6) bond length is 2.10 Å. The Co(2)-O(10) bond length is 2.13 Å. The Co(2)-O(2) bond length is 2.05 Å. The Co(2)-O(4) bond length is 2.07 Å. The Co(2)-O(9) bond length is 2.09 Å. There are twenty-seven inequivalent C sites. In the first C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(5), and one O(6) atom. The C(9)-C(11) bond length is 1.51 Å. The C(9)-O(5) bond length is 1.26 Å. The C(9)-O(6) bond length is 1.29 Å. In the second C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(5) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(5) bond length is 0.93 Å. In the third C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(9) atom. The C(11)-C(12) bond length is 1.39 Å. In the fourth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(12)-H(6) bond length is 0.93 Å. In the fifth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(7), and one O(8) atom. The C(13)-C(15) bond length is 1.50 Å. The C(13)-O(7) bond length is 1.26 Å. The C(13)-O(8) bond length is 1.25 Å. In the sixth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(7) atom. The C(14)-C(15) bond length is 1.43 Å. The C(14)-H(7) bond length is 0.93 Å. In the seventh C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(16) atom. The C(15)-C(16) bond length is 1.39 Å. In the eighth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(8) atom. The C(16)-H(8) bond length is 0.93 Å. In the ninth C site, C(18) is bonded in a 7-coordinate geometry to one N(1), one H(10), one H(11), one H(12), one H(30), one H(31), and one H(32) atom. The C(18)-N(1) bond length is 1.46 Å. The C(18)-H(10) bond length is 0.96 Å. The C(18)-H(11) bond length is 0.96 Å. The C(18)-H(12) bond length is 0.96 Å. The C(18)-H(30) bond length is 0.96 Å. The C(18)-H(31) bond length is 0.96 Å. The C(18)-H(32) bond length is 0.96 Å. In the tenth C site, C(19) is bonded in a tetrahedral geometry to one N(1), one H(13), one H(14), and one H(15) atom. The C(19)-N(1) bond length is 1.51 Å. The C(19)-H(13) bond length is 0.96 Å. The C(19)-H(14) bond length is 0.96 Å. The C(19)-H(15) bond length is 0.96 Å. In the eleventh C site, C(33) is bonded in a 3-coordinate geometry to one N(4) and two equivalent H(25,26) atoms. The C(33)-N(4) bond length is 1.46 Å. Both C(33)-H(25,26) bond lengths are 0.97 Å. In the twelfth C site, C(20) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(16) atom. The C(20)-N(2) bond length is 1.38 Å. The C(20)-N(3) bond length is 1.38 Å. The C(20)-H(16) bond length is 0.93 Å. In the thirteenth C site, C(34) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(27) atom. The C(34)-N(5) bond length is 1.31 Å. The C(34)-N(6) bond length is 1.36 Å. The C(34)-H(27) bond length is 0.93 Å. In the fourteenth C site, C(35) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(28) atom. The C(35)-N(4) bond length is 1.32 Å. The C(35)-N(6) bond length is 1.31 Å. The C(35)-H(28) bond length is 0.93 Å. In the fifteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one N(3) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-C(24) bond length is 1.49 Å. The C(21)-N(3) bond length is 1.36 Å. In the sixteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one F(1) atom. The C(22)-C(23) bond length is 1.38 Å. The C(22)-F(1) bond length is 1.31 Å. In the seventeenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one N(2), and one H(17) atom. The C(23)-N(2) bond length is 1.38 Å. The C(23)-H(17) bond length is 0.93 Å. In the eighteenth C site, C(24) is bonded in a single-bond geometry to one C(21) and one H(18) atom. The C(24)-H(18) bond length is 0.98 Å. In the nineteenth C site, C(17) is bonded in a trigonal planar geometry to one N(1), one H(9), and one O(10) atom. The C(17)-N(1) bond length is 1.40 Å. The C(17)-H(9) bond length is 0.93 Å. The C(17)-O(10) bond length is 1.23 Å. In the twentieth C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.38 Å. The C(1)-C(7) bond length is 1.51 Å. In the twenty-first C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.93 Å. In the twenty-second C site, C(3) is bonded in a single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.37 Å. The C(3)-H(2) bond length is 0.93 Å. In the twenty-third C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(8) bond length is 1.52 Å. In the twenty-fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 0.93 Å. In the twenty-fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the twenty-sixth C site, C(7) is bonded in a bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.25 Å. The C(7)-O(2) bond length is 1.27 Å. In the twenty-seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.25 Å. The C(8)-O(4) bond length is 1.30 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(19) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(20), and one C(23) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(20) and one C(21) atom. In the fourth N site, N(4) is bonded in a 2-coordinate geometry to one C(33) and one C(35) atom. In the fifth N site, N(5) is bonded in a distorted single-bond geometry to one C(34) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Co(2), one C(34), and one C(35) atom. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(10) is bonded in a distorted single-bond geometry to one C(18), one H(31), and one H(32) atom. The H(10)-H(31) bond length is 0.90 Å. The H(10)-H(32) bond length is 0.91 Å. In the eleventh H site, H(11) is bonded in a distorted single-bond geometry to one C(18) atom. In the twelfth H site, H(12) is bonded in a 4-coordinate geometry to one C(18), one H(12), one H(30), and one H(31) atom. The H(12)-H(12) bond length is 0.90 Å. The H(12)-H(30) bond length is 0.91 Å. The H(12)-H(31) bond length is 0.91 Å. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the nineteenth H site, H(30) is bonded in a 1-coordinate geometry to one C(18) and one H(12) atom. In the twentieth H site, H(31) is bonded in a 3-coordinate geometry to one C(18), one H(10), and one H(12) atom. In the twenty-first H site, H(32) is bonded in a distorted single-bond geometry to one C(18) and one H(10) atom. In the twenty-second H site, H(25,26) is bonded in a single-bond geometry to one C(33) atom. In the twenty-third H site, H(27) is bonded in a single-bond geometry to one C(34) atom. In the twenty-fourth H site, H(28) is bonded in a single-bond geometry to one C(35) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one C(7) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(8) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Co(1) and one C(9) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Co(1) and one C(13) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(13) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Co(1) and one Co(2) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one C(17) atom. F(1) is bonded in a single-bond geometry to one C(22) atom. Linkers: 16 [O]C(=O)c1ccc(C([O])=O)cc1 ,5 C[C@@H](c1ncncc1F)[C@](O)(Cn1cncn1)c1ccc(F)cc1F ,1 C[C@@H]([C]1N=C[N]C=C1F)[C@](O)(Cn1cncn1)c1ccc(F)cc1F ,2 C[C@@H](C1=C(F)[CH]N=C[N]1)[C@](O)(Cn1cncn1)c1ccc(F)cc1F. Metal clusters: 16 [Co]. The MOF has largest included sphere 5.87 A, density 1.00 g/cm3, surface area 4499.51 m2/g, accessible volume 0.52 cm3/g