W9Co4C34PN11H22O29C2NH2 crystallizes in the orthorhombic Pbca space group. The structure consists of eight n-methyl methanimine molecules inside a W9Co4C34PN11H22O29 framework. In the W9Co4C34PN11H22O29 framework, there are nine inequivalent W sites. In the first W site, W(1) is bonded in a 5-coordinate geometry to one O(17), one O(20), one O(21), one O(24), and one O(28) atom. The W(1)-O(17) bond length is 1.86 Å. The W(1)-O(20) bond length is 1.88 Å. The W(1)-O(21) bond length is 1.90 Å. The W(1)-O(24) bond length is 1.73 Å. The W(1)-O(28) bond length is 1.97 Å. In the second W site, W(2) is bonded in a 5-coordinate geometry to one O(16), one O(19), one O(20), one O(4), and one O(9) atom. The W(2)-O(16) bond length is 1.91 Å. The W(2)-O(19) bond length is 1.83 Å. The W(2)-O(20) bond length is 1.96 Å. The W(2)-O(4) bond length is 2.41 Å. The W(2)-O(9) bond length is 1.88 Å. In the third W site, W(3) is bonded in a 5-coordinate geometry to one O(1), one O(13), one O(26), one O(6), and one O(9) atom. The W(3)-O(1) bond length is 2.47 Å. The W(3)-O(13) bond length is 1.83 Å. The W(3)-O(26) bond length is 1.95 Å. The W(3)-O(6) bond length is 1.86 Å. The W(3)-O(9) bond length is 1.95 Å. In the fourth W site, W(4) is bonded to one O(1), one O(5), one O(6), one O(7), and one O(8) atom to form distorted WO5 square pyramids that share  a cornercorner with one Co(2)O6 octahedra and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 45°. The W(4)-O(1) bond length is 2.42 Å. The W(4)-O(5) bond length is 1.80 Å. The W(4)-O(6) bond length is 1.98 Å. The W(4)-O(7) bond length is 1.98 Å. The W(4)-O(8) bond length is 1.92 Å. In the fifth W site, W(5) is bonded in a 5-coordinate geometry to one O(12), one O(2), one O(21), one O(22), and one O(23) atom. The W(5)-O(12) bond length is 1.88 Å. The W(5)-O(2) bond length is 2.56 Å. The W(5)-O(21) bond length is 1.93 Å. The W(5)-O(22) bond length is 1.91 Å. The W(5)-O(23) bond length is 1.88 Å. In the sixth W site, W(6) is bonded in a 6-coordinate geometry to one O(15), one O(18), one O(2), one O(23), one O(27), and one O(29) atom. The W(6)-O(15) bond length is 1.76 Å. The W(6)-O(18) bond length is 1.92 Å. The W(6)-O(2) bond length is 2.40 Å. The W(6)-O(23) bond length is 2.02 Å. The W(6)-O(27) bond length is 1.95 Å. The W(6)-O(29) bond length is 1.75 Å. In the seventh W site, W(7) is bonded in a 5-coordinate geometry to one O(14), one O(16), one O(17), one O(18), and one O(4) atom. The W(7)-O(14) bond length is 1.76 Å. The W(7)-O(16) bond length is 1.96 Å. The W(7)-O(17) bond length is 2.01 Å. The W(7)-O(18) bond length is 1.89 Å. The W(7)-O(4) bond length is 2.42 Å. In the eighth W site, W(8) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(12), one O(2), one O(27), and one O(8) atom. The W(8)-O(10) bond length is 1.78 Å. The W(8)-O(11) bond length is 1.75 Å. The W(8)-O(12) bond length is 2.03 Å. The W(8)-O(2) bond length is 2.41 Å. The W(8)-O(27) bond length is 1.92 Å. The W(8)-O(8) bond length is 1.91 Å. In the ninth W site, W(9) is bonded in a 5-coordinate geometry to one O(22), one O(25), one O(26), one O(28), and one O(7) atom. The W(9)-O(22) bond length is 1.91 Å. The W(9)-O(25) bond length is 1.74 Å. The W(9)-O(26) bond length is 1.89 Å. The W(9)-O(28) bond length is 1.86 Å. The W(9)-O(7) bond length is 1.89 Å. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(10), one O(13), one O(15), one O(19), and one O(3) atom to form CoO5 square pyramids that share  a cornercorner with one P(1)O4 tetrahedra and edges with two equivalent Co(2)O6 octahedra. The Co(1)-O(10) bond length is 2.05 Å. The Co(1)-O(13) bond length is 2.09 Å. The Co(1)-O(15) bond length is 2.06 Å. The Co(1)-O(19) bond length is 2.12 Å. The Co(1)-O(3) bond length is 2.15 Å. In the second Co site, Co(2) is bonded to one O(13), one O(14), one O(19), one O(5), and two equivalent O(3) atoms to form CoO6 octahedra that share  a cornercorner with one W(4)O5 square pyramid, corners with two equivalent P(1)O4 tetrahedra,  an edgeedge with one Co(2)O6 octahedra, and edges with two equivalent Co(1)O5 square pyramids. The Co(2)-O(13) bond length is 2.03 Å. The Co(2)-O(14) bond length is 2.00 Å. The Co(2)-O(19) bond length is 2.05 Å. The Co(2)-O(5) bond length is 2.04 Å. There is one shorter (2.23 Å) and one longer (2.30 Å) Co(2)-O(3) bond length. In the third Co site, Co(3) is bonded in a rectangular see-saw-like geometry to one N(1), one N(11), one O(24), and one O(25) atom. The Co(3)-N(1) bond length is 2.12 Å. The Co(3)-N(11) bond length is 2.12 Å. The Co(3)-O(24) bond length is 2.10 Å. The Co(3)-O(25) bond length is 2.13 Å. In the fourth Co site, Co(4) is bonded in a T-shaped geometry to one N(2), one O(11), and one O(29) atom. The Co(4)-N(2) bond length is 2.14 Å. The Co(4)-O(11) bond length is 2.18 Å. The Co(4)-O(29) bond length is 2.10 Å. There are thirty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(22), one N(6), and one N(7) atom. The C(1)-C(22) bond length is 1.48 Å. The C(1)-N(6) bond length is 1.33 Å. The C(1)-N(7) bond length is 1.31 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(4), one N(6), and one N(8) atom. The C(2)-C(4) bond length is 1.50 Å. The C(2)-N(6) bond length is 1.31 Å. The C(2)-N(8) bond length is 1.34 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(7), and one N(8) atom. The C(3)-C(5) bond length is 1.52 Å. The C(3)-N(7) bond length is 1.32 Å. The C(3)-N(8) bond length is 1.32 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(30), and one C(32) atom. The C(4)-C(30) bond length is 1.36 Å. The C(4)-C(32) bond length is 1.37 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(3), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.37 Å. The C(5)-C(7) bond length is 1.38 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(21), one C(5), and one H(1) atom. The C(6)-C(21) bond length is 1.37 Å. The C(6)-H(1) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(7)-H(2) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(3) atom. The C(8)-N(9) bond length is 1.32 Å. The C(8)-H(3) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(3), and one N(4) atom. The C(9)-C(15) bond length is 1.49 Å. The C(9)-N(3) bond length is 1.34 Å. The C(9)-N(4) bond length is 1.31 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(17), one N(3), and one N(5) atom. The C(10)-C(17) bond length is 1.51 Å. The C(10)-N(3) bond length is 1.32 Å. The C(10)-N(5) bond length is 1.31 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(4), and one N(5) atom. The C(11)-C(12) bond length is 1.52 Å. The C(11)-N(4) bond length is 1.32 Å. The C(11)-N(5) bond length is 1.34 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(24) atom. The C(12)-C(13) bond length is 1.36 Å. The C(12)-C(24) bond length is 1.35 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(4) atom. The C(13)-H(4) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(14)-N(1) bond length is 1.35 Å. The C(14)-H(5) bond length is 0.93 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(16), one C(34), and one C(9) atom. The C(15)-C(16) bond length is 1.37 Å. The C(15)-C(34) bond length is 1.37 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(6) atom. The C(16)-H(6) bond length is 0.93 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(10), one C(18), and one C(26) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(26) bond length is 1.37 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(7) atom. The C(18)-C(19) bond length is 1.36 Å. The C(18)-H(7) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(10), and one H(8) atom. The C(19)-N(10) bond length is 1.37 Å. The C(19)-H(8) bond length is 0.93 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(24), one N(1), and one H(9) atom. The C(20)-C(24) bond length is 1.42 Å. The C(20)-N(1) bond length is 1.33 Å. The C(20)-H(9) bond length is 0.93 Å. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(9), and one H(10) atom. The C(21)-N(9) bond length is 1.36 Å. The C(21)-H(10) bond length is 0.93 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(1), one C(23), and one C(28) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(28) bond length is 1.37 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(22), one C(25), and one H(11) atom. The C(23)-C(25) bond length is 1.35 Å. The C(23)-H(11) bond length is 0.93 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(12), one C(20), and one H(12) atom. The C(24)-H(12) bond length is 0.93 Å. In the twenty-fifth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(23), one N(11), and one H(13) atom. The C(25)-N(11) bond length is 1.34 Å. The C(25)-H(13) bond length is 0.93 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(17), one C(36), and one H(14) atom. The C(26)-C(36) bond length is 1.35 Å. The C(26)-H(14) bond length is 0.93 Å. In the twenty-seventh C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(15) atom. The C(27)-N(2) bond length is 1.34 Å. The C(27)-H(15) bond length is 0.93 Å. In the twenty-eighth C site, C(28) is bonded in a distorted single-bond geometry to one C(22), one C(29), and one H(16) atom. The C(28)-C(29) bond length is 1.37 Å. The C(28)-H(16) bond length is 0.93 Å. In the twenty-ninth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one N(11), and one H(17) atom. The C(29)-N(11) bond length is 1.36 Å. The C(29)-H(17) bond length is 0.93 Å. In the thirtieth C site, C(30) is bonded in a distorted single-bond geometry to one C(4) and one H(18) atom. The C(30)-H(18) bond length is 0.93 Å. In the thirty-first C site, C(32) is bonded in a distorted single-bond geometry to one C(4) and one H(20) atom. The C(32)-H(20) bond length is 0.93 Å. In the thirty-second C site, C(34) is bonded in a distorted single-bond geometry to one C(15) and one H(22) atom. The C(34)-H(22) bond length is 0.93 Å. In the thirty-third C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(23) atom. The C(35)-N(2) bond length is 1.31 Å. The C(35)-H(23) bond length is 0.93 Å. In the thirty-fourth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(26), one N(10), and one H(24) atom. The C(36)-N(10) bond length is 1.36 Å. The C(36)-H(24) bond length is 0.93 Å. P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share corners with two equivalent Co(2)O6 octahedra,  a cornercorner with one W(4)O5 square pyramid, and  a cornercorner with one Co(1)O5 square pyramid. The corner-sharing octahedral tilt angles range from 57-58°. The P(1)-O(1) bond length is 1.53 Å. The P(1)-O(2) bond length is 1.55 Å. The P(1)-O(3) bond length is 1.54 Å. The P(1)-O(4) bond length is 1.55 Å. There are eleven inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(3), one C(14), and one C(20) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(4), one C(27), and one C(35) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(10) and one C(9) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(11) and one C(9) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(10) and one C(11) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the seventh N site, N(7) is bonded in a bent 120 degrees geometry to one C(1) and one C(3) atom. In the eighth N site, N(8) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. In the ninth N site, N(9) is bonded in a bent 120 degrees geometry to one C(21) and one C(8) atom. In the tenth N site, N(10) is bonded in a bent 120 degrees geometry to one C(19) and one C(36) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Co(3), one C(25), and one C(29) atom. There are twenty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(24) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(25) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(26) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(28) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(29) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(32) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(34) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(35) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(36) atom. There are twenty-nine inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one W(3), one W(4), and one P(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one W(5), one W(6), one W(8), and one P(1) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Co(1), two equivalent Co(2), and one P(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one W(2), one W(7), and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one W(4) and one Co(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one W(3) and one W(4) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one W(4) and one W(9) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one W(4) and one W(8) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one W(2) and one W(3) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one W(8) and one Co(1) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one W(8) and one Co(4) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one W(5) and one W(8) atom. In the thirteenth O site, O(13) is bonded in a trigonal planar geometry to one W(3), one Co(1), and one Co(2) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one W(7) and one Co(2) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one W(6) and one Co(1) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one W(2) and one W(7) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one W(1) and one W(7) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one W(6) and one W(7) atom. In the nineteenth O site, O(19) is bonded in a trigonal planar geometry to one W(2), one Co(1), and one Co(2) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one W(1) and one W(2) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one W(1) and one W(5) atom. In the twenty-second O site, O(22) is bonded in a bent 150 degrees geometry to one W(5) and one W(9) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one W(5) and one W(6) atom. In the twenty-fourth O site, O(24) is bonded in a linear geometry to one W(1) and one Co(3) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 150 degrees geometry to one W(9) and one Co(3) atom. In the twenty-sixth O site, O(26) is bonded in a bent 120 degrees geometry to one W(3) and one W(9) atom. In the twenty-seventh O site, O(27) is bonded in a bent 120 degrees geometry to one W(6) and one W(8) atom. In the twenty-eighth O site, O(28) is bonded in a bent 150 degrees geometry to one W(1) and one W(9) atom. In the twenty-ninth O site, O(29) is bonded in a distorted linear geometry to one W(6) and one Co(4) atom. Linkers: 8 n1ccc(cc1)C1=NC(=[N]=C([N]1)c1ccncc1)c1ccncc1. Metal clusters: 32 [Co] ,72 [W]. The MOF has largest included sphere 5.13 A, density 2.82 g/cm3, surface area 1763.76 m2/g, accessible volume 0.15 cm3/g