Fe4C24N32H8Cl crystallizes in the cubic Pm-3m space group. Fe(1) is bonded to four equivalent N(1) and one Cl(1) atom to form corner-sharing FeN4Cl square pyramids. All Fe(1)-N(1) bond lengths are 2.15 Å. The Fe(1)-Cl(1) bond length is 2.56 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one C(2) and two equivalent N(2) atoms. The C(1)-C(2) bond length is 1.44 Å. Both C(1)-N(2) bond lengths are 1.36 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1) and two equivalent C(3) atoms. Both C(2)-C(3) bond lengths are 1.41 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to two equivalent C(2) and one H(1) atom. The C(3)-H(1) bond length is 1.04 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Fe(1), one N(1), and one N(2) atom. The N(1)-N(1) bond length is 1.32 Å. The N(1)-N(2) bond length is 1.31 Å. In the second N site, N(2) is bonded in a water-like geometry to one C(1) and one N(1) atom. H(1) is bonded in a single-bond geometry to one C(3) atom. Cl(1) is bonded in a square co-planar geometry to four equivalent Fe(1) atoms. Linkers: 8 c1c(C2=NN=N[N]2)cc(C2=NN=N[N]2)cc1C1=NN=N[N]1. Metal clusters: 2 Cl[Fe]123N=N[Fe@]4(=N[N][Fe@@]5(=NN=[Fe@@](N=N5)(N=N1)N=N2)N=N4)N=N3 ,1 Cl[Fe]123N=N[Fe@]4(=N[N][Fe@]5(=NN=[Fe@@](N=N5)(N=N1)N=N2)N=N4)N=N3. The MOF has largest included sphere 15.68 A, density 0.74 g/cm3, surface area 3532.03 m2/g, accessible volume 0.97 cm3/g