MnC44H40(NO)6(C4H5)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four isobutylene molecules and one MnC44H40(NO)6 cluster. In the MnC44H40(NO)6 cluster, Mn(1) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. Both Mn(1)-O(1) bond lengths are 2.17 Å. Both Mn(1)-O(2) bond lengths are 2.19 Å. Both Mn(1)-O(3) bond lengths are 2.18 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(1) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-O(1) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(2)-C(3) bond length is 1.36 Å. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(6) bond length is 1.51 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.33 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(3) atom. The C(5)-N(1) bond length is 1.36 Å. The C(5)-H(3) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one H(4), one H(5), and one H(6) atom. The C(6)-H(4) bond length is 0.96 Å. The C(6)-H(5) bond length is 1.26 Å. The C(6)-H(6) bond length is 0.96 Å. In the seventh C site, C(7) is bonded in a 3-coordinate geometry to one C(8); one N(1); and two equivalent H(7,8) atoms. The C(7)-C(8) bond length is 1.51 Å. The C(7)-N(1) bond length is 1.49 Å. Both C(7)-H(7,8) bond lengths are 0.97 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.39 Å. The C(8)-C(9) bond length is 1.38 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(9) atom. The C(9)-H(9) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(10) atom. The C(10)-H(10) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(2) atom. The C(11)-N(2) bond length is 1.37 Å. The C(11)-O(2) bond length is 1.27 Å. In the twelfth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(13) atom. The C(15)-N(2) bond length is 1.36 Å. The C(15)-H(13) bond length is 0.93 Å. In the thirteenth C site, C(17) is bonded in a 3-coordinate geometry to one C(18), one N(2), one H(17), and one H(18) atom. The C(17)-C(18) bond length is 1.53 Å. The C(17)-N(2) bond length is 1.48 Å. The C(17)-H(17) bond length is 0.97 Å. The C(17)-H(18) bond length is 0.97 Å. In the fourteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(20) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-C(20) bond length is 1.36 Å. In the fifteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(19) atom. The C(19)-H(19) bond length is 0.93 Å. In the sixteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(18) and one H(20) atom. The C(20)-H(20) bond length is 0.93 Å. In the seventeenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(3) and one O(3) atom. The C(21)-N(3) bond length is 1.38 Å. The C(21)-O(3) bond length is 1.25 Å. In the eighteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(23) atom. The C(25)-N(3) bond length is 1.40 Å. The C(25)-H(23) bond length is 0.93 Å. In the nineteenth C site, C(27) is bonded in a 3-coordinate geometry to one C(28); one N(3); and two equivalent H(27,28) atoms. The C(27)-C(28) bond length is 1.51 Å. The C(27)-N(3) bond length is 1.45 Å. Both C(27)-H(27,28) bond lengths are 0.97 Å. In the twentieth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(30) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-C(30) bond length is 1.37 Å. In the twenty-first C site, C(29) is bonded in a single-bond geometry to one C(28) and one H(29) atom. The C(29)-H(29) bond length is 0.93 Å. In the twenty-second C site, C(30) is bonded in a single-bond geometry to one C(28) and one H(30) atom. The C(30)-H(30) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(17) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(27) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7,8) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the fifteenth H site, H(23) is bonded in a single-bond geometry to one C(25) atom. In the sixteenth H site, H(27,28) is bonded in a single-bond geometry to one C(27) atom. In the seventeenth H site, H(29) is bonded in a single-bond geometry to one C(29) atom. In the eighteenth H site, H(30) is bonded in a single-bond geometry to one C(30) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(11) atom. In the second O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(21) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(1) atom. Linkers: 3 Cc1ccn(Cc2ccc(Cn3ccc(C)cc3=O)cc2)c(=O)c1 ,1 [CH2]c1ccn(Cc2ccc(Cn3ccc([CH2])cc3=O)cc2)c(=O)c1. Metal clusters: 1 [O][Mn]([O])([O])([O])([O])[O]. RCSR code: pcu. The MOF has largest included sphere 4.42 A, density 1.16 g/cm3, surface area 5783.85 m2/g, accessible volume 0.29 cm3/g