CuC22N3H14CuH8(C6N)2(Si(C3H2)4)2(CuC12NH6O4)2(C2H)12(CH3)4C2NH2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; six hexa-1,5-diene-3-yne, 2,5-dimethyl- molecules; two n-methyl methanimine molecules; four tetrakis(prop-1-en-2-yl)silane molecules; two CuC12NH6O4 clusters; two CuC22N3H14 clusters; and two CuH8(C6N)2 clusters. In each CuC12NH6O4 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(4), one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-N(4) bond length is 2.21 Å. The Cu(1)-O(1) bond length is 1.94 Å. The Cu(1)-O(2) bond length is 2.00 Å. The Cu(1)-O(3) bond length is 2.00 Å. The Cu(1)-O(4) bond length is 2.04 Å. There are twelve inequivalent C sites. In the first C site, C(105) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(105)-O(1) bond length is 1.23 Å. The C(105)-O(2) bond length is 1.26 Å. In the second C site, C(107) is bonded in a 2-coordinate geometry to one O(3) and one O(4) atom. The C(107)-O(3) bond length is 1.23 Å. The C(107)-O(4) bond length is 1.23 Å. In the third C site, C(42) is bonded in a distorted single-bond geometry to one C(43) and one H(26) atom. The C(42)-C(43) bond length is 1.36 Å. The C(42)-H(26) bond length is 0.95 Å. In the fourth C site, C(43) is bonded in a trigonal planar geometry to one C(42), one C(44), and one C(46) atom. The C(43)-C(44) bond length is 1.39 Å. The C(43)-C(46) bond length is 1.42 Å. In the fifth C site, C(44) is bonded in a distorted single-bond geometry to one C(43) and one H(27) atom. The C(44)-H(27) bond length is 0.95 Å. In the sixth C site, C(46) is bonded in a linear geometry to one C(43) and one C(52) atom. The C(46)-C(52) bond length is 1.19 Å. In the seventh C site, C(47) is bonded in a distorted trigonal planar geometry to one C(48), one N(4), and one H(29) atom. The C(47)-C(48) bond length is 1.42 Å. The C(47)-N(4) bond length is 1.33 Å. The C(47)-H(29) bond length is 0.95 Å. In the eighth C site, C(48) is bonded in a distorted single-bond geometry to one C(47), one C(49), and one H(30) atom. The C(48)-C(49) bond length is 1.36 Å. The C(48)-H(30) bond length is 0.95 Å. In the ninth C site, C(49) is bonded in a trigonal planar geometry to one C(48), one C(50), and one C(52) atom. The C(49)-C(50) bond length is 1.38 Å. The C(49)-C(52) bond length is 1.47 Å. In the tenth C site, C(50) is bonded in a distorted single-bond geometry to one C(49) and one H(31) atom. The C(50)-H(31) bond length is 0.95 Å. In the eleventh C site, C(51) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(32) atom. The C(51)-N(4) bond length is 1.31 Å. The C(51)-H(32) bond length is 0.95 Å. In the twelfth C site, C(52) is bonded in a linear geometry to one C(46) and one C(49) atom. N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(47), and one C(51) atom. There are six inequivalent H sites. In the first H site, H(26) is bonded in a single-bond geometry to one C(42) atom. In the second H site, H(27) is bonded in a single-bond geometry to one C(44) atom. In the third H site, H(29) is bonded in a single-bond geometry to one C(47) atom. In the fourth H site, H(30) is bonded in a single-bond geometry to one C(48) atom. In the fifth H site, H(31) is bonded in a single-bond geometry to one C(50) atom. In the sixth H site, H(32) is bonded in a single-bond geometry to one C(51) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(105) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(105) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(107) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(107) atom. In each CuC22N3H14 cluster, Cu(2) is bonded in a T-shaped geometry to one N(1), one N(3), and one N(6) atom. The Cu(2)-N(1) bond length is 2.30 Å. The Cu(2)-N(3) bond length is 2.04 Å. The Cu(2)-N(6) bond length is 2.03 Å. There are twenty-two inequivalent C sites. In the first C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(8)-N(1) bond length is 1.33 Å. The C(8)-H(5) bond length is 0.95 Å. In the second C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(12)-N(1) bond length is 1.35 Å. The C(12)-H(8) bond length is 0.95 Å. In the third C site, C(29) is bonded in a distorted single-bond geometry to one C(30) and one H(18) atom. The C(29)-C(30) bond length is 1.37 Å. The C(29)-H(18) bond length is 0.95 Å. In the fourth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(33) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-C(33) bond length is 1.43 Å. In the fifth C site, C(31) is bonded in a single-bond geometry to one C(30) and one H(19) atom. The C(31)-H(19) bond length is 0.95 Å. In the sixth C site, C(33) is bonded in a linear geometry to one C(30) and one C(39) atom. The C(33)-C(39) bond length is 1.20 Å. In the seventh C site, C(34) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(21) atom. The C(34)-N(3) bond length is 1.32 Å. The C(34)-H(21) bond length is 0.95 Å. In the eighth C site, C(35) is bonded in a distorted single-bond geometry to one C(36) and one H(22) atom. The C(35)-C(36) bond length is 1.38 Å. The C(35)-H(22) bond length is 0.95 Å. In the ninth C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(39) atom. The C(36)-C(37) bond length is 1.37 Å. The C(36)-C(39) bond length is 1.47 Å. In the tenth C site, C(37) is bonded in a distorted single-bond geometry to one C(36), one C(38), and one H(23) atom. The C(37)-C(38) bond length is 1.42 Å. The C(37)-H(23) bond length is 0.95 Å. In the eleventh C site, C(38) is bonded in a distorted trigonal planar geometry to one C(37), one N(3), and one H(24) atom. The C(38)-N(3) bond length is 1.34 Å. The C(38)-H(24) bond length is 0.95 Å. In the twelfth C site, C(39) is bonded in a linear geometry to one C(33) and one C(36) atom. In the thirteenth C site, C(68) is bonded in a distorted single-bond geometry to one C(69) and one H(42) atom. The C(68)-C(69) bond length is 1.37 Å. The C(68)-H(42) bond length is 0.95 Å. In the fourteenth C site, C(69) is bonded in a trigonal planar geometry to one C(68), one C(70), and one C(72) atom. The C(69)-C(70) bond length is 1.36 Å. The C(69)-C(72) bond length is 1.44 Å. In the fifteenth C site, C(70) is bonded in a single-bond geometry to one C(69) and one H(43) atom. The C(70)-H(43) bond length is 0.95 Å. In the sixteenth C site, C(72) is bonded in a linear geometry to one C(69) and one C(78) atom. The C(72)-C(78) bond length is 1.20 Å. In the seventeenth C site, C(73) is bonded in a distorted trigonal planar geometry to one C(74), one N(6), and one H(45) atom. The C(73)-C(74) bond length is 1.43 Å. The C(73)-N(6) bond length is 1.34 Å. The C(73)-H(45) bond length is 0.95 Å. In the eighteenth C site, C(74) is bonded in a distorted single-bond geometry to one C(73), one C(75), and one H(46) atom. The C(74)-C(75) bond length is 1.38 Å. The C(74)-H(46) bond length is 0.95 Å. In the nineteenth C site, C(75) is bonded in a trigonal planar geometry to one C(74), one C(76), and one C(78) atom. The C(75)-C(76) bond length is 1.37 Å. The C(75)-C(78) bond length is 1.46 Å. In the twentieth C site, C(76) is bonded in a distorted single-bond geometry to one C(75), one C(77), and one H(47) atom. The C(76)-C(77) bond length is 1.42 Å. The C(76)-H(47) bond length is 0.95 Å. In the twenty-first C site, C(77) is bonded in a distorted trigonal planar geometry to one C(76), one N(6), and one H(48) atom. The C(77)-N(6) bond length is 1.32 Å. The C(77)-H(48) bond length is 0.95 Å. In the twenty-second C site, C(78) is bonded in a linear geometry to one C(72) and one C(75) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(2), one C(12), and one C(8) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cu(2), one C(34), and one C(38) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Cu(2), one C(73), and one C(77) atom. There are fourteen inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(18) is bonded in a single-bond geometry to one C(29) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(31) atom. In the fifth H site, H(21) is bonded in a single-bond geometry to one C(34) atom. In the sixth H site, H(22) is bonded in a single-bond geometry to one C(35) atom. In the seventh H site, H(23) is bonded in a single-bond geometry to one C(37) atom. In the eighth H site, H(24) is bonded in a single-bond geometry to one C(38) atom. In the ninth H site, H(42) is bonded in a single-bond geometry to one C(68) atom. In the tenth H site, H(43) is bonded in a single-bond geometry to one C(70) atom. In the eleventh H site, H(45) is bonded in a single-bond geometry to one C(73) atom. In the twelfth H site, H(46) is bonded in a single-bond geometry to one C(74) atom. In the thirteenth H site, H(47) is bonded in a single-bond geometry to one C(76) atom. In the fourteenth H site, H(48) is bonded in a single-bond geometry to one C(77) atom. In each CuH8(C6N)2 cluster, Cu(4) is bonded in a linear geometry to one N(2) and one N(5) atom. The Cu(4)-N(2) bond length is 2.01 Å. The Cu(4)-N(5) bond length is 2.05 Å. There are twelve inequivalent C sites. In the first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(13) atom. The C(21)-N(2) bond length is 1.33 Å. The C(21)-H(13) bond length is 0.95 Å. In the second C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(16) atom. The C(25)-N(2) bond length is 1.31 Å. The C(25)-H(16) bond length is 0.95 Å. In the third C site, C(55) is bonded in a distorted single-bond geometry to one C(56) and one H(34) atom. The C(55)-C(56) bond length is 1.38 Å. The C(55)-H(34) bond length is 0.95 Å. In the fourth C site, C(56) is bonded in a trigonal planar geometry to one C(55), one C(57), and one C(59) atom. The C(56)-C(57) bond length is 1.36 Å. The C(56)-C(59) bond length is 1.44 Å. In the fifth C site, C(57) is bonded in a distorted single-bond geometry to one C(56) and one H(35) atom. The C(57)-H(35) bond length is 0.95 Å. In the sixth C site, C(59) is bonded in a linear geometry to one C(56) and one C(65) atom. The C(59)-C(65) bond length is 1.19 Å. In the seventh C site, C(60) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(37) atom. The C(60)-N(5) bond length is 1.31 Å. The C(60)-H(37) bond length is 0.95 Å. In the eighth C site, C(61) is bonded in a distorted single-bond geometry to one C(62) and one H(38) atom. The C(61)-C(62) bond length is 1.37 Å. The C(61)-H(38) bond length is 0.95 Å. In the ninth C site, C(62) is bonded in a trigonal planar geometry to one C(61), one C(63), and one C(65) atom. The C(62)-C(63) bond length is 1.37 Å. The C(62)-C(65) bond length is 1.47 Å. In the tenth C site, C(63) is bonded in a distorted single-bond geometry to one C(62), one C(64), and one H(39) atom. The C(63)-C(64) bond length is 1.42 Å. The C(63)-H(39) bond length is 0.95 Å. In the eleventh C site, C(64) is bonded in a distorted trigonal planar geometry to one C(63), one N(5), and one H(40) atom. The C(64)-N(5) bond length is 1.31 Å. The C(64)-H(40) bond length is 0.95 Å. In the twelfth C site, C(65) is bonded in a linear geometry to one C(59) and one C(62) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cu(4), one C(21), and one C(25) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Cu(4), one C(60), and one C(64) atom. There are eight inequivalent H sites. In the first H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the second H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the third H site, H(34) is bonded in a single-bond geometry to one C(55) atom. In the fourth H site, H(35) is bonded in a single-bond geometry to one C(57) atom. In the fifth H site, H(37) is bonded in a single-bond geometry to one C(60) atom. In the sixth H site, H(38) is bonded in a single-bond geometry to one C(61) atom. In the seventh H site, H(39) is bonded in a single-bond geometry to one C(63) atom. In the eighth H site, H(40) is bonded in a single-bond geometry to one C(64) atom. Linkers: 1 [CH]C(=[CH])[Si@]([C]=[CH])(c1ccc(C#C/[C]=C/C=[N])cc1)c1ccc(C#CC2=C[CH]N([Cu]3N4[CH]C=C(C#Cc5ccc(cc5)[Si](c5ccc(C#Cc6ccncc6)cc5)(c5ccc(C#Cc6ccncc6)cc5)c5ccc(cc5)C#CC5=C[CH]N(C=C5)[Cu](N5[CH]C=C(C#Cc6ccc([Si](c7ccc(C#Cc8ccncc8)cc7)(c7ccc(C#Cc8ccncc8)cc7)c7ccc(C#Cc8ccncc8)cc7)cc6)C=C5)N5[CH]C=C(C#Cc6ccc(cc6)[Si](c6ccc(C#Cc7ccncc7)cc6)(c6ccc(C#Cc7ccncc7)cc6)c6ccc(cc6)C#CC6=C[CH]N3C=C6)C=C5)C=C4)C=C2)cc1 ,1 [CH]=[C][Si@@](c1ccc(C#C/[C]=C/C=[N])cc1)(c1ccc(C#CC2=C[CH]N([Cu](N3[CH]C=C(C#CC(=[CH])C=[CH])C=C3)N3[CH]C=C(C#Cc4ccc([Si](c5ccc(C#Cc6ccncc6)cc5)(c5ccc(C#Cc6ccncc6)cc5)c5ccc(C#Cc6ccncc6)cc5)cc4)C=C3)C=C2)cc1)c1ccc(C#Cc2ccncc2)cc1 ,2 [CH]=CC(=[CH])C#CC1=C[CH]N([Cu](N2[CH]C=[C]C=C2)N2[CH]C=C(C#Cc3ccc([Si](c4ccc(C#Cc5ccncc5)cc4)(c4ccc(C#Cc5ccncc5)cc4)c4ccc(C#Cc5ccncc5)cc4)cc3)C=C2)C=C1 ,1 [CH]C(=[CH])[Si@](c1ccc(C#CC2=C[CH]N([Cu]3N4[CH]C=C(C#Cc5ccc(cc5)[Si](c5ccc(C#Cc6ccncc6)cc5)(c5ccc(C#Cc6ccncc6)cc5)c5ccc(cc5)C#CC5=C[CH]N(C=C5)[Cu](N5[CH]C=C(C#Cc6ccc([Si@]([C]=[CH])(c7ccc(C#C/[C]=C/C=[N])cc7)c7ccc(C#Cc8ccncc8)cc7)cc6)C=C5)N5[CH]C=C(C#Cc6ccc(cc6)[Si](c6ccc(C#Cc7ccncc7)cc6)(c6ccc(C#Cc7ccncc7)cc6)c6ccc(cc6)C#CC6=C[CH]N3C=C6)C=C5)C=C4)C=C2)cc1)(c1ccc(C#Cc2c[c]ncc2)cc1)c1ccc(C#Cc2ccncc2)cc1 ,1 [CH]C(=[CH])[Si@@]([C]=[CH])(c1ccc(C#C/[C]=C/C=[N])cc1)c1ccc(C#CC2=C[CH]N([Cu]3N4[CH]C=C(C#Cc5ccc(cc5)[Si](c5ccc(C#Cc6ccncc6)cc5)(c5ccc(C#Cc6ccncc6)cc5)c5ccc(cc5)C#CC5=C[CH]N(C=C5)[Cu](N5[CH]C=C(C#Cc6ccc([Si](c7ccc(C#Cc8ccncc8)cc7)(c7ccc(C#Cc8ccncc8)cc7)c7ccc(C#Cc8ccncc8)cc7)cc6)C=C5)N5[CH]C=C(C#Cc6ccc(cc6)[Si](c6ccc(C#Cc7ccncc7)cc6)(c6ccc(C#Cc7ccncc7)cc6)c6ccc(cc6)C#CC6=C[CH]N3C=C6)C=C5)C=C4)C=C2)cc1 ,2 [C]#Cc1ccc([Si](c2ccc(C#CC3=C[CH]N([Cu](N4[CH]C=[C]C=C4)N4[CH]C=C(C#Cc5ccc([Si](c6ccc(C#Cc7ccncc7)cc6)(c6ccc(C#Cc7ccncc7)cc6)c6ccc(C#Cc7ccncc7)cc6)cc5)C=C4)C=C3)cc2)(c2ccc(C#Cc3ccncc3)cc2)c2ccc(C#Cc3ccncc3)cc2)cc1 ,1 [CH]C(=[CH])[Si@@](c1ccc(C#CC2=C[CH]N([Cu]3N4[CH]C=C(C#Cc5ccc(cc5)[Si](c5ccc(C#Cc6ccncc6)cc5)(c5ccc(C#Cc6ccncc6)cc5)c5ccc(cc5)C#CC5=C[CH]N(C=C5)[Cu](N5[CH]C=C(C#Cc6ccc([Si@@]([C]=[CH])(c7ccc(C#C/[C]=C/C=[N])cc7)c7ccc(C#Cc8ccncc8)cc7)cc6)C=C5)N5[CH]C=C(C#Cc6ccc(cc6)[Si](c6ccc(C#Cc7ccncc7)cc6)(c6ccc(C#Cc7ccncc7)cc6)c6ccc(cc6)C#CC6=C[CH]N3C=C6)C=C5)C=C4)C=C2)cc1)(c1ccc(C#Cc2c[c]ncc2)cc1)c1ccc(C#Cc2ccncc2)cc1 ,1 [CH]=[C][Si@](c1ccc(C#C/[C]=C/C=[N])cc1)(c1ccc(C#CC2=C[CH]N([Cu](N3[CH]C=C(C#CC(=[CH])C=[CH])C=C3)N3[CH]C=C(C#Cc4ccc([Si](c5ccc(C#Cc6ccncc6)cc5)(c5ccc(C#Cc6ccncc6)cc5)c5ccc(C#Cc6ccncc6)cc5)cc4)C=C3)C=C2)cc1)c1ccc(C#Cc2ccncc2)cc1. Metal clusters: 6 [Cu]. The MOF has largest included sphere 6.76 A, density 0.90 g/cm3, surface area 5351.23 m2/g, accessible volume 0.66 cm3/g