Co(HCOO)2 crystallizes in the triclinic P-1 space group. There are twenty inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(38), one O(51), one O(55), one O(58), one O(67), and one O(69) atom to form a mixture of edge and corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 65-67°. The Co(1)-O(38) bond length is 2.07 Å. The Co(1)-O(51) bond length is 2.08 Å. The Co(1)-O(55) bond length is 2.13 Å. The Co(1)-O(58) bond length is 2.11 Å. The Co(1)-O(67) bond length is 2.13 Å. The Co(1)-O(69) bond length is 2.08 Å. In the second Co site, Co(2) is bonded to one O(18), one O(39), one O(48), one O(56), one O(61), and one O(63) atom to form a mixture of edge and corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 66°. The Co(2)-O(18) bond length is 2.13 Å. The Co(2)-O(39) bond length is 2.14 Å. The Co(2)-O(48) bond length is 2.08 Å. The Co(2)-O(56) bond length is 2.15 Å. The Co(2)-O(61) bond length is 2.09 Å. The Co(2)-O(63) bond length is 2.08 Å. In the third Co site, Co(3) is bonded to one O(35), one O(45), one O(52), one O(54), one O(59), and one O(66) atom to form a mixture of edge and corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 64-65°. The Co(3)-O(35) bond length is 2.12 Å. The Co(3)-O(45) bond length is 2.06 Å. The Co(3)-O(52) bond length is 2.13 Å. The Co(3)-O(54) bond length is 2.10 Å. The Co(3)-O(59) bond length is 2.05 Å. The Co(3)-O(66) bond length is 2.13 Å. In the fourth Co site, Co(4) is bonded to one O(23), one O(44), one O(48), one O(52), one O(56), and one O(66) atom to form edge-sharing CoO6 octahedra. The Co(4)-O(23) bond length is 2.05 Å. The Co(4)-O(44) bond length is 2.04 Å. The Co(4)-O(48) bond length is 2.14 Å. The Co(4)-O(52) bond length is 2.11 Å. The Co(4)-O(56) bond length is 2.14 Å. The Co(4)-O(66) bond length is 2.13 Å. In the fifth Co site, Co(5) is bonded to one O(18), one O(38), one O(39), one O(40), one O(46), and one O(58) atom to form edge-sharing CoO6 octahedra. The Co(5)-O(18) bond length is 2.12 Å. The Co(5)-O(38) bond length is 2.10 Å. The Co(5)-O(39) bond length is 2.09 Å. The Co(5)-O(40) bond length is 2.05 Å. The Co(5)-O(46) bond length is 2.04 Å. The Co(5)-O(58) bond length is 2.12 Å. In the sixth Co site, Co(6) is bonded to one O(22), one O(27), one O(47), one O(53), one O(62), and one O(68) atom to form a mixture of edge and corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 65°. The Co(6)-O(22) bond length is 2.15 Å. The Co(6)-O(27) bond length is 2.12 Å. The Co(6)-O(47) bond length is 2.04 Å. The Co(6)-O(53) bond length is 2.09 Å. The Co(6)-O(62) bond length is 2.12 Å. The Co(6)-O(68) bond length is 2.06 Å. In the seventh Co site, Co(7) is bonded to one O(25), one O(28), one O(30), one O(37), one O(42), and one O(50) atom to form edge-sharing CoO6 octahedra. The Co(7)-O(25) bond length is 2.04 Å. The Co(7)-O(28) bond length is 2.06 Å. The Co(7)-O(30) bond length is 2.09 Å. The Co(7)-O(37) bond length is 2.09 Å. The Co(7)-O(42) bond length is 2.13 Å. The Co(7)-O(50) bond length is 2.12 Å. In the eighth Co site, Co(8) is bonded to one O(37), one O(49), one O(50), one O(64), one O(70), and one O(72) atom to form a mixture of edge and corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 65°. The Co(8)-O(37) bond length is 2.06 Å. The Co(8)-O(49) bond length is 2.06 Å. The Co(8)-O(50) bond length is 2.15 Å. The Co(8)-O(64) bond length is 2.08 Å. The Co(8)-O(70) bond length is 2.12 Å. The Co(8)-O(72) bond length is 2.11 Å. In the ninth Co site, Co(9) is bonded to one O(20), one O(31), one O(55), one O(60), one O(67), and one O(71) atom to form edge-sharing CoO6 octahedra. The Co(9)-O(20) bond length is 2.04 Å. The Co(9)-O(31) bond length is 2.06 Å. The Co(9)-O(55) bond length is 2.10 Å. The Co(9)-O(60) bond length is 2.10 Å. The Co(9)-O(67) bond length is 2.13 Å. The Co(9)-O(71) bond length is 2.10 Å. In the tenth Co site, Co(10) is bonded to one O(33), one O(41), one O(53), one O(62), one O(70), and one O(72) atom to form edge-sharing CoO6 octahedra. The Co(10)-O(33) bond length is 2.04 Å. The Co(10)-O(41) bond length is 2.06 Å. The Co(10)-O(53) bond length is 2.11 Å. The Co(10)-O(62) bond length is 2.09 Å. The Co(10)-O(70) bond length is 2.14 Å. The Co(10)-O(72) bond length is 2.11 Å. In the eleventh Co site, Co(11) is bonded to one O(22), one O(27), one O(32), one O(35), one O(43), and one O(54) atom to form edge-sharing CoO6 octahedra. The Co(11)-O(22) bond length is 2.11 Å. The Co(11)-O(27) bond length is 2.10 Å. The Co(11)-O(32) bond length is 2.07 Å. The Co(11)-O(35) bond length is 2.11 Å. The Co(11)-O(43) bond length is 2.07 Å. The Co(11)-O(54) bond length is 2.11 Å. In the twelfth Co site, Co(12) is bonded to one O(30), one O(42), one O(57), one O(60), one O(65), and one O(71) atom to form a mixture of edge and corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 64-66°. The Co(12)-O(30) bond length is 2.14 Å. The Co(12)-O(42) bond length is 2.12 Å. The Co(12)-O(57) bond length is 2.10 Å. The Co(12)-O(60) bond length is 2.08 Å. The Co(12)-O(65) bond length is 2.05 Å. The Co(12)-O(71) bond length is 2.13 Å. In the thirteenth Co site, Co(13) is bonded to one O(34), one O(36), one O(4), one O(57), one O(61), and one O(7) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 66°. The Co(13)-O(34) bond length is 2.07 Å. The Co(13)-O(36) bond length is 2.07 Å. The Co(13)-O(4) bond length is 2.07 Å. The Co(13)-O(57) bond length is 2.11 Å. The Co(13)-O(61) bond length is 2.13 Å. The Co(13)-O(7) bond length is 2.07 Å. In the fourteenth Co site, Co(14) is bonded to one O(11), one O(16), one O(2), one O(3), one O(59), and one O(69) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 64-65°. The Co(14)-O(11) bond length is 2.09 Å. The Co(14)-O(16) bond length is 2.05 Å. The Co(14)-O(2) bond length is 2.07 Å. The Co(14)-O(3) bond length is 2.10 Å. The Co(14)-O(59) bond length is 2.15 Å. The Co(14)-O(69) bond length is 2.12 Å. In the fifteenth Co site, Co(15) is bonded to one O(12), one O(15), one O(24), one O(26), one O(49), and one O(51) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 65-67°. The Co(15)-O(12) bond length is 2.08 Å. The Co(15)-O(15) bond length is 2.07 Å. The Co(15)-O(24) bond length is 2.08 Å. The Co(15)-O(26) bond length is 2.09 Å. The Co(15)-O(49) bond length is 2.15 Å. The Co(15)-O(51) bond length is 2.15 Å. In the sixteenth Co site, Co(16) is bonded to one O(14), one O(19), one O(47), one O(6), one O(65), and one O(8) atom to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles range from 64-65°. The Co(16)-O(14) bond length is 2.09 Å. The Co(16)-O(19) bond length is 2.05 Å. The Co(16)-O(47) bond length is 2.17 Å. The Co(16)-O(6) bond length is 2.06 Å. The Co(16)-O(65) bond length is 2.12 Å. The Co(16)-O(8) bond length is 2.11 Å. In the seventeenth Co site, Co(17) is bonded to two equivalent O(21), two equivalent O(5), and two equivalent O(68) atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 65°. Both Co(17)-O(21) bond lengths are 2.07 Å. Both Co(17)-O(5) bond lengths are 2.07 Å. Both Co(17)-O(68) bond lengths are 2.14 Å. In the eighteenth Co site, Co(18) is bonded to two equivalent O(10), two equivalent O(64), and two equivalent O(9) atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 65°. Both Co(18)-O(10) bond lengths are 2.06 Å. Both Co(18)-O(64) bond lengths are 2.13 Å. Both Co(18)-O(9) bond lengths are 2.05 Å. In the nineteenth Co site, Co(19) is bonded to two equivalent O(13), two equivalent O(29), and two equivalent O(45) atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 65°. Both Co(19)-O(13) bond lengths are 2.10 Å. Both Co(19)-O(29) bond lengths are 2.05 Å. Both Co(19)-O(45) bond lengths are 2.14 Å. In the twentieth Co site, Co(20) is bonded to two equivalent O(1), two equivalent O(17), and two equivalent O(63) atoms to form corner-sharing CoO6 octahedra. The corner-sharing octahedral tilt angles are 66°. Both Co(20)-O(1) bond lengths are 2.08 Å. Both Co(20)-O(17) bond lengths are 2.07 Å. Both Co(20)-O(63) bond lengths are 2.16 Å. There are thirty-six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one H(1), one O(12), and one O(58) atom. The C(1)-H(1) bond length is 0.93 Å. The C(1)-O(12) bond length is 1.23 Å. The C(1)-O(58) bond length is 1.29 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one H(2), one O(31), and one O(51) atom. The C(2)-H(2) bond length is 0.93 Å. The C(2)-O(31) bond length is 1.26 Å. The C(2)-O(51) bond length is 1.27 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one H(3), one O(41), and one O(49) atom. The C(3)-H(3) bond length is 0.93 Å. The C(3)-O(41) bond length is 1.22 Å. The C(3)-O(49) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one H(4), one O(60), and one O(8) atom. The C(4)-H(4) bond length is 0.93 Å. The C(4)-O(60) bond length is 1.22 Å. The C(4)-O(8) bond length is 1.25 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one H(5), one O(29), and one O(59) atom. The C(5)-H(5) bond length is 0.93 Å. The C(5)-O(29) bond length is 1.26 Å. The C(5)-O(59) bond length is 1.28 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one H(6), one O(3), and one O(38) atom. The C(6)-H(6) bond length is 0.93 Å. The C(6)-O(3) bond length is 1.26 Å. The C(6)-O(38) bond length is 1.27 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one H(7), one O(4), and one O(71) atom. The C(7)-H(7) bond length is 0.93 Å. The C(7)-O(4) bond length is 1.24 Å. The C(7)-O(71) bond length is 1.26 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one H(8), one O(6), and one O(62) atom. The C(8)-H(8) bond length is 0.93 Å. The C(8)-O(6) bond length is 1.18 Å. The C(8)-O(62) bond length is 1.29 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one H(9), one O(70), and one O(9) atom. The C(9)-H(9) bond length is 0.93 Å. The C(9)-O(70) bond length is 1.18 Å. The C(9)-O(9) bond length is 1.26 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one H(10), one O(26), and one O(69) atom. The C(10)-H(10) bond length is 0.93 Å. The C(10)-O(26) bond length is 1.17 Å. The C(10)-O(69) bond length is 1.30 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one H(11), one O(15), and one O(50) atom. The C(11)-H(11) bond length is 0.93 Å. The C(11)-O(15) bond length is 1.26 Å. The C(11)-O(50) bond length is 1.24 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one H(12), one O(24), and one O(64) atom. The C(12)-H(12) bond length is 0.93 Å. The C(12)-O(24) bond length is 1.25 Å. The C(12)-O(64) bond length is 1.29 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one H(13), one O(56), and one O(7) atom. The C(13)-H(13) bond length is 0.93 Å. The C(13)-O(56) bond length is 1.26 Å. The C(13)-O(7) bond length is 1.23 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one H(14), one O(36), and one O(65) atom. The C(14)-H(14) bond length is 0.93 Å. The C(14)-O(36) bond length is 1.25 Å. The C(14)-O(65) bond length is 1.25 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one H(15), one O(20), and one O(30) atom. The C(15)-H(15) bond length is 0.93 Å. The C(15)-O(20) bond length is 1.29 Å. The C(15)-O(30) bond length is 1.24 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one H(16), one O(11), and one O(66) atom. The C(16)-H(16) bond length is 0.93 Å. The C(16)-O(11) bond length is 1.24 Å. The C(16)-O(66) bond length is 1.28 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one H(17), one O(14), and one O(22) atom. The C(17)-H(17) bond length is 0.93 Å. The C(17)-O(14) bond length is 1.19 Å. The C(17)-O(22) bond length is 1.29 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one H(18), one O(2), and one O(35) atom. The C(18)-H(18) bond length is 0.93 Å. The C(18)-O(2) bond length is 1.18 Å. The C(18)-O(35) bond length is 1.30 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one H(19), one O(25), and one O(72) atom. The C(19)-H(19) bond length is 0.93 Å. The C(19)-O(25) bond length is 1.28 Å. The C(19)-O(72) bond length is 1.31 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one H(20), one O(21), and one O(47) atom. The C(20)-H(20) bond length is 0.93 Å. The C(20)-O(21) bond length is 1.25 Å. The C(20)-O(47) bond length is 1.30 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one H(21), one O(46), and one O(67) atom. The C(21)-H(21) bond length is 0.93 Å. The C(21)-O(46) bond length is 1.22 Å. The C(21)-O(67) bond length is 1.25 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one H(22), one O(34), and one O(63) atom. The C(22)-H(22) bond length is 0.93 Å. The C(22)-O(34) bond length is 1.23 Å. The C(22)-O(63) bond length is 1.29 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one H(23), one O(17), and one O(39) atom. The C(23)-H(23) bond length is 0.93 Å. The C(23)-O(17) bond length is 1.21 Å. The C(23)-O(39) bond length is 1.25 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one H(24), one O(27), and one O(33) atom. The C(24)-H(24) bond length is 0.93 Å. The C(24)-O(27) bond length is 1.27 Å. The C(24)-O(33) bond length is 1.24 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one H(25), one O(19), and one O(42) atom. The C(25)-H(25) bond length is 0.93 Å. The C(25)-O(19) bond length is 1.18 Å. The C(25)-O(42) bond length is 1.31 Å. In the twenty-sixth C site, C(26) is bonded in a trigonal planar geometry to one H(26), one O(32), and one O(52) atom. The C(26)-H(26) bond length is 0.93 Å. The C(26)-O(32) bond length is 1.25 Å. The C(26)-O(52) bond length is 1.26 Å. In the twenty-seventh C site, C(27) is bonded in a trigonal planar geometry to one H(27), one O(10), and one O(37) atom. The C(27)-H(27) bond length is 0.93 Å. The C(27)-O(10) bond length is 1.28 Å. The C(27)-O(37) bond length is 1.26 Å. In the twenty-eighth C site, C(28) is bonded in a trigonal planar geometry to one H(28), one O(16), and one O(55) atom. The C(28)-H(28) bond length is 0.93 Å. The C(28)-O(16) bond length is 1.20 Å. The C(28)-O(55) bond length is 1.30 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one H(29), one O(18), and one O(23) atom. The C(29)-H(29) bond length is 0.93 Å. The C(29)-O(18) bond length is 1.28 Å. The C(29)-O(23) bond length is 1.29 Å. In the thirtieth C site, C(30) is bonded in a trigonal planar geometry to one H(30), one O(5), and one O(53) atom. The C(30)-H(30) bond length is 0.93 Å. The C(30)-O(5) bond length is 1.23 Å. The C(30)-O(53) bond length is 1.32 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one H(31), one O(43), and one O(68) atom. The C(31)-H(31) bond length is 0.93 Å. The C(31)-O(43) bond length is 1.24 Å. The C(31)-O(68) bond length is 1.29 Å. In the thirty-second C site, C(32) is bonded in a trigonal planar geometry to one H(32), one O(28), and one O(57) atom. The C(32)-H(32) bond length is 0.93 Å. The C(32)-O(28) bond length is 1.23 Å. The C(32)-O(57) bond length is 1.29 Å. In the thirty-third C site, C(33) is bonded in a trigonal planar geometry to one H(33), one O(40), and one O(61) atom. The C(33)-H(33) bond length is 0.93 Å. The C(33)-O(40) bond length is 1.21 Å. The C(33)-O(61) bond length is 1.28 Å. In the thirty-fourth C site, C(34) is bonded in a trigonal planar geometry to one H(34), one O(44), and one O(45) atom. The C(34)-H(34) bond length is 0.93 Å. The C(34)-O(44) bond length is 1.26 Å. The C(34)-O(45) bond length is 1.28 Å. In the thirty-fifth C site, C(35) is bonded in a trigonal planar geometry to one H(35), one O(1), and one O(48) atom. The C(35)-H(35) bond length is 0.93 Å. The C(35)-O(1) bond length is 1.25 Å. The C(35)-O(48) bond length is 1.27 Å. In the thirty-sixth C site, C(36) is bonded in a trigonal planar geometry to one H(36), one O(13), and one O(54) atom. The C(36)-H(36) bond length is 0.93 Å. The C(36)-O(13) bond length is 1.20 Å. The C(36)-O(54) bond length is 1.31 Å. There are thirty-six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(21) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(22) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(23) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(24) atom. In the twenty-fifth H site, H(25) is bonded in a single-bond geometry to one C(25) atom. In the twenty-sixth H site, H(26) is bonded in a single-bond geometry to one C(26) atom. In the twenty-seventh H site, H(27) is bonded in a single-bond geometry to one C(27) atom. In the twenty-eighth H site, H(28) is bonded in a single-bond geometry to one C(28) atom. In the twenty-ninth H site, H(29) is bonded in a single-bond geometry to one C(29) atom. In the thirtieth H site, H(30) is bonded in a single-bond geometry to one C(30) atom. In the thirty-first H site, H(31) is bonded in a single-bond geometry to one C(31) atom. In the thirty-second H site, H(32) is bonded in a single-bond geometry to one C(32) atom. In the thirty-third H site, H(33) is bonded in a single-bond geometry to one C(33) atom. In the thirty-fourth H site, H(34) is bonded in a single-bond geometry to one C(34) atom. In the thirty-fifth H site, H(35) is bonded in a single-bond geometry to one C(35) atom. In the thirty-sixth H site, H(36) is bonded in a single-bond geometry to one C(36) atom. There are seventy-two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Co(20) and one C(35) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Co(14) and one C(18) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Co(14) and one C(6) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Co(13) and one C(7) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Co(17) and one C(30) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Co(16) and one C(8) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Co(13) and one C(13) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Co(16) and one C(4) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Co(18) and one C(9) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Co(18) and one C(27) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Co(14) and one C(16) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Co(15) and one C(1) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Co(19) and one C(36) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Co(16) and one C(17) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one Co(15) and one C(11) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Co(14) and one C(28) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Co(20) and one C(23) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(5), and one C(29) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 150 degrees geometry to one Co(16) and one C(25) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Co(9) and one C(15) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Co(17) and one C(20) atom. In the twenty-second O site, O(22) is bonded in a distorted trigonal planar geometry to one Co(11), one Co(6), and one C(17) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Co(4) and one C(29) atom. In the twenty-fourth O site, O(24) is bonded in a bent 150 degrees geometry to one Co(15) and one C(12) atom. In the twenty-fifth O site, O(25) is bonded in a bent 120 degrees geometry to one Co(7) and one C(19) atom. In the twenty-sixth O site, O(26) is bonded in a distorted bent 150 degrees geometry to one Co(15) and one C(10) atom. In the twenty-seventh O site, O(27) is bonded in a distorted trigonal planar geometry to one Co(11), one Co(6), and one C(24) atom. In the twenty-eighth O site, O(28) is bonded in a distorted bent 120 degrees geometry to one Co(7) and one C(32) atom. In the twenty-ninth O site, O(29) is bonded in a bent 150 degrees geometry to one Co(19) and one C(5) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal planar geometry to one Co(12), one Co(7), and one C(15) atom. In the thirty-first O site, O(31) is bonded in a distorted bent 120 degrees geometry to one Co(9) and one C(2) atom. In the thirty-second O site, O(32) is bonded in a bent 120 degrees geometry to one Co(11) and one C(26) atom. In the thirty-third O site, O(33) is bonded in a bent 120 degrees geometry to one Co(10) and one C(24) atom. In the thirty-fourth O site, O(34) is bonded in a bent 150 degrees geometry to one Co(13) and one C(22) atom. In the thirty-fifth O site, O(35) is bonded in a distorted trigonal planar geometry to one Co(11), one Co(3), and one C(18) atom. In the thirty-sixth O site, O(36) is bonded in a bent 150 degrees geometry to one Co(13) and one C(14) atom. In the thirty-seventh O site, O(37) is bonded in a distorted trigonal planar geometry to one Co(7), one Co(8), and one C(27) atom. In the thirty-eighth O site, O(38) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(5), and one C(6) atom. In the thirty-ninth O site, O(39) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(5), and one C(23) atom. In the fortieth O site, O(40) is bonded in a distorted bent 120 degrees geometry to one Co(5) and one C(33) atom. In the forty-first O site, O(41) is bonded in a distorted bent 120 degrees geometry to one Co(10) and one C(3) atom. In the forty-second O site, O(42) is bonded in a distorted trigonal planar geometry to one Co(12), one Co(7), and one C(25) atom. In the forty-third O site, O(43) is bonded in a distorted bent 120 degrees geometry to one Co(11) and one C(31) atom. In the forty-fourth O site, O(44) is bonded in a distorted bent 120 degrees geometry to one Co(4) and one C(34) atom. In the forty-fifth O site, O(45) is bonded in a trigonal planar geometry to one Co(19), one Co(3), and one C(34) atom. In the forty-sixth O site, O(46) is bonded in a bent 120 degrees geometry to one Co(5) and one C(21) atom. In the forty-seventh O site, O(47) is bonded in a trigonal planar geometry to one Co(16), one Co(6), and one C(20) atom. In the forty-eighth O site, O(48) is bonded in a 3-coordinate geometry to one Co(2), one Co(4), and one C(35) atom. In the forty-ninth O site, O(49) is bonded in a trigonal planar geometry to one Co(15), one Co(8), and one C(3) atom. In the fiftieth O site, O(50) is bonded in a 3-coordinate geometry to one Co(7), one Co(8), and one C(11) atom. In the fifty-first O site, O(51) is bonded in a trigonal planar geometry to one Co(1), one Co(15), and one C(2) atom. In the fifty-second O site, O(52) is bonded in a distorted trigonal planar geometry to one Co(3), one Co(4), and one C(26) atom. In the fifty-third O site, O(53) is bonded in a distorted trigonal planar geometry to one Co(10), one Co(6), and one C(30) atom. In the fifty-fourth O site, O(54) is bonded in a distorted trigonal planar geometry to one Co(11), one Co(3), and one C(36) atom. In the fifty-fifth O site, O(55) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(9), and one C(28) atom. In the fifty-sixth O site, O(56) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(4), and one C(13) atom. In the fifty-seventh O site, O(57) is bonded in a trigonal planar geometry to one Co(12), one Co(13), and one C(32) atom. In the fifty-eighth O site, O(58) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(5), and one C(1) atom. In the fifty-ninth O site, O(59) is bonded in a trigonal planar geometry to one Co(14), one Co(3), and one C(5) atom. In the sixtieth O site, O(60) is bonded in a distorted trigonal planar geometry to one Co(12), one Co(9), and one C(4) atom. In the sixty-first O site, O(61) is bonded in a trigonal planar geometry to one Co(13), one Co(2), and one C(33) atom. In the sixty-second O site, O(62) is bonded in a distorted trigonal planar geometry to one Co(10), one Co(6), and one C(8) atom. In the sixty-third O site, O(63) is bonded in a trigonal planar geometry to one Co(2), one Co(20), and one C(22) atom. In the sixty-fourth O site, O(64) is bonded in a trigonal planar geometry to one Co(18), one Co(8), and one C(12) atom. In the sixty-fifth O site, O(65) is bonded in a trigonal planar geometry to one Co(12), one Co(16), and one C(14) atom. In the sixty-sixth O site, O(66) is bonded in a distorted trigonal planar geometry to one Co(3), one Co(4), and one C(16) atom. In the sixty-seventh O site, O(67) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(9), and one C(21) atom. In the sixty-eighth O site, O(68) is bonded in a trigonal planar geometry to one Co(17), one Co(6), and one C(31) atom. In the sixty-ninth O site, O(69) is bonded in a trigonal planar geometry to one Co(1), one Co(14), and one C(10) atom. In the seventieth O site, O(70) is bonded in a 3-coordinate geometry to one Co(10), one Co(8), and one C(9) atom. In the seventy-first O site, O(71) is bonded in a distorted trigonal planar geometry to one Co(12), one Co(9), and one C(7) atom. In the seventy-second O site, O(72) is bonded in a distorted trigonal planar geometry to one Co(10), one Co(8), and one C(19) atom. Linkers: 72 [O]C=O. Metal clusters: 36 [Co]. The MOF has largest included sphere 5.10 A, density 1.74 g/cm3, surface area 2613.69 m2/g, accessible volume 0.25 cm3/g