EuAg3C65N21H54(CH)21 crystallizes in the monoclinic P2_1/c space group. The structure consists of eighty-four 02329_fluka molecules inside a EuAg3C65N21H54 framework. In the EuAg3C65N21H54 framework, Eu(1) is bonded in a distorted body-centered cubic geometry to one N(1), one N(11), one N(12), one N(15), one N(18), one N(2), one N(5), and one N(8) atom. The Eu(1)-N(1) bond length is 2.65 Å. The Eu(1)-N(11) bond length is 2.66 Å. The Eu(1)-N(12) bond length is 2.54 Å. The Eu(1)-N(15) bond length is 2.51 Å. The Eu(1)-N(18) bond length is 2.51 Å. The Eu(1)-N(2) bond length is 2.51 Å. The Eu(1)-N(5) bond length is 2.51 Å. The Eu(1)-N(8) bond length is 2.52 Å. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one N(20) and one N(4) atom. The Ag(1)-N(20) bond length is 2.15 Å. The Ag(1)-N(4) bond length is 2.14 Å. In the second Ag site, Ag(2) is bonded in a trigonal non-coplanar geometry to one N(10), one N(21), and one N(7) atom. The Ag(2)-N(10) bond length is 2.30 Å. The Ag(2)-N(21) bond length is 2.40 Å. The Ag(2)-N(7) bond length is 2.30 Å. In the third Ag site, Ag(3) is bonded in a linear geometry to one N(14) and one N(17) atom. The Ag(3)-N(14) bond length is 2.22 Å. The Ag(3)-N(17) bond length is 2.16 Å. There are sixty-five inequivalent C sites. In the first C site, C(1) is bonded in a 3-coordinate geometry to one C(2); one N(1); and two equivalent H(1,2) atoms. The C(1)-C(2) bond length is 1.49 Å. The C(1)-N(1) bond length is 1.47 Å. Both C(1)-H(1,2) bond lengths are 0.99 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(2), and one N(3) atom. The C(2)-N(2) bond length is 1.33 Å. The C(2)-N(3) bond length is 1.34 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(8) and one N(2) atom. The C(3)-C(8) bond length is 1.39 Å. The C(3)-N(2) bond length is 1.40 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-H(6) bond length is 0.95 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one N(3) atom. The C(8)-N(3) bond length is 1.37 Å. In the sixth C site, C(9) is bonded in a 3-coordinate geometry to one C(10); one N(3); and two equivalent H(7,8) atoms. The C(9)-C(10) bond length is 1.53 Å. The C(9)-N(3) bond length is 1.47 Å. Both C(9)-H(7,8) bond lengths are 0.99 Å. In the seventh C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(9) atom. The C(10)-C(11) bond length is 1.35 Å. The C(10)-C(14) bond length is 1.34 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(9) atom. The C(11)-H(9) bond length is 0.95 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(12)-C(13) bond length is 1.33 Å. The C(12)-H(10) bond length is 0.95 Å. In the tenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one N(4), and one H(11) atom. The C(13)-N(4) bond length is 1.33 Å. The C(13)-H(11) bond length is 0.95 Å. In the eleventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(10), one N(4), and one H(12) atom. The C(14)-N(4) bond length is 1.36 Å. The C(14)-H(12) bond length is 0.95 Å. In the twelfth C site, C(15) is bonded in a 3-coordinate geometry to one C(16); one N(1); and two equivalent H(13,14) atoms. The C(15)-C(16) bond length is 1.50 Å. The C(15)-N(1) bond length is 1.48 Å. Both C(15)-H(13,14) bond lengths are 0.99 Å. In the thirteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one N(5), and one N(6) atom. The C(16)-N(5) bond length is 1.33 Å. The C(16)-N(6) bond length is 1.36 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(22) and one N(5) atom. The C(17)-C(22) bond length is 1.39 Å. The C(17)-N(5) bond length is 1.40 Å. In the fifteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(18) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(18) bond length is 0.95 Å. In the sixteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(17), one C(21), and one N(6) atom. The C(22)-N(6) bond length is 1.39 Å. In the seventeenth C site, C(23) is bonded in a 3-coordinate geometry to one C(24), one N(6), one H(19), and one H(20) atom. The C(23)-C(24) bond length is 1.51 Å. The C(23)-N(6) bond length is 1.47 Å. The C(23)-H(19) bond length is 0.99 Å. The C(23)-H(20) bond length is 0.99 Å. In the eighteenth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(28) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-C(28) bond length is 1.37 Å. In the nineteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one C(26), and one H(21) atom. The C(25)-C(26) bond length is 1.37 Å. The C(25)-H(21) bond length is 0.95 Å. In the twentieth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(22) atom. The C(26)-H(22) bond length is 0.95 Å. In the twenty-first C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(23) atom. The C(27)-N(7) bond length is 1.32 Å. The C(27)-H(23) bond length is 0.95 Å. In the twenty-second C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(24), one N(7), and one H(24) atom. The C(28)-N(7) bond length is 1.34 Å. The C(28)-H(24) bond length is 0.95 Å. In the twenty-third C site, C(29) is bonded in a 3-coordinate geometry to one C(30), one N(1), one H(25), and one H(26) atom. The C(29)-C(30) bond length is 1.48 Å. The C(29)-N(1) bond length is 1.48 Å. The C(29)-H(25) bond length is 0.99 Å. The C(29)-H(26) bond length is 0.99 Å. In the twenty-fourth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one N(8), and one N(9) atom. The C(30)-N(8) bond length is 1.32 Å. The C(30)-N(9) bond length is 1.36 Å. In the twenty-fifth C site, C(31) is bonded in a distorted single-bond geometry to one C(36) and one N(8) atom. The C(31)-C(36) bond length is 1.40 Å. The C(31)-N(8) bond length is 1.40 Å. In the twenty-sixth C site, C(35) is bonded in a distorted single-bond geometry to one C(36) and one H(30) atom. The C(35)-C(36) bond length is 1.37 Å. The C(35)-H(30) bond length is 0.95 Å. In the twenty-seventh C site, C(36) is bonded in a distorted single-bond geometry to one C(31), one C(35), and one N(9) atom. The C(36)-N(9) bond length is 1.39 Å. In the twenty-eighth C site, C(37) is bonded in a 3-coordinate geometry to one C(38), one N(9), one H(31), and one H(32) atom. The C(37)-C(38) bond length is 1.51 Å. The C(37)-N(9) bond length is 1.47 Å. The C(37)-H(31) bond length is 0.99 Å. The C(37)-H(32) bond length is 0.99 Å. In the twenty-ninth C site, C(38) is bonded in a trigonal planar geometry to one C(37), one C(39), and one C(42) atom. The C(38)-C(39) bond length is 1.39 Å. The C(38)-C(42) bond length is 1.38 Å. In the thirtieth C site, C(39) is bonded in a distorted single-bond geometry to one C(38) and one H(33) atom. The C(39)-H(33) bond length is 0.95 Å. In the thirty-first C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(35) atom. The C(41)-N(10) bond length is 1.35 Å. The C(41)-H(35) bond length is 0.95 Å. In the thirty-second C site, C(42) is bonded in a distorted trigonal planar geometry to one C(38), one N(10), and one H(36) atom. The C(42)-N(10) bond length is 1.34 Å. The C(42)-H(36) bond length is 0.95 Å. In the thirty-third C site, C(43) is bonded in a 3-coordinate geometry to one C(44), one N(11), one H(37), and one H(38) atom. The C(43)-C(44) bond length is 1.49 Å. The C(43)-N(11) bond length is 1.47 Å. The C(43)-H(37) bond length is 0.99 Å. The C(43)-H(38) bond length is 0.99 Å. In the thirty-fourth C site, C(44) is bonded in a distorted trigonal planar geometry to one C(43), one N(12), and one N(13) atom. The C(44)-N(12) bond length is 1.32 Å. The C(44)-N(13) bond length is 1.34 Å. In the thirty-fifth C site, C(45) is bonded in a distorted single-bond geometry to one N(12) atom. The C(45)-N(12) bond length is 1.40 Å. In the thirty-sixth C site, C(50) is bonded in a distorted single-bond geometry to one N(13) atom. The C(50)-N(13) bond length is 1.40 Å. In the thirty-seventh C site, C(51) is bonded in a 3-coordinate geometry to one C(52); one N(13); and two equivalent H(43,44) atoms. The C(51)-C(52) bond length is 1.53 Å. The C(51)-N(13) bond length is 1.47 Å. Both C(51)-H(43,44) bond lengths are 0.99 Å. In the thirty-eighth C site, C(52) is bonded in a trigonal planar geometry to one C(51), one C(53), and one C(56) atom. The C(52)-C(53) bond length is 1.35 Å. The C(52)-C(56) bond length is 1.36 Å. In the thirty-ninth C site, C(53) is bonded in a distorted single-bond geometry to one C(52) and one H(45) atom. The C(53)-H(45) bond length is 0.95 Å. In the fortieth C site, C(55) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(47) atom. The C(55)-N(14) bond length is 1.29 Å. The C(55)-H(47) bond length is 0.95 Å. In the forty-first C site, C(56) is bonded in a distorted trigonal planar geometry to one C(52), one N(14), and one H(48) atom. The C(56)-N(14) bond length is 1.36 Å. The C(56)-H(48) bond length is 0.95 Å. In the forty-second C site, C(57) is bonded in a 3-coordinate geometry to one C(58); one N(11); and two equivalent H(49,50) atoms. The C(57)-C(58) bond length is 1.48 Å. The C(57)-N(11) bond length is 1.48 Å. Both C(57)-H(49,50) bond lengths are 0.99 Å. In the forty-third C site, C(58) is bonded in a distorted trigonal planar geometry to one C(57), one N(15), and one N(16) atom. The C(58)-N(15) bond length is 1.33 Å. The C(58)-N(16) bond length is 1.36 Å. In the forty-fourth C site, C(59) is bonded in a distorted single-bond geometry to one C(60), one C(64), and one N(15) atom. The C(59)-C(60) bond length is 1.40 Å. The C(59)-C(64) bond length is 1.40 Å. The C(59)-N(15) bond length is 1.41 Å. In the forty-fifth C site, C(60) is bonded in a distorted single-bond geometry to one C(59) and one H(51) atom. The C(60)-H(51) bond length is 0.95 Å. In the forty-sixth C site, C(63) is bonded in a distorted single-bond geometry to one C(64) and one H(54) atom. The C(63)-C(64) bond length is 1.38 Å. The C(63)-H(54) bond length is 0.95 Å. In the forty-seventh C site, C(64) is bonded in a distorted single-bond geometry to one C(59), one C(63), and one N(16) atom. The C(64)-N(16) bond length is 1.38 Å. In the forty-eighth C site, C(65) is bonded in a 3-coordinate geometry to one C(66), one N(16), one H(55), and one H(56) atom. The C(65)-C(66) bond length is 1.51 Å. The C(65)-N(16) bond length is 1.46 Å. The C(65)-H(55) bond length is 0.99 Å. The C(65)-H(56) bond length is 0.99 Å. In the forty-ninth C site, C(66) is bonded in a trigonal planar geometry to one C(65), one C(67), and one C(70) atom. The C(66)-C(67) bond length is 1.37 Å. The C(66)-C(70) bond length is 1.36 Å. In the fiftieth C site, C(67) is bonded in a distorted single-bond geometry to one C(66) and one H(57) atom. The C(67)-H(57) bond length is 0.95 Å. In the fifty-first C site, C(68) is bonded in a distorted single-bond geometry to one C(69) and one H(58) atom. The C(68)-C(69) bond length is 1.35 Å. The C(68)-H(58) bond length is 0.95 Å. In the fifty-second C site, C(69) is bonded in a distorted trigonal planar geometry to one C(68), one N(17), and one H(59) atom. The C(69)-N(17) bond length is 1.35 Å. The C(69)-H(59) bond length is 0.95 Å. In the fifty-third C site, C(70) is bonded in a distorted bent 120 degrees geometry to one C(66), one N(17), and one H(60) atom. The C(70)-N(17) bond length is 1.36 Å. The C(70)-H(60) bond length is 0.95 Å. In the fifty-fourth C site, C(71) is bonded in a 3-coordinate geometry to one C(72); one N(11); and two equivalent H(61,62) atoms. The C(71)-C(72) bond length is 1.48 Å. The C(71)-N(11) bond length is 1.47 Å. Both C(71)-H(61,62) bond lengths are 0.99 Å. In the fifty-fifth C site, C(72) is bonded in a distorted trigonal planar geometry to one C(71), one N(18), and one N(19) atom. The C(72)-N(18) bond length is 1.32 Å. The C(72)-N(19) bond length is 1.36 Å. In the fifty-sixth C site, C(73) is bonded in a distorted single-bond geometry to one N(18) atom. The C(73)-N(18) bond length is 1.42 Å. In the fifty-seventh C site, C(78) is bonded in a distorted single-bond geometry to one N(19) atom. The C(78)-N(19) bond length is 1.40 Å. In the fifty-eighth C site, C(79) is bonded in a 3-coordinate geometry to one C(80); one N(19); and two equivalent H(67,68) atoms. The C(79)-C(80) bond length is 1.51 Å. The C(79)-N(19) bond length is 1.46 Å. Both C(79)-H(67,68) bond lengths are 0.99 Å. In the fifty-ninth C site, C(80) is bonded in a trigonal planar geometry to one C(79), one C(81), and one C(84) atom. The C(80)-C(81) bond length is 1.37 Å. The C(80)-C(84) bond length is 1.35 Å. In the sixtieth C site, C(81) is bonded in a distorted single-bond geometry to one C(80) and one H(69) atom. The C(81)-H(69) bond length is 0.95 Å. In the sixty-first C site, C(82) is bonded in a distorted single-bond geometry to one C(83) and one H(70) atom. The C(82)-C(83) bond length is 1.36 Å. The C(82)-H(70) bond length is 0.95 Å. In the sixty-second C site, C(83) is bonded in a distorted trigonal planar geometry to one C(82), one N(20), and one H(71) atom. The C(83)-N(20) bond length is 1.34 Å. The C(83)-H(71) bond length is 0.95 Å. In the sixty-third C site, C(84) is bonded in a distorted trigonal planar geometry to one C(80), one N(20), and one H(72) atom. The C(84)-N(20) bond length is 1.33 Å. The C(84)-H(72) bond length is 0.95 Å. In the sixty-fourth C site, C(85) is bonded in a linear geometry to one C(86) and one N(21) atom. The C(85)-C(86) bond length is 1.46 Å. The C(85)-N(21) bond length is 1.12 Å. In the sixty-fifth C site, C(86) is bonded in a trigonal non-coplanar geometry to one C(85); one H(73); and two equivalent H(74,75) atoms. The C(86)-H(73) bond length is 0.98 Å. Both C(86)-H(74,75) bond lengths are 0.98 Å. There are twenty-one inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Eu(1), one C(1), one C(15), and one C(29) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Eu(1), one C(2), and one C(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(2), one C(8), and one C(9) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(1), one C(13), and one C(14) atom. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one Eu(1), one C(16), and one C(17) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(16), one C(22), and one C(23) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Ag(2), one C(27), and one C(28) atom. In the eighth N site, N(8) is bonded in a distorted trigonal non-coplanar geometry to one Eu(1), one C(30), and one C(31) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(30), one C(36), and one C(37) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Ag(2), one C(41), and one C(42) atom. In the eleventh N site, N(11) is bonded in a distorted trigonal non-coplanar geometry to one Eu(1), one C(43), one C(57), and one C(71) atom. In the twelfth N site, N(12) is bonded in a distorted trigonal non-coplanar geometry to one Eu(1), one C(44), and one C(45) atom. In the thirteenth N site, N(13) is bonded in a trigonal planar geometry to one C(44), one C(50), and one C(51) atom. In the fourteenth N site, N(14) is bonded in a trigonal planar geometry to one Ag(3), one C(55), and one C(56) atom. In the fifteenth N site, N(15) is bonded in a distorted trigonal non-coplanar geometry to one Eu(1), one C(58), and one C(59) atom. In the sixteenth N site, N(16) is bonded in a trigonal planar geometry to one C(58), one C(64), and one C(65) atom. In the seventeenth N site, N(17) is bonded in a trigonal planar geometry to one Ag(3), one C(69), and one C(70) atom. In the eighteenth N site, N(18) is bonded in a 3-coordinate geometry to one Eu(1), one C(72), and one C(73) atom. In the nineteenth N site, N(19) is bonded in a trigonal planar geometry to one C(72), one C(78), and one C(79) atom. In the twentieth N site, N(20) is bonded in a trigonal planar geometry to one Ag(1), one C(83), and one C(84) atom. In the twenty-first N site, N(21) is bonded in a linear geometry to one Ag(2) and one C(85) atom. There are forty-six inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(7,8) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(13,14) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(26) atom. In the fourteenth H site, H(23) is bonded in a single-bond geometry to one C(27) atom. In the fifteenth H site, H(24) is bonded in a single-bond geometry to one C(28) atom. In the sixteenth H site, H(25) is bonded in a single-bond geometry to one C(29) atom. In the seventeenth H site, H(26) is bonded in a single-bond geometry to one C(29) atom. In the eighteenth H site, H(30) is bonded in a single-bond geometry to one C(35) atom. In the nineteenth H site, H(31) is bonded in a single-bond geometry to one C(37) atom. In the twentieth H site, H(32) is bonded in a single-bond geometry to one C(37) atom. In the twenty-first H site, H(33) is bonded in a single-bond geometry to one C(39) atom. In the twenty-second H site, H(35) is bonded in a single-bond geometry to one C(41) atom. In the twenty-third H site, H(36) is bonded in a single-bond geometry to one C(42) atom. In the twenty-fourth H site, H(37) is bonded in a single-bond geometry to one C(43) atom. In the twenty-fifth H site, H(38) is bonded in a single-bond geometry to one C(43) atom. In the twenty-sixth H site, H(43,44) is bonded in a single-bond geometry to one C(51) atom. In the twenty-seventh H site, H(45) is bonded in a single-bond geometry to one C(53) atom. In the twenty-eighth H site, H(47) is bonded in a single-bond geometry to one C(55) atom. In the twenty-ninth H site, H(48) is bonded in a single-bond geometry to one C(56) atom. In the thirtieth H site, H(49,50) is bonded in a single-bond geometry to one C(57) atom. In the thirty-first H site, H(51) is bonded in a single-bond geometry to one C(60) atom. In the thirty-second H site, H(54) is bonded in a single-bond geometry to one C(63) atom. In the thirty-third H site, H(55) is bonded in a single-bond geometry to one C(65) atom. In the thirty-fourth H site, H(56) is bonded in a single-bond geometry to one C(65) atom. In the thirty-fifth H site, H(57) is bonded in a single-bond geometry to one C(67) atom. In the thirty-sixth H site, H(58) is bonded in a single-bond geometry to one C(68) atom. In the thirty-seventh H site, H(59) is bonded in a single-bond geometry to one C(69) atom. In the thirty-eighth H site, H(60) is bonded in a single-bond geometry to one C(70) atom. In the thirty-ninth H site, H(61,62) is bonded in a single-bond geometry to one C(71) atom. In the fortieth H site, H(67,68) is bonded in a single-bond geometry to one C(79) atom. In the forty-first H site, H(69) is bonded in a single-bond geometry to one C(81) atom. In the forty-second H site, H(70) is bonded in a single-bond geometry to one C(82) atom. In the forty-third H site, H(71) is bonded in a single-bond geometry to one C(83) atom. In the forty-fourth H site, H(72) is bonded in a single-bond geometry to one C(84) atom. In the forty-fifth H site, H(73) is bonded in a single-bond geometry to one C(86) atom. In the forty-sixth H site, H(74,75) is bonded in a single-bond geometry to one C(86) atom. Linkers: 1 C[C][N][Ag](N1[CH]C=CC(Cn2c(CN(Cc3nc4ccccc4n3Cc3cccnc3)Cc3nc4ccccc4n3Cc3cccnc3)nc3ccccc32)=C1)N1[CH]C=CC(Cn2c(CN(Cc3nc4ccccc4n3Cc3cccnc3)Cc3nc4ccccc4n3Cc3cccnc3)nc3ccccc32)=C1 ,6 c1cncc(Cn2c(CN(Cc3nc4ccccc4n3Cc3cccnc3)Cc3nc4ccccc4n3Cc3cccnc3)nc3ccccc32)c1. Metal clusters: 4 [Eu] ,11 [Ag]. The MOF has largest included sphere 4.72 A, density 1.23 g/cm3, surface area 4398.25 m2/g, accessible volume 0.37 cm3/g