ZnC10NH6O4C6H7(C3H2)2C4H3 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 2,3-dimethyl-1,3-butadiene molecules; four hexamethylbenzene molecules; eight isobutylene molecules; and four ZnC10NH6O4 clusters. In each ZnC10NH6O4 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.02 Å. The Zn(1)-O(3) bond length is 2.02 Å. The Zn(1)-O(4) bond length is 2.05 Å. There are ten inequivalent C sites. In the first C site, C(2) is bonded in a single-bond geometry to one C(6) and one H(16) atom. The C(2)-C(6) bond length is 1.37 Å. The C(2)-H(16) bond length is 0.94 Å. In the second C site, C(4) is bonded in a trigonal planar geometry to one C(14), one C(17), and one C(26) atom. The C(4)-C(14) bond length is 1.39 Å. The C(4)-C(17) bond length is 1.50 Å. The C(4)-C(26) bond length is 1.39 Å. In the third C site, C(6) is bonded in a trigonal planar geometry to one C(12), one C(2), and one C(22) atom. The C(6)-C(12) bond length is 1.39 Å. The C(6)-C(22) bond length is 1.50 Å. In the fourth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(8)-N(1) bond length is 1.33 Å. The C(8)-H(5) bond length is 0.94 Å. In the fifth C site, C(12) is bonded in a distorted single-bond geometry to one C(6) and one H(11) atom. The C(12)-H(11) bond length is 0.94 Å. In the sixth C site, C(14) is bonded in a distorted single-bond geometry to one C(4) and one H(15) atom. The C(14)-H(15) bond length is 0.94 Å. In the seventh C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(3) atom. The C(17)-O(2) bond length is 1.26 Å. The C(17)-O(3) bond length is 1.25 Å. In the eighth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(18) atom. The C(20)-N(1) bond length is 1.31 Å. The C(20)-H(18) bond length is 0.94 Å. In the ninth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(4) atom. The C(22)-O(1) bond length is 1.26 Å. The C(22)-O(4) bond length is 1.26 Å. In the tenth C site, C(26) is bonded in a single-bond geometry to one C(4) and one H(17) atom. The C(26)-H(17) bond length is 0.94 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(20), and one C(8) atom. There are six inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(22) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(22) atom. Linkers: 3 Cc1c(C)c(/C=C/c2ccncc2)c(C)c(C)c1/C=C/c1ccncc1 ,4 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 5.14 A, density 1.22 g/cm3, surface area 4889.47 m2/g, accessible volume 0.30 cm3/g