Zn3B4C88N12H6(O3F2)4 crystallizes in the tetragonal I4/m space group. The structure consists of a Zn3B4C88N12H6(O3F2)4 framework. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted square co-planar geometry to four equivalent O(3) atoms. All Zn(1)-O(3) bond lengths are 2.02 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one N(3), one N(4), and two equivalent O(2) atoms. The Zn(2)-N(3) bond length is 2.03 Å. The Zn(2)-N(4) bond length is 2.03 Å. Both Zn(2)-O(2) bond lengths are 1.94 Å. B(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one F(1), and one F(2) atom. The B(1)-N(1) bond length is 1.53 Å. The B(1)-N(2) bond length is 1.51 Å. The B(1)-F(1) bond length is 1.44 Å. The B(1)-F(2) bond length is 1.46 Å. There are twenty-seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(25), and one C(3) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-C(25) bond length is 1.36 Å. The C(1)-C(3) bond length is 1.52 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(26), and one H(1) atom. The C(2)-C(26) bond length is 1.39 Å. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(3)-O(1) bond length is 1.23 Å. The C(3)-O(2) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one N(3) atom. The C(4)-C(5) bond length is 1.43 Å. The C(4)-N(3) bond length is 1.25 Å. In the fifth C site, C(5) is bonded in a 3-coordinate geometry to one C(18), one C(4), and one C(5) atom. The C(5)-C(18) bond length is 1.43 Å. The C(5)-C(5) bond length is 1.36 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(11), one C(19), and one N(1) atom. The C(6)-C(11) bond length is 1.55 Å. The C(6)-C(19) bond length is 1.63 Å. The C(6)-N(1) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one N(4) atom. The C(7)-C(8) bond length is 1.42 Å. The C(7)-N(4) bond length is 1.25 Å. In the eighth C site, C(8) is bonded in a 3-coordinate geometry to one C(24), one C(7), and one C(8) atom. The C(8)-C(24) bond length is 1.45 Å. The C(8)-C(8) bond length is 1.38 Å. In the ninth C site, C(9) is bonded in a 3-coordinate geometry to one C(10), one C(24), and one C(9) atom. The C(9)-C(10) bond length is 1.43 Å. The C(9)-C(24) bond length is 1.31 Å. The C(9)-C(9) bond length is 1.22 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one N(4) atom. The C(10)-N(4) bond length is 1.46 Å. In the eleventh C site, C(11) is bonded in a single-bond geometry to one C(6) atom. In the twelfth C site, C(12) is bonded in a 3-coordinate geometry to one C(12), one C(13), and one C(18) atom. The C(12)-C(12) bond length is 1.21 Å. The C(12)-C(13) bond length is 1.41 Å. The C(12)-C(18) bond length is 1.32 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one N(3) atom. The C(13)-N(3) bond length is 1.45 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(14), one C(17), and one C(19) atom. The C(14)-C(14) bond length is 1.10 Å. The C(14)-C(17) bond length is 1.46 Å. The C(14)-C(19) bond length is 1.40 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16), one C(23), and one N(2) atom. The C(15)-C(16) bond length is 1.52 Å. The C(15)-C(23) bond length is 1.65 Å. The C(15)-N(2) bond length is 1.39 Å. In the sixteenth C site, C(16) is bonded in a single-bond geometry to one C(15) atom. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(14) atom. In the eighteenth C site, C(18) is bonded in a 5-coordinate geometry to one C(19), two equivalent C(12), and two equivalent C(5) atoms. The C(18)-C(19) bond length is 1.45 Å. In the nineteenth C site, C(19) is bonded in a 5-coordinate geometry to one C(18), two equivalent C(14), and two equivalent C(6) atoms. In the twentieth C site, C(20) is bonded in a 2-coordinate geometry to two equivalent N(1) atoms. Both C(20)-N(1) bond lengths are 1.43 Å. In the twenty-first C site, C(21) is bonded in a 2-coordinate geometry to one C(22) and two equivalent N(2) atoms. The C(21)-C(22) bond length is 1.44 Å. Both C(21)-N(2) bond lengths are 1.44 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(21) and one C(23) atom. The C(22)-C(23) bond length is 1.30 Å. In the twenty-third C site, C(23) is bonded in a 4-coordinate geometry to one C(22), one C(24), and two equivalent C(15) atoms. The C(23)-C(24) bond length is 1.41 Å. In the twenty-fourth C site, C(24) is bonded in a 5-coordinate geometry to one C(23), two equivalent C(8), and two equivalent C(9) atoms. In the twenty-fifth C site, C(25) is bonded in a distorted single-bond geometry to two equivalent C(1) and one H(2) atom. The C(25)-H(2) bond length is 0.93 Å. In the twenty-sixth C site, C(26) is bonded in a trigonal planar geometry to one C(27) and two equivalent C(2) atoms. The C(26)-C(27) bond length is 1.53 Å. In the twenty-seventh C site, C(27) is bonded in a bent 120 degrees geometry to one C(26) and two equivalent O(3) atoms. Both C(27)-O(3) bond lengths are 1.24 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to one B(1), one C(20), one C(6), and one N(1) atom. The N(1)-N(1) bond length is 1.43 Å. In the second N site, N(2) is bonded in a 4-coordinate geometry to one B(1), one C(15), one C(21), and one N(2) atom. The N(2)-N(2) bond length is 1.47 Å. In the third N site, N(3) is bonded in a 5-coordinate geometry to one Zn(2), two equivalent C(13), and two equivalent C(4) atoms. In the fourth N site, N(4) is bonded in a 5-coordinate geometry to one Zn(2), two equivalent C(10), and two equivalent C(7) atoms. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(25) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a water-like geometry to one Zn(2) and one C(3) atom. In the second O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(27) atom. In the third O site, O(1) is bonded in a single-bond geometry to one C(3) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(1) atom. Linkers: 1 F[B]F.O=[C]O[Zn].[B].[B].[B].[B].[B].[B].[B].[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]/[C]=[C]\[C].[C]/[C]=[C]\[C].[C]/[C]=[C]\[C].[C]/[C]=[C]\[C]=[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[CH].[C]C([O])=O.[C]N([C])[C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C]1[C][C]1.[C][C]=[C].[C][C]=[C].[C][C]=[C].[C][C]N1[C]N1B(F)F.[C][C]N1[C][N]1.[C][C][C].[C][C][C].[C][C][C].[C][C][C].[C][C][C].[C][C][C]1[C]C1([C])[C].[C][C][C][C].[C][C][C][C][C]([C])[C][C].[C][C][C][C][N][C].[C][C][N].[C][C][N].[C][C][N][C].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N][C].[C][N][C].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][C]=O.[O][C]=O.[O][Zn].[O][Zn].[O][Zn]N1[C][C]1.[O][Zn][O].[Zn].[Zn].[Zn].[Zn].[Zn].[Zn].[Zn].[c]1[c][c]c[c][c]1 ,1 F[B]F.F[B]F.[B].[B].[B].[B].[B].[B].[B].[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#N.[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]1[C][N]1.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[C][C]=[C].[C]=[C][C]C=[C].[C]N=[C].[C][CH].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C]/[C]=C\[C].[C][C]/[C]=[C]\O[Zn].[C][C]=[C].[C][C]=[C].[C][C]=[C].[C][C]N1[C]N1[B]F.[C][C]N1[C][N]1.[C][C][C].[C][C][C].[C][C][C].[C][C][C]([C])[C].[C][C][C]([C])[C][N][C].[C][C][C][C][C].[C][C][N].[C][C][N].[C][C][N].[C][C][N].[C][C][N].[C][C][N][C].[C][C][N][C].[C][C][N][C].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N][C].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][Zn].[O][Zn].[O][Zn].[O][Zn]([O])(N1[C][C]1)N1[C][C]1.[O][Zn][O].[Zn].[Zn].[Zn].[Zn].[Zn].[Zn].[c]1[c]c[c]c[c]1 ,1 F[B]F.[B].[B].[B].[B].[B].[B].[B].[B].[B].[B].[B].[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[B]F.[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]#[C].[C]/C(=[C]\[C]=[C])C([O])=O.[C]/C=[C]\C=[C]/[C]=C(\[C])C([O])=O.[C]/[C]=[C]\C=[C]/[C].[C]1[C]C12[C][C]2.[C]1[C][N]1.[C]1[C][N]1.[C]1[C][N]1.[C]1[C][N]1.[C]1[C][N]1.[C]1[C][N]1.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[C]/[C]=[C]\[CH].[C]=[C][C]1[C][C]1.[C]C1([C]=[C])[C][C]1.[C]C=[C].[C]N1[C][C]1.[C]N1[C][C]1.[C]N=[C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C]=[C].[C][C]=[C].[C][C]C1([C])[C][C]1.[C][C]C1([C][C])[C][C]1.[C][C]N1[C]N1[C][C].[C][C]N1[C][N]1.[C][C][C].[C][C][C].[C][C][C].[C][C][C].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N][C].[C][N][C].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[F].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][Zn].[O][Zn].[O][Zn].[O][Zn].[O][Zn][O].[O][Zn][O].[O][Zn][O].[O][Zn][O].[Zn].[Zn].[Zn].[Zn].[Zn]. Metal clusters: 2 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: dia. The MOF has largest included sphere 6.49 A, density 1.35 g/cm3, surface area 3652.58 m2/g, accessible volume 0.35 cm3/g