ZnC22H16(N3O)2 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnC22H16(N3O)2 clusters. Zn(1) is bonded in a tetrahedral geometry to one N(2), one N(4), one N(5), and one O(1) atom. The Zn(1)-N(2) bond length is 1.99 Å. The Zn(1)-N(4) bond length is 1.99 Å. The Zn(1)-N(5) bond length is 1.99 Å. The Zn(1)-O(1) bond length is 1.93 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one C(8) and one H(5) atom. The C(1)-C(8) bond length is 1.38 Å. The C(1)-H(5) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(18), one C(21), and one C(6) atom. The C(2)-C(18) bond length is 1.38 Å. The C(2)-C(21) bond length is 1.39 Å. The C(2)-C(6) bond length is 1.47 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(13) and one H(9) atom. The C(3)-C(13) bond length is 1.40 Å. The C(3)-H(9) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(4)-C(8) bond length is 1.39 Å. The C(4)-H(8) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(11) atom. The C(5)-C(12) bond length is 1.36 Å. The C(5)-N(2) bond length is 1.38 Å. The C(5)-H(11) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(15), one C(2), and one N(1) atom. The C(6)-C(15) bond length is 1.35 Å. The C(6)-N(1) bond length is 1.38 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(11) and one H(1) atom. The C(7)-C(11) bond length is 1.39 Å. The C(7)-H(1) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(1), one C(19), and one C(4) atom. The C(8)-C(19) bond length is 1.50 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(5), and one H(10) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-N(5) bond length is 1.32 Å. The C(9)-H(10) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(13) and one H(16) atom. The C(10)-C(13) bond length is 1.39 Å. The C(10)-H(16) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(17), one C(22), and one C(7) atom. The C(11)-C(17) bond length is 1.40 Å. The C(11)-C(22) bond length is 1.47 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(13), one C(5), and one N(3) atom. The C(12)-C(13) bond length is 1.46 Å. The C(12)-N(3) bond length is 1.38 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(3) atom. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(6) atom. The C(14)-N(4) bond length is 1.33 Å. The C(14)-N(6) bond length is 1.34 Å. The C(14)-H(6) bond length is 0.93 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(6), one N(5), and one H(14) atom. The C(15)-N(5) bond length is 1.38 Å. The C(15)-H(14) bond length is 0.93 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(4), and one H(12) atom. The C(16)-C(22) bond length is 1.36 Å. The C(16)-N(4) bond length is 1.37 Å. The C(16)-H(12) bond length is 0.93 Å. In the seventeenth C site, C(17) is bonded in a single-bond geometry to one C(11) and one H(15) atom. The C(17)-H(15) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(18)-H(3) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a bent 120 degrees geometry to one C(8), one O(1), and one O(2) atom. The C(19)-O(1) bond length is 1.28 Å. The C(19)-O(2) bond length is 1.23 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(2) atom. The C(20)-N(2) bond length is 1.32 Å. The C(20)-N(3) bond length is 1.34 Å. The C(20)-H(2) bond length is 0.93 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(2) and one H(7) atom. The C(21)-H(7) bond length is 0.93 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(11), one C(16), and one N(6) atom. The C(22)-N(6) bond length is 1.39 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(6), one C(9), and one H(13) atom. The N(1)-H(13) bond length is 0.86 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(20), and one C(5) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(12), one C(20), and one H(4) atom. The N(3)-H(4) bond length is 0.86 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(14), and one C(16) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(9) atom. In the sixth N site, N(6) is bonded in a water-like geometry to one C(14) and one C(22) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(20) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(18) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(3) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(5) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one N(1) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(19) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(19) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)cc1 ,1 C1=NC=C(c2ccc(C3=C[N]C=N3)cc2)[N]1 ,2 c1ncc(-c2ccc(-c3cnc[nH]3)cc2)[nH]1. Metal clusters: 2 O=[C]O[Zn]. The MOF has largest included sphere 3.98 A, density 1.36 g/cm3, surface area 5106.37 m2/g, accessible volume 0.24 cm3/g