Cd3C32H12(NO8)2(CH)4(C3H2)2 crystallizes in the tetragonal I4_1/a space group. The structure consists of sixty-four 02329_fluka molecules and sixteen 2,3-dimethyl-1,3-butadiene molecules inside a Cd3C32H12(NO8)2 framework. In the Cd3C32H12(NO8)2 framework, there are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 5-coordinate geometry to one N(1), one O(13), one O(14), one O(2), and one O(8) atom. The Cd(1)-N(1) bond length is 2.33 Å. The Cd(1)-O(13) bond length is 2.43 Å. The Cd(1)-O(14) bond length is 2.39 Å. The Cd(1)-O(2) bond length is 2.22 Å. The Cd(1)-O(8) bond length is 2.29 Å. In the second Cd site, Cd(2) is bonded in a water-like geometry to one O(1) and one O(5) atom. The Cd(2)-O(1) bond length is 2.26 Å. The Cd(2)-O(5) bond length is 2.23 Å. In the third Cd site, Cd(3) is bonded in a distorted trigonal bipyramidal geometry to one N(2), one O(10), one O(4), one O(6), and one O(9) atom. The Cd(3)-N(2) bond length is 2.32 Å. The Cd(3)-O(10) bond length is 2.37 Å. The Cd(3)-O(4) bond length is 2.21 Å. The Cd(3)-O(6) bond length is 2.21 Å. The Cd(3)-O(9) bond length is 2.45 Å. There are thirty-two inequivalent C sites. In the first C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(7) atom. The C(17)-C(18) bond length is 1.43 Å. The C(17)-H(7) bond length is 0.93 Å. In the second C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(29) atom. The C(18)-C(19) bond length is 1.34 Å. The C(18)-C(29) bond length is 1.50 Å. In the third C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(30) atom. The C(19)-C(20) bond length is 1.42 Å. The C(19)-C(30) bond length is 1.51 Å. In the fourth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(25) atom. The C(20)-C(21) bond length is 1.36 Å. The C(20)-C(25) bond length is 1.51 Å. In the fifth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(8) atom. The C(21)-H(8) bond length is 0.93 Å. In the sixth C site, C(23) is bonded in a trigonal planar geometry to one C(24), one C(28), and one C(32) atom. The C(23)-C(24) bond length is 1.45 Å. The C(23)-C(28) bond length is 1.38 Å. The C(23)-C(32) bond length is 1.50 Å. In the seventh C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(31) atom. The C(24)-C(25) bond length is 1.35 Å. The C(24)-C(31) bond length is 1.50 Å. In the eighth C site, C(25) is bonded in a trigonal planar geometry to one C(20), one C(24), and one C(26) atom. The C(25)-C(26) bond length is 1.37 Å. In the ninth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(10) atom. The C(26)-H(10) bond length is 0.93 Å. In the tenth C site, C(28) is bonded in a distorted single-bond geometry to one C(23) and one H(12) atom. The C(28)-H(12) bond length is 0.93 Å. In the eleventh C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(11), and one O(12) atom. The C(29)-O(11) bond length is 1.26 Å. The C(29)-O(12) bond length is 1.27 Å. In the twelfth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(10), and one O(9) atom. The C(30)-O(10) bond length is 1.28 Å. The C(30)-O(9) bond length is 1.24 Å. In the thirteenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(13), and one O(14) atom. The C(31)-O(13) bond length is 1.22 Å. The C(31)-O(14) bond length is 1.26 Å. In the fourteenth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(15), and one O(16) atom. The C(32)-O(15) bond length is 1.27 Å. The C(32)-O(16) bond length is 1.20 Å. In the fifteenth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(33)-N(1) bond length is 1.28 Å. The C(33)-H(13) bond length is 0.93 Å. In the sixteenth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(16) atom. The C(37)-N(1) bond length is 1.35 Å. The C(37)-H(16) bond length is 0.93 Å. In the seventeenth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(18) atom. The C(40)-N(2) bond length is 1.33 Å. The C(40)-H(18) bond length is 0.93 Å. In the eighteenth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(19) atom. The C(41)-N(2) bond length is 1.34 Å. The C(41)-H(19) bond length is 0.93 Å. In the nineteenth C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.36 Å. The C(1)-C(7) bond length is 1.49 Å. In the twentieth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(14), and one C(3) atom. The C(2)-C(14) bond length is 1.50 Å. The C(2)-C(3) bond length is 1.40 Å. In the twenty-first C site, C(3) is bonded in a trigonal planar geometry to one C(13), one C(2), and one C(4) atom. The C(3)-C(13) bond length is 1.48 Å. The C(3)-C(4) bond length is 1.39 Å. In the twenty-second C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(4)-H(1) bond length is 0.93 Å. In the twenty-third C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the twenty-fourth C site, C(7) is bonded in a trigonal planar geometry to one C(1), one C(12), and one C(8) atom. The C(7)-C(12) bond length is 1.39 Å. The C(7)-C(8) bond length is 1.41 Å. In the twenty-fifth C site, C(8) is bonded in a trigonal planar geometry to one C(15), one C(7), and one C(9) atom. The C(8)-C(15) bond length is 1.48 Å. The C(8)-C(9) bond length is 1.45 Å. In the twenty-sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(16), and one C(8) atom. The C(9)-C(10) bond length is 1.36 Å. The C(9)-C(16) bond length is 1.43 Å. In the twenty-seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(10)-H(4) bond length is 0.93 Å. In the twenty-eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(12)-H(6) bond length is 0.93 Å. In the twenty-ninth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(4) atom. The C(13)-O(3) bond length is 1.26 Å. The C(13)-O(4) bond length is 1.24 Å. In the thirtieth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(14)-O(1) bond length is 1.28 Å. The C(14)-O(2) bond length is 1.23 Å. In the thirty-first C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(5), and one O(6) atom. The C(15)-O(5) bond length is 1.22 Å. The C(15)-O(6) bond length is 1.26 Å. In the thirty-second C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(7), and one O(8) atom. The C(16)-O(7) bond length is 1.28 Å. The C(16)-O(8) bond length is 1.24 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(33), and one C(37) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(3), one C(40), and one C(41) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(26) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(28) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(33) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(37) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(40) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(41) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Cd(2) and one C(14) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1) and one C(14) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(13) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(3) and one C(13) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one C(15) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cd(3) and one C(15) atom. In the seventh O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(16) atom. In the eighth O site, O(9) is bonded in a distorted single-bond geometry to one Cd(3) and one C(30) atom. In the ninth O site, O(10) is bonded in a distorted single-bond geometry to one Cd(3) and one C(30) atom. In the tenth O site, O(11) is bonded in a single-bond geometry to one C(29) atom. In the eleventh O site, O(14) is bonded in a distorted single-bond geometry to one Cd(1) and one C(31) atom. In the twelfth O site, O(15) is bonded in a single-bond geometry to one C(32) atom. In the thirteenth O site, O(16) is bonded in a single-bond geometry to one C(32) atom. In the fourteenth O site, O(12) is bonded in a single-bond geometry to one C(29) atom. In the fifteenth O site, O(13) is bonded in a distorted single-bond geometry to one Cd(1) and one C(31) atom. In the sixteenth O site, O(7) is bonded in a single-bond geometry to one C(16) atom. Linkers: 14 [O]C(=O)c1cccc(-c2cccc(C([O])=O)c2C([O])=O)c1C([O])=O ,8 c1cc(-c2ccncc2)ccn1 ,2 [O]C(=O)c1cccc(-c2cccc([C]=O)c2C([O])=O)c1C([O])=O. Metal clusters: 8 O=[C]O[Cd]1(O[C]O[Cd]O[C]O[Cd]2(O[C]=O)O[C]O2)O[C]O1. The MOF has largest included sphere 9.08 A, density 1.36 g/cm3, surface area 3884.89 m2/g, accessible volume 0.36 cm3/g