Cu(OOCC6H4COO)(CH)4HC2N is Indium-derived structured and crystallizes in the orthorhombic Fddd space group. The structure is zero-dimensional and consists of one hundred and twenty-eight 02329_fluka molecules, thirty-two dimethylamine molecules, and sixteen Cu(OOCC6H4COO) clusters. In each Cu(OOCC6H4COO) cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-O(1) bond length is 1.97 Å. The Cu(1)-O(2) bond length is 1.95 Å. The Cu(1)-O(3) bond length is 1.96 Å. The Cu(1)-O(4) bond length is 1.97 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.48 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(2), and one O(3) atom. The C(7)-O(2) bond length is 1.26 Å. The C(7)-O(3) bond length is 1.26 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(1), and one O(4) atom. The C(8)-C(9) bond length is 1.50 Å. The C(8)-O(1) bond length is 1.26 Å. The C(8)-O(4) bond length is 1.26 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(14) bond length is 1.39 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(10)-H(5) bond length is 0.93 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. There are four inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(8) atom. In the second O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the third O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(8) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one Cu(1) and one C(7) atom. Linkers: 8 [O]C(=O)c1ccc(Nc2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: lvt. The MOF has largest included sphere 7.63 A, density 0.98 g/cm3, surface area 4204.13 m2/g, accessible volume 0.55 cm3/g