CdC19H10(NO3)3(CH)2 crystallizes in the monoclinic C2/m space group. The structure consists of eight 02329_fluka molecules inside a CdC19H10(NO3)3 framework. In the CdC19H10(NO3)3 framework, Cd(1) is bonded in a distorted pentagonal planar geometry to one O(4), two equivalent O(1), and two equivalent O(3) atoms. The Cd(1)-O(4) bond length is 2.38 Å. Both Cd(1)-O(1) bond lengths are 2.37 Å. Both Cd(1)-O(3) bond lengths are 2.36 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(1)-C(3) bond length is 1.41 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(4) and one O(2) atom. The C(2)-C(4) bond length is 1.39 Å. The C(2)-O(2) bond length is 1.37 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one N(1) atom. The C(3)-C(5) bond length is 1.38 Å. The C(3)-N(1) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-C(6) bond length is 1.51 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3), one C(4), and one H(3) atom. The C(5)-H(3) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a bent 120 degrees geometry to one C(4), one O(1), and one O(3) atom. The C(6)-O(1) bond length is 1.28 Å. The C(6)-O(3) bond length is 1.23 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(14), one C(9), and one O(6) atom. The C(8)-C(14) bond length is 1.37 Å. The C(8)-C(9) bond length is 1.41 Å. The C(8)-O(6) bond length is 1.38 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(9)-H(5) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one N(2) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(13) bond length is 1.37 Å. The C(10)-N(2) bond length is 1.43 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(6) atom. The C(11)-H(6) bond length is 0.93 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14), one O(4), and one O(5) atom. The C(12)-C(14) bond length is 1.48 Å. The C(12)-O(4) bond length is 1.34 Å. The C(12)-O(5) bond length is 1.20 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one H(7) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-H(7) bond length is 0.93 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(8) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(3) and one N(1) atom. The N(1)-N(1) bond length is 1.26 Å. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(10) and one N(2) atom. The N(2)-N(2) bond length is 1.31 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.82 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(8) is bonded in a distorted single-bond geometry to one O(4) and one O(6) atom. The H(8)-O(4) bond length is 1.68 Å. The H(8)-O(6) bond length is 0.82 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(6) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(2) and one H(2) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(6) atom. In the fourth O site, O(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(12), and one H(8) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(12) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one C(8) and one H(8) atom. Linkers: 1 [O][C]c1cc([N][N]c2ccc(O)c(C([O])=O)c2)ccc1O ,5 [O]C(=O)c1cc([N][N]c2ccc(O)c(C([O])=O)c2)ccc1O. Metal clusters: 2 O=[C]O[Cd]123O[C]O[Cd](O[C]=O)(O[C]O1)(O[C]O2)O[C]O3. RCSR code: pcu. The MOF has largest included sphere 6.26 A, density 0.98 g/cm3, surface area 4374.42 m2/g, accessible volume 0.62 cm3/g