WCu3C18N6H15S3Br(CH)2C7NH4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight schembl5425382 molecules, and eight WCu3C18N6H15S3Br clusters. In each WCu3C18N6H15S3Br cluster, W(1) is bonded in a 6-coordinate geometry to one Cu(1), one Cu(2), one Cu(3), one S(1), one S(2), and one S(3) atom. The W(1)-Cu(1) bond length is 2.64 Å. The W(1)-Cu(2) bond length is 2.69 Å. The W(1)-Cu(3) bond length is 2.65 Å. The W(1)-S(1) bond length is 2.26 Å. The W(1)-S(2) bond length is 2.26 Å. The W(1)-S(3) bond length is 2.25 Å. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 4-coordinate geometry to one W(1), one S(1), one S(3), and one Br(1) atom. The Cu(1)-S(1) bond length is 2.25 Å. The Cu(1)-S(3) bond length is 2.25 Å. The Cu(1)-Br(1) bond length is 2.26 Å. In the second Cu site, Cu(2) is bonded in a 4-coordinate geometry to one W(1), one N(1), one N(4), one S(1), and one S(2) atom. The Cu(2)-N(1) bond length is 2.09 Å. The Cu(2)-N(4) bond length is 1.97 Å. The Cu(2)-S(1) bond length is 2.29 Å. The Cu(2)-S(2) bond length is 2.28 Å. In the third Cu site, Cu(3) is bonded in a 3-coordinate geometry to one W(1), one N(6), one S(2), and one S(3) atom. The Cu(3)-N(6) bond length is 1.93 Å. The Cu(3)-S(2) bond length is 2.26 Å. The Cu(3)-S(3) bond length is 2.27 Å. There are eighteen inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(5) and one H(1) atom. The C(2)-C(5) bond length is 1.38 Å. The C(2)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(7) atom. The C(5)-C(6) bond length is 1.37 Å. The C(5)-N(7) bond length is 1.47 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a trigonal planar geometry to one N(6), one N(7), and one H(5) atom. The C(7)-N(6) bond length is 1.34 Å. The C(7)-N(7) bond length is 1.31 Å. The C(7)-H(5) bond length is 0.93 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(27), one N(6), and one H(6) atom. The C(8)-C(27) bond length is 1.33 Å. The C(8)-N(6) bond length is 1.34 Å. The C(8)-H(6) bond length is 0.93 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(7) atom. The C(9)-N(1) bond length is 1.32 Å. The C(9)-N(2) bond length is 1.36 Å. The C(9)-H(7) bond length is 0.93 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(1), and one H(8) atom. The C(10)-C(11) bond length is 1.35 Å. The C(10)-N(1) bond length is 1.37 Å. The C(10)-H(8) bond length is 0.93 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(2), and one H(9) atom. The C(11)-N(2) bond length is 1.41 Å. The C(11)-H(9) bond length is 0.93 Å. In the ninth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one C(14), and one N(2) atom. The C(12)-C(13) bond length is 1.36 Å. The C(12)-C(14) bond length is 1.40 Å. The C(12)-N(2) bond length is 1.40 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(13)-H(10) bond length is 0.93 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(14)-H(11) bond length is 0.93 Å. In the twelfth C site, C(19) is bonded in a 3-coordinate geometry to one C(21), one N(4), and one H(14) atom. The C(19)-C(21) bond length is 1.37 Å. The C(19)-N(4) bond length is 1.42 Å. The C(19)-H(14) bond length is 0.93 Å. In the thirteenth C site, C(20) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(15) atom. The C(20)-N(4) bond length is 1.31 Å. The C(20)-N(5) bond length is 1.35 Å. The C(20)-H(15) bond length is 0.93 Å. In the fourteenth C site, C(21) is bonded in a 3-coordinate geometry to one C(19), one N(5), and one H(16) atom. The C(21)-N(5) bond length is 1.38 Å. The C(21)-H(16) bond length is 0.93 Å. In the fifteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(23), one C(24), and one N(5) atom. The C(22)-C(23) bond length is 1.38 Å. The C(22)-C(24) bond length is 1.38 Å. The C(22)-N(5) bond length is 1.40 Å. In the sixteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(17) atom. The C(23)-H(17) bond length is 0.93 Å. In the seventeenth C site, C(24) is bonded in a distorted single-bond geometry to one C(22) and one H(18) atom. The C(24)-H(18) bond length is 0.93 Å. In the eighteenth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(8), one N(7), and one H(21) atom. The C(27)-N(7) bond length is 1.37 Å. The C(27)-H(21) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(2), one C(10), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(19), and one C(20) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one C(20), one C(21), and one C(22) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one Cu(3), one C(7), and one C(8) atom. In the sixth N site, N(7) is bonded in a trigonal planar geometry to one C(27), one C(5), and one C(7) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(27) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a 3-coordinate geometry to one W(1), one Cu(1), and one Cu(2) atom. In the second S site, S(2) is bonded in a 3-coordinate geometry to one W(1), one Cu(2), and one Cu(3) atom. In the third S site, S(3) is bonded in a 3-coordinate geometry to one W(1), one Cu(1), and one Cu(3) atom. Br(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 4 c1cn(-c2ccc(N(c3ccc(-n4ccnc4)cc3)c3ccc(-n4ccnc4)cc3)cc2)cn1 ,2 [C]N(C=[CH])c1ccc(N(c2ccc(-n3ccnc3)cc2)c2ccc(-n3ccnc3)cc2)cc1 ,2 [CH]=Nc1ccc(N(c2ccc(-n3ccnc3)cc2)c2ccc(-n3ccnc3)cc2)cc1. Metal clusters: 4 Br[Cu@]12[S]3[Cu]4[S@@]5[Cu]6[S]1[W]35462. The MOF has largest included sphere 7.43 A, density 1.59 g/cm3, surface area 3363.02 m2/g, accessible volume 0.25 cm3/g