CuH8(C2N)4(CH)16(CH2)2 is Indium-derived structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, sixty-four isobutylene molecules, and sixteen CuH8(C2N)4 clusters. In each CuH8(C2N)4 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Cu(1)-N(1) bond lengths are 2.04 Å. Both Cu(1)-N(2) bond lengths are 2.04 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.37 Å. The C(5)-H(4) bond length is 0.93 Å. In the third C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(11) atom. The C(9)-N(2) bond length is 1.34 Å. The C(9)-H(11) bond length is 0.93 Å. In the fourth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(14) atom. The C(13)-N(2) bond length is 1.33 Å. The C(13)-H(14) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(9) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(13) atom. Linkers: 32 c1cc(CCCc2ccncc2)ccn1. Metal clusters: 16 [Cu]. The MOF has largest included sphere 7.75 A, density 1.01 g/cm3, surface area 5619.97 m2/g, accessible volume 0.43 cm3/g