(CH)3CuC11N3H8O2Br(C5H2O2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules, sixteen methyl methacrylate molecules, and eight CuC11N3H8O2Br clusters. In each CuC11N3H8O2Br cluster, Cu(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(6), and one Br(1) atom. The Cu(1)-N(1) bond length is 2.02 Å. The Cu(1)-N(2) bond length is 2.10 Å. The Cu(1)-N(6) bond length is 2.04 Å. The Cu(1)-Br(1) bond length is 2.44 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(16)-N(2) bond length is 1.34 Å. The C(16)-H(9) bond length is 0.95 Å. In the fourth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(17)-N(2) bond length is 1.34 Å. The C(17)-H(10) bond length is 0.95 Å. In the fifth C site, C(35) is bonded in a distorted single-bond geometry to one O(11) atom. The C(35)-O(11) bond length is 1.40 Å. In the sixth C site, C(43) is bonded in a distorted bent 120 degrees geometry to one C(44), one O(11), and one O(12) atom. The C(43)-C(44) bond length is 1.50 Å. The C(43)-O(11) bond length is 1.36 Å. The C(43)-O(12) bond length is 1.19 Å. In the seventh C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(48) atom. The C(44)-C(45) bond length is 1.39 Å. The C(44)-C(48) bond length is 1.39 Å. In the eighth C site, C(45) is bonded in a distorted single-bond geometry to one C(44), one C(46), and one H(27) atom. The C(45)-C(46) bond length is 1.39 Å. The C(45)-H(27) bond length is 0.95 Å. In the ninth C site, C(46) is bonded in a distorted trigonal planar geometry to one C(45), one N(6), and one H(28) atom. The C(46)-N(6) bond length is 1.35 Å. The C(46)-H(28) bond length is 0.95 Å. In the tenth C site, C(47) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(29) atom. The C(47)-N(6) bond length is 1.35 Å. The C(47)-H(29) bond length is 0.95 Å. In the eleventh C site, C(48) is bonded in a distorted single-bond geometry to one C(44) and one H(12,30) atom. The C(48)-H(12,30) bond length is 0.95 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(16), and one C(17) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(46), and one C(47) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(12,30) is bonded in a single-bond geometry to one C(21) atom. The H(12,30)-C(21) bond length is 0.95 Å. In the sixth H site, H(27) is bonded in a single-bond geometry to one C(45) atom. In the seventh H site, H(28) is bonded in a single-bond geometry to one C(46) atom. In the eighth H site, H(29) is bonded in a single-bond geometry to one C(47) atom. There are two inequivalent O sites. In the first O site, O(11) is bonded in a bent 120 degrees geometry to one C(35) and one C(43) atom. In the second O site, O(12) is bonded in a single-bond geometry to one C(43) atom. Br(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 8 O=C(Oc1cc(OC(=O)c2ccncc2)cc(OC(=O)c2ccncc2)c1)c1ccncc1. Metal clusters: 8 [Cu]Br. The MOF has largest included sphere 9.53 A, density 1.13 g/cm3, surface area 4297.51 m2/g, accessible volume 0.47 cm3/g