AgH20(C4N)4AgH16(C6N)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four AgH16(C6N)2 clusters and four AgH20(C4N)4 clusters. In each AgH16(C6N)2 cluster, Ag(2) is bonded in a linear geometry to two equivalent N(3) atoms. Both Ag(2)-N(3) bond lengths are 2.22 Å. There are six inequivalent C sites. In the first C site, C(9) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(11,12) atoms. The C(9)-N(3) bond length is 1.49 Å. Both C(9)-H(11,12) bond lengths are 0.99 Å. In the second C site, C(11) is bonded in a 3-coordinate geometry to one C(12); one N(3); and two equivalent H(15,16) atoms. The C(11)-C(12) bond length is 1.50 Å. The C(11)-N(3) bond length is 1.49 Å. Both C(11)-H(15,16) bond lengths are 0.99 Å. In the third C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(14) bond length is 1.40 Å. In the fourth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(18) atom. The C(14)-H(18) bond length is 0.95 Å. In the fifth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(17) atom. The C(13)-H(17) bond length is 0.95 Å. In the sixth C site, C(8) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(9,10) atoms. The C(8)-N(3) bond length is 1.48 Å. Both C(8)-H(9,10) bond lengths are 0.99 Å. N(3) is bonded to one Ag(2), one C(11), one C(8), and one C(9) atom to form corner-sharing NAgC3 tetrahedra. There are five inequivalent H sites. In the first H site, H(9,10) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(11,12) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(15,16) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one C(14) atom. In each AgH20(C4N)4 cluster, Ag(1) is bonded in a linear geometry to two equivalent N(1) atoms. Both Ag(1)-N(1) bond lengths are 2.13 Å. There are eight inequivalent C sites. In the first C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent H(13,14) atoms. The C(10)-N(2) bond length is 1.45 Å. Both C(10)-H(13,14) bond lengths are 0.99 Å. In the second C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.36 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.95 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 0.95 Å. In the fourth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(6) bond length is 1.50 Å. In the fifth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-H(3) bond length is 0.95 Å. In the sixth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.95 Å. In the seventh C site, C(6) is bonded in a 3-coordinate geometry to one C(3); one N(2); and two equivalent H(5,6) atoms. The C(6)-N(2) bond length is 1.48 Å. Both C(6)-H(5,6) bond lengths are 0.99 Å. In the eighth C site, C(7) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(7,8) atoms. The C(7)-N(2) bond length is 1.47 Å. Both C(7)-H(7,8) bond lengths are 0.99 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal non-coplanar geometry to one C(10), one C(6), and one C(7) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(13,14) is bonded in a single-bond geometry to one C(10) atom. Linkers: 4 [N]/C=C\[C]CN1CCN(Cc2ccc(CN3CCN(Cc4ccncc4)CC3)cc2)CC1 ,6 c1cc(CN2CCN(Cc3ccc(CN4CCN(Cc5ccncc5)CC4)cc3)CC2)ccn1. Metal clusters: 8 [Ag]. The MOF has largest included sphere 4.84 A, density 1.18 g/cm3, surface area 4366.31 m2/g, accessible volume 0.45 cm3/g