CuH8(C2N)4C16H8S is Indium-derived structured and crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of sixteen C16H8S clusters and sixteen CuH8(C2N)4 clusters. In each C16H8S cluster, there are eight inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(2) bond length is 1.39 Å. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(6) bond length is 1.47 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.95 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-H(2) bond length is 0.95 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one C(3), one C(7), and one S(1) atom. The C(6)-C(7) bond length is 1.36 Å. The C(6)-S(1) bond length is 1.73 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(9)-C(8) bond length is 1.36 Å. The C(9)-H(5) bond length is 0.95 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(7), and one C(8) atom. The C(7)-C(7) bond length is 1.44 Å. The C(7)-C(8) bond length is 1.49 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(12)-C(8) bond length is 1.36 Å. The C(12)-H(8) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. There are four inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. S(1) is bonded in an L-shaped geometry to two equivalent C(6) atoms. In each CuH8(C2N)4 cluster, Cu(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Cu(1)-N(1) bond lengths are 2.05 Å. Both Cu(1)-N(2) bond lengths are 2.00 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(10)-N(2) bond length is 1.31 Å. The C(10)-H(6) bond length is 0.95 Å. In the fourth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(11)-N(2) bond length is 1.33 Å. The C(11)-H(7) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(11) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. Linkers: 16 c1cc(-c2sc(-c3ccncc3)c(-c3ccncc3)c2-c2ccncc2)ccn1. Metal clusters: 16 [Cu]. The MOF has largest included sphere 11.69 A, density 0.71 g/cm3, surface area 4806.56 m2/g, accessible volume 0.79 cm3/g