NaCo2C63H38(N2O9)2(CH)15 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixty 02329_fluka molecules and four NaCo2C63H38(N2O9)2 clusters. In each NaCo2C63H38(N2O9)2 cluster, Na(1) is bonded to one O(11), one O(14), one O(16), one O(17), one O(8), and one O(9) atom to form NaO6 octahedra that share  an edgeedge with one Co(2)N2O4 octahedra. The Na(1)-O(11) bond length is 2.25 Å. The Na(1)-O(14) bond length is 2.51 Å. The Na(1)-O(16) bond length is 2.37 Å. The Na(1)-O(17) bond length is 2.29 Å. The Na(1)-O(8) bond length is 2.30 Å. The Na(1)-O(9) bond length is 2.43 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 6-coordinate geometry to one N(3), one N(4), one O(16), one O(18), one O(7), and one O(8) atom. The Co(1)-N(3) bond length is 2.16 Å. The Co(1)-N(4) bond length is 2.10 Å. The Co(1)-O(16) bond length is 2.08 Å. The Co(1)-O(18) bond length is 2.00 Å. The Co(1)-O(7) bond length is 2.10 Å. The Co(1)-O(8) bond length is 2.38 Å. In the second Co site, Co(2) is bonded to one N(1), one N(2), one O(10), one O(14), one O(15), and one O(9) atom to form distorted CoN2O4 octahedra that share  an edgeedge with one Na(1)O6 octahedra. The Co(2)-N(1) bond length is 2.13 Å. The Co(2)-N(2) bond length is 2.12 Å. The Co(2)-O(10) bond length is 2.13 Å. The Co(2)-O(14) bond length is 2.05 Å. The Co(2)-O(15) bond length is 2.05 Å. The Co(2)-O(9) bond length is 2.26 Å. There are sixty-three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(7) bond length is 1.50 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(8) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(8) bond length is 1.51 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(9) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(9) bond length is 1.52 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(10), one C(3), and one C(5) atom. The C(4)-C(10) bond length is 1.51 Å. The C(4)-C(5) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(11), one C(4), and one C(6) atom. The C(5)-C(11) bond length is 1.51 Å. The C(5)-C(6) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(12), and one C(5) atom. The C(6)-C(12) bond length is 1.51 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(1); two equivalent H(1,2); and one O(6) atom. Both C(7)-H(1,2) bond lengths are 0.97 Å. The C(7)-O(6) bond length is 1.43 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(2); two equivalent H(3,4); and one O(1) atom. Both C(8)-H(3,4) bond lengths are 0.97 Å. The C(8)-O(1) bond length is 1.43 Å. In the ninth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(3); two equivalent H(5,6); and one O(2) atom. Both C(9)-H(5,6) bond lengths are 0.97 Å. The C(9)-O(2) bond length is 1.44 Å. In the tenth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(4); two equivalent H(7,8); and one O(3) atom. Both C(10)-H(7,8) bond lengths are 0.97 Å. The C(10)-O(3) bond length is 1.43 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one C(5); two equivalent H(9,10); and one O(4) atom. Both C(11)-H(9,10) bond lengths are 0.97 Å. The C(11)-O(4) bond length is 1.43 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(6); two equivalent H(11,12); and one O(5) atom. Both C(12)-H(11,12) bond lengths are 0.97 Å. The C(12)-O(5) bond length is 1.43 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one O(6) atom. The C(13)-O(6) bond length is 1.38 Å. In the fourteenth C site, C(16) is bonded in a single-bond geometry to one C(17) and one H(15) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-H(15) bond length is 0.93 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(19) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(19) bond length is 1.49 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(16,33) atom. The C(18)-H(16,33) bond length is 0.93 Å. In the seventeenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(15), and one O(16) atom. The C(19)-O(15) bond length is 1.27 Å. The C(19)-O(16) bond length is 1.25 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one O(1) atom. The C(20)-O(1) bond length is 1.37 Å. In the nineteenth C site, C(23) is bonded in a single-bond geometry to one C(24) and one H(19) atom. The C(23)-C(24) bond length is 1.36 Å. The C(23)-H(19) bond length is 0.93 Å. In the twentieth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(26) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-C(26) bond length is 1.50 Å. In the twenty-first C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(20) atom. The C(25)-H(20) bond length is 0.93 Å. In the twenty-second C site, C(27) is bonded in a single-bond geometry to one O(2) atom. The C(27)-O(2) bond length is 1.37 Å. In the twenty-third C site, C(26) is bonded in a bent 120 degrees geometry to one C(24), one O(7), and one O(8) atom. The C(26)-O(7) bond length is 1.26 Å. The C(26)-O(8) bond length is 1.23 Å. In the twenty-fourth C site, C(30) is bonded in a single-bond geometry to one C(31) and one H(23) atom. The C(30)-C(31) bond length is 1.37 Å. The C(30)-H(23) bond length is 0.93 Å. In the twenty-fifth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(54) atom. The C(31)-C(32) bond length is 1.38 Å. The C(31)-C(54) bond length is 1.51 Å. In the twenty-sixth C site, C(33) is bonded in a distorted single-bond geometry to one O(3) atom. The C(33)-O(3) bond length is 1.39 Å. In the twenty-seventh C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(24) atom. The C(32)-H(24) bond length is 0.93 Å. In the twenty-eighth C site, C(34) is bonded in a distorted single-bond geometry to one C(35) and one H(25) atom. The C(34)-C(35) bond length is 1.38 Å. The C(34)-H(25) bond length is 0.93 Å. In the twenty-ninth C site, C(35) is bonded in a trigonal planar geometry to one C(34), one C(36), and one C(39) atom. The C(35)-C(36) bond length is 1.37 Å. The C(35)-C(39) bond length is 1.52 Å. In the thirtieth C site, C(36) is bonded in a distorted single-bond geometry to one C(35) and one H(26) atom. The C(36)-H(26) bond length is 0.93 Å. In the thirty-first C site, C(39) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(17), and one O(18) atom. The C(39)-O(17) bond length is 1.22 Å. The C(39)-O(18) bond length is 1.26 Å. In the thirty-second C site, C(40) is bonded in a trigonal planar geometry to one C(41), one C(45), and one C(46) atom. The C(40)-C(41) bond length is 1.38 Å. The C(40)-C(45) bond length is 1.39 Å. The C(40)-C(46) bond length is 1.48 Å. In the thirty-third C site, C(41) is bonded in a distorted single-bond geometry to one C(40), one C(42), and one H(29) atom. The C(41)-C(42) bond length is 1.38 Å. The C(41)-H(29) bond length is 0.93 Å. In the thirty-fourth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(41), one C(43), and one O(5) atom. The C(42)-C(43) bond length is 1.38 Å. The C(42)-O(5) bond length is 1.37 Å. In the thirty-fifth C site, C(43) is bonded in a distorted single-bond geometry to one C(42) and one H(30) atom. The C(43)-H(30) bond length is 0.93 Å. In the thirty-sixth C site, C(45) is bonded in a distorted single-bond geometry to one C(40) and one H(32) atom. The C(45)-H(32) bond length is 0.93 Å. In the thirty-seventh C site, C(46) is bonded in a distorted bent 120 degrees geometry to one C(40), one O(11), and one O(12) atom. The C(46)-O(11) bond length is 1.21 Å. The C(46)-O(12) bond length is 1.30 Å. In the thirty-eighth C site, C(47) is bonded in a trigonal planar geometry to one C(48), one C(52), and one C(53) atom. The C(47)-C(48) bond length is 1.39 Å. The C(47)-C(52) bond length is 1.39 Å. The C(47)-C(53) bond length is 1.49 Å. In the thirty-ninth C site, C(48) is bonded in a single-bond geometry to one C(47) and one H(16,33) atom. The C(48)-H(16,33) bond length is 0.93 Å. In the fortieth C site, C(49) is bonded in a distorted single-bond geometry to one O(4) atom. The C(49)-O(4) bond length is 1.37 Å. In the forty-first C site, C(52) is bonded in a distorted single-bond geometry to one C(47) and one H(36) atom. The C(52)-H(36) bond length is 0.93 Å. In the forty-second C site, C(53) is bonded in a distorted bent 120 degrees geometry to one C(47), one O(10), and one O(9) atom. The C(53)-O(10) bond length is 1.27 Å. The C(53)-O(9) bond length is 1.27 Å. In the forty-third C site, C(54) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(13), and one O(14) atom. The C(54)-O(13) bond length is 1.26 Å. The C(54)-O(14) bond length is 1.25 Å. In the forty-fourth C site, C(55) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(37) atom. The C(55)-N(2) bond length is 1.33 Å. The C(55)-H(37) bond length is 0.93 Å. In the forty-fifth C site, C(57) is bonded in a distorted single-bond geometry to one C(58) and one H(39) atom. The C(57)-C(58) bond length is 1.41 Å. The C(57)-H(39) bond length is 0.93 Å. In the forty-sixth C site, C(58) is bonded in a trigonal planar geometry to one C(57), one C(59), and one C(63) atom. The C(58)-C(59) bond length is 1.40 Å. The C(58)-C(63) bond length is 1.43 Å. In the forty-seventh C site, C(59) is bonded in a distorted trigonal planar geometry to one C(58), one C(60), and one N(2) atom. The C(59)-C(60) bond length is 1.43 Å. The C(59)-N(2) bond length is 1.36 Å. In the forty-eighth C site, C(60) is bonded in a distorted trigonal planar geometry to one C(59), one C(61), and one N(1) atom. The C(60)-C(61) bond length is 1.41 Å. The C(60)-N(1) bond length is 1.35 Å. In the forty-ninth C site, C(61) is bonded in a trigonal planar geometry to one C(60), one C(62), and one C(64) atom. The C(61)-C(62) bond length is 1.42 Å. The C(61)-C(64) bond length is 1.41 Å. In the fiftieth C site, C(62) is bonded in a distorted single-bond geometry to one C(61) and one H(40) atom. The C(62)-H(40) bond length is 0.93 Å. In the fifty-first C site, C(63) is bonded in a distorted single-bond geometry to one C(58) and one H(41) atom. The C(63)-H(41) bond length is 0.93 Å. In the fifty-second C site, C(64) is bonded in a distorted single-bond geometry to one C(61) and one H(42) atom. The C(64)-H(42) bond length is 0.93 Å. In the fifty-third C site, C(66) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(44) atom. The C(66)-N(1) bond length is 1.33 Å. The C(66)-H(44) bond length is 0.93 Å. In the fifty-fourth C site, C(67) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(45) atom. The C(67)-N(3) bond length is 1.31 Å. The C(67)-H(45) bond length is 0.93 Å. In the fifty-fifth C site, C(69) is bonded in a distorted single-bond geometry to one C(70) and one H(47) atom. The C(69)-C(70) bond length is 1.38 Å. The C(69)-H(47) bond length is 0.93 Å. In the fifty-sixth C site, C(70) is bonded in a trigonal planar geometry to one C(69), one C(71), and one C(75) atom. The C(70)-C(71) bond length is 1.41 Å. The C(70)-C(75) bond length is 1.45 Å. In the fifty-seventh C site, C(71) is bonded in a distorted trigonal planar geometry to one C(70), one C(72), and one N(3) atom. The C(71)-C(72) bond length is 1.43 Å. The C(71)-N(3) bond length is 1.36 Å. In the fifty-eighth C site, C(72) is bonded in a distorted trigonal planar geometry to one C(71), one C(73), and one N(4) atom. The C(72)-C(73) bond length is 1.41 Å. The C(72)-N(4) bond length is 1.34 Å. In the fifty-ninth C site, C(73) is bonded in a trigonal planar geometry to one C(72), one C(74), and one C(78) atom. The C(73)-C(74) bond length is 1.42 Å. The C(73)-C(78) bond length is 1.38 Å. In the sixtieth C site, C(74) is bonded in a distorted single-bond geometry to one C(73) and one H(48) atom. The C(74)-H(48) bond length is 0.93 Å. In the sixty-first C site, C(75) is bonded in a distorted single-bond geometry to one C(70) and one H(49) atom. The C(75)-H(49) bond length is 0.93 Å. In the sixty-second C site, C(76) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(50) atom. The C(76)-N(4) bond length is 1.32 Å. The C(76)-H(50) bond length is 0.93 Å. In the sixty-third C site, C(78) is bonded in a distorted single-bond geometry to one C(73) and one H(52) atom. The C(78)-H(52) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(2), one C(60), and one C(66) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(2), one C(55), and one C(59) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(67), and one C(71) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(72), and one C(76) atom. There are thirty-one inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(16,33) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the eleventh H site, H(23) is bonded in a single-bond geometry to one C(30) atom. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(32) atom. In the thirteenth H site, H(25) is bonded in a single-bond geometry to one C(34) atom. In the fourteenth H site, H(26) is bonded in a single-bond geometry to one C(36) atom. In the fifteenth H site, H(29) is bonded in a single-bond geometry to one C(41) atom. In the sixteenth H site, H(30) is bonded in a single-bond geometry to one C(43) atom. In the seventeenth H site, H(32) is bonded in a single-bond geometry to one C(45) atom. In the eighteenth H site, H(36) is bonded in a single-bond geometry to one C(52) atom. In the nineteenth H site, H(37) is bonded in a single-bond geometry to one C(55) atom. In the twentieth H site, H(39) is bonded in a single-bond geometry to one C(57) atom. In the twenty-first H site, H(44) is bonded in a single-bond geometry to one C(66) atom. In the twenty-second H site, H(45) is bonded in a single-bond geometry to one C(67) atom. In the twenty-third H site, H(41) is bonded in a single-bond geometry to one C(63) atom. In the twenty-fourth H site, H(49) is bonded in a single-bond geometry to one C(75) atom. In the twenty-fifth H site, H(50) is bonded in a single-bond geometry to one C(76) atom. In the twenty-sixth H site, H(47) is bonded in a single-bond geometry to one C(69) atom. In the twenty-seventh H site, H(53) is bonded in a single-bond geometry to one O(12) atom. The H(53)-O(12) bond length is 0.82 Å. In the twenty-eighth H site, H(48) is bonded in a single-bond geometry to one C(74) atom. In the twenty-ninth H site, H(52) is bonded in a single-bond geometry to one C(78) atom. In the thirtieth H site, H(40) is bonded in a single-bond geometry to one C(62) atom. In the thirty-first H site, H(42) is bonded in a single-bond geometry to one C(64) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(20) and one C(8) atom. In the second O site, O(5) is bonded in a bent 120 degrees geometry to one C(12) and one C(42) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one C(11) and one C(49) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one C(27) and one C(9) atom. In the fifth O site, O(9) is bonded in a 3-coordinate geometry to one Na(1), one Co(2), and one C(53) atom. In the sixth O site, O(10) is bonded in an L-shaped geometry to one Co(2) and one C(53) atom. In the seventh O site, O(11) is bonded in a bent 150 degrees geometry to one Na(1) and one C(46) atom. In the eighth O site, O(12) is bonded in a water-like geometry to one C(46) and one H(53) atom. In the ninth O site, O(13) is bonded in a single-bond geometry to one C(54) atom. In the tenth O site, O(14) is bonded in a 3-coordinate geometry to one Na(1), one Co(2), and one C(54) atom. In the eleventh O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one C(39) atom. In the twelfth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(19) atom. In the thirteenth O site, O(16) is bonded in a 3-coordinate geometry to one Na(1), one Co(1), and one C(19) atom. In the fourteenth O site, O(3) is bonded in a bent 120 degrees geometry to one C(10) and one C(33) atom. In the fifteenth O site, O(6) is bonded in a bent 120 degrees geometry to one C(13) and one C(7) atom. In the sixteenth O site, O(7) is bonded in an L-shaped geometry to one Co(1) and one C(26) atom. In the seventeenth O site, O(8) is bonded in a distorted T-shaped geometry to one Na(1), one Co(1), and one C(26) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Co(1) and one C(39) atom. Linkers: 4 [O]C(=O)c1cccc(OCc2c(COc3cccc(C([O])=O)c3)c(COc3cccc(C([O])=O)c3)c(COc3cccc(C(=O)O)c3)c(COc3cccc(C([O])=O)c3)c2COc2cccc(C([O])=O)c2)c1 ,2 c1cnc2c(c1)ccc1cccnc12. Metal clusters: 4 O=[C]O[Co](O[C]O[Co]1(O[C]=O)O[C]O1)O[C]=O.O[C]O[Na]. RCSR code: sra. The MOF has largest included sphere 4.85 A, density 1.36 g/cm3, surface area 4572.03 m2/g, accessible volume 0.27 cm3/g