ZnGa7P8(O11F)3 crystallizes in the orthorhombic P2_12_12 space group. Zn(1) is bonded to one O(10), one O(24), one O(5), and one O(6) atom to form ZnO4 trigonal pyramids that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and corners with two equivalent P(2)O4 tetrahedra. The Zn(1)-O(10) bond length is 1.85 Å. The Zn(1)-O(24) bond length is 1.87 Å. The Zn(1)-O(5) bond length is 1.86 Å. The Zn(1)-O(6) bond length is 1.85 Å. There are seven inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(11), one O(12), one O(18), and one O(7) atom to form GaO4 tetrahedra that share  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The Ga(1)-O(11) bond length is 1.83 Å. The Ga(1)-O(12) bond length is 1.86 Å. The Ga(1)-O(18) bond length is 1.86 Å. The Ga(1)-O(7) bond length is 1.85 Å. In the second Ga site, Ga(2) is bonded to one O(1), one O(23), one O(30), one O(33), and one O(9) atom to form distorted GaO5 trigonal bipyramids that share  a cornercorner with one Ga(6)O5F octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles are 65°. The Ga(2)-O(1) bond length is 1.80 Å. The Ga(2)-O(23) bond length is 2.47 Å. The Ga(2)-O(30) bond length is 1.81 Å. The Ga(2)-O(33) bond length is 1.98 Å. The Ga(2)-O(9) bond length is 1.78 Å. In the third Ga site, Ga(3) is bonded to one O(15), one O(2), one O(21), one O(27), and one F(2) atom to form GaO4F trigonal bipyramids that share  a cornercorner with one Ga(7)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, and  a cornercorner with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. The Ga(3)-O(15) bond length is 1.93 Å. The Ga(3)-O(2) bond length is 1.84 Å. The Ga(3)-O(21) bond length is 1.86 Å. The Ga(3)-O(27) bond length is 1.86 Å. The Ga(3)-F(2) bond length is 2.05 Å. In the fourth Ga site, Ga(4) is bonded to one O(14), one O(19), one O(25), one O(8), and one F(3) atom to form GaO4F trigonal bipyramids that share  a cornercorner with one Ga(7)O4F2 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(7)O4 tetrahedra. The corner-sharing octahedral tilt angles are 62°. The Ga(4)-O(14) bond length is 1.83 Å. The Ga(4)-O(19) bond length is 2.01 Å. The Ga(4)-O(25) bond length is 1.85 Å. The Ga(4)-O(8) bond length is 1.85 Å. The Ga(4)-F(3) bond length is 2.04 Å. In the fifth Ga site, Ga(5) is bonded to one O(16), one O(20), one O(3), one O(31), and one F(1) atom to form GaO4F trigonal bipyramids that share  a cornercorner with one Ga(6)O5F octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and  a cornercorner with one P(8)O4 tetrahedra. The corner-sharing octahedral tilt angles are 50°. The Ga(5)-O(16) bond length is 1.84 Å. The Ga(5)-O(20) bond length is 1.86 Å. The Ga(5)-O(3) bond length is 1.91 Å. The Ga(5)-O(31) bond length is 1.86 Å. The Ga(5)-F(1) bond length is 2.05 Å. In the sixth Ga site, Ga(6) is bonded to one O(17), one O(28), one O(32), one O(33), one O(4), and one F(1) atom to form GaO5F octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  a cornercorner with one Ga(5)O4F trigonal bipyramid, and  a cornercorner with one Ga(2)O5 trigonal bipyramid. The Ga(6)-O(17) bond length is 1.96 Å. The Ga(6)-O(28) bond length is 1.90 Å. The Ga(6)-O(32) bond length is 1.94 Å. The Ga(6)-O(33) bond length is 2.02 Å. The Ga(6)-O(4) bond length is 1.93 Å. The Ga(6)-F(1) bond length is 1.96 Å. In the seventh Ga site, Ga(7) is bonded to one O(13), one O(22), one O(26), one O(29), one F(2), and one F(3) atom to form GaO4F2 octahedra that share  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  a cornercorner with one Ga(3)O4F trigonal bipyramid, and  a cornercorner with one Ga(4)O4F trigonal bipyramid. The Ga(7)-O(13) bond length is 1.94 Å. The Ga(7)-O(22) bond length is 1.96 Å. The Ga(7)-O(26) bond length is 1.94 Å. The Ga(7)-O(29) bond length is 1.93 Å. The Ga(7)-F(2) bond length is 1.96 Å. The Ga(7)-F(3) bond length is 2.01 Å. There are eight inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(6)O5F octahedra,  a cornercorner with one Ga(3)O4F trigonal bipyramid,  a cornercorner with one Ga(5)O4F trigonal bipyramid, and  a cornercorner with one Ga(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 46°. The P(1)-O(1) bond length is 1.55 Å. The P(1)-O(2) bond length is 1.55 Å. The P(1)-O(3) bond length is 1.52 Å. The P(1)-O(4) bond length is 1.52 Å. In the second P site, P(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4 tetrahedra,  a cornercorner with one Ga(4)O4F trigonal bipyramid, and corners with two equivalent Zn(1)O4 trigonal pyramids. The P(2)-O(5) bond length is 1.54 Å. The P(2)-O(6) bond length is 1.53 Å. The P(2)-O(7) bond length is 1.53 Å. The P(2)-O(8) bond length is 1.50 Å. In the third P site, P(3) is bonded to one O(10), one O(11), one O(12), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Ga(1)O4 tetrahedra,  a cornercorner with one Ga(2)O5 trigonal bipyramid, and  a cornercorner with one Zn(1)O4 trigonal pyramid. The P(3)-O(10) bond length is 1.54 Å. The P(3)-O(11) bond length is 1.54 Å. The P(3)-O(12) bond length is 1.53 Å. The P(3)-O(9) bond length is 1.51 Å. In the fourth P site, P(4) is bonded to one O(13), one O(14), one O(15), and one O(16) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(7)O4F2 octahedra,  a cornercorner with one Ga(3)O4F trigonal bipyramid,  a cornercorner with one Ga(4)O4F trigonal bipyramid, and  a cornercorner with one Ga(5)O4F trigonal bipyramid. The corner-sharing octahedral tilt angles are 47°. The P(4)-O(13) bond length is 1.51 Å. The P(4)-O(14) bond length is 1.54 Å. The P(4)-O(15) bond length is 1.52 Å. The P(4)-O(16) bond length is 1.56 Å. In the fifth P site, P(5) is bonded to one O(17), one O(18), one O(19), and one O(20) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(6)O5F octahedra,  a cornercorner with one Ga(1)O4 tetrahedra,  a cornercorner with one Ga(4)O4F trigonal bipyramid, and  a cornercorner with one Ga(5)O4F trigonal bipyramid. The corner-sharing octahedral tilt angles are 47°. The P(5)-O(17) bond length is 1.51 Å. The P(5)-O(18) bond length is 1.53 Å. The P(5)-O(19) bond length is 1.53 Å. The P(5)-O(20) bond length is 1.55 Å. In the sixth P site, P(6) is bonded to one O(21), one O(22), one O(23), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(7)O4F2 octahedra,  a cornercorner with one Ga(3)O4F trigonal bipyramid,  a cornercorner with one Ga(2)O5 trigonal bipyramid, and  a cornercorner with one Zn(1)O4 trigonal pyramid. The corner-sharing octahedral tilt angles are 47°. The P(6)-O(21) bond length is 1.55 Å. The P(6)-O(22) bond length is 1.51 Å. The P(6)-O(23) bond length is 1.54 Å. The P(6)-O(24) bond length is 1.52 Å. In the seventh P site, P(7) is bonded to one O(25), one O(26), one O(27), and one O(28) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(7)O4F2 octahedra,  a cornercorner with one Ga(6)O5F octahedra,  a cornercorner with one Ga(3)O4F trigonal bipyramid, and  a cornercorner with one Ga(4)O4F trigonal bipyramid. The corner-sharing octahedral tilt angles are 49°. The P(7)-O(25) bond length is 1.53 Å. The P(7)-O(26) bond length is 1.53 Å. The P(7)-O(27) bond length is 1.53 Å. The P(7)-O(28) bond length is 1.53 Å. In the eighth P site, P(8) is bonded to one O(29), one O(30), one O(31), and one O(32) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(7)O4F2 octahedra,  a cornercorner with one Ga(6)O5F octahedra,  a cornercorner with one Ga(5)O4F trigonal bipyramid, and  a cornercorner with one Ga(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles range from 46-49°. The P(8)-O(29) bond length is 1.52 Å. The P(8)-O(30) bond length is 1.53 Å. The P(8)-O(31) bond length is 1.53 Å. The P(8)-O(32) bond length is 1.51 Å. There are thirty-three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Ga(2) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ga(3) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ga(5) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ga(6) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Ga(1) and one P(2) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Ga(4) and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Ga(2) and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(3) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Ga(1) and one P(3) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Ga(1) and one P(3) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Ga(7) and one P(4) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Ga(4) and one P(4) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Ga(3) and one P(4) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Ga(5) and one P(4) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Ga(6) and one P(5) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one Ga(1) and one P(5) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Ga(4) and one P(5) atom. In the twentieth O site, O(20) is bonded in a distorted bent 150 degrees geometry to one Ga(5) and one P(5) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one Ga(3) and one P(6) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Ga(7) and one P(6) atom. In the twenty-third O site, O(23) is bonded in a distorted single-bond geometry to one Ga(2) and one P(6) atom. In the twenty-fourth O site, O(24) is bonded in a bent 150 degrees geometry to one Zn(1) and one P(6) atom. In the twenty-fifth O site, O(25) is bonded in a bent 120 degrees geometry to one Ga(4) and one P(7) atom. In the twenty-sixth O site, O(26) is bonded in a bent 120 degrees geometry to one Ga(7) and one P(7) atom. In the twenty-seventh O site, O(27) is bonded in a bent 120 degrees geometry to one Ga(3) and one P(7) atom. In the twenty-eighth O site, O(28) is bonded in a bent 120 degrees geometry to one Ga(6) and one P(7) atom. In the twenty-ninth O site, O(29) is bonded in a bent 120 degrees geometry to one Ga(7) and one P(8) atom. In the thirtieth O site, O(30) is bonded in a bent 120 degrees geometry to one Ga(2) and one P(8) atom. In the thirty-first O site, O(31) is bonded in a bent 120 degrees geometry to one Ga(5) and one P(8) atom. In the thirty-second O site, O(32) is bonded in a distorted bent 120 degrees geometry to one Ga(6) and one P(8) atom. In the thirty-third O site, O(33) is bonded in a bent 120 degrees geometry to one Ga(2) and one Ga(6) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Ga(5) and one Ga(6) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Ga(3) and one Ga(7) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Ga(4) and one Ga(7) atom. Linkers: 32 [O]P([O])([O])=O. Metal clusters: 4 [Zn] ,28 [Ga]. The MOF has largest included sphere 8.64 A, density 1.96 g/cm3, surface area 2021.54 m2/g, accessible volume 0.22 cm3/g