Zn3C46H28(NO6)2(C3H2)6(CH)2C13NH8C15NH10 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules; twenty-four 2,3-dimethyl-1,3-butadiene molecules; eight C13NH8 clusters; eight C15NH10 clusters; and eight Zn3C46H28(NO6)2 clusters. In each C13NH8 cluster, there are thirteen inequivalent C sites. In the first C site, C(10) is bonded in a distorted trigonal planar geometry to one C(25), one C(35), and one N(2) atom. The C(10)-C(25) bond length is 1.36 Å. The C(10)-C(35) bond length is 1.36 Å. The C(10)-N(2) bond length is 1.43 Å. In the second C site, C(18) is bonded in a distorted single-bond geometry to one N(2) atom. The C(18)-N(2) bond length is 1.36 Å. In the third C site, C(25) is bonded in a distorted single-bond geometry to one C(10) and one H(12) atom. The C(25)-H(12) bond length is 0.93 Å. In the fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(51) and one H(13) atom. The C(26)-C(51) bond length is 1.40 Å. The C(26)-H(13) bond length is 0.93 Å. In the fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(10) and one H(21) atom. The C(35)-H(21) bond length is 0.93 Å. In the sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(45) and one H(22) atom. The C(36)-C(45) bond length is 1.41 Å. The C(36)-H(22) bond length is 0.93 Å. In the seventh C site, C(39) is bonded in a distorted single-bond geometry to one C(45), one C(48), and one H(25) atom. The C(39)-C(45) bond length is 1.38 Å. The C(39)-C(48) bond length is 1.33 Å. The C(39)-H(25) bond length is 0.93 Å. In the eighth C site, C(43) is bonded in a trigonal planar geometry to one C(46), one C(48), and one C(51) atom. The C(43)-C(46) bond length is 1.36 Å. The C(43)-C(48) bond length is 1.40 Å. The C(43)-C(51) bond length is 1.43 Å. In the ninth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(36), one C(39), and one N(2) atom. The C(45)-N(2) bond length is 1.41 Å. In the tenth C site, C(46) is bonded in a distorted single-bond geometry to one C(43) and one H(28) atom. The C(46)-H(28) bond length is 0.93 Å. In the eleventh C site, C(48) is bonded in a distorted trigonal planar geometry to one C(39), one C(43), and one H(30) atom. The C(48)-H(30) bond length is 0.93 Å. In the twelfth C site, C(51) is bonded in a trigonal planar geometry to one C(26), one C(43), and one C(52) atom. The C(51)-C(52) bond length is 1.40 Å. In the thirteenth C site, C(52) is bonded in a distorted single-bond geometry to one C(51) and one H(33) atom. The C(52)-H(33) bond length is 0.93 Å. N(2) is bonded in a trigonal planar geometry to one C(10), one C(18), and one C(45) atom. There are eight inequivalent H sites. In the first H site, H(12) is bonded in a single-bond geometry to one C(25) atom. In the second H site, H(13) is bonded in a single-bond geometry to one C(26) atom. In the third H site, H(21) is bonded in a single-bond geometry to one C(35) atom. In the fourth H site, H(22) is bonded in a single-bond geometry to one C(36) atom. In the fifth H site, H(25) is bonded in a single-bond geometry to one C(39) atom. In the sixth H site, H(28) is bonded in a single-bond geometry to one C(46) atom. In the seventh H site, H(30) is bonded in a single-bond geometry to one C(48) atom. In the eighth H site, H(33) is bonded in a single-bond geometry to one C(52) atom. In each C15NH10 cluster, there are fifteen inequivalent C sites. In the first C site, C(69) is bonded in a single-bond geometry to one C(84) and one H(45) atom. The C(69)-C(84) bond length is 1.43 Å. The C(69)-H(45) bond length is 0.93 Å. In the second C site, C(70) is bonded in a trigonal planar geometry to one C(71), one C(80), and one C(90) atom. The C(70)-C(71) bond length is 1.55 Å. The C(70)-C(80) bond length is 1.38 Å. The C(70)-C(90) bond length is 1.37 Å. In the third C site, C(71) is bonded in a trigonal planar geometry to one C(70), one C(77), and one C(78) atom. The C(71)-C(77) bond length is 1.42 Å. The C(71)-C(78) bond length is 1.38 Å. In the fourth C site, C(72) is bonded in a distorted single-bond geometry to one C(83) and one H(46) atom. The C(72)-C(83) bond length is 1.35 Å. The C(72)-H(46) bond length is 0.93 Å. In the fifth C site, C(78) is bonded in a distorted single-bond geometry to one C(71) and one H(49) atom. The C(78)-H(49) bond length is 0.93 Å. In the sixth C site, C(80) is bonded in a distorted trigonal planar geometry to one C(70), one C(86), and one H(51) atom. The C(80)-C(86) bond length is 1.35 Å. The C(80)-H(51) bond length is 0.93 Å. In the seventh C site, C(77) is bonded in a distorted single-bond geometry to one C(71) and one H(48) atom. The C(77)-H(48) bond length is 0.93 Å. In the eighth C site, C(82) is bonded in a distorted trigonal planar geometry to one C(85), one C(86), and one N(4) atom. The C(82)-C(85) bond length is 1.34 Å. The C(82)-C(86) bond length is 1.40 Å. The C(82)-N(4) bond length is 1.42 Å. In the ninth C site, C(83) is bonded in a distorted trigonal planar geometry to one C(72), one C(89), and one N(4) atom. The C(83)-C(89) bond length is 1.37 Å. The C(83)-N(4) bond length is 1.44 Å. In the tenth C site, C(84) is bonded in a distorted trigonal planar geometry to one C(69), one C(91), and one N(4) atom. The C(84)-C(91) bond length is 1.41 Å. The C(84)-N(4) bond length is 1.42 Å. In the eleventh C site, C(85) is bonded in a distorted single-bond geometry to one C(82) and one H(53) atom. The C(85)-H(53) bond length is 0.93 Å. In the twelfth C site, C(86) is bonded in a distorted single-bond geometry to one C(80), one C(82), and one H(54) atom. The C(86)-H(54) bond length is 0.93 Å. In the thirteenth C site, C(89) is bonded in a distorted single-bond geometry to one C(83) and one H(57) atom. The C(89)-H(57) bond length is 0.93 Å. In the fourteenth C site, C(91) is bonded in a distorted single-bond geometry to one C(84) and one H(59) atom. The C(91)-H(59) bond length is 0.93 Å. In the fifteenth C site, C(90) is bonded in a distorted single-bond geometry to one C(70) and one H(58) atom. The C(90)-H(58) bond length is 0.93 Å. N(4) is bonded in a trigonal planar geometry to one C(82), one C(83), and one C(84) atom. There are ten inequivalent H sites. In the first H site, H(45) is bonded in a single-bond geometry to one C(69) atom. In the second H site, H(46) is bonded in a single-bond geometry to one C(72) atom. In the third H site, H(53) is bonded in a single-bond geometry to one C(85) atom. In the fourth H site, H(54) is bonded in a single-bond geometry to one C(86) atom. In the fifth H site, H(57) is bonded in a single-bond geometry to one C(89) atom. In the sixth H site, H(59) is bonded in a single-bond geometry to one C(91) atom. In the seventh H site, H(58) is bonded in a single-bond geometry to one C(90) atom. In the eighth H site, H(48) is bonded in a single-bond geometry to one C(77) atom. In the ninth H site, H(49) is bonded in a single-bond geometry to one C(78) atom. In the tenth H site, H(51) is bonded in a single-bond geometry to one C(80) atom. In each Zn3C46H28(NO6)2 cluster, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 4-coordinate geometry to one N(3), one O(1), one O(2), and one O(6) atom. The Zn(1)-N(3) bond length is 2.09 Å. The Zn(1)-O(1) bond length is 1.95 Å. The Zn(1)-O(2) bond length is 1.93 Å. The Zn(1)-O(6) bond length is 1.99 Å. In the second Zn site, Zn(2) is bonded in a trigonal pyramidal geometry to one N(1), one O(11), one O(7), and one O(9) atom. The Zn(2)-N(1) bond length is 1.94 Å. The Zn(2)-O(11) bond length is 1.93 Å. The Zn(2)-O(7) bond length is 1.86 Å. The Zn(2)-O(9) bond length is 1.94 Å. In the third Zn site, Zn(3) is bonded in a square pyramidal geometry to one O(10), one O(12), one O(4), one O(5), and one O(8) atom. The Zn(3)-O(10) bond length is 2.12 Å. The Zn(3)-O(12) bond length is 2.22 Å. The Zn(3)-O(4) bond length is 2.09 Å. The Zn(3)-O(5) bond length is 2.12 Å. The Zn(3)-O(8) bond length is 2.05 Å. There are forty-six inequivalent C sites. In the first C site, C(11) is bonded in a trigonal planar geometry to one C(23), one C(40), and one C(5) atom. The C(11)-C(23) bond length is 1.59 Å. The C(11)-C(40) bond length is 1.31 Å. The C(11)-C(5) bond length is 1.34 Å. In the second C site, C(12) is bonded in a trigonal planar geometry to one C(16), one C(17), and one C(38) atom. The C(12)-C(16) bond length is 1.44 Å. The C(12)-C(17) bond length is 1.37 Å. The C(12)-C(38) bond length is 1.42 Å. In the third C site, C(14) is bonded in a single-bond geometry to one C(22), one C(23), and one H(6) atom. The C(14)-C(22) bond length is 1.35 Å. The C(14)-C(23) bond length is 1.34 Å. The C(14)-H(6) bond length is 0.93 Å. In the fourth C site, C(13) is bonded in a trigonal planar geometry to one C(19), one C(41), and one C(6) atom. The C(13)-C(19) bond length is 1.39 Å. The C(13)-C(41) bond length is 1.61 Å. The C(13)-C(6) bond length is 1.30 Å. In the fifth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(3) atom. The C(16)-O(1) bond length is 1.26 Å. The C(16)-O(3) bond length is 1.31 Å. In the sixth C site, C(17) is bonded in a distorted single-bond geometry to one C(12) and one H(8) atom. The C(17)-H(8) bond length is 0.93 Å. In the seventh C site, C(19) is bonded in a single-bond geometry to one C(13) and one H(9) atom. The C(19)-H(9) bond length is 0.93 Å. In the eighth C site, C(22) is bonded in a 3-coordinate geometry to one C(14), one N(3), and one H(11) atom. The C(22)-N(3) bond length is 1.39 Å. The C(22)-H(11) bond length is 0.93 Å. In the ninth C site, C(23) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(54) atom. The C(23)-C(54) bond length is 1.35 Å. In the tenth C site, C(27) is bonded in a distorted single-bond geometry to one C(4) and one H(14) atom. The C(27)-C(4) bond length is 1.48 Å. The C(27)-H(14) bond length is 0.93 Å. In the eleventh C site, C(34) is bonded in a distorted single-bond geometry to one C(7) and one H(20) atom. The C(34)-C(7) bond length is 1.47 Å. The C(34)-H(20) bond length is 0.93 Å. In the twelfth C site, C(33) is bonded in a distorted single-bond geometry to one C(1), one C(2), and one H(19) atom. The C(33)-C(1) bond length is 1.39 Å. The C(33)-C(2) bond length is 1.47 Å. The C(33)-H(19) bond length is 0.93 Å. In the thirteenth C site, C(40) is bonded in a distorted single-bond geometry to one C(11) and one H(26) atom. The C(40)-H(26) bond length is 0.93 Å. In the fourteenth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(4), and one O(6) atom. The C(42)-C(7) bond length is 1.51 Å. The C(42)-O(4) bond length is 1.18 Å. The C(42)-O(6) bond length is 1.33 Å. In the fifteenth C site, C(38) is bonded in a distorted single-bond geometry to one C(12) and one H(24) atom. The C(38)-H(24) bond length is 0.93 Å. In the sixteenth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(2), and one O(5) atom. The C(41)-O(2) bond length is 1.21 Å. The C(41)-O(5) bond length is 1.26 Å. In the seventeenth C site, C(49) is bonded in a distorted single-bond geometry to one C(7) and one H(31) atom. The C(49)-C(7) bond length is 1.29 Å. The C(49)-H(31) bond length is 0.93 Å. In the eighteenth C site, C(50) is bonded in a single-bond geometry to one C(4) and one H(32) atom. The C(50)-C(4) bond length is 1.33 Å. The C(50)-H(32) bond length is 0.93 Å. In the nineteenth C site, C(53) is bonded in a distorted single-bond geometry to one C(2) and one H(34) atom. The C(53)-C(2) bond length is 1.32 Å. The C(53)-H(34) bond length is 0.93 Å. In the twentieth C site, C(54) is bonded in a distorted single-bond geometry to one C(23) and one H(35) atom. The C(54)-H(35) bond length is 0.93 Å. In the twenty-first C site, C(55) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(36) atom. The C(55)-N(3) bond length is 1.30 Å. The C(55)-H(36) bond length is 0.93 Å. In the twenty-second C site, C(56) is bonded in a trigonal planar geometry to one C(57), one C(64), and one C(94) atom. The C(56)-C(57) bond length is 1.33 Å. The C(56)-C(64) bond length is 1.27 Å. The C(56)-C(94) bond length is 1.56 Å. In the twenty-third C site, C(57) is bonded in a distorted trigonal planar geometry to one C(56), one C(65), and one H(37) atom. The C(57)-C(65) bond length is 1.41 Å. The C(57)-H(37) bond length is 0.93 Å. In the twenty-fourth C site, C(58) is bonded in a distorted single-bond geometry to one C(59) and one H(38) atom. The C(58)-C(59) bond length is 1.39 Å. The C(58)-H(38) bond length is 0.93 Å. In the twenty-fifth C site, C(59) is bonded in a trigonal planar geometry to one C(58), one C(63), and one C(92) atom. The C(59)-C(63) bond length is 1.32 Å. The C(59)-C(92) bond length is 1.56 Å. In the twenty-sixth C site, C(62) is bonded in a distorted trigonal planar geometry to one C(64), one C(67), and one H(41) atom. The C(62)-C(64) bond length is 1.37 Å. The C(62)-C(67) bond length is 1.42 Å. The C(62)-H(41) bond length is 0.93 Å. In the twenty-seventh C site, C(63) is bonded in a distorted single-bond geometry to one C(59) and one H(42) atom. The C(63)-H(42) bond length is 0.93 Å. In the twenty-eighth C site, C(64) is bonded in a distorted single-bond geometry to one C(56), one C(62), and one H(43) atom. The C(64)-H(43) bond length is 0.93 Å. In the twenty-ninth C site, C(65) is bonded in a distorted single-bond geometry to one C(57), one C(67), and one H(44) atom. The C(65)-C(67) bond length is 1.40 Å. The C(65)-H(44) bond length is 0.93 Å. In the thirtieth C site, C(67) is bonded in a trigonal planar geometry to one C(62), one C(65), and one C(75) atom. The C(67)-C(75) bond length is 1.49 Å. In the thirty-first C site, C(73) is bonded in a trigonal planar geometry to one C(74), one C(76), and one C(81) atom. The C(73)-C(74) bond length is 1.60 Å. The C(73)-C(76) bond length is 1.31 Å. The C(73)-C(81) bond length is 1.38 Å. In the thirty-second C site, C(74) is bonded in a distorted bent 120 degrees geometry to one C(73), one O(12), and one O(9) atom. The C(74)-O(12) bond length is 1.31 Å. The C(74)-O(9) bond length is 1.18 Å. In the thirty-third C site, C(76) is bonded in a distorted single-bond geometry to one C(73) and one H(47) atom. The C(76)-H(47) bond length is 0.93 Å. In the thirty-fourth C site, C(75) is bonded in a trigonal planar geometry to one C(67), one C(87), and one C(93) atom. The C(75)-C(87) bond length is 1.45 Å. The C(75)-C(93) bond length is 1.36 Å. In the thirty-fifth C site, C(81) is bonded in a distorted single-bond geometry to one C(73) and one H(52) atom. The C(81)-H(52) bond length is 0.93 Å. In the thirty-sixth C site, C(87) is bonded in a distorted single-bond geometry to one C(75) and one H(55) atom. The C(87)-H(55) bond length is 0.93 Å. In the thirty-seventh C site, C(92) is bonded in a distorted bent 120 degrees geometry to one C(59), one O(7), and one O(8) atom. The C(92)-O(7) bond length is 1.33 Å. The C(92)-O(8) bond length is 1.20 Å. In the thirty-eighth C site, C(93) is bonded in a distorted single-bond geometry to one C(75) and one H(60) atom. The C(93)-H(60) bond length is 0.93 Å. In the thirty-ninth C site, C(94) is bonded in a distorted bent 120 degrees geometry to one C(56), one O(10), and one O(11) atom. The C(94)-O(10) bond length is 1.15 Å. The C(94)-O(11) bond length is 1.29 Å. In the fortieth C site, C(1) is bonded in a 2-coordinate geometry to one C(33), one N(1), and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the forty-first C site, C(2) is bonded in a trigonal planar geometry to one C(33), one C(4), and one C(53) atom. The C(2)-C(4) bond length is 1.51 Å. In the forty-second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(3)-N(1) bond length is 1.38 Å. The C(3)-H(2) bond length is 0.93 Å. In the forty-third C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(27), and one C(50) atom. In the forty-fourth C site, C(5) is bonded in a single-bond geometry to one C(11) and one H(3) atom. The C(5)-H(3) bond length is 0.93 Å. In the forty-fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(13) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the forty-sixth C site, C(7) is bonded in a trigonal planar geometry to one C(34), one C(42), and one C(49) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(1), and one C(3) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(22), and one C(55) atom. There are twenty-eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(33) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(34) atom. In the twelfth H site, H(26) is bonded in a single-bond geometry to one C(40) atom. In the thirteenth H site, H(24) is bonded in a single-bond geometry to one C(38) atom. In the fourteenth H site, H(31) is bonded in a single-bond geometry to one C(49) atom. In the fifteenth H site, H(36) is bonded in a single-bond geometry to one C(55) atom. In the sixteenth H site, H(37) is bonded in a single-bond geometry to one C(57) atom. In the seventeenth H site, H(38) is bonded in a single-bond geometry to one C(58) atom. In the eighteenth H site, H(35) is bonded in a single-bond geometry to one C(54) atom. In the nineteenth H site, H(32) is bonded in a single-bond geometry to one C(50) atom. In the twentieth H site, H(34) is bonded in a single-bond geometry to one C(53) atom. In the twenty-first H site, H(41) is bonded in a single-bond geometry to one C(62) atom. In the twenty-second H site, H(43) is bonded in a single-bond geometry to one C(64) atom. In the twenty-third H site, H(44) is bonded in a single-bond geometry to one C(65) atom. In the twenty-fourth H site, H(42) is bonded in a single-bond geometry to one C(63) atom. In the twenty-fifth H site, H(47) is bonded in a single-bond geometry to one C(76) atom. In the twenty-sixth H site, H(52) is bonded in a single-bond geometry to one C(81) atom. In the twenty-seventh H site, H(55) is bonded in a single-bond geometry to one C(87) atom. In the twenty-eighth H site, H(60) is bonded in a single-bond geometry to one C(93) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(16) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(41) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one C(16) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(42) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Zn(3) and one C(41) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Zn(1) and one C(42) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(92) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Zn(3) and one C(92) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Zn(2) and one C(74) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Zn(3) and one C(94) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(94) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Zn(3) and one C(74) atom. Linkers: 16 [O]C(=O)c1ccc(-c2ccc(N(c3ccc(-c4ccc(C([O])=O)cc4)cc3)c3ccc(-c4ccc(C([O])=O)cc4)cc3)cc2)cc1 ,8 c1cc(-c2ccc(-c3ccncc3)cc2)ccn1. Metal clusters: 8 [O][C]O[Zn]1O[C]O[Zn]23(O[C]O1)O[C]O[Zn](O[C]O2)O[C]O3. The MOF has largest included sphere 12.12 A, density 0.62 g/cm3, surface area 4812.06 m2/g, accessible volume 1.16 cm3/g