(NiC17H11(NO3)2)2NiC20H14(NO2)2(CH)22(C4H3)4(C5H5O)12(H3(C2O)2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty-two 02329_fluka molecules, four isobutylene molecules, four methacrylic acid molecules, four schembl9685153 molecules, two NiC17H11(NO3)2 clusters, and one NiC20H14(NO2)2 cluster. In each NiC17H11(NO3)2 cluster, Ni(1) is bonded in a square pyramidal geometry to one N(2), one N(3), one O(2), one O(3), and one O(4) atom. The Ni(1)-N(2) bond length is 2.09 Å. The Ni(1)-N(3) bond length is 2.09 Å. The Ni(1)-O(2) bond length is 2.03 Å. The Ni(1)-O(3) bond length is 2.12 Å. The Ni(1)-O(4) bond length is 2.09 Å. There are seventeen inequivalent C sites. In the first C site, C(7) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(9) atom. The C(7)-C(15) bond length is 1.40 Å. The C(7)-C(17) bond length is 1.36 Å. The C(7)-C(9) bond length is 1.50 Å. In the second C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(2), and one O(9) atom. The C(9)-O(2) bond length is 1.27 Å. The C(9)-O(9) bond length is 1.25 Å. In the third C site, C(11) is bonded in a bent 120 degrees geometry to one C(36), one O(3), and one O(6) atom. The C(11)-C(36) bond length is 1.47 Å. The C(11)-O(3) bond length is 1.23 Å. The C(11)-O(6) bond length is 1.33 Å. In the fourth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5) atom. The C(13)-N(2) bond length is 1.32 Å. The C(13)-H(5) bond length is 0.93 Å. In the fifth C site, C(17) is bonded in a distorted single-bond geometry to one C(7) and one H(8) atom. The C(17)-H(8) bond length is 0.93 Å. In the sixth C site, C(14) is bonded in a trigonal planar geometry to one C(24), one C(25), and one C(54) atom. The C(14)-C(24) bond length is 1.36 Å. The C(14)-C(25) bond length is 1.49 Å. The C(14)-C(54) bond length is 1.36 Å. In the seventh C site, C(15) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(15)-H(6) bond length is 0.93 Å. In the eighth C site, C(24) is bonded in a distorted single-bond geometry to one C(14) and one H(13) atom. The C(24)-H(13) bond length is 0.93 Å. In the ninth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(12), and one O(4) atom. The C(25)-O(12) bond length is 1.24 Å. The C(25)-O(4) bond length is 1.25 Å. In the tenth C site, C(36) is bonded in a trigonal planar geometry to one C(11), one C(43), and one C(56) atom. The C(36)-C(43) bond length is 1.40 Å. The C(36)-C(56) bond length is 1.38 Å. In the eleventh C site, C(39) is bonded in a distorted single-bond geometry to one C(43) and one H(26) atom. The C(39)-C(43) bond length is 1.41 Å. The C(39)-H(26) bond length is 0.93 Å. In the twelfth C site, C(44) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(28) atom. The C(44)-N(2) bond length is 1.32 Å. The C(44)-H(28) bond length is 0.93 Å. In the thirteenth C site, C(43) is bonded in a distorted trigonal planar geometry to one C(36), one C(39), and one H(27) atom. The C(43)-H(27) bond length is 0.93 Å. In the fourteenth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(29) atom. The C(46)-N(3) bond length is 1.33 Å. The C(46)-H(29) bond length is 0.93 Å. In the fifteenth C site, C(54) is bonded in a distorted single-bond geometry to one C(14) and one H(36) atom. The C(54)-H(36) bond length is 0.93 Å. In the sixteenth C site, C(56) is bonded in a single-bond geometry to one C(36) and one H(40) atom. The C(56)-H(40) bond length is 0.93 Å. In the seventeenth C site, C(63) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(47) atom. The C(63)-N(3) bond length is 1.34 Å. The C(63)-H(47) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Ni(1), one C(13), and one C(44) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Ni(1), one C(46), and one C(63) atom. There are eleven inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(15) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(24) atom. In the fifth H site, H(26) is bonded in a single-bond geometry to one C(39) atom. In the sixth H site, H(28) is bonded in a single-bond geometry to one C(44) atom. In the seventh H site, H(29) is bonded in a single-bond geometry to one C(46) atom. In the eighth H site, H(27) is bonded in a single-bond geometry to one C(43) atom. In the ninth H site, H(36) is bonded in a single-bond geometry to one C(54) atom. In the tenth H site, H(40) is bonded in a single-bond geometry to one C(56) atom. In the eleventh H site, H(47) is bonded in a single-bond geometry to one C(63) atom. There are six inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(9) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(11) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(25) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(11) atom. In the fifth O site, O(9) is bonded in a single-bond geometry to one C(9) atom. In the sixth O site, O(12) is bonded in a single-bond geometry to one C(25) atom. In the NiC20H14(NO2)2 cluster, Ni(2) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Ni(2)-N(1) bond lengths are 2.15 Å. Both Ni(2)-O(1) bond lengths are 2.07 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(6) atom. The C(2)-C(10) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.51 Å. The C(2)-C(6) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(27), one N(1), and one H(2) atom. The C(3)-C(27) bond length is 1.37 Å. The C(3)-N(1) bond length is 1.33 Å. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(7) atom. The C(4)-O(1) bond length is 1.23 Å. The C(4)-O(7) bond length is 1.29 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(16), one C(19), and one C(27) atom. The C(5)-C(16) bond length is 1.46 Å. The C(5)-C(19) bond length is 1.39 Å. The C(5)-C(27) bond length is 1.41 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(10)-H(4) bond length is 0.93 Å. In the eighth C site, C(16) is bonded in a distorted single-bond geometry to one C(5) and one H(7) atom. The C(16)-H(7) bond length is 0.93 Å. In the ninth C site, C(19) is bonded in a distorted single-bond geometry to one C(5) and one H(10) atom. The C(19)-H(10) bond length is 0.93 Å. In the tenth C site, C(27) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(16) atom. The C(27)-H(16) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Ni(2), one C(1), and one C(3) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(27) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ni(2) and one C(4) atom. In the second O site, O(7) is bonded in a single-bond geometry to one C(4) atom. Linkers: 1 [CH2][O].[CH2][O].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=CC(=[CH])[C][O].[CH][C]=[CH].[CH][O].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]#[C].[C]/[C]=[C]\[C]=[C]/[C].[C]/[C]=[C]\[C]C.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]=[C][CH].[C]=[C][CH][C]=[CH].[C]C.[C]C.[C]C(=[CH])[O].[C]C(=[C])C=[CH].[C]N([CH])[Ni].[C]N=[C].[C]O[C].[C][CH].[C][CH].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C]=[C].[C][C]=[C].[C][C]=[C].[C][C][C].[C][N].[C][O].[C][O].[C][O].[C][O].[C][O].[C][O].[C][O].[C][O].[C][O].[C][O].[C][O].[C][O].[C][O].[C][O].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[Ni].[Ni].[Ni].[Ni].[OH].[OH].[OH].[OH].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][Ni].[O][Ni]. Metal clusters: 1 [Ni]. The MOF has largest included sphere 8.65 A, density 0.93 g/cm3, surface area 5343.03 m2/g, accessible volume 0.58 cm3/g