CdC18H12(NO2)2(C3H2)3C11H7CHC9H6N is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; six 2,3-dimethyl-1,3-butadiene molecules; four schembl1705614 molecules; four C11H7 clusters; and four CdC18H12(NO2)2 clusters. In each C11H7 cluster, there are eleven inequivalent C sites. In the first C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(36) atom. The C(33)-C(32) bond length is 1.39 Å. The C(33)-C(34) bond length is 1.40 Å. The C(33)-C(36) bond length is 1.48 Å. In the second C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(22) atom. The C(32)-H(22) bond length is 0.93 Å. In the third C site, C(34) is bonded in a distorted single-bond geometry to one C(33) and one H(23) atom. The C(34)-H(23) bond length is 0.93 Å. In the fourth C site, C(36) is bonded in a trigonal planar geometry to one C(33), one C(37), and one C(41) atom. The C(36)-C(37) bond length is 1.38 Å. The C(36)-C(41) bond length is 1.40 Å. In the fifth C site, C(37) is bonded in a distorted single-bond geometry to one C(36) and one H(25) atom. The C(37)-H(25) bond length is 0.93 Å. In the sixth C site, C(39) is bonded in a single-bond geometry to one C(40) and one H(27) atom. The C(39)-C(40) bond length is 1.38 Å. The C(39)-H(27) bond length is 0.93 Å. In the seventh C site, C(40) is bonded in a trigonal planar geometry to one C(39), one C(41), and one C(42) atom. The C(40)-C(41) bond length is 1.39 Å. The C(40)-C(42) bond length is 1.48 Å. In the eighth C site, C(41) is bonded in a single-bond geometry to one C(36), one C(40), and one H(28) atom. The C(41)-H(28) bond length is 0.93 Å. In the ninth C site, C(42) is bonded in a trigonal planar geometry to one C(40), one C(43), and one C(47) atom. The C(42)-C(43) bond length is 1.36 Å. The C(42)-C(47) bond length is 1.38 Å. In the tenth C site, C(43) is bonded in a distorted single-bond geometry to one C(42) and one H(29) atom. The C(43)-H(29) bond length is 0.93 Å. In the eleventh C site, C(47) is bonded in a distorted single-bond geometry to one C(42) and one H(32) atom. The C(47)-H(32) bond length is 0.93 Å. There are seven inequivalent H sites. In the first H site, H(29) is bonded in a single-bond geometry to one C(43) atom. In the second H site, H(32) is bonded in a single-bond geometry to one C(47) atom. In the third H site, H(22) is bonded in a single-bond geometry to one C(32) atom. In the fourth H site, H(23) is bonded in a single-bond geometry to one C(34) atom. In the fifth H site, H(25) is bonded in a single-bond geometry to one C(37) atom. In the sixth H site, H(27) is bonded in a single-bond geometry to one C(39) atom. In the seventh H site, H(28) is bonded in a single-bond geometry to one C(41) atom. In each CdC18H12(NO2)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(2), one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(2) bond length is 2.27 Å. The Cd(1)-N(3) bond length is 2.31 Å. The Cd(1)-O(1) bond length is 2.43 Å. The Cd(1)-O(2) bond length is 2.31 Å. The Cd(1)-O(3) bond length is 2.38 Å. The Cd(1)-O(4) bond length is 2.29 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(2) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(4) atom. The C(5)-N(2) bond length is 1.35 Å. The C(5)-H(4) bond length is 0.93 Å. In the fourth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(6) bond length is 1.49 Å. In the fifth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(7) atom. The C(6)-C(11) bond length is 1.38 Å. The C(6)-C(7) bond length is 1.38 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 0.93 Å. In the eighth C site, C(11) is bonded in a single-bond geometry to one C(6) and one H(8) atom. The C(11)-H(8) bond length is 0.93 Å. In the ninth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(14) atom. The C(20)-N(3) bond length is 1.33 Å. The C(20)-H(14) bond length is 0.93 Å. In the tenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(15) atom. The C(21)-N(3) bond length is 1.34 Å. The C(21)-H(15) bond length is 0.93 Å. In the eleventh C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(1), and one O(2) atom. The C(29)-C(30) bond length is 1.49 Å. The C(29)-O(1) bond length is 1.24 Å. The C(29)-O(2) bond length is 1.24 Å. In the twelfth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(35) atom. The C(30)-C(31) bond length is 1.38 Å. The C(30)-C(35) bond length is 1.40 Å. In the thirteenth C site, C(31) is bonded in a single-bond geometry to one C(30) and one H(21) atom. The C(31)-H(21) bond length is 0.93 Å. In the fourteenth C site, C(35) is bonded in a single-bond geometry to one C(30) and one H(24) atom. The C(35)-H(24) bond length is 0.93 Å. In the fifteenth C site, C(44) is bonded in a distorted single-bond geometry to one C(45) and one H(30) atom. The C(44)-C(45) bond length is 1.38 Å. The C(44)-H(30) bond length is 0.93 Å. In the sixteenth C site, C(45) is bonded in a trigonal planar geometry to one C(44), one C(46), and one C(48) atom. The C(45)-C(46) bond length is 1.37 Å. The C(45)-C(48) bond length is 1.50 Å. In the seventeenth C site, C(46) is bonded in a distorted single-bond geometry to one C(45) and one H(31) atom. The C(46)-H(31) bond length is 0.93 Å. In the eighteenth C site, C(48) is bonded in a bent 120 degrees geometry to one C(45), one O(3), and one O(4) atom. The C(48)-O(3) bond length is 1.24 Å. The C(48)-O(4) bond length is 1.24 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(20), and one C(21) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(21) is bonded in a single-bond geometry to one C(31) atom. In the tenth H site, H(24) is bonded in a single-bond geometry to one C(35) atom. In the eleventh H site, H(30) is bonded in a single-bond geometry to one C(44) atom. In the twelfth H site, H(31) is bonded in a single-bond geometry to one C(46) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(29) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(29) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(48) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Cd(1) and one C(48) atom. Linkers: 3 [C]/C(=C\[CH])c1ccc(N(c2ccc(-c3ccncc3)cc2)c2ccc(-c3ccc(N(c4ccc(-c5ccncc5)cc4)c4ccc(-c5ccncc5)cc4)cc3)cc2)cc1 ,4 [O]C(=O)c1ccc(-c2cccc(-c3ccc(C([O])=O)cc3)c2)cc1 ,4 [c]1[c]cc(N(c2ccc(-c3ccncc3)cc2)c2ccc(-c3ccncc3)cc2)cc1 ,1 [C][C](C=[CH])c1ccc(N(c2ccc(-c3ccncc3)cc2)c2ccc(-c3ccc(N(c4ccc(-c5ccncc5)cc4)c4ccc(-c5ccncc5)cc4)cc3)cc2)cc1. Metal clusters: 4 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 5.24 A, density 1.22 g/cm3, surface area 4853.37 m2/g, accessible volume 0.30 cm3/g