NiSi4H44(C7N)4(CH)4 is Indium-derived structured and crystallizes in the tetragonal I4_1/acd space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules and eight NiSi4H44(C7N)4 clusters. In each NiSi4H44(C7N)4 cluster, Ni(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. All Ni(1)-N(1) bond lengths are 2.10 Å. Si(1) is bonded in a tetrahedral geometry to one C(2), one C(6), one C(7), and one C(8) atom. The Si(1)-C(2) bond length is 1.89 Å. The Si(1)-C(6) bond length is 1.86 Å. The Si(1)-C(7) bond length is 1.86 Å. The Si(1)-C(8) bond length is 1.86 Å. There are seven inequivalent C sites. In the first C site, C(6) is bonded to one Si(1); one H(5,8,10); and two equivalent H(6,7) atoms to form distorted corner-sharing CSiH3 tetrahedra. The C(6)-H(5,8,10) bond length is 0.98 Å. Both C(6)-H(6,7) bond lengths are 0.98 Å. In the second C site, C(7) is bonded to one Si(1); one H(9); and two equivalent H(5,8,10) atoms to form distorted corner-sharing CSiH3 tetrahedra. The C(7)-H(9) bond length is 0.98 Å. Both C(7)-H(5,8,10) bond lengths are 0.98 Å. In the third C site, C(8) is bonded in a distorted water-like geometry to one Si(1) and two equivalent H(11,12) atoms. Both C(8)-H(11,12) bond lengths are 0.99 Å. In the fourth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-C(2) bond length is 1.40 Å. The C(3)-H(2) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.95 Å. In the sixth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the seventh C site, C(2) is bonded in a trigonal planar geometry to one Si(1), one C(1), and one C(3) atom. N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(1), and one C(5) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5,8,10) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6,7) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(8) atom. Linkers: 18 C[Si](C)(CC[Si](C)(C)c1cccnc1)c1cccnc1. Metal clusters: 8 [Ni]. The MOF has largest included sphere 4.09 A, density 1.02 g/cm3, surface area 5884.04 m2/g, accessible volume 0.47 cm3/g