CoZn3C36H15(N2O5)3(CH)6 crystallizes in the monoclinic P2_1/c space group. The structure consists of twenty-four 02329_fluka molecules inside a CoZn3C36H15(N2O5)3 framework. In the CoZn3C36H15(N2O5)3 framework, Co(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one N(5), and one N(6) atom. The Co(1)-N(1) bond length is 1.93 Å. The Co(1)-N(2) bond length is 1.93 Å. The Co(1)-N(3) bond length is 1.94 Å. The Co(1)-N(4) bond length is 1.95 Å. The Co(1)-N(5) bond length is 1.94 Å. The Co(1)-N(6) bond length is 1.94 Å. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Zn(1)-O(2) bond length is 2.45 Å. The Zn(1)-O(3) bond length is 1.99 Å. The Zn(1)-O(4) bond length is 1.94 Å. The Zn(1)-O(5) bond length is 1.96 Å. The Zn(1)-O(6) bond length is 2.08 Å. In the second Zn site, Zn(2) is bonded in a distorted T-shaped geometry to one O(12), one O(14), and one O(8) atom. The Zn(2)-O(12) bond length is 2.05 Å. The Zn(2)-O(14) bond length is 2.27 Å. The Zn(2)-O(8) bond length is 2.02 Å. In the third Zn site, Zn(3) is bonded in a 3-coordinate geometry to one O(11), one O(14), and one O(9) atom. The Zn(3)-O(11) bond length is 2.10 Å. The Zn(3)-O(14) bond length is 2.08 Å. The Zn(3)-O(9) bond length is 1.98 Å. There are thirty-six inequivalent C sites. In the first C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(18) atom. The C(31)-C(32) bond length is 1.37 Å. The C(31)-H(18) bond length is 0.93 Å. In the second C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31), one C(33), and one N(5) atom. The C(32)-C(33) bond length is 1.49 Å. The C(32)-N(5) bond length is 1.35 Å. In the third C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(32), one N(6), and one O(15) atom. The C(33)-N(6) bond length is 1.32 Å. The C(33)-O(15) bond length is 1.24 Å. In the fourth C site, C(34) is bonded in a distorted single-bond geometry to one N(6) atom. The C(34)-N(6) bond length is 1.44 Å. In the fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(36) and one H(19) atom. The C(35)-C(36) bond length is 1.38 Å. The C(35)-H(19) bond length is 0.93 Å. In the sixth C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(39) atom. The C(36)-C(37) bond length is 1.38 Å. The C(36)-C(39) bond length is 1.50 Å. In the seventh C site, C(37) is bonded in a distorted single-bond geometry to one C(36), one C(40), and one H(20) atom. The C(37)-C(40) bond length is 1.38 Å. The C(37)-H(20) bond length is 0.93 Å. In the eighth C site, C(38) is bonded in a distorted single-bond geometry to one C(40) and one H(21) atom. The C(38)-C(40) bond length is 1.38 Å. The C(38)-H(21) bond length is 0.93 Å. In the ninth C site, C(39) is bonded in a bent 120 degrees geometry to one C(36), one O(2), and one O(3) atom. The C(39)-O(2) bond length is 1.23 Å. The C(39)-O(3) bond length is 1.27 Å. In the tenth C site, C(40) is bonded in a trigonal planar geometry to one C(37), one C(38), and one C(41) atom. The C(40)-C(41) bond length is 1.50 Å. In the eleventh C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(40), one O(8), and one O(9) atom. The C(41)-O(8) bond length is 1.24 Å. The C(41)-O(9) bond length is 1.25 Å. In the twelfth C site, C(42) is bonded in a bent 120 degrees geometry to one C(23), one O(4), and one O(7) atom. The C(42)-C(23) bond length is 1.51 Å. The C(42)-O(4) bond length is 1.27 Å. The C(42)-O(7) bond length is 1.23 Å. In the thirteenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.93 Å. In the fourteenth C site, C(5) is bonded in a distorted single-bond geometry to one N(1) atom. The C(5)-N(1) bond length is 1.34 Å. In the fifteenth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(1) atom. The C(6)-N(2) bond length is 1.32 Å. The C(6)-O(1) bond length is 1.24 Å. In the sixteenth C site, C(7) is bonded in a distorted single-bond geometry to one N(2) atom. The C(7)-N(2) bond length is 1.42 Å. In the seventeenth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(8)-C(9) bond length is 1.38 Å. The C(8)-H(5) bond length is 0.93 Å. In the eighteenth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(8) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(13) bond length is 1.52 Å. In the nineteenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(6) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(6) bond length is 0.93 Å. In the twentieth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(14) bond length is 1.51 Å. In the twenty-first C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 0.93 Å. In the twenty-second C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(11), and one O(12) atom. The C(13)-O(11) bond length is 1.25 Å. The C(13)-O(12) bond length is 1.26 Å. In the twenty-third C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(10), and one O(5) atom. The C(14)-O(10) bond length is 1.22 Å. The C(14)-O(5) bond length is 1.27 Å. In the twenty-fourth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(8) atom. The C(15)-N(3) bond length is 1.35 Å. The C(15)-H(8) bond length is 0.93 Å. In the twenty-fifth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(10) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-H(10) bond length is 0.93 Å. In the twenty-sixth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(11) atom. The C(18)-C(19) bond length is 1.37 Å. The C(18)-H(11) bond length is 0.93 Å. In the twenty-seventh C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one N(3) atom. The C(19)-N(3) bond length is 1.34 Å. In the twenty-eighth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4) and one O(13) atom. The C(20)-N(4) bond length is 1.31 Å. The C(20)-O(13) bond length is 1.25 Å. In the twenty-ninth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one C(26), and one N(4) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-C(26) bond length is 1.40 Å. The C(21)-N(4) bond length is 1.44 Å. In the thirtieth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(12) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-H(12) bond length is 0.93 Å. In the thirty-first C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(42) atom. The C(23)-C(24) bond length is 1.38 Å. In the thirty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(13) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(13) bond length is 0.93 Å. In the thirty-third C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(27) atom. The C(25)-C(26) bond length is 1.38 Å. The C(25)-C(27) bond length is 1.50 Å. In the thirty-fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(21), one C(25), and one H(14) atom. The C(26)-H(14) bond length is 0.93 Å. In the thirty-fifth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(14), and one O(6) atom. The C(27)-O(14) bond length is 1.28 Å. The C(27)-O(6) bond length is 1.25 Å. In the thirty-sixth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(15) atom. The C(28)-N(5) bond length is 1.34 Å. The C(28)-H(15) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(6), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(15), and one C(19) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(20), and one C(21) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(1), one C(28), and one C(32) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Co(1), one C(33), and one C(34) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(28) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(31) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(35) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(37) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(38) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Zn(1) and one C(39) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(39) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(42) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(27) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(42) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(41) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(41) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(13) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(13) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Zn(2), one Zn(3), and one C(27) atom. In the fifteenth O site, O(15) is bonded in a single-bond geometry to one C(33) atom. Linkers: 12 [O]C(=O)c1cc([N]C(=O)c2ccccn2)cc(C([O])=O)c1. Metal clusters: 4 O=[C]O[Zn](O[C]O[Zn]1O[C]O[Zn]O[C]O1)(O[C]=O)O[C]=O ,4 [Co]. RCSR code: nov. The MOF has largest included sphere 5.39 A, density 1.35 g/cm3, surface area 3785.67 m2/g, accessible volume 0.33 cm3/g