DyC16NH7O6(CH)4 crystallizes in the triclinic P-1 space group. The structure consists of eight 02329_fluka molecules inside a DyC16NH7O6 framework. In the DyC16NH7O6 framework, Dy(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Dy(1)-O(1) bond length is 2.34 Å. The Dy(1)-O(2) bond length is 2.46 Å. The Dy(1)-O(3) bond length is 2.27 Å. The Dy(1)-O(4) bond length is 2.33 Å. The Dy(1)-O(5) bond length is 2.39 Å. The Dy(1)-O(6) bond length is 2.28 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(4) atom. The C(1)-C(4) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.23 Å. The C(1)-O(4) bond length is 1.24 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(2), and one O(5) atom. The C(2)-C(5) bond length is 1.51 Å. The C(2)-O(2) bond length is 1.25 Å. The C(2)-O(5) bond length is 1.25 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(3), and one O(6) atom. The C(3)-C(6) bond length is 1.50 Å. The C(3)-O(3) bond length is 1.25 Å. The C(3)-O(6) bond length is 1.22 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(19), and one C(7) atom. The C(4)-C(19) bond length is 1.37 Å. The C(4)-C(7) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(20), and one C(8) atom. The C(5)-C(20) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.38 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(9) atom. The C(6)-C(12) bond length is 1.37 Å. The C(6)-C(9) bond length is 1.39 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(10), one C(19), and one C(4) atom. The C(7)-C(10) bond length is 1.41 Å. The C(7)-C(19) bond length is 1.43 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(20), and one C(5) atom. The C(8)-C(11) bond length is 1.46 Å. The C(8)-C(20) bond length is 1.42 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(12), one C(6), and one N(1) atom. The C(9)-C(12) bond length is 1.38 Å. The C(9)-N(1) bond length is 1.43 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(7) and one H(1) atom. The C(10)-H(1) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a single-bond geometry to one C(8) and one H(2) atom. The C(11)-H(2) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(6), one C(9), and one H(3) atom. The C(12)-H(3) bond length is 0.93 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(19) and one H(8) atom. The C(17)-C(19) bond length is 1.43 Å. The C(17)-H(8) bond length is 0.93 Å. In the fourteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(20) and one H(9) atom. The C(18)-C(20) bond length is 1.43 Å. The C(18)-H(9) bond length is 0.93 Å. In the fifteenth C site, C(19) is bonded in a trigonal planar geometry to one C(17), one C(4), and one C(7) atom. In the sixteenth C site, C(20) is bonded in a trigonal planar geometry to one C(18), one C(5), and one C(8) atom. N(1) is bonded in a trigonal planar geometry to one C(9), one H(10), and one H(11) atom. The N(1)-H(10) bond length is 0.86 Å. The N(1)-H(11) bond length is 0.86 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one N(1) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one N(1) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Dy(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Dy(1) and one C(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Dy(1) and one C(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Dy(1) and one C(3) atom. Linkers: 4 [O]C(=O)c1c2ccccc2c(C([O])=O)c2ccccc12 ,1 Nc1cc(C([O])=O)c(N)cc1C([O])=O. Metal clusters: 1 [C]1O[Dy]234(O1)O[C]O[Dy]1(O[C]O1)(O[C]O2)(O[C]O3)O[C]O4. RCSR code: pcu. The MOF has largest included sphere 6.61 A, density 1.17 g/cm3, surface area 3647.04 m2/g, accessible volume 0.48 cm3/g