Al3C24H12O13(C17H11)3 is Indium-derived structured and crystallizes in the cubic Pm-3n space group. The structure is zero-dimensional and consists of eight Al3C24H12O13 clusters and twenty-four C17H11 clusters. In each Al3C24H12O13 cluster, Al(1) is bonded to one O(3), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing AlO5 square pyramids. The Al(1)-O(3) bond length is 1.83 Å. Both Al(1)-O(1) bond lengths are 1.89 Å. Both Al(1)-O(2) bond lengths are 1.91 Å. There are four inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(1) bond length is 1.48 Å. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(4) bond length is 1.40 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(4)-H(2) bond length is 0.93 Å. In the fourth C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.26 Å. There are two inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Al(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Al(1) and one C(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to three equivalent Al(1) atoms. In each C17H11 cluster, there are ten inequivalent C sites. In the first C site, C(5) is bonded in a distorted single-bond geometry to one C(7) and one H(3) atom. The C(5)-C(7) bond length is 1.40 Å. The C(5)-H(3) bond length is 0.93 Å. In the second C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(4) bond length is 0.93 Å. In the third C site, C(7) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(8) atom. The C(7)-C(8) bond length is 1.48 Å. In the fourth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.38 Å. In the fifth C site, C(9) is bonded in a single-bond geometry to one C(13), one C(8), and one H(5) atom. The C(9)-C(13) bond length is 1.41 Å. The C(9)-H(5) bond length is 0.93 Å. In the sixth C site, C(10) is bonded in a distorted single-bond geometry to one C(14) and one H(6) atom. The C(10)-C(14) bond length is 1.33 Å. The C(10)-H(6) bond length is 0.98 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(14) and one H(7) atom. The C(11)-C(14) bond length is 1.32 Å. The C(11)-H(7) bond length is 0.98 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to two equivalent C(8) and one H(8) atom. The C(12)-H(8) bond length is 0.93 Å. In the ninth C site, C(13) is bonded in a trigonal planar geometry to one C(14) and two equivalent C(9) atoms. The C(13)-C(14) bond length is 1.44 Å. In the tenth C site, C(14) is bonded in a 5-coordinate geometry to one C(13), two equivalent C(10), and two equivalent C(11) atoms. There are six inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. Linkers: 5 [C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@@H]4[C@H]5[C@@H]([C@@H]41)C235.[O]C(=O)c1ccc(-c2c[c]cc(-c3ccc(C([O])=O)cc3)c2)cc1.[O]C(=O)c1ccc(-c2c[c]cc(-c3ccc(C([O])=O)cc3)c2)cc1 ,9 [C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@H]4[C@@H]5[C@H]([C@H]41)C235.[O]C(=O)c1ccc(-c2c[c]cc(-c3ccc(C([O])=O)cc3)c2)cc1.[O]C(=O)c1ccc(-c2c[c]cc(-c3ccc(C([O])=O)cc3)c2)cc1. Metal clusters: 8 [C]1O[Al]23O[C]O[Al]45(O1)O[C]O[Al](O[C]O2)(O[C]O3)(O[C]O4)O5. RCSR code: soc. The MOF has largest included sphere 17.52 A, density 0.35 g/cm3, surface area 4569.31 m2/g, accessible volume 2.26 cm3/g