CdH11(C7N3)2CH is Indium-derived structured and crystallizes in the tetragonal P4_1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and four CdH11(C7N3)2 clusters. In each CdH11(C7N3)2 cluster, Cd(1) is bonded in a T-shaped geometry to one N(1), one N(3), and one N(6) atom. The Cd(1)-N(1) bond length is 2.28 Å. The Cd(1)-N(3) bond length is 2.44 Å. The Cd(1)-N(6) bond length is 2.29 Å. There are fourteen inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one N(2) atom. The C(2)-N(2) bond length is 1.44 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(2) bond length is 0.93 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(4) bond length is 1.42 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one N(5) atom. The C(6)-N(5) bond length is 1.43 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(4) atom. The C(7)-N(1) bond length is 1.31 Å. The C(7)-N(2) bond length is 1.34 Å. The C(7)-H(4) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(5) atom. The C(8)-C(9) bond length is 1.36 Å. The C(8)-N(1) bond length is 1.37 Å. The C(8)-H(5) bond length is 0.93 Å. In the eighth C site, C(9) is bonded in a 3-coordinate geometry to one C(8), one N(2), and one H(6) atom. The C(9)-N(2) bond length is 1.36 Å. The C(9)-H(6) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(7) atom. The C(10)-N(3) bond length is 1.32 Å. The C(10)-N(4) bond length is 1.35 Å. The C(10)-H(7) bond length is 0.93 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(3), and one H(8) atom. The C(11)-C(12) bond length is 1.34 Å. The C(11)-N(3) bond length is 1.36 Å. The C(11)-H(8) bond length is 0.93 Å. In the eleventh C site, C(12) is bonded in a 3-coordinate geometry to one C(11), one N(4), and one H(9) atom. The C(12)-N(4) bond length is 1.37 Å. The C(12)-H(9) bond length is 0.93 Å. In the twelfth C site, C(13) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(10) atom. The C(13)-N(5) bond length is 1.36 Å. The C(13)-N(6) bond length is 1.31 Å. The C(13)-H(10) bond length is 0.93 Å. In the thirteenth C site, C(14) is bonded in a 3-coordinate geometry to one C(15), one N(5), and one H(11) atom. The C(14)-C(15) bond length is 1.36 Å. The C(14)-N(5) bond length is 1.38 Å. The C(14)-H(11) bond length is 0.93 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(6), and one H(12) atom. The C(15)-N(6) bond length is 1.37 Å. The C(15)-H(12) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(7), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(7), and one C(9) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one Cd(1), one C(10), and one C(11) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(4) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(6) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(15) atom. There are eleven inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(15) atom. Linkers: 4 c1cn(-c2cc(-n3ccnc3)cc(-n3ccnc3)c2)cn1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 5.03 A, density 1.16 g/cm3, surface area 4222.88 m2/g, accessible volume 0.41 cm3/g