Yb3C24H12O13(C7H4)6 is Indium-derived structured and crystallizes in the hexagonal P-62c space group. The structure is zero-dimensional and consists of two 1,3,5-tris[3,5-bis(prop-1-en-2-yl)phenyl]benzene molecules and two Yb3C24H12O13 clusters. In each Yb3C24H12O13 cluster, Yb(1) is bonded to one O(3), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing YbO5 square pyramids. The Yb(1)-O(3) bond length is 2.11 Å. Both Yb(1)-O(1) bond lengths are 2.22 Å. Both Yb(1)-O(2) bond lengths are 2.22 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.24 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(7) bond length is 1.34 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a trigonal planar geometry to three equivalent Yb(1) atoms. In the second O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Yb(1) and one C(1) atom. In the third O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Yb(1) and one C(1) atom. Linkers: 4 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3cc(-c4cc(-c5ccc(C([O])=O)cc5)cc(-c5ccc(C([O])=O)cc5)c4)cc(-c4cc(-c5ccc(C([O])=O)cc5)cc(-c5ccc(C([O])=O)cc5)c4)c3)c2)cc1. Metal clusters: 2 [C]1O[Yb]23O[C]O[Yb]45(O1)O[C]O[Yb](O[C]O2)(O[C]O3)(O[C]O4)O5. RCSR code: nia. The MOF has largest included sphere 13.80 A, density 0.54 g/cm3, surface area 3541.69 m2/g, accessible volume 1.49 cm3/g