Cu4C10N3H10Cl4(CH)2(CH3)12 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, forty-eight 02329_fluka molecules, and four Cu4C10N3H10Cl4 clusters. In each Cu4C10N3H10Cl4 cluster, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a trigonal planar geometry to one N(1), one Cl(2), and one Cl(4) atom. The Cu(1)-N(1) bond length is 2.04 Å. The Cu(1)-Cl(2) bond length is 2.27 Å. The Cu(1)-Cl(4) bond length is 2.26 Å. In the second Cu site, Cu(2) is bonded in a 3-coordinate geometry to one N(2), one Cl(2), and one Cl(3) atom. The Cu(2)-N(2) bond length is 1.99 Å. The Cu(2)-Cl(2) bond length is 2.20 Å. The Cu(2)-Cl(3) bond length is 2.46 Å. In the third Cu site, Cu(3) is bonded in a distorted bent 150 degrees geometry to one N(3) and one Cl(1) atom. The Cu(3)-N(3) bond length is 1.87 Å. The Cu(3)-Cl(1) bond length is 2.14 Å. In the fourth Cu site, Cu(4) is bonded in a trigonal planar geometry to one Cl(1), one Cl(3), and one Cl(4) atom. The Cu(4)-Cl(1) bond length is 2.42 Å. The Cu(4)-Cl(3) bond length is 2.29 Å. The Cu(4)-Cl(4) bond length is 2.28 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 1.08 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2) atom. The C(2)-N(2) bond length is 1.31 Å. The C(2)-H(2) bond length is 1.08 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(3) atom. The C(3)-N(3) bond length is 1.28 Å. The C(3)-H(3) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a 4-coordinate geometry to one C(5), one C(6), one N(1), and one H(4) atom. The C(4)-C(5) bond length is 1.53 Å. The C(4)-C(6) bond length is 1.51 Å. The C(4)-N(1) bond length is 1.53 Å. The C(4)-H(4) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a single-bond geometry to one C(4) and one H(5,9) atom. The C(5)-H(5,9) bond length is 1.08 Å. In the sixth C site, C(6) is bonded in a single-bond geometry to one C(4) and one H(6) atom. The C(6)-H(6) bond length is 1.08 Å. In the seventh C site, C(7) is bonded in a 4-coordinate geometry to one C(8), one C(9), one N(2), and one H(7) atom. The C(7)-C(8) bond length is 1.53 Å. The C(7)-C(9) bond length is 1.54 Å. The C(7)-N(2) bond length is 1.56 Å. The C(7)-H(7) bond length is 1.08 Å. In the eighth C site, C(8) is bonded in a single-bond geometry to one C(7) and one H(8) atom. The C(8)-H(8) bond length is 1.08 Å. In the ninth C site, C(9) is bonded in a single-bond geometry to one C(7) and one H(5,9) atom. The C(9)-H(5,9) bond length is 1.08 Å. In the tenth C site, C(10) is bonded in a 2-coordinate geometry to one N(3) and one H(10) atom. The C(10)-N(3) bond length is 1.54 Å. The C(10)-H(10) bond length is 1.08 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(2), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(3), one C(10), and one C(3) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5,9) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in an L-shaped geometry to one Cu(3) and one Cu(4) atom. In the second Cl site, Cl(2) is bonded in an L-shaped geometry to one Cu(1) and one Cu(2) atom. In the third Cl site, Cl(3) is bonded in an L-shaped geometry to one Cu(2) and one Cu(4) atom. In the fourth Cl site, Cl(4) is bonded in an L-shaped geometry to one Cu(1) and one Cu(4) atom. Linkers: 4 CC(C)C([N]/C=C/[N]C(C(C)C)C(C)C)C(C)C ,2 CC(C)C(/N=C/C=N/C(C(C)C)C(C)C)C(C)C. Metal clusters: 16 [Cu]. The MOF has largest included sphere 6.52 A, density 1.11 g/cm3, surface area 5212.16 m2/g, accessible volume 0.43 cm3/g