Gd2Co2C32H12(NO4)5(CH)3 crystallizes in the orthorhombic Pna2_1 space group. The structure consists of twelve 02329_fluka molecules inside a Gd2Co2C32H12(NO4)5 framework. In the Gd2Co2C32H12(NO4)5 framework, there are two inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a distorted pentagonal pyramidal geometry to one O(1), one O(15), one O(18), one O(3), one O(5), and one O(7) atom. The Gd(1)-O(1) bond length is 2.38 Å. The Gd(1)-O(15) bond length is 2.32 Å. The Gd(1)-O(18) bond length is 2.37 Å. The Gd(1)-O(3) bond length is 2.35 Å. The Gd(1)-O(5) bond length is 2.41 Å. The Gd(1)-O(7) bond length is 2.29 Å. In the second Gd site, Gd(2) is bonded in a distorted pentagonal pyramidal geometry to one O(10), one O(11), one O(13), one O(16), one O(19), and one O(20) atom. The Gd(2)-O(10) bond length is 2.39 Å. The Gd(2)-O(11) bond length is 2.32 Å. The Gd(2)-O(13) bond length is 2.39 Å. The Gd(2)-O(16) bond length is 2.33 Å. The Gd(2)-O(19) bond length is 2.48 Å. The Gd(2)-O(20) bond length is 2.47 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted rectangular see-saw-like geometry to one N(2), one N(3), one O(6), and one O(9) atom. The Co(1)-N(2) bond length is 2.15 Å. The Co(1)-N(3) bond length is 2.15 Å. The Co(1)-O(6) bond length is 2.05 Å. The Co(1)-O(9) bond length is 2.06 Å. In the second Co site, Co(2) is bonded in an octahedral geometry to one N(1), one N(4), one N(5), one O(14), one O(17), and one O(2) atom. The Co(2)-N(1) bond length is 2.13 Å. The Co(2)-N(4) bond length is 2.09 Å. The Co(2)-N(5) bond length is 2.14 Å. The Co(2)-O(14) bond length is 2.09 Å. The Co(2)-O(17) bond length is 2.07 Å. The Co(2)-O(2) bond length is 2.03 Å. There are thirty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-C(6) bond length is 1.49 Å. The C(1)-N(1) bond length is 1.37 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.36 Å. The C(2)-C(7) bond length is 1.48 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(3) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.25 Å. The C(6)-O(2) bond length is 1.28 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(7)-O(3) bond length is 1.27 Å. The C(7)-O(4) bond length is 1.23 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one N(2) atom. The C(8)-C(13) bond length is 1.55 Å. The C(8)-C(9) bond length is 1.41 Å. The C(8)-N(2) bond length is 1.28 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(14) bond length is 1.52 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(10)-H(4) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(12)-N(2) bond length is 1.31 Å. The C(12)-H(6) bond length is 0.93 Å. In the eleventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(5), and one O(6) atom. The C(13)-O(5) bond length is 1.27 Å. The C(13)-O(6) bond length is 1.27 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(7), and one O(8) atom. The C(14)-O(7) bond length is 1.27 Å. The C(14)-O(8) bond length is 1.21 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one C(20), and one N(3) atom. The C(15)-C(16) bond length is 1.37 Å. The C(15)-C(20) bond length is 1.52 Å. The C(15)-N(3) bond length is 1.37 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-C(21) bond length is 1.50 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(7) atom. The C(17)-H(7) bond length is 0.93 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(8) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(8) bond length is 0.93 Å. In the seventeenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(3), and one H(9) atom. The C(19)-N(3) bond length is 1.37 Å. The C(19)-H(9) bond length is 0.93 Å. In the eighteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(10), and one O(9) atom. The C(20)-O(10) bond length is 1.27 Å. The C(20)-O(9) bond length is 1.26 Å. In the nineteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(11), and one O(12) atom. The C(21)-O(11) bond length is 1.23 Å. The C(21)-O(12) bond length is 1.27 Å. In the twentieth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(23), one C(27), and one N(4) atom. The C(22)-C(23) bond length is 1.36 Å. The C(22)-C(27) bond length is 1.50 Å. The C(22)-N(4) bond length is 1.35 Å. In the twenty-first C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.35 Å. The C(23)-C(28) bond length is 1.48 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(10) atom. The C(24)-H(10) bond length is 0.93 Å. In the twenty-third C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(12) atom. The C(26)-N(4) bond length is 1.30 Å. The C(26)-H(12) bond length is 0.93 Å. In the twenty-fourth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(13), and one O(14) atom. The C(27)-O(13) bond length is 1.24 Å. The C(27)-O(14) bond length is 1.29 Å. In the twenty-fifth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(15), and one O(16) atom. The C(28)-O(15) bond length is 1.25 Å. The C(28)-O(16) bond length is 1.24 Å. In the twenty-sixth C site, C(29) is bonded in a distorted single-bond geometry to one C(30) and one N(5) atom. The C(29)-C(30) bond length is 1.35 Å. The C(29)-N(5) bond length is 1.36 Å. In the twenty-seventh C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(35) atom. The C(30)-C(31) bond length is 1.44 Å. The C(30)-C(35) bond length is 1.52 Å. In the twenty-eighth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(13) atom. The C(31)-H(13) bond length is 0.93 Å. In the twenty-ninth C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(14) atom. The C(32)-C(33) bond length is 1.31 Å. The C(32)-H(14) bond length is 0.93 Å. In the thirtieth C site, C(33) is bonded in a distorted trigonal planar geometry to one C(32), one N(5), and one H(15) atom. The C(33)-N(5) bond length is 1.36 Å. The C(33)-H(15) bond length is 0.93 Å. In the thirty-first C site, C(34) is bonded in a distorted bent 120 degrees geometry to one O(17) and one O(18) atom. The C(34)-O(17) bond length is 1.29 Å. The C(34)-O(18) bond length is 1.22 Å. In the thirty-second C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(19), and one O(20) atom. The C(35)-O(19) bond length is 1.26 Å. The C(35)-O(20) bond length is 1.25 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(2), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(12), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(15), and one C(19) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one Co(2), one C(29), and one C(33) atom. In the fifth N site, N(4) is bonded in a trigonal planar geometry to one Co(2), one C(22), and one C(26) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(31) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(32) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(33) atom. There are twenty inequivalent O sites. In the first O site, O(20) is bonded in a distorted single-bond geometry to one Gd(2) and one C(35) atom. In the second O site, O(15) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one C(28) atom. In the third O site, O(12) is bonded in a single-bond geometry to one C(21) atom. In the fourth O site, O(1) is bonded in a distorted single-bond geometry to one Gd(1) and one C(6) atom. In the fifth O site, O(2) is bonded in a bent 120 degrees geometry to one Co(2) and one C(6) atom. In the sixth O site, O(3) is bonded in a distorted single-bond geometry to one Gd(1) and one C(7) atom. In the seventh O site, O(4) is bonded in a single-bond geometry to one C(7) atom. In the eighth O site, O(5) is bonded in a distorted single-bond geometry to one Gd(1) and one C(13) atom. In the ninth O site, O(6) is bonded in a bent 120 degrees geometry to one Co(1) and one C(13) atom. In the tenth O site, O(7) is bonded in a distorted single-bond geometry to one Gd(1) and one C(14) atom. In the eleventh O site, O(8) is bonded in a single-bond geometry to one C(14) atom. In the twelfth O site, O(9) is bonded in a distorted single-bond geometry to one Co(1) and one C(20) atom. In the thirteenth O site, O(10) is bonded in a distorted single-bond geometry to one Gd(2) and one C(20) atom. In the fourteenth O site, O(11) is bonded in a single-bond geometry to one Gd(2) and one C(21) atom. In the fifteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Co(2) and one C(27) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Gd(2) and one C(28) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Co(2) and one C(34) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one C(34) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Gd(2) and one C(35) atom. In the twentieth O site, O(13) is bonded in a distorted single-bond geometry to one Gd(2) and one C(27) atom. Linkers: 19 [O]C(=O)c1cccnc1C([O])=O. Metal clusters: 8 [Gd] ,8 [Co]. The MOF has largest included sphere 5.44 A, density 1.64 g/cm3, surface area 3275.64 m2/g, accessible volume 0.24 cm3/g