AgH20(C3N2)6 crystallizes in the orthorhombic Pbcn space group. The structure consists of a AgH20(C3N2)6 framework. Ag(1) is bonded in a tetrahedral geometry to one N(1), one N(10), one N(5), and one N(8) atom. The Ag(1)-N(1) bond length is 2.28 Å. The Ag(1)-N(10) bond length is 2.37 Å. The Ag(1)-N(5) bond length is 2.34 Å. The Ag(1)-N(8) bond length is 2.26 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.30 Å. The C(1)-N(3) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(2) atom. The C(2)-N(2) bond length is 1.28 Å. The C(2)-N(3) bond length is 1.32 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(3) atom. The C(3)-N(4) bond length is 1.30 Å. The C(3)-N(6) bond length is 1.35 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(4) atom. The C(4)-N(5) bond length is 1.28 Å. The C(4)-N(6) bond length is 1.34 Å. The C(4)-H(4) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(5) atom. The C(5)-N(7) bond length is 1.29 Å. The C(5)-N(9) bond length is 1.34 Å. The C(5)-H(5) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(8), one N(9), and one H(6) atom. The C(6)-N(8) bond length is 1.29 Å. The C(6)-N(9) bond length is 1.34 Å. The C(6)-H(6) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(7) atom. The C(7)-N(10) bond length is 1.31 Å. The C(7)-N(12) bond length is 1.34 Å. The C(7)-H(7) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(8) atom. The C(8)-N(11) bond length is 1.31 Å. The C(8)-N(12) bond length is 1.35 Å. The C(8)-H(8) bond length is 0.93 Å. In the ninth C site, C(9) is bonded to one C(10), one C(14), one C(15), and one N(3) atom to form distorted corner-sharing CC3N tetrahedra. The C(9)-C(10) bond length is 1.53 Å. The C(9)-C(14) bond length is 1.54 Å. The C(9)-C(15) bond length is 1.53 Å. The C(9)-N(3) bond length is 1.47 Å. In the tenth C site, C(10) is bonded in a water-like geometry to one C(11), one C(9), one H(10), and one H(9) atom. The C(10)-C(11) bond length is 1.52 Å. The C(10)-H(10) bond length is 0.97 Å. The C(10)-H(9) bond length is 0.97 Å. In the eleventh C site, C(11) is bonded to one C(10), one C(12), one C(17), and one N(6) atom to form distorted corner-sharing CC3N tetrahedra. The C(11)-C(12) bond length is 1.55 Å. The C(11)-C(17) bond length is 1.55 Å. The C(11)-N(6) bond length is 1.48 Å. In the twelfth C site, C(12) is bonded in a water-like geometry to one C(11); one C(13); and two equivalent H(11,12) atoms. The C(12)-C(13) bond length is 1.51 Å. Both C(12)-H(11,12) bond lengths are 0.97 Å. In the thirteenth C site, C(13) is bonded to one C(12), one C(14), one C(18), and one N(9) atom to form distorted corner-sharing CC3N tetrahedra. The C(13)-C(14) bond length is 1.53 Å. The C(13)-C(18) bond length is 1.53 Å. The C(13)-N(9) bond length is 1.47 Å. In the fourteenth C site, C(14) is bonded in a water-like geometry to one C(13), one C(9), one H(13), and one H(14) atom. The C(14)-H(13) bond length is 0.97 Å. The C(14)-H(14) bond length is 0.97 Å. In the fifteenth C site, C(15) is bonded in a water-like geometry to one C(16); one C(9); and two equivalent H(15,16) atoms. The C(15)-C(16) bond length is 1.53 Å. Both C(15)-H(15,16) bond lengths are 0.97 Å. In the sixteenth C site, C(16) is bonded to one C(15), one C(17), one C(18), and one N(12) atom to form distorted corner-sharing CC3N tetrahedra. The C(16)-C(17) bond length is 1.52 Å. The C(16)-C(18) bond length is 1.52 Å. The C(16)-N(12) bond length is 1.49 Å. In the seventeenth C site, C(17) is bonded in a water-like geometry to one C(11); one C(16); and two equivalent H(17,18) atoms. Both C(17)-H(17,18) bond lengths are 0.97 Å. In the eighteenth C site, C(18) is bonded in a water-like geometry to one C(13), one C(16), one H(19), and one H(20) atom. The C(18)-H(19) bond length is 0.97 Å. The C(18)-H(20) bond length is 0.97 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.34 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(2) and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(9) atom. In the fourth N site, N(4) is bonded in a distorted water-like geometry to one C(3) and one N(5) atom. The N(4)-N(5) bond length is 1.39 Å. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one Ag(1), one C(4), and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(4) atom. In the seventh N site, N(7) is bonded in a distorted water-like geometry to one C(5) and one N(8) atom. The N(7)-N(8) bond length is 1.33 Å. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(6), and one N(7) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(13), one C(5), and one C(6) atom. In the tenth N site, N(10) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(7), and one N(11) atom. The N(10)-N(11) bond length is 1.38 Å. In the eleventh N site, N(11) is bonded in a distorted single-bond geometry to one C(8) and one N(10) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one C(16), one C(7), and one C(8) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11,12) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(15,16) is bonded in a single-bond geometry to one C(15) atom. In the fifteenth H site, H(17,18) is bonded in a single-bond geometry to one C(17) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. Linkers: 8 c1nncn1[C@]12C[C@]3(n4cnnc4)C[C@](n4cnnc4)(C1)C[C@](n1cnnc1)(C2)C3. Metal clusters: 8 [Ag]. The MOF has largest included sphere 4.37 A, density 1.34 g/cm3, surface area 4068.41 m2/g, accessible volume 0.33 cm3/g