CdC14H12(NO)4(CH)2(CH2)2 is Indium-derived structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, eight 02329_fluka molecules, and four CdC14H12(NO)4 clusters. In each CdC14H12(NO)4 cluster, Cd(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(4), one O(1), one O(2), and one O(4) atom. The Cd(1)-N(1) bond length is 2.33 Å. The Cd(1)-N(4) bond length is 2.36 Å. The Cd(1)-O(1) bond length is 2.34 Å. The Cd(1)-O(2) bond length is 2.51 Å. The Cd(1)-O(4) bond length is 2.22 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(8) atom. The C(2)-C(3) bond length is 1.48 Å. The C(2)-C(4) bond length is 1.39 Å. The C(2)-C(8) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(7), and one N(3) atom. The C(3)-C(7) bond length is 1.49 Å. The C(3)-N(3) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(10), one C(11), and one N(2) atom. The C(5)-C(10) bond length is 1.49 Å. The C(5)-C(11) bond length is 1.50 Å. The C(5)-N(2) bond length is 1.27 Å. In the sixth C site, C(7) is bonded in a trigonal non-coplanar geometry to one C(3), one H(4), one H(5), and one H(6) atom. The C(7)-H(4) bond length is 0.96 Å. The C(7)-H(5) bond length is 0.96 Å. The C(7)-H(6) bond length is 0.96 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(7) atom. The C(8)-N(1) bond length is 1.33 Å. The C(8)-H(7) bond length is 0.93 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(4), and one H(8) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-N(4) bond length is 1.34 Å. The C(9)-H(8) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(12), one C(5), and one C(9) atom. The C(10)-C(12) bond length is 1.38 Å. In the tenth C site, C(11) is bonded in a trigonal non-coplanar geometry to one C(5); one H(9); and two equivalent H(10,11) atoms. The C(11)-H(9) bond length is 0.96 Å. Both C(11)-H(10,11) bond lengths are 0.96 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one H(12) atom. The C(12)-H(12) bond length is 0.93 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(13)-O(1) bond length is 1.26 Å. The C(13)-O(2) bond length is 1.24 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(13) atom. The C(14)-N(4) bond length is 1.32 Å. The C(14)-H(13) bond length is 0.93 Å. In the fourteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(18)-O(3) bond length is 1.22 Å. The C(18)-O(4) bond length is 1.27 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(8) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one C(5) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(14), and one C(9) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(10,11) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(14) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(13) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(13) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(18) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(18) atom. Linkers: 1 C[C]=[N].[CH2].[CH2].[CH2].[CH2].[CH2].[CH3].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[N].[CH]N=[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]=N[Cd].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[C]/[C]=[C]\[N].[C]=[C][C]C(C)=[N].[C]=[C][C][C]=[N].[C]C=[C].[C]N=[CH].[C]N=[C].[C][N].[Cd].[Cd].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][Cd]([N])([O])[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][Cd].[O][Cd].[O][Cd] ,2 [O]C(=O)CCC([O])=O. Metal clusters: 2 O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 4.53 A, density 1.39 g/cm3, surface area 4727.70 m2/g, accessible volume 0.29 cm3/g