(C5H3)3Co4C48N12H30SO10F3 crystallizes in the cubic P2_13 space group. The structure consists of four 1,3,5-triisopropenyl benzene molecules inside a Co4C48N12H30SO10F3 framework. In the Co4C48N12H30SO10F3 framework, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(1), one N(3), one O(1), one O(3), and two equivalent F(1) atoms to form CoN2O2F2 octahedra that share corners with two equivalent Co(1)N2O2F2 octahedra,  a cornercorner with one S(1)O4 tetrahedra, and  an edgeedge with one Co(2)O3F3 octahedra. The corner-sharing octahedral tilt angles are 54°. The Co(1)-N(1) bond length is 2.14 Å. The Co(1)-N(3) bond length is 2.12 Å. The Co(1)-O(1) bond length is 2.06 Å. The Co(1)-O(3) bond length is 2.04 Å. There is one shorter (2.08 Å) and one longer (2.11 Å) Co(1)-F(1) bond length. In the second Co site, Co(2) is bonded to three equivalent O(2) and three equivalent F(1) atoms to form edge-sharing CoO3F3 octahedra. All Co(2)-O(2) bond lengths are 2.05 Å. All Co(2)-F(1) bond lengths are 2.12 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(3) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(2) bond length is 1.26 Å. The C(1)-O(3) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1,4) atom. The C(3)-H(1,4) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a single-bond geometry to one C(2) and one H(1,4) atom. The C(7)-H(1,4) bond length is 0.93 Å. In the fifth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(1), and one H(6) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-N(1) bond length is 1.32 Å. The C(10)-H(6) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(7) atom. The C(11)-C(12) bond length is 1.36 Å. The C(11)-H(7) bond length is 0.93 Å. In the seventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(15) atom. The C(12)-C(13) bond length is 1.36 Å. The C(12)-C(15) bond length is 1.51 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(8) atom. The C(13)-H(8) bond length is 0.93 Å. In the ninth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(14)-N(1) bond length is 1.31 Å. The C(14)-H(9) bond length is 0.93 Å. In the tenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(12) and two equivalent N(2) atoms. There is one shorter (1.33 Å) and one longer (1.34 Å) C(15)-N(2) bond length. In the eleventh C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(3), and one H(10) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-N(3) bond length is 1.34 Å. The C(16)-H(10) bond length is 0.93 Å. In the twelfth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(11) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(11) bond length is 0.93 Å. In the thirteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(21) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-C(21) bond length is 1.50 Å. In the fourteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(12) atom. The C(19)-H(12) bond length is 0.93 Å. In the fifteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(13) atom. The C(20)-N(3) bond length is 1.36 Å. The C(20)-H(13) bond length is 0.93 Å. In the sixteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(18) and two equivalent N(4) atoms. There is one shorter (1.31 Å) and one longer (1.35 Å) C(21)-N(4) bond length. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(10), and one C(14) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to two equivalent C(15) atoms. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(16), and one C(20) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to two equivalent C(21) atoms. There are nine inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. S(1) is bonded to one O(4) and three equivalent O(1) atoms to form SO4 tetrahedra that share corners with three equivalent Co(1)N2O2F2 octahedra. The corner-sharing octahedral tilt angles are 51°. The S(1)-O(4) bond length is 1.45 Å. All S(1)-O(1) bond lengths are 1.50 Å. There are four inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one S(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Co(2) and one C(1) atom. In the fourth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(1) atom. F(1) is bonded in a distorted T-shaped geometry to one Co(2) and two equivalent Co(1) atoms. Linkers: 7 n1ccc(cc1)C1=NC(=[N]=C([N]1)c1ccncc1)c1ccncc1 ,4 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C([O])=O)cc3)c2)cc1. Metal clusters: 12 [Co] ,1 [O]S12O[Co](F)O[C]O[Co](O[C]O[Co](F)O1)O[C]O[Co](F)O2. The MOF has largest included sphere 8.13 A, density 0.72 g/cm3, surface area 4074.05 m2/g, accessible volume 1.08 cm3/g