CuH12(C7N2)2(C3H2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 2,3-dimethyl-1,3-butadiene molecules and four CuH12(C7N2)2 clusters. In two of the CuH12(C7N2)2 clusters, Cu(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one N(5), and one N(7) atom. The Cu(1)-N(1) bond length is 2.01 Å. The Cu(1)-N(3) bond length is 2.05 Å. The Cu(1)-N(5) bond length is 2.05 Å. The Cu(1)-N(7) bond length is 2.06 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.96 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(11)-N(3) bond length is 1.34 Å. The C(11)-H(9) bond length is 0.96 Å. In the fourth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(12) atom. The C(15)-N(3) bond length is 1.35 Å. The C(15)-H(12) bond length is 0.95 Å. In the fifth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(17) atom. The C(21)-N(5) bond length is 1.34 Å. The C(21)-H(17) bond length is 0.96 Å. In the sixth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(20) atom. The C(25)-N(5) bond length is 1.34 Å. The C(25)-H(20) bond length is 0.96 Å. In the seventh C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(25) atom. The C(31)-N(7) bond length is 1.35 Å. The C(31)-H(25) bond length is 0.96 Å. In the eighth C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(26) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-H(26) bond length is 0.96 Å. In the ninth C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(36) atom. The C(33)-C(34) bond length is 1.39 Å. The C(33)-C(36) bond length is 1.49 Å. In the tenth C site, C(34) is bonded in a distorted single-bond geometry to one C(33), one C(35), and one H(27) atom. The C(34)-C(35) bond length is 1.38 Å. The C(34)-H(27) bond length is 0.96 Å. In the eleventh C site, C(35) is bonded in a distorted trigonal planar geometry to one C(34), one N(7), and one H(28) atom. The C(35)-N(7) bond length is 1.35 Å. The C(35)-H(28) bond length is 0.96 Å. In the twelfth C site, C(36) is bonded in a trigonal planar geometry to one C(33), one C(37), and one C(40) atom. The C(36)-C(37) bond length is 1.38 Å. The C(36)-C(40) bond length is 1.39 Å. In the thirteenth C site, C(37) is bonded in a distorted single-bond geometry to one C(36) and one H(29) atom. The C(37)-H(29) bond length is 0.96 Å. In the fourteenth C site, C(40) is bonded in a distorted single-bond geometry to one C(36) and one H(32) atom. The C(40)-H(32) bond length is 0.96 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(15) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Cu(1), one C(21), and one C(25) atom. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one Cu(1), one C(31), and one C(35) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the seventh H site, H(25) is bonded in a single-bond geometry to one C(31) atom. In the eighth H site, H(26) is bonded in a single-bond geometry to one C(32) atom. In the ninth H site, H(27) is bonded in a single-bond geometry to one C(34) atom. In the tenth H site, H(28) is bonded in a single-bond geometry to one C(35) atom. In the eleventh H site, H(29) is bonded in a single-bond geometry to one C(37) atom. In the twelfth H site, H(32) is bonded in a single-bond geometry to one C(40) atom. In two of the CuH12(C7N2)2 clusters, Cu(2) is bonded in a tetrahedral geometry to one N(2), one N(4), one N(6), and one N(8) atom. The Cu(2)-N(2) bond length is 2.00 Å. The Cu(2)-N(4) bond length is 2.04 Å. The Cu(2)-N(6) bond length is 2.07 Å. The Cu(2)-N(8) bond length is 2.05 Å. There are fourteen inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-H(2) bond length is 0.96 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.48 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.96 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one C(10), one C(3), and one C(7) atom. The C(6)-C(10) bond length is 1.39 Å. The C(6)-C(7) bond length is 1.39 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 0.96 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(8)-N(2) bond length is 1.34 Å. The C(8)-H(6) bond length is 0.96 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(2), and one H(7) atom. The C(9)-C(10) bond length is 1.37 Å. The C(9)-N(2) bond length is 1.34 Å. The C(9)-H(7) bond length is 0.96 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(6), one C(9), and one H(8) atom. The C(10)-H(8) bond length is 0.96 Å. In the ninth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(14) atom. The C(18)-N(4) bond length is 1.34 Å. The C(18)-H(14) bond length is 0.97 Å. In the tenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(15) atom. The C(19)-N(4) bond length is 1.34 Å. The C(19)-H(15) bond length is 0.96 Å. In the eleventh C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(22) atom. The C(28)-N(6) bond length is 1.34 Å. The C(28)-H(22) bond length is 0.96 Å. In the twelfth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(23) atom. The C(29)-N(6) bond length is 1.33 Å. The C(29)-H(23) bond length is 0.96 Å. In the thirteenth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(30) atom. The C(38)-N(8) bond length is 1.34 Å. The C(38)-H(30) bond length is 0.96 Å. In the fourteenth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(31) atom. The C(39)-N(8) bond length is 1.33 Å. The C(39)-H(31) bond length is 0.96 Å. There are four inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(8), and one C(9) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(18), and one C(19) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Cu(2), one C(28), and one C(29) atom. In the fourth N site, N(8) is bonded in a trigonal planar geometry to one Cu(2), one C(38), and one C(39) atom. There are twelve inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(23) is bonded in a single-bond geometry to one C(29) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(28) atom. In the eleventh H site, H(30) is bonded in a single-bond geometry to one C(38) atom. In the twelfth H site, H(31) is bonded in a single-bond geometry to one C(39) atom. Linkers: 8 c1cc(-c2ccncc2)ccn1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 4.86 A, density 1.23 g/cm3, surface area 5090.47 m2/g, accessible volume 0.25 cm3/g