Zn7H60(C11N4)12(CH)24 crystallizes in the cubic I-43d space group. The structure consists of ninety-six 02329_fluka molecules inside a Zn7H60(C11N4)12 framework. In the Zn7H60(C11N4)12 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in an octahedral geometry to three equivalent N(1) and three equivalent N(2) atoms. All Zn(1)-N(1) bond lengths are 2.17 Å. All Zn(1)-N(2) bond lengths are 2.13 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to four equivalent N(3) atoms. All Zn(2)-N(3) bond lengths are 1.98 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(3) is bonded in a single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.42 Å. The C(3)-H(3) bond length is 0.95 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(13), one C(3), and one C(5) atom. The C(4)-C(13) bond length is 1.41 Å. The C(4)-C(5) bond length is 1.44 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(10), one C(4), and one N(1) atom. The C(5)-C(10) bond length is 1.44 Å. The C(5)-N(1) bond length is 1.34 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(4) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-H(4) bond length is 0.95 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-H(6) bond length is 0.95 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(12) bond length is 1.43 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(5), one C(9), and one N(2) atom. The C(10)-N(2) bond length is 1.36 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(7) atom. The C(11)-N(3) bond length is 1.37 Å. The C(11)-N(4) bond length is 1.33 Å. The C(11)-H(7) bond length is 0.95 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(9) and one N(4) atom. The C(12)-N(4) bond length is 1.37 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(4) and one N(3) atom. The C(13)-N(3) bond length is 1.40 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(11), and one C(13) atom. In the fourth N site, N(4) is bonded in a water-like geometry to one C(11) and one C(12) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. Linkers: 3 c1cnc2c(c1)c1ncn([Zn](n3cnc4c5cccnc5c5ncccc5c43)(n3cnc4c5cccnc5c5ncccc5c43)n3cnc4c5cccnc5c5ncccc5c43)c1c1cccnc12 ,9 C1=Nc2c(c3cccnc3c3ncccc23)[N]1. Metal clusters: 11 [Zn]. The MOF has largest included sphere 4.81 A, density 1.02 g/cm3, surface area 4407.00 m2/g, accessible volume 0.52 cm3/g