(CH)2Ag2C21N4H10O2F3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and four Ag2C21N4H10O2F3 clusters. In each Ag2C21N4H10O2F3 cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a trigonal planar geometry to one N(2), one N(4), and one O(1) atom. The Ag(1)-N(2) bond length is 2.25 Å. The Ag(1)-N(4) bond length is 2.24 Å. The Ag(1)-O(1) bond length is 2.33 Å. In the second Ag site, Ag(2) is bonded in a bent 150 degrees geometry to one N(3) and one O(2) atom. The Ag(2)-N(3) bond length is 2.27 Å. The Ag(2)-O(2) bond length is 2.33 Å. There are twenty-one inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(21), and one C(6) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(21) bond length is 1.46 Å. The C(1)-C(6) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one N(1) atom. The C(4)-N(1) bond length is 1.40 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one N(1) atom. The C(7)-C(12) bond length is 1.38 Å. The C(7)-C(8) bond length is 1.38 Å. The C(7)-N(1) bond length is 1.44 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(5) atom. The C(8)-C(9) bond length is 1.37 Å. The C(8)-H(5) bond length is 0.93 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(6) atom. The C(9)-C(10) bond length is 1.36 Å. The C(9)-H(6) bond length is 0.93 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(17), and one C(9) atom. The C(10)-C(11) bond length is 1.36 Å. The C(10)-C(17) bond length is 1.48 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(11)-H(7) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(8) atom. The C(12)-H(8) bond length is 0.93 Å. In the eleventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one N(1) atom. The C(13)-C(14) bond length is 1.36 Å. The C(13)-C(16) bond length is 1.37 Å. The C(13)-N(1) bond length is 1.41 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(9) atom. The C(14)-H(9) bond length is 0.93 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(19) and one H(10) atom. The C(15)-C(19) bond length is 1.39 Å. The C(15)-H(10) bond length is 0.93 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(16)-H(11) bond length is 0.93 Å. In the fifteenth C site, C(17) is bonded in a distorted linear geometry to one C(10) and one N(2) atom. The C(17)-N(2) bond length is 1.10 Å. In the sixteenth C site, C(18) is bonded in a distorted linear geometry to one C(19) and one N(3) atom. The C(18)-C(19) bond length is 1.44 Å. The C(18)-N(3) bond length is 1.13 Å. In the seventeenth C site, C(19) is bonded in a trigonal planar geometry to one C(15), one C(18), and one C(20) atom. The C(19)-C(20) bond length is 1.36 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(12) atom. The C(20)-H(12) bond length is 0.93 Å. In the nineteenth C site, C(21) is bonded in a distorted linear geometry to one C(1) and one N(4) atom. The C(21)-N(4) bond length is 1.09 Å. In the twentieth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(23), one O(1), and one O(2) atom. The C(22)-C(23) bond length is 1.54 Å. The C(22)-O(1) bond length is 1.24 Å. The C(22)-O(2) bond length is 1.19 Å. In the twenty-first C site, C(23) is bonded in a distorted trigonal non-coplanar geometry to one C(22), one F(1), one F(2), and one F(3) atom. The C(23)-F(1) bond length is 1.28 Å. The C(23)-F(2) bond length is 1.31 Å. The C(23)-F(3) bond length is 1.24 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(13), one C(4), and one C(7) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Ag(1) and one C(17) atom. In the third N site, N(3) is bonded in a distorted bent 150 degrees geometry to one Ag(2) and one C(18) atom. In the fourth N site, N(4) is bonded in a linear geometry to one Ag(1) and one C(21) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1) and one C(22) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(2) and one C(22) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(23) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(23) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(23) atom. Linkers: 4 N#Cc1ccc(N(c2ccc(C#N)cc2)c2ccc(C#N)cc2)cc1 ,4 [O]C(=O)C(F)(F)F. Metal clusters: 8 [Ag]. The MOF has largest included sphere 9.42 A, density 0.71 g/cm3, surface area 4150.51 m2/g, accessible volume 0.96 cm3/g