Zn2C43N3H35O8(C3H2)4 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of sixteen 2,3-dimethyl-1,3-butadiene molecules and eight Zn2C43N3H35O8 clusters. In each Zn2C43N3H35O8 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted square pyramidal geometry to one N(2), one O(12), one O(16), one O(7), and one O(9) atom. The Zn(1)-N(2) bond length is 2.05 Å. The Zn(1)-O(12) bond length is 2.01 Å. The Zn(1)-O(16) bond length is 2.02 Å. The Zn(1)-O(7) bond length is 2.02 Å. The Zn(1)-O(9) bond length is 2.01 Å. In the second Zn site, Zn(4) is bonded in a trigonal bipyramidal geometry to one N(1), one O(10), one O(3), one O(5), and one O(6) atom. The Zn(4)-N(1) bond length is 2.03 Å. The Zn(4)-O(10) bond length is 2.02 Å. The Zn(4)-O(3) bond length is 1.99 Å. The Zn(4)-O(5) bond length is 2.02 Å. The Zn(4)-O(6) bond length is 2.03 Å. There are forty-three inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(98) and one H(62) atom. The C(2)-C(98) bond length is 1.39 Å. The C(2)-H(62) bond length is 0.93 Å. In the second C site, C(6) is bonded in a distorted single-bond geometry to one C(14), one C(35), and one H(84) atom. The C(6)-C(14) bond length is 1.39 Å. The C(6)-C(35) bond length is 1.39 Å. The C(6)-H(84) bond length is 0.93 Å. In the third C site, C(7) is bonded in a distorted single-bond geometry to one N(4) atom. The C(7)-N(4) bond length is 1.38 Å. In the fourth C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(85), one H(21), one H(54), and one H(59) atom. The C(9)-C(85) bond length is 1.52 Å. The C(9)-H(21) bond length is 0.96 Å. The C(9)-H(54) bond length is 0.96 Å. The C(9)-H(59) bond length is 0.96 Å. In the fifth C site, C(10) is bonded in a trigonal non-coplanar geometry to one C(68), one H(1), one H(47), and one H(74) atom. The C(10)-C(68) bond length is 1.53 Å. The C(10)-H(1) bond length is 0.96 Å. The C(10)-H(47) bond length is 0.96 Å. The C(10)-H(74) bond length is 0.96 Å. In the sixth C site, C(12) is bonded in a trigonal planar geometry to one C(35), one C(68), and one C(95) atom. The C(12)-C(35) bond length is 1.48 Å. The C(12)-C(68) bond length is 1.39 Å. The C(12)-C(95) bond length is 1.39 Å. In the seventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(46) atom. The C(14)-N(1) bond length is 1.39 Å. The C(14)-H(46) bond length is 0.93 Å. In the eighth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(79), one O(6), and one O(7) atom. The C(17)-C(79) bond length is 1.49 Å. The C(17)-O(6) bond length is 1.24 Å. The C(17)-O(7) bond length is 1.17 Å. In the ninth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(29), one C(32), and one C(34) atom. The C(22)-C(29) bond length is 1.39 Å. The C(22)-C(32) bond length is 1.39 Å. The C(22)-C(34) bond length is 1.54 Å. In the tenth C site, C(23) is bonded in a trigonal planar geometry to one C(104), one C(28), and one C(85) atom. The C(23)-C(104) bond length is 1.39 Å. The C(23)-C(28) bond length is 1.43 Å. The C(23)-C(85) bond length is 1.39 Å. In the eleventh C site, C(25) is bonded in a bent 120 degrees geometry to one C(44), one O(5), and one O(9) atom. The C(25)-C(44) bond length is 1.55 Å. The C(25)-O(5) bond length is 1.28 Å. The C(25)-O(9) bond length is 1.27 Å. In the twelfth C site, C(26) is bonded in a single-bond geometry to one C(85) and one H(40) atom. The C(26)-C(85) bond length is 1.39 Å. The C(26)-H(40) bond length is 0.93 Å. In the thirteenth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(83), one N(2), and one H(57) atom. The C(27)-C(83) bond length is 1.39 Å. The C(27)-N(2) bond length is 1.39 Å. The C(27)-H(57) bond length is 0.93 Å. In the fourteenth C site, C(28) is bonded in a trigonal planar geometry to one C(23), one C(65), and one C(83) atom. The C(28)-C(65) bond length is 1.39 Å. The C(28)-C(83) bond length is 1.39 Å. In the fifteenth C site, C(29) is bonded in a distorted single-bond geometry to one C(22), one C(95), and one H(8) atom. The C(29)-C(95) bond length is 1.39 Å. The C(29)-H(8) bond length is 0.93 Å. In the sixteenth C site, C(32) is bonded in a distorted single-bond geometry to one C(22), one C(68), and one H(32) atom. The C(32)-C(68) bond length is 1.39 Å. The C(32)-H(32) bond length is 0.93 Å. In the seventeenth C site, C(34) is bonded in a distorted trigonal non-coplanar geometry to one C(22), one N(4), one H(43), and one H(55) atom. The C(34)-N(4) bond length is 1.48 Å. The C(34)-H(43) bond length is 0.97 Å. The C(34)-H(55) bond length is 0.97 Å. In the eighteenth C site, C(35) is bonded in a trigonal planar geometry to one C(12), one C(6), and one C(67) atom. The C(35)-C(67) bond length is 1.39 Å. In the nineteenth C site, C(39) is bonded in a bent 120 degrees geometry to one C(96), one O(10), and one O(16) atom. The C(39)-C(96) bond length is 1.50 Å. The C(39)-O(10) bond length is 1.31 Å. The C(39)-O(16) bond length is 1.23 Å. In the twentieth C site, C(40) is bonded in a trigonal non-coplanar geometry to one C(95); one H(58); and two equivalent H(26,33) atoms. The C(40)-C(95) bond length is 1.49 Å. The C(40)-H(58) bond length is 0.96 Å. Both C(40)-H(26,33) bond lengths are 0.96 Å. In the twenty-first C site, C(42) is bonded in a distorted single-bond geometry to one C(44) and one H(23,65,86) atom. The C(42)-C(44) bond length is 1.39 Å. The C(42)-H(23,65,86) bond length is 0.93 Å. In the twenty-second C site, C(44) is bonded in a trigonal planar geometry to one C(109), one C(25), and one C(42) atom. The C(44)-C(109) bond length is 1.39 Å. In the twenty-third C site, C(59) is bonded in a distorted single-bond geometry to one C(96) and one H(37,64) atom. The C(59)-C(96) bond length is 1.39 Å. The C(59)-H(37,64) bond length is 0.93 Å. In the twenty-fourth C site, C(65) is bonded in a distorted single-bond geometry to one C(102), one C(28), and one H(14) atom. The C(65)-C(102) bond length is 1.39 Å. The C(65)-H(14) bond length is 0.93 Å. In the twenty-fifth C site, C(67) is bonded in a distorted single-bond geometry to one C(35), one C(93), and one H(39) atom. The C(67)-C(93) bond length is 1.39 Å. The C(67)-H(39) bond length is 0.93 Å. In the twenty-sixth C site, C(68) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(32) atom. In the twenty-seventh C site, C(79) is bonded in a trigonal planar geometry to one C(103), one C(17), and one C(90) atom. The C(79)-C(103) bond length is 1.39 Å. The C(79)-C(90) bond length is 1.39 Å. In the twenty-eighth C site, C(80) is bonded in a trigonal non-coplanar geometry to one C(104), one H(38), one H(51), and one H(83) atom. The C(80)-C(104) bond length is 1.50 Å. The C(80)-H(38) bond length is 0.96 Å. The C(80)-H(51) bond length is 0.96 Å. The C(80)-H(83) bond length is 0.96 Å. In the twenty-ninth C site, C(83) is bonded in a distorted single-bond geometry to one C(27), one C(28), and one H(7) atom. The C(83)-H(7) bond length is 0.93 Å. In the thirtieth C site, C(85) is bonded in a trigonal planar geometry to one C(23), one C(26), and one C(9) atom. In the thirty-first C site, C(87) is bonded in a distorted single-bond geometry to one C(98) and one H(53) atom. The C(87)-C(98) bond length is 1.39 Å. The C(87)-H(53) bond length is 0.93 Å. In the thirty-second C site, C(90) is bonded in a distorted single-bond geometry to one C(79) and one H(71) atom. The C(90)-H(71) bond length is 0.93 Å. In the thirty-third C site, C(91) is bonded in a bent 120 degrees geometry to one C(98), one O(12), and one O(3) atom. The C(91)-C(98) bond length is 1.47 Å. The C(91)-O(12) bond length is 1.20 Å. The C(91)-O(3) bond length is 1.29 Å. In the thirty-fourth C site, C(93) is bonded in a distorted trigonal planar geometry to one C(67), one N(1), and one H(44) atom. The C(93)-N(1) bond length is 1.39 Å. The C(93)-H(44) bond length is 0.93 Å. In the thirty-fifth C site, C(95) is bonded in a trigonal planar geometry to one C(12), one C(29), and one C(40) atom. In the thirty-sixth C site, C(96) is bonded in a trigonal planar geometry to one C(39), one C(59), and one C(99) atom. The C(96)-C(99) bond length is 1.39 Å. In the thirty-seventh C site, C(98) is bonded in a trigonal planar geometry to one C(2), one C(87), and one C(91) atom. In the thirty-eighth C site, C(99) is bonded in a distorted single-bond geometry to one C(96) and one H(37,64) atom. The C(99)-H(37,64) bond length is 0.93 Å. In the thirty-ninth C site, C(102) is bonded in a distorted trigonal planar geometry to one C(65), one N(2), and one H(3) atom. The C(102)-N(2) bond length is 1.39 Å. The C(102)-H(3) bond length is 0.93 Å. In the fortieth C site, C(103) is bonded in a distorted single-bond geometry to one C(79) and one H(85) atom. The C(103)-H(85) bond length is 0.93 Å. In the forty-first C site, C(104) is bonded in a trigonal planar geometry to one C(107), one C(23), and one C(80) atom. The C(104)-C(107) bond length is 1.39 Å. In the forty-second C site, C(107) is bonded in a distorted single-bond geometry to one C(104) and one H(20) atom. The C(107)-H(20) bond length is 0.93 Å. In the forty-third C site, C(109) is bonded in a distorted single-bond geometry to one C(44) and one H(23,65,86) atom. The C(109)-H(23,65,86) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(4), one C(14), and one C(93) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(102), and one C(27) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one C(34), one C(7), and one H(22) atom. The N(4)-H(22) bond length is 0.86 Å. There are thirty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(102) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(83) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(29) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(65) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one C(107) atom. In the seventh H site, H(21) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(22) is bonded in a single-bond geometry to one N(4) atom. In the ninth H site, H(23,65,86) is bonded in a single-bond geometry to one C(94) atom. The H(23,65,86)-C(94) bond length is 0.93 Å. In the tenth H site, H(26,33) is bonded in a single-bond geometry to one C(40) atom. In the eleventh H site, H(32) is bonded in a single-bond geometry to one C(32) atom. In the twelfth H site, H(37,64) is bonded in a single-bond geometry to one C(99) atom. In the thirteenth H site, H(38) is bonded in a single-bond geometry to one C(80) atom. In the fourteenth H site, H(39) is bonded in a single-bond geometry to one C(67) atom. In the fifteenth H site, H(40) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(43) is bonded in a single-bond geometry to one C(34) atom. In the seventeenth H site, H(44) is bonded in a single-bond geometry to one C(93) atom. In the eighteenth H site, H(46) is bonded in a single-bond geometry to one C(14) atom. In the nineteenth H site, H(47) is bonded in a single-bond geometry to one C(10) atom. In the twentieth H site, H(51) is bonded in a single-bond geometry to one C(80) atom. In the twenty-first H site, H(53) is bonded in a single-bond geometry to one C(87) atom. In the twenty-second H site, H(54) is bonded in a single-bond geometry to one C(9) atom. In the twenty-third H site, H(55) is bonded in a single-bond geometry to one C(34) atom. In the twenty-fourth H site, H(57) is bonded in a single-bond geometry to one C(27) atom. In the twenty-fifth H site, H(58) is bonded in a single-bond geometry to one C(40) atom. In the twenty-sixth H site, H(59) is bonded in a single-bond geometry to one C(9) atom. In the twenty-seventh H site, H(62) is bonded in a single-bond geometry to one C(2) atom. In the twenty-eighth H site, H(71) is bonded in a single-bond geometry to one C(90) atom. In the twenty-ninth H site, H(74) is bonded in a single-bond geometry to one C(10) atom. In the thirtieth H site, H(83) is bonded in a single-bond geometry to one C(80) atom. In the thirty-first H site, H(84) is bonded in a single-bond geometry to one C(6) atom. In the thirty-second H site, H(85) is bonded in a single-bond geometry to one C(103) atom. There are eight inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(91) atom. In the second O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(25) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(17) atom. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. In the fifth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the sixth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(39) atom. In the seventh O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(91) atom. In the eighth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(39) atom. Linkers: 8 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cc2)cc1 ,4 Cc1cc(CNc2cc(C)c(-c3ccncc3)c(C)c2)cc(C)c1-c1ccncc1. Metal clusters: 4 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 8.35 A, density 0.61 g/cm3, surface area 5035.05 m2/g, accessible volume 1.07 cm3/g