Mo2C11H14(N3O)2(CH)2CH2 crystallizes in the orthorhombic Pnma space group. The structure consists of eight 02329_fluka molecules and four 02329_fluka molecules inside a Mo2C11H14(N3O)2 framework. In the Mo2C11H14(N3O)2 framework, Mo(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Mo(1)-N(1) bond length is 2.37 Å. The Mo(1)-N(2) bond length is 2.37 Å. The Mo(1)-O(1) bond length is 1.93 Å. The Mo(1)-O(2) bond length is 1.90 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.31 Å. The C(1)-N(3) bond length is 1.36 Å. The C(1)-H(1) bond length is 0.94 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(4), and one H(2) atom. The C(2)-N(2) bond length is 1.31 Å. The C(2)-N(4) bond length is 1.35 Å. The C(2)-H(2) bond length is 0.94 Å. In the third C site, C(3) is bonded in a water-like geometry to one C(8) and two equivalent H(4,5) atoms. The C(3)-C(8) bond length is 1.53 Å. Both C(3)-H(4,5) bond lengths are 0.98 Å. In the fourth C site, C(5) is bonded in a water-like geometry to one C(6) and two equivalent H(7,8) atoms. The C(5)-C(6) bond length is 1.53 Å. Both C(5)-H(7,8) bond lengths are 0.98 Å. In the fifth C site, C(6) is bonded to one C(7), two equivalent C(5), and one N(3) atom to form distorted corner-sharing CC3N tetrahedra. The C(6)-C(7) bond length is 1.53 Å. The C(6)-N(3) bond length is 1.49 Å. In the sixth C site, C(7) is bonded in a water-like geometry to one C(6), one C(8), and two equivalent H(3) atoms. The C(7)-C(8) bond length is 1.53 Å. Both C(7)-H(3) bond lengths are 0.97 Å. In the seventh C site, C(8) is bonded to one C(7), two equivalent C(3), and one N(4) atom to form distorted corner-sharing CC3N tetrahedra. The C(8)-N(4) bond length is 1.49 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Mo(1), one C(1), and one N(1) atom. The N(1)-N(1) bond length is 1.39 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Mo(1), one C(2), and one N(2) atom. The N(2)-N(2) bond length is 1.38 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(6) and two equivalent C(1) atoms. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(8) and two equivalent C(2) atoms. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4,5) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7,8) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to two equivalent Mo(1) atoms. In the second O site, O(2) is bonded in a linear geometry to two equivalent Mo(1) atoms. Linkers: 4 c1nncn1[C@]12C[C@H]3C[C@H](C[C@](n4cnnc4)(C3)C1)C2. Metal clusters: 8 [Mo]. The MOF has largest included sphere 3.89 A, density 1.40 g/cm3, surface area 3530.42 m2/g, accessible volume 0.40 cm3/g