Cu4C13P4H13(NO7)2CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a Cu4C13P4H13(NO7)2 framework. In the Cu4C13P4H13(NO7)2 framework, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one N(1), one O(1), one O(11), one O(13), and one O(9) atom to form distorted CuNO4 trigonal bipyramids that share  a cornercorner with one P(1)CO3 tetrahedra,  a cornercorner with one P(3)CO3 tetrahedra, and corners with two equivalent P(4)CO3 tetrahedra. The Cu(1)-N(1) bond length is 2.05 Å. The Cu(1)-O(1) bond length is 2.02 Å. The Cu(1)-O(11) bond length is 1.99 Å. The Cu(1)-O(13) bond length is 2.37 Å. The Cu(1)-O(9) bond length is 1.90 Å. In the second Cu site, Cu(2) is bonded in a rectangular see-saw-like geometry to one O(1), one O(10), one O(13), and one O(5) atom. The Cu(2)-O(1) bond length is 1.96 Å. The Cu(2)-O(10) bond length is 1.91 Å. The Cu(2)-O(13) bond length is 1.98 Å. The Cu(2)-O(5) bond length is 1.95 Å. In the third Cu site, Cu(3) is bonded in a rectangular see-saw-like geometry to one N(2), one O(2), one O(4), and one O(8) atom. The Cu(3)-N(2) bond length is 2.04 Å. The Cu(3)-O(2) bond length is 1.92 Å. The Cu(3)-O(4) bond length is 2.00 Å. The Cu(3)-O(8) bond length is 1.91 Å. In the fourth Cu site, Cu(4) is bonded in a linear geometry to one O(12) and one O(6) atom. The Cu(4)-O(12) bond length is 1.90 Å. The Cu(4)-O(6) bond length is 1.94 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted tetrahedral geometry to one C(2), one P(1), one P(2), and one O(7) atom. The C(1)-C(2) bond length is 1.56 Å. The C(1)-P(1) bond length is 1.83 Å. The C(1)-P(2) bond length is 1.86 Å. The C(1)-O(7) bond length is 1.44 Å. In the second C site, C(2) is bonded in a water-like geometry to one C(1); one C(3); and two equivalent H(3,4) atoms. The C(2)-C(3) bond length is 1.52 Å. Both C(2)-H(3,4) bond lengths are 0.97 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(7) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-C(7) bond length is 1.38 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(5) atom. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(5) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(6) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(3) and one H(8) atom. The C(7)-H(8) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a distorted tetrahedral geometry to one C(9), one P(3), one P(4), and one O(14) atom. The C(8)-C(9) bond length is 1.55 Å. The C(8)-P(3) bond length is 1.85 Å. The C(8)-P(4) bond length is 1.85 Å. The C(8)-O(14) bond length is 1.45 Å. In the eighth C site, C(9) is bonded in a water-like geometry to one C(10); one C(8); and two equivalent H(9,10) atoms. The C(9)-C(10) bond length is 1.51 Å. Both C(9)-H(9,10) bond lengths are 0.97 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(9) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-C(14) bond length is 1.39 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(11) atom. The C(11)-H(11) bond length is 0.93 Å. In the eleventh C site, C(12) is bonded in a single-bond geometry to one C(13) and one H(12) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-H(12) bond length is 0.93 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one N(2), and one H(13) atom. The C(13)-N(2) bond length is 1.36 Å. The C(13)-H(13) bond length is 0.93 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(14) atom. The C(14)-N(2) bond length is 1.33 Å. The C(14)-H(14) bond length is 0.93 Å. There are four inequivalent P sites. In the first P site, P(1) is bonded to one C(1), one O(1), one O(2), and one O(3) atom to form PCO3 tetrahedra that share  a cornercorner with one P(2)CO3 tetrahedra and  a cornercorner with one Cu(1)NO4 trigonal bipyramid. The P(1)-O(1) bond length is 1.54 Å. The P(1)-O(2) bond length is 1.49 Å. The P(1)-O(3) bond length is 1.52 Å. In the second P site, P(2) is bonded to one C(1), one O(4), one O(5), and one O(6) atom to form corner-sharing PCO3 tetrahedra. The P(2)-O(4) bond length is 1.53 Å. The P(2)-O(5) bond length is 1.53 Å. The P(2)-O(6) bond length is 1.51 Å. In the third P site, P(3) is bonded to one C(8), one O(10), one O(8), and one O(9) atom to form PCO3 tetrahedra that share  a cornercorner with one P(4)CO3 tetrahedra and  a cornercorner with one Cu(1)NO4 trigonal bipyramid. The P(3)-O(10) bond length is 1.53 Å. The P(3)-O(8) bond length is 1.51 Å. The P(3)-O(9) bond length is 1.53 Å. In the fourth P site, P(4) is bonded to one C(8), one O(11), one O(12), and one O(13) atom to form PCO3 tetrahedra that share  a cornercorner with one P(3)CO3 tetrahedra and corners with two equivalent Cu(1)NO4 trigonal bipyramids. The P(4)-O(11) bond length is 1.53 Å. The P(4)-O(12) bond length is 1.51 Å. The P(4)-O(13) bond length is 1.53 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(4), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(3), one C(13), and one C(14) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. The H(1)-O(7) bond length is 0.82 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(14) atom. The H(2)-O(14) bond length is 0.82 Å. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(14) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one Cu(2), and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(3) and one P(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one P(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one P(2) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Cu(4) and one P(2) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one C(1) and one H(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Cu(3) and one P(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Cu(2) and one P(3) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Cu(1) and one P(4) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Cu(4) and one P(4) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(2), and one P(4) atom. In the fourteenth O site, O(14) is bonded in a water-like geometry to one C(8) and one H(2) atom. Linkers: 4 [O]P([O])(=O)C(O)(Cc1cccnc1)P([O])([O])=O. Metal clusters: 8 [Cu]. The MOF has largest included sphere 4.33 A, density 2.00 g/cm3, surface area 2987.25 m2/g, accessible volume 0.18 cm3/g