AgAlC12(NO2)3(CH3)6 crystallizes in the cubic P2_13 space group. The structure consists of twenty-four 02329_fluka molecules inside a AgAlC12(NO2)3 framework. In the AgAlC12(NO2)3 framework, Ag(1) is bonded in a distorted trigonal planar geometry to three equivalent N(1) atoms. All Ag(1)-N(1) bond lengths are 2.28 Å. Al(1) is bonded in an octahedral geometry to three equivalent O(1) and three equivalent O(2) atoms. All Al(1)-O(1) bond lengths are 1.87 Å. All Al(1)-O(2) bond lengths are 1.86 Å. There are four inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one O(1) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-O(1) bond length is 1.27 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.43 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one O(2) atom. The C(4)-O(2) bond length is 1.27 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one N(1) atom. The C(6)-N(1) bond length is 1.15 Å. N(1) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one C(6) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Al(1) and one C(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Al(1) and one C(4) atom. Linkers: 12 CC(=O)[C](C#N)C(C)=O. Metal clusters: 4 [Al] ,4 [Ag]. The MOF has largest included sphere 4.99 A, density 1.21 g/cm3, surface area 4557.62 m2/g, accessible volume 0.34 cm3/g