(Zn4H9(C7O4)3)4(C9H8O4)3 is Indium-derived structured and crystallizes in the tetragonal P-4n2 space group. The structure is zero-dimensional and consists of twelve 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules and two Zn4H9(C7O4)3 clusters. In each Zn4H9(C7O4)3 cluster, there are eight inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted trigonal non-coplanar geometry to one O(3), one O(8), and one O(9) atom. The Zn(1)-O(3) bond length is 2.01 Å. The Zn(1)-O(8) bond length is 2.00 Å. The Zn(1)-O(9) bond length is 1.96 Å. In the second Zn site, Zn(2) is bonded in a trigonal non-coplanar geometry to one O(14), one O(23), and one O(28) atom. The Zn(2)-O(14) bond length is 1.97 Å. The Zn(2)-O(23) bond length is 1.86 Å. The Zn(2)-O(28) bond length is 2.03 Å. In the third Zn site, Zn(3) is bonded in a 3-coordinate geometry to one O(2), one O(27), and one O(6) atom. The Zn(3)-O(2) bond length is 1.95 Å. The Zn(3)-O(27) bond length is 1.95 Å. The Zn(3)-O(6) bond length is 1.95 Å. In the fourth Zn site, Zn(4) is bonded in a trigonal non-coplanar geometry to one O(13), one O(22), and one O(5) atom. The Zn(4)-O(13) bond length is 1.95 Å. The Zn(4)-O(22) bond length is 1.89 Å. The Zn(4)-O(5) bond length is 1.94 Å. In the fifth Zn site, Zn(5) is bonded in a trigonal non-coplanar geometry to one O(11), one O(24), and one O(4) atom. The Zn(5)-O(11) bond length is 1.91 Å. The Zn(5)-O(24) bond length is 1.96 Å. The Zn(5)-O(4) bond length is 1.88 Å. In the sixth Zn site, Zn(6) is bonded in a trigonal non-coplanar geometry to one O(1), one O(20), and one O(7) atom. The Zn(6)-O(1) bond length is 1.99 Å. The Zn(6)-O(20) bond length is 1.95 Å. The Zn(6)-O(7) bond length is 1.95 Å. In the seventh Zn site, Zn(7) is bonded in a trigonal non-coplanar geometry to one O(12), one O(15), and one O(30) atom. The Zn(7)-O(12) bond length is 1.94 Å. The Zn(7)-O(15) bond length is 1.97 Å. The Zn(7)-O(30) bond length is 1.93 Å. In the eighth Zn site, Zn(8) is bonded in a trigonal non-coplanar geometry to one O(10), one O(16), and one O(25) atom. The Zn(8)-O(10) bond length is 2.04 Å. The Zn(8)-O(16) bond length is 1.89 Å. The Zn(8)-O(25) bond length is 1.94 Å. There are forty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(13), and one O(23) atom. The C(1)-C(17) bond length is 1.59 Å. The C(1)-O(13) bond length is 1.45 Å. The C(1)-O(23) bond length is 1.04 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(4) atom. The C(2)-C(5) bond length is 1.56 Å. The C(2)-O(1) bond length is 1.28 Å. The C(2)-O(4) bond length is 1.16 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(11), one C(49), and one C(8) atom. The C(3)-C(11) bond length is 1.40 Å. The C(3)-C(49) bond length is 1.54 Å. The C(3)-C(8) bond length is 1.34 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(24), and one C(29) atom. The C(5)-C(24) bond length is 1.42 Å. The C(5)-C(29) bond length is 1.30 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(12), one C(33), and one C(42) atom. The C(6)-C(12) bond length is 1.46 Å. The C(6)-C(33) bond length is 1.54 Å. The C(6)-C(42) bond length is 1.35 Å. In the sixth C site, C(7) is bonded in a distorted bent 150 degrees geometry to one C(26), one O(15), and one O(3) atom. The C(7)-C(26) bond length is 1.67 Å. The C(7)-O(15) bond length is 1.27 Å. The C(7)-O(3) bond length is 1.03 Å. In the seventh C site, C(8) is bonded in a single-bond geometry to one C(3) and one H(20) atom. The C(8)-H(20) bond length is 0.93 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(14), one C(25), and one C(45) atom. The C(9)-C(14) bond length is 1.51 Å. The C(9)-C(25) bond length is 1.38 Å. The C(9)-C(45) bond length is 1.32 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(21) and one H(1) atom. The C(10)-C(21) bond length is 1.38 Å. The C(10)-H(1) bond length is 0.93 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(21), one C(3), and one H(8) atom. The C(11)-C(21) bond length is 1.36 Å. The C(11)-H(8) bond length is 0.93 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(17), one C(6), and one H(10) atom. The C(12)-C(17) bond length is 1.35 Å. The C(12)-H(10) bond length is 0.93 Å. In the twelfth C site, C(13) is bonded in a distorted bent 150 degrees geometry to one C(20), one O(11), and one O(20) atom. The C(13)-C(20) bond length is 1.60 Å. The C(13)-O(11) bond length is 1.17 Å. The C(13)-O(20) bond length is 1.22 Å. In the thirteenth C site, C(14) is bonded in a bent 120 degrees geometry to one C(9), one O(12), and one O(8) atom. The C(14)-O(12) bond length is 1.25 Å. The C(14)-O(8) bond length is 1.26 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(30), one C(45), and one C(55) atom. The C(16)-C(30) bond length is 1.50 Å. The C(16)-C(45) bond length is 1.35 Å. The C(16)-C(55) bond length is 1.42 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(1), one C(12), and one C(19) atom. The C(17)-C(19) bond length is 1.45 Å. In the sixteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(17) and one H(16) atom. The C(19)-H(16) bond length is 0.93 Å. In the seventeenth C site, C(20) is bonded in a trigonal planar geometry to one C(13), one C(22), and one C(51) atom. The C(20)-C(22) bond length is 1.32 Å. The C(20)-C(51) bond length is 1.50 Å. In the eighteenth C site, C(21) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(35) atom. The C(21)-C(35) bond length is 1.50 Å. In the nineteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(20), one C(37), and one H(9) atom. The C(22)-C(37) bond length is 1.43 Å. The C(22)-H(9) bond length is 0.93 Å. In the twentieth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(47), one C(5), and one H(12) atom. The C(24)-C(47) bond length is 1.39 Å. The C(24)-H(12) bond length is 0.93 Å. In the twenty-first C site, C(25) is bonded in a distorted single-bond geometry to one C(9) and one H(11) atom. The C(25)-H(11) bond length is 0.93 Å. In the twenty-second C site, C(26) is bonded in a trigonal planar geometry to one C(31), one C(41), and one C(7) atom. The C(26)-C(31) bond length is 1.31 Å. The C(26)-C(41) bond length is 1.43 Å. In the twenty-third C site, C(28) is bonded in a trigonal planar geometry to one C(32), one C(41), and one C(44) atom. The C(28)-C(32) bond length is 1.44 Å. The C(28)-C(41) bond length is 1.39 Å. The C(28)-C(44) bond length is 1.38 Å. In the twenty-fourth C site, C(29) is bonded in a distorted single-bond geometry to one C(5) and one H(23) atom. The C(29)-H(23) bond length is 0.93 Å. In the twenty-fifth C site, C(30) is bonded in a distorted single-bond geometry to one C(16) and one H(22) atom. The C(30)-H(22) bond length is 0.93 Å. In the twenty-sixth C site, C(31) is bonded in a distorted single-bond geometry to one C(26) and one H(7) atom. The C(31)-H(7) bond length is 0.93 Å. In the twenty-seventh C site, C(32) is bonded in a bent 120 degrees geometry to one C(28), one O(28), and one O(5) atom. The C(32)-O(28) bond length is 1.25 Å. The C(32)-O(5) bond length is 1.25 Å. In the twenty-eighth C site, C(33) is bonded in a distorted bent 150 degrees geometry to one C(6), one O(2), and one O(25) atom. The C(33)-O(2) bond length is 1.25 Å. The C(33)-O(25) bond length is 1.20 Å. In the twenty-ninth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(30), and one O(9) atom. The C(35)-O(30) bond length is 1.28 Å. The C(35)-O(9) bond length is 1.15 Å. In the thirtieth C site, C(37) is bonded in a trigonal planar geometry to one C(22), one C(40), and one C(52) atom. The C(37)-C(40) bond length is 1.39 Å. The C(37)-C(52) bond length is 1.39 Å. In the thirty-first C site, C(39) is bonded in a single-bond geometry to one C(47) and one H(13) atom. The C(39)-C(47) bond length is 1.37 Å. The C(39)-H(13) bond length is 0.93 Å. In the thirty-second C site, C(40) is bonded in a bent 120 degrees geometry to one C(37), one O(10), and one O(6) atom. The C(40)-O(10) bond length is 1.30 Å. The C(40)-O(6) bond length is 1.22 Å. In the thirty-third C site, C(41) is bonded in a distorted single-bond geometry to one C(26), one C(28), and one H(25) atom. The C(41)-H(25) bond length is 0.93 Å. In the thirty-fourth C site, C(42) is bonded in a single-bond geometry to one C(6) and one H(21) atom. The C(42)-H(21) bond length is 0.93 Å. In the thirty-fifth C site, C(44) is bonded in a distorted single-bond geometry to one C(28) and one H(14) atom. The C(44)-H(14) bond length is 0.93 Å. In the thirty-sixth C site, C(45) is bonded in a distorted single-bond geometry to one C(16), one C(9), and one H(19) atom. The C(45)-H(19) bond length is 0.93 Å. In the thirty-seventh C site, C(47) is bonded in a trigonal planar geometry to one C(24), one C(39), and one C(54) atom. The C(47)-C(54) bond length is 1.71 Å. In the thirty-eighth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(24), and one O(7) atom. The C(49)-O(24) bond length is 1.16 Å. The C(49)-O(7) bond length is 1.25 Å. In the thirty-ninth C site, C(51) is bonded in a single-bond geometry to one C(20) and one H(30) atom. The C(51)-H(30) bond length is 0.93 Å. In the fortieth C site, C(52) is bonded in a distorted single-bond geometry to one C(37) and one H(15) atom. The C(52)-H(15) bond length is 0.93 Å. In the forty-first C site, C(54) is bonded in a 2-coordinate geometry to one C(47), one O(16), and one O(27) atom. The C(54)-O(16) bond length is 1.11 Å. The C(54)-O(27) bond length is 1.25 Å. In the forty-second C site, C(55) is bonded in a bent 120 degrees geometry to one C(16), one O(14), and one O(22) atom. The C(55)-O(14) bond length is 1.31 Å. The C(55)-O(22) bond length is 1.21 Å. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(31) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(22) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(25) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(39) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(44) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(52) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(45) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(8) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(42) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(30) atom. In the sixteenth H site, H(23) is bonded in a single-bond geometry to one C(29) atom. In the seventeenth H site, H(25) is bonded in a single-bond geometry to one C(41) atom. In the eighteenth H site, H(30) is bonded in a single-bond geometry to one C(51) atom. There are twenty-four inequivalent O sites. In the first O site, O(27) is bonded in a single-bond geometry to one Zn(3) and one C(54) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Zn(6) and one C(2) atom. In the third O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(33) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(5) and one C(2) atom. In the sixth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(32) atom. In the seventh O site, O(6) is bonded in a bent 150 degrees geometry to one Zn(3) and one C(40) atom. In the eighth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(6) and one C(49) atom. In the ninth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the tenth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(35) atom. In the eleventh O site, O(10) is bonded in a distorted single-bond geometry to one Zn(8) and one C(40) atom. In the twelfth O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Zn(5) and one C(13) atom. In the thirteenth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Zn(7) and one C(14) atom. In the fourteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Zn(4) and one C(1) atom. In the fifteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(55) atom. In the sixteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Zn(7) and one C(7) atom. In the seventeenth O site, O(16) is bonded in a distorted single-bond geometry to one Zn(8) and one C(54) atom. In the eighteenth O site, O(20) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(13) atom. In the nineteenth O site, O(22) is bonded in a distorted bent 150 degrees geometry to one Zn(4) and one C(55) atom. In the twentieth O site, O(23) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(1) atom. In the twenty-first O site, O(24) is bonded in a distorted bent 120 degrees geometry to one Zn(5) and one C(49) atom. In the twenty-second O site, O(25) is bonded in a bent 120 degrees geometry to one Zn(8) and one C(33) atom. In the twenty-third O site, O(28) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(32) atom. In the twenty-fourth O site, O(30) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(35) atom. Linkers: 14 [O]C(=O)c1cc(OCC(COc2cc(C([O])=O)cc(C([O])=O)c2)(COc2cc(C([O])=O)cc(C([O])=O)c2)COc2cc(C([O])=O)cc(C([O])=O)c2)cc(C([O])=O)c1. Metal clusters: 32 [C]1O[Zn]2O[C]O[Zn](O1)O[C]O2. RCSR code: tee. The MOF has largest included sphere 11.41 A, density 0.70 g/cm3, surface area 3624.73 m2/g, accessible volume 1.04 cm3/g