(Co3H13(C2O)11)2(CH)16(C2O)5 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixty-four 02329_fluka molecules, twenty dimethyl ether molecules, and four Co3H13(C2O)11 clusters. In each Co3H13(C2O)11 cluster, there are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(13), one O(4), one O(6), and two equivalent O(8) atoms to form edge-sharing CoO6 octahedra. The Co(1)-O(1) bond length is 2.05 Å. The Co(1)-O(13) bond length is 2.09 Å. The Co(1)-O(4) bond length is 2.14 Å. The Co(1)-O(6) bond length is 2.03 Å. There is one shorter (2.11 Å) and one longer (2.13 Å) Co(1)-O(8) bond length. In the second Co site, Co(2) is bonded in a rectangular see-saw-like geometry to one O(12), one O(13), one O(2), and one O(7) atom. The Co(2)-O(12) bond length is 2.04 Å. The Co(2)-O(13) bond length is 2.07 Å. The Co(2)-O(2) bond length is 2.05 Å. The Co(2)-O(7) bond length is 2.08 Å. In the third Co site, Co(3) is bonded in a 5-coordinate geometry to one O(11), one O(13), one O(4), one O(5), and one O(9) atom. The Co(3)-O(11) bond length is 2.03 Å. The Co(3)-O(13) bond length is 2.02 Å. The Co(3)-O(4) bond length is 2.43 Å. The Co(3)-O(5) bond length is 2.04 Å. The Co(3)-O(9) bond length is 2.10 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(2) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.95 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(7)-H(5) bond length is 0.95 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(4), and one O(5) atom. The C(8)-C(9) bond length is 1.48 Å. The C(8)-O(4) bond length is 1.28 Å. The C(8)-O(5) bond length is 1.27 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.39 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(6,9) atom. The C(10)-H(6,9) bond length is 0.95 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(6,9) atom. The C(14)-H(6,9) bond length is 0.95 Å. In the tenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(6), and one O(7) atom. The C(15)-C(16) bond length is 1.51 Å. The C(15)-O(6) bond length is 1.25 Å. The C(15)-O(7) bond length is 1.25 Å. In the eleventh C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-C(21) bond length is 1.39 Å. In the twelfth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(10) atom. The C(17)-H(10) bond length is 0.95 Å. In the thirteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(13) atom. The C(21)-H(13) bond length is 0.95 Å. In the fourteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(8), and one O(9) atom. The C(22)-C(23) bond length is 1.49 Å. The C(22)-O(8) bond length is 1.27 Å. The C(22)-O(9) bond length is 1.26 Å. In the fifteenth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-C(28) bond length is 1.40 Å. In the sixteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(14) atom. The C(24)-H(14) bond length is 0.95 Å. In the seventeenth C site, C(28) is bonded in a single-bond geometry to one C(23) and one H(17) atom. The C(28)-H(17) bond length is 0.95 Å. In the eighteenth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(11), and one O(12) atom. The C(29)-C(30) bond length is 1.51 Å. The C(29)-O(11) bond length is 1.26 Å. The C(29)-O(12) bond length is 1.25 Å. In the nineteenth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(35) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-C(35) bond length is 1.40 Å. In the twentieth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(30), one C(32), and one H(18) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-H(18) bond length is 0.95 Å. In the twenty-first C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(19) atom. The C(32)-H(19) bond length is 0.95 Å. In the twenty-second C site, C(35) is bonded in a distorted single-bond geometry to one C(30) and one H(21) atom. The C(35)-H(21) bond length is 0.95 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(13) atom. The H(1)-O(13) bond length is 0.85 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6,9) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(28) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(31) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(32) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(35) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(2) and one C(1) atom. In the third O site, O(4) is bonded in a 3-coordinate geometry to one Co(1), one Co(3), and one C(8) atom. In the fourth O site, O(5) is bonded in a water-like geometry to one Co(3) and one C(8) atom. In the fifth O site, O(11) is bonded in a bent 120 degrees geometry to one Co(3) and one C(29) atom. In the sixth O site, O(12) is bonded in a bent 150 degrees geometry to one Co(2) and one C(29) atom. In the seventh O site, O(6) is bonded in a bent 120 degrees geometry to one Co(1) and one C(15) atom. In the eighth O site, O(7) is bonded in a 2-coordinate geometry to one Co(2) and one C(15) atom. In the ninth O site, O(8) is bonded in a distorted trigonal planar geometry to two equivalent Co(1) and one C(22) atom. In the tenth O site, O(9) is bonded in a bent 120 degrees geometry to one Co(3) and one C(22) atom. In the eleventh O site, O(13) is bonded in a distorted single-bond geometry to one Co(1), one Co(2), one Co(3), and one H(1) atom. Linkers: 20 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 O[Co@]12O[C]O[Co]3O[C]O[Co](O[C]O3)(O[C]O1)O[C]O[Co@]1(O)O[C]O[Co]3O[C]O[Co](O[C]O3)(O[C]O2)O[C]O1. The MOF has largest included sphere 7.16 A, density 1.01 g/cm3, surface area 3964.33 m2/g, accessible volume 0.56 cm3/g