Zn3H2(CO2)8(CH)8(CH2)4(CH3)4(C35H28O8)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four 02329_fluka molecules, four 02329_fluka molecules, two C35H28O8 clusters, and one Zn3H2(CO2)8 cluster. In each C35H28O8 cluster, there are thirty-five inequivalent C sites. In the first C site, C(41) is bonded in a tetrahedral geometry to one H(32); two equivalent H(30,31); and one O(8) atom. The C(41)-H(32) bond length is 0.96 Å. Both C(41)-H(30,31) bond lengths are 0.96 Å. The C(41)-O(8) bond length is 1.49 Å. In the second C site, C(42) is bonded in a 3-coordinate geometry to one H(33), one H(34), and one O(9) atom. The C(42)-H(33) bond length is 0.97 Å. The C(42)-H(34) bond length is 0.97 Å. The C(42)-O(9) bond length is 1.41 Å. In the third C site, C(47) is bonded in a tetrahedral geometry to three equivalent H(40,41,42) and one O(16) atom. All C(47)-H(40,41,42) bond lengths are 0.96 Å. The C(47)-O(16) bond length is 1.41 Å. In the fourth C site, C(45) is bonded in a distorted trigonal non-coplanar geometry to one H(38), one H(39), and one O(13) atom. The C(45)-H(38) bond length is 0.97 Å. The C(45)-H(39) bond length is 0.97 Å. The C(45)-O(13) bond length is 1.36 Å. In the fifth C site, C(44) is bonded in a tetrahedral geometry to one H(35); two equivalent H(36,37); and one O(12) atom. The C(44)-H(35) bond length is 0.96 Å. Both C(44)-H(36,37) bond lengths are 0.96 Å. The C(44)-O(12) bond length is 1.38 Å. In the sixth C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one O(1) atom. The C(2)-C(3) bond length is 1.32 Å. The C(2)-O(1) bond length is 1.39 Å. In the seventh C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(33), and one C(4) atom. The C(3)-C(33) bond length is 1.55 Å. The C(3)-C(4) bond length is 1.41 Å. In the eighth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-H(2) bond length is 0.93 Å. In the ninth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.35 Å. The C(5)-C(7) bond length is 1.53 Å. In the tenth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one O(4) atom. The C(6)-O(4) bond length is 1.40 Å. In the eleventh C site, C(7) is bonded in a single-bond geometry to one C(10), one C(5), one C(8), and one H(3) atom. The C(7)-C(10) bond length is 1.50 Å. The C(7)-C(8) bond length is 1.59 Å. The C(7)-H(3) bond length is 0.98 Å. In the twelfth C site, C(8) is bonded in a bent 120 degrees geometry to one C(7) and one C(9) atom. The C(8)-C(9) bond length is 1.51 Å. In the thirteenth C site, C(9) is bonded in a single-bond geometry to one C(8) atom. In the fourteenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(7) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.40 Å. In the fifteenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(4) atom. The C(11)-C(12) bond length is 1.34 Å. The C(11)-H(4) bond length is 0.93 Å. In the sixteenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(16) atom. The C(12)-C(13) bond length is 1.42 Å. The C(12)-C(16) bond length is 1.52 Å. In the seventeenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one O(8) atom. The C(13)-O(8) bond length is 1.36 Å. In the eighteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one O(5) atom. The C(15)-O(5) bond length is 1.38 Å. In the nineteenth C site, C(16) is bonded in a single-bond geometry to one C(12), one C(19), and one H(6) atom. The C(16)-C(19) bond length is 1.52 Å. The C(16)-H(6) bond length is 0.98 Å. In the twentieth C site, C(19) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-C(24) bond length is 1.40 Å. In the twenty-first C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one O(9) atom. The C(20)-O(9) bond length is 1.39 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one O(12) atom. The C(22)-C(23) bond length is 1.37 Å. The C(22)-O(12) bond length is 1.35 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(25) atom. The C(23)-C(24) bond length is 1.42 Å. The C(23)-C(25) bond length is 1.52 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(19), one C(23), and one H(13) atom. The C(24)-H(13) bond length is 0.93 Å. In the twenty-fifth C site, C(25) is bonded in a single-bond geometry to one C(23), one C(26), one C(27), and one H(14) atom. The C(25)-C(26) bond length is 1.54 Å. The C(25)-C(27) bond length is 1.51 Å. The C(25)-H(14) bond length is 0.98 Å. In the twenty-sixth C site, C(26) is bonded in a single-bond geometry to one C(25) atom. In the twenty-seventh C site, C(27) is bonded in a trigonal planar geometry to one C(25), one C(28), and one C(32) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-C(32) bond length is 1.41 Å. In the twenty-eighth C site, C(28) is bonded in a distorted single-bond geometry to one C(27), one C(29), and one H(15) atom. The C(28)-C(29) bond length is 1.35 Å. The C(28)-H(15) bond length is 0.93 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(33) atom. The C(29)-C(30) bond length is 1.37 Å. The C(29)-C(33) bond length is 1.47 Å. In the thirtieth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one O(16) atom. The C(30)-O(16) bond length is 1.41 Å. In the thirty-first C site, C(32) is bonded in a single-bond geometry to one C(27) and one O(13) atom. The C(32)-O(13) bond length is 1.33 Å. In the thirty-second C site, C(33) is bonded in a single-bond geometry to one C(29), one C(3), and one H(17) atom. The C(33)-H(17) bond length is 0.98 Å. In the thirty-third C site, C(36) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(23,24) and one O(1) atom. Both C(36)-H(23,24) bond lengths are 0.97 Å. The C(36)-O(1) bond length is 1.41 Å. In the thirty-fourth C site, C(38) is bonded in a tetrahedral geometry to one H(26); two equivalent H(25,27); and one O(4) atom. The C(38)-H(26) bond length is 0.96 Å. Both C(38)-H(25,27) bond lengths are 0.96 Å. The C(38)-O(4) bond length is 1.37 Å. In the thirty-fifth C site, C(39) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(28,29) and one O(5) atom. Both C(39)-H(28,29) bond lengths are 0.97 Å. The C(39)-O(5) bond length is 1.43 Å. There are twenty-one inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(24) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(25) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(28) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(33) atom. In the ninth H site, H(23,24) is bonded in a single-bond geometry to one C(36) atom. In the tenth H site, H(25,27) is bonded in a single-bond geometry to one C(38) atom. In the eleventh H site, H(26) is bonded in a single-bond geometry to one C(38) atom. In the twelfth H site, H(28,29) is bonded in a single-bond geometry to one C(39) atom. In the thirteenth H site, H(30,31) is bonded in a single-bond geometry to one C(41) atom. In the fourteenth H site, H(32) is bonded in a single-bond geometry to one C(41) atom. In the fifteenth H site, H(33) is bonded in a single-bond geometry to one C(42) atom. In the sixteenth H site, H(34) is bonded in a single-bond geometry to one C(42) atom. In the seventeenth H site, H(35) is bonded in a single-bond geometry to one C(44) atom. In the eighteenth H site, H(36,37) is bonded in a single-bond geometry to one C(44) atom. In the nineteenth H site, H(38) is bonded in a single-bond geometry to one C(45) atom. In the twentieth H site, H(39) is bonded in a single-bond geometry to one C(45) atom. In the twenty-first H site, H(40,41,42) is bonded in a single-bond geometry to one C(47) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(2) and one C(36) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one C(38) and one C(6) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one C(15) and one C(39) atom. In the fourth O site, O(8) is bonded in a bent 120 degrees geometry to one C(13) and one C(41) atom. In the fifth O site, O(9) is bonded in a bent 120 degrees geometry to one C(20) and one C(42) atom. In the sixth O site, O(12) is bonded in a bent 120 degrees geometry to one C(22) and one C(44) atom. In the seventh O site, O(13) is bonded in a bent 120 degrees geometry to one C(32) and one C(45) atom. In the eighth O site, O(16) is bonded in a bent 120 degrees geometry to one C(30) and one C(47) atom. In the Zn3H2(CO2)8 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to one O(10), one O(15), one O(2), one O(3), and one O(7) atom. The Zn(1)-O(10) bond length is 2.01 Å. The Zn(1)-O(15) bond length is 1.95 Å. The Zn(1)-O(2) bond length is 2.32 Å. The Zn(1)-O(3) bond length is 2.22 Å. The Zn(1)-O(7) bond length is 1.96 Å. In the second Zn site, Zn(2) is bonded in a square co-planar geometry to two equivalent O(11) and two equivalent O(3) atoms. Both Zn(2)-O(11) bond lengths are 2.26 Å. Both Zn(2)-O(3) bond lengths are 2.10 Å. There are four inequivalent C sites. In the first C site, C(40) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(40)-O(6) bond length is 1.19 Å. The C(40)-O(7) bond length is 1.27 Å. In the second C site, C(43) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(11) atom. The C(43)-O(10) bond length is 1.19 Å. The C(43)-O(11) bond length is 1.36 Å. In the third C site, C(46) is bonded in a distorted bent 120 degrees geometry to one O(14) and one O(15) atom. The C(46)-O(14) bond length is 1.22 Å. The C(46)-O(15) bond length is 1.24 Å. In the fourth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(37)-O(2) bond length is 1.23 Å. The C(37)-O(3) bond length is 1.23 Å. H(43) is bonded in a single-bond geometry to one O(14) atom. The H(43)-O(14) bond length is 0.82 Å. There are eight inequivalent O sites. In the first O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(43) atom. In the second O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(43) atom. In the third O site, O(14) is bonded in a water-like geometry to one C(46) and one H(43) atom. In the fourth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(46) atom. In the fifth O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(40) atom. In the sixth O site, O(2) is bonded in a distorted L-shaped geometry to one Zn(1) and one C(37) atom. In the seventh O site, O(3) is bonded in a 3-coordinate geometry to one Zn(1), one Zn(2), and one C(37) atom. In the eighth O site, O(6) is bonded in a single-bond geometry to one C(40) atom. Linkers: 1 [C][C][C@@H]1c2cc(c(OCC([O])=O)cc2OC)[C@H](CC)c2cc(c(OCC(=O)O)cc2OC)[C@H]([C])c2cc(c(OCC([O])=O)cc2OC)[C@H](CC)c2cc1c(OCC([O])=O)cc2OC ,1 [C][C][C@H]1c2cc(c(OCC([O])=O)cc2OC)[C@@H](CC)c2cc(c(OCC(=O)O)cc2OC)[C@@H]([C])c2cc(c(OCC([O])=O)cc2OC)[C@@H](CC)c2cc1c(OCC([O])=O)cc2OC. Metal clusters: 1 O=[C]O[Zn@]1(O[C]O)O[C]O[Zn]2(O[C]O[Zn@@](O[C]O)(O[C]=O)O[C]O2)O[C]O1. RCSR code: flu. The MOF has largest included sphere 5.02 A, density 1.09 g/cm3, surface area 4906.80 m2/g, accessible volume 0.41 cm3/g