AgH6(C3N2)2(CH)2 crystallizes in the orthorhombic Cmc2_1 space group. The structure consists of thirty-two 02329_fluka molecules inside a AgH6(C3N2)2 framework. In the AgH6(C3N2)2 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a tetrahedral geometry to one N(1), one N(3), one N(5), and one N(7) atom. The Ag(1)-N(1) bond length is 2.33 Å. The Ag(1)-N(3) bond length is 2.32 Å. The Ag(1)-N(5) bond length is 2.28 Å. The Ag(1)-N(7) bond length is 2.47 Å. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one N(2), one N(4), one N(6), and one N(8) atom. The Ag(2)-N(2) bond length is 2.36 Å. The Ag(2)-N(4) bond length is 2.39 Å. The Ag(2)-N(6) bond length is 2.36 Å. The Ag(2)-N(8) bond length is 2.25 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.31 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(5) atom. The C(5)-N(3) bond length is 1.33 Å. The C(5)-H(5) bond length is 0.95 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(3) atom. The C(3)-N(2) bond length is 1.32 Å. The C(3)-H(3) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(4) atom. The C(4)-N(1) bond length is 1.32 Å. The C(4)-N(2) bond length is 1.34 Å. The C(4)-H(4) bond length is 0.95 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(7) atom. The C(7)-N(4) bond length is 1.31 Å. The C(7)-H(7) bond length is 0.95 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(8) atom. The C(8)-N(3) bond length is 1.32 Å. The C(8)-N(4) bond length is 1.34 Å. The C(8)-H(8) bond length is 0.95 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(9) atom. The C(9)-N(5) bond length is 1.32 Å. The C(9)-H(9) bond length is 0.95 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(10) atom. The C(10)-N(6) bond length is 1.35 Å. The C(10)-H(10) bond length is 0.95 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(11) atom. The C(11)-N(7) bond length is 1.35 Å. The C(11)-H(11) bond length is 0.95 Å. In the tenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(13) atom. The C(13)-N(8) bond length is 1.34 Å. The C(13)-H(13) bond length is 0.95 Å. In the eleventh C site, C(14) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(14) atom. The C(14)-N(7) bond length is 1.34 Å. The C(14)-N(8) bond length is 1.33 Å. The C(14)-H(14) bond length is 0.95 Å. In the twelfth C site, C(16) is bonded in a trigonal planar geometry to two equivalent N(5) and one H(16) atom. Both C(16)-N(5) bond lengths are 1.33 Å. The C(16)-H(16) bond length is 0.95 Å. In the thirteenth C site, C(18) is bonded in a trigonal planar geometry to two equivalent N(6) and one H(18) atom. Both C(18)-N(6) bond lengths are 1.33 Å. The C(18)-H(18) bond length is 0.95 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(2), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(5), and one C(8) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(7), and one C(8) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Ag(1), one C(16), and one C(9) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Ag(2), one C(10), and one C(18) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(11), and one C(14) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Ag(2), one C(13), and one C(14) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. Linkers: 32 c1cncnc1. Metal clusters: 16 [Ag]. The MOF has largest included sphere 4.82 A, density 1.24 g/cm3, surface area 4148.16 m2/g, accessible volume 0.40 cm3/g