AgC10N6H6O is Indium-like structured and crystallizes in the tetragonal P4_2/mnm space group. The structure is zero-dimensional and consists of two AgC10N6H6O clusters. Ag(1) is bonded in a distorted pentagonal pyramidal geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. Both Ag(1)-N(1) bond lengths are 2.52 Å. Both Ag(1)-N(2) bond lengths are 2.37 Å. Both Ag(1)-N(3) bond lengths are 2.73 Å. There are five inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(3) atom. The C(5)-N(3) bond length is 1.33 Å. The C(5)-H(3) bond length is 0.93 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(1) atom. The C(1)-N(1) bond length is 1.30 Å. The C(1)-O(1) bond length is 1.34 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one N(3) atom. The C(2)-N(3) bond length is 1.33 Å. In the fourth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1) atom. The C(3)-N(2) bond length is 1.34 Å. The C(3)-H(1) bond length is 0.93 Å. In the fifth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2) atom. The C(4)-N(2) bond length is 1.32 Å. The C(4)-H(2) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(3), and one C(4) atom. In the second N site, N(1) is bonded in a 3-coordinate geometry to one Ag(1), one C(1), and one N(1) atom. The N(1)-N(1) bond length is 1.39 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(2), and one C(5) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. O(1) is bonded in a water-like geometry to two equivalent C(1) atoms. Linkers: 4 c1cnc(-c2nnc(-c3cnccn3)o2)cn1. Metal clusters: 2 N1=N[Ag]=NN=[Ag]1. The MOF has largest included sphere 4.71 A, density 1.35 g/cm3, surface area 3661.38 m2/g, accessible volume 0.36 cm3/g