ZnH10(C2N)4 crystallizes in the triclinic P1 space group. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(18), one N(19), and one N(4) atom. The Zn(1)-N(1) bond length is 1.98 Å. The Zn(1)-N(18) bond length is 1.98 Å. The Zn(1)-N(19) bond length is 1.98 Å. The Zn(1)-N(4) bond length is 1.98 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one N(17), one N(2), one N(20), and one N(3) atom. The Zn(2)-N(17) bond length is 1.98 Å. The Zn(2)-N(2) bond length is 1.98 Å. The Zn(2)-N(20) bond length is 1.98 Å. The Zn(2)-N(3) bond length is 1.98 Å. In the third Zn site, Zn(3) is bonded in a tetrahedral geometry to one N(14); one N(15); one N(5,13); and one N(8,16) atom. The Zn(3)-N(14) bond length is 1.98 Å. The Zn(3)-N(15) bond length is 1.98 Å. The Zn(3)-N(5,13) bond length is 1.98 Å. The Zn(3)-N(8,16) bond length is 1.98 Å. In the fourth Zn site, Zn(4) is bonded in a tetrahedral geometry to one N(5,13); one N(6); one N(7); and one N(8,16) atom. The Zn(4)-N(5,13) bond length is 1.98 Å. The Zn(4)-N(6) bond length is 1.98 Å. The Zn(4)-N(7) bond length is 1.98 Å. The Zn(4)-N(8,16) bond length is 1.98 Å. In the fifth Zn site, Zn(5) is bonded in a tetrahedral geometry to one N(12), one N(22), one N(23), and one N(9) atom. The Zn(5)-N(12) bond length is 1.98 Å. The Zn(5)-N(22) bond length is 1.98 Å. The Zn(5)-N(23) bond length is 1.98 Å. The Zn(5)-N(9) bond length is 1.98 Å. In the sixth Zn site, Zn(6) is bonded in a tetrahedral geometry to one N(10), one N(11), one N(21), and one N(24) atom. The Zn(6)-N(10) bond length is 1.98 Å. The Zn(6)-N(11) bond length is 1.98 Å. The Zn(6)-N(21) bond length is 1.98 Å. The Zn(6)-N(24) bond length is 1.98 Å. There are forty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,5,13) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-H(1,5,13) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2) atom. The C(2)-N(2) bond length is 1.36 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(3) atom. The C(3)-N(3) bond length is 1.36 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4,24) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(4,10,11,19) atom. The C(4,24)-N(4) bond length is 1.36 Å. The C(4,24)-H(4,10,11,19) bond length is 0.93 Å. In the fifth C site, C(5,13) is bonded in a distorted bent 120 degrees geometry to one N(5,13) and one H(1,5,13) atom. The C(5,13)-N(5,13) bond length is 1.36 Å. The C(5,13)-H(1,5,13) bond length is 0.93 Å. In the sixth C site, C(6,18) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(6,14) atom. The C(6,18)-N(6) bond length is 1.36 Å. The C(6,18)-H(6,14) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(7,8,15,16,22) atom. The C(7)-N(7) bond length is 1.36 Å. The C(7)-H(7,8,15,16,22) bond length is 0.93 Å. In the eighth C site, C(8,16) is bonded in a distorted bent 120 degrees geometry to one N(8,16) and one H(7,8,15,16,22) atom. The C(8,16)-N(8,16) bond length is 1.36 Å. The C(8,16)-H(7,8,15,16,22) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(9,21) atom. The C(9)-N(9) bond length is 1.36 Å. The C(9)-H(9,21) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(4,10,11,19) atom. The C(10)-N(10) bond length is 1.36 Å. The C(10)-H(4,10,11,19) bond length is 0.93 Å. In the eleventh C site, C(11,19) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(4,10,11,19) atom. The C(11,19)-N(11) bond length is 1.36 Å. The C(11,19)-H(4,10,11,19) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(12) and one H(12,20,23) atom. The C(12)-N(12) bond length is 1.36 Å. The C(12)-H(12,20,23) bond length is 0.93 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(6,14) atom. The C(14)-N(14) bond length is 1.36 Å. The C(14)-H(6,14) bond length is 0.93 Å. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(15) and one H(7,8,15,16,22) atom. The C(15)-N(15) bond length is 1.36 Å. The C(15)-H(7,8,15,16,22) bond length is 0.93 Å. In the fifteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(17) and one H(17) atom. The C(17)-N(17) bond length is 1.36 Å. The C(17)-H(17) bond length is 0.93 Å. In the sixteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(20) and one H(12,20,23) atom. The C(20)-N(20) bond length is 1.36 Å. The C(20)-H(12,20,23) bond length is 0.93 Å. In the seventeenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(21) and one H(9,21) atom. The C(21)-N(21) bond length is 1.36 Å. The C(21)-H(9,21) bond length is 0.93 Å. In the eighteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(22) and one H(7,8,15,16,22) atom. The C(22)-N(22) bond length is 1.36 Å. The C(22)-H(7,8,15,16,22) bond length is 0.93 Å. In the nineteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(23) and one H(12,20,23) atom. The C(23)-N(23) bond length is 1.36 Å. The C(23)-H(12,20,23) bond length is 0.93 Å. In the twentieth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one N(1), and one N(23) atom. The C(25)-C(26) bond length is 1.50 Å. The C(25)-N(1) bond length is 1.35 Å. The C(25)-N(23) bond length is 1.35 Å. In the twenty-first C site, C(26) is bonded in a distorted trigonal non-coplanar geometry to one C(25) and three equivalent H(25,55,56) atoms. All C(26)-H(25,55,56) bond lengths are 1.14 Å. In the twenty-second C site, C(27) is bonded in a distorted trigonal planar geometry to one C(28), one N(2), and one N(22) atom. The C(27)-C(28) bond length is 1.50 Å. The C(27)-N(2) bond length is 1.35 Å. The C(27)-N(22) bond length is 1.35 Å. In the twenty-third C site, C(28) is bonded in a distorted trigonal non-coplanar geometry to one C(27) and three equivalent H(26,27,28) atoms. All C(28)-H(26,27,28) bond lengths are 1.14 Å. In the twenty-fourth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(30), one N(21), and one N(3) atom. The C(29)-C(30) bond length is 1.50 Å. The C(29)-N(21) bond length is 1.35 Å. The C(29)-N(3) bond length is 1.35 Å. In the twenty-fifth C site, C(30) is bonded in a distorted trigonal non-coplanar geometry to one C(29) and three equivalent H(29,57,58) atoms. All C(30)-H(29,57,58) bond lengths are 1.14 Å. In the twenty-sixth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(32), one N(24), and one N(4) atom. The C(31)-C(32) bond length is 1.50 Å. The C(31)-N(24) bond length is 1.35 Å. The C(31)-N(4) bond length is 1.35 Å. In the twenty-seventh C site, C(32) is bonded in a distorted trigonal non-coplanar geometry to one C(31) and three equivalent H(30,31,32,33,34,48,49,54,59) atoms. All C(32)-H(30,31,32,33,34,48,49,54,59) bond lengths are 1.14 Å. In the twenty-eighth C site, C(33,45) is bonded in a distorted trigonal planar geometry to one C(34,46); one N(19); and one N(5,13) atom. The C(33,45)-C(34,46) bond length is 1.50 Å. The C(33,45)-N(19) bond length is 1.35 Å. The C(33,45)-N(5,13) bond length is 1.35 Å. In the twenty-ninth C site, C(34,46) is bonded in a distorted trigonal non-coplanar geometry to one C(33,45) and three equivalent H(30,31,32,33,34,48,49,54,59) atoms. All C(34,46)-H(30,31,32,33,34,48,49,54,59) bond lengths are 1.14 Å. In the thirtieth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(36), one N(18), and one N(6) atom. The C(35)-C(36) bond length is 1.50 Å. The C(35)-N(18) bond length is 1.35 Å. The C(35)-N(6) bond length is 1.35 Å. In the thirty-first C site, C(36) is bonded in a distorted trigonal non-coplanar geometry to one C(35) and three equivalent H(35,36,37,45,46,47) atoms. All C(36)-H(35,36,37,45,46,47) bond lengths are 1.14 Å. In the thirty-second C site, C(37) is bonded in a distorted trigonal planar geometry to one C(38), one N(17), and one N(7) atom. The C(37)-C(38) bond length is 1.50 Å. The C(37)-N(17) bond length is 1.35 Å. The C(37)-N(7) bond length is 1.35 Å. In the thirty-third C site, C(38) is bonded in a distorted trigonal non-coplanar geometry to one C(37) and three equivalent H(38,39,43,44,53,60) atoms. All C(38)-H(38,39,43,44,53,60) bond lengths are 1.14 Å. In the thirty-fourth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(40); one N(20); and one N(8,16) atom. The C(39)-C(40) bond length is 1.50 Å. The C(39)-N(20) bond length is 1.35 Å. The C(39)-N(8,16) bond length is 1.35 Å. In the thirty-fifth C site, C(40) is bonded in a distorted trigonal non-coplanar geometry to one C(39) and three equivalent H(40,41,42,50,51,52) atoms. All C(40)-H(40,41,42,50,51,52) bond lengths are 1.14 Å. In the thirty-sixth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(42), one N(15), and one N(9) atom. The C(41)-C(42) bond length is 1.50 Å. The C(41)-N(15) bond length is 1.35 Å. The C(41)-N(9) bond length is 1.35 Å. In the thirty-seventh C site, C(42) is bonded in a distorted trigonal non-coplanar geometry to one C(41) and three equivalent H(38,39,43,44,53,60) atoms. All C(42)-H(38,39,43,44,53,60) bond lengths are 1.14 Å. In the thirty-eighth C site, C(43) is bonded in a distorted trigonal planar geometry to one C(44), one N(10), and one N(14) atom. The C(43)-C(44) bond length is 1.50 Å. The C(43)-N(10) bond length is 1.35 Å. The C(43)-N(14) bond length is 1.35 Å. In the thirty-ninth C site, C(44) is bonded in a distorted trigonal non-coplanar geometry to one C(43) and three equivalent H(35,36,37,45,46,47) atoms. All C(44)-H(35,36,37,45,46,47) bond lengths are 1.14 Å. In the fortieth C site, C(47) is bonded in a distorted trigonal planar geometry to one C(48); one N(12); and one N(8,16) atom. The C(47)-C(48) bond length is 1.50 Å. The C(47)-N(12) bond length is 1.35 Å. The C(47)-N(8,16) bond length is 1.35 Å. In the forty-first C site, C(48) is bonded in a distorted trigonal non-coplanar geometry to one C(47) and three equivalent H(40,41,42,50,51,52) atoms. All C(48)-H(40,41,42,50,51,52) bond lengths are 1.14 Å. There are twenty-two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(25) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(2), and one C(27) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(29), and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1); one C(31); and one C(4,24) atom. In the fifth N site, N(5,13) is bonded in a trigonal planar geometry to one Zn(3); one C(33,45); and one C(5,13) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(4); one C(35); and one C(6,18) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Zn(4), one C(37), and one C(7) atom. In the eighth N site, N(8,16) is bonded in a trigonal planar geometry to one Zn(3); one C(39); and one C(8,16) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Zn(5), one C(41), and one C(9) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Zn(6), one C(10), and one C(43) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Zn(6); one C(11,19); and one C(33,45) atom. The N(11)-C(33,45) bond length is 1.35 Å. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Zn(5), one C(12), and one C(47) atom. In the thirteenth N site, N(14) is bonded in a trigonal planar geometry to one Zn(3), one C(14), and one C(43) atom. In the fourteenth N site, N(15) is bonded in a trigonal planar geometry to one Zn(3), one C(15), and one C(41) atom. In the fifteenth N site, N(17) is bonded in a trigonal planar geometry to one Zn(2), one C(17), and one C(37) atom. In the sixteenth N site, N(18) is bonded in a trigonal planar geometry to one Zn(1); one C(35); and one C(6,18) atom. The N(18)-C(6,18) bond length is 1.36 Å. In the seventeenth N site, N(19) is bonded in a trigonal planar geometry to one Zn(1); one C(11,19); and one C(33,45) atom. The N(19)-C(11,19) bond length is 1.36 Å. In the eighteenth N site, N(20) is bonded in a trigonal planar geometry to one Zn(2), one C(20), and one C(39) atom. In the nineteenth N site, N(21) is bonded in a trigonal planar geometry to one Zn(6), one C(21), and one C(29) atom. In the twentieth N site, N(22) is bonded in a trigonal planar geometry to one Zn(5), one C(22), and one C(27) atom. In the twenty-first N site, N(23) is bonded in a trigonal planar geometry to one Zn(5), one C(23), and one C(25) atom. In the twenty-second N site, N(24) is bonded in a trigonal planar geometry to one Zn(6); one C(31); and one C(4,24) atom. The N(24)-C(4,24) bond length is 1.36 Å. There are eighteen inequivalent H sites. In the first H site, H(1,5,13) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4,10,11,19) is bonded in a single-bond geometry to one C(4,24) atom. In the fifth H site, H(6,14) is bonded in a single-bond geometry to one C(6,18) atom. In the sixth H site, H(7,8,15,16,22) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(9,21) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(12,20,23) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(6,18) atom. The H(18)-C(6,18) bond length is 0.93 Å. In the eleventh H site, H(24) is bonded in a single-bond geometry to one C(4,24) atom. The H(24)-C(4,24) bond length is 0.93 Å. In the twelfth H site, H(25,55,56) is bonded in a single-bond geometry to one C(26) atom. In the thirteenth H site, H(26,27,28) is bonded in a single-bond geometry to one C(28) atom. In the fourteenth H site, H(29,57,58) is bonded in a single-bond geometry to one C(30) atom. In the fifteenth H site, H(30,31,32,33,34,48,49,54,59) is bonded in a single-bond geometry to one C(32) atom. In the sixteenth H site, H(35,36,37,45,46,47) is bonded in a single-bond geometry to one C(36) atom. In the seventeenth H site, H(38,39,43,44,53,60) is bonded in a single-bond geometry to one C(38) atom. In the eighteenth H site, H(40,41,42,50,51,52) is bonded in a single-bond geometry to one C(40) atom. Linkers: 5 CC1=N[CH]C=N1 ,7 CC1=NC=C[N]1. Metal clusters: 6 [Zn]. The MOF has largest included sphere 11.41 A, density 0.92 g/cm3, surface area 5231.37 m2/g, accessible volume 0.65 cm3/g