ZnC14NH16O4 is Indium-like structured and crystallizes in the orthorhombic Cmmm space group. The structure is zero-dimensional and consists of two ZnC14NH16O4 clusters. Zn(1) is bonded in a distorted square pyramidal geometry to one N(1) and four equivalent O(1) atoms. The Zn(1)-N(1) bond length is 2.07 Å. All Zn(1)-O(1) bond lengths are 2.03 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(4) and one H(1) atom. The C(1)-C(4) bond length is 1.38 Å. The C(1)-H(1) bond length is 0.94 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one N(1), one H(2), and one H(3) atom. The C(2)-N(1) bond length is 1.45 Å. The C(2)-H(2) bond length is 0.98 Å. The C(2)-H(3) bond length is 0.98 Å. In the third C site, C(3) is bonded in a bent 120 degrees geometry to one C(4) and two equivalent O(1) atoms. The C(3)-C(4) bond length is 1.51 Å. Both C(3)-O(1) bond lengths are 1.25 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3) and two equivalent C(1) atoms. In the fifth C site, C(5) is bonded in a distorted water-like geometry to one N(1) and two equivalent H(4) atoms. The C(5)-N(1) bond length is 1.46 Å. Both C(5)-H(4) bond lengths are 0.98 Å. N(1) is bonded in a 7-coordinate geometry to one Zn(1), two equivalent C(5), and four equivalent C(2) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a distorted bent 120 degrees geometry to one C(2) and one H(4) atom. The H(3)-H(4) bond length is 0.48 Å. In the fourth H site, H(4) is bonded in a distorted bent 120 degrees geometry to one C(5) and one H(3) atom. O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. Linkers: 1 [N]1CC1.C1C[N]21CC2.[CH2].[CH2].[CH2].[CH2].[CH2].[CH2] ,4 [O]C(=O)c1ccc(C([O])=O)cc1 ,1 C1C[N]21CC2.C1C[N]21CC2.[CH2].[CH2].[CH2].[CH2]. Metal clusters: 2 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 7.94 A, density 0.98 g/cm3, surface area 3471.17 m2/g, accessible volume 0.71 cm3/g