CdC8H8(N2Cl)2(H11(C7O)2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight CdC8H8(N2Cl)2 clusters and eight H11(C7O)2 clusters. In each CdC8H8(N2Cl)2 cluster, Cd(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one Cl(1), and one Cl(2) atom. The Cd(1)-N(1) bond length is 2.36 Å. The Cd(1)-N(2) bond length is 2.35 Å. The Cd(1)-N(3) bond length is 2.33 Å. The Cd(1)-N(4) bond length is 2.35 Å. The Cd(1)-Cl(1) bond length is 2.67 Å. The Cd(1)-Cl(2) bond length is 2.59 Å. There are eight inequivalent C sites. In the first C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(10)-N(1) bond length is 1.33 Å. The C(10)-H(8) bond length is 0.93 Å. In the second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(18) atom. The C(22)-N(2) bond length is 1.34 Å. The C(22)-H(18) bond length is 0.93 Å. In the third C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(17) atom. The C(21)-N(2) bond length is 1.33 Å. The C(21)-H(17) bond length is 0.93 Å. In the fourth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(28) atom. The C(34)-N(3) bond length is 1.35 Å. The C(34)-H(28) bond length is 0.93 Å. In the fifth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(29) atom. The C(35)-N(3) bond length is 1.34 Å. The C(35)-H(29) bond length is 0.93 Å. In the sixth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(1) atom. The C(1)-N(4) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.93 Å. In the seventh C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(3) atom. The C(4)-N(4) bond length is 1.34 Å. The C(4)-H(3) bond length is 0.93 Å. In the eighth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-H(5) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(21), and one C(22) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(34), and one C(35) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(4) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the seventh H site, H(28) is bonded in a single-bond geometry to one C(34) atom. In the eighth H site, H(29) is bonded in a single-bond geometry to one C(35) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cd(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cd(1) atom. In each H11(C7O)2 cluster, there are twenty-eight inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(6,7) atom. The C(9)-C(8) bond length is 1.39 Å. The C(9)-H(6,7) bond length is 0.93 Å. In the second C site, C(11) is bonded in a trigonal planar geometry to one C(12), one C(15), and one C(8) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(15) bond length is 1.39 Å. The C(11)-C(8) bond length is 1.49 Å. In the third C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(9) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(9) bond length is 0.93 Å. In the fourth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(19) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-C(19) bond length is 1.49 Å. In the fifth C site, C(14) is bonded in a single-bond geometry to one C(13), one C(16), and one O(2) atom. The C(14)-C(16) bond length is 1.41 Å. The C(14)-O(2) bond length is 1.37 Å. In the sixth C site, C(15) is bonded in a distorted single-bond geometry to one C(11), one C(16), and one O(1) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-O(1) bond length is 1.38 Å. In the seventh C site, C(16) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(24) atom. The C(16)-C(24) bond length is 1.49 Å. In the eighth C site, C(17) is bonded in a tetrahedral geometry to one H(11); two equivalent H(10,12); and one O(1) atom. The C(17)-H(11) bond length is 0.96 Å. Both C(17)-H(10,12) bond lengths are 0.96 Å. The C(17)-O(1) bond length is 1.45 Å. In the ninth C site, C(18) is bonded in a tetrahedral geometry to one H(13); two equivalent H(14,15); and one O(2) atom. The C(18)-H(13) bond length is 0.96 Å. Both C(18)-H(14,15) bond lengths are 0.96 Å. The C(18)-O(2) bond length is 1.45 Å. In the tenth C site, C(19) is bonded in a trigonal planar geometry to one C(13), one C(20), and one C(23) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-C(23) bond length is 1.38 Å. In the eleventh C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(16) atom. The C(20)-H(16) bond length is 0.93 Å. In the twelfth C site, C(23) is bonded in a distorted single-bond geometry to one C(19) and one H(19) atom. The C(23)-H(19) bond length is 0.93 Å. In the thirteenth C site, C(24) is bonded in a trigonal planar geometry to one C(16), one C(25), and one C(29) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-C(29) bond length is 1.40 Å. In the fourteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(24), one C(26), and one O(3) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-O(3) bond length is 1.39 Å. In the fifteenth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(32) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-C(32) bond length is 1.49 Å. In the sixteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(26), one C(28), and one H(20) atom. The C(27)-C(28) bond length is 1.39 Å. The C(27)-H(20) bond length is 0.93 Å. In the seventeenth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(3) atom. The C(28)-C(29) bond length is 1.39 Å. The C(28)-C(3) bond length is 1.47 Å. In the eighteenth C site, C(29) is bonded in a distorted single-bond geometry to one C(24), one C(28), and one O(4) atom. The C(29)-O(4) bond length is 1.38 Å. In the nineteenth C site, C(30) is bonded in a tetrahedral geometry to three equivalent H(21,22,23) and one O(4) atom. All C(30)-H(21,22,23) bond lengths are 0.96 Å. The C(30)-O(4) bond length is 1.43 Å. In the twentieth C site, C(31) is bonded in a tetrahedral geometry to one H(24); two equivalent H(25,26); and one O(3) atom. The C(31)-H(24) bond length is 0.96 Å. Both C(31)-H(25,26) bond lengths are 0.96 Å. The C(31)-O(3) bond length is 1.45 Å. In the twenty-first C site, C(32) is bonded in a trigonal planar geometry to one C(26), one C(33), and one C(36) atom. The C(32)-C(33) bond length is 1.40 Å. The C(32)-C(36) bond length is 1.40 Å. In the twenty-second C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(27) atom. The C(33)-H(27) bond length is 0.93 Å. In the twenty-third C site, C(36) is bonded in a single-bond geometry to one C(32) and one H(30) atom. The C(36)-H(30) bond length is 0.93 Å. In the twenty-fourth C site, C(2) is bonded in a single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2) bond length is 0.93 Å. In the twenty-fifth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(28), and one C(5) atom. The C(3)-C(5) bond length is 1.40 Å. In the twenty-sixth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(5)-H(4) bond length is 0.93 Å. In the twenty-seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(6,7) atom. The C(7)-C(8) bond length is 1.38 Å. The C(7)-H(6,7) bond length is 0.93 Å. In the twenty-eighth C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(7), and one C(9) atom. There are sixteen inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(10,12) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one C(27) atom. In the sixth H site, H(21,22,23) is bonded in a single-bond geometry to one C(30) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the eighth H site, H(24) is bonded in a single-bond geometry to one C(31) atom. In the ninth H site, H(25,26) is bonded in a single-bond geometry to one C(31) atom. In the tenth H site, H(27) is bonded in a single-bond geometry to one C(33) atom. In the eleventh H site, H(30) is bonded in a single-bond geometry to one C(36) atom. In the twelfth H site, H(6,7) is bonded in a single-bond geometry to one C(7) atom. In the thirteenth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(14,15) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(15) and one C(17) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(14) and one C(18) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(25) and one C(31) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(29) and one C(30) atom. Linkers: 8 COc1c(-c2ccncc2)cc(-c2ccncc2)c(OC)c1-c1c(OC)c(-c2ccncc2)cc(-c2ccncc2)c1OC. Metal clusters: 8 Cl[Cd]Cl. The MOF has largest included sphere 4.69 A, density 1.14 g/cm3, surface area 4914.62 m2/g, accessible volume 0.41 cm3/g