(ZnH14(C13N2)2)3Zn4C24H12O13 is Indium-like structured and crystallizes in the trigonal R-3c space group. The structure is zero-dimensional and consists of twelve Zn4C24H12O13 clusters and thirty-six ZnH14(C13N2)2 clusters. In each Zn4C24H12O13 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(2) bond length is 1.95 Å. The Zn(1)-O(3) bond length is 1.97 Å. The Zn(1)-O(5) bond length is 1.94 Å. In the second Zn site, Zn(2) is bonded to one O(5) and three equivalent O(4) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(5) bond length is 1.93 Å. All Zn(2)-O(4) bond lengths are 1.90 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(2) atom. The C(1)-C(3) bond length is 1.53 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.22 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(2)-C(4) bond length is 1.46 Å. The C(2)-O(3) bond length is 1.28 Å. The C(2)-O(4) bond length is 1.26 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(6) atom. The C(3)-C(5) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.36 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(7), and one C(8) atom. The C(4)-C(7) bond length is 1.38 Å. The C(4)-C(8) bond length is 1.31 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(5)-H(1) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(6)-H(2) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(7)-H(3) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(8)-H(4) bond length is 0.93 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(2) atom. In the fifth O site, O(5) is bonded in a tetrahedral geometry to one Zn(2) and three equivalent Zn(1) atoms. In eighteen of the ZnH14(C13N2)2 clusters, Zn(3) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Zn(3)-N(1) bond lengths are 1.99 Å. Both Zn(3)-N(2) bond lengths are 2.04 Å. There are thirteen inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(13) and one H(5) atom. The C(9)-C(13) bond length is 1.34 Å. The C(9)-H(5) bond length is 0.93 Å. In the second C site, C(10) is bonded in a distorted single-bond geometry to one C(13) and one H(6) atom. The C(10)-C(13) bond length is 1.37 Å. The C(10)-H(6) bond length is 0.93 Å. In the third C site, C(13) is bonded in a trigonal planar geometry to one C(10), one C(15), and one C(9) atom. The C(13)-C(15) bond length is 1.50 Å. In the fourth C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(18) atom. The C(15)-C(17) bond length is 1.39 Å. The C(15)-C(18) bond length is 1.37 Å. In the fifth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(15), one C(21), and one N(1) atom. The C(17)-C(21) bond length is 1.49 Å. The C(17)-N(1) bond length is 1.40 Å. In the sixth C site, C(18) is bonded in a trigonal planar geometry to one C(15), one C(22), and one N(2) atom. The C(18)-C(22) bond length is 1.38 Å. The C(18)-N(2) bond length is 1.33 Å. In the seventh C site, C(21) is bonded in a distorted single-bond geometry to one C(17) and one H(9) atom. The C(21)-H(9) bond length is 0.93 Å. In the eighth C site, C(22) is bonded in a single-bond geometry to one C(18) and one H(10) atom. The C(22)-H(10) bond length is 0.93 Å. In the ninth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one C(33), and one N(1) atom. The C(25)-C(26) bond length is 1.47 Å. The C(25)-C(33) bond length is 1.42 Å. The C(25)-N(1) bond length is 1.33 Å. In the tenth C site, C(26) is bonded in a single-bond geometry to one C(25) and one H(13) atom. The C(26)-H(13) bond length is 0.93 Å. In the eleventh C site, C(27) is bonded in a distorted trigonal planar geometry to one C(28), one C(33), and one N(2) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-C(33) bond length is 1.33 Å. The C(27)-N(2) bond length is 1.42 Å. In the twelfth C site, C(28) is bonded in a distorted single-bond geometry to one C(27) and one H(14) atom. The C(28)-H(14) bond length is 0.93 Å. In the thirteenth C site, C(33) is bonded in a single-bond geometry to one C(25), one C(27), and one H(17) atom. The C(33)-H(17) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(3), one C(17), and one C(25) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(3), one C(18), and one C(27) atom. There are seven inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(21) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(22) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(26) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(28) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(33) atom. In eighteen of the ZnH14(C13N2)2 clusters, Zn(4) is bonded in a rectangular see-saw-like geometry to two equivalent N(3) and two equivalent N(4) atoms. Both Zn(4)-N(3) bond lengths are 2.07 Å. Both Zn(4)-N(4) bond lengths are 2.00 Å. There are fourteen inequivalent C sites. In the first C site, C(11) is bonded in a distorted single-bond geometry to one C(14) and one H(7) atom. The C(11)-C(14) bond length is 1.30 Å. The C(11)-H(7) bond length is 0.93 Å. In the second C site, C(12) is bonded in a distorted single-bond geometry to one C(14) and one H(8) atom. The C(12)-C(14) bond length is 1.37 Å. The C(12)-H(8) bond length is 0.93 Å. In the third C site, C(34) is bonded in a distorted single-bond geometry to two equivalent C(30) and one H(18) atom. Both C(34)-C(30) bond lengths are 1.37 Å. The C(34)-H(18) bond length is 0.93 Å. In the fourth C site, C(14) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(16) atom. The C(14)-C(16) bond length is 1.45 Å. In the fifth C site, C(35) is bonded in a distorted single-bond geometry to two equivalent C(31) and one H(19) atom. Both C(35)-C(31) bond lengths are 1.39 Å. The C(35)-H(19) bond length is 0.93 Å. In the sixth C site, C(16) is bonded in a trigonal planar geometry to one C(14), one C(19), and one C(20) atom. The C(16)-C(19) bond length is 1.37 Å. The C(16)-C(20) bond length is 1.39 Å. In the seventh C site, C(19) is bonded in a distorted trigonal planar geometry to one C(16), one C(23), and one N(3) atom. The C(19)-C(23) bond length is 1.51 Å. The C(19)-N(3) bond length is 1.36 Å. In the eighth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(16), one C(24), and one N(4) atom. The C(20)-C(24) bond length is 1.51 Å. The C(20)-N(4) bond length is 1.43 Å. In the ninth C site, C(23) is bonded in a distorted single-bond geometry to one C(19) and one H(11) atom. The C(23)-H(11) bond length is 0.93 Å. In the tenth C site, C(24) is bonded in a distorted single-bond geometry to one C(20) and one H(12) atom. The C(24)-H(12) bond length is 0.93 Å. In the eleventh C site, C(29) is bonded in a distorted single-bond geometry to one C(30) and one H(15) atom. The C(29)-C(30) bond length is 1.51 Å. The C(29)-H(15) bond length is 0.93 Å. In the twelfth C site, C(30) is bonded in a distorted single-bond geometry to one C(29), one C(34), and one N(3) atom. The C(30)-N(3) bond length is 1.36 Å. In the thirteenth C site, C(31) is bonded in a distorted single-bond geometry to one C(32), one C(35), and one N(4) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-N(4) bond length is 1.36 Å. In the fourteenth C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(16) atom. The C(32)-H(16) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Zn(4), one C(19), and one C(30) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Zn(4), one C(20), and one C(31) atom. There are eight inequivalent H sites. In the first H site, H(18) is bonded in a single-bond geometry to one C(34) atom. In the second H site, H(19) is bonded in a single-bond geometry to one C(35) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(24) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(29) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(32) atom. Linkers: 3 [O]C(=O)c1ccc(/C2=C3\C=C/C(=C/C4=N/C(=C(/c5ccc(C([O])=O)cc5)C5=CC=C(/C=C6/C=CC2=N6)[N]5)C=C4)[N]3)cc1 ,17 [O]C(=O)c1ccc(cc1)C1=C2C=CC3=[N]2[Zn@]24n5c1ccc5C=C1[N]2=C(C=C1)C(=c1n4c(=C3)cc1)c1ccc(cc1)C(=O)[O] ,17 [O]C(=O)c1ccc(cc1)C1=C2C=CC3=[N]2[Zn@@]24n5c1ccc5C=C1[N]2=C(C=C1)C(=c1n4c(=C3)cc1)c1ccc(cc1)C(=O)[O]. Metal clusters: 10 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4 ,11 [Zn]. The MOF has largest included sphere 6.49 A, density 1.07 g/cm3, surface area 4224.20 m2/g, accessible volume 0.44 cm3/g