ZnH16(C6N)4(C2H)8 is Indium-derived structured and crystallizes in the orthorhombic Cmcm space group. The structure is zero-dimensional and consists of eight hexa-1,5-diene-3-yne, 2,5-dimethyl- molecules and four ZnH16(C6N)4 clusters. In each ZnH16(C6N)4 cluster, Zn(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Zn(1)-N(1) bond lengths are 2.13 Å. Both Zn(1)-N(2) bond lengths are 2.14 Å. There are eight inequivalent C sites. In the first C site, C(12) is bonded in a trigonal planar geometry to one C(13) and two equivalent C(4) atoms. The C(12)-C(13) bond length is 1.45 Å. Both C(12)-C(4) bond lengths are 1.33 Å. In the second C site, C(13) is bonded in a distorted linear geometry to one C(12) and one C(7) atom. The C(13)-C(7) bond length is 1.26 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1) atom. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(12) and one H(4) atom. The C(4)-H(4) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one H(5) atom. The C(5)-C(6) bond length is 1.38 Å. The C(5)-N(1) bond length is 1.27 Å. The C(5)-H(5) bond length is 0.95 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(10), one C(5), and one H(6) atom. The C(6)-C(10) bond length is 1.30 Å. The C(6)-H(6) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a linear geometry to one C(10) and one C(13) atom. The C(7)-C(10) bond length is 1.42 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(7) and two equivalent C(6) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1) and two equivalent C(5) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1) and two equivalent C(1) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. Linkers: 8 C(#Cc1ccc(C#Cc2ccncc2)cc1)c1ccncc1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 10.98 A, density 0.63 g/cm3, surface area 5723.54 m2/g, accessible volume 1.00 cm3/g