CuC17H15(NO)4(CH)4CH2C3H2O2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, four 02329_fluka molecules, four dimethoxymethane molecules, and four CuC17H15(NO)4 clusters. In each CuC17H15(NO)4 cluster, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(3), one O(1), and one O(5) atom. The Cu(1)-N(1) bond length is 1.97 Å. The Cu(1)-N(3) bond length is 1.98 Å. The Cu(1)-O(1) bond length is 1.94 Å. The Cu(1)-O(5) bond length is 1.94 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.23 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.38 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(8) is bonded in a 3-coordinate geometry to one C(9), one N(1), and one H(5) atom. The C(8)-C(9) bond length is 1.35 Å. The C(8)-N(1) bond length is 1.38 Å. The C(8)-H(5) bond length is 0.93 Å. In the sixth C site, C(9) is bonded in a 3-coordinate geometry to one C(8), one N(2), and one H(6) atom. The C(9)-N(2) bond length is 1.36 Å. The C(9)-H(6) bond length is 0.93 Å. In the seventh C site, C(10) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(7) atom. The C(10)-N(1) bond length is 1.31 Å. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(7) bond length is 0.93 Å. In the eighth C site, C(11) is bonded in a 4-coordinate geometry to one C(12); one N(2); and two equivalent H(8,9) atoms. The C(11)-C(12) bond length is 1.47 Å. The C(11)-N(2) bond length is 1.47 Å. Both C(11)-H(8,9) bond lengths are 0.97 Å. In the ninth C site, C(12) is bonded in a water-like geometry to one C(11) and two equivalent H(10,11) atoms. Both C(12)-H(10,11) bond lengths are 0.97 Å. In the tenth C site, C(13) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(12) atom. The C(13)-N(3) bond length is 1.32 Å. The C(13)-N(4) bond length is 1.34 Å. The C(13)-H(12) bond length is 0.93 Å. In the eleventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(3), and one H(13) atom. The C(14)-C(15) bond length is 1.36 Å. The C(14)-N(3) bond length is 1.37 Å. The C(14)-H(13) bond length is 0.93 Å. In the twelfth C site, C(15) is bonded in a distorted water-like geometry to one C(14) and one N(4) atom. The C(15)-N(4) bond length is 1.38 Å. In the thirteenth C site, C(17) is bonded in a 3-coordinate geometry to one N(4) and two equivalent H(16,17) atoms. The C(17)-N(4) bond length is 1.47 Å. Both C(17)-H(16,17) bond lengths are 0.97 Å. In the fourteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(4), and one O(5) atom. The C(18)-C(19) bond length is 1.51 Å. The C(18)-O(4) bond length is 1.23 Å. The C(18)-O(5) bond length is 1.28 Å. In the fifteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.38 Å. The C(19)-C(24) bond length is 1.39 Å. In the sixteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(18) atom. The C(20)-H(18) bond length is 0.93 Å. In the seventeenth C site, C(24) is bonded in a single-bond geometry to one C(19) and one H(21) atom. The C(24)-H(21) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(14) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(8,9) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(10,11) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(16,17) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(24) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(4) is bonded in a single-bond geometry to one C(18) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(18) atom. Linkers: 2 c1cn(CCCCn2ccnc2)cn1 ,4 [O]C(=O)c1ccc(OCOc2ccc(C([O])=O)cc2)cc1 ,2 [c]1cncn1CCCCn1[c]cnc1. Metal clusters: 4 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 5.14 A, density 1.25 g/cm3, surface area 5102.63 m2/g, accessible volume 0.35 cm3/g