(CdC9H5O4)2CdH4(C2O)4(CH)8(C2O)4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, sixteen dimethyl ether molecules, eight CdC9H5O4 clusters, and four CdH4(C2O)4 clusters. In each CdC9H5O4 cluster, Cd(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(6), and one O(7) atom. The Cd(1)-O(1) bond length is 2.45 Å. The Cd(1)-O(2) bond length is 2.26 Å. The Cd(1)-O(6) bond length is 2.26 Å. The Cd(1)-O(7) bond length is 2.46 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(4) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(1) atom. The C(3)-C(6) bond length is 1.39 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(15) atom. The C(11)-C(12) bond length is 1.49 Å. The C(11)-C(14) bond length is 1.40 Å. The C(11)-C(15) bond length is 1.37 Å. In the seventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(6), and one O(7) atom. The C(12)-O(6) bond length is 1.24 Å. The C(12)-O(7) bond length is 1.29 Å. In the eighth C site, C(14) is bonded in a single-bond geometry to one C(11) and one H(7) atom. The C(14)-H(7) bond length is 0.93 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(15)-H(8) bond length is 0.93 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the third O site, O(6) is bonded in a distorted water-like geometry to one Cd(1) and one C(12) atom. In the fourth O site, O(7) is bonded in a single-bond geometry to one Cd(1) and one C(12) atom. In each CdH4(C2O)4 cluster, Cd(2) is bonded in a rectangular see-saw-like geometry to two equivalent O(4) and two equivalent O(8) atoms. Both Cd(2)-O(4) bond lengths are 2.43 Å. Both Cd(2)-O(8) bond lengths are 2.34 Å. There are four inequivalent C sites. In the first C site, C(10) is bonded in a distorted single-bond geometry to one C(18) and one H(6) atom. The C(10)-C(18) bond length is 1.40 Å. The C(10)-H(6) bond length is 0.93 Å. In the second C site, C(18) is bonded in a trigonal planar geometry to one C(10), one C(20), and one C(21) atom. The C(18)-C(20) bond length is 1.38 Å. The C(18)-C(21) bond length is 1.47 Å. In the third C site, C(20) is bonded in a distorted single-bond geometry to one C(18) and one H(11) atom. The C(20)-H(11) bond length is 0.93 Å. In the fourth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(18), one O(4), and one O(8) atom. The C(21)-O(4) bond length is 1.26 Å. The C(21)-O(8) bond length is 1.23 Å. There are two inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(20) atom. There are two inequivalent O sites. In the first O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(21) atom. In the second O site, O(8) is bonded in a distorted single-bond geometry to one Cd(2) and one C(21) atom. Linkers: 1 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,2 O=[C]c1[c][c]cc(Oc2ccc([C]3O[Cd]4(O3)O[C](c3ccc(Oc5c[c]cc([C]6O[Cd]7(O6)O[C](c6c[c]cc(Oc8ccc([C]9O[Cd]%10(O[C](c%11ccc(Oc%12c[c][c]c([C]=O)c%12)cc%11)O%10)O9)cc8)c6)O7)c5)cc3)O4)cc2)c1 ,2 [O][C]c1[c]cc(Oc2cc(Oc3ccc([C]4O[Cd]5(O[C](c6ccc(Oc7cc(Oc8c[c]c([C]=O)cc8)cc([C]8O[Cd]9(O8)O[C](c8cc(Oc%10c[c]c([C]=O)cc%10)cc(Oc%10ccc([C]%11O[Cd]%12(O%11)O[C](c%11ccc(Oc%13cc(Oc%14c[c]c([C][O])cc%14)cc(C([O])=O)c%13)cc%11)O%12)cc%10)c8)O9)c7)cc6)O5)O4)cc3)cc(C([O])=O)c2)cc1. Metal clusters: 2 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 10.79 A, density 1.03 g/cm3, surface area 3987.45 m2/g, accessible volume 0.58 cm3/g