Cu(C6H4NO2)2C4H5(CH2)2C4NH4SO2 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four isobutylene molecules, four schembl9269457 molecules, and four Cu(C6H4NO2)2 clusters. In each Cu(C6H4NO2)2 cluster, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one O(2), and one O(4) atom. The Cu(1)-N(1) bond length is 2.05 Å. The Cu(1)-N(2) bond length is 2.05 Å. The Cu(1)-O(2) bond length is 1.98 Å. The Cu(1)-O(4) bond length is 1.96 Å. There are twelve inequivalent C sites. In the first C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(9)-O(1) bond length is 1.22 Å. The C(9)-O(2) bond length is 1.28 Å. In the second C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(12)-O(3) bond length is 1.20 Å. The C(12)-O(4) bond length is 1.29 Å. In the third C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(13)-N(1) bond length is 1.33 Å. The C(13)-H(13) bond length is 0.93 Å. In the fourth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(14) atom. The C(14)-C(15) bond length is 1.37 Å. The C(14)-H(14) bond length is 0.93 Å. In the fifth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.37 Å. The C(15)-C(18) bond length is 1.47 Å. In the sixth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(15) atom. The C(16)-H(15) bond length is 0.93 Å. In the seventh C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(16) atom. The C(17)-N(1) bond length is 1.32 Å. The C(17)-H(16) bond length is 0.93 Å. In the eighth C site, C(18) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(22) atom. The C(18)-C(19) bond length is 1.37 Å. The C(18)-C(22) bond length is 1.40 Å. In the ninth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(17) atom. The C(19)-C(20) bond length is 1.37 Å. The C(19)-H(17) bond length is 0.93 Å. In the tenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one N(2), and one H(18) atom. The C(20)-N(2) bond length is 1.33 Å. The C(20)-H(18) bond length is 0.93 Å. In the eleventh C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(2), and one H(19) atom. The C(21)-C(22) bond length is 1.37 Å. The C(21)-N(2) bond length is 1.34 Å. The C(21)-H(19) bond length is 0.93 Å. In the twelfth C site, C(22) is bonded in a distorted single-bond geometry to one C(18), one C(21), and one H(20) atom. The C(22)-H(20) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(17) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(20), and one C(21) atom. There are eight inequivalent H sites. In the first H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(22) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(9) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cu(1) and one C(9) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(12) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(12) atom. Linkers: 4 Cc1ccc(S(=O)(=O)N[C@@H](CCC([O])=O)C([O])=O)cc1 ,4 c1cc(-c2ccncc2)ccn1. Metal clusters: 4 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 5.92 A, density 1.13 g/cm3, surface area 4805.45 m2/g, accessible volume 0.41 cm3/g