(CH)10CH2(CdBC22N3H18(O2F)2)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of twenty-four 02329_fluka molecules, four 02329_fluka molecules, and four isobutylene molecules inside a CdBC22N3H18(O2F)2 framework. In the CdBC22N3H18(O2F)2 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 7-coordinate geometry to one N(1), one O(1), one O(2), one O(3), one O(5), one O(6), and one O(7) atom. The Cd(1)-N(1) bond length is 2.32 Å. The Cd(1)-O(1) bond length is 2.66 Å. The Cd(1)-O(2) bond length is 2.25 Å. The Cd(1)-O(3) bond length is 2.30 Å. The Cd(1)-O(5) bond length is 2.49 Å. The Cd(1)-O(6) bond length is 2.29 Å. The Cd(1)-O(7) bond length is 2.50 Å. In the second Cd site, Cd(2) is bonded in a distorted pentagonal bipyramidal geometry to one N(2), one O(1), one O(3), one O(4), one O(5), one O(7), and one O(8) atom. The Cd(2)-N(2) bond length is 2.32 Å. The Cd(2)-O(1) bond length is 2.29 Å. The Cd(2)-O(3) bond length is 2.51 Å. The Cd(2)-O(4) bond length is 2.35 Å. The Cd(2)-O(5) bond length is 2.33 Å. The Cd(2)-O(7) bond length is 2.42 Å. The Cd(2)-O(8) bond length is 2.43 Å. There are two inequivalent B sites. In the first B site, B(1) is bonded in a tetrahedral geometry to one N(3), one N(4), one F(1), and one F(2) atom. The B(1)-N(3) bond length is 1.54 Å. The B(1)-N(4) bond length is 1.53 Å. The B(1)-F(1) bond length is 1.37 Å. The B(1)-F(2) bond length is 1.44 Å. In the second B site, B(2) is bonded in a tetrahedral geometry to one N(5), one N(6), one F(3), and one F(4) atom. The B(2)-N(5) bond length is 1.50 Å. The B(2)-N(6) bond length is 1.49 Å. The B(2)-F(3) bond length is 1.38 Å. The B(2)-F(4) bond length is 1.45 Å. There are forty-four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(55), and one C(6) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(55) bond length is 1.31 Å. The C(1)-C(6) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1,5) atom. The C(2)-H(1,5) bond length is 0.93 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(1,5) atom. The C(6)-H(1,5) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(7)-N(2) bond length is 1.32 Å. The C(7)-H(6) bond length is 0.93 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(9) bond length is 0.93 Å. In the sixth C site, C(14) is bonded in a water-like geometry to one C(15) and two equivalent H(14,15) atoms. The C(14)-C(15) bond length is 1.52 Å. Both C(14)-H(14,15) bond lengths are 0.97 Å. In the seventh C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(19) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(19) bond length is 1.39 Å. In the eighth C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one H(16) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(16) bond length is 0.93 Å. In the ninth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(1), and one H(17) atom. The C(17)-N(1) bond length is 1.35 Å. The C(17)-H(17) bond length is 0.93 Å. In the tenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(18) atom. The C(18)-N(1) bond length is 1.34 Å. The C(18)-H(18) bond length is 0.93 Å. In the eleventh C site, C(19) is bonded in a distorted single-bond geometry to one C(15) and one H(19) atom. The C(19)-H(19) bond length is 0.93 Å. In the twelfth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(3), and one O(4) atom. The C(20)-C(21) bond length is 1.49 Å. The C(20)-O(3) bond length is 1.27 Å. The C(20)-O(4) bond length is 1.25 Å. In the thirteenth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(24) bond length is 1.40 Å. In the fourteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one N(4) atom. The C(22)-C(23) bond length is 1.49 Å. The C(22)-N(4) bond length is 1.36 Å. In the fifteenth C site, C(23) is bonded in a trigonal non-coplanar geometry to one C(22) and three equivalent H(20,21,22) atoms. All C(23)-H(20,21,22) bond lengths are 0.96 Å. In the sixteenth C site, C(24) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(26) atom. The C(24)-C(25) bond length is 1.41 Å. The C(24)-C(26) bond length is 1.50 Å. In the seventeenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one C(27), and one N(4) atom. The C(25)-C(27) bond length is 1.42 Å. The C(25)-N(4) bond length is 1.40 Å. In the eighteenth C site, C(26) is bonded in a trigonal non-coplanar geometry to one C(24) and three equivalent H(23,24,25) atoms. All C(26)-H(23,24,25) bond lengths are 0.96 Å. In the nineteenth C site, C(27) is bonded in a trigonal planar geometry to one C(25), one C(28), and one C(34) atom. The C(27)-C(28) bond length is 1.44 Å. The C(27)-C(34) bond length is 1.41 Å. In the twentieth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(33) atom. The C(28)-C(29) bond length is 1.38 Å. The C(28)-C(33) bond length is 1.39 Å. In the twenty-first C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(26) atom. The C(29)-H(26) bond length is 0.93 Å. In the twenty-second C site, C(33) is bonded in a distorted single-bond geometry to one C(28) and one H(30) atom. The C(33)-H(30) bond length is 0.93 Å. In the twenty-third C site, C(34) is bonded in a distorted trigonal planar geometry to one C(27), one C(35), and one N(3) atom. The C(34)-C(35) bond length is 1.41 Å. The C(34)-N(3) bond length is 1.40 Å. In the twenty-fourth C site, C(35) is bonded in a trigonal planar geometry to one C(34), one C(36), and one C(37) atom. The C(35)-C(36) bond length is 1.49 Å. The C(35)-C(37) bond length is 1.41 Å. In the twenty-fifth C site, C(36) is bonded in a trigonal non-coplanar geometry to one C(35) and three equivalent H(31,32,33) atoms. All C(36)-H(31,32,33) bond lengths are 0.96 Å. In the twenty-sixth C site, C(37) is bonded in a trigonal planar geometry to one C(35), one C(38), and one C(40) atom. The C(37)-C(38) bond length is 1.42 Å. The C(37)-C(40) bond length is 1.49 Å. In the twenty-seventh C site, C(38) is bonded in a distorted trigonal planar geometry to one C(37), one C(39), and one N(3) atom. The C(38)-C(39) bond length is 1.48 Å. The C(38)-N(3) bond length is 1.35 Å. In the twenty-eighth C site, C(39) is bonded in a trigonal non-coplanar geometry to one C(38); one H(34); and two equivalent H(35,36) atoms. The C(39)-H(34) bond length is 0.96 Å. Both C(39)-H(35,36) bond lengths are 0.96 Å. In the twenty-ninth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(1), and one O(2) atom. The C(40)-O(1) bond length is 1.27 Å. The C(40)-O(2) bond length is 1.27 Å. In the thirtieth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(42), one O(5), and one O(6) atom. The C(41)-C(42) bond length is 1.47 Å. The C(41)-O(5) bond length is 1.27 Å. The C(41)-O(6) bond length is 1.27 Å. In the thirty-first C site, C(42) is bonded in a trigonal planar geometry to one C(41), one C(43), and one C(45) atom. The C(42)-C(43) bond length is 1.42 Å. The C(42)-C(45) bond length is 1.41 Å. In the thirty-second C site, C(43) is bonded in a distorted trigonal planar geometry to one C(42), one C(44), and one N(5) atom. The C(43)-C(44) bond length is 1.50 Å. The C(43)-N(5) bond length is 1.37 Å. In the thirty-third C site, C(44) is bonded in a trigonal non-coplanar geometry to one C(43); one H(37); and two equivalent H(38,39) atoms. The C(44)-H(37) bond length is 0.96 Å. Both C(44)-H(38,39) bond lengths are 0.96 Å. In the thirty-fourth C site, C(45) is bonded in a trigonal planar geometry to one C(42), one C(46), and one C(47) atom. The C(45)-C(46) bond length is 1.49 Å. The C(45)-C(47) bond length is 1.39 Å. In the thirty-fifth C site, C(46) is bonded in a trigonal non-coplanar geometry to one C(45) and three equivalent H(40,41,42) atoms. All C(46)-H(40,41,42) bond lengths are 0.96 Å. In the thirty-sixth C site, C(47) is bonded in a distorted trigonal planar geometry to one C(45), one C(55), and one N(5) atom. The C(47)-C(55) bond length is 1.45 Å. The C(47)-N(5) bond length is 1.40 Å. In the thirty-seventh C site, C(48) is bonded in a distorted trigonal planar geometry to one C(53), one C(55), and one N(6) atom. The C(48)-C(53) bond length is 1.39 Å. The C(48)-C(55) bond length is 1.47 Å. The C(48)-N(6) bond length is 1.39 Å. In the thirty-eighth C site, C(49) is bonded in a distorted trigonal planar geometry to one C(50), one C(51), and one N(6) atom. The C(49)-C(50) bond length is 1.49 Å. The C(49)-C(51) bond length is 1.40 Å. The C(49)-N(6) bond length is 1.37 Å. In the thirty-ninth C site, C(50) is bonded in a trigonal non-coplanar geometry to one C(49); one H(43); and two equivalent H(44,45) atoms. The C(50)-H(43) bond length is 0.96 Å. Both C(50)-H(44,45) bond lengths are 0.96 Å. In the fortieth C site, C(51) is bonded in a trigonal planar geometry to one C(49), one C(52), and one C(53) atom. The C(51)-C(52) bond length is 1.49 Å. The C(51)-C(53) bond length is 1.41 Å. In the forty-first C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(51), one O(7), and one O(8) atom. The C(52)-O(7) bond length is 1.27 Å. The C(52)-O(8) bond length is 1.26 Å. In the forty-second C site, C(53) is bonded in a trigonal planar geometry to one C(48), one C(51), and one C(54) atom. The C(53)-C(54) bond length is 1.50 Å. In the forty-third C site, C(54) is bonded in a trigonal non-coplanar geometry to one C(53) and three equivalent H(46,47,48) atoms. All C(54)-H(46,47,48) bond lengths are 0.96 Å. In the forty-fourth C site, C(55) is bonded in a trigonal planar geometry to one C(1), one C(47), and one C(48) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(17), and one C(18) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(2), one C(11), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one B(1), one C(34), and one C(38) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one B(1), one C(22), and one C(25) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one B(2), one C(43), and one C(47) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one B(2), one C(48), and one C(49) atom. There are twenty-one inequivalent H sites. In the first H site, H(1,5) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(14,15) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(20,21,22) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(23,24,25) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(26) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(30) is bonded in a single-bond geometry to one C(33) atom. In the thirteenth H site, H(31,32,33) is bonded in a single-bond geometry to one C(36) atom. In the fourteenth H site, H(34) is bonded in a single-bond geometry to one C(39) atom. In the fifteenth H site, H(35,36) is bonded in a single-bond geometry to one C(39) atom. In the sixteenth H site, H(37) is bonded in a single-bond geometry to one C(44) atom. In the seventeenth H site, H(38,39) is bonded in a single-bond geometry to one C(44) atom. In the eighteenth H site, H(40,41,42) is bonded in a single-bond geometry to one C(46) atom. In the nineteenth H site, H(43) is bonded in a single-bond geometry to one C(50) atom. In the twentieth H site, H(44,45) is bonded in a single-bond geometry to one C(50) atom. In the twenty-first H site, H(46,47,48) is bonded in a single-bond geometry to one C(54) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a 1-coordinate geometry to one Cd(1), one Cd(2), and one C(40) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Cd(1) and one C(40) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(2), and one C(20) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(2) and one C(20) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(41) atom. In the sixth O site, O(6) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(41) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(52) atom. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(52) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one B(1) atom. In the second F site, F(2) is bonded in a single-bond geometry to one B(1) atom. In the third F site, F(3) is bonded in a single-bond geometry to one B(2) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one B(2) atom. Linkers: 8 [O]C(=O)c1c(C)c2n(c1C)[B](F)(F)n1c([C]2c2ccccc2)c(C)c(c1C)C(=O)[O] ,4 c1cc(CCCc2ccncc2)ccn1. Metal clusters: 2 [C]1O[Cd]2O[C]O[Cd]3(O1)(O[C]O[Cd]1O[C]O[Cd]4(O[C]O1)(O[C]O2)O[C]O4)O[C]O3. The MOF has largest included sphere 4.55 A, density 1.42 g/cm3, surface area 4223.80 m2/g, accessible volume 0.29 cm3/g