Zn4C30H18S6O13 crystallizes in the triclinic P1 space group. There are eight inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(11), one O(3), and one O(7) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.94 Å. The Zn(1)-O(11) bond length is 1.93 Å. The Zn(1)-O(3) bond length is 1.93 Å. The Zn(1)-O(7) bond length is 1.93 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(14), one O(4), and one O(9) atom to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(1) bond length is 1.94 Å. The Zn(2)-O(14) bond length is 1.93 Å. The Zn(2)-O(4) bond length is 1.93 Å. The Zn(2)-O(9) bond length is 1.93 Å. In the third Zn site, Zn(3) is bonded to one O(1), one O(10), one O(12), and one O(5) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(1) bond length is 1.94 Å. The Zn(3)-O(10) bond length is 1.93 Å. The Zn(3)-O(12) bond length is 1.93 Å. The Zn(3)-O(5) bond length is 1.93 Å. In the fourth Zn site, Zn(4) is bonded to one O(1), one O(13), one O(6), and one O(8) atom to form corner-sharing ZnO4 tetrahedra. The Zn(4)-O(1) bond length is 1.94 Å. The Zn(4)-O(13) bond length is 1.93 Å. The Zn(4)-O(6) bond length is 1.93 Å. The Zn(4)-O(8) bond length is 1.93 Å. In the fifth Zn site, Zn(5) is bonded to one O(15), one O(19), one O(2), and one O(23) atom to form corner-sharing ZnO4 tetrahedra. The Zn(5)-O(15) bond length is 1.93 Å. The Zn(5)-O(19) bond length is 1.93 Å. The Zn(5)-O(2) bond length is 1.94 Å. The Zn(5)-O(23) bond length is 1.93 Å. In the sixth Zn site, Zn(6) is bonded to one O(16), one O(2), one O(21), and one O(26) atom to form corner-sharing ZnO4 tetrahedra. The Zn(6)-O(16) bond length is 1.93 Å. The Zn(6)-O(2) bond length is 1.94 Å. The Zn(6)-O(21) bond length is 1.93 Å. The Zn(6)-O(26) bond length is 1.93 Å. In the seventh Zn site, Zn(7) is bonded to one O(17), one O(2), one O(22), and one O(24) atom to form corner-sharing ZnO4 tetrahedra. The Zn(7)-O(17) bond length is 1.93 Å. The Zn(7)-O(2) bond length is 1.94 Å. The Zn(7)-O(22) bond length is 1.93 Å. The Zn(7)-O(24) bond length is 1.93 Å. In the eighth Zn site, Zn(8) is bonded to one O(18), one O(2), one O(20), and one O(25) atom to form corner-sharing ZnO4 tetrahedra. The Zn(8)-O(18) bond length is 1.93 Å. The Zn(8)-O(2) bond length is 1.94 Å. The Zn(8)-O(20) bond length is 1.93 Å. The Zn(8)-O(25) bond length is 1.93 Å. There are sixty inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(37), and one C(43) atom. The C(1)-C(2) bond length is 1.28 Å. The C(1)-C(37) bond length is 1.80 Å. The C(1)-C(43) bond length is 1.80 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one S(1), and one S(7) atom. The C(2)-S(1) bond length is 1.80 Å. The C(2)-S(7) bond length is 1.80 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(4), one S(2), and one S(8) atom. The C(3)-C(4) bond length is 1.28 Å. The C(3)-S(2) bond length is 1.80 Å. The C(3)-S(8) bond length is 1.80 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(38), and one C(44) atom. The C(4)-C(38) bond length is 1.80 Å. The C(4)-C(44) bond length is 1.80 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(39), one C(48), and one C(6) atom. The C(5)-C(39) bond length is 1.80 Å. The C(5)-C(48) bond length is 1.80 Å. The C(5)-C(6) bond length is 1.28 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one S(12), and one S(3) atom. The C(6)-S(12) bond length is 1.80 Å. The C(6)-S(3) bond length is 1.80 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(8), one S(11), and one S(4) atom. The C(7)-C(8) bond length is 1.28 Å. The C(7)-S(11) bond length is 1.80 Å. The C(7)-S(4) bond length is 1.80 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(40), one C(47), and one C(7) atom. The C(8)-C(40) bond length is 1.80 Å. The C(8)-C(47) bond length is 1.80 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one S(10), and one S(5) atom. The C(9)-C(10) bond length is 1.28 Å. The C(9)-S(10) bond length is 1.80 Å. The C(9)-S(5) bond length is 1.80 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(41), one C(46), and one C(9) atom. The C(10)-C(41) bond length is 1.80 Å. The C(10)-C(46) bond length is 1.80 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(12), one S(6), and one S(9) atom. The C(11)-C(12) bond length is 1.28 Å. The C(11)-S(6) bond length is 1.80 Å. The C(11)-S(9) bond length is 1.80 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(42), and one C(45) atom. The C(12)-C(42) bond length is 1.80 Å. The C(12)-C(45) bond length is 1.80 Å. In the thirteenth C site, C(13) is bonded in a bent 120 degrees geometry to one C(14), one O(3), and one O(4) atom. The C(13)-C(14) bond length is 1.44 Å. The C(13)-O(3) bond length is 1.24 Å. The C(13)-O(4) bond length is 1.24 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(37), and one S(1) atom. The C(14)-C(37) bond length is 1.74 Å. The C(14)-S(1) bond length is 1.74 Å. In the fifteenth C site, C(15) is bonded in a bent 120 degrees geometry to one C(16), one O(5), and one O(6) atom. The C(15)-C(16) bond length is 1.44 Å. The C(15)-O(5) bond length is 1.24 Å. The C(15)-O(6) bond length is 1.24 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(38), and one S(2) atom. The C(16)-C(38) bond length is 1.74 Å. The C(16)-S(2) bond length is 1.74 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(7), and one O(8) atom. The C(17)-C(18) bond length is 1.44 Å. The C(17)-O(7) bond length is 1.24 Å. The C(17)-O(8) bond length is 1.24 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(39), and one S(3) atom. The C(18)-C(39) bond length is 1.74 Å. The C(18)-S(3) bond length is 1.74 Å. In the nineteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(10), and one O(9) atom. The C(19)-C(20) bond length is 1.44 Å. The C(19)-O(10) bond length is 1.24 Å. The C(19)-O(9) bond length is 1.24 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(40), and one S(4) atom. The C(20)-C(40) bond length is 1.74 Å. The C(20)-S(4) bond length is 1.74 Å. In the twenty-first C site, C(21) is bonded in a bent 120 degrees geometry to one C(22), one O(11), and one O(12) atom. The C(21)-C(22) bond length is 1.44 Å. The C(21)-O(11) bond length is 1.24 Å. The C(21)-O(12) bond length is 1.24 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(41), and one S(5) atom. The C(22)-C(41) bond length is 1.74 Å. The C(22)-S(5) bond length is 1.74 Å. In the twenty-third C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(13), and one O(14) atom. The C(23)-C(24) bond length is 1.44 Å. The C(23)-O(13) bond length is 1.24 Å. The C(23)-O(14) bond length is 1.24 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(42), and one S(6) atom. The C(24)-C(42) bond length is 1.74 Å. The C(24)-S(6) bond length is 1.74 Å. In the twenty-fifth C site, C(25) is bonded in a bent 120 degrees geometry to one C(26), one O(15), and one O(16) atom. The C(25)-C(26) bond length is 1.44 Å. The C(25)-O(15) bond length is 1.24 Å. The C(25)-O(16) bond length is 1.24 Å. In the twenty-sixth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(43), and one S(7) atom. The C(26)-C(43) bond length is 1.74 Å. The C(26)-S(7) bond length is 1.74 Å. In the twenty-seventh C site, C(27) is bonded in a bent 120 degrees geometry to one C(28), one O(17), and one O(18) atom. The C(27)-C(28) bond length is 1.44 Å. The C(27)-O(17) bond length is 1.24 Å. The C(27)-O(18) bond length is 1.24 Å. In the twenty-eighth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(44), and one S(8) atom. The C(28)-C(44) bond length is 1.74 Å. The C(28)-S(8) bond length is 1.74 Å. In the twenty-ninth C site, C(29) is bonded in a bent 120 degrees geometry to one C(30), one O(19), and one O(20) atom. The C(29)-C(30) bond length is 1.44 Å. The C(29)-O(19) bond length is 1.24 Å. The C(29)-O(20) bond length is 1.24 Å. In the thirtieth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(45), and one S(9) atom. The C(30)-C(45) bond length is 1.74 Å. The C(30)-S(9) bond length is 1.74 Å. In the thirty-first C site, C(31) is bonded in a bent 120 degrees geometry to one C(32), one O(21), and one O(22) atom. The C(31)-C(32) bond length is 1.44 Å. The C(31)-O(21) bond length is 1.24 Å. The C(31)-O(22) bond length is 1.24 Å. In the thirty-second C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(46), and one S(10) atom. The C(32)-C(46) bond length is 1.74 Å. The C(32)-S(10) bond length is 1.74 Å. In the thirty-third C site, C(33) is bonded in a bent 120 degrees geometry to one C(34), one O(23), and one O(24) atom. The C(33)-C(34) bond length is 1.44 Å. The C(33)-O(23) bond length is 1.24 Å. The C(33)-O(24) bond length is 1.24 Å. In the thirty-fourth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(47), and one S(11) atom. The C(34)-C(47) bond length is 1.74 Å. The C(34)-S(11) bond length is 1.74 Å. In the thirty-fifth C site, C(35) is bonded in a bent 120 degrees geometry to one C(36), one O(25), and one O(26) atom. The C(35)-C(36) bond length is 1.44 Å. The C(35)-O(25) bond length is 1.24 Å. The C(35)-O(26) bond length is 1.24 Å. In the thirty-sixth C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(48), and one S(12) atom. The C(36)-C(48) bond length is 1.74 Å. The C(36)-S(12) bond length is 1.74 Å. In the thirty-seventh C site, C(37) is bonded in a single-bond geometry to one C(1), one C(14), and one C(59) atom. The C(37)-C(59) bond length is 1.14 Å. In the thirty-eighth C site, C(38) is bonded in a single-bond geometry to one C(16), one C(4), and one C(49) atom. The C(38)-C(49) bond length is 1.14 Å. In the thirty-ninth C site, C(39) is bonded in a distorted single-bond geometry to one C(18), one C(5), and one C(51) atom. The C(39)-C(51) bond length is 1.14 Å. In the fortieth C site, C(40) is bonded in a single-bond geometry to one C(20), one C(53), and one C(8) atom. The C(40)-C(53) bond length is 1.14 Å. In the forty-first C site, C(41) is bonded in a single-bond geometry to one C(10), one C(22), and one C(57) atom. The C(41)-C(57) bond length is 1.14 Å. In the forty-second C site, C(42) is bonded in a distorted single-bond geometry to one C(12), one C(24), and one C(55) atom. The C(42)-C(55) bond length is 1.14 Å. In the forty-third C site, C(43) is bonded in a single-bond geometry to one C(1), one C(26), and one C(60) atom. The C(43)-C(60) bond length is 1.14 Å. In the forty-fourth C site, C(44) is bonded in a single-bond geometry to one C(28), one C(4), and one C(50) atom. The C(44)-C(50) bond length is 1.14 Å. In the forty-fifth C site, C(45) is bonded in a distorted single-bond geometry to one C(12), one C(30), and one C(56) atom. The C(45)-C(56) bond length is 1.14 Å. In the forty-sixth C site, C(46) is bonded in a single-bond geometry to one C(10), one C(32), and one C(58) atom. The C(46)-C(58) bond length is 1.14 Å. In the forty-seventh C site, C(47) is bonded in a single-bond geometry to one C(34), one C(54), and one C(8) atom. The C(47)-C(54) bond length is 1.14 Å. In the forty-eighth C site, C(48) is bonded in a distorted single-bond geometry to one C(36), one C(5), and one C(52) atom. The C(48)-C(52) bond length is 1.14 Å. In the forty-ninth C site, C(49) is bonded in a tetrahedral geometry to one C(38), one H(1), one H(2), and one H(3) atom. The C(49)-H(1) bond length is 1.14 Å. The C(49)-H(2) bond length is 1.14 Å. The C(49)-H(3) bond length is 1.14 Å. In the fiftieth C site, C(50) is bonded in a tetrahedral geometry to one C(44), one H(4), one H(5), and one H(6) atom. The C(50)-H(4) bond length is 1.14 Å. The C(50)-H(5) bond length is 1.14 Å. The C(50)-H(6) bond length is 1.14 Å. In the fifty-first C site, C(51) is bonded in a tetrahedral geometry to one C(39), one H(7), one H(8), and one H(9) atom. The C(51)-H(7) bond length is 1.14 Å. The C(51)-H(8) bond length is 1.14 Å. The C(51)-H(9) bond length is 1.14 Å. In the fifty-second C site, C(52) is bonded in a tetrahedral geometry to one C(48), one H(10), one H(11), and one H(12) atom. The C(52)-H(10) bond length is 1.14 Å. The C(52)-H(11) bond length is 1.14 Å. The C(52)-H(12) bond length is 1.14 Å. In the fifty-third C site, C(53) is bonded in a tetrahedral geometry to one C(40), one H(13), one H(14), and one H(34) atom. The C(53)-H(13) bond length is 1.14 Å. The C(53)-H(14) bond length is 1.14 Å. The C(53)-H(34) bond length is 1.14 Å. In the fifty-fourth C site, C(54) is bonded in a tetrahedral geometry to one C(47), one H(15), one H(16), and one H(36) atom. The C(54)-H(15) bond length is 1.14 Å. The C(54)-H(16) bond length is 1.14 Å. The C(54)-H(36) bond length is 1.14 Å. In the fifty-fifth C site, C(55) is bonded in a tetrahedral geometry to one C(42), one H(17), one H(18), and one H(19) atom. The C(55)-H(17) bond length is 1.14 Å. The C(55)-H(18) bond length is 1.14 Å. The C(55)-H(19) bond length is 1.14 Å. In the fifty-sixth C site, C(56) is bonded in a tetrahedral geometry to one C(45), one H(20), one H(21), and one H(22) atom. The C(56)-H(20) bond length is 1.14 Å. The C(56)-H(21) bond length is 1.14 Å. The C(56)-H(22) bond length is 1.14 Å. In the fifty-seventh C site, C(57) is bonded in a tetrahedral geometry to one C(41), one H(23), one H(24), and one H(25) atom. The C(57)-H(23) bond length is 1.14 Å. The C(57)-H(24) bond length is 1.14 Å. The C(57)-H(25) bond length is 1.14 Å. In the fifty-eighth C site, C(58) is bonded in a tetrahedral geometry to one C(46), one H(26), one H(27), and one H(35) atom. The C(58)-H(26) bond length is 1.14 Å. The C(58)-H(27) bond length is 1.14 Å. The C(58)-H(35) bond length is 1.14 Å. In the fifty-ninth C site, C(59) is bonded in a tetrahedral geometry to one C(37), one H(28), one H(29), and one H(30) atom. The C(59)-H(28) bond length is 1.14 Å. The C(59)-H(29) bond length is 1.14 Å. The C(59)-H(30) bond length is 1.14 Å. In the sixtieth C site, C(60) is bonded in a tetrahedral geometry to one C(43), one H(31), one H(32), and one H(33) atom. The C(60)-H(31) bond length is 1.14 Å. The C(60)-H(32) bond length is 1.14 Å. The C(60)-H(33) bond length is 1.14 Å. There are thirty-six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(49) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(49) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(49) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(50) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(50) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(50) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(51) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(51) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(51) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(52) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(52) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(52) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(53) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(53) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(54) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(54) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(55) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(55) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(55) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(56) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(56) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(56) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(57) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(57) atom. In the twenty-fifth H site, H(25) is bonded in a single-bond geometry to one C(57) atom. In the twenty-sixth H site, H(26) is bonded in a single-bond geometry to one C(58) atom. In the twenty-seventh H site, H(27) is bonded in a single-bond geometry to one C(58) atom. In the twenty-eighth H site, H(28) is bonded in a single-bond geometry to one C(59) atom. In the twenty-ninth H site, H(29) is bonded in a single-bond geometry to one C(59) atom. In the thirtieth H site, H(30) is bonded in a single-bond geometry to one C(59) atom. In the thirty-first H site, H(31) is bonded in a single-bond geometry to one C(60) atom. In the thirty-second H site, H(32) is bonded in a single-bond geometry to one C(60) atom. In the thirty-third H site, H(33) is bonded in a single-bond geometry to one C(60) atom. In the thirty-fourth H site, H(34) is bonded in a 2-coordinate geometry to one C(53) and one O(10) atom. The H(34)-O(10) bond length is 1.60 Å. In the thirty-fifth H site, H(35) is bonded in a bent 150 degrees geometry to one C(58) and one O(21) atom. The H(35)-O(21) bond length is 1.53 Å. In the thirty-sixth H site, H(36) is bonded in a bent 150 degrees geometry to one C(54) and one O(23) atom. The H(36)-O(23) bond length is 1.53 Å. There are twelve inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(14) and one C(2) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one C(16) and one C(3) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one C(18) and one C(6) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one C(20) and one C(7) atom. In the fifth S site, S(5) is bonded in an L-shaped geometry to one C(22) and one C(9) atom. In the sixth S site, S(6) is bonded in an L-shaped geometry to one C(11) and one C(24) atom. In the seventh S site, S(7) is bonded in an L-shaped geometry to one C(2) and one C(26) atom. In the eighth S site, S(8) is bonded in an L-shaped geometry to one C(28) and one C(3) atom. In the ninth S site, S(9) is bonded in an L-shaped geometry to one C(11) and one C(30) atom. In the tenth S site, S(10) is bonded in an L-shaped geometry to one C(32) and one C(9) atom. In the eleventh S site, S(11) is bonded in an L-shaped geometry to one C(34) and one C(7) atom. In the twelfth S site, S(12) is bonded in an L-shaped geometry to one C(36) and one C(6) atom. There are twenty-six inequivalent O sites. In the first O site, O(1) is bonded in a tetrahedral geometry to one Zn(1), one Zn(2), one Zn(3), and one Zn(4) atom. In the second O site, O(2) is bonded in a tetrahedral geometry to one Zn(5), one Zn(6), one Zn(7), and one Zn(8) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(13) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(15) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(15) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(17) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(19) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Zn(3), one C(19), and one H(34) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(21) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(21) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(23) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(23) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Zn(5) and one C(25) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Zn(6) and one C(25) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Zn(7) and one C(27) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Zn(8) and one C(27) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Zn(5) and one C(29) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Zn(8) and one C(29) atom. In the twenty-first O site, O(21) is bonded in a trigonal planar geometry to one Zn(6), one C(31), and one H(35) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Zn(7) and one C(31) atom. In the twenty-third O site, O(23) is bonded in a trigonal planar geometry to one Zn(5), one C(33), and one H(36) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 120 degrees geometry to one Zn(7) and one C(33) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 120 degrees geometry to one Zn(8) and one C(35) atom. In the twenty-sixth O site, O(26) is bonded in a distorted bent 120 degrees geometry to one Zn(6) and one C(35) atom. Linkers: 6 Cc1c(C([O])=O)sc2sc(C([O])=O)c(C)c12. Metal clusters: 2 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: pcu. The MOF has largest included sphere 17.26 A, density 0.56 g/cm3, surface area 3883.83 m2/g, accessible volume 1.36 cm3/g