Zn4C36H12O13(CH)12 crystallizes in the cubic I-43d space group. The structure consists of one hundred and ninety-two 02329_fluka molecules inside a Zn4C36H12O13 framework. In the Zn4C36H12O13 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form distorted corner-sharing ZnO4 trigonal pyramids. The Zn(1)-O(1) bond length is 2.14 Å. The Zn(1)-O(2) bond length is 2.02 Å. The Zn(1)-O(3) bond length is 2.03 Å. The Zn(1)-O(5) bond length is 1.97 Å. In the second Zn site, Zn(2) is bonded to one O(5) and three equivalent O(4) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(5) bond length is 1.93 Å. All Zn(2)-O(4) bond lengths are 1.99 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(11), one C(2), and one C(3) atom. The C(1)-C(11) bond length is 1.39 Å. The C(1)-C(2) bond length is 1.43 Å. The C(1)-C(3) bond length is 1.47 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(15), and one C(5) atom. The C(2)-C(15) bond length is 1.42 Å. The C(2)-C(5) bond length is 1.45 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(5)-H(3) bond length is 0.93 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(1), and one O(4) atom. The C(7)-C(11) bond length is 1.51 Å. The C(7)-O(1) bond length is 1.26 Å. The C(7)-O(4) bond length is 1.21 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(8)-C(10) bond length is 1.38 Å. The C(8)-H(5) bond length is 0.93 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(13) and one H(6) atom. The C(9)-C(13) bond length is 1.46 Å. The C(9)-H(6) bond length is 0.93 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(8) atom. The C(10)-C(13) bond length is 1.42 Å. The C(10)-C(15) bond length is 1.45 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(7) atom. The C(11)-C(13) bond length is 1.44 Å. In the tenth C site, C(13) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(9) atom. In the eleventh C site, C(15) is bonded in a trigonal planar geometry to one C(10), one C(16), and one C(2) atom. The C(15)-C(16) bond length is 1.50 Å. In the twelfth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(2), and one O(3) atom. The C(16)-O(2) bond length is 1.27 Å. The C(16)-O(3) bond length is 1.28 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. There are five inequivalent O sites. In the first O site, O(5) is bonded in a tetrahedral geometry to one Zn(2) and three equivalent Zn(1) atoms. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the third O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(16) atom. In the fourth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(16) atom. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(7) atom. Linkers: 24 [O]C(=O)c1c2ccccc2c(C([O])=O)c2ccccc12. Metal clusters: 8 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: bcs. The MOF has largest included sphere 6.94 A, density 1.19 g/cm3, surface area 3978.41 m2/g, accessible volume 0.50 cm3/g