CuH8(C4N)4AlH2(C3O2)2(CH)6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules, four AlH2(C3O2)2 clusters, and four CuH8(C4N)4 clusters. In each AlH2(C3O2)2 cluster, Al(1) is bonded in a tetrahedral geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Al(1)-O(1) bond length is 1.73 Å. The Al(1)-O(2) bond length is 1.73 Å. The Al(1)-O(3) bond length is 1.72 Å. The Al(1)-O(4) bond length is 1.74 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one O(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-O(1) bond length is 1.33 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.95 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.95 Å. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one O(2) atom. The C(8)-O(2) bond length is 1.34 Å. In the fifth C site, C(15) is bonded in a distorted single-bond geometry to one O(3) atom. The C(15)-O(3) bond length is 1.33 Å. In the sixth C site, C(22) is bonded in a distorted single-bond geometry to one O(4) atom. The C(22)-O(4) bond length is 1.33 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Al(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Al(1) and one C(8) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Al(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Al(1) and one C(22) atom. In each CuH8(C4N)4 cluster, Cu(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-N(2) bond length is 2.02 Å. The Cu(1)-N(3) bond length is 1.99 Å. The Cu(1)-N(4) bond length is 2.00 Å. There are sixteen inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(2) bond length is 0.95 Å. In the second C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-C(7) bond length is 1.43 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 0.95 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(4) and one N(4) atom. The C(7)-N(4) bond length is 1.14 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(6) bond length is 0.95 Å. In the sixth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(14) bond length is 1.43 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 0.95 Å. In the eighth C site, C(14) is bonded in a distorted linear geometry to one C(11) and one N(2) atom. The C(14)-N(2) bond length is 1.14 Å. In the ninth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(10) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(10) bond length is 0.95 Å. In the tenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(21) atom. The C(18)-C(19) bond length is 1.38 Å. The C(18)-C(21) bond length is 1.43 Å. In the eleventh C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(11) atom. The C(19)-H(11) bond length is 0.95 Å. In the twelfth C site, C(21) is bonded in a distorted linear geometry to one C(18) and one N(3) atom. The C(21)-N(3) bond length is 1.14 Å. In the thirteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(25) and one H(13,15) atom. The C(23)-C(25) bond length is 1.39 Å. The C(23)-H(13,15) bond length is 0.95 Å. In the fourteenth C site, C(25) is bonded in a trigonal planar geometry to one C(23), one C(26), and one C(28) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-C(28) bond length is 1.44 Å. In the fifteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(13,15) atom. The C(26)-H(13,15) bond length is 0.95 Å. In the sixteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(25) and one N(1) atom. The C(28)-N(1) bond length is 1.14 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a linear geometry to one Cu(1) and one C(28) atom. In the second N site, N(2) is bonded in a linear geometry to one Cu(1) and one C(14) atom. In the third N site, N(3) is bonded in a linear geometry to one Cu(1) and one C(21) atom. In the fourth N site, N(4) is bonded in a linear geometry to one Cu(1) and one C(7) atom. There are seven inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(13,15) is bonded in a single-bond geometry to one C(23) atom. Linkers: 16 N#Cc1ccc([O])cc1. Metal clusters: 4 [Al] ,4 [Cu]. The MOF has largest included sphere 4.62 A, density 1.20 g/cm3, surface area 4937.61 m2/g, accessible volume 0.39 cm3/g