AgH9(CN)3(CH2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules and eight AgH9(CN)3 clusters. In four of the AgH9(CN)3 clusters, Ag(1) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one N(2), and one N(6) atom. The Ag(1)-N(1) bond length is 2.23 Å. The Ag(1)-N(2) bond length is 2.36 Å. The Ag(1)-N(6) bond length is 2.24 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one N(1) and one H(13) atom. The C(1)-N(1) bond length is 1.49 Å. The C(1)-H(13) bond length is 0.98 Å. In the second C site, C(3) is bonded in a 2-coordinate geometry to one N(2) and one H(16) atom. The C(3)-N(2) bond length is 1.49 Å. The C(3)-H(16) bond length is 0.98 Å. In the third C site, C(11) is bonded in a 2-coordinate geometry to one N(6) and one H(28) atom. The C(11)-N(6) bond length is 1.47 Å. The C(11)-H(28) bond length is 0.98 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one Ag(1); one C(1); and two equivalent H(1,2,4) atoms. Both N(1)-H(1,2,4) bond lengths are 0.90 Å. In the second N site, N(2) is bonded in a 2-coordinate geometry to one Ag(1); one C(3); one H(1,2,4); and one H(3) atom. The N(2)-H(1,2,4) bond length is 0.90 Å. The N(2)-H(3) bond length is 0.90 Å. In the third N site, N(6) is bonded in a distorted water-like geometry to one Ag(1); one C(11); and two equivalent H(11,12) atoms. Both N(6)-H(11,12) bond lengths are 0.90 Å. There are six inequivalent H sites. In the first H site, H(28) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(1,2,4) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(11,12) is bonded in a single-bond geometry to one N(6) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(3) atom. In four of the AgH9(CN)3 clusters, Ag(2) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one N(4), and one N(5) atom. The Ag(2)-N(3) bond length is 2.44 Å. The Ag(2)-N(4) bond length is 2.22 Å. The Ag(2)-N(5) bond length is 2.21 Å. There are three inequivalent C sites. In the first C site, C(5) is bonded in a 2-coordinate geometry to one N(3) and one H(19) atom. The C(5)-N(3) bond length is 1.50 Å. The C(5)-H(19) bond length is 0.98 Å. In the second C site, C(7) is bonded in a 2-coordinate geometry to one N(4) and one H(22) atom. The C(7)-N(4) bond length is 1.48 Å. The C(7)-H(22) bond length is 0.98 Å. In the third C site, C(9) is bonded in a 2-coordinate geometry to one N(5) and one H(25) atom. The C(9)-N(5) bond length is 1.48 Å. The C(9)-H(25) bond length is 0.98 Å. There are three inequivalent N sites. In the first N site, N(3) is bonded in a 2-coordinate geometry to one Ag(2), one C(5), one H(5), and one H(6) atom. The N(3)-H(5) bond length is 0.90 Å. The N(3)-H(6) bond length is 0.90 Å. In the second N site, N(4) is bonded in a 2-coordinate geometry to one Ag(2); one C(7); and two equivalent H(7,8) atoms. Both N(4)-H(7,8) bond lengths are 0.90 Å. In the third N site, N(5) is bonded in a distorted water-like geometry to one Ag(2), one C(9), one H(10), and one H(9) atom. The N(5)-H(10) bond length is 0.90 Å. The N(5)-H(9) bond length is 0.90 Å. There are eight inequivalent H sites. In the first H site, H(25) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(5) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(6) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(7,8) is bonded in a single-bond geometry to one N(4) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one N(5) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one N(5) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(22) is bonded in a single-bond geometry to one C(7) atom. Linkers: 8 N[C@H]1C[C@H](N)C[C@@H](N)C1. Metal clusters: 8 [Ag]. The MOF has largest included sphere 3.89 A, density 1.55 g/cm3, surface area 3955.43 m2/g, accessible volume 0.27 cm3/g