ZnH30(C11O3)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two ZnH30(C11O3)4 clusters. Zn(1) is bonded in a distorted tetrahedral geometry to one O(11), one O(5), one O(7), and one O(9) atom. The Zn(1)-O(11) bond length is 1.95 Å. The Zn(1)-O(5) bond length is 2.01 Å. The Zn(1)-O(7) bond length is 1.94 Å. The Zn(1)-O(9) bond length is 1.97 Å. There are forty-four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(5) atom. The C(1)-C(10) bond length is 1.54 Å. The C(1)-C(14) bond length is 1.37 Å. The C(1)-C(5) bond length is 1.41 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(15), one C(31), and one H(1) atom. The C(2)-C(15) bond length is 1.37 Å. The C(2)-C(31) bond length is 1.40 Å. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(10), one C(31), and one O(6) atom. The C(3)-C(10) bond length is 1.38 Å. The C(3)-C(31) bond length is 1.37 Å. The C(3)-O(6) bond length is 1.44 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(5) atom. The C(4)-C(21) bond length is 1.54 Å. The C(4)-C(25) bond length is 1.37 Å. The C(4)-C(5) bond length is 1.37 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(1), one C(4), and one O(1) atom. The C(5)-O(1) bond length is 1.36 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(32) atom. The C(6)-C(29) bond length is 1.35 Å. The C(6)-C(31) bond length is 1.45 Å. The C(6)-C(32) bond length is 1.41 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(2), and one O(5) atom. The C(7)-C(12) bond length is 1.49 Å. The C(7)-O(2) bond length is 1.22 Å. The C(7)-O(5) bond length is 1.30 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(37), one C(38), and one C(42) atom. The C(8)-C(37) bond length is 1.49 Å. The C(8)-C(38) bond length is 1.37 Å. The C(8)-C(42) bond length is 1.37 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(15), one C(23), and one C(27) atom. The C(9)-C(15) bond length is 1.48 Å. The C(9)-C(23) bond length is 1.39 Å. The C(9)-C(27) bond length is 1.35 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(3) atom. The C(10)-C(13) bond length is 1.36 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(14), one C(25), and one C(30) atom. The C(11)-C(14) bond length is 1.38 Å. The C(11)-C(25) bond length is 1.42 Å. The C(11)-C(30) bond length is 1.45 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(20), one C(35), and one C(7) atom. The C(12)-C(20) bond length is 1.35 Å. The C(12)-C(35) bond length is 1.39 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(10), one C(15), and one O(3) atom. The C(13)-C(15) bond length is 1.41 Å. The C(13)-O(3) bond length is 1.38 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(1), one C(11), and one O(4) atom. The C(14)-O(4) bond length is 1.38 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(2), and one C(9) atom. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(21) and one H(2) atom. The C(16)-C(21) bond length is 1.40 Å. The C(16)-H(2) bond length is 0.93 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(21) and one H(3) atom. The C(17)-C(21) bond length is 1.42 Å. The C(17)-H(3) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a single-bond geometry to one C(30) and one H(4) atom. The C(18)-C(30) bond length is 1.40 Å. The C(18)-H(4) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(34) atom. The C(19)-C(24) bond length is 1.55 Å. The C(19)-C(26) bond length is 1.33 Å. The C(19)-C(34) bond length is 1.37 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(12) and one H(5) atom. The C(20)-H(5) bond length is 0.93 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(16), one C(17), and one C(4) atom. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(28) and one H(6) atom. The C(22)-C(28) bond length is 1.38 Å. The C(22)-H(6) bond length is 0.93 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(9) and one H(7) atom. The C(23)-H(7) bond length is 0.93 Å. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(10), and one O(7) atom. The C(24)-O(10) bond length is 1.25 Å. The C(24)-O(7) bond length is 1.29 Å. In the twenty-fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(11), one C(4), and one H(8) atom. The C(25)-H(8) bond length is 0.93 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(19) and one H(9) atom. The C(26)-H(9) bond length is 0.93 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(34), one C(9), and one H(10) atom. The C(27)-C(34) bond length is 1.45 Å. The C(27)-H(10) bond length is 0.93 Å. In the twenty-eighth C site, C(28) is bonded in a trigonal planar geometry to one C(22), one C(33), and one C(40) atom. The C(28)-C(33) bond length is 1.38 Å. The C(28)-C(40) bond length is 1.47 Å. In the twenty-ninth C site, C(29) is bonded in a distorted single-bond geometry to one C(6) and one H(11) atom. The C(29)-H(11) bond length is 0.93 Å. In the thirtieth C site, C(30) is bonded in a trigonal planar geometry to one C(11), one C(18), and one C(36) atom. The C(30)-C(36) bond length is 1.39 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(6) atom. In the thirty-second C site, C(32) is bonded in a distorted single-bond geometry to one C(6) and one H(12) atom. The C(32)-H(12) bond length is 0.93 Å. In the thirty-third C site, C(33) is bonded in a distorted single-bond geometry to one C(28) and one H(13) atom. The C(33)-H(13) bond length is 0.93 Å. In the thirty-fourth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(19), one C(27), and one H(14) atom. The C(34)-H(14) bond length is 0.93 Å. In the thirty-fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(12) and one H(15) atom. The C(35)-H(15) bond length is 0.93 Å. In the thirty-sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(30) and one H(16) atom. The C(36)-H(16) bond length is 0.93 Å. In the thirty-seventh C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(8), and one O(9) atom. The C(37)-O(8) bond length is 1.27 Å. The C(37)-O(9) bond length is 1.25 Å. In the thirty-eighth C site, C(38) is bonded in a distorted single-bond geometry to one C(8) and one H(17) atom. The C(38)-H(17) bond length is 0.93 Å. In the thirty-ninth C site, C(39) is bonded in a tetrahedral geometry to three equivalent H(18,19,20) and one O(4) atom. All C(39)-H(18,19,20) bond lengths are 0.96 Å. The C(39)-O(4) bond length is 1.46 Å. In the fortieth C site, C(40) is bonded in a bent 120 degrees geometry to one C(28), one O(11), and one O(12) atom. The C(40)-O(11) bond length is 1.29 Å. The C(40)-O(12) bond length is 1.24 Å. In the forty-first C site, C(41) is bonded in a tetrahedral geometry to one H(22); two equivalent H(21,23); and one O(6) atom. The C(41)-H(22) bond length is 0.96 Å. Both C(41)-H(21,23) bond lengths are 0.96 Å. The C(41)-O(6) bond length is 1.43 Å. In the forty-second C site, C(42) is bonded in a distorted single-bond geometry to one C(8) and one H(24) atom. The C(42)-H(24) bond length is 0.93 Å. In the forty-third C site, C(43) is bonded in a tetrahedral geometry to one H(26); two equivalent H(25,27); and one O(1) atom. The C(43)-H(26) bond length is 0.96 Å. Both C(43)-H(25,27) bond lengths are 0.96 Å. The C(43)-O(1) bond length is 1.42 Å. In the forty-fourth C site, C(44) is bonded in a tetrahedral geometry to one H(29); two equivalent H(28,30); and one O(3) atom. The C(44)-H(29) bond length is 0.96 Å. Both C(44)-H(28,30) bond lengths are 0.96 Å. The C(44)-O(3) bond length is 1.52 Å. There are twenty-five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(16) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(20) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(22) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(23) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(27) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(32) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(33) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(34) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(35) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(36) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(38) atom. In the eighteenth H site, H(18,19,20) is bonded in a single-bond geometry to one C(39) atom. In the nineteenth H site, H(21,23) is bonded in a single-bond geometry to one C(41) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(41) atom. In the twenty-first H site, H(24) is bonded in a single-bond geometry to one C(42) atom. In the twenty-second H site, H(25,27) is bonded in a single-bond geometry to one C(43) atom. In the twenty-third H site, H(26) is bonded in a single-bond geometry to one C(43) atom. In the twenty-fourth H site, H(28,30) is bonded in a single-bond geometry to one C(44) atom. In the twenty-fifth H site, H(29) is bonded in a single-bond geometry to one C(44) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(43) and one C(5) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one C(7) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(13) and one C(44) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(14) and one C(39) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Zn(1) and one C(7) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one C(3) and one C(41) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(24) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(37) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(37) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(24) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Zn(1) and one C(40) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one C(40) atom. Linkers: 2 COc1c(-c2ccc(C([O])=O)cc2)cc(-c2ccc(C([O])=O)cc2)c(OC)c1-c1c(OC)c(-c2ccc(C([O])=O)cc2)cc(-c2ccc(C([O])=O)cc2)c1OC. Metal clusters: 2 O=[C]O[Zn](O[C]=O)(O[C]=O)O[C]=O. RCSR code: dia. The MOF has largest included sphere 8.73 A, density 0.74 g/cm3, surface area 4908.26 m2/g, accessible volume 0.80 cm3/g