AlH9(C2O)4 crystallizes in the triclinic P1 space group. There are twelve inequivalent Al sites. In the first Al site, Al(1) is bonded to one O(1), one O(2), one O(3), one O(5), one O(7), and one O(8) atom to form AlO6 octahedra that share  a cornercorner with one C(13)H3O tetrahedra,  a cornercorner with one C(14)H3O tetrahedra,  a cornercorner with one C(15)H3O tetrahedra,  a cornercorner with one C(16)H3O tetrahedra,  an edgeedge with one Al(12)O6 octahedra, and  an edgeedge with one Al(2)O6 octahedra. The Al(1)-O(1) bond length is 1.89 Å. The Al(1)-O(2) bond length is 1.95 Å. The Al(1)-O(3) bond length is 1.87 Å. The Al(1)-O(5) bond length is 1.89 Å. The Al(1)-O(7) bond length is 2.02 Å. The Al(1)-O(8) bond length is 1.96 Å. In the second Al site, Al(2) is bonded to one O(2), one O(38), one O(39), one O(4), one O(40), and one O(5) atom to form AlO6 octahedra that share  a cornercorner with one C(13)H3O tetrahedra,  a cornercorner with one C(16)H3O tetrahedra,  a cornercorner with one C(79)H3O tetrahedra,  an edgeedge with one Al(1)O6 octahedra, and  an edgeedge with one Al(9)O6 octahedra. The Al(2)-O(2) bond length is 1.91 Å. The Al(2)-O(38) bond length is 1.90 Å. The Al(2)-O(39) bond length is 2.05 Å. The Al(2)-O(4) bond length is 1.89 Å. The Al(2)-O(40) bond length is 2.02 Å. The Al(2)-O(5) bond length is 1.95 Å. In the third Al site, Al(3) is bonded to one O(10), one O(11), one O(13), one O(15), one O(16), and one O(9) atom to form AlO6 octahedra that share  a cornercorner with one C(29)H3O tetrahedra,  a cornercorner with one C(30)H3O tetrahedra,  a cornercorner with one C(31)H3O tetrahedra,  a cornercorner with one C(32)H3O tetrahedra,  an edgeedge with one Al(4)O6 octahedra, and  an edgeedge with one Al(8)O6 octahedra. The Al(3)-O(10) bond length is 1.95 Å. The Al(3)-O(11) bond length is 1.87 Å. The Al(3)-O(13) bond length is 1.89 Å. The Al(3)-O(15) bond length is 2.02 Å. The Al(3)-O(16) bond length is 1.96 Å. The Al(3)-O(9) bond length is 1.89 Å. In the fourth Al site, Al(4) is bonded to one O(10), one O(12), one O(13), one O(46), one O(47), and one O(48) atom to form AlO6 octahedra that share  a cornercorner with one C(29)H3O tetrahedra,  a cornercorner with one C(32)H3O tetrahedra,  a cornercorner with one C(94)H3O tetrahedra,  a cornercorner with one C(95)H4O tetrahedra,  an edgeedge with one Al(11)O6 octahedra, and  an edgeedge with one Al(3)O6 octahedra. The Al(4)-O(10) bond length is 1.91 Å. The Al(4)-O(12) bond length is 1.89 Å. The Al(4)-O(13) bond length is 1.95 Å. The Al(4)-O(46) bond length is 1.90 Å. The Al(4)-O(47) bond length is 2.05 Å. The Al(4)-O(48) bond length is 2.02 Å. In the fifth Al site, Al(5) is bonded to one O(17), one O(18), one O(19), one O(21), one O(23), and one O(24) atom to form AlO6 octahedra that share  a cornercorner with one C(45)H3O tetrahedra,  a cornercorner with one C(46)H3O tetrahedra,  a cornercorner with one C(47)H3O tetrahedra,  a cornercorner with one C(48)H3O tetrahedra,  an edgeedge with one Al(10)O6 octahedra, and  an edgeedge with one Al(6)O6 octahedra. The Al(5)-O(17) bond length is 1.89 Å. The Al(5)-O(18) bond length is 1.95 Å. The Al(5)-O(19) bond length is 1.87 Å. The Al(5)-O(21) bond length is 1.89 Å. The Al(5)-O(23) bond length is 2.02 Å. The Al(5)-O(24) bond length is 1.96 Å. In the sixth Al site, Al(6) is bonded to one O(18), one O(20), one O(21), one O(30), one O(31), and one O(32) atom to form AlO6 octahedra that share  a cornercorner with one C(45)H3O tetrahedra,  a cornercorner with one C(48)H3O tetrahedra,  a cornercorner with one C(63)H3O tetrahedra,  an edgeedge with one Al(5)O6 octahedra, and  an edgeedge with one Al(7)O6 octahedra. The Al(6)-O(18) bond length is 1.91 Å. The Al(6)-O(20) bond length is 1.89 Å. The Al(6)-O(21) bond length is 1.95 Å. The Al(6)-O(30) bond length is 1.90 Å. The Al(6)-O(31) bond length is 2.05 Å. The Al(6)-O(32) bond length is 2.02 Å. In the seventh Al site, Al(7) is bonded to one O(25), one O(26), one O(27), one O(29), one O(31), and one O(32) atom to form AlO6 octahedra that share  a cornercorner with one C(61)H3O tetrahedra,  a cornercorner with one C(63)H3O tetrahedra,  a cornercorner with one C(64)H3O tetrahedra,  an edgeedge with one Al(6)O6 octahedra, and  an edgeedge with one Al(8)O6 octahedra. The Al(7)-O(25) bond length is 1.89 Å. The Al(7)-O(26) bond length is 1.95 Å. The Al(7)-O(27) bond length is 1.87 Å. The Al(7)-O(29) bond length is 1.89 Å. The Al(7)-O(31) bond length is 2.02 Å. The Al(7)-O(32) bond length is 1.96 Å. In the eighth Al site, Al(8) is bonded to one O(14), one O(15), one O(16), one O(26), one O(28), and one O(29) atom to form AlO6 octahedra that share  a cornercorner with one C(30)H3O tetrahedra,  a cornercorner with one C(31)H3O tetrahedra,  a cornercorner with one C(61)H3O tetrahedra,  a cornercorner with one C(64)H3O tetrahedra,  an edgeedge with one Al(3)O6 octahedra, and  an edgeedge with one Al(7)O6 octahedra. The Al(8)-O(14) bond length is 1.90 Å. The Al(8)-O(15) bond length is 2.05 Å. The Al(8)-O(16) bond length is 2.02 Å. The Al(8)-O(26) bond length is 1.91 Å. The Al(8)-O(28) bond length is 1.89 Å. The Al(8)-O(29) bond length is 1.95 Å. In the ninth Al site, Al(9) is bonded to one O(33), one O(34), one O(35), one O(37), one O(39), and one O(40) atom to form AlO6 octahedra that share  a cornercorner with one C(77)H3O tetrahedra,  a cornercorner with one C(79)H3O tetrahedra,  a cornercorner with one C(80)H3O tetrahedra,  an edgeedge with one Al(10)O6 octahedra, and  an edgeedge with one Al(2)O6 octahedra. The Al(9)-O(33) bond length is 1.89 Å. The Al(9)-O(34) bond length is 1.95 Å. The Al(9)-O(35) bond length is 1.87 Å. The Al(9)-O(37) bond length is 1.89 Å. The Al(9)-O(39) bond length is 2.02 Å. The Al(9)-O(40) bond length is 1.96 Å. In the tenth Al site, Al(10) is bonded to one O(22), one O(23), one O(24), one O(34), one O(36), and one O(37) atom to form AlO6 octahedra that share  a cornercorner with one C(46)H3O tetrahedra,  a cornercorner with one C(47)H3O tetrahedra,  a cornercorner with one C(77)H3O tetrahedra,  a cornercorner with one C(80)H3O tetrahedra,  an edgeedge with one Al(5)O6 octahedra, and  an edgeedge with one Al(9)O6 octahedra. The Al(10)-O(22) bond length is 1.90 Å. The Al(10)-O(23) bond length is 2.05 Å. The Al(10)-O(24) bond length is 2.02 Å. The Al(10)-O(34) bond length is 1.91 Å. The Al(10)-O(36) bond length is 1.89 Å. The Al(10)-O(37) bond length is 1.95 Å. In the eleventh Al site, Al(11) is bonded to one O(41), one O(42), one O(43), one O(45), one O(47), and one O(48) atom to form AlO6 octahedra that share  a cornercorner with one C(93)H3O tetrahedra,  a cornercorner with one C(94)H3O tetrahedra,  a cornercorner with one C(96)H3O tetrahedra,  a cornercorner with one C(95)H4O tetrahedra,  an edgeedge with one Al(12)O6 octahedra, and  an edgeedge with one Al(4)O6 octahedra. The Al(11)-O(41) bond length is 1.89 Å. The Al(11)-O(42) bond length is 1.95 Å. The Al(11)-O(43) bond length is 1.87 Å. The Al(11)-O(45) bond length is 1.89 Å. The Al(11)-O(47) bond length is 2.02 Å. The Al(11)-O(48) bond length is 1.96 Å. In the twelfth Al site, Al(12) is bonded to one O(42), one O(44), one O(45), one O(6), one O(7), and one O(8) atom to form AlO6 octahedra that share  a cornercorner with one C(14)H3O tetrahedra,  a cornercorner with one C(15)H3O tetrahedra,  a cornercorner with one C(93)H3O tetrahedra,  a cornercorner with one C(96)H3O tetrahedra,  an edgeedge with one Al(1)O6 octahedra, and  an edgeedge with one Al(11)O6 octahedra. The Al(12)-O(42) bond length is 1.91 Å. The Al(12)-O(44) bond length is 1.89 Å. The Al(12)-O(45) bond length is 1.95 Å. The Al(12)-O(6) bond length is 1.90 Å. The Al(12)-O(7) bond length is 2.05 Å. The Al(12)-O(8) bond length is 2.02 Å. There are ninety-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(6) atom. The C(1)-C(2) bond length is 1.47 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(6) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(6) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(1) bond length is 1.14 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2) bond length is 1.14 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(53), and one C(54) atom. The C(5)-C(53) bond length is 1.32 Å. The C(5)-C(54) bond length is 1.53 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(2), one C(53), and one H(3) atom. The C(6)-C(53) bond length is 1.53 Å. The C(6)-H(3) bond length is 1.14 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(10), one C(55), and one C(59) atom. The C(7)-C(10) bond length is 1.30 Å. The C(7)-C(55) bond length is 1.52 Å. The C(7)-C(59) bond length is 1.39 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(9) atom. The C(8)-C(10) bond length is 1.43 Å. The C(8)-C(12) bond length is 1.52 Å. The C(8)-C(9) bond length is 1.34 Å. In the ninth C site, C(9) is bonded in a distorted water-like geometry to one C(8), one H(4), and one H(5) atom. The C(9)-H(4) bond length is 1.14 Å. The C(9)-H(5) bond length is 1.14 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(7), one C(8), and one H(6) atom. The C(10)-H(6) bond length is 1.14 Å. In the eleventh C site, C(11) is bonded in a distorted water-like geometry to one C(55), one H(7), and one H(8) atom. The C(11)-C(55) bond length is 1.39 Å. The C(11)-H(7) bond length is 1.14 Å. The C(11)-H(8) bond length is 1.14 Å. In the twelfth C site, C(12) is bonded in a bent 120 degrees geometry to one C(8), one O(3), and one O(4) atom. The C(12)-O(3) bond length is 1.28 Å. The C(12)-O(4) bond length is 1.22 Å. In the thirteenth C site, C(13) is bonded to one H(10), one H(87), one H(9), and one O(5) atom to form CH3O tetrahedra that share  a cornercorner with one Al(1)O6 octahedra and  a cornercorner with one Al(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 68-69°. The C(13)-H(10) bond length is 1.14 Å. The C(13)-H(87) bond length is 1.14 Å. The C(13)-H(9) bond length is 1.14 Å. The C(13)-O(5) bond length is 1.39 Å. In the fourteenth C site, C(14) is bonded to one H(11), one H(12), one H(88), and one O(8) atom to form CH3O tetrahedra that share  a cornercorner with one Al(1)O6 octahedra and  a cornercorner with one Al(12)O6 octahedra. The corner-sharing octahedral tilt angles range from 65-70°. The C(14)-H(11) bond length is 1.14 Å. The C(14)-H(12) bond length is 1.14 Å. The C(14)-H(88) bond length is 1.14 Å. The C(14)-O(8) bond length is 1.41 Å. In the fifteenth C site, C(15) is bonded to one H(13), one H(14), one H(89), and one O(7) atom to form CH3O tetrahedra that share  a cornercorner with one Al(1)O6 octahedra and  a cornercorner with one Al(12)O6 octahedra. The corner-sharing octahedral tilt angles range from 71-75°. The C(15)-H(13) bond length is 1.14 Å. The C(15)-H(14) bond length is 1.14 Å. The C(15)-H(89) bond length is 1.14 Å. The C(15)-O(7) bond length is 1.41 Å. In the sixteenth C site, C(16) is bonded to one H(15), one H(16), one H(90), and one O(2) atom to form CH3O tetrahedra that share  a cornercorner with one Al(1)O6 octahedra and  a cornercorner with one Al(2)O6 octahedra. The corner-sharing octahedral tilt angles range from 67-69°. The C(16)-H(15) bond length is 1.14 Å. The C(16)-H(16) bond length is 1.14 Å. The C(16)-H(90) bond length is 1.14 Å. The C(16)-O(2) bond length is 1.36 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(14), and one O(9) atom. The C(17)-C(18) bond length is 1.47 Å. The C(17)-O(14) bond length is 1.27 Å. The C(17)-O(9) bond length is 1.25 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(22) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-C(22) bond length is 1.40 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(17) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(17) bond length is 1.14 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one H(18) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(18) bond length is 1.14 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(69), and one C(70) atom. The C(21)-C(69) bond length is 1.32 Å. The C(21)-C(70) bond length is 1.53 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(18), one C(69), and one H(19) atom. The C(22)-C(69) bond length is 1.53 Å. The C(22)-H(19) bond length is 1.14 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(26), one C(71), and one C(75) atom. The C(23)-C(26) bond length is 1.30 Å. The C(23)-C(71) bond length is 1.52 Å. The C(23)-C(75) bond length is 1.39 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(25), one C(26), and one C(28) atom. The C(24)-C(25) bond length is 1.34 Å. The C(24)-C(26) bond length is 1.43 Å. The C(24)-C(28) bond length is 1.52 Å. In the twenty-fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(24), one C(27), and one H(20) atom. The C(25)-C(27) bond length is 1.49 Å. The C(25)-H(20) bond length is 1.14 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(23), one C(24), and one H(21) atom. The C(26)-H(21) bond length is 1.14 Å. In the twenty-seventh C site, C(27) is bonded in a distorted trigonal planar geometry to one C(25), one C(71), and one H(22) atom. The C(27)-C(71) bond length is 1.39 Å. The C(27)-H(22) bond length is 1.14 Å. In the twenty-eighth C site, C(28) is bonded in a bent 120 degrees geometry to one C(24), one O(11), and one O(12) atom. The C(28)-O(11) bond length is 1.28 Å. The C(28)-O(12) bond length is 1.22 Å. In the twenty-ninth C site, C(29) is bonded to one H(23), one H(24), one H(91), and one O(13) atom to form CH3O tetrahedra that share  a cornercorner with one Al(3)O6 octahedra and  a cornercorner with one Al(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 68-69°. The C(29)-H(23) bond length is 1.14 Å. The C(29)-H(24) bond length is 1.14 Å. The C(29)-H(91) bond length is 1.14 Å. The C(29)-O(13) bond length is 1.39 Å. In the thirtieth C site, C(30) is bonded to one H(25), one H(26), one H(92), and one O(16) atom to form CH3O tetrahedra that share  a cornercorner with one Al(3)O6 octahedra and  a cornercorner with one Al(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 65-70°. The C(30)-H(25) bond length is 1.14 Å. The C(30)-H(26) bond length is 1.14 Å. The C(30)-H(92) bond length is 1.14 Å. The C(30)-O(16) bond length is 1.41 Å. In the thirty-first C site, C(31) is bonded to one H(27), one H(28), one H(93), and one O(15) atom to form CH3O tetrahedra that share  a cornercorner with one Al(3)O6 octahedra and  a cornercorner with one Al(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 71-75°. The C(31)-H(27) bond length is 1.14 Å. The C(31)-H(28) bond length is 1.14 Å. The C(31)-H(93) bond length is 1.14 Å. The C(31)-O(15) bond length is 1.41 Å. In the thirty-second C site, C(32) is bonded to one H(29), one H(30), one H(94), and one O(10) atom to form CH3O tetrahedra that share  a cornercorner with one Al(3)O6 octahedra and  a cornercorner with one Al(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 67-69°. The C(32)-H(29) bond length is 1.14 Å. The C(32)-H(30) bond length is 1.14 Å. The C(32)-H(94) bond length is 1.14 Å. The C(32)-O(10) bond length is 1.36 Å. In the thirty-third C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(34), one O(17), and one O(22) atom. The C(33)-C(34) bond length is 1.47 Å. The C(33)-O(17) bond length is 1.25 Å. The C(33)-O(22) bond length is 1.27 Å. In the thirty-fourth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(38) atom. The C(34)-C(35) bond length is 1.41 Å. The C(34)-C(38) bond length is 1.40 Å. In the thirty-fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(34), one C(36), and one H(31) atom. The C(35)-C(36) bond length is 1.40 Å. The C(35)-H(31) bond length is 1.14 Å. In the thirty-sixth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(35), one C(37), and one H(32) atom. The C(36)-C(37) bond length is 1.39 Å. The C(36)-H(32) bond length is 1.14 Å. In the thirty-seventh C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(85), and one C(86) atom. The C(37)-C(85) bond length is 1.32 Å. The C(37)-C(86) bond length is 1.53 Å. In the thirty-eighth C site, C(38) is bonded in a distorted single-bond geometry to one C(34), one C(85), and one H(33) atom. The C(38)-C(85) bond length is 1.53 Å. The C(38)-H(33) bond length is 1.14 Å. In the thirty-ninth C site, C(39) is bonded in a trigonal planar geometry to one C(42), one C(87), and one C(91) atom. The C(39)-C(42) bond length is 1.30 Å. The C(39)-C(87) bond length is 1.52 Å. The C(39)-C(91) bond length is 1.39 Å. In the fortieth C site, C(40) is bonded in a trigonal planar geometry to one C(41), one C(42), and one C(44) atom. The C(40)-C(41) bond length is 1.34 Å. The C(40)-C(42) bond length is 1.43 Å. The C(40)-C(44) bond length is 1.52 Å. In the forty-first C site, C(41) is bonded in a distorted single-bond geometry to one C(40), one C(43), and one H(34) atom. The C(41)-C(43) bond length is 1.49 Å. The C(41)-H(34) bond length is 1.14 Å. In the forty-second C site, C(42) is bonded in a distorted single-bond geometry to one C(39), one C(40), and one H(35) atom. The C(42)-H(35) bond length is 1.14 Å. In the forty-third C site, C(43) is bonded in a distorted trigonal planar geometry to one C(41), one C(87), and one H(36) atom. The C(43)-C(87) bond length is 1.39 Å. The C(43)-H(36) bond length is 1.14 Å. In the forty-fourth C site, C(44) is bonded in a bent 120 degrees geometry to one C(40), one O(19), and one O(20) atom. The C(44)-O(19) bond length is 1.28 Å. The C(44)-O(20) bond length is 1.22 Å. In the forty-fifth C site, C(45) is bonded to one H(37), one H(38), one H(95), and one O(21) atom to form CH3O tetrahedra that share  a cornercorner with one Al(5)O6 octahedra and  a cornercorner with one Al(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 68-69°. The C(45)-H(37) bond length is 1.14 Å. The C(45)-H(38) bond length is 1.14 Å. The C(45)-H(95) bond length is 1.14 Å. The C(45)-O(21) bond length is 1.39 Å. In the forty-sixth C site, C(46) is bonded to one H(39), one H(40), one H(96), and one O(24) atom to form CH3O tetrahedra that share  a cornercorner with one Al(10)O6 octahedra and  a cornercorner with one Al(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 65-70°. The C(46)-H(39) bond length is 1.14 Å. The C(46)-H(40) bond length is 1.14 Å. The C(46)-H(96) bond length is 1.14 Å. The C(46)-O(24) bond length is 1.41 Å. In the forty-seventh C site, C(47) is bonded to one H(41), one H(42), one H(97), and one O(23) atom to form CH3O tetrahedra that share  a cornercorner with one Al(10)O6 octahedra and  a cornercorner with one Al(5)O6 octahedra. The corner-sharing octahedral tilt angles range from 71-75°. The C(47)-H(41) bond length is 1.14 Å. The C(47)-H(42) bond length is 1.14 Å. The C(47)-H(97) bond length is 1.14 Å. The C(47)-O(23) bond length is 1.41 Å. In the forty-eighth C site, C(48) is bonded to one H(43), one H(44), one H(98), and one O(18) atom to form CH3O tetrahedra that share  a cornercorner with one Al(5)O6 octahedra and  a cornercorner with one Al(6)O6 octahedra. The corner-sharing octahedral tilt angles range from 67-69°. The C(48)-H(43) bond length is 1.14 Å. The C(48)-H(44) bond length is 1.14 Å. The C(48)-H(98) bond length is 1.14 Å. The C(48)-O(18) bond length is 1.36 Å. In the forty-ninth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(50), one O(25), and one O(30) atom. The C(49)-C(50) bond length is 1.47 Å. The C(49)-O(25) bond length is 1.25 Å. The C(49)-O(30) bond length is 1.27 Å. In the fiftieth C site, C(50) is bonded in a trigonal planar geometry to one C(49), one C(51), and one C(54) atom. The C(50)-C(51) bond length is 1.41 Å. The C(50)-C(54) bond length is 1.40 Å. In the fifty-first C site, C(51) is bonded in a distorted single-bond geometry to one C(50), one C(52), and one H(45) atom. The C(51)-C(52) bond length is 1.40 Å. The C(51)-H(45) bond length is 1.14 Å. In the fifty-second C site, C(52) is bonded in a distorted trigonal planar geometry to one C(51), one C(53), and one H(46) atom. The C(52)-C(53) bond length is 1.39 Å. The C(52)-H(46) bond length is 1.14 Å. In the fifty-third C site, C(53) is bonded in a trigonal planar geometry to one C(5), one C(52), and one C(6) atom. In the fifty-fourth C site, C(54) is bonded in a distorted single-bond geometry to one C(5), one C(50), and one H(47) atom. The C(54)-H(47) bond length is 1.14 Å. In the fifty-fifth C site, C(55) is bonded in a trigonal planar geometry to one C(11), one C(58), and one C(7) atom. The C(55)-C(58) bond length is 1.30 Å. In the fifty-sixth C site, C(56) is bonded in a trigonal planar geometry to one C(57), one C(58), and one C(60) atom. The C(56)-C(57) bond length is 1.34 Å. The C(56)-C(58) bond length is 1.43 Å. The C(56)-C(60) bond length is 1.52 Å. In the fifty-seventh C site, C(57) is bonded in a distorted single-bond geometry to one C(56), one C(59), and one H(48) atom. The C(57)-C(59) bond length is 1.49 Å. The C(57)-H(48) bond length is 1.14 Å. In the fifty-eighth C site, C(58) is bonded in a distorted single-bond geometry to one C(55), one C(56), and one H(49) atom. The C(58)-H(49) bond length is 1.14 Å. In the fifty-ninth C site, C(59) is bonded in a distorted trigonal planar geometry to one C(57), one C(7), and one H(50) atom. The C(59)-H(50) bond length is 1.14 Å. In the sixtieth C site, C(60) is bonded in a bent 120 degrees geometry to one C(56), one O(27), and one O(28) atom. The C(60)-O(27) bond length is 1.28 Å. The C(60)-O(28) bond length is 1.22 Å. In the sixty-first C site, C(61) is bonded to one H(51), one H(52), one H(99), and one O(29) atom to form CH3O tetrahedra that share  a cornercorner with one Al(7)O6 octahedra and  a cornercorner with one Al(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 68-69°. The C(61)-H(51) bond length is 1.14 Å. The C(61)-H(52) bond length is 1.14 Å. The C(61)-H(99) bond length is 1.14 Å. The C(61)-O(29) bond length is 1.39 Å. In the sixty-second C site, C(62) is bonded in a trigonal planar geometry to one H(53), one H(54), and one O(32) atom. The C(62)-H(53) bond length is 1.14 Å. The C(62)-H(54) bond length is 1.14 Å. The C(62)-O(32) bond length is 1.41 Å. In the sixty-third C site, C(63) is bonded to one H(100), one H(55), one H(56), and one O(31) atom to form CH3O tetrahedra that share  a cornercorner with one Al(6)O6 octahedra and  a cornercorner with one Al(7)O6 octahedra. The corner-sharing octahedral tilt angles range from 71-75°. The C(63)-H(100) bond length is 1.14 Å. The C(63)-H(55) bond length is 1.14 Å. The C(63)-H(56) bond length is 1.14 Å. The C(63)-O(31) bond length is 1.41 Å. In the sixty-fourth C site, C(64) is bonded to one H(101), one H(57), one H(58), and one O(26) atom to form CH3O tetrahedra that share  a cornercorner with one Al(7)O6 octahedra and  a cornercorner with one Al(8)O6 octahedra. The corner-sharing octahedral tilt angles range from 67-69°. The C(64)-H(101) bond length is 1.14 Å. The C(64)-H(57) bond length is 1.14 Å. The C(64)-H(58) bond length is 1.14 Å. The C(64)-O(26) bond length is 1.36 Å. In the sixty-fifth C site, C(65) is bonded in a distorted bent 120 degrees geometry to one C(66), one O(33), and one O(38) atom. The C(65)-C(66) bond length is 1.47 Å. The C(65)-O(33) bond length is 1.25 Å. The C(65)-O(38) bond length is 1.27 Å. In the sixty-sixth C site, C(66) is bonded in a trigonal planar geometry to one C(65), one C(67), and one C(70) atom. The C(66)-C(67) bond length is 1.41 Å. The C(66)-C(70) bond length is 1.40 Å. In the sixty-seventh C site, C(67) is bonded in a distorted single-bond geometry to one C(66), one C(68), and one H(59) atom. The C(67)-C(68) bond length is 1.40 Å. The C(67)-H(59) bond length is 1.14 Å. In the sixty-eighth C site, C(68) is bonded in a distorted trigonal planar geometry to one C(67), one C(69), and one H(60) atom. The C(68)-C(69) bond length is 1.39 Å. The C(68)-H(60) bond length is 1.14 Å. In the sixty-ninth C site, C(69) is bonded in a trigonal planar geometry to one C(21), one C(22), and one C(68) atom. In the seventieth C site, C(70) is bonded in a distorted single-bond geometry to one C(21), one C(66), and one H(61) atom. The C(70)-H(61) bond length is 1.14 Å. In the seventy-first C site, C(71) is bonded in a trigonal planar geometry to one C(23), one C(27), and one C(74) atom. The C(71)-C(74) bond length is 1.30 Å. In the seventy-second C site, C(72) is bonded in a trigonal planar geometry to one C(73), one C(74), and one C(76) atom. The C(72)-C(73) bond length is 1.34 Å. The C(72)-C(74) bond length is 1.43 Å. The C(72)-C(76) bond length is 1.52 Å. In the seventy-third C site, C(73) is bonded in a distorted single-bond geometry to one C(72), one C(75), and one H(62) atom. The C(73)-C(75) bond length is 1.49 Å. The C(73)-H(62) bond length is 1.14 Å. In the seventy-fourth C site, C(74) is bonded in a distorted single-bond geometry to one C(71), one C(72), and one H(63) atom. The C(74)-H(63) bond length is 1.14 Å. In the seventy-fifth C site, C(75) is bonded in a distorted trigonal planar geometry to one C(23), one C(73), and one H(64) atom. The C(75)-H(64) bond length is 1.14 Å. In the seventy-sixth C site, C(76) is bonded in a bent 120 degrees geometry to one C(72), one O(35), and one O(36) atom. The C(76)-O(35) bond length is 1.28 Å. The C(76)-O(36) bond length is 1.22 Å. In the seventy-seventh C site, C(77) is bonded to one H(102), one H(65), one H(66), and one O(37) atom to form CH3O tetrahedra that share  a cornercorner with one Al(10)O6 octahedra and  a cornercorner with one Al(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 68-69°. The C(77)-H(102) bond length is 1.14 Å. The C(77)-H(65) bond length is 1.14 Å. The C(77)-H(66) bond length is 1.14 Å. The C(77)-O(37) bond length is 1.39 Å. In the seventy-eighth C site, C(78) is bonded in a trigonal planar geometry to two equivalent H(67,68) and one O(40) atom. Both C(78)-H(67,68) bond lengths are 1.14 Å. The C(78)-O(40) bond length is 1.41 Å. In the seventy-ninth C site, C(79) is bonded to one H(103), one H(69), one H(70), and one O(39) atom to form distorted CH3O tetrahedra that share  a cornercorner with one Al(2)O6 octahedra and  a cornercorner with one Al(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 71-75°. The C(79)-H(103) bond length is 1.14 Å. The C(79)-H(69) bond length is 1.14 Å. The C(79)-H(70) bond length is 1.14 Å. The C(79)-O(39) bond length is 1.41 Å. In the eightieth C site, C(80) is bonded to one H(104), one H(71), one H(72), and one O(34) atom to form CH3O tetrahedra that share  a cornercorner with one Al(10)O6 octahedra and  a cornercorner with one Al(9)O6 octahedra. The corner-sharing octahedral tilt angles range from 67-69°. The C(80)-H(104) bond length is 1.14 Å. The C(80)-H(71) bond length is 1.14 Å. The C(80)-H(72) bond length is 1.14 Å. The C(80)-O(34) bond length is 1.36 Å. In the eighty-first C site, C(81) is bonded in a distorted bent 120 degrees geometry to one C(82), one O(41), and one O(46) atom. The C(81)-C(82) bond length is 1.47 Å. The C(81)-O(41) bond length is 1.25 Å. The C(81)-O(46) bond length is 1.27 Å. In the eighty-second C site, C(82) is bonded in a trigonal planar geometry to one C(81), one C(83), and one C(86) atom. The C(82)-C(83) bond length is 1.41 Å. The C(82)-C(86) bond length is 1.40 Å. In the eighty-third C site, C(83) is bonded in a distorted single-bond geometry to one C(82), one C(84), and one H(73) atom. The C(83)-C(84) bond length is 1.40 Å. The C(83)-H(73) bond length is 1.14 Å. In the eighty-fourth C site, C(84) is bonded in a distorted trigonal planar geometry to one C(83), one C(85), and one H(74) atom. The C(84)-C(85) bond length is 1.39 Å. The C(84)-H(74) bond length is 1.14 Å. In the eighty-fifth C site, C(85) is bonded in a trigonal planar geometry to one C(37), one C(38), and one C(84) atom. In the eighty-sixth C site, C(86) is bonded in a distorted single-bond geometry to one C(37), one C(82), and one H(75) atom. The C(86)-H(75) bond length is 1.14 Å. In the eighty-seventh C site, C(87) is bonded in a trigonal planar geometry to one C(39), one C(43), and one C(90) atom. The C(87)-C(90) bond length is 1.30 Å. In the eighty-eighth C site, C(88) is bonded in a trigonal planar geometry to one C(89), one C(90), and one C(92) atom. The C(88)-C(89) bond length is 1.34 Å. The C(88)-C(90) bond length is 1.43 Å. The C(88)-C(92) bond length is 1.52 Å. In the eighty-ninth C site, C(89) is bonded in a distorted single-bond geometry to one C(88), one C(91), and one H(76) atom. The C(89)-C(91) bond length is 1.49 Å. The C(89)-H(76) bond length is 1.14 Å. In the ninetieth C site, C(90) is bonded in a distorted single-bond geometry to one C(87), one C(88), and one H(77) atom. The C(90)-H(77) bond length is 1.14 Å. In the ninety-first C site, C(91) is bonded in a distorted trigonal planar geometry to one C(39), one C(89), and one H(78) atom. The C(91)-H(78) bond length is 1.14 Å. In the ninety-second C site, C(92) is bonded in a bent 120 degrees geometry to one C(88), one O(43), and one O(44) atom. The C(92)-O(43) bond length is 1.28 Å. The C(92)-O(44) bond length is 1.22 Å. In the ninety-third C site, C(93) is bonded to one H(105), one H(79), one H(80), and one O(45) atom to form CH3O tetrahedra that share  a cornercorner with one Al(11)O6 octahedra,  a cornercorner with one Al(12)O6 octahedra, and  a cornercorner with one C(95)H4O tetrahedra. The corner-sharing octahedral tilt angles range from 68-69°. The C(93)-H(105) bond length is 1.14 Å. The C(93)-H(79) bond length is 1.14 Å. The C(93)-H(80) bond length is 1.14 Å. The C(93)-O(45) bond length is 1.39 Å. In the ninety-fourth C site, C(94) is bonded to one H(106), one H(81), one H(82), and one O(48) atom to form CH3O tetrahedra that share  a cornercorner with one Al(11)O6 octahedra and  a cornercorner with one Al(4)O6 octahedra. The corner-sharing octahedral tilt angles range from 65-70°. The C(94)-H(106) bond length is 1.14 Å. The C(94)-H(81) bond length is 1.14 Å. The C(94)-H(82) bond length is 1.14 Å. The C(94)-O(48) bond length is 1.41 Å. In the ninety-fifth C site, C(95) is bonded to one H(107), one H(80), one H(83), one H(84), and one O(47) atom to form distorted CH4O tetrahedra that share  a cornercorner with one Al(11)O6 octahedra,  a cornercorner with one Al(4)O6 octahedra, and  a cornercorner with one C(93)H3O tetrahedra. The corner-sharing octahedral tilt angles range from 71-75°. The C(95)-H(107) bond length is 1.14 Å. The C(95)-H(80) bond length is 1.43 Å. The C(95)-H(83) bond length is 1.14 Å. The C(95)-H(84) bond length is 1.14 Å. The C(95)-O(47) bond length is 1.41 Å. In the ninety-sixth C site, C(96) is bonded to one H(108), one H(85), one H(86), and one O(42) atom to form CH3O tetrahedra that share  a cornercorner with one Al(11)O6 octahedra and  a cornercorner with one Al(12)O6 octahedra. The corner-sharing octahedral tilt angles range from 67-69°. The C(96)-H(108) bond length is 1.14 Å. The C(96)-H(85) bond length is 1.14 Å. The C(96)-H(86) bond length is 1.14 Å. The C(96)-O(42) bond length is 1.36 Å. There are one hundred and seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(10) is bonded in a distorted bent 120 degrees geometry to one C(13) and one H(14) atom. The H(10)-H(14) bond length is 0.73 Å. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the fourteenth H site, H(14) is bonded in a distorted water-like geometry to one C(15) and one H(10) atom. In the fifteenth H site, H(15) is bonded in a distorted single-bond geometry to one C(16) and one H(103) atom. The H(15)-H(103) bond length is 1.15 Å. In the sixteenth H site, H(16) is bonded in a distorted linear geometry to one C(16) and one H(79) atom. The H(16)-H(79) bond length is 0.79 Å. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(20) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(22) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(27) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(29) atom. In the twenty-fourth H site, H(24) is bonded in a distorted bent 120 degrees geometry to one C(29) and one H(93) atom. The H(24)-H(93) bond length is 0.87 Å. In the twenty-fifth H site, H(25) is bonded in a single-bond geometry to one C(30) atom. In the twenty-sixth H site, H(26) is bonded in a single-bond geometry to one C(30) atom. In the twenty-seventh H site, H(27) is bonded in a single-bond geometry to one C(31) atom. In the twenty-eighth H site, H(28) is bonded in a single-bond geometry to one C(31) atom. In the twenty-ninth H site, H(29) is bonded in a single-bond geometry to one C(32) atom. In the thirtieth H site, H(30) is bonded in a single-bond geometry to one C(32) atom. In the thirty-first H site, H(31) is bonded in a single-bond geometry to one C(35) atom. In the thirty-second H site, H(32) is bonded in a single-bond geometry to one C(36) atom. In the thirty-third H site, H(33) is bonded in a single-bond geometry to one C(38) atom. In the thirty-fourth H site, H(34) is bonded in a single-bond geometry to one C(41) atom. In the thirty-fifth H site, H(35) is bonded in a single-bond geometry to one C(42) atom. In the thirty-sixth H site, H(36) is bonded in a single-bond geometry to one C(43) atom. In the thirty-seventh H site, H(37) is bonded in a distorted bent 150 degrees geometry to one C(45) and one H(58) atom. The H(37)-H(58) bond length is 0.82 Å. In the thirty-eighth H site, H(38) is bonded in a single-bond geometry to one C(45) atom. In the thirty-ninth H site, H(39) is bonded in a single-bond geometry to one C(46) atom. In the fortieth H site, H(40) is bonded in a single-bond geometry to one C(46) atom. In the forty-first H site, H(41) is bonded in a single-bond geometry to one C(47) atom. In the forty-second H site, H(42) is bonded in a single-bond geometry to one C(47) atom. In the forty-third H site, H(43) is bonded in a single-bond geometry to one C(48) atom. In the forty-fourth H site, H(44) is bonded in a single-bond geometry to one C(48) atom. In the forty-fifth H site, H(45) is bonded in a single-bond geometry to one C(51) atom. In the forty-sixth H site, H(46) is bonded in a single-bond geometry to one C(52) atom. In the forty-seventh H site, H(47) is bonded in a single-bond geometry to one C(54) atom. In the forty-eighth H site, H(48) is bonded in a single-bond geometry to one C(57) atom. In the forty-ninth H site, H(49) is bonded in a single-bond geometry to one C(58) atom. In the fiftieth H site, H(50) is bonded in a single-bond geometry to one C(59) atom. In the fifty-first H site, H(51) is bonded in a single-bond geometry to one C(61) atom. In the fifty-second H site, H(52) is bonded in a single-bond geometry to one C(61) atom. In the fifty-third H site, H(53) is bonded in a single-bond geometry to one C(62) atom. In the fifty-fourth H site, H(54) is bonded in a single-bond geometry to one C(62) atom. In the fifty-fifth H site, H(55) is bonded in a single-bond geometry to one C(63) atom. In the fifty-sixth H site, H(56) is bonded in a single-bond geometry to one C(63) atom. In the fifty-seventh H site, H(57) is bonded in a single-bond geometry to one C(64) atom. In the fifty-eighth H site, H(58) is bonded in a bent 120 degrees geometry to one C(64) and one H(37) atom. In the fifty-ninth H site, H(59) is bonded in a single-bond geometry to one C(67) atom. In the sixtieth H site, H(60) is bonded in a single-bond geometry to one C(68) atom. In the sixty-first H site, H(61) is bonded in a single-bond geometry to one C(70) atom. In the sixty-second H site, H(62) is bonded in a single-bond geometry to one C(73) atom. In the sixty-third H site, H(63) is bonded in a single-bond geometry to one C(74) atom. In the sixty-fourth H site, H(64) is bonded in a single-bond geometry to one C(75) atom. In the sixty-fifth H site, H(65) is bonded in a distorted single-bond geometry to one C(77) atom. In the sixty-sixth H site, H(66) is bonded in a single-bond geometry to one C(77) atom. In the sixty-seventh H site, H(67,68) is bonded in a single-bond geometry to one C(78) atom. In the sixty-eighth H site, H(69) is bonded in a single-bond geometry to one C(79) atom. In the sixty-ninth H site, H(70) is bonded in a single-bond geometry to one C(79) atom. In the seventieth H site, H(71) is bonded in a distorted single-bond geometry to one C(80) and one H(97) atom. The H(71)-H(97) bond length is 0.92 Å. In the seventy-first H site, H(72) is bonded in a single-bond geometry to one C(80) atom. In the seventy-second H site, H(73) is bonded in a single-bond geometry to one C(83) atom. In the seventy-third H site, H(74) is bonded in a single-bond geometry to one C(84) atom. In the seventy-fourth H site, H(75) is bonded in a single-bond geometry to one C(86) atom. In the seventy-fifth H site, H(76) is bonded in a single-bond geometry to one C(89) atom. In the seventy-sixth H site, H(77) is bonded in a single-bond geometry to one C(90) atom. In the seventy-seventh H site, H(78) is bonded in a single-bond geometry to one C(91) atom. In the seventy-eighth H site, H(79) is bonded in a distorted bent 120 degrees geometry to one C(93) and one H(16) atom. In the seventy-ninth H site, H(80) is bonded in a 3-coordinate geometry to one C(93), one C(95), and one H(107) atom. The H(80)-H(107) bond length is 0.98 Å. In the eightieth H site, H(81) is bonded in a single-bond geometry to one C(94) atom. In the eighty-first H site, H(82) is bonded in a single-bond geometry to one C(94) atom. In the eighty-second H site, H(83) is bonded in a single-bond geometry to one C(95) atom. In the eighty-third H site, H(84) is bonded in a single-bond geometry to one C(95) atom. In the eighty-fourth H site, H(85) is bonded in a single-bond geometry to one C(96) atom. In the eighty-fifth H site, H(86) is bonded in a single-bond geometry to one C(96) atom. In the eighty-sixth H site, H(87) is bonded in a single-bond geometry to one C(13) and one O(39) atom. The H(87)-O(39) bond length is 1.75 Å. In the eighty-seventh H site, H(88) is bonded in a single-bond geometry to one C(14) atom. In the eighty-eighth H site, H(89) is bonded in a single-bond geometry to one C(15) atom. In the eighty-ninth H site, H(90) is bonded in a single-bond geometry to one C(16) atom. In the ninetieth H site, H(91) is bonded in a single-bond geometry to one C(29) atom. In the ninety-first H site, H(92) is bonded in a single-bond geometry to one C(30) atom. In the ninety-second H site, H(93) is bonded in a distorted water-like geometry to one C(31) and one H(24) atom. In the ninety-third H site, H(94) is bonded in a single-bond geometry to one C(32) atom. In the ninety-fourth H site, H(95) is bonded in a single-bond geometry to one C(45) atom. In the ninety-fifth H site, H(96) is bonded in a single-bond geometry to one C(46) atom. In the ninety-sixth H site, H(97) is bonded in a distorted bent 120 degrees geometry to one C(47) and one H(71) atom. In the ninety-seventh H site, H(98) is bonded in a single-bond geometry to one C(48) atom. In the ninety-eighth H site, H(99) is bonded in a single-bond geometry to one C(61) atom. In the ninety-ninth H site, H(100) is bonded in a single-bond geometry to one C(63) atom. In the one hundredth H site, H(101) is bonded in a single-bond geometry to one C(64) atom. In the one hundred and first H site, H(102) is bonded in a single-bond geometry to one C(77) atom. In the one hundred and second H site, H(103) is bonded in a distorted L-shaped geometry to one C(79) and one H(15) atom. In the one hundred and third H site, H(104) is bonded in a single-bond geometry to one C(80) atom. In the one hundred and fourth H site, H(105) is bonded in a single-bond geometry to one C(93) atom. In the one hundred and fifth H site, H(106) is bonded in a single-bond geometry to one C(94) atom. In the one hundred and sixth H site, H(107) is bonded in a distorted L-shaped geometry to one C(95) and one H(80) atom. In the one hundred and seventh H site, H(108) is bonded in a single-bond geometry to one C(96) atom. There are forty-eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Al(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Al(1), one Al(2), and one C(16) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Al(1) and one C(12) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Al(2) and one C(12) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Al(1), one Al(2), and one C(13) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Al(12) and one C(1) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Al(1), one Al(12), and one C(15) atom. In the eighth O site, O(8) is bonded in a trigonal non-coplanar geometry to one Al(1), one Al(12), and one C(14) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Al(3) and one C(17) atom. In the tenth O site, O(10) is bonded in a trigonal non-coplanar geometry to one Al(3), one Al(4), and one C(32) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Al(3) and one C(28) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Al(4) and one C(28) atom. In the thirteenth O site, O(13) is bonded in a trigonal non-coplanar geometry to one Al(3), one Al(4), and one C(29) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Al(8) and one C(17) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal non-coplanar geometry to one Al(3), one Al(8), and one C(31) atom. In the sixteenth O site, O(16) is bonded in a trigonal non-coplanar geometry to one Al(3), one Al(8), and one C(30) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Al(5) and one C(33) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal non-coplanar geometry to one Al(5), one Al(6), and one C(48) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Al(5) and one C(44) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Al(6) and one C(44) atom. In the twenty-first O site, O(21) is bonded in a trigonal non-coplanar geometry to one Al(5), one Al(6), and one C(45) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Al(10) and one C(33) atom. In the twenty-third O site, O(23) is bonded in a distorted trigonal non-coplanar geometry to one Al(10), one Al(5), and one C(47) atom. In the twenty-fourth O site, O(24) is bonded in a trigonal non-coplanar geometry to one Al(10), one Al(5), and one C(46) atom. In the twenty-fifth O site, O(25) is bonded in a bent 120 degrees geometry to one Al(7) and one C(49) atom. In the twenty-sixth O site, O(26) is bonded in a trigonal non-coplanar geometry to one Al(7), one Al(8), and one C(64) atom. In the twenty-seventh O site, O(27) is bonded in a bent 120 degrees geometry to one Al(7) and one C(60) atom. In the twenty-eighth O site, O(28) is bonded in a bent 120 degrees geometry to one Al(8) and one C(60) atom. In the twenty-ninth O site, O(29) is bonded in a trigonal non-coplanar geometry to one Al(7), one Al(8), and one C(61) atom. In the thirtieth O site, O(30) is bonded in a bent 120 degrees geometry to one Al(6) and one C(49) atom. In the thirty-first O site, O(31) is bonded in a distorted trigonal non-coplanar geometry to one Al(6), one Al(7), and one C(63) atom. In the thirty-second O site, O(32) is bonded in a trigonal non-coplanar geometry to one Al(6), one Al(7), and one C(62) atom. In the thirty-third O site, O(33) is bonded in a bent 120 degrees geometry to one Al(9) and one C(65) atom. In the thirty-fourth O site, O(34) is bonded in a trigonal non-coplanar geometry to one Al(10), one Al(9), and one C(80) atom. In the thirty-fifth O site, O(35) is bonded in a bent 120 degrees geometry to one Al(9) and one C(76) atom. In the thirty-sixth O site, O(36) is bonded in a bent 120 degrees geometry to one Al(10) and one C(76) atom. In the thirty-seventh O site, O(37) is bonded in a trigonal non-coplanar geometry to one Al(10), one Al(9), and one C(77) atom. In the thirty-eighth O site, O(38) is bonded in a bent 120 degrees geometry to one Al(2) and one C(65) atom. In the thirty-ninth O site, O(39) is bonded in a 4-coordinate geometry to one Al(2), one Al(9), one C(79), and one H(87) atom. In the fortieth O site, O(40) is bonded in a trigonal non-coplanar geometry to one Al(2), one Al(9), and one C(78) atom. In the forty-first O site, O(41) is bonded in a bent 120 degrees geometry to one Al(11) and one C(81) atom. In the forty-second O site, O(42) is bonded in a trigonal non-coplanar geometry to one Al(11), one Al(12), and one C(96) atom. In the forty-third O site, O(43) is bonded in a bent 120 degrees geometry to one Al(11) and one C(92) atom. In the forty-fourth O site, O(44) is bonded in a bent 120 degrees geometry to one Al(12) and one C(92) atom. In the forty-fifth O site, O(45) is bonded in a trigonal non-coplanar geometry to one Al(11), one Al(12), and one C(93) atom. In the forty-sixth O site, O(46) is bonded in a bent 120 degrees geometry to one Al(4) and one C(81) atom. In the forty-seventh O site, O(47) is bonded in a distorted trigonal non-coplanar geometry to one Al(11), one Al(4), and one C(95) atom. In the forty-eighth O site, O(48) is bonded in a trigonal non-coplanar geometry to one Al(11), one Al(4), and one C(94) atom. Linkers: 1 [O]C(=O)C1=Cc2ccc(C([O])=O)cc2CC1 ,5 [O]C(=O)c1ccc2cc(C([O])=O)ccc2c1. Metal clusters: 12 [Al]. The MOF has largest included sphere 13.21 A, density 0.62 g/cm3, surface area 4020.94 m2/g, accessible volume 1.23 cm3/g