(CH)2Cd3C38H24S6(N4O)4 crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a Cd3C38H24S6(N4O)4 framework. In the Cd3C38H24S6(N4O)4 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted octahedral geometry to one N(1), one N(2), one N(3), one N(7), one S(1), and one S(2) atom. The Cd(1)-N(1) bond length is 2.30 Å. The Cd(1)-N(2) bond length is 2.36 Å. The Cd(1)-N(3) bond length is 2.32 Å. The Cd(1)-N(7) bond length is 2.27 Å. The Cd(1)-S(1) bond length is 2.85 Å. The Cd(1)-S(2) bond length is 2.66 Å. In the second Cd site, Cd(2) is bonded in an octahedral geometry to two equivalent N(6), two equivalent N(8), and two equivalent S(3) atoms. Both Cd(2)-N(6) bond lengths are 2.36 Å. Both Cd(2)-N(8) bond lengths are 2.27 Å. Both Cd(2)-S(3) bond lengths are 2.73 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(2) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(2) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted linear geometry to one N(3) and one S(1) atom. The C(2)-N(3) bond length is 1.14 Å. The C(2)-S(1) bond length is 1.64 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(15), and one C(5) atom. The C(3)-C(15) bond length is 1.37 Å. The C(3)-C(5) bond length is 1.50 Å. In the fourth C site, C(4) is bonded in a distorted linear geometry to one N(7) and one S(3) atom. The C(4)-N(7) bond length is 1.15 Å. The C(4)-S(3) bond length is 1.64 Å. In the fifth C site, C(5) is bonded in a 3-coordinate geometry to one C(3), one N(5), and one O(2) atom. The C(5)-N(5) bond length is 1.35 Å. The C(5)-O(2) bond length is 1.19 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(14), one C(17), and one N(4) atom. The C(6)-C(14) bond length is 1.39 Å. The C(6)-C(17) bond length is 1.38 Å. The C(6)-N(4) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a distorted linear geometry to one N(8) and one S(2) atom. The C(7)-N(8) bond length is 1.16 Å. The C(7)-S(2) bond length is 1.64 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(2), and one H(4) atom. The C(8)-C(13) bond length is 1.37 Å. The C(8)-N(2) bond length is 1.33 Å. The C(8)-H(4) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(16), one N(1), and one H(5) atom. The C(9)-C(16) bond length is 1.36 Å. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(5) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(13), one N(4), and one O(1) atom. The C(10)-C(13) bond length is 1.49 Å. The C(10)-N(4) bond length is 1.35 Å. The C(10)-O(1) bond length is 1.22 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(18), and one N(5) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-C(18) bond length is 1.39 Å. The C(11)-N(5) bond length is 1.37 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(1), and one H(6) atom. The C(12)-N(1) bond length is 1.34 Å. The C(12)-H(6) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(10), one C(15), and one C(8) atom. The C(13)-C(15) bond length is 1.37 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(6), and one H(7) atom. The C(14)-N(6) bond length is 1.33 Å. The C(14)-H(7) bond length is 0.93 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(13), one C(3), and one H(8) atom. The C(15)-H(8) bond length is 0.93 Å. In the sixteenth C site, C(16) is bonded in a single-bond geometry to one C(9) and one H(9) atom. The C(16)-H(9) bond length is 0.93 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(6) and one H(10) atom. The C(17)-H(10) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(11) and one H(11) atom. The C(18)-H(11) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(12) atom. The C(19)-N(6) bond length is 1.32 Å. The C(19)-H(12) bond length is 0.93 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(12), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(8) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(10), one C(6), and one H(1) atom. The N(4)-H(1) bond length is 0.86 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(11), one C(5), and one H(3) atom. The N(5)-H(3) bond length is 0.86 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cd(2), one C(14), and one C(19) atom. In the seventh N site, N(7) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(4) atom. In the eighth N site, N(8) is bonded in a bent 150 degrees geometry to one Cd(2) and one C(7) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one Cd(1) and one C(2) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one Cd(1) and one C(7) atom. In the third S site, S(3) is bonded in a water-like geometry to one Cd(2) and one C(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(10) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(5) atom. Linkers: 2 O=C(Nc1cccnc1)c1cncc(C(=O)Nc2cccnc2)c1. Metal clusters: 3 [Cd]. The MOF has largest included sphere 5.89 A, density 1.26 g/cm3, surface area 4131.50 m2/g, accessible volume 0.37 cm3/g