Au4Ag6Cu4C40N8S8O16Cl crystallizes in the cubic P2_13 space group. There are four inequivalent Au sites. In the first Au site, Au(1) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), one S(1), and one S(2) atom. The Au(1)-Ag(1) bond length is 2.98 Å. The Au(1)-Ag(2) bond length is 2.88 Å. The Au(1)-Ag(3) bond length is 3.25 Å. The Au(1)-S(1) bond length is 2.31 Å. The Au(1)-S(2) bond length is 2.29 Å. In the second Au site, Au(2) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), one S(3), and one S(4) atom. The Au(2)-Ag(1) bond length is 2.99 Å. The Au(2)-Ag(2) bond length is 3.23 Å. The Au(2)-Ag(3) bond length is 2.90 Å. The Au(2)-S(3) bond length is 2.31 Å. The Au(2)-S(4) bond length is 2.30 Å. In the third Au site, Au(3) is bonded in a 5-coordinate geometry to one Ag(4), one Ag(5), one Ag(6), one S(5), and one S(6) atom. The Au(3)-Ag(4) bond length is 2.98 Å. The Au(3)-Ag(5) bond length is 2.93 Å. The Au(3)-Ag(6) bond length is 3.15 Å. The Au(3)-S(5) bond length is 2.30 Å. The Au(3)-S(6) bond length is 2.29 Å. In the fourth Au site, Au(4) is bonded in a 5-coordinate geometry to one Ag(4), one Ag(5), one Ag(6), one S(7), and one S(8) atom. The Au(4)-Ag(4) bond length is 3.00 Å. The Au(4)-Ag(5) bond length is 3.19 Å. The Au(4)-Ag(6) bond length is 2.92 Å. The Au(4)-S(7) bond length is 2.31 Å. The Au(4)-S(8) bond length is 2.29 Å. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one Au(1), one Au(2), one S(1), one S(3), and one Cl(1) atom. The Ag(1)-S(1) bond length is 2.56 Å. The Ag(1)-S(3) bond length is 2.55 Å. The Ag(1)-Cl(1) bond length is 2.41 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one Au(1), one Au(2), one S(1), and two equivalent S(4) atoms. The Ag(2)-S(1) bond length is 2.53 Å. There is one shorter (2.43 Å) and one longer (2.88 Å) Ag(2)-S(4) bond length. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to one Au(1), one Au(2), one S(3), and two equivalent S(2) atoms. The Ag(3)-S(3) bond length is 2.54 Å. There is one shorter (2.44 Å) and one longer (2.94 Å) Ag(3)-S(2) bond length. In the fourth Ag site, Ag(4) is bonded in a distorted bent 120 degrees geometry to one Au(3), one Au(4), one S(5), and one S(7) atom. The Ag(4)-S(5) bond length is 2.55 Å. The Ag(4)-S(7) bond length is 2.52 Å. In the fifth Ag site, Ag(5) is bonded in a 5-coordinate geometry to one Au(3), one Au(4), one S(5), and two equivalent S(8) atoms. The Ag(5)-S(5) bond length is 2.52 Å. There is one shorter (2.46 Å) and one longer (2.93 Å) Ag(5)-S(8) bond length. In the sixth Ag site, Ag(6) is bonded in a 5-coordinate geometry to one Au(3), one Au(4), one S(7), and two equivalent S(6) atoms. The Ag(6)-S(7) bond length is 2.46 Å. There is one shorter (2.45 Å) and one longer (3.03 Å) Ag(6)-S(6) bond length. There are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(2), one S(1), one O(1), and one O(3) atom. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-N(2) bond length is 1.99 Å. The Cu(1)-S(1) bond length is 3.00 Å. The Cu(1)-O(1) bond length is 1.84 Å. The Cu(1)-O(3) bond length is 1.94 Å. In the second Cu site, Cu(2) is bonded in a distorted rectangular see-saw-like geometry to one N(3), one N(4), one S(3), one O(5), and one O(7) atom. The Cu(2)-N(3) bond length is 1.96 Å. The Cu(2)-N(4) bond length is 2.02 Å. The Cu(2)-S(3) bond length is 2.98 Å. The Cu(2)-O(5) bond length is 1.87 Å. The Cu(2)-O(7) bond length is 1.95 Å. In the third Cu site, Cu(3) is bonded in a distorted rectangular see-saw-like geometry to one N(5), one N(6), one S(5), one O(11), and one O(9) atom. The Cu(3)-N(5) bond length is 1.98 Å. The Cu(3)-N(6) bond length is 1.94 Å. The Cu(3)-S(5) bond length is 3.02 Å. The Cu(3)-O(11) bond length is 1.91 Å. The Cu(3)-O(9) bond length is 1.97 Å. In the fourth Cu site, Cu(4) is bonded to one N(7), one N(8), one S(7), one O(13), one O(15), and one O(6) atom to form distorted CuSN2O3 trigonal bipyramids that share  a cornercorner with one C(38)C3S tetrahedra. The Cu(4)-N(7) bond length is 1.93 Å. The Cu(4)-N(8) bond length is 2.02 Å. The Cu(4)-S(7) bond length is 3.02 Å. The Cu(4)-O(13) bond length is 1.94 Å. The Cu(4)-O(15) bond length is 1.96 Å. The Cu(4)-O(6) bond length is 2.38 Å. There are forty inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.56 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.30 Å. In the second C site, C(2) is bonded in a trigonal non-coplanar geometry to one C(1), one C(3), and one N(1) atom. The C(2)-C(3) bond length is 1.52 Å. The C(2)-N(1) bond length is 1.49 Å. In the third C site, C(3) is bonded in a tetrahedral geometry to one C(2), one C(4), one C(5), and one S(1) atom. The C(3)-C(4) bond length is 1.55 Å. The C(3)-C(5) bond length is 1.57 Å. The C(3)-S(1) bond length is 1.88 Å. In the fourth C site, C(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth C site, C(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(4) atom. The C(6)-C(7) bond length is 1.57 Å. The C(6)-O(3) bond length is 1.27 Å. The C(6)-O(4) bond length is 1.27 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one C(8), and one N(2) atom. The C(7)-C(8) bond length is 1.53 Å. The C(7)-N(2) bond length is 1.50 Å. In the eighth C site, C(8) is bonded in a tetrahedral geometry to one C(10), one C(7), one C(9), and one S(4) atom. The C(8)-C(10) bond length is 1.55 Å. The C(8)-C(9) bond length is 1.53 Å. The C(8)-S(4) bond length is 1.83 Å. In the ninth C site, C(9) is bonded in a single-bond geometry to one C(8) atom. In the tenth C site, C(10) is bonded in a single-bond geometry to one C(8) atom. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(5), and one O(6) atom. The C(11)-C(12) bond length is 1.57 Å. The C(11)-O(5) bond length is 1.28 Å. The C(11)-O(6) bond length is 1.30 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one C(13), and one N(3) atom. The C(12)-C(13) bond length is 1.52 Å. The C(12)-N(3) bond length is 1.52 Å. In the thirteenth C site, C(13) is bonded in a tetrahedral geometry to one C(12), one C(14), one C(15), and one S(2) atom. The C(13)-C(14) bond length is 1.57 Å. The C(13)-C(15) bond length is 1.56 Å. The C(13)-S(2) bond length is 1.85 Å. In the fourteenth C site, C(14) is bonded in a single-bond geometry to one C(13) atom. In the fifteenth C site, C(15) is bonded in a single-bond geometry to one C(13) atom. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(17), one O(7), and one O(8) atom. The C(16)-C(17) bond length is 1.57 Å. The C(16)-O(7) bond length is 1.27 Å. The C(16)-O(8) bond length is 1.29 Å. In the seventeenth C site, C(17) is bonded in a bent 120 degrees geometry to one C(16), one C(18), and one N(4) atom. The C(17)-C(18) bond length is 1.53 Å. The C(17)-N(4) bond length is 1.50 Å. In the eighteenth C site, C(18) is bonded in a tetrahedral geometry to one C(17), one C(19), one C(20), and one S(3) atom. The C(18)-C(19) bond length is 1.55 Å. The C(18)-C(20) bond length is 1.54 Å. The C(18)-S(3) bond length is 1.87 Å. In the nineteenth C site, C(19) is bonded in a single-bond geometry to one C(18) atom. In the twentieth C site, C(20) is bonded in a single-bond geometry to one C(18) atom. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(10), and one O(9) atom. The C(21)-C(22) bond length is 1.56 Å. The C(21)-O(10) bond length is 1.27 Å. The C(21)-O(9) bond length is 1.27 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal non-coplanar geometry to one C(21), one C(23), and one N(5) atom. The C(22)-C(23) bond length is 1.52 Å. The C(22)-N(5) bond length is 1.51 Å. In the twenty-third C site, C(23) is bonded in a tetrahedral geometry to one C(22), one C(24), one C(25), and one S(5) atom. The C(23)-C(24) bond length is 1.54 Å. The C(23)-C(25) bond length is 1.55 Å. The C(23)-S(5) bond length is 1.83 Å. In the twenty-fourth C site, C(24) is bonded in a single-bond geometry to one C(23) atom. In the twenty-fifth C site, C(25) is bonded in a single-bond geometry to one C(23) atom. In the twenty-sixth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(11), and one O(12) atom. The C(26)-C(27) bond length is 1.58 Å. The C(26)-O(11) bond length is 1.26 Å. The C(26)-O(12) bond length is 1.26 Å. In the twenty-seventh C site, C(27) is bonded in a distorted trigonal non-coplanar geometry to one C(26), one C(28), and one N(6) atom. The C(27)-C(28) bond length is 1.53 Å. The C(27)-N(6) bond length is 1.52 Å. In the twenty-eighth C site, C(28) is bonded in a tetrahedral geometry to one C(27), one C(29), one C(30), and one S(8) atom. The C(28)-C(29) bond length is 1.53 Å. The C(28)-C(30) bond length is 1.56 Å. The C(28)-S(8) bond length is 1.90 Å. In the twenty-ninth C site, C(29) is bonded in a single-bond geometry to one C(28) atom. In the thirtieth C site, C(30) is bonded in a single-bond geometry to one C(28) atom. In the thirty-first C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(13), and one O(14) atom. The C(31)-C(32) bond length is 1.55 Å. The C(31)-O(13) bond length is 1.25 Å. The C(31)-O(14) bond length is 1.28 Å. In the thirty-second C site, C(32) is bonded in a distorted trigonal non-coplanar geometry to one C(31), one C(33), and one N(7) atom. The C(32)-C(33) bond length is 1.54 Å. The C(32)-N(7) bond length is 1.51 Å. In the thirty-third C site, C(33) is bonded in a tetrahedral geometry to one C(32), one C(34), one C(35), and one S(6) atom. The C(33)-C(34) bond length is 1.58 Å. The C(33)-C(35) bond length is 1.56 Å. The C(33)-S(6) bond length is 1.87 Å. In the thirty-fourth C site, C(34) is bonded in a single-bond geometry to one C(33) atom. In the thirty-fifth C site, C(35) is bonded in a single-bond geometry to one C(33) atom. In the thirty-sixth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(15), and one O(16) atom. The C(36)-C(37) bond length is 1.56 Å. The C(36)-O(15) bond length is 1.27 Å. The C(36)-O(16) bond length is 1.26 Å. In the thirty-seventh C site, C(37) is bonded in a distorted trigonal non-coplanar geometry to one C(36), one C(38), and one N(8) atom. The C(37)-C(38) bond length is 1.52 Å. The C(37)-N(8) bond length is 1.52 Å. In the thirty-eighth C site, C(38) is bonded to one C(37), one C(39), one C(40), and one S(7) atom to form CC3S tetrahedra that share  a cornercorner with one Cu(4)SN2O3 trigonal bipyramid. The C(38)-C(39) bond length is 1.54 Å. The C(38)-C(40) bond length is 1.56 Å. The C(38)-S(7) bond length is 1.83 Å. In the thirty-ninth C site, C(39) is bonded in a single-bond geometry to one C(38) atom. In the fortieth C site, C(40) is bonded in a single-bond geometry to one C(38) atom. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one Cu(1) and one C(2) atom. In the second N site, N(2) is bonded in a water-like geometry to one Cu(1) and one C(7) atom. In the third N site, N(3) is bonded in a water-like geometry to one Cu(2) and one C(12) atom. In the fourth N site, N(4) is bonded in a distorted water-like geometry to one Cu(2) and one C(17) atom. In the fifth N site, N(5) is bonded in a water-like geometry to one Cu(3) and one C(22) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(27) atom. In the seventh N site, N(7) is bonded in a water-like geometry to one Cu(4) and one C(32) atom. In the eighth N site, N(8) is bonded in a water-like geometry to one Cu(4) and one C(37) atom. There are eight inequivalent S sites. In the first S site, S(1) is bonded in a 5-coordinate geometry to one Au(1), one Ag(1), one Ag(2), one Cu(1), and one C(3) atom. In the second S site, S(2) is bonded in a distorted rectangular see-saw-like geometry to one Au(1), two equivalent Ag(3), and one C(13) atom. In the third S site, S(3) is bonded in a 5-coordinate geometry to one Au(2), one Ag(1), one Ag(3), one Cu(2), and one C(18) atom. In the fourth S site, S(4) is bonded to one Au(2), two equivalent Ag(2), and one C(8) atom to form distorted corner-sharing SAg2AuC trigonal pyramids. In the fifth S site, S(5) is bonded in a 5-coordinate geometry to one Au(3), one Ag(4), one Ag(5), one Cu(3), and one C(23) atom. In the sixth S site, S(6) is bonded to one Au(3), two equivalent Ag(6), and one C(33) atom to form distorted corner-sharing SAg2AuC trigonal pyramids. In the seventh S site, S(7) is bonded in a 5-coordinate geometry to one Au(4), one Ag(4), one Ag(6), one Cu(4), and one C(38) atom. In the eighth S site, S(8) is bonded to one Au(4), two equivalent Ag(5), and one C(28) atom to form distorted corner-sharing SAg2AuC trigonal pyramids. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(6) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(11) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one C(11) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Cu(2) and one C(16) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(21) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(21) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(26) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one C(26) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(31) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one C(31) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(36) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one C(36) atom. Cl(1) is bonded in a single-bond geometry to one Ag(1) atom. Linkers: 96 [C]C([C])([S])[C]([N])C([O])=O. Metal clusters: 48 [Cu] ,72 [Ag] ,48 [Au]. The MOF has largest included sphere 10.80 A, density 1.61 g/cm3, surface area 2481.16 m2/g, accessible volume 0.42 cm3/g