(CdH4(C5O4)2)2CdH4(C3O2)3CdH2(CO)6(CH3)7(C5H4NO)7 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of fourteen 02329_fluka molecules, fourteen n-methylmethacrylamide molecules, two CdH2(CO)6 clusters, two CdH4(C3O2)3 clusters, and four CdH4(C5O4)2 clusters. In each CdH2(CO)6 cluster, Cd(3) is bonded in a distorted octahedral geometry to one O(24), one O(25), one O(34), one O(35), one O(6), and one O(7) atom. The Cd(3)-O(24) bond length is 2.58 Å. The Cd(3)-O(25) bond length is 2.30 Å. The Cd(3)-O(34) bond length is 2.25 Å. The Cd(3)-O(35) bond length is 2.72 Å. The Cd(3)-O(6) bond length is 2.61 Å. The Cd(3)-O(7) bond length is 2.30 Å. There are six inequivalent C sites. In the first C site, C(12) is bonded in a bent 120 degrees geometry to one C(13), one O(6), and one O(7) atom. The C(12)-C(13) bond length is 1.50 Å. The C(12)-O(6) bond length is 1.26 Å. The C(12)-O(7) bond length is 1.26 Å. In the second C site, C(77) is bonded in a distorted bent 120 degrees geometry to one O(34) and one O(35) atom. The C(77)-O(34) bond length is 1.27 Å. The C(77)-O(35) bond length is 1.24 Å. In the third C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(18) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(18) bond length is 1.39 Å. In the fourth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(14)-H(11) bond length is 0.95 Å. In the fifth C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(14,40) atom. The C(18)-H(14,40) bond length is 0.95 Å. In the sixth C site, C(55) is bonded in a distorted bent 120 degrees geometry to one O(24) and one O(25) atom. The C(55)-O(24) bond length is 1.24 Å. The C(55)-O(25) bond length is 1.27 Å. There are two inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the second H site, H(14,40) is bonded in a single-bond geometry to one C(18) atom. There are six inequivalent O sites. In the first O site, O(24) is bonded in a distorted single-bond geometry to one Cd(3) and one C(55) atom. In the second O site, O(25) is bonded in a distorted single-bond geometry to one Cd(3) and one C(55) atom. In the third O site, O(34) is bonded in a distorted water-like geometry to one Cd(3) and one C(77) atom. In the fourth O site, O(35) is bonded in a single-bond geometry to one Cd(3) and one C(77) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one Cd(3) and one C(12) atom. In the sixth O site, O(7) is bonded in a water-like geometry to one Cd(3) and one C(12) atom. In each CdH4(C3O2)3 cluster, Cd(2) is bonded in a 6-coordinate geometry to one O(16), one O(17), one O(21), one O(22), one O(4), and one O(5) atom. The Cd(2)-O(16) bond length is 2.28 Å. The Cd(2)-O(17) bond length is 2.70 Å. The Cd(2)-O(21) bond length is 2.27 Å. The Cd(2)-O(22) bond length is 2.70 Å. The Cd(2)-O(4) bond length is 2.38 Å. The Cd(2)-O(5) bond length is 2.49 Å. There are nine inequivalent C sites. In the first C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(11)-O(4) bond length is 1.28 Å. The C(11)-O(5) bond length is 1.25 Å. In the second C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(16), and one O(17) atom. The C(34)-C(35) bond length is 1.50 Å. The C(34)-O(16) bond length is 1.26 Å. The C(34)-O(17) bond length is 1.25 Å. In the third C site, C(35) is bonded in a trigonal planar geometry to one C(34), one C(36), and one C(40) atom. The C(35)-C(36) bond length is 1.39 Å. The C(35)-C(40) bond length is 1.40 Å. In the fourth C site, C(36) is bonded in a distorted single-bond geometry to one C(35) and one H(29) atom. The C(36)-H(29) bond length is 0.95 Å. In the fifth C site, C(40) is bonded in a distorted single-bond geometry to one C(35) and one H(32) atom. The C(40)-H(32) bond length is 0.95 Å. In the sixth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(46), one O(21), and one O(22) atom. The C(45)-C(46) bond length is 1.51 Å. The C(45)-O(21) bond length is 1.26 Å. The C(45)-O(22) bond length is 1.25 Å. In the seventh C site, C(46) is bonded in a trigonal planar geometry to one C(45), one C(47), and one C(51) atom. The C(46)-C(47) bond length is 1.39 Å. The C(46)-C(51) bond length is 1.39 Å. In the eighth C site, C(47) is bonded in a distorted single-bond geometry to one C(46) and one H(38,41) atom. The C(47)-H(38,41) bond length is 0.95 Å. In the ninth C site, C(51) is bonded in a distorted single-bond geometry to one C(46) and one H(38,41) atom. The C(51)-H(38,41) bond length is 0.95 Å. There are three inequivalent H sites. In the first H site, H(29) is bonded in a single-bond geometry to one C(36) atom. In the second H site, H(32) is bonded in a single-bond geometry to one C(40) atom. In the third H site, H(38,41) is bonded in a single-bond geometry to one C(47) atom. There are six inequivalent O sites. In the first O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(11) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to one Cd(2) and one C(11) atom. In the third O site, O(16) is bonded in a distorted water-like geometry to one Cd(2) and one C(34) atom. In the fourth O site, O(17) is bonded in a single-bond geometry to one Cd(2) and one C(34) atom. In the fifth O site, O(21) is bonded in a water-like geometry to one Cd(2) and one C(45) atom. In the sixth O site, O(22) is bonded in a single-bond geometry to one Cd(2) and one C(45) atom. In each CdH4(C5O4)2 cluster, Cd(1) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(12), one O(19), one O(2), one O(20), one O(29), and one O(30) atom. The Cd(1)-O(1) bond length is 2.27 Å. The Cd(1)-O(11) bond length is 2.50 Å. The Cd(1)-O(12) bond length is 2.34 Å. The Cd(1)-O(19) bond length is 2.53 Å. The Cd(1)-O(2) bond length is 2.77 Å. The Cd(1)-O(20) bond length is 2.31 Å. The Cd(1)-O(29) bond length is 2.26 Å. The Cd(1)-O(30) bond length is 2.70 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 0.95 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(7)-H(5) bond length is 0.95 Å. In the fifth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(11), and one O(12) atom. The C(23)-C(24) bond length is 1.51 Å. The C(23)-O(11) bond length is 1.26 Å. The C(23)-O(12) bond length is 1.24 Å. In the sixth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(29) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-C(29) bond length is 1.39 Å. In the seventh C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(20,23) atom. The C(25)-H(20,23) bond length is 0.95 Å. In the eighth C site, C(29) is bonded in a distorted single-bond geometry to one C(24) and one H(20,23) atom. The C(29)-H(20,23) bond length is 0.95 Å. In the ninth C site, C(44) is bonded in a distorted bent 120 degrees geometry to one O(19) and one O(20) atom. The C(44)-O(19) bond length is 1.24 Å. The C(44)-O(20) bond length is 1.27 Å. In the tenth C site, C(66) is bonded in a distorted bent 120 degrees geometry to one O(29) and one O(30) atom. The C(66)-O(29) bond length is 1.28 Å. The C(66)-O(30) bond length is 1.24 Å. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(20,23) is bonded in a single-bond geometry to one C(25) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cd(1) and one C(1) atom. In the third O site, O(11) is bonded in a distorted single-bond geometry to one Cd(1) and one C(23) atom. In the fourth O site, O(12) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(23) atom. In the fifth O site, O(19) is bonded in a distorted single-bond geometry to one Cd(1) and one C(44) atom. In the sixth O site, O(20) is bonded in a distorted water-like geometry to one Cd(1) and one C(44) atom. In the seventh O site, O(29) is bonded in a water-like geometry to one Cd(1) and one C(66) atom. In the eighth O site, O(30) is bonded in a single-bond geometry to one Cd(1) and one C(66) atom. Linkers: 14 C[C@H](NC(=O)c1ccc(C([O])=O)cc1)C([O])=O. Metal clusters: 4 O=[C]O[Cd]12(O[C]=O)(O[C]O1)O[C]O2 ,2 O=[C]O[Cd]1(O[C]=O)O[C]O1 ,2 O=[C]O[Cd](O[C]=O)O[C]=O. RCSR code: jeb. The MOF has largest included sphere 5.97 A, density 1.11 g/cm3, surface area 4442.05 m2/g, accessible volume 0.42 cm3/g