Cd3C68N10H42(O5Cl2)2(C13H7OCl)4 is Indium-derived structured and crystallizes in the tetragonal P4_322 space group. The structure is zero-dimensional and consists of eight C13H7OCl clusters and four Cd3C68N10H42(O5Cl2)2 clusters. In each C13H7OCl cluster, there are twenty-six inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(6) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(6) bond length is 0.95 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.37 Å. The C(3)-C(6) bond length is 1.47 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(7) atom. The C(4)-H(7) bond length is 0.95 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(7) atom. The C(6)-C(11) bond length is 1.43 Å. The C(6)-C(7) bond length is 1.38 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(9) atom. The C(7)-C(8) bond length is 1.42 Å. The C(7)-H(9) bond length is 0.95 Å. In the sixth C site, C(8) is bonded in a 3-coordinate geometry to one C(7), one C(9), and one O(1) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-O(1) bond length is 1.34 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(16), and one C(8) atom. The C(9)-C(10) bond length is 1.45 Å. The C(9)-C(16) bond length is 1.48 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.40 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(6) atom. The C(11)-C(12) bond length is 1.42 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(10) atom. The C(12)-C(13) bond length is 1.35 Å. The C(12)-H(10) bond length is 0.95 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one Cl(1) atom. The C(13)-C(14) bond length is 1.42 Å. The C(13)-Cl(1) bond length is 1.75 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(11) atom. The C(14)-C(15) bond length is 1.35 Å. The C(14)-H(11) bond length is 0.95 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one H(12) atom. The C(15)-H(12) bond length is 0.95 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(17), one C(25), and one C(9) atom. The C(16)-C(17) bond length is 1.43 Å. The C(16)-C(25) bond length is 1.37 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(22) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(22) bond length is 1.44 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(13) atom. The C(18)-H(13) bond length is 0.95 Å. In the seventeenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one Cl(2) atom. The C(20)-C(19) bond length is 1.41 Å. The C(20)-C(21) bond length is 1.37 Å. The C(20)-Cl(2) bond length is 1.74 Å. In the eighteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one H(15) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-H(15) bond length is 0.95 Å. In the nineteenth C site, C(22) is bonded in a trigonal planar geometry to one C(17), one C(21), and one C(23) atom. The C(22)-C(23) bond length is 1.43 Å. In the twentieth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.34 Å. The C(23)-C(28) bond length is 1.49 Å. In the twenty-first C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(16) atom. The C(24)-H(16) bond length is 0.95 Å. In the twenty-second C site, C(25) is bonded in a distorted single-bond geometry to one C(16) and one O(2) atom. The C(25)-O(2) bond length is 1.34 Å. In the twenty-third C site, C(19) is bonded in a distorted single-bond geometry to one C(20) and one H(14) atom. The C(19)-H(14) bond length is 0.95 Å. In the twenty-fourth C site, C(27) is bonded in a distorted single-bond geometry to one C(28) and one H(18,19) atom. The C(27)-C(28) bond length is 1.36 Å. The C(27)-H(18,19) bond length is 0.95 Å. In the twenty-fifth C site, C(28) is bonded in a trigonal planar geometry to one C(23), one C(27), and one C(29) atom. The C(28)-C(29) bond length is 1.40 Å. In the twenty-sixth C site, C(29) is bonded in a single-bond geometry to one C(28) and one H(18,19) atom. The C(29)-H(18,19) bond length is 0.95 Å. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.84 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.84 Å. In the third H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the thirteenth H site, H(18,19) is bonded in a single-bond geometry to one C(27) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one C(8) and one H(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(25) and one H(2) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one C(20) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one C(13) atom. In each Cd3C68N10H42(O5Cl2)2 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a T-shaped geometry to one N(3), one N(4), and one O(6) atom. The Cd(1)-N(3) bond length is 2.33 Å. The Cd(1)-N(4) bond length is 2.29 Å. The Cd(1)-O(6) bond length is 2.30 Å. In the second Cd site, Cd(2) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent O(7) atoms. Both Cd(2)-N(1) bond lengths are 2.31 Å. Both Cd(2)-N(2) bond lengths are 2.32 Å. Both Cd(2)-O(7) bond lengths are 2.36 Å. There are thirty-four inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(8) bond length is 0.95 Å. In the second C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(17) atom. The C(26)-N(2) bond length is 1.33 Å. The C(26)-H(17) bond length is 0.95 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-H(5) bond length is 0.95 Å. In the fourth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(20) atom. The C(30)-N(2) bond length is 1.33 Å. The C(30)-H(20) bond length is 0.95 Å. In the fifth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(21) atom. The C(31)-N(3) bond length is 1.29 Å. The C(31)-H(21) bond length is 0.95 Å. In the sixth C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(22) atom. The C(32)-C(33) bond length is 1.35 Å. The C(32)-H(22) bond length is 0.95 Å. In the seventh C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(36) atom. The C(33)-C(34) bond length is 1.34 Å. The C(33)-C(36) bond length is 1.49 Å. In the eighth C site, C(34) is bonded in a distorted single-bond geometry to one C(33) and one H(23) atom. The C(34)-H(23) bond length is 0.95 Å. In the ninth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(24) atom. The C(35)-N(3) bond length is 1.29 Å. The C(35)-H(24) bond length is 0.95 Å. In the tenth C site, C(36) is bonded in a trigonal planar geometry to one C(33), one C(37), and one C(45) atom. The C(36)-C(37) bond length is 1.43 Å. The C(36)-C(45) bond length is 1.33 Å. In the eleventh C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one C(42) atom. The C(37)-C(38) bond length is 1.44 Å. The C(37)-C(42) bond length is 1.43 Å. In the twelfth C site, C(38) is bonded in a distorted single-bond geometry to one C(37), one C(39), and one H(25) atom. The C(38)-C(39) bond length is 1.36 Å. The C(38)-H(25) bond length is 0.95 Å. In the thirteenth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one Cl(3) atom. The C(39)-C(40) bond length is 1.44 Å. The C(39)-Cl(3) bond length is 1.74 Å. In the fourteenth C site, C(40) is bonded in a distorted trigonal planar geometry to one C(39), one C(41), and one H(26) atom. The C(40)-C(41) bond length is 1.36 Å. The C(40)-H(26) bond length is 0.95 Å. In the fifteenth C site, C(41) is bonded in a distorted single-bond geometry to one C(40), one C(42), and one H(27) atom. The C(41)-C(42) bond length is 1.41 Å. The C(41)-H(27) bond length is 0.95 Å. In the sixteenth C site, C(42) is bonded in a trigonal planar geometry to one C(37), one C(41), and one C(43) atom. The C(42)-C(43) bond length is 1.42 Å. In the seventeenth C site, C(43) is bonded in a trigonal planar geometry to one C(42), one C(44), and one C(46) atom. The C(43)-C(44) bond length is 1.37 Å. The C(43)-C(46) bond length is 1.50 Å. In the eighteenth C site, C(44) is bonded in a distorted single-bond geometry to one C(43) and one O(3) atom. The C(44)-O(3) bond length is 1.37 Å. In the nineteenth C site, C(45) is bonded in a distorted single-bond geometry to one C(36) and one H(28) atom. The C(45)-H(28) bond length is 0.95 Å. In the twentieth C site, C(46) is bonded in a trigonal planar geometry to one C(43), one C(47), and one C(55) atom. The C(46)-C(47) bond length is 1.41 Å. The C(46)-C(55) bond length is 1.37 Å. In the twenty-first C site, C(47) is bonded in a trigonal planar geometry to one C(46), one C(48), and one C(52) atom. The C(47)-C(48) bond length is 1.43 Å. The C(47)-C(52) bond length is 1.43 Å. In the twenty-second C site, C(48) is bonded in a distorted single-bond geometry to one C(47) and one H(29) atom. The C(48)-H(29) bond length is 0.95 Å. In the twenty-third C site, C(49) is bonded in a distorted single-bond geometry to one C(50) and one H(30) atom. The C(49)-C(50) bond length is 1.43 Å. The C(49)-H(30) bond length is 0.95 Å. In the twenty-fourth C site, C(50) is bonded in a trigonal planar geometry to one C(49), one C(51), and one Cl(4) atom. The C(50)-C(51) bond length is 1.37 Å. The C(50)-Cl(4) bond length is 1.73 Å. In the twenty-fifth C site, C(51) is bonded in a distorted single-bond geometry to one C(50), one C(52), and one H(31) atom. The C(51)-C(52) bond length is 1.39 Å. The C(51)-H(31) bond length is 0.95 Å. In the twenty-sixth C site, C(52) is bonded in a trigonal planar geometry to one C(47), one C(51), and one C(53) atom. The C(52)-C(53) bond length is 1.45 Å. In the twenty-seventh C site, C(53) is bonded in a trigonal planar geometry to one C(52), one C(54), and one C(58) atom. The C(53)-C(54) bond length is 1.34 Å. The C(53)-C(58) bond length is 1.49 Å. In the twenty-eighth C site, C(54) is bonded in a distorted single-bond geometry to one C(53) and one H(32) atom. The C(54)-H(32) bond length is 0.95 Å. In the twenty-ninth C site, C(55) is bonded in a distorted single-bond geometry to one C(46) and one O(4) atom. The C(55)-O(4) bond length is 1.34 Å. In the thirtieth C site, C(56) is bonded in a distorted bent 120 degrees geometry to one C(57) and one N(4) atom. The C(56)-C(57) bond length is 1.40 Å. The C(56)-N(4) bond length is 1.34 Å. In the thirty-first C site, C(57) is bonded in a distorted single-bond geometry to one C(56), one C(58), and one H(33) atom. The C(57)-C(58) bond length is 1.37 Å. The C(57)-H(33) bond length is 0.95 Å. In the thirty-second C site, C(58) is bonded in a trigonal planar geometry to one C(53), one C(57), and one C(59) atom. The C(58)-C(59) bond length is 1.40 Å. In the thirty-third C site, C(59) is bonded in a distorted single-bond geometry to one C(58) and one H(34) atom. The C(59)-H(34) bond length is 0.95 Å. In the thirty-fourth C site, C(60) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(35) atom. The C(60)-N(4) bond length is 1.35 Å. The C(60)-H(35) bond length is 0.95 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(2), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(2), one C(26), and one C(30) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(31), and one C(35) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one O(5), one O(6), and one O(7) atom. The N(5)-O(5) bond length is 1.25 Å. The N(5)-O(6) bond length is 1.19 Å. The N(5)-O(7) bond length is 1.25 Å. In the fifth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(56), and one C(60) atom. There are twenty-one inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one O(3) atom. The H(3)-O(3) bond length is 0.84 Å. In the second H site, H(4) is bonded in a single-bond geometry to one O(4) atom. The H(4)-O(4) bond length is 0.84 Å. In the third H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one C(30) atom. In the seventh H site, H(21) is bonded in a single-bond geometry to one C(31) atom. In the eighth H site, H(22) is bonded in a single-bond geometry to one C(32) atom. In the ninth H site, H(23) is bonded in a single-bond geometry to one C(34) atom. In the tenth H site, H(24) is bonded in a single-bond geometry to one C(35) atom. In the eleventh H site, H(25) is bonded in a single-bond geometry to one C(38) atom. In the twelfth H site, H(26) is bonded in a single-bond geometry to one C(40) atom. In the thirteenth H site, H(27) is bonded in a single-bond geometry to one C(41) atom. In the fourteenth H site, H(28) is bonded in a single-bond geometry to one C(45) atom. In the fifteenth H site, H(29) is bonded in a single-bond geometry to one C(48) atom. In the sixteenth H site, H(30) is bonded in a single-bond geometry to one C(49) atom. In the seventeenth H site, H(31) is bonded in a single-bond geometry to one C(51) atom. In the eighteenth H site, H(32) is bonded in a single-bond geometry to one C(54) atom. In the nineteenth H site, H(33) is bonded in a single-bond geometry to one C(57) atom. In the twentieth H site, H(34) is bonded in a single-bond geometry to one C(59) atom. In the twenty-first H site, H(35) is bonded in a single-bond geometry to one C(60) atom. There are five inequivalent O sites. In the first O site, O(3) is bonded in a water-like geometry to one C(44) and one H(3) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one C(55) and one H(4) atom. In the third O site, O(5) is bonded in a single-bond geometry to one N(5) atom. In the fourth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one N(5) atom. In the fifth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one N(5) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(3) is bonded in a single-bond geometry to one C(39) atom. In the second Cl site, Cl(4) is bonded in a single-bond geometry to one C(50) atom. Linkers: 8 Oc1cc(-c2c[c]ncc2)c2cc(Cl)ccc2c1-c1c(O)cc(-c2ccncc2)c2cc(Cl)ccc12. Metal clusters: 4 [O]N(O[Cd])O[Cd]ON([O])O[Cd]. The MOF has largest included sphere 12.17 A, density 0.81 g/cm3, surface area 4605.10 m2/g, accessible volume 0.70 cm3/g