Pt3Cu5C36H42(N6O7)2(CH)6 crystallizes in the monoclinic C2/c space group. The structure consists of twenty-four 02329_fluka molecules inside a Pt3Cu5C36H42(N6O7)2 framework. In the Pt3Cu5C36H42(N6O7)2 framework, there are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Pt(1)-N(1) bond length is 2.02 Å. The Pt(1)-N(2) bond length is 2.04 Å. The Pt(1)-N(3) bond length is 2.03 Å. The Pt(1)-N(4) bond length is 2.01 Å. In the second Pt site, Pt(2) is bonded in a square co-planar geometry to two equivalent N(5) and two equivalent N(6) atoms. Both Pt(2)-N(5) bond lengths are 2.02 Å. Both Pt(2)-N(6) bond lengths are 2.05 Å. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), one O(5), and one O(7) atom. The Cu(1)-O(2) bond length is 1.98 Å. The Cu(1)-O(3) bond length is 1.96 Å. The Cu(1)-O(5) bond length is 2.54 Å. The Cu(1)-O(7) bond length is 1.96 Å. In the second Cu site, Cu(2) is bonded in a distorted T-shaped geometry to one O(4), one O(6), and one O(7) atom. The Cu(2)-O(4) bond length is 1.94 Å. The Cu(2)-O(6) bond length is 1.93 Å. The Cu(2)-O(7) bond length is 1.95 Å. In the third Cu site, Cu(3) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(5), and two equivalent O(7) atoms. Both Cu(3)-O(1) bond lengths are 2.00 Å. Both Cu(3)-O(5) bond lengths are 2.32 Å. Both Cu(3)-O(7) bond lengths are 1.95 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a 4-coordinate geometry to one C(2), one N(1), one H(7), and one H(8) atom. The C(1)-C(2) bond length is 1.35 Å. The C(1)-N(1) bond length is 1.51 Å. The C(1)-H(7) bond length is 0.97 Å. The C(1)-H(8) bond length is 0.97 Å. In the second C site, C(2) is bonded in a 4-coordinate geometry to one C(1), one N(2), one H(10), and one H(9) atom. The C(2)-N(2) bond length is 1.48 Å. The C(2)-H(10) bond length is 0.97 Å. The C(2)-H(9) bond length is 0.97 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(3), and one H(11) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-N(3) bond length is 1.31 Å. The C(3)-H(11) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.35 Å. The C(4)-C(8) bond length is 1.51 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(12) atom. The C(5)-H(12) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(14) atom. The C(7)-N(3) bond length is 1.37 Å. The C(7)-H(14) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(8)-O(1) bond length is 1.26 Å. The C(8)-O(2) bond length is 1.26 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(4), and one H(15) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-N(4) bond length is 1.35 Å. The C(9)-H(15) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(9) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-C(14) bond length is 1.50 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(16) atom. The C(11)-H(16) bond length is 0.93 Å. In the eleventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(18) atom. The C(13)-N(4) bond length is 1.28 Å. The C(13)-H(18) bond length is 0.93 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.22 Å. The C(14)-O(4) bond length is 1.28 Å. In the thirteenth C site, C(15) is bonded in a 4-coordinate geometry to one C(15), one N(5), one H(19), and one H(20) atom. The C(15)-C(15) bond length is 1.30 Å. The C(15)-N(5) bond length is 1.52 Å. The C(15)-H(19) bond length is 0.97 Å. The C(15)-H(20) bond length is 0.97 Å. In the fourteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(6), and one H(21) atom. The C(16)-C(17) bond length is 1.36 Å. The C(16)-N(6) bond length is 1.34 Å. The C(16)-H(21) bond length is 0.93 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(21) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(21) bond length is 1.50 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(22) atom. The C(18)-H(22) bond length is 0.93 Å. In the seventeenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(24) atom. The C(20)-N(6) bond length is 1.33 Å. The C(20)-H(24) bond length is 0.93 Å. In the eighteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(5), and one O(6) atom. The C(21)-O(5) bond length is 1.22 Å. The C(21)-O(6) bond length is 1.26 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one Pt(1); one C(1); and two equivalent H(1,2) atoms. Both N(1)-H(1,2) bond lengths are 0.90 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one Pt(1), one C(2), one H(3), and one H(4) atom. The N(2)-H(3) bond length is 0.90 Å. The N(2)-H(4) bond length is 0.90 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Pt(1), one C(3), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Pt(1), one C(13), and one C(9) atom. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one Pt(2), one C(15), one H(5), and one H(6) atom. The N(5)-H(5) bond length is 0.90 Å. The N(5)-H(6) bond length is 0.90 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Pt(2), one C(16), and one C(20) atom. There are twenty inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(5) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one N(5) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(1) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(1) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(2) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(2) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(3) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(5) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(7) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(9) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(11) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(13) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(15) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(15) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(16) atom. In the nineteenth H site, H(22) is bonded in a single-bond geometry to one C(18) atom. In the twentieth H site, H(24) is bonded in a single-bond geometry to one C(20) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one C(8) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(8) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(14) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(14) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(3), and one C(21) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(21) atom. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to one Cu(1), one Cu(2), and one Cu(3) atom. Linkers: 11 [O]C(=O)C1=CC=CN([CH]1)[Pt]1([NH2]CC[NH2]1)N1C=CC=C([CH]1)C(=O)[O] ,1 [O]C(=O)C1=CC=CN([CH]1)[Pt]1([NH2]CC[NH2]1)N1[CH]C=CC(=C1)C(=O)[O]. Metal clusters: 4 [C]1O[Cu]O[C]O[Cu]234(O[C]O[Cu]O[C]O[Cu](O[C]O2)O3)O[C]O[Cu](O1)O4. RCSR code: cds. The MOF has largest included sphere 5.75 A, density 1.38 g/cm3, surface area 3180.09 m2/g, accessible volume 0.44 cm3/g