Zn4C30H12O13(CH)6 crystallizes in the monoclinic P2_1/c space group. The structure consists of forty-eight 02329_fluka molecules inside a Zn4C30H12O13 framework. In the Zn4C30H12O13 framework, there are eight inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(4), one O(5), one O(7), and one O(8) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(2)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra, and  a cornercorner with one Zn(4)O5 trigonal bipyramid. The Zn(1)-O(4) bond length is 1.98 Å. The Zn(1)-O(5) bond length is 1.98 Å. The Zn(1)-O(7) bond length is 1.92 Å. The Zn(1)-O(8) bond length is 1.93 Å. In the second Zn site, Zn(2) is bonded to one O(10), one O(2), one O(3), and one O(7) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra, and  a cornercorner with one Zn(4)O5 trigonal bipyramid. The Zn(2)-O(10) bond length is 1.92 Å. The Zn(2)-O(2) bond length is 1.95 Å. The Zn(2)-O(3) bond length is 1.93 Å. The Zn(2)-O(7) bond length is 1.93 Å. In the third Zn site, Zn(3) is bonded to one O(1), one O(26), one O(6), and one O(7) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(2)O4 tetrahedra, and  a cornercorner with one Zn(4)O5 trigonal bipyramid. The Zn(3)-O(1) bond length is 1.98 Å. The Zn(3)-O(26) bond length is 1.94 Å. The Zn(3)-O(6) bond length is 2.02 Å. The Zn(3)-O(7) bond length is 1.93 Å. In the fourth Zn site, Zn(4) is bonded to one O(11), one O(12), one O(14), one O(16), and one O(7) atom to form ZnO5 trigonal bipyramids that share  a cornercorner with one Zn(7)O6 octahedra,  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(2)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra,  a cornercorner with one Zn(5)O4 tetrahedra, and  a cornercorner with one Zn(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 66°. The Zn(4)-O(11) bond length is 2.09 Å. The Zn(4)-O(12) bond length is 2.12 Å. The Zn(4)-O(14) bond length is 2.12 Å. The Zn(4)-O(16) bond length is 1.95 Å. The Zn(4)-O(7) bond length is 1.97 Å. In the fifth Zn site, Zn(5) is bonded to one O(13), one O(16), one O(18), and one O(19) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(7)O6 octahedra,  a cornercorner with one Zn(6)O4 tetrahedra, and  a cornercorner with one Zn(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 68°. The Zn(5)-O(13) bond length is 1.97 Å. The Zn(5)-O(16) bond length is 1.94 Å. The Zn(5)-O(18) bond length is 1.97 Å. The Zn(5)-O(19) bond length is 1.95 Å. In the sixth Zn site, Zn(6) is bonded to one O(15), one O(16), one O(17), and one O(22) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(7)O6 octahedra,  a cornercorner with one Zn(5)O4 tetrahedra, and  a cornercorner with one Zn(4)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 67°. The Zn(6)-O(15) bond length is 1.97 Å. The Zn(6)-O(16) bond length is 1.93 Å. The Zn(6)-O(17) bond length is 1.95 Å. The Zn(6)-O(22) bond length is 1.95 Å. In the seventh Zn site, Zn(7) is bonded to one O(16), one O(20), one O(21), one O(23), one O(25), and one O(9) atom to form ZnO6 octahedra that share  a cornercorner with one Zn(5)O4 tetrahedra,  a cornercorner with one Zn(6)O4 tetrahedra, and  a cornercorner with one Zn(4)O5 trigonal bipyramid. The Zn(7)-O(16) bond length is 2.01 Å. The Zn(7)-O(20) bond length is 2.24 Å. The Zn(7)-O(21) bond length is 2.22 Å. The Zn(7)-O(23) bond length is 1.99 Å. The Zn(7)-O(25) bond length is 2.15 Å. The Zn(7)-O(9) bond length is 2.18 Å. In the eighth Zn site, Zn(8) is bonded in a distorted T-shaped geometry to one O(20), one O(21), and one O(24) atom. The Zn(8)-O(20) bond length is 2.19 Å. The Zn(8)-O(21) bond length is 2.16 Å. The Zn(8)-O(24) bond length is 2.01 Å. There are sixty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.36 Å. The C(2)-C(7) bond length is 1.43 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(35), one C(4), and one C(6) atom. The C(5)-C(35) bond length is 1.51 Å. The C(5)-C(6) bond length is 1.42 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(5), and one C(7) atom. The C(6)-C(11) bond length is 1.43 Å. The C(6)-C(7) bond length is 1.43 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(8) atom. The C(7)-C(8) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(3) atom. The C(8)-H(3) bond length is 0.93 Å. In the ninth C site, C(11) is bonded in a single-bond geometry to one C(6) and one H(6) atom. The C(11)-H(6) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(3), and one O(4) atom. The C(12)-C(13) bond length is 1.50 Å. The C(12)-O(3) bond length is 1.24 Å. The C(12)-O(4) bond length is 1.25 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(22) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(22) bond length is 1.37 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.42 Å. The C(14)-C(19) bond length is 1.43 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(7) atom. The C(15)-H(7) bond length is 0.93 Å. In the fourteenth C site, C(18) is bonded in a single-bond geometry to one C(19) and one H(10) atom. The C(18)-C(19) bond length is 1.42 Å. The C(18)-H(10) bond length is 0.93 Å. In the fifteenth C site, C(19) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(20) atom. The C(19)-C(20) bond length is 1.43 Å. In the sixteenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(72) atom. The C(20)-C(21) bond length is 1.35 Å. The C(20)-C(72) bond length is 1.49 Å. In the seventeenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(11) atom. The C(21)-H(11) bond length is 0.93 Å. In the eighteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(13) and one H(12) atom. The C(22)-H(12) bond length is 0.93 Å. In the nineteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(10), and one O(11) atom. The C(23)-C(24) bond length is 1.51 Å. The C(23)-O(10) bond length is 1.26 Å. The C(23)-O(11) bond length is 1.24 Å. In the twentieth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(29) atom. The C(24)-C(25) bond length is 1.36 Å. The C(24)-C(29) bond length is 1.44 Å. In the twenty-first C site, C(25) is bonded in a single-bond geometry to one C(24) and one H(13) atom. The C(25)-H(13) bond length is 0.93 Å. In the twenty-second C site, C(26) is bonded in a single-bond geometry to one C(27) and one H(14) atom. The C(26)-C(27) bond length is 1.37 Å. The C(26)-H(14) bond length is 0.93 Å. In the twenty-third C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(36) atom. The C(27)-C(28) bond length is 1.42 Å. The C(27)-C(36) bond length is 1.51 Å. In the twenty-fourth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(33) atom. The C(28)-C(29) bond length is 1.42 Å. The C(28)-C(33) bond length is 1.43 Å. In the twenty-fifth C site, C(29) is bonded in a trigonal planar geometry to one C(24), one C(28), and one C(30) atom. The C(29)-C(30) bond length is 1.43 Å. In the twenty-sixth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(15) atom. The C(30)-H(15) bond length is 0.93 Å. In the twenty-seventh C site, C(33) is bonded in a distorted single-bond geometry to one C(28) and one H(18) atom. The C(33)-H(18) bond length is 0.93 Å. In the twenty-eighth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(65), one O(8), and one O(9) atom. The C(34)-C(65) bond length is 1.50 Å. The C(34)-O(8) bond length is 1.28 Å. The C(34)-O(9) bond length is 1.23 Å. In the twenty-ninth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(14), and one O(15) atom. The C(35)-O(14) bond length is 1.24 Å. The C(35)-O(15) bond length is 1.27 Å. In the thirtieth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(5), and one O(6) atom. The C(36)-O(5) bond length is 1.23 Å. The C(36)-O(6) bond length is 1.22 Å. In the thirty-first C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(54), one O(17), and one O(18) atom. The C(37)-C(54) bond length is 1.49 Å. The C(37)-O(17) bond length is 1.26 Å. The C(37)-O(18) bond length is 1.26 Å. In the thirty-second C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(43), one O(19), and one O(20) atom. The C(38)-C(43) bond length is 1.50 Å. The C(38)-O(19) bond length is 1.26 Å. The C(38)-O(20) bond length is 1.27 Å. In the thirty-third C site, C(39) is bonded in a distorted bent 120 degrees geometry to one C(40), one O(25), and one O(26) atom. The C(39)-C(40) bond length is 1.51 Å. The C(39)-O(25) bond length is 1.24 Å. The C(39)-O(26) bond length is 1.26 Å. In the thirty-fourth C site, C(40) is bonded in a trigonal planar geometry to one C(39), one C(41), and one C(45) atom. The C(40)-C(41) bond length is 1.37 Å. The C(40)-C(45) bond length is 1.43 Å. In the thirty-fifth C site, C(41) is bonded in a distorted single-bond geometry to one C(40) and one H(19) atom. The C(41)-H(19) bond length is 0.93 Å. In the thirty-sixth C site, C(42) is bonded in a distorted single-bond geometry to one C(43) and one H(20) atom. The C(42)-C(43) bond length is 1.37 Å. The C(42)-H(20) bond length is 0.93 Å. In the thirty-seventh C site, C(43) is bonded in a trigonal planar geometry to one C(38), one C(42), and one C(44) atom. The C(43)-C(44) bond length is 1.43 Å. In the thirty-eighth C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(49) atom. The C(44)-C(45) bond length is 1.42 Å. The C(44)-C(49) bond length is 1.43 Å. In the thirty-ninth C site, C(45) is bonded in a trigonal planar geometry to one C(40), one C(44), and one C(46) atom. The C(45)-C(46) bond length is 1.41 Å. In the fortieth C site, C(46) is bonded in a distorted single-bond geometry to one C(45) and one H(21) atom. The C(46)-H(21) bond length is 0.93 Å. In the forty-first C site, C(49) is bonded in a distorted single-bond geometry to one C(44) and one H(24) atom. The C(49)-H(24) bond length is 0.93 Å. In the forty-second C site, C(50) is bonded in a distorted bent 120 degrees geometry to one C(51), one O(23), and one O(24) atom. The C(50)-C(51) bond length is 1.50 Å. The C(50)-O(23) bond length is 1.25 Å. The C(50)-O(24) bond length is 1.26 Å. In the forty-third C site, C(51) is bonded in a trigonal planar geometry to one C(50), one C(52), and one C(56) atom. The C(51)-C(52) bond length is 1.36 Å. The C(51)-C(56) bond length is 1.43 Å. In the forty-fourth C site, C(52) is bonded in a distorted single-bond geometry to one C(51) and one H(25) atom. The C(52)-H(25) bond length is 0.93 Å. In the forty-fifth C site, C(53) is bonded in a distorted single-bond geometry to one C(54) and one H(26) atom. The C(53)-C(54) bond length is 1.38 Å. The C(53)-H(26) bond length is 0.93 Å. In the forty-sixth C site, C(54) is bonded in a trigonal planar geometry to one C(37), one C(53), and one C(55) atom. The C(54)-C(55) bond length is 1.43 Å. In the forty-seventh C site, C(55) is bonded in a trigonal planar geometry to one C(54), one C(56), and one C(60) atom. The C(55)-C(56) bond length is 1.42 Å. The C(55)-C(60) bond length is 1.41 Å. In the forty-eighth C site, C(56) is bonded in a trigonal planar geometry to one C(51), one C(55), and one C(57) atom. The C(56)-C(57) bond length is 1.42 Å. In the forty-ninth C site, C(57) is bonded in a distorted single-bond geometry to one C(56) and one H(27) atom. The C(57)-H(27) bond length is 0.93 Å. In the fiftieth C site, C(60) is bonded in a distorted single-bond geometry to one C(55) and one H(30) atom. The C(60)-H(30) bond length is 0.93 Å. In the fifty-first C site, C(61) is bonded in a distorted bent 120 degrees geometry to one C(62), one O(21), and one O(22) atom. The C(61)-C(62) bond length is 1.49 Å. The C(61)-O(21) bond length is 1.27 Å. The C(61)-O(22) bond length is 1.26 Å. In the fifty-second C site, C(62) is bonded in a trigonal planar geometry to one C(61), one C(63), and one C(67) atom. The C(62)-C(63) bond length is 1.37 Å. The C(62)-C(67) bond length is 1.43 Å. In the fifty-third C site, C(63) is bonded in a single-bond geometry to one C(62) and one H(31) atom. The C(63)-H(31) bond length is 0.93 Å. In the fifty-fourth C site, C(64) is bonded in a single-bond geometry to one C(65) and one H(32) atom. The C(64)-C(65) bond length is 1.37 Å. The C(64)-H(32) bond length is 0.93 Å. In the fifty-fifth C site, C(65) is bonded in a trigonal planar geometry to one C(34), one C(64), and one C(66) atom. The C(65)-C(66) bond length is 1.42 Å. In the fifty-sixth C site, C(66) is bonded in a trigonal planar geometry to one C(65), one C(67), and one C(71) atom. The C(66)-C(67) bond length is 1.42 Å. The C(66)-C(71) bond length is 1.42 Å. In the fifty-seventh C site, C(67) is bonded in a trigonal planar geometry to one C(62), one C(66), and one C(68) atom. The C(67)-C(68) bond length is 1.42 Å. In the fifty-eighth C site, C(68) is bonded in a distorted single-bond geometry to one C(67) and one H(33) atom. The C(68)-H(33) bond length is 0.93 Å. In the fifty-ninth C site, C(71) is bonded in a distorted single-bond geometry to one C(66) and one H(36) atom. The C(71)-H(36) bond length is 0.93 Å. In the sixtieth C site, C(72) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(12), and one O(13) atom. The C(72)-O(12) bond length is 1.25 Å. The C(72)-O(13) bond length is 1.26 Å. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(30) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(33) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(41) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(42) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(46) atom. In the sixteenth H site, H(24) is bonded in a single-bond geometry to one C(49) atom. In the seventeenth H site, H(25) is bonded in a single-bond geometry to one C(52) atom. In the eighteenth H site, H(26) is bonded in a single-bond geometry to one C(53) atom. In the nineteenth H site, H(27) is bonded in a single-bond geometry to one C(57) atom. In the twentieth H site, H(30) is bonded in a single-bond geometry to one C(60) atom. In the twenty-first H site, H(31) is bonded in a single-bond geometry to one C(63) atom. In the twenty-second H site, H(32) is bonded in a single-bond geometry to one C(64) atom. In the twenty-third H site, H(33) is bonded in a single-bond geometry to one C(68) atom. In the twenty-fourth H site, H(36) is bonded in a single-bond geometry to one C(71) atom. There are twenty-six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(12) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(12) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(36) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(36) atom. In the seventh O site, O(7) is bonded to one Zn(1), one Zn(2), one Zn(3), and one Zn(4) atom to form corner-sharing OZn4 tetrahedra. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(34) atom. In the ninth O site, O(9) is bonded in a distorted linear geometry to one Zn(7) and one C(34) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(23) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(23) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(72) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(72) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(35) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(35) atom. In the sixteenth O site, O(16) is bonded to one Zn(4), one Zn(5), one Zn(6), and one Zn(7) atom to form corner-sharing OZn4 tetrahedra. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(37) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(37) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(38) atom. In the twentieth O site, O(20) is bonded in a 3-coordinate geometry to one Zn(7), one Zn(8), and one C(38) atom. In the twenty-first O site, O(21) is bonded in a distorted trigonal planar geometry to one Zn(7), one Zn(8), and one C(61) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(61) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 150 degrees geometry to one Zn(7) and one C(50) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 120 degrees geometry to one Zn(8) and one C(50) atom. In the twenty-fifth O site, O(25) is bonded in a bent 150 degrees geometry to one Zn(7) and one C(39) atom. In the twenty-sixth O site, O(26) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(39) atom. Linkers: 24 [O]C(=O)c1ccc(C([O])=O)c2ccccc12. Metal clusters: 4 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O[C]O[Zn]5O[C]O[Zn@]67O[C]O[Zn](O1)O[C]O[Zn@](O[C]O5)(O[C]O6)O7)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: pcu. The MOF has largest included sphere 5.24 A, density 1.48 g/cm3, surface area 3682.26 m2/g, accessible volume 0.27 cm3/g