MnC16H8S2(N2O3)2(CH)4 crystallizes in the monoclinic Pc space group. The structure consists of sixteen 02329_fluka molecules inside a MnC16H8S2(N2O3)2 framework. In the MnC16H8S2(N2O3)2 framework, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a rectangular see-saw-like geometry to one N(5), one N(8), one O(1), and one O(11) atom. The Mn(1)-N(5) bond length is 2.27 Å. The Mn(1)-N(8) bond length is 2.28 Å. The Mn(1)-O(1) bond length is 2.20 Å. The Mn(1)-O(11) bond length is 2.10 Å. In the second Mn site, Mn(2) is bonded in a rectangular see-saw-like geometry to one N(2), one N(4), one O(4), and one O(9) atom. The Mn(2)-N(2) bond length is 2.27 Å. The Mn(2)-N(4) bond length is 2.28 Å. The Mn(2)-O(4) bond length is 2.16 Å. The Mn(2)-O(9) bond length is 2.14 Å. There are thirty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.42 Å. The C(1)-S(1) bond length is 1.76 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.95 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-H(3) bond length is 0.95 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-C(7) bond length is 1.45 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(4) atom. The C(6)-H(4) bond length is 0.95 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5), one C(8), and one N(1) atom. The C(7)-C(8) bond length is 1.44 Å. The C(7)-N(1) bond length is 1.33 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(3) atom. The C(8)-C(9) bond length is 1.47 Å. The C(8)-N(3) bond length is 1.34 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.41 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(10)-H(5) bond length is 0.95 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(7) atom. The C(12)-C(13) bond length is 1.43 Å. The C(12)-H(7) bond length is 0.95 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one S(2) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-S(2) bond length is 1.75 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(9), and one H(8) atom. The C(14)-H(8) bond length is 0.95 Å. In the thirteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one N(2), and one N(3) atom. The C(15)-C(16) bond length is 1.49 Å. The C(15)-N(2) bond length is 1.35 Å. The C(15)-N(3) bond length is 1.35 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one N(4) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-N(4) bond length is 1.35 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(9) atom. The C(17)-H(9) bond length is 0.95 Å. In the sixteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(12) atom. The C(20)-N(4) bond length is 1.34 Å. The C(20)-H(12) bond length is 0.95 Å. In the seventeenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(13) atom. The C(21)-N(8) bond length is 1.37 Å. The C(21)-H(13) bond length is 0.95 Å. In the eighteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(16) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(16) bond length is 0.95 Å. In the nineteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one C(26), and one N(8) atom. The C(25)-C(26) bond length is 1.47 Å. The C(25)-N(8) bond length is 1.35 Å. In the twentieth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one N(5), and one N(7) atom. The C(26)-N(5) bond length is 1.36 Å. The C(26)-N(7) bond length is 1.34 Å. In the twenty-first C site, C(27) is bonded in a distorted trigonal planar geometry to one C(28), one C(35), and one N(7) atom. The C(27)-C(28) bond length is 1.44 Å. The C(27)-C(35) bond length is 1.49 Å. The C(27)-N(7) bond length is 1.30 Å. In the twenty-second C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one C(29), and one N(6) atom. The C(28)-C(29) bond length is 1.44 Å. The C(28)-N(6) bond length is 1.31 Å. In the twenty-third C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(34) atom. The C(29)-C(30) bond length is 1.45 Å. The C(29)-C(34) bond length is 1.41 Å. In the twenty-fourth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(17) atom. The C(30)-H(17) bond length is 0.95 Å. In the twenty-fifth C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(19) atom. The C(32)-C(33) bond length is 1.35 Å. The C(32)-H(19) bond length is 0.95 Å. In the twenty-sixth C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one S(4) atom. The C(33)-C(34) bond length is 1.39 Å. The C(33)-S(4) bond length is 1.78 Å. In the twenty-seventh C site, C(34) is bonded in a distorted single-bond geometry to one C(29), one C(33), and one H(20) atom. The C(34)-H(20) bond length is 0.95 Å. In the twenty-eighth C site, C(35) is bonded in a trigonal planar geometry to one C(27), one C(36), and one C(40) atom. The C(35)-C(36) bond length is 1.38 Å. The C(35)-C(40) bond length is 1.46 Å. In the twenty-ninth C site, C(36) is bonded in a distorted single-bond geometry to one C(35), one C(37), and one H(21) atom. The C(36)-C(37) bond length is 1.42 Å. The C(36)-H(21) bond length is 0.95 Å. In the thirtieth C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one S(3) atom. The C(37)-C(38) bond length is 1.37 Å. The C(37)-S(3) bond length is 1.78 Å. In the thirty-first C site, C(38) is bonded in a distorted single-bond geometry to one C(37) and one H(22) atom. The C(38)-H(22) bond length is 0.95 Å. In the thirty-second C site, C(40) is bonded in a distorted single-bond geometry to one C(35) and one H(24) atom. The C(40)-H(24) bond length is 0.95 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one C(7) and one N(2) atom. The N(1)-N(2) bond length is 1.35 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Mn(2), one C(15), and one N(1) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(15) and one C(8) atom. In the fourth N site, N(6) is bonded in a distorted bent 120 degrees geometry to one C(28) and one N(5) atom. The N(6)-N(5) bond length is 1.37 Å. In the fifth N site, N(8) is bonded in a trigonal planar geometry to one Mn(1), one C(21), and one C(25) atom. In the sixth N site, N(4) is bonded in a trigonal planar geometry to one Mn(2), one C(16), and one C(20) atom. In the seventh N site, N(5) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(26), and one N(6) atom. In the eighth N site, N(7) is bonded in a bent 120 degrees geometry to one C(26) and one C(27) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(30) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(32) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(34) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(36) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(38) atom. In the sixteenth H site, H(24) is bonded in a single-bond geometry to one C(40) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.47 Å. The S(1)-O(2) bond length is 1.48 Å. The S(1)-O(3) bond length is 1.45 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one C(13), one O(4), one O(5), and one O(6) atom. The S(2)-O(4) bond length is 1.43 Å. The S(2)-O(5) bond length is 1.43 Å. The S(2)-O(6) bond length is 1.45 Å. In the third S site, S(3) is bonded in a distorted trigonal non-coplanar geometry to one C(37), one O(10), one O(11), and one O(12) atom. The S(3)-O(10) bond length is 1.40 Å. The S(3)-O(11) bond length is 1.47 Å. The S(3)-O(12) bond length is 1.46 Å. In the fourth S site, S(4) is bonded in a distorted trigonal non-coplanar geometry to one C(33), one O(7), one O(8), and one O(9) atom. The S(4)-O(7) bond length is 1.37 Å. The S(4)-O(8) bond length is 1.45 Å. The S(4)-O(9) bond length is 1.43 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Mn(2) and one S(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(4) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one S(4) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Mn(2) and one S(4) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one S(3) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mn(1) and one S(3) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one S(3) atom. Linkers: 4 [O]S([O])([O])c1cccc(-c2nnc(-c3ccccn3)nc2-c2cccc(S([O])([O])[O])c2)c1 ,2 [C]/C=C(\C=[CH])c1nnc(-c2ccccn2)nc1-c1cccc(S([O])([O])[O])c1 ,2 [CH]/N=C(\[CH])c1nnc(-c2cccc(S([O])([O])[O])c2)c(-c2cccc(S([O])([O])[O])c2)n1. Metal clusters: 4 [O][S@](=O)O[Mn]O[S@@]([O])=O. The MOF has largest included sphere 4.66 A, density 1.23 g/cm3, surface area 4502.39 m2/g, accessible volume 0.38 cm3/g