Zn3C52H32(NO6)2(C3H2)6(CH)4(C7NH4)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; six 2,3-dimethyl-1,3-butadiene molecules; four schembl5425382 molecules; and two Zn3C52H32(NO6)2 clusters. In each Zn3C52H32(NO6)2 cluster, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 6-coordinate geometry to one N(1), one O(12), one O(3), one O(6), one O(8), and one O(9) atom. The Zn(1)-N(1) bond length is 2.08 Å. The Zn(1)-O(12) bond length is 2.43 Å. The Zn(1)-O(3) bond length is 1.98 Å. The Zn(1)-O(6) bond length is 2.41 Å. The Zn(1)-O(8) bond length is 2.04 Å. The Zn(1)-O(9) bond length is 2.00 Å. In the second Zn site, Zn(2) is bonded in a trigonal pyramidal geometry to one O(1), one O(4), one O(5), and one O(6) atom. The Zn(2)-O(1) bond length is 1.95 Å. The Zn(2)-O(4) bond length is 1.99 Å. The Zn(2)-O(5) bond length is 2.02 Å. The Zn(2)-O(6) bond length is 2.01 Å. In the third Zn site, Zn(3) is bonded in a distorted tetrahedral geometry to one N(2), one O(10), one O(2), and one O(7) atom. The Zn(3)-N(2) bond length is 2.04 Å. The Zn(3)-O(10) bond length is 1.94 Å. The Zn(3)-O(2) bond length is 1.94 Å. The Zn(3)-O(7) bond length is 1.93 Å. There are fifty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1) atom. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(21) and one H(2) atom. The C(2)-C(21) bond length is 1.40 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(7) and one H(3) atom. The C(3)-C(7) bond length is 1.40 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(4) bond length is 0.93 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(3) atom. The C(7)-C(21) bond length is 1.48 Å. The C(7)-C(25) bond length is 1.39 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(3), and one O(5) atom. The C(8)-C(24) bond length is 1.49 Å. The C(8)-O(3) bond length is 1.25 Å. The C(8)-O(5) bond length is 1.26 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(33), one O(12), and one O(9) atom. The C(10)-C(33) bond length is 1.50 Å. The C(10)-O(12) bond length is 1.26 Å. The C(10)-O(9) bond length is 1.25 Å. In the eighth C site, C(12) is bonded in a single-bond geometry to one C(21) and one H(5) atom. The C(12)-C(21) bond length is 1.36 Å. The C(12)-H(5) bond length is 0.93 Å. In the ninth C site, C(13) is bonded in a 3-coordinate geometry to one C(25), one N(2), and one H(6) atom. The C(13)-C(25) bond length is 1.38 Å. The C(13)-N(2) bond length is 1.34 Å. The C(13)-H(6) bond length is 0.93 Å. In the tenth C site, C(14) is bonded in a trigonal planar geometry to one C(26), one C(57), and one C(71) atom. The C(14)-C(26) bond length is 1.49 Å. The C(14)-C(57) bond length is 1.37 Å. The C(14)-C(71) bond length is 1.39 Å. In the eleventh C site, C(15) is bonded in a trigonal planar geometry to one C(20), one C(47), and one C(66) atom. The C(15)-C(20) bond length is 1.49 Å. The C(15)-C(47) bond length is 1.39 Å. The C(15)-C(66) bond length is 1.37 Å. In the twelfth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(11), and one O(7) atom. The C(16)-C(37) bond length is 1.48 Å. The C(16)-O(11) bond length is 1.23 Å. The C(16)-O(7) bond length is 1.29 Å. In the thirteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(24) and one H(7) atom. The C(17)-C(24) bond length is 1.38 Å. The C(17)-H(7) bond length is 0.93 Å. In the fourteenth C site, C(18) is bonded in a trigonal planar geometry to one C(50), one C(54), and one C(69) atom. The C(18)-C(50) bond length is 1.40 Å. The C(18)-C(54) bond length is 1.47 Å. The C(18)-C(69) bond length is 1.41 Å. In the fifteenth C site, C(20) is bonded in a bent 120 degrees geometry to one C(15), one O(6), and one O(8) atom. The C(20)-O(6) bond length is 1.26 Å. The C(20)-O(8) bond length is 1.25 Å. In the sixteenth C site, C(21) is bonded in a trigonal planar geometry to one C(12), one C(2), and one C(7) atom. In the seventeenth C site, C(22) is bonded in a distorted single-bond geometry to one C(37) and one H(8) atom. The C(22)-C(37) bond length is 1.39 Å. The C(22)-H(8) bond length is 0.93 Å. In the eighteenth C site, C(24) is bonded in a trigonal planar geometry to one C(17), one C(56), and one C(8) atom. The C(24)-C(56) bond length is 1.38 Å. In the nineteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(13), one C(7), and one H(9) atom. The C(25)-H(9) bond length is 0.93 Å. In the twentieth C site, C(26) is bonded in a trigonal planar geometry to one C(14), one C(41), and one C(64) atom. The C(26)-C(41) bond length is 1.39 Å. The C(26)-C(64) bond length is 1.40 Å. In the twenty-first C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(43), one O(1), and one O(10) atom. The C(27)-C(43) bond length is 1.48 Å. The C(27)-O(1) bond length is 1.24 Å. The C(27)-O(10) bond length is 1.25 Å. In the twenty-second C site, C(28) is bonded in a distorted single-bond geometry to one C(33) and one H(10) atom. The C(28)-C(33) bond length is 1.40 Å. The C(28)-H(10) bond length is 0.93 Å. In the twenty-third C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(51), one O(2), and one O(4) atom. The C(29)-C(51) bond length is 1.50 Å. The C(29)-O(2) bond length is 1.26 Å. The C(29)-O(4) bond length is 1.25 Å. In the twenty-fourth C site, C(30) is bonded in a distorted single-bond geometry to one C(54) and one H(11) atom. The C(30)-C(54) bond length is 1.40 Å. The C(30)-H(11) bond length is 0.93 Å. In the twenty-fifth C site, C(33) is bonded in a trigonal planar geometry to one C(10), one C(28), and one C(53) atom. The C(33)-C(53) bond length is 1.39 Å. In the twenty-sixth C site, C(37) is bonded in a trigonal planar geometry to one C(16), one C(22), and one C(74) atom. The C(37)-C(74) bond length is 1.40 Å. In the twenty-seventh C site, C(38) is bonded in a 2-coordinate geometry to one N(1) and one H(17) atom. The C(38)-N(1) bond length is 1.33 Å. The C(38)-H(17) bond length is 0.93 Å. In the twenty-eighth C site, C(39) is bonded in a distorted single-bond geometry to one C(51) and one H(18) atom. The C(39)-C(51) bond length is 1.36 Å. The C(39)-H(18) bond length is 0.93 Å. In the twenty-ninth C site, C(41) is bonded in a distorted single-bond geometry to one C(26) and one H(19) atom. The C(41)-H(19) bond length is 0.93 Å. In the thirtieth C site, C(43) is bonded in a trigonal planar geometry to one C(27), one C(70), and one C(83) atom. The C(43)-C(70) bond length is 1.39 Å. The C(43)-C(83) bond length is 1.38 Å. In the thirty-first C site, C(46) is bonded in a trigonal planar geometry to one C(65), one C(76), and one C(84) atom. The C(46)-C(65) bond length is 1.40 Å. The C(46)-C(76) bond length is 1.49 Å. The C(46)-C(84) bond length is 1.39 Å. In the thirty-second C site, C(47) is bonded in a distorted single-bond geometry to one C(15) and one H(21) atom. The C(47)-H(21) bond length is 0.93 Å. In the thirty-third C site, C(50) is bonded in a distorted single-bond geometry to one C(18) and one H(24) atom. The C(50)-H(24) bond length is 0.93 Å. In the thirty-fourth C site, C(51) is bonded in a trigonal planar geometry to one C(29), one C(39), and one C(61) atom. The C(51)-C(61) bond length is 1.39 Å. In the thirty-fifth C site, C(52) is bonded in a distorted single-bond geometry to one C(54) and one H(25) atom. The C(52)-C(54) bond length is 1.38 Å. The C(52)-H(25) bond length is 0.93 Å. In the thirty-sixth C site, C(53) is bonded in a distorted trigonal planar geometry to one C(33), one C(69), and one H(26) atom. The C(53)-C(69) bond length is 1.38 Å. The C(53)-H(26) bond length is 0.93 Å. In the thirty-seventh C site, C(54) is bonded in a trigonal planar geometry to one C(18), one C(30), and one C(52) atom. In the thirty-eighth C site, C(56) is bonded in a distorted single-bond geometry to one C(24) and one H(28) atom. The C(56)-H(28) bond length is 0.93 Å. In the thirty-ninth C site, C(57) is bonded in a distorted trigonal planar geometry to one C(14), one C(66), and one H(29) atom. The C(57)-C(66) bond length is 1.40 Å. The C(57)-H(29) bond length is 0.93 Å. In the fortieth C site, C(61) is bonded in a distorted single-bond geometry to one C(51) and one H(33) atom. The C(61)-H(33) bond length is 0.93 Å. In the forty-first C site, C(64) is bonded in a distorted single-bond geometry to one C(26) and one H(35) atom. The C(64)-H(35) bond length is 0.93 Å. In the forty-second C site, C(65) is bonded in a distorted trigonal planar geometry to one C(46), one C(70), and one H(36) atom. The C(65)-C(70) bond length is 1.39 Å. The C(65)-H(36) bond length is 0.93 Å. In the forty-third C site, C(66) is bonded in a distorted single-bond geometry to one C(15), one C(57), and one H(37) atom. The C(66)-H(37) bond length is 0.93 Å. In the forty-fourth C site, C(69) is bonded in a distorted single-bond geometry to one C(18), one C(53), and one H(40) atom. The C(69)-H(40) bond length is 0.93 Å. In the forty-fifth C site, C(70) is bonded in a distorted single-bond geometry to one C(43), one C(65), and one H(41) atom. The C(70)-H(41) bond length is 0.93 Å. In the forty-sixth C site, C(71) is bonded in a single-bond geometry to one C(14) and one H(42) atom. The C(71)-H(42) bond length is 0.93 Å. In the forty-seventh C site, C(74) is bonded in a distorted single-bond geometry to one C(37) and one H(44) atom. The C(74)-H(44) bond length is 0.93 Å. In the forty-eighth C site, C(76) is bonded in a trigonal planar geometry to one C(46), one C(80), and one C(88) atom. The C(76)-C(80) bond length is 1.37 Å. The C(76)-C(88) bond length is 1.39 Å. In the forty-ninth C site, C(80) is bonded in a distorted single-bond geometry to one C(76) and one H(49) atom. The C(80)-H(49) bond length is 0.93 Å. In the fiftieth C site, C(83) is bonded in a distorted single-bond geometry to one C(43) and one H(51) atom. The C(83)-H(51) bond length is 0.93 Å. In the fifty-first C site, C(84) is bonded in a distorted single-bond geometry to one C(46) and one H(52) atom. The C(84)-H(52) bond length is 0.93 Å. In the fifty-second C site, C(88) is bonded in a distorted single-bond geometry to one C(76) and one H(56) atom. The C(88)-H(56) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(38), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(3), one C(1), and one C(13) atom. There are thirty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(28) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(30) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(38) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(39) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(41) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(47) atom. In the sixteenth H site, H(24) is bonded in a single-bond geometry to one C(50) atom. In the seventeenth H site, H(25) is bonded in a single-bond geometry to one C(52) atom. In the eighteenth H site, H(26) is bonded in a single-bond geometry to one C(53) atom. In the nineteenth H site, H(28) is bonded in a single-bond geometry to one C(56) atom. In the twentieth H site, H(29) is bonded in a single-bond geometry to one C(57) atom. In the twenty-first H site, H(33) is bonded in a single-bond geometry to one C(61) atom. In the twenty-second H site, H(35) is bonded in a single-bond geometry to one C(64) atom. In the twenty-third H site, H(36) is bonded in a single-bond geometry to one C(65) atom. In the twenty-fourth H site, H(37) is bonded in a single-bond geometry to one C(66) atom. In the twenty-fifth H site, H(40) is bonded in a single-bond geometry to one C(69) atom. In the twenty-sixth H site, H(41) is bonded in a single-bond geometry to one C(70) atom. In the twenty-seventh H site, H(42) is bonded in a single-bond geometry to one C(71) atom. In the twenty-eighth H site, H(44) is bonded in a single-bond geometry to one C(74) atom. In the twenty-ninth H site, H(49) is bonded in a single-bond geometry to one C(80) atom. In the thirtieth H site, H(51) is bonded in a single-bond geometry to one C(83) atom. In the thirty-first H site, H(52) is bonded in a single-bond geometry to one C(84) atom. In the thirty-second H site, H(56) is bonded in a single-bond geometry to one C(88) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(27) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(29) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(29) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(8) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Zn(1), one Zn(2), and one C(20) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Zn(3) and one C(16) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Zn(1) and one C(20) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Zn(1) and one C(10) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(27) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one C(16) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Zn(1) and one C(10) atom. Linkers: 4 [O]C(=O)c1ccc(-c2ccc(N(c3ccc(-c4ccc(C([O])=O)cc4)cc3)c3ccc(-c4ccc(C([O])=O)cc4)cc3)cc2)cc1 ,2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 O=[C]O[Zn]1O[C]O[Zn]2(O[C]O1)O[C]O[Zn](O[C]=O)O[C]O2. The MOF has largest included sphere 9.75 A, density 0.75 g/cm3, surface area 4723.32 m2/g, accessible volume 0.84 cm3/g