Zn8C36H24O25(C5H3)12 is Indium-derived structured and crystallizes in the cubic Fm-3m space group. The structure is zero-dimensional and consists of forty-eight C5H3 clusters and eight Zn8C36H24O25 clusters. In each C5H3 cluster, there are seven inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(8) and one H(2) atom. The C(2)-C(8) bond length is 1.39 Å. The C(2)-H(2) bond length is 0.93 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(11) and one H(3) atom. The C(3)-C(11) bond length is 1.40 Å. The C(3)-H(3) bond length is 0.94 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(8) and one H(1,4) atom. The C(4)-C(8) bond length is 1.37 Å. The C(4)-H(1,4) bond length is 0.93 Å. In the fourth C site, C(8) is bonded in a 5-coordinate geometry to one C(9), two equivalent C(2), and two equivalent C(4) atoms. The C(8)-C(9) bond length is 1.43 Å. In the fifth C site, C(9) is bonded in a linear geometry to one C(10) and one C(8) atom. The C(9)-C(10) bond length is 1.13 Å. In the sixth C site, C(10) is bonded in a linear geometry to one C(11) and one C(9) atom. The C(10)-C(11) bond length is 1.49 Å. In the seventh C site, C(11) is bonded in a trigonal planar geometry to one C(10) and two equivalent C(3) atoms. There are three inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(1) atom. The H(1,4)-C(1) bond length is 0.93 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In each Zn8C36H24O25 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(3) and three equivalent O(1) atoms to form distorted corner-sharing ZnO4 tetrahedra. The Zn(1)-O(3) bond length is 2.00 Å. All Zn(1)-O(1) bond lengths are 2.05 Å. In the second Zn site, Zn(2) is bonded to one O(3) and three equivalent O(2) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(3) bond length is 1.94 Å. All Zn(2)-O(2) bond lengths are 1.92 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(7) and one H(1,4) atom. The C(1)-C(7) bond length is 1.40 Å. In the second C site, C(5) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(5)-C(7) bond length is 1.38 Å. The C(5)-H(5) bond length is 0.93 Å. In the third C site, C(6) is bonded in a 4-coordinate geometry to one C(7), two equivalent O(1), and two equivalent O(2) atoms. The C(6)-C(7) bond length is 1.52 Å. Both C(6)-O(1) bond lengths are 1.35 Å. Both C(6)-O(2) bond lengths are 1.21 Å. In the fourth C site, C(7) is bonded in a 5-coordinate geometry to one C(6), two equivalent C(1), and two equivalent C(5) atoms. There are two inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(5) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Zn(2) and one C(6) atom. In the third O site, O(3) is bonded in a body-centered cubic geometry to four equivalent Zn(1) and four equivalent Zn(2) atoms. Linkers: 3 C1=CC23C=CC14[C@H]1[C@@H]4[C@@H]2[C@H]13.C1=CC23C=CC14[C@H]1[C@@H]4[C@@H]2[C@H]13.[C]#Cc1ccc(C#[C])cc1.[O]C([O])([O])[O].[O]C([O])([O])[O] ,14 [C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@@H]4[C@H]5[C@@H]([C@@H]41)C235.[C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@@H]4[C@H]5[C@@H]([C@@H]41)C235.[C]#Cc1ccc(C#[C])cc1.[O]C([O])([O])[O].[O]C([O])([O])[O] ,4 C1=CC23C=CC14[C@H]1[C@@H]4[C@@H]2[C@H]13.[C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@@H]4[C@H]5[C@@H]([C@@H]41)C235.[C]#Cc1ccc(C#[C])cc1.[O]C([O])([O])[O].[O]C([O])([O])[O] ,1 [CH]1[C@@H]2[C@@H]3[C@H]4[C@H]5[CH][C@]32C=C[C@@]145.[CH]1[C@H]2[C@H]3[C@@H]4[C@@H]5[CH][C@@]32C=C[C@]145.[C]#Cc1ccc(C#[C])cc1.[O]C([O])([O])[O].[O]C([O])([O])[O] ,1 C1=CC23C=CC14[C@H]1[C@@H]4[C@@H]2[C@H]13.[CH]1[C@@H]2[C@@H]3[C@H]4[C@H]5[C@@H]6[C@H]([CH][C@@]145)[C@@]632.[C]#Cc1ccc(C#[C])cc1.[O]C([O])([O])[O].[O]C([O])([O])[O] ,1 C1=CC23C=CC14[C@H]1[C@@H]4[C@@H]2[C@H]13.[CH]1[C@@H]2[C@@H]3[CH][C@@]14[C@@H]1[C@H]4[C@H]4[C@@H]1[C@]423.[C]#Cc1ccc(C#[C])cc1.[O]C([O])([O])[O].[O]C([O])([O])[O]. Metal clusters: 1 [O]C([O])([O])O[Zn]1[Zn][Zn][Zn]1O[Zn]1[Zn][Zn][Zn]1(OC([O])([O])[O])(OC([O])([O])[O])OC([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O] ,1 [O]C([O])([O])O[Zn]1[Zn][Zn][Zn]1O[Zn]1[Zn][Zn][Zn]1(OC([O])([O])[O])OC([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O] ,1 [O]C([O])([O])O[Zn]1[Zn]O[Zn@]2([Zn]([Zn])OC([O])([O])[O])[Zn][Zn]1[Zn]2(OC([O])([O])[O])OC([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O] ,1 [O]C([O])([O])O[Zn]1[Zn]2O[Zn@@]13[Zn][Zn]([Zn]2)[Zn]3OC([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O].[Zn] ,1 [O]C([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O].[Zn][Zn]O[Zn]1[Zn][Zn]([Zn][Zn])[Zn]1 ,1 O1[Zn][Zn][Zn]12[Zn][Zn][Zn]2.[O]C([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O].[Zn][Zn] ,1 [O]C([O])([O])O[Zn]12O[Zn]([Zn]1)[Zn]2.[O]C([O])([O])O[Zn]1[Zn][Zn][Zn]1.[O]C([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O] ,1 [O]C([O])([O])O[Zn]1[Zn][Zn](OC([O])([O])[O])[Zn]1O[Zn]1[Zn][Zn][Zn]1.[O]C([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O].[O]C([O])([O])[O]. RCSR code: pcu. The MOF has largest included sphere 33.08 A, density 0.19 g/cm3, surface area 3394.01 m2/g, accessible volume 4.91 cm3/g