Cd3C10H4(NO6)2(CH)6(CH2)6(C3H2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules; six 02329_fluka molecules; one 2,3-dimethyl-1,3-butadiene molecule; and one Cd3C10H4(NO6)2 cluster. In the Cd3C10H4(NO6)2 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 5-coordinate geometry to one N(1), one O(1), one O(3), one O(4), and one O(6) atom. The Cd(1)-N(1) bond length is 2.26 Å. The Cd(1)-O(1) bond length is 2.25 Å. The Cd(1)-O(3) bond length is 2.33 Å. The Cd(1)-O(4) bond length is 2.50 Å. The Cd(1)-O(6) bond length is 2.25 Å. In the second Cd site, Cd(2) is bonded in an octahedral geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. Both Cd(2)-O(2) bond lengths are 2.23 Å. Both Cd(2)-O(4) bond lengths are 2.34 Å. Both Cd(2)-O(6) bond lengths are 2.29 Å. There are five inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(5)-O(5) bond length is 1.23 Å. The C(5)-O(6) bond length is 1.27 Å. In the second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.26 Å. The C(8)-O(4) bond length is 1.26 Å. In the third C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(10) atom. The C(10)-N(1) bond length is 1.32 Å. The C(10)-H(10) bond length is 0.93 Å. In the fourth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(14)-N(1) bond length is 1.33 Å. The C(14)-H(13) bond length is 0.93 Å. In the fifth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.25 Å. N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(14) atom. There are two inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(13) is bonded in a single-bond geometry to one C(14) atom. There are six inequivalent O sites. In the first O site, O(6) is bonded in a distorted trigonal non-coplanar geometry to one Cd(1), one Cd(2), and one C(5) atom. In the second O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(8) atom. In the third O site, O(1) is bonded in a 2-coordinate geometry to one Cd(1) and one C(1) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one C(1) atom. In the fifth O site, O(4) is bonded in a 1-coordinate geometry to one Cd(1), one Cd(2), and one C(8) atom. In the sixth O site, O(5) is bonded in a single-bond geometry to one C(5) atom. Linkers: 2 [O]C(=O)[C@H]1C[C@@H](C([O])=O)C[C@@H](C([O])=O)C1 ,1 c1cc(-c2ccncc2)ccn1. Metal clusters: 1 O=[C]O[Cd]1O[C]O[Cd]2(O[C]O1)O[C]O[Cd](O[C]=O)O[C]O2. RCSR code: kgd. The MOF has largest included sphere 5.73 A, density 1.22 g/cm3, surface area 3515.66 m2/g, accessible volume 0.46 cm3/g