Zn5C34N9H29O13(CH)2 crystallizes in the orthorhombic Pnma space group. The structure consists of eight 02329_fluka molecules inside a Zn5C34N9H29O13 framework. In the Zn5C34N9H29O13 framework, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(1), one N(4), one O(5), one O(6), and one O(7) atom to form distorted ZnN2O3 trigonal bipyramids that share  a cornercorner with one Zn(3)N3O tetrahedra and  a cornercorner with one Zn(1)N2O3 trigonal bipyramid. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-N(4) bond length is 2.04 Å. The Zn(1)-O(5) bond length is 2.26 Å. The Zn(1)-O(6) bond length is 2.03 Å. The Zn(1)-O(7) bond length is 2.02 Å. In the second Zn site, Zn(2) is bonded in a distorted square pyramidal geometry to one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(2)-N(3) bond length is 2.03 Å. The Zn(2)-O(1) bond length is 2.06 Å. The Zn(2)-O(2) bond length is 2.06 Å. The Zn(2)-O(3) bond length is 2.05 Å. The Zn(2)-O(4) bond length is 2.05 Å. In the third Zn site, Zn(3) is bonded to one N(5), two equivalent N(2), and one O(7) atom to form corner-sharing ZnN3O tetrahedra. The Zn(3)-N(5) bond length is 1.95 Å. Both Zn(3)-N(2) bond lengths are 1.99 Å. The Zn(3)-O(7) bond length is 1.99 Å. There are eighteen inequivalent C sites. In the first C site, C(18) is bonded in a distorted trigonal planar geometry to two equivalent C(7) and one H(16) atom. Both C(18)-C(7) bond lengths are 1.40 Å. The C(18)-H(16) bond length is 0.93 Å. In the second C site, C(19) is bonded in a single-bond geometry to two equivalent C(6) and one H(17) atom. Both C(19)-C(6) bond lengths are 1.39 Å. The C(19)-H(17) bond length is 0.93 Å. In the third C site, C(1) is bonded in a trigonal non-coplanar geometry to one C(2); one H(3); and two equivalent H(1,2) atoms. The C(1)-C(2) bond length is 1.48 Å. The C(1)-H(3) bond length is 0.96 Å. Both C(1)-H(1,2) bond lengths are 0.96 Å. In the fourth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one N(1), and one N(3) atom. The C(2)-N(1) bond length is 1.31 Å. The C(2)-N(3) bond length is 1.34 Å. In the fifth C site, C(3) is bonded in a trigonal planar geometry to one C(4), one N(2), and one N(3) atom. The C(3)-C(4) bond length is 1.48 Å. The C(3)-N(2) bond length is 1.33 Å. The C(3)-N(3) bond length is 1.35 Å. In the sixth C site, C(4) is bonded in a trigonal non-coplanar geometry to one C(3) and three equivalent H(4,5,6) atoms. All C(4)-H(4,5,6) bond lengths are 0.96 Å. In the seventh C site, C(5) is bonded in a bent 120 degrees geometry to one C(6), one O(1), and one O(2) atom. The C(5)-C(6) bond length is 1.48 Å. The C(5)-O(1) bond length is 1.24 Å. The C(5)-O(2) bond length is 1.25 Å. In the eighth C site, C(6) is bonded in a trigonal planar geometry to one C(19), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.37 Å. In the ninth C site, C(7) is bonded in a distorted single-bond geometry to one C(18), one C(6), and one H(7) atom. The C(7)-H(7) bond length is 0.93 Å. In the tenth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.43 Å. The C(9)-C(14) bond length is 1.38 Å. The C(9)-C(8) bond length is 1.54 Å. In the eleventh C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(10)-H(8) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(12)-C(13) bond length is 1.37 Å. The C(12)-H(10) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(15) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-C(15) bond length is 1.49 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(9), and one H(11) atom. The C(14)-H(11) bond length is 0.93 Å. In the fifteenth C site, C(15) is bonded in a bent 120 degrees geometry to one C(13), one O(3), and one O(4) atom. The C(15)-O(3) bond length is 1.26 Å. The C(15)-O(4) bond length is 1.25 Å. In the sixteenth C site, C(16) is bonded in a trigonal non-coplanar geometry to one C(17); one H(12); and two equivalent H(13,14) atoms. The C(16)-C(17) bond length is 1.49 Å. The C(16)-H(12) bond length is 0.96 Å. Both C(16)-H(13,14) bond lengths are 0.96 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(4), and one N(5) atom. The C(17)-N(4) bond length is 1.33 Å. The C(17)-N(5) bond length is 1.33 Å. In the eighteenth C site, C(8) is bonded in a bent 120 degrees geometry to one C(9), one O(5), and one O(6) atom. The C(8)-O(5) bond length is 1.17 Å. The C(8)-O(6) bond length is 1.20 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Zn(1), one C(2), and one N(2) atom. The N(1)-N(2) bond length is 1.38 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Zn(3), one C(3), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(2), and one C(3) atom. In the fourth N site, N(4) is bonded in a 2-coordinate geometry to one Zn(1) and one C(17) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(3) and two equivalent C(17) atoms. There are twelve inequivalent H sites. In the first H site, H(15) is bonded in a single-bond geometry to one O(7) atom. The H(15)-O(7) bond length is 0.90 Å. In the second H site, H(16) is bonded in a single-bond geometry to one C(18) atom. In the third H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(4,5,6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(13,14) is bonded in a single-bond geometry to one C(16) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(5) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(5) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(15) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(15) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Zn(1) and one C(8) atom. In the sixth O site, O(6) is bonded in an L-shaped geometry to one Zn(1) and one C(8) atom. In the seventh O site, O(7) is bonded in a distorted tetrahedral geometry to one Zn(3), two equivalent Zn(1), and one H(15) atom. Linkers: 12 [O]C(=O)c1cccc(C([O])=O)c1 ,8 CC1=NN=C(C)[N]1 ,4 CC1=NC(C)=N[N]1. Metal clusters: 4 O[Zn]1/N=N\[Zn]2(/N=N\[Zn]3(/N=N\1)O[C]O3)O[C]O2 ,4 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 8.06 A, density 0.99 g/cm3, surface area 4012.04 m2/g, accessible volume 0.65 cm3/g