MnC19H23(NO3)2MnC18H22(NO3)2C13H8(CH)3(CF3)6CF2 is Indium-derived structured and crystallizes in the tetragonal P4_32_12 space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules, eight difluoromethane molecules, forty-eight trifluoromethane molecules, eight C13H8 clusters, eight MnC18H22(NO3)2 clusters, and eight MnC19H23(NO3)2 clusters. In each C13H8 cluster, there are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one C(12), one C(2), one C(22), and one C(32) atom. The C(1)-C(12) bond length is 1.54 Å. The C(1)-C(2) bond length is 1.54 Å. The C(1)-C(22) bond length is 1.55 Å. The C(1)-C(32) bond length is 1.56 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.41 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(12) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.36 Å. The C(12)-C(17) bond length is 1.39 Å. In the sixth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(14) atom. The C(13)-H(14) bond length is 0.93 Å. In the seventh C site, C(17) is bonded in a distorted single-bond geometry to one C(12) and one H(17) atom. The C(17)-H(17) bond length is 0.93 Å. In the eighth C site, C(22) is bonded in a trigonal planar geometry to one C(1), one C(23), and one C(27) atom. The C(22)-C(23) bond length is 1.37 Å. The C(22)-C(27) bond length is 1.42 Å. In the ninth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(27) atom. The C(23)-H(27) bond length is 0.93 Å. In the tenth C site, C(27) is bonded in a distorted single-bond geometry to one C(22) and one H(30) atom. The C(27)-H(30) bond length is 0.93 Å. In the eleventh C site, C(32) is bonded in a trigonal planar geometry to one C(1), one C(33), and one C(37) atom. The C(32)-C(33) bond length is 1.40 Å. The C(32)-C(37) bond length is 1.39 Å. In the twelfth C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(40) atom. The C(33)-H(40) bond length is 0.93 Å. In the thirteenth C site, C(37) is bonded in a distorted single-bond geometry to one C(32) and one H(43) atom. The C(37)-H(43) bond length is 0.93 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(27) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(30) is bonded in a single-bond geometry to one C(27) atom. In the seventh H site, H(40) is bonded in a single-bond geometry to one C(33) atom. In the eighth H site, H(43) is bonded in a single-bond geometry to one C(37) atom. In each MnC18H22(NO3)2 cluster, Mn(2) is bonded in an octahedral geometry to one O(10), one O(11), one O(12), one O(2), one O(4), and one O(9) atom. The Mn(2)-O(10) bond length is 2.12 Å. The Mn(2)-O(11) bond length is 2.14 Å. The Mn(2)-O(12) bond length is 2.13 Å. The Mn(2)-O(2) bond length is 2.10 Å. The Mn(2)-O(4) bond length is 2.10 Å. The Mn(2)-O(9) bond length is 2.11 Å. There are eighteen inequivalent C sites. In the first C site, C(52) is bonded in a single-bond geometry to one O(9) atom. The C(52)-O(9) bond length is 1.23 Å. In the second C site, C(54) is bonded in a distorted single-bond geometry to one O(10) atom. The C(54)-O(10) bond length is 1.22 Å. In the third C site, C(57) is bonded in a distorted single-bond geometry to one O(11) atom. The C(57)-O(11) bond length is 1.27 Å. In the fourth C site, C(59) is bonded in a distorted single-bond geometry to one O(12) atom. The C(59)-O(12) bond length is 1.26 Å. In the fifth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(15) atom. The C(14)-C(15) bond length is 1.37 Å. The C(14)-H(15) bond length is 0.93 Å. In the sixth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one N(2) atom. The C(15)-C(16) bond length is 1.37 Å. The C(15)-N(2) bond length is 1.40 Å. In the seventh C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(16) atom. The C(16)-H(16) bond length is 0.93 Å. In the eighth C site, C(18) is bonded in a distorted tetrahedral geometry to one C(19), one C(20), one C(21), and one N(2) atom. The C(18)-C(19) bond length is 1.55 Å. The C(18)-C(20) bond length is 1.55 Å. The C(18)-C(21) bond length is 1.55 Å. The C(18)-N(2) bond length is 1.53 Å. In the ninth C site, C(19) is bonded in a trigonal non-coplanar geometry to one C(18) and three equivalent H(18,19,20,23) atoms. All C(19)-H(18,19,20,23) bond lengths are 0.96 Å. In the tenth C site, C(20) is bonded in a trigonal non-coplanar geometry to one C(18); one H(18,19,20,23); and two equivalent H(21,22) atoms. The C(20)-H(18,19,20,23) bond length is 0.96 Å. Both C(20)-H(21,22) bond lengths are 0.96 Å. In the eleventh C site, C(21) is bonded in a trigonal non-coplanar geometry to one C(18); one H(24); and two equivalent H(25,26) atoms. The C(21)-H(24) bond length is 0.96 Å. Both C(21)-H(25,26) bond lengths are 0.96 Å. In the twelfth C site, C(34) is bonded in a distorted single-bond geometry to one C(35) and one H(41) atom. The C(34)-C(35) bond length is 1.41 Å. The C(34)-H(41) bond length is 0.93 Å. In the thirteenth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(34), one C(36), and one N(4) atom. The C(35)-C(36) bond length is 1.40 Å. The C(35)-N(4) bond length is 1.44 Å. In the fourteenth C site, C(36) is bonded in a single-bond geometry to one C(35) and one H(42) atom. The C(36)-H(42) bond length is 0.93 Å. In the fifteenth C site, C(38) is bonded in a distorted tetrahedral geometry to one C(39), one C(40), one C(41), and one N(4) atom. The C(38)-C(39) bond length is 1.52 Å. The C(38)-C(40) bond length is 1.53 Å. The C(38)-C(41) bond length is 1.48 Å. The C(38)-N(4) bond length is 1.53 Å. In the sixteenth C site, C(39) is bonded in a trigonal non-coplanar geometry to one C(38), one H(44), one H(45), and one H(46) atom. The C(39)-H(44) bond length is 0.96 Å. The C(39)-H(45) bond length is 0.96 Å. The C(39)-H(46) bond length is 0.96 Å. In the seventeenth C site, C(40) is bonded in a trigonal non-coplanar geometry to one C(38) and three equivalent H(47,48,49,50,52) atoms. All C(40)-H(47,48,49,50,52) bond lengths are 0.96 Å. In the eighteenth C site, C(41) is bonded in a trigonal non-coplanar geometry to one C(38); one H(51); and two equivalent H(47,48,49,50,52) atoms. The C(41)-H(51) bond length is 0.96 Å. Both C(41)-H(47,48,49,50,52) bond lengths are 0.96 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one C(15), one C(18), and one O(2) atom. The N(2)-O(2) bond length is 1.29 Å. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(35), one C(38), and one O(4) atom. The N(4)-O(4) bond length is 1.29 Å. There are thirteen inequivalent H sites. In the first H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the second H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the third H site, H(18,19,20,23) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(21,22) is bonded in a single-bond geometry to one C(20) atom. In the fifth H site, H(24) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(25,26) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(41) is bonded in a single-bond geometry to one C(34) atom. In the eighth H site, H(42) is bonded in a single-bond geometry to one C(36) atom. In the ninth H site, H(44) is bonded in a single-bond geometry to one C(39) atom. In the tenth H site, H(45) is bonded in a single-bond geometry to one C(39) atom. In the eleventh H site, H(46) is bonded in a single-bond geometry to one C(39) atom. In the twelfth H site, H(47,48,49,50,52) is bonded in a single-bond geometry to one C(40) atom. In the thirteenth H site, H(51) is bonded in a single-bond geometry to one C(41) atom. There are six inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(2) and one N(2) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(2) and one N(4) atom. In the third O site, O(9) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(52) atom. In the fourth O site, O(10) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(54) atom. In the fifth O site, O(11) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(57) atom. In the sixth O site, O(12) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(59) atom. In each MnC19H23(NO3)2 cluster, Mn(1) is bonded in an octahedral geometry to one O(1), one O(3), one O(5), one O(6), one O(7), and one O(8) atom. The Mn(1)-O(1) bond length is 2.11 Å. The Mn(1)-O(3) bond length is 2.10 Å. The Mn(1)-O(5) bond length is 2.13 Å. The Mn(1)-O(6) bond length is 2.13 Å. The Mn(1)-O(7) bond length is 2.16 Å. The Mn(1)-O(8) bond length is 2.15 Å. There are nineteen inequivalent C sites. In the first C site, C(49) is bonded in a distorted single-bond geometry to one O(8) atom. The C(49)-O(8) bond length is 1.22 Å. In the second C site, C(4) is bonded in a single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2) bond length is 0.93 Å. In the third C site, C(8) is bonded in a distorted tetrahedral geometry to one C(10), one C(11), one C(9), and one N(1) atom. The C(8)-C(10) bond length is 1.58 Å. The C(8)-C(11) bond length is 1.57 Å. The C(8)-C(9) bond length is 1.50 Å. The C(8)-N(1) bond length is 1.51 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.37 Å. The C(5)-N(1) bond length is 1.45 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the sixth C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(8); one H(5); and two equivalent H(6,7) atoms. The C(9)-H(5) bond length is 0.96 Å. Both C(9)-H(6,7) bond lengths are 0.96 Å. In the seventh C site, C(10) is bonded in a trigonal non-coplanar geometry to one C(8); one H(10); one H(8); and one H(9,11,13) atom. The C(10)-H(10) bond length is 0.96 Å. The C(10)-H(8) bond length is 0.96 Å. The C(10)-H(9,11,13) bond length is 0.96 Å. In the eighth C site, C(11) is bonded in a trigonal non-coplanar geometry to one C(8); one H(12); and two equivalent H(9,11,13) atoms. The C(11)-H(12) bond length is 0.96 Å. Both C(11)-H(9,11,13) bond lengths are 0.96 Å. In the ninth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(28) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-H(28) bond length is 0.93 Å. In the tenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one C(26), and one N(3) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-N(3) bond length is 1.41 Å. In the eleventh C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(29) atom. The C(26)-H(29) bond length is 0.93 Å. In the twelfth C site, C(28) is bonded in a distorted tetrahedral geometry to one C(29), one C(30), one C(31), and one N(3) atom. The C(28)-C(29) bond length is 1.57 Å. The C(28)-C(30) bond length is 1.53 Å. The C(28)-C(31) bond length is 1.55 Å. The C(28)-N(3) bond length is 1.56 Å. In the thirteenth C site, C(29) is bonded in a trigonal non-coplanar geometry to one C(28); one H(33,36); and two equivalent H(31,32,37,38,39) atoms. The C(29)-H(33,36) bond length is 0.96 Å. Both C(29)-H(31,32,37,38,39) bond lengths are 0.96 Å. In the fourteenth C site, C(30) is bonded in a trigonal non-coplanar geometry to one C(28); one H(33,36); and two equivalent H(34,35) atoms. The C(30)-H(33,36) bond length is 0.96 Å. Both C(30)-H(34,35) bond lengths are 0.96 Å. In the fifteenth C site, C(31) is bonded in a trigonal non-coplanar geometry to one C(28) and three equivalent H(31,32,37,38,39) atoms. All C(31)-H(31,32,37,38,39) bond lengths are 0.96 Å. In the sixteenth C site, C(43) is bonded in a distorted single-bond geometry to one O(5) atom. The C(43)-O(5) bond length is 1.27 Å. In the seventeenth C site, C(44) is bonded in a distorted single-bond geometry to one C(45) and one H(53) atom. The C(44)-C(45) bond length is 1.36 Å. The C(44)-H(53) bond length is 0.93 Å. In the eighteenth C site, C(45) is bonded in a distorted single-bond geometry to one C(44) and one O(6) atom. The C(45)-O(6) bond length is 1.26 Å. In the nineteenth C site, C(47) is bonded in a distorted single-bond geometry to one O(7) atom. The C(47)-O(7) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(5), one C(8), and one O(1) atom. The N(1)-O(1) bond length is 1.30 Å. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(25), one C(28), and one O(3) atom. The N(3)-O(3) bond length is 1.29 Å. There are fourteen inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(6,7) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(9,11,13) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(28) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(29) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(31,32,37,38,39) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(33,36) is bonded in a single-bond geometry to one C(29) atom. In the thirteenth H site, H(34,35) is bonded in a single-bond geometry to one C(30) atom. In the fourteenth H site, H(53) is bonded in a single-bond geometry to one C(44) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one N(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one N(3) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(43) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(45) atom. In the fifth O site, O(7) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(47) atom. In the sixth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(49) atom. Linkers: 8 CC(C)(C)N([O])c1ccc(C(c2ccc(N([O])C(C)(C)C)cc2)(c2ccc(N([O])C(C)(C)C)cc2)c2ccc(N([O])C(C)(C)C)cc2)cc1. Metal clusters: 16 [Mn]. The MOF has largest included sphere 5.93 A, density 1.20 g/cm3, surface area 4760.59 m2/g, accessible volume 0.38 cm3/g