(Ag3C5H2O3)2CHCF3 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules and four trifluoromethane molecules inside a Ag3C5H2O3 framework. In the Ag3C5H2O3 framework, there are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a bent 150 degrees geometry to one C(1) and one O(1) atom. The Ag(1)-C(1) bond length is 2.15 Å. The Ag(1)-O(1) bond length is 2.23 Å. In the second Ag site, Ag(2) is bonded in a bent 120 degrees geometry to one C(1) and one O(3) atom. The Ag(2)-C(1) bond length is 2.19 Å. The Ag(2)-O(3) bond length is 2.52 Å. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one O(4) atom. The Ag(3)-C(1) bond length is 2.43 Å. The Ag(3)-C(2) bond length is 2.37 Å. The Ag(3)-O(4) bond length is 2.34 Å. In the fourth Ag site, Ag(4) is bonded in a 1-coordinate geometry to one C(1), two equivalent C(2), and one O(3) atom. The Ag(4)-C(1) bond length is 2.70 Å. There is one shorter (2.49 Å) and one longer (2.64 Å) Ag(4)-C(2) bond length. The Ag(4)-O(3) bond length is 2.41 Å. In the fifth Ag site, Ag(5) is bonded in a distorted T-shaped geometry to one C(2), one O(2), and one O(6) atom. The Ag(5)-C(2) bond length is 2.12 Å. The Ag(5)-O(2) bond length is 2.20 Å. The Ag(5)-O(6) bond length is 2.69 Å. In the sixth Ag site, Ag(6) is bonded in a 3-coordinate geometry to one C(1), one C(2), and one O(6) atom. The Ag(6)-C(1) bond length is 2.57 Å. The Ag(6)-C(2) bond length is 2.60 Å. The Ag(6)-O(6) bond length is 2.35 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a 6-coordinate geometry to one Ag(1), one Ag(2), one Ag(3), one Ag(4), one Ag(6), and one C(2) atom. The C(1)-C(2) bond length is 1.24 Å. In the second C site, C(2) is bonded in a 6-coordinate geometry to one Ag(3), one Ag(5), one Ag(6), two equivalent Ag(4), and one C(1) atom. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one O(1) and one O(2) atom. The C(3)-O(1) bond length is 1.23 Å. The C(3)-O(2) bond length is 1.26 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(3), and one O(4) atom. The C(5)-C(6) bond length is 1.51 Å. The C(5)-O(3) bond length is 1.28 Å. The C(5)-O(4) bond length is 1.25 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(5), and one C(7) atom. The C(6)-C(11) bond length is 1.39 Å. The C(6)-C(7) bond length is 1.40 Å. In the sixth C site, C(7) is bonded in a single-bond geometry to one C(6) and one H(1) atom. The C(7)-H(1) bond length is 0.93 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(3) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(3) bond length is 0.93 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(12) bond length is 1.50 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(6), and one H(4) atom. The C(11)-H(4) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(5), and one O(6) atom. The C(12)-O(5) bond length is 1.33 Å. The C(12)-O(6) bond length is 1.24 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one O(5) atom. The H(5)-O(5) bond length is 0.82 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Ag(1) and one C(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ag(5) and one C(3) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Ag(2), one Ag(4), and one C(5) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(3) and one C(5) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one C(12) and one H(5) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Ag(5), one Ag(6), and one C(12) atom. Linkers: 4 [O]C(=O)c1cccc(C(=O)O)c1. Metal clusters: 24 [Ag]. The MOF has largest included sphere 5.22 A, density 2.19 g/cm3, surface area 2050.44 m2/g, accessible volume 0.22 cm3/g