Zn2C24N3H17O7(C3H2)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 2,3-dimethyl-1,3-butadiene molecules and four Zn2C24N3H17O7 clusters. In each Zn2C24N3H17O7 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to one N(1), one H(25), one O(1), one O(2), and one O(3) atom. The Zn(1)-N(1) bond length is 2.05 Å. The Zn(1)-H(25) bond length is 1.83 Å. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(2) bond length is 1.94 Å. The Zn(1)-O(3) bond length is 1.95 Å. In the second Zn site, Zn(2) is bonded in a 5-coordinate geometry to one N(2), one N(3), one H(25), one O(3), and one O(4) atom. The Zn(2)-N(2) bond length is 2.04 Å. The Zn(2)-N(3) bond length is 2.04 Å. The Zn(2)-H(25) bond length is 1.88 Å. The Zn(2)-O(3) bond length is 1.93 Å. The Zn(2)-O(4) bond length is 1.96 Å. There are twenty-four inequivalent C sites. In the first C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(15) atom. The C(24)-N(2) bond length is 1.34 Å. The C(24)-H(15) bond length is 0.95 Å. In the second C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(17) atom. The C(27)-N(2) bond length is 1.34 Å. The C(27)-H(17) bond length is 0.95 Å. In the third C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one H(9) atom. The C(17)-C(15) bond length is 1.41 Å. The C(17)-H(9) bond length is 0.95 Å. In the fourth C site, C(31) is bonded in a 2-coordinate geometry to one N(3) and one H(20,23) atom. The C(31)-N(3) bond length is 1.33 Å. The C(31)-H(20,23) bond length is 0.95 Å. In the fifth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(20), one N(1), and one H(10) atom. The C(18)-C(20) bond length is 1.35 Å. The C(18)-N(1) bond length is 1.35 Å. The C(18)-H(10) bond length is 0.95 Å. In the sixth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(20,23) atom. The C(35)-N(3) bond length is 1.32 Å. The C(35)-H(20,23) bond length is 0.95 Å. In the seventh C site, C(15) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(17) atom. The C(15)-C(12) bond length is 1.48 Å. The C(15)-C(16) bond length is 1.42 Å. In the eighth C site, C(1) is bonded in a bent 120 degrees geometry to one C(6), one O(2), and one O(7) atom. The C(1)-C(6) bond length is 1.50 Å. The C(1)-O(2) bond length is 1.27 Å. The C(1)-O(7) bond length is 1.23 Å. In the ninth C site, C(2) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(5) atom. The C(2)-C(3) bond length is 1.51 Å. The C(2)-C(4) bond length is 1.38 Å. The C(2)-C(5) bond length is 1.40 Å. In the tenth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(5) atom. The C(3)-O(1) bond length is 1.28 Å. The C(3)-O(5) bond length is 1.24 Å. In the eleventh C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(1,2) atom. The C(4)-H(1,2) bond length is 0.95 Å. In the twelfth C site, C(5) is bonded in a distorted single-bond geometry to one C(2) and one H(1,2) atom. The C(5)-H(1,2) bond length is 0.95 Å. In the thirteenth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(8), and one C(9) atom. The C(6)-C(8) bond length is 1.38 Å. The C(6)-C(9) bond length is 1.37 Å. In the fourteenth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(4), and one O(6) atom. The C(7)-C(10) bond length is 1.50 Å. The C(7)-O(4) bond length is 1.27 Å. The C(7)-O(6) bond length is 1.25 Å. In the fifteenth C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(8)-H(3) bond length is 0.95 Å. In the sixteenth C site, C(9) is bonded in a single-bond geometry to one C(6) and one H(4) atom. The C(9)-H(4) bond length is 0.95 Å. In the seventeenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(19), and one C(7) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(19) bond length is 1.40 Å. In the eighteenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(11)-H(5) bond length is 0.95 Å. In the nineteenth C site, C(12) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(20) atom. The C(12)-C(14) bond length is 1.38 Å. The C(12)-C(20) bond length is 1.39 Å. In the twentieth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(1), and one H(6) atom. The C(13)-C(14) bond length is 1.36 Å. The C(13)-N(1) bond length is 1.34 Å. The C(13)-H(6) bond length is 0.95 Å. In the twenty-first C site, C(14) is bonded in a distorted single-bond geometry to one C(12), one C(13), and one H(7) atom. The C(14)-H(7) bond length is 0.95 Å. In the twenty-second C site, C(19) is bonded in a distorted single-bond geometry to one C(10) and one H(11) atom. The C(19)-H(11) bond length is 0.95 Å. In the twenty-third C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(8) atom. The C(16)-H(8) bond length is 0.95 Å. In the twenty-fourth C site, C(20) is bonded in a distorted single-bond geometry to one C(12), one C(18), and one H(12) atom. The C(20)-H(12) bond length is 0.95 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(18) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(24), and one C(27) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(31), and one C(35) atom. There are fifteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(27) atom. In the twelfth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(20,23) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(25) is bonded in a distorted single-bond geometry to one Zn(1), one Zn(2), and one O(3) atom. The H(25)-O(3) bond length is 1.12 Å. In the fifteenth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Zn(1), one Zn(2), and one H(25) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(3) atom. In the fifth O site, O(7) is bonded in a single-bond geometry to one C(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(7) atom. Linkers: 12 [O]C(=O)c1ccc(-c2ccncc2)cc1. Metal clusters: 4 O=[C]O[Zn].[OH].[O][C]=O.[O][C]=O.[Zn]. The MOF has largest included sphere 5.05 A, density 1.40 g/cm3, surface area 4565.37 m2/g, accessible volume 0.29 cm3/g