YAgC13H7(NO4)2CH crystallizes in the monoclinic C2/c space group. The structure consists of eight 02329_fluka molecules inside a YAgC13H7(NO4)2 framework. In the YAgC13H7(NO4)2 framework, Y(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. The Y(1)-O(1) bond length is 2.38 Å. The Y(1)-O(2) bond length is 2.35 Å. The Y(1)-O(3) bond length is 2.38 Å. The Y(1)-O(4) bond length is 2.39 Å. The Y(1)-O(5) bond length is 2.39 Å. The Y(1)-O(6) bond length is 2.40 Å. The Y(1)-O(7) bond length is 2.28 Å. The Y(1)-O(8) bond length is 2.29 Å. Ag(1) is bonded in a distorted T-shaped geometry to one N(1), one N(2), and one O(1) atom. The Ag(1)-N(1) bond length is 2.17 Å. The Ag(1)-N(2) bond length is 2.17 Å. The Ag(1)-O(1) bond length is 2.54 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(1), and one H(8) atom. The C(1)-C(12) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(8) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(2), and one O(7) atom. The C(2)-C(12) bond length is 1.49 Å. The C(2)-O(2) bond length is 1.24 Å. The C(2)-O(7) bond length is 1.25 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(3)-C(9) bond length is 1.38 Å. The C(3)-H(4) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(13), one C(9), and one H(2) atom. The C(4)-C(13) bond length is 1.38 Å. The C(4)-C(9) bond length is 1.39 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(6)-O(1) bond length is 1.28 Å. The C(6)-O(4) bond length is 1.24 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(7)-N(2) bond length is 1.32 Å. The C(7)-H(6) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(5), and one O(8) atom. The C(8)-C(9) bond length is 1.53 Å. The C(8)-O(5) bond length is 1.24 Å. The C(8)-O(8) bond length is 1.25 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(8) atom. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(12) and one H(5) atom. The C(10)-C(12) bond length is 1.39 Å. The C(10)-H(5) bond length is 0.93 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(11)-N(1) bond length is 1.33 Å. The C(11)-H(3) bond length is 0.93 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(2) atom. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one H(1) atom. The C(13)-N(2) bond length is 1.34 Å. The C(13)-H(1) bond length is 0.93 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(6) atom. The C(14)-O(3) bond length is 1.27 Å. The C(14)-O(6) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(11) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(13), and one C(7) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(1) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Y(1), one Ag(1), and one C(6) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Y(1) and one C(2) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one C(14) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one C(6) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Y(1) and one C(8) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one C(14) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one C(2) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one C(8) atom. Linkers: 4 [O]C(=O)C([O])=O ,4 [O]C(=O)c1ccncc1 ,3 [O]C(=O)c1cccnc1. Metal clusters: 4 [Y] ,4 [Ag]. The MOF has largest included sphere 3.90 A, density 2.03 g/cm3, surface area 3076.93 m2/g, accessible volume 0.17 cm3/g