(ZnC10N3H10)2ZnC14N3H14(CH)20 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten isobutylene molecules, four ZnC10N3H10 clusters, and two ZnC14N3H14 clusters. In each ZnC10N3H10 cluster, Zn(1) is bonded in a trigonal non-coplanar geometry to one N(1), one N(2), and one N(3) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-N(2) bond length is 2.06 Å. The Zn(1)-N(3) bond length is 2.03 Å. There are ten inequivalent C sites. In the first C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(16) atom. The C(17)-N(3) bond length is 1.35 Å. The C(17)-H(16) bond length is 0.95 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4,52) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4,52) bond length is 0.95 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(7)-N(2) bond length is 1.34 Å. The C(7)-H(7) bond length is 0.95 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(8) bond length is 0.95 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(8) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(12) bond length is 1.51 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(9) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-H(9) bond length is 0.95 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(2), and one H(10) atom. The C(11)-N(2) bond length is 1.35 Å. The C(11)-H(10) bond length is 0.95 Å. In the ninth C site, C(12) is bonded in a water-like geometry to one C(9) and two equivalent H(11,12) atoms. Both C(12)-H(11,12) bond lengths are 0.99 Å. In the tenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(13) atom. The C(13)-N(3) bond length is 1.35 Å. The C(13)-H(13) bond length is 0.95 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(17) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4,52) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(11,12) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In each ZnC14N3H14 cluster, Zn(2) is bonded in a trigonal non-coplanar geometry to one N(4), one N(5), and one N(7) atom. The Zn(2)-N(4) bond length is 2.00 Å. The Zn(2)-N(5) bond length is 2.06 Å. The Zn(2)-N(7) bond length is 2.04 Å. There are fourteen inequivalent C sites. In the first C site, C(19) is bonded in a distorted trigonal planar geometry to one C(20), one N(4), and one H(19) atom. The C(19)-C(20) bond length is 1.37 Å. The C(19)-N(4) bond length is 1.34 Å. The C(19)-H(19) bond length is 0.95 Å. In the second C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(20) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(20) bond length is 0.95 Å. In the third C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-C(24) bond length is 1.50 Å. In the fourth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(21) atom. The C(22)-C(23) bond length is 1.36 Å. The C(22)-H(21) bond length is 0.95 Å. In the fifth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one N(4), and one H(22) atom. The C(23)-N(4) bond length is 1.35 Å. The C(23)-H(22) bond length is 0.95 Å. In the sixth C site, C(24) is bonded in a water-like geometry to one C(21) and two equivalent H(23,24) atoms. Both C(24)-H(23,24) bond lengths are 0.99 Å. In the seventh C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(25) atom. The C(25)-N(5) bond length is 1.34 Å. The C(25)-H(25) bond length is 0.95 Å. In the eighth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(28) atom. The C(29)-N(5) bond length is 1.34 Å. The C(29)-H(28) bond length is 0.95 Å. In the ninth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(38), one N(7), and one H(37) atom. The C(37)-C(38) bond length is 1.38 Å. The C(37)-N(7) bond length is 1.35 Å. The C(37)-H(37) bond length is 0.95 Å. In the tenth C site, C(38) is bonded in a distorted single-bond geometry to one C(37), one C(39), and one H(38) atom. The C(38)-C(39) bond length is 1.39 Å. The C(38)-H(38) bond length is 0.95 Å. In the eleventh C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one H(39) atom. The C(40)-C(39) bond length is 1.38 Å. The C(40)-H(39) bond length is 0.95 Å. In the twelfth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(40) atom. The C(41)-N(7) bond length is 1.34 Å. The C(41)-H(40) bond length is 0.95 Å. In the thirteenth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(42) atom. The C(39)-C(42) bond length is 1.50 Å. In the fourteenth C site, C(42) is bonded in a water-like geometry to one C(39), one H(41), and one H(42) atom. The C(42)-H(41) bond length is 0.99 Å. The C(42)-H(42) bond length is 0.99 Å. There are three inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Zn(2), one C(19), and one C(23) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Zn(2), one C(25), and one C(29) atom. In the third N site, N(7) is bonded in a trigonal planar geometry to one Zn(2), one C(37), and one C(41) atom. There are thirteen inequivalent H sites. In the first H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the second H site, H(21) is bonded in a single-bond geometry to one C(22) atom. In the third H site, H(22) is bonded in a single-bond geometry to one C(23) atom. In the fourth H site, H(25) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the sixth H site, H(28) is bonded in a single-bond geometry to one C(29) atom. In the seventh H site, H(23,24) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(37) is bonded in a single-bond geometry to one C(37) atom. In the ninth H site, H(38) is bonded in a single-bond geometry to one C(38) atom. In the tenth H site, H(39) is bonded in a single-bond geometry to one C(40) atom. In the eleventh H site, H(40) is bonded in a single-bond geometry to one C(41) atom. In the twelfth H site, H(41) is bonded in a single-bond geometry to one C(42) atom. In the thirteenth H site, H(42) is bonded in a single-bond geometry to one C(42) atom. Linkers: 11 c1cc(CCc2ccncc2)ccn1. Metal clusters: 6 [Zn]. The MOF has largest included sphere 5.14 A, density 0.98 g/cm3, surface area 5421.81 m2/g, accessible volume 0.55 cm3/g