(NaH32(C17O3)2)2Zn3H16(C2O)16 is Marcasite structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four NaH32(C17O3)2 clusters and two Zn3H16(C2O)16 clusters. In each NaH32(C17O3)2 cluster, Na(1) is bonded in a distorted hexagonal planar geometry to one O(10), one O(11), one O(12), one O(13), one O(14), and one O(9) atom. The Na(1)-O(10) bond length is 2.48 Å. The Na(1)-O(11) bond length is 2.49 Å. The Na(1)-O(12) bond length is 2.46 Å. The Na(1)-O(13) bond length is 2.52 Å. The Na(1)-O(14) bond length is 2.46 Å. The Na(1)-O(9) bond length is 2.59 Å. There are thirty-four inequivalent C sites. In the first C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(31), and one C(5) atom. The C(4)-C(3) bond length is 1.39 Å. The C(4)-C(31) bond length is 1.45 Å. The C(4)-C(5) bond length is 1.39 Å. In the second C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(2,3) atom. The C(5)-H(2,3) bond length is 0.94 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2,3) atom. The C(3)-H(2,3) bond length is 0.94 Å. In the fourth C site, C(10) is bonded in a single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(6) bond length is 0.94 Å. In the fifth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(33) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(33) bond length is 1.44 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 0.94 Å. In the seventh C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(10) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(10) bond length is 0.94 Å. In the eighth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(37) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-C(37) bond length is 1.46 Å. In the ninth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(11) atom. The C(19)-H(11) bond length is 0.94 Å. In the tenth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(14,15) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(14,15) bond length is 0.94 Å. In the eleventh C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(39) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-C(39) bond length is 1.44 Å. In the twelfth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(14,15) atom. The C(26)-H(14,15) bond length is 0.94 Å. In the thirteenth C site, C(29) is bonded in a trigonal planar geometry to one C(30), one C(34), and one C(35) atom. The C(29)-C(30) bond length is 1.39 Å. The C(29)-C(34) bond length is 1.39 Å. The C(29)-C(35) bond length is 1.48 Å. In the fourteenth C site, C(30) is bonded in a single-bond geometry to one C(29), one C(31), and one H(17) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-H(17) bond length is 0.94 Å. In the fifteenth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(4) atom. The C(31)-C(32) bond length is 1.39 Å. In the sixteenth C site, C(32) is bonded in a distorted single-bond geometry to one C(31), one C(33), and one H(18) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-H(18) bond length is 0.94 Å. In the seventeenth C site, C(33) is bonded in a trigonal planar geometry to one C(11), one C(32), and one C(34) atom. The C(33)-C(34) bond length is 1.39 Å. In the eighteenth C site, C(34) is bonded in a distorted single-bond geometry to one C(29), one C(33), and one O(9) atom. The C(34)-O(9) bond length is 1.38 Å. In the nineteenth C site, C(35) is bonded in a trigonal planar geometry to one C(29), one C(36), and one C(40) atom. The C(35)-C(36) bond length is 1.39 Å. The C(35)-C(40) bond length is 1.39 Å. In the twentieth C site, C(36) is bonded in a distorted single-bond geometry to one C(35), one C(37), and one O(10) atom. The C(36)-C(37) bond length is 1.39 Å. The C(36)-O(10) bond length is 1.38 Å. In the twenty-first C site, C(37) is bonded in a trigonal planar geometry to one C(18), one C(36), and one C(38) atom. The C(37)-C(38) bond length is 1.39 Å. In the twenty-second C site, C(38) is bonded in a distorted single-bond geometry to one C(37), one C(39), and one H(19) atom. The C(38)-C(39) bond length is 1.39 Å. The C(38)-H(19) bond length is 0.94 Å. In the twenty-third C site, C(39) is bonded in a trigonal planar geometry to one C(25), one C(38), and one C(40) atom. The C(39)-C(40) bond length is 1.39 Å. In the twenty-fourth C site, C(40) is bonded in a distorted single-bond geometry to one C(35), one C(39), and one H(20) atom. The C(40)-H(20) bond length is 0.94 Å. In the twenty-fifth C site, C(41) is bonded in a distorted trigonal non-coplanar geometry to one H(21), one H(22), and one O(9) atom. The C(41)-H(21) bond length is 0.98 Å. The C(41)-H(22) bond length is 0.98 Å. The C(41)-O(9) bond length is 1.44 Å. In the twenty-sixth C site, C(42) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(23,24) and one O(10) atom. Both C(42)-H(23,24) bond lengths are 0.98 Å. The C(42)-O(10) bond length is 1.46 Å. In the twenty-seventh C site, C(43) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(25,26) and one O(11) atom. Both C(43)-H(25,26) bond lengths are 0.98 Å. The C(43)-O(11) bond length is 1.44 Å. In the twenty-eighth C site, C(44) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(27,28) and one O(12) atom. Both C(44)-H(27,28) bond lengths are 0.98 Å. The C(44)-O(12) bond length is 1.41 Å. In the twenty-ninth C site, C(45) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(29,30) and one O(11) atom. Both C(45)-H(29,30) bond lengths are 0.98 Å. The C(45)-O(11) bond length is 1.48 Å. In the thirtieth C site, C(46) is bonded in a distorted trigonal non-coplanar geometry to one H(31), one H(32), and one O(12) atom. The C(46)-H(31) bond length is 0.98 Å. The C(46)-H(32) bond length is 0.99 Å. The C(46)-O(12) bond length is 1.48 Å. In the thirty-first C site, C(47) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(33,34) and one O(13) atom. Both C(47)-H(33,34) bond lengths are 0.98 Å. The C(47)-O(13) bond length is 1.43 Å. In the thirty-second C site, C(48) is bonded in a distorted trigonal non-coplanar geometry to one H(35), one H(36), and one O(14) atom. The C(48)-H(35) bond length is 0.98 Å. The C(48)-H(36) bond length is 0.98 Å. The C(48)-O(14) bond length is 1.47 Å. In the thirty-third C site, C(49) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(37,38) and one O(13) atom. Both C(49)-H(37,38) bond lengths are 0.98 Å. The C(49)-O(13) bond length is 1.46 Å. In the thirty-fourth C site, C(50) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(39,40) and one O(14) atom. Both C(50)-H(39,40) bond lengths are 0.98 Å. The C(50)-O(14) bond length is 1.41 Å. There are twenty-three inequivalent H sites. In the first H site, H(2,3) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(14,15) is bonded in a single-bond geometry to one C(24) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(30) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(32) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(38) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(40) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(41) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(41) atom. In the thirteenth H site, H(23,24) is bonded in a single-bond geometry to one C(42) atom. In the fourteenth H site, H(25,26) is bonded in a single-bond geometry to one C(43) atom. In the fifteenth H site, H(27,28) is bonded in a single-bond geometry to one C(44) atom. In the sixteenth H site, H(29,30) is bonded in a single-bond geometry to one C(45) atom. In the seventeenth H site, H(31) is bonded in a single-bond geometry to one C(46) atom. In the eighteenth H site, H(32) is bonded in a single-bond geometry to one C(46) atom. In the nineteenth H site, H(33,34) is bonded in a single-bond geometry to one C(47) atom. In the twentieth H site, H(35) is bonded in a single-bond geometry to one C(48) atom. In the twenty-first H site, H(36) is bonded in a single-bond geometry to one C(48) atom. In the twenty-second H site, H(37,38) is bonded in a single-bond geometry to one C(49) atom. In the twenty-third H site, H(39,40) is bonded in a single-bond geometry to one C(50) atom. There are six inequivalent O sites. In the first O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Na(1), one C(34), and one C(41) atom. In the second O site, O(10) is bonded in a distorted trigonal planar geometry to one Na(1), one C(36), and one C(42) atom. In the third O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one C(43), and one C(45) atom. In the fourth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Na(1), one C(44), and one C(46) atom. In the fifth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Na(1), one C(47), and one C(49) atom. In the sixth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Na(1), one C(48), and one C(50) atom. In each Zn3H16(C2O)16 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one O(2), one O(4), one O(5), and one O(8) atom. The Zn(1)-O(2) bond length is 1.98 Å. The Zn(1)-O(4) bond length is 2.02 Å. The Zn(1)-O(5) bond length is 1.96 Å. The Zn(1)-O(8) bond length is 1.96 Å. In the second Zn site, Zn(2) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(7) atoms. Both Zn(2)-O(1) bond lengths are 2.05 Å. Both Zn(2)-O(3) bond lengths are 2.07 Å. Both Zn(2)-O(7) bond lengths are 2.09 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-C(7) bond length is 1.40 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1,4) atom. The C(2)-H(1,4) bond length is 0.94 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(1,4) atom. The C(6)-H(1,4) bond length is 0.94 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.37 Å. The C(7)-O(2) bond length is 1.36 Å. In the fifth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(9) atom. The C(8)-C(13) bond length is 1.39 Å. The C(8)-C(14) bond length is 1.38 Å. The C(8)-C(9) bond length is 1.39 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5,8) atom. The C(9)-H(5,8) bond length is 0.94 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(5,8) atom. The C(13)-H(5,8) bond length is 0.94 Å. In the eighth C site, C(14) is bonded in a distorted water-like geometry to one C(8), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.37 Å. The C(14)-O(4) bond length is 1.36 Å. In the ninth C site, C(15) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(28) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-C(20) bond length is 1.39 Å. The C(15)-C(28) bond length is 1.39 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(9,12) atom. The C(16)-H(9,12) bond length is 0.94 Å. In the eleventh C site, C(20) is bonded in a distorted single-bond geometry to one C(15) and one H(9,12) atom. The C(20)-H(9,12) bond length is 0.94 Å. In the twelfth C site, C(21) is bonded in a distorted water-like geometry to one C(22), one O(5), and one O(6) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-O(5) bond length is 1.35 Å. The C(21)-O(6) bond length is 1.37 Å. In the thirteenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(27) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-C(27) bond length is 1.39 Å. In the fourteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(13,16) atom. The C(23)-H(13,16) bond length is 0.94 Å. In the fifteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(22) and one H(13,16) atom. The C(27)-H(13,16) bond length is 0.94 Å. In the sixteenth C site, C(28) is bonded in a distorted water-like geometry to one C(15), one O(7), and one O(8) atom. The C(28)-O(7) bond length is 1.36 Å. The C(28)-O(8) bond length is 1.34 Å. There are four inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(5,8) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(9,12) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(13,16) is bonded in a single-bond geometry to one C(23) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(14) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(21) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(21) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(28) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(28) atom. Linkers: 4 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)c3c(c2)-c2cc(-c4ccc(C([O])=O)cc4)cc(-c4ccc(C([O])=O)cc4)c2OCCOCCOCCOCCOCCO3)cc1. Metal clusters: 4 [Na] ,6 [Zn]. The MOF has largest included sphere 7.42 A, density 0.93 g/cm3, surface area 4626.53 m2/g, accessible volume 0.64 cm3/g