CoC20H12(NO)4CoC14H9(NO2)2(CH)8C9H8O4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules; two 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; two CoC14H9(NO2)2 clusters; and one CoC20H12(NO)4 cluster. In each CoC14H9(NO2)2 cluster, Co(2) is bonded in a distorted rectangular see-saw-like geometry to one N(6), one O(10), one O(11), and one O(12) atom. The Co(2)-N(6) bond length is 2.08 Å. The Co(2)-O(10) bond length is 2.18 Å. The Co(2)-O(11) bond length is 2.15 Å. The Co(2)-O(12) bond length is 1.94 Å. There are fourteen inequivalent C sites. In the first C site, C(51) is bonded in a distorted single-bond geometry to one C(37) and one H(37) atom. The C(51)-C(37) bond length is 1.38 Å. The C(51)-H(37) bond length is 0.93 Å. In the second C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(11) bond length is 0.93 Å. In the third C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.49 Å. The C(12)-C(14) bond length is 1.40 Å. In the fourth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(12), and one O(5) atom. The C(13)-O(12) bond length is 1.27 Å. The C(13)-O(5) bond length is 1.25 Å. In the fifth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(12) atom. The C(14)-H(12) bond length is 0.93 Å. In the sixth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(10), and one O(11) atom. The C(34)-C(35) bond length is 1.54 Å. The C(34)-O(10) bond length is 1.20 Å. The C(34)-O(11) bond length is 1.25 Å. In the seventh C site, C(35) is bonded in a trigonal planar geometry to one C(34), one C(36), and one C(47) atom. The C(35)-C(36) bond length is 1.47 Å. The C(35)-C(47) bond length is 1.31 Å. In the eighth C site, C(36) is bonded in a distorted single-bond geometry to one C(35) and one H(26) atom. The C(36)-H(26) bond length is 0.93 Å. In the ninth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(44), one C(51), and one N(5) atom. The C(37)-C(44) bond length is 1.37 Å. The C(37)-N(5) bond length is 1.41 Å. In the tenth C site, C(44) is bonded in a distorted single-bond geometry to one C(37) and one H(30) atom. The C(44)-H(30) bond length is 0.93 Å. In the eleventh C site, C(47) is bonded in a distorted single-bond geometry to one C(35) and one H(33) atom. The C(47)-H(33) bond length is 0.93 Å. In the twelfth C site, C(48) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(34) atom. The C(48)-N(5) bond length is 1.28 Å. The C(48)-N(6) bond length is 1.29 Å. The C(48)-H(34) bond length is 0.93 Å. In the thirteenth C site, C(49) is bonded in a 3-coordinate geometry to one C(50), one N(6), and one H(35) atom. The C(49)-C(50) bond length is 1.35 Å. The C(49)-N(6) bond length is 1.32 Å. The C(49)-H(35) bond length is 0.93 Å. In the fourteenth C site, C(50) is bonded in a 3-coordinate geometry to one C(49), one N(5), and one H(36) atom. The C(50)-N(5) bond length is 1.43 Å. The C(50)-H(36) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one C(37), one C(48), and one C(50) atom. In the second N site, N(6) is bonded in a distorted trigonal planar geometry to one Co(2), one C(48), and one C(49) atom. There are nine inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(26) is bonded in a single-bond geometry to one C(36) atom. In the fourth H site, H(30) is bonded in a single-bond geometry to one C(44) atom. In the fifth H site, H(33) is bonded in a single-bond geometry to one C(47) atom. In the sixth H site, H(34) is bonded in a single-bond geometry to one C(48) atom. In the seventh H site, H(35) is bonded in a single-bond geometry to one C(49) atom. In the eighth H site, H(36) is bonded in a single-bond geometry to one C(50) atom. In the ninth H site, H(37) is bonded in a single-bond geometry to one C(51) atom. There are four inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one C(13) atom. In the second O site, O(10) is bonded in an L-shaped geometry to one Co(2) and one C(34) atom. In the third O site, O(11) is bonded in an L-shaped geometry to one Co(2) and one C(34) atom. In the fourth O site, O(12) is bonded in a bent 120 degrees geometry to one Co(2) and one C(13) atom. In the CoC20H12(NO)4 cluster, Co(1) is bonded in a 6-coordinate geometry to one N(1), one N(4), one O(6), one O(7), one O(8), and one O(9) atom. The Co(1)-N(1) bond length is 2.07 Å. The Co(1)-N(4) bond length is 2.04 Å. The Co(1)-O(6) bond length is 2.05 Å. The Co(1)-O(7) bond length is 2.42 Å. The Co(1)-O(8) bond length is 1.99 Å. The Co(1)-O(9) bond length is 2.56 Å. There are twenty inequivalent C sites. In the first C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(15) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(15) bond length is 0.93 Å. In the second C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(22) atom. The C(19)-C(20) bond length is 1.38 Å. The C(19)-C(22) bond length is 1.50 Å. In the third C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(16) atom. The C(20)-H(16) bond length is 0.93 Å. In the fourth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(6), and one O(7) atom. The C(22)-O(6) bond length is 1.29 Å. The C(22)-O(7) bond length is 1.24 Å. In the fifth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(25), one N(1), and one H(18) atom. The C(23)-C(25) bond length is 1.35 Å. The C(23)-N(1) bond length is 1.38 Å. The C(23)-H(18) bond length is 0.93 Å. In the sixth C site, C(24) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(19) atom. The C(24)-N(1) bond length is 1.34 Å. The C(24)-N(2) bond length is 1.35 Å. The C(24)-H(19) bond length is 0.93 Å. In the seventh C site, C(25) is bonded in a 3-coordinate geometry to one C(23), one N(2), and one H(20) atom. The C(25)-N(2) bond length is 1.36 Å. The C(25)-H(20) bond length is 0.93 Å. In the eighth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(27), one C(28), and one N(2) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-C(28) bond length is 1.37 Å. The C(26)-N(2) bond length is 1.45 Å. In the ninth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(21) atom. The C(27)-H(21) bond length is 0.93 Å. In the tenth C site, C(28) is bonded in a single-bond geometry to one C(26) and one H(22) atom. The C(28)-H(22) bond length is 0.93 Å. In the eleventh C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(8), and one O(9) atom. The C(29)-C(30) bond length is 1.51 Å. The C(29)-O(8) bond length is 1.28 Å. The C(29)-O(9) bond length is 1.24 Å. In the twelfth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(32) atom. The C(30)-C(31) bond length is 1.35 Å. The C(30)-C(32) bond length is 1.39 Å. In the thirteenth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(23) atom. The C(31)-H(23) bond length is 0.93 Å. In the fourteenth C site, C(32) is bonded in a distorted single-bond geometry to one C(30) and one H(24) atom. The C(32)-H(24) bond length is 0.93 Å. In the fifteenth C site, C(38) is bonded in a bent 120 degrees geometry to one C(39) and one C(40) atom. The C(38)-C(39) bond length is 1.38 Å. The C(38)-C(40) bond length is 1.38 Å. In the sixteenth C site, C(39) is bonded in a bent 120 degrees geometry to one C(38) and one C(40) atom. The C(39)-C(40) bond length is 1.39 Å. In the seventeenth C site, C(40) is bonded in a distorted trigonal planar geometry to one C(38), one C(39), and one N(3) atom. The C(40)-N(3) bond length is 1.45 Å. In the eighteenth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(42), one N(4), and one H(27) atom. The C(41)-C(42) bond length is 1.32 Å. The C(41)-N(4) bond length is 1.38 Å. The C(41)-H(27) bond length is 0.93 Å. In the nineteenth C site, C(42) is bonded in a 3-coordinate geometry to one C(41), one N(3), and one H(28) atom. The C(42)-N(3) bond length is 1.35 Å. The C(42)-H(28) bond length is 0.93 Å. In the twentieth C site, C(43) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(29) atom. The C(43)-N(3) bond length is 1.34 Å. The C(43)-N(4) bond length is 1.32 Å. The C(43)-H(29) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(23), and one C(24) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(24), one C(25), and one C(26) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(40), one C(42), and one C(43) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(41), and one C(43) atom. There are twelve inequivalent H sites. In the first H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the second H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the third H site, H(18) is bonded in a single-bond geometry to one C(23) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(24) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the sixth H site, H(21) is bonded in a single-bond geometry to one C(27) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one C(28) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the ninth H site, H(24) is bonded in a single-bond geometry to one C(32) atom. In the tenth H site, H(27) is bonded in a single-bond geometry to one C(41) atom. In the eleventh H site, H(28) is bonded in a single-bond geometry to one C(42) atom. In the twelfth H site, H(29) is bonded in a single-bond geometry to one C(43) atom. There are four inequivalent O sites. In the first O site, O(6) is bonded in a distorted water-like geometry to one Co(1) and one C(22) atom. In the second O site, O(7) is bonded in a distorted single-bond geometry to one Co(1) and one C(22) atom. In the third O site, O(8) is bonded in a water-like geometry to one Co(1) and one C(29) atom. In the fourth O site, O(9) is bonded in a single-bond geometry to one Co(1) and one C(29) atom. Linkers: 1 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,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=C[C]C([O])=O.[CH]O[C]=[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/C=C\[C][O].[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]C(=[CH])[O].[C]C(=[C])N1[CH]N([Co@]([N])([O])OC(=O)c2ccc(O[CH2])cc2)C=C1.[Co].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[O].[O].[O].[O].[O].[O].[O].[O][C]=O ,1 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,1 O=[C]O[Co].[CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]/[C]=[C]/[C]=O.[CH]=C[C](/C=C\[C][O])C([O])=O.[CH][C]=[CH].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#[C].[C]/C=C\[C][O].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]O[CH].[C]O[C]=[CH].[C][CH].[C][CH].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C]=[C].[C][C]=[C].[C][N].[C][N]C=[C].[C][N][C][N].[C][O].[C][O].[C][O].[Co].[Co].[Co].[Co].[Co].[Co].[Co].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N]C=[N].[N][Co]([O])[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][Co] ,1 [CH2].[CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=C[C]/C=C\[C][O].[CH][N].[CH][N][CH]/C=N/[C]=[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]/C=[C]\[CH].[C]=C[N].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[CH].[C]=[CH].[C]N([C])C=[C].[C][CH].[C][C].[C][C].[C][C].[C][C].[C][C]=[CH].[C][C]N([C])[Co]OC(=O)c1ccc(OC[C@@]([C])(C[O])COc2ccc([C]=O)cc2)cc1.[C][O].[C][O].[C][O].[Co].[Co].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N]C=[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][Co] ,1 [CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=[C][O].[C]C(=[C])N1[CH]N([Co]([N])OC(=O)c2ccc(O[CH2])cc2)C=C1.[C][CH].[C][C].[C][C]=[C].[C][C]C([O])=O.[C][O].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O] ,1 c1cn(-c2ccc(-n3ccnc3)cc2)cn1. Metal clusters: 2 O=[C]O[Co]1O[C]O1. The MOF has largest included sphere 4.11 A, density 1.36 g/cm3, surface area 4689.20 m2/g, accessible volume 0.23 cm3/g