FeC10H8(N3S)2(CH)8C9H8O4 is Indium-derived structured and crystallizes in the orthorhombic Cccm space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules; four 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and four FeC10H8(N3S)2 clusters. In each FeC10H8(N3S)2 cluster, Fe(1) is bonded in an octahedral geometry to two equivalent N(2) and four equivalent N(1) atoms. Both Fe(1)-N(2) bond lengths are 2.12 Å. All Fe(1)-N(1) bond lengths are 2.22 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.93 Å. In the third C site, C(7) is bonded in a single-bond geometry to one N(2) and one S(1) atom. The C(7)-N(2) bond length is 1.15 Å. The C(7)-S(1) bond length is 1.63 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a linear geometry to one Fe(1) and one C(7) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Fe(1), one C(1), and one C(5) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. S(1) is bonded in a single-bond geometry to one C(7) atom. Linkers: 3 c1cc(OCC(COc2ccncc2)(COc2ccncc2)COc2ccncc2)ccn1. Metal clusters: 2 [Fe]. The MOF has largest included sphere 5.52 A, density 0.83 g/cm3, surface area 5003.34 m2/g, accessible volume 0.74 cm3/g