AgH16(C3S2)2 crystallizes in the monoclinic C2 space group. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a tetrahedral geometry to one S(10), one S(2), one S(5), and one S(9) atom. The Ag(1)-S(10) bond length is 2.53 Å. The Ag(1)-S(2) bond length is 2.66 Å. The Ag(1)-S(5) bond length is 2.62 Å. The Ag(1)-S(9) bond length is 2.56 Å. In the second Ag site, Ag(2) is bonded in a tetrahedral geometry to one S(11), one S(12), one S(3), and one S(8) atom. The Ag(2)-S(11) bond length is 2.70 Å. The Ag(2)-S(12) bond length is 2.53 Å. The Ag(2)-S(3) bond length is 2.59 Å. The Ag(2)-S(8) bond length is 2.53 Å. In the third Ag site, Ag(3) is bonded in a tetrahedral geometry to one S(1), one S(4), one S(6), and one S(7) atom. The Ag(3)-S(1) bond length is 2.56 Å. The Ag(3)-S(4) bond length is 2.57 Å. The Ag(3)-S(6) bond length is 2.56 Å. The Ag(3)-S(7) bond length is 2.60 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a water-like geometry to one H(2), one H(3), one S(2), and one S(3) atom. The C(1)-H(2) bond length is 0.99 Å. The C(1)-H(3) bond length is 0.99 Å. The C(1)-S(2) bond length is 1.80 Å. The C(1)-S(3) bond length is 1.80 Å. In the second C site, C(2) is bonded in a trigonal non-coplanar geometry to one H(6); two equivalent H(4,5); and one S(10) atom. The C(2)-H(6) bond length is 0.98 Å. Both C(2)-H(4,5) bond lengths are 0.98 Å. The C(2)-S(10) bond length is 1.81 Å. In the third C site, C(3) is bonded in a trigonal non-coplanar geometry to one H(7), one H(8), one H(9), and one S(7) atom. The C(3)-H(7) bond length is 0.98 Å. The C(3)-H(8) bond length is 0.98 Å. The C(3)-H(9) bond length is 0.98 Å. The C(3)-S(7) bond length is 1.81 Å. In the fourth C site, C(4) is bonded in a trigonal non-coplanar geometry to one H(10), one H(11), one H(12), and one S(1) atom. The C(4)-H(10) bond length is 0.98 Å. The C(4)-H(11) bond length is 0.98 Å. The C(4)-H(12) bond length is 0.98 Å. The C(4)-S(1) bond length is 1.81 Å. In the fifth C site, C(5) is bonded in a trigonal non-coplanar geometry to one H(15); two equivalent H(13,14); and one S(2) atom. The C(5)-H(15) bond length is 0.98 Å. Both C(5)-H(13,14) bond lengths are 0.98 Å. The C(5)-S(2) bond length is 1.81 Å. In the sixth C site, C(6) is bonded in a trigonal non-coplanar geometry to one H(16), one H(17), one H(18), and one S(9) atom. The C(6)-H(16) bond length is 0.98 Å. The C(6)-H(17) bond length is 0.98 Å. The C(6)-H(18) bond length is 0.98 Å. The C(6)-S(9) bond length is 1.81 Å. In the seventh C site, C(7) is bonded in a water-like geometry to one H(19), one H(20), one S(12), and one S(6) atom. The C(7)-H(19) bond length is 0.99 Å. The C(7)-H(20) bond length is 0.99 Å. The C(7)-S(12) bond length is 1.80 Å. The C(7)-S(6) bond length is 1.81 Å. In the eighth C site, C(8) is bonded in a water-like geometry to two equivalent H(21,22); one S(5); and one S(8) atom. Both C(8)-H(21,22) bond lengths are 0.99 Å. The C(8)-S(5) bond length is 1.83 Å. The C(8)-S(8) bond length is 1.80 Å. In the ninth C site, C(9) is bonded in a water-like geometry to two equivalent H(24,25); one S(10); and one S(11) atom. Both C(9)-H(24,25) bond lengths are 0.99 Å. The C(9)-S(10) bond length is 1.81 Å. The C(9)-S(11) bond length is 1.82 Å. In the tenth C site, C(10) is bonded in a trigonal non-coplanar geometry to one H(27); two equivalent H(26,28); and one S(5) atom. The C(10)-H(27) bond length is 0.98 Å. Both C(10)-H(26,28) bond lengths are 0.98 Å. The C(10)-S(5) bond length is 1.81 Å. In the eleventh C site, C(11) is bonded in a trigonal non-coplanar geometry to three equivalent H(29,30,31) and one S(11) atom. All C(11)-H(29,30,31) bond lengths are 0.98 Å. The C(11)-S(11) bond length is 1.81 Å. In the twelfth C site, C(12) is bonded in a trigonal non-coplanar geometry to three equivalent H(32,33,34) and one S(12) atom. All C(12)-H(32,33,34) bond lengths are 0.98 Å. The C(12)-S(12) bond length is 1.81 Å. In the thirteenth C site, C(13) is bonded in a water-like geometry to one H(35), one H(36), one S(4), and one S(7) atom. The C(13)-H(35) bond length is 0.99 Å. The C(13)-H(36) bond length is 0.99 Å. The C(13)-S(4) bond length is 1.82 Å. The C(13)-S(7) bond length is 1.80 Å. In the fourteenth C site, C(14) is bonded in a trigonal non-coplanar geometry to one H(37), one H(38), one H(39), and one S(6) atom. The C(14)-H(37) bond length is 0.98 Å. The C(14)-H(38) bond length is 0.98 Å. The C(14)-H(39) bond length is 0.98 Å. The C(14)-S(6) bond length is 1.81 Å. In the fifteenth C site, C(15) is bonded in a trigonal non-coplanar geometry to one H(41); two equivalent H(40,42); and one S(3) atom. The C(15)-H(41) bond length is 0.98 Å. Both C(15)-H(40,42) bond lengths are 0.98 Å. The C(15)-S(3) bond length is 1.81 Å. In the sixteenth C site, C(16) is bonded in a trigonal non-coplanar geometry to three equivalent H(43,44,45) and one S(4) atom. All C(16)-H(43,44,45) bond lengths are 0.98 Å. The C(16)-S(4) bond length is 1.81 Å. In the seventeenth C site, C(17) is bonded in a trigonal non-coplanar geometry to one H(48); two equivalent H(46,47); and one S(8) atom. The C(17)-H(48) bond length is 0.98 Å. Both C(17)-H(46,47) bond lengths are 0.98 Å. The C(17)-S(8) bond length is 1.80 Å. In the eighteenth C site, C(18) is bonded in a water-like geometry to two equivalent H(1) and two equivalent S(1) atoms. Both C(18)-H(1) bond lengths are 0.99 Å. Both C(18)-S(1) bond lengths are 1.81 Å. In the nineteenth C site, C(19) is bonded in a water-like geometry to two equivalent H(23) and two equivalent S(9) atoms. Both C(19)-H(23) bond lengths are 0.99 Å. Both C(19)-S(9) bond lengths are 1.81 Å. There are thirty-five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(18) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4,5) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(3) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(4) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(4) atom. In the twelfth H site, H(13,14) is bonded in a single-bond geometry to one C(5) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(5) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(6) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(6) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(6) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(7) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(7) atom. In the nineteenth H site, H(21,22) is bonded in a single-bond geometry to one C(8) atom. In the twentieth H site, H(23) is bonded in a single-bond geometry to one C(19) atom. In the twenty-first H site, H(24,25) is bonded in a single-bond geometry to one C(9) atom. In the twenty-second H site, H(26,28) is bonded in a single-bond geometry to one C(10) atom. In the twenty-third H site, H(27) is bonded in a single-bond geometry to one C(10) atom. In the twenty-fourth H site, H(29,30,31) is bonded in a single-bond geometry to one C(11) atom. In the twenty-fifth H site, H(32,33,34) is bonded in a single-bond geometry to one C(12) atom. In the twenty-sixth H site, H(35) is bonded in a single-bond geometry to one C(13) atom. In the twenty-seventh H site, H(36) is bonded in a single-bond geometry to one C(13) atom. In the twenty-eighth H site, H(37) is bonded in a single-bond geometry to one C(14) atom. In the twenty-ninth H site, H(38) is bonded in a single-bond geometry to one C(14) atom. In the thirtieth H site, H(39) is bonded in a single-bond geometry to one C(14) atom. In the thirty-first H site, H(40,42) is bonded in a single-bond geometry to one C(15) atom. In the thirty-second H site, H(41) is bonded in a single-bond geometry to one C(15) atom. In the thirty-third H site, H(43,44,45) is bonded in a single-bond geometry to one C(16) atom. In the thirty-fourth H site, H(46,47) is bonded in a single-bond geometry to one C(17) atom. In the thirty-fifth H site, H(48) is bonded in a single-bond geometry to one C(17) atom. There are twelve inequivalent S sites. In the first S site, S(10) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(2), and one C(9) atom. In the second S site, S(6) is bonded in a trigonal non-coplanar geometry to one Ag(3), one C(14), and one C(7) atom. In the third S site, S(7) is bonded in a trigonal non-coplanar geometry to one Ag(3), one C(13), and one C(3) atom. In the fourth S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(3), one C(18), and one C(4) atom. In the fifth S site, S(5) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(10), and one C(8) atom. In the sixth S site, S(8) is bonded in a trigonal non-coplanar geometry to one Ag(2), one C(17), and one C(8) atom. In the seventh S site, S(11) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one C(11), and one C(9) atom. In the eighth S site, S(12) is bonded in a trigonal non-coplanar geometry to one Ag(2), one C(12), and one C(7) atom. In the ninth S site, S(9) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(19), and one C(6) atom. In the tenth S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one C(1), and one C(5) atom. In the eleventh S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(2), one C(1), and one C(15) atom. In the twelfth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Ag(3), one C(13), and one C(16) atom. Linkers: 24 CSCSC. Metal clusters: 12 [Ag]. The MOF has largest included sphere 4.92 A, density 1.35 g/cm3, surface area 4477.99 m2/g, accessible volume 0.27 cm3/g