In3C38N4H24O15(CH)8(C7H5(N2O)2)2 is Indium-derived structured and crystallizes in the trigonal P3_121 space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules, six C7H5(N2O)2 clusters, and three In3C38N4H24O15 clusters. In each C7H5(N2O)2 cluster, there are seven inequivalent C sites. In the first C site, C(5) is bonded in a single-bond geometry to one N(1) atom. The C(5)-N(1) bond length is 1.41 Å. In the second C site, C(8) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(8) atom. The C(8)-N(1) bond length is 1.37 Å. The C(8)-N(2) bond length is 1.38 Å. The C(8)-O(8) bond length is 1.22 Å. In the third C site, C(9) is bonded in a single-bond geometry to one C(14) and one N(2) atom. The C(9)-C(14) bond length is 1.39 Å. The C(9)-N(2) bond length is 1.38 Å. In the fourth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one N(5) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-N(5) bond length is 1.40 Å. In the fifth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one H(13) atom. The C(14)-H(13) bond length is 0.93 Å. In the sixth C site, C(23) is bonded in a trigonal planar geometry to one N(5), one N(6), and one O(9) atom. The C(23)-N(5) bond length is 1.36 Å. The C(23)-N(6) bond length is 1.36 Å. The C(23)-O(9) bond length is 1.24 Å. In the seventh C site, C(24) is bonded in a single-bond geometry to one N(6) atom. The C(24)-N(6) bond length is 1.41 Å. There are four inequivalent N sites. In the first N site, N(6) is bonded in a trigonal planar geometry to one C(23), one C(24), and one H(6) atom. The N(6)-H(6) bond length is 0.86 Å. In the second N site, N(1) is bonded in a trigonal planar geometry to one C(5), one C(8), and one H(1) atom. The N(1)-H(1) bond length is 0.86 Å. In the third N site, N(2) is bonded in a trigonal planar geometry to one C(8), one C(9), and one H(2) atom. The N(2)-H(2) bond length is 0.86 Å. In the fourth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(13), one C(23), and one H(5) atom. The N(5)-H(5) bond length is 0.86 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one N(5) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one N(6) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. There are two inequivalent O sites. In the first O site, O(8) is bonded in a single-bond geometry to one C(8) atom. In the second O site, O(9) is bonded in a single-bond geometry to one C(23) atom. In each In3C38N4H24O15 cluster, there are two inequivalent In sites. In the first In site, In(1) is bonded to one O(1), one O(10), one O(3), one O(4), and one O(6) atom to form corner-sharing InO5 square pyramids. The In(1)-O(1) bond length is 2.15 Å. The In(1)-O(10) bond length is 1.98 Å. The In(1)-O(3) bond length is 2.14 Å. The In(1)-O(4) bond length is 2.10 Å. The In(1)-O(6) bond length is 2.16 Å. In the second In site, In(2) is bonded to one O(10), two equivalent O(2), and two equivalent O(5) atoms to form corner-sharing InO5 square pyramids. The In(2)-O(10) bond length is 2.13 Å. Both In(2)-O(2) bond lengths are 2.18 Å. Both In(2)-O(5) bond lengths are 2.19 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(7) bond length is 1.37 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(7) atom. The C(3)-H(7) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(10) atom. The C(7)-H(10) bond length is 0.93 Å. In the fifth C site, C(10) is bonded in a single-bond geometry to one C(11) and one H(11) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-H(11) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(4) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(4) bond length is 1.43 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(12) atom. The C(12)-H(12) bond length is 0.93 Å. In the eighth C site, C(15) is bonded in a distorted trigonal planar geometry to one N(3), one N(4), and one O(7) atom. The C(15)-N(3) bond length is 1.38 Å. The C(15)-N(4) bond length is 1.41 Å. The C(15)-O(7) bond length is 1.21 Å. In the ninth C site, C(16) is bonded in a single-bond geometry to one C(17), one C(21), and one N(3) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-C(21) bond length is 1.43 Å. The C(16)-N(3) bond length is 1.38 Å. In the tenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(14) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-H(14) bond length is 0.93 Å. In the eleventh C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(15) atom. The C(18)-C(19) bond length is 1.34 Å. The C(18)-H(15) bond length is 0.93 Å. In the twelfth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(22) atom. The C(19)-C(20) bond length is 1.43 Å. The C(19)-C(22) bond length is 1.49 Å. In the thirteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(16) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(16) bond length is 0.93 Å. In the fourteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(16), one C(20), and one H(17) atom. The C(21)-H(17) bond length is 0.93 Å. In the fifteenth C site, C(22) is bonded in a bent 120 degrees geometry to one C(19), one O(3), and one O(4) atom. The C(22)-O(3) bond length is 1.29 Å. The C(22)-O(4) bond length is 1.25 Å. In the sixteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(27) and one H(19) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-H(19) bond length is 0.93 Å. In the seventeenth C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(30) atom. The C(27)-C(28) bond length is 1.36 Å. The C(27)-C(30) bond length is 1.50 Å. In the eighteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(27) and one H(20) atom. The C(28)-H(20) bond length is 0.93 Å. In the nineteenth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(5), and one O(6) atom. The C(30)-O(5) bond length is 1.24 Å. The C(30)-O(6) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one C(15), one C(16), and one H(3) atom. The N(3)-H(3) bond length is 0.86 Å. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(11), one C(15), and one H(4) atom. The N(4)-H(4) bond length is 0.86 Å. There are twelve inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(26) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(28) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one In(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one In(2) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one In(1) and one C(22) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one In(1) and one C(22) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one In(2) and one C(30) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one In(1) and one C(30) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth O site, O(10) is bonded in a trigonal planar geometry to one In(2) and two equivalent In(1) atoms. Linkers: 6 [O]C(=O)c1ccc(NC(=O)Nc2cc(NC(=O)Nc3ccc(C([O])=O)cc3)cc(NC(=O)Nc3ccc(C([O])=O)cc3)c2)cc1. Metal clusters: 3 O=[C]O[In]O[C]=O.[C]1O[In]2O[C]O[In](O1)O2.[O][C]=O.[O][C]=O. The MOF has largest included sphere 19.87 A, density 0.27 g/cm3, surface area 4175.29 m2/g, accessible volume 2.99 cm3/g