MnC42H30(NF)12 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four MnC42H30(NF)12 clusters. Mn(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(4), and two equivalent N(5) atoms. Both Mn(1)-N(1) bond lengths are 2.28 Å. Both Mn(1)-N(4) bond lengths are 2.24 Å. Both Mn(1)-N(5) bond lengths are 2.28 Å. There are twenty-one inequivalent C sites. In the first C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(6) atom. The C(5)-C(10) bond length is 1.38 Å. The C(5)-C(4) bond length is 1.52 Å. The C(5)-C(6) bond length is 1.36 Å. In the second C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one F(6) atom. The C(6)-F(6) bond length is 1.35 Å. In the third C site, C(7) is bonded in a single-bond geometry to one C(8) and one F(5) atom. The C(7)-C(8) bond length is 1.42 Å. The C(7)-F(5) bond length is 1.33 Å. In the fourth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(5), and one H(11) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-N(5) bond length is 1.34 Å. The C(15)-H(11) bond length is 0.93 Å. In the fifth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(6), and one H(12) atom. The C(16)-N(6) bond length is 1.36 Å. The C(16)-H(12) bond length is 0.93 Å. In the sixth C site, C(17) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(13) atom. The C(17)-N(5) bond length is 1.32 Å. The C(17)-N(6) bond length is 1.32 Å. The C(17)-H(13) bond length is 0.93 Å. In the seventh C site, C(18) is bonded in a 3-coordinate geometry to one C(19); one N(6); and two equivalent H(14,15) atoms. The C(18)-C(19) bond length is 1.53 Å. The C(18)-N(6) bond length is 1.46 Å. Both C(18)-H(14,15) bond lengths are 0.97 Å. In the eighth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(21) atom. The C(19)-C(20) bond length is 1.35 Å. The C(19)-C(21) bond length is 1.36 Å. In the ninth C site, C(20) is bonded in a single-bond geometry to one C(19) and one F(1) atom. The C(20)-F(1) bond length is 1.34 Å. In the tenth C site, C(21) is bonded in a single-bond geometry to one C(19) and one F(2) atom. The C(21)-F(2) bond length is 1.36 Å. In the eleventh C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(7), and one C(9) atom. The C(8)-C(11) bond length is 1.51 Å. The C(8)-C(9) bond length is 1.35 Å. In the twelfth C site, C(9) is bonded in a single-bond geometry to one C(8) and one F(4) atom. The C(9)-F(4) bond length is 1.34 Å. In the thirteenth C site, C(10) is bonded in a single-bond geometry to one C(5) and one F(3) atom. The C(10)-F(3) bond length is 1.33 Å. In the fourteenth C site, C(11) is bonded in a 3-coordinate geometry to one C(8); one N(3); and two equivalent H(6,7) atoms. The C(11)-N(3) bond length is 1.46 Å. Both C(11)-H(6,7) bond lengths are 0.97 Å. In the fifteenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one N(3), and one H(8) atom. The C(12)-C(13) bond length is 1.33 Å. The C(12)-N(3) bond length is 1.35 Å. The C(12)-H(8) bond length is 0.93 Å. In the sixteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(4), and one H(9) atom. The C(13)-N(4) bond length is 1.34 Å. The C(13)-H(9) bond length is 0.93 Å. In the seventeenth C site, C(14) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(10) atom. The C(14)-N(3) bond length is 1.32 Å. The C(14)-N(4) bond length is 1.31 Å. The C(14)-H(10) bond length is 0.93 Å. In the eighteenth C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.93 Å. In the nineteenth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 0.93 Å. In the twentieth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(3) atom. The C(3)-N(2) bond length is 1.35 Å. The C(3)-H(3) bond length is 0.93 Å. In the twenty-first C site, C(4) is bonded in a 3-coordinate geometry to one C(5), one N(2), one H(4), and one H(5) atom. The C(4)-N(2) bond length is 1.47 Å. The C(4)-H(4) bond length is 0.97 Å. The C(4)-H(5) bond length is 0.97 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(14) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(13), and one C(14) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(15), and one C(17) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(16), one C(17), and one C(18) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6,7) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(14,15) is bonded in a single-bond geometry to one C(18) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(20) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(21) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(10) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one C(6) atom. Linkers: 12 Fc1c(F)c(Cn2ccnc2)c(F)c(F)c1Cn1ccnc1. Metal clusters: 4 [Mn]. The MOF has largest included sphere 4.88 A, density 1.12 g/cm3, surface area 4684.32 m2/g, accessible volume 0.41 cm3/g