AgC11N6H14(CH)2CH2 crystallizes in the triclinic P-1 space group. The structure consists of eight 02329_fluka molecules and four 02329_fluka molecules inside a AgC11N6H14 framework. In the AgC11N6H14 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal pyramidal geometry to one N(1), one N(10), one N(11), and one N(2) atom. The Ag(1)-N(1) bond length is 2.19 Å. The Ag(1)-N(10) bond length is 2.50 Å. The Ag(1)-N(11) bond length is 2.18 Å. The Ag(1)-N(2) bond length is 2.41 Å. In the second Ag site, Ag(2) is bonded in a distorted rectangular see-saw-like geometry to one N(4), one N(5), one N(7), and one N(8) atom. The Ag(2)-N(4) bond length is 2.18 Å. The Ag(2)-N(5) bond length is 2.53 Å. The Ag(2)-N(7) bond length is 2.48 Å. The Ag(2)-N(8) bond length is 2.19 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.30 Å. The C(1)-N(3) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.94 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(2) atom. The C(2)-N(2) bond length is 1.32 Å. The C(2)-N(3) bond length is 1.36 Å. The C(2)-H(2) bond length is 0.94 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(3) atom. The C(3)-N(4) bond length is 1.32 Å. The C(3)-N(6) bond length is 1.34 Å. The C(3)-H(3) bond length is 0.94 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(4) atom. The C(4)-N(5) bond length is 1.29 Å. The C(4)-N(6) bond length is 1.37 Å. The C(4)-H(4) bond length is 0.94 Å. In the fifth C site, C(5) is bonded to one C(10), one C(11), one C(6), and one N(3) atom to form distorted corner-sharing CC3N tetrahedra. The C(5)-C(10) bond length is 1.53 Å. The C(5)-C(11) bond length is 1.52 Å. The C(5)-C(6) bond length is 1.55 Å. The C(5)-N(3) bond length is 1.49 Å. In the sixth C site, C(6) is bonded in a water-like geometry to one C(5); one C(7); and two equivalent H(5,6) atoms. The C(6)-C(7) bond length is 1.53 Å. Both C(6)-H(5,6) bond lengths are 0.98 Å. In the seventh C site, C(7) is bonded to one C(13), one C(6), one C(8), and one N(6) atom to form distorted corner-sharing CC3N tetrahedra. The C(7)-C(13) bond length is 1.50 Å. The C(7)-C(8) bond length is 1.53 Å. The C(7)-N(6) bond length is 1.50 Å. In the eighth C site, C(8) is bonded in a water-like geometry to one C(7) and two equivalent H(7,8,25) atoms. Both C(8)-H(7,8,25) bond lengths are 0.98 Å. In the ninth C site, C(10) is bonded in a water-like geometry to one C(5) and two equivalent H(10,11) atoms. Both C(10)-H(10,11) bond lengths are 0.98 Å. In the tenth C site, C(11) is bonded in a water-like geometry to one C(5) and two equivalent H(12,13) atoms. Both C(11)-H(12,13) bond lengths are 0.98 Å. In the eleventh C site, C(13) is bonded in a water-like geometry to one C(7) and two equivalent H(15,16) atoms. Both C(13)-H(15,16) bond lengths are 0.98 Å. In the twelfth C site, C(15) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(19) atom. The C(15)-N(7) bond length is 1.30 Å. The C(15)-N(9) bond length is 1.36 Å. The C(15)-H(19) bond length is 0.94 Å. In the thirteenth C site, C(16) is bonded in a trigonal planar geometry to one N(8), one N(9), and one H(20) atom. The C(16)-N(8) bond length is 1.31 Å. The C(16)-N(9) bond length is 1.35 Å. The C(16)-H(20) bond length is 0.94 Å. In the fourteenth C site, C(17) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(21) atom. The C(17)-N(10) bond length is 1.31 Å. The C(17)-N(12) bond length is 1.35 Å. The C(17)-H(21) bond length is 0.94 Å. In the fifteenth C site, C(18) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(22) atom. The C(18)-N(11) bond length is 1.31 Å. The C(18)-N(12) bond length is 1.35 Å. The C(18)-H(22) bond length is 0.94 Å. In the sixteenth C site, C(19) is bonded to one C(20), one C(24), one C(25), and one N(9) atom to form distorted corner-sharing CC3N tetrahedra. The C(19)-C(20) bond length is 1.54 Å. The C(19)-C(24) bond length is 1.53 Å. The C(19)-C(25) bond length is 1.53 Å. The C(19)-N(9) bond length is 1.48 Å. In the seventeenth C site, C(20) is bonded in a water-like geometry to one C(19); one C(21); and two equivalent H(23,24) atoms. The C(20)-C(21) bond length is 1.53 Å. Both C(20)-H(23,24) bond lengths are 0.98 Å. In the eighteenth C site, C(21) is bonded to one C(20), one C(22), one C(27), and one N(12) atom to form distorted corner-sharing CC3N tetrahedra. The C(21)-C(22) bond length is 1.53 Å. The C(21)-C(27) bond length is 1.51 Å. The C(21)-N(12) bond length is 1.50 Å. In the nineteenth C site, C(22) is bonded in a water-like geometry to one C(21); one H(26); and one H(7,8,25) atom. The C(22)-H(26) bond length is 0.98 Å. The C(22)-H(7,8,25) bond length is 0.98 Å. In the twentieth C site, C(24) is bonded in a water-like geometry to one C(19) and two equivalent H(28,29) atoms. Both C(24)-H(28,29) bond lengths are 0.98 Å. In the twenty-first C site, C(25) is bonded in a water-like geometry to one C(19) and two equivalent H(30,31) atoms. Both C(25)-H(30,31) bond lengths are 0.98 Å. In the twenty-second C site, C(27) is bonded in a water-like geometry to one C(21) and two equivalent H(33,34) atoms. Both C(27)-H(33,34) bond lengths are 0.98 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.38 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Ag(1), one C(2), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(5) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one Ag(2), one C(3), and one N(5) atom. The N(4)-N(5) bond length is 1.40 Å. In the fifth N site, N(5) is bonded in a distorted trigonal non-coplanar geometry to one Ag(2), one C(4), and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(7) atom. In the seventh N site, N(7) is bonded in a distorted single-bond geometry to one Ag(2), one C(15), and one N(8) atom. The N(7)-N(8) bond length is 1.41 Å. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(16), and one N(7) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(19) atom. In the tenth N site, N(10) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one C(17), and one N(11) atom. The N(10)-N(11) bond length is 1.39 Å. In the eleventh N site, N(11) is bonded in a 3-coordinate geometry to one Ag(1), one C(18), and one N(10) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(21) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7,8,25) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(10,11) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(12,13) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(15,16) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(23,24) is bonded in a single-bond geometry to one C(20) atom. In the fifteenth H site, H(26) is bonded in a single-bond geometry to one C(22) atom. In the sixteenth H site, H(28,29) is bonded in a single-bond geometry to one C(24) atom. In the seventeenth H site, H(30,31) is bonded in a single-bond geometry to one C(25) atom. In the eighteenth H site, H(33,34) is bonded in a single-bond geometry to one C(27) atom. Linkers: 4 c1nncn1[C@]12C[C@H]3C[C@H](C[C@](n4cnnc4)(C3)C1)C2. Metal clusters: 4 [Ag]. The MOF has largest included sphere 4.08 A, density 1.48 g/cm3, surface area 3906.78 m2/g, accessible volume 0.23 cm3/g