NaCd4C52H24(NO)20(CH)16 is Indium-derived structured and crystallizes in the cubic Fm-3c space group. The structure is zero-dimensional and consists of three hundred and eighty-four 02329_fluka molecules and twenty-four NaCd4C52H24(NO)20 clusters. In each NaCd4C52H24(NO)20 cluster, Na(1) is bonded in a rectangular see-saw-like geometry to four equivalent O(3) atoms. All Na(1)-O(3) bond lengths are 2.35 Å. Cd(1) is bonded in a 6-coordinate geometry to two equivalent N(2), two equivalent O(1), and two equivalent O(2) atoms. Both Cd(1)-N(2) bond lengths are 2.28 Å. Both Cd(1)-O(1) bond lengths are 2.33 Å. Both Cd(1)-O(2) bond lengths are 2.57 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.19 Å. The C(1)-O(2) bond length is 1.18 Å. In the second C site, C(9) is bonded in a trigonal planar geometry to two equivalent N(2) and one O(3) atom. Both C(9)-N(2) bond lengths are 1.36 Å. The C(9)-O(3) bond length is 1.23 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one N(1) atom. The C(5)-N(1) bond length is 1.48 Å. In the fourth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2,5) atom. The C(3)-C(2) bond length is 1.39 Å. The C(3)-H(2,5) bond length is 0.94 Å. In the fifth C site, C(8) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(3) atom. The C(8)-N(1) bond length is 1.30 Å. The C(8)-N(2) bond length is 1.34 Å. The C(8)-N(3) bond length is 1.33 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(2,5) atom. The C(7)-C(2) bond length is 1.39 Å. The C(7)-H(2,5) bond length is 0.94 Å. In the seventh C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(5), one C(8), and one H(1) atom. The N(1)-H(1) bond length is 0.87 Å. In the second N site, N(3) is bonded in a bent 120 degrees geometry to two equivalent C(8) atoms. In the third N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(8), and one C(9) atom. There are two inequivalent H sites. In the first H site, H(2,5) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(1) is bonded in a single-bond geometry to one N(1) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one Na(1) and one C(9) atom. In the second O site, O(1) is bonded in a water-like geometry to one Cd(1) and one C(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. Linkers: 4 [O]C(=O)c1ccc(NC2=NC(Nc3ccc(C([O])=O)cc3)=NC(=O)[N]2)cc1 ,20 O=C1[N]C(=[N]=C([N]1)Nc1ccc(cc1)C(=O)[O])Nc1ccc(cc1)C(=O)[O]. Metal clusters: 6 O=[C]O[Cd]1(O[C]=O)[N]C(=O)[N][Cd](O[C]=O)(O[C]=O)[N]C(=O)[N][Cd](/N=[C](=N/[Cd]([N]C(=O)[N]1)(O[C]=O)O[C]=O)/O[Na])(O[C]=O)O[C]=O. The MOF has largest included sphere 15.48 A, density 0.83 g/cm3, surface area 3587.55 m2/g, accessible volume 0.79 cm3/g