Zn2C13N15H10O4(CH)4 crystallizes in the orthorhombic Pnnm space group. The structure consists of sixteen 02329_fluka molecules inside a Zn2C13N15H10O4 framework. In the Zn2C13N15H10O4 framework, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(6), one N(7), and one O(1) atom. The Zn(1)-N(1) bond length is 1.99 Å. The Zn(1)-N(6) bond length is 2.03 Å. The Zn(1)-N(7) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 1.97 Å. There are seven inequivalent C sites. In the first C site, C(9) is bonded in a trigonal planar geometry to one N(8) and two equivalent N(1) atoms. The C(9)-N(8) bond length is 1.36 Å. Both C(9)-N(1) bond lengths are 1.33 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(6) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-C(5) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.41 Å. In the third C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(2)-O(1) bond length is 1.28 Å. The C(2)-O(2) bond length is 1.24 Å. In the fourth C site, C(3) is bonded in a trigonal planar geometry to one N(3), one N(6), and one N(7) atom. The C(3)-N(3) bond length is 1.34 Å. The C(3)-N(6) bond length is 1.35 Å. The C(3)-N(7) bond length is 1.34 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(8) atom. The C(5)-C(5) bond length is 1.49 Å. The C(5)-C(8) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(6)-H(5) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(5) and one H(7) atom. The C(8)-H(7) bond length is 0.93 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Zn(1), one C(9), and one N(4) atom. The N(1)-N(4) bond length is 1.35 Å. In the second N site, N(2) is bonded in a water-like geometry to one N(5) and one N(7) atom. The N(2)-N(5) bond length is 1.30 Å. The N(2)-N(7) bond length is 1.36 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(3), one H(1), and one H(2) atom. The N(3)-H(1) bond length is 0.86 Å. The N(3)-H(2) bond length is 0.86 Å. In the fourth N site, N(4) is bonded in a distorted water-like geometry to one N(1) and one N(4) atom. The N(4)-N(4) bond length is 1.28 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one N(2) and one N(6) atom. The N(5)-N(6) bond length is 1.36 Å. In the sixth N site, N(6) is bonded in a 3-coordinate geometry to one Zn(1), one C(3), and one N(5) atom. In the seventh N site, N(7) is bonded in a 3-coordinate geometry to one Zn(1), one C(3), and one N(2) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(9) and two equivalent H(3) atoms. Both N(8)-H(3) bond lengths are 0.90 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(8) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. Linkers: 6 [O]C(=O)c1ccccc1-c1ccccc1C([O])=O ,12 NC1=NN=N[N]1. Metal clusters: 8 O=[C]O[Zn]. The MOF has largest included sphere 6.30 A, density 1.16 g/cm3, surface area 4275.03 m2/g, accessible volume 0.46 cm3/g