(CuC8H4(NO2)2)2CuC10H6(NO2)2(CH2)6(CH)12 is Indium-derived structured and crystallizes in the trigonal R3 space group. The structure is zero-dimensional and consists of one hundred and eight 02329_fluka molecules, fifty-four 02329_fluka molecules, nine CuC10H6(NO2)2 clusters, and nine CuC8H4(NO2)2 clusters. In each CuC10H6(NO2)2 cluster, Cu(2) is bonded in a rectangular see-saw-like geometry to one N(3), one N(4), one O(3), and one O(9) atom. The Cu(2)-N(3) bond length is 2.01 Å. The Cu(2)-N(4) bond length is 1.99 Å. The Cu(2)-O(3) bond length is 1.93 Å. The Cu(2)-O(9) bond length is 1.94 Å. There are ten inequivalent C sites. In the first C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(20) atom. The C(22)-N(3) bond length is 1.34 Å. The C(22)-H(20) bond length is 0.93 Å. In the second C site, C(25) is bonded in a distorted single-bond geometry to one C(26) and one H(23) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-H(23) bond length is 0.93 Å. In the third C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one C(27), and one N(3) atom. The C(26)-C(27) bond length is 1.47 Å. The C(26)-N(3) bond length is 1.35 Å. In the fourth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(26), one C(28), and one N(4) atom. The C(27)-C(28) bond length is 1.38 Å. The C(27)-N(4) bond length is 1.35 Å. In the fifth C site, C(28) is bonded in a distorted single-bond geometry to one C(27) and one H(24) atom. The C(28)-H(24) bond length is 0.93 Å. In the sixth C site, C(29) is bonded in a distorted single-bond geometry to one C(30) and one H(25) atom. The C(29)-C(30) bond length is 1.38 Å. The C(29)-H(25) bond length is 0.93 Å. In the seventh C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one C(31), and one H(26) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-H(26) bond length is 0.93 Å. In the eighth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(30), one N(4), and one H(27) atom. The C(31)-N(4) bond length is 1.33 Å. The C(31)-H(27) bond length is 0.93 Å. In the ninth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(5)-O(3) bond length is 1.23 Å. The C(5)-O(4) bond length is 1.25 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(10)-O(10) bond length is 1.24 Å. The C(10)-O(9) bond length is 1.28 Å. There are two inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(27), and one C(31) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cu(2), one C(22), and one C(26) atom. There are six inequivalent H sites. In the first H site, H(20) is bonded in a single-bond geometry to one C(22) atom. In the second H site, H(23) is bonded in a single-bond geometry to one C(25) atom. In the third H site, H(24) is bonded in a single-bond geometry to one C(28) atom. In the fourth H site, H(25) is bonded in a single-bond geometry to one C(29) atom. In the fifth H site, H(26) is bonded in a single-bond geometry to one C(30) atom. In the sixth H site, H(27) is bonded in a single-bond geometry to one C(31) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(5) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(10) atom. In the fourth O site, O(10) is bonded in a single-bond geometry to one C(10) atom. In each CuC8H4(NO2)2 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square pyramidal geometry to one N(1), one N(2), one O(1), one O(11), and one O(7) atom. The Cu(1)-N(1) bond length is 2.01 Å. The Cu(1)-N(2) bond length is 2.03 Å. The Cu(1)-O(1) bond length is 1.97 Å. The Cu(1)-O(11) bond length is 2.32 Å. The Cu(1)-O(7) bond length is 1.94 Å. In the second Cu site, Cu(3) is bonded in a 6-coordinate geometry to one N(5), one N(6), one O(11), one O(12), one O(5), and one O(6) atom. The Cu(3)-N(5) bond length is 2.01 Å. The Cu(3)-N(6) bond length is 1.98 Å. The Cu(3)-O(11) bond length is 2.58 Å. The Cu(3)-O(12) bond length is 1.95 Å. The Cu(3)-O(5) bond length is 2.49 Å. The Cu(3)-O(6) bond length is 1.95 Å. There are sixteen inequivalent C sites. In the first C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one N(2) atom. The C(17)-C(16) bond length is 1.48 Å. The C(17)-C(18) bond length is 1.35 Å. The C(17)-N(2) bond length is 1.35 Å. In the second C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(16) atom. The C(18)-H(16) bond length is 0.93 Å. In the third C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one N(1) atom. The C(16)-C(15) bond length is 1.39 Å. The C(16)-N(1) bond length is 1.35 Å. In the fourth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(19) atom. The C(21)-N(2) bond length is 1.33 Å. The C(21)-H(19) bond length is 0.93 Å. In the fifth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. The C(32)-O(11) bond length is 1.26 Å. The C(32)-O(12) bond length is 1.28 Å. In the sixth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(30) atom. The C(34)-N(5) bond length is 1.33 Å. The C(34)-H(30) bond length is 0.93 Å. In the seventh C site, C(37) is bonded in a distorted single-bond geometry to one C(38) and one H(33) atom. The C(37)-C(38) bond length is 1.39 Å. The C(37)-H(33) bond length is 0.93 Å. In the eighth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(37), one C(39), and one N(5) atom. The C(38)-C(39) bond length is 1.45 Å. The C(38)-N(5) bond length is 1.33 Å. In the ninth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(38), one C(40), and one N(6) atom. The C(39)-C(40) bond length is 1.48 Å. The C(39)-N(6) bond length is 1.36 Å. In the tenth C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one H(34) atom. The C(40)-H(34) bond length is 0.93 Å. In the eleventh C site, C(43) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(37) atom. The C(43)-N(6) bond length is 1.31 Å. The C(43)-H(37) bond length is 0.93 Å. In the twelfth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.22 Å. In the thirteenth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(7)-O(5) bond length is 1.25 Å. The C(7)-O(6) bond length is 1.29 Å. In the fourteenth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(8)-O(7) bond length is 1.29 Å. The C(8)-O(8) bond length is 1.24 Å. In the fifteenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(12) atom. The C(12)-N(1) bond length is 1.34 Å. The C(12)-H(12) bond length is 0.93 Å. In the sixteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(15) atom. The C(15)-H(15) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(6) is bonded in a trigonal planar geometry to one Cu(3), one C(39), and one C(43) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Cu(3), one C(34), and one C(38) atom. In the third N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(12), and one C(16) atom. In the fourth N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(17), and one C(21) atom. There are eight inequivalent H sites. In the first H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the third H site, H(16) is bonded in a single-bond geometry to one C(18) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(21) atom. In the fifth H site, H(30) is bonded in a single-bond geometry to one C(34) atom. In the sixth H site, H(33) is bonded in a single-bond geometry to one C(37) atom. In the seventh H site, H(34) is bonded in a single-bond geometry to one C(40) atom. In the eighth H site, H(37) is bonded in a single-bond geometry to one C(43) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to one Cu(3) and one C(7) atom. In the fourth O site, O(6) is bonded in a water-like geometry to one Cu(3) and one C(7) atom. In the fifth O site, O(8) is bonded in a single-bond geometry to one C(8) atom. In the sixth O site, O(11) is bonded in a distorted single-bond geometry to one Cu(1), one Cu(3), and one C(32) atom. In the seventh O site, O(12) is bonded in a water-like geometry to one Cu(3) and one C(32) atom. In the eighth O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(8) atom. Linkers: 1 [O][C]CC(CC([O])=O)CC([O])=O ,1 [O][C]C[C@@H](CC([O])=O)CC(=O)O[Cu]1(OC(=O)CC(CC(=O)O[Cu]2(OC(=O)CC(CC([O])=O)CC([O])=O)N3C=CC=CC3=C3C=CC=CN32)CC(=O)O[Cu]2(OC(=O)CC(CC([O])=O)CC([O])=O)N3C=CC=CC3=C3C=CC=CN32)N2C=CC=CC2=C2C=CC=CN21 ,4 [O]C(=O)CC(CC([O])=O)CC(=O)O[Cu]1(OC(=O)CC(CC(=O)O[Cu]2(OC(=O)CC(CC([O])=O)CC([O])=O)N3C=CC=CC3=C3C=CC=CN32)CC(=O)O[Cu]2(OC(=O)CC(CC([O])=O)CC([O])=O)N3C=CC=CC3=C3C=CC=CN32)N2C=CC=CC2=C2C=CC=CN21 ,5 [O]C(=O)CC(CC([O])=O)CC([O])=O. Metal clusters: 9 O=[C]O[Cu]O[C]O[Cu](O[C]=O)O[C]=O. The MOF has largest included sphere 8.97 A, density 1.19 g/cm3, surface area 4542.86 m2/g, accessible volume 0.42 cm3/g