CoC10H8(N3S2)2(C9NH5O2)4 is Indium-derived structured and crystallizes in the orthorhombic Fddd space group. The structure is zero-dimensional and consists of sixteen C9NH5O2 clusters and eight CoC10H8(N3S2)2 clusters. In each C9NH5O2 cluster, there are nine inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to one C(10), one C(5), and one C(7) atom. The C(3)-C(10) bond length is 1.39 Å. The C(3)-C(5) bond length is 1.48 Å. The C(3)-C(7) bond length is 1.39 Å. In the second C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(6), and one C(9) atom. The C(4)-C(1) bond length is 1.38 Å. The C(4)-C(6) bond length is 1.50 Å. The C(4)-C(9) bond length is 1.37 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one O(1) atom. The C(5)-N(2) bond length is 1.39 Å. The C(5)-O(1) bond length is 1.20 Å. In the fourth C site, C(6) is bonded in a 3-coordinate geometry to one C(4); one N(2); and two equivalent H(3,4) atoms. The C(6)-N(2) bond length is 1.46 Å. Both C(6)-H(3,4) bond lengths are 0.97 Å. In the fifth C site, C(1) is bonded in a distorted single-bond geometry to one C(4) and one H(1) atom. The C(1)-H(1) bond length is 0.93 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(9)-H(6) bond length is 0.93 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(7) atom. The C(10)-C(7) bond length is 1.38 Å. The C(10)-H(7) bond length is 0.93 Å. In the eighth C site, C(7) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(3) atom. The C(7)-C(11) bond length is 1.48 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(2), and one O(2) atom. The C(11)-N(2) bond length is 1.38 Å. The C(11)-O(2) bond length is 1.21 Å. N(2) is bonded in a trigonal planar geometry to one C(11), one C(5), and one C(6) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one C(11) atom. In the second O site, O(1) is bonded in a single-bond geometry to one C(5) atom. In each CoC10H8(N3S2)2 cluster, Co(1) is bonded in an octahedral geometry to two equivalent N(3) and four equivalent N(1) atoms. Both Co(1)-N(3) bond lengths are 2.08 Å. All Co(1)-N(1) bond lengths are 2.17 Å. There are three inequivalent C sites. In the first C site, C(12) is bonded in a single-bond geometry to one N(3) and two equivalent S(1) atoms. The C(12)-N(3) bond length is 1.11 Å. Both C(12)-S(1) bond lengths are 1.68 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(8)-N(1) bond length is 1.32 Å. The C(8)-H(5) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a linear geometry to one Co(1) and one C(12) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(2), and one C(8) atom. There are two inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(8) atom. S(1) is bonded in a 2-coordinate geometry to one C(12) and one S(1) atom. The S(1)-S(1) bond length is 1.37 Å. Linkers: 16 O=c1c2cc3c(=O)n(Cc4ccncc4)c(=O)c3cc2c(=O)n1Cc1ccncc1. Metal clusters: 8 [N]([Co][N][C]1SS1)[C]1SS1. The MOF has largest included sphere 6.37 A, density 1.05 g/cm3, surface area 4692.50 m2/g, accessible volume 0.39 cm3/g