Cd6C68N11H40O23 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Cd6C68N11H40O23 cluster. There are four inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one N(5), one N(6), one O(10), one O(2), one O(3), and one O(9) atom to form distorted corner-sharing CdN2O4 octahedra. The corner-sharing octahedral tilt angles range from 73-74°. The Cd(1)-N(5) bond length is 2.38 Å. The Cd(1)-N(6) bond length is 2.30 Å. The Cd(1)-O(10) bond length is 2.22 Å. The Cd(1)-O(2) bond length is 2.33 Å. The Cd(1)-O(3) bond length is 2.40 Å. The Cd(1)-O(9) bond length is 2.26 Å. In the second Cd site, Cd(2,5) is bonded to one N(1,7); one N(4,10); one O(3); one O(5,17); one O(7,19); and one O(8,20) atom to form corner-sharing CdN2O4 octahedra. The corner-sharing octahedral tilt angles are 73°. The Cd(2,5)-N(1,7) bond length is 2.35 Å. The Cd(2,5)-N(4,10) bond length is 2.35 Å. The Cd(2,5)-O(3) bond length is 2.40 Å. The Cd(2,5)-O(5,17) bond length is 2.27 Å. The Cd(2,5)-O(7,19) bond length is 2.26 Å. The Cd(2,5)-O(8,20) bond length is 2.24 Å. In the third Cd site, Cd(3,6) is bonded to one N(2,8); one N(3,9); one O(1,13); one O(2); one O(4,16); and one O(6,18) atom to form corner-sharing CdN2O4 octahedra. The corner-sharing octahedral tilt angles are 74°. The Cd(3,6)-N(2,8) bond length is 2.36 Å. The Cd(3,6)-N(3,9) bond length is 2.34 Å. The Cd(3,6)-O(1,13) bond length is 2.27 Å. The Cd(3,6)-O(2) bond length is 2.40 Å. The Cd(3,6)-O(4,16) bond length is 2.25 Å. The Cd(3,6)-O(6,18) bond length is 2.24 Å. In the fourth Cd site, Cd(4) is bonded to one N(11), one O(12), one O(14), one O(15), one O(21), and one O(22) atom to form distorted corner-sharing CdNO5 octahedra. The corner-sharing octahedral tilt angles range from 73-74°. The Cd(4)-N(11) bond length is 2.38 Å. The Cd(4)-O(12) bond length is 2.30 Å. The Cd(4)-O(14) bond length is 2.33 Å. The Cd(4)-O(15) bond length is 2.40 Å. The Cd(4)-O(21) bond length is 2.26 Å. The Cd(4)-O(22) bond length is 2.22 Å. There are thirty-eight inequivalent C sites. In the first C site, C(1,35) is bonded in a distorted bent 120 degrees geometry to one C(2,36); one O(2); and one O(5,17) atom. The C(1,35)-C(2,36) bond length is 1.52 Å. The C(1,35)-O(2) bond length is 1.27 Å. The C(1,35)-O(5,17) bond length is 1.24 Å. In the second C site, C(2,36) is bonded in a trigonal planar geometry to one C(1,35); one C(6,40); and one C(9,43) atom. The C(2,36)-C(6,40) bond length is 1.39 Å. The C(2,36)-C(9,43) bond length is 1.38 Å. In the third C site, C(3,37) is bonded in a trigonal planar geometry to one C(11,45); one C(14,48); and one C(4,38) atom. The C(3,37)-C(11,45) bond length is 1.38 Å. The C(3,37)-C(14,48) bond length is 1.38 Å. The C(3,37)-C(4,38) bond length is 1.50 Å. In the fourth C site, C(4,38) is bonded in a distorted bent 120 degrees geometry to one C(3,37); one O(1,13); and one O(3) atom. The C(4,38)-O(1,13) bond length is 1.24 Å. The C(4,38)-O(3) bond length is 1.28 Å. In the fifth C site, C(5,39) is bonded in a distorted bent 120 degrees geometry to one C(7,41); one O(6,18); and one O(7,19) atom. The C(5,39)-C(7,41) bond length is 1.49 Å. The C(5,39)-O(6,18) bond length is 1.25 Å. The C(5,39)-O(7,19) bond length is 1.26 Å. In the sixth C site, C(6,40) is bonded in a distorted single-bond geometry to one C(2,36) and one H(1,21) atom. The C(6,40)-H(1,21) bond length is 0.93 Å. In the seventh C site, C(7,41) is bonded in a trigonal planar geometry to one C(27,61); one C(29,63); and one C(5,39) atom. The C(7,41)-C(27,61) bond length is 1.38 Å. The C(7,41)-C(29,63) bond length is 1.40 Å. In the eighth C site, C(8,42) is bonded in a distorted bent 120 degrees geometry to one N(3,9) and one H(2,22) atom. The C(8,42)-N(3,9) bond length is 1.34 Å. The C(8,42)-H(2,22) bond length is 0.93 Å. In the ninth C site, C(9,43) is bonded in a distorted single-bond geometry to one C(2,36) and one H(3,23) atom. The C(9,43)-H(3,23) bond length is 0.93 Å. In the tenth C site, C(10,44) is bonded in a distorted bent 120 degrees geometry to one C(19,53); one O(4,16); and one O(9) atom. The C(10,44)-C(19,53) bond length is 1.52 Å. The C(10,44)-O(4,16) bond length is 1.24 Å. The C(10,44)-O(9) bond length is 1.25 Å. In the eleventh C site, C(11,45) is bonded in a distorted single-bond geometry to one C(3,37) and one H(4,24) atom. The C(11,45)-H(4,24) bond length is 0.93 Å. In the twelfth C site, C(12,46) is bonded in a distorted bent 120 degrees geometry to one N(1,7) and one H(5,25) atom. The C(12,46)-N(1,7) bond length is 1.34 Å. The C(12,46)-H(5,25) bond length is 0.93 Å. In the thirteenth C site, C(13,47) is bonded in a distorted bent 120 degrees geometry to one C(15,49); one O(10); and one O(8,20) atom. The C(13,47)-C(15,49) bond length is 1.51 Å. The C(13,47)-O(10) bond length is 1.26 Å. The C(13,47)-O(8,20) bond length is 1.24 Å. In the fourteenth C site, C(14,48) is bonded in a distorted single-bond geometry to one C(3,37) and one H(6,26) atom. The C(14,48)-H(6,26) bond length is 0.93 Å. In the fifteenth C site, C(15,49) is bonded in a trigonal planar geometry to one C(13,47); one C(17,51); and one C(25,59) atom. The C(15,49)-C(17,51) bond length is 1.38 Å. The C(15,49)-C(25,59) bond length is 1.38 Å. In the sixteenth C site, C(16,50) is bonded in a distorted bent 120 degrees geometry to one N(3,9) and one H(7,27) atom. The C(16,50)-N(3,9) bond length is 1.34 Å. The C(16,50)-H(7,27) bond length is 0.93 Å. In the seventeenth C site, C(17,51) is bonded in a distorted single-bond geometry to one C(15,49) and one H(8,15,28,35) atom. The C(17,51)-H(8,15,28,35) bond length is 0.93 Å. In the eighteenth C site, C(18,52) is bonded in a distorted bent 120 degrees geometry to one N(1,7) and one H(9,29) atom. The C(18,52)-N(1,7) bond length is 1.34 Å. The C(18,52)-H(9,29) bond length is 0.93 Å. In the nineteenth C site, C(19,53) is bonded in a trigonal planar geometry to one C(10,44); one C(22,56); and one C(23,57) atom. The C(19,53)-C(22,56) bond length is 1.38 Å. The C(19,53)-C(23,57) bond length is 1.39 Å. In the twentieth C site, C(20,54) is bonded in a distorted bent 120 degrees geometry to one N(2,8) and one H(10,30) atom. The C(20,54)-N(2,8) bond length is 1.33 Å. The C(20,54)-H(10,30) bond length is 0.93 Å. In the twenty-first C site, C(21,55) is bonded in a distorted bent 120 degrees geometry to one N(2,8) and one H(11,31) atom. The C(21,55)-N(2,8) bond length is 1.34 Å. The C(21,55)-H(11,31) bond length is 0.93 Å. In the twenty-second C site, C(22,56) is bonded in a distorted single-bond geometry to one C(19,53) and one H(12,32) atom. The C(22,56)-H(12,32) bond length is 0.93 Å. In the twenty-third C site, C(23,57) is bonded in a distorted single-bond geometry to one C(19,53) and one H(13,33) atom. The C(23,57)-H(13,33) bond length is 0.93 Å. In the twenty-fourth C site, C(24,58) is bonded in a distorted bent 120 degrees geometry to one N(4,10) and one H(14,34) atom. The C(24,58)-N(4,10) bond length is 1.35 Å. The C(24,58)-H(14,34) bond length is 0.93 Å. In the twenty-fifth C site, C(25,59) is bonded in a distorted single-bond geometry to one C(15,49) and one H(8,15,28,35) atom. The C(25,59)-H(8,15,28,35) bond length is 0.93 Å. In the twenty-sixth C site, C(26,60) is bonded in a distorted bent 120 degrees geometry to one N(4,10) and one H(16,36) atom. The C(26,60)-N(4,10) bond length is 1.34 Å. The C(26,60)-H(16,36) bond length is 0.93 Å. In the twenty-seventh C site, C(27,61) is bonded in a distorted single-bond geometry to one C(7,41) and one H(17,37) atom. The C(27,61)-H(17,37) bond length is 0.93 Å. In the twenty-eighth C site, C(28,62) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(18,38) atom. The C(28,62)-N(5) bond length is 1.32 Å. The C(28,62)-H(18,38) bond length is 0.93 Å. In the twenty-ninth C site, C(29,63) is bonded in a single-bond geometry to one C(7,41) and one H(19,39) atom. The C(29,63)-H(19,39) bond length is 0.93 Å. In the thirtieth C site, C(30,64) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(20,40) atom. The C(30,64)-N(5) bond length is 1.34 Å. The C(30,64)-H(20,40) bond length is 0.93 Å. In the thirty-first C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(32), one N(6), and one O(11) atom. The C(31)-C(32) bond length is 1.49 Å. The C(31)-N(6) bond length is 1.29 Å. The C(31)-O(11) bond length is 1.15 Å. In the thirty-second C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(66), and one C(68) atom. The C(32)-C(66) bond length is 1.35 Å. The C(32)-C(68) bond length is 1.23 Å. In the thirty-third C site, C(33) is bonded in a single-bond geometry to one C(34) and one N(6) atom. The C(33)-C(34) bond length is 1.42 Å. The C(33)-N(6) bond length is 1.24 Å. In the thirty-fourth C site, C(34) is bonded in a bent 120 degrees geometry to one C(33) and one C(66) atom. The C(34)-C(66) bond length is 1.23 Å. In the thirty-fifth C site, C(65) is bonded in a bent 120 degrees geometry to one C(66), one O(12), and one O(23) atom. The C(65)-C(66) bond length is 1.49 Å. The C(65)-O(12) bond length is 1.29 Å. The C(65)-O(23) bond length is 1.15 Å. In the thirty-sixth C site, C(66) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(65) atom. In the thirty-seventh C site, C(67) is bonded in a single-bond geometry to one C(68) and one O(12) atom. The C(67)-C(68) bond length is 1.42 Å. The C(67)-O(12) bond length is 1.24 Å. In the thirty-eighth C site, C(68) is bonded in a bent 120 degrees geometry to one C(32) and one C(67) atom. There are seven inequivalent N sites. In the first N site, N(1,7) is bonded in a trigonal planar geometry to one Cd(2,5); one C(12,46); and one C(18,52) atom. In the second N site, N(2,8) is bonded in a trigonal planar geometry to one Cd(3,6); one C(20,54); and one C(21,55) atom. In the third N site, N(3,9) is bonded in a trigonal planar geometry to one Cd(3,6); one C(16,50); and one C(8,42) atom. In the fourth N site, N(4,10) is bonded in a trigonal planar geometry to one Cd(2,5); one C(24,58); and one C(26,60) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cd(1); one C(28,62); and one C(30,64) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cd(1), one C(31), and one C(33) atom. In the seventh N site, N(11) is bonded in a trigonal planar geometry to one Cd(4); one C(28,62); and one C(30,64) atom. The N(11)-C(28,62) bond length is 1.32 Å. The N(11)-C(30,64) bond length is 1.34 Å. There are nineteen inequivalent H sites. In the first H site, H(1,21) is bonded in a single-bond geometry to one C(6,40) atom. In the second H site, H(2,22) is bonded in a single-bond geometry to one C(8,42) atom. In the third H site, H(3,23) is bonded in a single-bond geometry to one C(9,43) atom. In the fourth H site, H(4,24) is bonded in a single-bond geometry to one C(11,45) atom. In the fifth H site, H(5,25) is bonded in a single-bond geometry to one C(12,46) atom. In the sixth H site, H(6,26) is bonded in a single-bond geometry to one C(14,48) atom. In the seventh H site, H(7,27) is bonded in a single-bond geometry to one C(16,50) atom. In the eighth H site, H(8,15,28,35) is bonded in a single-bond geometry to one C(17,51) atom. In the ninth H site, H(9,29) is bonded in a single-bond geometry to one C(18,52) atom. In the tenth H site, H(10,30) is bonded in a single-bond geometry to one C(20,54) atom. In the eleventh H site, H(11,31) is bonded in a single-bond geometry to one C(21,55) atom. In the twelfth H site, H(12,32) is bonded in a single-bond geometry to one C(22,56) atom. In the thirteenth H site, H(13,33) is bonded in a single-bond geometry to one C(23,57) atom. In the fourteenth H site, H(14,34) is bonded in a single-bond geometry to one C(24,58) atom. In the fifteenth H site, H(16,36) is bonded in a single-bond geometry to one C(26,60) atom. In the sixteenth H site, H(17,37) is bonded in a single-bond geometry to one C(27,61) atom. In the seventeenth H site, H(18,38) is bonded in a single-bond geometry to one C(28,62) atom. In the eighteenth H site, H(19,39) is bonded in a single-bond geometry to one C(29,63) atom. In the nineteenth H site, H(20,40) is bonded in a single-bond geometry to one C(30,64) atom. There are seventeen inequivalent O sites. In the first O site, O(1,13) is bonded in a distorted bent 120 degrees geometry to one Cd(3,6) and one C(4,38) atom. In the second O site, O(2) is bonded in a distorted trigonal planar geometry to one Cd(1); one Cd(3,6); and one C(1,35) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1); one Cd(2,5); and one C(4,38) atom. In the fourth O site, O(4,16) is bonded in a bent 120 degrees geometry to one Cd(3,6) and one C(10,44) atom. In the fifth O site, O(5,17) is bonded in a distorted bent 120 degrees geometry to one Cd(2,5) and one C(1,35) atom. In the sixth O site, O(6,18) is bonded in a bent 150 degrees geometry to one Cd(3,6) and one C(5,39) atom. In the seventh O site, O(7,19) is bonded in a distorted bent 120 degrees geometry to one Cd(2,5) and one C(5,39) atom. In the eighth O site, O(8,20) is bonded in a bent 120 degrees geometry to one Cd(2,5) and one C(13,47) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(10,44) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(13,47) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one C(31) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Cd(4), one C(65), and one C(67) atom. In the thirteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Cd(3,6); one Cd(4); and one C(1,35) atom. The O(14)-Cd(3,6) bond length is 2.40 Å. The O(14)-C(1,35) bond length is 1.27 Å. In the fourteenth O site, O(15) is bonded in a distorted single-bond geometry to one Cd(2,5); one Cd(4); and one C(4,38) atom. The O(15)-Cd(2,5) bond length is 2.40 Å. The O(15)-C(4,38) bond length is 1.28 Å. In the fifteenth O site, O(21) is bonded in a distorted bent 120 degrees geometry to one Cd(4) and one C(10,44) atom. The O(21)-C(10,44) bond length is 1.25 Å. In the sixteenth O site, O(22) is bonded in a bent 150 degrees geometry to one Cd(4) and one C(13,47) atom. The O(22)-C(13,47) bond length is 1.26 Å. In the seventeenth O site, O(23) is bonded in a single-bond geometry to one C(65) atom. Linkers: 10 [O]C(=O)c1ccncc1 ,1 O=C1N=[C][C]=C2C(=O)O[C][C]=C12. Metal clusters: 2 [C]1O[Cd]2O[C]O[Cd]3(O[C]O2)O[C]O[Cd](O1)O[C]O3. The MOF has largest included sphere 6.48 A, density 1.39 g/cm3, surface area 3500.86 m2/g, accessible volume 0.33 cm3/g