ZnC12N2H9O3C4H3O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two methallyl alcohol molecules and two ZnC12N2H9O3 clusters. In each ZnC12N2H9O3 cluster, Zn(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Zn(1)-N(1) bond length is 2.07 Å. The Zn(1)-N(2) bond length is 2.09 Å. The Zn(1)-O(1) bond length is 2.40 Å. The Zn(1)-O(2) bond length is 2.09 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(4) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(4)-H(4) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(5) bond length is 0.93 Å. In the sixth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-H(8) bond length is 0.93 Å. In the seventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(9) bond length is 0.93 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(10) bond length is 0.93 Å. In the ninth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.37 Å. The C(13)-C(16) bond length is 1.62 Å. In the tenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(11) atom. The C(14)-C(15) bond length is 1.37 Å. The C(14)-H(11) bond length is 0.93 Å. In the eleventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(2), and one H(12) atom. The C(15)-N(2) bond length is 1.34 Å. The C(15)-H(12) bond length is 0.93 Å. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(13) and one O(4) atom. The C(16)-O(4) bond length is 1.41 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(5), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(15) atom. There are nine inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one O(4) atom. The H(2)-O(4) bond length is 0.82 Å. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the third O site, O(4) is bonded in a water-like geometry to one C(16) and one H(2) atom. Linkers: 3 O[C]([C](O)c1ccncc1)c1ccncc1 ,1 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 O=[C]O[Zn]. The MOF has largest included sphere 4.87 A, density 1.15 g/cm3, surface area 4726.59 m2/g, accessible volume 0.43 cm3/g