(CH)6Zn7C87H87S2(N2O7)3 crystallizes in the monoclinic P2_1/c space group. The structure consists of twenty-four 02329_fluka molecules inside a Zn7C87H87S2(N2O7)3 framework. In each Zn7C87H87S2(N2O7)3 framework, there are seven inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.11 Å. The Zn(1)-N(2) bond length is 2.07 Å. The Zn(1)-O(3) bond length is 1.99 Å. The Zn(1)-O(4) bond length is 1.96 Å. In the second Zn site, Zn(2) is bonded in a distorted trigonal bipyramidal geometry to one N(3), one N(4), one O(15), one O(16), and one O(20) atom. The Zn(2)-N(3) bond length is 2.09 Å. The Zn(2)-N(4) bond length is 2.09 Å. The Zn(2)-O(15) bond length is 1.96 Å. The Zn(2)-O(16) bond length is 1.97 Å. The Zn(2)-O(20) bond length is 1.99 Å. In the third Zn site, Zn(3) is bonded to one O(1), one O(11), one O(18), and one O(21) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(1) bond length is 1.98 Å. The Zn(3)-O(11) bond length is 1.91 Å. The Zn(3)-O(18) bond length is 1.95 Å. The Zn(3)-O(21) bond length is 1.92 Å. In the fourth Zn site, Zn(4) is bonded to one O(13), one O(2), one O(21), and one O(7) atom to form corner-sharing ZnO4 tetrahedra. The Zn(4)-O(13) bond length is 1.94 Å. The Zn(4)-O(2) bond length is 2.01 Å. The Zn(4)-O(21) bond length is 1.93 Å. The Zn(4)-O(7) bond length is 1.96 Å. In the fifth Zn site, Zn(5) is bonded in a distorted see-saw-like geometry to one O(12), one O(14), one O(21), and one O(6) atom. The Zn(5)-O(12) bond length is 2.07 Å. The Zn(5)-O(14) bond length is 2.11 Å. The Zn(5)-O(21) bond length is 2.01 Å. The Zn(5)-O(6) bond length is 2.16 Å. In the sixth Zn site, Zn(6) is bonded to one O(17), one O(21), one O(5), and one O(8) atom to form corner-sharing ZnO4 tetrahedra. The Zn(6)-O(17) bond length is 1.99 Å. The Zn(6)-O(21) bond length is 1.93 Å. The Zn(6)-O(5) bond length is 1.94 Å. The Zn(6)-O(8) bond length is 1.95 Å. In the seventh Zn site, Zn(7) is bonded in a distorted square pyramidal geometry to one N(5), one N(6), one O(10), one O(19), and one O(9) atom. The Zn(7)-N(5) bond length is 2.10 Å. The Zn(7)-N(6) bond length is 2.10 Å. The Zn(7)-O(10) bond length is 1.96 Å. The Zn(7)-O(19) bond length is 1.99 Å. The Zn(7)-O(9) bond length is 1.95 Å. There are eighty-seven inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.24 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(12) bond length is 1.44 Å. The C(4)-C(5) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one O(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-O(3) bond length is 1.33 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-C(8) bond length is 1.55 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(2) atom. The C(7)-H(2) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a tetrahedral geometry to one C(10), one C(11), one C(6), and one C(9) atom. The C(8)-C(10) bond length is 1.55 Å. The C(8)-C(11) bond length is 1.54 Å. The C(8)-C(9) bond length is 1.58 Å. In the ninth C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(8); one H(5); and two equivalent H(3,4) atoms. The C(9)-H(5) bond length is 0.96 Å. Both C(9)-H(3,4) bond lengths are 0.96 Å. In the tenth C site, C(10) is bonded in a trigonal non-coplanar geometry to one C(8); one H(8); and two equivalent H(6,7) atoms. The C(10)-H(8) bond length is 0.96 Å. Both C(10)-H(6,7) bond lengths are 0.96 Å. In the eleventh C site, C(11) is bonded in a trigonal non-coplanar geometry to one C(8); one H(11); and two equivalent H(9,10) atoms. The C(11)-H(11) bond length is 0.96 Å. Both C(11)-H(9,10) bond lengths are 0.96 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(12) atom. The C(12)-N(2) bond length is 1.32 Å. The C(12)-H(12) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(18) and one N(2) atom. The C(13)-C(18) bond length is 1.39 Å. The C(13)-N(2) bond length is 1.43 Å. In the fourteenth C site, C(17) is bonded in a single-bond geometry to one C(18) and one H(16,41) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(16,41) bond length is 0.93 Å. In the fifteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(13), one C(17), and one N(1) atom. The C(18)-N(1) bond length is 1.43 Å. In the sixteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(1), and one H(17) atom. The C(19)-C(20) bond length is 1.47 Å. The C(19)-N(1) bond length is 1.29 Å. The C(19)-H(17) bond length is 0.93 Å. In the seventeenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(25) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-C(25) bond length is 1.39 Å. In the eighteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one H(18) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(18) bond length is 0.93 Å. In the nineteenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(30) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-C(30) bond length is 1.49 Å. In the twentieth C site, C(23) is bonded in a distorted single-bond geometry to one C(22), one C(24), and one H(19) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-H(19) bond length is 0.93 Å. In the twenty-first C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(26) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-C(26) bond length is 1.58 Å. In the twenty-second C site, C(25) is bonded in a distorted single-bond geometry to one C(20), one C(24), and one O(4) atom. The C(25)-O(4) bond length is 1.33 Å. In the twenty-third C site, C(26) is bonded in a tetrahedral geometry to one C(24), one C(27), one C(28), and one C(29) atom. The C(26)-C(27) bond length is 1.52 Å. The C(26)-C(28) bond length is 1.52 Å. The C(26)-C(29) bond length is 1.55 Å. In the twenty-fourth C site, C(27) is bonded in a trigonal non-coplanar geometry to one C(26); one H(21); and two equivalent H(20,22,23,25) atoms. The C(27)-H(21) bond length is 0.96 Å. Both C(27)-H(20,22,23,25) bond lengths are 0.96 Å. In the twenty-fifth C site, C(28) is bonded in a trigonal non-coplanar geometry to one C(26); one H(24); and two equivalent H(20,22,23,25) atoms. The C(28)-H(24) bond length is 0.96 Å. Both C(28)-H(20,22,23,25) bond lengths are 0.96 Å. In the twenty-sixth C site, C(29) is bonded in a trigonal non-coplanar geometry to one C(26) and three equivalent H(26,27,28) atoms. All C(29)-H(26,27,28) bond lengths are 0.96 Å. In the twenty-seventh C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(5), and one O(6) atom. The C(30)-O(5) bond length is 1.27 Å. The C(30)-O(6) bond length is 1.26 Å. In the twenty-eighth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(7), and one O(8) atom. The C(31)-C(32) bond length is 1.48 Å. The C(31)-O(7) bond length is 1.26 Å. The C(31)-O(8) bond length is 1.29 Å. In the twenty-ninth C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(37) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-C(37) bond length is 1.39 Å. In the thirtieth C site, C(33) is bonded in a single-bond geometry to one C(32), one C(34), and one H(29) atom. The C(33)-C(34) bond length is 1.39 Å. The C(33)-H(29) bond length is 0.93 Å. In the thirty-first C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(41) atom. The C(34)-C(35) bond length is 1.39 Å. The C(34)-C(41) bond length is 1.43 Å. In the thirty-second C site, C(35) is bonded in a distorted single-bond geometry to one C(34), one C(36), and one O(9) atom. The C(35)-C(36) bond length is 1.39 Å. The C(35)-O(9) bond length is 1.34 Å. In the thirty-third C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(38) atom. The C(36)-C(37) bond length is 1.39 Å. The C(36)-C(38) bond length is 1.62 Å. In the thirty-fourth C site, C(37) is bonded in a distorted single-bond geometry to one C(32), one C(36), and one H(30) atom. The C(37)-H(30) bond length is 0.93 Å. In the thirty-fifth C site, C(38) is bonded in a trigonal non-coplanar geometry to one C(36), one C(39), and one C(40) atom. The C(38)-C(39) bond length is 1.51 Å. The C(38)-C(40) bond length is 1.58 Å. In the thirty-sixth C site, C(39) is bonded in a trigonal non-coplanar geometry to one C(38); one H(31,34,36); one H(32); and one H(33,35) atom. The C(39)-H(31,34,36) bond length is 0.96 Å. The C(39)-H(32) bond length is 0.96 Å. The C(39)-H(33,35) bond length is 0.96 Å. In the thirty-seventh C site, C(40) is bonded in a trigonal non-coplanar geometry to one C(38); one H(33,35); and two equivalent H(31,34,36) atoms. The C(40)-H(33,35) bond length is 0.96 Å. Both C(40)-H(31,34,36) bond lengths are 0.96 Å. In the thirty-eighth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(34), one N(6), and one H(37) atom. The C(41)-N(6) bond length is 1.28 Å. The C(41)-H(37) bond length is 0.93 Å. In the thirty-ninth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(43), one C(47), and one N(6) atom. The C(42)-C(43) bond length is 1.39 Å. The C(42)-C(47) bond length is 1.39 Å. The C(42)-N(6) bond length is 1.42 Å. In the fortieth C site, C(43) is bonded in a single-bond geometry to one C(42) and one H(38) atom. The C(43)-H(38) bond length is 0.93 Å. In the forty-first C site, C(46) is bonded in a distorted single-bond geometry to one C(47) and one H(16,41) atom. The C(46)-C(47) bond length is 1.39 Å. The C(46)-H(16,41) bond length is 0.93 Å. In the forty-second C site, C(47) is bonded in a distorted trigonal planar geometry to one C(42), one C(46), and one N(5) atom. The C(47)-N(5) bond length is 1.43 Å. In the forty-third C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(49), one N(5), and one H(42) atom. The C(48)-C(49) bond length is 1.45 Å. The C(48)-N(5) bond length is 1.29 Å. The C(48)-H(42) bond length is 0.93 Å. In the forty-fourth C site, C(49) is bonded in a trigonal planar geometry to one C(48), one C(50), and one C(54) atom. The C(49)-C(50) bond length is 1.39 Å. The C(49)-C(54) bond length is 1.39 Å. In the forty-fifth C site, C(50) is bonded in a distorted single-bond geometry to one C(49), one C(51), and one H(43) atom. The C(50)-C(51) bond length is 1.39 Å. The C(50)-H(43) bond length is 0.93 Å. In the forty-sixth C site, C(51) is bonded in a trigonal planar geometry to one C(50), one C(52), and one C(59) atom. The C(51)-C(52) bond length is 1.39 Å. The C(51)-C(59) bond length is 1.52 Å. In the forty-seventh C site, C(52) is bonded in a single-bond geometry to one C(51), one C(53), and one H(44) atom. The C(52)-C(53) bond length is 1.39 Å. The C(52)-H(44) bond length is 0.93 Å. In the forty-eighth C site, C(53) is bonded in a trigonal planar geometry to one C(52), one C(54), and one C(55) atom. The C(53)-C(54) bond length is 1.39 Å. The C(53)-C(55) bond length is 1.56 Å. In the forty-ninth C site, C(54) is bonded in a distorted single-bond geometry to one C(49), one C(53), and one O(10) atom. The C(54)-O(10) bond length is 1.32 Å. In the fiftieth C site, C(55) is bonded in a tetrahedral geometry to one C(53), one C(56), one C(57), and one C(58) atom. The C(55)-C(56) bond length is 1.51 Å. The C(55)-C(57) bond length is 1.52 Å. The C(55)-C(58) bond length is 1.56 Å. In the fifty-first C site, C(56) is bonded in a trigonal non-coplanar geometry to one C(55); one H(45,49,51,53); one H(46); and one H(47,52) atom. The C(56)-H(45,49,51,53) bond length is 0.96 Å. The C(56)-H(46) bond length is 0.96 Å. The C(56)-H(47,52) bond length is 0.96 Å. In the fifty-second C site, C(57) is bonded in a trigonal non-coplanar geometry to one C(55); one H(45,49,51,53); one H(48); and one H(50) atom. The C(57)-H(45,49,51,53) bond length is 0.96 Å. The C(57)-H(48) bond length is 0.96 Å. The C(57)-H(50) bond length is 0.96 Å. In the fifty-third C site, C(58) is bonded in a trigonal non-coplanar geometry to one C(55); one H(47,52); and two equivalent H(45,49,51,53) atoms. The C(58)-H(47,52) bond length is 0.96 Å. Both C(58)-H(45,49,51,53) bond lengths are 0.96 Å. In the fifty-fourth C site, C(59) is bonded in a distorted bent 120 degrees geometry to one C(51), one O(11), and one O(12) atom. The C(59)-O(11) bond length is 1.28 Å. The C(59)-O(12) bond length is 1.23 Å. In the fifty-fifth C site, C(60) is bonded in a distorted bent 120 degrees geometry to one C(61), one O(13), and one O(14) atom. The C(60)-C(61) bond length is 1.52 Å. The C(60)-O(13) bond length is 1.27 Å. The C(60)-O(14) bond length is 1.24 Å. In the fifty-sixth C site, C(61) is bonded in a trigonal planar geometry to one C(60), one C(62), and one C(66) atom. The C(61)-C(62) bond length is 1.39 Å. The C(61)-C(66) bond length is 1.39 Å. In the fifty-seventh C site, C(62) is bonded in a distorted trigonal planar geometry to one C(61), one C(63), and one H(54) atom. The C(62)-C(63) bond length is 1.39 Å. The C(62)-H(54) bond length is 0.93 Å. In the fifty-eighth C site, C(63) is bonded in a trigonal planar geometry to one C(62), one C(64), and one C(71) atom. The C(63)-C(64) bond length is 1.39 Å. The C(63)-C(71) bond length is 1.47 Å. In the fifty-ninth C site, C(64) is bonded in a distorted single-bond geometry to one C(63), one C(65), and one O(15) atom. The C(64)-C(65) bond length is 1.39 Å. The C(64)-O(15) bond length is 1.32 Å. In the sixtieth C site, C(65) is bonded in a trigonal planar geometry to one C(64), one C(66), and one C(67) atom. The C(65)-C(66) bond length is 1.39 Å. The C(65)-C(67) bond length is 1.58 Å. In the sixty-first C site, C(66) is bonded in a distorted single-bond geometry to one C(61), one C(65), and one H(55) atom. The C(66)-H(55) bond length is 0.93 Å. In the sixty-second C site, C(67) is bonded in a tetrahedral geometry to one C(65), one C(68), one C(69), and one C(70) atom. The C(67)-C(68) bond length is 1.54 Å. The C(67)-C(69) bond length is 1.60 Å. The C(67)-C(70) bond length is 1.59 Å. In the sixty-third C site, C(68) is bonded in a trigonal non-coplanar geometry to one C(67); one H(57,59); and two equivalent H(56,58) atoms. The C(68)-H(57,59) bond length is 0.96 Å. Both C(68)-H(56,58) bond lengths are 0.96 Å. In the sixty-fourth C site, C(69) is bonded in a trigonal non-coplanar geometry to one C(67); one H(57,59); and two equivalent H(60,61) atoms. The C(69)-H(57,59) bond length is 0.96 Å. Both C(69)-H(60,61) bond lengths are 0.96 Å. In the sixty-fifth C site, C(70) is bonded in a trigonal non-coplanar geometry to one C(67) and three equivalent H(62,63,64) atoms. All C(70)-H(62,63,64) bond lengths are 0.96 Å. In the sixty-sixth C site, C(71) is bonded in a distorted bent 120 degrees geometry to one C(63), one N(3), and one H(65) atom. The C(71)-N(3) bond length is 1.31 Å. The C(71)-H(65) bond length is 0.93 Å. In the sixty-seventh C site, C(72) is bonded in a distorted trigonal planar geometry to one C(73), one C(77), and one N(3) atom. The C(72)-C(73) bond length is 1.39 Å. The C(72)-C(77) bond length is 1.39 Å. The C(72)-N(3) bond length is 1.42 Å. In the sixty-eighth C site, C(73) is bonded in a distorted trigonal planar geometry to one C(72), one C(74), and one H(66) atom. The C(73)-C(74) bond length is 1.39 Å. The C(73)-H(66) bond length is 0.93 Å. In the sixty-ninth C site, C(74) is bonded in a distorted single-bond geometry to one C(73) and one H(67) atom. The C(74)-H(67) bond length is 0.93 Å. In the seventieth C site, C(76) is bonded in a distorted single-bond geometry to one C(77) and one H(69) atom. The C(76)-C(77) bond length is 1.39 Å. The C(76)-H(69) bond length is 0.93 Å. In the seventy-first C site, C(77) is bonded in a distorted trigonal planar geometry to one C(72), one C(76), and one N(4) atom. The C(77)-N(4) bond length is 1.42 Å. In the seventy-second C site, C(78) is bonded in a distorted bent 120 degrees geometry to one C(79), one N(4), and one H(70) atom. The C(78)-C(79) bond length is 1.45 Å. The C(78)-N(4) bond length is 1.29 Å. The C(78)-H(70) bond length is 0.93 Å. In the seventy-third C site, C(79) is bonded in a trigonal planar geometry to one C(78), one C(80), and one C(84) atom. The C(79)-C(80) bond length is 1.39 Å. The C(79)-C(84) bond length is 1.39 Å. In the seventy-fourth C site, C(80) is bonded in a distorted trigonal planar geometry to one C(79), one C(81), and one H(71) atom. The C(80)-C(81) bond length is 1.39 Å. The C(80)-H(71) bond length is 0.93 Å. In the seventy-fifth C site, C(81) is bonded in a trigonal planar geometry to one C(80), one C(82), and one C(89) atom. The C(81)-C(82) bond length is 1.39 Å. The C(81)-C(89) bond length is 1.52 Å. In the seventy-sixth C site, C(82) is bonded in a distorted single-bond geometry to one C(81), one C(83), and one H(72) atom. The C(82)-C(83) bond length is 1.39 Å. The C(82)-H(72) bond length is 0.93 Å. In the seventy-seventh C site, C(83) is bonded in a trigonal planar geometry to one C(82), one C(84), and one C(85) atom. The C(83)-C(84) bond length is 1.39 Å. The C(83)-C(85) bond length is 1.57 Å. In the seventy-eighth C site, C(84) is bonded in a single-bond geometry to one C(79), one C(83), and one O(16) atom. The C(84)-O(16) bond length is 1.32 Å. In the seventy-ninth C site, C(85) is bonded in a tetrahedral geometry to one C(83), one C(86), one C(87), and one C(88) atom. The C(85)-C(86) bond length is 1.56 Å. The C(85)-C(87) bond length is 1.53 Å. The C(85)-C(88) bond length is 1.54 Å. In the eightieth C site, C(86) is bonded in a trigonal non-coplanar geometry to one C(85) and three equivalent H(73,74,75,81) atoms. All C(86)-H(73,74,75,81) bond lengths are 0.96 Å. In the eighty-first C site, C(87) is bonded in a trigonal non-coplanar geometry to one C(85), one H(76), one H(77), and one H(78) atom. The C(87)-H(76) bond length is 0.96 Å. The C(87)-H(77) bond length is 0.96 Å. The C(87)-H(78) bond length is 0.96 Å. In the eighty-second C site, C(88) is bonded in a trigonal non-coplanar geometry to one C(85); one H(73,74,75,81); one H(79); and one H(80) atom. The C(88)-H(73,74,75,81) bond length is 0.96 Å. The C(88)-H(79) bond length is 0.96 Å. The C(88)-H(80) bond length is 0.96 Å. In the eighty-third C site, C(89) is bonded in a distorted bent 120 degrees geometry to one C(81), one O(17), and one O(18) atom. The C(89)-O(17) bond length is 1.25 Å. The C(89)-O(18) bond length is 1.26 Å. In the eighty-fourth C site, C(90) is bonded in a trigonal non-coplanar geometry to one H(82), one H(83), one H(84), and one S(1) atom. The C(90)-H(82) bond length is 0.96 Å. The C(90)-H(83) bond length is 0.96 Å. The C(90)-H(84) bond length is 0.96 Å. The C(90)-S(1) bond length is 1.72 Å. In the eighty-fifth C site, C(91) is bonded in a trigonal non-coplanar geometry to one H(85), one H(86), one H(87), and one S(1) atom. The C(91)-H(85) bond length is 0.96 Å. The C(91)-H(86) bond length is 0.96 Å. The C(91)-H(87) bond length is 0.96 Å. The C(91)-S(1) bond length is 1.74 Å. In the eighty-sixth C site, C(92) is bonded in a trigonal non-coplanar geometry to one H(88), one H(89), one H(90), and one S(2) atom. The C(92)-H(88) bond length is 0.96 Å. The C(92)-H(89) bond length is 0.96 Å. The C(92)-H(90) bond length is 0.96 Å. The C(92)-S(2) bond length is 1.77 Å. In the eighty-seventh C site, C(93) is bonded in a trigonal non-coplanar geometry to one H(91), one H(92), one H(93), and one S(2) atom. The C(93)-H(91) bond length is 0.96 Å. The C(93)-H(92) bond length is 0.96 Å. The C(93)-H(93) bond length is 0.96 Å. The C(93)-S(2) bond length is 1.77 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(18), and one C(19) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(12), and one C(13) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(71), and one C(72) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(2), one C(77), and one C(78) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(7), one C(47), and one C(48) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(7), one C(41), and one C(42) atom. There are sixty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(6,7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(16,41) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(20,22,23,25) is bonded in a single-bond geometry to one C(27) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(24) is bonded in a single-bond geometry to one C(28) atom. In the seventeenth H site, H(26,27,28) is bonded in a single-bond geometry to one C(29) atom. In the eighteenth H site, H(29) is bonded in a single-bond geometry to one C(33) atom. In the nineteenth H site, H(30) is bonded in a single-bond geometry to one C(37) atom. In the twentieth H site, H(31,34,36) is bonded in a single-bond geometry to one C(39) atom. In the twenty-first H site, H(32) is bonded in a single-bond geometry to one C(39) atom. In the twenty-second H site, H(33,35) is bonded in a single-bond geometry to one C(39) atom. In the twenty-third H site, H(37) is bonded in a single-bond geometry to one C(41) atom. In the twenty-fourth H site, H(38) is bonded in a single-bond geometry to one C(43) atom. In the twenty-fifth H site, H(42) is bonded in a single-bond geometry to one C(48) atom. In the twenty-sixth H site, H(43) is bonded in a single-bond geometry to one C(50) atom. In the twenty-seventh H site, H(44) is bonded in a single-bond geometry to one C(52) atom. In the twenty-eighth H site, H(45,49,51,53) is bonded in a single-bond geometry to one C(56) atom. In the twenty-ninth H site, H(46) is bonded in a single-bond geometry to one C(56) atom. In the thirtieth H site, H(47,52) is bonded in a single-bond geometry to one C(56) atom. In the thirty-first H site, H(48) is bonded in a single-bond geometry to one C(57) atom. In the thirty-second H site, H(50) is bonded in a single-bond geometry to one C(57) atom. In the thirty-third H site, H(54) is bonded in a single-bond geometry to one C(62) atom. In the thirty-fourth H site, H(55) is bonded in a single-bond geometry to one C(66) atom. In the thirty-fifth H site, H(56,58) is bonded in a single-bond geometry to one C(68) atom. In the thirty-sixth H site, H(57,59) is bonded in a single-bond geometry to one C(68) atom. In the thirty-seventh H site, H(60,61) is bonded in a single-bond geometry to one C(69) atom. In the thirty-eighth H site, H(62,63,64) is bonded in a single-bond geometry to one C(70) atom. In the thirty-ninth H site, H(65) is bonded in a single-bond geometry to one C(71) atom. In the fortieth H site, H(66) is bonded in a single-bond geometry to one C(73) atom. In the forty-first H site, H(67) is bonded in a single-bond geometry to one C(74) atom. In the forty-second H site, H(69) is bonded in a single-bond geometry to one C(76) atom. In the forty-third H site, H(70) is bonded in a single-bond geometry to one C(78) atom. In the forty-fourth H site, H(71) is bonded in a single-bond geometry to one C(80) atom. In the forty-fifth H site, H(72) is bonded in a single-bond geometry to one C(82) atom. In the forty-sixth H site, H(73,74,75,81) is bonded in a single-bond geometry to one C(86) atom. In the forty-seventh H site, H(76) is bonded in a single-bond geometry to one C(87) atom. In the forty-eighth H site, H(77) is bonded in a single-bond geometry to one C(87) atom. In the forty-ninth H site, H(78) is bonded in a single-bond geometry to one C(87) atom. In the fiftieth H site, H(79) is bonded in a single-bond geometry to one C(88) atom. In the fifty-first H site, H(80) is bonded in a single-bond geometry to one C(88) atom. In the fifty-second H site, H(82) is bonded in a single-bond geometry to one C(90) atom. In the fifty-third H site, H(83) is bonded in a single-bond geometry to one C(90) atom. In the fifty-fourth H site, H(84) is bonded in a single-bond geometry to one C(90) atom. In the fifty-fifth H site, H(85) is bonded in a distorted bent 150 degrees geometry to one C(91) and one H(89) atom. The H(85)-H(89) bond length is 0.80 Å. In the fifty-sixth H site, H(86) is bonded in a single-bond geometry to one C(91) atom. In the fifty-seventh H site, H(87) is bonded in a single-bond geometry to one C(91) atom. In the fifty-eighth H site, H(88) is bonded in a single-bond geometry to one C(92) atom. In the fifty-ninth H site, H(89) is bonded in a distorted bent 150 degrees geometry to one C(92) and one H(85) atom. In the sixtieth H site, H(90) is bonded in a single-bond geometry to one C(92) atom. In the sixty-first H site, H(91) is bonded in a single-bond geometry to one C(93) atom. In the sixty-second H site, H(92) is bonded in a single-bond geometry to one C(93) atom. In the sixty-third H site, H(93) is bonded in a single-bond geometry to one C(93) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a distorted single-bond geometry to one C(90), one C(91), and one O(19) atom. The S(1)-O(19) bond length is 1.45 Å. In the second S site, S(2) is bonded in a distorted single-bond geometry to one C(92), one C(93), and one O(20) atom. The S(2)-O(20) bond length is 1.47 Å. There are twenty-one inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(30) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Zn(5) and one C(30) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(31) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(31) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(35) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Zn(7) and one C(54) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(59) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zn(5) and one C(59) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(60) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Zn(5) and one C(60) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(64) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(84) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(89) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(89) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Zn(7) and one S(1) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Zn(2) and one S(2) atom. In the twenty-first O site, O(21) is bonded in a tetrahedral geometry to one Zn(3), one Zn(4), one Zn(5), and one Zn(6) atom. Linkers: 4 CC(C)(C)c1cc(C([O])=O)cc2c1O[Zn]13Oc4c(cc(C([O])=O)cc4C(C)(C)C)[CH]N1c1ccccc1N3[CH]2 ,4 C[C](C)c1cc(C([O])=O)cc(/C=N/c2ccccc2/N=C/c2cc(C([O])=O)cc(C(C)(C)C)c2[O])c1[O] ,4 CC(C)(C)c1cc(C([O])=O)cc(/C=N/c2ccccc2/N=C/c2cc(C([O])=O)cc(C(C)(C)C)c2[O])c1[O]. Metal clusters: 8 [Zn] ,4 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. The MOF has largest included sphere 8.94 A, density 0.94 g/cm3, surface area 4477.62 m2/g, accessible volume 0.62 cm3/g