AgH6(C2N)4 crystallizes in the orthorhombic Fdd2 space group. Ag(1) is bonded in a trigonal pyramidal geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Ag(1)-N(1) bond lengths are 2.31 Å. Both Ag(1)-N(2) bond lengths are 2.39 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.36 Å. The C(2)-N(1) bond length is 1.33 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. The C(3)-C(3) bond length is 1.49 Å. The C(3)-C(4) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(3) atom. The C(4)-N(2) bond length is 1.33 Å. The C(4)-H(3) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(4) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(2) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. Linkers: 9 c1ncc(-c2cncnc2)cn1. Metal clusters: 8 [Ag]. The MOF has largest included sphere 4.62 A, density 1.44 g/cm3, surface area 3534.43 m2/g, accessible volume 0.36 cm3/g