CuH16(CN)12CuH20(C7N6)2(CH2)14 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of fourteen 02329_fluka molecules, one CuH16(CN)12 cluster, and one CuH20(C7N6)2 cluster. In the CuH16(CN)12 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(10) and two equivalent N(6) atoms. Both Cu(1)-N(10) bond lengths are 2.01 Å. Both Cu(1)-N(6) bond lengths are 2.01 Å. There are six inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to one N(10), one N(3), and one H(5) atom. The C(3)-N(10) bond length is 1.31 Å. The C(3)-N(3) bond length is 1.31 Å. The C(3)-H(5) bond length is 0.93 Å. In the second C site, C(7) is bonded in a 3-coordinate geometry to one N(11) and two equivalent H(11,12) atoms. The C(7)-N(11) bond length is 1.47 Å. Both C(7)-H(11,12) bond lengths are 0.97 Å. In the third C site, C(8) is bonded in a trigonal planar geometry to one N(10), one N(2), and one H(13) atom. The C(8)-N(10) bond length is 1.36 Å. The C(8)-N(2) bond length is 1.29 Å. The C(8)-H(13) bond length is 0.93 Å. In the fourth C site, C(12) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(19) atom. The C(12)-N(5) bond length is 1.31 Å. The C(12)-N(6) bond length is 1.34 Å. The C(12)-H(19) bond length is 0.93 Å. In the fifth C site, C(13) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(20,21) atoms. The C(13)-N(3) bond length is 1.48 Å. Both C(13)-H(20,21) bond lengths are 0.97 Å. In the sixth C site, C(18) is bonded in a trigonal planar geometry to one N(11), one N(6), and one H(28) atom. The C(18)-N(11) bond length is 1.31 Å. The C(18)-N(6) bond length is 1.34 Å. The C(18)-H(28) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(2) is bonded in a distorted water-like geometry to one C(8) and one N(3) atom. The N(2)-N(3) bond length is 1.34 Å. In the second N site, N(3) is bonded in a distorted trigonal planar geometry to one C(13), one C(3), and one N(2) atom. In the third N site, N(5) is bonded in a distorted water-like geometry to one C(12) and one N(11) atom. The N(5)-N(11) bond length is 1.34 Å. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(12), and one C(18) atom. In the fifth N site, N(10) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(3), and one C(8) atom. In the sixth N site, N(11) is bonded in a distorted trigonal planar geometry to one C(18), one C(7), and one N(5) atom. There are six inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(11,12) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(20,21) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(28) is bonded in a single-bond geometry to one C(18) atom. In the CuH20(C7N6)2 cluster, Cu(2) is bonded in a square co-planar geometry to two equivalent N(12) and two equivalent N(7) atoms. Both Cu(2)-N(12) bond lengths are 2.04 Å. Both Cu(2)-N(7) bond lengths are 2.01 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a water-like geometry to one C(4), one H(1), and one H(2) atom. The C(1)-C(4) bond length is 1.36 Å. The C(1)-H(1) bond length is 0.97 Å. The C(1)-H(2) bond length is 0.97 Å. In the second C site, C(4) is bonded in a 4-coordinate geometry to one C(1), one N(4), one H(6), and one H(7) atom. The C(4)-N(4) bond length is 1.47 Å. The C(4)-H(6) bond length is 0.97 Å. The C(4)-H(7) bond length is 0.97 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(8) atom. The C(5)-N(7) bond length is 1.35 Å. The C(5)-N(9) bond length is 1.29 Å. The C(5)-H(8) bond length is 0.93 Å. In the fourth C site, C(9) is bonded in a trigonal planar geometry to one N(4), one N(7), and one H(14) atom. The C(9)-N(4) bond length is 1.30 Å. The C(9)-N(7) bond length is 1.32 Å. The C(9)-H(14) bond length is 0.93 Å. In the fifth C site, C(15) is bonded in a trigonal planar geometry to one N(1), one N(12), and one H(24) atom. The C(15)-N(1) bond length is 1.33 Å. The C(15)-N(12) bond length is 1.36 Å. The C(15)-H(24) bond length is 0.93 Å. In the sixth C site, C(16) is bonded in a trigonal planar geometry to one N(12), one N(8), and one H(25) atom. The C(16)-N(12) bond length is 1.31 Å. The C(16)-N(8) bond length is 1.31 Å. The C(16)-H(25) bond length is 0.93 Å. In the seventh C site, C(20) is bonded in a 3-coordinate geometry to one N(8) and two equivalent H(31,32) atoms. The C(20)-N(8) bond length is 1.48 Å. Both C(20)-H(31,32) bond lengths are 0.97 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one C(15) and one N(8) atom. The N(1)-N(8) bond length is 1.36 Å. In the second N site, N(4) is bonded in a 3-coordinate geometry to one C(4), one C(9), and one N(9) atom. The N(4)-N(9) bond length is 1.37 Å. In the third N site, N(7) is bonded in a trigonal planar geometry to one Cu(2), one C(5), and one C(9) atom. In the fourth N site, N(8) is bonded in a 3-coordinate geometry to one C(16), one C(20), and one N(1) atom. In the fifth N site, N(9) is bonded in a distorted water-like geometry to one C(5) and one N(4) atom. In the sixth N site, N(12) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(15), and one C(16) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(24) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(25) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(31,32) is bonded in a single-bond geometry to one C(20) atom. Linkers: 4 [c]1ncn(CCCCCCn2cncn2)n1 ,2 c1ncn(CCCCCCn2cncn2)n1 ,2 [CH]1N=C[N]N1CCCCCCn1cncn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 7.07 A, density 0.92 g/cm3, surface area 5656.12 m2/g, accessible volume 0.59 cm3/g