Zn4C24H12O13(C5H6O2)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six C5H6O2 clusters and two Zn4C24H12O13 clusters. In each C5H6O2 cluster, there are ten inequivalent C sites. In the first C site, C(25) is bonded in a tetrahedral geometry to one H(8); two equivalent H(7,9); and one O(23) atom. The C(25)-H(8) bond length is 0.96 Å. Both C(25)-H(7,9) bond lengths are 0.96 Å. The C(25)-O(23) bond length is 1.44 Å. In the second C site, C(26) is bonded in a trigonal planar geometry to one C(24), one C(47), and one C(6) atom. The C(26)-C(24) bond length is 1.49 Å. The C(26)-C(47) bond length is 1.39 Å. The C(26)-C(6) bond length is 1.40 Å. In the third C site, C(36) is bonded in a tetrahedral geometry to three equivalent H(26,27,28) and one O(20) atom. All C(36)-H(26,27,28) bond lengths are 0.96 Å. The C(36)-O(20) bond length is 1.44 Å. In the fourth C site, C(38) is bonded in a tetrahedral geometry to one H(34); two equivalent H(32,33); and one O(9) atom. The C(38)-H(34) bond length is 0.96 Å. Both C(38)-H(32,33) bond lengths are 0.96 Å. The C(38)-O(9) bond length is 1.44 Å. In the fifth C site, C(47) is bonded in a distorted single-bond geometry to one C(26) and one O(24) atom. The C(47)-O(24) bond length is 1.36 Å. In the sixth C site, C(48) is bonded in a tetrahedral geometry to one H(42); two equivalent H(35,36,37,41,43); and one O(24) atom. The C(48)-H(42) bond length is 0.96 Å. Both C(48)-H(35,36,37,41,43) bond lengths are 0.96 Å. The C(48)-O(24) bond length is 1.43 Å. In the seventh C site, C(6) is bonded in a distorted single-bond geometry to one C(26) and one O(20) atom. The C(6)-O(20) bond length is 1.36 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(24) and one O(23) atom. The C(9)-C(24) bond length is 1.37 Å. The C(9)-O(23) bond length is 1.37 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(24) and one O(9) atom. The C(15)-C(24) bond length is 1.40 Å. The C(15)-O(9) bond length is 1.37 Å. In the tenth C site, C(24) is bonded in a trigonal planar geometry to one C(15), one C(26), and one C(9) atom. There are seven inequivalent H sites. In the first H site, H(7,9) is bonded in a single-bond geometry to one C(25) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(25) atom. In the third H site, H(26,27,28) is bonded in a single-bond geometry to one C(36) atom. In the fourth H site, H(32,33) is bonded in a single-bond geometry to one C(38) atom. In the fifth H site, H(34) is bonded in a single-bond geometry to one C(38) atom. In the sixth H site, H(35,36,37,41,43) is bonded in a single-bond geometry to one C(39) atom. The H(35,36,37,41,43)-C(39) bond length is 0.96 Å. In the seventh H site, H(42) is bonded in a single-bond geometry to one C(48) atom. There are four inequivalent O sites. In the first O site, O(9) is bonded in a bent 120 degrees geometry to one C(15) and one C(38) atom. In the second O site, O(20) is bonded in a bent 120 degrees geometry to one C(36) and one C(6) atom. In the third O site, O(23) is bonded in a bent 120 degrees geometry to one C(25) and one C(9) atom. In the fourth O site, O(24) is bonded in a bent 120 degrees geometry to one C(47) and one C(48) atom. In each Zn4C24H12O13 cluster, there are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(10), one O(13), and one O(14) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.90 Å. The Zn(1)-O(10) bond length is 1.91 Å. The Zn(1)-O(13) bond length is 1.97 Å. The Zn(1)-O(14) bond length is 1.96 Å. In the second Zn site, Zn(2) is bonded in a rectangular see-saw-like geometry to one O(1), one O(16), one O(4), and one O(6) atom. The Zn(2)-O(1) bond length is 2.01 Å. The Zn(2)-O(16) bond length is 2.28 Å. The Zn(2)-O(4) bond length is 2.09 Å. The Zn(2)-O(6) bond length is 2.09 Å. In the third Zn site, Zn(3) is bonded to one O(1), one O(2), one O(3), and one O(7) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(1) bond length is 1.92 Å. The Zn(3)-O(2) bond length is 1.94 Å. The Zn(3)-O(3) bond length is 1.96 Å. The Zn(3)-O(7) bond length is 1.97 Å. In the fourth Zn site, Zn(4) is bonded to one O(1), one O(11), one O(12), and one O(5) atom to form corner-sharing ZnO4 tetrahedra. The Zn(4)-O(1) bond length is 1.93 Å. The Zn(4)-O(11) bond length is 1.96 Å. The Zn(4)-O(12) bond length is 1.93 Å. The Zn(4)-O(5) bond length is 1.96 Å. There are twenty-four inequivalent C sites. In the first C site, C(30) is bonded in a distorted single-bond geometry to one C(11) and one H(13) atom. The C(30)-C(11) bond length is 1.38 Å. The C(30)-H(13) bond length is 0.93 Å. In the second C site, C(40) is bonded in a trigonal planar geometry to one C(22), one C(41), and one C(42) atom. The C(40)-C(22) bond length is 1.38 Å. The C(40)-C(41) bond length is 1.50 Å. The C(40)-C(42) bond length is 1.38 Å. In the third C site, C(41) is bonded in a bent 120 degrees geometry to one C(40), one O(12), and one O(16) atom. The C(41)-O(12) bond length is 1.26 Å. The C(41)-O(16) bond length is 1.26 Å. In the fourth C site, C(42) is bonded in a distorted single-bond geometry to one C(40) and one H(6,38) atom. The C(42)-H(6,38) bond length is 0.93 Å. In the fifth C site, C(43) is bonded in a distorted single-bond geometry to one C(44) and one H(39) atom. The C(43)-C(44) bond length is 1.37 Å. The C(43)-H(39) bond length is 0.93 Å. In the sixth C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(46) atom. The C(44)-C(45) bond length is 1.50 Å. The C(44)-C(46) bond length is 1.39 Å. In the seventh C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(44), one O(11), and one O(3) atom. The C(45)-O(11) bond length is 1.26 Å. The C(45)-O(3) bond length is 1.25 Å. In the eighth C site, C(46) is bonded in a distorted single-bond geometry to one C(44) and one H(40) atom. The C(46)-H(40) bond length is 0.93 Å. In the ninth C site, C(50) is bonded in a distorted single-bond geometry to one C(52) and one H(44) atom. The C(50)-C(52) bond length is 1.40 Å. The C(50)-H(44) bond length is 0.93 Å. In the tenth C site, C(51) is bonded in a distorted single-bond geometry to one C(52) and one H(45) atom. The C(51)-C(52) bond length is 1.37 Å. The C(51)-H(45) bond length is 0.93 Å. In the eleventh C site, C(52) is bonded in a trigonal planar geometry to one C(50), one C(51), and one C(53) atom. The C(52)-C(53) bond length is 1.51 Å. In the twelfth C site, C(53) is bonded in a distorted bent 120 degrees geometry to one C(52), one O(14), and one O(5) atom. The C(53)-O(14) bond length is 1.27 Å. The C(53)-O(5) bond length is 1.23 Å. In the thirteenth C site, C(2) is bonded in a distorted single-bond geometry to one C(12) and one H(1,2) atom. The C(2)-C(12) bond length is 1.38 Å. The C(2)-H(1,2) bond length is 0.93 Å. In the fourteenth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(13), and one O(7) atom. The C(4)-C(12) bond length is 1.50 Å. The C(4)-O(13) bond length is 1.24 Å. The C(4)-O(7) bond length is 1.26 Å. In the fifteenth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(2), and one O(6) atom. The C(5)-C(11) bond length is 1.51 Å. The C(5)-O(2) bond length is 1.27 Å. The C(5)-O(6) bond length is 1.24 Å. In the sixteenth C site, C(8) is bonded in a distorted single-bond geometry to one C(12) and one H(1,2) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-H(1,2) bond length is 0.93 Å. In the seventeenth C site, C(11) is bonded in a trigonal planar geometry to one C(13), one C(30), and one C(5) atom. The C(11)-C(13) bond length is 1.40 Å. In the eighteenth C site, C(12) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. In the nineteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(11) and one H(3) atom. The C(13)-H(3) bond length is 0.93 Å. In the twentieth C site, C(14) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(23) atom. The C(14)-C(17) bond length is 1.37 Å. The C(14)-C(18) bond length is 1.40 Å. The C(14)-C(23) bond length is 1.49 Å. In the twenty-first C site, C(17) is bonded in a distorted single-bond geometry to one C(14) and one H(4,5) atom. The C(17)-H(4,5) bond length is 0.93 Å. In the twenty-second C site, C(18) is bonded in a distorted single-bond geometry to one C(14) and one H(4,5) atom. The C(18)-H(4,5) bond length is 0.93 Å. In the twenty-third C site, C(22) is bonded in a distorted single-bond geometry to one C(40) and one H(6,38) atom. The C(22)-H(6,38) bond length is 0.93 Å. In the twenty-fourth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(10), and one O(4) atom. The C(23)-O(10) bond length is 1.27 Å. The C(23)-O(4) bond length is 1.24 Å. There are nine inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(4,5) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(6,38) is bonded in a single-bond geometry to one C(22) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(30) atom. In the sixth H site, H(39) is bonded in a single-bond geometry to one C(43) atom. In the seventh H site, H(40) is bonded in a single-bond geometry to one C(46) atom. In the eighth H site, H(44) is bonded in a single-bond geometry to one C(50) atom. In the ninth H site, H(45) is bonded in a single-bond geometry to one C(51) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a tetrahedral geometry to one Zn(1), one Zn(2), one Zn(3), and one Zn(4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(5) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(45) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(23) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(53) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(5) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(4) atom. In the eighth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(23) atom. In the ninth O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(45) atom. In the tenth O site, O(12) is bonded in a water-like geometry to one Zn(4) and one C(41) atom. In the eleventh O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the twelfth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(53) atom. In the thirteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(41) atom. Linkers: 6 COc1cc(C([O])=O)cc(OC)c1-c1c(OC)cc(C([O])=O)cc1OC. Metal clusters: 2 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: pcu. The MOF has largest included sphere 9.00 A, density 0.94 g/cm3, surface area 4570.35 m2/g, accessible volume 0.60 cm3/g