CuC36H28(NO2)4 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CuC36H28(NO2)4 clusters. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(2), one N(3), one N(5), and one N(6) atom. The Cu(1)-N(2) bond length is 2.03 Å. The Cu(1)-N(3) bond length is 2.02 Å. The Cu(1)-N(5) bond length is 2.03 Å. The Cu(1)-N(6) bond length is 2.02 Å. In the second Cu site, Cu(2) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(4) atoms. Both Cu(2)-N(1) bond lengths are 2.03 Å. Both Cu(2)-N(4) bond lengths are 2.04 Å. There are fifty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.36 Å. The C(2)-H(2) bond length is 0.95 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.35 Å. The C(3)-C(6) bond length is 1.48 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.30 Å. The C(5)-H(4) bond length is 0.95 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.26 Å. The C(6)-O(2) bond length is 1.28 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(24), one H(5), one H(6), and one O(2) atom. The C(7)-C(24) bond length is 1.51 Å. The C(7)-H(5) bond length is 0.99 Å. The C(7)-H(6) bond length is 0.99 Å. The C(7)-O(2) bond length is 1.46 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(2), and one H(7) atom. The C(8)-C(9) bond length is 1.37 Å. The C(8)-N(2) bond length is 1.33 Å. The C(8)-H(7) bond length is 0.95 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(8) atom. The C(9)-C(10) bond length is 1.35 Å. The C(9)-H(8) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(9) atom. The C(10)-C(11) bond length is 1.37 Å. The C(10)-C(13) bond length is 1.48 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(9) atom. The C(11)-C(12) bond length is 1.37 Å. The C(11)-H(9) bond length is 0.95 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(2), and one H(10) atom. The C(12)-N(2) bond length is 1.33 Å. The C(12)-H(10) bond length is 0.95 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(4) atom. The C(13)-O(3) bond length is 1.21 Å. The C(13)-O(4) bond length is 1.31 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to one C(26), one H(11), one H(12), and one O(4) atom. The C(14)-C(26) bond length is 1.47 Å. The C(14)-H(11) bond length is 0.99 Å. The C(14)-H(12) bond length is 0.99 Å. The C(14)-O(4) bond length is 1.48 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(13) atom. The C(15)-N(3) bond length is 1.33 Å. The C(15)-H(13) bond length is 0.95 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(14) atom. The C(16)-C(17) bond length is 1.35 Å. The C(16)-H(14) bond length is 0.95 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.33 Å. The C(17)-C(20) bond length is 1.54 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(15) atom. The C(18)-H(15) bond length is 0.95 Å. In the nineteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(16) atom. The C(19)-N(3) bond length is 1.34 Å. The C(19)-H(16) bond length is 0.95 Å. In the twentieth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(5), and one O(6) atom. The C(20)-O(5) bond length is 1.22 Å. The C(20)-O(6) bond length is 1.29 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one C(22), one H(17), one H(18), and one O(6) atom. The C(21)-C(22) bond length is 1.48 Å. The C(21)-H(17) bond length is 0.99 Å. The C(21)-H(18) bond length is 0.98 Å. The C(21)-O(6) bond length is 1.46 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(27) atom. The C(22)-C(23) bond length is 1.35 Å. The C(22)-C(27) bond length is 1.40 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(22), one C(24), and one H(19) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-H(19) bond length is 0.95 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(7) atom. The C(24)-C(25) bond length is 1.36 Å. In the twenty-fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(24), one C(26), and one H(20) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-H(20) bond length is 0.95 Å. In the twenty-sixth C site, C(26) is bonded in a trigonal planar geometry to one C(14), one C(25), and one C(27) atom. The C(26)-C(27) bond length is 1.39 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(22), one C(26), and one H(21) atom. The C(27)-H(21) bond length is 0.95 Å. In the twenty-eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(29), one N(4), and one H(22) atom. The C(28)-C(29) bond length is 1.36 Å. The C(28)-N(4) bond length is 1.33 Å. The C(28)-H(22) bond length is 0.95 Å. In the twenty-ninth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one C(30), and one H(23) atom. The C(29)-C(30) bond length is 1.41 Å. The C(29)-H(23) bond length is 0.95 Å. In the thirtieth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(33) atom. The C(30)-C(31) bond length is 1.36 Å. The C(30)-C(33) bond length is 1.49 Å. In the thirty-first C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(24) atom. The C(31)-H(24) bond length is 0.95 Å. In the thirty-second C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(25) atom. The C(32)-N(4) bond length is 1.36 Å. The C(32)-H(25) bond length is 0.95 Å. In the thirty-third C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(7), and one O(8) atom. The C(33)-O(7) bond length is 1.20 Å. The C(33)-O(8) bond length is 1.33 Å. In the thirty-fourth C site, C(34) is bonded in a distorted trigonal non-coplanar geometry to one C(49), one H(26), one H(27), and one O(8) atom. The C(34)-C(49) bond length is 1.50 Å. The C(34)-H(26) bond length is 0.99 Å. The C(34)-H(27) bond length is 0.99 Å. The C(34)-O(8) bond length is 1.48 Å. In the thirty-fifth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(28) atom. The C(35)-N(5) bond length is 1.30 Å. The C(35)-H(28) bond length is 0.95 Å. In the thirty-sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(37) and one H(29) atom. The C(36)-C(37) bond length is 1.34 Å. The C(36)-H(29) bond length is 0.95 Å. In the thirty-seventh C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one C(40) atom. The C(37)-C(38) bond length is 1.34 Å. The C(37)-C(40) bond length is 1.50 Å. In the thirty-eighth C site, C(38) is bonded in a distorted single-bond geometry to one C(37) and one H(30) atom. The C(38)-H(30) bond length is 0.96 Å. In the thirty-ninth C site, C(39) is bonded in a bent 120 degrees geometry to one N(5) and one H(31) atom. The C(39)-N(5) bond length is 1.26 Å. The C(39)-H(31) bond length is 0.95 Å. In the fortieth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(10), and one O(9) atom. The C(40)-O(10) bond length is 1.25 Å. The C(40)-O(9) bond length is 1.20 Å. In the forty-first C site, C(41) is bonded in a distorted trigonal non-coplanar geometry to one C(51), one H(32), one H(33), and one O(10) atom. The C(41)-C(51) bond length is 1.63 Å. The C(41)-H(32) bond length is 0.99 Å. The C(41)-H(33) bond length is 0.99 Å. The C(41)-O(10) bond length is 1.44 Å. In the forty-second C site, C(42) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(34) atom. The C(42)-N(6) bond length is 1.31 Å. The C(42)-H(34) bond length is 0.95 Å. In the forty-third C site, C(43) is bonded in a distorted single-bond geometry to one C(44) and one H(35) atom. The C(43)-C(44) bond length is 1.37 Å. The C(43)-H(35) bond length is 0.95 Å. In the forty-fourth C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(47) atom. The C(44)-C(45) bond length is 1.38 Å. The C(44)-C(47) bond length is 1.43 Å. In the forty-fifth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(44), one C(46), and one H(36) atom. The C(45)-C(46) bond length is 1.37 Å. The C(45)-H(36) bond length is 0.95 Å. In the forty-sixth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one C(45), one N(6), and one H(37) atom. The C(46)-N(6) bond length is 1.35 Å. The C(46)-H(37) bond length is 0.95 Å. In the forty-seventh C site, C(47) is bonded in a distorted bent 120 degrees geometry to one C(44), one O(11), and one O(12) atom. The C(47)-O(11) bond length is 1.21 Å. The C(47)-O(12) bond length is 1.30 Å. In the forty-eighth C site, C(48) is bonded in a distorted trigonal non-coplanar geometry to one C(53); two equivalent H(38,39); and one O(12) atom. The C(48)-C(53) bond length is 1.47 Å. Both C(48)-H(38,39) bond lengths are 0.99 Å. The C(48)-O(12) bond length is 1.44 Å. In the forty-ninth C site, C(49) is bonded in a trigonal planar geometry to one C(34), one C(50), and one C(54) atom. The C(49)-C(50) bond length is 1.40 Å. The C(49)-C(54) bond length is 1.38 Å. In the fiftieth C site, C(50) is bonded in a distorted single-bond geometry to one C(49), one C(51), and one H(40) atom. The C(50)-C(51) bond length is 1.36 Å. The C(50)-H(40) bond length is 0.95 Å. In the fifty-first C site, C(51) is bonded in a trigonal planar geometry to one C(41), one C(50), and one C(52) atom. The C(51)-C(52) bond length is 1.42 Å. In the fifty-second C site, C(52) is bonded in a distorted single-bond geometry to one C(51), one C(53), and one H(41) atom. The C(52)-C(53) bond length is 1.40 Å. The C(52)-H(41) bond length is 0.95 Å. In the fifty-third C site, C(53) is bonded in a trigonal planar geometry to one C(48), one C(52), and one C(54) atom. The C(53)-C(54) bond length is 1.37 Å. In the fifty-fourth C site, C(54) is bonded in a distorted single-bond geometry to one C(49), one C(53), and one H(42) atom. The C(54)-H(42) bond length is 0.95 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(2), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(12), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(15), and one C(19) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(28), and one C(32) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(1), one C(35), and one C(39) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(42), and one C(46) atom. There are forty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(21) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(27) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(28) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(29) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(31) atom. In the twenty-fifth H site, H(25) is bonded in a single-bond geometry to one C(32) atom. In the twenty-sixth H site, H(26) is bonded in a single-bond geometry to one C(34) atom. In the twenty-seventh H site, H(27) is bonded in a single-bond geometry to one C(34) atom. In the twenty-eighth H site, H(28) is bonded in a single-bond geometry to one C(35) atom. In the twenty-ninth H site, H(29) is bonded in a single-bond geometry to one C(36) atom. In the thirtieth H site, H(30) is bonded in a single-bond geometry to one C(38) atom. In the thirty-first H site, H(31) is bonded in a single-bond geometry to one C(39) atom. In the thirty-second H site, H(32) is bonded in a single-bond geometry to one C(41) atom. In the thirty-third H site, H(33) is bonded in a single-bond geometry to one C(41) atom. In the thirty-fourth H site, H(34) is bonded in a single-bond geometry to one C(42) atom. In the thirty-fifth H site, H(35) is bonded in a single-bond geometry to one C(43) atom. In the thirty-sixth H site, H(36) is bonded in a single-bond geometry to one C(45) atom. In the thirty-seventh H site, H(37) is bonded in a single-bond geometry to one C(46) atom. In the thirty-eighth H site, H(38,39) is bonded in a single-bond geometry to one C(48) atom. In the thirty-ninth H site, H(40) is bonded in a single-bond geometry to one C(50) atom. In the fortieth H site, H(41) is bonded in a single-bond geometry to one C(52) atom. In the forty-first H site, H(42) is bonded in a single-bond geometry to one C(54) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(6) and one C(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(13) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(13) and one C(14) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(20) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one C(20) and one C(21) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(33) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one C(33) and one C(34) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(40) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one C(40) and one C(41) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one C(47) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one C(47) and one C(48) atom. Linkers: 1 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,4 O=C(OCc1cc(COC(=O)c2ccncc2)cc(COC(=O)c2ccncc2)c1)c1ccncc1. Metal clusters: 6 [Cu]. The MOF has largest included sphere 9.23 A, density 0.80 g/cm3, surface area 5110.62 m2/g, accessible volume 0.78 cm3/g