(RhC8H8(N2Cl)2)2Cu5C44H24(NO11)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four Cu5C44H24(NO11)2 clusters and eight RhC8H8(N2Cl)2 clusters. In each Cu5C44H24(NO11)2 cluster, there are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a trigonal bipyramidal geometry to one N(5), one O(2), one O(3), one O(6), and one O(7) atom. The Cu(1)-N(5) bond length is 2.03 Å. The Cu(1)-O(2) bond length is 1.98 Å. The Cu(1)-O(3) bond length is 1.94 Å. The Cu(1)-O(6) bond length is 2.22 Å. The Cu(1)-O(7) bond length is 1.96 Å. In the second Cu site, Cu(2) is bonded in a trigonal bipyramidal geometry to one O(1), one O(11), one O(5), one O(8), and one O(9) atom. The Cu(2)-O(1) bond length is 1.95 Å. The Cu(2)-O(11) bond length is 1.98 Å. The Cu(2)-O(5) bond length is 1.95 Å. The Cu(2)-O(8) bond length is 1.98 Å. The Cu(2)-O(9) bond length is 2.14 Å. In the third Cu site, Cu(3) is bonded in a rectangular see-saw-like geometry to two equivalent O(10) and two equivalent O(11) atoms. Both Cu(3)-O(10) bond lengths are 1.95 Å. Both Cu(3)-O(11) bond lengths are 1.89 Å. There are twenty-two inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 0.95 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-C(6) bond length is 1.49 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.95 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.26 Å. The C(6)-O(2) bond length is 1.26 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(6) bond length is 0.95 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(8) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(12) bond length is 1.52 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(7) atom. The C(10)-H(7) bond length is 0.95 Å. In the eighth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(12)-O(3) bond length is 1.28 Å. The C(12)-O(4) bond length is 1.22 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(10) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(10) bond length is 0.95 Å. In the tenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-C(18) bond length is 1.51 Å. In the eleventh C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(11) atom. The C(16)-H(11) bond length is 0.95 Å. In the twelfth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(5), and one O(6) atom. The C(18)-O(5) bond length is 1.26 Å. The C(18)-O(6) bond length is 1.26 Å. In the thirteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(14) atom. The C(20)-C(21) bond length is 1.37 Å. The C(20)-H(14) bond length is 0.95 Å. In the fourteenth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(21)-C(22) bond length is 1.41 Å. The C(21)-C(24) bond length is 1.51 Å. In the fifteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(15) atom. The C(22)-H(15) bond length is 0.95 Å. In the sixteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(7), and one O(8) atom. The C(24)-O(7) bond length is 1.26 Å. The C(24)-O(8) bond length is 1.25 Å. In the seventeenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(17) atom. The C(25)-N(5) bond length is 1.37 Å. The C(25)-H(17) bond length is 0.95 Å. In the eighteenth C site, C(26) is bonded in a single-bond geometry to one C(27) and one H(18) atom. The C(26)-C(27) bond length is 1.36 Å. The C(26)-H(18) bond length is 0.95 Å. In the nineteenth C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(30) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-C(30) bond length is 1.52 Å. In the twentieth C site, C(28) is bonded in a distorted single-bond geometry to one C(27) and one H(19) atom. The C(28)-H(19) bond length is 0.95 Å. In the twenty-first C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(20) atom. The C(29)-N(5) bond length is 1.33 Å. The C(29)-H(20) bond length is 0.95 Å. In the twenty-second C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(10), and one O(9) atom. The C(30)-O(10) bond length is 1.27 Å. The C(30)-O(9) bond length is 1.25 Å. N(5) is bonded in a trigonal planar geometry to one Cu(1), one C(25), and one C(29) atom. There are twelve inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(28) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(29) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(6) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one C(6) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(12) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(12) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(18) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to one Cu(1) and one C(18) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(24) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(24) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(30) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one C(30) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Cu(2) and one Cu(3) atom. In each RhC8H8(N2Cl)2 cluster, Rh(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one Cl(1), and one Cl(2) atom. The Rh(1)-N(1) bond length is 2.05 Å. The Rh(1)-N(2) bond length is 2.05 Å. The Rh(1)-N(3) bond length is 2.06 Å. The Rh(1)-N(4) bond length is 2.06 Å. The Rh(1)-Cl(1) bond length is 2.33 Å. The Rh(1)-Cl(2) bond length is 2.34 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.36 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5) atom. The C(7)-N(2) bond length is 1.35 Å. The C(7)-H(5) bond length is 0.95 Å. In the fourth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(8) bond length is 0.95 Å. In the fifth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(13)-N(3) bond length is 1.33 Å. The C(13)-H(9) bond length is 0.95 Å. In the sixth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(12) atom. The C(17)-N(3) bond length is 1.35 Å. The C(17)-H(12) bond length is 0.95 Å. In the seventh C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(13) atom. The C(19)-N(4) bond length is 1.33 Å. The C(19)-H(13) bond length is 0.95 Å. In the eighth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(16) atom. The C(23)-N(4) bond length is 1.36 Å. The C(23)-H(16) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Rh(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Rh(1), one C(11), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Rh(1), one C(13), and one C(17) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Rh(1), one C(19), and one C(23) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Rh(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Rh(1) atom. Linkers: 3 [O]C(=O)C1=C[CH]N([Rh](Cl)(Cl)(N2[CH]C=C(C([O])=O)C=C2)(N2[CH]C=C(C([O])=O)C=C2)N2[CH]C=C(C([O])=O)C=C2)C=C1 ,1 [O][C]C1=C[CH]N([Rh](Cl)(Cl)(N2[CH]C=C(C([O])=O)C=C2)(N2[CH]C=C(C([O])=O)C=C2)N2[CH]C=C(C([O])=O)C=C2)C=C1 ,4 [O]C(=O)c1ccncc1. Metal clusters: 2 O=[C]O[Cu]123O[C]O[Cu]14(O[C]O[Cu]1(O[C]O[Cu]567(O[C]O[Cu]5(O[C]=O)(O[C]O6)O[C]O7)O1)O4)(O[C]O2)O[C]O3. The MOF has largest included sphere 4.23 A, density 1.70 g/cm3, surface area 3565.41 m2/g, accessible volume 0.20 cm3/g