ZnC14NH10O4(C3H2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 2,3-dimethyl-1,3-butadiene molecules and four ZnC14NH10O4 clusters. In each ZnC14NH10O4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 1.94 Å. The Zn(1)-O(3) bond length is 1.95 Å. The Zn(1)-O(4) bond length is 1.97 Å. There are fourteen inequivalent C sites. In the first C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(6) bond length is 0.95 Å. In the second C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(14) bond length is 1.48 Å. In the third C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 0.95 Å. In the fourth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.26 Å. The C(14)-O(4) bond length is 1.27 Å. In the fifth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(15)-N(1) bond length is 1.39 Å. The C(15)-H(9) bond length is 0.95 Å. In the sixth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(10) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(10) bond length is 0.95 Å. In the seventh C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-C(20) bond length is 1.51 Å. In the eighth C site, C(18) is bonded in a single-bond geometry to one C(17), one C(19), and one H(11) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(11) bond length is 0.95 Å. In the ninth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(1), and one H(12) atom. The C(19)-N(1) bond length is 1.39 Å. The C(19)-H(12) bond length is 0.95 Å. In the tenth C site, C(20) is bonded in a water-like geometry to one C(17) and two equivalent H(13,14) atoms. Both C(20)-H(13,14) bond lengths are 0.99 Å. In the eleventh C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.23 Å. In the twelfth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.39 Å. In the thirteenth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1,4) atom. The C(3)-H(1,4) bond length is 0.95 Å. In the fourteenth C site, C(7) is bonded in a single-bond geometry to one C(2) and one H(1,4) atom. The C(7)-H(1,4) bond length is 0.95 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(19) atom. There are eight inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(13,14) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. Linkers: 2 [O][C]c1[c]cc(-c2ccc(C([O])=O)cc2)cc1 ,2 c1cc(CCc2ccncc2)ccn1 ,2 [O]C(=O)c1ccc(-c2ccc([C]=O)cc2)cc1 ,4 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 O=[C]O[Zn]1O[C]O[Zn](O[C]=O)O[C]O1. The MOF has largest included sphere 5.09 A, density 1.27 g/cm3, surface area 4721.57 m2/g, accessible volume 0.36 cm3/g