CuH24(C4N3)4CuH16(CN)12(CH2)16 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, one CuH16(CN)12 cluster, and one CuH24(C4N3)4 cluster. In the CuH16(CN)12 cluster, Cu(2) is bonded in a square co-planar geometry to two equivalent N(12) and two equivalent N(6) atoms. Both Cu(2)-N(12) bond lengths are 2.01 Å. Both Cu(2)-N(6) bond lengths are 2.00 Å. There are six inequivalent C sites. In the first C site, C(6) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(9) atom. The C(6)-N(5) bond length is 1.29 Å. The C(6)-N(6) bond length is 1.35 Å. The C(6)-H(9) bond length is 0.93 Å. In the second C site, C(7) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(10) atom. The C(7)-N(4) bond length is 1.30 Å. The C(7)-N(6) bond length is 1.31 Å. The C(7)-H(10) bond length is 0.93 Å. In the third C site, C(8) is bonded in a 3-coordinate geometry to one N(4) and two equivalent H(11,12) atoms. The C(8)-N(4) bond length is 1.47 Å. Both C(8)-H(11,12) bond lengths are 0.97 Å. In the fourth C site, C(18) is bonded in a 3-coordinate geometry to one N(10) and two equivalent H(29,30) atoms. The C(18)-N(10) bond length is 1.46 Å. Both C(18)-H(29,30) bond lengths are 0.97 Å. In the fifth C site, C(19) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(31) atom. The C(19)-N(11) bond length is 1.32 Å. The C(19)-N(12) bond length is 1.32 Å. The C(19)-H(31) bond length is 0.93 Å. In the sixth C site, C(20) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(32) atom. The C(20)-N(10) bond length is 1.30 Å. The C(20)-N(12) bond length is 1.29 Å. The C(20)-H(32) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(11) is bonded in a distorted water-like geometry to one C(19) and one N(10) atom. The N(11)-N(10) bond length is 1.33 Å. In the second N site, N(12) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(19), and one C(20) atom. In the third N site, N(4) is bonded in a distorted trigonal planar geometry to one C(7), one C(8), and one N(5) atom. The N(4)-N(5) bond length is 1.33 Å. In the fourth N site, N(5) is bonded in a distorted water-like geometry to one C(6) and one N(4) atom. In the fifth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(6), and one C(7) atom. In the sixth N site, N(10) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one N(11) atom. There are six inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(11,12) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(29,30) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(31) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(32) is bonded in a single-bond geometry to one C(20) atom. In the CuH24(C4N3)4 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(3) and two equivalent N(9) atoms. Both Cu(1)-N(3) bond lengths are 2.03 Å. Both Cu(1)-N(9) bond lengths are 2.00 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(1) atom. The C(1)-N(2) bond length is 1.30 Å. The C(1)-N(3) bond length is 1.36 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(2) atom. The C(2)-N(1) bond length is 1.32 Å. The C(2)-N(3) bond length is 1.32 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a 3-coordinate geometry to one N(1) and two equivalent H(3,4) atoms. The C(3)-N(1) bond length is 1.46 Å. Both C(3)-H(3,4) bond lengths are 0.97 Å. In the fourth C site, C(11) is bonded in a trigonal planar geometry to one N(8), one N(9), and one H(17) atom. The C(11)-N(8) bond length is 1.30 Å. The C(11)-N(9) bond length is 1.35 Å. The C(11)-H(17) bond length is 0.93 Å. In the fifth C site, C(12) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(18) atom. The C(12)-N(7) bond length is 1.32 Å. The C(12)-N(9) bond length is 1.31 Å. The C(12)-H(18) bond length is 0.93 Å. In the sixth C site, C(13) is bonded in a 2-coordinate geometry to one N(7), one H(19), and one H(20) atom. The C(13)-N(7) bond length is 1.54 Å. The C(13)-H(19) bond length is 0.97 Å. The C(13)-H(20) bond length is 0.97 Å. In the seventh C site, C(21) is bonded in a 2-coordinate geometry to one N(7), one H(33), and one H(34) atom. The C(21)-N(7) bond length is 1.57 Å. The C(21)-H(33) bond length is 0.97 Å. The C(21)-H(34) bond length is 0.97 Å. In the eighth C site, C(22) is bonded in a 2-coordinate geometry to one H(20), one H(35), and one H(36) atom. The C(22)-H(20) bond length is 1.18 Å. The C(22)-H(35) bond length is 0.97 Å. The C(22)-H(36) bond length is 0.97 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one C(2), one C(3), and one N(2) atom. The N(1)-N(2) bond length is 1.35 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(1) and one N(1) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the fourth N site, N(7) is bonded in a 4-coordinate geometry to one C(12), one C(13), one C(21), and one N(8) atom. The N(7)-N(8) bond length is 1.36 Å. In the fifth N site, N(8) is bonded in a distorted water-like geometry to one C(11) and one N(7) atom. In the sixth N site, N(9) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(12) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(20) is bonded in a 3-coordinate geometry to one C(13), one C(22), and one H(36) atom. The H(20)-H(36) bond length is 0.64 Å. In the eighth H site, H(33) is bonded in a distorted single-bond geometry to one C(21) atom. In the ninth H site, H(34) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(35) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(36) is bonded in a distorted single-bond geometry to one C(22) and one H(20) atom. Linkers: 2 c1ncn(CCCCCCn2cncn2)n1 ,2 C1=NN=C[N]1.C1CCC1.[CH2]CCCn1cncn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 7.07 A, density 0.97 g/cm3, surface area 5444.17 m2/g, accessible volume 0.48 cm3/g