CoC12H8(NO2)2CoC26H16(NO)4(CH)4(C3H2)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; three 2,3-dimethyl-1,3-butadiene molecules; one CoC12H8(NO2)2 cluster; and one CoC26H16(NO)4 cluster. In the CoC12H8(NO2)2 cluster, Co(1) is bonded in a square co-planar geometry to two equivalent N(3) and two equivalent O(4) atoms. Both Co(1)-N(3) bond lengths are 2.12 Å. Both Co(1)-O(4) bond lengths are 2.04 Å. There are six inequivalent C sites. In the first C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17,20) atom. The C(26)-N(3) bond length is 1.33 Å. The C(26)-H(17,20) bond length is 0.93 Å. In the second C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17,20) atom. The C(30)-N(3) bond length is 1.33 Å. The C(30)-H(17,20) bond length is 0.93 Å. In the third C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(8)-C(9) bond length is 1.49 Å. The C(8)-O(3) bond length is 1.26 Å. The C(8)-O(4) bond length is 1.26 Å. In the fourth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(14) bond length is 1.40 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(10)-H(5) bond length is 0.93 Å. In the sixth C site, C(14) is bonded in a single-bond geometry to one C(9) and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. N(3) is bonded in a trigonal planar geometry to one Co(1), one C(26), and one C(30) atom. There are three inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(17,20) is bonded in a single-bond geometry to one C(26) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(8) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(8) atom. In the CoC26H16(NO)4 cluster, Co(2) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent O(2) atoms. Both Co(2)-N(2) bond lengths are 2.18 Å. Both Co(2)-O(2) bond lengths are 2.08 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.38 Å. The C(5)-N(1) bond length is 1.44 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(3) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(3) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one N(1) atom. The C(12)-N(1) bond length is 1.39 Å. In the ninth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(15)-N(2) bond length is 1.34 Å. The C(15)-H(9) bond length is 0.93 Å. In the tenth C site, C(19) is bonded in a 2-coordinate geometry to one N(2) and one H(12) atom. The C(19)-N(2) bond length is 1.33 Å. The C(19)-H(12) bond length is 0.93 Å. In the eleventh C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(14) atom. The C(22)-C(23) bond length is 1.38 Å. The C(22)-H(14) bond length is 0.93 Å. In the twelfth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one N(1) atom. The C(23)-C(24) bond length is 1.38 Å. The C(23)-N(1) bond length is 1.43 Å. In the thirteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(15) atom. The C(24)-H(15) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(12), one C(23), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(2), one C(15), and one C(19) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(24) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(1) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1 ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=N[Co].[CH]=[CH].[CH][C]=[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/C=C\[C]=N/[C]=[CH].[C]/[C]=C\[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]N([C])[Co](O[C]=O)O[C]=O.[C][CH].[C][CH].[C][C][C].[C][C][C].[C][N].[C][N].[C][N][C]([C])[C].[Co].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[O].[O].[O].[O].[O][C]=O.[O][C]=O ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=N[Co](O[C]=O)O[C]=O.[CH]=[CH].[CH][C]=[CH].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/[C]=C(\[C])C([C])=[CH].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]N=[CH].[C][CH].[C][CH].[C][C]=[CH].[C][C]=[CH].[C][C][C].[C][N].[C][N].[Co].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N][Co].[N][Co].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=N[Co]([O])[O].[CH]=[CH].[CH][C]=[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]N([CH])[Co].[C][CH].[C][CH].[C][C]=[CH].[C][C][C].[C][C][C].[C][C][C].[C][N].[C][N].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N][Co].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O]. Metal clusters: 1 O=[C]O[Co]O[C]=O. The MOF has largest included sphere 6.95 A, density 0.87 g/cm3, surface area 5119.55 m2/g, accessible volume 0.58 cm3/g