LaC24H20(NO2)4 is Indium-like structured and crystallizes in the orthorhombic Fddd space group. The structure is zero-dimensional and consists of eight LaC24H20(NO2)4 clusters. La(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Both La(1)-O(1) bond lengths are 2.50 Å. Both La(1)-O(2) bond lengths are 2.50 Å. Both La(1)-O(3) bond lengths are 2.53 Å. Both La(1)-O(4) bond lengths are 2.48 Å. There are twelve inequivalent C sites. In the first C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(3), and one O(4) atom. The C(2)-C(1) bond length is 1.51 Å. The C(2)-O(3) bond length is 1.24 Å. The C(2)-O(4) bond length is 1.25 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(1) and one H(1,6) atom. The C(3)-C(1) bond length is 1.38 Å. The C(3)-H(1,6) bond length is 0.93 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(4)-N(1) bond length is 1.33 Å. The C(4)-H(2) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(10), one C(6), and one H(3) atom. The C(5)-C(10) bond length is 1.38 Å. The C(5)-C(6) bond length is 1.36 Å. The C(5)-H(3) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(2), and one H(4) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-H(4) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(7)-N(1) bond length is 1.34 Å. The C(7)-H(5) bond length is 0.93 Å. In the seventh C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(8) atom. The C(1)-C(8) bond length is 1.38 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(7) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(12) bond length is 1.37 Å. The C(9)-H(7) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(5), and one C(9) atom. The C(10)-C(11) bond length is 1.50 Å. In the tenth C site, C(11) is bonded in a water-like geometry to one C(10) and two equivalent H(8,9) atoms. Both C(11)-H(8,9) bond lengths are 0.97 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(10) atom. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(10) bond length is 0.93 Å. In the twelfth C site, C(8) is bonded in a distorted single-bond geometry to one C(1) and one H(1,6) atom. The C(8)-H(1,6) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(4), one C(7), and one O(1) atom. The N(1)-O(1) bond length is 1.32 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(12), one C(6), and one O(2) atom. The N(2)-O(2) bond length is 1.32 Å. There are eight inequivalent H sites. In the first H site, H(1,6) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8,9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one La(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one La(1) and one N(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one La(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one La(1) and one C(2) atom. Linkers: 16 [O-][n+]1ccc(CCc2cc[n+]([O-])cc2)cc1 ,32 [O]C(=O)c1cc[n+]([O-])cc1. Metal clusters: 8 [O][La]123([O])([O])([O])O[C]O[La]([O])([O])([O])([O])(O[C]O1)(O[C]O2)O[C]O3. RCSR code: tsi. The MOF has largest included sphere 5.38 A, density 1.39 g/cm3, surface area 4060.55 m2/g, accessible volume 0.30 cm3/g