(Gd2C7H2O12)2(CH2)21(CH)7(H8(C2N)3)2(C5N3H7)2C11N6H15(C3H4N2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of fourteen 02329_fluka molecules, forty-two 02329_fluka molecules, two C11N6H15 clusters, two C3H4N2 clusters, two C5N3H7 clusters, four Gd2C7H2O12 clusters, and two H8(C2N)3 clusters. In each C11N6H15 cluster, there are eleven inequivalent C sites. In the first C site, C(43) is bonded in a trigonal planar geometry to one N(13), one N(15), and one N(16) atom. The C(43)-N(13) bond length is 1.36 Å. The C(43)-N(15) bond length is 1.37 Å. The C(43)-N(16) bond length is 1.35 Å. In the second C site, C(44) is bonded in a trigonal planar geometry to one N(13), one N(14), and one N(17) atom. The C(44)-N(13) bond length is 1.35 Å. The C(44)-N(14) bond length is 1.33 Å. The C(44)-N(17) bond length is 1.34 Å. In the third C site, C(45) is bonded in a trigonal planar geometry to one N(14), one N(15), and one N(18) atom. The C(45)-N(14) bond length is 1.37 Å. The C(45)-N(15) bond length is 1.28 Å. The C(45)-N(18) bond length is 1.35 Å. In the fourth C site, C(46) is bonded in a 4-coordinate geometry to one C(47), one N(16), one H(55), and one H(56) atom. The C(46)-C(47) bond length is 1.47 Å. The C(46)-N(16) bond length is 1.48 Å. The C(46)-H(55) bond length is 0.97 Å. The C(46)-H(56) bond length is 0.97 Å. In the fifth C site, C(47) is bonded in a water-like geometry to one C(46) and two equivalent H(57,58) atoms. Both C(47)-H(57,58) bond lengths are 0.97 Å. In the sixth C site, C(50) is bonded in a distorted trigonal non-coplanar geometry to one N(16) and two equivalent H(62,63) atoms. The C(50)-N(16) bond length is 1.46 Å. Both C(50)-H(62,63) bond lengths are 0.97 Å. In the seventh C site, C(52) is bonded in a 4-coordinate geometry to one C(53); one N(17); and two equivalent H(64,65) atoms. The C(52)-C(53) bond length is 1.45 Å. The C(52)-N(17) bond length is 1.50 Å. Both C(52)-H(64,65) bond lengths are 0.97 Å. In the eighth C site, C(53) is bonded in a single-bond geometry to one C(52) and one H(66) atom. The C(53)-H(66) bond length is 0.98 Å. In the ninth C site, C(56) is bonded in a distorted trigonal non-coplanar geometry to one N(17) and two equivalent H(71,72) atoms. The C(56)-N(17) bond length is 1.41 Å. Both C(56)-H(71,72) bond lengths are 0.97 Å. In the tenth C site, C(58) is bonded in a distorted trigonal non-coplanar geometry to one N(18), one H(73), and one H(74) atom. The C(58)-N(18) bond length is 1.40 Å. The C(58)-H(73) bond length is 0.97 Å. The C(58)-H(74) bond length is 0.97 Å. In the eleventh C site, C(62) is bonded in a distorted trigonal non-coplanar geometry to one N(18), one H(80), and one H(81) atom. The C(62)-N(18) bond length is 1.45 Å. The C(62)-H(80) bond length is 0.97 Å. The C(62)-H(81) bond length is 0.97 Å. There are six inequivalent N sites. In the first N site, N(13) is bonded in a bent 120 degrees geometry to one C(43) and one C(44) atom. In the second N site, N(14) is bonded in a water-like geometry to one C(44) and one C(45) atom. In the third N site, N(16) is bonded in a trigonal planar geometry to one C(43), one C(46), and one C(50) atom. In the fourth N site, N(15) is bonded in a bent 120 degrees geometry to one C(43) and one C(45) atom. In the fifth N site, N(17) is bonded in a trigonal planar geometry to one C(44), one C(52), and one C(56) atom. In the sixth N site, N(18) is bonded in a trigonal planar geometry to one C(45), one C(58), and one C(62) atom. There are eleven inequivalent H sites. In the first H site, H(55) is bonded in a single-bond geometry to one C(46) atom. In the second H site, H(56) is bonded in a single-bond geometry to one C(46) atom. In the third H site, H(57,58) is bonded in a single-bond geometry to one C(47) atom. In the fourth H site, H(62,63) is bonded in a single-bond geometry to one C(50) atom. In the fifth H site, H(64,65) is bonded in a single-bond geometry to one C(52) atom. In the sixth H site, H(66) is bonded in a single-bond geometry to one C(53) atom. In the seventh H site, H(71,72) is bonded in a single-bond geometry to one C(56) atom. In the eighth H site, H(73) is bonded in a single-bond geometry to one C(58) atom. In the ninth H site, H(74) is bonded in a single-bond geometry to one C(58) atom. In the tenth H site, H(80) is bonded in a single-bond geometry to one C(62) atom. In the eleventh H site, H(81) is bonded in a single-bond geometry to one C(62) atom. In each C3H4N2 cluster, there are nine inequivalent C sites. In the first C site, C(64) is bonded in a trigonal planar geometry to one N(19), one N(21), and one N(22) atom. The C(64)-N(19) bond length is 1.34 Å. The C(64)-N(21) bond length is 1.32 Å. The C(64)-N(22) bond length is 1.35 Å. In the second C site, C(65) is bonded in a trigonal planar geometry to one N(19), one N(20), and one N(23) atom. The C(65)-N(19) bond length is 1.30 Å. The C(65)-N(20) bond length is 1.35 Å. The C(65)-N(23) bond length is 1.36 Å. In the third C site, C(66) is bonded in a trigonal planar geometry to one N(20), one N(21), and one N(24) atom. The C(66)-N(20) bond length is 1.35 Å. The C(66)-N(21) bond length is 1.34 Å. The C(66)-N(24) bond length is 1.34 Å. In the fourth C site, C(67) is bonded in a 3-coordinate geometry to one N(22), one H(82), and one H(83) atom. The C(67)-N(22) bond length is 1.47 Å. The C(67)-H(82) bond length is 0.97 Å. The C(67)-H(83) bond length is 0.97 Å. In the fifth C site, C(71) is bonded in a 3-coordinate geometry to one N(22) and two equivalent H(89,90) atoms. The C(71)-N(22) bond length is 1.43 Å. Both C(71)-H(89,90) bond lengths are 0.97 Å. In the sixth C site, C(73) is bonded in a 3-coordinate geometry to one N(23), one H(91), and one H(92) atom. The C(73)-N(23) bond length is 1.45 Å. The C(73)-H(91) bond length is 0.97 Å. The C(73)-H(92) bond length is 0.97 Å. In the seventh C site, C(77) is bonded in a distorted trigonal non-coplanar geometry to one N(23), one H(98), and one H(99) atom. The C(77)-N(23) bond length is 1.41 Å. The C(77)-H(98) bond length is 0.97 Å. The C(77)-H(99) bond length is 0.97 Å. In the eighth C site, C(79) is bonded in a 3-coordinate geometry to one N(24) and two equivalent H(100,101) atoms. The C(79)-N(24) bond length is 1.48 Å. Both C(79)-H(100,101) bond lengths are 0.97 Å. In the ninth C site, C(83) is bonded in a distorted trigonal non-coplanar geometry to one N(24), one H(107), and one H(108) atom. The C(83)-N(24) bond length is 1.39 Å. The C(83)-H(107) bond length is 0.97 Å. The C(83)-H(108) bond length is 0.97 Å. There are six inequivalent N sites. In the first N site, N(19) is bonded in a bent 120 degrees geometry to one C(64) and one C(65) atom. In the second N site, N(20) is bonded in a bent 120 degrees geometry to one C(65) and one C(66) atom. In the third N site, N(21) is bonded in a bent 120 degrees geometry to one C(64) and one C(66) atom. In the fourth N site, N(22) is bonded in a trigonal planar geometry to one C(64), one C(67), and one C(71) atom. In the fifth N site, N(23) is bonded in a trigonal planar geometry to one C(65), one C(73), and one C(77) atom. In the sixth N site, N(24) is bonded in a trigonal planar geometry to one C(66), one C(79), and one C(83) atom. There are ten inequivalent H sites. In the first H site, H(82) is bonded in a single-bond geometry to one C(67) atom. In the second H site, H(83) is bonded in a single-bond geometry to one C(67) atom. In the third H site, H(89,90) is bonded in a single-bond geometry to one C(71) atom. In the fourth H site, H(91) is bonded in a single-bond geometry to one C(73) atom. In the fifth H site, H(92) is bonded in a single-bond geometry to one C(73) atom. In the sixth H site, H(98) is bonded in a single-bond geometry to one C(77) atom. In the seventh H site, H(99) is bonded in a single-bond geometry to one C(77) atom. In the eighth H site, H(100,101) is bonded in a single-bond geometry to one C(79) atom. In the ninth H site, H(107) is bonded in a single-bond geometry to one C(83) atom. In the tenth H site, H(108) is bonded in a single-bond geometry to one C(83) atom. In each C5N3H7 cluster, there are ten inequivalent C sites. In the first C site, C(29) is bonded in a 3-coordinate geometry to one N(10) and two equivalent H(35,36) atoms. The C(29)-N(10) bond length is 1.42 Å. Both C(29)-H(35,36) bond lengths are 0.97 Å. In the second C site, C(31) is bonded in a 4-coordinate geometry to one C(32), one N(11), one H(37), and one H(38) atom. The C(31)-C(32) bond length is 1.46 Å. The C(31)-N(11) bond length is 1.49 Å. The C(31)-H(37) bond length is 0.97 Å. The C(31)-H(38) bond length is 0.97 Å. In the third C site, C(32) is bonded in a water-like geometry to one C(31), one H(39), and one H(40) atom. The C(32)-H(39) bond length is 0.97 Å. The C(32)-H(40) bond length is 0.97 Å. In the fourth C site, C(35) is bonded in a distorted trigonal non-coplanar geometry to one N(11) and two equivalent H(44,45) atoms. The C(35)-N(11) bond length is 1.42 Å. Both C(35)-H(44,45) bond lengths are 0.97 Å. In the fifth C site, C(37) is bonded in a 3-coordinate geometry to one N(12) and two equivalent H(46,47) atoms. The C(37)-N(12) bond length is 1.42 Å. Both C(37)-H(46,47) bond lengths are 0.97 Å. In the sixth C site, C(41) is bonded in a distorted trigonal non-coplanar geometry to one N(12), one H(53), and one H(54) atom. The C(41)-N(12) bond length is 1.43 Å. The C(41)-H(53) bond length is 0.97 Å. The C(41)-H(54) bond length is 0.97 Å. In the seventh C site, C(22) is bonded in a trigonal planar geometry to one N(10), one N(7), and one N(9) atom. The C(22)-N(10) bond length is 1.32 Å. The C(22)-N(7) bond length is 1.29 Å. The C(22)-N(9) bond length is 1.38 Å. In the eighth C site, C(23) is bonded in a trigonal planar geometry to one N(11), one N(7), and one N(8) atom. The C(23)-N(11) bond length is 1.39 Å. The C(23)-N(7) bond length is 1.32 Å. The C(23)-N(8) bond length is 1.35 Å. In the ninth C site, C(24) is bonded in a trigonal planar geometry to one N(12), one N(8), and one N(9) atom. The C(24)-N(12) bond length is 1.31 Å. The C(24)-N(8) bond length is 1.35 Å. The C(24)-N(9) bond length is 1.33 Å. In the tenth C site, C(25) is bonded in a 3-coordinate geometry to one N(10) and two equivalent H(28,29) atoms. The C(25)-N(10) bond length is 1.47 Å. Both C(25)-H(28,29) bond lengths are 0.97 Å. There are six inequivalent N sites. In the first N site, N(7) is bonded in a bent 120 degrees geometry to one C(22) and one C(23) atom. In the second N site, N(8) is bonded in a bent 120 degrees geometry to one C(23) and one C(24) atom. In the third N site, N(9) is bonded in a bent 120 degrees geometry to one C(22) and one C(24) atom. In the fourth N site, N(10) is bonded in a trigonal planar geometry to one C(22), one C(25), and one C(29) atom. In the fifth N site, N(11) is bonded in a trigonal planar geometry to one C(23), one C(31), and one C(35) atom. In the sixth N site, N(12) is bonded in a trigonal planar geometry to one C(24), one C(37), and one C(41) atom. There are ten inequivalent H sites. In the first H site, H(28,29) is bonded in a single-bond geometry to one C(25) atom. In the second H site, H(35,36) is bonded in a single-bond geometry to one C(29) atom. In the third H site, H(37) is bonded in a single-bond geometry to one C(31) atom. In the fourth H site, H(38) is bonded in a single-bond geometry to one C(31) atom. In the fifth H site, H(39) is bonded in a single-bond geometry to one C(32) atom. In the sixth H site, H(40) is bonded in a single-bond geometry to one C(32) atom. In the seventh H site, H(44,45) is bonded in a single-bond geometry to one C(35) atom. In the eighth H site, H(46,47) is bonded in a single-bond geometry to one C(37) atom. In the ninth H site, H(53) is bonded in a single-bond geometry to one C(41) atom. In the tenth H site, H(54) is bonded in a single-bond geometry to one C(41) atom. In each Gd2C7H2O12 cluster, there are two inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 6-coordinate geometry to one O(1), one O(14), one O(2), one O(21), one O(22), and one O(24) atom. The Gd(1)-O(1) bond length is 2.67 Å. The Gd(1)-O(14) bond length is 2.40 Å. The Gd(1)-O(2) bond length is 2.51 Å. The Gd(1)-O(21) bond length is 2.46 Å. The Gd(1)-O(22) bond length is 2.39 Å. The Gd(1)-O(24) bond length is 2.31 Å. In the second Gd site, Gd(2) is bonded in a 7-coordinate geometry to one O(1), one O(10), one O(13), one O(14), one O(23), one O(7), and one O(8) atom. The Gd(2)-O(1) bond length is 2.29 Å. The Gd(2)-O(10) bond length is 2.61 Å. The Gd(2)-O(13) bond length is 2.40 Å. The Gd(2)-O(14) bond length is 2.64 Å. The Gd(2)-O(23) bond length is 2.38 Å. The Gd(2)-O(7) bond length is 2.45 Å. The Gd(2)-O(8) bond length is 2.53 Å. There are seven inequivalent C sites. In the first C site, C(30) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(30)-O(7) bond length is 1.26 Å. The C(30)-O(8) bond length is 1.29 Å. In the second C site, C(36) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(36)-O(10) bond length is 1.19 Å. The C(36)-O(9) bond length is 1.26 Å. In the third C site, C(49) is bonded in a single-bond geometry to one C(51) and one H(61) atom. The C(49)-C(51) bond length is 1.44 Å. The C(49)-H(61) bond length is 0.98 Å. In the fourth C site, C(51) is bonded in a distorted trigonal planar geometry to one C(49), one O(13), and one O(14) atom. The C(51)-O(13) bond length is 1.27 Å. The C(51)-O(14) bond length is 1.23 Å. In the fifth C site, C(78) is bonded in a distorted bent 120 degrees geometry to one O(21) and one O(22) atom. The C(78)-O(21) bond length is 1.24 Å. The C(78)-O(22) bond length is 1.22 Å. In the sixth C site, C(84) is bonded in a distorted bent 120 degrees geometry to one O(23) and one O(24) atom. The C(84)-O(23) bond length is 1.25 Å. The C(84)-O(24) bond length is 1.29 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(9)-O(1) bond length is 1.30 Å. The C(9)-O(2) bond length is 1.22 Å. There are two inequivalent H sites. In the first H site, H(61) is bonded in a single-bond geometry to one C(49) atom. In the second H site, H(109) is bonded in a single-bond geometry to one O(9) atom. The H(109)-O(9) bond length is 0.82 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Gd(1), one Gd(2), and one C(9) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Gd(1) and one C(9) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Gd(2) and one C(30) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one Gd(2) and one C(30) atom. In the fifth O site, O(9) is bonded in a water-like geometry to one C(36) and one H(109) atom. In the sixth O site, O(10) is bonded in a single-bond geometry to one Gd(2) and one C(36) atom. In the seventh O site, O(13) is bonded in a distorted single-bond geometry to one Gd(2) and one C(51) atom. In the eighth O site, O(14) is bonded in a 1-coordinate geometry to one Gd(1), one Gd(2), and one C(51) atom. In the ninth O site, O(21) is bonded in a single-bond geometry to one Gd(1) and one C(78) atom. In the tenth O site, O(22) is bonded in a distorted single-bond geometry to one Gd(1) and one C(78) atom. In the eleventh O site, O(23) is bonded in a distorted bent 150 degrees geometry to one Gd(2) and one C(84) atom. In the twelfth O site, O(24) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one C(84) atom. In each H8(C2N)3 cluster, there are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one N(4) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-N(3) bond length is 1.37 Å. The C(1)-N(4) bond length is 1.39 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(5) atom. The C(2)-N(1) bond length is 1.36 Å. The C(2)-N(2) bond length is 1.30 Å. The C(2)-N(5) bond length is 1.35 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(2), one N(3), and one N(6) atom. The C(3)-N(2) bond length is 1.36 Å. The C(3)-N(3) bond length is 1.35 Å. The C(3)-N(6) bond length is 1.36 Å. In the fourth C site, C(4) is bonded in a 4-coordinate geometry to one C(5); one N(4); and two equivalent H(1,2) atoms. The C(4)-C(5) bond length is 1.46 Å. The C(4)-N(4) bond length is 1.49 Å. Both C(4)-H(1,2) bond lengths are 0.97 Å. In the fifth C site, C(5) is bonded in a single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 0.98 Å. In the sixth C site, C(7) is bonded in a water-like geometry to one C(8) and two equivalent H(6,7) atoms. The C(7)-C(8) bond length is 1.44 Å. Both C(7)-H(6,7) bond lengths are 0.97 Å. In the seventh C site, C(8) is bonded in a 4-coordinate geometry to one C(7), one N(4), one H(8), and one H(9) atom. The C(8)-N(4) bond length is 1.46 Å. The C(8)-H(8) bond length is 0.97 Å. The C(8)-H(9) bond length is 0.97 Å. In the eighth C site, C(10) is bonded in a 4-coordinate geometry to one C(11), one N(5), one H(10), and one H(11) atom. The C(10)-C(11) bond length is 1.48 Å. The C(10)-N(5) bond length is 1.50 Å. The C(10)-H(10) bond length is 0.97 Å. The C(10)-H(11) bond length is 0.97 Å. In the ninth C site, C(11) is bonded in a single-bond geometry to one C(10) and one H(12) atom. The C(11)-H(12) bond length is 0.98 Å. In the tenth C site, C(14) is bonded in a 3-coordinate geometry to one N(5) and two equivalent H(17,18) atoms. The C(14)-N(5) bond length is 1.44 Å. Both C(14)-H(17,18) bond lengths are 0.97 Å. In the eleventh C site, C(16) is bonded in a 3-coordinate geometry to one N(6) and two equivalent H(19,20,26) atoms. The C(16)-N(6) bond length is 1.50 Å. Both C(16)-H(19,20,26) bond lengths are 0.97 Å. In the twelfth C site, C(20) is bonded in a 3-coordinate geometry to one N(6); one H(19,20,26); and one H(27) atom. The C(20)-N(6) bond length is 1.48 Å. The C(20)-H(19,20,26) bond length is 0.97 Å. The C(20)-H(27) bond length is 0.97 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(3) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(8) atom. In the fourth N site, N(2) is bonded in a bent 120 degrees geometry to one C(2) and one C(3) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(2) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(3) atom. There are eleven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(6,7) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(17,18) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(19,20,26) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(27) is bonded in a single-bond geometry to one C(20) atom. Linkers: 4 [O]C(=O)[C@@H]1CCCN(C1)C1=NC(=[N]=C([N]1)N1CCC[C@H](C1)C(=O)[O])N1CCC[C@H](C1)C(=O)[O] ,3 [O]C(=O)[C@@H]1CCCN(C1)C1=NC(=[N]=C([N]1)N1CCC[C@H](C1)C(=O)[O])N1CCC[C@H](C1)C(=O)O ,1 [O]C(=O)[C@@H]1CCCN(C1)C1=NC(=[N]=C([N]1)N1CCC[C@H](C1)C(=O)O)N1CCC[C@H](C1)C(=O)[O]. Metal clusters: 4 O[C]O[Gd]123(O[C]O[Gd]4(O[C]O4)(O[C]O1)O[C]O2)O[C]O3. The MOF has largest included sphere 4.64 A, density 1.49 g/cm3, surface area 3960.42 m2/g, accessible volume 0.27 cm3/g