CoC34H26(N2O3)2 crystallizes in the monoclinic Cm space group. Co(1,2,3,4) is bonded in an octahedral geometry to two equivalent N(1,2,3,4,5,6,7); one O(6); one O(9,18); and two equivalent O(1) atoms. Both Co(1,2,3,4)-N(1,2,3,4,5,6,7) bond lengths are 2.18 Å. The Co(1,2,3,4)-O(6) bond length is 2.02 Å. The Co(1,2,3,4)-O(9,18) bond length is 2.02 Å. Both Co(1,2,3,4)-O(1) bond lengths are 2.22 Å. There are eighty-eight inequivalent C sites. In the first C site, C(110) is bonded in a trigonal planar geometry to one C(111), one C(58), and one C(69) atom. The C(110)-C(111) bond length is 1.53 Å. The C(110)-C(58) bond length is 1.39 Å. The C(110)-C(69) bond length is 1.39 Å. In the second C site, C(111) is bonded in a distorted trigonal non-coplanar geometry to one C(110) and three equivalent H(77,78,79) atoms. All C(111)-H(77,78,79) bond lengths are 1.14 Å. In the third C site, C(111) is bonded in a distorted trigonal non-coplanar geometry to one C(110) and three equivalent H(77,78,79) atoms. The C(111)-C(110) bond length is 1.53 Å. All C(111)-H(77,78,79) bond lengths are 1.14 Å. In the fourth C site, C(114) is bonded in a trigonal planar geometry to one C(105,115) and two equivalent C(91) atoms. The C(114)-C(105,115) bond length is 1.53 Å. Both C(114)-C(91) bond lengths are 1.39 Å. In the fifth C site, C(25) is bonded in a trigonal planar geometry to one C(102), one C(108), and one C(28) atom. The C(25)-C(102) bond length is 1.39 Å. The C(25)-C(108) bond length is 1.39 Å. The C(25)-C(28) bond length is 1.55 Å. In the sixth C site, C(28) is bonded in a distorted trigonal non-coplanar geometry to one C(25); two equivalent H(1,10); and one O(2) atom. Both C(28)-H(1,10) bond lengths are 1.14 Å. The C(28)-O(2) bond length is 1.43 Å. In the seventh C site, C(102) is bonded in a trigonal planar geometry to one C(103), one C(25), and one C(69) atom. The C(102)-C(103) bond length is 1.53 Å. The C(102)-C(25) bond length is 1.39 Å. The C(102)-C(69) bond length is 1.39 Å. In the eighth C site, C(108) is bonded in a trigonal planar geometry to one C(109), one C(25), and one C(58) atom. The C(108)-C(109) bond length is 1.53 Å. The C(108)-C(58) bond length is 1.39 Å. In the ninth C site, C(110) is bonded in a trigonal planar geometry to one C(111), one C(58), and one C(69) atom. The C(110)-C(111) bond length is 1.53 Å. The C(110)-C(58) bond length is 1.39 Å. The C(110)-C(69) bond length is 1.39 Å. In the tenth C site, C(110) is bonded in a trigonal planar geometry to one C(111), one C(58), and one C(69) atom. The C(110)-C(111) bond length is 1.53 Å. The C(110)-C(58) bond length is 1.39 Å. The C(110)-C(69) bond length is 1.39 Å. In the eleventh C site, C(102) is bonded in a trigonal planar geometry to one C(103), one C(25), and one C(69) atom. The C(102)-C(103) bond length is 1.53 Å. The C(102)-C(69) bond length is 1.39 Å. In the twelfth C site, C(1,3,5,7,9,11,13,15,17,19,21,23) is bonded in a distorted trigonal planar geometry to one C(2,4,6,8,10,12,14,16,18,20,22,24); one C(29); and one H(2,5,8,11,14,17,20,23,26,29,32,35) atom. The C(1,3,5,7,9,11,13,15,17,19,21,23)-C(2,4,6,8,10,12,14,16,18,20,22,24) bond length is 1.38 Å. The C(1,3,5,7,9,11,13,15,17,19,21,23)-C(29) bond length is 1.39 Å. The C(1,3,5,7,9,11,13,15,17,19,21,23)-H(2,5,8,11,14,17,20,23,26,29,32,35) bond length is 1.14 Å. In the thirteenth C site, C(2,4,6,8,10,12,14,16,18,20,22,24) is bonded in a distorted bent 120 degrees geometry to one C(1,3,5,7,9,11,13,15,17,19,21,23); one N(1,2,3,4,5,6,7); and one H(3,6,9,12,15,18,21,24,27,30,33,36) atom. The C(2,4,6,8,10,12,14,16,18,20,22,24)-N(1,2,3,4,5,6,7) bond length is 1.31 Å. The C(2,4,6,8,10,12,14,16,18,20,22,24)-H(3,6,9,12,15,18,21,24,27,30,33,36) bond length is 1.14 Å. In the fourteenth C site, C(25) is bonded in a trigonal planar geometry to one C(102), one C(108), and one C(28) atom. The C(25)-C(102) bond length is 1.39 Å. The C(25)-C(108) bond length is 1.39 Å. The C(25)-C(28) bond length is 1.55 Å. In the fifteenth C site, C(26,37,48,59,70,81,92) is bonded in a distorted trigonal planar geometry to one C(29); one N(11); and one N(8,14) atom. The C(26,37,48,59,70,81,92)-C(29) bond length is 1.47 Å. The C(26,37,48,59,70,81,92)-N(11) bond length is 1.34 Å. The C(26,37,48,59,70,81,92)-N(8,14) bond length is 1.34 Å. In the sixteenth C site, C(27) is bonded in a bent 120 degrees geometry to one C(30), one O(1), and one O(3) atom. The C(27)-C(30) bond length is 1.53 Å. The C(27)-O(1) bond length is 1.25 Å. The C(27)-O(3) bond length is 1.27 Å. In the seventeenth C site, C(28) is bonded in a distorted trigonal non-coplanar geometry to one C(25); two equivalent H(1,10); and one O(2) atom. Both C(28)-H(1,10) bond lengths are 1.14 Å. The C(28)-O(2) bond length is 1.43 Å. In the eighteenth C site, C(29) is bonded in a trigonal planar geometry to one C(26,37,48,59,70,81,92) and two equivalent C(1,3,5,7,9,11,13,15,17,19,21,23) atoms. In the nineteenth C site, C(30) is bonded in a trigonal planar geometry to one C(27), one C(31), and one C(35) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-C(35) bond length is 1.37 Å. In the twentieth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(37) atom. The C(31)-H(37) bond length is 1.14 Å. In the twenty-first C site, C(32) is bonded in a single-bond geometry to one C(33) and one O(2) atom. The C(32)-C(33) bond length is 1.36 Å. The C(32)-O(2) bond length is 1.36 Å. In the twenty-second C site, C(33) is bonded in a distorted trigonal planar geometry to one C(32), one C(34), and one H(38) atom. The C(33)-C(34) bond length is 1.41 Å. The C(33)-H(38) bond length is 1.14 Å. In the twenty-third C site, C(34) is bonded in a distorted trigonal planar geometry to one C(33), one C(35), and one H(39) atom. The C(34)-C(35) bond length is 1.38 Å. The C(34)-H(39) bond length is 1.14 Å. In the twenty-fourth C site, C(35) is bonded in a distorted single-bond geometry to one C(30), one C(34), and one H(40) atom. The C(35)-H(40) bond length is 1.14 Å. In the twenty-fifth C site, C(36) is bonded in a trigonal planar geometry to one C(39) and two equivalent C(104) atoms. The C(36)-C(39) bond length is 1.55 Å. Both C(36)-C(104) bond lengths are 1.39 Å. In the twenty-sixth C site, C(38) is bonded in a bent 120 degrees geometry to one C(41), one O(4), and one O(6) atom. The C(38)-C(41) bond length is 1.53 Å. The C(38)-O(4) bond length is 1.25 Å. The C(38)-O(6) bond length is 1.27 Å. In the twenty-seventh C site, C(39) is bonded in a distorted trigonal non-coplanar geometry to one C(36), two equivalent H(4), and one O(5) atom. Both C(39)-H(4) bond lengths are 1.14 Å. The C(39)-O(5) bond length is 1.43 Å. In the twenty-eighth C site, C(40,73) is bonded in a trigonal planar geometry to one C(26,37,48,59,70,81,92) and two equivalent C(1,3,5,7,9,11,13,15,17,19,21,23) atoms. The C(40,73)-C(26,37,48,59,70,81,92) bond length is 1.47 Å. Both C(40,73)-C(1,3,5,7,9,11,13,15,17,19,21,23) bond lengths are 1.39 Å. In the twenty-ninth C site, C(41) is bonded in a trigonal planar geometry to one C(38), one C(42), and one C(46) atom. The C(41)-C(42) bond length is 1.40 Å. The C(41)-C(46) bond length is 1.37 Å. In the thirtieth C site, C(42) is bonded in a distorted single-bond geometry to one C(41) and one H(41) atom. The C(42)-H(41) bond length is 1.14 Å. In the thirty-first C site, C(43) is bonded in a single-bond geometry to one C(44) and one O(5) atom. The C(43)-C(44) bond length is 1.36 Å. The C(43)-O(5) bond length is 1.36 Å. In the thirty-second C site, C(44) is bonded in a distorted trigonal planar geometry to one C(43), one C(45), and one H(42) atom. The C(44)-C(45) bond length is 1.41 Å. The C(44)-H(42) bond length is 1.14 Å. In the thirty-third C site, C(45) is bonded in a distorted trigonal planar geometry to one C(44), one C(46), and one H(43) atom. The C(45)-C(46) bond length is 1.38 Å. The C(45)-H(43) bond length is 1.14 Å. In the thirty-fourth C site, C(46) is bonded in a distorted single-bond geometry to one C(41), one C(45), and one H(44) atom. The C(46)-H(44) bond length is 1.14 Å. In the thirty-fifth C site, C(47,80) is bonded in a trigonal planar geometry to one C(50) and two equivalent C(106,112) atoms. The C(47,80)-C(50) bond length is 1.55 Å. Both C(47,80)-C(106,112) bond lengths are 1.39 Å. In the thirty-sixth C site, C(49) is bonded in a bent 120 degrees geometry to one C(52,85); one O(7,16); and one O(9,18) atom. The C(49)-C(52,85) bond length is 1.53 Å. The C(49)-O(7,16) bond length is 1.25 Å. The C(49)-O(9,18) bond length is 1.27 Å. In the thirty-seventh C site, C(50) is bonded in a distorted trigonal non-coplanar geometry to one C(47,80); two equivalent H(7,19,31); and one O(8,17) atom. Both C(50)-H(7,19,31) bond lengths are 1.14 Å. The C(50)-O(8,17) bond length is 1.43 Å. In the thirty-eighth C site, C(51,62,95) is bonded in a trigonal planar geometry to one C(26,37,48,59,70,81,92) and two equivalent C(1,3,5,7,9,11,13,15,17,19,21,23) atoms. The C(51,62,95)-C(26,37,48,59,70,81,92) bond length is 1.47 Å. Both C(51,62,95)-C(1,3,5,7,9,11,13,15,17,19,21,23) bond lengths are 1.39 Å. In the thirty-ninth C site, C(52,85) is bonded in a trigonal planar geometry to one C(49), one C(53), and one C(57) atom. The C(52,85)-C(53) bond length is 1.40 Å. The C(52,85)-C(57) bond length is 1.37 Å. In the fortieth C site, C(53) is bonded in a distorted single-bond geometry to one C(52,85) and one H(45,57) atom. The C(53)-H(45,57) bond length is 1.14 Å. In the forty-first C site, C(54) is bonded in a single-bond geometry to one C(55) and one O(8,17) atom. The C(54)-C(55) bond length is 1.36 Å. The C(54)-O(8,17) bond length is 1.36 Å. In the forty-second C site, C(55) is bonded in a distorted trigonal planar geometry to one C(54), one C(56), and one H(46) atom. The C(55)-C(56) bond length is 1.41 Å. The C(55)-H(46) bond length is 1.14 Å. In the forty-third C site, C(56) is bonded in a trigonal planar geometry to one C(55), one C(57), and one H(47) atom. The C(56)-C(57) bond length is 1.38 Å. The C(56)-H(47) bond length is 1.14 Å. In the forty-fourth C site, C(57) is bonded in a distorted single-bond geometry to one C(52,85); one C(56); and one H(48,60) atom. The C(57)-H(48,60) bond length is 1.14 Å. In the forty-fifth C site, C(58) is bonded in a trigonal planar geometry to one C(108), one C(110), and one C(61) atom. The C(58)-C(108) bond length is 1.39 Å. The C(58)-C(61) bond length is 1.55 Å. In the forty-sixth C site, C(60) is bonded in a bent 120 degrees geometry to one C(63), one O(10), and one O(12) atom. The C(60)-C(63) bond length is 1.53 Å. The C(60)-O(10) bond length is 1.25 Å. The C(60)-O(12) bond length is 1.27 Å. In the forty-seventh C site, C(61) is bonded in a distorted trigonal non-coplanar geometry to one C(58); two equivalent H(13,34); and one O(11) atom. Both C(61)-H(13,34) bond lengths are 1.14 Å. The C(61)-O(11) bond length is 1.43 Å. In the forty-eighth C site, C(63) is bonded in a trigonal planar geometry to one C(60), one C(64), and one C(68) atom. The C(63)-C(64) bond length is 1.40 Å. The C(63)-C(68) bond length is 1.37 Å. In the forty-ninth C site, C(64) is bonded in a distorted single-bond geometry to one C(63) and one H(49) atom. The C(64)-H(49) bond length is 1.14 Å. In the fiftieth C site, C(65) is bonded in a single-bond geometry to one C(66) and one O(11) atom. The C(65)-C(66) bond length is 1.36 Å. The C(65)-O(11) bond length is 1.36 Å. In the fifty-first C site, C(66) is bonded in a distorted trigonal planar geometry to one C(65), one C(67), and one H(50) atom. The C(66)-C(67) bond length is 1.41 Å. The C(66)-H(50) bond length is 1.14 Å. In the fifty-second C site, C(67) is bonded in a distorted trigonal planar geometry to one C(66), one C(68), and one H(51) atom. The C(67)-C(68) bond length is 1.38 Å. The C(67)-H(51) bond length is 1.14 Å. In the fifty-third C site, C(68) is bonded in a distorted single-bond geometry to one C(63), one C(67), and one H(52) atom. The C(68)-H(52) bond length is 1.14 Å. In the fifty-fourth C site, C(69) is bonded in a trigonal planar geometry to one C(102), one C(110), and one C(72) atom. The C(69)-C(102) bond length is 1.39 Å. The C(69)-C(72) bond length is 1.55 Å. In the fifty-fifth C site, C(71) is bonded in a bent 120 degrees geometry to one C(74), one O(13), and one O(15) atom. The C(71)-C(74) bond length is 1.53 Å. The C(71)-O(13) bond length is 1.25 Å. The C(71)-O(15) bond length is 1.27 Å. In the fifty-sixth C site, C(72) is bonded in a distorted trigonal non-coplanar geometry to one C(69); two equivalent H(16,28); and one O(14) atom. Both C(72)-H(16,28) bond lengths are 1.14 Å. The C(72)-O(14) bond length is 1.43 Å. In the fifty-seventh C site, C(74) is bonded in a trigonal planar geometry to one C(71), one C(75), and one C(79) atom. The C(74)-C(75) bond length is 1.40 Å. The C(74)-C(79) bond length is 1.37 Å. In the fifty-eighth C site, C(75) is bonded in a distorted single-bond geometry to one C(74) and one H(53) atom. The C(75)-H(53) bond length is 1.14 Å. In the fifty-ninth C site, C(76) is bonded in a single-bond geometry to one C(77) and one O(14) atom. The C(76)-C(77) bond length is 1.36 Å. The C(76)-O(14) bond length is 1.36 Å. In the sixtieth C site, C(77) is bonded in a distorted trigonal planar geometry to one C(76), one C(78), and one H(54) atom. The C(77)-C(78) bond length is 1.41 Å. The C(77)-H(54) bond length is 1.14 Å. In the sixty-first C site, C(78) is bonded in a distorted trigonal planar geometry to one C(77), one C(79), and one H(55) atom. The C(78)-C(79) bond length is 1.38 Å. The C(78)-H(55) bond length is 1.14 Å. In the sixty-second C site, C(79) is bonded in a distorted single-bond geometry to one C(74), one C(78), and one H(56) atom. The C(79)-H(56) bond length is 1.14 Å. In the sixty-third C site, C(82) is bonded in a bent 120 degrees geometry to one C(52,85); one O(7,16); and one O(9,18) atom. The C(82)-C(52,85) bond length is 1.53 Å. The C(82)-O(7,16) bond length is 1.25 Å. The C(82)-O(9,18) bond length is 1.27 Å. In the sixty-fourth C site, C(83) is bonded in a distorted trigonal non-coplanar geometry to one C(47,80); two equivalent H(7,19,31); and one O(8,17) atom. The C(83)-C(47,80) bond length is 1.55 Å. Both C(83)-H(7,19,31) bond lengths are 1.14 Å. The C(83)-O(8,17) bond length is 1.43 Å. In the sixty-fifth C site, C(84) is bonded in a trigonal planar geometry to one C(26,37,48,59,70,81,92) and two equivalent C(1,3,5,7,9,11,13,15,17,19,21,23) atoms. The C(84)-C(26,37,48,59,70,81,92) bond length is 1.47 Å. Both C(84)-C(1,3,5,7,9,11,13,15,17,19,21,23) bond lengths are 1.39 Å. In the sixty-sixth C site, C(86) is bonded in a distorted single-bond geometry to one C(52,85) and one H(45,57) atom. The C(86)-C(52,85) bond length is 1.40 Å. The C(86)-H(45,57) bond length is 1.14 Å. In the sixty-seventh C site, C(87) is bonded in a single-bond geometry to one C(88) and one O(8,17) atom. The C(87)-C(88) bond length is 1.36 Å. The C(87)-O(8,17) bond length is 1.36 Å. In the sixty-eighth C site, C(88) is bonded in a distorted trigonal planar geometry to one C(87), one C(89), and one H(58) atom. The C(88)-C(89) bond length is 1.41 Å. The C(88)-H(58) bond length is 1.14 Å. In the sixty-ninth C site, C(89) is bonded in a trigonal planar geometry to one C(88), one C(90), and one H(59) atom. The C(89)-C(90) bond length is 1.38 Å. The C(89)-H(59) bond length is 1.14 Å. In the seventieth C site, C(90) is bonded in a distorted single-bond geometry to one C(52,85); one C(89); and one H(48,60) atom. The C(90)-C(52,85) bond length is 1.37 Å. The C(90)-H(48,60) bond length is 1.14 Å. In the seventy-first C site, C(91) is bonded in a trigonal planar geometry to one C(104), one C(114), and one C(94) atom. The C(91)-C(104) bond length is 1.39 Å. The C(91)-C(94) bond length is 1.55 Å. In the seventy-second C site, C(93) is bonded in a bent 120 degrees geometry to one C(96), one O(19), and one O(21) atom. The C(93)-C(96) bond length is 1.53 Å. The C(93)-O(19) bond length is 1.25 Å. The C(93)-O(21) bond length is 1.27 Å. In the seventy-third C site, C(94) is bonded in a distorted trigonal non-coplanar geometry to one C(91); two equivalent H(22,25); and one O(20) atom. Both C(94)-H(22,25) bond lengths are 1.14 Å. The C(94)-O(20) bond length is 1.43 Å. In the seventy-fourth C site, C(96) is bonded in a trigonal planar geometry to one C(101), one C(93), and one C(97) atom. The C(96)-C(101) bond length is 1.37 Å. The C(96)-C(97) bond length is 1.40 Å. In the seventy-fifth C site, C(97) is bonded in a distorted single-bond geometry to one C(96) and one H(61) atom. The C(97)-H(61) bond length is 1.14 Å. In the seventy-sixth C site, C(98) is bonded in a single-bond geometry to one C(99) and one O(20) atom. The C(98)-C(99) bond length is 1.36 Å. The C(98)-O(20) bond length is 1.36 Å. In the seventy-seventh C site, C(99) is bonded in a distorted trigonal planar geometry to one C(100), one C(98), and one H(62) atom. The C(99)-C(100) bond length is 1.41 Å. The C(99)-H(62) bond length is 1.14 Å. In the seventy-eighth C site, C(100) is bonded in a distorted trigonal planar geometry to one C(101), one C(99), and one H(63) atom. The C(100)-C(101) bond length is 1.38 Å. The C(100)-H(63) bond length is 1.14 Å. In the seventy-ninth C site, C(101) is bonded in a distorted single-bond geometry to one C(100), one C(96), and one H(64) atom. The C(101)-H(64) bond length is 1.14 Å. In the eightieth C site, C(72) is bonded in a distorted trigonal non-coplanar geometry to one C(69); two equivalent H(16,28); and one O(14) atom. The C(72)-C(69) bond length is 1.55 Å. Both C(72)-H(16,28) bond lengths are 1.14 Å. The C(72)-O(14) bond length is 1.43 Å. In the eighty-first C site, C(102) is bonded in a trigonal planar geometry to one C(103), one C(25), and one C(69) atom. The C(102)-C(103) bond length is 1.53 Å. In the eighty-second C site, C(103) is bonded in a trigonal non-coplanar geometry to one C(102) and three equivalent H(65,66,67,71,72,73,80,81) atoms. All C(103)-H(65,66,67,71,72,73,80,81) bond lengths are 1.14 Å. In the eighty-third C site, C(104) is bonded in a trigonal planar geometry to one C(105,115); one C(36); and one C(91) atom. The C(104)-C(105,115) bond length is 1.53 Å. In the eighty-fourth C site, C(105,115) is bonded in a distorted trigonal non-coplanar geometry to one C(104) and three equivalent H(68,69,70,74,75,76,82,83) atoms. All C(105,115)-H(68,69,70,74,75,76,82,83) bond lengths are 1.14 Å. In the eighty-fifth C site, C(106,112) is bonded in a trigonal planar geometry to one C(107,113) and two equivalent C(47,80) atoms. The C(106,112)-C(107,113) bond length is 1.53 Å. In the eighty-sixth C site, C(107,113) is bonded in a trigonal non-coplanar geometry to one C(106,112) and three equivalent H(65,66,67,71,72,73,80,81) atoms. All C(107,113)-H(65,66,67,71,72,73,80,81) bond lengths are 1.14 Å. In the eighty-seventh C site, C(108) is bonded in a trigonal planar geometry to one C(109), one C(25), and one C(58) atom. The C(108)-C(109) bond length is 1.53 Å. In the eighty-eighth C site, C(109) is bonded in a distorted trigonal non-coplanar geometry to one C(108) and three equivalent H(68,69,70,74,75,76,82,83) atoms. All C(109)-H(68,69,70,74,75,76,82,83) bond lengths are 1.14 Å. There are five inequivalent N sites. In the first N site, N(1,2,3,4,5,6,7) is bonded in a trigonal planar geometry to one Co(1,2,3,4) and two equivalent C(2,4,6,8,10,12,14,16,18,20,22,24) atoms. In the second N site, N(8,14) is bonded in a bent 120 degrees geometry to two equivalent C(26,37,48,59,70,81,92) atoms. In the third N site, N(9,13) is bonded in a bent 120 degrees geometry to two equivalent C(26,37,48,59,70,81,92) atoms. Both N(9,13)-C(26,37,48,59,70,81,92) bond lengths are 1.34 Å. In the fourth N site, N(10,12) is bonded in a bent 120 degrees geometry to two equivalent C(26,37,48,59,70,81,92) atoms. Both N(10,12)-C(26,37,48,59,70,81,92) bond lengths are 1.34 Å. In the fifth N site, N(11) is bonded in a bent 120 degrees geometry to two equivalent C(26,37,48,59,70,81,92) atoms. There are thirty-seven inequivalent H sites. In the first H site, H(1,10) is bonded in a single-bond geometry to one C(28) atom. In the second H site, H(2,5,8,11,14,17,20,23,26,29,32,35) is bonded in a single-bond geometry to one C(1,3,5,7,9,11,13,15,17,19,21,23) atom. In the third H site, H(3,6,9,12,15,18,21,24,27,30,33,36) is bonded in a single-bond geometry to one C(2,4,6,8,10,12,14,16,18,20,22,24) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(39) atom. In the fifth H site, H(7,19,31) is bonded in a single-bond geometry to one C(50) atom. In the sixth H site, H(13,34) is bonded in a single-bond geometry to one C(61) atom. In the seventh H site, H(16,28) is bonded in a single-bond geometry to one C(72) atom. In the eighth H site, H(22,25) is bonded in a single-bond geometry to one C(94) atom. In the ninth H site, H(37) is bonded in a single-bond geometry to one C(31) atom. In the tenth H site, H(38) is bonded in a single-bond geometry to one C(33) atom. In the eleventh H site, H(39) is bonded in a single-bond geometry to one C(34) atom. In the twelfth H site, H(40) is bonded in a single-bond geometry to one C(35) atom. In the thirteenth H site, H(41) is bonded in a single-bond geometry to one C(42) atom. In the fourteenth H site, H(42) is bonded in a single-bond geometry to one C(44) atom. In the fifteenth H site, H(43) is bonded in a single-bond geometry to one C(45) atom. In the sixteenth H site, H(44) is bonded in a single-bond geometry to one C(46) atom. In the seventeenth H site, H(45,57) is bonded in a single-bond geometry to one C(53) atom. In the eighteenth H site, H(46) is bonded in a single-bond geometry to one C(55) atom. In the nineteenth H site, H(47) is bonded in a single-bond geometry to one C(56) atom. In the twentieth H site, H(48,60) is bonded in a single-bond geometry to one C(57) atom. In the twenty-first H site, H(49) is bonded in a single-bond geometry to one C(64) atom. In the twenty-second H site, H(50) is bonded in a single-bond geometry to one C(66) atom. In the twenty-third H site, H(51) is bonded in a single-bond geometry to one C(67) atom. In the twenty-fourth H site, H(52) is bonded in a single-bond geometry to one C(68) atom. In the twenty-fifth H site, H(53) is bonded in a single-bond geometry to one C(75) atom. In the twenty-sixth H site, H(54) is bonded in a single-bond geometry to one C(77) atom. In the twenty-seventh H site, H(55) is bonded in a single-bond geometry to one C(78) atom. In the twenty-eighth H site, H(56) is bonded in a single-bond geometry to one C(79) atom. In the twenty-ninth H site, H(58) is bonded in a single-bond geometry to one C(88) atom. In the thirtieth H site, H(59) is bonded in a single-bond geometry to one C(89) atom. In the thirty-first H site, H(61) is bonded in a single-bond geometry to one C(97) atom. In the thirty-second H site, H(62) is bonded in a single-bond geometry to one C(99) atom. In the thirty-third H site, H(63) is bonded in a single-bond geometry to one C(100) atom. In the thirty-fourth H site, H(64) is bonded in a single-bond geometry to one C(101) atom. In the thirty-fifth H site, H(65,66,67,71,72,73,80,81) is bonded in a single-bond geometry to one C(103) atom. In the thirty-sixth H site, H(68,69,70,74,75,76,82,83) is bonded in a single-bond geometry to one C(105,115) atom. In the thirty-seventh H site, H(77,78,79) is bonded in a single-bond geometry to one C(111) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Co(1,2,3,4) and one C(27) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(28) and one C(32) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1,2,3,4) and one C(27) atom. The O(3)-Co(1,2,3,4) bond length is 2.02 Å. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Co(1,2,3,4) and one C(38) atom. The O(4)-Co(1,2,3,4) bond length is 2.22 Å. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(39) and one C(43) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Co(1,2,3,4) and one C(38) atom. In the seventh O site, O(7,16) is bonded in a bent 150 degrees geometry to one Co(1,2,3,4) and one C(49) atom. The O(7,16)-Co(1,2,3,4) bond length is 2.22 Å. In the eighth O site, O(8,17) is bonded in a bent 120 degrees geometry to one C(50) and one C(54) atom. In the ninth O site, O(9,18) is bonded in a bent 120 degrees geometry to one Co(1,2,3,4) and one C(49) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Co(1,2,3,4) and one C(60) atom. The O(10)-Co(1,2,3,4) bond length is 2.22 Å. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one C(61) and one C(65) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Co(1,2,3,4) and one C(60) atom. The O(12)-Co(1,2,3,4) bond length is 2.02 Å. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Co(1,2,3,4) and one C(71) atom. The O(13)-Co(1,2,3,4) bond length is 2.22 Å. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one C(72) and one C(76) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Co(1,2,3,4) and one C(71) atom. The O(15)-Co(1,2,3,4) bond length is 2.02 Å. In the sixteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Co(1,2,3,4) and one C(93) atom. The O(19)-Co(1,2,3,4) bond length is 2.22 Å. In the seventeenth O site, O(20) is bonded in a bent 120 degrees geometry to one C(94) and one C(98) atom. In the eighteenth O site, O(21) is bonded in a bent 120 degrees geometry to one Co(1,2,3,4) and one C(93) atom. The O(21)-Co(1,2,3,4) bond length is 2.02 Å. Linkers: 4 n1ccc(cc1)C1=NC(=[N]=C([N]1)c1ccncc1)c1ccncc1 ,4 Cc1c(COc2cccc(C([O])=O)c2)c(C)c(COc2cccc(C([O])=O)c2)c(C)c1COc1cccc(C([O])=O)c1. Metal clusters: 3 [C]1O[Co]23O[C]O[Co](O1)(O[C]O2)O[C]O3. RCSR code: bor. The MOF has largest included sphere 13.31 A, density 0.58 g/cm3, surface area 4891.68 m2/g, accessible volume 1.18 cm3/g