ZnH10(C2N)4 crystallizes in the triclinic P1 space group. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(18), one N(19), and one N(4) atom. The Zn(1)-N(1) bond length is 1.97 Å. The Zn(1)-N(18) bond length is 1.97 Å. The Zn(1)-N(19) bond length is 1.97 Å. The Zn(1)-N(4) bond length is 1.97 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one N(17), one N(2), one N(20), and one N(3) atom. The Zn(2)-N(17) bond length is 1.97 Å. The Zn(2)-N(2) bond length is 1.97 Å. The Zn(2)-N(20) bond length is 1.97 Å. The Zn(2)-N(3) bond length is 1.97 Å. In the third Zn site, Zn(3) is bonded in a tetrahedral geometry to one N(14), one N(15), one N(5), and one N(8) atom. The Zn(3)-N(14) bond length is 1.97 Å. The Zn(3)-N(15) bond length is 1.97 Å. The Zn(3)-N(5) bond length is 1.97 Å. The Zn(3)-N(8) bond length is 1.97 Å. In the fourth Zn site, Zn(4) is bonded in a tetrahedral geometry to one N(13), one N(16), one N(6), and one N(7) atom. The Zn(4)-N(13) bond length is 1.97 Å. The Zn(4)-N(16) bond length is 1.97 Å. The Zn(4)-N(6) bond length is 1.97 Å. The Zn(4)-N(7) bond length is 1.97 Å. In the fifth Zn site, Zn(5) is bonded in a tetrahedral geometry to one N(10,22); one N(11,23); one N(12); and one N(9) atom. The Zn(5)-N(10,22) bond length is 1.97 Å. The Zn(5)-N(11,23) bond length is 1.97 Å. The Zn(5)-N(12) bond length is 1.97 Å. The Zn(5)-N(9) bond length is 1.97 Å. In the sixth Zn site, Zn(6) is bonded in a tetrahedral geometry to one N(10,22); one N(11,23); one N(21); and one N(24) atom. The Zn(6)-N(10,22) bond length is 1.97 Å. The Zn(6)-N(11,23) bond length is 1.97 Å. The Zn(6)-N(21) bond length is 1.97 Å. The Zn(6)-N(24) bond length is 1.97 Å. There are forty inequivalent C sites. In the first C site, C(1,13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,14) atom. The C(1,13)-N(1) bond length is 1.40 Å. The C(1,13)-H(1,14) bond length is 0.93 Å. In the second C site, C(2,14) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2,8,13,20) atom. The C(2,14)-N(2) bond length is 1.40 Å. The C(2,14)-H(2,8,13,20) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(3,16,19) atom. The C(3)-N(3) bond length is 1.40 Å. The C(3)-H(3,16,19) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(4) atom. The C(4)-N(4) bond length is 1.40 Å. The C(4)-H(4) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(5) atom. The C(5)-N(5) bond length is 1.40 Å. The C(5)-H(5) bond length is 0.93 Å. In the sixth C site, C(6,18) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(6,15,18) atom. The C(6,18)-N(6) bond length is 1.40 Å. The C(6,18)-H(6,15,18) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(7) atom. The C(7)-N(7) bond length is 1.40 Å. The C(7)-H(7) bond length is 0.93 Å. In the eighth C site, C(8,20) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(2,8,13,20) atom. The C(8,20)-N(8) bond length is 1.40 Å. The C(8,20)-H(2,8,13,20) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(9,21) atom. The C(9)-N(9) bond length is 1.40 Å. The C(9)-H(9,21) bond length is 0.93 Å. In the tenth C site, C(10,22) is bonded in a distorted bent 120 degrees geometry to one N(10,22) and one H(10,22) atom. The C(10,22)-N(10,22) bond length is 1.40 Å. The C(10,22)-H(10,22) bond length is 0.93 Å. In the eleventh C site, C(11,23) is bonded in a distorted bent 120 degrees geometry to one N(11,23) and one H(11,23) atom. The C(11,23)-N(11,23) bond length is 1.40 Å. The C(11,23)-H(11,23) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(12) and one H(12,24) atom. The C(12)-N(12) bond length is 1.40 Å. The C(12)-H(12,24) bond length is 0.93 Å. In the thirteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(15) and one H(6,15,18) atom. The C(15)-N(15) bond length is 1.40 Å. The C(15)-H(6,15,18) bond length is 0.93 Å. In the fourteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(16) and one H(3,16,19) atom. The C(16)-N(16) bond length is 1.40 Å. The C(16)-H(3,16,19) bond length is 0.93 Å. In the fifteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(17) and one H(17) atom. The C(17)-N(17) bond length is 1.40 Å. The C(17)-H(17) bond length is 0.93 Å. In the sixteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(19) and one H(3,16,19) atom. The C(19)-N(19) bond length is 1.40 Å. The C(19)-H(3,16,19) bond length is 0.93 Å. In the seventeenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(21) and one H(9,21) atom. The C(21)-N(21) bond length is 1.40 Å. The C(21)-H(9,21) bond length is 0.93 Å. In the eighteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(24) and one H(12,24) atom. The C(24)-N(24) bond length is 1.40 Å. The C(24)-H(12,24) bond length is 0.93 Å. In the nineteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one N(1), and one N(13) atom. The C(25)-C(26) bond length is 1.49 Å. The C(25)-N(1) bond length is 1.35 Å. The C(25)-N(13) bond length is 1.35 Å. In the twentieth C site, C(26) is bonded in a distorted trigonal non-coplanar geometry to one C(25) and three equivalent H(25,26,27) atoms. All C(26)-H(25,26,27) bond lengths are 1.14 Å. In the twenty-first C site, C(27) is bonded in a distorted trigonal planar geometry to one C(28), one N(14), and one N(2) atom. The C(27)-C(28) bond length is 1.49 Å. The C(27)-N(14) bond length is 1.35 Å. The C(27)-N(2) bond length is 1.35 Å. In the twenty-second C site, C(28) is bonded in a distorted trigonal non-coplanar geometry to one C(27) and three equivalent H(28,29,30,41,42,49,50,54,55) atoms. All C(28)-H(28,29,30,41,42,49,50,54,55) bond lengths are 1.14 Å. In the twenty-third C site, C(29) is bonded in a distorted trigonal planar geometry to one C(30), one N(16), and one N(3) atom. The C(29)-C(30) bond length is 1.49 Å. The C(29)-N(16) bond length is 1.35 Å. The C(29)-N(3) bond length is 1.35 Å. In the twenty-fourth C site, C(30) is bonded in a distorted trigonal non-coplanar geometry to one C(29) and three equivalent H(31,57,58) atoms. All C(30)-H(31,57,58) bond lengths are 1.14 Å. In the twenty-fifth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(32), one N(15), and one N(4) atom. The C(31)-C(32) bond length is 1.49 Å. The C(31)-N(15) bond length is 1.35 Å. The C(31)-N(4) bond length is 1.35 Å. In the twenty-sixth C site, C(32) is bonded in a distorted trigonal non-coplanar geometry to one C(31) and three equivalent H(32,59,60) atoms. All C(32)-H(32,59,60) bond lengths are 1.14 Å. In the twenty-seventh C site, C(33) is bonded in a distorted trigonal planar geometry to one C(34), one N(21), and one N(5) atom. The C(33)-C(34) bond length is 1.49 Å. The C(33)-N(21) bond length is 1.35 Å. The C(33)-N(5) bond length is 1.35 Å. In the twenty-eighth C site, C(34) is bonded in a distorted trigonal non-coplanar geometry to one C(33) and three equivalent H(33,34,35,43,44,45) atoms. All C(34)-H(33,34,35,43,44,45) bond lengths are 1.14 Å. In the twenty-ninth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(36); one N(10,22); and one N(6) atom. The C(35)-C(36) bond length is 1.49 Å. The C(35)-N(10,22) bond length is 1.35 Å. The C(35)-N(6) bond length is 1.35 Å. In the thirtieth C site, C(36) is bonded in a distorted trigonal non-coplanar geometry to one C(35) and three equivalent H(36,37,38,46,47,48) atoms. All C(36)-H(36,37,38,46,47,48) bond lengths are 1.14 Å. In the thirty-first C site, C(37) is bonded in a distorted trigonal planar geometry to one C(38), one N(24), and one N(7) atom. The C(37)-C(38) bond length is 1.49 Å. The C(37)-N(24) bond length is 1.35 Å. The C(37)-N(7) bond length is 1.35 Å. In the thirty-second C site, C(38) is bonded in a distorted trigonal non-coplanar geometry to one C(37) and three equivalent H(39,40,51,52,53,56) atoms. All C(38)-H(39,40,51,52,53,56) bond lengths are 1.14 Å. In the thirty-third C site, C(39,45) is bonded in a distorted trigonal planar geometry to one C(40,46); one N(11,23); and one N(8) atom. The C(39,45)-C(40,46) bond length is 1.49 Å. The C(39,45)-N(11,23) bond length is 1.35 Å. The C(39,45)-N(8) bond length is 1.35 Å. In the thirty-fourth C site, C(40,46) is bonded in a distorted trigonal non-coplanar geometry to one C(39,45) and three equivalent H(28,29,30,41,42,49,50,54,55) atoms. All C(40,46)-H(28,29,30,41,42,49,50,54,55) bond lengths are 1.14 Å. In the thirty-fifth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(42), one N(17), and one N(9) atom. The C(41)-C(42) bond length is 1.49 Å. The C(41)-N(17) bond length is 1.35 Å. The C(41)-N(9) bond length is 1.35 Å. In the thirty-sixth C site, C(42) is bonded in a distorted trigonal non-coplanar geometry to one C(41) and three equivalent H(33,34,35,43,44,45) atoms. All C(42)-H(33,34,35,43,44,45) bond lengths are 1.14 Å. In the thirty-seventh C site, C(43) is bonded in a distorted trigonal planar geometry to one C(44); one N(10,22); and one N(18) atom. The C(43)-C(44) bond length is 1.49 Å. The C(43)-N(10,22) bond length is 1.35 Å. The C(43)-N(18) bond length is 1.35 Å. In the thirty-eighth C site, C(44) is bonded in a distorted trigonal non-coplanar geometry to one C(43) and three equivalent H(36,37,38,46,47,48) atoms. All C(44)-H(36,37,38,46,47,48) bond lengths are 1.14 Å. In the thirty-ninth C site, C(47) is bonded in a distorted trigonal planar geometry to one C(48), one N(12), and one N(19) atom. The C(47)-C(48) bond length is 1.49 Å. The C(47)-N(12) bond length is 1.35 Å. The C(47)-N(19) bond length is 1.35 Å. In the fortieth C site, C(48) is bonded in a distorted trigonal non-coplanar geometry to one C(47) and three equivalent H(39,40,51,52,53,56) atoms. All C(48)-H(39,40,51,52,53,56) bond lengths are 1.14 Å. There are twenty-two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1); one C(1,13); and one C(25) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2); one C(2,14); and one C(27) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(29), and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(31), and one C(4) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(3), one C(33), and one C(5) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(4); one C(35); and one C(6,18) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Zn(4), one C(37), and one C(7) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Zn(3); one C(39,45); and one C(8,20) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Zn(5), one C(41), and one C(9) atom. In the tenth N site, N(10,22) is bonded in a trigonal planar geometry to one Zn(6); one C(10,22); and one C(43) atom. In the eleventh N site, N(11,23) is bonded in a trigonal planar geometry to one Zn(6); one C(11,23); and one C(39,45) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Zn(5), one C(12), and one C(47) atom. In the thirteenth N site, N(13) is bonded in a trigonal planar geometry to one Zn(4); one C(1,13); and one C(25) atom. The N(13)-C(1,13) bond length is 1.40 Å. In the fourteenth N site, N(14) is bonded in a trigonal planar geometry to one Zn(3); one C(2,14); and one C(27) atom. The N(14)-C(2,14) bond length is 1.40 Å. In the fifteenth N site, N(15) is bonded in a trigonal planar geometry to one Zn(3), one C(15), and one C(31) atom. In the sixteenth N site, N(16) is bonded in a trigonal planar geometry to one Zn(4), one C(16), and one C(29) atom. In the seventeenth N site, N(17) is bonded in a trigonal planar geometry to one Zn(2), one C(17), and one C(41) atom. In the eighteenth N site, N(18) is bonded in a trigonal planar geometry to one Zn(1); one C(43); and one C(6,18) atom. The N(18)-C(6,18) bond length is 1.40 Å. In the nineteenth N site, N(19) is bonded in a trigonal planar geometry to one Zn(1), one C(19), and one C(47) atom. In the twentieth N site, N(20) is bonded in a trigonal planar geometry to one Zn(2); one C(39,45); and one C(8,20) atom. The N(20)-C(39,45) bond length is 1.35 Å. The N(20)-C(8,20) bond length is 1.40 Å. In the twenty-first N site, N(21) is bonded in a trigonal planar geometry to one Zn(6), one C(21), and one C(33) atom. In the twenty-second N site, N(24) is bonded in a trigonal planar geometry to one Zn(6), one C(24), and one C(37) atom. There are nineteen inequivalent H sites. In the first H site, H(1,14) is bonded in a single-bond geometry to one C(1,13) atom. In the second H site, H(2,8,13,20) is bonded in a single-bond geometry to one C(2,14) atom. In the third H site, H(3,16,19) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6,15,18) is bonded in a single-bond geometry to one C(6,18) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(9,21) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(10,22) is bonded in a single-bond geometry to one C(10,22) atom. In the tenth H site, H(11,23) is bonded in a single-bond geometry to one C(11,23) atom. In the eleventh H site, H(12,24) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(25,26,27) is bonded in a single-bond geometry to one C(26) atom. In the fourteenth H site, H(28,29,30,41,42,49,50,54,55) is bonded in a single-bond geometry to one C(28) atom. In the fifteenth H site, H(31,57,58) is bonded in a single-bond geometry to one C(30) atom. In the sixteenth H site, H(32,59,60) is bonded in a single-bond geometry to one C(32) atom. In the seventeenth H site, H(33,34,35,43,44,45) is bonded in a single-bond geometry to one C(34) atom. In the eighteenth H site, H(36,37,38,46,47,48) is bonded in a single-bond geometry to one C(36) atom. In the nineteenth H site, H(39,40,51,52,53,56) is bonded in a single-bond geometry to one C(38) atom. Linkers: 6 CC1=N[CH]C=N1 ,6 CC1=NC=C[N]1. Metal clusters: 6 [Zn]. The MOF has largest included sphere 11.33 A, density 0.95 g/cm3, surface area 5151.23 m2/g, accessible volume 0.64 cm3/g