CuC10H10(NO)4(CH2)4 crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four CuC10H10(NO)4 clusters. In two of the CuC10H10(NO)4 clusters, Cu(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(3) and two equivalent O(2) atoms. Both Cu(1)-N(3) bond lengths are 1.97 Å. Both Cu(1)-O(2) bond lengths are 1.96 Å. There are five inequivalent C sites. In the first C site, C(6) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(8) atom. The C(6)-N(3) bond length is 1.33 Å. The C(6)-N(4) bond length is 1.33 Å. The C(6)-H(8) bond length is 0.93 Å. In the second C site, C(7) is bonded in a 3-coordinate geometry to one C(8), one N(3), and one H(9) atom. The C(7)-C(8) bond length is 1.36 Å. The C(7)-N(3) bond length is 1.34 Å. The C(7)-H(9) bond length is 0.93 Å. In the third C site, C(8) is bonded in a 3-coordinate geometry to one C(7), one N(4), and one H(10) atom. The C(8)-N(4) bond length is 1.36 Å. The C(8)-H(10) bond length is 0.93 Å. In the fourth C site, C(9) is bonded in a 3-coordinate geometry to one N(4) and two equivalent H(11,12) atoms. The C(9)-N(4) bond length is 1.48 Å. Both C(9)-H(11,12) bond lengths are 0.97 Å. In the fifth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(14)-O(1) bond length is 1.23 Å. The C(14)-O(2) bond length is 1.29 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(6), and one C(7) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. There are four inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(11,12) is bonded in a single-bond geometry to one C(9) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(14) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(14) atom. In two of the CuC10H10(NO)4 clusters, Cu(2) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(3) atoms. Both Cu(2)-N(1) bond lengths are 1.97 Å. Both Cu(2)-O(3) bond lengths are 2.00 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.31 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a 3-coordinate geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.36 Å. The C(2)-N(1) bond length is 1.38 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a 3-coordinate geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.36 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(4,5) atoms. The C(4)-N(2) bond length is 1.48 Å. Both C(4)-H(4,5) bond lengths are 0.97 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(11)-O(3) bond length is 1.27 Å. The C(11)-O(4) bond length is 1.23 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(2), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4,5) is bonded in a single-bond geometry to one C(4) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a water-like geometry to one Cu(2) and one C(11) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(11) atom. Linkers: 4 [O]C(=O)CCC([O])=O ,4 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 4 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 3.99 A, density 1.32 g/cm3, surface area 4919.52 m2/g, accessible volume 0.26 cm3/g