C4NH3ZnC19NH10(O2F3)2 is Indium-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of eight 2-methylprop-2-en-1-imine molecules and four ZnC19NH10(O2F3)2 clusters. In each ZnC19NH10(O2F3)2 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one O(1), one O(4), one O(6), and one O(8) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 2.07 Å. The Zn(1)-O(4) bond length is 2.04 Å. The Zn(1)-O(6) bond length is 2.03 Å. The Zn(1)-O(8) bond length is 2.07 Å. In the second Zn site, Zn(2) is bonded in a trigonal bipyramidal geometry to one N(4), one O(2), one O(3), one O(5), and one O(7) atom. The Zn(2)-N(4) bond length is 2.04 Å. The Zn(2)-O(2) bond length is 2.01 Å. The Zn(2)-O(3) bond length is 2.09 Å. The Zn(2)-O(5) bond length is 2.04 Å. The Zn(2)-O(7) bond length is 2.02 Å. There are thirty-eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.24 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(7) bond length is 1.41 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1,4) atom. The C(3)-H(1,4) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2,3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2,3) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.56 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(2,3) atom. The C(6)-H(2,3) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(1,4) atom. The C(7)-H(1,4) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a tetrahedral geometry to one C(10), one C(11), one C(5), and one C(9) atom. The C(8)-C(10) bond length is 1.54 Å. The C(8)-C(11) bond length is 1.54 Å. The C(8)-C(9) bond length is 1.54 Å. In the ninth C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(8), one F(1), one F(2), and one F(3) atom. The C(9)-F(1) bond length is 1.35 Å. The C(9)-F(2) bond length is 1.34 Å. The C(9)-F(3) bond length is 1.32 Å. In the tenth C site, C(10) is bonded in a trigonal non-coplanar geometry to one C(8), one F(4), one F(5), and one F(6) atom. The C(10)-F(4) bond length is 1.34 Å. The C(10)-F(5) bond length is 1.33 Å. The C(10)-F(6) bond length is 1.36 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(8) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(16) bond length is 1.40 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(5) atom. The C(12)-H(5) bond length is 0.95 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(6) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-H(6) bond length is 0.95 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-C(17) bond length is 1.51 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(7) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(7) bond length is 0.95 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(11), one C(15), and one H(8) atom. The C(16)-H(8) bond length is 0.95 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(3), and one O(4) atom. The C(17)-O(3) bond length is 1.25 Å. The C(17)-O(4) bond length is 1.26 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(5), and one O(6) atom. The C(18)-C(19) bond length is 1.53 Å. The C(18)-O(5) bond length is 1.25 Å. The C(18)-O(6) bond length is 1.27 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.38 Å. The C(19)-C(24) bond length is 1.39 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(9) atom. The C(20)-H(9) bond length is 0.95 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(10) atom. The C(21)-C(22) bond length is 1.41 Å. The C(21)-H(10) bond length is 0.95 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(25) atom. The C(22)-C(23) bond length is 1.41 Å. The C(22)-C(25) bond length is 1.54 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(11) atom. The C(23)-H(11) bond length is 0.95 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(19) and one H(12) atom. The C(24)-H(12) bond length is 0.95 Å. In the twenty-fifth C site, C(25) is bonded in a tetrahedral geometry to one C(22), one C(26), one C(27), and one C(28) atom. The C(25)-C(26) bond length is 1.57 Å. The C(25)-C(27) bond length is 1.54 Å. The C(25)-C(28) bond length is 1.54 Å. In the twenty-sixth C site, C(26) is bonded in a trigonal non-coplanar geometry to one C(25), one F(7), one F(8), and one F(9) atom. The C(26)-F(7) bond length is 1.32 Å. The C(26)-F(8) bond length is 1.35 Å. The C(26)-F(9) bond length is 1.35 Å. In the twenty-seventh C site, C(27) is bonded in a trigonal non-coplanar geometry to one C(25), one F(10), one F(11), and one F(12) atom. The C(27)-F(10) bond length is 1.34 Å. The C(27)-F(11) bond length is 1.36 Å. The C(27)-F(12) bond length is 1.32 Å. In the twenty-eighth C site, C(28) is bonded in a trigonal planar geometry to one C(25), one C(29), and one C(33) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-C(33) bond length is 1.38 Å. In the twenty-ninth C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(13) atom. The C(29)-H(13) bond length is 0.95 Å. In the thirtieth C site, C(30) is bonded in a distorted single-bond geometry to one C(31) and one H(14) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-H(14) bond length is 0.95 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(34) atom. The C(31)-C(32) bond length is 1.37 Å. The C(31)-C(34) bond length is 1.50 Å. In the thirty-second C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31), one C(33), and one H(15) atom. The C(32)-C(33) bond length is 1.38 Å. The C(32)-H(15) bond length is 0.95 Å. In the thirty-third C site, C(33) is bonded in a distorted single-bond geometry to one C(28), one C(32), and one H(16) atom. The C(33)-H(16) bond length is 0.95 Å. In the thirty-fourth C site, C(34) is bonded in a bent 120 degrees geometry to one C(31), one O(7), and one O(8) atom. The C(34)-O(7) bond length is 1.26 Å. The C(34)-O(8) bond length is 1.25 Å. In the thirty-fifth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(17) atom. The C(35)-N(1) bond length is 1.33 Å. The C(35)-H(17) bond length is 0.95 Å. In the thirty-sixth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(20) atom. The C(39)-N(1) bond length is 1.32 Å. The C(39)-H(20) bond length is 0.95 Å. In the thirty-seventh C site, C(44) is bonded in a 2-coordinate geometry to one N(4) and one H(24) atom. The C(44)-N(4) bond length is 1.34 Å. The C(44)-H(24) bond length is 0.95 Å. In the thirty-eighth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(25) atom. The C(45)-N(4) bond length is 1.36 Å. The C(45)-H(25) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(35), and one C(39) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Zn(2), one C(44), and one C(45) atom. There are eighteen inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(30) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(32) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(33) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(35) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(39) atom. In the seventeenth H site, H(24) is bonded in a single-bond geometry to one C(44) atom. In the eighteenth H site, H(25) is bonded in a single-bond geometry to one C(45) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(17) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(18) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(18) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(34) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(34) atom. There are twelve inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(9) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(9) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one C(26) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one C(26) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one C(26) atom. In the tenth F site, F(10) is bonded in a single-bond geometry to one C(27) atom. In the eleventh F site, F(11) is bonded in a single-bond geometry to one C(27) atom. In the twelfth F site, F(12) is bonded in a single-bond geometry to one C(27) atom. Linkers: 4 [CH]([N][N][CH]c1ccncc1)c1ccncc1 ,8 [O]C(=O)c1ccc(C(c2ccc(C([O])=O)cc2)(C(F)(F)F)C(F)(F)F)cc1. Metal clusters: 4 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: sql. The MOF has largest included sphere 4.94 A, density 1.29 g/cm3, surface area 4163.36 m2/g, accessible volume 0.34 cm3/g