ZnH11(C7N3)2CH is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two 02329_fluka molecules and two ZnH11(C7N3)2 clusters. In one of the ZnH11(C7N3)2 clusters, Zn(1) is bonded in a trigonal non-coplanar geometry to one N(4), one N(8), and one N(9) atom. The Zn(1)-N(4) bond length is 2.03 Å. The Zn(1)-N(8) bond length is 2.01 Å. The Zn(1)-N(9) bond length is 2.01 Å. There are fourteen inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(8), and one H(22) atom. The C(2)-N(2) bond length is 1.34 Å. The C(2)-N(8) bond length is 1.30 Å. The C(2)-H(22) bond length is 0.93 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(8) atom. The C(3)-N(7) bond length is 1.34 Å. The C(3)-H(8) bond length is 0.93 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(13) and one H(14) atom. The C(6)-C(13) bond length is 1.39 Å. The C(6)-H(14) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one N(7) atom. The C(7)-N(7) bond length is 1.43 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(5) atom. The C(8)-N(4) bond length is 1.40 Å. The C(8)-H(5) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one N(11) atom. The C(11)-N(11) bond length is 1.45 Å. In the seventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(21), one C(6), and one N(2) atom. The C(13)-C(21) bond length is 1.36 Å. The C(13)-N(2) bond length is 1.41 Å. In the eighth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(8), and one H(9) atom. The C(14)-C(15) bond length is 1.37 Å. The C(14)-N(8) bond length is 1.40 Å. The C(14)-H(9) bond length is 0.93 Å. In the ninth C site, C(15) is bonded in a 3-coordinate geometry to one C(14), one N(2), and one H(13) atom. The C(15)-N(2) bond length is 1.40 Å. The C(15)-H(13) bond length is 0.93 Å. In the tenth C site, C(16) is bonded in a trigonal planar geometry to one N(4), one N(7), and one H(17) atom. The C(16)-N(4) bond length is 1.31 Å. The C(16)-N(7) bond length is 1.35 Å. The C(16)-H(17) bond length is 0.93 Å. In the eleventh C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(26), one N(11), and one H(1) atom. The C(17)-C(26) bond length is 1.37 Å. The C(17)-N(11) bond length is 1.34 Å. The C(17)-H(1) bond length is 0.93 Å. In the twelfth C site, C(21) is bonded in a distorted single-bond geometry to one C(13) and one H(3) atom. The C(21)-H(3) bond length is 0.93 Å. In the thirteenth C site, C(22) is bonded in a trigonal planar geometry to one N(11), one N(9), and one H(21) atom. The C(22)-N(11) bond length is 1.32 Å. The C(22)-N(9) bond length is 1.31 Å. The C(22)-H(21) bond length is 0.93 Å. In the fourteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(9), and one H(24) atom. The C(26)-N(9) bond length is 1.34 Å. The C(26)-H(24) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(2) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(16), and one C(8) atom. In the third N site, N(7) is bonded in a trigonal planar geometry to one C(16), one C(3), and one C(7) atom. In the fourth N site, N(8) is bonded in a trigonal planar geometry to one Zn(1), one C(14), and one C(2) atom. In the fifth N site, N(9) is bonded in a trigonal planar geometry to one Zn(1), one C(22), and one C(26) atom. In the sixth N site, N(11) is bonded in a trigonal planar geometry to one C(11), one C(17), and one C(22) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(17) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(21) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(21) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(2) atom. In the eleventh H site, H(24) is bonded in a single-bond geometry to one C(26) atom. In one of the ZnH11(C7N3)2 clusters, Zn(2) is bonded in a trigonal non-coplanar geometry to one N(12), one N(3), and one N(5) atom. The Zn(2)-N(12) bond length is 2.04 Å. The Zn(2)-N(3) bond length is 2.03 Å. The Zn(2)-N(5) bond length is 1.97 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(10), one C(23), and one N(6) atom. The C(1)-C(10) bond length is 1.40 Å. The C(1)-C(23) bond length is 1.38 Å. The C(1)-N(6) bond length is 1.42 Å. In the second C site, C(4) is bonded in a trigonal planar geometry to one N(10), one N(3), and one H(20) atom. The C(4)-N(10) bond length is 1.35 Å. The C(4)-N(3) bond length is 1.29 Å. The C(4)-H(20) bond length is 0.93 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(4) atom. The C(5)-N(5) bond length is 1.33 Å. The C(5)-N(6) bond length is 1.36 Å. The C(5)-H(4) bond length is 0.93 Å. In the fourth C site, C(9) is bonded in a 3-coordinate geometry to one C(12), one N(6), and one H(2) atom. The C(9)-C(12) bond length is 1.32 Å. The C(9)-N(6) bond length is 1.39 Å. The C(9)-H(2) bond length is 0.93 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(1) and one H(7,10) atom. The C(10)-H(7,10) bond length is 0.93 Å. In the sixth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(5), and one H(23) atom. The C(12)-N(5) bond length is 1.41 Å. The C(12)-H(23) bond length is 0.93 Å. In the seventh C site, C(18) is bonded in a distorted single-bond geometry to one N(1) atom. The C(18)-N(1) bond length is 1.42 Å. In the eighth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(6) atom. The C(20)-N(10) bond length is 1.35 Å. The C(20)-H(6) bond length is 0.93 Å. In the ninth C site, C(23) is bonded in a distorted single-bond geometry to one C(1) and one H(7,10) atom. The C(23)-H(7,10) bond length is 0.93 Å. In the tenth C site, C(24) is bonded in a 3-coordinate geometry to one C(25), one N(12), and one H(16) atom. The C(24)-C(25) bond length is 1.36 Å. The C(24)-N(12) bond length is 1.38 Å. The C(24)-H(16) bond length is 0.93 Å. In the eleventh C site, C(25) is bonded in a 2-coordinate geometry to one C(24), one N(1), and one H(11) atom. The C(25)-N(1) bond length is 1.33 Å. The C(25)-H(11) bond length is 0.93 Å. In the twelfth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(15) atom. The C(28)-N(3) bond length is 1.35 Å. The C(28)-H(15) bond length is 0.93 Å. In the thirteenth C site, C(29) is bonded in a trigonal planar geometry to one N(1), one N(12), and one H(18) atom. The C(29)-N(1) bond length is 1.35 Å. The C(29)-N(12) bond length is 1.30 Å. The C(29)-H(18) bond length is 0.93 Å. In the fourteenth C site, C(30) is bonded in a distorted single-bond geometry to one N(10) atom. The C(30)-N(10) bond length is 1.43 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(18), one C(25), and one C(29) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(28), and one C(4) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Zn(2), one C(12), and one C(5) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(9) atom. In the fifth N site, N(10) is bonded in a trigonal planar geometry to one C(20), one C(30), and one C(4) atom. In the sixth N site, N(12) is bonded in a trigonal planar geometry to one Zn(2), one C(24), and one C(29) atom. There are ten inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(20) atom. In the fourth H site, H(7,10) is bonded in a single-bond geometry to one C(23) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(25) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(28) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(29) atom. In the ninth H site, H(20) is bonded in a single-bond geometry to one C(4) atom. In the tenth H site, H(23) is bonded in a single-bond geometry to one C(12) atom. Linkers: 2 c1cn(-c2cc(-n3ccnc3)cc(-n3ccnc3)c2)cn1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 6.80 A, density 0.78 g/cm3, surface area 4820.52 m2/g, accessible volume 0.91 cm3/g