Ce2W15Mn2C25P2N5H20O49 crystallizes in the triclinic P-1 space group. There are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a distorted trigonal pyramidal geometry to one O(10), one O(27), one O(39), and one O(41) atom. The Ce(1)-O(10) bond length is 2.38 Å. The Ce(1)-O(27) bond length is 2.53 Å. The Ce(1)-O(39) bond length is 2.56 Å. The Ce(1)-O(41) bond length is 2.40 Å. In the second Ce site, Ce(2) is bonded in a distorted see-saw-like geometry to one O(17), one O(29), one O(34), and one O(44) atom. The Ce(2)-O(17) bond length is 2.59 Å. The Ce(2)-O(29) bond length is 2.47 Å. The Ce(2)-O(34) bond length is 2.44 Å. The Ce(2)-O(44) bond length is 2.43 Å. There are fifteen inequivalent W sites. In the first W site, W(1) is bonded in a 6-coordinate geometry to one O(17), one O(19), one O(33), one O(35), one O(45), and one O(8) atom. The W(1)-O(17) bond length is 1.71 Å. The W(1)-O(19) bond length is 1.90 Å. The W(1)-O(33) bond length is 1.87 Å. The W(1)-O(35) bond length is 2.36 Å. The W(1)-O(45) bond length is 1.89 Å. The W(1)-O(8) bond length is 1.86 Å. In the second W site, W(2) is bonded to one O(32), one O(38), one O(4), one O(6), and one O(9) atom to form distorted WO5 square pyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one W(11)O5 square pyramid,  a cornercorner with one W(4)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(3)O5 square pyramid. The corner-sharing octahedral tilt angles are 44°. The W(2)-O(32) bond length is 2.08 Å. The W(2)-O(38) bond length is 1.86 Å. The W(2)-O(4) bond length is 2.34 Å. The W(2)-O(6) bond length is 1.94 Å. The W(2)-O(9) bond length is 1.78 Å. In the third W site, W(3) is bonded to one O(21), one O(4), one O(47), one O(48), and one O(6) atom to form distorted WO5 square pyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one W(9)O5 square pyramid,  a cornercorner with one Mn(2)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(2)O5 square pyramid. The corner-sharing octahedral tilt angles are 51°. The W(3)-O(21) bond length is 1.84 Å. The W(3)-O(4) bond length is 2.36 Å. The W(3)-O(47) bond length is 2.06 Å. The W(3)-O(48) bond length is 1.90 Å. The W(3)-O(6) bond length is 1.89 Å. In the fourth W site, W(4) is bonded to one O(26), one O(30), one O(32), one O(37), and one O(40) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(12)O5 square pyramid,  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one W(8)O5 square pyramid, and  a cornercorner with one P(1)O4 tetrahedra. The W(4)-O(26) bond length is 2.38 Å. The W(4)-O(30) bond length is 1.89 Å. The W(4)-O(32) bond length is 1.79 Å. The W(4)-O(37) bond length is 1.89 Å. The W(4)-O(40) bond length is 1.99 Å. In the fifth W site, W(5) is bonded to one O(22), one O(28), one O(3), one O(31), and one O(5) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(10)O5 square pyramid,  a cornercorner with one W(6)O5 square pyramid, and  a cornercorner with one P(1)O4 tetrahedra. The W(5)-O(22) bond length is 1.89 Å. The W(5)-O(28) bond length is 1.89 Å. The W(5)-O(3) bond length is 1.76 Å. The W(5)-O(31) bond length is 2.31 Å. The W(5)-O(5) bond length is 2.02 Å. In the sixth W site, W(6) is bonded to one O(2), one O(20), one O(23), one O(24), and one O(28) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(14)O5 square pyramid,  a cornercorner with one W(5)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(8)O5 square pyramid. The W(6)-O(2) bond length is 2.01 Å. The W(6)-O(20) bond length is 1.80 Å. The W(6)-O(23) bond length is 2.39 Å. The W(6)-O(24) bond length is 1.91 Å. The W(6)-O(28) bond length is 1.90 Å. In the seventh W site, W(7) is bonded in a 6-coordinate geometry to one O(18), one O(26), one O(30), one O(33), one O(39), and one O(47) atom. The W(7)-O(18) bond length is 1.85 Å. The W(7)-O(26) bond length is 2.35 Å. The W(7)-O(30) bond length is 1.93 Å. The W(7)-O(33) bond length is 2.01 Å. The W(7)-O(39) bond length is 1.71 Å. The W(7)-O(47) bond length is 1.80 Å. In the eighth W site, W(8) is bonded to one O(23), one O(24), one O(37), one O(42), and one O(49) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(11)O5 square pyramid,  a cornercorner with one W(12)O5 square pyramid,  a cornercorner with one W(4)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(6)O5 square pyramid. The W(8)-O(23) bond length is 2.37 Å. The W(8)-O(24) bond length is 1.94 Å. The W(8)-O(37) bond length is 1.89 Å. The W(8)-O(42) bond length is 2.02 Å. The W(8)-O(49) bond length is 1.79 Å. In the ninth W site, W(9) is bonded to one O(13), one O(14), one O(36), one O(43), and one O(48) atom to form distorted WO5 square pyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one W(3)O5 square pyramid,  a cornercorner with one Mn(2)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(10)O5 square pyramid. The corner-sharing octahedral tilt angles are 50°. The W(9)-O(13) bond length is 2.03 Å. The W(9)-O(14) bond length is 1.88 Å. The W(9)-O(36) bond length is 1.83 Å. The W(9)-O(43) bond length is 2.37 Å. The W(9)-O(48) bond length is 1.87 Å. In the tenth W site, W(10) is bonded to one O(1), one O(14), one O(3), one O(43), and one O(46) atom to form distorted WO5 square pyramids that share  a cornercorner with one Mn(1)O6 octahedra,  a cornercorner with one W(14)O5 square pyramid,  a cornercorner with one W(5)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(9)O5 square pyramid. The corner-sharing octahedral tilt angles are 43°. The W(10)-O(1) bond length is 1.87 Å. The W(10)-O(14) bond length is 1.96 Å. The W(10)-O(3) bond length is 2.11 Å. The W(10)-O(43) bond length is 2.35 Å. The W(10)-O(46) bond length is 1.75 Å. In the eleventh W site, W(11) is bonded to one O(11), one O(16), one O(38), one O(49), and one O(7) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one W(8)O5 square pyramid,  a cornercorner with one Mn(2)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(14)O5 square pyramid. The W(11)-O(11) bond length is 2.37 Å. The W(11)-O(16) bond length is 1.78 Å. The W(11)-O(38) bond length is 1.95 Å. The W(11)-O(49) bond length is 2.07 Å. The W(11)-O(7) bond length is 1.91 Å. In the twelfth W site, W(12) is bonded to one O(15), one O(19), one O(35), one O(40), and one O(42) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(4)O5 square pyramid,  a cornercorner with one W(8)O5 square pyramid, and  a cornercorner with one P(1)O4 tetrahedra. The W(12)-O(15) bond length is 1.96 Å. The W(12)-O(19) bond length is 1.95 Å. The W(12)-O(35) bond length is 2.35 Å. The W(12)-O(40) bond length is 1.88 Å. The W(12)-O(42) bond length is 1.88 Å. In the thirteenth W site, W(13) is bonded in a 5-coordinate geometry to one O(15), one O(2), one O(35), one O(45), and one O(5) atom. The W(13)-O(15) bond length is 1.88 Å. The W(13)-O(2) bond length is 1.86 Å. The W(13)-O(35) bond length is 2.37 Å. The W(13)-O(45) bond length is 1.97 Å. The W(13)-O(5) bond length is 1.85 Å. In the fourteenth W site, W(14) is bonded to one O(1), one O(11), one O(12), one O(20), and one O(7) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(10)O5 square pyramid,  a cornercorner with one W(6)O5 square pyramid,  a cornercorner with one Mn(2)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(11)O5 square pyramid. The W(14)-O(1) bond length is 1.92 Å. The W(14)-O(11) bond length is 2.35 Å. The W(14)-O(12) bond length is 1.78 Å. The W(14)-O(20) bond length is 2.06 Å. The W(14)-O(7) bond length is 1.93 Å. In the fifteenth W site, W(15) is bonded in a 6-coordinate geometry to one O(13), one O(18), one O(22), one O(27), one O(31), and one O(8) atom. The W(15)-O(13) bond length is 1.82 Å. The W(15)-O(18) bond length is 1.90 Å. The W(15)-O(22) bond length is 1.90 Å. The W(15)-O(27) bond length is 1.73 Å. The W(15)-O(31) bond length is 2.40 Å. The W(15)-O(8) bond length is 2.02 Å. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(21), one O(36), one O(46), one O(9), and two equivalent O(25) atoms to form MnO6 octahedra that share  a cornercorner with one W(10)O5 square pyramid,  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one W(3)O5 square pyramid,  a cornercorner with one W(9)O5 square pyramid, corners with two equivalent P(2)O4 tetrahedra,  an edgeedge with one Mn(1)O6 octahedra, and edges with two equivalent Mn(2)O5 square pyramids. The Mn(1)-O(21) bond length is 2.19 Å. The Mn(1)-O(36) bond length is 2.17 Å. The Mn(1)-O(46) bond length is 2.09 Å. The Mn(1)-O(9) bond length is 2.07 Å. There is one shorter (2.25 Å) and one longer (2.26 Å) Mn(1)-O(25) bond length. In the second Mn site, Mn(2) is bonded to one O(12), one O(16), one O(21), one O(25), and one O(36) atom to form MnO5 square pyramids that share  a cornercorner with one W(11)O5 square pyramid,  a cornercorner with one W(14)O5 square pyramid,  a cornercorner with one W(3)O5 square pyramid,  a cornercorner with one W(9)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and edges with two equivalent Mn(1)O6 octahedra. The Mn(2)-O(12) bond length is 2.09 Å. The Mn(2)-O(16) bond length is 2.08 Å. The Mn(2)-O(21) bond length is 2.14 Å. The Mn(2)-O(25) bond length is 2.25 Å. The Mn(2)-O(36) bond length is 2.17 Å. There are twenty-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(17) atom. The C(1)-N(2) bond length is 1.27 Å. The C(1)-H(17) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(13) atom. The C(2)-N(3) bond length is 1.34 Å. The C(2)-H(13) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one H(5) atom. The C(3)-C(16) bond length is 1.36 Å. The C(3)-C(20) bond length is 1.29 Å. The C(3)-H(5) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(13), one N(4), and one H(8) atom. The C(4)-C(13) bond length is 1.34 Å. The C(4)-N(4) bond length is 1.29 Å. The C(4)-H(8) bond length is 0.94 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(25), one C(7), and one H(7) atom. The C(5)-C(25) bond length is 1.34 Å. The C(5)-C(7) bond length is 1.36 Å. The C(5)-H(7) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(14), one C(15), and one H(2) atom. The C(6)-C(14) bond length is 1.42 Å. The C(6)-C(15) bond length is 1.27 Å. The C(6)-H(2) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(5) atom. The C(7)-C(13) bond length is 1.40 Å. The C(7)-C(14) bond length is 1.45 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(3) atom. The C(8)-N(5) bond length is 1.30 Å. The C(8)-H(3) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a single-bond geometry to one C(17) and one H(15) atom. The C(9)-C(17) bond length is 1.36 Å. The C(9)-H(15) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(19), one N(5), and one H(6) atom. The C(10)-C(19) bond length is 1.38 Å. The C(10)-N(5) bond length is 1.32 Å. The C(10)-H(6) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(12), one C(17), and one C(19) atom. The C(11)-C(12) bond length is 1.35 Å. The C(11)-C(17) bond length is 1.43 Å. The C(11)-C(19) bond length is 1.37 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(18) atom. The C(12)-H(18) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(4), one C(7), and one H(11) atom. The C(13)-H(11) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(18), one C(6), and one C(7) atom. The C(14)-C(18) bond length is 1.37 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(6), one N(3), and one H(9) atom. The C(15)-N(3) bond length is 1.39 Å. The C(15)-H(9) bond length is 0.93 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(16), one C(22), and one C(3) atom. The C(16)-C(16) bond length is 1.55 Å. The C(16)-C(22) bond length is 1.43 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(11), one C(23), and one C(9) atom. The C(17)-C(23) bond length is 1.35 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(14) and one H(14) atom. The C(18)-H(14) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(10), one C(11), and one H(10) atom. The C(19)-H(10) bond length is 0.93 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(1) atom. The C(20)-N(1) bond length is 1.36 Å. The C(20)-H(1) bond length is 0.94 Å. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(21)-N(1) bond length is 1.30 Å. The C(21)-H(4) bond length is 0.93 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(22)-H(12) bond length is 0.93 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(17) and one H(20) atom. The C(23)-H(20) bond length is 0.93 Å. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(16) atom. The C(24)-N(2) bond length is 1.39 Å. The C(24)-H(16) bond length is 0.93 Å. In the twenty-fifth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(5), one N(4), and one H(19) atom. The C(25)-N(4) bond length is 1.32 Å. The C(25)-H(19) bond length is 0.93 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(23), one O(26), one O(31), and one O(35) atom to form PO4 tetrahedra that share  a cornercorner with one W(12)O5 square pyramid,  a cornercorner with one W(4)O5 square pyramid,  a cornercorner with one W(5)O5 square pyramid,  a cornercorner with one W(6)O5 square pyramid, and  a cornercorner with one W(8)O5 square pyramid. The P(1)-O(23) bond length is 1.51 Å. The P(1)-O(26) bond length is 1.51 Å. The P(1)-O(31) bond length is 1.50 Å. The P(1)-O(35) bond length is 1.61 Å. In the second P site, P(2) is bonded to one O(11), one O(25), one O(4), and one O(43) atom to form PO4 tetrahedra that share corners with two equivalent Mn(1)O6 octahedra,  a cornercorner with one W(10)O5 square pyramid,  a cornercorner with one W(11)O5 square pyramid,  a cornercorner with one W(14)O5 square pyramid,  a cornercorner with one W(2)O5 square pyramid,  a cornercorner with one W(3)O5 square pyramid,  a cornercorner with one W(9)O5 square pyramid, and  a cornercorner with one Mn(2)O5 square pyramid. The corner-sharing octahedral tilt angles are 59°. The P(2)-O(11) bond length is 1.54 Å. The P(2)-O(25) bond length is 1.61 Å. The P(2)-O(4) bond length is 1.54 Å. The P(2)-O(43) bond length is 1.51 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(20), one C(21), and one O(34) atom. The N(1)-O(34) bond length is 1.32 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(24), and one O(29) atom. The N(2)-O(29) bond length is 1.38 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(15), one C(2), and one O(10) atom. The N(3)-O(10) bond length is 1.34 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(25), one C(4), and one O(44) atom. The N(4)-O(44) bond length is 1.28 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(10), one C(8), and one O(41) atom. The N(5)-O(41) bond length is 1.32 Å. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(20) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(21) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(2) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(9) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(1) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(12) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(23) atom. There are forty-nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one W(10) and one W(14) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one W(13) and one W(6) atom. In the third O site, O(3) is bonded in a linear geometry to one W(10) and one W(5) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one W(2), one W(3), and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one W(13) and one W(5) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one W(2) and one W(3) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one W(11) and one W(14) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one W(1) and one W(15) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one W(2) and one Mn(1) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Ce(1) and one N(3) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one W(11), one W(14), and one P(2) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one W(14) and one Mn(2) atom. In the thirteenth O site, O(13) is bonded in a distorted linear geometry to one W(15) and one W(9) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one W(10) and one W(9) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one W(12) and one W(13) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one W(11) and one Mn(2) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Ce(2) and one W(1) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one W(15) and one W(7) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one W(1) and one W(12) atom. In the twentieth O site, O(20) is bonded in a linear geometry to one W(14) and one W(6) atom. In the twenty-first O site, O(21) is bonded in a trigonal planar geometry to one W(3), one Mn(1), and one Mn(2) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one W(15) and one W(5) atom. In the twenty-third O site, O(23) is bonded in a distorted single-bond geometry to one W(6), one W(8), and one P(1) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one W(6) and one W(8) atom. In the twenty-fifth O site, O(25) is bonded to one Mn(2), two equivalent Mn(1), and one P(2) atom to form distorted edge-sharing OMn3P trigonal pyramids. In the twenty-sixth O site, O(26) is bonded in a distorted single-bond geometry to one W(4), one W(7), and one P(1) atom. In the twenty-seventh O site, O(27) is bonded in a distorted single-bond geometry to one Ce(1) and one W(15) atom. In the twenty-eighth O site, O(28) is bonded in a bent 150 degrees geometry to one W(5) and one W(6) atom. In the twenty-ninth O site, O(29) is bonded in a bent 120 degrees geometry to one Ce(2) and one N(2) atom. In the thirtieth O site, O(30) is bonded in a bent 120 degrees geometry to one W(4) and one W(7) atom. In the thirty-first O site, O(31) is bonded in a distorted single-bond geometry to one W(15), one W(5), and one P(1) atom. In the thirty-second O site, O(32) is bonded in a linear geometry to one W(2) and one W(4) atom. In the thirty-third O site, O(33) is bonded in a bent 150 degrees geometry to one W(1) and one W(7) atom. In the thirty-fourth O site, O(34) is bonded in a bent 120 degrees geometry to one Ce(2) and one N(1) atom. In the thirty-fifth O site, O(35) is bonded in a distorted single-bond geometry to one W(1), one W(12), one W(13), and one P(1) atom. In the thirty-sixth O site, O(36) is bonded in a trigonal planar geometry to one W(9), one Mn(1), and one Mn(2) atom. In the thirty-seventh O site, O(37) is bonded in a bent 150 degrees geometry to one W(4) and one W(8) atom. In the thirty-eighth O site, O(38) is bonded in a bent 150 degrees geometry to one W(11) and one W(2) atom. In the thirty-ninth O site, O(39) is bonded in a distorted single-bond geometry to one Ce(1) and one W(7) atom. In the fortieth O site, O(40) is bonded in a bent 150 degrees geometry to one W(12) and one W(4) atom. In the forty-first O site, O(41) is bonded in a distorted bent 120 degrees geometry to one Ce(1) and one N(5) atom. In the forty-second O site, O(42) is bonded in a bent 150 degrees geometry to one W(12) and one W(8) atom. In the forty-third O site, O(43) is bonded in a distorted single-bond geometry to one W(10), one W(9), and one P(2) atom. In the forty-fourth O site, O(44) is bonded in a bent 150 degrees geometry to one Ce(2) and one N(4) atom. In the forty-fifth O site, O(45) is bonded in a distorted single-bond geometry to one W(1) and one W(13) atom. In the forty-sixth O site, O(46) is bonded in a bent 150 degrees geometry to one W(10) and one Mn(1) atom. In the forty-seventh O site, O(47) is bonded in a distorted linear geometry to one W(3) and one W(7) atom. In the forty-eighth O site, O(48) is bonded in a bent 150 degrees geometry to one W(3) and one W(9) atom. In the forty-ninth O site, O(49) is bonded in a linear geometry to one W(11) and one W(8) atom. Linkers: 3 [O-][n+]1ccc(-c2cc[n+]([O-])cc2)cc1 ,2 [O]N1[CH]C=C(c2cc[n+]([O-])cc2)C=C1. Metal clusters: 4 [Ce] ,4 [Mn] ,30 [W]. The MOF has largest included sphere 7.06 A, density 3.19 g/cm3, surface area 1409.86 m2/g, accessible volume 0.16 cm3/g