MnC11H9(NO)3(CH)2CH3CO is Indium-derived structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, sixteen dimethyl ether molecules, and eight MnC11H9(NO)3 clusters. In each MnC11H9(NO)3 cluster, Mn(1) is bonded to one N(1), one N(3), one O(2), one O(3), and two equivalent O(4) atoms to form MnN2O4 octahedra that share corners with two equivalent C(15)H3O tetrahedra and  an edgeedge with one Mn(1)N2O4 octahedra. The Mn(1)-N(1) bond length is 1.98 Å. The Mn(1)-N(3) bond length is 2.36 Å. The Mn(1)-O(2) bond length is 1.91 Å. The Mn(1)-O(3) bond length is 1.95 Å. There is one shorter (1.88 Å) and one longer (2.19 Å) Mn(1)-O(4) bond length. There are eleven inequivalent C sites. In the first C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(6) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-H(6) bond length is 0.95 Å. In the second C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-C(8) bond length is 1.43 Å. In the third C site, C(7) is bonded in a single-bond geometry to one C(6) and one O(2) atom. The C(7)-O(2) bond length is 1.32 Å. In the fourth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one H(7) atom. The C(8)-N(1) bond length is 1.28 Å. The C(8)-H(7) bond length is 0.95 Å. In the fifth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one O(3) atom. The C(9)-C(10) bond length is 1.48 Å. The C(9)-N(2) bond length is 1.29 Å. The C(9)-O(3) bond length is 1.30 Å. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(9) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-C(14) bond length is 1.39 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(11)-H(8) bond length is 0.95 Å. In the eighth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(12)-N(3) bond length is 1.34 Å. The C(12)-H(9) bond length is 0.95 Å. In the ninth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(10) atom. The C(13)-N(3) bond length is 1.34 Å. The C(13)-H(10) bond length is 0.95 Å. In the tenth C site, C(14) is bonded in a distorted single-bond geometry to one C(10) and one H(11) atom. The C(14)-H(11) bond length is 0.95 Å. In the eleventh C site, C(15) is bonded to one H(13); two equivalent H(12,14); and one O(4) atom to form CH3O tetrahedra that share corners with two equivalent Mn(1)N2O4 octahedra. The corner-sharing octahedral tilt angles range from 57-58°. The C(15)-H(13) bond length is 0.98 Å. Both C(15)-H(12,14) bond lengths are 0.98 Å. The C(15)-O(4) bond length is 1.41 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(8), and one N(2) atom. The N(1)-N(2) bond length is 1.41 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(9) and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Mn(1), one C(12), and one C(13) atom. There are eight inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(12,14) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. There are three inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(7) atom. In the second O site, O(3) is bonded in a water-like geometry to one Mn(1) and one C(9) atom. In the third O site, O(4) is bonded in a distorted trigonal planar geometry to two equivalent Mn(1) and one C(15) atom. Linkers: 8 COc1cccc(/C=N/[N]C(=O)c2ccncc2)c1[O]. Metal clusters: 4 CO[Mn]([O])[O].CO[Mn]([O])[O]. The MOF has largest included sphere 5.77 A, density 1.03 g/cm3, surface area 4634.50 m2/g, accessible volume 0.42 cm3/g