La(CO2)6(CoC4H10(NS)2)3 is Indium-derived structured and crystallizes in the trigonal R32 space group. The structure is zero-dimensional and consists of three CoC4H10(NS)2 clusters and three La(CO2)6 clusters. In each CoC4H10(NS)2 cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded to three equivalent N(1) and three equivalent S(1) atoms to form face-sharing CoS3N3 octahedra. All Co(1)-N(1) bond lengths are 1.99 Å. All Co(1)-S(1) bond lengths are 2.24 Å. In the second Co site, Co(2) is bonded to six equivalent S(1) atoms to form face-sharing CoS6 octahedra. All Co(2)-S(1) bond lengths are 2.26 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a water-like geometry to two equivalent H(3,4) and one S(1) atom. Both C(1)-H(3,4) bond lengths are 0.99 Å. The C(1)-S(1) bond length is 1.82 Å. In the second C site, C(2) is bonded in a 2-coordinate geometry to one N(1) and one H(5) atom. The C(2)-N(1) bond length is 1.49 Å. The C(2)-H(5) bond length is 1.00 Å. N(1) is bonded in a distorted water-like geometry to one Co(1), one C(2), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 0.92 Å. The N(1)-H(2) bond length is 0.92 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one Co(2), and one C(1) atom. In each La(CO2)6 cluster, La(1) is bonded in a cuboctahedral geometry to six equivalent O(1) and six equivalent O(2) atoms. All La(1)-O(1) bond lengths are 2.60 Å. All La(1)-O(2) bond lengths are 2.88 Å. C(3) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(3)-O(1) bond length is 1.27 Å. The C(3)-O(2) bond length is 1.24 Å. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one La(1) and one C(3) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one La(1) and one C(3) atom. Linkers: 18 N[C@@H](C[S])C([O])=O. Metal clusters: 3 [La] ,9 [Co]. The MOF has largest included sphere 4.89 A, density 1.62 g/cm3, surface area 2897.07 m2/g, accessible volume 0.26 cm3/g