La2CuC30N4H20O13(CH3)2 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a La2CuC30N4H20O13 framework. In the La2CuC30N4H20O13 framework, there are two inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(13), one O(2), one O(5), one O(6), one O(8), and one O(9) atom. The La(1)-O(1) bond length is 2.66 Å. The La(1)-O(10) bond length is 2.75 Å. The La(1)-O(11) bond length is 2.59 Å. The La(1)-O(13) bond length is 2.55 Å. The La(1)-O(2) bond length is 2.70 Å. The La(1)-O(5) bond length is 2.61 Å. The La(1)-O(6) bond length is 2.63 Å. The La(1)-O(8) bond length is 2.51 Å. The La(1)-O(9) bond length is 2.50 Å. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(10), one O(12), one O(13), one O(2), one O(3), one O(4), one O(7), and two equivalent O(9) atoms. The La(2)-O(10) bond length is 2.47 Å. The La(2)-O(12) bond length is 2.65 Å. The La(2)-O(13) bond length is 2.60 Å. The La(2)-O(2) bond length is 2.55 Å. The La(2)-O(3) bond length is 2.62 Å. The La(2)-O(4) bond length is 2.57 Å. The La(2)-O(7) bond length is 2.56 Å. There is one shorter (2.47 Å) and one longer (2.55 Å) La(2)-O(9) bond length. Cu(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Cu(1)-N(1) bond length is 2.05 Å. The Cu(1)-N(2) bond length is 2.04 Å. The Cu(1)-N(3) bond length is 2.05 Å. The Cu(1)-N(4) bond length is 2.04 Å. There are thirty inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(11), one C(2), and one N(1) atom. The C(1)-C(11) bond length is 1.48 Å. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.34 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(12), and one C(3) atom. The C(2)-C(12) bond length is 1.50 Å. The C(2)-C(3) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.48 Å. The C(5)-N(1) bond length is 1.34 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-N(2) bond length is 1.35 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(7)-H(3) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(4) bond length is 0.95 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-C(14) bond length is 1.50 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one N(2) atom. The C(10)-C(13) bond length is 1.49 Å. The C(10)-N(2) bond length is 1.35 Å. In the eleventh C site, C(11) is bonded in a trigonal non-coplanar geometry to one C(1) and three equivalent H(5,6,7) atoms. All C(11)-H(5,6,7) bond lengths are 0.98 Å. In the twelfth C site, C(12) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(12)-O(1) bond length is 1.25 Å. The C(12)-O(2) bond length is 1.27 Å. In the thirteenth C site, C(13) is bonded in a trigonal non-coplanar geometry to one C(10) and three equivalent H(8,9,10) atoms. All C(13)-H(8,9,10) bond lengths are 0.98 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.25 Å. The C(14)-O(4) bond length is 1.26 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one C(25), and one N(3) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-C(25) bond length is 1.51 Å. The C(15)-N(3) bond length is 1.35 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(26) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(26) bond length is 1.50 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(17)-H(11) bond length is 0.95 Å. In the eighteenth C site, C(18) is bonded in a single-bond geometry to one C(19) and one H(12) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-H(12) bond length is 0.95 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one N(3) atom. The C(19)-C(20) bond length is 1.48 Å. The C(19)-N(3) bond length is 1.35 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one N(4) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-N(4) bond length is 1.36 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one H(13) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-H(13) bond length is 0.95 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one H(14) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(14) bond length is 0.95 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.41 Å. The C(23)-C(28) bond length is 1.50 Å. In the twenty-fourth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one C(27), and one N(4) atom. The C(24)-C(27) bond length is 1.49 Å. The C(24)-N(4) bond length is 1.35 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal non-coplanar geometry to one C(15) and three equivalent H(15,16,17) atoms. All C(25)-H(15,16,17) bond lengths are 0.98 Å. In the twenty-sixth C site, C(26) is bonded in a bent 120 degrees geometry to one C(16), one O(5), and one O(6) atom. The C(26)-O(5) bond length is 1.26 Å. The C(26)-O(6) bond length is 1.26 Å. In the twenty-seventh C site, C(27) is bonded in a trigonal non-coplanar geometry to one C(24) and three equivalent H(18,19,20) atoms. All C(27)-H(18,19,20) bond lengths are 0.98 Å. In the twenty-eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(7), and one O(8) atom. The C(28)-O(7) bond length is 1.25 Å. The C(28)-O(8) bond length is 1.27 Å. In the twenty-ninth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(11) atom. The C(30)-O(10) bond length is 1.27 Å. The C(30)-O(11) bond length is 1.26 Å. In the thirtieth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one O(12) and one O(13) atom. The C(31)-O(12) bond length is 1.25 Å. The C(31)-O(13) bond length is 1.27 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(15), and one C(19) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(20), and one C(24) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5,6,7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8,9,10) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(15,16,17) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(18,19,20) is bonded in a single-bond geometry to one C(27) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one La(1) and one C(12) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one La(1), one La(2), and one C(12) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one La(2) and one C(14) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one La(2) and one C(14) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one La(1) and one C(26) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one La(1) and one C(26) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one La(2) and one C(28) atom. In the eighth O site, O(11) is bonded in a single-bond geometry to one La(1) and one C(30) atom. In the ninth O site, O(12) is bonded in a distorted single-bond geometry to one La(2) and one C(31) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one La(1), one La(2), and one C(30) atom. In the eleventh O site, O(8) is bonded in a distorted single-bond geometry to one La(1) and one C(28) atom. In the twelfth O site, O(9) is bonded in a trigonal non-coplanar geometry to one La(1) and two equivalent La(2) atoms. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one La(1), one La(2), and one C(31) atom. Linkers: 2 C[C]1C(C([O])=O)=CC=C2[C]3C=CC(C([O])=O)=C(C)N3[Cu]3(N12)N1[C](C)C(C([O])=O)=CC=C1[C]1C=CC(C([O])=O)=C(C)N13. Metal clusters: 1 C[C]1O[La]2345(O[C]O2)O[C]O[La]26(O[C]O2)(O[C]O[La]278(O[C]O2)(O[C]O[La]2(O[C]O2)(O[C]O3)(O[C](C)O7)(O[C](C)O4)O8)O[C](C)O6)(O1)O5. RCSR code: flu. The MOF has largest included sphere 4.86 A, density 1.45 g/cm3, surface area 3507.97 m2/g, accessible volume 0.33 cm3/g