CuH24(C8N)4CuH8(C2N)4 is alpha Po structured and crystallizes in the tetragonal P4/ncc space group. The structure is zero-dimensional and consists of four CuH24(C8N)4 clusters and four CuH8(C2N)4 clusters. In each CuH24(C8N)4 cluster, Cu(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. All Cu(1)-N(1) bond lengths are 2.04 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(10) and one H(1) atom. The C(1)-C(10) bond length is 1.39 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3), one C(8), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(8) bond length is 1.41 Å. The C(2)-H(2) bond length is 0.95 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(3) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-H(3) bond length is 0.95 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(5)-C(10) bond length is 1.39 Å. The C(5)-H(5) bond length is 0.95 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(6)-N(1) bond length is 1.33 Å. The C(6)-H(6) bond length is 0.95 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(7) atom. The C(8)-C(10) bond length is 1.47 Å. The C(8)-C(7) bond length is 1.37 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(7)-H(7) bond length is 0.95 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(8) atom. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(6) atom. There are six inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In each CuH8(C2N)4 cluster, Cu(2) is bonded in a rectangular see-saw-like geometry to four equivalent N(2) atoms. All Cu(2)-N(2) bond lengths are 2.03 Å. There are two inequivalent C sites. In the first C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(4) atom. The C(4)-N(2) bond length is 1.34 Å. The C(4)-H(4) bond length is 0.95 Å. In the second C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(9)-N(2) bond length is 1.33 Å. The C(9)-H(8) bond length is 0.95 Å. N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(4), and one C(9) atom. There are two inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(9) atom. Linkers: 16 c1cc(-c2ccncc2)ccn1. Metal clusters: 8 [Cu]. The MOF has largest included sphere 4.95 A, density 1.24 g/cm3, surface area 4942.06 m2/g, accessible volume 0.33 cm3/g