CuH24(C10N)4 is Indium-like structured and crystallizes in the orthorhombic Cmcm space group. The structure is zero-dimensional and consists of four CuH24(C10N)4 clusters. Cu(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Cu(1)-N(1) bond lengths are 2.02 Å. Both Cu(1)-N(2) bond lengths are 2.04 Å. There are fourteen inequivalent C sites. In the first C site, C(11) is bonded in a trigonal planar geometry to one C(12) and two equivalent C(4) atoms. The C(11)-C(12) bond length is 1.40 Å. Both C(11)-C(4) bond lengths are 1.38 Å. In the second C site, C(12) is bonded in a linear geometry to one C(11) and one C(13) atom. The C(12)-C(13) bond length is 1.22 Å. In the third C site, C(13) is bonded in a linear geometry to one C(12) and one C(14) atom. The C(13)-C(14) bond length is 1.41 Å. In the fourth C site, C(14) is bonded in a trigonal planar geometry to one C(13) and two equivalent C(5) atoms. Both C(14)-C(5) bond lengths are 1.36 Å. In the fifth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-N(1) bond length is 1.28 Å. The C(1)-H(1) bond length is 0.95 Å. In the sixth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(7), and one H(2) atom. The C(2)-C(7) bond length is 1.31 Å. The C(2)-H(2) bond length is 0.95 Å. In the seventh C site, C(3) is bonded in a distorted trigonal planar geometry to one C(10), one C(4), and one H(3) atom. The C(3)-C(10) bond length is 1.37 Å. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(3) bond length is 0.95 Å. In the eighth C site, C(4) is bonded in a single-bond geometry to one C(11), one C(3), and one H(4) atom. The C(4)-H(4) bond length is 0.95 Å. In the ninth C site, C(5) is bonded in a distorted single-bond geometry to one C(14) and one H(5) atom. The C(5)-H(5) bond length is 0.95 Å. In the tenth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(6)-N(2) bond length is 1.32 Å. The C(6)-H(6) bond length is 0.95 Å. In the eleventh C site, C(7) is bonded in a trigonal planar geometry to one C(8) and two equivalent C(2) atoms. The C(7)-C(8) bond length is 1.42 Å. In the twelfth C site, C(8) is bonded in a linear geometry to one C(7) and one C(9) atom. The C(8)-C(9) bond length is 1.23 Å. In the thirteenth C site, C(9) is bonded in a linear geometry to one C(10) and one C(8) atom. The C(9)-C(10) bond length is 1.42 Å. In the fourteenth C site, C(10) is bonded in a trigonal planar geometry to one C(9) and two equivalent C(3) atoms. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1) and two equivalent C(1) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1) and two equivalent C(6) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. Linkers: 8 C(#Cc1ccc(C#Cc2ccncc2)cc1)c1ccncc1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 10.68 A, density 0.62 g/cm3, surface area 5688.04 m2/g, accessible volume 1.01 cm3/g