PdC6H4(N2O)2(CH)2 crystallizes in the cubic Pn-3m space group. The structure consists of twenty-four 02329_fluka molecules inside a PdC6H4(N2O)2 framework. In the PdC6H4(N2O)2 framework, Pd(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. All Pd(1)-N(1) bond lengths are 2.00 Å. There are two inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to two equivalent N(1) and one O(1) atom. Both C(2)-N(1) bond lengths are 1.36 Å. The C(2)-O(1) bond length is 1.25 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-H(1) bond length is 0.95 Å. N(1) is bonded in a trigonal planar geometry to one Pd(1), one C(1), and one C(2) atom. H(1) is bonded in a single-bond geometry to one C(1) atom. O(1) is bonded in a single-bond geometry to one C(2) atom. Linkers: 24 O=C1N=C[CH]C=N1. Metal clusters: 12 [Pd]. The MOF has largest included sphere 7.13 A, density 1.35 g/cm3, surface area 3763.36 m2/g, accessible volume 0.43 cm3/g