CuH4(C2N)2(Cu2C19H16(N2O)3)2CuC18H16(NO2)2(C3H2)12(CH2CO)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twelve 2,3-dimethyl-1,3-butadiene molecules; four dimethyl ether molecules; four Cu2C19H16(N2O)3 clusters; two CuC18H16(NO2)2 clusters; and two CuH4(C2N)2 clusters. In each Cu2C19H16(N2O)3 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one N(3), one N(5), one N(6), one O(4), and one O(6) atom to form corner-sharing CuN3O2 square pyramids. The Cu(1)-N(3) bond length is 2.04 Å. The Cu(1)-N(5) bond length is 2.05 Å. The Cu(1)-N(6) bond length is 2.04 Å. The Cu(1)-O(4) bond length is 2.21 Å. The Cu(1)-O(6) bond length is 1.93 Å. In the second Cu site, Cu(2) is bonded to one N(4), one N(7), one N(8), one O(5), and one O(6) atom to form corner-sharing CuN3O2 trigonal bipyramids. The Cu(2)-N(4) bond length is 2.04 Å. The Cu(2)-N(7) bond length is 2.05 Å. The Cu(2)-N(8) bond length is 2.06 Å. The Cu(2)-O(5) bond length is 2.16 Å. The Cu(2)-O(6) bond length is 1.94 Å. There are nineteen inequivalent C sites. In the first C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(10)-O(4) bond length is 1.24 Å. The C(10)-O(5) bond length is 1.27 Å. In the second C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(21)-N(3) bond length is 1.33 Å. The C(21)-H(17) bond length is 0.93 Å. In the third C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(18) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(18) bond length is 0.93 Å. In the fourth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.37 Å. The C(23)-C(28) bond length is 1.49 Å. In the fifth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(19) atom. The C(24)-H(19) bond length is 0.93 Å. In the sixth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(20) atom. The C(25)-N(3) bond length is 1.33 Å. The C(25)-H(20) bond length is 0.93 Å. In the seventh C site, C(26) is bonded in a distorted trigonal planar geometry to one C(27), one N(4), and one H(21) atom. The C(26)-C(27) bond length is 1.38 Å. The C(26)-N(4) bond length is 1.32 Å. The C(26)-H(21) bond length is 0.93 Å. In the eighth C site, C(27) is bonded in a distorted single-bond geometry to one C(26), one C(28), and one H(22) atom. The C(27)-C(28) bond length is 1.38 Å. The C(27)-H(22) bond length is 0.93 Å. In the ninth C site, C(28) is bonded in a trigonal planar geometry to one C(23), one C(27), and one C(29) atom. The C(28)-C(29) bond length is 1.38 Å. In the tenth C site, C(29) is bonded in a distorted single-bond geometry to one C(28), one C(30), and one H(23) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-H(23) bond length is 0.93 Å. In the eleventh C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one N(4), and one H(24) atom. The C(30)-N(4) bond length is 1.35 Å. The C(30)-H(24) bond length is 0.93 Å. In the twelfth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(25) atom. The C(31)-N(5) bond length is 1.35 Å. The C(31)-H(25) bond length is 0.93 Å. In the thirteenth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(28) atom. The C(35)-N(5) bond length is 1.32 Å. The C(35)-H(28) bond length is 0.93 Å. In the fourteenth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(29) atom. The C(36)-N(6) bond length is 1.38 Å. The C(36)-H(29) bond length is 0.93 Å. In the fifteenth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(32) atom. The C(40)-N(6) bond length is 1.36 Å. The C(40)-H(32) bond length is 0.93 Å. In the sixteenth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(33) atom. The C(41)-N(7) bond length is 1.33 Å. The C(41)-H(33) bond length is 0.93 Å. In the seventeenth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(36) atom. The C(45)-N(7) bond length is 1.34 Å. The C(45)-H(36) bond length is 0.93 Å. In the eighteenth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(37) atom. The C(46)-N(8) bond length is 1.35 Å. The C(46)-H(37) bond length is 0.93 Å. In the nineteenth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(40) atom. The C(50)-N(8) bond length is 1.31 Å. The C(50)-H(40) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(21), and one C(25) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(26), and one C(30) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Cu(1), one C(31), and one C(35) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(36), and one C(40) atom. In the fifth N site, N(7) is bonded in a trigonal planar geometry to one Cu(2), one C(41), and one C(45) atom. In the sixth N site, N(8) is bonded in a trigonal planar geometry to one Cu(2), one C(46), and one C(50) atom. There are sixteen inequivalent H sites. In the first H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the second H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(24) atom. In the fourth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the sixth H site, H(22) is bonded in a single-bond geometry to one C(27) atom. In the seventh H site, H(23) is bonded in a single-bond geometry to one C(29) atom. In the eighth H site, H(24) is bonded in a single-bond geometry to one C(30) atom. In the ninth H site, H(25) is bonded in a single-bond geometry to one C(31) atom. In the tenth H site, H(28) is bonded in a single-bond geometry to one C(35) atom. In the eleventh H site, H(29) is bonded in a single-bond geometry to one C(36) atom. In the twelfth H site, H(32) is bonded in a single-bond geometry to one C(40) atom. In the thirteenth H site, H(33) is bonded in a single-bond geometry to one C(41) atom. In the fourteenth H site, H(36) is bonded in a single-bond geometry to one C(45) atom. In the fifteenth H site, H(37) is bonded in a single-bond geometry to one C(46) atom. In the sixteenth H site, H(40) is bonded in a single-bond geometry to one C(50) atom. There are three inequivalent O sites. In the first O site, O(4) is bonded in a 2-coordinate geometry to one Cu(1) and one C(10) atom. In the second O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(10) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one Cu(2) atom. In each CuC18H16(NO2)2 cluster, Cu(3) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Cu(3)-N(1) bond lengths are 1.98 Å. Both Cu(3)-O(1) bond lengths are 1.99 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.53 Å. The C(1)-O(1) bond length is 1.24 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.43 Å. The C(2)-C(7) bond length is 1.37 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(8) bond length is 1.51 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(5)-H(2) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(7)-H(3) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(4); one H(4); and two equivalent H(5,6) atoms. The C(8)-H(4) bond length is 0.96 Å. Both C(8)-H(5,6) bond lengths are 0.96 Å. In the eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(11)-N(1) bond length is 1.35 Å. The C(11)-H(9) bond length is 0.93 Å. In the ninth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(12) atom. The C(15)-N(1) bond length is 1.35 Å. The C(15)-H(12) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Cu(3), one C(11), and one C(15) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(15) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In each CuH4(C2N)2 cluster, Cu(4) is bonded in a linear geometry to two equivalent N(2) atoms. Both Cu(4)-N(2) bond lengths are 1.98 Å. There are two inequivalent C sites. In the first C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(13) atom. The C(16)-N(2) bond length is 1.34 Å. The C(16)-H(13) bond length is 0.93 Å. In the second C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(16) atom. The C(20)-N(2) bond length is 1.33 Å. The C(20)-H(16) bond length is 0.93 Å. N(2) is bonded in a trigonal planar geometry to one Cu(4), one C(16), and one C(20) atom. There are two inequivalent H sites. In the first H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the second H site, H(16) is bonded in a single-bond geometry to one C(20) atom. Linkers: 4 Cc1cc(OCC([O])=O)cc(C([O])=O)c1 ,5 c1cc(-c2ccncc2)ccn1. Metal clusters: 4 [C]1O[Cu]O[Cu]O1 ,4 [Cu]. The MOF has largest included sphere 5.36 A, density 1.10 g/cm3, surface area 4775.31 m2/g, accessible volume 0.42 cm3/g