Cr3Cd2C32N6H20O13Cl8(CH)4 crystallizes in the orthorhombic Ccce space group. The structure consists of thirty-two 02329_fluka molecules inside a Cr3Cd2C32N6H20O13Cl8 framework. In the Cr3Cd2C32N6H20O13Cl8 framework, there are two inequivalent Cr sites. In the first Cr site, Cr(1) is bonded to one O(2), one O(4), one O(5), one O(6), and one O(7) atom to form corner-sharing CrO5 square pyramids. The Cr(1)-O(2) bond length is 1.99 Å. The Cr(1)-O(4) bond length is 1.98 Å. The Cr(1)-O(5) bond length is 1.98 Å. The Cr(1)-O(6) bond length is 1.97 Å. The Cr(1)-O(7) bond length is 1.88 Å. In the second Cr site, Cr(2) is bonded to one O(7), two equivalent O(1), and two equivalent O(3) atoms to form corner-sharing CrO5 square pyramids. The Cr(2)-O(7) bond length is 1.94 Å. Both Cr(2)-O(1) bond lengths are 1.90 Å. Both Cr(2)-O(3) bond lengths are 1.93 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted hexagonal bipyramidal geometry to two equivalent N(1), two equivalent Cl(1), two equivalent Cl(2), and two equivalent Cl(3) atoms. Both Cd(1)-N(1) bond lengths are 2.26 Å. Both Cd(1)-Cl(1) bond lengths are 2.59 Å. Both Cd(1)-Cl(2) bond lengths are 2.39 Å. Both Cd(1)-Cl(3) bond lengths are 2.38 Å. In the second Cd site, Cd(2) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(3), and two equivalent Cl(4) atoms. Both Cd(2)-N(2) bond lengths are 2.42 Å. Both Cd(2)-N(3) bond lengths are 2.32 Å. Both Cd(2)-Cl(4) bond lengths are 2.55 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.39 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(2) atom. The C(2)-C(4) bond length is 1.39 Å. The C(2)-N(1) bond length is 1.39 Å. The C(2)-H(2) bond length is 0.95 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(3)-C(5) bond length is 1.39 Å. The C(3)-H(3) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-C(6) bond length is 1.44 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(3), one C(4), and one H(4) atom. The C(5)-H(4) bond length is 0.95 Å. In the sixth C site, C(6) is bonded in a bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.27 Å. The C(6)-O(2) bond length is 1.28 Å. In the seventh C site, C(7) is bonded in a bent 120 degrees geometry to one C(9), one O(3), and one O(6) atom. The C(7)-C(9) bond length is 1.46 Å. The C(7)-O(3) bond length is 1.26 Å. The C(7)-O(6) bond length is 1.25 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(4), and one O(5) atom. The C(8)-C(10) bond length is 1.53 Å. The C(8)-O(4) bond length is 1.26 Å. The C(8)-O(5) bond length is 1.21 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(7) atom. The C(9)-C(11) bond length is 1.37 Å. The C(9)-C(12) bond length is 1.38 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(8) atom. The C(10)-C(13) bond length is 1.48 Å. The C(10)-C(14) bond length is 1.41 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(11)-H(5) bond length is 0.95 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(2), and one H(6) atom. The C(12)-N(2) bond length is 1.32 Å. The C(12)-H(6) bond length is 0.95 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(13)-H(7) bond length is 0.95 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(3), and one H(8) atom. The C(14)-N(3) bond length is 1.38 Å. The C(14)-H(8) bond length is 0.95 Å. In the fifteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(11) atom. The C(17)-N(2) bond length is 1.37 Å. The C(17)-H(11) bond length is 0.95 Å. In the sixteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(12) atom. The C(18)-N(3) bond length is 1.36 Å. The C(18)-H(12) bond length is 0.95 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(2), one C(12), and one C(17) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(2), one C(14), and one C(18) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cr(2) and one C(6) atom. In the second O site, O(7) is bonded in a trigonal planar geometry to one Cr(2) and two equivalent Cr(1) atoms. In the third O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cr(1) and one C(6) atom. In the fourth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cr(2) and one C(7) atom. In the fifth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cr(1) and one C(8) atom. In the sixth O site, O(5) is bonded in a bent 120 degrees geometry to one Cr(1) and one C(8) atom. In the seventh O site, O(6) is bonded in a bent 120 degrees geometry to one Cr(1) and one C(7) atom. There are four inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted single-bond geometry to one Cd(1) atom. In the second Cl site, Cl(2) is bonded in a 2-coordinate geometry to one Cd(1) and one Cl(3) atom. The Cl(2)-Cl(3) bond length is 1.86 Å. In the third Cl site, Cl(3) is bonded in a 2-coordinate geometry to one Cd(1) and one Cl(2) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one Cd(2) atom. Linkers: 1 [O]C(=O)C1=CC=CN([Cd](Cl)(Cl)(N2[CH]C=CC(C([O])=O)=C2)(N2[CH]C=CC(C([O])=O)=C2)N2[CH]C=CC(C([O])=O)=C2)[CH]1 ,1 [O]C(=O)C1=CC=CN([Cd](Cl)(Cl)(N2[CH]C(C([O])=O)=CC=C2)(N2[CH]C(C([O])=O)=CC=C2)N2[CH]C=CC(C([O])=O)=C2)[CH]1 ,6 [O]C(=O)C1=CC=CN([Cd](Cl)(Cl)(N2[CH]C(C([O])=O)=CC=C2)(N2[CH]C(C([O])=O)=CC=C2)N2[CH]C(C([O])=O)=CC=C2)[CH]1 ,3 [O]C(=O)C1=CC=CN([Cd](Cl)(Cl)(N2[CH]C(C([O])=O)=CC=C2)(N2[CH]C=CC(C([O])=O)=C2)N2[CH]C=CC(C([O])=O)=C2)[CH]1 ,7 ClCl.ClCl.ClCl.[O]C(=O)C1=CN([Cd]N2[CH]C=CC(C([O])=O)=C2)[CH]C=C1 ,1 ClCl.ClCl.ClCl.[O]C(=O)C1=CC=CN([Cd]N2[CH]C=CC(C([O])=O)=C2)[CH]1. Metal clusters: 8 [C]1O[Cr]23O[C]O[Cr]45(O1)O[C]O[Cr](O[C]O2)(O[C]O3)(O[C]O4)O5. RCSR code: fsc. The MOF has largest included sphere 7.57 A, density 1.09 g/cm3, surface area 3554.27 m2/g, accessible volume 0.57 cm3/g