ZnC12H10(N2O)2(CH)2(CH2)4 is Indium-derived structured and crystallizes in the orthorhombic Pmn2_1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, sixteen 02329_fluka molecules, and four ZnC12H10(N2O)2 clusters. In each ZnC12H10(N2O)2 cluster, Zn(1) is bonded in a water-like geometry to two equivalent N(3) atoms. Both Zn(1)-N(3) bond lengths are 2.11 Å. There are six inequivalent C sites. In the first C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(13)-N(3) bond length is 1.33 Å. The C(13)-H(17) bond length is 0.93 Å. In the second C site, C(15) is bonded in a single-bond geometry to one C(16) and one H(4,19) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-H(4,19) bond length is 0.93 Å. In the third C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one N(4) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-N(4) bond length is 1.41 Å. In the fourth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(3), and one H(20) atom. The C(17)-N(3) bond length is 1.35 Å. The C(17)-H(20) bond length is 0.93 Å. In the fifth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(10), one N(4), and one O(2) atom. The C(18)-C(10) bond length is 1.52 Å. The C(18)-N(4) bond length is 1.37 Å. The C(18)-O(2) bond length is 1.22 Å. In the sixth C site, C(10) is bonded in a single-bond geometry to one C(18) and one H(12) atom. The C(10)-H(12) bond length is 0.98 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(17) atom. In the second N site, N(4) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(2) atom. The N(4)-H(2) bond length is 0.86 Å. There are five inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one N(4) atom. In the second H site, H(4,19) is bonded in a single-bond geometry to one C(3) atom. The H(4,19)-C(3) bond length is 0.93 Å. In the third H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one C(17) atom. O(2) is bonded in a single-bond geometry to one C(18) atom. Linkers: 2 [C][CH]/C(=[NH]\C(=O)[C@@H]1CC[C@H](CC1)C(=O)Nc1cccnc1)/[CH][N] ,4 O=C(Nc1cccnc1)[C@H]1CC[C@H](C(=O)Nc2cccnc2)CC1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 5.03 A, density 1.12 g/cm3, surface area 5108.37 m2/g, accessible volume 0.38 cm3/g