(CoH7(C2O)6)2(H4(C3F2)3)3 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two CoH7(C2O)6 clusters and six H4(C3F2)3 clusters. In each CoH7(C2O)6 cluster, Co(1) is bonded in a distorted square pyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(6) atom. The Co(1)-O(1) bond length is 1.96 Å. The Co(1)-O(2) bond length is 1.98 Å. The Co(1)-O(3) bond length is 2.17 Å. The Co(1)-O(4) bond length is 2.00 Å. The Co(1)-O(6) bond length is 2.04 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(10), one O(1), and one O(2) atom. The C(1)-C(10) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(2)-C(4) bond length is 1.48 Å. The C(2)-O(3) bond length is 1.27 Å. The C(2)-O(4) bond length is 1.23 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(1) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(5) atom. The C(4)-C(5) bond length is 1.36 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(5)-H(2) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(5), and one O(6) atom. The C(6)-C(20) bond length is 1.46 Å. The C(6)-O(5) bond length is 1.30 Å. The C(6)-O(6) bond length is 1.21 Å. In the seventh C site, C(10) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(17) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(17) bond length is 1.38 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(3) atom. The C(11)-H(3) bond length is 0.93 Å. In the ninth C site, C(17) is bonded in a distorted single-bond geometry to one C(10) and one H(6) atom. The C(17)-H(6) bond length is 0.93 Å. In the tenth C site, C(19) is bonded in a distorted single-bond geometry to one C(20) and one H(8) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-H(8) bond length is 0.93 Å. In the eleventh C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(6) atom. The C(20)-C(21) bond length is 1.38 Å. In the twelfth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(9) atom. The C(21)-H(9) bond length is 0.93 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one O(3) and one O(5) atom. The H(13)-O(3) bond length is 1.74 Å. The H(13)-O(5) bond length is 0.82 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Co(1), one C(2), and one H(13) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one C(6) and one H(13) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(6) atom. In two of the H4(C3F2)3 clusters, there are five inequivalent C sites. In the first C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(26), one F(7), one F(8), and one F(9) atom. The C(9)-C(26) bond length is 1.54 Å. The C(9)-F(7) bond length is 1.32 Å. The C(9)-F(8) bond length is 1.36 Å. The C(9)-F(9) bond length is 1.35 Å. In the second C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(10) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-H(10) bond length is 0.93 Å. In the third C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(26) atom. The C(23)-C(24) bond length is 1.36 Å. The C(23)-C(26) bond length is 1.55 Å. In the fourth C site, C(26) is bonded in a tetrahedral geometry to two equivalent C(23) and two equivalent C(9) atoms. In the fifth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(11) atom. The C(24)-H(11) bond length is 0.93 Å. There are two inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one C(22) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(24) atom. There are three inequivalent F sites. In the first F site, F(7) is bonded in a single-bond geometry to one C(9) atom. In the second F site, F(8) is bonded in a single-bond geometry to one C(9) atom. In the third F site, F(9) is bonded in a single-bond geometry to one C(9) atom. In four of the H4(C3F2)3 clusters, there are nine inequivalent C sites. In the first C site, C(7) is bonded in a trigonal non-coplanar geometry to one C(12), one F(1), one F(2), and one F(3) atom. The C(7)-C(12) bond length is 1.55 Å. The C(7)-F(1) bond length is 1.32 Å. The C(7)-F(2) bond length is 1.32 Å. The C(7)-F(3) bond length is 1.33 Å. In the second C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(12), one F(4), one F(5), and one F(6) atom. The C(8)-C(12) bond length is 1.54 Å. The C(8)-F(4) bond length is 1.32 Å. The C(8)-F(5) bond length is 1.31 Å. The C(8)-F(6) bond length is 1.33 Å. In the third C site, C(12) is bonded in a tetrahedral geometry to one C(13), one C(14), one C(7), and one C(8) atom. The C(12)-C(13) bond length is 1.52 Å. The C(12)-C(14) bond length is 1.54 Å. In the fourth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(15), and one C(16) atom. The C(13)-C(15) bond length is 1.38 Å. The C(13)-C(16) bond length is 1.38 Å. In the fifth C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(18), and one C(25) atom. The C(14)-C(18) bond length is 1.40 Å. The C(14)-C(25) bond length is 1.37 Å. In the sixth C site, C(15) is bonded in a distorted single-bond geometry to one C(13) and one H(4) atom. The C(15)-H(4) bond length is 0.93 Å. In the seventh C site, C(16) is bonded in a distorted single-bond geometry to one C(13) and one H(5) atom. The C(16)-H(5) bond length is 0.93 Å. In the eighth C site, C(18) is bonded in a distorted single-bond geometry to one C(14) and one H(7) atom. The C(18)-H(7) bond length is 0.93 Å. In the ninth C site, C(25) is bonded in a distorted single-bond geometry to one C(14) and one H(12) atom. The C(25)-H(12) bond length is 0.93 Å. There are four inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(15) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(16) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(18) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(25) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(7) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(7) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one C(8) atom. Linkers: 4 [O]C(=O)c1ccc(C(c2ccc(C([O])=O)cc2)(C(F)(F)F)C(F)(F)F)cc1 ,1 O=[C]c1ccc(C(c2ccc(C(=O)O)cc2)(C(F)(F)F)C(F)(F)F)cc1 ,1 O=C(O)c1ccc(C(c2ccc(C(=O)O)cc2)(C(F)(F)F)C(F)(F)F)cc1. Metal clusters: 2 O[C]O[Co]1234O[C]O[Co]1(O[C]O)(O[C]O2)(O[C]O3)O[C]O4. RCSR code: pcu. The MOF has largest included sphere 4.97 A, density 1.61 g/cm3, surface area 3874.17 m2/g, accessible volume 0.19 cm3/g