Zn2C24H15(NO4)2(CH2)14(CH3)2C4H3(C15H10O2)2 crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of fifty-six 02329_fluka molecules, eight 02329_fluka molecules, four isobutylene molecules, four C15H10O2 clusters, and four Zn2C24H15(NO4)2 clusters. In each C15H10O2 cluster, there are fifteen inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.44 Å. The C(4)-H(2) bond length is 0.93 Å. In the second C site, C(5) is bonded in a trigonal planar geometry to one C(15), one C(4), and one C(6) atom. The C(5)-C(15) bond length is 1.48 Å. The C(5)-C(6) bond length is 1.47 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the fourth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(6) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(6) bond length is 0.93 Å. In the fifth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(18), and one C(9) atom. The C(10)-C(11) bond length is 1.35 Å. The C(10)-C(18) bond length is 1.48 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(11)-H(7) bond length is 0.93 Å. In the seventh C site, C(15) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(5) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-C(20) bond length is 1.56 Å. In the eighth C site, C(16) is bonded in a bent 120 degrees geometry to one C(15) and one C(17) atom. The C(16)-C(17) bond length is 1.49 Å. In the ninth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one O(5) atom. The C(17)-C(18) bond length is 1.34 Å. The C(17)-O(5) bond length is 1.42 Å. In the tenth C site, C(18) is bonded in a trigonal planar geometry to one C(10), one C(17), and one C(19) atom. The C(18)-C(19) bond length is 1.49 Å. In the eleventh C site, C(19) is bonded in a bent 120 degrees geometry to one C(18) and one C(20) atom. The C(19)-C(20) bond length is 1.59 Å. In the twelfth C site, C(20) is bonded in a single-bond geometry to one C(15), one C(19), and one O(6) atom. The C(20)-O(6) bond length is 1.20 Å. In the thirteenth C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(9,10) and one O(6) atom. Both C(21)-H(9,10) bond lengths are 0.97 Å. The C(21)-O(6) bond length is 1.39 Å. In the fourteenth C site, C(27) is bonded in a 5-coordinate geometry to one C(28), one H(22), one H(23), one H(31), and one O(5) atom. The C(27)-C(28) bond length is 1.13 Å. The C(27)-H(22) bond length is 0.97 Å. The C(27)-H(23) bond length is 0.97 Å. The C(27)-H(31) bond length is 1.42 Å. The C(27)-O(5) bond length is 1.44 Å. In the fifteenth C site, C(28) is bonded in a distorted water-like geometry to one C(27), one H(24), and one H(31) atom. The C(28)-H(24) bond length is 0.97 Å. The C(28)-H(31) bond length is 0.97 Å. There are nine inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(22) is bonded in a single-bond geometry to one C(27) atom. In the seventh H site, H(23) is bonded in a single-bond geometry to one C(27) atom. In the eighth H site, H(24) is bonded in a single-bond geometry to one C(28) atom. In the ninth H site, H(31) is bonded in a 1-coordinate geometry to one C(27) and one C(28) atom. There are two inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one C(17) and one C(27) atom. In the second O site, O(6) is bonded in a bent 120 degrees geometry to one C(20) and one C(21) atom. In each Zn2C24H15(NO4)2 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), two equivalent O(1), and two equivalent O(3) atoms. The Zn(1)-N(1) bond length is 2.01 Å. Both Zn(1)-O(1) bond lengths are 2.03 Å. Both Zn(1)-O(3) bond lengths are 2.05 Å. In the second Zn site, Zn(2) is bonded in a square pyramidal geometry to one N(2), two equivalent O(2), and two equivalent O(4) atoms. The Zn(2)-N(2) bond length is 2.00 Å. Both Zn(2)-O(2) bond lengths are 2.03 Å. Both Zn(2)-O(4) bond lengths are 2.03 Å. There are sixteen inequivalent C sites. In the first C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(32) atom. The C(32)-N(2) bond length is 1.31 Å. The C(32)-H(32) bond length is 0.93 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.46 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.25 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the fourth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fifth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(38), one N(1), and one H(36) atom. The C(37)-C(38) bond length is 1.30 Å. The C(37)-N(1) bond length is 1.48 Å. The C(37)-H(36) bond length is 0.93 Å. In the sixth C site, C(38) is bonded in a distorted single-bond geometry to one C(37), one C(39), and one H(37) atom. The C(38)-C(39) bond length is 1.55 Å. The C(38)-H(37) bond length is 0.93 Å. In the seventh C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(39) atom. The C(41)-N(1) bond length is 1.20 Å. The C(41)-H(39) bond length is 0.93 Å. In the eighth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the ninth C site, C(8) is bonded in a distorted single-bond geometry to one C(13) and one H(5) atom. The C(8)-C(13) bond length is 1.36 Å. The C(8)-H(5) bond length is 0.93 Å. In the tenth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(43) atom. The C(39)-C(40) bond length is 1.17 Å. The C(39)-C(43) bond length is 1.47 Å. In the eleventh C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one H(38) atom. The C(40)-H(38) bond length is 0.93 Å. In the twelfth C site, C(43) is bonded in a 1-coordinate geometry to one C(39) and one H(41) atom. The C(43)-H(41) bond length is 0.93 Å. In the thirteenth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(8) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(8) bond length is 0.93 Å. In the fourteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(8) atom. The C(13)-C(14) bond length is 1.48 Å. In the fifteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.25 Å. The C(14)-O(4) bond length is 1.25 Å. In the sixteenth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(35) atom. The C(36)-N(2) bond length is 1.35 Å. The C(36)-H(35) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(37), and one C(41) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(32), and one C(36) atom. There are eleven inequivalent H sites. In the first H site, H(32) is bonded in a single-bond geometry to one C(32) atom. In the second H site, H(35) is bonded in a distorted single-bond geometry to one C(36) atom. In the third H site, H(36) is bonded in a single-bond geometry to one C(37) atom. In the fourth H site, H(37) is bonded in a single-bond geometry to one C(38) atom. In the fifth H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(39) is bonded in a single-bond geometry to one C(41) atom. In the seventh H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(41) is bonded in a single-bond geometry to one C(43) atom. In the ninth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(38) is bonded in a single-bond geometry to one C(40) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(14) atom. Linkers: 8 [CH2]CCCCOc1[c]c(-c2ccc(C([O])=O)cc2)c(OCCCCCC)[c]c1-c1ccc(C([O])=O)cc1 ,4 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 4 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: sql. The MOF has largest included sphere 12.07 A, density 0.71 g/cm3, surface area 5203.21 m2/g, accessible volume 0.87 cm3/g