LaC28H24(NO)8(C3H2)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 2,3-dimethyl-1,3-butadiene molecules and four LaC28H24(NO)8 clusters. In each LaC28H24(NO)8 cluster, La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. The La(1)-O(1) bond length is 2.53 Å. The La(1)-O(2) bond length is 2.48 Å. The La(1)-O(3) bond length is 2.50 Å. The La(1)-O(4) bond length is 2.51 Å. The La(1)-O(5) bond length is 2.50 Å. The La(1)-O(6) bond length is 2.44 Å. The La(1)-O(7) bond length is 2.47 Å. The La(1)-O(8) bond length is 2.50 Å. There are twenty-eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(13), one C(2), and one C(4) atom. The C(3)-C(13) bond length is 1.49 Å. The C(3)-C(2) bond length is 1.38 Å. The C(3)-C(4) bond length is 1.39 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(3) bond length is 0.95 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 0.95 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-H(5) bond length is 0.95 Å. In the sixth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(8) bond length is 0.95 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(10) bond length is 0.95 Å. In the eighth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(3) atom. The C(13)-C(14) bond length is 1.40 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(14)-H(11) bond length is 0.95 Å. In the tenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(13) atom. The C(16)-N(4) bond length is 1.34 Å. The C(16)-H(13) bond length is 0.95 Å. In the eleventh C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(16) atom. The C(20)-N(4) bond length is 1.33 Å. The C(20)-H(16) bond length is 0.95 Å. In the twelfth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one N(5), and one H(17) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-N(5) bond length is 1.34 Å. The C(21)-H(17) bond length is 0.95 Å. In the thirteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(18) atom. The C(22)-C(23) bond length is 1.38 Å. The C(22)-H(18) bond length is 0.95 Å. In the fourteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one N(5), and one H(20) atom. The C(25)-C(24) bond length is 1.38 Å. The C(25)-N(5) bond length is 1.33 Å. The C(25)-H(20) bond length is 0.95 Å. In the fifteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(21) atom. The C(26)-N(6) bond length is 1.34 Å. The C(26)-H(21) bond length is 0.95 Å. In the sixteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(19) atom. The C(24)-C(23) bond length is 1.38 Å. The C(24)-H(19) bond length is 0.95 Å. In the seventeenth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(24) atom. The C(30)-N(6) bond length is 1.35 Å. The C(30)-H(24) bond length is 0.95 Å. In the eighteenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(25) atom. The C(31)-N(7) bond length is 1.36 Å. The C(31)-H(25) bond length is 0.95 Å. In the nineteenth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(28) atom. The C(35)-N(7) bond length is 1.33 Å. The C(35)-H(28) bond length is 0.95 Å. In the twentieth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(29) atom. The C(36)-N(8) bond length is 1.34 Å. The C(36)-H(29) bond length is 0.95 Å. In the twenty-first C site, C(40) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(32) atom. The C(40)-N(8) bond length is 1.34 Å. The C(40)-H(32) bond length is 0.95 Å. In the twenty-second C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(33) atom. The C(23)-C(33) bond length is 1.49 Å. In the twenty-third C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(26) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-H(26) bond length is 0.95 Å. In the twenty-fourth C site, C(33) is bonded in a trigonal planar geometry to one C(23), one C(32), and one C(34) atom. The C(33)-C(34) bond length is 1.39 Å. In the twenty-fifth C site, C(34) is bonded in a distorted single-bond geometry to one C(33) and one H(7,27) atom. The C(34)-H(7,27) bond length is 0.95 Å. In the twenty-sixth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9,12) atom. The C(11)-N(3) bond length is 1.34 Å. The C(11)-H(9,12) bond length is 0.95 Å. In the twenty-seventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9,12) atom. The C(15)-N(3) bond length is 1.34 Å. The C(15)-H(9,12) bond length is 0.95 Å. In the twenty-eighth C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-H(2) bond length is 0.95 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(5), and one O(1) atom. The N(1)-O(1) bond length is 1.34 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(6), and one O(2) atom. The N(2)-O(2) bond length is 1.34 Å. In the third N site, N(5) is bonded in a trigonal planar geometry to one C(21), one C(25), and one O(5) atom. The N(5)-O(5) bond length is 1.33 Å. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one C(26), one C(30), and one O(6) atom. The N(6)-O(6) bond length is 1.33 Å. In the fifth N site, N(7) is bonded in a trigonal planar geometry to one C(31), one C(35), and one O(7) atom. The N(7)-O(7) bond length is 1.33 Å. In the sixth N site, N(8) is bonded in a trigonal planar geometry to one C(36), one C(40), and one O(8) atom. The N(8)-O(8) bond length is 1.34 Å. In the seventh N site, N(3) is bonded in a trigonal planar geometry to one C(11), one C(15), and one O(3) atom. The N(3)-O(3) bond length is 1.32 Å. In the eighth N site, N(4) is bonded in a trigonal planar geometry to one C(16), one C(20), and one O(4) atom. The N(4)-O(4) bond length is 1.33 Å. There are twenty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(30) atom. In the thirteenth H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourteenth H site, H(25) is bonded in a single-bond geometry to one C(31) atom. In the fifteenth H site, H(28) is bonded in a single-bond geometry to one C(35) atom. In the sixteenth H site, H(29) is bonded in a single-bond geometry to one C(36) atom. In the seventeenth H site, H(32) is bonded in a single-bond geometry to one C(40) atom. In the eighteenth H site, H(7,27) is bonded in a single-bond geometry to one C(9) atom. The H(7,27)-C(9) bond length is 0.95 Å. In the nineteenth H site, H(9,12) is bonded in a single-bond geometry to one C(11) atom. In the twentieth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the twenty-first H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the twenty-second H site, H(26) is bonded in a single-bond geometry to one C(32) atom. In the twenty-third H site, H(16) is bonded in a single-bond geometry to one C(20) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one La(1) and one N(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one La(1) and one N(2) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one La(1) and one N(3) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one La(1) and one N(5) atom. In the fifth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one La(1) and one N(6) atom. In the sixth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one La(1) and one N(7) atom. In the seventh O site, O(8) is bonded in a distorted bent 120 degrees geometry to one La(1) and one N(8) atom. In the eighth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one La(1) and one N(4) atom. Linkers: 8 [O-][n+]1ccc(-c2cc[n+]([O-])cc2)cc1. Metal clusters: 4 [O][La]([O])([O])([O])([O])([O])([O])[O]. RCSR code: hcb. The MOF has largest included sphere 6.32 A, density 0.89 g/cm3, surface area 4441.67 m2/g, accessible volume 0.70 cm3/g