CdH8(C2N)4(CH)8C9H8O4 is Indium-derived structured and crystallizes in the orthorhombic Ccce space group. The structure is zero-dimensional and consists of one hundred and twenty-eight 02329_fluka molecules; sixteen 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and sixteen CdH8(C2N)4 clusters. In each CdH8(C2N)4 cluster, Cd(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(2) and two equivalent N(3) atoms. Both Cd(1)-N(2) bond lengths are 2.33 Å. Both Cd(1)-N(3) bond lengths are 2.35 Å. There are four inequivalent C sites. In the first C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(22) atom. The C(23)-N(3) bond length is 1.31 Å. The C(23)-H(22) bond length is 0.93 Å. In the second C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(23) atom. The C(24)-N(3) bond length is 1.33 Å. The C(24)-H(23) bond length is 0.93 Å. In the third C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(10) bond length is 0.93 Å. In the fourth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(11) atom. The C(12)-N(2) bond length is 1.31 Å. The C(12)-H(11) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(12) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(23), and one C(24) atom. There are four inequivalent H sites. In the first H site, H(22) is bonded in a single-bond geometry to one C(23) atom. In the second H site, H(23) is bonded in a single-bond geometry to one C(24) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. Linkers: 4 c1cc(OCC(COc2ccncc2)(COc2ccncc2)COc2ccncc2)ccn1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 5.90 A, density 0.85 g/cm3, surface area 4682.88 m2/g, accessible volume 0.67 cm3/g