Zn5C34H36(NO9)2(CH)2 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a Zn5C34H36(NO9)2 framework. In the Zn5C34H36(NO9)2 framework, there are five inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(11), one O(14), one O(17), and one O(18) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(11) bond length is 1.93 Å. The Zn(1)-O(14) bond length is 1.93 Å. The Zn(1)-O(17) bond length is 1.94 Å. The Zn(1)-O(18) bond length is 1.95 Å. In the second Zn site, Zn(2) is bonded to one N(2), one O(4), one O(6), one O(7), and one O(8) atom to form ZnNO4 trigonal bipyramids that share  a cornercorner with one Zn(4)O5 square pyramid and  a cornercorner with one Zn(3)O4 tetrahedra. The Zn(2)-N(2) bond length is 2.15 Å. The Zn(2)-O(4) bond length is 2.01 Å. The Zn(2)-O(6) bond length is 2.07 Å. The Zn(2)-O(7) bond length is 1.99 Å. The Zn(2)-O(8) bond length is 1.96 Å. In the third Zn site, Zn(3) is bonded to one O(10), one O(15), one O(16), and one O(7) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(10) bond length is 1.94 Å. The Zn(3)-O(15) bond length is 1.99 Å. The Zn(3)-O(16) bond length is 1.94 Å. The Zn(3)-O(7) bond length is 1.90 Å. In the fourth Zn site, Zn(4) is bonded to one O(1), one O(12), one O(2), one O(3), and one O(4) atom to form corner-sharing ZnO5 square pyramids. The Zn(4)-O(1) bond length is 2.08 Å. The Zn(4)-O(12) bond length is 2.12 Å. The Zn(4)-O(2) bond length is 2.15 Å. The Zn(4)-O(3) bond length is 2.08 Å. The Zn(4)-O(4) bond length is 2.09 Å. In the fifth Zn site, Zn(5) is bonded to one N(1), one O(13), one O(14), one O(2), and one O(9) atom to form ZnNO4 trigonal bipyramids that share  a cornercorner with one Zn(4)O5 square pyramid and  a cornercorner with one Zn(1)O4 tetrahedra. The Zn(5)-N(1) bond length is 2.16 Å. The Zn(5)-O(13) bond length is 2.05 Å. The Zn(5)-O(14) bond length is 2.03 Å. The Zn(5)-O(2) bond length is 1.99 Å. The Zn(5)-O(9) bond length is 2.00 Å. There are thirty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(10), and one O(17) atom. The C(1)-C(15) bond length is 1.51 Å. The C(1)-O(10) bond length is 1.24 Å. The C(1)-O(17) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(12), and one O(8) atom. The C(2)-C(22) bond length is 1.52 Å. The C(2)-O(12) bond length is 1.22 Å. The C(2)-O(8) bond length is 1.29 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(20), one C(23), and one H(3) atom. The C(3)-C(20) bond length is 1.39 Å. The C(3)-C(23) bond length is 1.35 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(10), one C(19), and one H(4) atom. The C(4)-C(10) bond length is 1.38 Å. The C(4)-C(19) bond length is 1.40 Å. The C(4)-H(4) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(11), and one O(16) atom. The C(5)-C(23) bond length is 1.53 Å. The C(5)-O(11) bond length is 1.26 Å. The C(5)-O(16) bond length is 1.26 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(5,6) and one O(4) atom. Both C(6)-H(5,6) bond lengths are 0.97 Å. The C(6)-O(4) bond length is 1.44 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(15), one C(22), and one H(7) atom. The C(7)-C(15) bond length is 1.40 Å. The C(7)-C(22) bond length is 1.37 Å. The C(7)-H(7) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(8,9) and one O(2) atom. Both C(8)-H(8,9) bond lengths are 0.97 Å. The C(8)-O(2) bond length is 1.42 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(10) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-H(10) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(21), one C(4), and one C(9) atom. The C(10)-C(21) bond length is 1.51 Å. In the eleventh C site, C(11) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(11,12) atoms. The C(11)-N(2) bond length is 1.48 Å. Both C(11)-H(11,12) bond lengths are 0.97 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(13,14) and one O(13) atom. Both C(12)-H(13,14) bond lengths are 0.97 Å. The C(12)-O(13) bond length is 1.45 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one H(15), one H(16), and one O(7) atom. The C(13)-H(15) bond length is 0.97 Å. The C(13)-H(16) bond length is 0.97 Å. The C(13)-O(7) bond length is 1.45 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(17,18) and one O(14) atom. Both C(14)-H(17,18) bond lengths are 0.97 Å. The C(14)-O(14) bond length is 1.42 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(1), one C(27), and one C(7) atom. The C(15)-C(27) bond length is 1.38 Å. In the sixteenth C site, C(17) is bonded in a 3-coordinate geometry to one N(1); one H(20,30,31); and one H(21) atom. The C(17)-N(1) bond length is 1.51 Å. The C(17)-H(20,30,31) bond length is 0.97 Å. The C(17)-H(21) bond length is 0.97 Å. In the seventeenth C site, C(18) is bonded in a distorted single-bond geometry to one C(22) and one H(22) atom. The C(18)-C(22) bond length is 1.39 Å. The C(18)-H(22) bond length is 0.93 Å. In the eighteenth C site, C(19) is bonded in a trigonal planar geometry to one C(24), one C(33), and one C(4) atom. The C(19)-C(24) bond length is 1.38 Å. The C(19)-C(33) bond length is 1.51 Å. In the nineteenth C site, C(20) is bonded in a trigonal planar geometry to one C(25), one C(3), and one C(34) atom. The C(20)-C(25) bond length is 1.37 Å. The C(20)-C(34) bond length is 1.49 Å. In the twentieth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(1), and one O(5) atom. The C(21)-O(1) bond length is 1.27 Å. The C(21)-O(5) bond length is 1.26 Å. In the twenty-first C site, C(22) is bonded in a trigonal planar geometry to one C(18), one C(2), and one C(7) atom. In the twenty-second C site, C(23) is bonded in a trigonal planar geometry to one C(29), one C(3), and one C(5) atom. The C(23)-C(29) bond length is 1.38 Å. In the twenty-third C site, C(24) is bonded in a distorted single-bond geometry to one C(19) and one H(23) atom. The C(24)-H(23) bond length is 0.93 Å. In the twenty-fourth C site, C(25) is bonded in a distorted single-bond geometry to one C(20) and one H(24) atom. The C(25)-H(24) bond length is 0.93 Å. In the twenty-fifth C site, C(27) is bonded in a single-bond geometry to one C(15) and one H(26) atom. The C(27)-H(26) bond length is 0.93 Å. In the twenty-sixth C site, C(28) is bonded in a 3-coordinate geometry to one N(1) and two equivalent H(27,28) atoms. The C(28)-N(1) bond length is 1.45 Å. Both C(28)-H(27,28) bond lengths are 0.97 Å. In the twenty-seventh C site, C(29) is bonded in a distorted trigonal planar geometry to one C(23), one C(36), and one H(29) atom. The C(29)-C(36) bond length is 1.36 Å. The C(29)-H(29) bond length is 0.93 Å. In the twenty-eighth C site, C(30) is bonded in a 3-coordinate geometry to one N(1) and two equivalent H(20,30,31) atoms. The C(30)-N(1) bond length is 1.49 Å. Both C(30)-H(20,30,31) bond lengths are 0.97 Å. In the twenty-ninth C site, C(31) is bonded in a distorted trigonal non-coplanar geometry to one C(32); two equivalent H(32,33); and one O(6) atom. The C(31)-C(32) bond length is 1.48 Å. Both C(31)-H(32,33) bond lengths are 0.97 Å. The C(31)-O(6) bond length is 1.45 Å. In the thirtieth C site, C(32) is bonded in a 4-coordinate geometry to one C(31); one N(2); and two equivalent H(34,35) atoms. The C(32)-N(2) bond length is 1.50 Å. Both C(32)-H(34,35) bond lengths are 0.97 Å. In the thirty-first C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(15), and one O(18) atom. The C(33)-O(15) bond length is 1.25 Å. The C(33)-O(18) bond length is 1.27 Å. In the thirty-second C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(3), and one O(9) atom. The C(34)-O(3) bond length is 1.26 Å. The C(34)-O(9) bond length is 1.26 Å. In the thirty-third C site, C(35) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(36,37) atoms. The C(35)-N(2) bond length is 1.48 Å. Both C(35)-H(36,37) bond lengths are 0.97 Å. In the thirty-fourth C site, C(36) is bonded in a distorted single-bond geometry to one C(29) and one H(38) atom. The C(36)-H(38) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Zn(5), one C(17), one C(28), and one C(30) atom to form NZnC3 tetrahedra that share  a cornercorner with one O(2)Zn2HC tetrahedra. In the second N site, N(2) is bonded in a tetrahedral geometry to one Zn(2), one C(11), one C(32), and one C(35) atom. There are twenty-five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(6) atom. The H(1)-O(6) bond length is 0.85 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(13) and one O(2) atom. The H(2)-O(13) bond length is 0.86 Å. The H(2)-O(2) bond length is 1.72 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8,9) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(11,12) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(13,14) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(17,18) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(20,30,31) is bonded in a single-bond geometry to one C(17) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(17) atom. In the sixteenth H site, H(22) is bonded in a single-bond geometry to one C(18) atom. In the seventeenth H site, H(23) is bonded in a single-bond geometry to one C(24) atom. In the eighteenth H site, H(24) is bonded in a single-bond geometry to one C(25) atom. In the nineteenth H site, H(26) is bonded in a single-bond geometry to one C(27) atom. In the twentieth H site, H(27,28) is bonded in a single-bond geometry to one C(28) atom. In the twenty-first H site, H(29) is bonded in a single-bond geometry to one C(29) atom. In the twenty-second H site, H(32,33) is bonded in a single-bond geometry to one C(31) atom. In the twenty-third H site, H(34,35) is bonded in a single-bond geometry to one C(32) atom. In the twenty-fourth H site, H(36,37) is bonded in a single-bond geometry to one C(35) atom. In the twenty-fifth H site, H(38) is bonded in a single-bond geometry to one C(36) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(21) atom. In the second O site, O(2) is bonded to one Zn(4), one Zn(5), one C(8), and one H(2) atom to form distorted OZn2HC tetrahedra that share  a cornercorner with one N(1)ZnC3 tetrahedra. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(34) atom. In the fourth O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2), one Zn(4), and one C(6) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(21) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Zn(2), one C(31), and one H(1) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Zn(2), one Zn(3), and one C(13) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(34) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Zn(3) and one C(1) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(2) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Zn(5), one C(12), and one H(2) atom. In the fourteenth O site, O(14) is bonded in a trigonal planar geometry to one Zn(1), one Zn(5), and one C(14) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(33) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(5) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(33) atom. Linkers: 6 [O]C(=O)c1cccc(C([O])=O)c1. Metal clusters: 10 [Zn]. The MOF has largest included sphere 7.50 A, density 1.45 g/cm3, surface area 3804.15 m2/g, accessible volume 0.35 cm3/g