AgH2(CN2)2 crystallizes in the orthorhombic Pnma space group. Ag(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Ag(1)-N(1) bond lengths are 2.42 Å. Both Ag(1)-N(2) bond lengths are 2.49 Å. C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.94 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.32 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one N(1) atom. H(1) is bonded in a single-bond geometry to one C(1) atom. Linkers: 4 c1nncnn1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 3.87 A, density 2.11 g/cm3, surface area 2953.89 m2/g, accessible volume 0.21 cm3/g