(CH)2Sn2C11H16O5 is Indium-derived structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of thirty-six 02329_fluka molecules and nine Sn2C11H16O5 clusters. In each Sn2C11H16O5 cluster, there are two inequivalent Sn sites. In the first Sn site, Sn(1) is bonded to one C(12), one C(13), one O(4), and two equivalent O(5) atoms to form a mixture of edge and corner-sharing SnC2O3 trigonal bipyramids. The Sn(1)-C(12) bond length is 2.10 Å. The Sn(1)-C(13) bond length is 2.10 Å. The Sn(1)-O(4) bond length is 2.24 Å. There is one shorter (2.03 Å) and one longer (2.16 Å) Sn(1)-O(5) bond length. In the second Sn site, Sn(2) is bonded to one C(10), one C(11), one O(1), one O(3), and one O(5) atom to form distorted corner-sharing SnC2O3 trigonal bipyramids. The Sn(2)-C(10) bond length is 2.10 Å. The Sn(2)-C(11) bond length is 2.10 Å. The Sn(2)-O(1) bond length is 2.17 Å. The Sn(2)-O(3) bond length is 2.30 Å. The Sn(2)-O(5) bond length is 2.02 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.29 Å. The C(1)-O(2) bond length is 1.24 Å. In the second C site, C(2) is bonded in a water-like geometry to one C(3) and two equivalent H(1,2) atoms. The C(2)-C(3) bond length is 1.50 Å. Both C(2)-H(1,2) bond lengths are 0.99 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(8) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.95 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(6) bond length is 0.95 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.50 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(3), and one O(4) atom. The C(9)-O(3) bond length is 1.26 Å. The C(9)-O(4) bond length is 1.26 Å. In the eighth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one Sn(2), one H(7), one H(8), and one H(9) atom. The C(10)-H(7) bond length is 0.98 Å. The C(10)-H(8) bond length is 0.98 Å. The C(10)-H(9) bond length is 0.98 Å. In the ninth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one Sn(2), one H(10), one H(11), and one H(12) atom. The C(11)-H(10) bond length is 0.98 Å. The C(11)-H(11) bond length is 0.98 Å. The C(11)-H(12) bond length is 0.98 Å. In the tenth C site, C(12) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1), one H(13), one H(14), and one H(15) atom. The C(12)-H(13) bond length is 0.98 Å. The C(12)-H(14) bond length is 0.98 Å. The C(12)-H(15) bond length is 0.98 Å. In the eleventh C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one Sn(1); one H(16); and two equivalent H(17,18) atoms. The C(13)-H(16) bond length is 0.98 Å. Both C(13)-H(17,18) bond lengths are 0.98 Å. There are fourteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(13) atom. In the fourteenth H site, H(17,18) is bonded in a single-bond geometry to one C(13) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Sn(2) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Sn(2) and one C(9) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Sn(1) and one C(9) atom. In the fifth O site, O(5) is bonded in a trigonal planar geometry to one Sn(2) and two equivalent Sn(1) atoms. Linkers: 6 [O]C(=O)Cc1ccccc1C([O])=O. Metal clusters: 3 O=[C]O[Sn]1O[C]O[Sn]O1.O=[C]O[Sn]1O[C]O[Sn]O1. RCSR code: nbo. The MOF has largest included sphere 7.22 A, density 1.76 g/cm3, surface area 3445.57 m2/g, accessible volume 0.24 cm3/g