DyH8(C2O)8CuH12(C7N2)2(C3H2)6 is Indium-derived structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of twenty-four 2,3-dimethyl-1,3-butadiene molecules; eight CuH12(C7N2)2 clusters; and eight DyH8(C2O)8 clusters. In each CuH12(C7N2)2 cluster, Cu(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Cu(1)-N(1) bond length is 2.04 Å. The Cu(1)-N(2) bond length is 1.99 Å. The Cu(1)-N(3) bond length is 2.08 Å. The Cu(1)-N(4) bond length is 2.18 Å. There are fourteen inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(7) and one H(2) atom. The C(4)-C(7) bond length is 1.39 Å. The C(4)-H(2) bond length is 0.93 Å. In the second C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(5) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(8) bond length is 1.41 Å. The C(9)-H(5) bond length is 0.93 Å. In the third C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(6) atom. The C(10)-N(1) bond length is 1.35 Å. The C(10)-H(6) bond length is 0.93 Å. In the fourth C site, C(11) is bonded in a distorted single-bond geometry to one C(8) and one H(7,29) atom. The C(11)-C(8) bond length is 1.38 Å. The C(11)-H(7,29) bond length is 0.93 Å. In the fifth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(12)-N(1) bond length is 1.33 Å. The C(12)-H(8) bond length is 0.93 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(7), and one C(9) atom. The C(8)-C(7) bond length is 1.47 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(7)-C(6) bond length is 1.39 Å. In the eighth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(14) atom. The C(22)-N(2) bond length is 1.34 Å. The C(22)-H(14) bond length is 0.93 Å. In the ninth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(16) atom. The C(24)-N(2) bond length is 1.35 Å. The C(24)-H(16) bond length is 0.93 Å. In the tenth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(22) atom. The C(34)-N(3) bond length is 1.34 Å. The C(34)-H(22) bond length is 0.93 Å. In the eleventh C site, C(36) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(24) atom. The C(36)-N(3) bond length is 1.34 Å. The C(36)-H(24) bond length is 0.93 Å. In the twelfth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(30) atom. The C(46)-N(4) bond length is 1.34 Å. The C(46)-H(30) bond length is 0.93 Å. In the thirteenth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(32) atom. The C(48)-N(4) bond length is 1.33 Å. The C(48)-H(32) bond length is 0.93 Å. In the fourteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(12) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(34), and one C(36) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(22), and one C(24) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(46), and one C(48) atom. There are twelve inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(7,29) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(22) is bonded in a single-bond geometry to one C(34) atom. In the ninth H site, H(24) is bonded in a single-bond geometry to one C(36) atom. In the tenth H site, H(30) is bonded in a single-bond geometry to one C(46) atom. In the eleventh H site, H(32) is bonded in a single-bond geometry to one C(48) atom. In the twelfth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In each DyH8(C2O)8 cluster, Dy(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. The Dy(1)-O(1) bond length is 2.35 Å. The Dy(1)-O(2) bond length is 2.40 Å. The Dy(1)-O(3) bond length is 2.43 Å. The Dy(1)-O(4) bond length is 2.37 Å. The Dy(1)-O(5) bond length is 2.41 Å. The Dy(1)-O(6) bond length is 2.34 Å. The Dy(1)-O(7) bond length is 2.42 Å. The Dy(1)-O(8) bond length is 2.37 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(5) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(5) bond length is 1.41 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(5)-H(3) bond length is 0.93 Å. In the fourth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fifth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(3), and one O(4) atom. The C(13)-C(14) bond length is 1.50 Å. The C(13)-O(3) bond length is 1.27 Å. The C(13)-O(4) bond length is 1.24 Å. In the sixth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.38 Å. The C(14)-C(17) bond length is 1.37 Å. In the seventh C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(9) atom. The C(15)-H(9) bond length is 0.93 Å. In the eighth C site, C(17) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(17)-H(11) bond length is 0.93 Å. In the ninth C site, C(25) is bonded in a bent 120 degrees geometry to one C(26), one O(5), and one O(6) atom. The C(25)-C(26) bond length is 1.48 Å. The C(25)-O(5) bond length is 1.27 Å. The C(25)-O(6) bond length is 1.27 Å. In the tenth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(29) atom. The C(26)-C(27) bond length is 1.38 Å. The C(26)-C(29) bond length is 1.39 Å. In the eleventh C site, C(27) is bonded in a single-bond geometry to one C(26) and one H(17) atom. The C(27)-H(17) bond length is 0.93 Å. In the twelfth C site, C(29) is bonded in a single-bond geometry to one C(26) and one H(19) atom. The C(29)-H(19) bond length is 0.93 Å. In the thirteenth C site, C(37) is bonded in a bent 120 degrees geometry to one C(38), one O(7), and one O(8) atom. The C(37)-C(38) bond length is 1.51 Å. The C(37)-O(7) bond length is 1.23 Å. The C(37)-O(8) bond length is 1.27 Å. In the fourteenth C site, C(38) is bonded in a trigonal planar geometry to one C(37), one C(39), and one C(41) atom. The C(38)-C(39) bond length is 1.33 Å. The C(38)-C(41) bond length is 1.38 Å. In the fifteenth C site, C(39) is bonded in a distorted single-bond geometry to one C(38) and one H(25) atom. The C(39)-H(25) bond length is 0.93 Å. In the sixteenth C site, C(41) is bonded in a single-bond geometry to one C(38) and one H(27) atom. The C(41)-H(27) bond length is 0.93 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(27) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the seventh H site, H(25) is bonded in a single-bond geometry to one C(39) atom. In the eighth H site, H(27) is bonded in a single-bond geometry to one C(41) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Dy(1) and one C(1) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Dy(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Dy(1) and one C(13) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Dy(1) and one C(13) atom. In the fifth O site, O(5) is bonded in a distorted L-shaped geometry to one Dy(1) and one C(25) atom. In the sixth O site, O(6) is bonded in an L-shaped geometry to one Dy(1) and one C(25) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Dy(1) and one C(37) atom. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one Dy(1) and one C(37) atom. Linkers: 4 [O]C(=O)c1ccc(C2=C[CH]N([Cu](N3[CH]C=C(c4ccc(C([O])=O)cc4)C=C3)(N3[CH]C=C(c4ccc(C([O])=O)cc4)C=C3)N3[CH]C=C(c4ccc(C([O])=O)cc4)C=C3)C=C2)cc1 ,1 [CH][N][Cu](N1[CH]C=C(c2ccc(C([O])=O)cc2)C=C1)(N1[CH]C=C(c2ccc(C([O])=O)cc2)C=C1)N1[CH]C=C(c2ccc(C([O])=O)cc2)C=C1 ,1 [O]C(=O)c1ccc(C2=C[CH]N([Cu](N3[CH]C=C(c4ccc([C]=O)cc4)C=C3)(N3[CH]C=C(c4ccc(C([O])=O)cc4)C=C3)N3[CH]C=C(c4ccc(C([O])=O)cc4)C=C3)C=C2)cc1. Metal clusters: 4 O=[C]O[Dy]12(O[C]=O)(O[C]O1)O[C]O2. RCSR code: mdf. The MOF has largest included sphere 5.82 A, density 1.30 g/cm3, surface area 4454.92 m2/g, accessible volume 0.35 cm3/g