Sr2C68H32O8Cl(CH)16 crystallizes in the monoclinic P2_1/c space group. The structure consists of sixty-four 02329_fluka molecules inside a Sr2C68H32O8Cl framework. In the Sr2C68H32O8Cl framework, there are two inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(6), one O(8), and one Cl(1) atom. The Sr(1)-O(3) bond length is 2.45 Å. The Sr(1)-O(4) bond length is 2.53 Å. The Sr(1)-O(5) bond length is 2.65 Å. The Sr(1)-O(6) bond length is 2.55 Å. The Sr(1)-O(8) bond length is 2.49 Å. The Sr(1)-Cl(1) bond length is 2.86 Å. In the second Sr site, Sr(2) is bonded in a 4-coordinate geometry to one O(1), one O(5), one O(8), and one Cl(1) atom. The Sr(2)-O(1) bond length is 2.58 Å. The Sr(2)-O(5) bond length is 2.52 Å. The Sr(2)-O(8) bond length is 2.69 Å. The Sr(2)-Cl(1) bond length is 2.89 Å. There are sixty-eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(83) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.38 Å. The C(1)-C(83) bond length is 1.51 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(7) bond length is 1.50 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(4), and one C(8) atom. The C(7)-C(12) bond length is 1.42 Å. The C(7)-C(8) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(20), one C(7), and one C(9) atom. The C(8)-C(20) bond length is 1.42 Å. The C(8)-C(9) bond length is 1.44 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(17), and one C(8) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(17) bond length is 1.42 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(21), and one C(9) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-C(21) bond length is 1.49 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(16) atom. The C(11)-C(12) bond length is 1.43 Å. The C(11)-C(16) bond length is 1.41 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(7) atom. The C(12)-C(13) bond length is 1.43 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(5) atom. The C(13)-H(5) bond length is 0.93 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(11) and one H(8,40) atom. The C(16)-H(8,40) bond length is 0.93 Å. In the fifteenth C site, C(17) is bonded in a single-bond geometry to one C(9) and one H(9) atom. The C(17)-H(9) bond length is 0.93 Å. In the sixteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(8) and one H(12) atom. The C(20)-H(12) bond length is 0.93 Å. In the seventeenth C site, C(21) is bonded in a trigonal planar geometry to one C(10), one C(22), and one C(26) atom. The C(21)-C(22) bond length is 1.41 Å. The C(21)-C(26) bond length is 1.41 Å. In the eighteenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(34) atom. The C(22)-C(23) bond length is 1.43 Å. The C(22)-C(34) bond length is 1.42 Å. In the nineteenth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(31) atom. The C(23)-C(24) bond length is 1.42 Å. The C(23)-C(31) bond length is 1.44 Å. In the twentieth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(35) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-C(35) bond length is 1.49 Å. In the twenty-first C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(30) atom. The C(25)-C(26) bond length is 1.44 Å. The C(25)-C(30) bond length is 1.43 Å. In the twenty-second C site, C(26) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(27) atom. The C(26)-C(27) bond length is 1.42 Å. In the twenty-third C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(13) atom. The C(27)-H(13) bond length is 0.93 Å. In the twenty-fourth C site, C(30) is bonded in a distorted single-bond geometry to one C(25) and one H(16) atom. The C(30)-H(16) bond length is 0.93 Å. In the twenty-fifth C site, C(31) is bonded in a distorted single-bond geometry to one C(23) and one H(17) atom. The C(31)-H(17) bond length is 0.93 Å. In the twenty-sixth C site, C(34) is bonded in a distorted single-bond geometry to one C(22) and one H(20) atom. The C(34)-H(20) bond length is 0.93 Å. In the twenty-seventh C site, C(35) is bonded in a trigonal planar geometry to one C(24), one C(36), and one C(40) atom. The C(35)-C(36) bond length is 1.39 Å. The C(35)-C(40) bond length is 1.39 Å. In the twenty-eighth C site, C(36) is bonded in a distorted single-bond geometry to one C(35), one C(37), and one H(21) atom. The C(36)-C(37) bond length is 1.39 Å. The C(36)-H(21) bond length is 0.93 Å. In the twenty-ninth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(36), one C(38), and one H(22) atom. The C(37)-C(38) bond length is 1.41 Å. The C(37)-H(22) bond length is 0.93 Å. In the thirtieth C site, C(38) is bonded in a trigonal planar geometry to one C(37), one C(39), and one C(41) atom. The C(38)-C(39) bond length is 1.38 Å. The C(38)-C(41) bond length is 1.50 Å. In the thirty-first C site, C(39) is bonded in a distorted single-bond geometry to one C(38) and one H(23) atom. The C(39)-H(23) bond length is 0.93 Å. In the thirty-second C site, C(40) is bonded in a distorted single-bond geometry to one C(35) and one H(24) atom. The C(40)-H(24) bond length is 0.93 Å. In the thirty-third C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(38), one O(2), and one O(3) atom. The C(41)-O(2) bond length is 1.28 Å. The C(41)-O(3) bond length is 1.24 Å. In the thirty-fourth C site, C(42) is bonded in a trigonal planar geometry to one C(43), one C(47), and one C(84) atom. The C(42)-C(43) bond length is 1.38 Å. The C(42)-C(47) bond length is 1.39 Å. The C(42)-C(84) bond length is 1.49 Å. In the thirty-fifth C site, C(43) is bonded in a distorted single-bond geometry to one C(42) and one H(25) atom. The C(43)-H(25) bond length is 0.93 Å. In the thirty-sixth C site, C(44) is bonded in a distorted single-bond geometry to one C(45) and one H(26) atom. The C(44)-C(45) bond length is 1.38 Å. The C(44)-H(26) bond length is 0.93 Å. In the thirty-seventh C site, C(45) is bonded in a trigonal planar geometry to one C(44), one C(46), and one C(48) atom. The C(45)-C(46) bond length is 1.39 Å. The C(45)-C(48) bond length is 1.48 Å. In the thirty-eighth C site, C(46) is bonded in a distorted single-bond geometry to one C(45), one C(47), and one H(27) atom. The C(46)-C(47) bond length is 1.39 Å. The C(46)-H(27) bond length is 0.93 Å. In the thirty-ninth C site, C(47) is bonded in a distorted trigonal planar geometry to one C(42), one C(46), and one H(28) atom. The C(47)-H(28) bond length is 0.93 Å. In the fortieth C site, C(48) is bonded in a trigonal planar geometry to one C(45), one C(49), and one C(53) atom. The C(48)-C(49) bond length is 1.42 Å. The C(48)-C(53) bond length is 1.40 Å. In the forty-first C site, C(49) is bonded in a trigonal planar geometry to one C(48), one C(50), and one C(58) atom. The C(49)-C(50) bond length is 1.43 Å. The C(49)-C(58) bond length is 1.44 Å. In the forty-second C site, C(50) is bonded in a trigonal planar geometry to one C(49), one C(51), and one C(61) atom. The C(50)-C(51) bond length is 1.40 Å. The C(50)-C(61) bond length is 1.44 Å. In the forty-third C site, C(51) is bonded in a trigonal planar geometry to one C(50), one C(52), and one C(62) atom. The C(51)-C(52) bond length is 1.40 Å. The C(51)-C(62) bond length is 1.49 Å. In the forty-fourth C site, C(52) is bonded in a trigonal planar geometry to one C(51), one C(53), and one C(57) atom. The C(52)-C(53) bond length is 1.45 Å. The C(52)-C(57) bond length is 1.44 Å. In the forty-fifth C site, C(53) is bonded in a trigonal planar geometry to one C(48), one C(52), and one C(54) atom. The C(53)-C(54) bond length is 1.43 Å. In the forty-sixth C site, C(54) is bonded in a distorted single-bond geometry to one C(53) and one H(29) atom. The C(54)-H(29) bond length is 0.93 Å. In the forty-seventh C site, C(57) is bonded in a distorted single-bond geometry to one C(52) and one H(32) atom. The C(57)-H(32) bond length is 0.93 Å. In the forty-eighth C site, C(58) is bonded in a distorted single-bond geometry to one C(49) and one H(33) atom. The C(58)-H(33) bond length is 0.93 Å. In the forty-ninth C site, C(61) is bonded in a distorted single-bond geometry to one C(50) and one H(36) atom. The C(61)-H(36) bond length is 0.93 Å. In the fiftieth C site, C(62) is bonded in a trigonal planar geometry to one C(51), one C(63), and one C(67) atom. The C(62)-C(63) bond length is 1.41 Å. The C(62)-C(67) bond length is 1.43 Å. In the fifty-first C site, C(63) is bonded in a trigonal planar geometry to one C(62), one C(64), and one C(72) atom. The C(63)-C(64) bond length is 1.43 Å. The C(63)-C(72) bond length is 1.41 Å. In the fifty-second C site, C(64) is bonded in a trigonal planar geometry to one C(63), one C(65), and one C(75) atom. The C(64)-C(65) bond length is 1.43 Å. The C(64)-C(75) bond length is 1.42 Å. In the fifty-third C site, C(65) is bonded in a trigonal planar geometry to one C(64), one C(66), and one C(76) atom. The C(65)-C(66) bond length is 1.42 Å. The C(65)-C(76) bond length is 1.48 Å. In the fifty-fourth C site, C(66) is bonded in a trigonal planar geometry to one C(65), one C(67), and one C(71) atom. The C(66)-C(67) bond length is 1.43 Å. The C(66)-C(71) bond length is 1.42 Å. In the fifty-fifth C site, C(67) is bonded in a trigonal planar geometry to one C(62), one C(66), and one C(68) atom. The C(67)-C(68) bond length is 1.42 Å. In the fifty-sixth C site, C(68) is bonded in a distorted single-bond geometry to one C(67) and one H(37) atom. The C(68)-H(37) bond length is 0.93 Å. In the fifty-seventh C site, C(71) is bonded in a distorted single-bond geometry to one C(66) and one H(8,40) atom. The C(71)-H(8,40) bond length is 0.93 Å. In the fifty-eighth C site, C(72) is bonded in a distorted single-bond geometry to one C(63) and one H(41) atom. The C(72)-H(41) bond length is 0.93 Å. In the fifty-ninth C site, C(75) is bonded in a distorted single-bond geometry to one C(64) and one H(44) atom. The C(75)-H(44) bond length is 0.93 Å. In the sixtieth C site, C(76) is bonded in a trigonal planar geometry to one C(65), one C(77), and one C(81) atom. The C(76)-C(77) bond length is 1.41 Å. The C(76)-C(81) bond length is 1.38 Å. In the sixty-first C site, C(77) is bonded in a distorted single-bond geometry to one C(76), one C(78), and one H(45) atom. The C(77)-C(78) bond length is 1.40 Å. The C(77)-H(45) bond length is 0.93 Å. In the sixty-second C site, C(78) is bonded in a distorted trigonal planar geometry to one C(77), one C(79), and one H(46) atom. The C(78)-C(79) bond length is 1.39 Å. The C(78)-H(46) bond length is 0.93 Å. In the sixty-third C site, C(79) is bonded in a trigonal planar geometry to one C(78), one C(80), and one C(82) atom. The C(79)-C(80) bond length is 1.38 Å. The C(79)-C(82) bond length is 1.50 Å. In the sixty-fourth C site, C(80) is bonded in a distorted trigonal planar geometry to one C(79), one C(81), and one H(47) atom. The C(80)-C(81) bond length is 1.38 Å. The C(80)-H(47) bond length is 0.93 Å. In the sixty-fifth C site, C(81) is bonded in a distorted single-bond geometry to one C(76), one C(80), and one H(48) atom. The C(81)-H(48) bond length is 0.93 Å. In the sixty-sixth C site, C(82) is bonded in a distorted bent 120 degrees geometry to one C(79), one O(6), and one O(7) atom. The C(82)-O(6) bond length is 1.25 Å. The C(82)-O(7) bond length is 1.29 Å. In the sixty-seventh C site, C(83) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(8) atom. The C(83)-O(1) bond length is 1.25 Å. The C(83)-O(8) bond length is 1.26 Å. In the sixty-eighth C site, C(84) is bonded in a distorted bent 120 degrees geometry to one C(42), one O(4), and one O(5) atom. The C(84)-O(4) bond length is 1.25 Å. The C(84)-O(5) bond length is 1.28 Å. There are thirty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(8,40) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(30) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(31) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(34) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(36) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(37) atom. In the fifteenth H site, H(23) is bonded in a single-bond geometry to one C(39) atom. In the sixteenth H site, H(24) is bonded in a single-bond geometry to one C(40) atom. In the seventeenth H site, H(25) is bonded in a single-bond geometry to one C(43) atom. In the eighteenth H site, H(26) is bonded in a single-bond geometry to one C(44) atom. In the nineteenth H site, H(27) is bonded in a single-bond geometry to one C(46) atom. In the twentieth H site, H(28) is bonded in a single-bond geometry to one C(47) atom. In the twenty-first H site, H(29) is bonded in a single-bond geometry to one C(54) atom. In the twenty-second H site, H(32) is bonded in a single-bond geometry to one C(57) atom. In the twenty-third H site, H(33) is bonded in a single-bond geometry to one C(58) atom. In the twenty-fourth H site, H(36) is bonded in a single-bond geometry to one C(61) atom. In the twenty-fifth H site, H(37) is bonded in a single-bond geometry to one C(68) atom. In the twenty-sixth H site, H(41) is bonded in a single-bond geometry to one C(72) atom. In the twenty-seventh H site, H(44) is bonded in a single-bond geometry to one C(75) atom. In the twenty-eighth H site, H(45) is bonded in a single-bond geometry to one C(77) atom. In the twenty-ninth H site, H(46) is bonded in a single-bond geometry to one C(78) atom. In the thirtieth H site, H(47) is bonded in a single-bond geometry to one C(80) atom. In the thirty-first H site, H(48) is bonded in a single-bond geometry to one C(81) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Sr(2) and one C(83) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(41) atom. In the third O site, O(5) is bonded in a distorted T-shaped geometry to one Sr(1), one Sr(2), and one C(84) atom. In the fourth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Sr(1) and one C(82) atom. In the fifth O site, O(3) is bonded in a bent 150 degrees geometry to one Sr(1) and one C(41) atom. In the sixth O site, O(4) is bonded in a distorted single-bond geometry to one Sr(1) and one C(84) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(82) atom. In the eighth O site, O(8) is bonded in a distorted T-shaped geometry to one Sr(1), one Sr(2), and one C(83) atom. Cl(1) is bonded in a linear geometry to one Sr(1) and one Sr(2) atom. Linkers: 8 [O]C(=O)c1ccc(-c2c3ccccc3c(-c3c4ccccc4c(-c4ccc(C([O])=O)cc4)c4ccccc34)c3ccccc23)cc1. Metal clusters: 8 [Sr]. The MOF has largest included sphere 6.66 A, density 1.07 g/cm3, surface area 4796.79 m2/g, accessible volume 0.52 cm3/g