ZnC10H4(NO)4 is Indium-like structured and crystallizes in the tetragonal P4/mmm space group. The structure is zero-dimensional and consists of one ZnC10H4(NO)4 cluster. Zn(1) is bonded in a square co-planar geometry to four equivalent O(1) atoms. All Zn(1)-O(1) bond lengths are 2.06 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(1) atom. The C(1)-C(3) bond length is 1.42 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3) and two equivalent O(1) atoms. The C(2)-C(3) bond length is 1.50 Å. Both C(2)-O(1) bond lengths are 1.26 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2) and two equivalent C(1) atoms. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to two equivalent N(1) atoms. Both C(4)-N(1) bond lengths are 1.34 Å. N(1) is bonded in a bent 120 degrees geometry to one C(1) and one C(4) atom. H(1) is bonded in a single-bond geometry to one C(1) atom. O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. Linkers: 2 [O]C(=O)c1cnc(-c2ncc(C([O])=O)cn2)nc1. Metal clusters: 1 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: sql. The MOF has largest included sphere 13.96 A, density 0.47 g/cm3, surface area 4094.27 m2/g, accessible volume 1.72 cm3/g