Cu2C32N3H18O8C5H4 is High-temperature superconductor structured and crystallizes in the cubic Im-3m space group. The structure is zero-dimensional and consists of six C5H4 clusters and two Cu2C32N3H18O8 clusters. In each C5H4 cluster, there are two inequivalent C sites. In the first C site, C(1) is bonded in a 5-coordinate geometry to one C(1) and four equivalent C(10) atoms. The C(1)-C(1) bond length is 1.48 Å. All C(1)-C(10) bond lengths are 1.30 Å. In the second C site, C(10) is bonded in a distorted single-bond geometry to one C(1) and one H(6) atom. The C(10)-H(6) bond length is 0.96 Å. H(6) is bonded in a single-bond geometry to one C(10) atom. In each Cu2C32N3H18O8 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. All Cu(1)-O(1) bond lengths are 1.98 Å. In the second Cu site, Cu(2) is bonded in a square pyramidal geometry to one N(1) and four equivalent O(2) atoms. The Cu(2)-N(1) bond length is 2.10 Å. All Cu(2)-O(2) bond lengths are 1.93 Å. There are eight inequivalent C sites. In the first C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(2) atom. The C(2)-C(3) bond length is 1.45 Å. The C(2)-O(1) bond length is 1.25 Å. The C(2)-O(2) bond length is 1.24 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.42 Å. The C(3)-C(8) bond length is 1.51 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2) bond length is 0.96 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(5), and one C(6) atom. The C(5)-C(5) bond length is 1.42 Å. The C(5)-C(6) bond length is 1.47 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.30 Å. The C(6)-N(2) bond length is 1.29 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(3) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(3) bond length is 0.96 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(4) atom. The C(8)-H(4) bond length is 0.96 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(9)-N(1) bond length is 1.27 Å. The C(9)-H(5) bond length is 0.96 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 5-coordinate geometry to one Cu(2) and four equivalent C(9) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to two equivalent C(6) and one H(1) atom. The N(2)-H(1) bond length is 0.90 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(2) atom. Linkers: 1 [CH]1[C@@H]2[C@H]3[C@@]42[C@H]2[CH][N@@]51[C@@H]([C@H]35)[C@@H]42.C1=C[N]23C=C[C@@]41[C@@H]1[C@H]4[C@H]2[C@H]31 ,1 [CH]1[C@@H]2[C@H]3[C@]42[C@H]2[C@H]5[N@@]1([CH]3)[C@H]5[C@@H]42.[CH]1[C@@H]2[C@H]3[C@]42[C@H]2[C@H]5[N@@]1([CH]3)[C@H]5[C@@H]42 ,1 [CH]1[C@@H]2[C@H]3[N@@]42[C@@H]2[C@@H]5[C@@]1([CH]3)[C@@H]5[C@H]42.[CH]1[C@@H]2[C@H]3[N@@]42[C@@H]2[C@@H]5[C@@]1([CH]3)[C@@H]5[C@H]42 ,1 [CH]1[C@@H]2[C@H]3[C@]42[C@H]2[CH][N@@]51[C@@H]([C@H]35)[C@@H]42.C1=C[N]23[CH][C@H]4[C@@]51[CH][C@@H]3[C@@H]2[C@@H]45 ,1 [CH]1[C@@H]2[C@H]3[N@]42[C@H]2[C@H]5[C@@]1([CH]3)[C@H]5[C@@H]42.[CH]1[C@@H]2[C@H]3[N@]42[C@H]2[C@H]5[C@@]1([CH]3)[C@H]5[C@@H]42 ,1 [CH]1[C@@H]2[C@H]3[C@]42[C@H]2[CH][N@@]51[C@@H]([C@H]35)[C@@H]42.[CH]1[C@@H]2[C@H]3[C@@]42[C@H]2[CH][N@@]51[C@@H]([C@H]35)[C@@H]42 ,24 [O]C(=O)c1ccc2[nH]c3ccc(C([O])=O)cc3c2c1. Metal clusters: 12 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 12.03 A, density 0.53 g/cm3, surface area 4047.14 m2/g, accessible volume 1.29 cm3/g