(CuC5O4)2Cu(C2O)4(C)32(P(C5O2)2)2 is Indium-derived structured and crystallizes in the orthorhombic C222 space group. The structure is zero-dimensional and consists of eight C clusters, two Cu(C2O)4 clusters, four CuC5O4 clusters, and four P(C5O2)2 clusters. In each C cluster, there are sixteen inequivalent C sites. In the first C site, C(16) is bonded in a distorted single-bond geometry to one C(26) atom. The C(16)-C(26) bond length is 1.00 Å. In the second C site, C(17) is bonded in a distorted single-bond geometry to one C(27) and one C(4) atom. The C(17)-C(27) bond length is 1.11 Å. The C(17)-C(4) bond length is 1.60 Å. In the third C site, C(21) is bonded in a single-bond geometry to one C(22), one C(26), and one C(31) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-C(26) bond length is 1.62 Å. The C(21)-C(31) bond length is 1.07 Å. In the fourth C site, C(22) is bonded in a 3-coordinate geometry to one C(21), one C(23), and one C(32) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-C(32) bond length is 0.97 Å. In the fifth C site, C(23) is bonded in a distorted single-bond geometry to one C(10), one C(22), and one C(33) atom. The C(23)-C(10) bond length is 1.70 Å. The C(23)-C(33) bond length is 1.06 Å. In the sixth C site, C(26) is bonded in a 4-coordinate geometry to one C(16), one C(21), one C(27), and one C(31) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-C(31) bond length is 1.39 Å. In the seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(17), one C(26), and one C(4) atom. The C(27)-C(4) bond length is 1.85 Å. In the eighth C site, C(31) is bonded in a single-bond geometry to one C(21) and one C(26) atom. In the ninth C site, C(32) is bonded in a distorted single-bond geometry to one C(22) atom. In the tenth C site, C(33) is bonded in a distorted single-bond geometry to one C(10) and one C(23) atom. The C(33)-C(10) bond length is 1.53 Å. In the eleventh C site, C(3) is bonded in a single-bond geometry to one C(4) atom. The C(3)-C(4) bond length is 1.39 Å. In the twelfth C site, C(4) is bonded in a 4-coordinate geometry to one C(17), one C(27), one C(3), and one C(5) atom. The C(4)-C(5) bond length is 1.39 Å. In the thirteenth C site, C(5) is bonded in a single-bond geometry to one C(4) atom. In the fourteenth C site, C(9) is bonded in a single-bond geometry to one C(10) atom. The C(9)-C(10) bond length is 1.39 Å. In the fifteenth C site, C(10) is bonded in a 4-coordinate geometry to one C(11), one C(23), one C(33), and one C(9) atom. The C(10)-C(11) bond length is 1.39 Å. In the sixteenth C site, C(11) is bonded in a single-bond geometry to one C(10) atom. In each Cu(C2O)4 cluster, Cu(2) is bonded in a distorted T-shaped geometry to one Cu(2) and two equivalent O(1) atoms. The Cu(2)-Cu(2) bond length is 2.65 Å. Both Cu(2)-O(1) bond lengths are 1.90 Å. There are four inequivalent C sites. In the first C site, C(15) is bonded in a bent 150 degrees geometry to one C(1), one O(1), and one O(6) atom. The C(15)-C(1) bond length is 1.64 Å. The C(15)-O(1) bond length is 1.25 Å. The C(15)-O(6) bond length is 1.20 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one C(15), one C(2), and one C(6) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.39 Å. In the third C site, C(2) is bonded in a single-bond geometry to one C(1) atom. In the fourth C site, C(6) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cu(2) and one C(15) atom. In the second O site, O(6) is bonded in a single-bond geometry to one C(15) atom. In each CuC5O4 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), one O(4), and one O(5) atom. The Cu(1)-O(2) bond length is 2.02 Å. The Cu(1)-O(3) bond length is 1.87 Å. The Cu(1)-O(4) bond length is 1.90 Å. The Cu(1)-O(5) bond length is 1.92 Å. There are five inequivalent C sites. In the first C site, C(13) is bonded in a bent 150 degrees geometry to one O(3) and one O(4) atom. The C(13)-O(3) bond length is 1.31 Å. The C(13)-O(4) bond length is 1.16 Å. In the second C site, C(14) is bonded in a distorted bent 150 degrees geometry to one C(7), one O(2), and one O(5) atom. The C(14)-C(7) bond length is 1.64 Å. The C(14)-O(2) bond length is 1.17 Å. The C(14)-O(5) bond length is 1.33 Å. In the third C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(8) atom. The C(7)-C(12) bond length is 1.39 Å. The C(7)-C(8) bond length is 1.39 Å. In the fourth C site, C(8) is bonded in a single-bond geometry to one C(7) atom. In the fifth C site, C(12) is bonded in a single-bond geometry to one C(7) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Cu(1) and one C(14) atom. In the second O site, O(3) is bonded in a water-like geometry to one Cu(1) and one C(13) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(13) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one Cu(1) and one C(14) atom. In each P(C5O2)2 cluster, there are ten inequivalent C sites. In the first C site, C(18) is bonded in a single-bond geometry to one C(28) atom. The C(18)-C(28) bond length is 1.28 Å. In the second C site, C(19) is bonded in a distorted single-bond geometry to one C(29) atom. The C(19)-C(29) bond length is 1.35 Å. In the third C site, C(20) is bonded in a 1-coordinate geometry to one C(25) and one C(30) atom. The C(20)-C(25) bond length is 1.39 Å. The C(20)-C(30) bond length is 1.25 Å. In the fourth C site, C(24) is bonded in a 1-coordinate geometry to one C(25), one C(34), and one O(7) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-C(34) bond length is 1.23 Å. The C(24)-O(7) bond length is 1.36 Å. In the fifth C site, C(25) is bonded in a 4-coordinate geometry to one C(20), one C(24), one C(25), and one C(35) atom. The C(25)-C(25) bond length is 1.57 Å. The C(25)-C(35) bond length is 1.33 Å. In the sixth C site, C(28) is bonded in a 1-coordinate geometry to one C(18), one C(29), and one O(10) atom. The C(28)-C(29) bond length is 1.39 Å. The C(28)-O(10) bond length is 1.49 Å. In the seventh C site, C(29) is bonded in a 4-coordinate geometry to one C(19), one C(28), one C(29), and one C(30) atom. The C(29)-C(29) bond length is 1.55 Å. The C(29)-C(30) bond length is 1.39 Å. In the eighth C site, C(30) is bonded in a distorted single-bond geometry to one C(20) and one C(29) atom. In the ninth C site, C(34) is bonded in a single-bond geometry to one C(24) atom. In the tenth C site, C(35) is bonded in a distorted single-bond geometry to one C(25) atom. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted tetrahedral geometry to two equivalent O(7) and two equivalent O(8) atoms. Both P(1)-O(7) bond lengths are 1.65 Å. Both P(1)-O(8) bond lengths are 1.39 Å. In the second P site, P(2) is bonded in a tetrahedral geometry to two equivalent O(10) and two equivalent O(9) atoms. Both P(2)-O(10) bond lengths are 1.53 Å. Both P(2)-O(9) bond lengths are 1.43 Å. There are four inequivalent O sites. In the first O site, O(7) is bonded in a bent 120 degrees geometry to one C(24) and one P(1) atom. In the second O site, O(8) is bonded in a single-bond geometry to one P(1) atom. In the third O site, O(9) is bonded in a single-bond geometry to one P(2) atom. In the fourth O site, O(10) is bonded in a bent 120 degrees geometry to one C(28) and one P(2) atom. Linkers: 5 [O]C(=O)c1[c][c]c([C@]23[C]4[C]5[C]2[C@@]26[C]7[C]8[C@]9(c%10[c][c]c(C([O])=O)[c][c]%10)[C]%10[C]%11[C@@]%12%13[C@@]8%10O[P@]([O])(=O)O[C@]8%10[C]%14[C]%15[C]%16[C@@]%14(c%14[c][c]c(C([O])=O)[c][c]%14)[C]8[C]8[C@@]%10%12[C@]%10%12[C]%14[C]%17[C@@]%18(c%19[c][c]c(C([O])=O)[c][c]%19)[C]%19[C]%20[C]%18[C@]%15%10[C@]%20%16[C@]8%12[C@@]%148[C@@]%19%17O[P@@]([O])(=O)O[C@@]4%10[C]3[C]3[C@@]%108[C@]%11([C@]52[C]79)[C@@]36%13)[c][c]1. Metal clusters: 6 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 16.78 A, density 0.36 g/cm3, surface area 3350.85 m2/g, accessible volume 2.31 cm3/g