V12Ni4C36N15H34O22(C3H2)13 crystallizes in the triclinic P1 space group. The structure consists of thirteen 2,3-dimethyl-1,3-butadiene molecules inside a V12Ni4C36N15H34O22 framework. In the V12Ni4C36N15H34O22 framework, there are twenty-four inequivalent V sites. In the first V site, V(1) is bonded in a trigonal non-coplanar geometry to one O(23), one O(31), and one O(5) atom. The V(1)-O(23) bond length is 1.81 Å. The V(1)-O(31) bond length is 1.81 Å. The V(1)-O(5) bond length is 1.66 Å. In the second V site, V(2) is bonded in a trigonal non-coplanar geometry to one O(10), one O(17), and one O(6) atom. The V(2)-O(10) bond length is 1.82 Å. The V(2)-O(17) bond length is 1.82 Å. The V(2)-O(6) bond length is 1.65 Å. In the third V site, V(3) is bonded in a trigonal non-coplanar geometry to one O(34), one O(35), and one O(4) atom. The V(3)-O(34) bond length is 1.83 Å. The V(3)-O(35) bond length is 1.80 Å. The V(3)-O(4) bond length is 1.67 Å. In the fourth V site, V(4) is bonded in a trigonal non-coplanar geometry to one O(16), one O(17), and one O(29) atom. The V(4)-O(16) bond length is 1.78 Å. The V(4)-O(17) bond length is 1.78 Å. The V(4)-O(29) bond length is 1.76 Å. In the fifth V site, V(5) is bonded in a trigonal non-coplanar geometry to one O(13), one O(24), and one O(3) atom. The V(5)-O(13) bond length is 1.83 Å. The V(5)-O(24) bond length is 1.79 Å. The V(5)-O(3) bond length is 1.66 Å. In the sixth V site, V(6) is bonded in a trigonal non-coplanar geometry to one O(12), one O(7), and one O(8) atom. The V(6)-O(12) bond length is 1.82 Å. The V(6)-O(7) bond length is 1.83 Å. The V(6)-O(8) bond length is 1.66 Å. In the seventh V site, V(7) is bonded in a trigonal non-coplanar geometry to one O(13), one O(19), and one O(7) atom. The V(7)-O(13) bond length is 1.75 Å. The V(7)-O(19) bond length is 1.76 Å. The V(7)-O(7) bond length is 1.77 Å. In the eighth V site, V(8) is bonded in a trigonal non-coplanar geometry to one O(16), one O(24), and one O(32) atom. The V(8)-O(16) bond length is 1.84 Å. The V(8)-O(24) bond length is 1.79 Å. The V(8)-O(32) bond length is 1.67 Å. In the ninth V site, V(9) is bonded in a trigonal non-coplanar geometry to one O(22), one O(25), and one O(26) atom. The V(9)-O(22) bond length is 1.69 Å. The V(9)-O(25) bond length is 1.86 Å. The V(9)-O(26) bond length is 1.80 Å. In the tenth V site, V(10) is bonded in a trigonal non-coplanar geometry to one O(18), one O(19), and one O(29) atom. The V(10)-O(18) bond length is 1.67 Å. The V(10)-O(19) bond length is 1.81 Å. The V(10)-O(29) bond length is 1.81 Å. In the eleventh V site, V(11) is bonded in a trigonal non-coplanar geometry to one O(10), one O(31), and one O(34) atom. The V(11)-O(10) bond length is 1.75 Å. The V(11)-O(31) bond length is 1.76 Å. The V(11)-O(34) bond length is 1.77 Å. In the twelfth V site, V(12) is bonded in a trigonal non-coplanar geometry to one O(1), one O(14), and one O(42) atom. The V(12)-O(1) bond length is 1.64 Å. The V(12)-O(14) bond length is 1.78 Å. The V(12)-O(42) bond length is 1.82 Å. In the thirteenth V site, V(13) is bonded in a trigonal non-coplanar geometry to one O(11), one O(12), and one O(23) atom. The V(13)-O(11) bond length is 1.77 Å. The V(13)-O(12) bond length is 1.77 Å. The V(13)-O(23) bond length is 1.77 Å. In the fourteenth V site, V(14) is bonded in a trigonal non-coplanar geometry to one O(15), one O(40), and one O(9) atom. The V(14)-O(15) bond length is 1.83 Å. The V(14)-O(40) bond length is 1.81 Å. The V(14)-O(9) bond length is 1.68 Å. In the fifteenth V site, V(15) is bonded in a trigonal non-coplanar geometry to one O(15), one O(25), and one O(30) atom. The V(15)-O(15) bond length is 1.75 Å. The V(15)-O(25) bond length is 1.78 Å. The V(15)-O(30) bond length is 1.72 Å. In the sixteenth V site, V(16) is bonded in a trigonal non-coplanar geometry to one O(33), one O(40), and one O(41) atom. The V(16)-O(33) bond length is 1.73 Å. The V(16)-O(40) bond length is 1.71 Å. The V(16)-O(41) bond length is 1.75 Å. In the seventeenth V site, V(17) is bonded in a trigonal non-coplanar geometry to one O(21), one O(37), and one O(42) atom. The V(17)-O(21) bond length is 1.75 Å. The V(17)-O(37) bond length is 1.76 Å. The V(17)-O(42) bond length is 1.75 Å. In the eighteenth V site, V(18) is bonded in a trigonal non-coplanar geometry to one O(20), one O(26), and one O(33) atom. The V(18)-O(20) bond length is 1.69 Å. The V(18)-O(26) bond length is 1.78 Å. The V(18)-O(33) bond length is 1.82 Å. In the nineteenth V site, V(19) is bonded in a trigonal non-coplanar geometry to one O(27), one O(28), and one O(38) atom. The V(19)-O(27) bond length is 1.68 Å. The V(19)-O(28) bond length is 1.77 Å. The V(19)-O(38) bond length is 1.82 Å. In the twentieth V site, V(20) is bonded in a trigonal non-coplanar geometry to one O(11), one O(2), and one O(35) atom. The V(20)-O(11) bond length is 1.85 Å. The V(20)-O(2) bond length is 1.67 Å. The V(20)-O(35) bond length is 1.78 Å. In the twenty-first V site, V(21) is bonded in a trigonal non-coplanar geometry to one O(28), one O(36), and one O(37) atom. The V(21)-O(28) bond length is 1.81 Å. The V(21)-O(36) bond length is 1.67 Å. The V(21)-O(37) bond length is 1.85 Å. In the twenty-second V site, V(22) is bonded in a trigonal non-coplanar geometry to one O(30), one O(41), and one O(44) atom. The V(22)-O(30) bond length is 1.80 Å. The V(22)-O(41) bond length is 1.80 Å. The V(22)-O(44) bond length is 1.64 Å. In the twenty-third V site, V(23) is bonded in a trigonal non-coplanar geometry to one O(21), one O(39), and one O(43) atom. The V(23)-O(21) bond length is 1.82 Å. The V(23)-O(39) bond length is 1.63 Å. The V(23)-O(43) bond length is 1.81 Å. In the twenty-fourth V site, V(24) is bonded in a trigonal non-coplanar geometry to one O(14), one O(38), and one O(43) atom. The V(24)-O(14) bond length is 1.86 Å. The V(24)-O(38) bond length is 1.73 Å. The V(24)-O(43) bond length is 1.77 Å. There are eight inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in an octahedral geometry to one N(16), one N(17), one N(18), one N(23), one O(32), and one O(9) atom. The Ni(1)-N(16) bond length is 2.12 Å. The Ni(1)-N(17) bond length is 2.09 Å. The Ni(1)-N(18) bond length is 2.10 Å. The Ni(1)-N(23) bond length is 2.10 Å. The Ni(1)-O(32) bond length is 2.04 Å. The Ni(1)-O(9) bond length is 2.04 Å. In the second Ni site, Ni(2) is bonded in an octahedral geometry to one N(12), one N(3), one N(4), one N(8), one O(36), and one O(44) atom. The Ni(2)-N(12) bond length is 2.14 Å. The Ni(2)-N(3) bond length is 2.13 Å. The Ni(2)-N(4) bond length is 2.11 Å. The Ni(2)-N(8) bond length is 2.08 Å. The Ni(2)-O(36) bond length is 2.01 Å. The Ni(2)-O(44) bond length is 2.00 Å. In the third Ni site, Ni(3) is bonded in an octahedral geometry to one N(13), one N(14), one N(15), one N(24), one O(1), and one O(2) atom. The Ni(3)-N(13) bond length is 2.11 Å. The Ni(3)-N(14) bond length is 2.12 Å. The Ni(3)-N(15) bond length is 2.11 Å. The Ni(3)-N(24) bond length is 2.11 Å. The Ni(3)-O(1) bond length is 2.07 Å. The Ni(3)-O(2) bond length is 2.06 Å. In the fourth Ni site, Ni(4) is bonded in a square pyramidal geometry to one N(26), one N(27), one N(28), one O(22), and one O(8) atom. The Ni(4)-N(26) bond length is 2.12 Å. The Ni(4)-N(27) bond length is 2.09 Å. The Ni(4)-N(28) bond length is 2.11 Å. The Ni(4)-O(22) bond length is 2.07 Å. The Ni(4)-O(8) bond length is 2.07 Å. In the fifth Ni site, Ni(5) is bonded in a square pyramidal geometry to one N(25), one N(29), one N(30), one O(27), and one O(6) atom. The Ni(5)-N(25) bond length is 2.11 Å. The Ni(5)-N(29) bond length is 2.11 Å. The Ni(5)-N(30) bond length is 2.11 Å. The Ni(5)-O(27) bond length is 2.05 Å. The Ni(5)-O(6) bond length is 2.04 Å. In the sixth Ni site, Ni(6) is bonded in an octahedral geometry to one N(10), one N(11), one N(19), one N(21), one O(18), and one O(3) atom. The Ni(6)-N(10) bond length is 2.12 Å. The Ni(6)-N(11) bond length is 2.09 Å. The Ni(6)-N(19) bond length is 2.15 Å. The Ni(6)-N(21) bond length is 2.12 Å. The Ni(6)-O(18) bond length is 2.02 Å. The Ni(6)-O(3) bond length is 2.03 Å. In the seventh Ni site, Ni(7) is bonded in an octahedral geometry to one N(2), one N(20), one N(22), one N(7), one O(4), and one O(5) atom. The Ni(7)-N(2) bond length is 2.10 Å. The Ni(7)-N(20) bond length is 2.09 Å. The Ni(7)-N(22) bond length is 2.13 Å. The Ni(7)-N(7) bond length is 2.11 Å. The Ni(7)-O(4) bond length is 2.02 Å. The Ni(7)-O(5) bond length is 2.02 Å. In the eighth Ni site, Ni(8) is bonded in an octahedral geometry to one N(1), one N(5), one N(6), one N(9), one O(20), and one O(39) atom. The Ni(8)-N(1) bond length is 2.13 Å. The Ni(8)-N(5) bond length is 2.10 Å. The Ni(8)-N(6) bond length is 2.13 Å. The Ni(8)-N(9) bond length is 2.08 Å. The Ni(8)-O(20) bond length is 1.99 Å. The Ni(8)-O(39) bond length is 2.01 Å. There are seventy-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5) atom. The C(6)-N(2) bond length is 1.36 Å. The C(6)-H(5) bond length is 0.95 Å. In the fourth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(8) bond length is 0.95 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(11)-N(3) bond length is 1.34 Å. The C(11)-H(9) bond length is 0.95 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(12)-C(13) bond length is 1.36 Å. The C(12)-H(10) bond length is 0.95 Å. In the seventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(18) atom. The C(13)-C(14) bond length is 1.34 Å. The C(13)-C(18) bond length is 1.53 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(14)-H(11) bond length is 0.95 Å. In the ninth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(12) atom. The C(15)-N(3) bond length is 1.36 Å. The C(15)-H(12) bond length is 0.95 Å. In the tenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(13) atom. The C(16)-N(4) bond length is 1.36 Å. The C(16)-H(13) bond length is 0.95 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(14) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-H(14) bond length is 0.95 Å. In the twelfth C site, C(18) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(19) atom. The C(18)-C(19) bond length is 1.41 Å. In the thirteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(15) atom. The C(19)-C(20) bond length is 1.37 Å. The C(19)-H(15) bond length is 0.95 Å. In the fourteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(4), and one H(16) atom. The C(20)-N(4) bond length is 1.37 Å. The C(20)-H(16) bond length is 0.95 Å. In the fifteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(17) atom. The C(21)-N(5) bond length is 1.35 Å. The C(21)-H(17) bond length is 0.95 Å. In the sixteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(20) atom. The C(25)-N(5) bond length is 1.37 Å. The C(25)-H(20) bond length is 0.95 Å. In the seventeenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(21) atom. The C(26)-N(6) bond length is 1.32 Å. The C(26)-H(21) bond length is 0.95 Å. In the eighteenth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(24) atom. The C(30)-N(6) bond length is 1.32 Å. The C(30)-H(24) bond length is 0.95 Å. In the nineteenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(25) atom. The C(31)-N(7) bond length is 1.35 Å. The C(31)-H(25) bond length is 0.95 Å. In the twentieth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(28) atom. The C(35)-N(7) bond length is 1.34 Å. The C(35)-H(28) bond length is 0.95 Å. In the twenty-first C site, C(36) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(29) atom. The C(36)-N(8) bond length is 1.37 Å. The C(36)-H(29) bond length is 0.95 Å. In the twenty-second C site, C(40) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(32) atom. The C(40)-N(8) bond length is 1.36 Å. The C(40)-H(32) bond length is 0.95 Å. In the twenty-third C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(33) atom. The C(41)-N(9) bond length is 1.30 Å. The C(41)-H(33) bond length is 0.95 Å. In the twenty-fourth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(36) atom. The C(45)-N(9) bond length is 1.30 Å. The C(45)-H(36) bond length is 0.95 Å. In the twenty-fifth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(37) atom. The C(46)-N(10) bond length is 1.35 Å. The C(46)-H(37) bond length is 0.95 Å. In the twenty-sixth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(40) atom. The C(50)-N(10) bond length is 1.34 Å. The C(50)-H(40) bond length is 0.95 Å. In the twenty-seventh C site, C(51) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(41) atom. The C(51)-N(11) bond length is 1.32 Å. The C(51)-H(41) bond length is 0.95 Å. In the twenty-eighth C site, C(55) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(44) atom. The C(55)-N(11) bond length is 1.32 Å. The C(55)-H(44) bond length is 0.95 Å. In the twenty-ninth C site, C(58) is bonded in a distorted bent 120 degrees geometry to one N(12) and one H(46,47) atom. The C(58)-N(12) bond length is 1.39 Å. The C(58)-H(46,47) bond length is 0.95 Å. In the thirtieth C site, C(59) is bonded in a distorted bent 120 degrees geometry to one N(12) and one H(46,47) atom. The C(59)-N(12) bond length is 1.39 Å. The C(59)-H(46,47) bond length is 0.95 Å. In the thirty-first C site, C(61) is bonded in a distorted bent 120 degrees geometry to one N(13) and one H(49) atom. The C(61)-N(13) bond length is 1.34 Å. The C(61)-H(49) bond length is 0.95 Å. In the thirty-second C site, C(65) is bonded in a distorted bent 120 degrees geometry to one N(13) and one H(52) atom. The C(65)-N(13) bond length is 1.33 Å. The C(65)-H(52) bond length is 0.95 Å. In the thirty-third C site, C(66) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(53,56) atom. The C(66)-N(14) bond length is 1.39 Å. The C(66)-H(53,56) bond length is 0.95 Å. In the thirty-fourth C site, C(70) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(53,56) atom. The C(70)-N(14) bond length is 1.39 Å. The C(70)-H(53,56) bond length is 0.95 Å. In the thirty-fifth C site, C(71) is bonded in a distorted bent 120 degrees geometry to one N(15) and one H(57) atom. The C(71)-N(15) bond length is 1.34 Å. The C(71)-H(57) bond length is 0.95 Å. In the thirty-sixth C site, C(75) is bonded in a distorted bent 120 degrees geometry to one N(15) and one H(60) atom. The C(75)-N(15) bond length is 1.32 Å. The C(75)-H(60) bond length is 0.95 Å. In the thirty-seventh C site, C(76) is bonded in a distorted bent 120 degrees geometry to one N(16) and one H(61) atom. The C(76)-N(16) bond length is 1.33 Å. The C(76)-H(61) bond length is 0.95 Å. In the thirty-eighth C site, C(80) is bonded in a distorted bent 120 degrees geometry to one N(16) and one H(64) atom. The C(80)-N(16) bond length is 1.33 Å. The C(80)-H(64) bond length is 0.95 Å. In the thirty-ninth C site, C(81) is bonded in a distorted bent 120 degrees geometry to one N(17) and one H(65,80) atom. The C(81)-N(17) bond length is 1.35 Å. The C(81)-H(65,80) bond length is 0.95 Å. In the fortieth C site, C(85) is bonded in a distorted bent 120 degrees geometry to one N(17) and one H(68) atom. The C(85)-N(17) bond length is 1.34 Å. The C(85)-H(68) bond length is 0.95 Å. In the forty-first C site, C(86) is bonded in a distorted bent 120 degrees geometry to one N(18) and one H(69) atom. The C(86)-N(18) bond length is 1.33 Å. The C(86)-H(69) bond length is 0.95 Å. In the forty-second C site, C(90) is bonded in a distorted bent 120 degrees geometry to one N(18) and one H(72) atom. The C(90)-N(18) bond length is 1.34 Å. The C(90)-H(72) bond length is 0.95 Å. In the forty-third C site, C(91) is bonded in a distorted bent 120 degrees geometry to one N(19) and one H(73) atom. The C(91)-N(19) bond length is 1.36 Å. The C(91)-H(73) bond length is 0.95 Å. In the forty-fourth C site, C(95) is bonded in a distorted bent 120 degrees geometry to one N(19) and one H(76) atom. The C(95)-N(19) bond length is 1.35 Å. The C(95)-H(76) bond length is 0.95 Å. In the forty-fifth C site, C(96) is bonded in a distorted bent 120 degrees geometry to one N(20) and one H(77) atom. The C(96)-N(20) bond length is 1.37 Å. The C(96)-H(77) bond length is 0.95 Å. In the forty-sixth C site, C(100) is bonded in a distorted bent 120 degrees geometry to one N(20) and one H(65,80) atom. The C(100)-N(20) bond length is 1.35 Å. The C(100)-H(65,80) bond length is 0.95 Å. In the forty-seventh C site, C(101) is bonded in a distorted bent 120 degrees geometry to one N(21) and one H(81) atom. The C(101)-N(21) bond length is 1.35 Å. The C(101)-H(81) bond length is 0.95 Å. In the forty-eighth C site, C(105) is bonded in a distorted bent 120 degrees geometry to one N(21) and one H(84) atom. The C(105)-N(21) bond length is 1.34 Å. The C(105)-H(84) bond length is 0.95 Å. In the forty-ninth C site, C(106) is bonded in a distorted bent 120 degrees geometry to one N(22) and one H(85) atom. The C(106)-N(22) bond length is 1.35 Å. The C(106)-H(85) bond length is 0.95 Å. In the fiftieth C site, C(110) is bonded in a distorted bent 120 degrees geometry to one N(22) and one H(88) atom. The C(110)-N(22) bond length is 1.36 Å. The C(110)-H(88) bond length is 0.95 Å. In the fifty-first C site, C(111) is bonded in a distorted bent 120 degrees geometry to one N(23) and one H(89) atom. The C(111)-N(23) bond length is 1.36 Å. The C(111)-H(89) bond length is 0.95 Å. In the fifty-second C site, C(115) is bonded in a distorted bent 120 degrees geometry to one N(23) and one H(92) atom. The C(115)-N(23) bond length is 1.36 Å. The C(115)-H(92) bond length is 0.95 Å. In the fifty-third C site, C(116) is bonded in a distorted bent 120 degrees geometry to one N(24) and one H(93) atom. The C(116)-N(24) bond length is 1.36 Å. The C(116)-H(93) bond length is 0.95 Å. In the fifty-fourth C site, C(120) is bonded in a distorted bent 120 degrees geometry to one N(24) and one H(96) atom. The C(120)-N(24) bond length is 1.33 Å. The C(120)-H(96) bond length is 0.95 Å. In the fifty-fifth C site, C(121) is bonded in a distorted bent 120 degrees geometry to one N(25) and one H(97) atom. The C(121)-N(25) bond length is 1.35 Å. The C(121)-H(97) bond length is 0.95 Å. In the fifty-sixth C site, C(125) is bonded in a distorted bent 120 degrees geometry to one N(25) and one H(100) atom. The C(125)-N(25) bond length is 1.34 Å. The C(125)-H(100) bond length is 0.95 Å. In the fifty-seventh C site, C(126) is bonded in a distorted bent 120 degrees geometry to one N(26) and one H(101) atom. The C(126)-N(26) bond length is 1.34 Å. The C(126)-H(101) bond length is 0.95 Å. In the fifty-eighth C site, C(130) is bonded in a distorted bent 120 degrees geometry to one N(26) and one H(104) atom. The C(130)-N(26) bond length is 1.32 Å. The C(130)-H(104) bond length is 0.95 Å. In the fifty-ninth C site, C(131) is bonded in a distorted bent 120 degrees geometry to one N(27) and one H(105) atom. The C(131)-N(27) bond length is 1.35 Å. The C(131)-H(105) bond length is 0.95 Å. In the sixtieth C site, C(135) is bonded in a distorted bent 120 degrees geometry to one N(27) and one H(108) atom. The C(135)-N(27) bond length is 1.33 Å. The C(135)-H(108) bond length is 0.95 Å. In the sixty-first C site, C(136) is bonded in a distorted bent 120 degrees geometry to one N(28) and one H(109) atom. The C(136)-N(28) bond length is 1.34 Å. The C(136)-H(109) bond length is 0.95 Å. In the sixty-second C site, C(140) is bonded in a distorted bent 120 degrees geometry to one N(28) and one H(112) atom. The C(140)-N(28) bond length is 1.33 Å. The C(140)-H(112) bond length is 0.95 Å. In the sixty-third C site, C(141) is bonded in a distorted bent 120 degrees geometry to one N(29) and one H(113) atom. The C(141)-N(29) bond length is 1.35 Å. The C(141)-H(113) bond length is 0.95 Å. In the sixty-fourth C site, C(142) is bonded in a distorted single-bond geometry to one C(143) and one H(114) atom. The C(142)-C(143) bond length is 1.37 Å. The C(142)-H(114) bond length is 0.95 Å. In the sixty-fifth C site, C(143) is bonded in a trigonal planar geometry to one C(142), one C(144), and one C(148) atom. The C(143)-C(144) bond length is 1.40 Å. The C(143)-C(148) bond length is 1.50 Å. In the sixty-sixth C site, C(144) is bonded in a single-bond geometry to one C(143), one C(145), and one H(115) atom. The C(144)-C(145) bond length is 1.37 Å. The C(144)-H(115) bond length is 0.95 Å. In the sixty-seventh C site, C(145) is bonded in a distorted trigonal planar geometry to one C(144), one N(29), and one H(116) atom. The C(145)-N(29) bond length is 1.35 Å. The C(145)-H(116) bond length is 0.95 Å. In the sixty-eighth C site, C(146) is bonded in a distorted bent 120 degrees geometry to one C(147), one N(30), and one H(117) atom. The C(146)-C(147) bond length is 1.39 Å. The C(146)-N(30) bond length is 1.35 Å. The C(146)-H(117) bond length is 0.95 Å. In the sixty-ninth C site, C(147) is bonded in a distorted single-bond geometry to one C(146), one C(148), and one H(118) atom. The C(147)-C(148) bond length is 1.39 Å. The C(147)-H(118) bond length is 0.95 Å. In the seventieth C site, C(148) is bonded in a trigonal planar geometry to one C(143), one C(147), and one C(149) atom. The C(148)-C(149) bond length is 1.40 Å. In the seventy-first C site, C(149) is bonded in a distorted single-bond geometry to one C(148), one C(150), and one H(119) atom. The C(149)-C(150) bond length is 1.37 Å. The C(149)-H(119) bond length is 0.95 Å. In the seventy-second C site, C(150) is bonded in a distorted trigonal planar geometry to one C(149), one N(30), and one H(120) atom. The C(150)-N(30) bond length is 1.33 Å. The C(150)-H(120) bond length is 0.95 Å. There are thirty inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(8), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ni(7), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ni(2), one C(11), and one C(15) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ni(2), one C(16), and one C(20) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Ni(8), one C(21), and one C(25) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Ni(8), one C(26), and one C(30) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Ni(7), one C(31), and one C(35) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Ni(2), one C(36), and one C(40) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Ni(8), one C(41), and one C(45) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Ni(6), one C(46), and one C(50) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Ni(6), one C(51), and one C(55) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Ni(2), one C(58), and one C(59) atom. In the thirteenth N site, N(13) is bonded in a trigonal planar geometry to one Ni(3), one C(61), and one C(65) atom. In the fourteenth N site, N(14) is bonded in a trigonal planar geometry to one Ni(3), one C(66), and one C(70) atom. In the fifteenth N site, N(15) is bonded in a trigonal planar geometry to one Ni(3), one C(71), and one C(75) atom. In the sixteenth N site, N(16) is bonded in a trigonal planar geometry to one Ni(1), one C(76), and one C(80) atom. In the seventeenth N site, N(17) is bonded in a trigonal planar geometry to one Ni(1), one C(81), and one C(85) atom. In the eighteenth N site, N(18) is bonded in a trigonal planar geometry to one Ni(1), one C(86), and one C(90) atom. In the nineteenth N site, N(19) is bonded in a trigonal planar geometry to one Ni(6), one C(91), and one C(95) atom. In the twentieth N site, N(20) is bonded in a trigonal planar geometry to one Ni(7), one C(100), and one C(96) atom. In the twenty-first N site, N(21) is bonded in a trigonal planar geometry to one Ni(6), one C(101), and one C(105) atom. In the twenty-second N site, N(22) is bonded in a trigonal planar geometry to one Ni(7), one C(106), and one C(110) atom. In the twenty-third N site, N(23) is bonded in a trigonal planar geometry to one Ni(1), one C(111), and one C(115) atom. In the twenty-fourth N site, N(24) is bonded in a trigonal planar geometry to one Ni(3), one C(116), and one C(120) atom. In the twenty-fifth N site, N(25) is bonded in a trigonal planar geometry to one Ni(5), one C(121), and one C(125) atom. In the twenty-sixth N site, N(26) is bonded in a trigonal planar geometry to one Ni(4), one C(126), and one C(130) atom. In the twenty-seventh N site, N(27) is bonded in a trigonal planar geometry to one Ni(4), one C(131), and one C(135) atom. In the twenty-eighth N site, N(28) is bonded in a trigonal planar geometry to one Ni(4), one C(136), and one C(140) atom. In the twenty-ninth N site, N(29) is bonded in a trigonal planar geometry to one Ni(5), one C(141), and one C(145) atom. In the thirtieth N site, N(30) is bonded in a trigonal planar geometry to one Ni(5), one C(146), and one C(150) atom. There are sixty-five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(24) is bonded in a single-bond geometry to one C(30) atom. In the seventeenth H site, H(25) is bonded in a single-bond geometry to one C(31) atom. In the eighteenth H site, H(28) is bonded in a single-bond geometry to one C(35) atom. In the nineteenth H site, H(29) is bonded in a single-bond geometry to one C(36) atom. In the twentieth H site, H(32) is bonded in a single-bond geometry to one C(40) atom. In the twenty-first H site, H(33) is bonded in a single-bond geometry to one C(41) atom. In the twenty-second H site, H(36) is bonded in a single-bond geometry to one C(45) atom. In the twenty-third H site, H(37) is bonded in a single-bond geometry to one C(46) atom. In the twenty-fourth H site, H(40) is bonded in a single-bond geometry to one C(50) atom. In the twenty-fifth H site, H(41) is bonded in a single-bond geometry to one C(51) atom. In the twenty-sixth H site, H(44) is bonded in a single-bond geometry to one C(55) atom. In the twenty-seventh H site, H(46,47) is bonded in a single-bond geometry to one C(58) atom. In the twenty-eighth H site, H(49) is bonded in a single-bond geometry to one C(61) atom. In the twenty-ninth H site, H(52) is bonded in a single-bond geometry to one C(65) atom. In the thirtieth H site, H(53,56) is bonded in a single-bond geometry to one C(66) atom. In the thirty-first H site, H(57) is bonded in a single-bond geometry to one C(71) atom. In the thirty-second H site, H(60) is bonded in a single-bond geometry to one C(75) atom. In the thirty-third H site, H(61) is bonded in a single-bond geometry to one C(76) atom. In the thirty-fourth H site, H(64) is bonded in a single-bond geometry to one C(80) atom. In the thirty-fifth H site, H(65,80) is bonded in a single-bond geometry to one C(81) atom. In the thirty-sixth H site, H(68) is bonded in a single-bond geometry to one C(85) atom. In the thirty-seventh H site, H(69) is bonded in a single-bond geometry to one C(86) atom. In the thirty-eighth H site, H(72) is bonded in a single-bond geometry to one C(90) atom. In the thirty-ninth H site, H(73) is bonded in a single-bond geometry to one C(91) atom. In the fortieth H site, H(76) is bonded in a single-bond geometry to one C(95) atom. In the forty-first H site, H(77) is bonded in a single-bond geometry to one C(96) atom. In the forty-second H site, H(81) is bonded in a single-bond geometry to one C(101) atom. In the forty-third H site, H(84) is bonded in a single-bond geometry to one C(105) atom. In the forty-fourth H site, H(85) is bonded in a single-bond geometry to one C(106) atom. In the forty-fifth H site, H(88) is bonded in a single-bond geometry to one C(110) atom. In the forty-sixth H site, H(89) is bonded in a single-bond geometry to one C(111) atom. In the forty-seventh H site, H(92) is bonded in a single-bond geometry to one C(115) atom. In the forty-eighth H site, H(93) is bonded in a single-bond geometry to one C(116) atom. In the forty-ninth H site, H(96) is bonded in a single-bond geometry to one C(120) atom. In the fiftieth H site, H(97) is bonded in a single-bond geometry to one C(121) atom. In the fifty-first H site, H(100) is bonded in a single-bond geometry to one C(125) atom. In the fifty-second H site, H(101) is bonded in a single-bond geometry to one C(126) atom. In the fifty-third H site, H(104) is bonded in a single-bond geometry to one C(130) atom. In the fifty-fourth H site, H(105) is bonded in a single-bond geometry to one C(131) atom. In the fifty-fifth H site, H(108) is bonded in a single-bond geometry to one C(135) atom. In the fifty-sixth H site, H(109) is bonded in a single-bond geometry to one C(136) atom. In the fifty-seventh H site, H(112) is bonded in a single-bond geometry to one C(140) atom. In the fifty-eighth H site, H(113) is bonded in a single-bond geometry to one C(141) atom. In the fifty-ninth H site, H(114) is bonded in a single-bond geometry to one C(142) atom. In the sixtieth H site, H(115) is bonded in a single-bond geometry to one C(144) atom. In the sixty-first H site, H(116) is bonded in a single-bond geometry to one C(145) atom. In the sixty-second H site, H(117) is bonded in a single-bond geometry to one C(146) atom. In the sixty-third H site, H(118) is bonded in a single-bond geometry to one C(147) atom. In the sixty-fourth H site, H(119) is bonded in a single-bond geometry to one C(149) atom. In the sixty-fifth H site, H(120) is bonded in a single-bond geometry to one C(150) atom. There are forty-four inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one V(12) and one Ni(3) atom. In the second O site, O(2) is bonded in a linear geometry to one V(20) and one Ni(3) atom. In the third O site, O(3) is bonded in a linear geometry to one V(5) and one Ni(6) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one V(3) and one Ni(7) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one V(1) and one Ni(7) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one V(2) and one Ni(5) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one V(6) and one V(7) atom. In the eighth O site, O(8) is bonded in a linear geometry to one V(6) and one Ni(4) atom. In the ninth O site, O(9) is bonded in a linear geometry to one V(14) and one Ni(1) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one V(11) and one V(2) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one V(13) and one V(20) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one V(13) and one V(6) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one V(5) and one V(7) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one V(12) and one V(24) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one V(14) and one V(15) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one V(4) and one V(8) atom. In the seventeenth O site, O(17) is bonded in a bent 150 degrees geometry to one V(2) and one V(4) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one V(10) and one Ni(6) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one V(10) and one V(7) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one V(18) and one Ni(8) atom. In the twenty-first O site, O(21) is bonded in a bent 150 degrees geometry to one V(17) and one V(23) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 150 degrees geometry to one V(9) and one Ni(4) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 120 degrees geometry to one V(1) and one V(13) atom. In the twenty-fourth O site, O(24) is bonded in a linear geometry to one V(5) and one V(8) atom. In the twenty-fifth O site, O(25) is bonded in a bent 150 degrees geometry to one V(15) and one V(9) atom. In the twenty-sixth O site, O(26) is bonded in a bent 150 degrees geometry to one V(18) and one V(9) atom. In the twenty-seventh O site, O(27) is bonded in a bent 150 degrees geometry to one V(19) and one Ni(5) atom. In the twenty-eighth O site, O(28) is bonded in a bent 150 degrees geometry to one V(19) and one V(21) atom. In the twenty-ninth O site, O(29) is bonded in a bent 150 degrees geometry to one V(10) and one V(4) atom. In the thirtieth O site, O(30) is bonded in a bent 150 degrees geometry to one V(15) and one V(22) atom. In the thirty-first O site, O(31) is bonded in a bent 150 degrees geometry to one V(1) and one V(11) atom. In the thirty-second O site, O(32) is bonded in a bent 150 degrees geometry to one V(8) and one Ni(1) atom. In the thirty-third O site, O(33) is bonded in a bent 120 degrees geometry to one V(16) and one V(18) atom. In the thirty-fourth O site, O(34) is bonded in a bent 120 degrees geometry to one V(11) and one V(3) atom. In the thirty-fifth O site, O(35) is bonded in a linear geometry to one V(20) and one V(3) atom. In the thirty-sixth O site, O(36) is bonded in a bent 150 degrees geometry to one V(21) and one Ni(2) atom. In the thirty-seventh O site, O(37) is bonded in a bent 120 degrees geometry to one V(17) and one V(21) atom. In the thirty-eighth O site, O(38) is bonded in a bent 150 degrees geometry to one V(19) and one V(24) atom. In the thirty-ninth O site, O(39) is bonded in a bent 150 degrees geometry to one V(23) and one Ni(8) atom. In the fortieth O site, O(40) is bonded in a bent 150 degrees geometry to one V(14) and one V(16) atom. In the forty-first O site, O(41) is bonded in a bent 150 degrees geometry to one V(16) and one V(22) atom. In the forty-second O site, O(42) is bonded in a bent 150 degrees geometry to one V(12) and one V(17) atom. In the forty-third O site, O(43) is bonded in a bent 150 degrees geometry to one V(23) and one V(24) atom. In the forty-fourth O site, O(44) is bonded in a linear geometry to one V(22) and one Ni(2) atom. Linkers: 9 c1cc(-c2ccncc2)ccn1. Metal clusters: 24 [V] ,8 [Ni]. The MOF has largest included sphere 5.20 A, density 1.46 g/cm3, surface area 3871.87 m2/g, accessible volume 0.23 cm3/g