Cd2C13H10(N3O2)2C7H6(CH2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; four 2,4-dimethyl-1,4-pentadiene molecules; and four Cd2C13H10(N3O2)2 clusters. In each Cd2C13H10(N3O2)2 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted T-shaped geometry to one N(1), one N(4), and one O(4) atom. The Cd(1)-N(1) bond length is 2.48 Å. The Cd(1)-N(4) bond length is 2.35 Å. The Cd(1)-O(4) bond length is 2.38 Å. In the second Cd site, Cd(2) is bonded in a distorted pentagonal pyramidal geometry to one N(2), one N(5), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(2)-N(2) bond length is 2.35 Å. The Cd(2)-N(5) bond length is 2.33 Å. The Cd(2)-O(1) bond length is 2.32 Å. The Cd(2)-O(2) bond length is 2.47 Å. The Cd(2)-O(3) bond length is 2.31 Å. The Cd(2)-O(4) bond length is 2.47 Å. There are thirteen inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-H(4) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(3) atom. The C(5)-C(6) bond length is 1.38 Å. The C(5)-N(3) bond length is 1.45 Å. In the third C site, C(6) is bonded in a single-bond geometry to one C(5) and one H(5) atom. The C(6)-H(5) bond length is 0.93 Å. In the fourth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(8) bond length is 0.93 Å. In the fifth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(6) atom. The C(11)-C(12) bond length is 1.37 Å. The C(11)-N(6) bond length is 1.44 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(9) atom. The C(12)-H(9) bond length is 0.93 Å. In the seventh C site, C(14) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(11) atom. The C(14)-N(1) bond length is 1.30 Å. The C(14)-N(3) bond length is 1.36 Å. The C(14)-H(11) bond length is 0.93 Å. In the eighth C site, C(15) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(12) atom. The C(15)-N(2) bond length is 1.30 Å. The C(15)-N(3) bond length is 1.36 Å. The C(15)-H(12) bond length is 0.93 Å. In the ninth C site, C(16) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(13) atom. The C(16)-N(4) bond length is 1.31 Å. The C(16)-N(6) bond length is 1.36 Å. The C(16)-H(13) bond length is 0.93 Å. In the tenth C site, C(17) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(14) atom. The C(17)-N(5) bond length is 1.31 Å. The C(17)-N(6) bond length is 1.36 Å. The C(17)-H(14) bond length is 0.93 Å. In the eleventh C site, C(18) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(18)-O(1) bond length is 1.25 Å. The C(18)-O(2) bond length is 1.24 Å. In the twelfth C site, C(21) is bonded in a water-like geometry to one C(22) and two equivalent H(19,20) atoms. The C(21)-C(22) bond length is 1.52 Å. Both C(21)-H(19,20) bond lengths are 0.97 Å. In the thirteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one O(3), and one O(4) atom. The C(22)-O(3) bond length is 1.25 Å. The C(22)-O(4) bond length is 1.26 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(14), and one N(2) atom. The N(1)-N(2) bond length is 1.37 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(15), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(5) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(16), and one N(5) atom. The N(4)-N(5) bond length is 1.39 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(17), and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(11), one C(16), and one C(17) atom. There are nine inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(19,20) is bonded in a single-bond geometry to one C(21) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(18) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(2) and one C(18) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(22) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(22) atom. Linkers: 4 c1cc(-n2cnnc2)ccc1Cc1ccc(-n2cnnc2)cc1 ,4 [O]C(=O)CCCC([O])=O. Metal clusters: 4 [C]1O[Cd]2N=N[Cd]3(N=N2)(O1)O[C]O3. The MOF has largest included sphere 6.77 A, density 1.16 g/cm3, surface area 4044.44 m2/g, accessible volume 0.48 cm3/g