Cu2C23H16(NO)6 crystallizes in the triclinic P1 space group. There are six inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to one N(4), one N(5), one O(4), and one O(5) atom. The Cu(1)-N(4) bond length is 1.91 Å. The Cu(1)-N(5) bond length is 1.96 Å. The Cu(1)-O(4) bond length is 1.99 Å. The Cu(1)-O(5) bond length is 1.95 Å. In the second Cu site, Cu(2) is bonded in a rectangular see-saw-like geometry to one N(13), one N(15), one O(14), and one O(15) atom. The Cu(2)-N(13) bond length is 1.99 Å. The Cu(2)-N(15) bond length is 1.92 Å. The Cu(2)-O(14) bond length is 1.97 Å. The Cu(2)-O(15) bond length is 2.00 Å. In the third Cu site, Cu(3) is bonded in a rectangular see-saw-like geometry to one N(16), one N(17), one O(16), and one O(17) atom. The Cu(3)-N(16) bond length is 1.89 Å. The Cu(3)-N(17) bond length is 1.95 Å. The Cu(3)-O(16) bond length is 1.98 Å. The Cu(3)-O(17) bond length is 1.93 Å. In the fourth Cu site, Cu(4) is bonded in a rectangular see-saw-like geometry to one N(2), one N(3), one O(2), and one O(3) atom. The Cu(4)-N(2) bond length is 1.96 Å. The Cu(4)-N(3) bond length is 1.91 Å. The Cu(4)-O(2) bond length is 1.95 Å. The Cu(4)-O(3) bond length is 2.02 Å. In the fifth Cu site, Cu(5) is bonded in a square pyramidal geometry to one N(10), one N(11), one O(10), one O(11), and one O(13) atom. The Cu(5)-N(10) bond length is 1.91 Å. The Cu(5)-N(11) bond length is 1.97 Å. The Cu(5)-O(10) bond length is 2.00 Å. The Cu(5)-O(11) bond length is 1.96 Å. The Cu(5)-O(13) bond length is 2.36 Å. In the sixth Cu site, Cu(6) is bonded in a square pyramidal geometry to one N(8), one N(9), one O(6), one O(8), and one O(9) atom. The Cu(6)-N(8) bond length is 1.98 Å. The Cu(6)-N(9) bond length is 1.92 Å. The Cu(6)-O(6) bond length is 2.37 Å. The Cu(6)-O(8) bond length is 1.98 Å. The Cu(6)-O(9) bond length is 1.97 Å. There are sixty-nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.23 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a 2-coordinate geometry to one C(67), one N(3), and one H(7) atom. The C(2)-C(67) bond length is 1.48 Å. The C(2)-N(3) bond length is 1.46 Å. The C(2)-H(7) bond length is 1.00 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(3) and one O(4) atom. The C(3)-N(3) bond length is 1.27 Å. The C(3)-O(4) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a 2-coordinate geometry to one N(4) and one O(3) atom. The C(4)-N(4) bond length is 1.29 Å. The C(4)-O(3) bond length is 1.29 Å. In the fifth C site, C(5) is bonded in a 2-coordinate geometry to one C(7), one N(4), and one H(8) atom. The C(5)-C(7) bond length is 1.55 Å. The C(5)-N(4) bond length is 1.46 Å. The C(5)-H(8) bond length is 1.00 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(6)-O(5) bond length is 1.29 Å. The C(6)-O(6) bond length is 1.25 Å. In the seventh C site, C(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(9); one H(10); and two equivalent H(9,11) atoms. The C(8)-C(9) bond length is 1.53 Å. The C(8)-H(10) bond length is 0.98 Å. Both C(8)-H(9,11) bond lengths are 0.98 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(1) atom. The C(9)-C(10) bond length is 1.36 Å. The C(9)-N(1) bond length is 1.34 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(34), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(34) bond length is 1.48 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(2) atom. The C(11)-C(12) bond length is 1.51 Å. The C(11)-N(2) bond length is 1.32 Å. In the twelfth C site, C(12) is bonded in a trigonal non-coplanar geometry to one C(11) and three equivalent H(12,13,14) atoms. All C(12)-H(12,13,14) bond lengths are 0.98 Å. In the thirteenth C site, C(13) is bonded in a trigonal non-coplanar geometry to one C(14) and three equivalent H(15,16,17) atoms. The C(13)-C(14) bond length is 1.52 Å. All C(13)-H(15,16,17) bond lengths are 0.98 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one N(5) atom. The C(14)-C(15) bond length is 1.42 Å. The C(14)-N(5) bond length is 1.33 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(63) atom. The C(15)-C(16) bond length is 1.37 Å. The C(15)-C(63) bond length is 1.47 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one N(6) atom. The C(16)-C(17) bond length is 1.50 Å. The C(16)-N(6) bond length is 1.35 Å. In the seventeenth C site, C(17) is bonded in a trigonal non-coplanar geometry to one C(16) and three equivalent H(18,19,20) atoms. All C(17)-H(18,19,20) bond lengths are 0.98 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(18)-O(7) bond length is 1.27 Å. The C(18)-O(8) bond length is 1.28 Å. In the nineteenth C site, C(19) is bonded in a 2-coordinate geometry to one C(20), one N(9), and one H(21) atom. The C(19)-C(20) bond length is 1.55 Å. The C(19)-N(9) bond length is 1.43 Å. The C(19)-H(21) bond length is 1.00 Å. In the twentieth C site, C(20) is bonded in a bent 120 degrees geometry to one C(19) and one C(21) atom. The C(20)-C(21) bond length is 1.50 Å. In the twenty-first C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one C(20), one C(22), and one C(23) atom. The C(21)-C(22) bond length is 1.53 Å. The C(21)-C(23) bond length is 1.34 Å. In the twenty-second C site, C(22) is bonded in a single-bond geometry to one C(21) atom. In the twenty-third C site, C(23) is bonded in a single-bond geometry to one C(21) atom. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(9) and one O(10) atom. The C(24)-N(9) bond length is 1.27 Å. The C(24)-O(10) bond length is 1.27 Å. In the twenty-fifth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(10) and one O(9) atom. The C(25)-N(10) bond length is 1.29 Å. The C(25)-O(9) bond length is 1.26 Å. In the twenty-sixth C site, C(26) is bonded in a 2-coordinate geometry to one C(27), one N(10), and one H(22) atom. The C(26)-C(27) bond length is 1.53 Å. The C(26)-N(10) bond length is 1.47 Å. The C(26)-H(22) bond length is 1.00 Å. In the twenty-seventh C site, C(27) is bonded in a bent 120 degrees geometry to one C(26) and one C(28) atom. The C(27)-C(28) bond length is 1.47 Å. In the twenty-eighth C site, C(28) is bonded in a trigonal non-coplanar geometry to one C(27), one C(29), and one C(30) atom. The C(28)-C(29) bond length is 1.56 Å. The C(28)-C(30) bond length is 1.57 Å. In the twenty-ninth C site, C(29) is bonded in a single-bond geometry to one C(28) atom. In the thirtieth C site, C(30) is bonded in a single-bond geometry to one C(28) atom. In the thirty-first C site, C(31) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. The C(31)-O(11) bond length is 1.29 Å. The C(31)-O(12) bond length is 1.26 Å. In the thirty-second C site, C(32) is bonded in a trigonal non-coplanar geometry to one C(33) and three equivalent H(23,24,25) atoms. The C(32)-C(33) bond length is 1.47 Å. All C(32)-H(23,24,25) bond lengths are 0.98 Å. In the thirty-third C site, C(33) is bonded in a distorted trigonal planar geometry to one C(32), one C(34), and one N(11) atom. The C(33)-C(34) bond length is 1.43 Å. The C(33)-N(11) bond length is 1.35 Å. In the thirty-fourth C site, C(34) is bonded in a trigonal planar geometry to one C(10), one C(33), and one C(35) atom. The C(34)-C(35) bond length is 1.38 Å. In the thirty-fifth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(34), one C(36), and one N(12) atom. The C(35)-C(36) bond length is 1.50 Å. The C(35)-N(12) bond length is 1.33 Å. In the thirty-sixth C site, C(36) is bonded in a trigonal non-coplanar geometry to one C(35); one H(27); and two equivalent H(26,28) atoms. The C(36)-H(27) bond length is 0.98 Å. Both C(36)-H(26,28) bond lengths are 0.98 Å. In the thirty-seventh C site, C(37) is bonded in a trigonal non-coplanar geometry to one C(38), one H(29), one H(30), and one H(31) atom. The C(37)-C(38) bond length is 1.48 Å. The C(37)-H(29) bond length is 0.98 Å. The C(37)-H(30) bond length is 0.99 Å. The C(37)-H(31) bond length is 0.97 Å. In the thirty-eighth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(37), one C(39), and one N(7) atom. The C(38)-C(39) bond length is 1.38 Å. The C(38)-N(7) bond length is 1.36 Å. In the thirty-ninth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(58) atom. The C(39)-C(40) bond length is 1.38 Å. The C(39)-C(58) bond length is 1.50 Å. In the fortieth C site, C(40) is bonded in a distorted single-bond geometry to one C(39), one C(41), and one N(8) atom. The C(40)-C(41) bond length is 1.51 Å. The C(40)-N(8) bond length is 1.32 Å. In the forty-first C site, C(41) is bonded in a trigonal non-coplanar geometry to one C(40); one H(33); and two equivalent H(32,34) atoms. The C(41)-H(33) bond length is 0.98 Å. Both C(41)-H(32,34) bond lengths are 0.98 Å. In the forty-second C site, C(42) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(14) atom. The C(42)-O(13) bond length is 1.22 Å. The C(42)-O(14) bond length is 1.28 Å. In the forty-third C site, C(43) is bonded in a 2-coordinate geometry to one C(44), one N(15), and one H(35) atom. The C(43)-C(44) bond length is 1.56 Å. The C(43)-N(15) bond length is 1.43 Å. The C(43)-H(35) bond length is 1.00 Å. In the forty-fourth C site, C(44) is bonded in a bent 120 degrees geometry to one C(43) and one C(45) atom. The C(44)-C(45) bond length is 1.27 Å. In the forty-fifth C site, C(45) is bonded in a trigonal planar geometry to one C(44), one C(46), and one C(47) atom. The C(45)-C(46) bond length is 1.55 Å. The C(45)-C(47) bond length is 1.49 Å. In the forty-sixth C site, C(46) is bonded in a single-bond geometry to one C(45) atom. In the forty-seventh C site, C(47) is bonded in a single-bond geometry to one C(45) atom. In the forty-eighth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one N(15) and one O(16) atom. The C(48)-N(15) bond length is 1.30 Å. The C(48)-O(16) bond length is 1.27 Å. In the forty-ninth C site, C(49) is bonded in a 2-coordinate geometry to one N(16) and one O(15) atom. The C(49)-N(16) bond length is 1.34 Å. The C(49)-O(15) bond length is 1.22 Å. In the fiftieth C site, C(50) is bonded in a 2-coordinate geometry to one C(52), one N(16), and one H(36) atom. The C(50)-C(52) bond length is 1.50 Å. The C(50)-N(16) bond length is 1.46 Å. The C(50)-H(36) bond length is 1.00 Å. In the fifty-first C site, C(51) is bonded in a distorted bent 120 degrees geometry to one O(17) and one O(18) atom. The C(51)-O(17) bond length is 1.24 Å. The C(51)-O(18) bond length is 1.23 Å. In the fifty-second C site, C(52) is bonded in a bent 120 degrees geometry to one C(50) and one C(53) atom. The C(52)-C(53) bond length is 1.48 Å. In the fifty-third C site, C(53) is bonded in a trigonal non-coplanar geometry to one C(52), one C(54), and one C(55) atom. The C(53)-C(54) bond length is 1.47 Å. The C(53)-C(55) bond length is 1.51 Å. In the fifty-fourth C site, C(54) is bonded in a single-bond geometry to one C(53) atom. In the fifty-fifth C site, C(55) is bonded in a single-bond geometry to one C(53) atom. In the fifty-sixth C site, C(56) is bonded in a trigonal non-coplanar geometry to one C(57) and three equivalent H(37,38,39) atoms. The C(56)-C(57) bond length is 1.52 Å. All C(56)-H(37,38,39) bond lengths are 0.98 Å. In the fifty-seventh C site, C(57) is bonded in a distorted trigonal planar geometry to one C(56), one C(58), and one N(17) atom. The C(57)-C(58) bond length is 1.39 Å. The C(57)-N(17) bond length is 1.35 Å. In the fifty-eighth C site, C(58) is bonded in a trigonal planar geometry to one C(39), one C(57), and one C(59) atom. The C(58)-C(59) bond length is 1.35 Å. In the fifty-ninth C site, C(59) is bonded in a distorted trigonal planar geometry to one C(58), one C(60), and one N(18) atom. The C(59)-C(60) bond length is 1.50 Å. The C(59)-N(18) bond length is 1.33 Å. In the sixtieth C site, C(60) is bonded in a trigonal non-coplanar geometry to one C(59), one H(40), one H(41), and one H(42) atom. The C(60)-H(40) bond length is 0.98 Å. The C(60)-H(41) bond length is 0.98 Å. The C(60)-H(42) bond length is 0.98 Å. In the sixty-first C site, C(61) is bonded in a trigonal non-coplanar geometry to one C(62); one H(44); and two equivalent H(43,45) atoms. The C(61)-C(62) bond length is 1.52 Å. The C(61)-H(44) bond length is 0.98 Å. Both C(61)-H(43,45) bond lengths are 0.98 Å. In the sixty-second C site, C(62) is bonded in a distorted trigonal planar geometry to one C(61), one C(63), and one N(14) atom. The C(62)-C(63) bond length is 1.38 Å. The C(62)-N(14) bond length is 1.31 Å. In the sixty-third C site, C(63) is bonded in a trigonal planar geometry to one C(15), one C(62), and one C(64) atom. The C(63)-C(64) bond length is 1.37 Å. In the sixty-fourth C site, C(64) is bonded in a distorted trigonal planar geometry to one C(63), one C(65), and one N(13) atom. The C(64)-C(65) bond length is 1.52 Å. The C(64)-N(13) bond length is 1.31 Å. In the sixty-fifth C site, C(65) is bonded in a trigonal non-coplanar geometry to one C(64) and three equivalent H(46,47,48) atoms. All C(65)-H(46,47,48) bond lengths are 0.98 Å. In the sixty-sixth C site, C(66) is bonded in a trigonal non-coplanar geometry to one C(67), one C(68), and one C(69) atom. The C(66)-C(67) bond length is 1.54 Å. The C(66)-C(68) bond length is 1.56 Å. The C(66)-C(69) bond length is 1.53 Å. In the sixty-seventh C site, C(67) is bonded in a water-like geometry to one C(2) and one C(66) atom. In the sixty-eighth C site, C(68) is bonded in a single-bond geometry to one C(66) atom. In the sixty-ninth C site, C(69) is bonded in a single-bond geometry to one C(66) atom. There are eighteen inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one C(9), one N(2), and one H(1) atom. The N(1)-N(2) bond length is 1.38 Å. The N(1)-H(1) bond length is 0.88 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Cu(4), one C(11), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(4), one C(2), and one C(3) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(4), and one C(5) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(14), and one N(6) atom. The N(5)-N(6) bond length is 1.35 Å. In the sixth N site, N(6) is bonded in a 1-coordinate geometry to one C(16), one N(5), and one H(2) atom. The N(6)-H(2) bond length is 0.88 Å. In the seventh N site, N(7) is bonded in a 3-coordinate geometry to one C(38), one N(8), and one H(3) atom. The N(7)-N(8) bond length is 1.34 Å. The N(7)-H(3) bond length is 0.88 Å. In the eighth N site, N(8) is bonded in a 3-coordinate geometry to one Cu(6), one C(40), and one N(7) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Cu(6), one C(19), and one C(24) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Cu(5), one C(25), and one C(26) atom. In the eleventh N site, N(11) is bonded in a 3-coordinate geometry to one Cu(5), one C(33), and one N(12) atom. The N(11)-N(12) bond length is 1.37 Å. In the twelfth N site, N(12) is bonded in a 3-coordinate geometry to one C(35), one N(11), and one H(4) atom. The N(12)-H(4) bond length is 0.88 Å. In the thirteenth N site, N(13) is bonded in a 3-coordinate geometry to one Cu(2), one C(64), and one N(14) atom. The N(13)-N(14) bond length is 1.35 Å. In the fourteenth N site, N(14) is bonded in a 1-coordinate geometry to one C(62), one N(13), and one H(5) atom. The N(14)-H(5) bond length is 0.88 Å. In the fifteenth N site, N(15) is bonded in a trigonal planar geometry to one Cu(2), one C(43), and one C(48) atom. In the sixteenth N site, N(16) is bonded in a trigonal planar geometry to one Cu(3), one C(49), and one C(50) atom. In the seventeenth N site, N(17) is bonded in a 3-coordinate geometry to one Cu(3), one C(57), and one N(18) atom. The N(17)-N(18) bond length is 1.32 Å. In the eighteenth N site, N(18) is bonded in a 3-coordinate geometry to one C(59), one N(17), and one H(6) atom. The N(18)-H(6) bond length is 0.88 Å. There are thirty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(12) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(14) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(18) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9,11) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(12,13,14) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(15,16,17) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(18,19,20) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(23,24,25) is bonded in a single-bond geometry to one C(32) atom. In the seventeenth H site, H(26,28) is bonded in a single-bond geometry to one C(36) atom. In the eighteenth H site, H(27) is bonded in a single-bond geometry to one C(36) atom. In the nineteenth H site, H(29) is bonded in a single-bond geometry to one C(37) atom. In the twentieth H site, H(30) is bonded in a single-bond geometry to one C(37) atom. In the twenty-first H site, H(31) is bonded in a single-bond geometry to one C(37) atom. In the twenty-second H site, H(32,34) is bonded in a single-bond geometry to one C(41) atom. In the twenty-third H site, H(33) is bonded in a single-bond geometry to one C(41) atom. In the twenty-fourth H site, H(35) is bonded in a single-bond geometry to one C(43) atom. In the twenty-fifth H site, H(36) is bonded in a single-bond geometry to one C(50) atom. In the twenty-sixth H site, H(37,38,39) is bonded in a single-bond geometry to one C(56) atom. In the twenty-seventh H site, H(40) is bonded in a single-bond geometry to one C(60) atom. In the twenty-eighth H site, H(41) is bonded in a single-bond geometry to one C(60) atom. In the twenty-ninth H site, H(42) is bonded in a single-bond geometry to one C(60) atom. In the thirtieth H site, H(43,45) is bonded in a single-bond geometry to one C(61) atom. In the thirty-first H site, H(44) is bonded in a single-bond geometry to one C(61) atom. In the thirty-second H site, H(46,47,48) is bonded in a single-bond geometry to one C(65) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cu(4) and one C(4) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Cu(1) and one C(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(6) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(6) and one C(6) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(18) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(6) and one C(18) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Cu(6) and one C(25) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Cu(5) and one C(24) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Cu(5) and one C(31) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one C(31) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Cu(5) and one C(42) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(42) atom. In the fifteenth O site, O(15) is bonded in a water-like geometry to one Cu(2) and one C(49) atom. In the sixteenth O site, O(16) is bonded in a water-like geometry to one Cu(3) and one C(48) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(51) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one C(51) atom. Linkers: 3 Cc1n[nH]c(C)c1-c1c(C)n[nH]c1C ,1 [C][C]([C])[C][C@@H]([N]C(=O)C(=O)[N][C@H]([C][C]([C])[C])C([O])=O)C([O])=O ,1 [C][C]([C])[C][C@@H]([N]C(=O)C(=O)[N][C@H]([C])C([O])=O)C([O])=O. Metal clusters: 6 [Cu]. The MOF has largest included sphere 6.71 A, density 1.19 g/cm3, surface area 4639.83 m2/g, accessible volume 0.42 cm3/g