Zn2C38H28O13 crystallizes in the orthorhombic Imma space group. The structure consists of a Zn2C38H28O13 framework. Zn(1) is bonded in a 7-coordinate geometry to one O(4), two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms. The Zn(1)-O(4) bond length is 1.92 Å. Both Zn(1)-O(1) bond lengths are 1.99 Å. Both Zn(1)-O(2) bond lengths are 2.01 Å. Both Zn(1)-O(3) bond lengths are 2.41 Å. There are seventeen inequivalent C sites. In the first C site, C(4) is bonded to one C(17), one C(5), and two equivalent C(1) atoms to form corner-sharing CC4 tetrahedra. The C(4)-C(17) bond length is 1.54 Å. The C(4)-C(5) bond length is 1.54 Å. Both C(4)-C(1) bond lengths are 1.52 Å. In the second C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(6) atom. The C(5)-C(10) bond length is 1.34 Å. The C(5)-C(6) bond length is 1.35 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(6) atom. The C(6)-C(7) bond length is 1.35 Å. The C(6)-H(6) bond length is 0.99 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(7) atom. The C(7)-C(8) bond length is 1.34 Å. The C(7)-H(7) bond length is 0.96 Å. In the fifth C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(7), and one C(9) atom. The C(8)-C(11) bond length is 1.57 Å. The C(8)-C(9) bond length is 1.34 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(9)-H(8) bond length is 1.02 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(5) and one H(9) atom. The C(10)-H(9) bond length is 0.99 Å. In the eighth C site, C(11) is bonded in a 4-coordinate geometry to one C(8), two equivalent O(2), and two equivalent O(3) atoms. Both C(11)-O(2) bond lengths are 1.24 Å. Both C(11)-O(3) bond lengths are 1.25 Å. In the ninth C site, C(12) is bonded to one C(13), one C(16), and two equivalent C(1) atoms to form corner-sharing CC4 tetrahedra. The C(12)-C(13) bond length is 1.50 Å. The C(12)-C(16) bond length is 1.53 Å. Both C(12)-C(1) bond lengths are 1.53 Å. In the tenth C site, C(13) is bonded in a trigonal planar geometry to one C(12) and two equivalent C(2) atoms. Both C(13)-C(2) bond lengths are 1.35 Å. In the eleventh C site, C(14) is bonded in a trigonal planar geometry to one C(15) and two equivalent C(3) atoms. The C(14)-C(15) bond length is 1.48 Å. Both C(14)-C(3) bond lengths are 1.35 Å. In the twelfth C site, C(15) is bonded in a bent 120 degrees geometry to one C(14) and two equivalent O(1) atoms. Both C(15)-O(1) bond lengths are 1.23 Å. In the thirteenth C site, C(16) is bonded in a water-like geometry to two equivalent C(12) and two equivalent H(5) atoms. Both C(16)-H(5) bond lengths are 0.98 Å. In the fourteenth C site, C(17) is bonded in a water-like geometry to two equivalent C(4) and two equivalent H(10) atoms. Both C(17)-H(10) bond lengths are 1.01 Å. In the fifteenth C site, C(1) is bonded in a water-like geometry to one C(12), one C(4), one H(1), and one H(2) atom. The C(1)-H(1) bond length is 0.99 Å. The C(1)-H(2) bond length is 0.99 Å. In the sixteenth C site, C(2) is bonded in a distorted single-bond geometry to one C(13), one C(3), and one H(3) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-H(3) bond length is 0.98 Å. In the seventeenth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(14), one C(2), and one H(4) atom. The C(3)-H(4) bond length is 1.00 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(15) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Zn(1), one C(11), and one O(2) atom. The O(2)-O(2) bond length is 0.93 Å. In the third O site, O(3) is bonded in a single-bond geometry to one Zn(1) and one C(11) atom. In the fourth O site, O(4) is bonded in a water-like geometry to two equivalent Zn(1) atoms. Linkers: 1 [C]OO[O].[C]O[O].[O].[O].[O].[O]C(=O)c1ccc([C@]23C[C@]4(c5cc[c]cc5)C[C@](c5cc[c]cc5)(C2)C[C@@](c2ccc(C([O])=O)cc2)(C4)C3)cc1 ,3 [C]OO[O].[C]OO[O].[O].[O].[O]C(=O)c1ccc([C@]23C[C@]4(c5cc[c]cc5)C[C@](c5cc[c]cc5)(C2)C[C@@](c2ccc(C([O])=O)cc2)(C4)C3)cc1. Metal clusters: 4 [C]1O[Zn]2O[C]O[Zn](O1)O2.[O]OO[O].[O]OO[O]. The MOF has largest included sphere 9.44 A, density 0.78 g/cm3, surface area 4074.14 m2/g, accessible volume 0.73 cm3/g