CuC14NH5O4(CH)3 is Indium-derived structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of one hundred and forty-four 02329_fluka molecules and four CuC14NH5O4 clusters. In each CuC14NH5O4 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(4), one O(5), and one O(8) atom. The Cu(1)-O(2) bond length is 1.88 Å. The Cu(1)-O(4) bond length is 1.94 Å. The Cu(1)-O(5) bond length is 1.94 Å. The Cu(1)-O(8) bond length is 1.92 Å. In the second Cu site, Cu(2) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(3), one O(6), and one O(7) atom. The Cu(2)-O(1) bond length is 1.96 Å. The Cu(2)-O(3) bond length is 1.95 Å. The Cu(2)-O(6) bond length is 1.93 Å. The Cu(2)-O(7) bond length is 1.99 Å. There are twenty-eight inequivalent C sites. In the first C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(11) bond length is 1.43 Å. The C(12)-C(13) bond length is 1.41 Å. The C(12)-C(14) bond length is 1.50 Å. In the second C site, C(6) is bonded in a single-bond geometry to one C(7) and one N(1) atom. The C(6)-C(7) bond length is 1.37 Å. The C(6)-N(1) bond length is 1.32 Å. In the third C site, C(8) is bonded in a distorted trigonal planar geometry to one C(13), one C(7), and one C(9) atom. The C(8)-C(13) bond length is 1.38 Å. The C(8)-C(7) bond length is 1.38 Å. The C(8)-C(9) bond length is 1.52 Å. In the fourth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one N(1) atom. The C(9)-N(1) bond length is 1.47 Å. In the fifth C site, C(1) is bonded in a bent 120 degrees geometry to one C(3), one O(1), and one O(2) atom. The C(1)-C(3) bond length is 1.40 Å. The C(1)-O(1) bond length is 1.34 Å. The C(1)-O(2) bond length is 1.34 Å. In the sixth C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(4) atom. The C(3)-C(2) bond length is 1.44 Å. The C(3)-C(4) bond length is 1.46 Å. In the seventh C site, C(2) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(1) atom. The C(2)-C(7) bond length is 1.28 Å. The C(2)-H(1) bond length is 0.95 Å. In the eighth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(4)-H(2) bond length is 0.95 Å. In the ninth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one C(8) atom. In the tenth C site, C(15) is bonded in a distorted single-bond geometry to one N(1) atom. The C(15)-N(1) bond length is 1.29 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(8) atom. The C(17)-C(18) bond length is 1.24 Å. The C(17)-H(8) bond length is 0.95 Å. In the twelfth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one N(2) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-N(2) bond length is 1.48 Å. In the thirteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(9) atom. The C(19)-H(9) bond length is 0.95 Å. In the fourteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(6) atom. The C(13)-H(6) bond length is 0.95 Å. In the fifteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one C(26), and one C(29) atom. The C(21)-C(22) bond length is 1.37 Å. The C(21)-C(26) bond length is 1.38 Å. The C(21)-C(29) bond length is 1.34 Å. In the sixteenth C site, C(22) is bonded in a single-bond geometry to one C(21) and one N(2) atom. The C(22)-N(2) bond length is 1.27 Å. In the seventeenth C site, C(14) is bonded in a bent 120 degrees geometry to one C(12), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.27 Å. The C(14)-O(4) bond length is 1.27 Å. In the eighteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(12) atom. The C(24)-C(25) bond length is 1.45 Å. The C(24)-H(12) bond length is 0.95 Å. In the nineteenth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(27) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-C(27) bond length is 1.53 Å. In the twentieth C site, C(26) is bonded in a distorted single-bond geometry to one C(21), one C(25), and one H(13) atom. The C(26)-H(13) bond length is 0.95 Å. In the twenty-first C site, C(27) is bonded in a bent 120 degrees geometry to one C(25), one O(5), and one O(6) atom. The C(27)-O(5) bond length is 1.29 Å. The C(27)-O(6) bond length is 1.23 Å. In the twenty-second C site, C(28) is bonded in a distorted single-bond geometry to one C(29), one C(33), and one H(14) atom. The C(28)-C(29) bond length is 1.39 Å. The C(28)-C(33) bond length is 1.35 Å. The C(28)-H(14) bond length is 0.95 Å. In the twenty-third C site, C(29) is bonded in a distorted trigonal planar geometry to one C(21), one C(28), and one C(30) atom. The C(29)-C(30) bond length is 1.50 Å. In the twenty-fourth C site, C(30) is bonded in a single-bond geometry to one C(29) and one N(2) atom. The C(30)-N(2) bond length is 1.34 Å. In the twenty-fifth C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(16) atom. The C(32)-C(33) bond length is 1.46 Å. The C(32)-H(16) bond length is 0.95 Å. In the twenty-sixth C site, C(33) is bonded in a trigonal planar geometry to one C(28), one C(32), and one C(34) atom. The C(33)-C(34) bond length is 1.36 Å. In the twenty-seventh C site, C(34) is bonded in a bent 120 degrees geometry to one C(33), one O(7), and one O(8) atom. The C(34)-O(7) bond length is 1.27 Å. The C(34)-O(8) bond length is 1.34 Å. In the twenty-eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(5) atom. The C(11)-H(5) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(15), one C(6), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(18), one C(22), and one C(30) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(26) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(28) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(32) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cu(2) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cu(2) and one C(14) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(14) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(27) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(27) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cu(2) and one C(34) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(34) atom. Linkers: 24 [O]C(=O)c1ccc2c(c1)c1cc(C([O])=O)ccc1n2-c1ccc(-n2c3ccc(C([O])=O)cc3c3cc(C([O])=O)ccc32)cc1. Metal clusters: 24 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: nbo. The MOF has largest included sphere 16.55 A, density 0.46 g/cm3, surface area 4069.71 m2/g, accessible volume 1.94 cm3/g