CdH10(C11O4)2 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four CdH10(C11O4)2 clusters. Cd(1) is bonded in a 7-coordinate geometry to one O(1), one O(4), one O(5), one O(6), one O(7), and two equivalent O(2) atoms. The Cd(1)-O(1) bond length is 2.42 Å. The Cd(1)-O(4) bond length is 2.26 Å. The Cd(1)-O(5) bond length is 2.33 Å. The Cd(1)-O(6) bond length is 2.15 Å. The Cd(1)-O(7) bond length is 2.63 Å. There is one shorter (2.42 Å) and one longer (2.57 Å) Cd(1)-O(2) bond length. There are twenty-two inequivalent C sites. In the first C site, C(22) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(6) atom. The C(22)-C(10) bond length is 1.39 Å. The C(22)-C(2) bond length is 1.40 Å. The C(22)-C(6) bond length is 1.50 Å. In the second C site, C(21) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(21)-C(7) bond length is 1.37 Å. The C(21)-H(4) bond length is 0.93 Å. In the third C site, C(1) is bonded in a distorted single-bond geometry to one C(16) and one H(1) atom. The C(1)-C(16) bond length is 1.39 Å. The C(1)-H(1) bond length is 0.93 Å. In the fourth C site, C(2) is bonded in a trigonal planar geometry to one C(14), one C(19), and one C(22) atom. The C(2)-C(14) bond length is 1.39 Å. The C(2)-C(19) bond length is 1.50 Å. In the fifth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(3), and one O(6) atom. The C(3)-C(18) bond length is 1.48 Å. The C(3)-O(3) bond length is 1.25 Å. The C(3)-O(6) bond length is 1.26 Å. In the sixth C site, C(4) is bonded in a distorted single-bond geometry to one C(18) and one H(3) atom. The C(4)-C(18) bond length is 1.39 Å. The C(4)-H(3) bond length is 0.93 Å. In the seventh C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(15) atom. The C(5)-C(10) bond length is 1.38 Å. The C(5)-C(13) bond length is 1.49 Å. The C(5)-C(15) bond length is 1.40 Å. In the eighth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(1), and one O(8) atom. The C(6)-O(1) bond length is 1.29 Å. The C(6)-O(8) bond length is 1.24 Å. In the ninth C site, C(7) is bonded in a trigonal planar geometry to one C(15), one C(20), and one C(21) atom. The C(7)-C(15) bond length is 1.50 Å. The C(7)-C(20) bond length is 1.38 Å. In the tenth C site, C(8) is bonded in a distorted single-bond geometry to one C(13) and one H(2,9) atom. The C(8)-C(13) bond length is 1.37 Å. The C(8)-H(2,9) bond length is 0.93 Å. In the eleventh C site, C(9) is bonded in a bent 120 degrees geometry to one C(16), one O(5), and one O(7) atom. The C(9)-C(16) bond length is 1.50 Å. The C(9)-O(5) bond length is 1.27 Å. The C(9)-O(7) bond length is 1.25 Å. In the twelfth C site, C(10) is bonded in a single-bond geometry to one C(22), one C(5), and one H(7) atom. The C(10)-H(7) bond length is 0.93 Å. In the thirteenth C site, C(11) is bonded in a distorted single-bond geometry to one C(18) and one H(6) atom. The C(11)-C(18) bond length is 1.39 Å. The C(11)-H(6) bond length is 0.93 Å. In the fourteenth C site, C(12) is bonded in a distorted single-bond geometry to one C(16) and one H(8) atom. The C(12)-C(16) bond length is 1.37 Å. The C(12)-H(8) bond length is 0.93 Å. In the fifteenth C site, C(13) is bonded in a trigonal planar geometry to one C(17), one C(5), and one C(8) atom. The C(13)-C(17) bond length is 1.38 Å. In the sixteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(15), one C(2), and one H(5) atom. The C(14)-C(15) bond length is 1.38 Å. The C(14)-H(5) bond length is 0.93 Å. In the seventeenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(5), and one C(7) atom. In the eighteenth C site, C(16) is bonded in a trigonal planar geometry to one C(1), one C(12), and one C(9) atom. In the nineteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(13) and one H(2,9) atom. The C(17)-H(2,9) bond length is 0.93 Å. In the twentieth C site, C(18) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(4) atom. In the twenty-first C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(4) atom. The C(19)-O(2) bond length is 1.27 Å. The C(19)-O(4) bond length is 1.26 Å. In the twenty-second C site, C(20) is bonded in a distorted single-bond geometry to one C(7) and one H(10) atom. The C(20)-H(10) bond length is 0.93 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2,9) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(21) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(20) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(6) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(19) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth O site, O(5) is bonded in a water-like geometry to one Cd(1) and one C(9) atom. In the fifth O site, O(6) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(3) atom. In the sixth O site, O(8) is bonded in a single-bond geometry to one C(6) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cd(1) and one C(9) atom. In the eighth O site, O(4) is bonded in a distorted water-like geometry to one Cd(1) and one C(19) atom. Linkers: 4 [O]C(=O)c1ccc(-c2cc(C([O])=O)c(C([O])=O)cc2-c2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 O=[C]O[Cd]1(O[C]=O)(O[C]=O)O[C]O[Cd](O[C]=O)(O[C]=O)(O[C]=O)O[C]O1. The MOF has largest included sphere 6.01 A, density 1.02 g/cm3, surface area 3962.40 m2/g, accessible volume 0.56 cm3/g