Sr2CdC14H6(NO7)2(CH)2 crystallizes in the tetragonal P4_12_12 space group. The structure consists of eight 02329_fluka molecules inside a Sr2CdC14H6(NO7)2 framework. In the Sr2CdC14H6(NO7)2 framework, Sr(1) is bonded in a 7-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(7), and two equivalent O(6) atoms. The Sr(1)-O(2) bond length is 2.64 Å. The Sr(1)-O(3) bond length is 2.68 Å. The Sr(1)-O(4) bond length is 2.51 Å. The Sr(1)-O(5) bond length is 2.70 Å. The Sr(1)-O(7) bond length is 2.69 Å. There is one shorter (2.71 Å) and one longer (2.83 Å) Sr(1)-O(6) bond length. Cd(1) is bonded in a distorted hexagonal bipyramidal geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Both Cd(1)-O(1) bond lengths are 2.36 Å. Both Cd(1)-O(2) bond lengths are 2.36 Å. Both Cd(1)-O(3) bond lengths are 2.30 Å. Both Cd(1)-O(4) bond lengths are 2.62 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(3), one O(1), and one O(2) atom. The C(1)-C(3) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.24 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a bent 120 degrees geometry to one C(7), one O(3), and one O(4) atom. The C(2)-C(7) bond length is 1.50 Å. The C(2)-O(3) bond length is 1.26 Å. The C(2)-O(4) bond length is 1.25 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(8) bond length is 1.38 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(4)-H(1) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(3) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(3) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(8) atom. The C(7)-C(8) bond length is 1.38 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(4) atom. The C(8)-H(4) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one O(5), one O(6), and one O(7) atom. The N(1)-O(5) bond length is 1.25 Å. The N(1)-O(6) bond length is 1.26 Å. The N(1)-O(7) bond length is 1.22 Å. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(8) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Sr(1), one Cd(1), and one C(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Sr(1), one Cd(1), and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Sr(1), one Cd(1), and one C(2) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Sr(1) and one N(1) atom. In the sixth O site, O(6) is bonded in a distorted T-shaped geometry to two equivalent Sr(1) and one N(1) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Sr(1) and one N(1) atom. Linkers: 8 [O]C(=O)c1cccc(C([O])=O)c1. Metal clusters: 8 [Sr] ,4 [Cd]. The MOF has largest included sphere 6.62 A, density 1.22 g/cm3, surface area 3157.85 m2/g, accessible volume 0.46 cm3/g