CuC17H11(NO)2 is Indium-like structured and crystallizes in the orthorhombic Pccn space group. The structure is zero-dimensional and consists of four CuC17H11(NO)2 clusters. Cu(1) is bonded in a see-saw-like geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Cu(1)-N(1) bond length is 2.00 Å. The Cu(1)-N(2) bond length is 2.01 Å. The Cu(1)-O(1) bond length is 2.21 Å. The Cu(1)-O(2) bond length is 1.95 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(7) atom. The C(1)-C(10) bond length is 1.39 Å. The C(1)-C(12) bond length is 1.49 Å. The C(1)-C(7) bond length is 1.39 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(16) atom. The C(2)-C(11) bond length is 1.39 Å. The C(2)-C(14) bond length is 1.38 Å. The C(2)-C(16) bond length is 1.48 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(2) atom. The C(3)-C(6) bond length is 1.51 Å. The C(3)-O(1) bond length is 1.24 Å. The C(3)-O(2) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(12), one C(6), and one H(1) atom. The C(4)-C(12) bond length is 1.40 Å. The C(4)-C(6) bond length is 1.39 Å. The C(4)-H(1) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a single-bond geometry to one C(12), one C(16), and one H(2) atom. The C(5)-C(12) bond length is 1.39 Å. The C(5)-C(16) bond length is 1.40 Å. The C(5)-H(2) bond length is 0.95 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(17), one C(3), and one C(4) atom. The C(6)-C(17) bond length is 1.38 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(1) and one H(3,6) atom. The C(7)-H(3,6) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(4) atom. The C(8)-N(2) bond length is 1.33 Å. The C(8)-H(4) bond length is 0.95 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5,8) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-H(5,8) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(1) and one H(3,6) atom. The C(10)-H(3,6) bond length is 0.95 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(2) and one H(7,9) atom. The C(11)-H(7,9) bond length is 0.95 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(5) atom. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5,8) atom. The C(13)-N(1) bond length is 1.34 Å. The C(13)-H(5,8) bond length is 0.95 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(2) and one H(7,9) atom. The C(14)-H(7,9) bond length is 0.95 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(15)-N(2) bond length is 1.34 Å. The C(15)-H(10) bond length is 0.95 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(17), one C(2), and one C(5) atom. The C(16)-C(17) bond length is 1.40 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(6), and one H(11) atom. The C(17)-H(11) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(15), and one C(8) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3,6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5,8) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7,9) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Cu(1) and one C(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. Linkers: 8 [O]C(=O)c1cc(-c2ccncc2)cc(-c2ccncc2)c1. Metal clusters: 4 [C]1O[Cu]O[C]O[Cu]O1. The MOF has largest included sphere 6.08 A, density 0.89 g/cm3, surface area 4454.11 m2/g, accessible volume 0.66 cm3/g