ZnC18H12(NO2)2(CH)2C3H2C2NH2C4H2O is Indium-derived structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules; eight 2,3-dimethyl-1,3-butadiene molecules; sixteen 2-methoxypropene molecules; sixteen n-methyl methanimine molecules; and sixteen ZnC18H12(NO2)2 clusters. In each ZnC18H12(NO2)2 cluster, Zn(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(3), one O(1), and one O(4) atom. The Zn(1)-N(1) bond length is 1.98 Å. The Zn(1)-N(3) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 1.95 Å. The Zn(1)-O(4) bond length is 1.96 Å. There are eighteen inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(1) bond length is 1.53 Å. The C(2)-C(3) bond length is 1.36 Å. The C(2)-C(7) bond length is 1.33 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-O(1) bond length is 1.19 Å. The C(1)-O(2) bond length is 1.22 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.34 Å. The C(10)-H(6) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.37 Å. The C(11)-C(14) bond length is 1.46 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 0.93 Å. In the eighth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(4), and one O(5) atom. The C(14)-O(4) bond length is 1.25 Å. The C(14)-O(5) bond length is 1.27 Å. In the ninth C site, C(15) is bonded in a 3-coordinate geometry to one C(16), one N(1), and one H(9) atom. The C(15)-C(16) bond length is 1.35 Å. The C(15)-N(1) bond length is 1.36 Å. The C(15)-H(9) bond length is 0.93 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one H(10) atom. The C(16)-C(17) bond length is 1.37 Å. The C(16)-H(10) bond length is 0.93 Å. In the eleventh C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-C(20) bond length is 1.44 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(11) atom. The C(18)-H(11) bond length is 0.93 Å. In the thirteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(12) atom. The C(19)-N(1) bond length is 1.33 Å. The C(19)-H(12) bond length is 0.93 Å. In the fourteenth C site, C(20) is bonded in a trigonal planar geometry to one C(17), one C(21), and one C(24) atom. The C(20)-C(21) bond length is 1.34 Å. The C(20)-C(24) bond length is 1.34 Å. In the fifteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(13) atom. The C(21)-H(13) bond length is 0.93 Å. In the sixteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(20) and one H(16) atom. The C(24)-H(16) bond length is 0.93 Å. In the seventeenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(25)-N(3) bond length is 1.26 Å. The C(25)-H(17) bond length is 0.93 Å. In the eighteenth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(20) atom. The C(29)-N(3) bond length is 1.31 Å. The C(29)-H(20) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(19) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(25), and one C(29) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(29) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(14) atom. Linkers: 8 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,4 c1cc(-c2ccncc2)ccn1. Metal clusters: 8 [Zn]. The MOF has largest included sphere 6.91 A, density 1.15 g/cm3, surface area 4984.66 m2/g, accessible volume 0.37 cm3/g