(Mo6Zn2C21H12O16)2Mo12Zn4C12H6O31 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Mo12Zn4C12H6O31 cluster and one Mo6Zn2C21H12O16 cluster. In the Mo12Zn4C12H6O31 cluster, there are twelve inequivalent Mo sites. In the first Mo site, Mo(13) is bonded in a distorted square co-planar geometry to one O(40), one O(46), one O(47), and one O(51) atom. The Mo(13)-O(40) bond length is 1.96 Å. The Mo(13)-O(46) bond length is 2.07 Å. The Mo(13)-O(47) bond length is 2.01 Å. The Mo(13)-O(51) bond length is 1.93 Å. In the second Mo site, Mo(14) is bonded in a 4-coordinate geometry to one O(40), one O(51), one O(52), and one O(55) atom. The Mo(14)-O(40) bond length is 1.97 Å. The Mo(14)-O(51) bond length is 1.94 Å. The Mo(14)-O(52) bond length is 1.97 Å. The Mo(14)-O(55) bond length is 2.13 Å. In the third Mo site, Mo(15) is bonded in a 4-coordinate geometry to one O(37), one O(38), one O(43), and one O(52) atom. The Mo(15)-O(37) bond length is 1.81 Å. The Mo(15)-O(38) bond length is 2.03 Å. The Mo(15)-O(43) bond length is 2.01 Å. The Mo(15)-O(52) bond length is 1.84 Å. In the fourth Mo site, Mo(16) is bonded in a 3-coordinate geometry to one O(36), one O(47), one O(50), and one O(54) atom. The Mo(16)-O(36) bond length is 2.01 Å. The Mo(16)-O(47) bond length is 1.84 Å. The Mo(16)-O(50) bond length is 1.82 Å. The Mo(16)-O(54) bond length is 2.00 Å. In the fifth Mo site, Mo(17) is bonded in a distorted rectangular see-saw-like geometry to one O(33), one O(37), one O(39), and one O(55) atom. The Mo(17)-O(33) bond length is 1.96 Å. The Mo(17)-O(37) bond length is 1.99 Å. The Mo(17)-O(39) bond length is 1.96 Å. The Mo(17)-O(55) bond length is 2.01 Å. In the sixth Mo site, Mo(18) is bonded in a 4-coordinate geometry to one O(35), one O(46), one O(48), and one O(50) atom. The Mo(18)-O(35) bond length is 1.95 Å. The Mo(18)-O(46) bond length is 2.09 Å. The Mo(18)-O(48) bond length is 1.95 Å. The Mo(18)-O(50) bond length is 2.00 Å. In the seventh Mo site, Mo(19) is bonded in a distorted square co-planar geometry to one O(32), one O(34), one O(44), and one O(49) atom. The Mo(19)-O(32) bond length is 1.95 Å. The Mo(19)-O(34) bond length is 1.99 Å. The Mo(19)-O(44) bond length is 1.99 Å. The Mo(19)-O(49) bond length is 1.94 Å. In the eighth Mo site, Mo(20) is bonded in a distorted rectangular see-saw-like geometry to one O(33), one O(39), one O(41), and one O(42) atom. The Mo(20)-O(33) bond length is 1.95 Å. The Mo(20)-O(39) bond length is 1.95 Å. The Mo(20)-O(41) bond length is 1.98 Å. The Mo(20)-O(42) bond length is 2.05 Å. In the ninth Mo site, Mo(21) is bonded in a distorted rectangular see-saw-like geometry to one O(36), one O(41), one O(53), and one O(54) atom. The Mo(21)-O(36) bond length is 2.01 Å. The Mo(21)-O(41) bond length is 1.83 Å. The Mo(21)-O(53) bond length is 1.82 Å. The Mo(21)-O(54) bond length is 2.02 Å. In the tenth Mo site, Mo(22) is bonded in a 4-coordinate geometry to one O(32), one O(42), one O(49), and one O(53) atom. The Mo(22)-O(32) bond length is 1.95 Å. The Mo(22)-O(42) bond length is 2.07 Å. The Mo(22)-O(49) bond length is 1.94 Å. The Mo(22)-O(53) bond length is 2.00 Å. In the eleventh Mo site, Mo(23) is bonded in a distorted rectangular see-saw-like geometry to one O(34), one O(35), one O(45), and one O(48) atom. The Mo(23)-O(34) bond length is 2.04 Å. The Mo(23)-O(35) bond length is 1.98 Å. The Mo(23)-O(45) bond length is 2.01 Å. The Mo(23)-O(48) bond length is 1.93 Å. In the twelfth Mo site, Mo(24) is bonded in a 4-coordinate geometry to one O(38), one O(43), one O(44), and one O(45) atom. The Mo(24)-O(38) bond length is 2.03 Å. The Mo(24)-O(43) bond length is 2.01 Å. The Mo(24)-O(44) bond length is 1.86 Å. The Mo(24)-O(45) bond length is 1.82 Å. There are four inequivalent Zn sites. In the first Zn site, Zn(5) is bonded in a tetrahedral geometry to one O(32), one O(34), one O(35), and one O(36) atom. The Zn(5)-O(32) bond length is 1.99 Å. The Zn(5)-O(34) bond length is 1.93 Å. The Zn(5)-O(35) bond length is 1.97 Å. The Zn(5)-O(36) bond length is 1.95 Å. In the second Zn site, Zn(6) is bonded in a tetrahedral geometry to one O(33), one O(38), one O(49), and one O(56) atom. The Zn(6)-O(33) bond length is 1.97 Å. The Zn(6)-O(38) bond length is 1.92 Å. The Zn(6)-O(49) bond length is 1.97 Å. The Zn(6)-O(56) bond length is 1.90 Å. In the third Zn site, Zn(7) is bonded in a tetrahedral geometry to one O(40), one O(43), one O(48), and one O(58) atom. The Zn(7)-O(40) bond length is 1.98 Å. The Zn(7)-O(43) bond length is 1.93 Å. The Zn(7)-O(48) bond length is 1.97 Å. The Zn(7)-O(58) bond length is 1.88 Å. In the fourth Zn site, Zn(8) is bonded in a tetrahedral geometry to one O(39), one O(51), one O(54), and one O(61) atom. The Zn(8)-O(39) bond length is 1.97 Å. The Zn(8)-O(51) bond length is 2.01 Å. The Zn(8)-O(54) bond length is 1.94 Å. The Zn(8)-O(61) bond length is 1.93 Å. There are twelve inequivalent C sites. In the first C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(9) atom. The C(16)-C(17) bond length is 1.46 Å. The C(16)-H(9) bond length is 0.93 Å. In the second C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.36 Å. The C(17)-C(20) bond length is 1.46 Å. In the third C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(10) atom. The C(18)-H(10) bond length is 0.93 Å. In the fourth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(60), and one O(61) atom. The C(20)-O(60) bond length is 1.28 Å. The C(20)-O(61) bond length is 1.30 Å. In the fifth C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(13) atom. The C(23)-C(24) bond length is 1.42 Å. The C(23)-H(13) bond length is 0.93 Å. In the sixth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(27) atom. The C(24)-C(25) bond length is 1.36 Å. The C(24)-C(27) bond length is 1.50 Å. In the seventh C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(14) atom. The C(25)-H(14) bond length is 0.93 Å. In the eighth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(56), and one O(57) atom. The C(27)-O(56) bond length is 1.25 Å. The C(27)-O(57) bond length is 1.20 Å. In the ninth C site, C(43) is bonded in a distorted single-bond geometry to one C(44) and one H(24) atom. The C(43)-C(44) bond length is 1.45 Å. The C(43)-H(24) bond length is 0.93 Å. In the tenth C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(47) atom. The C(44)-C(45) bond length is 1.36 Å. The C(44)-C(47) bond length is 1.47 Å. In the eleventh C site, C(45) is bonded in a distorted single-bond geometry to one C(44) and one H(25) atom. The C(45)-H(25) bond length is 0.93 Å. In the twelfth C site, C(47) is bonded in a 4-coordinate geometry to one C(44), one O(58), one O(59), and one O(62) atom. The C(47)-O(58) bond length is 1.29 Å. The C(47)-O(59) bond length is 1.32 Å. The C(47)-O(62) bond length is 1.30 Å. There are six inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(23) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(24) is bonded in a single-bond geometry to one C(43) atom. In the sixth H site, H(25) is bonded in a single-bond geometry to one C(45) atom. There are thirty-one inequivalent O sites. In the first O site, O(49) is bonded in a 3-coordinate geometry to one Mo(19), one Mo(22), and one Zn(6) atom. In the second O site, O(54) is bonded in a single-bond geometry to one Mo(16), one Mo(21), and one Zn(8) atom. In the third O site, O(32) is bonded in a 3-coordinate geometry to one Mo(19), one Mo(22), and one Zn(5) atom. In the fourth O site, O(33) is bonded in a 3-coordinate geometry to one Mo(17), one Mo(20), and one Zn(6) atom. In the fifth O site, O(34) is bonded in a trigonal planar geometry to one Mo(19), one Mo(23), and one Zn(5) atom. In the sixth O site, O(35) is bonded in a 3-coordinate geometry to one Mo(18), one Mo(23), and one Zn(5) atom. In the seventh O site, O(36) is bonded in a distorted single-bond geometry to one Mo(16), one Mo(21), and one Zn(5) atom. In the eighth O site, O(37) is bonded in a bent 120 degrees geometry to one Mo(15) and one Mo(17) atom. In the ninth O site, O(38) is bonded in a single-bond geometry to one Mo(15), one Mo(24), and one Zn(6) atom. In the tenth O site, O(39) is bonded in a 3-coordinate geometry to one Mo(17), one Mo(20), and one Zn(8) atom. In the eleventh O site, O(40) is bonded in a 3-coordinate geometry to one Mo(13), one Mo(14), and one Zn(7) atom. In the twelfth O site, O(41) is bonded in a bent 120 degrees geometry to one Mo(20) and one Mo(21) atom. In the thirteenth O site, O(42) is bonded in a bent 120 degrees geometry to one Mo(20) and one Mo(22) atom. In the fourteenth O site, O(43) is bonded in a single-bond geometry to one Mo(15), one Mo(24), and one Zn(7) atom. In the fifteenth O site, O(56) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(27) atom. In the sixteenth O site, O(57) is bonded in a single-bond geometry to one C(27) atom. In the seventeenth O site, O(62) is bonded in a single-bond geometry to one C(47) atom. In the eighteenth O site, O(58) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(47) atom. In the nineteenth O site, O(59) is bonded in a distorted single-bond geometry to one C(47) atom. In the twentieth O site, O(51) is bonded in a 3-coordinate geometry to one Mo(13), one Mo(14), and one Zn(8) atom. In the twenty-first O site, O(60) is bonded in a single-bond geometry to one C(20) atom. In the twenty-second O site, O(61) is bonded in a bent 120 degrees geometry to one Zn(8) and one C(20) atom. In the twenty-third O site, O(50) is bonded in a distorted bent 120 degrees geometry to one Mo(16) and one Mo(18) atom. In the twenty-fourth O site, O(55) is bonded in a bent 120 degrees geometry to one Mo(14) and one Mo(17) atom. In the twenty-fifth O site, O(52) is bonded in a bent 120 degrees geometry to one Mo(14) and one Mo(15) atom. In the twenty-sixth O site, O(44) is bonded in a single-bond geometry to one Mo(19) and one Mo(24) atom. In the twenty-seventh O site, O(53) is bonded in a distorted bent 120 degrees geometry to one Mo(21) and one Mo(22) atom. In the twenty-eighth O site, O(45) is bonded in a distorted single-bond geometry to one Mo(23) and one Mo(24) atom. In the twenty-ninth O site, O(46) is bonded in a bent 120 degrees geometry to one Mo(13) and one Mo(18) atom. In the thirtieth O site, O(47) is bonded in a bent 120 degrees geometry to one Mo(13) and one Mo(16) atom. In the thirty-first O site, O(48) is bonded in a 3-coordinate geometry to one Mo(18), one Mo(23), and one Zn(7) atom. In the Mo6Zn2C21H12O16 cluster, there are twelve inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 4-coordinate geometry to one O(11), one O(15), one O(25), and one O(9) atom. The Mo(1)-O(11) bond length is 1.98 Å. The Mo(1)-O(15) bond length is 2.03 Å. The Mo(1)-O(25) bond length is 1.99 Å. The Mo(1)-O(9) bond length is 1.94 Å. In the second Mo site, Mo(2) is bonded in a 4-coordinate geometry to one O(11), one O(18), one O(23), and one O(9) atom. The Mo(2)-O(11) bond length is 1.98 Å. The Mo(2)-O(18) bond length is 2.06 Å. The Mo(2)-O(23) bond length is 2.01 Å. The Mo(2)-O(9) bond length is 1.95 Å. In the third Mo site, Mo(3) is bonded in a distorted rectangular see-saw-like geometry to one O(12), one O(22), one O(3), and one O(5) atom. The Mo(3)-O(12) bond length is 1.83 Å. The Mo(3)-O(22) bond length is 1.81 Å. The Mo(3)-O(3) bond length is 2.02 Å. The Mo(3)-O(5) bond length is 2.02 Å. In the fourth Mo site, Mo(4) is bonded in a 4-coordinate geometry to one O(13), one O(20), one O(21), and one O(8) atom. The Mo(4)-O(13) bond length is 2.03 Å. The Mo(4)-O(20) bond length is 2.00 Å. The Mo(4)-O(21) bond length is 1.95 Å. The Mo(4)-O(8) bond length is 1.95 Å. In the fifth Mo site, Mo(5) is bonded in a distorted rectangular see-saw-like geometry to one O(15), one O(21), one O(24), and one O(8) atom. The Mo(5)-O(15) bond length is 2.11 Å. The Mo(5)-O(21) bond length is 1.96 Å. The Mo(5)-O(24) bond length is 1.99 Å. The Mo(5)-O(8) bond length is 1.92 Å. In the sixth Mo site, Mo(6) is bonded in a 4-coordinate geometry to one O(17), one O(18), one O(2), and one O(6) atom. The Mo(6)-O(17) bond length is 2.01 Å. The Mo(6)-O(18) bond length is 2.08 Å. The Mo(6)-O(2) bond length is 1.95 Å. The Mo(6)-O(6) bond length is 1.96 Å. In the seventh Mo site, Mo(7) is bonded in a distorted rectangular see-saw-like geometry to one O(24), one O(25), one O(3), and one O(5) atom. The Mo(7)-O(24) bond length is 1.86 Å. The Mo(7)-O(25) bond length is 1.82 Å. The Mo(7)-O(3) bond length is 1.99 Å. The Mo(7)-O(5) bond length is 2.02 Å. In the eighth Mo site, Mo(8) is bonded in a 4-coordinate geometry to one O(19), one O(20), one O(4), and one O(7) atom. The Mo(8)-O(19) bond length is 1.83 Å. The Mo(8)-O(20) bond length is 1.81 Å. The Mo(8)-O(4) bond length is 2.04 Å. The Mo(8)-O(7) bond length is 2.01 Å. In the ninth Mo site, Mo(9) is bonded in a 4-coordinate geometry to one O(17), one O(23), one O(4), and one O(7) atom. The Mo(9)-O(17) bond length is 1.81 Å. The Mo(9)-O(23) bond length is 1.81 Å. The Mo(9)-O(4) bond length is 2.03 Å. The Mo(9)-O(7) bond length is 2.03 Å. In the tenth Mo site, Mo(10) is bonded to one O(10), one O(16), one O(2), one O(22), one O(6), and one O(63) atom to form distorted MoO6 octahedra that share  a cornercorner with one Zn(1)O4 tetrahedra and corners with two equivalent Zn(4)O4 tetrahedra. The Mo(10)-O(10) bond length is 2.03 Å. The Mo(10)-O(16) bond length is 1.68 Å. The Mo(10)-O(2) bond length is 1.96 Å. The Mo(10)-O(22) bond length is 2.04 Å. The Mo(10)-O(6) bond length is 1.93 Å. The Mo(10)-O(63) bond length is 1.71 Å. In the eleventh Mo site, Mo(11) is bonded in a 4-coordinate geometry to one O(1), one O(13), one O(14), and one O(19) atom. The Mo(11)-O(1) bond length is 1.96 Å. The Mo(11)-O(13) bond length is 2.10 Å. The Mo(11)-O(14) bond length is 1.93 Å. The Mo(11)-O(19) bond length is 1.99 Å. In the twelfth Mo site, Mo(12) is bonded in a distorted square co-planar geometry to one O(1), one O(10), one O(12), and one O(14) atom. The Mo(12)-O(1) bond length is 1.99 Å. The Mo(12)-O(10) bond length is 2.01 Å. The Mo(12)-O(12) bond length is 2.00 Å. The Mo(12)-O(14) bond length is 1.93 Å. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(26), one O(3), one O(6), and one O(9) atom to form ZnO4 tetrahedra that share  a cornercorner with one Mo(10)O6 octahedra. The corner-sharing octahedral tilt angles are 49°. The Zn(1)-O(26) bond length is 1.88 Å. The Zn(1)-O(3) bond length is 1.94 Å. The Zn(1)-O(6) bond length is 1.99 Å. The Zn(1)-O(9) bond length is 1.98 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one O(11), one O(21), one O(30), and one O(7) atom. The Zn(2)-O(11) bond length is 1.94 Å. The Zn(2)-O(21) bond length is 1.98 Å. The Zn(2)-O(30) bond length is 1.93 Å. The Zn(2)-O(7) bond length is 1.92 Å. In the third Zn site, Zn(3) is bonded in a tetrahedral geometry to one O(1), one O(29), one O(5), and one O(8) atom. The Zn(3)-O(1) bond length is 1.96 Å. The Zn(3)-O(29) bond length is 1.95 Å. The Zn(3)-O(5) bond length is 1.94 Å. The Zn(3)-O(8) bond length is 2.01 Å. In the fourth Zn site, Zn(4) is bonded to one O(10), one O(14), one O(2), and one O(4) atom to form ZnO4 tetrahedra that share corners with two equivalent Mo(10)O6 octahedra. The corner-sharing octahedral tilt angles range from 42-65°. The Zn(4)-O(10) bond length is 1.94 Å. The Zn(4)-O(14) bond length is 2.02 Å. The Zn(4)-O(2) bond length is 1.98 Å. The Zn(4)-O(4) bond length is 1.92 Å. There are forty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-C(7) bond length is 1.49 Å. In the second C site, C(2) is bonded in a single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(4) atom. The C(3)-C(14) bond length is 1.51 Å. The C(3)-C(4) bond length is 1.29 Å. In the fourth C site, C(4) is bonded in a single-bond geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(21), one C(4), and one C(6) atom. The C(5)-C(21) bond length is 1.42 Å. The C(5)-C(6) bond length is 1.46 Å. In the sixth C site, C(6) is bonded in a single-bond geometry to one C(1), one C(5), and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(1), one C(12), and one C(8) atom. The C(7)-C(12) bond length is 1.48 Å. The C(7)-C(8) bond length is 1.33 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(8)-H(4) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(9)-C(10) bond length is 1.33 Å. The C(9)-H(5) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(9) atom. The C(10)-C(11) bond length is 1.43 Å. The C(10)-C(13) bond length is 1.53 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(6) atom. The C(11)-C(12) bond length is 1.29 Å. The C(11)-H(6) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a single-bond geometry to one C(11), one C(7), and one H(7) atom. The C(12)-H(7) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(26), and one O(27) atom. The C(13)-O(26) bond length is 1.32 Å. The C(13)-O(27) bond length is 1.20 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(3) atom. The C(14)-C(15) bond length is 1.36 Å. The C(14)-C(19) bond length is 1.40 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(8) atom. The C(15)-H(8) bond length is 0.93 Å. In the sixteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(19)-H(11) bond length is 0.93 Å. In the seventeenth C site, C(21) is bonded in a trigonal planar geometry to one C(22), one C(26), and one C(5) atom. The C(21)-C(22) bond length is 1.33 Å. The C(21)-C(26) bond length is 1.47 Å. In the eighteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(12) atom. The C(22)-H(12) bond length is 0.93 Å. In the nineteenth C site, C(26) is bonded in a single-bond geometry to one C(21) and one H(15) atom. The C(26)-H(15) bond length is 0.93 Å. In the twentieth C site, C(28) is bonded in a trigonal planar geometry to one C(29), one C(33), and one C(34) atom. The C(28)-C(29) bond length is 1.42 Å. The C(28)-C(33) bond length is 1.37 Å. The C(28)-C(34) bond length is 1.51 Å. In the twenty-first C site, C(29) is bonded in a single-bond geometry to one C(28), one C(30), and one H(16) atom. The C(29)-C(30) bond length is 1.35 Å. The C(29)-H(16) bond length is 0.93 Å. In the twenty-second C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(41) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-C(41) bond length is 1.51 Å. In the twenty-third C site, C(31) is bonded in a single-bond geometry to one C(30), one C(32), and one H(17) atom. The C(31)-C(32) bond length is 1.34 Å. The C(31)-H(17) bond length is 0.93 Å. In the twenty-fourth C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(48) atom. The C(32)-C(33) bond length is 1.42 Å. The C(32)-C(48) bond length is 1.45 Å. In the twenty-fifth C site, C(33) is bonded in a distorted single-bond geometry to one C(28), one C(32), and one H(18) atom. The C(33)-H(18) bond length is 0.93 Å. In the twenty-sixth C site, C(34) is bonded in a trigonal planar geometry to one C(28), one C(35), and one C(39) atom. The C(34)-C(35) bond length is 1.46 Å. The C(34)-C(39) bond length is 1.30 Å. In the twenty-seventh C site, C(35) is bonded in a single-bond geometry to one C(34) and one H(19) atom. The C(35)-H(19) bond length is 0.93 Å. In the twenty-eighth C site, C(36) is bonded in a distorted single-bond geometry to one C(37) and one H(20) atom. The C(36)-C(37) bond length is 1.35 Å. The C(36)-H(20) bond length is 0.93 Å. In the twenty-ninth C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one C(40) atom. The C(37)-C(38) bond length is 1.36 Å. The C(37)-C(40) bond length is 1.55 Å. In the thirtieth C site, C(38) is bonded in a distorted single-bond geometry to one C(37) and one H(21) atom. The C(38)-H(21) bond length is 0.93 Å. In the thirty-first C site, C(39) is bonded in a distorted single-bond geometry to one C(34) and one H(22) atom. The C(39)-H(22) bond length is 0.93 Å. In the thirty-second C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(28), and one O(29) atom. The C(40)-O(28) bond length is 1.22 Å. The C(40)-O(29) bond length is 1.26 Å. In the thirty-third C site, C(41) is bonded in a trigonal planar geometry to one C(30), one C(42), and one C(46) atom. The C(41)-C(42) bond length is 1.35 Å. The C(41)-C(46) bond length is 1.46 Å. In the thirty-fourth C site, C(42) is bonded in a distorted single-bond geometry to one C(41) and one H(23) atom. The C(42)-H(23) bond length is 0.93 Å. In the thirty-fifth C site, C(46) is bonded in a distorted single-bond geometry to one C(41) and one H(26) atom. The C(46)-H(26) bond length is 0.93 Å. In the thirty-sixth C site, C(48) is bonded in a trigonal planar geometry to one C(32), one C(49), and one C(53) atom. The C(48)-C(49) bond length is 1.40 Å. The C(48)-C(53) bond length is 1.39 Å. In the thirty-seventh C site, C(49) is bonded in a distorted trigonal planar geometry to one C(48), one C(50), and one H(27) atom. The C(49)-C(50) bond length is 1.39 Å. The C(49)-H(27) bond length is 0.93 Å. In the thirty-eighth C site, C(50) is bonded in a distorted single-bond geometry to one C(49), one C(51), and one H(28) atom. The C(50)-C(51) bond length is 1.32 Å. The C(50)-H(28) bond length is 0.93 Å. In the thirty-ninth C site, C(51) is bonded in a trigonal planar geometry to one C(50), one C(52), and one C(54) atom. The C(51)-C(52) bond length is 1.36 Å. The C(51)-C(54) bond length is 1.51 Å. In the fortieth C site, C(52) is bonded in a distorted single-bond geometry to one C(51) and one H(29) atom. The C(52)-H(29) bond length is 0.93 Å. In the forty-first C site, C(53) is bonded in a single-bond geometry to one C(48) and one H(30) atom. The C(53)-H(30) bond length is 0.93 Å. In the forty-second C site, C(54) is bonded in a bent 120 degrees geometry to one C(51), one O(30), and one O(31) atom. The C(54)-O(30) bond length is 1.32 Å. The C(54)-O(31) bond length is 1.24 Å. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(29) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(33) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(35) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(36) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(38) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(39) atom. In the nineteenth H site, H(23) is bonded in a single-bond geometry to one C(42) atom. In the twentieth H site, H(26) is bonded in a single-bond geometry to one C(46) atom. In the twenty-first H site, H(27) is bonded in a single-bond geometry to one C(49) atom. In the twenty-second H site, H(28) is bonded in a single-bond geometry to one C(50) atom. In the twenty-third H site, H(29) is bonded in a single-bond geometry to one C(52) atom. In the twenty-fourth H site, H(30) is bonded in a single-bond geometry to one C(53) atom. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mo(11), one Mo(12), and one Zn(3) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mo(10), one Mo(6), and one Zn(4) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Mo(3), one Mo(7), and one Zn(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Mo(8), one Mo(9), and one Zn(4) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Mo(3), one Mo(7), and one Zn(3) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Mo(10), one Mo(6), and one Zn(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Mo(8), one Mo(9), and one Zn(2) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Mo(4), one Mo(5), and one Zn(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Zn(1) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Mo(10), one Mo(12), and one Zn(4) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Mo(1), one Mo(2), and one Zn(2) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one Mo(12) and one Mo(3) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Mo(11) and one Mo(4) atom. In the fourteenth O site, O(14) is bonded in a distorted T-shaped geometry to one Mo(11), one Mo(12), and one Zn(4) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(5) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Mo(10) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Mo(6) and one Mo(9) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(6) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Mo(11) and one Mo(8) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Mo(4) and one Mo(8) atom. In the twenty-first O site, O(21) is bonded in a 3-coordinate geometry to one Mo(4), one Mo(5), and one Zn(2) atom. In the twenty-second O site, O(22) is bonded in a single-bond geometry to one Mo(10) and one Mo(3) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(9) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 120 degrees geometry to one Mo(5) and one Mo(7) atom. In the twenty-fifth O site, O(25) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(7) atom. In the twenty-sixth O site, O(26) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the twenty-seventh O site, O(27) is bonded in a single-bond geometry to one C(13) atom. In the twenty-eighth O site, O(28) is bonded in a single-bond geometry to one C(40) atom. In the twenty-ninth O site, O(29) is bonded in a water-like geometry to one Zn(3) and one C(40) atom. In the thirtieth O site, O(30) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(54) atom. In the thirty-first O site, O(31) is bonded in a single-bond geometry to one C(54) atom. In the thirty-second O site, O(63) is bonded in a single-bond geometry to one Mo(10) atom. Linkers: 2 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C([O])=O)cc3)c2)cc1 ,2 [O]C(=O)c1ccc(-c2cc(-c3cc[c]cc3)cc(-c3ccc(C([O])=O)cc3)c2)cc1.[O][C]O[O]. Metal clusters: 1 [O]O[Mo].[O]O[Mo].[O][Mo]O[Mo@@]12O[Zn]3O[Mo]4O[Mo@]5(O[Zn](O[C]=O)O[Mo@@]67O[Zn](O[C]=O)O[Mo]89(O[Mo]%10O[Zn](O[C]=O)O[Mo]%11(O6)(O[Mo@@]%11(O4)O5)O[Mo]45(O7)O[Mo]4(O%10)(O8)O5)O[Mo@@]9(O[Mo][O])O[Zn]4O[Mo]5O[Mo@@]6(O[Zn](O[C]=O)O[Mo@]78O[Zn](O[C]=O)O[Mo]19(O[Mo]1O[Zn](O[C]=O)O[Mo]%10(O7)(O[Mo@]%10(O5)O6)O[Mo]56(O8)O[Mo]5(O1)(O9)O6)O2)O4)O3 ,1 [O][Zn]O[Mo@]1(O[Zn]O[C]=O)O[Mo]234O[Mo]25(O[Mo](O[Zn]O[C]=O)O[Mo]26(O[Zn]7O[Mo]8O[Mo]9%10(O[Mo]9(O[Mo]O[Mo]2O6)(O[Zn]2O[Mo]6O[Mo]9%11%12O[Mo]9(O[Mo]O[Mo]9O[Mo]9%13(O2)O[Mo](O[Zn]O[C]=O)O[Mo]29(O%13)O[Mo]2%13(O[Mo@@](O[Zn][O])(O[Zn]O[C]=O)O[Mo]2%14(O[Mo]2(O6)(O%11)O%14)O%13)O9)(O7)O%12)O%10)O[Mo]26(O8)O[Mo]2(O1)(O6)O3)O5)O4. RCSR code: rtl. The MOF has largest included sphere 9.16 A, density 1.30 g/cm3, surface area 2238.94 m2/g, accessible volume 0.50 cm3/g