WCu6C32H24S4(N6I)4 crystallizes in the cubic I-43d space group. W(1) is bonded in a 10-coordinate geometry to two equivalent Cu(2), four equivalent Cu(1), and four equivalent S(1) atoms. Both W(1)-Cu(2) bond lengths are 2.69 Å. All W(1)-Cu(1) bond lengths are 2.73 Å. All W(1)-S(1) bond lengths are 2.26 Å. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 4-coordinate geometry to one W(1), one N(1), two equivalent S(1), and one I(1) atom. The Cu(1)-N(1) bond length is 1.98 Å. There is one shorter (2.33 Å) and one longer (2.34 Å) Cu(1)-S(1) bond length. The Cu(1)-I(1) bond length is 2.56 Å. In the second Cu site, Cu(2) is bonded in a 4-coordinate geometry to one W(1), two equivalent N(4), and two equivalent S(1) atoms. Both Cu(2)-N(4) bond lengths are 1.98 Å. Both Cu(2)-S(1) bond lengths are 2.32 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.43 Å. The C(1)-N(2) bond length is 1.42 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(1) bond length is 1.41 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.43 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(2) and two equivalent N(3) atoms. The C(4)-N(2) bond length is 1.35 Å. There is one shorter (1.33 Å) and one longer (1.42 Å) C(4)-N(3) bond length. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(4) atom. The C(5)-N(4) bond length is 1.40 Å. The C(5)-N(5) bond length is 1.43 Å. The C(5)-H(4) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(4), and one H(5) atom. The C(6)-C(7) bond length is 1.42 Å. The C(6)-N(4) bond length is 1.42 Å. The C(6)-H(5) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one N(5), and one H(6) atom. The C(7)-N(5) bond length is 1.41 Å. The C(7)-H(6) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(5) and two equivalent N(6) atoms. The C(8)-N(5) bond length is 1.36 Å. There is one shorter (1.34 Å) and one longer (1.37 Å) C(8)-N(6) bond length. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a water-like geometry to two equivalent C(4) atoms. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(5), and one C(6) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. In the sixth N site, N(6) is bonded in a water-like geometry to two equivalent C(8) atoms. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. S(1) is bonded to one W(1), one Cu(2), and two equivalent Cu(1) atoms to form distorted edge-sharing SCu3W tetrahedra. I(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 17 n1ccn(c1)C1=NC(=[N]=C([N]1)n1ccnc1)n1ccnc1. Metal clusters: 6 I[Cu]1[S@]23[Cu](I)[S@]45[Cu](I)[S@]67[Cu](I)[S@@]18[Cu]4[W]6285[Cu]73. The MOF has largest included sphere 8.70 A, density 1.39 g/cm3, surface area 2977.95 m2/g, accessible volume 0.47 cm3/g