Cu(OOCC6H4COO)CuH24(C7O)6(CH3)2 is Indium-derived structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, eight Cu(OOCC6H4COO) clusters, and eight CuH24(C7O)6 clusters. In each Cu(OOCC6H4COO) cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(7), and one O(8) atom. The Cu(1)-O(1) bond length is 1.94 Å. The Cu(1)-O(2) bond length is 1.98 Å. The Cu(1)-O(7) bond length is 1.94 Å. The Cu(1)-O(8) bond length is 2.04 Å. There are eight inequivalent C sites. In the first C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(1), and one O(7) atom. The C(7)-C(11) bond length is 1.48 Å. The C(7)-O(1) bond length is 1.20 Å. The C(7)-O(7) bond length is 1.39 Å. In the second C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6,7) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-H(6,7) bond length is 0.93 Å. In the third C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(7) atom. The C(11)-C(12) bond length is 1.41 Å. In the fourth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(6,7) atom. The C(12)-H(6,7) bond length is 0.93 Å. In the fifth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(2), and one O(8) atom. The C(14)-C(25) bond length is 1.51 Å. The C(14)-O(2) bond length is 1.24 Å. The C(14)-O(8) bond length is 1.22 Å. In the sixth C site, C(25) is bonded in a trigonal planar geometry to one C(14), one C(26), and one C(30) atom. The C(25)-C(26) bond length is 1.41 Å. The C(25)-C(30) bond length is 1.41 Å. In the seventh C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(13) atom. The C(26)-H(13) bond length is 0.93 Å. In the eighth C site, C(30) is bonded in a distorted single-bond geometry to one C(25) and one H(16) atom. The C(30)-H(16) bond length is 0.93 Å. There are three inequivalent H sites. In the first H site, H(6,7) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(13) is bonded in a single-bond geometry to one C(26) atom. In the third H site, H(16) is bonded in a single-bond geometry to one C(30) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(14) atom. In the third O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the fourth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(14) atom. In each CuH24(C7O)6 cluster, Cu(2) is bonded in a distorted rectangular see-saw-like geometry to one O(3), one O(4), one O(5), and one O(6) atom. The Cu(2)-O(3) bond length is 1.95 Å. The Cu(2)-O(4) bond length is 1.97 Å. The Cu(2)-O(5) bond length is 1.96 Å. The Cu(2)-O(6) bond length is 1.93 Å. There are forty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(23), and one C(6) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(23) bond length is 1.51 Å. The C(1)-C(6) bond length is 1.41 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2,3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(2,3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(38), and one C(5) atom. The C(4)-C(38) bond length is 1.39 Å. The C(4)-C(5) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(2,3) atom. The C(5)-H(2,3) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(18), and one C(9) atom. The C(8)-C(13) bond length is 1.41 Å. The C(8)-C(18) bond length is 1.55 Å. The C(8)-C(9) bond length is 1.41 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5,8) atom. The C(9)-H(5,8) bond length is 0.93 Å. In the ninth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(5,8) atom. The C(13)-H(5,8) bond length is 0.93 Å. In the tenth C site, C(15) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(39) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-C(20) bond length is 1.41 Å. The C(15)-C(39) bond length is 1.47 Å. In the eleventh C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one O(9) atom. The C(16)-O(9) bond length is 1.39 Å. In the twelfth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(9) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-H(9) bond length is 0.93 Å. In the thirteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(8) atom. The C(18)-C(19) bond length is 1.41 Å. In the fourteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-C(24) bond length is 1.43 Å. In the fifteenth C site, C(20) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(21) atom. The C(20)-C(21) bond length is 1.37 Å. In the sixteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(10) atom. The C(21)-H(10) bond length is 0.93 Å. In the seventeenth C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(11) atom. The C(22)-C(23) bond length is 1.38 Å. The C(22)-H(11) bond length is 0.93 Å. In the eighteenth C site, C(23) is bonded in a trigonal planar geometry to one C(1), one C(22), and one C(24) atom. The C(23)-C(24) bond length is 1.35 Å. In the nineteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(19), one C(23), and one H(12) atom. The C(24)-H(12) bond length is 0.93 Å. In the twentieth C site, C(27) is bonded in a distorted single-bond geometry to one C(28) and one H(14,15) atom. The C(27)-C(28) bond length is 1.41 Å. The C(27)-H(14,15) bond length is 0.93 Å. In the twenty-first C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(47) atom. The C(28)-C(29) bond length is 1.41 Å. The C(28)-C(47) bond length is 1.50 Å. In the twenty-second C site, C(29) is bonded in a single-bond geometry to one C(28) and one H(14,15) atom. The C(29)-H(14,15) bond length is 0.93 Å. In the twenty-third C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(4), and one O(5) atom. The C(31)-C(35) bond length is 1.58 Å. The C(31)-O(4) bond length is 1.27 Å. The C(31)-O(5) bond length is 1.21 Å. In the twenty-fourth C site, C(32) is bonded in a trigonal planar geometry to one C(33), one C(37), and one C(42) atom. The C(32)-C(33) bond length is 1.41 Å. The C(32)-C(37) bond length is 1.41 Å. The C(32)-C(42) bond length is 1.47 Å. In the twenty-fifth C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(17) atom. The C(33)-H(17) bond length is 0.93 Å. In the twenty-sixth C site, C(34) is bonded in a distorted single-bond geometry to one C(35) and one H(18) atom. The C(34)-C(35) bond length is 1.41 Å. The C(34)-H(18) bond length is 0.93 Å. In the twenty-seventh C site, C(35) is bonded in a trigonal planar geometry to one C(31), one C(34), and one C(36) atom. The C(35)-C(36) bond length is 1.41 Å. In the twenty-eighth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(35), one C(37), and one H(19) atom. The C(36)-C(37) bond length is 1.41 Å. The C(36)-H(19) bond length is 0.93 Å. In the twenty-ninth C site, C(37) is bonded in a distorted single-bond geometry to one C(32), one C(36), and one H(20) atom. The C(37)-H(20) bond length is 0.93 Å. In the thirtieth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(6) atom. The C(38)-O(3) bond length is 1.36 Å. The C(38)-O(6) bond length is 1.34 Å. In the thirty-first C site, C(39) is bonded in a trigonal planar geometry to one C(15), one C(40), and one C(44) atom. The C(39)-C(40) bond length is 1.41 Å. The C(39)-C(44) bond length is 1.41 Å. In the thirty-second C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one O(10) atom. The C(40)-O(10) bond length is 1.36 Å. In the thirty-third C site, C(41) is bonded in a distorted single-bond geometry to one C(42) and one H(21) atom. The C(41)-C(42) bond length is 1.41 Å. The C(41)-H(21) bond length is 0.93 Å. In the thirty-fourth C site, C(42) is bonded in a trigonal planar geometry to one C(32), one C(41), and one C(43) atom. The C(42)-C(43) bond length is 1.41 Å. In the thirty-fifth C site, C(43) is bonded in a trigonal planar geometry to one C(42), one C(44), and one C(48) atom. The C(43)-C(44) bond length is 1.41 Å. The C(43)-C(48) bond length is 1.40 Å. In the thirty-sixth C site, C(44) is bonded in a trigonal planar geometry to one C(39), one C(43), and one C(45) atom. The C(44)-C(45) bond length is 1.42 Å. In the thirty-seventh C site, C(45) is bonded in a distorted single-bond geometry to one C(44) and one H(22) atom. The C(45)-H(22) bond length is 0.93 Å. In the thirty-eighth C site, C(46) is bonded in a distorted single-bond geometry to one C(47) and one H(23) atom. The C(46)-C(47) bond length is 1.41 Å. The C(46)-H(23) bond length is 0.93 Å. In the thirty-ninth C site, C(47) is bonded in a trigonal planar geometry to one C(28), one C(46), and one C(48) atom. The C(47)-C(48) bond length is 1.37 Å. In the fortieth C site, C(48) is bonded in a distorted single-bond geometry to one C(43), one C(47), and one H(24) atom. The C(48)-H(24) bond length is 0.93 Å. In the forty-first C site, C(49) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(25,26) and one O(10) atom. Both C(49)-H(25,26) bond lengths are 0.97 Å. The C(49)-O(10) bond length is 1.50 Å. In the forty-second C site, C(51) is bonded in a 3-coordinate geometry to one H(30), one H(31), and one O(9) atom. The C(51)-H(30) bond length is 0.97 Å. The C(51)-H(31) bond length is 0.97 Å. The C(51)-O(9) bond length is 1.51 Å. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5,8) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(14,15) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(33) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(34) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(36) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(37) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(41) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(45) atom. In the sixteenth H site, H(23) is bonded in a single-bond geometry to one C(46) atom. In the seventeenth H site, H(24) is bonded in a single-bond geometry to one C(48) atom. In the eighteenth H site, H(25,26) is bonded in a single-bond geometry to one C(49) atom. In the nineteenth H site, H(30) is bonded in a single-bond geometry to one C(51) atom. In the twentieth H site, H(31) is bonded in a single-bond geometry to one C(51) atom. There are six inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(38) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Cu(2) and one C(31) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(31) atom. In the fourth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(38) atom. In the fifth O site, O(9) is bonded in a bent 120 degrees geometry to one C(16) and one C(51) atom. In the sixth O site, O(10) is bonded in a bent 120 degrees geometry to one C(40) and one C(49) atom. Linkers: 8 CCOc1cc(-c2ccc(C([O])=O)cc2)c2cc(-c3ccc(C([O])=O)cc3)ccc2c1-c1c(OCC)cc(-c2ccc(C([O])=O)cc2)c2cc(-c3ccc(C([O])=O)cc3)ccc12. Metal clusters: 8 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: wbl. The MOF has largest included sphere 9.79 A, density 0.58 g/cm3, surface area 4746.01 m2/g, accessible volume 1.35 cm3/g