ZnC12H8(NO2)2(C3H2)5C11H7CHC9H6N is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; ten 2,3-dimethyl-1,3-butadiene molecules; four schembl1705614 molecules; four C11H7 clusters; and four ZnC12H8(NO2)2 clusters. In each C11H7 cluster, there are eleven inequivalent C sites. In the first C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(36) atom. The C(33)-C(32) bond length is 1.39 Å. The C(33)-C(34) bond length is 1.38 Å. The C(33)-C(36) bond length is 1.48 Å. In the second C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(22) atom. The C(32)-H(22) bond length is 0.93 Å. In the third C site, C(34) is bonded in a distorted single-bond geometry to one C(33) and one H(23) atom. The C(34)-H(23) bond length is 0.93 Å. In the fourth C site, C(36) is bonded in a trigonal planar geometry to one C(33), one C(37), and one C(41) atom. The C(36)-C(37) bond length is 1.38 Å. The C(36)-C(41) bond length is 1.40 Å. In the fifth C site, C(37) is bonded in a distorted single-bond geometry to one C(36) and one H(25) atom. The C(37)-H(25) bond length is 0.93 Å. In the sixth C site, C(39) is bonded in a single-bond geometry to one C(40) and one H(27) atom. The C(39)-C(40) bond length is 1.38 Å. The C(39)-H(27) bond length is 0.93 Å. In the seventh C site, C(40) is bonded in a trigonal planar geometry to one C(39), one C(41), and one C(42) atom. The C(40)-C(41) bond length is 1.39 Å. The C(40)-C(42) bond length is 1.49 Å. In the eighth C site, C(41) is bonded in a single-bond geometry to one C(36), one C(40), and one H(28) atom. The C(41)-H(28) bond length is 0.93 Å. In the ninth C site, C(42) is bonded in a trigonal planar geometry to one C(40), one C(43), and one C(46) atom. The C(42)-C(43) bond length is 1.34 Å. The C(42)-C(46) bond length is 1.40 Å. In the tenth C site, C(43) is bonded in a distorted single-bond geometry to one C(42) and one H(29) atom. The C(43)-H(29) bond length is 0.93 Å. In the eleventh C site, C(46) is bonded in a distorted single-bond geometry to one C(42) and one H(32) atom. The C(46)-H(32) bond length is 0.93 Å. There are seven inequivalent H sites. In the first H site, H(29) is bonded in a single-bond geometry to one C(43) atom. In the second H site, H(32) is bonded in a single-bond geometry to one C(46) atom. In the third H site, H(22) is bonded in a single-bond geometry to one C(32) atom. In the fourth H site, H(23) is bonded in a single-bond geometry to one C(34) atom. In the fifth H site, H(25) is bonded in a single-bond geometry to one C(37) atom. In the sixth H site, H(27) is bonded in a single-bond geometry to one C(39) atom. In the seventh H site, H(28) is bonded in a single-bond geometry to one C(41) atom. In each ZnC12H8(NO2)2 cluster, Zn(1) is bonded in a 6-coordinate geometry to one N(2), one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(2) bond length is 2.11 Å. The Zn(1)-N(3) bond length is 2.07 Å. The Zn(1)-O(1) bond length is 2.14 Å. The Zn(1)-O(2) bond length is 2.26 Å. The Zn(1)-O(3) bond length is 2.06 Å. The Zn(1)-O(4) bond length is 2.36 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1) atom. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(4) atom. The C(5)-N(2) bond length is 1.32 Å. The C(5)-H(4) bond length is 0.93 Å. In the third C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(14) atom. The C(20)-N(3) bond length is 1.34 Å. The C(20)-H(14) bond length is 0.93 Å. In the fourth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(15) atom. The C(21)-N(3) bond length is 1.31 Å. The C(21)-H(15) bond length is 0.93 Å. In the fifth C site, C(29) is bonded in a bent 120 degrees geometry to one C(30), one O(1), and one O(2) atom. The C(29)-C(30) bond length is 1.51 Å. The C(29)-O(1) bond length is 1.21 Å. The C(29)-O(2) bond length is 1.23 Å. In the sixth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(35) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-C(35) bond length is 1.38 Å. In the seventh C site, C(31) is bonded in a single-bond geometry to one C(30) and one H(21) atom. The C(31)-H(21) bond length is 0.93 Å. In the eighth C site, C(35) is bonded in a single-bond geometry to one C(30) and one H(24) atom. The C(35)-H(24) bond length is 0.93 Å. In the ninth C site, C(44) is bonded in a distorted single-bond geometry to one C(47) and one H(30) atom. The C(44)-C(47) bond length is 1.35 Å. The C(44)-H(30) bond length is 0.93 Å. In the tenth C site, C(45) is bonded in a single-bond geometry to one C(47) and one H(31) atom. The C(45)-C(47) bond length is 1.37 Å. The C(45)-H(31) bond length is 0.93 Å. In the eleventh C site, C(47) is bonded in a trigonal planar geometry to one C(44), one C(45), and one C(48) atom. The C(47)-C(48) bond length is 1.48 Å. In the twelfth C site, C(48) is bonded in a bent 120 degrees geometry to one C(47), one O(3), and one O(4) atom. The C(48)-O(3) bond length is 1.22 Å. The C(48)-O(4) bond length is 1.17 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(20), and one C(21) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the fifth H site, H(21) is bonded in a single-bond geometry to one C(31) atom. In the sixth H site, H(24) is bonded in a single-bond geometry to one C(35) atom. In the seventh H site, H(30) is bonded in a single-bond geometry to one C(44) atom. In the eighth H site, H(31) is bonded in a single-bond geometry to one C(45) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Zn(1) and one C(29) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Zn(1) and one C(29) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(48) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Zn(1) and one C(48) atom. Linkers: 3 [CH]/C=[C]/[N]c1ccc(-c2ccc(N(c3ccc(-c4ccncc4)cc3)c3ccc(-c4ccncc4)cc3)cc2)cc1 ,2 c1cc(-c2ccc(N(c3ccc(-c4ccncc4)cc3)c3ccc(-c4ccc(N(c5ccc(-c6ccncc6)cc5)c5ccc(-c6ccncc6)cc5)cc4)cc3)cc2)ccn1 ,4 [O]C(=O)c1ccc(-c2cccc(-c3ccc(C([O])=O)cc3)c2)cc1 ,1 [CH]=C[C][N]c1ccc(-c2ccc(N(c3ccc(-c4ccncc4)cc3)c3ccc(-c4ccncc4)cc3)cc2)cc1. Metal clusters: 4 O=[C]O[Zn]1O[C]O1. The MOF has largest included sphere 5.27 A, density 1.18 g/cm3, surface area 5157.51 m2/g, accessible volume 0.36 cm3/g