CoC21H14(NO2)2CoC24H16(NO2)2C3H2 is Indium-derived structured and crystallizes in the tetragonal I4 space group. The structure is zero-dimensional and consists of eight 2,3-dimethyl-1,3-butadiene molecules; eight CoC21H14(NO2)2 clusters; and sixteen CoC24H16(NO2)2 clusters. In each CoC21H14(NO2)2 cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted octahedral geometry to one N(2), one N(6), one O(13), one O(3), one O(7), and one O(9) atom. The Co(1)-N(2) bond length is 1.95 Å. The Co(1)-N(6) bond length is 2.06 Å. The Co(1)-O(13) bond length is 2.29 Å. The Co(1)-O(3) bond length is 2.22 Å. The Co(1)-O(7) bond length is 2.08 Å. The Co(1)-O(9) bond length is 2.03 Å. In the second Co site, Co(3) is bonded in a 6-coordinate geometry to one N(3), one N(7), one O(1), one O(11), one O(15), and one O(16) atom. The Co(3)-N(3) bond length is 2.08 Å. The Co(3)-N(7) bond length is 2.13 Å. The Co(3)-O(1) bond length is 2.32 Å. The Co(3)-O(11) bond length is 2.06 Å. The Co(3)-O(15) bond length is 2.06 Å. The Co(3)-O(16) bond length is 2.19 Å. There are forty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(33), and one C(44) atom. The C(1)-C(2) bond length is 1.55 Å. The C(1)-C(33) bond length is 1.38 Å. The C(1)-C(44) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(11) atom. The C(2)-O(1) bond length is 1.26 Å. The C(2)-O(11) bond length is 1.16 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(13), one C(34), and one C(62) atom. The C(4)-C(13) bond length is 1.40 Å. The C(4)-C(34) bond length is 1.43 Å. The C(4)-C(62) bond length is 1.36 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(76), and one C(88) atom. The C(5)-C(10) bond length is 1.47 Å. The C(5)-C(76) bond length is 1.43 Å. The C(5)-C(88) bond length is 1.31 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(52), one C(73), and one H(1) atom. The C(6)-C(52) bond length is 1.44 Å. The C(6)-C(73) bond length is 1.34 Å. The C(6)-H(1) bond length is 0.95 Å. In the sixth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(3), and one O(7) atom. The C(10)-O(3) bond length is 1.24 Å. The C(10)-O(7) bond length is 1.38 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(13)-H(3) bond length is 0.95 Å. In the eighth C site, C(19) is bonded in a trigonal planar geometry to one C(24), one C(36), and one C(55) atom. The C(19)-C(24) bond length is 1.46 Å. The C(19)-C(36) bond length is 1.37 Å. The C(19)-C(55) bond length is 1.51 Å. In the ninth C site, C(24) is bonded in a distorted single-bond geometry to one C(19) and one H(8) atom. The C(24)-H(8) bond length is 0.95 Å. In the tenth C site, C(28) is bonded in a distorted single-bond geometry to one C(54), one C(73), and one H(10) atom. The C(28)-C(54) bond length is 1.31 Å. The C(28)-C(73) bond length is 1.38 Å. The C(28)-H(10) bond length is 0.95 Å. In the eleventh C site, C(31) is bonded in a single-bond geometry to one C(41) and one H(13) atom. The C(31)-C(41) bond length is 1.38 Å. The C(31)-H(13) bond length is 0.95 Å. In the twelfth C site, C(33) is bonded in a distorted single-bond geometry to one C(1), one C(72), and one H(14) atom. The C(33)-C(72) bond length is 1.46 Å. The C(33)-H(14) bond length is 0.95 Å. In the thirteenth C site, C(34) is bonded in a bent 120 degrees geometry to one C(4), one O(13), and one O(9) atom. The C(34)-O(13) bond length is 1.27 Å. The C(34)-O(9) bond length is 1.31 Å. In the fourteenth C site, C(36) is bonded in a distorted single-bond geometry to one C(19), one C(57), and one H(16) atom. The C(36)-C(57) bond length is 1.43 Å. The C(36)-H(16) bond length is 0.95 Å. In the fifteenth C site, C(37) is bonded in a trigonal planar geometry to one C(83), one C(87), and one C(93) atom. The C(37)-C(83) bond length is 1.30 Å. The C(37)-C(87) bond length is 1.48 Å. The C(37)-C(93) bond length is 1.43 Å. In the sixteenth C site, C(41) is bonded in a trigonal planar geometry to one C(31), one C(70), and one C(73) atom. The C(41)-C(70) bond length is 1.31 Å. The C(41)-C(73) bond length is 1.56 Å. In the seventeenth C site, C(42) is bonded in a distorted single-bond geometry to one C(55) and one H(18,61) atom. The C(42)-C(55) bond length is 1.39 Å. The C(42)-H(18,61) bond length is 0.95 Å. In the eighteenth C site, C(43) is bonded in a 2-coordinate geometry to one N(2) and one H(19) atom. The C(43)-N(2) bond length is 1.41 Å. The C(43)-H(19) bond length is 0.95 Å. In the nineteenth C site, C(44) is bonded in a distorted single-bond geometry to one C(1) and one H(20) atom. The C(44)-H(20) bond length is 0.95 Å. In the twentieth C site, C(46) is bonded in a single-bond geometry to one C(94) and one H(22) atom. The C(46)-C(94) bond length is 1.38 Å. The C(46)-H(22) bond length is 0.95 Å. In the twenty-first C site, C(51) is bonded in a distorted single-bond geometry to one C(94) and one H(26) atom. The C(51)-C(94) bond length is 1.35 Å. The C(51)-H(26) bond length is 0.95 Å. In the twenty-second C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(3), and one H(27) atom. The C(52)-N(3) bond length is 1.39 Å. The C(52)-H(27) bond length is 0.95 Å. In the twenty-third C site, C(54) is bonded in a distorted trigonal planar geometry to one C(28), one N(3), and one H(29) atom. The C(54)-N(3) bond length is 1.33 Å. The C(54)-H(29) bond length is 0.95 Å. In the twenty-fourth C site, C(55) is bonded in a trigonal planar geometry to one C(19), one C(42), and one C(90) atom. The C(55)-C(90) bond length is 1.46 Å. In the twenty-fifth C site, C(57) is bonded in a 3-coordinate geometry to one C(36), one N(6), and one H(31) atom. The C(57)-N(6) bond length is 1.42 Å. The C(57)-H(31) bond length is 0.95 Å. In the twenty-sixth C site, C(62) is bonded in a distorted single-bond geometry to one C(4) and one H(34) atom. The C(62)-H(34) bond length is 0.95 Å. In the twenty-seventh C site, C(63) is bonded in a distorted single-bond geometry to one C(87) and one H(35) atom. The C(63)-C(87) bond length is 1.43 Å. The C(63)-H(35) bond length is 0.95 Å. In the twenty-eighth C site, C(70) is bonded in a single-bond geometry to one C(41) and one H(42) atom. The C(70)-H(42) bond length is 0.95 Å. In the twenty-ninth C site, C(72) is bonded in a distorted trigonal planar geometry to one C(33), one C(87), and one H(44) atom. The C(72)-C(87) bond length is 1.34 Å. The C(72)-H(44) bond length is 0.95 Å. In the thirtieth C site, C(73) is bonded in a trigonal planar geometry to one C(28), one C(41), and one C(6) atom. In the thirty-first C site, C(76) is bonded in a distorted single-bond geometry to one C(5) and one H(47) atom. The C(76)-H(47) bond length is 0.95 Å. In the thirty-second C site, C(78) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(49) atom. The C(78)-N(7) bond length is 1.29 Å. The C(78)-H(49) bond length is 0.95 Å. In the thirty-third C site, C(80) is bonded in a distorted bent 120 degrees geometry to one C(83), one N(2), and one H(52) atom. The C(80)-C(83) bond length is 1.38 Å. The C(80)-N(2) bond length is 1.42 Å. The C(80)-H(52) bond length is 0.95 Å. In the thirty-fourth C site, C(83) is bonded in a distorted trigonal planar geometry to one C(37), one C(80), and one H(55) atom. The C(83)-H(55) bond length is 0.95 Å. In the thirty-fifth C site, C(87) is bonded in a trigonal planar geometry to one C(37), one C(63), and one C(72) atom. In the thirty-sixth C site, C(88) is bonded in a distorted single-bond geometry to one C(5) and one H(59) atom. The C(88)-H(59) bond length is 0.95 Å. In the thirty-seventh C site, C(90) is bonded in a single-bond geometry to one C(55) and one H(18,61) atom. The C(90)-H(18,61) bond length is 0.95 Å. In the thirty-eighth C site, C(92) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(63) atom. The C(92)-N(6) bond length is 1.35 Å. The C(92)-H(63) bond length is 0.95 Å. In the thirty-ninth C site, C(93) is bonded in a distorted single-bond geometry to one C(37) and one H(64) atom. The C(93)-H(64) bond length is 0.95 Å. In the fortieth C site, C(94) is bonded in a trigonal planar geometry to one C(46), one C(51), and one C(95) atom. The C(94)-C(95) bond length is 1.59 Å. In the forty-first C site, C(95) is bonded in a bent 120 degrees geometry to one C(94), one O(15), and one O(16) atom. The C(95)-O(15) bond length is 1.17 Å. The C(95)-O(16) bond length is 1.23 Å. In the forty-second C site, C(96) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(50) atom. The C(96)-N(7) bond length is 1.30 Å. The C(96)-H(50) bond length is 1.01 Å. There are four inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(43), and one C(80) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Co(3), one C(52), and one C(54) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Co(1), one C(57), and one C(92) atom. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one Co(3), one C(78), and one C(96) atom. There are twenty-seven inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(24) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(28) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(33) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(31) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(36) atom. In the eighth H site, H(18,61) is bonded in a single-bond geometry to one C(42) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(43) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(44) atom. In the eleventh H site, H(22) is bonded in a single-bond geometry to one C(46) atom. In the twelfth H site, H(26) is bonded in a single-bond geometry to one C(51) atom. In the thirteenth H site, H(27) is bonded in a single-bond geometry to one C(52) atom. In the fourteenth H site, H(29) is bonded in a single-bond geometry to one C(54) atom. In the fifteenth H site, H(31) is bonded in a single-bond geometry to one C(57) atom. In the sixteenth H site, H(34) is bonded in a single-bond geometry to one C(62) atom. In the seventeenth H site, H(35) is bonded in a single-bond geometry to one C(63) atom. In the eighteenth H site, H(44) is bonded in a single-bond geometry to one C(72) atom. In the nineteenth H site, H(47) is bonded in a single-bond geometry to one C(76) atom. In the twentieth H site, H(42) is bonded in a single-bond geometry to one C(70) atom. In the twenty-first H site, H(49) is bonded in a single-bond geometry to one C(78) atom. In the twenty-second H site, H(50) is bonded in a single-bond geometry to one C(96) atom. In the twenty-third H site, H(52) is bonded in a single-bond geometry to one C(80) atom. In the twenty-fourth H site, H(55) is bonded in a single-bond geometry to one C(83) atom. In the twenty-fifth H site, H(59) is bonded in a single-bond geometry to one C(88) atom. In the twenty-sixth H site, H(63) is bonded in a single-bond geometry to one C(92) atom. In the twenty-seventh H site, H(64) is bonded in a single-bond geometry to one C(93) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Co(3) and one C(2) atom. In the second O site, O(3) is bonded in a distorted L-shaped geometry to one Co(1) and one C(10) atom. In the third O site, O(7) is bonded in an L-shaped geometry to one Co(1) and one C(10) atom. In the fourth O site, O(9) is bonded in an L-shaped geometry to one Co(1) and one C(34) atom. In the fifth O site, O(11) is bonded in a distorted L-shaped geometry to one Co(3) and one C(2) atom. In the sixth O site, O(13) is bonded in a distorted L-shaped geometry to one Co(1) and one C(34) atom. In the seventh O site, O(15) is bonded in an L-shaped geometry to one Co(3) and one C(95) atom. In the eighth O site, O(16) is bonded in an L-shaped geometry to one Co(3) and one C(95) atom. In each CoC24H16(NO2)2 cluster, Co(2) is bonded in a 6-coordinate geometry to one N(4), one N(5), one O(10), one O(14), one O(4), and one O(6) atom. The Co(2)-N(4) bond length is 1.98 Å. The Co(2)-N(5) bond length is 2.05 Å. The Co(2)-O(10) bond length is 2.03 Å. The Co(2)-O(14) bond length is 2.35 Å. The Co(2)-O(4) bond length is 2.27 Å. The Co(2)-O(6) bond length is 2.00 Å. There are twenty-four inequivalent C sites. In the first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(10), and one O(4) atom. The C(3)-C(15) bond length is 1.39 Å. The C(3)-O(10) bond length is 1.38 Å. The C(3)-O(4) bond length is 1.27 Å. In the second C site, C(14) is bonded in a trigonal planar geometry to one C(25), one C(49), and one C(61) atom. The C(14)-C(25) bond length is 1.43 Å. The C(14)-C(49) bond length is 1.41 Å. The C(14)-C(61) bond length is 1.38 Å. In the third C site, C(15) is bonded in a trigonal planar geometry to one C(3), one C(47), and one C(64) atom. The C(15)-C(47) bond length is 1.42 Å. The C(15)-C(64) bond length is 1.39 Å. In the fourth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(7) atom. The C(23)-N(4) bond length is 1.37 Å. The C(23)-H(7) bond length is 0.95 Å. In the fifth C site, C(25) is bonded in a single-bond geometry to one C(14) and one H(9) atom. The C(25)-H(9) bond length is 0.95 Å. In the sixth C site, C(26) is bonded in a trigonal planar geometry to one C(38), one C(81), and one C(82) atom. The C(26)-C(38) bond length is 1.55 Å. The C(26)-C(81) bond length is 1.32 Å. The C(26)-C(82) bond length is 1.35 Å. In the seventh C site, C(29) is bonded in a distorted single-bond geometry to one C(58) and one H(11) atom. The C(29)-C(58) bond length is 1.46 Å. The C(29)-H(11) bond length is 0.95 Å. In the eighth C site, C(32) is bonded in a trigonal planar geometry to one C(45), one C(58), and one C(59) atom. The C(32)-C(45) bond length is 1.37 Å. The C(32)-C(58) bond length is 1.45 Å. The C(32)-C(59) bond length is 1.49 Å. In the ninth C site, C(35) is bonded in a 3-coordinate geometry to one C(56), one N(5), and one H(15) atom. The C(35)-C(56) bond length is 1.42 Å. The C(35)-N(5) bond length is 1.39 Å. The C(35)-H(15) bond length is 0.95 Å. In the tenth C site, C(38) is bonded in a trigonal planar geometry to one C(26), one C(71), and one C(77) atom. The C(38)-C(71) bond length is 1.31 Å. The C(38)-C(77) bond length is 1.39 Å. In the eleventh C site, C(45) is bonded in a distorted single-bond geometry to one C(32) and one H(21) atom. The C(45)-H(21) bond length is 0.95 Å. In the twelfth C site, C(47) is bonded in a distorted single-bond geometry to one C(15), one C(77), and one H(23) atom. The C(47)-C(77) bond length is 1.35 Å. The C(47)-H(23) bond length is 0.95 Å. In the thirteenth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(24) atom. The C(48)-N(4) bond length is 1.36 Å. The C(48)-H(24) bond length is 0.95 Å. In the fourteenth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(14), and one O(6) atom. The C(49)-O(14) bond length is 1.30 Å. The C(49)-O(6) bond length is 1.36 Å. In the fifteenth C site, C(56) is bonded in a distorted single-bond geometry to one C(35), one C(58), and one H(30) atom. The C(56)-C(58) bond length is 1.41 Å. The C(56)-H(30) bond length is 0.95 Å. In the sixteenth C site, C(58) is bonded in a trigonal planar geometry to one C(29), one C(32), and one C(56) atom. In the seventeenth C site, C(59) is bonded in a single-bond geometry to one C(32) and one H(32) atom. The C(59)-H(32) bond length is 0.95 Å. In the eighteenth C site, C(61) is bonded in a distorted single-bond geometry to one C(14) and one H(33) atom. The C(61)-H(33) bond length is 0.95 Å. In the nineteenth C site, C(64) is bonded in a distorted single-bond geometry to one C(15) and one H(36) atom. The C(64)-H(36) bond length is 0.95 Å. In the twentieth C site, C(71) is bonded in a distorted single-bond geometry to one C(38) and one H(43) atom. The C(71)-H(43) bond length is 0.95 Å. In the twenty-first C site, C(75) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(46) atom. The C(75)-N(5) bond length is 1.29 Å. The C(75)-H(46) bond length is 0.95 Å. In the twenty-second C site, C(77) is bonded in a distorted single-bond geometry to one C(38), one C(47), and one H(48) atom. The C(77)-H(48) bond length is 0.95 Å. In the twenty-third C site, C(81) is bonded in a single-bond geometry to one C(26) and one H(53) atom. The C(81)-H(53) bond length is 0.95 Å. In the twenty-fourth C site, C(82) is bonded in a distorted single-bond geometry to one C(26) and one H(54) atom. The C(82)-H(54) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Co(2), one C(23), and one C(48) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Co(2), one C(35), and one C(75) atom. There are sixteen inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(23) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(25) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(29) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(35) atom. In the fifth H site, H(21) is bonded in a single-bond geometry to one C(45) atom. In the sixth H site, H(23) is bonded in a single-bond geometry to one C(47) atom. In the seventh H site, H(24) is bonded in a single-bond geometry to one C(48) atom. In the eighth H site, H(30) is bonded in a single-bond geometry to one C(56) atom. In the ninth H site, H(33) is bonded in a single-bond geometry to one C(61) atom. In the tenth H site, H(32) is bonded in a single-bond geometry to one C(59) atom. In the eleventh H site, H(36) is bonded in a single-bond geometry to one C(64) atom. In the twelfth H site, H(43) is bonded in a single-bond geometry to one C(71) atom. In the thirteenth H site, H(46) is bonded in a single-bond geometry to one C(75) atom. In the fourteenth H site, H(48) is bonded in a single-bond geometry to one C(77) atom. In the fifteenth H site, H(53) is bonded in a single-bond geometry to one C(81) atom. In the sixteenth H site, H(54) is bonded in a single-bond geometry to one C(82) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted L-shaped geometry to one Co(2) and one C(3) atom. In the second O site, O(6) is bonded in an L-shaped geometry to one Co(2) and one C(49) atom. In the third O site, O(10) is bonded in an L-shaped geometry to one Co(2) and one C(3) atom. In the fourth O site, O(14) is bonded in a distorted L-shaped geometry to one Co(2) and one C(49) atom. Linkers: 32 [O]C(=O)c1ccc(-c2ccncc2)cc1. Metal clusters: 16 [C]1O[Co]2(O1)O[C]O2. The MOF has largest included sphere 9.22 A, density 0.93 g/cm3, surface area 4739.51 m2/g, accessible volume 0.49 cm3/g