In10C7H3(NS4)4(In5C4H2(NS4)2)2(CH)13 crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of fifty-two 02329_fluka molecules, one In10C7H3(NS4)4 framework, and one In5C4H2(NS4)2 framework. In the In10C7H3(NS4)4 framework, there are ten inequivalent In sites. In the first In site, In(1) is bonded to one N(1), one S(1), one S(2), and one S(3) atom to form corner-sharing InS3N tetrahedra. The In(1)-N(1) bond length is 2.17 Å. The In(1)-S(1) bond length is 2.43 Å. The In(1)-S(2) bond length is 2.43 Å. The In(1)-S(3) bond length is 2.41 Å. In the second In site, In(2) is bonded to one S(1), one S(4), one S(5), and one S(6) atom to form InS4 tetrahedra that share  a cornercorner with one In(1)S3N tetrahedra,  a cornercorner with one In(5)S3N tetrahedra,  a cornercorner with one In(3)S4 tetrahedra,  a cornercorner with one In(4)S4 tetrahedra,  a cornercorner with one In(6)S4 tetrahedra, and  a cornercorner with one In(7)S4 tetrahedra. The In(2)-S(1) bond length is 2.40 Å. The In(2)-S(4) bond length is 2.41 Å. The In(2)-S(5) bond length is 2.51 Å. The In(2)-S(6) bond length is 2.51 Å. In the third In site, In(3) is bonded to one S(2), one S(5), one S(7), and one S(8) atom to form InS4 tetrahedra that share  a cornercorner with one In(1)S3N tetrahedra,  a cornercorner with one In(8)S3N tetrahedra,  a cornercorner with one In(2)S4 tetrahedra,  a cornercorner with one In(4)S4 tetrahedra,  a cornercorner with one In(6)S4 tetrahedra, and  a cornercorner with one In(9)S4 tetrahedra. The In(3)-S(2) bond length is 2.41 Å. The In(3)-S(5) bond length is 2.52 Å. The In(3)-S(7) bond length is 2.41 Å. The In(3)-S(8) bond length is 2.49 Å. In the fourth In site, In(4) is bonded to one S(3), one S(6), one S(8), and one S(9) atom to form InS4 tetrahedra that share  a cornercorner with one In(1)S3N tetrahedra,  a cornercorner with one In(10)S3N tetrahedra,  a cornercorner with one In(2)S4 tetrahedra,  a cornercorner with one In(3)S4 tetrahedra,  a cornercorner with one In(7)S4 tetrahedra, and  a cornercorner with one In(9)S4 tetrahedra. The In(4)-S(3) bond length is 2.41 Å. The In(4)-S(6) bond length is 2.52 Å. The In(4)-S(8) bond length is 2.52 Å. The In(4)-S(9) bond length is 2.41 Å. In the fifth In site, In(5) is bonded to one N(3), one S(10), one S(11), and one S(4) atom to form corner-sharing InS3N tetrahedra. The In(5)-N(3) bond length is 2.18 Å. The In(5)-S(10) bond length is 2.42 Å. The In(5)-S(11) bond length is 2.44 Å. The In(5)-S(4) bond length is 2.42 Å. In the sixth In site, In(6) is bonded to one S(10), one S(12), one S(13), and one S(5) atom to form InS4 tetrahedra that share  a cornercorner with one In(5)S3N tetrahedra,  a cornercorner with one In(8)S3N tetrahedra,  a cornercorner with one In(2)S4 tetrahedra,  a cornercorner with one In(3)S4 tetrahedra,  a cornercorner with one In(7)S4 tetrahedra, and  a cornercorner with one In(9)S4 tetrahedra. The In(6)-S(10) bond length is 2.40 Å. The In(6)-S(12) bond length is 2.41 Å. The In(6)-S(13) bond length is 2.50 Å. The In(6)-S(5) bond length is 2.49 Å. In the seventh In site, In(7) is bonded to one S(11), one S(13), one S(14), and one S(6) atom to form InS4 tetrahedra that share  a cornercorner with one In(10)S3N tetrahedra,  a cornercorner with one In(5)S3N tetrahedra,  a cornercorner with one In(2)S4 tetrahedra,  a cornercorner with one In(4)S4 tetrahedra,  a cornercorner with one In(6)S4 tetrahedra, and  a cornercorner with one In(9)S4 tetrahedra. The In(7)-S(11) bond length is 2.40 Å. The In(7)-S(13) bond length is 2.52 Å. The In(7)-S(14) bond length is 2.40 Å. The In(7)-S(6) bond length is 2.51 Å. In the eighth In site, In(8) is bonded to one N(2), one S(12), one S(15), and one S(7) atom to form distorted corner-sharing InS3N tetrahedra. The In(8)-N(2) bond length is 2.18 Å. The In(8)-S(12) bond length is 2.44 Å. The In(8)-S(15) bond length is 2.40 Å. The In(8)-S(7) bond length is 2.45 Å. In the ninth In site, In(9) is bonded to one S(13), one S(15), one S(16), and one S(8) atom to form InS4 tetrahedra that share  a cornercorner with one In(10)S3N tetrahedra,  a cornercorner with one In(8)S3N tetrahedra,  a cornercorner with one In(3)S4 tetrahedra,  a cornercorner with one In(4)S4 tetrahedra,  a cornercorner with one In(6)S4 tetrahedra, and  a cornercorner with one In(7)S4 tetrahedra. The In(9)-S(13) bond length is 2.49 Å. The In(9)-S(15) bond length is 2.41 Å. The In(9)-S(16) bond length is 2.41 Å. The In(9)-S(8) bond length is 2.51 Å. In the tenth In site, In(10) is bonded to one N(4), one S(14), one S(16), and one S(9) atom to form corner-sharing InS3N tetrahedra. The In(10)-N(4) bond length is 2.19 Å. The In(10)-S(14) bond length is 2.42 Å. The In(10)-S(16) bond length is 2.42 Å. The In(10)-S(9) bond length is 2.42 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one N(1) atom. The C(2)-N(1) bond length is 1.43 Å. In the third C site, C(7) is bonded in a distorted single-bond geometry to one N(2) atom. The C(7)-N(2) bond length is 1.38 Å. In the fourth C site, C(8) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(6) atom. The C(8)-N(3) bond length is 1.38 Å. The C(8)-N(4) bond length is 1.32 Å. The C(8)-H(6) bond length is 0.95 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(14) and one N(4) atom. The C(9)-C(14) bond length is 1.38 Å. The C(9)-N(4) bond length is 1.37 Å. In the sixth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(10) atom. The C(13)-C(14) bond length is 1.34 Å. The C(13)-H(10) bond length is 0.95 Å. In the seventh C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(9), and one N(3) atom. The C(14)-N(3) bond length is 1.42 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one In(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one In(8), one C(1), and one C(7) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one In(5), one C(14), and one C(8) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one In(10), one C(8), and one C(9) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(13) atom. There are sixteen inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one In(1) and one In(2) atom. In the second S site, S(2) is bonded in a water-like geometry to one In(1) and one In(3) atom. In the third S site, S(3) is bonded in a water-like geometry to one In(1) and one In(4) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one In(2) and one In(5) atom. In the fifth S site, S(5) is bonded in a trigonal non-coplanar geometry to one In(2), one In(3), and one In(6) atom. In the sixth S site, S(6) is bonded in a trigonal non-coplanar geometry to one In(2), one In(4), and one In(7) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one In(3) and one In(8) atom. In the eighth S site, S(8) is bonded in a trigonal non-coplanar geometry to one In(3), one In(4), and one In(9) atom. In the ninth S site, S(9) is bonded in a water-like geometry to one In(10) and one In(4) atom. In the tenth S site, S(10) is bonded in a water-like geometry to one In(5) and one In(6) atom. In the eleventh S site, S(11) is bonded in a water-like geometry to one In(5) and one In(7) atom. In the twelfth S site, S(12) is bonded in a water-like geometry to one In(6) and one In(8) atom. In the thirteenth S site, S(13) is bonded in a trigonal non-coplanar geometry to one In(6), one In(7), and one In(9) atom. In the fourteenth S site, S(14) is bonded in a water-like geometry to one In(10) and one In(7) atom. In the fifteenth S site, S(15) is bonded in a water-like geometry to one In(8) and one In(9) atom. In the sixteenth S site, S(16) is bonded in a water-like geometry to one In(10) and one In(9) atom. In the In5C4H2(NS4)2 framework, there are ten inequivalent In sites. In the first In site, In(11) is bonded to one N(5), one S(17), one S(18), and one S(19) atom to form corner-sharing InS3N tetrahedra. The In(11)-N(5) bond length is 2.20 Å. The In(11)-S(17) bond length is 2.41 Å. The In(11)-S(18) bond length is 2.43 Å. The In(11)-S(19) bond length is 2.43 Å. In the second In site, In(12) is bonded to one S(17), one S(20), one S(21), and one S(22) atom to form InS4 tetrahedra that share  a cornercorner with one In(11)S3N tetrahedra,  a cornercorner with one In(15)S3N tetrahedra,  a cornercorner with one In(13)S4 tetrahedra,  a cornercorner with one In(14)S4 tetrahedra,  a cornercorner with one In(16)S4 tetrahedra, and  a cornercorner with one In(17)S4 tetrahedra. The In(12)-S(17) bond length is 2.43 Å. The In(12)-S(20) bond length is 2.40 Å. The In(12)-S(21) bond length is 2.51 Å. The In(12)-S(22) bond length is 2.50 Å. In the third In site, In(13) is bonded to one S(18), one S(21), one S(23), and one S(24) atom to form InS4 tetrahedra that share  a cornercorner with one In(11)S3N tetrahedra,  a cornercorner with one In(18)S3N tetrahedra,  a cornercorner with one In(12)S4 tetrahedra,  a cornercorner with one In(14)S4 tetrahedra,  a cornercorner with one In(16)S4 tetrahedra, and  a cornercorner with one In(19)S4 tetrahedra. The In(13)-S(18) bond length is 2.42 Å. The In(13)-S(21) bond length is 2.51 Å. The In(13)-S(23) bond length is 2.41 Å. The In(13)-S(24) bond length is 2.51 Å. In the fourth In site, In(14) is bonded to one S(19), one S(22), one S(24), and one S(25) atom to form InS4 tetrahedra that share  a cornercorner with one In(11)S3N tetrahedra,  a cornercorner with one In(20)S3N tetrahedra,  a cornercorner with one In(12)S4 tetrahedra,  a cornercorner with one In(13)S4 tetrahedra,  a cornercorner with one In(17)S4 tetrahedra, and  a cornercorner with one In(19)S4 tetrahedra. The In(14)-S(19) bond length is 2.42 Å. The In(14)-S(22) bond length is 2.50 Å. The In(14)-S(24) bond length is 2.49 Å. The In(14)-S(25) bond length is 2.42 Å. In the fifth In site, In(15) is bonded to one N(7), one S(20), one S(26), and one S(27) atom to form corner-sharing InS3N tetrahedra. The In(15)-N(7) bond length is 2.18 Å. The In(15)-S(20) bond length is 2.42 Å. The In(15)-S(26) bond length is 2.43 Å. The In(15)-S(27) bond length is 2.40 Å. In the sixth In site, In(16) is bonded to one S(21), one S(26), one S(28), and one S(29) atom to form InS4 tetrahedra that share  a cornercorner with one In(15)S3N tetrahedra,  a cornercorner with one In(18)S3N tetrahedra,  a cornercorner with one In(12)S4 tetrahedra,  a cornercorner with one In(13)S4 tetrahedra,  a cornercorner with one In(17)S4 tetrahedra, and  a cornercorner with one In(19)S4 tetrahedra. The In(16)-S(21) bond length is 2.51 Å. The In(16)-S(26) bond length is 2.41 Å. The In(16)-S(28) bond length is 2.40 Å. The In(16)-S(29) bond length is 2.49 Å. In the seventh In site, In(17) is bonded to one S(22), one S(27), one S(29), and one S(30) atom to form InS4 tetrahedra that share  a cornercorner with one In(15)S3N tetrahedra,  a cornercorner with one In(20)S3N tetrahedra,  a cornercorner with one In(12)S4 tetrahedra,  a cornercorner with one In(14)S4 tetrahedra,  a cornercorner with one In(16)S4 tetrahedra, and  a cornercorner with one In(19)S4 tetrahedra. The In(17)-S(22) bond length is 2.52 Å. The In(17)-S(27) bond length is 2.41 Å. The In(17)-S(29) bond length is 2.51 Å. The In(17)-S(30) bond length is 2.40 Å. In the eighth In site, In(18) is bonded to one N(8), one S(23), one S(28), and one S(31) atom to form corner-sharing InS3N tetrahedra. The In(18)-N(8) bond length is 2.21 Å. The In(18)-S(23) bond length is 2.41 Å. The In(18)-S(28) bond length is 2.42 Å. The In(18)-S(31) bond length is 2.42 Å. In the ninth In site, In(19) is bonded to one S(24), one S(29), one S(31), and one S(32) atom to form InS4 tetrahedra that share  a cornercorner with one In(18)S3N tetrahedra,  a cornercorner with one In(20)S3N tetrahedra,  a cornercorner with one In(13)S4 tetrahedra,  a cornercorner with one In(14)S4 tetrahedra,  a cornercorner with one In(16)S4 tetrahedra, and  a cornercorner with one In(17)S4 tetrahedra. The In(19)-S(24) bond length is 2.51 Å. The In(19)-S(29) bond length is 2.51 Å. The In(19)-S(31) bond length is 2.40 Å. The In(19)-S(32) bond length is 2.40 Å. In the tenth In site, In(20) is bonded to one N(6), one S(25), one S(30), and one S(32) atom to form corner-sharing InS3N tetrahedra. The In(20)-N(6) bond length is 2.21 Å. The In(20)-S(25) bond length is 2.44 Å. The In(20)-S(30) bond length is 2.41 Å. The In(20)-S(32) bond length is 2.41 Å. There are eight inequivalent C sites. In the first C site, C(15) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(11) atom. The C(15)-N(5) bond length is 1.32 Å. The C(15)-N(6) bond length is 1.29 Å. The C(15)-H(11) bond length is 0.95 Å. In the second C site, C(16) is bonded in a distorted single-bond geometry to one N(5) atom. The C(16)-N(5) bond length is 1.37 Å. In the third C site, C(19) is bonded in a distorted single-bond geometry to one C(20) and one H(14) atom. The C(19)-C(20) bond length is 1.37 Å. The C(19)-H(14) bond length is 0.95 Å. In the fourth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one H(15) atom. The C(20)-C(21) bond length is 1.31 Å. The C(20)-H(15) bond length is 0.95 Å. In the fifth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one N(6) atom. The C(21)-N(6) bond length is 1.41 Å. In the sixth C site, C(22) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(16) atom. The C(22)-N(7) bond length is 1.34 Å. The C(22)-N(8) bond length is 1.32 Å. The C(22)-H(16) bond length is 0.95 Å. In the seventh C site, C(23) is bonded in a distorted single-bond geometry to one N(7) atom. The C(23)-N(7) bond length is 1.39 Å. In the eighth C site, C(28) is bonded in a distorted single-bond geometry to one N(8) atom. The C(28)-N(8) bond length is 1.37 Å. There are four inequivalent N sites. In the first N site, N(5) is bonded in a distorted trigonal planar geometry to one In(11), one C(15), and one C(16) atom. In the second N site, N(6) is bonded in a trigonal planar geometry to one In(20), one C(15), and one C(21) atom. In the third N site, N(7) is bonded in a trigonal planar geometry to one In(15), one C(22), and one C(23) atom. In the fourth N site, N(8) is bonded in a trigonal planar geometry to one In(18), one C(22), and one C(28) atom. There are four inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the second H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. There are sixteen inequivalent S sites. In the first S site, S(17) is bonded in a water-like geometry to one In(11) and one In(12) atom. In the second S site, S(18) is bonded in a water-like geometry to one In(11) and one In(13) atom. In the third S site, S(19) is bonded in a water-like geometry to one In(11) and one In(14) atom. In the fourth S site, S(20) is bonded in a water-like geometry to one In(12) and one In(15) atom. In the fifth S site, S(21) is bonded in a trigonal non-coplanar geometry to one In(12), one In(13), and one In(16) atom. In the sixth S site, S(22) is bonded in a trigonal non-coplanar geometry to one In(12), one In(14), and one In(17) atom. In the seventh S site, S(23) is bonded in a water-like geometry to one In(13) and one In(18) atom. In the eighth S site, S(24) is bonded in a trigonal non-coplanar geometry to one In(13), one In(14), and one In(19) atom. In the ninth S site, S(25) is bonded in a water-like geometry to one In(14) and one In(20) atom. In the tenth S site, S(26) is bonded in a water-like geometry to one In(15) and one In(16) atom. In the eleventh S site, S(27) is bonded in a water-like geometry to one In(15) and one In(17) atom. In the twelfth S site, S(28) is bonded in a water-like geometry to one In(16) and one In(18) atom. In the thirteenth S site, S(29) is bonded in a trigonal non-coplanar geometry to one In(16), one In(17), and one In(19) atom. In the fourteenth S site, S(30) is bonded in a water-like geometry to one In(17) and one In(20) atom. In the fifteenth S site, S(31) is bonded in a water-like geometry to one In(18) and one In(19) atom. In the sixteenth S site, S(32) is bonded in a water-like geometry to one In(19) and one In(20) atom. Linkers: 16 C1=Nc2ccccc2[N]1. Metal clusters: 8 [S][In]1S[In]2S[In]([S])S[In]3S[In]4S[In](S1)S[In]1S[In](S[In]([S])S2)S[In](S3)[S]41. The MOF has largest included sphere 6.95 A, density 1.53 g/cm3, surface area 2409.52 m2/g, accessible volume 0.46 cm3/g