(CdH6(C5O2)2)2CdH4(C2O)4(CH)6(C2O)4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules, sixteen dimethyl ether molecules, four CdH4(C2O)4 clusters, and eight CdH6(C5O2)2 clusters. In each CdH4(C2O)4 cluster, Cd(2) is bonded in a rectangular see-saw-like geometry to two equivalent O(7) and two equivalent O(8) atoms. Both Cd(2)-O(7) bond lengths are 2.43 Å. Both Cd(2)-O(8) bond lengths are 2.30 Å. There are four inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-H(5) bond length is 0.93 Å. In the second C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(21), and one C(9) atom. The C(10)-C(11) bond length is 1.37 Å. The C(10)-C(21) bond length is 1.50 Å. In the third C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(6) atom. The C(11)-H(6) bond length is 0.93 Å. In the fourth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(10), one O(7), and one O(8) atom. The C(21)-O(7) bond length is 1.23 Å. The C(21)-O(8) bond length is 1.25 Å. There are two inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent O sites. In the first O site, O(7) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(21) atom. In the second O site, O(8) is bonded in a distorted single-bond geometry to one Cd(2) and one C(21) atom. In each CdH6(C5O2)2 cluster, Cd(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(5), and one O(6) atom. The Cd(1)-O(1) bond length is 2.45 Å. The Cd(1)-O(2) bond length is 2.26 Å. The Cd(1)-O(5) bond length is 2.39 Å. The Cd(1)-O(6) bond length is 2.29 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(7) is bonded in a single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the sixth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(9) atom. The C(16)-C(17) bond length is 1.35 Å. The C(16)-H(9) bond length is 0.93 Å. In the seventh C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.37 Å. The C(17)-C(20) bond length is 1.48 Å. In the eighth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(10) atom. The C(18)-C(19) bond length is 1.45 Å. The C(18)-H(10) bond length is 0.93 Å. In the ninth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(11) atom. The C(19)-H(11) bond length is 0.93 Å. In the tenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(5), and one O(6) atom. The C(20)-O(5) bond length is 1.26 Å. The C(20)-O(6) bond length is 1.25 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the second O site, O(1) is bonded in a single-bond geometry to one Cd(1) and one C(1) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one C(20) atom. In the fourth O site, O(6) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(20) atom. Linkers: 4 [O]C(=O)c1ccc(Oc2cc(Oc3ccc(C([O])=O)cc3)cc(C([O])=O)c2)cc1 ,2 [C]=C(/C=C\[C][C]=O)Oc1cc(Oc2ccc(C([O])=O)cc2)cc(C([O])=O)c1 ,2 [C][CH]/C(=C\[C][C]=O)Oc1ccc(C([O])=O)cc1. Metal clusters: 6 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 10.74 A, density 1.04 g/cm3, surface area 4027.31 m2/g, accessible volume 0.58 cm3/g