Cu(OOCC6H4COO)(CuC17NH8O4)2(CH)4(C4H3)4 is Indium-derived structured and crystallizes in the cubic Pm-3m space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules, twelve C4H3 clusters, three Cu(OOCC6H4COO) clusters, and one CuC17NH8O4 cluster. In each C4H3 cluster, there are four inequivalent C sites. In the first C site, C(12) is bonded in a trigonal planar geometry to one C(9) and two equivalent C(8) atoms. The C(12)-C(9) bond length is 1.49 Å. Both C(12)-C(8) bond lengths are 1.37 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(9) and one H(2) atom. The C(4)-C(9) bond length is 1.39 Å. The C(4)-H(2) bond length is 0.93 Å. In the third C site, C(8) is bonded in a single-bond geometry to one C(12) and one H(7) atom. The C(8)-H(7) bond length is 0.93 Å. In the fourth C site, C(9) is bonded in a 5-coordinate geometry to one C(12) and four equivalent C(4) atoms. There are two inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In each Cu(OOCC6H4COO) cluster, Cu(1) is bonded in a distorted square co-planar geometry to four equivalent O(3) atoms. All Cu(1)-O(3) bond lengths are 1.96 Å. There are three inequivalent C sites. In the first C site, C(16) is bonded in a trigonal planar geometry to one C(7) and two equivalent C(15) atoms. The C(16)-C(7) bond length is 1.52 Å. Both C(16)-C(15) bond lengths are 1.38 Å. In the second C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(3) atom. The C(15)-H(3) bond length is 0.93 Å. In the third C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(16) and two equivalent O(3) atoms. Both C(7)-O(3) bond lengths are 1.27 Å. H(3) is bonded in a single-bond geometry to one C(15) atom. O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the CuC17NH8O4 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(2) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. All Cu(2)-O(1) bond lengths are 1.96 Å. In the second Cu site, Cu(3) is bonded in a distorted square co-planar geometry to four equivalent O(2) atoms. All Cu(3)-O(2) bond lengths are 1.96 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to four equivalent C(2) and one N(1) atom. All C(1)-C(2) bond lengths are 1.36 Å. The C(1)-N(1) bond length is 1.45 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(2)-H(4) bond length is 0.93 Å. In the third C site, C(13) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(13)-C(11) bond length is 1.38 Å. The C(13)-C(13) bond length is 1.44 Å. The C(13)-C(14) bond length is 1.42 Å. In the fourth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one N(1) atom. The C(14)-N(1) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(5)-C(10) bond length is 1.41 Å. The C(5)-H(5) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a bent 120 degrees geometry to one C(10), one O(1), and one O(2) atom. The C(6)-C(10) bond length is 1.48 Å. The C(6)-O(1) bond length is 1.26 Å. The C(6)-O(2) bond length is 1.26 Å. In the seventh C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(5), and one C(6) atom. The C(10)-C(11) bond length is 1.38 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(13), and one H(6) atom. The C(11)-H(6) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one C(1) and two equivalent C(14) atoms. There are three inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(6) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one C(6) atom. Linkers: 2 [C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@@H]4[C@H]5[C@@H]([C@@H]41)C235.[O]C(=O)C1=C[C]2C(=Nc3ccc(C([O])=O)cc32)C=C1.[O]C(=O)c1cc[c]cc1 ,4 [C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@@H]4[C@H]5[C@@H]([C@@H]41)C235.[O]C(=O)C1=CC=C2N=c3ccc(C([O])=O)cc3=C2[CH]1.[O]C(=O)c1cc[c]cc1 ,1 [C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@H]4[C@@H]5[C@H]([C@H]41)C235.[O]C(=O)C1=C[C]2C(=Nc3ccc(C([O])=O)cc32)C=C1.[O]C(=O)c1cc[c]cc1 ,3 [C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@@H]4[C@H]5[C@@H]([C@@H]41)C235.[O]C(=O)C1=C[CH]C2=Nc3ccc(C([O])=O)cc3C2=C1.[O]C(=O)c1cc[c]cc1 ,1 [C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@H]4[C@@H]5[C@H]([C@H]41)C235.[O]C(=O)C1=C[CH]C2=Nc3ccc(C([O])=O)cc3C2=C1.[O]C(=O)c1cc[c]cc1 ,1 [C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@H]4[C@@H]5[C@H]([C@H]41)C235.[O]C(=O)C1=CC2=c3cc(C([O])=O)ccc3=N[C]2C=C1.[O]C(=O)c1cc[c]cc1. Metal clusters: 9 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: gee. The MOF has largest included sphere 28.54 A, density 0.30 g/cm3, surface area 4039.24 m2/g, accessible volume 2.77 cm3/g