Zn2C26N2H15O9(CH2)11(CH3)2(C3H2)2C8H7OC15H12O2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight (1e)-1-ethoxy-2,3-dimethylbuta-1,3-diene molecules; eighty-eight 02329_fluka molecules; sixteen 02329_fluka molecules; eight 2,3-dimethyl-1,3-butadiene molecules; eight C15H12O2 clusters; and eight Zn2C26N2H15O9 clusters. In each C15H12O2 cluster, there are fifteen inequivalent C sites. In the first C site, C(26) is bonded in a distorted single-bond geometry to one C(27) and one H(16) atom. The C(26)-C(27) bond length is 1.48 Å. The C(26)-H(16) bond length is 0.95 Å. In the second C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(30) atom. The C(27)-C(28) bond length is 1.36 Å. The C(27)-C(30) bond length is 1.63 Å. In the third C site, C(28) is bonded in a distorted single-bond geometry to one C(27) and one H(17) atom. The C(28)-H(17) bond length is 0.95 Å. In the fourth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(27), one C(31), and one C(32) atom. The C(30)-C(31) bond length is 1.62 Å. The C(30)-C(32) bond length is 1.15 Å. In the fifth C site, C(31) is bonded in a single-bond geometry to one C(30) and one H(19) atom. The C(31)-H(19) bond length is 0.95 Å. In the sixth C site, C(32) is bonded in a 3-coordinate geometry to one C(30), one C(33), and one O(11) atom. The C(32)-C(33) bond length is 1.41 Å. The C(32)-O(11) bond length is 1.56 Å. In the seventh C site, C(33) is bonded in a single-bond geometry to one C(32), one C(34), and one H(20) atom. The C(33)-C(34) bond length is 1.24 Å. The C(33)-H(20) bond length is 0.95 Å. In the eighth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(36) atom. The C(34)-C(35) bond length is 1.50 Å. The C(34)-C(36) bond length is 1.55 Å. In the ninth C site, C(35) is bonded in a distorted single-bond geometry to one C(34) and one O(12) atom. The C(35)-O(12) bond length is 1.44 Å. In the tenth C site, C(36) is bonded in a trigonal planar geometry to one C(34), one C(37), and one C(41) atom. The C(36)-C(37) bond length is 1.44 Å. The C(36)-C(41) bond length is 1.38 Å. In the eleventh C site, C(37) is bonded in a distorted single-bond geometry to one C(36) and one H(21) atom. The C(37)-H(21) bond length is 0.95 Å. In the twelfth C site, C(41) is bonded in a distorted single-bond geometry to one C(36) and one H(24) atom. The C(41)-H(24) bond length is 0.95 Å. In the thirteenth C site, C(43) is bonded in a distorted tetrahedral geometry to one C(44), one H(25), one H(26), and one O(11) atom. The C(43)-C(44) bond length is 1.17 Å. The C(43)-H(25) bond length is 0.99 Å. The C(43)-H(26) bond length is 0.99 Å. The C(43)-O(11) bond length is 1.50 Å. In the fourteenth C site, C(44) is bonded in a distorted water-like geometry to one C(43), one H(27), and one H(28) atom. The C(44)-H(27) bond length is 0.99 Å. The C(44)-H(28) bond length is 0.99 Å. In the fifteenth C site, C(51) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(42,43) and one O(12) atom. Both C(51)-H(42,43) bond lengths are 0.99 Å. The C(51)-O(12) bond length is 1.44 Å. There are eleven inequivalent H sites. In the first H site, H(16) is bonded in a single-bond geometry to one C(26) atom. In the second H site, H(17) is bonded in a single-bond geometry to one C(28) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(31) atom. In the fourth H site, H(20) is bonded in a distorted bent 150 degrees geometry to one C(33) and one H(28) atom. The H(20)-H(28) bond length is 0.95 Å. In the fifth H site, H(21) is bonded in a single-bond geometry to one C(37) atom. In the sixth H site, H(24) is bonded in a single-bond geometry to one C(41) atom. In the seventh H site, H(25) is bonded in a single-bond geometry to one C(43) atom. In the eighth H site, H(26) is bonded in a single-bond geometry to one C(43) atom. In the ninth H site, H(27) is bonded in a single-bond geometry to one C(44) atom. In the tenth H site, H(28) is bonded in a distorted single-bond geometry to one C(44) and one H(20) atom. In the eleventh H site, H(42,43) is bonded in a single-bond geometry to one C(51) atom. There are two inequivalent O sites. In the first O site, O(11) is bonded in a bent 120 degrees geometry to one C(32) and one C(43) atom. In the second O site, O(12) is bonded in a bent 120 degrees geometry to one C(35) and one C(51) atom. In each Zn2C26N2H15O9 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(10), one O(2), one O(4), and one O(8) atom. The Zn(1)-N(1) bond length is 2.09 Å. The Zn(1)-O(10) bond length is 2.02 Å. The Zn(1)-O(2) bond length is 2.02 Å. The Zn(1)-O(4) bond length is 1.98 Å. The Zn(1)-O(8) bond length is 2.03 Å. In the second Zn site, Zn(2) is bonded in a trigonal bipyramidal geometry to one N(2), one O(1), one O(3), one O(7), and one O(9) atom. The Zn(2)-N(2) bond length is 1.99 Å. The Zn(2)-O(1) bond length is 2.03 Å. The Zn(2)-O(3) bond length is 2.06 Å. The Zn(2)-O(7) bond length is 2.03 Å. The Zn(2)-O(9) bond length is 2.04 Å. There are twenty-six inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.45 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.21 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.95 Å. In the fifth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one O(6) atom. The C(11)-C(12) bond length is 1.29 Å. The C(11)-O(6) bond length is 1.44 Å. In the sixth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.48 Å. The C(12)-C(14) bond length is 1.46 Å. In the seventh C site, C(13) is bonded in a single-bond geometry to one C(12) and one H(6) atom. The C(13)-H(6) bond length is 0.95 Å. In the eighth C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.28 Å. The C(14)-C(19) bond length is 1.42 Å. In the ninth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(7) atom. The C(15)-C(16) bond length is 1.47 Å. The C(15)-H(7) bond length is 0.95 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one H(8) atom. The C(16)-C(17) bond length is 1.33 Å. The C(16)-H(8) bond length is 0.95 Å. In the eleventh C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.36 Å. The C(17)-C(20) bond length is 1.53 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(9) atom. The C(18)-H(9) bond length is 0.95 Å. In the thirteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(10) atom. The C(19)-H(10) bond length is 0.95 Å. In the fourteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(3), and one O(4) atom. The C(20)-O(3) bond length is 1.16 Å. The C(20)-O(4) bond length is 1.31 Å. In the fifteenth C site, C(23) is bonded in a bent 120 degrees geometry to one C(24), one O(7), and one O(8) atom. The C(23)-C(24) bond length is 1.47 Å. The C(23)-O(7) bond length is 1.30 Å. The C(23)-O(8) bond length is 1.21 Å. In the sixteenth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(29) atom. The C(24)-C(25) bond length is 1.41 Å. The C(24)-C(29) bond length is 1.39 Å. In the seventeenth C site, C(25) is bonded in a single-bond geometry to one C(24) and one H(15) atom. The C(25)-H(15) bond length is 0.95 Å. In the eighteenth C site, C(29) is bonded in a distorted single-bond geometry to one C(24) and one H(18) atom. The C(29)-H(18) bond length is 0.95 Å. In the nineteenth C site, C(38) is bonded in a single-bond geometry to one C(39) and one H(22) atom. The C(38)-C(39) bond length is 1.44 Å. The C(38)-H(22) bond length is 0.95 Å. In the twentieth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(42) atom. The C(39)-C(40) bond length is 1.35 Å. The C(39)-C(42) bond length is 1.49 Å. In the twenty-first C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one H(23) atom. The C(40)-H(23) bond length is 0.95 Å. In the twenty-second C site, C(42) is bonded in a bent 120 degrees geometry to one C(39), one O(10), and one O(9) atom. The C(42)-O(10) bond length is 1.25 Å. The C(42)-O(9) bond length is 1.26 Å. In the twenty-third C site, C(59) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(59) atom. The C(59)-N(1) bond length is 1.19 Å. The C(59)-H(59) bond length is 0.95 Å. In the twenty-fourth C site, C(63) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(62) atom. The C(63)-N(1) bond length is 1.26 Å. The C(63)-H(62) bond length is 0.95 Å. In the twenty-fifth C site, C(64) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(63) atom. The C(64)-N(2) bond length is 1.31 Å. The C(64)-H(63) bond length is 0.95 Å. In the twenty-sixth C site, C(68) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(66) atom. The C(68)-N(2) bond length is 1.37 Å. The C(68)-H(66) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(59), and one C(63) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(64), and one C(68) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(29) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(38) atom. In the eleventh H site, H(23) is bonded in a single-bond geometry to one C(40) atom. In the twelfth H site, H(59) is bonded in a single-bond geometry to one C(59) atom. In the thirteenth H site, H(62) is bonded in a single-bond geometry to one C(63) atom. In the fourteenth H site, H(63) is bonded in a single-bond geometry to one C(64) atom. In the fifteenth H site, H(66) is bonded in a single-bond geometry to one C(68) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(20) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(20) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(11) atom. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(23) atom. In the seventh O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(23) atom. In the eighth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(42) atom. In the ninth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(42) atom. Linkers: 8 CCCCCCCCOc1cc(-c2ccc(C([O])=O)cc2)c(OCCCCCCCC)cc1-c1ccc(C([O])=O)cc1 ,8 [CH2]COc1cc(-c2ccc(C([O])=O)cc2)c([O])cc1-c1ccc(C([O])=O)cc1 ,8 c1cc(-c2ccncc2)ccn1. Metal clusters: 8 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 8.40 A, density 0.80 g/cm3, surface area 5051.72 m2/g, accessible volume 0.78 cm3/g