CuH24(C3N)8 crystallizes in the triclinic P-1 space group. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(10), one N(12), one N(6), and one N(8) atom. The Cu(1)-N(10) bond length is 2.02 Å. The Cu(1)-N(12) bond length is 2.01 Å. The Cu(1)-N(6) bond length is 2.00 Å. The Cu(1)-N(8) bond length is 2.01 Å. In the second Cu site, Cu(2) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent N(4) atoms. Both Cu(2)-N(2) bond lengths are 2.00 Å. Both Cu(2)-N(4) bond lengths are 1.98 Å. There are thirty-six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-C(7) bond length is 1.51 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-H(1) bond length is 0.95 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(11), one C(2), and one C(4) atom. The C(3)-C(11) bond length is 1.51 Å. The C(3)-C(4) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(15), one C(4), and one C(6) atom. The C(5)-C(15) bond length is 1.51 Å. The C(5)-C(6) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(3) atom. The C(6)-H(3) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a 3-coordinate geometry to one C(1); one N(1); and two equivalent H(4,5) atoms. The C(7)-N(1) bond length is 1.46 Å. Both C(7)-H(4,5) bond lengths are 0.99 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(6) atom. The C(8)-N(1) bond length is 1.34 Å. The C(8)-N(2) bond length is 1.32 Å. The C(8)-H(6) bond length is 0.95 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(9)-N(2) bond length is 1.36 Å. The C(9)-H(7) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(10)-N(1) bond length is 1.36 Å. The C(10)-H(8) bond length is 0.95 Å. In the eleventh C site, C(11) is bonded in a 3-coordinate geometry to one C(3); one N(3); and two equivalent H(9,10) atoms. The C(11)-N(3) bond length is 1.46 Å. Both C(11)-H(9,10) bond lengths are 0.99 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(11) atom. The C(12)-N(3) bond length is 1.34 Å. The C(12)-N(4) bond length is 1.31 Å. The C(12)-H(11) bond length is 0.95 Å. In the thirteenth C site, C(13) is bonded in a 3-coordinate geometry to one C(14), one N(4), and one H(12) atom. The C(13)-C(14) bond length is 1.35 Å. The C(13)-N(4) bond length is 1.39 Å. The C(13)-H(12) bond length is 0.95 Å. In the fourteenth C site, C(14) is bonded in a 3-coordinate geometry to one C(13), one N(3), and one H(13) atom. The C(14)-N(3) bond length is 1.37 Å. The C(14)-H(13) bond length is 0.95 Å. In the fifteenth C site, C(15) is bonded in a 3-coordinate geometry to one C(5); one N(5); and two equivalent H(14,15) atoms. The C(15)-N(5) bond length is 1.46 Å. Both C(15)-H(14,15) bond lengths are 0.99 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(16) atom. The C(16)-N(5) bond length is 1.35 Å. The C(16)-N(6) bond length is 1.32 Å. The C(16)-H(16) bond length is 0.95 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(6), and one H(17) atom. The C(17)-C(18) bond length is 1.36 Å. The C(17)-N(6) bond length is 1.38 Å. The C(17)-H(17) bond length is 0.95 Å. In the eighteenth C site, C(18) is bonded in a 3-coordinate geometry to one C(17), one N(5), and one H(18) atom. The C(18)-N(5) bond length is 1.37 Å. The C(18)-H(18) bond length is 0.95 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(20), one C(24), and one C(25) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-C(24) bond length is 1.38 Å. The C(19)-C(25) bond length is 1.52 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(19) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(19) bond length is 0.95 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(29) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-C(29) bond length is 1.52 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(20) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(20) bond length is 0.95 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(33) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-C(33) bond length is 1.51 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(19), one C(23), and one H(21) atom. The C(24)-H(21) bond length is 0.95 Å. In the twenty-fifth C site, C(25) is bonded in a 3-coordinate geometry to one C(19); one N(7); and two equivalent H(22,23) atoms. The C(25)-N(7) bond length is 1.47 Å. Both C(25)-H(22,23) bond lengths are 0.99 Å. In the twenty-sixth C site, C(26) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(24) atom. The C(26)-N(7) bond length is 1.34 Å. The C(26)-N(8) bond length is 1.32 Å. The C(26)-H(24) bond length is 0.95 Å. In the twenty-seventh C site, C(27) is bonded in a distorted trigonal planar geometry to one C(28), one N(8), and one H(25) atom. The C(27)-C(28) bond length is 1.35 Å. The C(27)-N(8) bond length is 1.38 Å. The C(27)-H(25) bond length is 0.95 Å. In the twenty-eighth C site, C(28) is bonded in a 3-coordinate geometry to one C(27), one N(7), and one H(26) atom. The C(28)-N(7) bond length is 1.37 Å. The C(28)-H(26) bond length is 0.95 Å. In the twenty-ninth C site, C(29) is bonded in a 3-coordinate geometry to one C(21), one N(9), one H(27), and one H(28) atom. The C(29)-N(9) bond length is 1.46 Å. The C(29)-H(27) bond length is 0.99 Å. The C(29)-H(28) bond length is 0.99 Å. In the thirtieth C site, C(30) is bonded in a trigonal planar geometry to one N(10), one N(9), and one H(29) atom. The C(30)-N(10) bond length is 1.32 Å. The C(30)-N(9) bond length is 1.34 Å. The C(30)-H(29) bond length is 0.95 Å. In the thirty-first C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(32), one N(10), and one H(30) atom. The C(31)-C(32) bond length is 1.35 Å. The C(31)-N(10) bond length is 1.37 Å. The C(31)-H(30) bond length is 0.95 Å. In the thirty-second C site, C(32) is bonded in a 3-coordinate geometry to one C(31), one N(9), and one H(31) atom. The C(32)-N(9) bond length is 1.37 Å. The C(32)-H(31) bond length is 0.95 Å. In the thirty-third C site, C(33) is bonded in a 3-coordinate geometry to one C(23); one N(11); and two equivalent H(32,33) atoms. The C(33)-N(11) bond length is 1.46 Å. Both C(33)-H(32,33) bond lengths are 0.99 Å. In the thirty-fourth C site, C(34) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(34) atom. The C(34)-N(11) bond length is 1.34 Å. The C(34)-N(12) bond length is 1.31 Å. The C(34)-H(34) bond length is 0.95 Å. In the thirty-fifth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(36), one N(12), and one H(35) atom. The C(35)-C(36) bond length is 1.35 Å. The C(35)-N(12) bond length is 1.38 Å. The C(35)-H(35) bond length is 0.95 Å. In the thirty-sixth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(35), one N(11), and one H(36) atom. The C(36)-N(11) bond length is 1.36 Å. The C(36)-H(36) bond length is 0.95 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(8), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(14) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(12), and one C(13) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(18) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(16), and one C(17) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(25), one C(26), and one C(28) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Cu(1), one C(26), and one C(27) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(29), one C(30), and one C(32) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Cu(1), one C(30), and one C(31) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one C(33), one C(34), and one C(36) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Cu(1), one C(34), and one C(35) atom. There are thirty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4,5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(9,10) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(14,15) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(22) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(24) atom. In the nineteenth H site, H(22,23) is bonded in a single-bond geometry to one C(25) atom. In the twentieth H site, H(24) is bonded in a single-bond geometry to one C(26) atom. In the twenty-first H site, H(25) is bonded in a single-bond geometry to one C(27) atom. In the twenty-second H site, H(26) is bonded in a single-bond geometry to one C(28) atom. In the twenty-third H site, H(27) is bonded in a single-bond geometry to one C(29) atom. In the twenty-fourth H site, H(28) is bonded in a single-bond geometry to one C(29) atom. In the twenty-fifth H site, H(29) is bonded in a single-bond geometry to one C(30) atom. In the twenty-sixth H site, H(30) is bonded in a single-bond geometry to one C(31) atom. In the twenty-seventh H site, H(31) is bonded in a single-bond geometry to one C(32) atom. In the twenty-eighth H site, H(32,33) is bonded in a single-bond geometry to one C(33) atom. In the twenty-ninth H site, H(34) is bonded in a single-bond geometry to one C(34) atom. In the thirtieth H site, H(35) is bonded in a single-bond geometry to one C(35) atom. In the thirty-first H site, H(36) is bonded in a single-bond geometry to one C(36) atom. Linkers: 4 c1cn(Cc2cc(Cn3ccnc3)cc(Cn3ccnc3)c2)cn1. Metal clusters: 3 [Cu]. The MOF has largest included sphere 4.12 A, density 1.20 g/cm3, surface area 5059.24 m2/g, accessible volume 0.31 cm3/g