(C3H2)4(C4H5)2Cd3C30N9H24O6F is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 2,3-dimethyl-1,3-butadiene molecules; eight isobutylene molecules; and four Cd3C30N9H24O6F clusters. In each Cd3C30N9H24O6F cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one N(1), one N(3), one N(4), one O(2), one O(3), and one F(1) atom to form corner-sharing CdN3O2F octahedra. The corner-sharing octahedral tilt angles range from 55-63°. The Cd(1)-N(1) bond length is 2.38 Å. The Cd(1)-N(3) bond length is 2.35 Å. The Cd(1)-N(4) bond length is 2.34 Å. The Cd(1)-O(2) bond length is 2.25 Å. The Cd(1)-O(3) bond length is 2.25 Å. The Cd(1)-F(1) bond length is 2.35 Å. In the second Cd site, Cd(2) is bonded to one N(5), two equivalent N(2), two equivalent O(1), and one F(1) atom to form corner-sharing CdN3O2F octahedra. The corner-sharing octahedral tilt angles are 63°. The Cd(2)-N(5) bond length is 2.39 Å. Both Cd(2)-N(2) bond lengths are 2.37 Å. Both Cd(2)-O(1) bond lengths are 2.24 Å. The Cd(2)-F(1) bond length is 2.29 Å. There are sixteen inequivalent C sites. In the first C site, C(25) is bonded in a bent 120 degrees geometry to one C(26) and two equivalent O(3) atoms. The C(25)-C(26) bond length is 1.51 Å. Both C(25)-O(3) bond lengths are 1.24 Å. In the second C site, C(26) is bonded in a trigonal planar geometry to one C(25) and two equivalent C(7) atoms. Both C(26)-C(7) bond lengths are 1.38 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.24 Å. The C(1)-O(2) bond length is 1.24 Å. In the fourth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(4) bond length is 1.38 Å. In the fifth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1,2) atom. The C(3)-H(1,2) bond length is 0.93 Å. In the sixth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(1,2) atom. The C(4)-H(1,2) bond length is 0.93 Å. In the seventh C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(5)-N(1) bond length is 1.32 Å. The C(5)-H(3) bond length is 0.93 Å. In the eighth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(6)-N(1) bond length is 1.33 Å. The C(6)-H(4) bond length is 0.93 Å. In the ninth C site, C(7) is bonded in a single-bond geometry to one C(26) and one H(5) atom. The C(7)-H(5) bond length is 0.93 Å. In the tenth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(6) atom. The C(8)-N(5) bond length is 1.34 Å. The C(8)-H(6) bond length is 0.93 Å. In the eleventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(8) bond length is 0.93 Å. In the twelfth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(9)-N(2) bond length is 1.34 Å. The C(9)-H(7) bond length is 0.93 Å. In the thirteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(13) atom. The C(17)-N(3) bond length is 1.33 Å. The C(17)-H(13) bond length is 0.93 Å. In the fourteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(14) atom. The C(18)-N(3) bond length is 1.34 Å. The C(18)-H(14) bond length is 0.93 Å. In the fifteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(15) atom. The C(19)-N(4) bond length is 1.33 Å. The C(19)-H(15) bond length is 0.93 Å. In the sixteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(16) atom. The C(20)-N(4) bond length is 1.34 Å. The C(20)-H(16) bond length is 0.93 Å. There are five inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one Cd(2) and two equivalent C(8) atoms. In the second N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(5), and one C(6) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one Cd(2), one C(10), and one C(9) atom. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(17), and one C(18) atom. In the fifth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(19), and one C(20) atom. There are eleven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(20) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cd(2) and one C(1) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(25) atom. F(1) is bonded in a trigonal planar geometry to one Cd(2) and two equivalent Cd(1) atoms. Linkers: 8 c1cc(-c2ccncc2)ccn1 ,12 [O]C(=O)c1ccncc1. Metal clusters: 12 [Cd]. The MOF has largest included sphere 5.52 A, density 1.30 g/cm3, surface area 4341.83 m2/g, accessible volume 0.35 cm3/g