Zn7H24(C16O9)3(CH)15(C13H9O)6(C25H17O2)3 is Indium-derived structured and crystallizes in the trigonal R-3c space group. The structure is zero-dimensional and consists of one hundred and eighty 02329_fluka molecules, thirty-six C13H9O clusters, thirty-six C25H17O2 clusters, and twelve Zn7H24(C16O9)3 clusters. In each C13H9O cluster, there are twenty-six inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(13) and one H(5) atom. The C(9)-C(13) bond length is 1.40 Å. The C(9)-H(5) bond length is 0.95 Å. In the second C site, C(10) is bonded in a distorted single-bond geometry to one C(13) and one H(6) atom. The C(10)-C(13) bond length is 1.39 Å. The C(10)-H(6) bond length is 0.95 Å. In the third C site, C(13) is bonded in a trigonal planar geometry to one C(10), one C(15), and one C(9) atom. The C(13)-C(15) bond length is 1.48 Å. In the fourth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one C(13), one H(10), one H(9), and one O(9) atom. The C(15)-H(10) bond length is 0.99 Å. The C(15)-H(9) bond length is 0.99 Å. The C(15)-O(9) bond length is 1.39 Å. In the fifth C site, C(17) is bonded in a distorted single-bond geometry to one C(20) and one O(9) atom. The C(17)-C(20) bond length is 1.45 Å. The C(17)-O(9) bond length is 1.39 Å. In the sixth C site, C(20) is bonded in a trigonal planar geometry to one C(17), one C(24), and one C(25) atom. The C(20)-C(24) bond length is 1.35 Å. The C(20)-C(25) bond length is 1.46 Å. In the seventh C site, C(24) is bonded in a trigonal planar geometry to one C(20), one C(29), and one C(30) atom. The C(24)-C(29) bond length is 1.38 Å. The C(24)-C(30) bond length is 1.55 Å. In the eighth C site, C(25) is bonded in a distorted single-bond geometry to one C(20), one C(31), one C(32), and one H(16) atom. The C(25)-C(31) bond length is 1.38 Å. The C(25)-C(32) bond length is 1.47 Å. The C(25)-H(16) bond length is 1.00 Å. In the ninth C site, C(29) is bonded in a single-bond geometry to one C(24) and one O(11) atom. The C(29)-O(11) bond length is 1.32 Å. In the tenth C site, C(30) is bonded in a distorted single-bond geometry to one C(24), one C(37), one C(38), and one H(19) atom. The C(30)-C(37) bond length is 1.54 Å. The C(30)-C(38) bond length is 1.46 Å. The C(30)-H(19) bond length is 1.00 Å. In the eleventh C site, C(31) is bonded in a trigonal planar geometry to one C(25), one C(37), and one C(39) atom. The C(31)-C(37) bond length is 1.35 Å. The C(31)-C(39) bond length is 1.38 Å. In the twelfth C site, C(32) is bonded in a trigonal planar geometry to one C(25), one C(38), and one C(40) atom. The C(32)-C(38) bond length is 1.37 Å. The C(32)-C(40) bond length is 1.41 Å. In the thirteenth C site, C(37) is bonded in a trigonal planar geometry to one C(30), one C(31), and one C(46) atom. The C(37)-C(46) bond length is 1.54 Å. In the fourteenth C site, C(38) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(47) atom. The C(38)-C(47) bond length is 1.26 Å. In the fifteenth C site, C(39) is bonded in a distorted single-bond geometry to one C(31), one C(48), and one H(21) atom. The C(39)-C(48) bond length is 1.66 Å. The C(39)-H(21) bond length is 0.95 Å. In the sixteenth C site, C(40) is bonded in a distorted single-bond geometry to one C(32), one C(49), and one H(22) atom. The C(40)-C(49) bond length is 1.32 Å. The C(40)-H(22) bond length is 0.95 Å. In the seventeenth C site, C(45) is bonded in a distorted trigonal non-coplanar geometry to one C(55), one H(25), one H(26), and one O(11) atom. The C(45)-C(55) bond length is 1.50 Å. The C(45)-H(25) bond length is 0.99 Å. The C(45)-H(26) bond length is 0.99 Å. The C(45)-O(11) bond length is 1.28 Å. In the eighteenth C site, C(46) is bonded in a single-bond geometry to one C(37) and one H(27) atom. The C(46)-H(27) bond length is 0.95 Å. In the nineteenth C site, C(47) is bonded in a distorted single-bond geometry to one C(38) and one H(28) atom. The C(47)-H(28) bond length is 0.95 Å. In the twentieth C site, C(48) is bonded in a 3-coordinate geometry to one C(39), one C(56), and one H(29) atom. The C(48)-C(56) bond length is 1.11 Å. The C(48)-H(29) bond length is 0.95 Å. In the twenty-first C site, C(49) is bonded in a distorted trigonal planar geometry to one C(40), one C(57), and one H(30) atom. The C(49)-C(57) bond length is 1.54 Å. The C(49)-H(30) bond length is 0.95 Å. In the twenty-second C site, C(55) is bonded in a trigonal planar geometry to one C(45), one C(61), and one C(62) atom. The C(55)-C(61) bond length is 1.37 Å. The C(55)-C(62) bond length is 1.41 Å. In the twenty-third C site, C(56) is bonded in a distorted single-bond geometry to one C(48) and one H(37) atom. The C(56)-H(37) bond length is 0.95 Å. In the twenty-fourth C site, C(57) is bonded in a distorted single-bond geometry to one C(49) and one H(38) atom. The C(57)-H(38) bond length is 0.95 Å. In the twenty-fifth C site, C(61) is bonded in a distorted single-bond geometry to one C(55) and one H(41) atom. The C(61)-H(41) bond length is 0.95 Å. In the twenty-sixth C site, C(62) is bonded in a distorted single-bond geometry to one C(55) and one H(42) atom. The C(62)-H(42) bond length is 0.95 Å. There are eighteen inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(30) atom. In the seventh H site, H(21) is bonded in a single-bond geometry to one C(39) atom. In the eighth H site, H(22) is bonded in a single-bond geometry to one C(40) atom. In the ninth H site, H(25) is bonded in a single-bond geometry to one C(45) atom. In the tenth H site, H(26) is bonded in a single-bond geometry to one C(45) atom. In the eleventh H site, H(27) is bonded in a single-bond geometry to one C(46) atom. In the twelfth H site, H(28) is bonded in a single-bond geometry to one C(47) atom. In the thirteenth H site, H(29) is bonded in a single-bond geometry to one C(48) atom. In the fourteenth H site, H(30) is bonded in a single-bond geometry to one C(49) atom. In the fifteenth H site, H(37) is bonded in a single-bond geometry to one C(56) atom. In the sixteenth H site, H(38) is bonded in a single-bond geometry to one C(57) atom. In the seventeenth H site, H(41) is bonded in a single-bond geometry to one C(61) atom. In the eighteenth H site, H(42) is bonded in a single-bond geometry to one C(62) atom. There are two inequivalent O sites. In the first O site, O(9) is bonded in a bent 120 degrees geometry to one C(15) and one C(17) atom. In the second O site, O(11) is bonded in a bent 120 degrees geometry to one C(29) and one C(45) atom. In each C25H17O2 cluster, there are twenty-five inequivalent C sites. In the first C site, C(11) is bonded in a single-bond geometry to one C(14) and one H(7) atom. The C(11)-C(14) bond length is 1.36 Å. The C(11)-H(7) bond length is 0.95 Å. In the second C site, C(12) is bonded in a distorted single-bond geometry to one C(14) and one H(8) atom. The C(12)-C(14) bond length is 1.37 Å. The C(12)-H(8) bond length is 0.95 Å. In the third C site, C(14) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(16) atom. The C(14)-C(16) bond length is 1.50 Å. In the fourth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one C(14), one H(11), one H(12), and one O(10) atom. The C(16)-H(11) bond length is 0.99 Å. The C(16)-H(12) bond length is 0.99 Å. The C(16)-O(10) bond length is 1.40 Å. In the fifth C site, C(18) is bonded in a distorted single-bond geometry to one C(22) and one O(10) atom. The C(18)-C(22) bond length is 1.45 Å. The C(18)-O(10) bond length is 1.33 Å. In the sixth C site, C(22) is bonded in a trigonal planar geometry to one C(18), one C(27), and one C(28) atom. The C(22)-C(27) bond length is 1.37 Å. The C(22)-C(28) bond length is 1.48 Å. In the seventh C site, C(26) is bonded in a distorted single-bond geometry to one C(33) and one H(17) atom. The C(26)-C(33) bond length is 1.49 Å. The C(26)-H(17) bond length is 0.95 Å. In the eighth C site, C(27) is bonded in a trigonal planar geometry to one C(22), one C(33), and one C(34) atom. The C(27)-C(33) bond length is 1.33 Å. The C(27)-C(34) bond length is 1.43 Å. In the ninth C site, C(28) is bonded in a distorted single-bond geometry to one C(22), one C(35), one C(36), and one H(18) atom. The C(28)-C(35) bond length is 1.42 Å. The C(28)-C(36) bond length is 1.57 Å. The C(28)-H(18) bond length is 1.00 Å. In the tenth C site, C(33) is bonded in a distorted single-bond geometry to one C(26), one C(27), and one O(12) atom. The C(33)-O(12) bond length is 1.42 Å. In the eleventh C site, C(34) is bonded in a distorted single-bond geometry to one C(27), one C(41), one C(42), and one H(20) atom. The C(34)-C(41) bond length is 1.48 Å. The C(34)-C(42) bond length is 1.56 Å. The C(34)-H(20) bond length is 1.00 Å. In the twelfth C site, C(35) is bonded in a trigonal planar geometry to one C(28), one C(41), and one C(43) atom. The C(35)-C(41) bond length is 1.40 Å. The C(35)-C(43) bond length is 1.41 Å. In the thirteenth C site, C(36) is bonded in a trigonal planar geometry to one C(28), one C(42), and one C(44) atom. The C(36)-C(42) bond length is 1.52 Å. The C(36)-C(44) bond length is 1.37 Å. In the fourteenth C site, C(41) is bonded in a trigonal planar geometry to one C(34), one C(35), and one C(51) atom. The C(41)-C(51) bond length is 1.31 Å. In the fifteenth C site, C(43) is bonded in a distorted single-bond geometry to one C(35) and one H(23) atom. The C(43)-H(23) bond length is 0.95 Å. In the sixteenth C site, C(44) is bonded in a single-bond geometry to one C(36) and one H(24) atom. The C(44)-H(24) bond length is 0.95 Å. In the seventeenth C site, C(42) is bonded in a trigonal planar geometry to one C(34), one C(36), and one C(52) atom. The C(42)-C(52) bond length is 1.36 Å. In the eighteenth C site, C(50) is bonded in a distorted trigonal non-coplanar geometry to one C(58), one H(31), one H(32), and one O(12) atom. The C(50)-C(58) bond length is 1.46 Å. The C(50)-H(31) bond length is 0.99 Å. The C(50)-H(32) bond length is 0.99 Å. The C(50)-O(12) bond length is 1.38 Å. In the nineteenth C site, C(51) is bonded in a distorted single-bond geometry to one C(41), one C(59), and one H(33) atom. The C(51)-C(59) bond length is 1.40 Å. The C(51)-H(33) bond length is 0.95 Å. In the twentieth C site, C(52) is bonded in a distorted single-bond geometry to one C(42) and one H(34) atom. The C(52)-H(34) bond length is 0.95 Å. In the twenty-first C site, C(53) is bonded in a distorted single-bond geometry to one C(59) and one H(35) atom. The C(53)-C(59) bond length is 1.37 Å. The C(53)-H(35) bond length is 0.95 Å. In the twenty-second C site, C(58) is bonded in a trigonal planar geometry to one C(50), one C(63), and one C(64) atom. The C(58)-C(63) bond length is 1.45 Å. The C(58)-C(64) bond length is 1.31 Å. In the twenty-third C site, C(59) is bonded in a distorted trigonal planar geometry to one C(51), one C(53), and one H(39) atom. The C(59)-H(39) bond length is 0.95 Å. In the twenty-fourth C site, C(63) is bonded in a distorted single-bond geometry to one C(58) and one H(43) atom. The C(63)-H(43) bond length is 0.95 Å. In the twenty-fifth C site, C(64) is bonded in a distorted single-bond geometry to one C(58) and one H(44) atom. The C(64)-H(44) bond length is 0.95 Å. There are seventeen inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(28) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(34) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(43) atom. In the ninth H site, H(24) is bonded in a single-bond geometry to one C(44) atom. In the tenth H site, H(31) is bonded in a single-bond geometry to one C(50) atom. In the eleventh H site, H(32) is bonded in a single-bond geometry to one C(50) atom. In the twelfth H site, H(33) is bonded in a single-bond geometry to one C(51) atom. In the thirteenth H site, H(34) is bonded in a single-bond geometry to one C(52) atom. In the fourteenth H site, H(35) is bonded in a single-bond geometry to one C(53) atom. In the fifteenth H site, H(39) is bonded in a single-bond geometry to one C(59) atom. In the sixteenth H site, H(43) is bonded in a single-bond geometry to one C(63) atom. In the seventeenth H site, H(44) is bonded in a single-bond geometry to one C(64) atom. There are two inequivalent O sites. In the first O site, O(10) is bonded in a bent 120 degrees geometry to one C(16) and one C(18) atom. In the second O site, O(12) is bonded in a bent 120 degrees geometry to one C(33) and one C(50) atom. In each Zn7H24(C16O9)3 cluster, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra and  a cornercorner with one Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 70°. The Zn(1)-O(1) bond length is 1.91 Å. The Zn(1)-O(2) bond length is 1.96 Å. The Zn(1)-O(3) bond length is 1.89 Å. The Zn(1)-O(4) bond length is 1.85 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(5), one O(6), and one O(7) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra and  a cornercorner with one Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 45°. The Zn(2)-O(1) bond length is 1.96 Å. The Zn(2)-O(5) bond length is 1.94 Å. The Zn(2)-O(6) bond length is 1.90 Å. The Zn(2)-O(7) bond length is 1.92 Å. In the third Zn site, Zn(3) is bonded to three equivalent O(1) and three equivalent O(8) atoms to form corner-sharing ZnO6 octahedra. All Zn(3)-O(1) bond lengths are 2.11 Å. All Zn(3)-O(8) bond lengths are 2.07 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one C(3), one O(2), and one O(5) atom. The C(1)-C(3) bond length is 1.55 Å. The C(1)-O(2) bond length is 1.26 Å. The C(1)-O(5) bond length is 1.24 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(6) atom. The C(2)-C(4) bond length is 1.53 Å. The C(2)-O(3) bond length is 1.32 Å. The C(2)-O(6) bond length is 1.27 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(6) atom. The C(3)-C(5) bond length is 1.44 Å. The C(3)-C(6) bond length is 1.34 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(7), and one C(8) atom. The C(4)-C(7) bond length is 1.46 Å. The C(4)-C(8) bond length is 1.37 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(5)-H(1) bond length is 0.95 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(6)-H(2) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(7)-H(3) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(8)-H(4) bond length is 0.95 Å. In the ninth C site, C(65) is bonded in a distorted single-bond geometry to one C(69) and one H(45) atom. The C(65)-C(69) bond length is 1.42 Å. The C(65)-H(45) bond length is 0.95 Å. In the tenth C site, C(66) is bonded in a distorted single-bond geometry to one C(69) and one H(46) atom. The C(66)-C(69) bond length is 1.32 Å. The C(66)-H(46) bond length is 0.95 Å. In the eleventh C site, C(68) is bonded in a distorted single-bond geometry to one C(70) and one H(48) atom. The C(68)-C(70) bond length is 1.37 Å. The C(68)-H(48) bond length is 0.95 Å. In the twelfth C site, C(69) is bonded in a trigonal planar geometry to one C(65), one C(66), and one C(71) atom. The C(69)-C(71) bond length is 1.48 Å. In the thirteenth C site, C(70) is bonded in a trigonal planar geometry to one C(67), one C(68), and one C(72) atom. The C(70)-C(67) bond length is 1.28 Å. The C(70)-C(72) bond length is 1.42 Å. In the fourteenth C site, C(71) is bonded in a distorted bent 120 degrees geometry to one C(69), one O(4), and one O(8) atom. The C(71)-O(4) bond length is 1.24 Å. The C(71)-O(8) bond length is 1.26 Å. In the fifteenth C site, C(72) is bonded in a bent 120 degrees geometry to one C(70), one O(13), and one O(7) atom. The C(72)-O(13) bond length is 1.23 Å. The C(72)-O(7) bond length is 1.17 Å. In the sixteenth C site, C(67) is bonded in a distorted single-bond geometry to one C(70) and one H(47) atom. The C(67)-H(47) bond length is 0.95 Å. There are eight inequivalent H sites. In the first H site, H(45) is bonded in a single-bond geometry to one C(65) atom. In the second H site, H(46) is bonded in a single-bond geometry to one C(66) atom. In the third H site, H(47) is bonded in a single-bond geometry to one C(67) atom. In the fourth H site, H(48) is bonded in a single-bond geometry to one C(68) atom. In the fifth H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(2), and one Zn(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(71) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(72) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Zn(3) and one C(71) atom. In the ninth O site, O(13) is bonded in a single-bond geometry to one C(72) atom. Linkers: 72 [O]C(=O)c1ccc(COc2ccc(OCc3ccc(C([O])=O)cc3)c3c2[C@H]2c4ccccc4[C@@H]3c3ccccc32)cc1. Metal clusters: 12 O=[C]O[Zn@]12O[C]O[Zn@](O[C]O[Zn](O[C]O[Zn@]34O[C]O[Zn@](O[C]=O)(O[C]O3)O4)O[C]O[Zn@]34O[C]O[Zn@](O[C]=O)(O[C]O3)O4)(O[C]O1)O2. RCSR code: pcu. The MOF has largest included sphere 17.39 A, density 0.74 g/cm3, surface area 4735.69 m2/g, accessible volume 0.83 cm3/g