CdC14N3H8O2(CH)3 crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of twelve 02329_fluka molecules inside a CdC14N3H8O2 framework. In the CdC14N3H8O2 framework, Cd(1) is bonded in a distorted pentagonal planar geometry to one N(1), one N(2), one N(3), one O(1), and one O(2) atom. The Cd(1)-N(1) bond length is 2.31 Å. The Cd(1)-N(2) bond length is 2.39 Å. The Cd(1)-N(3) bond length is 2.35 Å. The Cd(1)-O(1) bond length is 2.49 Å. The Cd(1)-O(2) bond length is 2.47 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-N(1) bond length is 1.37 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(6) atom. The C(2)-C(5) bond length is 1.38 Å. The C(2)-C(6) bond length is 1.50 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(3) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(5)-H(4) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(2), one C(7), and one O(2) atom. The C(6)-C(7) bond length is 1.50 Å. The C(6)-O(2) bond length is 1.22 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(2) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-N(2) bond length is 1.33 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(8)-H(5) bond length is 0.93 Å. In the eighth C site, C(10) is bonded in a single-bond geometry to one C(11) and one H(7) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-H(7) bond length is 0.93 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(2) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-N(2) bond length is 1.32 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(16), and one O(1) atom. The C(12)-C(16) bond length is 1.46 Å. The C(12)-O(1) bond length is 1.24 Å. In the eleventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(8) atom. The C(13)-N(3) bond length is 1.33 Å. The C(13)-H(8) bond length is 0.93 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(10) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(10) bond length is 0.93 Å. In the thirteenth C site, C(16) is bonded in a trigonal planar geometry to one C(12), one C(15), and one C(17) atom. The C(16)-C(17) bond length is 1.38 Å. In the fourteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(3), and one H(11) atom. The C(17)-N(3) bond length is 1.34 Å. The C(17)-H(11) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(17) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(12) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(6) atom. Linkers: 4 O=C(c1cccnc1)c1cccc(C(=O)c2cccnc2)n1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 4.84 A, density 1.04 g/cm3, surface area 4095.52 m2/g, accessible volume 0.56 cm3/g