ZnH14(C4N)4(C4H3)4(C2NH2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen isobutylene molecules, eight n-methyl methanimine molecules, and four ZnH14(C4N)4 clusters. In each ZnH14(C4N)4 cluster, Zn(1) is bonded in a see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Zn(1)-N(1) bond lengths are 2.04 Å. Both Zn(1)-N(2) bond lengths are 2.25 Å. There are eight inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.93 Å. In the second C site, C(12) is bonded in a single-bond geometry to one C(9) and one H(10) atom. The C(12)-C(9) bond length is 1.50 Å. The C(12)-H(10) bond length is 0.98 Å. In the third C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(7)-N(2) bond length is 1.34 Å. The C(7)-H(6) bond length is 0.93 Å. In the fourth C site, C(8) is bonded in a single-bond geometry to one C(9) and one H(7) atom. The C(8)-C(9) bond length is 1.38 Å. The C(8)-H(7) bond length is 0.93 Å. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(8) atom. The C(9)-C(10) bond length is 1.39 Å. In the sixth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(8) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-H(8) bond length is 0.93 Å. In the seventh C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.93 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(2), and one H(9) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(9) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(7) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. Linkers: 5 c1cc([C@H]2[C@H](c3ccncc3)[C@H](c3ccncc3)[C@H]2c2ccncc2)ccn1 ,4 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 4.36 A, density 1.16 g/cm3, surface area 5069.55 m2/g, accessible volume 0.35 cm3/g