AgP2H28(C15N2)2(CH)10 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eighty 02329_fluka molecules and eight AgP2H28(C15N2)2 clusters. In each AgP2H28(C15N2)2 cluster, Ag(1) is bonded in a tetrahedral geometry to one P(1), one P(2), one N(1), and one N(4) atom. The Ag(1)-P(1) bond length is 2.44 Å. The Ag(1)-P(2) bond length is 2.44 Å. The Ag(1)-N(1) bond length is 2.39 Å. The Ag(1)-N(4) bond length is 2.34 Å. There are thirty inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one P(1) and two equivalent H(1,2) atoms. The C(1)-P(1) bond length is 1.84 Å. Both C(1)-H(1,2) bond lengths are 0.97 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one P(2) and two equivalent H(3,4) atoms. The C(2)-P(2) bond length is 1.83 Å. Both C(2)-H(3,4) bond lengths are 0.97 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(4), one C(8), and one P(1) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-C(8) bond length is 1.38 Å. The C(3)-P(1) bond length is 1.82 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(4)-H(5) bond length is 0.93 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(3) and one H(9) atom. The C(8)-H(9) bond length is 0.93 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one P(1) atom. The C(9)-C(10) bond length is 1.36 Å. The C(9)-C(14) bond length is 1.38 Å. The C(9)-P(1) bond length is 1.82 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(10) atom. The C(10)-H(10) bond length is 0.93 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(14) atom. The C(14)-H(14) bond length is 0.93 Å. In the ninth C site, C(15) is bonded in a trigonal planar geometry to one C(16), one C(20), and one P(2) atom. The C(15)-C(16) bond length is 1.37 Å. The C(15)-C(20) bond length is 1.39 Å. The C(15)-P(2) bond length is 1.82 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one H(15) atom. The C(16)-C(17) bond length is 1.37 Å. The C(16)-H(15) bond length is 0.93 Å. In the eleventh C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(16) atom. The C(17)-C(18) bond length is 1.36 Å. The C(17)-H(16) bond length is 0.93 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(17) atom. The C(18)-H(17) bond length is 0.93 Å. In the thirteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(15) and one H(19) atom. The C(20)-H(19) bond length is 0.93 Å. In the fourteenth C site, C(21) is bonded in a trigonal planar geometry to one C(22), one C(26), and one P(2) atom. The C(21)-C(22) bond length is 1.37 Å. The C(21)-C(26) bond length is 1.38 Å. The C(21)-P(2) bond length is 1.79 Å. In the fifteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(20) atom. The C(22)-H(20) bond length is 0.93 Å. In the sixteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(21) and one H(24) atom. The C(26)-H(24) bond length is 0.93 Å. In the seventeenth C site, C(27) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(25) atom. The C(27)-N(1) bond length is 1.32 Å. The C(27)-N(2) bond length is 1.32 Å. The C(27)-H(25) bond length is 0.93 Å. In the eighteenth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(29), one N(1), and one H(26) atom. The C(28)-C(29) bond length is 1.34 Å. The C(28)-N(1) bond length is 1.34 Å. The C(28)-H(26) bond length is 0.93 Å. In the nineteenth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(28), one N(2), and one H(27) atom. The C(29)-N(2) bond length is 1.36 Å. The C(29)-H(27) bond length is 0.93 Å. In the twentieth C site, C(30) is bonded in a distorted trigonal non-coplanar geometry to one C(31), one N(2), one H(28), and one H(29) atom. The C(30)-C(31) bond length is 1.53 Å. The C(30)-N(2) bond length is 1.45 Å. The C(30)-H(28) bond length is 0.97 Å. The C(30)-H(29) bond length is 0.97 Å. In the twenty-first C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(33) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-C(33) bond length is 1.35 Å. In the twenty-second C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(30) atom. The C(32)-H(30) bond length is 0.93 Å. In the twenty-third C site, C(33) is bonded in a distorted single-bond geometry to one C(31) and one H(31) atom. The C(33)-H(31) bond length is 0.93 Å. In the twenty-fourth C site, C(34) is bonded in a distorted single-bond geometry to one C(36) and one H(32) atom. The C(34)-C(36) bond length is 1.36 Å. The C(34)-H(32) bond length is 0.93 Å. In the twenty-fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(36) and one H(33) atom. The C(35)-C(36) bond length is 1.37 Å. The C(35)-H(33) bond length is 0.93 Å. In the twenty-sixth C site, C(36) is bonded in a trigonal planar geometry to one C(34), one C(35), and one C(37) atom. The C(36)-C(37) bond length is 1.49 Å. In the twenty-seventh C site, C(37) is bonded in a 3-coordinate geometry to one C(36), one N(3), one H(34), and one H(35) atom. The C(37)-N(3) bond length is 1.49 Å. The C(37)-H(34) bond length is 0.97 Å. The C(37)-H(35) bond length is 0.97 Å. In the twenty-eighth C site, C(38) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(36) atom. The C(38)-N(3) bond length is 1.34 Å. The C(38)-N(4) bond length is 1.32 Å. The C(38)-H(36) bond length is 0.93 Å. In the twenty-ninth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(40), one N(3), and one H(37) atom. The C(39)-C(40) bond length is 1.33 Å. The C(39)-N(3) bond length is 1.36 Å. The C(39)-H(37) bond length is 0.93 Å. In the thirtieth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(39), one N(4), and one H(38) atom. The C(40)-N(4) bond length is 1.37 Å. The C(40)-H(38) bond length is 0.93 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one Ag(1), one C(1), one C(3), and one C(9) atom to form distorted corner-sharing PAgC3 tetrahedra. In the second P site, P(2) is bonded to one Ag(1), one C(15), one C(2), and one C(21) atom to form distorted corner-sharing PAgC3 tetrahedra. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(27), and one C(28) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(30) atom. In the third N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(38), and one C(40) atom. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one C(37), one C(38), and one C(39) atom. There are twenty-six inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(26) atom. In the thirteenth H site, H(25) is bonded in a single-bond geometry to one C(27) atom. In the fourteenth H site, H(26) is bonded in a single-bond geometry to one C(28) atom. In the fifteenth H site, H(27) is bonded in a single-bond geometry to one C(29) atom. In the sixteenth H site, H(28) is bonded in a single-bond geometry to one C(30) atom. In the seventeenth H site, H(29) is bonded in a single-bond geometry to one C(30) atom. In the eighteenth H site, H(30) is bonded in a single-bond geometry to one C(32) atom. In the nineteenth H site, H(31) is bonded in a single-bond geometry to one C(33) atom. In the twentieth H site, H(32) is bonded in a single-bond geometry to one C(34) atom. In the twenty-first H site, H(33) is bonded in a single-bond geometry to one C(35) atom. In the twenty-second H site, H(34) is bonded in a single-bond geometry to one C(37) atom. In the twenty-third H site, H(35) is bonded in a single-bond geometry to one C(37) atom. In the twenty-fourth H site, H(36) is bonded in a single-bond geometry to one C(38) atom. In the twenty-fifth H site, H(37) is bonded in a single-bond geometry to one C(39) atom. In the twenty-sixth H site, H(38) is bonded in a single-bond geometry to one C(40) atom. Linkers: 8 c1cn(Cc2ccc(Cn3ccnc3)cc2)cn1. Metal clusters: 8 [Ag]. The MOF has largest included sphere 5.11 A, density 1.11 g/cm3, surface area 5323.83 m2/g, accessible volume 0.42 cm3/g