(ZnC22H21(N3O)2)2ZnC16H14(NO)4(CH2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two ZnC16H14(NO)4 clusters, and four ZnC22H21(N3O)2 clusters. In each ZnC16H14(NO)4 cluster, Zn(2) is bonded in a tetrahedral geometry to one N(5), one N(7), one O(3), and one O(5) atom. The Zn(2)-N(5) bond length is 1.99 Å. The Zn(2)-N(7) bond length is 2.01 Å. The Zn(2)-O(3) bond length is 1.96 Å. The Zn(2)-O(5) bond length is 1.96 Å. There are sixteen inequivalent C sites. In the first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(3)-O(3) bond length is 1.25 Å. The C(3)-O(4) bond length is 1.25 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(5)-O(5) bond length is 1.27 Å. The C(5)-O(6) bond length is 1.23 Å. In the third C site, C(24) is bonded in a 3-coordinate geometry to one C(23), one N(6), and one H(24) atom. The C(24)-C(23) bond length is 1.35 Å. The C(24)-N(6) bond length is 1.35 Å. The C(24)-H(24) bond length is 0.93 Å. In the fourth C site, C(25) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(25) atom. The C(25)-N(5) bond length is 1.31 Å. The C(25)-N(6) bond length is 1.32 Å. The C(25)-H(25) bond length is 0.93 Å. In the fifth C site, C(23) is bonded in a 3-coordinate geometry to one C(24), one N(5), and one H(23) atom. The C(23)-N(5) bond length is 1.37 Å. The C(23)-H(23) bond length is 0.93 Å. In the sixth C site, C(29) is bonded in a 3-coordinate geometry to one C(30); one N(6); and two equivalent H(29,30) atoms. The C(29)-C(30) bond length is 1.50 Å. The C(29)-N(6) bond length is 1.48 Å. Both C(29)-H(29,30) bond lengths are 0.97 Å. In the seventh C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(35) atom. The C(30)-C(31) bond length is 1.41 Å. The C(30)-C(35) bond length is 1.36 Å. In the eighth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(31) atom. The C(31)-H(31) bond length is 0.93 Å. In the ninth C site, C(35) is bonded in a distorted single-bond geometry to one C(30) and one H(34) atom. The C(35)-H(34) bond length is 0.93 Å. In the tenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(27), one N(7), and one H(26) atom. The C(26)-C(27) bond length is 1.33 Å. The C(26)-N(7) bond length is 1.38 Å. The C(26)-H(26) bond length is 0.93 Å. In the eleventh C site, C(27) is bonded in a 3-coordinate geometry to one C(26), one N(8), and one H(27) atom. The C(27)-N(8) bond length is 1.38 Å. The C(27)-H(27) bond length is 0.93 Å. In the twelfth C site, C(28) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(28) atom. The C(28)-N(7) bond length is 1.32 Å. The C(28)-N(8) bond length is 1.35 Å. The C(28)-H(28) bond length is 0.93 Å. In the thirteenth C site, C(36) is bonded in a 3-coordinate geometry to one C(33); one N(8); and two equivalent H(35,36) atoms. The C(36)-C(33) bond length is 1.51 Å. The C(36)-N(8) bond length is 1.46 Å. Both C(36)-H(35,36) bond lengths are 0.97 Å. In the fourteenth C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(32) atom. The C(32)-C(33) bond length is 1.38 Å. The C(32)-H(32) bond length is 0.93 Å. In the fifteenth C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(36) atom. The C(33)-C(34) bond length is 1.36 Å. In the sixteenth C site, C(34) is bonded in a distorted single-bond geometry to one C(33) and one H(33) atom. The C(34)-H(33) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one Zn(2), one C(23), and one C(25) atom. In the second N site, N(6) is bonded in a trigonal planar geometry to one C(24), one C(25), and one C(29) atom. In the third N site, N(7) is bonded in a trigonal planar geometry to one Zn(2), one C(26), and one C(28) atom. In the fourth N site, N(8) is bonded in a trigonal planar geometry to one C(27), one C(28), and one C(36) atom. There are twelve inequivalent H sites. In the first H site, H(26) is bonded in a single-bond geometry to one C(26) atom. In the second H site, H(23) is bonded in a single-bond geometry to one C(23) atom. In the third H site, H(24) is bonded in a single-bond geometry to one C(24) atom. In the fourth H site, H(25) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(29,30) is bonded in a single-bond geometry to one C(29) atom. In the sixth H site, H(31) is bonded in a single-bond geometry to one C(31) atom. In the seventh H site, H(34) is bonded in a single-bond geometry to one C(35) atom. In the eighth H site, H(28) is bonded in a single-bond geometry to one C(28) atom. In the ninth H site, H(27) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(32) is bonded in a single-bond geometry to one C(32) atom. In the eleventh H site, H(33) is bonded in a single-bond geometry to one C(34) atom. In the twelfth H site, H(35,36) is bonded in a single-bond geometry to one C(36) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a water-like geometry to one Zn(2) and one C(3) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(3) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(5) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(5) atom. In two of the ZnC22H21(N3O)2 clusters, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(13), one N(15), and one O(1) atom. The Zn(1)-N(1) bond length is 2.00 Å. The Zn(1)-N(13) bond length is 2.01 Å. The Zn(1)-N(15) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 1.95 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.22 Å. In the second C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(9) atom. The C(9)-C(10) bond length is 1.33 Å. The C(9)-N(1) bond length is 1.36 Å. The C(9)-H(9) bond length is 0.93 Å. In the third C site, C(11) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(11) atom. The C(11)-N(1) bond length is 1.32 Å. The C(11)-N(2) bond length is 1.32 Å. The C(11)-H(11) bond length is 0.93 Å. In the fourth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(10) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(10) bond length is 0.93 Å. In the fifth C site, C(15) is bonded in a 4-coordinate geometry to one C(16); one N(2); and two equivalent H(15,16) atoms. The C(15)-C(16) bond length is 1.48 Å. The C(15)-N(2) bond length is 1.50 Å. Both C(15)-H(15,16) bond lengths are 0.97 Å. In the sixth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(20) atom. The C(21)-C(16) bond length is 1.36 Å. The C(21)-H(20) bond length is 0.93 Å. In the seventh C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.39 Å. In the eighth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(17) atom. The C(17)-H(17) bond length is 0.93 Å. In the ninth C site, C(51) is bonded in a distorted bent 120 degrees geometry to one C(52), one N(13), and one H(51) atom. The C(51)-C(52) bond length is 1.36 Å. The C(51)-N(13) bond length is 1.37 Å. The C(51)-H(51) bond length is 0.93 Å. In the tenth C site, C(55) is bonded in a trigonal planar geometry to one C(54), one C(56), and one C(61) atom. The C(55)-C(54) bond length is 1.49 Å. The C(55)-C(56) bond length is 1.40 Å. The C(55)-C(61) bond length is 1.40 Å. In the eleventh C site, C(56) is bonded in a distorted single-bond geometry to one C(55) and one H(56) atom. The C(56)-H(56) bond length is 0.93 Å. In the twelfth C site, C(53) is bonded in a trigonal planar geometry to one N(13), one N(14), and one H(53) atom. The C(53)-N(13) bond length is 1.32 Å. The C(53)-N(14) bond length is 1.32 Å. The C(53)-H(53) bond length is 0.93 Å. In the thirteenth C site, C(52) is bonded in a distorted trigonal planar geometry to one C(51), one N(14), and one H(52) atom. The C(52)-N(14) bond length is 1.36 Å. The C(52)-H(52) bond length is 0.93 Å. In the fourteenth C site, C(54) is bonded in a 3-coordinate geometry to one C(55); one N(14); and two equivalent H(54,55) atoms. The C(54)-N(14) bond length is 1.48 Å. Both C(54)-H(54,55) bond lengths are 0.97 Å. In the fifteenth C site, C(57) is bonded in a distorted trigonal planar geometry to one C(58), one N(15), and one H(57) atom. The C(57)-C(58) bond length is 1.31 Å. The C(57)-N(15) bond length is 1.37 Å. The C(57)-H(57) bond length is 0.93 Å. In the sixteenth C site, C(59) is bonded in a trigonal planar geometry to one N(15), one N(16), and one H(59) atom. The C(59)-N(15) bond length is 1.29 Å. The C(59)-N(16) bond length is 1.32 Å. The C(59)-H(59) bond length is 0.93 Å. In the seventeenth C site, C(58) is bonded in a 3-coordinate geometry to one C(57), one N(16), and one H(58) atom. The C(58)-N(16) bond length is 1.38 Å. The C(58)-H(58) bond length is 0.93 Å. In the eighteenth C site, C(60) is bonded in a 3-coordinate geometry to one C(62); one N(16); and two equivalent H(60,61) atoms. The C(60)-C(62) bond length is 1.51 Å. The C(60)-N(16) bond length is 1.45 Å. Both C(60)-H(60,61) bond lengths are 0.97 Å. In the nineteenth C site, C(62) is bonded in a trigonal planar geometry to one C(60), one C(63), and one C(64) atom. The C(62)-C(63) bond length is 1.39 Å. The C(62)-C(64) bond length is 1.36 Å. In the twentieth C site, C(63) is bonded in a distorted single-bond geometry to one C(62) and one H(63) atom. The C(63)-H(63) bond length is 0.93 Å. In the twenty-first C site, C(64) is bonded in a distorted single-bond geometry to one C(62) and one H(64) atom. The C(64)-H(64) bond length is 0.93 Å. In the twenty-second C site, C(61) is bonded in a distorted single-bond geometry to one C(55) and one H(62) atom. The C(61)-H(62) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(15) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(9) atom. In the third N site, N(13) is bonded in a trigonal planar geometry to one Zn(1), one C(51), and one C(53) atom. In the fourth N site, N(15) is bonded in a trigonal planar geometry to one Zn(1), one C(57), and one C(59) atom. In the fifth N site, N(14) is bonded in a trigonal planar geometry to one C(52), one C(53), and one C(54) atom. In the sixth N site, N(16) is bonded in a trigonal planar geometry to one C(58), one C(59), and one C(60) atom. There are eighteen inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(15,16) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(52) is bonded in a single-bond geometry to one C(52) atom. In the eighth H site, H(51) is bonded in a single-bond geometry to one C(51) atom. In the ninth H site, H(54,55) is bonded in a single-bond geometry to one C(54) atom. In the tenth H site, H(56) is bonded in a single-bond geometry to one C(56) atom. In the eleventh H site, H(58) is bonded in a single-bond geometry to one C(58) atom. In the twelfth H site, H(53) is bonded in a single-bond geometry to one C(53) atom. In the thirteenth H site, H(57) is bonded in a single-bond geometry to one C(57) atom. In the fourteenth H site, H(59) is bonded in a single-bond geometry to one C(59) atom. In the fifteenth H site, H(60,61) is bonded in a single-bond geometry to one C(60) atom. In the sixteenth H site, H(64) is bonded in a single-bond geometry to one C(64) atom. In the seventeenth H site, H(62) is bonded in a single-bond geometry to one C(61) atom. In the eighteenth H site, H(63) is bonded in a single-bond geometry to one C(63) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In two of the ZnC22H21(N3O)2 clusters, Zn(3) is bonded in a tetrahedral geometry to one N(11), one N(3), one N(9), and one O(7) atom. The Zn(3)-N(11) bond length is 1.98 Å. The Zn(3)-N(3) bond length is 2.05 Å. The Zn(3)-N(9) bond length is 2.01 Å. The Zn(3)-O(7) bond length is 1.96 Å. There are twenty-two inequivalent C sites. In the first C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(8)-O(7) bond length is 1.25 Å. The C(8)-O(8) bond length is 1.22 Å. In the second C site, C(12) is bonded in a 3-coordinate geometry to one C(13), one N(3), and one H(12) atom. The C(12)-C(13) bond length is 1.29 Å. The C(12)-N(3) bond length is 1.41 Å. The C(12)-H(12) bond length is 0.93 Å. In the third C site, C(13) is bonded in a 3-coordinate geometry to one C(12), one N(4), and one H(13) atom. The C(13)-N(4) bond length is 1.36 Å. The C(13)-H(13) bond length is 0.93 Å. In the fourth C site, C(14) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(14) atom. The C(14)-N(3) bond length is 1.25 Å. The C(14)-N(4) bond length is 1.37 Å. The C(14)-H(14) bond length is 0.93 Å. In the fifth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(18) atom. The C(18)-C(19) bond length is 1.43 Å. The C(18)-H(18) bond length is 0.93 Å. In the sixth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(22) atom. The C(19)-C(20) bond length is 1.30 Å. The C(19)-C(22) bond length is 1.52 Å. In the seventh C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(19) atom. The C(20)-H(19) bond length is 0.93 Å. In the eighth C site, C(22) is bonded in a 3-coordinate geometry to one C(19), one N(4), one H(21), and one H(22) atom. The C(22)-N(4) bond length is 1.47 Å. The C(22)-H(21) bond length is 0.97 Å. The C(22)-H(22) bond length is 0.97 Å. In the ninth C site, C(37) is bonded in a 3-coordinate geometry to one C(38), one N(9), and one H(37) atom. The C(37)-C(38) bond length is 1.34 Å. The C(37)-N(9) bond length is 1.38 Å. The C(37)-H(37) bond length is 0.93 Å. In the tenth C site, C(39) is bonded in a trigonal planar geometry to one N(10), one N(9), and one H(39) atom. The C(39)-N(10) bond length is 1.34 Å. The C(39)-N(9) bond length is 1.32 Å. The C(39)-H(39) bond length is 0.93 Å. In the eleventh C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(37), one N(10), and one H(38) atom. The C(38)-N(10) bond length is 1.37 Å. The C(38)-H(38) bond length is 0.93 Å. In the twelfth C site, C(43) is bonded in a 3-coordinate geometry to one C(44); one N(10); and two equivalent H(43,44) atoms. The C(43)-C(44) bond length is 1.51 Å. The C(43)-N(10) bond length is 1.48 Å. Both C(43)-H(43,44) bond lengths are 0.97 Å. In the thirteenth C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(49) atom. The C(44)-C(45) bond length is 1.40 Å. The C(44)-C(49) bond length is 1.37 Å. In the fourteenth C site, C(45) is bonded in a distorted single-bond geometry to one C(44) and one H(45) atom. The C(45)-H(45) bond length is 0.93 Å. In the fifteenth C site, C(49) is bonded in a distorted single-bond geometry to one C(44) and one H(48) atom. The C(49)-H(48) bond length is 0.93 Å. In the sixteenth C site, C(50) is bonded in a distorted trigonal non-coplanar geometry to one C(47); one N(12); and two equivalent H(49,50) atoms. The C(50)-C(47) bond length is 1.52 Å. The C(50)-N(12) bond length is 1.44 Å. Both C(50)-H(49,50) bond lengths are 0.97 Å. In the seventeenth C site, C(46) is bonded in a distorted single-bond geometry to one C(47) and one H(46) atom. The C(46)-C(47) bond length is 1.37 Å. The C(46)-H(46) bond length is 0.93 Å. In the eighteenth C site, C(47) is bonded in a trigonal planar geometry to one C(46), one C(48), and one C(50) atom. The C(47)-C(48) bond length is 1.36 Å. In the nineteenth C site, C(48) is bonded in a distorted single-bond geometry to one C(47) and one H(47) atom. The C(48)-H(47) bond length is 0.93 Å. In the twentieth C site, C(40) is bonded in a 2-coordinate geometry to one N(11) and one H(40) atom. The C(40)-N(11) bond length is 1.39 Å. The C(40)-H(40) bond length is 0.93 Å. In the twenty-first C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(12) and one H(41) atom. The C(41)-N(12) bond length is 1.33 Å. The C(41)-H(41) bond length is 0.93 Å. In the twenty-second C site, C(42) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(42) atom. The C(42)-N(11) bond length is 1.28 Å. The C(42)-N(12) bond length is 1.39 Å. The C(42)-H(42) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(3) is bonded in a distorted trigonal planar geometry to one Zn(3), one C(12), and one C(14) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(22) atom. In the third N site, N(9) is bonded in a trigonal planar geometry to one Zn(3), one C(37), and one C(39) atom. In the fourth N site, N(10) is bonded in a trigonal planar geometry to one C(38), one C(39), and one C(43) atom. In the fifth N site, N(11) is bonded in a trigonal planar geometry to one Zn(3), one C(40), and one C(42) atom. In the sixth N site, N(12) is bonded in a trigonal planar geometry to one C(41), one C(42), and one C(50) atom. There are nineteen inequivalent H sites. In the first H site, H(46) is bonded in a single-bond geometry to one C(46) atom. In the second H site, H(47) is bonded in a single-bond geometry to one C(48) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(21) is bonded in a single-bond geometry to one C(22) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(37) is bonded in a single-bond geometry to one C(37) atom. In the eleventh H site, H(39) is bonded in a single-bond geometry to one C(39) atom. In the twelfth H site, H(38) is bonded in a single-bond geometry to one C(38) atom. In the thirteenth H site, H(43,44) is bonded in a single-bond geometry to one C(43) atom. In the fourteenth H site, H(45) is bonded in a single-bond geometry to one C(45) atom. In the fifteenth H site, H(48) is bonded in a single-bond geometry to one C(49) atom. In the sixteenth H site, H(49,50) is bonded in a single-bond geometry to one C(50) atom. In the seventeenth H site, H(40) is bonded in a single-bond geometry to one C(40) atom. In the eighteenth H site, H(41) is bonded in a single-bond geometry to one C(41) atom. In the nineteenth H site, H(42) is bonded in a single-bond geometry to one C(42) atom. There are two inequivalent O sites. In the first O site, O(7) is bonded in a water-like geometry to one Zn(3) and one C(8) atom. In the second O site, O(8) is bonded in a single-bond geometry to one C(8) atom. Linkers: 4 [O]C(=O)CCC([O])=O ,8 c1cn(Cc2ccc(Cn3ccnc3)cc2)cn1. Metal clusters: 4 O=[C]O[Zn] ,2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.51 A, density 1.22 g/cm3, surface area 5292.00 m2/g, accessible volume 0.32 cm3/g