CoAgC38N9H26(CH)4 crystallizes in the orthorhombic Pbcn space group. The structure consists of thirty-two 02329_fluka molecules inside a CoAgC38N9H26 framework. In each CoAgC38N9H26 framework, Co(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(4), one N(5), one N(7), and one N(8) atom. The Co(1)-N(1) bond length is 1.94 Å. The Co(1)-N(2) bond length is 1.94 Å. The Co(1)-N(4) bond length is 1.93 Å. The Co(1)-N(5) bond length is 1.94 Å. The Co(1)-N(7) bond length is 1.93 Å. The Co(1)-N(8) bond length is 1.93 Å. Ag(1) is bonded in a trigonal planar geometry to one N(3), one N(6), and one N(9) atom. The Ag(1)-N(3) bond length is 2.25 Å. The Ag(1)-N(6) bond length is 2.24 Å. The Ag(1)-N(9) bond length is 2.23 Å. There are thirty-eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.42 Å. The C(3)-H(3) bond length is 0.95 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(1) bond length is 1.40 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(6) atom. The C(5)-C(10) bond length is 1.48 Å. The C(5)-C(6) bond length is 1.38 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.42 Å. The C(6)-N(2) bond length is 1.39 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(4) atom. The C(7)-C(8) bond length is 1.37 Å. The C(7)-H(4) bond length is 0.95 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(5) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-H(5) bond length is 0.95 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(2), and one H(6) atom. The C(9)-N(2) bond length is 1.34 Å. The C(9)-H(6) bond length is 0.95 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(5) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(14) bond length is 1.38 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(7) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(7) bond length is 0.95 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(3), and one H(8) atom. The C(12)-N(3) bond length is 1.33 Å. The C(12)-H(8) bond length is 0.95 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(13)-N(3) bond length is 1.32 Å. The C(13)-H(9) bond length is 0.95 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(10) and one H(10) atom. The C(14)-H(10) bond length is 0.95 Å. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(11) atom. The C(15)-N(4) bond length is 1.34 Å. The C(15)-H(11) bond length is 0.95 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(13) atom. The C(17)-C(18) bond length is 1.42 Å. The C(17)-H(13) bond length is 0.95 Å. In the sixteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(18) bond length is 1.38 Å. The C(19)-C(20) bond length is 1.39 Å. The C(19)-C(24) bond length is 1.49 Å. In the seventeenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(16) atom. The C(23)-N(5) bond length is 1.32 Å. The C(23)-H(16) bond length is 0.95 Å. In the eighteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(17) atom. The C(25)-C(24) bond length is 1.37 Å. The C(25)-H(17) bond length is 0.95 Å. In the nineteenth C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(38) atom. The C(33)-C(32) bond length is 1.39 Å. The C(33)-C(34) bond length is 1.39 Å. The C(33)-C(38) bond length is 1.49 Å. In the twentieth C site, C(34) is bonded in a distorted single-bond geometry to one C(33), one C(35), and one N(8) atom. The C(34)-C(35) bond length is 1.42 Å. The C(34)-N(8) bond length is 1.40 Å. In the twenty-first C site, C(40) is bonded in a distorted trigonal planar geometry to one C(39), one N(9), and one H(28) atom. The C(40)-C(39) bond length is 1.36 Å. The C(40)-N(9) bond length is 1.35 Å. The C(40)-H(28) bond length is 0.95 Å. In the twenty-second C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(42), one N(9), and one H(29) atom. The C(41)-C(42) bond length is 1.39 Å. The C(41)-N(9) bond length is 1.33 Å. The C(41)-H(29) bond length is 0.95 Å. In the twenty-third C site, C(42) is bonded in a distorted trigonal planar geometry to one C(38), one C(41), and one H(30) atom. The C(42)-C(38) bond length is 1.39 Å. The C(42)-H(30) bond length is 0.95 Å. In the twenty-fourth C site, C(35) is bonded in a distorted single-bond geometry to one C(34), one C(36), and one H(24) atom. The C(35)-C(36) bond length is 1.38 Å. The C(35)-H(24) bond length is 0.95 Å. In the twenty-fifth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31), one C(33), and one N(7) atom. The C(32)-C(31) bond length is 1.42 Å. The C(32)-N(7) bond length is 1.39 Å. In the twenty-sixth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(28), one N(6), and one H(19) atom. The C(27)-C(28) bond length is 1.37 Å. The C(27)-N(6) bond length is 1.35 Å. The C(27)-H(19) bond length is 0.95 Å. In the twenty-seventh C site, C(36) is bonded in a distorted single-bond geometry to one C(35), one C(37), and one H(25) atom. The C(36)-C(37) bond length is 1.41 Å. The C(36)-H(25) bond length is 0.95 Å. In the twenty-eighth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(36), one N(8), and one H(26) atom. The C(37)-N(8) bond length is 1.34 Å. The C(37)-H(26) bond length is 0.95 Å. In the twenty-ninth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(18) atom. The C(26)-N(6) bond length is 1.32 Å. The C(26)-H(18) bond length is 0.95 Å. In the thirtieth C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(23) atom. The C(31)-H(23) bond length is 0.95 Å. In the thirty-first C site, C(38) is bonded in a trigonal planar geometry to one C(33), one C(39), and one C(42) atom. The C(38)-C(39) bond length is 1.39 Å. In the thirty-second C site, C(39) is bonded in a distorted single-bond geometry to one C(38), one C(40), and one H(27) atom. The C(39)-H(27) bond length is 0.95 Å. In the thirty-third C site, C(28) is bonded in a distorted single-bond geometry to one C(24), one C(27), and one H(20) atom. The C(28)-C(24) bond length is 1.38 Å. The C(28)-H(20) bond length is 0.95 Å. In the thirty-fourth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one N(4) atom. The C(18)-N(4) bond length is 1.39 Å. In the thirty-fifth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one N(5) atom. The C(20)-C(21) bond length is 1.42 Å. The C(20)-N(5) bond length is 1.40 Å. In the thirty-sixth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(21) atom. The C(29)-N(7) bond length is 1.34 Å. The C(29)-H(21) bond length is 0.95 Å. In the thirty-seventh C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(14) atom. The C(21)-H(14) bond length is 0.95 Å. In the thirty-eighth C site, C(24) is bonded in a trigonal planar geometry to one C(19), one C(25), and one C(28) atom. There are nine inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(6), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(12), and one C(13) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(15), and one C(18) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(1), one C(20), and one C(23) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Ag(1), one C(26), and one C(27) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Co(1), one C(29), and one C(32) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Co(1), one C(34), and one C(37) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Ag(1), one C(40), and one C(41) atom. There are twenty-six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(28) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the nineteenth H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the twentieth H site, H(24) is bonded in a single-bond geometry to one C(35) atom. In the twenty-first H site, H(25) is bonded in a single-bond geometry to one C(36) atom. In the twenty-second H site, H(26) is bonded in a single-bond geometry to one C(37) atom. In the twenty-third H site, H(27) is bonded in a single-bond geometry to one C(39) atom. In the twenty-fourth H site, H(28) is bonded in a single-bond geometry to one C(40) atom. In the twenty-fifth H site, H(29) is bonded in a single-bond geometry to one C(41) atom. In the twenty-sixth H site, H(30) is bonded in a single-bond geometry to one C(42) atom. Linkers: 1 [CH]1C=NC(/C(C2=C[CH]N([Ag](N3[CH]C=C(/C(C4=N[CH]C=C4)=C4\C=CC=N4)C=C3)N3[CH]C=C(/C(C4=N[CH]C=C4)=C4\C=CC=N4)C=C3)C=C2)=C2/C=CC=N2)=C1 ,2 [CH]1C=NC([C](C2=C[CH]N([Ag](N3[CH]C=C([C](C4=CC=C[N]4)C4=N[CH]C=C4)C=C3)N3[CH]C=C(/C(C4=C[CH]C=N4)=C4\C=CC=N4)C=C3)C=C2)C2=NC=C[CH]2)=C1 ,1 [CH]1C=NC([C](C2=C[CH]N([Ag](N3[CH]C=C([C](C4=NC=C[CH]4)C4=N[CH]C=C4)C=C3)N3[CH]C=C(/C([C]4C=CC=N4)=C4\C=CC=N4)C=C3)C=C2)C2=N[CH]C=C2)=C1 ,1 [CH]1C=CN=C1[C](C1=C[CH]N([Ag](N2[CH]C=C([C](C3=CC=C[N]3)C3=CC=C[N]3)C=C2)N2[CH]C=C(/C(C3=NC=C[CH]3)=C3\C=CC=N3)C=C2)C=C1)C1=CC=C[N]1 ,1 [CH]1C=NC(/C(C2=C[CH]N([Ag](N3[CH]C=C([C](C4=N[CH]C=C4)C4=N[CH]C=C4)C=C3)N3[CH]C=C(/C([C]4C=CC=N4)=C4\C=CC=N4)C=C3)C=C2)=C2/C=CC=N2)=C1 ,1 [CH]1C=CC([C](C2=C[CH]N([Ag](N3[CH]C=C([C](C4=CC=C[N]4)C4=CC=C[N]4)C=C3)N3[CH]C=C([C](C4=CC=C[N]4)C4=NC=C[CH]4)C=C3)C=C2)C2=CC=C[N]2)=N1 ,1 [CH]1C=NC([C](C2=C[CH]N([Ag](N3[CH]C=C([C](C4=CC=C[N]4)C4=NC=C[CH]4)C=C3)N3[CH]C=C([C](C4=C[CH]C=N4)C4=NC=C[CH]4)C=C3)C=C2)C2=CC=C[N]2)=C1. Metal clusters: 8 [Co]. The MOF has largest included sphere 6.05 A, density 0.98 g/cm3, surface area 4389.77 m2/g, accessible volume 0.47 cm3/g