Co2C22H13(NO2)5(C3H2)2(CH)6 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules; eight 2,3-dimethyl-1,3-butadiene molecules; and four Co2C22H13(NO2)5 clusters. In each Co2C22H13(NO2)5 cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(2), one O(2), one O(5), one O(9), and two equivalent O(1) atoms to form CoNO5 octahedra that share corners with two equivalent Co(2)NO3 tetrahedra and  an edgeedge with one Co(1)NO5 octahedra. The Co(1)-N(2) bond length is 2.11 Å. The Co(1)-O(2) bond length is 2.12 Å. The Co(1)-O(5) bond length is 2.18 Å. The Co(1)-O(9) bond length is 2.10 Å. There is one shorter (2.07 Å) and one longer (2.11 Å) Co(1)-O(1) bond length. In the second Co site, Co(2) is bonded to one N(1), one O(1), one O(4), and one O(8) atom to form corner-sharing CoNO3 tetrahedra. The corner-sharing octahedral tilt angles range from 45-80°. The Co(2)-N(1) bond length is 2.03 Å. The Co(2)-O(1) bond length is 1.94 Å. The Co(2)-O(4) bond length is 1.96 Å. The Co(2)-O(8) bond length is 1.96 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.93 Å. In the third C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(8)-N(2) bond length is 1.33 Å. The C(8)-H(6) bond length is 0.93 Å. In the fourth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(9)-N(2) bond length is 1.35 Å. The C(9)-H(7) bond length is 0.93 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(2), and one O(3) atom. The C(11)-C(12) bond length is 1.51 Å. The C(11)-O(2) bond length is 1.27 Å. The C(11)-O(3) bond length is 1.25 Å. In the sixth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-C(17) bond length is 1.41 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(9) atom. The C(13)-H(9) bond length is 0.93 Å. In the eighth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(12) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(12) bond length is 0.93 Å. In the ninth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(12), one C(16), and one N(3) atom. The C(17)-N(3) bond length is 1.41 Å. In the tenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(3) and one O(7) atom. The C(18)-N(3) bond length is 1.33 Å. The C(18)-O(7) bond length is 1.22 Å. In the eleventh C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(4) and one O(6) atom. The C(19)-N(4) bond length is 1.35 Å. The C(19)-O(6) bond length is 1.22 Å. In the twelfth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(21), one C(25), and one N(4) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-C(25) bond length is 1.41 Å. The C(20)-N(4) bond length is 1.40 Å. In the thirteenth C site, C(21) is bonded in a single-bond geometry to one C(20) and one H(13) atom. The C(21)-H(13) bond length is 0.93 Å. In the fourteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(16) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(16) bond length is 0.93 Å. In the fifteenth C site, C(25) is bonded in a trigonal planar geometry to one C(20), one C(24), and one C(26) atom. The C(25)-C(26) bond length is 1.50 Å. In the sixteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(4), and one O(5) atom. The C(26)-O(4) bond length is 1.28 Å. The C(26)-O(5) bond length is 1.26 Å. In the seventeenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(8), and one O(9) atom. The C(27)-C(28) bond length is 1.49 Å. The C(27)-O(8) bond length is 1.28 Å. The C(27)-O(9) bond length is 1.24 Å. In the eighteenth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(33) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-C(33) bond length is 1.41 Å. In the nineteenth C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(17) atom. The C(29)-H(17) bond length is 0.93 Å. In the twentieth C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(20) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-H(20) bond length is 0.93 Å. In the twenty-first C site, C(33) is bonded in a distorted trigonal planar geometry to one C(28), one C(32), and one N(5) atom. The C(33)-N(5) bond length is 1.40 Å. In the twenty-second C site, C(34) is bonded in a distorted bent 120 degrees geometry to one N(5) and one O(10) atom. The C(34)-N(5) bond length is 1.34 Å. The C(34)-O(10) bond length is 1.22 Å. There are five inequivalent N sites. In the first N site, N(3) is bonded in a distorted trigonal planar geometry to one C(17), one C(18), and one H(21) atom. The N(3)-H(21) bond length is 0.86 Å. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(19), one C(20), and one H(22) atom. The N(4)-H(22) bond length is 0.86 Å. In the third N site, N(1) is bonded in a trigonal planar geometry to one Co(2), one C(1), and one C(5) atom. In the fourth N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(8), and one C(9) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(33), one C(34), and one H(23) atom. The N(5)-H(23) bond length is 0.86 Å. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(29) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(32) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one N(3) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one N(4) atom. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one N(5) atom. There are ten inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one C(11) atom. In the second O site, O(3) is bonded in a single-bond geometry to one C(11) atom. In the third O site, O(1) is bonded in a distorted T-shaped geometry to one Co(2) and two equivalent Co(1) atoms. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(19) atom. In the fifth O site, O(7) is bonded in a single-bond geometry to one C(18) atom. In the sixth O site, O(8) is bonded in a bent 120 degrees geometry to one Co(2) and one C(27) atom. In the seventh O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(27) atom. In the eighth O site, O(10) is bonded in a single-bond geometry to one C(34) atom. In the ninth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(2) and one C(26) atom. In the tenth O site, O(5) is bonded in a bent 150 degrees geometry to one Co(1) and one C(26) atom. Linkers: 4 c1cc(-c2ccncc2)ccn1 ,6 [O]C(=O)c1ccccc1NC(=O)C(=O)Nc1ccccc1C([O])=O ,2 [O]C(=O)c1[c][c]ccc1NC(=O)C(=O)Nc1ccccc1C([O])=O. Metal clusters: 2 O=[C]O[Co@]12O[C]O[Co](O[C]O1)O[Co@@]1(O[C]=O)O[C]O[Co](O[C]O1)O2. The MOF has largest included sphere 4.57 A, density 1.41 g/cm3, surface area 4335.26 m2/g, accessible volume 0.24 cm3/g