ZnC12H8(NO2)2(CH)8CHN(OC6H4) is Indium-derived structured and crystallizes in the orthorhombic Pccn space group. The structure is zero-dimensional and consists of sixteen isobutylene molecules, eight CHN(OC6H4) clusters, and eight ZnC12H8(NO2)2 clusters. In each CHN(OC6H4) cluster, there are seven inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.33 Å. The C(3)-H(3) bond length is 0.93 Å. In the second C site, C(4) is bonded in a trigonal planar geometry to one C(15), one C(3), and one C(5) atom. The C(4)-C(15) bond length is 1.53 Å. The C(4)-C(5) bond length is 1.36 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one N(1) atom. The C(7)-C(12) bond length is 1.33 Å. The C(7)-C(8) bond length is 1.37 Å. The C(7)-N(1) bond length is 1.42 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 0.93 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(9) atom. The C(12)-H(9) bond length is 0.93 Å. In the seventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one O(5) atom. The C(15)-N(1) bond length is 1.28 Å. The C(15)-O(5) bond length is 1.25 Å. N(1) is bonded in a distorted trigonal planar geometry to one C(15), one C(7), and one H(1) atom. The N(1)-H(1) bond length is 0.86 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. O(5) is bonded in a single-bond geometry to one C(15) atom. In each ZnC12H8(NO2)2 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to one N(2), one N(3), one O(1), and one O(4) atom. The Zn(1)-N(2) bond length is 2.04 Å. The Zn(1)-N(3) bond length is 2.05 Å. The Zn(1)-O(1) bond length is 1.93 Å. The Zn(1)-O(4) bond length is 1.99 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(13), one C(2), and one C(6) atom. The C(1)-C(13) bond length is 1.52 Å. The C(1)-C(2) bond length is 1.36 Å. The C(1)-C(6) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2,5) atom. The C(2)-H(2,5) bond length is 0.93 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(2,5) atom. The C(6)-H(2,5) bond length is 0.93 Å. In the fourth C site, C(9) is bonded in a single-bond geometry to one C(10) and one H(7) atom. The C(9)-C(10) bond length is 1.34 Å. The C(9)-H(7) bond length is 0.93 Å. In the fifth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(9) atom. The C(10)-C(11) bond length is 1.34 Å. The C(10)-C(14) bond length is 1.52 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(11)-H(8) bond length is 0.93 Å. In the seventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(3), and one O(4) atom. The C(13)-O(3) bond length is 1.19 Å. The C(13)-O(4) bond length is 1.27 Å. In the eighth C site, C(14) is bonded in a bent 120 degrees geometry to one C(10), one O(1), and one O(2) atom. The C(14)-O(1) bond length is 1.20 Å. The C(14)-O(2) bond length is 1.26 Å. In the ninth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(10) atom. The C(16)-N(3) bond length is 1.29 Å. The C(16)-H(10) bond length is 0.93 Å. In the tenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(13) atom. The C(20)-N(3) bond length is 1.35 Å. The C(20)-H(13) bond length is 0.93 Å. In the eleventh C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(19) atom. The C(25)-N(2) bond length is 1.33 Å. The C(25)-H(19) bond length is 0.93 Å. In the twelfth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(20) atom. The C(26)-N(2) bond length is 1.31 Å. The C(26)-H(20) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(25), and one C(26) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(16), and one C(20) atom. There are seven inequivalent H sites. In the first H site, H(2,5) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(26) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(14) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(13) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zn(1) and one C(13) atom. Linkers: 1 c1cc(CCc2ccncc2)ccn1 ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH][C]=[CH].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]#[C].[C]=N[Zn].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]=[C]/C=[C]\[N].[C]N([C])[Zn]([O])([O])/N=[C]/[C]=[C].[C]O[Zn].[C][C]=[CH].[C][C]=[CH].[C][C]=[C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[NH].[NH].[NH].[NH].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][Zn]O[C]=O.[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[Zn].[Zn].[Zn] ,1 [CH2]C/[C]=C/C=[N].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=CC(=[CH])[NH].[CH]=[N].[CH][C]=[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]#[C].[C]#[C].[C]/[C]=C\[C].[C]/[C]=[C]\[C]=[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[CH].[C]=[CH].[C]=[C]/C=[C]\[CH].[C]=[C][CH].[C]=[C][CH].[C][CH].[C][C]=[C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[NH].[NH].[NH].[NH].[NH].[NH].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][Zn].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[Zn].[Zn].[Zn].[Zn].[Zn].[Zn] ,1 [C]/C=C(\C=[CH])CCC1=C[CH]N([Zn@](OC(=O)c2ccc(NC(=O)c3ccc(C([O])=O)cc3)cc2)(OC(=O)c2ccc(C(=O)Nc3ccc(C([O])=O)cc3)cc2)N2[CH]C=C(CCc3c[c]ncc3)C=C2)C=C1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 5.00 A, density 1.19 g/cm3, surface area 5137.73 m2/g, accessible volume 0.39 cm3/g