La3C123N2H77O19 crystallizes in the hexagonal P6_5 space group. There are three inequivalent La sites. In the first La site, La(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(6), two equivalent O(4), and two equivalent O(5) atoms. The La(1)-O(1) bond length is 2.76 Å. The La(1)-O(2) bond length is 2.64 Å. The La(1)-O(3) bond length is 2.48 Å. The La(1)-O(6) bond length is 2.48 Å. There is one shorter (2.51 Å) and one longer (2.81 Å) La(1)-O(4) bond length. There is one shorter (2.54 Å) and one longer (2.77 Å) La(1)-O(5) bond length. In the second La site, La(2) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(15), one O(18), one O(19), one O(7), one O(8), and one O(9) atom. The La(2)-O(10) bond length is 2.56 Å. The La(2)-O(11) bond length is 2.64 Å. The La(2)-O(15) bond length is 2.68 Å. The La(2)-O(18) bond length is 2.56 Å. The La(2)-O(19) bond length is 2.85 Å. The La(2)-O(7) bond length is 2.56 Å. The La(2)-O(8) bond length is 2.37 Å. The La(2)-O(9) bond length is 2.44 Å. In the third La site, La(3) is bonded in a 10-coordinate geometry to one H(71), one O(11), one O(12), one O(13), one O(14), one O(15), one O(16), one O(17), one O(19), and one O(7) atom. The La(3)-H(71) bond length is 2.75 Å. The La(3)-O(11) bond length is 2.90 Å. The La(3)-O(12) bond length is 2.41 Å. The La(3)-O(13) bond length is 2.45 Å. The La(3)-O(14) bond length is 2.42 Å. The La(3)-O(15) bond length is 2.59 Å. The La(3)-O(16) bond length is 2.56 Å. The La(3)-O(17) bond length is 2.50 Å. The La(3)-O(19) bond length is 2.62 Å. The La(3)-O(7) bond length is 2.66 Å. There are one hundred and twenty-three inequivalent C sites. In the first C site, C(33) is bonded in a trigonal planar geometry to one C(112), one C(31), and one C(96) atom. The C(33)-C(112) bond length is 1.39 Å. The C(33)-C(31) bond length is 1.39 Å. The C(33)-C(96) bond length is 1.52 Å. In the second C site, C(34) is bonded in a distorted single-bond geometry to one C(25), one C(36), and one H(24) atom. The C(34)-C(25) bond length is 1.44 Å. The C(34)-C(36) bond length is 1.42 Å. The C(34)-H(24) bond length is 0.95 Å. In the third C site, C(35) is bonded in a trigonal planar geometry to one C(17), one C(46), and one C(54) atom. The C(35)-C(17) bond length is 1.47 Å. The C(35)-C(46) bond length is 1.54 Å. The C(35)-C(54) bond length is 1.34 Å. In the fourth C site, C(36) is bonded in a trigonal planar geometry to one C(34), one C(41), and one C(98) atom. The C(36)-C(41) bond length is 1.38 Å. The C(36)-C(98) bond length is 1.34 Å. In the fifth C site, C(37) is bonded in a trigonal planar geometry to one C(114), one C(51), and one C(93) atom. The C(37)-C(114) bond length is 1.38 Å. The C(37)-C(51) bond length is 1.42 Å. The C(37)-C(93) bond length is 1.51 Å. In the sixth C site, C(38) is bonded in a bent 120 degrees geometry to one C(1), one O(2), and one O(4) atom. The C(38)-C(1) bond length is 1.53 Å. The C(38)-O(2) bond length is 1.16 Å. The C(38)-O(4) bond length is 1.32 Å. In the seventh C site, C(39) is bonded in a single-bond geometry to one C(53), one C(63), and one H(25) atom. The C(39)-C(53) bond length is 1.36 Å. The C(39)-C(63) bond length is 1.39 Å. The C(39)-H(25) bond length is 0.95 Å. In the eighth C site, C(40) is bonded in a trigonal planar geometry to one C(110), one C(49), and one C(96) atom. The C(40)-C(110) bond length is 1.54 Å. The C(40)-C(49) bond length is 1.47 Å. The C(40)-C(96) bond length is 1.29 Å. In the ninth C site, C(41) is bonded in a trigonal planar geometry to one C(15), one C(21), and one C(36) atom. The C(41)-C(15) bond length is 1.50 Å. The C(41)-C(21) bond length is 1.43 Å. In the tenth C site, C(42) is bonded in a distorted single-bond geometry to one C(31), one C(60), and one H(26) atom. The C(42)-C(31) bond length is 1.39 Å. The C(42)-C(60) bond length is 1.39 Å. The C(42)-H(26) bond length is 0.95 Å. In the eleventh C site, C(43) is bonded in a distorted single-bond geometry to one C(13), one C(94), and one H(27) atom. The C(43)-C(13) bond length is 1.25 Å. The C(43)-C(94) bond length is 1.54 Å. The C(43)-H(27) bond length is 0.95 Å. In the twelfth C site, C(44) is bonded in a trigonal planar geometry to one C(24), one C(48), and one C(65) atom. The C(44)-C(24) bond length is 1.39 Å. The C(44)-C(48) bond length is 1.52 Å. The C(44)-C(65) bond length is 1.39 Å. In the thirteenth C site, C(45) is bonded in a trigonal planar geometry to one C(113), one C(75), and one C(92) atom. The C(45)-C(113) bond length is 1.41 Å. The C(45)-C(75) bond length is 1.42 Å. The C(45)-C(92) bond length is 1.42 Å. In the fourteenth C site, C(46) is bonded in a trigonal planar geometry to one C(29), one C(35), and one C(67) atom. The C(46)-C(29) bond length is 1.52 Å. The C(46)-C(67) bond length is 1.34 Å. In the fifteenth C site, C(47) is bonded in a distorted single-bond geometry to one C(5) and one H(28) atom. The C(47)-C(5) bond length is 1.36 Å. The C(47)-H(28) bond length is 0.95 Å. In the sixteenth C site, C(48) is bonded in a distorted single-bond geometry to one C(44) and one H(29) atom. The C(48)-H(29) bond length is 0.95 Å. In the seventeenth C site, C(119) is bonded in a bent 120 degrees geometry to one C(87), one O(13), and one O(8) atom. The C(119)-C(87) bond length is 1.55 Å. The C(119)-O(13) bond length is 1.26 Å. The C(119)-O(8) bond length is 1.13 Å. In the eighteenth C site, C(120) is bonded in a bent 120 degrees geometry to one C(60), one O(12), and one O(9) atom. The C(120)-C(60) bond length is 1.51 Å. The C(120)-O(12) bond length is 1.12 Å. The C(120)-O(9) bond length is 1.29 Å. In the nineteenth C site, C(49) is bonded in a trigonal planar geometry to one C(28), one C(29), and one C(40) atom. The C(49)-C(28) bond length is 1.41 Å. The C(49)-C(29) bond length is 1.36 Å. In the twentieth C site, C(122) is bonded to one N(2), one H(72), one H(73), and one H(74) atom to form corner-sharing CH3N tetrahedra. The C(122)-N(2) bond length is 1.46 Å. The C(122)-H(72) bond length is 0.98 Å. The C(122)-H(73) bond length is 0.98 Å. The C(122)-H(74) bond length is 0.98 Å. In the twenty-first C site, C(123) is bonded to one N(2), one H(75), one H(76), and one H(77) atom to form corner-sharing CH3N tetrahedra. The C(123)-N(2) bond length is 1.46 Å. The C(123)-H(75) bond length is 0.98 Å. The C(123)-H(76) bond length is 0.98 Å. The C(123)-H(77) bond length is 0.98 Å. In the twenty-second C site, C(50) is bonded in a distorted single-bond geometry to one C(19) and one H(30) atom. The C(50)-C(19) bond length is 1.39 Å. The C(50)-H(30) bond length is 0.95 Å. In the twenty-third C site, C(51) is bonded in a distorted single-bond geometry to one C(37), one C(99), and one H(31) atom. The C(51)-C(99) bond length is 1.34 Å. The C(51)-H(31) bond length is 0.95 Å. In the twenty-fourth C site, C(52) is bonded in a trigonal planar geometry to one C(101), one C(56), and one C(91) atom. The C(52)-C(101) bond length is 1.37 Å. The C(52)-C(56) bond length is 1.47 Å. The C(52)-C(91) bond length is 1.35 Å. In the twenty-fifth C site, C(53) is bonded in a trigonal planar geometry to one C(26), one C(39), and one C(99) atom. The C(53)-C(26) bond length is 1.40 Å. The C(53)-C(99) bond length is 1.46 Å. In the twenty-sixth C site, C(54) is bonded in a distorted single-bond geometry to one C(35) and one H(32) atom. The C(54)-H(32) bond length is 0.95 Å. In the twenty-seventh C site, C(55) is bonded in a trigonal planar geometry to one C(63), one C(74), and one C(75) atom. The C(55)-C(63) bond length is 1.59 Å. The C(55)-C(74) bond length is 1.41 Å. The C(55)-C(75) bond length is 1.29 Å. In the twenty-eighth C site, C(56) is bonded in a distorted single-bond geometry to one C(52), one C(89), and one H(33) atom. The C(56)-C(89) bond length is 1.32 Å. The C(56)-H(33) bond length is 0.95 Å. In the twenty-ninth C site, C(57) is bonded in a single-bond geometry to one C(2) and one H(34) atom. The C(57)-C(2) bond length is 1.39 Å. The C(57)-H(34) bond length is 0.95 Å. In the thirtieth C site, C(58) is bonded in a trigonal planar geometry to one C(104), one C(59), and one C(88) atom. The C(58)-C(104) bond length is 1.39 Å. The C(58)-C(59) bond length is 1.47 Å. The C(58)-C(88) bond length is 1.39 Å. In the thirty-first C site, C(59) is bonded in a distorted single-bond geometry to one C(58), one C(95), and one H(35) atom. The C(59)-C(95) bond length is 1.31 Å. The C(59)-H(35) bond length is 0.95 Å. In the thirty-second C site, C(60) is bonded in a trigonal planar geometry to one C(120), one C(42), and one C(64) atom. The C(60)-C(64) bond length is 1.39 Å. In the thirty-third C site, C(61) is bonded in a distorted single-bond geometry to one C(70), one C(87), and one H(36) atom. The C(61)-C(70) bond length is 1.39 Å. The C(61)-C(87) bond length is 1.33 Å. The C(61)-H(36) bond length is 0.95 Å. In the thirty-fourth C site, C(62) is bonded in a distorted single-bond geometry to one C(113), one C(80), and one H(37) atom. The C(62)-C(113) bond length is 1.53 Å. The C(62)-C(80) bond length is 1.30 Å. The C(62)-H(37) bond length is 0.95 Å. In the thirty-fifth C site, C(63) is bonded in a trigonal planar geometry to one C(16), one C(39), and one C(55) atom. The C(63)-C(16) bond length is 1.40 Å. In the thirty-sixth C site, C(64) is bonded in a distorted single-bond geometry to one C(60) and one H(38) atom. The C(64)-H(38) bond length is 0.95 Å. In the thirty-seventh C site, C(65) is bonded in a trigonal planar geometry to one C(106), one C(44), and one C(84) atom. The C(65)-C(106) bond length is 1.39 Å. The C(65)-C(84) bond length is 1.39 Å. In the thirty-eighth C site, C(66) is bonded in a distorted single-bond geometry to one C(20) and one H(39) atom. The C(66)-C(20) bond length is 1.43 Å. The C(66)-H(39) bond length is 0.95 Å. In the thirty-ninth C site, C(67) is bonded in a single-bond geometry to one C(46), one C(76), and one H(40) atom. The C(67)-C(76) bond length is 1.47 Å. The C(67)-H(40) bond length is 0.95 Å. In the fortieth C site, C(68) is bonded in a distorted single-bond geometry to one C(100) and one H(41) atom. The C(68)-C(100) bond length is 1.42 Å. The C(68)-H(41) bond length is 0.95 Å. In the forty-first C site, C(69) is bonded in a distorted single-bond geometry to one C(89) and one H(42) atom. The C(69)-C(89) bond length is 1.36 Å. The C(69)-H(42) bond length is 0.95 Å. In the forty-second C site, C(70) is bonded in a trigonal planar geometry to one C(61), one C(85), and one C(94) atom. The C(70)-C(85) bond length is 1.36 Å. The C(70)-C(94) bond length is 1.43 Å. In the forty-third C site, C(71) is bonded in a trigonal planar geometry to one C(24), one C(78), and one C(9) atom. The C(71)-C(24) bond length is 1.39 Å. The C(71)-C(78) bond length is 1.39 Å. The C(71)-C(9) bond length is 1.53 Å. In the forty-fourth C site, C(72) is bonded in a trigonal planar geometry to one C(23), one C(89), and one C(98) atom. The C(72)-C(23) bond length is 1.50 Å. The C(72)-C(89) bond length is 1.53 Å. The C(72)-C(98) bond length is 1.38 Å. In the forty-fifth C site, C(73) is bonded in a distorted single-bond geometry to one C(91) and one H(43) atom. The C(73)-C(91) bond length is 1.33 Å. The C(73)-H(43) bond length is 0.95 Å. In the forty-sixth C site, C(74) is bonded in a distorted single-bond geometry to one C(55) and one H(44) atom. The C(74)-H(44) bond length is 0.95 Å. In the forty-seventh C site, C(75) is bonded in a distorted single-bond geometry to one C(45), one C(55), and one H(45) atom. The C(75)-H(45) bond length is 0.95 Å. In the forty-eighth C site, C(76) is bonded in a trigonal planar geometry to one C(28), one C(67), and one C(95) atom. The C(76)-C(28) bond length is 1.37 Å. The C(76)-C(95) bond length is 1.55 Å. In the forty-ninth C site, C(77) is bonded in a distorted single-bond geometry to one C(82), one C(91), and one H(46) atom. The C(77)-C(82) bond length is 1.39 Å. The C(77)-C(91) bond length is 1.51 Å. The C(77)-H(46) bond length is 0.95 Å. In the fiftieth C site, C(78) is bonded in a distorted single-bond geometry to one C(71) and one H(47) atom. The C(78)-H(47) bond length is 0.95 Å. In the fifty-first C site, C(79) is bonded in a trigonal planar geometry to one C(14), one C(20), and one C(27) atom. The C(79)-C(14) bond length is 1.38 Å. The C(79)-C(20) bond length is 1.47 Å. The C(79)-C(27) bond length is 1.43 Å. In the fifty-second C site, C(80) is bonded in a trigonal planar geometry to one C(116), one C(62), and one C(86) atom. The C(80)-C(116) bond length is 1.46 Å. The C(80)-C(86) bond length is 1.53 Å. In the fifty-third C site, C(81) is bonded in a distorted single-bond geometry to one C(22) and one H(48) atom. The C(81)-C(22) bond length is 1.31 Å. The C(81)-H(48) bond length is 0.95 Å. In the fifty-fourth C site, C(82) is bonded in a trigonal planar geometry to one C(111), one C(118), and one C(77) atom. The C(82)-C(111) bond length is 1.41 Å. The C(82)-C(118) bond length is 1.46 Å. In the fifty-fifth C site, C(83) is bonded in a distorted single-bond geometry to one C(4), one C(93), and one H(49) atom. The C(83)-C(4) bond length is 1.40 Å. The C(83)-C(93) bond length is 1.43 Å. The C(83)-H(49) bond length is 0.95 Å. In the fifty-sixth C site, C(84) is bonded in a distorted single-bond geometry to one C(22), one C(65), and one H(50) atom. The C(84)-C(22) bond length is 1.49 Å. The C(84)-H(50) bond length is 0.95 Å. In the fifty-seventh C site, C(85) is bonded in a distorted single-bond geometry to one C(70) and one H(51) atom. The C(85)-H(51) bond length is 0.95 Å. In the fifty-eighth C site, C(86) is bonded in a distorted bent 120 degrees geometry to one C(80), one O(16), and one O(7) atom. The C(86)-O(16) bond length is 1.25 Å. The C(86)-O(7) bond length is 1.31 Å. In the fifty-ninth C site, C(87) is bonded in a trigonal planar geometry to one C(115), one C(119), and one C(61) atom. The C(87)-C(115) bond length is 1.41 Å. In the sixtieth C site, C(88) is bonded in a trigonal planar geometry to one C(102), one C(58), and one C(90) atom. The C(88)-C(102) bond length is 1.31 Å. The C(88)-C(90) bond length is 1.39 Å. In the sixty-first C site, C(89) is bonded in a trigonal planar geometry to one C(56), one C(69), and one C(72) atom. In the sixty-second C site, C(90) is bonded in a distorted single-bond geometry to one C(2), one C(88), and one H(52) atom. The C(90)-C(2) bond length is 1.39 Å. The C(90)-H(52) bond length is 0.95 Å. In the sixty-third C site, C(91) is bonded in a trigonal planar geometry to one C(52), one C(73), and one C(77) atom. In the sixty-fourth C site, C(92) is bonded in a distorted single-bond geometry to one C(45) and one H(53) atom. The C(92)-H(53) bond length is 0.95 Å. In the sixty-fifth C site, C(93) is bonded in a trigonal planar geometry to one C(3), one C(37), and one C(83) atom. The C(93)-C(3) bond length is 1.30 Å. In the sixty-sixth C site, C(94) is bonded in a trigonal planar geometry to one C(107), one C(43), and one C(70) atom. The C(94)-C(107) bond length is 1.41 Å. In the sixty-seventh C site, C(95) is bonded in a trigonal planar geometry to one C(109), one C(59), and one C(76) atom. The C(95)-C(109) bond length is 1.35 Å. In the sixty-eighth C site, C(96) is bonded in a distorted single-bond geometry to one C(33), one C(40), and one H(54) atom. The C(96)-H(54) bond length is 0.95 Å. In the sixty-ninth C site, C(97) is bonded in a distorted single-bond geometry to one C(113) and one H(55) atom. The C(97)-C(113) bond length is 1.34 Å. The C(97)-H(55) bond length is 0.95 Å. In the seventieth C site, C(98) is bonded in a distorted single-bond geometry to one C(36), one C(72), and one H(56) atom. The C(98)-H(56) bond length is 0.95 Å. In the seventy-first C site, C(99) is bonded in a trigonal planar geometry to one C(51), one C(53), and one C(6) atom. The C(99)-C(6) bond length is 1.47 Å. In the seventy-second C site, C(100) is bonded in a trigonal planar geometry to one C(18), one C(19), and one C(68) atom. The C(100)-C(18) bond length is 1.45 Å. The C(100)-C(19) bond length is 1.45 Å. In the seventy-third C site, C(101) is bonded in a distorted single-bond geometry to one C(52) and one H(57) atom. The C(101)-H(57) bond length is 0.95 Å. In the seventy-fourth C site, C(102) is bonded in a distorted single-bond geometry to one C(88) and one H(58) atom. The C(102)-H(58) bond length is 0.95 Å. In the seventy-fifth C site, C(103) is bonded in a single-bond geometry to one C(4) and one H(59) atom. The C(103)-C(4) bond length is 1.35 Å. The C(103)-H(59) bond length is 0.95 Å. In the seventy-sixth C site, C(104) is bonded in a distorted single-bond geometry to one C(58) and one H(60) atom. The C(104)-H(60) bond length is 0.95 Å. In the seventy-seventh C site, C(105) is bonded in a single-bond geometry to one C(13) and one H(61) atom. The C(105)-C(13) bond length is 1.47 Å. The C(105)-H(61) bond length is 0.95 Å. In the seventy-eighth C site, C(106) is bonded in a distorted single-bond geometry to one C(65) and one H(62) atom. The C(106)-H(62) bond length is 0.95 Å. In the seventy-ninth C site, C(107) is bonded in a distorted single-bond geometry to one C(94) and one H(63) atom. The C(107)-H(63) bond length is 0.95 Å. In the eightieth C site, C(108) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(10), and one O(19) atom. The C(108)-C(2) bond length is 1.50 Å. The C(108)-O(10) bond length is 1.30 Å. The C(108)-O(19) bond length is 1.46 Å. In the eighty-first C site, C(109) is bonded in a distorted single-bond geometry to one C(95) and one H(64) atom. The C(109)-H(64) bond length is 0.95 Å. In the eighty-second C site, C(110) is bonded in a single-bond geometry to one C(40) and one H(65) atom. The C(110)-H(65) bond length is 0.95 Å. In the eighty-third C site, C(111) is bonded in a distorted single-bond geometry to one C(82) and one H(66) atom. The C(111)-H(66) bond length is 0.95 Å. In the eighty-fourth C site, C(112) is bonded in a distorted single-bond geometry to one C(33) and one H(67) atom. The C(112)-H(67) bond length is 0.95 Å. In the eighty-fifth C site, C(113) is bonded in a trigonal planar geometry to one C(45), one C(62), and one C(97) atom. In the eighty-sixth C site, C(114) is bonded in a distorted single-bond geometry to one C(37) and one H(68) atom. The C(114)-H(68) bond length is 0.95 Å. In the eighty-seventh C site, C(115) is bonded in a distorted single-bond geometry to one C(87) and one H(69) atom. The C(115)-H(69) bond length is 0.95 Å. In the eighty-eighth C site, C(116) is bonded in a distorted single-bond geometry to one C(80) and one H(70) atom. The C(116)-H(70) bond length is 0.95 Å. In the eighty-ninth C site, C(117) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(11), and one O(17) atom. The C(117)-C(4) bond length is 1.47 Å. The C(117)-O(11) bond length is 1.54 Å. The C(117)-O(17) bond length is 1.30 Å. In the ninetieth C site, C(118) is bonded in a distorted bent 120 degrees geometry to one C(82), one O(15), and one O(18) atom. The C(118)-O(15) bond length is 1.29 Å. The C(118)-O(18) bond length is 1.23 Å. In the ninety-first C site, C(121) is bonded in a 4-coordinate geometry to one C(10), one H(4), one H(71), and one O(14) atom. The C(121)-C(10) bond length is 1.00 Å. The C(121)-H(4) bond length is 0.82 Å. The C(121)-H(71) bond length is 0.95 Å. The C(121)-O(14) bond length is 1.23 Å. In the ninety-second C site, C(1) is bonded in a trigonal planar geometry to one C(18), one C(32), and one C(38) atom. The C(1)-C(18) bond length is 1.30 Å. The C(1)-C(32) bond length is 1.34 Å. In the ninety-third C site, C(2) is bonded in a trigonal planar geometry to one C(108), one C(57), and one C(90) atom. In the ninety-fourth C site, C(3) is bonded in a distorted single-bond geometry to one C(93) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. In the ninety-fifth C site, C(4) is bonded in a trigonal planar geometry to one C(103), one C(117), and one C(83) atom. In the ninety-sixth C site, C(5) is bonded in a trigonal planar geometry to one C(14), one C(47), and one C(7) atom. The C(5)-C(14) bond length is 1.32 Å. The C(5)-C(7) bond length is 1.38 Å. In the ninety-seventh C site, C(6) is bonded in a single-bond geometry to one C(99) and one H(2) atom. The C(6)-H(2) bond length is 0.95 Å. In the ninety-eighth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(5) atom. The C(7)-O(1) bond length is 1.20 Å. The C(7)-O(5) bond length is 1.31 Å. In the ninety-ninth C site, C(8) is bonded in a distorted single-bond geometry to one C(31) and one H(3) atom. The C(8)-C(31) bond length is 1.44 Å. The C(8)-H(3) bond length is 0.95 Å. In the one hundredth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(71), one O(3), and one O(6) atom. The C(9)-O(3) bond length is 1.09 Å. The C(9)-O(6) bond length is 1.38 Å. In the one hundred and first C site, C(10) is bonded in a 4-coordinate geometry to one C(121), one N(1), one H(4), and one O(14) atom. The C(10)-N(1) bond length is 1.45 Å. The C(10)-H(4) bond length is 0.95 Å. The C(10)-O(14) bond length is 1.22 Å. In the one hundred and second C site, C(11) is bonded to one N(1); one H(5); and two equivalent H(6,7) atoms to form corner-sharing CH3N tetrahedra. The C(11)-N(1) bond length is 1.46 Å. The C(11)-H(5) bond length is 0.98 Å. Both C(11)-H(6,7) bond lengths are 0.98 Å. In the one hundred and third C site, C(12) is bonded to one N(1), one H(10), one H(8), and one H(9) atom to form corner-sharing CH3N tetrahedra. The C(12)-N(1) bond length is 1.46 Å. The C(12)-H(10) bond length is 0.98 Å. The C(12)-H(8) bond length is 0.98 Å. The C(12)-H(9) bond length is 0.98 Å. In the one hundred and fourth C site, C(13) is bonded in a trigonal planar geometry to one C(105), one C(25), and one C(43) atom. The C(13)-C(25) bond length is 1.48 Å. In the one hundred and fifth C site, C(14) is bonded in a distorted single-bond geometry to one C(5), one C(79), and one H(11) atom. The C(14)-H(11) bond length is 0.95 Å. In the one hundred and sixth C site, C(15) is bonded in a single-bond geometry to one C(20), one C(41), and one H(12) atom. The C(15)-C(20) bond length is 1.36 Å. The C(15)-H(12) bond length is 0.95 Å. In the one hundred and seventh C site, C(16) is bonded in a distorted single-bond geometry to one C(30), one C(63), and one H(13) atom. The C(16)-C(30) bond length is 1.30 Å. The C(16)-H(13) bond length is 0.95 Å. In the one hundred and eighth C site, C(17) is bonded in a single-bond geometry to one C(19), one C(35), and one H(14) atom. The C(17)-C(19) bond length is 1.38 Å. The C(17)-H(14) bond length is 0.95 Å. In the one hundred and ninth C site, C(18) is bonded in a distorted single-bond geometry to one C(1), one C(100), and one H(15) atom. The C(18)-H(15) bond length is 0.95 Å. In the one hundred and tenth C site, C(19) is bonded in a trigonal planar geometry to one C(100), one C(17), and one C(50) atom. In the one hundred and eleventh C site, C(20) is bonded in a trigonal planar geometry to one C(15), one C(66), and one C(79) atom. In the one hundred and twelfth C site, C(21) is bonded in a distorted single-bond geometry to one C(41) and one H(16) atom. The C(21)-H(16) bond length is 0.95 Å. In the one hundred and thirteenth C site, C(22) is bonded in a trigonal planar geometry to one C(30), one C(81), and one C(84) atom. The C(22)-C(30) bond length is 1.60 Å. In the one hundred and fourteenth C site, C(23) is bonded in a single-bond geometry to one C(25), one C(72), and one H(17) atom. The C(23)-C(25) bond length is 1.30 Å. The C(23)-H(17) bond length is 0.95 Å. In the one hundred and fifteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(44), one C(71), and one H(18) atom. The C(24)-H(18) bond length is 0.95 Å. In the one hundred and sixteenth C site, C(25) is bonded in a trigonal planar geometry to one C(13), one C(23), and one C(34) atom. In the one hundred and seventeenth C site, C(26) is bonded in a distorted single-bond geometry to one C(30), one C(53), and one H(19) atom. The C(26)-C(30) bond length is 1.33 Å. The C(26)-H(19) bond length is 0.95 Å. In the one hundred and eighteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(79) and one H(20) atom. The C(27)-H(20) bond length is 0.95 Å. In the one hundred and nineteenth C site, C(28) is bonded in a single-bond geometry to one C(49), one C(76), and one H(21) atom. The C(28)-H(21) bond length is 0.95 Å. In the one hundred and twentieth C site, C(29) is bonded in a distorted single-bond geometry to one C(46), one C(49), and one H(22) atom. The C(29)-H(22) bond length is 0.95 Å. In the one hundred and twenty-first C site, C(30) is bonded in a trigonal planar geometry to one C(16), one C(22), and one C(26) atom. In the one hundred and twenty-second C site, C(31) is bonded in a trigonal planar geometry to one C(33), one C(42), and one C(8) atom. In the one hundred and twenty-third C site, C(32) is bonded in a single-bond geometry to one C(1) and one H(23) atom. The C(32)-H(23) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted T-shaped geometry to one C(10), one C(11), and one C(12) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one C(122), one C(123), and one H(4) atom. The N(2)-H(4) bond length is 0.71 Å. There are seventy-six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4) is bonded in a 3-coordinate geometry to one C(10), one C(121), and one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6,7) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(26) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(27) atom. In the twentieth H site, H(21) is bonded in a single-bond geometry to one C(28) atom. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one C(29) atom. In the twenty-second H site, H(23) is bonded in a single-bond geometry to one C(32) atom. In the twenty-third H site, H(24) is bonded in a single-bond geometry to one C(34) atom. In the twenty-fourth H site, H(25) is bonded in a single-bond geometry to one C(39) atom. In the twenty-fifth H site, H(26) is bonded in a single-bond geometry to one C(42) atom. In the twenty-sixth H site, H(27) is bonded in a single-bond geometry to one C(43) atom. In the twenty-seventh H site, H(28) is bonded in a single-bond geometry to one C(47) atom. In the twenty-eighth H site, H(29) is bonded in a single-bond geometry to one C(48) atom. In the twenty-ninth H site, H(30) is bonded in a single-bond geometry to one C(50) atom. In the thirtieth H site, H(31) is bonded in a single-bond geometry to one C(51) atom. In the thirty-first H site, H(32) is bonded in a single-bond geometry to one C(54) atom. In the thirty-second H site, H(33) is bonded in a single-bond geometry to one C(56) atom. In the thirty-third H site, H(34) is bonded in a single-bond geometry to one C(57) atom. In the thirty-fourth H site, H(35) is bonded in a single-bond geometry to one C(59) atom. In the thirty-fifth H site, H(36) is bonded in a single-bond geometry to one C(61) atom. In the thirty-sixth H site, H(37) is bonded in a single-bond geometry to one C(62) atom. In the thirty-seventh H site, H(38) is bonded in a single-bond geometry to one C(64) atom. In the thirty-eighth H site, H(39) is bonded in a single-bond geometry to one C(66) atom. In the thirty-ninth H site, H(40) is bonded in a single-bond geometry to one C(67) atom. In the fortieth H site, H(41) is bonded in a single-bond geometry to one C(68) atom. In the forty-first H site, H(42) is bonded in a single-bond geometry to one C(69) atom. In the forty-second H site, H(43) is bonded in a single-bond geometry to one C(73) atom. In the forty-third H site, H(44) is bonded in a single-bond geometry to one C(74) atom. In the forty-fourth H site, H(45) is bonded in a single-bond geometry to one C(75) atom. In the forty-fifth H site, H(46) is bonded in a single-bond geometry to one C(77) atom. In the forty-sixth H site, H(47) is bonded in a single-bond geometry to one C(78) atom. In the forty-seventh H site, H(48) is bonded in a single-bond geometry to one C(81) atom. In the forty-eighth H site, H(49) is bonded in a single-bond geometry to one C(83) atom. In the forty-ninth H site, H(50) is bonded in a single-bond geometry to one C(84) atom. In the fiftieth H site, H(51) is bonded in a single-bond geometry to one C(85) atom. In the fifty-first H site, H(52) is bonded in a single-bond geometry to one C(90) atom. In the fifty-second H site, H(53) is bonded in a single-bond geometry to one C(92) atom. In the fifty-third H site, H(54) is bonded in a single-bond geometry to one C(96) atom. In the fifty-fourth H site, H(55) is bonded in a single-bond geometry to one C(97) atom. In the fifty-fifth H site, H(56) is bonded in a single-bond geometry to one C(98) atom. In the fifty-sixth H site, H(57) is bonded in a single-bond geometry to one C(101) atom. In the fifty-seventh H site, H(58) is bonded in a single-bond geometry to one C(102) atom. In the fifty-eighth H site, H(59) is bonded in a single-bond geometry to one C(103) atom. In the fifty-ninth H site, H(60) is bonded in a single-bond geometry to one C(104) atom. In the sixtieth H site, H(61) is bonded in a single-bond geometry to one C(105) atom. In the sixty-first H site, H(62) is bonded in a single-bond geometry to one C(106) atom. In the sixty-second H site, H(63) is bonded in a single-bond geometry to one C(107) atom. In the sixty-third H site, H(64) is bonded in a single-bond geometry to one C(109) atom. In the sixty-fourth H site, H(65) is bonded in a single-bond geometry to one C(110) atom. In the sixty-fifth H site, H(66) is bonded in a single-bond geometry to one C(111) atom. In the sixty-sixth H site, H(67) is bonded in a single-bond geometry to one C(112) atom. In the sixty-seventh H site, H(68) is bonded in a single-bond geometry to one C(114) atom. In the sixty-eighth H site, H(69) is bonded in a single-bond geometry to one C(115) atom. In the sixty-ninth H site, H(70) is bonded in a single-bond geometry to one C(116) atom. In the seventieth H site, H(71) is bonded in a single-bond geometry to one La(3) and one C(121) atom. In the seventy-first H site, H(72) is bonded in a single-bond geometry to one C(122) atom. In the seventy-second H site, H(73) is bonded in a single-bond geometry to one C(122) atom. In the seventy-third H site, H(74) is bonded in a single-bond geometry to one C(122) atom. In the seventy-fourth H site, H(75) is bonded in a single-bond geometry to one C(123) atom. In the seventy-fifth H site, H(76) is bonded in a single-bond geometry to one C(123) atom. In the seventy-sixth H site, H(77) is bonded in a single-bond geometry to one C(123) atom. There are nineteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one La(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one La(1) and one C(38) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one La(1) and one C(9) atom. In the fourth O site, O(4) is bonded in a 1-coordinate geometry to two equivalent La(1) and one C(38) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent La(1) and one C(7) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one La(1) and one C(9) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one La(2), one La(3), and one C(86) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one La(2) and one C(119) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one La(2) and one C(120) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one La(2) and one C(108) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one La(2), one La(3), and one C(117) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one La(3) and one C(120) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one La(3) and one C(119) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one La(3), one C(10), and one C(121) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one La(2), one La(3), and one C(118) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one La(3) and one C(86) atom. In the seventeenth O site, O(17) is bonded in a distorted water-like geometry to one La(3) and one C(117) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one La(2) and one C(118) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one La(2), one La(3), and one C(108) atom. Linkers: 18 [O]C(=O)c1ccc2cc(-c3cc(-c4ccc5cc(C([O])=O)ccc5c4)cc(-c4ccc5cc(C([O])=O)ccc5c4)c3)ccc2c1. Metal clusters: 18 [La]. The MOF has largest included sphere 6.70 A, density 1.03 g/cm3, surface area 4197.03 m2/g, accessible volume 0.57 cm3/g