Co3C48H28(N5O8)2(CH)4 crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a Co3C48H28(N5O8)2 framework. In the Co3C48H28(N5O8)2 framework, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted octahedral geometry to one N(3), one N(5), one O(1), one O(2), one O(5), and one O(6) atom. The Co(1)-N(3) bond length is 2.17 Å. The Co(1)-N(5) bond length is 2.15 Å. The Co(1)-O(1) bond length is 2.02 Å. The Co(1)-O(2) bond length is 2.03 Å. The Co(1)-O(5) bond length is 2.12 Å. The Co(1)-O(6) bond length is 2.25 Å. In the second Co site, Co(2) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(3) atoms. Both Co(2)-N(1) bond lengths are 2.18 Å. Both Co(2)-O(3) bond lengths are 2.06 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.24 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(9) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(9) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.50 Å. The C(4)-C(6) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(5), and one O(6) atom. The C(5)-O(5) bond length is 1.26 Å. The C(5)-O(6) bond length is 1.26 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4), one C(7), and one H(2) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-H(2) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. The C(7)-C(8) bond length is 1.51 Å. The C(7)-C(9) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.25 Å. The C(8)-O(4) bond length is 1.25 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(2), one C(7), and one H(3) atom. The C(9)-H(3) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(10)-N(1) bond length is 1.33 Å. The C(10)-H(4) bond length is 0.93 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(6) atom. The C(12)-C(13) bond length is 1.37 Å. The C(12)-H(6) bond length is 0.93 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one N(2) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-N(2) bond length is 1.42 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(1), and one H(7) atom. The C(14)-N(1) bond length is 1.33 Å. The C(14)-H(7) bond length is 0.93 Å. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(2), and one O(8) atom. The C(15)-C(16) bond length is 1.50 Å. The C(15)-N(2) bond length is 1.30 Å. The C(15)-O(8) bond length is 1.26 Å. In the fifteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(20) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-C(20) bond length is 1.37 Å. In the sixteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(3), and one H(8) atom. The C(17)-N(3) bond length is 1.35 Å. The C(17)-H(8) bond length is 0.93 Å. In the seventeenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(3), and one H(9) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-N(3) bond length is 1.34 Å. The C(18)-H(9) bond length is 0.93 Å. In the eighteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(21) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-C(21) bond length is 1.49 Å. In the nineteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(16), one C(19), and one H(10) atom. The C(20)-H(10) bond length is 0.93 Å. In the twentieth C site, C(21) is bonded in a distorted water-like geometry to one C(19), one N(4), and one O(7) atom. The C(21)-N(4) bond length is 1.25 Å. The C(21)-O(7) bond length is 1.49 Å. In the twenty-first C site, C(22) is bonded in a distorted trigonal planar geometry to one C(23), one C(26), and one N(4) atom. The C(22)-C(23) bond length is 1.38 Å. The C(22)-C(26) bond length is 1.37 Å. The C(22)-N(4) bond length is 1.41 Å. In the twenty-second C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(11) atom. The C(23)-H(11) bond length is 0.93 Å. In the twenty-third C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(13) atom. The C(25)-N(5) bond length is 1.33 Å. The C(25)-H(13) bond length is 0.93 Å. In the twenty-fourth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(22), one N(5), and one H(14) atom. The C(26)-N(5) bond length is 1.35 Å. The C(26)-H(14) bond length is 0.93 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(2), one C(10), and one C(14) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(15) atom. The N(2)-H(15) bond length is 0.86 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(17), and one C(18) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(21), one C(22), and one H(16) atom. The N(4)-H(16) bond length is 0.86 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(1), one C(25), and one C(26) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(26) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one N(2) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one N(4) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(8) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Co(1) and one C(5) atom. In the sixth O site, O(6) is bonded in a distorted L-shaped geometry to one Co(1) and one C(5) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(21) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(15) atom. Linkers: 2 [O]C(=O)c1cc(C([O])=O)cc(C([O])=O)c1 ,2 [O][C](Nc1cccnc1)c1cncc(C(=O)Nc2cccnc2)c1. Metal clusters: 1 [C]1O[Co]2(O1)O[C]O[Co]1(O[C]O1)O[C]O2 ,1 O=[C]O[Co]O[C]=O. The MOF has largest included sphere 4.80 A, density 1.37 g/cm3, surface area 4193.67 m2/g, accessible volume 0.26 cm3/g