Mn3Zn6C78H40(NO10)4(CH)26 crystallizes in the triclinic P-1 space group. The structure consists of ten 02329_fluka molecules and four isobutylene molecules inside a Mn3Zn6C78H40(NO10)4 framework. In the Mn3Zn6C78H40(NO10)4 framework, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in an octahedral geometry to one O(11), one O(16), one O(19), one O(2), one O(4), and one O(9) atom. The Mn(1)-O(11) bond length is 2.16 Å. The Mn(1)-O(16) bond length is 2.16 Å. The Mn(1)-O(19) bond length is 2.18 Å. The Mn(1)-O(2) bond length is 2.16 Å. The Mn(1)-O(4) bond length is 2.22 Å. The Mn(1)-O(9) bond length is 2.18 Å. In the second Mn site, Mn(2) is bonded to two equivalent O(12), two equivalent O(13), and two equivalent O(8) atoms to form MnO6 octahedra that share corners with two equivalent Zn(2)NO4 trigonal bipyramids. Both Mn(2)-O(12) bond lengths are 2.13 Å. Both Mn(2)-O(13) bond lengths are 2.21 Å. Both Mn(2)-O(8) bond lengths are 2.18 Å. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one N(2), one O(10), one O(6), and one O(7) atom. The Zn(1)-N(2) bond length is 2.04 Å. The Zn(1)-O(10) bond length is 1.90 Å. The Zn(1)-O(6) bond length is 1.94 Å. The Zn(1)-O(7) bond length is 1.94 Å. In the second Zn site, Zn(2) is bonded to one N(1), one O(12), one O(14), one O(20), and one O(5) atom to form distorted ZnNO4 trigonal bipyramids that share  a cornercorner with one Mn(2)O6 octahedra. The corner-sharing octahedral tilt angles are 73°. The Zn(2)-N(1) bond length is 2.06 Å. The Zn(2)-O(12) bond length is 2.37 Å. The Zn(2)-O(14) bond length is 1.91 Å. The Zn(2)-O(20) bond length is 2.07 Å. The Zn(2)-O(5) bond length is 1.92 Å. In the third Zn site, Zn(3) is bonded in a 5-coordinate geometry to one O(15), one O(3), one O(4), and two equivalent O(1) atoms. The Zn(3)-O(15) bond length is 2.03 Å. The Zn(3)-O(3) bond length is 2.09 Å. The Zn(3)-O(4) bond length is 2.55 Å. There is one shorter (2.15 Å) and one longer (2.18 Å) Zn(3)-O(1) bond length. There are thirty-nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(11), one C(5), and one C(6) atom. The C(1)-C(11) bond length is 1.41 Å. The C(1)-C(5) bond length is 1.49 Å. The C(1)-C(6) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(2), and one O(3) atom. The C(2)-C(13) bond length is 1.51 Å. The C(2)-O(2) bond length is 1.25 Å. The C(2)-O(3) bond length is 1.27 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(10), one C(28), and one H(1) atom. The C(3)-C(10) bond length is 1.38 Å. The C(3)-C(28) bond length is 1.39 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a single-bond geometry to one C(13), one C(9), and one H(2) atom. The C(4)-C(13) bond length is 1.37 Å. The C(4)-C(9) bond length is 1.40 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(4) atom. The C(5)-O(1) bond length is 1.27 Å. The C(5)-O(4) bond length is 1.24 Å. In the sixth C site, C(6) is bonded in a single-bond geometry to one C(1), one C(12), and one H(3) atom. The C(6)-C(12) bond length is 1.41 Å. The C(6)-H(3) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(10), and one O(19) atom. The C(7)-C(12) bond length is 1.51 Å. The C(7)-O(10) bond length is 1.27 Å. The C(7)-O(19) bond length is 1.25 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(5), and one O(8) atom. The C(8)-C(9) bond length is 1.50 Å. The C(8)-O(5) bond length is 1.27 Å. The C(8)-O(8) bond length is 1.24 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(19), one C(4), and one C(8) atom. The C(9)-C(19) bond length is 1.37 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(15), one C(3), and one C(34) atom. The C(10)-C(15) bond length is 1.49 Å. The C(10)-C(34) bond length is 1.40 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(11)-H(4) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(23), one C(6), and one C(7) atom. The C(12)-C(23) bond length is 1.37 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(2), one C(24), and one C(4) atom. The C(13)-C(24) bond length is 1.40 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(18), one C(21), and one C(26) atom. The C(14)-C(18) bond length is 1.51 Å. The C(14)-C(21) bond length is 1.37 Å. The C(14)-C(26) bond length is 1.39 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(7), and one O(9) atom. The C(15)-O(7) bond length is 1.27 Å. The C(15)-O(9) bond length is 1.25 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(50), one O(11), and one O(6) atom. The C(16)-C(50) bond length is 1.49 Å. The C(16)-O(11) bond length is 1.25 Å. The C(16)-O(6) bond length is 1.25 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(13), and one O(14) atom. The C(17)-C(30) bond length is 1.49 Å. The C(17)-O(13) bond length is 1.24 Å. The C(17)-O(14) bond length is 1.27 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(15), and one O(16) atom. The C(18)-O(15) bond length is 1.25 Å. The C(18)-O(16) bond length is 1.25 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(19)-H(6) bond length is 0.93 Å. In the twentieth C site, C(21) is bonded in a distorted single-bond geometry to one C(14), one C(32), and one H(8) atom. The C(21)-C(32) bond length is 1.39 Å. The C(21)-H(8) bond length is 0.93 Å. In the twenty-first C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(22)-N(1) bond length is 1.33 Å. The C(22)-H(9) bond length is 0.93 Å. In the twenty-second C site, C(23) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(23)-H(10) bond length is 0.93 Å. In the twenty-third C site, C(24) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(24)-H(11) bond length is 0.93 Å. In the twenty-fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(14) and one H(12) atom. The C(26)-H(12) bond length is 0.93 Å. In the twenty-fifth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(17), and one O(18) atom. The C(27)-C(32) bond length is 1.51 Å. The C(27)-O(17) bond length is 1.30 Å. The C(27)-O(18) bond length is 1.22 Å. In the twenty-sixth C site, C(28) is bonded in a trigonal planar geometry to one C(3), one C(31), and one C(52) atom. The C(28)-C(31) bond length is 1.38 Å. The C(28)-C(52) bond length is 1.48 Å. In the twenty-seventh C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(13) atom. The C(29)-N(2) bond length is 1.33 Å. The C(29)-H(13) bond length is 0.93 Å. In the twenty-eighth C site, C(30) is bonded in a trigonal planar geometry to one C(17), one C(47), and one C(48) atom. The C(30)-C(47) bond length is 1.39 Å. The C(30)-C(48) bond length is 1.41 Å. In the twenty-ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(28) and one H(14) atom. The C(31)-H(14) bond length is 0.93 Å. In the thirtieth C site, C(32) is bonded in a trigonal planar geometry to one C(21), one C(27), and one C(46) atom. The C(32)-C(46) bond length is 1.38 Å. In the thirty-first C site, C(34) is bonded in a distorted single-bond geometry to one C(10) and one H(16) atom. The C(34)-H(16) bond length is 0.93 Å. In the thirty-second C site, C(42) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(25) atom. The C(42)-N(2) bond length is 1.32 Å. The C(42)-H(25) bond length is 0.93 Å. In the thirty-third C site, C(45) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(28) atom. The C(45)-N(1) bond length is 1.33 Å. The C(45)-H(28) bond length is 0.93 Å. In the thirty-fourth C site, C(46) is bonded in a distorted single-bond geometry to one C(32) and one H(29) atom. The C(46)-H(29) bond length is 0.93 Å. In the thirty-fifth C site, C(47) is bonded in a distorted single-bond geometry to one C(30), one C(50), and one H(30) atom. The C(47)-C(50) bond length is 1.39 Å. The C(47)-H(30) bond length is 0.93 Å. In the thirty-sixth C site, C(48) is bonded in a distorted single-bond geometry to one C(30) and one H(31) atom. The C(48)-H(31) bond length is 0.93 Å. In the thirty-seventh C site, C(50) is bonded in a trigonal planar geometry to one C(16), one C(47), and one C(51) atom. The C(50)-C(51) bond length is 1.38 Å. In the thirty-eighth C site, C(51) is bonded in a distorted single-bond geometry to one C(50) and one H(33) atom. The C(51)-H(33) bond length is 0.93 Å. In the thirty-ninth C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(12), and one O(20) atom. The C(52)-O(12) bond length is 1.26 Å. The C(52)-O(20) bond length is 1.26 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(22), and one C(45) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(29), and one C(42) atom. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(17) atom. The H(5)-O(17) bond length is 0.82 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(26) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(29) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(34) atom. In the fifteenth H site, H(25) is bonded in a single-bond geometry to one C(42) atom. In the sixteenth H site, H(28) is bonded in a single-bond geometry to one C(45) atom. In the seventeenth H site, H(29) is bonded in a single-bond geometry to one C(46) atom. In the eighteenth H site, H(30) is bonded in a single-bond geometry to one C(47) atom. In the nineteenth H site, H(31) is bonded in a single-bond geometry to one C(48) atom. In the twentieth H site, H(33) is bonded in a single-bond geometry to one C(51) atom. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to two equivalent Zn(3) and one C(5) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted linear geometry to one Mn(1), one Zn(3), and one C(5) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(8) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(16) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(15) atom. In the eighth O site, O(8) is bonded in a bent 150 degrees geometry to one Mn(2) and one C(8) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(15) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(16) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Mn(2), one Zn(2), and one C(52) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Mn(2) and one C(17) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(17) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(18) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(18) atom. In the seventeenth O site, O(17) is bonded in a water-like geometry to one C(27) and one H(5) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one C(27) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(7) atom. In the twentieth O site, O(20) is bonded in a water-like geometry to one Zn(2) and one C(52) atom. Linkers: 2 c1cc(CCc2ccncc2)ccn1 ,8 [O]C(=O)c1cccc(C([O])=O)c1. Metal clusters: 2 [Mn] ,4 [Zn] ,1 [C]1O[Zn]2O[C]O[Mn]34(O1)(O[C]O2)O[C]O[Zn](O[C]O3)O[C]O4. The MOF has largest included sphere 6.92 A, density 1.39 g/cm3, surface area 4162.18 m2/g, accessible volume 0.30 cm3/g