NiC12H8(NO2)2(C3H2)2(CH)4C2O is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules; eight 2,3-dimethyl-1,3-butadiene molecules; eight dimethyl ether molecules; and four NiC12H8(NO2)2 clusters. In each NiC12H8(NO2)2 cluster, Ni(1) is bonded in an octahedral geometry to one N(1), one N(2), one O(1), one O(2), one O(4), and one O(5) atom. The Ni(1)-N(1) bond length is 2.10 Å. The Ni(1)-N(2) bond length is 2.10 Å. The Ni(1)-O(1) bond length is 2.13 Å. The Ni(1)-O(2) bond length is 2.16 Å. The Ni(1)-O(4) bond length is 2.04 Å. The Ni(1)-O(5) bond length is 2.00 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(8)-N(2) bond length is 1.31 Å. The C(8)-H(6) bond length is 0.95 Å. In the fourth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(9)-N(2) bond length is 1.31 Å. The C(9)-H(7) bond length is 0.95 Å. In the fifth C site, C(11) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(17) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-C(16) bond length is 1.38 Å. The C(11)-C(17) bond length is 1.50 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(9) atom. The C(12)-H(9) bond length is 0.95 Å. In the seventh C site, C(16) is bonded in a distorted single-bond geometry to one C(11) and one H(12) atom. The C(16)-H(12) bond length is 0.95 Å. In the eighth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(4), and one O(5) atom. The C(17)-O(4) bond length is 1.25 Å. The C(17)-O(5) bond length is 1.26 Å. In the ninth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(14,15) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(14,15) bond length is 0.95 Å. In the tenth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-C(24) bond length is 1.49 Å. In the eleventh C site, C(22) is bonded in a single-bond geometry to one C(21) and one H(14,15) atom. The C(22)-H(14,15) bond length is 0.95 Å. In the twelfth C site, C(24) is bonded in a bent 120 degrees geometry to one C(21), one O(1), and one O(2) atom. The C(24)-O(1) bond length is 1.28 Å. The C(24)-O(2) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ni(1), one C(8), and one C(9) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(14,15) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Ni(1) and one C(24) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Ni(1) and one C(24) atom. In the third O site, O(4) is bonded in a bent 150 degrees geometry to one Ni(1) and one C(17) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(17) atom. Linkers: 4 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,4 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [C]1O[Ni]2(O1)O[C]O[Ni]1(O[C]O1)O[C]O2. The MOF has largest included sphere 3.81 A, density 1.36 g/cm3, surface area 4607.36 m2/g, accessible volume 0.25 cm3/g