(ZnC8H4O4)2(CH)8C9H8O4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules; two 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and two ZnC8H4O4 clusters. In one of the ZnC8H4O4 clusters, Zn(1) is bonded in a distorted square co-planar geometry to one O(1), one O(2), one O(5), and one O(6) atom. The Zn(1)-O(1) bond length is 2.01 Å. The Zn(1)-O(2) bond length is 2.04 Å. The Zn(1)-O(5) bond length is 2.05 Å. The Zn(1)-O(6) bond length is 2.02 Å. There are eight inequivalent C sites. In the first C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(10) atom. The C(13)-C(14) bond length is 1.37 Å. The C(13)-H(10) bond length is 0.95 Å. In the second C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-C(17) bond length is 1.50 Å. In the third C site, C(15) is bonded in a single-bond geometry to one C(14) and one H(11) atom. The C(15)-H(11) bond length is 0.95 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-C(2) bond length is 1.39 Å. The C(7)-H(4) bond length is 0.95 Å. In the fifth C site, C(17) is bonded in a bent 120 degrees geometry to one C(14), one O(5), and one O(6) atom. The C(17)-O(5) bond length is 1.21 Å. The C(17)-O(6) bond length is 1.26 Å. In the sixth C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.24 Å. The C(1)-O(2) bond length is 1.24 Å. In the seventh C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. In the eighth C site, C(3) is bonded in a single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. In one of the ZnC8H4O4 clusters, Zn(2) is bonded in a 3-coordinate geometry to one O(11), one O(12), one O(8), and one O(9) atom. The Zn(2)-O(11) bond length is 2.36 Å. The Zn(2)-O(12) bond length is 2.01 Å. The Zn(2)-O(8) bond length is 2.01 Å. The Zn(2)-O(9) bond length is 2.01 Å. There are eight inequivalent C sites. In the first C site, C(21) is bonded in a single-bond geometry to one C(22) and one H(16) atom. The C(21)-C(22) bond length is 1.36 Å. The C(21)-H(16) bond length is 0.95 Å. In the second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(25) atom. The C(22)-C(23) bond length is 1.41 Å. The C(22)-C(25) bond length is 1.50 Å. In the third C site, C(23) is bonded in a single-bond geometry to one C(22) and one H(17) atom. The C(23)-H(17) bond length is 0.95 Å. In the fourth C site, C(25) is bonded in a bent 120 degrees geometry to one C(22), one O(8), and one O(9) atom. The C(25)-O(8) bond length is 1.24 Å. The C(25)-O(9) bond length is 1.28 Å. In the fifth C site, C(29) is bonded in a distorted single-bond geometry to one C(30) and one H(22) atom. The C(29)-C(30) bond length is 1.39 Å. The C(29)-H(22) bond length is 0.95 Å. In the sixth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(33) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-C(33) bond length is 1.50 Å. In the seventh C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(23) atom. The C(31)-H(23) bond length is 0.95 Å. In the eighth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(11), and one O(12) atom. The C(33)-O(11) bond length is 1.23 Å. The C(33)-O(12) bond length is 1.28 Å. There are four inequivalent H sites. In the first H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the second H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the third H site, H(22) is bonded in a single-bond geometry to one C(29) atom. In the fourth H site, H(23) is bonded in a single-bond geometry to one C(31) atom. There are four inequivalent O sites. In the first O site, O(11) is bonded in a distorted single-bond geometry to one Zn(2) and one C(33) atom. In the second O site, O(12) is bonded in a water-like geometry to one Zn(2) and one C(33) atom. In the third O site, O(8) is bonded in a water-like geometry to one Zn(2) and one C(25) atom. In the fourth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(25) atom. Linkers: 2 [O]C(=O)c1ccc(OCC(COc2ccc(C([O])=O)cc2)(COc2ccc(C([O])=O)cc2)COc2ccc(C([O])=O)cc2)cc1. Metal clusters: 1 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3 ,1 O=[C]O[Zn]1O[C]O[Zn](O[C]=O)O[C]O1. RCSR code: pts. The MOF has largest included sphere 6.17 A, density 1.08 g/cm3, surface area 4370.79 m2/g, accessible volume 0.42 cm3/g