AgH12(CN)4(CH2)4 is Indium-derived structured and crystallizes in the cubic I2_13 space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules and twelve AgH12(CN)4 clusters. In each AgH12(CN)4 cluster, Ag(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Ag(1)-N(1) bond lengths are 2.38 Å. Both Ag(1)-N(2) bond lengths are 2.35 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one N(1) and one H(3) atom. The C(1)-N(1) bond length is 1.46 Å. The C(1)-H(3) bond length is 0.98 Å. In the second C site, C(3) is bonded in a 2-coordinate geometry to one N(2) and one H(8) atom. The C(3)-N(2) bond length is 1.45 Å. The C(3)-H(8) bond length is 0.94 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Ag(1), one C(1), one H(1), and one H(2) atom. The N(1)-H(1) bond length is 0.95 Å. The N(1)-H(2) bond length is 0.96 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Ag(1), one C(3), one H(6), and one H(7) atom. The N(2)-H(6) bond length is 0.94 Å. The N(2)-H(7) bond length is 0.97 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(3) atom. Linkers: 16 N[C@H]1C[C@@H](N)C[C@@H](N)C1. Metal clusters: 12 [Ag]. RCSR code: ctn. The MOF has largest included sphere 4.84 A, density 1.18 g/cm3, surface area 4513.16 m2/g, accessible volume 0.40 cm3/g