CdH8(C2N)4(C7H4F2)4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen C7H4F2 clusters and four CdH8(C2N)4 clusters. In each C7H4F2 cluster, there are seven inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(3)-C(5) bond length is 1.39 Å. The C(3)-H(3) bond length is 0.95 Å. In the second C site, C(5) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(6) atom. The C(5)-C(4) bond length is 1.39 Å. The C(5)-C(6) bond length is 1.52 Å. In the third C site, C(6) is bonded in a water-like geometry to one C(5), one C(7), one H(5), and one H(6) atom. The C(6)-C(7) bond length is 1.51 Å. The C(6)-H(5) bond length is 0.99 Å. The C(6)-H(6) bond length is 0.99 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-H(4) bond length is 0.95 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-C(9) bond length is 1.39 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one F(1) atom. The C(8)-F(1) bond length is 1.35 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(7) and one F(2) atom. The C(9)-F(2) bond length is 1.35 Å. There are four inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(8) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(9) atom. In each CdH8(C2N)4 cluster, Cd(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Cd(1)-N(1) bond lengths are 2.35 Å. Both Cd(1)-N(2) bond lengths are 2.38 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-H(2) bond length is 0.95 Å. In the third C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(10)-N(2) bond length is 1.33 Å. The C(10)-H(7) bond length is 0.95 Å. In the fourth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(8) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(11) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. Linkers: 4 Fc1c(F)c(Cc2ccncc2)c(F)c(F)c1Cc1c[c]ncc1 ,4 Fc1c(F)c(Cc2ccncc2)c(F)c(F)c1Cc1ccncc1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 5.04 A, density 1.04 g/cm3, surface area 4602.53 m2/g, accessible volume 0.47 cm3/g