Ag(C2N)6 crystallizes in the cubic P2_13 space group. Ag(1) is bonded in a distorted octahedral geometry to three equivalent N(1) and three equivalent N(2) atoms. All Ag(1)-N(1) bond lengths are 2.45 Å. All Ag(1)-N(2) bond lengths are 2.46 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to two equivalent C(2) and one N(2) atom. There is one shorter (1.38 Å) and one longer (1.39 Å) C(1)-C(2) bond length. The C(1)-N(2) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to two equivalent C(1) and one N(1) atom. The C(2)-N(1) bond length is 1.39 Å. In the third C site, C(3) is bonded in a single-bond geometry to one N(1) atom. The C(3)-N(1) bond length is 1.39 Å. In the fourth C site, C(4) is bonded in a single-bond geometry to one N(2) atom. The C(4)-N(2) bond length is 1.39 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(4) atom. Linkers: 3 [c]1[c]nc2c(n1)c1n[c][c]nc1c1n[c][c]nc21. Metal clusters: 4 [Ag]. The MOF has largest included sphere 6.07 A, density 1.15 g/cm3, surface area 3474.37 m2/g, accessible volume 0.57 cm3/g