La(CO2)3(CH)3(CH2)6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, twenty-four 02329_fluka molecules, and two La(CO2)3 clusters. In each La(CO2)3 cluster, La(1) is bonded in a 7-coordinate geometry to one O(1), one O(3), one O(4), one O(5), one O(6), and two equivalent O(2) atoms. The La(1)-O(1) bond length is 2.50 Å. The La(1)-O(3) bond length is 2.61 Å. The La(1)-O(4) bond length is 2.58 Å. The La(1)-O(5) bond length is 2.53 Å. The La(1)-O(6) bond length is 2.63 Å. There is one shorter (2.48 Å) and one longer (2.67 Å) La(1)-O(2) bond length. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(5) atom. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(5) bond length is 1.25 Å. In the second C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(11)-O(3) bond length is 1.25 Å. The C(11)-O(4) bond length is 1.24 Å. In the third C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(6) atom. The C(12)-O(2) bond length is 1.26 Å. The C(12)-O(6) bond length is 1.24 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one La(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent La(1) and one C(12) atom. In the third O site, O(3) is bonded in a single-bond geometry to one La(1) and one C(11) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one La(1) and one C(11) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one La(1) and one C(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one La(1) and one C(12) atom. Linkers: 6 [O]C(=O)[C@H]1CC[C@H](C([O])=O)CC1. Metal clusters: 2 [C]1O[La]234(O1)O[C]O[La]1(O[C]O1)(O[C]O2)(O[C]O3)O[C]O4. RCSR code: pcu. The MOF has largest included sphere 5.40 A, density 1.21 g/cm3, surface area 3685.34 m2/g, accessible volume 0.50 cm3/g