Na4Dy2Zn2C95H46(N3O7)3(CH)2 crystallizes in the monoclinic C2/m space group. The structure consists of eight 02329_fluka molecules inside a Na4Dy2Zn2C95H46(N3O7)3 framework. In the Na4Dy2Zn2C95H46(N3O7)3 framework, there are three inequivalent Na sites. In the first Na site, Na(1) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(2), one O(4), and one O(5) atom. The Na(1)-O(10) bond length is 2.27 Å. The Na(1)-O(11) bond length is 2.80 Å. The Na(1)-O(2) bond length is 2.26 Å. The Na(1)-O(4) bond length is 2.42 Å. The Na(1)-O(5) bond length is 2.45 Å. In the second Na site, Na(2) is bonded in a square co-planar geometry to two equivalent O(7) and two equivalent O(9) atoms. Both Na(2)-O(7) bond lengths are 2.29 Å. Both Na(2)-O(9) bond lengths are 2.24 Å. In the third Na site, Na(3) is bonded in a distorted trigonal pyramidal geometry to two equivalent O(4) and two equivalent O(5) atoms. Both Na(3)-O(4) bond lengths are 2.33 Å. Both Na(3)-O(5) bond lengths are 2.33 Å. There are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 10-coordinate geometry to one O(11), one O(12), two equivalent O(1), two equivalent O(2), two equivalent O(5), and two equivalent O(9) atoms. The Dy(1)-O(11) bond length is 2.38 Å. The Dy(1)-O(12) bond length is 2.44 Å. Both Dy(1)-O(1) bond lengths are 2.47 Å. Both Dy(1)-O(2) bond lengths are 2.51 Å. Both Dy(1)-O(5) bond lengths are 2.53 Å. Both Dy(1)-O(9) bond lengths are 2.43 Å. In the second Dy site, Dy(2) is bonded in a 10-coordinate geometry to one O(11), one O(8), two equivalent O(10), two equivalent O(4), two equivalent O(6), and two equivalent O(7) atoms. The Dy(2)-O(11) bond length is 2.36 Å. The Dy(2)-O(8) bond length is 2.42 Å. Both Dy(2)-O(10) bond lengths are 2.50 Å. Both Dy(2)-O(4) bond lengths are 2.58 Å. Both Dy(2)-O(6) bond lengths are 2.42 Å. Both Dy(2)-O(7) bond lengths are 2.48 Å. Zn(1) is bonded in a square pyramidal geometry to one N(1), one N(2), one N(4), one N(5), and one O(3) atom. The Zn(1)-N(1) bond length is 2.07 Å. The Zn(1)-N(2) bond length is 2.06 Å. The Zn(1)-N(4) bond length is 2.08 Å. The Zn(1)-N(5) bond length is 2.08 Å. The Zn(1)-O(3) bond length is 2.09 Å. There are forty-eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(48) and one H(6) atom. The C(1)-C(48) bond length is 1.45 Å. The C(1)-H(6) bond length is 0.95 Å. In the second C site, C(2) is bonded in a bent 120 degrees geometry to one C(40), one O(10), and one O(6) atom. The C(2)-C(40) bond length is 1.50 Å. The C(2)-O(10) bond length is 1.26 Å. The C(2)-O(6) bond length is 1.27 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(22), one C(46), and one H(24) atom. The C(3)-C(22) bond length is 1.39 Å. The C(3)-C(46) bond length is 1.39 Å. The C(3)-H(24) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(28) and one H(20) atom. The C(4)-C(28) bond length is 1.44 Å. The C(4)-H(20) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(39) atom. The C(5)-C(15) bond length is 1.38 Å. The C(5)-C(16) bond length is 1.37 Å. The C(5)-C(39) bond length is 1.50 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(17), one C(25), and one N(2) atom. The C(6)-C(17) bond length is 1.45 Å. The C(6)-C(25) bond length is 1.41 Å. The C(6)-N(2) bond length is 1.37 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(22), one C(28), and one C(30) atom. The C(7)-C(22) bond length is 1.49 Å. The C(7)-C(28) bond length is 1.41 Å. The C(7)-C(30) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(38) and one H(15) atom. The C(8)-C(38) bond length is 1.44 Å. The C(8)-H(15) bond length is 0.95 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(23) and one H(11,23) atom. The C(9)-C(23) bond length is 1.38 Å. The C(9)-H(11,23) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(44), one C(45), and one C(48) atom. The C(10)-C(44) bond length is 1.49 Å. The C(10)-C(45) bond length is 1.40 Å. The C(10)-C(48) bond length is 1.41 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(27), one C(33), and one C(43) atom. The C(11)-C(27) bond length is 1.39 Å. The C(11)-C(33) bond length is 1.49 Å. The C(11)-C(43) bond length is 1.36 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(16), one C(29), and one H(18) atom. The C(12)-C(16) bond length is 1.39 Å. The C(12)-C(29) bond length is 1.38 Å. The C(12)-H(18) bond length is 0.95 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(29) and one H(5) atom. The C(13)-C(29) bond length is 1.36 Å. The C(13)-H(5) bond length is 0.95 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(22) and one H(10) atom. The C(14)-C(22) bond length is 1.39 Å. The C(14)-H(10) bond length is 0.95 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(5) and one H(7) atom. The C(15)-H(7) bond length is 0.95 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(12), one C(5), and one H(16) atom. The C(16)-H(16) bond length is 0.95 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(6) and one H(2) atom. The C(17)-H(2) bond length is 0.95 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(44) and one H(11,23) atom. The C(18)-C(44) bond length is 1.40 Å. The C(18)-H(11,23) bond length is 0.95 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(36) and one H(22) atom. The C(19)-C(36) bond length is 1.45 Å. The C(19)-H(22) bond length is 0.95 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(40) and one H(19) atom. The C(20)-C(40) bond length is 1.37 Å. The C(20)-H(19) bond length is 0.95 Å. In the twenty-first C site, C(21) is bonded in a bent 120 degrees geometry to one C(29), one O(4), and one O(7) atom. The C(21)-C(29) bond length is 1.49 Å. The C(21)-O(4) bond length is 1.27 Å. The C(21)-O(7) bond length is 1.26 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(14), one C(3), and one C(7) atom. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(25), one C(34), and one C(9) atom. The C(23)-C(25) bond length is 1.50 Å. The C(23)-C(34) bond length is 1.37 Å. In the twenty-fourth C site, C(24) is bonded in a bent 120 degrees geometry to one C(31), one O(2), and one O(9) atom. The C(24)-C(31) bond length is 1.49 Å. The C(24)-O(2) bond length is 1.26 Å. The C(24)-O(9) bond length is 1.27 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(23), one C(36), and one C(6) atom. The C(25)-C(36) bond length is 1.40 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(45) and one H(3) atom. The C(26)-C(45) bond length is 1.45 Å. The C(26)-H(3) bond length is 0.95 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(11) and one H(17) atom. The C(27)-H(17) bond length is 0.95 Å. In the twenty-eighth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(4), one C(7), and one N(1) atom. The C(28)-N(1) bond length is 1.36 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(21) atom. In the thirtieth C site, C(30) is bonded in a distorted single-bond geometry to one C(7) and one N(5) atom. The C(30)-N(5) bond length is 1.37 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one C(24), one C(37), and one C(42) atom. The C(31)-C(37) bond length is 1.39 Å. The C(31)-C(42) bond length is 1.39 Å. In the thirty-second C site, C(32) is bonded in a distorted single-bond geometry to one C(44) and one H(21) atom. The C(32)-C(44) bond length is 1.39 Å. The C(32)-H(21) bond length is 0.95 Å. In the thirty-third C site, C(33) is bonded in a bent 120 degrees geometry to one C(11), one O(1), and one O(5) atom. The C(33)-O(1) bond length is 1.25 Å. The C(33)-O(5) bond length is 1.27 Å. In the thirty-fourth C site, C(34) is bonded in a distorted single-bond geometry to one C(23) and one H(4) atom. The C(34)-H(4) bond length is 0.95 Å. In the thirty-fifth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(19), one C(25), and one N(1) atom. The C(36)-N(1) bond length is 1.37 Å. In the thirty-sixth C site, C(37) is bonded in a distorted single-bond geometry to one C(31) and one H(8) atom. The C(37)-H(8) bond length is 0.95 Å. In the thirty-seventh C site, C(38) is bonded in a distorted trigonal planar geometry to one C(39), one C(8), and one N(2) atom. The C(38)-C(39) bond length is 1.40 Å. The C(38)-N(2) bond length is 1.38 Å. In the thirty-eighth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(41), and one C(5) atom. The C(39)-C(41) bond length is 1.41 Å. In the thirty-ninth C site, C(40) is bonded in a trigonal planar geometry to one C(2), one C(20), and one C(46) atom. The C(40)-C(46) bond length is 1.39 Å. In the fortieth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(39), one C(47), and one N(4) atom. The C(41)-C(47) bond length is 1.44 Å. The C(41)-N(4) bond length is 1.37 Å. In the forty-first C site, C(42) is bonded in a distorted single-bond geometry to one C(31) and one H(1,13) atom. The C(42)-H(1,13) bond length is 0.95 Å. In the forty-second C site, C(43) is bonded in a distorted single-bond geometry to one C(11) and one H(1,13) atom. The C(43)-H(1,13) bond length is 0.95 Å. In the forty-third C site, C(44) is bonded in a trigonal planar geometry to one C(10), one C(18), and one C(32) atom. In the forty-fourth C site, C(45) is bonded in a distorted single-bond geometry to one C(10), one C(26), and one N(5) atom. The C(45)-N(5) bond length is 1.37 Å. In the forty-fifth C site, C(46) is bonded in a distorted trigonal planar geometry to one C(3), one C(40), and one H(9) atom. The C(46)-H(9) bond length is 0.95 Å. In the forty-sixth C site, C(47) is bonded in a distorted single-bond geometry to one C(41) and one H(14) atom. The C(47)-H(14) bond length is 0.95 Å. In the forty-seventh C site, C(48) is bonded in a distorted trigonal planar geometry to one C(1), one C(10), and one N(4) atom. The C(48)-N(4) bond length is 1.37 Å. In the forty-eighth C site, C(49) is bonded in a bent 150 degrees geometry to two equivalent O(3) atoms. Both C(49)-O(3) bond lengths are 1.16 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(28), and one C(36) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(38), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one O(11), one O(12), and one O(8) atom. The N(3)-O(11) bond length is 1.33 Å. The N(3)-O(12) bond length is 1.25 Å. The N(3)-O(8) bond length is 1.28 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(41), and one C(48) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(1), one C(30), and one C(45) atom. There are twenty-one inequivalent H sites. In the first H site, H(1,13) is bonded in a single-bond geometry to one C(42) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(17) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(26) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(34) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(1) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(37) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(46) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(11,23) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(47) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(8) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(12) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(4) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(32) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(19) atom. In the twenty-first H site, H(24) is bonded in a single-bond geometry to one C(3) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Dy(1) and one C(33) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Na(1), one Dy(1), and one C(24) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(49) atom. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Na(1), one Na(3), one Dy(2), and one C(21) atom. In the fifth O site, O(5) is bonded in a 4-coordinate geometry to one Na(1), one Na(3), one Dy(1), and one C(33) atom. In the sixth O site, O(6) is bonded in a distorted L-shaped geometry to one Dy(2) and one C(2) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Na(2), one Dy(2), and one C(21) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Dy(2) and one N(3) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Na(2), one Dy(1), and one C(24) atom. In the tenth O site, O(10) is bonded in a distorted T-shaped geometry to one Na(1), one Dy(2), and one C(2) atom. In the eleventh O site, O(11) is bonded in a 5-coordinate geometry to two equivalent Na(1), one Dy(1), one Dy(2), and one N(3) atom. In the twelfth O site, O(12) is bonded in an L-shaped geometry to one Dy(1) and one N(3) atom. Linkers: 4 [O]C(=O)c1ccc(/C2=C3\C=C/C(=C(\c4ccc(C([O])=O)cc4)C4=N/C(=C(/c5ccc(C([O])=O)cc5)C5=CC=C([N]5)/C(c5ccc(C([O])=O)cc5)=C5/C=CC2=N5)C=C4)[N]3)cc1. Metal clusters: 8 [Na] ,4 [Dy] ,2 [Zn]O[C]O[Zn]. The MOF has largest included sphere 8.23 A, density 1.19 g/cm3, surface area 3517.75 m2/g, accessible volume 0.41 cm3/g