MnC16H14(NO)4(CH2)4(CH)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, sixteen 02329_fluka molecules, and four MnC16H14(NO)4 clusters. In each MnC16H14(NO)4 cluster, Mn(1) is bonded in a rectangular see-saw-like geometry to one N(2), one N(3), one O(2), and one O(3) atom. The Mn(1)-N(2) bond length is 2.26 Å. The Mn(1)-N(3) bond length is 2.25 Å. The Mn(1)-O(2) bond length is 2.19 Å. The Mn(1)-O(3) bond length is 2.20 Å. There are sixteen inequivalent C sites. In the first C site, C(20) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(9) atom. The C(20)-C(2) bond length is 1.36 Å. The C(20)-C(5) bond length is 1.37 Å. The C(20)-C(9) bond length is 1.49 Å. In the second C site, C(22) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(5) atom. The C(22)-N(1) bond length is 1.34 Å. The C(22)-N(3) bond length is 1.31 Å. The C(22)-H(5) bond length is 0.93 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one C(20) and one H(20) atom. The C(2)-H(20) bond length is 0.93 Å. In the fourth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(3)-O(3) bond length is 1.28 Å. The C(3)-O(4) bond length is 1.24 Å. In the fifth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(4)-O(1) bond length is 1.25 Å. The C(4)-O(2) bond length is 1.27 Å. In the sixth C site, C(5) is bonded in a distorted single-bond geometry to one C(20) and one H(2) atom. The C(5)-H(2) bond length is 0.93 Å. In the seventh C site, C(6) is bonded in a distorted trigonal planar geometry to one C(16), one N(3), and one H(23) atom. The C(6)-C(16) bond length is 1.35 Å. The C(6)-N(3) bond length is 1.37 Å. The C(6)-H(23) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(13) and one H(16) atom. The C(8)-C(13) bond length is 1.39 Å. The C(8)-H(16) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a 3-coordinate geometry to one C(20), one N(1), one H(17), and one H(7) atom. The C(9)-N(1) bond length is 1.46 Å. The C(9)-H(17) bond length is 0.97 Å. The C(9)-H(7) bond length is 0.97 Å. In the tenth C site, C(10) is bonded in a 3-coordinate geometry to one C(13); one N(4); and two equivalent H(1,8) atoms. The C(10)-C(13) bond length is 1.52 Å. The C(10)-N(4) bond length is 1.46 Å. Both C(10)-H(1,8) bond lengths are 0.97 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(10), one C(19), and one C(8) atom. The C(13)-C(19) bond length is 1.37 Å. In the twelfth C site, C(14) is bonded in a 3-coordinate geometry to one C(18), one N(4), and one H(4) atom. The C(14)-C(18) bond length is 1.36 Å. The C(14)-N(4) bond length is 1.37 Å. The C(14)-H(4) bond length is 0.93 Å. In the thirteenth C site, C(16) is bonded in a 3-coordinate geometry to one C(6), one N(1), and one H(22) atom. The C(16)-N(1) bond length is 1.37 Å. The C(16)-H(22) bond length is 0.93 Å. In the fourteenth C site, C(17) is bonded in a trigonal planar geometry to one N(2), one N(4), and one H(9) atom. The C(17)-N(2) bond length is 1.32 Å. The C(17)-N(4) bond length is 1.34 Å. The C(17)-H(9) bond length is 0.93 Å. In the fifteenth C site, C(18) is bonded in a 3-coordinate geometry to one C(14), one N(2), and one H(3) atom. The C(18)-N(2) bond length is 1.38 Å. The C(18)-H(3) bond length is 0.93 Å. In the sixteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(13) and one H(15) atom. The C(19)-H(15) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(16), one C(22), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(1), one C(17), and one C(18) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(22), and one C(6) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(17) atom. There are thirteen inequivalent H sites. In the first H site, H(1,8) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(18) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(22) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(2) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one C(6) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(4) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(3) atom. Linkers: 9 c1cn(Cc2ccc(Cn3ccnc3)cc2)cn1 ,2 [N]=C[N]Cc1ccc(Cn2ccnc2)cc1 ,4 [O]C(=O)[C@H]1CC[C@@H](C([O])=O)CC1. Metal clusters: 4 O=[C]O[Mn]O[C]=O. The MOF has largest included sphere 4.28 A, density 1.22 g/cm3, surface area 5468.78 m2/g, accessible volume 0.32 cm3/g