ZnC20NH14O4(CH)2C2O is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight dimethyl ether molecules, and four ZnC20NH14O4 clusters. In each ZnC20NH14O4 cluster, Zn(1) is bonded in a 5-coordinate geometry to one N(1), one O(1), one O(2), one O(4), and one O(5) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 2.42 Å. The Zn(1)-O(2) bond length is 1.98 Å. The Zn(1)-O(4) bond length is 1.94 Å. The Zn(1)-O(5) bond length is 1.99 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(2) is bonded in a single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-H(2) bond length is 0.95 Å. In the third C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.39 Å. The C(8)-C(7) bond length is 1.46 Å. The C(8)-C(9) bond length is 1.39 Å. In the fourth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 0.95 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(10)-H(8) bond length is 0.95 Å. In the sixth C site, C(11) is bonded in a bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(11)-C(12) bond length is 1.48 Å. The C(11)-O(1) bond length is 1.25 Å. The C(11)-O(2) bond length is 1.27 Å. In the seventh C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(4), and one O(5) atom. The C(18)-C(19) bond length is 1.48 Å. The C(18)-O(4) bond length is 1.25 Å. The C(18)-O(5) bond length is 1.26 Å. In the eighth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.36 Å. The C(19)-C(24) bond length is 1.39 Å. In the ninth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one H(13) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(13) bond length is 0.95 Å. In the tenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(14) atom. The C(21)-H(14) bond length is 0.95 Å. In the eleventh C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(15) atom. The C(23)-C(24) bond length is 1.37 Å. The C(23)-H(15) bond length is 0.95 Å. In the twelfth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(19), one C(23), and one H(16) atom. The C(24)-H(16) bond length is 0.95 Å. In the thirteenth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-C(6) bond length is 1.46 Å. In the fourteenth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.95 Å. In the fifteenth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.95 Å. In the sixteenth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one H(5) atom. The C(6)-C(7) bond length is 1.33 Å. The C(6)-H(5) bond length is 0.95 Å. In the seventeenth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(6) atom. The C(7)-H(6) bond length is 0.95 Å. In the eighteenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-C(17) bond length is 1.38 Å. In the nineteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(9) atom. The C(13)-H(9) bond length is 0.95 Å. In the twentieth C site, C(17) is bonded in a distorted single-bond geometry to one C(12) and one H(12) atom. The C(17)-H(12) bond length is 0.95 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Zn(1) and one C(11) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(11) atom. In the third O site, O(4) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(18) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(18) atom. Linkers: 5 C(=C/c1ccc(/C=C/c2ccncc2)cc1)\c1ccncc1 ,7 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,1 [O]C(=O)c1ccc(Oc2ccc([C]=O)cc2)cc1. Metal clusters: 4 O=[C]O[Zn]1O[C]O[Zn](O[C]=O)O[C]O1. RCSR code: sql. The MOF has largest included sphere 7.40 A, density 1.14 g/cm3, surface area 4743.11 m2/g, accessible volume 0.41 cm3/g