Zn4C36O13Br24 is alpha Po structured and crystallizes in the cubic Fm-3m space group. The structure is zero-dimensional and consists of eight Zn4C36O13Br24 clusters. Zn(1) is bonded to one O(1) and three equivalent O(2) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.94 Å. All Zn(1)-O(2) bond lengths are 1.94 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one Br(1) atom. The C(1)-C(1) bond length is 0.93 Å. The C(1)-C(3) bond length is 1.32 Å. The C(1)-Br(1) bond length is 2.08 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3) and two equivalent O(2) atoms. The C(2)-C(3) bond length is 1.43 Å. Both C(2)-O(2) bond lengths are 1.25 Å. In the third C site, C(3) is bonded in a 5-coordinate geometry to one C(2) and four equivalent C(1) atoms. There are two inequivalent O sites. In the first O site, O(1) is bonded in a tetrahedral geometry to four equivalent Zn(1) atoms. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. Br(1) is bonded in a single-bond geometry to one C(1) atom. Linkers: 3 BrBr.BrBr.Br[C]1[C](Br)c2[c]c3c([c]c21)[C](Br)[C]3Br.[O][C]=O.[O][C]=O ,4 BrBr.BrBr.Br[C@@]12[C][C][C@]1(Br)[C][C@@]1(Br)[C][C][C@@]1(Br)[C]2.[O][C]=O.[O][C]=O ,1 [Br].[Br].[Br].[Br].[C][C]1[C](Br)[C](Br)[C]1[C][C@@]1(Br)[C][C][C]1Br.[O][C]=O.[O][C]=O ,1 Br[C@@]12[C][C][C@]1(Br)[C][C@@]1(Br)[C][C][C@@]1(Br)[C]2.[Br].[Br].[Br].[Br].[O][C]=O.[O][C]=O ,2 BrBr.BrBr.Br[C]1[C][C]2[C][C]3[C][C](Br)[C@@]3(Br)[C][C@]12Br.[O][C]=O.[O][C]=O ,1 BrBr.BrBr.[C][C]1[C][C@@](Br)([C][C@@]2(Br)[C][C][C]2Br)[C]1Br.[O][C]=O.[O][C]=O ,1 Br[C]1[C][C]2[C][C]3[C][C](Br)[C@@]3(Br)[C][C@]12Br.[Br].[Br].[Br].[Br].[O][C]=O.[O][C]=O ,2 Br[C]1[C][C]2[C][C]3[C][C](Br)[C@]3(Br)[C][C@@]12Br.[Br].[Br].[Br].[Br].[O][C]=O.[O][C]=O ,1 BrBr.BrBr.Br[C]1[C][C][C]1Br.[C][C]1[C][C@@]([C])(Br)[C]1Br.[O][C]=O.[O][C]=O ,1 BrBr.BrBr.[C][C@@]1(Br)[C][C][C]1Br.[C][C]1[C][C](Br)[C]1Br.[O][C]=O.[O][C]=O ,1 BrBr.BrBr.Br[C]1[C](Br)[C]2[C][C@@]3(Br)[C][C][C@@]3(Br)[C][C]12.[O][C]=O.[O][C]=O ,1 BrBr.BrBr.Br[C]1[C][C]2[C][C]3[C][C](Br)[C@@]3(Br)[C][C@@]12Br.[O][C]=O.[O][C]=O ,2 BrBr.BrBr.Br[C]1[C][C][C]1Br.[C][C]1[C][C](Br)[C@]1([C])Br.[O][C]=O.[O][C]=O ,2 Br[C]1[C][C][C]1Br.[Br].[Br].[Br].[Br].[C][C]1[C][C](Br)[C@@]1([C])Br.[O][C]=O.[O][C]=O ,1 Br[C]1[C][C]2[C][C]3[C][C](Br)[C@@]3(Br)[C][C@@]12Br.[Br].[Br].[Br].[Br].[O][C]=O.[O][C]=O. Metal clusters: 8 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: pcu. The MOF has largest included sphere 12.81 A, density 2.19 g/cm3, surface area 1587.98 m2/g, accessible volume 0.27 cm3/g