Ag3C16H20(NO)4(CH)12 is Indium-derived structured and crystallizes in the orthorhombic Pnnn space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules and four Ag3C16H20(NO)4 clusters. In each Ag3C16H20(NO)4 cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one Ag(2), one N(1), and one N(2) atom. The Ag(1)-Ag(2) bond length is 0.86 Å. The Ag(1)-N(1) bond length is 2.11 Å. The Ag(1)-N(2) bond length is 2.15 Å. In the second Ag site, Ag(2) is bonded in a distorted linear geometry to two equivalent Ag(1) atoms. There are eight inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(7) and one O(2) atom. The C(2)-C(7) bond length is 1.45 Å. The C(2)-O(2) bond length is 1.37 Å. In the second C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(1,2) and one O(2) atom. Both C(1)-H(1,2) bond lengths are 0.97 Å. The C(1)-O(2) bond length is 1.45 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-H(6) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(7)-N(1) bond length is 1.46 Å. In the fifth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one N(2) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.41 Å. The C(8)-N(2) bond length is 1.40 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 0.93 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one O(1) atom. The C(13)-O(1) bond length is 1.38 Å. In the eighth C site, C(14) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(11,12) and one O(1) atom. Both C(14)-H(11,12) bond lengths are 0.97 Å. The C(14)-O(1) bond length is 1.42 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted water-like geometry to one Ag(1), one C(7), one H(13), and one H(14) atom. The N(1)-H(13) bond length is 0.90 Å. The N(1)-H(14) bond length is 0.90 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one Ag(1), one C(8), one H(15), and one H(16) atom. The N(2)-H(15) bond length is 0.90 Å. The N(2)-H(16) bond length is 0.90 Å. There are eight inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(11,12) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one N(2) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one N(1) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(13) and one C(14) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. Linkers: 10 Nc1ccccc1OCCOc1ccccc1N. Metal clusters: 12 [Ag]. The MOF has largest included sphere 5.29 A, density 1.73 g/cm3, surface area 3632.07 m2/g, accessible volume 0.17 cm3/g