(Zn4C24H12O13)2(CH)24(C9H8O4)3 is Indium-derived structured and crystallizes in the cubic P23 space group. The structure is zero-dimensional and consists of ninety-six 02329_fluka molecules; twelve 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and eight Zn4C24H12O13 clusters. In each Zn4C24H12O13 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(11), one O(12), one O(13), and one O(2) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(11) bond length is 1.91 Å. The Zn(1)-O(12) bond length is 1.95 Å. The Zn(1)-O(13) bond length is 1.95 Å. The Zn(1)-O(2) bond length is 1.94 Å. In the second Zn site, Zn(3) is bonded to one O(13) and three equivalent O(3) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(13) bond length is 1.89 Å. All Zn(3)-O(3) bond lengths are 1.95 Å. There are eight inequivalent C sites. In the first C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.36 Å. The C(5)-H(4) bond length is 0.93 Å. In the second C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(6)-C(7) bond length is 1.37 Å. The C(6)-C(9) bond length is 1.48 Å. In the third C site, C(7) is bonded in a single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 0.93 Å. In the fourth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(2), and one O(3) atom. The C(9)-O(2) bond length is 1.23 Å. The C(9)-O(3) bond length is 1.22 Å. In the fifth C site, C(29) is bonded in a single-bond geometry to one C(30) and one H(22) atom. The C(29)-C(30) bond length is 1.37 Å. The C(29)-H(22) bond length is 0.93 Å. In the sixth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(33) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-C(33) bond length is 1.52 Å. In the seventh C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(23) atom. The C(31)-H(23) bond length is 0.93 Å. In the eighth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(11), and one O(12) atom. The C(33)-O(11) bond length is 1.34 Å. The C(33)-O(12) bond length is 1.49 Å. There are four inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(22) is bonded in a single-bond geometry to one C(29) atom. In the fourth H site, H(23) is bonded in a single-bond geometry to one C(31) atom. There are five inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(9) atom. In the third O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(33) atom. In the fourth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(33) atom. In the fifth O site, O(13) is bonded in a tetrahedral geometry to one Zn(3) and three equivalent Zn(1) atoms. Linkers: 12 [O]C(=O)c1ccc(OCC(COc2ccc(C([O])=O)cc2)(COc2ccc(C([O])=O)cc2)COc2ccc(C([O])=O)cc2)cc1. Metal clusters: 8 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. The MOF has largest included sphere 7.59 A, density 1.15 g/cm3, surface area 4280.25 m2/g, accessible volume 0.42 cm3/g