(CuH4(C7O2)2)3CH crystallizes in the tetragonal I4/mmm space group. The structure consists of sixteen 02329_fluka molecules inside a CuH4(C7O2)2 framework. In each CuH4(C7O2)2 framework, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(5) atoms. Both Cu(1)-O(1) bond lengths are 1.94 Å. Both Cu(1)-O(5) bond lengths are 1.95 Å. In the second Cu site, Cu(2) is bonded in a distorted square co-planar geometry to two equivalent O(2) and two equivalent O(6) atoms. Both Cu(2)-O(2) bond lengths are 1.96 Å. Both Cu(2)-O(6) bond lengths are 1.97 Å. In the third Cu site, Cu(3) is bonded in a square co-planar geometry to four equivalent O(4) atoms. All Cu(3)-O(4) bond lengths are 1.97 Å. In the fourth Cu site, Cu(4) is bonded in a square co-planar geometry to four equivalent O(3) atoms. All Cu(4)-O(3) bond lengths are 1.94 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.24 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-C(8) bond length is 1.49 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(2) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-H(2) bond length is 0.95 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(6)-C(7) bond length is 1.41 Å. The C(6)-C(9) bond length is 1.42 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(3) atom. The C(7)-H(3) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.27 Å. In the ninth C site, C(9) is bonded in a linear geometry to one C(10) and one C(6) atom. The C(9)-C(10) bond length is 1.20 Å. In the tenth C site, C(10) is bonded in a linear geometry to one C(11) and one C(9) atom. The C(10)-C(11) bond length is 1.41 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(19) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(19) bond length is 1.40 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(4) atom. The C(12)-H(4) bond length is 0.95 Å. In the thirteenth C site, C(13) is bonded in a bent 120 degrees geometry to one C(14), one O(5), and one O(6) atom. The C(13)-C(14) bond length is 1.49 Å. The C(13)-O(5) bond length is 1.26 Å. The C(13)-O(6) bond length is 1.26 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(21) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-C(21) bond length is 1.40 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(22), and one H(5) atom. The C(15)-C(22) bond length is 1.40 Å. The C(15)-H(5) bond length is 0.95 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(16), one C(17), and one C(23) atom. The C(16)-C(16) bond length is 0.93 Å. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(23) bond length is 1.31 Å. In the seventeenth C site, C(17) is bonded in a 4-coordinate geometry to one C(16), one C(17), one C(18), and one C(24) atom. The C(17)-C(17) bond length is 1.36 Å. The C(17)-C(18) bond length is 1.54 Å. The C(17)-C(24) bond length is 1.37 Å. In the eighteenth C site, C(18) is bonded in a bent 120 degrees geometry to one C(17) and one C(25) atom. The C(18)-C(25) bond length is 1.35 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to two equivalent C(11) and one H(6) atom. The C(19)-H(6) bond length is 0.95 Å. In the twentieth C site, C(21) is bonded in a distorted single-bond geometry to two equivalent C(14) and one H(8) atom. The C(21)-H(8) bond length is 0.95 Å. In the twenty-first C site, C(22) is bonded in a trigonal planar geometry to one C(23) and two equivalent C(15) atoms. The C(22)-C(23) bond length is 1.39 Å. In the twenty-second C site, C(23) is bonded in a 3-coordinate geometry to one C(22) and two equivalent C(16) atoms. In the twenty-third C site, C(24) is bonded in a distorted trigonal non-coplanar geometry to one C(24) and two equivalent C(17) atoms. The C(24)-C(24) bond length is 0.77 Å. In the twenty-fourth C site, C(25) is bonded in a bent 120 degrees geometry to two equivalent C(18) atoms. There are seven inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(19) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(21) atom. In the third H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(4) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(5) is bonded in a single-bond geometry to one C(15) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(8) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(13) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Cu(2) and one C(13) atom. Linkers: 2 [C][C]1[C][C@@]23[C][C]=[C][C@@]45[C][C]([C])[C@@]46[C]=[C][C][C@@]12[C]6[C]35.[O]C(=O)c1c[c]cc(C([O])=O)c1.[O]C(=O)c1c[c]cc(C([O])=O)c1 ,1 [C][C]1[C][C@@]23[C]=[C][C][C@@]45[C][C]([C])[C@@]46[C]=[C][C][C@@]12[C]6[C]53.[O]C(=O)c1c[c]cc(C([O])=O)c1.[O]C(=O)c1c[c]cc(C([O])=O)c1 ,16 [O]C(=O)c1cc(C#Cc2cccc(C#Cc3cc(C([O])=O)cc(C([O])=O)c3)c2)cc(C([O])=O)c1 ,1 [C][C]1[C][C@@]23[C][C]=[C][C@@]45[C]([C])[C][C@@]46[C][C]=[C][C@@]12[C]6[C]35.[O]C(=O)c1c[c]cc(C([O])=O)c1.[O]C(=O)c1c[c]cc(C([O])=O)c1 ,1 [C][C]1[C][C@@]23[C][C]=[C][C@@]45[C]([C])[C][C@@]46[C]=[C][C][C@@]12[C]6[C]35.[O]C(=O)c1c[c]cc(C([O])=O)c1.[O]C(=O)c1c[c]cc(C([O])=O)c1 ,2 [C][C]1[C][C@]23[C][C]=[C][C@]45[C][C]([C])[C@]46[C]=[C][C][C@]12[C]6[C]35.[O]C(=O)c1c[c]cc(C([O])=O)c1.[O]C(=O)c1c[c]cc(C([O])=O)c1 ,1 [C][C]1[C][C@@]23[C]=[C][C][C@@]45[C]([C])[C][C@@]46[C]=[C][C][C@@]12[C]6[C]53.[O]C(=O)c1c[c]cc(C([O])=O)c1.[O]C(=O)c1c[c]cc(C([O])=O)c1. Metal clusters: 24 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 13.02 A, density 0.93 g/cm3, surface area 3934.00 m2/g, accessible volume 0.69 cm3/g