(CH)4CuC32N8H24O4Cl crystallizes in the tetragonal P4bm space group. The structure consists of eight 02329_fluka molecules inside a CuC32N8H24O4Cl framework. In the CuC32N8H24O4Cl framework, Cu(1) is bonded to four equivalent N(1) and two equivalent Cl(1) atoms to form corner-sharing CuN4Cl2 octahedra. The corner-sharing octahedra are not tilted. All Cu(1)-N(1) bond lengths are 2.06 Å. There is one shorter (2.57 Å) and one longer (2.60 Å) Cu(1)-Cl(1) bond length. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(3) bond length is 0.93 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(2) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(2) bond length is 1.41 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(2), and one O(1) atom. The C(6)-C(7) bond length is 1.50 Å. The C(6)-N(2) bond length is 1.36 Å. The C(6)-O(1) bond length is 1.23 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-C(9) bond length is 1.39 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(10), one C(7), and one H(6) atom. The C(8)-C(10) bond length is 1.39 Å. The C(8)-H(6) bond length is 0.93 Å. In the eighth C site, C(9) is bonded in a single-bond geometry to two equivalent C(7) and one H(7) atom. The C(9)-H(7) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to two equivalent C(8) and one H(8) atom. The C(10)-H(8) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(5) atom. The N(2)-H(5) bond length is 0.86 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. O(1) is bonded in a single-bond geometry to one C(6) atom. Cl(1) is bonded in a linear geometry to two equivalent Cu(1) atoms. Linkers: 4 O=C(Nc1cccnc1)c1cccc(C(=O)Nc2cccnc2)c1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 8.44 A, density 1.01 g/cm3, surface area 4695.49 m2/g, accessible volume 0.49 cm3/g