(C11H7)2Cd2C25N4H16(O2F3)2C2O is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight (3e)-2,3,6-trimethyl-5-methylidenehepta-1,3,6-triene molecules; four dimethyl ether molecules; and four Cd2C25N4H16(O2F3)2 clusters. In each Cd2C25N4H16(O2F3)2 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(3), one O(1), and one O(2) atom. The Cd(1)-N(1) bond length is 2.38 Å. The Cd(1)-N(3) bond length is 2.34 Å. The Cd(1)-O(1) bond length is 2.27 Å. The Cd(1)-O(2) bond length is 2.53 Å. In the second Cd site, Cd(2) is bonded in a T-shaped geometry to one N(2), one N(4), and one O(3) atom. The Cd(2)-N(2) bond length is 2.40 Å. The Cd(2)-N(4) bond length is 2.43 Å. The Cd(2)-O(3) bond length is 2.32 Å. There are twenty-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,4) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1,4) bond length is 0.93 Å. In the second C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(26)-N(3) bond length is 1.35 Å. The C(26)-H(17) bond length is 0.93 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,4) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(1,4) bond length is 0.93 Å. In the fourth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(14)-N(2) bond length is 1.33 Å. The C(14)-H(9) bond length is 0.93 Å. In the fifth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(15)-N(2) bond length is 1.34 Å. The C(15)-H(10) bond length is 0.93 Å. In the sixth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(20) atom. The C(30)-N(4) bond length is 1.33 Å. The C(30)-H(20) bond length is 0.93 Å. In the seventh C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(16) atom. The C(25)-N(3) bond length is 1.34 Å. The C(25)-H(16) bond length is 0.93 Å. In the eighth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(19) atom. The C(29)-N(4) bond length is 1.34 Å. The C(29)-H(19) bond length is 0.93 Å. In the ninth C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(38) atom. The C(33)-C(32) bond length is 1.52 Å. The C(33)-C(34) bond length is 1.39 Å. The C(33)-C(38) bond length is 1.39 Å. In the tenth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(33), one C(35), and one H(22) atom. The C(34)-C(35) bond length is 1.40 Å. The C(34)-H(22) bond length is 0.93 Å. In the eleventh C site, C(35) is bonded in a distorted single-bond geometry to one C(34), one C(36), and one H(23) atom. The C(35)-C(36) bond length is 1.39 Å. The C(35)-H(23) bond length is 0.93 Å. In the twelfth C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(39) atom. The C(36)-C(37) bond length is 1.40 Å. The C(36)-C(39) bond length is 1.56 Å. In the thirteenth C site, C(38) is bonded in a distorted single-bond geometry to one C(33) and one H(25) atom. The C(38)-H(25) bond length is 0.93 Å. In the fourteenth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(33), one O(1), and one O(2) atom. The C(32)-O(1) bond length is 1.25 Å. The C(32)-O(2) bond length is 1.24 Å. In the fifteenth C site, C(37) is bonded in a distorted single-bond geometry to one C(36) and one H(24) atom. The C(37)-H(24) bond length is 0.93 Å. In the sixteenth C site, C(39) is bonded in a tetrahedral geometry to one C(36), one C(40), one C(41), and one C(42) atom. The C(39)-C(40) bond length is 1.55 Å. The C(39)-C(41) bond length is 1.56 Å. The C(39)-C(42) bond length is 1.54 Å. In the seventeenth C site, C(40) is bonded in a trigonal non-coplanar geometry to one C(39), one F(1), one F(2), and one F(3) atom. The C(40)-F(1) bond length is 1.34 Å. The C(40)-F(2) bond length is 1.35 Å. The C(40)-F(3) bond length is 1.34 Å. In the eighteenth C site, C(41) is bonded in a trigonal non-coplanar geometry to one C(39), one F(4), one F(5), and one F(6) atom. The C(41)-F(4) bond length is 1.33 Å. The C(41)-F(5) bond length is 1.35 Å. The C(41)-F(6) bond length is 1.33 Å. In the nineteenth C site, C(42) is bonded in a trigonal planar geometry to one C(39), one C(43), and one C(47) atom. The C(42)-C(43) bond length is 1.40 Å. The C(42)-C(47) bond length is 1.40 Å. In the twentieth C site, C(43) is bonded in a distorted single-bond geometry to one C(42), one C(44), and one H(26) atom. The C(43)-C(44) bond length is 1.39 Å. The C(43)-H(26) bond length is 0.93 Å. In the twenty-first C site, C(47) is bonded in a distorted single-bond geometry to one C(42) and one H(29) atom. The C(47)-H(29) bond length is 0.93 Å. In the twenty-second C site, C(44) is bonded in a distorted trigonal planar geometry to one C(43), one C(45), and one H(27) atom. The C(44)-C(45) bond length is 1.38 Å. The C(44)-H(27) bond length is 0.93 Å. In the twenty-third C site, C(45) is bonded in a trigonal planar geometry to one C(44), one C(46), and one C(48) atom. The C(45)-C(46) bond length is 1.38 Å. The C(45)-C(48) bond length is 1.51 Å. In the twenty-fourth C site, C(46) is bonded in a distorted single-bond geometry to one C(45) and one H(28) atom. The C(46)-H(28) bond length is 0.93 Å. In the twenty-fifth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(45), one O(3), and one O(4) atom. The C(48)-O(3) bond length is 1.26 Å. The C(48)-O(4) bond length is 1.24 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(2), one C(14), and one C(15) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(25), and one C(26) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(2), one C(29), and one C(30) atom. There are fifteen inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(30) atom. In the eighth H site, H(22) is bonded in a single-bond geometry to one C(34) atom. In the ninth H site, H(23) is bonded in a single-bond geometry to one C(35) atom. In the tenth H site, H(24) is bonded in a single-bond geometry to one C(37) atom. In the eleventh H site, H(25) is bonded in a single-bond geometry to one C(38) atom. In the twelfth H site, H(26) is bonded in a single-bond geometry to one C(43) atom. In the thirteenth H site, H(27) is bonded in a single-bond geometry to one C(44) atom. In the fourteenth H site, H(28) is bonded in a single-bond geometry to one C(46) atom. In the fifteenth H site, H(29) is bonded in a single-bond geometry to one C(47) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1) and one C(32) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(32) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one C(48) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(48) atom. There are six inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(40) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(40) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(40) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(41) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(41) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one C(41) atom. Linkers: 4 c1cc(-c2cc(Oc3cc(-c4ccncc4)cc(-c4ccncc4)c3)cc(-c3ccncc3)c2)ccn1 ,4 [O]C(=O)c1ccc(C(c2ccc(C([O])=O)cc2)(C(F)(F)F)C(F)(F)F)cc1. Metal clusters: 4 [C]1O[Cd]O1 ,4 O=[C]O[Cd]. The MOF has largest included sphere 6.51 A, density 1.16 g/cm3, surface area 4244.84 m2/g, accessible volume 0.38 cm3/g