AgH28(C6N)4AgH8(C2N)4 is Indium-like structured and crystallizes in the orthorhombic Pnn2 space group. The structure is zero-dimensional and consists of two AgH28(C6N)4 clusters and two AgH8(C2N)4 clusters. In each AgH28(C6N)4 cluster, Ag(1) is bonded in a 4-coordinate geometry to two equivalent N(2) and two equivalent N(3) atoms. Both Ag(1)-N(2) bond lengths are 2.32 Å. Both Ag(1)-N(3) bond lengths are 2.34 Å. There are twelve inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-H(2) bond length is 0.95 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(6) bond length is 1.51 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.95 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.50 Å. The C(6)-N(2) bond length is 1.27 Å. In the fifth C site, C(7) is bonded in a trigonal non-coplanar geometry to one C(6) and three equivalent H(5,6,7) atoms. All C(7)-H(5,6,7) bond lengths are 0.98 Å. In the sixth C site, C(8) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(8,9) atoms. The C(8)-N(2) bond length is 1.46 Å. Both C(8)-H(8,9) bond lengths are 0.99 Å. In the seventh C site, C(9) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(10,11) atoms. The C(9)-N(3) bond length is 1.47 Å. Both C(9)-H(10,11) bond lengths are 0.99 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(12), and one N(3) atom. The C(10)-C(11) bond length is 1.50 Å. The C(10)-C(12) bond length is 1.51 Å. The C(10)-N(3) bond length is 1.27 Å. In the ninth C site, C(11) is bonded in a trigonal non-coplanar geometry to one C(10); one H(14); and two equivalent H(12,13) atoms. The C(11)-H(14) bond length is 0.98 Å. Both C(11)-H(12,13) bond lengths are 0.98 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(16) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-C(16) bond length is 1.38 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(15) atom. The C(13)-H(15) bond length is 0.95 Å. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(12) and one H(18) atom. The C(16)-H(18) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(6), and one C(8) atom. In the second N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(10), and one C(9) atom. There are nine inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5,6,7) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(8,9) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(10,11) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(12,13) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In each AgH8(C2N)4 cluster, Ag(2) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(4) atoms. Both Ag(2)-N(1) bond lengths are 2.39 Å. Both Ag(2)-N(4) bond lengths are 2.38 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(16) atom. The C(14)-N(4) bond length is 1.34 Å. The C(14)-H(16) bond length is 0.95 Å. In the fourth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(17) atom. The C(15)-N(4) bond length is 1.33 Å. The C(15)-H(17) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(1), and one C(5) atom. In the second N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(14), and one C(15) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. Linkers: 4 C/C(=N\CC/N=C(\C)c1ccncc1)c1ccncc1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 4.49 A, density 1.25 g/cm3, surface area 4646.67 m2/g, accessible volume 0.38 cm3/g