CoC12H8(NO2)2(C11H13SO)2 is Indium-derived structured and crystallizes in the tetragonal I4_1/acd space group. The structure is zero-dimensional and consists of eight 15,35,55,75-tetra-tert-butyl-12,32,52,72-tetramethoxy-2,4,6,8-tetrathia-1,3,5,7(1,3)-tetrabenzenacyclooctaphane molecules and sixteen CoC12H8(NO2)2 clusters. In each CoC12H8(NO2)2 cluster, Co(1) is bonded in a square co-planar geometry to one N(1), one N(2), and two equivalent O(2) atoms. The Co(1)-N(1) bond length is 2.13 Å. The Co(1)-N(2) bond length is 2.13 Å. Both Co(1)-O(2) bond lengths are 2.05 Å. There are seven inequivalent C sites. In the first C site, C(17) is bonded in a trigonal planar geometry to one C(18) and two equivalent C(14) atoms. The C(17)-C(18) bond length is 1.48 Å. Both C(17)-C(14) bond lengths are 1.39 Å. In the second C site, C(18) is bonded in a trigonal planar geometry to one C(17) and two equivalent C(15) atoms. Both C(18)-C(15) bond lengths are 1.37 Å. In the third C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(14) atom. The C(13)-N(1) bond length is 1.33 Å. The C(13)-H(14) bond length is 0.95 Å. In the fourth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(8)-O(2) bond length is 1.27 Å. The C(8)-O(3) bond length is 1.22 Å. In the fifth C site, C(14) is bonded in a distorted single-bond geometry to one C(17) and one H(15) atom. The C(14)-H(15) bond length is 0.95 Å. In the sixth C site, C(15) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(16) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-H(16) bond length is 0.95 Å. In the seventh C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one N(2), and one H(17) atom. The C(16)-N(2) bond length is 1.33 Å. The C(16)-H(17) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Co(1) and two equivalent C(16) atoms. In the second N site, N(1) is bonded in a trigonal planar geometry to one Co(1) and two equivalent C(13) atoms. There are four inequivalent H sites. In the first H site, H(17) is bonded in a single-bond geometry to one C(16) atom. In the second H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(15) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(8) atom. In the second O site, O(3) is bonded in a single-bond geometry to one C(8) atom. Linkers: 4 CC(C)(C)c1cc2c(OCC([O])=O)c(c1)Sc1cc(C(C)(C)C)cc(c1OCC([O])=O)Sc1cc(C(C)(C)C)cc(c1OCC([O])=O)Sc1cc(C(C)(C)C)cc(c1OCC([O])=O)S2 ,8 c1cc(-c2ccncc2)ccn1. Metal clusters: 8 O=[C]O[Co]O[C]=O. The MOF has largest included sphere 9.91 A, density 0.79 g/cm3, surface area 5251.63 m2/g, accessible volume 0.74 cm3/g