Mn2FeC42N10H34(OCl)4(CH)2 crystallizes in the trigonal P3_221 space group. The structure consists of six 02329_fluka molecules inside a Mn2FeC42N10H34(OCl)4 framework. In the Mn2FeC42N10H34(OCl)4 framework, Mn(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one O(1), and one O(2) atom. The Mn(1)-N(1) bond length is 2.02 Å. The Mn(1)-N(2) bond length is 2.03 Å. The Mn(1)-N(3) bond length is 2.39 Å. The Mn(1)-N(4) bond length is 2.33 Å. The Mn(1)-O(1) bond length is 1.90 Å. The Mn(1)-O(2) bond length is 1.88 Å. Fe(1) is bonded in an octahedral geometry to two equivalent C(20), two equivalent C(21), and two equivalent C(22) atoms. Both Fe(1)-C(20) bond lengths are 1.98 Å. Both Fe(1)-C(21) bond lengths are 1.94 Å. Both Fe(1)-C(22) bond lengths are 1.96 Å. There are twenty-one inequivalent C sites. In the first C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. The C(12)-C(11) bond length is 1.44 Å. The C(12)-C(13) bond length is 1.41 Å. The C(12)-C(17) bond length is 1.41 Å. In the second C site, C(13) is bonded in a single-bond geometry to one C(12), one C(14), and one H(10) atom. The C(13)-C(14) bond length is 1.37 Å. The C(13)-H(10) bond length is 0.95 Å. In the third C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one Cl(2) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-Cl(2) bond length is 1.75 Å. In the fourth C site, C(15) is bonded in a single-bond geometry to one C(14) and one H(11) atom. The C(15)-H(11) bond length is 0.95 Å. In the fifth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(12) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-H(12) bond length is 0.95 Å. In the sixth C site, C(17) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one O(2) atom. The C(17)-O(2) bond length is 1.32 Å. In the seventh C site, C(18) is bonded in a trigonal non-coplanar geometry to one C(9) and three equivalent H(13,14,15,16,18) atoms. The C(18)-C(9) bond length is 1.52 Å. All C(18)-H(13,14,15,16,18) bond lengths are 0.98 Å. In the eighth C site, C(19) is bonded in a trigonal non-coplanar geometry to one C(9); one H(17); and two equivalent H(13,14,15,16,18) atoms. The C(19)-C(9) bond length is 1.54 Å. The C(19)-H(17) bond length is 0.98 Å. Both C(19)-H(13,14,15,16,18) bond lengths are 0.98 Å. In the ninth C site, C(20) is bonded in a linear geometry to one Fe(1) and one N(4) atom. The C(20)-N(4) bond length is 1.15 Å. In the tenth C site, C(21) is bonded in a linear geometry to one Fe(1) and one N(5) atom. The C(21)-N(5) bond length is 1.15 Å. In the eleventh C site, C(22) is bonded in a linear geometry to one Fe(1) and one N(3) atom. The C(22)-N(3) bond length is 1.16 Å. In the twelfth C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one O(1) atom. The C(1)-C(6) bond length is 1.41 Å. The C(1)-O(1) bond length is 1.33 Å. In the thirteenth C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(2) bond length is 0.95 Å. In the fourteenth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one Cl(1) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-Cl(1) bond length is 1.75 Å. In the fifteenth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one H(3) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-H(3) bond length is 0.95 Å. In the sixteenth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.44 Å. In the seventeenth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one H(4) atom. The C(7)-N(1) bond length is 1.29 Å. The C(7)-H(4) bond length is 0.95 Å. In the eighteenth C site, C(8) is bonded in a 3-coordinate geometry to one C(9); one N(1); and two equivalent H(5,6) atoms. The C(8)-C(9) bond length is 1.53 Å. The C(8)-N(1) bond length is 1.47 Å. Both C(8)-H(5,6) bond lengths are 0.99 Å. In the nineteenth C site, C(9) is bonded in a tetrahedral geometry to one C(10), one C(18), one C(19), and one C(8) atom. The C(9)-C(10) bond length is 1.54 Å. In the twentieth C site, C(10) is bonded in a 3-coordinate geometry to one C(9), one N(2), one H(7), and one H(8) atom. The C(10)-N(2) bond length is 1.48 Å. The C(10)-H(7) bond length is 0.99 Å. The C(10)-H(8) bond length is 0.99 Å. In the twenty-first C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(2), and one H(9) atom. The C(11)-N(2) bond length is 1.29 Å. The C(11)-H(9) bond length is 0.95 Å. There are five inequivalent N sites. In the first N site, N(5) is bonded in a single-bond geometry to one C(21) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Mn(1), one C(7), and one C(8) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one Mn(1), one C(10), and one C(11) atom. In the fourth N site, N(3) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(22) atom. In the fifth N site, N(4) is bonded in a linear geometry to one Mn(1) and one C(20) atom. There are twelve inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(13,14,15,16,18) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(17) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(4) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(14) atom. Linkers: 2 CC(C)(C/N=C/c1cc(Cl)ccc1[O])C/N=C/c1cc(Cl)ccc1[O]. Metal clusters: 6 [Mn] ,3 [Fe]. The MOF has largest included sphere 5.35 A, density 1.20 g/cm3, surface area 4721.75 m2/g, accessible volume 0.37 cm3/g