NiAgH30(C4N)12(CH)12 crystallizes in the cubic P2_13 space group. The structure consists of ninety-six 02329_fluka molecules and two NiAgH30(C4N)12 frameworks. In one of the NiAgH30(C4N)12 frameworks, Ni(1) is bonded in an octahedral geometry to three equivalent N(1) and three equivalent N(3) atoms. All Ni(1)-N(1) bond lengths are 2.10 Å. All Ni(1)-N(3) bond lengths are 2.12 Å. Ag(1) is bonded in a trigonal planar geometry to three equivalent N(4) atoms. All Ag(1)-N(4) bond lengths are 2.21 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.35 Å. The C(1)-N(1) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.95 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.39 Å. The C(5)-H(4) bond length is 0.95 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(7), and one N(3) atom. The C(6)-C(7) bond length is 1.42 Å. The C(6)-N(3) bond length is 1.42 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.42 Å. The C(7)-H(5) bond length is 0.95 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(2), and one H(6) atom. The C(8)-N(2) bond length is 1.42 Å. The C(8)-H(6) bond length is 0.95 Å. In the seventh C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one N(2), one H(7), and one H(8) atom. The C(9)-C(10) bond length is 1.57 Å. The C(9)-N(2) bond length is 1.39 Å. The C(9)-H(7) bond length is 0.99 Å. The C(9)-H(8) bond length is 0.99 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(15) bond length is 1.39 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(9) atom. The C(11)-H(9) bond length is 0.95 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(10) bond length is 0.95 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(20) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-C(20) bond length is 1.40 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(16) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-C(16) bond length is 1.39 Å. In the thirteenth C site, C(15) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(19) atom. The C(15)-C(19) bond length is 1.39 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(14) and one H(11,25) atom. The C(16)-H(11,25) bond length is 0.95 Å. In the fifteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(15) and one H(14) atom. The C(19)-H(14) bond length is 0.95 Å. In the sixteenth C site, C(20) is bonded in a distorted linear geometry to one C(13) and one N(4) atom. The C(20)-N(4) bond length is 1.25 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(8), one C(9), and one N(3) atom. The N(2)-N(3) bond length is 1.42 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Ni(1), one C(6), and one N(2) atom. In the fourth N site, N(4) is bonded in a bent 150 degrees geometry to one Ag(1) and one C(20) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11,25) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In one of the NiAgH30(C4N)12 frameworks, Ni(2) is bonded in an octahedral geometry to three equivalent N(5) and three equivalent N(7) atoms. All Ni(2)-N(5) bond lengths are 2.11 Å. All Ni(2)-N(7) bond lengths are 2.11 Å. Ag(2) is bonded in a trigonal planar geometry to three equivalent N(8) atoms. All Ag(2)-N(8) bond lengths are 2.26 Å. There are sixteen inequivalent C sites. In the first C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one C(26), and one N(5) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-C(26) bond length is 1.35 Å. The C(21)-N(5) bond length is 1.39 Å. In the second C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(15) atom. The C(22)-H(15) bond length is 0.95 Å. In the third C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(18) atom. The C(25)-N(5) bond length is 1.39 Å. The C(25)-H(18) bond length is 0.95 Å. In the fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(21), one C(27), and one N(7) atom. The C(26)-C(27) bond length is 1.42 Å. The C(26)-N(7) bond length is 1.42 Å. In the fifth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(19) atom. The C(27)-H(19) bond length is 0.95 Å. In the sixth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(20) atom. The C(28)-N(6) bond length is 1.42 Å. The C(28)-H(20) bond length is 0.95 Å. In the seventh C site, C(29) is bonded in a distorted trigonal non-coplanar geometry to one C(30), one N(6), one H(21), and one H(22) atom. The C(29)-C(30) bond length is 1.51 Å. The C(29)-N(6) bond length is 1.37 Å. The C(29)-H(21) bond length is 0.99 Å. The C(29)-H(22) bond length is 0.99 Å. In the eighth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(35) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-C(35) bond length is 1.39 Å. In the ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(23) atom. The C(31)-H(23) bond length is 0.95 Å. In the tenth C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(24) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-H(24) bond length is 0.95 Å. In the eleventh C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(40) atom. The C(33)-C(34) bond length is 1.39 Å. The C(33)-C(40) bond length is 1.42 Å. In the twelfth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(36) atom. The C(34)-C(35) bond length is 1.39 Å. The C(34)-C(36) bond length is 1.39 Å. In the thirteenth C site, C(35) is bonded in a trigonal planar geometry to one C(30), one C(34), and one C(39) atom. The C(35)-C(39) bond length is 1.39 Å. In the fourteenth C site, C(36) is bonded in a distorted single-bond geometry to one C(34) and one H(11,25) atom. The C(36)-H(11,25) bond length is 0.95 Å. In the fifteenth C site, C(39) is bonded in a distorted single-bond geometry to one C(35) and one H(28) atom. The C(39)-H(28) bond length is 0.95 Å. In the sixteenth C site, C(40) is bonded in a distorted linear geometry to one C(33) and one N(8) atom. The C(40)-N(8) bond length is 1.17 Å. There are four inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one Ni(2), one C(21), and one C(25) atom. In the second N site, N(6) is bonded in a distorted trigonal planar geometry to one C(28), one C(29), and one N(7) atom. The N(6)-N(7) bond length is 1.42 Å. In the third N site, N(7) is bonded in a 3-coordinate geometry to one Ni(2), one C(26), and one N(6) atom. In the fourth N site, N(8) is bonded in a distorted bent 150 degrees geometry to one Ag(2) and one C(40) atom. There are ten inequivalent H sites. In the first H site, H(11,25) is bonded in a single-bond geometry to one C(16) atom. In the second H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the third H site, H(18) is bonded in a single-bond geometry to one C(25) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one C(28) atom. In the sixth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one C(29) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the ninth H site, H(24) is bonded in a single-bond geometry to one C(32) atom. In the tenth H site, H(28) is bonded in a single-bond geometry to one C(39) atom. Linkers: 24 N#Cc1ccc(Cn2ccc(-c3ccccn3)n2)c2ccccc12. Metal clusters: 8 [Ni] ,8 [Ag]. The MOF has largest included sphere 5.97 A, density 1.20 g/cm3, surface area 4857.21 m2/g, accessible volume 0.32 cm3/g