ZnH15(C2N)10ZnH12(C2N)8(CH)9 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of thirty-six 02329_fluka molecules, four ZnH12(C2N)8 clusters, and four ZnH15(C2N)10 clusters. In each ZnH12(C2N)8 cluster, Zn(2) is bonded in a tetrahedral geometry to one N(15), one N(17), one N(3), and one N(5) atom. The Zn(2)-N(15) bond length is 1.98 Å. The Zn(2)-N(17) bond length is 1.96 Å. The Zn(2)-N(3) bond length is 1.98 Å. The Zn(2)-N(5) bond length is 2.00 Å. There are sixteen inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one N(4) atom. The C(3)-N(4) bond length is 1.43 Å. In the second C site, C(5) is bonded in a distorted single-bond geometry to one N(6) atom. The C(5)-N(6) bond length is 1.42 Å. In the third C site, C(10) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(7) atom. The C(10)-N(3) bond length is 1.32 Å. The C(10)-N(4) bond length is 1.35 Å. The C(10)-H(7) bond length is 0.95 Å. In the fourth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(3), and one H(8) atom. The C(11)-C(12) bond length is 1.35 Å. The C(11)-N(3) bond length is 1.40 Å. The C(11)-H(8) bond length is 0.95 Å. In the fifth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(4), and one H(9) atom. The C(12)-N(4) bond length is 1.39 Å. The C(12)-H(9) bond length is 0.95 Å. In the sixth C site, C(13) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(10) atom. The C(13)-N(5) bond length is 1.32 Å. The C(13)-N(6) bond length is 1.36 Å. The C(13)-H(10) bond length is 0.95 Å. In the seventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(5), and one H(11) atom. The C(14)-C(15) bond length is 1.35 Å. The C(14)-N(5) bond length is 1.39 Å. The C(14)-H(11) bond length is 0.95 Å. In the eighth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(6), and one H(12) atom. The C(15)-N(6) bond length is 1.40 Å. The C(15)-H(12) bond length is 0.95 Å. In the ninth C site, C(33) is bonded in a distorted single-bond geometry to one N(16) atom. The C(33)-N(16) bond length is 1.43 Å. In the tenth C site, C(35) is bonded in a distorted single-bond geometry to one N(18) atom. The C(35)-N(18) bond length is 1.43 Å. In the eleventh C site, C(40) is bonded in a trigonal planar geometry to one N(15), one N(16), and one H(31) atom. The C(40)-N(15) bond length is 1.33 Å. The C(40)-N(16) bond length is 1.35 Å. The C(40)-H(31) bond length is 0.95 Å. In the twelfth C site, C(41) is bonded in a 3-coordinate geometry to one C(42), one N(15), and one H(32) atom. The C(41)-C(42) bond length is 1.35 Å. The C(41)-N(15) bond length is 1.40 Å. The C(41)-H(32) bond length is 0.95 Å. In the thirteenth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(41), one N(16), and one H(33) atom. The C(42)-N(16) bond length is 1.38 Å. The C(42)-H(33) bond length is 0.95 Å. In the fourteenth C site, C(43) is bonded in a trigonal planar geometry to one N(17), one N(18), and one H(34) atom. The C(43)-N(17) bond length is 1.33 Å. The C(43)-N(18) bond length is 1.34 Å. The C(43)-H(34) bond length is 0.95 Å. In the fifteenth C site, C(44) is bonded in a distorted bent 120 degrees geometry to one C(45), one N(17), and one H(35) atom. The C(44)-C(45) bond length is 1.36 Å. The C(44)-N(17) bond length is 1.38 Å. The C(44)-H(35) bond length is 0.95 Å. In the sixteenth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(44), one N(18), and one H(36) atom. The C(45)-N(18) bond length is 1.37 Å. The C(45)-H(36) bond length is 0.95 Å. There are eight inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(10), and one C(11) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(3) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Zn(2), one C(13), and one C(14) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(5) atom. In the fifth N site, N(15) is bonded in a trigonal planar geometry to one Zn(2), one C(40), and one C(41) atom. In the sixth N site, N(16) is bonded in a trigonal planar geometry to one C(33), one C(40), and one C(42) atom. In the seventh N site, N(17) is bonded in a trigonal planar geometry to one Zn(2), one C(43), and one C(44) atom. In the eighth N site, N(18) is bonded in a trigonal planar geometry to one C(35), one C(43), and one C(45) atom. There are twelve inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(31) is bonded in a single-bond geometry to one C(40) atom. In the eighth H site, H(33) is bonded in a single-bond geometry to one C(42) atom. In the ninth H site, H(32) is bonded in a single-bond geometry to one C(41) atom. In the tenth H site, H(34) is bonded in a single-bond geometry to one C(43) atom. In the eleventh H site, H(35) is bonded in a single-bond geometry to one C(44) atom. In the twelfth H site, H(36) is bonded in a single-bond geometry to one C(45) atom. In each ZnH15(C2N)10 cluster, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(11), one N(13), one N(7), and one N(9) atom. The Zn(1)-N(1) bond length is 2.19 Å. The Zn(1)-N(11) bond length is 2.24 Å. The Zn(1)-N(13) bond length is 2.04 Å. The Zn(1)-N(7) bond length is 2.02 Å. The Zn(1)-N(9) bond length is 2.03 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one N(2) atom. The C(1)-N(2) bond length is 1.43 Å. In the second C site, C(7) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(4) atom. The C(7)-N(1) bond length is 1.33 Å. The C(7)-N(2) bond length is 1.36 Å. The C(7)-H(4) bond length is 0.95 Å. In the third C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(1), and one H(5) atom. The C(8)-C(9) bond length is 1.35 Å. The C(8)-N(1) bond length is 1.38 Å. The C(8)-H(5) bond length is 0.95 Å. In the fourth C site, C(9) is bonded in a 3-coordinate geometry to one C(8), one N(2), and one H(6) atom. The C(9)-N(2) bond length is 1.38 Å. The C(9)-H(6) bond length is 0.95 Å. In the fifth C site, C(16) is bonded in a distorted single-bond geometry to one N(8) atom. The C(16)-N(8) bond length is 1.42 Å. In the sixth C site, C(18) is bonded in a distorted single-bond geometry to one N(10) atom. The C(18)-N(10) bond length is 1.43 Å. In the seventh C site, C(20) is bonded in a single-bond geometry to one N(12) atom. The C(20)-N(12) bond length is 1.44 Å. In the eighth C site, C(22) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(16) atom. The C(22)-N(7) bond length is 1.33 Å. The C(22)-N(8) bond length is 1.36 Å. The C(22)-H(16) bond length is 0.95 Å. In the ninth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(24), one N(7), and one H(17) atom. The C(23)-C(24) bond length is 1.35 Å. The C(23)-N(7) bond length is 1.39 Å. The C(23)-H(17) bond length is 0.95 Å. In the tenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one N(8), and one H(18) atom. The C(24)-N(8) bond length is 1.37 Å. The C(24)-H(18) bond length is 0.95 Å. In the eleventh C site, C(25) is bonded in a trigonal planar geometry to one N(10), one N(9), and one H(19) atom. The C(25)-N(10) bond length is 1.36 Å. The C(25)-N(9) bond length is 1.31 Å. The C(25)-H(19) bond length is 0.95 Å. In the twelfth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(27), one N(9), and one H(20) atom. The C(26)-C(27) bond length is 1.34 Å. The C(26)-N(9) bond length is 1.39 Å. The C(26)-H(20) bond length is 0.95 Å. In the thirteenth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(26), one N(10), and one H(21) atom. The C(27)-N(10) bond length is 1.38 Å. The C(27)-H(21) bond length is 0.95 Å. In the fourteenth C site, C(28) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(22) atom. The C(28)-N(11) bond length is 1.33 Å. The C(28)-N(12) bond length is 1.35 Å. The C(28)-H(22) bond length is 0.95 Å. In the fifteenth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(30), one N(11), and one H(23) atom. The C(29)-C(30) bond length is 1.36 Å. The C(29)-N(11) bond length is 1.36 Å. The C(29)-H(23) bond length is 0.95 Å. In the sixteenth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one N(12), and one H(24) atom. The C(30)-N(12) bond length is 1.38 Å. The C(30)-H(24) bond length is 0.95 Å. In the seventeenth C site, C(31) is bonded in a distorted single-bond geometry to one N(14) atom. The C(31)-N(14) bond length is 1.43 Å. In the eighteenth C site, C(37) is bonded in a trigonal planar geometry to one N(13), one N(14), and one H(28) atom. The C(37)-N(13) bond length is 1.32 Å. The C(37)-N(14) bond length is 1.36 Å. The C(37)-H(28) bond length is 0.95 Å. In the nineteenth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(39), one N(13), and one H(29) atom. The C(38)-C(39) bond length is 1.34 Å. The C(38)-N(13) bond length is 1.39 Å. The C(38)-H(29) bond length is 0.95 Å. In the twentieth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(38), one N(14), and one H(30) atom. The C(39)-N(14) bond length is 1.39 Å. The C(39)-H(30) bond length is 0.95 Å. There are ten inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(7), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(7), and one C(9) atom. In the third N site, N(7) is bonded in a trigonal planar geometry to one Zn(1), one C(22), and one C(23) atom. In the fourth N site, N(8) is bonded in a trigonal planar geometry to one C(16), one C(22), and one C(24) atom. In the fifth N site, N(9) is bonded in a trigonal planar geometry to one Zn(1), one C(25), and one C(26) atom. In the sixth N site, N(10) is bonded in a trigonal planar geometry to one C(18), one C(25), and one C(27) atom. In the seventh N site, N(11) is bonded in a trigonal planar geometry to one Zn(1), one C(28), and one C(29) atom. In the eighth N site, N(12) is bonded in a trigonal planar geometry to one C(20), one C(28), and one C(30) atom. In the ninth N site, N(13) is bonded in a trigonal planar geometry to one Zn(1), one C(37), and one C(38) atom. In the tenth N site, N(14) is bonded in a trigonal planar geometry to one C(31), one C(37), and one C(39) atom. There are fifteen inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(21) is bonded in a single-bond geometry to one C(27) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(20) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(28) atom. In the eleventh H site, H(23) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(30) atom. In the thirteenth H site, H(28) is bonded in a single-bond geometry to one C(37) atom. In the fourteenth H site, H(29) is bonded in a single-bond geometry to one C(38) atom. In the fifteenth H site, H(30) is bonded in a single-bond geometry to one C(39) atom. Linkers: 6 c1cn(-c2cc(-n3ccnc3)cc(-n3ccnc3)c2)cn1 ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=N[Zn].[CH]=[C]N=[CH].[CH]=[N].[CH]=[N].[CH][N].[CH][N][CH][C][N].[CH][N][CH][C][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]/N=[Zn]\[N].[C]/N=[Zn]\[N].[C]=C[C][N].[C]=C[N].[C]=C[N].[C][CH].[C][CH].[C][CH].[C][C].[C][C]([C])n1[c]n[c]c1.[C][C][N].[C][N].[C][N].[C][N]C=[C].[C][N][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N]/C=C\[N].[N]/C=C\[N].[N][C][CH][N].[N][C][CH][N].[Zn].[Zn].[Zn]. Metal clusters: 6 [Zn]. The MOF has largest included sphere 8.02 A, density 0.70 g/cm3, surface area 4934.42 m2/g, accessible volume 0.96 cm3/g