(C4H3)6Cd3C24H22S2(NO)8 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twenty-four isobutylene molecules and four Cd3C24H22S2(NO)8 clusters. In each Cd3C24H22S2(NO)8 cluster, there are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one N(1), one N(2), one N(5), one N(6), one O(1), and one O(5) atom to form CdN4O2 octahedra that share  a cornercorner with one S(1)O4 tetrahedra and  a cornercorner with one S(2)O4 tetrahedra. The Cd(1)-N(1) bond length is 2.37 Å. The Cd(1)-N(2) bond length is 2.34 Å. The Cd(1)-N(5) bond length is 2.37 Å. The Cd(1)-N(6) bond length is 2.33 Å. The Cd(1)-O(1) bond length is 2.33 Å. The Cd(1)-O(5) bond length is 2.31 Å. In the second Cd site, Cd(2) is bonded in a T-shaped geometry to one N(3), one N(4), and one O(4) atom. The Cd(2)-N(3) bond length is 2.32 Å. The Cd(2)-N(4) bond length is 2.32 Å. The Cd(2)-O(4) bond length is 2.30 Å. In the third Cd site, Cd(3) is bonded in a T-shaped geometry to one N(7), one N(8), and one O(6) atom. The Cd(3)-N(7) bond length is 2.31 Å. The Cd(3)-N(8) bond length is 2.32 Å. The Cd(3)-O(6) bond length is 2.27 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,21) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1,21) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4,24) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(4,24) bond length is 0.93 Å. In the third C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(7)-N(2) bond length is 1.32 Å. The C(7)-H(6) bond length is 0.93 Å. In the fourth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(9) bond length is 0.93 Å. In the fifth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(11) atom. The C(13)-N(3) bond length is 1.33 Å. The C(13)-H(11) bond length is 0.93 Å. In the sixth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(12) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(12) bond length is 0.93 Å. In the seventh C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-C(18) bond length is 1.49 Å. In the eighth C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one H(13) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-H(13) bond length is 0.93 Å. In the ninth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(3), and one H(14) atom. The C(17)-N(3) bond length is 1.33 Å. The C(17)-H(14) bond length is 0.93 Å. In the tenth C site, C(18) is bonded in a single-bond geometry to one C(15) and one H(15) atom. The C(18)-H(15) bond length is 0.98 Å. In the eleventh C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(16) atom. The C(19)-N(4) bond length is 1.34 Å. The C(19)-H(16) bond length is 0.93 Å. In the twelfth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(19) atom. The C(23)-N(4) bond length is 1.34 Å. The C(23)-H(19) bond length is 0.93 Å. In the thirteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(1,21) atom. The C(25)-N(5) bond length is 1.33 Å. The C(25)-H(1,21) bond length is 0.93 Å. In the fourteenth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(4,24) atom. The C(29)-N(5) bond length is 1.33 Å. The C(29)-H(4,24) bond length is 0.93 Å. In the fifteenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(26) atom. The C(31)-N(6) bond length is 1.33 Å. The C(31)-H(26) bond length is 0.93 Å. In the sixteenth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(29) atom. The C(35)-N(6) bond length is 1.33 Å. The C(35)-H(29) bond length is 0.93 Å. In the seventeenth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(38), one N(7), and one H(31) atom. The C(37)-C(38) bond length is 1.38 Å. The C(37)-N(7) bond length is 1.33 Å. The C(37)-H(31) bond length is 0.93 Å. In the eighteenth C site, C(38) is bonded in a distorted single-bond geometry to one C(37), one C(39), and one H(32) atom. The C(38)-C(39) bond length is 1.39 Å. The C(38)-H(32) bond length is 0.93 Å. In the nineteenth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(42) atom. The C(39)-C(40) bond length is 1.37 Å. The C(39)-C(42) bond length is 1.50 Å. In the twentieth C site, C(40) is bonded in a distorted single-bond geometry to one C(39), one C(41), and one H(33) atom. The C(40)-C(41) bond length is 1.38 Å. The C(40)-H(33) bond length is 0.93 Å. In the twenty-first C site, C(41) is bonded in a distorted trigonal planar geometry to one C(40), one N(7), and one H(34) atom. The C(41)-N(7) bond length is 1.33 Å. The C(41)-H(34) bond length is 0.93 Å. In the twenty-second C site, C(42) is bonded in a single-bond geometry to one C(39) and one H(35) atom. The C(42)-H(35) bond length is 0.98 Å. In the twenty-third C site, C(43) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(36) atom. The C(43)-N(8) bond length is 1.33 Å. The C(43)-H(36) bond length is 0.93 Å. In the twenty-fourth C site, C(47) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(39) atom. The C(47)-N(8) bond length is 1.34 Å. The C(47)-H(39) bond length is 0.93 Å. There are eight inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Cd(2), one C(19), and one C(23) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(7) atom. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one Cd(2), one C(13), and one C(17) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cd(1), one C(25), and one C(29) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cd(1), one C(31), and one C(35) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Cd(3), one C(37), and one C(41) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Cd(3), one C(43), and one C(47) atom. There are twenty inequivalent H sites. In the first H site, H(1,21) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4,24) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(26) is bonded in a single-bond geometry to one C(31) atom. In the twelfth H site, H(29) is bonded in a single-bond geometry to one C(35) atom. In the thirteenth H site, H(31) is bonded in a single-bond geometry to one C(37) atom. In the fourteenth H site, H(32) is bonded in a single-bond geometry to one C(38) atom. In the fifteenth H site, H(34) is bonded in a single-bond geometry to one C(41) atom. In the sixteenth H site, H(33) is bonded in a single-bond geometry to one C(40) atom. In the seventeenth H site, H(35) is bonded in a single-bond geometry to one C(42) atom. In the eighteenth H site, H(36) is bonded in a single-bond geometry to one C(43) atom. In the nineteenth H site, H(39) is bonded in a single-bond geometry to one C(47) atom. In the twentieth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 16°. The S(1)-O(1) bond length is 1.46 Å. The S(1)-O(2) bond length is 1.43 Å. The S(1)-O(3) bond length is 1.43 Å. The S(1)-O(4) bond length is 1.49 Å. In the second S site, S(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form SO4 tetrahedra that share  a cornercorner with one Cd(1)N4O2 octahedra. The corner-sharing octahedral tilt angles are 26°. The S(2)-O(5) bond length is 1.46 Å. The S(2)-O(6) bond length is 1.44 Å. The S(2)-O(7) bond length is 1.44 Å. The S(2)-O(8) bond length is 1.43 Å. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Cd(1) and one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Cd(2) and one S(1) atom. In the fourth O site, O(5) is bonded in a bent 150 degrees geometry to one Cd(1) and one S(2) atom. In the fifth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Cd(3) and one S(2) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one S(2) atom. In the seventh O site, O(3) is bonded in a single-bond geometry to one S(1) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one S(2) atom. Linkers: 8 c1cc([C@H]2[C@H](c3ccncc3)[C@@H](c3ccncc3)[C@@H]2c2ccncc2)ccn1. Metal clusters: 4 [O]S([O])(O[Cd])O[Cd]OS([O])([O])O[Cd]. The MOF has largest included sphere 5.99 A, density 1.31 g/cm3, surface area 4218.62 m2/g, accessible volume 0.30 cm3/g