NiC14N3H10O4(C3H2)4(CH2)4(CH)2C9H6N is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; sixteen 02329_fluka molecules; eight 2,3-dimethyl-1,3-butadiene molecules; four schembl1705614 molecules; and four NiC14N3H10O4 clusters. In each NiC14N3H10O4 cluster, Ni(1) is bonded in a square pyramidal geometry to one N(1), one N(2), one N(3), one O(1), and one O(3) atom. The Ni(1)-N(1) bond length is 2.13 Å. The Ni(1)-N(2) bond length is 2.15 Å. The Ni(1)-N(3) bond length is 2.10 Å. The Ni(1)-O(1) bond length is 2.03 Å. The Ni(1)-O(3) bond length is 2.07 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.39 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.38 Å. The C(5)-H(4) bond length is 0.93 Å. In the third C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(12)-N(2) bond length is 1.39 Å. The C(12)-H(9) bond length is 0.93 Å. In the fourth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(16)-N(2) bond length is 1.37 Å. The C(16)-H(12) bond length is 0.93 Å. In the fifth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(23)-N(3) bond length is 1.40 Å. The C(23)-H(17) bond length is 0.93 Å. In the sixth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(18) atom. The C(24)-C(25) bond length is 1.44 Å. The C(24)-H(18) bond length is 0.93 Å. In the seventh C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(28) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(28) bond length is 1.49 Å. In the eighth C site, C(26) is bonded in a distorted single-bond geometry to one C(25), one C(27), and one H(19) atom. The C(26)-C(27) bond length is 1.34 Å. The C(26)-H(19) bond length is 0.93 Å. In the ninth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(26), one N(3), and one H(20) atom. The C(27)-N(3) bond length is 1.37 Å. The C(27)-H(20) bond length is 0.93 Å. In the tenth C site, C(28) is bonded in a trigonal planar geometry to one C(25), one C(29), and one C(33) atom. The C(28)-C(29) bond length is 1.45 Å. The C(28)-C(33) bond length is 1.39 Å. In the eleventh C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(21) atom. The C(29)-H(21) bond length is 0.93 Å. In the twelfth C site, C(33) is bonded in a distorted single-bond geometry to one C(28) and one H(24) atom. The C(33)-H(24) bond length is 0.93 Å. In the thirteenth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(34)-O(1) bond length is 1.24 Å. The C(34)-O(2) bond length is 1.27 Å. In the fourteenth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(38)-O(3) bond length is 1.23 Å. The C(38)-O(4) bond length is 1.26 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ni(1), one C(12), and one C(16) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ni(1), one C(23), and one C(27) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(26) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the tenth H site, H(24) is bonded in a single-bond geometry to one C(33) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(34) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(34) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(38) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(38) atom. Linkers: 4 c1cc(-c2ccc(N(c3ccc(-c4ccncc4)cc3)c3ccc(-c4ccncc4)cc3)cc2)ccn1 ,5 [O]C(=O)[C@H]1CC[C@H](C([O])=O)CC1. Metal clusters: 4 O=[C]O[Ni]O[C]=O. The MOF has largest included sphere 4.77 A, density 1.08 g/cm3, surface area 5120.31 m2/g, accessible volume 0.36 cm3/g