CuC22H18(NO)6(CH)4(CH2)2 is Indium-derived structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, sixteen 02329_fluka molecules, and eight CuC22H18(NO)6 clusters. In each CuC22H18(NO)6 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 2.00 Å. Both Cu(1)-O(1) bond lengths are 1.96 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(3), and one O(3) atom. The C(1)-C(3) bond length is 1.51 Å. The C(1)-N(3) bond length is 1.33 Å. The C(1)-O(3) bond length is 1.23 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(2)-C(4) bond length is 1.51 Å. The C(2)-O(1) bond length is 1.26 Å. The C(2)-O(2) bond length is 1.24 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(5) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(5) bond length is 1.38 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(6) atom. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(5)-H(1) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(6)-H(2) bond length is 0.93 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(5) atom. The C(9)-N(1) bond length is 1.31 Å. The C(9)-N(2) bond length is 1.35 Å. The C(9)-H(5) bond length is 0.93 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(1), and one H(6) atom. The C(10)-C(11) bond length is 1.33 Å. The C(10)-N(1) bond length is 1.39 Å. The C(10)-H(6) bond length is 0.93 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(7) atom. The C(11)-N(2) bond length is 1.36 Å. The C(11)-H(7) bond length is 0.93 Å. In the tenth C site, C(13) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(10,11) atoms. The C(13)-N(2) bond length is 1.47 Å. Both C(13)-H(10,11) bond lengths are 0.97 Å. In the eleventh C site, C(14) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(12,13) atoms. The C(14)-N(3) bond length is 1.47 Å. Both C(14)-H(12,13) bond lengths are 0.97 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(9) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(14) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(10,11) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(12,13) is bonded in a single-bond geometry to one C(14) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(2) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. Linkers: 16 [O]C(=O)c1ccccc1C(=O)[N]CCCn1ccnc1. Metal clusters: 8 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 6.40 A, density 1.13 g/cm3, surface area 4997.84 m2/g, accessible volume 0.40 cm3/g