AgH16(C2S)4(CO)2 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of eight formaldehyde molecules and four AgH16(C2S)4 clusters. In each AgH16(C2S)4 cluster, Ag(1) is bonded in a distorted tetrahedral geometry to one S(1), one S(2), one S(3), and one S(4) atom. The Ag(1)-S(1) bond length is 2.64 Å. The Ag(1)-S(2) bond length is 2.59 Å. The Ag(1)-S(3) bond length is 2.57 Å. The Ag(1)-S(4) bond length is 2.66 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a water-like geometry to one H(1), one H(2), and one S(1) atom. The C(1)-H(1) bond length is 0.96 Å. The C(1)-H(2) bond length is 0.96 Å. The C(1)-S(1) bond length is 1.80 Å. In the second C site, C(3) is bonded in a distorted water-like geometry to one H(3), one H(4), and one S(2) atom. The C(3)-H(3) bond length is 0.98 Å. The C(3)-H(4) bond length is 0.96 Å. The C(3)-S(2) bond length is 1.82 Å. In the third C site, C(4) is bonded in a water-like geometry to one H(5), one H(6), and one S(2) atom. The C(4)-H(5) bond length is 0.96 Å. The C(4)-H(6) bond length is 0.96 Å. The C(4)-S(2) bond length is 1.83 Å. In the fourth C site, C(5) is bonded in a distorted water-like geometry to one H(7), one H(8), and one S(3) atom. The C(5)-H(7) bond length is 0.95 Å. The C(5)-H(8) bond length is 0.95 Å. The C(5)-S(3) bond length is 1.82 Å. In the fifth C site, C(6) is bonded in a distorted water-like geometry to one H(10), one H(9), and one S(3) atom. The C(6)-H(10) bond length is 0.96 Å. The C(6)-H(9) bond length is 0.96 Å. The C(6)-S(3) bond length is 1.81 Å. In the sixth C site, C(8) is bonded in a water-like geometry to one H(11), one H(12), and one S(4) atom. The C(8)-H(11) bond length is 0.97 Å. The C(8)-H(12) bond length is 0.96 Å. The C(8)-S(4) bond length is 1.81 Å. In the seventh C site, C(9) is bonded in a distorted water-like geometry to one H(13), one H(14), and one S(4) atom. The C(9)-H(13) bond length is 0.96 Å. The C(9)-H(14) bond length is 0.95 Å. The C(9)-S(4) bond length is 1.83 Å. In the eighth C site, C(10) is bonded in a water-like geometry to one H(15), one H(16), and one S(1) atom. The C(10)-H(15) bond length is 0.98 Å. The C(10)-H(16) bond length is 0.97 Å. The C(10)-S(1) bond length is 1.81 Å. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(8) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(9) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(10) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(1), and one C(10) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(3), and one C(4) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(5), and one C(6) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(8), and one C(9) atom. Linkers: 1 O=[C][CH]S[CH][CH][S].[Ag].[Ag].[CH2].[CH2].[CH2].[CH2].[CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH][S].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]C[S].[C][CH]S[C].[C][CH][S]([CH][C]=O)[Ag](SC[C])[S]([CH])[CH][CH][S].[C][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[O].[O].[O].[O].[O].[O].[O].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S] ,1 O=C1CSCCSCC(=O)CSCCSC1. Metal clusters: 3 [Ag]. The MOF has largest included sphere 4.93 A, density 1.40 g/cm3, surface area 3822.72 m2/g, accessible volume 0.38 cm3/g