CuC6N3H6Cl2(C3H2)6C9H6N is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of twelve 2,3-dimethyl-1,3-butadiene molecules; four schembl1705614 molecules; and four CuC6N3H6Cl2 clusters. In each CuC6N3H6Cl2 cluster, Cu(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(2), one N(3), one Cl(1), and one Cl(2) atom. The Cu(1)-N(1) bond length is 2.03 Å. The Cu(1)-N(2) bond length is 2.12 Å. The Cu(1)-N(3) bond length is 2.02 Å. The Cu(1)-Cl(1) bond length is 2.31 Å. The Cu(1)-Cl(2) bond length is 2.47 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(9) bond length is 0.95 Å. In the fourth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(16)-N(2) bond length is 1.34 Å. The C(16)-H(12) bond length is 0.95 Å. In the fifth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(23)-N(3) bond length is 1.34 Å. The C(23)-H(17) bond length is 0.95 Å. In the sixth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(20) atom. The C(27)-N(3) bond length is 1.34 Å. The C(27)-H(20) bond length is 0.95 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(12), and one C(16) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(23), and one C(27) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one C(27) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Cu(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 2 c1cc(-c2ccc(N(c3ccc(-c4ccncc4)cc3)c3ccc(-c4ccncc4)cc3)cc2)ccn1 ,2 [CH]C(=[CH])c1ccc(N(c2ccc(-c3ccncc3)cc2)c2ccc(-c3ccncc3)cc2)cc1 ,2 [CH]=C[C]c1ccc(N(c2ccc(-c3ccncc3)cc2)c2ccc(-c3ccncc3)cc2)cc1. Metal clusters: 2 Cl[Cu]Cl. The MOF has largest included sphere 4.45 A, density 1.29 g/cm3, surface area 4767.67 m2/g, accessible volume 0.28 cm3/g