(ZnC9H5O4)2(CH)6C9H8O4 is Indium-derived structured and crystallizes in the tetragonal P-4n2 space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules; eight 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and eight ZnC9H5O4 clusters. In each ZnC9H5O4 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal non-coplanar geometry to one O(10), one O(5), and one O(6) atom. The Zn(1)-O(10) bond length is 1.94 Å. The Zn(1)-O(5) bond length is 1.92 Å. The Zn(1)-O(6) bond length is 1.93 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one O(11), one O(7), one O(8), and one O(9) atom. The Zn(2)-O(11) bond length is 1.96 Å. The Zn(2)-O(7) bond length is 1.92 Å. The Zn(2)-O(8) bond length is 1.93 Å. The Zn(2)-O(9) bond length is 1.96 Å. There are eighteen inequivalent C sites. In the first C site, C(4) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(27) atom. The C(4)-C(15) bond length is 1.47 Å. The C(4)-C(19) bond length is 1.35 Å. The C(4)-C(27) bond length is 1.36 Å. In the second C site, C(5) is bonded in a trigonal planar geometry to one C(17), one C(21), and one C(28) atom. The C(5)-C(17) bond length is 1.35 Å. The C(5)-C(21) bond length is 1.47 Å. The C(5)-C(28) bond length is 1.41 Å. In the third C site, C(8) is bonded in a single-bond geometry to one C(30) and one H(4) atom. The C(8)-C(30) bond length is 1.30 Å. The C(8)-H(4) bond length is 0.93 Å. In the fourth C site, C(10) is bonded in a bent 120 degrees geometry to one C(30), one O(12), and one O(7) atom. The C(10)-C(30) bond length is 1.52 Å. The C(10)-O(12) bond length is 1.19 Å. The C(10)-O(7) bond length is 1.22 Å. In the fifth C site, C(12) is bonded in a trigonal planar geometry to one C(13), one C(16), and one C(25) atom. The C(12)-C(13) bond length is 1.42 Å. The C(12)-C(16) bond length is 1.46 Å. The C(12)-C(25) bond length is 1.40 Å. In the sixth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(11), and one O(6) atom. The C(15)-O(11) bond length is 1.26 Å. The C(15)-O(6) bond length is 1.25 Å. In the seventh C site, C(13) is bonded in a single-bond geometry to one C(12) and one H(9) atom. The C(13)-H(9) bond length is 0.93 Å. In the eighth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(29), one C(4), and one H(13) atom. The C(19)-C(29) bond length is 1.39 Å. The C(19)-H(13) bond length is 0.93 Å. In the ninth C site, C(17) is bonded in a single-bond geometry to one C(5) and one H(12) atom. The C(17)-H(12) bond length is 0.93 Å. In the tenth C site, C(16) is bonded in a bent 120 degrees geometry to one C(12), one O(5), and one O(9) atom. The C(16)-O(5) bond length is 1.24 Å. The C(16)-O(9) bond length is 1.23 Å. In the eleventh C site, C(21) is bonded in a bent 120 degrees geometry to one C(5), one O(10), and one O(8) atom. The C(21)-O(10) bond length is 1.25 Å. The C(21)-O(8) bond length is 1.26 Å. In the twelfth C site, C(23) is bonded in a distorted single-bond geometry to one C(25) and one H(15) atom. The C(23)-C(25) bond length is 1.37 Å. The C(23)-H(15) bond length is 0.93 Å. In the thirteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(12), one C(23), and one H(17) atom. The C(25)-H(17) bond length is 0.93 Å. In the fourteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(4) and one H(19) atom. The C(27)-H(19) bond length is 0.93 Å. In the fifteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(5) and one H(20) atom. The C(28)-H(20) bond length is 0.93 Å. In the sixteenth C site, C(29) is bonded in a distorted single-bond geometry to one C(19) and one H(21) atom. The C(29)-H(21) bond length is 0.93 Å. In the seventeenth C site, C(30) is bonded in a trigonal planar geometry to one C(10), one C(33), and one C(8) atom. The C(30)-C(33) bond length is 1.44 Å. In the eighteenth C site, C(33) is bonded in a distorted single-bond geometry to one C(30) and one H(24) atom. The C(33)-H(24) bond length is 0.93 Å. There are ten inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(28) atom. In the ninth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the tenth H site, H(24) is bonded in a single-bond geometry to one C(33) atom. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(16) atom. In the second O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(15) atom. In the third O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(21) atom. In the fourth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(16) atom. In the fifth O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(15) atom. In the sixth O site, O(10) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(21) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(10) atom. In the eighth O site, O(12) is bonded in a single-bond geometry to one C(10) atom. Linkers: 8 [O]C(=O)c1ccc(OCC(COc2ccc(C([O])=O)cc2)(COc2ccc(C([O])=O)cc2)COc2ccc(C([O])=O)cc2)cc1. Metal clusters: 8 O=[C]O[Zn]12O[C]O[Zn](O[C]O1)O[C]O2. RCSR code: crb. The MOF has largest included sphere 9.86 A, density 0.71 g/cm3, surface area 4522.45 m2/g, accessible volume 0.95 cm3/g