ZnC12NH8O4(C5H3)2C5N4H8 is Indium-derived structured and crystallizes in the cubic P-43n space group. The structure is zero-dimensional and consists of eight 1,3,5-triisopropenyl benzene molecules; six C5N4H8 clusters; and six ZnC12NH8O4 clusters. In each C5N4H8 cluster, there are three inequivalent C sites. In the first C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one N(2) atom. The C(13)-C(14) bond length is 1.42 Å. The C(13)-N(2) bond length is 1.45 Å. In the second C site, C(14) is bonded in a 5-coordinate geometry to one C(14), two equivalent C(11), and two equivalent C(13) atoms. The C(14)-C(14) bond length is 1.48 Å. Both C(14)-C(11) bond lengths are 1.40 Å. In the third C site, C(11) is bonded in a distorted single-bond geometry to one C(14) and one N(1) atom. The C(11)-N(1) bond length is 1.44 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(11), one H(7), and one H(8) atom. The N(1)-H(7) bond length is 0.86 Å. The N(1)-H(8) bond length is 0.86 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(13), one H(10), and one H(11) atom. The N(2)-H(10) bond length is 0.86 Å. The N(2)-H(11) bond length is 0.86 Å. There are four inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(8) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(10) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one N(2) atom. In each ZnC12NH8O4 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(3), two equivalent O(1), and two equivalent O(2) atoms. The Zn(1)-N(3) bond length is 1.96 Å. Both Zn(1)-O(1) bond lengths are 2.08 Å. Both Zn(1)-O(2) bond lengths are 1.94 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.63 Å. The C(1)-O(1) bond length is 1.41 Å. The C(1)-O(2) bond length is 1.12 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1,4) atom. The C(3)-H(1,4) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(1,4) atom. The C(7)-H(1,4) bond length is 0.93 Å. In the fifth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(6) atom. The C(10)-N(3) bond length is 1.32 Å. The C(10)-H(6) bond length is 0.93 Å. In the sixth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(12)-N(3) bond length is 1.35 Å. The C(12)-H(9) bond length is 0.93 Å. N(3) is bonded in a 5-coordinate geometry to one Zn(1), two equivalent C(10), and two equivalent C(12) atoms. There are three inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. Linkers: 3 N[C@]12[C@H]3[C@H]4[C@@]2([C@@]21[C@]1([C@@]2([C@H]2[N@@]34[C@@H]12)N)N)N.N[C@]12[C@H]3[C@H]4[C@@]2([C@@]21[C@]1([C@@]2([C@H]2[N@@]34[C@@H]12)N)N)N ,3 N[C@]12[C@H]3[C@H]4[C@@]2([C@@]21[C@@]1([C@]2([C@@H]2[N@@]34[C@H]12)N)N)N.N[C@]12[C@H]3[C@H]4[C@@]2([C@@]21[C@@]1([C@]2([C@@H]2[N@@]34[C@H]12)N)N)N ,8 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C([O])=O)cc3)c2)cc1. Metal clusters: 6 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4. RCSR code: pto. The MOF has largest included sphere 20.18 A, density 0.51 g/cm3, surface area 4110.95 m2/g, accessible volume 1.52 cm3/g