ZnH36(C7N2)4(CH)4 is Indium-derived structured and crystallizes in the orthorhombic Fddd space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules and eight ZnH36(C7N2)4 clusters. In each ZnH36(C7N2)4 cluster, Zn(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. All Zn(1)-N(1) bond lengths are 2.16 Å. There are seven inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-C(2) bond length is 1.41 Å. The C(3)-H(2) bond length is 0.95 Å. In the second C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent H(9,10) atoms. The C(8)-N(2) bond length is 1.44 Å. Both C(8)-H(9,10) bond lengths are 0.99 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(1) bond length is 1.38 Å. The C(2)-C(6) bond length is 1.50 Å. In the fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the fifth C site, C(7) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(7,8) atoms. The C(7)-N(2) bond length is 1.48 Å. Both C(7)-H(7,8) bond lengths are 0.99 Å. In the sixth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.95 Å. In the seventh C site, C(6) is bonded in a 3-coordinate geometry to one C(2), one N(2), one H(5), and one H(6) atom. The C(6)-N(2) bond length is 1.51 Å. The C(6)-H(5) bond length is 0.99 Å. The C(6)-H(6) bond length is 0.99 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal non-coplanar geometry to one C(6), one C(7), and one C(8) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7,8) is bonded in a single-bond geometry to one C(7) atom. Linkers: 5 c1cncc(CN2CCN(Cc3cccnc3)CC2)c1 ,2 [c]1cncc(CN2CCN(Cc3cccnc3)CC2)c1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 5.92 A, density 0.87 g/cm3, surface area 5525.58 m2/g, accessible volume 0.67 cm3/g