Cu3C38H22(N3O4)2(CH)10 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of forty 02329_fluka molecules and four Cu3C38H22(N3O4)2 clusters. In each Cu3C38H22(N3O4)2 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(2), one O(1), and one O(3) atom. The Cu(1)-N(1) bond length is 2.02 Å. The Cu(1)-N(2) bond length is 2.00 Å. The Cu(1)-O(1) bond length is 1.94 Å. The Cu(1)-O(3) bond length is 1.93 Å. In the second Cu site, Cu(2) is bonded in a 6-coordinate geometry to two equivalent N(3), two equivalent O(1), and two equivalent O(4) atoms. Both Cu(2)-N(3) bond lengths are 2.01 Å. Both Cu(2)-O(1) bond lengths are 2.61 Å. Both Cu(2)-O(4) bond lengths are 1.94 Å. There are nineteen inequivalent C sites. In the first C site, C(2) is bonded in a single-bond geometry to one C(1) and one H(2) atom. The C(2)-C(1) bond length is 1.40 Å. The C(2)-H(2) bond length is 0.93 Å. In the second C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(7)-C(11) bond length is 1.40 Å. The C(7)-C(6) bond length is 1.42 Å. The C(7)-C(8) bond length is 1.40 Å. In the third C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 0.93 Å. In the fourth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(7) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-H(7) bond length is 0.93 Å. In the fifth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.33 Å. The C(10)-H(8) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(7), and one N(2) atom. The C(11)-C(12) bond length is 1.42 Å. The C(11)-N(2) bond length is 1.37 Å. In the seventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(4), and one N(1) atom. The C(12)-C(4) bond length is 1.39 Å. The C(12)-N(1) bond length is 1.35 Å. In the eighth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(13)-N(3) bond length is 1.32 Å. The C(13)-H(9) bond length is 0.93 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-H(11) bond length is 0.93 Å. In the tenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. The C(16)-C(17) bond length is 1.43 Å. The C(16)-C(18) bond length is 1.39 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(17)-H(12) bond length is 0.93 Å. In the twelfth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one N(3) atom. The C(18)-C(18) bond length is 1.41 Å. The C(18)-N(3) bond length is 1.37 Å. In the thirteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(19)-O(1) bond length is 1.27 Å. The C(19)-O(2) bond length is 1.24 Å. In the fourteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(22)-O(3) bond length is 1.23 Å. The C(22)-O(4) bond length is 1.26 Å. In the fifteenth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.93 Å. In the sixteenth C site, C(3) is bonded in a single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 0.93 Å. In the seventeenth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(5) bond length is 1.45 Å. In the eighteenth C site, C(5) is bonded in a single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 0.93 Å. In the nineteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-H(5) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(12) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(11) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(2), one C(13), and one C(18) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(17) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1), one Cu(2), and one C(19) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(19) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one C(22) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(22) atom. Linkers: 8 [O]C(=O)/C=C/C=C/C([O])=O ,6 c1cnc2c(c1)ccc1cccnc12. Metal clusters: 4 O=[C]O[Cu]O[C]O[Cu]O[C]O[Cu]O[C]=O. The MOF has largest included sphere 4.34 A, density 1.25 g/cm3, surface area 4343.58 m2/g, accessible volume 0.41 cm3/g