Co3C36N2H18O15(CH)6(C3H2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules; four 2,3-dimethyl-1,3-butadiene molecules; and two Co3C36N2H18O15 clusters. In each Co3C36N2H18O15 cluster, there are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(13), one O(15), one O(7), and one O(8) atom to form corner-sharing CoO5 square pyramids. The Co(1)-O(1) bond length is 2.10 Å. The Co(1)-O(13) bond length is 2.09 Å. The Co(1)-O(15) bond length is 2.10 Å. The Co(1)-O(7) bond length is 2.15 Å. The Co(1)-O(8) bond length is 2.11 Å. In the second Co site, Co(2) is bonded in an octahedral geometry to one N(1), one N(2), one O(10), one O(5), one O(6), and one O(9) atom. The Co(2)-N(1) bond length is 2.15 Å. The Co(2)-N(2) bond length is 2.13 Å. The Co(2)-O(10) bond length is 2.09 Å. The Co(2)-O(5) bond length is 2.08 Å. The Co(2)-O(6) bond length is 2.06 Å. The Co(2)-O(9) bond length is 2.05 Å. In the third Co site, Co(3) is bonded to one O(11), one O(14), one O(15), one O(2), and one O(4) atom to form corner-sharing CoO5 square pyramids. The Co(3)-O(11) bond length is 2.03 Å. The Co(3)-O(14) bond length is 2.01 Å. The Co(3)-O(15) bond length is 2.20 Å. The Co(3)-O(2) bond length is 2.02 Å. The Co(3)-O(4) bond length is 2.07 Å. There are thirty-six inequivalent C sites. In the first C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(5)-C(6) bond length is 1.42 Å. The C(5)-H(5) bond length is 0.93 Å. In the second C site, C(6) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(6)-C(3) bond length is 1.41 Å. The C(6)-C(9) bond length is 1.41 Å. In the third C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(7) atom. The C(8)-C(9) bond length is 1.42 Å. The C(8)-H(7) bond length is 0.93 Å. In the fourth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(6), and one C(8) atom. The C(9)-C(10) bond length is 1.40 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(10)-H(8) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(2) and one O(3) atom. The C(11)-C(2) bond length is 1.42 Å. The C(11)-O(3) bond length is 1.39 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one O(3) atom. The C(12)-O(3) bond length is 1.37 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(9) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(9) bond length is 0.93 Å. In the ninth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(18) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(18) bond length is 1.51 Å. In the tenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(19) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-C(19) bond length is 1.48 Å. In the eleventh C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(6), and one O(7) atom. The C(18)-O(6) bond length is 1.26 Å. The C(18)-O(7) bond length is 1.25 Å. In the twelfth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(8), and one O(9) atom. The C(20)-C(21) bond length is 1.51 Å. The C(20)-O(8) bond length is 1.25 Å. The C(20)-O(9) bond length is 1.26 Å. In the thirteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(26) and one H(14) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-H(14) bond length is 0.93 Å. In the fourteenth C site, C(26) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(27) atom. The C(26)-C(21) bond length is 1.39 Å. The C(26)-C(27) bond length is 1.50 Å. In the fifteenth C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(42) atom. The C(29)-C(28) bond length is 1.41 Å. The C(29)-C(30) bond length is 1.37 Å. The C(29)-C(42) bond length is 1.51 Å. In the sixteenth C site, C(30) is bonded in a distorted single-bond geometry to one C(29), one C(31), and one H(15) atom. The C(30)-C(31) bond length is 1.42 Å. The C(30)-H(15) bond length is 0.93 Å. In the seventeenth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(36) atom. The C(31)-C(32) bond length is 1.42 Å. The C(31)-C(36) bond length is 1.40 Å. In the eighteenth C site, C(35) is bonded in a distorted single-bond geometry to one C(36) and one H(19) atom. The C(35)-C(36) bond length is 1.42 Å. The C(35)-H(19) bond length is 0.93 Å. In the nineteenth C site, C(36) is bonded in a trigonal planar geometry to one C(31), one C(35), and one C(37) atom. The C(36)-C(37) bond length is 1.41 Å. In the twentieth C site, C(37) is bonded in a distorted single-bond geometry to one C(36) and one H(20) atom. The C(37)-H(20) bond length is 0.93 Å. In the twenty-first C site, C(38) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(21) atom. The C(38)-N(1) bond length is 1.33 Å. The C(38)-H(21) bond length is 0.93 Å. In the twenty-second C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(13), and one O(14) atom. The C(42)-O(13) bond length is 1.23 Å. The C(42)-O(14) bond length is 1.26 Å. In the twenty-third C site, C(45) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(25) atom. The C(45)-N(2) bond length is 1.35 Å. The C(45)-H(25) bond length is 0.93 Å. In the twenty-fourth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(26) atom. The C(46)-N(2) bond length is 1.31 Å. The C(46)-H(26) bond length is 0.93 Å. In the twenty-fifth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(10) atom. The C(16)-H(10) bond length is 0.93 Å. In the twenty-sixth C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(16) atom. The C(32)-H(16) bond length is 0.93 Å. In the twenty-seventh C site, C(19) is bonded in a bent 120 degrees geometry to one C(15), one O(4), and one O(5) atom. The C(19)-O(4) bond length is 1.25 Å. The C(19)-O(5) bond length is 1.26 Å. In the twenty-eighth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(26) atom. The C(21)-C(22) bond length is 1.39 Å. In the twenty-ninth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(12) atom. The C(22)-H(12) bond length is 0.93 Å. In the thirtieth C site, C(23) is bonded in a distorted single-bond geometry to one O(12) atom. The C(23)-O(12) bond length is 1.38 Å. In the thirty-first C site, C(27) is bonded in a bent 120 degrees geometry to one C(26), one O(10), and one O(11) atom. The C(27)-O(10) bond length is 1.25 Å. The C(27)-O(11) bond length is 1.24 Å. In the thirty-second C site, C(28) is bonded in a distorted single-bond geometry to one C(29) and one O(12) atom. The C(28)-O(12) bond length is 1.38 Å. In the thirty-third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.53 Å. The C(1)-O(1) bond length is 1.24 Å. The C(1)-O(2) bond length is 1.25 Å. In the thirty-fourth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(3) atom. The C(2)-C(3) bond length is 1.37 Å. In the thirty-fifth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(3) atom. The C(3)-H(3) bond length is 0.93 Å. In the thirty-sixth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(4)-N(1) bond length is 1.32 Å. The C(4)-H(4) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(2), one C(38), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(2), one C(45), and one C(46) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(15) atom. The H(1)-O(15) bond length is 0.88 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(15) atom. The H(2)-O(15) bond length is 0.78 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(30) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(32) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(35) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(37) atom. In the sixteenth H site, H(21) is bonded in a single-bond geometry to one C(38) atom. In the seventeenth H site, H(25) is bonded in a single-bond geometry to one C(45) atom. In the eighteenth H site, H(26) is bonded in a single-bond geometry to one C(46) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Co(3) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(11) and one C(12) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Co(3) and one C(19) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(19) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(18) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(18) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Co(1) and one C(20) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Co(2) and one C(20) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(27) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Co(3) and one C(27) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one C(23) and one C(28) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(42) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Co(3) and one C(42) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Co(1), one Co(3), one H(1), and one H(2) atom. Linkers: 4 c1cc(-c2ccncc2)ccn1 ,8 [O]C(=O)c1cc2ccccc2cc1Oc1ccc(C([O])=O)c(C([O])=O)c1. Metal clusters: 2 O.O.[C]1O[Co]23O[C]O[Co]4(O1)O[C]O[Co]1(O[C]O2)O[C]O[Co]25O[C]O[Co](O[C]O2)(O[C]O1)O[C]O[Co](O[C]O3)(O[C]O4)O[C]O5. The MOF has largest included sphere 4.99 A, density 1.47 g/cm3, surface area 3960.67 m2/g, accessible volume 0.18 cm3/g