ZnC24H22(NO)4 is Indium-like structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of eighteen ZnC24H22(NO)4 clusters. Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(4), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 1.99 Å. The Zn(1)-N(4) bond length is 2.00 Å. The Zn(1)-O(1) bond length is 1.92 Å. The Zn(1)-O(3) bond length is 1.92 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(8) atom. The C(1)-C(5) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.40 Å. The C(1)-C(8) bond length is 1.48 Å. In the second C site, C(5) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(6) is bonded in a single-bond geometry to one C(1) and one H(5) atom. The C(6)-H(5) bond length is 0.95 Å. In the fourth C site, C(8) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(9) atom. The C(8)-C(10) bond length is 1.39 Å. The C(8)-C(9) bond length is 1.40 Å. In the fifth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(11), one C(8), and one N(1) atom. The C(9)-C(11) bond length is 1.50 Å. The C(9)-N(1) bond length is 1.34 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one N(2) atom. The C(10)-C(12) bond length is 1.49 Å. The C(10)-N(2) bond length is 1.35 Å. In the seventh C site, C(11) is bonded in a trigonal non-coplanar geometry to one C(9); one H(8); and two equivalent H(7,9) atoms. The C(11)-H(8) bond length is 0.98 Å. Both C(11)-H(7,9) bond lengths are 0.98 Å. In the eighth C site, C(12) is bonded in a trigonal non-coplanar geometry to one C(10); one H(11); and two equivalent H(10,12) atoms. The C(12)-H(11) bond length is 0.98 Å. Both C(12)-H(10,12) bond lengths are 0.98 Å. In the ninth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(3), and one O(4) atom. The C(13)-C(14) bond length is 1.50 Å. The C(13)-O(3) bond length is 1.28 Å. The C(13)-O(4) bond length is 1.24 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(14) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(14) bond length is 0.95 Å. In the eleventh C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(20) bond length is 1.47 Å. In the twelfth C site, C(18) is bonded in a single-bond geometry to one C(17) and one H(15) atom. The C(18)-H(15) bond length is 0.95 Å. In the thirteenth C site, C(20) is bonded in a trigonal planar geometry to one C(17), one C(21), and one C(22) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-C(22) bond length is 1.40 Å. In the fourteenth C site, C(21) is bonded in a 3-coordinate geometry to one C(20), one C(23), and one N(3) atom. The C(21)-C(23) bond length is 1.49 Å. The C(21)-N(3) bond length is 1.34 Å. In the fifteenth C site, C(22) is bonded in a 3-coordinate geometry to one C(20), one C(24), and one N(4) atom. The C(22)-C(24) bond length is 1.51 Å. The C(22)-N(4) bond length is 1.34 Å. In the sixteenth C site, C(23) is bonded in a trigonal non-coplanar geometry to one C(21); one H(17,20,22); and two equivalent H(18,19) atoms. The C(23)-H(17,20,22) bond length is 0.98 Å. Both C(23)-H(18,19) bond lengths are 0.98 Å. In the seventeenth C site, C(24) is bonded in a trigonal non-coplanar geometry to one C(22); one H(21); and two equivalent H(17,20,22) atoms. The C(24)-H(21) bond length is 0.98 Å. Both C(24)-H(17,20,22) bond lengths are 0.98 Å. In the eighteenth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(7) atom. The C(3)-C(2) bond length is 1.50 Å. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(7) bond length is 1.39 Å. In the nineteenth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3,6) atom. The C(4)-H(3,6) bond length is 0.95 Å. In the twentieth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(16) atom. The C(19)-C(14) bond length is 1.38 Å. The C(19)-H(16) bond length is 0.95 Å. In the twenty-first C site, C(7) is bonded in a distorted single-bond geometry to one C(3) and one H(3,6) atom. The C(7)-H(3,6) bond length is 0.95 Å. In the twenty-second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(2) atom. The C(2)-O(1) bond length is 1.28 Å. The C(2)-O(2) bond length is 1.24 Å. In the twenty-third C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.39 Å. In the twenty-fourth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(13) atom. The C(15)-H(13) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Zn(1), one C(9), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(1), and one H(1) atom. The N(2)-H(1) bond length is 0.88 Å. In the third N site, N(3) is bonded in a 1-coordinate geometry to one C(21), one N(4), and one H(2) atom. The N(3)-N(4) bond length is 1.36 Å. The N(3)-H(2) bond length is 0.88 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(22), and one N(3) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(3) atom. In the third H site, H(3,6) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7,9) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10,12) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(17,20,22) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(18,19) is bonded in a single-bond geometry to one C(23) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the sixteenth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one C(2) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the third O site, O(4) is bonded in a single-bond geometry to one C(13) atom. In the fourth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(2) atom. Linkers: 36 Cc1n[nH]c(C)c1-c1ccc(C([O])=O)cc1. Metal clusters: 18 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 7.22 A, density 1.05 g/cm3, surface area 5104.68 m2/g, accessible volume 0.39 cm3/g