AgPH24(C5N)6(CH)3 is Indium-derived structured and crystallizes in the cubic P2_13 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and four AgPH24(C5N)6 clusters. In each AgPH24(C5N)6 cluster, Ag(1) is bonded in a tetrahedral geometry to one P(1) and three equivalent N(2) atoms. The Ag(1)-P(1) bond length is 2.44 Å. All Ag(1)-N(2) bond lengths are 2.32 Å. There are ten inequivalent C sites. In the first C site, C(5) is bonded in a distorted single-bond geometry to one C(3), one C(8), and one H(3) atom. The C(5)-C(3) bond length is 1.38 Å. The C(5)-C(8) bond length is 1.39 Å. The C(5)-H(3) bond length is 0.93 Å. In the second C site, C(1) is bonded in a distorted single-bond geometry to one N(1) atom. The C(1)-N(1) bond length is 1.42 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(4), one C(5), and one P(1) atom. The C(3)-C(4) bond length is 1.37 Å. The C(3)-P(1) bond length is 1.82 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(6)-C(7) bond length is 1.36 Å. The C(6)-H(4) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.33 Å. The C(7)-H(5) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(6) atom. The C(8)-H(6) bond length is 0.93 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(7) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-N(2) bond length is 1.31 Å. The C(9)-H(7) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(2), and one H(8) atom. The C(10)-C(11) bond length is 1.33 Å. The C(10)-N(2) bond length is 1.38 Å. The C(10)-H(8) bond length is 0.93 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(9) atom. The C(11)-N(1) bond length is 1.37 Å. The C(11)-H(9) bond length is 0.93 Å. P(1) is bonded in a distorted tetrahedral geometry to one Ag(1) and three equivalent C(3) atoms. There are two inequivalent N sites. In the first N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(10), and one C(9) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(9) atom. There are eight inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. Linkers: 4 c1cn(-c2cc(-n3ccnc3)cc(-n3ccnc3)c2)cn1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 6.18 A, density 1.12 g/cm3, surface area 4977.68 m2/g, accessible volume 0.40 cm3/g