CoC19N3H12O5(CH)4C7NH4OC2O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, two dimethyl ether molecules, two schembl6802232 molecules, and one CoC19N3H12O5 cluster. In the CoC19N3H12O5 cluster, Co(1) is bonded in an octahedral geometry to one N(1), one N(4), one O(4), one O(5), one O(6), and one O(7) atom. The Co(1)-N(1) bond length is 2.14 Å. The Co(1)-N(4) bond length is 2.15 Å. The Co(1)-O(4) bond length is 2.16 Å. The Co(1)-O(5) bond length is 2.20 Å. The Co(1)-O(6) bond length is 2.01 Å. The Co(1)-O(7) bond length is 2.03 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(4) bond length is 0.93 Å. In the third C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(10,11) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(10,11) bond length is 0.93 Å. In the fourth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(19) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-C(19) bond length is 1.49 Å. In the fifth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(10,11) atom. The C(17)-H(10,11) bond length is 0.93 Å. In the sixth C site, C(19) is bonded in a 3-coordinate geometry to one C(16), one N(3), and one O(3) atom. The C(19)-N(3) bond length is 1.38 Å. The C(19)-O(3) bond length is 1.22 Å. In the seventh C site, C(20) is bonded in a distorted trigonal planar geometry to one C(21), one C(24), and one N(3) atom. The C(20)-C(21) bond length is 1.37 Å. The C(20)-C(24) bond length is 1.37 Å. The C(20)-N(3) bond length is 1.39 Å. In the eighth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(13) atom. The C(21)-H(13) bond length is 0.93 Å. In the ninth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(14) atom. The C(22)-N(4) bond length is 1.32 Å. The C(22)-H(14) bond length is 0.93 Å. In the tenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(24), one N(4), and one H(15) atom. The C(23)-C(24) bond length is 1.36 Å. The C(23)-N(4) bond length is 1.32 Å. The C(23)-H(15) bond length is 0.93 Å. In the eleventh C site, C(24) is bonded in a distorted trigonal planar geometry to one C(20), one C(23), and one H(16) atom. The C(24)-H(16) bond length is 0.93 Å. In the twelfth C site, C(25) is bonded in a bent 120 degrees geometry to one C(26), one O(4), and one O(5) atom. The C(25)-C(26) bond length is 1.50 Å. The C(25)-O(4) bond length is 1.25 Å. The C(25)-O(5) bond length is 1.26 Å. In the thirteenth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(28) atom. The C(26)-C(27) bond length is 1.37 Å. The C(26)-C(28) bond length is 1.39 Å. In the fourteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(17) atom. The C(27)-H(17) bond length is 0.93 Å. In the fifteenth C site, C(28) is bonded in a single-bond geometry to one C(26) and one H(18) atom. The C(28)-H(18) bond length is 0.93 Å. In the sixteenth C site, C(29) is bonded in a single-bond geometry to one C(31) and one H(19) atom. The C(29)-C(31) bond length is 1.41 Å. The C(29)-H(19) bond length is 0.93 Å. In the seventeenth C site, C(30) is bonded in a single-bond geometry to one C(31) and one H(20) atom. The C(30)-C(31) bond length is 1.38 Å. The C(30)-H(20) bond length is 0.93 Å. In the eighteenth C site, C(31) is bonded in a trigonal planar geometry to one C(29), one C(30), and one C(32) atom. The C(31)-C(32) bond length is 1.48 Å. In the nineteenth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(6), and one O(7) atom. The C(32)-O(6) bond length is 1.25 Å. The C(32)-O(7) bond length is 1.26 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(5) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one C(19) and one C(20) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(22), and one C(23) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(10,11) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(28) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(30) atom. There are five inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(19) atom. In the second O site, O(4) is bonded in an L-shaped geometry to one Co(1) and one C(25) atom. In the third O site, O(5) is bonded in an L-shaped geometry to one Co(1) and one C(25) atom. In the fourth O site, O(6) is bonded in a bent 150 degrees geometry to one Co(1) and one C(32) atom. In the fifth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(32) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 1 [C]1O[Co]2(O1)O[C]O[Co]1(O[C]O1)O[C]O2. RCSR code: sql. The MOF has largest included sphere 5.49 A, density 1.15 g/cm3, surface area 4631.96 m2/g, accessible volume 0.42 cm3/g