Zn4C24H12O13 is Indium-like structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight Zn4C24H12O13 clusters. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(2) bond length is 1.94 Å. The Zn(1)-O(3) bond length is 1.94 Å. The Zn(1)-O(5) bond length is 1.95 Å. In the second Zn site, Zn(2) is bonded to one O(5) and three equivalent O(4) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(5) bond length is 1.94 Å. All Zn(2)-O(4) bond lengths are 1.93 Å. There are eight inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(5) atom. The C(2)-C(1) bond length is 1.49 Å. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(5) bond length is 1.39 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(4) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(4) bond length is 1.26 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(8) and one H(2) atom. The C(4)-C(8) bond length is 1.39 Å. The C(4)-H(2) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(5)-H(3) bond length is 0.95 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(2), and one O(3) atom. The C(7)-C(8) bond length is 1.50 Å. The C(7)-O(2) bond length is 1.26 Å. The C(7)-O(3) bond length is 1.26 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(8)-C(6) bond length is 1.39 Å. In the eighth C site, C(6) is bonded in a distorted single-bond geometry to one C(8) and one H(4) atom. The C(6)-H(4) bond length is 0.95 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. There are five inequivalent O sites. In the first O site, O(5) is bonded in a tetrahedral geometry to one Zn(2) and three equivalent Zn(1) atoms. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the fourth O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. Linkers: 24 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 8 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: pcu. The MOF has largest included sphere 13.36 A, density 0.62 g/cm3, surface area 3726.29 m2/g, accessible volume 1.15 cm3/g