CuC15N3H14O5CH is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four CuC15N3H14O5 clusters. In each CuC15N3H14O5 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square pyramidal geometry to one N(3), one N(4), one O(1), one O(2), and one O(4) atom. The Cu(1)-N(3) bond length is 2.24 Å. The Cu(1)-N(4) bond length is 2.02 Å. The Cu(1)-O(1) bond length is 1.96 Å. The Cu(1)-O(2) bond length is 1.96 Å. The Cu(1)-O(4) bond length is 1.98 Å. In the second Cu site, Cu(2) is bonded in a square pyramidal geometry to one N(2), one N(6), one O(10), one O(5), and one O(6) atom. The Cu(2)-N(2) bond length is 2.02 Å. The Cu(2)-N(6) bond length is 2.22 Å. The Cu(2)-O(10) bond length is 1.95 Å. The Cu(2)-O(5) bond length is 1.96 Å. The Cu(2)-O(6) bond length is 1.98 Å. There are thirty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(8) atom. The C(1)-C(2) bond length is 1.55 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(8) bond length is 1.23 Å. In the second C site, C(2) is bonded in a tetrahedral geometry to one C(1), one C(23), one C(24), and one C(3) atom. The C(2)-C(23) bond length is 1.53 Å. The C(2)-C(24) bond length is 1.54 Å. The C(2)-C(3) bond length is 1.54 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(6) atom. The C(3)-O(2) bond length is 1.26 Å. The C(3)-O(6) bond length is 1.25 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(2) atom. The C(4)-N(3) bond length is 1.33 Å. The C(4)-H(2) bond length is 0.95 Å. In the fifth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(5) atom. The C(10)-N(3) bond length is 1.34 Å. The C(10)-H(5) bond length is 0.95 Å. In the sixth C site, C(31) is bonded in a trigonal non-coplanar geometry to one C(30) and three equivalent H(25,26,27) atoms. The C(31)-C(30) bond length is 1.53 Å. All C(31)-H(25,26,27) bond lengths are 0.98 Å. In the seventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(6) atom. The C(11)-N(4) bond length is 1.35 Å. The C(11)-H(6) bond length is 0.95 Å. In the eighth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(4), and one O(5) atom. The C(16)-C(30) bond length is 1.54 Å. The C(16)-O(4) bond length is 1.26 Å. The C(16)-O(5) bond length is 1.27 Å. In the ninth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(11) atom. The C(17)-N(6) bond length is 1.33 Å. The C(17)-H(11) bond length is 0.95 Å. In the tenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(14) atom. The C(22)-N(6) bond length is 1.35 Å. The C(22)-H(14) bond length is 0.95 Å. In the eleventh C site, C(23) is bonded in a trigonal non-coplanar geometry to one C(2); one H(17); and two equivalent H(15,16) atoms. The C(23)-H(17) bond length is 0.98 Å. Both C(23)-H(15,16) bond lengths are 0.98 Å. In the twelfth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(10), and one O(7) atom. The C(29)-C(30) bond length is 1.54 Å. The C(29)-O(10) bond length is 1.28 Å. The C(29)-O(7) bond length is 1.24 Å. In the thirteenth C site, C(30) is bonded in a tetrahedral geometry to one C(16), one C(29), one C(31), and one C(32) atom. The C(30)-C(32) bond length is 1.55 Å. In the fourteenth C site, C(32) is bonded in a trigonal non-coplanar geometry to one C(30), one H(28), one H(29), and one H(30) atom. The C(32)-H(28) bond length is 0.98 Å. The C(32)-H(29) bond length is 0.98 Å. The C(32)-H(30) bond length is 0.98 Å. In the fifteenth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(6)-C(5) bond length is 1.38 Å. The C(6)-C(7) bond length is 1.50 Å. The C(6)-C(9) bond length is 1.39 Å. In the sixteenth C site, C(7) is bonded in a 3-coordinate geometry to one C(6), one N(1), and one O(3) atom. The C(7)-N(1) bond length is 1.35 Å. The C(7)-O(3) bond length is 1.22 Å. In the seventeenth C site, C(8) is bonded in a trigonal planar geometry to one C(27), one C(28), and one N(1) atom. The C(8)-C(27) bond length is 1.39 Å. The C(8)-C(28) bond length is 1.39 Å. The C(8)-N(1) bond length is 1.41 Å. In the eighteenth C site, C(9) is bonded in a distorted single-bond geometry to one C(6) and one H(3,4) atom. The C(9)-H(3,4) bond length is 0.95 Å. In the nineteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(8) and one H(23) atom. The C(27)-H(23) bond length is 0.95 Å. In the twentieth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(21) atom. The C(25)-N(2) bond length is 1.35 Å. The C(25)-H(21) bond length is 0.95 Å. In the twenty-first C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(8) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(8) bond length is 0.95 Å. In the twenty-second C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one N(5) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-N(5) bond length is 1.40 Å. In the twenty-third C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(4), and one H(9) atom. The C(15)-N(4) bond length is 1.33 Å. The C(15)-H(9) bond length is 0.95 Å. In the twenty-fourth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(2), and one H(24) atom. The C(28)-N(2) bond length is 1.35 Å. The C(28)-H(24) bond length is 0.95 Å. In the twenty-fifth C site, C(5) is bonded in a single-bond geometry to one C(6) and one H(3,4) atom. The C(5)-H(3,4) bond length is 0.95 Å. In the twenty-sixth C site, C(18) is bonded in a single-bond geometry to one C(19) and one H(12) atom. The C(18)-C(19) bond length is 1.38 Å. The C(18)-H(12) bond length is 0.95 Å. In the twenty-seventh C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(21) atom. The C(19)-C(20) bond length is 1.50 Å. The C(19)-C(21) bond length is 1.39 Å. In the twenty-eighth C site, C(20) is bonded in a 3-coordinate geometry to one C(19), one N(5), and one O(9) atom. The C(20)-N(5) bond length is 1.36 Å. The C(20)-O(9) bond length is 1.22 Å. In the twenty-ninth C site, C(21) is bonded in a distorted single-bond geometry to one C(19) and one H(13) atom. The C(21)-H(13) bond length is 0.95 Å. In the thirtieth C site, C(24) is bonded in a trigonal non-coplanar geometry to one C(2); one H(20); and two equivalent H(18,19) atoms. The C(24)-H(20) bond length is 0.98 Å. Both C(24)-H(18,19) bond lengths are 0.98 Å. There are six inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(25), and one C(28) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(15) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one Cu(2), one C(17), and one C(22) atom. In the fifth N site, N(1) is bonded in a distorted trigonal planar geometry to one C(7), one C(8), and one H(1) atom. The N(1)-H(1) bond length is 0.88 Å. In the sixth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(14), one C(20), and one H(10) atom. The N(5)-H(10) bond length is 0.88 Å. There are twenty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one N(5) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(15,16) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the fifteenth H site, H(18,19) is bonded in a single-bond geometry to one C(24) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(25) atom. In the eighteenth H site, H(23) is bonded in a single-bond geometry to one C(27) atom. In the nineteenth H site, H(24) is bonded in a single-bond geometry to one C(28) atom. In the twentieth H site, H(25,26,27) is bonded in a single-bond geometry to one C(31) atom. In the twenty-first H site, H(28) is bonded in a single-bond geometry to one C(32) atom. In the twenty-second H site, H(29) is bonded in a single-bond geometry to one C(32) atom. In the twenty-third H site, H(30) is bonded in a single-bond geometry to one C(32) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(16) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(16) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(3) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(29) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(1) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(20) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(29) atom. Linkers: 16 CC(C)(C([O])=O)C([O])=O ,16 O=C(Nc1cccnc1)c1ccncc1. Metal clusters: 4 O=[C]O[Cu]1O[C]O[Cu](O[C]=O)O[C]O[Cu](O[C]=O)O[C]O[Cu](O[C]=O)O[C]O1. The MOF has largest included sphere 6.47 A, density 1.26 g/cm3, surface area 4527.37 m2/g, accessible volume 0.30 cm3/g