CuH30(C11O3)4 is Indium-like structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two CuH30(C11O3)4 clusters. Cu(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. The Cu(1)-O(2) bond length is 2.20 Å. The Cu(1)-O(4) bond length is 2.22 Å. The Cu(1)-O(5) bond length is 2.37 Å. The Cu(1)-O(6) bond length is 2.39 Å. The Cu(1)-O(7) bond length is 2.27 Å. The Cu(1)-O(8) bond length is 2.41 Å. There are forty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.46 Å. The C(1)-O(1) bond length is 1.19 Å. The C(1)-O(2) bond length is 1.24 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(7) bond length is 1.32 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.30 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-C(8) bond length is 1.49 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(3) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(3) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(5), and one C(9) atom. The C(8)-C(13) bond length is 1.42 Å. The C(8)-C(9) bond length is 1.36 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(5) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(5) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(16), and one C(9) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-C(16) bond length is 1.45 Å. In the eleventh C site, C(11) is bonded in a single-bond geometry to one C(10), one C(12), and one O(11) atom. The C(11)-C(12) bond length is 1.45 Å. The C(11)-O(11) bond length is 1.37 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(23) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-C(23) bond length is 1.48 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one O(12) atom. The C(13)-O(12) bond length is 1.35 Å. In the fourteenth C site, C(14) is bonded in a tetrahedral geometry to one H(7); two equivalent H(6,8); and one O(12) atom. The C(14)-H(7) bond length is 0.96 Å. Both C(14)-H(6,8) bond lengths are 0.96 Å. The C(14)-O(12) bond length is 1.39 Å. In the fifteenth C site, C(15) is bonded in a tetrahedral geometry to one H(10), one H(11), one H(9), and one O(11) atom. The C(15)-H(10) bond length is 0.96 Å. The C(15)-H(11) bond length is 0.96 Å. The C(15)-H(9) bond length is 0.96 Å. The C(15)-O(11) bond length is 1.42 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(10), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(21) bond length is 1.42 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(17)-H(12) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(13) atom. The C(18)-C(19) bond length is 1.33 Å. The C(18)-H(13) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(22) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-C(22) bond length is 1.58 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(14) atom. The C(20)-H(14) bond length is 0.93 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(15) atom. The C(21)-H(15) bond length is 0.93 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(3), and one O(4) atom. The C(22)-O(3) bond length is 1.17 Å. The C(22)-O(4) bond length is 1.23 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(12), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.42 Å. The C(23)-C(28) bond length is 1.36 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one O(9) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-O(9) bond length is 1.38 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(31) atom. The C(25)-C(26) bond length is 1.42 Å. The C(25)-C(31) bond length is 1.51 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(25), one C(27), and one H(16) atom. The C(26)-C(27) bond length is 1.35 Å. The C(26)-H(16) bond length is 0.93 Å. In the twenty-seventh C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(38) atom. The C(27)-C(28) bond length is 1.38 Å. The C(27)-C(38) bond length is 1.52 Å. In the twenty-eighth C site, C(28) is bonded in a distorted single-bond geometry to one C(23), one C(27), and one O(10) atom. The C(28)-O(10) bond length is 1.42 Å. In the twenty-ninth C site, C(29) is bonded in a tetrahedral geometry to one H(19); two equivalent H(17,18); and one O(10) atom. The C(29)-H(19) bond length is 0.96 Å. Both C(29)-H(17,18) bond lengths are 0.96 Å. The C(29)-O(10) bond length is 1.42 Å. In the thirtieth C site, C(30) is bonded in a tetrahedral geometry to one H(22); two equivalent H(20,21); and one O(9) atom. The C(30)-H(22) bond length is 0.96 Å. Both C(30)-H(20,21) bond lengths are 0.96 Å. The C(30)-O(9) bond length is 1.50 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one C(25), one C(32), and one C(36) atom. The C(31)-C(32) bond length is 1.32 Å. The C(31)-C(36) bond length is 1.41 Å. In the thirty-second C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(23) atom. The C(32)-H(23) bond length is 0.93 Å. In the thirty-third C site, C(33) is bonded in a distorted single-bond geometry to one C(34) and one H(24) atom. The C(33)-C(34) bond length is 1.41 Å. The C(33)-H(24) bond length is 0.93 Å. In the thirty-fourth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(37) atom. The C(34)-C(35) bond length is 1.32 Å. The C(34)-C(37) bond length is 1.44 Å. In the thirty-fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(34) and one H(25) atom. The C(35)-H(25) bond length is 0.93 Å. In the thirty-sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(31) and one H(26) atom. The C(36)-H(26) bond length is 0.93 Å. In the thirty-seventh C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(34), one O(5), and one O(6) atom. The C(37)-O(5) bond length is 1.24 Å. The C(37)-O(6) bond length is 1.35 Å. In the thirty-eighth C site, C(38) is bonded in a trigonal planar geometry to one C(27), one C(39), and one C(43) atom. The C(38)-C(39) bond length is 1.37 Å. The C(38)-C(43) bond length is 1.40 Å. In the thirty-ninth C site, C(39) is bonded in a distorted single-bond geometry to one C(38) and one H(27) atom. The C(39)-H(27) bond length is 0.93 Å. In the fortieth C site, C(40) is bonded in a distorted single-bond geometry to one C(41) and one H(28) atom. The C(40)-C(41) bond length is 1.33 Å. The C(40)-H(28) bond length is 0.93 Å. In the forty-first C site, C(41) is bonded in a trigonal planar geometry to one C(40), one C(42), and one C(44) atom. The C(41)-C(42) bond length is 1.38 Å. The C(41)-C(44) bond length is 1.55 Å. In the forty-second C site, C(42) is bonded in a distorted single-bond geometry to one C(41) and one H(29) atom. The C(42)-H(29) bond length is 0.93 Å. In the forty-third C site, C(43) is bonded in a distorted single-bond geometry to one C(38) and one H(30) atom. The C(43)-H(30) bond length is 0.93 Å. In the forty-fourth C site, C(44) is bonded in a bent 120 degrees geometry to one C(41), one O(7), and one O(8) atom. The C(44)-O(7) bond length is 1.30 Å. The C(44)-O(8) bond length is 1.21 Å. There are twenty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6,8) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(17,18) is bonded in a single-bond geometry to one C(29) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the eighteenth H site, H(20,21) is bonded in a single-bond geometry to one C(30) atom. In the nineteenth H site, H(22) is bonded in a single-bond geometry to one C(30) atom. In the twentieth H site, H(23) is bonded in a single-bond geometry to one C(32) atom. In the twenty-first H site, H(24) is bonded in a single-bond geometry to one C(33) atom. In the twenty-second H site, H(25) is bonded in a single-bond geometry to one C(35) atom. In the twenty-third H site, H(26) is bonded in a single-bond geometry to one C(36) atom. In the twenty-fourth H site, H(27) is bonded in a single-bond geometry to one C(39) atom. In the twenty-fifth H site, H(28) is bonded in a single-bond geometry to one C(40) atom. In the twenty-sixth H site, H(29) is bonded in a single-bond geometry to one C(42) atom. In the twenty-seventh H site, H(30) is bonded in a single-bond geometry to one C(43) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(22) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(22) atom. In the fifth O site, O(5) is bonded in a distorted L-shaped geometry to one Cu(1) and one C(37) atom. In the sixth O site, O(6) is bonded in an L-shaped geometry to one Cu(1) and one C(37) atom. In the seventh O site, O(7) is bonded in an L-shaped geometry to one Cu(1) and one C(44) atom. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one Cu(1) and one C(44) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one C(24) and one C(30) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one C(28) and one C(29) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one C(11) and one C(15) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one C(13) and one C(14) atom. Linkers: 2 COc1c(-c2ccc(C([O])=O)cc2)cc(-c2ccc(C([O])=O)cc2)c(OC)c1-c1c(OC)c(-c2ccc(C([O])=O)cc2)cc(-c2ccc(C([O])=O)cc2)c1OC. Metal clusters: 2 O=[C]O[Cu]12(O[C]=O)(O[C]O1)O[C]O2. RCSR code: dia. The MOF has largest included sphere 9.35 A, density 0.70 g/cm3, surface area 4963.28 m2/g, accessible volume 1.02 cm3/g