Ag7C18N4H10(O2F)3 crystallizes in the monoclinic P2_1/c space group. There are seven inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal planar geometry to one C(7), one C(8), and one O(1) atom. The Ag(1)-C(7) bond length is 2.41 Å. The Ag(1)-C(8) bond length is 2.45 Å. The Ag(1)-O(1) bond length is 2.33 Å. In the second Ag site, Ag(2) is bonded in a distorted trigonal planar geometry to one C(8), one O(2), and one O(3) atom. The Ag(2)-C(8) bond length is 2.40 Å. The Ag(2)-O(2) bond length is 2.41 Å. The Ag(2)-O(3) bond length is 2.25 Å. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one C(7), one N(4), and one O(6) atom. The Ag(3)-C(7) bond length is 2.31 Å. The Ag(3)-N(4) bond length is 2.42 Å. The Ag(3)-O(6) bond length is 2.28 Å. In the fourth Ag site, Ag(4) is bonded in a distorted bent 120 degrees geometry to one C(7) and one C(8) atom. The Ag(4)-C(7) bond length is 2.22 Å. The Ag(4)-C(8) bond length is 2.49 Å. In the fifth Ag site, Ag(5) is bonded in a distorted rectangular see-saw-like geometry to one C(6), one C(7), one N(3), and one O(1) atom. The Ag(5)-C(6) bond length is 2.43 Å. The Ag(5)-C(7) bond length is 2.29 Å. The Ag(5)-N(3) bond length is 2.22 Å. The Ag(5)-O(1) bond length is 2.51 Å. In the sixth Ag site, Ag(6) is bonded in a distorted bent 150 degrees geometry to one C(7), one C(8), and one O(5) atom. The Ag(6)-C(7) bond length is 2.70 Å. The Ag(6)-C(8) bond length is 2.14 Å. The Ag(6)-O(5) bond length is 2.16 Å. In the seventh Ag site, Ag(7) is bonded in a 6-coordinate geometry to one C(15), one C(8), one N(1), one N(2), one O(3), and one O(4) atom. The Ag(7)-C(15) bond length is 2.54 Å. The Ag(7)-C(8) bond length is 2.45 Å. The Ag(7)-N(1) bond length is 2.35 Å. The Ag(7)-N(2) bond length is 2.40 Å. The Ag(7)-O(3) bond length is 2.45 Å. The Ag(7)-O(4) bond length is 2.48 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(18), one C(2), and one N(2) atom. The C(1)-C(18) bond length is 1.39 Å. The C(1)-C(2) bond length is 1.49 Å. The C(1)-N(2) bond length is 1.34 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(3), and one O(4) atom. The C(2)-O(3) bond length is 1.26 Å. The C(2)-O(4) bond length is 1.23 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(3), and one H(8) atom. The C(3)-C(5) bond length is 1.38 Å. The C(3)-N(3) bond length is 1.33 Å. The C(3)-H(8) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted trigonal non-coplanar geometry to one C(12), one F(1), one F(2), and one F(3) atom. The C(4)-C(12) bond length is 1.52 Å. The C(4)-F(1) bond length is 1.30 Å. The C(4)-F(2) bond length is 1.23 Å. The C(4)-F(3) bond length is 1.21 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(10), one C(3), and one N(4) atom. The C(5)-C(10) bond length is 1.50 Å. The C(5)-N(4) bond length is 1.34 Å. In the sixth C site, C(6) is bonded in a 3-coordinate geometry to one Ag(5), one C(11), and one C(7) atom. The C(6)-C(11) bond length is 1.45 Å. The C(6)-C(7) bond length is 1.23 Å. In the seventh C site, C(7) is bonded in a 6-coordinate geometry to one Ag(1), one Ag(3), one Ag(4), one Ag(5), one Ag(6), and one C(6) atom. In the eighth C site, C(8) is bonded in a 6-coordinate geometry to one Ag(1), one Ag(2), one Ag(4), one Ag(6), one Ag(7), and one C(15) atom. The C(8)-C(15) bond length is 1.20 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(1) atom. The C(9)-N(4) bond length is 1.33 Å. The C(9)-H(1) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(6) atom. The C(10)-O(1) bond length is 1.25 Å. The C(10)-O(6) bond length is 1.23 Å. In the eleventh C site, C(11) is bonded in a water-like geometry to one C(6) and two equivalent H(3,9) atoms. Both C(11)-H(3,9) bond lengths are 0.97 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(4), one O(2), and one O(5) atom. The C(12)-O(2) bond length is 1.20 Å. The C(12)-O(5) bond length is 1.26 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(1), and one H(5) atom. The C(13)-C(14) bond length is 1.37 Å. The C(13)-N(1) bond length is 1.34 Å. The C(13)-H(5) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(2), and one H(2) atom. The C(14)-N(2) bond length is 1.33 Å. The C(14)-H(2) bond length is 0.93 Å. In the fifteenth C site, C(15) is bonded in a 3-coordinate geometry to one Ag(7), one C(17), and one C(8) atom. The C(15)-C(17) bond length is 1.48 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(6) atom. The C(16)-N(3) bond length is 1.34 Å. The C(16)-H(6) bond length is 0.93 Å. In the seventeenth C site, C(17) is bonded in a water-like geometry to one C(15) and two equivalent H(4,7) atoms. Both C(17)-H(4,7) bond lengths are 0.97 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one H(10) atom. The C(18)-N(1) bond length is 1.31 Å. The C(18)-H(10) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(7), one C(13), and one C(18) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(7), one C(1), and one C(14) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(5), one C(16), and one C(3) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(3), one C(5), and one C(9) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(3,9) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(4,7) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Ag(1), one Ag(5), and one C(10) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ag(2) and one C(12) atom. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to one Ag(2), one Ag(7), and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(7) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Ag(6) and one C(12) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ag(3) and one C(10) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(4) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(4) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(4) atom. Linkers: 7 [O]C(=O)c1cnccn1. Metal clusters: 28 [Ag]. The MOF has largest included sphere 4.94 A, density 2.53 g/cm3, surface area 2058.42 m2/g, accessible volume 0.15 cm3/g