(YC14H7(NO3)2)2(CH)2(C4H2O)3 is Indium-derived structured and crystallizes in the tetragonal I-42d space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, twenty-four furan molecules, and eight YC14H7(NO3)2 clusters. In each YC14H7(NO3)2 cluster, Y(1) is bonded in a 8-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(4), one O(5), one O(6), and one O(7) atom. The Y(1)-N(1) bond length is 2.52 Å. The Y(1)-N(2) bond length is 2.53 Å. The Y(1)-O(1) bond length is 2.35 Å. The Y(1)-O(2) bond length is 2.25 Å. The Y(1)-O(4) bond length is 2.51 Å. The Y(1)-O(5) bond length is 2.33 Å. The Y(1)-O(6) bond length is 2.35 Å. The Y(1)-O(7) bond length is 2.25 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(6)-O(4) bond length is 1.25 Å. The C(6)-O(5) bond length is 1.26 Å. In the third C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(7)-O(6) bond length is 1.25 Å. The C(7)-O(7) bond length is 1.26 Å. In the fourth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(1), and one H(4) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-N(1) bond length is 1.31 Å. The C(10)-H(4) bond length is 0.95 Å. In the fifth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(5) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-H(5) bond length is 0.95 Å. In the sixth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(6) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-H(6) bond length is 0.95 Å. In the seventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(21) atom. The C(13)-C(14) bond length is 1.44 Å. The C(13)-C(21) bond length is 1.40 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(7) atom. The C(14)-H(7) bond length is 0.95 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(8) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(8) bond length is 0.95 Å. In the tenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(20) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(20) bond length is 1.42 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(9) atom. The C(17)-H(9) bond length is 0.95 Å. In the twelfth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(11) atom. The C(19)-N(2) bond length is 1.33 Å. The C(19)-H(11) bond length is 0.95 Å. In the thirteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(16), one C(21), and one N(2) atom. The C(20)-C(21) bond length is 1.43 Å. The C(20)-N(2) bond length is 1.35 Å. In the fourteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(13), one C(20), and one N(1) atom. The C(21)-N(1) bond length is 1.36 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Y(1), one C(10), and one C(21) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Y(1), one C(19), and one C(20) atom. There are seven inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Y(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one C(1) atom. In the third O site, O(4) is bonded in a distorted single-bond geometry to one Y(1) and one C(6) atom. In the fourth O site, O(5) is bonded in a distorted L-shaped geometry to one Y(1) and one C(6) atom. In the fifth O site, O(6) is bonded in a 2-coordinate geometry to one Y(1) and one C(7) atom. In the sixth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Y(1) and one C(7) atom. Linkers: 24 [O]C(=O)c1ccc(C([O])=O)o1. Metal clusters: 8 [C]1O[Y]234(O1)O[C]O[Y]1(O[C]O1)(O[C]O2)(O[C]O3)O[C]O4. RCSR code: sne. The MOF has largest included sphere 5.44 A, density 1.51 g/cm3, surface area 3856.21 m2/g, accessible volume 0.19 cm3/g