CdC20H14(NO2)2(C10NH4O2)2 is Indium-derived structured and crystallizes in the orthorhombic Cmce space group. The structure is zero-dimensional and consists of eight C10NH4O2 clusters and four CdC20H14(NO2)2 clusters. In each C10NH4O2 cluster, there are ten inequivalent C sites. In the first C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(8) atom. The C(9)-C(10) bond length is 1.36 Å. The C(9)-C(11) bond length is 1.41 Å. The C(9)-C(8) bond length is 1.46 Å. In the second C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(7) atom. The C(10)-H(7) bond length is 0.95 Å. In the third C site, C(11) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(11)-C(11) bond length is 1.40 Å. The C(11)-C(12) bond length is 1.42 Å. In the fourth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-C(14) bond length is 1.47 Å. In the fifth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(8) atom. The C(13)-H(8) bond length is 1.08 Å. In the sixth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(2), and one O(2) atom. The C(14)-N(2) bond length is 1.41 Å. The C(14)-O(2) bond length is 1.21 Å. In the seventh C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(4) bond length is 0.93 Å. In the eighth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(2) atom. The C(5)-C(6) bond length is 1.36 Å. The C(5)-N(2) bond length is 1.44 Å. In the ninth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(5) atom. The C(6)-H(5) bond length is 0.93 Å. In the tenth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one O(1) atom. The C(8)-N(2) bond length is 1.42 Å. The C(8)-O(1) bond length is 1.21 Å. N(2) is bonded in a trigonal planar geometry to one C(14), one C(5), and one C(8) atom. There are four inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one C(14) atom. In the second O site, O(1) is bonded in a single-bond geometry to one C(8) atom. In each CdC20H14(NO2)2 cluster, Cd(1) is bonded to two equivalent N(1), one O(3), one O(5), one O(6), and two equivalent O(4) atoms to form edge-sharing CdN2O5 pentagonal bipyramids. Both Cd(1)-N(1) bond lengths are 2.35 Å. The Cd(1)-O(3) bond length is 2.33 Å. The Cd(1)-O(5) bond length is 2.48 Å. The Cd(1)-O(6) bond length is 2.29 Å. There is one shorter (2.36 Å) and one longer (2.46 Å) Cd(1)-O(4) bond length. There are sixteen inequivalent C sites. In the first C site, C(15) is bonded in a bent 120 degrees geometry to one C(16), one O(5), and one O(6) atom. The C(15)-C(16) bond length is 1.50 Å. The C(15)-O(5) bond length is 1.24 Å. The C(15)-O(6) bond length is 1.25 Å. In the second C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(20) atom. The C(16)-C(17) bond length is 1.36 Å. The C(16)-C(20) bond length is 1.39 Å. In the third C site, C(17) is bonded in a single-bond geometry to one C(16) and one H(9) atom. The C(17)-H(9) bond length is 0.93 Å. In the fourth C site, C(20) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(20)-H(12) bond length is 0.93 Å. In the fifth C site, C(18) is bonded in a distorted single-bond geometry to one C(21) and one H(10) atom. The C(18)-C(21) bond length is 1.39 Å. The C(18)-H(10) bond length is 0.93 Å. In the sixth C site, C(19) is bonded in a single-bond geometry to one C(21) and one H(11) atom. The C(19)-C(21) bond length is 1.38 Å. The C(19)-H(11) bond length is 0.93 Å. In the seventh C site, C(21) is bonded in a trigonal planar geometry to one C(18), one C(19), and one C(22) atom. The C(21)-C(22) bond length is 1.47 Å. In the eighth C site, C(22) is bonded in a 4-coordinate geometry to one C(21), one C(23), and two equivalent C(2) atoms. The C(22)-C(23) bond length is 1.26 Å. Both C(22)-C(2) bond lengths are 1.52 Å. In the ninth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one H(13) atom. The C(23)-C(24) bond length is 1.41 Å. The C(23)-H(13) bond length is 0.93 Å. In the tenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(14) atom. The C(24)-C(25) bond length is 1.29 Å. The C(24)-H(14) bond length is 0.93 Å. In the eleventh C site, C(25) is bonded in a distorted tetrahedral geometry to one C(24), one C(26), and two equivalent C(1) atoms. The C(25)-C(26) bond length is 1.49 Å. Both C(25)-C(1) bond lengths are 1.50 Å. In the twelfth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(3), and one O(4) atom. The C(26)-O(3) bond length is 1.22 Å. The C(26)-O(4) bond length is 1.22 Å. In the thirteenth C site, C(1) is bonded in a distorted single-bond geometry to one C(25) and one H(1) atom. The C(1)-H(1) bond length is 0.96 Å. In the fourteenth C site, C(2) is bonded in a distorted single-bond geometry to one C(22) and one H(2) atom. The C(2)-H(2) bond length is 0.96 Å. In the fifteenth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(3)-N(1) bond length is 1.33 Å. The C(3)-H(3) bond length is 0.93 Å. In the sixteenth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(7)-N(1) bond length is 1.32 Å. The C(7)-H(6) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(3), and one C(7) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted water-like geometry to one Cd(1) and one C(26) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(26) atom. In the third O site, O(5) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(15) atom. In the fourth O site, O(6) is bonded in an L-shaped geometry to one Cd(1) and one C(15) atom. Linkers: 8 [O]C(=O)c1ccc([C@]23C=C[C@@]4(C([O])=O)[C@@H]5[C@H]4[C@H]2[C@@H]53)cc1 ,4 O=C1c2ccc3c4c(ccc(c24)C(=O)N1c1ccncc1)C(=O)N(c1ccncc1)C3=O. Metal clusters: 4 [C]1O[Cd]2(O1)O[C]O[Cd]1(O[C]O1)O[C]O2. RCSR code: sql. The MOF has largest included sphere 6.86 A, density 1.13 g/cm3, surface area 4169.39 m2/g, accessible volume 0.49 cm3/g