Co3C24H16S(NO3)4(CH)8(C4NH3)4(C2O)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, eight dimethyl ether molecules, eight C4NH3 clusters, and four Co3C24H16S(NO3)4 clusters. In each C4NH3 cluster, there are eight inequivalent C sites. In the first C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(10,11) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(10,11) bond length is 0.93 Å. In the second C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-C(20) bond length is 1.46 Å. In the third C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(10,11) atom. The C(18)-H(10,11) bond length is 0.93 Å. In the fourth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(2), and one H(13) atom. The C(20)-N(2) bond length is 1.27 Å. The C(20)-H(13) bond length is 0.93 Å. In the fifth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(3), and one H(14) atom. The C(21)-C(22) bond length is 1.48 Å. The C(21)-N(3) bond length is 1.26 Å. The C(21)-H(14) bond length is 0.93 Å. In the sixth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(24) atom. The C(22)-C(23) bond length is 1.37 Å. The C(22)-C(24) bond length is 1.36 Å. In the seventh C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(15) atom. The C(23)-H(15) bond length is 0.93 Å. In the eighth C site, C(24) is bonded in a distorted single-bond geometry to one C(22) and one H(16) atom. The C(24)-H(16) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a distorted water-like geometry to one C(20) and one N(3) atom. The N(2)-N(3) bond length is 1.41 Å. In the second N site, N(3) is bonded in a distorted bent 120 degrees geometry to one C(21) and one N(2) atom. There are five inequivalent H sites. In the first H site, H(10,11) is bonded in a single-bond geometry to one C(16) atom. In the second H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the third H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In each Co3C24H16S(NO3)4 cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a rectangular see-saw-like geometry to one N(1), one O(1), one O(4), and one O(7) atom. The Co(1)-N(1) bond length is 2.15 Å. The Co(1)-O(1) bond length is 2.06 Å. The Co(1)-O(4) bond length is 2.13 Å. The Co(1)-O(7) bond length is 2.07 Å. In the second Co site, Co(2) is bonded to two equivalent N(4), two equivalent O(4), and two equivalent O(6) atoms to form CoN2O4 octahedra that share  an edgeedge with one S(1)O4 tetrahedra. Both Co(2)-N(4) bond lengths are 2.18 Å. Both Co(2)-O(4) bond lengths are 2.20 Å. Both Co(2)-O(6) bond lengths are 2.00 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(6), and one O(7) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(6) bond length is 1.26 Å. The C(1)-O(7) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(6) bond length is 1.36 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the fifth C site, C(10) is bonded in a single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(6) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-C(14) bond length is 1.50 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 0.93 Å. In the eighth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(1), and one O(2) atom. The C(14)-O(1) bond length is 1.25 Å. The C(14)-O(2) bond length is 1.25 Å. In the ninth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(15)-N(1) bond length is 1.35 Å. The C(15)-H(9) bond length is 0.93 Å. In the tenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(12) atom. The C(19)-N(1) bond length is 1.33 Å. The C(19)-H(12) bond length is 0.93 Å. In the eleventh C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(17) atom. The C(25)-N(4) bond length is 1.33 Å. The C(25)-H(17) bond length is 0.93 Å. In the twelfth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(18) atom. The C(26)-N(4) bond length is 1.32 Å. The C(26)-H(18) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(15), and one C(19) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Co(2), one C(25), and one C(26) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. S(1) is bonded to two equivalent O(4) and two equivalent O(5) atoms to form SO4 tetrahedra that share  an edgeedge with one Co(2)N2O4 octahedra. Both S(1)-O(4) bond lengths are 1.51 Å. Both S(1)-O(5) bond lengths are 1.44 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(14) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(14) atom. In the third O site, O(4) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(2), and one S(1) atom. In the fourth O site, O(6) is bonded in a bent 150 degrees geometry to one Co(2) and one C(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(1) atom. Linkers: 4 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,4 [CH]([N][N][CH]c1ccncc1)c1ccncc1. Metal clusters: 2 [O]S1([O])O[Co](O[C]=O)O[C]O[Co]O[C]O[Co](O[C]=O)O1. The MOF has largest included sphere 5.21 A, density 1.39 g/cm3, surface area 4601.19 m2/g, accessible volume 0.25 cm3/g