CoCdC14H6(NO)5(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a CoCdC14H6(NO)5 framework. In the CoCdC14H6(NO)5 framework, Co(1) is bonded to one N(2), one N(4), one N(5), and two equivalent O(5) atoms to form corner-sharing CoN3O2 square pyramids. The Co(1)-N(2) bond length is 2.14 Å. The Co(1)-N(4) bond length is 2.15 Å. The Co(1)-N(5) bond length is 2.15 Å. There is one shorter (2.07 Å) and one longer (2.08 Å) Co(1)-O(5) bond length. Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(3), one O(1), one O(2), one O(4), and one O(5) atom. The Cd(1)-N(1) bond length is 2.41 Å. The Cd(1)-N(3) bond length is 2.41 Å. The Cd(1)-O(1) bond length is 2.37 Å. The Cd(1)-O(2) bond length is 2.34 Å. The Cd(1)-O(4) bond length is 2.24 Å. The Cd(1)-O(5) bond length is 2.33 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one N(3) atom. The C(1)-C(6) bond length is 1.47 Å. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(3) bond length is 1.34 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(5), one C(6), and one H(1) atom. The C(2)-C(5) bond length is 1.38 Å. The C(2)-C(6) bond length is 1.39 Å. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(4) atom. The C(3)-C(14) bond length is 1.51 Å. The C(3)-C(16) bond length is 1.38 Å. The C(3)-C(4) bond length is 1.38 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(10), one C(3), and one H(2) atom. The C(4)-C(10) bond length is 1.39 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(7), and one C(8) atom. The C(5)-C(7) bond length is 1.50 Å. The C(5)-C(8) bond length is 1.39 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(2) atom. The C(6)-C(11) bond length is 1.39 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.26 Å. The C(7)-O(2) bond length is 1.25 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(8)-H(3) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(4) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-H(4) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(13), one C(4), and one C(9) atom. The C(10)-C(13) bond length is 1.44 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(11)-H(5) bond length is 0.93 Å. In the twelfth C site, C(13) is bonded in a distorted linear geometry to one C(10) and one N(5) atom. The C(13)-N(5) bond length is 1.14 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.26 Å. The C(14)-O(4) bond length is 1.25 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(3) and one H(8) atom. The C(16)-H(8) bond length is 0.93 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Cd(1), one C(1), and one N(4) atom. The N(1)-N(4) bond length is 1.35 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one N(3), and one N(4) atom. The N(2)-N(3) bond length is 1.34 Å. The N(2)-N(4) bond length is 1.30 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Cd(1), one C(1), and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Co(1), one N(1), and one N(2) atom. In the fifth N site, N(5) is bonded in a linear geometry to one Co(1) and one C(13) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. There are five inequivalent O sites. In the first O site, O(5) is bonded in a trigonal planar geometry to two equivalent Co(1) and one Cd(1) atom. In the second O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(7) atom. In the third O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(7) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one C(14) atom. In the fifth O site, O(4) is bonded in a water-like geometry to one Cd(1) and one C(14) atom. Linkers: 4 [O]C(=O)c1cccc(C2=NN=N[N]2)c1. Metal clusters: 4 [Cd] ,4 [Co]. The MOF has largest included sphere 4.08 A, density 1.73 g/cm3, surface area 3514.76 m2/g, accessible volume 0.19 cm3/g