FeC8H10(N2S)2(CH)8C9H8O4 is Indium-derived structured and crystallizes in the tetragonal P4_2/n space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules; four 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and four FeC8H10(N2S)2 clusters. In each FeC8H10(N2S)2 cluster, Fe(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(2), and two equivalent S(1) atoms. Both Fe(1)-N(1) bond lengths are 2.25 Å. Both Fe(1)-N(2) bond lengths are 2.27 Å. Both Fe(1)-S(1) bond lengths are 2.45 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.93 Å. In the third C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(8)-N(2) bond length is 1.31 Å. The C(8)-H(9) bond length is 0.93 Å. In the fourth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(12)-N(2) bond length is 1.31 Å. The C(12)-H(12) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Fe(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Fe(1), one C(12), and one C(8) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one S(1) atom. The H(13)-S(1) bond length is 1.20 Å. S(1) is bonded in a distorted single-bond geometry to one Fe(1) and one H(13) atom. Linkers: 4 c1cc(OCC(COc2ccncc2)(COc2ccncc2)COc2ccncc2)ccn1. Metal clusters: 4 S[Fe]S. The MOF has largest included sphere 7.25 A, density 1.03 g/cm3, surface area 4718.12 m2/g, accessible volume 0.39 cm3/g