CdH24(C6N)4(CH)4(CF)8 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, sixteen fluoromethane molecules, and two CdH24(C6N)4 clusters. In each CdH24(C6N)4 cluster, Cd(1,2) is bonded in a rectangular see-saw-like geometry to one N(1); one N(2,6); one N(3,7); and one N(8) atom. The Cd(1,2)-N(1) bond length is 2.40 Å. The Cd(1,2)-N(2,6) bond length is 2.38 Å. The Cd(1,2)-N(3,7) bond length is 2.35 Å. The Cd(1,2)-N(8) bond length is 2.41 Å. There are twenty-four inequivalent C sites. In the first C site, C(1,37) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,17) atom. The C(1,37)-N(1) bond length is 1.32 Å. The C(1,37)-H(1,17) bond length is 1.14 Å. In the second C site, C(2,38) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(2) atom. The C(2,38)-C(4) bond length is 1.42 Å. The C(2,38)-N(1) bond length is 1.55 Å. The C(2,38)-H(2) bond length is 1.14 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(5,41) and one H(3,19) atom. The C(3)-C(5,41) bond length is 1.45 Å. The C(3)-H(3,19) bond length is 1.14 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(2,38); one C(5,41); and one H(4,20) atom. The C(4)-C(5,41) bond length is 1.45 Å. The C(4)-H(4,20) bond length is 1.14 Å. In the fifth C site, C(5,41) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(6) atom. The C(5,41)-C(6) bond length is 1.58 Å. In the sixth C site, C(6) is bonded in a distorted water-like geometry to one C(5,41); one H(33,45); and one H(34,46) atom. The C(6)-H(33,45) bond length is 1.14 Å. The C(6)-H(34,46) bond length is 1.14 Å. In the seventh C site, C(13,49) is bonded in a distorted water-like geometry to one C(14), one H(37), and one H(38) atom. The C(13,49)-C(14) bond length is 1.49 Å. The C(13,49)-H(37) bond length is 1.14 Å. The C(13,49)-H(38) bond length is 1.14 Å. In the eighth C site, C(15,51) is bonded in a distorted single-bond geometry to one C(14) and one H(5) atom. The C(15,51)-C(14) bond length is 1.42 Å. The C(15,51)-H(5) bond length is 1.14 Å. In the ninth C site, C(16,52) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one H(6) atom. The C(16,52)-C(14) bond length is 1.32 Å. The C(16,52)-C(18) bond length is 1.45 Å. The C(16,52)-H(6) bond length is 1.14 Å. In the tenth C site, C(17,53) is bonded in a distorted water-like geometry to one N(3,7) and one H(7,23) atom. The C(17,53)-N(3,7) bond length is 1.18 Å. The C(17,53)-H(7,23) bond length is 1.14 Å. In the eleventh C site, C(19,55) is bonded in a distorted bent 120 degrees geometry to one C(21,57); one N(2,6); and one H(9,25) atom. The C(19,55)-C(21,57) bond length is 1.31 Å. The C(19,55)-N(2,6) bond length is 1.34 Å. The C(19,55)-H(9,25) bond length is 1.14 Å. In the twelfth C site, C(20,56) is bonded in a distorted bent 120 degrees geometry to one N(2,6) and one H(10,26) atom. The C(20,56)-N(2,6) bond length is 1.36 Å. The C(20,56)-H(10,26) bond length is 1.14 Å. In the thirteenth C site, C(21,57) is bonded in a distorted trigonal planar geometry to one C(19,55); one C(23,59); and one H(11,27) atom. The C(21,57)-C(23,59) bond length is 1.46 Å. The C(21,57)-H(11,27) bond length is 1.14 Å. In the fourteenth C site, C(22,58) is bonded in a distorted single-bond geometry to one C(23,59) and one H(12,28) atom. The C(22,58)-C(23,59) bond length is 1.37 Å. The C(22,58)-H(12,28) bond length is 1.14 Å. In the fifteenth C site, C(23,59) is bonded in a trigonal planar geometry to one C(21,57); one C(22,58); and one C(24,60) atom. The C(23,59)-C(24,60) bond length is 1.59 Å. In the sixteenth C site, C(24,60) is bonded in a distorted water-like geometry to one C(23,59); one H(39,51); and one H(40,52) atom. The C(24,60)-H(39,51) bond length is 1.14 Å. The C(24,60)-H(40,52) bond length is 1.14 Å. In the seventeenth C site, C(32,68) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(34) atom. The C(32,68)-C(31) bond length is 1.52 Å. The C(32,68)-C(33) bond length is 1.39 Å. The C(32,68)-C(34) bond length is 1.42 Å. In the eighteenth C site, C(35,71) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(15,31) atom. The C(35,71)-N(4) bond length is 1.37 Å. The C(35,71)-H(15,31) bond length is 1.14 Å. In the nineteenth C site, C(36,72) is bonded in a distorted bent 120 degrees geometry to one C(34), one N(4), and one H(16) atom. The C(36,72)-C(34) bond length is 1.53 Å. The C(36,72)-N(4) bond length is 1.34 Å. The C(36,72)-H(16) bond length is 1.14 Å. In the twentieth C site, C(50) is bonded in a trigonal planar geometry to one C(13,49); one C(15,51); and one C(16,52) atom. The C(50)-C(13,49) bond length is 1.49 Å. The C(50)-C(15,51) bond length is 1.42 Å. The C(50)-C(16,52) bond length is 1.32 Å. In the twenty-first C site, C(54) is bonded in a distorted bent 120 degrees geometry to one C(16,52); one N(3,7); and one H(8,24) atom. The C(54)-C(16,52) bond length is 1.45 Å. The C(54)-N(3,7) bond length is 1.43 Å. The C(54)-H(8,24) bond length is 1.14 Å. In the twenty-second C site, C(67) is bonded in a distorted water-like geometry to one C(32,68); one H(43,55); and one H(44,56) atom. The C(67)-C(32,68) bond length is 1.52 Å. The C(67)-H(43,55) bond length is 1.14 Å. The C(67)-H(44,56) bond length is 1.14 Å. In the twenty-third C site, C(69) is bonded in a distorted single-bond geometry to one C(32,68) and one H(13,29) atom. The C(69)-C(32,68) bond length is 1.39 Å. The C(69)-H(13,29) bond length is 1.14 Å. In the twenty-fourth C site, C(70) is bonded in a distorted trigonal planar geometry to one C(32,68); one C(36,72); and one H(14,30) atom. The C(70)-C(32,68) bond length is 1.42 Å. The C(70)-C(36,72) bond length is 1.53 Å. The C(70)-H(14,30) bond length is 1.14 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1,2); one C(1,37); and one C(2,38) atom. In the second N site, N(2,6) is bonded in a trigonal planar geometry to one Cd(1,2); one C(19,55); and one C(20,56) atom. In the third N site, N(3,7) is bonded in a distorted trigonal planar geometry to one Cd(1,2); one C(17,53); and one C(18) atom. The N(3,7)-C(18) bond length is 1.43 Å. In the fourth N site, N(8) is bonded in a trigonal planar geometry to one Cd(1,2); one C(35,71); and one C(36,72) atom. The N(8)-C(35,71) bond length is 1.37 Å. The N(8)-C(36,72) bond length is 1.34 Å. There are twenty-four inequivalent H sites. In the first H site, H(1,17) is bonded in a single-bond geometry to one C(1,37) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2,38) atom. In the third H site, H(4,20) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(3,19) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(9,25) is bonded in a single-bond geometry to one C(19,55) atom. In the sixth H site, H(10,26) is bonded in a single-bond geometry to one C(20,56) atom. In the seventh H site, H(11,27) is bonded in a single-bond geometry to one C(21,57) atom. In the eighth H site, H(12,28) is bonded in a single-bond geometry to one C(22,58) atom. In the ninth H site, H(7,23) is bonded in a single-bond geometry to one C(17,53) atom. In the tenth H site, H(8,24) is bonded in a single-bond geometry to one C(18) atom. The H(8,24)-C(18) bond length is 1.14 Å. In the eleventh H site, H(13,29) is bonded in a single-bond geometry to one C(33) atom. The H(13,29)-C(33) bond length is 1.14 Å. In the twelfth H site, H(14,30) is bonded in a single-bond geometry to one C(34) atom. The H(14,30)-C(34) bond length is 1.14 Å. In the thirteenth H site, H(15,31) is bonded in a single-bond geometry to one C(35,71) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(15,51) atom. The H(21)-C(15,51) bond length is 1.14 Å. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(16,52) atom. The H(22)-C(16,52) bond length is 1.14 Å. In the sixteenth H site, H(32) is bonded in a single-bond geometry to one C(36,72) atom. The H(32)-C(36,72) bond length is 1.14 Å. In the seventeenth H site, H(33,45) is bonded in a single-bond geometry to one C(6) atom. In the eighteenth H site, H(34,46) is bonded in a single-bond geometry to one C(6) atom. In the nineteenth H site, H(39,51) is bonded in a single-bond geometry to one C(24,60) atom. In the twentieth H site, H(40,52) is bonded in a single-bond geometry to one C(24,60) atom. In the twenty-first H site, H(43,55) is bonded in a single-bond geometry to one C(31) atom. The H(43,55)-C(31) bond length is 1.14 Å. In the twenty-second H site, H(44,56) is bonded in a single-bond geometry to one C(31) atom. The H(44,56)-C(31) bond length is 1.14 Å. In the twenty-third H site, H(49) is bonded in a single-bond geometry to one C(13,49) atom. The H(49)-C(13,49) bond length is 1.14 Å. In the twenty-fourth H site, H(50) is bonded in a single-bond geometry to one C(13,49) atom. The H(50)-C(13,49) bond length is 1.14 Å. Linkers: 4 FC1=C(F)[C@H](Cc2ccncc2)C(F)=C(F)[C@@H]1Cc1ccncc1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 5.06 A, density 1.05 g/cm3, surface area 4890.97 m2/g, accessible volume 0.47 cm3/g