CoH22(C7N3)4(CH)8 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and two CoH22(C7N3)4 clusters. In each CoH22(C7N3)4 cluster, Co(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(3), and two equivalent N(5) atoms. Both Co(1)-N(1) bond lengths are 2.15 Å. Both Co(1)-N(3) bond lengths are 2.19 Å. Both Co(1)-N(5) bond lengths are 2.15 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.31 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.35 Å. The C(2)-N(1) bond length is 1.39 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.37 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one N(2) atom. The C(4)-N(2) bond length is 1.43 Å. In the fifth C site, C(8) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(7) atom. The C(8)-N(3) bond length is 1.32 Å. The C(8)-N(4) bond length is 1.36 Å. The C(8)-H(7) bond length is 0.93 Å. In the sixth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(3), and one H(8) atom. The C(9)-C(10) bond length is 1.35 Å. The C(9)-N(3) bond length is 1.38 Å. The C(9)-H(8) bond length is 0.93 Å. In the seventh C site, C(10) is bonded in a 3-coordinate geometry to one C(9), one N(4), and one H(9) atom. The C(10)-N(4) bond length is 1.38 Å. The C(10)-H(9) bond length is 0.93 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(13), and one N(4) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(13) bond length is 1.39 Å. The C(11)-N(4) bond length is 1.44 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(10) atom. The C(12)-H(10) bond length is 0.93 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(11) and one H(11) atom. The C(13)-H(11) bond length is 0.93 Å. In the eleventh C site, C(14) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(12) atom. The C(14)-N(5) bond length is 1.32 Å. The C(14)-N(6) bond length is 1.35 Å. The C(14)-H(12) bond length is 0.93 Å. In the twelfth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(5), and one H(13) atom. The C(15)-C(16) bond length is 1.35 Å. The C(15)-N(5) bond length is 1.38 Å. The C(15)-H(13) bond length is 0.93 Å. In the thirteenth C site, C(16) is bonded in a 3-coordinate geometry to one C(15), one N(6), and one H(14) atom. The C(16)-N(6) bond length is 1.38 Å. The C(16)-H(14) bond length is 0.93 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one N(6) atom. The C(17)-N(6) bond length is 1.43 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Co(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Co(1), one C(8), and one C(9) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(8) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Co(1), one C(14), and one C(15) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(17) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. Linkers: 6 c1cn(-c2ccc(-n3ccnc3)cc2)cn1. Metal clusters: 2 [Co]. The MOF has largest included sphere 5.05 A, density 1.02 g/cm3, surface area 5095.19 m2/g, accessible volume 0.45 cm3/g