Cu3C24H16(N10Cl)2 is Protactinium structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of two Cu3C24H16(N10Cl)2 clusters. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to four equivalent N(1) and two equivalent Cl(1) atoms to form distorted corner-sharing CuN4Cl2 octahedra. All Cu(1)-N(1) bond lengths are 2.02 Å. Both Cu(1)-Cl(1) bond lengths are 2.73 Å. In the second Cu site, Cu(2) is bonded to two equivalent N(2), two equivalent N(5), and one Cl(1) atom to form distorted corner-sharing CuN4Cl square pyramids. The corner-sharing octahedral tilt angles are 96°. Both Cu(2)-N(2) bond lengths are 2.02 Å. Both Cu(2)-N(5) bond lengths are 2.02 Å. The Cu(2)-Cl(1) bond length is 2.54 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(3), and one N(4) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-N(3) bond length is 1.33 Å. The C(1)-N(4) bond length is 1.33 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(6) bond length is 1.34 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the fifth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(2) atom. The C(4)-N(5) bond length is 1.30 Å. The C(4)-H(2) bond length is 0.93 Å. In the sixth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(3) atom. The C(5)-N(5) bond length is 1.31 Å. The C(5)-H(3) bond length is 0.93 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one N(2), and one N(4) atom. The N(1)-N(2) bond length is 1.32 Å. The N(1)-N(4) bond length is 1.33 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(2), one N(1), and one N(3) atom. The N(2)-N(3) bond length is 1.32 Å. In the third N site, N(3) is bonded in a water-like geometry to one C(1) and one N(2) atom. In the fourth N site, N(4) is bonded in a water-like geometry to one C(1) and one N(1) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(2), one C(4), and one C(5) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. Cl(1) is bonded in an L-shaped geometry to one Cu(1) and one Cu(2) atom. Linkers: 8 c1cc(C2=NN=N[N]2)ccn1. Metal clusters: 2 Cl[Cu]1[N]N=[Cu]2(N=N1)N=N[Cu](Cl)N=N2. The MOF has largest included sphere 7.28 A, density 0.94 g/cm3, surface area 3924.28 m2/g, accessible volume 0.62 cm3/g