Cd2OCdC10H2(NO2)4(CH)2 crystallizes in the cubic Im-3m space group. The structure consists of twenty-four 02329_fluka molecules and twelve Cd2O clusters inside a CdC10H2(NO2)4 framework. In each Cd2O cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(2) is bonded in a distorted single-bond geometry to one Cd(3) atom. The Cd(2)-Cd(3) bond length is 0.78 Å. In the second Cd site, Cd(3) is bonded in a distorted linear geometry to one Cd(2) and one O(1) atom. The Cd(3)-O(1) bond length is 1.47 Å. O(1) is bonded in a single-bond geometry to one Cd(3) atom. In the CdC10H2(NO2)4 framework, Cd(1) is bonded in a 8-coordinate geometry to four equivalent N(1) and four equivalent O(2) atoms. All Cd(1)-N(1) bond lengths are 2.41 Å. All Cd(1)-O(2) bond lengths are 2.43 Å. There are three inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to two equivalent N(1) and one H(1) atom. Both C(3)-N(1) bond lengths are 1.33 Å. The C(3)-H(1) bond length is 0.93 Å. In the second C site, C(1) is bonded in a distorted single-bond geometry to one N(1) atom. The C(1)-N(1) bond length is 1.32 Å. In the third C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(2)-O(2) bond length is 1.24 Å. The C(2)-O(3) bond length is 1.25 Å. N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(3) atom. H(1) is bonded in a single-bond geometry to one C(3) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(2) atom. In the second O site, O(3) is bonded in a distorted single-bond geometry to one C(2) atom. Linkers: 24 [O]C(=O)c1cc(C([O])=O)ncn1. Metal clusters: 36 [Cd]. The MOF has largest included sphere 8.55 A, density 2.06 g/cm3, surface area 2179.83 m2/g, accessible volume 0.20 cm3/g