Zn4C54H72O13 crystallizes in the cubic P-43m space group. Zn(1) is bonded to one O(2) and three equivalent O(1) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(2) bond length is 1.95 Å. All Zn(1)-O(1) bond lengths are 1.94 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(5), and one H(3) atom. The C(1)-C(2) bond length is 1.43 Å. The C(1)-C(5) bond length is 1.40 Å. The C(1)-H(3) bond length is 1.08 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.45 Å. The C(2)-C(6) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one C(2), one H(4), two equivalent H(1), and two equivalent H(2) atoms. The C(3)-H(4) bond length is 0.94 Å. Both C(3)-H(1) bond lengths are 0.99 Å. Both C(3)-H(2) bond lengths are 1.12 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5) and two equivalent O(1) atoms. The C(4)-C(5) bond length is 1.42 Å. Both C(4)-O(1) bond lengths are 1.30 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4) and two equivalent C(1) atoms. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(6) and two equivalent C(2) atoms. The C(6)-C(6) bond length is 1.50 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) and one H(2) atom. The H(1)-H(2) bond length is 0.77 Å. In the second H site, H(2) is bonded in a 3-coordinate geometry to one C(3), one H(1), and one H(2) atom. The H(2)-H(2) bond length is 0.39 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the second O site, O(2) is bonded in a tetrahedral geometry to four equivalent Zn(1) atoms. Linkers: 3 [CH3].[CH3].[CH3].[CH3].[H].[H].[H].[H].[H].[H].[H].[H].[O]C(=O)c1c[c]c(-c2[c]cc(C([O])=O)c[c]2)[c]c1. Metal clusters: 1 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: pcu. The MOF has largest included sphere 15.80 A, density 0.39 g/cm3, surface area 4640.38 m2/g, accessible volume 2.15 cm3/g