Zn8C24H12O19(Zn4C72H36O13)2(C2H)24(CH3CO)36 is Indium-derived structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of one hundred and eight dimethyl ether molecules, nine C2H clusters, six Zn4C72H36O13 clusters, and three Zn8C24H12O19 clusters. In each C2H cluster, there are eight inequivalent C sites. In the first C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(15), and one C(8) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(15) bond length is 1.44 Å. The C(9)-C(8) bond length is 1.42 Å. In the second C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(8), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(8) bond length is 1.42 Å. In the third C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(11)-H(5) bond length is 0.93 Å. In the fourth C site, C(15) is bonded in a distorted single-bond geometry to one C(9) and one H(9) atom. The C(15)-H(9) bond length is 0.93 Å. In the fifth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(2) bond length is 0.93 Å. In the sixth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(8) bond length is 1.48 Å. In the seventh C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(5), and one C(9) atom. There are four inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In each Zn4C72H36O13 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(3) is bonded to one O(15), one O(7), one O(8), and one O(9) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(15) bond length is 1.94 Å. The Zn(3)-O(7) bond length is 1.94 Å. The Zn(3)-O(8) bond length is 1.92 Å. The Zn(3)-O(9) bond length is 1.95 Å. In the second Zn site, Zn(4) is bonded to one O(15) and three equivalent O(10) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(4)-O(15) bond length is 1.98 Å. All Zn(4)-O(10) bond lengths are 1.85 Å. There are twenty-four inequivalent C sites. In the first C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(7), and one O(9) atom. The C(17)-C(18) bond length is 1.52 Å. The C(17)-O(7) bond length is 1.30 Å. The C(17)-O(9) bond length is 1.20 Å. In the second C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(23) atom. The C(18)-C(19) bond length is 1.38 Å. The C(18)-C(23) bond length is 1.41 Å. In the third C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(13,16) atom. The C(19)-H(13,16) bond length is 0.93 Å. In the fourth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(14) atom. The C(20)-C(21) bond length is 1.38 Å. The C(20)-H(14) bond length is 0.93 Å. In the fifth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-C(24) bond length is 1.44 Å. In the sixth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(15) atom. The C(22)-H(15) bond length is 0.93 Å. In the seventh C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(13,16) atom. The C(23)-H(13,16) bond length is 0.93 Å. In the eighth C site, C(24) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(41) atom. The C(24)-C(25) bond length is 1.48 Å. The C(24)-C(41) bond length is 1.41 Å. In the ninth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(32) atom. The C(25)-C(26) bond length is 1.41 Å. The C(25)-C(32) bond length is 1.41 Å. In the tenth C site, C(26) is bonded in a single-bond geometry to one C(25) and one H(17) atom. The C(26)-H(17) bond length is 0.93 Å. In the eleventh C site, C(31) is bonded in a single-bond geometry to one C(32) and one H(24) atom. The C(31)-C(32) bond length is 1.37 Å. The C(31)-H(24) bond length is 0.93 Å. In the twelfth C site, C(32) is bonded in a trigonal planar geometry to one C(25), one C(31), and one C(33) atom. The C(32)-C(33) bond length is 1.45 Å. In the thirteenth C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(42) atom. The C(33)-C(34) bond length is 1.40 Å. The C(33)-C(42) bond length is 1.47 Å. In the fourteenth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(41) atom. The C(34)-C(35) bond length is 1.49 Å. The C(34)-C(41) bond length is 1.38 Å. In the fifteenth C site, C(35) is bonded in a distorted single-bond geometry to one C(34) and one H(25) atom. The C(35)-H(25) bond length is 0.93 Å. In the sixteenth C site, C(40) is bonded in a distorted single-bond geometry to one C(41) and one H(32) atom. The C(40)-C(41) bond length is 1.44 Å. The C(40)-H(32) bond length is 0.93 Å. In the seventeenth C site, C(41) is bonded in a trigonal planar geometry to one C(24), one C(34), and one C(40) atom. In the eighteenth C site, C(42) is bonded in a trigonal planar geometry to one C(33), one C(43), and one C(48) atom. The C(42)-C(43) bond length is 1.35 Å. The C(42)-C(48) bond length is 1.40 Å. In the nineteenth C site, C(43) is bonded in a distorted single-bond geometry to one C(42) and one H(33) atom. The C(43)-H(33) bond length is 0.93 Å. In the twentieth C site, C(44) is bonded in a distorted single-bond geometry to one C(45) and one H(34) atom. The C(44)-C(45) bond length is 1.39 Å. The C(44)-H(34) bond length is 0.93 Å. In the twenty-first C site, C(45) is bonded in a trigonal planar geometry to one C(44), one C(46), and one C(47) atom. The C(45)-C(46) bond length is 1.50 Å. The C(45)-C(47) bond length is 1.36 Å. In the twenty-second C site, C(46) is bonded in a distorted bent 120 degrees geometry to one C(45), one O(10), and one O(8) atom. The C(46)-O(10) bond length is 1.30 Å. The C(46)-O(8) bond length is 1.25 Å. In the twenty-third C site, C(47) is bonded in a distorted trigonal planar geometry to one C(45), one C(48), and one H(35) atom. The C(47)-C(48) bond length is 1.36 Å. The C(47)-H(35) bond length is 0.93 Å. In the twenty-fourth C site, C(48) is bonded in a distorted single-bond geometry to one C(42), one C(47), and one H(36) atom. The C(48)-H(36) bond length is 0.93 Å. There are eleven inequivalent H sites. In the first H site, H(24) is bonded in a single-bond geometry to one C(31) atom. In the second H site, H(25) is bonded in a single-bond geometry to one C(35) atom. In the third H site, H(32) is bonded in a single-bond geometry to one C(40) atom. In the fourth H site, H(33) is bonded in a single-bond geometry to one C(43) atom. In the fifth H site, H(34) is bonded in a single-bond geometry to one C(44) atom. In the sixth H site, H(35) is bonded in a single-bond geometry to one C(47) atom. In the seventh H site, H(36) is bonded in a single-bond geometry to one C(48) atom. In the eighth H site, H(13,16) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(26) atom. There are five inequivalent O sites. In the first O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(17) atom. In the second O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(46) atom. In the third O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(17) atom. In the fourth O site, O(10) is bonded in a bent 150 degrees geometry to one Zn(4) and one C(46) atom. In the fifth O site, O(15) is bonded in a tetrahedral geometry to one Zn(4) and three equivalent Zn(3) atoms. In each Zn8C24H12O19 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), and one O(6) atom to form a mixture of distorted edge and corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.93 Å. The Zn(1)-O(2) bond length is 1.95 Å. The Zn(1)-O(3) bond length is 2.13 Å. The Zn(1)-O(6) bond length is 1.94 Å. In the second Zn site, Zn(2) is bonded to one O(6) and three equivalent O(3) atoms to form a mixture of distorted edge and corner-sharing ZnO4 trigonal pyramids. The Zn(2)-O(6) bond length is 1.91 Å. All Zn(2)-O(3) bond lengths are 2.11 Å. There are four inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(1) bond length is 1.51 Å. The C(2)-C(3) bond length is 1.31 Å. The C(2)-C(7) bond length is 1.39 Å. In the second C site, C(1) is bonded in a 3-coordinate geometry to one C(2), one O(1), one O(2), and one O(3) atom. The C(1)-O(1) bond length is 1.39 Å. The C(1)-O(2) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.14 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Zn(1), one C(1), and one O(2) atom. The O(1)-O(2) bond length is 1.23 Å. In the second O site, O(3) is bonded in a distorted single-bond geometry to one Zn(1), one Zn(2), and one C(1) atom. In the third O site, O(6) is bonded in a body-centered cubic geometry to two equivalent Zn(2) and six equivalent Zn(1) atoms. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to one Zn(1), one C(1), and one O(1) atom. Linkers: 18 COc1cc2c(-c3ccc(C([O])=O)cc3)c3cc(OC)c(OC)cc3c(-c3ccc(C([O])=O)cc3)c2cc1OC ,9 COc1cc2c(-c3ccc(C4([O])OO4)cc3)c3cc(OC)c(OC)cc3c(-c3ccc(C4([O])OO4)cc3)c2cc1OC. Metal clusters: 24 [Zn] ,6 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. The MOF has largest included sphere 11.13 A, density 1.03 g/cm3, surface area 4331.62 m2/g, accessible volume 0.46 cm3/g