CdC11H6(NO)2(CH)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules and four CdC11H6(NO)2 clusters. In each CdC11H6(NO)2 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 4-coordinate geometry to one N(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.26 Å. The Cd(1)-O(2) bond length is 2.38 Å. The Cd(1)-O(3) bond length is 2.24 Å. The Cd(1)-O(4) bond length is 2.52 Å. In the second Cd site, Cd(2) is bonded in a distorted rectangular see-saw-like geometry to one N(3), one O(1), one O(2), and one O(4) atom. The Cd(2)-N(3) bond length is 2.29 Å. The Cd(2)-O(1) bond length is 2.42 Å. The Cd(2)-O(2) bond length is 2.38 Å. The Cd(2)-O(4) bond length is 2.38 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.31 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(7), and one N(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.40 Å. The C(2)-N(1) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-H(5) bond length is 0.93 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one N(2) atom. The C(7)-N(2) bond length is 1.40 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one N(2) atom. The C(8)-C(11) bond length is 1.39 Å. The C(8)-C(9) bond length is 1.38 Å. The C(8)-N(2) bond length is 1.43 Å. In the seventh C site, C(9) is bonded in a single-bond geometry to one C(8) and one H(6) atom. The C(9)-H(6) bond length is 0.93 Å. In the eighth C site, C(11) is bonded in a single-bond geometry to one C(8) and one H(8) atom. The C(11)-H(8) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(13) and one H(7) atom. The C(10)-C(13) bond length is 1.40 Å. The C(10)-H(7) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(9) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-H(9) bond length is 0.93 Å. In the eleventh C site, C(15) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(10) atom. The C(15)-N(3) bond length is 1.32 Å. The C(15)-N(4) bond length is 1.36 Å. The C(15)-H(10) bond length is 0.93 Å. In the twelfth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one C(21), and one N(3) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.39 Å. The C(16)-N(3) bond length is 1.39 Å. In the thirteenth C site, C(17) is bonded in a single-bond geometry to one C(16) and one H(11) atom. The C(17)-H(11) bond length is 0.93 Å. In the fourteenth C site, C(13) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(13)-C(14) bond length is 1.49 Å. In the fifteenth C site, C(14) is bonded in a bent 120 degrees geometry to one C(13), one O(1), and one O(2) atom. The C(14)-O(1) bond length is 1.25 Å. The C(14)-O(2) bond length is 1.28 Å. In the sixteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(14) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(14) bond length is 0.93 Å. In the seventeenth C site, C(21) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one N(4) atom. The C(21)-N(4) bond length is 1.41 Å. In the eighteenth C site, C(22) is bonded in a distorted single-bond geometry to one N(4) atom. The C(22)-N(4) bond length is 1.42 Å. In the nineteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(16) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-H(16) bond length is 0.93 Å. In the twentieth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(28) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(28) bond length is 1.50 Å. In the twenty-first C site, C(26) is bonded in a single-bond geometry to one C(25) and one H(17) atom. The C(26)-H(17) bond length is 0.93 Å. In the twenty-second C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(3), and one O(4) atom. The C(28)-O(3) bond length is 1.25 Å. The C(28)-O(4) bond length is 1.27 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(7), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(2), one C(15), and one C(16) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(15), one C(21), and one C(22) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(14) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(2), and one C(14) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cd(1) and one C(28) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(2), and one C(28) atom. Linkers: 8 [O]C(=O)c1ccc(-n2cnc3ccccc32)cc1. Metal clusters: 4 [Cd]O[C]O[Cd]1O[C]O1. The MOF has largest included sphere 6.59 A, density 1.04 g/cm3, surface area 3963.15 m2/g, accessible volume 0.61 cm3/g