ZnC24H22(NO)4 is Indium-like structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of thirty-two ZnC24H22(NO)4 clusters. In eight of the ZnC24H22(NO)4 clusters, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(2) and two equivalent O(2) atoms. Both Zn(1)-N(2) bond lengths are 2.04 Å. Both Zn(1)-O(2) bond lengths are 1.94 Å. There are twelve inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(6) and one H(3,25,27,29) atom. The C(4)-C(6) bond length is 1.39 Å. The C(4)-H(3,25,27,29) bond length is 0.93 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(9) atom. The C(1)-C(10) bond length is 1.52 Å. The C(1)-C(2) bond length is 1.38 Å. The C(1)-C(9) bond length is 1.40 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 0.93 Å. In the fourth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(11), one C(5), and one N(2) atom. The C(3)-C(11) bond length is 1.50 Å. The C(3)-C(5) bond length is 1.38 Å. The C(3)-N(2) bond length is 1.34 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(3), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.49 Å. The C(5)-C(7) bond length is 1.41 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(8)-C(6) bond length is 1.39 Å. The C(8)-H(4) bond length is 0.93 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(9)-H(5) bond length is 0.93 Å. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(10)-O(1) bond length is 1.22 Å. The C(10)-O(2) bond length is 1.27 Å. In the ninth C site, C(11) is bonded in a trigonal non-coplanar geometry to one C(3); one H(6); and two equivalent H(7,8) atoms. The C(11)-H(6) bond length is 0.96 Å. Both C(11)-H(7,8) bond lengths are 0.96 Å. In the tenth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(12), one C(5), and one N(1) atom. The C(7)-C(12) bond length is 1.49 Å. The C(7)-N(1) bond length is 1.32 Å. In the eleventh C site, C(6) is bonded in a trigonal planar geometry to one C(4), one C(5), and one C(8) atom. In the twelfth C site, C(12) is bonded in a trigonal non-coplanar geometry to one C(7), one H(10), one H(11), and one H(9) atom. The C(12)-H(10) bond length is 0.96 Å. The C(12)-H(11) bond length is 0.96 Å. The C(12)-H(9) bond length is 0.96 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a 3-coordinate geometry to one Zn(1), one C(3), and one N(1) atom. The N(2)-N(1) bond length is 1.37 Å. In the second N site, N(1) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(2), and one H(1) atom. The N(1)-H(1) bond length is 0.86 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3,25,27,29) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(7,8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(10) atom. In the second O site, O(1) is bonded in a single-bond geometry to one C(10) atom. In eight of the ZnC24H22(NO)4 clusters, Zn(2) is bonded in a tetrahedral geometry to two equivalent N(4) and two equivalent O(3) atoms. Both Zn(2)-N(4) bond lengths are 1.98 Å. Both Zn(2)-O(3) bond lengths are 1.95 Å. There are twelve inequivalent C sites. In the first C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(21), and one C(22) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-C(21) bond length is 1.39 Å. The C(13)-C(22) bond length is 1.50 Å. In the second C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(13) atom. The C(14)-H(13) bond length is 0.93 Å. In the third C site, C(15) is bonded in a distorted single-bond geometry to one C(17), one C(23), and one N(4) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-C(23) bond length is 1.50 Å. The C(15)-N(4) bond length is 1.33 Å. In the fourth C site, C(16) is bonded in a distorted single-bond geometry to one C(18) and one H(14) atom. The C(16)-C(18) bond length is 1.40 Å. The C(16)-H(14) bond length is 0.93 Å. In the fifth C site, C(17) is bonded in a trigonal planar geometry to one C(15), one C(18), and one C(19) atom. The C(17)-C(18) bond length is 1.47 Å. The C(17)-C(19) bond length is 1.41 Å. In the sixth C site, C(18) is bonded in a trigonal planar geometry to one C(16), one C(17), and one C(20) atom. The C(18)-C(20) bond length is 1.38 Å. In the seventh C site, C(19) is bonded in a distorted trigonal planar geometry to one C(17), one C(24), and one N(3) atom. The C(19)-C(24) bond length is 1.49 Å. The C(19)-N(3) bond length is 1.34 Å. In the eighth C site, C(20) is bonded in a single-bond geometry to one C(18) and one H(15) atom. The C(20)-H(15) bond length is 0.93 Å. In the ninth C site, C(21) is bonded in a distorted single-bond geometry to one C(13) and one H(16) atom. The C(21)-H(16) bond length is 0.93 Å. In the tenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(3), and one O(4) atom. The C(22)-O(3) bond length is 1.28 Å. The C(22)-O(4) bond length is 1.24 Å. In the eleventh C site, C(23) is bonded in a trigonal non-coplanar geometry to one C(15); one H(19); and two equivalent H(17,18) atoms. The C(23)-H(19) bond length is 0.96 Å. Both C(23)-H(17,18) bond lengths are 0.96 Å. In the twelfth C site, C(24) is bonded in a trigonal non-coplanar geometry to one C(19); one H(21); and two equivalent H(20,22) atoms. The C(24)-H(21) bond length is 0.96 Å. Both C(24)-H(20,22) bond lengths are 0.96 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a 3-coordinate geometry to one C(19), one N(4), and one H(12) atom. The N(3)-N(4) bond length is 1.36 Å. The N(3)-H(12) bond length is 0.86 Å. In the second N site, N(4) is bonded in a 3-coordinate geometry to one Zn(2), one C(15), and one N(3) atom. There are nine inequivalent H sites. In the first H site, H(12) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(17,18) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the eighth H site, H(20,22) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(21) is bonded in a single-bond geometry to one C(24) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(22) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(22) atom. In sixteen of the ZnC24H22(NO)4 clusters, Zn(3) is bonded in a tetrahedral geometry to one N(7), one N(8), one O(5), and one O(8) atom. The Zn(3)-N(7) bond length is 2.00 Å. The Zn(3)-N(8) bond length is 1.99 Å. The Zn(3)-O(5) bond length is 1.95 Å. The Zn(3)-O(8) bond length is 1.94 Å. There are twenty-four inequivalent C sites. In the first C site, C(25) is bonded in a trigonal planar geometry to one C(27), one C(41), and one C(43) atom. The C(25)-C(27) bond length is 1.40 Å. The C(25)-C(41) bond length is 1.39 Å. The C(25)-C(43) bond length is 1.48 Å. In the second C site, C(26) is bonded in a trigonal planar geometry to one C(28), one C(42), and one C(44) atom. The C(26)-C(28) bond length is 1.38 Å. The C(26)-C(42) bond length is 1.42 Å. The C(26)-C(44) bond length is 1.49 Å. In the third C site, C(27) is bonded in a single-bond geometry to one C(25) and one H(3,25,27,29) atom. The C(27)-H(3,25,27,29) bond length is 0.93 Å. In the fourth C site, C(28) is bonded in a distorted single-bond geometry to one C(26) and one H(26) atom. The C(28)-H(26) bond length is 0.93 Å. In the fifth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(33), one C(45), and one N(7) atom. The C(29)-C(33) bond length is 1.38 Å. The C(29)-C(45) bond length is 1.50 Å. The C(29)-N(7) bond length is 1.34 Å. In the sixth C site, C(30) is bonded in a distorted single-bond geometry to one C(34), one C(46), and one N(8) atom. The C(30)-C(34) bond length is 1.44 Å. The C(30)-C(46) bond length is 1.47 Å. The C(30)-N(8) bond length is 1.33 Å. In the seventh C site, C(31) is bonded in a distorted single-bond geometry to one C(35) and one H(3,25,27,29) atom. The C(31)-C(35) bond length is 1.40 Å. The C(31)-H(3,25,27,29) bond length is 0.93 Å. In the eighth C site, C(32) is bonded in a single-bond geometry to one C(36) and one H(28) atom. The C(32)-C(36) bond length is 1.42 Å. The C(32)-H(28) bond length is 0.93 Å. In the ninth C site, C(33) is bonded in a trigonal planar geometry to one C(29), one C(35), and one C(37) atom. The C(33)-C(35) bond length is 1.50 Å. The C(33)-C(37) bond length is 1.38 Å. In the tenth C site, C(34) is bonded in a trigonal planar geometry to one C(30), one C(36), and one C(38) atom. The C(34)-C(36) bond length is 1.44 Å. The C(34)-C(38) bond length is 1.40 Å. In the eleventh C site, C(35) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(39) atom. The C(35)-C(39) bond length is 1.39 Å. In the twelfth C site, C(36) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(40) atom. The C(36)-C(40) bond length is 1.39 Å. In the thirteenth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(33), one C(47), and one N(5) atom. The C(37)-C(47) bond length is 1.51 Å. The C(37)-N(5) bond length is 1.33 Å. In the fourteenth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(34), one C(48), and one N(6) atom. The C(38)-C(48) bond length is 1.48 Å. The C(38)-N(6) bond length is 1.35 Å. In the fifteenth C site, C(39) is bonded in a distorted single-bond geometry to one C(35) and one H(3,25,27,29) atom. The C(39)-H(3,25,27,29) bond length is 0.93 Å. In the sixteenth C site, C(40) is bonded in a distorted single-bond geometry to one C(36) and one H(30) atom. The C(40)-H(30) bond length is 0.93 Å. In the seventeenth C site, C(41) is bonded in a distorted single-bond geometry to one C(25) and one H(31) atom. The C(41)-H(31) bond length is 0.93 Å. In the eighteenth C site, C(42) is bonded in a distorted single-bond geometry to one C(26) and one H(32) atom. The C(42)-H(32) bond length is 0.93 Å. In the nineteenth C site, C(43) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(5), and one O(7) atom. The C(43)-O(5) bond length is 1.28 Å. The C(43)-O(7) bond length is 1.26 Å. In the twentieth C site, C(44) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(6), and one O(8) atom. The C(44)-O(6) bond length is 1.27 Å. The C(44)-O(8) bond length is 1.27 Å. In the twenty-first C site, C(45) is bonded in a trigonal non-coplanar geometry to one C(29), one H(33), one H(34), and one H(35) atom. The C(45)-H(33) bond length is 0.96 Å. The C(45)-H(34) bond length is 0.96 Å. The C(45)-H(35) bond length is 0.96 Å. In the twenty-second C site, C(46) is bonded in a trigonal non-coplanar geometry to one C(30); one H(36); and two equivalent H(37,38) atoms. The C(46)-H(36) bond length is 0.96 Å. Both C(46)-H(37,38) bond lengths are 0.96 Å. In the twenty-third C site, C(47) is bonded in a trigonal non-coplanar geometry to one C(37); one H(41); and two equivalent H(39,40) atoms. The C(47)-H(41) bond length is 0.96 Å. Both C(47)-H(39,40) bond lengths are 0.96 Å. In the twenty-fourth C site, C(48) is bonded in a trigonal non-coplanar geometry to one C(38), one H(42), one H(43), and one H(44) atom. The C(48)-H(42) bond length is 0.96 Å. The C(48)-H(43) bond length is 0.96 Å. The C(48)-H(44) bond length is 0.96 Å. There are four inequivalent N sites. In the first N site, N(5) is bonded in a 2-coordinate geometry to one C(37), one N(7), and one H(23) atom. The N(5)-N(7) bond length is 1.35 Å. The N(5)-H(23) bond length is 0.86 Å. In the second N site, N(6) is bonded in a 3-coordinate geometry to one C(38), one N(8), and one H(24) atom. The N(6)-N(8) bond length is 1.37 Å. The N(6)-H(24) bond length is 0.86 Å. In the third N site, N(7) is bonded in a 3-coordinate geometry to one Zn(3), one C(29), and one N(5) atom. In the fourth N site, N(8) is bonded in a 3-coordinate geometry to one Zn(3), one C(30), and one N(6) atom. There are eighteen inequivalent H sites. In the first H site, H(31) is bonded in a single-bond geometry to one C(41) atom. In the second H site, H(32) is bonded in a single-bond geometry to one C(42) atom. In the third H site, H(33) is bonded in a single-bond geometry to one C(45) atom. In the fourth H site, H(34) is bonded in a single-bond geometry to one C(45) atom. In the fifth H site, H(35) is bonded in a single-bond geometry to one C(45) atom. In the sixth H site, H(36) is bonded in a single-bond geometry to one C(46) atom. In the seventh H site, H(37,38) is bonded in a single-bond geometry to one C(46) atom. In the eighth H site, H(39,40) is bonded in a single-bond geometry to one C(47) atom. In the ninth H site, H(41) is bonded in a single-bond geometry to one C(47) atom. In the tenth H site, H(42) is bonded in a single-bond geometry to one C(48) atom. In the eleventh H site, H(43) is bonded in a single-bond geometry to one C(48) atom. In the twelfth H site, H(44) is bonded in a single-bond geometry to one C(48) atom. In the thirteenth H site, H(3,25,27,29) is bonded in a single-bond geometry to one C(4) atom. In the fourteenth H site, H(23) is bonded in a single-bond geometry to one N(5) atom. In the fifteenth H site, H(24) is bonded in a single-bond geometry to one N(6) atom. In the sixteenth H site, H(26) is bonded in a single-bond geometry to one C(28) atom. In the seventeenth H site, H(28) is bonded in a single-bond geometry to one C(32) atom. In the eighteenth H site, H(30) is bonded in a single-bond geometry to one C(40) atom. There are four inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(43) atom. In the second O site, O(6) is bonded in a single-bond geometry to one C(44) atom. In the third O site, O(7) is bonded in a single-bond geometry to one C(43) atom. In the fourth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(44) atom. Linkers: 64 Cc1n[nH]c(C)c1-c1ccc(C([O])=O)cc1. Metal clusters: 32 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 5.08 A, density 1.19 g/cm3, surface area 5185.35 m2/g, accessible volume 0.29 cm3/g