AgH4(C4N3)2(CH)2 crystallizes in the cubic I-43d space group. The structure consists of forty-eight 02329_fluka molecules inside a AgH4(C4N3)2 framework. In each AgH4(C4N3)2 framework, Ag(1) is bonded in a 6-coordinate geometry to two equivalent N(1), two equivalent N(2), and two equivalent N(3) atoms. Both Ag(1)-N(1) bond lengths are 2.58 Å. Both Ag(1)-N(2) bond lengths are 2.28 Å. Both Ag(1)-N(3) bond lengths are 2.50 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one N(3) atom. The C(1)-C(3) bond length is 1.47 Å. The C(1)-N(1) bond length is 1.39 Å. The C(1)-N(3) bond length is 1.38 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(2)-N(1) bond length is 1.39 Å. The C(2)-H(1) bond length is 0.92 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(1) and two equivalent N(2) atoms. There is one shorter (1.27 Å) and one longer (1.30 Å) C(3)-N(2) bond length. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(2) atom. The C(4)-N(3) bond length is 1.40 Å. The C(4)-H(2) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1) and two equivalent C(3) atoms. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(4) atom. There are two inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(2) atom. Linkers: 15 c1cnc(nc1)C1=NC(=[N]=C([N]1)c1ncccn1)c1ncccn1. Metal clusters: 24 [Ag]. The MOF has largest included sphere 4.05 A, density 1.53 g/cm3, surface area 3618.71 m2/g, accessible volume 0.28 cm3/g