Cu2C8N4H8Cl(CH)16(CH2)2 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, sixty-four isobutylene molecules, and eight Cu2C8N4H8Cl clusters. In each Cu2C8N4H8Cl cluster, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 3-coordinate geometry to one N(1), one N(3), and one Cl(1) atom. The Cu(1)-N(1) bond length is 1.93 Å. The Cu(1)-N(3) bond length is 1.92 Å. The Cu(1)-Cl(1) bond length is 2.47 Å. In the second Cu site, Cu(2) is bonded in a 4-coordinate geometry to one N(16), one N(5), one Cl(1), and one Cl(4) atom. The Cu(2)-N(16) bond length is 1.96 Å. The Cu(2)-N(5) bond length is 1.97 Å. The Cu(2)-Cl(1) bond length is 2.55 Å. The Cu(2)-Cl(4) bond length is 2.62 Å. In the third Cu site, Cu(7) is bonded in a 3-coordinate geometry to one N(14), one N(15), and one Cl(4) atom. The Cu(7)-N(14) bond length is 1.93 Å. The Cu(7)-N(15) bond length is 1.93 Å. The Cu(7)-Cl(4) bond length is 2.47 Å. In the fourth Cu site, Cu(8) is bonded in a 2-coordinate geometry to one N(12), one N(4), one Cl(1), and one Cl(4) atom. The Cu(8)-N(12) bond length is 1.94 Å. The Cu(8)-N(4) bond length is 1.94 Å. The Cu(8)-Cl(1) bond length is 2.88 Å. The Cu(8)-Cl(4) bond length is 2.67 Å. There are sixteen inequivalent C sites. In the first C site, C(71) is bonded in a distorted bent 120 degrees geometry to one N(12) and one H(75,78) atom. The C(71)-N(12) bond length is 1.33 Å. The C(71)-H(75,78) bond length is 0.95 Å. In the second C site, C(75) is bonded in a distorted bent 120 degrees geometry to one N(12) and one H(75,78) atom. The C(75)-N(12) bond length is 1.31 Å. The C(75)-H(75,78) bond length is 0.95 Å. In the third C site, C(84) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(89) atom. The C(84)-N(14) bond length is 1.34 Å. The C(84)-H(89) bond length is 0.95 Å. In the fourth C site, C(88) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(92) atom. The C(88)-N(14) bond length is 1.34 Å. The C(88)-H(92) bond length is 0.95 Å. In the fifth C site, C(92) is bonded in a distorted bent 120 degrees geometry to one N(15) and one H(99) atom. The C(92)-N(15) bond length is 1.35 Å. The C(92)-H(99) bond length is 0.95 Å. In the sixth C site, C(97) is bonded in a distorted bent 120 degrees geometry to one N(16) and one H(103) atom. The C(97)-N(16) bond length is 1.34 Å. The C(97)-H(103) bond length is 0.95 Å. In the seventh C site, C(96) is bonded in a distorted bent 120 degrees geometry to one N(15) and one H(102) atom. The C(96)-N(15) bond length is 1.33 Å. The C(96)-H(102) bond length is 0.95 Å. In the eighth C site, C(101) is bonded in a distorted bent 120 degrees geometry to one N(16) and one H(106) atom. The C(101)-N(16) bond length is 1.34 Å. The C(101)-H(106) bond length is 0.95 Å. In the ninth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,71) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1,71) bond length is 0.95 Å. In the tenth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4,64,88) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4,64,88) bond length is 0.95 Å. In the eleventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(15) atom. The C(14)-N(3) bond length is 1.36 Å. The C(14)-H(15) bond length is 0.95 Å. In the twelfth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(18) atom. The C(18)-N(3) bond length is 1.33 Å. The C(18)-H(18) bond length is 0.95 Å. In the thirteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(19) atom. The C(19)-N(4) bond length is 1.35 Å. The C(19)-H(19) bond length is 0.95 Å. In the fourteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(22) atom. The C(23)-N(4) bond length is 1.34 Å. The C(23)-H(22) bond length is 0.95 Å. In the fifteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(29) atom. The C(27)-N(5) bond length is 1.34 Å. The C(27)-H(29) bond length is 0.95 Å. In the sixteenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(32) atom. The C(31)-N(5) bond length is 1.33 Å. The C(31)-H(32) bond length is 0.95 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Cu(2), one C(27), and one C(31) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one Cu(8), one C(19), and one C(23) atom. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(14), and one C(18) atom. In the fifth N site, N(12) is bonded in a trigonal planar geometry to one Cu(8), one C(71), and one C(75) atom. In the sixth N site, N(14) is bonded in a trigonal planar geometry to one Cu(7), one C(84), and one C(88) atom. In the seventh N site, N(15) is bonded in a trigonal planar geometry to one Cu(7), one C(92), and one C(96) atom. In the eighth N site, N(16) is bonded in a trigonal planar geometry to one Cu(2), one C(101), and one C(97) atom. There are fifteen inequivalent H sites. In the first H site, H(99) is bonded in a single-bond geometry to one C(92) atom. In the second H site, H(102) is bonded in a single-bond geometry to one C(96) atom. In the third H site, H(103) is bonded in a single-bond geometry to one C(97) atom. In the fourth H site, H(106) is bonded in a single-bond geometry to one C(101) atom. In the fifth H site, H(1,71) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(4,64,88) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(29) is bonded in a single-bond geometry to one C(27) atom. In the twelfth H site, H(32) is bonded in a single-bond geometry to one C(31) atom. In the thirteenth H site, H(75,78) is bonded in a single-bond geometry to one C(71) atom. In the fourteenth H site, H(89) is bonded in a single-bond geometry to one C(84) atom. In the fifteenth H site, H(92) is bonded in a single-bond geometry to one C(88) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a distorted T-shaped geometry to one Cu(1), one Cu(2), and one Cu(8) atom. In the second Cl site, Cl(4) is bonded in a distorted T-shaped geometry to one Cu(2), one Cu(7), and one Cu(8) atom. Linkers: 30 c1cc(CCCc2ccncc2)ccn1. Metal clusters: 16 [Cu] ,4 Cl[Cu][Cu].Cl[Cu][Cu]. The MOF has largest included sphere 5.27 A, density 1.09 g/cm3, surface area 5140.51 m2/g, accessible volume 0.44 cm3/g