CoC10N3H7O4(CH)2(CH2)4C4NH3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, thirty-two 02329_fluka molecules, four C4NH3 clusters, and four CoC10N3H7O4 clusters. In each C4NH3 cluster, there are eight inequivalent C sites. In the first C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(12) atom. The C(14)-C(15) bond length is 1.38 Å. The C(14)-H(12) bond length is 0.93 Å. In the second C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-C(18) bond length is 1.48 Å. In the third C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(13) atom. The C(16)-H(13) bond length is 0.93 Å. In the fourth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(6), and one H(15) atom. The C(18)-N(6) bond length is 1.25 Å. The C(18)-H(15) bond length is 0.93 Å. In the fifth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(7), and one H(16) atom. The C(19)-C(20) bond length is 1.49 Å. The C(19)-N(7) bond length is 1.25 Å. The C(19)-H(16) bond length is 0.93 Å. In the sixth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(24) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-C(24) bond length is 1.37 Å. In the seventh C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(17) atom. The C(21)-H(17) bond length is 0.93 Å. In the eighth C site, C(24) is bonded in a distorted single-bond geometry to one C(20) and one H(20) atom. The C(24)-H(20) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(6) is bonded in a distorted single-bond geometry to one C(18) and one N(7) atom. The N(6)-N(7) bond length is 1.40 Å. In the second N site, N(7) is bonded in a distorted single-bond geometry to one C(19) and one N(6) atom. There are six inequivalent H sites. In the first H site, H(20) is bonded in a single-bond geometry to one C(24) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In each CoC10N3H7O4 cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a 6-coordinate geometry to one N(1), one N(5), one O(1), one O(6), one O(7), and one O(8) atom. The Co(1)-N(1) bond length is 2.16 Å. The Co(1)-N(5) bond length is 2.15 Å. The Co(1)-O(1) bond length is 2.01 Å. The Co(1)-O(6) bond length is 2.04 Å. The Co(1)-O(7) bond length is 2.07 Å. The Co(1)-O(8) bond length is 2.55 Å. In the second Co site, Co(2) is bonded in a distorted octahedral geometry to one N(4), one N(8), one O(2), one O(3), one O(4), and one O(5) atom. The Co(2)-N(4) bond length is 2.15 Å. The Co(2)-N(8) bond length is 2.17 Å. The Co(2)-O(2) bond length is 2.05 Å. The Co(2)-O(3) bond length is 2.35 Å. The Co(2)-O(4) bond length is 2.09 Å. The Co(2)-O(5) bond length is 2.00 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.49 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.36 Å. The C(5)-H(4) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(5) atom. The C(6)-N(2) bond length is 1.26 Å. The C(6)-H(5) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(3), and one H(6) atom. The C(7)-C(8) bond length is 1.45 Å. The C(7)-N(3) bond length is 1.30 Å. The C(7)-H(6) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.37 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(7) atom. The C(9)-C(10) bond length is 1.37 Å. The C(9)-H(7) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(4), and one H(8) atom. The C(10)-N(4) bond length is 1.35 Å. The C(10)-H(8) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(4), and one H(9) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(4) bond length is 1.33 Å. The C(11)-H(9) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(8), and one H(10) atom. The C(12)-H(10) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(11) atom. The C(13)-N(5) bond length is 1.35 Å. The C(13)-H(11) bond length is 0.93 Å. In the fourteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(14) atom. The C(17)-N(5) bond length is 1.35 Å. The C(17)-H(14) bond length is 0.93 Å. In the fifteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(18) atom. The C(22)-N(8) bond length is 1.34 Å. The C(22)-H(18) bond length is 0.93 Å. In the sixteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(19) atom. The C(23)-N(8) bond length is 1.32 Å. The C(23)-H(19) bond length is 0.93 Å. In the seventeenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(25)-O(1) bond length is 1.25 Å. The C(25)-O(2) bond length is 1.24 Å. In the eighteenth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(32)-O(3) bond length is 1.25 Å. The C(32)-O(4) bond length is 1.23 Å. In the nineteenth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(33)-O(5) bond length is 1.26 Å. The C(33)-O(6) bond length is 1.27 Å. In the twentieth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(40)-O(7) bond length is 1.30 Å. The C(40)-O(8) bond length is 1.23 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted single-bond geometry to one C(6) and one N(3) atom. The N(2)-N(3) bond length is 1.42 Å. In the third N site, N(3) is bonded in a distorted single-bond geometry to one C(7) and one N(2) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one Co(1), one C(13), and one C(17) atom. In the fifth N site, N(4) is bonded in a trigonal planar geometry to one Co(2), one C(10), and one C(11) atom. In the sixth N site, N(8) is bonded in a trigonal planar geometry to one Co(2), one C(22), and one C(23) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Co(1) and one C(25) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(25) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Co(2) and one C(32) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Co(2) and one C(32) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one C(33) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Co(1) and one C(33) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Co(1) and one C(40) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Co(1) and one C(40) atom. Linkers: 8 [CH]([N][N][CH]c1ccncc1)c1ccncc1 ,8 [O]C(=O)[C@H]1CC[C@@H](C([O])=O)CC1. Metal clusters: 4 O=[C]O[Co]1O[C]O[Co]2(O[C]O1)O[C]O2. RCSR code: sql. The MOF has largest included sphere 4.64 A, density 1.27 g/cm3, surface area 4683.39 m2/g, accessible volume 0.26 cm3/g