Co2C27N3H16O8(CH)4(C3H2)4C7NH4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules; eight 2,3-dimethyl-1,3-butadiene molecules; four schembl5425382 molecules; and four Co2C27N3H16O8 clusters. In each Co2C27N3H16O8 cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a trigonal bipyramidal geometry to one N(2), one O(2), one O(4), one O(6), and one O(8) atom. The Co(1)-N(2) bond length is 2.06 Å. The Co(1)-O(2) bond length is 2.05 Å. The Co(1)-O(4) bond length is 2.05 Å. The Co(1)-O(6) bond length is 2.01 Å. The Co(1)-O(8) bond length is 2.04 Å. In the second Co site, Co(2) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(3), one O(5), and one O(7) atom. The Co(2)-N(1) bond length is 2.06 Å. The Co(2)-O(1) bond length is 2.01 Å. The Co(2)-O(3) bond length is 2.03 Å. The Co(2)-O(5) bond length is 2.11 Å. The Co(2)-O(7) bond length is 2.03 Å. There are twenty-seven inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(3) bond length is 1.26 Å. The C(1)-O(4) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(7) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(10) atom. The C(16)-N(1) bond length is 1.31 Å. The C(16)-H(10) bond length is 0.93 Å. In the sixth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(11) atom. The C(17)-N(1) bond length is 1.31 Å. The C(17)-H(11) bond length is 0.93 Å. In the seventh C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(14) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(14) bond length is 0.93 Å. In the eighth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(25) atom. The C(22)-C(23) bond length is 1.38 Å. The C(22)-C(25) bond length is 1.48 Å. In the ninth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(15) atom. The C(23)-H(15) bond length is 0.93 Å. In the tenth C site, C(25) is bonded in a bent 120 degrees geometry to one C(22), one O(1), and one O(2) atom. The C(25)-O(1) bond length is 1.26 Å. The C(25)-O(2) bond length is 1.26 Å. In the eleventh C site, C(26) is bonded in a bent 120 degrees geometry to one C(27), one O(5), and one O(6) atom. The C(26)-C(27) bond length is 1.49 Å. The C(26)-O(5) bond length is 1.26 Å. The C(26)-O(6) bond length is 1.27 Å. In the twelfth C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(32) atom. The C(27)-C(28) bond length is 1.38 Å. The C(27)-C(32) bond length is 1.39 Å. In the thirteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(27) and one H(17) atom. The C(28)-H(17) bond length is 0.93 Å. In the fourteenth C site, C(32) is bonded in a distorted single-bond geometry to one C(27) and one H(20) atom. The C(32)-H(20) bond length is 0.93 Å. In the fifteenth C site, C(30) is bonded in a distorted single-bond geometry to one N(4) atom. The C(30)-N(4) bond length is 1.42 Å. In the sixteenth C site, C(33) is bonded in a distorted trigonal planar geometry to one C(34), one C(38), and one N(4) atom. The C(33)-C(34) bond length is 1.38 Å. The C(33)-C(38) bond length is 1.39 Å. The C(33)-N(4) bond length is 1.43 Å. In the seventeenth C site, C(34) is bonded in a distorted single-bond geometry to one C(33) and one H(21,24) atom. The C(34)-H(21,24) bond length is 0.93 Å. In the eighteenth C site, C(38) is bonded in a distorted single-bond geometry to one C(33) and one H(21,24) atom. The C(38)-H(21,24) bond length is 0.93 Å. In the nineteenth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(26) atom. The C(41)-N(2) bond length is 1.33 Å. The C(41)-H(26) bond length is 0.93 Å. In the twentieth C site, C(43) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(28) atom. The C(43)-N(2) bond length is 1.33 Å. The C(43)-H(28) bond length is 0.93 Å. In the twenty-first C site, C(44) is bonded in a distorted trigonal planar geometry to one C(45), one C(49), and one N(4) atom. The C(44)-C(45) bond length is 1.38 Å. The C(44)-C(49) bond length is 1.38 Å. The C(44)-N(4) bond length is 1.42 Å. In the twenty-second C site, C(45) is bonded in a single-bond geometry to one C(44) and one H(29) atom. The C(45)-H(29) bond length is 0.93 Å. In the twenty-third C site, C(46) is bonded in a distorted single-bond geometry to one C(47) and one H(30) atom. The C(46)-C(47) bond length is 1.38 Å. The C(46)-H(30) bond length is 0.93 Å. In the twenty-fourth C site, C(47) is bonded in a trigonal planar geometry to one C(46), one C(48), and one C(50) atom. The C(47)-C(48) bond length is 1.38 Å. The C(47)-C(50) bond length is 1.48 Å. In the twenty-fifth C site, C(48) is bonded in a distorted trigonal planar geometry to one C(47), one C(49), and one H(31) atom. The C(48)-C(49) bond length is 1.37 Å. The C(48)-H(31) bond length is 0.93 Å. In the twenty-sixth C site, C(49) is bonded in a distorted single-bond geometry to one C(44), one C(48), and one H(32) atom. The C(49)-H(32) bond length is 0.93 Å. In the twenty-seventh C site, C(50) is bonded in a distorted bent 120 degrees geometry to one C(47), one O(7), and one O(8) atom. The C(50)-O(7) bond length is 1.26 Å. The C(50)-O(8) bond length is 1.26 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(2), one C(16), and one C(17) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(41), and one C(43) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one C(30), one C(33), and one C(44) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(28) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(32) atom. In the ninth H site, H(21,24) is bonded in a single-bond geometry to one C(34) atom. In the tenth H site, H(26) is bonded in a single-bond geometry to one C(41) atom. In the eleventh H site, H(28) is bonded in a single-bond geometry to one C(43) atom. In the twelfth H site, H(29) is bonded in a single-bond geometry to one C(45) atom. In the thirteenth H site, H(30) is bonded in a single-bond geometry to one C(46) atom. In the fourteenth H site, H(31) is bonded in a single-bond geometry to one C(48) atom. In the fifteenth H site, H(32) is bonded in a single-bond geometry to one C(49) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(2) and one C(25) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one C(25) atom. In the third O site, O(3) is bonded in a water-like geometry to one Co(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Co(1) and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(26) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Co(1) and one C(26) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(50) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Co(1) and one C(50) atom. Linkers: 8 [O]C(=O)c1ccc(N(c2ccc(C([O])=O)cc2)c2ccc(-c3ccncc3)cc2)cc1. Metal clusters: 4 [C]1O[Co]234O[C]O[Co]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 5.89 A, density 0.98 g/cm3, surface area 4483.46 m2/g, accessible volume 0.58 cm3/g