Cu7C132H126(N3O7)2Cu6C12H12S9(N3O17)2 is alpha structured and crystallizes in the hexagonal P6_322 space group. The structure is zero-dimensional and consists of two Cu6C12H12S9(N3O17)2 clusters and two Cu7C132H126(N3O7)2 clusters. In each Cu6C12H12S9(N3O17)2 cluster, Cu(2) is bonded to one N(1), one O(5), one O(7), one O(9), and two equivalent O(3) atoms to form CuNO5 octahedra that share corners with two equivalent Cu(2)NO5 octahedra, corners with two equivalent S(1)O4 tetrahedra, corners with two equivalent S(2)O4 tetrahedra, and  an edgeedge with one Cu(2)NO5 octahedra. The corner-sharing octahedral tilt angles are 63°. The Cu(2)-N(1) bond length is 1.98 Å. The Cu(2)-O(5) bond length is 1.94 Å. The Cu(2)-O(7) bond length is 1.91 Å. The Cu(2)-O(9) bond length is 1.99 Å. There is one shorter (2.17 Å) and one longer (2.20 Å) Cu(2)-O(3) bond length. There are two inequivalent C sites. In the first C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(21,22) atom. The C(22)-N(1) bond length is 1.39 Å. The C(22)-H(21,22) bond length is 0.93 Å. In the second C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(21,22) atom. The C(23)-N(1) bond length is 1.39 Å. The C(23)-H(21,22) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Cu(2), one C(22), and one C(23) atom. H(21,22) is bonded in a single-bond geometry to one C(22) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(10), one O(5), one O(6), and one O(7) atom to form SO4 tetrahedra that share corners with two equivalent Cu(2)NO5 octahedra and corners with two equivalent S(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 57°. The S(1)-O(10) bond length is 1.52 Å. The S(1)-O(5) bond length is 1.47 Å. The S(1)-O(6) bond length is 1.50 Å. The S(1)-O(7) bond length is 1.50 Å. In the second S site, S(2) is bonded to two equivalent O(3) and two equivalent O(4) atoms to form SO4 tetrahedra that share corners with four equivalent Cu(2)NO5 octahedra. The corner-sharing octahedral tilt angles range from 54-59°. Both S(2)-O(3) bond lengths are 1.49 Å. Both S(2)-O(4) bond lengths are 1.46 Å. There are seven inequivalent O sites. In the first O site, O(9) is bonded in a trigonal planar geometry to three equivalent Cu(2) atoms. In the second O site, O(10) is bonded in a trigonal planar geometry to three equivalent S(1) atoms. In the third O site, O(3) is bonded in a distorted trigonal planar geometry to two equivalent Cu(2) and one S(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one S(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one S(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(2) and one S(1) atom. In each Cu7C132H126(N3O7)2 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one N(2), one O(2), one O(8), and two equivalent O(1) atoms to form distorted CuNO4 trigonal bipyramids that share  an edgeedge with one Cu(3)O6 octahedra and edges with two equivalent Cu(1)NO4 trigonal bipyramids. The Cu(1)-N(2) bond length is 1.92 Å. The Cu(1)-O(2) bond length is 1.89 Å. The Cu(1)-O(8) bond length is 2.01 Å. There is one shorter (2.00 Å) and one longer (2.38 Å) Cu(1)-O(1) bond length. In the second Cu site, Cu(3) is bonded to six equivalent O(1) atoms to form edge-sharing CuO6 octahedra. All Cu(3)-O(1) bond lengths are 2.10 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one O(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-O(1) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-C(8) bond length is 1.52 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(7) bond length is 1.52 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(6) atom. The C(6)-C(6) bond length is 1.54 Å. In the seventh C site, C(7) is bonded in a trigonal non-coplanar geometry to one C(5); one H(2,5,7); and two equivalent H(3,4) atoms. The C(7)-H(2,5,7) bond length is 0.96 Å. Both C(7)-H(3,4) bond lengths are 0.96 Å. In the eighth C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(4); one H(6); and two equivalent H(2,5,7) atoms. The C(8)-H(6) bond length is 0.96 Å. Both C(8)-H(2,5,7) bond lengths are 0.96 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(8) atom. The C(9)-C(10) bond length is 1.43 Å. The C(9)-N(2) bond length is 1.28 Å. The C(9)-H(8) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(15) bond length is 1.39 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one O(2) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-O(2) bond length is 1.35 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(16) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-C(16) bond length is 1.55 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(9) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(9) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(20) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-C(20) bond length is 1.51 Å. In the fifteenth C site, C(15) is bonded in a single-bond geometry to one C(10), one C(14), and one H(10) atom. The C(15)-H(10) bond length is 0.93 Å. In the sixteenth C site, C(16) is bonded in a tetrahedral geometry to one C(12), one C(17), one C(18), and one C(19) atom. The C(16)-C(17) bond length is 1.53 Å. The C(16)-C(18) bond length is 1.54 Å. The C(16)-C(19) bond length is 1.56 Å. In the seventeenth C site, C(17) is bonded in a trigonal non-coplanar geometry to one C(16) and three equivalent H(11,12,13,14,16,17,18,19) atoms. All C(17)-H(11,12,13,14,16,17,18,19) bond lengths are 0.96 Å. In the eighteenth C site, C(18) is bonded in a trigonal non-coplanar geometry to one C(16); one H(15); and two equivalent H(11,12,13,14,16,17,18,19) atoms. The C(18)-H(15) bond length is 0.96 Å. Both C(18)-H(11,12,13,14,16,17,18,19) bond lengths are 0.96 Å. In the nineteenth C site, C(19) is bonded in a trigonal non-coplanar geometry to one C(16) and three equivalent H(11,12,13,14,16,17,18,19) atoms. All C(19)-H(11,12,13,14,16,17,18,19) bond lengths are 0.96 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(14), one C(21), and one C(24) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-C(24) bond length is 1.39 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(20,23) atom. The C(21)-H(20,23) bond length is 0.93 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(20) and one H(20,23) atom. The C(24)-H(20,23) bond length is 0.93 Å. N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(2), and one C(9) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2,5,7) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(11,12,13,14,16,17,18,19) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(20,23) is bonded in a single-bond geometry to one C(21) atom. There are three inequivalent O sites. In the first O site, O(8) is bonded in a trigonal non-coplanar geometry to three equivalent Cu(1) atoms. In the second O site, O(1) is bonded in a distorted rectangular see-saw-like geometry to one Cu(3), two equivalent Cu(1), and one C(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(11) atom. Linkers: 10 Cc1cc(/N=C/c2cc(-c3ccncc3)cc(C(C)(C)C)c2[O])c([O])c(-c2c(C)c(C)cc(/N=C/c3cc(-c4ccncc4)cc(C(C)(C)C)c3[O])c2[O])c1C ,4 O=S(=O)=O.[O]S([O])([O])OS([O])([O])[O]. Metal clusters: 14 [Cu] ,1 [O]S1([O])O[Cu]2O[S@@](=O)O[Cu@@]34O[S@@](=O)O[Cu@@](O[S@@](=O)O2)(OS([O])([O])O[Cu@@]25O[S@](=O)O[Cu@](O[S@](=O)O[Cu](O[S@](=O)O2)OS([O])([O])O3)(O1)O5)O4 ,1 [O]S1([O])O[Cu]2O[S@@](=O)O[Cu@@]34O[S@@](=O)O[Cu@@](O[S@@](=O)O2)(OS([O])([O])O[Cu@]25O[S@@](=O)O[Cu@@](O[S@@](=O)O[Cu](O[S@@](=O)O2)O1)(OS([O])([O])O3)O5)O4. The MOF has largest included sphere 12.15 A, density 0.87 g/cm3, surface area 3702.50 m2/g, accessible volume 0.68 cm3/g