CoCu2C36H32(N2Cl)6 crystallizes in the monoclinic C2/c space group. Co(1) is bonded in a tetrahedral geometry to two equivalent N(6) and two equivalent Cl(1) atoms. Both Co(1)-N(6) bond lengths are 1.99 Å. Both Co(1)-Cl(1) bond lengths are 2.21 Å. Cu(1) is bonded to one N(1), one N(4), one Cl(2), and two equivalent Cl(3) atoms to form distorted edge-sharing CuN2Cl3 trigonal bipyramids. The Cu(1)-N(1) bond length is 2.00 Å. The Cu(1)-N(4) bond length is 2.00 Å. The Cu(1)-Cl(2) bond length is 2.27 Å. There is one shorter (2.39 Å) and one longer (2.60 Å) Cu(1)-Cl(3) bond length. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.99 Å. In the second C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(3), and one H(9) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-N(3) bond length is 1.32 Å. The C(9)-H(9) bond length is 1.00 Å. In the third C site, C(10) is bonded in a water-like geometry to one C(11) and one C(9) atom. The C(10)-C(11) bond length is 1.36 Å. In the fourth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(4), and one H(10) atom. The C(11)-N(4) bond length is 1.32 Å. The C(11)-H(10) bond length is 1.01 Å. In the fifth C site, C(12) is bonded in a bent 120 degrees geometry to one C(13) and one C(7) atom. The C(12)-C(13) bond length is 1.42 Å. The C(12)-C(7) bond length is 1.38 Å. In the sixth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(15) atom. The C(13)-C(14) bond length is 1.37 Å. The C(13)-C(15) bond length is 1.50 Å. In the seventh C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(5), and one H(11) atom. The C(14)-C(5) bond length is 1.39 Å. The C(14)-H(11) bond length is 1.01 Å. In the eighth C site, C(15) is bonded in a 3-coordinate geometry to one C(13), one N(5), one H(12), and one H(13) atom. The C(15)-N(5) bond length is 1.48 Å. The C(15)-H(12) bond length is 0.97 Å. The C(15)-H(13) bond length is 0.96 Å. In the ninth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one N(5), and one H(14) atom. The C(16)-C(17) bond length is 1.36 Å. The C(16)-N(5) bond length is 1.30 Å. The C(16)-H(14) bond length is 1.05 Å. In the tenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(15) atom. The C(17)-C(18) bond length is 1.36 Å. The C(17)-H(15) bond length is 1.04 Å. In the eleventh C site, C(18) is bonded in a 2-coordinate geometry to one C(17), one N(6), and one H(16) atom. The C(18)-N(6) bond length is 1.34 Å. The C(18)-H(16) bond length is 0.94 Å. In the twelfth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.34 Å. The C(2)-H(2) bond length is 0.90 Å. In the thirteenth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.34 Å. The C(3)-H(3) bond length is 1.01 Å. In the fourteenth C site, C(4) is bonded in a 3-coordinate geometry to one C(5), one N(2), one H(4), and one H(5) atom. The C(4)-C(5) bond length is 1.51 Å. The C(4)-N(2) bond length is 1.47 Å. The C(4)-H(4) bond length is 0.99 Å. The C(4)-H(5) bond length is 0.99 Å. In the fifteenth C site, C(5) is bonded in a trigonal planar geometry to one C(14), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.37 Å. In the sixteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(6) atom. The C(6)-C(7) bond length is 1.45 Å. The C(6)-H(6) bond length is 0.98 Å. In the seventeenth C site, C(7) is bonded in a 4-coordinate geometry to one C(12), one C(6), one C(8), and one H(6) atom. The C(7)-C(8) bond length is 1.52 Å. The C(7)-H(6) bond length is 1.39 Å. In the eighteenth C site, C(8) is bonded in a 3-coordinate geometry to one C(7), one N(3), one H(7), and one H(8) atom. The C(8)-N(3) bond length is 1.47 Å. The C(8)-H(7) bond length is 1.02 Å. The C(8)-H(8) bond length is 0.98 Å. There are six inequivalent N sites. In the first N site, N(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(4), and one N(1) atom. The N(2)-N(1) bond length is 1.37 Å. In the second N site, N(3) is bonded in a distorted trigonal planar geometry to one C(8), one C(9), and one N(4) atom. The N(3)-N(4) bond length is 1.36 Å. In the third N site, N(4) is bonded in a 3-coordinate geometry to one Cu(1), one C(11), and one N(3) atom. In the fourth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one C(15), one C(16), and one N(6) atom. The N(5)-N(6) bond length is 1.37 Å. In the fifth N site, N(6) is bonded in a 3-coordinate geometry to one Co(1), one C(18), and one N(5) atom. In the sixth N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one N(2) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a 2-coordinate geometry to one C(6) and one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Co(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one Cu(1) atom. In the third Cl site, Cl(3) is bonded in an L-shaped geometry to two equivalent Cu(1) atoms. Linkers: 1 Cl[Co](Cl)(N1[CH]C=CN1Cc1[c]c(Cn2c[c]cn2)cc(Cn2cccn2)c1)N1C=C[CH]N1Cc1[c]c(Cn2c[c]cn2)cc(Cn2cccn2)c1 ,1 Cl[Co](Cl)(N1C=C[CH]N1Cc1[c]c(Cn2c[c]cn2)cc(Cn2cccn2)c1)N1C=C[CH]N1Cc1[c]c(Cn2c[c]cn2)cc(Cn2cccn2)c1. Metal clusters: 2 Cl[Cu]Cl.Cl[Cu]Cl. The MOF has largest included sphere 4.71 A, density 1.48 g/cm3, surface area 4549.95 m2/g, accessible volume 0.22 cm3/g