(Cu(OOCC6H4COO))2CuH14(C13O2)2 is Indium-like structured and crystallizes in the orthorhombic Immm space group. The structure is zero-dimensional and consists of eight Cu(OOCC6H4COO) clusters and four CuH14(C13O2)2 clusters. In each Cu(OOCC6H4COO) cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(2), one O(3), one O(4), and one O(5) atom. The Cu(1)-O(2) bond length is 1.92 Å. The Cu(1)-O(3) bond length is 1.96 Å. The Cu(1)-O(4) bond length is 1.97 Å. The Cu(1)-O(5) bond length is 1.98 Å. There are eight inequivalent C sites. In the first C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(5)-C(6) bond length is 1.36 Å. The C(5)-H(3) bond length is 0.94 Å. In the second C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(6)-C(7) bond length is 1.34 Å. The C(6)-C(9) bond length is 1.54 Å. In the third C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(7)-H(4) bond length is 0.94 Å. In the fourth C site, C(9) is bonded in a bent 120 degrees geometry to one C(6), one O(2), and one O(4) atom. The C(9)-O(2) bond length is 1.22 Å. The C(9)-O(4) bond length is 1.33 Å. In the fifth C site, C(10) is bonded in a bent 120 degrees geometry to one C(11), one O(3), and one O(5) atom. The C(10)-C(11) bond length is 1.52 Å. The C(10)-O(3) bond length is 1.21 Å. The C(10)-O(5) bond length is 1.28 Å. In the sixth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(16) atom. The C(11)-C(12) bond length is 1.36 Å. The C(11)-C(16) bond length is 1.39 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(12)-H(6) bond length is 0.94 Å. In the eighth C site, C(16) is bonded in a distorted single-bond geometry to one C(11) and one H(9) atom. The C(16)-H(9) bond length is 0.94 Å. There are four inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted single-bond geometry to one Cu(1) and one C(10) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Cu(1) and one C(9) atom. In the third O site, O(2) is bonded in a single-bond geometry to one Cu(1) and one C(9) atom. In the fourth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(10) atom. In each CuH14(C13O2)2 cluster, Cu(2) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. All Cu(2)-O(1) bond lengths are 1.98 Å. There are eight inequivalent C sites. In the first C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20) and two equivalent O(1) atoms. The C(19)-C(20) bond length is 1.48 Å. Both C(19)-O(1) bond lengths are 1.26 Å. In the second C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(20), and one H(1) atom. The C(1)-C(2) bond length is 1.46 Å. The C(1)-C(20) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.94 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(21), and one C(3) atom. The C(2)-C(21) bond length is 1.42 Å. The C(2)-C(3) bond length is 1.50 Å. In the fourth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.31 Å. The C(3)-C(8) bond length is 1.42 Å. In the fifth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(4)-H(2) bond length is 0.94 Å. In the sixth C site, C(20) is bonded in a trigonal planar geometry to one C(19) and two equivalent C(1) atoms. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(8)-H(5) bond length is 0.94 Å. In the eighth C site, C(21) is bonded in a distorted single-bond geometry to two equivalent C(2) and one H(11) atom. The C(21)-H(11) bond length is 0.94 Å. There are four inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(21) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(1) is bonded in a single-bond geometry to one C(1) atom. O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(19) atom. Linkers: 8 [O]C(=O)c1ccc(-c2cc(C([O])=O)cc(-c3ccc(C([O])=O)cc3)c2)cc1. Metal clusters: 6 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: fmj. The MOF has largest included sphere 14.44 A, density 0.44 g/cm3, surface area 4095.84 m2/g, accessible volume 1.94 cm3/g