Zn2C64N7H28(O2F5)2 crystallizes in the orthorhombic Pmmm space group. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted square pyramidal geometry to one N(2) and four equivalent O(1) atoms. The Zn(1)-N(2) bond length is 2.05 Å. All Zn(1)-O(1) bond lengths are 2.00 Å. In the second Zn site, Zn(2) is bonded in a square co-planar geometry to two equivalent N(3) and two equivalent N(4) atoms. Both Zn(2)-N(3) bond lengths are 1.90 Å. Both Zn(2)-N(4) bond lengths are 2.00 Å. In the third Zn site, Zn(3) is bonded in a distorted hexagonal bipyramidal geometry to eight equivalent N(1) atoms. All Zn(3)-N(1) bond lengths are 2.04 Å. There are twenty-five inequivalent C sites. In the first C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12) and two equivalent O(1) atoms. The C(11)-C(12) bond length is 1.54 Å. Both C(11)-O(1) bond lengths are 1.23 Å. In the second C site, C(12) is bonded in a trigonal planar geometry to one C(11) and two equivalent C(1) atoms. Both C(12)-C(1) bond lengths are 1.36 Å. In the third C site, C(13) is bonded in a trigonal planar geometry to one C(14) and two equivalent C(2) atoms. The C(13)-C(14) bond length is 1.46 Å. Both C(13)-C(2) bond lengths are 1.36 Å. In the fourth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.45 Å. The C(14)-C(17) bond length is 1.37 Å. In the fifth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one N(4) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-N(4) bond length is 1.38 Å. In the sixth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(7) atom. The C(16)-H(7) bond length is 0.95 Å. In the seventh C site, C(17) is bonded in a trigonal planar geometry to one C(14), one C(18), and one N(3) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-N(3) bond length is 1.50 Å. In the eighth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(8) atom. The C(18)-H(8) bond length is 0.95 Å. In the ninth C site, C(19) is bonded in a distorted T-shaped geometry to one C(20) and two equivalent C(8) atoms. The C(19)-C(20) bond length is 1.51 Å. Both C(19)-C(8) bond lengths are 1.41 Å. In the tenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(25) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(25) bond length is 1.42 Å. In the eleventh C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one F(1) atom. The C(21)-F(1) bond length is 1.32 Å. In the twelfth C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one F(2) atom. The C(22)-C(23) bond length is 1.41 Å. The C(22)-F(2) bond length is 1.34 Å. In the thirteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one F(3) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-F(3) bond length is 1.34 Å. In the fourteenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one C(25), and one F(4) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-F(4) bond length is 1.34 Å. In the fifteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(20), one C(24), and one F(5) atom. The C(25)-F(5) bond length is 1.34 Å. In the sixteenth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(12), one C(2), and one H(1) atom. The C(1)-C(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the seventeenth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(13), and one H(2) atom. The C(2)-H(2) bond length is 0.95 Å. In the eighteenth C site, C(3) is bonded in a 4-coordinate geometry to one C(3), one C(4), one N(2), and one H(3) atom. The C(3)-C(3) bond length is 1.23 Å. The C(3)-C(4) bond length is 1.35 Å. The C(3)-N(2) bond length is 1.32 Å. The C(3)-H(3) bond length is 0.95 Å. In the nineteenth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(9), and one H(4) atom. The C(4)-C(9) bond length is 1.39 Å. The C(4)-H(4) bond length is 0.95 Å. In the twentieth C site, C(5) is bonded in a distorted single-bond geometry to one C(10) and one N(1) atom. The C(5)-C(10) bond length is 1.41 Å. The C(5)-N(1) bond length is 1.35 Å. In the twenty-first C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-C(7) bond length is 1.35 Å. The C(6)-H(5) bond length is 0.95 Å. In the twenty-second C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(6) atom. The C(7)-C(8) bond length is 1.46 Å. The C(7)-H(6) bond length is 0.96 Å. In the twenty-third C site, C(8) is bonded in a 3-coordinate geometry to one C(19), one C(7), and one N(1) atom. The C(8)-N(1) bond length is 1.39 Å. In the twenty-fourth C site, C(9) is bonded in a 5-coordinate geometry to one C(10) and four equivalent C(4) atoms. The C(9)-C(10) bond length is 1.51 Å. In the twenty-fifth C site, C(10) is bonded in a 5-coordinate geometry to one C(9) and four equivalent C(5) atoms. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Zn(3), one C(5), and one C(8) atom. In the second N site, N(2) is bonded in a 5-coordinate geometry to one Zn(1) and four equivalent C(3) atoms. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Zn(2) and two equivalent C(17) atoms. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Zn(2) and two equivalent C(15) atoms. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(18) atom. O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(11) atom. There are five inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(21) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(22) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(23) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(24) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(25) atom. Linkers: 1 [C@@H]12[C@@H]3[C@@]42[C@@H]2[C@H]4[C@@H]4[C@H]1[N@]14[C@H]3[C@H]21.[C@@H]12[C@@H]3[C@@]42[C@@H]2[C@H]4[C@@H]4[C@H]1[N@@]14[C@H]3[C@H]21.Fc1c(c(F)c(c(c1F)F)F)/C/1=C/2\C=C[C@@]34N2N2/C/5=C(\[C]6[N@]7[N@]8[C]1C=C[C@]18[C@@]7([C@@]71[C@@]18[C@@]97C=C[C]7[N@]9[N@]8[C](C=C1)/C(=C/1\N8[C@]9([C@]4([C@]32C=C5)[C@@]29C=C/C(=C/7\c3c(F)c(F)c(c(c3F)F)F)/N82)C=C1)/c1c(F)c(F)c(c(c1F)F)F)C=C6)/c1c(F)c(F)c(c(c1F)F)F ,1 [O]C(=O)c1ccc(cc1)C1=C2C=CC3=[N]2[Zn@@]24n5c1ccc5C(=C1[N]2=C(C=C1)C(=c1n4c(=C3c2ccc(cc2)C(=O)[O])cc1)c1ccc(cc1)C(=O)[O])c1ccc(cc1)C(=O)[O]. Metal clusters: 1 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3 ,1 [N][N][Zn]12([N][N])([N][N]1)[N][N]2. RCSR code: sql. The MOF has largest included sphere 10.50 A, density 0.68 g/cm3, surface area 3862.87 m2/g, accessible volume 1.10 cm3/g