Zn7H24(C30O13)2(CH)12 crystallizes in the orthorhombic Cmce space group. The structure consists of forty-eight 02329_fluka molecules inside a Zn7H24(C30O13)2 framework. In the Zn7H24(C30O13)2 framework, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(4), one O(5), and one O(8) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra,  a cornercorner with one Zn(1)O4 tetrahedra, and  a cornercorner with one Zn(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 68°. The Zn(1)-O(2) bond length is 1.92 Å. The Zn(1)-O(4) bond length is 1.95 Å. The Zn(1)-O(5) bond length is 1.98 Å. The Zn(1)-O(8) bond length is 1.91 Å. In the second Zn site, Zn(2) is bonded to one O(7), one O(8), and two equivalent O(3) atoms to form ZnO4 tetrahedra that share  a cornercorner with one Zn(3)O6 octahedra and corners with two equivalent Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 70°. The Zn(2)-O(7) bond length is 1.89 Å. The Zn(2)-O(8) bond length is 1.95 Å. Both Zn(2)-O(3) bond lengths are 2.00 Å. In the third Zn site, Zn(3) is bonded to two equivalent O(8) and four equivalent O(1) atoms to form corner-sharing ZnO6 octahedra. Both Zn(3)-O(8) bond lengths are 1.97 Å. All Zn(3)-O(1) bond lengths are 2.24 Å. There are twenty inequivalent C sites. In the first C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(22), and one C(23) atom. The C(13)-C(14) bond length is 1.31 Å. The C(13)-C(22) bond length is 1.39 Å. The C(13)-C(23) bond length is 1.52 Å. In the second C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(7) atom. The C(14)-H(7) bond length is 0.93 Å. In the third C site, C(15) is bonded in a single-bond geometry to one C(16) and one H(8) atom. The C(15)-C(16) bond length is 1.35 Å. The C(15)-H(8) bond length is 0.93 Å. In the fourth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(24) atom. The C(16)-C(17) bond length is 1.37 Å. The C(16)-C(24) bond length is 1.52 Å. In the fifth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(22) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-C(22) bond length is 1.44 Å. In the sixth C site, C(18) is bonded in a single-bond geometry to one C(17) and one H(9) atom. The C(18)-H(9) bond length is 0.93 Å. In the seventh C site, C(21) is bonded in a single-bond geometry to one C(22) and one H(12) atom. The C(21)-C(22) bond length is 1.41 Å. The C(21)-H(12) bond length is 0.93 Å. In the eighth C site, C(22) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(21) atom. In the ninth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(13) and two equivalent O(5) atoms. Both C(23)-O(5) bond lengths are 1.23 Å. In the tenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(6), and one O(7) atom. The C(24)-O(6) bond length is 1.21 Å. The C(24)-O(7) bond length is 1.23 Å. In the eleventh C site, C(1) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(2) atom. The C(1)-C(10) bond length is 1.42 Å. The C(1)-C(11) bond length is 1.49 Å. The C(1)-C(2) bond length is 1.35 Å. In the twelfth C site, C(2) is bonded in a single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.93 Å. In the thirteenth C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-H(2) bond length is 0.93 Å. In the fourteenth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(4)-C(12) bond length is 1.50 Å. The C(4)-C(5) bond length is 1.43 Å. In the fifteenth C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(6) atom. The C(5)-C(10) bond length is 1.43 Å. The C(5)-C(6) bond length is 1.39 Å. In the sixteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the seventeenth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(6) atom. The C(9)-C(10) bond length is 1.35 Å. The C(9)-H(6) bond length is 0.93 Å. In the eighteenth C site, C(10) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(9) atom. In the nineteenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(11)-O(1) bond length is 1.22 Å. The C(11)-O(2) bond length is 1.27 Å. In the twentieth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(12)-O(3) bond length is 1.23 Å. The C(12)-O(4) bond length is 1.26 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(21) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(3) and one C(11) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(11) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(12) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(12) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(23) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(24) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(24) atom. In the eighth O site, O(8) is bonded to one Zn(2), one Zn(3), and two equivalent Zn(1) atoms to form corner-sharing OZn4 tetrahedra. Linkers: 12 [O]C(=O)c1ccc(C([O])=O)c2ccccc12. Metal clusters: 2 O=[C]O[Zn]1O[C]O[Zn@]23O[C]O[Zn]4(O[C]O[Zn@@]56O[C]O[Zn](O[C]=O)O[C]O[Zn@@](O[C]O4)(O[C]O5)O6)O[C]O[Zn@](O[C]O1)(O[C]O2)O3. RCSR code: bcu. The MOF has largest included sphere 5.58 A, density 1.47 g/cm3, surface area 3851.74 m2/g, accessible volume 0.29 cm3/g