(CdH4(C2O)4)2CdH6(C5O2)2(CH)10(C2PNO2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of forty 02329_fluka molecules, four oprea1_327699 molecules, four CdH4(C2O)4 clusters, and four CdH6(C5O2)2 clusters. In each CdH4(C2O)4 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one O(10), one O(15), one O(16), one O(2), and one O(9) atom to form distorted edge-sharing CdO5 trigonal bipyramids. The Cd(1)-O(10) bond length is 2.42 Å. The Cd(1)-O(15) bond length is 2.38 Å. The Cd(1)-O(16) bond length is 2.31 Å. The Cd(1)-O(2) bond length is 2.31 Å. The Cd(1)-O(9) bond length is 2.39 Å. In the second Cd site, Cd(2) is bonded to one O(12), one O(13), one O(2), one O(3), and one O(9) atom to form distorted edge-sharing CdO5 trigonal bipyramids. The Cd(2)-O(12) bond length is 2.28 Å. The Cd(2)-O(13) bond length is 2.42 Å. The Cd(2)-O(2) bond length is 2.35 Å. The Cd(2)-O(3) bond length is 2.42 Å. The Cd(2)-O(9) bond length is 2.33 Å. There are sixteen inequivalent C sites. In the first C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(14) atom. The C(23)-C(24) bond length is 1.41 Å. The C(23)-H(14) bond length is 0.93 Å. In the second C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(27) atom. The C(24)-C(25) bond length is 1.32 Å. The C(24)-C(27) bond length is 1.49 Å. In the third C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(15) atom. The C(25)-H(15) bond length is 0.93 Å. In the fourth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(10), and one O(9) atom. The C(27)-O(10) bond length is 1.21 Å. The C(27)-O(9) bond length is 1.34 Å. In the fifth C site, C(30) is bonded in a distorted single-bond geometry to one C(31) and one H(18) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-H(18) bond length is 0.93 Å. In the sixth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(34) atom. The C(31)-C(32) bond length is 1.38 Å. The C(31)-C(34) bond length is 1.50 Å. In the seventh C site, C(32) is bonded in a single-bond geometry to one C(31) and one H(19) atom. The C(32)-H(19) bond length is 0.93 Å. In the eighth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(12), and one O(13) atom. The C(34)-O(12) bond length is 1.25 Å. The C(34)-O(13) bond length is 1.24 Å. In the ninth C site, C(37) is bonded in a distorted single-bond geometry to one C(38) and one H(22) atom. The C(37)-C(38) bond length is 1.38 Å. The C(37)-H(22) bond length is 0.93 Å. In the tenth C site, C(38) is bonded in a trigonal planar geometry to one C(37), one C(39), and one C(41) atom. The C(38)-C(39) bond length is 1.39 Å. The C(38)-C(41) bond length is 1.49 Å. In the eleventh C site, C(39) is bonded in a single-bond geometry to one C(38) and one H(23) atom. The C(39)-H(23) bond length is 0.93 Å. In the twelfth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(38), one O(15), and one O(16) atom. The C(41)-O(15) bond length is 1.27 Å. The C(41)-O(16) bond length is 1.26 Å. In the thirteenth C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.42 Å. The C(3)-H(2) bond length is 0.93 Å. In the fourteenth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(7) bond length is 1.46 Å. In the fifteenth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 0.93 Å. In the sixteenth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(3) atom. The C(7)-O(2) bond length is 1.21 Å. The C(7)-O(3) bond length is 1.30 Å. There are eight inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(14) is bonded in a single-bond geometry to one C(23) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(32) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one C(37) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(39) atom. There are eight inequivalent O sites. In the first O site, O(2) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(2), and one C(7) atom. In the second O site, O(3) is bonded in an L-shaped geometry to one Cd(2) and one C(7) atom. In the third O site, O(9) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(2), and one C(27) atom. In the fourth O site, O(10) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(27) atom. In the fifth O site, O(12) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(34) atom. In the sixth O site, O(13) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(34) atom. In the seventh O site, O(15) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(41) atom. In the eighth O site, O(16) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(41) atom. In each CdH6(C5O2)2 cluster, Cd(3) is bonded in a 4-coordinate geometry to one O(17), one O(18), one O(6), and one O(7) atom. The Cd(3)-O(17) bond length is 2.39 Å. The Cd(3)-O(18) bond length is 2.39 Å. The Cd(3)-O(6) bond length is 2.39 Å. The Cd(3)-O(7) bond length is 2.53 Å. There are ten inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(9)-C(10) bond length is 1.37 Å. The C(9)-H(5) bond length is 0.93 Å. In the second C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(6) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-H(6) bond length is 0.93 Å. In the third C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(42) atom. The C(11)-C(12) bond length is 1.35 Å. The C(11)-C(42) bond length is 1.47 Å. In the fourth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 0.93 Å. In the fifth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(9) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(9) bond length is 0.93 Å. In the sixth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(10) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(10) bond length is 0.93 Å. In the seventh C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-C(20) bond length is 1.46 Å. In the eighth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(11) atom. The C(18)-H(11) bond length is 0.93 Å. In the ninth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(6), and one O(7) atom. The C(20)-O(6) bond length is 1.20 Å. The C(20)-O(7) bond length is 1.23 Å. In the tenth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(17), and one O(18) atom. The C(42)-O(17) bond length is 1.20 Å. The C(42)-O(18) bond length is 1.27 Å. There are six inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(6) is bonded in a distorted water-like geometry to one Cd(3) and one C(20) atom. In the second O site, O(7) is bonded in a distorted single-bond geometry to one Cd(3) and one C(20) atom. In the third O site, O(17) is bonded in a single-bond geometry to one Cd(3) and one C(42) atom. In the fourth O site, O(18) is bonded in a distorted L-shaped geometry to one Cd(3) and one C(42) atom. Linkers: 2 [O]C(=O)c1ccc(O[P]2(Oc3ccc(C([O])=O)cc3)[N][P@]3(Oc4ccc(C([O])=O)cc4)[N][P@@](Oc4ccc(C([O])=O)cc4)([N]2)Oc2ccc(cc2)[C]2O[Cd]4(O2)O[C](O4)c2ccc(cc2)O[P@@]2(Oc4ccc(C([O])=O)cc4)[N][P](Oc4ccc(C([O])=O)cc4)(Oc4ccc(C([O])=O)cc4)[N][P@@](Oc4ccc(C([O])=O)cc4)([N]2)Oc2ccc(cc2)[C]2O[Cd]4(O[C](O4)c4ccc(cc4)O3)O2)cc1. Metal clusters: 4 [C]1O[Cd]2(O1)O[C]O[Cd]1(O[C]O1)O[C]O2. RCSR code: flu. The MOF has largest included sphere 9.04 A, density 0.97 g/cm3, surface area 3836.73 m2/g, accessible volume 0.64 cm3/g