Mo12Zn4C24N3H13O32C8N3H5 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight C8N3H5 clusters and eight Mo12Zn4C24N3H13O32 clusters. In each C8N3H5 cluster, there are eight inequivalent C sites. In the first C site, C(19) is bonded in a distorted single-bond geometry to one C(3) and one H(10) atom. The C(19)-C(3) bond length is 1.40 Å. The C(19)-H(10) bond length is 0.93 Å. In the second C site, C(29) is bonded in a distorted single-bond geometry to one C(6) and one H(17) atom. The C(29)-C(6) bond length is 1.37 Å. The C(29)-H(17) bond length is 0.93 Å. In the third C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one N(3) atom. The C(1)-C(3) bond length is 1.44 Å. The C(1)-N(2) bond length is 1.30 Å. The C(1)-N(3) bond length is 1.33 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one N(2) atom. The C(5)-C(6) bond length is 1.45 Å. The C(5)-N(1) bond length is 1.33 Å. The C(5)-N(2) bond length is 1.30 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(2), one C(29), and one C(5) atom. The C(6)-C(2) bond length is 1.41 Å. In the sixth C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(19), and one C(4) atom. The C(3)-C(4) bond length is 1.45 Å. In the seventh C site, C(2) is bonded in a distorted single-bond geometry to one C(6) and one H(2) atom. The C(2)-H(2) bond length is 0.93 Å. In the eighth C site, C(4) is bonded in a single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(3), and one H(1) atom. The N(1)-N(3) bond length is 1.34 Å. The N(1)-H(1) bond length is 0.86 Å. In the second N site, N(3) is bonded in a distorted single-bond geometry to one C(1) and one N(1) atom. In the third N site, N(2) is bonded in a water-like geometry to one C(1) and one C(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(19) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(29) atom. In each Mo12Zn4C24N3H13O32 cluster, there are twelve inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 4-coordinate geometry to one O(13), one O(25), one O(3), and one O(5) atom. The Mo(1)-O(13) bond length is 1.81 Å. The Mo(1)-O(25) bond length is 1.82 Å. The Mo(1)-O(3) bond length is 2.02 Å. The Mo(1)-O(5) bond length is 1.99 Å. In the second Mo site, Mo(2) is bonded in a distorted square co-planar geometry to one O(12), one O(13), one O(2), and one O(7) atom. The Mo(2)-O(12) bond length is 1.89 Å. The Mo(2)-O(13) bond length is 2.07 Å. The Mo(2)-O(2) bond length is 1.95 Å. The Mo(2)-O(7) bond length is 1.96 Å. In the third Mo site, Mo(3) is bonded in a distorted rectangular see-saw-like geometry to one O(19), one O(20), one O(6), and one O(9) atom. The Mo(3)-O(19) bond length is 1.98 Å. The Mo(3)-O(20) bond length is 1.78 Å. The Mo(3)-O(6) bond length is 1.99 Å. The Mo(3)-O(9) bond length is 1.82 Å. In the fourth Mo site, Mo(4) is bonded in a distorted square co-planar geometry to one O(16), one O(18), one O(4), and one O(8) atom. The Mo(4)-O(16) bond length is 2.07 Å. The Mo(4)-O(18) bond length is 2.02 Å. The Mo(4)-O(4) bond length is 1.93 Å. The Mo(4)-O(8) bond length is 1.94 Å. In the fifth Mo site, Mo(5) is bonded in a 4-coordinate geometry to one O(18), one O(19), one O(24), and one O(6) atom. The Mo(5)-O(18) bond length is 1.78 Å. The Mo(5)-O(19) bond length is 2.01 Å. The Mo(5)-O(24) bond length is 1.87 Å. The Mo(5)-O(6) bond length is 1.95 Å. In the sixth Mo site, Mo(6) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(17), one O(3), and one O(5) atom. The Mo(6)-O(11) bond length is 1.81 Å. The Mo(6)-O(17) bond length is 1.82 Å. The Mo(6)-O(3) bond length is 1.96 Å. The Mo(6)-O(5) bond length is 2.01 Å. In the seventh Mo site, Mo(7) is bonded in a distorted square co-planar geometry to one O(12), one O(25), one O(4), and one O(8) atom. The Mo(7)-O(12) bond length is 1.99 Å. The Mo(7)-O(25) bond length is 2.02 Å. The Mo(7)-O(4) bond length is 1.95 Å. The Mo(7)-O(8) bond length is 1.94 Å. In the eighth Mo site, Mo(8) is bonded in a 4-coordinate geometry to one O(2), one O(20), one O(21), and one O(7) atom. The Mo(8)-O(2) bond length is 1.94 Å. The Mo(8)-O(20) bond length is 2.05 Å. The Mo(8)-O(21) bond length is 2.06 Å. The Mo(8)-O(7) bond length is 1.95 Å. In the ninth Mo site, Mo(9) is bonded in a 4-coordinate geometry to one O(1), one O(11), one O(15), and one O(26) atom. The Mo(9)-O(1) bond length is 1.94 Å. The Mo(9)-O(11) bond length is 2.01 Å. The Mo(9)-O(15) bond length is 1.95 Å. The Mo(9)-O(26) bond length is 2.02 Å. In the tenth Mo site, Mo(10) is bonded in a 4-coordinate geometry to one O(1), one O(15), one O(21), and one O(9) atom. The Mo(10)-O(1) bond length is 1.96 Å. The Mo(10)-O(15) bond length is 1.93 Å. The Mo(10)-O(21) bond length is 2.07 Å. The Mo(10)-O(9) bond length is 2.01 Å. In the eleventh Mo site, Mo(11) is bonded in a 4-coordinate geometry to one O(10), one O(16), one O(22), and one O(24) atom. The Mo(11)-O(10) bond length is 1.96 Å. The Mo(11)-O(16) bond length is 2.08 Å. The Mo(11)-O(22) bond length is 1.95 Å. The Mo(11)-O(24) bond length is 1.97 Å. In the twelfth Mo site, Mo(12) is bonded in a 4-coordinate geometry to one O(10), one O(17), one O(22), and one O(26) atom. The Mo(12)-O(10) bond length is 1.95 Å. The Mo(12)-O(17) bond length is 1.99 Å. The Mo(12)-O(22) bond length is 1.94 Å. The Mo(12)-O(26) bond length is 2.09 Å. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one O(29), one O(6), one O(7), and one O(8) atom. The Zn(1)-O(29) bond length is 1.91 Å. The Zn(1)-O(6) bond length is 2.00 Å. The Zn(1)-O(7) bond length is 2.01 Å. The Zn(1)-O(8) bond length is 1.99 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one O(1), one O(14), one O(2), and one O(5) atom. The Zn(2)-O(1) bond length is 1.97 Å. The Zn(2)-O(14) bond length is 1.91 Å. The Zn(2)-O(2) bond length is 1.98 Å. The Zn(2)-O(5) bond length is 1.95 Å. In the third Zn site, Zn(3) is bonded in a tetrahedral geometry to one O(10), one O(23), one O(3), and one O(4) atom. The Zn(3)-O(10) bond length is 1.97 Å. The Zn(3)-O(23) bond length is 1.93 Å. The Zn(3)-O(3) bond length is 1.96 Å. The Zn(3)-O(4) bond length is 1.97 Å. In the fourth Zn site, Zn(4) is bonded in a tetrahedral geometry to one O(15), one O(19), one O(22), and one O(27) atom. The Zn(4)-O(15) bond length is 1.99 Å. The Zn(4)-O(19) bond length is 1.96 Å. The Zn(4)-O(22) bond length is 1.97 Å. The Zn(4)-O(27) bond length is 1.90 Å. There are twenty-four inequivalent C sites. In the first C site, C(7) is bonded in a 3-coordinate geometry to one C(8), one N(4), and one N(5) atom. The C(7)-C(8) bond length is 1.46 Å. The C(7)-N(4) bond length is 1.33 Å. The C(7)-N(5) bond length is 1.34 Å. In the second C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(7) atom. The C(8)-C(11) bond length is 1.43 Å. The C(8)-C(14) bond length is 1.43 Å. In the third C site, C(9) is bonded in a single-bond geometry to one C(12) and one H(4) atom. The C(9)-C(12) bond length is 1.35 Å. The C(9)-H(4) bond length is 0.93 Å. In the fourth C site, C(10) is bonded in a distorted single-bond geometry to one C(12) and one H(5) atom. The C(10)-C(12) bond length is 1.43 Å. The C(10)-H(5) bond length is 0.93 Å. In the fifth C site, C(11) is bonded in a single-bond geometry to one C(8) and one H(6) atom. The C(11)-H(6) bond length is 0.93 Å. In the sixth C site, C(12) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(9) atom. The C(12)-C(13) bond length is 1.45 Å. In the seventh C site, C(13) is bonded in a bent 120 degrees geometry to one C(12), one O(23), and one O(30) atom. The C(13)-O(23) bond length is 1.23 Å. The C(13)-O(30) bond length is 1.24 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(14)-H(7) bond length is 0.93 Å. In the ninth C site, C(15) is bonded in a 2-coordinate geometry to one C(27), one N(4), and one N(6) atom. The C(15)-C(27) bond length is 1.49 Å. The C(15)-N(4) bond length is 1.33 Å. The C(15)-N(6) bond length is 1.34 Å. In the tenth C site, C(16) is bonded in a trigonal planar geometry to one C(17), one C(22), and one C(26) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(22) bond length is 1.41 Å. The C(16)-C(26) bond length is 1.48 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(8) atom. The C(17)-H(8) bond length is 0.93 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(30) and one H(9) atom. The C(18)-C(30) bond length is 1.36 Å. The C(18)-H(9) bond length is 0.93 Å. In the thirteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(30) and one H(11) atom. The C(20)-C(30) bond length is 1.43 Å. The C(20)-H(11) bond length is 0.93 Å. In the fourteenth C site, C(21) is bonded in a trigonal planar geometry to one C(23), one C(28), and one C(32) atom. The C(21)-C(23) bond length is 1.46 Å. The C(21)-C(28) bond length is 1.42 Å. The C(21)-C(32) bond length is 1.41 Å. In the fifteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(16), one C(25), and one H(12) atom. The C(22)-C(25) bond length is 1.41 Å. The C(22)-H(12) bond length is 0.93 Å. In the sixteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(21), one O(29), and one O(31) atom. The C(23)-O(29) bond length is 1.26 Å. The C(23)-O(31) bond length is 1.23 Å. In the seventeenth C site, C(24) is bonded in a distorted single-bond geometry to one C(27) and one H(14) atom. The C(24)-C(27) bond length is 1.30 Å. The C(24)-H(14) bond length is 0.93 Å. In the eighteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(22), one C(27), and one H(15) atom. The C(25)-C(27) bond length is 1.35 Å. The C(25)-H(15) bond length is 0.93 Å. In the nineteenth C site, C(26) is bonded in a bent 120 degrees geometry to one C(16), one O(14), and one O(28) atom. The C(26)-O(14) bond length is 1.29 Å. The C(26)-O(28) bond length is 1.23 Å. In the twentieth C site, C(27) is bonded in a trigonal planar geometry to one C(15), one C(24), and one C(25) atom. In the twenty-first C site, C(28) is bonded in a distorted single-bond geometry to one C(21) and one H(16) atom. The C(28)-H(16) bond length is 0.93 Å. In the twenty-second C site, C(30) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(31) atom. The C(30)-C(31) bond length is 1.41 Å. In the twenty-third C site, C(31) is bonded in a bent 120 degrees geometry to one C(30), one O(27), and one O(32) atom. The C(31)-O(27) bond length is 1.31 Å. The C(31)-O(32) bond length is 1.26 Å. In the twenty-fourth C site, C(32) is bonded in a distorted single-bond geometry to one C(21) and one H(18) atom. The C(32)-H(18) bond length is 0.92 Å. There are three inequivalent N sites. In the first N site, N(4) is bonded in a water-like geometry to one C(15) and one C(7) atom. In the second N site, N(5) is bonded in a 2-coordinate geometry to one C(7) and one H(13) atom. The N(5)-H(13) bond length is 0.86 Å. In the third N site, N(6) is bonded in a distorted single-bond geometry to one C(15) atom. There are thirteen inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one N(5) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(28) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(32) atom. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Mo(10), one Mo(9), and one Zn(2) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mo(2), one Mo(8), and one Zn(2) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to one Mo(1), one Mo(6), and one Zn(3) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Mo(4), one Mo(7), and one Zn(3) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to one Mo(1), one Mo(6), and one Zn(2) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Mo(3), one Mo(5), and one Zn(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Mo(2), one Mo(8), and one Zn(1) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Mo(4), one Mo(7), and one Zn(1) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Mo(10) and one Mo(3) atom. In the tenth O site, O(10) is bonded in a 3-coordinate geometry to one Mo(11), one Mo(12), and one Zn(3) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Mo(6) and one Mo(9) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mo(2) and one Mo(7) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(26) atom. In the fifteenth O site, O(15) is bonded in a 3-coordinate geometry to one Mo(10), one Mo(9), and one Zn(4) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Mo(11) and one Mo(4) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Mo(12) and one Mo(6) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Mo(4) and one Mo(5) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Mo(3), one Mo(5), and one Zn(4) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Mo(3) and one Mo(8) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Mo(10) and one Mo(8) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Mo(11), one Mo(12), and one Zn(4) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(13) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Mo(11) and one Mo(5) atom. In the twenty-fifth O site, O(25) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(7) atom. In the twenty-sixth O site, O(26) is bonded in a bent 120 degrees geometry to one Mo(12) and one Mo(9) atom. In the twenty-seventh O site, O(27) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(31) atom. In the twenty-eighth O site, O(28) is bonded in a single-bond geometry to one C(26) atom. In the twenty-ninth O site, O(29) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(23) atom. In the thirtieth O site, O(30) is bonded in a single-bond geometry to one C(13) atom. In the thirty-first O site, O(31) is bonded in a single-bond geometry to one C(23) atom. In the thirty-second O site, O(32) is bonded in a single-bond geometry to one C(31) atom. Linkers: 16 [O]C(=O)c1ccc([C]2N=C(c3ccc(C([O])=O)cc3)[N]N2)cc1. Metal clusters: 8 O=[C]O[Zn].O=[C]O[Zn]O[Mo]1O[Mo]234O[Mo]25(O[Mo]2O[Mo]6(O[Zn]O[C]=O)O[Mo]78(O[Mo]7(O1)(O3)O8)O[Mo]13(O6)O[Mo]16(O[Mo](O[Zn]O[C]=O)O[Mo]17(O[Mo]1(O2)(O5)O7)O6)O3)O4. RCSR code: dia. The MOF has largest included sphere 7.86 A, density 1.30 g/cm3, surface area 2456.68 m2/g, accessible volume 0.47 cm3/g