LaC28H24(NO)8(C3H2)4 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12 space group. The structure is zero-dimensional and consists of four 2,3-dimethyl-1,3-butadiene molecules and two LaC28H24(NO)8 clusters. In each LaC28H24(NO)8 cluster, La(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Both La(1)-O(1) bond lengths are 2.46 Å. Both La(1)-O(2) bond lengths are 2.45 Å. Both La(1)-O(3) bond lengths are 2.54 Å. Both La(1)-O(4) bond lengths are 2.56 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-H(5) bond length is 0.95 Å. In the fourth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(8) bond length is 0.95 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9,12) atom. The C(11)-N(3) bond length is 1.36 Å. The C(11)-H(9,12) bond length is 0.95 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(10) bond length is 0.95 Å. In the seventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(18) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(18) bond length is 1.48 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(14)-H(11) bond length is 0.95 Å. In the ninth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9,12) atom. The C(15)-N(3) bond length is 1.35 Å. The C(15)-H(9,12) bond length is 0.95 Å. In the tenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(4), and one H(13) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-N(4) bond length is 1.34 Å. The C(16)-H(13) bond length is 0.95 Å. In the eleventh C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(14) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(14) bond length is 0.95 Å. In the twelfth C site, C(18) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(19) atom. The C(18)-C(19) bond length is 1.38 Å. In the thirteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(15) atom. The C(19)-H(15) bond length is 0.95 Å. In the fourteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(16) atom. The C(20)-N(4) bond length is 1.36 Å. The C(20)-H(16) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(5), and one O(1) atom. The N(1)-O(1) bond length is 1.34 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(6), and one O(2) atom. The N(2)-O(2) bond length is 1.33 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(11), one C(15), and one O(3) atom. The N(3)-O(3) bond length is 1.32 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(16), one C(20), and one O(4) atom. The N(4)-O(4) bond length is 1.32 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(9,12) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one La(1) and one N(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one La(1) and one N(2) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one La(1) and one N(3) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one La(1) and one N(4) atom. Linkers: 8 [O-][n+]1ccc(-c2cc[n+]([O-])cc2)cc1. Metal clusters: 2 [O][La]([O])([O])([O])([O])([O])([O])[O]. RCSR code: pcu. The MOF has largest included sphere 9.56 A, density 0.68 g/cm3, surface area 4441.11 m2/g, accessible volume 1.12 cm3/g