Zn3C24N3H18O10(CH)3 crystallizes in the orthorhombic Pnn2 space group. The structure consists of twelve 02329_fluka molecules inside a Zn3C24N3H18O10 framework. In the Zn3C24N3H18O10 framework, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted trigonal pyramidal geometry to one N(1), one O(1), one O(5), and one O(9) atom. The Zn(1)-N(1) bond length is 2.06 Å. The Zn(1)-O(1) bond length is 2.00 Å. The Zn(1)-O(5) bond length is 1.97 Å. The Zn(1)-O(9) bond length is 1.87 Å. In the second Zn site, Zn(2) is bonded in a rectangular see-saw-like geometry to one O(10), one O(2), one O(7), and one O(9) atom. The Zn(2)-O(10) bond length is 1.99 Å. The Zn(2)-O(2) bond length is 2.13 Å. The Zn(2)-O(7) bond length is 2.12 Å. The Zn(2)-O(9) bond length is 1.98 Å. In the third Zn site, Zn(3) is bonded in a distorted trigonal pyramidal geometry to one N(3), one O(10), one O(3), and one O(8) atom. The Zn(3)-N(3) bond length is 2.08 Å. The Zn(3)-O(10) bond length is 1.87 Å. The Zn(3)-O(3) bond length is 1.96 Å. The Zn(3)-O(8) bond length is 1.98 Å. There are twenty-five inequivalent C sites. In the first C site, C(26) is bonded in a distorted single-bond geometry to two equivalent C(10) and one H(20) atom. Both C(26)-C(10) bond lengths are 1.40 Å. The C(26)-H(20) bond length is 0.93 Å. In the second C site, C(28) is bonded in a single-bond geometry to two equivalent C(13) and one H(22) atom. Both C(28)-C(13) bond lengths are 1.39 Å. The C(28)-H(22) bond length is 0.93 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.24 Å. In the fourth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(7) bond length is 1.40 Å. In the fifth C site, C(3) is bonded in a single-bond geometry to one C(2), one C(4), and one H(4) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(4) bond length is 0.93 Å. In the sixth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-C(8) bond length is 1.50 Å. In the seventh C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(5) atom. The C(5)-H(5) bond length is 0.93 Å. In the eighth C site, C(7) is bonded in a single-bond geometry to one C(2) and one H(7) atom. The C(7)-H(7) bond length is 0.93 Å. In the ninth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.28 Å. The C(8)-O(4) bond length is 1.22 Å. In the tenth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(5), and one O(6) atom. The C(9)-C(10) bond length is 1.50 Å. The C(9)-O(5) bond length is 1.28 Å. The C(9)-O(6) bond length is 1.23 Å. In the eleventh C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(26), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. In the twelfth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(11)-H(8) bond length is 0.93 Å. In the thirteenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(7), and one O(8) atom. The C(12)-C(13) bond length is 1.51 Å. The C(12)-O(7) bond length is 1.23 Å. The C(12)-O(8) bond length is 1.26 Å. In the fourteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(28) atom. The C(13)-C(14) bond length is 1.38 Å. In the fifteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(9) atom. The C(14)-H(9) bond length is 0.93 Å. In the sixteenth C site, C(15) is bonded in a 3-coordinate geometry to one C(16), one N(1), and one H(10) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-N(1) bond length is 1.33 Å. The C(15)-H(10) bond length is 0.93 Å. In the seventeenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(20) atom. The C(16)-C(17) bond length is 1.35 Å. The C(16)-C(20) bond length is 1.48 Å. In the eighteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(17)-H(11) bond length is 0.93 Å. In the nineteenth C site, C(18) is bonded in a single-bond geometry to one C(19) and one H(12) atom. The C(18)-C(19) bond length is 1.38 Å. The C(18)-H(12) bond length is 0.93 Å. In the twentieth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(1), and one H(13) atom. The C(19)-N(1) bond length is 1.34 Å. The C(19)-H(13) bond length is 0.93 Å. In the twenty-first C site, C(20) is bonded in a 3-coordinate geometry to one C(16); one N(2); and two equivalent H(14,15) atoms. The C(20)-N(2) bond length is 1.45 Å. Both C(20)-H(14,15) bond lengths are 0.97 Å. In the twenty-second C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(16) atom. The C(21)-N(3) bond length is 1.33 Å. The C(21)-H(16) bond length is 0.93 Å. In the twenty-third C site, C(22) is bonded in a distorted single-bond geometry to one N(2) atom. The C(22)-N(2) bond length is 1.39 Å. In the twenty-fourth C site, C(24) is bonded in a single-bond geometry to one C(25) and one H(18) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-H(18) bond length is 0.93 Å. In the twenty-fifth C site, C(25) is bonded in a 3-coordinate geometry to one C(24), one N(3), and one H(19) atom. The C(25)-N(3) bond length is 1.32 Å. The C(25)-H(19) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(19) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(20), one C(22), and one H(3) atom. The N(2)-H(3) bond length is 0.86 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(3), one C(21), and one C(25) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(9) atom. The H(1)-O(9) bond length is 0.85 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. The H(2)-O(10) bond length is 0.85 Å. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(14,15) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(26) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(28) atom. There are ten inequivalent O sites. In the first O site, O(9) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(2), and one H(1) atom. In the second O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(12) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the fourth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(1) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(8) atom. In the sixth O site, O(4) is bonded in a single-bond geometry to one C(8) atom. In the seventh O site, O(5) is bonded in a water-like geometry to one Zn(1) and one C(9) atom. In the eighth O site, O(6) is bonded in a single-bond geometry to one C(9) atom. In the ninth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(12) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Zn(2), one Zn(3), and one H(2) atom. Linkers: 8 [O]C(=O)c1cccc(C([O])=O)c1 ,4 c1cncc(CNc2cccnc2)c1. Metal clusters: 4 O=[C]O[Zn](O)O[C]O[Zn]O[C]O[Zn](O)O[C]=O. RCSR code: dmp. The MOF has largest included sphere 4.96 A, density 1.37 g/cm3, surface area 4140.64 m2/g, accessible volume 0.33 cm3/g