LiC3NH2O(CH)2 is Indium-derived structured and crystallizes in the tetragonal P-42c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and two LiC3NH2O clusters. In each LiC3NH2O cluster, Li(1) is bonded in a rectangular see-saw-like geometry to one N(1) and three equivalent O(1) atoms. The Li(1)-N(1) bond length is 1.99 Å. There are two shorter (1.96 Å) and one longer (1.97 Å) Li(1)-O(1) bond length. There are three inequivalent C sites. In the first C site, C(5) is bonded in a distorted single-bond geometry to one O(1) atom. The C(5)-O(1) bond length is 1.32 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(3)-N(1) bond length is 1.31 Å. The C(3)-H(3) bond length is 0.93 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(4)-N(1) bond length is 1.28 Å. The C(4)-H(4) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Li(1), one C(3), and one C(4) atom. There are two inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(4) atom. O(1) is bonded in a rectangular see-saw-like geometry to three equivalent Li(1) and one C(5) atom. Linkers: 8 [O]c1ccncc1. Metal clusters: 2 [Li][O].[Li][O].[Li][O].[Li][O]. The MOF has largest included sphere 4.15 A, density 1.01 g/cm3, surface area 5113.29 m2/g, accessible volume 0.40 cm3/g