Cu7C15N15H9I4(CH)3 crystallizes in the trigonal P-3c1 space group. The structure consists of twelve 02329_fluka molecules inside a Cu7C15N15H9I4 framework. In the Cu7C15N15H9I4 framework, there are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 4-coordinate geometry to one Cu(3), one N(1), one N(2), and two equivalent I(1) atoms. The Cu(1)-Cu(3) bond length is 2.74 Å. The Cu(1)-N(1) bond length is 2.05 Å. The Cu(1)-N(2) bond length is 2.02 Å. Both Cu(1)-I(1) bond lengths are 2.63 Å. In the second Cu site, Cu(2) is bonded to one N(4), one N(5), one I(1), and one I(2) atom to form distorted corner-sharing CuI2N2 tetrahedra. The Cu(2)-N(4) bond length is 2.03 Å. The Cu(2)-N(5) bond length is 2.04 Å. The Cu(2)-I(1) bond length is 2.78 Å. The Cu(2)-I(2) bond length is 2.69 Å. In the third Cu site, Cu(3) is bonded in a distorted trigonal non-coplanar geometry to three equivalent Cu(1) and three equivalent I(1) atoms. All Cu(3)-I(1) bond lengths are 2.76 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(5), and one H(1) atom. The C(1)-C(3) bond length is 1.42 Å. The C(1)-N(5) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a 2-coordinate geometry to one C(3), one N(3), and one N(4) atom. The C(2)-C(3) bond length is 1.48 Å. The C(2)-N(3) bond length is 1.35 Å. The C(2)-N(4) bond length is 1.35 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(6) atom. The C(3)-C(6) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(2) atom. The C(4)-N(5) bond length is 1.36 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a single-bond geometry to one C(3) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one N(2), and one N(4) atom. The N(1)-N(2) bond length is 1.33 Å. The N(1)-N(4) bond length is 1.34 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(1), one N(1), and one N(3) atom. The N(2)-N(3) bond length is 1.35 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(2) and one N(2) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one Cu(2), one C(2), and one N(1) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(2), one C(1), and one C(4) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent I sites. In the first I site, I(2) is bonded in a trigonal non-coplanar geometry to three equivalent Cu(2) atoms. In the second I site, I(1) is bonded in a 4-coordinate geometry to one Cu(2), one Cu(3), and two equivalent Cu(1) atoms. Linkers: 10 c1cncc(C2=NN=N[N]2)c1 ,2 c1cncc(C2=N[N]N=N2)c1. Metal clusters: 28 [Cu]. The MOF has largest included sphere 8.37 A, density 2.22 g/cm3, surface area 2506.92 m2/g, accessible volume 0.23 cm3/g