KNiC39N4H22O9(CH)7(CH2CO)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of fourteen 02329_fluka molecules, six dimethyl ether molecules, and one KNiC39N4H22O9 cluster. In the KNiC39N4H22O9 cluster, K(1) is bonded in a 7-coordinate geometry to one O(12), one O(2), one O(5), one O(6), one O(7), and two equivalent O(9) atoms. The K(1)-O(12) bond length is 2.84 Å. The K(1)-O(2) bond length is 2.70 Å. The K(1)-O(5) bond length is 2.85 Å. The K(1)-O(6) bond length is 2.99 Å. The K(1)-O(7) bond length is 3.13 Å. There is one shorter (2.75 Å) and one longer (2.91 Å) K(1)-O(9) bond length. Ni(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Ni(1)-N(1) bond length is 1.94 Å. The Ni(1)-N(2) bond length is 1.93 Å. The Ni(1)-N(3) bond length is 1.95 Å. The Ni(1)-N(4) bond length is 1.94 Å. There are thirty-nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(20), and one N(1) atom. The C(1)-C(2) bond length is 1.43 Å. The C(1)-C(20) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.38 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.43 Å. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-N(1) bond length is 1.38 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(21), one C(4), and one C(6) atom. The C(5)-C(21) bond length is 1.50 Å. The C(5)-C(6) bond length is 1.38 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.42 Å. The C(6)-N(2) bond length is 1.38 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(7)-H(3) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(8)-C(9) bond length is 1.44 Å. The C(8)-H(4) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(2) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-N(2) bond length is 1.37 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(29), and one C(9) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(29) bond length is 1.49 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(3) atom. The C(11)-C(12) bond length is 1.43 Å. The C(11)-N(3) bond length is 1.37 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(5) atom. The C(12)-H(5) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(6) atom. The C(13)-C(14) bond length is 1.43 Å. The C(13)-H(6) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one N(3) atom. The C(14)-C(15) bond length is 1.38 Å. The C(14)-N(3) bond length is 1.39 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(37) atom. The C(15)-C(16) bond length is 1.37 Å. The C(15)-C(37) bond length is 1.49 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one N(4) atom. The C(16)-C(17) bond length is 1.42 Å. The C(16)-N(4) bond length is 1.39 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(7) atom. The C(17)-H(7) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(8) atom. The C(18)-C(19) bond length is 1.45 Å. The C(18)-H(8) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one N(4) atom. The C(19)-C(20) bond length is 1.38 Å. The C(19)-N(4) bond length is 1.36 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(1), one C(19), and one C(45) atom. The C(20)-C(45) bond length is 1.50 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(22), one C(26), and one C(5) atom. The C(21)-C(22) bond length is 1.37 Å. The C(21)-C(26) bond length is 1.38 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(9) atom. The C(22)-H(9) bond length is 0.93 Å. In the twenty-third C site, C(26) is bonded in a distorted single-bond geometry to one C(21) and one H(12) atom. The C(26)-H(12) bond length is 0.93 Å. In the twenty-fourth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(28)-O(2) bond length is 1.17 Å. The C(28)-O(3) bond length is 1.27 Å. In the twenty-fifth C site, C(29) is bonded in a trigonal planar geometry to one C(10), one C(30), and one C(34) atom. The C(29)-C(30) bond length is 1.38 Å. The C(29)-C(34) bond length is 1.39 Å. In the twenty-sixth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(16) atom. The C(30)-H(16) bond length is 0.93 Å. In the twenty-seventh C site, C(34) is bonded in a distorted single-bond geometry to one C(29) and one H(19) atom. The C(34)-H(19) bond length is 0.93 Å. In the twenty-eighth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(36)-O(5) bond length is 1.23 Å. The C(36)-O(6) bond length is 1.25 Å. In the twenty-ninth C site, C(37) is bonded in a trigonal planar geometry to one C(15), one C(38), and one C(42) atom. The C(37)-C(38) bond length is 1.37 Å. The C(37)-C(42) bond length is 1.38 Å. In the thirtieth C site, C(38) is bonded in a distorted single-bond geometry to one C(37), one C(39), and one H(22) atom. The C(38)-C(39) bond length is 1.38 Å. The C(38)-H(22) bond length is 0.93 Å. In the thirty-first C site, C(39) is bonded in a distorted trigonal planar geometry to one C(38), one C(40), and one H(23) atom. The C(39)-C(40) bond length is 1.37 Å. The C(39)-H(23) bond length is 0.93 Å. In the thirty-second C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one O(7) atom. The C(40)-O(7) bond length is 1.38 Å. In the thirty-third C site, C(42) is bonded in a distorted single-bond geometry to one C(37) and one H(25) atom. The C(42)-H(25) bond length is 0.93 Å. In the thirty-fourth C site, C(43) is bonded in a distorted trigonal non-coplanar geometry to one C(44); two equivalent H(26,27); and one O(7) atom. The C(43)-C(44) bond length is 1.51 Å. Both C(43)-H(26,27) bond lengths are 0.97 Å. The C(43)-O(7) bond length is 1.40 Å. In the thirty-fifth C site, C(44) is bonded in a distorted trigonal planar geometry to one C(43), one O(8), and one O(9) atom. The C(44)-O(8) bond length is 1.30 Å. The C(44)-O(9) bond length is 1.19 Å. In the thirty-sixth C site, C(45) is bonded in a trigonal planar geometry to one C(20), one C(46), and one C(50) atom. The C(45)-C(46) bond length is 1.37 Å. The C(45)-C(50) bond length is 1.39 Å. In the thirty-seventh C site, C(46) is bonded in a distorted single-bond geometry to one C(45) and one H(29) atom. The C(46)-H(29) bond length is 0.93 Å. In the thirty-eighth C site, C(50) is bonded in a distorted single-bond geometry to one C(45) and one H(32) atom. The C(50)-H(32) bond length is 0.93 Å. In the thirty-ninth C site, C(52) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. The C(52)-O(11) bond length is 1.32 Å. The C(52)-O(12) bond length is 1.18 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ni(1), one C(6), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ni(1), one C(11), and one C(14) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ni(1), one C(16), and one C(19) atom. There are twenty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one O(3) atom. The H(15)-O(3) bond length is 0.82 Å. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(30) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(34) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(38) atom. In the fifteenth H site, H(23) is bonded in a single-bond geometry to one C(39) atom. In the sixteenth H site, H(25) is bonded in a single-bond geometry to one C(42) atom. In the seventeenth H site, H(26,27) is bonded in a single-bond geometry to one C(43) atom. In the eighteenth H site, H(28) is bonded in a single-bond geometry to one O(8) atom. The H(28)-O(8) bond length is 0.82 Å. In the nineteenth H site, H(29) is bonded in a single-bond geometry to one C(46) atom. In the twentieth H site, H(32) is bonded in a single-bond geometry to one C(50) atom. In the twenty-first H site, H(35) is bonded in a single-bond geometry to one O(11) atom. The H(35)-O(11) bond length is 0.82 Å. There are nine inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 150 degrees geometry to one K(1) and one C(28) atom. In the second O site, O(3) is bonded in a water-like geometry to one C(28) and one H(15) atom. In the third O site, O(5) is bonded in a single-bond geometry to one K(1) and one C(36) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one K(1) and one C(36) atom. In the fifth O site, O(7) is bonded in a bent 120 degrees geometry to one K(1), one C(40), and one C(43) atom. In the sixth O site, O(8) is bonded in a water-like geometry to one C(44) and one H(28) atom. In the seventh O site, O(9) is bonded in a 3-coordinate geometry to two equivalent K(1) and one C(44) atom. In the eighth O site, O(11) is bonded in a water-like geometry to one C(52) and one H(35) atom. In the ninth O site, O(12) is bonded in a single-bond geometry to one K(1) and one C(52) atom. Linkers: 1 OC(=O)COc1ccc(cc1)C1=c2ccc3=C(C4=[N]5[Ni@]6([N]7=C1C=CC7=C(c1ccc(cc1)OCC(=O)[O])c1n6c(C(=C5C=C4)c4ccc(cc4)[O])cc1)n23)c1ccc(cc1)OCC(=O)O ,1 OC(=O)COc1ccc(cc1)C1=c2ccc3=C(C4=[N]5[Ni@@]6([N]7=C1C=CC7=C(c1ccc(cc1)OCC(=O)O)c1n6c(C(=C5C=C4)c4ccc(cc4)[O])cc1)n23)c1ccc(cc1)OCC(=O)[O]. Metal clusters: 1 O=[C]O.O=[C]O.O[C]O[K].O[C]O[K].[O]CC(=O)O.[O]CC(=O)O.[O][C]=O.[O][C]=O. RCSR code: kgd. The MOF has largest included sphere 7.29 A, density 1.08 g/cm3, surface area 4459.08 m2/g, accessible volume 0.38 cm3/g