In2C10H3(NO7)2 crystallizes in the orthorhombic Pbca space group. There are two inequivalent In sites. In the first In site, In(1) is bonded in a distorted pentagonal bipyramidal geometry to one N(1), one O(1), one O(13), one O(14), one O(2), one O(5), and one O(6) atom. The In(1)-N(1) bond length is 2.18 Å. The In(1)-O(1) bond length is 2.20 Å. The In(1)-O(13) bond length is 2.22 Å. The In(1)-O(14) bond length is 2.21 Å. The In(1)-O(2) bond length is 2.31 Å. The In(1)-O(5) bond length is 2.22 Å. The In(1)-O(6) bond length is 2.27 Å. In the second In site, In(2) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(12), one O(3), one O(4), one O(7), one O(8), and one O(9) atom. The In(2)-O(10) bond length is 2.28 Å. The In(2)-O(11) bond length is 2.26 Å. The In(2)-O(12) bond length is 2.29 Å. The In(2)-O(3) bond length is 2.27 Å. The In(2)-O(4) bond length is 2.33 Å. The In(2)-O(7) bond length is 2.21 Å. The In(2)-O(8) bond length is 2.32 Å. The In(2)-O(9) bond length is 2.18 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(4) bond length is 1.24 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(2)-O(2) bond length is 1.23 Å. The C(2)-O(3) bond length is 1.26 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(3)-O(5) bond length is 1.26 Å. The C(3)-O(6) bond length is 1.25 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(7) atom. The C(4)-O(10) bond length is 1.24 Å. The C(4)-O(7) bond length is 1.26 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(8) and one O(9) atom. The C(5)-O(8) bond length is 1.24 Å. The C(5)-O(9) bond length is 1.27 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(14) atom. The C(6)-O(11) bond length is 1.26 Å. The C(6)-O(14) bond length is 1.26 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(12) and one O(13) atom. The C(7)-O(12) bond length is 1.25 Å. The C(7)-O(13) bond length is 1.25 Å. In the eighth C site, C(8) is bonded in a 2-coordinate geometry to one C(10), one N(1), and one H(1) atom. The C(8)-C(10) bond length is 1.35 Å. The C(8)-N(1) bond length is 1.38 Å. The C(8)-H(1) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(2) atom. The C(9)-N(1) bond length is 1.33 Å. The C(9)-N(2) bond length is 1.32 Å. The C(9)-H(2) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a 3-coordinate geometry to one C(8), one N(2), and one H(3) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(3) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one In(1), one C(8), and one C(9) atom. In the second N site, N(2) is bonded in a water-like geometry to one C(10) and one C(9) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(10) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one In(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one In(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one In(2) and one C(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one In(2) and one C(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one In(1) and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one In(1) and one C(3) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one In(2) and one C(4) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one In(2) and one C(5) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one In(2) and one C(5) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one In(2) and one C(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one In(2) and one C(6) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one In(2) and one C(7) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one In(1) and one C(7) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one In(1) and one C(6) atom. Linkers: 27 [O]C(=O)C([O])=O. Metal clusters: 16 [In]. The MOF has largest included sphere 5.92 A, density 1.63 g/cm3, surface area 2833.97 m2/g, accessible volume 0.32 cm3/g