Na2Co3C130H130S8(N2O7)4(CH)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two Na2Co3C130H130S8(N2O7)4 clusters. In each Na2Co3C130H130S8(N2O7)4 cluster, Na(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(3), one O(7), and one O(9) atom. The Na(1)-O(1) bond length is 2.47 Å. The Na(1)-O(3) bond length is 2.29 Å. The Na(1)-O(7) bond length is 2.50 Å. The Na(1)-O(9) bond length is 2.26 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a tetrahedral geometry to one N(4), one O(11), one O(5), and one O(8) atom. The Co(1)-N(4) bond length is 2.03 Å. The Co(1)-O(11) bond length is 1.96 Å. The Co(1)-O(5) bond length is 1.93 Å. The Co(1)-O(8) bond length is 1.95 Å. In the second Co site, Co(2) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(2) atoms. Both Co(2)-N(1) bond lengths are 2.13 Å. Both Co(2)-O(2) bond lengths are 2.09 Å. There are sixty-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one O(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.38 Å. The C(1)-O(1) bond length is 1.39 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one S(4) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-S(4) bond length is 1.78 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(33), and one C(5) atom. The C(4)-C(33) bond length is 1.54 Å. The C(4)-C(5) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(2) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(2) bond length is 0.95 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one S(1) atom. The C(6)-S(1) bond length is 1.78 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one O(4) atom. The C(7)-C(12) bond length is 1.39 Å. The C(7)-C(8) bond length is 1.39 Å. The C(7)-O(4) bond length is 1.38 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(7), one C(9), and one S(1) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-S(1) bond length is 1.78 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(3) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(3) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(37), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(37) bond length is 1.53 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(4) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-H(4) bond length is 0.95 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(7), and one S(2) atom. The C(12)-S(2) bond length is 1.77 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one O(7) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-C(18) bond length is 1.40 Å. The C(13)-O(7) bond length is 1.38 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one S(2) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-S(2) bond length is 1.78 Å. In the fifteenth C site, C(15) is bonded in a single-bond geometry to one C(14), one C(16), and one H(5) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-H(5) bond length is 0.95 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(41) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-C(41) bond length is 1.54 Å. In the seventeenth C site, C(17) is bonded in a single-bond geometry to one C(16), one C(18), and one H(6) atom. The C(17)-C(18) bond length is 1.37 Å. The C(17)-H(6) bond length is 0.95 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(13), one C(17), and one S(3) atom. The C(18)-S(3) bond length is 1.77 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(20), one C(24), and one O(10) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-C(24) bond length is 1.40 Å. The C(19)-O(10) bond length is 1.37 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one S(3) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-S(3) bond length is 1.76 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one H(7) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(7) bond length is 0.95 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(45) atom. The C(22)-C(23) bond length is 1.41 Å. The C(22)-C(45) bond length is 1.53 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(22), one C(24), and one H(8) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-H(8) bond length is 0.95 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(19), one C(23), and one S(4) atom. The C(24)-S(4) bond length is 1.78 Å. In the twenty-fifth C site, C(25) is bonded in a distorted trigonal non-coplanar geometry to one H(10), one H(9), and one O(1) atom. The C(25)-H(10) bond length is 0.99 Å. The C(25)-H(9) bond length is 0.99 Å. The C(25)-O(1) bond length is 1.44 Å. In the twenty-sixth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(26)-O(2) bond length is 1.26 Å. The C(26)-O(3) bond length is 1.25 Å. In the twenty-seventh C site, C(27) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(11,12) and one O(4) atom. Both C(27)-H(11,12) bond lengths are 0.99 Å. The C(27)-O(4) bond length is 1.43 Å. In the twenty-eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(28)-O(5) bond length is 1.27 Å. The C(28)-O(6) bond length is 1.21 Å. In the twenty-ninth C site, C(29) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(13,14) and one O(7) atom. Both C(29)-H(13,14) bond lengths are 0.99 Å. The C(29)-O(7) bond length is 1.45 Å. In the thirtieth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one O(8) and one O(9) atom. The C(30)-O(8) bond length is 1.28 Å. The C(30)-O(9) bond length is 1.23 Å. In the thirty-first C site, C(31) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(15,16) and one O(10) atom. Both C(31)-H(15,16) bond lengths are 0.99 Å. The C(31)-O(10) bond length is 1.44 Å. In the thirty-second C site, C(32) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. The C(32)-O(11) bond length is 1.26 Å. The C(32)-O(12) bond length is 1.23 Å. In the thirty-third C site, C(33) is bonded in a tetrahedral geometry to one C(34), one C(35), one C(36), and one C(4) atom. The C(33)-C(34) bond length is 1.52 Å. The C(33)-C(35) bond length is 1.51 Å. The C(33)-C(36) bond length is 1.52 Å. In the thirty-fourth C site, C(34) is bonded in a trigonal non-coplanar geometry to one C(33); one H(18); and two equivalent H(17,19,20,21,22,25) atoms. The C(34)-H(18) bond length is 0.98 Å. Both C(34)-H(17,19,20,21,22,25) bond lengths are 0.98 Å. In the thirty-fifth C site, C(35) is bonded in a trigonal non-coplanar geometry to one C(33) and three equivalent H(17,19,20,21,22,25) atoms. All C(35)-H(17,19,20,21,22,25) bond lengths are 0.98 Å. In the thirty-sixth C site, C(36) is bonded in a trigonal non-coplanar geometry to one C(33); one H(17,19,20,21,22,25); and two equivalent H(23,24) atoms. The C(36)-H(17,19,20,21,22,25) bond length is 0.98 Å. Both C(36)-H(23,24) bond lengths are 0.98 Å. In the thirty-seventh C site, C(37) is bonded in a tetrahedral geometry to one C(10), one C(38), one C(39), and one C(40) atom. The C(37)-C(38) bond length is 1.54 Å. The C(37)-C(39) bond length is 1.64 Å. The C(37)-C(40) bond length is 1.45 Å. In the thirty-eighth C site, C(38) is bonded in a trigonal non-coplanar geometry to one C(37) and three equivalent H(26,27,28,29,31) atoms. All C(38)-H(26,27,28,29,31) bond lengths are 0.98 Å. In the thirty-ninth C site, C(39) is bonded in a trigonal non-coplanar geometry to one C(37); one H(30); and two equivalent H(26,27,28,29,31) atoms. The C(39)-H(30) bond length is 0.98 Å. Both C(39)-H(26,27,28,29,31) bond lengths are 0.98 Å. In the fortieth C site, C(40) is bonded in a trigonal non-coplanar geometry to one C(37); one H(33); and two equivalent H(32,34) atoms. The C(40)-H(33) bond length is 0.98 Å. Both C(40)-H(32,34) bond lengths are 0.98 Å. In the forty-first C site, C(41) is bonded in a tetrahedral geometry to one C(16), one C(42), one C(43), and one C(44) atom. The C(41)-C(42) bond length is 1.52 Å. The C(41)-C(43) bond length is 1.53 Å. The C(41)-C(44) bond length is 1.51 Å. In the forty-second C site, C(42) is bonded in a trigonal non-coplanar geometry to one C(41) and three equivalent H(35,36,37,38,39,40,43) atoms. All C(42)-H(35,36,37,38,39,40,43) bond lengths are 0.98 Å. In the forty-third C site, C(43) is bonded in a trigonal non-coplanar geometry to one C(41) and three equivalent H(35,36,37,38,39,40,43) atoms. All C(43)-H(35,36,37,38,39,40,43) bond lengths are 0.98 Å. In the forty-fourth C site, C(44) is bonded in a trigonal non-coplanar geometry to one C(41); one H(35,36,37,38,39,40,43); and two equivalent H(41,42) atoms. The C(44)-H(35,36,37,38,39,40,43) bond length is 0.98 Å. Both C(44)-H(41,42) bond lengths are 0.98 Å. In the forty-fifth C site, C(45) is bonded in a tetrahedral geometry to one C(22), one C(46), one C(47), and one C(48) atom. The C(45)-C(46) bond length is 1.53 Å. The C(45)-C(47) bond length is 1.51 Å. The C(45)-C(48) bond length is 1.53 Å. In the forty-sixth C site, C(46) is bonded in a trigonal non-coplanar geometry to one C(45); one H(45); and two equivalent H(44,46,47,50,51,52) atoms. The C(46)-H(45) bond length is 0.98 Å. Both C(46)-H(44,46,47,50,51,52) bond lengths are 0.98 Å. In the forty-seventh C site, C(47) is bonded in a trigonal non-coplanar geometry to one C(45); one H(44,46,47,50,51,52); and two equivalent H(48,49) atoms. The C(47)-H(44,46,47,50,51,52) bond length is 0.98 Å. Both C(47)-H(48,49) bond lengths are 0.98 Å. In the forty-eighth C site, C(48) is bonded in a trigonal non-coplanar geometry to one C(45) and three equivalent H(44,46,47,50,51,52) atoms. All C(48)-H(44,46,47,50,51,52) bond lengths are 0.98 Å. In the forty-ninth C site, C(49) is bonded in a distorted single-bond geometry to one C(53) and one H(55) atom. The C(49)-C(53) bond length is 1.40 Å. The C(49)-H(55) bond length is 0.95 Å. In the fiftieth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(56) atom. The C(50)-N(1) bond length is 1.33 Å. The C(50)-H(56) bond length is 0.95 Å. In the fifty-first C site, C(51) is bonded in a distorted trigonal planar geometry to one C(52), one N(1), and one H(57) atom. The C(51)-C(52) bond length is 1.35 Å. The C(51)-N(1) bond length is 1.35 Å. The C(51)-H(57) bond length is 0.95 Å. In the fifty-second C site, C(52) is bonded in a distorted single-bond geometry to one C(51), one C(53), and one H(58) atom. The C(52)-C(53) bond length is 1.40 Å. The C(52)-H(58) bond length is 0.95 Å. In the fifty-third C site, C(53) is bonded in a distorted trigonal planar geometry to one C(49), one C(52), and one N(2) atom. The C(53)-N(2) bond length is 1.38 Å. In the fifty-fourth C site, C(54) is bonded in a distorted bent 120 degrees geometry to one C(55), one N(2), and one O(13) atom. The C(54)-C(55) bond length is 1.50 Å. The C(54)-N(2) bond length is 1.37 Å. The C(54)-O(13) bond length is 1.23 Å. In the fifty-fifth C site, C(55) is bonded in a trigonal planar geometry to one C(54), one C(56), and one C(60) atom. The C(55)-C(56) bond length is 1.38 Å. The C(55)-C(60) bond length is 1.39 Å. In the fifty-sixth C site, C(56) is bonded in a distorted single-bond geometry to one C(55) and one H(59) atom. The C(56)-H(59) bond length is 0.95 Å. In the fifty-seventh C site, C(58) is bonded in a distorted single-bond geometry to one C(59) and one H(61) atom. The C(58)-C(59) bond length is 1.41 Å. The C(58)-H(61) bond length is 0.95 Å. In the fifty-eighth C site, C(59) is bonded in a trigonal planar geometry to one C(58), one C(60), and one C(61) atom. The C(59)-C(60) bond length is 1.37 Å. The C(59)-C(61) bond length is 1.48 Å. In the fifty-ninth C site, C(60) is bonded in a distorted single-bond geometry to one C(55), one C(59), and one H(62) atom. The C(60)-H(62) bond length is 0.95 Å. In the sixtieth C site, C(61) is bonded in a distorted bent 120 degrees geometry to one C(59), one N(3), and one O(14) atom. The C(61)-N(3) bond length is 1.35 Å. The C(61)-O(14) bond length is 1.24 Å. In the sixty-first C site, C(62) is bonded in a distorted trigonal planar geometry to one C(63), one C(66), and one N(3) atom. The C(62)-C(63) bond length is 1.38 Å. The C(62)-C(66) bond length is 1.38 Å. The C(62)-N(3) bond length is 1.39 Å. In the sixty-second C site, C(63) is bonded in a distorted single-bond geometry to one C(62) and one H(63,66) atom. The C(63)-H(63,66) bond length is 0.95 Å. In the sixty-third C site, C(64) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(64) atom. The C(64)-N(4) bond length is 1.32 Å. The C(64)-H(64) bond length is 0.95 Å. In the sixty-fourth C site, C(65) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(65) atom. The C(65)-N(4) bond length is 1.35 Å. The C(65)-H(65) bond length is 0.95 Å. In the sixty-fifth C site, C(66) is bonded in a distorted single-bond geometry to one C(62) and one H(63,66) atom. The C(66)-H(63,66) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(2), one C(50), and one C(51) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(53), one C(54), and one H(53) atom. The N(2)-H(53) bond length is 0.88 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(61), one C(62), and one H(54) atom. The N(3)-H(54) bond length is 0.88 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(64), and one C(65) atom. There are thirty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(25) atom. In the eleventh H site, H(11,12) is bonded in a single-bond geometry to one C(27) atom. In the twelfth H site, H(13,14) is bonded in a single-bond geometry to one C(29) atom. In the thirteenth H site, H(15,16) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(17,19,20,21,22,25) is bonded in a single-bond geometry to one C(34) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(34) atom. In the sixteenth H site, H(23,24) is bonded in a single-bond geometry to one C(36) atom. In the seventeenth H site, H(26,27,28,29,31) is bonded in a single-bond geometry to one C(38) atom. In the eighteenth H site, H(30) is bonded in a single-bond geometry to one C(39) atom. In the nineteenth H site, H(32,34) is bonded in a single-bond geometry to one C(40) atom. In the twentieth H site, H(33) is bonded in a single-bond geometry to one C(40) atom. In the twenty-first H site, H(35,36,37,38,39,40,43) is bonded in a single-bond geometry to one C(42) atom. In the twenty-second H site, H(41,42) is bonded in a single-bond geometry to one C(44) atom. In the twenty-third H site, H(44,46,47,50,51,52) is bonded in a single-bond geometry to one C(46) atom. In the twenty-fourth H site, H(45) is bonded in a single-bond geometry to one C(46) atom. In the twenty-fifth H site, H(48,49) is bonded in a single-bond geometry to one C(47) atom. In the twenty-sixth H site, H(53) is bonded in a single-bond geometry to one N(2) atom. In the twenty-seventh H site, H(54) is bonded in a single-bond geometry to one N(3) atom. In the twenty-eighth H site, H(55) is bonded in a single-bond geometry to one C(49) atom. In the twenty-ninth H site, H(56) is bonded in a single-bond geometry to one C(50) atom. In the thirtieth H site, H(57) is bonded in a single-bond geometry to one C(51) atom. In the thirty-first H site, H(58) is bonded in a single-bond geometry to one C(52) atom. In the thirty-second H site, H(59) is bonded in a single-bond geometry to one C(56) atom. In the thirty-third H site, H(61) is bonded in a single-bond geometry to one C(58) atom. In the thirty-fourth H site, H(62) is bonded in a single-bond geometry to one C(60) atom. In the thirty-fifth H site, H(63,66) is bonded in a single-bond geometry to one C(63) atom. In the thirty-sixth H site, H(64) is bonded in a single-bond geometry to one C(64) atom. In the thirty-seventh H site, H(65) is bonded in a single-bond geometry to one C(65) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one C(6) and one C(8) atom. In the second S site, S(2) is bonded in a water-like geometry to one C(12) and one C(14) atom. In the third S site, S(3) is bonded in a water-like geometry to one C(18) and one C(20) atom. In the fourth S site, S(4) is bonded in a water-like geometry to one C(2) and one C(24) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Na(1), one C(1), and one C(25) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(26) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Na(1) and one C(26) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one C(27) and one C(7) atom. In the fifth O site, O(7) is bonded in a distorted trigonal planar geometry to one Na(1), one C(13), and one C(29) atom. In the sixth O site, O(9) is bonded in a bent 120 degrees geometry to one Na(1) and one C(30) atom. In the seventh O site, O(10) is bonded in a bent 120 degrees geometry to one C(19) and one C(31) atom. In the eighth O site, O(13) is bonded in a single-bond geometry to one C(54) atom. In the ninth O site, O(14) is bonded in a single-bond geometry to one C(61) atom. In the tenth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(28) atom. In the eleventh O site, O(6) is bonded in a single-bond geometry to one C(28) atom. In the twelfth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(30) atom. In the thirteenth O site, O(11) is bonded in a bent 120 degrees geometry to one Co(1) and one C(32) atom. In the fourteenth O site, O(12) is bonded in a single-bond geometry to one C(32) atom. Linkers: 4 O=C(Nc1ccncc1)c1cccc(C(=O)Nc2ccncc2)c1 ,4 CC(C)(C)c1cc2c(OCC([O])=O)c(c1)Sc1cc(C(C)(C)C)cc(c1OCC([O])=O)Sc1cc(C(C)(C)C)cc(c1OCC([O])=O)Sc1cc(C(C)(C)C)cc(c1OCC([O])=O)S2. Metal clusters: 2 [O]CC(=O)O[Co]OC(=O)C[O].[O]C[C](O[Na])O[Co](O[C]=O)O[C]=O.[O]C[C](O[Na])O[Co](O[C]=O)O[C]=O. The MOF has largest included sphere 7.21 A, density 1.06 g/cm3, surface area 4840.87 m2/g, accessible volume 0.34 cm3/g