CdC12H8(NO2)2(CH3)2(C8NH3O2)2 is Indium-derived structured and crystallizes in the tetragonal P4_32_12 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight 20958-66-1 molecules, and eight CdC12H8(NO2)2 clusters. In each CdC12H8(NO2)2 cluster, Cd(1) is bonded in a distorted pentagonal pyramidal geometry to one N(3), one N(4), one O(1), one O(2), one O(7), and one O(8) atom. The Cd(1)-N(3) bond length is 2.29 Å. The Cd(1)-N(4) bond length is 2.33 Å. The Cd(1)-O(1) bond length is 2.43 Å. The Cd(1)-O(2) bond length is 2.38 Å. The Cd(1)-O(7) bond length is 2.40 Å. The Cd(1)-O(8) bond length is 2.48 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(20) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(20)-O(7) bond length is 1.24 Å. The C(20)-O(8) bond length is 1.27 Å. In the third C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one N(3), and one H(13) atom. The C(21)-C(22) bond length is 1.37 Å. The C(21)-N(3) bond length is 1.35 Å. The C(21)-H(13) bond length is 0.95 Å. In the fourth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(14) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-H(14) bond length is 0.95 Å. In the fifth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(28) bond length is 1.48 Å. In the sixth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(15) atom. The C(24)-H(15) bond length is 0.95 Å. In the seventh C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(16) atom. The C(25)-N(3) bond length is 1.33 Å. The C(25)-H(16) bond length is 0.95 Å. In the eighth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(17) atom. The C(26)-N(4) bond length is 1.34 Å. The C(26)-H(17) bond length is 0.95 Å. In the ninth C site, C(27) is bonded in a distorted single-bond geometry to one C(28) and one H(18) atom. The C(27)-C(28) bond length is 1.41 Å. The C(27)-H(18) bond length is 0.95 Å. In the tenth C site, C(28) is bonded in a trigonal planar geometry to one C(23), one C(27), and one C(29) atom. The C(28)-C(29) bond length is 1.39 Å. In the eleventh C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(19) atom. The C(29)-H(19) bond length is 0.95 Å. In the twelfth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(20) atom. The C(30)-N(4) bond length is 1.34 Å. The C(30)-H(20) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(21), and one C(25) atom. In the second N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(26), and one C(30) atom. There are eight inequivalent H sites. In the first H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the second H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(24) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(27) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(30) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Cd(1) and one C(20) atom. In the fourth O site, O(8) is bonded in a distorted single-bond geometry to one Cd(1) and one C(20) atom. Linkers: 8 C[C@@H](C([O])=O)N1C(=O)c2ccc3c4c(ccc(c24)C1=O)C(=O)N([C@@H](C)C([O])=O)C3=O ,8 c1cc(-c2ccncc2)ccn1. Metal clusters: 8 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 6.16 A, density 1.28 g/cm3, surface area 4169.08 m2/g, accessible volume 0.38 cm3/g