ZnH15(C3N)6C9H6N is Indium-derived structured and crystallizes in the orthorhombic Pnna space group. The structure is zero-dimensional and consists of eight schembl1705614 molecules and eight ZnH15(C3N)6 clusters. In each ZnH15(C3N)6 cluster, Zn(1) is bonded in a trigonal non-coplanar geometry to one N(2), one N(4), and one N(7) atom. The Zn(1)-N(2) bond length is 2.02 Å. The Zn(1)-N(4) bond length is 2.00 Å. The Zn(1)-N(7) bond length is 2.01 Å. There are eighteen inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(5), and one H(1) atom. The C(2)-N(2) bond length is 1.32 Å. The C(2)-N(5) bond length is 1.34 Å. The C(2)-H(1) bond length is 0.93 Å. In the second C site, C(4) is bonded in a distorted trigonal planar geometry to one C(12), one C(23), and one N(6) atom. The C(4)-C(12) bond length is 1.37 Å. The C(4)-C(23) bond length is 1.36 Å. The C(4)-N(6) bond length is 1.45 Å. In the third C site, C(6) is bonded in a distorted trigonal planar geometry to one C(13), one C(14), and one N(5) atom. The C(6)-C(13) bond length is 1.36 Å. The C(6)-C(14) bond length is 1.38 Å. The C(6)-N(5) bond length is 1.44 Å. In the fourth C site, C(7) is bonded in a 3-coordinate geometry to one C(19), one N(5), and one H(3) atom. The C(7)-C(19) bond length is 1.36 Å. The C(7)-N(5) bond length is 1.37 Å. The C(7)-H(3) bond length is 0.93 Å. In the fifth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(10), one C(18), and one N(3) atom. The C(8)-C(10) bond length is 1.39 Å. The C(8)-C(18) bond length is 1.37 Å. The C(8)-N(3) bond length is 1.44 Å. In the sixth C site, C(10) is bonded in a distorted single-bond geometry to one C(8) and one H(5,12) atom. The C(10)-H(5,12) bond length is 0.93 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(12)-H(6) bond length is 0.93 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(6) and one H(7) atom. The C(13)-H(7) bond length is 0.93 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(6) and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. In the tenth C site, C(15) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(9) atom. The C(15)-N(3) bond length is 1.32 Å. The C(15)-N(4) bond length is 1.31 Å. The C(15)-H(9) bond length is 0.93 Å. In the eleventh C site, C(18) is bonded in a distorted single-bond geometry to one C(8) and one H(5,12) atom. The C(18)-H(5,12) bond length is 0.93 Å. In the twelfth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(7), one N(2), and one H(13) atom. The C(19)-N(2) bond length is 1.36 Å. The C(19)-H(13) bond length is 0.93 Å. In the thirteenth C site, C(21) is bonded in a trigonal planar geometry to one N(6), one N(7), and one H(15) atom. The C(21)-N(6) bond length is 1.34 Å. The C(21)-N(7) bond length is 1.31 Å. The C(21)-H(15) bond length is 0.93 Å. In the fourteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(16) atom. The C(22)-N(4) bond length is 1.37 Å. The C(22)-H(16) bond length is 0.93 Å. In the fifteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(4) and one H(17) atom. The C(23)-H(17) bond length is 0.93 Å. In the sixteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(18) atom. The C(24)-N(3) bond length is 1.35 Å. The C(24)-H(18) bond length is 0.93 Å. In the seventeenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(27), one N(7), and one H(20) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-N(7) bond length is 1.31 Å. The C(26)-H(20) bond length is 0.93 Å. In the eighteenth C site, C(27) is bonded in a 3-coordinate geometry to one C(26), one N(6), and one H(21) atom. The C(27)-N(6) bond length is 1.37 Å. The C(27)-H(21) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(19), and one C(2) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(15), one C(24), and one C(8) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(22) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. In the fifth N site, N(7) is bonded in a trigonal planar geometry to one Zn(1), one C(21), and one C(26) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(21), one C(27), and one C(4) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(5,12) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(26) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(27) atom. Linkers: 8 c1cn(-c2ccc(N(c3ccc(-n4ccnc4)cc3)c3ccc(-n4ccnc4)cc3)cc2)cn1. Metal clusters: 8 [Zn]. The MOF has largest included sphere 8.36 A, density 0.89 g/cm3, surface area 5112.22 m2/g, accessible volume 0.62 cm3/g