CdC14H10(NO2)2CdC8NH5O4(CH)4(CH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, four 02329_fluka molecules, one CdC14H10(NO2)2 cluster, and two CdC8NH5O4 clusters. In the CdC14H10(NO2)2 cluster, Cd(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.32 Å. The Cd(1)-N(2) bond length is 2.36 Å. The Cd(1)-O(1) bond length is 2.29 Å. The Cd(1)-O(3) bond length is 2.32 Å. The Cd(1)-O(4) bond length is 2.24 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.36 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.34 Å. The C(3)-C(6) bond length is 1.54 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.36 Å. The C(5)-H(4) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a single-bond geometry to one C(3) and one H(5) atom. The C(6)-H(5) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a single-bond geometry to one C(8) and one H(6) atom. The C(7)-C(8) bond length is 1.48 Å. The C(7)-H(6) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.39 Å. The C(8)-C(9) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a single-bond geometry to one C(10), one C(8), and one H(7) atom. The C(9)-C(10) bond length is 1.37 Å. The C(9)-H(7) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(8) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(11)-N(2) bond length is 1.31 Å. The C(11)-H(9) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(8) and one H(10) atom. The C(12)-H(10) bond length is 0.93 Å. In the thirteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(19)-O(1) bond length is 1.30 Å. The C(19)-O(2) bond length is 1.23 Å. In the fourteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(26)-O(3) bond length is 1.25 Å. The C(26)-O(4) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(11) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cd(1) and one C(19) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(19) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Cd(1) and one C(26) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Cd(1) and one C(26) atom. In each CdC8NH5O4 cluster, Cd(2) is bonded in a distorted rectangular see-saw-like geometry to one N(3), one O(5), one O(6), and one O(7) atom. The Cd(2)-N(3) bond length is 2.37 Å. The Cd(2)-O(5) bond length is 2.38 Å. The Cd(2)-O(6) bond length is 2.44 Å. The Cd(2)-O(7) bond length is 2.25 Å. There are eight inequivalent C sites. In the first C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one H(11) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-N(3) bond length is 1.33 Å. The C(13)-H(11) bond length is 0.93 Å. In the second C site, C(14) is bonded in a single-bond geometry to one C(13), one C(15), and one H(12) atom. The C(14)-C(15) bond length is 1.34 Å. The C(14)-H(12) bond length is 0.93 Å. In the third C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.34 Å. The C(15)-C(18) bond length is 1.52 Å. In the fourth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(13) atom. The C(16)-H(13) bond length is 0.93 Å. In the fifth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(14) atom. The C(17)-N(3) bond length is 1.34 Å. The C(17)-H(14) bond length is 0.93 Å. In the sixth C site, C(18) is bonded in a distorted single-bond geometry to one C(15) and one H(15) atom. The C(18)-H(15) bond length is 0.93 Å. In the seventh C site, C(27) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(27)-O(5) bond length is 1.27 Å. The C(27)-O(6) bond length is 1.25 Å. In the eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(28)-O(7) bond length is 1.28 Å. The C(28)-O(8) bond length is 1.27 Å. N(3) is bonded in a trigonal planar geometry to one Cd(2), one C(13), and one C(17) atom. There are five inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Cd(2) and one C(27) atom. In the second O site, O(6) is bonded in a distorted single-bond geometry to one Cd(2) and one C(27) atom. In the third O site, O(7) is bonded in a distorted water-like geometry to one Cd(2) and one C(28) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one C(28) atom. Linkers: 1 [CH2].[CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]O[Cd][N].[C][CH].[Cd].[Cd].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N][Cd]([O])OC(=O)[C@H]1C[C@@H](C([O])=O)[C@@H](C([O])=O)C[C@H]1C([O])=O.[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][C]=O ,1 [CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]/C=[C]/C=[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]N([CH])[Cd]OC(=O)[C@H]1C[C@@H](C([O])=O)[C@@H](C([O])=O)C[C@H]1C([O])=O.[C]N=[C].[C]O[Cd].[Cd].[Cd].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O] ,1 O=[C]O[Cd].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[N].[CH][CH2].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]=O.[C]=[CH].[C]C(=[CH])C=[C].[C]N([CH])[Cd].[C][C].[C][C]1O[Cd]([N])(OC(=O)[C@@H]2C[CH][C@H](C([O])=O)C[C@@H]2C([O])=O)O1.[Cd].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O ,1 O=[C]O[Cd].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]N=[CH].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[Cd].[Cd].[Cd].[Cd].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][Cd] ,1 [CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C][CH].[C][N][Cd]1(O[C])O[C]([C@H]2C[C@@H](C(=O)O[Cd][N])[C@@H](C([O])=O)C[C@H]2C([O])=O)O1.[Cd].[Cd].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O] ,1 [CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]=O.[C]=O.[C]=O.[C]=[C][CH].[C]N([C])[Cd]OC(=O)[C@@H]1C[C@H](C([O])=O)[C@H](C([O])=O)C[C@@H]1C([O])=O.[C]N=[C].[C][C].[C][C].[Cd].[Cd].[Cd].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][C]=O ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]=O.[C]=O.[C]=O.[C]O[Cd].[C][CH][CH][C][C]1O[Cd]([N][CH])O1.[C][CH][N][Cd][O].[C][C].[C][C][C]=[C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[O].[O].[O].[O].[O].[O].[O]C(=O)[C@@H]1[CH]C[C@H](C(=O)O[Cd])[C@H](C([O])=O)C1.[O][C]=O.[O][C]=O ,2 [CH]([CH]c1ccncc1)c1ccncc1. Metal clusters: 1 O=[C]O[Cd]1O[C]O[Cd](O[C]=O)O[C]O1. The MOF has largest included sphere 4.44 A, density 1.45 g/cm3, surface area 3898.86 m2/g, accessible volume 0.27 cm3/g