(CdH4(C2O)4)3(CH)12C16H16O7 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules, four schembl9144749 molecules, and four CdH4(C2O)4 clusters. In each CdH4(C2O)4 cluster, there are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted square co-planar geometry to one O(12), one O(17), one O(8), and one O(9) atom. The Cd(1)-O(12) bond length is 2.25 Å. The Cd(1)-O(17) bond length is 2.25 Å. The Cd(1)-O(8) bond length is 2.52 Å. The Cd(1)-O(9) bond length is 2.34 Å. In the second Cd site, Cd(2) is bonded in an octahedral geometry to one O(10), one O(13), one O(14), one O(16), one O(18), and one O(9) atom. The Cd(2)-O(10) bond length is 2.33 Å. The Cd(2)-O(13) bond length is 2.25 Å. The Cd(2)-O(14) bond length is 2.21 Å. The Cd(2)-O(16) bond length is 2.22 Å. The Cd(2)-O(18) bond length is 2.33 Å. The Cd(2)-O(9) bond length is 2.32 Å. In the third Cd site, Cd(3) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(15), one O(18), and one O(19) atom. The Cd(3)-O(10) bond length is 2.34 Å. The Cd(3)-O(11) bond length is 2.63 Å. The Cd(3)-O(15) bond length is 2.21 Å. The Cd(3)-O(18) bond length is 2.49 Å. The Cd(3)-O(19) bond length is 2.30 Å. There are twenty-four inequivalent C sites. In the first C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(18) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-H(18) bond length is 0.93 Å. In the second C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-C(17) bond length is 1.48 Å. In the third C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(19) atom. The C(15)-H(19) bond length is 0.93 Å. In the fourth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(8), and one O(9) atom. The C(17)-O(8) bond length is 1.24 Å. The C(17)-O(9) bond length is 1.26 Å. In the fifth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(22) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(22) bond length is 0.93 Å. In the sixth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-C(24) bond length is 1.47 Å. In the seventh C site, C(22) is bonded in a single-bond geometry to one C(21) and one H(23) atom. The C(22)-H(23) bond length is 0.93 Å. In the eighth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(10), and one O(11) atom. The C(24)-O(10) bond length is 1.29 Å. The C(24)-O(11) bond length is 1.26 Å. In the ninth C site, C(27) is bonded in a distorted single-bond geometry to one C(28) and one H(26) atom. The C(27)-C(28) bond length is 1.38 Å. The C(27)-H(26) bond length is 0.93 Å. In the tenth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(31) atom. The C(28)-C(29) bond length is 1.38 Å. The C(28)-C(31) bond length is 1.50 Å. In the eleventh C site, C(29) is bonded in a single-bond geometry to one C(28) and one H(27) atom. The C(29)-H(27) bond length is 0.93 Å. In the twelfth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(12), and one O(13) atom. The C(31)-O(12) bond length is 1.26 Å. The C(31)-O(13) bond length is 1.26 Å. In the thirteenth C site, C(34) is bonded in a single-bond geometry to one C(35) and one H(30) atom. The C(34)-C(35) bond length is 1.38 Å. The C(34)-H(30) bond length is 0.93 Å. In the fourteenth C site, C(35) is bonded in a trigonal planar geometry to one C(34), one C(36), and one C(38) atom. The C(35)-C(36) bond length is 1.38 Å. The C(35)-C(38) bond length is 1.50 Å. In the fifteenth C site, C(36) is bonded in a distorted single-bond geometry to one C(35) and one H(31) atom. The C(36)-H(31) bond length is 0.93 Å. In the sixteenth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(14), and one O(15) atom. The C(38)-O(14) bond length is 1.23 Å. The C(38)-O(15) bond length is 1.25 Å. In the seventeenth C site, C(41) is bonded in a distorted single-bond geometry to one C(42) and one H(34) atom. The C(41)-C(42) bond length is 1.39 Å. The C(41)-H(34) bond length is 0.93 Å. In the eighteenth C site, C(42) is bonded in a trigonal planar geometry to one C(41), one C(43), and one C(45) atom. The C(42)-C(43) bond length is 1.39 Å. The C(42)-C(45) bond length is 1.50 Å. In the nineteenth C site, C(43) is bonded in a distorted single-bond geometry to one C(42) and one H(35) atom. The C(43)-H(35) bond length is 0.93 Å. In the twentieth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(42), one O(16), and one O(17) atom. The C(45)-O(16) bond length is 1.25 Å. The C(45)-O(17) bond length is 1.27 Å. In the twenty-first C site, C(48) is bonded in a distorted single-bond geometry to one C(49) and one H(38) atom. The C(48)-C(49) bond length is 1.37 Å. The C(48)-H(38) bond length is 0.93 Å. In the twenty-second C site, C(49) is bonded in a trigonal planar geometry to one C(48), one C(50), and one C(52) atom. The C(49)-C(50) bond length is 1.39 Å. The C(49)-C(52) bond length is 1.52 Å. In the twenty-third C site, C(50) is bonded in a single-bond geometry to one C(49) and one H(39) atom. The C(50)-H(39) bond length is 0.93 Å. In the twenty-fourth C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(49), one O(18), and one O(19) atom. The C(52)-O(18) bond length is 1.23 Å. The C(52)-O(19) bond length is 1.25 Å. There are twelve inequivalent H sites. In the first H site, H(18) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(19) is bonded in a single-bond geometry to one C(15) atom. In the third H site, H(22) is bonded in a single-bond geometry to one C(20) atom. In the fourth H site, H(23) is bonded in a single-bond geometry to one C(22) atom. In the fifth H site, H(26) is bonded in a single-bond geometry to one C(27) atom. In the sixth H site, H(27) is bonded in a single-bond geometry to one C(29) atom. In the seventh H site, H(30) is bonded in a single-bond geometry to one C(34) atom. In the eighth H site, H(31) is bonded in a single-bond geometry to one C(36) atom. In the ninth H site, H(34) is bonded in a single-bond geometry to one C(41) atom. In the tenth H site, H(35) is bonded in a single-bond geometry to one C(43) atom. In the eleventh H site, H(38) is bonded in a single-bond geometry to one C(48) atom. In the twelfth H site, H(39) is bonded in a single-bond geometry to one C(50) atom. There are twelve inequivalent O sites. In the first O site, O(8) is bonded in a distorted single-bond geometry to one Cd(1) and one C(17) atom. In the second O site, O(9) is bonded in a distorted T-shaped geometry to one Cd(1), one Cd(2), and one C(17) atom. In the third O site, O(10) is bonded in a distorted T-shaped geometry to one Cd(2), one Cd(3), and one C(24) atom. In the fourth O site, O(11) is bonded in a distorted single-bond geometry to one Cd(3) and one C(24) atom. In the fifth O site, O(12) is bonded in a distorted water-like geometry to one Cd(1) and one C(31) atom. In the sixth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one C(31) atom. In the seventh O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one C(38) atom. In the eighth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Cd(3) and one C(38) atom. In the ninth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one Cd(2) and one C(45) atom. In the tenth O site, O(17) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(45) atom. In the eleventh O site, O(18) is bonded in a distorted T-shaped geometry to one Cd(2), one Cd(3), and one C(52) atom. In the twelfth O site, O(19) is bonded in a distorted L-shaped geometry to one Cd(3) and one C(52) atom. Linkers: 4 [O]C(=O)c1ccc(OCC(COCC(COc2ccc(C([O])=O)cc2)(COc2ccc(C([O])=O)cc2)COc2ccc(C([O])=O)cc2)(COc2ccc(C([O])=O)cc2)COc2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 O=[C]O[Cd]123(O[C]O[Cd]O[C]O1)O[C]O[Cd](O[C]O2)O[C]O3. RCSR code: sra. The MOF has largest included sphere 8.42 A, density 0.86 g/cm3, surface area 4055.26 m2/g, accessible volume 0.72 cm3/g