AgC7N5H6CH crystallizes in the orthorhombic Fdd2 space group. The structure consists of sixteen 02329_fluka molecules inside a AgC7N5H6 framework. In the AgC7N5H6 framework, Ag(1) is bonded in a distorted trigonal planar geometry to one N(1), one N(2), and one N(5) atom. The Ag(1)-N(1) bond length is 2.19 Å. The Ag(1)-N(2) bond length is 2.30 Å. The Ag(1)-N(5) bond length is 2.29 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-N(3) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(2) atom. The C(2)-N(2) bond length is 1.31 Å. The C(2)-N(3) bond length is 1.37 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(4), and one H(3) atom. The C(3)-C(4) bond length is 1.48 Å. The C(3)-N(4) bond length is 1.26 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-C(8) bond length is 1.38 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(6) atom. The C(7)-N(5) bond length is 1.35 Å. The C(7)-H(6) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(5), and one H(7) atom. The C(8)-N(5) bond length is 1.34 Å. The C(8)-H(7) bond length is 0.93 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.39 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Ag(1), one C(2), and one N(1) atom. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(1), one C(2), and one N(4) atom. The N(3)-N(4) bond length is 1.41 Å. In the fourth N site, N(4) is bonded in a distorted bent 120 degrees geometry to one C(3) and one N(3) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Ag(1), one C(7), and one C(8) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. Linkers: 16 C(=N/n1cnnc1)\c1cccnc1. Metal clusters: 16 [Ag]. The MOF has largest included sphere 4.61 A, density 1.47 g/cm3, surface area 3679.39 m2/g, accessible volume 0.31 cm3/g