CuC13H7O4CH is Indium-derived structured and crystallizes in the tetragonal I4_1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and four CuC13H7O4 clusters. In each CuC13H7O4 cluster, Cu(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-O(1) bond length is 2.01 Å. The Cu(1)-O(2) bond length is 1.93 Å. The Cu(1)-O(3) bond length is 1.98 Å. The Cu(1)-O(4) bond length is 2.01 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.43 Å. The C(1)-O(1) bond length is 1.22 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1,4) atom. The C(3)-H(1,4) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.45 Å. The C(5)-C(8) bond length is 1.46 Å. In the sixth C site, C(6) is bonded in a single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(1,4) atom. The C(7)-H(1,4) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(5), and one C(9) atom. The C(8)-C(13) bond length is 1.37 Å. The C(8)-C(9) bond length is 1.36 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(9)-H(5) bond length is 0.93 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(7) atom. The C(11)-C(12) bond length is 1.36 Å. The C(11)-H(7) bond length is 0.93 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-C(14) bond length is 1.56 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(8) atom. The C(13)-H(8) bond length is 0.93 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.22 Å. The C(14)-O(4) bond length is 1.25 Å. There are six inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(14) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cu(1) and one C(14) atom. Linkers: 4 [O]C(=O)c1ccc(-c2cccc(C([O])=O)c2)cc1. Metal clusters: 2 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: dia. The MOF has largest included sphere 7.69 A, density 0.95 g/cm3, surface area 4231.52 m2/g, accessible volume 0.69 cm3/g