(CH2)2C4BiO7 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four C4BiO7 clusters. In each C4BiO7 cluster, there are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.15 Å. The C(1)-O(2) bond length is 1.34 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one O(4), and one O(5) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-O(4) bond length is 1.28 Å. The C(2)-O(5) bond length is 1.32 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one O(3) atom. The C(3)-O(3) bond length is 1.42 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(5)-O(6) bond length is 1.26 Å. The C(5)-O(7) bond length is 1.27 Å. Bi(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(5), one O(6), and one O(7) atom. The Bi(1)-O(1) bond length is 2.44 Å. The Bi(1)-O(2) bond length is 2.53 Å. The Bi(1)-O(3) bond length is 2.10 Å. The Bi(1)-O(5) bond length is 2.24 Å. The Bi(1)-O(6) bond length is 2.46 Å. The Bi(1)-O(7) bond length is 2.46 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one C(1) and one Bi(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) and one Bi(1) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one C(3) and one Bi(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one C(2) and one Bi(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one C(5) and one Bi(1) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one C(5) and one Bi(1) atom. Linkers: 6 [O]C(=O)[CH]C([O])(CC([O])=O)C([O])=O ,2 [O][C]C([O])([CH]C([O])=O)CC([O])=O. Metal clusters: 4 [O][C]=O.[O][C]=O.[O][C]O[Bi]1O[C]C(=O)O1.[O][C]O[Bi]1O[C]C(=O)O1. The MOF has largest included sphere 4.54 A, density 2.48 g/cm3, surface area 2073.37 m2/g, accessible volume 0.16 cm3/g