Ru2C35H25S(NO2)4(CH)3 crystallizes in the triclinic P-1 space group. The structure consists of twelve 02329_fluka molecules inside a Ru2C35H25S(NO2)4 framework. In the Ru2C35H25S(NO2)4 framework, there are four inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Ru(1)-N(1) bond length is 2.21 Å. The Ru(1)-O(1) bond length is 2.02 Å. The Ru(1)-O(2) bond length is 2.04 Å. The Ru(1)-O(3) bond length is 2.01 Å. The Ru(1)-O(4) bond length is 2.02 Å. In the second Ru site, Ru(2) is bonded in a distorted square pyramidal geometry to one N(4), one O(11), one O(5), one O(7), and one O(9) atom. The Ru(2)-N(4) bond length is 2.22 Å. The Ru(2)-O(11) bond length is 2.02 Å. The Ru(2)-O(5) bond length is 2.03 Å. The Ru(2)-O(7) bond length is 2.03 Å. The Ru(2)-O(9) bond length is 2.04 Å. In the third Ru site, Ru(3) is bonded in a distorted square pyramidal geometry to one N(5), one O(10), one O(12), one O(6), and one O(8) atom. The Ru(3)-N(5) bond length is 2.23 Å. The Ru(3)-O(10) bond length is 2.01 Å. The Ru(3)-O(12) bond length is 2.02 Å. The Ru(3)-O(6) bond length is 2.02 Å. The Ru(3)-O(8) bond length is 2.02 Å. In the fourth Ru site, Ru(4) is bonded in a distorted square pyramidal geometry to one N(8), one O(13), one O(14), one O(15), and one O(16) atom. The Ru(4)-N(8) bond length is 2.22 Å. The Ru(4)-O(13) bond length is 2.02 Å. The Ru(4)-O(14) bond length is 2.03 Å. The Ru(4)-O(15) bond length is 2.02 Å. The Ru(4)-O(16) bond length is 2.02 Å. There are seventy inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(8) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(8) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.50 Å. The C(4)-C(6) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a trigonal non-coplanar geometry to one C(4), one H(2), one H(3), and one H(4) atom. The C(5)-H(2) bond length is 0.95 Å. The C(5)-H(3) bond length is 0.94 Å. The C(5)-H(4) bond length is 0.96 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(5) atom. The C(6)-H(5) bond length is 0.95 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(2) and one H(7) atom. The C(8)-H(7) bond length is 0.95 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(4) atom. The C(9)-C(10) bond length is 1.47 Å. The C(9)-O(3) bond length is 1.27 Å. The C(9)-O(4) bond length is 1.28 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(16), and one C(9) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(16) bond length is 1.38 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(8) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(8) bond length is 0.95 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.50 Å. The C(12)-C(14) bond length is 1.39 Å. In the twelfth C site, C(13) is bonded in a trigonal non-coplanar geometry to one C(12), one H(10), one H(11), and one H(9) atom. The C(13)-H(10) bond length is 0.95 Å. The C(13)-H(11) bond length is 0.96 Å. The C(13)-H(9) bond length is 0.95 Å. In the thirteenth C site, C(14) is bonded in a single-bond geometry to one C(12) and one H(12) atom. The C(14)-H(12) bond length is 0.96 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(10) and one H(14) atom. The C(16)-H(14) bond length is 0.95 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one N(1) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-N(1) bond length is 1.15 Å. In the sixteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(20) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-C(20) bond length is 1.45 Å. In the seventeenth C site, C(19) is bonded in a distorted linear geometry to one C(18) and one N(4) atom. The C(19)-N(4) bond length is 1.14 Å. In the eighteenth C site, C(20) is bonded in a trigonal planar geometry to one C(18), one C(21), and one C(22) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(22) bond length is 1.42 Å. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one N(2) atom. The C(21)-C(22) bond length is 1.45 Å. The C(21)-N(2) bond length is 1.38 Å. In the twentieth C site, C(22) is bonded in a distorted single-bond geometry to one C(20), one C(21), and one N(3) atom. The C(22)-N(3) bond length is 1.36 Å. In the twenty-first C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(5), and one O(6) atom. The C(23)-C(24) bond length is 1.48 Å. The C(23)-O(5) bond length is 1.27 Å. The C(23)-O(6) bond length is 1.27 Å. In the twenty-second C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(30) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-C(30) bond length is 1.39 Å. In the twenty-third C site, C(25) is bonded in a distorted single-bond geometry to one C(24), one C(26), and one H(15) atom. The C(25)-C(26) bond length is 1.38 Å. The C(25)-H(15) bond length is 0.95 Å. In the twenty-fourth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(28) atom. The C(26)-C(27) bond length is 1.50 Å. The C(26)-C(28) bond length is 1.40 Å. In the twenty-fifth C site, C(27) is bonded in a trigonal non-coplanar geometry to one C(26), one H(16), one H(17), and one H(18) atom. The C(27)-H(16) bond length is 0.96 Å. The C(27)-H(17) bond length is 0.94 Å. The C(27)-H(18) bond length is 0.95 Å. In the twenty-sixth C site, C(28) is bonded in a distorted single-bond geometry to one C(26) and one H(19) atom. The C(28)-H(19) bond length is 0.95 Å. In the twenty-seventh C site, C(30) is bonded in a distorted single-bond geometry to one C(24) and one H(21) atom. The C(30)-H(21) bond length is 0.95 Å. In the twenty-eighth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(7), and one O(8) atom. The C(31)-C(32) bond length is 1.47 Å. The C(31)-O(7) bond length is 1.28 Å. The C(31)-O(8) bond length is 1.28 Å. In the twenty-ninth C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(38) atom. The C(32)-C(33) bond length is 1.40 Å. The C(32)-C(38) bond length is 1.39 Å. In the thirtieth C site, C(33) is bonded in a distorted single-bond geometry to one C(32), one C(34), and one H(22) atom. The C(33)-C(34) bond length is 1.39 Å. The C(33)-H(22) bond length is 0.95 Å. In the thirty-first C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(36) atom. The C(34)-C(35) bond length is 1.50 Å. The C(34)-C(36) bond length is 1.39 Å. In the thirty-second C site, C(35) is bonded in a trigonal non-coplanar geometry to one C(34), one H(23), one H(24), and one H(25) atom. The C(35)-H(23) bond length is 0.96 Å. The C(35)-H(24) bond length is 0.95 Å. The C(35)-H(25) bond length is 0.95 Å. In the thirty-third C site, C(36) is bonded in a distorted single-bond geometry to one C(34), one C(37), and one H(26) atom. The C(36)-C(37) bond length is 1.38 Å. The C(36)-H(26) bond length is 0.95 Å. In the thirty-fourth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(36), one C(38), and one H(27) atom. The C(37)-C(38) bond length is 1.38 Å. The C(37)-H(27) bond length is 0.96 Å. In the thirty-fifth C site, C(38) is bonded in a distorted single-bond geometry to one C(32), one C(37), and one H(28) atom. The C(38)-H(28) bond length is 0.96 Å. In the thirty-sixth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one C(40), one O(10), and one O(9) atom. The C(39)-C(40) bond length is 1.49 Å. The C(39)-O(10) bond length is 1.28 Å. The C(39)-O(9) bond length is 1.28 Å. In the thirty-seventh C site, C(40) is bonded in a trigonal planar geometry to one C(39), one C(41), and one C(46) atom. The C(40)-C(41) bond length is 1.38 Å. The C(40)-C(46) bond length is 1.40 Å. In the thirty-eighth C site, C(41) is bonded in a distorted single-bond geometry to one C(40), one C(42), and one H(29) atom. The C(41)-C(42) bond length is 1.39 Å. The C(41)-H(29) bond length is 0.95 Å. In the thirty-ninth C site, C(42) is bonded in a trigonal planar geometry to one C(41), one C(43), and one C(44) atom. The C(42)-C(43) bond length is 1.49 Å. The C(42)-C(44) bond length is 1.39 Å. In the fortieth C site, C(43) is bonded in a trigonal non-coplanar geometry to one C(42), one H(30), one H(31), and one H(32) atom. The C(43)-H(30) bond length is 0.96 Å. The C(43)-H(31) bond length is 0.95 Å. The C(43)-H(32) bond length is 0.95 Å. In the forty-first C site, C(44) is bonded in a distorted single-bond geometry to one C(42) and one H(33) atom. The C(44)-H(33) bond length is 0.95 Å. In the forty-second C site, C(46) is bonded in a distorted single-bond geometry to one C(40) and one H(35) atom. The C(46)-H(35) bond length is 0.96 Å. In the forty-third C site, C(47) is bonded in a distorted bent 120 degrees geometry to one C(48), one O(11), and one O(12) atom. The C(47)-C(48) bond length is 1.48 Å. The C(47)-O(11) bond length is 1.28 Å. The C(47)-O(12) bond length is 1.27 Å. In the forty-fourth C site, C(48) is bonded in a trigonal planar geometry to one C(47), one C(49), and one C(54) atom. The C(48)-C(49) bond length is 1.40 Å. The C(48)-C(54) bond length is 1.39 Å. In the forty-fifth C site, C(49) is bonded in a distorted single-bond geometry to one C(48), one C(50), and one H(36) atom. The C(49)-C(50) bond length is 1.39 Å. The C(49)-H(36) bond length is 0.95 Å. In the forty-sixth C site, C(50) is bonded in a trigonal planar geometry to one C(49), one C(51), and one C(52) atom. The C(50)-C(51) bond length is 1.50 Å. The C(50)-C(52) bond length is 1.39 Å. In the forty-seventh C site, C(51) is bonded in a trigonal non-coplanar geometry to one C(50); one H(38); and two equivalent H(37,39) atoms. The C(51)-H(38) bond length is 0.96 Å. Both C(51)-H(37,39) bond lengths are 0.95 Å. In the forty-eighth C site, C(52) is bonded in a distorted single-bond geometry to one C(50) and one H(40) atom. The C(52)-H(40) bond length is 0.95 Å. In the forty-ninth C site, C(54) is bonded in a distorted single-bond geometry to one C(48) and one H(42) atom. The C(54)-H(42) bond length is 0.95 Å. In the fiftieth C site, C(55) is bonded in a distorted linear geometry to one C(56) and one N(5) atom. The C(55)-C(56) bond length is 1.40 Å. The C(55)-N(5) bond length is 1.15 Å. In the fifty-first C site, C(56) is bonded in a trigonal planar geometry to one C(55), one C(57), and one C(58) atom. The C(56)-C(57) bond length is 1.40 Å. The C(56)-C(58) bond length is 1.45 Å. In the fifty-second C site, C(57) is bonded in a distorted single-bond geometry to one C(56) and one N(8) atom. The C(57)-N(8) bond length is 1.15 Å. In the fifty-third C site, C(58) is bonded in a trigonal planar geometry to one C(56), one C(59), and one C(60) atom. The C(58)-C(59) bond length is 1.41 Å. The C(58)-C(60) bond length is 1.41 Å. In the fifty-fourth C site, C(59) is bonded in a distorted trigonal planar geometry to one C(58), one C(60), and one N(6) atom. The C(59)-C(60) bond length is 1.46 Å. The C(59)-N(6) bond length is 1.36 Å. In the fifty-fifth C site, C(60) is bonded in a distorted trigonal planar geometry to one C(58), one C(59), and one N(7) atom. The C(60)-N(7) bond length is 1.36 Å. In the fifty-sixth C site, C(61) is bonded in a distorted bent 120 degrees geometry to one C(62), one O(13), and one O(14) atom. The C(61)-C(62) bond length is 1.48 Å. The C(61)-O(13) bond length is 1.28 Å. The C(61)-O(14) bond length is 1.29 Å. In the fifty-seventh C site, C(62) is bonded in a trigonal planar geometry to one C(61), one C(63), and one C(68) atom. The C(62)-C(63) bond length is 1.39 Å. The C(62)-C(68) bond length is 1.39 Å. In the fifty-eighth C site, C(63) is bonded in a distorted single-bond geometry to one C(62), one C(64), and one H(43) atom. The C(63)-C(64) bond length is 1.40 Å. The C(63)-H(43) bond length is 0.95 Å. In the fifty-ninth C site, C(64) is bonded in a trigonal planar geometry to one C(63), one C(65), and one C(66) atom. The C(64)-C(65) bond length is 1.50 Å. The C(64)-C(66) bond length is 1.38 Å. In the sixtieth C site, C(65) is bonded in a trigonal non-coplanar geometry to one C(64), one H(44), one H(45), and one H(46) atom. The C(65)-H(44) bond length is 0.96 Å. The C(65)-H(45) bond length is 0.94 Å. The C(65)-H(46) bond length is 0.95 Å. In the sixty-first C site, C(66) is bonded in a distorted trigonal planar geometry to one C(64), one C(67), and one H(47) atom. The C(66)-C(67) bond length is 1.39 Å. The C(66)-H(47) bond length is 0.95 Å. In the sixty-second C site, C(67) is bonded in a distorted single-bond geometry to one C(66) and one H(48) atom. The C(67)-H(48) bond length is 0.95 Å. In the sixty-third C site, C(68) is bonded in a distorted single-bond geometry to one C(62) and one H(49) atom. The C(68)-H(49) bond length is 0.95 Å. In the sixty-fourth C site, C(69) is bonded in a distorted bent 120 degrees geometry to one C(70), one O(15), and one O(16) atom. The C(69)-C(70) bond length is 1.48 Å. The C(69)-O(15) bond length is 1.28 Å. The C(69)-O(16) bond length is 1.27 Å. In the sixty-fifth C site, C(70) is bonded in a trigonal planar geometry to one C(69), one C(71), and one C(76) atom. The C(70)-C(71) bond length is 1.39 Å. The C(70)-C(76) bond length is 1.38 Å. In the sixty-sixth C site, C(71) is bonded in a distorted single-bond geometry to one C(70), one C(72), and one H(50) atom. The C(71)-C(72) bond length is 1.40 Å. The C(71)-H(50) bond length is 0.95 Å. In the sixty-seventh C site, C(72) is bonded in a trigonal planar geometry to one C(71), one C(73), and one C(74) atom. The C(72)-C(73) bond length is 1.50 Å. The C(72)-C(74) bond length is 1.39 Å. In the sixty-eighth C site, C(73) is bonded in a trigonal non-coplanar geometry to one C(72), one H(51), one H(52), and one H(53) atom. The C(73)-H(51) bond length is 0.95 Å. The C(73)-H(52) bond length is 0.96 Å. The C(73)-H(53) bond length is 0.95 Å. In the sixty-ninth C site, C(74) is bonded in a distorted single-bond geometry to one C(72) and one H(54) atom. The C(74)-H(54) bond length is 0.95 Å. In the seventieth C site, C(76) is bonded in a distorted single-bond geometry to one C(70) and one H(56) atom. The C(76)-H(56) bond length is 0.95 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Ru(1) and one C(17) atom. In the second N site, N(2) is bonded in a water-like geometry to one C(21) and one S(1) atom. The N(2)-S(1) bond length is 1.61 Å. In the third N site, N(3) is bonded in a water-like geometry to one C(22) and one S(1) atom. The N(3)-S(1) bond length is 1.60 Å. In the fourth N site, N(4) is bonded in a linear geometry to one Ru(2) and one C(19) atom. In the fifth N site, N(5) is bonded in a bent 150 degrees geometry to one Ru(3) and one C(55) atom. In the sixth N site, N(6) is bonded in a water-like geometry to one C(59) and one S(2) atom. The N(6)-S(2) bond length is 1.60 Å. In the seventh N site, N(7) is bonded in a water-like geometry to one C(60) and one S(2) atom. The N(7)-S(2) bond length is 1.60 Å. In the eighth N site, N(8) is bonded in a distorted bent 150 degrees geometry to one Ru(4) and one C(57) atom. There are forty-nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(27) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(28) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(30) atom. In the nineteenth H site, H(22) is bonded in a single-bond geometry to one C(33) atom. In the twentieth H site, H(23) is bonded in a single-bond geometry to one C(35) atom. In the twenty-first H site, H(24) is bonded in a single-bond geometry to one C(35) atom. In the twenty-second H site, H(25) is bonded in a single-bond geometry to one C(35) atom. In the twenty-third H site, H(26) is bonded in a single-bond geometry to one C(36) atom. In the twenty-fourth H site, H(27) is bonded in a single-bond geometry to one C(37) atom. In the twenty-fifth H site, H(28) is bonded in a single-bond geometry to one C(38) atom. In the twenty-sixth H site, H(29) is bonded in a single-bond geometry to one C(41) atom. In the twenty-seventh H site, H(30) is bonded in a single-bond geometry to one C(43) atom. In the twenty-eighth H site, H(31) is bonded in a single-bond geometry to one C(43) atom. In the twenty-ninth H site, H(32) is bonded in a single-bond geometry to one C(43) atom. In the thirtieth H site, H(33) is bonded in a single-bond geometry to one C(44) atom. In the thirty-first H site, H(35) is bonded in a single-bond geometry to one C(46) atom. In the thirty-second H site, H(36) is bonded in a single-bond geometry to one C(49) atom. In the thirty-third H site, H(37,39) is bonded in a single-bond geometry to one C(51) atom. In the thirty-fourth H site, H(38) is bonded in a single-bond geometry to one C(51) atom. In the thirty-fifth H site, H(40) is bonded in a single-bond geometry to one C(52) atom. In the thirty-sixth H site, H(42) is bonded in a single-bond geometry to one C(54) atom. In the thirty-seventh H site, H(43) is bonded in a single-bond geometry to one C(63) atom. In the thirty-eighth H site, H(44) is bonded in a single-bond geometry to one C(65) atom. In the thirty-ninth H site, H(45) is bonded in a single-bond geometry to one C(65) atom. In the fortieth H site, H(46) is bonded in a single-bond geometry to one C(65) atom. In the forty-first H site, H(47) is bonded in a single-bond geometry to one C(66) atom. In the forty-second H site, H(48) is bonded in a single-bond geometry to one C(67) atom. In the forty-third H site, H(49) is bonded in a single-bond geometry to one C(68) atom. In the forty-fourth H site, H(50) is bonded in a single-bond geometry to one C(71) atom. In the forty-fifth H site, H(51) is bonded in a single-bond geometry to one C(73) atom. In the forty-sixth H site, H(52) is bonded in a single-bond geometry to one C(73) atom. In the forty-seventh H site, H(53) is bonded in a single-bond geometry to one C(73) atom. In the forty-eighth H site, H(54) is bonded in a single-bond geometry to one C(74) atom. In the forty-ninth H site, H(56) is bonded in a single-bond geometry to one C(76) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a water-like geometry to one N(2) and one N(3) atom. In the second S site, S(2) is bonded in a water-like geometry to one N(6) and one N(7) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(9) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(9) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Ru(2) and one C(23) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ru(3) and one C(23) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Ru(2) and one C(31) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Ru(3) and one C(31) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Ru(2) and one C(39) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Ru(3) and one C(39) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Ru(2) and one C(47) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Ru(3) and one C(47) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Ru(4) and one C(61) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Ru(4) and one C(61) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Ru(4) and one C(69) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Ru(4) and one C(69) atom. Linkers: 16 Cc1cccc(C([O])=O)c1 ,2 N#C[C](C#N)c1c2c(c([C](C#N)C#N)c3c1=NS[N]3)=NS[N]2 ,1 N#C[C](C#N)c1c2c(c([C](C#N)C#N)c3nsnc13)[N]S[N]2. Metal clusters: 8 [Ru]. The MOF has largest included sphere 6.18 A, density 1.29 g/cm3, surface area 4449.63 m2/g, accessible volume 0.34 cm3/g