(ZnC16N3H11O4)2(CH)2(C3H2)2C7NH4C15NH10 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; four 2,3-dimethyl-1,3-butadiene molecules; four schembl5425382 molecules; four C15NH10 clusters; and eight ZnC16N3H11O4 clusters. In each C15NH10 cluster, there are fifteen inequivalent C sites. In the first C site, C(27) is bonded in a distorted single-bond geometry to one C(28) and one H(18) atom. The C(27)-C(28) bond length is 1.39 Å. The C(27)-H(18) bond length is 0.93 Å. In the second C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(31) atom. The C(28)-C(29) bond length is 1.39 Å. The C(28)-C(31) bond length is 1.48 Å. In the third C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(19) atom. The C(29)-H(19) bond length is 0.93 Å. In the fourth C site, C(31) is bonded in a trigonal planar geometry to one C(28), one C(32), and one C(36) atom. The C(31)-C(32) bond length is 1.40 Å. The C(31)-C(36) bond length is 1.38 Å. In the fifth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31), one C(33), and one H(21) atom. The C(32)-C(33) bond length is 1.37 Å. The C(32)-H(21) bond length is 0.93 Å. In the sixth C site, C(33) is bonded in a distorted single-bond geometry to one C(32), one C(34), and one H(22) atom. The C(33)-C(34) bond length is 1.37 Å. The C(33)-H(22) bond length is 0.93 Å. In the seventh C site, C(34) is bonded in a distorted trigonal planar geometry to one C(33), one C(35), and one N(4) atom. The C(34)-C(35) bond length is 1.38 Å. The C(34)-N(4) bond length is 1.41 Å. In the eighth C site, C(35) is bonded in a distorted single-bond geometry to one C(34) and one H(6,23) atom. The C(35)-H(6,23) bond length is 0.93 Å. In the ninth C site, C(36) is bonded in a distorted single-bond geometry to one C(31) and one H(24) atom. The C(36)-H(24) bond length is 0.93 Å. In the tenth C site, C(40) is bonded in a distorted single-bond geometry to one C(41) and one H(26) atom. The C(40)-C(41) bond length is 1.36 Å. The C(40)-H(26) bond length is 0.93 Å. In the eleventh C site, C(41) is bonded in a distorted trigonal planar geometry to one C(40), one C(42), and one N(4) atom. The C(41)-C(42) bond length is 1.36 Å. The C(41)-N(4) bond length is 1.42 Å. In the twelfth C site, C(42) is bonded in a distorted single-bond geometry to one C(41) and one H(27) atom. The C(42)-H(27) bond length is 0.93 Å. In the thirteenth C site, C(47) is bonded in a distorted single-bond geometry to one C(48) and one H(30) atom. The C(47)-C(48) bond length is 1.38 Å. The C(47)-H(30) bond length is 0.93 Å. In the fourteenth C site, C(48) is bonded in a distorted trigonal planar geometry to one C(47), one C(49), and one N(4) atom. The C(48)-C(49) bond length is 1.39 Å. The C(48)-N(4) bond length is 1.42 Å. In the fifteenth C site, C(49) is bonded in a distorted single-bond geometry to one C(48) and one H(31) atom. The C(49)-H(31) bond length is 0.93 Å. N(4) is bonded in a trigonal planar geometry to one C(34), one C(41), and one C(48) atom. There are ten inequivalent H sites. In the first H site, H(6,23) is bonded in a single-bond geometry to one C(11) atom. The H(6,23)-C(11) bond length is 0.93 Å. In the second H site, H(18) is bonded in a single-bond geometry to one C(27) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the fourth H site, H(21) is bonded in a single-bond geometry to one C(32) atom. In the fifth H site, H(22) is bonded in a single-bond geometry to one C(33) atom. In the sixth H site, H(24) is bonded in a single-bond geometry to one C(36) atom. In the seventh H site, H(26) is bonded in a single-bond geometry to one C(40) atom. In the eighth H site, H(27) is bonded in a single-bond geometry to one C(42) atom. In the ninth H site, H(30) is bonded in a single-bond geometry to one C(47) atom. In the tenth H site, H(31) is bonded in a single-bond geometry to one C(49) atom. In four of the ZnC16N3H11O4 clusters, Zn(1) is bonded in a 6-coordinate geometry to one N(1), one N(7), one O(5), one O(6), one O(7), and one O(8) atom. The Zn(1)-N(1) bond length is 2.07 Å. The Zn(1)-N(7) bond length is 2.03 Å. The Zn(1)-O(5) bond length is 2.00 Å. The Zn(1)-O(6) bond length is 2.51 Å. The Zn(1)-O(7) bond length is 2.14 Å. The Zn(1)-O(8) bond length is 2.25 Å. There are sixteen inequivalent C sites. In the first C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(15)-N(1) bond length is 1.34 Å. The C(15)-H(9) bond length is 0.93 Å. In the second C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(12) atom. The C(19)-N(1) bond length is 1.32 Å. The C(19)-H(12) bond length is 0.93 Å. In the third C site, C(37) is bonded in a bent 120 degrees geometry to one C(38), one O(7), and one O(8) atom. The C(37)-C(38) bond length is 1.50 Å. The C(37)-O(7) bond length is 1.19 Å. The C(37)-O(8) bond length is 1.20 Å. In the fourth C site, C(38) is bonded in a trigonal planar geometry to one C(37), one C(39), and one C(43) atom. The C(38)-C(39) bond length is 1.34 Å. The C(38)-C(43) bond length is 1.35 Å. In the fifth C site, C(39) is bonded in a distorted single-bond geometry to one C(38) and one H(25) atom. The C(39)-H(25) bond length is 0.93 Å. In the sixth C site, C(43) is bonded in a distorted single-bond geometry to one C(38) and one H(28) atom. The C(43)-H(28) bond length is 0.93 Å. In the seventh C site, C(44) is bonded in a distorted bent 120 degrees geometry to one C(45), one O(5), and one O(6) atom. The C(44)-C(45) bond length is 1.51 Å. The C(44)-O(5) bond length is 1.27 Å. The C(44)-O(6) bond length is 1.25 Å. In the eighth C site, C(45) is bonded in a trigonal planar geometry to one C(44), one C(46), and one C(50) atom. The C(45)-C(46) bond length is 1.38 Å. The C(45)-C(50) bond length is 1.37 Å. In the ninth C site, C(46) is bonded in a distorted single-bond geometry to one C(45) and one H(29) atom. The C(46)-H(29) bond length is 0.93 Å. In the tenth C site, C(50) is bonded in a distorted single-bond geometry to one C(45) and one H(32) atom. The C(50)-H(32) bond length is 0.93 Å. In the eleventh C site, C(57) is bonded in a distorted trigonal planar geometry to one C(58), one N(7), and one H(38) atom. The C(57)-C(58) bond length is 1.34 Å. The C(57)-N(7) bond length is 1.38 Å. The C(57)-H(38) bond length is 0.93 Å. In the twelfth C site, C(58) is bonded in a 2-coordinate geometry to one C(57), one N(8), and one H(39) atom. The C(58)-N(8) bond length is 1.36 Å. The C(58)-H(39) bond length is 0.93 Å. In the thirteenth C site, C(59) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(40) atom. The C(59)-N(7) bond length is 1.30 Å. The C(59)-N(8) bond length is 1.34 Å. The C(59)-H(40) bond length is 0.93 Å. In the fourteenth C site, C(60) is bonded in a single-bond geometry to one C(61) and one H(41) atom. The C(60)-C(61) bond length is 1.38 Å. The C(60)-H(41) bond length is 0.93 Å. In the fifteenth C site, C(61) is bonded in a distorted trigonal planar geometry to one C(60), one C(62), and one N(8) atom. The C(61)-C(62) bond length is 1.38 Å. The C(61)-N(8) bond length is 1.43 Å. In the sixteenth C site, C(62) is bonded in a distorted single-bond geometry to one C(61) and one H(42) atom. The C(62)-H(42) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(19) atom. In the second N site, N(7) is bonded in a trigonal planar geometry to one Zn(1), one C(57), and one C(59) atom. In the third N site, N(8) is bonded in a trigonal planar geometry to one C(58), one C(59), and one C(61) atom. There are eleven inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the third H site, H(25) is bonded in a single-bond geometry to one C(39) atom. In the fourth H site, H(28) is bonded in a single-bond geometry to one C(43) atom. In the fifth H site, H(29) is bonded in a single-bond geometry to one C(46) atom. In the sixth H site, H(32) is bonded in a single-bond geometry to one C(50) atom. In the seventh H site, H(38) is bonded in a single-bond geometry to one C(57) atom. In the eighth H site, H(40) is bonded in a single-bond geometry to one C(59) atom. In the ninth H site, H(39) is bonded in a single-bond geometry to one C(58) atom. In the tenth H site, H(41) is bonded in a single-bond geometry to one C(60) atom. In the eleventh H site, H(42) is bonded in a single-bond geometry to one C(62) atom. There are four inequivalent O sites. In the first O site, O(5) is bonded in a water-like geometry to one Zn(1) and one C(44) atom. In the second O site, O(6) is bonded in a single-bond geometry to one Zn(1) and one C(44) atom. In the third O site, O(7) is bonded in a distorted water-like geometry to one Zn(1) and one C(37) atom. In the fourth O site, O(8) is bonded in a distorted L-shaped geometry to one Zn(1) and one C(37) atom. In four of the ZnC16N3H11O4 clusters, Zn(2) is bonded in a 5-coordinate geometry to one N(3), one N(5), one O(1), one O(2), and one O(3) atom. The Zn(2)-N(3) bond length is 2.06 Å. The Zn(2)-N(5) bond length is 2.01 Å. The Zn(2)-O(1) bond length is 2.05 Å. The Zn(2)-O(2) bond length is 2.43 Å. The Zn(2)-O(3) bond length is 1.96 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(7) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(8)-C(9) bond length is 1.50 Å. The C(8)-O(3) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.24 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-C(14) bond length is 1.37 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(10)-H(5) bond length is 0.93 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. In the ninth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(26)-N(3) bond length is 1.32 Å. The C(26)-H(17) bond length is 0.93 Å. In the tenth C site, C(30) is bonded in a 2-coordinate geometry to one N(3) and one H(20) atom. The C(30)-N(3) bond length is 1.35 Å. The C(30)-H(20) bond length is 0.93 Å. In the eleventh C site, C(51) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(33) atom. The C(51)-N(5) bond length is 1.31 Å. The C(51)-N(6) bond length is 1.33 Å. The C(51)-H(33) bond length is 0.93 Å. In the twelfth C site, C(52) is bonded in a 3-coordinate geometry to one C(53), one N(6), and one H(34) atom. The C(52)-C(53) bond length is 1.33 Å. The C(52)-N(6) bond length is 1.38 Å. The C(52)-H(34) bond length is 0.93 Å. In the thirteenth C site, C(53) is bonded in a distorted bent 120 degrees geometry to one C(52), one N(5), and one H(35) atom. The C(53)-N(5) bond length is 1.36 Å. The C(53)-H(35) bond length is 0.93 Å. In the fourteenth C site, C(54) is bonded in a distorted single-bond geometry to one C(55) and one H(36) atom. The C(54)-C(55) bond length is 1.38 Å. The C(54)-H(36) bond length is 0.93 Å. In the fifteenth C site, C(55) is bonded in a trigonal planar geometry to one C(54), one C(56), and one N(6) atom. The C(55)-C(56) bond length is 1.38 Å. The C(55)-N(6) bond length is 1.43 Å. In the sixteenth C site, C(56) is bonded in a distorted single-bond geometry to one C(55) and one H(37) atom. The C(56)-H(37) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(26), and one C(30) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Zn(2), one C(51), and one C(53) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one C(51), one C(52), and one C(55) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one C(30) atom. In the seventh H site, H(33) is bonded in a single-bond geometry to one C(51) atom. In the eighth H site, H(34) is bonded in a single-bond geometry to one C(52) atom. In the ninth H site, H(35) is bonded in a single-bond geometry to one C(53) atom. In the tenth H site, H(36) is bonded in a single-bond geometry to one C(54) atom. In the eleventh H site, H(37) is bonded in a single-bond geometry to one C(56) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(2) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Zn(2) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(8) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(8) atom. Linkers: 4 c1cn(-c2ccc(-n3ccnc3)cc2)cn1 ,8 [O]C(=O)c1ccc(N(c2ccc(C([O])=O)cc2)c2ccc(-c3ccncc3)cc2)cc1. Metal clusters: 4 O=[C]O[Zn]1O[C]O1 ,4 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 6.31 A, density 1.10 g/cm3, surface area 4903.45 m2/g, accessible volume 0.34 cm3/g