Mn3C21N8H11O9(CH)17(CH2)10(CH3)3 crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of one hundred and forty-four 02329_fluka molecules, one hundred and sixty 02329_fluka molecules, forty-eight 02329_fluka molecules, thirty-two isobutylene molecules, and eight Mn3C21N8H11O9 clusters. In each Mn3C21N8H11O9 cluster, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted octahedral geometry to one N(1), one N(3), one N(7), one O(1), one O(3), and one O(8) atom. The Mn(1)-N(1) bond length is 1.94 Å. The Mn(1)-N(3) bond length is 2.29 Å. The Mn(1)-N(7) bond length is 2.23 Å. The Mn(1)-O(1) bond length is 1.85 Å. The Mn(1)-O(3) bond length is 1.92 Å. The Mn(1)-O(8) bond length is 1.98 Å. In the second Mn site, Mn(2) is bonded in a distorted square pyramidal geometry to one N(2), one N(4), one O(2), one O(4), and one O(6) atom. The Mn(2)-N(2) bond length is 2.24 Å. The Mn(2)-N(4) bond length is 1.93 Å. The Mn(2)-O(2) bond length is 1.97 Å. The Mn(2)-O(4) bond length is 1.86 Å. The Mn(2)-O(6) bond length is 1.93 Å. In the third Mn site, Mn(3) is bonded in a distorted octahedral geometry to one N(5), one N(6), one N(8), one O(5), one O(7), and one O(9) atom. The Mn(3)-N(5) bond length is 2.26 Å. The Mn(3)-N(6) bond length is 1.94 Å. The Mn(3)-N(8) bond length is 2.28 Å. The Mn(3)-O(5) bond length is 1.98 Å. The Mn(3)-O(7) bond length is 1.86 Å. The Mn(3)-O(9) bond length is 1.92 Å. There are twenty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one O(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-O(1) bond length is 1.33 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.47 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one O(2) atom. The C(7)-N(1) bond length is 1.32 Å. The C(7)-O(2) bond length is 1.28 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(3) atom. The C(8)-N(2) bond length is 1.29 Å. The C(8)-O(3) bond length is 1.30 Å. In the sixth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(16) atom. The C(14)-N(3) bond length is 1.32 Å. The C(14)-H(16) bond length is 0.95 Å. In the seventh C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(19) atom. The C(18)-N(3) bond length is 1.33 Å. The C(18)-H(19) bond length is 0.95 Å. In the eighth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one O(4) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-O(4) bond length is 1.33 Å. In the ninth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(26) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-C(26) bond length is 1.47 Å. In the tenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(22) atom. The C(22)-H(22) bond length is 0.95 Å. In the eleventh C site, C(26) is bonded in a distorted trigonal planar geometry to one C(21), one N(4), and one O(5) atom. The C(26)-N(4) bond length is 1.31 Å. The C(26)-O(5) bond length is 1.27 Å. In the twelfth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(28), one N(5), and one O(6) atom. The C(27)-C(28) bond length is 1.49 Å. The C(27)-N(5) bond length is 1.30 Å. The C(27)-O(6) bond length is 1.30 Å. In the thirteenth C site, C(28) is bonded in a water-like geometry to one C(27) and two equivalent H(26,27) atoms. Both C(28)-H(26,27) bond lengths are 0.99 Å. In the fourteenth C site, C(33) is bonded in a distorted single-bond geometry to one C(34) and one O(7) atom. The C(33)-C(34) bond length is 1.39 Å. The C(33)-O(7) bond length is 1.33 Å. In the fifteenth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(39) atom. The C(34)-C(35) bond length is 1.40 Å. The C(34)-C(39) bond length is 1.47 Å. In the sixteenth C site, C(35) is bonded in a distorted single-bond geometry to one C(34) and one H(37) atom. The C(35)-H(37) bond length is 0.95 Å. In the seventeenth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one C(34), one N(6), and one O(8) atom. The C(39)-N(6) bond length is 1.31 Å. The C(39)-O(8) bond length is 1.28 Å. In the eighteenth C site, C(40) is bonded in a distorted trigonal planar geometry to one C(41), one N(7), and one O(9) atom. The C(40)-C(41) bond length is 1.49 Å. The C(40)-N(7) bond length is 1.29 Å. The C(40)-O(9) bond length is 1.30 Å. In the nineteenth C site, C(41) is bonded in a water-like geometry to one C(40) and two equivalent H(41,42) atoms. Both C(41)-H(41,42) bond lengths are 0.99 Å. In the twentieth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(52) atom. The C(46)-N(8) bond length is 1.33 Å. The C(46)-H(52) bond length is 0.95 Å. In the twenty-first C site, C(50) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(55) atom. The C(50)-N(8) bond length is 1.33 Å. The C(50)-H(55) bond length is 0.95 Å. There are eight inequivalent N sites. In the first N site, N(8) is bonded in a trigonal planar geometry to one Mn(3), one C(46), and one C(50) atom. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(7), and one N(2) atom. The N(1)-N(2) bond length is 1.41 Å. In the third N site, N(2) is bonded in a 3-coordinate geometry to one Mn(2), one C(8), and one N(1) atom. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one Mn(1), one C(14), and one C(18) atom. In the fifth N site, N(4) is bonded in a distorted trigonal planar geometry to one Mn(2), one C(26), and one N(5) atom. The N(4)-N(5) bond length is 1.42 Å. In the sixth N site, N(5) is bonded in a 3-coordinate geometry to one Mn(3), one C(27), and one N(4) atom. In the seventh N site, N(6) is bonded in a distorted trigonal planar geometry to one Mn(3), one C(39), and one N(7) atom. The N(6)-N(7) bond length is 1.41 Å. In the eighth N site, N(7) is bonded in a 3-coordinate geometry to one Mn(1), one C(40), and one N(6) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the fourth H site, H(22) is bonded in a single-bond geometry to one C(22) atom. In the fifth H site, H(26,27) is bonded in a single-bond geometry to one C(28) atom. In the sixth H site, H(37) is bonded in a single-bond geometry to one C(35) atom. In the seventh H site, H(41,42) is bonded in a single-bond geometry to one C(41) atom. In the eighth H site, H(52) is bonded in a single-bond geometry to one C(46) atom. In the ninth H site, H(55) is bonded in a single-bond geometry to one C(50) atom. There are nine inequivalent O sites. In the first O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(39) atom. In the second O site, O(9) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(40) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(7) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(8) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(20) atom. In the seventh O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(26) atom. In the eighth O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(27) atom. In the ninth O site, O(7) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(33) atom. Linkers: 24 CCCCCC(=O)[N][N]C(=O)c1ccccc1[O] ,8 c1cc(CCc2ccncc2)ccn1. Metal clusters: 24 [Mn]. The MOF has largest included sphere 8.83 A, density 1.00 g/cm3, surface area 5041.29 m2/g, accessible volume 0.48 cm3/g