Dy2C33N3H17O13(CH)6 crystallizes in the triclinic P-1 space group. The structure consists of twelve 02329_fluka molecules inside a Dy2C33N3H17O13 framework. In the Dy2C33N3H17O13 framework, there are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded to one O(1), one O(11), one O(12), one O(5), one O(8), and two equivalent O(6) atoms to form distorted edge-sharing DyO7 pentagonal bipyramids. The Dy(1)-O(1) bond length is 2.23 Å. The Dy(1)-O(11) bond length is 2.36 Å. The Dy(1)-O(12) bond length is 2.37 Å. The Dy(1)-O(5) bond length is 2.42 Å. The Dy(1)-O(8) bond length is 2.31 Å. There is one shorter (2.38 Å) and one longer (2.52 Å) Dy(1)-O(6) bond length. In the second Dy site, Dy(2) is bonded in a 7-coordinate geometry to one H(1), one O(10), one O(2), one O(3), one O(4), one O(7), and one O(9) atom. The Dy(2)-H(1) bond length is 2.08 Å. The Dy(2)-O(10) bond length is 2.39 Å. The Dy(2)-O(2) bond length is 2.34 Å. The Dy(2)-O(3) bond length is 2.43 Å. The Dy(2)-O(4) bond length is 2.49 Å. The Dy(2)-O(7) bond length is 2.26 Å. The Dy(2)-O(9) bond length is 2.31 Å. There are thirty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(6) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-C(7) bond length is 1.50 Å. In the fifth C site, C(5) is bonded in a 3-coordinate geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(5) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-H(5) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(4), and one C(8) atom. The C(7)-C(12) bond length is 1.40 Å. The C(7)-C(8) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 0.93 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(9) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(9) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(7) atom. The C(12)-C(13) bond length is 1.50 Å. In the eleventh C site, C(13) is bonded in a bent 120 degrees geometry to one C(12), one O(3), and one O(4) atom. The C(13)-O(3) bond length is 1.26 Å. The C(13)-O(4) bond length is 1.27 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(5), and one O(6) atom. The C(14)-C(15) bond length is 1.50 Å. The C(14)-O(5) bond length is 1.24 Å. The C(14)-O(6) bond length is 1.27 Å. In the thirteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(20) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-C(20) bond length is 1.40 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.49 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(10) atom. The C(17)-H(10) bond length is 0.93 Å. In the sixteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(15) and one H(13,20) atom. The C(20)-H(13,20) bond length is 0.93 Å. In the seventeenth C site, C(21) is bonded in a trigonal planar geometry to one C(16), one C(22), and one C(25) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(25) bond length is 1.39 Å. In the eighteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(14) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(14) bond length is 0.93 Å. In the nineteenth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(26) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(26) bond length is 1.49 Å. In the twentieth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(23), one N(2), and one H(15) atom. The C(24)-N(2) bond length is 1.33 Å. The C(24)-H(15) bond length is 0.93 Å. In the twenty-first C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(2), and one H(16) atom. The C(25)-N(2) bond length is 1.35 Å. The C(25)-H(16) bond length is 0.93 Å. In the twenty-second C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(7), and one O(8) atom. The C(26)-O(7) bond length is 1.27 Å. The C(26)-O(8) bond length is 1.25 Å. In the twenty-third C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(10), and one O(9) atom. The C(27)-C(28) bond length is 1.50 Å. The C(27)-O(10) bond length is 1.25 Å. The C(27)-O(9) bond length is 1.27 Å. In the twenty-fourth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(33) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-C(33) bond length is 1.41 Å. In the twenty-fifth C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(17) atom. The C(29)-H(17) bond length is 0.93 Å. In the twenty-sixth C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(13,20) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-H(13,20) bond length is 0.93 Å. In the twenty-seventh C site, C(33) is bonded in a trigonal planar geometry to one C(28), one C(32), and one C(34) atom. The C(33)-C(34) bond length is 1.49 Å. In the twenty-eighth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(38) atom. The C(34)-C(35) bond length is 1.39 Å. The C(34)-C(38) bond length is 1.40 Å. In the twenty-ninth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(34), one N(3), and one H(21) atom. The C(35)-N(3) bond length is 1.35 Å. The C(35)-H(21) bond length is 0.93 Å. In the thirtieth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(37), one N(3), and one H(22) atom. The C(36)-C(37) bond length is 1.39 Å. The C(36)-N(3) bond length is 1.35 Å. The C(36)-H(22) bond length is 0.93 Å. In the thirty-first C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one C(39) atom. The C(37)-C(38) bond length is 1.39 Å. The C(37)-C(39) bond length is 1.49 Å. In the thirty-second C site, C(38) is bonded in a distorted single-bond geometry to one C(34), one C(37), and one H(23) atom. The C(38)-H(23) bond length is 0.93 Å. In the thirty-third C site, C(39) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(11), and one O(12) atom. The C(39)-O(11) bond length is 1.27 Å. The C(39)-O(12) bond length is 1.27 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(5) and one C(6) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(24) and one C(25) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(35) and one C(36) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one Dy(2) and one O(13) atom. The H(1)-O(13) bond length is 0.85 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(13) atom. The H(2)-O(13) bond length is 0.73 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(13,20) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(24) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(29) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(35) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(36) atom. In the sixteenth H site, H(23) is bonded in a single-bond geometry to one C(38) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Dy(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Dy(2) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Dy(2) and one C(13) atom. In the fourth O site, O(7) is bonded in a distorted linear geometry to one Dy(2) and one C(26) atom. In the fifth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one C(26) atom. In the sixth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Dy(2) and one C(27) atom. In the seventh O site, O(13) is bonded in a bent 150 degrees geometry to one H(1) and one H(2) atom. In the eighth O site, O(4) is bonded in a distorted single-bond geometry to one Dy(2) and one C(13) atom. In the ninth O site, O(5) is bonded in a distorted single-bond geometry to one Dy(1) and one C(14) atom. In the tenth O site, O(6) is bonded in a distorted single-bond geometry to two equivalent Dy(1) and one C(14) atom. In the eleventh O site, O(10) is bonded in a distorted single-bond geometry to one Dy(2) and one C(27) atom. In the twelfth O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one C(39) atom. In the thirteenth O site, O(12) is bonded in a 2-coordinate geometry to one Dy(1) and one C(39) atom. Linkers: 6 [O]C(=O)c1cncc(-c2ccccc2C([O])=O)c1. Metal clusters: 4 [Dy]. The MOF has largest included sphere 4.72 A, density 1.69 g/cm3, surface area 3517.07 m2/g, accessible volume 0.24 cm3/g