CdC16H14(NO)4(CH2)3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and four CdC16H14(NO)4 clusters. In each CdC16H14(NO)4 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(4), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.26 Å. The Cd(1)-N(4) bond length is 2.24 Å. The Cd(1)-O(1) bond length is 2.28 Å. The Cd(1)-O(2) bond length is 2.48 Å. The Cd(1)-O(3) bond length is 2.33 Å. The Cd(1)-O(4) bond length is 2.40 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(4) bond length is 1.40 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(2) and one H(1,2) atom. The C(3)-H(1,2) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a single-bond geometry to one C(2) and one H(1,2) atom. The C(4)-H(1,2) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(3), and one O(4) atom. The C(5)-C(6) bond length is 1.50 Å. The C(5)-O(3) bond length is 1.26 Å. The C(5)-O(4) bond length is 1.25 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-C(8) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(3,4) atom. The C(7)-H(3,4) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one H(3,4) atom. The C(8)-H(3,4) bond length is 0.95 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(5) atom. The C(9)-N(1) bond length is 1.32 Å. The C(9)-N(2) bond length is 1.34 Å. The C(9)-H(5) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one H(6) atom. The C(10)-C(11) bond length is 1.35 Å. The C(10)-N(1) bond length is 1.38 Å. The C(10)-H(6) bond length is 0.95 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(7) atom. The C(11)-N(2) bond length is 1.38 Å. The C(11)-H(7) bond length is 0.95 Å. In the twelfth C site, C(12) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(8,9) atoms. The C(12)-N(2) bond length is 1.47 Å. Both C(12)-H(8,9) bond lengths are 0.99 Å. In the thirteenth C site, C(16) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(16,17) atoms. The C(16)-N(3) bond length is 1.47 Å. Both C(16)-H(16,17) bond lengths are 0.99 Å. In the fourteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(18) atom. The C(17)-N(3) bond length is 1.37 Å. The C(17)-H(18) bond length is 0.95 Å. In the fifteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(19) atom. The C(18)-N(4) bond length is 1.38 Å. The C(18)-H(19) bond length is 0.95 Å. In the sixteenth C site, C(19) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(20) atom. The C(19)-N(3) bond length is 1.34 Å. The C(19)-N(4) bond length is 1.32 Å. The C(19)-H(20) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(16), one C(17), and one C(19) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(18), and one C(19) atom. There are ten inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8,9) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(16,17) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(19) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(5) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Cd(1) and one C(5) atom. Linkers: 4 [O]C(=O)c1ccc(C([O])=O)cc1 ,4 c1cn(CCCCCn2ccnc2)cn1. Metal clusters: 4 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 4.75 A, density 1.33 g/cm3, surface area 4616.15 m2/g, accessible volume 0.32 cm3/g