Gd2Ag6C36N12H14O25 crystallizes in the triclinic P-1 space group. There are two inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a distorted pentagonal planar geometry to one O(1), one O(18), one O(25), one O(3), and one O(5) atom. The Gd(1)-O(1) bond length is 2.42 Å. The Gd(1)-O(18) bond length is 2.37 Å. The Gd(1)-O(25) bond length is 2.38 Å. The Gd(1)-O(3) bond length is 2.39 Å. The Gd(1)-O(5) bond length is 2.36 Å. In the second Gd site, Gd(2) is bonded in a 3-coordinate geometry to one O(13), one O(15), and one O(9) atom. The Gd(2)-O(13) bond length is 2.31 Å. The Gd(2)-O(15) bond length is 2.43 Å. The Gd(2)-O(9) bond length is 2.39 Å. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 5-coordinate geometry to one N(4), one N(5), one O(16), one O(17), and one O(23) atom. The Ag(1)-N(4) bond length is 2.26 Å. The Ag(1)-N(5) bond length is 2.27 Å. The Ag(1)-O(16) bond length is 2.77 Å. The Ag(1)-O(17) bond length is 2.48 Å. The Ag(1)-O(23) bond length is 2.55 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one N(8), one N(9), one O(19), and one O(21) atom. The Ag(2)-N(8) bond length is 2.34 Å. The Ag(2)-N(9) bond length is 2.21 Å. The Ag(2)-O(19) bond length is 2.77 Å. The Ag(2)-O(21) bond length is 2.31 Å. In the third Ag site, Ag(3) is bonded in a 5-coordinate geometry to one N(2), one N(7), one O(24), one O(4), and one O(7) atom. The Ag(3)-N(2) bond length is 2.28 Å. The Ag(3)-N(7) bond length is 2.27 Å. The Ag(3)-O(24) bond length is 2.56 Å. The Ag(3)-O(4) bond length is 2.45 Å. The Ag(3)-O(7) bond length is 2.76 Å. In the fourth Ag site, Ag(4) is bonded in a 5-coordinate geometry to one N(11), one N(6), one O(11), one O(14), and one O(20) atom. The Ag(4)-N(11) bond length is 2.31 Å. The Ag(4)-N(6) bond length is 2.28 Å. The Ag(4)-O(11) bond length is 2.72 Å. The Ag(4)-O(14) bond length is 2.45 Å. The Ag(4)-O(20) bond length is 2.52 Å. In the fifth Ag site, Ag(5) is bonded in a distorted pentagonal planar geometry to one N(10), one N(12), one O(15), one O(8), and one O(9) atom. The Ag(5)-N(10) bond length is 2.26 Å. The Ag(5)-N(12) bond length is 2.28 Å. The Ag(5)-O(15) bond length is 2.68 Å. The Ag(5)-O(8) bond length is 2.49 Å. The Ag(5)-O(9) bond length is 2.64 Å. In the sixth Ag site, Ag(6) is bonded in a distorted pentagonal planar geometry to one N(1), one N(3), one O(1), one O(12), and one O(5) atom. The Ag(6)-N(1) bond length is 2.30 Å. The Ag(6)-N(3) bond length is 2.28 Å. The Ag(6)-O(1) bond length is 2.65 Å. The Ag(6)-O(12) bond length is 2.47 Å. The Ag(6)-O(5) bond length is 2.65 Å. There are thirty-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(2) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.52 Å. The C(1)-N(2) bond length is 1.36 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one N(1) atom. The C(2)-C(5) bond length is 1.54 Å. The C(2)-N(1) bond length is 1.36 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1) atom. The C(3)-N(2) bond length is 1.33 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(4)-N(1) bond length is 1.33 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(5)-O(1) bond length is 1.29 Å. The C(5)-O(2) bond length is 1.22 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(3), and one O(4) atom. The C(6)-O(3) bond length is 1.27 Å. The C(6)-O(4) bond length is 1.21 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(11), one C(8), and one N(3) atom. The C(7)-C(11) bond length is 1.51 Å. The C(7)-C(8) bond length is 1.38 Å. The C(7)-N(3) bond length is 1.34 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(12), one C(7), and one N(4) atom. The C(8)-C(12) bond length is 1.54 Å. The C(8)-N(4) bond length is 1.34 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(3) atom. The C(9)-N(4) bond length is 1.33 Å. The C(9)-H(3) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(4) atom. The C(10)-N(3) bond length is 1.33 Å. The C(10)-H(4) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(5), and one O(6) atom. The C(11)-O(5) bond length is 1.26 Å. The C(11)-O(6) bond length is 1.22 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(7), and one O(8) atom. The C(12)-O(7) bond length is 1.25 Å. The C(12)-O(8) bond length is 1.24 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one C(17), and one N(8) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(17) bond length is 1.50 Å. The C(13)-N(8) bond length is 1.35 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(18), and one N(7) atom. The C(14)-C(18) bond length is 1.54 Å. The C(14)-N(7) bond length is 1.33 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(5) atom. The C(15)-N(8) bond length is 1.34 Å. The C(15)-H(5) bond length is 0.93 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(6) atom. The C(16)-N(7) bond length is 1.34 Å. The C(16)-H(6) bond length is 0.93 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(21), and one O(22) atom. The C(17)-O(21) bond length is 1.24 Å. The C(17)-O(22) bond length is 1.25 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(23), and one O(24) atom. The C(18)-O(23) bond length is 1.23 Å. The C(18)-O(24) bond length is 1.25 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(20), one C(23), and one N(9) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-C(23) bond length is 1.54 Å. The C(19)-N(9) bond length is 1.33 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one N(10) atom. The C(20)-N(10) bond length is 1.34 Å. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(7) atom. The C(21)-N(9) bond length is 1.33 Å. The C(21)-H(7) bond length is 0.93 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(8) atom. The C(22)-N(10) bond length is 1.33 Å. The C(22)-H(8) bond length is 0.93 Å. In the twenty-third C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(11), and one O(12) atom. The C(23)-O(11) bond length is 1.26 Å. The C(23)-O(12) bond length is 1.24 Å. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(24)-O(10) bond length is 1.22 Å. The C(24)-O(9) bond length is 1.27 Å. In the twenty-fifth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one C(29), and one N(11) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(29) bond length is 1.53 Å. The C(25)-N(11) bond length is 1.34 Å. In the twenty-sixth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one C(30), and one N(12) atom. The C(26)-C(30) bond length is 1.53 Å. The C(26)-N(12) bond length is 1.34 Å. In the twenty-seventh C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(28), one N(11), and one H(9) atom. The C(27)-C(28) bond length is 1.36 Å. The C(27)-N(11) bond length is 1.34 Å. The C(27)-H(9) bond length is 0.93 Å. In the twenty-eighth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one N(12), and one H(10) atom. The C(28)-N(12) bond length is 1.34 Å. The C(28)-H(10) bond length is 0.93 Å. In the twenty-ninth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(13), and one O(14) atom. The C(29)-O(13) bond length is 1.26 Å. The C(29)-O(14) bond length is 1.22 Å. In the thirtieth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(15), and one O(16) atom. The C(30)-O(15) bond length is 1.26 Å. The C(30)-O(16) bond length is 1.24 Å. In the thirty-first C site, C(31) is bonded in a distorted trigonal planar geometry to one C(32), one C(35), and one N(6) atom. The C(31)-C(32) bond length is 1.40 Å. The C(31)-C(35) bond length is 1.53 Å. The C(31)-N(6) bond length is 1.33 Å. In the thirty-second C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31), one C(36), and one N(5) atom. The C(32)-C(36) bond length is 1.51 Å. The C(32)-N(5) bond length is 1.35 Å. In the thirty-third C site, C(33) is bonded in a distorted trigonal planar geometry to one C(34), one N(6), and one H(11) atom. The C(33)-C(34) bond length is 1.37 Å. The C(33)-N(6) bond length is 1.33 Å. The C(33)-H(11) bond length is 0.93 Å. In the thirty-fourth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(33), one N(5), and one H(12) atom. The C(34)-N(5) bond length is 1.33 Å. The C(34)-H(12) bond length is 0.93 Å. In the thirty-fifth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(19), and one O(20) atom. The C(35)-O(19) bond length is 1.25 Å. The C(35)-O(20) bond length is 1.24 Å. In the thirty-sixth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(17), and one O(18) atom. The C(36)-O(17) bond length is 1.24 Å. The C(36)-O(18) bond length is 1.27 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(6), one C(2), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(3), one C(1), and one C(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(6), one C(10), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(1), one C(8), and one C(9) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Ag(1), one C(32), and one C(34) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Ag(4), one C(31), and one C(33) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Ag(3), one C(14), and one C(16) atom. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(13), and one C(15) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Ag(2), one C(19), and one C(21) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Ag(5), one C(20), and one C(22) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Ag(4), one C(25), and one C(27) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Ag(5), one C(26), and one C(28) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(28) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(33) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(34) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one O(25) atom. The H(13)-O(25) bond length is 0.85 Å. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one O(25) atom. The H(14)-O(25) bond length is 0.85 Å. There are twenty-five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Gd(1), one Ag(6), and one C(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(5) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Gd(1) and one C(6) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(3) and one C(6) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Gd(1), one Ag(6), and one C(11) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Ag(3) and one C(12) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Ag(5) and one C(12) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Gd(2), one Ag(5), and one C(24) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(24) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Ag(4) and one C(23) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Ag(6) and one C(23) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Gd(2) and one C(29) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Ag(4) and one C(29) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Gd(2), one Ag(5), and one C(30) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one Ag(1) and one C(30) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Ag(1) and one C(36) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one C(36) atom. In the nineteenth O site, O(19) is bonded in a single-bond geometry to one Ag(2) and one C(35) atom. In the twentieth O site, O(20) is bonded in a distorted single-bond geometry to one Ag(4) and one C(35) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 120 degrees geometry to one Ag(2) and one C(17) atom. In the twenty-second O site, O(22) is bonded in a single-bond geometry to one C(17) atom. In the twenty-third O site, O(23) is bonded in a distorted single-bond geometry to one Ag(1) and one C(18) atom. In the twenty-fourth O site, O(24) is bonded in a distorted single-bond geometry to one Ag(3) and one C(18) atom. In the twenty-fifth O site, O(25) is bonded in a distorted water-like geometry to one Gd(1), one H(13), and one H(14) atom. Linkers: 11 [O]C(=O)c1nccnc1C([O])=O. Metal clusters: 4 [Gd] ,12 [Ag]. The MOF has largest included sphere 5.23 A, density 2.20 g/cm3, surface area 2466.81 m2/g, accessible volume 0.14 cm3/g