CuC20NH12O5 crystallizes in the triclinic P1 space group. There are eight inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(12), one O(18), and one O(27) atom. The Cu(1)-N(1) bond length is 2.04 Å. The Cu(1)-O(1) bond length is 1.85 Å. The Cu(1)-O(12) bond length is 1.86 Å. The Cu(1)-O(18) bond length is 1.86 Å. The Cu(1)-O(27) bond length is 1.85 Å. In the second Cu site, Cu(2) is bonded in a distorted square pyramidal geometry to one N(2), one O(10), one O(20), one O(25), and one O(3) atom. The Cu(2)-N(2) bond length is 2.04 Å. The Cu(2)-O(10) bond length is 1.86 Å. The Cu(2)-O(20) bond length is 1.86 Å. The Cu(2)-O(25) bond length is 1.85 Å. The Cu(2)-O(3) bond length is 1.85 Å. In the third Cu site, Cu(3) is bonded in a distorted square pyramidal geometry to one N(3); one O(14); one O(21,29); one O(22,30); and one O(5) atom. The Cu(3)-N(3) bond length is 2.03 Å. The Cu(3)-O(14) bond length is 1.86 Å. The Cu(3)-O(21,29) bond length is 1.85 Å. The Cu(3)-O(22,30) bond length is 1.86 Å. The Cu(3)-O(5) bond length is 1.85 Å. In the fourth Cu site, Cu(4) is bonded in a distorted square pyramidal geometry to one N(4), one O(16), one O(24), one O(31), and one O(7) atom. The Cu(4)-N(4) bond length is 2.03 Å. The Cu(4)-O(16) bond length is 1.86 Å. The Cu(4)-O(24) bond length is 1.86 Å. The Cu(4)-O(31) bond length is 1.85 Å. The Cu(4)-O(7) bond length is 1.85 Å. In the fifth Cu site, Cu(5) is bonded in a distorted square pyramidal geometry to one N(5), one O(19), one O(26), one O(4), and one O(9) atom. The Cu(5)-N(5) bond length is 2.04 Å. The Cu(5)-O(19) bond length is 1.85 Å. The Cu(5)-O(26) bond length is 1.86 Å. The Cu(5)-O(4) bond length is 1.85 Å. The Cu(5)-O(9) bond length is 1.85 Å. In the sixth Cu site, Cu(6) is bonded in a distorted square pyramidal geometry to one N(6), one O(11), one O(17), one O(2), and one O(28) atom. The Cu(6)-N(6) bond length is 2.04 Å. The Cu(6)-O(11) bond length is 1.85 Å. The Cu(6)-O(17) bond length is 1.85 Å. The Cu(6)-O(2) bond length is 1.86 Å. The Cu(6)-O(28) bond length is 1.85 Å. In the seventh Cu site, Cu(7) is bonded in a distorted square pyramidal geometry to one N(7); one O(13); one O(21,29); one O(22,30); and one O(6) atom. The Cu(7)-N(7) bond length is 2.03 Å. The Cu(7)-O(13) bond length is 1.85 Å. The Cu(7)-O(21,29) bond length is 1.85 Å. The Cu(7)-O(22,30) bond length is 1.86 Å. The Cu(7)-O(6) bond length is 1.86 Å. In the eighth Cu site, Cu(8) is bonded in a distorted square pyramidal geometry to one N(8), one O(15), one O(23), one O(32), and one O(8) atom. The Cu(8)-N(8) bond length is 2.03 Å. The Cu(8)-O(15) bond length is 1.85 Å. The Cu(8)-O(23) bond length is 1.85 Å. The Cu(8)-O(32) bond length is 1.86 Å. The Cu(8)-O(8) bond length is 1.86 Å. There are one hundred and sixteen inequivalent C sites. In the first C site, C(1,118) is bonded in a distorted bent 120 degrees geometry to one C(2,119); one N(1); and one H(65,67,89,91) atom. The C(1,118)-C(2,119) bond length is 1.41 Å. The C(1,118)-N(1) bond length is 1.36 Å. The C(1,118)-H(65,67,89,91) bond length is 1.08 Å. In the second C site, C(2,119) is bonded in a distorted trigonal planar geometry to one C(1,118); one C(145); and one H(66,92) atom. The C(2,119)-C(145) bond length is 1.42 Å. The C(2,119)-H(66,92) bond length is 1.08 Å. In the third C site, C(3) is bonded in a bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(3)-C(4) bond length is 1.48 Å. The C(3)-O(1) bond length is 1.27 Å. The C(3)-O(2) bond length is 1.27 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3); one C(5,113); and one C(9,117) atom. The C(4)-C(5,113) bond length is 1.41 Å. The C(4)-C(9,117) bond length is 1.41 Å. In the fifth C site, C(5,113) is bonded in a distorted trigonal planar geometry to one C(4); one C(6); and one H(1,29,33,53,57,61) atom. The C(5,113)-C(6) bond length is 1.40 Å. The C(5,113)-H(1,29,33,53,57,61) bond length is 1.08 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5,113); one C(7); and one H(2,50) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(2,50) bond length is 1.08 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(153), one C(6), and one C(8) atom. The C(7)-C(153) bond length is 1.48 Å. The C(7)-C(8) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7); one C(9,117); and one H(3,7,35,39,43,51,55) atom. The C(8)-C(9,117) bond length is 1.40 Å. The C(8)-H(3,7,35,39,43,51,55) bond length is 1.08 Å. In the ninth C site, C(9,117) is bonded in a distorted trigonal planar geometry to one C(4); one C(8); and one H(4,40,56) atom. The C(9,117)-H(4,40,56) bond length is 1.08 Å. In the tenth C site, C(10,109) is bonded in a distorted bent 120 degrees geometry to one C(11,110); one N(2); and one H(65,67,89,91) atom. The C(10,109)-C(11,110) bond length is 1.41 Å. The C(10,109)-N(2) bond length is 1.36 Å. The C(10,109)-H(65,67,89,91) bond length is 1.08 Å. In the eleventh C site, C(11,110) is bonded in a distorted trigonal planar geometry to one C(10,109); one C(146); and one H(68,90) atom. The C(11,110)-C(146) bond length is 1.42 Å. The C(11,110)-H(68,90) bond length is 1.08 Å. In the twelfth C site, C(12) is bonded in a bent 120 degrees geometry to one C(13), one O(3), and one O(4) atom. The C(12)-C(13) bond length is 1.48 Å. The C(12)-O(3) bond length is 1.27 Å. The C(12)-O(4) bond length is 1.27 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(18) atom. The C(13)-C(14) bond length is 1.41 Å. The C(13)-C(18) bond length is 1.41 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(15), and one H(5) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(5) bond length is 1.08 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14); one C(16); and one H(6,34) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(6,34) bond length is 1.08 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(154), and one C(17) atom. The C(16)-C(154) bond length is 1.48 Å. The C(16)-C(17) bond length is 1.40 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16); one C(18); and one H(3,7,35,39,43,51,55) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(3,7,35,39,43,51,55) bond length is 1.08 Å. In the eighteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(13); one C(17); and one H(8,12,24,36,52) atom. The C(18)-H(8,12,24,36,52) bond length is 1.08 Å. In the nineteenth C site, C(19,136) is bonded in a distorted bent 120 degrees geometry to one C(20); one N(3); and one H(69,77,79) atom. The C(19,136)-C(20) bond length is 1.41 Å. The C(19,136)-N(3) bond length is 1.36 Å. The C(19,136)-H(69,77,79) bond length is 1.08 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(147); one C(19,136); and one H(70,84,96) atom. The C(20)-C(147) bond length is 1.42 Å. The C(20)-H(70,84,96) bond length is 1.08 Å. In the twenty-first C site, C(21) is bonded in a bent 120 degrees geometry to one C(22), one O(5), and one O(6) atom. The C(21)-C(22) bond length is 1.48 Å. The C(21)-O(5) bond length is 1.27 Å. The C(21)-O(6) bond length is 1.27 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(27) atom. The C(22)-C(23) bond length is 1.41 Å. The C(22)-C(27) bond length is 1.41 Å. In the twenty-third C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22); one C(24,51,114); and one H(9,13,17,21,37,45,49) atom. The C(23)-C(24,51,114) bond length is 1.40 Å. The C(23)-H(9,13,17,21,37,45,49) bond length is 1.08 Å. In the twenty-fourth C site, C(24,51,114) is bonded in a distorted trigonal planar geometry to one C(23); one C(25); and one H(10,26) atom. The C(24,51,114)-C(25) bond length is 1.41 Å. The C(24,51,114)-H(10,26) bond length is 1.08 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(155); one C(24,51,114); and one C(26,53,116) atom. The C(25)-C(155) bond length is 1.48 Å. The C(25)-C(26,53,116) bond length is 1.40 Å. In the twenty-sixth C site, C(26,53,116) is bonded in a distorted single-bond geometry to one C(25); one C(27); and one H(11,15,47) atom. The C(26,53,116)-C(27) bond length is 1.40 Å. The C(26,53,116)-H(11,15,47) bond length is 1.08 Å. In the twenty-seventh C site, C(27) is bonded in a distorted trigonal planar geometry to one C(22); one C(26,53,116); and one H(8,12,24,36,52) atom. The C(27)-H(8,12,24,36,52) bond length is 1.08 Å. In the twenty-eighth C site, C(28,127) is bonded in a distorted bent 120 degrees geometry to one C(29); one N(4); and one H(71,85,87,93) atom. The C(28,127)-C(29) bond length is 1.41 Å. The C(28,127)-N(4) bond length is 1.44 Å. The C(28,127)-H(71,85,87,93) bond length is 1.08 Å. In the twenty-ninth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(148); one C(28,127); and one H(72,94) atom. The C(29)-C(148) bond length is 1.42 Å. The C(29)-H(72,94) bond length is 1.08 Å. In the thirtieth C site, C(30,102) is bonded in a bent 120 degrees geometry to one C(31), one O(7), and one O(8) atom. The C(30,102)-C(31) bond length is 1.48 Å. The C(30,102)-O(7) bond length is 1.27 Å. The C(30,102)-O(8) bond length is 1.27 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one C(30,102); one C(32); and one C(36) atom. The C(31)-C(32) bond length is 1.41 Å. The C(31)-C(36) bond length is 1.41 Å. In the thirty-second C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31); one C(33,42,105); and one H(9,13,17,21,37,45,49) atom. The C(32)-C(33,42,105) bond length is 1.40 Å. The C(32)-H(9,13,17,21,37,45,49) bond length is 1.08 Å. In the thirty-third C site, C(33,42,105) is bonded in a distorted trigonal planar geometry to one C(32); one C(34); and one H(14,18,22,30,42,58,62) atom. The C(33,42,105)-C(34) bond length is 1.41 Å. The C(33,42,105)-H(14,18,22,30,42,58,62) bond length is 1.08 Å. In the thirty-fourth C site, C(34) is bonded in a trigonal planar geometry to one C(156); one C(33,42,105); and one C(35,44,107) atom. The C(34)-C(156) bond length is 1.48 Å. The C(34)-C(35,44,107) bond length is 1.40 Å. In the thirty-fifth C site, C(35,44,107) is bonded in a distorted single-bond geometry to one C(34); one C(36); and one H(11,15,47) atom. The C(35,44,107)-C(36) bond length is 1.40 Å. The C(35,44,107)-H(11,15,47) bond length is 1.08 Å. In the thirty-sixth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(31); one C(35,44,107); and one H(16,20,48,60) atom. The C(36)-H(16,20,48,60) bond length is 1.08 Å. In the thirty-seventh C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(38), one N(5), and one H(73) atom. The C(37)-C(38) bond length is 1.41 Å. The C(37)-N(5) bond length is 1.44 Å. The C(37)-H(73) bond length is 1.08 Å. In the thirty-eighth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(149), one C(37), and one H(74) atom. The C(38)-C(149) bond length is 1.42 Å. The C(38)-H(74) bond length is 1.08 Å. In the thirty-ninth C site, C(39,84) is bonded in a bent 120 degrees geometry to one C(40), one O(10), and one O(9) atom. The C(39,84)-C(40) bond length is 1.48 Å. The C(39,84)-O(10) bond length is 1.27 Å. The C(39,84)-O(9) bond length is 1.27 Å. In the fortieth C site, C(40) is bonded in a trigonal planar geometry to one C(39,84); one C(41,95,131); and one C(45,99,135) atom. The C(40)-C(41,95,131) bond length is 1.41 Å. The C(40)-C(45,99,135) bond length is 1.41 Å. In the forty-first C site, C(41,95,131) is bonded in a distorted trigonal planar geometry to one C(33,42,105); one C(40); and one H(9,13,17,21,37,45,49) atom. The C(41,95,131)-C(33,42,105) bond length is 1.40 Å. The C(41,95,131)-H(9,13,17,21,37,45,49) bond length is 1.08 Å. In the forty-second C site, C(43,52,124) is bonded in a trigonal planar geometry to one C(156); one C(33,42,105); and one C(35,44,107) atom. The C(43,52,124)-C(156) bond length is 1.48 Å. The C(43,52,124)-C(33,42,105) bond length is 1.40 Å. The C(43,52,124)-C(35,44,107) bond length is 1.40 Å. In the forty-third C site, C(45,99,135) is bonded in a distorted trigonal planar geometry to one C(35,44,107); one C(40); and one H(16,20,48,60) atom. The C(45,99,135)-C(35,44,107) bond length is 1.40 Å. The C(45,99,135)-H(16,20,48,60) bond length is 1.08 Å. In the forty-fourth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one C(47,74); one N(6); and one H(75,81) atom. The C(46)-C(47,74) bond length is 1.41 Å. The C(46)-N(6) bond length is 1.36 Å. The C(46)-H(75,81) bond length is 1.08 Å. In the forty-fifth C site, C(47,74) is bonded in a distorted trigonal planar geometry to one C(150), one C(46), and one H(76) atom. The C(47,74)-C(150) bond length is 1.42 Å. The C(47,74)-H(76) bond length is 1.08 Å. In the forty-sixth C site, C(48,75,120) is bonded in a bent 120 degrees geometry to one C(49,112); one O(11); and one O(12) atom. The C(48,75,120)-C(49,112) bond length is 1.48 Å. The C(48,75,120)-O(11) bond length is 1.27 Å. The C(48,75,120)-O(12) bond length is 1.27 Å. In the forty-seventh C site, C(49,112) is bonded in a trigonal planar geometry to one C(48,75,120); one C(50,68,122); and one C(54,72,126) atom. The C(49,112)-C(50,68,122) bond length is 1.41 Å. The C(49,112)-C(54,72,126) bond length is 1.41 Å. In the forty-eighth C site, C(50,68,122) is bonded in a distorted trigonal planar geometry to one C(24,51,114); one C(49,112); and one H(9,13,17,21,37,45,49) atom. The C(50,68,122)-C(24,51,114) bond length is 1.40 Å. The C(50,68,122)-H(9,13,17,21,37,45,49) bond length is 1.08 Å. In the forty-ninth C site, C(54,72,126) is bonded in a distorted trigonal planar geometry to one C(26,53,116); one C(49,112); and one H(8,12,24,36,52) atom. The C(54,72,126)-C(26,53,116) bond length is 1.40 Å. The C(54,72,126)-H(8,12,24,36,52) bond length is 1.08 Å. In the fiftieth C site, C(55,64) is bonded in a distorted bent 120 degrees geometry to one C(56,65); one N(7); and one H(69,77,79) atom. The C(55,64)-C(56,65) bond length is 1.41 Å. The C(55,64)-N(7) bond length is 1.36 Å. The C(55,64)-H(69,77,79) bond length is 1.08 Å. In the fifty-first C site, C(56,65) is bonded in a distorted trigonal planar geometry to one C(151,152); one C(55,64); and one H(78,80) atom. The C(56,65)-C(151,152) bond length is 1.42 Å. The C(56,65)-H(78,80) bond length is 1.08 Å. In the fifty-second C site, C(57) is bonded in a bent 120 degrees geometry to one C(58), one O(13), and one O(14) atom. The C(57)-C(58) bond length is 1.48 Å. The C(57)-O(13) bond length is 1.27 Å. The C(57)-O(14) bond length is 1.27 Å. In the fifty-third C site, C(58) is bonded in a trigonal planar geometry to one C(57), one C(59), and one C(63) atom. The C(58)-C(59) bond length is 1.41 Å. The C(58)-C(63) bond length is 1.41 Å. In the fifty-fourth C site, C(59) is bonded in a distorted trigonal planar geometry to one C(58), one C(60), and one H(25) atom. The C(59)-C(60) bond length is 1.40 Å. The C(59)-H(25) bond length is 1.08 Å. In the fifty-fifth C site, C(60) is bonded in a distorted trigonal planar geometry to one C(59); one C(61); and one H(10,26) atom. The C(60)-C(61) bond length is 1.40 Å. The C(60)-H(10,26) bond length is 1.08 Å. In the fifty-sixth C site, C(61) is bonded in a trigonal planar geometry to one C(154), one C(60), and one C(62) atom. The C(61)-C(154) bond length is 1.48 Å. The C(61)-C(62) bond length is 1.40 Å. In the fifty-seventh C site, C(62) is bonded in a distorted single-bond geometry to one C(61); one C(63); and one H(19,23,27,31,59) atom. The C(62)-C(63) bond length is 1.40 Å. The C(62)-H(19,23,27,31,59) bond length is 1.08 Å. In the fifty-eighth C site, C(63) is bonded in a distorted trigonal planar geometry to one C(58), one C(62), and one H(28) atom. The C(63)-H(28) bond length is 1.08 Å. In the fifty-ninth C site, C(66,138) is bonded in a bent 120 degrees geometry to one C(67), one O(15), and one O(16) atom. The C(66,138)-C(67) bond length is 1.48 Å. The C(66,138)-O(15) bond length is 1.27 Å. The C(66,138)-O(16) bond length is 1.27 Å. In the sixtieth C site, C(67) is bonded in a trigonal planar geometry to one C(50,68,122); one C(54,72,126); and one C(66,138) atom. The C(67)-C(50,68,122) bond length is 1.41 Å. The C(67)-C(54,72,126) bond length is 1.41 Å. In the sixty-first C site, C(69,141) is bonded in a distorted trigonal planar geometry to one C(50,68,122); one C(70,97,133,142); and one H(14,18,22,30,42,58,62) atom. The C(69,141)-C(50,68,122) bond length is 1.40 Å. The C(69,141)-C(70,97,133,142) bond length is 1.41 Å. The C(69,141)-H(14,18,22,30,42,58,62) bond length is 1.08 Å. In the sixty-second C site, C(70,97,133,142) is bonded in a trigonal planar geometry to one C(153); one C(69,141); and one C(71,143) atom. The C(70,97,133,142)-C(153) bond length is 1.48 Å. The C(70,97,133,142)-C(71,143) bond length is 1.40 Å. In the sixty-third C site, C(71,143) is bonded in a distorted single-bond geometry to one C(54,72,126); one C(70,97,133,142); and one H(19,23,27,31,59) atom. The C(71,143)-C(54,72,126) bond length is 1.40 Å. The C(71,143)-H(19,23,27,31,59) bond length is 1.08 Å. In the sixty-fourth C site, C(73) is bonded in a distorted bent 120 degrees geometry to one C(47,74); one N(6); and one H(75,81) atom. The C(73)-C(47,74) bond length is 1.41 Å. The C(73)-N(6) bond length is 1.36 Å. The C(73)-H(75,81) bond length is 1.08 Å. In the sixty-fifth C site, C(76) is bonded in a trigonal planar geometry to one C(48,75,120); one C(77); and one C(81) atom. The C(76)-C(48,75,120) bond length is 1.48 Å. The C(76)-C(77) bond length is 1.41 Å. The C(76)-C(81) bond length is 1.41 Å. In the sixty-sixth C site, C(77) is bonded in a distorted trigonal planar geometry to one C(76); one C(78); and one H(1,29,33,53,57,61) atom. The C(77)-C(78) bond length is 1.40 Å. The C(77)-H(1,29,33,53,57,61) bond length is 1.08 Å. In the sixty-seventh C site, C(78) is bonded in a distorted trigonal planar geometry to one C(77); one C(79); and one H(6,34) atom. The C(78)-C(79) bond length is 1.40 Å. The C(78)-H(6,34) bond length is 1.08 Å. In the sixty-eighth C site, C(79) is bonded in a trigonal planar geometry to one C(157), one C(78), and one C(80) atom. The C(79)-C(157) bond length is 1.48 Å. The C(79)-C(80) bond length is 1.40 Å. In the sixty-ninth C site, C(80) is bonded in a distorted single-bond geometry to one C(79); one C(81); and one H(3,7,35,39,43,51,55) atom. The C(80)-C(81) bond length is 1.40 Å. The C(80)-H(3,7,35,39,43,51,55) bond length is 1.08 Å. In the seventieth C site, C(81) is bonded in a distorted trigonal planar geometry to one C(76); one C(80); and one H(8,12,24,36,52) atom. The C(81)-H(8,12,24,36,52) bond length is 1.08 Å. In the seventy-first C site, C(82) is bonded in a distorted bent 120 degrees geometry to one C(83), one N(5), and one H(83) atom. The C(82)-C(83) bond length is 1.41 Å. The C(82)-N(5) bond length is 1.36 Å. The C(82)-H(83) bond length is 1.08 Å. In the seventy-second C site, C(83) is bonded in a distorted trigonal planar geometry to one C(149); one C(82); and one H(70,84,96) atom. The C(83)-C(149) bond length is 1.42 Å. The C(83)-H(70,84,96) bond length is 1.08 Å. In the seventy-third C site, C(85) is bonded in a trigonal planar geometry to one C(39,84); one C(86); and one C(90) atom. The C(85)-C(39,84) bond length is 1.48 Å. The C(85)-C(86) bond length is 1.41 Å. The C(85)-C(90) bond length is 1.41 Å. In the seventy-fourth C site, C(86) is bonded in a distorted trigonal planar geometry to one C(85); one C(87); and one H(9,13,17,21,37,45,49) atom. The C(86)-C(87) bond length is 1.40 Å. The C(86)-H(9,13,17,21,37,45,49) bond length is 1.08 Å. In the seventy-fifth C site, C(87) is bonded in a distorted trigonal planar geometry to one C(86); one C(88); and one H(38,46,54) atom. The C(87)-C(88) bond length is 1.40 Å. The C(87)-H(38,46,54) bond length is 1.08 Å. In the seventy-sixth C site, C(88) is bonded in a trigonal planar geometry to one C(158), one C(87), and one C(89) atom. The C(88)-C(158) bond length is 1.48 Å. The C(88)-C(89) bond length is 1.40 Å. In the seventy-seventh C site, C(89) is bonded in a distorted single-bond geometry to one C(88); one C(90); and one H(3,7,35,39,43,51,55) atom. The C(89)-C(90) bond length is 1.40 Å. The C(89)-H(3,7,35,39,43,51,55) bond length is 1.08 Å. In the seventy-eighth C site, C(90) is bonded in a distorted trigonal planar geometry to one C(85); one C(89); and one H(4,40,56) atom. The C(90)-H(4,40,56) bond length is 1.08 Å. In the seventy-ninth C site, C(91,100) is bonded in a distorted bent 120 degrees geometry to one C(92,101); one N(7); and one H(71,85,87,93) atom. The C(91,100)-C(92,101) bond length is 1.41 Å. The C(91,100)-N(7) bond length is 1.44 Å. The C(91,100)-H(71,85,87,93) bond length is 1.08 Å. In the eightieth C site, C(92,101) is bonded in a distorted trigonal planar geometry to one C(151,152); one C(91,100); and one H(86,88) atom. The C(92,101)-C(151,152) bond length is 1.42 Å. The C(92,101)-H(86,88) bond length is 1.08 Å. In the eighty-first C site, C(93,129) is bonded in a bent 120 degrees geometry to one C(94); one O(21,29); and one O(22,30) atom. The C(93,129)-C(94) bond length is 1.48 Å. The C(93,129)-O(21,29) bond length is 1.27 Å. The C(93,129)-O(22,30) bond length is 1.27 Å. In the eighty-second C site, C(94) is bonded in a trigonal planar geometry to one C(41,95,131); one C(45,99,135); and one C(93,129) atom. The C(94)-C(41,95,131) bond length is 1.41 Å. The C(94)-C(45,99,135) bond length is 1.41 Å. In the eighty-third C site, C(96) is bonded in a distorted trigonal planar geometry to one C(41,95,131); one C(70,97,133,142); and one H(14,18,22,30,42,58,62) atom. The C(96)-C(41,95,131) bond length is 1.40 Å. The C(96)-C(70,97,133,142) bond length is 1.40 Å. The C(96)-H(14,18,22,30,42,58,62) bond length is 1.08 Å. In the eighty-fourth C site, C(98) is bonded in a distorted single-bond geometry to one C(45,99,135); one C(70,97,133,142); and one H(3,7,35,39,43,51,55) atom. The C(98)-C(45,99,135) bond length is 1.40 Å. The C(98)-C(70,97,133,142) bond length is 1.40 Å. The C(98)-H(3,7,35,39,43,51,55) bond length is 1.08 Å. In the eighty-fifth C site, C(103) is bonded in a trigonal planar geometry to one C(104); one C(108); and one C(30,102) atom. The C(103)-C(104) bond length is 1.41 Å. The C(103)-C(108) bond length is 1.41 Å. The C(103)-C(30,102) bond length is 1.48 Å. In the eighty-sixth C site, C(104) is bonded in a distorted trigonal planar geometry to one C(103); one C(33,42,105); and one H(9,13,17,21,37,45,49) atom. The C(104)-C(33,42,105) bond length is 1.40 Å. The C(104)-H(9,13,17,21,37,45,49) bond length is 1.08 Å. In the eighty-seventh C site, C(106) is bonded in a trigonal planar geometry to one C(160); one C(33,42,105); and one C(35,44,107) atom. The C(106)-C(160) bond length is 1.48 Å. The C(106)-C(33,42,105) bond length is 1.41 Å. The C(106)-C(35,44,107) bond length is 1.40 Å. In the eighty-eighth C site, C(108) is bonded in a distorted trigonal planar geometry to one C(103); one C(35,44,107); and one H(16,20,48,60) atom. The C(108)-C(35,44,107) bond length is 1.40 Å. The C(108)-H(16,20,48,60) bond length is 1.08 Å. In the eighty-ninth C site, C(111) is bonded in a bent 120 degrees geometry to one C(49,112); one O(25); and one O(26) atom. The C(111)-C(49,112) bond length is 1.48 Å. The C(111)-O(25) bond length is 1.27 Å. The C(111)-O(26) bond length is 1.27 Å. In the ninetieth C site, C(115) is bonded in a trigonal planar geometry to one C(160); one C(24,51,114); and one C(26,53,116) atom. The C(115)-C(160) bond length is 1.48 Å. The C(115)-C(24,51,114) bond length is 1.40 Å. The C(115)-C(26,53,116) bond length is 1.40 Å. In the ninety-first C site, C(121) is bonded in a trigonal planar geometry to one C(48,75,120); one C(50,68,122); and one C(54,72,126) atom. The C(121)-C(48,75,120) bond length is 1.48 Å. The C(121)-C(50,68,122) bond length is 1.41 Å. The C(121)-C(54,72,126) bond length is 1.41 Å. In the ninety-second C site, C(123) is bonded in a distorted trigonal planar geometry to one C(43,52,124); one C(50,68,122); and one H(38,46,54) atom. The C(123)-C(43,52,124) bond length is 1.40 Å. The C(123)-C(50,68,122) bond length is 1.40 Å. The C(123)-H(38,46,54) bond length is 1.08 Å. In the ninety-third C site, C(125) is bonded in a distorted single-bond geometry to one C(43,52,124); one C(54,72,126); and one H(3,7,35,39,43,51,55) atom. The C(125)-C(43,52,124) bond length is 1.40 Å. The C(125)-C(54,72,126) bond length is 1.40 Å. The C(125)-H(3,7,35,39,43,51,55) bond length is 1.08 Å. In the ninety-fourth C site, C(128) is bonded in a distorted trigonal planar geometry to one C(147); one C(28,127); and one H(72,94) atom. The C(128)-C(147) bond length is 1.42 Å. The C(128)-C(28,127) bond length is 1.41 Å. The C(128)-H(72,94) bond length is 1.08 Å. In the ninety-fifth C site, C(130) is bonded in a trigonal planar geometry to one C(41,95,131); one C(45,99,135); and one C(93,129) atom. The C(130)-C(41,95,131) bond length is 1.41 Å. The C(130)-C(45,99,135) bond length is 1.41 Å. The C(130)-C(93,129) bond length is 1.48 Å. In the ninety-sixth C site, C(132) is bonded in a distorted trigonal planar geometry to one C(41,95,131); one C(70,97,133,142); and one H(14,18,22,30,42,58,62) atom. The C(132)-C(41,95,131) bond length is 1.40 Å. The C(132)-C(70,97,133,142) bond length is 1.40 Å. The C(132)-H(14,18,22,30,42,58,62) bond length is 1.08 Å. In the ninety-seventh C site, C(134) is bonded in a distorted single-bond geometry to one C(45,99,135); one C(70,97,133,142); and one H(19,23,27,31,59) atom. The C(134)-C(45,99,135) bond length is 1.40 Å. The C(134)-C(70,97,133,142) bond length is 1.40 Å. The C(134)-H(19,23,27,31,59) bond length is 1.08 Å. In the ninety-eighth C site, C(137) is bonded in a distorted trigonal planar geometry to one C(148); one C(19,136); and one H(70,84,96) atom. The C(137)-C(148) bond length is 1.42 Å. The C(137)-C(19,136) bond length is 1.41 Å. The C(137)-H(70,84,96) bond length is 1.08 Å. In the ninety-ninth C site, C(139) is bonded in a trigonal planar geometry to one C(140); one C(144); and one C(66,138) atom. The C(139)-C(140) bond length is 1.41 Å. The C(139)-C(144) bond length is 1.41 Å. The C(139)-C(66,138) bond length is 1.48 Å. In the one hundredth C site, C(140) is bonded in a distorted trigonal planar geometry to one C(139); one C(69,141); and one H(1,29,33,53,57,61) atom. The C(140)-C(69,141) bond length is 1.40 Å. The C(140)-H(1,29,33,53,57,61) bond length is 1.08 Å. In the one hundred and first C site, C(144) is bonded in a distorted trigonal planar geometry to one C(139); one C(71,143); and one H(32,44,64) atom. The C(144)-C(71,143) bond length is 1.40 Å. The C(144)-H(32,44,64) bond length is 1.08 Å. In the one hundred and second C site, C(145) is bonded in a trigonal planar geometry to one C(146) and two equivalent C(2,119) atoms. The C(145)-C(146) bond length is 1.54 Å. In the one hundred and third C site, C(146) is bonded in a trigonal planar geometry to one C(145) and two equivalent C(11,110) atoms. In the one hundred and fourth C site, C(147) is bonded in a trigonal planar geometry to one C(128), one C(148), and one C(20) atom. The C(147)-C(148) bond length is 1.54 Å. In the one hundred and fifth C site, C(148) is bonded in a trigonal planar geometry to one C(137), one C(147), and one C(29) atom. In the one hundred and sixth C site, C(149) is bonded in a trigonal planar geometry to one C(150), one C(38), and one C(83) atom. The C(149)-C(150) bond length is 1.54 Å. In the one hundred and seventh C site, C(150) is bonded in a trigonal planar geometry to one C(149) and two equivalent C(47,74) atoms. In the one hundred and eighth C site, C(151,152) is bonded in a trigonal planar geometry to one C(151,152); one C(56,65); and one C(92,101) atom. The C(151,152)-C(151,152) bond length is 1.54 Å. In the one hundred and ninth C site, C(153) is bonded in a distorted trigonal planar geometry to one C(7); one C(70,97,133,142); and one O(33,37,38,39) atom. The C(153)-O(33,37,38,39) bond length is 1.22 Å. In the one hundred and tenth C site, C(154) is bonded in a distorted trigonal planar geometry to one C(16), one C(61), and one O(34) atom. The C(154)-O(34) bond length is 1.22 Å. In the one hundred and eleventh C site, C(155) is bonded in a distorted trigonal planar geometry to one C(25); one C(43,52,124); and one O(35,36,40) atom. The C(155)-C(43,52,124) bond length is 1.48 Å. The C(155)-O(35,36,40) bond length is 1.22 Å. In the one hundred and twelfth C site, C(156) is bonded in a distorted trigonal planar geometry to one C(34); one C(43,52,124); and one O(35,36,40) atom. The C(156)-O(35,36,40) bond length is 1.22 Å. In the one hundred and thirteenth C site, C(157) is bonded in a distorted trigonal planar geometry to one C(70,97,133,142); one C(79); and one O(33,37,38,39) atom. The C(157)-C(70,97,133,142) bond length is 1.48 Å. The C(157)-O(33,37,38,39) bond length is 1.22 Å. In the one hundred and fourteenth C site, C(158) is bonded in a distorted trigonal planar geometry to one C(70,97,133,142); one C(88); and one O(33,37,38,39) atom. The C(158)-C(70,97,133,142) bond length is 1.48 Å. The C(158)-O(33,37,38,39) bond length is 1.22 Å. In the one hundred and fifteenth C site, C(159) is bonded in a distorted trigonal planar geometry to one C(43,52,124); one C(70,97,133,142); and one O(33,37,38,39) atom. The C(159)-C(43,52,124) bond length is 1.48 Å. The C(159)-C(70,97,133,142) bond length is 1.48 Å. The C(159)-O(33,37,38,39) bond length is 1.22 Å. In the one hundred and sixteenth C site, C(160) is bonded in a distorted trigonal planar geometry to one C(106); one C(115); and one O(35,36,40) atom. The C(160)-O(35,36,40) bond length is 1.22 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1) and two equivalent C(1,118) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2) and two equivalent C(10,109) atoms. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(3); one C(19,136); and one C(28,127) atom. The N(3)-C(28,127) bond length is 1.44 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(4); one C(19,136); and one C(28,127) atom. The N(4)-C(19,136) bond length is 1.36 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(5), one C(37), and one C(82) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(6), one C(46), and one C(73) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Cu(7); one C(55,64); and one C(91,100) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Cu(8); one C(55,64); and one C(91,100) atom. The N(8)-C(55,64) bond length is 1.36 Å. The N(8)-C(91,100) bond length is 1.44 Å. There are thirty-five inequivalent H sites. In the first H site, H(1,29,33,53,57,61) is bonded in a single-bond geometry to one C(5,113) atom. In the second H site, H(2,50) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3,7,35,39,43,51,55) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4,40,56) is bonded in a single-bond geometry to one C(9,117) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(6,34) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(8,12,24,36,52) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(9,13,17,21,37,45,49) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(10,26) is bonded in a single-bond geometry to one C(24,51,114) atom. In the tenth H site, H(11,15,47) is bonded in a single-bond geometry to one C(26,53,116) atom. In the eleventh H site, H(14,18,22,30,42,58,62) is bonded in a single-bond geometry to one C(33,42,105) atom. In the twelfth H site, H(16,20,48,60) is bonded in a single-bond geometry to one C(36) atom. In the thirteenth H site, H(19,23,27,31,59) is bonded in a single-bond geometry to one C(35,44,107) atom. The H(19,23,27,31,59)-C(35,44,107) bond length is 1.08 Å. In the fourteenth H site, H(25) is bonded in a single-bond geometry to one C(59) atom. In the fifteenth H site, H(28) is bonded in a single-bond geometry to one C(63) atom. In the sixteenth H site, H(32,44,64) is bonded in a single-bond geometry to one C(54,72,126) atom. The H(32,44,64)-C(54,72,126) bond length is 1.08 Å. In the seventeenth H site, H(38,46,54) is bonded in a single-bond geometry to one C(87) atom. In the eighteenth H site, H(41) is bonded in a single-bond geometry to one C(41,95,131) atom. The H(41)-C(41,95,131) bond length is 1.08 Å. In the nineteenth H site, H(63) is bonded in a single-bond geometry to one C(71,143) atom. The H(63)-C(71,143) bond length is 1.08 Å. In the twentieth H site, H(65,67,89,91) is bonded in a single-bond geometry to one C(1,118) atom. In the twenty-first H site, H(66,92) is bonded in a single-bond geometry to one C(2,119) atom. In the twenty-second H site, H(68,90) is bonded in a single-bond geometry to one C(11,110) atom. In the twenty-third H site, H(69,77,79) is bonded in a single-bond geometry to one C(19,136) atom. In the twenty-fourth H site, H(70,84,96) is bonded in a single-bond geometry to one C(20) atom. In the twenty-fifth H site, H(71,85,87,93) is bonded in a single-bond geometry to one C(28,127) atom. In the twenty-sixth H site, H(72,94) is bonded in a single-bond geometry to one C(29) atom. In the twenty-seventh H site, H(73) is bonded in a single-bond geometry to one C(37) atom. In the twenty-eighth H site, H(74) is bonded in a single-bond geometry to one C(38) atom. In the twenty-ninth H site, H(75,81) is bonded in a single-bond geometry to one C(46) atom. In the thirtieth H site, H(76) is bonded in a single-bond geometry to one C(47,74) atom. In the thirty-first H site, H(78,80) is bonded in a single-bond geometry to one C(56,65) atom. In the thirty-second H site, H(82) is bonded in a single-bond geometry to one C(47,74) atom. The H(82)-C(47,74) bond length is 1.08 Å. In the thirty-third H site, H(83) is bonded in a single-bond geometry to one C(82) atom. In the thirty-fourth H site, H(86,88) is bonded in a single-bond geometry to one C(92,101) atom. In the thirty-fifth H site, H(95) is bonded in a single-bond geometry to one C(19,136) atom. The H(95)-C(19,136) bond length is 1.08 Å. There are thirty-three inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(6) and one C(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(12) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(5) and one C(12) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(21) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(7) and one C(21) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(30,102) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(8) and one C(30,102) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(5) and one C(39,84) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(39,84) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Cu(6) and one C(48,75,120) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(48,75,120) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Cu(7) and one C(57) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(57) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Cu(8) and one C(66,138) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(66,138) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Cu(6) and one C(48,75,120) atom. The O(17)-C(48,75,120) bond length is 1.27 Å. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(48,75,120) atom. The O(18)-C(48,75,120) bond length is 1.27 Å. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Cu(5) and one C(39,84) atom. The O(19)-C(39,84) bond length is 1.27 Å. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(39,84) atom. The O(20)-C(39,84) bond length is 1.27 Å. In the twenty-first O site, O(21,29) is bonded in a bent 120 degrees geometry to one Cu(7) and one C(93,129) atom. In the twenty-second O site, O(22,30) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(93,129) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Cu(8) and one C(30,102) atom. The O(23)-C(30,102) bond length is 1.27 Å. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(30,102) atom. The O(24)-C(30,102) bond length is 1.27 Å. In the twenty-fifth O site, O(25) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(111) atom. In the twenty-sixth O site, O(26) is bonded in a bent 120 degrees geometry to one Cu(5) and one C(111) atom. In the twenty-seventh O site, O(27) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(48,75,120) atom. The O(27)-C(48,75,120) bond length is 1.27 Å. In the twenty-eighth O site, O(28) is bonded in a bent 120 degrees geometry to one Cu(6) and one C(48,75,120) atom. The O(28)-C(48,75,120) bond length is 1.27 Å. In the twenty-ninth O site, O(31) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(66,138) atom. The O(31)-C(66,138) bond length is 1.27 Å. In the thirtieth O site, O(32) is bonded in a bent 120 degrees geometry to one Cu(8) and one C(66,138) atom. The O(32)-C(66,138) bond length is 1.27 Å. In the thirty-first O site, O(33,37,38,39) is bonded in a single-bond geometry to one C(153) atom. In the thirty-second O site, O(34) is bonded in a single-bond geometry to one C(154) atom. In the thirty-third O site, O(35,36,40) is bonded in a single-bond geometry to one C(155) atom. Linkers: 8 [O]C(=O)c1ccc(C(=O)c2ccc(C([O])=O)cc2)cc1 ,4 c1cc(-c2ccncc2)ccn1. Metal clusters: 4 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 18.78 A, density 0.32 g/cm3, surface area 4714.33 m2/g, accessible volume 2.82 cm3/g