Dy2Co2C32N5H12O22(CH)3 crystallizes in the orthorhombic Pna2_1 space group. The structure consists of twelve 02329_fluka molecules inside a Dy2Co2C32N5H12O22 framework. In the Dy2Co2C32N5H12O22 framework, there are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a distorted pentagonal pyramidal geometry to one O(1), one O(14), one O(15), one O(19), one O(3), and one O(9) atom. The Dy(1)-O(1) bond length is 2.45 Å. The Dy(1)-O(14) bond length is 2.40 Å. The Dy(1)-O(15) bond length is 2.36 Å. The Dy(1)-O(19) bond length is 2.34 Å. The Dy(1)-O(3) bond length is 2.31 Å. The Dy(1)-O(9) bond length is 2.38 Å. In the second Dy site, Dy(2) is bonded in a 8-coordinate geometry to one O(11), one O(12), one O(18), one O(20), one O(21), one O(22), one O(5), and one O(7) atom. The Dy(2)-O(11) bond length is 2.48 Å. The Dy(2)-O(12) bond length is 2.48 Å. The Dy(2)-O(18) bond length is 2.39 Å. The Dy(2)-O(20) bond length is 2.32 Å. The Dy(2)-O(21) bond length is 2.46 Å. The Dy(2)-O(22) bond length is 2.52 Å. The Dy(2)-O(5) bond length is 2.43 Å. The Dy(2)-O(7) bond length is 2.34 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted see-saw-like geometry to one N(1), one N(2), one O(2), and one O(6) atom. The Co(1)-N(1) bond length is 2.14 Å. The Co(1)-N(2) bond length is 2.14 Å. The Co(1)-O(2) bond length is 2.06 Å. The Co(1)-O(6) bond length is 2.07 Å. In the second Co site, Co(2) is bonded in an octahedral geometry to one N(3), one N(4), one N(5), one O(10), one O(13), and one O(17) atom. The Co(2)-N(3) bond length is 2.13 Å. The Co(2)-N(4) bond length is 2.15 Å. The Co(2)-N(5) bond length is 2.09 Å. The Co(2)-O(10) bond length is 2.05 Å. The Co(2)-O(13) bond length is 2.04 Å. The Co(2)-O(17) bond length is 2.10 Å. There are thirty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-C(6) bond length is 1.50 Å. The C(1)-N(1) bond length is 1.29 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(7) bond length is 1.51 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(5)-N(1) bond length is 1.32 Å. The C(5)-H(3) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.26 Å. The C(6)-O(2) bond length is 1.27 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(7)-O(3) bond length is 1.27 Å. The C(7)-O(4) bond length is 1.20 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one N(2) atom. The C(8)-C(13) bond length is 1.57 Å. The C(8)-C(9) bond length is 1.36 Å. The C(8)-N(2) bond length is 1.37 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-C(14) bond length is 1.49 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(10)-H(4) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(12)-N(2) bond length is 1.35 Å. The C(12)-H(6) bond length is 0.93 Å. In the eleventh C site, C(13) is bonded in a bent 120 degrees geometry to one C(8), one O(5), and one O(6) atom. The C(13)-O(5) bond length is 1.24 Å. The C(13)-O(6) bond length is 1.26 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(7), and one O(8) atom. The C(14)-O(7) bond length is 1.23 Å. The C(14)-O(8) bond length is 1.21 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one N(3) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-N(3) bond length is 1.32 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.43 Å. The C(16)-C(21) bond length is 1.53 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(7) atom. The C(17)-H(7) bond length is 0.93 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(8) atom. The C(18)-C(19) bond length is 1.35 Å. The C(18)-H(8) bond length is 0.93 Å. In the seventeenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(3), and one H(9) atom. The C(19)-N(3) bond length is 1.32 Å. The C(19)-H(9) bond length is 0.93 Å. In the eighteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(20)-O(10) bond length is 1.26 Å. The C(20)-O(9) bond length is 1.24 Å. In the nineteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(11), and one O(12) atom. The C(21)-O(11) bond length is 1.24 Å. The C(21)-O(12) bond length is 1.26 Å. In the twentieth C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one N(4) atom. The C(22)-C(23) bond length is 1.44 Å. The C(22)-N(4) bond length is 1.30 Å. In the twenty-first C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.34 Å. The C(23)-C(28) bond length is 1.48 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(10) atom. The C(24)-H(10) bond length is 0.93 Å. In the twenty-third C site, C(25) is bonded in a distorted single-bond geometry to one C(26) and one H(11) atom. The C(25)-C(26) bond length is 1.32 Å. The C(25)-H(11) bond length is 0.93 Å. In the twenty-fourth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one N(4), and one H(12) atom. The C(26)-N(4) bond length is 1.34 Å. The C(26)-H(12) bond length is 0.93 Å. In the twenty-fifth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(14) atom. The C(27)-O(13) bond length is 1.33 Å. The C(27)-O(14) bond length is 1.21 Å. In the twenty-sixth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(15), and one O(16) atom. The C(28)-O(15) bond length is 1.27 Å. The C(28)-O(16) bond length is 1.24 Å. In the twenty-seventh C site, C(29) is bonded in a distorted trigonal planar geometry to one C(30), one C(34), and one N(5) atom. The C(29)-C(30) bond length is 1.42 Å. The C(29)-C(34) bond length is 1.48 Å. The C(29)-N(5) bond length is 1.37 Å. In the twenty-eighth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(35) atom. The C(30)-C(31) bond length is 1.37 Å. The C(30)-C(35) bond length is 1.50 Å. In the twenty-ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(13) atom. The C(31)-H(13) bond length is 0.93 Å. In the thirtieth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(15) atom. The C(33)-N(5) bond length is 1.32 Å. The C(33)-H(15) bond length is 0.93 Å. In the thirty-first C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(17), and one O(18) atom. The C(34)-O(17) bond length is 1.29 Å. The C(34)-O(18) bond length is 1.24 Å. In the thirty-second C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(19), and one O(20) atom. The C(35)-O(19) bond length is 1.23 Å. The C(35)-O(20) bond length is 1.20 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(12), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(2), one C(15), and one C(19) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(2), one C(22), and one C(26) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(2), one C(29), and one C(33) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(31) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(33) atom. There are twenty-two inequivalent O sites. In the first O site, O(21) is bonded in an L-shaped geometry to one Dy(2) and one O(22) atom. The O(21)-O(22) bond length is 0.94 Å. In the second O site, O(22) is bonded in a distorted L-shaped geometry to one Dy(2) and one O(21) atom. In the third O site, O(15) is bonded in a distorted single-bond geometry to one Dy(1) and one C(28) atom. In the fourth O site, O(12) is bonded in a distorted L-shaped geometry to one Dy(2) and one C(21) atom. In the fifth O site, O(13) is bonded in a bent 120 degrees geometry to one Co(2) and one C(27) atom. In the sixth O site, O(1) is bonded in a distorted single-bond geometry to one Dy(1) and one C(6) atom. In the seventh O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one C(6) atom. In the eighth O site, O(3) is bonded in a distorted single-bond geometry to one Dy(1) and one C(7) atom. In the ninth O site, O(4) is bonded in a single-bond geometry to one C(7) atom. In the tenth O site, O(5) is bonded in a distorted single-bond geometry to one Dy(2) and one C(13) atom. In the eleventh O site, O(6) is bonded in a distorted single-bond geometry to one Co(1) and one C(13) atom. In the twelfth O site, O(7) is bonded in a distorted single-bond geometry to one Dy(2) and one C(14) atom. In the thirteenth O site, O(8) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one C(20) atom. In the fifteenth O site, O(10) is bonded in a bent 120 degrees geometry to one Co(2) and one C(20) atom. In the sixteenth O site, O(11) is bonded in a distorted single-bond geometry to one Dy(2) and one C(21) atom. In the seventeenth O site, O(14) is bonded in a distorted single-bond geometry to one Dy(1) and one C(27) atom. In the eighteenth O site, O(16) is bonded in a single-bond geometry to one C(28) atom. In the nineteenth O site, O(17) is bonded in a bent 120 degrees geometry to one Co(2) and one C(34) atom. In the twentieth O site, O(18) is bonded in a distorted single-bond geometry to one Dy(2) and one C(34) atom. In the twenty-first O site, O(19) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one C(35) atom. In the twenty-second O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Dy(2) and one C(35) atom. Linkers: 19 [O]C(=O)c1cccnc1C([O])=O. Metal clusters: 8 [Dy] ,8 [Co]. The MOF has largest included sphere 4.81 A, density 1.69 g/cm3, surface area 3274.80 m2/g, accessible volume 0.27 cm3/g