AgH12(C2S)3(CH2)3 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and four AgH12(C2S)3 clusters. In each AgH12(C2S)3 cluster, Ag(1) is bonded in a distorted trigonal non-coplanar geometry to one S(1), one S(2), and one S(3) atom. The Ag(1)-S(1) bond length is 2.46 Å. The Ag(1)-S(2) bond length is 2.48 Å. The Ag(1)-S(3) bond length is 2.62 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one H(1), one H(2), and one S(1) atom. The C(1)-H(1) bond length is 1.03 Å. The C(1)-H(2) bond length is 1.06 Å. The C(1)-S(1) bond length is 1.83 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one H(5), one H(6), and one S(2) atom. The C(3)-H(5) bond length is 1.13 Å. The C(3)-H(6) bond length is 1.07 Å. The C(3)-S(2) bond length is 1.83 Å. In the third C site, C(4) is bonded in a bent 120 degrees geometry to one H(7), one H(8), and one S(2) atom. The C(4)-H(7) bond length is 1.03 Å. The C(4)-H(8) bond length is 0.96 Å. The C(4)-S(2) bond length is 1.82 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one H(11), one H(12), and one S(3) atom. The C(6)-H(11) bond length is 1.05 Å. The C(6)-H(12) bond length is 0.81 Å. The C(6)-S(3) bond length is 1.82 Å. In the fifth C site, C(7) is bonded in a distorted L-shaped geometry to one H(13), one H(14), and one S(3) atom. The C(7)-H(13) bond length is 1.18 Å. The C(7)-H(14) bond length is 1.06 Å. The C(7)-S(3) bond length is 1.81 Å. In the sixth C site, C(9) is bonded in a water-like geometry to one H(17), one H(18), and one S(1) atom. The C(9)-H(17) bond length is 1.02 Å. The C(9)-H(18) bond length is 0.95 Å. The C(9)-S(1) bond length is 1.82 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(7) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(9) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(1), and one C(9) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(3), and one C(4) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(6), and one C(7) atom. Linkers: 4 C1CSCCCSCCCSC1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 5.48 A, density 1.11 g/cm3, surface area 4253.75 m2/g, accessible volume 0.43 cm3/g