Zn2C24P2N2H16O9(CH)2(CH3)8 is Indium-derived structured and crystallizes in the tetragonal I-42d space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, one hundred and twenty-eight 02329_fluka molecules, and eight Zn2C24P2N2H16O9 clusters. In each Zn2C24P2N2H16O9 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(6), one O(8), and one O(9) atom to form ZnO4 trigonal pyramids that share  a cornercorner with one P(1)O4 tetrahedra and corners with two equivalent P(2)O4 tetrahedra. The Zn(1)-O(2) bond length is 1.94 Å. The Zn(1)-O(6) bond length is 1.93 Å. The Zn(1)-O(8) bond length is 1.96 Å. The Zn(1)-O(9) bond length is 2.08 Å. In the second Zn site, Zn(2) is bonded to one N(2), one O(3), one O(4), and one O(7) atom to form ZnNO3 trigonal pyramids that share  a cornercorner with one P(2)O4 tetrahedra and corners with two equivalent P(1)O4 tetrahedra. The Zn(2)-N(2) bond length is 2.13 Å. The Zn(2)-O(3) bond length is 1.93 Å. The Zn(2)-O(4) bond length is 1.95 Å. The Zn(2)-O(7) bond length is 1.95 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one O(5) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-C(6) bond length is 1.38 Å. The C(1)-O(5) bond length is 1.38 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-C(2) bond length is 1.38 Å. The C(3)-H(1) bond length is 0.95 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(3) atom. The C(2)-C(10) bond length is 1.51 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(3) bond length is 0.95 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.61 Å. In the sixth C site, C(7) is bonded in a single-bond geometry to one C(6) and one H(4) atom. The C(7)-H(4) bond length is 1.00 Å. In the seventh C site, C(10) is bonded in a single-bond geometry to one C(2) and one H(11) atom. The C(10)-H(11) bond length is 1.00 Å. In the eighth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one O(1) atom. The C(13)-C(14) bond length is 1.36 Å. The C(13)-C(18) bond length is 1.36 Å. The C(13)-O(1) bond length is 1.38 Å. In the ninth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(32) atom. The C(14)-C(15) bond length is 1.36 Å. The C(14)-C(32) bond length is 1.52 Å. In the tenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(18) atom. The C(15)-H(18) bond length is 0.95 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(20) atom. The C(17)-C(18) bond length is 1.36 Å. The C(17)-H(20) bond length is 0.95 Å. In the twelfth C site, C(18) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(19) atom. The C(18)-C(19) bond length is 1.51 Å. In the thirteenth C site, C(19) is bonded in a single-bond geometry to one C(18) and one H(21) atom. The C(19)-H(21) bond length is 1.00 Å. In the fourteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(23), one N(1), and one H(28) atom. The C(22)-C(23) bond length is 1.37 Å. The C(22)-N(1) bond length is 1.32 Å. The C(22)-H(28) bond length is 0.95 Å. In the fifteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22), one C(24), and one H(29) atom. The C(23)-C(24) bond length is 1.43 Å. The C(23)-H(29) bond length is 0.95 Å. In the sixteenth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(26) atom. The C(24)-C(25) bond length is 1.52 Å. The C(24)-C(26) bond length is 1.34 Å. In the seventeenth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(29), and one C(30) atom. The C(25)-C(29) bond length is 1.36 Å. The C(25)-C(30) bond length is 1.36 Å. In the eighteenth C site, C(26) is bonded in a single-bond geometry to one C(24), one C(27), and one H(30) atom. The C(26)-C(27) bond length is 1.38 Å. The C(26)-H(30) bond length is 0.95 Å. In the nineteenth C site, C(27) is bonded in a 3-coordinate geometry to one C(26), one N(1), and one H(31) atom. The C(27)-N(1) bond length is 1.33 Å. The C(27)-H(31) bond length is 0.95 Å. In the twentieth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(32) atom. The C(28)-N(2) bond length is 1.32 Å. The C(28)-H(32) bond length is 0.95 Å. In the twenty-first C site, C(29) is bonded in a distorted single-bond geometry to one C(25) and one H(33) atom. The C(29)-H(33) bond length is 0.95 Å. In the twenty-second C site, C(30) is bonded in a distorted single-bond geometry to one C(25) and one H(34) atom. The C(30)-H(34) bond length is 0.95 Å. In the twenty-third C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(35) atom. The C(31)-N(2) bond length is 1.34 Å. The C(31)-H(35) bond length is 0.95 Å. In the twenty-fourth C site, C(32) is bonded in a single-bond geometry to one C(14) and one H(36) atom. The C(32)-H(36) bond length is 1.00 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)O4 trigonal pyramid and corners with two equivalent Zn(2)NO3 trigonal pyramids. The P(1)-O(1) bond length is 1.68 Å. The P(1)-O(2) bond length is 1.51 Å. The P(1)-O(3) bond length is 1.49 Å. The P(1)-O(4) bond length is 1.48 Å. In the second P site, P(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(2)NO3 trigonal pyramid and corners with two equivalent Zn(1)O4 trigonal pyramids. The P(2)-O(5) bond length is 1.66 Å. The P(2)-O(6) bond length is 1.50 Å. The P(2)-O(7) bond length is 1.49 Å. The P(2)-O(8) bond length is 1.50 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(22), one C(27), and one O(9) atom. The N(1)-O(9) bond length is 1.34 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(28), and one C(31) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(21) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(28) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(29) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(30) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(31) is bonded in a single-bond geometry to one C(27) atom. In the twelfth H site, H(32) is bonded in a single-bond geometry to one C(28) atom. In the thirteenth H site, H(34) is bonded in a single-bond geometry to one C(30) atom. In the fourteenth H site, H(36) is bonded in a single-bond geometry to one C(32) atom. In the fifteenth H site, H(35) is bonded in a single-bond geometry to one C(31) atom. In the sixteenth H site, H(33) is bonded in a single-bond geometry to one C(29) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(13) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one C(1) and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one P(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(1) and one N(1) atom. Linkers: 16 [O-][n+]1ccc(-c2ccncc2)cc1. Metal clusters: 32 [Zn]. The MOF has largest included sphere 12.66 A, density 0.66 g/cm3, surface area 4971.22 m2/g, accessible volume 1.04 cm3/g