ZnC10H6(NO2)2(CH)2 crystallizes in the tetragonal I-42d space group. The structure consists of sixteen 02329_fluka molecules inside a ZnC10H6(NO2)2 framework. In the ZnC10H6(NO2)2 framework, Zn(1) is bonded in a 6-coordinate geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. Both Zn(1)-N(1) bond lengths are 2.06 Å. Both Zn(1)-O(1) bond lengths are 2.06 Å. Both Zn(1)-O(2) bond lengths are 2.34 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(3) is bonded in a single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(3) bond length is 0.95 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-C(6) bond length is 1.48 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 0.95 Å. In the fifth C site, C(6) is bonded in a bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.26 Å. The C(6)-O(2) bond length is 1.26 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Zn(1) and one C(6) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Zn(1) and one C(6) atom. Linkers: 8 [O]C(=O)c1cccnc1. Metal clusters: 4 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.72 A, density 1.30 g/cm3, surface area 4423.75 m2/g, accessible volume 0.28 cm3/g