(CH)8ZnC12N2H4(OF)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight isobutylene molecules and four ZnC12N2H4(OF)4 clusters. In each ZnC12N2H4(OF)4 cluster, Zn(1) is bonded in a distorted trigonal pyramidal geometry to one N(1), one N(2), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-N(2) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 1.95 Å. The Zn(1)-O(3) bond length is 1.95 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.23 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(4) bond length is 1.39 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(2) and one F(1) atom. The C(3)-F(1) bond length is 1.34 Å. In the fourth C site, C(4) is bonded in a single-bond geometry to one C(2) and one F(2) atom. The C(4)-F(2) bond length is 1.35 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(7) and one F(3) atom. The C(5)-C(7) bond length is 1.38 Å. The C(5)-F(3) bond length is 1.35 Å. In the sixth C site, C(6) is bonded in a single-bond geometry to one C(7) and one F(4) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-F(4) bond length is 1.34 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(8) atom. The C(7)-C(8) bond length is 1.52 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.23 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,2) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-H(1,2) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,2) atom. The C(10)-N(1) bond length is 1.34 Å. The C(10)-H(1,2) bond length is 0.93 Å. In the eleventh C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(11) atom. The C(19)-N(2) bond length is 1.34 Å. The C(19)-H(11) bond length is 0.93 Å. In the twelfth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(20)-N(2) bond length is 1.34 Å. The C(20)-H(12) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(19), and one C(20) atom. There are three inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(8) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(3) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(4) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(6) atom. Linkers: 4 c1cc(CCc2ccncc2)ccn1 ,4 [O]C(=O)c1c(F)c(F)c(C([O])=O)c(F)c1F. Metal clusters: 4 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 5.22 A, density 1.32 g/cm3, surface area 4489.39 m2/g, accessible volume 0.26 cm3/g