Sr3Ag6C35H21S6(N3O7)2CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a Sr3Ag6C35H21S6(N3O7)2 framework. In the Sr3Ag6C35H21S6(N3O7)2 framework, there are three inequivalent Sr sites. In the first Sr site, Sr(1) is bonded in a 5-coordinate geometry to one O(1), one O(11), one O(4), and two equivalent O(2) atoms. The Sr(1)-O(1) bond length is 2.59 Å. The Sr(1)-O(11) bond length is 2.55 Å. The Sr(1)-O(4) bond length is 2.47 Å. There is one shorter (2.52 Å) and one longer (2.85 Å) Sr(1)-O(2) bond length. In the second Sr site, Sr(2) is bonded in a 4-coordinate geometry to one S(5), one O(10), one O(13), and one O(14) atom. The Sr(2)-S(5) bond length is 3.19 Å. The Sr(2)-O(10) bond length is 2.49 Å. The Sr(2)-O(13) bond length is 2.71 Å. The Sr(2)-O(14) bond length is 2.60 Å. In the third Sr site, Sr(3) is bonded in a 8-coordinate geometry to one O(10), one O(13), one O(14), one O(5), one O(7), one O(9), and two equivalent O(8) atoms. The Sr(3)-O(10) bond length is 2.71 Å. The Sr(3)-O(13) bond length is 2.70 Å. The Sr(3)-O(14) bond length is 2.63 Å. The Sr(3)-O(5) bond length is 2.64 Å. The Sr(3)-O(7) bond length is 2.74 Å. The Sr(3)-O(9) bond length is 2.72 Å. There is one shorter (2.52 Å) and one longer (2.75 Å) Sr(3)-O(8) bond length. There are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one N(1), one S(2), and one S(6) atom. The Ag(1)-N(1) bond length is 2.30 Å. The Ag(1)-S(2) bond length is 2.50 Å. The Ag(1)-S(6) bond length is 2.47 Å. In the second Ag site, Ag(2) is bonded in a distorted trigonal planar geometry to one N(2), one S(1), and one S(3) atom. The Ag(2)-N(2) bond length is 2.31 Å. The Ag(2)-S(1) bond length is 2.48 Å. The Ag(2)-S(3) bond length is 2.49 Å. In the third Ag site, Ag(3) is bonded in a 3-coordinate geometry to one N(3), one S(2), and one S(4) atom. The Ag(3)-N(3) bond length is 2.30 Å. The Ag(3)-S(2) bond length is 2.46 Å. The Ag(3)-S(4) bond length is 2.51 Å. In the fourth Ag site, Ag(4) is bonded in a distorted trigonal planar geometry to one N(4), one S(3), and one S(5) atom. The Ag(4)-N(4) bond length is 2.32 Å. The Ag(4)-S(3) bond length is 2.49 Å. The Ag(4)-S(5) bond length is 2.47 Å. In the fifth Ag site, Ag(5) is bonded in a distorted trigonal planar geometry to one N(5), one S(4), and one S(6) atom. The Ag(5)-N(5) bond length is 2.30 Å. The Ag(5)-S(4) bond length is 2.51 Å. The Ag(5)-S(6) bond length is 2.48 Å. In the sixth Ag site, Ag(6) is bonded in a distorted trigonal planar geometry to one N(6), one S(1), and one S(5) atom. The Ag(6)-N(6) bond length is 2.27 Å. The Ag(6)-S(1) bond length is 2.49 Å. The Ag(6)-S(5) bond length is 2.51 Å. There are thirty-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one S(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-S(1) bond length is 1.77 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(6) bond length is 1.50 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(3) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(3) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.26 Å. The C(6)-O(2) bond length is 1.25 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one S(2) atom. The C(7)-C(8) bond length is 1.41 Å. The C(7)-N(2) bond length is 1.35 Å. The C(7)-S(2) bond length is 1.76 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.51 Å. The C(8)-C(9) bond length is 1.38 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(4) atom. The C(9)-H(4) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(5) atom. The C(10)-C(11) bond length is 1.37 Å. The C(10)-H(5) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(2), and one H(6) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(6) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(3), and one O(4) atom. The C(12)-O(3) bond length is 1.25 Å. The C(12)-O(4) bond length is 1.25 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one S(3) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-N(3) bond length is 1.35 Å. The C(13)-S(3) bond length is 1.76 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(18) atom. The C(14)-C(15) bond length is 1.38 Å. The C(14)-C(18) bond length is 1.51 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(7) atom. The C(15)-H(7) bond length is 0.93 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(8) atom. The C(16)-C(17) bond length is 1.37 Å. The C(16)-H(8) bond length is 0.93 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one N(3), and one H(9) atom. The C(17)-N(3) bond length is 1.34 Å. The C(17)-H(9) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(5), and one O(6) atom. The C(18)-O(5) bond length is 1.25 Å. The C(18)-O(6) bond length is 1.25 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(20), one N(4), and one S(4) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-N(4) bond length is 1.34 Å. The C(19)-S(4) bond length is 1.76 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(24) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-C(24) bond length is 1.51 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(10) atom. The C(21)-H(10) bond length is 0.93 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(11) atom. The C(22)-C(23) bond length is 1.37 Å. The C(22)-H(11) bond length is 0.93 Å. In the twenty-third C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one N(4), and one H(12) atom. The C(23)-N(4) bond length is 1.34 Å. The C(23)-H(12) bond length is 0.93 Å. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(7), and one O(8) atom. The C(24)-O(7) bond length is 1.25 Å. The C(24)-O(8) bond length is 1.25 Å. In the twenty-fifth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one N(5), and one S(5) atom. The C(25)-C(26) bond length is 1.41 Å. The C(25)-N(5) bond length is 1.35 Å. The C(25)-S(5) bond length is 1.77 Å. In the twenty-sixth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(30) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-C(30) bond length is 1.51 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(13) atom. The C(27)-H(13) bond length is 0.93 Å. In the twenty-eighth C site, C(28) is bonded in a distorted single-bond geometry to one C(29) and one H(14) atom. The C(28)-C(29) bond length is 1.38 Å. The C(28)-H(14) bond length is 0.93 Å. In the twenty-ninth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one N(5), and one H(15) atom. The C(29)-N(5) bond length is 1.34 Å. The C(29)-H(15) bond length is 0.93 Å. In the thirtieth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(10), and one O(9) atom. The C(30)-O(10) bond length is 1.26 Å. The C(30)-O(9) bond length is 1.25 Å. In the thirty-first C site, C(31) is bonded in a distorted trigonal planar geometry to one C(32), one N(6), and one S(6) atom. The C(31)-C(32) bond length is 1.40 Å. The C(31)-N(6) bond length is 1.35 Å. The C(31)-S(6) bond length is 1.76 Å. In the thirty-second C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(36) atom. The C(32)-C(33) bond length is 1.38 Å. The C(32)-C(36) bond length is 1.50 Å. In the thirty-third C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(16) atom. The C(33)-H(16) bond length is 0.93 Å. In the thirty-fourth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(18) atom. The C(35)-N(6) bond length is 1.34 Å. The C(35)-H(18) bond length is 0.93 Å. In the thirty-fifth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(32), one O(11), and one O(12) atom. The C(36)-O(11) bond length is 1.25 Å. The C(36)-O(12) bond length is 1.26 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(2), one C(11), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(3), one C(13), and one C(17) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(4), one C(19), and one C(23) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Ag(5), one C(25), and one C(29) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Ag(6), one C(31), and one C(35) atom. There are twenty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(27) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(28) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(29) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(33) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(35) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one O(13) atom. The H(19)-O(13) bond length is 0.75 Å. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one O(13) atom. The H(20)-O(13) bond length is 0.91 Å. In the twentieth H site, H(21) is bonded in a single-bond geometry to one O(14) atom. The H(21)-O(14) bond length is 0.71 Å. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one O(14) atom. The H(22)-O(14) bond length is 0.81 Å. There are six inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(2), one Ag(6), and one C(1) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(3), and one C(7) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to one Ag(2), one Ag(4), and one C(13) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to one Ag(3), one Ag(5), and one C(19) atom. In the fifth S site, S(5) is bonded in a distorted tetrahedral geometry to one Sr(2), one Ag(4), one Ag(6), and one C(25) atom. In the sixth S site, S(6) is bonded in a trigonal non-coplanar geometry to one Ag(1), one Ag(5), and one C(31) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Sr(1) and one C(6) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Sr(1) and one C(6) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(12) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Sr(1) and one C(12) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Sr(3) and one C(18) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(18) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Sr(3) and one C(24) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to two equivalent Sr(3) and one C(24) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Sr(3) and one C(30) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Sr(2), one Sr(3), and one C(30) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Sr(1) and one C(36) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one C(36) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one Sr(2), one Sr(3), one H(19), and one H(20) atom. In the fourteenth O site, O(14) is bonded in a water-like geometry to one Sr(2), one Sr(3), one H(21), and one H(22) atom. Linkers: 12 [O]C(=O)[C]1C=CC=NC1=S. Metal clusters: 6 [Sr] ,12 [Ag]. The MOF has largest included sphere 5.50 A, density 1.83 g/cm3, surface area 2779.38 m2/g, accessible volume 0.23 cm3/g