(CuC4NH2O4)4(CH3)8C45H40O4 is Indium-derived structured and crystallizes in the tetragonal P4_2/n space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, two C45H40O4 clusters, and four CuC4NH2O4 clusters. In each C45H40O4 cluster, there are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(6) atom. The C(1)-C(3) bond length is 1.32 Å. The C(1)-C(4) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.51 Å. In the second C site, C(3) is bonded in a single-bond geometry to one C(1) and one H(2) atom. The C(3)-H(2) bond length is 0.94 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(4)-H(3) bond length is 0.94 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(12), and one C(8) atom. The C(6)-C(12) bond length is 1.25 Å. The C(6)-C(8) bond length is 1.40 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(10), one C(11), and one O(5) atom. The C(7)-C(10) bond length is 1.36 Å. The C(7)-C(11) bond length is 1.41 Å. The C(7)-O(5) bond length is 1.45 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(6), and one C(9) atom. The C(8)-C(10) bond length is 1.38 Å. The C(8)-C(9) bond length is 1.46 Å. In the seventh C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(8), one H(5), one H(6), and one H(7) atom. The C(9)-H(5) bond length is 0.97 Å. The C(9)-H(6) bond length is 0.97 Å. The C(9)-H(7) bond length is 0.97 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(7), one C(8), and one H(8) atom. The C(10)-H(8) bond length is 0.94 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(7) and one H(9) atom. The C(11)-H(9) bond length is 0.94 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(6) and one H(10) atom. The C(12)-H(10) bond length is 0.94 Å. In the eleventh C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one C(18); two equivalent H(11,12); and one O(5) atom. The C(13)-C(18) bond length is 1.50 Å. Both C(13)-H(11,12) bond lengths are 0.98 Å. The C(13)-O(5) bond length is 1.37 Å. In the twelfth C site, C(18) is bonded in a tetrahedral geometry to four equivalent C(13) atoms. There are nine inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11,12) is bonded in a single-bond geometry to one C(13) atom. O(5) is bonded in a water-like geometry to one C(13) and one C(7) atom. In each CuC4NH2O4 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-N(1) bond length is 2.19 Å. The Cu(1)-O(1) bond length is 1.99 Å. The Cu(1)-O(2) bond length is 1.98 Å. The Cu(1)-O(3) bond length is 1.97 Å. The Cu(1)-O(4) bond length is 1.98 Å. There are four inequivalent C sites. In the first C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(15)-O(2) bond length is 1.26 Å. The C(15)-O(4) bond length is 1.26 Å. In the second C site, C(16) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(16)-O(1) bond length is 1.25 Å. The C(16)-O(3) bond length is 1.26 Å. In the third C site, C(2) is bonded in a 2-coordinate geometry to one N(1) and one H(1) atom. The C(2)-N(1) bond length is 1.32 Å. The C(2)-H(1) bond length is 0.94 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.31 Å. The C(5)-H(4) bond length is 0.94 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(2), and one C(5) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(16) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(15) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(16) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(15) atom. Linkers: 2 [CH]=[C]c1ccc(OCC(COc2ccc([C]=[CH])c(C)c2)(COc2ccc(-c3ccncc3)c(C)c2)COc2ccc(-c3ccncc3)c(C)c2)cc1C ,2 Cc1cc(OCC(C[O])(C[O])COc2ccc(-c3ccncc3)c(C)c2)ccc1-c1ccncc1 ,2 Cc1cc(OCC(COc2ccc(-c3ccncc3)c(C)c2)(COc2ccc(-c3ccncc3)c(C)c2)COc2ccc(-c3ccncc3)c(C)c2)ccc1-c1ccncc1. Metal clusters: 8 [Cu]. The MOF has largest included sphere 12.29 A, density 0.74 g/cm3, surface area 5083.11 m2/g, accessible volume 0.90 cm3/g