Cd2C23H8(N2O7)3CH3 crystallizes in the triclinic P1 space group. The structure consists of two 02329_fluka molecules inside a Cd2C23H8(N2O7)3 framework. In the Cd2C23H8(N2O7)3 framework, there are four inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted pentagonal planar geometry to one O(1), one O(27), one O(3), one O(38), and one O(40) atom. The Cd(1)-O(1) bond length is 2.37 Å. The Cd(1)-O(27) bond length is 2.20 Å. The Cd(1)-O(3) bond length is 2.35 Å. The Cd(1)-O(38) bond length is 2.36 Å. The Cd(1)-O(40) bond length is 2.54 Å. In the second Cd site, Cd(2) is bonded to one O(1), one O(28), one O(29), one O(4), and one O(41) atom to form distorted corner-sharing CdO5 trigonal bipyramids. The Cd(2)-O(1) bond length is 2.28 Å. The Cd(2)-O(28) bond length is 2.37 Å. The Cd(2)-O(29) bond length is 2.39 Å. The Cd(2)-O(4) bond length is 2.22 Å. The Cd(2)-O(41) bond length is 2.22 Å. In the third Cd site, Cd(3) is bonded to one O(15), one O(16), one O(2), one O(29), one O(39), and one O(5) atom to form distorted CdO6 pentagonal pyramids that share  a cornercorner with one Cd(4)O7 pentagonal bipyramid and  a cornercorner with one Cd(2)O5 trigonal bipyramid. The Cd(3)-O(15) bond length is 2.26 Å. The Cd(3)-O(16) bond length is 2.28 Å. The Cd(3)-O(2) bond length is 2.31 Å. The Cd(3)-O(29) bond length is 2.28 Å. The Cd(3)-O(39) bond length is 2.31 Å. The Cd(3)-O(5) bond length is 2.24 Å. In the fourth Cd site, Cd(4) is bonded to one O(14), one O(17), one O(26), one O(38), one O(39), one O(40), and one O(42) atom to form distorted corner-sharing CdO7 pentagonal bipyramids. The Cd(4)-O(14) bond length is 2.32 Å. The Cd(4)-O(17) bond length is 2.23 Å. The Cd(4)-O(26) bond length is 2.25 Å. The Cd(4)-O(38) bond length is 2.61 Å. The Cd(4)-O(39) bond length is 2.38 Å. The Cd(4)-O(40) bond length is 2.33 Å. The Cd(4)-O(42) bond length is 2.32 Å. There are forty-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.31 Å. The C(1)-O(2) bond length is 1.22 Å. In the second C site, C(2) is bonded in a distorted water-like geometry to one C(1), one H(1), and one O(3) atom. The C(2)-H(1) bond length is 0.98 Å. The C(2)-O(3) bond length is 1.46 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(4), and one O(5) atom. The C(4)-C(5) bond length is 1.49 Å. The C(4)-O(4) bond length is 1.26 Å. The C(4)-O(5) bond length is 1.23 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(6) atom. The C(5)-C(10) bond length is 1.38 Å. The C(5)-C(6) bond length is 1.32 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(5) atom. The C(6)-C(7) bond length is 1.44 Å. The C(6)-H(5) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(2) atom. The C(7)-C(8) bond length is 1.33 Å. The C(7)-N(2) bond length is 1.51 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(7), and one C(9) atom. The C(8)-C(11) bond length is 1.48 Å. The C(8)-C(9) bond length is 1.44 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(3) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-N(3) bond length is 1.44 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(5), one C(9), and one H(6) atom. The C(10)-H(6) bond length is 0.93 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(8) atom. The C(11)-C(12) bond length is 1.44 Å. The C(11)-C(16) bond length is 1.38 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one N(4) atom. The C(12)-C(13) bond length is 1.37 Å. The C(12)-N(4) bond length is 1.48 Å. In the twelfth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one H(7) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-H(7) bond length is 0.93 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-C(17) bond length is 1.51 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(8) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(8) bond length is 0.93 Å. In the fifteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(11), one C(15), and one N(5) atom. The C(16)-N(5) bond length is 1.49 Å. In the sixteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(14), and one O(15) atom. The C(17)-O(14) bond length is 1.30 Å. The C(17)-O(15) bond length is 1.24 Å. In the seventeenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(16), and one O(17) atom. The C(18)-C(19) bond length is 1.55 Å. The C(18)-O(16) bond length is 1.21 Å. The C(18)-O(17) bond length is 1.29 Å. In the eighteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.42 Å. The C(19)-C(24) bond length is 1.32 Å. In the nineteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(9) atom. The C(20)-C(21) bond length is 1.33 Å. The C(20)-H(9) bond length is 0.93 Å. In the twentieth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one N(6) atom. The C(21)-C(22) bond length is 1.41 Å. The C(21)-N(6) bond length is 1.49 Å. In the twenty-first C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(25) atom. The C(22)-C(23) bond length is 1.37 Å. The C(22)-C(25) bond length is 1.51 Å. In the twenty-second C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one N(9) atom. The C(23)-C(24) bond length is 1.44 Å. The C(23)-N(9) bond length is 1.49 Å. In the twenty-third C site, C(24) is bonded in a distorted single-bond geometry to one C(19), one C(23), and one H(10) atom. The C(24)-H(10) bond length is 0.93 Å. In the twenty-fourth C site, C(25) is bonded in a trigonal planar geometry to one C(22), one C(26), and one C(30) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(30) bond length is 1.38 Å. In the twenty-fifth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one C(27), and one N(7) atom. The C(26)-C(27) bond length is 1.43 Å. The C(26)-N(7) bond length is 1.46 Å. In the twenty-sixth C site, C(27) is bonded in a distorted single-bond geometry to one C(26), one C(28), and one H(11) atom. The C(27)-C(28) bond length is 1.38 Å. The C(27)-H(11) bond length is 0.93 Å. In the twenty-seventh C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(31) atom. The C(28)-C(29) bond length is 1.34 Å. The C(28)-C(31) bond length is 1.55 Å. In the twenty-eighth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one C(30), and one H(12) atom. The C(29)-C(30) bond length is 1.37 Å. The C(29)-H(12) bond length is 0.93 Å. In the twenty-ninth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(25), one C(29), and one N(8) atom. The C(30)-N(8) bond length is 1.45 Å. In the thirtieth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(26), and one O(27) atom. The C(31)-O(26) bond length is 1.24 Å. The C(31)-O(27) bond length is 1.28 Å. In the thirty-first C site, C(32) is bonded in a bent 120 degrees geometry to one C(33), one O(28), and one O(29) atom. The C(32)-C(33) bond length is 1.53 Å. The C(32)-O(28) bond length is 1.24 Å. The C(32)-O(29) bond length is 1.28 Å. In the thirty-second C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(38) atom. The C(33)-C(34) bond length is 1.34 Å. The C(33)-C(38) bond length is 1.40 Å. In the thirty-third C site, C(34) is bonded in a distorted single-bond geometry to one C(33), one C(35), and one H(13) atom. The C(34)-C(35) bond length is 1.40 Å. The C(34)-H(13) bond length is 0.93 Å. In the thirty-fourth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(34), one C(36), and one N(12) atom. The C(35)-C(36) bond length is 1.39 Å. The C(35)-N(12) bond length is 1.46 Å. In the thirty-fifth C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(39) atom. The C(36)-C(37) bond length is 1.38 Å. The C(36)-C(39) bond length is 1.47 Å. In the thirty-sixth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(36), one C(38), and one N(1) atom. The C(37)-C(38) bond length is 1.32 Å. The C(37)-N(1) bond length is 1.45 Å. In the thirty-seventh C site, C(38) is bonded in a distorted single-bond geometry to one C(33), one C(37), and one H(14) atom. The C(38)-H(14) bond length is 0.93 Å. In the thirty-eighth C site, C(39) is bonded in a trigonal planar geometry to one C(36), one C(40), and one C(44) atom. The C(39)-C(40) bond length is 1.40 Å. The C(39)-C(44) bond length is 1.48 Å. In the thirty-ninth C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one N(11) atom. The C(40)-N(11) bond length is 1.42 Å. In the fortieth C site, C(41) is bonded in a distorted single-bond geometry to one C(42) and one H(15) atom. The C(41)-C(42) bond length is 1.40 Å. The C(41)-H(15) bond length is 0.93 Å. In the forty-first C site, C(42) is bonded in a trigonal planar geometry to one C(41), one C(43), and one C(45) atom. The C(42)-C(43) bond length is 1.39 Å. The C(42)-C(45) bond length is 1.54 Å. In the forty-second C site, C(43) is bonded in a distorted single-bond geometry to one C(42), one C(44), and one H(16) atom. The C(43)-C(44) bond length is 1.33 Å. The C(43)-H(16) bond length is 0.93 Å. In the forty-third C site, C(44) is bonded in a distorted trigonal planar geometry to one C(39), one C(43), and one N(10) atom. The C(44)-N(10) bond length is 1.47 Å. In the forty-fourth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(42), one O(38), and one O(39) atom. The C(45)-O(38) bond length is 1.25 Å. The C(45)-O(39) bond length is 1.23 Å. In the forty-fifth C site, C(46) is bonded in a distorted trigonal planar geometry to one O(40) and one O(41) atom. The C(46)-O(40) bond length is 1.26 Å. The C(46)-O(41) bond length is 1.27 Å. In the forty-sixth C site, C(47) is bonded in a distorted water-like geometry to one H(17) and one O(42) atom. The C(47)-H(17) bond length is 0.98 Å. The C(47)-O(42) bond length is 1.38 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(37), one O(30), and one O(31) atom. The N(1)-O(30) bond length is 1.28 Å. The N(1)-O(31) bond length is 1.22 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(7), one O(6), and one O(7) atom. The N(2)-O(6) bond length is 1.22 Å. The N(2)-O(7) bond length is 1.18 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(9), one O(8), and one O(9) atom. The N(3)-O(8) bond length is 1.26 Å. The N(3)-O(9) bond length is 1.20 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(12), one O(10), and one O(11) atom. The N(4)-O(10) bond length is 1.15 Å. The N(4)-O(11) bond length is 1.21 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(16), one O(12), and one O(13) atom. The N(5)-O(12) bond length is 1.23 Å. The N(5)-O(13) bond length is 1.21 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(21), one O(18), and one O(19) atom. The N(6)-O(18) bond length is 1.15 Å. The N(6)-O(19) bond length is 1.23 Å. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(26), one O(22), and one O(23) atom. The N(7)-O(22) bond length is 1.26 Å. The N(7)-O(23) bond length is 1.15 Å. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(30), one O(24), and one O(25) atom. The N(8)-O(24) bond length is 1.21 Å. The N(8)-O(25) bond length is 1.19 Å. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(23), one O(20), and one O(21) atom. The N(9)-O(20) bond length is 1.22 Å. The N(9)-O(21) bond length is 1.18 Å. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one C(44), one O(34), and one O(35) atom. The N(10)-O(34) bond length is 1.20 Å. The N(10)-O(35) bond length is 1.20 Å. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one C(40), one O(36), and one O(37) atom. The N(11)-O(36) bond length is 1.23 Å. The N(11)-O(37) bond length is 1.13 Å. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one C(35), one O(32), and one O(33) atom. The N(12)-O(32) bond length is 1.28 Å. The N(12)-O(33) bond length is 1.19 Å. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(29) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(34) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(38) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(41) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(43) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(47) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one O(3) atom. The H(21)-O(3) bond length is 0.93 Å. In the sixteenth H site, H(22) is bonded in a single-bond geometry to one O(42) atom. The H(22)-O(42) bond length is 0.93 Å. There are forty-two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one Cd(2), and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Cd(3) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cd(1), one C(2), and one H(21) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Cd(2) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cd(3) and one C(4) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one N(2) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one N(3) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one N(3) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one N(4) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one N(4) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one N(5) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one N(5) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Cd(4) and one C(17) atom. In the fifteenth O site, O(15) is bonded in a water-like geometry to one Cd(3) and one C(17) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one Cd(3) and one C(18) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Cd(4) and one C(18) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one N(6) atom. In the nineteenth O site, O(19) is bonded in a single-bond geometry to one N(6) atom. In the twentieth O site, O(20) is bonded in a single-bond geometry to one N(9) atom. In the twenty-first O site, O(21) is bonded in a single-bond geometry to one N(9) atom. In the twenty-second O site, O(22) is bonded in a single-bond geometry to one N(7) atom. In the twenty-third O site, O(23) is bonded in a single-bond geometry to one N(7) atom. In the twenty-fourth O site, O(24) is bonded in a single-bond geometry to one N(8) atom. In the twenty-fifth O site, O(25) is bonded in a single-bond geometry to one N(8) atom. In the twenty-sixth O site, O(26) is bonded in a bent 120 degrees geometry to one Cd(4) and one C(31) atom. In the twenty-seventh O site, O(27) is bonded in a bent 150 degrees geometry to one Cd(1) and one C(31) atom. In the twenty-eighth O site, O(28) is bonded in a distorted single-bond geometry to one Cd(2) and one C(32) atom. In the twenty-ninth O site, O(29) is bonded in a 3-coordinate geometry to one Cd(2), one Cd(3), and one C(32) atom. In the thirtieth O site, O(30) is bonded in a single-bond geometry to one N(1) atom. In the thirty-first O site, O(31) is bonded in a single-bond geometry to one N(1) atom. In the thirty-second O site, O(32) is bonded in a single-bond geometry to one N(12) atom. In the thirty-third O site, O(33) is bonded in a single-bond geometry to one N(12) atom. In the thirty-fourth O site, O(34) is bonded in a single-bond geometry to one N(10) atom. In the thirty-fifth O site, O(35) is bonded in a single-bond geometry to one N(10) atom. In the thirty-sixth O site, O(36) is bonded in a single-bond geometry to one N(11) atom. In the thirty-seventh O site, O(37) is bonded in a single-bond geometry to one N(11) atom. In the thirty-eighth O site, O(38) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(4), and one C(45) atom. In the thirty-ninth O site, O(39) is bonded in a 3-coordinate geometry to one Cd(3), one Cd(4), and one C(45) atom. In the fortieth O site, O(40) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(4), and one C(46) atom. In the forty-first O site, O(41) is bonded in a bent 120 degrees geometry to one Cd(2) and one C(46) atom. In the forty-second O site, O(42) is bonded in a distorted trigonal planar geometry to one Cd(4), one C(47), and one H(22) atom. Linkers: 3 [O]C(=O)c1cc([N+](=O)[O-])c(-c2c([N+](=O)[O-])cc(C([O])=O)cc2[N+](=O)[O-])c([N+](=O)[O-])c1 ,2 C[C@H](O)C([O])=O. Metal clusters: 4 [Cd]. The MOF has largest included sphere 5.72 A, density 1.35 g/cm3, surface area 3541.49 m2/g, accessible volume 0.31 cm3/g