Cu11C59H53(N3O4)6(CH)5 crystallizes in the trigonal P3_221 space group. The structure consists of fifteen 02329_fluka molecules inside a Cu11C59H53(N3O4)6 framework. In the Cu11C59H53(N3O4)6 framework, there are six inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted single-bond geometry to one Cu(5), one N(5), one N(7), and one O(12) atom. The Cu(1)-Cu(5) bond length is 0.52 Å. The Cu(1)-N(5) bond length is 1.97 Å. The Cu(1)-N(7) bond length is 1.97 Å. The Cu(1)-O(12) bond length is 1.97 Å. In the second Cu site, Cu(2) is bonded in a rectangular see-saw-like geometry to one N(1), one N(8), one O(1), and one O(2) atom. The Cu(2)-N(1) bond length is 1.96 Å. The Cu(2)-N(8) bond length is 1.97 Å. The Cu(2)-O(1) bond length is 2.02 Å. The Cu(2)-O(2) bond length is 1.94 Å. In the third Cu site, Cu(3) is bonded in a rectangular see-saw-like geometry to one N(2), one N(4), one O(1), and one O(6) atom. The Cu(3)-N(2) bond length is 2.00 Å. The Cu(3)-N(4) bond length is 2.00 Å. The Cu(3)-O(1) bond length is 2.02 Å. The Cu(3)-O(6) bond length is 1.95 Å. In the fourth Cu site, Cu(4) is bonded in a distorted rectangular see-saw-like geometry to one N(3), one N(9), one O(10), and one O(8) atom. The Cu(4)-N(3) bond length is 1.96 Å. The Cu(4)-N(9) bond length is 1.97 Å. The Cu(4)-O(10) bond length is 1.97 Å. The Cu(4)-O(8) bond length is 1.98 Å. In the fifth Cu site, Cu(5) is bonded in a distorted single-bond geometry to one Cu(1), one N(5), and one N(7) atom. The Cu(5)-N(5) bond length is 1.89 Å. The Cu(5)-N(7) bond length is 1.93 Å. In the sixth Cu site, Cu(6) is bonded in a distorted octahedral geometry to two equivalent N(6), two equivalent O(4), and two equivalent O(5) atoms. Both Cu(6)-N(6) bond lengths are 2.01 Å. Both Cu(6)-O(4) bond lengths are 2.22 Å. Both Cu(6)-O(5) bond lengths are 2.26 Å. There are thirty inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one C(2), one H(2), one H(3), and one H(4) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-H(2) bond length is 0.96 Å. The C(1)-H(3) bond length is 0.96 Å. The C(1)-H(4) bond length is 0.96 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one N(1), and one N(3) atom. The C(2)-N(1) bond length is 1.32 Å. The C(2)-N(3) bond length is 1.37 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(4), one N(2), and one N(3) atom. The C(3)-C(4) bond length is 1.54 Å. The C(3)-N(2) bond length is 1.34 Å. The C(3)-N(3) bond length is 1.32 Å. In the fourth C site, C(4) is bonded in a trigonal non-coplanar geometry to one C(3), one H(5), one H(6), and one H(7) atom. The C(4)-H(5) bond length is 0.96 Å. The C(4)-H(6) bond length is 0.96 Å. The C(4)-H(7) bond length is 0.96 Å. In the fifth C site, C(5) is bonded in a trigonal non-coplanar geometry to one C(6), one H(10), one H(8), and one H(9) atom. The C(5)-C(6) bond length is 1.49 Å. The C(5)-H(10) bond length is 0.96 Å. The C(5)-H(8) bond length is 0.96 Å. The C(5)-H(9) bond length is 0.96 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(4), and one N(6) atom. The C(6)-N(4) bond length is 1.30 Å. The C(6)-N(6) bond length is 1.39 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(8), one N(5), and one N(6) atom. The C(7)-C(8) bond length is 1.47 Å. The C(7)-N(5) bond length is 1.35 Å. The C(7)-N(6) bond length is 1.30 Å. In the eighth C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(7) and three equivalent H(11,12,13) atoms. All C(8)-H(11,12,13) bond lengths are 0.96 Å. In the ninth C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(10), one H(14), one H(15), and one H(16) atom. The C(9)-C(10) bond length is 1.51 Å. The C(9)-H(14) bond length is 0.96 Å. The C(9)-H(15) bond length is 0.96 Å. The C(9)-H(16) bond length is 0.96 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(7), and one N(9) atom. The C(10)-N(7) bond length is 1.31 Å. The C(10)-N(9) bond length is 1.37 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(8), and one N(9) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-N(8) bond length is 1.32 Å. The C(11)-N(9) bond length is 1.32 Å. In the twelfth C site, C(12) is bonded in a trigonal non-coplanar geometry to one C(11); one H(18); and two equivalent H(17,19) atoms. The C(12)-H(18) bond length is 0.96 Å. Both C(12)-H(17,19) bond lengths are 0.96 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(2), and one O(3) atom. The C(13)-C(14) bond length is 1.50 Å. The C(13)-O(2) bond length is 1.26 Å. The C(13)-O(3) bond length is 1.20 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.38 Å. The C(14)-C(19) bond length is 1.41 Å. In the fifteenth C site, C(15) is bonded in a single-bond geometry to one C(14) and one H(20) atom. The C(15)-H(20) bond length is 0.93 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(22) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-H(22) bond length is 0.93 Å. In the seventeenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(20) atom. The C(18)-C(19) bond length is 1.33 Å. The C(18)-C(20) bond length is 1.59 Å. In the eighteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one H(23) atom. The C(19)-H(23) bond length is 0.93 Å. In the nineteenth C site, C(20) is bonded in a bent 120 degrees geometry to one C(18), one O(4), and one O(5) atom. The C(20)-O(4) bond length is 1.32 Å. The C(20)-O(5) bond length is 1.12 Å. In the twentieth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(6), and one O(7) atom. The C(21)-C(22) bond length is 1.53 Å. The C(21)-O(6) bond length is 1.28 Å. The C(21)-O(7) bond length is 1.24 Å. In the twenty-first C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(27) atom. The C(22)-C(23) bond length is 1.35 Å. The C(22)-C(27) bond length is 1.38 Å. In the twenty-second C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(24) atom. The C(23)-H(24) bond length is 0.93 Å. In the twenty-third C site, C(25) is bonded in a distorted single-bond geometry to one C(26) and one H(26) atom. The C(25)-C(26) bond length is 1.38 Å. The C(25)-H(26) bond length is 0.93 Å. In the twenty-fourth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(28) atom. The C(26)-C(27) bond length is 1.37 Å. The C(26)-C(28) bond length is 1.51 Å. In the twenty-fifth C site, C(27) is bonded in a distorted single-bond geometry to one C(22), one C(26), and one H(27) atom. The C(27)-H(27) bond length is 0.93 Å. In the twenty-sixth C site, C(28) is bonded in a bent 120 degrees geometry to one C(26), one O(8), and one O(9) atom. The C(28)-O(8) bond length is 1.29 Å. The C(28)-O(9) bond length is 1.23 Å. In the twenty-seventh C site, C(29) is bonded in a bent 120 degrees geometry to one C(30), one O(10), and one O(11) atom. The C(29)-C(30) bond length is 1.52 Å. The C(29)-O(10) bond length is 1.30 Å. The C(29)-O(11) bond length is 1.23 Å. In the twenty-eighth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(33) atom. The C(30)-C(31) bond length is 1.35 Å. The C(30)-C(33) bond length is 1.39 Å. In the twenty-ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(28) atom. The C(31)-H(28) bond length is 0.93 Å. In the thirtieth C site, C(33) is bonded in a distorted single-bond geometry to two equivalent C(30) and one H(30) atom. The C(33)-H(30) bond length is 0.93 Å. There are nine inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(2), and one N(2) atom. The N(1)-N(2) bond length is 1.35 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(3), one C(3), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(4), one C(2), and one C(3) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cu(3), one C(6), and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a 4-coordinate geometry to one Cu(1), one Cu(5), one C(7), and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(6), one C(6), and one C(7) atom. In the seventh N site, N(7) is bonded in a 4-coordinate geometry to one Cu(1), one Cu(5), one C(10), and one N(8) atom. The N(7)-N(8) bond length is 1.36 Å. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(11), and one N(7) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Cu(4), one C(10), and one C(11) atom. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.87 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(11,12,13) is bonded in a single-bond geometry to one C(8) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(9) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(9) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(9) atom. In the fifteenth H site, H(17,19) is bonded in a single-bond geometry to one C(12) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(12) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(15) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(17) atom. In the nineteenth H site, H(23) is bonded in a single-bond geometry to one C(19) atom. In the twentieth H site, H(24) is bonded in a single-bond geometry to one C(23) atom. In the twenty-first H site, H(26) is bonded in a single-bond geometry to one C(25) atom. In the twenty-second H site, H(27) is bonded in a single-bond geometry to one C(27) atom. In the twenty-third H site, H(28) is bonded in a single-bond geometry to one C(31) atom. In the twenty-fourth H site, H(30) is bonded in a single-bond geometry to one C(33) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cu(2), one Cu(3), and one H(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(13) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(13) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Cu(6) and one C(20) atom. In the fifth O site, O(5) is bonded in a distorted L-shaped geometry to one Cu(6) and one C(20) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(21) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(21) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Cu(4) and one C(28) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(28) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Cu(4) and one C(29) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one C(29) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Cu(1) atom. Linkers: 3 Cc1nnc(C)n1[Cu](OC(=O)c1cccc(C([O])=O)c1)(OC(=O)c1cccc(C(=O)O[Cu](OC(=O)c2cccc(C([O])=O)c2)(n2c(C)nnc2C)n2c(C)nnc2C)c1)n1c(C)nnc1C ,4 Cc1nnc(C)n1[Cu]12(n3c(C)nnc3C)(O[C](c3cccc(C([O])=O)c3)O1)O[C](c1cccc(C([O])=O)c1)O2. Metal clusters: 6 [O][Cu][Cu]1(O)/N=N\[Cu](O[C]=O)/N=N\[Cu](O[C]=O)/N=N\1. The MOF has largest included sphere 11.51 A, density 0.79 g/cm3, surface area 3945.03 m2/g, accessible volume 0.78 cm3/g