CuH20(C7N6)2CuC13N12H18(CH2)13 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of fifty-two 02329_fluka molecules, four CuC13N12H18 clusters, and four CuH20(C7N6)2 clusters. In each CuC13N12H18 cluster, Cu(2) is bonded in a rectangular see-saw-like geometry to one N(1), one N(22), one N(6), and one N(7) atom. The Cu(2)-N(1) bond length is 2.01 Å. The Cu(2)-N(22) bond length is 2.01 Å. The Cu(2)-N(6) bond length is 1.99 Å. The Cu(2)-N(7) bond length is 1.99 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a 3-coordinate geometry to one N(3), one H(1), and one H(2) atom. The C(1)-N(3) bond length is 1.45 Å. The C(1)-H(1) bond length is 0.97 Å. The C(1)-H(2) bond length is 0.97 Å. In the second C site, C(6) is bonded in a 3-coordinate geometry to one N(5) and two equivalent H(11,12) atoms. The C(6)-N(5) bond length is 1.46 Å. Both C(6)-H(11,12) bond lengths are 0.97 Å. In the third C site, C(7) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(13) atom. The C(7)-N(4) bond length is 1.30 Å. The C(7)-N(6) bond length is 1.36 Å. The C(7)-H(13) bond length is 0.93 Å. In the fourth C site, C(8) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(14) atom. The C(8)-N(5) bond length is 1.31 Å. The C(8)-N(6) bond length is 1.33 Å. The C(8)-H(14) bond length is 0.93 Å. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(15) atom. The C(9)-N(7) bond length is 1.33 Å. The C(9)-N(9) bond length is 1.28 Å. The C(9)-H(15) bond length is 0.93 Å. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(16) atom. The C(10)-N(7) bond length is 1.33 Å. The C(10)-N(8) bond length is 1.29 Å. The C(10)-H(16) bond length is 0.93 Å. In the seventh C site, C(11) is bonded in a 4-coordinate geometry to one C(12); one N(8); and two equivalent H(17,18) atoms. The C(11)-C(12) bond length is 1.44 Å. The C(11)-N(8) bond length is 1.47 Å. Both C(11)-H(17,18) bond lengths are 0.97 Å. In the eighth C site, C(12) is bonded in a water-like geometry to one C(11), one H(19), and one H(20) atom. The C(12)-H(19) bond length is 0.97 Å. The C(12)-H(20) bond length is 0.97 Å. In the ninth C site, C(34) is bonded in a trigonal planar geometry to one N(22), one N(24), and one H(55) atom. The C(34)-N(22) bond length is 1.32 Å. The C(34)-N(24) bond length is 1.29 Å. The C(34)-H(55) bond length is 0.93 Å. In the tenth C site, C(35) is bonded in a trigonal planar geometry to one N(22), one N(23), and one H(56) atom. The C(35)-N(22) bond length is 1.34 Å. The C(35)-N(23) bond length is 1.31 Å. The C(35)-H(56) bond length is 0.93 Å. In the eleventh C site, C(36) is bonded in a 3-coordinate geometry to one N(24) and two equivalent H(57,58) atoms. The C(36)-N(24) bond length is 1.47 Å. Both C(36)-H(57,58) bond lengths are 0.97 Å. In the twelfth C site, C(39) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(63) atom. The C(39)-N(1) bond length is 1.37 Å. The C(39)-N(2) bond length is 1.33 Å. The C(39)-H(63) bond length is 0.93 Å. In the thirteenth C site, C(40) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(64) atom. The C(40)-N(1) bond length is 1.31 Å. The C(40)-N(3) bond length is 1.35 Å. The C(40)-H(64) bond length is 0.93 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(39), and one C(40) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(39) and one N(3) atom. The N(2)-N(3) bond length is 1.35 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(1), one C(40), and one N(2) atom. In the fourth N site, N(7) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(10), and one C(9) atom. In the fifth N site, N(8) is bonded in a distorted trigonal planar geometry to one C(10), one C(11), and one N(9) atom. The N(8)-N(9) bond length is 1.34 Å. In the sixth N site, N(9) is bonded in a distorted water-like geometry to one C(9) and one N(8) atom. In the seventh N site, N(4) is bonded in a water-like geometry to one C(7) and one N(5) atom. The N(4)-N(5) bond length is 1.33 Å. In the eighth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(4) atom. In the ninth N site, N(6) is bonded in a trigonal planar geometry to one Cu(2), one C(7), and one C(8) atom. In the tenth N site, N(22) is bonded in a trigonal planar geometry to one Cu(2), one C(34), and one C(35) atom. In the eleventh N site, N(24) is bonded in a distorted trigonal planar geometry to one C(34), one C(36), and one N(23) atom. The N(24)-N(23) bond length is 1.35 Å. In the twelfth N site, N(23) is bonded in a water-like geometry to one C(35) and one N(24) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(11,12) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(17,18) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(55) is bonded in a single-bond geometry to one C(34) atom. In the twelfth H site, H(56) is bonded in a single-bond geometry to one C(35) atom. In the thirteenth H site, H(57,58) is bonded in a single-bond geometry to one C(36) atom. In the fourteenth H site, H(63) is bonded in a single-bond geometry to one C(39) atom. In the fifteenth H site, H(64) is bonded in a single-bond geometry to one C(40) atom. In each CuH20(C7N6)2 cluster, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(10), one N(13), one N(18), and one N(19) atom. The Cu(1)-N(10) bond length is 1.98 Å. The Cu(1)-N(13) bond length is 1.96 Å. The Cu(1)-N(18) bond length is 2.01 Å. The Cu(1)-N(19) bond length is 2.00 Å. There are fourteen inequivalent C sites. In the first C site, C(27) is bonded in a trigonal planar geometry to one N(17), one N(18), and one H(45) atom. The C(27)-N(17) bond length is 1.28 Å. The C(27)-N(18) bond length is 1.37 Å. The C(27)-H(45) bond length is 0.93 Å. In the second C site, C(15) is bonded in a water-like geometry to one C(16) and two equivalent H(25,26) atoms. The C(15)-C(16) bond length is 1.48 Å. Both C(15)-H(25,26) bond lengths are 0.97 Å. In the third C site, C(16) is bonded in a 4-coordinate geometry to one C(15); one N(12); and two equivalent H(27,28) atoms. The C(16)-N(12) bond length is 1.51 Å. Both C(16)-H(27,28) bond lengths are 0.97 Å. In the fourth C site, C(17) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(29) atom. The C(17)-N(10) bond length is 1.34 Å. The C(17)-N(12) bond length is 1.31 Å. The C(17)-H(29) bond length is 0.93 Å. In the fifth C site, C(18) is bonded in a trigonal planar geometry to one N(10), one N(11), and one H(30) atom. The C(18)-N(10) bond length is 1.35 Å. The C(18)-N(11) bond length is 1.31 Å. The C(18)-H(30) bond length is 0.93 Å. In the sixth C site, C(19) is bonded in a trigonal planar geometry to one N(13), one N(15), and one H(31) atom. The C(19)-N(13) bond length is 1.35 Å. The C(19)-N(15) bond length is 1.31 Å. The C(19)-H(31) bond length is 0.93 Å. In the seventh C site, C(20) is bonded in a trigonal planar geometry to one N(13), one N(14), and one H(32) atom. The C(20)-N(13) bond length is 1.33 Å. The C(20)-N(14) bond length is 1.31 Å. The C(20)-H(32) bond length is 0.93 Å. In the eighth C site, C(21) is bonded in a 3-coordinate geometry to one N(14) and two equivalent H(33,34) atoms. The C(21)-N(14) bond length is 1.45 Å. Both C(21)-H(33,34) bond lengths are 0.97 Å. In the ninth C site, C(25) is bonded in a distorted water-like geometry to one C(26) and two equivalent H(41,42) atoms. The C(25)-C(26) bond length is 1.49 Å. Both C(25)-H(41,42) bond lengths are 0.97 Å. In the tenth C site, C(26) is bonded in a 4-coordinate geometry to one C(25); one N(16); and two equivalent H(43,44) atoms. The C(26)-N(16) bond length is 1.49 Å. Both C(26)-H(43,44) bond lengths are 0.97 Å. In the eleventh C site, C(29) is bonded in a trigonal planar geometry to one N(19), one N(21), and one H(47) atom. The C(29)-N(19) bond length is 1.31 Å. The C(29)-N(21) bond length is 1.34 Å. The C(29)-H(47) bond length is 0.93 Å. In the twelfth C site, C(30) is bonded in a trigonal planar geometry to one N(19), one N(20), and one H(48) atom. The C(30)-N(19) bond length is 1.35 Å. The C(30)-N(20) bond length is 1.28 Å. The C(30)-H(48) bond length is 0.93 Å. In the thirteenth C site, C(31) is bonded in a 3-coordinate geometry to one N(21), one H(49), and one H(50) atom. The C(31)-N(21) bond length is 1.45 Å. The C(31)-H(49) bond length is 0.97 Å. The C(31)-H(50) bond length is 0.97 Å. In the fourteenth C site, C(28) is bonded in a trigonal planar geometry to one N(16), one N(18), and one H(46) atom. The C(28)-N(16) bond length is 1.31 Å. The C(28)-N(18) bond length is 1.32 Å. The C(28)-H(46) bond length is 0.93 Å. There are twelve inequivalent N sites. In the first N site, N(10) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(17), and one C(18) atom. In the second N site, N(11) is bonded in a distorted water-like geometry to one C(18) and one N(12) atom. The N(11)-N(12) bond length is 1.37 Å. In the third N site, N(12) is bonded in a 2-coordinate geometry to one C(16), one C(17), and one N(11) atom. In the fourth N site, N(13) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(19), and one C(20) atom. In the fifth N site, N(14) is bonded in a distorted trigonal planar geometry to one C(20), one C(21), and one N(15) atom. The N(14)-N(15) bond length is 1.33 Å. In the sixth N site, N(15) is bonded in a distorted water-like geometry to one C(19) and one N(14) atom. In the seventh N site, N(19) is bonded in a trigonal planar geometry to one Cu(1), one C(29), and one C(30) atom. In the eighth N site, N(20) is bonded in a distorted water-like geometry to one C(30) and one N(21) atom. The N(20)-N(21) bond length is 1.34 Å. In the ninth N site, N(21) is bonded in a 2-coordinate geometry to one C(29), one C(31), and one N(20) atom. In the tenth N site, N(16) is bonded in a distorted trigonal planar geometry to one C(26), one C(28), and one N(17) atom. The N(16)-N(17) bond length is 1.35 Å. In the eleventh N site, N(17) is bonded in a distorted water-like geometry to one C(27) and one N(16) atom. In the twelfth N site, N(18) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(27), and one C(28) atom. There are fifteen inequivalent H sites. In the first H site, H(45) is bonded in a single-bond geometry to one C(27) atom. In the second H site, H(46) is bonded in a single-bond geometry to one C(28) atom. In the third H site, H(25,26) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(27,28) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(29) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(30) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(31) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(32) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(33,34) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(41,42) is bonded in a single-bond geometry to one C(25) atom. In the eleventh H site, H(47) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(48) is bonded in a single-bond geometry to one C(30) atom. In the thirteenth H site, H(49) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(50) is bonded in a single-bond geometry to one C(31) atom. In the fifteenth H site, H(43,44) is bonded in a single-bond geometry to one C(26) atom. Linkers: 5 [CH]1N=C[N]N1CCCCCCN1[CH]N=C[N]1 ,10 [CH]1N=C[N]N1CCCCCCn1cncn1 ,1 c1ncn(CCCCCCn2cncn2)n1. Metal clusters: 8 [Cu]. The MOF has largest included sphere 7.57 A, density 0.97 g/cm3, surface area 5527.92 m2/g, accessible volume 0.46 cm3/g