CuH24(C6N)4CuH8(C2N)4(CH)16 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen isobutylene molecules, four CuH24(C6N)4 clusters, and four CuH8(C2N)4 clusters. In each CuH24(C6N)4 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(3) atoms. Both Cu(1)-N(1) bond lengths are 2.08 Å. Both Cu(1)-N(3) bond lengths are 2.05 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.37 Å. The C(3)-C(6) bond length is 1.51 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-H(3) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.37 Å. The C(5)-H(4) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a water-like geometry to one C(3) and two equivalent H(5,6) atoms. Both C(6)-H(5,6) bond lengths are 0.97 Å. In the seventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one H(13) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-N(3) bond length is 1.32 Å. The C(13)-H(13) bond length is 0.93 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(14) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(14) bond length is 0.93 Å. In the ninth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-C(18) bond length is 1.52 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(15) atom. The C(16)-H(15) bond length is 0.93 Å. In the eleventh C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(16) atom. The C(17)-N(3) bond length is 1.34 Å. The C(17)-H(16) bond length is 0.93 Å. In the twelfth C site, C(18) is bonded in a water-like geometry to one C(15) and two equivalent H(17,18) atoms. Both C(18)-H(17,18) bond lengths are 0.97 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(17) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(17,18) is bonded in a single-bond geometry to one C(18) atom. In each CuH8(C2N)4 cluster, Cu(2) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent N(4) atoms. Both Cu(2)-N(2) bond lengths are 2.02 Å. Both Cu(2)-N(4) bond lengths are 2.08 Å. There are four inequivalent C sites. In the first C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(19) atom. The C(19)-N(4) bond length is 1.34 Å. The C(19)-H(19) bond length is 0.93 Å. In the second C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(7)-N(2) bond length is 1.33 Å. The C(7)-H(7) bond length is 0.93 Å. In the third C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(10) bond length is 0.93 Å. In the fourth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(22) atom. The C(23)-N(4) bond length is 1.32 Å. The C(23)-H(22) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(11), and one C(7) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(19), and one C(23) atom. There are four inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(22) is bonded in a single-bond geometry to one C(23) atom. Linkers: 8 c1cc(CCc2ccncc2)ccn1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 4.84 A, density 0.99 g/cm3, surface area 5568.47 m2/g, accessible volume 0.49 cm3/g