CdC12H8(NO2)2(C3H2)2(CH)2(C9NH3O2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; four 2,3-dimethyl-1,3-butadiene molecules; four 6-methyl-13-prop-1-en-2-yl-6,13-diazatetracyclo[6.6.2.04,16.011,15]hexadeca-1(15),2,4(16),8,10-pentaene-5,7,12,14-tetrone molecules; and two CdC12H8(NO2)2 clusters. In each CdC12H8(NO2)2 cluster, Cd(1) is bonded to one N(1), one N(4), one O(1), one O(2), one O(4), and two equivalent O(3) atoms to form edge-sharing CdN2O5 pentagonal bipyramids. The Cd(1)-N(1) bond length is 2.34 Å. The Cd(1)-N(4) bond length is 2.34 Å. The Cd(1)-O(1) bond length is 2.47 Å. The Cd(1)-O(2) bond length is 2.32 Å. The Cd(1)-O(4) bond length is 2.34 Å. There is one shorter (2.38 Å) and one longer (2.55 Å) Cd(1)-O(3) bond length. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.23 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.36 Å. The C(2)-C(4) bond length is 1.37 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(11) is bonded in a distorted single-bond geometry to one C(13) and one H(7) atom. The C(11)-C(13) bond length is 1.35 Å. The C(11)-H(7) bond length is 0.93 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(8) atom. The C(12)-C(13) bond length is 1.37 Å. The C(12)-H(8) bond length is 0.93 Å. In the seventh C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(14) atom. The C(13)-C(14) bond length is 1.48 Å. In the eighth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.27 Å. The C(14)-O(4) bond length is 1.24 Å. In the ninth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9,10) atom. The C(15)-N(1) bond length is 1.33 Å. The C(15)-H(9,10) bond length is 0.93 Å. In the tenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9,10) atom. The C(16)-N(1) bond length is 1.32 Å. The C(16)-H(9,10) bond length is 0.93 Å. In the eleventh C site, C(37) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(19) atom. The C(37)-N(4) bond length is 1.31 Å. The C(37)-H(19) bond length is 0.93 Å. In the twelfth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(20) atom. The C(38)-N(4) bond length is 1.33 Å. The C(38)-H(20) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(15), and one C(16) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(37), and one C(38) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(9,10) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(37) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(38) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Cd(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(14) atom. In the fourth O site, O(4) is bonded in a distorted water-like geometry to one Cd(1) and one C(14) atom. Linkers: 4 O=C1c2ccc3c4c(ccc(c24)C(=O)N1c1ccncc1)C(=O)N(c1ccncc1)C3=O ,4 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 [C]1O[Cd]2(O1)O[C]O[Cd]1(O[C]O1)O[C]O2. The MOF has largest included sphere 6.94 A, density 1.07 g/cm3, surface area 4294.93 m2/g, accessible volume 0.48 cm3/g