InC12H6(NO2)2 crystallizes in the trigonal R3c space group. In(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one O(3), and one O(4) atom. The In(1)-N(1) bond length is 2.28 Å. The In(1)-N(2) bond length is 2.28 Å. The In(1)-O(3) bond length is 2.10 Å. The In(1)-O(4) bond length is 2.10 Å. There are twelve inequivalent C sites. In the first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(3) atom. The C(3)-C(6) bond length is 1.48 Å. The C(3)-O(1) bond length is 1.20 Å. The C(3)-O(3) bond length is 1.27 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(1), and one H(2) atom. The C(4)-C(9) bond length is 1.36 Å. The C(4)-N(1) bond length is 1.32 Å. The C(4)-H(2) bond length is 0.93 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(2), one C(8), and one H(3) atom. The C(5)-C(2) bond length is 1.37 Å. The C(5)-C(8) bond length is 1.36 Å. The C(5)-H(3) bond length is 0.93 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(8) atom. The C(6)-C(11) bond length is 1.37 Å. The C(6)-C(8) bond length is 1.37 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(12), one C(9), and one H(6) atom. The C(7)-C(12) bond length is 1.39 Å. The C(7)-C(9) bond length is 1.36 Å. The C(7)-H(6) bond length is 0.93 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(5), one C(6), and one H(1) atom. The C(8)-H(1) bond length is 0.93 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(7) atom. The C(9)-C(1) bond length is 1.51 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(12) and one N(1) atom. The C(10)-C(12) bond length is 1.37 Å. The C(10)-N(1) bond length is 1.32 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(2), and one H(5) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(5) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(10), one C(7), and one H(4) atom. The C(12)-H(4) bond length is 0.93 Å. In the eleventh C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(2), and one O(4) atom. The C(1)-O(2) bond length is 1.21 Å. The C(1)-O(4) bond length is 1.25 Å. In the twelfth C site, C(2) is bonded in a distorted single-bond geometry to one C(5) and one N(2) atom. The C(2)-N(2) bond length is 1.32 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one In(1), one C(10), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one In(1), one C(11), and one C(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one In(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one In(1) and one C(1) atom. 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Metal clusters: 2 O=[C]O[In]O[C]=O. The MOF has largest included sphere 8.76 A, density 0.88 g/cm3, surface area 3514.47 m2/g, accessible volume 0.78 cm3/g