ZnC6H4(NO2)2(CH)8(CH2)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, eight isobutylene molecules, and four ZnC6H4(NO2)2 clusters. In each ZnC6H4(NO2)2 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(2), one O(1), and one O(4) atom. The Zn(1)-N(1) bond length is 2.07 Å. The Zn(1)-N(2) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(4) bond length is 1.99 Å. There are six inequivalent C sites. In the first C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(4)-N(2) bond length is 1.34 Å. The C(4)-H(9) bond length is 0.95 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(14) atom. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(14) bond length is 0.95 Å. In the third C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(7)-O(1) bond length is 1.27 Å. The C(7)-O(2) bond length is 1.24 Å. In the fourth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(9)-N(1) bond length is 1.33 Å. The C(9)-H(5) bond length is 0.95 Å. In the fifth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(10)-O(3) bond length is 1.23 Å. The C(10)-O(4) bond length is 1.28 Å. In the sixth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(14)-N(1) bond length is 1.34 Å. The C(14)-H(3) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(14), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(4) atom. There are four inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(14) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(1) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(7) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(7) atom. In the third O site, O(4) is bonded in a water-like geometry to one Zn(1) and one C(10) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one C(10) atom. Linkers: 4 [O]C(=O)CCC([O])=O ,3 c1cc(CCc2ccncc2)ccn1. Metal clusters: 2 [Zn] ,2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 3.94 A, density 1.27 g/cm3, surface area 5144.61 m2/g, accessible volume 0.34 cm3/g