Zn5C28H12O19(CH2)6(CH2CO)4 crystallizes in the monoclinic P2_1/c space group. The structure consists of twenty-four 02329_fluka molecules and sixteen dimethyl ether molecules inside a Zn5C28H12O19 framework. In the Zn5C28H12O19 framework, there are five inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(20), and one O(5) atom. The Zn(1)-O(1) bond length is 2.05 Å. The Zn(1)-O(20) bond length is 1.97 Å. The Zn(1)-O(5) bond length is 2.05 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(12), one O(13), one O(15), and one O(4) atom to form corner-sharing ZnO5 trigonal bipyramids. The Zn(2)-O(1) bond length is 1.95 Å. The Zn(2)-O(12) bond length is 2.03 Å. The Zn(2)-O(13) bond length is 1.97 Å. The Zn(2)-O(15) bond length is 2.35 Å. The Zn(2)-O(4) bond length is 2.01 Å. In the third Zn site, Zn(3) is bonded to one O(11), one O(13), one O(16), and one O(19) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(11) bond length is 1.99 Å. The Zn(3)-O(13) bond length is 1.93 Å. The Zn(3)-O(16) bond length is 1.98 Å. The Zn(3)-O(19) bond length is 1.93 Å. In the fourth Zn site, Zn(4) is bonded in a 5-coordinate geometry to one O(1), one O(14), one O(17), one O(21), and one O(5) atom. The Zn(4)-O(1) bond length is 2.26 Å. The Zn(4)-O(14) bond length is 2.00 Å. The Zn(4)-O(17) bond length is 2.00 Å. The Zn(4)-O(21) bond length is 2.08 Å. The Zn(4)-O(5) bond length is 2.01 Å. In the fifth Zn site, Zn(5) is bonded in a 5-coordinate geometry to one O(10), one O(3), one O(5), one O(8), and one O(9) atom. The Zn(5)-O(10) bond length is 1.97 Å. The Zn(5)-O(3) bond length is 2.06 Å. The Zn(5)-O(5) bond length is 2.01 Å. The Zn(5)-O(8) bond length is 2.31 Å. The Zn(5)-O(9) bond length is 1.96 Å. There are twenty-eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(25), one C(39), and one C(41) atom. The C(1)-C(25) bond length is 1.36 Å. The C(1)-C(39) bond length is 1.37 Å. The C(1)-C(41) bond length is 1.50 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(5) atom. The C(2)-C(11) bond length is 1.38 Å. The C(2)-C(15) bond length is 1.51 Å. The C(2)-C(5) bond length is 1.38 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(34), one C(35), and one C(38) atom. The C(4)-C(34) bond length is 1.38 Å. The C(4)-C(35) bond length is 1.50 Å. The C(4)-C(38) bond length is 1.36 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(2) and one H(32) atom. The C(5)-H(32) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(40) and one H(20) atom. The C(6)-C(40) bond length is 1.36 Å. The C(6)-H(20) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(20), one C(21), and one H(1) atom. The C(7)-C(20) bond length is 1.41 Å. The C(7)-C(21) bond length is 1.38 Å. The C(7)-H(1) bond length is 0.93 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(20) and one H(13) atom. The C(9)-C(20) bond length is 1.39 Å. The C(9)-H(13) bond length is 0.93 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(26), one C(33), and one C(39) atom. The C(10)-C(26) bond length is 1.51 Å. The C(10)-C(33) bond length is 1.40 Å. The C(10)-C(39) bond length is 1.37 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(2), one C(40), and one H(3) atom. The C(11)-C(40) bond length is 1.39 Å. The C(11)-H(3) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(11), and one O(4) atom. The C(12)-C(29) bond length is 1.51 Å. The C(12)-O(11) bond length is 1.27 Å. The C(12)-O(4) bond length is 1.25 Å. In the eleventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(16), and one O(23) atom. The C(13)-C(20) bond length is 1.50 Å. The C(13)-O(16) bond length is 1.26 Å. The C(13)-O(23) bond length is 1.26 Å. In the twelfth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(15), and one O(19) atom. The C(15)-O(15) bond length is 1.25 Å. The C(15)-O(19) bond length is 1.28 Å. In the thirteenth C site, C(20) is bonded in a trigonal planar geometry to one C(13), one C(7), and one C(9) atom. In the fourteenth C site, C(21) is bonded in a trigonal planar geometry to one C(27), one C(31), and one C(7) atom. The C(21)-C(27) bond length is 1.51 Å. The C(21)-C(31) bond length is 1.38 Å. In the fifteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(1) and one H(27) atom. The C(25)-H(27) bond length is 0.93 Å. In the sixteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(14), and one O(2) atom. The C(26)-O(14) bond length is 1.27 Å. The C(26)-O(2) bond length is 1.26 Å. In the seventeenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(21), and one O(9) atom. The C(27)-O(21) bond length is 1.25 Å. The C(27)-O(9) bond length is 1.26 Å. In the eighteenth C site, C(29) is bonded in a trigonal planar geometry to one C(12), one C(36), and one C(38) atom. The C(29)-C(36) bond length is 1.37 Å. The C(29)-C(38) bond length is 1.39 Å. In the nineteenth C site, C(31) is bonded in a distorted single-bond geometry to one C(21) and one H(12) atom. The C(31)-H(12) bond length is 0.93 Å. In the twentieth C site, C(33) is bonded in a distorted single-bond geometry to one C(10) and one H(28) atom. The C(33)-H(28) bond length is 0.93 Å. In the twenty-first C site, C(34) is bonded in a distorted single-bond geometry to one C(4) and one H(25) atom. The C(34)-H(25) bond length is 0.93 Å. In the twenty-second C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(8) atom. The C(35)-O(3) bond length is 1.25 Å. The C(35)-O(8) bond length is 1.24 Å. In the twenty-third C site, C(36) is bonded in a distorted single-bond geometry to one C(29) and one H(8) atom. The C(36)-H(8) bond length is 0.93 Å. In the twenty-fourth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(40), one O(12), and one O(20) atom. The C(37)-C(40) bond length is 1.49 Å. The C(37)-O(12) bond length is 1.26 Å. The C(37)-O(20) bond length is 1.26 Å. In the twenty-fifth C site, C(38) is bonded in a distorted single-bond geometry to one C(29), one C(4), and one H(29) atom. The C(38)-H(29) bond length is 0.93 Å. In the twenty-sixth C site, C(39) is bonded in a distorted single-bond geometry to one C(1), one C(10), and one H(21) atom. The C(39)-H(21) bond length is 0.93 Å. In the twenty-seventh C site, C(40) is bonded in a trigonal planar geometry to one C(11), one C(37), and one C(6) atom. In the twenty-eighth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(10), and one O(17) atom. The C(41)-O(10) bond length is 1.27 Å. The C(41)-O(17) bond length is 1.26 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(36) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(31) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(21) is bonded in a single-bond geometry to one C(39) atom. In the eighth H site, H(25) is bonded in a single-bond geometry to one C(34) atom. In the ninth H site, H(27) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(28) is bonded in a single-bond geometry to one C(33) atom. In the eleventh H site, H(29) is bonded in a single-bond geometry to one C(38) atom. In the twelfth H site, H(32) is bonded in a single-bond geometry to one C(5) atom. There are nineteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one Zn(2), and one Zn(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(26) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Zn(5) and one C(35) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(12) atom. In the fifth O site, O(5) is bonded in a trigonal non-coplanar geometry to one Zn(1), one Zn(4), and one Zn(5) atom. In the sixth O site, O(8) is bonded in a distorted L-shaped geometry to one Zn(5) and one C(35) atom. In the seventh O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(27) atom. In the eighth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(41) atom. In the ninth O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(12) atom. In the tenth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(37) atom. In the eleventh O site, O(13) is bonded in a water-like geometry to one Zn(2) and one Zn(3) atom. In the twelfth O site, O(14) is bonded in a water-like geometry to one Zn(4) and one C(26) atom. In the thirteenth O site, O(15) is bonded in a distorted single-bond geometry to one Zn(2) and one C(15) atom. In the fourteenth O site, O(16) is bonded in a water-like geometry to one Zn(3) and one C(13) atom. In the fifteenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Zn(4) and one C(41) atom. In the sixteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(15) atom. In the seventeenth O site, O(20) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(37) atom. In the eighteenth O site, O(21) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(27) atom. In the nineteenth O site, O(23) is bonded in a single-bond geometry to one C(13) atom. Linkers: 8 [O]C(=O)c1cc(OCCCCCOc2cc(C([O])=O)cc(C([O])=O)c2)cc(C([O])=O)c1. Metal clusters: 2 O=[C]O[Zn]1(O[C]=O)O[C]O[Zn@@]2(O[C]O[Zn]O2)O1.O=[C]O[Zn]12O[C]O[Zn]3(O[C]O1)(O[C]O3)O2 ,2 O=[C]O[Zn]1(O[C]=O)O[C]O[Zn@]2(O[C]O[Zn]O2)O1.O=[C]O[Zn]12O[C]O[Zn]3(O[C]O1)(O[C]O3)O2. The MOF has largest included sphere 4.42 A, density 1.45 g/cm3, surface area 4039.77 m2/g, accessible volume 0.27 cm3/g