Cd6C79H47(NO2)10(CH)21C6NH5C4NH3 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eighty-four 02329_fluka molecules, four methyl(propan-2-ylidene)azanium molecules, four C6NH5 clusters, and four Cd6C79H47(NO2)10 clusters. In each C6NH5 cluster, there are six inequivalent C sites. In the first C site, C(40) is bonded in a distorted single-bond geometry to one C(41) and one H(30,31) atom. The C(40)-C(41) bond length is 1.38 Å. The C(40)-H(30,31) bond length is 0.95 Å. In the second C site, C(41) is bonded in a distorted trigonal planar geometry to one C(40), one C(42), and one N(5) atom. The C(41)-C(42) bond length is 1.36 Å. The C(41)-N(5) bond length is 1.39 Å. In the third C site, C(42) is bonded in a distorted single-bond geometry to one C(41) and one H(30,31) atom. The C(42)-H(30,31) bond length is 0.95 Å. In the fourth C site, C(44) is bonded in a distorted trigonal planar geometry to one C(45), one C(48), and one N(5) atom. The C(44)-C(45) bond length is 1.36 Å. The C(44)-C(48) bond length is 1.40 Å. The C(44)-N(5) bond length is 1.38 Å. In the fifth C site, C(45) is bonded in a distorted single-bond geometry to one C(44) and one H(33) atom. The C(45)-H(33) bond length is 0.95 Å. In the sixth C site, C(48) is bonded in a single-bond geometry to one C(44) and one H(36) atom. The C(48)-H(36) bond length is 0.95 Å. N(5) is bonded in a trigonal planar geometry to one C(41), one C(44), and one H(2) atom. The N(5)-H(2) bond length is 0.88 Å. There are four inequivalent H sites. In the first H site, H(30,31) is bonded in a single-bond geometry to one C(40) atom. In the second H site, H(33) is bonded in a single-bond geometry to one C(45) atom. In the third H site, H(2) is bonded in a single-bond geometry to one N(5) atom. In the fourth H site, H(36) is bonded in a single-bond geometry to one C(48) atom. In each Cd6C79H47(NO2)10 cluster, there are six inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in an octahedral geometry to one N(1), one N(4), one O(1), one O(3), one O(5), and one O(7) atom. The Cd(1)-N(1) bond length is 2.25 Å. The Cd(1)-N(4) bond length is 2.27 Å. The Cd(1)-O(1) bond length is 2.39 Å. The Cd(1)-O(3) bond length is 2.36 Å. The Cd(1)-O(5) bond length is 2.38 Å. The Cd(1)-O(7) bond length is 2.27 Å. In the second Cd site, Cd(2) is bonded in a T-shaped geometry to one N(7), one O(1), and one O(2) atom. The Cd(2)-N(7) bond length is 2.30 Å. The Cd(2)-O(1) bond length is 2.55 Å. The Cd(2)-O(2) bond length is 2.46 Å. In the third Cd site, Cd(3) is bonded in an octahedral geometry to one N(12), one N(9), one O(11), one O(13), one O(15), and one O(9) atom. The Cd(3)-N(12) bond length is 2.28 Å. The Cd(3)-N(9) bond length is 2.26 Å. The Cd(3)-O(11) bond length is 2.34 Å. The Cd(3)-O(13) bond length is 2.31 Å. The Cd(3)-O(15) bond length is 2.29 Å. The Cd(3)-O(9) bond length is 2.44 Å. In the fourth Cd site, Cd(4) is bonded in a 5-coordinate geometry to one N(6), one O(10), one O(13), one O(14), and one O(9) atom. The Cd(4)-N(6) bond length is 2.28 Å. The Cd(4)-O(10) bond length is 2.48 Å. The Cd(4)-O(13) bond length is 2.48 Å. The Cd(4)-O(14) bond length is 2.41 Å. The Cd(4)-O(9) bond length is 2.38 Å. In the fifth Cd site, Cd(5) is bonded in a 6-coordinate geometry to one N(10), one O(17), one O(19), one O(3), one O(4), and one O(5) atom. The Cd(5)-N(10) bond length is 2.26 Å. The Cd(5)-O(17) bond length is 2.19 Å. The Cd(5)-O(19) bond length is 2.62 Å. The Cd(5)-O(3) bond length is 2.41 Å. The Cd(5)-O(4) bond length is 2.39 Å. The Cd(5)-O(5) bond length is 2.44 Å. In the sixth Cd site, Cd(6) is bonded in a 3-coordinate geometry to one N(3), one O(12), and one O(20) atom. The Cd(6)-N(3) bond length is 2.31 Å. The Cd(6)-O(12) bond length is 2.31 Å. The Cd(6)-O(20) bond length is 2.24 Å. There are seventy-nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(2) atom. The C(1)-C(3) bond length is 1.47 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(35) and one H(5) atom. The C(2)-C(35) bond length is 1.40 Å. The C(2)-H(5) bond length is 0.95 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(8) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(6) atom. The C(4)-H(6) bond length is 0.95 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(9) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(9) bond length is 0.95 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.49 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.42 Å. The C(9)-C(14) bond length is 1.39 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-C(15) bond length is 1.49 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(10) atom. The C(11)-H(10) bond length is 0.95 Å. In the tenth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(13) atom. The C(14)-H(13) bond length is 0.95 Å. In the eleventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(4) atom. The C(15)-O(3) bond length is 1.27 Å. The C(15)-O(4) bond length is 1.27 Å. In the twelfth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(5), and one O(6) atom. The C(16)-C(17) bond length is 1.49 Å. The C(16)-O(5) bond length is 1.26 Å. The C(16)-O(6) bond length is 1.25 Å. In the thirteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(22) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(22) bond length is 1.38 Å. In the fourteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(23) atom. The C(18)-C(19) bond length is 1.38 Å. The C(18)-C(23) bond length is 1.50 Å. In the fifteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(14) atom. The C(19)-H(14) bond length is 0.95 Å. In the sixteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(17) and one H(17) atom. The C(22)-H(17) bond length is 0.95 Å. In the seventeenth C site, C(23) is bonded in a trigonal planar geometry to one C(18), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.34 Å. The C(23)-C(28) bond length is 1.43 Å. In the eighteenth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(29) atom. The C(24)-C(25) bond length is 1.43 Å. The C(24)-C(29) bond length is 1.46 Å. In the nineteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(18) atom. The C(25)-H(18) bond length is 0.95 Å. In the twentieth C site, C(28) is bonded in a distorted single-bond geometry to one C(23) and one H(21) atom. The C(28)-H(21) bond length is 0.95 Å. In the twenty-first C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(7), and one O(8) atom. The C(29)-O(7) bond length is 1.35 Å. The C(29)-O(8) bond length is 1.22 Å. In the twenty-second C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(22) atom. The C(30)-N(1) bond length is 1.35 Å. The C(30)-H(22) bond length is 0.95 Å. In the twenty-third C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(23) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-H(23) bond length is 0.95 Å. In the twenty-fourth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31), one C(33), and one N(2) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-N(2) bond length is 1.38 Å. In the twenty-fifth C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(24) atom. The C(33)-H(24) bond length is 0.95 Å. In the twenty-sixth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(25) atom. The C(34)-N(1) bond length is 1.35 Å. The C(34)-H(25) bond length is 0.95 Å. In the twenty-seventh C site, C(35) is bonded in a distorted single-bond geometry to one C(2), one C(36), and one N(2) atom. The C(35)-C(36) bond length is 1.40 Å. The C(35)-N(2) bond length is 1.38 Å. In the twenty-eighth C site, C(36) is bonded in a single-bond geometry to one C(35), one C(37), and one H(26) atom. The C(36)-C(37) bond length is 1.36 Å. The C(36)-H(26) bond length is 0.95 Å. In the twenty-ninth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(36), one N(3), and one H(27) atom. The C(37)-N(3) bond length is 1.34 Å. The C(37)-H(27) bond length is 0.95 Å. In the thirtieth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(28) atom. The C(38)-N(3) bond length is 1.33 Å. The C(38)-H(28) bond length is 0.95 Å. In the thirty-first C site, C(39) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(29) atom. The C(39)-N(4) bond length is 1.34 Å. The C(39)-H(29) bond length is 0.95 Å. In the thirty-second C site, C(43) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(32) atom. The C(43)-N(4) bond length is 1.33 Å. The C(43)-H(32) bond length is 0.95 Å. In the thirty-third C site, C(46) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(34) atom. The C(46)-N(6) bond length is 1.34 Å. The C(46)-H(34) bond length is 0.95 Å. In the thirty-fourth C site, C(47) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(35) atom. The C(47)-N(6) bond length is 1.34 Å. The C(47)-H(35) bond length is 0.95 Å. In the thirty-fifth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(37) atom. The C(49)-N(7) bond length is 1.33 Å. The C(49)-H(37) bond length is 0.95 Å. In the thirty-sixth C site, C(52) is bonded in a distorted single-bond geometry to one C(53) and one H(39) atom. The C(52)-C(53) bond length is 1.38 Å. The C(52)-H(39) bond length is 0.95 Å. In the thirty-seventh C site, C(53) is bonded in a distorted trigonal planar geometry to one C(52), one N(7), and one H(40) atom. The C(53)-N(7) bond length is 1.33 Å. The C(53)-H(40) bond length is 0.95 Å. In the thirty-eighth C site, C(56) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(42) atom. The C(56)-N(9) bond length is 1.34 Å. The C(56)-H(42) bond length is 0.95 Å. In the thirty-ninth C site, C(57) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(43) atom. The C(57)-N(9) bond length is 1.35 Å. The C(57)-H(43) bond length is 0.95 Å. In the fortieth C site, C(59) is bonded in a distorted bent 120 degrees geometry to one C(60), one O(10), and one O(9) atom. The C(59)-C(60) bond length is 1.48 Å. The C(59)-O(10) bond length is 1.25 Å. The C(59)-O(9) bond length is 1.26 Å. In the forty-first C site, C(60) is bonded in a trigonal planar geometry to one C(59), one C(61), and one C(65) atom. The C(60)-C(61) bond length is 1.42 Å. The C(60)-C(65) bond length is 1.37 Å. In the forty-second C site, C(61) is bonded in a trigonal planar geometry to one C(60), one C(62), and one C(66) atom. The C(61)-C(62) bond length is 1.39 Å. The C(61)-C(66) bond length is 1.49 Å. In the forty-third C site, C(62) is bonded in a distorted single-bond geometry to one C(61) and one H(45) atom. The C(62)-H(45) bond length is 0.95 Å. In the forty-fourth C site, C(65) is bonded in a distorted single-bond geometry to one C(60) and one H(48) atom. The C(65)-H(48) bond length is 0.95 Å. In the forty-fifth C site, C(66) is bonded in a trigonal planar geometry to one C(61), one C(67), and one C(71) atom. The C(66)-C(67) bond length is 1.41 Å. The C(66)-C(71) bond length is 1.39 Å. In the forty-sixth C site, C(67) is bonded in a trigonal planar geometry to one C(66), one C(68), and one C(72) atom. The C(67)-C(68) bond length is 1.39 Å. The C(67)-C(72) bond length is 1.49 Å. In the forty-seventh C site, C(68) is bonded in a distorted single-bond geometry to one C(67) and one H(49) atom. The C(68)-H(49) bond length is 0.95 Å. In the forty-eighth C site, C(71) is bonded in a distorted single-bond geometry to one C(66) and one H(52) atom. The C(71)-H(52) bond length is 0.95 Å. In the forty-ninth C site, C(72) is bonded in a distorted bent 120 degrees geometry to one C(67), one O(11), and one O(12) atom. The C(72)-O(11) bond length is 1.27 Å. The C(72)-O(12) bond length is 1.27 Å. In the fiftieth C site, C(73) is bonded in a bent 120 degrees geometry to one C(74), one O(13), and one O(14) atom. The C(73)-C(74) bond length is 1.50 Å. The C(73)-O(13) bond length is 1.28 Å. The C(73)-O(14) bond length is 1.24 Å. In the fifty-first C site, C(74) is bonded in a trigonal planar geometry to one C(73), one C(75), and one C(79) atom. The C(74)-C(75) bond length is 1.41 Å. The C(74)-C(79) bond length is 1.39 Å. In the fifty-second C site, C(75) is bonded in a trigonal planar geometry to one C(74), one C(76), and one C(80) atom. The C(75)-C(76) bond length is 1.38 Å. The C(75)-C(80) bond length is 1.50 Å. In the fifty-third C site, C(76) is bonded in a distorted single-bond geometry to one C(75) and one H(53) atom. The C(76)-H(53) bond length is 0.95 Å. In the fifty-fourth C site, C(79) is bonded in a distorted single-bond geometry to one C(74) and one H(56) atom. The C(79)-H(56) bond length is 0.95 Å. In the fifty-fifth C site, C(80) is bonded in a trigonal planar geometry to one C(75), one C(81), and one C(85) atom. The C(80)-C(81) bond length is 1.40 Å. The C(80)-C(85) bond length is 1.40 Å. In the fifty-sixth C site, C(81) is bonded in a trigonal planar geometry to one C(80), one C(82), and one C(86) atom. The C(81)-C(82) bond length is 1.41 Å. The C(81)-C(86) bond length is 1.52 Å. In the fifty-seventh C site, C(82) is bonded in a distorted single-bond geometry to one C(81) and one H(57) atom. The C(82)-H(57) bond length is 0.95 Å. In the fifty-eighth C site, C(85) is bonded in a distorted single-bond geometry to one C(80) and one H(60) atom. The C(85)-H(60) bond length is 0.95 Å. In the fifty-ninth C site, C(86) is bonded in a distorted bent 120 degrees geometry to one C(81), one O(15), and one O(16) atom. The C(86)-O(15) bond length is 1.29 Å. The C(86)-O(16) bond length is 1.24 Å. In the sixtieth C site, C(87) is bonded in a distorted bent 120 degrees geometry to one C(88), one O(17), and one O(18) atom. The C(87)-C(88) bond length is 1.52 Å. The C(87)-O(17) bond length is 1.27 Å. The C(87)-O(18) bond length is 1.24 Å. In the sixty-first C site, C(88) is bonded in a trigonal planar geometry to one C(87), one C(89), and one C(93) atom. The C(88)-C(89) bond length is 1.40 Å. The C(88)-C(93) bond length is 1.40 Å. In the sixty-second C site, C(89) is bonded in a trigonal planar geometry to one C(88), one C(90), and one C(94) atom. The C(89)-C(90) bond length is 1.41 Å. The C(89)-C(94) bond length is 1.48 Å. In the sixty-third C site, C(90) is bonded in a distorted single-bond geometry to one C(89) and one H(61) atom. The C(90)-H(61) bond length is 0.95 Å. In the sixty-fourth C site, C(93) is bonded in a distorted single-bond geometry to one C(88) and one H(64) atom. The C(93)-H(64) bond length is 0.95 Å. In the sixty-fifth C site, C(94) is bonded in a trigonal planar geometry to one C(89), one C(95), and one C(99) atom. The C(94)-C(95) bond length is 1.39 Å. The C(94)-C(99) bond length is 1.40 Å. In the sixty-sixth C site, C(95) is bonded in a trigonal planar geometry to one C(100), one C(94), and one C(96) atom. The C(95)-C(100) bond length is 1.52 Å. The C(95)-C(96) bond length is 1.40 Å. In the sixty-seventh C site, C(96) is bonded in a distorted single-bond geometry to one C(95) and one H(65) atom. The C(96)-H(65) bond length is 0.95 Å. In the sixty-eighth C site, C(99) is bonded in a distorted single-bond geometry to one C(94) and one H(68) atom. The C(99)-H(68) bond length is 0.95 Å. In the sixty-ninth C site, C(100) is bonded in a distorted bent 120 degrees geometry to one C(95), one O(19), and one O(20) atom. The C(100)-O(19) bond length is 1.25 Å. The C(100)-O(20) bond length is 1.25 Å. In the seventieth C site, C(101) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(69) atom. The C(101)-N(10) bond length is 1.36 Å. The C(101)-H(69) bond length is 0.95 Å. In the seventy-first C site, C(102) is bonded in a distorted single-bond geometry to one C(103) and one H(70) atom. The C(102)-C(103) bond length is 1.40 Å. The C(102)-H(70) bond length is 0.95 Å. In the seventy-second C site, C(103) is bonded in a distorted single-bond geometry to one C(102), one C(104), and one N(11) atom. The C(103)-C(104) bond length is 1.39 Å. The C(103)-N(11) bond length is 1.38 Å. In the seventy-third C site, C(104) is bonded in a single-bond geometry to one C(103) and one H(71) atom. The C(104)-H(71) bond length is 0.95 Å. In the seventy-fourth C site, C(105) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(72) atom. The C(105)-N(10) bond length is 1.32 Å. The C(105)-H(72) bond length is 0.95 Å. In the seventy-fifth C site, C(106) is bonded in a distorted trigonal planar geometry to one C(107), one C(110), and one N(11) atom. The C(106)-C(107) bond length is 1.40 Å. The C(106)-C(110) bond length is 1.41 Å. The C(106)-N(11) bond length is 1.40 Å. In the seventy-sixth C site, C(107) is bonded in a distorted single-bond geometry to one C(106), one C(108), and one H(73) atom. The C(107)-C(108) bond length is 1.38 Å. The C(107)-H(73) bond length is 0.95 Å. In the seventy-seventh C site, C(108) is bonded in a distorted trigonal planar geometry to one C(107), one N(12), and one H(74) atom. The C(108)-N(12) bond length is 1.36 Å. The C(108)-H(74) bond length is 0.95 Å. In the seventy-eighth C site, C(109) is bonded in a distorted trigonal planar geometry to one C(110), one N(12), and one H(75) atom. The C(109)-C(110) bond length is 1.37 Å. The C(109)-N(12) bond length is 1.33 Å. The C(109)-H(75) bond length is 0.95 Å. In the seventy-ninth C site, C(110) is bonded in a distorted single-bond geometry to one C(106), one C(109), and one H(76) atom. The C(110)-H(76) bond length is 0.95 Å. There are ten inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(30), and one C(34) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(32), one C(35), and one H(1) atom. The N(2)-H(1) bond length is 0.88 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(6), one C(37), and one C(38) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(39), and one C(43) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one Cd(4), one C(46), and one C(47) atom. In the sixth N site, N(7) is bonded in a trigonal planar geometry to one Cd(2), one C(49), and one C(53) atom. In the seventh N site, N(9) is bonded in a trigonal planar geometry to one Cd(3), one C(56), and one C(57) atom. In the eighth N site, N(10) is bonded in a trigonal planar geometry to one Cd(5), one C(101), and one C(105) atom. In the ninth N site, N(11) is bonded in a trigonal planar geometry to one C(103), one C(106), and one H(4) atom. The N(11)-H(4) bond length is 0.88 Å. In the tenth N site, N(12) is bonded in a trigonal planar geometry to one Cd(3), one C(108), and one C(109) atom. There are forty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one N(11) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(25) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(28) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(30) atom. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(24) is bonded in a single-bond geometry to one C(33) atom. In the fifteenth H site, H(25) is bonded in a single-bond geometry to one C(34) atom. In the sixteenth H site, H(26) is bonded in a single-bond geometry to one C(36) atom. In the seventeenth H site, H(27) is bonded in a single-bond geometry to one C(37) atom. In the eighteenth H site, H(28) is bonded in a single-bond geometry to one C(38) atom. In the nineteenth H site, H(29) is bonded in a single-bond geometry to one C(39) atom. In the twentieth H site, H(32) is bonded in a single-bond geometry to one C(43) atom. In the twenty-first H site, H(34) is bonded in a single-bond geometry to one C(46) atom. In the twenty-second H site, H(35) is bonded in a single-bond geometry to one C(47) atom. In the twenty-third H site, H(37) is bonded in a single-bond geometry to one C(49) atom. In the twenty-fourth H site, H(39) is bonded in a single-bond geometry to one C(52) atom. In the twenty-fifth H site, H(40) is bonded in a single-bond geometry to one C(53) atom. In the twenty-sixth H site, H(42) is bonded in a single-bond geometry to one C(56) atom. In the twenty-seventh H site, H(43) is bonded in a single-bond geometry to one C(57) atom. In the twenty-eighth H site, H(45) is bonded in a single-bond geometry to one C(62) atom. In the twenty-ninth H site, H(48) is bonded in a single-bond geometry to one C(65) atom. In the thirtieth H site, H(49) is bonded in a single-bond geometry to one C(68) atom. In the thirty-first H site, H(52) is bonded in a single-bond geometry to one C(71) atom. In the thirty-second H site, H(53) is bonded in a single-bond geometry to one C(76) atom. In the thirty-third H site, H(56) is bonded in a single-bond geometry to one C(79) atom. In the thirty-fourth H site, H(57) is bonded in a single-bond geometry to one C(82) atom. In the thirty-fifth H site, H(60) is bonded in a single-bond geometry to one C(85) atom. In the thirty-sixth H site, H(61) is bonded in a single-bond geometry to one C(90) atom. In the thirty-seventh H site, H(64) is bonded in a single-bond geometry to one C(93) atom. In the thirty-eighth H site, H(65) is bonded in a single-bond geometry to one C(96) atom. In the thirty-ninth H site, H(68) is bonded in a single-bond geometry to one C(99) atom. In the fortieth H site, H(69) is bonded in a single-bond geometry to one C(101) atom. In the forty-first H site, H(70) is bonded in a single-bond geometry to one C(102) atom. In the forty-second H site, H(71) is bonded in a single-bond geometry to one C(104) atom. In the forty-third H site, H(72) is bonded in a single-bond geometry to one C(105) atom. In the forty-fourth H site, H(73) is bonded in a single-bond geometry to one C(107) atom. In the forty-fifth H site, H(74) is bonded in a single-bond geometry to one C(108) atom. In the forty-sixth H site, H(75) is bonded in a single-bond geometry to one C(109) atom. In the forty-seventh H site, H(76) is bonded in a single-bond geometry to one C(110) atom. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cd(2) and one C(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(5), and one C(15) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(5) and one C(15) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(5), and one C(16) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(16) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(29) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(29) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Cd(3), one Cd(4), and one C(59) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one Cd(4) and one C(59) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Cd(3) and one C(72) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Cd(6) and one C(72) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Cd(3), one Cd(4), and one C(73) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Cd(4) and one C(73) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Cd(3) and one C(86) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one C(86) atom. In the seventeenth O site, O(17) is bonded in a distorted water-like geometry to one Cd(5) and one C(87) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one C(87) atom. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Cd(5) and one C(100) atom. In the twentieth O site, O(20) is bonded in a water-like geometry to one Cd(6) and one C(100) atom. Linkers: 16 c1cc(Nc2ccncc2)ccn1 ,20 [O]C(=O)c1ccccc1-c1ccccc1C([O])=O. Metal clusters: 4 O=[C]O[Cd]O[C]O[Cd](O[C]O[Cd])(O[C]=O)O[C]=O.O=[C]O[Cd]O[C]O[Cd](O[C]O[Cd]1O[C]O1)O[C]=O. The MOF has largest included sphere 5.79 A, density 1.44 g/cm3, surface area 4097.43 m2/g, accessible volume 0.29 cm3/g