ZnH16(C13N3)2 is Indium-like structured and crystallizes in the tetragonal P4_2 space group. The structure is zero-dimensional and consists of two ZnH16(C13N3)2 clusters. Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent N(3) atoms. Both Zn(1)-N(1) bond lengths are 1.98 Å. Both Zn(1)-N(3) bond lengths are 1.98 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(5) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-C(3) bond length is 1.34 Å. The C(1)-C(5) bond length is 1.47 Å. In the second C site, C(2) is bonded in a water-like geometry to one C(1) and one C(4) atom. The C(2)-C(4) bond length is 1.35 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one H(3) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-H(3) bond length is 0.96 Å. In the fourth C site, C(4) is bonded in a 3-coordinate geometry to one C(2), one N(1), and one H(4) atom. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(4) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(7) bond length is 1.37 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(1) atom. The C(6)-H(1) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(7)-H(2) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted water-like geometry to one C(10) and one N(2) atom. The C(8)-C(10) bond length is 1.35 Å. The C(8)-N(2) bond length is 1.37 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(7) atom. The C(9)-N(2) bond length is 1.34 Å. The C(9)-N(3) bond length is 1.34 Å. The C(9)-H(7) bond length is 0.96 Å. In the tenth C site, C(10) is bonded in a 3-coordinate geometry to one C(8), one N(3), and one H(8) atom. The C(10)-N(3) bond length is 1.34 Å. The C(10)-H(8) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(13), and one N(2) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(13) bond length is 1.37 Å. The C(11)-N(2) bond length is 1.47 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(5) atom. The C(12)-H(5) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(13)-H(6) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(8), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(9) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. Linkers: 4 [C]1=C(c2ccc(-n3[c]cnc3)cc2)[CH]N=C1. Metal clusters: 2 [Zn]. The MOF has largest included sphere 4.33 A, density 1.30 g/cm3, surface area 4936.44 m2/g, accessible volume 0.23 cm3/g