CdC19N3H11O2(CH)3 is Indium-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules and eight CdC19N3H11O2 clusters. In four of the CdC19N3H11O2 clusters, Cd(1) is bonded in a 5-coordinate geometry to one N(1), one N(2), one N(3), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.34 Å. The Cd(1)-N(2) bond length is 2.41 Å. The Cd(1)-N(3) bond length is 2.39 Å. The Cd(1)-O(3) bond length is 2.56 Å. The Cd(1)-O(4) bond length is 2.27 Å. There are nineteen inequivalent C sites. In the first C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(6) atom. The C(10)-C(9) bond length is 1.34 Å. The C(10)-N(2) bond length is 1.36 Å. The C(10)-H(6) bond length is 0.93 Å. In the second C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(5), and one N(3) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(5) bond length is 1.51 Å. The C(11)-N(3) bond length is 1.36 Å. In the third C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 0.93 Å. In the fourth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(9)-H(5) bond length is 0.93 Å. In the fifth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(10) atom. The C(15)-N(3) bond length is 1.31 Å. The C(15)-H(10) bond length is 0.93 Å. In the sixth C site, C(16) is bonded in a trigonal planar geometry to one C(17), one C(21), and one C(3) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(21) bond length is 1.39 Å. The C(16)-C(3) bond length is 1.51 Å. In the seventh C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(17)-H(11) bond length is 0.93 Å. In the eighth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(14) atom. The C(21)-H(14) bond length is 0.93 Å. In the ninth C site, C(40) is bonded in a distorted single-bond geometry to one C(41) and one H(26) atom. The C(40)-C(41) bond length is 1.39 Å. The C(40)-H(26) bond length is 0.93 Å. In the tenth C site, C(41) is bonded in a trigonal planar geometry to one C(40), one C(42), and one C(44) atom. The C(41)-C(42) bond length is 1.37 Å. The C(41)-C(44) bond length is 1.53 Å. In the eleventh C site, C(42) is bonded in a distorted single-bond geometry to one C(41) and one H(27) atom. The C(42)-H(27) bond length is 0.93 Å. In the twelfth C site, C(44) is bonded in a distorted bent 120 degrees geometry to one C(41), one O(3), and one O(4) atom. The C(44)-O(3) bond length is 1.27 Å. The C(44)-O(4) bond length is 1.26 Å. In the thirteenth C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.35 Å. The C(1)-C(6) bond length is 1.50 Å. The C(1)-N(1) bond length is 1.37 Å. In the fourteenth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-H(1) bond length is 0.93 Å. In the fifteenth C site, C(3) is bonded in a trigonal planar geometry to one C(16), one C(2), and one C(4) atom. The C(3)-C(4) bond length is 1.41 Å. In the sixteenth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(2) bond length is 0.93 Å. In the seventeenth C site, C(5) is bonded in a distorted single-bond geometry to one C(11), one C(4), and one N(1) atom. The C(5)-N(1) bond length is 1.30 Å. In the eighteenth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-N(2) bond length is 1.33 Å. In the nineteenth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(7)-H(3) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one C(15) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(27) is bonded in a single-bond geometry to one C(42) atom. In the eleventh H site, H(26) is bonded in a single-bond geometry to one C(40) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Cd(1) and one C(44) atom. In the second O site, O(4) is bonded in a distorted water-like geometry to one Cd(1) and one C(44) atom. In four of the CdC19N3H11O2 clusters, Cd(2) is bonded in a distorted pentagonal planar geometry to one N(4), one N(5), one N(6), one O(1), and one O(2) atom. The Cd(2)-N(4) bond length is 2.30 Å. The Cd(2)-N(5) bond length is 2.35 Å. The Cd(2)-N(6) bond length is 2.31 Å. The Cd(2)-O(1) bond length is 2.45 Å. The Cd(2)-O(2) bond length is 2.33 Å. There are nineteen inequivalent C sites. In the first C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(12) atom. The C(18)-C(19) bond length is 1.38 Å. The C(18)-H(12) bond length is 0.93 Å. In the second C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(22) atom. The C(19)-C(20) bond length is 1.35 Å. The C(19)-C(22) bond length is 1.51 Å. In the third C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(13) atom. The C(20)-H(13) bond length is 0.93 Å. In the fourth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(1), and one O(2) atom. The C(22)-O(1) bond length is 1.24 Å. The C(22)-O(2) bond length is 1.30 Å. In the fifth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(24), one C(28), and one N(4) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(28) bond length is 1.47 Å. The C(23)-N(4) bond length is 1.37 Å. In the sixth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(15) atom. The C(24)-C(25) bond length is 1.35 Å. The C(24)-H(15) bond length is 0.93 Å. In the seventh C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(38) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-C(38) bond length is 1.53 Å. In the eighth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(16) atom. The C(26)-H(16) bond length is 0.93 Å. In the ninth C site, C(27) is bonded in a distorted single-bond geometry to one C(33) and one N(4) atom. The C(27)-C(33) bond length is 1.51 Å. The C(27)-N(4) bond length is 1.30 Å. In the tenth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(23), one C(29), and one N(5) atom. The C(28)-C(29) bond length is 1.38 Å. The C(28)-N(5) bond length is 1.34 Å. In the eleventh C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(17) atom. The C(29)-H(17) bond length is 0.93 Å. In the twelfth C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(19) atom. The C(31)-C(32) bond length is 1.37 Å. The C(31)-H(19) bond length is 0.93 Å. In the thirteenth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31), one N(5), and one H(20) atom. The C(32)-N(5) bond length is 1.36 Å. The C(32)-H(20) bond length is 0.93 Å. In the fourteenth C site, C(33) is bonded in a distorted trigonal planar geometry to one C(27), one C(34), and one N(6) atom. The C(33)-C(34) bond length is 1.39 Å. The C(33)-N(6) bond length is 1.31 Å. In the fifteenth C site, C(34) is bonded in a distorted single-bond geometry to one C(33) and one H(21) atom. The C(34)-H(21) bond length is 0.93 Å. In the sixteenth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(24) atom. The C(37)-N(6) bond length is 1.37 Å. The C(37)-H(24) bond length is 0.93 Å. In the seventeenth C site, C(38) is bonded in a trigonal planar geometry to one C(25), one C(39), and one C(43) atom. The C(38)-C(39) bond length is 1.37 Å. The C(38)-C(43) bond length is 1.39 Å. In the eighteenth C site, C(43) is bonded in a distorted single-bond geometry to one C(38) and one H(28) atom. The C(43)-H(28) bond length is 0.93 Å. In the nineteenth C site, C(39) is bonded in a distorted single-bond geometry to one C(38) and one H(25) atom. The C(39)-H(25) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Cd(2), one C(23), and one C(27) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Cd(2), one C(28), and one C(32) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Cd(2), one C(33), and one C(37) atom. There are eleven inequivalent H sites. In the first H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the second H site, H(15) is bonded in a single-bond geometry to one C(24) atom. In the third H site, H(20) is bonded in a single-bond geometry to one C(32) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(29) atom. In the fifth H site, H(19) is bonded in a single-bond geometry to one C(31) atom. In the sixth H site, H(24) is bonded in a single-bond geometry to one C(37) atom. In the seventh H site, H(21) is bonded in a single-bond geometry to one C(34) atom. In the eighth H site, H(25) is bonded in a single-bond geometry to one C(39) atom. In the ninth H site, H(28) is bonded in a single-bond geometry to one C(43) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(26) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(2) and one C(22) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(22) atom. Linkers: 8 [O]C(=O)c1ccc(-c2cc(-c3ccccn3)nc(-c3ccccn3)c2)cc1. Metal clusters: 4 O=[C]O[Cd] ,4 [C]1O[Cd]O1. The MOF has largest included sphere 4.41 A, density 1.37 g/cm3, surface area 3956.04 m2/g, accessible volume 0.31 cm3/g