Cu8C63H24(NO9)4(CH2)8 crystallizes in the tetragonal P4_12_12 space group. The structure consists of thirty-two 02329_fluka molecules inside a Cu8C63H24(NO9)4 framework. In the Cu8C63H24(NO9)4 framework, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square pyramidal geometry to one O(3), one O(4), one O(5), one O(6), and one O(8) atom. The Cu(1)-O(3) bond length is 2.01 Å. The Cu(1)-O(4) bond length is 1.92 Å. The Cu(1)-O(5) bond length is 1.95 Å. The Cu(1)-O(6) bond length is 1.97 Å. The Cu(1)-O(8) bond length is 2.14 Å. In the second Cu site, Cu(2) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(7), and one O(9) atom. The Cu(2)-O(1) bond length is 1.98 Å. The Cu(2)-O(2) bond length is 1.94 Å. The Cu(2)-O(7) bond length is 1.94 Å. The Cu(2)-O(9) bond length is 2.01 Å. In the third Cu site, Cu(3) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(15), one O(16), and one O(17) atom. The Cu(3)-O(11) bond length is 1.94 Å. The Cu(3)-O(15) bond length is 1.97 Å. The Cu(3)-O(16) bond length is 1.91 Å. The Cu(3)-O(17) bond length is 2.04 Å. In the fourth Cu site, Cu(4) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(13), one O(14), and one O(18) atom. The Cu(4)-O(10) bond length is 1.98 Å. The Cu(4)-O(13) bond length is 2.07 Å. The Cu(4)-O(14) bond length is 1.92 Å. The Cu(4)-O(18) bond length is 1.88 Å. There are thirty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(7) atom. The C(1)-C(10) bond length is 1.49 Å. The C(1)-O(3) bond length is 1.25 Å. The C(1)-O(7) bond length is 1.29 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(1), and one O(5) atom. The C(2)-C(13) bond length is 1.50 Å. The C(2)-O(1) bond length is 1.28 Å. The C(2)-O(5) bond length is 1.24 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(10), one C(6), and one H(1) atom. The C(3)-C(10) bond length is 1.38 Å. The C(3)-C(6) bond length is 1.40 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a single-bond geometry to one C(12), one C(13), and one H(2) atom. The C(4)-C(12) bond length is 1.40 Å. The C(4)-C(13) bond length is 1.38 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a bent 120 degrees geometry to one C(18), one O(10), and one O(11) atom. The C(5)-C(18) bond length is 1.50 Å. The C(5)-O(10) bond length is 1.25 Å. The C(5)-O(11) bond length is 1.23 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(3), one C(8), and one C(9) atom. The C(6)-C(8) bond length is 1.50 Å. The C(6)-C(9) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(14), and one O(15) atom. The C(7)-C(21) bond length is 1.53 Å. The C(7)-O(14) bond length is 1.24 Å. The C(7)-O(15) bond length is 1.23 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one O(8) atom. The C(8)-N(1) bond length is 1.33 Å. The C(8)-O(8) bond length is 1.25 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(21), one C(6), and one H(3) atom. The C(9)-C(21) bond length is 1.39 Å. The C(9)-H(3) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(1), one C(17), and one C(3) atom. The C(10)-C(17) bond length is 1.38 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(9) atom. The C(11)-O(4) bond length is 1.26 Å. The C(11)-O(9) bond length is 1.28 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(16), one C(19), and one C(4) atom. The C(12)-C(16) bond length is 1.53 Å. The C(12)-C(19) bond length is 1.38 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(4) atom. The C(13)-C(14) bond length is 1.41 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(18), and one H(4) atom. The C(14)-C(18) bond length is 1.38 Å. The C(14)-H(4) bond length is 0.93 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(6) atom. The C(15)-O(2) bond length is 1.24 Å. The C(15)-O(6) bond length is 1.26 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(2), and one O(12) atom. The C(16)-N(2) bond length is 1.29 Å. The C(16)-O(12) bond length is 1.23 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(10), one C(21), and one H(5) atom. The C(17)-C(21) bond length is 1.38 Å. The C(17)-H(5) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(14), one C(19), and one C(5) atom. The C(18)-C(19) bond length is 1.41 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(12), one C(18), and one H(6) atom. The C(19)-H(6) bond length is 0.93 Å. In the twentieth C site, C(20) is bonded in a 2-coordinate geometry to one N(2) and one H(7) atom. The C(20)-N(2) bond length is 1.49 Å. The C(20)-H(7) bond length is 0.98 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(17), one C(7), and one C(9) atom. In the twenty-second C site, C(23) is bonded in a 2-coordinate geometry to one N(1) and one H(10) atom. The C(23)-N(1) bond length is 1.47 Å. The C(23)-H(10) bond length is 0.98 Å. In the twenty-third C site, C(24) is bonded in a 3-coordinate geometry to one N(1) and two equivalent H(11,12) atoms. The C(24)-N(1) bond length is 1.46 Å. Both C(24)-H(11,12) bond lengths are 0.97 Å. In the twenty-fourth C site, C(25) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent H(13,14) atoms. The C(25)-N(2) bond length is 1.48 Å. Both C(25)-H(13,14) bond lengths are 0.97 Å. In the twenty-fifth C site, C(36) is bonded in a distorted rectangular see-saw-like geometry to two equivalent C(34) and two equivalent C(35) atoms. Both C(36)-C(34) bond lengths are 1.18 Å. Both C(36)-C(35) bond lengths are 1.37 Å. In the twenty-sixth C site, C(27) is bonded in a bent 120 degrees geometry to one C(29) and one C(32) atom. The C(27)-C(29) bond length is 1.17 Å. The C(27)-C(32) bond length is 1.48 Å. In the twenty-seventh C site, C(29) is bonded in a trigonal planar geometry to one C(27), one C(31), and one C(35) atom. The C(29)-C(31) bond length is 1.76 Å. The C(29)-C(35) bond length is 1.42 Å. In the twenty-eighth C site, C(31) is bonded in a distorted bent 150 degrees geometry to one C(29), one O(17), and one O(18) atom. The C(31)-O(17) bond length is 1.08 Å. The C(31)-O(18) bond length is 1.31 Å. In the twenty-ninth C site, C(32) is bonded in a trigonal planar geometry to one C(27), one C(33), and one C(34) atom. The C(32)-C(33) bond length is 1.54 Å. The C(32)-C(34) bond length is 1.37 Å. In the thirtieth C site, C(33) is bonded in a distorted bent 150 degrees geometry to one C(32), one O(13), and one O(16) atom. The C(33)-O(13) bond length is 1.29 Å. The C(33)-O(16) bond length is 1.27 Å. In the thirty-first C site, C(34) is bonded in a 3-coordinate geometry to one C(32), one C(34), and one C(36) atom. The C(34)-C(34) bond length is 1.25 Å. In the thirty-second C site, C(35) is bonded in a 3-coordinate geometry to one C(29), one C(35), and one C(36) atom. The C(35)-C(35) bond length is 1.38 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(23), one C(24), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(25) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(11,12) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(13,14) is bonded in a single-bond geometry to one C(25) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(2) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(15) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(11) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(15) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(1) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(8) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(11) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(5) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one C(5) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Cu(4) and one C(33) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one C(7) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one C(7) atom. In the sixteenth O site, O(16) is bonded in a water-like geometry to one Cu(3) and one C(33) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Cu(3) and one C(31) atom. In the eighteenth O site, O(18) is bonded in a water-like geometry to one Cu(4) and one C(31) atom. Linkers: 4 [O]C(=O)[C]1[C]=C(C([O])=O)[C]2[C]3C(C([O])=O)=[C][C](C([O])=O)[C]4[C]1C423 ,16 [O]C(=O)c1cc(C([O])=O)cc(C(=O)N2CCC[C@H]2C([O])=O)c1. Metal clusters: 8 [O][Cu]1234O[C]O[Cu]1(O[C]O2)(O[C]O3)O[C]O4 ,8 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 7.27 A, density 1.24 g/cm3, surface area 3494.52 m2/g, accessible volume 0.44 cm3/g