CoC10NH6O4(C5H3)2C3H2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of eight 1,3,5-triisopropenyl benzene molecules; six 2,3-dimethyl-1,3-butadiene molecules; and six CoC10NH6O4 clusters. In each CoC10NH6O4 cluster, Co(1,2,3,4,5,6,7,8,10,12) is bonded in a square pyramidal geometry to one N(1,2,3,4,5,6,7,8,9,10,11,12); two equivalent O(1,2,3,4,5,6,7,8,9,10,11,12,37,38,39,40,41,42,43,44,45,46,47,48); and two equivalent O(13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36) atoms. The Co(1,2,3,4,5,6,7,8,10,12)-N(1,2,3,4,5,6,7,8,9,10,11,12) bond length is 2.03 Å. Both Co(1,2,3,4,5,6,7,8,10,12)-O(1,2,3,4,5,6,7,8,9,10,11,12,37,38,39,40,41,42,43,44,45,46,47,48) bond lengths are 1.83 Å. Both Co(1,2,3,4,5,6,7,8,10,12)-O(13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36) bond lengths are 1.83 Å. There are eight inequivalent C sites. In the first C site, C(157,169,173,201,209,241,249) is bonded in a bent 120 degrees geometry to one C(158,162,166,170,174,178,182,186,190,194,198,202,206,210,214,218,222,226,230,234,238,242,246,250); one O(1,2,3,4,5,6,7,8,9,10,11,12,37,38,39,40,41,42,43,44,45,46,47,48); and one O(13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36) atom. The C(157,169,173,201,209,241,249)-C(158,162,166,170,174,178,182,186,190,194,198,202,206,210,214,218,222,226,230,234,238,242,246,250) bond length is 1.50 Å. The C(157,169,173,201,209,241,249)-O(1,2,3,4,5,6,7,8,9,10,11,12,37,38,39,40,41,42,43,44,45,46,47,48) bond length is 1.29 Å. The C(157,169,173,201,209,241,249)-O(13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36) bond length is 1.29 Å. In the second C site, C(158,162,166,170,174,178,182,186,190,194,198,202,206,210,214,218,222,226,230,234,238,242,246,250) is bonded in a trigonal planar geometry to one C(1,9,13,27,109,121,129); one C(157,169,173,201,209,241,249); and one C(31,37,41,61,67,97,105) atom. The C(158,162,166,170,174,178,182,186,190,194,198,202,206,210,214,218,222,226,230,234,238,242,246,250)-C(1,9,13,27,109,121,129) bond length is 1.41 Å. The C(158,162,166,170,174,178,182,186,190,194,198,202,206,210,214,218,222,226,230,234,238,242,246,250)-C(31,37,41,61,67,97,105) bond length is 1.41 Å. In the third C site, C(29,33,43,45,49,53,55,57,65,69,73,77,81,85,89,93,101) is bonded in a distorted single-bond geometry to one C(158,162,166,170,174,178,182,186,190,194,198,202,206,210,214,218,222,226,230,234,238,242,246,250) and one H(1,3,5,9,13,15,17,19,21,23,25,27,29,31,33,37,41,43,45,49,53,55,57,61,65,67,69,73,77,81,85,89,93,97,101,105,109,111,113,117,121,123,125,129,133,135,137,141) atom. The C(29,33,43,45,49,53,55,57,65,69,73,77,81,85,89,93,101)-C(158,162,166,170,174,178,182,186,190,194,198,202,206,210,214,218,222,226,230,234,238,242,246,250) bond length is 1.41 Å. The C(29,33,43,45,49,53,55,57,65,69,73,77,81,85,89,93,101)-H(1,3,5,9,13,15,17,19,21,23,25,27,29,31,33,37,41,43,45,49,53,55,57,61,65,67,69,73,77,81,85,89,93,97,101,105,109,111,113,117,121,123,125,129,133,135,137,141) bond length is 1.08 Å. In the fourth C site, C(161,165,177,181,185,189,193,197,205,213,217,221,225,229,233,237,245) is bonded in a bent 120 degrees geometry to one C(158,162,166,170,174,178,182,186,190,194,198,202,206,210,214,218,222,226,230,234,238,242,246,250); one O(1,2,3,4,5,6,7,8,9,10,11,12,37,38,39,40,41,42,43,44,45,46,47,48); and one O(13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36) atom. The C(161,165,177,181,185,189,193,197,205,213,217,221,225,229,233,237,245)-C(158,162,166,170,174,178,182,186,190,194,198,202,206,210,214,218,222,226,230,234,238,242,246,250) bond length is 1.50 Å. The C(161,165,177,181,185,189,193,197,205,213,217,221,225,229,233,237,245)-O(1,2,3,4,5,6,7,8,9,10,11,12,37,38,39,40,41,42,43,44,45,46,47,48) bond length is 1.29 Å. The C(161,165,177,181,185,189,193,197,205,213,217,221,225,229,233,237,245)-O(13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36) bond length is 1.29 Å. In the fifth C site, C(1,9,13,27,109,121,129) is bonded in a distorted single-bond geometry to one C(158,162,166,170,174,178,182,186,190,194,198,202,206,210,214,218,222,226,230,234,238,242,246,250) and one H(1,3,5,9,13,15,17,19,21,23,25,27,29,31,33,37,41,43,45,49,53,55,57,61,65,67,69,73,77,81,85,89,93,97,101,105,109,111,113,117,121,123,125,129,133,135,137,141) atom. The C(1,9,13,27,109,121,129)-H(1,3,5,9,13,15,17,19,21,23,25,27,29,31,33,37,41,43,45,49,53,55,57,61,65,67,69,73,77,81,85,89,93,97,101,105,109,111,113,117,121,123,125,129,133,135,137,141) bond length is 1.08 Å. In the sixth C site, C(3,5,15,17,19,21,23,25,111,113,117,123,125,133,135,137,141) is bonded in a distorted single-bond geometry to one C(158,162,166,170,174,178,182,186,190,194,198,202,206,210,214,218,222,226,230,234,238,242,246,250) and one H(1,3,5,9,13,15,17,19,21,23,25,27,29,31,33,37,41,43,45,49,53,55,57,61,65,67,69,73,77,81,85,89,93,97,101,105,109,111,113,117,121,123,125,129,133,135,137,141) atom. The C(3,5,15,17,19,21,23,25,111,113,117,123,125,133,135,137,141)-C(158,162,166,170,174,178,182,186,190,194,198,202,206,210,214,218,222,226,230,234,238,242,246,250) bond length is 1.41 Å. The C(3,5,15,17,19,21,23,25,111,113,117,123,125,133,135,137,141)-H(1,3,5,9,13,15,17,19,21,23,25,27,29,31,33,37,41,43,45,49,53,55,57,61,65,67,69,73,77,81,85,89,93,97,101,105,109,111,113,117,121,123,125,129,133,135,137,141) bond length is 1.08 Å. In the seventh C site, C(31,37,41,61,67,97,105) is bonded in a distorted single-bond geometry to one C(158,162,166,170,174,178,182,186,190,194,198,202,206,210,214,218,222,226,230,234,238,242,246,250) and one H(1,3,5,9,13,15,17,19,21,23,25,27,29,31,33,37,41,43,45,49,53,55,57,61,65,67,69,73,77,81,85,89,93,97,101,105,109,111,113,117,121,123,125,129,133,135,137,141) atom. The C(31,37,41,61,67,97,105)-H(1,3,5,9,13,15,17,19,21,23,25,27,29,31,33,37,41,43,45,49,53,55,57,61,65,67,69,73,77,81,85,89,93,97,101,105,109,111,113,117,121,123,125,129,133,135,137,141) bond length is 1.08 Å. In the eighth C site, C(7,11,35,39,47,51,59,63,71,75,79,83,87,91,95,99,103,107,115,119,127,131,139,143) is bonded in a distorted bent 120 degrees geometry to one N(1,2,3,4,5,6,7,8,9,10,11,12) and one H(7,11,35,39,47,51,59,63,71,75,79,83,87,91,95,99,103,107,115,119,127,131,139,143) atom. The C(7,11,35,39,47,51,59,63,71,75,79,83,87,91,95,99,103,107,115,119,127,131,139,143)-N(1,2,3,4,5,6,7,8,9,10,11,12) bond length is 1.37 Å. The C(7,11,35,39,47,51,59,63,71,75,79,83,87,91,95,99,103,107,115,119,127,131,139,143)-H(7,11,35,39,47,51,59,63,71,75,79,83,87,91,95,99,103,107,115,119,127,131,139,143) bond length is 1.08 Å. N(1,2,3,4,5,6,7,8,9,10,11,12) is bonded in a trigonal planar geometry to one Co(1,2,3,4,5,6,7,8,10,12) and two equivalent C(7,11,35,39,47,51,59,63,71,75,79,83,87,91,95,99,103,107,115,119,127,131,139,143) atoms. There are two inequivalent H sites. In the first H site, H(1,3,5,9,13,15,17,19,21,23,25,27,29,31,33,37,41,43,45,49,53,55,57,61,65,67,69,73,77,81,85,89,93,97,101,105,109,111,113,117,121,123,125,129,133,135,137,141) is bonded in a single-bond geometry to one C(1,9,13,27,109,121,129) atom. In the second H site, H(7,11,35,39,47,51,59,63,71,75,79,83,87,91,95,99,103,107,115,119,127,131,139,143) is bonded in a single-bond geometry to one C(7,11,35,39,47,51,59,63,71,75,79,83,87,91,95,99,103,107,115,119,127,131,139,143) atom. There are two inequivalent O sites. In the first O site, O(13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36) is bonded in a bent 120 degrees geometry to one Co(1,2,3,4,5,6,7,8,10,12) and one C(161,165,177,181,185,189,193,197,205,213,217,221,225,229,233,237,245) atom. In the second O site, O(1,2,3,4,5,6,7,8,9,10,11,12,37,38,39,40,41,42,43,44,45,46,47,48) is bonded in a bent 120 degrees geometry to one Co(1,2,3,4,5,6,7,8,10,12) and one C(157,169,173,201,209,241,249) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1 ,8 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C([O])=O)cc3)c2)cc1. Metal clusters: 8 [Co] ,2 [C]1O[Co]234O[C]O[Co]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 20.26 A, density 0.40 g/cm3, surface area 4676.16 m2/g, accessible volume 1.91 cm3/g