Zn2C20N3H11O7(CH)10 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of forty 02329_fluka molecules and two Zn2C20N3H11O7 clusters. In each Zn2C20N3H11O7 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(3), and two equivalent O(7) atoms. The Zn(1)-O(1) bond length is 2.05 Å. The Zn(1)-O(3) bond length is 2.09 Å. There is one shorter (2.05 Å) and one longer (2.15 Å) Zn(1)-O(7) bond length. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one O(2), one O(4), one O(5), and one O(7) atom. The Zn(2)-O(2) bond length is 2.00 Å. The Zn(2)-O(4) bond length is 1.96 Å. The Zn(2)-O(5) bond length is 1.94 Å. The Zn(2)-O(7) bond length is 1.96 Å. There are twenty inequivalent C sites. In the first C site, C(6) is bonded in a distorted single-bond geometry to one N(1) atom. The C(6)-N(1) bond length is 1.39 Å. In the second C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one N(1) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-N(1) bond length is 1.41 Å. In the third C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(7), and one C(9) atom. The C(8)-C(13) bond length is 1.55 Å. The C(8)-C(9) bond length is 1.38 Å. In the fourth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(9) atom. The C(9)-H(9) bond length is 0.93 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one N(2) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-N(2) bond length is 1.40 Å. In the sixth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-C(14) bond length is 1.49 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(10) atom. The C(12)-H(10) bond length is 0.93 Å. In the eighth C site, C(13) is bonded in a bent 120 degrees geometry to one C(8), one O(3), and one O(4) atom. The C(13)-O(3) bond length is 1.23 Å. The C(13)-O(4) bond length is 1.26 Å. In the ninth C site, C(14) is bonded in a bent 120 degrees geometry to one C(11), one O(1), and one O(2) atom. The C(14)-O(1) bond length is 1.25 Å. The C(14)-O(2) bond length is 1.26 Å. In the tenth C site, C(15) is bonded in a distorted single-bond geometry to one N(2) atom. The C(15)-N(2) bond length is 1.40 Å. In the eleventh C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(5), and one O(6) atom. The C(21)-C(22) bond length is 1.46 Å. The C(21)-O(5) bond length is 1.31 Å. The C(21)-O(6) bond length is 1.22 Å. In the twelfth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(24) atom. The C(22)-C(23) bond length is 1.38 Å. The C(22)-C(24) bond length is 1.42 Å. In the thirteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(16) atom. The C(23)-H(16) bond length is 0.93 Å. In the fourteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(22) and one N(3) atom. The C(24)-N(3) bond length is 1.38 Å. In the fifteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one C(30), and one N(3) atom. The C(25)-C(26) bond length is 1.41 Å. The C(25)-C(30) bond length is 1.37 Å. The C(25)-N(3) bond length is 1.41 Å. In the sixteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(25), one C(28), and one H(17) atom. The C(26)-C(28) bond length is 1.45 Å. The C(26)-H(17) bond length is 0.93 Å. In the seventeenth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(28), one C(29), and one H(18) atom. The C(27)-C(28) bond length is 1.49 Å. The C(27)-C(29) bond length is 1.29 Å. The C(27)-H(18) bond length is 0.93 Å. In the eighteenth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(26), one C(27), and one H(19) atom. The C(28)-H(19) bond length is 0.93 Å. In the nineteenth C site, C(29) is bonded in a distorted single-bond geometry to one C(27) and one H(20) atom. The C(29)-H(20) bond length is 0.93 Å. In the twentieth C site, C(30) is bonded in a distorted single-bond geometry to one C(25) and one H(21) atom. The C(30)-H(21) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(6), one C(7), and one H(1) atom. The N(1)-H(1) bond length is 0.86 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(15), and one H(2) atom. The N(2)-H(2) bond length is 0.86 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(24), one C(25), and one H(3) atom. The N(3)-H(3) bond length is 0.86 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(28) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(29) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(30) atom. There are seven inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(13) atom. In the second O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(14) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(21) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(21) atom. In the fifth O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(14) atom. In the sixth O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Zn(2) and two equivalent Zn(1) atoms. In the seventh O site, O(3) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(13) atom. Linkers: 7 [O]C(=O)c1cc(Nc2ccccc2)c(C([O])=O)cc1Nc1ccccc1. Metal clusters: 2 O=[C]O[Zn@]12O[C]O[Zn](O[C]O1)O[Zn@@]1(O[C]=O)O[C]O[Zn](O[C]O1)O2. RCSR code: pcu. The MOF has largest included sphere 8.32 A, density 0.87 g/cm3, surface area 4587.05 m2/g, accessible volume 0.74 cm3/g