MnInC31H17O9C5H2 is Indium-derived structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of six 1,3,5-triisopropenyl benzene molecules and nine MnInC31H17O9 clusters. In each MnInC31H17O9 cluster, Mn(1) is bonded to one O(1), one O(2), one O(8), and two equivalent O(7) atoms to form edge-sharing MnO5 trigonal bipyramids. The Mn(1)-O(1) bond length is 2.13 Å. The Mn(1)-O(2) bond length is 2.13 Å. The Mn(1)-O(8) bond length is 2.24 Å. There is one shorter (2.17 Å) and one longer (2.19 Å) Mn(1)-O(7) bond length. In(1) is bonded in a 6-coordinate geometry to one O(3), one O(4), one O(5), one O(6), one O(7), and one O(9) atom. The In(1)-O(3) bond length is 2.26 Å. The In(1)-O(4) bond length is 2.31 Å. The In(1)-O(5) bond length is 2.14 Å. The In(1)-O(6) bond length is 2.13 Å. The In(1)-O(7) bond length is 2.14 Å. The In(1)-O(9) bond length is 2.14 Å. There are thirty-one inequivalent C sites. In the first C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(8)-C(9) bond length is 1.38 Å. The C(8)-H(6) bond length is 0.93 Å. In the second C site, C(10) is bonded in a trigonal planar geometry to one C(14), one C(4), and one C(9) atom. The C(10)-C(14) bond length is 1.40 Å. The C(10)-C(4) bond length is 1.38 Å. The C(10)-C(9) bond length is 1.50 Å. In the third C site, C(19) is bonded in a distorted single-bond geometry to one C(20) and one H(11) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-H(11) bond length is 0.93 Å. In the fourth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(5) atom. The C(20)-C(21) bond length is 1.50 Å. The C(20)-C(5) bond length is 1.38 Å. In the fifth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(2), and one O(5) atom. The C(21)-O(2) bond length is 1.25 Å. The C(21)-O(5) bond length is 1.26 Å. In the sixth C site, C(14) is bonded in a single-bond geometry to one C(10), one C(16), and one H(9) atom. The C(14)-C(16) bond length is 1.39 Å. The C(14)-H(9) bond length is 0.93 Å. In the seventh C site, C(15) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(17) atom. The C(15)-C(12) bond length is 1.40 Å. The C(15)-C(16) bond length is 1.50 Å. The C(15)-C(17) bond length is 1.39 Å. In the eighth C site, C(16) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(6) atom. The C(16)-C(6) bond length is 1.38 Å. In the ninth C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one H(10) atom. The C(17)-H(10) bond length is 0.93 Å. In the tenth C site, C(7) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(6) atom. The C(7)-C(3) bond length is 1.50 Å. The C(7)-C(4) bond length is 1.40 Å. The C(7)-C(6) bond length is 1.38 Å. In the eleventh C site, C(22) is bonded in a distorted single-bond geometry to one C(27) and one H(12) atom. The C(22)-C(27) bond length is 1.40 Å. The C(22)-H(12) bond length is 0.93 Å. In the twelfth C site, C(24) is bonded in a distorted single-bond geometry to one C(27) and one H(13) atom. The C(24)-C(27) bond length is 1.40 Å. The C(24)-H(13) bond length is 0.93 Å. In the thirteenth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(32), and one C(8) atom. The C(9)-C(32) bond length is 1.38 Å. In the fourteenth C site, C(27) is bonded in a trigonal planar geometry to one C(18), one C(22), and one C(24) atom. The C(27)-C(18) bond length is 1.51 Å. In the fifteenth C site, C(29) is bonded in a trigonal planar geometry to one C(13), one C(30), and one C(34) atom. The C(29)-C(13) bond length is 1.51 Å. The C(29)-C(30) bond length is 1.37 Å. The C(29)-C(34) bond length is 1.40 Å. In the sixteenth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(14) atom. The C(30)-H(14) bond length is 0.93 Å. In the seventeenth C site, C(34) is bonded in a distorted single-bond geometry to one C(2), one C(29), and one H(18) atom. The C(34)-C(2) bond length is 1.39 Å. The C(34)-H(18) bond length is 0.93 Å. In the eighteenth C site, C(35) is bonded in a distorted single-bond geometry to one C(28) and one H(19) atom. The C(35)-C(28) bond length is 1.33 Å. The C(35)-H(19) bond length is 0.93 Å. In the nineteenth C site, C(33) is bonded in a distorted single-bond geometry to one C(3) and one H(17) atom. The C(33)-C(3) bond length is 1.40 Å. The C(33)-H(17) bond length is 0.93 Å. In the twentieth C site, C(28) is bonded in a trigonal planar geometry to one C(31), one C(35), and one C(36) atom. The C(28)-C(31) bond length is 1.37 Å. The C(28)-C(36) bond length is 1.54 Å. In the twenty-first C site, C(31) is bonded in a distorted single-bond geometry to one C(28) and one H(15) atom. The C(31)-H(15) bond length is 0.93 Å. In the twenty-second C site, C(36) is bonded in a bent 120 degrees geometry to one C(28), one O(8), and one O(9) atom. The C(36)-O(8) bond length is 1.25 Å. The C(36)-O(9) bond length is 1.19 Å. In the twenty-third C site, C(32) is bonded in a distorted single-bond geometry to one C(9) and one H(16) atom. The C(32)-H(16) bond length is 0.93 Å. In the twenty-fourth C site, C(12) is bonded in a single-bond geometry to one C(15) and one H(8) atom. The C(12)-H(8) bond length is 0.93 Å. In the twenty-fifth C site, C(13) is bonded in a bent 120 degrees geometry to one C(29), one O(3), and one O(4) atom. The C(13)-O(3) bond length is 1.26 Å. The C(13)-O(4) bond length is 1.24 Å. In the twenty-sixth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(1), and one O(6) atom. The C(18)-O(1) bond length is 1.25 Å. The C(18)-O(6) bond length is 1.25 Å. In the twenty-seventh C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(34), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-H(2) bond length is 0.93 Å. In the twenty-eighth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(33), and one C(7) atom. In the twenty-ninth C site, C(4) is bonded in a distorted single-bond geometry to one C(10), one C(7), and one H(3) atom. The C(4)-H(3) bond length is 0.93 Å. In the thirtieth C site, C(5) is bonded in a distorted single-bond geometry to one C(20) and one H(4) atom. The C(5)-H(4) bond length is 0.93 Å. In the thirty-first C site, C(6) is bonded in a single-bond geometry to one C(16), one C(7), and one H(5) atom. The C(6)-H(5) bond length is 0.93 Å. There are seventeen inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(30) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(31) atom. In the thirteenth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(33) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(34) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(35) atom. In the seventeenth H site, H(16) is bonded in a single-bond geometry to one C(32) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(18) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(21) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one In(1) and one C(13) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one In(1) and one C(13) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one In(1) and one C(21) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one In(1) and one C(18) atom. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to two equivalent Mn(1) and one In(1) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Mn(1) and one C(36) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one In(1) and one C(36) atom. Linkers: 6 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C([O])=O)cc3)c2)cc1 ,2 [O]C(=O)c1ccc(-c2[c]c(-c3ccc(C([O])=O)cc3)[c]c(-c3ccc(C([O])=O)cc3)[c]2)cc1. Metal clusters: 3 O=[C]O[Mn@]12O[C]O[In](O[C]O[Mn@@]3(O[C]=O)O[C]O[In](O[C]O1)O3)O2.[O][C]=O.[O][C]=O. RCSR code: the. The MOF has largest included sphere 15.02 A, density 0.82 g/cm3, surface area 4078.80 m2/g, accessible volume 0.79 cm3/g