CuC10NH6O4(C5H3)2C3H2 is Indium-derived structured and crystallizes in the cubic Pm-3n space group. The structure is zero-dimensional and consists of eight 1,3,5-triisopropenyl benzene molecules; six 2,3-dimethyl-2-butene molecules; and six CuC10NH6O4 clusters. In each CuC10NH6O4 cluster, Cu(1) is bonded in a square pyramidal geometry to one N(1) and four equivalent O(1) atoms. The Cu(1)-N(1) bond length is 2.13 Å. All Cu(1)-O(1) bond lengths are 1.97 Å. There are four inequivalent C sites. In the first C site, C(4) is bonded in a bent 120 degrees geometry to one C(5) and two equivalent O(1) atoms. The C(4)-C(5) bond length is 1.50 Å. Both C(4)-O(1) bond lengths are 1.26 Å. In the second C site, C(5) is bonded in a trigonal planar geometry to one C(4) and two equivalent C(1) atoms. Both C(5)-C(1) bond lengths are 1.40 Å. In the third C site, C(1) is bonded in a distorted single-bond geometry to one C(5) and one H(1) atom. The C(1)-H(1) bond length is 0.93 Å. In the fourth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(9)-N(1) bond length is 1.33 Å. The C(9)-H(4) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1) and two equivalent C(9) atoms. There are two inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(1) atom. O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(4) atom. Linkers: 6 c1cc(-c2ccncc2)ccn1 ,8 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C([O])=O)cc3)c2)cc1. Metal clusters: 6 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 20.30 A, density 0.41 g/cm3, surface area 4568.09 m2/g, accessible volume 1.96 cm3/g