ZnC24(NO2)4 is Indium-like structured and crystallizes in the tetragonal I4_1/acd space group. The structure is zero-dimensional and consists of eight ZnC24(NO2)4 clusters. Zn(1) is bonded in a 4-coordinate geometry to four equivalent O(1) atoms. All Zn(1)-O(1) bond lengths are 2.05 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.23 Å. In the second C site, C(2) is bonded in a water-like geometry to one C(1) and one C(3) atom. The C(2)-C(3) bond length is 1.52 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one N(1) atom. The C(3)-N(1) bond length is 1.53 Å. In the fourth C site, C(4) is bonded in a single-bond geometry to one N(1) atom. The C(4)-N(1) bond length is 1.51 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one N(1) atom. The C(5)-N(1) bond length is 1.48 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one N(1) atom. The C(6)-N(1) bond length is 1.48 Å. N(1) is bonded in a tetrahedral geometry to one C(3), one C(4), one C(5), and one C(6) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Linkers: 16 [O]C(=O)[C][C][N@]12[C][C][N@]([C][C]1)([C][C]2)[C][C]C(=O)[O]. Metal clusters: 8 O=[C]O[Zn](O[C]=O)(O[C]=O)O[C]=O. RCSR code: dia. The MOF has largest included sphere 5.10 A, density 1.21 g/cm3, surface area 4849.20 m2/g, accessible volume 0.29 cm3/g