KNa5Sm6W30MnP5H14(C7O59)2 crystallizes in the orthorhombic P2_12_12_1 space group. K(1) is bonded in a 2-coordinate geometry to one O(116) and one O(118) atom. The K(1)-O(116) bond length is 2.26 Å. The K(1)-O(118) bond length is 2.95 Å. There are five inequivalent Na sites. In the first Na site, Na(1) is bonded in a distorted single-bond geometry to one Na(5) atom. The Na(1)-Na(5) bond length is 0.68 Å. In the second Na site, Na(2) is bonded in a 4-coordinate geometry to one O(13), one O(14), one O(16), and one O(3) atom. The Na(2)-O(13) bond length is 2.36 Å. The Na(2)-O(14) bond length is 2.36 Å. The Na(2)-O(16) bond length is 2.30 Å. The Na(2)-O(3) bond length is 2.64 Å. In the third Na site, Na(3) is bonded in a distorted single-bond geometry to one O(59) atom. The Na(3)-O(59) bond length is 2.93 Å. In the fourth Na site, Na(4) is bonded in a distorted single-bond geometry to one O(18) atom. The Na(4)-O(18) bond length is 2.61 Å. In the fifth Na site, Na(5) is bonded in a distorted single-bond geometry to one Na(1), one O(32), one O(50), and one O(88) atom. The Na(5)-O(32) bond length is 2.78 Å. The Na(5)-O(50) bond length is 2.78 Å. The Na(5)-O(88) bond length is 2.65 Å. There are six inequivalent Sm sites. In the first Sm site, Sm(1) is bonded in a 7-coordinate geometry to one O(1), one O(18), one O(19), one O(20), one O(21), one O(63), and one O(66) atom. The Sm(1)-O(1) bond length is 2.36 Å. The Sm(1)-O(18) bond length is 2.62 Å. The Sm(1)-O(19) bond length is 2.44 Å. The Sm(1)-O(20) bond length is 2.61 Å. The Sm(1)-O(21) bond length is 2.70 Å. The Sm(1)-O(63) bond length is 2.39 Å. The Sm(1)-O(66) bond length is 2.38 Å. In the second Sm site, Sm(2) is bonded in a 7-coordinate geometry to one O(113), one O(18), one O(19), one O(2), one O(20), one O(23), and one O(97) atom. The Sm(2)-O(113) bond length is 2.42 Å. The Sm(2)-O(18) bond length is 2.62 Å. The Sm(2)-O(19) bond length is 2.56 Å. The Sm(2)-O(2) bond length is 2.41 Å. The Sm(2)-O(20) bond length is 2.44 Å. The Sm(2)-O(23) bond length is 2.48 Å. The Sm(2)-O(97) bond length is 2.40 Å. In the third Sm site, Sm(3) is bonded to one O(11), one O(118), one O(6), one O(7), one O(86), and one O(95) atom to form distorted SmO6 pentagonal pyramids that share  a cornercorner with one W(19)O6 octahedra and  a cornercorner with one W(20)O6 octahedra. The corner-sharing octahedral tilt angles range from 17-21°. The Sm(3)-O(11) bond length is 2.36 Å. The Sm(3)-O(118) bond length is 2.45 Å. The Sm(3)-O(6) bond length is 2.45 Å. The Sm(3)-O(7) bond length is 2.44 Å. The Sm(3)-O(86) bond length is 2.45 Å. The Sm(3)-O(95) bond length is 2.46 Å. In the fourth Sm site, Sm(4) is bonded in a 7-coordinate geometry to one O(12), one O(13), one O(14), one O(8), one O(87), one O(9), and one O(90) atom. The Sm(4)-O(12) bond length is 2.56 Å. The Sm(4)-O(13) bond length is 2.43 Å. The Sm(4)-O(14) bond length is 2.43 Å. The Sm(4)-O(8) bond length is 2.32 Å. The Sm(4)-O(87) bond length is 2.44 Å. The Sm(4)-O(9) bond length is 2.50 Å. The Sm(4)-O(90) bond length is 2.51 Å. In the fifth Sm site, Sm(5) is bonded in a 4-coordinate geometry to one O(15), one O(16), one O(17), and one O(75) atom. The Sm(5)-O(15) bond length is 2.34 Å. The Sm(5)-O(16) bond length is 2.43 Å. The Sm(5)-O(17) bond length is 2.51 Å. The Sm(5)-O(75) bond length is 2.43 Å. In the sixth Sm site, Sm(6) is bonded to one O(10), one O(117), one O(3), one O(4), one O(5), and one O(56) atom to form distorted SmO6 pentagonal pyramids that share  a cornercorner with one W(3)O6 octahedra. The corner-sharing octahedral tilt angles are 22°. The Sm(6)-O(10) bond length is 2.46 Å. The Sm(6)-O(117) bond length is 2.55 Å. The Sm(6)-O(3) bond length is 2.28 Å. The Sm(6)-O(4) bond length is 2.52 Å. The Sm(6)-O(5) bond length is 2.30 Å. The Sm(6)-O(56) bond length is 2.50 Å. There are thirty inequivalent W sites. In the first W site, W(1) is bonded in a 6-coordinate geometry to one O(117), one O(24), one O(34), one O(45), one O(59), and one O(83) atom. The W(1)-O(117) bond length is 1.71 Å. The W(1)-O(24) bond length is 1.90 Å. The W(1)-O(34) bond length is 2.08 Å. The W(1)-O(45) bond length is 1.83 Å. The W(1)-O(59) bond length is 1.95 Å. The W(1)-O(83) bond length is 2.28 Å. In the second W site, W(2) is bonded to one O(111), one O(113), one O(29), one O(33), one O(39), and one O(68) atom to form distorted WO6 octahedra that share  a cornercorner with one W(12)O6 octahedra,  a cornercorner with one W(25)O6 octahedra,  a cornercorner with one W(15)O5 square pyramid,  a cornercorner with one W(18)O5 square pyramid, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 18-29°. The W(2)-O(111) bond length is 1.89 Å. The W(2)-O(113) bond length is 1.73 Å. The W(2)-O(29) bond length is 1.87 Å. The W(2)-O(33) bond length is 1.91 Å. The W(2)-O(39) bond length is 1.93 Å. The W(2)-O(68) bond length is 2.17 Å. In the third W site, W(3) is bonded to one O(108), one O(30), one O(40), one O(56), one O(58), and one O(98) atom to form distorted WO6 octahedra that share  a cornercorner with one W(20)O6 octahedra,  a cornercorner with one Sm(6)O6 pentagonal pyramid,  a cornercorner with one W(8)O5 square pyramid,  a cornercorner with one W(9)O5 square pyramid,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one W(28)O5 square pyramid. The corner-sharing octahedral tilt angles are 27°. The W(3)-O(108) bond length is 2.27 Å. The W(3)-O(30) bond length is 1.87 Å. The W(3)-O(40) bond length is 1.84 Å. The W(3)-O(56) bond length is 1.76 Å. The W(3)-O(58) bond length is 1.95 Å. The W(3)-O(98) bond length is 2.10 Å. In the fourth W site, W(4) is bonded to one O(106), one O(62), one O(64), one O(76), and one O(91) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(16)O5 square pyramid,  a cornercorner with one W(7)O5 square pyramid,  a cornercorner with one W(8)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(18)O5 square pyramid. The W(4)-O(106) bond length is 2.23 Å. The W(4)-O(62) bond length is 1.83 Å. The W(4)-O(64) bond length is 2.11 Å. The W(4)-O(76) bond length is 1.95 Å. The W(4)-O(91) bond length is 1.81 Å. In the fifth W site, W(5) is bonded to one O(27), one O(46), one O(77), one O(78), and one O(99) atom to form WO5 square pyramids that share  a cornercorner with one W(19)O6 octahedra,  a cornercorner with one W(22)O6 octahedra,  a cornercorner with one W(23)O6 octahedra,  a cornercorner with one W(15)O5 square pyramid, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 25-32°. The W(5)-O(27) bond length is 1.90 Å. The W(5)-O(46) bond length is 1.95 Å. The W(5)-O(77) bond length is 1.88 Å. The W(5)-O(78) bond length is 2.19 Å. The W(5)-O(99) bond length is 1.95 Å. In the sixth W site, W(6) is bonded to one O(104), one O(50), one O(60), one O(71), and one O(88) atom to form WO5 square pyramids that share  a cornercorner with one W(13)O6 octahedra,  a cornercorner with one W(20)O6 octahedra,  a cornercorner with one W(21)O6 octahedra,  a cornercorner with one W(24)O5 square pyramid, and  a cornercorner with one P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 18-30°. The W(6)-O(104) bond length is 1.95 Å. The W(6)-O(50) bond length is 1.88 Å. The W(6)-O(60) bond length is 2.18 Å. The W(6)-O(71) bond length is 1.94 Å. The W(6)-O(88) bond length is 1.89 Å. In the seventh W site, W(7) is bonded to one O(100), one O(103), one O(54), one O(69), and one O(91) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(10)O5 square pyramid,  a cornercorner with one W(11)O5 square pyramid,  a cornercorner with one W(4)O5 square pyramid,  a cornercorner with one P(3)O4 tetrahedra, and  an edgeedge with one W(17)O5 square pyramid. The W(7)-O(100) bond length is 1.90 Å. The W(7)-O(103) bond length is 1.90 Å. The W(7)-O(54) bond length is 1.82 Å. The W(7)-O(69) bond length is 2.30 Å. The W(7)-O(91) bond length is 2.04 Å. In the eighth W site, W(8) is bonded to one O(101), one O(40), one O(51), one O(64), and one O(72) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(3)O6 octahedra,  a cornercorner with one W(16)O5 square pyramid,  a cornercorner with one W(4)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(25)O6 octahedra. The corner-sharing octahedral tilt angles are 20°. The W(8)-O(101) bond length is 1.90 Å. The W(8)-O(40) bond length is 2.03 Å. The W(8)-O(51) bond length is 2.31 Å. The W(8)-O(64) bond length is 1.81 Å. The W(8)-O(72) bond length is 1.92 Å. In the ninth W site, W(9) is bonded to one O(37), one O(41), one O(67), one O(80), and one O(98) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(13)O6 octahedra,  a cornercorner with one W(20)O6 octahedra,  a cornercorner with one W(3)O6 octahedra,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one W(29)O5 square pyramid. The corner-sharing octahedral tilt angles range from 21-35°. The W(9)-O(37) bond length is 1.92 Å. The W(9)-O(41) bond length is 2.28 Å. The W(9)-O(67) bond length is 1.99 Å. The W(9)-O(80) bond length is 2.07 Å. The W(9)-O(98) bond length is 1.81 Å. In the tenth W site, W(10) is bonded to one O(100), one O(32), one O(42), one O(74), and one O(81) atom to form WO5 square pyramids that share  a cornercorner with one W(21)O6 octahedra,  a cornercorner with one W(11)O5 square pyramid,  a cornercorner with one W(16)O5 square pyramid,  a cornercorner with one W(7)O5 square pyramid, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 18°. The W(10)-O(100) bond length is 1.90 Å. The W(10)-O(32) bond length is 1.89 Å. The W(10)-O(42) bond length is 1.94 Å. The W(10)-O(74) bond length is 1.92 Å. The W(10)-O(81) bond length is 2.23 Å. In the eleventh W site, W(11) is bonded to one O(102), one O(34), one O(44), one O(54), and one O(74) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(10)O5 square pyramid,  a cornercorner with one W(7)O5 square pyramid,  a cornercorner with one P(3)O4 tetrahedra, and  an edgeedge with one W(27)O6 octahedra. The W(11)-O(102) bond length is 2.31 Å. The W(11)-O(34) bond length is 1.80 Å. The W(11)-O(44) bond length is 1.93 Å. The W(11)-O(54) bond length is 2.13 Å. The W(11)-O(74) bond length is 1.90 Å. In the twelfth W site, W(12) is bonded to one O(107), one O(114), one O(29), one O(31), one O(52), and one O(63) atom to form distorted WO6 octahedra that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(22)O6 octahedra,  a cornercorner with one W(27)O6 octahedra,  a cornercorner with one W(17)O5 square pyramid, and  a cornercorner with one P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 17-35°. The W(12)-O(107) bond length is 1.90 Å. The W(12)-O(114) bond length is 2.20 Å. The W(12)-O(29) bond length is 1.91 Å. The W(12)-O(31) bond length is 1.92 Å. The W(12)-O(52) bond length is 1.95 Å. The W(12)-O(63) bond length is 1.76 Å. In the thirteenth W site, W(13) is bonded to one O(104), one O(43), one O(61), one O(79), one O(80), and one O(89) atom to form distorted WO6 octahedra that share  a cornercorner with one W(24)O5 square pyramid,  a cornercorner with one W(6)O5 square pyramid,  a cornercorner with one W(9)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(23)O6 octahedra. The W(13)-O(104) bond length is 1.90 Å. The W(13)-O(43) bond length is 2.23 Å. The W(13)-O(61) bond length is 2.11 Å. The W(13)-O(79) bond length is 1.72 Å. The W(13)-O(80) bond length is 1.80 Å. The W(13)-O(89) bond length is 1.93 Å. In the fourteenth W site, W(14) is bonded to one O(38), one O(45), one O(49), one O(53), one O(75), and one O(92) atom to form distorted WO6 octahedra that share  a cornercorner with one W(21)O6 octahedra,  a cornercorner with one W(24)O5 square pyramid,  a cornercorner with one P(5)O4 tetrahedra, and  an edgeedge with one W(26)O6 octahedra. The corner-sharing octahedral tilt angles are 24°. The W(14)-O(38) bond length is 1.94 Å. The W(14)-O(45) bond length is 2.07 Å. The W(14)-O(49) bond length is 1.82 Å. The W(14)-O(53) bond length is 1.83 Å. The W(14)-O(75) bond length is 1.73 Å. The W(14)-O(92) bond length is 2.21 Å. In the fifteenth W site, W(15) is bonded to one O(109), one O(28), one O(39), one O(77), and one O(85) atom to form WO5 square pyramids that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(28)O5 square pyramid,  a cornercorner with one W(29)O5 square pyramid,  a cornercorner with one W(5)O5 square pyramid, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 18°. The W(15)-O(109) bond length is 1.93 Å. The W(15)-O(28) bond length is 1.92 Å. The W(15)-O(39) bond length is 1.86 Å. The W(15)-O(77) bond length is 1.92 Å. The W(15)-O(85) bond length is 2.23 Å. In the sixteenth W site, W(16) is bonded to one O(32), one O(35), one O(62), one O(72), and one O(73) atom to form WO5 square pyramids that share  a cornercorner with one W(20)O6 octahedra,  a cornercorner with one W(10)O5 square pyramid,  a cornercorner with one W(4)O5 square pyramid,  a cornercorner with one W(8)O5 square pyramid, and  a cornercorner with one P(2)O4 tetrahedra. The corner-sharing octahedral tilt angles are 18°. The W(16)-O(32) bond length is 1.90 Å. The W(16)-O(35) bond length is 1.88 Å. The W(16)-O(62) bond length is 1.97 Å. The W(16)-O(72) bond length is 1.91 Å. The W(16)-O(73) bond length is 2.20 Å. In the seventeenth W site, W(17) is bonded to one O(103), one O(25), one O(52), one O(57), and one O(69) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(12)O6 octahedra,  a cornercorner with one W(27)O6 octahedra,  a cornercorner with one W(18)O5 square pyramid,  a cornercorner with one P(3)O4 tetrahedra, and  an edgeedge with one W(7)O5 square pyramid. The corner-sharing octahedral tilt angles range from 26-31°. The W(17)-O(103) bond length is 1.95 Å. The W(17)-O(25) bond length is 2.10 Å. The W(17)-O(52) bond length is 1.86 Å. The W(17)-O(57) bond length is 1.80 Å. The W(17)-O(69) bond length is 2.21 Å. In the eighteenth W site, W(18) is bonded to one O(106), one O(110), one O(111), one O(57), and one O(76) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(25)O6 octahedra,  a cornercorner with one W(17)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(4)O5 square pyramid. The corner-sharing octahedral tilt angles range from 31-32°. The W(18)-O(106) bond length is 2.28 Å. The W(18)-O(110) bond length is 1.81 Å. The W(18)-O(111) bond length is 1.91 Å. The W(18)-O(57) bond length is 2.07 Å. The W(18)-O(76) bond length is 1.89 Å. In the nineteenth W site, W(19) is bonded to one O(26), one O(36), one O(47), one O(65), one O(86), and one O(99) atom to form distorted WO6 octahedra that share  a cornercorner with one W(23)O6 octahedra,  a cornercorner with one W(26)O6 octahedra,  a cornercorner with one Sm(3)O6 pentagonal pyramid,  a cornercorner with one W(5)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(24)O5 square pyramid. The corner-sharing octahedral tilt angles range from 19-31°. The W(19)-O(26) bond length is 1.92 Å. The W(19)-O(36) bond length is 1.82 Å. The W(19)-O(47) bond length is 2.23 Å. The W(19)-O(65) bond length is 2.06 Å. The W(19)-O(86) bond length is 1.74 Å. The W(19)-O(99) bond length is 1.87 Å. In the twentieth W site, W(20) is bonded to one O(30), one O(35), one O(67), one O(88), one O(95), and one O(96) atom to form distorted WO6 octahedra that share  a cornercorner with one W(3)O6 octahedra,  a cornercorner with one Sm(3)O6 pentagonal pyramid,  a cornercorner with one W(16)O5 square pyramid,  a cornercorner with one W(6)O5 square pyramid,  a cornercorner with one W(9)O5 square pyramid, and  a cornercorner with one P(4)O4 tetrahedra. The corner-sharing octahedral tilt angles are 27°. The W(20)-O(30) bond length is 1.96 Å. The W(20)-O(35) bond length is 1.92 Å. The W(20)-O(67) bond length is 1.84 Å. The W(20)-O(88) bond length is 1.90 Å. The W(20)-O(95) bond length is 1.75 Å. The W(20)-O(96) bond length is 2.15 Å. In the twenty-first W site, W(21) is bonded to one O(24), one O(42), one O(48), one O(50), one O(53), and one O(87) atom to form distorted WO6 octahedra that share  a cornercorner with one W(14)O6 octahedra,  a cornercorner with one W(10)O5 square pyramid,  a cornercorner with one W(6)O5 square pyramid, and  a cornercorner with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 24°. The W(21)-O(24) bond length is 1.91 Å. The W(21)-O(42) bond length is 1.84 Å. The W(21)-O(48) bond length is 2.19 Å. The W(21)-O(50) bond length is 1.90 Å. The W(21)-O(53) bond length is 1.96 Å. The W(21)-O(87) bond length is 1.69 Å. In the twenty-second W site, W(22) is bonded to one O(107), one O(27), one O(55), one O(70), one O(82), and one O(84) atom to form distorted WO6 octahedra that share  a cornercorner with one W(12)O6 octahedra,  a cornercorner with one W(26)O6 octahedra,  a cornercorner with one W(30)O5 square pyramid,  a cornercorner with one W(5)O5 square pyramid, and  a cornercorner with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 17-35°. The W(22)-O(107) bond length is 1.88 Å. The W(22)-O(27) bond length is 1.92 Å. The W(22)-O(55) bond length is 1.90 Å. The W(22)-O(70) bond length is 1.93 Å. The W(22)-O(82) bond length is 1.67 Å. The W(22)-O(84) bond length is 2.16 Å. In the twenty-third W site, W(23) is bonded to one O(105), one O(43), one O(46), one O(65), one O(89), and one O(90) atom to form distorted WO6 octahedra that share  a cornercorner with one W(19)O6 octahedra,  a cornercorner with one W(29)O5 square pyramid,  a cornercorner with one W(5)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(13)O6 octahedra. The corner-sharing octahedral tilt angles are 31°. The W(23)-O(105) bond length is 2.04 Å. The W(23)-O(43) bond length is 2.29 Å. The W(23)-O(46) bond length is 1.84 Å. The W(23)-O(65) bond length is 1.83 Å. The W(23)-O(89) bond length is 1.93 Å. The W(23)-O(90) bond length is 1.69 Å. In the twenty-fourth W site, W(24) is bonded to one O(26), one O(47), one O(49), one O(61), and one O(71) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(13)O6 octahedra,  a cornercorner with one W(14)O6 octahedra,  a cornercorner with one W(6)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra, and  an edgeedge with one W(19)O6 octahedra. The corner-sharing octahedral tilt angles range from 20-29°. The W(24)-O(26) bond length is 1.98 Å. The W(24)-O(47) bond length is 2.28 Å. The W(24)-O(49) bond length is 2.03 Å. The W(24)-O(61) bond length is 1.79 Å. The W(24)-O(71) bond length is 1.87 Å. In the twenty-fifth W site, W(25) is bonded to one O(101), one O(110), one O(33), one O(51), one O(66), and one O(93) atom to form distorted WO6 octahedra that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(18)O5 square pyramid,  a cornercorner with one W(28)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra, and  an edgeedge with one W(8)O5 square pyramid. The corner-sharing octahedral tilt angles are 29°. The W(25)-O(101) bond length is 1.97 Å. The W(25)-O(110) bond length is 2.09 Å. The W(25)-O(33) bond length is 1.93 Å. The W(25)-O(51) bond length is 2.21 Å. The W(25)-O(66) bond length is 1.77 Å. The W(25)-O(93) bond length is 1.81 Å. In the twenty-sixth W site, W(26) is bonded to one O(116), one O(36), one O(38), one O(55), one O(92), and one O(94) atom to form distorted WO6 octahedra that share  a cornercorner with one W(19)O6 octahedra,  a cornercorner with one W(22)O6 octahedra,  a cornercorner with one W(30)O5 square pyramid,  a cornercorner with one P(5)O4 tetrahedra, and  an edgeedge with one W(14)O6 octahedra. The corner-sharing octahedral tilt angles range from 19-35°. The W(26)-O(116) bond length is 1.75 Å. The W(26)-O(36) bond length is 2.03 Å. The W(26)-O(38) bond length is 1.91 Å. The W(26)-O(55) bond length is 1.92 Å. The W(26)-O(92) bond length is 2.25 Å. The W(26)-O(94) bond length is 1.80 Å. In the twenty-seventh W site, W(27) is bonded to one O(102), one O(115), one O(25), one O(31), one O(44), and one O(97) atom to form distorted WO6 octahedra that share  a cornercorner with one W(12)O6 octahedra,  a cornercorner with one W(17)O5 square pyramid,  a cornercorner with one W(30)O5 square pyramid,  a cornercorner with one P(3)O4 tetrahedra, and  an edgeedge with one W(11)O5 square pyramid. The corner-sharing octahedral tilt angles are 35°. The W(27)-O(102) bond length is 2.27 Å. The W(27)-O(115) bond length is 1.99 Å. The W(27)-O(25) bond length is 1.81 Å. The W(27)-O(31) bond length is 1.90 Å. The W(27)-O(44) bond length is 1.92 Å. The W(27)-O(97) bond length is 1.73 Å. In the twenty-eighth W site, W(28) is bonded to one O(108), one O(112), one O(28), one O(58), and one O(93) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(25)O6 octahedra,  a cornercorner with one W(15)O5 square pyramid,  a cornercorner with one W(29)O5 square pyramid,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one W(3)O6 octahedra. The corner-sharing octahedral tilt angles are 21°. The W(28)-O(108) bond length is 2.27 Å. The W(28)-O(112) bond length is 1.81 Å. The W(28)-O(28) bond length is 1.90 Å. The W(28)-O(58) bond length is 1.95 Å. The W(28)-O(93) bond length is 2.06 Å. In the twenty-ninth W site, W(29) is bonded to one O(105), one O(109), one O(112), one O(37), and one O(41) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(23)O6 octahedra,  a cornercorner with one W(15)O5 square pyramid,  a cornercorner with one W(28)O5 square pyramid,  a cornercorner with one P(4)O4 tetrahedra, and  an edgeedge with one W(9)O5 square pyramid. The corner-sharing octahedral tilt angles are 22°. The W(29)-O(105) bond length is 1.84 Å. The W(29)-O(109) bond length is 1.88 Å. The W(29)-O(112) bond length is 2.08 Å. The W(29)-O(37) bond length is 1.99 Å. The W(29)-O(41) bond length is 2.30 Å. In the thirtieth W site, W(30) is bonded to one O(115), one O(59), one O(70), one O(83), and one O(94) atom to form distorted WO5 square pyramids that share  a cornercorner with one W(22)O6 octahedra,  a cornercorner with one W(26)O6 octahedra,  a cornercorner with one W(27)O6 octahedra, and  a cornercorner with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 19-31°. The W(30)-O(115) bond length is 1.85 Å. The W(30)-O(59) bond length is 1.93 Å. The W(30)-O(70) bond length is 1.90 Å. The W(30)-O(83) bond length is 2.25 Å. The W(30)-O(94) bond length is 2.11 Å. Mn(1) is bonded in a distorted rectangular see-saw-like geometry to one O(21), one O(22), one O(79), and one O(82) atom. The Mn(1)-O(21) bond length is 2.19 Å. The Mn(1)-O(22) bond length is 2.34 Å. The Mn(1)-O(79) bond length is 2.09 Å. The Mn(1)-O(82) bond length is 2.16 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(14), one H(1), one H(2), and one O(12) atom. The C(1)-C(14) bond length is 1.40 Å. The C(1)-H(1) bond length is 0.97 Å. The C(1)-H(2) bond length is 0.97 Å. The C(1)-O(12) bond length is 1.46 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(7), one O(13), and one O(15) atom. The C(2)-C(7) bond length is 1.49 Å. The C(2)-O(13) bond length is 1.22 Å. The C(2)-O(15) bond length is 1.29 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one H(3), one H(4), and one O(17) atom. The C(3)-H(3) bond length is 0.97 Å. The C(3)-H(4) bond length is 0.98 Å. The C(3)-O(17) bond length is 1.41 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(20) and one O(21) atom. The C(4)-O(20) bond length is 1.27 Å. The C(4)-O(21) bond length is 1.22 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one C(12), one H(5), one H(6), and one O(23) atom. The C(5)-C(12) bond length is 1.43 Å. The C(5)-H(5) bond length is 0.97 Å. The C(5)-H(6) bond length is 0.97 Å. The C(5)-O(23) bond length is 1.43 Å. In the sixth C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to one H(7), one H(8), and one O(4) atom. The C(6)-H(7) bond length is 0.97 Å. The C(6)-H(8) bond length is 0.97 Å. The C(6)-O(4) bond length is 1.44 Å. In the seventh C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(2); two equivalent H(9,10); and one O(9) atom. Both C(7)-H(9,10) bond lengths are 0.97 Å. The C(7)-O(9) bond length is 1.55 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(16) and one O(3) atom. The C(8)-O(16) bond length is 1.20 Å. The C(8)-O(3) bond length is 1.35 Å. In the ninth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(11,12) and one O(22) atom. Both C(9)-H(11,12) bond lengths are 0.97 Å. The C(9)-O(22) bond length is 1.38 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(11) atom. The C(10)-O(10) bond length is 1.26 Å. The C(10)-O(11) bond length is 1.23 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(13), one O(7), and one O(8) atom. The C(11)-C(13) bond length is 1.43 Å. The C(11)-O(7) bond length is 1.21 Å. The C(11)-O(8) bond length is 1.36 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(5), one O(1), and one O(2) atom. The C(12)-O(1) bond length is 1.30 Å. The C(12)-O(2) bond length is 1.30 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one H(13), one H(14), and one O(6) atom. The C(13)-H(13) bond length is 0.97 Å. The C(13)-H(14) bond length is 0.97 Å. The C(13)-O(6) bond length is 1.47 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(1), one O(14), and one O(5) atom. The C(14)-O(14) bond length is 1.38 Å. The C(14)-O(5) bond length is 1.30 Å. There are five inequivalent P sites. In the first P site, P(1) is bonded to one O(43), one O(47), one O(60), and one O(78) atom to form PO4 tetrahedra that share  a cornercorner with one W(13)O6 octahedra,  a cornercorner with one W(19)O6 octahedra,  a cornercorner with one W(23)O6 octahedra,  a cornercorner with one W(24)O5 square pyramid,  a cornercorner with one W(5)O5 square pyramid, and  a cornercorner with one W(6)O5 square pyramid. The corner-sharing octahedral tilt angles range from 49-56°. The P(1)-O(43) bond length is 1.56 Å. The P(1)-O(47) bond length is 1.59 Å. The P(1)-O(60) bond length is 1.55 Å. The P(1)-O(78) bond length is 1.52 Å. In the second P site, P(2) is bonded to one O(106), one O(51), one O(68), and one O(73) atom to form PO4 tetrahedra that share  a cornercorner with one W(2)O6 octahedra,  a cornercorner with one W(25)O6 octahedra,  a cornercorner with one W(16)O5 square pyramid,  a cornercorner with one W(18)O5 square pyramid,  a cornercorner with one W(4)O5 square pyramid, and  a cornercorner with one W(8)O5 square pyramid. The corner-sharing octahedral tilt angles range from 48-50°. The P(2)-O(106) bond length is 1.58 Å. The P(2)-O(51) bond length is 1.58 Å. The P(2)-O(68) bond length is 1.52 Å. The P(2)-O(73) bond length is 1.52 Å. In the third P site, P(3) is bonded to one O(102), one O(114), one O(69), and one O(81) atom to form PO4 tetrahedra that share  a cornercorner with one W(12)O6 octahedra,  a cornercorner with one W(27)O6 octahedra,  a cornercorner with one W(10)O5 square pyramid,  a cornercorner with one W(11)O5 square pyramid,  a cornercorner with one W(17)O5 square pyramid, and  a cornercorner with one W(7)O5 square pyramid. The corner-sharing octahedral tilt angles range from 49-58°. The P(3)-O(102) bond length is 1.57 Å. The P(3)-O(114) bond length is 1.51 Å. The P(3)-O(69) bond length is 1.59 Å. The P(3)-O(81) bond length is 1.51 Å. In the fourth P site, P(4) is bonded to one O(108), one O(41), one O(85), and one O(96) atom to form PO4 tetrahedra that share  a cornercorner with one W(20)O6 octahedra,  a cornercorner with one W(3)O6 octahedra,  a cornercorner with one W(15)O5 square pyramid,  a cornercorner with one W(28)O5 square pyramid,  a cornercorner with one W(29)O5 square pyramid, and  a cornercorner with one W(9)O5 square pyramid. The corner-sharing octahedral tilt angles range from 48-52°. The P(4)-O(108) bond length is 1.58 Å. The P(4)-O(41) bond length is 1.55 Å. The P(4)-O(85) bond length is 1.54 Å. The P(4)-O(96) bond length is 1.55 Å. In the fifth P site, P(5) is bonded to one O(48), one O(83), one O(84), and one O(92) atom to form PO4 tetrahedra that share  a cornercorner with one W(14)O6 octahedra,  a cornercorner with one W(21)O6 octahedra,  a cornercorner with one W(22)O6 octahedra,  a cornercorner with one W(26)O6 octahedra, and  a cornercorner with one W(30)O5 square pyramid. The corner-sharing octahedral tilt angles range from 48-56°. The P(5)-O(48) bond length is 1.50 Å. The P(5)-O(83) bond length is 1.56 Å. The P(5)-O(84) bond length is 1.54 Å. The P(5)-O(92) bond length is 1.60 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(9,10) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(11,12) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(13) atom. There are one hundred and eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Sm(1) and one C(12) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Sm(2) and one C(12) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(2), one Sm(6), and one C(8) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Sm(6) and one C(6) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Sm(6) and one C(14) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Sm(3) and one C(13) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Sm(3) and one C(11) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Sm(4) and one C(11) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Sm(4) and one C(7) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Sm(6) and one C(10) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Sm(3) and one C(10) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Sm(4) and one C(1) atom. In the thirteenth O site, O(13) is bonded in a 3-coordinate geometry to one Na(2), one Sm(4), and one C(2) atom. In the fourteenth O site, O(14) is bonded in a 3-coordinate geometry to one Na(2), one Sm(4), and one C(14) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 150 degrees geometry to one Sm(5) and one C(2) atom. In the sixteenth O site, O(16) is bonded in a 3-coordinate geometry to one Na(2), one Sm(5), and one C(8) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one Sm(5) and one C(3) atom. In the eighteenth O site, O(18) is bonded in a distorted trigonal non-coplanar geometry to one Na(4), one Sm(1), and one Sm(2) atom. In the nineteenth O site, O(19) is bonded in a water-like geometry to one Sm(1) and one Sm(2) atom. In the twentieth O site, O(20) is bonded in a distorted single-bond geometry to one Sm(1), one Sm(2), and one C(4) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one Sm(1), one Mn(1), and one C(4) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one Mn(1) and one C(9) atom. In the twenty-third O site, O(23) is bonded in a distorted single-bond geometry to one Sm(2) and one C(5) atom. In the twenty-fourth O site, O(24) is bonded in a bent 150 degrees geometry to one W(1) and one W(21) atom. In the twenty-fifth O site, O(25) is bonded in a bent 150 degrees geometry to one W(17) and one W(27) atom. In the twenty-sixth O site, O(26) is bonded in a bent 120 degrees geometry to one W(19) and one W(24) atom. In the twenty-seventh O site, O(27) is bonded in a bent 150 degrees geometry to one W(22) and one W(5) atom. In the twenty-eighth O site, O(28) is bonded in a bent 150 degrees geometry to one W(15) and one W(28) atom. In the twenty-ninth O site, O(29) is bonded in a bent 150 degrees geometry to one W(12) and one W(2) atom. In the thirtieth O site, O(30) is bonded in a bent 150 degrees geometry to one W(20) and one W(3) atom. In the thirty-first O site, O(31) is bonded in a bent 150 degrees geometry to one W(12) and one W(27) atom. In the thirty-second O site, O(32) is bonded in a distorted T-shaped geometry to one Na(5), one W(10), and one W(16) atom. In the thirty-third O site, O(33) is bonded in a bent 150 degrees geometry to one W(2) and one W(25) atom. In the thirty-fourth O site, O(34) is bonded in a bent 150 degrees geometry to one W(1) and one W(11) atom. In the thirty-fifth O site, O(35) is bonded in a distorted T-shaped geometry to one W(16) and one W(20) atom. In the thirty-sixth O site, O(36) is bonded in a bent 150 degrees geometry to one W(19) and one W(26) atom. In the thirty-seventh O site, O(37) is bonded in a bent 120 degrees geometry to one W(29) and one W(9) atom. In the thirty-eighth O site, O(38) is bonded in a bent 120 degrees geometry to one W(14) and one W(26) atom. In the thirty-ninth O site, O(39) is bonded in a bent 150 degrees geometry to one W(15) and one W(2) atom. In the fortieth O site, O(40) is bonded in a distorted bent 150 degrees geometry to one W(3) and one W(8) atom. In the forty-first O site, O(41) is bonded in a distorted single-bond geometry to one W(29), one W(9), and one P(4) atom. In the forty-second O site, O(42) is bonded in a 2-coordinate geometry to one W(10) and one W(21) atom. In the forty-third O site, O(43) is bonded in a distorted single-bond geometry to one W(13), one W(23), and one P(1) atom. In the forty-fourth O site, O(44) is bonded in a bent 120 degrees geometry to one W(11) and one W(27) atom. In the forty-fifth O site, O(45) is bonded in a bent 150 degrees geometry to one W(1) and one W(14) atom. In the forty-sixth O site, O(46) is bonded in a bent 150 degrees geometry to one W(23) and one W(5) atom. In the forty-seventh O site, O(47) is bonded in a distorted single-bond geometry to one W(19), one W(24), and one P(1) atom. In the forty-eighth O site, O(48) is bonded in a distorted single-bond geometry to one W(21) and one P(5) atom. In the forty-ninth O site, O(49) is bonded in a distorted bent 150 degrees geometry to one W(14) and one W(24) atom. In the fiftieth O site, O(50) is bonded in a distorted T-shaped geometry to one Na(5), one W(21), and one W(6) atom. In the fifty-first O site, O(51) is bonded in a distorted single-bond geometry to one W(25), one W(8), and one P(2) atom. In the fifty-second O site, O(52) is bonded in a bent 150 degrees geometry to one W(12) and one W(17) atom. In the fifty-third O site, O(53) is bonded in a bent 150 degrees geometry to one W(14) and one W(21) atom. In the fifty-fourth O site, O(54) is bonded in a bent 150 degrees geometry to one W(11) and one W(7) atom. In the fifty-fifth O site, O(55) is bonded in a bent 150 degrees geometry to one W(22) and one W(26) atom. In the fifty-sixth O site, O(56) is bonded in a distorted bent 150 degrees geometry to one Sm(6) and one W(3) atom. In the fifty-seventh O site, O(57) is bonded in a distorted single-bond geometry to one W(17) and one W(18) atom. In the fifty-eighth O site, O(58) is bonded in a bent 120 degrees geometry to one W(28) and one W(3) atom. In the fifty-ninth O site, O(59) is bonded in a distorted trigonal non-coplanar geometry to one Na(3), one W(1), and one W(30) atom. In the sixtieth O site, O(60) is bonded in a distorted single-bond geometry to one W(6) and one P(1) atom. In the sixty-first O site, O(61) is bonded in a bent 150 degrees geometry to one W(13) and one W(24) atom. In the sixty-second O site, O(62) is bonded in a bent 150 degrees geometry to one W(16) and one W(4) atom. In the sixty-third O site, O(63) is bonded in a distorted linear geometry to one Sm(1) and one W(12) atom. In the sixty-fourth O site, O(64) is bonded in a bent 150 degrees geometry to one W(4) and one W(8) atom. In the sixty-fifth O site, O(65) is bonded in a bent 150 degrees geometry to one W(19) and one W(23) atom. In the sixty-sixth O site, O(66) is bonded in a 1-coordinate geometry to one Sm(1) and one W(25) atom. In the sixty-seventh O site, O(67) is bonded in a bent 150 degrees geometry to one W(20) and one W(9) atom. In the sixty-eighth O site, O(68) is bonded in a distorted single-bond geometry to one W(2) and one P(2) atom. In the sixty-ninth O site, O(69) is bonded in a distorted single-bond geometry to one W(17), one W(7), and one P(3) atom. In the seventieth O site, O(70) is bonded in a bent 150 degrees geometry to one W(22) and one W(30) atom. In the seventy-first O site, O(71) is bonded in a bent 150 degrees geometry to one W(24) and one W(6) atom. In the seventy-second O site, O(72) is bonded in a bent 150 degrees geometry to one W(16) and one W(8) atom. In the seventy-third O site, O(73) is bonded in a distorted single-bond geometry to one W(16) and one P(2) atom. In the seventy-fourth O site, O(74) is bonded in a bent 150 degrees geometry to one W(10) and one W(11) atom. In the seventy-fifth O site, O(75) is bonded in a distorted single-bond geometry to one Sm(5) and one W(14) atom. In the seventy-sixth O site, O(76) is bonded in a bent 120 degrees geometry to one W(18) and one W(4) atom. In the seventy-seventh O site, O(77) is bonded in a bent 150 degrees geometry to one W(15) and one W(5) atom. In the seventy-eighth O site, O(78) is bonded in a distorted single-bond geometry to one W(5) and one P(1) atom. In the seventy-ninth O site, O(79) is bonded in a bent 150 degrees geometry to one W(13) and one Mn(1) atom. In the eightieth O site, O(80) is bonded in a distorted bent 150 degrees geometry to one W(13) and one W(9) atom. In the eighty-first O site, O(81) is bonded in a distorted single-bond geometry to one W(10) and one P(3) atom. In the eighty-second O site, O(82) is bonded in a distorted single-bond geometry to one W(22) and one Mn(1) atom. In the eighty-third O site, O(83) is bonded in a distorted single-bond geometry to one W(1), one W(30), and one P(5) atom. In the eighty-fourth O site, O(84) is bonded in a distorted bent 120 degrees geometry to one W(22) and one P(5) atom. In the eighty-fifth O site, O(85) is bonded in a distorted single-bond geometry to one W(15) and one P(4) atom. In the eighty-sixth O site, O(86) is bonded in a distorted bent 150 degrees geometry to one Sm(3) and one W(19) atom. In the eighty-seventh O site, O(87) is bonded in a distorted linear geometry to one Sm(4) and one W(21) atom. In the eighty-eighth O site, O(88) is bonded in a distorted T-shaped geometry to one Na(5), one W(20), and one W(6) atom. In the eighty-ninth O site, O(89) is bonded in a bent 120 degrees geometry to one W(13) and one W(23) atom. In the ninetieth O site, O(90) is bonded in a distorted single-bond geometry to one Sm(4) and one W(23) atom. In the ninety-first O site, O(91) is bonded in a distorted bent 150 degrees geometry to one W(4) and one W(7) atom. In the ninety-second O site, O(92) is bonded in a distorted single-bond geometry to one W(14), one W(26), and one P(5) atom. In the ninety-third O site, O(93) is bonded in a distorted bent 150 degrees geometry to one W(25) and one W(28) atom. In the ninety-fourth O site, O(94) is bonded in a distorted bent 150 degrees geometry to one W(26) and one W(30) atom. In the ninety-fifth O site, O(95) is bonded in a distorted linear geometry to one Sm(3) and one W(20) atom. In the ninety-sixth O site, O(96) is bonded in a 1-coordinate geometry to one W(20) and one P(4) atom. In the ninety-seventh O site, O(97) is bonded in a distorted linear geometry to one Sm(2) and one W(27) atom. In the ninety-eighth O site, O(98) is bonded in a bent 150 degrees geometry to one W(3) and one W(9) atom. In the ninety-ninth O site, O(99) is bonded in a bent 150 degrees geometry to one W(19) and one W(5) atom. In the one hundredth O site, O(100) is bonded in a bent 150 degrees geometry to one W(10) and one W(7) atom. In the one hundred and first O site, O(101) is bonded in a bent 120 degrees geometry to one W(25) and one W(8) atom. In the one hundred and second O site, O(102) is bonded in a distorted single-bond geometry to one W(11), one W(27), and one P(3) atom. In the one hundred and third O site, O(103) is bonded in a bent 120 degrees geometry to one W(17) and one W(7) atom. In the one hundred and fourth O site, O(104) is bonded in a bent 150 degrees geometry to one W(13) and one W(6) atom. In the one hundred and fifth O site, O(105) is bonded in a bent 150 degrees geometry to one W(23) and one W(29) atom. In the one hundred and sixth O site, O(106) is bonded in a distorted single-bond geometry to one W(18), one W(4), and one P(2) atom. In the one hundred and seventh O site, O(107) is bonded in a linear geometry to one W(12) and one W(22) atom. In the one hundred and eighth O site, O(108) is bonded in a distorted single-bond geometry to one W(28), one W(3), and one P(4) atom. In the one hundred and ninth O site, O(109) is bonded in a bent 150 degrees geometry to one W(15) and one W(29) atom. In the one hundred and tenth O site, O(110) is bonded in a bent 150 degrees geometry to one W(18) and one W(25) atom. In the one hundred and eleventh O site, O(111) is bonded in a bent 150 degrees geometry to one W(18) and one W(2) atom. In the one hundred and twelfth O site, O(112) is bonded in a bent 150 degrees geometry to one W(28) and one W(29) atom. In the one hundred and thirteenth O site, O(113) is bonded in a linear geometry to one Sm(2) and one W(2) atom. In the one hundred and fourteenth O site, O(114) is bonded in a distorted single-bond geometry to one W(12) and one P(3) atom. In the one hundred and fifteenth O site, O(115) is bonded in a bent 150 degrees geometry to one W(27) and one W(30) atom. In the one hundred and sixteenth O site, O(116) is bonded in a distorted bent 150 degrees geometry to one K(1) and one W(26) atom. In the one hundred and seventeenth O site, O(117) is bonded in a distorted single-bond geometry to one Sm(6) and one W(1) atom. In the one hundred and eighteenth O site, O(118) is bonded in a bent 150 degrees geometry to one K(1) and one Sm(3) atom. Linkers: 28 [O]CC([O])=O. Metal clusters: 4 [K] ,20 [Na] ,24 [Sm] ,4 [Mn] ,120 [W]. The MOF has largest included sphere 5.37 A, density 3.96 g/cm3, surface area 1189.31 m2/g, accessible volume 0.07 cm3/g