(CH2)2CdC14N4H14(OF)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two CdC14N4H14(OF)2 clusters. In each CdC14N4H14(OF)2 cluster, Cd(1) is bonded in a distorted T-shaped geometry to one N(1), one N(2), and one O(2) atom. The Cd(1)-N(1) bond length is 2.37 Å. The Cd(1)-N(2) bond length is 2.26 Å. The Cd(1)-O(2) bond length is 2.30 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(11), one N(1), and one N(4) atom. The C(1)-C(11) bond length is 1.48 Å. The C(1)-N(1) bond length is 1.30 Å. The C(1)-N(4) bond length is 1.33 Å. In the second C site, C(2) is bonded in a 3-coordinate geometry to one C(4), one N(4), and one H(4) atom. The C(2)-C(4) bond length is 1.31 Å. The C(2)-N(4) bond length is 1.42 Å. The C(2)-H(4) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(7) and one F(2) atom. The C(3)-C(7) bond length is 1.38 Å. The C(3)-F(2) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a 3-coordinate geometry to one C(2), one N(1), and one H(11) atom. The C(4)-N(1) bond length is 1.44 Å. The C(4)-H(11) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(7) and one F(1) atom. The C(5)-C(7) bond length is 1.39 Å. The C(5)-F(1) bond length is 1.35 Å. In the sixth C site, C(6) is bonded in a trigonal non-coplanar geometry to one C(8); one H(17); and two equivalent H(5,7) atoms. The C(6)-C(8) bond length is 1.49 Å. The C(6)-H(17) bond length is 0.96 Å. Both C(6)-H(5,7) bond lengths are 0.96 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(3), and one C(5) atom. The C(7)-C(12) bond length is 1.53 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(6), one N(2), and one N(3) atom. The C(8)-N(2) bond length is 1.33 Å. The C(8)-N(3) bond length is 1.35 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(2), and one H(10) atom. The C(9)-C(16) bond length is 1.36 Å. The C(9)-N(2) bond length is 1.38 Å. The C(9)-H(10) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(8,12) atoms. The C(10)-N(3) bond length is 1.48 Å. Both C(10)-H(8,12) bond lengths are 0.97 Å. In the eleventh C site, C(11) is bonded in a trigonal non-coplanar geometry to one C(1); one H(3); and two equivalent H(2,6) atoms. The C(11)-H(3) bond length is 0.96 Å. Both C(11)-H(2,6) bond lengths are 0.96 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(1), and one O(2) atom. The C(12)-O(1) bond length is 1.23 Å. The C(12)-O(2) bond length is 1.25 Å. In the thirteenth C site, C(13) is bonded in a 3-coordinate geometry to one N(4) and two equivalent H(15,18) atoms. The C(13)-N(4) bond length is 1.45 Å. Both C(13)-H(15,18) bond lengths are 0.97 Å. In the fourteenth C site, C(16) is bonded in a 2-coordinate geometry to one C(9), one N(3), and one H(14) atom. The C(16)-N(3) bond length is 1.37 Å. The C(16)-H(14) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(8), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(16), and one C(8) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(2) atom. There are ten inequivalent H sites. In the first H site, H(2,6) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5,7) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(8,12) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(15,18) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(12) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(12) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(5) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(3) atom. Linkers: 3 Cc1nccn1CCCCn1ccnc1C ,1 [O]C(=O)c1c(F)c(F)c(C([O])=O)c(F)c1F. Metal clusters: 2 O=[C]O[Cd]. The MOF has largest included sphere 4.48 A, density 1.23 g/cm3, surface area 4677.89 m2/g, accessible volume 0.35 cm3/g