CuC18H12(NO)4(CH)8(C5H2O2)2 is Indium-derived structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules, twelve methyl methacrylate molecules, and six CuC18H12(NO)4 clusters. In two of the CuC18H12(NO)4 clusters, Cu(2) is bonded in a rectangular see-saw-like geometry to two equivalent N(3) and two equivalent N(5) atoms. Both Cu(2)-N(3) bond lengths are 1.98 Å. Both Cu(2)-N(5) bond lengths are 2.03 Å. There are nine inequivalent C sites. In the first C site, C(19) is bonded in a distorted single-bond geometry to one O(5) atom. The C(19)-O(5) bond length is 1.38 Å. In the second C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(26), one N(3), and one H(17) atom. The C(25)-C(26) bond length is 1.33 Å. The C(25)-N(3) bond length is 1.32 Å. The C(25)-H(17) bond length is 0.93 Å. In the third C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one C(27), and one H(18) atom. The C(26)-C(27) bond length is 1.36 Å. The C(26)-H(18) bond length is 0.93 Å. In the fourth C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(30) atom. The C(27)-C(28) bond length is 1.34 Å. The C(27)-C(30) bond length is 1.50 Å. In the fifth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one C(29), and one H(19) atom. The C(28)-C(29) bond length is 1.29 Å. The C(28)-H(19) bond length is 0.93 Å. In the sixth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(28), one N(3), and one H(20) atom. The C(29)-N(3) bond length is 1.35 Å. The C(29)-H(20) bond length is 0.93 Å. In the seventh C site, C(30) is bonded in a bent 120 degrees geometry to one C(27), one O(5), and one O(6) atom. The C(30)-O(5) bond length is 1.30 Å. The C(30)-O(6) bond length is 1.17 Å. In the eighth C site, C(43) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(29) atom. The C(43)-N(5) bond length is 1.27 Å. The C(43)-H(29) bond length is 0.93 Å. In the ninth C site, C(47) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(32) atom. The C(47)-N(5) bond length is 1.29 Å. The C(47)-H(32) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Cu(2), one C(25), and one C(29) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Cu(2), one C(43), and one C(47) atom. There are six inequivalent H sites. In the first H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the second H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(28) atom. In the fourth H site, H(20) is bonded in a single-bond geometry to one C(29) atom. In the fifth H site, H(29) is bonded in a single-bond geometry to one C(43) atom. In the sixth H site, H(32) is bonded in a single-bond geometry to one C(47) atom. There are two inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one C(19) and one C(30) atom. In the second O site, O(6) is bonded in a single-bond geometry to one C(30) atom. In four of the CuC18H12(NO)4 clusters, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one N(4), and one N(6) atom. The Cu(1)-N(1) bond length is 2.02 Å. The Cu(1)-N(2) bond length is 1.98 Å. The Cu(1)-N(4) bond length is 2.03 Å. The Cu(1)-N(6) bond length is 2.01 Å. There are eighteen inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one O(3) atom. The C(3)-O(3) bond length is 1.39 Å. In the second C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(7)-N(1) bond length is 1.31 Å. The C(7)-H(5) bond length is 0.93 Å. In the third C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(11)-N(1) bond length is 1.29 Å. The C(11)-H(8) bond length is 0.93 Å. In the fourth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(13)-N(2) bond length is 1.35 Å. The C(13)-H(9) bond length is 0.93 Å. In the fifth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(10) atom. The C(14)-C(15) bond length is 1.36 Å. The C(14)-H(10) bond length is 0.93 Å. In the sixth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.33 Å. The C(15)-C(18) bond length is 1.49 Å. In the seventh C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(11) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(11) bond length is 0.93 Å. In the eighth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(2), and one H(12) atom. The C(17)-N(2) bond length is 1.30 Å. The C(17)-H(12) bond length is 0.93 Å. In the ninth C site, C(18) is bonded in a bent 120 degrees geometry to one C(15), one O(3), and one O(4) atom. The C(18)-O(3) bond length is 1.29 Å. The C(18)-O(4) bond length is 1.22 Å. In the tenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(21) atom. The C(31)-N(4) bond length is 1.30 Å. The C(31)-H(21) bond length is 0.93 Å. In the eleventh C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(24) atom. The C(35)-N(4) bond length is 1.30 Å. The C(35)-H(24) bond length is 0.93 Å. In the twelfth C site, C(37) is bonded in a distorted single-bond geometry to one O(11) atom. The C(37)-O(11) bond length is 1.40 Å. In the thirteenth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(33) atom. The C(49)-N(6) bond length is 1.32 Å. The C(49)-H(33) bond length is 0.93 Å. In the fourteenth C site, C(50) is bonded in a distorted single-bond geometry to one C(51) and one H(34) atom. The C(50)-C(51) bond length is 1.39 Å. The C(50)-H(34) bond length is 0.93 Å. In the fifteenth C site, C(51) is bonded in a trigonal planar geometry to one C(50), one C(52), and one C(54) atom. The C(51)-C(52) bond length is 1.31 Å. The C(51)-C(54) bond length is 1.45 Å. In the sixteenth C site, C(52) is bonded in a distorted single-bond geometry to one C(51), one C(53), and one H(35) atom. The C(52)-C(53) bond length is 1.34 Å. The C(52)-H(35) bond length is 0.93 Å. In the seventeenth C site, C(53) is bonded in a distorted bent 120 degrees geometry to one C(52), one N(6), and one H(36) atom. The C(53)-N(6) bond length is 1.35 Å. The C(53)-H(36) bond length is 0.93 Å. In the eighteenth C site, C(54) is bonded in a bent 120 degrees geometry to one C(51), one O(11), and one O(12) atom. The C(54)-O(11) bond length is 1.33 Å. The C(54)-O(12) bond length is 1.18 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(17) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(31), and one C(35) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(49), and one C(53) atom. There are twelve inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(21) is bonded in a single-bond geometry to one C(31) atom. In the eighth H site, H(24) is bonded in a single-bond geometry to one C(35) atom. In the ninth H site, H(33) is bonded in a single-bond geometry to one C(49) atom. In the tenth H site, H(34) is bonded in a single-bond geometry to one C(50) atom. In the eleventh H site, H(35) is bonded in a single-bond geometry to one C(52) atom. In the twelfth H site, H(36) is bonded in a single-bond geometry to one C(53) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one C(18) and one C(3) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(18) atom. In the third O site, O(11) is bonded in a bent 120 degrees geometry to one C(37) and one C(54) atom. In the fourth O site, O(12) is bonded in a single-bond geometry to one C(54) atom. Linkers: 12 O=C(Oc1cccc(OC(=O)c2ccncc2)c1)c1ccncc1. Metal clusters: 6 [Cu]. The MOF has largest included sphere 5.82 A, density 1.08 g/cm3, surface area 4917.94 m2/g, accessible volume 0.46 cm3/g