CdC12N2H6O3(CH)4C4H3C3H2 is Indium-derived structured and crystallizes in the tetragonal I-42d space group. The structure is zero-dimensional and consists of sixty-four 02329_fluka molecules; eight 2,3-dimethyl-1,3-butadiene molecules; sixteen isobutylene molecules; and eight CdC12N2H6O3 clusters. In each CdC12N2H6O3 cluster, Cd(1) is bonded to one N(1), one N(2), one O(2), one O(3), and two equivalent O(1) atoms to form distorted edge-sharing CdN2O4 pentagonal pyramids. The Cd(1)-N(1) bond length is 2.35 Å. The Cd(1)-N(2) bond length is 2.33 Å. The Cd(1)-O(2) bond length is 2.41 Å. The Cd(1)-O(3) bond length is 2.33 Å. Both Cd(1)-O(1) bond lengths are 2.26 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one O(1) atom. The C(1)-C(6) bond length is 1.43 Å. The C(1)-O(1) bond length is 1.31 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3,4) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-H(3,4) bond length is 0.94 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.42 Å. The C(5)-C(7) bond length is 1.40 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one N(1) atom. The C(6)-N(1) bond length is 1.36 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one H(3,4) atom. The C(7)-H(3,4) bond length is 0.94 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one N(1) atom. The C(9)-N(1) bond length is 1.36 Å. In the seventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(14)-N(2) bond length is 1.34 Å. The C(14)-H(9) bond length is 0.94 Å. In the eighth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(15)-N(2) bond length is 1.31 Å. The C(15)-H(10) bond length is 0.94 Å. In the ninth C site, C(17) is bonded in a bent 120 degrees geometry to one C(18), one O(2), and one O(3) atom. The C(17)-C(18) bond length is 1.51 Å. The C(17)-O(2) bond length is 1.27 Å. The C(17)-O(3) bond length is 1.25 Å. In the tenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(12) atom. The C(19)-C(18) bond length is 1.39 Å. The C(19)-H(12) bond length is 0.94 Å. In the eleventh C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(23) atom. The C(18)-C(23) bond length is 1.38 Å. In the twelfth C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(15) atom. The C(23)-H(15) bond length is 0.94 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(6), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(14), and one C(15) atom. There are five inequivalent H sites. In the first H site, H(3,4) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(17) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Cd(1) and one C(17) atom. Linkers: 9 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cc2)cc1 ,16 [O]c1cccc2ccc(/C=C/c3ccncc3)nc12. Metal clusters: 16 [Cd]. The MOF has largest included sphere 5.82 A, density 1.22 g/cm3, surface area 4261.34 m2/g, accessible volume 0.39 cm3/g