Zn3C20H12(N2O7)2(ZnC10NH6O4)2(C19H9)4(CH)28(C3H2)4(C9H4)8 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty-eight 02329_fluka molecules; two 2,3-dimethyl-1,3-butadiene molecules; two C19H9 clusters; two C9H4 clusters; one Zn3C20H12(N2O7)2 cluster; and one ZnC10NH6O4 cluster. In each C19H9 cluster, there are thirty-eight inequivalent C sites. In the first C site, C(5) is bonded in a distorted single-bond geometry to one C(7) and one H(3) atom. The C(5)-C(7) bond length is 1.38 Å. The C(5)-H(3) bond length is 0.92 Å. In the second C site, C(6) is bonded in a single-bond geometry to one C(7) and one H(4) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(4) bond length is 0.93 Å. In the third C site, C(7) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(8) atom. The C(7)-C(8) bond length is 1.40 Å. In the fourth C site, C(8) is bonded in a linear geometry to one C(7) and one C(9) atom. The C(8)-C(9) bond length is 1.25 Å. In the fifth C site, C(9) is bonded in a linear geometry to one C(10) and one C(8) atom. The C(9)-C(10) bond length is 1.36 Å. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(12) bond length is 1.41 Å. In the seventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(14) atom. The C(11)-C(13) bond length is 1.50 Å. The C(11)-C(14) bond length is 1.39 Å. In the eighth C site, C(12) is bonded in a trigonal planar geometry to one C(10), one C(15), and one C(16) atom. The C(12)-C(15) bond length is 1.54 Å. The C(12)-C(16) bond length is 1.39 Å. In the ninth C site, C(13) is bonded in a single-bond geometry to one C(11), one C(17), one C(18), and one H(5) atom. The C(13)-C(17) bond length is 1.50 Å. The C(13)-C(18) bond length is 1.50 Å. The C(13)-H(5) bond length is 0.98 Å. In the tenth C site, C(14) is bonded in a trigonal planar geometry to one C(11), one C(19), and one C(20) atom. The C(14)-C(19) bond length is 1.57 Å. The C(14)-C(20) bond length is 1.41 Å. In the eleventh C site, C(15) is bonded in a single-bond geometry to one C(12), one C(21), one C(22), and one H(6) atom. The C(15)-C(21) bond length is 1.54 Å. The C(15)-C(22) bond length is 1.50 Å. The C(15)-H(6) bond length is 0.98 Å. In the twelfth C site, C(16) is bonded in a trigonal planar geometry to one C(12), one C(20), and one C(23) atom. The C(16)-C(20) bond length is 1.40 Å. The C(16)-C(23) bond length is 1.53 Å. In the thirteenth C site, C(17) is bonded in a trigonal planar geometry to one C(13), one C(24), and one C(25) atom. The C(17)-C(24) bond length is 1.41 Å. The C(17)-C(25) bond length is 1.40 Å. In the fourteenth C site, C(18) is bonded in a trigonal planar geometry to one C(13), one C(26), and one C(27) atom. The C(18)-C(26) bond length is 1.40 Å. The C(18)-C(27) bond length is 1.39 Å. In the fifteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14), one C(24), one C(26), and one H(7) atom. The C(19)-C(24) bond length is 1.54 Å. The C(19)-C(26) bond length is 1.46 Å. The C(19)-H(7) bond length is 0.99 Å. In the sixteenth C site, C(20) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(28) atom. The C(20)-C(28) bond length is 1.41 Å. In the seventeenth C site, C(21) is bonded in a trigonal planar geometry to one C(15), one C(29), and one C(30) atom. The C(21)-C(29) bond length is 1.39 Å. The C(21)-C(30) bond length is 1.40 Å. In the eighteenth C site, C(22) is bonded in a trigonal planar geometry to one C(15), one C(31), and one C(32) atom. The C(22)-C(31) bond length is 1.39 Å. The C(22)-C(32) bond length is 1.40 Å. In the nineteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(16), one C(29), one C(31), and one H(8) atom. The C(23)-C(29) bond length is 1.52 Å. The C(23)-C(31) bond length is 1.47 Å. The C(23)-H(8) bond length is 0.98 Å. In the twentieth C site, C(24) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(33) atom. The C(24)-C(33) bond length is 1.39 Å. In the twenty-first C site, C(25) is bonded in a distorted single-bond geometry to one C(17) and one H(9) atom. The C(25)-H(9) bond length is 0.93 Å. In the twenty-second C site, C(26) is bonded in a trigonal planar geometry to one C(18), one C(19), and one C(35) atom. The C(26)-C(35) bond length is 1.40 Å. In the twenty-third C site, C(27) is bonded in a distorted single-bond geometry to one C(18) and one H(10) atom. The C(27)-H(10) bond length is 0.93 Å. In the twenty-fourth C site, C(28) is bonded in a linear geometry to one C(20) and one C(37) atom. The C(28)-C(37) bond length is 1.22 Å. In the twenty-fifth C site, C(29) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(38) atom. The C(29)-C(38) bond length is 1.39 Å. In the twenty-sixth C site, C(30) is bonded in a distorted single-bond geometry to one C(21) and one H(11) atom. The C(30)-H(11) bond length is 0.93 Å. In the twenty-seventh C site, C(31) is bonded in a trigonal planar geometry to one C(22), one C(23), and one C(40) atom. The C(31)-C(40) bond length is 1.40 Å. In the twenty-eighth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(22), one C(41), and one H(12) atom. The C(32)-C(41) bond length is 1.40 Å. The C(32)-H(12) bond length is 0.94 Å. In the twenty-ninth C site, C(33) is bonded in a distorted single-bond geometry to one C(24) and one H(13) atom. The C(33)-H(13) bond length is 0.93 Å. In the thirtieth C site, C(35) is bonded in a distorted single-bond geometry to one C(26) and one H(15) atom. The C(35)-H(15) bond length is 0.93 Å. In the thirty-first C site, C(37) is bonded in a linear geometry to one C(28) and one C(44) atom. The C(37)-C(44) bond length is 1.39 Å. In the thirty-second C site, C(38) is bonded in a distorted trigonal planar geometry to one C(29), one C(45), and one H(17) atom. The C(38)-C(45) bond length is 1.38 Å. The C(38)-H(17) bond length is 0.94 Å. In the thirty-third C site, C(40) is bonded in a distorted single-bond geometry to one C(31) and one H(19) atom. The C(40)-H(19) bond length is 0.94 Å. In the thirty-fourth C site, C(41) is bonded in a distorted single-bond geometry to one C(32) and one H(20) atom. The C(41)-H(20) bond length is 0.93 Å. In the thirty-fifth C site, C(44) is bonded in a trigonal planar geometry to one C(37), one C(47), and one C(48) atom. The C(44)-C(47) bond length is 1.41 Å. The C(44)-C(48) bond length is 1.39 Å. In the thirty-sixth C site, C(45) is bonded in a distorted single-bond geometry to one C(38) and one H(23) atom. The C(45)-H(23) bond length is 0.94 Å. In the thirty-seventh C site, C(47) is bonded in a distorted single-bond geometry to one C(44) and one H(25) atom. The C(47)-H(25) bond length is 0.93 Å. In the thirty-eighth C site, C(48) is bonded in a distorted single-bond geometry to one C(44) and one H(26) atom. The C(48)-H(26) bond length is 0.93 Å. There are eighteen inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(25) is bonded in a single-bond geometry to one C(47) atom. In the fourth H site, H(23) is bonded in a single-bond geometry to one C(45) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(27) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(30) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(32) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(33) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(35) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(38) atom. In the sixteenth H site, H(19) is bonded in a single-bond geometry to one C(40) atom. In the seventeenth H site, H(26) is bonded in a single-bond geometry to one C(48) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(41) atom. In each C9H4 cluster, there are thirty-six inequivalent C sites. In the first C site, C(63) is bonded in a distorted single-bond geometry to one C(67) and one H(35) atom. The C(63)-C(67) bond length is 1.40 Å. The C(63)-H(35) bond length is 0.94 Å. In the second C site, C(64) is bonded in a single-bond geometry to one C(67) and one H(36) atom. The C(64)-C(67) bond length is 1.40 Å. The C(64)-H(36) bond length is 0.93 Å. In the third C site, C(67) is bonded in a trigonal planar geometry to one C(63), one C(64), and one C(70) atom. The C(67)-C(70) bond length is 1.41 Å. In the fourth C site, C(70) is bonded in a linear geometry to one C(67) and one C(71) atom. The C(70)-C(71) bond length is 1.26 Å. In the fifth C site, C(71) is bonded in a linear geometry to one C(70) and one C(72) atom. The C(71)-C(72) bond length is 1.41 Å. In the sixth C site, C(72) is bonded in a trigonal planar geometry to one C(71), one C(73), and one C(74) atom. The C(72)-C(73) bond length is 1.40 Å. The C(72)-C(74) bond length is 1.40 Å. In the seventh C site, C(73) is bonded in a trigonal planar geometry to one C(72), one C(75), and one C(76) atom. The C(73)-C(75) bond length is 1.56 Å. The C(73)-C(76) bond length is 1.40 Å. In the eighth C site, C(74) is bonded in a trigonal planar geometry to one C(72), one C(77), and one C(78) atom. The C(74)-C(77) bond length is 1.51 Å. The C(74)-C(78) bond length is 1.41 Å. In the ninth C site, C(75) is bonded in a distorted single-bond geometry to one C(73), one C(79), one C(80), and one H(41) atom. The C(75)-C(79) bond length is 1.44 Å. The C(75)-C(80) bond length is 1.53 Å. The C(75)-H(41) bond length is 0.99 Å. In the tenth C site, C(76) is bonded in a trigonal planar geometry to one C(73), one C(81), and one C(82) atom. The C(76)-C(81) bond length is 1.50 Å. The C(76)-C(82) bond length is 1.40 Å. In the eleventh C site, C(77) is bonded in a single-bond geometry to one C(74), one C(83), one C(84), and one H(42) atom. The C(77)-C(83) bond length is 1.61 Å. The C(77)-C(84) bond length is 1.49 Å. The C(77)-H(42) bond length is 0.98 Å. In the twelfth C site, C(78) is bonded in a trigonal planar geometry to one C(74), one C(82), and one C(85) atom. The C(78)-C(82) bond length is 1.39 Å. The C(78)-C(85) bond length is 1.52 Å. In the thirteenth C site, C(79) is bonded in a trigonal planar geometry to one C(75), one C(86), and one C(87) atom. The C(79)-C(86) bond length is 1.40 Å. The C(79)-C(87) bond length is 1.40 Å. In the fourteenth C site, C(80) is bonded in a trigonal planar geometry to one C(75), one C(88), and one C(89) atom. The C(80)-C(88) bond length is 1.39 Å. The C(80)-C(89) bond length is 1.40 Å. In the fifteenth C site, C(81) is bonded in a distorted single-bond geometry to one C(76), one C(86), one C(88), and one H(43) atom. The C(81)-C(86) bond length is 1.54 Å. The C(81)-C(88) bond length is 1.47 Å. The C(81)-H(43) bond length is 0.99 Å. In the sixteenth C site, C(82) is bonded in a trigonal planar geometry to one C(76), one C(78), and one C(90) atom. The C(82)-C(90) bond length is 1.44 Å. In the seventeenth C site, C(83) is bonded in a trigonal planar geometry to one C(77), one C(91), and one C(92) atom. The C(83)-C(91) bond length is 1.40 Å. The C(83)-C(92) bond length is 1.40 Å. In the eighteenth C site, C(84) is bonded in a trigonal planar geometry to one C(77), one C(93), and one C(94) atom. The C(84)-C(93) bond length is 1.40 Å. The C(84)-C(94) bond length is 1.40 Å. In the nineteenth C site, C(85) is bonded in a distorted single-bond geometry to one C(78), one C(91), one C(93), and one H(44) atom. The C(85)-C(91) bond length is 1.49 Å. The C(85)-C(93) bond length is 1.55 Å. The C(85)-H(44) bond length is 0.99 Å. In the twentieth C site, C(86) is bonded in a trigonal planar geometry to one C(79), one C(81), and one C(95) atom. The C(86)-C(95) bond length is 1.40 Å. In the twenty-first C site, C(87) is bonded in a distorted single-bond geometry to one C(79) and one H(45) atom. The C(87)-H(45) bond length is 0.93 Å. In the twenty-second C site, C(88) is bonded in a trigonal planar geometry to one C(80), one C(81), and one C(97) atom. The C(88)-C(97) bond length is 1.39 Å. In the twenty-third C site, C(89) is bonded in a distorted single-bond geometry to one C(80) and one H(46) atom. The C(89)-H(46) bond length is 0.93 Å. In the twenty-fourth C site, C(90) is bonded in a linear geometry to one C(82) and one C(99) atom. The C(90)-C(99) bond length is 1.17 Å. In the twenty-fifth C site, C(91) is bonded in a trigonal planar geometry to one C(100), one C(83), and one C(85) atom. The C(91)-C(100) bond length is 1.39 Å. In the twenty-sixth C site, C(92) is bonded in a distorted single-bond geometry to one C(83) and one H(47) atom. The C(92)-H(47) bond length is 0.92 Å. In the twenty-seventh C site, C(93) is bonded in a trigonal planar geometry to one C(102), one C(84), and one C(85) atom. The C(93)-C(102) bond length is 1.40 Å. In the twenty-eighth C site, C(94) is bonded in a distorted single-bond geometry to one C(84) and one H(48) atom. The C(94)-H(48) bond length is 0.94 Å. In the twenty-ninth C site, C(95) is bonded in a distorted single-bond geometry to one C(86) and one H(49) atom. The C(95)-H(49) bond length is 0.93 Å. In the thirtieth C site, C(97) is bonded in a distorted single-bond geometry to one C(88) and one H(51) atom. The C(97)-H(51) bond length is 0.93 Å. In the thirty-first C site, C(99) is bonded in a linear geometry to one C(106) and one C(90) atom. The C(99)-C(106) bond length is 1.40 Å. In the thirty-second C site, C(100) is bonded in a distorted single-bond geometry to one C(91) and one H(53) atom. The C(100)-H(53) bond length is 0.93 Å. In the thirty-third C site, C(102) is bonded in a distorted single-bond geometry to one C(93) and one H(55) atom. The C(102)-H(55) bond length is 0.92 Å. In the thirty-fourth C site, C(106) is bonded in a trigonal planar geometry to one C(109), one C(110), and one C(99) atom. The C(106)-C(109) bond length is 1.39 Å. The C(106)-C(110) bond length is 1.39 Å. In the thirty-fifth C site, C(109) is bonded in a distorted single-bond geometry to one C(106) and one H(61) atom. The C(109)-H(61) bond length is 0.93 Å. In the thirty-sixth C site, C(110) is bonded in a distorted single-bond geometry to one C(106) and one H(62) atom. The C(110)-H(62) bond length is 0.93 Å. There are sixteen inequivalent H sites. In the first H site, H(35) is bonded in a single-bond geometry to one C(63) atom. In the second H site, H(36) is bonded in a single-bond geometry to one C(64) atom. In the third H site, H(41) is bonded in a single-bond geometry to one C(75) atom. In the fourth H site, H(42) is bonded in a single-bond geometry to one C(77) atom. In the fifth H site, H(43) is bonded in a single-bond geometry to one C(81) atom. In the sixth H site, H(44) is bonded in a single-bond geometry to one C(85) atom. In the seventh H site, H(45) is bonded in a single-bond geometry to one C(87) atom. In the eighth H site, H(46) is bonded in a single-bond geometry to one C(89) atom. In the ninth H site, H(47) is bonded in a single-bond geometry to one C(92) atom. In the tenth H site, H(48) is bonded in a single-bond geometry to one C(94) atom. In the eleventh H site, H(49) is bonded in a single-bond geometry to one C(95) atom. In the twelfth H site, H(51) is bonded in a single-bond geometry to one C(97) atom. In the thirteenth H site, H(53) is bonded in a single-bond geometry to one C(100) atom. In the fourteenth H site, H(55) is bonded in a single-bond geometry to one C(102) atom. In the fifteenth H site, H(61) is bonded in a single-bond geometry to one C(109) atom. In the sixteenth H site, H(62) is bonded in a single-bond geometry to one C(110) atom. In the Zn3C20H12(N2O7)2 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(2), one O(2), one O(4), and one O(5) atom to form corner-sharing ZnNO3 trigonal pyramids. The corner-sharing octahedral tilt angles are 70°. The Zn(1)-N(2) bond length is 2.00 Å. The Zn(1)-O(2) bond length is 1.96 Å. The Zn(1)-O(4) bond length is 1.91 Å. The Zn(1)-O(5) bond length is 2.05 Å. In the second Zn site, Zn(3) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(3) atoms to form corner-sharing ZnO6 octahedra. Both Zn(3)-O(1) bond lengths are 2.09 Å. Both Zn(3)-O(2) bond lengths are 2.04 Å. Both Zn(3)-O(3) bond lengths are 2.04 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(4) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(4) bond length is 1.29 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(4) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.94 Å. In the fourth C site, C(4) is bonded in a single-bond geometry to one C(2) and one H(2) atom. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(68) is bonded in a 2-coordinate geometry to one N(2) and one H(39) atom. The C(68)-N(2) bond length is 1.39 Å. The C(68)-H(39) bond length is 0.94 Å. In the sixth C site, C(69) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(40) atom. The C(69)-N(2) bond length is 1.39 Å. The C(69)-H(40) bond length is 0.94 Å. In the seventh C site, C(111) is bonded in a distorted single-bond geometry to one C(113) and one H(63,64) atom. The C(111)-C(113) bond length is 1.39 Å. The C(111)-H(63,64) bond length is 0.93 Å. In the eighth C site, C(112) is bonded in a distorted single-bond geometry to one C(113) and one H(63,64) atom. The C(112)-C(113) bond length is 1.40 Å. The C(112)-H(63,64) bond length is 0.94 Å. In the ninth C site, C(113) is bonded in a trigonal planar geometry to one C(111), one C(112), and one C(114) atom. The C(113)-C(114) bond length is 1.51 Å. In the tenth C site, C(114) is bonded in a distorted bent 120 degrees geometry to one C(113), one O(3), and one O(5) atom. The C(114)-O(3) bond length is 1.29 Å. The C(114)-O(5) bond length is 1.24 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one O(2), one O(6), and one O(7) atom. The N(1)-O(2) bond length is 1.31 Å. The N(1)-O(6) bond length is 1.30 Å. The N(1)-O(7) bond length is 1.30 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(68), and one C(69) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(39) is bonded in a single-bond geometry to one C(68) atom. In the fourth H site, H(40) is bonded in a single-bond geometry to one C(69) atom. In the fifth H site, H(63,64) is bonded in a single-bond geometry to one C(111) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Zn(3) and one C(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Zn(1), one Zn(3), and one N(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(114) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the fifth O site, O(7) is bonded in a single-bond geometry to one N(1) atom. In the sixth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(114) atom. In the seventh O site, O(6) is bonded in a single-bond geometry to one N(1) atom. In the ZnC10NH6O4 cluster, Zn(2) is bonded in a trigonal bipyramidal geometry to one N(3), one O(10), one O(11), one O(8), and one O(9) atom. The Zn(2)-N(3) bond length is 2.01 Å. The Zn(2)-O(10) bond length is 2.03 Å. The Zn(2)-O(11) bond length is 2.11 Å. The Zn(2)-O(8) bond length is 2.06 Å. The Zn(2)-O(9) bond length is 2.06 Å. There are ten inequivalent C sites. In the first C site, C(49) is bonded in a distorted single-bond geometry to one C(51) and one H(27) atom. The C(49)-C(51) bond length is 1.38 Å. The C(49)-H(27) bond length is 0.93 Å. In the second C site, C(50) is bonded in a distorted single-bond geometry to one C(51) and one H(28) atom. The C(50)-C(51) bond length is 1.40 Å. The C(50)-H(28) bond length is 0.93 Å. In the third C site, C(51) is bonded in a trigonal planar geometry to one C(49), one C(50), and one C(52) atom. The C(51)-C(52) bond length is 1.51 Å. In the fourth C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(51), one O(8), and one O(9) atom. The C(52)-O(8) bond length is 1.23 Å. The C(52)-O(9) bond length is 1.20 Å. In the fifth C site, C(53) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(29) atom. The C(53)-N(3) bond length is 1.39 Å. The C(53)-H(29) bond length is 0.93 Å. In the sixth C site, C(54) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(30) atom. The C(54)-N(3) bond length is 1.39 Å. The C(54)-H(30) bond length is 0.94 Å. In the seventh C site, C(55) is bonded in a bent 120 degrees geometry to one C(58), one O(10), and one O(11) atom. The C(55)-C(58) bond length is 1.51 Å. The C(55)-O(10) bond length is 1.24 Å. The C(55)-O(11) bond length is 1.19 Å. In the eighth C site, C(58) is bonded in a trigonal planar geometry to one C(55), one C(60), and one C(61) atom. The C(58)-C(60) bond length is 1.40 Å. The C(58)-C(61) bond length is 1.41 Å. In the ninth C site, C(60) is bonded in a distorted single-bond geometry to one C(58) and one H(33) atom. The C(60)-H(33) bond length is 0.94 Å. In the tenth C site, C(61) is bonded in a distorted single-bond geometry to one C(58) and one H(34) atom. The C(61)-H(34) bond length is 0.94 Å. N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(53), and one C(54) atom. There are six inequivalent H sites. In the first H site, H(27) is bonded in a single-bond geometry to one C(49) atom. In the second H site, H(28) is bonded in a single-bond geometry to one C(50) atom. In the third H site, H(29) is bonded in a single-bond geometry to one C(53) atom. In the fourth H site, H(30) is bonded in a single-bond geometry to one C(54) atom. In the fifth H site, H(33) is bonded in a single-bond geometry to one C(60) atom. In the sixth H site, H(34) is bonded in a single-bond geometry to one C(61) atom. There are four inequivalent O sites. In the first O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(52) atom. In the second O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(52) atom. In the third O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(55) atom. In the fourth O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(55) atom. Linkers: 4 [O]C(=O)c1ccc(C#Cc2c3c(c(C#Cc4ccc(C([O])=O)cc4)c4c2[C@H]2c5ccccc5[C@@H]4c4ccccc42)[C@H]2c4ccccc4[C@@H]3c3ccccc32)cc1 ,2 c1cc(-c2ccncc2)ccn1. Metal clusters: 1 O=[N+]([O-])O[Zn]1O[C]O[Zn]2(O[C]O1)O[C]O[Zn](O[N+](=O)[O-])O[C]O2 ,1 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 6.68 A, density 0.99 g/cm3, surface area 4971.65 m2/g, accessible volume 0.52 cm3/g