AgSiH16(C4N)4AgSi2C25N4H26Si(CH)8(CH2)3(CH3)4 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, sixteen 02329_fluka molecules, four dimethyl-bis(prop-1-en-2-yl)silane molecules, four AgSi2C25N4H26 clusters, and four AgSiH16(C4N)4 clusters. In each AgSi2C25N4H26 cluster, Ag(2) is bonded in a tetrahedral geometry to one N(5), one N(6), one N(7), and one N(8) atom. The Ag(2)-N(5) bond length is 2.30 Å. The Ag(2)-N(6) bond length is 2.31 Å. The Ag(2)-N(7) bond length is 2.40 Å. The Ag(2)-N(8) bond length is 2.29 Å. There are two inequivalent Si sites. In the first Si site, Si(3) is bonded in a tetrahedral geometry to one C(31), one C(34), one C(37), and one C(38) atom. The Si(3)-C(31) bond length is 1.92 Å. The Si(3)-C(34) bond length is 1.71 Å. The Si(3)-C(37) bond length is 1.99 Å. The Si(3)-C(38) bond length is 1.85 Å. In the second Si site, Si(4) is bonded in a tetrahedral geometry to one C(45), one C(48), one C(50), and one C(52) atom. The Si(4)-C(45) bond length is 1.86 Å. The Si(4)-C(48) bond length is 1.91 Å. The Si(4)-C(50) bond length is 1.89 Å. The Si(4)-C(52) bond length is 1.91 Å. There are twenty-five inequivalent C sites. In the first C site, C(30) is bonded in a distorted single-bond geometry to one C(31) and one H(36) atom. The C(30)-C(31) bond length is 1.45 Å. The C(30)-H(36) bond length is 0.95 Å. In the second C site, C(31) is bonded in a trigonal planar geometry to one Si(3), one C(30), and one C(32) atom. The C(31)-C(32) bond length is 1.28 Å. In the third C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(37) atom. The C(32)-H(37) bond length is 0.95 Å. In the fourth C site, C(34) is bonded in a distorted tetrahedral geometry to one Si(3), one C(35), one H(39), and one H(40) atom. The C(34)-C(35) bond length is 1.30 Å. The C(34)-H(39) bond length is 0.99 Å. The C(34)-H(40) bond length is 0.99 Å. In the fifth C site, C(35) is bonded in a distorted water-like geometry to one C(34), one H(41), and one H(42) atom. The C(35)-H(41) bond length is 0.99 Å. The C(35)-H(42) bond length is 0.99 Å. In the sixth C site, C(29) is bonded in a 2-coordinate geometry to one N(5) and one H(35) atom. The C(29)-N(5) bond length is 1.34 Å. The C(29)-H(35) bond length is 0.95 Å. In the seventh C site, C(37) is bonded in a distorted water-like geometry to one Si(3) and two equivalent H(45,46) atoms. Both C(37)-H(45,46) bond lengths are 0.99 Å. In the eighth C site, C(38) is bonded in a trigonal planar geometry to one Si(3), one C(39), and one C(42) atom. The C(38)-C(39) bond length is 1.34 Å. The C(38)-C(42) bond length is 1.35 Å. In the ninth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(38), one C(40), and one H(47) atom. The C(39)-C(40) bond length is 1.40 Å. The C(39)-H(47) bond length is 0.95 Å. In the tenth C site, C(42) is bonded in a distorted single-bond geometry to one C(38) and one H(50) atom. The C(42)-H(50) bond length is 0.95 Å. In the eleventh C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(39), one N(6), and one H(48) atom. The C(40)-N(6) bond length is 1.33 Å. The C(40)-H(48) bond length is 0.95 Å. In the twelfth C site, C(50) is bonded in a distorted water-like geometry to one Si(4) and two equivalent H(60,61) atoms. Both C(50)-H(60,61) bond lengths are 0.99 Å. In the thirteenth C site, C(52) is bonded in a trigonal planar geometry to one Si(4), one C(53), and one C(56) atom. The C(52)-C(53) bond length is 1.38 Å. The C(52)-C(56) bond length is 1.37 Å. In the fourteenth C site, C(53) is bonded in a distorted single-bond geometry to one C(52), one C(54), and one H(65) atom. The C(53)-C(54) bond length is 1.31 Å. The C(53)-H(65) bond length is 0.95 Å. In the fifteenth C site, C(54) is bonded in a distorted trigonal planar geometry to one C(53), one N(8), and one H(66) atom. The C(54)-N(8) bond length is 1.39 Å. The C(54)-H(66) bond length is 0.95 Å. In the sixteenth C site, C(55) is bonded in a distorted trigonal planar geometry to one C(56), one N(8), and one H(67) atom. The C(55)-C(56) bond length is 1.35 Å. The C(55)-N(8) bond length is 1.31 Å. The C(55)-H(67) bond length is 0.95 Å. In the seventeenth C site, C(56) is bonded in a distorted single-bond geometry to one C(52), one C(55), and one H(68) atom. The C(56)-H(68) bond length is 0.95 Å. In the eighteenth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(49) atom. The C(41)-N(6) bond length is 1.30 Å. The C(41)-H(49) bond length is 0.95 Å. In the nineteenth C site, C(43) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(51) atom. The C(43)-N(7) bond length is 1.32 Å. The C(43)-H(51) bond length is 0.95 Å. In the twentieth C site, C(44) is bonded in a distorted single-bond geometry to one C(45) and one H(52) atom. The C(44)-C(45) bond length is 1.38 Å. The C(44)-H(52) bond length is 0.95 Å. In the twenty-first C site, C(45) is bonded in a trigonal planar geometry to one Si(4), one C(44), and one C(46) atom. The C(45)-C(46) bond length is 1.39 Å. In the twenty-second C site, C(46) is bonded in a distorted single-bond geometry to one C(45) and one H(53) atom. The C(46)-H(53) bond length is 0.95 Å. In the twenty-third C site, C(47) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(54) atom. The C(47)-N(7) bond length is 1.30 Å. The C(47)-H(54) bond length is 0.95 Å. In the twenty-fourth C site, C(48) is bonded in a distorted water-like geometry to one Si(4) and two equivalent H(55,56) atoms. Both C(48)-H(55,56) bond lengths are 0.99 Å. In the twenty-fifth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(38) atom. The C(33)-N(5) bond length is 1.31 Å. The C(33)-H(38) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(7) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(43), and one C(47) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Ag(2), one C(29), and one C(33) atom. In the third N site, N(6) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(40), and one C(41) atom. In the fourth N site, N(8) is bonded in a trigonal planar geometry to one Ag(2), one C(54), and one C(55) atom. There are twenty-three inequivalent H sites. In the first H site, H(36) is bonded in a single-bond geometry to one C(30) atom. In the second H site, H(39) is bonded in a single-bond geometry to one C(34) atom. In the third H site, H(40) is bonded in a single-bond geometry to one C(34) atom. In the fourth H site, H(37) is bonded in a single-bond geometry to one C(32) atom. In the fifth H site, H(41) is bonded in a single-bond geometry to one C(35) atom. In the sixth H site, H(45,46) is bonded in a single-bond geometry to one C(37) atom. In the seventh H site, H(42) is bonded in a single-bond geometry to one C(35) atom. In the eighth H site, H(47) is bonded in a single-bond geometry to one C(39) atom. In the ninth H site, H(48) is bonded in a single-bond geometry to one C(40) atom. In the tenth H site, H(52) is bonded in a single-bond geometry to one C(44) atom. In the eleventh H site, H(53) is bonded in a single-bond geometry to one C(46) atom. In the twelfth H site, H(55,56) is bonded in a single-bond geometry to one C(48) atom. In the thirteenth H site, H(50) is bonded in a single-bond geometry to one C(42) atom. In the fourteenth H site, H(38) is bonded in a single-bond geometry to one C(33) atom. In the fifteenth H site, H(60,61) is bonded in a single-bond geometry to one C(50) atom. In the sixteenth H site, H(54) is bonded in a single-bond geometry to one C(47) atom. In the seventeenth H site, H(65) is bonded in a single-bond geometry to one C(53) atom. In the eighteenth H site, H(35) is bonded in a single-bond geometry to one C(29) atom. In the nineteenth H site, H(66) is bonded in a single-bond geometry to one C(54) atom. In the twentieth H site, H(67) is bonded in a single-bond geometry to one C(55) atom. In the twenty-first H site, H(68) is bonded in a single-bond geometry to one C(56) atom. In the twenty-second H site, H(49) is bonded in a single-bond geometry to one C(41) atom. In the twenty-third H site, H(51) is bonded in a single-bond geometry to one C(43) atom. In each AgSiH16(C4N)4 cluster, Ag(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Ag(1)-N(1) bond length is 2.32 Å. The Ag(1)-N(2) bond length is 2.38 Å. The Ag(1)-N(3) bond length is 2.32 Å. The Ag(1)-N(4) bond length is 2.27 Å. Si(2) is bonded in a tetrahedral geometry to one C(17), one C(20), one C(22), and one C(24) atom. The Si(2)-C(17) bond length is 1.91 Å. The Si(2)-C(20) bond length is 1.88 Å. The Si(2)-C(22) bond length is 1.86 Å. The Si(2)-C(24) bond length is 1.87 Å. There are sixteen inequivalent C sites. In the first C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(15)-N(3) bond length is 1.32 Å. The C(15)-H(17) bond length is 0.95 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1) atom. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(4) atom. The C(5)-N(2) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.95 Å. In the fourth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(20) atom. The C(19)-N(3) bond length is 1.26 Å. The C(19)-H(20) bond length is 0.95 Å. In the fifth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(14) atom. The C(12)-N(1) bond length is 1.32 Å. The C(12)-H(14) bond length is 0.95 Å. In the sixth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(15) atom. The C(13)-N(1) bond length is 1.35 Å. The C(13)-H(15) bond length is 0.95 Å. In the seventh C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(18) atom. The C(16)-C(17) bond length is 1.22 Å. The C(16)-H(18) bond length is 0.95 Å. In the eighth C site, C(17) is bonded in a trigonal planar geometry to one Si(2), one C(16), and one C(18) atom. The C(17)-C(18) bond length is 1.36 Å. In the ninth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(19) atom. The C(18)-H(19) bond length is 0.95 Å. In the tenth C site, C(20) is bonded in a distorted water-like geometry to one Si(2) and two equivalent H(21,22) atoms. Both C(20)-H(21,22) bond lengths are 0.99 Å. In the eleventh C site, C(22) is bonded in a distorted water-like geometry to one Si(2), one H(26), and one H(27) atom. The C(22)-H(26) bond length is 0.99 Å. The C(22)-H(27) bond length is 0.99 Å. In the twelfth C site, C(24) is bonded in a trigonal planar geometry to one Si(2), one C(25), and one C(28) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-C(28) bond length is 1.34 Å. In the thirteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(24), one C(26), and one H(31) atom. The C(25)-C(26) bond length is 1.33 Å. The C(25)-H(31) bond length is 0.95 Å. In the fourteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(25), one N(4), and one H(32) atom. The C(26)-N(4) bond length is 1.30 Å. The C(26)-H(32) bond length is 0.95 Å. In the fifteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(33) atom. The C(27)-N(4) bond length is 1.31 Å. The C(27)-H(33) bond length is 0.95 Å. In the sixteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(24) and one H(34) atom. The C(28)-H(34) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(12), and one C(13) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(15), and one C(19) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(26), and one C(27) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(21,22) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(20) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(26) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(27) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(31) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(32) is bonded in a single-bond geometry to one C(26) atom. In the fourteenth H site, H(34) is bonded in a single-bond geometry to one C(28) atom. In the fifteenth H site, H(33) is bonded in a single-bond geometry to one C(27) atom. Linkers: 8 CC[Si](CC)(c1ccncc1)c1ccncc1 ,8 c1cc([Si]2(c3ccncc3)CCCC2)ccn1. Metal clusters: 8 [Ag]. The MOF has largest included sphere 5.05 A, density 1.15 g/cm3, surface area 5207.54 m2/g, accessible volume 0.30 cm3/g