CuC24H24(N2O)4(CH)4 is Indium-derived structured and crystallizes in the orthorhombic Pca2_1 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four CuC24H24(N2O)4 clusters. In each CuC24H24(N2O)4 cluster, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one N(5), and one N(6) atom. The Cu(1)-N(1) bond length is 2.06 Å. The Cu(1)-N(2) bond length is 2.02 Å. The Cu(1)-N(5) bond length is 2.04 Å. The Cu(1)-N(6) bond length is 2.03 Å. There are twenty-four inequivalent C sites. In the first C site, C(13) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(11,12) atoms. The C(13)-N(3) bond length is 1.47 Å. Both C(13)-H(11,12) bond lengths are 0.97 Å. In the second C site, C(15) is bonded in a trigonal planar geometry to one C(16), one C(19), and one C(20) atom. The C(15)-C(16) bond length is 1.37 Å. The C(15)-C(19) bond length is 1.38 Å. The C(15)-C(20) bond length is 1.48 Å. In the third C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(5), and one H(15) atom. The C(16)-N(5) bond length is 1.34 Å. The C(16)-H(15) bond length is 0.93 Å. In the fourth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(16) atom. The C(17)-N(5) bond length is 1.37 Å. The C(17)-H(16) bond length is 0.93 Å. In the fifth C site, C(19) is bonded in a single-bond geometry to one C(15) and one H(18) atom. The C(19)-H(18) bond length is 0.93 Å. In the sixth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(7), and one O(3) atom. The C(20)-N(7) bond length is 1.36 Å. The C(20)-O(3) bond length is 1.24 Å. In the seventh C site, C(27) is bonded in a distorted trigonal non-coplanar geometry to one N(7) and two equivalent H(25,26) atoms. The C(27)-N(7) bond length is 1.44 Å. Both C(27)-H(25,26) bond lengths are 0.97 Å. In the eighth C site, C(14) is bonded in a 3-coordinate geometry to one N(4) and two equivalent H(13,14) atoms. The C(14)-N(4) bond length is 1.48 Å. Both C(14)-H(13,14) bond lengths are 0.97 Å. In the ninth C site, C(28) is bonded in a 3-coordinate geometry to one N(8) and two equivalent H(27,28) atoms. The C(28)-N(8) bond length is 1.45 Å. Both C(28)-H(27,28) bond lengths are 0.97 Å. In the tenth C site, C(21) is bonded in a trigonal planar geometry to one C(22), one C(25), and one C(26) atom. The C(21)-C(22) bond length is 1.37 Å. The C(21)-C(25) bond length is 1.39 Å. The C(21)-C(26) bond length is 1.50 Å. In the eleventh C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(6), and one H(19) atom. The C(22)-N(6) bond length is 1.35 Å. The C(22)-H(19) bond length is 0.93 Å. In the twelfth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(20) atom. The C(23)-N(6) bond length is 1.36 Å. The C(23)-H(20) bond length is 0.93 Å. In the thirteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(21) and one H(22) atom. The C(25)-H(22) bond length is 0.93 Å. In the fourteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(8), and one O(4) atom. The C(26)-N(8) bond length is 1.34 Å. The C(26)-O(4) bond length is 1.22 Å. In the fifteenth C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(6) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-C(5) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.48 Å. In the sixteenth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one H(1) atom. The C(2)-N(1) bond length is 1.33 Å. The C(2)-H(1) bond length is 0.93 Å. In the seventeenth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(3)-N(1) bond length is 1.36 Å. The C(3)-H(2) bond length is 0.93 Å. In the eighteenth C site, C(5) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(5)-H(4) bond length is 0.93 Å. In the nineteenth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(3), and one O(1) atom. The C(6)-N(3) bond length is 1.35 Å. The C(6)-O(1) bond length is 1.24 Å. In the twentieth C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(8) atom. The C(7)-C(11) bond length is 1.41 Å. The C(7)-C(12) bond length is 1.51 Å. The C(7)-C(8) bond length is 1.34 Å. In the twenty-first C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(2), and one H(5) atom. The C(8)-N(2) bond length is 1.37 Å. The C(8)-H(5) bond length is 0.93 Å. In the twenty-second C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(9)-N(2) bond length is 1.34 Å. The C(9)-H(6) bond length is 0.93 Å. In the twenty-third C site, C(11) is bonded in a distorted single-bond geometry to one C(7) and one H(8) atom. The C(11)-H(8) bond length is 0.93 Å. In the twenty-fourth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(4), and one O(2) atom. The C(12)-N(4) bond length is 1.32 Å. The C(12)-O(2) bond length is 1.23 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(8), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(13), one C(6), and one H(9) atom. The N(3)-H(9) bond length is 0.86 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(12), one C(14), and one H(10) atom. The N(4)-H(10) bond length is 0.86 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(1), one C(16), and one C(17) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(22), and one C(23) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(20), one C(27), and one H(23) atom. The N(7)-H(23) bond length is 0.86 Å. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(26), one C(28), and one H(24) atom. The N(8)-H(24) bond length is 0.86 Å. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(11,12) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(4) atom. In the eleventh H site, H(13,14) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one N(7) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(23) atom. In the fifteenth H site, H(25,26) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(22) is bonded in a single-bond geometry to one C(25) atom. In the seventeenth H site, H(24) is bonded in a single-bond geometry to one N(8) atom. In the eighteenth H site, H(27,28) is bonded in a single-bond geometry to one C(28) atom. In the nineteenth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the twentieth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(3) is bonded in a single-bond geometry to one C(20) atom. In the third O site, O(2) is bonded in a single-bond geometry to one C(12) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(26) atom. Linkers: 8 O=C(NCCNC(=O)c1cccnc1)c1cccnc1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 5.52 A, density 1.07 g/cm3, surface area 5134.48 m2/g, accessible volume 0.40 cm3/g