Cu3C19N8H20CH crystallizes in the triclinic P-1 space group. The structure consists of two 02329_fluka molecules inside a Cu3C19N8H20 framework. In each Cu3C19N8H20 framework, there are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one N(5) atom. The Cu(1)-C(2) bond length is 1.86 Å. The Cu(1)-N(1) bond length is 1.99 Å. The Cu(1)-N(5) bond length is 2.00 Å. In the second Cu site, Cu(2) is bonded in a trigonal planar geometry to one C(20), one N(4), and one N(7) atom. The Cu(2)-C(20) bond length is 1.86 Å. The Cu(2)-N(4) bond length is 2.01 Å. The Cu(2)-N(7) bond length is 1.93 Å. In the third Cu site, Cu(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one N(8) atom. The Cu(3)-C(4) bond length is 1.87 Å. The Cu(3)-N(2) bond length is 2.07 Å. The Cu(3)-N(8) bond length is 1.91 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(11), one C(5), and one N(4) atom. The C(1)-C(11) bond length is 1.49 Å. The C(1)-C(5) bond length is 1.40 Å. The C(1)-N(4) bond length is 1.34 Å. In the second C site, C(2) is bonded in a linear geometry to one Cu(1) and one N(7) atom. The C(2)-N(7) bond length is 1.14 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(16), one C(9), and one N(1) atom. The C(3)-C(16) bond length is 1.49 Å. The C(3)-C(9) bond length is 1.41 Å. The C(3)-N(1) bond length is 1.32 Å. In the fourth C site, C(4) is bonded in a linear geometry to one Cu(3) and one N(5) atom. The C(4)-N(5) bond length is 1.13 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(7), and one C(8) atom. The C(5)-C(7) bond length is 1.37 Å. The C(5)-C(8) bond length is 1.51 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(18), one C(9), and one N(6) atom. The C(6)-C(18) bond length is 1.49 Å. The C(6)-C(9) bond length is 1.38 Å. The C(6)-N(6) bond length is 1.35 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(17), one C(5), and one N(3) atom. The C(7)-C(17) bond length is 1.52 Å. The C(7)-N(3) bond length is 1.33 Å. In the eighth C site, C(8) is bonded in a water-like geometry to one C(10), one C(5), one H(3), and one H(4) atom. The C(8)-C(10) bond length is 1.50 Å. The C(8)-H(3) bond length is 0.97 Å. The C(8)-H(4) bond length is 0.97 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(13), one C(3), and one C(6) atom. The C(9)-C(13) bond length is 1.50 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(15), one C(8), and one N(2) atom. The C(10)-C(15) bond length is 1.38 Å. The C(10)-N(2) bond length is 1.34 Å. In the eleventh C site, C(11) is bonded in a trigonal non-coplanar geometry to one C(1) and three equivalent H(5,6,7) atoms. All C(11)-H(5,6,7) bond lengths are 0.96 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(13), one C(14), and one N(2) atom. The C(12)-C(13) bond length is 1.51 Å. The C(12)-C(14) bond length is 1.38 Å. The C(12)-N(2) bond length is 1.33 Å. In the thirteenth C site, C(13) is bonded in a water-like geometry to one C(12); one C(9); and two equivalent H(8,9) atoms. Both C(13)-H(8,9) bond lengths are 0.97 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(14)-H(10) bond length is 0.93 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one H(11) atom. The C(15)-H(11) bond length is 0.93 Å. In the sixteenth C site, C(16) is bonded in a trigonal non-coplanar geometry to one C(3) and three equivalent H(12,13,14) atoms. All C(16)-H(12,13,14) bond lengths are 0.96 Å. In the seventeenth C site, C(17) is bonded in a trigonal non-coplanar geometry to one C(7), one H(15), one H(16), and one H(17) atom. The C(17)-H(15) bond length is 0.96 Å. The C(17)-H(16) bond length is 0.96 Å. The C(17)-H(17) bond length is 0.96 Å. In the eighteenth C site, C(18) is bonded in a trigonal non-coplanar geometry to one C(6) and three equivalent H(18,19,20) atoms. All C(18)-H(18,19,20) bond lengths are 0.96 Å. In the nineteenth C site, C(20) is bonded in a linear geometry to one Cu(2) and one N(8) atom. The C(20)-N(8) bond length is 1.15 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Cu(1), one C(3), and one N(6) atom. The N(1)-N(6) bond length is 1.34 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(3), one C(10), and one C(12) atom. In the third N site, N(3) is bonded in a 2-coordinate geometry to one C(7), one N(4), and one H(1) atom. The N(3)-N(4) bond length is 1.36 Å. The N(3)-H(1) bond length is 0.86 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(1), and one N(3) atom. In the fifth N site, N(5) is bonded in a bent 150 degrees geometry to one Cu(1) and one C(4) atom. In the sixth N site, N(6) is bonded in a 2-coordinate geometry to one C(6), one N(1), and one H(2) atom. The N(6)-H(2) bond length is 0.86 Å. In the seventh N site, N(7) is bonded in a linear geometry to one Cu(2) and one C(2) atom. In the eighth N site, N(8) is bonded in a linear geometry to one Cu(3) and one C(20) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5,6,7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8,9) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(12,13,14) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(18,19,20) is bonded in a single-bond geometry to one C(18) atom. Linkers: 2 Cc1n[nH]c(C)c1Cc1cccc(Cc2c(C)n[nH]c2C)n1. Metal clusters: 6 [Cu]. The MOF has largest included sphere 5.12 A, density 1.33 g/cm3, surface area 4714.99 m2/g, accessible volume 0.35 cm3/g