Zn3C30H13(NO8)2(C3H2)4C9H6NCH3CN crystallizes in the triclinic P-1 space group. The structure consists of four 2,3-dimethyl-1,3-butadiene molecules; two dimethylamine molecules; and two schembl1705614 molecules inside a Zn3C30H13(NO8)2 framework. In the Zn3C30H13(NO8)2 framework, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal non-coplanar geometry to one N(4), one O(10), and one O(4) atom. The Zn(1)-N(4) bond length is 2.07 Å. The Zn(1)-O(10) bond length is 1.99 Å. The Zn(1)-O(4) bond length is 1.96 Å. In the second Zn site, Zn(2) is bonded in a 2-coordinate geometry to one O(15) and one O(3) atom. The Zn(2)-O(15) bond length is 2.04 Å. The Zn(2)-O(3) bond length is 1.99 Å. In the third Zn site, Zn(3) is bonded in a tetrahedral geometry to one N(2), one O(6), one O(7), and one O(9) atom. The Zn(3)-N(2) bond length is 2.07 Å. The Zn(3)-O(6) bond length is 2.02 Å. The Zn(3)-O(7) bond length is 1.99 Å. The Zn(3)-O(9) bond length is 2.01 Å. There are thirty inequivalent C sites. In the first C site, C(46) is bonded in a distorted single-bond geometry to one C(34), one C(48), and one H(10) atom. The C(46)-C(34) bond length is 1.45 Å. The C(46)-C(48) bond length is 1.41 Å. The C(46)-H(10) bond length is 0.93 Å. In the second C site, C(48) is bonded in a trigonal planar geometry to one C(18), one C(34), and one C(46) atom. The C(48)-C(18) bond length is 1.50 Å. The C(48)-C(34) bond length is 1.40 Å. In the third C site, C(49) is bonded in a distorted single-bond geometry to one C(45) and one H(11) atom. The C(49)-C(45) bond length is 1.42 Å. The C(49)-H(11) bond length is 0.93 Å. In the fourth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(11), and one O(15) atom. The C(50)-C(12) bond length is 1.49 Å. The C(50)-O(11) bond length is 1.26 Å. The C(50)-O(15) bond length is 1.27 Å. In the fifth C site, C(53) is bonded in a distorted single-bond geometry to one C(45) and one H(9) atom. The C(53)-C(45) bond length is 1.43 Å. The C(53)-H(9) bond length is 0.93 Å. In the sixth C site, C(2) is bonded in a trigonal planar geometry to one C(22), one C(32), and one C(4) atom. The C(2)-C(22) bond length is 1.43 Å. The C(2)-C(32) bond length is 1.43 Å. The C(2)-C(4) bond length is 1.50 Å. In the seventh C site, C(3) is bonded in a distorted single-bond geometry to one C(12), one C(22), and one H(18) atom. The C(3)-C(12) bond length is 1.42 Å. The C(3)-C(22) bond length is 1.39 Å. The C(3)-H(18) bond length is 0.93 Å. In the eighth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(14), and one O(6) atom. The C(4)-O(14) bond length is 1.24 Å. The C(4)-O(6) bond length is 1.27 Å. In the ninth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(1), and one O(10) atom. The C(6)-C(22) bond length is 1.52 Å. The C(6)-O(1) bond length is 1.25 Å. The C(6)-O(10) bond length is 1.26 Å. In the tenth C site, C(9) is bonded in a trigonal planar geometry to one C(12), one C(19), and one C(32) atom. The C(9)-C(12) bond length is 1.43 Å. The C(9)-C(19) bond length is 1.51 Å. The C(9)-C(32) bond length is 1.40 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(35) atom. The C(11)-C(16) bond length is 1.51 Å. The C(11)-C(20) bond length is 1.42 Å. The C(11)-C(35) bond length is 1.38 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(3), one C(50), and one C(9) atom. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(21), one C(31), and one C(45) atom. The C(13)-C(21) bond length is 1.41 Å. The C(13)-C(31) bond length is 1.39 Å. The C(13)-C(45) bond length is 1.50 Å. In the fourteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(2), and one O(7) atom. The C(16)-O(2) bond length is 1.28 Å. The C(16)-O(7) bond length is 1.27 Å. In the fifteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(21) atom. The C(17)-N(4) bond length is 1.37 Å. The C(17)-H(21) bond length is 0.93 Å. In the sixteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(48), one O(4), and one O(5) atom. The C(18)-O(4) bond length is 1.26 Å. The C(18)-O(5) bond length is 1.23 Å. In the seventeenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(13), and one O(9) atom. The C(19)-O(13) bond length is 1.26 Å. The C(19)-O(9) bond length is 1.24 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(11), one C(35), and one H(6) atom. The C(20)-C(35) bond length is 1.44 Å. The C(20)-H(6) bond length is 0.93 Å. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(13), one C(44), and one H(3) atom. The C(21)-C(44) bond length is 1.39 Å. The C(21)-H(3) bond length is 0.93 Å. In the twentieth C site, C(22) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(6) atom. In the twenty-first C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(4) atom. The C(24)-N(4) bond length is 1.36 Å. The C(24)-H(4) bond length is 0.93 Å. In the twenty-second C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(23) atom. The C(25)-N(2) bond length is 1.40 Å. The C(25)-H(23) bond length is 0.93 Å. In the twenty-third C site, C(31) is bonded in a distorted single-bond geometry to one C(13) and one H(22) atom. The C(31)-H(22) bond length is 0.93 Å. In the twenty-fourth C site, C(32) is bonded in a distorted single-bond geometry to one C(2), one C(9), and one H(20) atom. The C(32)-H(20) bond length is 0.93 Å. In the twenty-fifth C site, C(34) is bonded in a trigonal planar geometry to one C(42), one C(46), and one C(48) atom. The C(34)-C(42) bond length is 1.49 Å. In the twenty-sixth C site, C(35) is bonded in a trigonal planar geometry to one C(11), one C(20), and one C(37) atom. The C(35)-C(37) bond length is 1.50 Å. In the twenty-seventh C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(16), and one O(8) atom. The C(37)-O(16) bond length is 1.25 Å. The C(37)-O(8) bond length is 1.27 Å. In the twenty-eighth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(34), one O(12), and one O(3) atom. The C(42)-O(12) bond length is 1.25 Å. The C(42)-O(3) bond length is 1.26 Å. In the twenty-ninth C site, C(44) is bonded in a distorted trigonal planar geometry to one C(21), one N(2), and one H(16) atom. The C(44)-N(2) bond length is 1.37 Å. The C(44)-H(16) bond length is 0.93 Å. In the thirtieth C site, C(45) is bonded in a trigonal planar geometry to one C(13), one C(49), and one C(53) atom. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Zn(3), one C(25), and one C(44) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(17), and one C(24) atom. There are thirteen inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(21) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(24) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(20) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(53) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(46) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(49) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(44) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(3) atom. In the ninth H site, H(20) is bonded in a single-bond geometry to one C(32) atom. In the tenth H site, H(21) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(22) is bonded in a single-bond geometry to one C(31) atom. In the twelfth H site, H(23) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(30) is bonded in a single-bond geometry to one O(9) atom. The H(30)-O(9) bond length is 0.85 Å. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(16) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Zn(2) and one C(42) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(18) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(18) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(4) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(16) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(37) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Zn(3), one C(19), and one H(30) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one C(50) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one C(42) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one C(4) atom. In the fifteenth O site, O(15) is bonded in a distorted water-like geometry to one Zn(2) and one C(50) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one C(37) atom. Linkers: 2 [CH]1C=C(c2ccc(N(c3ccc(-c4ccncc4)cc3)c3ccc(-c4ccncc4)cc3)cc2)C=CN1 ,2 [O]C(=O)c1cc(C([O])=O)c(C([O])=O)cc1C([O])=O ,2 [O]C(=O)c1cc(C([O])=O)c(C(=O)O)cc1C([O])=O. Metal clusters: 4 O=[C]O[Zn]O[C]=O ,2 O=[C]O.O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 5.61 A, density 1.24 g/cm3, surface area 4549.93 m2/g, accessible volume 0.36 cm3/g