CoC22H18(N3S)2CoC16H13(N3S)2(C4H3)4C6H5 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight isobutylene molecules, two methane;pentane molecules, two CoC16H13(N3S)2 clusters, and two CoC22H18(N3S)2 clusters. In each CoC16H13(N3S)2 cluster, Co(2) is bonded in an octahedral geometry to one N(10), one N(11), one N(12), one N(7), one N(8), and one N(9) atom. The Co(2)-N(10) bond length is 2.22 Å. The Co(2)-N(11) bond length is 2.08 Å. The Co(2)-N(12) bond length is 2.08 Å. The Co(2)-N(7) bond length is 2.20 Å. The Co(2)-N(8) bond length is 2.20 Å. The Co(2)-N(9) bond length is 2.19 Å. There are sixteen inequivalent C sites. In the first C site, C(31) is bonded in a 3-coordinate geometry to one C(36), one N(7), and one H(25) atom. The C(31)-C(36) bond length is 0.95 Å. The C(31)-N(7) bond length is 1.32 Å. The C(31)-H(25) bond length is 0.93 Å. In the second C site, C(35) is bonded in a 3-coordinate geometry to one C(39), one N(7), and one H(28) atom. The C(35)-C(39) bond length is 0.91 Å. The C(35)-N(7) bond length is 1.32 Å. The C(35)-H(28) bond length is 0.93 Å. In the third C site, C(36) is bonded in a 3-coordinate geometry to one C(31), one N(7), and one H(29) atom. The C(36)-N(7) bond length is 1.33 Å. The C(36)-H(29) bond length is 0.93 Å. In the fourth C site, C(39) is bonded in a 3-coordinate geometry to one C(35), one N(7), and one H(32) atom. The C(39)-N(7) bond length is 1.30 Å. The C(39)-H(32) bond length is 0.93 Å. In the fifth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(34) atom. The C(41)-N(8) bond length is 1.34 Å. The C(41)-H(34) bond length is 0.93 Å. In the sixth C site, C(42) is bonded in a distorted single-bond geometry to one C(43) and one H(35) atom. The C(42)-C(43) bond length is 1.39 Å. The C(42)-H(35) bond length is 0.93 Å. In the seventh C site, C(43) is bonded in a trigonal planar geometry to one C(42), one C(44), and one C(46) atom. The C(43)-C(44) bond length is 1.34 Å. The C(43)-C(46) bond length is 1.48 Å. In the eighth C site, C(44) is bonded in a distorted single-bond geometry to one C(43), one C(45), and one H(36) atom. The C(44)-C(45) bond length is 1.34 Å. The C(44)-H(36) bond length is 0.93 Å. In the ninth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(44), one N(8), and one H(37) atom. The C(45)-N(8) bond length is 1.33 Å. The C(45)-H(37) bond length is 0.93 Å. In the tenth C site, C(46) is bonded in a distorted single-bond geometry to one C(43) and one H(38) atom. The C(46)-H(38) bond length is 0.93 Å. In the eleventh C site, C(47) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(39) atom. The C(47)-N(9) bond length is 1.32 Å. The C(47)-H(39) bond length is 0.93 Å. In the twelfth C site, C(51) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(42) atom. The C(51)-N(9) bond length is 1.34 Å. The C(51)-H(42) bond length is 0.93 Å. In the thirteenth C site, C(53) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(44) atom. The C(53)-N(10) bond length is 1.29 Å. The C(53)-H(44) bond length is 0.93 Å. In the fourteenth C site, C(57) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(20,47) atom. The C(57)-N(10) bond length is 1.28 Å. The C(57)-H(20,47) bond length is 0.93 Å. In the fifteenth C site, C(59) is bonded in a distorted single-bond geometry to one N(11) and one S(3) atom. The C(59)-N(11) bond length is 1.13 Å. The C(59)-S(3) bond length is 1.62 Å. In the sixteenth C site, C(60) is bonded in a distorted single-bond geometry to one N(12) and one S(4) atom. The C(60)-N(12) bond length is 1.15 Å. The C(60)-S(4) bond length is 1.62 Å. There are six inequivalent N sites. In the first N site, N(7) is bonded in a 5-coordinate geometry to one Co(2), one C(31), one C(35), one C(36), and one C(39) atom. In the second N site, N(8) is bonded in a trigonal planar geometry to one Co(2), one C(41), and one C(45) atom. In the third N site, N(9) is bonded in a trigonal planar geometry to one Co(2), one C(47), and one C(51) atom. In the fourth N site, N(10) is bonded in a trigonal planar geometry to one Co(2), one C(53), and one C(57) atom. In the fifth N site, N(11) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one C(59) atom. In the sixth N site, N(12) is bonded in a bent 150 degrees geometry to one Co(2) and one C(60) atom. There are thirteen inequivalent H sites. In the first H site, H(20,47) is bonded in a single-bond geometry to one C(23) atom. The H(20,47)-C(23) bond length is 0.93 Å. In the second H site, H(25) is bonded in a single-bond geometry to one C(31) atom. In the third H site, H(28) is bonded in a single-bond geometry to one C(35) atom. In the fourth H site, H(29) is bonded in a single-bond geometry to one C(36) atom. In the fifth H site, H(32) is bonded in a single-bond geometry to one C(39) atom. In the sixth H site, H(34) is bonded in a single-bond geometry to one C(41) atom. In the seventh H site, H(35) is bonded in a single-bond geometry to one C(42) atom. In the eighth H site, H(36) is bonded in a single-bond geometry to one C(44) atom. In the ninth H site, H(37) is bonded in a single-bond geometry to one C(45) atom. In the tenth H site, H(38) is bonded in a single-bond geometry to one C(46) atom. In the eleventh H site, H(39) is bonded in a single-bond geometry to one C(47) atom. In the twelfth H site, H(42) is bonded in a single-bond geometry to one C(51) atom. In the thirteenth H site, H(44) is bonded in a single-bond geometry to one C(53) atom. There are two inequivalent S sites. In the first S site, S(3) is bonded in a single-bond geometry to one C(59) atom. In the second S site, S(4) is bonded in a single-bond geometry to one C(60) atom. In each CoC22H18(N3S)2 cluster, Co(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one N(5), and one N(6) atom. The Co(1)-N(1) bond length is 2.20 Å. The Co(1)-N(2) bond length is 2.21 Å. The Co(1)-N(3) bond length is 2.19 Å. The Co(1)-N(4) bond length is 2.23 Å. The Co(1)-N(5) bond length is 2.08 Å. The Co(1)-N(6) bond length is 2.07 Å. There are twenty-two inequivalent C sites. In the first C site, C(30) is bonded in a distorted single-bond geometry to one N(6) and one S(2) atom. The C(30)-N(6) bond length is 1.15 Å. The C(30)-S(2) bond length is 1.63 Å. In the second C site, C(29) is bonded in a distorted single-bond geometry to one N(5) and one S(1) atom. The C(29)-N(5) bond length is 1.13 Å. The C(29)-S(1) bond length is 1.62 Å. In the third C site, C(10) is bonded in a distorted single-bond geometry to one C(3) and one H(9) atom. The C(10)-C(3) bond length is 1.47 Å. The C(10)-H(9) bond length is 0.93 Å. In the fourth C site, C(3) is bonded in a 5-coordinate geometry to one C(10), one C(2), one C(4), one C(7), and one C(8) atom. The C(3)-C(2) bond length is 1.31 Å. The C(3)-C(4) bond length is 1.38 Å. The C(3)-C(7) bond length is 1.55 Å. The C(3)-C(8) bond length is 1.14 Å. In the fifth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one C(5), one C(8), and one H(3) atom. The C(4)-C(5) bond length is 1.32 Å. The C(4)-C(8) bond length is 0.92 Å. The C(4)-H(3) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a 2-coordinate geometry to one C(2), one C(3), and one H(6) atom. The C(7)-C(2) bond length is 1.04 Å. The C(7)-H(6) bond length is 0.93 Å. In the seventh C site, C(1) is bonded in a 3-coordinate geometry to one C(6), one N(1), and one H(1) atom. The C(1)-C(6) bond length is 0.95 Å. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.93 Å. In the eighth C site, C(5) is bonded in a 4-coordinate geometry to one C(4), one C(9), one N(1), and one H(4) atom. The C(5)-C(9) bond length is 0.92 Å. The C(5)-N(1) bond length is 1.32 Å. The C(5)-H(4) bond length is 0.93 Å. In the ninth C site, C(6) is bonded in a 3-coordinate geometry to one C(1), one N(1), and one H(5) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-H(5) bond length is 0.93 Å. In the tenth C site, C(9) is bonded in a 3-coordinate geometry to one C(5), one N(1), and one H(8) atom. The C(9)-N(1) bond length is 1.31 Å. The C(9)-H(8) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(11)-N(2) bond length is 1.33 Å. The C(11)-H(10) bond length is 0.93 Å. In the twelfth C site, C(8) is bonded in a 2-coordinate geometry to one C(3), one C(4), and one H(7) atom. The C(8)-H(7) bond length is 0.93 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(15), and one H(12) atom. The C(14)-C(13) bond length is 1.35 Å. The C(14)-C(15) bond length is 1.35 Å. The C(14)-H(12) bond length is 0.93 Å. In the fourteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(2), and one H(13) atom. The C(15)-N(2) bond length is 1.33 Å. The C(15)-H(13) bond length is 0.93 Å. In the fifteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(12) bond length is 1.39 Å. The C(13)-C(16) bond length is 1.48 Å. In the sixteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(15) atom. The C(17)-N(3) bond length is 1.32 Å. The C(17)-H(15) bond length is 0.93 Å. In the seventeenth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(12)-H(11) bond length is 0.93 Å. In the eighteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(18) atom. The C(21)-N(3) bond length is 1.34 Å. The C(21)-H(18) bond length is 0.93 Å. In the nineteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(13) and one H(14) atom. The C(16)-H(14) bond length is 0.93 Å. In the twentieth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(20,47) atom. The C(23)-N(4) bond length is 1.28 Å. In the twenty-first C site, C(2) is bonded in a 2-coordinate geometry to one C(3), one C(7), and one H(2) atom. The C(2)-H(2) bond length is 0.93 Å. In the twenty-second C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(23) atom. The C(27)-N(4) bond length is 1.28 Å. The C(27)-H(23) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a 5-coordinate geometry to one Co(1), one C(1), one C(5), one C(6), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(11), and one C(15) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(17), and one C(21) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(23), and one C(27) atom. In the fifth N site, N(5) is bonded in a distorted linear geometry to one Co(1) and one C(29) atom. In the sixth N site, N(6) is bonded in a bent 150 degrees geometry to one Co(1) and one C(30) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(21) atom. In the seventeenth H site, H(20,47) is bonded in a single-bond geometry to one C(23) atom. In the eighteenth H site, H(23) is bonded in a single-bond geometry to one C(27) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a single-bond geometry to one C(29) atom. In the second S site, S(2) is bonded in a single-bond geometry to one C(30) atom. Linkers: 4 C(=C/c1ccncc1)\c1ccncc1 ,1 [CH][CH].[C]1[C@@H]2[CH][CH][C@@H]2[N][C@@H]2[CH][CH][C@H]12.[N][C@H]1[CH][CH][C@H]1[C]C1[CH][CH][CH]1. Metal clusters: 4 [Co]. The MOF has largest included sphere 4.42 A, density 1.33 g/cm3, surface area 4592.41 m2/g, accessible volume 0.26 cm3/g