AgH18(C7N2)2CH2 is Indium-derived structured and crystallizes in the orthorhombic Fddd space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and sixteen AgH18(C7N2)2 clusters. In each AgH18(C7N2)2 cluster, Ag(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Ag(1)-N(1) bond lengths are 2.36 Å. Both Ag(1)-N(2) bond lengths are 2.42 Å. There are seven inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(2)-C(3) bond length is 1.36 Å. The C(2)-H(3) bond length is 0.93 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.36 Å. The C(3)-C(6) bond length is 1.52 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(4)-H(4) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(5) bond length is 0.93 Å. In the fifth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-H(2) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a 3-coordinate geometry to one C(3), one N(2), one H(6), and one H(7) atom. The C(6)-N(2) bond length is 1.49 Å. The C(6)-H(6) bond length is 0.97 Å. The C(6)-H(7) bond length is 0.97 Å. In the seventh C site, C(7) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(8,9) atoms. The C(7)-N(2) bond length is 1.48 Å. Both C(7)-H(8,9) bond lengths are 0.97 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a 1-coordinate geometry to one Ag(1), one C(6), one C(7), and one H(1) atom. The N(2)-H(1) bond length is 0.88 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8,9) is bonded in a single-bond geometry to one C(7) atom. Linkers: 16 c1cc(CNCCCNCc2ccncc2)ccn1. Metal clusters: 16 [NH][Ag][NH]. The MOF has largest included sphere 4.82 A, density 1.28 g/cm3, surface area 4587.06 m2/g, accessible volume 0.37 cm3/g