Cu8C63H24(NO9)4(CH2)8 crystallizes in the tetragonal P4_32_12 space group. The structure consists of thirty-two 02329_fluka molecules inside a Cu8C63H24(NO9)4 framework. In the Cu8C63H24(NO9)4 framework, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(13), one O(14), one O(6), and one O(7) atom. The Cu(1)-O(13) bond length is 1.95 Å. The Cu(1)-O(14) bond length is 2.00 Å. The Cu(1)-O(6) bond length is 1.91 Å. The Cu(1)-O(7) bond length is 1.95 Å. In the second Cu site, Cu(2) is bonded in a trigonal bipyramidal geometry to one O(1), one O(2), one O(3), one O(4), and one O(5) atom. The Cu(2)-O(1) bond length is 1.92 Å. The Cu(2)-O(2) bond length is 2.00 Å. The Cu(2)-O(3) bond length is 1.97 Å. The Cu(2)-O(4) bond length is 1.95 Å. The Cu(2)-O(5) bond length is 2.14 Å. In the third Cu site, Cu(3) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(17), one O(18), and one O(9) atom. The Cu(3)-O(11) bond length is 1.96 Å. The Cu(3)-O(17) bond length is 2.09 Å. The Cu(3)-O(18) bond length is 1.85 Å. The Cu(3)-O(9) bond length is 1.94 Å. In the fourth Cu site, Cu(4) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(15), one O(16), and one O(8) atom. The Cu(4)-O(10) bond length is 1.97 Å. The Cu(4)-O(15) bond length is 2.04 Å. The Cu(4)-O(16) bond length is 1.89 Å. The Cu(4)-O(8) bond length is 1.92 Å. There are thirty-two inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one C(15), one C(18), and one H(1) atom. The C(1)-C(15) bond length is 1.38 Å. The C(1)-C(18) bond length is 1.38 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(10), one C(17), and one C(22) atom. The C(2)-C(10) bond length is 1.48 Å. The C(2)-C(17) bond length is 1.41 Å. The C(2)-C(22) bond length is 1.35 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(2) atom. The C(3)-C(11) bond length is 1.37 Å. The C(3)-C(13) bond length is 1.40 Å. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(5) atom. The C(4)-C(12) bond length is 1.39 Å. The C(4)-C(14) bond length is 1.48 Å. The C(4)-C(5) bond length is 1.38 Å. In the fifth C site, C(5) is bonded in a single-bond geometry to one C(11), one C(4), and one H(3) atom. The C(5)-C(11) bond length is 1.42 Å. The C(5)-H(3) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(4), and one O(7) atom. The C(6)-C(15) bond length is 1.50 Å. The C(6)-O(4) bond length is 1.23 Å. The C(6)-O(7) bond length is 1.31 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(2), and one O(5) atom. The C(7)-C(11) bond length is 1.49 Å. The C(7)-N(2) bond length is 1.33 Å. The C(7)-O(5) bond length is 1.22 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(14) atom. The C(8)-O(1) bond length is 1.26 Å. The C(8)-O(14) bond length is 1.27 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(6) atom. The C(9)-O(3) bond length is 1.28 Å. The C(9)-O(6) bond length is 1.22 Å. In the tenth C site, C(10) is bonded in a bent 120 degrees geometry to one C(2), one O(11), and one O(8) atom. The C(10)-O(11) bond length is 1.21 Å. The C(10)-O(8) bond length is 1.34 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(13), one C(4), and one H(4) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(4) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(19), and one C(3) atom. The C(13)-C(19) bond length is 1.52 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(13), and one O(2) atom. The C(14)-O(13) bond length is 1.27 Å. The C(14)-O(2) bond length is 1.26 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(1), one C(22), and one C(6) atom. The C(15)-C(22) bond length is 1.42 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(1), and one O(12) atom. The C(16)-C(18) bond length is 1.50 Å. The C(16)-N(1) bond length is 1.31 Å. The C(16)-O(12) bond length is 1.24 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18), one C(2), and one H(5) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(5) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(1), one C(16), and one C(17) atom. In the nineteenth C site, C(19) is bonded in a bent 120 degrees geometry to one C(13), one O(10), and one O(9) atom. The C(19)-O(10) bond length is 1.17 Å. The C(19)-O(9) bond length is 1.26 Å. In the twentieth C site, C(20) is bonded in a 2-coordinate geometry to one N(2) and one H(6) atom. The C(20)-N(2) bond length is 1.47 Å. The C(20)-H(6) bond length is 0.98 Å. In the twenty-first C site, C(21) is bonded in a 2-coordinate geometry to one N(1) and one H(7) atom. The C(21)-N(1) bond length is 1.44 Å. The C(21)-H(7) bond length is 0.98 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(15), one C(2), and one H(8) atom. The C(22)-H(8) bond length is 0.93 Å. In the twenty-third C site, C(25) is bonded in a 3-coordinate geometry to one N(1) and two equivalent H(13,14) atoms. The C(25)-N(1) bond length is 1.47 Å. Both C(25)-H(13,14) bond lengths are 0.97 Å. In the twenty-fourth C site, C(26) is bonded in a bent 150 degrees geometry to one C(29), one O(16), and one O(17) atom. The C(26)-C(29) bond length is 1.70 Å. The C(26)-O(16) bond length is 1.20 Å. The C(26)-O(17) bond length is 1.14 Å. In the twenty-fifth C site, C(27) is bonded in a distorted bent 150 degrees geometry to one C(34), one O(15), and one O(18) atom. The C(27)-C(34) bond length is 1.60 Å. The C(27)-O(15) bond length is 1.19 Å. The C(27)-O(18) bond length is 1.26 Å. In the twenty-sixth C site, C(28) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(15,16) atoms. The C(28)-N(2) bond length is 1.46 Å. Both C(28)-H(15,16) bond lengths are 0.97 Å. In the twenty-seventh C site, C(29) is bonded in a distorted trigonal planar geometry to one C(26), one C(32), and one C(33) atom. The C(29)-C(32) bond length is 1.56 Å. The C(29)-C(33) bond length is 1.26 Å. In the twenty-eighth C site, C(36) is bonded in a 4-coordinate geometry to two equivalent C(33) and two equivalent C(35) atoms. Both C(36)-C(33) bond lengths are 1.53 Å. Both C(36)-C(35) bond lengths are 1.46 Å. In the twenty-ninth C site, C(32) is bonded in a bent 120 degrees geometry to one C(29) and one C(34) atom. The C(32)-C(34) bond length is 1.33 Å. In the thirtieth C site, C(33) is bonded in a 3-coordinate geometry to one C(29), one C(33), and one C(36) atom. The C(33)-C(33) bond length is 1.35 Å. In the thirty-first C site, C(34) is bonded in a trigonal planar geometry to one C(27), one C(32), and one C(35) atom. The C(34)-C(35) bond length is 1.26 Å. In the thirty-second C site, C(35) is bonded in a 3-coordinate geometry to one C(34), one C(35), and one C(36) atom. The C(35)-C(35) bond length is 1.81 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(16), one C(21), and one C(25) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(20), one C(28), and one C(7) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(13,14) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(15,16) is bonded in a single-bond geometry to one C(28) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(8) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(14) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(9) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(6) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(7) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(9) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(6) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(4) and one C(10) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one C(19) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one C(19) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(10) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(14) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(8) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Cu(4) and one C(27) atom. In the sixteenth O site, O(16) is bonded in a distorted water-like geometry to one Cu(4) and one C(26) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Cu(3) and one C(26) atom. In the eighteenth O site, O(18) is bonded in a water-like geometry to one Cu(3) and one C(27) atom. Linkers: 16 [O]C(=O)c1cc(C([O])=O)cc(C(=O)N2CCC[C@@H]2C([O])=O)c1 ,4 [O]C(=O)[C]1[C][C](C([O])=O)[C]2[C]3[C](C([O])=O)[C][C](C([O])=O)[C]4[C]1C423. Metal clusters: 8 [O][Cu]1234O[C]O[Cu]1(O[C]O2)(O[C]O3)O[C]O4 ,8 [C]1O[Cu]23O[C]O[Cu](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 7.30 A, density 1.23 g/cm3, surface area 3524.62 m2/g, accessible volume 0.48 cm3/g