Zn2C53H30O8Zn2C53H32O8 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Zn2C53H30O8 cluster and two Zn2C53H32O8 clusters. In the Zn2C53H30O8 cluster, there are three inequivalent Zn sites. In the first Zn site, Zn(1,3,5) is bonded in a distorted trigonal bipyramidal geometry to one O(16,24,32); one O(3,11,19); one O(4,12,20); one O(5,21,29); and one O(7,15,31) atom. The Zn(1,3,5)-O(16,24,32) bond length is 1.97 Å. The Zn(1,3,5)-O(3,11,19) bond length is 2.09 Å. The Zn(1,3,5)-O(4,12,20) bond length is 2.26 Å. The Zn(1,3,5)-O(5,21,29) bond length is 1.90 Å. The Zn(1,3,5)-O(7,15,31) bond length is 1.99 Å. In the second Zn site, Zn(2,4,6,8) is bonded in a 3-coordinate geometry to one O(1,9,17,25); one O(23); and one O(6,14,22,30) atom. The Zn(2,4,6,8)-O(1,9,17,25) bond length is 2.07 Å. The Zn(2,4,6,8)-O(23) bond length is 2.06 Å. The Zn(2,4,6,8)-O(6,14,22,30) bond length is 2.11 Å. In the third Zn site, Zn(7) is bonded in a distorted trigonal bipyramidal geometry to one O(13), one O(23), one O(27), one O(28), and one O(8) atom. The Zn(7)-O(13) bond length is 1.90 Å. The Zn(7)-O(23) bond length is 1.99 Å. The Zn(7)-O(27) bond length is 2.09 Å. The Zn(7)-O(28) bond length is 2.26 Å. The Zn(7)-O(8) bond length is 1.97 Å. There are ninety-four inequivalent C sites. In the first C site, C(1,54,107,160) is bonded in a distorted single-bond geometry to one C(2,55,108,161) and one H(1,2,30,31,33,34,62,63,65,66,94,95,97,98,122,123) atom. The C(1,54,107,160)-C(2,55,108,161) bond length is 1.39 Å. The C(1,54,107,160)-H(1,2,30,31,33,34,62,63,65,66,94,95,97,98,122,123) bond length is 1.14 Å. In the second C site, C(2,55,108,161) is bonded in a trigonal planar geometry to one C(1,54,107,160); one C(3,56,109,162); and one C(7,60,113,166) atom. The C(2,55,108,161)-C(3,56,109,162) bond length is 1.39 Å. The C(2,55,108,161)-C(7,60,113,166) bond length is 1.43 Å. In the third C site, C(3,56,109,162) is bonded in a distorted single-bond geometry to one C(2,55,108,161) and one H(1,2,30,31,33,34,62,63,65,66,94,95,97,98,122,123) atom. The C(3,56,109,162)-H(1,2,30,31,33,34,62,63,65,66,94,95,97,98,122,123) bond length is 1.14 Å. In the fourth C site, C(4,57) is bonded in a single-bond geometry to one C(5,58) and one H(3,4,35,36) atom. The C(4,57)-C(5,58) bond length is 1.39 Å. The C(4,57)-H(3,4,35,36) bond length is 1.14 Å. In the fifth C site, C(5,58) is bonded in a trigonal planar geometry to one C(31,84); one C(4,57); and one C(6,59) atom. The C(5,58)-C(31,84) bond length is 1.54 Å. The C(5,58)-C(6,59) bond length is 1.39 Å. In the sixth C site, C(6,59) is bonded in a distorted single-bond geometry to one C(5,58) and one H(3,4,35,36) atom. The C(6,59)-H(3,4,35,36) bond length is 1.14 Å. In the seventh C site, C(7,60,113,166) is bonded in a distorted bent 120 degrees geometry to one C(2,55,108,161); one O(2,10,18,26); and one O(7,15,31) atom. The C(7,60,113,166)-O(2,10,18,26) bond length is 1.23 Å. The C(7,60,113,166)-O(7,15,31) bond length is 1.27 Å. In the eighth C site, C(8,61,114) is bonded in a trigonal planar geometry to one C(13,66,119); one C(27,80,133); and one C(9,62,115) atom. The C(8,61,114)-C(13,66,119) bond length is 1.39 Å. The C(8,61,114)-C(27,80,133) bond length is 1.51 Å. The C(8,61,114)-C(9,62,115) bond length is 1.39 Å. In the ninth C site, C(9,62,115) is bonded in a distorted single-bond geometry to one C(10,63,116); one C(8,61,114); and one H(5,37,69) atom. The C(9,62,115)-C(10,63,116) bond length is 1.39 Å. The C(9,62,115)-H(5,37,69) bond length is 1.14 Å. In the tenth C site, C(10,63,116) is bonded in a distorted trigonal planar geometry to one C(11,64,117); one C(9,62,115); and one H(6,38,70) atom. The C(10,63,116)-C(11,64,117) bond length is 1.39 Å. The C(10,63,116)-H(6,38,70) bond length is 1.14 Å. In the eleventh C site, C(11,64,117) is bonded in a trigonal planar geometry to one C(10,63,116); one C(12,65,118); and one C(14,67,120) atom. The C(11,64,117)-C(12,65,118) bond length is 1.39 Å. The C(11,64,117)-C(14,67,120) bond length is 1.53 Å. In the twelfth C site, C(12,65,118) is bonded in a distorted single-bond geometry to one C(11,64,117) and one H(7,39,71) atom. The C(12,65,118)-H(7,39,71) bond length is 1.14 Å. In the thirteenth C site, C(13,66,119) is bonded in a distorted single-bond geometry to one C(8,61,114) and one H(8,40,72) atom. The C(13,66,119)-H(8,40,72) bond length is 1.14 Å. In the fourteenth C site, C(14,67,120) is bonded in a trigonal planar geometry to one C(11,64,117); one C(15,68,121); and one C(19,72,125) atom. The C(14,67,120)-C(15,68,121) bond length is 1.39 Å. The C(14,67,120)-C(19,72,125) bond length is 1.39 Å. In the fifteenth C site, C(15,68,121) is bonded in a distorted single-bond geometry to one C(14,67,120) and one H(9,41,73) atom. The C(15,68,121)-H(9,41,73) bond length is 1.14 Å. In the sixteenth C site, C(16,69,122) is bonded in a distorted single-bond geometry to one C(17,70,123) and one H(10,42,74) atom. The C(16,69,122)-C(17,70,123) bond length is 1.39 Å. The C(16,69,122)-H(10,42,74) bond length is 1.14 Å. In the seventeenth C site, C(17,70,123) is bonded in a trigonal planar geometry to one C(16,69,122); one C(18,71,124); and one C(20,73,126) atom. The C(17,70,123)-C(18,71,124) bond length is 1.39 Å. The C(17,70,123)-C(20,73,126) bond length is 1.45 Å. In the eighteenth C site, C(18,71,124) is bonded in a distorted trigonal planar geometry to one C(17,70,123); one C(19,72,125); and one H(11,43,75) atom. The C(18,71,124)-C(19,72,125) bond length is 1.39 Å. The C(18,71,124)-H(11,43,75) bond length is 1.14 Å. In the nineteenth C site, C(19,72,125) is bonded in a distorted single-bond geometry to one C(14,67,120); one C(18,71,124); and one H(12,44) atom. The C(19,72,125)-H(12,44) bond length is 1.14 Å. In the twentieth C site, C(20,73,126) is bonded in a distorted bent 120 degrees geometry to one C(17,70,123); one O(3,11,19); and one O(4,12,20) atom. The C(20,73,126)-O(3,11,19) bond length is 1.22 Å. The C(20,73,126)-O(4,12,20) bond length is 1.22 Å. In the twenty-first C site, C(21,74,127) is bonded in a trigonal planar geometry to one C(22,75,128); one C(26,79,132); and one C(27,80,133) atom. The C(21,74,127)-C(22,75,128) bond length is 1.39 Å. The C(21,74,127)-C(26,79,132) bond length is 1.39 Å. The C(21,74,127)-C(27,80,133) bond length is 1.61 Å. In the twenty-second C site, C(22,75,128) is bonded in a distorted single-bond geometry to one C(21,74,127) and one H(13,45,77) atom. The C(22,75,128)-H(13,45,77) bond length is 1.14 Å. In the twenty-third C site, C(23,76,129,182) is bonded in a distorted single-bond geometry to one C(24,77,130) and one H(14,46,78,106) atom. The C(23,76,129,182)-C(24,77,130) bond length is 1.39 Å. The C(23,76,129,182)-H(14,46,78,106) bond length is 1.14 Å. In the twenty-fourth C site, C(24,77,130) is bonded in a trigonal planar geometry to one C(23,76,129,182); one C(25,78,131); and one C(50,103,156,209) atom. The C(24,77,130)-C(25,78,131) bond length is 1.39 Å. The C(24,77,130)-C(50,103,156,209) bond length is 1.57 Å. In the twenty-fifth C site, C(25,78,131) is bonded in a distorted trigonal planar geometry to one C(24,77,130); one C(26,79,132); and one H(15,47,79) atom. The C(25,78,131)-C(26,79,132) bond length is 1.39 Å. The C(25,78,131)-H(15,47,79) bond length is 1.14 Å. In the twenty-sixth C site, C(26,79,132) is bonded in a distorted trigonal planar geometry to one C(21,74,127); one C(25,78,131); and one H(16,48,80) atom. The C(26,79,132)-H(16,48,80) bond length is 1.14 Å. In the twenty-seventh C site, C(27,80,133) is bonded in a tetrahedral geometry to one C(21,74,127); one C(28,81,134); one C(35,88,141); and one C(8,61,114) atom. The C(27,80,133)-C(28,81,134) bond length is 1.60 Å. The C(27,80,133)-C(35,88,141) bond length is 1.60 Å. In the twenty-eighth C site, C(28,81,134) is bonded in a trigonal planar geometry to one C(27,80,133); one C(29,82,135); and one C(33,86,139) atom. The C(28,81,134)-C(29,82,135) bond length is 1.39 Å. The C(28,81,134)-C(33,86,139) bond length is 1.39 Å. In the twenty-ninth C site, C(29,82,135) is bonded in a distorted single-bond geometry to one C(28,81,134) and one H(17,49,81) atom. The C(29,82,135)-H(17,49,81) bond length is 1.14 Å. In the thirtieth C site, C(30,83) is bonded in a distorted single-bond geometry to one C(31,84) and one H(18,50,82) atom. The C(30,83)-C(31,84) bond length is 1.39 Å. The C(30,83)-H(18,50,82) bond length is 1.14 Å. In the thirty-first C site, C(31,84) is bonded in a trigonal planar geometry to one C(30,83); one C(32,85); and one C(5,58) atom. The C(31,84)-C(32,85) bond length is 1.39 Å. In the thirty-second C site, C(32,85) is bonded in a distorted trigonal planar geometry to one C(31,84); one C(33,86,139); and one H(19,51,83) atom. The C(32,85)-C(33,86,139) bond length is 1.39 Å. The C(32,85)-H(19,51,83) bond length is 1.14 Å. In the thirty-third C site, C(33,86,139) is bonded in a distorted trigonal planar geometry to one C(28,81,134); one C(32,85); and one H(20,84) atom. The C(33,86,139)-H(20,84) bond length is 1.14 Å. In the thirty-fourth C site, C(34,87,140,193) is bonded in a distorted bent 120 degrees geometry to one C(53,106,159,212); one O(5,21,29); and one O(6,14,22,30) atom. The C(34,87,140,193)-C(53,106,159,212) bond length is 1.44 Å. The C(34,87,140,193)-O(5,21,29) bond length is 1.13 Å. The C(34,87,140,193)-O(6,14,22,30) bond length is 1.31 Å. In the thirty-fifth C site, C(35,88,141) is bonded in a trigonal planar geometry to one C(27,80,133); one C(36,89,142); and one C(40,93,146) atom. The C(35,88,141)-C(36,89,142) bond length is 1.39 Å. The C(35,88,141)-C(40,93,146) bond length is 1.39 Å. In the thirty-sixth C site, C(36,89,142) is bonded in a distorted trigonal planar geometry to one C(35,88,141); one C(37,90,143); and one H(21,53,85) atom. The C(36,89,142)-C(37,90,143) bond length is 1.39 Å. The C(36,89,142)-H(21,53,85) bond length is 1.14 Å. In the thirty-seventh C site, C(37,90,143) is bonded in a distorted single-bond geometry to one C(36,89,142); one C(38,91,144); and one H(22,54,86) atom. The C(37,90,143)-C(38,91,144) bond length is 1.39 Å. The C(37,90,143)-H(22,54,86) bond length is 1.14 Å. In the thirty-eighth C site, C(38,91,144) is bonded in a trigonal planar geometry to one C(37,90,143); one C(39,92,145); and one C(43,96,149) atom. The C(38,91,144)-C(39,92,145) bond length is 1.39 Å. The C(38,91,144)-C(43,96,149) bond length is 1.53 Å. In the thirty-ninth C site, C(39,92,145) is bonded in a distorted trigonal planar geometry to one C(38,91,144); one C(40,93,146); and one H(23,55,87) atom. The C(39,92,145)-C(40,93,146) bond length is 1.39 Å. The C(39,92,145)-H(23,55,87) bond length is 1.14 Å. In the fortieth C site, C(40,93,146) is bonded in a distorted trigonal planar geometry to one C(35,88,141); one C(39,92,145); and one H(24,56,88) atom. The C(40,93,146)-H(24,56,88) bond length is 1.14 Å. In the forty-first C site, C(41,94,147) is bonded in a distorted single-bond geometry to one C(46,99,152) and one H(25,28,57,60,89,92,120) atom. The C(41,94,147)-C(46,99,152) bond length is 1.39 Å. The C(41,94,147)-H(25,28,57,60,89,92,120) bond length is 1.14 Å. In the forty-second C site, C(42,95,148) is bonded in a distorted single-bond geometry to one C(43,96,149) and one H(26,27,58,59,90,91,119) atom. The C(42,95,148)-C(43,96,149) bond length is 1.39 Å. The C(42,95,148)-H(26,27,58,59,90,91,119) bond length is 1.14 Å. In the forty-third C site, C(43,96,149) is bonded in a trigonal planar geometry to one C(38,91,144); one C(42,95,148); and one C(44,97,150) atom. The C(43,96,149)-C(44,97,150) bond length is 1.39 Å. In the forty-fourth C site, C(44,97,150) is bonded in a distorted single-bond geometry to one C(43,96,149) and one H(26,27,58,59,90,91,119) atom. The C(44,97,150)-H(26,27,58,59,90,91,119) bond length is 1.14 Å. In the forty-fifth C site, C(45,98,151) is bonded in a distorted single-bond geometry to one C(46,99,152) and one H(25,28,57,60,89,92,120) atom. The C(45,98,151)-C(46,99,152) bond length is 1.39 Å. The C(45,98,151)-H(25,28,57,60,89,92,120) bond length is 1.14 Å. In the forty-sixth C site, C(46,99,152) is bonded in a trigonal planar geometry to one C(41,94,147); one C(45,98,151); and one C(47,100,153) atom. The C(46,99,152)-C(47,100,153) bond length is 1.66 Å. In the forty-seventh C site, C(47,100,153) is bonded in a distorted bent 150 degrees geometry to one C(46,99,152); one O(1,9,17,25); and one O(8) atom. The C(47,100,153)-O(1,9,17,25) bond length is 1.31 Å. The C(47,100,153)-O(8) bond length is 1.11 Å. In the forty-eighth C site, C(48,101,154,207) is bonded in a distorted single-bond geometry to one C(53,106,159,212) and one H(29,32,61,64,93,96,121,124) atom. The C(48,101,154,207)-C(53,106,159,212) bond length is 1.39 Å. The C(48,101,154,207)-H(29,32,61,64,93,96,121,124) bond length is 1.14 Å. In the forty-ninth C site, C(49,102,155,208) is bonded in a distorted single-bond geometry to one C(50,103,156,209) and one H(1,2,30,31,33,34,62,63,65,66,94,95,97,98,122,123) atom. The C(49,102,155,208)-C(50,103,156,209) bond length is 1.39 Å. The C(49,102,155,208)-H(1,2,30,31,33,34,62,63,65,66,94,95,97,98,122,123) bond length is 1.14 Å. In the fiftieth C site, C(50,103,156,209) is bonded in a trigonal planar geometry to one C(24,77,130); one C(49,102,155,208); and one C(51,104,157,210) atom. The C(50,103,156,209)-C(51,104,157,210) bond length is 1.39 Å. In the fifty-first C site, C(51,104,157,210) is bonded in a distorted single-bond geometry to one C(50,103,156,209) and one H(1,2,30,31,33,34,62,63,65,66,94,95,97,98,122,123) atom. The C(51,104,157,210)-H(1,2,30,31,33,34,62,63,65,66,94,95,97,98,122,123) bond length is 1.14 Å. In the fifty-second C site, C(52,105,158,211) is bonded in a distorted single-bond geometry to one C(53,106,159,212) and one H(29,32,61,64,93,96,121,124) atom. The C(52,105,158,211)-C(53,106,159,212) bond length is 1.39 Å. The C(52,105,158,211)-H(29,32,61,64,93,96,121,124) bond length is 1.14 Å. In the fifty-third C site, C(53,106,159,212) is bonded in a trigonal planar geometry to one C(34,87,140,193); one C(48,101,154,207); and one C(52,105,158,211) atom. In the fifty-fourth C site, C(163) is bonded in a distorted single-bond geometry to one C(164) and one H(99,100) atom. The C(163)-C(164) bond length is 1.39 Å. The C(163)-H(99,100) bond length is 1.14 Å. In the fifty-fifth C site, C(164) is bonded in a trigonal planar geometry to one C(163), one C(165), and one C(190) atom. The C(164)-C(165) bond length is 1.39 Å. The C(164)-C(190) bond length is 1.54 Å. In the fifty-sixth C site, C(165) is bonded in a distorted single-bond geometry to one C(164) and one H(99,100) atom. The C(165)-H(99,100) bond length is 1.14 Å. In the fifty-seventh C site, C(167) is bonded in a trigonal planar geometry to one C(168), one C(172), and one C(186) atom. The C(167)-C(168) bond length is 1.39 Å. The C(167)-C(172) bond length is 1.39 Å. The C(167)-C(186) bond length is 1.51 Å. In the fifty-eighth C site, C(168) is bonded in a bent 120 degrees geometry to one C(167) and one C(169) atom. The C(168)-C(169) bond length is 1.39 Å. In the fifty-ninth C site, C(169) is bonded in a bent 120 degrees geometry to one C(168) and one C(170) atom. The C(169)-C(170) bond length is 1.39 Å. In the sixtieth C site, C(170) is bonded in a trigonal planar geometry to one C(169), one C(171), and one C(173) atom. The C(170)-C(171) bond length is 1.39 Å. The C(170)-C(173) bond length is 1.53 Å. In the sixty-first C site, C(171) is bonded in a bent 120 degrees geometry to one C(170) and one C(172) atom. The C(171)-C(172) bond length is 1.39 Å. In the sixty-second C site, C(172) is bonded in a bent 120 degrees geometry to one C(167) and one C(171) atom. In the sixty-third C site, C(173) is bonded in a trigonal planar geometry to one C(170), one C(174), and one C(178) atom. The C(173)-C(174) bond length is 1.39 Å. The C(173)-C(178) bond length is 1.39 Å. In the sixty-fourth C site, C(174) is bonded in a distorted single-bond geometry to one C(173) and one H(101) atom. The C(174)-H(101) bond length is 1.14 Å. In the sixty-fifth C site, C(175) is bonded in a distorted single-bond geometry to one C(176) and one H(102) atom. The C(175)-C(176) bond length is 1.39 Å. The C(175)-H(102) bond length is 1.14 Å. In the sixty-sixth C site, C(176) is bonded in a trigonal planar geometry to one C(175), one C(177), and one C(179) atom. The C(176)-C(177) bond length is 1.39 Å. The C(176)-C(179) bond length is 1.45 Å. In the sixty-seventh C site, C(177) is bonded in a distorted trigonal planar geometry to one C(176), one C(178), and one H(103) atom. The C(177)-C(178) bond length is 1.39 Å. The C(177)-H(103) bond length is 1.14 Å. In the sixty-eighth C site, C(178) is bonded in a distorted trigonal planar geometry to one C(173), one C(177), and one H(104) atom. The C(178)-H(104) bond length is 1.14 Å. In the sixty-ninth C site, C(179) is bonded in a distorted bent 120 degrees geometry to one C(176), one O(27), and one O(28) atom. The C(179)-O(27) bond length is 1.22 Å. The C(179)-O(28) bond length is 1.22 Å. In the seventieth C site, C(180) is bonded in a trigonal planar geometry to one C(181), one C(185), and one C(186) atom. The C(180)-C(181) bond length is 1.39 Å. The C(180)-C(185) bond length is 1.39 Å. The C(180)-C(186) bond length is 1.61 Å. In the seventy-first C site, C(181) is bonded in a distorted single-bond geometry to one C(180) and one H(105) atom. The C(181)-H(105) bond length is 1.14 Å. In the seventy-second C site, C(183) is bonded in a trigonal planar geometry to one C(184); one C(23,76,129,182); and one C(50,103,156,209) atom. The C(183)-C(184) bond length is 1.39 Å. The C(183)-C(23,76,129,182) bond length is 1.39 Å. The C(183)-C(50,103,156,209) bond length is 1.57 Å. In the seventy-third C site, C(184) is bonded in a distorted trigonal planar geometry to one C(183), one C(185), and one H(107) atom. The C(184)-C(185) bond length is 1.39 Å. The C(184)-H(107) bond length is 1.14 Å. In the seventy-fourth C site, C(185) is bonded in a distorted trigonal planar geometry to one C(180), one C(184), and one H(108) atom. The C(185)-H(108) bond length is 1.14 Å. In the seventy-fifth C site, C(186) is bonded in a tetrahedral geometry to one C(167), one C(180), one C(187), and one C(194) atom. The C(186)-C(187) bond length is 1.60 Å. The C(186)-C(194) bond length is 1.60 Å. In the seventy-sixth C site, C(187) is bonded in a trigonal planar geometry to one C(186), one C(188), and one C(192) atom. The C(187)-C(188) bond length is 1.39 Å. The C(187)-C(192) bond length is 1.39 Å. In the seventy-seventh C site, C(188) is bonded in a distorted single-bond geometry to one C(187), one C(189), and one H(109) atom. The C(188)-C(189) bond length is 1.39 Å. The C(188)-H(109) bond length is 1.14 Å. In the seventy-eighth C site, C(189) is bonded in a distorted trigonal planar geometry to one C(188), one C(190), and one H(110) atom. The C(189)-C(190) bond length is 1.39 Å. The C(189)-H(110) bond length is 1.14 Å. In the seventy-ninth C site, C(190) is bonded in a trigonal planar geometry to one C(164), one C(189), and one C(191) atom. The C(190)-C(191) bond length is 1.39 Å. In the eightieth C site, C(191) is bonded in a distorted trigonal planar geometry to one C(190), one C(192), and one H(111) atom. The C(191)-C(192) bond length is 1.39 Å. The C(191)-H(111) bond length is 1.14 Å. In the eighty-first C site, C(192) is bonded in a distorted single-bond geometry to one C(187), one C(191), and one H(112) atom. The C(192)-H(112) bond length is 1.14 Å. In the eighty-second C site, C(194) is bonded in a trigonal planar geometry to one C(186), one C(195), and one C(199) atom. The C(194)-C(195) bond length is 1.39 Å. The C(194)-C(199) bond length is 1.39 Å. In the eighty-third C site, C(195) is bonded in a distorted trigonal planar geometry to one C(194), one C(196), and one H(113) atom. The C(195)-C(196) bond length is 1.39 Å. The C(195)-H(113) bond length is 1.14 Å. In the eighty-fourth C site, C(196) is bonded in a distorted single-bond geometry to one C(195), one C(197), and one H(114) atom. The C(196)-C(197) bond length is 1.39 Å. The C(196)-H(114) bond length is 1.14 Å. In the eighty-fifth C site, C(197) is bonded in a trigonal planar geometry to one C(196), one C(198), and one C(202) atom. The C(197)-C(198) bond length is 1.39 Å. The C(197)-C(202) bond length is 1.53 Å. In the eighty-sixth C site, C(198) is bonded in a distorted trigonal planar geometry to one C(197), one C(199), and one H(115) atom. The C(198)-C(199) bond length is 1.39 Å. The C(198)-H(115) bond length is 1.14 Å. In the eighty-seventh C site, C(199) is bonded in a distorted single-bond geometry to one C(194), one C(198), and one H(116) atom. The C(199)-H(116) bond length is 1.14 Å. In the eighty-eighth C site, C(200) is bonded in a distorted trigonal planar geometry to one C(201), one C(205), and one H(117) atom. The C(200)-C(201) bond length is 1.39 Å. The C(200)-C(205) bond length is 1.39 Å. The C(200)-H(117) bond length is 1.14 Å. In the eighty-ninth C site, C(201) is bonded in a distorted single-bond geometry to one C(200), one C(202), and one H(118) atom. The C(201)-C(202) bond length is 1.39 Å. The C(201)-H(118) bond length is 1.14 Å. In the ninetieth C site, C(202) is bonded in a trigonal planar geometry to one C(197), one C(201), and one C(203) atom. The C(202)-C(203) bond length is 1.39 Å. In the ninety-first C site, C(203) is bonded in a distorted single-bond geometry to one C(202) and one H(26,27,58,59,90,91,119) atom. The C(203)-H(26,27,58,59,90,91,119) bond length is 1.14 Å. In the ninety-second C site, C(204) is bonded in a distorted single-bond geometry to one C(205) and one H(25,28,57,60,89,92,120) atom. The C(204)-C(205) bond length is 1.39 Å. The C(204)-H(25,28,57,60,89,92,120) bond length is 1.14 Å. In the ninety-third C site, C(205) is bonded in a trigonal planar geometry to one C(200), one C(204), and one C(206) atom. The C(205)-C(206) bond length is 1.66 Å. In the ninety-fourth C site, C(206) is bonded in a distorted bent 150 degrees geometry to one C(205); one O(1,9,17,25); and one O(16,24,32) atom. The C(206)-O(1,9,17,25) bond length is 1.31 Å. The C(206)-O(16,24,32) bond length is 1.11 Å. There are forty-three inequivalent H sites. In the first H site, H(1,2,30,31,33,34,62,63,65,66,94,95,97,98,122,123) is bonded in a single-bond geometry to one C(1,54,107,160) atom. In the second H site, H(3,4,35,36) is bonded in a single-bond geometry to one C(4,57) atom. In the third H site, H(5,37,69) is bonded in a single-bond geometry to one C(9,62,115) atom. In the fourth H site, H(6,38,70) is bonded in a single-bond geometry to one C(10,63,116) atom. In the fifth H site, H(7,39,71) is bonded in a single-bond geometry to one C(12,65,118) atom. In the sixth H site, H(8,40,72) is bonded in a single-bond geometry to one C(13,66,119) atom. In the seventh H site, H(9,41,73) is bonded in a single-bond geometry to one C(15,68,121) atom. In the eighth H site, H(10,42,74) is bonded in a single-bond geometry to one C(16,69,122) atom. In the ninth H site, H(11,43,75) is bonded in a single-bond geometry to one C(18,71,124) atom. In the tenth H site, H(12,44) is bonded in a single-bond geometry to one C(19,72,125) atom. In the eleventh H site, H(13,45,77) is bonded in a single-bond geometry to one C(22,75,128) atom. In the twelfth H site, H(14,46,78,106) is bonded in a single-bond geometry to one C(23,76,129,182) atom. In the thirteenth H site, H(15,47,79) is bonded in a single-bond geometry to one C(25,78,131) atom. In the fourteenth H site, H(16,48,80) is bonded in a single-bond geometry to one C(26,79,132) atom. In the fifteenth H site, H(17,49,81) is bonded in a single-bond geometry to one C(29,82,135) atom. In the sixteenth H site, H(18,50,82) is bonded in a single-bond geometry to one C(30,83) atom. In the seventeenth H site, H(19,51,83) is bonded in a single-bond geometry to one C(32,85) atom. In the eighteenth H site, H(20,84) is bonded in a single-bond geometry to one C(33,86,139) atom. In the nineteenth H site, H(21,53,85) is bonded in a single-bond geometry to one C(36,89,142) atom. In the twentieth H site, H(22,54,86) is bonded in a single-bond geometry to one C(37,90,143) atom. In the twenty-first H site, H(23,55,87) is bonded in a single-bond geometry to one C(39,92,145) atom. In the twenty-second H site, H(24,56,88) is bonded in a single-bond geometry to one C(40,93,146) atom. In the twenty-third H site, H(25,28,57,60,89,92,120) is bonded in a single-bond geometry to one C(41,94,147) atom. In the twenty-fourth H site, H(26,27,58,59,90,91,119) is bonded in a single-bond geometry to one C(42,95,148) atom. In the twenty-fifth H site, H(29,32,61,64,93,96,121,124) is bonded in a single-bond geometry to one C(48,101,154,207) atom. In the twenty-sixth H site, H(99,100) is bonded in a single-bond geometry to one C(163) atom. In the twenty-seventh H site, H(101) is bonded in a single-bond geometry to one C(174) atom. In the twenty-eighth H site, H(102) is bonded in a single-bond geometry to one C(175) atom. In the twenty-ninth H site, H(103) is bonded in a single-bond geometry to one C(177) atom. In the thirtieth H site, H(104) is bonded in a single-bond geometry to one C(178) atom. In the thirty-first H site, H(105) is bonded in a single-bond geometry to one C(181) atom. In the thirty-second H site, H(107) is bonded in a single-bond geometry to one C(184) atom. In the thirty-third H site, H(108) is bonded in a single-bond geometry to one C(185) atom. In the thirty-fourth H site, H(109) is bonded in a single-bond geometry to one C(188) atom. In the thirty-fifth H site, H(110) is bonded in a single-bond geometry to one C(189) atom. In the thirty-sixth H site, H(111) is bonded in a single-bond geometry to one C(191) atom. In the thirty-seventh H site, H(112) is bonded in a single-bond geometry to one C(192) atom. In the thirty-eighth H site, H(113) is bonded in a single-bond geometry to one C(195) atom. In the thirty-ninth H site, H(114) is bonded in a single-bond geometry to one C(196) atom. In the fortieth H site, H(115) is bonded in a single-bond geometry to one C(198) atom. In the forty-first H site, H(116) is bonded in a single-bond geometry to one C(199) atom. In the forty-second H site, H(117) is bonded in a single-bond geometry to one C(200) atom. In the forty-third H site, H(118) is bonded in a single-bond geometry to one C(201) atom. There are thirteen inequivalent O sites. In the first O site, O(1,9,17,25) is bonded in a bent 120 degrees geometry to one Zn(2,4,6,8) and one C(47,100,153) atom. In the second O site, O(2,10,18,26) is bonded in a single-bond geometry to one C(7,60,113,166) atom. In the third O site, O(3,11,19) is bonded in an L-shaped geometry to one Zn(1,3,5) and one C(20,73,126) atom. In the fourth O site, O(4,12,20) is bonded in an L-shaped geometry to one Zn(1,3,5) and one C(20,73,126) atom. In the fifth O site, O(5,21,29) is bonded in a bent 120 degrees geometry to one Zn(1,3,5) and one C(34,87,140,193) atom. In the sixth O site, O(6,14,22,30) is bonded in a bent 150 degrees geometry to one Zn(2,4,6,8) and one C(34,87,140,193) atom. In the seventh O site, O(7,15,31) is bonded in a distorted trigonal planar geometry to one Zn(1,3,5); one Zn(2,4,6,8); and one C(7,60,113,166) atom. The O(7,15,31)-Zn(2,4,6,8) bond length is 2.06 Å. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(47,100,153) atom. In the ninth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(34,87,140,193) atom. The O(13)-C(34,87,140,193) bond length is 1.13 Å. In the tenth O site, O(16,24,32) is bonded in a bent 120 degrees geometry to one Zn(1,3,5) and one C(47,100,153) atom. The O(16,24,32)-C(47,100,153) bond length is 1.11 Å. In the eleventh O site, O(23) is bonded in a distorted trigonal planar geometry to one Zn(2,4,6,8); one Zn(7); and one C(7,60,113,166) atom. The O(23)-C(7,60,113,166) bond length is 1.27 Å. In the twelfth O site, O(27) is bonded in an L-shaped geometry to one Zn(7) and one C(179) atom. In the thirteenth O site, O(28) is bonded in an L-shaped geometry to one Zn(7) and one C(179) atom. In each Zn2C53H32O8 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1,3,5) is bonded in a distorted trigonal bipyramidal geometry to one O(16,24,32); one O(3,11,19); one O(4,12,20); one O(5,21,29); and one O(7,15,31) atom. In the second Zn site, Zn(2,4,6,8) is bonded in a 3-coordinate geometry to one O(1,9,17,25); one O(23); and one O(6,14,22,30) atom. There are fifty-three inequivalent C sites. In the first C site, C(1,54,107,160) is bonded in a distorted single-bond geometry to one C(2,55,108,161) and one H(1,2,30,31,33,34,62,63,65,66,94,95,97,98,122,123) atom. In the second C site, C(2,55,108,161) is bonded in a trigonal planar geometry to one C(1,54,107,160); one C(3,56,109,162); and one C(7,60,113,166) atom. In the third C site, C(3,56,109,162) is bonded in a distorted single-bond geometry to one C(2,55,108,161) and one H(1,2,30,31,33,34,62,63,65,66,94,95,97,98,122,123) atom. In the fourth C site, C(4,57) is bonded in a single-bond geometry to one C(5,58) and one H(3,4,35,36) atom. In the fifth C site, C(5,58) is bonded in a trigonal planar geometry to one C(31,84); one C(4,57); and one C(6,59) atom. In the sixth C site, C(6,59) is bonded in a distorted single-bond geometry to one C(5,58) and one H(3,4,35,36) atom. In the seventh C site, C(7,60,113,166) is bonded in a distorted bent 120 degrees geometry to one C(2,55,108,161); one O(2,10,18,26); and one O(7,15,31) atom. In the eighth C site, C(8,61,114) is bonded in a trigonal planar geometry to one C(13,66,119); one C(27,80,133); and one C(9,62,115) atom. In the ninth C site, C(9,62,115) is bonded in a distorted single-bond geometry to one C(10,63,116); one C(8,61,114); and one H(5,37,69) atom. In the tenth C site, C(10,63,116) is bonded in a distorted trigonal planar geometry to one C(11,64,117); one C(9,62,115); and one H(6,38,70) atom. In the eleventh C site, C(11,64,117) is bonded in a trigonal planar geometry to one C(10,63,116); one C(12,65,118); and one C(14,67,120) atom. In the twelfth C site, C(12,65,118) is bonded in a distorted single-bond geometry to one C(11,64,117) and one H(7,39,71) atom. In the thirteenth C site, C(13,66,119) is bonded in a distorted single-bond geometry to one C(8,61,114) and one H(8,40,72) atom. In the fourteenth C site, C(14,67,120) is bonded in a trigonal planar geometry to one C(11,64,117); one C(15,68,121); and one C(19,72,125) atom. In the fifteenth C site, C(15,68,121) is bonded in a distorted single-bond geometry to one C(14,67,120) and one H(9,41,73) atom. In the sixteenth C site, C(16,69,122) is bonded in a distorted single-bond geometry to one C(17,70,123) and one H(10,42,74) atom. In the seventeenth C site, C(17,70,123) is bonded in a trigonal planar geometry to one C(16,69,122); one C(18,71,124); and one C(20,73,126) atom. In the eighteenth C site, C(18,71,124) is bonded in a distorted trigonal planar geometry to one C(17,70,123); one C(19,72,125); and one H(11,43,75) atom. In the nineteenth C site, C(19,72,125) is bonded in a distorted single-bond geometry to one C(14,67,120); one C(18,71,124); and one H(12,44) atom. In the twentieth C site, C(20,73,126) is bonded in a distorted bent 120 degrees geometry to one C(17,70,123); one O(3,11,19); and one O(4,12,20) atom. In the twenty-first C site, C(21,74,127) is bonded in a trigonal planar geometry to one C(22,75,128); one C(26,79,132); and one C(27,80,133) atom. In the twenty-second C site, C(22,75,128) is bonded in a distorted single-bond geometry to one C(21,74,127) and one H(13,45,77) atom. In the twenty-third C site, C(23,76,129,182) is bonded in a distorted single-bond geometry to one C(24,77,130) and one H(14,46,78,106) atom. In the twenty-fourth C site, C(24,77,130) is bonded in a trigonal planar geometry to one C(23,76,129,182); one C(25,78,131); and one C(50,103,156,209) atom. In the twenty-fifth C site, C(25,78,131) is bonded in a distorted trigonal planar geometry to one C(24,77,130); one C(26,79,132); and one H(15,47,79) atom. In the twenty-sixth C site, C(26,79,132) is bonded in a distorted trigonal planar geometry to one C(21,74,127); one C(25,78,131); and one H(16,48,80) atom. In the twenty-seventh C site, C(27,80,133) is bonded in a tetrahedral geometry to one C(21,74,127); one C(28,81,134); one C(35,88,141); and one C(8,61,114) atom. In the twenty-eighth C site, C(28,81,134) is bonded in a trigonal planar geometry to one C(27,80,133); one C(29,82,135); and one C(33,86,139) atom. In the twenty-ninth C site, C(29,82,135) is bonded in a distorted single-bond geometry to one C(28,81,134) and one H(17,49,81) atom. In the thirtieth C site, C(30,83) is bonded in a distorted single-bond geometry to one C(31,84) and one H(18,50,82) atom. In the thirty-first C site, C(31,84) is bonded in a trigonal planar geometry to one C(30,83); one C(32,85); and one C(5,58) atom. In the thirty-second C site, C(32,85) is bonded in a distorted trigonal planar geometry to one C(31,84); one C(33,86,139); and one H(19,51,83) atom. In the thirty-third C site, C(33,86,139) is bonded in a distorted trigonal planar geometry to one C(28,81,134); one C(32,85); and one H(20,84) atom. In the thirty-fourth C site, C(34,87,140,193) is bonded in a distorted bent 120 degrees geometry to one C(53,106,159,212); one O(5,21,29); and one O(6,14,22,30) atom. In the thirty-fifth C site, C(35,88,141) is bonded in a trigonal planar geometry to one C(27,80,133); one C(36,89,142); and one C(40,93,146) atom. In the thirty-sixth C site, C(36,89,142) is bonded in a distorted trigonal planar geometry to one C(35,88,141); one C(37,90,143); and one H(21,53,85) atom. In the thirty-seventh C site, C(37,90,143) is bonded in a distorted single-bond geometry to one C(36,89,142); one C(38,91,144); and one H(22,54,86) atom. In the thirty-eighth C site, C(38,91,144) is bonded in a trigonal planar geometry to one C(37,90,143); one C(39,92,145); and one C(43,96,149) atom. In the thirty-ninth C site, C(39,92,145) is bonded in a distorted trigonal planar geometry to one C(38,91,144); one C(40,93,146); and one H(23,55,87) atom. In the fortieth C site, C(40,93,146) is bonded in a distorted trigonal planar geometry to one C(35,88,141); one C(39,92,145); and one H(24,56,88) atom. In the forty-first C site, C(41,94,147) is bonded in a distorted single-bond geometry to one C(46,99,152) and one H(25,28,57,60,89,92,120) atom. In the forty-second C site, C(42,95,148) is bonded in a distorted single-bond geometry to one C(43,96,149) and one H(26,27,58,59,90,91,119) atom. In the forty-third C site, C(43,96,149) is bonded in a trigonal planar geometry to one C(38,91,144); one C(42,95,148); and one C(44,97,150) atom. In the forty-fourth C site, C(44,97,150) is bonded in a distorted single-bond geometry to one C(43,96,149) and one H(26,27,58,59,90,91,119) atom. In the forty-fifth C site, C(45,98,151) is bonded in a distorted single-bond geometry to one C(46,99,152) and one H(25,28,57,60,89,92,120) atom. In the forty-sixth C site, C(46,99,152) is bonded in a trigonal planar geometry to one C(41,94,147); one C(45,98,151); and one C(47,100,153) atom. In the forty-seventh C site, C(47,100,153) is bonded in a distorted bent 150 degrees geometry to one C(46,99,152); one O(1,9,17,25); and one O(8) atom. In the forty-eighth C site, C(48,101,154,207) is bonded in a distorted single-bond geometry to one C(53,106,159,212) and one H(29,32,61,64,93,96,121,124) atom. In the forty-ninth C site, C(49,102,155,208) is bonded in a distorted single-bond geometry to one C(50,103,156,209) and one H(1,2,30,31,33,34,62,63,65,66,94,95,97,98,122,123) atom. In the fiftieth C site, C(50,103,156,209) is bonded in a trigonal planar geometry to one C(24,77,130); one C(49,102,155,208); and one C(51,104,157,210) atom. In the fifty-first C site, C(51,104,157,210) is bonded in a distorted single-bond geometry to one C(50,103,156,209) and one H(1,2,30,31,33,34,62,63,65,66,94,95,97,98,122,123) atom. In the fifty-second C site, C(52,105,158,211) is bonded in a distorted single-bond geometry to one C(53,106,159,212) and one H(29,32,61,64,93,96,121,124) atom. In the fifty-third C site, C(53,106,159,212) is bonded in a trigonal planar geometry to one C(34,87,140,193); one C(48,101,154,207); and one C(52,105,158,211) atom. There are twenty-five inequivalent H sites. In the first H site, H(1,2,30,31,33,34,62,63,65,66,94,95,97,98,122,123) is bonded in a single-bond geometry to one C(1,54,107,160) atom. In the second H site, H(3,4,35,36) is bonded in a single-bond geometry to one C(4,57) atom. In the third H site, H(5,37,69) is bonded in a single-bond geometry to one C(9,62,115) atom. In the fourth H site, H(6,38,70) is bonded in a single-bond geometry to one C(10,63,116) atom. In the fifth H site, H(7,39,71) is bonded in a single-bond geometry to one C(12,65,118) atom. In the sixth H site, H(8,40,72) is bonded in a single-bond geometry to one C(13,66,119) atom. In the seventh H site, H(9,41,73) is bonded in a single-bond geometry to one C(15,68,121) atom. In the eighth H site, H(10,42,74) is bonded in a single-bond geometry to one C(16,69,122) atom. In the ninth H site, H(11,43,75) is bonded in a single-bond geometry to one C(18,71,124) atom. In the tenth H site, H(12,44) is bonded in a single-bond geometry to one C(19,72,125) atom. In the eleventh H site, H(13,45,77) is bonded in a single-bond geometry to one C(22,75,128) atom. In the twelfth H site, H(14,46,78,106) is bonded in a single-bond geometry to one C(23,76,129,182) atom. In the thirteenth H site, H(15,47,79) is bonded in a single-bond geometry to one C(25,78,131) atom. In the fourteenth H site, H(16,48,80) is bonded in a single-bond geometry to one C(26,79,132) atom. In the fifteenth H site, H(17,49,81) is bonded in a single-bond geometry to one C(29,82,135) atom. In the sixteenth H site, H(18,50,82) is bonded in a single-bond geometry to one C(30,83) atom. In the seventeenth H site, H(19,51,83) is bonded in a single-bond geometry to one C(32,85) atom. In the eighteenth H site, H(21,53,85) is bonded in a single-bond geometry to one C(36,89,142) atom. In the nineteenth H site, H(22,54,86) is bonded in a single-bond geometry to one C(37,90,143) atom. In the twentieth H site, H(23,55,87) is bonded in a single-bond geometry to one C(39,92,145) atom. In the twenty-first H site, H(24,56,88) is bonded in a single-bond geometry to one C(40,93,146) atom. In the twenty-second H site, H(25,28,57,60,89,92,120) is bonded in a single-bond geometry to one C(41,94,147) atom. In the twenty-third H site, H(26,27,58,59,90,91,119) is bonded in a single-bond geometry to one C(42,95,148) atom. In the twenty-fourth H site, H(29,32,61,64,93,96,121,124) is bonded in a single-bond geometry to one C(48,101,154,207) atom. In the twenty-fifth H site, H(52) is bonded in a single-bond geometry to one C(33,86,139) atom. The H(52)-C(33,86,139) bond length is 1.14 Å. There are eight inequivalent O sites. In the first O site, O(1,9,17,25) is bonded in a bent 120 degrees geometry to one Zn(2,4,6,8) and one C(47,100,153) atom. In the second O site, O(2,10,18,26) is bonded in a single-bond geometry to one C(7,60,113,166) atom. In the third O site, O(3,11,19) is bonded in an L-shaped geometry to one Zn(1,3,5) and one C(20,73,126) atom. In the fourth O site, O(4,12,20) is bonded in an L-shaped geometry to one Zn(1,3,5) and one C(20,73,126) atom. In the fifth O site, O(5,21,29) is bonded in a bent 120 degrees geometry to one Zn(1,3,5) and one C(34,87,140,193) atom. In the sixth O site, O(6,14,22,30) is bonded in a bent 150 degrees geometry to one Zn(2,4,6,8) and one C(34,87,140,193) atom. In the seventh O site, O(7,15,31) is bonded in a distorted trigonal planar geometry to one Zn(1,3,5); one Zn(2,4,6,8); and one C(7,60,113,166) atom. In the eighth O site, O(16,24,32) is bonded in a bent 120 degrees geometry to one Zn(1,3,5) and one C(47,100,153) atom. Linkers: 3 [O]C(=O)c1ccc(-c2ccc(C(c3ccc(-c4ccc(C([O])=O)cc4)cc3)(c3ccc(-c4ccc(C([O])=O)cc4)cc3)c3ccc(-c4ccc(C([O])=O)cc4)cc3)cc2)cc1 ,4 [O]C(=O)c1ccc(-c2ccc([C]c3ccc(-c4ccc(C([O])=O)cc4)cc3)cc2)cc1 ,1 [O]C(=O)c1ccc(-c2[c][c]c(C(c3ccc(-c4ccc(C([O])=O)cc4)cc3)(c3ccc(-c4ccc(C([O])=O)cc4)cc3)c3ccc(-c4ccc(C([O])=O)cc4)cc3)[c][c]2)cc1 ,3 [O]C(=O)c1ccc(-c2ccc(C(c3ccc(-c4c[c]c([C]=O)cc4)cc3)(c3ccc(-c4c[c]c([C]=O)cc4)cc3)c3ccc(-c4ccc(C([O])=O)cc4)cc3)cc2)cc1 ,1 [O]C(=O)c1ccc(-c2[c][c]c(C(c3ccc(-c4c[c]c([C]=O)cc4)cc3)(c3ccc(-c4c[c]c([C]=O)cc4)cc3)c3ccc(-c4ccc(C([O])=O)cc4)cc3)[c][c]2)cc1. Metal clusters: 4 O=[C]O[Zn]12(O[C]O[Zn]O[C]O1)O[C]O2. The MOF has largest included sphere 7.52 A, density 1.01 g/cm3, surface area 4843.46 m2/g, accessible volume 0.45 cm3/g