Ag2H10(C3N2)5 crystallizes in the orthorhombic Pnnm space group. Ag(1) is bonded in a distorted square pyramidal geometry to one N(1), one N(2), one N(3), one N(4), and one N(5) atom. The Ag(1)-N(1) bond length is 2.45 Å. The Ag(1)-N(2) bond length is 2.37 Å. The Ag(1)-N(3) bond length is 2.36 Å. The Ag(1)-N(4) bond length is 2.56 Å. The Ag(1)-N(5) bond length is 2.45 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(1), and one H(1) atom. The C(1)-C(8) bond length is 1.42 Å. The C(1)-N(1) bond length is 1.30 Å. The C(1)-H(1) bond length is 0.94 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(2), and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(2) bond length is 1.31 Å. The C(2)-H(2) bond length is 0.94 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. The C(3)-C(3) bond length is 1.43 Å. The C(3)-C(4) bond length is 1.39 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(3), and one H(3) atom. The C(4)-N(3) bond length is 1.29 Å. The C(4)-H(3) bond length is 0.94 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(4), and one H(4) atom. The C(5)-C(6) bond length is 1.43 Å. The C(5)-N(4) bond length is 1.33 Å. The C(5)-H(4) bond length is 0.94 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(7) atom. The C(6)-C(6) bond length is 1.33 Å. The C(6)-C(7) bond length is 1.43 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(5), and one H(5) atom. The C(7)-N(5) bond length is 1.35 Å. The C(7)-H(5) bond length is 0.94 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(8) and two equivalent C(1) atoms. The C(8)-C(8) bond length is 1.34 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one N(1) atom. The N(1)-N(1) bond length is 1.37 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(2), and one N(2) atom. The N(2)-N(2) bond length is 1.39 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(4), and one N(3) atom. The N(3)-N(3) bond length is 1.41 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(5), and one N(4) atom. The N(4)-N(4) bond length is 1.38 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(7), and one N(5) atom. The N(5)-N(5) bond length is 1.33 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. Linkers: 10 c1nncc2cnncc12. Metal clusters: 8 [Ag]. The MOF has largest included sphere 4.62 A, density 1.64 g/cm3, surface area 3373.59 m2/g, accessible volume 0.26 cm3/g