Cd2Zn7C128H122(N5O13)2(CH)12 crystallizes in the orthorhombic I2_12_12_1 space group. The structure consists of forty-eight 02329_fluka molecules inside a Cd2Zn7C128H122(N5O13)2 framework. In the Cd2Zn7C128H122(N5O13)2 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 6-coordinate geometry to two equivalent N(5), two equivalent O(3), and two equivalent O(7) atoms. Both Cd(1)-N(5) bond lengths are 2.20 Å. Both Cd(1)-O(3) bond lengths are 2.18 Å. Both Cd(1)-O(7) bond lengths are 2.37 Å. In the second Cd site, Cd(2) is bonded in a pentagonal pyramidal geometry to two equivalent N(4), two equivalent O(13), and two equivalent O(8) atoms. Both Cd(2)-N(4) bond lengths are 2.44 Å. Both Cd(2)-O(13) bond lengths are 2.32 Å. Both Cd(2)-O(8) bond lengths are 2.43 Å. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(2), one O(1), one O(10), one O(11), and one O(2) atom to form distorted ZnNO4 trigonal bipyramids that share  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(2)NO4 trigonal bipyramid, and  an edgeedge with one Zn(4)NO4 trigonal bipyramid. The Zn(1)-N(2) bond length is 2.02 Å. The Zn(1)-O(1) bond length is 2.00 Å. The Zn(1)-O(10) bond length is 2.02 Å. The Zn(1)-O(11) bond length is 2.25 Å. The Zn(1)-O(2) bond length is 1.93 Å. In the second Zn site, Zn(2) is bonded to one N(1), one O(1), one O(11), one O(5), and one O(6) atom to form distorted ZnNO4 trigonal bipyramids that share  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(1)NO4 trigonal bipyramid, and  an edgeedge with one Zn(4)NO4 trigonal bipyramid. The Zn(2)-N(1) bond length is 1.98 Å. The Zn(2)-O(1) bond length is 2.01 Å. The Zn(2)-O(11) bond length is 2.03 Å. The Zn(2)-O(5) bond length is 1.91 Å. The Zn(2)-O(6) bond length is 2.25 Å. In the third Zn site, Zn(3) is bonded to two equivalent O(10), two equivalent O(11), and two equivalent O(6) atoms to form edge-sharing ZnO6 octahedra. Both Zn(3)-O(10) bond lengths are 2.08 Å. Both Zn(3)-O(11) bond lengths are 2.06 Å. Both Zn(3)-O(6) bond lengths are 2.09 Å. In the fourth Zn site, Zn(4) is bonded to one N(3), one O(1), one O(10), one O(4), and one O(6) atom to form distorted ZnNO4 trigonal bipyramids that share  an edgeedge with one Zn(3)O6 octahedra,  an edgeedge with one Zn(1)NO4 trigonal bipyramid, and  an edgeedge with one Zn(2)NO4 trigonal bipyramid. The Zn(4)-N(3) bond length is 1.99 Å. The Zn(4)-O(1) bond length is 2.03 Å. The Zn(4)-O(10) bond length is 2.23 Å. The Zn(4)-O(4) bond length is 1.92 Å. The Zn(4)-O(6) bond length is 2.04 Å. There are sixty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(44), one C(48), and one N(1) atom. The C(1)-C(44) bond length is 1.39 Å. The C(1)-C(48) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.44 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(31), one C(41), and one H(45) atom. The C(2)-C(31) bond length is 1.39 Å. The C(2)-C(41) bond length is 1.39 Å. The C(2)-H(45) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(2), and one H(34) atom. The C(3)-C(19) bond length is 1.46 Å. The C(3)-N(2) bond length is 1.28 Å. The C(3)-H(34) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a trigonal non-coplanar geometry to one C(9), one H(23), one H(36), and one H(59) atom. The C(5)-C(9) bond length is 1.47 Å. The C(5)-H(23) bond length is 0.96 Å. The C(5)-H(36) bond length is 0.96 Å. The C(5)-H(59) bond length is 0.96 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one O(10) atom. The C(6)-C(21) bond length is 1.39 Å. The C(6)-C(23) bond length is 1.39 Å. The C(6)-O(10) bond length is 1.36 Å. In the sixth C site, C(7) is bonded in a trigonal non-coplanar geometry to one C(25); one H(29,52); one H(51); and one H(65) atom. The C(7)-C(25) bond length is 1.62 Å. The C(7)-H(29,52) bond length is 0.96 Å. The C(7)-H(51) bond length is 0.96 Å. The C(7)-H(65) bond length is 0.96 Å. In the seventh C site, C(14) is bonded in a trigonal non-coplanar geometry to one C(25), one H(53), one H(55), and one H(62) atom. The C(14)-C(25) bond length is 1.55 Å. The C(14)-H(53) bond length is 0.96 Å. The C(14)-H(55) bond length is 0.96 Å. The C(14)-H(62) bond length is 0.96 Å. In the eighth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(54,60) atom. The C(15)-N(5) bond length is 1.39 Å. The C(15)-H(54,60) bond length is 0.93 Å. In the ninth C site, C(8) is bonded in a trigonal planar geometry to one C(27), one C(44), and one C(62) atom. The C(8)-C(27) bond length is 1.39 Å. The C(8)-C(44) bond length is 1.39 Å. The C(8)-C(62) bond length is 1.53 Å. In the tenth C site, C(18) is bonded in a bent 120 degrees geometry to one C(45), one O(3), and one O(7) atom. The C(18)-C(45) bond length is 1.48 Å. The C(18)-O(3) bond length is 1.27 Å. The C(18)-O(7) bond length is 1.30 Å. In the eleventh C site, C(10) is bonded in a trigonal planar geometry to one C(42), one C(49), and one C(64) atom. The C(10)-C(42) bond length is 1.39 Å. The C(10)-C(49) bond length is 1.55 Å. The C(10)-C(64) bond length is 1.39 Å. In the twelfth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(54,60) atom. The C(11)-N(5) bond length is 1.39 Å. The C(11)-H(54,60) bond length is 0.93 Å. In the thirteenth C site, C(16) is bonded in a trigonal planar geometry to one C(22), one C(35), and one C(50) atom. The C(16)-C(22) bond length is 1.50 Å. The C(16)-C(35) bond length is 1.39 Å. The C(16)-C(50) bond length is 1.39 Å. In the fourteenth C site, C(17) is bonded in a trigonal non-coplanar geometry to one C(47), one H(44), one H(5), and one H(61) atom. The C(17)-C(47) bond length is 1.55 Å. The C(17)-H(44) bond length is 0.96 Å. The C(17)-H(5) bond length is 0.96 Å. The C(17)-H(61) bond length is 0.96 Å. In the fifteenth C site, C(19) is bonded in a trigonal planar geometry to one C(3), one C(50), and one C(63) atom. The C(19)-C(50) bond length is 1.39 Å. The C(19)-C(63) bond length is 1.39 Å. In the sixteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(21), one C(33), and one H(11) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-C(33) bond length is 1.39 Å. The C(20)-H(11) bond length is 0.93 Å. In the seventeenth C site, C(23) is bonded in a trigonal planar geometry to one C(23), one C(6), and one C(9) atom. The C(23)-C(23) bond length is 1.54 Å. The C(23)-C(9) bond length is 1.39 Å. In the eighteenth C site, C(24) is bonded in a trigonal non-coplanar geometry to one C(41), one H(10), one H(58), and one H(64) atom. The C(24)-C(41) bond length is 1.57 Å. The C(24)-H(10) bond length is 0.96 Å. The C(24)-H(58) bond length is 0.96 Å. The C(24)-H(64) bond length is 0.96 Å. In the nineteenth C site, C(25) is bonded in a tetrahedral geometry to one C(14), one C(39), one C(67), and one C(7) atom. The C(25)-C(39) bond length is 1.57 Å. The C(25)-C(67) bond length is 1.47 Å. In the twentieth C site, C(27) is bonded in a trigonal planar geometry to one C(49), one C(53), and one C(8) atom. The C(27)-C(49) bond length is 1.39 Å. The C(27)-C(53) bond length is 1.58 Å. In the twenty-first C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(58), one N(3), and one H(15) atom. The C(28)-C(58) bond length is 1.47 Å. The C(28)-N(3) bond length is 1.27 Å. The C(28)-H(15) bond length is 0.93 Å. In the twenty-second C site, C(29) is bonded in a trigonal non-coplanar geometry to one C(65), one H(30), one H(35), and one H(40) atom. The C(29)-C(65) bond length is 1.54 Å. The C(29)-H(30) bond length is 0.95 Å. The C(29)-H(35) bond length is 0.96 Å. The C(29)-H(40) bond length is 0.97 Å. In the twenty-third C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(12) atom. The C(30)-N(4) bond length is 1.38 Å. The C(30)-H(12) bond length is 0.93 Å. In the twenty-fourth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(2), one C(64), and one N(2) atom. The C(31)-C(64) bond length is 1.39 Å. The C(31)-N(2) bond length is 1.41 Å. In the twenty-fifth C site, C(32) is bonded in a trigonal planar geometry to one C(12), one C(54), and one C(60) atom. The C(32)-C(12) bond length is 1.47 Å. The C(32)-C(54) bond length is 1.39 Å. The C(32)-C(60) bond length is 1.39 Å. In the twenty-sixth C site, C(33) is bonded in a trigonal planar geometry to one C(20), one C(59), and one C(9) atom. The C(33)-C(59) bond length is 1.57 Å. The C(33)-C(9) bond length is 1.39 Å. In the twenty-seventh C site, C(35) is bonded in a distorted single-bond geometry to one C(16), one C(39), and one H(24) atom. The C(35)-C(39) bond length is 1.39 Å. The C(35)-H(24) bond length is 0.93 Å. In the twenty-eighth C site, C(36) is bonded in a distorted single-bond geometry to one C(45), one C(55), and one H(14) atom. The C(36)-C(45) bond length is 1.39 Å. The C(36)-C(55) bond length is 1.39 Å. The C(36)-H(14) bond length is 0.93 Å. In the twenty-ninth C site, C(37) is bonded in a trigonal non-coplanar geometry to one C(42); one H(63); and two equivalent H(8,28) atoms. The C(37)-C(42) bond length is 1.63 Å. The C(37)-H(63) bond length is 0.96 Å. Both C(37)-H(8,28) bond lengths are 0.96 Å. In the thirtieth C site, C(38) is bonded in a trigonal non-coplanar geometry to one C(65); one H(19); and two equivalent H(1,2,46) atoms. The C(38)-C(65) bond length is 1.58 Å. The C(38)-H(19) bond length is 0.96 Å. Both C(38)-H(1,2,46) bond lengths are 0.96 Å. In the thirty-first C site, C(39) is bonded in a trigonal planar geometry to one C(25), one C(35), and one C(63) atom. The C(39)-C(63) bond length is 1.39 Å. In the thirty-second C site, C(40) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(26) atom. The C(40)-N(4) bond length is 1.39 Å. The C(40)-H(26) bond length is 0.93 Å. In the thirty-third C site, C(41) is bonded in a trigonal planar geometry to one C(2), one C(24), and one C(42) atom. The C(41)-C(42) bond length is 1.39 Å. In the thirty-fourth C site, C(42) is bonded in a trigonal planar geometry to one C(10), one C(37), and one C(41) atom. In the thirty-fifth C site, C(43) is bonded in a trigonal non-coplanar geometry to one C(47), one H(13), one H(48), and one H(56) atom. The C(43)-C(47) bond length is 1.44 Å. The C(43)-H(13) bond length is 0.96 Å. The C(43)-H(48) bond length is 0.96 Å. The C(43)-H(56) bond length is 0.96 Å. In the thirty-sixth C site, C(44) is bonded in a distorted single-bond geometry to one C(1), one C(8), and one H(50) atom. The C(44)-H(50) bond length is 0.93 Å. In the thirty-seventh C site, C(45) is bonded in a trigonal planar geometry to one C(18), one C(36), and one C(46) atom. The C(45)-C(46) bond length is 1.39 Å. In the thirty-eighth C site, C(46) is bonded in a distorted single-bond geometry to one C(45), one C(58), and one H(25) atom. The C(46)-C(58) bond length is 1.39 Å. The C(46)-H(25) bond length is 0.93 Å. In the thirty-ninth C site, C(47) is bonded in a tetrahedral geometry to one C(13), one C(17), one C(43), and one C(66) atom. The C(47)-C(13) bond length is 1.56 Å. The C(47)-C(66) bond length is 1.55 Å. In the fortieth C site, C(48) is bonded in a distorted single-bond geometry to one C(1), one C(49), and one O(6) atom. The C(48)-C(49) bond length is 1.39 Å. The C(48)-O(6) bond length is 1.35 Å. In the forty-first C site, C(49) is bonded in a trigonal planar geometry to one C(10), one C(27), and one C(48) atom. In the forty-second C site, C(50) is bonded in a distorted single-bond geometry to one C(16), one C(19), and one H(22) atom. The C(50)-H(22) bond length is 0.93 Å. In the forty-third C site, C(52) is bonded in a trigonal planar geometry to one C(60), one C(61), and one C(69) atom. The C(52)-C(60) bond length is 1.39 Å. The C(52)-C(61) bond length is 1.47 Å. The C(52)-C(69) bond length is 1.39 Å. In the forty-fourth C site, C(53) is bonded in a trigonal non-coplanar geometry to one C(27); one H(3); and two equivalent H(17,42) atoms. The C(53)-H(3) bond length is 0.96 Å. Both C(53)-H(17,42) bond lengths are 0.96 Å. In the forty-fifth C site, C(54) is bonded in a distorted single-bond geometry to one C(13), one C(32), and one O(5) atom. The C(54)-C(13) bond length is 1.39 Å. The C(54)-O(5) bond length is 1.33 Å. In the forty-sixth C site, C(55) is bonded in a trigonal planar geometry to one C(36), one C(65), and one C(68) atom. The C(55)-C(65) bond length is 1.56 Å. The C(55)-C(68) bond length is 1.39 Å. In the forty-seventh C site, C(57) is bonded in a trigonal non-coplanar geometry to one C(65); one H(1,2,46); one H(38); and one H(9) atom. The C(57)-C(65) bond length is 1.55 Å. The C(57)-H(1,2,46) bond length is 0.96 Å. The C(57)-H(38) bond length is 0.96 Å. The C(57)-H(9) bond length is 0.96 Å. In the forty-eighth C site, C(58) is bonded in a trigonal planar geometry to one C(28), one C(46), and one C(68) atom. The C(58)-C(68) bond length is 1.39 Å. In the forty-ninth C site, C(59) is bonded in a trigonal non-coplanar geometry to one C(33), one H(31), one H(37), and one H(57) atom. The C(59)-H(31) bond length is 0.96 Å. The C(59)-H(37) bond length is 0.95 Å. The C(59)-H(57) bond length is 0.96 Å. In the fiftieth C site, C(60) is bonded in a distorted single-bond geometry to one C(32), one C(52), and one H(66) atom. The C(60)-H(66) bond length is 0.93 Å. In the fifty-first C site, C(61) is bonded in a bent 120 degrees geometry to one C(52), one O(13), and one O(8) atom. The C(61)-O(13) bond length is 1.25 Å. The C(61)-O(8) bond length is 1.27 Å. In the fifty-second C site, C(62) is bonded in a trigonal non-coplanar geometry to one C(8), one H(18), one H(27), and one H(6) atom. The C(62)-H(18) bond length is 0.96 Å. The C(62)-H(27) bond length is 0.96 Å. The C(62)-H(6) bond length is 0.96 Å. In the fifty-third C site, C(63) is bonded in a distorted single-bond geometry to one C(19), one C(39), and one O(2) atom. The C(63)-O(2) bond length is 1.33 Å. In the fifty-fourth C site, C(64) is bonded in a distorted single-bond geometry to one C(10), one C(31), and one O(11) atom. The C(64)-O(11) bond length is 1.36 Å. In the fifty-fifth C site, C(65) is bonded in a tetrahedral geometry to one C(29), one C(38), one C(55), and one C(57) atom. In the fifty-sixth C site, C(66) is bonded in a trigonal non-coplanar geometry to one C(47); one H(43); and two equivalent H(7,16) atoms. The C(66)-H(43) bond length is 0.96 Å. Both C(66)-H(7,16) bond lengths are 0.96 Å. In the fifty-seventh C site, C(67) is bonded in a trigonal non-coplanar geometry to one C(25); one H(29,52); one H(33); and one H(49) atom. The C(67)-H(29,52) bond length is 0.96 Å. The C(67)-H(33) bond length is 0.96 Å. The C(67)-H(49) bond length is 0.96 Å. In the fifty-eighth C site, C(68) is bonded in a distorted single-bond geometry to one C(55), one C(58), and one O(4) atom. The C(68)-O(4) bond length is 1.35 Å. In the fifty-ninth C site, C(69) is bonded in a distorted single-bond geometry to one C(13), one C(52), and one H(41) atom. The C(69)-C(13) bond length is 1.39 Å. The C(69)-H(41) bond length is 0.93 Å. In the sixtieth C site, C(9) is bonded in a trigonal planar geometry to one C(23), one C(33), and one C(5) atom. In the sixty-first C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(32), one N(1), and one H(4) atom. The C(12)-N(1) bond length is 1.30 Å. The C(12)-H(4) bond length is 0.93 Å. In the sixty-second C site, C(13) is bonded in a trigonal planar geometry to one C(47), one C(54), and one C(69) atom. In the sixty-third C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(6), and one N(3) atom. The C(21)-N(3) bond length is 1.46 Å. In the sixty-fourth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(12), and one O(9) atom. The C(22)-O(12) bond length is 1.30 Å. The C(22)-O(9) bond length is 1.23 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(1), and one C(12) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(3), and one C(31) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(4), one C(21), and one C(28) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(2), one C(30), and one C(40) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(15) atom. There are fifty-four inequivalent H sites. In the first H site, H(1,2,46) is bonded in a single-bond geometry to one C(38) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(53) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(62) atom. In the sixth H site, H(7,16) is bonded in a single-bond geometry to one C(66) atom. In the seventh H site, H(8,28) is bonded in a single-bond geometry to one C(37) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(57) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(30) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(43) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(36) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(28) atom. In the fifteenth H site, H(17,42) is bonded in a single-bond geometry to one C(53) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(62) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(38) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(50) atom. In the nineteenth H site, H(23) is bonded in a single-bond geometry to one C(5) atom. In the twentieth H site, H(24) is bonded in a single-bond geometry to one C(35) atom. In the twenty-first H site, H(25) is bonded in a single-bond geometry to one C(46) atom. In the twenty-second H site, H(26) is bonded in a single-bond geometry to one C(40) atom. In the twenty-third H site, H(27) is bonded in a single-bond geometry to one C(62) atom. In the twenty-fourth H site, H(29,52) is bonded in a single-bond geometry to one C(67) atom. In the twenty-fifth H site, H(30) is bonded in a single-bond geometry to one C(29) atom. In the twenty-sixth H site, H(31) is bonded in a single-bond geometry to one C(59) atom. In the twenty-seventh H site, H(33) is bonded in a single-bond geometry to one C(67) atom. In the twenty-eighth H site, H(34) is bonded in a single-bond geometry to one C(3) atom. In the twenty-ninth H site, H(35) is bonded in a single-bond geometry to one C(29) atom. In the thirtieth H site, H(36) is bonded in a single-bond geometry to one C(5) atom. In the thirty-first H site, H(37) is bonded in a single-bond geometry to one C(59) atom. In the thirty-second H site, H(38) is bonded in a single-bond geometry to one C(57) atom. In the thirty-third H site, H(40) is bonded in a single-bond geometry to one C(29) atom. In the thirty-fourth H site, H(41) is bonded in a single-bond geometry to one C(69) atom. In the thirty-fifth H site, H(43) is bonded in a single-bond geometry to one C(66) atom. In the thirty-sixth H site, H(44) is bonded in a single-bond geometry to one C(17) atom. In the thirty-seventh H site, H(45) is bonded in a single-bond geometry to one C(2) atom. In the thirty-eighth H site, H(48) is bonded in a single-bond geometry to one C(43) atom. In the thirty-ninth H site, H(49) is bonded in a single-bond geometry to one C(67) atom. In the fortieth H site, H(50) is bonded in a single-bond geometry to one C(44) atom. In the forty-first H site, H(51) is bonded in a single-bond geometry to one C(7) atom. In the forty-second H site, H(53) is bonded in a single-bond geometry to one C(14) atom. In the forty-third H site, H(54,60) is bonded in a single-bond geometry to one C(15) atom. In the forty-fourth H site, H(55) is bonded in a single-bond geometry to one C(14) atom. In the forty-fifth H site, H(56) is bonded in a single-bond geometry to one C(43) atom. In the forty-sixth H site, H(57) is bonded in a single-bond geometry to one C(59) atom. In the forty-seventh H site, H(58) is bonded in a single-bond geometry to one C(24) atom. In the forty-eighth H site, H(59) is bonded in a single-bond geometry to one C(5) atom. In the forty-ninth H site, H(61) is bonded in a single-bond geometry to one C(17) atom. In the fiftieth H site, H(62) is bonded in a single-bond geometry to one C(14) atom. In the fifty-first H site, H(63) is bonded in a single-bond geometry to one C(37) atom. In the fifty-second H site, H(64) is bonded in a single-bond geometry to one C(24) atom. In the fifty-third H site, H(65) is bonded in a single-bond geometry to one C(7) atom. In the fifty-fourth H site, H(66) is bonded in a single-bond geometry to one C(60) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(2), and one Zn(4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(63) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Cd(1) and one C(18) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(68) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(54) atom. In the sixth O site, O(6) is bonded to one Zn(2), one Zn(3), one Zn(4), and one C(48) atom to form a mixture of distorted edge and corner-sharing OZn3C trigonal pyramids. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(18) atom. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(61) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(22) atom. In the tenth O site, O(10) is bonded to one Zn(1), one Zn(3), one Zn(4), and one C(6) atom to form a mixture of distorted edge and corner-sharing OZn3C trigonal pyramids. In the eleventh O site, O(11) is bonded to one Zn(1), one Zn(2), one Zn(3), and one C(64) atom to form a mixture of distorted edge and corner-sharing OZn3C trigonal pyramids. In the twelfth O site, O(12) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth O site, O(13) is bonded in an L-shaped geometry to one Cd(2) and one C(61) atom. Linkers: 6 Cc1cc(/N=C/c2cc(C([O])=O)cc(C(C)(C)C)c2[O])c([O])c(-c2c(C)c(C)cc(/N=C/c3cc(C([O])=O)cc(C(C)(C)C)c3[O])c2[O])c1C. Metal clusters: 14 [Zn] ,4 [Cd]. The MOF has largest included sphere 7.46 A, density 0.92 g/cm3, surface area 4377.10 m2/g, accessible volume 0.68 cm3/g