ZnC6NH4O2(CH)2C6H5O crystallizes in the trigonal R-3 space group. The structure consists of thirty-six 02329_fluka molecules and eighteen C6H5O clusters inside a ZnC6NH4O2 framework. In each C6H5O cluster, there are six inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one H(6) atom. The C(9)-C(4) bond length is 1.41 Å. The C(9)-C(8) bond length is 1.38 Å. The C(9)-H(6) bond length is 0.93 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.46 Å. The C(3)-H(2) bond length is 0.93 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(4)-C(5) bond length is 1.39 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one O(3) atom. The C(5)-O(3) bond length is 1.35 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(4) atom. The C(7)-C(8) bond length is 1.37 Å. The C(7)-H(4) bond length is 0.93 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one H(5) atom. The C(8)-H(5) bond length is 0.93 Å. There are five inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one O(3) atom. The H(11)-O(3) bond length is 0.82 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. O(3) is bonded in a water-like geometry to one C(5) and one H(11) atom. In the ZnC6NH4O2 framework, Zn(1) is bonded in a trigonal non-coplanar geometry to one N(1), one O(1), and one O(2) atom. The Zn(1)-N(1) bond length is 2.05 Å. The Zn(1)-O(1) bond length is 1.95 Å. The Zn(1)-O(2) bond length is 1.98 Å. There are six inequivalent C sites. In the first C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(7) atom. The C(10)-N(1) bond length is 1.33 Å. The C(10)-H(7) bond length is 0.93 Å. In the second C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(8) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(8) bond length is 0.93 Å. In the third C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(13) atom. The C(12)-C(12) bond length is 1.48 Å. The C(12)-C(13) bond length is 1.40 Å. In the fourth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(9) atom. The C(13)-C(14) bond length is 1.37 Å. The C(13)-H(9) bond length is 0.93 Å. In the fifth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(1), and one H(10) atom. The C(14)-N(1) bond length is 1.34 Å. The C(14)-H(10) bond length is 0.93 Å. In the sixth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.26 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(14) atom. There are four inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(1) atom. Linkers: 9 c1cc(-c2ccncc2)ccn1. Metal clusters: 18 [Zn]. The MOF has largest included sphere 9.99 A, density 0.81 g/cm3, surface area 4780.82 m2/g, accessible volume 0.75 cm3/g