Cu4P8H57(C3O)32(CH)8 crystallizes in the triclinic P1 space group. The structure consists of eight 02329_fluka molecules inside a Cu4P8H57(C3O)32 framework. In the Cu4P8H57(C3O)32 framework, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(15), one O(21), and one O(32) atom. The Cu(1)-O(1) bond length is 1.92 Å. The Cu(1)-O(15) bond length is 1.91 Å. The Cu(1)-O(21) bond length is 1.92 Å. The Cu(1)-O(32) bond length is 1.91 Å. In the second Cu site, Cu(2) is bonded in a rectangular see-saw-like geometry to one O(24), one O(29), one O(7), and one O(9) atom. The Cu(2)-O(24) bond length is 1.91 Å. The Cu(2)-O(29) bond length is 1.92 Å. The Cu(2)-O(7) bond length is 1.91 Å. The Cu(2)-O(9) bond length is 1.92 Å. In the third Cu site, Cu(3) is bonded in a rectangular see-saw-like geometry to one O(16), one O(17), one O(31), and one O(5) atom. The Cu(3)-O(16) bond length is 1.91 Å. The Cu(3)-O(17) bond length is 1.92 Å. The Cu(3)-O(31) bond length is 1.91 Å. The Cu(3)-O(5) bond length is 1.92 Å. In the fourth Cu site, Cu(4) is bonded in a rectangular see-saw-like geometry to one O(13), one O(23), one O(25), and one O(8) atom. The Cu(4)-O(13) bond length is 1.92 Å. The Cu(4)-O(23) bond length is 1.91 Å. The Cu(4)-O(25) bond length is 1.92 Å. The Cu(4)-O(8) bond length is 1.91 Å. There are ninety-six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(3), one C(6), and one C(9) atom. The C(1)-C(3) bond length is 1.42 Å. The C(1)-C(6) bond length is 1.43 Å. The C(1)-C(9) bond length is 1.42 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(3), one C(7), and one P(1) atom. The C(2)-C(3) bond length is 1.35 Å. The C(2)-C(7) bond length is 1.40 Å. The C(2)-P(1) bond length is 1.80 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(2), and one H(1) atom. The C(3)-H(1) bond length is 1.14 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(5), and one C(8) atom. The C(4)-C(12) bond length is 1.36 Å. The C(4)-C(5) bond length is 1.48 Å. The C(4)-C(8) bond length is 1.45 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(13), one C(4), and one C(6) atom. The C(5)-C(13) bond length is 1.42 Å. The C(5)-C(6) bond length is 1.43 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(5) atom. The C(6)-C(11) bond length is 1.35 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(11), one C(2), and one H(2) atom. The C(7)-C(11) bond length is 1.42 Å. The C(7)-H(2) bond length is 1.14 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(4) atom. The C(8)-C(15) bond length is 1.42 Å. The C(8)-C(17) bond length is 1.43 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(9)-H(3) bond length is 1.14 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one H(5) atom. The C(11)-H(5) bond length is 1.14 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(22), one C(4), and one O(2) atom. The C(12)-C(22) bond length is 1.41 Å. The C(12)-O(2) bond length is 1.37 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(5) and one O(3) atom. The C(13)-O(3) bond length is 1.37 Å. In the thirteenth C site, C(14) is bonded in a tetrahedral geometry to three equivalent H(6,7,8,22,23,24) and one O(3) atom. All C(14)-H(6,7,8,22,23,24) bond lengths are 1.14 Å. The C(14)-O(3) bond length is 1.47 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(8) and one H(9,25,42,57) atom. The C(15)-H(9,25,42,57) bond length is 1.14 Å. In the fifteenth C site, C(16) is bonded in a tetrahedral geometry to three equivalent H(10,11,12) and one O(2) atom. All C(16)-H(10,11,12) bond lengths are 1.14 Å. The C(16)-O(2) bond length is 1.30 Å. In the sixteenth C site, C(17) is bonded in a trigonal planar geometry to one C(18), one C(19), and one C(8) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(19) bond length is 1.40 Å. In the seventeenth C site, C(18) is bonded in a bent 120 degrees geometry to one C(17) and one C(22) atom. The C(18)-C(22) bond length is 1.43 Å. In the eighteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(17), one C(21), and one H(13) atom. The C(19)-C(21) bond length is 1.36 Å. The C(19)-H(13) bond length is 1.14 Å. In the nineteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(14) atom. The C(20)-C(21) bond length is 1.45 Å. The C(20)-H(14) bond length is 1.14 Å. In the twentieth C site, C(21) is bonded in a trigonal planar geometry to one C(19), one C(20), and one P(2) atom. The C(21)-P(2) bond length is 1.78 Å. In the twenty-first C site, C(22) is bonded in a bent 120 degrees geometry to one C(12) and one C(18) atom. In the twenty-second C site, C(23) is bonded in a distorted single-bond geometry to one O(6) atom. The C(23)-O(6) bond length is 1.43 Å. In the twenty-third C site, C(25) is bonded in a distorted linear geometry to one C(26) and one H(16) atom. The C(25)-C(26) bond length is 1.32 Å. The C(25)-H(16) bond length is 1.14 Å. In the twenty-fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one O(4) atom. The C(26)-O(4) bond length is 1.34 Å. In the twenty-fifth C site, C(27) is bonded in a trigonal planar geometry to one C(29), one C(32), and one C(35) atom. The C(27)-C(29) bond length is 1.42 Å. The C(27)-C(32) bond length is 1.43 Å. The C(27)-C(35) bond length is 1.42 Å. In the twenty-sixth C site, C(28) is bonded in a trigonal planar geometry to one C(29), one C(33), and one P(3) atom. The C(28)-C(29) bond length is 1.35 Å. The C(28)-C(33) bond length is 1.40 Å. The C(28)-P(3) bond length is 1.80 Å. In the twenty-seventh C site, C(29) is bonded in a distorted single-bond geometry to one C(27), one C(28), and one H(17) atom. The C(29)-H(17) bond length is 1.14 Å. In the twenty-eighth C site, C(30) is bonded in a trigonal planar geometry to one C(31), one C(34), and one C(38) atom. The C(30)-C(31) bond length is 1.48 Å. The C(30)-C(34) bond length is 1.45 Å. The C(30)-C(38) bond length is 1.36 Å. In the twenty-ninth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(39) atom. The C(31)-C(32) bond length is 1.43 Å. The C(31)-C(39) bond length is 1.42 Å. In the thirtieth C site, C(32) is bonded in a trigonal planar geometry to one C(27), one C(31), and one C(37) atom. The C(32)-C(37) bond length is 1.35 Å. In the thirty-first C site, C(33) is bonded in a distorted trigonal planar geometry to one C(28); one C(37); and one H(18,50) atom. The C(33)-C(37) bond length is 1.42 Å. The C(33)-H(18,50) bond length is 1.14 Å. In the thirty-second C site, C(34) is bonded in a trigonal planar geometry to one C(30), one C(41), and one C(43) atom. The C(34)-C(41) bond length is 1.42 Å. The C(34)-C(43) bond length is 1.43 Å. In the thirty-third C site, C(35) is bonded in a distorted single-bond geometry to one C(27) and one H(19) atom. The C(35)-H(19) bond length is 1.14 Å. In the thirty-fourth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(32), one C(33), and one H(21) atom. The C(37)-H(21) bond length is 1.14 Å. In the thirty-fifth C site, C(38) is bonded in a distorted single-bond geometry to one C(30) and one O(10,26) atom. The C(38)-O(10,26) bond length is 1.37 Å. In the thirty-sixth C site, C(39) is bonded in a distorted single-bond geometry to one C(31) and one O(11) atom. The C(39)-O(11) bond length is 1.37 Å. In the thirty-seventh C site, C(40) is bonded in a tetrahedral geometry to three equivalent H(6,7,8,22,23,24) and one O(11) atom. All C(40)-H(6,7,8,22,23,24) bond lengths are 1.14 Å. The C(40)-O(11) bond length is 1.47 Å. In the thirty-eighth C site, C(41) is bonded in a distorted single-bond geometry to one C(34) and one H(9,25,42,57) atom. The C(41)-H(9,25,42,57) bond length is 1.14 Å. In the thirty-ninth C site, C(42) is bonded in a tetrahedral geometry to three equivalent H(26,27,28,58,59,60) and one O(10,26) atom. All C(42)-H(26,27,28,58,59,60) bond lengths are 1.14 Å. The C(42)-O(10,26) bond length is 1.30 Å. In the fortieth C site, C(43) is bonded in a trigonal planar geometry to one C(34), one C(44), and one C(45) atom. The C(43)-C(44) bond length is 1.40 Å. The C(43)-C(45) bond length is 1.40 Å. In the forty-first C site, C(44) is bonded in a distorted single-bond geometry to one C(43) and one H(29,51,61) atom. The C(44)-H(29,51,61) bond length is 1.14 Å. In the forty-second C site, C(45) is bonded in a bent 120 degrees geometry to one C(43) and one C(47) atom. The C(45)-C(47) bond length is 1.36 Å. In the forty-third C site, C(46) is bonded in a distorted single-bond geometry to one C(47) and one H(30) atom. The C(46)-C(47) bond length is 1.45 Å. The C(46)-H(30) bond length is 1.14 Å. In the forty-fourth C site, C(47) is bonded in a trigonal planar geometry to one C(45), one C(46), and one P(4) atom. The C(47)-P(4) bond length is 1.78 Å. In the forty-fifth C site, C(49) is bonded in a distorted single-bond geometry to one C(50) and one O(14) atom. The C(49)-C(50) bond length is 1.56 Å. The C(49)-O(14) bond length is 1.43 Å. In the forty-sixth C site, C(50) is bonded in a distorted linear geometry to one C(49) and one H(32) atom. The C(50)-H(32) bond length is 1.14 Å. In the forty-seventh C site, C(51) is bonded in a linear geometry to one C(52) and one H(33) atom. The C(51)-C(52) bond length is 1.32 Å. The C(51)-H(33) bond length is 1.14 Å. In the forty-eighth C site, C(52) is bonded in a distorted single-bond geometry to one C(51) and one O(12) atom. The C(52)-O(12) bond length is 1.34 Å. In the forty-ninth C site, C(53) is bonded in a trigonal planar geometry to one C(55), one C(58), and one C(61) atom. The C(53)-C(55) bond length is 1.42 Å. The C(53)-C(58) bond length is 1.43 Å. The C(53)-C(61) bond length is 1.42 Å. In the fiftieth C site, C(54) is bonded in a trigonal planar geometry to one C(55), one C(59), and one P(5) atom. The C(54)-C(55) bond length is 1.35 Å. The C(54)-C(59) bond length is 1.40 Å. The C(54)-P(5) bond length is 1.80 Å. In the fifty-first C site, C(55) is bonded in a distorted single-bond geometry to one C(53), one C(54), and one H(34) atom. The C(55)-H(34) bond length is 1.14 Å. In the fifty-second C site, C(56) is bonded in a trigonal planar geometry to one C(57), one C(60), and one C(64) atom. The C(56)-C(57) bond length is 1.48 Å. The C(56)-C(60) bond length is 1.45 Å. The C(56)-C(64) bond length is 1.36 Å. In the fifty-third C site, C(57) is bonded in a trigonal planar geometry to one C(56), one C(58), and one C(65) atom. The C(57)-C(58) bond length is 1.43 Å. The C(57)-C(65) bond length is 1.42 Å. In the fifty-fourth C site, C(58) is bonded in a trigonal planar geometry to one C(53), one C(57), and one C(63) atom. The C(58)-C(63) bond length is 1.35 Å. In the fifty-fifth C site, C(59) is bonded in a distorted trigonal planar geometry to one C(54), one C(63), and one H(35) atom. The C(59)-C(63) bond length is 1.42 Å. The C(59)-H(35) bond length is 1.14 Å. In the fifty-sixth C site, C(60) is bonded in a trigonal planar geometry to one C(56), one C(67), and one C(69) atom. The C(60)-C(67) bond length is 1.42 Å. The C(60)-C(69) bond length is 1.43 Å. In the fifty-seventh C site, C(61) is bonded in a distorted single-bond geometry to one C(53) and one H(36) atom. The C(61)-H(36) bond length is 1.14 Å. In the fifty-eighth C site, C(63) is bonded in a distorted trigonal planar geometry to one C(58), one C(59), and one H(38) atom. The C(63)-H(38) bond length is 1.14 Å. In the fifty-ninth C site, C(64) is bonded in a distorted single-bond geometry to one C(56), one C(74), and one O(18) atom. The C(64)-C(74) bond length is 1.41 Å. The C(64)-O(18) bond length is 1.37 Å. In the sixtieth C site, C(65) is bonded in a distorted single-bond geometry to one C(57) and one O(19) atom. The C(65)-O(19) bond length is 1.37 Å. In the sixty-first C site, C(66) is bonded in a tetrahedral geometry to one H(39); two equivalent H(40,41); and one O(19) atom. The C(66)-H(39) bond length is 1.14 Å. Both C(66)-H(40,41) bond lengths are 1.14 Å. The C(66)-O(19) bond length is 1.47 Å. In the sixty-second C site, C(67) is bonded in a distorted single-bond geometry to one C(60) and one H(9,25,42,57) atom. The C(67)-H(9,25,42,57) bond length is 1.14 Å. In the sixty-third C site, C(68) is bonded in a tetrahedral geometry to three equivalent H(43,44,45) and one O(18) atom. All C(68)-H(43,44,45) bond lengths are 1.14 Å. The C(68)-O(18) bond length is 1.30 Å. In the sixty-fourth C site, C(69) is bonded in a trigonal planar geometry to one C(60), one C(70), and one C(71) atom. The C(69)-C(70) bond length is 1.40 Å. The C(69)-C(71) bond length is 1.40 Å. In the sixty-fifth C site, C(70) is bonded in a bent 120 degrees geometry to one C(69) and one C(74) atom. The C(70)-C(74) bond length is 1.43 Å. In the sixty-sixth C site, C(71) is bonded in a bent 120 degrees geometry to one C(69) and one C(73) atom. The C(71)-C(73) bond length is 1.36 Å. In the sixty-seventh C site, C(72) is bonded in a distorted single-bond geometry to one C(73) and one H(46) atom. The C(72)-C(73) bond length is 1.45 Å. The C(72)-H(46) bond length is 1.14 Å. In the sixty-eighth C site, C(73) is bonded in a trigonal planar geometry to one C(71), one C(72), and one P(6) atom. The C(73)-P(6) bond length is 1.78 Å. In the sixty-ninth C site, C(74) is bonded in a bent 120 degrees geometry to one C(64) and one C(70) atom. In the seventieth C site, C(75) is bonded in a distorted single-bond geometry to one O(22) atom. The C(75)-O(22) bond length is 1.43 Å. In the seventy-first C site, C(77) is bonded in a distorted linear geometry to one C(78) and one H(48) atom. The C(77)-C(78) bond length is 1.32 Å. The C(77)-H(48) bond length is 1.14 Å. In the seventy-second C site, C(78) is bonded in a distorted single-bond geometry to one C(77) and one O(20) atom. The C(78)-O(20) bond length is 1.34 Å. In the seventy-third C site, C(79) is bonded in a trigonal planar geometry to one C(81), one C(84), and one C(87) atom. The C(79)-C(81) bond length is 1.42 Å. The C(79)-C(84) bond length is 1.43 Å. The C(79)-C(87) bond length is 1.42 Å. In the seventy-fourth C site, C(80) is bonded in a trigonal planar geometry to one C(81), one C(85), and one P(7) atom. The C(80)-C(81) bond length is 1.35 Å. The C(80)-C(85) bond length is 1.40 Å. The C(80)-P(7) bond length is 1.80 Å. In the seventy-fifth C site, C(81) is bonded in a distorted single-bond geometry to one C(79), one C(80), and one H(49) atom. The C(81)-H(49) bond length is 1.14 Å. In the seventy-sixth C site, C(82) is bonded in a trigonal planar geometry to one C(83), one C(86), and one C(90) atom. The C(82)-C(83) bond length is 1.48 Å. The C(82)-C(86) bond length is 1.45 Å. The C(82)-C(90) bond length is 1.36 Å. In the seventy-seventh C site, C(83) is bonded in a trigonal planar geometry to one C(82), one C(84), and one C(91) atom. The C(83)-C(84) bond length is 1.43 Å. The C(83)-C(91) bond length is 1.42 Å. In the seventy-eighth C site, C(84) is bonded in a trigonal planar geometry to one C(79), one C(83), and one C(89) atom. The C(84)-C(89) bond length is 1.35 Å. In the seventy-ninth C site, C(85) is bonded in a distorted trigonal planar geometry to one C(80); one C(89); and one H(18,50) atom. The C(85)-C(89) bond length is 1.42 Å. The C(85)-H(18,50) bond length is 1.14 Å. In the eightieth C site, C(86) is bonded in a trigonal planar geometry to one C(82), one C(93), and one C(95) atom. The C(86)-C(93) bond length is 1.42 Å. The C(86)-C(95) bond length is 1.43 Å. In the eighty-first C site, C(87) is bonded in a distorted single-bond geometry to one C(79) and one H(29,51,61) atom. The C(87)-H(29,51,61) bond length is 1.14 Å. In the eighty-second C site, C(89) is bonded in a distorted trigonal planar geometry to one C(84), one C(85), and one H(53) atom. The C(89)-H(53) bond length is 1.14 Å. In the eighty-third C site, C(90) is bonded in a distorted single-bond geometry to one C(82) and one O(10,26) atom. The C(90)-O(10,26) bond length is 1.37 Å. In the eighty-fourth C site, C(91) is bonded in a distorted single-bond geometry to one C(83) and one O(27) atom. The C(91)-O(27) bond length is 1.37 Å. In the eighty-fifth C site, C(92) is bonded in a tetrahedral geometry to three equivalent H(54,55,56) and one O(27) atom. All C(92)-H(54,55,56) bond lengths are 1.14 Å. The C(92)-O(27) bond length is 1.47 Å. In the eighty-sixth C site, C(93) is bonded in a distorted single-bond geometry to one C(86) and one H(9,25,42,57) atom. The C(93)-H(9,25,42,57) bond length is 1.14 Å. In the eighty-seventh C site, C(94) is bonded in a tetrahedral geometry to three equivalent H(26,27,28,58,59,60) and one O(10,26) atom. All C(94)-H(26,27,28,58,59,60) bond lengths are 1.14 Å. The C(94)-O(10,26) bond length is 1.30 Å. In the eighty-eighth C site, C(95) is bonded in a trigonal planar geometry to one C(86), one C(96), and one C(97) atom. The C(95)-C(96) bond length is 1.40 Å. The C(95)-C(97) bond length is 1.40 Å. In the eighty-ninth C site, C(96) is bonded in a distorted single-bond geometry to one C(95) and one H(29,51,61) atom. The C(96)-H(29,51,61) bond length is 1.14 Å. In the ninetieth C site, C(97) is bonded in a bent 120 degrees geometry to one C(95) and one C(99) atom. The C(97)-C(99) bond length is 1.36 Å. In the ninety-first C site, C(98) is bonded in a distorted single-bond geometry to one C(99) and one H(62) atom. The C(98)-C(99) bond length is 1.45 Å. The C(98)-H(62) bond length is 1.14 Å. In the ninety-second C site, C(99) is bonded in a trigonal planar geometry to one C(97), one C(98), and one P(8) atom. The C(99)-P(8) bond length is 1.78 Å. In the ninety-third C site, C(101) is bonded in a distorted single-bond geometry to one C(102) and one O(30) atom. The C(101)-C(102) bond length is 1.56 Å. The C(101)-O(30) bond length is 1.43 Å. In the ninety-fourth C site, C(102) is bonded in a distorted linear geometry to one C(101) and one H(64) atom. The C(102)-H(64) bond length is 1.14 Å. In the ninety-fifth C site, C(103) is bonded in a linear geometry to one C(104) and one H(65) atom. The C(103)-C(104) bond length is 1.32 Å. The C(103)-H(65) bond length is 1.14 Å. In the ninety-sixth C site, C(104) is bonded in a distorted single-bond geometry to one C(103) and one O(28) atom. The C(104)-O(28) bond length is 1.34 Å. There are eight inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one C(2), one O(1), one O(4), and one O(8) atom. The P(1)-O(1) bond length is 1.51 Å. The P(1)-O(4) bond length is 1.57 Å. The P(1)-O(8) bond length is 1.52 Å. In the second P site, P(2) is bonded in a tetrahedral geometry to one C(21), one O(5), one O(6), and one O(7) atom. The P(2)-O(5) bond length is 1.47 Å. The P(2)-O(6) bond length is 1.58 Å. The P(2)-O(7) bond length is 1.50 Å. In the third P site, P(3) is bonded in a tetrahedral geometry to one C(28), one O(12), one O(16), and one O(9) atom. The P(3)-O(12) bond length is 1.57 Å. The P(3)-O(16) bond length is 1.52 Å. The P(3)-O(9) bond length is 1.51 Å. In the fourth P site, P(4) is bonded in a tetrahedral geometry to one C(47), one O(13), one O(14), and one O(15) atom. The P(4)-O(13) bond length is 1.47 Å. The P(4)-O(14) bond length is 1.58 Å. The P(4)-O(15) bond length is 1.50 Å. In the fifth P site, P(5) is bonded in a tetrahedral geometry to one C(54), one O(17), one O(20), and one O(24) atom. The P(5)-O(17) bond length is 1.51 Å. The P(5)-O(20) bond length is 1.57 Å. The P(5)-O(24) bond length is 1.52 Å. In the sixth P site, P(6) is bonded in a tetrahedral geometry to one C(73), one O(21), one O(22), and one O(23) atom. The P(6)-O(21) bond length is 1.47 Å. The P(6)-O(22) bond length is 1.58 Å. The P(6)-O(23) bond length is 1.50 Å. In the seventh P site, P(7) is bonded in a tetrahedral geometry to one C(80), one O(25), one O(28), and one O(32) atom. The P(7)-O(25) bond length is 1.51 Å. The P(7)-O(28) bond length is 1.57 Å. The P(7)-O(32) bond length is 1.52 Å. In the eighth P site, P(8) is bonded in a tetrahedral geometry to one C(99), one O(29), one O(30), and one O(31) atom. The P(8)-O(29) bond length is 1.47 Å. The P(8)-O(30) bond length is 1.58 Å. The P(8)-O(31) bond length is 1.50 Å. There are thirty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(6,7,8,22,23,24) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(9,25,42,57) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(10,11,12) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(18,50) is bonded in a single-bond geometry to one C(33) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(35) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(37) atom. In the fifteenth H site, H(26,27,28,58,59,60) is bonded in a single-bond geometry to one C(42) atom. In the sixteenth H site, H(29,51,61) is bonded in a single-bond geometry to one C(44) atom. In the seventeenth H site, H(30) is bonded in a single-bond geometry to one C(46) atom. In the eighteenth H site, H(32) is bonded in a single-bond geometry to one C(50) atom. In the nineteenth H site, H(33) is bonded in a single-bond geometry to one C(51) atom. In the twentieth H site, H(34) is bonded in a single-bond geometry to one C(55) atom. In the twenty-first H site, H(35) is bonded in a single-bond geometry to one C(59) atom. In the twenty-second H site, H(36) is bonded in a single-bond geometry to one C(61) atom. In the twenty-third H site, H(38) is bonded in a single-bond geometry to one C(63) atom. In the twenty-fourth H site, H(39) is bonded in a single-bond geometry to one C(66) atom. In the twenty-fifth H site, H(40,41) is bonded in a single-bond geometry to one C(66) atom. In the twenty-sixth H site, H(43,44,45) is bonded in a single-bond geometry to one C(68) atom. In the twenty-seventh H site, H(46) is bonded in a single-bond geometry to one C(72) atom. In the twenty-eighth H site, H(48) is bonded in a single-bond geometry to one C(77) atom. In the twenty-ninth H site, H(49) is bonded in a single-bond geometry to one C(81) atom. In the thirtieth H site, H(53) is bonded in a single-bond geometry to one C(89) atom. In the thirty-first H site, H(54,55,56) is bonded in a single-bond geometry to one C(92) atom. In the thirty-second H site, H(62) is bonded in a single-bond geometry to one C(98) atom. In the thirty-third H site, H(64) is bonded in a single-bond geometry to one C(102) atom. In the thirty-fourth H site, H(65) is bonded in a single-bond geometry to one C(103) atom. There are thirty-one inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one C(12) and one C(16) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one C(13) and one C(14) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one C(26) and one P(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Cu(3) and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one C(23) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one P(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(4) and one P(1) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(2) and one P(3) atom. In the tenth O site, O(10,26) is bonded in a bent 120 degrees geometry to one C(38) and one C(42) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one C(39) and one C(40) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one C(52) and one P(3) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Cu(4) and one P(4) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one C(49) and one P(4) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one P(4) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Cu(3) and one P(3) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Cu(3) and one P(5) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one C(64) and one C(68) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one C(65) and one C(66) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one C(78) and one P(5) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one P(6) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one C(75) and one P(6) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one P(6) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Cu(2) and one P(5) atom. In the twenty-fifth O site, O(25) is bonded in a bent 120 degrees geometry to one Cu(4) and one P(7) atom. In the twenty-sixth O site, O(27) is bonded in a bent 120 degrees geometry to one C(91) and one C(92) atom. In the twenty-seventh O site, O(28) is bonded in a bent 120 degrees geometry to one C(104) and one P(7) atom. In the twenty-eighth O site, O(29) is bonded in a distorted bent 150 degrees geometry to one Cu(2) and one P(8) atom. In the twenty-ninth O site, O(30) is bonded in a bent 120 degrees geometry to one C(101) and one P(8) atom. In the thirtieth O site, O(31) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one P(8) atom. In the thirty-first O site, O(32) is bonded in a bent 120 degrees geometry to one Cu(1) and one P(7) atom. Linkers: 1 [CH][C]O[P@@]([O])(=O)c1[c]c2ccc(OC)c(-c3c(OC)ccc4cc([P@]([O])(=O)O[C][CH])ccc34)c2cc1 ,1 [CH][C]O[P@@]([O])(=O)c1ccc2c(-c3c(OC)ccc4cc([P@]([O])(=O)O[C][CH])ccc34)c(OC)[c][c]c2c1 ,1 [CH][C]O[P@]([O])(=O)c1[c]c2[c][c]c(OC)c(-c3c(OC)ccc4cc([P@@]([O])(=O)O[C][CH])ccc34)c2cc1 ,1 [CH][C]O[P@]([O])(=O)c1[c]c2ccc(OC)c(-c3c(OC)ccc4cc([P@@]([O])(=O)O[C][CH])ccc34)c2cc1. Metal clusters: 4 [Cu]. RCSR code: lvt. The MOF has largest included sphere 3.99 A, density 1.37 g/cm3, surface area 4751.48 m2/g, accessible volume 0.23 cm3/g