Co7C28H22(NO)18(CH)32 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, twelve isobutylene molecules, and two Co7C28H22(NO)18 clusters. In each Co7C28H22(NO)18 cluster, there are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(5), one N(7), one O(1), one O(5), and one O(9) atom to form distorted CoN2O3 square pyramids that share  a cornercorner with one Co(2)N2O4 octahedra,  a cornercorner with one Co(4)O6 octahedra, and  a cornercorner with one Co(3)N2O3 square pyramid. The corner-sharing octahedral tilt angles range from 51-67°. The Co(1)-N(5) bond length is 2.15 Å. The Co(1)-N(7) bond length is 2.14 Å. The Co(1)-O(1) bond length is 2.01 Å. The Co(1)-O(5) bond length is 2.09 Å. The Co(1)-O(9) bond length is 2.17 Å. In the second Co site, Co(2) is bonded to one N(6), one N(8), one O(1), one O(2), one O(3), and one O(6) atom to form CoN2O4 octahedra that share  a cornercorner with one Co(1)N2O3 square pyramid,  a cornercorner with one Co(3)N2O3 square pyramid, and  an edgeedge with one Co(4)O6 octahedra. The Co(2)-N(6) bond length is 2.10 Å. The Co(2)-N(8) bond length is 2.11 Å. The Co(2)-O(1) bond length is 2.07 Å. The Co(2)-O(2) bond length is 2.10 Å. The Co(2)-O(3) bond length is 2.06 Å. The Co(2)-O(6) bond length is 2.08 Å. In the third Co site, Co(3) is bonded to one N(1), one N(9), one O(2), one O(4), and one O(9) atom to form distorted CoN2O3 square pyramids that share  a cornercorner with one Co(2)N2O4 octahedra,  a cornercorner with one Co(4)O6 octahedra, and  a cornercorner with one Co(1)N2O3 square pyramid. The corner-sharing octahedral tilt angles range from 52-67°. The Co(3)-N(1) bond length is 2.14 Å. The Co(3)-N(9) bond length is 2.15 Å. The Co(3)-O(2) bond length is 2.03 Å. The Co(3)-O(4) bond length is 2.10 Å. The Co(3)-O(9) bond length is 2.17 Å. In the fourth Co site, Co(4) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent O(8) atoms to form CoO6 octahedra that share corners with two equivalent Co(1)N2O3 square pyramids, corners with two equivalent Co(3)N2O3 square pyramids, and edges with two equivalent Co(2)N2O4 octahedra. Both Co(4)-O(1) bond lengths are 2.06 Å. Both Co(4)-O(2) bond lengths are 2.08 Å. Both Co(4)-O(8) bond lengths are 2.17 Å. There are fourteen inequivalent C sites. In the first C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(8)-O(7) bond length is 1.25 Å. The C(8)-O(8) bond length is 1.25 Å. In the second C site, C(9) is bonded in a distorted single-bond geometry to one N(4) atom. The C(9)-N(4) bond length is 1.45 Å. In the third C site, C(11) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(11)-C(3) bond length is 1.37 Å. The C(11)-H(4) bond length is 0.93 Å. In the fourth C site, C(13) is bonded in a trigonal planar geometry to one N(4), one N(7), and one H(6) atom. The C(13)-N(4) bond length is 1.36 Å. The C(13)-N(7) bond length is 1.30 Å. The C(13)-H(6) bond length is 0.93 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one N(3) atom. The C(10)-N(3) bond length is 1.44 Å. In the sixth C site, C(16) is bonded in a trigonal planar geometry to one N(3), one N(5), and one H(9) atom. The C(16)-N(3) bond length is 1.36 Å. The C(16)-N(5) bond length is 1.31 Å. The C(16)-H(9) bond length is 0.93 Å. In the seventh C site, C(17) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(10) atom. The C(17)-N(1) bond length is 1.31 Å. The C(17)-N(2) bond length is 1.34 Å. The C(17)-H(10) bond length is 0.93 Å. In the eighth C site, C(19) is bonded in a trigonal planar geometry to one N(3), one N(8), and one H(13) atom. The C(19)-N(3) bond length is 1.36 Å. The C(19)-N(8) bond length is 1.30 Å. The C(19)-H(13) bond length is 0.93 Å. In the ninth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(5) atom. The C(20)-O(3) bond length is 1.25 Å. The C(20)-O(5) bond length is 1.25 Å. In the tenth C site, C(25) is bonded in a trigonal planar geometry to one N(2), one N(6), and one H(18) atom. The C(25)-N(2) bond length is 1.35 Å. The C(25)-N(6) bond length is 1.30 Å. The C(25)-H(18) bond length is 0.93 Å. In the eleventh C site, C(30) is bonded in a distorted single-bond geometry to one C(3) and one H(24) atom. The C(30)-C(3) bond length is 1.35 Å. The C(30)-H(24) bond length is 0.93 Å. In the twelfth C site, C(1) is bonded in a trigonal planar geometry to one N(4), one N(9), and one H(1) atom. The C(1)-N(4) bond length is 1.36 Å. The C(1)-N(9) bond length is 1.29 Å. The C(1)-H(1) bond length is 0.93 Å. In the thirteenth C site, C(3) is bonded in a trigonal planar geometry to one C(11), one C(30), and one N(2) atom. The C(3)-N(2) bond length is 1.46 Å. In the fourteenth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. The C(4)-O(4) bond length is 1.27 Å. The C(4)-O(6) bond length is 1.24 Å. There are nine inequivalent N sites. In the first N site, N(9) is bonded in a 3-coordinate geometry to one Co(3), one C(1), and one N(7) atom. The N(9)-N(7) bond length is 1.40 Å. In the second N site, N(1) is bonded in a 3-coordinate geometry to one Co(3), one C(17), and one N(6) atom. The N(1)-N(6) bond length is 1.36 Å. In the third N site, N(2) is bonded in a trigonal planar geometry to one C(17), one C(25), and one C(3) atom. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one C(10), one C(16), and one C(19) atom. In the fifth N site, N(4) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(9) atom. In the sixth N site, N(5) is bonded in a distorted trigonal planar geometry to one Co(1), one C(16), and one N(8) atom. The N(5)-N(8) bond length is 1.37 Å. In the seventh N site, N(6) is bonded in a 3-coordinate geometry to one Co(2), one C(25), and one N(1) atom. In the eighth N site, N(7) is bonded in a distorted trigonal planar geometry to one Co(1), one C(13), and one N(9) atom. In the ninth N site, N(8) is bonded in a 3-coordinate geometry to one Co(2), one C(19), and one N(5) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(25) atom. In the eighth H site, H(24) is bonded in a single-bond geometry to one C(30) atom. In the ninth H site, H(25) is bonded in a single-bond geometry to one O(2) atom. The H(25)-O(2) bond length is 0.84 Å. In the tenth H site, H(26) is bonded in a single-bond geometry to one O(1) atom. The H(26)-O(1) bond length is 0.84 Å. In the eleventh H site, H(27) is bonded in a single-bond geometry to one O(9) atom. The H(27)-O(9) bond length is 0.84 Å. There are nine inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(20) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Co(1), one Co(2), one Co(4), and one H(26) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Co(2), one Co(3), one Co(4), and one H(25) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(3) and one C(4) atom. In the fifth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one C(4) atom. In the sixth O site, O(7) is bonded in a single-bond geometry to one C(8) atom. In the seventh O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Co(4) and one C(8) atom. In the eighth O site, O(9) is bonded in a distorted single-bond geometry to one Co(1), one Co(3), and one H(27) atom. In the ninth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(20) atom. Linkers: 12 [O]C(=O)Cc1ccc(-n2cnnc2)cc1. Metal clusters: 2 O=[C]O[Co]O[C]=O.O[Co@]12N=N[Co@@]3(N=N[Co](O)(O)(/N=N\[Co@@]4(O)N=N[Co@]5(N=N[Co](O)(O)(/N=N\1)O[C]O5)O[C]O4)O[C]O3)O[C]O2. The MOF has largest included sphere 7.73 A, density 1.04 g/cm3, surface area 3854.74 m2/g, accessible volume 0.49 cm3/g