CuC12(OF2)4(C7HF4)2 is Indium-derived structured and crystallizes in the cubic F432 space group. The structure is zero-dimensional and consists of thirty-two C7HF4 clusters and twenty-four CuC12(OF2)4 clusters. In each C7HF4 cluster, there are seven inequivalent C sites. In the first C site, C(7) is bonded in a distorted single-bond geometry to one C(3) and one F(6) atom. The C(7)-C(3) bond length is 1.48 Å. The C(7)-F(6) bond length is 1.36 Å. In the second C site, C(12) is bonded in a trigonal planar geometry to one C(3) and two equivalent C(13) atoms. The C(12)-C(3) bond length is 1.51 Å. Both C(12)-C(13) bond lengths are 1.37 Å. In the third C site, C(8) is bonded in a distorted single-bond geometry to one C(3) and one F(7) atom. The C(8)-C(3) bond length is 1.33 Å. The C(8)-F(7) bond length is 1.34 Å. In the fourth C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one F(2) atom. The C(2)-C(3) bond length is 1.45 Å. The C(2)-F(2) bond length is 1.36 Å. In the fifth C site, C(3) is bonded in a 5-coordinate geometry to one C(12), one C(2), one C(4), one C(7), and one C(8) atom. The C(3)-C(4) bond length is 1.36 Å. In the sixth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one F(3) atom. The C(4)-F(3) bond length is 1.34 Å. In the seventh C site, C(13) is bonded in a single-bond geometry to two equivalent C(12) and one H(1) atom. The C(13)-H(1) bond length is 0.93 Å. H(1) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one C(2) atom. In the second F site, F(3) is bonded in a single-bond geometry to one C(4) atom. In the third F site, F(6) is bonded in a single-bond geometry to one C(7) atom. In the fourth F site, F(7) is bonded in a single-bond geometry to one C(8) atom. In each CuC12(OF2)4 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one Cu(1) and four equivalent O(1,2) atoms. The Cu(1)-Cu(1) bond length is 2.69 Å. All Cu(1)-O(1,2) bond lengths are 1.98 Å. There are four inequivalent C sites. In the first C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11) and two equivalent O(1,2) atoms. The C(10)-C(11) bond length is 1.53 Å. Both C(10)-O(1,2) bond lengths are 1.22 Å. In the second C site, C(11) is bonded in a 5-coordinate geometry to one C(10); two equivalent C(1,6); and two equivalent C(5,9) atoms. Both C(11)-C(1,6) bond lengths are 1.39 Å. Both C(11)-C(5,9) bond lengths are 1.38 Å. In the third C site, C(1,6) is bonded in a distorted single-bond geometry to one C(11) and one F(1,5) atom. The C(1,6)-F(1,5) bond length is 1.28 Å. In the fourth C site, C(5,9) is bonded in a distorted single-bond geometry to one C(11) and one F(4,8) atom. The C(5,9)-F(4,8) bond length is 1.37 Å. O(1,2) is bonded in a single-bond geometry to one Cu(1) and one C(10) atom. There are two inequivalent F sites. In the first F site, F(1,5) is bonded in a single-bond geometry to one C(1,6) atom. In the second F site, F(4,8) is bonded in a single-bond geometry to one C(5,9) atom. Linkers: 32 F[C@]12C34[C@@]1(F)[C@@]1(F)C5([C@@]21F)[C@]1(F)[C@@]3(F)[C@@]4(F)[C@]51F.F[C@]12C34[C@@]1(F)[C@@]1(F)C5([C@@]21F)[C@]1(F)[C@@]3(F)[C@@]4(F)[C@]51F.F[C@]12C34[C@@]1(F)[C@@]1(F)C5([C@@]21F)[C@]1(F)[C@@]3(F)[C@@]4(F)[C@]51F.[O][C]=O.[O][C]=O.[O][C]=O.[c]1c[c]c[c]c1. Metal clusters: 24 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: tbo. The MOF has largest included sphere 27.96 A, density 0.56 g/cm3, surface area 3177.87 m2/g, accessible volume 1.36 cm3/g