Cd2Zn7C26P6H34(NO5)6(CH2)10 crystallizes in the monoclinic C2/c space group. The structure consists of forty 02329_fluka molecules inside a Cd2Zn7C26P6H34(NO5)6 framework. In the Cd2Zn7C26P6H34(NO5)6 framework, Cd(1) is bonded in a 5-coordinate geometry to one O(11), one O(4), one O(5), one O(6), and one O(7) atom. The Cd(1)-O(11) bond length is 2.29 Å. The Cd(1)-O(4) bond length is 2.72 Å. The Cd(1)-O(5) bond length is 2.33 Å. The Cd(1)-O(6) bond length is 2.71 Å. The Cd(1)-O(7) bond length is 2.36 Å. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(2), one O(1), one O(12), one O(15), and one O(9) atom to form ZnNO4 trigonal bipyramids that share  a cornercorner with one Zn(4)O6 octahedra,  a cornercorner with one C(18)PH2N tetrahedra,  a cornercorner with one P(1)CO3 tetrahedra,  a cornercorner with one P(2)CO3 tetrahedra, and  a cornercorner with one P(3)CO3 tetrahedra. The corner-sharing octahedral tilt angles are 62°. The Zn(1)-N(2) bond length is 2.10 Å. The Zn(1)-O(1) bond length is 1.95 Å. The Zn(1)-O(12) bond length is 2.07 Å. The Zn(1)-O(15) bond length is 2.16 Å. The Zn(1)-O(9) bond length is 1.99 Å. In the second Zn site, Zn(2) is bonded to one N(1), one O(10), one O(13), one O(2), and one O(4) atom to form distorted ZnNO4 trigonal bipyramids that share  a cornercorner with one Zn(4)O6 octahedra,  a cornercorner with one C(4)PH2N tetrahedra,  a cornercorner with one P(1)CO3 tetrahedra,  a cornercorner with one P(2)CO3 tetrahedra, and  a cornercorner with one P(3)CO3 tetrahedra. The corner-sharing octahedral tilt angles are 63°. The Zn(2)-N(1) bond length is 2.13 Å. The Zn(2)-O(10) bond length is 1.95 Å. The Zn(2)-O(13) bond length is 1.98 Å. The Zn(2)-O(2) bond length is 2.12 Å. The Zn(2)-O(4) bond length is 2.04 Å. In the third Zn site, Zn(3) is bonded to one N(3), one O(14), one O(3), one O(6), and one O(8) atom to form distorted ZnNO4 trigonal bipyramids that share  a cornercorner with one Zn(4)O6 octahedra,  a cornercorner with one C(12)PH2N tetrahedra,  a cornercorner with one P(1)CO3 tetrahedra,  a cornercorner with one P(2)CO3 tetrahedra, and  a cornercorner with one P(3)CO3 tetrahedra. The corner-sharing octahedral tilt angles are 62°. The Zn(3)-N(3) bond length is 2.15 Å. The Zn(3)-O(14) bond length is 1.95 Å. The Zn(3)-O(3) bond length is 1.99 Å. The Zn(3)-O(6) bond length is 2.03 Å. The Zn(3)-O(8) bond length is 2.14 Å. In the fourth Zn site, Zn(4) is bonded to two equivalent O(15), two equivalent O(2), and two equivalent O(8) atoms to form ZnO6 octahedra that share corners with two equivalent P(1)CO3 tetrahedra, corners with two equivalent P(2)CO3 tetrahedra, corners with two equivalent P(3)CO3 tetrahedra, corners with two equivalent Zn(1)NO4 trigonal bipyramids, corners with two equivalent Zn(2)NO4 trigonal bipyramids, and corners with two equivalent Zn(3)NO4 trigonal bipyramids. Both Zn(4)-O(15) bond lengths are 2.10 Å. Both Zn(4)-O(2) bond lengths are 2.10 Å. Both Zn(4)-O(8) bond lengths are 2.11 Å. There are thirteen inequivalent C sites. In the first C site, C(3) is bonded in a 3-coordinate geometry to one N(1) and two equivalent H(5,6) atoms. The C(3)-N(1) bond length is 1.51 Å. Both C(3)-H(5,6) bond lengths are 0.97 Å. In the second C site, C(4) is bonded to one P(1); one N(1); and two equivalent H(7,8) atoms to form distorted CPH2N tetrahedra that share  a cornercorner with one Zn(2)NO4 trigonal bipyramid. The C(4)-P(1) bond length is 1.83 Å. The C(4)-N(1) bond length is 1.47 Å. Both C(4)-H(7,8) bond lengths are 0.97 Å. In the third C site, C(5) is bonded in a 2-coordinate geometry to one N(1) and one H(9) atom. The C(5)-N(1) bond length is 1.52 Å. The C(5)-H(9) bond length is 0.98 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(6)-O(4) bond length is 1.26 Å. The C(6)-O(5) bond length is 1.27 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(7)-O(6) bond length is 1.27 Å. The C(7)-O(7) bond length is 1.26 Å. In the sixth C site, C(8) is bonded in a 2-coordinate geometry to one N(3) and one H(10) atom. The C(8)-N(3) bond length is 1.52 Å. The C(8)-H(10) bond length is 0.98 Å. In the seventh C site, C(11) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(15,16) atoms. The C(11)-N(3) bond length is 1.49 Å. Both C(11)-H(15,16) bond lengths are 0.97 Å. In the eighth C site, C(12) is bonded to one P(2); one N(3); and two equivalent H(17,18) atoms to form distorted CPH2N tetrahedra that share  a cornercorner with one Zn(3)NO4 trigonal bipyramid. The C(12)-P(2) bond length is 1.82 Å. The C(12)-N(3) bond length is 1.50 Å. Both C(12)-H(17,18) bond lengths are 0.97 Å. In the ninth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one O(11), and one O(12) atom. The C(13)-C(14) bond length is 1.54 Å. The C(13)-O(11) bond length is 1.27 Å. The C(13)-O(12) bond length is 1.25 Å. In the tenth C site, C(14) is bonded in a 2-coordinate geometry to one C(13), one N(2), and one H(19) atom. The C(14)-N(2) bond length is 1.50 Å. The C(14)-H(19) bond length is 0.98 Å. In the eleventh C site, C(16) is bonded in a water-like geometry to one C(17) and two equivalent H(22,23) atoms. The C(16)-C(17) bond length is 1.51 Å. Both C(16)-H(22,23) bond lengths are 0.97 Å. In the twelfth C site, C(17) is bonded in a 4-coordinate geometry to one C(16), one N(2), one H(24), and one H(25) atom. The C(17)-N(2) bond length is 1.52 Å. The C(17)-H(24) bond length is 0.97 Å. The C(17)-H(25) bond length is 0.97 Å. In the thirteenth C site, C(18) is bonded to one P(3); one N(2); and two equivalent H(26,27) atoms to form distorted CPH2N tetrahedra that share  a cornercorner with one Zn(1)NO4 trigonal bipyramid. The C(18)-P(3) bond length is 1.82 Å. The C(18)-N(2) bond length is 1.49 Å. Both C(18)-H(26,27) bond lengths are 0.97 Å. There are three inequivalent P sites. In the first P site, P(1) is bonded to one C(4), one O(1), one O(2), and one O(3) atom to form PCO3 tetrahedra that share  a cornercorner with one Zn(4)O6 octahedra,  a cornercorner with one N(1)ZnC3 tetrahedra,  a cornercorner with one Zn(1)NO4 trigonal bipyramid,  a cornercorner with one Zn(2)NO4 trigonal bipyramid, and  a cornercorner with one Zn(3)NO4 trigonal bipyramid. The corner-sharing octahedral tilt angles are 51°. The P(1)-O(1) bond length is 1.53 Å. The P(1)-O(2) bond length is 1.55 Å. The P(1)-O(3) bond length is 1.52 Å. In the second P site, P(2) is bonded to one C(12), one O(10), one O(8), and one O(9) atom to form PCO3 tetrahedra that share  a cornercorner with one Zn(4)O6 octahedra,  a cornercorner with one N(3)ZnC3 tetrahedra,  a cornercorner with one Zn(1)NO4 trigonal bipyramid,  a cornercorner with one Zn(2)NO4 trigonal bipyramid, and  a cornercorner with one Zn(3)NO4 trigonal bipyramid. The corner-sharing octahedral tilt angles are 51°. The P(2)-O(10) bond length is 1.53 Å. The P(2)-O(8) bond length is 1.55 Å. The P(2)-O(9) bond length is 1.53 Å. In the third P site, P(3) is bonded to one C(18), one O(13), one O(14), and one O(15) atom to form PCO3 tetrahedra that share  a cornercorner with one Zn(4)O6 octahedra,  a cornercorner with one N(2)ZnC3 tetrahedra,  a cornercorner with one Zn(1)NO4 trigonal bipyramid,  a cornercorner with one Zn(2)NO4 trigonal bipyramid, and  a cornercorner with one Zn(3)NO4 trigonal bipyramid. The corner-sharing octahedral tilt angles are 53°. The P(3)-O(13) bond length is 1.54 Å. The P(3)-O(14) bond length is 1.52 Å. The P(3)-O(15) bond length is 1.55 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded to one Zn(2), one C(3), one C(4), and one C(5) atom to form NZnC3 tetrahedra that share  a cornercorner with one P(1)CO3 tetrahedra. In the second N site, N(2) is bonded to one Zn(1), one C(14), one C(17), and one C(18) atom to form NZnC3 tetrahedra that share  a cornercorner with one P(3)CO3 tetrahedra. In the third N site, N(3) is bonded to one Zn(3), one C(11), one C(12), and one C(8) atom to form NZnC3 tetrahedra that share  a cornercorner with one P(2)CO3 tetrahedra. There are eleven inequivalent H sites. In the first H site, H(5,6) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(7,8) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(15,16) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(17,18) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(22,23) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(24) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(25) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(26,27) is bonded in a single-bond geometry to one C(18) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Zn(2), one Zn(4), and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cd(1), one Zn(2), and one C(6) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Cd(1) and one C(6) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cd(1), one Zn(3), and one C(7) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Cd(1) and one C(7) atom. In the eighth O site, O(8) is bonded in a trigonal planar geometry to one Zn(3), one Zn(4), and one P(2) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(2) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(2) and one P(2) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(13) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(2) and one P(3) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(3) atom. In the fifteenth O site, O(15) is bonded in a trigonal planar geometry to one Zn(1), one Zn(4), and one P(3) atom. Linkers: 6 [O]C(=O)[C@@H]1CCCN1CP([O])([O])=O ,6 [O]C(=O)[C@H]1CCCN1CP([O])([O])=O. Metal clusters: 14 [Zn] ,4 [Cd]. The MOF has largest included sphere 6.67 A, density 1.49 g/cm3, surface area 3203.88 m2/g, accessible volume 0.36 cm3/g