CuH16(CN)12(CH2)4 is Indium-derived structured and crystallizes in the orthorhombic Fddd space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules and eight CuH16(CN)12 clusters. In each CuH16(CN)12 cluster, Cu(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. All Cu(1)-N(1) bond lengths are 2.01 Å. There are three inequivalent C sites. In the first C site, C(3) is bonded in a 3-coordinate geometry to one N(2), one H(3), and one H(4) atom. The C(3)-N(2) bond length is 1.46 Å. The C(3)-H(3) bond length is 0.97 Å. The C(3)-H(4) bond length is 0.97 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-N(3) bond length is 1.31 Å. The C(1)-H(1) bond length is 0.93 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(2) atom. The C(2)-N(1) bond length is 1.32 Å. The C(2)-N(2) bond length is 1.31 Å. The C(2)-H(2) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(3) is bonded in a distorted water-like geometry to one C(1) and one N(2) atom. The N(3)-N(2) bond length is 1.37 Å. In the second N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the third N site, N(2) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one N(3) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. Linkers: 5 [CH]1N=C[N]N1CCCCn1cncn1 ,11 [CH]1N=C[N]N1CCCCN1[CH]N=C[N]1. Metal clusters: 8 [Cu]. The MOF has largest included sphere 3.86 A, density 1.10 g/cm3, surface area 5382.38 m2/g, accessible volume 0.52 cm3/g