CuH16(CN)12(CH2)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four CuH16(CN)12 clusters. In each CuH16(CN)12 cluster, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(10), one N(6), and one N(7) atom. The Cu(1)-N(1) bond length is 2.00 Å. The Cu(1)-N(10) bond length is 2.01 Å. The Cu(1)-N(6) bond length is 1.99 Å. The Cu(1)-N(7) bond length is 2.00 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.31 Å. The C(1)-N(3) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(2) atom. The C(2)-N(1) bond length is 1.36 Å. The C(2)-N(2) bond length is 1.36 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(3,4) atoms. The C(3)-N(3) bond length is 1.50 Å. Both C(3)-H(3,4) bond lengths are 0.97 Å. In the fourth C site, C(6) is bonded in a 3-coordinate geometry to one N(5), one H(10), and one H(9) atom. The C(6)-N(5) bond length is 1.43 Å. The C(6)-H(10) bond length is 0.97 Å. The C(6)-H(9) bond length is 0.97 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(11) atom. The C(7)-N(5) bond length is 1.34 Å. The C(7)-N(6) bond length is 1.34 Å. The C(7)-H(11) bond length is 0.93 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(12) atom. The C(8)-N(4) bond length is 1.33 Å. The C(8)-N(6) bond length is 1.34 Å. The C(8)-H(12) bond length is 0.93 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(13) atom. The C(9)-N(7) bond length is 1.40 Å. The C(9)-N(9) bond length is 1.30 Å. The C(9)-H(13) bond length is 0.93 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(14) atom. The C(10)-N(7) bond length is 1.36 Å. The C(10)-N(8) bond length is 1.30 Å. The C(10)-H(14) bond length is 0.93 Å. In the ninth C site, C(11) is bonded in a 3-coordinate geometry to one N(8), one H(15), and one H(16) atom. The C(11)-N(8) bond length is 1.52 Å. The C(11)-H(15) bond length is 0.97 Å. The C(11)-H(16) bond length is 0.97 Å. In the tenth C site, C(13) is bonded in a trigonal planar geometry to one N(10), one N(11), and one H(19) atom. The C(13)-N(10) bond length is 1.38 Å. The C(13)-N(11) bond length is 1.31 Å. The C(13)-H(19) bond length is 0.93 Å. In the eleventh C site, C(14) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(20) atom. The C(14)-N(10) bond length is 1.30 Å. The C(14)-N(12) bond length is 1.28 Å. The C(14)-H(20) bond length is 0.93 Å. In the twelfth C site, C(15) is bonded in a 3-coordinate geometry to one N(12) and two equivalent H(21,22) atoms. The C(15)-N(12) bond length is 1.46 Å. Both C(15)-H(21,22) bond lengths are 0.97 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a water-like geometry to one C(2) and one N(3) atom. The N(2)-N(3) bond length is 1.33 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(2) atom. In the fourth N site, N(4) is bonded in a water-like geometry to one C(8) and one N(5) atom. The N(4)-N(5) bond length is 1.38 Å. In the fifth N site, N(5) is bonded in a 2-coordinate geometry to one C(6), one C(7), and one N(4) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(7), and one C(8) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(9) atom. In the eighth N site, N(8) is bonded in a distorted bent 120 degrees geometry to one C(10), one C(11), and one N(9) atom. The N(8)-N(9) bond length is 1.32 Å. In the ninth N site, N(9) is bonded in a distorted water-like geometry to one C(9) and one N(8) atom. In the tenth N site, N(10) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(13), and one C(14) atom. In the eleventh N site, N(11) is bonded in a distorted water-like geometry to one C(13) and one N(12) atom. The N(11)-N(12) bond length is 1.36 Å. In the twelfth N site, N(12) is bonded in a 3-coordinate geometry to one C(14), one C(15), and one N(11) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(21,22) is bonded in a single-bond geometry to one C(15) atom. Linkers: 1 [CH]1N=C[N]N1CCCCN1[CH]N=C[N]1 ,7 [CH]1N=C[N]N1CCCCn1cncn1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 8.33 A, density 0.83 g/cm3, surface area 5363.12 m2/g, accessible volume 0.71 cm3/g