CdC9H5(NO)4CH crystallizes in the cubic Im-3m space group. The structure consists of forty-eight 02329_fluka molecules inside a CdC9H5(NO)4 framework. In the CdC9H5(NO)4 framework, Cd(1) is bonded in a 8-coordinate geometry to two equivalent N(1), two equivalent N(2), two equivalent O(1), and two equivalent O(2) atoms. Both Cd(1)-N(1) bond lengths are 2.42 Å. Both Cd(1)-N(2) bond lengths are 2.42 Å. Both Cd(1)-O(1) bond lengths are 2.42 Å. Both Cd(1)-O(2) bond lengths are 2.40 Å. There are seven inequivalent C sites. In the first C site, C(5) is bonded in a single-bond geometry to two equivalent C(1) and one H(3) atom. Both C(5)-C(1) bond lengths are 1.37 Å. The C(5)-H(3) bond length is 0.95 Å. In the second C site, C(1) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the third C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2) atom. The C(2)-N(2) bond length is 1.30 Å. The C(2)-H(2) bond length is 0.95 Å. In the fourth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4) and two equivalent O(1) atoms. The C(3)-C(4) bond length is 1.50 Å. Both C(3)-O(1) bond lengths are 1.24 Å. In the fifth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3) and two equivalent N(1) atoms. Both C(4)-N(1) bond lengths are 1.33 Å. In the sixth C site, C(6) is bonded in a bent 120 degrees geometry to one C(7) and two equivalent O(2) atoms. The C(6)-C(7) bond length is 1.49 Å. Both C(6)-O(2) bond lengths are 1.25 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6) and two equivalent N(2) atoms. Both C(7)-N(2) bond lengths are 1.33 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(2), and one C(7) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(6) atom. Linkers: 48 [O]C(=O)c1ncccn1. Metal clusters: 24 [Cd]. The MOF has largest included sphere 17.26 A, density 1.05 g/cm3, surface area 3292.89 m2/g, accessible volume 0.61 cm3/g