ZnC10NH6O4(C4H3)3(C2H)3(CH)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, four hexamethylbenzene molecules, twenty-four isobutylene molecules, and four ZnC10NH6O4 clusters. In each ZnC10NH6O4 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.02 Å. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.03 Å. The Zn(1)-O(3) bond length is 2.03 Å. The Zn(1)-O(4) bond length is 2.02 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(7) is bonded in a single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.95 Å. In the fifth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(8) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(8) bond length is 0.95 Å. In the sixth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-C(16) bond length is 1.49 Å. In the seventh C site, C(14) is bonded in a single-bond geometry to one C(13) and one H(9) atom. The C(14)-H(9) bond length is 0.95 Å. In the eighth C site, C(16) is bonded in a bent 120 degrees geometry to one C(13), one O(3), and one O(4) atom. The C(16)-O(3) bond length is 1.25 Å. The C(16)-O(4) bond length is 1.25 Å. In the ninth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(11) atom. The C(17)-N(1) bond length is 1.33 Å. The C(17)-H(11) bond length is 0.95 Å. In the tenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(14) atom. The C(21)-N(1) bond length is 1.31 Å. The C(21)-H(14) bond length is 0.95 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(17), and one C(21) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(16) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(16) atom. Linkers: 4 C(=C/c1c2ccccc2c(/C=C/c2ccncc2)c2ccccc12)\c1ccncc1 ,8 [O]C(=O)c1ccc(/C=C/c2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 6.22 A, density 1.07 g/cm3, surface area 4917.04 m2/g, accessible volume 0.46 cm3/g