Zn3C12P4H13(NO7)2(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a Zn3C12P4H13(NO7)2 framework. In the Zn3C12P4H13(NO7)2 framework, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(12), one O(4), and one O(8) atom to form ZnO4 tetrahedra that share  a cornercorner with one P(1)CO3 tetrahedra,  a cornercorner with one P(2)CO3 tetrahedra,  a cornercorner with one P(3)CO3 tetrahedra, and  a cornercorner with one P(4)CO3 tetrahedra. The Zn(1)-O(1) bond length is 1.94 Å. The Zn(1)-O(12) bond length is 1.94 Å. The Zn(1)-O(4) bond length is 1.93 Å. The Zn(1)-O(8) bond length is 1.98 Å. In the second Zn site, Zn(2) is bonded to one N(2), one O(10), one O(13), and one O(9) atom to form ZnNO3 tetrahedra that share  a cornercorner with one P(4)CO3 tetrahedra and corners with two equivalent P(3)CO3 tetrahedra. The Zn(2)-N(2) bond length is 2.02 Å. The Zn(2)-O(10) bond length is 1.93 Å. The Zn(2)-O(13) bond length is 1.95 Å. The Zn(2)-O(9) bond length is 2.00 Å. In the third Zn site, Zn(3) is bonded to one O(11), one O(2), one O(3), and one O(5) atom to form ZnO4 tetrahedra that share  a cornercorner with one P(2)CO3 tetrahedra,  a cornercorner with one P(4)CO3 tetrahedra, and corners with two equivalent P(1)CO3 tetrahedra. The Zn(3)-O(11) bond length is 1.95 Å. The Zn(3)-O(2) bond length is 1.93 Å. The Zn(3)-O(3) bond length is 2.00 Å. The Zn(3)-O(5) bond length is 1.92 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a 4-coordinate geometry to one C(2), one P(1), one P(2), and one O(7) atom. The C(1)-C(2) bond length is 1.55 Å. The C(1)-P(1) bond length is 1.85 Å. The C(1)-P(2) bond length is 1.85 Å. The C(1)-O(7) bond length is 1.43 Å. In the second C site, C(2) is bonded in a water-like geometry to one C(1); one C(3); and two equivalent H(4,5) atoms. The C(2)-C(3) bond length is 1.50 Å. Both C(2)-H(4,5) bond lengths are 0.97 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(7) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(7) bond length is 1.38 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(6) atom. The C(4)-H(6) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(6)-N(1) bond length is 1.33 Å. The C(6)-H(8) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(9) atom. The C(7)-N(1) bond length is 1.33 Å. The C(7)-H(9) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a distorted tetrahedral geometry to one C(9), one P(3), one P(4), and one O(14) atom. The C(8)-C(9) bond length is 1.55 Å. The C(8)-P(3) bond length is 1.85 Å. The C(8)-P(4) bond length is 1.85 Å. The C(8)-O(14) bond length is 1.45 Å. In the eighth C site, C(9) is bonded in a water-like geometry to one C(10); one C(8); and two equivalent H(10,11) atoms. The C(9)-C(10) bond length is 1.52 Å. Both C(9)-H(10,11) bond lengths are 0.97 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(9) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(14) bond length is 1.38 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(12) atom. The C(11)-H(12) bond length is 0.93 Å. In the eleventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(14) atom. The C(13)-N(2) bond length is 1.33 Å. The C(13)-H(14) bond length is 0.93 Å. In the twelfth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(10), one N(2), and one H(15) atom. The C(14)-N(2) bond length is 1.35 Å. The C(14)-H(15) bond length is 0.93 Å. There are four inequivalent P sites. In the first P site, P(1) is bonded to one C(1), one O(1), one O(2), and one O(3) atom to form PCO3 tetrahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one P(2)CO3 tetrahedra, and corners with two equivalent Zn(3)O4 tetrahedra. The P(1)-O(1) bond length is 1.52 Å. The P(1)-O(2) bond length is 1.51 Å. The P(1)-O(3) bond length is 1.54 Å. In the second P site, P(2) is bonded to one C(1), one O(4), one O(5), and one O(6) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra, and  a cornercorner with one P(1)CO3 tetrahedra. The P(2)-O(4) bond length is 1.53 Å. The P(2)-O(5) bond length is 1.53 Å. The P(2)-O(6) bond length is 1.51 Å. In the third P site, P(3) is bonded to one C(8), one O(10), one O(8), and one O(9) atom to form PCO3 tetrahedra that share  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one P(4)CO3 tetrahedra, and corners with two equivalent Zn(2)NO3 tetrahedra. The P(3)-O(10) bond length is 1.52 Å. The P(3)-O(8) bond length is 1.52 Å. The P(3)-O(9) bond length is 1.53 Å. In the fourth P site, P(4) is bonded to one C(8), one O(11), one O(12), and one O(13) atom to form PCO3 tetrahedra that share  a cornercorner with one Zn(2)NO3 tetrahedra,  a cornercorner with one Zn(1)O4 tetrahedra,  a cornercorner with one Zn(3)O4 tetrahedra, and  a cornercorner with one P(3)CO3 tetrahedra. The P(4)-O(11) bond length is 1.53 Å. The P(4)-O(12) bond length is 1.52 Å. The P(4)-O(13) bond length is 1.52 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(6), one C(7), and one H(3) atom. The N(1)-H(3) bond length is 0.86 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(13), and one C(14) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(7) atom. The H(1)-O(7) bond length is 0.82 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(14) atom. The H(2)-O(14) bond length is 0.82 Å. In the third H site, H(3) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(4,5) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(10,11) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(14) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(3) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(2) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one P(2) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one C(1) and one H(1) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(3) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(2) and one P(3) atom. In the eleventh O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(2) and one P(4) atom. In the twelfth O site, O(14) is bonded in a water-like geometry to one C(8) and one H(2) atom. In the thirteenth O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(4) atom. In the fourteenth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one P(4) atom. Linkers: 4 [O]P([O])(=O)C(O)(CC1=CC=CN[CH]1)P([O])([O])=O ,4 [O]P([O])(=O)C(O)(Cc1cccnc1)P([O])([O])=O. Metal clusters: 12 [Zn]. The MOF has largest included sphere 4.47 A, density 1.80 g/cm3, surface area 3250.30 m2/g, accessible volume 0.24 cm3/g