Cu11H72(C4N)30(Cu2C11N6H10)2(CuH8(C2N)4)2 is Indium-like structured and crystallizes in the monoclinic C2 space group. The structure is zero-dimensional and consists of four Cu11H72(C4N)30 clusters, eight Cu2C11N6H10 clusters, and eight CuH8(C2N)4 clusters. In each Cu11H72(C4N)30 cluster, there are six inequivalent Cu sites. In the first Cu site, Cu(1,9) is bonded in a distorted trigonal planar geometry to one N(10,36); one N(2,28); and one N(6,32) atom. The Cu(1,9)-N(10,36) bond length is 1.95 Å. The Cu(1,9)-N(2,28) bond length is 1.95 Å. The Cu(1,9)-N(6,32) bond length is 2.07 Å. In the second Cu site, Cu(3,11) is bonded in a linear geometry to one N(15,41) and one N(3,29) atom. The Cu(3,11)-N(15,41) bond length is 1.86 Å. The Cu(3,11)-N(3,29) bond length is 1.86 Å. In the third Cu site, Cu(4,12) is bonded in a linear geometry to one N(19,45) and one N(7,33) atom. The Cu(4,12)-N(19,45) bond length is 1.86 Å. The Cu(4,12)-N(7,33) bond length is 1.86 Å. In the fourth Cu site, Cu(5,13) is bonded in a linear geometry to one N(11,37) and one N(23,49) atom. The Cu(5,13)-N(11,37) bond length is 1.87 Å. The Cu(5,13)-N(23,49) bond length is 1.87 Å. In the fifth Cu site, Cu(2,10) is bonded in a trigonal planar geometry to one N(14,40); one N(18,44); and one N(22,48) atom. The Cu(2,10)-N(14,40) bond length is 1.94 Å. The Cu(2,10)-N(18,44) bond length is 1.96 Å. The Cu(2,10)-N(22,48) bond length is 2.06 Å. In the sixth Cu site, Cu(17,18) is bonded in a tetrahedral geometry to two equivalent N(1,27) and two equivalent N(16,42) atoms. Both Cu(17,18)-N(1,27) bond lengths are 2.05 Å. Both Cu(17,18)-N(16,42) bond lengths are 2.07 Å. There are sixty inequivalent C sites. In the first C site, C(14,94) is bonded in a distorted single-bond geometry to one C(18,98) and one H(10,64) atom. The C(14,94)-C(18,98) bond length is 1.38 Å. The C(14,94)-H(10,64) bond length is 0.93 Å. In the second C site, C(18,98) is bonded in a trigonal planar geometry to one C(14,94); one C(17,97); and one C(19,99) atom. The C(18,98)-C(17,97) bond length is 1.39 Å. The C(18,98)-C(19,99) bond length is 1.45 Å. In the third C site, C(19,99) is bonded in a distorted single-bond geometry to one C(18,98); one C(20,100); and one N(6,32) atom. The C(19,99)-C(20,100) bond length is 1.37 Å. The C(19,99)-N(6,32) bond length is 1.35 Å. In the fourth C site, C(20,100) is bonded in a distorted single-bond geometry to one C(19,99); one C(21,101); and one H(14,68) atom. The C(20,100)-C(21,101) bond length is 1.37 Å. The C(20,100)-H(14,68) bond length is 0.93 Å. In the fifth C site, C(21,101) is bonded in a distorted single-bond geometry to one C(20,100); one C(22,102); and one N(7,33) atom. The C(21,101)-C(22,102) bond length is 1.47 Å. The C(21,101)-N(7,33) bond length is 1.34 Å. In the sixth C site, C(17,97) is bonded in a single-bond geometry to one C(18,98) and one H(13,67) atom. The C(17,97)-H(13,67) bond length is 0.93 Å. In the seventh C site, C(22,102) is bonded in a trigonal planar geometry to one C(21,101); one C(23,103); and one C(26,106) atom. The C(22,102)-C(23,103) bond length is 1.31 Å. The C(22,102)-C(26,106) bond length is 1.31 Å. In the eighth C site, C(23,103) is bonded in a distorted single-bond geometry to one C(22,102) and one H(15,69) atom. The C(23,103)-H(15,69) bond length is 0.93 Å. In the ninth C site, C(26,106) is bonded in a distorted single-bond geometry to one C(22,102) and one H(18,72) atom. The C(26,106)-H(18,72) bond length is 0.93 Å. In the tenth C site, C(27,107) is bonded in a distorted single-bond geometry to one C(31,111) and one H(19,73) atom. The C(27,107)-C(31,111) bond length is 1.37 Å. The C(27,107)-H(19,73) bond length is 0.93 Å. In the eleventh C site, C(30,110) is bonded in a distorted single-bond geometry to one C(31,111) and one H(22,76) atom. The C(30,110)-C(31,111) bond length is 1.39 Å. The C(30,110)-H(22,76) bond length is 0.93 Å. In the twelfth C site, C(31,111) is bonded in a trigonal planar geometry to one C(27,107); one C(30,110); and one C(32,112) atom. The C(31,111)-C(32,112) bond length is 1.45 Å. In the thirteenth C site, C(32,112) is bonded in a distorted single-bond geometry to one C(31,111); one C(33,113); and one N(10,36) atom. The C(32,112)-C(33,113) bond length is 1.38 Å. The C(32,112)-N(10,36) bond length is 1.35 Å. In the fourteenth C site, C(33,113) is bonded in a distorted single-bond geometry to one C(32,112); one C(34,114); and one H(23,77) atom. The C(33,113)-C(34,114) bond length is 1.39 Å. The C(33,113)-H(23,77) bond length is 0.93 Å. In the fifteenth C site, C(34,114) is bonded in a distorted single-bond geometry to one C(33,113); one C(35,115); and one N(11,37) atom. The C(34,114)-C(35,115) bond length is 1.49 Å. The C(34,114)-N(11,37) bond length is 1.34 Å. In the sixteenth C site, C(35,115) is bonded in a trigonal planar geometry to one C(34,114); one C(36,116); and one C(39,119) atom. The C(35,115)-C(36,116) bond length is 1.37 Å. The C(35,115)-C(39,119) bond length is 1.37 Å. In the seventeenth C site, C(36,116) is bonded in a distorted single-bond geometry to one C(35,115) and one H(24,78) atom. The C(36,116)-H(24,78) bond length is 0.93 Å. In the eighteenth C site, C(13,93) is bonded in a distorted single-bond geometry to one C(12,92); one C(9,89); and one H(9,63) atom. The C(13,93)-C(12,92) bond length is 1.42 Å. The C(13,93)-C(9,89) bond length is 1.31 Å. The C(13,93)-H(9,63) bond length is 0.93 Å. In the nineteenth C site, C(39,119) is bonded in a distorted single-bond geometry to one C(35,115) and one H(27,81) atom. The C(39,119)-H(27,81) bond length is 0.93 Å. In the twentieth C site, C(40,120) is bonded in a distorted single-bond geometry to one C(44,124) and one H(28,82) atom. The C(40,120)-C(44,124) bond length is 1.39 Å. The C(40,120)-H(28,82) bond length is 0.93 Å. In the twenty-first C site, C(43,123) is bonded in a distorted single-bond geometry to one C(44,124) and one H(31,85) atom. The C(43,123)-C(44,124) bond length is 1.39 Å. The C(43,123)-H(31,85) bond length is 0.93 Å. In the twenty-second C site, C(44,124) is bonded in a trigonal planar geometry to one C(40,120); one C(43,123); and one C(45,125) atom. The C(44,124)-C(45,125) bond length is 1.47 Å. In the twenty-third C site, C(45,125) is bonded in a distorted trigonal planar geometry to one C(44,124); one C(46,126); and one N(14,40) atom. The C(45,125)-C(46,126) bond length is 1.39 Å. The C(45,125)-N(14,40) bond length is 1.35 Å. In the twenty-fourth C site, C(46,126) is bonded in a distorted single-bond geometry to one C(45,125); one C(47,127); and one H(32,86) atom. The C(46,126)-C(47,127) bond length is 1.38 Å. The C(46,126)-H(32,86) bond length is 0.93 Å. In the twenty-fifth C site, C(47,127) is bonded in a distorted trigonal planar geometry to one C(46,126); one C(48,128); and one N(15,41) atom. The C(47,127)-C(48,128) bond length is 1.47 Å. The C(47,127)-N(15,41) bond length is 1.36 Å. In the twenty-sixth C site, C(48,128) is bonded in a trigonal planar geometry to one C(47,127); one C(49,129); and one C(52,132) atom. The C(48,128)-C(49,129) bond length is 1.40 Å. The C(48,128)-C(52,132) bond length is 1.36 Å. In the twenty-seventh C site, C(50,130) is bonded in a distorted bent 120 degrees geometry to one N(16,42) and one H(34,88) atom. The C(50,130)-N(16,42) bond length is 1.32 Å. The C(50,130)-H(34,88) bond length is 0.93 Å. In the twenty-eighth C site, C(51,131) is bonded in a distorted bent 120 degrees geometry to one N(16,42) and one H(35,89) atom. The C(51,131)-N(16,42) bond length is 1.35 Å. The C(51,131)-H(35,89) bond length is 0.93 Å. In the twenty-ninth C site, C(49,129) is bonded in a distorted single-bond geometry to one C(48,128) and one H(33,87) atom. The C(49,129)-H(33,87) bond length is 0.93 Å. In the thirtieth C site, C(53,133) is bonded in a distorted single-bond geometry to one C(57,137) and one H(37,91) atom. The C(53,133)-C(57,137) bond length is 1.36 Å. The C(53,133)-H(37,91) bond length is 0.93 Å. In the thirty-first C site, C(52,132) is bonded in a distorted single-bond geometry to one C(48,128) and one H(36,90) atom. The C(52,132)-H(36,90) bond length is 0.93 Å. In the thirty-second C site, C(56,136) is bonded in a distorted single-bond geometry to one C(57,137) and one H(40,94) atom. The C(56,136)-C(57,137) bond length is 1.40 Å. The C(56,136)-H(40,94) bond length is 0.93 Å. In the thirty-third C site, C(57,137) is bonded in a trigonal planar geometry to one C(53,133); one C(56,136); and one C(58,138) atom. The C(57,137)-C(58,138) bond length is 1.47 Å. In the thirty-fourth C site, C(58,138) is bonded in a distorted single-bond geometry to one C(57,137); one C(59,139); and one N(18,44) atom. The C(58,138)-C(59,139) bond length is 1.39 Å. The C(58,138)-N(18,44) bond length is 1.34 Å. In the thirty-fifth C site, C(59,139) is bonded in a distorted single-bond geometry to one C(58,138); one C(60,140); and one H(41,95) atom. The C(59,139)-C(60,140) bond length is 1.39 Å. The C(59,139)-H(41,95) bond length is 0.93 Å. In the thirty-sixth C site, C(60,140) is bonded in a distorted single-bond geometry to one C(59,139); one C(61,141); and one N(19,45) atom. The C(60,140)-C(61,141) bond length is 1.46 Å. The C(60,140)-N(19,45) bond length is 1.37 Å. In the thirty-seventh C site, C(61,141) is bonded in a trigonal planar geometry to one C(60,140); one C(62,142); and one C(65,145) atom. The C(61,141)-C(62,142) bond length is 1.36 Å. The C(61,141)-C(65,145) bond length is 1.37 Å. In the thirty-eighth C site, C(62,142) is bonded in a distorted single-bond geometry to one C(61,141) and one H(42,96) atom. The C(62,142)-H(42,96) bond length is 0.93 Å. In the thirty-ninth C site, C(65,145) is bonded in a single-bond geometry to one C(61,141) and one H(45,99) atom. The C(65,145)-H(45,99) bond length is 0.93 Å. In the fortieth C site, C(66,146) is bonded in a single-bond geometry to one C(70,150) and one H(46,100) atom. The C(66,146)-C(70,150) bond length is 1.37 Å. The C(66,146)-H(46,100) bond length is 0.93 Å. In the forty-first C site, C(69,149) is bonded in a distorted single-bond geometry to one C(70,150) and one H(49,103) atom. The C(69,149)-C(70,150) bond length is 1.36 Å. The C(69,149)-H(49,103) bond length is 0.93 Å. In the forty-second C site, C(70,150) is bonded in a trigonal planar geometry to one C(66,146); one C(69,149); and one C(71,151) atom. The C(70,150)-C(71,151) bond length is 1.48 Å. In the forty-third C site, C(72,152) is bonded in a distorted single-bond geometry to one C(71,151); one C(73,153); and one H(50,104) atom. The C(72,152)-C(71,151) bond length is 1.39 Å. The C(72,152)-C(73,153) bond length is 1.38 Å. The C(72,152)-H(50,104) bond length is 0.93 Å. In the forty-fourth C site, C(73,153) is bonded in a distorted single-bond geometry to one C(72,152); one C(74,154); and one N(23,49) atom. The C(73,153)-C(74,154) bond length is 1.47 Å. The C(73,153)-N(23,49) bond length is 1.34 Å. In the forty-fifth C site, C(74,154) is bonded in a trigonal planar geometry to one C(73,153); one C(75,155); and one C(78,158) atom. The C(74,154)-C(75,155) bond length is 1.40 Å. The C(74,154)-C(78,158) bond length is 1.38 Å. In the forty-sixth C site, C(75,155) is bonded in a distorted single-bond geometry to one C(74,154) and one H(51,105) atom. The C(75,155)-H(51,105) bond length is 0.93 Å. In the forty-seventh C site, C(71,151) is bonded in a distorted single-bond geometry to one C(70,150); one C(72,152); and one N(22,48) atom. The C(71,151)-N(22,48) bond length is 1.35 Å. In the forty-eighth C site, C(78,158) is bonded in a distorted single-bond geometry to one C(74,154) and one H(54,108) atom. The C(78,158)-H(54,108) bond length is 0.93 Å. In the forty-ninth C site, C(1,81) is bonded in a distorted single-bond geometry to one C(5,85) and one H(1,55) atom. The C(1,81)-C(5,85) bond length is 1.37 Å. The C(1,81)-H(1,55) bond length is 0.93 Å. In the fiftieth C site, C(2,82) is bonded in a distorted bent 120 degrees geometry to one N(1,27) and one H(2,29,56,83) atom. The C(2,82)-N(1,27) bond length is 1.34 Å. The C(2,82)-H(2,29,56,83) bond length is 0.93 Å. In the fifty-first C site, C(3,83) is bonded in a 3-coordinate geometry to one C(4,84); one N(1,27); and one H(3,57) atom. The C(3,83)-C(4,84) bond length is 1.38 Å. The C(3,83)-N(1,27) bond length is 1.33 Å. The C(3,83)-H(3,57) bond length is 0.93 Å. In the fifty-second C site, C(4,84) is bonded in a single-bond geometry to one C(3,83); one C(5,85); and one H(4,58) atom. The C(4,84)-C(5,85) bond length is 1.38 Å. The C(4,84)-H(4,58) bond length is 0.93 Å. In the fifty-third C site, C(5,85) is bonded in a trigonal planar geometry to one C(1,81); one C(4,84); and one C(6,86) atom. The C(5,85)-C(6,86) bond length is 1.48 Å. In the fifty-fourth C site, C(6,86) is bonded in a distorted trigonal planar geometry to one C(5,85); one C(7,87); and one N(2,28) atom. The C(6,86)-C(7,87) bond length is 1.39 Å. The C(6,86)-N(2,28) bond length is 1.36 Å. In the fifty-fifth C site, C(7,87) is bonded in a distorted single-bond geometry to one C(6,86); one C(8,88); and one H(5,59) atom. The C(7,87)-C(8,88) bond length is 1.38 Å. The C(7,87)-H(5,59) bond length is 0.93 Å. In the fifty-sixth C site, C(8,88) is bonded in a distorted trigonal planar geometry to one C(7,87); one C(9,89); and one N(3,29) atom. The C(8,88)-C(9,89) bond length is 1.46 Å. The C(8,88)-N(3,29) bond length is 1.35 Å. In the fifty-seventh C site, C(9,89) is bonded in a trigonal planar geometry to one C(10,90); one C(13,93); and one C(8,88) atom. The C(9,89)-C(10,90) bond length is 1.38 Å. In the fifty-eighth C site, C(10,90) is bonded in a single-bond geometry to one C(11,91); one C(9,89); and one H(6,60) atom. The C(10,90)-C(11,91) bond length is 1.36 Å. The C(10,90)-H(6,60) bond length is 0.93 Å. In the fifty-ninth C site, C(11,91) is bonded in a distorted trigonal planar geometry to one C(10,90); one N(4,30); and one H(7,61) atom. The C(11,91)-N(4,30) bond length is 1.35 Å. The C(11,91)-H(7,61) bond length is 0.93 Å. In the sixtieth C site, C(12,92) is bonded in a 3-coordinate geometry to one C(13,93); one N(4,30); and one H(8,62) atom. The C(12,92)-N(4,30) bond length is 1.30 Å. The C(12,92)-H(8,62) bond length is 0.93 Å. There are fifteen inequivalent N sites. In the first N site, N(1,27) is bonded in a trigonal planar geometry to one Cu(17,18); one C(2,82); and one C(3,83) atom. In the second N site, N(2,28) is bonded in a 3-coordinate geometry to one Cu(1,9); one C(6,86); and one N(3,29) atom. The N(2,28)-N(3,29) bond length is 1.37 Å. In the third N site, N(3,29) is bonded in a distorted trigonal planar geometry to one Cu(3,11); one C(8,88); and one N(2,28) atom. In the fourth N site, N(4,30) is bonded in a bent 120 degrees geometry to one C(11,91) and one C(12,92) atom. In the fifth N site, N(6,32) is bonded in a 3-coordinate geometry to one Cu(1,9); one C(19,99); and one N(7,33) atom. The N(6,32)-N(7,33) bond length is 1.37 Å. In the sixth N site, N(7,33) is bonded in a distorted trigonal planar geometry to one Cu(4,12); one C(21,101); and one N(6,32) atom. In the seventh N site, N(10,36) is bonded in a 3-coordinate geometry to one Cu(1,9); one C(32,112); and one N(11,37) atom. The N(10,36)-N(11,37) bond length is 1.37 Å. In the eighth N site, N(11,37) is bonded in a distorted trigonal planar geometry to one Cu(5,13); one C(34,114); and one N(10,36) atom. In the ninth N site, N(14,40) is bonded in a 3-coordinate geometry to one Cu(2,10); one C(45,125); and one N(15,41) atom. The N(14,40)-N(15,41) bond length is 1.37 Å. In the tenth N site, N(15,41) is bonded in a 3-coordinate geometry to one Cu(3,11); one C(47,127); and one N(14,40) atom. In the eleventh N site, N(16,42) is bonded in a trigonal planar geometry to one Cu(17,18); one C(50,130); and one C(51,131) atom. In the twelfth N site, N(18,44) is bonded in a 3-coordinate geometry to one Cu(2,10); one C(58,138); and one N(19,45) atom. The N(18,44)-N(19,45) bond length is 1.38 Å. In the thirteenth N site, N(19,45) is bonded in a distorted trigonal planar geometry to one Cu(4,12); one C(60,140); and one N(18,44) atom. In the fourteenth N site, N(22,48) is bonded in a 3-coordinate geometry to one Cu(2,10); one C(71,151); and one N(23,49) atom. The N(22,48)-N(23,49) bond length is 1.37 Å. In the fifteenth N site, N(23,49) is bonded in a distorted trigonal planar geometry to one Cu(5,13); one C(73,153); and one N(22,48) atom. There are thirty-six inequivalent H sites. In the first H site, H(46,100) is bonded in a single-bond geometry to one C(66,146) atom. In the second H site, H(1,55) is bonded in a single-bond geometry to one C(1,81) atom. In the third H site, H(2,29,56,83) is bonded in a single-bond geometry to one C(2,82) atom. In the fourth H site, H(3,57) is bonded in a single-bond geometry to one C(3,83) atom. In the fifth H site, H(4,58) is bonded in a single-bond geometry to one C(4,84) atom. In the sixth H site, H(5,59) is bonded in a single-bond geometry to one C(7,87) atom. In the seventh H site, H(6,60) is bonded in a single-bond geometry to one C(10,90) atom. In the eighth H site, H(7,61) is bonded in a single-bond geometry to one C(11,91) atom. In the ninth H site, H(8,62) is bonded in a single-bond geometry to one C(12,92) atom. In the tenth H site, H(9,63) is bonded in a single-bond geometry to one C(13,93) atom. In the eleventh H site, H(10,64) is bonded in a single-bond geometry to one C(14,94) atom. In the twelfth H site, H(49,103) is bonded in a single-bond geometry to one C(69,149) atom. In the thirteenth H site, H(13,67) is bonded in a single-bond geometry to one C(17,97) atom. In the fourteenth H site, H(14,68) is bonded in a single-bond geometry to one C(20,100) atom. In the fifteenth H site, H(15,69) is bonded in a single-bond geometry to one C(23,103) atom. In the sixteenth H site, H(18,72) is bonded in a single-bond geometry to one C(26,106) atom. In the seventeenth H site, H(19,73) is bonded in a single-bond geometry to one C(27,107) atom. In the eighteenth H site, H(22,76) is bonded in a single-bond geometry to one C(30,110) atom. In the nineteenth H site, H(23,77) is bonded in a single-bond geometry to one C(33,113) atom. In the twentieth H site, H(24,78) is bonded in a single-bond geometry to one C(36,116) atom. In the twenty-first H site, H(27,81) is bonded in a single-bond geometry to one C(39,119) atom. In the twenty-second H site, H(28,82) is bonded in a single-bond geometry to one C(40,120) atom. In the twenty-third H site, H(31,85) is bonded in a single-bond geometry to one C(43,123) atom. In the twenty-fourth H site, H(32,86) is bonded in a single-bond geometry to one C(46,126) atom. In the twenty-fifth H site, H(33,87) is bonded in a single-bond geometry to one C(49,129) atom. In the twenty-sixth H site, H(34,88) is bonded in a single-bond geometry to one C(50,130) atom. In the twenty-seventh H site, H(35,89) is bonded in a single-bond geometry to one C(51,131) atom. In the twenty-eighth H site, H(36,90) is bonded in a single-bond geometry to one C(52,132) atom. In the twenty-ninth H site, H(37,91) is bonded in a single-bond geometry to one C(53,133) atom. In the thirtieth H site, H(40,94) is bonded in a single-bond geometry to one C(56,136) atom. In the thirty-first H site, H(41,95) is bonded in a single-bond geometry to one C(59,139) atom. In the thirty-second H site, H(42,96) is bonded in a single-bond geometry to one C(62,142) atom. In the thirty-third H site, H(45,99) is bonded in a single-bond geometry to one C(65,145) atom. In the thirty-fourth H site, H(50,104) is bonded in a single-bond geometry to one C(72,152) atom. In the thirty-fifth H site, H(51,105) is bonded in a single-bond geometry to one C(75,155) atom. In the thirty-sixth H site, H(54,108) is bonded in a single-bond geometry to one C(78,158) atom. In each Cu2C11N6H10 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(6) is bonded in a tetrahedral geometry to one C(79), one N(20), one N(5), and one N(9) atom. The Cu(6)-C(79) bond length is 1.93 Å. The Cu(6)-N(20) bond length is 2.14 Å. The Cu(6)-N(5) bond length is 2.13 Å. The Cu(6)-N(9) bond length is 2.03 Å. In the second Cu site, Cu(16) is bonded in a distorted T-shaped geometry to one N(25), one N(39), and one N(8) atom. The Cu(16)-N(25) bond length is 1.89 Å. The Cu(16)-N(39) bond length is 1.93 Å. The Cu(16)-N(8) bond length is 2.19 Å. There are eleven inequivalent C sites. In the first C site, C(15,95) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(11,65) atom. The C(15,95)-N(5) bond length is 1.31 Å. The C(15,95)-H(11,65) bond length is 0.93 Å. In the second C site, C(16,96) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(12,66) atom. The C(16,96)-N(5) bond length is 1.34 Å. The C(16,96)-H(12,66) bond length is 0.93 Å. In the third C site, C(24,104) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(16,70) atom. The C(24,104)-N(8) bond length is 1.21 Å. The C(24,104)-H(16,70) bond length is 0.93 Å. In the fourth C site, C(25,105) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(17,71) atom. The C(25,105)-N(8) bond length is 1.27 Å. The C(25,105)-H(17,71) bond length is 0.93 Å. In the fifth C site, C(28,108) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(20,74) atom. The C(28,108)-N(9) bond length is 1.33 Å. The C(28,108)-H(20,74) bond length is 0.93 Å. In the sixth C site, C(29,109) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(21,75) atom. The C(29,109)-N(9) bond length is 1.35 Å. The C(29,109)-H(21,75) bond length is 0.93 Å. In the seventh C site, C(41,121) is bonded in a distorted bent 120 degrees geometry to one N(13) and one H(2,29,56,83) atom. The C(41,121)-N(13) bond length is 1.34 Å. The C(41,121)-H(2,29,56,83) bond length is 0.93 Å. In the eighth C site, C(42,122) is bonded in a distorted bent 120 degrees geometry to one N(13) and one H(30,84) atom. The C(42,122)-N(13) bond length is 1.32 Å. The C(42,122)-H(30,84) bond length is 0.93 Å. In the ninth C site, C(63,143) is bonded in a distorted bent 120 degrees geometry to one N(20) and one H(43,97) atom. The C(63,143)-N(20) bond length is 1.32 Å. The C(63,143)-H(43,97) bond length is 0.93 Å. In the tenth C site, C(64,144) is bonded in a distorted bent 120 degrees geometry to one N(20) and one H(44,98) atom. The C(64,144)-N(20) bond length is 1.31 Å. The C(64,144)-H(44,98) bond length is 0.93 Å. In the eleventh C site, C(79) is bonded in a linear geometry to one Cu(6) and one N(25) atom. The C(79)-N(25) bond length is 1.14 Å. There are six inequivalent N sites. In the first N site, N(25) is bonded in a bent 150 degrees geometry to one Cu(16) and one C(79) atom. In the second N site, N(39) is bonded in a trigonal planar geometry to one Cu(16); one C(41,121); and one C(42,122) atom. The N(39)-C(41,121) bond length is 1.34 Å. The N(39)-C(42,122) bond length is 1.32 Å. In the third N site, N(5) is bonded in a trigonal planar geometry to one Cu(6); one C(15,95); and one C(16,96) atom. In the fourth N site, N(8) is bonded in a distorted trigonal planar geometry to one Cu(16); one C(24,104); and one C(25,105) atom. In the fifth N site, N(9) is bonded in a trigonal planar geometry to one Cu(6); one C(28,108); and one C(29,109) atom. In the sixth N site, N(20) is bonded in a trigonal planar geometry to one Cu(6); one C(63,143); and one C(64,144) atom. There are ten inequivalent H sites. In the first H site, H(2,29,56,83) is bonded in a single-bond geometry to one C(2,82) atom. In the second H site, H(11,65) is bonded in a single-bond geometry to one C(15,95) atom. In the third H site, H(12,66) is bonded in a single-bond geometry to one C(16,96) atom. In the fourth H site, H(16,70) is bonded in a single-bond geometry to one C(24,104) atom. In the fifth H site, H(17,71) is bonded in a single-bond geometry to one C(25,105) atom. In the sixth H site, H(20,74) is bonded in a single-bond geometry to one C(28,108) atom. In the seventh H site, H(21,75) is bonded in a single-bond geometry to one C(29,109) atom. In the eighth H site, H(30,84) is bonded in a single-bond geometry to one C(42,122) atom. In the ninth H site, H(43,97) is bonded in a single-bond geometry to one C(63,143) atom. In the tenth H site, H(44,98) is bonded in a single-bond geometry to one C(64,144) atom. In each CuH8(C2N)4 cluster, Cu(7,15) is bonded in a tetrahedral geometry to one N(12,38); one N(17,43); one N(21,47); and one N(24,50) atom. The Cu(7,15)-N(12,38) bond length is 2.01 Å. The Cu(7,15)-N(17,43) bond length is 2.00 Å. The Cu(7,15)-N(21,47) bond length is 2.16 Å. The Cu(7,15)-N(24,50) bond length is 2.18 Å. There are eight inequivalent C sites. In the first C site, C(37,117) is bonded in a distorted bent 120 degrees geometry to one N(12,38) and one H(25,79) atom. The C(37,117)-N(12,38) bond length is 1.32 Å. The C(37,117)-H(25,79) bond length is 0.93 Å. In the second C site, C(38,118) is bonded in a distorted bent 120 degrees geometry to one N(12,38) and one H(26,80) atom. The C(38,118)-N(12,38) bond length is 1.34 Å. The C(38,118)-H(26,80) bond length is 0.93 Å. In the third C site, C(54,134) is bonded in a distorted bent 120 degrees geometry to one N(17,43) and one H(38,92) atom. The C(54,134)-N(17,43) bond length is 1.31 Å. The C(54,134)-H(38,92) bond length is 0.93 Å. In the fourth C site, C(55,135) is bonded in a distorted bent 120 degrees geometry to one N(17,43) and one H(39,93) atom. The C(55,135)-N(17,43) bond length is 1.32 Å. The C(55,135)-H(39,93) bond length is 0.93 Å. In the fifth C site, C(67,147) is bonded in a distorted bent 120 degrees geometry to one N(21,47) and one H(47,101) atom. The C(67,147)-N(21,47) bond length is 1.34 Å. The C(67,147)-H(47,101) bond length is 0.93 Å. In the sixth C site, C(68,148) is bonded in a distorted bent 120 degrees geometry to one N(21,47) and one H(48,102) atom. The C(68,148)-N(21,47) bond length is 1.32 Å. The C(68,148)-H(48,102) bond length is 0.93 Å. In the seventh C site, C(76,156) is bonded in a distorted bent 120 degrees geometry to one N(24,50) and one H(52,106) atom. The C(76,156)-N(24,50) bond length is 1.33 Å. The C(76,156)-H(52,106) bond length is 0.93 Å. In the eighth C site, C(77,157) is bonded in a distorted bent 120 degrees geometry to one N(24,50) and one H(53,107) atom. The C(77,157)-N(24,50) bond length is 1.30 Å. The C(77,157)-H(53,107) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(21,47) is bonded in a trigonal planar geometry to one Cu(7,15); one C(67,147); and one C(68,148) atom. In the second N site, N(24,50) is bonded in a trigonal non-coplanar geometry to one Cu(7,15); one C(76,156); and one C(77,157) atom. In the third N site, N(12,38) is bonded in a trigonal planar geometry to one Cu(7,15); one C(37,117); and one C(38,118) atom. In the fourth N site, N(17,43) is bonded in a trigonal planar geometry to one Cu(7,15); one C(54,134); and one C(55,135) atom. There are eight inequivalent H sites. In the first H site, H(25,79) is bonded in a single-bond geometry to one C(37,117) atom. In the second H site, H(26,80) is bonded in a single-bond geometry to one C(38,118) atom. In the third H site, H(38,92) is bonded in a single-bond geometry to one C(54,134) atom. In the fourth H site, H(39,93) is bonded in a single-bond geometry to one C(55,135) atom. In the fifth H site, H(47,101) is bonded in a single-bond geometry to one C(67,147) atom. In the sixth H site, H(48,102) is bonded in a single-bond geometry to one C(68,148) atom. In the seventh H site, H(52,106) is bonded in a single-bond geometry to one C(76,156) atom. In the eighth H site, H(53,107) is bonded in a single-bond geometry to one C(77,157) atom. Linkers: 1 [C]/C=C(\C=[CH])C1=NN=C(C2=C[CH]N([Cu@](N3[CH]C=C(C4=CC(c5ccncc5)=N[N]4)C=C3)(N3[CH]C=C(C4=N[N]C(C([CH])=[CH])=C4)C=C3)N3[CH]C=C(C4=N[N]C(c5ccncc5)=C4)C=C3)C=C2)[CH]1 ,1 [CH]1C=C2C=CN1[Cu@@](N1[CH]C=C([C]3C=C(c4ccncc4)N=N3)C=C1)(N1[CH]C=C(C3=C[C](c4ccncc4)N=N3)C=C1)N1[CH]C=C(C=C1)C1=N[N]C(=C1)C1=C[CH]N(C=C1)[Cu@@](N1[CH]C=C([C]3C=C(c4ccncc4)N=N3)C=C1)(N1[CH]C=C(C3=C[C](c4ccncc4)N=N3)C=C1)N1[CH]C=C(C=C1)C1=C[C]2N=N1 ,1 [CH]1C=C2C=CN1[Cu@](N1[CH]C=C(C3=CC(c4ccncc4)=N[N]3)C=C1)(N1[CH]C=C(C3=N[N]C(c4ccncc4)=C3)C=C1)N1[CH]C=C(C=C1)C1=CC(=N[N]1)C1=C[CH]N(C=C1)[Cu@](N1[CH]C=C([C]3C=C(c4ccncc4)N=N3)C=C1)(N1[CH]C=C(C3=N[N]C(c4ccncc4)=C3)C=C1)N1[CH]C=C(C=C1)C1=C[C]2N=N1 ,1 [CH]1C(C2=C[CH]N([Cu](N3[CH]C=C(C4=NN=C(c5ccncc5)[CH]4)C=C3)(N3[CH]C=C(C4=N[N]C(c5ccncc5)=C4)C=C3)N3[CH]C=C(C4=N[N]C(c5ccncc5)=C4)C=C3)C=C2)=NN=C1c1ccncc1 ,1 [CH]1C=C([C]2C=C(c3ccncc3)N=N2)C=CN1[Cu](N1[CH]C=C(C2=CC(c3ccncc3)=N[N]2)C=C1)(N1[CH]C=C(C2=N[N]C(c3ccncc3)=C2)C=C1)N1[CH]C=C(C2=N[N]C(c3ccncc3)=C2)C=C1 ,1 [CH]=[C]C1=C[CH]N([Cu@@]2(N3[CH]C=C(C4=N[N]C(c5ccncc5)=C4)C=C3)N3[CH]C=C(C=C3)C3=C[C](N=N3)C3=C[CH]N(C=C3)[Cu@](N3[CH]C=C(C4=CC(c5ccncc5)=N[N]4)C=C3)(N3[CH]C=C(C4=N[N]C(c5ccncc5)=C4)C=C3)N3[CH]C=C(C=C3)C3=CC(=N[N]3)C3=C[CH]N2C=C3)C=C1 ,1 [CH]=[C]C1=C[CH]N([Cu@@]2(N3[CH]C=C(C4=C[C](c5ccncc5)N=N4)C=C3)N3[CH]C=C(C=C3)C3=CC(=N[N]3)C3=C[CH]N(C=C3)[Cu@](N3[CH]C=C(C4=NN=C(c5ccncc5)[CH]4)C=C3)(N3[CH]C=C(C4=N[N]C(c5ccncc5)=C4)C=C3)N3[CH]C=C(C=C3)C3=NN=C([CH]3)C3=C[CH]N2C=C3)C=C1 ,1 [CH]1C2=NN=C1C1=C[CH]N(C=C1)[Cu@](N1[CH]C=C([C]3C=C(c4ccncc4)N=N3)C=C1)(N1[CH]C=C(C3=N[N]C(c4ccncc4)=C3)C=C1)N1[CH]C=C(C=C1)C1=CC(=N[N]1)C1=C[CH]N(C=C1)[Cu](N1[CH]C=C(C3=NN=C(c4ccncc4)[CH]3)C=C1)(N1[CH]C=C(C3=NN=C(c4ccncc4)[CH]3)C=C1)N1[CH]C=C2C=C1 ,1 [C]1=NN=C(C2=C[CH]N([Cu@](N3[CH]C=C(C4=CC(c5ccncc5)=N[N]4)C=C3)(N3[CH]C=C(C4=C[C](c5ccncc5)N=N4)C=C3)N3[CH]C=C(C4=NN=C(c5ccncc5)[CH]4)C=C3)C=C2)[CH]1 ,1 [CH]1C(C2=C[CH]N([Cu](N3[CH]C=C(C4=CC(c5ccncc5)=N[N]4)C=C3)(N3[CH]C=C(C4=NN=C(c5ccncc5)[CH]4)C=C3)N3[CH]C=C(C4=N[N]C(c5ccncc5)=C4)C=C3)C=C2)=NN=C1c1ccncc1 ,1 [C]/C=C(\C=[CH])C1=C[C](C2=C[CH]N([Cu@](N3[CH]C=C(C4=CC(C([CH])=[CH])=N[N]4)C=C3)(N3[CH]C=C(C4=NN=C(c5ccncc5)[CH]4)C=C3)N3[CH]C=C(C4=N[N]C(c5ccncc5)=C4)C=C3)C=C2)N=N1 ,1 [CH]1C=C([C]2C=C(c3ccncc3)N=N2)C=CN1[Cu](N1[CH]C=C(C2=CC(c3ccncc3)=N[N]2)C=C1)(N1[CH]C=C(C2=CC(c3ccncc3)=N[N]2)C=C1)N1[CH]C=C(C2=C[C](c3ccncc3)N=N2)C=C1 ,1 [C]1=C[C](C2=C[CH]N([Cu@](N3[CH]C=C(C4=CC(c5ccncc5)=N[N]4)C=C3)(N3[CH]C=C(C4=C[C](c5ccncc5)N=N4)C=C3)N3[CH]C=C(C4=N[N]C(c5ccncc5)=C4)C=C3)C=C2)N=N1 ,4 C1=C(c2ccncc2)[N]N=C1c1ccncc1 ,1 [CH]1C(C2=C[CH]N([Cu@@]3(N4[CH]C=C(C5=CC(c6ccncc6)=N[N]5)C=C4)N4[CH]C=C(C=C4)[C]4C=C(N=N4)C4=C[CH]N(C=C4)[Cu@@](N4[CH]C=C([C]5C=C(c6ccncc6)N=N5)C=C4)(N4[CH]C=C(C5=N[N]C(c6ccncc6)=C5)C=C4)N4[CH]C=C(C=C4)C4=N[N]C(=C4)C4=C[CH]N3C=C4)C=C2)=NN=C1c1ccncc1 ,2 [CH]1C(c2ccncc2)=NN=C1c1ccncc1 ,2 C1=C(c2ccncc2)N=N[C]1c1ccncc1 ,1 [CH]1C(C2=C[CH]N([Cu](N3[CH]C=C(C4=CC(c5ccncc5)=N[N]4)C=C3)(N3[CH]C=C(C4=N[N]C(c5ccncc5)=C4)C=C3)N3[CH]C=C(C4=N[N]C(c5ccncc5)=C4)C=C3)C=C2)=NN=C1c1ccncc1 ,1 [CH]=[C]C1=C[CH]N([Cu@@]2(N3[CH]C=C(C4=NN=C(c5ccncc5)[CH]4)C=C3)N3[CH]C=C(C=C3)C3=CC(=N[N]3)C3=C[CH]N(C=C3)[Cu@@](N3[CH]C=C(C4=CC(c5ccncc5)=N[N]4)C=C3)(N3[CH]C=C(C4=N[N]C(c5ccncc5)=C4)C=C3)N3[CH]C=C(C=C3)[C]3C=C(N=N3)C3=C[CH]N2C=C3)C=C1 ,1 [C]1=N[N]C(C2=C[CH]N([Cu](N3[CH]C=C(C4=C[C](c5ccncc5)N=N4)C=C3)(N3[CH]C=C(C4=NN=C(c5ccncc5)[CH]4)C=C3)N3[CH]C=C(C4=NN=C(c5ccncc5)[CH]4)C=C3)C=C2)=C1 ,1 [CH]=[C]C1=C[CH]N([Cu@@]2(N3[CH]C=C(C4=NN=C(c5ccncc5)[CH]4)C=C3)N3[CH]C=C(C=C3)[C]3C=C(N=N3)C3=C[CH]N(C=C3)[Cu@@](N3[CH]C=C([C]4C=C(c5ccncc5)N=N4)C=C3)(N3[CH]C=C(C4=C[C](c5ccncc5)N=N4)C=C3)N3[CH]C=C(C=C3)C3=CC(=N[N]3)C3=C[CH]N2C=C3)C=C1 ,1 [C]/C=C(\C=[CH])C1=N[N]C(C2=C[CH]N([Cu@@](N3[CH]C=C([C]4C=C(c5ccncc5)N=N4)C=C3)(N3[CH]C=C(C4=C[C](C([CH])=[CH])N=N4)C=C3)N3[CH]C=C(C4=C[C](c5ccncc5)N=N4)C=C3)C=C2)=C1 ,1 [C]/C=C(\C=[CH])C1=N[N]C(C2=C[CH]N([Cu@](N3[CH]C=C([C]4C=C(c5ccncc5)N=N4)C=C3)(N3[CH]C=C(C4=C[C](C([CH])=[CH])N=N4)C=C3)N3[CH]C=C(C4=C[C](c5ccncc5)N=N4)C=C3)C=C2)=C1 ,1 [C]1=CC(C2=C[CH]N([Cu@](N3[CH]C=C([C]4C=C(c5ccncc5)N=N4)C=C3)(N3[CH]C=C(C4=C[C](c5ccncc5)N=N4)C=C3)N3[CH]C=C(C4=NN=C(c5ccncc5)[CH]4)C=C3)C=C2)=N[N]1. Metal clusters: 4 [N]1[N][Cu@@]23[N][N][Cu]4[N][N][Cu]45([N][N][Cu]1)[N][N][Cu@@]25[N][N]3 ,8 [Cu][C][N][Cu] ,4 [N]1[N][Cu@]23[N][N][Cu]4[N][N][Cu]45([N][N][Cu]1)[N][N][Cu@]25[N][N]3. The MOF has largest included sphere 4.24 A, density 1.56 g/cm3, surface area 4231.28 m2/g, accessible volume 0.26 cm3/g