CdH4(C2O)4CdC14NH10O4CdC10NH6O4CH2(CH)14(C2O)4 is Indium-derived structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of forty 02329_fluka molecules, four 02329_fluka molecules, sixteen dimethyl ether molecules, four isobutylene molecules, four CdC10NH6O4 clusters, four CdC14NH10O4 clusters, and four CdH4(C2O)4 clusters. In each CdC10NH6O4 cluster, Cd(2) is bonded in a distorted trigonal bipyramidal geometry to one N(2), one O(12), one O(13), one O(15), and one O(16) atom. The Cd(2)-N(2) bond length is 2.31 Å. The Cd(2)-O(12) bond length is 2.44 Å. The Cd(2)-O(13) bond length is 2.27 Å. The Cd(2)-O(15) bond length is 2.24 Å. The Cd(2)-O(16) bond length is 2.46 Å. There are ten inequivalent C sites. In the first C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(11) atom. The C(9)-N(2) bond length is 1.31 Å. The C(9)-H(11) bond length is 0.93 Å. In the second C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(14) atom. The C(13)-N(2) bond length is 1.33 Å. The C(13)-H(14) bond length is 0.93 Å. In the third C site, C(44) is bonded in a distorted single-bond geometry to one C(45) and one H(30) atom. The C(44)-C(45) bond length is 1.40 Å. The C(44)-H(30) bond length is 0.93 Å. In the fourth C site, C(45) is bonded in a trigonal planar geometry to one C(44), one C(46), and one C(48) atom. The C(45)-C(46) bond length is 1.38 Å. The C(45)-C(48) bond length is 1.54 Å. In the fifth C site, C(46) is bonded in a distorted single-bond geometry to one C(45) and one H(31) atom. The C(46)-H(31) bond length is 0.93 Å. In the sixth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(45), one O(12), and one O(13) atom. The C(48)-O(12) bond length is 1.20 Å. The C(48)-O(13) bond length is 1.33 Å. In the seventh C site, C(51) is bonded in a distorted single-bond geometry to one C(52) and one H(34) atom. The C(51)-C(52) bond length is 1.39 Å. The C(51)-H(34) bond length is 0.93 Å. In the eighth C site, C(52) is bonded in a trigonal planar geometry to one C(51), one C(53), and one C(55) atom. The C(52)-C(53) bond length is 1.39 Å. The C(52)-C(55) bond length is 1.49 Å. In the ninth C site, C(53) is bonded in a single-bond geometry to one C(52) and one H(35) atom. The C(53)-H(35) bond length is 0.93 Å. In the tenth C site, C(55) is bonded in a bent 120 degrees geometry to one C(52), one O(15), and one O(16) atom. The C(55)-O(15) bond length is 1.24 Å. The C(55)-O(16) bond length is 1.26 Å. N(2) is bonded in a trigonal planar geometry to one Cd(2), one C(13), and one C(9) atom. There are six inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(30) is bonded in a single-bond geometry to one C(44) atom. In the fourth H site, H(31) is bonded in a single-bond geometry to one C(46) atom. In the fifth H site, H(34) is bonded in a single-bond geometry to one C(51) atom. In the sixth H site, H(35) is bonded in a single-bond geometry to one C(53) atom. There are four inequivalent O sites. In the first O site, O(12) is bonded in a distorted single-bond geometry to one Cd(2) and one C(48) atom. In the second O site, O(13) is bonded in an L-shaped geometry to one Cd(2) and one C(48) atom. In the third O site, O(15) is bonded in a distorted water-like geometry to one Cd(2) and one C(55) atom. In the fourth O site, O(16) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(55) atom. In each CdC14NH10O4 cluster, Cd(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one O(4), one O(5), one O(7), and one O(8) atom. The Cd(1)-N(1) bond length is 2.31 Å. The Cd(1)-O(4) bond length is 2.45 Å. The Cd(1)-O(5) bond length is 2.24 Å. The Cd(1)-O(7) bond length is 2.38 Å. The Cd(1)-O(8) bond length is 2.35 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.30 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.26 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.34 Å. The C(3)-C(6) bond length is 1.56 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(3) atom. The C(4)-C(5) bond length is 1.35 Å. The C(4)-H(3) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.36 Å. The C(5)-H(4) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a water-like geometry to one C(3) and two equivalent H(5,6) atoms. Both C(6)-H(5,6) bond lengths are 0.97 Å. In the seventh C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(19) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-H(19) bond length is 0.93 Å. In the eighth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(27) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-C(27) bond length is 1.42 Å. In the ninth C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(20) atom. The C(25)-H(20) bond length is 0.93 Å. In the tenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(4), and one O(5) atom. The C(27)-O(4) bond length is 1.34 Å. The C(27)-O(5) bond length is 1.22 Å. In the eleventh C site, C(30) is bonded in a single-bond geometry to one C(31) and one H(23,24) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-H(23,24) bond length is 0.93 Å. In the twelfth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(34) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-C(34) bond length is 1.50 Å. In the thirteenth C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(23,24) atom. The C(32)-H(23,24) bond length is 0.93 Å. In the fourteenth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(7), and one O(8) atom. The C(34)-O(7) bond length is 1.26 Å. The C(34)-O(8) bond length is 1.29 Å. N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the eighth H site, H(23,24) is bonded in a single-bond geometry to one C(30) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(27) atom. In the second O site, O(5) is bonded in a distorted water-like geometry to one Cd(1) and one C(27) atom. In the third O site, O(7) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(34) atom. In the fourth O site, O(8) is bonded in an L-shaped geometry to one Cd(1) and one C(34) atom. In each CdH4(C2O)4 cluster, Cd(3) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(10), one O(2), and one O(9) atom. The Cd(3)-O(1) bond length is 2.33 Å. The Cd(3)-O(10) bond length is 2.33 Å. The Cd(3)-O(2) bond length is 2.43 Å. The Cd(3)-O(9) bond length is 2.38 Å. There are eight inequivalent C sites. In the first C site, C(37) is bonded in a distorted single-bond geometry to one C(36) and one H(26) atom. The C(37)-C(36) bond length is 1.34 Å. The C(37)-H(26) bond length is 0.93 Å. In the second C site, C(41) is bonded in a distorted single-bond geometry to one C(36) and one H(28) atom. The C(41)-C(36) bond length is 1.43 Å. The C(41)-H(28) bond length is 0.93 Å. In the third C site, C(14) is bonded in a distorted trigonal planar geometry to one C(15), one O(1), and one O(2) atom. The C(14)-C(15) bond length is 1.45 Å. The C(14)-O(1) bond length is 1.26 Å. The C(14)-O(2) bond length is 1.29 Å. In the fourth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(20) atom. The C(15)-C(16) bond length is 1.34 Å. The C(15)-C(20) bond length is 1.42 Å. In the fifth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(15) atom. The C(16)-H(15) bond length is 0.93 Å. In the sixth C site, C(20) is bonded in a distorted single-bond geometry to one C(15) and one H(17) atom. The C(20)-H(17) bond length is 0.93 Å. In the seventh C site, C(35) is bonded in a distorted trigonal planar geometry to one C(36), one O(10), and one O(9) atom. The C(35)-C(36) bond length is 1.46 Å. The C(35)-O(10) bond length is 1.23 Å. The C(35)-O(9) bond length is 1.29 Å. In the eighth C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(41) atom. There are four inequivalent H sites. In the first H site, H(26) is bonded in a single-bond geometry to one C(37) atom. In the second H site, H(28) is bonded in a single-bond geometry to one C(41) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one Cd(3) and one C(14) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cd(3) and one C(14) atom. In the third O site, O(9) is bonded in a distorted L-shaped geometry to one Cd(3) and one C(35) atom. In the fourth O site, O(10) is bonded in a distorted single-bond geometry to one Cd(3) and one C(35) atom. Linkers: 4 c1cc(CCCc2ccncc2)ccn1 ,6 [O]C(=O)c1ccc(Oc2cc(Oc3c[c]c([C]=O)cc3)cc(C([O])=O)c2)cc1 ,8 [O]C(=O)c1ccc(Oc2cc(Oc3ccc(C([O])=O)cc3)cc(C([O])=O)c2)cc1 ,2 [O][C]c1[c]cc(Oc2cc(Oc3ccc(C([O])=O)cc3)cc(C([O])=O)c2)cc1 ,4 [O][C]c1[c][c]cc(Oc2ccc(C([O])=O)cc2)c1 ,4 [O]C(=O)c1ccc(Oc2c[c]cc(C([O])=O)c2)cc1. Metal clusters: 12 [C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 6.26 A, density 1.24 g/cm3, surface area 4324.91 m2/g, accessible volume 0.33 cm3/g