Zn7C88N29H58I14Zn2C20N7H14I4ZnC16N5H10I2ZnC4H4(NI)2ZnC16N5H9I2 is Indium-like structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of two Zn2C20N7H14I4 clusters, two Zn7C88N29H58I14 clusters, two ZnC16N5H10I2 clusters, two ZnC16N5H9I2 clusters, and two ZnC4H4(NI)2 clusters. In each Zn2C20N7H14I4 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(3) is bonded in a distorted tetrahedral geometry to one N(3), one N(7), one I(5), and one I(6) atom. The Zn(3)-N(3) bond length is 2.08 Å. The Zn(3)-N(7) bond length is 2.07 Å. The Zn(3)-I(5) bond length is 2.52 Å. The Zn(3)-I(6) bond length is 2.56 Å. In the second Zn site, Zn(4) is bonded in a tetrahedral geometry to one N(13), one N(8), one I(7), and one I(8) atom. The Zn(4)-N(13) bond length is 2.07 Å. The Zn(4)-N(8) bond length is 2.06 Å. The Zn(4)-I(7) bond length is 2.54 Å. The Zn(4)-I(8) bond length is 2.56 Å. There are twenty inequivalent C sites. In the first C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(11)-N(3) bond length is 1.33 Å. The C(11)-H(9) bond length is 0.95 Å. In the second C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(12) atom. The C(15)-N(3) bond length is 1.34 Å. The C(15)-H(12) bond length is 0.95 Å. In the third C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(13) atom. The C(19)-N(7) bond length is 1.34 Å. The C(19)-H(13) bond length is 0.95 Å. In the fourth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(14) atom. The C(20)-C(21) bond length is 1.38 Å. The C(20)-H(14) bond length is 0.95 Å. In the fifth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(34) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-C(34) bond length is 1.49 Å. In the sixth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one H(15) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(15) bond length is 0.95 Å. In the seventh C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(7), and one H(16) atom. The C(23)-N(7) bond length is 1.33 Å. The C(23)-H(16) bond length is 0.95 Å. In the eighth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(25), one N(8), and one H(17) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-N(8) bond length is 1.34 Å. The C(24)-H(17) bond length is 0.95 Å. In the ninth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one C(26), and one H(18) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-H(18) bond length is 0.95 Å. In the tenth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(35) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-C(35) bond length is 1.48 Å. In the eleventh C site, C(27) is bonded in a distorted trigonal planar geometry to one C(26), one C(28), and one H(19) atom. The C(27)-C(28) bond length is 1.37 Å. The C(27)-H(19) bond length is 0.95 Å. In the twelfth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(27), one N(8), and one H(20) atom. The C(28)-N(8) bond length is 1.34 Å. The C(28)-H(20) bond length is 0.95 Å. In the thirteenth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one N(13) and one H(25) atom. The C(37)-N(13) bond length is 1.34 Å. The C(37)-H(25) bond length is 0.95 Å. In the fourteenth C site, C(30) is bonded in a distorted single-bond geometry to one C(31) and one H(22,23) atom. The C(30)-C(31) bond length is 1.38 Å. The C(30)-H(22,23) bond length is 0.95 Å. In the fifteenth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(36) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-C(36) bond length is 1.49 Å. In the sixteenth C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(22,23) atom. The C(32)-H(22,23) bond length is 0.95 Å. In the seventeenth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(21), one N(10), and one N(12) atom. The C(34)-N(10) bond length is 1.34 Å. The C(34)-N(12) bond length is 1.34 Å. In the eighteenth C site, C(35) is bonded in a trigonal planar geometry to one C(26), one N(10), and one N(11) atom. The C(35)-N(10) bond length is 1.34 Å. The C(35)-N(11) bond length is 1.34 Å. In the nineteenth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(31), one N(11), and one N(12) atom. The C(36)-N(11) bond length is 1.34 Å. The C(36)-N(12) bond length is 1.32 Å. In the twentieth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(13) and one H(28) atom. The C(41)-N(13) bond length is 1.33 Å. The C(41)-H(28) bond length is 0.95 Å. There are seven inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Zn(3), one C(11), and one C(15) atom. In the second N site, N(7) is bonded in a trigonal planar geometry to one Zn(3), one C(19), and one C(23) atom. In the third N site, N(10) is bonded in a bent 120 degrees geometry to one C(34) and one C(35) atom. In the fourth N site, N(11) is bonded in a bent 120 degrees geometry to one C(35) and one C(36) atom. In the fifth N site, N(12) is bonded in a bent 120 degrees geometry to one C(34) and one C(36) atom. In the sixth N site, N(8) is bonded in a trigonal planar geometry to one Zn(4), one C(24), and one C(28) atom. In the seventh N site, N(13) is bonded in a trigonal planar geometry to one Zn(4), one C(37), and one C(41) atom. There are thirteen inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(25) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(22,23) is bonded in a single-bond geometry to one C(30) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(28) atom. In the twelfth H site, H(25) is bonded in a single-bond geometry to one C(37) atom. In the thirteenth H site, H(28) is bonded in a single-bond geometry to one C(41) atom. There are four inequivalent I sites. In the first I site, I(5) is bonded in a single-bond geometry to one Zn(3) atom. In the second I site, I(6) is bonded in a single-bond geometry to one Zn(3) atom. In the third I site, I(7) is bonded in a single-bond geometry to one Zn(4) atom. In the fourth I site, I(8) is bonded in a single-bond geometry to one Zn(4) atom. In each Zn7C88N29H58I14 cluster, there are seven inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(45), one I(1), and one I(2) atom. The Zn(1)-N(1) bond length is 2.06 Å. The Zn(1)-N(45) bond length is 2.09 Å. The Zn(1)-I(1) bond length is 2.55 Å. The Zn(1)-I(2) bond length is 2.54 Å. In the second Zn site, Zn(2) is bonded in a distorted tetrahedral geometry to one N(2), one N(33), one I(3), and one I(4) atom. The Zn(2)-N(2) bond length is 2.09 Å. The Zn(2)-N(33) bond length is 2.07 Å. The Zn(2)-I(3) bond length is 2.55 Å. The Zn(2)-I(4) bond length is 2.54 Å. In the third Zn site, Zn(6) is bonded in a distorted tetrahedral geometry to one N(14), one N(19), one I(11), and one I(12) atom. The Zn(6)-N(14) bond length is 2.06 Å. The Zn(6)-N(19) bond length is 2.07 Å. The Zn(6)-I(11) bond length is 2.56 Å. The Zn(6)-I(12) bond length is 2.51 Å. In the fourth Zn site, Zn(10) is bonded in a distorted tetrahedral geometry to one N(38), one N(43), one I(19), and one I(20) atom. The Zn(10)-N(38) bond length is 2.06 Å. The Zn(10)-N(43) bond length is 2.08 Å. The Zn(10)-I(19) bond length is 2.57 Å. The Zn(10)-I(20) bond length is 2.50 Å. In the fifth Zn site, Zn(12) is bonded in a distorted tetrahedral geometry to one N(15), one N(44), one I(23), and one I(24) atom. The Zn(12)-N(15) bond length is 2.07 Å. The Zn(12)-N(44) bond length is 2.06 Å. The Zn(12)-I(23) bond length is 2.53 Å. The Zn(12)-I(24) bond length is 2.55 Å. In the sixth Zn site, Zn(11) is bonded in a tetrahedral geometry to one N(32), one N(39), one I(21), and one I(22) atom. The Zn(11)-N(32) bond length is 2.08 Å. The Zn(11)-N(39) bond length is 2.07 Å. The Zn(11)-I(21) bond length is 2.55 Å. The Zn(11)-I(22) bond length is 2.54 Å. In the seventh Zn site, Zn(9) is bonded in a distorted tetrahedral geometry to one N(26), one N(31), one I(17), and one I(18) atom. The Zn(9)-N(26) bond length is 2.07 Å. The Zn(9)-N(31) bond length is 2.06 Å. The Zn(9)-I(17) bond length is 2.56 Å. The Zn(9)-I(18) bond length is 2.53 Å. There are eighty-eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 0.95 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(16), one C(2), and one C(4) atom. The C(3)-C(16) bond length is 1.48 Å. The C(3)-C(4) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.32 Å. The C(5)-H(4) bond length is 0.95 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(2), and one H(5) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-N(2) bond length is 1.33 Å. The C(6)-H(5) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one H(6) atom. The C(7)-C(8) bond length is 1.38 Å. The C(7)-H(6) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(17), one C(7), and one C(9) atom. The C(8)-C(17) bond length is 1.48 Å. The C(8)-C(9) bond length is 1.39 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(9)-H(7) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(8) bond length is 0.95 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(10) bond length is 0.95 Å. In the twelfth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(18) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-C(18) bond length is 1.48 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(14)-H(11) bond length is 0.95 Å. In the fourteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(4), and one N(6) atom. The C(16)-N(4) bond length is 1.34 Å. The C(16)-N(6) bond length is 1.33 Å. In the fifteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(8), one N(4), and one N(5) atom. The C(17)-N(4) bond length is 1.34 Å. The C(17)-N(5) bond length is 1.34 Å. In the sixteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(13), one N(5), and one N(6) atom. The C(18)-N(5) bond length is 1.35 Å. The C(18)-N(6) bond length is 1.33 Å. In the seventeenth C site, C(38) is bonded in a distorted single-bond geometry to one C(39) and one H(26) atom. The C(38)-C(39) bond length is 1.38 Å. The C(38)-H(26) bond length is 0.95 Å. In the eighteenth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(52) atom. The C(39)-C(40) bond length is 1.39 Å. The C(39)-C(52) bond length is 1.48 Å. In the nineteenth C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one H(27) atom. The C(40)-H(27) bond length is 0.95 Å. In the twentieth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(43), one N(14), and one H(29) atom. The C(42)-C(43) bond length is 1.37 Å. The C(42)-N(14) bond length is 1.33 Å. The C(42)-H(29) bond length is 0.95 Å. In the twenty-first C site, C(43) is bonded in a distorted single-bond geometry to one C(42), one C(44), and one H(30) atom. The C(43)-C(44) bond length is 1.39 Å. The C(43)-H(30) bond length is 0.95 Å. In the twenty-second C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(53) atom. The C(44)-C(45) bond length is 1.39 Å. The C(44)-C(53) bond length is 1.49 Å. In the twenty-third C site, C(45) is bonded in a distorted single-bond geometry to one C(44), one C(46), and one H(31) atom. The C(45)-C(46) bond length is 1.38 Å. The C(45)-H(31) bond length is 0.95 Å. In the twenty-fourth C site, C(46) is bonded in a 3-coordinate geometry to one C(45), one N(14), and one H(32) atom. The C(46)-N(14) bond length is 1.36 Å. The C(46)-H(32) bond length is 0.95 Å. In the twenty-fifth C site, C(47) is bonded in a distorted bent 120 degrees geometry to one C(48), one N(15), and one H(33) atom. The C(47)-C(48) bond length is 1.38 Å. The C(47)-N(15) bond length is 1.33 Å. The C(47)-H(33) bond length is 0.95 Å. In the twenty-sixth C site, C(48) is bonded in a distorted trigonal planar geometry to one C(47), one C(49), and one H(34) atom. The C(48)-C(49) bond length is 1.39 Å. The C(48)-H(34) bond length is 0.95 Å. In the twenty-seventh C site, C(49) is bonded in a trigonal planar geometry to one C(48), one C(50), and one C(54) atom. The C(49)-C(50) bond length is 1.39 Å. The C(49)-C(54) bond length is 1.47 Å. In the twenty-eighth C site, C(50) is bonded in a distorted single-bond geometry to one C(49) and one H(35) atom. The C(50)-H(35) bond length is 0.95 Å. In the twenty-ninth C site, C(51) is bonded in a distorted bent 120 degrees geometry to one N(15) and one H(36) atom. The C(51)-N(15) bond length is 1.34 Å. The C(51)-H(36) bond length is 0.95 Å. In the thirtieth C site, C(52) is bonded in a distorted trigonal planar geometry to one C(39), one N(16), and one N(18) atom. The C(52)-N(16) bond length is 1.33 Å. The C(52)-N(18) bond length is 1.33 Å. In the thirty-first C site, C(53) is bonded in a distorted trigonal planar geometry to one C(44), one N(16), and one N(17) atom. The C(53)-N(16) bond length is 1.34 Å. The C(53)-N(17) bond length is 1.34 Å. In the thirty-second C site, C(54) is bonded in a distorted trigonal planar geometry to one C(49), one N(17), and one N(18) atom. The C(54)-N(17) bond length is 1.35 Å. The C(54)-N(18) bond length is 1.33 Å. In the thirty-third C site, C(55) is bonded in a distorted bent 120 degrees geometry to one N(19) and one H(37) atom. The C(55)-N(19) bond length is 1.35 Å. The C(55)-H(37) bond length is 0.95 Å. In the thirty-fourth C site, C(59) is bonded in a distorted bent 120 degrees geometry to one N(19) and one H(40) atom. The C(59)-N(19) bond length is 1.34 Å. The C(59)-H(40) bond length is 0.95 Å. In the thirty-fifth C site, C(78) is bonded in a distorted bent 120 degrees geometry to one N(26) and one H(52) atom. The C(78)-N(26) bond length is 1.34 Å. The C(78)-H(52) bond length is 0.95 Å. In the thirty-sixth C site, C(82) is bonded in a distorted bent 120 degrees geometry to one N(26) and one H(55) atom. The C(82)-N(26) bond length is 1.33 Å. The C(82)-H(55) bond length is 0.95 Å. In the thirty-seventh C site, C(91) is bonded in a distorted bent 120 degrees geometry to one N(31) and one H(60) atom. The C(91)-N(31) bond length is 1.35 Å. The C(91)-H(60) bond length is 0.95 Å. In the thirty-eighth C site, C(92) is bonded in a distorted single-bond geometry to one C(93) and one H(61) atom. The C(92)-C(93) bond length is 1.38 Å. The C(92)-H(61) bond length is 0.95 Å. In the thirty-ninth C site, C(93) is bonded in a trigonal planar geometry to one C(106), one C(92), and one C(94) atom. The C(93)-C(106) bond length is 1.49 Å. The C(93)-C(94) bond length is 1.38 Å. In the fortieth C site, C(94) is bonded in a distorted trigonal planar geometry to one C(93), one C(95), and one H(62) atom. The C(94)-C(95) bond length is 1.39 Å. The C(94)-H(62) bond length is 0.95 Å. In the forty-first C site, C(95) is bonded in a distorted bent 120 degrees geometry to one C(94), one N(31), and one H(63) atom. The C(95)-N(31) bond length is 1.32 Å. The C(95)-H(63) bond length is 0.95 Å. In the forty-second C site, C(96) is bonded in a distorted bent 120 degrees geometry to one C(97), one N(32), and one H(64) atom. The C(96)-C(97) bond length is 1.38 Å. The C(96)-N(32) bond length is 1.32 Å. The C(96)-H(64) bond length is 0.95 Å. In the forty-third C site, C(97) is bonded in a distorted trigonal planar geometry to one C(96), one C(98), and one H(65) atom. The C(97)-C(98) bond length is 1.36 Å. The C(97)-H(65) bond length is 0.95 Å. In the forty-fourth C site, C(98) is bonded in a trigonal planar geometry to one C(107), one C(97), and one C(99) atom. The C(98)-C(107) bond length is 1.50 Å. The C(98)-C(99) bond length is 1.35 Å. In the forty-fifth C site, C(99) is bonded in a distorted trigonal planar geometry to one C(100), one C(98), and one H(66) atom. The C(99)-C(100) bond length is 1.38 Å. The C(99)-H(66) bond length is 0.95 Å. In the forty-sixth C site, C(100) is bonded in a distorted bent 120 degrees geometry to one C(99), one N(32), and one H(67) atom. The C(100)-N(32) bond length is 1.32 Å. The C(100)-H(67) bond length is 0.95 Å. In the forty-seventh C site, C(101) is bonded in a distorted bent 120 degrees geometry to one C(102), one N(33), and one H(68) atom. The C(101)-C(102) bond length is 1.39 Å. The C(101)-N(33) bond length is 1.33 Å. The C(101)-H(68) bond length is 0.95 Å. In the forty-eighth C site, C(102) is bonded in a distorted trigonal planar geometry to one C(101), one C(103), and one H(69) atom. The C(102)-C(103) bond length is 1.37 Å. The C(102)-H(69) bond length is 0.95 Å. In the forty-ninth C site, C(103) is bonded in a trigonal planar geometry to one C(102), one C(104), and one C(108) atom. The C(103)-C(104) bond length is 1.39 Å. The C(103)-C(108) bond length is 1.48 Å. In the fiftieth C site, C(104) is bonded in a distorted single-bond geometry to one C(103) and one H(70) atom. The C(104)-H(70) bond length is 0.95 Å. In the fifty-first C site, C(105) is bonded in a distorted bent 120 degrees geometry to one N(33) and one H(71) atom. The C(105)-N(33) bond length is 1.32 Å. The C(105)-H(71) bond length is 0.95 Å. In the fifty-second C site, C(106) is bonded in a distorted trigonal planar geometry to one C(93), one N(34), and one N(36) atom. The C(106)-N(34) bond length is 1.35 Å. The C(106)-N(36) bond length is 1.33 Å. In the fifty-third C site, C(107) is bonded in a trigonal planar geometry to one C(98), one N(34), and one N(35) atom. The C(107)-N(34) bond length is 1.35 Å. The C(107)-N(35) bond length is 1.33 Å. In the fifty-fourth C site, C(108) is bonded in a distorted trigonal planar geometry to one C(103), one N(35), and one N(36) atom. The C(108)-N(35) bond length is 1.33 Å. The C(108)-N(36) bond length is 1.34 Å. In the fifty-fifth C site, C(110) is bonded in a distorted single-bond geometry to one C(111) and one H(73) atom. The C(110)-C(111) bond length is 1.38 Å. The C(110)-H(73) bond length is 0.95 Å. In the fifty-sixth C site, C(111) is bonded in a trigonal planar geometry to one C(110), one C(112), and one C(124) atom. The C(111)-C(112) bond length is 1.39 Å. The C(111)-C(124) bond length is 1.48 Å. In the fifty-seventh C site, C(112) is bonded in a distorted single-bond geometry to one C(111) and one H(74) atom. The C(112)-H(74) bond length is 0.95 Å. In the fifty-eighth C site, C(114) is bonded in a distorted bent 120 degrees geometry to one N(38) and one H(76) atom. The C(114)-N(38) bond length is 1.34 Å. The C(114)-H(76) bond length is 0.95 Å. In the fifty-ninth C site, C(115) is bonded in a single-bond geometry to one C(116) and one H(77) atom. The C(115)-C(116) bond length is 1.38 Å. The C(115)-H(77) bond length is 0.95 Å. In the sixtieth C site, C(116) is bonded in a trigonal planar geometry to one C(115), one C(117), and one C(125) atom. The C(116)-C(117) bond length is 1.38 Å. The C(116)-C(125) bond length is 1.49 Å. In the sixty-first C site, C(117) is bonded in a distorted trigonal planar geometry to one C(116), one C(118), and one H(78) atom. The C(117)-C(118) bond length is 1.39 Å. The C(117)-H(78) bond length is 0.95 Å. In the sixty-second C site, C(118) is bonded in a distorted bent 120 degrees geometry to one C(117), one N(38), and one H(79) atom. The C(118)-N(38) bond length is 1.34 Å. The C(118)-H(79) bond length is 0.95 Å. In the sixty-third C site, C(119) is bonded in a distorted bent 120 degrees geometry to one N(39) and one H(80) atom. The C(119)-N(39) bond length is 1.33 Å. The C(119)-H(80) bond length is 0.95 Å. In the sixty-fourth C site, C(120) is bonded in a distorted single-bond geometry to one C(121) and one H(81) atom. The C(120)-C(121) bond length is 1.38 Å. The C(120)-H(81) bond length is 0.95 Å. In the sixty-fifth C site, C(121) is bonded in a trigonal planar geometry to one C(120), one C(122), and one C(126) atom. The C(121)-C(122) bond length is 1.39 Å. The C(121)-C(126) bond length is 1.48 Å. In the sixty-sixth C site, C(122) is bonded in a distorted trigonal planar geometry to one C(121), one C(123), and one H(82) atom. The C(122)-C(123) bond length is 1.37 Å. The C(122)-H(82) bond length is 0.95 Å. In the sixty-seventh C site, C(123) is bonded in a distorted bent 120 degrees geometry to one C(122), one N(39), and one H(83) atom. The C(123)-N(39) bond length is 1.34 Å. The C(123)-H(83) bond length is 0.95 Å. In the sixty-eighth C site, C(124) is bonded in a distorted trigonal planar geometry to one C(111), one N(40), and one N(42) atom. The C(124)-N(40) bond length is 1.34 Å. The C(124)-N(42) bond length is 1.33 Å. In the sixty-ninth C site, C(125) is bonded in a distorted trigonal planar geometry to one C(116), one N(40), and one N(41) atom. The C(125)-N(40) bond length is 1.33 Å. The C(125)-N(41) bond length is 1.33 Å. In the seventieth C site, C(126) is bonded in a distorted trigonal planar geometry to one C(121), one N(41), and one N(42) atom. The C(126)-N(41) bond length is 1.34 Å. The C(126)-N(42) bond length is 1.32 Å. In the seventy-first C site, C(127) is bonded in a distorted trigonal planar geometry to one C(128), one N(43), and one H(84) atom. The C(127)-C(128) bond length is 1.38 Å. The C(127)-N(43) bond length is 1.33 Å. The C(127)-H(84) bond length is 0.95 Å. In the seventy-second C site, C(128) is bonded in a single-bond geometry to one C(127), one C(129), and one H(85) atom. The C(128)-C(129) bond length is 1.38 Å. The C(128)-H(85) bond length is 0.95 Å. In the seventy-third C site, C(129) is bonded in a trigonal planar geometry to one C(128), one C(130), and one C(142) atom. The C(129)-C(130) bond length is 1.39 Å. The C(129)-C(142) bond length is 1.48 Å. In the seventy-fourth C site, C(130) is bonded in a distorted single-bond geometry to one C(129) and one H(86) atom. The C(130)-H(86) bond length is 0.95 Å. In the seventy-fifth C site, C(131) is bonded in a distorted bent 120 degrees geometry to one N(43) and one H(87) atom. The C(131)-N(43) bond length is 1.34 Å. The C(131)-H(87) bond length is 0.95 Å. In the seventy-sixth C site, C(132) is bonded in a distorted trigonal planar geometry to one C(133), one N(44), and one H(88) atom. The C(132)-C(133) bond length is 1.39 Å. The C(132)-N(44) bond length is 1.35 Å. The C(132)-H(88) bond length is 0.95 Å. In the seventy-seventh C site, C(133) is bonded in a single-bond geometry to one C(132), one C(134), and one H(89) atom. The C(133)-C(134) bond length is 1.39 Å. The C(133)-H(89) bond length is 0.95 Å. In the seventy-eighth C site, C(134) is bonded in a trigonal planar geometry to one C(133), one C(135), and one C(143) atom. The C(134)-C(135) bond length is 1.40 Å. The C(134)-C(143) bond length is 1.49 Å. In the seventy-ninth C site, C(135) is bonded in a distorted single-bond geometry to one C(134), one C(136), and one H(90) atom. The C(135)-C(136) bond length is 1.38 Å. The C(135)-H(90) bond length is 0.95 Å. In the eightieth C site, C(136) is bonded in a distorted bent 120 degrees geometry to one C(135), one N(44), and one H(91) atom. The C(136)-N(44) bond length is 1.34 Å. The C(136)-H(91) bond length is 0.95 Å. In the eighty-first C site, C(137) is bonded in a distorted bent 120 degrees geometry to one C(138), one N(45), and one H(92) atom. The C(137)-C(138) bond length is 1.38 Å. The C(137)-N(45) bond length is 1.33 Å. The C(137)-H(92) bond length is 0.95 Å. In the eighty-second C site, C(138) is bonded in a distorted trigonal planar geometry to one C(137), one C(139), and one H(93) atom. The C(138)-C(139) bond length is 1.40 Å. The C(138)-H(93) bond length is 0.95 Å. In the eighty-third C site, C(139) is bonded in a trigonal planar geometry to one C(138), one C(140), and one C(144) atom. The C(139)-C(140) bond length is 1.38 Å. The C(139)-C(144) bond length is 1.48 Å. In the eighty-fourth C site, C(140) is bonded in a distorted trigonal planar geometry to one C(139), one C(141), and one H(94) atom. The C(140)-C(141) bond length is 1.39 Å. The C(140)-H(94) bond length is 0.95 Å. In the eighty-fifth C site, C(141) is bonded in a distorted bent 120 degrees geometry to one C(140), one N(45), and one H(95) atom. The C(141)-N(45) bond length is 1.33 Å. The C(141)-H(95) bond length is 0.95 Å. In the eighty-sixth C site, C(142) is bonded in a distorted trigonal planar geometry to one C(129), one N(46), and one N(48) atom. The C(142)-N(46) bond length is 1.34 Å. The C(142)-N(48) bond length is 1.34 Å. In the eighty-seventh C site, C(143) is bonded in a distorted trigonal planar geometry to one C(134), one N(46), and one N(47) atom. The C(143)-N(46) bond length is 1.34 Å. The C(143)-N(47) bond length is 1.34 Å. In the eighty-eighth C site, C(144) is bonded in a distorted trigonal planar geometry to one C(139), one N(47), and one N(48) atom. The C(144)-N(47) bond length is 1.34 Å. The C(144)-N(48) bond length is 1.34 Å. There are twenty-nine inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(10), and one C(6) atom. In the third N site, N(4) is bonded in a bent 120 degrees geometry to one C(16) and one C(17) atom. In the fourth N site, N(5) is bonded in a bent 120 degrees geometry to one C(17) and one C(18) atom. In the fifth N site, N(6) is bonded in a bent 120 degrees geometry to one C(16) and one C(18) atom. In the sixth N site, N(14) is bonded in a trigonal planar geometry to one Zn(6), one C(42), and one C(46) atom. In the seventh N site, N(15) is bonded in a trigonal planar geometry to one Zn(12), one C(47), and one C(51) atom. In the eighth N site, N(16) is bonded in a bent 120 degrees geometry to one C(52) and one C(53) atom. In the ninth N site, N(17) is bonded in a bent 120 degrees geometry to one C(53) and one C(54) atom. In the tenth N site, N(18) is bonded in a bent 120 degrees geometry to one C(52) and one C(54) atom. In the eleventh N site, N(19) is bonded in a trigonal planar geometry to one Zn(6), one C(55), and one C(59) atom. In the twelfth N site, N(26) is bonded in a trigonal planar geometry to one Zn(9), one C(78), and one C(82) atom. In the thirteenth N site, N(31) is bonded in a trigonal planar geometry to one Zn(9), one C(91), and one C(95) atom. In the fourteenth N site, N(32) is bonded in a trigonal planar geometry to one Zn(11), one C(100), and one C(96) atom. In the fifteenth N site, N(33) is bonded in a trigonal planar geometry to one Zn(2), one C(101), and one C(105) atom. In the sixteenth N site, N(34) is bonded in a bent 120 degrees geometry to one C(106) and one C(107) atom. In the seventeenth N site, N(35) is bonded in a bent 120 degrees geometry to one C(107) and one C(108) atom. In the eighteenth N site, N(36) is bonded in a bent 120 degrees geometry to one C(106) and one C(108) atom. In the nineteenth N site, N(38) is bonded in a trigonal planar geometry to one Zn(10), one C(114), and one C(118) atom. In the twentieth N site, N(39) is bonded in a trigonal planar geometry to one Zn(11), one C(119), and one C(123) atom. In the twenty-first N site, N(40) is bonded in a bent 120 degrees geometry to one C(124) and one C(125) atom. In the twenty-second N site, N(41) is bonded in a bent 120 degrees geometry to one C(125) and one C(126) atom. In the twenty-third N site, N(42) is bonded in a bent 120 degrees geometry to one C(124) and one C(126) atom. In the twenty-fourth N site, N(43) is bonded in a trigonal planar geometry to one Zn(10), one C(127), and one C(131) atom. In the twenty-fifth N site, N(44) is bonded in a trigonal planar geometry to one Zn(12), one C(132), and one C(136) atom. In the twenty-sixth N site, N(45) is bonded in a trigonal planar geometry to one Zn(1), one C(137), and one C(141) atom. In the twenty-seventh N site, N(46) is bonded in a bent 120 degrees geometry to one C(142) and one C(143) atom. In the twenty-eighth N site, N(47) is bonded in a bent 120 degrees geometry to one C(143) and one C(144) atom. In the twenty-ninth N site, N(48) is bonded in a bent 120 degrees geometry to one C(142) and one C(144) atom. There are fifty-eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(26) is bonded in a single-bond geometry to one C(38) atom. In the twelfth H site, H(27) is bonded in a single-bond geometry to one C(40) atom. In the thirteenth H site, H(33) is bonded in a single-bond geometry to one C(47) atom. In the fourteenth H site, H(34) is bonded in a single-bond geometry to one C(48) atom. In the fifteenth H site, H(35) is bonded in a single-bond geometry to one C(50) atom. In the sixteenth H site, H(36) is bonded in a single-bond geometry to one C(51) atom. In the seventeenth H site, H(30) is bonded in a single-bond geometry to one C(43) atom. In the eighteenth H site, H(31) is bonded in a single-bond geometry to one C(45) atom. In the nineteenth H site, H(32) is bonded in a single-bond geometry to one C(46) atom. In the twentieth H site, H(37) is bonded in a single-bond geometry to one C(55) atom. In the twenty-first H site, H(40) is bonded in a single-bond geometry to one C(59) atom. In the twenty-second H site, H(61) is bonded in a single-bond geometry to one C(92) atom. In the twenty-third H site, H(64) is bonded in a single-bond geometry to one C(96) atom. In the twenty-fourth H site, H(65) is bonded in a single-bond geometry to one C(97) atom. In the twenty-fifth H site, H(66) is bonded in a single-bond geometry to one C(99) atom. In the twenty-sixth H site, H(67) is bonded in a single-bond geometry to one C(100) atom. In the twenty-seventh H site, H(62) is bonded in a single-bond geometry to one C(94) atom. In the twenty-eighth H site, H(69) is bonded in a single-bond geometry to one C(102) atom. In the twenty-ninth H site, H(70) is bonded in a single-bond geometry to one C(104) atom. In the thirtieth H site, H(68) is bonded in a single-bond geometry to one C(101) atom. In the thirty-first H site, H(63) is bonded in a single-bond geometry to one C(95) atom. In the thirty-second H site, H(73) is bonded in a single-bond geometry to one C(110) atom. In the thirty-third H site, H(74) is bonded in a single-bond geometry to one C(112) atom. In the thirty-fourth H site, H(71) is bonded in a single-bond geometry to one C(105) atom. In the thirty-fifth H site, H(76) is bonded in a single-bond geometry to one C(114) atom. In the thirty-sixth H site, H(77) is bonded in a single-bond geometry to one C(115) atom. In the thirty-seventh H site, H(78) is bonded in a single-bond geometry to one C(117) atom. In the thirty-eighth H site, H(79) is bonded in a single-bond geometry to one C(118) atom. In the thirty-ninth H site, H(80) is bonded in a single-bond geometry to one C(119) atom. In the fortieth H site, H(81) is bonded in a single-bond geometry to one C(120) atom. In the forty-first H site, H(82) is bonded in a single-bond geometry to one C(122) atom. In the forty-second H site, H(83) is bonded in a single-bond geometry to one C(123) atom. In the forty-third H site, H(84) is bonded in a single-bond geometry to one C(127) atom. In the forty-fourth H site, H(85) is bonded in a single-bond geometry to one C(128) atom. In the forty-fifth H site, H(86) is bonded in a single-bond geometry to one C(130) atom. In the forty-sixth H site, H(87) is bonded in a single-bond geometry to one C(131) atom. In the forty-seventh H site, H(88) is bonded in a single-bond geometry to one C(132) atom. In the forty-eighth H site, H(89) is bonded in a single-bond geometry to one C(133) atom. In the forty-ninth H site, H(90) is bonded in a single-bond geometry to one C(135) atom. In the fiftieth H site, H(91) is bonded in a single-bond geometry to one C(136) atom. In the fifty-first H site, H(92) is bonded in a single-bond geometry to one C(137) atom. In the fifty-second H site, H(93) is bonded in a single-bond geometry to one C(138) atom. In the fifty-third H site, H(94) is bonded in a single-bond geometry to one C(140) atom. In the fifty-fourth H site, H(95) is bonded in a single-bond geometry to one C(141) atom. In the fifty-fifth H site, H(29) is bonded in a single-bond geometry to one C(42) atom. In the fifty-sixth H site, H(52) is bonded in a single-bond geometry to one C(78) atom. In the fifty-seventh H site, H(55) is bonded in a single-bond geometry to one C(82) atom. In the fifty-eighth H site, H(60) is bonded in a single-bond geometry to one C(91) atom. There are fourteen inequivalent I sites. In the first I site, I(11) is bonded in a single-bond geometry to one Zn(6) atom. In the second I site, I(12) is bonded in a single-bond geometry to one Zn(6) atom. In the third I site, I(17) is bonded in a single-bond geometry to one Zn(9) atom. In the fourth I site, I(18) is bonded in a single-bond geometry to one Zn(9) atom. In the fifth I site, I(19) is bonded in a single-bond geometry to one Zn(10) atom. In the sixth I site, I(20) is bonded in a single-bond geometry to one Zn(10) atom. In the seventh I site, I(23) is bonded in a single-bond geometry to one Zn(12) atom. In the eighth I site, I(24) is bonded in a single-bond geometry to one Zn(12) atom. In the ninth I site, I(21) is bonded in a single-bond geometry to one Zn(11) atom. In the tenth I site, I(22) is bonded in a single-bond geometry to one Zn(11) atom. In the eleventh I site, I(1) is bonded in a single-bond geometry to one Zn(1) atom. In the twelfth I site, I(2) is bonded in a single-bond geometry to one Zn(1) atom. In the thirteenth I site, I(3) is bonded in a single-bond geometry to one Zn(2) atom. In the fourteenth I site, I(4) is bonded in a single-bond geometry to one Zn(2) atom. In each ZnC16N5H10I2 cluster, Zn(5) is bonded in a distorted tetrahedral geometry to one N(27), one N(9), one I(10), and one I(9) atom. The Zn(5)-N(27) bond length is 2.08 Å. The Zn(5)-N(9) bond length is 2.07 Å. The Zn(5)-I(10) bond length is 2.54 Å. The Zn(5)-I(9) bond length is 2.55 Å. There are sixteen inequivalent C sites. In the first C site, C(74) is bonded in a distorted single-bond geometry to one C(75) and one H(49,50) atom. The C(74)-C(75) bond length is 1.38 Å. The C(74)-H(49,50) bond length is 0.95 Å. In the second C site, C(75) is bonded in a trigonal planar geometry to one C(74), one C(76), and one C(88) atom. The C(75)-C(76) bond length is 1.38 Å. The C(75)-C(88) bond length is 1.48 Å. In the third C site, C(76) is bonded in a distorted single-bond geometry to one C(75) and one H(49,50) atom. The C(76)-H(49,50) bond length is 0.95 Å. In the fourth C site, C(79) is bonded in a distorted single-bond geometry to one C(80) and one H(53) atom. The C(79)-C(80) bond length is 1.39 Å. The C(79)-H(53) bond length is 0.95 Å. In the fifth C site, C(80) is bonded in a trigonal planar geometry to one C(79), one C(81), and one C(89) atom. The C(80)-C(81) bond length is 1.39 Å. The C(80)-C(89) bond length is 1.49 Å. In the sixth C site, C(81) is bonded in a distorted single-bond geometry to one C(80) and one H(54) atom. The C(81)-H(54) bond length is 0.95 Å. In the seventh C site, C(83) is bonded in a distorted bent 120 degrees geometry to one N(27) and one H(56) atom. The C(83)-N(27) bond length is 1.35 Å. The C(83)-H(56) bond length is 0.95 Å. In the eighth C site, C(84) is bonded in a distorted single-bond geometry to one C(85) and one H(57) atom. The C(84)-C(85) bond length is 1.39 Å. The C(84)-H(57) bond length is 0.95 Å. In the ninth C site, C(85) is bonded in a trigonal planar geometry to one C(84), one C(86), and one C(90) atom. The C(85)-C(86) bond length is 1.40 Å. The C(85)-C(90) bond length is 1.48 Å. In the tenth C site, C(86) is bonded in a distorted trigonal planar geometry to one C(85), one C(87), and one H(58) atom. The C(86)-C(87) bond length is 1.39 Å. The C(86)-H(58) bond length is 0.95 Å. In the eleventh C site, C(87) is bonded in a distorted bent 120 degrees geometry to one C(86), one N(27), and one H(59) atom. The C(87)-N(27) bond length is 1.34 Å. The C(87)-H(59) bond length is 0.95 Å. In the twelfth C site, C(90) is bonded in a distorted bent 120 degrees geometry to one C(85), one N(29), and one N(30) atom. The C(90)-N(29) bond length is 1.33 Å. The C(90)-N(30) bond length is 1.34 Å. In the thirteenth C site, C(88) is bonded in a distorted bent 120 degrees geometry to one C(75), one N(28), and one N(30) atom. The C(88)-N(28) bond length is 1.32 Å. The C(88)-N(30) bond length is 1.34 Å. In the fourteenth C site, C(89) is bonded in a distorted trigonal planar geometry to one C(80), one N(28), and one N(29) atom. The C(89)-N(28) bond length is 1.32 Å. The C(89)-N(29) bond length is 1.34 Å. In the fifteenth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(21) atom. The C(29)-N(9) bond length is 1.35 Å. The C(29)-H(21) bond length is 0.95 Å. In the sixteenth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(24) atom. The C(33)-N(9) bond length is 1.33 Å. The C(33)-H(24) bond length is 0.95 Å. There are five inequivalent N sites. In the first N site, N(9) is bonded in a trigonal planar geometry to one Zn(5), one C(29), and one C(33) atom. In the second N site, N(27) is bonded in a trigonal planar geometry to one Zn(5), one C(83), and one C(87) atom. In the third N site, N(28) is bonded in a bent 120 degrees geometry to one C(88) and one C(89) atom. In the fourth N site, N(29) is bonded in a bent 120 degrees geometry to one C(89) and one C(90) atom. In the fifth N site, N(30) is bonded in a bent 120 degrees geometry to one C(88) and one C(90) atom. There are nine inequivalent H sites. In the first H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the second H site, H(24) is bonded in a single-bond geometry to one C(33) atom. In the third H site, H(49,50) is bonded in a single-bond geometry to one C(74) atom. In the fourth H site, H(53) is bonded in a single-bond geometry to one C(79) atom. In the fifth H site, H(54) is bonded in a single-bond geometry to one C(81) atom. In the sixth H site, H(56) is bonded in a single-bond geometry to one C(83) atom. In the seventh H site, H(57) is bonded in a single-bond geometry to one C(84) atom. In the eighth H site, H(58) is bonded in a single-bond geometry to one C(86) atom. In the ninth H site, H(59) is bonded in a single-bond geometry to one C(87) atom. There are two inequivalent I sites. In the first I site, I(9) is bonded in a single-bond geometry to one Zn(5) atom. In the second I site, I(10) is bonded in a single-bond geometry to one Zn(5) atom. In each ZnC16N5H9I2 cluster, Zn(8) is bonded in a tetrahedral geometry to one N(21), one N(25), one I(15), and one I(16) atom. The Zn(8)-N(21) bond length is 2.07 Å. The Zn(8)-N(25) bond length is 2.06 Å. The Zn(8)-I(15) bond length is 2.56 Å. The Zn(8)-I(16) bond length is 2.55 Å. There are sixteen inequivalent C sites. In the first C site, C(56) is bonded in a single-bond geometry to one C(57) and one H(38) atom. The C(56)-C(57) bond length is 1.40 Å. The C(56)-H(38) bond length is 0.95 Å. In the second C site, C(57) is bonded in a trigonal planar geometry to one C(56), one C(58), and one C(70) atom. The C(57)-C(58) bond length is 1.39 Å. The C(57)-C(70) bond length is 1.48 Å. In the third C site, C(58) is bonded in a distorted single-bond geometry to one C(57) and one H(39) atom. The C(58)-H(39) bond length is 0.95 Å. In the fourth C site, C(61) is bonded in a distorted single-bond geometry to one C(62) and one H(42) atom. The C(61)-C(62) bond length is 1.40 Å. The C(61)-H(42) bond length is 0.95 Å. In the fifth C site, C(62) is bonded in a trigonal planar geometry to one C(61), one C(63), and one C(71) atom. The C(62)-C(63) bond length is 1.38 Å. The C(62)-C(71) bond length is 1.48 Å. In the sixth C site, C(63) is bonded in a single-bond geometry to one C(62) and one H(43) atom. The C(63)-H(43) bond length is 0.95 Å. In the seventh C site, C(65) is bonded in a distorted bent 120 degrees geometry to one C(66), one N(21), and one H(45) atom. The C(65)-C(66) bond length is 1.38 Å. The C(65)-N(21) bond length is 1.34 Å. The C(65)-H(45) bond length is 0.95 Å. In the eighth C site, C(66) is bonded in a distorted trigonal planar geometry to one C(65), one C(67), and one H(46) atom. The C(66)-C(67) bond length is 1.38 Å. The C(66)-H(46) bond length is 0.95 Å. In the ninth C site, C(67) is bonded in a trigonal planar geometry to one C(66), one C(68), and one C(72) atom. The C(67)-C(68) bond length is 1.39 Å. The C(67)-C(72) bond length is 1.48 Å. In the tenth C site, C(68) is bonded in a distorted single-bond geometry to one C(67), one C(69), and one H(47) atom. The C(68)-C(69) bond length is 1.39 Å. The C(68)-H(47) bond length is 0.95 Å. In the eleventh C site, C(69) is bonded in a distorted bent 120 degrees geometry to one C(68) and one N(21) atom. The C(69)-N(21) bond length is 1.34 Å. In the twelfth C site, C(70) is bonded in a distorted trigonal planar geometry to one C(57), one N(22), and one N(24) atom. The C(70)-N(22) bond length is 1.33 Å. The C(70)-N(24) bond length is 1.33 Å. In the thirteenth C site, C(71) is bonded in a distorted trigonal planar geometry to one C(62), one N(22), and one N(23) atom. The C(71)-N(22) bond length is 1.34 Å. The C(71)-N(23) bond length is 1.33 Å. In the fourteenth C site, C(72) is bonded in a distorted trigonal planar geometry to one C(67), one N(23), and one N(24) atom. The C(72)-N(23) bond length is 1.34 Å. The C(72)-N(24) bond length is 1.34 Å. In the fifteenth C site, C(73) is bonded in a distorted bent 120 degrees geometry to one N(25) and one H(48) atom. The C(73)-N(25) bond length is 1.34 Å. The C(73)-H(48) bond length is 0.95 Å. In the sixteenth C site, C(77) is bonded in a distorted bent 120 degrees geometry to one N(25) and one H(51) atom. The C(77)-N(25) bond length is 1.34 Å. The C(77)-H(51) bond length is 0.95 Å. There are five inequivalent N sites. In the first N site, N(21) is bonded in a trigonal planar geometry to one Zn(8), one C(65), and one C(69) atom. In the second N site, N(22) is bonded in a bent 120 degrees geometry to one C(70) and one C(71) atom. In the third N site, N(23) is bonded in a bent 120 degrees geometry to one C(71) and one C(72) atom. In the fourth N site, N(24) is bonded in a bent 120 degrees geometry to one C(70) and one C(72) atom. In the fifth N site, N(25) is bonded in a trigonal planar geometry to one Zn(8), one C(73), and one C(77) atom. There are nine inequivalent H sites. In the first H site, H(38) is bonded in a single-bond geometry to one C(56) atom. In the second H site, H(39) is bonded in a single-bond geometry to one C(58) atom. In the third H site, H(42) is bonded in a single-bond geometry to one C(61) atom. In the fourth H site, H(43) is bonded in a single-bond geometry to one C(63) atom. In the fifth H site, H(45) is bonded in a single-bond geometry to one C(65) atom. In the sixth H site, H(46) is bonded in a single-bond geometry to one C(66) atom. In the seventh H site, H(47) is bonded in a single-bond geometry to one C(68) atom. In the eighth H site, H(48) is bonded in a single-bond geometry to one C(73) atom. In the ninth H site, H(51) is bonded in a single-bond geometry to one C(77) atom. There are two inequivalent I sites. In the first I site, I(15) is bonded in a single-bond geometry to one Zn(8) atom. In the second I site, I(16) is bonded in a single-bond geometry to one Zn(8) atom. In each ZnC4H4(NI)2 cluster, Zn(7) is bonded in a distorted tetrahedral geometry to one N(20), one N(37), one I(13), and one I(14) atom. The Zn(7)-N(20) bond length is 2.07 Å. The Zn(7)-N(37) bond length is 2.07 Å. The Zn(7)-I(13) bond length is 2.52 Å. The Zn(7)-I(14) bond length is 2.55 Å. There are four inequivalent C sites. In the first C site, C(109) is bonded in a distorted bent 120 degrees geometry to one N(37) and one H(72) atom. The C(109)-N(37) bond length is 1.34 Å. The C(109)-H(72) bond length is 0.95 Å. In the second C site, C(113) is bonded in a distorted bent 120 degrees geometry to one N(37) and one H(75) atom. The C(113)-N(37) bond length is 1.34 Å. The C(113)-H(75) bond length is 0.95 Å. In the third C site, C(60) is bonded in a distorted bent 120 degrees geometry to one N(20) and one H(41) atom. The C(60)-N(20) bond length is 1.34 Å. The C(60)-H(41) bond length is 0.95 Å. In the fourth C site, C(64) is bonded in a distorted bent 120 degrees geometry to one N(20) and one H(44) atom. The C(64)-N(20) bond length is 1.34 Å. The C(64)-H(44) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(37) is bonded in a trigonal planar geometry to one Zn(7), one C(109), and one C(113) atom. In the second N site, N(20) is bonded in a trigonal planar geometry to one Zn(7), one C(60), and one C(64) atom. There are four inequivalent H sites. In the first H site, H(41) is bonded in a single-bond geometry to one C(60) atom. In the second H site, H(75) is bonded in a single-bond geometry to one C(113) atom. In the third H site, H(44) is bonded in a single-bond geometry to one C(64) atom. In the fourth H site, H(72) is bonded in a single-bond geometry to one C(109) atom. There are two inequivalent I sites. In the first I site, I(13) is bonded in a single-bond geometry to one Zn(7) atom. In the second I site, I(14) is bonded in a single-bond geometry to one Zn(7) atom. Linkers: 14 n1ccc(cc1)C1=NC(=[N]=C([N]1)c1ccncc1)c1ccncc1 ,2 N1=[C]C=C(C=C1)C1=NC(=[N]=C([N]1)c1ccncc1)c1ccncc1. Metal clusters: 24 I[Zn]I. The MOF has largest included sphere 10.28 A, density 1.28 g/cm3, surface area 3282.00 m2/g, accessible volume 0.45 cm3/g