Ce2C14H6S(NO6)2 crystallizes in the monoclinic C2/c space group. Ce(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Ce(1)-O(1) bond length is 2.49 Å. The Ce(1)-O(2) bond length is 2.49 Å. The Ce(1)-O(3) bond length is 2.36 Å. The Ce(1)-O(4) bond length is 2.42 Å. The Ce(1)-O(5) bond length is 2.51 Å. The Ce(1)-O(6) bond length is 2.61 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(3) bond length is 1.25 Å. The C(1)-O(4) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(6) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(1), and one H(2) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(7) bond length is 1.51 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.25 Å. The C(7)-O(2) bond length is 1.27 Å. N(1) is bonded in a bent 120 degrees geometry to one C(3) and one C(4) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. S(1) is bonded in a tetrahedral geometry to two equivalent O(5) and two equivalent O(6) atoms. Both S(1)-O(5) bond lengths are 1.47 Å. Both S(1)-O(6) bond lengths are 1.47 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Ce(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Ce(1) and one C(7) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Ce(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ce(1) and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Ce(1) and one S(1) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Ce(1) and one S(1) atom. Linkers: 8 [O]C(=O)c1cncc(C([O])=O)c1. Metal clusters: 8 [Ce]. The MOF has largest included sphere 4.42 A, density 1.96 g/cm3, surface area 2918.73 m2/g, accessible volume 0.16 cm3/g