CuC9H5O4Cu(OOCC6H4COO)(CH)7(C2O)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of fifty-six 02329_fluka molecules, sixteen dimethyl ether molecules, four Cu(OOCC6H4COO) clusters, and four CuC9H5O4 clusters. In each Cu(OOCC6H4COO) cluster, Cu(2) is bonded in a distorted rectangular see-saw-like geometry to one O(4), one O(5), one O(8), and one O(9) atom. The Cu(2)-O(4) bond length is 1.96 Å. The Cu(2)-O(5) bond length is 1.97 Å. The Cu(2)-O(8) bond length is 1.97 Å. The Cu(2)-O(9) bond length is 1.97 Å. There are eight inequivalent C sites. In the first C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(9) atom. The C(18)-C(19) bond length is 1.38 Å. The C(18)-H(9) bond length is 0.93 Å. In the second C site, C(20) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(25) atom. The C(20)-C(11) bond length is 1.40 Å. The C(20)-C(12) bond length is 1.49 Å. The C(20)-C(25) bond length is 1.39 Å. In the third C site, C(19) is bonded in a trigonal planar geometry to one C(13), one C(18), and one C(26) atom. The C(19)-C(13) bond length is 1.50 Å. The C(19)-C(26) bond length is 1.39 Å. In the fourth C site, C(25) is bonded in a distorted single-bond geometry to one C(20) and one H(14) atom. The C(25)-H(14) bond length is 0.93 Å. In the fifth C site, C(26) is bonded in a distorted single-bond geometry to one C(19) and one H(15) atom. The C(26)-H(15) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(20) and one H(6) atom. The C(11)-H(6) bond length is 0.93 Å. In the seventh C site, C(12) is bonded in a bent 120 degrees geometry to one C(20), one O(5), and one O(8) atom. The C(12)-O(5) bond length is 1.27 Å. The C(12)-O(8) bond length is 1.27 Å. In the eighth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(4), and one O(9) atom. The C(13)-O(4) bond length is 1.26 Å. The C(13)-O(9) bond length is 1.27 Å. There are four inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the third H site, H(14) is bonded in a single-bond geometry to one C(25) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(26) atom. There are four inequivalent O sites. In the first O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(13) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(13) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(12) atom. In the fourth O site, O(8) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(12) atom. In each CuC9H5O4 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(6), and one O(7) atom. The Cu(1)-O(1) bond length is 1.93 Å. The Cu(1)-O(2) bond length is 2.00 Å. The Cu(1)-O(6) bond length is 1.93 Å. The Cu(1)-O(7) bond length is 1.99 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(5) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(5) bond length is 1.37 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(3) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(3) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the sixth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(6), and one O(7) atom. The C(10)-C(14) bond length is 1.49 Å. The C(10)-O(6) bond length is 1.27 Å. The C(10)-O(7) bond length is 1.26 Å. In the seventh C site, C(14) is bonded in a trigonal planar geometry to one C(10), one C(21), and one C(22) atom. The C(14)-C(21) bond length is 1.40 Å. The C(14)-C(22) bond length is 1.39 Å. In the eighth C site, C(21) is bonded in a distorted single-bond geometry to one C(14) and one H(10) atom. The C(21)-H(10) bond length is 0.93 Å. In the ninth C site, C(22) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(22)-H(11) bond length is 0.93 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(22) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(21) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(10) atom. In the fourth O site, O(7) is bonded in a distorted single-bond geometry to one Cu(1) and one C(10) atom. Linkers: 8 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: pts. The MOF has largest included sphere 7.81 A, density 0.97 g/cm3, surface area 4106.38 m2/g, accessible volume 0.50 cm3/g