CdH16(C4N)4(CH)23CdC19H14(N2F)2(CF)14 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of seven 02329_fluka molecules, fourteen fluoromethane molecules, four isobutylene molecules, one CdC19H14(N2F)2 cluster, and one CdH16(C4N)4 cluster. In the CdC19H14(N2F)2 cluster, Cd(2) is bonded in a square co-planar geometry to one N(6); one N(8); and two equivalent N(5,7) atoms. The Cd(2)-N(6) bond length is 2.39 Å. The Cd(2)-N(8) bond length is 2.39 Å. Both Cd(2)-N(5,7) bond lengths are 2.37 Å. There are sixteen inequivalent C sites. In the first C site, C(1,37,55) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,29,37) atom. The C(1,37,55)-N(1) bond length is 1.37 Å. The C(1,37,55)-H(1,29,37) bond length is 1.14 Å. In the second C site, C(2,38,56) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2,30,38) atom. The C(2,38,56)-N(1) bond length is 1.36 Å. The C(2,38,56)-H(2,30,38) bond length is 1.14 Å. In the third C site, C(10,28,64) is bonded in a distorted bent 120 degrees geometry to one C(12,30,66); one N(2); and one H(8,22,44) atom. The C(10,28,64)-C(12,30,66) bond length is 1.42 Å. The C(10,28,64)-N(2) bond length is 1.34 Å. The C(10,28,64)-H(8,22,44) bond length is 1.14 Å. In the fourth C site, C(11,29,47,65) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9,23,34,45) atom. The C(11,29,47,65)-N(2) bond length is 1.36 Å. The C(11,29,47,65)-H(9,23,34,45) bond length is 1.14 Å. In the fifth C site, C(12,30,66) is bonded in a distorted trigonal planar geometry to one C(10,28,64); one C(14,32,68); and one H(10,24,46) atom. The C(12,30,66)-C(14,32,68) bond length is 1.44 Å. The C(12,30,66)-H(10,24,46) bond length is 1.14 Å. In the sixth C site, C(13,31,67) is bonded in a distorted single-bond geometry to one C(14,32,68) and one H(11,25,47) atom. The C(13,31,67)-C(14,32,68) bond length is 1.37 Å. The C(13,31,67)-H(11,25,47) bond length is 1.14 Å. In the seventh C site, C(14,32,68) is bonded in a trigonal planar geometry to one C(12,30,66); one C(13,31,67); and one C(15,33,69) atom. The C(14,32,68)-C(15,33,69) bond length is 1.55 Å. In the eighth C site, C(15,33,69) is bonded in a distorted water-like geometry to one C(14,32,68) and two equivalent H(12,13,26,27,48,49) atoms. Both C(15,33,69)-H(12,13,26,27,48,49) bond lengths are 1.14 Å. In the ninth C site, C(18) is bonded in a distorted single-bond geometry to one C(52) and one F(4) atom. The C(18)-C(52) bond length is 1.41 Å. The C(18)-F(4) bond length is 1.36 Å. In the tenth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one C(48), one N(6), and one H(33) atom. The C(46)-C(48) bond length is 1.42 Å. The C(46)-N(6) bond length is 1.34 Å. The C(46)-H(33) bond length is 1.14 Å. In the eleventh C site, C(48) is bonded in a distorted trigonal planar geometry to one C(46), one C(50), and one H(35) atom. The C(48)-C(50) bond length is 1.44 Å. The C(48)-H(35) bond length is 1.14 Å. In the twelfth C site, C(49) is bonded in a distorted single-bond geometry to one C(50) and one H(36) atom. The C(49)-C(50) bond length is 1.37 Å. The C(49)-H(36) bond length is 1.14 Å. In the thirteenth C site, C(50) is bonded in a trigonal planar geometry to one C(48), one C(49), and one C(51) atom. The C(50)-C(51) bond length is 1.55 Å. In the fourteenth C site, C(51) is bonded in a water-like geometry to one C(50) and one C(52) atom. The C(51)-C(52) bond length is 1.54 Å. In the fifteenth C site, C(52) is bonded in a trigonal planar geometry to one C(18), one C(51), and one C(53) atom. The C(52)-C(53) bond length is 1.41 Å. In the sixteenth C site, C(53) is bonded in a distorted single-bond geometry to one C(52) and one F(11) atom. The C(53)-F(11) bond length is 1.36 Å. There are three inequivalent N sites. In the first N site, N(5,7) is bonded in a trigonal planar geometry to one Cd(2); one C(1,37,55); and one C(2,38,56) atom. The N(5,7)-C(1,37,55) bond length is 1.37 Å. The N(5,7)-C(2,38,56) bond length is 1.36 Å. In the second N site, N(6) is bonded in a trigonal planar geometry to one Cd(2); one C(11,29,47,65); and one C(46) atom. The N(6)-C(11,29,47,65) bond length is 1.36 Å. In the third N site, N(8) is bonded in a trigonal planar geometry to one Cd(2); one C(10,28,64); and one C(11,29,47,65) atom. The N(8)-C(10,28,64) bond length is 1.34 Å. The N(8)-C(11,29,47,65) bond length is 1.36 Å. There are ten inequivalent H sites. In the first H site, H(1,29,37) is bonded in a single-bond geometry to one C(1,37,55) atom. In the second H site, H(2,30,38) is bonded in a single-bond geometry to one C(2,38,56) atom. In the third H site, H(8,22,44) is bonded in a single-bond geometry to one C(10,28,64) atom. In the fourth H site, H(9,23,34,45) is bonded in a single-bond geometry to one C(11,29,47,65) atom. In the fifth H site, H(10,24,46) is bonded in a single-bond geometry to one C(12,30,66) atom. In the sixth H site, H(11,25,47) is bonded in a single-bond geometry to one C(13,31,67) atom. In the seventh H site, H(12,13,26,27,48,49) is bonded in a single-bond geometry to one C(15,33,69) atom. In the eighth H site, H(33) is bonded in a single-bond geometry to one C(46) atom. In the ninth H site, H(35) is bonded in a single-bond geometry to one C(48) atom. In the tenth H site, H(36) is bonded in a single-bond geometry to one C(49) atom. There are two inequivalent F sites. In the first F site, F(4) is bonded in a single-bond geometry to one C(18) atom. In the second F site, F(11) is bonded in a single-bond geometry to one C(53) atom. In the CdH16(C4N)4 cluster, Cd(1) is bonded in a square co-planar geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Cd(1)-N(1) bond length is 2.37 Å. The Cd(1)-N(2) bond length is 2.39 Å. The Cd(1)-N(3) bond length is 2.37 Å. The Cd(1)-N(4) bond length is 2.39 Å. There are ten inequivalent C sites. In the first C site, C(1,37,55) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,29,37) atom. In the second C site, C(2,38,56) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2,30,38) atom. In the third C site, C(10,28,64) is bonded in a distorted bent 120 degrees geometry to one C(12,30,66); one N(2); and one H(8,22,44) atom. In the fourth C site, C(11,29,47,65) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9,23,34,45) atom. In the fifth C site, C(12,30,66) is bonded in a distorted trigonal planar geometry to one C(10,28,64); one C(14,32,68); and one H(10,24,46) atom. In the sixth C site, C(13,31,67) is bonded in a distorted single-bond geometry to one C(14,32,68) and one H(11,25,47) atom. In the seventh C site, C(14,32,68) is bonded in a trigonal planar geometry to one C(12,30,66); one C(13,31,67); and one C(15,33,69) atom. In the eighth C site, C(15,33,69) is bonded in a distorted water-like geometry to one C(14,32,68) and two equivalent H(12,13,26,27,48,49) atoms. In the ninth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(15) atom. The C(19)-N(3) bond length is 1.37 Å. The C(19)-H(15) bond length is 1.14 Å. In the tenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(16) atom. The C(20)-N(3) bond length is 1.36 Å. The C(20)-H(16) bond length is 1.14 Å. There are four inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(19), and one C(20) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cd(1); one C(10,28,64); and one C(11,29,47,65) atom. The N(4)-C(10,28,64) bond length is 1.34 Å. The N(4)-C(11,29,47,65) bond length is 1.36 Å. In the third N site, N(2) is bonded in a trigonal planar geometry to one Cd(1); one C(10,28,64); and one C(11,29,47,65) atom. In the fourth N site, N(1) is bonded in a trigonal planar geometry to one Cd(1); one C(1,37,55); and one C(2,38,56) atom. There are nine inequivalent H sites. In the first H site, H(1,29,37) is bonded in a single-bond geometry to one C(1,37,55) atom. In the second H site, H(2,30,38) is bonded in a single-bond geometry to one C(2,38,56) atom. In the third H site, H(8,22,44) is bonded in a single-bond geometry to one C(10,28,64) atom. In the fourth H site, H(9,23,34,45) is bonded in a single-bond geometry to one C(11,29,47,65) atom. In the fifth H site, H(10,24,46) is bonded in a single-bond geometry to one C(12,30,66) atom. In the sixth H site, H(11,25,47) is bonded in a single-bond geometry to one C(13,31,67) atom. In the seventh H site, H(12,13,26,27,48,49) is bonded in a single-bond geometry to one C(15,33,69) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. Linkers: 1 FC1=C(F)C(Cc2ccncc2)C(F)=C(F)[C]1[C]c1ccncc1 ,1 FC1=C(F)C(Cc2c[c]ncc2)C(F)=C(F)[C]1[C]c1ccncc1 ,2 FC1=C(F)[C@H](Cc2ccncc2)C(F)=C(F)[C@H]1Cc1c[c]ncc1 ,3 FC1=C(F)[C@H](Cc2ccncc2)C(F)=C(F)[C@H]1Cc1ccncc1 ,1 FC1=C(F)C(Cc2ccncc2)C(F)=C(F)[C]1[C]c1c[c]ncc1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 4.99 A, density 1.05 g/cm3, surface area 4937.61 m2/g, accessible volume 0.50 cm3/g