Cu4C8N32Cl(C13N2)8 is Indium-derived structured and crystallizes in the cubic Im-3m space group. The structure is zero-dimensional and consists of sixteen C13N2 clusters and six Cu4C8N32Cl clusters. In each C13N2 cluster, there are nine inequivalent C sites. In the first C site, C(3) is bonded in a distorted T-shaped geometry to one C(1), one C(4), and one C(8) atom. The C(3)-C(1) bond length is 1.39 Å. The C(3)-C(4) bond length is 1.24 Å. The C(3)-C(8) bond length is 1.34 Å. In the second C site, C(4) is bonded in a 4-coordinate geometry to one C(2), one C(3), one C(8), and one C(9) atom. The C(4)-C(2) bond length is 1.50 Å. The C(4)-C(8) bond length is 1.73 Å. The C(4)-C(9) bond length is 1.38 Å. In the third C site, C(1) is bonded in a distorted T-shaped geometry to one C(2), one C(3), and one C(6) atom. The C(1)-C(2) bond length is 1.13 Å. The C(1)-C(6) bond length is 1.35 Å. In the fourth C site, C(6) is bonded in a single-bond geometry to one C(7) and two equivalent C(1) atoms. The C(6)-C(7) bond length is 0.91 Å. In the fifth C site, C(7) is bonded in a single-bond geometry to one C(6) and two equivalent C(2) atoms. Both C(7)-C(2) bond lengths are 1.34 Å. In the sixth C site, C(8) is bonded in a distorted trigonal pyramidal geometry to one C(10), one C(9), two equivalent C(3), and two equivalent C(4) atoms. The C(8)-C(10) bond length is 1.53 Å. The C(8)-C(9) bond length is 1.53 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and two equivalent C(4) atoms. In the eighth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(8), two equivalent N(3), and two equivalent N(4) atoms. Both C(10)-N(3) bond lengths are 1.39 Å. Both C(10)-N(4) bond lengths are 1.93 Å. In the ninth C site, C(2) is bonded in a 3-coordinate geometry to one C(1), one C(4), and one C(7) atom. There are two inequivalent N sites. In the first N site, N(3) is bonded in a distorted bent 120 degrees geometry to two equivalent C(10) and one N(4) atom. The N(3)-N(4) bond length is 1.33 Å. In the second N site, N(4) is bonded in a 3-coordinate geometry to two equivalent C(10) and one N(3) atom. In each Cu4C8N32Cl cluster, Cu(1) is bonded to four equivalent N(1) and one Cl(1) atom to form corner-sharing CuN4Cl square pyramids. All Cu(1)-N(1) bond lengths are 2.04 Å. The Cu(1)-Cl(1) bond length is 2.55 Å. C(5) is bonded in a distorted bent 120 degrees geometry to two equivalent N(2) atoms. Both C(5)-N(2) bond lengths are 1.37 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one N(1), and one N(2) atom. The N(1)-N(1) bond length is 1.37 Å. The N(1)-N(2) bond length is 1.27 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(5) and one N(1) atom. Cl(1) is bonded in a square co-planar geometry to four equivalent Cu(1) atoms. Linkers: 7 [N]N1[C]([C@]23[C]4[C]5[C]2[C]2[C]5[C@@]5(C6=N[N]N=N6)[C]6[C]4[C]3[C]6[C]25)N([N])[C]([C@]23[C]4[C]5[C]2[C]2[C]5[C@@]5(C6=N[N]N=N6)[C]6[C]4[C]3[C]6[C]25)N([N])[C]1[C@]12[C]3[C]4[C]1[C]1[C]4[C@@]4(C5=N[N]N=N5)[C]5[C]3[C]2[C]5[C]14 ,6 [N]N1[C]([C@]23[C]4[C]5[C]2[C]2[C]5[C@@]5(C6=NN=N[N]6)[C]6[C]4[C]3[C]6[C]25)N([N])[C]([C@]23[C]4[C]5[C]2[C]2[C]5[C@@]5(C6=N[N]N=N6)[C]6[C]4[C]3[C]6[C]25)N([N])[C]1[C@]12[C]3[C]4[C]1[C]1[C]4[C@@]4(C5=N[N]N=N5)[C]5[C]3[C]2[C]5[C]14 ,3 [N]N1[C]([C@]23[C]4[C]5[C]2[C]2[C]5[C@@]5(C6=NN=N[N]6)[C]6[C]4[C]3[C]6[C]25)N([N])[C]([C@]23[C]4[C]5[C]2[C]2[C]5[C@@]5(C6=N[N]N=N6)[C]6[C]4[C]3[C]6[C]25)N([N])[C]1[C@]12[C]3[C]4[C]1[C]1[C]4[C@@]4(C5=NN=N[N]5)[C]5[C]3[C]2[C]5[C]14. Metal clusters: 4 Cl[Cu]123N=N[Cu@]4(=N[N][Cu@]5(=NN=[Cu@@](N=N5)(N=N1)N=N2)N=N4)N=N3 ,2 Cl[Cu]123N=N[Cu@]4(=N[N][Cu@@]5(=NN=[Cu@@](N=N5)(N=N1)N=N2)N=N4)N=N3. The MOF has largest included sphere 15.32 A, density 0.99 g/cm3, surface area 3118.55 m2/g, accessible volume 0.61 cm3/g