NaCo3C30H18(NO)12(CH)6 is Indium-derived structured and crystallizes in the hexagonal P6_3 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and two NaCo3C30H18(NO)12 clusters. In each NaCo3C30H18(NO)12 cluster, Na(1) is bonded in an octahedral geometry to three equivalent O(2) and three equivalent O(4) atoms. All Na(1)-O(2) bond lengths are 2.38 Å. All Na(1)-O(4) bond lengths are 2.37 Å. Co(1) is bonded in a 5-coordinate geometry to one N(3), one N(4), one O(1), one O(2), and one O(4) atom. The Co(1)-N(3) bond length is 2.01 Å. The Co(1)-N(4) bond length is 2.03 Å. The Co(1)-O(1) bond length is 2.34 Å. The Co(1)-O(2) bond length is 2.02 Å. The Co(1)-O(4) bond length is 2.04 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one O(2) and one O(3) atom. The C(1)-O(2) bond length is 1.27 Å. The C(1)-O(3) bond length is 1.22 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(3)-O(1) bond length is 1.25 Å. The C(3)-O(4) bond length is 1.29 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(4), and one H(2) atom. The C(4)-C(6) bond length is 1.37 Å. The C(4)-N(4) bond length is 1.35 Å. The C(4)-H(2) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(5)-C(6) bond length is 1.48 Å. The C(5)-H(3) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(4), one C(5), and one N(1) atom. The C(6)-N(1) bond length is 1.32 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(8)-C(9) bond length is 1.46 Å. The C(8)-H(5) bond length is 0.93 Å. In the seventh C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(2) atom. The C(9)-C(10) bond length is 1.35 Å. The C(9)-N(2) bond length is 1.38 Å. In the eighth C site, C(10) is bonded in a 2-coordinate geometry to one C(9), one N(3), and one H(6) atom. The C(10)-N(3) bond length is 1.38 Å. The C(10)-H(6) bond length is 0.93 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(7) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-N(3) bond length is 1.32 Å. The C(11)-H(7) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one N(1), one N(4), and one H(8) atom. The C(12)-N(1) bond length is 1.30 Å. The C(12)-N(4) bond length is 1.31 Å. The C(12)-H(8) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(2) is bonded in a water-like geometry to one C(11) and one C(9) atom. In the second N site, N(1) is bonded in a water-like geometry to one C(12) and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(10), and one C(11) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Co(1), one C(12), and one C(4) atom. There are six inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Co(1) and one C(3) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Na(1), one Co(1), and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Na(1), one Co(1), and one C(3) atom. Linkers: 1 [O]C(=O)/C=C/C1=NC=N[CH]1 ,11 [O]C(=O)/C=C/C1=C[N]C=N1. Metal clusters: 2 O=[C]O[Co]1O[C]O1.O=[C]O[Co]1O[C]O1.O=[C]O[Co]1O[C]O1.[Na]. The MOF has largest included sphere 5.85 A, density 1.41 g/cm3, surface area 4130.22 m2/g, accessible volume 0.33 cm3/g