Zn8C24H12O25(C9H6N)2 is Indium-derived structured and crystallizes in the cubic Ia-3 space group. The structure is zero-dimensional and consists of sixteen schembl1705614 molecules and eight Zn8C24H12O25 clusters. In each Zn8C24H12O25 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(4), and one O(5) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(2) bond length is 1.89 Å. The Zn(1)-O(3) bond length is 1.97 Å. The Zn(1)-O(4) bond length is 1.94 Å. The Zn(1)-O(5) bond length is 1.97 Å. In the second Zn site, Zn(2) is bonded to one O(5) and three equivalent O(1) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(5) bond length is 1.80 Å. All Zn(2)-O(1) bond lengths are 1.98 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-C(6) bond length is 1.38 Å. The C(1)-C(7) bond length is 1.49 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.95 Å. In the third C site, C(7) is bonded in a 5-coordinate geometry to one C(1), one O(1), one O(2), one O(3), and one O(4) atom. The C(7)-O(1) bond length is 1.22 Å. The C(7)-O(2) bond length is 1.22 Å. The C(7)-O(3) bond length is 1.34 Å. The C(7)-O(4) bond length is 1.28 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.95 Å. There are two inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(2) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Zn(2), one C(7), and one O(2) atom. The O(1)-O(2) bond length is 0.90 Å. In the second O site, O(3) is bonded in a 3-coordinate geometry to one Zn(1), one C(7), and one O(4) atom. The O(3)-O(4) bond length is 0.93 Å. In the third O site, O(4) is bonded in a 3-coordinate geometry to one Zn(1), one C(7), and one O(3) atom. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to one Zn(1), one C(7), and one O(1) atom. In the fifth O site, O(5) is bonded in a body-centered cubic geometry to two equivalent Zn(2) and six equivalent Zn(1) atoms. Linkers: 16 O=O.O=O.O=O.[C]O[O].[C]O[O].[C]O[O].[c]1ccc(N(c2cc[c]cc2)c2cc[c]cc2)cc1. Metal clusters: 4 O1O[Zn]2OO[Zn@@]34OO[Zn@]56OO[Zn@@]78OO[Zn@]9%10OO[Zn]1OO[Zn]73(OO8)(OO4)O[Zn]59(OO2)(OO6)OO%10 ,3 O1O[Zn]2OO[Zn@]34OO[Zn@@]56OO[Zn@]78OO[Zn@@]9%10OO[Zn]1OO[Zn]73(OO8)(OO4)O[Zn]59(OO2)(OO6)OO%10 ,1 O1O[Zn@@]23OO[Zn@]45OO[Zn]6OO[Zn@]78OO[Zn@@]9%10OO[Zn]1OO[Zn]47(OO5)(OO8)O[Zn]29(OO6)(OO3)OO%10. The MOF has largest included sphere 5.29 A, density 1.77 g/cm3, surface area 2616.52 m2/g, accessible volume 0.31 cm3/g