Zn6H59(C2N)24 crystallizes in the triclinic P1 space group. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(22), one N(24), and one N(3) atom. The Zn(1)-N(1) bond length is 1.99 Å. The Zn(1)-N(22) bond length is 1.99 Å. The Zn(1)-N(24) bond length is 1.99 Å. The Zn(1)-N(3) bond length is 1.99 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one N(2), one N(21), one N(23), and one N(4) atom. The Zn(2)-N(2) bond length is 1.99 Å. The Zn(2)-N(21) bond length is 1.99 Å. The Zn(2)-N(23) bond length is 1.99 Å. The Zn(2)-N(4) bond length is 1.99 Å. In the third Zn site, Zn(3) is bonded in a tetrahedral geometry to one N(18), one N(20), one N(5), and one N(7) atom. The Zn(3)-N(18) bond length is 1.99 Å. The Zn(3)-N(20) bond length is 1.99 Å. The Zn(3)-N(5) bond length is 1.99 Å. The Zn(3)-N(7) bond length is 1.99 Å. In the fourth Zn site, Zn(4) is bonded in a tetrahedral geometry to one N(17), one N(19), one N(6), and one N(8) atom. The Zn(4)-N(17) bond length is 1.99 Å. The Zn(4)-N(19) bond length is 1.99 Å. The Zn(4)-N(6) bond length is 1.99 Å. The Zn(4)-N(8) bond length is 1.99 Å. In the fifth Zn site, Zn(5) is bonded in a tetrahedral geometry to one N(10,16); one N(11); one N(12,14); and one N(9) atom. The Zn(5)-N(10,16) bond length is 1.99 Å. The Zn(5)-N(11) bond length is 1.99 Å. The Zn(5)-N(12,14) bond length is 1.99 Å. The Zn(5)-N(9) bond length is 1.99 Å. In the sixth Zn site, Zn(6) is bonded in a tetrahedral geometry to one N(10,16); one N(12,14); one N(13); and one N(15) atom. The Zn(6)-N(10,16) bond length is 1.99 Å. The Zn(6)-N(12,14) bond length is 1.99 Å. The Zn(6)-N(13) bond length is 1.99 Å. The Zn(6)-N(15) bond length is 1.99 Å. There are thirty-four inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-H(1) bond length is 1.14 Å. In the second C site, C(2,19) is bonded in a 2-coordinate geometry to one N(2) and one H(2) atom. The C(2,19)-N(2) bond length is 1.37 Å. The C(2,19)-H(2) bond length is 1.14 Å. In the third C site, C(3,18) is bonded in a 2-coordinate geometry to one N(3) and one H(3,6,11,13) atom. The C(3,18)-N(3) bond length is 1.37 Å. The C(3,18)-H(3,6,11,13) bond length is 1.14 Å. In the fourth C site, C(4) is bonded in a 2-coordinate geometry to one N(4) and one H(4) atom. The C(4)-N(4) bond length is 1.37 Å. The C(4)-H(4) bond length is 1.14 Å. In the fifth C site, C(5,22) is bonded in a 2-coordinate geometry to one N(5) and one H(5) atom. The C(5,22)-N(5) bond length is 1.37 Å. The C(5,22)-H(5) bond length is 1.14 Å. In the sixth C site, C(6,9,15,21) is bonded in a 2-coordinate geometry to one N(6) and one H(3,6,11,13) atom. The C(6,9,15,21)-N(6) bond length is 1.37 Å. The C(6,9,15,21)-H(3,6,11,13) bond length is 1.14 Å. In the seventh C site, C(7) is bonded in a 2-coordinate geometry to one N(7) and one H(7) atom. The C(7)-N(7) bond length is 1.37 Å. The C(7)-H(7) bond length is 1.14 Å. In the eighth C site, C(8,10,16,23) is bonded in a 2-coordinate geometry to one N(8) and one H(8,23) atom. The C(8,10,16,23)-N(8) bond length is 1.37 Å. The C(8,10,16,23)-H(8,23) bond length is 1.14 Å. In the ninth C site, C(11,13) is bonded in a 2-coordinate geometry to one N(11) and one H(3,6,11,13) atom. The C(11,13)-N(11) bond length is 1.37 Å. The C(11,13)-H(3,6,11,13) bond length is 1.14 Å. In the tenth C site, C(12,14) is bonded in a 2-coordinate geometry to one N(12,14) and one H(12,14,18,19,21) atom. The C(12,14)-N(12,14) bond length is 1.37 Å. The C(12,14)-H(12,14,18,19,21) bond length is 1.14 Å. In the eleventh C site, C(17) is bonded in a 2-coordinate geometry to one N(17) and one H(17) atom. The C(17)-N(17) bond length is 1.37 Å. The C(17)-H(17) bond length is 1.14 Å. In the twelfth C site, C(20) is bonded in a 2-coordinate geometry to one N(20) and one H(20) atom. The C(20)-N(20) bond length is 1.37 Å. The C(20)-H(20) bond length is 1.14 Å. In the thirteenth C site, C(24) is bonded in a distorted single-bond geometry to one N(24) atom. The C(24)-N(24) bond length is 1.37 Å. In the fourteenth C site, C(25) is bonded in a distorted trigonal non-coplanar geometry to one C(26) and three equivalent H(24,25,26) atoms. The C(25)-C(26) bond length is 1.49 Å. All C(25)-H(24,25,26) bond lengths are 1.14 Å. In the fifteenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one N(1), and one N(17) atom. The C(26)-N(1) bond length is 1.34 Å. The C(26)-N(17) bond length is 1.34 Å. In the sixteenth C site, C(27) is bonded in a distorted trigonal non-coplanar geometry to one C(28) and three equivalent H(27,28,29) atoms. The C(27)-C(28) bond length is 1.49 Å. All C(27)-H(27,28,29) bond lengths are 1.14 Å. In the seventeenth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one N(19), and one N(2) atom. The C(28)-N(19) bond length is 1.34 Å. The C(28)-N(2) bond length is 1.34 Å. In the eighteenth C site, C(29) is bonded in a distorted trigonal non-coplanar geometry to one C(30) and three equivalent H(30,31,32) atoms. The C(29)-C(30) bond length is 1.49 Å. All C(29)-H(30,31,32) bond lengths are 1.14 Å. In the nineteenth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one N(18), and one N(3) atom. The C(30)-N(18) bond length is 1.34 Å. The C(30)-N(3) bond length is 1.34 Å. In the twentieth C site, C(31) is bonded in a distorted trigonal non-coplanar geometry to one C(32) and three equivalent H(33,34,35) atoms. The C(31)-C(32) bond length is 1.49 Å. All C(31)-H(33,34,35) bond lengths are 1.14 Å. In the twenty-first C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31), one N(20), and one N(4) atom. The C(32)-N(20) bond length is 1.34 Å. The C(32)-N(4) bond length is 1.34 Å. In the twenty-second C site, C(33) is bonded in a distorted trigonal non-coplanar geometry to one C(34,46) and three equivalent H(36,37,38,54,55,56) atoms. The C(33)-C(34,46) bond length is 1.49 Å. All C(33)-H(36,37,38,54,55,56) bond lengths are 1.14 Å. In the twenty-third C site, C(34,46) is bonded in a distorted trigonal planar geometry to one C(33), one N(13), and one N(5) atom. The C(34,46)-N(13) bond length is 1.34 Å. The C(34,46)-N(5) bond length is 1.34 Å. In the twenty-fourth C site, C(35) is bonded in a distorted trigonal non-coplanar geometry to one C(36,42) and three equivalent H(39,40,41,48,49,50) atoms. The C(35)-C(36,42) bond length is 1.49 Å. All C(35)-H(39,40,41,48,49,50) bond lengths are 1.14 Å. In the twenty-fifth C site, C(36,42) is bonded in a distorted trigonal planar geometry to one C(35), one N(15), and one N(6) atom. The C(36,42)-N(15) bond length is 1.34 Å. The C(36,42)-N(6) bond length is 1.34 Å. In the twenty-sixth C site, C(37) is bonded in a distorted trigonal non-coplanar geometry to one C(38) and three equivalent H(42,43,44,57,58,59) atoms. The C(37)-C(38) bond length is 1.49 Å. All C(37)-H(42,43,44,57,58,59) bond lengths are 1.14 Å. In the twenty-seventh C site, C(38) is bonded in a distorted trigonal planar geometry to one C(37); one N(12,14); and one N(7) atom. The C(38)-N(12,14) bond length is 1.34 Å. The C(38)-N(7) bond length is 1.34 Å. In the twenty-eighth C site, C(39) is bonded in a distorted trigonal non-coplanar geometry to one C(40,44) and three equivalent H(45,46,47,51,52,53) atoms. The C(39)-C(40,44) bond length is 1.49 Å. All C(39)-H(45,46,47,51,52,53) bond lengths are 1.14 Å. In the twenty-ninth C site, C(40,44) is bonded in a distorted trigonal planar geometry to one C(39); one N(10,16); and one N(8) atom. The C(40,44)-N(10,16) bond length is 1.34 Å. The C(40,44)-N(8) bond length is 1.34 Å. In the thirtieth C site, C(41) is bonded in a distorted trigonal non-coplanar geometry to one C(36,42) and three equivalent H(39,40,41,48,49,50) atoms. The C(41)-C(36,42) bond length is 1.49 Å. All C(41)-H(39,40,41,48,49,50) bond lengths are 1.14 Å. In the thirty-first C site, C(43) is bonded in a distorted trigonal non-coplanar geometry to one C(40,44) and three equivalent H(45,46,47,51,52,53) atoms. The C(43)-C(40,44) bond length is 1.49 Å. All C(43)-H(45,46,47,51,52,53) bond lengths are 1.14 Å. In the thirty-second C site, C(45) is bonded in a distorted trigonal non-coplanar geometry to one C(34,46) and three equivalent H(36,37,38,54,55,56) atoms. The C(45)-C(34,46) bond length is 1.49 Å. All C(45)-H(36,37,38,54,55,56) bond lengths are 1.14 Å. In the thirty-third C site, C(47) is bonded in a distorted trigonal non-coplanar geometry to one C(48) and three equivalent H(42,43,44,57,58,59) atoms. The C(47)-C(48) bond length is 1.49 Å. All C(47)-H(42,43,44,57,58,59) bond lengths are 1.14 Å. In the thirty-fourth C site, C(48) is bonded in a distorted trigonal planar geometry to one C(47); one N(12,14); and one N(24) atom. The C(48)-N(12,14) bond length is 1.34 Å. The C(48)-N(24) bond length is 1.34 Å. There are twenty-two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(26) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2); one C(2,19); and one C(28) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1); one C(3,18); and one C(30) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(2), one C(32), and one C(4) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(3); one C(34,46); and one C(5,22) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(4); one C(36,42); and one C(6,9,15,21) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Zn(3), one C(38), and one C(7) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Zn(4); one C(40,44); and one C(8,10,16,23) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Zn(5); one C(36,42); and one C(6,9,15,21) atom. The N(9)-C(36,42) bond length is 1.34 Å. The N(9)-C(6,9,15,21) bond length is 1.37 Å. In the tenth N site, N(10,16) is bonded in a trigonal planar geometry to one Zn(6); one C(40,44); and one C(8,10,16,23) atom. The N(10,16)-C(8,10,16,23) bond length is 1.37 Å. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Zn(5); one C(11,13); and one C(34,46) atom. The N(11)-C(34,46) bond length is 1.34 Å. In the twelfth N site, N(12,14) is bonded in a trigonal planar geometry to one Zn(6); one C(12,14); and one C(48) atom. In the thirteenth N site, N(13) is bonded in a trigonal planar geometry to one Zn(6); one C(11,13); and one C(34,46) atom. The N(13)-C(11,13) bond length is 1.37 Å. In the fourteenth N site, N(15) is bonded in a trigonal planar geometry to one Zn(6); one C(36,42); and one C(6,9,15,21) atom. The N(15)-C(6,9,15,21) bond length is 1.37 Å. In the fifteenth N site, N(17) is bonded in a trigonal planar geometry to one Zn(4), one C(17), and one C(26) atom. In the sixteenth N site, N(18) is bonded in a trigonal planar geometry to one Zn(3); one C(3,18); and one C(30) atom. The N(18)-C(3,18) bond length is 1.37 Å. In the seventeenth N site, N(19) is bonded in a trigonal planar geometry to one Zn(4); one C(2,19); and one C(28) atom. The N(19)-C(2,19) bond length is 1.37 Å. In the eighteenth N site, N(20) is bonded in a trigonal planar geometry to one Zn(3), one C(20), and one C(32) atom. In the nineteenth N site, N(21) is bonded in a trigonal planar geometry to one Zn(2); one C(36,42); and one C(6,9,15,21) atom. The N(21)-C(36,42) bond length is 1.34 Å. The N(21)-C(6,9,15,21) bond length is 1.37 Å. In the twentieth N site, N(22) is bonded in a trigonal planar geometry to one Zn(1); one C(34,46); and one C(5,22) atom. The N(22)-C(34,46) bond length is 1.34 Å. The N(22)-C(5,22) bond length is 1.37 Å. In the twenty-first N site, N(23) is bonded in a trigonal planar geometry to one Zn(2); one C(40,44); and one C(8,10,16,23) atom. The N(23)-C(40,44) bond length is 1.34 Å. The N(23)-C(8,10,16,23) bond length is 1.37 Å. In the twenty-second N site, N(24) is bonded in a trigonal planar geometry to one Zn(1), one C(24), and one C(48) atom. There are twenty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2,19) atom. In the third H site, H(3,6,11,13) is bonded in a single-bond geometry to one C(3,18) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5,22) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8,23) is bonded in a single-bond geometry to one C(8,10,16,23) atom. In the eighth H site, H(9,15) is bonded in a single-bond geometry to one C(6,9,15,21) atom. The H(9,15)-C(6,9,15,21) bond length is 1.14 Å. In the ninth H site, H(10,16) is bonded in a single-bond geometry to one C(8,10,16,23) atom. The H(10,16)-C(8,10,16,23) bond length is 1.14 Å. In the tenth H site, H(12,14,18,19,21) is bonded in a single-bond geometry to one C(12,14) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(5,22) atom. The H(22)-C(5,22) bond length is 1.14 Å. In the fourteenth H site, H(24,25,26) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(27,28,29) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(30,31,32) is bonded in a single-bond geometry to one C(29) atom. In the seventeenth H site, H(33,34,35) is bonded in a single-bond geometry to one C(31) atom. In the eighteenth H site, H(36,37,38,54,55,56) is bonded in a single-bond geometry to one C(33) atom. In the nineteenth H site, H(39,40,41,48,49,50) is bonded in a single-bond geometry to one C(35) atom. In the twentieth H site, H(42,43,44,57,58,59) is bonded in a single-bond geometry to one C(37) atom. In the twenty-first H site, H(45,46,47,51,52,53) is bonded in a single-bond geometry to one C(39) atom. Linkers: 8 CC1=N[CH]C=N1 ,3 CC1=NC=C[N]1 ,1 CC1=N[C]C=N1. Metal clusters: 6 [Zn]. The MOF has largest included sphere 11.43 A, density 0.92 g/cm3, surface area 5294.64 m2/g, accessible volume 0.64 cm3/g