CuC9H5O4Cu(OOCC6H4COO)(CH)7(C2O)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of fifty-six 02329_fluka molecules, sixteen dimethyl ether molecules, four Cu(OOCC6H4COO) clusters, and four CuC9H5O4 clusters. In each Cu(OOCC6H4COO) cluster, Cu(2) is bonded in a square co-planar geometry to one O(3), one O(4), one O(6), and one O(7) atom. The Cu(2)-O(3) bond length is 1.97 Å. The Cu(2)-O(4) bond length is 1.98 Å. The Cu(2)-O(6) bond length is 1.99 Å. The Cu(2)-O(7) bond length is 1.99 Å. There are eight inequivalent C sites. In the first C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(9) atom. The C(17)-C(16) bond length is 1.42 Å. The C(17)-H(9) bond length is 0.93 Å. In the second C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(21)-C(16) bond length is 1.36 Å. The C(21)-H(12) bond length is 0.93 Å. In the third C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(6), and one O(7) atom. The C(15)-C(16) bond length is 1.53 Å. The C(15)-O(6) bond length is 1.29 Å. The C(15)-O(7) bond length is 1.26 Å. In the fourth C site, C(8) is bonded in a bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(8)-C(9) bond length is 1.49 Å. The C(8)-O(3) bond length is 1.29 Å. The C(8)-O(4) bond length is 1.28 Å. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.43 Å. The C(9)-C(14) bond length is 1.37 Å. In the sixth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(10)-H(5) bond length is 0.93 Å. In the seventh C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. In the eighth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. There are four inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(8) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(8) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(15) atom. In the fourth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(15) atom. In each CuC9H5O4 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(8), and one O(9) atom. The Cu(1)-O(1) bond length is 2.01 Å. The Cu(1)-O(2) bond length is 1.96 Å. The Cu(1)-O(8) bond length is 2.06 Å. The Cu(1)-O(9) bond length is 1.94 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.30 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.44 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(22) is bonded in a bent 120 degrees geometry to one C(23), one O(8), and one O(9) atom. The C(22)-C(23) bond length is 1.52 Å. The C(22)-O(8) bond length is 1.32 Å. The C(22)-O(9) bond length is 1.21 Å. In the sixth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(28) bond length is 1.40 Å. In the seventh C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one C(25), and one H(13) atom. The C(24)-C(25) bond length is 1.36 Å. The C(24)-H(13) bond length is 0.93 Å. In the eighth C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(14) atom. The C(25)-H(14) bond length is 0.93 Å. In the ninth C site, C(28) is bonded in a distorted single-bond geometry to one C(23) and one H(16) atom. The C(28)-H(16) bond length is 0.93 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(24) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(28) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(22) atom. In the fourth O site, O(9) is bonded in a distorted single-bond geometry to one Cu(1) and one C(22) atom. Linkers: 8 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: pts. The MOF has largest included sphere 8.12 A, density 0.91 g/cm3, surface area 4267.72 m2/g, accessible volume 0.63 cm3/g