CuH16(CN)12(CH2)2 is Indium-derived structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of eighteen 02329_fluka molecules and nine CuH16(CN)12 clusters. In each CuH16(CN)12 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent N(6) atoms. Both Cu(1)-N(2) bond lengths are 2.02 Å. Both Cu(1)-N(6) bond lengths are 2.03 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(2), one N(5), and one H(9) atom. The C(1)-N(2) bond length is 1.43 Å. The C(1)-N(5) bond length is 1.35 Å. The C(1)-H(9) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(5) atom. The C(2)-N(4) bond length is 1.37 Å. The C(2)-N(6) bond length is 1.37 Å. The C(2)-H(5) bond length is 0.95 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(3) atom. The C(5)-N(2) bond length is 1.29 Å. The C(5)-N(3) bond length is 1.24 Å. The C(5)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(1), one N(6), and one H(4) atom. The C(4)-N(1) bond length is 1.38 Å. The C(4)-N(6) bond length is 1.39 Å. The C(4)-H(4) bond length is 0.92 Å. In the fifth C site, C(6) is bonded in a 3-coordinate geometry to one N(3), one H(1), and one H(2) atom. The C(6)-N(3) bond length is 1.51 Å. The C(6)-H(1) bond length is 0.98 Å. The C(6)-H(2) bond length is 0.96 Å. In the sixth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one H(7), and one H(8) atom. The C(7)-N(4) bond length is 1.42 Å. The C(7)-H(7) bond length is 0.99 Å. The C(7)-H(8) bond length is 0.97 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a water-like geometry to one C(4) and one N(4) atom. The N(1)-N(4) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one C(5), one C(6), and one N(5) atom. The N(3)-N(5) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one C(2), one C(7), and one N(1) atom. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(1) and one N(3) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(2), and one C(4) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(1) atom. Linkers: 2 [CH]1N=C[N]N1CCCN1[CH][N]C=N1 ,2 [CH]1N=C[N]N1CCCn1cncn1 ,1 [CH]1[N]C=NN1CCCn1cncn1 ,1 [CH]1N=C[N]N1CCCN1[CH]N=C[N]1. Metal clusters: 3 [Cu]. The MOF has largest included sphere 10.37 A, density 0.79 g/cm3, surface area 5028.29 m2/g, accessible volume 0.72 cm3/g