Cu6C99H85(NO)16CH3 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and four Cu6C99H85(NO)16 clusters. In each Cu6C99H85(NO)16 cluster, there are six inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(13), one O(14), one O(2), and one O(3) atom. The Cu(1)-O(13) bond length is 1.98 Å. The Cu(1)-O(14) bond length is 1.98 Å. The Cu(1)-O(2) bond length is 1.96 Å. The Cu(1)-O(3) bond length is 1.96 Å. In the second Cu site, Cu(2) is bonded in a distorted square co-planar geometry to one O(10), one O(6), one O(7), and one O(9) atom. The Cu(2)-O(10) bond length is 1.95 Å. The Cu(2)-O(6) bond length is 1.96 Å. The Cu(2)-O(7) bond length is 1.95 Å. The Cu(2)-O(9) bond length is 1.95 Å. In the third Cu site, Cu(3) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(12), one O(15), and one O(4) atom. The Cu(3)-O(1) bond length is 1.95 Å. The Cu(3)-O(12) bond length is 1.95 Å. The Cu(3)-O(15) bond length is 1.96 Å. The Cu(3)-O(4) bond length is 1.95 Å. In the fourth Cu site, Cu(4) is bonded in a distorted rectangular see-saw-like geometry to one O(11), one O(16), one O(5), and one O(8) atom. The Cu(4)-O(11) bond length is 1.97 Å. The Cu(4)-O(16) bond length is 1.97 Å. The Cu(4)-O(5) bond length is 1.97 Å. The Cu(4)-O(8) bond length is 1.97 Å. In the fifth Cu site, Cu(5) is bonded in a tetrahedral geometry to one N(13), one N(16), one N(5), and one N(8) atom. The Cu(5)-N(13) bond length is 2.05 Å. The Cu(5)-N(16) bond length is 2.01 Å. The Cu(5)-N(5) bond length is 2.04 Å. The Cu(5)-N(8) bond length is 2.10 Å. In the sixth Cu site, Cu(6) is bonded in a tetrahedral geometry to one N(14), one N(15), one N(6), and one N(7) atom. The Cu(6)-N(14) bond length is 2.04 Å. The Cu(6)-N(15) bond length is 2.07 Å. The Cu(6)-N(6) bond length is 2.07 Å. The Cu(6)-N(7) bond length is 2.02 Å. There are ninety-nine inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one N(1); one N(9); and two equivalent H(1,2) atoms. The C(1)-N(1) bond length is 1.45 Å. The C(1)-N(9) bond length is 1.45 Å. Both C(1)-H(1,2) bond lengths are 0.99 Å. In the second C site, C(2) is bonded in a tetrahedral geometry to one N(10), one N(2), one H(3), and one H(4) atom. The C(2)-N(10) bond length is 1.45 Å. The C(2)-N(2) bond length is 1.45 Å. The C(2)-H(3) bond length is 0.99 Å. The C(2)-H(4) bond length is 0.99 Å. In the third C site, C(3) is bonded in a tetrahedral geometry to one N(11), one N(3), one H(5), and one H(6) atom. The C(3)-N(11) bond length is 1.46 Å. The C(3)-N(3) bond length is 1.44 Å. The C(3)-H(5) bond length is 0.99 Å. The C(3)-H(6) bond length is 0.99 Å. In the fourth C site, C(4) is bonded in a tetrahedral geometry to one N(12), one N(4), one H(7), and one H(8) atom. The C(4)-N(12) bond length is 1.44 Å. The C(4)-N(4) bond length is 1.46 Å. The C(4)-H(7) bond length is 0.99 Å. The C(4)-H(8) bond length is 0.99 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(17), one C(9), and one N(5) atom. The C(5)-C(17) bond length is 1.48 Å. The C(5)-C(9) bond length is 1.43 Å. The C(5)-N(5) bond length is 1.34 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(10) and one N(6) atom. The C(6)-C(10) bond length is 1.41 Å. The C(6)-N(6) bond length is 1.33 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(11), one C(19), and one N(7) atom. The C(7)-C(11) bond length is 1.42 Å. The C(7)-C(19) bond length is 1.49 Å. The C(7)-N(7) bond length is 1.34 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(12), one C(20), and one N(8) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(20) bond length is 1.52 Å. The C(8)-N(8) bond length is 1.34 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(13), one C(25), and one C(5) atom. The C(9)-C(13) bond length is 1.39 Å. The C(9)-C(25) bond length is 1.48 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(14), one C(26), and one C(6) atom. The C(10)-C(14) bond length is 1.40 Å. The C(10)-C(26) bond length is 1.47 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(15), one C(27), and one C(7) atom. The C(11)-C(15) bond length is 1.39 Å. The C(11)-C(27) bond length is 1.48 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(16), one C(28), and one C(8) atom. The C(12)-C(16) bond length is 1.39 Å. The C(12)-C(28) bond length is 1.48 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(21), one C(9), and one N(1) atom. The C(13)-C(21) bond length is 1.49 Å. The C(13)-N(1) bond length is 1.36 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(10), one C(22), and one N(2) atom. The C(14)-C(22) bond length is 1.49 Å. The C(14)-N(2) bond length is 1.36 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(11), one C(23), and one N(3) atom. The C(15)-C(23) bond length is 1.48 Å. The C(15)-N(3) bond length is 1.35 Å. In the sixteenth C site, C(16) is bonded in a 3-coordinate geometry to one C(12), one C(24), and one N(4) atom. The C(16)-C(24) bond length is 1.45 Å. The C(16)-N(4) bond length is 1.36 Å. In the seventeenth C site, C(17) is bonded in a trigonal non-coplanar geometry to one C(5); one H(11); and two equivalent H(9,10) atoms. The C(17)-H(11) bond length is 0.98 Å. Both C(17)-H(9,10) bond lengths are 0.98 Å. In the eighteenth C site, C(19) is bonded in a trigonal non-coplanar geometry to one C(7) and three equivalent H(15,16,17) atoms. All C(19)-H(15,16,17) bond lengths are 0.98 Å. In the nineteenth C site, C(20) is bonded in a trigonal non-coplanar geometry to one C(8); one H(19); and two equivalent H(18,20) atoms. The C(20)-H(19) bond length is 0.98 Å. Both C(20)-H(18,20) bond lengths are 0.98 Å. In the twentieth C site, C(21) is bonded in a trigonal non-coplanar geometry to one C(13); one H(23); and two equivalent H(21,22) atoms. The C(21)-H(23) bond length is 0.98 Å. Both C(21)-H(21,22) bond lengths are 0.98 Å. In the twenty-first C site, C(22) is bonded in a trigonal non-coplanar geometry to one C(14); one H(25); and two equivalent H(24,26) atoms. The C(22)-H(25) bond length is 0.98 Å. Both C(22)-H(24,26) bond lengths are 0.98 Å. In the twenty-second C site, C(23) is bonded in a trigonal non-coplanar geometry to one C(15); one H(28); and two equivalent H(27,29) atoms. The C(23)-H(28) bond length is 0.98 Å. Both C(23)-H(27,29) bond lengths are 0.98 Å. In the twenty-third C site, C(24) is bonded in a trigonal non-coplanar geometry to one C(16), one H(30), one H(31), and one H(32) atom. The C(24)-H(30) bond length is 0.98 Å. The C(24)-H(31) bond length is 0.98 Å. The C(24)-H(32) bond length is 0.98 Å. In the twenty-fourth C site, C(25) is bonded in a trigonal planar geometry to one C(29), one C(45), and one C(9) atom. The C(25)-C(29) bond length is 1.39 Å. The C(25)-C(45) bond length is 1.40 Å. In the twenty-fifth C site, C(26) is bonded in a trigonal planar geometry to one C(10), one C(30), and one C(46) atom. The C(26)-C(30) bond length is 1.40 Å. The C(26)-C(46) bond length is 1.39 Å. In the twenty-sixth C site, C(27) is bonded in a trigonal planar geometry to one C(11), one C(31), and one C(47) atom. The C(27)-C(31) bond length is 1.40 Å. The C(27)-C(47) bond length is 1.41 Å. In the twenty-seventh C site, C(28) is bonded in a trigonal planar geometry to one C(12), one C(32), and one C(48) atom. The C(28)-C(32) bond length is 1.39 Å. The C(28)-C(48) bond length is 1.40 Å. In the twenty-eighth C site, C(29) is bonded in a single-bond geometry to one C(25) and one H(33) atom. The C(29)-H(33) bond length is 0.95 Å. In the twenty-ninth C site, C(30) is bonded in a distorted single-bond geometry to one C(26) and one H(34) atom. The C(30)-H(34) bond length is 0.95 Å. In the thirtieth C site, C(31) is bonded in a single-bond geometry to one C(27) and one H(35) atom. The C(31)-H(35) bond length is 0.95 Å. In the thirty-first C site, C(32) is bonded in a distorted single-bond geometry to one C(28) and one H(36) atom. The C(32)-H(36) bond length is 0.95 Å. In the thirty-second C site, C(33) is bonded in a distorted single-bond geometry to one C(37) and one H(37) atom. The C(33)-C(37) bond length is 1.39 Å. The C(33)-H(37) bond length is 0.95 Å. In the thirty-third C site, C(34) is bonded in a distorted single-bond geometry to one C(38) and one H(38) atom. The C(34)-C(38) bond length is 1.40 Å. The C(34)-H(38) bond length is 0.95 Å. In the thirty-fourth C site, C(35) is bonded in a distorted single-bond geometry to one C(39) and one H(39) atom. The C(35)-C(39) bond length is 1.40 Å. The C(35)-H(39) bond length is 0.95 Å. In the thirty-fifth C site, C(36) is bonded in a distorted single-bond geometry to one C(40) and one H(40) atom. The C(36)-C(40) bond length is 1.39 Å. The C(36)-H(40) bond length is 0.95 Å. In the thirty-sixth C site, C(37) is bonded in a trigonal planar geometry to one C(33), one C(41), and one C(49) atom. The C(37)-C(41) bond length is 1.40 Å. The C(37)-C(49) bond length is 1.51 Å. In the thirty-seventh C site, C(38) is bonded in a trigonal planar geometry to one C(34), one C(42), and one C(50) atom. The C(38)-C(42) bond length is 1.39 Å. The C(38)-C(50) bond length is 1.50 Å. In the thirty-eighth C site, C(39) is bonded in a trigonal planar geometry to one C(35), one C(43), and one C(51) atom. The C(39)-C(43) bond length is 1.36 Å. The C(39)-C(51) bond length is 1.50 Å. In the thirty-ninth C site, C(40) is bonded in a trigonal planar geometry to one C(36), one C(44), and one C(52) atom. The C(40)-C(44) bond length is 1.41 Å. The C(40)-C(52) bond length is 1.50 Å. In the fortieth C site, C(41) is bonded in a distorted single-bond geometry to one C(37) and one H(41) atom. The C(41)-H(41) bond length is 0.95 Å. In the forty-first C site, C(42) is bonded in a distorted trigonal planar geometry to one C(38), one C(46), and one H(42) atom. The C(42)-C(46) bond length is 1.37 Å. The C(42)-H(42) bond length is 0.95 Å. In the forty-second C site, C(43) is bonded in a distorted single-bond geometry to one C(39) and one H(43) atom. The C(43)-H(43) bond length is 0.95 Å. In the forty-third C site, C(44) is bonded in a distorted trigonal planar geometry to one C(40), one C(48), and one H(44) atom. The C(44)-C(48) bond length is 1.38 Å. The C(44)-H(44) bond length is 0.95 Å. In the forty-fourth C site, C(45) is bonded in a distorted single-bond geometry to one C(25) and one H(45) atom. The C(45)-H(45) bond length is 0.95 Å. In the forty-fifth C site, C(46) is bonded in a distorted single-bond geometry to one C(26), one C(42), and one H(46) atom. The C(46)-H(46) bond length is 0.95 Å. In the forty-sixth C site, C(47) is bonded in a distorted single-bond geometry to one C(27) and one H(47) atom. The C(47)-H(47) bond length is 0.95 Å. In the forty-seventh C site, C(48) is bonded in a distorted single-bond geometry to one C(28), one C(44), and one H(48) atom. The C(48)-H(48) bond length is 0.95 Å. In the forty-eighth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(1), and one O(5) atom. The C(49)-O(1) bond length is 1.27 Å. The C(49)-O(5) bond length is 1.26 Å. In the forty-ninth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one C(38), one O(2), and one O(6) atom. The C(50)-O(2) bond length is 1.28 Å. The C(50)-O(6) bond length is 1.26 Å. In the fiftieth C site, C(51) is bonded in a distorted bent 120 degrees geometry to one C(39), one O(3), and one O(7) atom. The C(51)-O(3) bond length is 1.27 Å. The C(51)-O(7) bond length is 1.26 Å. In the fifty-first C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(40), one O(4), and one O(8) atom. The C(52)-O(4) bond length is 1.28 Å. The C(52)-O(8) bond length is 1.28 Å. In the fifty-second C site, C(53) is bonded in a distorted single-bond geometry to one C(57), one C(65), and one N(13) atom. The C(53)-C(57) bond length is 1.41 Å. The C(53)-C(65) bond length is 1.51 Å. The C(53)-N(13) bond length is 1.34 Å. In the fifty-third C site, C(54) is bonded in a distorted single-bond geometry to one C(58), one C(66), and one N(14) atom. The C(54)-C(58) bond length is 1.40 Å. The C(54)-C(66) bond length is 1.51 Å. The C(54)-N(14) bond length is 1.33 Å. In the fifty-fourth C site, C(55) is bonded in a distorted single-bond geometry to one C(59), one C(67), and one N(15) atom. The C(55)-C(59) bond length is 1.39 Å. The C(55)-C(67) bond length is 1.51 Å. The C(55)-N(15) bond length is 1.33 Å. In the fifty-fifth C site, C(56) is bonded in a distorted single-bond geometry to one C(60), one C(68), and one N(16) atom. The C(56)-C(60) bond length is 1.42 Å. The C(56)-C(68) bond length is 1.48 Å. The C(56)-N(16) bond length is 1.35 Å. In the fifty-sixth C site, C(57) is bonded in a trigonal planar geometry to one C(53), one C(61), and one C(73) atom. The C(57)-C(61) bond length is 1.38 Å. The C(57)-C(73) bond length is 1.47 Å. In the fifty-seventh C site, C(58) is bonded in a trigonal planar geometry to one C(54), one C(62), and one C(74) atom. The C(58)-C(62) bond length is 1.37 Å. The C(58)-C(74) bond length is 1.49 Å. In the fifty-eighth C site, C(59) is bonded in a trigonal planar geometry to one C(55), one C(63), and one C(75) atom. The C(59)-C(63) bond length is 1.39 Å. The C(59)-C(75) bond length is 1.49 Å. In the fifty-ninth C site, C(60) is bonded in a trigonal planar geometry to one C(56), one C(64), and one C(76) atom. The C(60)-C(64) bond length is 1.38 Å. The C(60)-C(76) bond length is 1.48 Å. In the sixtieth C site, C(61) is bonded in a distorted trigonal planar geometry to one C(57), one C(69), and one N(9) atom. The C(61)-C(69) bond length is 1.51 Å. The C(61)-N(9) bond length is 1.34 Å. In the sixty-first C site, C(62) is bonded in a 3-coordinate geometry to one C(58), one C(70), and one N(10) atom. The C(62)-C(70) bond length is 1.52 Å. The C(62)-N(10) bond length is 1.36 Å. In the sixty-second C site, C(63) is bonded in a 3-coordinate geometry to one C(59), one C(71), and one N(11) atom. The C(63)-C(71) bond length is 1.49 Å. The C(63)-N(11) bond length is 1.35 Å. In the sixty-third C site, C(64) is bonded in a 3-coordinate geometry to one C(60), one C(72), and one N(12) atom. The C(64)-C(72) bond length is 1.49 Å. The C(64)-N(12) bond length is 1.36 Å. In the sixty-fourth C site, C(65) is bonded in a trigonal non-coplanar geometry to one C(53); one H(51); and two equivalent H(49,50) atoms. The C(65)-H(51) bond length is 0.98 Å. Both C(65)-H(49,50) bond lengths are 0.98 Å. In the sixty-fifth C site, C(66) is bonded in a trigonal non-coplanar geometry to one C(54); one H(53); and two equivalent H(52,54) atoms. The C(66)-H(53) bond length is 0.98 Å. Both C(66)-H(52,54) bond lengths are 0.98 Å. In the sixty-sixth C site, C(67) is bonded in a trigonal non-coplanar geometry to one C(55); one H(56); and two equivalent H(55,57) atoms. The C(67)-H(56) bond length is 0.98 Å. Both C(67)-H(55,57) bond lengths are 0.98 Å. In the sixty-seventh C site, C(68) is bonded in a trigonal non-coplanar geometry to one C(56); one H(58); and two equivalent H(59,60) atoms. The C(68)-H(58) bond length is 0.98 Å. Both C(68)-H(59,60) bond lengths are 0.98 Å. In the sixty-eighth C site, C(69) is bonded in a trigonal non-coplanar geometry to one C(61) and three equivalent H(61,62,63) atoms. All C(69)-H(61,62,63) bond lengths are 0.98 Å. In the sixty-ninth C site, C(70) is bonded in a trigonal non-coplanar geometry to one C(62); one H(64,67); one H(65,70,71,72); and one H(66,69) atom. The C(70)-H(64,67) bond length is 0.98 Å. The C(70)-H(65,70,71,72) bond length is 0.98 Å. The C(70)-H(66,69) bond length is 0.98 Å. In the seventieth C site, C(71) is bonded in a trigonal non-coplanar geometry to one C(63); one H(64,67); one H(66,69); and one H(68) atom. The C(71)-H(64,67) bond length is 0.98 Å. The C(71)-H(66,69) bond length is 0.98 Å. The C(71)-H(68) bond length is 0.98 Å. In the seventy-first C site, C(72) is bonded in a trigonal non-coplanar geometry to one C(64) and three equivalent H(65,70,71,72) atoms. All C(72)-H(65,70,71,72) bond lengths are 0.98 Å. In the seventy-second C site, C(73) is bonded in a trigonal planar geometry to one C(57), one C(77), and one C(93) atom. The C(73)-C(77) bond length is 1.39 Å. The C(73)-C(93) bond length is 1.39 Å. In the seventy-third C site, C(74) is bonded in a trigonal planar geometry to one C(58), one C(78), and one C(94) atom. The C(74)-C(78) bond length is 1.40 Å. The C(74)-C(94) bond length is 1.39 Å. In the seventy-fourth C site, C(75) is bonded in a trigonal planar geometry to one C(59), one C(79), and one C(95) atom. The C(75)-C(79) bond length is 1.38 Å. The C(75)-C(95) bond length is 1.37 Å. In the seventy-fifth C site, C(76) is bonded in a trigonal planar geometry to one C(60), one C(80), and one C(96) atom. The C(76)-C(80) bond length is 1.39 Å. The C(76)-C(96) bond length is 1.41 Å. In the seventy-sixth C site, C(77) is bonded in a distorted single-bond geometry to one C(73), one C(81), and one H(73) atom. The C(77)-C(81) bond length is 1.38 Å. The C(77)-H(73) bond length is 0.95 Å. In the seventy-seventh C site, C(78) is bonded in a single-bond geometry to one C(74) and one H(74) atom. The C(78)-H(74) bond length is 0.95 Å. In the seventy-eighth C site, C(79) is bonded in a distorted single-bond geometry to one C(75) and one H(75) atom. The C(79)-H(75) bond length is 0.95 Å. In the seventy-ninth C site, C(80) is bonded in a distorted single-bond geometry to one C(76) and one H(76) atom. The C(80)-H(76) bond length is 0.95 Å. In the eightieth C site, C(81) is bonded in a distorted trigonal planar geometry to one C(77), one C(85), and one H(77) atom. The C(81)-C(85) bond length is 1.39 Å. The C(81)-H(77) bond length is 0.95 Å. In the eighty-first C site, C(82) is bonded in a distorted single-bond geometry to one C(86) and one H(78) atom. The C(82)-C(86) bond length is 1.37 Å. The C(82)-H(78) bond length is 0.95 Å. In the eighty-second C site, C(83) is bonded in a distorted single-bond geometry to one C(87) and one H(79) atom. The C(83)-C(87) bond length is 1.37 Å. The C(83)-H(79) bond length is 0.95 Å. In the eighty-third C site, C(84) is bonded in a distorted single-bond geometry to one C(88) and one H(80) atom. The C(84)-C(88) bond length is 1.39 Å. The C(84)-H(80) bond length is 0.95 Å. In the eighty-fourth C site, C(85) is bonded in a trigonal planar geometry to one C(81), one C(89), and one C(97) atom. The C(85)-C(89) bond length is 1.37 Å. The C(85)-C(97) bond length is 1.51 Å. In the eighty-fifth C site, C(86) is bonded in a trigonal planar geometry to one C(82), one C(90), and one C(98) atom. The C(86)-C(90) bond length is 1.40 Å. The C(86)-C(98) bond length is 1.49 Å. In the eighty-sixth C site, C(87) is bonded in a trigonal planar geometry to one C(83), one C(91), and one C(99) atom. The C(87)-C(91) bond length is 1.40 Å. The C(87)-C(99) bond length is 1.50 Å. In the eighty-seventh C site, C(88) is bonded in a trigonal planar geometry to one C(100), one C(84), and one C(92) atom. The C(88)-C(100) bond length is 1.51 Å. The C(88)-C(92) bond length is 1.40 Å. In the eighty-eighth C site, C(89) is bonded in a distorted trigonal planar geometry to one C(85), one C(93), and one H(81) atom. The C(89)-C(93) bond length is 1.40 Å. The C(89)-H(81) bond length is 0.95 Å. In the eighty-ninth C site, C(90) is bonded in a distorted single-bond geometry to one C(86) and one H(82) atom. The C(90)-H(82) bond length is 0.95 Å. In the ninetieth C site, C(91) is bonded in a distorted trigonal planar geometry to one C(87), one C(95), and one H(83) atom. The C(91)-C(95) bond length is 1.40 Å. The C(91)-H(83) bond length is 0.95 Å. In the ninety-first C site, C(92) is bonded in a distorted single-bond geometry to one C(88) and one H(84) atom. The C(92)-H(84) bond length is 0.95 Å. In the ninety-second C site, C(93) is bonded in a distorted single-bond geometry to one C(73), one C(89), and one H(85) atom. The C(93)-H(85) bond length is 0.95 Å. In the ninety-third C site, C(94) is bonded in a distorted single-bond geometry to one C(74) and one H(86) atom. The C(94)-H(86) bond length is 0.95 Å. In the ninety-fourth C site, C(95) is bonded in a distorted single-bond geometry to one C(75), one C(91), and one H(87) atom. The C(95)-H(87) bond length is 0.95 Å. In the ninety-fifth C site, C(96) is bonded in a distorted single-bond geometry to one C(76) and one H(88) atom. The C(96)-H(88) bond length is 0.95 Å. In the ninety-sixth C site, C(97) is bonded in a bent 120 degrees geometry to one C(85), one O(13), and one O(9) atom. The C(97)-O(13) bond length is 1.26 Å. The C(97)-O(9) bond length is 1.26 Å. In the ninety-seventh C site, C(98) is bonded in a bent 120 degrees geometry to one C(86), one O(10), and one O(14) atom. The C(98)-O(10) bond length is 1.27 Å. The C(98)-O(14) bond length is 1.27 Å. In the ninety-eighth C site, C(99) is bonded in a bent 120 degrees geometry to one C(87), one O(11), and one O(15) atom. The C(99)-O(11) bond length is 1.28 Å. The C(99)-O(15) bond length is 1.26 Å. In the ninety-ninth C site, C(100) is bonded in a bent 120 degrees geometry to one C(88), one O(12), and one O(16) atom. The C(100)-O(12) bond length is 1.26 Å. The C(100)-O(16) bond length is 1.25 Å. There are sixteen inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(1), one C(13), and one N(5) atom. The N(1)-N(5) bond length is 1.38 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(14), one C(2), and one N(6) atom. The N(2)-N(6) bond length is 1.36 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(15), one C(3), and one N(7) atom. The N(3)-N(7) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(16), one C(4), and one N(8) atom. The N(4)-N(8) bond length is 1.36 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cu(5), one C(5), and one N(1) atom. In the sixth N site, N(6) is bonded in a 3-coordinate geometry to one Cu(6), one C(6), and one N(2) atom. In the seventh N site, N(7) is bonded in a 3-coordinate geometry to one Cu(6), one C(7), and one N(3) atom. In the eighth N site, N(8) is bonded in a 3-coordinate geometry to one Cu(5), one C(8), and one N(4) atom. In the ninth N site, N(9) is bonded in a distorted trigonal planar geometry to one C(1), one C(61), and one N(13) atom. The N(9)-N(13) bond length is 1.36 Å. In the tenth N site, N(10) is bonded in a distorted trigonal planar geometry to one C(2), one C(62), and one N(14) atom. The N(10)-N(14) bond length is 1.35 Å. In the eleventh N site, N(11) is bonded in a distorted trigonal planar geometry to one C(3), one C(63), and one N(15) atom. The N(11)-N(15) bond length is 1.37 Å. In the twelfth N site, N(12) is bonded in a distorted trigonal planar geometry to one C(4), one C(64), and one N(16) atom. The N(12)-N(16) bond length is 1.37 Å. In the thirteenth N site, N(13) is bonded in a distorted trigonal planar geometry to one Cu(5), one C(53), and one N(9) atom. In the fourteenth N site, N(14) is bonded in a distorted trigonal planar geometry to one Cu(6), one C(54), and one N(10) atom. In the fifteenth N site, N(15) is bonded in a 3-coordinate geometry to one Cu(6), one C(55), and one N(11) atom. In the sixteenth N site, N(16) is bonded in a 3-coordinate geometry to one Cu(5), one C(56), and one N(12) atom. There are sixty-six inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the eighth H site, H(9,10) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(15,16,17) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(18,20) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(21,22) is bonded in a single-bond geometry to one C(21) atom. In the fourteenth H site, H(23) is bonded in a single-bond geometry to one C(21) atom. In the fifteenth H site, H(24,26) is bonded in a single-bond geometry to one C(22) atom. In the sixteenth H site, H(25) is bonded in a single-bond geometry to one C(22) atom. In the seventeenth H site, H(27,29) is bonded in a single-bond geometry to one C(23) atom. In the eighteenth H site, H(28) is bonded in a single-bond geometry to one C(23) atom. In the nineteenth H site, H(30) is bonded in a single-bond geometry to one C(24) atom. In the twentieth H site, H(31) is bonded in a single-bond geometry to one C(24) atom. In the twenty-first H site, H(32) is bonded in a single-bond geometry to one C(24) atom. In the twenty-second H site, H(33) is bonded in a single-bond geometry to one C(29) atom. In the twenty-third H site, H(34) is bonded in a single-bond geometry to one C(30) atom. In the twenty-fourth H site, H(35) is bonded in a single-bond geometry to one C(31) atom. In the twenty-fifth H site, H(36) is bonded in a single-bond geometry to one C(32) atom. In the twenty-sixth H site, H(37) is bonded in a single-bond geometry to one C(33) atom. In the twenty-seventh H site, H(38) is bonded in a single-bond geometry to one C(34) atom. In the twenty-eighth H site, H(39) is bonded in a single-bond geometry to one C(35) atom. In the twenty-ninth H site, H(40) is bonded in a single-bond geometry to one C(36) atom. In the thirtieth H site, H(41) is bonded in a single-bond geometry to one C(41) atom. In the thirty-first H site, H(42) is bonded in a single-bond geometry to one C(42) atom. In the thirty-second H site, H(43) is bonded in a single-bond geometry to one C(43) atom. In the thirty-third H site, H(44) is bonded in a single-bond geometry to one C(44) atom. In the thirty-fourth H site, H(45) is bonded in a single-bond geometry to one C(45) atom. In the thirty-fifth H site, H(46) is bonded in a single-bond geometry to one C(46) atom. In the thirty-sixth H site, H(47) is bonded in a single-bond geometry to one C(47) atom. In the thirty-seventh H site, H(48) is bonded in a single-bond geometry to one C(48) atom. In the thirty-eighth H site, H(49,50) is bonded in a single-bond geometry to one C(65) atom. In the thirty-ninth H site, H(51) is bonded in a single-bond geometry to one C(65) atom. In the fortieth H site, H(52,54) is bonded in a single-bond geometry to one C(66) atom. In the forty-first H site, H(53) is bonded in a single-bond geometry to one C(66) atom. In the forty-second H site, H(55,57) is bonded in a single-bond geometry to one C(67) atom. In the forty-third H site, H(56) is bonded in a single-bond geometry to one C(67) atom. In the forty-fourth H site, H(58) is bonded in a single-bond geometry to one C(68) atom. In the forty-fifth H site, H(59,60) is bonded in a single-bond geometry to one C(68) atom. In the forty-sixth H site, H(61,62,63) is bonded in a single-bond geometry to one C(69) atom. In the forty-seventh H site, H(64,67) is bonded in a single-bond geometry to one C(70) atom. In the forty-eighth H site, H(65,70,71,72) is bonded in a single-bond geometry to one C(70) atom. In the forty-ninth H site, H(66,69) is bonded in a single-bond geometry to one C(70) atom. In the fiftieth H site, H(68) is bonded in a single-bond geometry to one C(71) atom. In the fifty-first H site, H(73) is bonded in a single-bond geometry to one C(77) atom. In the fifty-second H site, H(74) is bonded in a single-bond geometry to one C(78) atom. In the fifty-third H site, H(75) is bonded in a single-bond geometry to one C(79) atom. In the fifty-fourth H site, H(76) is bonded in a single-bond geometry to one C(80) atom. In the fifty-fifth H site, H(77) is bonded in a single-bond geometry to one C(81) atom. In the fifty-sixth H site, H(78) is bonded in a single-bond geometry to one C(82) atom. In the fifty-seventh H site, H(79) is bonded in a single-bond geometry to one C(83) atom. In the fifty-eighth H site, H(80) is bonded in a single-bond geometry to one C(84) atom. In the fifty-ninth H site, H(81) is bonded in a single-bond geometry to one C(89) atom. In the sixtieth H site, H(82) is bonded in a single-bond geometry to one C(90) atom. In the sixty-first H site, H(83) is bonded in a single-bond geometry to one C(91) atom. In the sixty-second H site, H(84) is bonded in a single-bond geometry to one C(92) atom. In the sixty-third H site, H(85) is bonded in a single-bond geometry to one C(93) atom. In the sixty-fourth H site, H(86) is bonded in a single-bond geometry to one C(94) atom. In the sixty-fifth H site, H(87) is bonded in a single-bond geometry to one C(95) atom. In the sixty-sixth H site, H(88) is bonded in a single-bond geometry to one C(96) atom. There are sixteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(49) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(50) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cu(1) and one C(51) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one C(52) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one C(49) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(50) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(51) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Cu(4) and one C(52) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Cu(2) and one C(97) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(98) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Cu(4) and one C(99) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(100) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Cu(1) and one C(97) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one Cu(1) and one C(98) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Cu(3) and one C(99) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one C(100) atom. Linkers: 8 C[C]1C(c2ccc(C([O])=O)cc2)=C(C)N2CN3C(C)=C(c4ccc(C([O])=O)cc4)[C](C)N3[Cu]3(N12)N1[C](C)C(c2ccc(C([O])=O)cc2)=C(C)N1CN1C(C)=C(c2ccc(C([O])=O)cc2)[C](C)N13. Metal clusters: 8 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 12.61 A, density 0.58 g/cm3, surface area 4671.77 m2/g, accessible volume 1.32 cm3/g