(AgH8(C2N)4)2Ag2C20H16S17O3CF3 is Indium-derived structured and crystallizes in the orthorhombic Pnnm space group. The structure is zero-dimensional and consists of four trifluoromethane molecules, two Ag2C20H16S17O3 clusters, and eight AgH8(C2N)4 clusters. In each Ag2C20H16S17O3 cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(2) is bonded in a distorted bent 150 degrees geometry to two equivalent S(5) atoms. Both Ag(2)-S(5) bond lengths are 2.50 Å. In the second Ag site, Ag(3) is bonded in a distorted trigonal pyramidal geometry to two equivalent S(6) and two equivalent O(1) atoms. Both Ag(3)-S(6) bond lengths are 2.52 Å. Both Ag(3)-O(1) bond lengths are 2.36 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(4), one S(1), and one S(2) atom. The C(1)-C(4) bond length is 1.36 Å. The C(1)-S(1) bond length is 1.76 Å. The C(1)-S(2) bond length is 1.76 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(3), one S(2), and one S(5) atom. The C(2)-C(3) bond length is 1.35 Å. The C(2)-S(2) bond length is 1.76 Å. The C(2)-S(5) bond length is 1.75 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one S(1), and one S(6) atom. The C(3)-S(1) bond length is 1.76 Å. The C(3)-S(6) bond length is 1.76 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one S(3), and one S(4) atom. The C(4)-S(3) bond length is 1.75 Å. The C(4)-S(4) bond length is 1.75 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(6), one S(3), and one S(7) atom. The C(5)-C(6) bond length is 1.34 Å. The C(5)-S(3) bond length is 1.76 Å. The C(5)-S(7) bond length is 1.75 Å. In the sixth C site, C(10) is bonded in a water-like geometry to one H(5), one H(6), and one S(6) atom. The C(10)-H(5) bond length is 0.95 Å. The C(10)-H(6) bond length is 0.95 Å. The C(10)-S(6) bond length is 1.81 Å. In the seventh C site, C(6) is bonded in a trigonal planar geometry to one C(5), one S(4), and one S(8) atom. The C(6)-S(4) bond length is 1.75 Å. The C(6)-S(8) bond length is 1.75 Å. In the eighth C site, C(7) is bonded in a water-like geometry to two equivalent H(1,2) and one S(5) atom. Both C(7)-H(1,2) bond lengths are 0.95 Å. The C(7)-S(5) bond length is 1.82 Å. In the ninth C site, C(13) is bonded in a water-like geometry to one H(10), one H(9), and one S(7) atom. The C(13)-H(10) bond length is 0.95 Å. The C(13)-H(9) bond length is 0.95 Å. The C(13)-S(7) bond length is 1.81 Å. In the tenth C site, C(16) is bonded in a water-like geometry to two equivalent H(13,14) and one S(8) atom. Both C(16)-H(13,14) bond lengths are 0.95 Å. The C(16)-S(8) bond length is 1.81 Å. There are six inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(13,14) is bonded in a single-bond geometry to one C(16) atom. There are nine inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(1) and one C(3) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one C(1) and one C(2) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one C(4) and one C(5) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one C(4) and one C(6) atom. In the fifth S site, S(5) is bonded in a trigonal non-coplanar geometry to one Ag(2), one C(2), and one C(7) atom. In the sixth S site, S(6) is bonded in a trigonal non-coplanar geometry to one Ag(3), one C(10), and one C(3) atom. In the seventh S site, S(7) is bonded in a water-like geometry to one C(13) and one C(5) atom. In the eighth S site, S(8) is bonded in a water-like geometry to one C(16) and one C(6) atom. In the ninth S site, S(9) is bonded in a distorted trigonal non-coplanar geometry to one O(2) and two equivalent O(1) atoms. The S(9)-O(2) bond length is 1.44 Å. Both S(9)-O(1) bond lengths are 1.44 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a 2-coordinate geometry to one Ag(3) and one S(9) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(9) atom. In each AgH8(C2N)4 cluster, Ag(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Ag(1)-N(1) bond length is 2.34 Å. The Ag(1)-N(2) bond length is 2.22 Å. The Ag(1)-N(3) bond length is 2.21 Å. The Ag(1)-N(4) bond length is 2.31 Å. There are eight inequivalent C sites. In the first C site, C(17) is bonded in a water-like geometry to one C(18), one H(15), and one H(16) atom. The C(17)-C(18) bond length is 1.46 Å. The C(17)-H(15) bond length is 0.95 Å. The C(17)-H(16) bond length is 0.95 Å. In the second C site, C(18) is bonded in a linear geometry to one C(17) and one N(4) atom. The C(18)-N(4) bond length is 1.13 Å. In the third C site, C(11) is bonded in a water-like geometry to one C(12) and two equivalent H(7,8) atoms. The C(11)-C(12) bond length is 1.47 Å. Both C(11)-H(7,8) bond lengths are 0.95 Å. In the fourth C site, C(15) is bonded in a linear geometry to one C(14) and one N(3) atom. The C(15)-C(14) bond length is 1.48 Å. The C(15)-N(3) bond length is 1.12 Å. In the fifth C site, C(8) is bonded in a water-like geometry to one C(9) and two equivalent H(3,4) atoms. The C(8)-C(9) bond length is 1.46 Å. Both C(8)-H(3,4) bond lengths are 0.95 Å. In the sixth C site, C(9) is bonded in a linear geometry to one C(8) and one N(1) atom. The C(9)-N(1) bond length is 1.13 Å. In the seventh C site, C(12) is bonded in a linear geometry to one C(11) and one N(2) atom. The C(12)-N(2) bond length is 1.13 Å. In the eighth C site, C(14) is bonded in a water-like geometry to one C(15) and two equivalent H(11,12) atoms. Both C(14)-H(11,12) bond lengths are 0.95 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted linear geometry to one Ag(1) and one C(9) atom. In the second N site, N(2) is bonded in a distorted linear geometry to one Ag(1) and one C(12) atom. In the third N site, N(4) is bonded in a linear geometry to one Ag(1) and one C(18) atom. In the fourth N site, N(3) is bonded in a linear geometry to one Ag(1) and one C(15) atom. There are five inequivalent H sites. In the first H site, H(3,4) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(7,8) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(11,12) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. Linkers: 8 N#CCCSC1=C(SCCC#N)SC(=C2SC(SCCC#N)=C(SCCC#N)S2)S1. Metal clusters: 16 [Ag]. The MOF has largest included sphere 5.74 A, density 1.56 g/cm3, surface area 3734.08 m2/g, accessible volume 0.28 cm3/g