Tb3C43H27O22(CH)2 crystallizes in the tetragonal I-42d space group. The structure consists of sixteen 02329_fluka molecules inside a Tb3C43H27O22 framework. In the Tb3C43H27O22 framework, there are two inequivalent Tb sites. In the first Tb site, Tb(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(2), one O(3), one O(4), one O(7), one O(8), and one O(9) atom. The Tb(1)-O(1) bond length is 2.98 Å. The Tb(1)-O(10) bond length is 2.38 Å. The Tb(1)-O(11) bond length is 2.36 Å. The Tb(1)-O(2) bond length is 2.34 Å. The Tb(1)-O(3) bond length is 2.35 Å. The Tb(1)-O(4) bond length is 2.39 Å. The Tb(1)-O(7) bond length is 2.29 Å. The Tb(1)-O(8) bond length is 2.40 Å. The Tb(1)-O(9) bond length is 2.55 Å. In the second Tb site, Tb(2) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. Both Tb(2)-O(1) bond lengths are 2.27 Å. Both Tb(2)-O(5) bond lengths are 2.34 Å. Both Tb(2)-O(6) bond lengths are 2.43 Å. Both Tb(2)-O(7) bond lengths are 2.77 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(19), one C(2), and one C(6) atom. The C(1)-C(19) bond length is 1.46 Å. The C(1)-C(2) bond length is 1.27 Å. The C(1)-C(6) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(2)-H(3) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(3)-C(4) bond length is 1.49 Å. The C(3)-H(4) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.31 Å. The C(4)-C(7) bond length is 1.52 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(20), one C(4), and one C(6) atom. The C(5)-C(20) bond length is 1.49 Å. The C(5)-C(6) bond length is 1.41 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(5) atom. The C(6)-H(5) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(4), and one C(8) atom. The C(7)-C(12) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.36 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(10)-C(11) bond length is 1.31 Å. The C(10)-H(8) bond length is 0.92 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(13) atom. The C(11)-C(12) bond length is 1.34 Å. The C(11)-C(13) bond length is 1.49 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(7), and one H(9) atom. The C(12)-H(9) bond length is 0.93 Å. In the twelfth C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(18) atom. The C(13)-C(14) bond length is 1.46 Å. The C(13)-C(18) bond length is 1.30 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(14)-H(10) bond length is 0.93 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(15)-C(16) bond length is 1.29 Å. The C(15)-H(11) bond length is 0.93 Å. In the fifteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(22) atom. The C(16)-C(17) bond length is 1.37 Å. The C(16)-C(22) bond length is 1.50 Å. In the sixteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(12) atom. The C(17)-C(18) bond length is 1.44 Å. The C(17)-H(12) bond length is 0.93 Å. In the seventeenth C site, C(18) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(21) atom. The C(18)-C(21) bond length is 1.53 Å. In the eighteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(19)-O(1) bond length is 1.31 Å. The C(19)-O(2) bond length is 1.33 Å. In the nineteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(4), and one O(5) atom. The C(20)-O(4) bond length is 1.23 Å. The C(20)-O(5) bond length is 1.22 Å. In the twentieth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(6), and one O(7) atom. The C(21)-O(6) bond length is 1.27 Å. The C(21)-O(7) bond length is 1.24 Å. In the twenty-first C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(8), and one O(9) atom. The C(22)-O(8) bond length is 1.38 Å. The C(22)-O(9) bond length is 1.30 Å. In the twenty-second C site, C(23) is bonded in a trigonal planar geometry to one H(15) and two equivalent O(10) atoms. The C(23)-H(15) bond length is 0.93 Å. Both C(23)-O(10) bond lengths are 1.15 Å. There are fourteen inequivalent H sites. In the first H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the second H site, H(1) is bonded in a single-bond geometry to one O(3) atom. The H(1)-O(3) bond length is 0.89 Å. In the third H site, H(2) is bonded in a 2-coordinate geometry to one O(11) and one O(3) atom. The H(2)-O(11) bond length is 0.74 Å. The H(2)-O(3) bond length is 0.82 Å. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one O(11) atom. The H(13)-O(11) bond length is 0.81 Å. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one O(3) atom. The H(14)-O(3) bond length is 0.71 Å. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Tb(1), one Tb(2), and one C(19) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Tb(1) and one C(19) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Tb(1), one H(1), one H(14), and one H(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Tb(1) and one C(20) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Tb(2) and one C(20) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Tb(2) and one C(21) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Tb(1), one Tb(2), and one C(21) atom. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one Tb(1) and one C(22) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Tb(1) and one C(22) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Tb(1) and one C(23) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Tb(1), one H(13), and one H(2) atom. Linkers: 16 [O]C(=O)c1ccc(-c2cccc(-c3ccc(C([O])=O)cc3C([O])=O)c2)c(C([O])=O)c1. Metal clusters: 24 [Tb]. The MOF has largest included sphere 7.14 A, density 1.45 g/cm3, surface area 2952.37 m2/g, accessible volume 0.36 cm3/g