ZnC19N4H12O5(CH)4(C3NH2)2C2NHO is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, eight n-methylformamide molecules, eight schembl20201198 molecules, and eight ZnC19N4H12O5 clusters. In each ZnC19N4H12O5 cluster, Zn(1) is bonded in a 5-coordinate geometry to one N(1), one N(4), one O(1), one O(2), and one O(4) atom. The Zn(1)-N(1) bond length is 2.07 Å. The Zn(1)-N(4) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 2.07 Å. The Zn(1)-O(2) bond length is 2.36 Å. The Zn(1)-O(4) bond length is 1.99 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(1)-C(2) bond length is 1.47 Å. The C(1)-O(3) bond length is 1.24 Å. The C(1)-O(4) bond length is 1.23 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(8) is bonded in a bent 120 degrees geometry to one C(9), one O(1), and one O(2) atom. The C(8)-C(9) bond length is 1.49 Å. The C(8)-O(1) bond length is 1.26 Å. The C(8)-O(2) bond length is 1.25 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-C(14) bond length is 1.39 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(10)-H(5) bond length is 0.93 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. In the ninth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(16)-N(1) bond length is 1.35 Å. The C(16)-H(9) bond length is 0.93 Å. In the tenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(12) atom. The C(20)-N(1) bond length is 1.35 Å. The C(20)-H(12) bond length is 0.93 Å. In the eleventh C site, C(21) is bonded in a distorted trigonal planar geometry to one C(26), one N(3), and one O(6) atom. The C(21)-C(26) bond length is 1.45 Å. The C(21)-N(3) bond length is 1.36 Å. The C(21)-O(6) bond length is 1.26 Å. In the twelfth C site, C(22) is bonded in a distorted single-bond geometry to one N(5) atom. The C(22)-N(5) bond length is 1.33 Å. In the thirteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(26) and one H(15) atom. The C(25)-C(26) bond length is 1.38 Å. The C(25)-H(15) bond length is 0.93 Å. In the fourteenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(21), one C(25), and one N(5) atom. The C(26)-N(5) bond length is 1.35 Å. In the fifteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(16) atom. The C(27)-N(4) bond length is 1.31 Å. The C(27)-H(16) bond length is 0.93 Å. In the sixteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(29) and one H(17) atom. The C(28)-C(29) bond length is 1.39 Å. The C(28)-H(17) bond length is 0.93 Å. In the seventeenth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one C(30), and one N(3) atom. The C(29)-C(30) bond length is 1.39 Å. The C(29)-N(3) bond length is 1.39 Å. In the eighteenth C site, C(30) is bonded in a distorted single-bond geometry to one C(29), one C(31), and one H(18) atom. The C(30)-C(31) bond length is 1.36 Å. The C(30)-H(18) bond length is 0.93 Å. In the nineteenth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(30), one N(4), and one H(19) atom. The C(31)-N(4) bond length is 1.36 Å. The C(31)-H(19) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(16), and one C(20) atom. In the second N site, N(3) is bonded in a distorted trigonal planar geometry to one C(21), one C(29), and one H(20) atom. The N(3)-H(20) bond length is 0.85 Å. In the third N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(27), and one C(31) atom. In the fourth N site, N(5) is bonded in a bent 120 degrees geometry to one C(22) and one C(26) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(28) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(31) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one N(3) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Zn(1) and one C(8) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Zn(1) and one C(8) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the fifth O site, O(6) is bonded in a single-bond geometry to one C(21) atom. Linkers: 5 [O]C(=O)c1ccc([N][N]c2ccc(C([O])=O)cc2)cc1 ,8 O=C(Nc1ccncc1)c1cccc(C(=O)Nc2ccncc2)n1 ,4 [O]C(=O)c1ccc(/N=N/c2ccc(C([O])=O)cc2)cc1. Metal clusters: 8 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 7.77 A, density 1.00 g/cm3, surface area 4786.28 m2/g, accessible volume 0.47 cm3/g