RuAg2C16H16(N4Cl)2 crystallizes in the monoclinic P2_1/c space group. Ru(1) is bonded in an octahedral geometry to one N(2), one N(3), one N(5), one N(7), one Cl(1), and one Cl(2) atom. The Ru(1)-N(2) bond length is 2.06 Å. The Ru(1)-N(3) bond length is 2.05 Å. The Ru(1)-N(5) bond length is 2.06 Å. The Ru(1)-N(7) bond length is 2.08 Å. The Ru(1)-Cl(1) bond length is 2.39 Å. The Ru(1)-Cl(2) bond length is 2.40 Å. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal non-coplanar geometry to one N(4), one N(6), and one Cl(2) atom. The Ag(1)-N(4) bond length is 2.33 Å. The Ag(1)-N(6) bond length is 2.29 Å. The Ag(1)-Cl(2) bond length is 2.50 Å. In the second Ag site, Ag(2) is bonded in a trigonal planar geometry to one N(1), one N(8), and one Cl(1) atom. The Ag(2)-N(1) bond length is 2.31 Å. The Ag(2)-N(8) bond length is 2.29 Å. The Ag(2)-Cl(1) bond length is 2.53 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(2), and one H(1) atom. The C(1)-C(4) bond length is 1.39 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(3), and one H(2) atom. The C(2)-C(12) bond length is 1.39 Å. The C(2)-N(3) bond length is 1.34 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(5), and one H(3) atom. The C(3)-C(13) bond length is 1.37 Å. The C(3)-N(5) bond length is 1.34 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one H(4) atom. The C(4)-N(1) bond length is 1.32 Å. The C(4)-H(4) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(4), and one H(5) atom. The C(5)-C(6) bond length is 1.38 Å. The C(5)-N(4) bond length is 1.30 Å. The C(5)-H(5) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(3), and one H(6) atom. The C(6)-N(3) bond length is 1.36 Å. The C(6)-H(6) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(7), and one H(7) atom. The C(7)-C(16) bond length is 1.34 Å. The C(7)-N(7) bond length is 1.34 Å. The C(7)-H(7) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(5), and one H(8) atom. The C(8)-C(14) bond length is 1.36 Å. The C(8)-N(5) bond length is 1.34 Å. The C(8)-H(8) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(2), and one H(9) atom. The C(9)-C(11) bond length is 1.34 Å. The C(9)-N(2) bond length is 1.35 Å. The C(9)-H(9) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(7), and one H(10) atom. The C(10)-C(15) bond length is 1.39 Å. The C(10)-N(7) bond length is 1.33 Å. The C(10)-H(10) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(11) atom. The C(11)-N(1) bond length is 1.32 Å. The C(11)-H(11) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(2), one N(4), and one H(12) atom. The C(12)-N(4) bond length is 1.33 Å. The C(12)-H(12) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(3), one N(6), and one H(13) atom. The C(13)-N(6) bond length is 1.34 Å. The C(13)-H(13) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(8), one N(6), and one H(14) atom. The C(14)-N(6) bond length is 1.33 Å. The C(14)-H(14) bond length is 0.93 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(10), one N(8), and one H(15) atom. The C(15)-N(8) bond length is 1.31 Å. The C(15)-H(15) bond length is 0.93 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(7), one N(8), and one H(16) atom. The C(16)-N(8) bond length is 1.33 Å. The C(16)-H(16) bond length is 0.93 Å. There are eight inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Ag(1), one C(12), and one C(5) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Ru(1), one C(3), and one C(8) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Ag(1), one C(13), and one C(14) atom. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one Ru(1), one C(10), and one C(7) atom. In the fifth N site, N(8) is bonded in a trigonal planar geometry to one Ag(2), one C(15), and one C(16) atom. In the sixth N site, N(1) is bonded in a trigonal planar geometry to one Ag(2), one C(11), and one C(4) atom. In the seventh N site, N(2) is bonded in a trigonal planar geometry to one Ru(1), one C(1), and one C(9) atom. In the eighth N site, N(3) is bonded in a trigonal planar geometry to one Ru(1), one C(2), and one C(6) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a bent 150 degrees geometry to one Ru(1) and one Ag(2) atom. In the second Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one Ru(1) and one Ag(1) atom. Linkers: 16 c1cnccn1. Metal clusters: 4 Cl[Ru]Cl.[Ag].[Ag]. The MOF has largest included sphere 6.47 A, density 1.18 g/cm3, surface area 3216.56 m2/g, accessible volume 0.53 cm3/g