ZnC12H8(NO2)2(C5NH6)2C6H4SO2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 1,4-bis(prop-1-en-2-yl)piperazine molecules; sixteen di-isopropenylsulfon molecules; sixteen n,n-dimethylprop-1-en-2-amine molecules; and sixteen ZnC12H8(NO2)2 clusters. In four of the ZnC12H8(NO2)2 clusters, Zn(2) is bonded in a tetrahedral geometry to two equivalent N(4) and two equivalent O(1) atoms. Both Zn(2)-N(4) bond lengths are 2.02 Å. Both Zn(2)-O(1) bond lengths are 1.94 Å. There are six inequivalent C sites. In the first C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(17,39) atom. The C(17)-C(16) bond length is 1.39 Å. The C(17)-H(17,39) bond length is 0.95 Å. In the second C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(20) atom. The C(21)-C(16) bond length is 1.39 Å. The C(21)-H(20) bond length is 0.95 Å. In the third C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(14) atom. The C(12)-N(4) bond length is 1.34 Å. The C(12)-H(14) bond length is 0.95 Å. In the fourth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(15) atom. The C(13)-N(4) bond length is 1.35 Å. The C(13)-H(15) bond length is 0.95 Å. In the fifth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(1), and one O(2) atom. The C(15)-C(16) bond length is 1.53 Å. The C(15)-O(1) bond length is 1.27 Å. The C(15)-O(2) bond length is 1.22 Å. In the sixth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. N(4) is bonded in a trigonal planar geometry to one Zn(2), one C(12), and one C(13) atom. There are four inequivalent H sites. In the first H site, H(17,39) is bonded in a single-bond geometry to one C(17) atom. In the second H site, H(20) is bonded in a single-bond geometry to one C(21) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(15) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(15) atom. In four of the ZnC12H8(NO2)2 clusters, Zn(3) is bonded in a tetrahedral geometry to two equivalent N(8) and two equivalent O(11) atoms. Both Zn(3)-N(8) bond lengths are 2.05 Å. Both Zn(3)-O(11) bond lengths are 1.97 Å. There are six inequivalent C sites. In the first C site, C(49) is bonded in a distorted bent 120 degrees geometry to one C(46), one O(11), and one O(12) atom. The C(49)-C(46) bond length is 1.50 Å. The C(49)-O(11) bond length is 1.28 Å. The C(49)-O(12) bond length is 1.25 Å. In the second C site, C(50) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(41) atom. The C(50)-N(8) bond length is 1.32 Å. The C(50)-H(41) bond length is 0.95 Å. In the third C site, C(54) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(44) atom. The C(54)-N(8) bond length is 1.33 Å. The C(54)-H(44) bond length is 0.95 Å. In the fourth C site, C(45) is bonded in a distorted single-bond geometry to one C(46) and one H(38) atom. The C(45)-C(46) bond length is 1.37 Å. The C(45)-H(38) bond length is 0.95 Å. In the fifth C site, C(46) is bonded in a trigonal planar geometry to one C(45), one C(47), and one C(49) atom. The C(46)-C(47) bond length is 1.40 Å. In the sixth C site, C(47) is bonded in a distorted single-bond geometry to one C(46) and one H(17,39) atom. The C(47)-H(17,39) bond length is 0.95 Å. N(8) is bonded in a trigonal planar geometry to one Zn(3), one C(50), and one C(54) atom. There are four inequivalent H sites. In the first H site, H(17,39) is bonded in a single-bond geometry to one C(17) atom. In the second H site, H(38) is bonded in a single-bond geometry to one C(45) atom. In the third H site, H(41) is bonded in a single-bond geometry to one C(50) atom. In the fourth H site, H(44) is bonded in a single-bond geometry to one C(54) atom. There are two inequivalent O sites. In the first O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(49) atom. In the second O site, O(12) is bonded in a single-bond geometry to one C(49) atom. In eight of the ZnC12H8(NO2)2 clusters, Zn(1) is bonded in a 6-coordinate geometry to one N(1), one N(5), one O(5), one O(6), one O(7), and one O(8) atom. The Zn(1)-N(1) bond length is 2.05 Å. The Zn(1)-N(5) bond length is 2.05 Å. The Zn(1)-O(5) bond length is 2.37 Å. The Zn(1)-O(6) bond length is 2.07 Å. The Zn(1)-O(7) bond length is 2.40 Å. The Zn(1)-O(8) bond length is 2.05 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(28) atom. The C(25)-C(24) bond length is 1.38 Å. The C(25)-C(26) bond length is 1.38 Å. The C(25)-C(28) bond length is 1.50 Å. In the fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(22) atom. The C(24)-H(22) bond length is 0.95 Å. In the fifth C site, C(28) is bonded in a bent 120 degrees geometry to one C(25), one O(5), and one O(6) atom. The C(28)-O(5) bond length is 1.26 Å. The C(28)-O(6) bond length is 1.25 Å. In the sixth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(25) atom. The C(29)-N(5) bond length is 1.33 Å. The C(29)-H(25) bond length is 0.95 Å. In the seventh C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(23) atom. The C(26)-H(23) bond length is 0.95 Å. In the eighth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(28) atom. The C(33)-N(5) bond length is 1.35 Å. The C(33)-H(28) bond length is 0.95 Å. In the ninth C site, C(36) is bonded in a bent 120 degrees geometry to one C(37), one O(7), and one O(8) atom. The C(36)-C(37) bond length is 1.52 Å. The C(36)-O(7) bond length is 1.23 Å. The C(36)-O(8) bond length is 1.27 Å. In the tenth C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one C(42) atom. The C(37)-C(38) bond length is 1.39 Å. The C(37)-C(42) bond length is 1.38 Å. In the eleventh C site, C(38) is bonded in a distorted single-bond geometry to one C(37) and one H(33,36) atom. The C(38)-H(33,36) bond length is 0.95 Å. In the twelfth C site, C(42) is bonded in a distorted single-bond geometry to one C(37) and one H(33,36) atom. The C(42)-H(33,36) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Zn(1), one C(29), and one C(33) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(23) is bonded in a single-bond geometry to one C(26) atom. In the fourth H site, H(25) is bonded in a single-bond geometry to one C(29) atom. In the fifth H site, H(28) is bonded in a single-bond geometry to one C(33) atom. In the sixth H site, H(33,36) is bonded in a single-bond geometry to one C(38) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one C(24) atom. There are four inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Zn(1) and one C(28) atom. In the second O site, O(6) is bonded in an L-shaped geometry to one Zn(1) and one C(28) atom. In the third O site, O(7) is bonded in a distorted single-bond geometry to one Zn(1) and one C(36) atom. In the fourth O site, O(8) is bonded in an L-shaped geometry to one Zn(1) and one C(36) atom. Linkers: 16 c1cc(N2CCN(c3ccncc3)CC2)ccn1 ,16 [O]C(=O)c1ccc(S(=O)(=O)c2ccc(C([O])=O)cc2)cc1. Metal clusters: 16 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 5.00 A, density 1.36 g/cm3, surface area 4592.81 m2/g, accessible volume 0.28 cm3/g