AgH10(C2N)4(CH2)2 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and eight AgH10(C2N)4 clusters. In each AgH10(C2N)4 cluster, Ag(1) is bonded in a linear geometry to one N(1) and one N(3) atom. The Ag(1)-N(1) bond length is 2.11 Å. The Ag(1)-N(3) bond length is 2.10 Å. There are eight inequivalent C sites. In the first C site, C(9) is bonded in a 3-coordinate geometry to one N(4) and two equivalent H(11,12) atoms. The C(9)-N(4) bond length is 1.45 Å. Both C(9)-H(11,12) bond lengths are 0.97 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.93 Å. In the third C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.35 Å. The C(2)-N(1) bond length is 1.37 Å. The C(2)-H(2) bond length is 0.93 Å. In the fourth C site, C(3) is bonded in a 2-coordinate geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.38 Å. The C(3)-H(3) bond length is 0.93 Å. In the fifth C site, C(4) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(4,5) atoms. The C(4)-N(2) bond length is 1.48 Å. Both C(4)-H(4,5) bond lengths are 0.97 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(8) atom. The C(6)-N(3) bond length is 1.32 Å. The C(6)-N(4) bond length is 1.34 Å. The C(6)-H(8) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a 3-coordinate geometry to one C(8), one N(3), and one H(9) atom. The C(7)-C(8) bond length is 1.35 Å. The C(7)-N(3) bond length is 1.37 Å. The C(7)-H(9) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a 3-coordinate geometry to one C(7), one N(4), and one H(10) atom. The C(8)-N(4) bond length is 1.37 Å. The C(8)-H(10) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(6), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4,5) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(11,12) is bonded in a single-bond geometry to one C(9) atom. Linkers: 8 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 8 [Ag]. The MOF has largest included sphere 4.83 A, density 1.27 g/cm3, surface area 4522.59 m2/g, accessible volume 0.39 cm3/g