Cd6C43N24H45(CH3)5 crystallizes in the triclinic P1 space group. The structure consists of five 02329_fluka molecules inside a Cd6C43N24H45 framework. In the Cd6C43N24H45 framework, there are six inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a tetrahedral geometry to one N(1), one N(22), one N(24), and one N(3) atom. The Cd(1)-N(1) bond length is 2.20 Å. The Cd(1)-N(22) bond length is 2.20 Å. The Cd(1)-N(24) bond length is 2.20 Å. The Cd(1)-N(3) bond length is 2.20 Å. In the second Cd site, Cd(2) is bonded in a tetrahedral geometry to one N(2), one N(21), one N(23), and one N(4) atom. The Cd(2)-N(2) bond length is 2.20 Å. The Cd(2)-N(21) bond length is 2.20 Å. The Cd(2)-N(23) bond length is 2.20 Å. The Cd(2)-N(4) bond length is 2.20 Å. In the third Cd site, Cd(3) is bonded in a tetrahedral geometry to one N(18), one N(20), one N(5), and one N(7) atom. The Cd(3)-N(18) bond length is 2.20 Å. The Cd(3)-N(20) bond length is 2.20 Å. The Cd(3)-N(5) bond length is 2.20 Å. The Cd(3)-N(7) bond length is 2.20 Å. In the fourth Cd site, Cd(4) is bonded in a tetrahedral geometry to one N(17), one N(19), one N(6), and one N(8) atom. The Cd(4)-N(17) bond length is 2.20 Å. The Cd(4)-N(19) bond length is 2.20 Å. The Cd(4)-N(6) bond length is 2.20 Å. The Cd(4)-N(8) bond length is 2.20 Å. In the fifth Cd site, Cd(5) is bonded in a tetrahedral geometry to one N(10,16); one N(11); one N(12,14); and one N(9) atom. The Cd(5)-N(10,16) bond length is 2.20 Å. The Cd(5)-N(11) bond length is 2.20 Å. The Cd(5)-N(12,14) bond length is 2.20 Å. The Cd(5)-N(9) bond length is 2.20 Å. In the sixth Cd site, Cd(6) is bonded in a tetrahedral geometry to one N(10,16); one N(12,14); one N(13); and one N(15) atom. The Cd(6)-N(10,16) bond length is 2.20 Å. The Cd(6)-N(12,14) bond length is 2.20 Å. The Cd(6)-N(13) bond length is 2.20 Å. The Cd(6)-N(15) bond length is 2.20 Å. There are thirty-two inequivalent C sites. In the first C site, C(1) is bonded in a 2-coordinate geometry to one N(1) and one H(1,3,9,10,15,16,20,21) atom. The C(1)-N(1) bond length is 1.37 Å. The C(1)-H(1,3,9,10,15,16,20,21) bond length is 1.14 Å. In the second C site, C(2,19) is bonded in a 2-coordinate geometry to one N(2) and one H(2) atom. The C(2,19)-N(2) bond length is 1.37 Å. The C(2,19)-H(2) bond length is 1.14 Å. In the third C site, C(3) is bonded in a 2-coordinate geometry to one N(3) and one H(1,3,9,10,15,16,20,21) atom. The C(3)-N(3) bond length is 1.37 Å. The C(3)-H(1,3,9,10,15,16,20,21) bond length is 1.14 Å. In the fourth C site, C(4,6,17,21) is bonded in a 2-coordinate geometry to one N(4) and one H(4,17) atom. The C(4,6,17,21)-N(4) bond length is 1.37 Å. The C(4,6,17,21)-H(4,17) bond length is 1.14 Å. In the fifth C site, C(5) is bonded in a 2-coordinate geometry to one N(5) and one H(5,6,7,12,14,22) atom. The C(5)-N(5) bond length is 1.37 Å. The C(5)-H(5,6,7,12,14,22) bond length is 1.14 Å. In the sixth C site, C(7) is bonded in a 2-coordinate geometry to one N(7) and one H(5,6,7,12,14,22) atom. The C(7)-N(7) bond length is 1.37 Å. The C(7)-H(5,6,7,12,14,22) bond length is 1.14 Å. In the seventh C site, C(8) is bonded in a 2-coordinate geometry to one N(8) and one H(8,24) atom. The C(8)-N(8) bond length is 1.37 Å. The C(8)-H(8,24) bond length is 1.14 Å. In the eighth C site, C(9,15) is bonded in a 2-coordinate geometry to one N(9) and one H(1,3,9,10,15,16,20,21) atom. The C(9,15)-N(9) bond length is 1.37 Å. The C(9,15)-H(1,3,9,10,15,16,20,21) bond length is 1.14 Å. In the ninth C site, C(10,16) is bonded in a 2-coordinate geometry to one N(10,16) and one H(1,3,9,10,15,16,20,21) atom. The C(10,16)-N(10,16) bond length is 1.37 Å. The C(10,16)-H(1,3,9,10,15,16,20,21) bond length is 1.14 Å. In the tenth C site, C(11,13) is bonded in a 2-coordinate geometry to one N(11) and one H(11,13) atom. The C(11,13)-N(11) bond length is 1.37 Å. The C(11,13)-H(11,13) bond length is 1.14 Å. In the eleventh C site, C(12,14) is bonded in a 2-coordinate geometry to one N(12,14) and one H(5,6,7,12,14,22) atom. The C(12,14)-N(12,14) bond length is 1.37 Å. The C(12,14)-H(5,6,7,12,14,22) bond length is 1.14 Å. In the twelfth C site, C(18) is bonded in a 2-coordinate geometry to one N(18) and one H(18,23) atom. The C(18)-N(18) bond length is 1.37 Å. The C(18)-H(18,23) bond length is 1.14 Å. In the thirteenth C site, C(20) is bonded in a 2-coordinate geometry to one N(20) and one H(1,3,9,10,15,16,20,21) atom. The C(20)-N(20) bond length is 1.37 Å. The C(20)-H(1,3,9,10,15,16,20,21) bond length is 1.14 Å. In the fourteenth C site, C(22) is bonded in a 2-coordinate geometry to one N(22) and one H(5,6,7,12,14,22) atom. The C(22)-N(22) bond length is 1.37 Å. The C(22)-H(5,6,7,12,14,22) bond length is 1.14 Å. In the fifteenth C site, C(23) is bonded in a 2-coordinate geometry to one N(23) and one H(18,23) atom. The C(23)-N(23) bond length is 1.37 Å. The C(23)-H(18,23) bond length is 1.14 Å. In the sixteenth C site, C(24) is bonded in a 2-coordinate geometry to one N(24) and one H(8,24) atom. The C(24)-N(24) bond length is 1.37 Å. The C(24)-H(8,24) bond length is 1.14 Å. In the seventeenth C site, C(25,47) is bonded in a trigonal non-coplanar geometry to one C(26) and three equivalent H(25,26,27,58,59,60) atoms. The C(25,47)-C(26) bond length is 1.58 Å. All C(25,47)-H(25,26,27,58,59,60) bond lengths are 1.14 Å. In the eighteenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25,47); one N(1); and one N(12,14) atom. The C(26)-N(1) bond length is 1.28 Å. The C(26)-N(12,14) bond length is 1.28 Å. In the nineteenth C site, C(27) is bonded in a trigonal non-coplanar geometry to one C(28,46) and three equivalent H(28,29,30,55,56,57) atoms. The C(27)-C(28,46) bond length is 1.58 Å. All C(27)-H(28,29,30,55,56,57) bond lengths are 1.14 Å. In the twentieth C site, C(28,46) is bonded in a distorted trigonal planar geometry to one C(27), one N(13), and one N(2) atom. The C(28,46)-N(13) bond length is 1.28 Å. The C(28,46)-N(2) bond length is 1.28 Å. In the twenty-first C site, C(29) is bonded in a trigonal non-coplanar geometry to one C(30) and three equivalent H(31,32,33,49,50,51) atoms. The C(29)-C(30) bond length is 1.58 Å. All C(29)-H(31,32,33,49,50,51) bond lengths are 1.14 Å. In the twenty-second C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one N(15), and one N(3) atom. The C(30)-N(15) bond length is 1.28 Å. The C(30)-N(3) bond length is 1.28 Å. In the twenty-third C site, C(32,44) is bonded in a distorted bent 120 degrees geometry to one N(10,16) and one N(4) atom. The C(32,44)-N(10,16) bond length is 1.28 Å. The C(32,44)-N(4) bond length is 1.28 Å. In the twenty-fourth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one N(22) and one N(5) atom. The C(34)-N(22) bond length is 1.28 Å. The C(34)-N(5) bond length is 1.28 Å. In the twenty-fifth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one N(21) and one N(6) atom. The C(36)-N(21) bond length is 1.28 Å. The C(36)-N(6) bond length is 1.28 Å. In the twenty-sixth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one N(23) and one N(7) atom. The C(38)-N(23) bond length is 1.28 Å. The C(38)-N(7) bond length is 1.28 Å. In the twenty-seventh C site, C(39) is bonded in a trigonal non-coplanar geometry to one C(40) and three equivalent H(46,47,48) atoms. The C(39)-C(40) bond length is 1.58 Å. All C(39)-H(46,47,48) bond lengths are 1.14 Å. In the twenty-eighth C site, C(40) is bonded in a distorted trigonal planar geometry to one C(39), one N(24), and one N(8) atom. The C(40)-N(24) bond length is 1.28 Å. The C(40)-N(8) bond length is 1.28 Å. In the twenty-ninth C site, C(41) is bonded in a trigonal non-coplanar geometry to one C(42) and three equivalent H(31,32,33,49,50,51) atoms. The C(41)-C(42) bond length is 1.58 Å. All C(41)-H(31,32,33,49,50,51) bond lengths are 1.14 Å. In the thirtieth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(41), one N(18), and one N(9) atom. The C(42)-N(18) bond length is 1.28 Å. The C(42)-N(9) bond length is 1.28 Å. In the thirty-first C site, C(45) is bonded in a trigonal non-coplanar geometry to one C(28,46) and three equivalent H(28,29,30,55,56,57) atoms. The C(45)-C(28,46) bond length is 1.58 Å. All C(45)-H(28,29,30,55,56,57) bond lengths are 1.14 Å. In the thirty-second C site, C(48) is bonded in a distorted trigonal planar geometry to one C(25,47); one N(12,14); and one N(20) atom. The C(48)-C(25,47) bond length is 1.58 Å. The C(48)-N(12,14) bond length is 1.28 Å. The C(48)-N(20) bond length is 1.28 Å. There are twenty-two inequivalent N sites. In the first N site, N(15) is bonded in a distorted trigonal planar geometry to one Cd(6); one C(30); and one C(9,15) atom. The N(15)-C(9,15) bond length is 1.37 Å. In the second N site, N(17) is bonded in a distorted trigonal planar geometry to one Cd(4); one C(32,44); and one C(4,6,17,21) atom. The N(17)-C(32,44) bond length is 1.28 Å. The N(17)-C(4,6,17,21) bond length is 1.37 Å. In the third N site, N(18) is bonded in a distorted trigonal planar geometry to one Cd(3), one C(18), and one C(42) atom. In the fourth N site, N(20) is bonded in a distorted trigonal planar geometry to one Cd(3), one C(20), and one C(48) atom. In the fifth N site, N(21) is bonded in a distorted trigonal planar geometry to one Cd(2); one C(36); and one C(4,6,17,21) atom. The N(21)-C(4,6,17,21) bond length is 1.37 Å. In the sixth N site, N(23) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(23), and one C(38) atom. In the seventh N site, N(24) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(24), and one C(40) atom. In the eighth N site, N(19) is bonded in a distorted trigonal planar geometry to one Cd(4); one C(2,19); and one C(28,46) atom. The N(19)-C(2,19) bond length is 1.37 Å. The N(19)-C(28,46) bond length is 1.28 Å. In the ninth N site, N(22) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(22), and one C(34) atom. In the tenth N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(26) atom. In the eleventh N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(2); one C(2,19); and one C(28,46) atom. In the twelfth N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(3), and one C(30) atom. In the thirteenth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(2); one C(32,44); and one C(4,6,17,21) atom. In the fourteenth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cd(3), one C(34), and one C(5) atom. In the fifteenth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cd(4); one C(36); and one C(4,6,17,21) atom. The N(6)-C(4,6,17,21) bond length is 1.37 Å. In the sixteenth N site, N(7) is bonded in a distorted trigonal planar geometry to one Cd(3), one C(38), and one C(7) atom. In the seventeenth N site, N(8) is bonded in a distorted trigonal planar geometry to one Cd(4), one C(40), and one C(8) atom. In the eighteenth N site, N(9) is bonded in a distorted trigonal planar geometry to one Cd(5); one C(42); and one C(9,15) atom. In the nineteenth N site, N(10,16) is bonded in a distorted trigonal planar geometry to one Cd(6); one C(10,16); and one C(32,44) atom. In the twentieth N site, N(11) is bonded in a distorted trigonal planar geometry to one Cd(5); one C(11,13); and one C(28,46) atom. The N(11)-C(28,46) bond length is 1.28 Å. In the twenty-first N site, N(12,14) is bonded in a distorted trigonal planar geometry to one Cd(6); one C(12,14); and one C(48) atom. In the twenty-second N site, N(13) is bonded in a distorted trigonal planar geometry to one Cd(6); one C(11,13); and one C(28,46) atom. The N(13)-C(11,13) bond length is 1.37 Å. There are twelve inequivalent H sites. In the first H site, H(1,3,9,10,15,16,20,21) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2,19) atom. In the third H site, H(4,17) is bonded in a single-bond geometry to one C(4,6,17,21) atom. In the fourth H site, H(5,6,7,12,14,22) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(8,24) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(11,13) is bonded in a single-bond geometry to one C(11,13) atom. In the seventh H site, H(18,23) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(2,19) atom. The H(19)-C(2,19) bond length is 1.14 Å. In the ninth H site, H(25,26,27,58,59,60) is bonded in a single-bond geometry to one C(25,47) atom. In the tenth H site, H(28,29,30,55,56,57) is bonded in a single-bond geometry to one C(27) atom. In the eleventh H site, H(31,32,33,49,50,51) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(46,47,48) is bonded in a single-bond geometry to one C(39) atom. Linkers: 6 CC1=N[CH]C=N1 ,6 CC1=NC=C[N]1. Metal clusters: 6 [Cd]. The MOF has largest included sphere 12.69 A, density 0.92 g/cm3, surface area 4621.04 m2/g, accessible volume 0.72 cm3/g