CdC15H11(N3O2)2(CH)2 crystallizes in the monoclinic C2/c space group. The structure consists of sixteen 02329_fluka molecules inside a CdC15H11(N3O2)2 framework. In the CdC15H11(N3O2)2 framework, Cd(1) is bonded in a distorted square pyramidal geometry to one N(3), one N(6), one O(1), one O(2), and one O(3) atom. The Cd(1)-N(3) bond length is 2.30 Å. The Cd(1)-N(6) bond length is 2.29 Å. The Cd(1)-O(1) bond length is 2.40 Å. The Cd(1)-O(2) bond length is 2.34 Å. The Cd(1)-O(3) bond length is 2.27 Å. There are fifteen inequivalent C sites. In the first C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(3), and one O(4) atom. The C(17)-C(14) bond length is 1.51 Å. The C(17)-O(3) bond length is 1.27 Å. The C(17)-O(4) bond length is 1.24 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.38 Å. The C(1)-C(7) bond length is 1.50 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(8) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(8) bond length is 1.51 Å. In the fourth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a 3-coordinate geometry to one C(1), one N(1), one H(5), and one H(6) atom. The C(7)-N(1) bond length is 1.45 Å. The C(7)-H(5) bond length is 0.97 Å. The C(7)-H(6) bond length is 0.97 Å. In the seventh C site, C(8) is bonded in a 3-coordinate geometry to one C(2), one N(4), one H(7), and one H(8) atom. The C(8)-N(4) bond length is 1.48 Å. The C(8)-H(7) bond length is 0.97 Å. The C(8)-H(8) bond length is 0.97 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(9) atom. The C(9)-N(2) bond length is 1.32 Å. The C(9)-N(3) bond length is 1.32 Å. The C(9)-H(9) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(10) atom. The C(10)-N(1) bond length is 1.31 Å. The C(10)-N(3) bond length is 1.31 Å. The C(10)-H(10) bond length is 0.93 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(11) atom. The C(11)-N(5) bond length is 1.33 Å. The C(11)-N(6) bond length is 1.34 Å. The C(11)-H(11) bond length is 0.93 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(12) atom. The C(12)-N(4) bond length is 1.31 Å. The C(12)-N(6) bond length is 1.33 Å. The C(12)-H(12) bond length is 0.93 Å. In the twelfth C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(16) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(15) bond length is 1.39 Å. The C(13)-C(16) bond length is 1.49 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.37 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(13), one C(14), and one H(13) atom. The C(15)-H(13) bond length is 0.93 Å. In the fifteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(1), and one O(2) atom. The C(16)-O(1) bond length is 1.27 Å. The C(16)-O(2) bond length is 1.24 Å. There are six inequivalent N sites. In the first N site, N(6) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one C(12) atom. In the second N site, N(1) is bonded in a 2-coordinate geometry to one C(10), one C(7), and one N(2) atom. The N(1)-N(2) bond length is 1.37 Å. In the third N site, N(2) is bonded in a distorted water-like geometry to one C(9) and one N(1) atom. In the fourth N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one C(9) atom. In the fifth N site, N(4) is bonded in a 2-coordinate geometry to one C(12), one C(8), and one N(5) atom. The N(4)-N(5) bond length is 1.34 Å. In the sixth N site, N(5) is bonded in a distorted water-like geometry to one C(11) and one N(4) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(15) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(16) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(16) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(17) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(17) atom. Linkers: 7 c1ccc(Cn2cncn2)c(Cn2cncn2)c1 ,1 [CH]1N=C[N]N1Cc1ccccc1Cn1cncn1 ,4 [O]C(=O)c1cc(C([O])=O)c(C([O])=O)cc1C([O])=O. Metal clusters: 8 O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 4.20 A, density 1.36 g/cm3, surface area 4248.49 m2/g, accessible volume 0.26 cm3/g