LaC20N6H12O10Cl(CH)12(CH2)8 is Indium-derived structured and crystallizes in the tetragonal P4_12_12 space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules, thirty-two 02329_fluka molecules, and four LaC20N6H12O10Cl clusters. In each LaC20N6H12O10Cl cluster, La(1) is bonded in a 9-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), two equivalent O(5), and one Cl(1) atom. Both La(1)-O(1) bond lengths are 2.67 Å. Both La(1)-O(2) bond lengths are 2.46 Å. Both La(1)-O(3) bond lengths are 2.52 Å. Both La(1)-O(5) bond lengths are 2.62 Å. The La(1)-Cl(1) bond length is 2.87 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(3), and one H(15) atom. The C(1)-C(3) bond length is 1.42 Å. The C(1)-N(3) bond length is 1.30 Å. The C(1)-H(15) bond length is 0.93 Å. In the second C site, C(2) is bonded in a 2-coordinate geometry to one N(3) and one H(12) atom. The C(2)-N(3) bond length is 1.46 Å. The C(2)-H(12) bond length is 0.98 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(20), and one C(4) atom. The C(3)-C(20) bond length is 1.39 Å. The C(3)-C(4) bond length is 1.45 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one O(3) atom. The C(4)-O(3) bond length is 1.31 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(9) atom. The C(7)-C(12) bond length is 1.41 Å. The C(7)-C(14) bond length is 1.44 Å. The C(7)-C(9) bond length is 1.41 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(7) and one H(2) atom. The C(9)-H(2) bond length is 0.93 Å. In the seventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(1), and one H(9) atom. The C(12)-N(1) bond length is 1.30 Å. The C(12)-H(9) bond length is 0.93 Å. In the eighth C site, C(13) is bonded in a 2-coordinate geometry to one N(1) and one H(1) atom. The C(13)-N(1) bond length is 1.48 Å. The C(13)-H(1) bond length is 0.98 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(7) and one O(2) atom. The C(14)-O(2) bond length is 1.28 Å. In the tenth C site, C(20) is bonded in a distorted single-bond geometry to one C(3) and one H(13) atom. The C(20)-H(13) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(12) and one C(13) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one O(1), one O(4), and one O(5) atom. The N(2)-O(1) bond length is 1.24 Å. The N(2)-O(4) bond length is 1.31 Å. The N(2)-O(5) bond length is 1.27 Å. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(1) and one C(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(1) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one La(1) and one N(2) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one La(1) and one C(14) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one La(1) and one C(4) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one La(1) and one N(2) atom. Cl(1) is bonded in a single-bond geometry to one La(1) atom. Linkers: 8 [O]c1ccccc1/C=N/[C@@H]1CCCC[C@H]1/N=C/c1ccccc1[O]. Metal clusters: 4 [O]N1O[La]2([O])([O])([O])([O])(Cl)(O1)ON([O])O2. RCSR code: dia. The MOF has largest included sphere 5.26 A, density 1.15 g/cm3, surface area 4786.01 m2/g, accessible volume 0.33 cm3/g