CHCu4C17H9S2(N7O4)2 crystallizes in the trigonal R-3 space group. The structure consists of eighteen 02329_fluka molecules inside a Cu4C17H9S2(N7O4)2 framework. In the Cu4C17H9S2(N7O4)2 framework, there are four inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one N(11), one N(6), one N(9), one O(3), and one O(8) atom to form CuN3O2 square pyramids that share  a cornercorner with one S(1)O4 tetrahedra and  a cornercorner with one S(2)O4 tetrahedra. The Cu(1)-N(11) bond length is 2.03 Å. The Cu(1)-N(6) bond length is 1.98 Å. The Cu(1)-N(9) bond length is 1.99 Å. The Cu(1)-O(3) bond length is 1.98 Å. The Cu(1)-O(8) bond length is 2.22 Å. In the second Cu site, Cu(2) is bonded in a rectangular see-saw-like geometry to one N(12), one N(3), one N(5), and one O(6) atom. The Cu(2)-N(12) bond length is 1.93 Å. The Cu(2)-N(3) bond length is 1.97 Å. The Cu(2)-N(5) bond length is 2.05 Å. The Cu(2)-O(6) bond length is 1.96 Å. In the third Cu site, Cu(3) is bonded in a distorted rectangular see-saw-like geometry to one N(14), one N(7), one N(8), and one O(1) atom. The Cu(3)-N(14) bond length is 1.98 Å. The Cu(3)-N(7) bond length is 2.07 Å. The Cu(3)-N(8) bond length is 1.95 Å. The Cu(3)-O(1) bond length is 1.97 Å. In the fourth Cu site, Cu(4) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one O(5), and one O(7) atom. The Cu(4)-N(1) bond length is 2.06 Å. The Cu(4)-N(2) bond length is 1.97 Å. The Cu(4)-O(5) bond length is 1.96 Å. The Cu(4)-O(7) bond length is 1.96 Å. There are seventeen inequivalent C sites. In the first C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(4) bond length is 1.38 Å. The C(5)-C(6) bond length is 1.47 Å. The C(5)-N(1) bond length is 1.36 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(2), and one N(4) atom. The C(6)-N(2) bond length is 1.33 Å. The C(6)-N(4) bond length is 1.35 Å. In the third C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(3), and one N(4) atom. The C(7)-C(8) bond length is 1.45 Å. The C(7)-N(3) bond length is 1.35 Å. The C(7)-N(4) bond length is 1.33 Å. In the fourth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(14), and one N(5) atom. The C(8)-N(14) bond length is 1.34 Å. The C(8)-N(5) bond length is 1.32 Å. In the fifth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(5) atom. The C(9)-N(7) bond length is 1.36 Å. The C(9)-H(5) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(7) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(7) bond length is 0.93 Å. In the seventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(8) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-H(8) bond length is 0.93 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one N(7) atom. The C(13)-N(7) bond length is 1.33 Å. In the ninth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(10) and one N(8) atom. The C(14)-N(10) bond length is 1.34 Å. The C(14)-N(8) bond length is 1.33 Å. In the tenth C site, C(15) is bonded in a 3-coordinate geometry to one C(16), one N(10), and one N(9) atom. The C(15)-C(16) bond length is 1.45 Å. The C(15)-N(10) bond length is 1.33 Å. The C(15)-N(9) bond length is 1.33 Å. In the eleventh C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(11), and one N(13) atom. The C(16)-N(11) bond length is 1.34 Å. The C(16)-N(13) bond length is 1.33 Å. In the twelfth C site, C(17) is bonded in a trigonal planar geometry to one N(12), one N(13), and one H(9) atom. The C(17)-N(12) bond length is 1.33 Å. The C(17)-N(13) bond length is 1.35 Å. The C(17)-H(9) bond length is 0.93 Å. In the thirteenth C site, C(18) is bonded in a trigonal planar geometry to one N(14), one N(6), and one H(10) atom. The C(18)-N(14) bond length is 1.35 Å. The C(18)-N(6) bond length is 1.32 Å. The C(18)-H(10) bond length is 0.93 Å. In the fourteenth C site, C(1) is bonded in a 3-coordinate geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.93 Å. In the fifteenth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-H(2) bond length is 0.93 Å. In the sixteenth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(3)-H(3) bond length is 0.93 Å. In the seventeenth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-H(4) bond length is 0.93 Å. There are fourteen inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(4), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Cu(4), one C(6), and one N(3) atom. The N(2)-N(3) bond length is 1.35 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Cu(2), one C(7), and one N(2) atom. In the fourth N site, N(4) is bonded in a water-like geometry to one C(6) and one C(7) atom. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one Cu(2), one C(8), and one N(6) atom. The N(5)-N(6) bond length is 1.37 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(18), and one N(5) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Cu(3), one C(13), and one C(9) atom. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Cu(3), one C(14), and one N(9) atom. The N(8)-N(9) bond length is 1.36 Å. In the ninth N site, N(9) is bonded in a distorted bent 120 degrees geometry to one Cu(1), one C(15), and one N(8) atom. In the tenth N site, N(10) is bonded in a water-like geometry to one C(14) and one C(15) atom. In the eleventh N site, N(11) is bonded in a 3-coordinate geometry to one Cu(1), one C(16), and one N(12) atom. The N(11)-N(12) bond length is 1.36 Å. In the twelfth N site, N(12) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(17), and one N(11) atom. In the thirteenth N site, N(13) is bonded in a water-like geometry to one C(16) and one C(17) atom. In the fourteenth N site, N(14) is bonded in a distorted trigonal planar geometry to one Cu(3), one C(18), and one C(8) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded to one O(4), one O(5), one O(6), and one O(8) atom to form SO4 tetrahedra that share  a cornercorner with one Cu(1)N3O2 square pyramid. The S(1)-O(4) bond length is 1.46 Å. The S(1)-O(5) bond length is 1.49 Å. The S(1)-O(6) bond length is 1.49 Å. The S(1)-O(8) bond length is 1.46 Å. In the second S site, S(2) is bonded to one O(1), one O(2), one O(3), and one O(7) atom to form SO4 tetrahedra that share  a cornercorner with one Cu(1)N3O2 square pyramid. The S(2)-O(1) bond length is 1.48 Å. The S(2)-O(2) bond length is 1.44 Å. The S(2)-O(3) bond length is 1.48 Å. The S(2)-O(7) bond length is 1.48 Å. There are eight inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one S(1) atom. In the second O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one S(1) atom. In the third O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Cu(4) and one S(2) atom. In the fourth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one S(1) atom. In the fifth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one S(2) atom. In the sixth O site, O(2) is bonded in a single-bond geometry to one S(2) atom. In the seventh O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one S(2) atom. In the eighth O site, O(4) is bonded in a single-bond geometry to one S(1) atom. Linkers: 11 C1=NN=C(C2=NN=C(c3ccccn3)[N]2)[N]1. Metal clusters: 24 [Cu]. The MOF has largest included sphere 15.82 A, density 0.96 g/cm3, surface area 3323.67 m2/g, accessible volume 0.81 cm3/g