ZnC14H8(N3O2)2(CH)4 is Indium-derived structured and crystallizes in the orthorhombic Pbcn space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules and eight ZnC14H8(N3O2)2 clusters. In each ZnC14H8(N3O2)2 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to one N(2), one N(5), one O(2), and one O(3) atom. The Zn(1)-N(2) bond length is 2.04 Å. The Zn(1)-N(5) bond length is 2.01 Å. The Zn(1)-O(2) bond length is 1.94 Å. The Zn(1)-O(3) bond length is 1.95 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.28 Å. The C(1)-N(3) bond length is 1.37 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(2) atom. The C(2)-N(2) bond length is 1.31 Å. The C(2)-N(3) bond length is 1.33 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one N(3) atom. The C(3)-N(3) bond length is 1.43 Å. In the fourth C site, C(5) is bonded in a single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(4) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-C(9) bond length is 1.51 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 0.93 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(1), and one O(2) atom. The C(9)-O(1) bond length is 1.23 Å. The C(9)-O(2) bond length is 1.27 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(7) atom. The C(10)-N(5) bond length is 1.31 Å. The C(10)-N(6) bond length is 1.36 Å. The C(10)-H(7) bond length is 0.93 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(8) atom. The C(11)-N(4) bond length is 1.31 Å. The C(11)-N(6) bond length is 1.36 Å. The C(11)-H(8) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one N(6) atom. The C(12)-N(6) bond length is 1.44 Å. In the eleventh C site, C(14) is bonded in a single-bond geometry to one C(15) and one H(10) atom. The C(14)-C(15) bond length is 1.37 Å. The C(14)-H(10) bond length is 0.93 Å. In the twelfth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-C(18) bond length is 1.51 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(11) atom. The C(16)-H(11) bond length is 0.93 Å. In the fourteenth C site, C(18) is bonded in a bent 120 degrees geometry to one C(15), one O(3), and one O(4) atom. The C(18)-O(3) bond length is 1.27 Å. The C(18)-O(4) bond length is 1.23 Å. There are six inequivalent N sites. In the first N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(2), and one N(1) atom. The N(2)-N(1) bond length is 1.39 Å. In the second N site, N(1) is bonded in a distorted single-bond geometry to one C(1) and one N(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. In the fourth N site, N(4) is bonded in a distorted water-like geometry to one C(11) and one N(5) atom. The N(4)-N(5) bond length is 1.39 Å. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one Zn(1), one C(10), and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(12) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(9) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(18) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(18) atom. Linkers: 16 [O]C(=O)c1ccc(-n2cnnc2)cc1. Metal clusters: 8 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 6.94 A, density 1.11 g/cm3, surface area 4875.53 m2/g, accessible volume 0.41 cm3/g