FeCoAg2H52(C38N9)2(CH)8 crystallizes in the orthorhombic P2_12_12 space group. The structure consists of thirty-two 02329_fluka molecules inside a FeCoAg2H52(C38N9)2 framework. In each FeCoAg2H52(C38N9)2 framework, Fe(1) is bonded in an octahedral geometry to one N(1), one N(13), one N(14), one N(2), one N(7), and one N(8) atom. The Fe(1)-N(1) bond length is 1.94 Å. The Fe(1)-N(13) bond length is 1.95 Å. The Fe(1)-N(14) bond length is 1.96 Å. The Fe(1)-N(2) bond length is 1.95 Å. The Fe(1)-N(7) bond length is 1.96 Å. The Fe(1)-N(8) bond length is 1.94 Å. Co(1) is bonded in an octahedral geometry to one N(10), one N(11), one N(16), one N(17), one N(4), and one N(5) atom. The Co(1)-N(10) bond length is 1.94 Å. The Co(1)-N(11) bond length is 1.95 Å. The Co(1)-N(16) bond length is 1.96 Å. The Co(1)-N(17) bond length is 1.94 Å. The Co(1)-N(4) bond length is 1.95 Å. The Co(1)-N(5) bond length is 1.96 Å. Ag(1,2) is bonded in a trigonal planar geometry to one N(3,12); one N(6,15); and one N(9,18) atom. The Ag(1,2)-N(3,12) bond length is 2.25 Å. The Ag(1,2)-N(6,15) bond length is 2.25 Å. The Ag(1,2)-N(9,18) bond length is 2.24 Å. There are sixty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3,33) atom. The C(3)-C(4) bond length is 1.43 Å. The C(3)-H(3,33) bond length is 0.95 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-N(1) bond length is 1.39 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(10,52); one C(4); and one C(6) atom. The C(5)-C(10,52) bond length is 1.48 Å. The C(5)-C(6) bond length is 1.39 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.42 Å. The C(6)-N(2) bond length is 1.38 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6); one C(8); and one H(4,34) atom. The C(7)-C(8) bond length is 1.36 Å. The C(7)-H(4,34) bond length is 0.95 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7); one C(9); and one H(5,35) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-H(5,35) bond length is 0.95 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(2), and one H(6) atom. The C(9)-N(2) bond length is 1.34 Å. The C(9)-H(6) bond length is 0.95 Å. In the ninth C site, C(10,52) is bonded in a trigonal planar geometry to one C(11,53); one C(14,56); and one C(5) atom. The C(10,52)-C(11,53) bond length is 1.39 Å. The C(10,52)-C(14,56) bond length is 1.40 Å. In the tenth C site, C(11,53) is bonded in a distorted trigonal planar geometry to one C(10,52); one C(12,54); and one H(7,37) atom. The C(11,53)-C(12,54) bond length is 1.39 Å. The C(11,53)-H(7,37) bond length is 0.95 Å. In the eleventh C site, C(12,54) is bonded in a distorted bent 120 degrees geometry to one C(11,53); one N(3,12); and one H(8,38) atom. The C(12,54)-N(3,12) bond length is 1.32 Å. The C(12,54)-H(8,38) bond length is 0.95 Å. In the twelfth C site, C(13,55) is bonded in a distorted trigonal planar geometry to one C(14,56); one N(3,12); and one H(9,39) atom. The C(13,55)-C(14,56) bond length is 1.35 Å. The C(13,55)-N(3,12) bond length is 1.34 Å. The C(13,55)-H(9,39) bond length is 0.95 Å. In the thirteenth C site, C(14,56) is bonded in a distorted single-bond geometry to one C(10,52); one C(13,55); and one H(10,40) atom. The C(14,56)-H(10,40) bond length is 0.95 Å. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(11) atom. The C(15)-N(4) bond length is 1.35 Å. The C(15)-H(11) bond length is 0.95 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(13,43) atom. The C(17)-C(18) bond length is 1.42 Å. The C(17)-H(13,43) bond length is 0.95 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one N(4) atom. The C(18)-C(19) bond length is 1.38 Å. The C(18)-N(4) bond length is 1.40 Å. In the seventeenth C site, C(19) is bonded in a trigonal planar geometry to one C(18); one C(20); and one C(24,66) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-C(24,66) bond length is 1.50 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one N(5) atom. The C(20)-C(21) bond length is 1.42 Å. The C(20)-N(5) bond length is 1.39 Å. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(14,44) atom. The C(21)-H(14,44) bond length is 0.95 Å. In the twentieth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(16) atom. The C(23)-N(5) bond length is 1.31 Å. The C(23)-H(16) bond length is 0.95 Å. In the twenty-first C site, C(24,66) is bonded in a trigonal planar geometry to one C(19); one C(25,67); and one C(28,70) atom. The C(24,66)-C(25,67) bond length is 1.36 Å. The C(24,66)-C(28,70) bond length is 1.40 Å. In the twenty-second C site, C(25,67) is bonded in a distorted single-bond geometry to one C(24,66) and one H(17,47) atom. The C(25,67)-H(17,47) bond length is 0.95 Å. In the twenty-third C site, C(26,68) is bonded in a distorted bent 120 degrees geometry to one N(6,15) and one H(18,48) atom. The C(26,68)-N(6,15) bond length is 1.32 Å. The C(26,68)-H(18,48) bond length is 0.95 Å. In the twenty-fourth C site, C(27,69) is bonded in a distorted trigonal planar geometry to one C(28,70); one N(6,15); and one H(19,49) atom. The C(27,69)-C(28,70) bond length is 1.37 Å. The C(27,69)-N(6,15) bond length is 1.33 Å. The C(27,69)-H(19,49) bond length is 0.95 Å. In the twenty-fifth C site, C(28,70) is bonded in a distorted single-bond geometry to one C(24,66); one C(27,69); and one H(20,50) atom. The C(28,70)-H(20,50) bond length is 0.95 Å. In the twenty-sixth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(21) atom. The C(29)-N(7) bond length is 1.34 Å. The C(29)-H(21) bond length is 0.95 Å. In the twenty-seventh C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(23,53) atom. The C(31)-C(32) bond length is 1.41 Å. The C(31)-H(23,53) bond length is 0.95 Å. In the twenty-eighth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31), one C(33), and one N(7) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-N(7) bond length is 1.41 Å. In the twenty-ninth C site, C(33) is bonded in a trigonal planar geometry to one C(32); one C(34); and one C(38,80) atom. The C(33)-C(34) bond length is 1.39 Å. The C(33)-C(38,80) bond length is 1.49 Å. In the thirtieth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(33), one C(35), and one N(8) atom. The C(34)-C(35) bond length is 1.42 Å. The C(34)-N(8) bond length is 1.40 Å. In the thirty-first C site, C(35) is bonded in a distorted single-bond geometry to one C(34); one C(36); and one H(24,54) atom. The C(35)-C(36) bond length is 1.37 Å. The C(35)-H(24,54) bond length is 0.95 Å. In the thirty-second C site, C(36) is bonded in a distorted single-bond geometry to one C(35); one C(37); and one H(25,55) atom. The C(36)-C(37) bond length is 1.42 Å. The C(36)-H(25,55) bond length is 0.95 Å. In the thirty-third C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(36), one N(8), and one H(26) atom. The C(37)-N(8) bond length is 1.32 Å. The C(37)-H(26) bond length is 0.95 Å. In the thirty-fourth C site, C(38,80) is bonded in a trigonal planar geometry to one C(33); one C(39,81); and one C(42,84) atom. The C(38,80)-C(39,81) bond length is 1.38 Å. The C(38,80)-C(42,84) bond length is 1.38 Å. In the thirty-fifth C site, C(39,81) is bonded in a distorted single-bond geometry to one C(38,80); one C(40,82); and one H(27,57) atom. The C(39,81)-C(40,82) bond length is 1.39 Å. The C(39,81)-H(27,57) bond length is 0.95 Å. In the thirty-sixth C site, C(40,82) is bonded in a distorted trigonal planar geometry to one C(39,81); one N(9,18); and one H(28,58) atom. The C(40,82)-N(9,18) bond length is 1.32 Å. The C(40,82)-H(28,58) bond length is 0.95 Å. In the thirty-seventh C site, C(41,83) is bonded in a distorted bent 120 degrees geometry to one N(9,18) and one H(29,59) atom. The C(41,83)-N(9,18) bond length is 1.33 Å. The C(41,83)-H(29,59) bond length is 0.95 Å. In the thirty-eighth C site, C(42,84) is bonded in a distorted single-bond geometry to one C(38,80) and one H(30,60) atom. The C(42,84)-H(30,60) bond length is 0.95 Å. In the thirty-ninth C site, C(43) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(31) atom. The C(43)-N(10) bond length is 1.33 Å. The C(43)-H(31) bond length is 0.95 Å. In the fortieth C site, C(45) is bonded in a distorted single-bond geometry to one C(46) and one H(3,33) atom. The C(45)-C(46) bond length is 1.43 Å. The C(45)-H(3,33) bond length is 0.95 Å. In the forty-first C site, C(46) is bonded in a distorted trigonal planar geometry to one C(45), one C(47), and one N(10) atom. The C(46)-C(47) bond length is 1.40 Å. The C(46)-N(10) bond length is 1.39 Å. In the forty-second C site, C(47) is bonded in a trigonal planar geometry to one C(10,52); one C(46); and one C(48) atom. The C(47)-C(10,52) bond length is 1.48 Å. The C(47)-C(48) bond length is 1.39 Å. In the forty-third C site, C(48) is bonded in a distorted single-bond geometry to one C(47), one C(49), and one N(11) atom. The C(48)-C(49) bond length is 1.42 Å. The C(48)-N(11) bond length is 1.38 Å. In the forty-fourth C site, C(49) is bonded in a distorted single-bond geometry to one C(48); one C(50); and one H(4,34) atom. The C(49)-C(50) bond length is 1.36 Å. The C(49)-H(4,34) bond length is 0.95 Å. In the forty-fifth C site, C(50) is bonded in a distorted single-bond geometry to one C(49); one C(51); and one H(5,35) atom. The C(50)-C(51) bond length is 1.41 Å. The C(50)-H(5,35) bond length is 0.95 Å. In the forty-sixth C site, C(51) is bonded in a distorted bent 120 degrees geometry to one C(50), one N(11), and one H(36) atom. The C(51)-N(11) bond length is 1.34 Å. The C(51)-H(36) bond length is 0.95 Å. In the forty-seventh C site, C(57) is bonded in a distorted bent 120 degrees geometry to one N(13) and one H(41) atom. The C(57)-N(13) bond length is 1.35 Å. The C(57)-H(41) bond length is 0.95 Å. In the forty-eighth C site, C(59) is bonded in a distorted single-bond geometry to one C(60) and one H(13,43) atom. The C(59)-C(60) bond length is 1.42 Å. The C(59)-H(13,43) bond length is 0.95 Å. In the forty-ninth C site, C(60) is bonded in a distorted single-bond geometry to one C(59), one C(61), and one N(13) atom. The C(60)-C(61) bond length is 1.38 Å. The C(60)-N(13) bond length is 1.40 Å. In the fiftieth C site, C(61) is bonded in a trigonal planar geometry to one C(24,66); one C(60); and one C(62) atom. The C(61)-C(24,66) bond length is 1.50 Å. The C(61)-C(62) bond length is 1.39 Å. In the fifty-first C site, C(62) is bonded in a distorted single-bond geometry to one C(61), one C(63), and one N(14) atom. The C(62)-C(63) bond length is 1.42 Å. The C(62)-N(14) bond length is 1.39 Å. In the fifty-second C site, C(63) is bonded in a distorted single-bond geometry to one C(62) and one H(14,44) atom. The C(63)-H(14,44) bond length is 0.95 Å. In the fifty-third C site, C(65) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(46) atom. The C(65)-N(14) bond length is 1.31 Å. The C(65)-H(46) bond length is 0.95 Å. In the fifty-fourth C site, C(71) is bonded in a distorted bent 120 degrees geometry to one N(16) and one H(51) atom. The C(71)-N(16) bond length is 1.34 Å. The C(71)-H(51) bond length is 0.95 Å. In the fifty-fifth C site, C(73) is bonded in a distorted single-bond geometry to one C(74) and one H(23,53) atom. The C(73)-C(74) bond length is 1.41 Å. The C(73)-H(23,53) bond length is 0.95 Å. In the fifty-sixth C site, C(74) is bonded in a distorted trigonal planar geometry to one C(73), one C(75), and one N(16) atom. The C(74)-C(75) bond length is 1.39 Å. The C(74)-N(16) bond length is 1.41 Å. In the fifty-seventh C site, C(75) is bonded in a trigonal planar geometry to one C(38,80); one C(74); and one C(76) atom. The C(75)-C(38,80) bond length is 1.49 Å. The C(75)-C(76) bond length is 1.39 Å. In the fifty-eighth C site, C(76) is bonded in a distorted trigonal planar geometry to one C(75), one C(77), and one N(17) atom. The C(76)-C(77) bond length is 1.42 Å. The C(76)-N(17) bond length is 1.40 Å. In the fifty-ninth C site, C(77) is bonded in a distorted single-bond geometry to one C(76); one C(78); and one H(24,54) atom. The C(77)-C(78) bond length is 1.37 Å. The C(77)-H(24,54) bond length is 0.95 Å. In the sixtieth C site, C(78) is bonded in a distorted single-bond geometry to one C(77); one C(79); and one H(25,55) atom. The C(78)-C(79) bond length is 1.42 Å. The C(78)-H(25,55) bond length is 0.95 Å. In the sixty-first C site, C(79) is bonded in a distorted bent 120 degrees geometry to one C(78), one N(17), and one H(56) atom. The C(79)-N(17) bond length is 1.32 Å. The C(79)-H(56) bond length is 0.95 Å. There are fifteen inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Fe(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Fe(1), one C(6), and one C(9) atom. In the third N site, N(3,12) is bonded in a trigonal planar geometry to one Ag(1,2); one C(12,54); and one C(13,55) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(15), and one C(18) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(1), one C(20), and one C(23) atom. In the sixth N site, N(6,15) is bonded in a trigonal planar geometry to one Ag(1,2); one C(26,68); and one C(27,69) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Fe(1), one C(29), and one C(32) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Fe(1), one C(34), and one C(37) atom. In the ninth N site, N(9,18) is bonded in a trigonal planar geometry to one Ag(1,2); one C(40,82); and one C(41,83) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Co(1), one C(43), and one C(46) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Co(1), one C(48), and one C(51) atom. In the twelfth N site, N(13) is bonded in a trigonal planar geometry to one Fe(1), one C(57), and one C(60) atom. In the thirteenth N site, N(14) is bonded in a trigonal planar geometry to one Fe(1), one C(62), and one C(65) atom. In the fourteenth N site, N(16) is bonded in a trigonal planar geometry to one Co(1), one C(71), and one C(74) atom. In the fifteenth N site, N(17) is bonded in a trigonal planar geometry to one Co(1), one C(76), and one C(79) atom. There are thirty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3,33) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4,34) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5,35) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7,37) is bonded in a single-bond geometry to one C(11,53) atom. In the seventh H site, H(8,38) is bonded in a single-bond geometry to one C(12,54) atom. In the eighth H site, H(9,39) is bonded in a single-bond geometry to one C(13,55) atom. In the ninth H site, H(10,40) is bonded in a single-bond geometry to one C(14,56) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(13,43) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(14,44) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(17,47) is bonded in a single-bond geometry to one C(25,67) atom. In the fifteenth H site, H(18,48) is bonded in a single-bond geometry to one C(26,68) atom. In the sixteenth H site, H(19,49) is bonded in a single-bond geometry to one C(27,69) atom. In the seventeenth H site, H(20,50) is bonded in a single-bond geometry to one C(28,70) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the nineteenth H site, H(23,53) is bonded in a single-bond geometry to one C(31) atom. In the twentieth H site, H(24,54) is bonded in a single-bond geometry to one C(35) atom. In the twenty-first H site, H(25,55) is bonded in a single-bond geometry to one C(36) atom. In the twenty-second H site, H(26) is bonded in a single-bond geometry to one C(37) atom. In the twenty-third H site, H(27,57) is bonded in a single-bond geometry to one C(39,81) atom. In the twenty-fourth H site, H(28,58) is bonded in a single-bond geometry to one C(40,82) atom. In the twenty-fifth H site, H(29,59) is bonded in a single-bond geometry to one C(41,83) atom. In the twenty-sixth H site, H(30,60) is bonded in a single-bond geometry to one C(42,84) atom. In the twenty-seventh H site, H(31) is bonded in a single-bond geometry to one C(43) atom. In the twenty-eighth H site, H(41) is bonded in a single-bond geometry to one C(57) atom. In the twenty-ninth H site, H(36) is bonded in a single-bond geometry to one C(51) atom. In the thirtieth H site, H(46) is bonded in a single-bond geometry to one C(65) atom. In the thirty-first H site, H(51) is bonded in a single-bond geometry to one C(71) atom. In the thirty-second H site, H(56) is bonded in a single-bond geometry to one C(79) atom. Linkers: 1 [CH]1C=NC([C](C2=C[CH]N([Ag](N3[CH]C=C([C](C4=N[CH]C=C4)C4=N[CH]C=C4)C=C3)N3[CH]C=C(/C(C4=C[CH]C=N4)=C4\C=CC=N4)C=C3)C=C2)C2=NC=C[CH]2)=C1 ,1 [CH]1C=CN=C1[C](C1=C[CH]N([Ag](N2[CH]C=C([C](C3=CC=C[N]3)C3=CC=C[N]3)C=C2)N2[CH]C=C([C](C3=NC=C[CH]3)C3=NC=C[CH]3)C=C2)C=C1)C1=CC=C[N]1 ,1 [CH]1C=NC(/C(C2=C[CH]N([Ag](N3[CH]C=C([C](C4=CC=C[N]4)C4=CC=C[N]4)C=C3)N3[CH]C=C([C](C4=CC=C[N]4)C4=NC=C[CH]4)C=C3)C=C2)=C2/C=CC=N2)=C1 ,1 [CH]1C=NC([C](C2=C[CH]N([Ag](N3[CH]C=C([C](C4=C[CH]C=N4)C4=NC=C[CH]4)C=C3)N3[CH]C=C(/C(C4=NC=C[CH]4)=C4\C=CC=N4)C=C3)C=C2)C2=CC=C[N]2)=C1 ,2 [CH]1C=NC([C](C2=C[CH]N([Ag](N3[CH]C=C([C](C4=CC=C[N]4)C4=NC=C[CH]4)C=C3)N3[CH]C=C(/C(C4=C[CH]C=N4)=C4\C=CC=N4)C=C3)C=C2)C2=NC=C[CH]2)=C1 ,1 [CH]1C=CC([C](C2=C[CH]N([Ag](N3[CH]C=C([C](C4=CC=C[N]4)C4=NC=C[CH]4)C=C3)N3[CH]C=C(/C(C4=N[CH]C=C4)=C4\C=CC=N4)C=C3)C=C2)C2=CC=C[N]2)=N1 ,1 [CH]1C=NC([C](C2=C[CH]N([Ag](N3[CH]C=C([C](C4=CC=C[N]4)C4=N[CH]C=C4)C=C3)N3[CH]C=C(/C(C4=CC=C[N]4)=C4\C=CC=N4)C=C3)C=C2)C2=CC=C[N]2)=C1. Metal clusters: 4 [Fe] ,4 [Co]. The MOF has largest included sphere 6.06 A, density 0.97 g/cm3, surface area 4413.61 m2/g, accessible volume 0.55 cm3/g