Ag2C2N3H2 is Tungsten structured and crystallizes in the cubic Pn-3m space group. The structure is zero-dimensional and consists of two Ag2C2N3H2 clusters. There are three inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to two equivalent N(1) atoms. Both Ag(1)-N(1) bond lengths are 2.11 Å. In the second Ag site, Ag(2) is bonded in a linear geometry to one N(2) and one N(3) atom. The Ag(2)-N(2) bond length is 2.11 Å. The Ag(2)-N(3) bond length is 2.19 Å. In the third Ag site, Ag(3) is bonded in a distorted single-bond geometry to one Ag(3) and one N(4) atom. The Ag(3)-Ag(3) bond length is 1.47 Å. The Ag(3)-N(4) bond length is 2.11 Å. There are two inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(2) atom. The C(2)-N(3) bond length is 1.32 Å. The C(2)-N(4) bond length is 1.26 Å. The C(2)-H(2) bond length is 0.93 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-N(2) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(4) is bonded in a 4-coordinate geometry to two equivalent Ag(3) and two equivalent C(2) atoms. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(2) and two equivalent C(1) atoms. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(2), one C(2), and one N(3) atom. The N(3)-N(3) bond length is 1.29 Å. In the fourth N site, N(1) is bonded in a 3-coordinate geometry to one Ag(1), one C(1), and one N(1) atom. The N(1)-N(1) bond length is 1.37 Å. There are two inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(1) atom. Linkers: 6 C1=NN=C[N]1 ,20 C1=NC=N[N]1 ,10 [N]1=CN=NC=1. Metal clusters: 8 N1=N\[Ag]/N=N\[Ag]/N=N\[Ag]/1 ,6 N1=N[Ag]2[Ag]3N=N[Ag]2[Ag]13 ,12 [N][Ag][Ag]. The MOF has largest included sphere 8.00 A, density 2.35 g/cm3, surface area 2103.58 m2/g, accessible volume 0.20 cm3/g