Zn2C12N14H15O(CH)2CH3 crystallizes in the monoclinic C2 space group. The structure consists of eight 02329_fluka molecules and four 02329_fluka molecules inside a Zn2C12N14H15O framework. In the Zn2C12N14H15O framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(10), one N(11), and one N(8) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-N(10) bond length is 2.01 Å. The Zn(1)-N(11) bond length is 1.99 Å. The Zn(1)-N(8) bond length is 2.02 Å. In the second Zn site, Zn(2) is bonded in a trigonal bipyramidal geometry to one N(12), one N(2), one N(5), one N(9), and one O(1) atom. The Zn(2)-N(12) bond length is 2.02 Å. The Zn(2)-N(2) bond length is 2.04 Å. The Zn(2)-N(5) bond length is 2.03 Å. The Zn(2)-N(9) bond length is 2.14 Å. The Zn(2)-O(1) bond length is 2.37 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(3), one N(5), and one N(8) atom. The C(1)-C(3) bond length is 1.50 Å. The C(1)-N(5) bond length is 1.31 Å. The C(1)-N(8) bond length is 1.34 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(8) and one H(1) atom. The C(2)-C(8) bond length is 1.41 Å. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal non-coplanar geometry to one C(1); one H(3); and two equivalent H(2,4) atoms. The C(3)-H(3) bond length is 0.96 Å. Both C(3)-H(2,4) bond lengths are 0.96 Å. In the fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(13), one N(10), and one N(9) atom. The C(6)-C(13) bond length is 1.52 Å. The C(6)-N(10) bond length is 1.33 Å. The C(6)-N(9) bond length is 1.34 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(9), one N(11), and one N(12) atom. The C(7)-C(9) bond length is 1.52 Å. The C(7)-N(11) bond length is 1.35 Å. The C(7)-N(12) bond length is 1.35 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(10), one C(2), and one N(11) atom. The C(8)-C(10) bond length is 1.41 Å. The C(8)-N(11) bond length is 1.39 Å. In the seventh C site, C(9) is bonded in a distorted water-like geometry to one C(7), one H(7), and one O(1) atom. The C(9)-H(7) bond length is 0.98 Å. The C(9)-O(1) bond length is 1.44 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(8), and one N(12) atom. The C(10)-C(11) bond length is 1.42 Å. The C(10)-N(12) bond length is 1.40 Å. In the ninth C site, C(11) is bonded in a single-bond geometry to one C(10) and one H(8) atom. The C(11)-H(8) bond length is 0.93 Å. In the tenth C site, C(13) is bonded in a trigonal non-coplanar geometry to one C(6) and three equivalent H(12,13,14) atoms. All C(13)-H(12,13,14) bond lengths are 0.96 Å. In the eleventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(15) and two equivalent N(2) atoms. The C(14)-C(15) bond length is 1.50 Å. Both C(14)-N(2) bond lengths are 1.33 Å. In the twelfth C site, C(15) is bonded in a 6-coordinate geometry to one C(14), two equivalent H(15), two equivalent H(16), and two equivalent H(17) atoms. Both C(15)-H(15) bond lengths are 0.96 Å. Both C(15)-H(16) bond lengths are 0.96 Å. Both C(15)-H(17) bond lengths are 0.96 Å. In the thirteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17) and two equivalent N(1) atoms. The C(16)-C(17) bond length is 1.53 Å. Both C(16)-N(1) bond lengths are 1.32 Å. In the fourteenth C site, C(17) is bonded in a 6-coordinate geometry to one C(16), two equivalent H(18), two equivalent H(19), and two equivalent H(20) atoms. Both C(17)-H(18) bond lengths are 0.96 Å. Both C(17)-H(19) bond lengths are 0.96 Å. Both C(17)-H(20) bond lengths are 0.96 Å. There are fourteen inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Zn(1), one C(16), and one N(4) atom. The N(1)-N(4) bond length is 1.40 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Zn(2), one C(14), and one N(3) atom. The N(2)-N(3) bond length is 1.38 Å. In the third N site, N(3) is bonded in a water-like geometry to one N(2) and one N(3) atom. The N(3)-N(3) bond length is 1.29 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one N(1) and one N(4) atom. The N(4)-N(4) bond length is 1.27 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(1), and one N(7) atom. The N(5)-N(7) bond length is 1.36 Å. In the sixth N site, N(6) is bonded in a water-like geometry to one N(7) and one N(8) atom. The N(6)-N(7) bond length is 1.32 Å. The N(6)-N(8) bond length is 1.37 Å. In the seventh N site, N(7) is bonded in a water-like geometry to one N(5) and one N(6) atom. In the eighth N site, N(8) is bonded in a 3-coordinate geometry to one Zn(1), one C(1), and one N(6) atom. In the ninth N site, N(9) is bonded in a 3-coordinate geometry to one Zn(2), one C(6), and one N(13) atom. The N(9)-N(13) bond length is 1.35 Å. In the tenth N site, N(10) is bonded in a 3-coordinate geometry to one Zn(1), one C(6), and one N(14) atom. The N(10)-N(14) bond length is 1.38 Å. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Zn(1), one C(7), and one C(8) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one Zn(2), one C(10), and one C(7) atom. In the thirteenth N site, N(13) is bonded in a water-like geometry to one N(14) and one N(9) atom. The N(13)-N(14) bond length is 1.28 Å. In the fourteenth N site, N(14) is bonded in a water-like geometry to one N(10) and one N(13) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2,4) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(12,13,14) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(17) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(17) atom. O(1) is bonded in a distorted single-bond geometry to one Zn(2) and one C(9) atom. Linkers: 3 C.[C]1=NN=N[N]1.[H].[H] ,8 CC1=NN=N[N]1 ,1 C.[C]1=N[N]N=N1.[H].[H] ,4 C[C@@H]([O])C1=Nc2ccccc2[N]1. Metal clusters: 8 [Zn]. The MOF has largest included sphere 4.48 A, density 1.31 g/cm3, surface area 4592.33 m2/g, accessible volume 0.31 cm3/g