Co7C50H42(N4F3)4(C13N2H9)2 crystallizes in the orthorhombic Pbca space group. The structure consists of eight C13N2H9 clusters inside a Co7C50H42(N4F3)4 framework. In each C13N2H9 cluster, there are thirteen inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2,12,22) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2,12,22) bond length is 0.95 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(11), one C(2), and one C(4) atom. The C(3)-C(11) bond length is 1.47 Å. The C(3)-C(4) bond length is 1.37 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3,13,23) atom. The C(4)-H(3,13,23) bond length is 0.95 Å. In the fourth C site, C(11) is bonded in a trigonal planar geometry to one C(13); one C(3); and one N(3,7) atom. The C(11)-C(13) bond length is 1.38 Å. The C(11)-N(3,7) bond length is 1.38 Å. In the fifth C site, C(13) is bonded in a single-bond geometry to one C(11), one C(37), and one H(9) atom. The C(13)-C(37) bond length is 1.38 Å. The C(13)-H(9) bond length is 0.95 Å. In the sixth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(2,12,22) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-H(2,12,22) bond length is 0.95 Å. In the seventh C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(25) atom. The C(17)-C(18) bond length is 1.37 Å. The C(17)-C(25) bond length is 1.47 Å. In the eighth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(3,13,23) atom. The C(18)-H(3,13,23) bond length is 0.95 Å. In the ninth C site, C(25) is bonded in a trigonal planar geometry to one C(17) and two equivalent N(3,7) atoms. The C(25)-C(17) bond length is 1.47 Å. Both C(25)-N(3,7) bond lengths are 1.38 Å. In the tenth C site, C(28) is bonded in a distorted single-bond geometry to one C(29) and one H(2,12,22) atom. The C(28)-C(29) bond length is 1.41 Å. The C(28)-H(2,12,22) bond length is 0.95 Å. In the eleventh C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(37) atom. The C(29)-C(30) bond length is 1.37 Å. The C(29)-C(37) bond length is 1.47 Å. In the twelfth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(3,13,23) atom. The C(30)-H(3,13,23) bond length is 0.95 Å. In the thirteenth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(13); one C(29); and one N(3,7) atom. The C(37)-N(3,7) bond length is 1.38 Å. N(3,7) is bonded in a distorted trigonal planar geometry to one C(11), one C(25), and one H(19) atom. The N(3,7)-H(19) bond length is 0.95 Å. There are five inequivalent H sites. In the first H site, H(2,12,22) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3,13,23) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one N(3,7) atom. In the fifth H site, H(29) is bonded in a single-bond geometry to one N(3,7) atom. The H(29)-N(3,7) bond length is 0.95 Å. In the Co7C50H42(N4F3)4 framework, there are two inequivalent Co sites. In the first Co site, Co(1,2,3) is bonded to one N(1,5,9); one N(2,6,10); two equivalent F(1,3,5); and two equivalent F(2,4,6) atoms to form CoN2F4 octahedra that share  an edgeedge with one Co(4)F6 octahedra and edges with two equivalent Co(1,2,3)N2F4 octahedra. The Co(1,2,3)-N(1,5,9) bond length is 2.11 Å. The Co(1,2,3)-N(2,6,10) bond length is 2.10 Å. Both Co(1,2,3)-F(1,3,5) bond lengths are 2.04 Å. There is one shorter (2.07 Å) and one longer (2.12 Å) Co(1,2,3)-F(2,4,6) bond length. In the second Co site, Co(4) is bonded to six equivalent F(2,4,6) atoms to form edge-sharing CoF6 octahedra. All Co(4)-F(2,4,6) bond lengths are 2.05 Å. There are twenty inequivalent C sites. In the first C site, C(1,15,27) is bonded in a distorted bent 120 degrees geometry to one N(2,6,10) and one H(1,11,21) atom. The C(1,15,27)-N(2,6,10) bond length is 1.33 Å. The C(1,15,27)-H(1,11,21) bond length is 0.95 Å. In the second C site, C(5,19,31) is bonded in a distorted bent 120 degrees geometry to one N(2,6,10) and one H(4,14,24) atom. The C(5,19,31)-N(2,6,10) bond length is 1.35 Å. The C(5,19,31)-H(4,14,24) bond length is 0.95 Å. In the third C site, C(6,20,32) is bonded in a distorted bent 120 degrees geometry to one C(7); one N(1,5,9); and one H(5,15,25) atom. The C(6,20,32)-C(7) bond length is 1.37 Å. The C(6,20,32)-N(1,5,9) bond length is 1.35 Å. The C(6,20,32)-H(5,15,25) bond length is 0.95 Å. In the fourth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6,20,32); one C(8); and one H(6,16,26) atom. The C(7)-C(8) bond length is 1.37 Å. The C(7)-H(6,16,26) bond length is 0.95 Å. In the fifth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.47 Å. The C(8)-C(9) bond length is 1.38 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(7,17,27) atom. The C(9)-H(7,17,27) bond length is 0.95 Å. In the seventh C site, C(10,24,36) is bonded in a distorted bent 120 degrees geometry to one N(1,5,9) and one H(8,18,28) atom. The C(10,24,36)-N(1,5,9) bond length is 1.33 Å. The C(10,24,36)-H(8,18,28) bond length is 0.95 Å. In the eighth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14); one C(8); and one N(4,8) atom. The C(12)-C(14) bond length is 1.37 Å. The C(12)-N(4,8) bond length is 1.38 Å. In the ninth C site, C(14) is bonded in a single-bond geometry to one C(12), one C(38), and one H(10) atom. The C(14)-C(38) bond length is 1.38 Å. The C(14)-H(10) bond length is 0.95 Å. In the tenth C site, C(38) is bonded in a trigonal planar geometry to one C(14); one C(34); and one N(4,8) atom. The C(38)-C(34) bond length is 1.47 Å. The C(38)-N(4,8) bond length is 1.37 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14); one C(8); and one N(4,8) atom. The C(12)-C(14) bond length is 1.37 Å. The C(12)-C(8) bond length is 1.47 Å. The C(12)-N(4,8) bond length is 1.38 Å. In the twelfth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22); one C(6,20,32); and one H(6,16,26) atom. The C(21)-C(22) bond length is 1.37 Å. The C(21)-C(6,20,32) bond length is 1.37 Å. The C(21)-H(6,16,26) bond length is 0.95 Å. In the thirteenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(26) atom. The C(22)-C(23) bond length is 1.38 Å. The C(22)-C(26) bond length is 1.47 Å. In the fourteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(7,17,27) atom. The C(23)-H(7,17,27) bond length is 0.95 Å. In the fifteenth C site, C(26) is bonded in a trigonal planar geometry to one C(22) and two equivalent N(4,8) atoms. There is one shorter (1.37 Å) and one longer (1.38 Å) C(26)-N(4,8) bond length. In the sixteenth C site, C(26) is bonded in a trigonal planar geometry to one C(22) and two equivalent N(4,8) atoms. The C(26)-C(22) bond length is 1.47 Å. There is one shorter (1.37 Å) and one longer (1.38 Å) C(26)-N(4,8) bond length. In the seventeenth C site, C(33) is bonded in a distorted trigonal planar geometry to one C(34); one C(6,20,32); and one H(6,16,26) atom. The C(33)-C(34) bond length is 1.37 Å. The C(33)-C(6,20,32) bond length is 1.37 Å. The C(33)-H(6,16,26) bond length is 0.95 Å. In the eighteenth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(38) atom. The C(34)-C(35) bond length is 1.38 Å. The C(34)-C(38) bond length is 1.47 Å. In the nineteenth C site, C(35) is bonded in a distorted single-bond geometry to one C(34) and one H(7,17,27) atom. The C(35)-H(7,17,27) bond length is 0.95 Å. In the twentieth C site, C(38) is bonded in a trigonal planar geometry to one C(14); one C(34); and one N(4,8) atom. The C(38)-C(14) bond length is 1.38 Å. The C(38)-N(4,8) bond length is 1.37 Å. There are three inequivalent N sites. In the first N site, N(1,5,9) is bonded in a trigonal planar geometry to one Co(1,2,3); one C(10,24,36); and one C(6,20,32) atom. In the second N site, N(2,6,10) is bonded in a trigonal planar geometry to one Co(1,2,3); one C(1,15,27); and one C(5,19,31) atom. In the third N site, N(4,8) is bonded in a distorted trigonal planar geometry to one C(12), one C(26), and one H(20) atom. The N(4,8)-H(20) bond length is 0.95 Å. There are nine inequivalent H sites. In the first H site, H(1,11,21) is bonded in a single-bond geometry to one C(1,15,27) atom. In the second H site, H(4,14,24) is bonded in a single-bond geometry to one C(5,19,31) atom. In the third H site, H(5,15,25) is bonded in a single-bond geometry to one C(6,20,32) atom. In the fourth H site, H(6,16,26) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7,17,27) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8,18,28) is bonded in a single-bond geometry to one C(10,24,36) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one N(4,8) atom. In the ninth H site, H(30) is bonded in a single-bond geometry to one N(4,8) atom. The H(30)-N(4,8) bond length is 0.95 Å. There are two inequivalent F sites. In the first F site, F(1,3,5) is bonded in a water-like geometry to two equivalent Co(1,2,3) atoms. In the second F site, F(2,4,6) is bonded in a distorted T-shaped geometry to one Co(4) and two equivalent Co(1,2,3) atoms. Linkers: 16 C1=C(c2ccncc2)N[C](c2ccncc2)N[C]1c1ccncc1. Metal clusters: 4 F[Co].F[Co].F[Co].F[Co].F[Co].F[Co].F[Co](F)(F)(F)(F)F. The MOF has largest included sphere 7.99 A, density 0.85 g/cm3, surface area 3855.81 m2/g, accessible volume 0.60 cm3/g