Sc3C24H12O13 is Indium-like structured and crystallizes in the hexagonal P6_3/mmc space group. The structure is zero-dimensional and consists of two Sc3C24H12O13 clusters. Sc(1) is bonded to one O(2) and four equivalent O(1) atoms to form corner-sharing ScO5 square pyramids. The Sc(1)-O(2) bond length is 2.03 Å. All Sc(1)-O(1) bond lengths are 2.10 Å. There are three inequivalent C sites. In the first C site, C(2) is bonded in a bent 120 degrees geometry to one C(3) and two equivalent O(1) atoms. The C(2)-C(3) bond length is 1.50 Å. Both C(2)-O(1) bond lengths are 1.27 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2) and two equivalent C(1) atoms. Both C(3)-C(1) bond lengths are 1.39 Å. In the third C site, C(1) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(1)-H(1) bond length is 0.95 Å. H(1) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a trigonal planar geometry to three equivalent Sc(1) atoms. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Sc(1) and one C(2) atom. Linkers: 6 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 2 [C]1O[Sc]23O[C]O[Sc]45(O1)O[C]O[Sc](O[C]O2)(O[C]O3)(O[C]O4)O5. RCSR code: acs. The MOF has largest included sphere 8.61 A, density 0.69 g/cm3, surface area 4026.47 m2/g, accessible volume 1.00 cm3/g