Zn2C28H19(NO)6(C3H2)3(CH)2C9H6N is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; three 2,3-dimethyl-1,3-butadiene molecules; two schembl1705614 molecules; and two Zn2C28H19(NO)6 clusters. In each Zn2C28H19(NO)6 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal non-coplanar geometry to one N(4), one O(1), and one O(6) atom. The Zn(1)-N(4) bond length is 2.00 Å. The Zn(1)-O(1) bond length is 1.99 Å. The Zn(1)-O(6) bond length is 1.94 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one N(3), one N(5), one O(2), and one O(5) atom. The Zn(2)-N(3) bond length is 2.01 Å. The Zn(2)-N(5) bond length is 2.01 Å. The Zn(2)-O(2) bond length is 1.97 Å. The Zn(2)-O(5) bond length is 1.96 Å. There are twenty-eight inequivalent C sites. In the first C site, C(41) is bonded in a distorted single-bond geometry to one C(36) and one H(6) atom. The C(41)-C(36) bond length is 1.36 Å. The C(41)-H(6) bond length is 0.93 Å. In the second C site, C(44) is bonded in a 3-coordinate geometry to one C(15), one N(4), and one H(26) atom. The C(44)-C(15) bond length is 1.36 Å. The C(44)-N(4) bond length is 1.36 Å. The C(44)-H(26) bond length is 0.93 Å. In the third C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(47), one O(1), and one O(2) atom. The C(45)-C(47) bond length is 1.49 Å. The C(45)-O(1) bond length is 1.25 Å. The C(45)-O(2) bond length is 1.25 Å. In the fourth C site, C(46) is bonded in a distorted single-bond geometry to one C(5) and one H(10) atom. The C(46)-C(5) bond length is 1.37 Å. The C(46)-H(10) bond length is 0.93 Å. In the fifth C site, C(47) is bonded in a trigonal planar geometry to one C(30), one C(45), and one C(6) atom. The C(47)-C(30) bond length is 1.39 Å. The C(47)-C(6) bond length is 1.40 Å. In the sixth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(33), one C(4), and one N(7) atom. The C(2)-C(33) bond length is 1.39 Å. The C(2)-C(4) bond length is 1.37 Å. The C(2)-N(7) bond length is 1.43 Å. In the seventh C site, C(3) is bonded in a trigonal planar geometry to one C(14), one C(38), and one C(7) atom. The C(3)-C(14) bond length is 1.39 Å. The C(3)-C(38) bond length is 1.49 Å. The C(3)-C(7) bond length is 1.38 Å. In the eighth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(31) atom. The C(4)-H(31) bond length is 0.93 Å. In the ninth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(13), one C(46), and one N(2) atom. The C(5)-C(13) bond length is 1.38 Å. The C(5)-N(2) bond length is 1.43 Å. In the tenth C site, C(6) is bonded in a distorted single-bond geometry to one C(47) and one H(13,19) atom. The C(6)-H(13,19) bond length is 0.93 Å. In the eleventh C site, C(7) is bonded in a distorted single-bond geometry to one C(3) and one H(15) atom. The C(7)-H(15) bond length is 0.93 Å. In the twelfth C site, C(9) is bonded in a distorted single-bond geometry to one C(36) and one H(25) atom. The C(9)-C(36) bond length is 1.38 Å. The C(9)-H(25) bond length is 0.93 Å. In the thirteenth C site, C(11) is bonded in a 3-coordinate geometry to one C(24), one N(6), and one H(5) atom. The C(11)-C(24) bond length is 1.33 Å. The C(11)-N(6) bond length is 1.38 Å. The C(11)-H(5) bond length is 0.93 Å. In the fourteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(5) and one H(33) atom. The C(13)-H(33) bond length is 0.93 Å. In the fifteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(3) and one H(23) atom. The C(14)-H(23) bond length is 0.93 Å. In the sixteenth C site, C(15) is bonded in a 3-coordinate geometry to one C(44), one N(7), and one H(21) atom. The C(15)-N(7) bond length is 1.38 Å. The C(15)-H(21) bond length is 0.93 Å. In the seventeenth C site, C(18) is bonded in a 3-coordinate geometry to one C(28), one N(2), and one H(32) atom. The C(18)-C(28) bond length is 1.34 Å. The C(18)-N(2) bond length is 1.38 Å. The C(18)-H(32) bond length is 0.93 Å. In the eighteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(36), one O(3), and one O(5) atom. The C(21)-C(36) bond length is 1.49 Å. The C(21)-O(3) bond length is 1.24 Å. The C(21)-O(5) bond length is 1.28 Å. In the nineteenth C site, C(24) is bonded in a 2-coordinate geometry to one C(11), one N(5), and one H(3) atom. The C(24)-N(5) bond length is 1.37 Å. The C(24)-H(3) bond length is 0.93 Å. In the twentieth C site, C(26) is bonded in a distorted single-bond geometry to one N(6) atom. The C(26)-N(6) bond length is 1.44 Å. In the twenty-first C site, C(28) is bonded in a distorted trigonal planar geometry to one C(18), one N(3), and one H(20) atom. The C(28)-N(3) bond length is 1.39 Å. The C(28)-H(20) bond length is 0.93 Å. In the twenty-second C site, C(30) is bonded in a distorted single-bond geometry to one C(47) and one H(13,19) atom. The C(30)-H(13,19) bond length is 0.93 Å. In the twenty-third C site, C(32) is bonded in a trigonal planar geometry to one N(4), one N(7), and one H(28) atom. The C(32)-N(4) bond length is 1.32 Å. The C(32)-N(7) bond length is 1.32 Å. The C(32)-H(28) bond length is 0.93 Å. In the twenty-fourth C site, C(33) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(33)-H(1) bond length is 0.93 Å. In the twenty-fifth C site, C(36) is bonded in a trigonal planar geometry to one C(21), one C(41), and one C(9) atom. In the twenty-sixth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(4), and one O(6) atom. The C(38)-O(4) bond length is 1.22 Å. The C(38)-O(6) bond length is 1.27 Å. In the twenty-seventh C site, C(39) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(29) atom. The C(39)-N(2) bond length is 1.34 Å. The C(39)-N(3) bond length is 1.31 Å. The C(39)-H(29) bond length is 0.93 Å. In the twenty-eighth C site, C(40) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(11) atom. The C(40)-N(5) bond length is 1.30 Å. The C(40)-N(6) bond length is 1.34 Å. The C(40)-H(11) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one C(18), one C(39), and one C(5) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(28), and one C(39) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(32), and one C(44) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one Zn(2), one C(24), and one C(40) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one C(11), one C(26), and one C(40) atom. In the sixth N site, N(7) is bonded in a trigonal planar geometry to one C(15), one C(2), and one C(32) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(33) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(24) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(41) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(46) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(40) atom. In the seventh H site, H(13,19) is bonded in a single-bond geometry to one C(30) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(20) is bonded in a single-bond geometry to one C(28) atom. In the tenth H site, H(21) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(23) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(25) is bonded in a single-bond geometry to one C(9) atom. In the thirteenth H site, H(26) is bonded in a single-bond geometry to one C(44) atom. In the fourteenth H site, H(28) is bonded in a single-bond geometry to one C(32) atom. In the fifteenth H site, H(29) is bonded in a single-bond geometry to one C(39) atom. In the sixteenth H site, H(31) is bonded in a single-bond geometry to one C(4) atom. In the seventeenth H site, H(32) is bonded in a single-bond geometry to one C(18) atom. In the eighteenth H site, H(33) is bonded in a single-bond geometry to one C(13) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(45) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(45) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(21) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(38) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Zn(2) and one C(21) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Zn(1) and one C(38) atom. Linkers: 4 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cc2)cc1 ,2 [O]C(=O)c1ccc(-c2ccc([C]=O)cc2)cc1 ,2 c1cn(-c2ccc(N(c3ccc(-n4ccnc4)cc3)c3ccc(-n4ccnc4)cc3)cc2)cn1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 5.35 A, density 1.28 g/cm3, surface area 4895.23 m2/g, accessible volume 0.34 cm3/g