In3C36N8H22O13(CH)4 crystallizes in the cubic I-43d space group. The structure consists of ninety-six 02329_fluka molecules inside a In3C36N8H22O13 framework. In each In3C36N8H22O13 framework, there are two inequivalent In sites. In the first In site, In(1) is bonded to one N(1), one O(3), one O(4), one O(5), one O(6), and one O(7) atom to form InNO5 octahedra that share  a cornercorner with one In(1)NO5 octahedra and  a cornercorner with one In(2)O5 square pyramid. The corner-sharing octahedral tilt angles are 62°. The In(1)-N(1) bond length is 2.22 Å. The In(1)-O(3) bond length is 2.19 Å. The In(1)-O(4) bond length is 2.17 Å. The In(1)-O(5) bond length is 2.18 Å. The In(1)-O(6) bond length is 2.15 Å. The In(1)-O(7) bond length is 2.04 Å. In the second In site, In(2) is bonded to one O(7), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing InO5 square pyramids. The corner-sharing octahedral tilt angles are 59°. The In(2)-O(7) bond length is 2.05 Å. Both In(2)-O(1) bond lengths are 2.21 Å. Both In(2)-O(2) bond lengths are 2.19 Å. There are eighteen inequivalent C sites. In the first C site, C(18) is bonded in a distorted single-bond geometry to one C(10) and one H(11) atom. The C(18)-C(10) bond length is 1.40 Å. The C(18)-H(11) bond length is 0.93 Å. In the second C site, C(19) is bonded in a distorted trigonal planar geometry to one C(11), one C(17), and one H(12) atom. The C(19)-C(11) bond length is 1.41 Å. The C(19)-C(17) bond length is 1.26 Å. The C(19)-H(12) bond length is 0.93 Å. In the third C site, C(20) is bonded in a distorted trigonal planar geometry to one C(14), one C(17), and one H(13) atom. The C(20)-C(14) bond length is 1.41 Å. The C(20)-C(17) bond length is 1.36 Å. The C(20)-H(13) bond length is 0.93 Å. In the fourth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(4) atom. The C(2)-C(10) bond length is 1.49 Å. The C(2)-O(3) bond length is 1.26 Å. The C(2)-O(4) bond length is 1.24 Å. In the fifth C site, C(1) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(1)-C(4) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.50 Å. The C(1)-C(7) bond length is 1.37 Å. In the sixth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(1) atom. The C(3)-C(4) bond length is 1.43 Å. The C(3)-N(1) bond length is 1.32 Å. The C(3)-H(1) bond length is 0.93 Å. In the seventh C site, C(4) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(2) atom. The C(4)-N(2) bond length is 1.35 Å. In the eighth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(2) bond length is 0.93 Å. In the ninth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(5) atom. The C(6)-O(1) bond length is 1.28 Å. The C(6)-O(5) bond length is 1.26 Å. In the tenth C site, C(7) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(7)-H(5) bond length is 0.93 Å. In the eleventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(2), and one O(6) atom. The C(8)-C(9) bond length is 1.50 Å. The C(8)-O(2) bond length is 1.28 Å. The C(8)-O(6) bond length is 1.27 Å. In the twelfth C site, C(9) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(8) atom. The C(9)-C(11) bond length is 1.38 Å. The C(9)-C(14) bond length is 1.33 Å. In the thirteenth C site, C(11) is bonded in a distorted single-bond geometry to one C(19), one C(9), and one H(6) atom. The C(11)-H(6) bond length is 0.93 Å. In the fourteenth C site, C(13) is bonded in a single-bond geometry to one N(4) atom. The C(13)-N(4) bond length is 1.43 Å. In the fifteenth C site, C(17) is bonded in a single-bond geometry to one C(19), one C(20), and one N(3) atom. The C(17)-N(3) bond length is 1.45 Å. In the sixteenth C site, C(10) is bonded in a trigonal planar geometry to one C(15), one C(18), and one C(2) atom. The C(10)-C(15) bond length is 1.40 Å. In the seventeenth C site, C(14) is bonded in a distorted single-bond geometry to one C(20), one C(9), and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. In the eighteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one H(9) atom. The C(15)-H(9) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one In(1), one C(3), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(4), one H(3), and one H(4) atom. The N(2)-H(3) bond length is 0.86 Å. The N(2)-H(4) bond length is 0.86 Å. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one C(17) and one N(4) atom. The N(3)-N(4) bond length is 1.25 Å. In the fourth N site, N(4) is bonded in a distorted single-bond geometry to one C(13) and one N(3) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(2) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(20) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one In(2) and one C(6) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one In(2) and one C(8) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one In(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one In(1) and one C(2) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one In(1) and one C(6) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one In(1) and one C(8) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one In(2) and two equivalent In(1) atoms. Linkers: 24 [O]C(=O)c1ccc([N][N]c2ccc(C([O])=O)cc2)cc1 ,24 Nc1cnccc1C([O])=O. Metal clusters: 12 O=[C]O[In]1O[C]O[In]O[C]O[In](O[C]=O)O1.[O][C]=O.[O][C]=O. The MOF has largest included sphere 8.96 A, density 0.80 g/cm3, surface area 3702.93 m2/g, accessible volume 0.87 cm3/g