ZnC13NH8O4(C3H2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 2,3-dimethyl-1,3-butadiene molecules and two ZnC13NH8O4 clusters. In each ZnC13NH8O4 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(2), one O(3), one O(6), and one O(8) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.04 Å. The Zn(1)-O(3) bond length is 2.07 Å. The Zn(1)-O(6) bond length is 2.04 Å. The Zn(1)-O(8) bond length is 2.08 Å. In the second Zn site, Zn(2) is bonded in a square pyramidal geometry to one N(2), one O(1), one O(4), one O(5), and one O(7) atom. The Zn(2)-N(2) bond length is 2.04 Å. The Zn(2)-O(1) bond length is 2.03 Å. The Zn(2)-O(4) bond length is 2.04 Å. The Zn(2)-O(5) bond length is 2.05 Å. The Zn(2)-O(7) bond length is 2.05 Å. There are twenty-six inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(3), and one O(4) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(3) bond length is 1.25 Å. The C(1)-O(4) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(9) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(9) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(7), and one O(8) atom. The C(6)-C(7) bond length is 1.53 Å. The C(6)-O(7) bond length is 1.26 Å. The C(6)-O(8) bond length is 1.25 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(6) atom. The C(7)-C(10) bond length is 1.39 Å. The C(7)-C(11) bond length is 1.39 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(9)-H(5) bond length is 0.93 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(10)-H(6) bond length is 0.93 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(11)-H(7) bond length is 0.93 Å. In the ninth C site, C(15) is bonded in a bent 120 degrees geometry to one C(16), one O(1), and one O(2) atom. The C(15)-C(16) bond length is 1.50 Å. The C(15)-O(1) bond length is 1.27 Å. The C(15)-O(2) bond length is 1.26 Å. In the tenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-C(18) bond length is 1.41 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(9) atom. The C(17)-H(9) bond length is 0.93 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(16) and one H(10) atom. The C(18)-H(10) bond length is 0.93 Å. In the thirteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(14) atom. The C(24)-C(25) bond length is 1.36 Å. The C(24)-H(14) bond length is 0.93 Å. In the fourteenth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(36), and one C(37) atom. The C(25)-C(36) bond length is 1.50 Å. The C(25)-C(37) bond length is 1.41 Å. In the fifteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(15) atom. The C(26)-N(1) bond length is 1.36 Å. The C(26)-H(15) bond length is 0.93 Å. In the sixteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(16) atom. The C(27)-N(1) bond length is 1.32 Å. The C(27)-H(16) bond length is 0.93 Å. In the seventeenth C site, C(28) is bonded in a distorted single-bond geometry to one C(29) and one H(17) atom. The C(28)-C(29) bond length is 1.41 Å. The C(28)-H(17) bond length is 0.93 Å. In the eighteenth C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(31) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-C(31) bond length is 1.47 Å. In the nineteenth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(18) atom. The C(30)-H(18) bond length is 0.93 Å. In the twentieth C site, C(31) is bonded in a trigonal planar geometry to one C(29), one C(32), and one C(33) atom. The C(31)-C(32) bond length is 1.45 Å. The C(31)-C(33) bond length is 1.40 Å. In the twenty-first C site, C(32) is bonded in a distorted single-bond geometry to one C(31), one C(34), and one H(19) atom. The C(32)-C(34) bond length is 1.33 Å. The C(32)-H(19) bond length is 0.93 Å. In the twenty-second C site, C(33) is bonded in a single-bond geometry to one C(31), one C(35), and one H(20) atom. The C(33)-C(35) bond length is 1.35 Å. The C(33)-H(20) bond length is 0.93 Å. In the twenty-third C site, C(34) is bonded in a distorted trigonal planar geometry to one C(32), one N(2), and one H(21) atom. The C(34)-N(2) bond length is 1.43 Å. The C(34)-H(21) bond length is 0.93 Å. In the twenty-fourth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(33), one N(2), and one H(22) atom. The C(35)-N(2) bond length is 1.38 Å. The C(35)-H(22) bond length is 0.93 Å. In the twenty-fifth C site, C(36) is bonded in a bent 120 degrees geometry to one C(25), one O(5), and one O(6) atom. The C(36)-O(5) bond length is 1.27 Å. The C(36)-O(6) bond length is 1.26 Å. In the twenty-sixth C site, C(37) is bonded in a distorted single-bond geometry to one C(25) and one H(23) atom. The C(37)-H(23) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(34), and one C(35) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(26), and one C(27) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(28) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(32) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(33) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(34) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(35) atom. In the fifteenth H site, H(23) is bonded in a single-bond geometry to one C(37) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(15) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(15) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(36) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(36) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(6) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. Linkers: 4 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cc2)cc1 ,2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: sql. The MOF has largest included sphere 8.88 A, density 0.78 g/cm3, surface area 4584.77 m2/g, accessible volume 0.78 cm3/g