Mn3C23N8H13O9(CH)15(CH3)2CH2 crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of one hundred and twelve 02329_fluka molecules, sixteen 02329_fluka molecules, thirty-two 02329_fluka molecules, thirty-two isobutylene molecules, and eight Mn3C23N8H13O9 clusters. In each Mn3C23N8H13O9 cluster, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted square pyramidal geometry to one N(1), one N(7), one O(1), one O(3), and one O(8) atom. The Mn(1)-N(1) bond length is 1.95 Å. The Mn(1)-N(7) bond length is 2.24 Å. The Mn(1)-O(1) bond length is 1.86 Å. The Mn(1)-O(3) bond length is 1.94 Å. The Mn(1)-O(8) bond length is 1.97 Å. In the second Mn site, Mn(2) is bonded in a distorted octahedral geometry to one N(2), one N(3), one N(5), one O(2), one O(4), and one O(6) atom. The Mn(2)-N(2) bond length is 2.26 Å. The Mn(2)-N(3) bond length is 1.95 Å. The Mn(2)-N(5) bond length is 2.29 Å. The Mn(2)-O(2) bond length is 1.99 Å. The Mn(2)-O(4) bond length is 1.86 Å. The Mn(2)-O(6) bond length is 1.94 Å. In the third Mn site, Mn(3) is bonded in a distorted octahedral geometry to one N(4), one N(6), one N(8), one O(5), one O(7), and one O(9) atom. The Mn(3)-N(4) bond length is 2.25 Å. The Mn(3)-N(6) bond length is 1.95 Å. The Mn(3)-N(8) bond length is 2.28 Å. The Mn(3)-O(5) bond length is 1.99 Å. The Mn(3)-O(7) bond length is 1.86 Å. The Mn(3)-O(9) bond length is 1.94 Å. There are twenty-three inequivalent C sites. In the first C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(16), one N(3), and one O(5) atom. The C(17)-C(16) bond length is 1.49 Å. The C(17)-N(3) bond length is 1.32 Å. The C(17)-O(5) bond length is 1.28 Å. In the second C site, C(27) is bonded in a distorted single-bond geometry to one C(32) and one O(7) atom. The C(27)-C(32) bond length is 1.41 Å. The C(27)-O(7) bond length is 1.34 Å. In the third C site, C(19) is bonded in a water-like geometry to one C(18), one H(14), and one H(15) atom. The C(19)-C(18) bond length is 1.50 Å. The C(19)-H(14) bond length is 0.99 Å. The C(19)-H(15) bond length is 0.99 Å. In the fourth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(19) atom. The C(21)-N(5) bond length is 1.30 Å. The C(21)-H(19) bond length is 0.95 Å. In the fifth C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(28) atom. The C(31)-C(32) bond length is 1.41 Å. The C(31)-H(28) bond length is 0.95 Å. In the sixth C site, C(32) is bonded in a trigonal planar geometry to one C(27), one C(31), and one C(33) atom. The C(32)-C(33) bond length is 1.47 Å. In the seventh C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(32), one N(6), and one O(8) atom. The C(33)-N(6) bond length is 1.32 Å. The C(33)-O(8) bond length is 1.29 Å. In the eighth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one N(7) and one O(9) atom. The C(34)-N(7) bond length is 1.31 Å. The C(34)-O(9) bond length is 1.30 Å. In the ninth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(31) atom. The C(36)-N(8) bond length is 1.33 Å. The C(36)-H(31) bond length is 0.95 Å. In the tenth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(34) atom. The C(40)-N(8) bond length is 1.33 Å. The C(40)-H(34) bond length is 0.95 Å. In the eleventh C site, C(18) is bonded in a distorted trigonal planar geometry to one C(19), one N(4), and one O(6) atom. The C(18)-N(4) bond length is 1.30 Å. The C(18)-O(6) bond length is 1.31 Å. In the twelfth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(22) atom. The C(25)-N(5) bond length is 1.35 Å. The C(25)-H(22) bond length is 0.95 Å. In the thirteenth C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one O(1) atom. The C(1)-C(6) bond length is 1.43 Å. The C(1)-O(1) bond length is 1.30 Å. In the fourteenth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(4) bond length is 0.95 Å. In the fifteenth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.46 Å. In the sixteenth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one O(2) atom. The C(7)-N(1) bond length is 1.31 Å. The C(7)-O(2) bond length is 1.30 Å. In the seventeenth C site, C(8) is bonded in a trigonal planar geometry to one C(9), one N(2), and one O(3) atom. The C(8)-C(9) bond length is 1.49 Å. The C(8)-N(2) bond length is 1.31 Å. The C(8)-O(3) bond length is 1.31 Å. In the eighteenth C site, C(9) is bonded in a water-like geometry to one C(8), one H(5), and one H(6) atom. The C(9)-H(5) bond length is 0.99 Å. The C(9)-H(6) bond length is 0.99 Å. In the nineteenth C site, C(11) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one O(4) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-C(16) bond length is 1.41 Å. The C(11)-O(4) bond length is 1.33 Å. In the twentieth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(10) atom. The C(12)-C(13) bond length is 1.35 Å. The C(12)-H(10) bond length is 0.95 Å. In the twenty-first C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(13)-H(11) bond length is 0.95 Å. In the twenty-second C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(13) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(13) bond length is 0.95 Å. In the twenty-third C site, C(16) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(17) atom. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(7), and one N(2) atom. The N(1)-N(2) bond length is 1.41 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Mn(2), one C(8), and one N(1) atom. In the third N site, N(6) is bonded in a distorted trigonal planar geometry to one Mn(3), one C(33), and one N(7) atom. The N(6)-N(7) bond length is 1.42 Å. In the fourth N site, N(7) is bonded in a 3-coordinate geometry to one Mn(1), one C(34), and one N(6) atom. In the fifth N site, N(3) is bonded in a distorted trigonal planar geometry to one Mn(2), one C(17), and one N(4) atom. The N(3)-N(4) bond length is 1.42 Å. In the sixth N site, N(4) is bonded in a 3-coordinate geometry to one Mn(3), one C(18), and one N(3) atom. In the seventh N site, N(5) is bonded in a trigonal planar geometry to one Mn(2), one C(21), and one C(25) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Mn(3), one C(36), and one C(40) atom. There are thirteen inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(25) atom. In the eleventh H site, H(28) is bonded in a single-bond geometry to one C(31) atom. In the twelfth H site, H(31) is bonded in a single-bond geometry to one C(36) atom. In the thirteenth H site, H(34) is bonded in a single-bond geometry to one C(40) atom. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(7) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(11) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(17) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(18) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(27) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(33) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(34) atom. Linkers: 16 CCC(=O)[N][N]C(=O)c1ccccc1[O] ,8 [CH2]C(=O)[N][N]C(=O)c1ccccc1[O] ,8 c1cc(CCc2ccncc2)ccn1. Metal clusters: 24 [Mn]. The MOF has largest included sphere 12.14 A, density 0.87 g/cm3, surface area 4554.76 m2/g, accessible volume 0.76 cm3/g