Zn6C24H12O13(C10H7)2 is Indium-derived structured and crystallizes in the cubic Ia-3 space group. The structure is zero-dimensional and consists of sixteen 2,4-dimethyl-3-prop-1-en-2-ylpenta-1,4-diene molecules and eight Zn6C24H12O13 clusters. In each Zn6C24H12O13 cluster, Zn(1) is bonded to one O(2), one O(3), and two equivalent O(1) atoms to form a mixture of distorted edge and corner-sharing ZnO4 tetrahedra. The Zn(1)-O(2) bond length is 1.99 Å. The Zn(1)-O(3) bond length is 1.96 Å. There is one shorter (2.11 Å) and one longer (2.15 Å) Zn(1)-O(1) bond length. There are four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.43 Å. The C(1)-C(6) bond length is 1.36 Å. The C(1)-C(7) bond length is 1.50 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.18 Å. The C(7)-O(2) bond length is 1.24 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent Zn(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(7) atom. In the third O site, O(3) is bonded in a distorted hexagonal planar geometry to six equivalent Zn(1) atoms. Linkers: 16 [O]C(=O)c1ccc(C(c2ccc(C([O])=O)cc2)c2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 [C]1O[Zn@]23O[C]O[Zn@]24O[C]O[Zn]425O[C]O[Zn]24(O[C]O[Zn@@]42O[C]O[Zn@@]32O1)O5 ,2 [C]1O[Zn]23O[C]O[Zn@@]24O[C]O[Zn]425O[C]O[Zn]24O[C]O[Zn]42(O[C]O[Zn@]32O1)O5 ,1 [C]1O[Zn]23O[C]O[Zn@]24O[C]O[Zn]425O[C]O[Zn]24O[C]O[Zn]42(O[C]O[Zn@@]32O1)O5 ,1 [C]1O[Zn@@]23O[C]O[Zn]245O[C]O[Zn@]42O[C]O[Zn@@]24O[C]O[Zn]42(O[C]O[Zn@]32O1)O5. RCSR code: pyr. The MOF has largest included sphere 5.25 A, density 1.34 g/cm3, surface area 3438.99 m2/g, accessible volume 0.38 cm3/g