CdC13H6(NO2)2(CH)2 crystallizes in the tetragonal I4_1/a space group. The structure consists of thirty-two 02329_fluka molecules inside a CdC13H6(NO2)2 framework. In the CdC13H6(NO2)2 framework, Cd(1) is bonded in a distorted pentagonal planar geometry to one N(1), one N(2), one O(1), and two equivalent O(3) atoms. The Cd(1)-N(1) bond length is 2.18 Å. The Cd(1)-N(2) bond length is 2.25 Å. The Cd(1)-O(1) bond length is 2.53 Å. There is one shorter (2.29 Å) and one longer (2.40 Å) Cd(1)-O(3) bond length. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one N(2) atom. The C(1)-C(6) bond length is 1.47 Å. The C(1)-N(1) bond length is 1.37 Å. The C(1)-N(2) bond length is 1.33 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(4) and one N(1) atom. The C(2)-C(4) bond length is 1.40 Å. The C(2)-N(1) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(3)-O(1) bond length is 1.23 Å. The C(3)-O(2) bond length is 1.32 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one N(2) atom. The C(4)-C(5) bond length is 1.47 Å. The C(4)-N(2) bond length is 1.37 Å. In the fifth C site, C(10) is bonded in a single-bond geometry to one C(9) and one H(3,8) atom. The C(10)-C(9) bond length is 1.42 Å. The C(10)-H(3,8) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(4) atom. The C(11)-C(6) bond length is 1.42 Å. The C(11)-C(8) bond length is 1.42 Å. The C(11)-H(4) bond length is 0.93 Å. In the seventh C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(5)-O(3) bond length is 1.24 Å. The C(5)-O(4) bond length is 1.27 Å. In the eighth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(7) atom. The C(6)-C(7) bond length is 1.42 Å. In the ninth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(2) atom. The C(7)-H(2) bond length is 0.93 Å. In the tenth C site, C(15) is bonded in a distorted single-bond geometry to one C(9) and one H(3,8) atom. The C(15)-C(9) bond length is 1.42 Å. The C(15)-H(3,8) bond length is 0.93 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(8) and one H(7) atom. The C(14)-C(8) bond length is 1.42 Å. The C(14)-H(7) bond length is 0.93 Å. In the twelfth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(15), and one C(8) atom. The C(9)-C(8) bond length is 1.42 Å. In the thirteenth C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(9) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(4) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a distorted single-bond geometry to one O(2) atom. The H(1)-O(2) bond length is 0.82 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3,8) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(14) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Cd(1) and one C(3) atom. In the second O site, O(2) is bonded in a water-like geometry to one C(3) and one H(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Cd(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one C(5) atom. Linkers: 1 [O]C(=O)C1=C(C(=O)O)[N]C(c2ccc3ccccc3c2)=N1 ,6 [O]C(=O)C1=NC(c2ccc3ccccc3c2)=N[C]1C(=O)O. Metal clusters: 8 [Cd]. The MOF has largest included sphere 4.91 A, density 1.38 g/cm3, surface area 3895.05 m2/g, accessible volume 0.35 cm3/g