Cu2C7N2H5O7(CH2)3(C3H2)2(C2NH2O)3 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules; eight 2,3-dimethyl-1,3-butadiene molecules; eight trimethyl isocyanurate molecules; and four Cu2C7N2H5O7 clusters. In each Cu2C7N2H5O7 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded to one N(4), one O(10), one O(4), one O(6), and one O(8) atom to form corner-sharing CuNO4 square pyramids. The Cu(1)-N(4) bond length is 1.99 Å. The Cu(1)-O(10) bond length is 1.98 Å. The Cu(1)-O(4) bond length is 1.99 Å. The Cu(1)-O(6) bond length is 1.96 Å. The Cu(1)-O(8) bond length is 2.19 Å. In the second Cu site, Cu(2) is bonded to one N(5), one O(5), one O(9), and two equivalent O(10) atoms to form a mixture of distorted edge and corner-sharing CuNO4 square pyramids. The Cu(2)-N(5) bond length is 1.97 Å. The Cu(2)-O(5) bond length is 2.41 Å. The Cu(2)-O(9) bond length is 1.94 Å. There is one shorter (1.96 Å) and one longer (1.99 Å) Cu(2)-O(10) bond length. There are seven inequivalent C sites. In the first C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(6)-O(4) bond length is 1.27 Å. The C(6)-O(5) bond length is 1.25 Å. In the second C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(9)-O(6) bond length is 1.27 Å. The C(9)-O(7) bond length is 1.24 Å. In the third C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(8) and one O(9) atom. The C(12)-O(8) bond length is 1.23 Å. The C(12)-O(9) bond length is 1.26 Å. In the fourth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(14) atom. The C(13)-N(4) bond length is 1.32 Å. The C(13)-H(14) bond length is 0.93 Å. In the fifth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(17) atom. The C(17)-N(4) bond length is 1.35 Å. The C(17)-H(17) bond length is 0.93 Å. In the sixth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(18) atom. The C(18)-N(5) bond length is 1.33 Å. The C(18)-H(18) bond length is 0.93 Å. In the seventh C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(21) atom. The C(22)-N(5) bond length is 1.33 Å. The C(22)-H(21) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(17) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Cu(2), one C(18), and one C(22) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(10) atom. The H(1)-O(10) bond length is 0.98 Å. In the second H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(21) is bonded in a single-bond geometry to one C(22) atom. There are seven inequivalent O sites. In the first O site, O(4) is bonded in a water-like geometry to one Cu(1) and one C(6) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to one Cu(2) and one C(6) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(9) atom. In the fourth O site, O(7) is bonded in a single-bond geometry to one C(9) atom. In the fifth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(12) atom. In the sixth O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(12) atom. In the seventh O site, O(10) is bonded to one Cu(1), two equivalent Cu(2), and one H(1) atom to form distorted edge-sharing OCu3H tetrahedra. Linkers: 8 [O]C(=O)CCn1c(=O)n(CCC([O])=O)c(=O)n(CCC([O])=O)c1=O ,8 c1cc(-c2ccncc2)ccn1. Metal clusters: 4 O=[C]O[Cu]1O[C]O[Cu](O)O[C]O[Cu](O[C]=O)O[C]O[Cu](O)O[C]O1. The MOF has largest included sphere 7.32 A, density 0.91 g/cm3, surface area 4135.63 m2/g, accessible volume 0.66 cm3/g