Dy5Ge7C18NH22O32(CH2)5CH3 crystallizes in the monoclinic P2_1/c space group. The structure consists of twenty 02329_fluka molecules and four 02329_fluka molecules inside a Dy5Ge7C18NH22O32 framework. In the Dy5Ge7C18NH22O32 framework, there are five inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(13), one O(19), one O(29), one O(30), one O(7), and one O(8) atom. The Dy(1)-O(10) bond length is 2.30 Å. The Dy(1)-O(11) bond length is 2.33 Å. The Dy(1)-O(13) bond length is 2.45 Å. The Dy(1)-O(19) bond length is 2.49 Å. The Dy(1)-O(29) bond length is 2.30 Å. The Dy(1)-O(30) bond length is 2.37 Å. The Dy(1)-O(7) bond length is 2.28 Å. The Dy(1)-O(8) bond length is 2.34 Å. In the second Dy site, Dy(2) is bonded to one O(10), one O(12), one O(17), one O(24), one O(28), one O(7), and one O(9) atom to form distorted DyO7 pentagonal bipyramids that share  a cornercorner with one Ge(3)CO3 tetrahedra,  a cornercorner with one Ge(6)CO3 tetrahedra,  a cornercorner with one Ge(7)CO3 tetrahedra, and  a cornercorner with one Ge(4)CO4 trigonal bipyramid. The Dy(2)-O(10) bond length is 2.25 Å. The Dy(2)-O(12) bond length is 2.31 Å. The Dy(2)-O(17) bond length is 2.31 Å. The Dy(2)-O(24) bond length is 2.37 Å. The Dy(2)-O(28) bond length is 2.44 Å. The Dy(2)-O(7) bond length is 2.25 Å. The Dy(2)-O(9) bond length is 2.30 Å. In the third Dy site, Dy(3) is bonded in a 7-coordinate geometry to one O(11), one O(12), one O(15), one O(21), one O(31), one O(8), and one O(9) atom. The Dy(3)-O(11) bond length is 2.33 Å. The Dy(3)-O(12) bond length is 2.32 Å. The Dy(3)-O(15) bond length is 2.40 Å. The Dy(3)-O(21) bond length is 2.43 Å. The Dy(3)-O(31) bond length is 2.41 Å. The Dy(3)-O(8) bond length is 2.27 Å. The Dy(3)-O(9) bond length is 2.30 Å. In the fourth Dy site, Dy(4) is bonded to one N(1), one O(14), one O(20), one O(25), one O(26), one O(29), and one O(30) atom to form distorted DyNO6 pentagonal bipyramids that share  a cornercorner with one Ge(7)CO3 tetrahedra. The Dy(4)-N(1) bond length is 2.57 Å. The Dy(4)-O(14) bond length is 2.40 Å. The Dy(4)-O(20) bond length is 2.43 Å. The Dy(4)-O(25) bond length is 2.29 Å. The Dy(4)-O(26) bond length is 2.38 Å. The Dy(4)-O(29) bond length is 2.39 Å. The Dy(4)-O(30) bond length is 2.39 Å. In the fifth Dy site, Dy(5) is bonded in a distorted hexagonal planar geometry to one O(1), one O(2), one O(23), one O(3), one O(4), and one O(5) atom. The Dy(5)-O(1) bond length is 2.50 Å. The Dy(5)-O(2) bond length is 2.37 Å. The Dy(5)-O(23) bond length is 2.24 Å. The Dy(5)-O(3) bond length is 2.55 Å. The Dy(5)-O(4) bond length is 2.31 Å. The Dy(5)-O(5) bond length is 2.55 Å. There are seven inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 4-coordinate geometry to one C(1), one O(1), one O(6), and one O(7) atom. The Ge(1)-C(1) bond length is 1.91 Å. The Ge(1)-O(1) bond length is 1.79 Å. The Ge(1)-O(6) bond length is 1.80 Å. The Ge(1)-O(7) bond length is 1.76 Å. In the second Ge site, Ge(2) is bonded in a 5-coordinate geometry to one C(4), one O(1), one O(15), one O(2), and one O(8) atom. The Ge(2)-C(4) bond length is 1.91 Å. The Ge(2)-O(1) bond length is 1.86 Å. The Ge(2)-O(15) bond length is 2.37 Å. The Ge(2)-O(2) bond length is 1.81 Å. The Ge(2)-O(8) bond length is 1.77 Å. In the third Ge site, Ge(3) is bonded to one C(7), one O(2), one O(3), and one O(9) atom to form distorted GeCO3 tetrahedra that share  a cornercorner with one Dy(2)O7 pentagonal bipyramid and  a cornercorner with one Ge(4)CO4 trigonal bipyramid. The Ge(3)-C(7) bond length is 1.95 Å. The Ge(3)-O(2) bond length is 1.81 Å. The Ge(3)-O(3) bond length is 1.78 Å. The Ge(3)-O(9) bond length is 1.73 Å. In the fourth Ge site, Ge(4) is bonded to one C(10), one O(10), one O(19), one O(3), and one O(4) atom to form distorted GeCO4 trigonal bipyramids that share  a cornercorner with one Dy(2)O7 pentagonal bipyramid,  a cornercorner with one Ge(3)CO3 tetrahedra, and  a cornercorner with one Ge(5)CO4 trigonal bipyramid. The Ge(4)-C(10) bond length is 1.93 Å. The Ge(4)-O(10) bond length is 1.76 Å. The Ge(4)-O(19) bond length is 2.30 Å. The Ge(4)-O(3) bond length is 1.84 Å. The Ge(4)-O(4) bond length is 1.83 Å. In the fifth Ge site, Ge(5) is bonded to one C(13), one O(11), one O(21), one O(4), and one O(5) atom to form distorted GeCO4 trigonal bipyramids that share  a cornercorner with one Ge(6)CO3 tetrahedra and  a cornercorner with one Ge(4)CO4 trigonal bipyramid. The Ge(5)-C(13) bond length is 1.93 Å. The Ge(5)-O(11) bond length is 1.74 Å. The Ge(5)-O(21) bond length is 2.32 Å. The Ge(5)-O(4) bond length is 1.82 Å. The Ge(5)-O(5) bond length is 1.84 Å. In the sixth Ge site, Ge(6) is bonded to one C(16), one O(12), one O(5), and one O(6) atom to form GeCO3 tetrahedra that share  a cornercorner with one Dy(2)O7 pentagonal bipyramid and  a cornercorner with one Ge(5)CO4 trigonal bipyramid. The Ge(6)-C(16) bond length is 1.95 Å. The Ge(6)-O(12) bond length is 1.74 Å. The Ge(6)-O(5) bond length is 1.76 Å. The Ge(6)-O(6) bond length is 1.79 Å. In the seventh Ge site, Ge(7) is bonded to one C(19), one O(27), one O(28), and one O(29) atom to form distorted GeCO3 tetrahedra that share  a cornercorner with one Dy(4)NO6 pentagonal bipyramid and  a cornercorner with one Dy(2)O7 pentagonal bipyramid. The Ge(7)-C(19) bond length is 1.93 Å. The Ge(7)-O(27) bond length is 1.76 Å. The Ge(7)-O(28) bond length is 1.82 Å. The Ge(7)-O(29) bond length is 1.70 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one Ge(1), one H(4), and one H(5) atom. The C(1)-H(4) bond length is 0.97 Å. The C(1)-H(5) bond length is 0.97 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(14) atom. The C(3)-O(13) bond length is 1.26 Å. The C(3)-O(14) bond length is 1.22 Å. In the third C site, C(4) is bonded in a distorted water-like geometry to one Ge(2) and two equivalent H(8,9) atoms. Both C(4)-H(8,9) bond lengths are 0.97 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(15) and one O(16) atom. The C(6)-O(15) bond length is 1.25 Å. The C(6)-O(16) bond length is 1.22 Å. In the fifth C site, C(7) is bonded in a distorted water-like geometry to one Ge(3) and two equivalent H(12,13) atoms. Both C(7)-H(12,13) bond lengths are 0.97 Å. In the sixth C site, C(8) is bonded in a water-like geometry to one C(9), one H(14), and one H(15) atom. The C(8)-C(9) bond length is 1.53 Å. The C(8)-H(14) bond length is 0.97 Å. The C(8)-H(15) bond length is 0.97 Å. In the seventh C site, C(9) is bonded in a 4-coordinate geometry to one C(8), one O(17), one O(18), and one O(32) atom. The C(9)-O(17) bond length is 1.22 Å. The C(9)-O(18) bond length is 1.33 Å. The C(9)-O(32) bond length is 1.35 Å. In the eighth C site, C(10) is bonded in a distorted water-like geometry to one Ge(4), one H(16), and one H(17) atom. The C(10)-H(16) bond length is 0.97 Å. The C(10)-H(17) bond length is 0.97 Å. In the ninth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(19) and one O(20) atom. The C(12)-O(19) bond length is 1.28 Å. The C(12)-O(20) bond length is 1.26 Å. In the tenth C site, C(13) is bonded in a distorted water-like geometry to one Ge(5) and two equivalent H(20,21) atoms. Both C(13)-H(20,21) bond lengths are 0.97 Å. In the eleventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(21) and one O(22) atom. The C(15)-O(21) bond length is 1.25 Å. The C(15)-O(22) bond length is 1.26 Å. In the twelfth C site, C(16) is bonded in a distorted water-like geometry to one Ge(6) and two equivalent H(24,25) atoms. Both C(16)-H(24,25) bond lengths are 0.97 Å. In the thirteenth C site, C(17) is bonded in a water-like geometry to one C(18), one H(26), and one H(27) atom. The C(17)-C(18) bond length is 1.53 Å. The C(17)-H(26) bond length is 0.98 Å. The C(17)-H(27) bond length is 0.97 Å. In the fourteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(23), and one O(24) atom. The C(18)-O(23) bond length is 1.23 Å. The C(18)-O(24) bond length is 1.26 Å. In the fifteenth C site, C(19) is bonded in a distorted water-like geometry to one Ge(7) and two equivalent H(28,29) atoms. Both C(19)-H(28,29) bond lengths are 0.97 Å. In the sixteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(25) and one O(26) atom. The C(21)-O(25) bond length is 1.26 Å. The C(21)-O(26) bond length is 1.21 Å. In the seventeenth C site, C(23) is bonded in a 1-coordinate geometry to one N(1) and one H(35) atom. The C(23)-N(1) bond length is 1.45 Å. The C(23)-H(35) bond length is 0.98 Å. In the eighteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one O(30) and one O(31) atom. The C(24)-O(30) bond length is 1.32 Å. The C(24)-O(31) bond length is 1.23 Å. N(1) is bonded in a 2-coordinate geometry to one Dy(4), one C(23), and one H(1) atom. The N(1)-H(1) bond length is 0.86 Å. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one O(27) atom. The H(2)-O(27) bond length is 0.82 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(28) atom. The H(3)-O(28) bond length is 0.93 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the sixth H site, H(8,9) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(12,13) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(20,21) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(24,25) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(26) is bonded in a single-bond geometry to one C(17) atom. In the fifteenth H site, H(27) is bonded in a single-bond geometry to one C(17) atom. In the sixteenth H site, H(28,29) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(35) is bonded in a single-bond geometry to one C(23) atom. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Dy(5), one Ge(1), and one Ge(2) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Dy(5), one Ge(2), and one Ge(3) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Dy(5), one Ge(3), and one Ge(4) atom. In the fourth O site, O(4) is bonded in a trigonal non-coplanar geometry to one Dy(5), one Ge(4), and one Ge(5) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Dy(5), one Ge(5), and one Ge(6) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ge(1) and one Ge(6) atom. In the seventh O site, O(7) is bonded in a trigonal planar geometry to one Dy(1), one Dy(2), and one Ge(1) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Dy(1), one Dy(3), and one Ge(2) atom. In the ninth O site, O(9) is bonded in a distorted trigonal planar geometry to one Dy(2), one Dy(3), and one Ge(3) atom. In the tenth O site, O(10) is bonded in a distorted trigonal planar geometry to one Dy(1), one Dy(2), and one Ge(4) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal non-coplanar geometry to one Dy(1), one Dy(3), and one Ge(5) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal planar geometry to one Dy(2), one Dy(3), and one Ge(6) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Dy(1) and one C(3) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one Dy(4) and one C(3) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Dy(3), one Ge(2), and one C(6) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one C(6) atom. In the seventeenth O site, O(17) is bonded in a distorted linear geometry to one Dy(2) and one C(9) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one C(9) and one O(32) atom. The O(18)-O(32) bond length is 0.98 Å. In the nineteenth O site, O(19) is bonded in a distorted single-bond geometry to one Dy(1), one Ge(4), and one C(12) atom. In the twentieth O site, O(20) is bonded in a distorted single-bond geometry to one Dy(4) and one C(12) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one Dy(3), one Ge(5), and one C(15) atom. In the twenty-second O site, O(22) is bonded in a single-bond geometry to one C(15) atom. In the twenty-third O site, O(23) is bonded in a bent 150 degrees geometry to one Dy(5) and one C(18) atom. In the twenty-fourth O site, O(24) is bonded in a bent 150 degrees geometry to one Dy(2) and one C(18) atom. In the twenty-fifth O site, O(25) is bonded in a distorted linear geometry to one Dy(4) and one C(21) atom. In the twenty-sixth O site, O(26) is bonded in a distorted bent 120 degrees geometry to one Dy(4) and one C(21) atom. In the twenty-seventh O site, O(27) is bonded in a water-like geometry to one Ge(7) and one H(2) atom. In the twenty-eighth O site, O(28) is bonded in a 3-coordinate geometry to one Dy(2), one Ge(7), and one H(3) atom. In the twenty-ninth O site, O(29) is bonded in a distorted trigonal planar geometry to one Dy(1), one Dy(4), and one Ge(7) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal planar geometry to one Dy(1), one Dy(4), and one C(24) atom. In the thirty-first O site, O(31) is bonded in a distorted bent 150 degrees geometry to one Dy(3) and one C(24) atom. In the thirty-second O site, O(32) is bonded in a distorted single-bond geometry to one C(9) and one O(18) atom. Linkers: 4 [O][Ge]1O[Ge]([O])O[Ge]([O])O[Ge]([O])O[Ge]([O])O[Ge]([O])O1. Metal clusters: 20 [Dy]. The MOF has largest included sphere 8.18 A, density 2.17 g/cm3, surface area 1886.96 m2/g, accessible volume 0.19 cm3/g