ZnC14H10(NO2)2(CH)4 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four ZnC14H10(NO2)2 clusters. In each ZnC14H10(NO2)2 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Zn(1)-N(1) bond lengths are 2.04 Å. Both Zn(1)-O(1) bond lengths are 1.97 Å. There are seven inequivalent C sites. In the first C site, C(5) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(3) atom. The C(5)-C(2) bond length is 1.38 Å. The C(5)-C(4) bond length is 1.40 Å. The C(5)-H(3) bond length is 0.93 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-H(4) bond length is 0.93 Å. In the third C site, C(9) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(9)-C(4) bond length is 1.47 Å. The C(9)-H(6) bond length is 0.93 Å. In the fourth C site, C(1) is bonded in a distorted single-bond geometry to one C(4) and one H(1) atom. The C(1)-C(4) bond length is 1.39 Å. The C(1)-H(1) bond length is 0.93 Å. In the fifth C site, C(2) is bonded in a 3-coordinate geometry to one C(5), one N(1), and one H(2) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 0.93 Å. In the sixth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(3)-O(1) bond length is 1.28 Å. The C(3)-O(2) bond length is 1.24 Å. In the seventh C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(9) atom. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(2), and one C(6) atom. There are five inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. Linkers: 2 [O]C(=O)/C=C/C=C/C([O])=O ,2 O=[C]/C=C/C=C/C(=O)O[Zn](OC(=O)/C=C/C=C/[C]=O)(N1[CH]C=C(/C=C/c2ccncc2)C=C1)N1[CH]C=C(/C=C/c2ccncc2)C=C1 ,2 [CH]1C=C(/C=C/c2ccncc2)C=CN1[Zn]N1[CH]C=C(/C=C/c2ccncc2)C=C1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.21 A, density 1.26 g/cm3, surface area 4785.82 m2/g, accessible volume 0.38 cm3/g