W2Cu3H6(C11N10)2(CH)2 crystallizes in the monoclinic C2/m space group. The structure consists of eight 02329_fluka molecules inside a W2Cu3H6(C11N10)2 framework. In the W2Cu3H6(C11N10)2 framework, there are two inequivalent W sites. In the first W site, W(1) is bonded in a 8-coordinate geometry to one C(11), one C(12), two equivalent C(1), two equivalent C(2), and two equivalent C(3) atoms. The W(1)-C(11) bond length is 2.16 Å. The W(1)-C(12) bond length is 2.17 Å. Both W(1)-C(1) bond lengths are 2.16 Å. Both W(1)-C(2) bond lengths are 2.15 Å. Both W(1)-C(3) bond lengths are 2.16 Å. In the second W site, W(2) is bonded in a 8-coordinate geometry to one C(13), one C(14), two equivalent C(4), two equivalent C(5), and two equivalent C(6) atoms. The W(2)-C(13) bond length is 2.16 Å. The W(2)-C(14) bond length is 2.17 Å. Both W(2)-C(4) bond lengths are 2.16 Å. Both W(2)-C(5) bond lengths are 2.16 Å. Both W(2)-C(6) bond lengths are 2.17 Å. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(5), and two equivalent N(7) atoms. Both Cu(1)-N(1) bond lengths are 1.99 Å. Both Cu(1)-N(5) bond lengths are 2.36 Å. Both Cu(1)-N(7) bond lengths are 2.05 Å. In the second Cu site, Cu(2) is bonded in an octahedral geometry to two equivalent N(3), two equivalent N(6), and two equivalent N(8) atoms. Both Cu(2)-N(3) bond lengths are 2.36 Å. Both Cu(2)-N(6) bond lengths are 2.02 Å. Both Cu(2)-N(8) bond lengths are 2.05 Å. In the third Cu site, Cu(3) is bonded in a rectangular see-saw-like geometry to two equivalent N(2) and two equivalent N(4) atoms. Both Cu(3)-N(2) bond lengths are 1.97 Å. Both Cu(3)-N(4) bond lengths are 1.98 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted linear geometry to one W(1) and one N(1) atom. The C(1)-N(1) bond length is 1.13 Å. In the second C site, C(2) is bonded in a linear geometry to one W(1) and one N(2) atom. The C(2)-N(2) bond length is 1.14 Å. In the third C site, C(3) is bonded in a linear geometry to one W(1) and one N(3) atom. The C(3)-N(3) bond length is 1.14 Å. In the fourth C site, C(4) is bonded in a distorted linear geometry to one W(2) and one N(4) atom. The C(4)-N(4) bond length is 1.13 Å. In the fifth C site, C(5) is bonded in a distorted linear geometry to one W(2) and one N(5) atom. The C(5)-N(5) bond length is 1.15 Å. In the sixth C site, C(6) is bonded in a distorted linear geometry to one W(2) and one N(6) atom. The C(6)-N(6) bond length is 1.14 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(1) atom. The C(7)-N(7) bond length is 1.33 Å. The C(7)-H(1) bond length is 0.93 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(3) atom. The C(9)-N(8) bond length is 1.33 Å. The C(9)-H(3) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(4) atom. The C(10)-N(7) bond length is 1.33 Å. The C(10)-N(8) bond length is 1.32 Å. The C(10)-H(4) bond length is 0.93 Å. In the tenth C site, C(11) is bonded in a distorted linear geometry to one W(1) and one N(9) atom. The C(11)-N(9) bond length is 1.14 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one W(1) and one N(10) atom. The C(12)-N(10) bond length is 1.14 Å. In the twelfth C site, C(13) is bonded in a distorted linear geometry to one W(2) and one N(11) atom. The C(13)-N(11) bond length is 1.14 Å. In the thirteenth C site, C(14) is bonded in a distorted linear geometry to one W(2) and one N(12) atom. The C(14)-N(12) bond length is 1.14 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Cu(1) and one C(1) atom. In the second N site, N(2) is bonded in a linear geometry to one Cu(3) and one C(2) atom. In the third N site, N(3) is bonded in a bent 150 degrees geometry to one Cu(2) and one C(3) atom. In the fourth N site, N(4) is bonded in a linear geometry to one Cu(3) and one C(4) atom. In the fifth N site, N(5) is bonded in a linear geometry to one Cu(1) and one C(5) atom. In the sixth N site, N(6) is bonded in a linear geometry to one Cu(2) and one C(6) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(7) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Cu(2), one C(10), and one C(9) atom. In the ninth N site, N(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth N site, N(10) is bonded in a single-bond geometry to one C(12) atom. In the eleventh N site, N(11) is bonded in a single-bond geometry to one C(13) atom. In the twelfth N site, N(12) is bonded in a single-bond geometry to one C(14) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(10) atom. Linkers: 4 c1cncnc1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 5.02 A, density 1.75 g/cm3, surface area 2849.07 m2/g, accessible volume 0.23 cm3/g