CuC16H8(NO3)2(CH)4 is Indium-derived structured and crystallizes in the cubic Pn-3n space group. The structure is zero-dimensional and consists of ninety-six 02329_fluka molecules and twelve CuC16H8(NO3)2 clusters. In each CuC16H8(NO3)2 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(2) atoms. Both Cu(1)-O(1) bond lengths are 1.88 Å. Both Cu(1)-O(2) bond lengths are 1.97 Å. There are eight inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(8) atom. The C(9)-C(8) bond length is 1.44 Å. In the second C site, C(1) is bonded in a distorted bent 150 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.20 Å. The C(1)-O(2) bond length is 1.23 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.39 Å. In the fourth C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(2) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a single-bond geometry to one C(4) and one N(1) atom. The C(5)-C(4) bond length is 1.39 Å. The C(5)-N(1) bond length is 1.36 Å. In the sixth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(3) atom. The C(4)-H(3) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(5) atom. The C(7)-H(5) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(1), and one O(3) atom. The C(8)-N(1) bond length is 1.30 Å. The C(8)-O(3) bond length is 1.22 Å. N(1) is bonded in a trigonal planar geometry to one C(5), one C(8), and one H(1) atom. The N(1)-H(1) bond length is 0.88 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(8) atom. Linkers: 16 [O]C(=O)c1ccc(NC(=O)c2cc(C(=O)Nc3ccc(C([O])=O)cc3)cc(C(=O)Nc3ccc(C([O])=O)cc3)c2)cc1. Metal clusters: 12 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: pto. The MOF has largest included sphere 21.56 A, density 0.52 g/cm3, surface area 4164.69 m2/g, accessible volume 1.55 cm3/g