Zn3C54H32O13 is gamma nitrogen structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four Zn3C54H32O13 clusters. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(5), and one O(7) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(2)O5 square pyramid and  a cornercorner with one Zn(1)O4 tetrahedra. The Zn(1)-O(2) bond length is 1.97 Å. The Zn(1)-O(3) bond length is 1.95 Å. The Zn(1)-O(5) bond length is 1.91 Å. The Zn(1)-O(7) bond length is 1.98 Å. In the second Zn site, Zn(2) is bonded to one O(7), two equivalent O(1), and two equivalent O(4) atoms to form corner-sharing ZnO5 square pyramids. The Zn(2)-O(7) bond length is 2.06 Å. Both Zn(2)-O(1) bond lengths are 2.05 Å. Both Zn(2)-O(4) bond lengths are 2.09 Å. There are twenty-seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(9) is bonded in a single-bond geometry to one C(10), one C(8), and one H(6) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(8) bond length is 1.41 Å. The C(9)-H(6) bond length is 0.95 Å. In the third C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(14) bond length is 1.51 Å. In the fourth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(7) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(7) bond length is 0.95 Å. In the fifth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(21) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-C(21) bond length is 1.51 Å. In the sixth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(8) atom. The C(13)-C(8) bond length is 1.38 Å. The C(13)-H(8) bond length is 0.95 Å. In the seventh C site, C(14) is bonded in a trigonal planar geometry to one C(10), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.33 Å. The C(14)-C(19) bond length is 1.40 Å. In the eighth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(9) atom. The C(15)-H(9) bond length is 0.95 Å. In the ninth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(12) atom. The C(19)-H(12) bond length is 0.95 Å. In the tenth C site, C(21) is bonded in a trigonal planar geometry to one C(12), one C(22), and one C(26) atom. The C(21)-C(22) bond length is 1.32 Å. The C(21)-C(26) bond length is 1.42 Å. In the eleventh C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(13) atom. The C(22)-H(13) bond length is 0.95 Å. In the twelfth C site, C(26) is bonded in a single-bond geometry to one C(21) and one H(16) atom. The C(26)-H(16) bond length is 0.95 Å. In the thirteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(3), and one O(4) atom. The C(20)-C(17) bond length is 1.51 Å. The C(20)-O(3) bond length is 1.27 Å. The C(20)-O(4) bond length is 1.23 Å. In the fourteenth C site, C(23) is bonded in a single-bond geometry to one C(24) and one H(14) atom. The C(23)-C(24) bond length is 1.34 Å. The C(23)-H(14) bond length is 0.95 Å. In the fifteenth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(27) atom. The C(24)-C(25) bond length is 1.33 Å. The C(24)-C(27) bond length is 1.58 Å. In the sixteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(15) atom. The C(25)-H(15) bond length is 0.95 Å. In the seventeenth C site, C(27) is bonded in a bent 120 degrees geometry to one C(24), one O(5), and one O(6) atom. The C(27)-O(5) bond length is 1.17 Å. The C(27)-O(6) bond length is 1.20 Å. In the eighteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(10) atom. The C(16)-C(17) bond length is 1.36 Å. The C(16)-H(10) bond length is 0.95 Å. In the nineteenth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.36 Å. The C(2)-C(7) bond length is 1.38 Å. In the twentieth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 0.95 Å. In the twenty-first C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(4)-C(5) bond length is 1.36 Å. The C(4)-H(3) bond length is 0.95 Å. In the twenty-second C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.43 Å. The C(5)-C(8) bond length is 1.50 Å. In the twenty-third C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.42 Å. In the twenty-fourth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one H(4) atom. The C(6)-C(7) bond length is 1.37 Å. The C(6)-H(4) bond length is 0.95 Å. In the twenty-fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(5) atom. The C(7)-H(5) bond length is 0.95 Å. In the twenty-sixth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(5), and one C(9) atom. In the twenty-seventh C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(11) atom. The C(18)-H(11) bond length is 0.95 Å. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(6) atom. The H(1)-O(6) bond length is 0.84 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(23) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(26) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(20) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(20) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(27) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one C(27) and one H(1) atom. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to one Zn(2) and two equivalent Zn(1) atoms. Linkers: 8 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C(=O)O)cc3)c2)cc1. Metal clusters: 4 O[C]O[Zn@]12O[C]O[Zn]3(O[C]O[Zn@](O[C]O)(O[C]O3)O1)O[C]O2. RCSR code: sit. The MOF has largest included sphere 10.51 A, density 0.77 g/cm3, surface area 4591.67 m2/g, accessible volume 0.87 cm3/g