LiC4H7O5(C5H7)2(CH2)9(CH)2CH3CH3C(O)COCH2O is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, thirty-six 02329_fluka molecules, four 02329_fluka molecules, four dimethoxymethane molecules, four methanol molecules, eight neopentane molecules, and four LiC4H7O5 clusters. In each LiC4H7O5 cluster, Li(1) is bonded in a tetrahedral geometry to one O(1), one O(5), one O(6), and one O(8) atom. The Li(1)-O(1) bond length is 1.88 Å. The Li(1)-O(5) bond length is 1.89 Å. The Li(1)-O(6) bond length is 1.96 Å. The Li(1)-O(8) bond length is 1.97 Å. There are four inequivalent C sites. In the first C site, C(27) is bonded in a distorted water-like geometry to one H(41) and one O(6) atom. The C(27)-H(41) bond length is 1.00 Å. The C(27)-O(6) bond length is 1.43 Å. In the second C site, C(30) is bonded in a distorted trigonal non-coplanar geometry to one H(47), one H(48), and one O(8) atom. The C(30)-H(47) bond length is 0.99 Å. The C(30)-H(48) bond length is 0.99 Å. The C(30)-O(8) bond length is 1.42 Å. In the third C site, C(26) is bonded in a distorted water-like geometry to one H(40) and one O(5) atom. The C(26)-H(40) bond length is 1.00 Å. The C(26)-O(5) bond length is 1.42 Å. In the fourth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(21)-O(1) bond length is 1.26 Å. The C(21)-O(2) bond length is 1.26 Å. There are seven inequivalent H sites. In the first H site, H(40) is bonded in a single-bond geometry to one C(26) atom. In the second H site, H(41) is bonded in a single-bond geometry to one C(27) atom. In the third H site, H(44) is bonded in a single-bond geometry to one O(5) atom. The H(44)-O(5) bond length is 0.84 Å. In the fourth H site, H(45) is bonded in a single-bond geometry to one O(6) atom. The H(45)-O(6) bond length is 0.84 Å. In the fifth H site, H(47) is bonded in a single-bond geometry to one C(30) atom. In the sixth H site, H(48) is bonded in a single-bond geometry to one C(30) atom. In the seventh H site, H(49) is bonded in a single-bond geometry to one O(8) atom. The H(49)-O(8) bond length is 0.84 Å. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Li(1) and one C(21) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(21) atom. In the third O site, O(5) is bonded in a 3-coordinate geometry to one Li(1), one C(26), and one H(44) atom. In the fourth O site, O(6) is bonded in a distorted trigonal planar geometry to one Li(1), one C(27), and one H(45) atom. In the fifth O site, O(8) is bonded in a distorted trigonal planar geometry to one Li(1), one C(30), and one H(49) atom. Linkers: 2 [CH2][C@]12CC[C@@H](O[C@H]3O[C@H](CO)[C@@H](O)[C@H](O)[C@H]3O)C[C]1[C]C[C@H]1[C@@H]3CC[C@H]([C@H](C)CCC([O])=O)[C@@]3(C)CC[C@@H]12 ,4 C[C@H](CCC([O])=O)[C@H]1CC[C@H]2[C@@H]3CC[C@@H]4C[C@H](O[C@H]5O[C@H](CO)[C@@H](O)[C@H](O)[C@H]5O)CC[C@]4(C)[C@H]3CC[C@]12C ,2 C[C@H](C[C][C]=O)[C@H]1CC[C@H]2[C@@H]3CC[C@@H]4C[C@H](O[C@H]5O[C@H](CO)[C@@H](O)[C@H](O)[C@H]5O)CC[C@]4(C)[C@H]3CC[C@]12C. Metal clusters: 4 [Li]. The MOF has largest included sphere 5.19 A, density 1.04 g/cm3, surface area 5451.89 m2/g, accessible volume 0.39 cm3/g