Eu3C24H12(NO5)7(CH)4(C3H2)4(C5NH4)4(C6NH4)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules; four 14967-65-8 molecules; eight 2,3-dimethyl-1,3-butadiene molecules; sixteen n,n-dimethylprop-1-en-2-amine molecules; and four Eu3C24H12(NO5)7 clusters. In each Eu3C24H12(NO5)7 cluster, there are two inequivalent Eu sites. In the first Eu site, Eu(1) is bonded in a 9-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. The Eu(1)-O(1) bond length is 2.41 Å. The Eu(1)-O(2) bond length is 2.40 Å. The Eu(1)-O(3) bond length is 2.63 Å. The Eu(1)-O(4) bond length is 2.61 Å. The Eu(1)-O(5) bond length is 2.85 Å. The Eu(1)-O(6) bond length is 2.61 Å. The Eu(1)-O(7) bond length is 2.67 Å. The Eu(1)-O(8) bond length is 2.69 Å. The Eu(1)-O(9) bond length is 2.44 Å. In the second Eu site, Eu(2) is bonded in a 10-coordinate geometry to two equivalent O(10), two equivalent O(11), two equivalent O(15), two equivalent O(16), and two equivalent O(17) atoms. Both Eu(2)-O(10) bond lengths are 2.38 Å. Both Eu(2)-O(11) bond lengths are 2.37 Å. Both Eu(2)-O(15) bond lengths are 2.42 Å. Both Eu(2)-O(16) bond lengths are 2.62 Å. Both Eu(2)-O(17) bond lengths are 2.46 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(10) atom. The C(1)-C(3) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(10) bond length is 1.23 Å. In the second C site, C(2) is bonded in a 4-coordinate geometry to one C(4), one O(11), one O(17), and one O(2) atom. The C(2)-C(4) bond length is 1.51 Å. The C(2)-O(11) bond length is 1.31 Å. The C(2)-O(17) bond length is 1.33 Å. The C(2)-O(2) bond length is 1.21 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(6) atom. The C(3)-C(5) bond length is 1.39 Å. The C(3)-C(6) bond length is 1.37 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(7), and one C(8) atom. The C(4)-C(7) bond length is 1.38 Å. The C(4)-C(8) bond length is 1.37 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(5)-H(1) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(6)-H(2) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(7)-H(3) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a single-bond geometry to one C(4) and one H(4) atom. The C(8)-H(4) bond length is 0.93 Å. In the ninth C site, C(33) is bonded in a distorted single-bond geometry to one C(35) and one H(23) atom. The C(33)-C(35) bond length is 1.38 Å. The C(33)-H(23) bond length is 0.93 Å. In the tenth C site, C(34) is bonded in a distorted single-bond geometry to one C(35) and one H(24) atom. The C(34)-C(35) bond length is 1.39 Å. The C(34)-H(24) bond length is 0.93 Å. In the eleventh C site, C(35) is bonded in a trigonal planar geometry to one C(33), one C(34), and one C(36) atom. The C(35)-C(36) bond length is 1.50 Å. In the twelfth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(15), and one O(9) atom. The C(36)-O(15) bond length is 1.25 Å. The C(36)-O(9) bond length is 1.26 Å. There are four inequivalent N sites. In the first N site, N(7) is bonded in a trigonal planar geometry to one O(18) and two equivalent O(16) atoms. The N(7)-O(18) bond length is 1.27 Å. Both N(7)-O(16) bond lengths are 1.26 Å. In the second N site, N(1) is bonded in a trigonal planar geometry to one O(12), one O(3), and one O(4) atom. The N(1)-O(12) bond length is 1.23 Å. The N(1)-O(3) bond length is 1.25 Å. The N(1)-O(4) bond length is 1.26 Å. In the third N site, N(2) is bonded in a trigonal planar geometry to one O(13), one O(5), and one O(6) atom. The N(2)-O(13) bond length is 1.28 Å. The N(2)-O(5) bond length is 1.24 Å. The N(2)-O(6) bond length is 1.18 Å. In the fourth N site, N(3) is bonded in a trigonal planar geometry to one O(14), one O(7), and one O(8) atom. The N(3)-O(14) bond length is 1.24 Å. The N(3)-O(7) bond length is 1.28 Å. The N(3)-O(8) bond length is 1.25 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(23) is bonded in a single-bond geometry to one C(33) atom. In the sixth H site, H(24) is bonded in a single-bond geometry to one C(34) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Eu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Eu(1) and one C(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Eu(1) and one N(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Eu(1) and one N(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one Eu(1) and one N(2) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Eu(1) and one N(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Eu(1) and one N(3) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one Eu(1) and one N(3) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Eu(1) and one C(36) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Eu(2) and one C(1) atom. In the eleventh O site, O(12) is bonded in a single-bond geometry to one N(1) atom. In the twelfth O site, O(13) is bonded in a single-bond geometry to one N(2) atom. In the thirteenth O site, O(14) is bonded in a single-bond geometry to one N(3) atom. In the fourteenth O site, O(15) is bonded in a distorted single-bond geometry to one Eu(2) and one C(36) atom. In the fifteenth O site, O(11) is bonded in a 3-coordinate geometry to one Eu(2), one C(2), and one O(17) atom. The O(11)-O(17) bond length is 0.92 Å. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one Eu(2) and one N(7) atom. In the seventeenth O site, O(17) is bonded in a 3-coordinate geometry to one Eu(2), one C(2), and one O(11) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one N(7) atom. Linkers: 6 [O]O[C]=O.[O]O[C]=O.[c]1ccc(N2[CH]C=C(C3=C[CH]N(c4cc[c]cc4)C=C3)C=C2)cc1 ,8 [O]C(=O)c1ccc(N2[CH]C=C(C3=C[CH]N(c4ccc(C([O])=O)cc4)C=C3)C=C2)cc1. Metal clusters: 12 [Eu]. The MOF has largest included sphere 4.28 A, density 1.49 g/cm3, surface area 3877.79 m2/g, accessible volume 0.23 cm3/g