(Zn2C20N7H14I4)2ZnC16N5H10I2ZnC4H4(NI)2(C4NH2)3 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four C4NH2 clusters, eight Zn2C20N7H14I4 clusters, four ZnC16N5H10I2 clusters, and four ZnC4H4(NI)2 clusters. In each C4NH2 cluster, there are twelve inequivalent C sites. In the first C site, C(38) is bonded in a distorted single-bond geometry to one C(41) and one H(26) atom. The C(38)-C(41) bond length is 1.40 Å. The C(38)-H(26) bond length is 0.93 Å. In the second C site, C(40) is bonded in a distorted single-bond geometry to one C(41) and one H(28) atom. The C(40)-C(41) bond length is 1.35 Å. The C(40)-H(28) bond length is 0.93 Å. In the third C site, C(41) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(42) atom. The C(41)-C(42) bond length is 1.51 Å. In the fourth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(41), one N(16), and one N(18) atom. The C(42)-N(16) bond length is 1.34 Å. The C(42)-N(18) bond length is 1.29 Å. In the fifth C site, C(44) is bonded in a distorted single-bond geometry to one C(47) and one H(30) atom. The C(44)-C(47) bond length is 1.39 Å. The C(44)-H(30) bond length is 0.93 Å. In the sixth C site, C(46) is bonded in a distorted single-bond geometry to one C(47) and one H(32) atom. The C(46)-C(47) bond length is 1.38 Å. The C(46)-H(32) bond length is 0.93 Å. In the seventh C site, C(47) is bonded in a trigonal planar geometry to one C(44), one C(46), and one C(48) atom. The C(47)-C(48) bond length is 1.46 Å. In the eighth C site, C(48) is bonded in a distorted trigonal planar geometry to one C(47), one N(16), and one N(17) atom. The C(48)-N(16) bond length is 1.29 Å. The C(48)-N(17) bond length is 1.35 Å. In the ninth C site, C(50) is bonded in a distorted single-bond geometry to one C(53) and one H(34) atom. The C(50)-C(53) bond length is 1.40 Å. The C(50)-H(34) bond length is 0.93 Å. In the tenth C site, C(52) is bonded in a distorted single-bond geometry to one C(53) and one H(36) atom. The C(52)-C(53) bond length is 1.31 Å. The C(52)-H(36) bond length is 0.93 Å. In the eleventh C site, C(53) is bonded in a trigonal planar geometry to one C(50), one C(52), and one C(54) atom. The C(53)-C(54) bond length is 1.51 Å. In the twelfth C site, C(54) is bonded in a distorted trigonal planar geometry to one C(53), one N(17), and one N(18) atom. The C(54)-N(17) bond length is 1.31 Å. The C(54)-N(18) bond length is 1.30 Å. There are three inequivalent N sites. In the first N site, N(16) is bonded in a bent 120 degrees geometry to one C(42) and one C(48) atom. In the second N site, N(17) is bonded in a bent 120 degrees geometry to one C(48) and one C(54) atom. In the third N site, N(18) is bonded in a bent 120 degrees geometry to one C(42) and one C(54) atom. There are six inequivalent H sites. In the first H site, H(34) is bonded in a single-bond geometry to one C(50) atom. In the second H site, H(36) is bonded in a single-bond geometry to one C(52) atom. In the third H site, H(26) is bonded in a single-bond geometry to one C(38) atom. In the fourth H site, H(28) is bonded in a single-bond geometry to one C(40) atom. In the fifth H site, H(30) is bonded in a single-bond geometry to one C(44) atom. In the sixth H site, H(32) is bonded in a single-bond geometry to one C(46) atom. In four of the Zn2C20N7H14I4 clusters, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one N(2), one N(8), one I(1), and one I(2) atom. The Zn(1)-N(2) bond length is 2.07 Å. The Zn(1)-N(8) bond length is 2.05 Å. The Zn(1)-I(1) bond length is 2.55 Å. The Zn(1)-I(2) bond length is 2.55 Å. In the second Zn site, Zn(3) is bonded in a distorted tetrahedral geometry to one N(1), one N(9), one I(5), and one I(6) atom. The Zn(3)-N(1) bond length is 2.05 Å. The Zn(3)-N(9) bond length is 2.04 Å. The Zn(3)-I(5) bond length is 2.55 Å. The Zn(3)-I(6) bond length is 2.54 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one H(2) atom. The C(2)-C(5) bond length is 1.41 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(3)-N(1) bond length is 1.37 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-H(4) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.46 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one N(4), and one N(6) atom. The C(6)-N(4) bond length is 1.36 Å. The C(6)-N(6) bond length is 1.33 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(2), and one H(5) atom. The C(7)-C(8) bond length is 1.36 Å. The C(7)-N(2) bond length is 1.33 Å. The C(7)-H(5) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(11), one C(7), and one H(6) atom. The C(8)-C(11) bond length is 1.38 Å. The C(8)-H(6) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(9)-N(2) bond length is 1.38 Å. The C(9)-H(7) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(10)-C(11) bond length is 1.36 Å. The C(10)-H(8) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(8) atom. The C(11)-C(12) bond length is 1.52 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(4), and one N(5) atom. The C(12)-N(4) bond length is 1.37 Å. The C(12)-N(5) bond length is 1.32 Å. In the thirteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(17) and one H(10) atom. The C(14)-C(17) bond length is 1.37 Å. The C(14)-H(10) bond length is 0.93 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(12) atom. The C(16)-C(17) bond length is 1.46 Å. The C(16)-H(12) bond length is 0.93 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(17)-C(18) bond length is 1.50 Å. In the sixteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one N(5), and one N(6) atom. The C(18)-N(5) bond length is 1.37 Å. The C(18)-N(6) bond length is 1.31 Å. In the seventeenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(17) atom. The C(25)-N(8) bond length is 1.37 Å. The C(25)-H(17) bond length is 0.93 Å. In the eighteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(19) atom. The C(27)-N(8) bond length is 1.32 Å. The C(27)-H(19) bond length is 0.93 Å. In the nineteenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(21) atom. The C(31)-N(9) bond length is 1.36 Å. The C(31)-H(21) bond length is 0.93 Å. In the twentieth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(23) atom. The C(33)-N(9) bond length is 1.37 Å. The C(33)-H(23) bond length is 0.93 Å. There are seven inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(7), and one C(9) atom. In the second N site, N(4) is bonded in a bent 120 degrees geometry to one C(12) and one C(6) atom. In the third N site, N(5) is bonded in a bent 120 degrees geometry to one C(12) and one C(18) atom. In the fourth N site, N(6) is bonded in a bent 120 degrees geometry to one C(18) and one C(6) atom. In the fifth N site, N(1) is bonded in a trigonal planar geometry to one Zn(3), one C(1), and one C(3) atom. In the sixth N site, N(8) is bonded in a trigonal planar geometry to one Zn(1), one C(25), and one C(27) atom. In the seventh N site, N(9) is bonded in a trigonal planar geometry to one Zn(3), one C(31), and one C(33) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(23) is bonded in a single-bond geometry to one C(33) atom. There are four inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Zn(1) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Zn(1) atom. In the third I site, I(5) is bonded in a single-bond geometry to one Zn(3) atom. In the fourth I site, I(6) is bonded in a single-bond geometry to one Zn(3) atom. In four of the Zn2C20N7H14I4 clusters, there are two inequivalent Zn sites. In the first Zn site, Zn(5) is bonded in a tetrahedral geometry to one N(13), one N(20), one I(10), and one I(9) atom. The Zn(5)-N(13) bond length is 2.07 Å. The Zn(5)-N(20) bond length is 2.07 Å. The Zn(5)-I(10) bond length is 2.54 Å. The Zn(5)-I(9) bond length is 2.57 Å. In the second Zn site, Zn(6) is bonded in a tetrahedral geometry to one N(14), one N(21), one I(11), and one I(12) atom. The Zn(6)-N(14) bond length is 2.07 Å. The Zn(6)-N(21) bond length is 2.05 Å. The Zn(6)-I(11) bond length is 2.56 Å. The Zn(6)-I(12) bond length is 2.56 Å. There are twenty inequivalent C sites. In the first C site, C(61) is bonded in a distorted bent 120 degrees geometry to one N(20) and one H(41) atom. The C(61)-N(20) bond length is 1.30 Å. The C(61)-H(41) bond length is 0.93 Å. In the second C site, C(62) is bonded in a distorted single-bond geometry to one C(65) and one H(42) atom. The C(62)-C(65) bond length is 1.37 Å. The C(62)-H(42) bond length is 0.93 Å. In the third C site, C(63) is bonded in a distorted bent 120 degrees geometry to one C(64), one N(20), and one H(43) atom. The C(63)-C(64) bond length is 1.43 Å. The C(63)-N(20) bond length is 1.40 Å. The C(63)-H(43) bond length is 0.93 Å. In the fourth C site, C(64) is bonded in a distorted trigonal planar geometry to one C(63), one C(65), and one H(44) atom. The C(64)-C(65) bond length is 1.32 Å. The C(64)-H(44) bond length is 0.93 Å. In the fifth C site, C(65) is bonded in a trigonal planar geometry to one C(62), one C(64), and one C(66) atom. The C(65)-C(66) bond length is 1.53 Å. In the sixth C site, C(66) is bonded in a distorted trigonal planar geometry to one C(65), one N(22), and one N(23) atom. The C(66)-N(22) bond length is 1.31 Å. The C(66)-N(23) bond length is 1.31 Å. In the seventh C site, C(68) is bonded in a distorted single-bond geometry to one C(71) and one H(46) atom. The C(68)-C(71) bond length is 1.43 Å. The C(68)-H(46) bond length is 0.93 Å. In the eighth C site, C(70) is bonded in a distorted single-bond geometry to one C(69), one C(71), and one H(48) atom. The C(70)-C(69) bond length is 1.36 Å. The C(70)-C(71) bond length is 1.38 Å. The C(70)-H(48) bond length is 0.93 Å. In the ninth C site, C(71) is bonded in a trigonal planar geometry to one C(68), one C(70), and one C(72) atom. The C(71)-C(72) bond length is 1.42 Å. In the tenth C site, C(72) is bonded in a trigonal planar geometry to one C(71), one N(23), and one N(24) atom. The C(72)-N(23) bond length is 1.40 Å. The C(72)-N(24) bond length is 1.32 Å. In the eleventh C site, C(67) is bonded in a distorted bent 120 degrees geometry to one N(21) and one H(45) atom. The C(67)-N(21) bond length is 1.30 Å. The C(67)-H(45) bond length is 0.93 Å. In the twelfth C site, C(69) is bonded in a distorted trigonal planar geometry to one C(70), one N(21), and one H(47) atom. The C(69)-N(21) bond length is 1.36 Å. The C(69)-H(47) bond length is 0.93 Å. In the thirteenth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one N(13) and one H(25) atom. The C(37)-N(13) bond length is 1.32 Å. The C(37)-H(25) bond length is 0.93 Å. In the fourteenth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one N(13) and one H(27) atom. The C(39)-N(13) bond length is 1.33 Å. The C(39)-H(27) bond length is 0.93 Å. In the fifteenth C site, C(43) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(29) atom. The C(43)-N(14) bond length is 1.34 Å. The C(43)-H(29) bond length is 0.93 Å. In the sixteenth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(31) atom. The C(45)-N(14) bond length is 1.30 Å. The C(45)-H(31) bond length is 0.93 Å. In the seventeenth C site, C(56) is bonded in a distorted single-bond geometry to one C(59) and one H(38) atom. The C(56)-C(59) bond length is 1.40 Å. The C(56)-H(38) bond length is 0.93 Å. In the eighteenth C site, C(58) is bonded in a distorted single-bond geometry to one C(59) and one H(40) atom. The C(58)-C(59) bond length is 1.37 Å. The C(58)-H(40) bond length is 0.93 Å. In the nineteenth C site, C(59) is bonded in a trigonal planar geometry to one C(56), one C(58), and one C(60) atom. The C(59)-C(60) bond length is 1.54 Å. In the twentieth C site, C(60) is bonded in a distorted trigonal planar geometry to one C(59), one N(22), and one N(24) atom. The C(60)-N(22) bond length is 1.32 Å. The C(60)-N(24) bond length is 1.31 Å. There are seven inequivalent N sites. In the first N site, N(13) is bonded in a trigonal planar geometry to one Zn(5), one C(37), and one C(39) atom. In the second N site, N(14) is bonded in a trigonal planar geometry to one Zn(6), one C(43), and one C(45) atom. In the third N site, N(20) is bonded in a trigonal planar geometry to one Zn(5), one C(61), and one C(63) atom. In the fourth N site, N(21) is bonded in a trigonal planar geometry to one Zn(6), one C(67), and one C(69) atom. In the fifth N site, N(22) is bonded in a bent 120 degrees geometry to one C(60) and one C(66) atom. In the sixth N site, N(23) is bonded in a bent 120 degrees geometry to one C(66) and one C(72) atom. In the seventh N site, N(24) is bonded in a bent 120 degrees geometry to one C(60) and one C(72) atom. There are fourteen inequivalent H sites. In the first H site, H(38) is bonded in a single-bond geometry to one C(56) atom. In the second H site, H(41) is bonded in a single-bond geometry to one C(61) atom. In the third H site, H(42) is bonded in a single-bond geometry to one C(62) atom. In the fourth H site, H(43) is bonded in a single-bond geometry to one C(63) atom. In the fifth H site, H(44) is bonded in a single-bond geometry to one C(64) atom. In the sixth H site, H(48) is bonded in a single-bond geometry to one C(70) atom. In the seventh H site, H(46) is bonded in a single-bond geometry to one C(68) atom. In the eighth H site, H(47) is bonded in a single-bond geometry to one C(69) atom. In the ninth H site, H(40) is bonded in a single-bond geometry to one C(58) atom. In the tenth H site, H(45) is bonded in a single-bond geometry to one C(67) atom. In the eleventh H site, H(27) is bonded in a single-bond geometry to one C(39) atom. In the twelfth H site, H(25) is bonded in a single-bond geometry to one C(37) atom. In the thirteenth H site, H(31) is bonded in a single-bond geometry to one C(45) atom. In the fourteenth H site, H(29) is bonded in a single-bond geometry to one C(43) atom. There are four inequivalent I sites. In the first I site, I(9) is bonded in a single-bond geometry to one Zn(5) atom. In the second I site, I(10) is bonded in a single-bond geometry to one Zn(5) atom. In the third I site, I(11) is bonded in a single-bond geometry to one Zn(6) atom. In the fourth I site, I(12) is bonded in a single-bond geometry to one Zn(6) atom. In each ZnC16N5H10I2 cluster, Zn(2) is bonded in a tetrahedral geometry to one N(3), one N(7), one I(3), and one I(4) atom. The Zn(2)-N(3) bond length is 2.05 Å. The Zn(2)-N(7) bond length is 2.07 Å. The Zn(2)-I(3) bond length is 2.56 Å. The Zn(2)-I(4) bond length is 2.53 Å. There are sixteen inequivalent C sites. In the first C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(13)-N(3) bond length is 1.38 Å. The C(13)-H(9) bond length is 0.93 Å. In the second C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(11) atom. The C(15)-N(3) bond length is 1.36 Å. The C(15)-H(11) bond length is 0.93 Å. In the third C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(13) atom. The C(19)-N(7) bond length is 1.37 Å. The C(19)-H(13) bond length is 0.93 Å. In the fourth C site, C(20) is bonded in a distorted single-bond geometry to one C(23) and one H(14) atom. The C(20)-C(23) bond length is 1.37 Å. The C(20)-H(14) bond length is 0.93 Å. In the fifth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(7), and one H(15) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-N(7) bond length is 1.33 Å. The C(21)-H(15) bond length is 0.93 Å. In the sixth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one H(16) atom. The C(22)-C(23) bond length is 1.41 Å. The C(22)-H(16) bond length is 0.93 Å. In the seventh C site, C(23) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(23)-C(24) bond length is 1.47 Å. In the eighth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one N(10), and one N(12) atom. The C(24)-N(10) bond length is 1.32 Å. The C(24)-N(12) bond length is 1.34 Å. In the ninth C site, C(26) is bonded in a distorted single-bond geometry to one C(29) and one H(18) atom. The C(26)-C(29) bond length is 1.40 Å. The C(26)-H(18) bond length is 0.93 Å. In the tenth C site, C(28) is bonded in a distorted single-bond geometry to one C(29) and one H(20) atom. The C(28)-C(29) bond length is 1.38 Å. The C(28)-H(20) bond length is 0.93 Å. In the eleventh C site, C(29) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(30) atom. The C(29)-C(30) bond length is 1.47 Å. In the twelfth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one N(10), and one N(11) atom. The C(30)-N(10) bond length is 1.38 Å. The C(30)-N(11) bond length is 1.32 Å. In the thirteenth C site, C(32) is bonded in a distorted single-bond geometry to one C(35) and one H(22,24) atom. The C(32)-C(35) bond length is 1.37 Å. The C(32)-H(22,24) bond length is 0.93 Å. In the fourteenth C site, C(34) is bonded in a distorted single-bond geometry to one C(35) and one H(22,24) atom. The C(34)-C(35) bond length is 1.37 Å. The C(34)-H(22,24) bond length is 0.93 Å. In the fifteenth C site, C(35) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(36) atom. The C(35)-C(36) bond length is 1.49 Å. In the sixteenth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(35), one N(11), and one N(12) atom. The C(36)-N(11) bond length is 1.33 Å. The C(36)-N(12) bond length is 1.31 Å. There are five inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(13), and one C(15) atom. In the second N site, N(7) is bonded in a trigonal planar geometry to one Zn(2), one C(19), and one C(21) atom. In the third N site, N(10) is bonded in a bent 120 degrees geometry to one C(24) and one C(30) atom. In the fourth N site, N(11) is bonded in a bent 120 degrees geometry to one C(30) and one C(36) atom. In the fifth N site, N(12) is bonded in a bent 120 degrees geometry to one C(24) and one C(36) atom. There are nine inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(28) atom. In the ninth H site, H(22,24) is bonded in a single-bond geometry to one C(32) atom. There are two inequivalent I sites. In the first I site, I(4) is bonded in a single-bond geometry to one Zn(2) atom. In the second I site, I(3) is bonded in a single-bond geometry to one Zn(2) atom. In each ZnC4H4(NI)2 cluster, Zn(4) is bonded in a distorted tetrahedral geometry to one N(15), one N(19), one I(7), and one I(8) atom. The Zn(4)-N(15) bond length is 2.06 Å. The Zn(4)-N(19) bond length is 2.07 Å. The Zn(4)-I(7) bond length is 2.56 Å. The Zn(4)-I(8) bond length is 2.54 Å. There are four inequivalent C sites. In the first C site, C(55) is bonded in a distorted bent 120 degrees geometry to one N(19) and one H(37) atom. The C(55)-N(19) bond length is 1.33 Å. The C(55)-H(37) bond length is 0.93 Å. In the second C site, C(49) is bonded in a distorted bent 120 degrees geometry to one N(15) and one H(33) atom. The C(49)-N(15) bond length is 1.38 Å. The C(49)-H(33) bond length is 0.93 Å. In the third C site, C(51) is bonded in a distorted bent 120 degrees geometry to one N(15) and one H(35) atom. The C(51)-N(15) bond length is 1.31 Å. The C(51)-H(35) bond length is 0.93 Å. In the fourth C site, C(57) is bonded in a distorted bent 120 degrees geometry to one N(19) and one H(39) atom. The C(57)-N(19) bond length is 1.29 Å. The C(57)-H(39) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(15) is bonded in a trigonal planar geometry to one Zn(4), one C(49), and one C(51) atom. In the second N site, N(19) is bonded in a trigonal planar geometry to one Zn(4), one C(55), and one C(57) atom. There are four inequivalent H sites. In the first H site, H(33) is bonded in a single-bond geometry to one C(49) atom. In the second H site, H(35) is bonded in a single-bond geometry to one C(51) atom. In the third H site, H(37) is bonded in a single-bond geometry to one C(55) atom. In the fourth H site, H(39) is bonded in a single-bond geometry to one C(57) atom. There are two inequivalent I sites. In the first I site, I(7) is bonded in a single-bond geometry to one Zn(4) atom. In the second I site, I(8) is bonded in a single-bond geometry to one Zn(4) atom. Linkers: 16 n1ccc(cc1)C1=NC(=[N]=C([N]1)c1ccncc1)c1ccncc1. Metal clusters: 24 I[Zn]I. The MOF has largest included sphere 8.21 A, density 1.22 g/cm3, surface area 3304.88 m2/g, accessible volume 0.50 cm3/g