Zn4C36H36O13 crystallizes in the triclinic P1 space group. There are eight inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(11), one O(3), and one O(7) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.94 Å. The Zn(1)-O(11) bond length is 1.93 Å. The Zn(1)-O(3) bond length is 1.93 Å. The Zn(1)-O(7) bond length is 1.93 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(14), one O(4), and one O(9) atom to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(1) bond length is 1.94 Å. The Zn(2)-O(14) bond length is 1.93 Å. The Zn(2)-O(4) bond length is 1.93 Å. The Zn(2)-O(9) bond length is 1.93 Å. In the third Zn site, Zn(3) is bonded to one O(1), one O(10), one O(12), and one O(5) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(1) bond length is 1.94 Å. The Zn(3)-O(10) bond length is 1.93 Å. The Zn(3)-O(12) bond length is 1.93 Å. The Zn(3)-O(5) bond length is 1.93 Å. In the fourth Zn site, Zn(4) is bonded to one O(1), one O(13), one O(6), and one O(8) atom to form corner-sharing ZnO4 tetrahedra. The Zn(4)-O(1) bond length is 1.94 Å. The Zn(4)-O(13) bond length is 1.93 Å. The Zn(4)-O(6) bond length is 1.93 Å. The Zn(4)-O(8) bond length is 1.93 Å. In the fifth Zn site, Zn(5) is bonded to one O(15), one O(19), one O(2), and one O(23) atom to form corner-sharing ZnO4 tetrahedra. The Zn(5)-O(15) bond length is 1.93 Å. The Zn(5)-O(19) bond length is 1.93 Å. The Zn(5)-O(2) bond length is 1.94 Å. The Zn(5)-O(23) bond length is 1.93 Å. In the sixth Zn site, Zn(6) is bonded to one O(16), one O(2), one O(21), and one O(26) atom to form corner-sharing ZnO4 tetrahedra. The Zn(6)-O(16) bond length is 1.93 Å. The Zn(6)-O(2) bond length is 1.94 Å. The Zn(6)-O(21) bond length is 1.93 Å. The Zn(6)-O(26) bond length is 1.93 Å. In the seventh Zn site, Zn(7) is bonded to one O(17), one O(2), one O(22), and one O(24) atom to form corner-sharing ZnO4 tetrahedra. The Zn(7)-O(17) bond length is 1.93 Å. The Zn(7)-O(2) bond length is 1.94 Å. The Zn(7)-O(22) bond length is 1.93 Å. The Zn(7)-O(24) bond length is 1.93 Å. In the eighth Zn site, Zn(8) is bonded to one O(18), one O(2), one O(20), and one O(25) atom to form corner-sharing ZnO4 tetrahedra. The Zn(8)-O(18) bond length is 1.93 Å. The Zn(8)-O(2) bond length is 1.94 Å. The Zn(8)-O(20) bond length is 1.93 Å. The Zn(8)-O(25) bond length is 1.93 Å. There are seventy-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(3), and one O(6) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(3) bond length is 1.25 Å. The C(1)-O(6) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(25), and one C(31) atom. The C(2)-C(25) bond length is 1.36 Å. The C(2)-C(31) bond length is 1.36 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(4), and one O(5) atom. The C(3)-C(4) bond length is 1.49 Å. The C(3)-O(4) bond length is 1.25 Å. The C(3)-O(5) bond length is 1.25 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(3) atom. The C(4)-C(27) bond length is 1.36 Å. The C(4)-C(29) bond length is 1.36 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(10), and one O(7) atom. The C(5)-C(6) bond length is 1.49 Å. The C(5)-O(10) bond length is 1.25 Å. The C(5)-O(7) bond length is 1.25 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(33), one C(39), and one C(5) atom. The C(6)-C(33) bond length is 1.36 Å. The C(6)-C(39) bond length is 1.36 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(8), and one O(9) atom. The C(7)-C(8) bond length is 1.49 Å. The C(7)-O(8) bond length is 1.25 Å. The C(7)-O(9) bond length is 1.25 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(7) atom. The C(8)-C(35) bond length is 1.36 Å. The C(8)-C(37) bond length is 1.36 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(11), and one O(14) atom. The C(9)-C(10) bond length is 1.49 Å. The C(9)-O(11) bond length is 1.25 Å. The C(9)-O(14) bond length is 1.25 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(41), one C(47), and one C(9) atom. The C(10)-C(41) bond length is 1.36 Å. The C(10)-C(47) bond length is 1.36 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(12), and one O(13) atom. The C(11)-C(12) bond length is 1.49 Å. The C(11)-O(12) bond length is 1.25 Å. The C(11)-O(13) bond length is 1.25 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(43), and one C(45) atom. The C(12)-C(43) bond length is 1.36 Å. The C(12)-C(45) bond length is 1.36 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(15), and one O(18) atom. The C(13)-C(14) bond length is 1.49 Å. The C(13)-O(15) bond length is 1.25 Å. The C(13)-O(18) bond length is 1.25 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(49), and one C(55) atom. The C(14)-C(49) bond length is 1.36 Å. The C(14)-C(55) bond length is 1.36 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(16), and one O(17) atom. The C(15)-C(16) bond length is 1.49 Å. The C(15)-O(16) bond length is 1.25 Å. The C(15)-O(17) bond length is 1.25 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(51), and one C(53) atom. The C(16)-C(51) bond length is 1.36 Å. The C(16)-C(53) bond length is 1.36 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(19), and one O(22) atom. The C(17)-C(18) bond length is 1.49 Å. The C(17)-O(19) bond length is 1.25 Å. The C(17)-O(22) bond length is 1.25 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(57), and one C(63) atom. The C(18)-C(57) bond length is 1.36 Å. The C(18)-C(63) bond length is 1.36 Å. In the nineteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(20), and one O(21) atom. The C(19)-C(20) bond length is 1.49 Å. The C(19)-O(20) bond length is 1.25 Å. The C(19)-O(21) bond length is 1.25 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(59), and one C(61) atom. The C(20)-C(59) bond length is 1.36 Å. The C(20)-C(61) bond length is 1.36 Å. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(23), and one O(26) atom. The C(21)-C(22) bond length is 1.49 Å. The C(21)-O(23) bond length is 1.25 Å. The C(21)-O(26) bond length is 1.25 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(65), and one C(71) atom. The C(22)-C(65) bond length is 1.36 Å. The C(22)-C(71) bond length is 1.36 Å. In the twenty-third C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(24), and one O(25) atom. The C(23)-C(24) bond length is 1.49 Å. The C(23)-O(24) bond length is 1.25 Å. The C(23)-O(25) bond length is 1.25 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(67), and one C(69) atom. The C(24)-C(67) bond length is 1.36 Å. The C(24)-C(69) bond length is 1.36 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(2), one C(26), and one C(61) atom. The C(25)-C(26) bond length is 1.55 Å. The C(25)-C(61) bond length is 1.38 Å. In the twenty-sixth C site, C(26) is bonded in a trigonal non-coplanar geometry to one C(25) and three equivalent H(1,2,3,22,23,24,55,56,57) atoms. All C(26)-H(1,2,3,22,23,24,55,56,57) bond lengths are 1.14 Å. In the twenty-seventh C site, C(27) is bonded in a trigonal planar geometry to one C(28,38); one C(4); and one C(57) atom. The C(27)-C(28,38) bond length is 1.55 Å. The C(27)-C(57) bond length is 1.38 Å. In the twenty-eighth C site, C(28,38) is bonded in a trigonal non-coplanar geometry to one C(27) and three equivalent H(4,5,6) atoms. All C(28,38)-H(4,5,6) bond lengths are 1.14 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(30), one C(4), and one C(63) atom. The C(29)-C(30) bond length is 1.55 Å. The C(29)-C(63) bond length is 1.38 Å. In the thirtieth C site, C(30) is bonded in a trigonal non-coplanar geometry to one C(29) and three equivalent H(7,8,9) atoms. All C(30)-H(7,8,9) bond lengths are 1.14 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one C(2), one C(32), and one C(59) atom. The C(31)-C(32) bond length is 1.55 Å. The C(31)-C(59) bond length is 1.38 Å. In the thirty-second C site, C(32) is bonded in a trigonal non-coplanar geometry to one C(31); one H(11); and two equivalent H(10,12) atoms. The C(32)-H(11) bond length is 1.14 Å. Both C(32)-H(10,12) bond lengths are 1.14 Å. In the thirty-third C site, C(33) is bonded in a trigonal planar geometry to one C(34), one C(51), and one C(6) atom. The C(33)-C(34) bond length is 1.55 Å. The C(33)-C(51) bond length is 1.38 Å. In the thirty-fourth C site, C(34) is bonded in a trigonal non-coplanar geometry to one C(33); one H(13); and two equivalent H(14,15) atoms. The C(34)-H(13) bond length is 1.14 Å. Both C(34)-H(14,15) bond lengths are 1.14 Å. In the thirty-fifth C site, C(35) is bonded in a trigonal planar geometry to one C(36), one C(55), and one C(8) atom. The C(35)-C(36) bond length is 1.55 Å. The C(35)-C(55) bond length is 1.38 Å. In the thirty-sixth C site, C(36) is bonded in a trigonal non-coplanar geometry to one C(35) and three equivalent H(16,17,18) atoms. All C(36)-H(16,17,18) bond lengths are 1.14 Å. In the thirty-seventh C site, C(37) is bonded in a trigonal planar geometry to one C(28,38); one C(49); and one C(8) atom. The C(37)-C(28,38) bond length is 1.55 Å. The C(37)-C(49) bond length is 1.38 Å. In the thirty-eighth C site, C(39) is bonded in a trigonal planar geometry to one C(40), one C(53), and one C(6) atom. The C(39)-C(40) bond length is 1.55 Å. The C(39)-C(53) bond length is 1.38 Å. In the thirty-ninth C site, C(40) is bonded in a trigonal non-coplanar geometry to one C(39) and three equivalent H(1,2,3,22,23,24,55,56,57) atoms. All C(40)-H(1,2,3,22,23,24,55,56,57) bond lengths are 1.14 Å. In the fortieth C site, C(41) is bonded in a trigonal planar geometry to one C(10), one C(42), and one C(71) atom. The C(41)-C(42) bond length is 1.55 Å. The C(41)-C(71) bond length is 1.38 Å. In the forty-first C site, C(42) is bonded in a trigonal non-coplanar geometry to one C(41) and three equivalent H(25,26,27) atoms. All C(42)-H(25,26,27) bond lengths are 1.14 Å. In the forty-second C site, C(43) is bonded in a trigonal planar geometry to one C(12), one C(44), and one C(67) atom. The C(43)-C(44) bond length is 1.55 Å. The C(43)-C(67) bond length is 1.38 Å. In the forty-third C site, C(44) is bonded in a trigonal non-coplanar geometry to one C(43); one H(30); and two equivalent H(28,29) atoms. The C(44)-H(30) bond length is 1.14 Å. Both C(44)-H(28,29) bond lengths are 1.14 Å. In the forty-fourth C site, C(45) is bonded in a trigonal planar geometry to one C(12), one C(46), and one C(69) atom. The C(45)-C(46) bond length is 1.55 Å. The C(45)-C(69) bond length is 1.38 Å. In the forty-fifth C site, C(46) is bonded in a trigonal non-coplanar geometry to one C(45) and three equivalent H(31,32,33) atoms. All C(46)-H(31,32,33) bond lengths are 1.14 Å. In the forty-sixth C site, C(47) is bonded in a trigonal planar geometry to one C(10), one C(48), and one C(65) atom. The C(47)-C(48) bond length is 1.55 Å. The C(47)-C(65) bond length is 1.38 Å. In the forty-seventh C site, C(48) is bonded in a trigonal non-coplanar geometry to one C(47) and three equivalent H(34,35,36) atoms. All C(48)-H(34,35,36) bond lengths are 1.14 Å. In the forty-eighth C site, C(49) is bonded in a trigonal planar geometry to one C(14), one C(37), and one C(50) atom. The C(49)-C(50) bond length is 1.55 Å. In the forty-ninth C site, C(50) is bonded in a trigonal non-coplanar geometry to one C(49) and three equivalent H(19,20,21,37,38,39,49,50,51) atoms. All C(50)-H(19,20,21,37,38,39,49,50,51) bond lengths are 1.14 Å. In the fiftieth C site, C(51) is bonded in a trigonal planar geometry to one C(16), one C(33), and one C(52) atom. The C(51)-C(52) bond length is 1.55 Å. In the fifty-first C site, C(52) is bonded in a trigonal non-coplanar geometry to one C(51), one H(40), one H(41), and one H(42) atom. The C(52)-H(40) bond length is 1.14 Å. The C(52)-H(41) bond length is 1.14 Å. The C(52)-H(42) bond length is 1.14 Å. In the fifty-second C site, C(53) is bonded in a trigonal planar geometry to one C(16), one C(39), and one C(54) atom. The C(53)-C(54) bond length is 1.55 Å. In the fifty-third C site, C(54) is bonded in a trigonal non-coplanar geometry to one C(53) and three equivalent H(43,44,45) atoms. All C(54)-H(43,44,45) bond lengths are 1.14 Å. In the fifty-fourth C site, C(55) is bonded in a trigonal planar geometry to one C(14), one C(35), and one C(56) atom. The C(55)-C(56) bond length is 1.55 Å. In the fifty-fifth C site, C(56) is bonded in a trigonal non-coplanar geometry to one C(55) and three equivalent H(46,47,48) atoms. All C(56)-H(46,47,48) bond lengths are 1.14 Å. In the fifty-sixth C site, C(57) is bonded in a trigonal planar geometry to one C(18), one C(27), and one C(58) atom. The C(57)-C(58) bond length is 1.55 Å. In the fifty-seventh C site, C(58) is bonded in a trigonal non-coplanar geometry to one C(57) and three equivalent H(19,20,21,37,38,39,49,50,51) atoms. All C(58)-H(19,20,21,37,38,39,49,50,51) bond lengths are 1.14 Å. In the fifty-eighth C site, C(59) is bonded in a trigonal planar geometry to one C(20), one C(31), and one C(60) atom. The C(59)-C(60) bond length is 1.55 Å. In the fifty-ninth C site, C(60) is bonded in a trigonal non-coplanar geometry to one C(59); one H(52); and two equivalent H(53,54) atoms. The C(60)-H(52) bond length is 1.14 Å. Both C(60)-H(53,54) bond lengths are 1.14 Å. In the sixtieth C site, C(61) is bonded in a trigonal planar geometry to one C(20), one C(25), and one C(62) atom. The C(61)-C(62) bond length is 1.55 Å. In the sixty-first C site, C(62) is bonded in a trigonal non-coplanar geometry to one C(61) and three equivalent H(1,2,3,22,23,24,55,56,57) atoms. All C(62)-H(1,2,3,22,23,24,55,56,57) bond lengths are 1.14 Å. In the sixty-second C site, C(63) is bonded in a trigonal planar geometry to one C(18), one C(29), and one C(64) atom. The C(63)-C(64) bond length is 1.55 Å. In the sixty-third C site, C(64) is bonded in a trigonal non-coplanar geometry to one C(63) and three equivalent H(58,59,60) atoms. All C(64)-H(58,59,60) bond lengths are 1.14 Å. In the sixty-fourth C site, C(65) is bonded in a trigonal planar geometry to one C(22), one C(47), and one C(66) atom. The C(65)-C(66) bond length is 1.55 Å. In the sixty-fifth C site, C(66) is bonded in a trigonal non-coplanar geometry to one C(65) and three equivalent H(61,62,63) atoms. All C(66)-H(61,62,63) bond lengths are 1.14 Å. In the sixty-sixth C site, C(67) is bonded in a trigonal planar geometry to one C(24), one C(43), and one C(68) atom. The C(67)-C(68) bond length is 1.55 Å. In the sixty-seventh C site, C(68) is bonded in a trigonal non-coplanar geometry to one C(67); one H(65); and two equivalent H(64,66) atoms. The C(68)-H(65) bond length is 1.14 Å. Both C(68)-H(64,66) bond lengths are 1.14 Å. In the sixty-eighth C site, C(69) is bonded in a trigonal planar geometry to one C(24), one C(45), and one C(70) atom. The C(69)-C(70) bond length is 1.55 Å. In the sixty-ninth C site, C(70) is bonded in a trigonal non-coplanar geometry to one C(69) and three equivalent H(67,68,69) atoms. All C(70)-H(67,68,69) bond lengths are 1.14 Å. In the seventieth C site, C(71) is bonded in a trigonal planar geometry to one C(22), one C(41), and one C(72) atom. The C(71)-C(72) bond length is 1.55 Å. In the seventy-first C site, C(72) is bonded in a trigonal non-coplanar geometry to one C(71) and three equivalent H(70,71,72) atoms. All C(72)-H(70,71,72) bond lengths are 1.14 Å. There are twenty-seven inequivalent H sites. In the first H site, H(1,2,3,22,23,24,55,56,57) is bonded in a single-bond geometry to one C(26) atom. In the second H site, H(4,5,6) is bonded in a single-bond geometry to one C(28,38) atom. In the third H site, H(7,8,9) is bonded in a single-bond geometry to one C(30) atom. In the fourth H site, H(10,12) is bonded in a single-bond geometry to one C(32) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(32) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(34) atom. In the seventh H site, H(14,15) is bonded in a single-bond geometry to one C(34) atom. In the eighth H site, H(16,17,18) is bonded in a single-bond geometry to one C(36) atom. In the ninth H site, H(19,20,21,37,38,39,49,50,51) is bonded in a single-bond geometry to one C(28,38) atom. The H(19,20,21,37,38,39,49,50,51)-C(28,38) bond length is 1.14 Å. In the tenth H site, H(25,26,27) is bonded in a single-bond geometry to one C(42) atom. In the eleventh H site, H(28,29) is bonded in a single-bond geometry to one C(44) atom. In the twelfth H site, H(30) is bonded in a single-bond geometry to one C(44) atom. In the thirteenth H site, H(31,32,33) is bonded in a single-bond geometry to one C(46) atom. In the fourteenth H site, H(34,35,36) is bonded in a single-bond geometry to one C(48) atom. In the fifteenth H site, H(40) is bonded in a single-bond geometry to one C(52) atom. In the sixteenth H site, H(41) is bonded in a single-bond geometry to one C(52) atom. In the seventeenth H site, H(42) is bonded in a single-bond geometry to one C(52) atom. In the eighteenth H site, H(43,44,45) is bonded in a single-bond geometry to one C(54) atom. In the nineteenth H site, H(46,47,48) is bonded in a single-bond geometry to one C(56) atom. In the twentieth H site, H(52) is bonded in a single-bond geometry to one C(60) atom. In the twenty-first H site, H(53,54) is bonded in a single-bond geometry to one C(60) atom. In the twenty-second H site, H(58,59,60) is bonded in a single-bond geometry to one C(64) atom. In the twenty-third H site, H(61,62,63) is bonded in a single-bond geometry to one C(66) atom. In the twenty-fourth H site, H(64,66) is bonded in a single-bond geometry to one C(68) atom. In the twenty-fifth H site, H(65) is bonded in a single-bond geometry to one C(68) atom. In the twenty-sixth H site, H(67,68,69) is bonded in a single-bond geometry to one C(70) atom. In the twenty-seventh H site, H(70,71,72) is bonded in a single-bond geometry to one C(72) atom. There are twenty-six inequivalent O sites. In the first O site, O(1) is bonded in a tetrahedral geometry to one Zn(1), one Zn(2), one Zn(3), and one Zn(4) atom. In the second O site, O(2) is bonded in a tetrahedral geometry to one Zn(5), one Zn(6), one Zn(7), and one Zn(8) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(3) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(3) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(1) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(7) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(7) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(5) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(11) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(11) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(9) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Zn(5) and one C(13) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Zn(6) and one C(15) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Zn(7) and one C(15) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Zn(8) and one C(13) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Zn(5) and one C(17) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Zn(8) and one C(19) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 120 degrees geometry to one Zn(6) and one C(19) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Zn(7) and one C(17) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 120 degrees geometry to one Zn(5) and one C(21) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 120 degrees geometry to one Zn(7) and one C(23) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 120 degrees geometry to one Zn(8) and one C(23) atom. In the twenty-sixth O site, O(26) is bonded in a distorted bent 120 degrees geometry to one Zn(6) and one C(21) atom. Linkers: 6 Cc1c(C)c(C([O])=O)c(C)c(C)c1C([O])=O. Metal clusters: 2 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: pcu. The MOF has largest included sphere 14.25 A, density 0.74 g/cm3, surface area 4558.22 m2/g, accessible volume 0.94 cm3/g