CdC13H9(N3O)2(CH)5C4H3O is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four (e)-1,4-dimethoxy-2,3-dimethylbut-2-ene molecules; forty 02329_fluka molecules; and eight CdC13H9(N3O)2 clusters. In four of the CdC13H9(N3O)2 clusters, Cd(1) is bonded in a trigonal bipyramidal geometry to one N(10), one N(12), one N(7), one O(1), and one O(5) atom. The Cd(1)-N(10) bond length is 2.35 Å. The Cd(1)-N(12) bond length is 2.38 Å. The Cd(1)-N(7) bond length is 2.32 Å. The Cd(1)-O(1) bond length is 2.39 Å. The Cd(1)-O(5) bond length is 2.54 Å. There are thirteen inequivalent C sites. In the first C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(5) atom. The C(14)-O(1) bond length is 1.23 Å. The C(14)-O(5) bond length is 1.26 Å. In the second C site, C(15) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(11) atom. The C(15)-N(7) bond length is 1.31 Å. The C(15)-N(8) bond length is 1.35 Å. The C(15)-H(11) bond length is 0.93 Å. In the third C site, C(17) is bonded in a 3-coordinate geometry to one C(16), one N(8), and one H(13) atom. The C(17)-C(16) bond length is 1.34 Å. The C(17)-N(8) bond length is 1.37 Å. The C(17)-H(13) bond length is 0.93 Å. In the fourth C site, C(18) is bonded in a distorted single-bond geometry to one N(8) atom. The C(18)-N(8) bond length is 1.42 Å. In the fifth C site, C(16) is bonded in a 2-coordinate geometry to one C(17), one N(7), and one H(12) atom. The C(16)-N(7) bond length is 1.36 Å. The C(16)-H(12) bond length is 0.93 Å. In the sixth C site, C(20) is bonded in a distorted single-bond geometry to one N(11) atom. The C(20)-N(11) bond length is 1.44 Å. In the seventh C site, C(22) is bonded in a distorted single-bond geometry to one N(9) atom. The C(22)-N(9) bond length is 1.42 Å. In the eighth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(25), one N(9), and one H(17) atom. The C(24)-C(25) bond length is 1.33 Å. The C(24)-N(9) bond length is 1.36 Å. The C(24)-H(17) bond length is 0.93 Å. In the ninth C site, C(25) is bonded in a 3-coordinate geometry to one C(24), one N(10), and one H(18) atom. The C(25)-N(10) bond length is 1.35 Å. The C(25)-H(18) bond length is 0.93 Å. In the tenth C site, C(26) is bonded in a trigonal planar geometry to one N(10), one N(9), and one H(19) atom. The C(26)-N(10) bond length is 1.30 Å. The C(26)-N(9) bond length is 1.35 Å. The C(26)-H(19) bond length is 0.93 Å. In the eleventh C site, C(27) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(20) atom. The C(27)-N(11) bond length is 1.36 Å. The C(27)-N(12) bond length is 1.31 Å. The C(27)-H(20) bond length is 0.93 Å. In the twelfth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(29), one N(12), and one H(21) atom. The C(28)-C(29) bond length is 1.33 Å. The C(28)-N(12) bond length is 1.36 Å. The C(28)-H(21) bond length is 0.93 Å. In the thirteenth C site, C(29) is bonded in a 3-coordinate geometry to one C(28), one N(11), and one H(22) atom. The C(29)-N(11) bond length is 1.36 Å. The C(29)-H(22) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(7) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(15), and one C(16) atom. In the second N site, N(8) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. In the third N site, N(9) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(26) atom. In the fourth N site, N(10) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(25), and one C(26) atom. In the fifth N site, N(11) is bonded in a trigonal planar geometry to one C(20), one C(27), and one C(29) atom. In the sixth N site, N(12) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(27), and one C(28) atom. There are nine inequivalent H sites. In the first H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(24) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one C(25) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(26) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(27) atom. In the eighth H site, H(21) is bonded in a single-bond geometry to one C(28) atom. In the ninth H site, H(22) is bonded in a single-bond geometry to one C(29) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(14) atom. In the second O site, O(5) is bonded in a distorted single-bond geometry to one Cd(1) and one C(14) atom. In four of the CdC13H9(N3O)2 clusters, Cd(2) is bonded in a trigonal bipyramidal geometry to one N(1), one N(4), one N(6), one O(4), and one O(6) atom. The Cd(2)-N(1) bond length is 2.33 Å. The Cd(2)-N(4) bond length is 2.34 Å. The Cd(2)-N(6) bond length is 2.34 Å. The Cd(2)-O(4) bond length is 2.34 Å. The Cd(2)-O(6) bond length is 2.50 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. The C(1)-O(4) bond length is 1.25 Å. The C(1)-O(6) bond length is 1.26 Å. In the second C site, C(30) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(23) atom. The C(30)-N(1) bond length is 1.29 Å. The C(30)-N(2) bond length is 1.35 Å. The C(30)-H(23) bond length is 0.93 Å. In the third C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(32), one N(1), and one H(24) atom. The C(31)-C(32) bond length is 1.35 Å. The C(31)-N(1) bond length is 1.36 Å. The C(31)-H(24) bond length is 0.93 Å. In the fourth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(31), one N(2), and one H(25) atom. The C(32)-N(2) bond length is 1.37 Å. The C(32)-H(25) bond length is 0.93 Å. In the fifth C site, C(33) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(26) atom. The C(33)-N(5) bond length is 1.34 Å. The C(33)-N(6) bond length is 1.29 Å. The C(33)-H(26) bond length is 0.93 Å. In the sixth C site, C(34) is bonded in a 3-coordinate geometry to one C(35), one N(6), and one H(27) atom. The C(34)-C(35) bond length is 1.36 Å. The C(34)-N(6) bond length is 1.32 Å. The C(34)-H(27) bond length is 0.93 Å. In the seventh C site, C(35) is bonded in a 3-coordinate geometry to one C(34), one N(5), and one H(28) atom. The C(35)-N(5) bond length is 1.38 Å. The C(35)-H(28) bond length is 0.93 Å. In the eighth C site, C(37) is bonded in a distorted single-bond geometry to one N(2) atom. The C(37)-N(2) bond length is 1.43 Å. In the ninth C site, C(39) is bonded in a distorted single-bond geometry to one N(3) atom. The C(39)-N(3) bond length is 1.43 Å. In the tenth C site, C(41) is bonded in a distorted single-bond geometry to one N(5) atom. The C(41)-N(5) bond length is 1.43 Å. In the eleventh C site, C(42) is bonded in a 3-coordinate geometry to one C(44), one N(3), and one H(32) atom. The C(42)-C(44) bond length is 1.35 Å. The C(42)-N(3) bond length is 1.38 Å. The C(42)-H(32) bond length is 0.93 Å. In the twelfth C site, C(43) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(33) atom. The C(43)-N(3) bond length is 1.36 Å. The C(43)-N(4) bond length is 1.32 Å. The C(43)-H(33) bond length is 0.93 Å. In the thirteenth C site, C(44) is bonded in a 3-coordinate geometry to one C(42), one N(4), and one H(34) atom. The C(44)-N(4) bond length is 1.38 Å. The C(44)-H(34) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(30), and one C(31) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(37) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(39), one C(42), and one C(43) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(43), and one C(44) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(41) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(33), and one C(34) atom. There are nine inequivalent H sites. In the first H site, H(23) is bonded in a single-bond geometry to one C(30) atom. In the second H site, H(24) is bonded in a single-bond geometry to one C(31) atom. In the third H site, H(25) is bonded in a single-bond geometry to one C(32) atom. In the fourth H site, H(26) is bonded in a single-bond geometry to one C(33) atom. In the fifth H site, H(27) is bonded in a single-bond geometry to one C(34) atom. In the sixth H site, H(28) is bonded in a single-bond geometry to one C(35) atom. In the seventh H site, H(32) is bonded in a single-bond geometry to one C(42) atom. In the eighth H site, H(33) is bonded in a single-bond geometry to one C(43) atom. In the ninth H site, H(34) is bonded in a single-bond geometry to one C(44) atom. There are two inequivalent O sites. In the first O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(1) atom. In the second O site, O(6) is bonded in a distorted single-bond geometry to one Cd(2) and one C(1) atom. Linkers: 4 [CH]1[CH]N(c2cc(-n3ccnc3)cc(-n3ccnc3)c2)[CH][N]1 ,4 c1cn(-c2cc(-n3ccnc3)cc(-n3ccnc3)c2)cn1 ,4 [O]C(=O)COc1cccc2c(OCC([O])=O)cccc12. Metal clusters: 8 [C]1O[Cd]O1. The MOF has largest included sphere 4.79 A, density 1.33 g/cm3, surface area 4463.71 m2/g, accessible volume 0.32 cm3/g