(C)7Cu2C26N5O8 is Indium-derived structured and crystallizes in the cubic Fm-3m space group. The structure is zero-dimensional and consists of twenty-four C clusters and four Cu2C26N5O8 clusters. In each C cluster, there are three inequivalent C sites. In the first C site, C(7) is bonded in a 7-coordinate geometry to one C(7), two equivalent C(11), and four equivalent C(4) atoms. The C(7)-C(7) bond length is 1.57 Å. Both C(7)-C(11) bond lengths are 1.36 Å. All C(7)-C(4) bond lengths are 1.32 Å. In the second C site, C(4) is bonded in a 2-coordinate geometry to one C(11) and one C(7) atom. The C(4)-C(11) bond length is 1.12 Å. In the third C site, C(11) is bonded in a 3-coordinate geometry to one C(7) and two equivalent C(4) atoms. In each Cu2C26N5O8 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(1) atoms. All Cu(1)-O(1) bond lengths are 1.94 Å. In the second Cu site, Cu(2) is bonded in a distorted square pyramidal geometry to one N(1) and four equivalent O(2) atoms. The Cu(2)-N(1) bond length is 2.17 Å. All Cu(2)-O(2) bond lengths are 1.96 Å. There are eight inequivalent C sites. In the first C site, C(5) is bonded in a 3-coordinate geometry to one C(5), one C(6), and one N(1) atom. The C(5)-C(5) bond length is 0.86 Å. The C(5)-C(6) bond length is 0.92 Å. The C(5)-N(1) bond length is 1.34 Å. In the second C site, C(6) is bonded in a 3-coordinate geometry to one C(5), one C(6), and one N(1) atom. The C(6)-C(6) bond length is 0.79 Å. The C(6)-N(1) bond length is 1.34 Å. In the third C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.28 Å. In the fourth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(8) atom. The C(2)-C(3) bond length is 1.47 Å. The C(2)-C(8) bond length is 1.41 Å. In the fifth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(10), one C(2), and one C(9) atom. The C(3)-C(10) bond length is 1.43 Å. The C(3)-C(9) bond length is 1.48 Å. In the sixth C site, C(8) is bonded in a bent 120 degrees geometry to two equivalent C(2) atoms. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10), two equivalent C(3), and one N(2) atom. The C(9)-C(10) bond length is 1.06 Å. The C(9)-N(2) bond length is 1.43 Å. In the eighth C site, C(10) is bonded in a single-bond geometry to one C(9), two equivalent C(3), and one N(3) atom. The C(10)-N(3) bond length is 1.43 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a 9-coordinate geometry to one Cu(2), four equivalent C(5), and four equivalent C(6) atoms. In the second N site, N(2) is bonded in a single-bond geometry to one C(9) atom. In the third N site, N(3) is bonded in a distorted single-bond geometry to one C(10) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(1) atom. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Cu(1) and one C(1) atom. Linkers: 1 [C]1[C]2[C]3[C@]45[N][C@]67[C][C]4[C]4[C@@]68[C@@]6([C]2[C@@]32[C@@]45[C@]628)[C]17.[N][C@@]12[C]3[C][C]4[C]5[C]6[C][C]1[C@]17[C]6[C@@]56[C@@]45[C]3[C@]21[C@@]567 ,2 [N][C@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@@]17[C]6[C@]56[C@]45[C]3[C@]12[C@]657.[N][C@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@@]17[C]6[C@]56[C@]45[C]3[C@]12[C@]657 ,1 [N][C@@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@]17[C]6[C@@]56[C@@]45[C]3[C@@]12[C@]567.[N][C@]12[C][C]3[C]4[C]5[C][C]6[C]7[C@@]58[C@@]45[C]3[C@@]13[C@@]7([C]62)[C@]583 ,1 [N][C@@]12[C]3[C][C]4[C]5[C][C]6[C]1[C@]17[C]6[C@@]56[C@@]45[C]3[C@]21[C@@]567.[N][C@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@@]17[C]6[C@]56[C@]45[C]3[C@]12[C@@]657 ,1 [N][C@@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@]17[C]6[C@@]56[C@@]45[C]3[C@@]12[C@@]567.[N][C@@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@]17[C]6[C@@]56[C@@]45[C]3[C@@]12[C@@]567 ,1 [N][C@@]12[C]3[C][C]4[C]5[C][C]6[C]1[C@]17[C]6[C@@]56[C@@]45[C]3[C@]21[C@]567.[N][C@]12[C]3[C][C]4[C]5[C]6[C][C]1[C@@]17[C]6[C@]56[C@]45[C]3[C@@]21[C@]657 ,1 [N][C@@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@]17[C]6[C@@]56[C@@]45[C]3[C@@]12[C@]567.[N][C@]12[C]3[C][C]4[C]5[C][C]6[C]1[C@@]17[C]6[C@]56[C@]45[C]3[C@@]21[C@]657 ,1 [N][C@@]12[C][C]3[C]4[C]5[C][C]6[C]7[C@]58[C@]45[C]3[C@]13[C@]7([C]62)[C@@]853.[N][C@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@@]17[C]6[C@]56[C@]45[C]3[C@]12[C@@]657 ,1 [C]1[C]2[C]3[C@]45[N][C@]67[C][C]4[C]4[C@@]68[C@@]6([C]2[C@@]32[C@@]45[C@]628)[C]17.[N][C@@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@]17[C]6[C@@]56[C@@]45[C]3[C@@]12[C@]567 ,1 [C]1[C]2[C]3[C@@]45[N][C@]67[C][C]4[C]4[C@@]58[C@@]35[C]2[C@]2([C]16)[C@@]47[C@]528.[N][C@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@@]17[C]6[C@]56[C@]45[C]3[C@]12[C@@]657 ,1 [C]1[C]2[C]3[C@@]45[C]1[C@@]16[N][C@]78[C][C]1[C]1[C@]64[C@]54[C@@]3([C]27)[C@]148.[C]1[C]2[C]3[C@@]45[N][C@]67[C][C]4[C]4[C@@]58[C@@]35[C]2[C@]2([C]16)[C@@]47[C@@]528 ,1 [C]1[C]2[C]3[C@@]45[C]1[C@@]16[N][C@]78[C][C]1[C]1[C@]64[C@]54[C@@]3([C]27)[C@]148.[C]1[C]2[C]3[C@@]45[C]1[C@@]16[N][C@]78[C][C]1[C]1[C@]64[C@]54[C@@]3([C]27)[C@]148 ,39 [O]C(=O)[C]1[C][C@@]2([C][N][N]2)[C]C(C([O])=O)=[C]1 ,1 [C]1[C]2[C]3[C@]45[N][C@]67[C][C]4[C]4[C@@]68[C@@]6([C]2[C@@]32[C@@]45[C@@]628)[C]17.[N][C@@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@]17[C]6[C@@]56[C@@]45[C]3[C@@]12[C@@]567 ,57 [O]C(=O)[C]1[C][C@]2([C][N][N]2)[C]C(C([O])=O)=[C]1 ,1 [C]1[C]2[C]3[C@@]45[N][C@]67[C][C]4[C]4[C@@]58[C@@]35[C]2[C@]2([C]16)[C@@]47[C@@]528.[C]1[C]2[C]3[C@]45[N][C@]67[C][C]4[C]4[C@@]68[C@@]6([C]2[C@@]32[C@@]45[C@]628)[C]17 ,1 [C]1[C]2[C]3[C@@]45[N][C@]67[C][C]4[C]4[C@@]58[C@@]35[C]2[C@]2([C]16)[C@@]47[C@]528.[N][C@@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@]17[C]6[C@@]56[C@@]45[C]3[C@@]12[C@@]567 ,1 [N][C@@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@]17[C]6[C@@]56[C@@]45[C]3[C@@]12[C@@]567.[N][C@@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@]17[C]6[C@@]56[C@@]45[C]3[C@@]12[C@]567 ,1 [C]1[C]2[C]3[C@@]45[N][C@]67[C][C]4[C]4[C@@]58[C@@]35[C]2[C@]2([C]16)[C@@]47[C@@]528.[N][C@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@@]17[C]6[C@]56[C@]45[C]3[C@]12[C@@]657 ,1 [C]1[C]2[C]3[C@]45[N][C@]67[C][C]4[C]4[C@@]68[C@@]6([C]2[C@@]32[C@@]45[C@]628)[C]17.[N][C@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@@]17[C]6[C@]56[C@]45[C]3[C@]12[C@]657 ,1 [C]1[C]2[C]3[C@@]45[N][C@]67[C][C]4[C]4[C@@]58[C@@]35[C]2[C@]2([C]16)[C@@]47[C@]528.[C]1[C]2[C]3[C@]45[N][C@]67[C][C]4[C]4[C@@]68[C@@]6([C]2[C@@]32[C@@]45[C@]628)[C]17 ,1 [C]1[C]2[C]3[C@@]45[N][C@]67[C][C]4[C]4[C@@]58[C@@]35[C]2[C@]2([C]16)[C@@]47[C@@]528.[N][C@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@@]17[C]6[C@]56[C@]45[C]3[C@]12[C@]657 ,1 [C]1[C]2[C]3[C@]45[N][C@]67[C][C]4[C]4[C@@]68[C@@]6([C]2[C@@]32[C@@]45[C@]628)[C]17.[N][C@@]12[C][C]3[C]4[C]5[C]6[C][C]1[C@]17[C]6[C@@]56[C@@]45[C]3[C@@]12[C@@]567 ,1 [N][C@@]12[C]3[C][C]4[C]5[C][C]6[C]1[C@]17[C]6[C@@]56[C@@]45[C]3[C@]21[C@]567.[N][C@]12[C]3[C][C]4[C]5[C][C]6[C]1[C@@]17[C]6[C@]56[C@]45[C]3[C@@]21[C@]657 ,1 [C]1[C]2[C]3[C@@]45[C]2[C@@]26[C][C]7[C]8[C@@]42[C@]52[C@]34[C]1[C@@]7([N]6)[C@]842.[C]1[C]2[C]3[C@]45[N][C@]67[C][C]4[C]4[C@@]68[C@@]6([C]2[C@@]32[C@@]45[C@]628)[C]17. Metal clusters: 48 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 22.60 A, density 0.59 g/cm3, surface area 3403.46 m2/g, accessible volume 1.40 cm3/g