ZnC7NH4O4(CH)6CH2CO is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight dimethyl ether molecules, eight isobutylene molecules, and four ZnC7NH4O4 clusters. In each ZnC7NH4O4 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(4), and one O(5) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 2.01 Å. The Zn(1)-O(2) bond length is 2.02 Å. The Zn(1)-O(4) bond length is 2.07 Å. The Zn(1)-O(5) bond length is 2.08 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(9)-O(4) bond length is 1.26 Å. The C(9)-O(5) bond length is 1.24 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.40 Å. In the fourth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the sixth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(10) atom. The C(14)-N(1) bond length is 1.33 Å. The C(14)-H(10) bond length is 0.93 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(7) atom. The C(10)-N(1) bond length is 1.33 Å. The C(10)-H(7) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(14) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the fourth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(9) atom. Linkers: 3 c1cc(CCc2ccncc2)ccn1 ,4 [O]C(=O)COc1ccc(C([O])=O)cc1. Metal clusters: 2 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: sql. The MOF has largest included sphere 4.37 A, density 1.46 g/cm3, surface area 4556.94 m2/g, accessible volume 0.22 cm3/g