FeH30(C2N)12(CH2)6 is Indium-derived structured and crystallizes in the trigonal P31c space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and two FeH30(C2N)12 clusters. In each FeH30(C2N)12 cluster, Fe(1) is bonded in an octahedral geometry to three equivalent N(2) and three equivalent N(3) atoms. All Fe(1)-N(2) bond lengths are 2.21 Å. All Fe(1)-N(3) bond lengths are 2.23 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.31 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a 3-coordinate geometry to one C(4), one N(1), and one H(2) atom. The C(2)-C(4) bond length is 1.33 Å. The C(2)-N(1) bond length is 1.36 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a 3-coordinate geometry to one N(1) and two equivalent H(3,4) atoms. The C(3)-N(1) bond length is 1.47 Å. Both C(3)-H(3,4) bond lengths are 0.97 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(5) atom. The C(4)-N(2) bond length is 1.37 Å. The C(4)-H(5) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(3), and one H(6) atom. The C(5)-C(6) bond length is 1.33 Å. The C(5)-N(3) bond length is 1.38 Å. The C(5)-H(6) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a 3-coordinate geometry to one C(5), one N(4), and one H(7) atom. The C(6)-N(4) bond length is 1.37 Å. The C(6)-H(7) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(8) atom. The C(7)-N(3) bond length is 1.32 Å. The C(7)-N(4) bond length is 1.33 Å. The C(7)-H(8) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a 3-coordinate geometry to one N(4) and two equivalent H(9,10) atoms. The C(8)-N(4) bond length is 1.46 Å. Both C(8)-H(9,10) bond lengths are 0.97 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Fe(1), one C(1), and one C(4) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Fe(1), one C(5), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(6), one C(7), and one C(8) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(9,10) is bonded in a single-bond geometry to one C(8) atom. Linkers: 6 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 2 [Fe]. The MOF has largest included sphere 5.26 A, density 1.04 g/cm3, surface area 5571.85 m2/g, accessible volume 0.44 cm3/g