(ZnC10NH6O4)2ZnC12H8(NO2)2(C3H2)16(CH)4(C7NH4)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; eight 2,3-dimethyl-1,3-butadiene molecules; two schembl5425382 molecules; one ZnC10NH6O4 cluster; and one ZnC12H8(NO2)2 cluster. In the ZnC10NH6O4 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(3), one O(2), one O(3), one O(4), and one O(5) atom. The Zn(1)-N(3) bond length is 2.03 Å. The Zn(1)-O(2) bond length is 2.04 Å. The Zn(1)-O(3) bond length is 2.06 Å. The Zn(1)-O(4) bond length is 2.03 Å. The Zn(1)-O(5) bond length is 2.04 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(9) and one H(1) atom. The C(1)-C(9) bond length is 1.40 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(6) is bonded in a distorted single-bond geometry to one C(18) and one H(5) atom. The C(6)-C(18) bond length is 1.40 Å. The C(6)-H(5) bond length is 0.93 Å. In the third C site, C(9) is bonded in a trigonal planar geometry to one C(1), one C(16), and one C(22) atom. The C(9)-C(16) bond length is 1.38 Å. The C(9)-C(22) bond length is 1.50 Å. In the fourth C site, C(11) is bonded in a distorted single-bond geometry to one C(18) and one H(9) atom. The C(11)-C(18) bond length is 1.39 Å. The C(11)-H(9) bond length is 0.93 Å. In the fifth C site, C(16) is bonded in a single-bond geometry to one C(9) and one H(13) atom. The C(16)-H(13) bond length is 0.93 Å. In the sixth C site, C(18) is bonded in a trigonal planar geometry to one C(11), one C(45), and one C(6) atom. The C(18)-C(45) bond length is 1.49 Å. In the seventh C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(22)-O(3) bond length is 1.25 Å. The C(22)-O(4) bond length is 1.24 Å. In the eighth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(27) atom. The C(41)-N(3) bond length is 1.35 Å. The C(41)-H(27) bond length is 0.93 Å. In the ninth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(2), and one O(5) atom. The C(45)-O(2) bond length is 1.25 Å. The C(45)-O(5) bond length is 1.26 Å. In the tenth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(31) atom. The C(48)-N(3) bond length is 1.34 Å. The C(48)-H(31) bond length is 0.93 Å. N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(41), and one C(48) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(27) is bonded in a single-bond geometry to one C(41) atom. In the sixth H site, H(31) is bonded in a single-bond geometry to one C(48) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(45) atom. In the second O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(22) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(22) atom. In the fourth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(45) atom. In the ZnC12H8(NO2)2 cluster, Zn(2) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent O(6) atoms. Both Zn(2)-N(2) bond lengths are 2.17 Å. Both Zn(2)-O(6) bond lengths are 2.05 Å. There are six inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(40), one O(1), and one O(6) atom. The C(5)-C(40) bond length is 1.50 Å. The C(5)-O(1) bond length is 1.23 Å. The C(5)-O(6) bond length is 1.28 Å. In the second C site, C(40) is bonded in a trigonal planar geometry to one C(13), one C(46), and one C(5) atom. The C(40)-C(13) bond length is 1.39 Å. The C(40)-C(46) bond length is 1.39 Å. In the third C site, C(13) is bonded in a distorted single-bond geometry to one C(40) and one H(11) atom. The C(13)-H(11) bond length is 0.93 Å. In the fourth C site, C(46) is bonded in a distorted single-bond geometry to one C(40) and one H(29) atom. The C(46)-H(29) bond length is 0.93 Å. In the fifth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(32) atom. The C(49)-N(2) bond length is 1.31 Å. The C(49)-H(32) bond length is 0.93 Å. In the sixth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(19) atom. The C(25)-N(2) bond length is 1.33 Å. The C(25)-H(19) bond length is 0.93 Å. N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(25), and one C(49) atom. There are four inequivalent H sites. In the first H site, H(32) is bonded in a single-bond geometry to one C(49) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the fourth H site, H(29) is bonded in a single-bond geometry to one C(46) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(5) atom. In the second O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(5) atom. Linkers: 1 [O]C(=O)c1ccc(-c2ccc(N(c3ccc(-c4ccc(C([O])=O)cc4)cc3)c3ccc(-c4ccc(C(=O)O[Zn](OC(=O)c5ccc(-c6ccc(N(c7ccc(-c8ccc(C([O])=O)cc8)cc7)c7ccc(-c8ccc(C([O])=O)cc8)cc7)cc6)cc5)(N5[CH]C=C(c6ccncc6)C=C5)N5[CH]C=C(c6ccncc6)C=C5)cc4)cc3)cc2)cc1. Metal clusters: 1 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: sql. The MOF has largest included sphere 7.81 A, density 0.91 g/cm3, surface area 4899.63 m2/g, accessible volume 0.57 cm3/g