ZnC12H8(NO2)2(C4H3)2(C3H2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 2,3-dimethyl-1,3-butadiene molecules; eight isobutylene molecules; and four ZnC12H8(NO2)2 clusters. In each ZnC12H8(NO2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Zn(1)-N(1) bond lengths are 2.05 Å. Both Zn(1)-O(1) bond lengths are 1.96 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.23 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(6) bond length is 0.93 Å. In the sixth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(13)-N(1) bond length is 1.31 Å. The C(13)-H(9) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(13), and one C(9) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Linkers: 2 c1cc(-c2ccncc2)ccn1 ,2 [O]C(=O)c1ccc(/C=C/c2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.68 A, density 1.06 g/cm3, surface area 5036.10 m2/g, accessible volume 0.48 cm3/g