La2C39N2H24O13 crystallizes in the monoclinic C2/c space group. La(1) is bonded in a 8-coordinate geometry to one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and two equivalent O(1) atoms. The La(1)-O(2) bond length is 2.57 Å. The La(1)-O(3) bond length is 2.49 Å. The La(1)-O(4) bond length is 2.41 Å. The La(1)-O(5) bond length is 2.49 Å. The La(1)-O(6) bond length is 2.51 Å. The La(1)-O(7) bond length is 2.77 Å. There is one shorter (2.51 Å) and one longer (2.74 Å) La(1)-O(1) bond length. There are twenty inequivalent C sites. In the first C site, C(20) is bonded in a trigonal planar geometry to two equivalent N(1) and one O(7) atom. Both C(20)-N(1) bond lengths are 1.41 Å. The C(20)-O(7) bond length is 1.41 Å. In the second C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.25 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(15), and one C(6) atom. The C(2)-C(15) bond length is 1.41 Å. The C(2)-C(6) bond length is 1.34 Å. In the fourth C site, C(3) is bonded in a trigonal planar geometry to one C(16), one C(3), and one C(6) atom. The C(3)-C(16) bond length is 1.40 Å. The C(3)-C(3) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.41 Å. In the fifth C site, C(4) is bonded in a trigonal planar geometry to one C(17), one C(5), and one C(7) atom. The C(4)-C(17) bond length is 1.40 Å. The C(4)-C(5) bond length is 1.51 Å. The C(4)-C(7) bond length is 1.37 Å. In the sixth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(5)-O(3) bond length is 1.23 Å. The C(5)-O(4) bond length is 1.24 Å. In the seventh C site, C(6) is bonded in a distorted single-bond geometry to one C(2), one C(3), and one H(1) atom. The C(6)-H(1) bond length is 0.93 Å. In the eighth C site, C(7) is bonded in a distorted single-bond geometry to one C(14), one C(4), and one H(2) atom. The C(7)-C(14) bond length is 1.42 Å. The C(7)-H(2) bond length is 0.93 Å. In the ninth C site, C(8) is bonded in a distorted single-bond geometry to one C(14) and one H(3) atom. The C(8)-C(14) bond length is 1.42 Å. The C(8)-H(3) bond length is 0.93 Å. In the tenth C site, C(9) is bonded in a single-bond geometry to one C(13) and one H(4) atom. The C(9)-C(13) bond length is 1.42 Å. The C(9)-H(4) bond length is 0.93 Å. In the eleventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(5), and one O(6) atom. The C(10)-C(11) bond length is 1.50 Å. The C(10)-O(5) bond length is 1.24 Å. The C(10)-O(6) bond length is 1.26 Å. In the twelfth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(18) atom. The C(11)-C(12) bond length is 1.35 Å. The C(11)-C(18) bond length is 1.40 Å. In the thirteenth C site, C(12) is bonded in a single-bond geometry to one C(11), one C(13), and one H(5) atom. The C(12)-C(13) bond length is 1.43 Å. The C(12)-H(5) bond length is 0.93 Å. In the fourteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(9) atom. The C(13)-C(13) bond length is 1.43 Å. In the fifteenth C site, C(14) is bonded in a trigonal planar geometry to one C(14), one C(7), and one C(8) atom. The C(14)-C(14) bond length is 1.40 Å. In the sixteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(2) and one H(6) atom. The C(15)-H(6) bond length is 0.93 Å. In the seventeenth C site, C(16) is bonded in a distorted single-bond geometry to one C(3) and one H(7) atom. The C(16)-H(7) bond length is 0.93 Å. In the eighteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(4) and one H(8) atom. The C(17)-H(8) bond length is 0.93 Å. In the nineteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(11) and one H(9) atom. The C(18)-H(9) bond length is 0.93 Å. In the twentieth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(10), and one H(11) atom. The C(19)-N(1) bond length is 1.44 Å. The C(19)-H(10) bond length is 0.97 Å. The C(19)-H(11) bond length is 0.97 Å. N(1) is bonded in a trigonal planar geometry to one C(19), one C(20), and one H(12) atom. The N(1)-H(12) bond length is 0.86 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(1) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to two equivalent La(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one La(1) and one C(1) atom. In the third O site, O(3) is bonded in a 2-coordinate geometry to one La(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one La(1) and one C(5) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one La(1) and one C(10) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one La(1) and one C(10) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to two equivalent La(1) and one C(20) atom. Linkers: 6 [O]C(=O)c1ccc2cc(C([O])=O)ccc2c1. Metal clusters: 4 [La]. The MOF has largest included sphere 5.42 A, density 1.54 g/cm3, surface area 3525.53 m2/g, accessible volume 0.21 cm3/g