ZnC10H8(NO2)2(C4H3)2 is Indium-derived structured and crystallizes in the orthorhombic Pnna space group. The structure is zero-dimensional and consists of eight isobutylene molecules and four ZnC10H8(NO2)2 clusters. In each ZnC10H8(NO2)2 cluster, Zn(1) is bonded in a 6-coordinate geometry to two equivalent N(1), two equivalent O(1), and two equivalent O(2) atoms. Both Zn(1)-N(1) bond lengths are 2.06 Å. Both Zn(1)-O(1) bond lengths are 2.00 Å. Both Zn(1)-O(2) bond lengths are 2.48 Å. There are five inequivalent C sites. In the first C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(8)-N(1) bond length is 1.36 Å. The C(8)-H(6) bond length is 0.93 Å. In the second C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.21 Å. In the third C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.32 Å. The C(2)-H(1) bond length is 0.93 Å. In the fourth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 0.93 Å. In the fifth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(4)-N(1) bond length is 1.37 Å. The C(4)-H(3) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(4), and one C(8) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Zn(1) and one C(1) atom. Linkers: 5 C(=C/c1ccncc1)\c1ccncc1 ,4 [O]C(=O)/C=C/C=C/C([O])=O. Metal clusters: 4 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 5.95 A, density 0.99 g/cm3, surface area 5053.06 m2/g, accessible volume 0.58 cm3/g