Ag3C22H18(N3S2)2(CH)6 crystallizes in the monoclinic C2/c space group. The structure consists of twenty-four 02329_fluka molecules inside a Ag3C22H18(N3S2)2 framework. In the Ag3C22H18(N3S2)2 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one S(1), and one S(2) atom. The Ag(1)-N(1) bond length is 2.58 Å. The Ag(1)-N(2) bond length is 2.27 Å. The Ag(1)-S(1) bond length is 2.79 Å. The Ag(1)-S(2) bond length is 2.60 Å. In the second Ag site, Ag(2) is bonded in a distorted linear geometry to two equivalent N(3) and two equivalent S(1) atoms. Both Ag(2)-N(3) bond lengths are 2.21 Å. Both Ag(2)-S(1) bond lengths are 3.09 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one N(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-C(3) bond length is 1.51 Å. The C(1)-N(1) bond length is 1.33 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(9), and one N(1) atom. The C(2)-C(9) bond length is 1.52 Å. The C(2)-N(1) bond length is 1.33 Å. In the third C site, C(3) is bonded in a water-like geometry to one C(1); two equivalent H(1,2); and one S(1) atom. Both C(3)-H(1,2) bond lengths are 0.98 Å. The C(3)-S(1) bond length is 1.80 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one N(2), and one S(1) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-N(2) bond length is 1.34 Å. The C(4)-S(1) bond length is 1.77 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 0.94 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(7)-C(8) bond length is 1.35 Å. The C(7)-H(5) bond length is 0.94 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one N(2), and one H(6) atom. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(6) bond length is 0.94 Å. In the eighth C site, C(9) is bonded in a water-like geometry to one C(2); two equivalent H(7,8); and one S(2) atom. Both C(9)-H(7,8) bond lengths are 0.98 Å. The C(9)-S(2) bond length is 1.80 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(10)-N(3) bond length is 1.35 Å. The C(10)-H(9) bond length is 0.94 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(12) atom. The C(13)-C(14) bond length is 1.37 Å. The C(13)-H(12) bond length is 0.94 Å. In the eleventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one N(3), and one S(2) atom. The C(14)-N(3) bond length is 1.34 Å. The C(14)-S(2) bond length is 1.77 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(4), and one C(8) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(2), one C(10), and one C(14) atom. There are seven inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7,8) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(13) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a 4-coordinate geometry to one Ag(1), one Ag(2), one C(3), and one C(4) atom. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one Ag(1), one C(14), and one C(9) atom. Linkers: 1 [Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[CH2][S].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=C([N])S[CH]/[C]=N/[C][CH][S].[CH]C([N])=S.[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]#[C].[C]N([C])[Ag].[C]N([C])[Ag].[C]N=[C].[C]S[Ag@]([N])([S])N([C])/[C]=[C]\[N].[C][C].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N][C].[C][S].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N][Ag].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S] ,1 [Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[CH2].[CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C][N].[CH][C]=[CH].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]#[C].[C]#[C].[C]/N=[C]/C[S].[C]=[CH].[C]=[CH].[C]N([Ag])[C][S].[C]N([C])[Ag].[C]N([C])[Ag].[C]N=[CH].[C]N=[C].[C][C].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N][Ag].[C][S].[C][S].[C][S].[C][S].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S] ,1 [Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[CH].[CH]=[CH].[CH]C([N])=S.[CH]S[Ag].[CH]S[Ag][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]S[Ag][N][C]SC[C][N][Ag](N([C])[C]=[CH])[S]([C])[CH2].[C]S[C][N].[C][C]=[C].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N][Ag].[N][C]C[S].[N][C][CH][S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S] ,1 [Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[CH2][S].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[CH].[CH]=[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/N=[C]/[CH][S]([C][N])[Ag]/N=C/[CH].[C]N([CH])[Ag].[C]S[Ag][N][C]CS[Ag][S].[C][C]N1[Ag]S[CH]/C1=C(/[N])[CH][S].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[C][N].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S].[S]. Metal clusters: 4 [Ag]. The MOF has largest included sphere 3.93 A, density 1.72 g/cm3, surface area 3514.67 m2/g, accessible volume 0.23 cm3/g