Ni2C10N3H9O11(CH)4(CH2)2C3H2 is Indium-derived structured and crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules; eight 02329_fluka molecules; two 2,3-dimethyl-1,3-butadiene molecules; and two Ni2C10N3H9O11 clusters. In each Ni2C10N3H9O11 cluster, there are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded to one N(2), one O(6), two equivalent O(2), and two equivalent O(3) atoms to form corner-sharing NiNO5 octahedra. The Ni(1)-N(2) bond length is 2.07 Å. The Ni(1)-O(6) bond length is 2.08 Å. Both Ni(1)-O(2) bond lengths are 2.04 Å. Both Ni(1)-O(3) bond lengths are 2.08 Å. In the second Ni site, Ni(2) is bonded to two equivalent N(1), one O(6), and two equivalent O(1) atoms to form corner-sharing NiN2O3 square pyramids. The corner-sharing octahedral tilt angles are 64°. Both Ni(2)-N(1) bond lengths are 2.10 Å. The Ni(2)-O(6) bond length is 2.04 Å. Both Ni(2)-O(1) bond lengths are 2.01 Å. There are six inequivalent C sites. In the first C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(4)-O(1) bond length is 1.25 Å. The C(4)-O(2) bond length is 1.25 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(5)-O(3) bond length is 1.25 Å. The C(5)-O(4) bond length is 1.27 Å. In the third C site, C(6) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one H(7) atom. The C(6)-C(11) bond length is 1.36 Å. The C(6)-N(1) bond length is 1.35 Å. The C(6)-H(7) bond length is 0.95 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(7)-N(2) bond length is 1.32 Å. The C(7)-H(8) bond length is 0.95 Å. In the fifth C site, C(10) is bonded in a distorted bent 120 degrees geometry to two equivalent N(1) atoms. Both C(10)-N(1) bond lengths are 1.29 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to two equivalent C(6) and one H(10) atom. The C(11)-H(10) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(2), one C(10), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ni(1) and two equivalent C(7) atoms. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(6) atom. The H(1)-O(6) bond length is 0.85 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(4) atom. The H(2)-O(4) bond length is 0.85 Å. In the third H site, H(7) is bonded in a bent 120 degrees geometry to one C(6) and one O(5) atom. The H(7)-O(5) bond length is 1.14 Å. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Ni(2) and one C(4) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(4) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one C(5) and one H(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one H(7) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Ni(1), one Ni(2), and two equivalent H(1) atoms. Linkers: 2 [O].[O].[O].[O].c1cnc(-c2ncccn2)nc1 ,2 c1cc(-c2ccncc2)ccn1 ,4 [O]C(=O)[C@H]1C[C@@H](C(=O)O)[C@H](C([O])=O)C[C@@H]1C(=O)O. Metal clusters: 4 O.O[C]O[Ni]1(O[C]O)O[C]O[Ni]O[C]O1. RCSR code: sql. The MOF has largest included sphere 4.47 A, density 1.43 g/cm3, surface area 3813.99 m2/g, accessible volume 0.29 cm3/g