CuC8NH6O4(CH2)3 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules and four CuC8NH6O4 clusters. In each CuC8NH6O4 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-N(1) bond length is 2.16 Å. The Cu(1)-O(1) bond length is 1.96 Å. The Cu(1)-O(2) bond length is 1.95 Å. The Cu(1)-O(3) bond length is 1.96 Å. The Cu(1)-O(4) bond length is 1.96 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.24 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(5)-O(3) bond length is 1.25 Å. The C(5)-O(4) bond length is 1.24 Å. In the third C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(7) atom. The C(6)-N(1) bond length is 1.32 Å. The C(6)-H(7) bond length is 0.95 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(8) bond length is 0.95 Å. In the fifth C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(7), and one C(9) atom. The C(8)-C(11) bond length is 1.50 Å. The C(8)-C(9) bond length is 1.36 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(9) atom. The C(9)-C(10) bond length is 1.37 Å. The C(9)-H(9) bond length is 0.95 Å. In the seventh C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(10) atom. The C(10)-N(1) bond length is 1.33 Å. The C(10)-H(10) bond length is 0.95 Å. In the eighth C site, C(11) is bonded in a water-like geometry to one C(8) and two equivalent H(11,12) atoms. Both C(11)-H(11,12) bond lengths are 0.99 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(6) atom. There are five inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(11,12) is bonded in a single-bond geometry to one C(11) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(5) atom. Linkers: 4 c1cc(CCc2ccncc2)ccn1 ,4 [O]C(=O)CCCC([O])=O. Metal clusters: 2 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 4.97 A, density 1.48 g/cm3, surface area 4298.25 m2/g, accessible volume 0.23 cm3/g