CoC19H7(N3O2)2CoC21H9(N3O2)2Zn5H18(C17O9)2(CH)10 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty 02329_fluka molecules, two CoC19H7(N3O2)2 clusters, two CoC21H9(N3O2)2 clusters, and two Zn5H18(C17O9)2 clusters. In each CoC19H7(N3O2)2 cluster, Co(1) is bonded in an octahedral geometry to one N(1), one N(10), one N(2), one N(5), one N(6), and one N(7) atom. The Co(1)-N(1) bond length is 1.98 Å. The Co(1)-N(10) bond length is 1.97 Å. The Co(1)-N(2) bond length is 1.88 Å. The Co(1)-N(5) bond length is 1.92 Å. The Co(1)-N(6) bond length is 1.96 Å. The Co(1)-N(7) bond length is 1.85 Å. There are nineteen inequivalent C sites. In the first C site, C(27) is bonded in a distorted single-bond geometry to one C(1), one C(44), and one N(7) atom. The C(27)-C(1) bond length is 1.38 Å. The C(27)-C(44) bond length is 1.47 Å. The C(27)-N(7) bond length is 1.37 Å. In the second C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(26) atom. The C(30)-N(1) bond length is 1.33 Å. The C(30)-O(26) bond length is 1.26 Å. In the third C site, C(31) is bonded in a distorted trigonal planar geometry to one C(24), one C(66), and one N(5) atom. The C(31)-C(24) bond length is 1.39 Å. The C(31)-C(66) bond length is 1.42 Å. The C(31)-N(5) bond length is 1.44 Å. In the fourth C site, C(44) is bonded in a distorted bent 120 degrees geometry to one C(27), one N(5), and one O(25) atom. The C(44)-N(5) bond length is 1.32 Å. The C(44)-O(25) bond length is 1.28 Å. In the fifth C site, C(51) is bonded in a distorted single-bond geometry to one C(69) and one H(2,12) atom. The C(51)-C(69) bond length is 1.38 Å. The C(51)-H(2,12) bond length is 0.95 Å. In the sixth C site, C(57) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(10), and one O(10) atom. The C(57)-C(21) bond length is 1.49 Å. The C(57)-N(10) bond length is 1.36 Å. The C(57)-O(10) bond length is 1.22 Å. In the seventh C site, C(61) is bonded in a distorted single-bond geometry to one C(21) and one H(7) atom. The C(61)-C(21) bond length is 1.39 Å. The C(61)-H(7) bond length is 0.95 Å. In the eighth C site, C(63) is bonded in a distorted single-bond geometry to one N(6) atom. The C(63)-N(6) bond length is 1.42 Å. In the ninth C site, C(66) is bonded in a distorted single-bond geometry to one C(31) and one H(15) atom. The C(66)-H(15) bond length is 0.95 Å. In the tenth C site, C(69) is bonded in a distorted trigonal planar geometry to one C(51), one C(8), and one N(10) atom. The C(69)-C(8) bond length is 1.41 Å. The C(69)-N(10) bond length is 1.39 Å. In the eleventh C site, C(74) is bonded in a distorted single-bond geometry to one C(15), one C(6), and one N(2) atom. The C(74)-C(15) bond length is 1.51 Å. The C(74)-C(6) bond length is 1.35 Å. The C(74)-N(2) bond length is 1.32 Å. In the twelfth C site, C(76) is bonded in a distorted single-bond geometry to one N(2) atom. The C(76)-N(2) bond length is 1.31 Å. In the thirteenth C site, C(1) is bonded in a distorted single-bond geometry to one C(27) and one H(35) atom. The C(1)-H(35) bond length is 0.95 Å. In the fourteenth C site, C(4) is bonded in a distorted single-bond geometry to one N(1) atom. The C(4)-N(1) bond length is 1.43 Å. In the fifteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(74) and one H(33) atom. The C(6)-H(33) bond length is 0.95 Å. In the sixteenth C site, C(8) is bonded in a distorted single-bond geometry to one C(69) and one H(2,12) atom. The C(8)-H(2,12) bond length is 0.95 Å. In the seventeenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(74), one N(6), and one O(9) atom. The C(15)-N(6) bond length is 1.32 Å. The C(15)-O(9) bond length is 1.26 Å. In the eighteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(57), one C(61), and one N(7) atom. The C(21)-N(7) bond length is 1.33 Å. In the nineteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(31) and one H(23) atom. The C(24)-H(23) bond length is 0.95 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(30), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(74), and one C(76) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Co(1), one C(15), and one C(63) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one Co(1), one C(31), and one C(44) atom. In the fifth N site, N(7) is bonded in a trigonal planar geometry to one Co(1), one C(21), and one C(27) atom. In the sixth N site, N(10) is bonded in a trigonal planar geometry to one Co(1), one C(57), and one C(69) atom. There are six inequivalent H sites. In the first H site, H(2,12) is bonded in a single-bond geometry to one C(51) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(61) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(66) atom. In the fourth H site, H(23) is bonded in a single-bond geometry to one C(24) atom. In the fifth H site, H(33) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(35) is bonded in a single-bond geometry to one C(1) atom. There are four inequivalent O sites. In the first O site, O(9) is bonded in a single-bond geometry to one C(15) atom. In the second O site, O(10) is bonded in a single-bond geometry to one C(57) atom. In the third O site, O(25) is bonded in a single-bond geometry to one C(44) atom. In the fourth O site, O(26) is bonded in a single-bond geometry to one C(30) atom. In each CoC21H9(N3O2)2 cluster, Co(2) is bonded in an octahedral geometry to one N(11), one N(12), one N(3), one N(4), one N(8), and one N(9) atom. The Co(2)-N(11) bond length is 1.85 Å. The Co(2)-N(12) bond length is 1.98 Å. The Co(2)-N(3) bond length is 1.94 Å. The Co(2)-N(4) bond length is 1.94 Å. The Co(2)-N(8) bond length is 1.86 Å. The Co(2)-N(9) bond length is 1.94 Å. There are twenty-one inequivalent C sites. In the first C site, C(34) is bonded in a distorted single-bond geometry to one C(53), one C(71), and one H(27) atom. The C(34)-C(53) bond length is 1.38 Å. The C(34)-C(71) bond length is 1.40 Å. The C(34)-H(27) bond length is 0.95 Å. In the second C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(65), one N(3), and one O(2) atom. The C(38)-C(65) bond length is 1.48 Å. The C(38)-N(3) bond length is 1.32 Å. The C(38)-O(2) bond length is 1.25 Å. In the third C site, C(43) is bonded in a distorted single-bond geometry to one C(47) and one H(36) atom. The C(43)-C(47) bond length is 1.39 Å. The C(43)-H(36) bond length is 0.95 Å. In the fourth C site, C(45) is bonded in a distorted single-bond geometry to one C(65) and one H(19) atom. The C(45)-C(65) bond length is 1.40 Å. The C(45)-H(19) bond length is 0.95 Å. In the fifth C site, C(47) is bonded in a distorted trigonal planar geometry to one C(43), one C(56), and one N(4) atom. The C(47)-C(56) bond length is 1.37 Å. The C(47)-N(4) bond length is 1.45 Å. In the sixth C site, C(52) is bonded in a distorted single-bond geometry to one C(20) and one H(5,31) atom. The C(52)-C(20) bond length is 1.37 Å. The C(52)-H(5,31) bond length is 0.95 Å. In the seventh C site, C(53) is bonded in a distorted single-bond geometry to one C(2), one C(34), and one N(11) atom. The C(53)-C(2) bond length is 1.45 Å. The C(53)-N(11) bond length is 1.31 Å. In the eighth C site, C(56) is bonded in a distorted single-bond geometry to one C(47) and one H(13) atom. The C(56)-H(13) bond length is 0.95 Å. In the ninth C site, C(58) is bonded in a distorted single-bond geometry to one C(67) and one H(41) atom. The C(58)-C(67) bond length is 1.39 Å. The C(58)-H(41) bond length is 0.95 Å. In the tenth C site, C(59) is bonded in a distorted single-bond geometry to one C(71) and one H(38) atom. The C(59)-C(71) bond length is 1.40 Å. The C(59)-H(38) bond length is 0.95 Å. In the eleventh C site, C(65) is bonded in a distorted single-bond geometry to one C(38), one C(45), and one N(8) atom. The C(65)-N(8) bond length is 1.31 Å. In the twelfth C site, C(67) is bonded in a distorted single-bond geometry to one C(58), one C(84), and one N(8) atom. The C(67)-C(84) bond length is 1.53 Å. The C(67)-N(8) bond length is 1.32 Å. In the thirteenth C site, C(71) is bonded in a distorted trigonal planar geometry to one C(34), one C(59), and one H(3) atom. The C(71)-H(3) bond length is 0.95 Å. In the fourteenth C site, C(73) is bonded in a distorted single-bond geometry to one C(20) and one H(5,31) atom. The C(73)-C(20) bond length is 1.38 Å. The C(73)-H(5,31) bond length is 0.95 Å. In the fifteenth C site, C(75) is bonded in a distorted single-bond geometry to one N(12) atom. The C(75)-N(12) bond length is 1.41 Å. In the sixteenth C site, C(78) is bonded in a distorted single-bond geometry to one N(11) atom. The C(78)-N(11) bond length is 1.32 Å. In the seventeenth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(53), one N(9), and one O(13) atom. The C(2)-N(9) bond length is 1.34 Å. The C(2)-O(13) bond length is 1.24 Å. In the eighteenth C site, C(12) is bonded in a distorted single-bond geometry to one N(9) atom. The C(12)-N(9) bond length is 1.40 Å. In the nineteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(12) and one O(20) atom. The C(16)-N(12) bond length is 1.33 Å. The C(16)-O(20) bond length is 1.26 Å. In the twentieth C site, C(84) is bonded in a distorted bent 120 degrees geometry to one C(67), one N(4), and one O(23) atom. The C(84)-N(4) bond length is 1.31 Å. The C(84)-O(23) bond length is 1.25 Å. In the twenty-first C site, C(20) is bonded in a distorted trigonal planar geometry to one C(52), one C(73), and one N(3) atom. The C(20)-N(3) bond length is 1.44 Å. There are six inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Co(2), one C(20), and one C(38) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Co(2), one C(47), and one C(84) atom. In the third N site, N(8) is bonded in a trigonal planar geometry to one Co(2), one C(65), and one C(67) atom. In the fourth N site, N(9) is bonded in a trigonal planar geometry to one Co(2), one C(12), and one C(2) atom. In the fifth N site, N(11) is bonded in a trigonal planar geometry to one Co(2), one C(53), and one C(78) atom. In the sixth N site, N(12) is bonded in a trigonal planar geometry to one Co(2), one C(16), and one C(75) atom. There are eight inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(71) atom. In the second H site, H(5,31) is bonded in a single-bond geometry to one C(73) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(56) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(45) atom. In the fifth H site, H(27) is bonded in a single-bond geometry to one C(34) atom. In the sixth H site, H(36) is bonded in a single-bond geometry to one C(43) atom. In the seventh H site, H(38) is bonded in a single-bond geometry to one C(59) atom. In the eighth H site, H(41) is bonded in a single-bond geometry to one C(58) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one C(38) atom. In the second O site, O(13) is bonded in a single-bond geometry to one C(2) atom. In the third O site, O(20) is bonded in a single-bond geometry to one C(16) atom. In the fourth O site, O(23) is bonded in a single-bond geometry to one C(84) atom. In each Zn5H18(C17O9)2 cluster, there are five inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a T-shaped geometry to one O(15), one O(16), and one O(21) atom. The Zn(1)-O(15) bond length is 2.03 Å. The Zn(1)-O(16) bond length is 2.06 Å. The Zn(1)-O(21) bond length is 2.06 Å. In the second Zn site, Zn(2) is bonded to one O(11), one O(12), one O(18), one O(21), and one O(7) atom to form corner-sharing ZnO5 square pyramids. The Zn(2)-O(11) bond length is 2.09 Å. The Zn(2)-O(12) bond length is 2.12 Å. The Zn(2)-O(18) bond length is 1.97 Å. The Zn(2)-O(21) bond length is 2.11 Å. The Zn(2)-O(7) bond length is 2.05 Å. In the third Zn site, Zn(3) is bonded to one O(12), one O(24), one O(5), and one O(8) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(12) bond length is 1.99 Å. The Zn(3)-O(24) bond length is 1.95 Å. The Zn(3)-O(5) bond length is 1.95 Å. The Zn(3)-O(8) bond length is 1.95 Å. In the fourth Zn site, Zn(4) is bonded in a 4-coordinate geometry to one O(12), one O(14), one O(3), and one O(6) atom. The Zn(4)-O(12) bond length is 1.93 Å. The Zn(4)-O(14) bond length is 1.96 Å. The Zn(4)-O(3) bond length is 2.47 Å. The Zn(4)-O(6) bond length is 1.99 Å. In the fifth Zn site, Zn(5) is bonded to one O(17), one O(21), one O(22), and one O(4) atom to form distorted corner-sharing ZnO4 tetrahedra. The Zn(5)-O(17) bond length is 1.96 Å. The Zn(5)-O(21) bond length is 1.95 Å. The Zn(5)-O(22) bond length is 1.96 Å. The Zn(5)-O(4) bond length is 1.99 Å. There are thirty-four inequivalent C sites. In the first C site, C(28) is bonded in a trigonal planar geometry to one C(40), one C(7), and one C(83) atom. The C(28)-C(40) bond length is 1.44 Å. The C(28)-C(7) bond length is 1.40 Å. The C(28)-C(83) bond length is 1.35 Å. In the second C site, C(29) is bonded in a single-bond geometry to one C(62) and one H(26) atom. The C(29)-C(62) bond length is 1.40 Å. The C(29)-H(26) bond length is 0.95 Å. In the third C site, C(26) is bonded in a distorted single-bond geometry to one C(33) and one H(10) atom. The C(26)-C(33) bond length is 1.36 Å. The C(26)-H(10) bond length is 0.95 Å. In the fourth C site, C(33) is bonded in a trigonal planar geometry to one C(11), one C(26), and one C(68) atom. The C(33)-C(11) bond length is 1.37 Å. The C(33)-C(68) bond length is 1.51 Å. In the fifth C site, C(32) is bonded in a trigonal planar geometry to one C(36), one C(72), and one C(80) atom. The C(32)-C(36) bond length is 1.35 Å. The C(32)-C(72) bond length is 1.39 Å. The C(32)-C(80) bond length is 1.49 Å. In the sixth C site, C(35) is bonded in a trigonal planar geometry to one C(22), one C(39), and one C(64) atom. The C(35)-C(22) bond length is 1.48 Å. The C(35)-C(39) bond length is 1.37 Å. The C(35)-C(64) bond length is 1.40 Å. In the seventh C site, C(36) is bonded in a distorted single-bond geometry to one C(32) and one H(42) atom. The C(36)-H(42) bond length is 0.95 Å. In the eighth C site, C(37) is bonded in a distorted single-bond geometry to one C(62) and one H(25) atom. The C(37)-C(62) bond length is 1.36 Å. The C(37)-H(25) bond length is 0.95 Å. In the ninth C site, C(39) is bonded in a distorted single-bond geometry to one C(35) and one H(34) atom. The C(39)-H(34) bond length is 0.95 Å. In the tenth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(11), and one O(5) atom. The C(40)-O(11) bond length is 1.26 Å. The C(40)-O(5) bond length is 1.29 Å. In the eleventh C site, C(42) is bonded in a distorted single-bond geometry to one C(82) and one H(1) atom. The C(42)-C(82) bond length is 1.35 Å. The C(42)-H(1) bond length is 0.95 Å. In the twelfth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(14), and one O(3) atom. The C(46)-C(25) bond length is 1.50 Å. The C(46)-O(14) bond length is 1.23 Å. The C(46)-O(3) bond length is 1.26 Å. In the thirteenth C site, C(49) is bonded in a distorted single-bond geometry to one C(60) and one H(28) atom. The C(49)-C(60) bond length is 1.39 Å. The C(49)-H(28) bond length is 0.95 Å. In the fourteenth C site, C(54) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(15), and one O(18) atom. The C(54)-C(19) bond length is 1.50 Å. The C(54)-O(15) bond length is 1.24 Å. The C(54)-O(18) bond length is 1.29 Å. In the fifteenth C site, C(55) is bonded in a distorted single-bond geometry to one C(19) and one H(21) atom. The C(55)-C(19) bond length is 1.38 Å. The C(55)-H(21) bond length is 0.95 Å. In the sixteenth C site, C(60) is bonded in a trigonal planar geometry to one C(14), one C(49), and one C(82) atom. The C(60)-C(14) bond length is 1.50 Å. The C(60)-C(82) bond length is 1.38 Å. In the seventeenth C site, C(62) is bonded in a trigonal planar geometry to one C(23), one C(29), and one C(37) atom. The C(62)-C(23) bond length is 1.49 Å. In the eighteenth C site, C(64) is bonded in a distorted trigonal planar geometry to one C(17), one C(35), and one H(29) atom. The C(64)-C(17) bond length is 1.38 Å. The C(64)-H(29) bond length is 0.95 Å. In the nineteenth C site, C(68) is bonded in a distorted bent 120 degrees geometry to one C(33), one O(1), and one O(17) atom. The C(68)-O(1) bond length is 1.21 Å. The C(68)-O(17) bond length is 1.25 Å. In the twentieth C site, C(72) is bonded in a distorted single-bond geometry to one C(32) and one H(17) atom. The C(72)-H(17) bond length is 0.95 Å. In the twenty-first C site, C(77) is bonded in a distorted single-bond geometry to one C(19) and one H(30) atom. The C(77)-C(19) bond length is 1.35 Å. The C(77)-H(30) bond length is 0.95 Å. In the twenty-second C site, C(80) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(22), and one O(7) atom. The C(80)-O(22) bond length is 1.27 Å. The C(80)-O(7) bond length is 1.24 Å. In the twenty-third C site, C(82) is bonded in a distorted trigonal planar geometry to one C(42), one C(60), and one H(11) atom. The C(82)-H(11) bond length is 0.95 Å. In the twenty-fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(28) and one H(22) atom. The C(7)-H(22) bond length is 0.95 Å. In the twenty-fifth C site, C(83) is bonded in a distorted single-bond geometry to one C(28) and one H(40) atom. The C(83)-H(40) bond length is 0.95 Å. In the twenty-sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(25) and one H(20) atom. The C(9)-C(25) bond length is 1.36 Å. The C(9)-H(20) bond length is 0.95 Å. In the twenty-seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(33) and one H(32) atom. The C(11)-H(32) bond length is 0.95 Å. In the twenty-eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(25) and one H(6) atom. The C(13)-C(25) bond length is 1.39 Å. The C(13)-H(6) bond length is 0.95 Å. In the twenty-ninth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(60), one O(6), and one O(8) atom. The C(14)-O(6) bond length is 1.28 Å. The C(14)-O(8) bond length is 1.26 Å. In the thirtieth C site, C(17) is bonded in a distorted single-bond geometry to one C(64) and one H(18) atom. The C(17)-H(18) bond length is 0.95 Å. In the thirty-first C site, C(19) is bonded in a trigonal planar geometry to one C(54), one C(55), and one C(77) atom. In the thirty-second C site, C(22) is bonded in a bent 120 degrees geometry to one C(35), one O(16), and one O(4) atom. The C(22)-O(16) bond length is 1.24 Å. The C(22)-O(4) bond length is 1.27 Å. In the thirty-third C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(62), one O(19), and one O(24) atom. The C(23)-O(19) bond length is 1.23 Å. The C(23)-O(24) bond length is 1.26 Å. In the thirty-fourth C site, C(25) is bonded in a trigonal planar geometry to one C(13), one C(46), and one C(9) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(42) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(26) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(82) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(72) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(21) is bonded in a single-bond geometry to one C(55) atom. In the ninth H site, H(22) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(25) is bonded in a single-bond geometry to one C(37) atom. In the eleventh H site, H(26) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(28) is bonded in a single-bond geometry to one C(49) atom. In the thirteenth H site, H(29) is bonded in a single-bond geometry to one C(64) atom. In the fourteenth H site, H(30) is bonded in a single-bond geometry to one C(77) atom. In the fifteenth H site, H(32) is bonded in a single-bond geometry to one C(11) atom. In the sixteenth H site, H(34) is bonded in a single-bond geometry to one C(39) atom. In the seventeenth H site, H(40) is bonded in a single-bond geometry to one C(83) atom. In the eighteenth H site, H(42) is bonded in a single-bond geometry to one C(36) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(68) atom. In the second O site, O(3) is bonded in a distorted single-bond geometry to one Zn(4) and one C(46) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(40) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(14) atom. In the fifth O site, O(7) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(80) atom. In the sixth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(14) atom. In the seventh O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(22) atom. In the eighth O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(40) atom. In the ninth O site, O(12) is bonded in a trigonal non-coplanar geometry to one Zn(2), one Zn(3), and one Zn(4) atom. In the tenth O site, O(14) is bonded in a water-like geometry to one Zn(4) and one C(46) atom. In the eleventh O site, O(15) is bonded in a distorted single-bond geometry to one Zn(1) and one C(54) atom. In the twelfth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(22) atom. In the thirteenth O site, O(17) is bonded in a water-like geometry to one Zn(5) and one C(68) atom. In the fourteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(54) atom. In the fifteenth O site, O(19) is bonded in a single-bond geometry to one C(23) atom. In the sixteenth O site, O(21) is bonded in a trigonal non-coplanar geometry to one Zn(1), one Zn(2), and one Zn(5) atom. In the seventeenth O site, O(22) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(80) atom. In the eighteenth O site, O(24) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(23) atom. Linkers: 8 [O]C(=O)c1ccc([N]C(=O)c2cccc(C(=O)[N]c3ccc(C([O])=O)cc3)n2)cc1. Metal clusters: 1 O=[C]O[Zn]1O[C]O[Zn@](O[C]O[Zn]2O[C]O[Zn]3O[C]O[Zn@](O[C]=O)(O[C]O2)O3)(O[C]=O)O1 ,1 O=[C]O[Zn]1O[C]O[Zn@@](O[C]O[Zn]2O[C]O[Zn]3O[C]O[Zn@@](O[C]=O)(O[C]O2)O3)(O[C]=O)O1 ,4 [Co]. The MOF has largest included sphere 7.37 A, density 1.08 g/cm3, surface area 3913.99 m2/g, accessible volume 0.46 cm3/g