Cd2C19H11O8(CH)5C9H8O4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules; two 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and one Cd2C19H11O8 cluster. In the Cd2C19H11O8 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a rectangular see-saw-like geometry to one O(10), one O(7), and two equivalent O(5) atoms. The Cd(1)-O(10) bond length is 2.28 Å. The Cd(1)-O(7) bond length is 2.27 Å. Both Cd(1)-O(5) bond lengths are 2.28 Å. In the second Cd site, Cd(2) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(12), one O(2), one O(4), one O(7), and one O(9) atom. The Cd(2)-O(10) bond length is 2.64 Å. The Cd(2)-O(11) bond length is 2.24 Å. The Cd(2)-O(12) bond length is 2.36 Å. The Cd(2)-O(2) bond length is 2.31 Å. The Cd(2)-O(4) bond length is 2.24 Å. The Cd(2)-O(7) bond length is 2.45 Å. The Cd(2)-O(9) bond length is 2.42 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(14) and one H(1) atom. The C(1)-C(14) bond length is 1.37 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(6) is bonded in a distorted single-bond geometry to one C(25) and one H(8) atom. The C(6)-C(25) bond length is 1.38 Å. The C(6)-H(8) bond length is 0.95 Å. In the third C site, C(9) is bonded in a distorted single-bond geometry to one C(19) and one H(11) atom. The C(9)-C(19) bond length is 1.41 Å. The C(9)-H(11) bond length is 0.95 Å. In the fourth C site, C(10) is bonded in a distorted single-bond geometry to one C(32) and one H(12) atom. The C(10)-C(32) bond length is 1.39 Å. The C(10)-H(12) bond length is 0.95 Å. In the fifth C site, C(12) is bonded in a distorted single-bond geometry to one C(25) and one H(14) atom. The C(12)-C(25) bond length is 1.39 Å. The C(12)-H(14) bond length is 0.95 Å. In the sixth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(1), one C(27), and one H(17) atom. The C(14)-C(27) bond length is 1.38 Å. The C(14)-H(17) bond length is 0.95 Å. In the seventh C site, C(15) is bonded in a distorted single-bond geometry to one C(23) and one H(18) atom. The C(15)-C(23) bond length is 1.37 Å. The C(15)-H(18) bond length is 0.95 Å. In the eighth C site, C(18) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(28) atom. The C(18)-C(21) bond length is 1.44 Å. The C(18)-C(23) bond length is 1.43 Å. The C(18)-C(28) bond length is 1.40 Å. In the ninth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(32), one C(9), and one H(19) atom. The C(19)-C(32) bond length is 1.38 Å. The C(19)-H(19) bond length is 0.95 Å. In the tenth C site, C(21) is bonded in a bent 120 degrees geometry to one C(18), one O(12), and one O(9) atom. The C(21)-O(12) bond length is 1.25 Å. The C(21)-O(9) bond length is 1.26 Å. In the eleventh C site, C(23) is bonded in a distorted trigonal planar geometry to one C(15), one C(18), and one H(20) atom. The C(23)-H(20) bond length is 0.95 Å. In the twelfth C site, C(25) is bonded in a trigonal planar geometry to one C(12), one C(33), and one C(6) atom. The C(25)-C(33) bond length is 1.47 Å. In the thirteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(4), and one O(5) atom. The C(26)-C(27) bond length is 1.50 Å. The C(26)-O(4) bond length is 1.26 Å. The C(26)-O(5) bond length is 1.31 Å. In the fourteenth C site, C(27) is bonded in a trigonal planar geometry to one C(14), one C(26), and one C(29) atom. The C(27)-C(29) bond length is 1.37 Å. In the fifteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(18) and one H(23) atom. The C(28)-H(23) bond length is 0.95 Å. In the sixteenth C site, C(29) is bonded in a single-bond geometry to one C(27) and one H(24) atom. The C(29)-H(24) bond length is 0.95 Å. In the seventeenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(10), and one O(11) atom. The C(31)-C(32) bond length is 1.45 Å. The C(31)-O(10) bond length is 1.31 Å. The C(31)-O(11) bond length is 1.24 Å. In the eighteenth C site, C(32) is bonded in a trigonal planar geometry to one C(10), one C(19), and one C(31) atom. In the nineteenth C site, C(33) is bonded in a bent 120 degrees geometry to one C(25), one O(2), and one O(7) atom. The C(33)-O(2) bond length is 1.24 Å. The C(33)-O(7) bond length is 1.30 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(20) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(23) is bonded in a single-bond geometry to one C(28) atom. In the eleventh H site, H(24) is bonded in a single-bond geometry to one C(29) atom. There are eight inequivalent O sites. In the first O site, O(11) is bonded in a water-like geometry to one Cd(2) and one C(31) atom. In the second O site, O(12) is bonded in an L-shaped geometry to one Cd(2) and one C(21) atom. In the third O site, O(2) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(33) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cd(2) and one C(26) atom. In the fifth O site, O(5) is bonded in a distorted trigonal planar geometry to two equivalent Cd(1) and one C(26) atom. In the sixth O site, O(7) is bonded in a distorted single-bond geometry to one Cd(1), one Cd(2), and one C(33) atom. In the seventh O site, O(9) is bonded in an L-shaped geometry to one Cd(2) and one C(21) atom. In the eighth O site, O(10) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(2), and one C(31) atom. Linkers: 2 [O]C(=O)c1ccc(OCC(COc2ccc(C([O])=O)cc2)(COc2ccc(C([O])=O)cc2)COc2ccc(C([O])=O)cc2)cc1. Metal clusters: 1 [C]1O[Cd]2O[C]O[Cd]3(O1)(O[C]O[Cd]1O[C]O[Cd]4(O[C]O1)(O[C]O2)O[C]O4)O[C]O3. RCSR code: flu. The MOF has largest included sphere 8.29 A, density 0.86 g/cm3, surface area 4101.90 m2/g, accessible volume 0.74 cm3/g