ZnC14NH9O4C11H7(CH)2(CH2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight (3e)-2,3,6-trimethyl-5-methylidenehepta-1,3,6-triene molecules; sixteen 02329_fluka molecules; sixteen 02329_fluka molecules; and four ZnC14NH9O4 clusters. In each ZnC14NH9O4 cluster, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 2.05 Å. The Zn(1)-O(2) bond length is 2.02 Å. The Zn(1)-O(3) bond length is 2.05 Å. The Zn(1)-O(4) bond length is 2.04 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(25), and one C(3) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-C(25) bond length is 1.50 Å. The C(1)-C(3) bond length is 1.38 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(16) is bonded in a single-bond geometry to one C(18) and one H(11) atom. The C(16)-C(18) bond length is 1.37 Å. The C(16)-H(11) bond length is 0.93 Å. In the fifth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(12) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-H(12) bond length is 0.93 Å. In the sixth C site, C(18) is bonded in a trigonal planar geometry to one C(16), one C(17), and one C(19) atom. The C(18)-C(19) bond length is 1.49 Å. In the seventh C site, C(19) is bonded in a bent 120 degrees geometry to one C(18), one O(3), and one O(4) atom. The C(19)-O(3) bond length is 1.25 Å. The C(19)-O(4) bond length is 1.27 Å. In the eighth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(22), one N(1), and one H(13) atom. The C(20)-C(22) bond length is 1.37 Å. The C(20)-N(1) bond length is 1.35 Å. The C(20)-H(13) bond length is 0.93 Å. In the ninth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(24), one N(1), and one H(14) atom. The C(21)-C(24) bond length is 1.38 Å. The C(21)-N(1) bond length is 1.33 Å. The C(21)-H(14) bond length is 0.93 Å. In the tenth C site, C(22) is bonded in a single-bond geometry to one C(20) and one H(15) atom. The C(22)-H(15) bond length is 0.93 Å. In the eleventh C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(16) atom. The C(23)-C(24) bond length is 1.38 Å. The C(23)-H(16) bond length is 0.93 Å. In the twelfth C site, C(24) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(26) atom. The C(24)-C(26) bond length is 1.51 Å. In the thirteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(25)-O(1) bond length is 1.23 Å. The C(25)-O(2) bond length is 1.26 Å. In the fourteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(24) and one H(17) atom. The C(26)-H(17) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(20), and one C(21) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(25) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(19) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(19) atom. Linkers: 8 [O]C(=O)c1ccc(-c2cccc(-c3ccc(C([O])=O)cc3)c2)cc1 ,4 c1cncc([CH][C@H]2CC[C@H]([CH]c3cccnc3)CC2)c1. Metal clusters: 4 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: sql. The MOF has largest included sphere 6.38 A, density 1.11 g/cm3, surface area 5016.00 m2/g, accessible volume 0.44 cm3/g