Zn4C96N6H60O25 crystallizes in the monoclinic P2_1/c space group. The structure consists of a Zn4C96N6H60O25 framework. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(15), one O(2), and one O(8) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(15) bond length is 1.98 Å. The Zn(1)-O(2) bond length is 1.91 Å. The Zn(1)-O(8) bond length is 1.94 Å. In the second Zn site, Zn(2) is bonded in a rectangular see-saw-like geometry to one O(1), one O(22), one O(24), and one O(9) atom. The Zn(2)-O(1) bond length is 2.03 Å. The Zn(2)-O(22) bond length is 2.01 Å. The Zn(2)-O(24) bond length is 2.33 Å. The Zn(2)-O(9) bond length is 2.02 Å. In the third Zn site, Zn(3) is bonded to one O(1), one O(14), one O(20), and one O(23) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(1) bond length is 1.90 Å. The Zn(3)-O(14) bond length is 1.92 Å. The Zn(3)-O(20) bond length is 1.98 Å. The Zn(3)-O(23) bond length is 1.94 Å. In the fourth Zn site, Zn(4) is bonded to one O(1), one O(21), one O(25), and one O(3) atom to form corner-sharing ZnO4 tetrahedra. The Zn(4)-O(1) bond length is 1.93 Å. The Zn(4)-O(21) bond length is 1.93 Å. The Zn(4)-O(25) bond length is 1.93 Å. The Zn(4)-O(3) bond length is 1.92 Å. There are ninety-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(3) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(2) bond length is 1.33 Å. The C(1)-O(3) bond length is 1.23 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.47 Å. The C(2)-C(7) bond length is 1.42 Å. In the third C site, C(3) is bonded in a 1-coordinate geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.35 Å. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-C(8) bond length is 1.58 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.33 Å. The C(5)-N(1) bond length is 1.45 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(6)-C(7) bond length is 1.37 Å. The C(6)-C(9) bond length is 1.66 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(2) atom. The C(7)-H(2) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(4); one H(5); and two equivalent H(3,4) atoms. The C(8)-H(5) bond length is 0.98 Å. Both C(8)-H(3,4) bond lengths are 0.98 Å. In the ninth C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(6), one H(6), one H(7), and one H(8) atom. The C(9)-H(6) bond length is 0.98 Å. The C(9)-H(7) bond length is 0.98 Å. The C(9)-H(8) bond length is 0.98 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(1), and one O(4) atom. The C(10)-C(11) bond length is 1.47 Å. The C(10)-N(1) bond length is 1.35 Å. The C(10)-O(4) bond length is 1.24 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(15) atom. The C(11)-C(12) bond length is 1.48 Å. The C(11)-C(15) bond length is 1.33 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(18) atom. The C(12)-C(13) bond length is 1.30 Å. The C(12)-C(18) bond length is 1.38 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(21) atom. The C(13)-C(14) bond length is 1.53 Å. The C(13)-C(21) bond length is 1.35 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(1), and one O(5) atom. The C(14)-N(1) bond length is 1.37 Å. The C(14)-O(5) bond length is 1.24 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(11) and one H(9) atom. The C(15)-H(9) bond length is 0.95 Å. In the sixteenth C site, C(16) is bonded in a single-bond geometry to one C(17) and one H(10) atom. The C(16)-C(17) bond length is 1.36 Å. The C(16)-H(10) bond length is 0.95 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(22) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-C(22) bond length is 1.47 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(12), one C(17), and one C(19) atom. The C(18)-C(19) bond length is 1.39 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(23) atom. The C(19)-C(20) bond length is 1.36 Å. The C(19)-C(23) bond length is 1.53 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(11) atom. The C(20)-H(11) bond length is 0.95 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(13) and one H(12) atom. The C(21)-H(12) bond length is 0.95 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(2), and one O(6) atom. The C(22)-N(2) bond length is 1.38 Å. The C(22)-O(6) bond length is 1.27 Å. In the twenty-third C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(2), and one O(7) atom. The C(23)-N(2) bond length is 1.35 Å. The C(23)-O(7) bond length is 1.17 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(25), one C(29), and one N(2) atom. The C(24)-C(25) bond length is 1.37 Å. The C(24)-C(29) bond length is 1.33 Å. The C(24)-N(2) bond length is 1.48 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(30) atom. The C(25)-C(26) bond length is 1.48 Å. The C(25)-C(30) bond length is 1.49 Å. In the twenty-sixth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one C(27), and one H(13) atom. The C(26)-C(27) bond length is 1.32 Å. The C(26)-H(13) bond length is 0.95 Å. In the twenty-seventh C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(95) atom. The C(27)-C(28) bond length is 1.35 Å. The C(27)-C(95) bond length is 1.51 Å. In the twenty-eighth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one C(29), and one H(14) atom. The C(28)-C(29) bond length is 1.47 Å. The C(28)-H(14) bond length is 0.95 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(24), one C(28), and one C(31) atom. The C(29)-C(31) bond length is 1.55 Å. In the thirtieth C site, C(30) is bonded in a trigonal non-coplanar geometry to one C(25); one H(15,47); and two equivalent H(16,17) atoms. The C(30)-H(15,47) bond length is 0.98 Å. Both C(30)-H(16,17) bond lengths are 0.98 Å. In the thirty-first C site, C(31) is bonded in a trigonal non-coplanar geometry to one C(29), one H(18), one H(19), and one H(20) atom. The C(31)-H(18) bond length is 0.98 Å. The C(31)-H(19) bond length is 0.98 Å. The C(31)-H(20) bond length is 0.98 Å. In the thirty-second C site, C(32) is bonded in a 2-coordinate geometry to one C(33), one O(8), and one O(9) atom. The C(32)-C(33) bond length is 1.53 Å. The C(32)-O(8) bond length is 1.28 Å. The C(32)-O(9) bond length is 1.27 Å. In the thirty-third C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(38) atom. The C(33)-C(34) bond length is 1.42 Å. The C(33)-C(38) bond length is 1.38 Å. In the thirty-fourth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(33), one C(35), and one H(21) atom. The C(34)-C(35) bond length is 1.45 Å. The C(34)-H(21) bond length is 0.95 Å. In the thirty-fifth C site, C(35) is bonded in a trigonal planar geometry to one C(34), one C(36), and one C(39) atom. The C(35)-C(36) bond length is 1.41 Å. The C(35)-C(39) bond length is 1.54 Å. In the thirty-sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(35), one C(37), and one N(3) atom. The C(36)-C(37) bond length is 1.38 Å. The C(36)-N(3) bond length is 1.43 Å. In the thirty-seventh C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one C(40) atom. The C(37)-C(38) bond length is 1.38 Å. The C(37)-C(40) bond length is 1.56 Å. In the thirty-eighth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(33), one C(37), and one H(22) atom. The C(38)-H(22) bond length is 0.95 Å. In the thirty-ninth C site, C(39) is bonded in a trigonal non-coplanar geometry to one C(35); one H(25); and two equivalent H(23,24) atoms. The C(39)-H(25) bond length is 0.98 Å. Both C(39)-H(23,24) bond lengths are 0.98 Å. In the fortieth C site, C(40) is bonded in a trigonal non-coplanar geometry to one C(37); one H(26); and two equivalent H(27,28) atoms. The C(40)-H(26) bond length is 0.98 Å. Both C(40)-H(27,28) bond lengths are 0.98 Å. In the forty-first C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(42), one N(3), and one O(10) atom. The C(41)-C(42) bond length is 1.51 Å. The C(41)-N(3) bond length is 1.36 Å. The C(41)-O(10) bond length is 1.21 Å. In the forty-second C site, C(42) is bonded in a trigonal planar geometry to one C(41), one C(43), and one C(46) atom. The C(42)-C(43) bond length is 1.40 Å. The C(42)-C(46) bond length is 1.40 Å. In the forty-third C site, C(43) is bonded in a trigonal planar geometry to one C(42), one C(44), and one C(49) atom. The C(43)-C(44) bond length is 1.39 Å. The C(43)-C(49) bond length is 1.43 Å. In the forty-fourth C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(52) atom. The C(44)-C(45) bond length is 1.54 Å. The C(44)-C(52) bond length is 1.37 Å. In the forty-fifth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(44), one N(3), and one O(11) atom. The C(45)-N(3) bond length is 1.36 Å. The C(45)-O(11) bond length is 1.21 Å. In the forty-sixth C site, C(46) is bonded in a single-bond geometry to one C(42) and one H(29) atom. The C(46)-H(29) bond length is 0.95 Å. In the forty-seventh C site, C(47) is bonded in a distorted single-bond geometry to one C(48) and one H(30) atom. The C(47)-C(48) bond length is 1.34 Å. The C(47)-H(30) bond length is 0.95 Å. In the forty-eighth C site, C(48) is bonded in a trigonal planar geometry to one C(47), one C(49), and one C(53) atom. The C(48)-C(49) bond length is 1.44 Å. The C(48)-C(53) bond length is 1.54 Å. In the forty-ninth C site, C(49) is bonded in a trigonal planar geometry to one C(43), one C(48), and one C(50) atom. The C(49)-C(50) bond length is 1.39 Å. In the fiftieth C site, C(50) is bonded in a trigonal planar geometry to one C(49), one C(51), and one C(54) atom. The C(50)-C(51) bond length is 1.38 Å. The C(50)-C(54) bond length is 1.47 Å. In the fifty-first C site, C(51) is bonded in a distorted trigonal planar geometry to one C(50), one C(52), and one H(31) atom. The C(51)-C(52) bond length is 1.47 Å. The C(51)-H(31) bond length is 0.95 Å. In the fifty-second C site, C(52) is bonded in a distorted single-bond geometry to one C(44), one C(51), and one H(32) atom. The C(52)-H(32) bond length is 0.95 Å. In the fifty-third C site, C(53) is bonded in a distorted bent 120 degrees geometry to one C(48), one N(4), and one O(12) atom. The C(53)-N(4) bond length is 1.39 Å. The C(53)-O(12) bond length is 1.26 Å. In the fifty-fourth C site, C(54) is bonded in a distorted bent 120 degrees geometry to one C(50), one N(4), and one O(13) atom. The C(54)-N(4) bond length is 1.43 Å. The C(54)-O(13) bond length is 1.14 Å. In the fifty-fifth C site, C(55) is bonded in a distorted single-bond geometry to one C(56), one C(60), and one N(4) atom. The C(55)-C(56) bond length is 1.41 Å. The C(55)-C(60) bond length is 1.34 Å. The C(55)-N(4) bond length is 1.49 Å. In the fifty-sixth C site, C(56) is bonded in a trigonal planar geometry to one C(55), one C(57), and one C(61) atom. The C(56)-C(57) bond length is 1.45 Å. The C(56)-C(61) bond length is 1.53 Å. In the fifty-seventh C site, C(57) is bonded in a distorted trigonal planar geometry to one C(56), one C(58), and one H(33) atom. The C(57)-C(58) bond length is 1.37 Å. The C(57)-H(33) bond length is 0.95 Å. In the fifty-eighth C site, C(58) is bonded in a trigonal planar geometry to one C(57), one C(59), and one C(96) atom. The C(58)-C(59) bond length is 1.38 Å. The C(58)-C(96) bond length is 1.54 Å. In the fifty-ninth C site, C(59) is bonded in a distorted trigonal planar geometry to one C(58), one C(60), and one H(34) atom. The C(59)-C(60) bond length is 1.39 Å. The C(59)-H(34) bond length is 0.95 Å. In the sixtieth C site, C(60) is bonded in a trigonal planar geometry to one C(55), one C(59), and one C(62) atom. The C(60)-C(62) bond length is 1.48 Å. In the sixty-first C site, C(61) is bonded in a trigonal non-coplanar geometry to one C(56); one H(35); and two equivalent H(36,37) atoms. The C(61)-H(35) bond length is 0.98 Å. Both C(61)-H(36,37) bond lengths are 0.98 Å. In the sixty-second C site, C(62) is bonded in a trigonal non-coplanar geometry to one C(60); one H(39); and two equivalent H(38,40) atoms. The C(62)-H(39) bond length is 0.98 Å. Both C(62)-H(38,40) bond lengths are 0.98 Å. In the sixty-third C site, C(63) is bonded in a distorted bent 120 degrees geometry to one C(64), one O(14), and one O(15) atom. The C(63)-C(64) bond length is 1.48 Å. The C(63)-O(14) bond length is 1.26 Å. The C(63)-O(15) bond length is 1.27 Å. In the sixty-fourth C site, C(64) is bonded in a trigonal planar geometry to one C(63), one C(65), and one C(69) atom. The C(64)-C(65) bond length is 1.33 Å. The C(64)-C(69) bond length is 1.34 Å. In the sixty-fifth C site, C(65) is bonded in a distorted single-bond geometry to one C(64), one C(66), and one H(41) atom. The C(65)-C(66) bond length is 1.44 Å. The C(65)-H(41) bond length is 0.95 Å. In the sixty-sixth C site, C(66) is bonded in a trigonal planar geometry to one C(65), one C(67), and one C(70) atom. The C(66)-C(67) bond length is 1.32 Å. The C(66)-C(70) bond length is 1.47 Å. In the sixty-seventh C site, C(67) is bonded in a distorted single-bond geometry to one C(66), one C(68), and one N(5) atom. The C(67)-C(68) bond length is 1.38 Å. The C(67)-N(5) bond length is 1.47 Å. In the sixty-eighth C site, C(68) is bonded in a trigonal planar geometry to one C(67), one C(69), and one C(71) atom. The C(68)-C(69) bond length is 1.45 Å. The C(68)-C(71) bond length is 1.54 Å. In the sixty-ninth C site, C(69) is bonded in a distorted trigonal planar geometry to one C(64), one C(68), and one H(42) atom. The C(69)-H(42) bond length is 0.95 Å. In the seventieth C site, C(70) is bonded in a trigonal non-coplanar geometry to one C(66), one H(43), one H(44), and one H(45) atom. The C(70)-H(43) bond length is 0.98 Å. The C(70)-H(44) bond length is 0.98 Å. The C(70)-H(45) bond length is 0.98 Å. In the seventy-first C site, C(71) is bonded in a trigonal non-coplanar geometry to one C(68); one H(15,47); and two equivalent H(46,48) atoms. The C(71)-H(15,47) bond length is 0.98 Å. Both C(71)-H(46,48) bond lengths are 0.98 Å. In the seventy-second C site, C(72) is bonded in a distorted bent 120 degrees geometry to one C(73), one N(5), and one O(17) atom. The C(72)-C(73) bond length is 1.48 Å. The C(72)-N(5) bond length is 1.40 Å. The C(72)-O(17) bond length is 1.25 Å. In the seventy-third C site, C(73) is bonded in a trigonal planar geometry to one C(72), one C(74), and one C(77) atom. The C(73)-C(74) bond length is 1.42 Å. The C(73)-C(77) bond length is 1.34 Å. In the seventy-fourth C site, C(74) is bonded in a trigonal planar geometry to one C(73), one C(75), and one C(80) atom. The C(74)-C(75) bond length is 1.43 Å. The C(74)-C(80) bond length is 1.40 Å. In the seventy-fifth C site, C(75) is bonded in a trigonal planar geometry to one C(74), one C(76), and one C(83) atom. The C(75)-C(76) bond length is 1.47 Å. The C(75)-C(83) bond length is 1.36 Å. In the seventy-sixth C site, C(76) is bonded in a distorted bent 120 degrees geometry to one C(75), one N(5), and one O(16) atom. The C(76)-N(5) bond length is 1.41 Å. The C(76)-O(16) bond length is 1.22 Å. In the seventy-seventh C site, C(77) is bonded in a single-bond geometry to one C(73) and one H(49) atom. The C(77)-H(49) bond length is 0.95 Å. In the seventy-eighth C site, C(78) is bonded in a distorted single-bond geometry to one C(79) and one H(50) atom. The C(78)-C(79) bond length is 1.34 Å. The C(78)-H(50) bond length is 0.95 Å. In the seventy-ninth C site, C(79) is bonded in a trigonal planar geometry to one C(78), one C(80), and one C(84) atom. The C(79)-C(80) bond length is 1.36 Å. The C(79)-C(84) bond length is 1.47 Å. In the eightieth C site, C(80) is bonded in a trigonal planar geometry to one C(74), one C(79), and one C(81) atom. The C(80)-C(81) bond length is 1.46 Å. In the eighty-first C site, C(81) is bonded in a trigonal planar geometry to one C(80), one C(82), and one C(85) atom. The C(81)-C(82) bond length is 1.40 Å. The C(81)-C(85) bond length is 1.45 Å. In the eighty-second C site, C(82) is bonded in a distorted single-bond geometry to one C(81), one C(83), and one H(51) atom. The C(82)-C(83) bond length is 1.40 Å. The C(82)-H(51) bond length is 0.95 Å. In the eighty-third C site, C(83) is bonded in a distorted trigonal planar geometry to one C(75), one C(82), and one H(52) atom. The C(83)-H(52) bond length is 0.95 Å. In the eighty-fourth C site, C(84) is bonded in a distorted bent 120 degrees geometry to one C(79), one N(6), and one O(19) atom. The C(84)-N(6) bond length is 1.46 Å. The C(84)-O(19) bond length is 1.22 Å. In the eighty-fifth C site, C(85) is bonded in a distorted bent 120 degrees geometry to one C(81), one N(6), and one O(18) atom. The C(85)-N(6) bond length is 1.38 Å. The C(85)-O(18) bond length is 1.24 Å. In the eighty-sixth C site, C(86) is bonded in a distorted single-bond geometry to one C(91), one C(92), and one N(6) atom. The C(86)-C(91) bond length is 1.37 Å. The C(86)-C(92) bond length is 1.36 Å. The C(86)-N(6) bond length is 1.47 Å. In the eighty-seventh C site, C(87) is bonded in a trigonal non-coplanar geometry to one C(92) and three equivalent H(53,54,55) atoms. The C(87)-C(92) bond length is 1.53 Å. All C(87)-H(53,54,55) bond lengths are 0.98 Å. In the eighty-eighth C site, C(88) is bonded in a distorted single-bond geometry to one C(92), one C(93), and one H(56) atom. The C(88)-C(92) bond length is 1.39 Å. The C(88)-C(93) bond length is 1.39 Å. The C(88)-H(56) bond length is 0.95 Å. In the eighty-ninth C site, C(89) is bonded in a trigonal non-coplanar geometry to one C(91); one H(59); and two equivalent H(57,58) atoms. The C(89)-C(91) bond length is 1.51 Å. The C(89)-H(59) bond length is 0.98 Å. Both C(89)-H(57,58) bond lengths are 0.98 Å. In the ninetieth C site, C(90) is bonded in a distorted trigonal planar geometry to one C(91), one C(93), and one H(60) atom. The C(90)-C(91) bond length is 1.39 Å. The C(90)-C(93) bond length is 1.29 Å. The C(90)-H(60) bond length is 0.95 Å. In the ninety-first C site, C(91) is bonded in a trigonal planar geometry to one C(86), one C(89), and one C(90) atom. In the ninety-second C site, C(92) is bonded in a trigonal planar geometry to one C(86), one C(87), and one C(88) atom. In the ninety-third C site, C(93) is bonded in a trigonal planar geometry to one C(88), one C(90), and one C(94) atom. The C(93)-C(94) bond length is 1.49 Å. In the ninety-fourth C site, C(94) is bonded in a bent 120 degrees geometry to one C(93), one O(24), and one O(25) atom. The C(94)-O(24) bond length is 1.29 Å. The C(94)-O(25) bond length is 1.23 Å. In the ninety-fifth C site, C(95) is bonded in a distorted trigonal planar geometry to one C(27), one O(22), and one O(23) atom. The C(95)-O(22) bond length is 1.26 Å. The C(95)-O(23) bond length is 1.30 Å. In the ninety-sixth C site, C(96) is bonded in a distorted bent 120 degrees geometry to one C(58), one O(20), and one O(21) atom. The C(96)-O(20) bond length is 1.24 Å. The C(96)-O(21) bond length is 1.29 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(22), one C(23), and one C(24) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(36), one C(41), and one C(45) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(53), one C(54), and one C(55) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(67), one C(72), and one C(76) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(84), one C(85), and one C(86) atom. There are forty-nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(26) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(28) atom. In the fourteenth H site, H(15,47) is bonded in a single-bond geometry to one C(30) atom. In the fifteenth H site, H(16,17) is bonded in a single-bond geometry to one C(30) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(31) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(31) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(31) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(34) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(38) atom. In the twenty-first H site, H(23,24) is bonded in a single-bond geometry to one C(39) atom. In the twenty-second H site, H(25) is bonded in a single-bond geometry to one C(39) atom. In the twenty-third H site, H(26) is bonded in a single-bond geometry to one C(40) atom. In the twenty-fourth H site, H(27,28) is bonded in a single-bond geometry to one C(40) atom. In the twenty-fifth H site, H(29) is bonded in a single-bond geometry to one C(46) atom. In the twenty-sixth H site, H(30) is bonded in a single-bond geometry to one C(47) atom. In the twenty-seventh H site, H(31) is bonded in a single-bond geometry to one C(51) atom. In the twenty-eighth H site, H(32) is bonded in a single-bond geometry to one C(52) atom. In the twenty-ninth H site, H(33) is bonded in a single-bond geometry to one C(57) atom. In the thirtieth H site, H(34) is bonded in a single-bond geometry to one C(59) atom. In the thirty-first H site, H(35) is bonded in a single-bond geometry to one C(61) atom. In the thirty-second H site, H(36,37) is bonded in a single-bond geometry to one C(61) atom. In the thirty-third H site, H(38,40) is bonded in a single-bond geometry to one C(62) atom. In the thirty-fourth H site, H(39) is bonded in a single-bond geometry to one C(62) atom. In the thirty-fifth H site, H(41) is bonded in a single-bond geometry to one C(65) atom. In the thirty-sixth H site, H(42) is bonded in a single-bond geometry to one C(69) atom. In the thirty-seventh H site, H(43) is bonded in a single-bond geometry to one C(70) atom. In the thirty-eighth H site, H(44) is bonded in a single-bond geometry to one C(70) atom. In the thirty-ninth H site, H(45) is bonded in a single-bond geometry to one C(70) atom. In the fortieth H site, H(46,48) is bonded in a single-bond geometry to one C(71) atom. In the forty-first H site, H(49) is bonded in a single-bond geometry to one C(77) atom. In the forty-second H site, H(50) is bonded in a single-bond geometry to one C(78) atom. In the forty-third H site, H(51) is bonded in a single-bond geometry to one C(82) atom. In the forty-fourth H site, H(52) is bonded in a single-bond geometry to one C(83) atom. In the forty-fifth H site, H(53,54,55) is bonded in a single-bond geometry to one C(87) atom. In the forty-sixth H site, H(56) is bonded in a single-bond geometry to one C(88) atom. In the forty-seventh H site, H(57,58) is bonded in a single-bond geometry to one C(89) atom. In the forty-eighth H site, H(59) is bonded in a single-bond geometry to one C(89) atom. In the forty-ninth H site, H(60) is bonded in a single-bond geometry to one C(90) atom. There are twenty-five inequivalent O sites. In the first O site, O(1) is bonded in a tetrahedral geometry to one Zn(1), one Zn(2), one Zn(3), and one Zn(4) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(14) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(22) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one C(23) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(32) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(32) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(41) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one C(45) atom. In the twelfth O site, O(12) is bonded in a single-bond geometry to one C(53) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one C(54) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(63) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(63) atom. In the sixteenth O site, O(16) is bonded in a single-bond geometry to one C(76) atom. In the seventeenth O site, O(17) is bonded in a single-bond geometry to one C(72) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one C(85) atom. In the nineteenth O site, O(19) is bonded in a single-bond geometry to one C(84) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(96) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(96) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(95) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(95) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(94) atom. In the twenty-fifth O site, O(25) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(94) atom. Linkers: 12 Cc1cc(C([O])=O)cc(C)c1N1C(=O)c2ccc3c4c(ccc(c24)C1=O)C(=O)N(c1c(C)cc(C([O])=O)cc1C)C3=O. Metal clusters: 2 [O][C]O[Zn@@]12O[C]O[Zn]3O[C]O[Zn]O[C]O[Zn@](O[C]O3)(O[C]O1)O2 ,2 [O][C]O[Zn@]12O[C]O[Zn]3O[C]O[Zn]O[C]O[Zn@@](O[C]O3)(O[C]O1)O2. RCSR code: pcu. The MOF has largest included sphere 15.20 A, density 0.50 g/cm3, surface area 4608.92 m2/g, accessible volume 1.50 cm3/g