Mn2C32N5H24O8(CH)12(CH2)3C2NH2 crystallizes in the triclinic P-1 space group. The structure consists of six 02329_fluka molecules, six isobutylene molecules, and two n-methyl methanimine molecules inside a Mn2C32N5H24O8 framework. In the Mn2C32N5H24O8 framework, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a square pyramidal geometry to one N(3), one N(4), one N(6), one O(1), and one O(5) atom. The Mn(1)-N(3) bond length is 2.30 Å. The Mn(1)-N(4) bond length is 2.32 Å. The Mn(1)-N(6) bond length is 2.29 Å. The Mn(1)-O(1) bond length is 2.16 Å. The Mn(1)-O(5) bond length is 2.15 Å. In the second Mn site, Mn(2) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent O(2) atoms. Both Mn(2)-N(2) bond lengths are 2.28 Å. Both Mn(2)-O(2) bond lengths are 2.19 Å. In the third Mn site, Mn(3) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(7) atoms. Both Mn(3)-N(1) bond lengths are 2.29 Å. Both Mn(3)-O(7) bond lengths are 2.16 Å. There are thirty-two inequivalent C sites. In the first C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(48), one O(7), and one O(8) atom. The C(37)-C(48) bond length is 1.52 Å. The C(37)-O(7) bond length is 1.26 Å. The C(37)-O(8) bond length is 1.25 Å. In the second C site, C(40) is bonded in a distorted single-bond geometry to one C(3), one C(7), and one H(35) atom. The C(40)-C(3) bond length is 1.40 Å. The C(40)-C(7) bond length is 1.40 Å. The C(40)-H(35) bond length is 0.93 Å. In the third C site, C(41) is bonded in a water-like geometry to one C(17) and two equivalent H(36,37) atoms. The C(41)-C(17) bond length is 1.51 Å. Both C(41)-H(36,37) bond lengths are 0.97 Å. In the fourth C site, C(43) is bonded in a distorted single-bond geometry to one C(48), one C(49), and one H(40) atom. The C(43)-C(48) bond length is 1.39 Å. The C(43)-C(49) bond length is 1.40 Å. The C(43)-H(40) bond length is 0.93 Å. In the fifth C site, C(48) is bonded in a trigonal planar geometry to one C(37), one C(43), and one C(49) atom. The C(48)-C(49) bond length is 1.41 Å. In the sixth C site, C(49) is bonded in a trigonal planar geometry to one C(15), one C(43), and one C(48) atom. The C(49)-C(15) bond length is 1.52 Å. In the seventh C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(2), and one O(4) atom. The C(1)-C(3) bond length is 1.53 Å. The C(1)-O(2) bond length is 1.27 Å. The C(1)-O(4) bond length is 1.25 Å. In the eighth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(1), and one O(3) atom. The C(2)-C(7) bond length is 1.51 Å. The C(2)-O(1) bond length is 1.28 Å. The C(2)-O(3) bond length is 1.25 Å. In the ninth C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(40), and one C(7) atom. The C(3)-C(7) bond length is 1.41 Å. In the tenth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(16), one N(3), and one H(1) atom. The C(4)-C(16) bond length is 1.39 Å. The C(4)-N(3) bond length is 1.34 Å. The C(4)-H(1) bond length is 0.93 Å. In the eleventh C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(2) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(2) bond length is 0.93 Å. In the twelfth C site, C(6) is bonded in a distorted single-bond geometry to one C(18), one C(5), and one H(3) atom. The C(6)-C(18) bond length is 1.39 Å. The C(6)-H(3) bond length is 0.93 Å. In the thirteenth C site, C(7) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(40) atom. In the fourteenth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(4) atom. The C(8)-N(6) bond length is 1.34 Å. The C(8)-H(4) bond length is 0.93 Å. In the fifteenth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one H(5) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-N(1) bond length is 1.35 Å. The C(9)-H(5) bond length is 0.93 Å. In the sixteenth C site, C(10) is bonded in a single-bond geometry to one C(18), one C(9), and one H(6) atom. The C(10)-C(18) bond length is 1.40 Å. The C(10)-H(6) bond length is 0.93 Å. In the seventeenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(14)-N(2) bond length is 1.34 Å. The C(14)-H(9) bond length is 0.93 Å. In the eighteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(49), one O(5), and one O(6) atom. The C(15)-O(5) bond length is 1.26 Å. The C(15)-O(6) bond length is 1.26 Å. In the nineteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17), one C(4), and one H(10) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(10) bond length is 0.93 Å. In the twentieth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(25), and one C(41) atom. The C(17)-C(25) bond length is 1.39 Å. In the twenty-first C site, C(18) is bonded in a trigonal planar geometry to one C(10), one C(30), and one C(6) atom. The C(18)-C(30) bond length is 1.52 Å. In the twenty-second C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(11) atom. The C(19)-N(6) bond length is 1.35 Å. The C(19)-H(11) bond length is 0.93 Å. In the twenty-third C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(14) atom. The C(21)-N(4) bond length is 1.34 Å. The C(21)-H(14) bond length is 0.93 Å. In the twenty-fourth C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(15) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(15) bond length is 0.93 Å. In the twenty-fifth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(36) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(36) bond length is 1.51 Å. In the twenty-sixth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(35), and one H(16) atom. The C(24)-C(35) bond length is 1.38 Å. The C(24)-H(16) bond length is 0.93 Å. In the twenty-seventh C site, C(25) is bonded in a distorted single-bond geometry to one C(17) and one H(17) atom. The C(25)-H(17) bond length is 0.93 Å. In the twenty-eighth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(20) atom. The C(27)-N(2) bond length is 1.34 Å. The C(27)-H(20) bond length is 0.93 Å. In the twenty-ninth C site, C(30) is bonded in a water-like geometry to one C(18) and two equivalent H(22,23) atoms. Both C(30)-H(22,23) bond lengths are 0.97 Å. In the thirtieth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(26) atom. The C(32)-N(3) bond length is 1.35 Å. The C(32)-H(26) bond length is 0.93 Å. In the thirty-first C site, C(35) is bonded in a distorted trigonal planar geometry to one C(24), one N(4), and one H(30) atom. The C(35)-N(4) bond length is 1.35 Å. The C(35)-H(30) bond length is 0.93 Å. In the thirty-second C site, C(36) is bonded in a water-like geometry to one C(23) and two equivalent H(31,32) atoms. Both C(36)-H(31,32) bond lengths are 0.97 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(3), one C(5), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(2), one C(14), and one C(27) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Mn(1), one C(32), and one C(4) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Mn(1), one C(21), and one C(35) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one Mn(1), one C(19), and one C(8) atom. There are twenty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(27) atom. In the fifteenth H site, H(22,23) is bonded in a single-bond geometry to one C(30) atom. In the sixteenth H site, H(26) is bonded in a single-bond geometry to one C(32) atom. In the seventeenth H site, H(30) is bonded in a single-bond geometry to one C(35) atom. In the eighteenth H site, H(31,32) is bonded in a single-bond geometry to one C(36) atom. In the nineteenth H site, H(35) is bonded in a single-bond geometry to one C(40) atom. In the twentieth H site, H(36,37) is bonded in a single-bond geometry to one C(41) atom. In the twenty-first H site, H(40) is bonded in a single-bond geometry to one C(43) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(15) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(15) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Mn(3) and one C(37) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(37) atom. Linkers: 1 [CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH][N].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]/[C]=[C]\[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]N=[CH].[C][CH].[C][CH][C].[C][C].[C][C].[C][C].[C][C]/C=[C]\[N].[C][C]C[CH].[C][N][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[Mn].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][Mn].[O][Mn][O]. Metal clusters: 3 [Mn]. The MOF has largest included sphere 5.75 A, density 1.19 g/cm3, surface area 5352.35 m2/g, accessible volume 0.32 cm3/g