(CoC24H12(N2O)3)2(CH)15 crystallizes in the trigonal P31c space group. The structure consists of thirty 02329_fluka molecules inside a CoC24H12(N2O)3 framework. In the CoC24H12(N2O)3 framework, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded in an octahedral geometry to three equivalent N(1) and three equivalent O(2) atoms. All Co(1)-N(1) bond lengths are 2.18 Å. All Co(1)-O(2) bond lengths are 2.09 Å. In the second Co site, Co(2) is bonded in an octahedral geometry to three equivalent N(4) and three equivalent O(1) atoms. All Co(2)-N(4) bond lengths are 2.17 Å. All Co(2)-O(1) bond lengths are 2.03 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.27 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3), one C(4), and one N(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(4) bond length is 1.43 Å. The C(2)-N(1) bond length is 1.44 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a 3-coordinate geometry to one C(2), one C(7), and one N(2) atom. The C(4)-C(7) bond length is 1.23 Å. The C(4)-N(2) bond length is 1.43 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(8), one C(9), and one N(2) atom. The C(5)-C(8) bond length is 1.43 Å. The C(5)-C(9) bond length is 1.43 Å. The C(5)-N(2) bond length is 1.44 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a single-bond geometry to one C(11), one C(5), and one H(5) atom. The C(8)-C(11) bond length is 1.34 Å. The C(8)-H(5) bond length is 0.93 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(12), one C(5), and one H(6) atom. The C(9)-C(12) bond length is 1.33 Å. The C(9)-H(6) bond length is 0.93 Å. In the ninth C site, C(11) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(8) atom. The C(11)-C(13) bond length is 1.51 Å. The C(11)-C(14) bond length is 1.45 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14), one C(9), and one N(3) atom. The C(12)-C(14) bond length is 1.33 Å. The C(12)-N(3) bond length is 1.43 Å. In the eleventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(1), and one O(2) atom. The C(13)-O(1) bond length is 1.32 Å. The C(13)-O(2) bond length is 1.19 Å. In the twelfth C site, C(14) is bonded in a single-bond geometry to one C(11), one C(12), and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. In the thirteenth C site, C(15) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(9) atom. The C(15)-N(3) bond length is 1.38 Å. The C(15)-N(4) bond length is 1.38 Å. The C(15)-H(9) bond length is 0.93 Å. In the fourteenth C site, C(16) is bonded in a 3-coordinate geometry to one C(17), one C(18), and one N(3) atom. The C(16)-C(17) bond length is 1.36 Å. The C(16)-C(18) bond length is 1.53 Å. The C(16)-N(3) bond length is 1.36 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one N(4) atom. The C(17)-N(4) bond length is 1.36 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(16) and one H(10) atom. The C(18)-H(10) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Co(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(5) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(12), one C(15), and one C(16) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Co(2), one C(15), and one C(17) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Co(2) and one C(13) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(13) atom. Linkers: 6 [O]C(=O)c1cc(-n2cnc3ccccc32)cc(-n2cnc3ccccc32)c1. Metal clusters: 2 [C]1O[Co]2O[C]O[Co](O1)O[C]O2. The MOF has largest included sphere 6.87 A, density 1.12 g/cm3, surface area 4410.65 m2/g, accessible volume 0.42 cm3/g