Mn3C21N8H11O9(CH)17(CH2)10(CH3)3 is Indium-derived structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of one hundred and forty-four 02329_fluka molecules, one hundred and sixty 02329_fluka molecules, forty-eight 02329_fluka molecules, thirty-two isobutylene molecules, and eight Mn3C21N8H11O9 clusters. In each Mn3C21N8H11O9 cluster, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted square pyramidal geometry to one N(1), one N(7), one O(1), one O(3), and one O(8) atom. The Mn(1)-N(1) bond length is 1.93 Å. The Mn(1)-N(7) bond length is 2.25 Å. The Mn(1)-O(1) bond length is 1.86 Å. The Mn(1)-O(3) bond length is 1.95 Å. The Mn(1)-O(8) bond length is 1.97 Å. In the second Mn site, Mn(2) is bonded in a distorted octahedral geometry to one N(2), one N(3), one N(5), one O(2), one O(4), and one O(6) atom. The Mn(2)-N(2) bond length is 2.25 Å. The Mn(2)-N(3) bond length is 1.93 Å. The Mn(2)-N(5) bond length is 2.28 Å. The Mn(2)-O(2) bond length is 1.99 Å. The Mn(2)-O(4) bond length is 1.87 Å. The Mn(2)-O(6) bond length is 1.94 Å. In the third Mn site, Mn(3) is bonded in an octahedral geometry to one N(4), one N(6), one N(8), one O(5), one O(7), and one O(9) atom. The Mn(3)-N(4) bond length is 2.23 Å. The Mn(3)-N(6) bond length is 1.94 Å. The Mn(3)-N(8) bond length is 2.27 Å. The Mn(3)-O(5) bond length is 1.98 Å. The Mn(3)-O(7) bond length is 1.86 Å. The Mn(3)-O(9) bond length is 1.94 Å. There are twenty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one O(1) atom. The C(1)-C(6) bond length is 1.40 Å. The C(1)-O(1) bond length is 1.34 Å. In the second C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.46 Å. In the fourth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one O(2) atom. The C(7)-N(1) bond length is 1.33 Å. The C(7)-O(2) bond length is 1.26 Å. In the fifth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one O(3) atom. The C(8)-C(9) bond length is 1.49 Å. The C(8)-N(2) bond length is 1.31 Å. The C(8)-O(3) bond length is 1.29 Å. In the sixth C site, C(9) is bonded in a water-like geometry to one C(8) and two equivalent H(5,6) atoms. Both C(9)-H(5,6) bond lengths are 0.99 Å. In the seventh C site, C(14) is bonded in a distorted single-bond geometry to one C(19) and one O(4) atom. The C(14)-C(19) bond length is 1.40 Å. The C(14)-O(4) bond length is 1.33 Å. In the eighth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(19) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(19) bond length is 0.95 Å. In the ninth C site, C(19) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(20) atom. The C(19)-C(20) bond length is 1.49 Å. In the tenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(3), and one O(5) atom. The C(20)-N(3) bond length is 1.33 Å. The C(20)-O(5) bond length is 1.28 Å. In the eleventh C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one N(4), and one O(6) atom. The C(21)-C(22) bond length is 1.51 Å. The C(21)-N(4) bond length is 1.30 Å. The C(21)-O(6) bond length is 1.29 Å. In the twelfth C site, C(22) is bonded in a water-like geometry to one C(21) and two equivalent H(20,21) atoms. Both C(22)-H(20,21) bond lengths are 0.99 Å. In the thirteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(31) atom. The C(27)-N(5) bond length is 1.34 Å. The C(27)-H(31) bond length is 0.95 Å. In the fourteenth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(33) atom. The C(29)-N(5) bond length is 1.32 Å. The C(29)-H(33) bond length is 0.95 Å. In the fifteenth C site, C(33) is bonded in a single-bond geometry to one C(38) and one O(7) atom. The C(33)-C(38) bond length is 1.42 Å. The C(33)-O(7) bond length is 1.32 Å. In the sixteenth C site, C(37) is bonded in a distorted single-bond geometry to one C(38) and one H(40) atom. The C(37)-C(38) bond length is 1.41 Å. The C(37)-H(40) bond length is 0.95 Å. In the seventeenth C site, C(38) is bonded in a trigonal planar geometry to one C(33), one C(37), and one C(39) atom. The C(38)-C(39) bond length is 1.49 Å. In the eighteenth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one C(38), one N(6), and one O(8) atom. The C(39)-N(6) bond length is 1.32 Å. The C(39)-O(8) bond length is 1.28 Å. In the nineteenth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one N(7) and one O(9) atom. The C(40)-N(7) bond length is 1.29 Å. The C(40)-O(9) bond length is 1.28 Å. In the twentieth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(52) atom. The C(46)-N(8) bond length is 1.36 Å. The C(46)-H(52) bond length is 0.95 Å. In the twenty-first C site, C(48) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(54) atom. The C(48)-N(8) bond length is 1.32 Å. The C(48)-H(54) bond length is 0.95 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(7), and one N(2) atom. The N(1)-N(2) bond length is 1.43 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Mn(2), one C(8), and one N(1) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Mn(2), one C(20), and one N(4) atom. The N(3)-N(4) bond length is 1.43 Å. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one Mn(3), one C(21), and one N(3) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Mn(2), one C(27), and one C(29) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Mn(3), one C(39), and one N(7) atom. The N(6)-N(7) bond length is 1.42 Å. In the seventh N site, N(7) is bonded in a 3-coordinate geometry to one Mn(1), one C(40), and one N(6) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Mn(3), one C(46), and one C(48) atom. There are nine inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(5,6) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the fourth H site, H(20,21) is bonded in a single-bond geometry to one C(22) atom. In the fifth H site, H(31) is bonded in a single-bond geometry to one C(27) atom. In the sixth H site, H(33) is bonded in a single-bond geometry to one C(29) atom. In the seventh H site, H(40) is bonded in a single-bond geometry to one C(37) atom. In the eighth H site, H(52) is bonded in a single-bond geometry to one C(46) atom. In the ninth H site, H(54) is bonded in a single-bond geometry to one C(48) atom. There are nine inequivalent O sites. In the first O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(39) atom. In the second O site, O(9) is bonded in a water-like geometry to one Mn(3) and one C(40) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(33) atom. In the fifth O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(7) atom. In the sixth O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(8) atom. In the seventh O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(14) atom. In the eighth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(20) atom. In the ninth O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(21) atom. Linkers: 7 c1cc(CCc2ccncc2)ccn1 ,24 CCCCCC(=O)[N][N]C(=O)c1ccccc1[O]. Metal clusters: 24 [Mn]. The MOF has largest included sphere 8.29 A, density 1.02 g/cm3, surface area 5050.50 m2/g, accessible volume 0.47 cm3/g