CdC20H14(NO)4(CH)12 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules; two 2,4-dimethyl-1,3-pentadiene molecules; and one CdC20H14(NO)4 cluster. In the CdC20H14(NO)4 cluster, Cd(1) is bonded in a 7-coordinate geometry to one N(1), one N(3), one O(1), one O(3), one O(4), and two equivalent O(2) atoms. The Cd(1)-N(1) bond length is 2.30 Å. The Cd(1)-N(3) bond length is 2.35 Å. The Cd(1)-O(1) bond length is 2.46 Å. The Cd(1)-O(3) bond length is 2.65 Å. The Cd(1)-O(4) bond length is 2.31 Å. There is one shorter (2.30 Å) and one longer (2.48 Å) Cd(1)-O(2) bond length. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(1)-O(2) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.23 Å. In the second C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(4) atom. The C(10)-O(1) bond length is 1.25 Å. The C(10)-O(4) bond length is 1.24 Å. In the third C site, C(11) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(9) atom. The C(11)-N(1) bond length is 1.31 Å. The C(11)-N(2) bond length is 1.35 Å. The C(11)-H(9) bond length is 0.93 Å. In the fourth C site, C(12) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one N(1) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-C(17) bond length is 1.39 Å. The C(12)-N(1) bond length is 1.40 Å. In the fifth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(13)-H(10) bond length is 0.93 Å. In the sixth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(13) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(13) bond length is 0.93 Å. In the seventh C site, C(17) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one N(2) atom. The C(17)-N(2) bond length is 1.39 Å. In the eighth C site, C(18) is bonded in a 3-coordinate geometry to one C(20); one N(2); and two equivalent H(14,15) atoms. The C(18)-C(20) bond length is 1.52 Å. The C(18)-N(2) bond length is 1.46 Å. Both C(18)-H(14,15) bond lengths are 0.97 Å. In the ninth C site, C(19) is bonded in a distorted single-bond geometry to one C(20) and one H(16) atom. The C(19)-C(20) bond length is 1.37 Å. The C(19)-H(16) bond length is 0.93 Å. In the tenth C site, C(20) is bonded in a trigonal planar geometry to one C(18), one C(19), and one C(21) atom. The C(20)-C(21) bond length is 1.36 Å. In the eleventh C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(17) atom. The C(21)-H(17) bond length is 0.93 Å. In the twelfth C site, C(22) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(18) atom. The C(22)-N(3) bond length is 1.31 Å. The C(22)-N(4) bond length is 1.36 Å. The C(22)-H(18) bond length is 0.93 Å. In the thirteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(24), one C(28), and one N(3) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(28) bond length is 1.39 Å. The C(23)-N(3) bond length is 1.40 Å. In the fourteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(19) atom. The C(24)-H(19) bond length is 0.93 Å. In the fifteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(28) and one H(22) atom. The C(27)-C(28) bond length is 1.38 Å. The C(27)-H(22) bond length is 0.93 Å. In the sixteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(23), one C(27), and one N(4) atom. The C(28)-N(4) bond length is 1.39 Å. In the seventeenth C site, C(29) is bonded in a 3-coordinate geometry to one C(31), one N(4), one H(23), and one H(24) atom. The C(29)-C(31) bond length is 1.53 Å. The C(29)-N(4) bond length is 1.46 Å. The C(29)-H(23) bond length is 0.97 Å. The C(29)-H(24) bond length is 0.97 Å. In the eighteenth C site, C(30) is bonded in a distorted single-bond geometry to one C(31) and one H(25) atom. The C(30)-C(31) bond length is 1.38 Å. The C(30)-H(25) bond length is 0.93 Å. In the nineteenth C site, C(31) is bonded in a trigonal planar geometry to one C(29), one C(30), and one C(32) atom. The C(31)-C(32) bond length is 1.38 Å. In the twentieth C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(26) atom. The C(32)-H(26) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one C(12) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(17), and one C(18) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(22), and one C(23) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(22), one C(28), and one C(29) atom. There are thirteen inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(14,15) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(22) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(23) is bonded in a single-bond geometry to one C(29) atom. In the eleventh H site, H(24) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(25) is bonded in a single-bond geometry to one C(30) atom. In the thirteenth H site, H(26) is bonded in a single-bond geometry to one C(32) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one Cd(1) and one C(1) atom. In the second O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(10) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(10) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(1) atom. Linkers: 6 c1ccc2c(c1)ncn2Cc1ccc(Cn2cnc3ccccc32)cc1 ,2 [O]C(=O)Cc1cccc(CC([O])=O)c1. Metal clusters: 1 O=[C]O[Cd]1O[C]O1.O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 5.17 A, density 1.17 g/cm3, surface area 4853.73 m2/g, accessible volume 0.35 cm3/g