(ZnC8H4O4)3(CH)4(C3H2)8(C7NH2)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules; sixteen 2,3-dimethyl-1,3-butadiene molecules; eight pyrrole, 1,3,4-trimethyl- molecules; and four ZnC8H4O4 clusters. In each ZnC8H4O4 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted single-bond geometry to one O(1) and one O(5) atom. The Zn(1)-O(1) bond length is 1.98 Å. The Zn(1)-O(5) bond length is 1.95 Å. In the second Zn site, Zn(2) is bonded in an octahedral geometry to two equivalent O(2), two equivalent O(4), and two equivalent O(6) atoms. Both Zn(2)-O(2) bond lengths are 2.05 Å. Both Zn(2)-O(4) bond lengths are 2.09 Å. Both Zn(2)-O(6) bond lengths are 2.02 Å. There are twelve inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(1) bond length is 1.49 Å. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(7) bond length is 1.39 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-O(1) bond length is 1.24 Å. The C(1)-O(2) bond length is 1.21 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(26) atom. The C(23)-C(22) bond length is 1.40 Å. The C(23)-C(24) bond length is 1.35 Å. The C(23)-C(26) bond length is 1.50 Å. In the sixth C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(12) atom. The C(22)-H(12) bond length is 0.93 Å. In the seventh C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(13) atom. The C(24)-H(13) bond length is 0.93 Å. In the eighth C site, C(26) is bonded in a bent 120 degrees geometry to one C(23), one O(3), and one O(4) atom. The C(26)-O(3) bond length is 1.25 Å. The C(26)-O(4) bond length is 1.25 Å. In the ninth C site, C(29) is bonded in a distorted single-bond geometry to one C(30) and one H(16) atom. The C(29)-C(30) bond length is 1.38 Å. The C(29)-H(16) bond length is 0.93 Å. In the tenth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(33) atom. The C(30)-C(31) bond length is 1.38 Å. The C(30)-C(33) bond length is 1.50 Å. In the eleventh C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(17) atom. The C(31)-H(17) bond length is 0.93 Å. In the twelfth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(5), and one O(6) atom. The C(33)-O(5) bond length is 1.27 Å. The C(33)-O(6) bond length is 1.25 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(24) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(29) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(31) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Zn(2) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(26) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(26) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(33) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(33) atom. Linkers: 8 [O]C(=O)c1ccc(-c2ccc3c4ccc(-c5ccc(C([O])=O)cc5)cc4n(-c4ccc(C([O])=O)cc4)c3c2)cc1. Metal clusters: 4 [C]1O[Zn]2O[C]O[Zn]34(O1)(O[C]O2)O[C]O[Zn](O[C]O3)O[C]O4. The MOF has largest included sphere 8.53 A, density 0.85 g/cm3, surface area 4398.05 m2/g, accessible volume 0.66 cm3/g