CdH8(C2N)4(C7H4F2)4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen C7H4F2 clusters and four CdH8(C2N)4 clusters. In each C7H4F2 cluster, there are seven inequivalent C sites. In the first C site, C(12) is bonded in a distorted single-bond geometry to one C(14) and one H(3) atom. The C(12)-C(14) bond length is 1.38 Å. The C(12)-H(3) bond length is 0.95 Å. In the second C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(4) atom. The C(13)-C(14) bond length is 1.37 Å. The C(13)-H(4) bond length is 0.95 Å. In the third C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(15) atom. The C(14)-C(15) bond length is 1.52 Å. In the fourth C site, C(15) is bonded in a water-like geometry to one C(14), one C(16), one H(11), and one H(12) atom. The C(15)-C(16) bond length is 1.51 Å. The C(15)-H(11) bond length is 1.02 Å. The C(15)-H(12) bond length is 0.99 Å. In the fifth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-C(18) bond length is 1.39 Å. In the sixth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one F(3) atom. The C(17)-F(3) bond length is 1.35 Å. In the seventh C site, C(18) is bonded in a single-bond geometry to one C(16) and one F(4) atom. The C(18)-F(4) bond length is 1.34 Å. There are four inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. There are two inequivalent F sites. In the first F site, F(3) is bonded in a single-bond geometry to one C(17) atom. In the second F site, F(4) is bonded in a single-bond geometry to one C(18) atom. In each CdH8(C2N)4 cluster, Cd(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Cd(1)-N(1) bond lengths are 2.35 Å. Both Cd(1)-N(2) bond lengths are 2.37 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(5) bond length is 0.96 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-H(6) bond length is 0.87 Å. In the third C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(1) bond length is 0.95 Å. In the fourth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2) atom. The C(11)-N(2) bond length is 1.32 Å. The C(11)-H(2) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(11) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(2) atom. Linkers: 6 Fc1c(F)c(Cc2ccncc2)c(F)c(F)c1Cc1ccncc1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 4.67 A, density 1.08 g/cm3, surface area 4697.25 m2/g, accessible volume 0.53 cm3/g