(Cu2C8N2H10O3)2(CH)4C9H8O4 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; two 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and two Cu2C8N2H10O3 clusters. In each Cu2C8N2H10O3 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a T-shaped geometry to one N(2), one O(1), and one O(5) atom. The Cu(1)-N(2) bond length is 1.99 Å. The Cu(1)-O(1) bond length is 1.96 Å. The Cu(1)-O(5) bond length is 2.22 Å. In the second Cu site, Cu(2) is bonded in a rectangular see-saw-like geometry to one N(1), one O(4), and two equivalent O(1) atoms. The Cu(2)-N(1) bond length is 1.98 Å. The Cu(2)-O(4) bond length is 1.92 Å. There is one shorter (1.94 Å) and one longer (1.98 Å) Cu(2)-O(1) bond length. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(2) bond length is 0.93 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(11) and one H(5) atom. The C(4)-C(11) bond length is 1.37 Å. The C(4)-H(5) bond length is 0.93 Å. In the third C site, C(7) is bonded in a distorted trigonal planar geometry to one C(14), one O(4), and one O(5) atom. The C(7)-C(14) bond length is 1.50 Å. The C(7)-O(4) bond length is 1.28 Å. The C(7)-O(5) bond length is 1.23 Å. In the fourth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(9) atom. The C(8)-C(9) bond length is 1.37 Å. The C(8)-N(2) bond length is 1.33 Å. The C(8)-H(9) bond length is 0.93 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(10) atom. The C(9)-H(10) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one H(11) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(11) bond length is 0.93 Å. In the seventh C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(13)-N(1) bond length is 1.34 Å. The C(13)-H(13) bond length is 0.93 Å. In the eighth C site, C(14) is bonded in a trigonal non-coplanar geometry to one C(7); one H(14); and two equivalent H(15,16) atoms. The C(14)-H(14) bond length is 0.96 Å. Both C(14)-H(15,16) bond lengths are 0.96 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(2), one C(1), and one C(13) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(8) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.98 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(15,16) is bonded in a single-bond geometry to one C(14) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded to one Cu(1), two equivalent Cu(2), and one H(1) atom to form distorted edge-sharing OCu3H tetrahedra. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(7) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(7) atom. Linkers: 2 c1cc(OCC(COc2ccncc2)(COc2ccncc2)COc2ccncc2)ccn1. Metal clusters: 2 C[C](O[Cu])O[Cu]O.C[C](O[Cu])O[Cu]O. The MOF has largest included sphere 6.14 A, density 0.94 g/cm3, surface area 4464.52 m2/g, accessible volume 0.62 cm3/g