Zn8C131H84(N15O16)2(CH)8 crystallizes in the triclinic P-1 space group. The structure consists of sixteen 02329_fluka molecules inside a Zn8C131H84(N15O16)2 framework. In each Zn8C131H84(N15O16)2 framework, there are eight inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one N(13), one N(19), one O(16), and one O(23) atom. The Zn(1)-N(13) bond length is 1.99 Å. The Zn(1)-N(19) bond length is 2.00 Å. The Zn(1)-O(16) bond length is 1.93 Å. The Zn(1)-O(23) bond length is 1.95 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one N(24), one N(25), one O(1), and one O(5) atom. The Zn(2)-N(24) bond length is 2.04 Å. The Zn(2)-N(25) bond length is 1.99 Å. The Zn(2)-O(1) bond length is 1.95 Å. The Zn(2)-O(5) bond length is 2.03 Å. In the third Zn site, Zn(3) is bonded in a tetrahedral geometry to one N(16), one N(4), one O(27), and one O(4) atom. The Zn(3)-N(16) bond length is 1.97 Å. The Zn(3)-N(4) bond length is 2.00 Å. The Zn(3)-O(27) bond length is 1.94 Å. The Zn(3)-O(4) bond length is 1.91 Å. In the fourth Zn site, Zn(4) is bonded in a tetrahedral geometry to one N(22), one N(28), one O(14), and one O(9) atom. The Zn(4)-N(22) bond length is 2.02 Å. The Zn(4)-N(28) bond length is 2.01 Å. The Zn(4)-O(14) bond length is 1.94 Å. The Zn(4)-O(9) bond length is 1.99 Å. In the fifth Zn site, Zn(5) is bonded in a tetrahedral geometry to one N(17), one N(30), one O(12), and one O(19) atom. The Zn(5)-N(17) bond length is 2.13 Å. The Zn(5)-N(30) bond length is 2.00 Å. The Zn(5)-O(12) bond length is 1.95 Å. The Zn(5)-O(19) bond length is 1.96 Å. In the sixth Zn site, Zn(6) is bonded in a tetrahedral geometry to one N(6), one N(7), one O(17), and one O(21) atom. The Zn(6)-N(6) bond length is 2.05 Å. The Zn(6)-N(7) bond length is 1.98 Å. The Zn(6)-O(17) bond length is 2.00 Å. The Zn(6)-O(21) bond length is 1.92 Å. In the seventh Zn site, Zn(7) is bonded in a trigonal non-coplanar geometry to one N(9), one O(29), and one O(7) atom. The Zn(7)-N(9) bond length is 1.97 Å. The Zn(7)-O(29) bond length is 1.95 Å. The Zn(7)-O(7) bond length is 1.92 Å. In the eighth Zn site, Zn(8) is bonded in a tetrahedral geometry to one N(1), one N(11), one O(25), and one O(31) atom. The Zn(8)-N(1) bond length is 1.99 Å. The Zn(8)-N(11) bond length is 2.00 Å. The Zn(8)-O(25) bond length is 1.93 Å. The Zn(8)-O(31) bond length is 1.96 Å. There are one hundred and thirty-one inequivalent C sites. In the first C site, C(43) is bonded in a trigonal planar geometry to one N(17), one N(18), and one H(34) atom. The C(43)-N(17) bond length is 1.27 Å. The C(43)-N(18) bond length is 1.41 Å. The C(43)-H(34) bond length is 0.96 Å. In the second C site, C(44) is bonded in a distorted bent 120 degrees geometry to one N(18) and one H(35) atom. The C(44)-N(18) bond length is 1.35 Å. The C(44)-H(35) bond length is 0.96 Å. In the third C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(1) atom. The C(1)-C(2) bond length is 1.36 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-H(1) bond length is 0.93 Å. In the fourth C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(3) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(3) bond length is 1.41 Å. In the fifth C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(2) atom. The C(3)-C(4) bond length is 1.37 Å. The C(3)-H(2) bond length is 0.93 Å. In the sixth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-N(2) bond length is 1.43 Å. In the seventh C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(3) atom. The C(5)-C(6) bond length is 1.37 Å. The C(5)-H(3) bond length is 0.93 Å. In the eighth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one N(5) atom. The C(6)-N(5) bond length is 1.46 Å. In the ninth C site, C(7) is bonded in a 3-coordinate geometry to one C(8), one N(3), and one H(4) atom. The C(7)-C(8) bond length is 1.33 Å. The C(7)-N(3) bond length is 1.38 Å. The C(7)-H(4) bond length is 0.93 Å. In the tenth C site, C(9) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(6) atom. The C(9)-N(3) bond length is 1.31 Å. The C(9)-N(4) bond length is 1.31 Å. The C(9)-H(6) bond length is 0.93 Å. In the eleventh C site, C(10) is bonded in a 2-coordinate geometry to one C(11), one N(5), and one H(7) atom. The C(10)-C(11) bond length is 1.35 Å. The C(10)-N(5) bond length is 1.53 Å. The C(10)-H(7) bond length is 0.96 Å. In the twelfth C site, C(11) is bonded in a 3-coordinate geometry to one C(10), one N(6), and one H(8) atom. The C(11)-N(6) bond length is 1.53 Å. The C(11)-H(8) bond length is 0.96 Å. In the thirteenth C site, C(12) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(9) atom. The C(12)-N(5) bond length is 1.27 Å. The C(12)-N(6) bond length is 1.27 Å. The C(12)-H(9) bond length is 0.93 Å. In the fourteenth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one N(4), and one H(5) atom. The C(8)-N(4) bond length is 1.35 Å. The C(8)-H(5) bond length is 0.93 Å. In the fifteenth C site, C(14) is bonded in a 3-coordinate geometry to one C(13), one N(2), and one H(11) atom. The C(14)-C(13) bond length is 1.30 Å. The C(14)-N(2) bond length is 1.41 Å. The C(14)-H(11) bond length is 0.93 Å. In the sixteenth C site, C(15) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(12) atom. The C(15)-N(1) bond length is 1.32 Å. The C(15)-N(2) bond length is 1.34 Å. The C(15)-H(12) bond length is 0.93 Å. In the seventeenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17), one C(21), and one H(13) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-C(21) bond length is 1.40 Å. The C(16)-H(13) bond length is 0.93 Å. In the eighteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one N(10) atom. The C(17)-C(18) bond length is 1.36 Å. The C(17)-N(10) bond length is 1.42 Å. In the nineteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(14) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(14) bond length is 0.93 Å. In the twentieth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one N(12) atom. The C(19)-C(20) bond length is 1.42 Å. The C(19)-N(12) bond length is 1.41 Å. In the twenty-first C site, C(20) is bonded in a single-bond geometry to one C(19), one C(21), and one H(15) atom. The C(20)-C(21) bond length is 1.37 Å. The C(20)-H(15) bond length is 0.93 Å. In the twenty-second C site, C(21) is bonded in a distorted trigonal planar geometry to one C(16), one C(20), and one N(8) atom. The C(21)-N(8) bond length is 1.42 Å. In the twenty-third C site, C(22) is bonded in a trigonal planar geometry to one N(10), one N(9), and one H(16) atom. The C(22)-N(10) bond length is 1.35 Å. The C(22)-N(9) bond length is 1.33 Å. The C(22)-H(16) bond length is 0.93 Å. In the twenty-fourth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(1), and one H(10) atom. The C(13)-N(1) bond length is 1.39 Å. The C(13)-H(10) bond length is 0.93 Å. In the twenty-fifth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(18) atom. The C(24)-N(10) bond length is 1.38 Å. The C(24)-H(18) bond length is 0.93 Å. In the twenty-sixth C site, C(25) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(19) atom. The C(25)-N(7) bond length is 1.32 Å. The C(25)-N(8) bond length is 1.36 Å. The C(25)-H(19) bond length is 0.93 Å. In the twenty-seventh C site, C(26) is bonded in a distorted trigonal planar geometry to one C(27), one N(7), and one H(20) atom. The C(26)-C(27) bond length is 1.37 Å. The C(26)-N(7) bond length is 1.37 Å. The C(26)-H(20) bond length is 0.93 Å. In the twenty-eighth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(26), one N(8), and one H(21) atom. The C(27)-N(8) bond length is 1.42 Å. The C(27)-H(21) bond length is 0.93 Å. In the twenty-ninth C site, C(28) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(22) atom. The C(28)-N(11) bond length is 1.35 Å. The C(28)-N(12) bond length is 1.39 Å. The C(28)-H(22) bond length is 0.93 Å. In the thirtieth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(30), one N(12), and one H(23) atom. The C(29)-C(30) bond length is 1.35 Å. The C(29)-N(12) bond length is 1.37 Å. The C(29)-H(23) bond length is 0.93 Å. In the thirty-first C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(29), one N(11), and one H(24) atom. The C(30)-N(11) bond length is 1.36 Å. The C(30)-H(24) bond length is 0.93 Å. In the thirty-second C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(17) atom. The C(23)-N(9) bond length is 1.38 Å. The C(23)-H(17) bond length is 0.93 Å. In the thirty-third C site, C(32) is bonded in a single-bond geometry to one N(18) atom. The C(32)-N(18) bond length is 1.39 Å. In the thirty-fourth C site, C(34) is bonded in a single-bond geometry to one N(15) atom. The C(34)-N(15) bond length is 1.40 Å. In the thirty-fifth C site, C(36) is bonded in a distorted single-bond geometry to one N(14) atom. The C(36)-N(14) bond length is 1.43 Å. In the thirty-sixth C site, C(37) is bonded in a trigonal planar geometry to one N(13), one N(14), and one H(28) atom. The C(37)-N(13) bond length is 1.31 Å. The C(37)-N(14) bond length is 1.29 Å. The C(37)-H(28) bond length is 0.93 Å. In the thirty-seventh C site, C(38) is bonded in a 3-coordinate geometry to one C(39), one N(14), and one H(29) atom. The C(38)-C(39) bond length is 1.37 Å. The C(38)-N(14) bond length is 1.52 Å. The C(38)-H(29) bond length is 0.93 Å. In the thirty-eighth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one C(38), one N(13), and one H(30) atom. The C(39)-N(13) bond length is 1.47 Å. The C(39)-H(30) bond length is 0.93 Å. In the thirty-ninth C site, C(40) is bonded in a trigonal planar geometry to one N(15), one N(16), and one H(31) atom. The C(40)-N(15) bond length is 1.35 Å. The C(40)-N(16) bond length is 1.32 Å. The C(40)-H(31) bond length is 0.93 Å. In the fortieth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(15) and one H(32) atom. The C(41)-N(15) bond length is 1.34 Å. The C(41)-H(32) bond length is 0.93 Å. In the forty-first C site, C(42) is bonded in a distorted bent 120 degrees geometry to one N(16) and one H(33) atom. The C(42)-N(16) bond length is 1.39 Å. The C(42)-H(33) bond length is 0.93 Å. In the forty-second C site, C(46) is bonded in a distorted single-bond geometry to one C(47), one C(51), and one H(37) atom. The C(46)-C(47) bond length is 1.37 Å. The C(46)-C(51) bond length is 1.38 Å. The C(46)-H(37) bond length is 0.93 Å. In the forty-third C site, C(47) is bonded in a distorted trigonal planar geometry to one C(46), one C(48), and one N(21) atom. The C(47)-C(48) bond length is 1.42 Å. The C(47)-N(21) bond length is 1.43 Å. In the forty-fourth C site, C(48) is bonded in a distorted single-bond geometry to one C(47), one C(49), and one H(38) atom. The C(48)-C(49) bond length is 1.39 Å. The C(48)-H(38) bond length is 0.93 Å. In the forty-fifth C site, C(49) is bonded in a distorted trigonal planar geometry to one C(48), one C(50), and one N(23) atom. The C(49)-C(50) bond length is 1.36 Å. The C(49)-N(23) bond length is 1.45 Å. In the forty-sixth C site, C(50) is bonded in a distorted single-bond geometry to one C(49), one C(51), and one H(39) atom. The C(50)-C(51) bond length is 1.36 Å. The C(50)-H(39) bond length is 0.93 Å. In the forty-seventh C site, C(51) is bonded in a distorted trigonal planar geometry to one C(46), one C(50), and one N(20) atom. The C(51)-N(20) bond length is 1.45 Å. In the forty-eighth C site, C(52) is bonded in a trigonal planar geometry to one N(19), one N(20), and one H(40) atom. The C(52)-N(19) bond length is 1.29 Å. The C(52)-N(20) bond length is 1.33 Å. The C(52)-H(40) bond length is 0.93 Å. In the forty-ninth C site, C(53) is bonded in a 3-coordinate geometry to one C(54), one N(20), and one H(41) atom. The C(53)-C(54) bond length is 1.35 Å. The C(53)-N(20) bond length is 1.37 Å. The C(53)-H(41) bond length is 0.93 Å. In the fiftieth C site, C(54) is bonded in a distorted trigonal planar geometry to one C(53), one N(19), and one H(42) atom. The C(54)-N(19) bond length is 1.36 Å. The C(54)-H(42) bond length is 0.93 Å. In the fifty-first C site, C(55) is bonded in a trigonal planar geometry to one N(21), one N(22), and one H(43) atom. The C(55)-N(21) bond length is 1.34 Å. The C(55)-N(22) bond length is 1.31 Å. The C(55)-H(43) bond length is 0.93 Å. In the fifty-second C site, C(56) is bonded in a distorted trigonal planar geometry to one C(57), one N(22), and one H(44) atom. The C(56)-C(57) bond length is 1.32 Å. The C(56)-N(22) bond length is 1.36 Å. The C(56)-H(44) bond length is 0.93 Å. In the fifty-third C site, C(57) is bonded in a 3-coordinate geometry to one C(56), one N(21), and one H(45) atom. The C(57)-N(21) bond length is 1.36 Å. The C(57)-H(45) bond length is 0.93 Å. In the fifty-fourth C site, C(58) is bonded in a trigonal planar geometry to one N(23), one N(24), and one H(46) atom. The C(58)-N(23) bond length is 1.33 Å. The C(58)-N(24) bond length is 1.31 Å. The C(58)-H(46) bond length is 0.93 Å. In the fifty-fifth C site, C(59) is bonded in a distorted bent 120 degrees geometry to one C(60), one N(23), and one H(47) atom. The C(59)-C(60) bond length is 1.34 Å. The C(59)-N(23) bond length is 1.37 Å. The C(59)-H(47) bond length is 0.93 Å. In the fifty-sixth C site, C(60) is bonded in a distorted trigonal planar geometry to one C(59), one N(24), and one H(48) atom. The C(60)-N(24) bond length is 1.39 Å. The C(60)-H(48) bond length is 0.93 Å. In the fifty-seventh C site, C(61) is bonded in a distorted single-bond geometry to one N(29) atom. The C(61)-N(29) bond length is 1.43 Å. In the fifty-eighth C site, C(62) is bonded in a distorted single-bond geometry to one C(63) and one H(49) atom. The C(62)-C(63) bond length is 1.39 Å. The C(62)-H(49) bond length is 0.93 Å. In the fifty-ninth C site, C(63) is bonded in a distorted trigonal planar geometry to one C(62), one C(64), and one N(27) atom. The C(63)-C(64) bond length is 1.38 Å. The C(63)-N(27) bond length is 1.43 Å. In the sixtieth C site, C(64) is bonded in a single-bond geometry to one C(63), one C(65), and one H(50) atom. The C(64)-C(65) bond length is 1.40 Å. The C(64)-H(50) bond length is 0.93 Å. In the sixty-first C site, C(65) is bonded in a distorted trigonal planar geometry to one C(64), one C(66), and one N(26) atom. The C(65)-C(66) bond length is 1.39 Å. The C(65)-N(26) bond length is 1.41 Å. In the sixty-second C site, C(66) is bonded in a distorted single-bond geometry to one C(65) and one H(51) atom. The C(66)-H(51) bond length is 0.93 Å. In the sixty-third C site, C(67) is bonded in a 3-coordinate geometry to one C(68), one N(29), and one H(52) atom. The C(67)-C(68) bond length is 1.36 Å. The C(67)-N(29) bond length is 1.39 Å. The C(67)-H(52) bond length is 0.93 Å. In the sixty-fourth C site, C(68) is bonded in a distorted bent 120 degrees geometry to one C(67), one N(30), and one H(53) atom. The C(68)-N(30) bond length is 1.39 Å. The C(68)-H(53) bond length is 0.93 Å. In the sixty-fifth C site, C(69) is bonded in a trigonal planar geometry to one N(29), one N(30), and one H(54) atom. The C(69)-N(29) bond length is 1.34 Å. The C(69)-N(30) bond length is 1.32 Å. The C(69)-H(54) bond length is 0.93 Å. In the sixty-sixth C site, C(70) is bonded in a trigonal planar geometry to one N(25), one N(26), and one H(55) atom. The C(70)-N(25) bond length is 1.29 Å. The C(70)-N(26) bond length is 1.33 Å. The C(70)-H(55) bond length is 0.93 Å. In the sixty-seventh C site, C(71) is bonded in a 2-coordinate geometry to one C(72), one N(26), and one H(56) atom. The C(71)-C(72) bond length is 1.39 Å. The C(71)-N(26) bond length is 1.39 Å. The C(71)-H(56) bond length is 0.93 Å. In the sixty-eighth C site, C(72) is bonded in a distorted trigonal planar geometry to one C(71), one N(25), and one H(57) atom. The C(72)-N(25) bond length is 1.35 Å. The C(72)-H(57) bond length is 0.93 Å. In the sixty-ninth C site, C(73) is bonded in a trigonal planar geometry to one N(27), one N(28), and one H(58) atom. The C(73)-N(27) bond length is 1.36 Å. The C(73)-N(28) bond length is 1.34 Å. The C(73)-H(58) bond length is 0.93 Å. In the seventieth C site, C(74) is bonded in a distorted bent 120 degrees geometry to one C(75), one N(28), and one H(59) atom. The C(74)-C(75) bond length is 1.33 Å. The C(74)-N(28) bond length is 1.34 Å. The C(74)-H(59) bond length is 0.93 Å. In the seventy-first C site, C(75) is bonded in a 3-coordinate geometry to one C(74), one N(27), and one H(60) atom. The C(75)-N(27) bond length is 1.39 Å. The C(75)-H(60) bond length is 0.93 Å. In the seventy-second C site, C(76) is bonded in a distorted bent 120 degrees geometry to one C(77), one O(25), and one O(26) atom. The C(76)-C(77) bond length is 1.50 Å. The C(76)-O(25) bond length is 1.30 Å. The C(76)-O(26) bond length is 1.24 Å. In the seventy-third C site, C(77) is bonded in a trigonal planar geometry to one C(76), one C(78), and one C(83) atom. The C(77)-C(78) bond length is 1.42 Å. The C(77)-C(83) bond length is 1.39 Å. In the seventy-fourth C site, C(81) is bonded in a trigonal planar geometry to one C(80), one C(82), and one C(83) atom. The C(81)-C(80) bond length is 1.40 Å. The C(81)-C(82) bond length is 1.49 Å. The C(81)-C(83) bond length is 1.40 Å. In the seventy-fifth C site, C(82) is bonded in a distorted bent 120 degrees geometry to one C(81), one O(27), and one O(28) atom. The C(82)-O(27) bond length is 1.27 Å. The C(82)-O(28) bond length is 1.20 Å. In the seventy-sixth C site, C(83) is bonded in a distorted single-bond geometry to one C(77), one C(81), and one H(64) atom. The C(83)-H(64) bond length is 0.93 Å. In the seventy-seventh C site, C(84) is bonded in a distorted bent 120 degrees geometry to one C(85), one O(31), and one O(32) atom. The C(84)-C(85) bond length is 1.48 Å. The C(84)-O(31) bond length is 1.28 Å. The C(84)-O(32) bond length is 1.27 Å. In the seventy-eighth C site, C(85) is bonded in a trigonal planar geometry to one C(84), one C(86), and one C(90) atom. The C(85)-C(86) bond length is 1.41 Å. The C(85)-C(90) bond length is 1.40 Å. In the seventy-ninth C site, C(80) is bonded in a distorted single-bond geometry to one C(81) and one H(63) atom. The C(80)-H(63) bond length is 0.93 Å. In the eightieth C site, C(89) is bonded in a trigonal planar geometry to one C(88), one C(90), and one C(91) atom. The C(89)-C(88) bond length is 1.37 Å. The C(89)-C(90) bond length is 1.41 Å. The C(89)-C(91) bond length is 1.50 Å. In the eighty-first C site, C(91) is bonded in a distorted bent 120 degrees geometry to one C(89), one O(29), and one O(30) atom. The C(91)-O(29) bond length is 1.28 Å. The C(91)-O(30) bond length is 1.24 Å. In the eighty-second C site, C(92) is bonded in a bent 120 degrees geometry to one C(93), one O(17), and one O(18) atom. The C(92)-C(93) bond length is 1.47 Å. The C(92)-O(17) bond length is 1.24 Å. The C(92)-O(18) bond length is 1.27 Å. In the eighty-third C site, C(93) is bonded in a trigonal planar geometry to one C(92), one C(94), and one C(98) atom. The C(93)-C(94) bond length is 1.36 Å. The C(93)-C(98) bond length is 1.38 Å. In the eighty-fourth C site, C(94) is bonded in a distorted single-bond geometry to one C(93) and one H(69) atom. The C(94)-H(69) bond length is 0.93 Å. In the eighty-fifth C site, C(96) is bonded in a distorted single-bond geometry to one C(97) and one H(71) atom. The C(96)-C(97) bond length is 1.35 Å. The C(96)-H(71) bond length is 0.93 Å. In the eighty-sixth C site, C(97) is bonded in a trigonal planar geometry to one C(96), one C(98), and one C(99) atom. The C(97)-C(98) bond length is 1.45 Å. The C(97)-C(99) bond length is 1.48 Å. In the eighty-seventh C site, C(98) is bonded in a distorted single-bond geometry to one C(93), one C(97), and one H(72) atom. The C(98)-H(72) bond length is 0.93 Å. In the eighty-eighth C site, C(99) is bonded in a distorted bent 120 degrees geometry to one C(97), one O(19), and one O(20) atom. The C(99)-O(19) bond length is 1.31 Å. The C(99)-O(20) bond length is 1.24 Å. In the eighty-ninth C site, C(100) is bonded in a distorted bent 120 degrees geometry to one C(101), one O(21), and one O(22) atom. The C(100)-C(101) bond length is 1.53 Å. The C(100)-O(21) bond length is 1.28 Å. The C(100)-O(22) bond length is 1.20 Å. In the ninetieth C site, C(101) is bonded in a trigonal planar geometry to one C(100), one C(102), and one C(106) atom. The C(101)-C(102) bond length is 1.39 Å. The C(101)-C(106) bond length is 1.37 Å. In the ninety-first C site, C(102) is bonded in a distorted single-bond geometry to one C(101) and one H(73) atom. The C(102)-H(73) bond length is 0.93 Å. In the ninety-second C site, C(104) is bonded in a distorted single-bond geometry to one C(105) and one H(75) atom. The C(104)-C(105) bond length is 1.36 Å. The C(104)-H(75) bond length is 0.93 Å. In the ninety-third C site, C(105) is bonded in a trigonal planar geometry to one C(104), one C(106), and one C(107) atom. The C(105)-C(106) bond length is 1.43 Å. The C(105)-C(107) bond length is 1.49 Å. In the ninety-fourth C site, C(106) is bonded in a single-bond geometry to one C(101), one C(105), and one H(76) atom. The C(106)-H(76) bond length is 0.93 Å. In the ninety-fifth C site, C(107) is bonded in a bent 120 degrees geometry to one C(105), one O(23), and one O(24) atom. The C(107)-O(23) bond length is 1.29 Å. The C(107)-O(24) bond length is 1.22 Å. In the ninety-sixth C site, C(108) is bonded in a distorted bent 120 degrees geometry to one C(109), one O(5), and one O(6) atom. The C(108)-C(109) bond length is 1.58 Å. The C(108)-O(5) bond length is 1.21 Å. The C(108)-O(6) bond length is 1.31 Å. In the ninety-seventh C site, C(109) is bonded in a trigonal planar geometry to one C(108), one C(110), and one C(114) atom. The C(109)-C(110) bond length is 1.40 Å. The C(109)-C(114) bond length is 1.39 Å. In the ninety-eighth C site, C(110) is bonded in a distorted single-bond geometry to one C(109) and one H(77) atom. The C(110)-H(77) bond length is 0.93 Å. In the ninety-ninth C site, C(112) is bonded in a distorted single-bond geometry to one C(113) and one H(79) atom. The C(112)-C(113) bond length is 1.39 Å. The C(112)-H(79) bond length is 0.93 Å. In the one hundredth C site, C(113) is bonded in a trigonal planar geometry to one C(112), one C(114), and one C(115) atom. The C(113)-C(114) bond length is 1.34 Å. The C(113)-C(115) bond length is 1.46 Å. In the one hundred and first C site, C(114) is bonded in a distorted single-bond geometry to one C(109), one C(113), and one H(80) atom. The C(114)-H(80) bond length is 0.93 Å. In the one hundred and second C site, C(115) is bonded in a distorted bent 120 degrees geometry to one C(113), one O(7), and one O(8) atom. The C(115)-O(7) bond length is 1.30 Å. The C(115)-O(8) bond length is 1.23 Å. In the one hundred and third C site, C(116) is bonded in a bent 120 degrees geometry to one C(117), one O(1), and one O(2) atom. The C(116)-C(117) bond length is 1.48 Å. The C(116)-O(1) bond length is 1.32 Å. The C(116)-O(2) bond length is 1.20 Å. In the one hundred and fourth C site, C(117) is bonded in a trigonal planar geometry to one C(116), one C(118), and one C(122) atom. The C(117)-C(118) bond length is 1.36 Å. The C(117)-C(122) bond length is 1.38 Å. In the one hundred and fifth C site, C(118) is bonded in a distorted single-bond geometry to one C(117) and one H(81) atom. The C(118)-H(81) bond length is 0.93 Å. In the one hundred and sixth C site, C(120) is bonded in a distorted single-bond geometry to one C(121) and one H(83) atom. The C(120)-C(121) bond length is 1.37 Å. The C(120)-H(83) bond length is 0.93 Å. In the one hundred and seventh C site, C(121) is bonded in a trigonal planar geometry to one C(120), one C(122), and one C(123) atom. The C(121)-C(122) bond length is 1.38 Å. The C(121)-C(123) bond length is 1.46 Å. In the one hundred and eighth C site, C(122) is bonded in a single-bond geometry to one C(117), one C(121), and one H(84) atom. The C(122)-H(84) bond length is 0.93 Å. In the one hundred and ninth C site, C(123) is bonded in a bent 120 degrees geometry to one C(121), one O(3), and one O(4) atom. The C(123)-O(3) bond length is 1.23 Å. The C(123)-O(4) bond length is 1.27 Å. In the one hundred and tenth C site, C(124) is bonded in a distorted bent 120 degrees geometry to one C(125), one O(13), and one O(14) atom. The C(124)-C(125) bond length is 1.51 Å. The C(124)-O(13) bond length is 1.22 Å. The C(124)-O(14) bond length is 1.27 Å. In the one hundred and eleventh C site, C(125) is bonded in a trigonal planar geometry to one C(124), one C(126), and one C(130) atom. The C(125)-C(126) bond length is 1.37 Å. The C(125)-C(130) bond length is 1.40 Å. In the one hundred and twelfth C site, C(126) is bonded in a distorted single-bond geometry to one C(125) and one H(85) atom. The C(126)-H(85) bond length is 0.93 Å. In the one hundred and thirteenth C site, C(127) is bonded in a distorted single-bond geometry to one C(128) and one H(86) atom. The C(127)-C(128) bond length is 1.34 Å. The C(127)-H(86) bond length is 0.93 Å. In the one hundred and fourteenth C site, C(128) is bonded in a distorted trigonal planar geometry to one C(127), one C(129), and one H(87) atom. The C(128)-C(129) bond length is 1.36 Å. The C(128)-H(87) bond length is 0.93 Å. In the one hundred and fifteenth C site, C(129) is bonded in a trigonal planar geometry to one C(128), one C(130), and one C(131) atom. The C(129)-C(130) bond length is 1.38 Å. The C(129)-C(131) bond length is 1.54 Å. In the one hundred and sixteenth C site, C(130) is bonded in a distorted single-bond geometry to one C(125), one C(129), and one H(88) atom. The C(130)-H(88) bond length is 0.93 Å. In the one hundred and seventeenth C site, C(131) is bonded in a bent 120 degrees geometry to one C(129), one O(15), and one O(16) atom. The C(131)-O(15) bond length is 1.22 Å. The C(131)-O(16) bond length is 1.26 Å. In the one hundred and eighteenth C site, C(132) is bonded in a distorted bent 120 degrees geometry to one C(133), one O(11), and one O(12) atom. The C(132)-C(133) bond length is 1.55 Å. The C(132)-O(11) bond length is 1.22 Å. The C(132)-O(12) bond length is 1.27 Å. In the one hundred and nineteenth C site, C(133) is bonded in a trigonal planar geometry to one C(132), one C(134), and one C(138) atom. The C(133)-C(134) bond length is 1.39 Å. The C(133)-C(138) bond length is 1.39 Å. In the one hundred and twentieth C site, C(134) is bonded in a distorted single-bond geometry to one C(133), one C(135), and one H(89) atom. The C(134)-C(135) bond length is 1.38 Å. The C(134)-H(89) bond length is 0.93 Å. In the one hundred and twenty-first C site, C(135) is bonded in a trigonal planar geometry to one C(134), one C(136), and one C(139) atom. The C(135)-C(136) bond length is 1.43 Å. The C(135)-C(139) bond length is 1.48 Å. In the one hundred and twenty-second C site, C(136) is bonded in a distorted single-bond geometry to one C(135), one C(137), and one H(90) atom. The C(136)-C(137) bond length is 1.34 Å. The C(136)-H(90) bond length is 0.93 Å. In the one hundred and twenty-third C site, C(137) is bonded in a distorted trigonal planar geometry to one C(136), one C(138), and one H(91) atom. The C(137)-C(138) bond length is 1.37 Å. The C(137)-H(91) bond length is 0.93 Å. In the one hundred and twenty-fourth C site, C(138) is bonded in a distorted single-bond geometry to one C(133), one C(137), and one H(92) atom. The C(138)-H(92) bond length is 0.93 Å. In the one hundred and twenty-fifth C site, C(139) is bonded in a distorted bent 120 degrees geometry to one C(135), one O(10), and one O(9) atom. The C(139)-O(10) bond length is 1.20 Å. The C(139)-O(9) bond length is 1.29 Å. In the one hundred and twenty-sixth C site, C(78) is bonded in a distorted single-bond geometry to one C(77) and one H(61) atom. The C(78)-H(61) bond length is 0.93 Å. In the one hundred and twenty-seventh C site, C(86) is bonded in a distorted single-bond geometry to one C(85) and one H(65) atom. The C(86)-H(65) bond length is 0.93 Å. In the one hundred and twenty-eighth C site, C(87) is bonded in a distorted single-bond geometry to one C(88) and one H(66) atom. The C(87)-C(88) bond length is 1.35 Å. The C(87)-H(66) bond length is 0.93 Å. In the one hundred and twenty-ninth C site, C(88) is bonded in a distorted trigonal planar geometry to one C(87), one C(89), and one H(67) atom. The C(88)-H(67) bond length is 0.93 Å. In the one hundred and thirtieth C site, C(90) is bonded in a distorted single-bond geometry to one C(85), one C(89), and one H(68) atom. The C(90)-H(68) bond length is 0.93 Å. In the one hundred and thirty-first C site, C(45) is bonded in a distorted bent 120 degrees geometry to one N(17) and one H(36) atom. The C(45)-N(17) bond length is 1.39 Å. The C(45)-H(36) bond length is 0.96 Å. There are thirty inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(8), one C(13), and one C(15) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(14), one C(15), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(2), one C(7), and one C(9) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(3), one C(8), and one C(9) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one C(6) atom. In the sixth N site, N(6) is bonded in a distorted trigonal non-coplanar geometry to one Zn(6), one C(11), and one C(12) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Zn(6), one C(25), and one C(26) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(27) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Zn(7), one C(22), and one C(23) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one C(17), one C(22), and one C(24) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Zn(8), one C(28), and one C(30) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one C(19), one C(28), and one C(29) atom. In the thirteenth N site, N(13) is bonded in a trigonal planar geometry to one Zn(1), one C(37), and one C(39) atom. In the fourteenth N site, N(14) is bonded in a trigonal planar geometry to one C(36), one C(37), and one C(38) atom. In the fifteenth N site, N(15) is bonded in a trigonal planar geometry to one C(34), one C(40), and one C(41) atom. In the sixteenth N site, N(16) is bonded in a trigonal planar geometry to one Zn(3), one C(40), and one C(42) atom. In the seventeenth N site, N(17) is bonded in a trigonal planar geometry to one Zn(5), one C(43), and one C(45) atom. In the eighteenth N site, N(18) is bonded in a trigonal planar geometry to one C(32), one C(43), and one C(44) atom. In the nineteenth N site, N(19) is bonded in a trigonal planar geometry to one Zn(1), one C(52), and one C(54) atom. In the twentieth N site, N(20) is bonded in a trigonal planar geometry to one C(51), one C(52), and one C(53) atom. In the twenty-first N site, N(21) is bonded in a trigonal planar geometry to one C(47), one C(55), and one C(57) atom. In the twenty-second N site, N(22) is bonded in a trigonal planar geometry to one Zn(4), one C(55), and one C(56) atom. In the twenty-third N site, N(23) is bonded in a trigonal planar geometry to one C(49), one C(58), and one C(59) atom. In the twenty-fourth N site, N(24) is bonded in a trigonal planar geometry to one Zn(2), one C(58), and one C(60) atom. In the twenty-fifth N site, N(25) is bonded in a trigonal planar geometry to one Zn(2), one C(70), and one C(72) atom. In the twenty-sixth N site, N(26) is bonded in a trigonal planar geometry to one C(65), one C(70), and one C(71) atom. In the twenty-seventh N site, N(27) is bonded in a trigonal planar geometry to one C(63), one C(73), and one C(75) atom. In the twenty-eighth N site, N(28) is bonded in a trigonal planar geometry to one Zn(4), one C(73), and one C(74) atom. In the twenty-ninth N site, N(29) is bonded in a trigonal planar geometry to one C(61), one C(67), and one C(69) atom. In the thirtieth N site, N(30) is bonded in a trigonal planar geometry to one Zn(5), one C(68), and one C(69) atom. There are eighty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(26) atom. In the seventeenth H site, H(28) is bonded in a single-bond geometry to one C(37) atom. In the eighteenth H site, H(29) is bonded in a single-bond geometry to one C(38) atom. In the nineteenth H site, H(30) is bonded in a single-bond geometry to one C(39) atom. In the twentieth H site, H(37) is bonded in a single-bond geometry to one C(46) atom. In the twenty-first H site, H(38) is bonded in a single-bond geometry to one C(48) atom. In the twenty-second H site, H(39) is bonded in a single-bond geometry to one C(50) atom. In the twenty-third H site, H(40) is bonded in a single-bond geometry to one C(52) atom. In the twenty-fourth H site, H(41) is bonded in a single-bond geometry to one C(53) atom. In the twenty-fifth H site, H(42) is bonded in a single-bond geometry to one C(54) atom. In the twenty-sixth H site, H(43) is bonded in a single-bond geometry to one C(55) atom. In the twenty-seventh H site, H(44) is bonded in a single-bond geometry to one C(56) atom. In the twenty-eighth H site, H(45) is bonded in a single-bond geometry to one C(57) atom. In the twenty-ninth H site, H(46) is bonded in a single-bond geometry to one C(58) atom. In the thirtieth H site, H(47) is bonded in a single-bond geometry to one C(59) atom. In the thirty-first H site, H(48) is bonded in a single-bond geometry to one C(60) atom. In the thirty-second H site, H(49) is bonded in a single-bond geometry to one C(62) atom. In the thirty-third H site, H(50) is bonded in a single-bond geometry to one C(64) atom. In the thirty-fourth H site, H(51) is bonded in a single-bond geometry to one C(66) atom. In the thirty-fifth H site, H(52) is bonded in a single-bond geometry to one C(67) atom. In the thirty-sixth H site, H(53) is bonded in a single-bond geometry to one C(68) atom. In the thirty-seventh H site, H(54) is bonded in a single-bond geometry to one C(69) atom. In the thirty-eighth H site, H(55) is bonded in a single-bond geometry to one C(70) atom. In the thirty-ninth H site, H(56) is bonded in a single-bond geometry to one C(71) atom. In the fortieth H site, H(57) is bonded in a single-bond geometry to one C(72) atom. In the forty-first H site, H(58) is bonded in a single-bond geometry to one C(73) atom. In the forty-second H site, H(59) is bonded in a single-bond geometry to one C(74) atom. In the forty-third H site, H(60) is bonded in a single-bond geometry to one C(75) atom. In the forty-fourth H site, H(61) is bonded in a single-bond geometry to one C(78) atom. In the forty-fifth H site, H(63) is bonded in a single-bond geometry to one C(80) atom. In the forty-sixth H site, H(64) is bonded in a single-bond geometry to one C(83) atom. In the forty-seventh H site, H(65) is bonded in a single-bond geometry to one C(86) atom. In the forty-eighth H site, H(66) is bonded in a single-bond geometry to one C(87) atom. In the forty-ninth H site, H(67) is bonded in a single-bond geometry to one C(88) atom. In the fiftieth H site, H(68) is bonded in a single-bond geometry to one C(90) atom. In the fifty-first H site, H(69) is bonded in a single-bond geometry to one C(94) atom. In the fifty-second H site, H(71) is bonded in a single-bond geometry to one C(96) atom. In the fifty-third H site, H(72) is bonded in a single-bond geometry to one C(98) atom. In the fifty-fourth H site, H(73) is bonded in a single-bond geometry to one C(102) atom. In the fifty-fifth H site, H(75) is bonded in a single-bond geometry to one C(104) atom. In the fifty-sixth H site, H(76) is bonded in a single-bond geometry to one C(106) atom. In the fifty-seventh H site, H(77) is bonded in a single-bond geometry to one C(110) atom. In the fifty-eighth H site, H(79) is bonded in a single-bond geometry to one C(112) atom. In the fifty-ninth H site, H(80) is bonded in a single-bond geometry to one C(114) atom. In the sixtieth H site, H(81) is bonded in a single-bond geometry to one C(118) atom. In the sixty-first H site, H(83) is bonded in a single-bond geometry to one C(120) atom. In the sixty-second H site, H(84) is bonded in a single-bond geometry to one C(122) atom. In the sixty-third H site, H(85) is bonded in a single-bond geometry to one C(126) atom. In the sixty-fourth H site, H(86) is bonded in a single-bond geometry to one C(127) atom. In the sixty-fifth H site, H(87) is bonded in a single-bond geometry to one C(128) atom. In the sixty-sixth H site, H(88) is bonded in a single-bond geometry to one C(130) atom. In the sixty-seventh H site, H(89) is bonded in a single-bond geometry to one C(134) atom. In the sixty-eighth H site, H(90) is bonded in a single-bond geometry to one C(136) atom. In the sixty-ninth H site, H(91) is bonded in a single-bond geometry to one C(137) atom. In the seventieth H site, H(92) is bonded in a single-bond geometry to one C(138) atom. In the seventy-first H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the seventy-second H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the seventy-third H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the seventy-fourth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In the seventy-fifth H site, H(21) is bonded in a single-bond geometry to one C(27) atom. In the seventy-sixth H site, H(22) is bonded in a single-bond geometry to one C(28) atom. In the seventy-seventh H site, H(23) is bonded in a single-bond geometry to one C(29) atom. In the seventy-eighth H site, H(24) is bonded in a single-bond geometry to one C(30) atom. In the seventy-ninth H site, H(31) is bonded in a single-bond geometry to one C(40) atom. In the eightieth H site, H(32) is bonded in a single-bond geometry to one C(41) atom. In the eighty-first H site, H(33) is bonded in a single-bond geometry to one C(42) atom. In the eighty-second H site, H(34) is bonded in a single-bond geometry to one C(43) atom. In the eighty-third H site, H(35) is bonded in a single-bond geometry to one C(44) atom. In the eighty-fourth H site, H(36) is bonded in a single-bond geometry to one C(45) atom. There are thirty-two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(116) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(116) atom. In the third O site, O(5) is bonded in a water-like geometry to one Zn(2) and one C(108) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(108) atom. In the fifth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(139) atom. In the sixth O site, O(10) is bonded in a single-bond geometry to one C(139) atom. In the seventh O site, O(13) is bonded in a single-bond geometry to one C(124) atom. In the eighth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(124) atom. In the ninth O site, O(15) is bonded in a single-bond geometry to one C(131) atom. In the tenth O site, O(16) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(131) atom. In the eleventh O site, O(17) is bonded in a water-like geometry to one Zn(6) and one C(92) atom. In the twelfth O site, O(21) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(100) atom. In the thirteenth O site, O(22) is bonded in a single-bond geometry to one C(100) atom. In the fourteenth O site, O(23) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(107) atom. In the fifteenth O site, O(24) is bonded in a single-bond geometry to one C(107) atom. In the sixteenth O site, O(18) is bonded in a single-bond geometry to one C(92) atom. In the seventeenth O site, O(19) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(99) atom. In the eighteenth O site, O(3) is bonded in a single-bond geometry to one C(123) atom. In the nineteenth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(123) atom. In the twentieth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(7) and one C(115) atom. In the twenty-first O site, O(8) is bonded in a single-bond geometry to one C(115) atom. In the twenty-second O site, O(11) is bonded in a single-bond geometry to one C(132) atom. In the twenty-third O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(132) atom. In the twenty-fourth O site, O(20) is bonded in a single-bond geometry to one C(99) atom. In the twenty-fifth O site, O(27) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(82) atom. In the twenty-sixth O site, O(26) is bonded in a single-bond geometry to one C(76) atom. In the twenty-seventh O site, O(28) is bonded in a single-bond geometry to one C(82) atom. In the twenty-eighth O site, O(29) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(91) atom. In the twenty-ninth O site, O(30) is bonded in a single-bond geometry to one C(91) atom. In the thirtieth O site, O(31) is bonded in a bent 120 degrees geometry to one Zn(8) and one C(84) atom. In the thirty-first O site, O(32) is bonded in a single-bond geometry to one C(84) atom. In the thirty-second O site, O(25) is bonded in a bent 120 degrees geometry to one Zn(8) and one C(76) atom. Linkers: 16 [O]C(=O)c1cccc(C([O])=O)c1 ,2 [CH]1[N]C=CN1c1cc(-n2ccnc2)cc(-n2ccnc2)c1 ,6 c1cn(-c2cc(-n3ccnc3)cc(-n3ccnc3)c2)cn1 ,2 [CH]1[N]C=CN1c1cc(N2[CH][N]C=C2)cc(-n2ccnc2)c1. Metal clusters: 14 O=[C]O[Zn]O[C]=O ,2 [O][C]O[Zn]O[C]=O. The MOF has largest included sphere 7.12 A, density 1.11 g/cm3, surface area 4682.30 m2/g, accessible volume 0.49 cm3/g