MnC12NH6O4CH crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a MnC12NH6O4 framework. In the MnC12NH6O4 framework, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one O(2), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. The Mn(1)-O(2) bond length is 2.10 Å. The Mn(1)-O(4) bond length is 2.08 Å. The Mn(1)-O(5) bond length is 2.23 Å. The Mn(1)-O(6) bond length is 2.22 Å. The Mn(1)-O(7) bond length is 2.22 Å. The Mn(1)-O(8) bond length is 2.37 Å. In the second Mn site, Mn(2) is bonded in a square pyramidal geometry to one N(1), one N(2), one O(1), one O(3), and one O(7) atom. The Mn(2)-N(1) bond length is 2.27 Å. The Mn(2)-N(2) bond length is 2.24 Å. The Mn(2)-O(1) bond length is 2.13 Å. The Mn(2)-O(3) bond length is 2.14 Å. The Mn(2)-O(7) bond length is 2.21 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.27 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-C(8) bond length is 1.51 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(2) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(2) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(12), one C(5), and one C(7) atom. The C(6)-C(12) bond length is 1.51 Å. The C(6)-C(7) bond length is 1.39 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(3) atom. The C(7)-H(3) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.25 Å. The C(8)-O(4) bond length is 1.25 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(14), and one H(4) atom. The C(9)-C(10) bond length is 1.36 Å. The C(9)-C(14) bond length is 1.40 Å. The C(9)-H(4) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(16), and one C(9) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(16) bond length is 1.50 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(5) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(5) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(6) atom. The C(12)-C(13) bond length is 1.37 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(6) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(6) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(9) atom. The C(14)-C(15) bond length is 1.48 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(5), and one O(6) atom. The C(15)-O(5) bond length is 1.26 Å. The C(15)-O(6) bond length is 1.26 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(7), and one O(8) atom. The C(16)-O(7) bond length is 1.29 Å. The C(16)-O(8) bond length is 1.24 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(18), one N(1), and one H(7) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-N(1) bond length is 1.32 Å. The C(17)-H(7) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(8) atom. The C(18)-H(8) bond length is 0.93 Å. In the nineteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(10) atom. The C(20)-C(21) bond length is 1.37 Å. The C(20)-H(10) bond length is 0.93 Å. In the twentieth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one C(22), and one N(1) atom. The C(21)-C(22) bond length is 1.47 Å. The C(21)-N(1) bond length is 1.36 Å. In the twenty-first C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one N(2) atom. The C(22)-C(23) bond length is 1.42 Å. The C(22)-N(2) bond length is 1.39 Å. In the twenty-second C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(11) atom. The C(23)-H(11) bond length is 0.93 Å. In the twenty-third C site, C(25) is bonded in a distorted single-bond geometry to one C(26) and one H(13) atom. The C(25)-C(26) bond length is 1.36 Å. The C(25)-H(13) bond length is 0.93 Å. In the twenty-fourth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one N(2), and one H(14) atom. The C(26)-N(2) bond length is 1.30 Å. The C(26)-H(14) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(2), one C(17), and one C(21) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(2), one C(22), and one C(26) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(26) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(2) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(8) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Mn(1) and one C(15) atom. In the sixth O site, O(6) is bonded in an L-shaped geometry to one Mn(1) and one C(15) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(2), and one C(16) atom. In the eighth O site, O(8) is bonded in a distorted L-shaped geometry to one Mn(1) and one C(16) atom. Linkers: 2 c1ccc(-c2ccccn2)nc1 ,4 [O]C(=O)c1cc(C([O])=O)cc(-c2cc(C([O])=O)cc(C([O])=O)c2)c1. Metal clusters: 4 [C]1O[Mn]2O[C]O[Mn]3(O1)(O[C]O2)O[C]O3. RCSR code: pts. The MOF has largest included sphere 4.96 A, density 1.16 g/cm3, surface area 4128.81 m2/g, accessible volume 0.43 cm3/g