Cu2C15H12(NO)6(CH)3 is Indium-derived structured and crystallizes in the hexagonal P6_322 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and two Cu2C15H12(NO)6 clusters. In each Cu2C15H12(NO)6 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 1.99 Å. Both Cu(1)-O(1) bond lengths are 2.00 Å. In the second Cu site, Cu(2) is bonded in an octahedral geometry to six equivalent O(2) atoms. All Cu(2)-O(2) bond lengths are 2.26 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(2) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(2) bond length is 0.95 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(3), one N(1), and one H(3) atom. The C(2)-C(3) bond length is 1.35 Å. The C(2)-N(1) bond length is 1.39 Å. The C(2)-H(3) bond length is 0.95 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(2) atom. The C(3)-C(4) bond length is 1.46 Å. The C(3)-N(2) bond length is 1.38 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(6)-O(1) bond length is 1.27 Å. The C(6)-O(2) bond length is 1.24 Å. In the fifth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(4)-H(4) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(1) atom. The N(2)-H(1) bond length is 0.88 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(6) atom. In the second O site, O(2) is bonded in a 2-coordinate geometry to one Cu(2) and one C(6) atom. Linkers: 12 [O]C(=O)/C=C/c1cnc[nH]1. Metal clusters: 2 [C]1O[Cu]O[C]O[Cu]23(O1)(O[C]O[Cu]O[C]O2)O[C]O[Cu]O[C]O3. The MOF has largest included sphere 4.61 A, density 1.55 g/cm3, surface area 4354.40 m2/g, accessible volume 0.24 cm3/g