(CoC13H11(NO2)2)2CH2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and four CoC13H11(NO2)2 clusters. In each CoC13H11(NO2)2 cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a trigonal bipyramidal geometry to one N(1), one O(1), one O(4), one O(6), and one O(7) atom. The Co(1)-N(1) bond length is 2.04 Å. The Co(1)-O(1) bond length is 2.05 Å. The Co(1)-O(4) bond length is 2.02 Å. The Co(1)-O(6) bond length is 2.05 Å. The Co(1)-O(7) bond length is 2.03 Å. In the second Co site, Co(2) is bonded in a distorted trigonal bipyramidal geometry to one N(4), one O(2), one O(3), one O(5), and one O(8) atom. The Co(2)-N(4) bond length is 2.06 Å. The Co(2)-O(2) bond length is 2.04 Å. The Co(2)-O(3) bond length is 2.05 Å. The Co(2)-O(5) bond length is 2.03 Å. The Co(2)-O(8) bond length is 2.05 Å. There are twenty-six inequivalent C sites. In the first C site, C(27) is bonded in a trigonal non-coplanar geometry to one C(17) and three equivalent H(22,23,24) atoms. The C(27)-C(17) bond length is 1.48 Å. All C(27)-H(22,23,24) bond lengths are 0.97 Å. In the second C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(18) atom. The C(25)-N(3) bond length is 1.39 Å. The C(25)-H(18) bond length is 0.94 Å. In the third C site, C(26) is bonded in a trigonal non-coplanar geometry to one C(23) and three equivalent H(19,20,21) atoms. The C(26)-C(23) bond length is 1.49 Å. All C(26)-H(19,20,21) bond lengths are 0.97 Å. In the fourth C site, C(16) is bonded in a distorted single-bond geometry to one C(10) and one H(2,5,8) atom. The C(16)-C(10) bond length is 1.39 Å. The C(16)-H(2,5,8) bond length is 0.94 Å. In the fifth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(27), one N(1), and one N(2) atom. The C(17)-N(1) bond length is 1.33 Å. The C(17)-N(2) bond length is 1.35 Å. In the sixth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(2), and one H(9) atom. The C(18)-C(19) bond length is 1.34 Å. The C(18)-N(2) bond length is 1.37 Å. The C(18)-H(9) bond length is 0.94 Å. In the seventh C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(1), and one O(2) atom. The C(1)-C(10) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.26 Å. In the eighth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(4) atom. The C(2)-C(3) bond length is 1.49 Å. The C(2)-O(3) bond length is 1.25 Å. The C(2)-O(4) bond length is 1.25 Å. In the ninth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(5) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(5) bond length is 1.39 Å. In the tenth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(5), and one O(6) atom. The C(6)-C(7) bond length is 1.50 Å. The C(6)-O(5) bond length is 1.26 Å. The C(6)-O(6) bond length is 1.25 Å. In the eleventh C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-C(9) bond length is 1.40 Å. In the twelfth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(4)-H(1) bond length is 0.94 Å. In the thirteenth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(2,5,8) atom. The C(5)-H(2,5,8) bond length is 0.94 Å. In the fourteenth C site, C(10) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(16) atom. The C(10)-C(11) bond length is 1.40 Å. In the fifteenth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(6) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(6) bond length is 0.94 Å. In the sixteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(15) atom. The C(13)-C(14) bond length is 1.50 Å. The C(13)-C(15) bond length is 1.38 Å. In the seventeenth C site, C(14) is bonded in a bent 120 degrees geometry to one C(13), one O(7), and one O(8) atom. The C(14)-O(7) bond length is 1.26 Å. The C(14)-O(8) bond length is 1.25 Å. In the eighteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(13) and one H(7) atom. The C(15)-H(7) bond length is 0.94 Å. In the nineteenth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(3) atom. The C(8)-H(3) bond length is 0.94 Å. In the twentieth C site, C(9) is bonded in a single-bond geometry to one C(7) and one H(4) atom. The C(9)-H(4) bond length is 0.94 Å. In the twenty-first C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(2,5,8) atom. The C(11)-H(2,5,8) bond length is 0.94 Å. In the twenty-second C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(1), and one H(10) atom. The C(19)-N(1) bond length is 1.38 Å. The C(19)-H(10) bond length is 0.94 Å. In the twenty-third C site, C(20) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(11,12) atoms. The C(20)-N(2) bond length is 1.47 Å. Both C(20)-H(11,12) bond lengths are 0.98 Å. In the twenty-fourth C site, C(22) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(15,16) atoms. The C(22)-N(3) bond length is 1.47 Å. Both C(22)-H(15,16) bond lengths are 0.98 Å. In the twenty-fifth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(26), one N(3), and one N(4) atom. The C(23)-N(3) bond length is 1.35 Å. The C(23)-N(4) bond length is 1.33 Å. In the twenty-sixth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(17) atom. The C(24)-N(4) bond length is 1.39 Å. The C(24)-H(17) bond length is 0.94 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(17), and one C(19) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(20) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(22), one C(23), and one C(25) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(2), one C(23), and one C(24) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2,5,8) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(11,12) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(15,16) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(24) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(19,20,21) is bonded in a single-bond geometry to one C(26) atom. In the fourteenth H site, H(22,23,24) is bonded in a single-bond geometry to one C(27) atom. There are eight inequivalent O sites. In the first O site, O(8) is bonded in a bent 120 degrees geometry to one Co(2) and one C(14) atom. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(1) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Co(2) and one C(1) atom. In the fourth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Co(2) and one C(2) atom. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one C(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Co(1) and one C(6) atom. In the seventh O site, O(5) is bonded in a bent 120 degrees geometry to one Co(2) and one C(6) atom. In the eighth O site, O(7) is bonded in a bent 120 degrees geometry to one Co(1) and one C(14) atom. Linkers: 8 [O]C(=O)c1ccc(C([O])=O)cc1 ,4 Cc1nccn1CCCn1ccnc1C. Metal clusters: 4 [C]1O[Co]234O[C]O[Co]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 5.15 A, density 1.20 g/cm3, surface area 4320.05 m2/g, accessible volume 0.37 cm3/g