AgC17N6H12 is Indium-like structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of eight AgC17N6H12 clusters. Ag(1) is bonded in a trigonal non-coplanar geometry to one N(1), one N(5), and one N(6) atom. The Ag(1)-N(1) bond length is 2.26 Å. The Ag(1)-N(5) bond length is 2.35 Å. The Ag(1)-N(6) bond length is 2.43 Å. There are seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(5) and one H(1) atom. The C(1)-C(5) bond length is 1.38 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(2)-N(1) bond length is 1.33 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(4) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.47 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one N(2), and one N(4) atom. The C(6)-N(2) bond length is 1.31 Å. The C(6)-N(4) bond length is 1.37 Å. In the seventh C site, C(7) is bonded in a distorted water-like geometry to one C(8), one N(3), and one N(4) atom. The C(7)-C(8) bond length is 1.46 Å. The C(7)-N(3) bond length is 1.31 Å. The C(7)-N(4) bond length is 1.37 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.38 Å. The C(8)-C(9) bond length is 1.38 Å. In the ninth C site, C(9) is bonded in a single-bond geometry to one C(10), one C(8), and one H(5) atom. The C(9)-C(10) bond length is 1.36 Å. The C(9)-H(5) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(5), and one H(6) atom. The C(10)-N(5) bond length is 1.34 Å. The C(10)-H(6) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(7) atom. The C(11)-N(5) bond length is 1.33 Å. The C(11)-H(7) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(12)-H(8) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(17), one N(4), and one N(6) atom. The C(13)-C(17) bond length is 1.37 Å. The C(13)-N(4) bond length is 1.44 Å. The C(13)-N(6) bond length is 1.32 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(6), and one H(9) atom. The C(14)-C(15) bond length is 1.37 Å. The C(14)-N(6) bond length is 1.34 Å. The C(14)-H(9) bond length is 0.93 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(10) atom. The C(15)-C(16) bond length is 1.36 Å. The C(15)-H(10) bond length is 0.93 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(11) atom. The C(16)-H(11) bond length is 0.93 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(13) and one H(12) atom. The C(17)-H(12) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(6) and one N(3) atom. The N(2)-N(3) bond length is 1.38 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(7) and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(13), one C(6), and one C(7) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(10), and one C(11) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(13), and one C(14) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. Linkers: 1 [CH]N([C]n1c(C2=[C][CH]N([Ag]([N])N=[CH])C=C2)nnc1C1=C[CH]N([Ag]([N])N2C=CC=C[C]2n2c(-c3ccncc3)nnc2-c2ccncc2)C=C1)[Ag](N1[CH][C]=C(C2=NC(C3=C[CH]N([Ag]4N5[CH]C=C(C=C5)c5nnc(C6=C[CH]N([Ag]7N8[CH]C=C(C=C8)c8nnc(-c9ccncc9)n8[C]8C=CC=CN8[Ag](N8[CH]C=C(c9nnc(C%10=C[CH]N([Ag])C=C%10)n9-c9ccccn9)C=C8)N8[CH]C=C(C=C8)c8nnc(C9=C[CH]N([Ag]%10N%11[CH]C=C(C=C%11)c%11nnc(C%12=C[CH]N([Ag])C=C%12)n%11[C]%11C=CC=CN%11[Ag](N%11[CH]C=C(C(=[N])[N][N])C=C%11)N%11[CH]C=C(C=C%11)c%11nnc(-c%12ccncc%12)n%11[C]%11C=CC=CN%11%10)C=C9)n8[C]8C=CC=CN87)C=C6)n5[C]5C=CC=CN5[Ag](N5[CH]C=C(c6nnc(-c7ccncc7)n6-c6ccccn6)C=C5)N5[CH]C=C(C=C5)c5nnc(-c6ccncc6)n5[C]5C=CC=CN54)C=C3)=N[N]2)C=C1)N1[CH]C=C(c2nnc(-c3ccncc3)n2-c2ccccn2)C=C1 ,1 [C].[C][C](C=[CH])c1nnc(C2=C[CH]N([Ag])C=C2)n1[C]1C=CC=CN1[Ag]([N]/C=C\C(=[CH])C([N])=[N])N1[CH]C=C(c2nnc3n2[C]2C=CC=CN2[Ag](N2[CH]C=C(c4nnc(C5=C[CH]N([Ag])C=C5)n4-c4ccccn4)[C]=C2)N2[CH]C=C(C=C2)c2nnc(-c4ccncc4)n2[C]2C=CC=CN2[Ag](N2[CH]C=C(c4nnc(C5=C[CH]N([Ag](N6[CH]C=C(c7nnc8n7[C]7C=CC=CN7[Ag](N7[CH]C=C(c9nnc(-c%10ccncc%10)n9-c9ccccn9)C=C7)N7[CH]C=C(C=C7)c7nnc(C9=C[CH]N([Ag]([N])N%10C=CC=C[C]%10n%10c(C(=[CH])/C=C\[N])nnc%10-c%10ccncc%10)C=C9)n7C7=CC=C[CH]N7[Ag](N7[CH]C=C([C]=[N])C=C7)N7[CH]C=C8C=C7)C=C6)N6C=CC=C[C]6n6c(-c7ccncc7)nnc6-c6ccncc6)C=C5)n4-c4ccccn4)C=C2)N2[CH]C=C3C=C2)C=C1.[N][Ag](N1[C]C=CC=C1)N1[CH]C=C(c2nnc(-c3ccncc3)n2-c2ccccn2)C=C1.[N][C][N] ,3 c1ccc(-n2c(-c3ccncc3)nnc2-c2ccncc2)nc1 ,1 [Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]/N=[C]/[N].[CH]=[CH].[CH]=[C][C]/[C]=N/[Ag].[CH]C(=[N])N=[CH].[CH]N([C][N])[Ag]([N])[N].[CH]N=[CH].[CH]N=[CH].[CH][C]=[CH].[CH][C]=[CH].[CH][N].[CH][N].[CH][N].[CH][N].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#N.[C]#[C].[C]N([CH])[Ag].[C]N([CH])[Ag].[C]N([CH])[Ag].[C]N=[CH].[C]N=[CH].[C]N=[CH].[C][CH].[C][CH].[C][CH].[C][CH].[C][CH].[C][CH].[C][CH].[C][CH].[C][CH].[C][C].[C][C].[C][C].[C][C].[C][C]/C=[C]\N([CH])[Ag].[C][C]/C=[C]\N=[Ag]\[N].[C][C]/[C]=[C]\N([C])[Ag][N].[C][C]=[CH].[C][C]=[CH].[C][C]=[CH].[C][C]=[CH].[C][C]=[C].[C][C][C].[C][C][C].[C][N].[C][N].[C][N].[C][N].[C][N].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][Ag].[N][Ag].[N][Ag].[N][Ag]([N])[N].[N][C]=[N].[N][C][N].[N][C][N].[N][C][N].[N][C][N][N].[N][C][N][N].[N][N] ,1 [C].[C][C](C=[CH])c1nnc(C2=C[CH]N([Ag])C=C2)n1[C]1C=CC=CN1[Ag]([N]/C=C\C(=[CH])C([N])=[N])N1[CH]C=C(c2nnc3n2[C]2C=CC=CN2[Ag](/N=C/[C]=C(\[C])c2nnc(C4=C[CH]N([Ag])C=C4)n2-c2ccccn2)N2[CH]C=C(C=C2)c2nnc(-c4ccncc4)n2[C]2C=CC=CN2[Ag](N2[CH]C=C(c4nnc(C5=C[CH]N([Ag](N6[CH]C=C(c7nnc8n7[C]7C=CC=CN7[Ag](N7[CH]C=C(c9nnc(-c%10ccncc%10)n9-c9ccccn9)C=C7)N7[CH]C=C(C=C7)c7nnc(C9=C[CH]N([Ag]([N])N%10C=CC=C[C]%10n%10c(C(=[CH])/C=C\[N])nnc%10-c%10ccncc%10)C=C9)n7C7=CC=C[CH]N7[Ag](N7[CH]C=C([C]=[N])C=C7)N7[CH]C=C8C=C7)C=C6)N6C=CC=C[C]6n6c(-c7ccncc7)nnc6-c6ccncc6)C=C5)n4-c4ccccn4)C=C2)N2[CH]C=C3C=C2)C=C1.[N][Ag](N1[C]C=CC=C1)N1[CH]C=C(c2nnc(-c3ccncc3)n2-c2ccccn2)C=C1.[N][C][N]. Metal clusters: 7 [Ag]. The MOF has largest included sphere 4.81 A, density 1.40 g/cm3, surface area 4278.30 m2/g, accessible volume 0.29 cm3/g