Co3C60H36(N3O4)2 crystallizes in the monoclinic Pm space group. There are six inequivalent Co sites. In the first Co site, Co(1,9) is bonded in a rectangular see-saw-like geometry to one N(3); one N(4,6,14,16,24,26,36); and two equivalent N(7,8,9,17,19,27,29,37,39,40) atoms. The Co(1,9)-N(3) bond length is 1.97 Å. The Co(1,9)-N(4,6,14,16,24,26,36) bond length is 1.97 Å. Both Co(1,9)-N(7,8,9,17,19,27,29,37,39,40) bond lengths are 1.97 Å. In the second Co site, Co(2) is bonded in a rectangular see-saw-like geometry to one N(10,15,18,20,28,30); one N(4,6,14,16,24,26,36); one N(5,25,35); and one N(7,8,9,17,19,27,29,37,39,40) atom. The Co(2)-N(10,15,18,20,28,30) bond length is 1.97 Å. The Co(2)-N(4,6,14,16,24,26,36) bond length is 1.97 Å. The Co(2)-N(5,25,35) bond length is 1.97 Å. The Co(2)-N(7,8,9,17,19,27,29,37,39,40) bond length is 1.97 Å. In the third Co site, Co(3,4,7,8,11,12,15,16) is bonded in a distorted square pyramidal geometry to one N(1,2,11,12,21,22,31,32); two equivalent O(3,4,5,7,11,12,13,15,19,20,21,23,27,28,29,31); and two equivalent O(6,8,9,10,17,24,25,32) atoms. The Co(3,4,7,8,11,12,15,16)-N(1,2,11,12,21,22,31,32) bond length is 2.06 Å. Both Co(3,4,7,8,11,12,15,16)-O(3,4,5,7,11,12,13,15,19,20,21,23,27,28,29,31) bond lengths are 1.83 Å. Both Co(3,4,7,8,11,12,15,16)-O(6,8,9,10,17,24,25,32) bond lengths are 1.83 Å. In the fourth Co site, Co(5) is bonded in a rectangular see-saw-like geometry to one N(10,15,18,20,28,30); one N(13,23,33,38); one N(4,6,14,16,24,26,36); and one N(7,8,9,17,19,27,29,37,39,40) atom. The Co(5)-N(10,15,18,20,28,30) bond length is 1.97 Å. The Co(5)-N(13,23,33,38) bond length is 1.97 Å. The Co(5)-N(4,6,14,16,24,26,36) bond length is 1.97 Å. The Co(5)-N(7,8,9,17,19,27,29,37,39,40) bond length is 1.97 Å. In the fifth Co site, Co(6,13) is bonded in a rectangular see-saw-like geometry to one N(4,6,14,16,24,26,36); one N(7,8,9,17,19,27,29,37,39,40); and two equivalent N(10,15,18,20,28,30) atoms. The Co(6,13)-N(4,6,14,16,24,26,36) bond length is 1.97 Å. The Co(6,13)-N(7,8,9,17,19,27,29,37,39,40) bond length is 1.97 Å. Both Co(6,13)-N(10,15,18,20,28,30) bond lengths are 1.97 Å. In the sixth Co site, Co(10,14) is bonded in a rectangular see-saw-like geometry to one N(10,15,18,20,28,30); one N(4,6,14,16,24,26,36); one N(5,25,35); and one N(7,8,9,17,19,27,29,37,39,40) atom. The Co(10,14)-N(10,15,18,20,28,30) bond length is 1.97 Å. The Co(10,14)-N(4,6,14,16,24,26,36) bond length is 1.97 Å. The Co(10,14)-N(5,25,35) bond length is 1.97 Å. The Co(10,14)-N(7,8,9,17,19,27,29,37,39,40) bond length is 1.97 Å. There are forty-five inequivalent C sites. In the first C site, C(151) is bonded in a distorted single-bond geometry to one C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365) and one H(29,31,33,35,38,40,42,44,74,76,78,80,81,83,85,87,118,120,121,123,125,127,130,132,162,164,165,167,169,171,174,176) atom. The C(151)-C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365) bond length is 1.47 Å. The C(151)-H(29,31,33,35,38,40,42,44,74,76,78,80,81,83,85,87,118,120,121,123,125,127,130,132,162,164,165,167,169,171,174,176) bond length is 1.08 Å. In the second C site, C(251) is bonded in a trigonal planar geometry to one C(56,68,118,126,210,252,302,344) and two equivalent C(2,6,130,135,190,222,282,314) atoms. The C(251)-C(56,68,118,126,210,252,302,344) bond length is 1.50 Å. Both C(251)-C(2,6,130,135,190,222,282,314) bond lengths are 1.41 Å. In the third C site, C(299) is bonded in a trigonal planar geometry to one C(124,300); one C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365); and one C(74,142,149,154,164,176,181,234,326,348,353,357,362) atom. The C(299)-C(124,300) bond length is 1.50 Å. The C(299)-C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365) bond length is 1.47 Å. The C(299)-C(74,142,149,154,164,176,181,234,326,348,353,357,362) bond length is 1.34 Å. In the fourth C site, C(328) is bonded in a distorted single-bond geometry to one C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365) and one H(29,31,33,35,38,40,42,44,74,76,78,80,81,83,85,87,118,120,121,123,125,127,130,132,162,164,165,167,169,171,174,176) atom. The C(328)-C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365) bond length is 1.47 Å. The C(328)-H(29,31,33,35,38,40,42,44,74,76,78,80,81,83,85,87,118,120,121,123,125,127,130,132,162,164,165,167,169,171,174,176) bond length is 1.08 Å. In the fifth C site, C(1,5,129,134,221,281,313) is bonded in a distorted trigonal planar geometry to one C(2,6,130,135,190,222,282,314); one C(54,66,250,342); and one H(1,5,67,71,93,111,137,155) atom. The C(1,5,129,134,221,281,313)-C(2,6,130,135,190,222,282,314) bond length is 1.41 Å. The C(1,5,129,134,221,281,313)-C(54,66,250,342) bond length is 1.41 Å. The C(1,5,129,134,221,281,313)-H(1,5,67,71,93,111,137,155) bond length is 1.08 Å. In the sixth C site, C(2,6,130,135,190,222,282,314) is bonded in a distorted trigonal planar geometry to one C(1,5,129,134,221,281,313); one C(55,67,117,125,209,301,343); and one H(2,6,68,72,112,138,156) atom. The C(2,6,130,135,190,222,282,314)-C(55,67,117,125,209,301,343) bond length is 1.41 Å. The C(2,6,130,135,190,222,282,314)-H(2,6,68,72,112,138,156) bond length is 1.08 Å. In the seventh C site, C(3,7,99,187,191,283) is bonded in a distorted single-bond geometry to one C(39,44,131,136,223,228,315,320) and one H(3,7,47,91,95,135) atom. The C(3,7,99,187,191,283)-C(39,44,131,136,223,228,315,320) bond length is 1.42 Å. The C(3,7,99,187,191,283)-H(3,7,47,91,95,135) bond length is 1.08 Å. In the eighth C site, C(4,8,96,100,188,192,280,284) is bonded in a distorted bent 120 degrees geometry to one N(1,2,11,12,21,22,31,32) and one H(4,8,48,52,92,96,136,140) atom. The C(4,8,96,100,188,192,280,284)-N(1,2,11,12,21,22,31,32) bond length is 1.38 Å. The C(4,8,96,100,188,192,280,284)-H(4,8,48,52,92,96,136,140) bond length is 1.08 Å. In the ninth C site, C(9,14,35,40,101,106,127,132,193,198,219,224,285,290,311,316) is bonded in a distorted trigonal planar geometry to one C(10,15,36,41,102,107,128,133,194,199,220,225,286,291,312,317); one C(28,78,90,112,120,170,182,212,262,304,354,366); and one H(9,15,21,25,53,59,65,69,97,103,109,113,141,147,153,157) atom. The C(9,14,35,40,101,106,127,132,193,198,219,224,285,290,311,316)-C(10,15,36,41,102,107,128,133,194,199,220,225,286,291,312,317) bond length is 1.41 Å. The C(9,14,35,40,101,106,127,132,193,198,219,224,285,290,311,316)-C(28,78,90,112,120,170,182,212,262,304,354,366) bond length is 1.41 Å. The C(9,14,35,40,101,106,127,132,193,198,219,224,285,290,311,316)-H(9,15,21,25,53,59,65,69,97,103,109,113,141,147,153,157) bond length is 1.08 Å. In the tenth C site, C(10,15,36,41,102,107,128,133,194,199,220,225,286,291,312,317) is bonded in a distorted trigonal planar geometry to one C(21,29,79,91,113,121,171,183,205,213,263,275,297,305,355,367); one C(9,14,35,40,101,106,127,132,193,198,219,224,285,290,311,316); and one H(10,16,22,26,54,60,66,70,98,104,110,114,142,148,154,158) atom. The C(10,15,36,41,102,107,128,133,194,199,220,225,286,291,312,317)-C(21,29,79,91,113,121,171,183,205,213,263,275,297,305,355,367) bond length is 1.41 Å. The C(10,15,36,41,102,107,128,133,194,199,220,225,286,291,312,317)-H(10,16,22,26,54,60,66,70,98,104,110,114,142,148,154,158) bond length is 1.08 Å. In the eleventh C site, C(11,16,103,108,195,200,287,292) is bonded in a distorted trigonal planar geometry to one C(12,17,104,109,196,201,288,293); one C(13,18,105,110,197,202,289,294); and one N(1,2,11,12,21,22,31,32) atom. The C(11,16,103,108,195,200,287,292)-C(12,17,104,109,196,201,288,293) bond length is 1.44 Å. The C(11,16,103,108,195,200,287,292)-C(13,18,105,110,197,202,289,294) bond length is 1.51 Å. The C(11,16,103,108,195,200,287,292)-N(1,2,11,12,21,22,31,32) bond length is 1.39 Å. In the twelfth C site, C(12,17,104,109,196,201,288,293) is bonded in a distorted single-bond geometry to one C(11,16,103,108,195,200,287,292); one C(39,44,131,136,223,228,315,320); and one H(11,17,55,61,99,105,143,149) atom. The C(12,17,104,109,196,201,288,293)-C(39,44,131,136,223,228,315,320) bond length is 1.42 Å. The C(12,17,104,109,196,201,288,293)-H(11,17,55,61,99,105,143,149) bond length is 1.08 Å. In the thirteenth C site, C(13,18,105,110,197,202,289,294) is bonded in a distorted trigonal non-coplanar geometry to one C(11,16,103,108,195,200,287,292); one H(12,18,56,62,100,106,144,150); and two equivalent H(13,14,19,20,57,58,63,64,101,102,107,108,145,146,151,152) atoms. The C(13,18,105,110,197,202,289,294)-H(12,18,56,62,100,106,144,150) bond length is 1.09 Å. Both C(13,18,105,110,197,202,289,294)-H(13,14,19,20,57,58,63,64,101,102,107,108,145,146,151,152) bond lengths are 1.11 Å. In the fourteenth C site, C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361) is bonded in a trigonal planar geometry to one C(20,204,274,296); one C(45,145,237,253,268,273,345); and one C(69,169,229,261,321) atom. The C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361)-C(20,204,274,296) bond length is 1.51 Å. The C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361)-C(45,145,237,253,268,273,345) bond length is 1.47 Å. The C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361)-C(69,169,229,261,321) bond length is 1.34 Å. In the fifteenth C site, C(20,204,274,296) is bonded in a trigonal planar geometry to one C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361) and two equivalent C(9,14,35,40,101,106,127,132,193,198,219,224,285,290,311,316) atoms. Both C(20,204,274,296)-C(9,14,35,40,101,106,127,132,193,198,219,224,285,290,311,316) bond lengths are 1.41 Å. In the sixteenth C site, C(21,29,79,91,113,121,171,183,205,213,263,275,297,305,355,367) is bonded in a trigonal planar geometry to one C(22,30,80,92,114,122,172,184,206,214,264,276,298,306,356,368) and two equivalent C(10,15,36,41,102,107,128,133,194,199,220,225,286,291,312,317) atoms. The C(21,29,79,91,113,121,171,183,205,213,263,275,297,305,355,367)-C(22,30,80,92,114,122,172,184,206,214,264,276,298,306,356,368) bond length is 1.50 Å. In the seventeenth C site, C(22,30,80,92,114,122,172,184,206,214,264,276,298,306,356,368) is bonded in a bent 120 degrees geometry to one C(21,29,79,91,113,121,171,183,205,213,263,275,297,305,355,367) and two equivalent O(3,4,5,7,11,12,13,15,19,20,21,23,27,28,29,31) atoms. Both C(22,30,80,92,114,122,172,184,206,214,264,276,298,306,356,368)-O(3,4,5,7,11,12,13,15,19,20,21,23,27,28,29,31) bond lengths are 1.29 Å. In the eighteenth C site, C(23,31,141,153,215,233,307,325) is bonded in a trigonal planar geometry to one C(24,32,146,158,216,238,308,330); one C(53,65,81,137,249,265,341); and one C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365) atom. The C(23,31,141,153,215,233,307,325)-C(24,32,146,158,216,238,308,330) bond length is 1.50 Å. The C(23,31,141,153,215,233,307,325)-C(53,65,81,137,249,265,341) bond length is 1.34 Å. The C(23,31,141,153,215,233,307,325)-C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365) bond length is 1.47 Å. In the nineteenth C site, C(24,32,146,158,216,238,308,330) is bonded in a trigonal planar geometry to one C(23,31,141,153,215,233,307,325) and two equivalent C(37,42,93,97,185,189,226,277,318) atoms. Both C(24,32,146,158,216,238,308,330)-C(37,42,93,97,185,189,226,277,318) bond lengths are 1.41 Å. In the twentieth C site, C(25,33,147,159,217,239,309,331) is bonded in a trigonal planar geometry to one C(26,34,148,160,218,240,310,332) and two equivalent C(38,43,94,98,186,227,278,319) atoms. The C(25,33,147,159,217,239,309,331)-C(26,34,148,160,218,240,310,332) bond length is 1.50 Å. Both C(25,33,147,159,217,239,309,331)-C(38,43,94,98,186,227,278,319) bond lengths are 1.41 Å. In the twenty-first C site, C(26,34,148,160,218,240,310,332) is bonded in a bent 120 degrees geometry to one C(25,33,147,159,217,239,309,331) and two equivalent O(6,8,9,10,17,24,25,32) atoms. Both C(26,34,148,160,218,240,310,332)-O(6,8,9,10,17,24,25,32) bond lengths are 1.28 Å. In the twenty-second C site, C(28,78,90,112,120,170,182,212,262,304,354,366) is bonded in a trigonal planar geometry to one C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361) and two equivalent C(9,14,35,40,101,106,127,132,193,198,219,224,285,290,311,316) atoms. The C(28,78,90,112,120,170,182,212,262,304,354,366)-C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361) bond length is 1.51 Å. In the twenty-third C site, C(37,42,93,97,185,189,226,277,318) is bonded in a distorted trigonal planar geometry to one C(24,32,146,158,216,238,308,330); one C(38,43,94,98,186,227,278,319); and one H(23,27,45,49,89,115,133,159) atom. The C(37,42,93,97,185,189,226,277,318)-C(38,43,94,98,186,227,278,319) bond length is 1.41 Å. The C(37,42,93,97,185,189,226,277,318)-H(23,27,45,49,89,115,133,159) bond length is 1.08 Å. In the twenty-fourth C site, C(38,43,94,98,186,227,278,319) is bonded in a distorted trigonal planar geometry to one C(25,33,147,159,217,239,309,331); one C(37,42,93,97,185,189,226,277,318); and one H(24,28,46,50,90,94,116,134,160) atom. The C(38,43,94,98,186,227,278,319)-H(24,28,46,50,90,94,116,134,160) bond length is 1.08 Å. In the twenty-fifth C site, C(39,44,131,136,223,228,315,320) is bonded in a trigonal planar geometry to one C(12,17,104,109,196,201,288,293); one C(3,7,99,187,191,283); and one C(39,44,131,136,223,228,315,320) atom. The C(39,44,131,136,223,228,315,320)-C(39,44,131,136,223,228,315,320) bond length is 1.58 Å. In the twenty-sixth C site, C(45,145,237,253,268,273,345) is bonded in a distorted trigonal planar geometry to one C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361); one C(46,51,58,71,76,83,88,139,144,156,162,167,174,179,231,236,242,247,254,259,267,272,323,334,339,346,351,359,364); and one N(3) atom. The C(45,145,237,253,268,273,345)-C(46,51,58,71,76,83,88,139,144,156,162,167,174,179,231,236,242,247,254,259,267,272,323,334,339,346,351,359,364) bond length is 1.47 Å. The C(45,145,237,253,268,273,345)-N(3) bond length is 1.31 Å. In the twenty-seventh C site, C(46,51,58,71,76,83,88,139,144,156,162,167,174,179,231,236,242,247,254,259,267,272,323,334,339,346,351,359,364) is bonded in a distorted single-bond geometry to one C(45,145,237,253,268,273,345) and one H(29,31,33,35,38,40,42,44,74,76,78,80,81,83,85,87,118,120,121,123,125,127,130,132,162,164,165,167,169,171,174,176) atom. The C(46,51,58,71,76,83,88,139,144,156,162,167,174,179,231,236,242,247,254,259,267,272,323,334,339,346,351,359,364)-H(29,31,33,35,38,40,42,44,74,76,78,80,81,83,85,87,118,120,121,123,125,127,130,132,162,164,165,167,169,171,174,176) bond length is 1.08 Å. In the twenty-eighth C site, C(47,59,243,335) is bonded in a distorted single-bond geometry to one C(48,60,86,244,256,270,336) and one H(30,32,34,36,39,41,43,73,75,77,79,82,86,88,117,119,122,124,126,129,131,161,163,166,168,170,172,173,175) atom. The C(47,59,243,335)-C(48,60,86,244,256,270,336) bond length is 1.46 Å. The C(47,59,243,335)-H(30,32,34,36,39,41,43,73,75,77,79,82,86,88,117,119,122,124,126,129,131,161,163,166,168,170,172,173,175) bond length is 1.08 Å. In the twenty-ninth C site, C(48,60,86,244,256,270,336) is bonded in a trigonal planar geometry to one C(47,59,243,335); one C(49,61,245,337); and one N(3) atom. The C(48,60,86,244,256,270,336)-C(49,61,245,337) bond length is 1.34 Å. The C(48,60,86,244,256,270,336)-N(3) bond length is 1.44 Å. In the thirtieth C site, C(49,61,245,337) is bonded in a trigonal planar geometry to one C(48,60,86,244,256,270,336); one C(50,62,84,246,338); and one C(54,66,250,342) atom. The C(49,61,245,337)-C(50,62,84,246,338) bond length is 1.47 Å. The C(49,61,245,337)-C(54,66,250,342) bond length is 1.50 Å. In the thirty-first C site, C(50,62,84,246,338) is bonded in a distorted trigonal planar geometry to one C(46,51,58,71,76,83,88,139,144,156,162,167,174,179,231,236,242,247,254,259,267,272,323,334,339,346,351,359,364); one C(49,61,245,337); and one N(4,6,14,16,24,26,36) atom. The C(50,62,84,246,338)-C(46,51,58,71,76,83,88,139,144,156,162,167,174,179,231,236,242,247,254,259,267,272,323,334,339,346,351,359,364) bond length is 1.47 Å. The C(50,62,84,246,338)-N(4,6,14,16,24,26,36) bond length is 1.31 Å. In the thirty-second C site, C(52,64,143,155,235,248,327,340) is bonded in a distorted single-bond geometry to one C(53,65,81,137,249,265,341) and one H(30,32,34,36,39,41,43,73,75,77,79,82,86,88,117,119,122,124,126,129,131,161,163,166,168,170,172,173,175) atom. The C(52,64,143,155,235,248,327,340)-C(53,65,81,137,249,265,341) bond length is 1.46 Å. The C(52,64,143,155,235,248,327,340)-H(30,32,34,36,39,41,43,73,75,77,79,82,86,88,117,119,122,124,126,129,131,161,163,166,168,170,172,173,175) bond length is 1.08 Å. In the thirty-third C site, C(53,65,81,137,249,265,341) is bonded in a trigonal planar geometry to one C(23,31,141,153,215,233,307,325); one C(52,64,143,155,235,248,327,340); and one N(4,6,14,16,24,26,36) atom. The C(53,65,81,137,249,265,341)-N(4,6,14,16,24,26,36) bond length is 1.44 Å. In the thirty-fourth C site, C(54,66,250,342) is bonded in a trigonal planar geometry to one C(49,61,245,337) and two equivalent C(1,5,129,134,221,281,313) atoms. In the thirty-fifth C site, C(55,67,117,125,209,301,343) is bonded in a trigonal planar geometry to one C(56,68,118,126,210,252,302,344) and two equivalent C(2,6,130,135,190,222,282,314) atoms. The C(55,67,117,125,209,301,343)-C(56,68,118,126,210,252,302,344) bond length is 1.50 Å. In the thirty-sixth C site, C(56,68,118,126,210,252,302,344) is bonded in a bent 120 degrees geometry to one C(55,67,117,125,209,301,343) and two equivalent O(1,2,14,16,22,26,30) atoms. Both C(56,68,118,126,210,252,302,344)-O(1,2,14,16,22,26,30) bond lengths are 1.28 Å. In the thirty-seventh C site, C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365) is bonded in a distorted trigonal planar geometry to one C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361); one C(46,51,58,71,76,83,88,139,144,156,162,167,174,179,231,236,242,247,254,259,267,272,323,334,339,346,351,359,364); and one N(5,25,35) atom. The C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365)-C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361) bond length is 1.47 Å. The C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365)-C(46,51,58,71,76,83,88,139,144,156,162,167,174,179,231,236,242,247,254,259,267,272,323,334,339,346,351,359,364) bond length is 1.47 Å. The C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365)-N(5,25,35) bond length is 1.31 Å. In the thirty-eighth C site, C(63) is bonded in a distorted single-bond geometry to one C(50,62,84,246,338) and one H(29,31,33,35,38,40,42,44,74,76,78,80,81,83,85,87,118,120,121,123,125,127,130,132,162,164,165,167,169,171,174,176) atom. The C(63)-C(50,62,84,246,338) bond length is 1.47 Å. The C(63)-H(29,31,33,35,38,40,42,44,74,76,78,80,81,83,85,87,118,120,121,123,125,127,130,132,162,164,165,167,169,171,174,176) bond length is 1.08 Å. In the thirty-ninth C site, C(69,169,229,261,321) is bonded in a trigonal planar geometry to one C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361); one C(70,75,82,87,138,150,163,168,175,180,230,255,260,266,271,322,347,352,358,363); and one N(7,8,9,17,19,27,29,37,39,40) atom. The C(69,169,229,261,321)-C(70,75,82,87,138,150,163,168,175,180,230,255,260,266,271,322,347,352,358,363) bond length is 1.46 Å. The C(69,169,229,261,321)-N(7,8,9,17,19,27,29,37,39,40) bond length is 1.44 Å. In the fortieth C site, C(70,75,82,87,138,150,163,168,175,180,230,255,260,266,271,322,347,352,358,363) is bonded in a distorted single-bond geometry to one C(69,169,229,261,321) and one H(37,84,128) atom. The C(70,75,82,87,138,150,163,168,175,180,230,255,260,266,271,322,347,352,358,363)-H(37,84,128) bond length is 1.08 Å. In the forty-first C site, C(72,166,258) is bonded in a distorted trigonal planar geometry to one C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361); one C(46,51,58,71,76,83,88,139,144,156,162,167,174,179,231,236,242,247,254,259,267,272,323,334,339,346,351,359,364); and one N(7,8,9,17,19,27,29,37,39,40) atom. The C(72,166,258)-C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361) bond length is 1.47 Å. The C(72,166,258)-C(46,51,58,71,76,83,88,139,144,156,162,167,174,179,231,236,242,247,254,259,267,272,323,334,339,346,351,359,364) bond length is 1.47 Å. The C(72,166,258)-N(7,8,9,17,19,27,29,37,39,40) bond length is 1.31 Å. In the forty-second C site, C(74,142,149,154,164,176,181,234,326,348,353,357,362) is bonded in a trigonal planar geometry to one C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361); one C(70,75,82,87,138,150,163,168,175,180,230,255,260,266,271,322,347,352,358,363); and one N(7,8,9,17,19,27,29,37,39,40) atom. The C(74,142,149,154,164,176,181,234,326,348,353,357,362)-C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361) bond length is 1.34 Å. The C(74,142,149,154,164,176,181,234,326,348,353,357,362)-C(70,75,82,87,138,150,163,168,175,180,230,255,260,266,271,322,347,352,358,363) bond length is 1.46 Å. The C(74,142,149,154,164,176,181,234,326,348,353,357,362)-N(7,8,9,17,19,27,29,37,39,40) bond length is 1.44 Å. In the forty-third C site, C(95,279) is bonded in a distorted single-bond geometry to one C(39,44,131,136,223,228,315,320) and one H(3,7,47,91,95,135) atom. The C(95,279)-C(39,44,131,136,223,228,315,320) bond length is 1.42 Å. The C(95,279)-H(3,7,47,91,95,135) bond length is 1.08 Å. In the forty-fourth C site, C(116,208) is bonded in a trigonal planar geometry to one C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361) and two equivalent C(1,5,129,134,221,281,313) atoms. The C(116,208)-C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361) bond length is 1.50 Å. Both C(116,208)-C(1,5,129,134,221,281,313) bond lengths are 1.41 Å. In the forty-fifth C site, C(124,300) is bonded in a trigonal planar geometry to one C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361) and two equivalent C(1,5,129,134,221,281,313) atoms. The C(124,300)-C(19,27,73,85,111,115,119,123,165,177,203,207,211,257,269,295,303,349,361) bond length is 1.50 Å. Both C(124,300)-C(1,5,129,134,221,281,313) bond lengths are 1.41 Å. There are eight inequivalent N sites. In the first N site, N(1,2,11,12,21,22,31,32) is bonded in a trigonal planar geometry to one Co(3,4,7,8,11,12,15,16); one C(11,16,103,108,195,200,287,292); and one C(4,8,96,100,188,192,280,284) atom. In the second N site, N(3) is bonded in a distorted trigonal planar geometry to one Co(1,9); one C(45,145,237,253,268,273,345); and one C(48,60,86,244,256,270,336) atom. In the third N site, N(4,6,14,16,24,26,36) is bonded in a distorted trigonal planar geometry to one Co(1,9); one C(50,62,84,246,338); and one C(53,65,81,137,249,265,341) atom. In the fourth N site, N(5,25,35) is bonded in a distorted trigonal planar geometry to one Co(2); one C(48,60,86,244,256,270,336); and one C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365) atom. The N(5,25,35)-C(48,60,86,244,256,270,336) bond length is 1.44 Å. In the fifth N site, N(7,8,9,17,19,27,29,37,39,40) is bonded in a distorted trigonal planar geometry to one Co(1,9); one C(69,169,229,261,321); and one C(72,166,258) atom. In the sixth N site, N(10,15,18,20,28,30) is bonded in a distorted trigonal planar geometry to one Co(2); one C(48,60,86,244,256,270,336); and one C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365) atom. The N(10,15,18,20,28,30)-C(48,60,86,244,256,270,336) bond length is 1.44 Å. The N(10,15,18,20,28,30)-C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365) bond length is 1.31 Å. In the seventh N site, N(13,23,33,38) is bonded in a distorted trigonal planar geometry to one Co(5); one C(53,65,81,137,249,265,341); and one C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365) atom. The N(13,23,33,38)-C(53,65,81,137,249,265,341) bond length is 1.44 Å. The N(13,23,33,38)-C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365) bond length is 1.31 Å. In the eighth N site, N(34) is bonded in a distorted trigonal planar geometry to one Co(6,13); one C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365); and one C(74,142,149,154,164,176,181,234,326,348,353,357,362) atom. The N(34)-Co(6,13) bond length is 1.97 Å. The N(34)-C(57,77,89,140,152,157,161,173,178,232,241,324,329,333,350,360,365) bond length is 1.31 Å. The N(34)-C(74,142,149,154,164,176,181,234,326,348,353,357,362) bond length is 1.44 Å. There are fifteen inequivalent H sites. In the first H site, H(1,5,67,71,93,111,137,155) is bonded in a single-bond geometry to one C(1,5,129,134,221,281,313) atom. In the second H site, H(2,6,68,72,112,138,156) is bonded in a single-bond geometry to one C(2,6,130,135,190,222,282,314) atom. In the third H site, H(3,7,47,91,95,135) is bonded in a single-bond geometry to one C(95,279) atom. In the fourth H site, H(4,8,48,52,92,96,136,140) is bonded in a single-bond geometry to one C(4,8,96,100,188,192,280,284) atom. In the fifth H site, H(9,15,21,25,53,59,65,69,97,103,109,113,141,147,153,157) is bonded in a single-bond geometry to one C(9,14,35,40,101,106,127,132,193,198,219,224,285,290,311,316) atom. In the sixth H site, H(10,16,22,26,54,60,66,70,98,104,110,114,142,148,154,158) is bonded in a single-bond geometry to one C(10,15,36,41,102,107,128,133,194,199,220,225,286,291,312,317) atom. In the seventh H site, H(11,17,55,61,99,105,143,149) is bonded in a single-bond geometry to one C(12,17,104,109,196,201,288,293) atom. In the eighth H site, H(12,18,56,62,100,106,144,150) is bonded in a single-bond geometry to one C(13,18,105,110,197,202,289,294) atom. In the ninth H site, H(13,14,19,20,57,58,63,64,101,102,107,108,145,146,151,152) is bonded in a single-bond geometry to one C(13,18,105,110,197,202,289,294) atom. In the tenth H site, H(23,27,45,49,89,115,133,159) is bonded in a single-bond geometry to one C(37,42,93,97,185,189,226,277,318) atom. In the eleventh H site, H(24,28,46,50,90,94,116,134,160) is bonded in a single-bond geometry to one C(38,43,94,98,186,227,278,319) atom. In the twelfth H site, H(29,31,33,35,38,40,42,44,74,76,78,80,81,83,85,87,118,120,121,123,125,127,130,132,162,164,165,167,169,171,174,176) is bonded in a single-bond geometry to one C(46,51,58,71,76,83,88,139,144,156,162,167,174,179,231,236,242,247,254,259,267,272,323,334,339,346,351,359,364) atom. In the thirteenth H site, H(30,32,34,36,39,41,43,73,75,77,79,82,86,88,117,119,122,124,126,129,131,161,163,166,168,170,172,173,175) is bonded in a single-bond geometry to one C(47,59,243,335) atom. In the fourteenth H site, H(37,84,128) is bonded in a single-bond geometry to one C(70,75,82,87,138,150,163,168,175,180,230,255,260,266,271,322,347,352,358,363) atom. In the fifteenth H site, H(51,139) is bonded in a single-bond geometry to one C(3,7,99,187,191,283) atom. The H(51,139)-C(3,7,99,187,191,283) bond length is 1.08 Å. There are four inequivalent O sites. In the first O site, O(1,2,14,16,22,26,30) is bonded in a bent 120 degrees geometry to one Co(3,4,7,8,11,12,15,16) and one C(56,68,118,126,210,252,302,344) atom. The O(1,2,14,16,22,26,30)-Co(3,4,7,8,11,12,15,16) bond length is 1.83 Å. In the second O site, O(3,4,5,7,11,12,13,15,19,20,21,23,27,28,29,31) is bonded in a bent 120 degrees geometry to one Co(3,4,7,8,11,12,15,16) and one C(22,30,80,92,114,122,172,184,206,214,264,276,298,306,356,368) atom. In the third O site, O(6,8,9,10,17,24,25,32) is bonded in a bent 120 degrees geometry to one Co(3,4,7,8,11,12,15,16) and one C(26,34,148,160,218,240,310,332) atom. In the fourth O site, O(18) is bonded in a bent 120 degrees geometry to one Co(3,4,7,8,11,12,15,16) and one C(56,68,118,126,210,252,302,344) atom. The O(18)-Co(3,4,7,8,11,12,15,16) bond length is 1.83 Å. The O(18)-C(56,68,118,126,210,252,302,344) bond length is 1.28 Å. Linkers: 8 Cc1cc(-c2ccnc(C)c2)ccn1 ,8 [O]C(=O)c1ccc(cc1)C1=C2C=CC3=[N]2[Co@@]24n5c1ccc5C(=C1[N]2=C(C=C1)C(=c1n4c(=C3c2ccc(cc2)C(=O)[O])cc1)c1ccc(cc1)C(=O)[O])c1ccc(cc1)C(=O)[O]. Metal clusters: 8 [C]1O[Co]234O[C]O[Co]2(O1)(O[C]O3)O[C]O4. RCSR code: sql. The MOF has largest included sphere 12.63 A, density 0.49 g/cm3, surface area 4426.21 m2/g, accessible volume 1.50 cm3/g