Na3Cu6C48H44(N3O13)2(CH)12(CH2)6 crystallizes in the hexagonal P6_3/m space group. The structure consists of twenty-four 02329_fluka molecules and twelve 02329_fluka molecules inside a Na3Cu6C48H44(N3O13)2 framework. In the Na3Cu6C48H44(N3O13)2 framework, Na(1) is bonded in a rectangular see-saw-like geometry to two equivalent O(2) and two equivalent O(4) atoms. Both Na(1)-O(2) bond lengths are 2.32 Å. Both Na(1)-O(4) bond lengths are 2.31 Å. Cu(1) is bonded to one N(1), one O(1), one O(5), and two equivalent O(3) atoms to form distorted edge-sharing CuNO4 square pyramids. The Cu(1)-N(1) bond length is 1.98 Å. The Cu(1)-O(1) bond length is 1.96 Å. The Cu(1)-O(5) bond length is 2.02 Å. There is one shorter (1.98 Å) and one longer (2.30 Å) Cu(1)-O(3) bond length. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.41 Å. The C(1)-C(7) bond length is 1.51 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-H(5) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.28 Å. The C(7)-O(2) bond length is 1.25 Å. In the fifth C site, C(8) is bonded in a 3-coordinate geometry to one C(6); one N(1); and two equivalent H(6,7) atoms. The C(8)-C(6) bond length is 1.50 Å. The C(8)-N(1) bond length is 1.48 Å. Both C(8)-H(6,7) bond lengths are 0.97 Å. In the sixth C site, C(9) is bonded in a 3-coordinate geometry to one N(1) and two equivalent H(8,9) atoms. The C(9)-N(1) bond length is 1.49 Å. Both C(9)-H(8,9) bond lengths are 0.97 Å. In the seventh C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(8) atom. In the eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(11)-O(3) bond length is 1.29 Å. The C(11)-O(4) bond length is 1.23 Å. N(1) is bonded in a distorted tetrahedral geometry to one Cu(1), one C(8), one C(9), and one H(1) atom. The N(1)-H(1) bond length is 0.98 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(6,7) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one O(5) atom. The H(12)-O(5) bond length is 0.98 Å. In the sixth H site, H(8,9) is bonded in a single-bond geometry to one C(9) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one C(7) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Cu(1) and one C(11) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Na(1) and one C(11) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to three equivalent Cu(1) and one H(12) atom. Linkers: 12 [O]C(=O)CCNCc1ccccc1C([O])=O. Metal clusters: 6 [Na] ,12 [Cu]. The MOF has largest included sphere 4.29 A, density 1.35 g/cm3, surface area 4166.53 m2/g, accessible volume 0.27 cm3/g