Zn4C24H12O13(CH)22(C17H10O)4(C18H11O)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of forty-four 02329_fluka molecules, four C17H10O clusters, two C18H11O clusters, and two Zn4C24H12O13 clusters. In two of the C17H10O clusters, there are thirty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(19), one C(2), and one O(2) atom. The C(1)-C(19) bond length is 1.42 Å. The C(1)-C(2) bond length is 1.38 Å. The C(1)-O(2) bond length is 1.39 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(5) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(5) bond length is 1.53 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.44 Å. The C(3)-C(6) bond length is 1.53 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(20), one C(3), and one O(5) atom. The C(4)-C(20) bond length is 1.37 Å. The C(4)-O(5) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a single-bond geometry to one C(13), one C(2), one C(7), and one H(1) atom. The C(5)-C(13) bond length is 1.51 Å. The C(5)-C(7) bond length is 1.48 Å. The C(5)-H(1) bond length is 1.00 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(14), one C(3), one C(8), and one H(2) atom. The C(6)-C(14) bond length is 1.50 Å. The C(6)-C(8) bond length is 1.54 Å. The C(6)-H(2) bond length is 1.00 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(5), and one C(8) atom. The C(7)-C(12) bond length is 1.38 Å. The C(7)-C(8) bond length is 1.42 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(6), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.36 Å. In the ninth C site, C(9) is bonded in a single-bond geometry to one C(8) and one H(3) atom. The C(9)-H(3) bond length is 0.95 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(12)-H(6) bond length is 0.95 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(5) atom. The C(13)-C(14) bond length is 1.43 Å. The C(13)-C(18) bond length is 1.37 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(6) atom. The C(14)-C(15) bond length is 1.38 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(7) atom. The C(15)-H(7) bond length is 0.95 Å. In the fourteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(18)-H(10) bond length is 0.95 Å. In the fifteenth C site, C(19) is bonded in a trigonal planar geometry to one C(1), one C(20), and one C(21) atom. The C(19)-C(20) bond length is 1.38 Å. The C(19)-C(21) bond length is 1.53 Å. In the sixteenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(22), and one C(4) atom. The C(20)-C(22) bond length is 1.54 Å. In the seventeenth C site, C(21) is bonded in a single-bond geometry to one C(19), one C(23), one C(29), and one H(11) atom. The C(21)-C(23) bond length is 1.50 Å. The C(21)-C(29) bond length is 1.52 Å. The C(21)-H(11) bond length is 1.00 Å. In the eighteenth C site, C(22) is bonded in a single-bond geometry to one C(20), one C(24), one C(30), and one H(12) atom. The C(22)-C(24) bond length is 1.52 Å. The C(22)-C(30) bond length is 1.53 Å. The C(22)-H(12) bond length is 1.00 Å. In the nineteenth C site, C(23) is bonded in a trigonal planar geometry to one C(21), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.37 Å. The C(23)-C(28) bond length is 1.37 Å. In the twentieth C site, C(24) is bonded in a trigonal planar geometry to one C(22), one C(23), and one C(25) atom. The C(24)-C(25) bond length is 1.39 Å. In the twenty-first C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(13) atom. The C(25)-H(13) bond length is 0.95 Å. In the twenty-second C site, C(49) is bonded in a distorted single-bond geometry to one C(44) and one H(32) atom. The C(49)-C(44) bond length is 1.38 Å. The C(49)-H(32) bond length is 0.95 Å. In the twenty-third C site, C(28) is bonded in a distorted single-bond geometry to one C(23) and one H(16) atom. The C(28)-H(16) bond length is 0.95 Å. In the twenty-fourth C site, C(29) is bonded in a trigonal planar geometry to one C(21), one C(30), and one C(34) atom. The C(29)-C(30) bond length is 1.39 Å. The C(29)-C(34) bond length is 1.37 Å. In the twenty-fifth C site, C(30) is bonded in a trigonal planar geometry to one C(22), one C(29), and one C(31) atom. The C(30)-C(31) bond length is 1.40 Å. In the twenty-sixth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(17,45) atom. The C(31)-H(17,45) bond length is 0.95 Å. In the twenty-seventh C site, C(34) is bonded in a distorted single-bond geometry to one C(29) and one H(20) atom. The C(34)-H(20) bond length is 0.95 Å. In the twenty-eighth C site, C(35) is bonded in a distorted trigonal non-coplanar geometry to one C(36), one H(21), one H(22), and one O(2) atom. The C(35)-C(36) bond length is 1.48 Å. The C(35)-H(21) bond length is 0.99 Å. The C(35)-H(22) bond length is 0.99 Å. The C(35)-O(2) bond length is 1.42 Å. In the twenty-ninth C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(41) atom. The C(36)-C(37) bond length is 1.37 Å. The C(36)-C(41) bond length is 1.36 Å. In the thirtieth C site, C(37) is bonded in a distorted single-bond geometry to one C(36) and one H(23) atom. The C(37)-H(23) bond length is 0.95 Å. In the thirty-first C site, C(41) is bonded in a distorted single-bond geometry to one C(36) and one H(26) atom. The C(41)-H(26) bond length is 0.95 Å. In the thirty-second C site, C(43) is bonded in a distorted trigonal non-coplanar geometry to one C(44), one H(27), one H(28), and one O(5) atom. The C(43)-C(44) bond length is 1.45 Å. The C(43)-H(27) bond length is 0.99 Å. The C(43)-H(28) bond length is 0.99 Å. The C(43)-O(5) bond length is 1.44 Å. In the thirty-third C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(49) atom. The C(44)-C(45) bond length is 1.37 Å. In the thirty-fourth C site, C(45) is bonded in a distorted single-bond geometry to one C(44) and one H(29) atom. The C(45)-H(29) bond length is 0.95 Å. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(28) atom. In the eleventh H site, H(17,45) is bonded in a single-bond geometry to one C(31) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(34) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(35) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(35) atom. In the fifteenth H site, H(23) is bonded in a single-bond geometry to one C(37) atom. In the sixteenth H site, H(26) is bonded in a single-bond geometry to one C(41) atom. In the seventeenth H site, H(27) is bonded in a single-bond geometry to one C(43) atom. In the eighteenth H site, H(28) is bonded in a single-bond geometry to one C(43) atom. In the nineteenth H site, H(29) is bonded in a single-bond geometry to one C(45) atom. In the twentieth H site, H(32) is bonded in a single-bond geometry to one C(49) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a water-like geometry to one C(1) and one C(35) atom. In the second O site, O(5) is bonded in a bent 120 degrees geometry to one C(4) and one C(43) atom. In two of the C17H10O clusters, there are seventeen inequivalent C sites. In the first C site, C(101) is bonded in a distorted single-bond geometry to one C(102), one C(103), and one O(14) atom. The C(101)-C(102) bond length is 1.41 Å. The C(101)-C(103) bond length is 1.39 Å. The C(101)-O(14) bond length is 1.38 Å. In the second C site, C(102) is bonded in a trigonal planar geometry to one C(101), one C(103), and one C(104) atom. The C(102)-C(103) bond length is 1.35 Å. The C(102)-C(104) bond length is 1.52 Å. In the third C site, C(103) is bonded in a trigonal planar geometry to one C(101), one C(102), and one C(105) atom. The C(103)-C(105) bond length is 1.54 Å. In the fourth C site, C(104) is bonded in a distorted single-bond geometry to one C(102), one C(106), one C(112), and one H(65) atom. The C(104)-C(106) bond length is 1.50 Å. The C(104)-C(112) bond length is 1.47 Å. The C(104)-H(65) bond length is 1.00 Å. In the fifth C site, C(105) is bonded in a single-bond geometry to one C(103), one C(107), one C(113), and one H(66) atom. The C(105)-C(107) bond length is 1.53 Å. The C(105)-C(113) bond length is 1.53 Å. The C(105)-H(66) bond length is 1.00 Å. In the sixth C site, C(106) is bonded in a trigonal planar geometry to one C(104), one C(107), and one C(111) atom. The C(106)-C(107) bond length is 1.37 Å. The C(106)-C(111) bond length is 1.37 Å. In the seventh C site, C(107) is bonded in a trigonal planar geometry to one C(105), one C(106), and one C(108) atom. The C(107)-C(108) bond length is 1.42 Å. In the eighth C site, C(108) is bonded in a distorted single-bond geometry to one C(107) and one H(67) atom. The C(108)-H(67) bond length is 0.95 Å. In the ninth C site, C(111) is bonded in a distorted single-bond geometry to one C(106) and one H(70) atom. The C(111)-H(70) bond length is 0.95 Å. In the tenth C site, C(112) is bonded in a trigonal planar geometry to one C(104), one C(113), and one C(117) atom. The C(112)-C(113) bond length is 1.40 Å. The C(112)-C(117) bond length is 1.39 Å. In the eleventh C site, C(113) is bonded in a trigonal planar geometry to one C(105), one C(112), and one C(114) atom. The C(113)-C(114) bond length is 1.39 Å. In the twelfth C site, C(114) is bonded in a distorted single-bond geometry to one C(113) and one H(71) atom. The C(114)-H(71) bond length is 0.95 Å. In the thirteenth C site, C(117) is bonded in a distorted single-bond geometry to one C(112) and one H(74) atom. The C(117)-H(74) bond length is 0.95 Å. In the fourteenth C site, C(118) is bonded in a distorted trigonal non-coplanar geometry to one C(119), one H(75), one H(76), and one O(14) atom. The C(118)-C(119) bond length is 1.49 Å. The C(118)-H(75) bond length is 0.99 Å. The C(118)-H(76) bond length is 0.99 Å. The C(118)-O(14) bond length is 1.51 Å. In the fifteenth C site, C(119) is bonded in a trigonal planar geometry to one C(118), one C(120), and one C(124) atom. The C(119)-C(120) bond length is 1.39 Å. The C(119)-C(124) bond length is 1.30 Å. In the sixteenth C site, C(120) is bonded in a distorted single-bond geometry to one C(119) and one H(77) atom. The C(120)-H(77) bond length is 0.95 Å. In the seventeenth C site, C(124) is bonded in a distorted single-bond geometry to one C(119) and one H(80) atom. The C(124)-H(80) bond length is 0.95 Å. There are ten inequivalent H sites. In the first H site, H(65) is bonded in a single-bond geometry to one C(104) atom. In the second H site, H(66) is bonded in a single-bond geometry to one C(105) atom. In the third H site, H(67) is bonded in a single-bond geometry to one C(108) atom. In the fourth H site, H(70) is bonded in a single-bond geometry to one C(111) atom. In the fifth H site, H(71) is bonded in a single-bond geometry to one C(114) atom. In the sixth H site, H(74) is bonded in a single-bond geometry to one C(117) atom. In the seventh H site, H(75) is bonded in a single-bond geometry to one C(118) atom. In the eighth H site, H(76) is bonded in a single-bond geometry to one C(118) atom. In the ninth H site, H(77) is bonded in a single-bond geometry to one C(120) atom. In the tenth H site, H(80) is bonded in a single-bond geometry to one C(124) atom. O(14) is bonded in a water-like geometry to one C(101) and one C(118) atom. In each C18H11O cluster, there are thirty-six inequivalent C sites. In the first C site, C(57) is bonded in a trigonal planar geometry to one C(55), one C(58), and one C(62) atom. The C(57)-C(55) bond length is 1.50 Å. The C(57)-C(58) bond length is 1.36 Å. The C(57)-C(62) bond length is 1.42 Å. In the second C site, C(58) is bonded in a trigonal planar geometry to one C(56), one C(57), and one C(59) atom. The C(58)-C(56) bond length is 1.57 Å. The C(58)-C(59) bond length is 1.38 Å. In the third C site, C(59) is bonded in a distorted single-bond geometry to one C(58) and one H(35) atom. The C(59)-H(35) bond length is 0.95 Å. In the fourth C site, C(62) is bonded in a distorted single-bond geometry to one C(57) and one H(38) atom. The C(62)-H(38) bond length is 0.95 Å. In the fifth C site, C(63) is bonded in a trigonal planar geometry to one C(55), one C(64), and one C(68) atom. The C(63)-C(55) bond length is 1.52 Å. The C(63)-C(64) bond length is 1.36 Å. The C(63)-C(68) bond length is 1.39 Å. In the sixth C site, C(64) is bonded in a trigonal planar geometry to one C(56), one C(63), and one C(65) atom. The C(64)-C(56) bond length is 1.54 Å. The C(64)-C(65) bond length is 1.38 Å. In the seventh C site, C(65) is bonded in a distorted single-bond geometry to one C(64), one C(66), and one H(39) atom. The C(65)-C(66) bond length is 1.39 Å. The C(65)-H(39) bond length is 0.95 Å. In the eighth C site, C(66) is bonded in a distorted trigonal planar geometry to one C(65), one C(67), and one H(40) atom. The C(66)-C(67) bond length is 1.38 Å. The C(66)-H(40) bond length is 0.95 Å. In the ninth C site, C(67) is bonded in a distorted single-bond geometry to one C(66) and one H(41) atom. The C(67)-H(41) bond length is 0.95 Å. In the tenth C site, C(68) is bonded in a distorted single-bond geometry to one C(63) and one H(42) atom. The C(68)-H(42) bond length is 0.95 Å. In the eleventh C site, C(69) is bonded in a trigonal planar geometry to one C(51), one C(70), and one C(71) atom. The C(69)-C(51) bond length is 1.40 Å. The C(69)-C(70) bond length is 1.39 Å. The C(69)-C(71) bond length is 1.54 Å. In the twelfth C site, C(70) is bonded in a trigonal planar geometry to one C(54), one C(69), and one C(72) atom. The C(70)-C(54) bond length is 1.37 Å. The C(70)-C(72) bond length is 1.52 Å. In the thirteenth C site, C(71) is bonded in a single-bond geometry to one C(69), one C(73), one C(79), and one H(43) atom. The C(71)-C(73) bond length is 1.53 Å. The C(71)-C(79) bond length is 1.54 Å. The C(71)-H(43) bond length is 1.00 Å. In the fourteenth C site, C(72) is bonded in a single-bond geometry to one C(70), one C(74), one C(80), and one H(44) atom. The C(72)-C(74) bond length is 1.53 Å. The C(72)-C(80) bond length is 1.53 Å. The C(72)-H(44) bond length is 1.00 Å. In the fifteenth C site, C(73) is bonded in a trigonal planar geometry to one C(71), one C(74), and one C(78) atom. The C(73)-C(74) bond length is 1.39 Å. The C(73)-C(78) bond length is 1.42 Å. In the sixteenth C site, C(74) is bonded in a trigonal planar geometry to one C(72), one C(73), and one C(75) atom. The C(74)-C(75) bond length is 1.38 Å. In the seventeenth C site, C(75) is bonded in a distorted single-bond geometry to one C(74) and one H(17,45) atom. The C(75)-H(17,45) bond length is 0.95 Å. In the eighteenth C site, C(78) is bonded in a distorted single-bond geometry to one C(73) and one H(48) atom. The C(78)-H(48) bond length is 0.95 Å. In the nineteenth C site, C(79) is bonded in a trigonal planar geometry to one C(71), one C(80), and one C(84) atom. The C(79)-C(80) bond length is 1.37 Å. The C(79)-C(84) bond length is 1.36 Å. In the twentieth C site, C(80) is bonded in a trigonal planar geometry to one C(72), one C(79), and one C(81) atom. The C(80)-C(81) bond length is 1.41 Å. In the twenty-first C site, C(81) is bonded in a distorted single-bond geometry to one C(80) and one H(49) atom. The C(81)-H(49) bond length is 0.95 Å. In the twenty-second C site, C(84) is bonded in a distorted single-bond geometry to one C(79) and one H(52) atom. The C(84)-H(52) bond length is 0.95 Å. In the twenty-third C site, C(85) is bonded in a distorted trigonal non-coplanar geometry to one C(86); two equivalent H(53,54); and one O(8) atom. The C(85)-C(86) bond length is 1.53 Å. Both C(85)-H(53,54) bond lengths are 0.99 Å. The C(85)-O(8) bond length is 1.42 Å. In the twenty-fourth C site, C(86) is bonded in a trigonal planar geometry to one C(85), one C(87), and one C(91) atom. The C(86)-C(87) bond length is 1.37 Å. The C(86)-C(91) bond length is 1.37 Å. In the twenty-fifth C site, C(87) is bonded in a distorted single-bond geometry to one C(86) and one H(55) atom. The C(87)-H(55) bond length is 0.95 Å. In the twenty-sixth C site, C(91) is bonded in a distorted single-bond geometry to one C(86) and one H(58) atom. The C(91)-H(58) bond length is 0.95 Å. In the twenty-seventh C site, C(93) is bonded in a distorted trigonal non-coplanar geometry to one C(94); two equivalent H(59,60); and one O(11) atom. The C(93)-C(94) bond length is 1.49 Å. Both C(93)-H(59,60) bond lengths are 0.99 Å. The C(93)-O(11) bond length is 1.46 Å. In the twenty-eighth C site, C(94) is bonded in a trigonal planar geometry to one C(93), one C(95), and one C(99) atom. The C(94)-C(95) bond length is 1.38 Å. The C(94)-C(99) bond length is 1.42 Å. In the twenty-ninth C site, C(95) is bonded in a distorted single-bond geometry to one C(94) and one H(61,64) atom. The C(95)-H(61,64) bond length is 0.95 Å. In the thirtieth C site, C(99) is bonded in a distorted single-bond geometry to one C(94) and one H(61,64) atom. The C(99)-H(61,64) bond length is 0.95 Å. In the thirty-first C site, C(52) is bonded in a trigonal planar geometry to one C(51), one C(53), and one C(55) atom. The C(52)-C(51) bond length is 1.38 Å. The C(52)-C(53) bond length is 1.40 Å. The C(52)-C(55) bond length is 1.53 Å. In the thirty-second C site, C(51) is bonded in a distorted single-bond geometry to one C(52), one C(69), and one O(8) atom. The C(51)-O(8) bond length is 1.37 Å. In the thirty-third C site, C(53) is bonded in a trigonal planar geometry to one C(52), one C(54), and one C(56) atom. The C(53)-C(54) bond length is 1.41 Å. The C(53)-C(56) bond length is 1.50 Å. In the thirty-fourth C site, C(54) is bonded in a distorted trigonal planar geometry to one C(53), one C(70), and one O(11) atom. The C(54)-O(11) bond length is 1.39 Å. In the thirty-fifth C site, C(55) is bonded in a single-bond geometry to one C(52), one C(57), one C(63), and one H(33) atom. The C(55)-H(33) bond length is 1.00 Å. In the thirty-sixth C site, C(56) is bonded in a distorted single-bond geometry to one C(53), one C(58), one C(64), and one H(34) atom. The C(56)-H(34) bond length is 1.00 Å. There are nineteen inequivalent H sites. In the first H site, H(17,45) is bonded in a single-bond geometry to one C(31) atom. In the second H site, H(33) is bonded in a single-bond geometry to one C(55) atom. In the third H site, H(34) is bonded in a single-bond geometry to one C(56) atom. In the fourth H site, H(35) is bonded in a single-bond geometry to one C(59) atom. In the fifth H site, H(38) is bonded in a single-bond geometry to one C(62) atom. In the sixth H site, H(39) is bonded in a single-bond geometry to one C(65) atom. In the seventh H site, H(40) is bonded in a single-bond geometry to one C(66) atom. In the eighth H site, H(41) is bonded in a single-bond geometry to one C(67) atom. In the ninth H site, H(42) is bonded in a single-bond geometry to one C(68) atom. In the tenth H site, H(43) is bonded in a single-bond geometry to one C(71) atom. In the eleventh H site, H(44) is bonded in a single-bond geometry to one C(72) atom. In the twelfth H site, H(48) is bonded in a single-bond geometry to one C(78) atom. In the thirteenth H site, H(49) is bonded in a single-bond geometry to one C(81) atom. In the fourteenth H site, H(52) is bonded in a single-bond geometry to one C(84) atom. In the fifteenth H site, H(53,54) is bonded in a single-bond geometry to one C(85) atom. In the sixteenth H site, H(55) is bonded in a single-bond geometry to one C(87) atom. In the seventeenth H site, H(58) is bonded in a single-bond geometry to one C(91) atom. In the eighteenth H site, H(59,60) is bonded in a single-bond geometry to one C(93) atom. In the nineteenth H site, H(61,64) is bonded in a single-bond geometry to one C(95) atom. There are two inequivalent O sites. In the first O site, O(11) is bonded in a bent 120 degrees geometry to one C(54) and one C(93) atom. In the second O site, O(8) is bonded in a bent 120 degrees geometry to one C(51) and one C(85) atom. In each Zn4C24H12O13 cluster, there are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(12), one O(19), and one O(7) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.92 Å. The Zn(1)-O(12) bond length is 1.97 Å. The Zn(1)-O(19) bond length is 1.91 Å. The Zn(1)-O(7) bond length is 1.97 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(13), one O(15), and one O(3) atom to form distorted corner-sharing ZnO4 tetrahedra. The Zn(2)-O(1) bond length is 1.92 Å. The Zn(2)-O(13) bond length is 1.98 Å. The Zn(2)-O(15) bond length is 1.99 Å. The Zn(2)-O(3) bond length is 1.92 Å. In the third Zn site, Zn(3) is bonded to one O(1), one O(16), one O(6), and one O(9) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(1) bond length is 1.93 Å. The Zn(3)-O(16) bond length is 1.96 Å. The Zn(3)-O(6) bond length is 2.04 Å. The Zn(3)-O(9) bond length is 1.92 Å. In the fourth Zn site, Zn(4) is bonded in a 3-coordinate geometry to one O(1), one O(10), and one O(18) atom. The Zn(4)-O(1) bond length is 2.04 Å. The Zn(4)-O(10) bond length is 2.12 Å. The Zn(4)-O(18) bond length is 2.13 Å. There are twenty-four inequivalent C sites. In the first C site, C(88) is bonded in a distorted single-bond geometry to one C(89) and one H(56,57) atom. The C(88)-C(89) bond length is 1.37 Å. The C(88)-H(56,57) bond length is 0.95 Å. In the second C site, C(89) is bonded in a trigonal planar geometry to one C(88), one C(90), and one C(92) atom. The C(89)-C(90) bond length is 1.38 Å. The C(89)-C(92) bond length is 1.50 Å. In the third C site, C(90) is bonded in a distorted single-bond geometry to one C(89) and one H(56,57) atom. The C(90)-H(56,57) bond length is 0.95 Å. In the fourth C site, C(92) is bonded in a distorted bent 120 degrees geometry to one C(89), one O(10), and one O(9) atom. The C(92)-O(10) bond length is 1.23 Å. The C(92)-O(9) bond length is 1.28 Å. In the fifth C site, C(96) is bonded in a distorted single-bond geometry to one C(97) and one H(62) atom. The C(96)-C(97) bond length is 1.40 Å. The C(96)-H(62) bond length is 0.95 Å. In the sixth C site, C(97) is bonded in a trigonal planar geometry to one C(100), one C(96), and one C(98) atom. The C(97)-C(100) bond length is 1.48 Å. The C(97)-C(98) bond length is 1.37 Å. In the seventh C site, C(98) is bonded in a distorted single-bond geometry to one C(97) and one H(63) atom. The C(98)-H(63) bond length is 0.95 Å. In the eighth C site, C(100) is bonded in a distorted bent 120 degrees geometry to one C(97), one O(12), and one O(13) atom. The C(100)-O(12) bond length is 1.27 Å. The C(100)-O(13) bond length is 1.25 Å. In the ninth C site, C(121) is bonded in a distorted single-bond geometry to one C(122) and one H(78) atom. The C(121)-C(122) bond length is 1.39 Å. The C(121)-H(78) bond length is 0.95 Å. In the tenth C site, C(122) is bonded in a trigonal planar geometry to one C(121), one C(123), and one C(125) atom. The C(122)-C(123) bond length is 1.35 Å. The C(122)-C(125) bond length is 1.51 Å. In the eleventh C site, C(123) is bonded in a distorted single-bond geometry to one C(122) and one H(79) atom. The C(123)-H(79) bond length is 0.95 Å. In the twelfth C site, C(125) is bonded in a distorted bent 120 degrees geometry to one C(122), one O(15), and one O(16) atom. The C(125)-O(15) bond length is 1.27 Å. The C(125)-O(16) bond length is 1.24 Å. In the thirteenth C site, C(146) is bonded in a distorted single-bond geometry to one C(147) and one H(94) atom. The C(146)-C(147) bond length is 1.39 Å. The C(146)-H(94) bond length is 0.95 Å. In the fourteenth C site, C(147) is bonded in a trigonal planar geometry to one C(146), one C(148), and one C(150) atom. The C(147)-C(148) bond length is 1.41 Å. The C(147)-C(150) bond length is 1.49 Å. In the fifteenth C site, C(148) is bonded in a distorted single-bond geometry to one C(147) and one H(95) atom. The C(148)-H(95) bond length is 0.95 Å. In the sixteenth C site, C(48) is bonded in a distorted single-bond geometry to one C(47) and one H(31) atom. The C(48)-C(47) bond length is 1.40 Å. The C(48)-H(31) bond length is 0.95 Å. In the seventeenth C site, C(150) is bonded in a distorted bent 120 degrees geometry to one C(147), one O(18), and one O(19) atom. The C(150)-O(18) bond length is 1.26 Å. The C(150)-O(19) bond length is 1.25 Å. In the eighteenth C site, C(38) is bonded in a distorted single-bond geometry to one C(39) and one H(24) atom. The C(38)-C(39) bond length is 1.37 Å. The C(38)-H(24) bond length is 0.95 Å. In the nineteenth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(42) atom. The C(39)-C(40) bond length is 1.41 Å. The C(39)-C(42) bond length is 1.53 Å. In the twentieth C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one H(25) atom. The C(40)-H(25) bond length is 0.95 Å. In the twenty-first C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(39), one O(3), and one O(4) atom. The C(42)-O(3) bond length is 1.23 Å. The C(42)-O(4) bond length is 1.26 Å. In the twenty-second C site, C(46) is bonded in a distorted single-bond geometry to one C(47) and one H(30) atom. The C(46)-C(47) bond length is 1.39 Å. The C(46)-H(30) bond length is 0.95 Å. In the twenty-third C site, C(47) is bonded in a trigonal planar geometry to one C(46), one C(48), and one C(50) atom. The C(47)-C(50) bond length is 1.48 Å. In the twenty-fourth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one C(47), one O(6), and one O(7) atom. The C(50)-O(6) bond length is 1.24 Å. The C(50)-O(7) bond length is 1.24 Å. There are eleven inequivalent H sites. In the first H site, H(25) is bonded in a single-bond geometry to one C(40) atom. In the second H site, H(24) is bonded in a single-bond geometry to one C(38) atom. In the third H site, H(30) is bonded in a single-bond geometry to one C(46) atom. In the fourth H site, H(31) is bonded in a single-bond geometry to one C(48) atom. In the fifth H site, H(56,57) is bonded in a single-bond geometry to one C(88) atom. In the sixth H site, H(62) is bonded in a single-bond geometry to one C(96) atom. In the seventh H site, H(63) is bonded in a single-bond geometry to one C(98) atom. In the eighth H site, H(78) is bonded in a single-bond geometry to one C(121) atom. In the ninth H site, H(79) is bonded in a single-bond geometry to one C(123) atom. In the tenth H site, H(94) is bonded in a single-bond geometry to one C(146) atom. In the eleventh H site, H(95) is bonded in a single-bond geometry to one C(148) atom. There are thirteen inequivalent O sites. In the first O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(100) atom. In the second O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(125) atom. In the third O site, O(19) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(150) atom. In the fourth O site, O(16) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(125) atom. In the fifth O site, O(18) is bonded in a distorted single-bond geometry to one Zn(4) and one C(150) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(50) atom. In the seventh O site, O(1) is bonded in a tetrahedral geometry to one Zn(1), one Zn(2), one Zn(3), and one Zn(4) atom. In the eighth O site, O(3) is bonded in a water-like geometry to one Zn(2) and one C(42) atom. In the ninth O site, O(4) is bonded in a single-bond geometry to one C(42) atom. In the tenth O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(50) atom. In the eleventh O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(92) atom. In the twelfth O site, O(10) is bonded in a 2-coordinate geometry to one Zn(4) and one C(92) atom. In the thirteenth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(100) atom. Linkers: 8 [O]C(=O)c1ccc(COc2c3c(c(OCc4ccc(C([O])=O)cc4)c4c2[C@H]2c5ccccc5[C@@H]4c4ccccc42)[C@H]2c4ccccc4[C@@H]3c3ccccc32)cc1. Metal clusters: 1 O=[C]O[Zn@]12O[C]O[Zn]3O[C]O[Zn]O[C]O[Zn@@](O[C]O3)(O[C]O1)O2 ,1 O=[C]O[Zn@@]12O[C]O[Zn]3O[C]O[Zn]O[C]O[Zn@](O[C]O3)(O[C]O1)O2. RCSR code: pcu. The MOF has largest included sphere 8.10 A, density 0.92 g/cm3, surface area 4861.37 m2/g, accessible volume 0.54 cm3/g