Pr2C24H15(NO4)3 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Pr2C24H15(NO4)3 cluster. There are two inequivalent Pr sites. In the first Pr site, Pr(1) is bonded to one O(1), one O(10), one O(3), one O(5), one O(6), one O(7), and one O(8) atom to form distorted edge-sharing PrO7 hexagonal pyramids. The Pr(1)-O(1) bond length is 2.29 Å. The Pr(1)-O(10) bond length is 2.32 Å. The Pr(1)-O(3) bond length is 2.23 Å. The Pr(1)-O(5) bond length is 2.36 Å. The Pr(1)-O(6) bond length is 2.38 Å. The Pr(1)-O(7) bond length is 2.40 Å. The Pr(1)-O(8) bond length is 2.35 Å. In the second Pr site, Pr(2) is bonded to one O(1), one O(11), one O(12), one O(2), one O(4), one O(7), and one O(9) atom to form distorted edge-sharing PrO7 pentagonal bipyramids. The Pr(2)-O(1) bond length is 2.31 Å. The Pr(2)-O(11) bond length is 2.38 Å. The Pr(2)-O(12) bond length is 2.38 Å. The Pr(2)-O(2) bond length is 2.37 Å. The Pr(2)-O(4) bond length is 2.40 Å. The Pr(2)-O(7) bond length is 2.31 Å. The Pr(2)-O(9) bond length is 2.32 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a water-like geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.38 Å. The C(1)-O(2) bond length is 1.21 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(4) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(13) atom. The C(3)-H(13) bond length is 1.08 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(4)-H(1) bond length is 1.08 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(3), and one O(4) atom. The C(5)-C(6) bond length is 1.48 Å. The C(5)-O(3) bond length is 1.28 Å. The C(5)-O(4) bond length is 1.31 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(8) atom. The C(6)-C(7) bond length is 1.43 Å. The C(6)-C(8) bond length is 1.40 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one N(1) atom. The C(7)-N(1) bond length is 1.43 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one H(2) atom. The C(8)-H(2) bond length is 1.08 Å. In the ninth C site, C(9) is bonded in a distorted water-like geometry to one C(10), one O(5), and one O(6) atom. The C(9)-C(10) bond length is 1.56 Å. The C(9)-O(5) bond length is 1.27 Å. The C(9)-O(6) bond length is 1.28 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.43 Å. The C(10)-C(12) bond length is 1.42 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one N(2) atom. The C(11)-N(2) bond length is 1.43 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one H(3) atom. The C(12)-H(3) bond length is 1.08 Å. In the thirteenth C site, C(13) is bonded in a distorted water-like geometry to one C(14), one O(7), and one O(8) atom. The C(13)-C(14) bond length is 1.53 Å. The C(13)-O(7) bond length is 1.38 Å. The C(13)-O(8) bond length is 1.20 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(16) atom. The C(14)-C(15) bond length is 1.43 Å. The C(14)-C(16) bond length is 1.41 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one N(3) atom. The C(15)-N(3) bond length is 1.43 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(14) and one H(8) atom. The C(16)-H(8) bond length is 1.08 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(10), and one O(9) atom. The C(17)-C(18) bond length is 1.47 Å. The C(17)-O(10) bond length is 1.31 Å. The C(17)-O(9) bond length is 1.30 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(20) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-C(20) bond length is 1.39 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(14) atom. The C(19)-H(14) bond length is 1.08 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(18) and one H(9) atom. The C(20)-H(9) bond length is 1.08 Å. In the twenty-first C site, C(21) is bonded in a distorted water-like geometry to one C(22), one O(11), and one O(12) atom. The C(21)-C(22) bond length is 1.55 Å. The C(21)-O(11) bond length is 1.27 Å. The C(21)-O(12) bond length is 1.27 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(24) atom. The C(22)-C(23) bond length is 1.42 Å. The C(22)-C(24) bond length is 1.42 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(15) atom. The C(23)-H(15) bond length is 1.08 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(22) and one H(10) atom. The C(24)-H(10) bond length is 1.08 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(7), one H(4), and one H(5) atom. The N(1)-H(4) bond length is 1.04 Å. The N(1)-H(5) bond length is 1.04 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(11), one H(6), and one H(7) atom. The N(2)-H(6) bond length is 1.04 Å. The N(2)-H(7) bond length is 1.04 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(15), one H(11), and one H(12) atom. The N(3)-H(11) bond length is 1.04 Å. The N(3)-H(12) bond length is 1.04 Å. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(1) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(2) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(2) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(3) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(3) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(3) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Pr(1), one Pr(2), and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Pr(2) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Pr(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Pr(2) and one C(5) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Pr(1) and one C(9) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Pr(1) and one C(9) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Pr(1), one Pr(2), and one C(13) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one Pr(1) and one C(13) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Pr(2) and one C(17) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Pr(1) and one C(17) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Pr(2) and one C(21) atom. In the twelfth O site, O(12) is bonded in a 2-coordinate geometry to one Pr(2) and one C(21) atom. Linkers: 3 Nc1cc(C([O])=O)ccc1C([O])=O. Metal clusters: 1 [O][C]O[Pr]123(O[C]O[Pr]4(O[C]O4)(O[C]O1)O[C]O2)O[C]O3. RCSR code: pcu. The MOF has largest included sphere 6.98 A, density 1.00 g/cm3, surface area 3374.49 m2/g, accessible volume 0.61 cm3/g