Mn3C22N8H12O9(CH)16(CH2)23(CH3)2 is Indium-derived structured and crystallizes in the trigonal R-3 space group. The structure is zero-dimensional and consists of one hundred and forty-four 02329_fluka molecules, three hundred and seventy-eight 02329_fluka molecules, thirty-six 02329_fluka molecules, eighteen ethane molecules, thirty-six isobutylene molecules, and nine Mn3C22N8H12O9 clusters. In each Mn3C22N8H12O9 cluster, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted octahedral geometry to one N(1), one N(3), one N(7), one O(1), one O(3), and one O(8) atom. The Mn(1)-N(1) bond length is 1.96 Å. The Mn(1)-N(3) bond length is 2.28 Å. The Mn(1)-N(7) bond length is 2.24 Å. The Mn(1)-O(1) bond length is 1.86 Å. The Mn(1)-O(3) bond length is 1.93 Å. The Mn(1)-O(8) bond length is 1.99 Å. In the second Mn site, Mn(2) is bonded in a square pyramidal geometry to one N(2), one N(4), one O(2), one O(4), and one O(6) atom. The Mn(2)-N(2) bond length is 2.25 Å. The Mn(2)-N(4) bond length is 1.94 Å. The Mn(2)-O(2) bond length is 1.96 Å. The Mn(2)-O(4) bond length is 1.86 Å. The Mn(2)-O(6) bond length is 1.94 Å. In the third Mn site, Mn(3) is bonded in a distorted octahedral geometry to one N(5), one N(6), one N(8), one O(5), one O(7), and one O(9) atom. The Mn(3)-N(5) bond length is 2.24 Å. The Mn(3)-N(6) bond length is 1.93 Å. The Mn(3)-N(8) bond length is 2.27 Å. The Mn(3)-O(5) bond length is 1.97 Å. The Mn(3)-O(7) bond length is 1.85 Å. The Mn(3)-O(9) bond length is 1.95 Å. There are twenty-two inequivalent C sites. In the first C site, C(45) is bonded in a distorted single-bond geometry to one C(50) and one O(7) atom. The C(45)-C(50) bond length is 1.39 Å. The C(45)-O(7) bond length is 1.34 Å. In the second C site, C(34) is bonded in a water-like geometry to one C(33), one H(38), and one H(39) atom. The C(34)-C(33) bond length is 1.47 Å. The C(34)-H(38) bond length is 0.99 Å. The C(34)-H(39) bond length is 0.99 Å. In the third C site, C(49) is bonded in a distorted single-bond geometry to one C(50) and one H(64) atom. The C(49)-C(50) bond length is 1.38 Å. The C(49)-H(64) bond length is 0.95 Å. In the fourth C site, C(50) is bonded in a trigonal planar geometry to one C(45), one C(49), and one C(51) atom. The C(50)-C(51) bond length is 1.47 Å. In the fifth C site, C(51) is bonded in a distorted bent 120 degrees geometry to one C(50), one N(6), and one O(8) atom. The C(51)-N(6) bond length is 1.32 Å. The C(51)-O(8) bond length is 1.27 Å. In the sixth C site, C(52) is bonded in a distorted bent 120 degrees geometry to one N(7) and one O(9) atom. The C(52)-N(7) bond length is 1.28 Å. The C(52)-O(9) bond length is 1.30 Å. In the seventh C site, C(58) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(75) atom. The C(58)-N(8) bond length is 1.13 Å. The C(58)-H(75) bond length is 0.95 Å. In the eighth C site, C(62) is bonded in a 2-coordinate geometry to one N(8) and one H(78) atom. The C(62)-N(8) bond length is 1.40 Å. The C(62)-H(78) bond length is 0.95 Å. In the ninth C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one O(1) atom. The C(1)-C(6) bond length is 1.41 Å. The C(1)-O(1) bond length is 1.34 Å. In the tenth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.38 Å. The C(5)-H(4) bond length is 0.95 Å. In the eleventh C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.47 Å. In the twelfth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one O(2) atom. The C(7)-N(1) bond length is 1.33 Å. The C(7)-O(2) bond length is 1.28 Å. In the thirteenth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one O(3) atom. The C(8)-C(9) bond length is 1.48 Å. The C(8)-N(2) bond length is 1.31 Å. The C(8)-O(3) bond length is 1.30 Å. In the fourteenth C site, C(9) is bonded in a distorted water-like geometry to one C(8), one H(5), and one H(6) atom. The C(9)-H(5) bond length is 0.99 Å. The C(9)-H(6) bond length is 0.99 Å. In the fifteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(28) atom. The C(20)-N(3) bond length is 1.31 Å. The C(20)-H(28) bond length is 0.95 Å. In the sixteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(31) atom. The C(24)-N(3) bond length is 1.24 Å. The C(24)-H(31) bond length is 0.95 Å. In the seventeenth C site, C(26) is bonded in a distorted single-bond geometry to one C(27), one C(31), and one O(4) atom. The C(26)-C(27) bond length is 1.38 Å. The C(26)-C(31) bond length is 1.42 Å. The C(26)-O(4) bond length is 1.33 Å. In the eighteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(34) atom. The C(27)-H(34) bond length is 0.95 Å. In the nineteenth C site, C(30) is bonded in a distorted single-bond geometry to one C(31) and one H(37) atom. The C(30)-C(31) bond length is 1.37 Å. The C(30)-H(37) bond length is 0.95 Å. In the twentieth C site, C(31) is bonded in a trigonal planar geometry to one C(26), one C(30), and one C(32) atom. The C(31)-C(32) bond length is 1.46 Å. In the twenty-first C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(31), one N(4), and one O(5) atom. The C(32)-N(4) bond length is 1.31 Å. The C(32)-O(5) bond length is 1.29 Å. In the twenty-second C site, C(33) is bonded in a distorted trigonal planar geometry to one C(34), one N(5), and one O(6) atom. The C(33)-N(5) bond length is 1.29 Å. The C(33)-O(6) bond length is 1.32 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(7), and one N(2) atom. The N(1)-N(2) bond length is 1.41 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Mn(2), one C(8), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Mn(1), one C(20), and one C(24) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Mn(2), one C(32), and one N(5) atom. The N(4)-N(5) bond length is 1.41 Å. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one Mn(3), one C(33), and one N(4) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Mn(3), one C(51), and one N(7) atom. The N(6)-N(7) bond length is 1.43 Å. In the seventh N site, N(7) is bonded in a 3-coordinate geometry to one Mn(1), one C(52), and one N(6) atom. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one Mn(3), one C(58), and one C(62) atom. There are twelve inequivalent H sites. In the first H site, H(75) is bonded in a single-bond geometry to one C(58) atom. In the second H site, H(78) is bonded in a single-bond geometry to one C(62) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(28) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(31) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(34) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(38) is bonded in a single-bond geometry to one C(34) atom. In the tenth H site, H(39) is bonded in a single-bond geometry to one C(34) atom. In the eleventh H site, H(37) is bonded in a single-bond geometry to one C(30) atom. In the twelfth H site, H(64) is bonded in a single-bond geometry to one C(49) atom. There are nine inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(26) atom. In the second O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(32) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one Mn(2) and one C(7) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(8) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(33) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(45) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(51) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Mn(3) and one C(52) atom. Linkers: 12 CCCCCCCCCCCC(=O)[N][N]C(=O)c1ccccc1[O] ,6 [CH]1[CH][C](CCc2ccncc2)C=C[N]1 ,6 [CH2]CCCCC(=O)[N][N]C(=O)c1ccccc1[O]. Metal clusters: 18 [Mn]. The MOF has largest included sphere 14.84 A, density 0.80 g/cm3, surface area 5441.01 m2/g, accessible volume 0.75 cm3/g