ZnC19H13(NO2)2(CH)2C2O is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight dimethyl ether molecules, and four ZnC19H13(NO2)2 clusters. In each ZnC19H13(NO2)2 cluster, Zn(1) is bonded in a 5-coordinate geometry to one N(1), one O(2), one O(3), one O(4), and one O(5) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.01 Å. The Zn(1)-O(3) bond length is 2.30 Å. The Zn(1)-O(4) bond length is 2.00 Å. The Zn(1)-O(5) bond length is 1.96 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-C(7) bond length is 1.48 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.95 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.95 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(2), and one O(3) atom. The C(7)-O(2) bond length is 1.29 Å. The C(7)-O(3) bond length is 1.25 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-H(5) bond length is 0.95 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(6) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(6) bond length is 0.95 Å. In the seventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(4), and one O(5) atom. The C(14)-C(11) bond length is 1.50 Å. The C(14)-O(4) bond length is 1.27 Å. The C(14)-O(5) bond length is 1.25 Å. In the eighth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one N(1), and one H(9) atom. The C(15)-C(16) bond length is 1.36 Å. The C(15)-N(1) bond length is 1.34 Å. The C(15)-H(9) bond length is 0.95 Å. In the ninth C site, C(16) is bonded in a single-bond geometry to one C(15), one C(17), and one H(10) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(10) bond length is 0.95 Å. In the tenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-C(20) bond length is 1.49 Å. In the eleventh C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(11) atom. The C(18)-H(11) bond length is 0.95 Å. In the twelfth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(12) atom. The C(19)-N(1) bond length is 1.36 Å. The C(19)-H(12) bond length is 0.95 Å. In the thirteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(2), and one H(13) atom. The C(20)-N(2) bond length is 1.26 Å. The C(20)-H(13) bond length is 0.95 Å. In the fourteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one C(23), and one N(2) atom. The C(21)-C(22) bond length is 1.42 Å. The C(21)-C(23) bond length is 1.38 Å. The C(21)-N(2) bond length is 1.42 Å. In the fifteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(14,15) atom. The C(22)-H(14,15) bond length is 0.95 Å. In the sixteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(21) and one H(14,15) atom. The C(23)-H(14,15) bond length is 0.95 Å. In the seventeenth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.39 Å. In the eighteenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(7) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(7) bond length is 0.95 Å. In the nineteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(8) atom. The C(13)-H(8) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(19) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(20) and one C(21) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(14,15) is bonded in a single-bond geometry to one C(22) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in an L-shaped geometry to one Zn(1) and one C(7) atom. In the second O site, O(3) is bonded in a distorted single-bond geometry to one Zn(1) and one C(7) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the fourth O site, O(5) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(14) atom. Linkers: 5 C(=N/c1ccc(/N=C/c2ccncc2)cc1)\c1ccncc1 ,8 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 [C]1O[Zn]2(O1)O[C]O[Zn]1(O[C]O1)O[C]O2. RCSR code: sql. The MOF has largest included sphere 7.52 A, density 1.14 g/cm3, surface area 4676.12 m2/g, accessible volume 0.37 cm3/g