Co3C30NH16O14 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four Co3C30NH16O14 clusters. There are three inequivalent Co sites. In the first Co site, Co(1) is bonded in a 5-coordinate geometry to one O(12), one O(13), one O(4), one O(7), and one O(9) atom. The Co(1)-O(12) bond length is 2.37 Å. The Co(1)-O(13) bond length is 1.97 Å. The Co(1)-O(4) bond length is 1.99 Å. The Co(1)-O(7) bond length is 1.97 Å. The Co(1)-O(9) bond length is 2.06 Å. In the second Co site, Co(2) is bonded in a 5-coordinate geometry to one N(1), one O(10), one O(11), one O(2), and one O(8) atom. The Co(2)-N(1) bond length is 2.11 Å. The Co(2)-O(10) bond length is 2.11 Å. The Co(2)-O(11) bond length is 2.28 Å. The Co(2)-O(2) bond length is 2.02 Å. The Co(2)-O(8) bond length is 2.02 Å. In the third Co site, Co(3) is bonded in an octahedral geometry to one O(1), one O(10), one O(3), one O(5), one O(6), and one O(9) atom. The Co(3)-O(1) bond length is 2.06 Å. The Co(3)-O(10) bond length is 2.12 Å. The Co(3)-O(3) bond length is 2.07 Å. The Co(3)-O(5) bond length is 2.05 Å. The Co(3)-O(6) bond length is 2.05 Å. The Co(3)-O(9) bond length is 2.18 Å. There are thirty inequivalent C sites. In the first C site, C(3) is bonded in a trigonal planar geometry to one C(12), one C(20), and one C(26) atom. The C(3)-C(12) bond length is 1.49 Å. The C(3)-C(20) bond length is 1.37 Å. The C(3)-C(26) bond length is 1.43 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(5), and one O(8) atom. The C(5)-C(8) bond length is 1.53 Å. The C(5)-O(5) bond length is 1.24 Å. The C(5)-O(8) bond length is 1.24 Å. In the third C site, C(8) is bonded in a trigonal planar geometry to one C(15), one C(22), and one C(5) atom. The C(8)-C(15) bond length is 1.36 Å. The C(8)-C(22) bond length is 1.39 Å. In the fourth C site, C(20) is bonded in a distorted single-bond geometry to one C(3) and one H(9) atom. The C(20)-H(9) bond length is 0.93 Å. In the fifth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(2), and one O(6) atom. The C(12)-O(2) bond length is 1.26 Å. The C(12)-O(6) bond length is 1.25 Å. In the sixth C site, C(15) is bonded in a distorted single-bond geometry to one C(8) and one H(4) atom. The C(15)-H(4) bond length is 0.93 Å. In the seventh C site, C(1) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(27) atom. The C(1)-C(17) bond length is 1.38 Å. The C(1)-C(19) bond length is 1.41 Å. The C(1)-C(27) bond length is 1.47 Å. In the eighth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(4) atom. The C(2)-C(4) bond length is 1.50 Å. The C(2)-O(1) bond length is 1.23 Å. The C(2)-O(4) bond length is 1.27 Å. In the ninth C site, C(4) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(21) atom. The C(4)-C(14) bond length is 1.39 Å. The C(4)-C(21) bond length is 1.37 Å. In the tenth C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(18), and one C(25) atom. The C(7)-C(11) bond length is 1.49 Å. The C(7)-C(18) bond length is 1.40 Å. The C(7)-C(25) bond length is 1.37 Å. In the eleventh C site, C(10) is bonded in a bent 120 degrees geometry to one C(9), one O(12), and one O(9) atom. The C(10)-C(9) bond length is 1.48 Å. The C(10)-O(12) bond length is 1.23 Å. The C(10)-O(9) bond length is 1.27 Å. In the twelfth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(3), and one O(7) atom. The C(11)-O(3) bond length is 1.23 Å. The C(11)-O(7) bond length is 1.27 Å. In the thirteenth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(6) atom. The C(9)-C(13) bond length is 1.43 Å. The C(9)-C(6) bond length is 1.38 Å. In the fourteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(9) and one H(1) atom. The C(6)-H(1) bond length is 0.93 Å. In the fifteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(16)-N(1) bond length is 1.28 Å. The C(16)-H(5) bond length is 0.93 Å. In the sixteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(9) and one H(2) atom. The C(13)-H(2) bond length is 0.93 Å. In the seventeenth C site, C(14) is bonded in a single-bond geometry to one C(4) and one H(3) atom. The C(14)-H(3) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a single-bond geometry to one C(7) and one H(7) atom. The C(18)-H(7) bond length is 0.93 Å. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(4) and one H(10) atom. The C(21)-H(10) bond length is 0.93 Å. In the twentieth C site, C(17) is bonded in a distorted single-bond geometry to one C(1) and one H(6) atom. The C(17)-H(6) bond length is 0.93 Å. In the twenty-first C site, C(23) is bonded in a distorted single-bond geometry to one C(28) and one H(12) atom. The C(23)-C(28) bond length is 1.34 Å. The C(23)-H(12) bond length is 0.93 Å. In the twenty-second C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(24)-N(1) bond length is 1.33 Å. The C(24)-H(13) bond length is 0.93 Å. In the twenty-third C site, C(25) is bonded in a distorted single-bond geometry to one C(7) and one H(14) atom. The C(25)-H(14) bond length is 0.93 Å. In the twenty-fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(3) and one H(15) atom. The C(26)-H(15) bond length is 0.93 Å. In the twenty-fifth C site, C(19) is bonded in a distorted single-bond geometry to one C(1) and one H(8) atom. The C(19)-H(8) bond length is 0.93 Å. In the twenty-sixth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(10), and one O(11) atom. The C(27)-O(10) bond length is 1.27 Å. The C(27)-O(11) bond length is 1.24 Å. In the twenty-seventh C site, C(28) is bonded in a trigonal planar geometry to one C(23), one C(29), and one C(30) atom. The C(28)-C(29) bond length is 1.50 Å. The C(28)-C(30) bond length is 1.33 Å. In the twenty-eighth C site, C(29) is bonded in a bent 120 degrees geometry to one C(28), one O(13), and one O(14) atom. The C(29)-O(13) bond length is 1.23 Å. The C(29)-O(14) bond length is 1.21 Å. In the twenty-ninth C site, C(30) is bonded in a distorted single-bond geometry to one C(28) and one H(16) atom. The C(30)-H(16) bond length is 0.93 Å. In the thirtieth C site, C(22) is bonded in a distorted single-bond geometry to one C(8) and one H(11) atom. The C(22)-H(11) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Co(2), one C(16), and one C(24) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(30) atom. There are fourteen inequivalent O sites. In the first O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Co(3) and one C(5) atom. In the second O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Co(3) and one C(12) atom. In the third O site, O(1) is bonded in a bent 150 degrees geometry to one Co(3) and one C(2) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one Co(2) and one C(12) atom. In the fifth O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Co(3) and one C(11) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one C(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Co(1) and one C(11) atom. In the eighth O site, O(9) is bonded in a distorted trigonal non-coplanar geometry to one Co(1), one Co(3), and one C(10) atom. In the ninth O site, O(10) is bonded in a 3-coordinate geometry to one Co(2), one Co(3), and one C(27) atom. In the tenth O site, O(11) is bonded in a distorted single-bond geometry to one Co(2) and one C(27) atom. In the eleventh O site, O(12) is bonded in a distorted L-shaped geometry to one Co(1) and one C(10) atom. In the twelfth O site, O(13) is bonded in a bent 120 degrees geometry to one Co(1) and one C(29) atom. In the thirteenth O site, O(14) is bonded in a single-bond geometry to one C(29) atom. In the fourteenth O site, O(8) is bonded in a bent 120 degrees geometry to one Co(2) and one C(5) atom. Linkers: 12 [O]C(=O)c1ccc(C([O])=O)cc1 ,4 [O]C(=O)c1ccncc1. Metal clusters: 4 O=[C]O[Co]1(O[C]=O)O[C]O[Co]2(O[C]O[Co]3(O[C]O3)O[C]O2)O[C]O1. The MOF has largest included sphere 7.05 A, density 0.97 g/cm3, surface area 3782.52 m2/g, accessible volume 0.56 cm3/g