Mn16H95(C3O)64 crystallizes in the triclinic P1 space group. There are five inequivalent Mn sites. In the first Mn site, Mn(1,3,7,9,13,15) is bonded in a distorted square pyramidal geometry to one O(2,10,26,34,50,58); one O(3,11,27,35,43,51,59); one O(5,13,21,37,45,53,61); one O(6,14,22,46,54,62); and one O(8,16,24,32,40,48,56) atom. The Mn(1,3,7,9,13,15)-O(2,10,26,34,50,58) bond length is 2.12 Å. The Mn(1,3,7,9,13,15)-O(3,11,27,35,43,51,59) bond length is 2.18 Å. The Mn(1,3,7,9,13,15)-O(5,13,21,37,45,53,61) bond length is 2.22 Å. The Mn(1,3,7,9,13,15)-O(6,14,22,46,54,62) bond length is 2.44 Å. The Mn(1,3,7,9,13,15)-O(8,16,24,32,40,48,56) bond length is 2.08 Å. In the second Mn site, Mn(2,4,6,8,10,14,16) is bonded in a rectangular see-saw-like geometry to one O(1,9,17,25,33,49,57); one O(4,12,20,28,36,52,60); one O(6,14,22,46,54,62); and one O(7,15,23,31,39,47,55) atom. The Mn(2,4,6,8,10,14,16)-O(1,9,17,25,33,49,57) bond length is 2.13 Å. The Mn(2,4,6,8,10,14,16)-O(4,12,20,28,36,52,60) bond length is 2.13 Å. The Mn(2,4,6,8,10,14,16)-O(6,14,22,46,54,62) bond length is 2.24 Å. The Mn(2,4,6,8,10,14,16)-O(7,15,23,31,39,47,55) bond length is 2.17 Å. In the third Mn site, Mn(5) is bonded in a distorted square pyramidal geometry to one O(18), one O(19), one O(29), one O(30), and one O(64) atom. The Mn(5)-O(18) bond length is 2.12 Å. The Mn(5)-O(19) bond length is 2.18 Å. The Mn(5)-O(29) bond length is 2.22 Å. The Mn(5)-O(30) bond length is 2.44 Å. The Mn(5)-O(64) bond length is 2.08 Å. In the fourth Mn site, Mn(11) is bonded in a distorted square pyramidal geometry to one O(3,11,27,35,43,51,59); one O(38); one O(42); one O(5,13,21,37,45,53,61); and one O(8,16,24,32,40,48,56) atom. The Mn(11)-O(3,11,27,35,43,51,59) bond length is 2.18 Å. The Mn(11)-O(38) bond length is 2.44 Å. The Mn(11)-O(42) bond length is 2.12 Å. The Mn(11)-O(5,13,21,37,45,53,61) bond length is 2.22 Å. The Mn(11)-O(8,16,24,32,40,48,56) bond length is 2.08 Å. In the fifth Mn site, Mn(12) is bonded in a rectangular see-saw-like geometry to one O(38), one O(41), one O(44), and one O(63) atom. The Mn(12)-O(38) bond length is 2.24 Å. The Mn(12)-O(41) bond length is 2.13 Å. The Mn(12)-O(44) bond length is 2.13 Å. The Mn(12)-O(63) bond length is 2.17 Å. There are forty-four inequivalent C sites. In the first C site, C(1,25,49,73,97,145,169) is bonded in a distorted single-bond geometry to one C(2,26,50,74,98,146,170); one C(9,33,57,81,105,153,177); and one H(1,13,25,37,49,72,84) atom. The C(1,25,49,73,97,145,169)-C(2,26,50,74,98,146,170) bond length is 1.37 Å. The C(1,25,49,73,97,145,169)-C(9,33,57,81,105,153,177) bond length is 1.42 Å. The C(1,25,49,73,97,145,169)-H(1,13,25,37,49,72,84) bond length is 1.14 Å. In the second C site, C(2,26,50,74,98,146,170) is bonded in a trigonal planar geometry to one C(1,25,49,73,97,145,169); one C(11,35,59,83,107,155,179); and one C(3,27,51,75,99,147,171) atom. The C(2,26,50,74,98,146,170)-C(11,35,59,83,107,155,179) bond length is 1.51 Å. The C(2,26,50,74,98,146,170)-C(3,27,51,75,99,147,171) bond length is 1.41 Å. In the third C site, C(3,27,51,75,99,147,171) is bonded in a distorted trigonal planar geometry to one C(2,26,50,74,98,146,170); one C(4,28,52,76,100,148,172); and one H(2,14,26,38,50,73,85) atom. The C(3,27,51,75,99,147,171)-C(4,28,52,76,100,148,172) bond length is 1.37 Å. The C(3,27,51,75,99,147,171)-H(2,14,26,38,50,73,85) bond length is 1.14 Å. In the fourth C site, C(4,28,52,76,100,148,172) is bonded in a distorted trigonal planar geometry to one C(10,34,58,82,106,154,178); one C(3,27,51,75,99,147,171); and one H(3,15,27,39,51,62,74,86) atom. The C(4,28,52,76,100,148,172)-C(10,34,58,82,106,154,178) bond length is 1.41 Å. The C(4,28,52,76,100,148,172)-H(3,15,27,39,51,62,74,86) bond length is 1.14 Å. In the fifth C site, C(5,29,53,77,101,149,173) is bonded in a distorted trigonal planar geometry to one C(10,34,58,82,106,154,178); one C(6,30,54,78,102,126,150,174); and one H(4,16,28,40,52,63,75,87) atom. The C(5,29,53,77,101,149,173)-C(10,34,58,82,106,154,178) bond length is 1.41 Å. The C(5,29,53,77,101,149,173)-C(6,30,54,78,102,126,150,174) bond length is 1.36 Å. The C(5,29,53,77,101,149,173)-H(4,16,28,40,52,63,75,87) bond length is 1.14 Å. In the sixth C site, C(6,30,54,78,102,126,150,174) is bonded in a trigonal planar geometry to one C(12,36,60,84,108,132,156,180); one C(5,29,53,77,101,149,173); and one C(7,31,55,79,103,127,151,175) atom. The C(6,30,54,78,102,126,150,174)-C(12,36,60,84,108,132,156,180) bond length is 1.50 Å. The C(6,30,54,78,102,126,150,174)-C(7,31,55,79,103,127,151,175) bond length is 1.41 Å. In the seventh C site, C(7,31,55,79,103,127,151,175) is bonded in a distorted single-bond geometry to one C(6,30,54,78,102,126,150,174) and one H(5,17,29,41,53,64,76,88) atom. The C(7,31,55,79,103,127,151,175)-H(5,17,29,41,53,64,76,88) bond length is 1.14 Å. In the eighth C site, C(8,32,56,80,104,152,176) is bonded in a distorted single-bond geometry to one C(9,33,57,81,105,153,177) and one H(6,18,30,42,54,77,89) atom. The C(8,32,56,80,104,152,176)-C(9,33,57,81,105,153,177) bond length is 1.41 Å. The C(8,32,56,80,104,152,176)-H(6,18,30,42,54,77,89) bond length is 1.14 Å. In the ninth C site, C(9,33,57,81,105,153,177) is bonded in a trigonal planar geometry to one C(1,25,49,73,97,145,169); one C(10,34,58,82,106,154,178); and one C(8,32,56,80,104,152,176) atom. The C(9,33,57,81,105,153,177)-C(10,34,58,82,106,154,178) bond length is 1.42 Å. In the tenth C site, C(10,34,58,82,106,154,178) is bonded in a trigonal planar geometry to one C(4,28,52,76,100,148,172); one C(5,29,53,77,101,149,173); and one C(9,33,57,81,105,153,177) atom. In the eleventh C site, C(11,35,59,83,107,155,179) is bonded in a distorted bent 120 degrees geometry to one C(2,26,50,74,98,146,170); one O(1,9,17,25,33,49,57); and one O(2,10,26,34,50,58) atom. The C(11,35,59,83,107,155,179)-O(1,9,17,25,33,49,57) bond length is 1.26 Å. The C(11,35,59,83,107,155,179)-O(2,10,26,34,50,58) bond length is 1.25 Å. In the twelfth C site, C(12,36,60,84,108,132,156,180) is bonded in a distorted bent 120 degrees geometry to one C(6,30,54,78,102,126,150,174); one O(5,13,21,37,45,53,61); and one O(6,14,22,46,54,62) atom. The C(12,36,60,84,108,132,156,180)-O(5,13,21,37,45,53,61) bond length is 1.25 Å. The C(12,36,60,84,108,132,156,180)-O(6,14,22,46,54,62) bond length is 1.27 Å. In the thirteenth C site, C(13,37,85,109,133,157,181) is bonded in a distorted trigonal planar geometry to one C(14,38,62,86,110,134,158,182); one C(20,44,68,92,116,140,164,188); and one H(7,19,31,43,55,66,78,90) atom. The C(13,37,85,109,133,157,181)-C(14,38,62,86,110,134,158,182) bond length is 1.41 Å. The C(13,37,85,109,133,157,181)-C(20,44,68,92,116,140,164,188) bond length is 1.37 Å. The C(13,37,85,109,133,157,181)-H(7,19,31,43,55,66,78,90) bond length is 1.14 Å. In the fourteenth C site, C(14,38,62,86,110,134,158,182) is bonded in a trigonal planar geometry to one C(13,37,85,109,133,157,181); one C(15,39,87,111,135,159,183); and one C(23,47,95,119,143,167,191) atom. The C(14,38,62,86,110,134,158,182)-C(15,39,87,111,135,159,183) bond length is 1.36 Å. The C(14,38,62,86,110,134,158,182)-C(23,47,95,119,143,167,191) bond length is 1.50 Å. In the fifteenth C site, C(15,39,87,111,135,159,183) is bonded in a distorted trigonal planar geometry to one C(14,38,62,86,110,134,158,182); one C(21,45,69,93,117,141,165,189); and one H(8,20,32,44,56,67,79,91) atom. The C(15,39,87,111,135,159,183)-C(21,45,69,93,117,141,165,189) bond length is 1.42 Å. The C(15,39,87,111,135,159,183)-H(8,20,32,44,56,67,79,91) bond length is 1.14 Å. In the sixteenth C site, C(16,40,88,112,136,160) is bonded in a distorted trigonal planar geometry to one C(17,41,65,89,113,137,161); one C(21,45,69,93,117,141,165,189); and one H(9,21,33,45,57,68,80,92) atom. The C(16,40,88,112,136,160)-C(17,41,65,89,113,137,161) bond length is 1.36 Å. The C(16,40,88,112,136,160)-C(21,45,69,93,117,141,165,189) bond length is 1.41 Å. The C(16,40,88,112,136,160)-H(9,21,33,45,57,68,80,92) bond length is 1.14 Å. In the seventeenth C site, C(17,41,65,89,113,137,161) is bonded in a distorted trigonal planar geometry to one C(16,40,88,112,136,160); one C(18,42,66,90,114,138,162); and one H(10,22,34,46,58,69,81) atom. The C(17,41,65,89,113,137,161)-C(18,42,66,90,114,138,162) bond length is 1.41 Å. The C(17,41,65,89,113,137,161)-H(10,22,34,46,58,69,81) bond length is 1.14 Å. In the eighteenth C site, C(18,42,66,90,114,138,162) is bonded in a trigonal planar geometry to one C(17,41,65,89,113,137,161); one C(19,43,67,91,115,139,163); and one C(24,48,72,96,120,144,168) atom. The C(18,42,66,90,114,138,162)-C(19,43,67,91,115,139,163) bond length is 1.36 Å. The C(18,42,66,90,114,138,162)-C(24,48,72,96,120,144,168) bond length is 1.51 Å. In the nineteenth C site, C(19,43,67,91,115,139,163) is bonded in a distorted trigonal planar geometry to one C(18,42,66,90,114,138,162); one C(22,46,94,118,142,166); and one H(11,23,35,47,59,70,82) atom. The C(19,43,67,91,115,139,163)-C(22,46,94,118,142,166) bond length is 1.41 Å. The C(19,43,67,91,115,139,163)-H(11,23,35,47,59,70,82) bond length is 1.14 Å. In the twentieth C site, C(20,44,68,92,116,140,164,188) is bonded in a distorted trigonal planar geometry to one C(13,37,85,109,133,157,181); one C(22,46,94,118,142,166); and one H(12,24,36,48,60,71,83,95) atom. The C(20,44,68,92,116,140,164,188)-C(22,46,94,118,142,166) bond length is 1.41 Å. The C(20,44,68,92,116,140,164,188)-H(12,24,36,48,60,71,83,95) bond length is 1.14 Å. In the twenty-first C site, C(21,45,69,93,117,141,165,189) is bonded in a trigonal planar geometry to one C(15,39,87,111,135,159,183); one C(16,40,88,112,136,160); and one C(22,46,94,118,142,166) atom. The C(21,45,69,93,117,141,165,189)-C(22,46,94,118,142,166) bond length is 1.42 Å. In the twenty-second C site, C(22,46,94,118,142,166) is bonded in a trigonal planar geometry to one C(19,43,67,91,115,139,163); one C(20,44,68,92,116,140,164,188); and one C(21,45,69,93,117,141,165,189) atom. In the twenty-third C site, C(23,47,95,119,143,167,191) is bonded in a distorted bent 120 degrees geometry to one C(14,38,62,86,110,134,158,182); one O(3,11,27,35,43,51,59); and one O(4,12,20,28,36,52,60) atom. The C(23,47,95,119,143,167,191)-O(3,11,27,35,43,51,59) bond length is 1.26 Å. The C(23,47,95,119,143,167,191)-O(4,12,20,28,36,52,60) bond length is 1.25 Å. In the twenty-fourth C site, C(24,48,72,96,120,144,168) is bonded in a distorted bent 120 degrees geometry to one C(18,42,66,90,114,138,162); one O(7,15,23,31,39,47,55); and one O(8,16,24,32,40,48,56) atom. The C(24,48,72,96,120,144,168)-O(7,15,23,31,39,47,55) bond length is 1.25 Å. The C(24,48,72,96,120,144,168)-O(8,16,24,32,40,48,56) bond length is 1.25 Å. In the twenty-fifth C site, C(61) is bonded in a distorted trigonal planar geometry to one C(14,38,62,86,110,134,158,182); one C(20,44,68,92,116,140,164,188); and one H(7,19,31,43,55,66,78,90) atom. The C(61)-C(14,38,62,86,110,134,158,182) bond length is 1.41 Å. The C(61)-C(20,44,68,92,116,140,164,188) bond length is 1.37 Å. The C(61)-H(7,19,31,43,55,66,78,90) bond length is 1.14 Å. In the twenty-sixth C site, C(63) is bonded in a distorted trigonal planar geometry to one C(14,38,62,86,110,134,158,182); one C(21,45,69,93,117,141,165,189); and one H(8,20,32,44,56,67,79,91) atom. The C(63)-C(14,38,62,86,110,134,158,182) bond length is 1.36 Å. The C(63)-C(21,45,69,93,117,141,165,189) bond length is 1.42 Å. The C(63)-H(8,20,32,44,56,67,79,91) bond length is 1.14 Å. In the twenty-seventh C site, C(64) is bonded in a distorted trigonal planar geometry to one C(17,41,65,89,113,137,161); one C(21,45,69,93,117,141,165,189); and one H(9,21,33,45,57,68,80,92) atom. The C(64)-C(17,41,65,89,113,137,161) bond length is 1.36 Å. The C(64)-C(21,45,69,93,117,141,165,189) bond length is 1.41 Å. The C(64)-H(9,21,33,45,57,68,80,92) bond length is 1.14 Å. In the twenty-eighth C site, C(70) is bonded in a trigonal planar geometry to one C(19,43,67,91,115,139,163); one C(20,44,68,92,116,140,164,188); and one C(21,45,69,93,117,141,165,189) atom. The C(70)-C(19,43,67,91,115,139,163) bond length is 1.41 Å. The C(70)-C(20,44,68,92,116,140,164,188) bond length is 1.41 Å. The C(70)-C(21,45,69,93,117,141,165,189) bond length is 1.42 Å. In the twenty-ninth C site, C(71) is bonded in a distorted bent 120 degrees geometry to one C(14,38,62,86,110,134,158,182); one O(19); and one O(4,12,20,28,36,52,60) atom. The C(71)-C(14,38,62,86,110,134,158,182) bond length is 1.50 Å. The C(71)-O(19) bond length is 1.26 Å. The C(71)-O(4,12,20,28,36,52,60) bond length is 1.25 Å. In the thirtieth C site, C(121) is bonded in a bent 120 degrees geometry to one C(122) and one C(129) atom. The C(121)-C(122) bond length is 1.37 Å. The C(121)-C(129) bond length is 1.42 Å. In the thirty-first C site, C(122) is bonded in a trigonal planar geometry to one C(121), one C(123), and one C(131) atom. The C(122)-C(123) bond length is 1.41 Å. The C(122)-C(131) bond length is 1.51 Å. In the thirty-second C site, C(123) is bonded in a distorted trigonal planar geometry to one C(122), one C(124), and one H(61) atom. The C(123)-C(124) bond length is 1.37 Å. The C(123)-H(61) bond length is 1.14 Å. In the thirty-third C site, C(124) is bonded in a distorted trigonal planar geometry to one C(123); one C(130); and one H(3,15,27,39,51,62,74,86) atom. The C(124)-C(130) bond length is 1.41 Å. The C(124)-H(3,15,27,39,51,62,74,86) bond length is 1.14 Å. In the thirty-fourth C site, C(125) is bonded in a distorted trigonal planar geometry to one C(130); one C(6,30,54,78,102,126,150,174); and one H(4,16,28,40,52,63,75,87) atom. The C(125)-C(130) bond length is 1.41 Å. The C(125)-C(6,30,54,78,102,126,150,174) bond length is 1.36 Å. The C(125)-H(4,16,28,40,52,63,75,87) bond length is 1.14 Å. In the thirty-fifth C site, C(128) is bonded in a distorted single-bond geometry to one C(129) and one H(65) atom. The C(128)-C(129) bond length is 1.41 Å. The C(128)-H(65) bond length is 1.14 Å. In the thirty-sixth C site, C(129) is bonded in a trigonal planar geometry to one C(121), one C(128), and one C(130) atom. The C(129)-C(130) bond length is 1.42 Å. In the thirty-seventh C site, C(130) is bonded in a trigonal planar geometry to one C(124), one C(125), and one C(129) atom. In the thirty-eighth C site, C(131) is bonded in a distorted bent 120 degrees geometry to one C(122), one O(41), and one O(42) atom. The C(131)-O(41) bond length is 1.26 Å. The C(131)-O(42) bond length is 1.25 Å. In the thirty-ninth C site, C(184) is bonded in a distorted trigonal planar geometry to one C(185); one C(21,45,69,93,117,141,165,189); and one H(9,21,33,45,57,68,80,92) atom. The C(184)-C(185) bond length is 1.36 Å. The C(184)-C(21,45,69,93,117,141,165,189) bond length is 1.41 Å. The C(184)-H(9,21,33,45,57,68,80,92) bond length is 1.14 Å. In the fortieth C site, C(185) is bonded in a distorted trigonal planar geometry to one C(184), one C(186), and one H(93) atom. The C(185)-C(186) bond length is 1.41 Å. The C(185)-H(93) bond length is 1.14 Å. In the forty-first C site, C(186) is bonded in a trigonal planar geometry to one C(185), one C(187), and one C(192) atom. The C(186)-C(187) bond length is 1.36 Å. The C(186)-C(192) bond length is 1.51 Å. In the forty-second C site, C(187) is bonded in a distorted trigonal planar geometry to one C(186), one C(190), and one H(94) atom. The C(187)-C(190) bond length is 1.41 Å. The C(187)-H(94) bond length is 1.14 Å. In the forty-third C site, C(190) is bonded in a trigonal planar geometry to one C(187); one C(20,44,68,92,116,140,164,188); and one C(21,45,69,93,117,141,165,189) atom. The C(190)-C(20,44,68,92,116,140,164,188) bond length is 1.41 Å. The C(190)-C(21,45,69,93,117,141,165,189) bond length is 1.42 Å. In the forty-fourth C site, C(192) is bonded in a distorted bent 120 degrees geometry to one C(186), one O(63), and one O(64) atom. The C(192)-O(63) bond length is 1.25 Å. The C(192)-O(64) bond length is 1.25 Å. There are sixteen inequivalent H sites. In the first H site, H(1,13,25,37,49,72,84) is bonded in a single-bond geometry to one C(1,25,49,73,97,145,169) atom. In the second H site, H(2,14,26,38,50,73,85) is bonded in a single-bond geometry to one C(3,27,51,75,99,147,171) atom. In the third H site, H(3,15,27,39,51,62,74,86) is bonded in a single-bond geometry to one C(4,28,52,76,100,148,172) atom. In the fourth H site, H(4,16,28,40,52,63,75,87) is bonded in a single-bond geometry to one C(5,29,53,77,101,149,173) atom. In the fifth H site, H(5,17,29,41,53,64,76,88) is bonded in a single-bond geometry to one C(7,31,55,79,103,127,151,175) atom. In the sixth H site, H(6,18,30,42,54,77,89) is bonded in a single-bond geometry to one C(8,32,56,80,104,152,176) atom. In the seventh H site, H(7,19,31,43,55,66,78,90) is bonded in a single-bond geometry to one C(13,37,85,109,133,157,181) atom. In the eighth H site, H(8,20,32,44,56,67,79,91) is bonded in a single-bond geometry to one C(15,39,87,111,135,159,183) atom. In the ninth H site, H(9,21,33,45,57,68,80,92) is bonded in a single-bond geometry to one C(16,40,88,112,136,160) atom. In the tenth H site, H(10,22,34,46,58,69,81) is bonded in a single-bond geometry to one C(17,41,65,89,113,137,161) atom. In the eleventh H site, H(11,23,35,47,59,70,82) is bonded in a single-bond geometry to one C(19,43,67,91,115,139,163) atom. In the twelfth H site, H(12,24,36,48,60,71,83,95) is bonded in a single-bond geometry to one C(20,44,68,92,116,140,164,188) atom. In the thirteenth H site, H(61) is bonded in a single-bond geometry to one C(123) atom. In the fourteenth H site, H(65) is bonded in a single-bond geometry to one C(128) atom. In the fifteenth H site, H(93) is bonded in a single-bond geometry to one C(185) atom. In the sixteenth H site, H(94) is bonded in a single-bond geometry to one C(187) atom. There are eighteen inequivalent O sites. In the first O site, O(1,9,17,25,33,49,57) is bonded in a distorted bent 150 degrees geometry to one Mn(2,4,6,8,10,14,16) and one C(11,35,59,83,107,155,179) atom. In the second O site, O(2,10,26,34,50,58) is bonded in a bent 120 degrees geometry to one Mn(1,3,7,9,13,15) and one C(11,35,59,83,107,155,179) atom. In the third O site, O(3,11,27,35,43,51,59) is bonded in a bent 120 degrees geometry to one Mn(1,3,7,9,13,15) and one C(23,47,95,119,143,167,191) atom. In the fourth O site, O(4,12,20,28,36,52,60) is bonded in a bent 150 degrees geometry to one Mn(2,4,6,8,10,14,16) and one C(23,47,95,119,143,167,191) atom. In the fifth O site, O(5,13,21,37,45,53,61) is bonded in an L-shaped geometry to one Mn(1,3,7,9,13,15) and one C(12,36,60,84,108,132,156,180) atom. In the sixth O site, O(6,14,22,46,54,62) is bonded in a distorted T-shaped geometry to one Mn(1,3,7,9,13,15); one Mn(2,4,6,8,10,14,16); and one C(12,36,60,84,108,132,156,180) atom. In the seventh O site, O(7,15,23,31,39,47,55) is bonded in a distorted bent 120 degrees geometry to one Mn(2,4,6,8,10,14,16) and one C(24,48,72,96,120,144,168) atom. In the eighth O site, O(8,16,24,32,40,48,56) is bonded in a bent 150 degrees geometry to one Mn(11) and one C(24,48,72,96,120,144,168) atom. In the ninth O site, O(18) is bonded in a bent 120 degrees geometry to one Mn(5) and one C(11,35,59,83,107,155,179) atom. The O(18)-C(11,35,59,83,107,155,179) bond length is 1.25 Å. In the tenth O site, O(19) is bonded in a bent 120 degrees geometry to one Mn(5) and one C(71) atom. In the eleventh O site, O(29) is bonded in an L-shaped geometry to one Mn(5) and one C(12,36,60,84,108,132,156,180) atom. The O(29)-C(12,36,60,84,108,132,156,180) bond length is 1.25 Å. In the twelfth O site, O(30) is bonded in a distorted T-shaped geometry to one Mn(2,4,6,8,10,14,16); one Mn(5); and one C(12,36,60,84,108,132,156,180) atom. The O(30)-Mn(2,4,6,8,10,14,16) bond length is 2.24 Å. The O(30)-C(12,36,60,84,108,132,156,180) bond length is 1.27 Å. In the thirteenth O site, O(38) is bonded in a distorted T-shaped geometry to one Mn(11); one Mn(12); and one C(12,36,60,84,108,132,156,180) atom. The O(38)-C(12,36,60,84,108,132,156,180) bond length is 1.27 Å. In the fourteenth O site, O(41) is bonded in a distorted bent 150 degrees geometry to one Mn(12) and one C(131) atom. In the fifteenth O site, O(42) is bonded in a bent 120 degrees geometry to one Mn(11) and one C(131) atom. In the sixteenth O site, O(44) is bonded in a bent 150 degrees geometry to one Mn(12) and one C(23,47,95,119,143,167,191) atom. The O(44)-C(23,47,95,119,143,167,191) bond length is 1.25 Å. In the seventeenth O site, O(63) is bonded in a distorted bent 120 degrees geometry to one Mn(12) and one C(192) atom. In the eighteenth O site, O(64) is bonded in a bent 150 degrees geometry to one Mn(5) and one C(192) atom. Linkers: 15 [O]C(=O)c1ccc2cc(C([O])=O)ccc2c1 ,1 [O]C(=O)c1[c]c2ccc(C([O])=O)cc2cc1. Metal clusters: 16 [Mn]. The MOF has largest included sphere 6.02 A, density 1.02 g/cm3, surface area 4261.85 m2/g, accessible volume 0.50 cm3/g