ZnC11NH10O4(C3H2)2 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of four 2,3-dimethyl-1,3-butadiene molecules and two ZnC11NH10O4 clusters. In each ZnC11NH10O4 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1,3) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one O(1), one O(6), one O(7), and one O(8) atom. The Zn(1,3)-N(1) bond length is 1.93 Å. The Zn(1,3)-O(1) bond length is 1.85 Å. The Zn(1,3)-O(6) bond length is 1.85 Å. The Zn(1,3)-O(7) bond length is 1.85 Å. The Zn(1,3)-O(8) bond length is 1.85 Å. In the second Zn site, Zn(2,4) is bonded in a distorted trigonal bipyramidal geometry to one N(2), one O(2), one O(3), one O(4), and one O(5) atom. The Zn(2,4)-N(2) bond length is 1.93 Å. The Zn(2,4)-O(2) bond length is 1.85 Å. The Zn(2,4)-O(3) bond length is 1.85 Å. The Zn(2,4)-O(4) bond length is 1.85 Å. The Zn(2,4)-O(5) bond length is 1.85 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(4), and one O(7) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(4) bond length is 1.28 Å. The C(1)-O(7) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(19), and one C(27) atom. The C(2)-C(19) bond length is 1.41 Å. The C(2)-C(27) bond length is 1.41 Å. In the third C site, C(4) is bonded in a bent 120 degrees geometry to one C(5,39); one O(3); and one O(6) atom. The C(4)-C(5,39) bond length is 1.52 Å. The C(4)-O(3) bond length is 1.28 Å. The C(4)-O(6) bond length is 1.28 Å. In the fourth C site, C(5,39) is bonded in a trigonal planar geometry to one C(21), one C(29), and one C(4) atom. The C(5,39)-C(21) bond length is 1.41 Å. The C(5,39)-C(29) bond length is 1.41 Å. In the fifth C site, C(7) is bonded in a bent 120 degrees geometry to one C(8), one O(5), and one O(8) atom. The C(7)-C(8) bond length is 1.52 Å. The C(7)-O(5) bond length is 1.28 Å. The C(7)-O(8) bond length is 1.28 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(23), one C(33), and one C(7) atom. The C(8)-C(23) bond length is 1.41 Å. The C(8)-C(33) bond length is 1.41 Å. In the seventh C site, C(10) is bonded in a bent 120 degrees geometry to one C(11), one O(1), and one O(2) atom. The C(10)-C(11) bond length is 1.52 Å. The C(10)-O(1) bond length is 1.28 Å. The C(10)-O(2) bond length is 1.28 Å. In the eighth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(25), and one C(31) atom. The C(11)-C(25) bond length is 1.41 Å. The C(11)-C(31) bond length is 1.41 Å. In the ninth C site, C(13,17,47,51) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent H(17,18,19,20,25,26,27,28,45,46,47,48,52,53,54,55,56) atoms. The C(13,17,47,51)-N(1) bond length is 1.48 Å. Both C(13,17,47,51)-H(17,18,19,20,25,26,27,28,45,46,47,48,52,53,54,55,56) bond lengths are 1.11 Å. In the tenth C site, C(14,18,48,52) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent H(17,18,19,20,25,26,27,28,45,46,47,48,52,53,54,55,56) atoms. The C(14,18,48,52)-N(1) bond length is 1.48 Å. Both C(14,18,48,52)-H(17,18,19,20,25,26,27,28,45,46,47,48,52,53,54,55,56) bond lengths are 1.11 Å. In the eleventh C site, C(15,16,49,50) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent H(21,22,23,24,49,50,51) atoms. The C(15,16,49,50)-N(1) bond length is 1.48 Å. Both C(15,16,49,50)-H(21,22,23,24,49,50,51) bond lengths are 1.11 Å. In the twelfth C site, C(19) is bonded in a distorted single-bond geometry to one C(2) and one H(1,9,29,37) atom. The C(19)-H(1,9,29,37) bond length is 1.08 Å. In the thirteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(5,39) and one H(3,11,31,39) atom. The C(21)-H(3,11,31,39) bond length is 1.08 Å. In the fourteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(8) and one H(5,15) atom. The C(23)-H(5,15) bond length is 1.08 Å. In the fifteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(11) and one H(7,13) atom. The C(25)-H(7,13) bond length is 1.08 Å. In the sixteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(2) and one H(1,9,29,37) atom. The C(27)-H(1,9,29,37) bond length is 1.08 Å. In the seventeenth C site, C(29) is bonded in a distorted single-bond geometry to one C(5,39) and one H(3,11,31,39) atom. The C(29)-H(3,11,31,39) bond length is 1.08 Å. In the eighteenth C site, C(31) is bonded in a distorted single-bond geometry to one C(11) and one H(7,13) atom. The C(31)-H(7,13) bond length is 1.08 Å. In the nineteenth C site, C(33) is bonded in a distorted single-bond geometry to one C(8) and one H(5,15) atom. The C(33)-H(5,15) bond length is 1.08 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a tetrahedral geometry to one Zn(2,4); one C(13,17,47,51); one C(14,18,48,52); and one C(15,16,49,50) atom. The N(2)-C(13,17,47,51) bond length is 1.48 Å. The N(2)-C(14,18,48,52) bond length is 1.48 Å. The N(2)-C(15,16,49,50) bond length is 1.48 Å. In the second N site, N(1) is bonded in a tetrahedral geometry to one Zn(1,3); one C(13,17,47,51); one C(14,18,48,52); and one C(15,16,49,50) atom. There are six inequivalent H sites. In the first H site, H(1,9,29,37) is bonded in a single-bond geometry to one C(19) atom. In the second H site, H(3,11,31,39) is bonded in a single-bond geometry to one C(21) atom. In the third H site, H(5,15) is bonded in a single-bond geometry to one C(23) atom. In the fourth H site, H(7,13) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(17,18,19,20,25,26,27,28,45,46,47,48,52,53,54,55,56) is bonded in a single-bond geometry to one C(13,17,47,51) atom. In the sixth H site, H(21,22,23,24,49,50,51) is bonded in a single-bond geometry to one C(15,16,49,50) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1,3) and one C(10) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(2,4) and one C(10) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(2,4) and one C(4) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(2,4) and one C(1) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Zn(2,4) and one C(7) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Zn(1,3) and one C(4) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Zn(1,3) and one C(1) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Zn(1,3) and one C(7) atom. Linkers: 2 C1CN2CCN1CC2 ,4 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: sql. The MOF has largest included sphere 13.11 A, density 0.54 g/cm3, surface area 4459.83 m2/g, accessible volume 1.48 cm3/g