CuH24(C2N)12 is Indium-like structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight CuH24(C2N)12 clusters. Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(10), one N(4), and one N(7) atom. The Cu(1)-N(1) bond length is 2.02 Å. The Cu(1)-N(10) bond length is 1.98 Å. The Cu(1)-N(4) bond length is 2.06 Å. The Cu(1)-N(7) bond length is 2.04 Å. There are twenty-four inequivalent C sites. In the first C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-C(12) bond length is 1.38 Å. The C(10)-C(9) bond length is 1.49 Å. In the second C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(11) atom. The C(11)-H(11) bond length is 0.93 Å. In the third C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one H(12) atom. The C(12)-H(12) bond length is 0.93 Å. In the fourth C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.93 Å. In the fifth C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(3) bond length is 1.34 Å. The C(2)-H(2) bond length is 0.93 Å. In the sixth C site, C(3) is bonded in a 3-coordinate geometry to one C(4); one N(3); and two equivalent H(3,4) atoms. The C(3)-C(4) bond length is 1.49 Å. The C(3)-N(3) bond length is 1.43 Å. Both C(3)-H(3,4) bond lengths are 0.97 Å. In the seventh C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-C(6) bond length is 1.38 Å. In the eighth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(5) atom. The C(5)-H(5) bond length is 0.93 Å. In the ninth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(6) atom. The C(6)-H(6) bond length is 0.93 Å. In the tenth C site, C(7) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(7) atom. The C(7)-N(4) bond length is 1.31 Å. The C(7)-N(5) bond length is 1.31 Å. The C(7)-H(7) bond length is 0.93 Å. In the eleventh C site, C(8) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(8) atom. The C(8)-N(4) bond length is 1.31 Å. The C(8)-N(6) bond length is 1.31 Å. The C(8)-H(8) bond length is 0.93 Å. In the twelfth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(10); one N(6); and two equivalent H(9,10) atoms. The C(9)-N(6) bond length is 1.43 Å. Both C(9)-H(9,10) bond lengths are 0.97 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(13) atom. The C(13)-N(7) bond length is 1.31 Å. The C(13)-N(8) bond length is 1.31 Å. The C(13)-H(13) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(14) atom. The C(14)-N(7) bond length is 1.31 Å. The C(14)-N(9) bond length is 1.31 Å. The C(14)-H(14) bond length is 0.93 Å. In the fifteenth C site, C(15) is bonded in a 3-coordinate geometry to one C(16), one N(9), one H(15), and one H(16) atom. The C(15)-C(16) bond length is 1.47 Å. The C(15)-N(9) bond length is 1.43 Å. The C(15)-H(15) bond length is 0.98 Å. The C(15)-H(16) bond length is 0.96 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. The C(16)-C(17) bond length is 1.36 Å. The C(16)-C(18) bond length is 1.36 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(17) atom. The C(17)-H(17) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(16) and one H(18) atom. The C(18)-H(18) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one N(10), one N(11), and one H(19) atom. The C(19)-N(10) bond length is 1.37 Å. The C(19)-N(11) bond length is 1.37 Å. The C(19)-H(19) bond length is 0.93 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(20) atom. The C(20)-N(10) bond length is 1.36 Å. The C(20)-N(12) bond length is 1.37 Å. The C(20)-H(20) bond length is 0.93 Å. In the twenty-first C site, C(21) is bonded in a 3-coordinate geometry to one C(22), one N(12), one H(21), and one H(22) atom. The C(21)-C(22) bond length is 1.46 Å. The C(21)-N(12) bond length is 1.43 Å. The C(21)-H(21) bond length is 0.97 Å. The C(21)-H(22) bond length is 0.98 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(24) atom. The C(22)-C(23) bond length is 1.36 Å. The C(22)-C(24) bond length is 1.36 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(23) atom. The C(23)-H(23) bond length is 0.93 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(22) and one H(24) atom. The C(24)-H(24) bond length is 0.93 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(1) and one N(3) atom. The N(2)-N(3) bond length is 1.34 Å. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one C(3), and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(7), and one C(8) atom. In the fifth N site, N(6) is bonded in a distorted bent 120 degrees geometry to one C(8), one C(9), and one N(5) atom. The N(6)-N(5) bond length is 1.31 Å. In the sixth N site, N(7) is bonded in a trigonal planar geometry to one Cu(1), one C(13), and one C(14) atom. In the seventh N site, N(8) is bonded in a water-like geometry to one C(13) and one N(9) atom. The N(8)-N(9) bond length is 1.31 Å. In the eighth N site, N(9) is bonded in a distorted bent 120 degrees geometry to one C(14), one C(15), and one N(8) atom. In the ninth N site, N(10) is bonded in a trigonal planar geometry to one Cu(1), one C(19), and one C(20) atom. In the tenth N site, N(11) is bonded in a distorted water-like geometry to one C(19) and one N(12) atom. The N(11)-N(12) bond length is 1.36 Å. In the eleventh N site, N(12) is bonded in a distorted bent 120 degrees geometry to one C(20), one C(21), and one N(11) atom. In the twelfth N site, N(5) is bonded in a distorted water-like geometry to one C(7) and one N(6) atom. There are twenty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(21) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(22) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(23) is bonded in a single-bond geometry to one C(23) atom. In the fifteenth H site, H(24) is bonded in a single-bond geometry to one C(24) atom. In the sixteenth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the seventeenth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the eighteenth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the nineteenth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the twentieth H site, H(9,10) is bonded in a single-bond geometry to one C(9) atom. In the twenty-first H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the twenty-second H site, H(12) is bonded in a single-bond geometry to one C(12) atom. Linkers: 16 [CH]1N=C[N]N1Cc1ccc(CN2[CH]N=C[N]2)cc1. Metal clusters: 8 [Cu]. The MOF has largest included sphere 9.11 A, density 0.63 g/cm3, surface area 5242.75 m2/g, accessible volume 1.14 cm3/g