Mo8Co8C10P12N5H22O56(C3H2)5 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 2,3-dimethyl-1,3-butadiene molecules; four propylene molecules; and two Mo8Co8C10P12N5H22O56 clusters. In each Mo8Co8C10P12N5H22O56 cluster, there are eight inequivalent Mo sites. In the first Mo site, Mo(1) is bonded to one O(1), one O(2), one O(3), one O(4), and one O(5) atom to form distorted MoO5 square pyramids that share  a cornercorner with one Co(2)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one Co(1)NO4 trigonal bipyramid, and  an edgeedge with one Mo(2)O5 square pyramid. The Mo(1)-O(1) bond length is 1.96 Å. The Mo(1)-O(2) bond length is 2.08 Å. The Mo(1)-O(3) bond length is 1.94 Å. The Mo(1)-O(4) bond length is 2.08 Å. The Mo(1)-O(5) bond length is 2.20 Å. In the second Mo site, Mo(2) is bonded to one O(1), one O(3), one O(6), one O(7), and one O(8) atom to form distorted MoO5 square pyramids that share  a cornercorner with one Mo(3)O5 square pyramid,  a cornercorner with one Co(2)O5 square pyramid,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one Co(1)NO4 trigonal bipyramid, and  an edgeedge with one Mo(1)O5 square pyramid. The Mo(2)-O(1) bond length is 1.93 Å. The Mo(2)-O(3) bond length is 1.95 Å. The Mo(2)-O(6) bond length is 2.45 Å. The Mo(2)-O(7) bond length is 2.01 Å. The Mo(2)-O(8) bond length is 2.06 Å. In the third Mo site, Mo(3) is bonded to one O(21), one O(22), one O(23), one O(24), and one O(6) atom to form distorted MoO5 square pyramids that share  a cornercorner with one Mo(2)O5 square pyramid,  a cornercorner with one Co(6)O5 square pyramid,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one Co(4)NO4 trigonal bipyramid, and  an edgeedge with one Mo(4)O5 square pyramid. The Mo(3)-O(21) bond length is 2.04 Å. The Mo(3)-O(22) bond length is 1.93 Å. The Mo(3)-O(23) bond length is 1.92 Å. The Mo(3)-O(24) bond length is 2.07 Å. The Mo(3)-O(6) bond length is 2.40 Å. In the fourth Mo site, Mo(4) is bonded to one O(20), one O(22), one O(23), one O(27), and one O(28) atom to form MoO5 square pyramids that share  a cornercorner with one Co(6)O5 square pyramid,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  a cornercorner with one P(9)O4 tetrahedra,  a cornercorner with one Co(4)NO4 trigonal bipyramid, and  an edgeedge with one Mo(3)O5 square pyramid. The Mo(4)-O(20) bond length is 2.20 Å. The Mo(4)-O(22) bond length is 1.96 Å. The Mo(4)-O(23) bond length is 1.96 Å. The Mo(4)-O(27) bond length is 2.05 Å. The Mo(4)-O(28) bond length is 2.06 Å. In the fifth Mo site, Mo(5) is bonded to one O(12), one O(29), one O(36), one O(37), and one O(38) atom to form MoO5 square pyramids that share  a cornercorner with one Co(3)NO5 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(10)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  a cornercorner with one Co(8)NO4 trigonal bipyramid, and  an edgeedge with one Mo(7)O5 square pyramid. The corner-sharing octahedral tilt angles are 41°. The Mo(5)-O(12) bond length is 2.07 Å. The Mo(5)-O(29) bond length is 1.96 Å. The Mo(5)-O(36) bond length is 2.06 Å. The Mo(5)-O(37) bond length is 2.14 Å. The Mo(5)-O(38) bond length is 1.96 Å. In the sixth Mo site, Mo(6) is bonded to one O(18), one O(39), one O(45), one O(46), and one O(47) atom to form MoO5 square pyramids that share  a cornercorner with one Co(7)NO5 octahedra,  a cornercorner with one P(10)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(9)O4 tetrahedra, and  an edgeedge with one Mo(8)O5 square pyramid. The corner-sharing octahedral tilt angles are 39°. The Mo(6)-O(18) bond length is 2.09 Å. The Mo(6)-O(39) bond length is 1.93 Å. The Mo(6)-O(45) bond length is 1.98 Å. The Mo(6)-O(46) bond length is 2.02 Å. The Mo(6)-O(47) bond length is 2.20 Å. In the seventh Mo site, Mo(7) is bonded to one O(29), one O(38), one O(48), one O(49), and one O(50) atom to form distorted MoO5 square pyramids that share  a cornercorner with one Co(3)NO5 octahedra,  a cornercorner with one Mo(8)O5 square pyramid,  a cornercorner with one P(10)O4 tetrahedra,  a cornercorner with one P(11)O4 tetrahedra,  a cornercorner with one P(12)O4 tetrahedra,  a cornercorner with one Co(8)NO4 trigonal bipyramid, and  an edgeedge with one Mo(5)O5 square pyramid. The corner-sharing octahedral tilt angles are 48°. The Mo(7)-O(29) bond length is 1.94 Å. The Mo(7)-O(38) bond length is 1.95 Å. The Mo(7)-O(48) bond length is 2.03 Å. The Mo(7)-O(49) bond length is 2.39 Å. The Mo(7)-O(50) bond length is 2.09 Å. In the eighth Mo site, Mo(8) is bonded to one O(39), one O(45), one O(49), one O(51), and one O(52) atom to form distorted MoO5 square pyramids that share  a cornercorner with one Co(7)NO5 octahedra,  a cornercorner with one Mo(7)O5 square pyramid,  a cornercorner with one P(10)O4 tetrahedra,  a cornercorner with one P(11)O4 tetrahedra,  a cornercorner with one P(12)O4 tetrahedra, and  an edgeedge with one Mo(6)O5 square pyramid. The corner-sharing octahedral tilt angles are 49°. The Mo(8)-O(39) bond length is 1.94 Å. The Mo(8)-O(45) bond length is 1.93 Å. The Mo(8)-O(49) bond length is 2.42 Å. The Mo(8)-O(51) bond length is 2.05 Å. The Mo(8)-O(52) bond length is 2.06 Å. There are eight inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(1), one O(1), one O(10), one O(11), and one O(9) atom to form CoNO4 trigonal bipyramids that share  a cornercorner with one Mo(1)O5 square pyramid,  a cornercorner with one Mo(2)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one Co(4)NO4 trigonal bipyramid, and  an edgeedge with one Co(3)NO5 octahedra. The Co(1)-N(1) bond length is 2.16 Å. The Co(1)-O(1) bond length is 2.01 Å. The Co(1)-O(10) bond length is 2.11 Å. The Co(1)-O(11) bond length is 2.05 Å. The Co(1)-O(9) bond length is 2.08 Å. In the second Co site, Co(2) is bonded to one O(14), one O(15), one O(16), one O(17), and one O(3) atom to form CoO5 square pyramids that share  a cornercorner with one Mo(1)O5 square pyramid,  a cornercorner with one Mo(2)O5 square pyramid,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra, and  an edgeedge with one Co(6)O5 square pyramid. The Co(2)-O(14) bond length is 2.09 Å. The Co(2)-O(15) bond length is 2.17 Å. The Co(2)-O(16) bond length is 2.12 Å. The Co(2)-O(17) bond length is 2.17 Å. The Co(2)-O(3) bond length is 2.04 Å. In the third Co site, Co(3) is bonded to one N(2), one O(11), one O(29), one O(30), one O(31), and one O(9) atom to form CoNO5 octahedra that share  a cornercorner with one Mo(5)O5 square pyramid,  a cornercorner with one Mo(7)O5 square pyramid,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(10)O4 tetrahedra,  a cornercorner with one P(11)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  an edgeedge with one Co(7)NO5 octahedra, and  an edgeedge with one Co(1)NO4 trigonal bipyramid. The Co(3)-N(2) bond length is 2.13 Å. The Co(3)-O(11) bond length is 2.07 Å. The Co(3)-O(29) bond length is 2.02 Å. The Co(3)-O(30) bond length is 2.23 Å. The Co(3)-O(31) bond length is 2.24 Å. The Co(3)-O(9) bond length is 2.15 Å. In the fourth Co site, Co(4) is bonded to one N(3), one O(10), one O(23), one O(32), and one O(33) atom to form CoNO4 trigonal bipyramids that share  a cornercorner with one Mo(3)O5 square pyramid,  a cornercorner with one Mo(4)O5 square pyramid,  a cornercorner with one P(5)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(9)O4 tetrahedra,  a cornercorner with one Co(1)NO4 trigonal bipyramid, and  an edgeedge with one Co(7)NO5 octahedra. The Co(4)-N(3) bond length is 2.14 Å. The Co(4)-O(10) bond length is 2.09 Å. The Co(4)-O(23) bond length is 2.03 Å. The Co(4)-O(32) bond length is 2.08 Å. The Co(4)-O(33) bond length is 2.09 Å. In the fifth Co site, Co(5) is bonded in a rectangular see-saw-like geometry to one O(14), one O(16), one O(39), and one O(40) atom. The Co(5)-O(14) bond length is 2.09 Å. The Co(5)-O(16) bond length is 2.03 Å. The Co(5)-O(39) bond length is 2.04 Å. The Co(5)-O(40) bond length is 2.10 Å. In the sixth Co site, Co(6) is bonded to one O(15), one O(17), one O(22), one O(41), and one O(42) atom to form CoO5 square pyramids that share  a cornercorner with one Mo(3)O5 square pyramid,  a cornercorner with one Mo(4)O5 square pyramid,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra,  an edgeedge with one Co(2)O5 square pyramid, and  an edgeedge with one Co(8)NO4 trigonal bipyramid. The Co(6)-O(15) bond length is 2.27 Å. The Co(6)-O(17) bond length is 2.24 Å. The Co(6)-O(22) bond length is 2.07 Å. The Co(6)-O(41) bond length is 2.09 Å. The Co(6)-O(42) bond length is 2.18 Å. In the seventh Co site, Co(7) is bonded to one N(4), one O(30), one O(31), one O(32), one O(33), and one O(45) atom to form CoNO5 octahedra that share  a cornercorner with one Mo(6)O5 square pyramid,  a cornercorner with one Mo(8)O5 square pyramid,  a cornercorner with one P(10)O4 tetrahedra,  a cornercorner with one P(11)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra,  a cornercorner with one P(9)O4 tetrahedra,  an edgeedge with one Co(3)NO5 octahedra, and  an edgeedge with one Co(4)NO4 trigonal bipyramid. The Co(7)-N(4) bond length is 2.14 Å. The Co(7)-O(30) bond length is 2.20 Å. The Co(7)-O(31) bond length is 2.26 Å. The Co(7)-O(32) bond length is 2.18 Å. The Co(7)-O(33) bond length is 2.07 Å. The Co(7)-O(45) bond length is 2.01 Å. In the eighth Co site, Co(8) is bonded to one N(5), one O(38), one O(40), one O(41), and one O(42) atom to form CoNO4 trigonal bipyramids that share  a cornercorner with one Mo(5)O5 square pyramid,  a cornercorner with one Mo(7)O5 square pyramid,  a cornercorner with one P(12)O4 tetrahedra,  a cornercorner with one P(7)O4 tetrahedra,  a cornercorner with one P(8)O4 tetrahedra, and  an edgeedge with one Co(6)O5 square pyramid. The Co(8)-N(5) bond length is 2.11 Å. The Co(8)-O(38) bond length is 2.03 Å. The Co(8)-O(40) bond length is 2.08 Å. The Co(8)-O(41) bond length is 2.10 Å. The Co(8)-O(42) bond length is 2.07 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(1)-N(2) bond length is 1.30 Å. The C(1)-H(8) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(2)-N(2) bond length is 1.37 Å. The C(2)-H(9) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(10) atom. The C(3)-N(3) bond length is 1.35 Å. The C(3)-H(10) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(11) atom. The C(4)-N(3) bond length is 1.36 Å. The C(4)-H(11) bond length is 0.94 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(20) atom. The C(11)-N(5) bond length is 1.36 Å. The C(11)-H(20) bond length is 0.93 Å. In the sixth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(21) atom. The C(12)-N(5) bond length is 1.35 Å. The C(12)-H(21) bond length is 0.93 Å. In the seventh C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(28) atom. The C(22)-N(4) bond length is 1.32 Å. The C(22)-H(28) bond length is 0.93 Å. In the eighth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(29) atom. The C(23)-N(4) bond length is 1.34 Å. The C(23)-H(29) bond length is 0.92 Å. In the ninth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(30) atom. The C(24)-N(1) bond length is 1.33 Å. The C(24)-H(30) bond length is 0.93 Å. In the tenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(31) atom. The C(25)-N(1) bond length is 1.30 Å. The C(25)-H(31) bond length is 0.93 Å. There are twelve inequivalent P sites. In the first P site, P(1) is bonded to one O(12), one O(13), one O(2), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Co(3)NO5 octahedra,  a cornercorner with one Mo(1)O5 square pyramid,  a cornercorner with one Mo(5)O5 square pyramid, and  a cornercorner with one Co(1)NO4 trigonal bipyramid. The corner-sharing octahedral tilt angles are 48°. The P(1)-O(12) bond length is 1.49 Å. The P(1)-O(13) bond length is 1.57 Å. The P(1)-O(2) bond length is 1.51 Å. The P(1)-O(9) bond length is 1.54 Å. In the second P site, P(2) is bonded to one O(14), one O(18), one O(19), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Mo(1)O5 square pyramid,  a cornercorner with one Mo(6)O5 square pyramid, and  a cornercorner with one Co(2)O5 square pyramid. The P(2)-O(14) bond length is 1.55 Å. The P(2)-O(18) bond length is 1.51 Å. The P(2)-O(19) bond length is 1.54 Å. The P(2)-O(4) bond length is 1.52 Å. In the third P site, P(3) is bonded to one O(15), one O(20), one O(5), and one O(6) atom to form PO4 tetrahedra that share  a cornercorner with one Mo(1)O5 square pyramid,  a cornercorner with one Mo(2)O5 square pyramid,  a cornercorner with one Mo(3)O5 square pyramid,  a cornercorner with one Mo(4)O5 square pyramid,  a cornercorner with one Co(2)O5 square pyramid, and  a cornercorner with one Co(6)O5 square pyramid. The P(3)-O(15) bond length is 1.60 Å. The P(3)-O(20) bond length is 1.53 Å. The P(3)-O(5) bond length is 1.52 Å. The P(3)-O(6) bond length is 1.58 Å. In the fourth P site, P(4) is bonded to one O(17), one O(21), one O(25), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Mo(2)O5 square pyramid,  a cornercorner with one Mo(3)O5 square pyramid,  a cornercorner with one Co(2)O5 square pyramid, and  a cornercorner with one Co(6)O5 square pyramid. The P(4)-O(17) bond length is 1.56 Å. The P(4)-O(21) bond length is 1.54 Å. The P(4)-O(25) bond length is 1.51 Å. The P(4)-O(7) bond length is 1.53 Å. In the fifth P site, P(5) is bonded to one O(10), one O(24), one O(26), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Mo(2)O5 square pyramid,  a cornercorner with one Mo(3)O5 square pyramid,  a cornercorner with one Co(1)NO4 trigonal bipyramid, and  a cornercorner with one Co(4)NO4 trigonal bipyramid. The P(5)-O(10) bond length is 1.50 Å. The P(5)-O(24) bond length is 1.54 Å. The P(5)-O(26) bond length is 1.58 Å. The P(5)-O(8) bond length is 1.54 Å. In the sixth P site, P(6) is bonded to one O(11), one O(33), one O(34), and one O(35) atom to form PO4 tetrahedra that share  a cornercorner with one Co(3)NO5 octahedra,  a cornercorner with one Co(7)NO5 octahedra,  a cornercorner with one Co(1)NO4 trigonal bipyramid, and  a cornercorner with one Co(4)NO4 trigonal bipyramid. The corner-sharing octahedral tilt angles are 55°. The P(6)-O(11) bond length is 1.56 Å. The P(6)-O(33) bond length is 1.51 Å. The P(6)-O(34) bond length is 1.56 Å. The P(6)-O(35) bond length is 1.52 Å. In the seventh P site, P(7) is bonded to one O(16), one O(41), one O(43), and one O(44) atom to form PO4 tetrahedra that share  a cornercorner with one Co(2)O5 square pyramid,  a cornercorner with one Co(6)O5 square pyramid, and  a cornercorner with one Co(8)NO4 trigonal bipyramid. The P(7)-O(16) bond length is 1.55 Å. The P(7)-O(41) bond length is 1.54 Å. The P(7)-O(43) bond length is 1.51 Å. The P(7)-O(44) bond length is 1.55 Å. In the eighth P site, P(8) is bonded to one O(27), one O(36), one O(42), and one O(53) atom to form PO4 tetrahedra that share  a cornercorner with one Mo(4)O5 square pyramid,  a cornercorner with one Mo(5)O5 square pyramid,  a cornercorner with one Co(6)O5 square pyramid, and  a cornercorner with one Co(8)NO4 trigonal bipyramid. The P(8)-O(27) bond length is 1.53 Å. The P(8)-O(36) bond length is 1.49 Å. The P(8)-O(42) bond length is 1.52 Å. The P(8)-O(53) bond length is 1.56 Å. In the ninth P site, P(9) is bonded to one O(28), one O(32), one O(46), and one O(54) atom to form PO4 tetrahedra that share  a cornercorner with one Co(7)NO5 octahedra,  a cornercorner with one Mo(4)O5 square pyramid,  a cornercorner with one Mo(6)O5 square pyramid, and  a cornercorner with one Co(4)NO4 trigonal bipyramid. The corner-sharing octahedral tilt angles are 46°. The P(9)-O(28) bond length is 1.54 Å. The P(9)-O(32) bond length is 1.53 Å. The P(9)-O(46) bond length is 1.53 Å. The P(9)-O(54) bond length is 1.53 Å. In the tenth P site, P(10) is bonded to one O(30), one O(37), one O(47), and one O(49) atom to form PO4 tetrahedra that share  a cornercorner with one Co(3)NO5 octahedra,  a cornercorner with one Co(7)NO5 octahedra,  a cornercorner with one Mo(5)O5 square pyramid,  a cornercorner with one Mo(6)O5 square pyramid,  a cornercorner with one Mo(7)O5 square pyramid, and  a cornercorner with one Mo(8)O5 square pyramid. The corner-sharing octahedral tilt angles range from 63-65°. The P(10)-O(30) bond length is 1.61 Å. The P(10)-O(37) bond length is 1.51 Å. The P(10)-O(47) bond length is 1.57 Å. The P(10)-O(49) bond length is 1.57 Å. In the eleventh P site, P(11) is bonded to one O(31), one O(48), one O(51), and one O(55) atom to form PO4 tetrahedra that share  a cornercorner with one Co(3)NO5 octahedra,  a cornercorner with one Co(7)NO5 octahedra,  a cornercorner with one Mo(7)O5 square pyramid, and  a cornercorner with one Mo(8)O5 square pyramid. The corner-sharing octahedral tilt angles range from 57-58°. The P(11)-O(31) bond length is 1.52 Å. The P(11)-O(48) bond length is 1.54 Å. The P(11)-O(51) bond length is 1.54 Å. The P(11)-O(55) bond length is 1.53 Å. In the twelfth P site, P(12) is bonded to one O(40), one O(50), one O(52), and one O(56) atom to form PO4 tetrahedra that share  a cornercorner with one Mo(7)O5 square pyramid,  a cornercorner with one Mo(8)O5 square pyramid, and  a cornercorner with one Co(8)NO4 trigonal bipyramid. The P(12)-O(40) bond length is 1.53 Å. The P(12)-O(50) bond length is 1.54 Å. The P(12)-O(52) bond length is 1.54 Å. The P(12)-O(56) bond length is 1.52 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(24), and one C(25) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(3), one C(1), and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(4), one C(3), and one C(4) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(7), one C(22), and one C(23) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Co(8), one C(11), and one C(12) atom. There are twenty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(13) atom. The H(1)-O(13) bond length is 0.82 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(25) atom. The H(2)-O(25) bond length is 0.82 Å. In the third H site, H(3) is bonded in a distorted single-bond geometry to one O(26) atom. The H(3)-O(26) bond length is 0.82 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(34) atom. The H(4)-O(34) bond length is 0.82 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(35) atom. The H(5)-O(35) bond length is 0.82 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(43) atom. The H(6)-O(43) bond length is 0.82 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one O(44) atom. The H(7)-O(44) bond length is 0.82 Å. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(1) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(2) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(3) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(4) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one O(53) atom. The H(12)-O(53) bond length is 0.82 Å. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one O(54) atom. The H(13)-O(54) bond length is 0.82 Å. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one O(55) atom. The H(14)-O(55) bond length is 0.82 Å. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one O(56) atom. The H(19)-O(56) bond length is 0.82 Å. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(11) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(12) atom. In the eighteenth H site, H(28) is bonded in a single-bond geometry to one C(22) atom. In the nineteenth H site, H(29) is bonded in a single-bond geometry to one C(23) atom. In the twentieth H site, H(30) is bonded in a single-bond geometry to one C(24) atom. In the twenty-first H site, H(31) is bonded in a single-bond geometry to one C(25) atom. In the twenty-second H site, H(32) is bonded in a distorted single-bond geometry to one O(19) atom. The H(32)-O(19) bond length is 0.82 Å. There are fifty-six inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to one Mo(1), one Mo(2), and one Co(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mo(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted T-shaped geometry to one Mo(1), one Mo(2), and one Co(2) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Mo(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Mo(1) and one P(3) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Mo(2), one Mo(3), and one P(3) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Mo(2) and one P(4) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Mo(2) and one P(5) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Co(1), one Co(3), and one P(1) atom. In the tenth O site, O(10) is bonded in a trigonal planar geometry to one Co(1), one Co(4), and one P(5) atom. In the eleventh O site, O(11) is bonded in a distorted trigonal planar geometry to one Co(1), one Co(3), and one P(6) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Mo(5) and one P(1) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one P(1) and one H(1) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(5), and one P(2) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal non-coplanar geometry to one Co(2), one Co(6), and one P(3) atom. In the sixteenth O site, O(16) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(5), and one P(7) atom. In the seventeenth O site, O(17) is bonded in a distorted trigonal planar geometry to one Co(2), one Co(6), and one P(4) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 150 degrees geometry to one Mo(6) and one P(2) atom. In the nineteenth O site, O(19) is bonded in a water-like geometry to one P(2) and one H(32) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Mo(4) and one P(3) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one Mo(3) and one P(4) atom. In the twenty-second O site, O(22) is bonded in a 3-coordinate geometry to one Mo(3), one Mo(4), and one Co(6) atom. In the twenty-third O site, O(23) is bonded in a distorted T-shaped geometry to one Mo(3), one Mo(4), and one Co(4) atom. In the twenty-fourth O site, O(24) is bonded in a distorted single-bond geometry to one Mo(3) and one P(5) atom. In the twenty-fifth O site, O(25) is bonded in a water-like geometry to one P(4) and one H(2) atom. In the twenty-sixth O site, O(26) is bonded in a water-like geometry to one P(5) and one H(3) atom. In the twenty-seventh O site, O(27) is bonded in a distorted bent 150 degrees geometry to one Mo(4) and one P(8) atom. In the twenty-eighth O site, O(28) is bonded in a distorted bent 150 degrees geometry to one Mo(4) and one P(9) atom. In the twenty-ninth O site, O(29) is bonded in a distorted T-shaped geometry to one Mo(5), one Mo(7), and one Co(3) atom. In the thirtieth O site, O(30) is bonded in a distorted trigonal non-coplanar geometry to one Co(3), one Co(7), and one P(10) atom. In the thirty-first O site, O(31) is bonded in a 3-coordinate geometry to one Co(3), one Co(7), and one P(11) atom. In the thirty-second O site, O(32) is bonded in a 3-coordinate geometry to one Co(4), one Co(7), and one P(9) atom. In the thirty-third O site, O(33) is bonded in a distorted trigonal planar geometry to one Co(4), one Co(7), and one P(6) atom. In the thirty-fourth O site, O(34) is bonded in a water-like geometry to one P(6) and one H(4) atom. In the thirty-fifth O site, O(35) is bonded in a distorted water-like geometry to one P(6) and one H(5) atom. In the thirty-sixth O site, O(36) is bonded in a distorted bent 150 degrees geometry to one Mo(5) and one P(8) atom. In the thirty-seventh O site, O(37) is bonded in a distorted bent 120 degrees geometry to one Mo(5) and one P(10) atom. In the thirty-eighth O site, O(38) is bonded in a distorted T-shaped geometry to one Mo(5), one Mo(7), and one Co(8) atom. In the thirty-ninth O site, O(39) is bonded in a distorted T-shaped geometry to one Mo(6), one Mo(8), and one Co(5) atom. In the fortieth O site, O(40) is bonded in a distorted trigonal planar geometry to one Co(5), one Co(8), and one P(12) atom. In the forty-first O site, O(41) is bonded in a 3-coordinate geometry to one Co(6), one Co(8), and one P(7) atom. In the forty-second O site, O(42) is bonded in a 3-coordinate geometry to one Co(6), one Co(8), and one P(8) atom. In the forty-third O site, O(43) is bonded in a water-like geometry to one P(7) and one H(6) atom. In the forty-fourth O site, O(44) is bonded in a water-like geometry to one P(7) and one H(7) atom. In the forty-fifth O site, O(45) is bonded in a distorted T-shaped geometry to one Mo(6), one Mo(8), and one Co(7) atom. In the forty-sixth O site, O(46) is bonded in a distorted bent 150 degrees geometry to one Mo(6) and one P(9) atom. In the forty-seventh O site, O(47) is bonded in a distorted bent 120 degrees geometry to one Mo(6) and one P(10) atom. In the forty-eighth O site, O(48) is bonded in a distorted single-bond geometry to one Mo(7) and one P(11) atom. In the forty-ninth O site, O(49) is bonded in a distorted single-bond geometry to one Mo(7), one Mo(8), and one P(10) atom. In the fiftieth O site, O(50) is bonded in a distorted single-bond geometry to one Mo(7) and one P(12) atom. In the fifty-first O site, O(51) is bonded in a distorted bent 150 degrees geometry to one Mo(8) and one P(11) atom. In the fifty-second O site, O(52) is bonded in a distorted single-bond geometry to one Mo(8) and one P(12) atom. In the fifty-third O site, O(53) is bonded in a water-like geometry to one P(8) and one H(12) atom. In the fifty-fourth O site, O(54) is bonded in a water-like geometry to one P(9) and one H(13) atom. In the fifty-fifth O site, O(55) is bonded in a water-like geometry to one P(11) and one H(14) atom. In the fifty-sixth O site, O(56) is bonded in a water-like geometry to one P(12) and one H(19) atom. Linkers: 8 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 O[P](O)(O[Co])O[Co].O[P](O)(O[Co])O[Co].O[P]1(O)O[Co]O[P@@]2(O)O[Mo]3456O[P@@]7(O)O[Co]8O[P@@]9(O)O[Mo]3(O[P@@]3(O)O[Co]O[P@@]%10(O)O[Mo]%11%12%13%14O[P@@]%15(O)O[Co]%16O[P@]%17(O)O[Mo]%18%19%20O[P@]%21(O)O[Co]O[P@]%22(O)O[Mo]%23%24%25(O7)O[P@@]7%26O[Co]O[P](O)(O)O[Co]O[P@](O)(O[Mo]%18(O%15)(O[P@]%15(O%16)O[Mo]%16%18(O%21)(O%17)O[Mo]%16(O[P@@]%16(O)O[Co](N%17[CH]C=[C]C=C%17)O[P@@]%17(O)O[Mo]%11(O[P@@](O)(O[Co])O[Mo]%11%21%27(O%17)O[P@@](O[Co]O1)(O%12)O[Mo]%11(O2)(O%16)(O%21)O%27)(O%13)O%14)(O%22)(O%15)O%18)(O%19)O%20)O[Mo]12%11(O[P@@](O)(O[Co](N%12[CH]C=[C]C=C%12)O[P@]%12(O)O[Mo]%23(O[P@](O)(O[Co])O[Mo]1(O%12)(O7)(O2)O%11)(O%24)O%25)O[Mo]127(O%10)O[P@@](O8)(O4)O[Mo]1(O9)(O3)(O2)O7)O%26)(O5)O6. The MOF has largest included sphere 5.48 A, density 1.81 g/cm3, surface area 2273.10 m2/g, accessible volume 0.30 cm3/g