WCu6C36H28S4(N4Br)4(CH)4 crystallizes in the cubic I-43d space group. The structure consists of forty-eight 02329_fluka molecules inside a WCu6C36H28S4(N4Br)4 framework. In the WCu6C36H28S4(N4Br)4 framework, W(1) is bonded to two equivalent Cu(2), four equivalent Cu(1), and four equivalent S(1) atoms to form distorted WCu6S4 tetrahedra that share faces with four equivalent S(1)Cu3W tetrahedra. Both W(1)-Cu(2) bond lengths are 2.66 Å. All W(1)-Cu(1) bond lengths are 2.74 Å. All W(1)-S(1) bond lengths are 2.21 Å. There are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a 4-coordinate geometry to one W(1), one N(1), two equivalent S(1), and one Br(1) atom. The Cu(1)-N(1) bond length is 2.04 Å. There is one shorter (2.32 Å) and one longer (2.34 Å) Cu(1)-S(1) bond length. The Cu(1)-Br(1) bond length is 2.44 Å. In the second Cu site, Cu(2) is bonded in a 4-coordinate geometry to one W(1), two equivalent N(3), and two equivalent S(1) atoms. Both Cu(2)-N(3) bond lengths are 1.99 Å. Both Cu(2)-S(1) bond lengths are 2.28 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-N(2) bond length is 1.26 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.31 Å. The C(2)-N(1) bond length is 1.38 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a 3-coordinate geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.43 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one N(2) atom. The C(4)-N(2) bond length is 1.41 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(5) atom. The C(6)-N(3) bond length is 1.32 Å. The C(6)-N(4) bond length is 1.27 Å. The C(6)-H(5) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(3), and one H(6) atom. The C(7)-C(8) bond length is 1.35 Å. The C(7)-N(3) bond length is 1.32 Å. The C(7)-H(6) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one N(4), and one H(7) atom. The C(8)-N(4) bond length is 1.36 Å. The C(8)-H(7) bond length is 0.93 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to two equivalent C(10) and one N(4) atom. There is one shorter (1.39 Å) and one longer (1.41 Å) C(9)-C(10) bond length. The C(9)-N(4) bond length is 1.42 Å. In the ninth C site, C(10) is bonded in a single-bond geometry to two equivalent C(9) and one H(8) atom. The C(10)-H(8) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(2), one C(6), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. S(1) is bonded to one W(1), one Cu(2), and two equivalent Cu(1) atoms to form distorted SCu3W tetrahedra that share edges with three equivalent S(1)Cu3W tetrahedra and  a faceface with one W(1)Cu6S4 tetrahedra. Br(1) is bonded in a single-bond geometry to one Cu(1) atom. Linkers: 18 c1cn(-c2cc(-n3ccnc3)cc(-n3ccnc3)c2)cn1. Metal clusters: 36 [Cu] ,6 [W]. The MOF has largest included sphere 7.91 A, density 1.24 g/cm3, surface area 3133.54 m2/g, accessible volume 0.52 cm3/g