Ag3Si6H64(C8N)8(AgH6(C2N)3)2Si(CH)8(CH2)14 is Indium-derived structured and crystallizes in the trigonal P3_221 space group. The structure is zero-dimensional and consists of forty-two 02329_fluka molecules, three dimethyl-bis(prop-1-en-2-yl)silane molecules, three Ag3Si6H64(C8N)8 clusters, and six AgH6(C2N)3 clusters. In each Ag3Si6H64(C8N)8 cluster, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one N(5) atom. The Ag(1)-N(1) bond length is 2.31 Å. The Ag(1)-N(3) bond length is 2.27 Å. The Ag(1)-N(5) bond length is 2.30 Å. In the second Ag site, Ag(3) is bonded in a bent 150 degrees geometry to two equivalent N(2) atoms. Both Ag(3)-N(2) bond lengths are 2.15 Å. There are three inequivalent Si sites. In the first Si site, Si(1) is bonded in a tetrahedral geometry to one C(10), one C(3), one C(6), and one C(9) atom. The Si(1)-C(10) bond length is 1.89 Å. The Si(1)-C(3) bond length is 1.89 Å. The Si(1)-C(6) bond length is 1.87 Å. The Si(1)-C(9) bond length is 1.88 Å. In the second Si site, Si(2) is bonded in a tetrahedral geometry to one C(17), one C(20), one C(23), and one C(24) atom. The Si(2)-C(17) bond length is 1.90 Å. The Si(2)-C(20) bond length is 1.88 Å. The Si(2)-C(23) bond length is 1.87 Å. The Si(2)-C(24) bond length is 1.87 Å. In the third Si site, Si(3) is bonded in a tetrahedral geometry to one C(31), one C(34), one C(36), and one C(38) atom. The Si(3)-C(31) bond length is 1.90 Å. The Si(3)-C(34) bond length is 1.87 Å. The Si(3)-C(36) bond length is 1.84 Å. The Si(3)-C(38) bond length is 1.87 Å. There are thirty-two inequivalent C sites. In the first C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(2), and one H(15) atom. The C(13)-C(14) bond length is 1.43 Å. The C(13)-N(2) bond length is 1.33 Å. The C(13)-H(15) bond length is 0.93 Å. In the second C site, C(14) is bonded in a distorted single-bond geometry to one C(10), one C(13), and one H(16) atom. The C(14)-C(10) bond length is 1.34 Å. The C(14)-H(16) bond length is 0.93 Å. In the third C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(15)-N(3) bond length is 1.35 Å. The C(15)-H(17) bond length is 0.93 Å. In the fourth C site, C(17) is bonded in a trigonal planar geometry to one Si(2), one C(16), and one C(18) atom. The C(17)-C(16) bond length is 1.37 Å. The C(17)-C(18) bond length is 1.38 Å. In the fifth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(19) atom. The C(18)-C(19) bond length is 1.36 Å. The C(18)-H(19) bond length is 0.93 Å. In the sixth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(3), and one H(20) atom. The C(19)-N(3) bond length is 1.34 Å. The C(19)-H(20) bond length is 0.93 Å. In the seventh C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(18) atom. The C(16)-H(18) bond length is 0.93 Å. In the eighth C site, C(20) is bonded in a distorted water-like geometry to one Si(2) and two equivalent H(21,22,27) atoms. Both C(20)-H(21,22,27) bond lengths are 0.97 Å. In the ninth C site, C(23) is bonded in a distorted water-like geometry to one Si(2); one H(21,22,27); and one H(28) atom. The C(23)-H(21,22,27) bond length is 0.97 Å. The C(23)-H(28) bond length is 0.97 Å. In the tenth C site, C(24) is bonded in a trigonal planar geometry to one Si(2), one C(25), and one C(28) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-C(28) bond length is 1.40 Å. In the eleventh C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(29) atom. The C(25)-H(29) bond length is 0.93 Å. In the twelfth C site, C(28) is bonded in a distorted single-bond geometry to one C(24) and one H(32) atom. The C(28)-H(32) bond length is 0.93 Å. In the thirteenth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(30), one N(5), and one H(33) atom. The C(29)-C(30) bond length is 1.38 Å. The C(29)-N(5) bond length is 1.32 Å. The C(29)-H(33) bond length is 0.93 Å. In the fourteenth C site, C(30) is bonded in a distorted single-bond geometry to one C(29), one C(31), and one H(34) atom. The C(30)-C(31) bond length is 1.38 Å. The C(30)-H(34) bond length is 0.93 Å. In the fifteenth C site, C(31) is bonded in a trigonal planar geometry to one Si(3), one C(30), and one C(32) atom. The C(31)-C(32) bond length is 1.40 Å. In the sixteenth C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(35) atom. The C(32)-H(35) bond length is 0.93 Å. In the seventeenth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(36) atom. The C(33)-N(5) bond length is 1.34 Å. The C(33)-H(36) bond length is 0.93 Å. In the eighteenth C site, C(34) is bonded in a distorted water-like geometry to one Si(3) and two equivalent H(37,38,41) atoms. Both C(34)-H(37,38,41) bond lengths are 0.97 Å. In the nineteenth C site, C(36) is bonded in a distorted water-like geometry to one Si(3); one H(37,38,41); and one H(42) atom. The C(36)-H(37,38,41) bond length is 0.97 Å. The C(36)-H(42) bond length is 0.97 Å. In the twentieth C site, C(38) is bonded in a trigonal planar geometry to one Si(3), one C(39), and one C(42) atom. The C(38)-C(39) bond length is 1.37 Å. The C(38)-C(42) bond length is 1.39 Å. In the twenty-first C site, C(39) is bonded in a distorted single-bond geometry to one C(38) and one H(45) atom. The C(39)-H(45) bond length is 0.93 Å. In the twenty-second C site, C(42) is bonded in a distorted single-bond geometry to one C(38) and one H(48) atom. The C(42)-H(48) bond length is 0.93 Å. In the twenty-third C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the twenty-fourth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.35 Å. The C(2)-H(2) bond length is 0.93 Å. In the twenty-fifth C site, C(3) is bonded in a trigonal planar geometry to one Si(1), one C(2), and one C(4) atom. The C(3)-C(4) bond length is 1.43 Å. In the twenty-sixth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.93 Å. In the twenty-seventh C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(4) bond length is 0.93 Å. In the twenty-eighth C site, C(6) is bonded in a distorted water-like geometry to one Si(1) and two equivalent H(5,6) atoms. Both C(6)-H(5,6) bond lengths are 0.97 Å. In the twenty-ninth C site, C(9) is bonded in a distorted water-like geometry to one Si(1), one H(11), and one H(12) atom. The C(9)-H(11) bond length is 0.97 Å. The C(9)-H(12) bond length is 0.97 Å. In the thirtieth C site, C(10) is bonded in a trigonal planar geometry to one Si(1), one C(11), and one C(14) atom. The C(10)-C(11) bond length is 1.40 Å. In the thirty-first C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(13) atom. The C(11)-C(12) bond length is 1.34 Å. The C(11)-H(13) bond length is 0.93 Å. In the thirty-second C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one H(14) atom. The C(12)-N(2) bond length is 1.33 Å. The C(12)-H(14) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(3), one C(12), and one C(13) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(15), and one C(19) atom. In the fourth N site, N(5) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(29), and one C(33) atom. There are twenty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(19) atom. In the sixteenth H site, H(21,22,27) is bonded in a single-bond geometry to one C(20) atom. In the seventeenth H site, H(28) is bonded in a single-bond geometry to one C(23) atom. In the eighteenth H site, H(29) is bonded in a single-bond geometry to one C(25) atom. In the nineteenth H site, H(32) is bonded in a single-bond geometry to one C(28) atom. In the twentieth H site, H(33) is bonded in a single-bond geometry to one C(29) atom. In the twenty-first H site, H(34) is bonded in a single-bond geometry to one C(30) atom. In the twenty-second H site, H(35) is bonded in a single-bond geometry to one C(32) atom. In the twenty-third H site, H(36) is bonded in a single-bond geometry to one C(33) atom. In the twenty-fourth H site, H(37,38,41) is bonded in a single-bond geometry to one C(34) atom. In the twenty-fifth H site, H(42) is bonded in a single-bond geometry to one C(36) atom. In the twenty-sixth H site, H(45) is bonded in a single-bond geometry to one C(39) atom. In the twenty-seventh H site, H(48) is bonded in a single-bond geometry to one C(42) atom. In each AgH6(C2N)3 cluster, Ag(2) is bonded in a trigonal planar geometry to one N(4), one N(6), and one N(7) atom. The Ag(2)-N(4) bond length is 2.23 Å. The Ag(2)-N(6) bond length is 2.23 Å. The Ag(2)-N(7) bond length is 2.26 Å. There are six inequivalent C sites. In the first C site, C(47) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(52) atom. The C(47)-N(7) bond length is 1.32 Å. The C(47)-H(52) bond length is 0.93 Å. In the second C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(30) atom. The C(26)-N(4) bond length is 1.31 Å. The C(26)-H(30) bond length is 0.93 Å. In the third C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(31) atom. The C(27)-N(4) bond length is 1.36 Å. The C(27)-H(31) bond length is 0.93 Å. In the fourth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(46) atom. The C(40)-N(6) bond length is 1.34 Å. The C(40)-H(46) bond length is 0.93 Å. In the fifth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(47) atom. The C(41)-N(6) bond length is 1.32 Å. The C(41)-H(47) bond length is 0.93 Å. In the sixth C site, C(43) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(49) atom. The C(43)-N(7) bond length is 1.31 Å. The C(43)-H(49) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(7) is bonded in a trigonal planar geometry to one Ag(2), one C(43), and one C(47) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Ag(2), one C(26), and one C(27) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Ag(2), one C(40), and one C(41) atom. There are six inequivalent H sites. In the first H site, H(30) is bonded in a single-bond geometry to one C(26) atom. In the second H site, H(31) is bonded in a single-bond geometry to one C(27) atom. In the third H site, H(46) is bonded in a single-bond geometry to one C(40) atom. In the fourth H site, H(47) is bonded in a single-bond geometry to one C(41) atom. In the fifth H site, H(49) is bonded in a single-bond geometry to one C(43) atom. In the sixth H site, H(52) is bonded in a single-bond geometry to one C(47) atom. Linkers: 1 [Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[CH2].[CH2].[CH2].[CH2][Si].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C]/C=C\[N].[CH]=[C]/[C]=[C]\[N].[CH]=[N].[CH]N([CH])[Ag].[CH][CH][CH].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]#[C].[C]#[C].[C]/C=[C]\[N].[C]=[CH].[C]C(=[CH])[Si]1(C2=C[CH]N([Ag](N3[CH]C=C([Si])C=C3)N3[CH]C=C([Si]4(c5ccncc5)CCCC4)C=C3)C=C2)CCCC1.[C]N([C])[Ag].[C]N=[CH].[C]N=[C].[C]N=[C].[C]N=[C].[C][CH].[C][C].[C][C]=[CH].[C][C]C[CH2].[C][C][C].[C][C][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][Ag].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si] 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[Ag].[Ag].[Ag].[CH2].[CH2]CC[CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=CN=[CH].[CH]=[N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]=[C][CH].[C]N([CH])[Ag].[C]N([CH])[Ag][N].[C]N([C])[Ag].[C]N=[C].[C][CH].[C][C]([C])[Si].[C][C][C].[C][C][C][C].[C][N][C].[C][Si]C([C])=[C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si]C1=C[CH]N([Ag](N2[CH]C=C([Si]3CCCC3)C=C2)N2[CH]C=C([Si]3(C4=C[CH]N([Ag])C=C4)CCCC3)C=C2)C=C1.c1cc([Si]2(c3ccncc3)CCCC2)ccn1 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[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[CH2].[CH2].[CH2].[CH2].[CH2][Si].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C]/C=C\[N].[CH]=[C][Si].[CH]=[N].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#[C].[C]#[C].[C]=[CH].[C]N([C])[Ag].[C]N=[CH].[C]N=[C].[C]N=[C].[C]N=[C].[C][CH].[C][CH]CC[Si]([C])C1=C[CH]N([Ag](N2[CH]C=C([Si]3(C([C])=[CH])CCCC3)C=C2)N2[CH]C=C([Si]3(C4=C[CH]N([Ag][N])C=C4)CCCC3)C=C2)C=C1.[C][C].[C][C].[C][C]=[C].[C][N].[C][N][Ag].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si] 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[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[N].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#[C].[C]#[C].[C]#[C].[C]=C[N].[C]=[CH].[C]=[CH].[C]N([CH])[Ag].[C]N([C])[Ag][N].[C]N=[CH].[C]N=[CH].[C][CH][CH][CH2].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C]=[C].[C][C]=[C].[C][C][C].[C][C][C].[C][N].[C][N].[C][N].[C][N].[C][N][C].[C][Si]1(c2ccncc2)CCCC1.[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][Ag].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si]c1ccncc1 ,1 [Ag].[Ag].[Ag].[Ag]N1[CH]C=C([Si]2(C3=C[CH]N([Ag]N4[CH]C=C([Si]5(c6ccncc6)CCCC5)C=C4)C=C3)CCCC2)C=C1.[CH2].[CH2].[CH2].[CH2][CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#N.[C]#N.[C]#[C].[C]=[CH].[C]=[C][C]=[N].[C]N([C])[Ag].[C]N([C])[Ag].[C]N=[CH].[C]N=[CH].[C][CH].[C][C].[C][C]CC[Si].[C][C][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N]/C=C\[C][Si]1(c2ccncc2)[CH][CH][CH]C1.[N][Ag].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si] ,1 [Ag].[Ag].[Ag].[Ag].[Ag]N1[C][C]=[C][C]=[C]1.[CH2].[CH2].[CH2][Si].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]N=[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#N.[C]#[C].[C]#[C].[C]=[CH].[C]=[CH].[C]=[C][C]=[N].[C]CC[CH].[C]CC[C].[C]N=[C].[C][C].[C][C].[C][C].[C][C][CH].[C][N].[C][N].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N]/C=C\[C][Si]1(c2ccncc2)[CH][CH][CH]C1.[N][Ag]N1[CH]C=C([Si]2(C3=C[CH]N([Ag]N4[CH]C=C([Si]5(C6=C[CH]N([Ag])C=C6)CCCC5)C=C4)C=C3)CCCC2)C=C1.[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si] ,1 [Ag].[Ag].[Ag].[CH2].[CH2].[CH2][CH][CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=CN=[CH].[CH]=[N].[CH]N(/C=C\[C]=[CH])[Ag]([N])N1[CH]C=C([Si]2(c3ccncc3)CCCC2)C=C1.[CH][CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]/C=C\N([CH])[Ag].[C]=[CH].[C]C(=[C])[Si].[C]N([C])[Ag].[C]N([C])[Ag].[C]N([C])[Ag].[C]N=[C].[C][C].[C][C].[C][C]=[C].[C][C]=[C].[C][C][CH].[C][C][C].[C][N].[C][N][CH].[C][N][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si] ,1 [Ag].[Ag].[Ag].[Ag].[CH2].[CH2].[CH2].[CH2].[CH2].[CH2][CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[N].[CH]=[N].[CH]=[N].[CH][CH].[CH][C]=[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#[C].[C]/C=C\N([CH])[Ag](N1[CH]C=C([Si]2(c3ccncc3)CCCC2)C=C1)N([CH])/C=C\[C]=[CH].[C]=[CH].[C]C(=[CH])[Si].[C]N([C])[Ag].[C]N=[CH].[C]N=[C].[C][CH].[C][C].[C][C].[C][C][C].[C][N][C].[C][N][C].[C][Si]C([C])=[C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][Ag].[N][Ag].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[c]1[c]cncc1 ,1 [Ag].[Ag].[Ag].[Ag].[Ag].[CH2].[CH2].[CH2].[CH2]CC[Si].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C]/C=C\N=[CH].[CH]=[C]/C=C\[N].[CH]N([CH])[Ag].[CH]N=[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#[C].[C]=[CH].[C]C(=[C])[Si]1CCCC1.[C]N([CH])[Ag].[C]N([C])[Ag].[C]N([C])[Ag].[C]N=[CH].[C]N=[C].[C][C].[C][C].[C][C].[C][C]=[C].[C][C]=[C].[C][N].[C][N][CH].[C][N][C].[C][Si].[C][Si]1(c2ccncc2)CCCC1.[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][Ag].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si] ,1 [Ag].[Ag].[Ag].[CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[N].[CH]=[N].[CH]CC[CH2].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]=[C]/[C]=C\N([CH])[Ag].[C]C[C].[C]N([C])[Ag].[C]N([C])[Ag]N([CH])/C=[C]\[C]=[C].[C][C].[C][C]=[C].[C][C][C][C]=[N].[C][N][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][Ag].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].c1cc([Si]2(c3ccncc3)CCCC2)ccn1.c1cc([Si]2(c3ccncc3)CCCC2)ccn1 ,1 [Ag].[Ag].[Ag].[Ag].[Ag].[Ag].[CH2].[CH2].[CH2].[CH2]CC[CH2].[CH2][Si].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C]/C=C\N=[CH].[CH]=[C]/C=C\[N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#[C].[C]#[C].[C]=[CH].[C]=[CH].[C]N([C])[Ag].[C]N([C])[Ag].[C]N([C])[Ag][N].[C]N=[CH].[C]N=[C].[C][CH].[C][C].[C][C].[C][C]([C])[Si].[C][C]=[CH].[C][C]=[C].[C][C]=[C].[C][N].[C][N].[C][N][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][Ag].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si].[Si]c1ccncc1. Metal clusters: 3 [Ag]. The MOF has largest included sphere 5.64 A, density 1.20 g/cm3, surface area 4911.77 m2/g, accessible volume 0.40 cm3/g