CuC11NH12O3(CH)3 crystallizes in the cubic Ia-3d space group. The structure consists of two hundred and eighty-eight 02329_fluka molecules inside a CuC11NH12O3 framework. In the CuC11NH12O3 framework, Cu(1) is bonded to one N(1), one O(2), one O(3), and two equivalent O(1) atoms to form distorted CuNO4 square pyramids that share  a cornercorner with one C(8)C3N tetrahedra and  an edgeedge with one Cu(1)NO4 square pyramid. The Cu(1)-N(1) bond length is 1.99 Å. The Cu(1)-O(2) bond length is 1.95 Å. The Cu(1)-O(3) bond length is 2.25 Å. Both Cu(1)-O(1) bond lengths are 1.95 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one O(1) atom. The C(1)-C(6) bond length is 1.40 Å. The C(1)-O(1) bond length is 1.34 Å. In the second C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.38 Å. The C(5)-H(4) bond length is 0.94 Å. In the third C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.51 Å. In the fourth C site, C(7) is bonded in a 3-coordinate geometry to one C(6); one N(1); and two equivalent H(5,6) atoms. The C(7)-N(1) bond length is 1.49 Å. Both C(7)-H(5,6) bond lengths are 0.98 Å. In the fifth C site, C(8) is bonded to one C(12), one C(13), one C(9), and one N(1) atom to form distorted CC3N tetrahedra that share  a cornercorner with one Cu(1)NO4 square pyramid. The C(8)-C(12) bond length is 1.56 Å. The C(8)-C(13) bond length is 1.53 Å. The C(8)-C(9) bond length is 1.54 Å. The C(8)-N(1) bond length is 1.49 Å. In the sixth C site, C(9) is bonded in a water-like geometry to one C(8) and two equivalent H(8,9) atoms. Both C(9)-H(8,9) bond lengths are 0.98 Å. In the seventh C site, C(10) is bonded in a water-like geometry to one C(14), one H(10), and one H(11) atom. The C(10)-C(14) bond length is 1.55 Å. The C(10)-H(10) bond length is 0.98 Å. The C(10)-H(11) bond length is 0.98 Å. In the eighth C site, C(11) is bonded in a distorted water-like geometry to one C(14), one H(12), and one H(13) atom. The C(11)-C(14) bond length is 1.11 Å. The C(11)-H(12) bond length is 0.98 Å. The C(11)-H(13) bond length is 0.98 Å. In the ninth C site, C(12) is bonded in a water-like geometry to one C(14), one C(8), one H(14), and one H(15) atom. The C(12)-C(14) bond length is 1.54 Å. The C(12)-H(14) bond length is 0.98 Å. The C(12)-H(15) bond length is 0.98 Å. In the tenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(2), and one O(3) atom. The C(13)-O(2) bond length is 1.29 Å. The C(13)-O(3) bond length is 1.23 Å. In the eleventh C site, C(14) is bonded in a 6-coordinate geometry to one C(10), one C(11), one C(12), one H(11), one H(12), and one H(15) atom. The C(14)-H(11) bond length is 1.53 Å. The C(14)-H(12) bond length is 1.21 Å. The C(14)-H(15) bond length is 1.55 Å. N(1) is bonded in a distorted single-bond geometry to one Cu(1), one C(7), one C(8), and one H(7) atom. The N(1)-H(7) bond length is 0.81 Å. There are ten inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(5,6) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(7) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(8,9) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(11) is bonded in a distorted single-bond geometry to one C(10) and one C(14) atom. In the seventh H site, H(12) is bonded in a distorted single-bond geometry to one C(11) and one C(14) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(12) and one C(14) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to two equivalent Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(13) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(13) atom. Linkers: 96 [CH2]C[C]CC[C](NCc1ccccc1[O])C([O])=O. Metal clusters: 96 [Cu]. The MOF has largest included sphere 6.11 A, density 1.31 g/cm3, surface area 4183.27 m2/g, accessible volume 0.34 cm3/g