CoCdC26H26(NO3)2(CH2)4 crystallizes in the monoclinic C2 space group. The structure consists of sixty-four 02329_fluka molecules inside a CoCdC26H26(NO3)2 framework. In the CoCdC26H26(NO3)2 framework, there are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a square co-planar geometry to one N(1), one N(2), one O(3), and one O(4) atom. The Co(1)-N(1) bond length is 1.80 Å. The Co(1)-N(2) bond length is 1.82 Å. The Co(1)-O(3) bond length is 1.90 Å. The Co(1)-O(4) bond length is 1.89 Å. In the second Co site, Co(2) is bonded in a rectangular see-saw-like geometry to one N(3), one N(4), one O(10), and one O(9) atom. The Co(2)-N(3) bond length is 1.79 Å. The Co(2)-N(4) bond length is 1.83 Å. The Co(2)-O(10) bond length is 1.96 Å. The Co(2)-O(9) bond length is 1.81 Å. In the third Co site, Co(3) is bonded in a rectangular see-saw-like geometry to one N(5), one N(6), one O(15), and one O(16) atom. The Co(3)-N(5) bond length is 1.91 Å. The Co(3)-N(6) bond length is 1.94 Å. The Co(3)-O(15) bond length is 1.78 Å. The Co(3)-O(16) bond length is 1.80 Å. In the fourth Co site, Co(4) is bonded in a rectangular see-saw-like geometry to one N(7), one N(8), one O(21), and one O(22) atom. The Co(4)-N(7) bond length is 1.84 Å. The Co(4)-N(8) bond length is 1.94 Å. The Co(4)-O(21) bond length is 1.75 Å. The Co(4)-O(22) bond length is 1.97 Å. There are six inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one O(18), one O(20), one O(5), one O(6), and one O(8) atom to form distorted corner-sharing CdO5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 79°. The Cd(1)-O(18) bond length is 2.33 Å. The Cd(1)-O(20) bond length is 2.28 Å. The Cd(1)-O(5) bond length is 2.47 Å. The Cd(1)-O(6) bond length is 2.15 Å. The Cd(1)-O(8) bond length is 2.32 Å. In the second Cd site, Cd(2) is bonded to one O(1), one O(11), one O(13), one O(14), and one O(23) atom to form distorted corner-sharing CdO5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 85°. The Cd(2)-O(1) bond length is 2.25 Å. The Cd(2)-O(11) bond length is 2.01 Å. The Cd(2)-O(13) bond length is 2.41 Å. The Cd(2)-O(14) bond length is 2.51 Å. The Cd(2)-O(23) bond length is 2.40 Å. In the third Cd site, Cd(3) is bonded to two equivalent O(17), two equivalent O(19), and two equivalent O(5) atoms to form corner-sharing CdO6 octahedra. Both Cd(3)-O(17) bond lengths are 2.20 Å. Both Cd(3)-O(19) bond lengths are 2.34 Å. Both Cd(3)-O(5) bond lengths are 2.30 Å. In the fourth Cd site, Cd(4) is bonded in a distorted square co-planar geometry to two equivalent O(19) and two equivalent O(7) atoms. Both Cd(4)-O(19) bond lengths are 2.30 Å. Both Cd(4)-O(7) bond lengths are 2.32 Å. In the fifth Cd site, Cd(5) is bonded in a rectangular see-saw-like geometry to two equivalent O(12) and two equivalent O(24) atoms. Both Cd(5)-O(12) bond lengths are 2.37 Å. Both Cd(5)-O(24) bond lengths are 2.05 Å. In the sixth Cd site, Cd(6) is bonded to two equivalent O(12), two equivalent O(14), and two equivalent O(2) atoms to form corner-sharing CdO6 octahedra. Both Cd(6)-O(12) bond lengths are 2.35 Å. Both Cd(6)-O(14) bond lengths are 2.43 Å. Both Cd(6)-O(2) bond lengths are 2.21 Å. There are one hundred and four inequivalent C sites. In the first C site, C(56) is bonded in a tetrahedral geometry to one C(52), one C(57), one C(58), and one C(59) atom. The C(56)-C(52) bond length is 1.56 Å. The C(56)-C(57) bond length is 1.54 Å. The C(56)-C(58) bond length is 1.55 Å. The C(56)-C(59) bond length is 1.55 Å. In the second C site, C(38) is bonded in a tetrahedral geometry to one C(36), one C(39), one C(40), and one C(41) atom. The C(38)-C(36) bond length is 1.54 Å. The C(38)-C(39) bond length is 1.54 Å. The C(38)-C(40) bond length is 1.54 Å. The C(38)-C(41) bond length is 1.52 Å. In the third C site, C(39) is bonded in a trigonal non-coplanar geometry to one C(38), one H(37), one H(38), and one H(39) atom. The C(39)-H(37) bond length is 0.96 Å. The C(39)-H(38) bond length is 0.96 Å. The C(39)-H(39) bond length is 0.96 Å. In the fourth C site, C(40) is bonded in a trigonal non-coplanar geometry to one C(38); one H(41,45); and two equivalent H(40,42,43,44) atoms. The C(40)-H(41,45) bond length is 0.96 Å. Both C(40)-H(40,42,43,44) bond lengths are 0.96 Å. In the fifth C site, C(41) is bonded in a trigonal non-coplanar geometry to one C(38); one H(41,45); and two equivalent H(40,42,43,44) atoms. The C(41)-H(41,45) bond length is 0.96 Å. Both C(41)-H(40,42,43,44) bond lengths are 0.96 Å. In the sixth C site, C(57) is bonded in a trigonal non-coplanar geometry to one C(56); one H(60); and two equivalent H(61,62,64) atoms. The C(57)-H(60) bond length is 0.96 Å. Both C(57)-H(61,62,64) bond lengths are 0.96 Å. In the seventh C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(34), one N(3), and one H(46) atom. The C(42)-C(34) bond length is 1.39 Å. The C(42)-N(3) bond length is 1.37 Å. The C(42)-H(46) bond length is 0.93 Å. In the eighth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.55 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.22 Å. In the ninth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.39 Å. In the tenth C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 0.93 Å. In the eleventh C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-C(9) bond length is 1.54 Å. In the twelfth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one O(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-O(3) bond length is 1.33 Å. In the thirteenth C site, C(6) is bonded in a trigonal planar geometry to one C(12), one C(5), and one C(7) atom. The C(6)-C(12) bond length is 1.38 Å. The C(6)-C(7) bond length is 1.39 Å. In the fourteenth C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(2) atom. The C(7)-H(2) bond length is 0.93 Å. In the fifteenth C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(9); one H(3); one H(4); and one H(5,11,66) atom. The C(8)-C(9) bond length is 1.55 Å. The C(8)-H(3) bond length is 0.96 Å. The C(8)-H(4) bond length is 0.96 Å. The C(8)-H(5,11,66) bond length is 0.96 Å. In the sixteenth C site, C(9) is bonded in a tetrahedral geometry to one C(10), one C(11), one C(4), and one C(8) atom. The C(9)-C(10) bond length is 1.55 Å. The C(9)-C(11) bond length is 1.54 Å. In the seventeenth C site, C(10) is bonded in a trigonal non-coplanar geometry to one C(9) and three equivalent H(6,7,8) atoms. All C(10)-H(6,7,8) bond lengths are 0.96 Å. In the eighteenth C site, C(11) is bonded in a trigonal non-coplanar geometry to one C(9); one H(10); one H(5,11,66); and one H(9,67) atom. The C(11)-H(10) bond length is 0.96 Å. The C(11)-H(5,11,66) bond length is 0.96 Å. The C(11)-H(9,67) bond length is 0.96 Å. In the nineteenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one H(12) atom. The C(12)-N(1) bond length is 1.23 Å. The C(12)-H(12) bond length is 0.93 Å. In the twentieth C site, C(13) is bonded in a 1-coordinate geometry to one N(1) and one H(13) atom. The C(13)-N(1) bond length is 1.45 Å. The C(13)-H(13) bond length is 0.98 Å. In the twenty-first C site, C(18) is bonded in a 2-coordinate geometry to one N(2) and one H(22) atom. The C(18)-N(2) bond length is 1.53 Å. The C(18)-H(22) bond length is 0.98 Å. In the twenty-second C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one O(4) atom. The C(21)-C(20) bond length is 1.39 Å. The C(21)-C(22) bond length is 1.39 Å. The C(21)-O(4) bond length is 1.31 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(22), one C(24), and one H(24) atom. The C(23)-C(22) bond length is 1.39 Å. The C(23)-C(24) bond length is 1.39 Å. The C(23)-H(24) bond length is 0.93 Å. In the twenty-fourth C site, C(25) is bonded in a single-bond geometry to one C(20), one C(24), and one H(25) atom. The C(25)-C(20) bond length is 1.39 Å. The C(25)-C(24) bond length is 1.39 Å. The C(25)-H(25) bond length is 0.93 Å. In the twenty-fifth C site, C(26) is bonded in a tetrahedral geometry to one C(22), one C(27), one C(28), and one C(29) atom. The C(26)-C(22) bond length is 1.55 Å. The C(26)-C(27) bond length is 1.54 Å. The C(26)-C(28) bond length is 1.54 Å. The C(26)-C(29) bond length is 1.55 Å. In the twenty-sixth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(7), and one O(8) atom. The C(31)-C(32) bond length is 1.56 Å. The C(31)-O(7) bond length is 1.30 Å. The C(31)-O(8) bond length is 1.44 Å. In the twenty-seventh C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(37) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-C(37) bond length is 1.39 Å. In the twenty-eighth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(42) atom. The C(34)-C(33) bond length is 1.39 Å. The C(34)-C(35) bond length is 1.39 Å. In the twenty-ninth C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(38) atom. The C(36)-C(35) bond length is 1.39 Å. The C(36)-C(37) bond length is 1.39 Å. In the thirtieth C site, C(37) is bonded in a distorted single-bond geometry to one C(32), one C(36), and one H(36) atom. The C(37)-H(36) bond length is 0.93 Å. In the thirty-first C site, C(43) is bonded in a 1-coordinate geometry to one N(3) and one H(47) atom. The C(43)-N(3) bond length is 1.49 Å. The C(43)-H(47) bond length is 0.98 Å. In the thirty-second C site, C(48) is bonded in a 1-coordinate geometry to one N(4) and one H(56) atom. The C(48)-N(4) bond length is 1.50 Å. The C(48)-H(56) bond length is 0.98 Å. In the thirty-third C site, C(49) is bonded in a 3-coordinate geometry to one C(50), one N(4), and one H(57) atom. The C(49)-C(50) bond length is 1.38 Å. The C(49)-N(4) bond length is 1.42 Å. The C(49)-H(57) bond length is 0.93 Å. In the thirty-fourth C site, C(50) is bonded in a trigonal planar geometry to one C(49), one C(51), and one C(55) atom. The C(50)-C(51) bond length is 1.39 Å. The C(50)-C(55) bond length is 1.39 Å. In the thirty-fifth C site, C(51) is bonded in a distorted single-bond geometry to one C(50), one C(52), and one O(10) atom. The C(51)-C(52) bond length is 1.39 Å. The C(51)-O(10) bond length is 1.29 Å. In the thirty-sixth C site, C(52) is bonded in a trigonal planar geometry to one C(51), one C(53), and one C(56) atom. The C(52)-C(53) bond length is 1.39 Å. In the thirty-seventh C site, C(58) is bonded in a trigonal non-coplanar geometry to one C(56); one H(61,62,64); one H(63); and one H(65) atom. The C(58)-H(61,62,64) bond length is 0.96 Å. The C(58)-H(63) bond length is 0.96 Å. The C(58)-H(65) bond length is 0.96 Å. In the thirty-eighth C site, C(60) is bonded in a distorted bent 120 degrees geometry to one C(54), one O(11), and one O(12) atom. The C(60)-C(54) bond length is 1.35 Å. The C(60)-O(11) bond length is 1.42 Å. The C(60)-O(12) bond length is 1.29 Å. In the thirty-ninth C site, C(61) is bonded in a distorted bent 120 degrees geometry to one C(62), one O(13), and one O(14) atom. The C(61)-C(62) bond length is 1.50 Å. The C(61)-O(13) bond length is 1.22 Å. The C(61)-O(14) bond length is 1.21 Å. In the fortieth C site, C(62) is bonded in a trigonal planar geometry to one C(61), one C(63), and one C(67) atom. The C(62)-C(63) bond length is 1.39 Å. The C(62)-C(67) bond length is 1.39 Å. In the forty-first C site, C(63) is bonded in a distorted single-bond geometry to one C(62), one C(64), and one H(69) atom. The C(63)-C(64) bond length is 1.39 Å. The C(63)-H(69) bond length is 0.93 Å. In the forty-second C site, C(64) is bonded in a trigonal planar geometry to one C(63), one C(65), and one C(68) atom. The C(64)-C(65) bond length is 1.39 Å. The C(64)-C(68) bond length is 1.53 Å. In the forty-third C site, C(74) is bonded in a 1-coordinate geometry to one N(5) and one H(83) atom. The C(74)-N(5) bond length is 1.49 Å. The C(74)-H(83) bond length is 0.98 Å. In the forty-fourth C site, C(78) is bonded in a 2-coordinate geometry to one N(6) and one H(90) atom. The C(78)-N(6) bond length is 1.45 Å. The C(78)-H(90) bond length is 0.98 Å. In the forty-fifth C site, C(79) is bonded in a distorted bent 120 degrees geometry to one C(80), one N(6), and one H(91) atom. The C(79)-C(80) bond length is 1.53 Å. The C(79)-N(6) bond length is 1.23 Å. The C(79)-H(91) bond length is 0.93 Å. In the forty-sixth C site, C(65) is bonded in a distorted single-bond geometry to one C(64), one C(66), and one O(15) atom. The C(65)-C(66) bond length is 1.39 Å. The C(65)-O(15) bond length is 1.36 Å. In the forty-seventh C site, C(80) is bonded in a trigonal planar geometry to one C(79), one C(81), and one C(85) atom. The C(80)-C(81) bond length is 1.39 Å. The C(80)-C(85) bond length is 1.39 Å. In the forty-eighth C site, C(81) is bonded in a distorted single-bond geometry to one C(80), one C(82), and one O(16) atom. The C(81)-C(82) bond length is 1.39 Å. The C(81)-O(16) bond length is 1.40 Å. In the forty-ninth C site, C(66) is bonded in a trigonal planar geometry to one C(65), one C(67), and one C(73) atom. The C(66)-C(67) bond length is 1.39 Å. The C(66)-C(73) bond length is 1.41 Å. In the fiftieth C site, C(83) is bonded in a distorted single-bond geometry to one C(82), one C(84), and one H(92) atom. The C(83)-C(82) bond length is 1.39 Å. The C(83)-C(84) bond length is 1.39 Å. The C(83)-H(92) bond length is 0.93 Å. In the fifty-first C site, C(67) is bonded in a single-bond geometry to one C(62), one C(66), and one H(70) atom. The C(67)-H(70) bond length is 0.93 Å. In the fifty-second C site, C(68) is bonded in a tetrahedral geometry to one C(64), one C(69), one C(70), and one C(72) atom. The C(68)-C(69) bond length is 1.54 Å. The C(68)-C(70) bond length is 1.55 Å. The C(68)-C(72) bond length is 1.56 Å. In the fifty-third C site, C(93) is bonded in a single-bond geometry to one C(92), one C(94), and one H(103) atom. The C(93)-C(92) bond length is 1.39 Å. The C(93)-C(94) bond length is 1.39 Å. The C(93)-H(103) bond length is 0.93 Å. In the fifty-fourth C site, C(95) is bonded in a distorted single-bond geometry to one C(94), one C(96), and one O(21) atom. The C(95)-C(94) bond length is 1.39 Å. The C(95)-C(96) bond length is 1.39 Å. The C(95)-O(21) bond length is 1.34 Å. In the fifty-fifth C site, C(96) is bonded in a trigonal planar geometry to one C(95), one C(97), and one C(99) atom. The C(96)-C(97) bond length is 1.39 Å. The C(96)-C(99) bond length is 1.55 Å. In the fifty-sixth C site, C(69) is bonded in a trigonal non-coplanar geometry to one C(68) and three equivalent H(71,72,73) atoms. All C(69)-H(71,72,73) bond lengths are 0.96 Å. In the fifty-seventh C site, C(98) is bonded in a trigonal non-coplanar geometry to one C(99), one H(105), one H(106), and one H(107) atom. The C(98)-C(99) bond length is 1.55 Å. The C(98)-H(105) bond length is 0.96 Å. The C(98)-H(106) bond length is 0.96 Å. The C(98)-H(107) bond length is 0.96 Å. In the fifty-eighth C site, C(99) is bonded in a tetrahedral geometry to one C(100), one C(101), one C(96), and one C(98) atom. The C(99)-C(100) bond length is 1.54 Å. The C(99)-C(101) bond length is 1.53 Å. In the fifty-ninth C site, C(100) is bonded in a trigonal non-coplanar geometry to one C(99) and three equivalent H(108,109,110) atoms. All C(100)-H(108,109,110) bond lengths are 0.96 Å. In the sixtieth C site, C(101) is bonded in a trigonal non-coplanar geometry to one C(99); one H(112); and two equivalent H(111,113) atoms. The C(101)-H(112) bond length is 0.96 Å. Both C(101)-H(111,113) bond lengths are 0.96 Å. In the sixty-first C site, C(70) is bonded in a trigonal non-coplanar geometry to one C(68); one H(76); and two equivalent H(74,75) atoms. The C(70)-H(76) bond length is 0.96 Å. Both C(70)-H(74,75) bond lengths are 0.96 Å. In the sixty-second C site, C(106) is bonded in a bent 120 degrees geometry to one C(110), one N(8), and one H(121) atom. The C(106)-C(110) bond length is 1.56 Å. The C(106)-N(8) bond length is 1.21 Å. The C(106)-H(121) bond length is 0.93 Å. In the sixty-third C site, C(107) is bonded in a 2-coordinate geometry to one N(7) and one H(122) atom. The C(107)-N(7) bond length is 1.48 Å. The C(107)-H(122) bond length is 0.98 Å. In the sixty-fourth C site, C(109) is bonded in a 2-coordinate geometry to one N(8) and one H(125) atom. The C(109)-N(8) bond length is 1.45 Å. The C(109)-H(125) bond length is 0.98 Å. In the sixty-fifth C site, C(110) is bonded in a trigonal planar geometry to one C(106), one C(111), and one C(115) atom. The C(110)-C(111) bond length is 1.39 Å. The C(110)-C(115) bond length is 1.39 Å. In the sixty-sixth C site, C(111) is bonded in a distorted single-bond geometry to one C(110), one C(112), and one O(22) atom. The C(111)-C(112) bond length is 1.39 Å. The C(111)-O(22) bond length is 1.35 Å. In the sixty-seventh C site, C(112) is bonded in a trigonal planar geometry to one C(111), one C(113), and one C(117) atom. The C(112)-C(113) bond length is 1.39 Å. The C(112)-C(117) bond length is 1.55 Å. In the sixty-eighth C site, C(113) is bonded in a distorted single-bond geometry to one C(112), one C(114), and one H(126) atom. The C(113)-C(114) bond length is 1.39 Å. The C(113)-H(126) bond length is 0.93 Å. In the sixty-ninth C site, C(114) is bonded in a trigonal planar geometry to one C(113), one C(115), and one C(120) atom. The C(114)-C(115) bond length is 1.39 Å. The C(114)-C(120) bond length is 1.47 Å. In the seventieth C site, C(115) is bonded in a distorted single-bond geometry to one C(110), one C(114), and one H(127) atom. The C(115)-H(127) bond length is 0.93 Å. In the seventy-first C site, C(72) is bonded in a trigonal non-coplanar geometry to one C(68), one H(79), one H(80), and one H(81) atom. The C(72)-H(79) bond length is 0.96 Å. The C(72)-H(80) bond length is 0.96 Å. The C(72)-H(81) bond length is 0.96 Å. In the seventy-second C site, C(116) is bonded in a trigonal non-coplanar geometry to one C(117), one H(128), one H(129), and one H(130) atom. The C(116)-C(117) bond length is 1.54 Å. The C(116)-H(128) bond length is 0.96 Å. The C(116)-H(129) bond length is 0.96 Å. The C(116)-H(130) bond length is 0.96 Å. In the seventy-third C site, C(117) is bonded in a tetrahedral geometry to one C(112), one C(116), one C(118), and one C(119) atom. The C(117)-C(118) bond length is 1.54 Å. The C(117)-C(119) bond length is 1.54 Å. In the seventy-fourth C site, C(118) is bonded in a trigonal non-coplanar geometry to one C(117) and three equivalent H(131,132,133,134,136) atoms. All C(118)-H(131,132,133,134,136) bond lengths are 0.96 Å. In the seventy-fifth C site, C(119) is bonded in a trigonal non-coplanar geometry to one C(117); one H(135); and two equivalent H(131,132,133,134,136) atoms. The C(119)-H(135) bond length is 0.96 Å. Both C(119)-H(131,132,133,134,136) bond lengths are 0.96 Å. In the seventy-sixth C site, C(73) is bonded in a distorted bent 120 degrees geometry to one C(66), one N(5), and one H(82) atom. The C(73)-N(5) bond length is 1.30 Å. The C(73)-H(82) bond length is 0.93 Å. In the seventy-seventh C site, C(120) is bonded in a distorted bent 120 degrees geometry to one C(114), one O(23), and one O(24) atom. The C(120)-O(23) bond length is 1.22 Å. The C(120)-O(24) bond length is 1.26 Å. In the seventy-eighth C site, C(82) is bonded in a trigonal planar geometry to one C(81), one C(83), and one C(86) atom. The C(82)-C(86) bond length is 1.56 Å. In the seventy-ninth C site, C(84) is bonded in a trigonal planar geometry to one C(83), one C(85), and one C(91) atom. The C(84)-C(85) bond length is 1.39 Å. The C(84)-C(91) bond length is 1.53 Å. In the eightieth C site, C(85) is bonded in a distorted single-bond geometry to one C(80), one C(84), and one H(93) atom. The C(85)-H(93) bond length is 0.93 Å. In the eighty-first C site, C(86) is bonded in a tetrahedral geometry to one C(82), one C(87), one C(88), and one C(89) atom. The C(86)-C(87) bond length is 1.56 Å. The C(86)-C(88) bond length is 1.52 Å. The C(86)-C(89) bond length is 1.52 Å. In the eighty-second C site, C(87) is bonded in a trigonal non-coplanar geometry to one C(86), one H(94), one H(95), and one H(96) atom. The C(87)-H(94) bond length is 0.96 Å. The C(87)-H(95) bond length is 0.96 Å. The C(87)-H(96) bond length is 0.96 Å. In the eighty-third C site, C(88) is bonded in a trigonal non-coplanar geometry to one C(86); one H(97); and two equivalent H(98,99) atoms. The C(88)-H(97) bond length is 0.96 Å. Both C(88)-H(98,99) bond lengths are 0.96 Å. In the eighty-fourth C site, C(89) is bonded in a trigonal non-coplanar geometry to one C(86) and three equivalent H(100,101,102) atoms. All C(89)-H(100,101,102) bond lengths are 0.96 Å. In the eighty-fifth C site, C(90) is bonded in a distorted bent 120 degrees geometry to one C(92), one O(19), and one O(20) atom. The C(90)-C(92) bond length is 1.57 Å. The C(90)-O(19) bond length is 1.24 Å. The C(90)-O(20) bond length is 1.18 Å. In the eighty-sixth C site, C(91) is bonded in a distorted bent 120 degrees geometry to one C(84), one O(17), and one O(18) atom. The C(91)-O(17) bond length is 1.31 Å. The C(91)-O(18) bond length is 1.25 Å. In the eighty-seventh C site, C(92) is bonded in a trigonal planar geometry to one C(90), one C(93), and one C(97) atom. The C(92)-C(97) bond length is 1.39 Å. In the eighty-eighth C site, C(94) is bonded in a trigonal planar geometry to one C(102), one C(93), and one C(95) atom. The C(94)-C(102) bond length is 1.46 Å. In the eighty-ninth C site, C(97) is bonded in a distorted single-bond geometry to one C(92), one C(96), and one H(104) atom. The C(97)-H(104) bond length is 0.93 Å. In the ninetieth C site, C(102) is bonded in a distorted bent 120 degrees geometry to one C(94), one N(7), and one H(114) atom. The C(102)-N(7) bond length is 1.20 Å. The C(102)-H(114) bond length is 0.93 Å. In the ninety-first C site, C(59) is bonded in a trigonal non-coplanar geometry to one C(56); one H(5,11,66); one H(68); and one H(9,67) atom. The C(59)-H(5,11,66) bond length is 0.96 Å. The C(59)-H(68) bond length is 0.96 Å. The C(59)-H(9,67) bond length is 0.96 Å. In the ninety-second C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(2), and one H(23) atom. The C(19)-C(20) bond length is 1.45 Å. The C(19)-N(2) bond length is 1.30 Å. The C(19)-H(23) bond length is 0.93 Å. In the ninety-third C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(25) atom. In the ninety-fourth C site, C(53) is bonded in a distorted single-bond geometry to one C(52), one C(54), and one H(58) atom. The C(53)-C(54) bond length is 1.39 Å. The C(53)-H(58) bond length is 0.93 Å. In the ninety-fifth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(26) atom. In the ninety-sixth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(30) atom. The C(24)-C(30) bond length is 1.48 Å. In the ninety-seventh C site, C(54) is bonded in a trigonal planar geometry to one C(53), one C(55), and one C(60) atom. The C(54)-C(55) bond length is 1.39 Å. In the ninety-eighth C site, C(27) is bonded in a trigonal non-coplanar geometry to one C(26), one H(26), one H(27), and one H(28) atom. The C(27)-H(26) bond length is 0.96 Å. The C(27)-H(27) bond length is 0.96 Å. The C(27)-H(28) bond length is 0.96 Å. In the ninety-ninth C site, C(28) is bonded in a trigonal non-coplanar geometry to one C(26); one H(31); and two equivalent H(29,30) atoms. The C(28)-H(31) bond length is 0.96 Å. Both C(28)-H(29,30) bond lengths are 0.96 Å. In the one hundredth C site, C(29) is bonded in a trigonal non-coplanar geometry to one C(26) and three equivalent H(32,33,34) atoms. All C(29)-H(32,33,34) bond lengths are 0.96 Å. In the one hundred and first C site, C(30) is bonded in a bent 120 degrees geometry to one C(24), one O(5), and one O(6) atom. The C(30)-O(5) bond length is 1.32 Å. The C(30)-O(6) bond length is 1.24 Å. In the one hundred and second C site, C(55) is bonded in a single-bond geometry to one C(50), one C(54), and one H(59) atom. The C(55)-H(59) bond length is 0.93 Å. In the one hundred and third C site, C(33) is bonded in a distorted trigonal planar geometry to one C(32), one C(34), and one H(35) atom. The C(33)-H(35) bond length is 0.93 Å. In the one hundred and fourth C site, C(35) is bonded in a distorted single-bond geometry to one C(34), one C(36), and one O(9) atom. The C(35)-O(9) bond length is 1.29 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(12), and one C(13) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(18), and one C(19) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Co(3), one C(73), and one C(74) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one Co(3), one C(78), and one C(79) atom. In the fifth N site, N(7) is bonded in a trigonal planar geometry to one Co(4), one C(102), and one C(107) atom. In the sixth N site, N(8) is bonded in a trigonal planar geometry to one Co(4), one C(106), and one C(109) atom. In the seventh N site, N(3) is bonded in a trigonal planar geometry to one Co(2), one C(42), and one C(43) atom. In the eighth N site, N(4) is bonded in a trigonal planar geometry to one Co(2), one C(48), and one C(49) atom. There are seventy-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5,11,66) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(6,7,8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9,67) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(22) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(23) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(24) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(25) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(26) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(27) is bonded in a single-bond geometry to one C(27) atom. In the seventeenth H site, H(28) is bonded in a single-bond geometry to one C(27) atom. In the eighteenth H site, H(29,30) is bonded in a single-bond geometry to one C(28) atom. In the nineteenth H site, H(31) is bonded in a single-bond geometry to one C(28) atom. In the twentieth H site, H(32,33,34) is bonded in a single-bond geometry to one C(29) atom. In the twenty-first H site, H(35) is bonded in a single-bond geometry to one C(33) atom. In the twenty-second H site, H(36) is bonded in a single-bond geometry to one C(37) atom. In the twenty-third H site, H(37) is bonded in a single-bond geometry to one C(39) atom. In the twenty-fourth H site, H(38) is bonded in a single-bond geometry to one C(39) atom. In the twenty-fifth H site, H(39) is bonded in a single-bond geometry to one C(39) atom. In the twenty-sixth H site, H(40,42,43,44) is bonded in a single-bond geometry to one C(40) atom. In the twenty-seventh H site, H(41,45) is bonded in a single-bond geometry to one C(40) atom. In the twenty-eighth H site, H(46) is bonded in a single-bond geometry to one C(42) atom. In the twenty-ninth H site, H(47) is bonded in a single-bond geometry to one C(43) atom. In the thirtieth H site, H(56) is bonded in a single-bond geometry to one C(48) atom. In the thirty-first H site, H(57) is bonded in a single-bond geometry to one C(49) atom. In the thirty-second H site, H(58) is bonded in a single-bond geometry to one C(53) atom. In the thirty-third H site, H(59) is bonded in a single-bond geometry to one C(55) atom. In the thirty-fourth H site, H(60) is bonded in a single-bond geometry to one C(57) atom. In the thirty-fifth H site, H(61,62,64) is bonded in a single-bond geometry to one C(57) atom. In the thirty-sixth H site, H(63) is bonded in a single-bond geometry to one C(58) atom. In the thirty-seventh H site, H(65) is bonded in a single-bond geometry to one C(58) atom. In the thirty-eighth H site, H(68) is bonded in a single-bond geometry to one C(59) atom. In the thirty-ninth H site, H(69) is bonded in a single-bond geometry to one C(63) atom. In the fortieth H site, H(70) is bonded in a single-bond geometry to one C(67) atom. In the forty-first H site, H(71,72,73) is bonded in a single-bond geometry to one C(69) atom. In the forty-second H site, H(74,75) is bonded in a single-bond geometry to one C(70) atom. In the forty-third H site, H(76) is bonded in a single-bond geometry to one C(70) atom. In the forty-fourth H site, H(79) is bonded in a single-bond geometry to one C(72) atom. In the forty-fifth H site, H(80) is bonded in a single-bond geometry to one C(72) atom. In the forty-sixth H site, H(81) is bonded in a single-bond geometry to one C(72) atom. In the forty-seventh H site, H(82) is bonded in a single-bond geometry to one C(73) atom. In the forty-eighth H site, H(83) is bonded in a single-bond geometry to one C(74) atom. In the forty-ninth H site, H(90) is bonded in a single-bond geometry to one C(78) atom. In the fiftieth H site, H(91) is bonded in a single-bond geometry to one C(79) atom. In the fifty-first H site, H(92) is bonded in a single-bond geometry to one C(83) atom. In the fifty-second H site, H(93) is bonded in a single-bond geometry to one C(85) atom. In the fifty-third H site, H(94) is bonded in a single-bond geometry to one C(87) atom. In the fifty-fourth H site, H(95) is bonded in a single-bond geometry to one C(87) atom. In the fifty-fifth H site, H(96) is bonded in a single-bond geometry to one C(87) atom. In the fifty-sixth H site, H(97) is bonded in a single-bond geometry to one C(88) atom. In the fifty-seventh H site, H(98,99) is bonded in a single-bond geometry to one C(88) atom. In the fifty-eighth H site, H(100,101,102) is bonded in a single-bond geometry to one C(89) atom. In the fifty-ninth H site, H(103) is bonded in a single-bond geometry to one C(93) atom. In the sixtieth H site, H(104) is bonded in a single-bond geometry to one C(97) atom. In the sixty-first H site, H(105) is bonded in a single-bond geometry to one C(98) atom. In the sixty-second H site, H(106) is bonded in a single-bond geometry to one C(98) atom. In the sixty-third H site, H(107) is bonded in a single-bond geometry to one C(98) atom. In the sixty-fourth H site, H(108,109,110) is bonded in a single-bond geometry to one C(100) atom. In the sixty-fifth H site, H(111,113) is bonded in a single-bond geometry to one C(101) atom. In the sixty-sixth H site, H(112) is bonded in a single-bond geometry to one C(101) atom. In the sixty-seventh H site, H(114) is bonded in a single-bond geometry to one C(102) atom. In the sixty-eighth H site, H(121) is bonded in a single-bond geometry to one C(106) atom. In the sixty-ninth H site, H(122) is bonded in a single-bond geometry to one C(107) atom. In the seventieth H site, H(125) is bonded in a single-bond geometry to one C(109) atom. In the seventy-first H site, H(126) is bonded in a single-bond geometry to one C(113) atom. In the seventy-second H site, H(127) is bonded in a single-bond geometry to one C(115) atom. In the seventy-third H site, H(128) is bonded in a single-bond geometry to one C(116) atom. In the seventy-fourth H site, H(129) is bonded in a single-bond geometry to one C(116) atom. In the seventy-fifth H site, H(130) is bonded in a single-bond geometry to one C(116) atom. In the seventy-sixth H site, H(131,132,133,134,136) is bonded in a single-bond geometry to one C(118) atom. In the seventy-seventh H site, H(135) is bonded in a single-bond geometry to one C(119) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(6) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Co(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Co(1) and one C(21) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(3), and one C(30) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one Cd(1) and one C(30) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Cd(4) and one C(31) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Cd(1) and one C(31) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(35) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(51) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Cd(2) and one C(60) atom. In the twelfth O site, O(12) is bonded in a 3-coordinate geometry to one Cd(5), one Cd(6), and one C(60) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Cd(2) and one C(61) atom. In the fourteenth O site, O(14) is bonded in a distorted T-shaped geometry to one Cd(2), one Cd(6), and one C(61) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Co(3) and one C(65) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Co(3) and one C(81) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Cd(3) and one C(91) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(91) atom. In the nineteenth O site, O(19) is bonded in a 3-coordinate geometry to one Cd(3), one Cd(4), and one C(90) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(90) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Co(4) and one C(95) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Co(4) and one C(111) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one C(120) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 150 degrees geometry to one Cd(5) and one C(120) atom. Linkers: 7 CC(C)(C)C1=CC(C([O])=O)=CC2=CN3[C@@H]4CCCC[C@H]4N4C=C5[CH]C(C([O])=O)=CC(C(C)(C)C)=C5O[Co@@]34O[C]21 ,8 CC(C)(C)C1=CC(C([O])=O)=CC2=CN3[C@@H]4CCCC[C@H]4N4C=C5[CH]C(C([O])=O)=CC(C(C)(C)C)=C5O[Co@]34O[C]21 ,1 CC(C)(C)c1cc(C([O])=O)cc(/C=N/[C@@H]2CCCC[C@H]2/N=C/c2cc(C([O])=O)cc(C(C)(C)C)c2[O])c1[O]. Metal clusters: 1 [C]1O[Cd]23O[C]O[Cd]4(O1)O[C]O[Cd]1(O[C]O4)O[C]O[Cd](O[C]O2)(O[C]O3)O[C]O1 ,8 [Cd] ,1 [Co] ,1 [C]1O[Cd]O[C]O[Cd]23O[C]O[Cd]45(O[C]O[Cd](O1)(O[C]O4)O[C]O5)(O[C]O2)O[C]O3. The MOF has largest included sphere 8.09 A, density 1.05 g/cm3, surface area 4281.58 m2/g, accessible volume 0.49 cm3/g