(ZnC16H14(NO)4)2C9H8O4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules and four ZnC16H14(NO)4 clusters. In each ZnC16H14(NO)4 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(4) atom. The Zn(1)-N(1) bond length is 2.05 Å. The Zn(1)-N(2) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(4) bond length is 1.96 Å. There are sixteen inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(10), one C(11), and one H(3) atom. The C(3)-C(10) bond length is 1.39 Å. The C(3)-C(11) bond length is 1.40 Å. The C(3)-H(3) bond length is 0.93 Å. In the second C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(1), and one O(2) atom. The C(4)-C(10) bond length is 1.50 Å. The C(4)-O(1) bond length is 1.27 Å. The C(4)-O(2) bond length is 1.24 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(12) and one H(4) atom. The C(5)-C(12) bond length is 1.41 Å. The C(5)-H(4) bond length is 0.93 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(19) and one H(5) atom. The C(6)-C(19) bond length is 1.38 Å. The C(6)-H(5) bond length is 0.93 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(13), one N(1), and one H(6) atom. The C(7)-C(13) bond length is 1.37 Å. The C(7)-N(1) bond length is 1.35 Å. The C(7)-H(6) bond length is 0.93 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(4), and one O(6) atom. The C(8)-C(12) bond length is 1.50 Å. The C(8)-O(4) bond length is 1.28 Å. The C(8)-O(6) bond length is 1.23 Å. In the seventh C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(4) atom. The C(10)-C(11) bond length is 1.41 Å. In the eighth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(3), and one N(3) atom. The C(11)-N(3) bond length is 1.38 Å. In the ninth C site, C(12) is bonded in a trigonal planar geometry to one C(20), one C(5), and one C(8) atom. The C(12)-C(20) bond length is 1.40 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(13)-H(7) bond length is 0.93 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(8) atom. The C(14)-C(15) bond length is 1.37 Å. The C(14)-H(8) bond length is 0.93 Å. In the twelfth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one N(2), and one H(9) atom. The C(15)-N(2) bond length is 1.35 Å. The C(15)-H(9) bond length is 0.93 Å. In the thirteenth C site, C(16) is bonded in a single-bond geometry to one C(17) and one H(10) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-H(10) bond length is 0.93 Å. In the fourteenth C site, C(17) is bonded in a 3-coordinate geometry to one C(16), one N(2), and one H(11) atom. The C(17)-N(2) bond length is 1.34 Å. The C(17)-H(11) bond length is 0.93 Å. In the fifteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(14) atom. The C(19)-N(1) bond length is 1.35 Å. The C(19)-H(14) bond length is 0.93 Å. In the sixteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(12) and one N(4) atom. The C(20)-N(4) bond length is 1.35 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(19), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(15), and one C(17) atom. In the third N site, N(3) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one H(15), and one H(16) atom. The N(3)-H(15) bond length is 0.86 Å. The N(3)-H(16) bond length is 0.86 Å. In the fourth N site, N(4) is bonded in a trigonal non-coplanar geometry to one C(20), one H(17), and one H(18) atom. The N(4)-H(17) bond length is 0.86 Å. The N(4)-H(18) bond length is 0.86 Å. There are fourteen inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one N(3) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one N(3) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one N(4) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one N(4) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(4) atom. In the third O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(8) atom. Linkers: 4 c1cc(OCC(COc2ccncc2)(COc2ccncc2)COc2ccncc2)ccn1 ,4 Nc1cc(C([O])=O)c(N)cc1C([O])=O ,4 Nc1c(C([O])=O)ccc(C([O])=O)c1N. Metal clusters: 8 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 5.17 A, density 1.36 g/cm3, surface area 4709.22 m2/g, accessible volume 0.27 cm3/g