Co3C56H26(N4O3)4(CH)18 crystallizes in the monoclinic Cc space group. The structure consists of seventy-two 02329_fluka molecules inside a Co3C56H26(N4O3)4 framework. In the Co3C56H26(N4O3)4 framework, there are three inequivalent Co sites. In the first Co site, Co(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(5), one N(6), one O(5), and one O(6) atom. The Co(1)-N(1) bond length is 2.15 Å. The Co(1)-N(2) bond length is 2.15 Å. The Co(1)-N(5) bond length is 2.14 Å. The Co(1)-N(6) bond length is 2.09 Å. The Co(1)-O(5) bond length is 2.15 Å. The Co(1)-O(6) bond length is 2.27 Å. In the second Co site, Co(2) is bonded in a 5-coordinate geometry to one N(7), one N(9), one O(11), one O(12), and one O(3) atom. The Co(2)-N(7) bond length is 2.04 Å. The Co(2)-N(9) bond length is 2.03 Å. The Co(2)-O(11) bond length is 2.08 Å. The Co(2)-O(12) bond length is 2.38 Å. The Co(2)-O(3) bond length is 2.00 Å. In the third Co site, Co(3) is bonded in an octahedral geometry to one N(11), one N(12), one N(13), one N(14), one O(7), and one O(8) atom. The Co(3)-N(11) bond length is 2.14 Å. The Co(3)-N(12) bond length is 2.09 Å. The Co(3)-N(13) bond length is 2.13 Å. The Co(3)-N(14) bond length is 2.16 Å. The Co(3)-O(7) bond length is 2.16 Å. The Co(3)-O(8) bond length is 2.20 Å. There are fifty-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.29 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(9) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(9) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.49 Å. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(5)-O(3) bond length is 1.28 Å. The C(5)-O(4) bond length is 1.25 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4), one C(7), and one H(2) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(2) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. The C(7)-C(8) bond length is 1.50 Å. The C(7)-C(9) bond length is 1.41 Å. In the eighth C site, C(8) is bonded in a bent 120 degrees geometry to one C(7), one O(5), and one O(6) atom. The C(8)-O(5) bond length is 1.25 Å. The C(8)-O(6) bond length is 1.27 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(2), one C(7), and one H(3) atom. The C(9)-H(3) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(15), and one N(1) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(15) bond length is 1.40 Å. The C(10)-N(1) bond length is 1.41 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(4) atom. The C(11)-H(4) bond length is 0.93 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(7,11) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-H(7,11) bond length is 0.93 Å. In the thirteenth C site, C(15) is bonded in a 3-coordinate geometry to one C(10), one C(14), and one N(4) atom. The C(15)-N(4) bond length is 1.36 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17), one C(21), and one N(2) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.40 Å. The C(16)-N(2) bond length is 1.40 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(8) atom. The C(17)-H(8) bond length is 0.93 Å. In the sixteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(7,11) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-H(7,11) bond length is 0.93 Å. In the seventeenth C site, C(21) is bonded in a 3-coordinate geometry to one C(16), one C(20), and one N(3) atom. The C(21)-N(3) bond length is 1.40 Å. In the eighteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(23), one N(1), and one N(4) atom. The C(22)-C(23) bond length is 1.46 Å. The C(22)-N(1) bond length is 1.33 Å. The C(22)-N(4) bond length is 1.35 Å. In the nineteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one N(2), and one N(3) atom. The C(23)-N(2) bond length is 1.32 Å. The C(23)-N(3) bond length is 1.35 Å. In the twentieth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(25), one C(29), and one N(5) atom. The C(24)-C(25) bond length is 1.43 Å. The C(24)-C(29) bond length is 1.38 Å. The C(24)-N(5) bond length is 1.37 Å. In the twenty-first C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(12) atom. The C(25)-H(12) bond length is 0.93 Å. In the twenty-second C site, C(28) is bonded in a distorted single-bond geometry to one C(29) and one H(15) atom. The C(28)-C(29) bond length is 1.42 Å. The C(28)-H(15) bond length is 0.93 Å. In the twenty-third C site, C(29) is bonded in a distorted trigonal planar geometry to one C(24), one C(28), and one N(8) atom. The C(29)-N(8) bond length is 1.36 Å. In the twenty-fourth C site, C(30) is bonded in a distorted single-bond geometry to one C(31), one C(35), and one N(6) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-C(35) bond length is 1.39 Å. The C(30)-N(6) bond length is 1.39 Å. In the twenty-fifth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(16) atom. The C(31)-H(16) bond length is 0.93 Å. In the twenty-sixth C site, C(35) is bonded in a distorted single-bond geometry to one C(30) and one N(7) atom. The C(35)-N(7) bond length is 1.41 Å. In the twenty-seventh C site, C(36) is bonded in a distorted trigonal planar geometry to one C(37), one N(5), and one N(8) atom. The C(36)-C(37) bond length is 1.42 Å. The C(36)-N(5) bond length is 1.33 Å. The C(36)-N(8) bond length is 1.38 Å. In the twenty-eighth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(36), one N(6), and one N(7) atom. The C(37)-N(6) bond length is 1.36 Å. The C(37)-N(7) bond length is 1.37 Å. In the twenty-ninth C site, C(38) is bonded in a distorted single-bond geometry to one C(39), one C(43), and one N(9) atom. The C(38)-C(39) bond length is 1.42 Å. The C(38)-C(43) bond length is 1.40 Å. The C(38)-N(9) bond length is 1.39 Å. In the thirtieth C site, C(39) is bonded in a distorted single-bond geometry to one C(38) and one H(20) atom. The C(39)-H(20) bond length is 0.93 Å. In the thirty-first C site, C(42) is bonded in a distorted single-bond geometry to one C(43) and one H(23) atom. The C(42)-C(43) bond length is 1.43 Å. The C(42)-H(23) bond length is 0.93 Å. In the thirty-second C site, C(43) is bonded in a distorted single-bond geometry to one C(38), one C(42), and one N(12) atom. The C(43)-N(12) bond length is 1.38 Å. In the thirty-third C site, C(44) is bonded in a distorted trigonal planar geometry to one C(45), one C(49), and one N(10) atom. The C(44)-C(45) bond length is 1.38 Å. The C(44)-C(49) bond length is 1.40 Å. The C(44)-N(10) bond length is 1.38 Å. In the thirty-fourth C site, C(45) is bonded in a distorted single-bond geometry to one C(44) and one H(24) atom. The C(45)-H(24) bond length is 0.93 Å. In the thirty-fifth C site, C(48) is bonded in a distorted single-bond geometry to one C(49) and one H(27) atom. The C(48)-C(49) bond length is 1.40 Å. The C(48)-H(27) bond length is 0.93 Å. In the thirty-sixth C site, C(49) is bonded in a distorted trigonal planar geometry to one C(44), one C(48), and one N(11) atom. The C(49)-N(11) bond length is 1.42 Å. In the thirty-seventh C site, C(50) is bonded in a distorted trigonal planar geometry to one C(51), one N(12), and one N(9) atom. The C(50)-C(51) bond length is 1.47 Å. The C(50)-N(12) bond length is 1.36 Å. The C(50)-N(9) bond length is 1.35 Å. In the thirty-eighth C site, C(51) is bonded in a distorted trigonal planar geometry to one C(50), one N(10), and one N(11) atom. The C(51)-N(10) bond length is 1.35 Å. The C(51)-N(11) bond length is 1.30 Å. In the thirty-ninth C site, C(52) is bonded in a distorted single-bond geometry to one C(57) and one N(13) atom. The C(52)-C(57) bond length is 1.41 Å. The C(52)-N(13) bond length is 1.42 Å. In the fortieth C site, C(56) is bonded in a single-bond geometry to one C(57) and one H(31) atom. The C(56)-C(57) bond length is 1.39 Å. The C(56)-H(31) bond length is 0.93 Å. In the forty-first C site, C(57) is bonded in a distorted single-bond geometry to one C(52), one C(56), and one N(16) atom. The C(57)-N(16) bond length is 1.39 Å. In the forty-second C site, C(58) is bonded in a distorted trigonal planar geometry to one C(59), one C(63), and one N(14) atom. The C(58)-C(59) bond length is 1.40 Å. The C(58)-C(63) bond length is 1.39 Å. The C(58)-N(14) bond length is 1.39 Å. In the forty-third C site, C(59) is bonded in a distorted single-bond geometry to one C(58) and one H(32) atom. The C(59)-H(32) bond length is 0.93 Å. In the forty-fourth C site, C(62) is bonded in a distorted single-bond geometry to one C(63) and one H(35) atom. The C(62)-C(63) bond length is 1.40 Å. The C(62)-H(35) bond length is 0.93 Å. In the forty-fifth C site, C(63) is bonded in a distorted trigonal planar geometry to one C(58), one C(62), and one N(15) atom. The C(63)-N(15) bond length is 1.41 Å. In the forty-sixth C site, C(64) is bonded in a distorted bent 120 degrees geometry to one N(13) and one N(16) atom. The C(64)-N(13) bond length is 1.34 Å. The C(64)-N(16) bond length is 1.34 Å. In the forty-seventh C site, C(65) is bonded in a distorted bent 120 degrees geometry to one N(14) and one N(15) atom. The C(65)-N(14) bond length is 1.30 Å. The C(65)-N(15) bond length is 1.35 Å. In the forty-eighth C site, C(66) is bonded in a bent 120 degrees geometry to one C(67), one O(7), and one O(8) atom. The C(66)-C(67) bond length is 1.52 Å. The C(66)-O(7) bond length is 1.25 Å. The C(66)-O(8) bond length is 1.26 Å. In the forty-ninth C site, C(67) is bonded in a trigonal planar geometry to one C(66), one C(68), and one C(74) atom. The C(67)-C(68) bond length is 1.41 Å. The C(67)-C(74) bond length is 1.37 Å. In the fiftieth C site, C(68) is bonded in a distorted single-bond geometry to one C(67), one C(69), and one H(36) atom. The C(68)-C(69) bond length is 1.39 Å. The C(68)-H(36) bond length is 0.93 Å. In the fifty-first C site, C(69) is bonded in a trigonal planar geometry to one C(68), one C(70), and one C(71) atom. The C(69)-C(70) bond length is 1.53 Å. The C(69)-C(71) bond length is 1.41 Å. In the fifty-second C site, C(70) is bonded in a bent 120 degrees geometry to one C(69), one O(11), and one O(12) atom. The C(70)-O(11) bond length is 1.28 Å. The C(70)-O(12) bond length is 1.24 Å. In the fifty-third C site, C(71) is bonded in a distorted single-bond geometry to one C(69), one C(72), and one H(37) atom. The C(71)-C(72) bond length is 1.39 Å. The C(71)-H(37) bond length is 0.93 Å. In the fifty-fourth C site, C(72) is bonded in a trigonal planar geometry to one C(71), one C(73), and one C(74) atom. The C(72)-C(73) bond length is 1.50 Å. The C(72)-C(74) bond length is 1.40 Å. In the fifty-fifth C site, C(73) is bonded in a distorted bent 120 degrees geometry to one C(72), one O(10), and one O(9) atom. The C(73)-O(10) bond length is 1.27 Å. The C(73)-O(9) bond length is 1.26 Å. In the fifty-sixth C site, C(74) is bonded in a distorted single-bond geometry to one C(67), one C(72), and one H(38) atom. The C(74)-H(38) bond length is 0.93 Å. There are sixteen inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Co(1), one C(10), and one C(22) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Co(1), one C(16), and one C(23) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one H(39) atom. The N(3)-H(39) bond length is 0.86 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(15), one C(22), and one H(40) atom. The N(4)-H(40) bond length is 0.86 Å. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Co(1), one C(24), and one C(36) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Co(1), one C(30), and one C(37) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Co(2), one C(35), and one C(37) atom. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one C(29), one C(36), and one H(41) atom. The N(8)-H(41) bond length is 0.86 Å. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Co(2), one C(38), and one C(50) atom. In the tenth N site, N(10) is bonded in a distorted trigonal planar geometry to one C(44), one C(51), and one H(42) atom. The N(10)-H(42) bond length is 0.86 Å. In the eleventh N site, N(11) is bonded in a distorted trigonal planar geometry to one Co(3), one C(49), and one C(51) atom. In the twelfth N site, N(12) is bonded in a distorted trigonal planar geometry to one Co(3), one C(43), and one C(50) atom. In the thirteenth N site, N(13) is bonded in a distorted trigonal planar geometry to one Co(3), one C(52), and one C(64) atom. In the fourteenth N site, N(14) is bonded in a distorted trigonal planar geometry to one Co(3), one C(58), and one C(65) atom. In the fifteenth N site, N(15) is bonded in a distorted trigonal planar geometry to one C(63), one C(65), and one H(43) atom. The N(15)-H(43) bond length is 0.86 Å. In the sixteenth N site, N(16) is bonded in a distorted trigonal planar geometry to one C(57), one C(64), and one H(44) atom. The N(16)-H(44) bond length is 0.86 Å. There are twenty-five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(7,11) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(25) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(28) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(31) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(39) atom. In the eleventh H site, H(23) is bonded in a single-bond geometry to one C(42) atom. In the twelfth H site, H(24) is bonded in a single-bond geometry to one C(45) atom. In the thirteenth H site, H(27) is bonded in a single-bond geometry to one C(48) atom. In the fourteenth H site, H(31) is bonded in a single-bond geometry to one C(56) atom. In the fifteenth H site, H(32) is bonded in a single-bond geometry to one C(59) atom. In the sixteenth H site, H(35) is bonded in a single-bond geometry to one C(62) atom. In the seventeenth H site, H(36) is bonded in a single-bond geometry to one C(68) atom. In the eighteenth H site, H(37) is bonded in a single-bond geometry to one C(71) atom. In the nineteenth H site, H(38) is bonded in a single-bond geometry to one C(74) atom. In the twentieth H site, H(39) is bonded in a single-bond geometry to one N(3) atom. In the twenty-first H site, H(40) is bonded in a single-bond geometry to one N(4) atom. In the twenty-second H site, H(41) is bonded in a single-bond geometry to one N(8) atom. In the twenty-third H site, H(42) is bonded in a single-bond geometry to one N(10) atom. In the twenty-fourth H site, H(43) is bonded in a single-bond geometry to one N(15) atom. In the twenty-fifth H site, H(44) is bonded in a single-bond geometry to one N(16) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Co(2) and one C(5) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Co(1) and one C(8) atom. In the sixth O site, O(6) is bonded in a distorted L-shaped geometry to one Co(1) and one C(8) atom. In the seventh O site, O(7) is bonded in an L-shaped geometry to one Co(3) and one C(66) atom. In the eighth O site, O(12) is bonded in a distorted single-bond geometry to one Co(2) and one C(70) atom. In the ninth O site, O(8) is bonded in an L-shaped geometry to one Co(3) and one C(66) atom. In the tenth O site, O(9) is bonded in a single-bond geometry to one C(73) atom. In the eleventh O site, O(10) is bonded in a single-bond geometry to one C(73) atom. In the twelfth O site, O(11) is bonded in an L-shaped geometry to one Co(2) and one C(70) atom. Linkers: 1 [C]C1=C([CH])NC2=C3Nc4ccccc4N3[Co]34(O[C]O3)(N12)N1C(=C2N([Co@](OC(=O)C([CH])=[CH])(OC(=O)c3cc([C]5O[Co]67(O5)(N5[C](Nc8ccccc85)c5nc8ccccc8n56)N5C(=C6Nc8ccccc8N67)Nc6ccccc65)cc(C([O])=O)c3)N3C5=C6Nc7ccccc7N6[Co]67(O[C](c8cc(C([O])=O)cc(C([O])=O)c8)O6)(N6C(=C8Nc9ccccc9N87)Nc7ccccc76)N5c5ccccc53)c3ccccc3N24)Nc2ccccc21 ,1 [CH]C1=[C]NC2=C3Nc4ccccc4N3[Co]34(O[C](c5cc(C([O])=O)cc(C(=O)O[Co](OC(=O)c6cc([C]7O[Co]89(O7)(N7[C](Nc%10ccccc%107)c7nc%10ccccc%10n78)N7C(=C8Nc%10ccccc%10N89)Nc8ccccc87)cc(C([O])=O)c6)(N6C7=C8Nc9ccccc9N8[Co]89(O[C](c%10cc(C([O])=O)cc(C([O])=O)c%10)O8)(N8C(=C%10Nc%11ccccc%11N%109)Nc9ccccc98)N7c7ccccc76)N6C7=C8Nc9ccccc9N8[Co]89(O[C](c%10cc(C([O])=O)cc(C([O])=O)c%10)O8)(N8C(=C%10Nc%11ccccc%11N%109)Nc9ccccc98)N7c7ccccc76)c5)O3)(N12)N1[C](Nc2ccccc21)c1nc2ccccc2n14 ,1 [O]C(=O)c1cc([C]2O[Co]34(O2)(N2C(=C5Nc6ccccc6N53)Nc3ccccc32)N2C(=C3N([Co](OC(=O)c5cc([C]6O[Co]78(O6)(N6[C](Nc9ccccc96)c6nc9ccccc9n67)N6C(=C7Nc9ccccc9N78)Nc7ccccc76)cc(C([O])=O)c5)(OC(=O)c5cc([C]6O[Co]78(O6)(N6[C](Nc9ccccc96)c6nc9ccccc9n67)N6C(=C7Nc9ccccc9N78)Nc7ccccc76)cc(C([O])=O)c5)N5C6=C7Nc8ccccc8N7[Co]78(O[C](c9cc(C([O])=O)cc(C([O])=O)c9)O7)(N7C(=C9Nc%10ccccc%10N98)Nc8ccccc87)N6c6ccccc65)c5ccccc5N34)Nc3ccccc32)cc(C([O])=O)c1 ,1 [CH]C1=[C]NC2=C3Nc4ccccc4N3[Co]34(O[C](c5cc(C([O])=O)cc(C(=O)O[Co@](OC(=O)c6cc([C]7O[Co]89(O7)(N7[C](Nc%10ccccc%107)c7nc%10ccccc%10n78)N7C(=C8Nc%10ccccc%10N89)Nc8ccccc87)cc(C([O])=O)c6)(N6C7=C8Nc9ccccc9N8[Co]89(O[C](c%10cc(C([O])=O)cc(C([O])=O)c%10)O8)(N8C(=C%10Nc%11ccccc%11N%109)Nc9c[c]ccc98)N7c7ccccc76)N6C7=C8Nc9ccccc9N8[Co]89(O[C](c%10cc(C([O])=O)cc(C([O])=O)c%10)O8)(N8C(=C%10Nc%11ccccc%11N%109)Nc9ccccc98)N7c7ccccc76)c5)O3)(N12)N1[C](Nc2ccccc21)c1nc2ccccc2n14 ,1 [CH]C1=[C]NC2=C3Nc4ccccc4N3[Co]34(O[C](c5cc(C([O])=O)cc(C([O])=O)c5)O3)(N12)N1C(=C2N([Co@@](OC(=O)C(=[CH])/C=[C]/C([O])=O)(OC(=O)c3cc([C]5O[Co]67(O5)(N5[C](Nc8ccccc85)c5nc8ccccc8n56)N5C(=C6Nc8ccccc8N67)Nc6ccccc65)cc(C([O])=O)c3)N3C5=C6Nc7ccccc7N6[Co]67(O[C]([C]=[CH])O6)(N6C(=C8Nc9ccccc9N87)Nc7ccccc76)N5c5c[c]ccc53)c3ccccc3N24)Nc2ccccc21 ,1 [O]C(=O)c1cc([C]2O[Co]34(O2)(N2C(=C5Nc6ccccc6N53)Nc3c[c]ccc32)N2C(=C3N([Co](OC(=O)c5cc([C]6O[Co]78(O6)(N6[C](Nc9ccccc96)c6nc9ccccc9n67)N6C(=C7Nc9ccccc9N78)Nc7ccccc76)cc(C([O])=O)c5)(OC(=O)c5cc([C]6O[Co]78(O6)(N6[C](Nc9ccccc96)c6nc9ccccc9n67)N6C(=C7Nc9ccccc9N78)Nc7ccccc76)cc(C([O])=O)c5)N5C6=C7Nc8ccccc8N7[Co]78(O[C](c9cc(C([O])=O)cc(C([O])=O)c9)O7)(N7C(=C9Nc%10ccccc%10N98)Nc8ccccc87)N6c6ccccc65)c5ccccc5N34)Nc3ccccc32)cc(C([O])=O)c1. Metal clusters: 1 O=[C]O[Co]O[C]=O. The MOF has largest included sphere 5.01 A, density 1.13 g/cm3, surface area 4726.35 m2/g, accessible volume 0.41 cm3/g