Cu(OOCC6H4COO)C17H7O2 is Indium-derived structured and crystallizes in the tetragonal I4/mmm space group. The structure is zero-dimensional and consists of sixteen C17H7O2 clusters and eight Cu(OOCC6H4COO) clusters. In each C17H7O2 cluster, there are ten inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-H(2) bond length is 0.93 Å. In the second C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.38 Å. The C(5)-C(8) bond length is 1.48 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the fourth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(5), and one C(9) atom. The C(8)-C(12) bond length is 1.39 Å. The C(8)-C(9) bond length is 1.39 Å. In the fifth C site, C(9) is bonded in a single-bond geometry to one C(13), one C(8), and one H(5) atom. The C(9)-C(13) bond length is 1.41 Å. The C(9)-H(5) bond length is 0.93 Å. In the sixth C site, C(10) is bonded in a distorted single-bond geometry to one C(14) and one O(3) atom. The C(10)-C(14) bond length is 1.39 Å. The C(10)-O(3) bond length is 1.38 Å. In the seventh C site, C(11) is bonded in a single-bond geometry to one O(3) atom. The C(11)-O(3) bond length is 1.45 Å. In the eighth C site, C(12) is bonded in a single-bond geometry to two equivalent C(8) and one H(6) atom. The C(12)-H(6) bond length is 0.93 Å. In the ninth C site, C(13) is bonded in a trigonal planar geometry to one C(14) and two equivalent C(9) atoms. The C(13)-C(14) bond length is 1.48 Å. In the tenth C site, C(14) is bonded in a trigonal planar geometry to one C(13) and two equivalent C(10) atoms. There are four inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. O(3) is bonded in a distorted bent 120 degrees geometry to one C(10) and one C(11) atom. In each Cu(OOCC6H4COO) cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square co-planar geometry to four equivalent O(2) atoms. All Cu(1)-O(2) bond lengths are 1.95 Å. In the second Cu site, Cu(2) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. All Cu(2)-O(1) bond lengths are 1.95 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(1) atom. Linkers: 8 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3c4o[c][c]oc4c(-c4cc(-c5ccc(C([O])=O)cc5)cc(-c5ccc(C([O])=O)cc5)c4)c4o[c][c]oc34)c2)cc1. Metal clusters: 8 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: ssb. The MOF has largest included sphere 23.86 A, density 0.29 g/cm3, surface area 4435.65 m2/g, accessible volume 2.92 cm3/g