Zn3H2(C3O5)2(CH)2 is Indium-derived structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules and four Zn3H2(C3O5)2 clusters. In each Zn3H2(C3O5)2 cluster, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(10), one O(2), one O(5), one O(6), and one O(9) atom to form distorted corner-sharing ZnO6 octahedra. The Zn(1)-O(1) bond length is 2.17 Å. The Zn(1)-O(10) bond length is 2.01 Å. The Zn(1)-O(2) bond length is 2.19 Å. The Zn(1)-O(5) bond length is 1.99 Å. The Zn(1)-O(6) bond length is 1.95 Å. The Zn(1)-O(9) bond length is 2.18 Å. In the second Zn site, Zn(2) is bonded to one O(10), one O(3), one O(4), one O(7), and one O(8) atom to form distorted corner-sharing ZnO5 trigonal bipyramids. The corner-sharing octahedral tilt angles are 76°. The Zn(2)-O(10) bond length is 1.95 Å. The Zn(2)-O(3) bond length is 2.14 Å. The Zn(2)-O(4) bond length is 2.03 Å. The Zn(2)-O(7) bond length is 2.20 Å. The Zn(2)-O(8) bond length is 2.04 Å. In the third Zn site, Zn(3) is bonded in a rectangular see-saw-like geometry to one O(2), one O(9), and two equivalent O(10) atoms. The Zn(3)-O(2) bond length is 2.08 Å. The Zn(3)-O(9) bond length is 2.20 Å. There is one shorter (1.90 Å) and one longer (1.91 Å) Zn(3)-O(10) bond length. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one H(1) and one O(1) atom. The C(1)-H(1) bond length is 0.98 Å. The C(1)-O(1) bond length is 1.47 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(2)-O(2) bond length is 1.23 Å. The C(2)-O(3) bond length is 1.23 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(4)-O(4) bond length is 1.32 Å. The C(4)-O(5) bond length is 1.19 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(6)-O(6) bond length is 1.25 Å. The C(6)-O(7) bond length is 1.26 Å. In the fifth C site, C(7) is bonded in a distorted water-like geometry to one H(4) and one O(1) atom. The C(7)-H(4) bond length is 0.98 Å. The C(7)-O(1) bond length is 1.45 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(8) and one O(9) atom. The C(8)-O(8) bond length is 1.27 Å. The C(8)-O(9) bond length is 1.24 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one C(1), and one C(7) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Zn(1), one Zn(3), and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(4) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(6) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(8) atom. In the ninth O site, O(9) is bonded in a 3-coordinate geometry to one Zn(1), one Zn(3), and one C(8) atom. In the tenth O site, O(10) is bonded to one Zn(1), one Zn(2), and two equivalent Zn(3) atoms to form corner-sharing OZn4 tetrahedra. Linkers: 24 [O]C(=O)[C@@H]1[C@H](C([O])=O)[C@@H](C([O])=O)O[C@H]1C([O])=O. Metal clusters: 72 [Zn]. The MOF has largest included sphere 6.41 A, density 2.12 g/cm3, surface area 2278.22 m2/g, accessible volume 0.25 cm3/g