Zn29C360H342(N9O40)2 crystallizes in the hexagonal P6_322 space group. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(2), one O(1), one O(12), one O(5), and one O(7) atom to form distorted ZnNO4 trigonal bipyramids that share  an edgeedge with one Zn(5)O6 octahedra,  an edgeedge with one Zn(2)NO4 trigonal bipyramid, and  an edgeedge with one Zn(3)NO4 trigonal bipyramid. The Zn(1)-N(2) bond length is 1.96 Å. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(12) bond length is 1.92 Å. The Zn(1)-O(5) bond length is 2.24 Å. The Zn(1)-O(7) bond length is 2.04 Å. In the second Zn site, Zn(2) is bonded to one N(3), one O(13), one O(5), one O(7), and one O(9) atom to form distorted ZnNO4 trigonal bipyramids that share  an edgeedge with one Zn(5)O6 octahedra,  an edgeedge with one Zn(1)NO4 trigonal bipyramid, and  an edgeedge with one Zn(3)NO4 trigonal bipyramid. The Zn(2)-N(3) bond length is 1.96 Å. The Zn(2)-O(13) bond length is 1.95 Å. The Zn(2)-O(5) bond length is 2.04 Å. The Zn(2)-O(7) bond length is 2.01 Å. The Zn(2)-O(9) bond length is 2.31 Å. In the third Zn site, Zn(3) is bonded to one N(1), one O(1), one O(4), one O(7), and one O(9) atom to form distorted ZnNO4 trigonal bipyramids that share  an edgeedge with one Zn(5)O6 octahedra,  an edgeedge with one Zn(1)NO4 trigonal bipyramid, and  an edgeedge with one Zn(2)NO4 trigonal bipyramid. The Zn(3)-N(1) bond length is 1.97 Å. The Zn(3)-O(1) bond length is 2.25 Å. The Zn(3)-O(4) bond length is 1.94 Å. The Zn(3)-O(7) bond length is 2.06 Å. The Zn(3)-O(9) bond length is 2.01 Å. In the fourth Zn site, Zn(4) is bonded in a distorted see-saw-like geometry to one O(10), one O(14), one O(2), and one O(8) atom. The Zn(4)-O(10) bond length is 1.94 Å. The Zn(4)-O(14) bond length is 1.95 Å. The Zn(4)-O(2) bond length is 2.13 Å. The Zn(4)-O(8) bond length is 2.15 Å. In the fifth Zn site, Zn(5) is bonded to two equivalent O(1), two equivalent O(5), and two equivalent O(9) atoms to form edge-sharing ZnO6 octahedra. Both Zn(5)-O(1) bond lengths are 2.08 Å. Both Zn(5)-O(5) bond lengths are 2.08 Å. Both Zn(5)-O(9) bond lengths are 2.07 Å. In the sixth Zn site, Zn(6) is bonded in a tetrahedral geometry to one O(14) and three equivalent O(11) atoms. The Zn(6)-O(14) bond length is 1.91 Å. All Zn(6)-O(11) bond lengths are 1.92 Å. There are sixty inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(12), one C(33), and one C(35) atom. The C(1)-C(12) bond length is 1.39 Å. The C(1)-C(33) bond length is 1.39 Å. The C(1)-C(35) bond length is 1.55 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(11), and one O(2) atom. The C(2)-C(19) bond length is 1.48 Å. The C(2)-O(11) bond length is 1.19 Å. The C(2)-O(2) bond length is 1.26 Å. In the third C site, C(3) is bonded in a tetrahedral geometry to one C(18), one C(37), one C(48), and one C(59) atom. The C(3)-C(18) bond length is 1.36 Å. The C(3)-C(37) bond length is 1.55 Å. The C(3)-C(48) bond length is 1.26 Å. The C(3)-C(59) bond length is 1.58 Å. In the fourth C site, C(4) is bonded in a trigonal non-coplanar geometry to one C(14); one H(34); and two equivalent H(25,26,37) atoms. The C(4)-C(14) bond length is 1.53 Å. The C(4)-H(34) bond length is 0.96 Å. Both C(4)-H(25,26,37) bond lengths are 0.96 Å. In the fifth C site, C(5) is bonded in a trigonal non-coplanar geometry to one C(14), one H(12), one H(29), and one H(40) atom. The C(5)-C(14) bond length is 1.54 Å. The C(5)-H(12) bond length is 0.96 Å. The C(5)-H(29) bond length is 0.96 Å. The C(5)-H(40) bond length is 0.96 Å. In the sixth C site, C(6) is bonded in a trigonal non-coplanar geometry to one C(28), one H(41), one H(44), and one H(57) atom. The C(6)-C(28) bond length is 1.53 Å. The C(6)-H(41) bond length is 0.96 Å. The C(6)-H(44) bond length is 0.96 Å. The C(6)-H(57) bond length is 0.96 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(16), one C(60), and one C(8) atom. The C(7)-C(16) bond length is 1.52 Å. The C(7)-C(60) bond length is 1.39 Å. The C(7)-C(8) bond length is 1.39 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(25), one C(7), and one O(13) atom. The C(8)-C(25) bond length is 1.39 Å. The C(8)-O(13) bond length is 1.27 Å. In the ninth C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(12), one H(17), one H(27), and one H(32) atom. The C(9)-C(12) bond length is 1.56 Å. The C(9)-H(17) bond length is 0.96 Å. The C(9)-H(27) bond length is 0.96 Å. The C(9)-H(32) bond length is 0.96 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(34), one C(44), and one C(46) atom. The C(10)-C(34) bond length is 1.39 Å. The C(10)-C(44) bond length is 1.39 Å. The C(10)-C(46) bond length is 1.58 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(25), one C(57), and one H(51) atom. The C(11)-C(25) bond length is 1.39 Å. The C(11)-C(57) bond length is 1.39 Å. The C(11)-H(51) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(1), one C(54), and one C(9) atom. The C(12)-C(54) bond length is 1.39 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(39), one C(41), and one C(50) atom. The C(13)-C(39) bond length is 1.39 Å. The C(13)-C(41) bond length is 1.39 Å. The C(13)-C(50) bond length is 1.46 Å. In the fourteenth C site, C(14) is bonded in a tetrahedral geometry to one C(24), one C(27), one C(4), and one C(5) atom. The C(14)-C(24) bond length is 1.54 Å. The C(14)-C(27) bond length is 1.61 Å. In the fifteenth C site, C(15) is bonded in a trigonal non-coplanar geometry to one C(16); one H(45); and two equivalent H(36,42) atoms. The C(15)-C(16) bond length is 1.54 Å. The C(15)-H(45) bond length is 0.96 Å. Both C(15)-H(36,42) bond lengths are 0.96 Å. In the sixteenth C site, C(16) is bonded in a tetrahedral geometry to one C(15), one C(21), one C(23), and one C(7) atom. The C(16)-C(21) bond length is 1.56 Å. The C(16)-C(23) bond length is 1.50 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(26), one C(49), and one O(5) atom. The C(17)-C(26) bond length is 1.39 Å. The C(17)-C(49) bond length is 1.39 Å. The C(17)-O(5) bond length is 1.35 Å. In the eighteenth C site, C(18) is bonded in a trigonal non-coplanar geometry to one C(3), one H(18), one H(24), and one H(49) atom. The C(18)-H(18) bond length is 0.96 Å. The C(18)-H(24) bond length is 0.96 Å. The C(18)-H(49) bond length is 0.96 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(2), one C(41), and one C(56) atom. The C(19)-C(41) bond length is 1.39 Å. The C(19)-C(56) bond length is 1.39 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(30), one C(44), and one H(15) atom. The C(20)-C(30) bond length is 1.39 Å. The C(20)-C(44) bond length is 1.39 Å. The C(20)-H(15) bond length is 0.93 Å. In the twenty-first C site, C(21) is bonded in a trigonal non-coplanar geometry to one C(16); one H(11,21); one H(2,31); and one H(38) atom. The C(21)-H(11,21) bond length is 0.96 Å. The C(21)-H(2,31) bond length is 0.96 Å. The C(21)-H(38) bond length is 0.96 Å. In the twenty-second C site, C(22) is bonded in a trigonal non-coplanar geometry to one C(47) and three equivalent H(8,22,48) atoms. The C(22)-C(47) bond length is 1.52 Å. All C(22)-H(8,22,48) bond lengths are 0.96 Å. In the twenty-third C site, C(23) is bonded in a trigonal non-coplanar geometry to one C(16); one H(11,21); one H(2,31); and one H(39) atom. The C(23)-H(11,21) bond length is 0.96 Å. The C(23)-H(2,31) bond length is 0.96 Å. The C(23)-H(39) bond length is 0.96 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal non-coplanar geometry to one C(14); one H(25,26,37); one H(46); and one H(52) atom. The C(24)-H(25,26,37) bond length is 0.96 Å. The C(24)-H(46) bond length is 0.96 Å. The C(24)-H(52) bond length is 0.96 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(11), one C(53), and one C(8) atom. The C(25)-C(53) bond length is 1.46 Å. In the twenty-sixth C site, C(26) is bonded in a trigonal planar geometry to one C(17), one C(28), and one C(34) atom. The C(26)-C(28) bond length is 1.39 Å. The C(26)-C(34) bond length is 1.54 Å. In the twenty-seventh C site, C(27) is bonded in a trigonal planar geometry to one C(14), one C(45), and one C(58) atom. The C(27)-C(45) bond length is 1.39 Å. The C(27)-C(58) bond length is 1.39 Å. In the twenty-eighth C site, C(28) is bonded in a trigonal planar geometry to one C(26), one C(47), and one C(6) atom. The C(28)-C(47) bond length is 1.39 Å. In the twenty-ninth C site, C(29) is bonded in a 2-coordinate geometry to one C(31), one N(1), and one H(20) atom. The C(29)-C(31) bond length is 1.39 Å. The C(29)-N(1) bond length is 1.25 Å. The C(29)-H(20) bond length is 0.93 Å. In the thirtieth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(20), one C(43), and one N(1) atom. The C(30)-C(43) bond length is 1.39 Å. The C(30)-N(1) bond length is 1.46 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one C(29), one C(38), and one C(58) atom. The C(31)-C(38) bond length is 1.39 Å. The C(31)-C(58) bond length is 1.39 Å. In the thirty-second C site, C(32) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(45) atom. The C(32)-C(38) bond length is 1.39 Å. The C(32)-C(40) bond length is 1.58 Å. The C(32)-C(45) bond length is 1.39 Å. In the thirty-third C site, C(33) is bonded in a trigonal planar geometry to one C(1), one C(33), and one C(42) atom. The C(33)-C(33) bond length is 1.55 Å. The C(33)-C(42) bond length is 1.39 Å. In the thirty-fourth C site, C(34) is bonded in a trigonal planar geometry to one C(10), one C(26), and one C(43) atom. The C(34)-C(43) bond length is 1.39 Å. In the thirty-fifth C site, C(35) is bonded in a trigonal non-coplanar geometry to one C(1); one H(16); and two equivalent H(19,35) atoms. The C(35)-H(16) bond length is 0.96 Å. Both C(35)-H(19,35) bond lengths are 0.96 Å. In the thirty-sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(47), one C(49), and one H(28) atom. The C(36)-C(47) bond length is 1.39 Å. The C(36)-C(49) bond length is 1.39 Å. The C(36)-H(28) bond length is 0.93 Å. In the thirty-seventh C site, C(37) is bonded in a trigonal non-coplanar geometry to one C(3); one H(53); and two equivalent H(54,56) atoms. The C(37)-H(53) bond length is 0.96 Å. Both C(37)-H(54,56) bond lengths are 0.96 Å. In the thirty-eighth C site, C(38) is bonded in a distorted single-bond geometry to one C(31), one C(32), and one H(13) atom. The C(38)-H(13) bond length is 0.93 Å. In the thirty-ninth C site, C(39) is bonded in a distorted single-bond geometry to one C(13), one C(59), and one O(12) atom. The C(39)-C(59) bond length is 1.39 Å. The C(39)-O(12) bond length is 1.29 Å. In the fortieth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(10), and one O(8) atom. The C(40)-O(10) bond length is 1.15 Å. The C(40)-O(8) bond length is 1.21 Å. In the forty-first C site, C(41) is bonded in a distorted single-bond geometry to one C(13), one C(19), and one H(23) atom. The C(41)-H(23) bond length is 0.93 Å. In the forty-second C site, C(42) is bonded in a distorted single-bond geometry to one C(33), one C(52), and one O(9) atom. The C(42)-C(52) bond length is 1.39 Å. The C(42)-O(9) bond length is 1.36 Å. In the forty-third C site, C(43) is bonded in a distorted single-bond geometry to one C(30), one C(34), and one O(1) atom. The C(43)-O(1) bond length is 1.37 Å. In the forty-fourth C site, C(44) is bonded in a trigonal planar geometry to one C(10), one C(20), and one C(55) atom. The C(44)-C(55) bond length is 1.57 Å. In the forty-fifth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(27), one C(32), and one H(47) atom. The C(45)-H(47) bond length is 0.93 Å. In the forty-sixth C site, C(46) is bonded in a trigonal non-coplanar geometry to one C(10), one H(10), one H(33), and one H(50) atom. The C(46)-H(10) bond length is 0.96 Å. The C(46)-H(33) bond length is 0.96 Å. The C(46)-H(50) bond length is 0.96 Å. In the forty-seventh C site, C(47) is bonded in a trigonal planar geometry to one C(22), one C(28), and one C(36) atom. In the forty-eighth C site, C(48) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one H(14), one H(4), and one H(9) atom. The C(48)-H(14) bond length is 0.96 Å. The C(48)-H(4) bond length is 0.96 Å. The C(48)-H(9) bond length is 0.96 Å. In the forty-ninth C site, C(49) is bonded in a distorted trigonal planar geometry to one C(17), one C(36), and one N(2) atom. The C(49)-N(2) bond length is 1.47 Å. In the fiftieth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(2), and one H(5) atom. The C(50)-N(2) bond length is 1.26 Å. The C(50)-H(5) bond length is 0.93 Å. In the fifty-first C site, C(51) is bonded in a distorted trigonal planar geometry to one C(57), one O(3), and one O(6) atom. The C(51)-C(57) bond length is 1.49 Å. The C(51)-O(3) bond length is 1.24 Å. The C(51)-O(6) bond length is 1.26 Å. In the fifty-second C site, C(52) is bonded in a distorted trigonal planar geometry to one C(42), one C(54), and one N(3) atom. The C(52)-C(54) bond length is 1.39 Å. The C(52)-N(3) bond length is 1.43 Å. In the fifty-third C site, C(53) is bonded in a distorted bent 120 degrees geometry to one C(25), one N(3), and one H(6) atom. The C(53)-N(3) bond length is 1.33 Å. The C(53)-H(6) bond length is 0.93 Å. In the fifty-fourth C site, C(54) is bonded in a distorted single-bond geometry to one C(12), one C(52), and one H(7) atom. The C(54)-H(7) bond length is 0.93 Å. In the fifty-fifth C site, C(55) is bonded in a trigonal non-coplanar geometry to one C(44); one H(3); and two equivalent H(1,55) atoms. The C(55)-H(3) bond length is 0.96 Å. Both C(55)-H(1,55) bond lengths are 0.96 Å. In the fifty-sixth C site, C(56) is bonded in a distorted single-bond geometry to one C(19), one C(59), and one H(43) atom. The C(56)-C(59) bond length is 1.39 Å. The C(56)-H(43) bond length is 0.93 Å. In the fifty-seventh C site, C(57) is bonded in a trigonal planar geometry to one C(11), one C(51), and one C(60) atom. The C(57)-C(60) bond length is 1.39 Å. In the fifty-eighth C site, C(58) is bonded in a distorted single-bond geometry to one C(27), one C(31), and one O(4) atom. The C(58)-O(4) bond length is 1.33 Å. In the fifty-ninth C site, C(59) is bonded in a trigonal planar geometry to one C(3), one C(39), and one C(56) atom. In the sixtieth C site, C(60) is bonded in a distorted single-bond geometry to one C(57), one C(7), and one H(30) atom. The C(60)-H(30) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(3), one C(29), and one C(30) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(49), and one C(50) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(52), and one C(53) atom. There are forty-seven inequivalent H sites. In the first H site, H(1,55) is bonded in a single-bond geometry to one C(55) atom. In the second H site, H(2,31) is bonded in a single-bond geometry to one C(21) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(55) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(48) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(50) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(53) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(54) atom. In the eighth H site, H(8,22,48) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(48) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(46) atom. In the eleventh H site, H(11,21) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(5) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(38) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(48) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(35) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(9) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the nineteenth H site, H(19,35) is bonded in a single-bond geometry to one C(35) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(29) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(41) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(18) atom. In the twenty-third H site, H(25,26,37) is bonded in a single-bond geometry to one C(24) atom. In the twenty-fourth H site, H(27) is bonded in a single-bond geometry to one C(9) atom. In the twenty-fifth H site, H(28) is bonded in a single-bond geometry to one C(36) atom. In the twenty-sixth H site, H(29) is bonded in a single-bond geometry to one C(5) atom. In the twenty-seventh H site, H(30) is bonded in a single-bond geometry to one C(60) atom. In the twenty-eighth H site, H(32) is bonded in a single-bond geometry to one C(9) atom. In the twenty-ninth H site, H(33) is bonded in a single-bond geometry to one C(46) atom. In the thirtieth H site, H(34) is bonded in a single-bond geometry to one C(4) atom. In the thirty-first H site, H(36,42) is bonded in a single-bond geometry to one C(15) atom. In the thirty-second H site, H(38) is bonded in a single-bond geometry to one C(21) atom. In the thirty-third H site, H(39) is bonded in a single-bond geometry to one C(23) atom. In the thirty-fourth H site, H(40) is bonded in a single-bond geometry to one C(5) atom. In the thirty-fifth H site, H(41) is bonded in a single-bond geometry to one C(6) atom. In the thirty-sixth H site, H(43) is bonded in a single-bond geometry to one C(56) atom. In the thirty-seventh H site, H(44) is bonded in a single-bond geometry to one C(6) atom. In the thirty-eighth H site, H(45) is bonded in a single-bond geometry to one C(15) atom. In the thirty-ninth H site, H(46) is bonded in a single-bond geometry to one C(24) atom. In the fortieth H site, H(47) is bonded in a single-bond geometry to one C(45) atom. In the forty-first H site, H(49) is bonded in a single-bond geometry to one C(18) atom. In the forty-second H site, H(50) is bonded in a single-bond geometry to one C(46) atom. In the forty-third H site, H(51) is bonded in a single-bond geometry to one C(11) atom. In the forty-fourth H site, H(52) is bonded in a single-bond geometry to one C(24) atom. In the forty-fifth H site, H(53) is bonded in a single-bond geometry to one C(37) atom. In the forty-sixth H site, H(54,56) is bonded in a single-bond geometry to one C(37) atom. In the forty-seventh H site, H(57) is bonded in a single-bond geometry to one C(6) atom. There are fourteen inequivalent O sites. In the first O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(8) atom. In the second O site, O(14) is bonded in a tetrahedral geometry to one Zn(6) and three equivalent Zn(4) atoms. In the third O site, O(1) is bonded to one Zn(1), one Zn(3), one Zn(5), and one C(43) atom to form a mixture of distorted edge and corner-sharing OZn3C trigonal pyramids. In the fourth O site, O(2) is bonded in a distorted single-bond geometry to one Zn(4) and one C(2) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one C(51) atom. In the sixth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(58) atom. In the seventh O site, O(5) is bonded to one Zn(1), one Zn(2), one Zn(5), and one C(17) atom to form a mixture of distorted edge and corner-sharing OZn3C trigonal pyramids. In the eighth O site, O(6) is bonded in a single-bond geometry to one C(51) atom. In the ninth O site, O(7) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(2), and one Zn(3) atom. In the tenth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(40) atom. In the eleventh O site, O(9) is bonded in a 4-coordinate geometry to one Zn(2), one Zn(3), one Zn(5), and one C(42) atom. In the twelfth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(40) atom. In the thirteenth O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(2) atom. In the fourteenth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(39) atom. Linkers: 12 Cc1cc(/N=C/c2cc(C([O])=O)cc(C(C)(C)C)c2[O])c([O])c(-c2c(C)c(C)cc(/N=C/c3cc(C([O])=O)cc(C(C)(C)C)c3[O])c2[O])c1C ,1 Cc1cc(/N=C/C2=C[C](C([O])=O)C=C(C(C)(C)C)C2=O)c([O])c(-c2c(C)c(C)cc(/N=C/C3=C[C](C([O])=O)C=C(C(C)(C)C)C3=O)c2[O])c1C ,2 Cc1cc(/N=C/C2=CC(C([O])=O)=C[C](C(C)(C)C)C2=O)c([O])c(-c2c(C)c(C)cc(/N=C/C3=C[C](C([O])=O)C=C(C(C)(C)C)C3=O)c2[O])c1C ,2 Cc1cc(/N=C/[C]2C=C(C([O])=O)C=C(C(C)(C)C)C2=O)c([O])c(-c2c(C)c(C)cc(/N=C/C3=C[C](C([O])=O)C=C(C(C)(C)C)C3=O)c2[O])c1C ,1 Cc1cc(/N=C/[C]2C=C(C([O])=O)C=C(C(C)(C)C)C2=O)c([O])c(-c2c(C)c(C)cc(/N=C/C3=CC(C([O])=O)=C[C](C(C)(C)C)C3=O)c2[O])c1C. Metal clusters: 42 [Zn] ,4 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. The MOF has largest included sphere 17.47 A, density 0.79 g/cm3, surface area 4145.68 m2/g, accessible volume 0.88 cm3/g