CuC24N6H23SO7 crystallizes in the triclinic P-1 space group. Cu(1) is bonded in a trigonal bipyramidal geometry to one N(3), one N(6), one O(1), one O(2), and one O(3) atom. The Cu(1)-N(3) bond length is 1.98 Å. The Cu(1)-N(6) bond length is 1.99 Å. The Cu(1)-O(1) bond length is 1.94 Å. The Cu(1)-O(2) bond length is 2.24 Å. The Cu(1)-O(3) bond length is 1.98 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(3) bond length is 1.41 Å. The C(1)-C(4) bond length is 1.52 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(5) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(5) bond length is 1.52 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(6) atom. The C(3)-C(6) bond length is 1.52 Å. In the fourth C site, C(4) is bonded in a 3-coordinate geometry to one C(1), one N(1), one H(1), and one H(2) atom. The C(4)-N(1) bond length is 1.46 Å. The C(4)-H(1) bond length is 0.98 Å. The C(4)-H(2) bond length is 0.98 Å. In the fifth C site, C(5) is bonded in a trigonal non-coplanar geometry to one C(2); one H(4); and two equivalent H(3,5) atoms. The C(5)-H(4) bond length is 0.97 Å. Both C(5)-H(3,5) bond lengths are 0.97 Å. In the sixth C site, C(6) is bonded in a trigonal non-coplanar geometry to one C(3); one H(7); and two equivalent H(6,8) atoms. The C(6)-H(7) bond length is 0.97 Å. Both C(6)-H(6,8) bond lengths are 0.97 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(9) atom. The C(7)-N(2) bond length is 1.31 Å. The C(7)-N(3) bond length is 1.36 Å. The C(7)-H(9) bond length is 0.94 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(10) atom. The C(8)-N(1) bond length is 1.32 Å. The C(8)-N(3) bond length is 1.32 Å. The C(8)-H(10) bond length is 0.94 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(12) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(11) bond length is 1.41 Å. The C(9)-C(12) bond length is 1.52 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(13) bond length is 1.51 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(9) atom. The C(11)-C(14) bond length is 1.51 Å. In the twelfth C site, C(12) is bonded in a 3-coordinate geometry to one C(9); one N(4); and two equivalent H(11,12) atoms. The C(12)-N(4) bond length is 1.48 Å. Both C(12)-H(11,12) bond lengths are 0.98 Å. In the thirteenth C site, C(13) is bonded in a trigonal non-coplanar geometry to one C(10) and three equivalent H(13,14,15) atoms. All C(13)-H(13,14,15) bond lengths are 0.97 Å. In the fourteenth C site, C(14) is bonded in a trigonal non-coplanar geometry to one C(11) and three equivalent H(16,17,18) atoms. All C(14)-H(16,17,18) bond lengths are 0.97 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(19) atom. The C(15)-N(5) bond length is 1.31 Å. The C(15)-N(6) bond length is 1.35 Å. The C(15)-H(19) bond length is 0.94 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(20) atom. The C(16)-N(4) bond length is 1.32 Å. The C(16)-N(6) bond length is 1.32 Å. The C(16)-H(20) bond length is 0.94 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(18), one C(22), and one C(23) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-C(22) bond length is 1.39 Å. The C(17)-C(23) bond length is 1.51 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(21) atom. The C(18)-C(19) bond length is 1.38 Å. The C(18)-H(21) bond length is 0.94 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-C(24) bond length is 1.51 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(22) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(22) bond length is 0.94 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one S(1) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-S(1) bond length is 1.77 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(17), one C(21), and one H(23) atom. The C(22)-H(23) bond length is 0.94 Å. In the twenty-third C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(1), and one O(2) atom. The C(23)-O(1) bond length is 1.27 Å. The C(23)-O(2) bond length is 1.23 Å. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(3), and one O(4) atom. The C(24)-O(3) bond length is 1.26 Å. The C(24)-O(4) bond length is 1.25 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(4), one C(8), and one N(2) atom. The N(1)-N(2) bond length is 1.36 Å. In the second N site, N(2) is bonded in a water-like geometry to one C(7) and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(7), and one C(8) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(12), one C(16), and one N(5) atom. The N(4)-N(5) bond length is 1.36 Å. In the fifth N site, N(5) is bonded in a water-like geometry to one C(15) and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(15), and one C(16) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3,5) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(6,8) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(11,12) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(13,14,15) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(16,17,18) is bonded in a single-bond geometry to one C(14) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(20) atom. In the sixteenth H site, H(23) is bonded in a single-bond geometry to one C(22) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(21), one O(5), one O(6), and one O(7) atom. The S(1)-O(5) bond length is 1.45 Å. The S(1)-O(6) bond length is 1.44 Å. The S(1)-O(7) bond length is 1.47 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(23) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one C(23) atom. In the third O site, O(3) is bonded in a water-like geometry to one Cu(1) and one C(24) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(24) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one S(1) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one S(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one S(1) atom. Linkers: 1 Cc1c(C)c(Cn2cncn2)c(C)c(C)c1Cn1cncn1 ,2 [O]C(=O)c1cc(C([O])=O)cc(S([O])([O])[O])c1 ,1 Cc1c(C)c(Cn2cncn2)c(C)c(C)c1CN1[CH]N=C[N]1. Metal clusters: 1 O=[C]O[Cu]1O[C]O[Cu](O[C]=O)O[C]O1. The MOF has largest included sphere 5.31 A, density 1.04 g/cm3, surface area 4787.55 m2/g, accessible volume 0.47 cm3/g