CdH8(C2N)4(C7H4F2)4 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight C7H4F2 clusters and two CdH8(C2N)4 clusters. In four of the C7H4F2 clusters, there are seven inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(3)-C(5) bond length is 1.39 Å. The C(3)-H(3) bond length is 0.92 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(4) bond length is 0.93 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.52 Å. In the fourth C site, C(6) is bonded in a bent 120 degrees geometry to one C(5), one C(7), one H(5), and one H(6) atom. The C(6)-C(7) bond length is 1.50 Å. The C(6)-H(5) bond length is 0.95 Å. The C(6)-H(6) bond length is 0.92 Å. In the fifth C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-C(9) bond length is 1.39 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one F(1,2) atom. The C(8)-F(1,2) bond length is 1.35 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(7) and one F(1,2) atom. The C(9)-F(1,2) bond length is 1.35 Å. There are four inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. F(1,2) is bonded in a single-bond geometry to one C(8) atom. In four of the C7H4F2 clusters, there are seven inequivalent C sites. In the first C site, C(21) is bonded in a distorted single-bond geometry to one C(23) and one H(15) atom. The C(21)-C(23) bond length is 1.38 Å. The C(21)-H(15) bond length is 0.88 Å. In the second C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(16) atom. The C(22)-C(23) bond length is 1.38 Å. The C(22)-H(16) bond length is 0.92 Å. In the third C site, C(23) is bonded in a trigonal planar geometry to one C(21), one C(22), and one C(24) atom. The C(23)-C(24) bond length is 1.51 Å. In the fourth C site, C(24) is bonded in a water-like geometry to one C(23), one C(25), one H(17), and one H(18) atom. The C(24)-C(25) bond length is 1.52 Å. The C(24)-H(17) bond length is 0.93 Å. The C(24)-H(18) bond length is 0.92 Å. In the fifth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(27) atom. The C(25)-C(26) bond length is 1.38 Å. The C(25)-C(27) bond length is 1.38 Å. In the sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one F(5) atom. The C(26)-F(5) bond length is 1.35 Å. In the seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(25) and one F(6) atom. The C(27)-F(6) bond length is 1.35 Å. There are four inequivalent H sites. In the first H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the second H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the third H site, H(17) is bonded in a single-bond geometry to one C(24) atom. In the fourth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. There are two inequivalent F sites. In the first F site, F(5) is bonded in a single-bond geometry to one C(26) atom. In the second F site, F(6) is bonded in a single-bond geometry to one C(27) atom. In each CdH8(C2N)4 cluster, Cd(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Cd(1)-N(1) bond length is 2.35 Å. The Cd(1)-N(2) bond length is 2.35 Å. The Cd(1)-N(3) bond length is 2.38 Å. The Cd(1)-N(4) bond length is 2.37 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.92 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-H(2) bond length is 0.89 Å. In the third C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(7) bond length is 0.91 Å. In the fourth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(8) bond length is 0.97 Å. In the fifth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(13) atom. The C(19)-N(3) bond length is 1.33 Å. The C(19)-H(13) bond length is 0.96 Å. In the sixth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(14) atom. The C(20)-N(3) bond length is 1.35 Å. The C(20)-H(14) bond length is 0.92 Å. In the seventh C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(19) atom. The C(28)-N(4) bond length is 1.33 Å. The C(28)-H(19) bond length is 0.95 Å. In the eighth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(20) atom. The C(29)-N(4) bond length is 1.33 Å. The C(29)-H(20) bond length is 0.99 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(11) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(19), and one C(20) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(28), and one C(29) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(28) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(29) atom. Linkers: 6 Fc1c(F)c(Cc2ccncc2)c(F)c(F)c1Cc1ccncc1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 5.13 A, density 1.06 g/cm3, surface area 4881.67 m2/g, accessible volume 0.52 cm3/g