ZnC13H6(NO)4(CH)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of eight 02329_fluka molecules inside a ZnC13H6(NO)4 framework. In the ZnC13H6(NO)4 framework, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(2), one N(3), one N(4), one O(2), and one O(3) atom. The Zn(1)-N(2) bond length is 2.13 Å. The Zn(1)-N(3) bond length is 2.11 Å. The Zn(1)-N(4) bond length is 2.21 Å. The Zn(1)-O(2) bond length is 2.00 Å. The Zn(1)-O(3) bond length is 2.03 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(1)-C(4) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(3), and one O(4) atom. The C(2)-C(5) bond length is 1.49 Å. The C(2)-O(3) bond length is 1.28 Å. The C(2)-O(4) bond length is 1.26 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4), one C(5), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-C(5) bond length is 1.41 Å. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(7) atom. The C(5)-C(7) bond length is 1.41 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one H(2) atom. The C(6)-C(8) bond length is 1.39 Å. The C(6)-H(2) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(5), one C(8), and one H(3) atom. The C(7)-C(8) bond length is 1.38 Å. The C(7)-H(3) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one N(1) atom. The C(8)-N(1) bond length is 1.46 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(4) atom. The C(9)-N(1) bond length is 1.36 Å. The C(9)-N(2) bond length is 1.32 Å. The C(9)-H(4) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a distorted water-like geometry to one C(11), one N(1), and one N(3) atom. The C(10)-C(11) bond length is 1.48 Å. The C(10)-N(1) bond length is 1.36 Å. The C(10)-N(3) bond length is 1.32 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one N(4) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-N(4) bond length is 1.35 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(5) atom. The C(12)-H(5) bond length is 0.95 Å. In the thirteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(8) atom. The C(15)-N(4) bond length is 1.36 Å. The C(15)-H(8) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(10), one C(8), and one C(9) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1), one C(9), and one N(3) atom. The N(2)-N(3) bond length is 1.38 Å. In the third N site, N(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1), one C(10), and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(15) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(2) atom. Linkers: 4 [O]C(=O)c1cc(C([O])=O)cc(-n2cnnc2-c2ccccn2)c1. Metal clusters: 2 O=[C]O[Zn]1(O[C]=O)N=N[Zn](O[C]=O)(O[C]=O)N=N1. The MOF has largest included sphere 4.86 A, density 1.19 g/cm3, surface area 4215.86 m2/g, accessible volume 0.44 cm3/g