(PtAuC8H18(NS)2)2Zn(CO2)4 is Indium-derived structured and crystallizes in the hexagonal P6_422 space group. The structure is zero-dimensional and consists of three PtAuC8H18(NS)2 clusters and three Zn(CO2)4 clusters. In each PtAuC8H18(NS)2 cluster, Pt(1) is bonded in a distorted square co-planar geometry to two equivalent N(1) and two equivalent S(1) atoms. Both Pt(1)-N(1) bond lengths are 2.05 Å. Both Pt(1)-S(1) bond lengths are 2.30 Å. Au(1) is bonded in a linear geometry to two equivalent S(1) atoms. Both Au(1)-S(1) bond lengths are 2.29 Å. There are four inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one C(2), one C(3), one C(4), and one S(1) atom. The C(1)-C(2) bond length is 1.53 Å. The C(1)-C(3) bond length is 1.51 Å. The C(1)-C(4) bond length is 1.54 Å. The C(1)-S(1) bond length is 1.87 Å. In the second C site, C(2) is bonded in a 2-coordinate geometry to one C(1), one N(1), and one H(3) atom. The C(2)-N(1) bond length is 1.50 Å. The C(2)-H(3) bond length is 1.00 Å. In the third C site, C(3) is bonded in a trigonal non-coplanar geometry to one C(1); one H(4,7); and two equivalent H(5,6) atoms. The C(3)-H(4,7) bond length is 0.98 Å. Both C(3)-H(5,6) bond lengths are 0.98 Å. In the fourth C site, C(4) is bonded in a trigonal non-coplanar geometry to one C(1); one H(4,7); and two equivalent H(8,9) atoms. The C(4)-H(4,7) bond length is 0.98 Å. Both C(4)-H(8,9) bond lengths are 0.98 Å. N(1) is bonded in a distorted water-like geometry to one Pt(1); one C(2); and two equivalent H(1,2) atoms. Both N(1)-H(1,2) bond lengths are 0.92 Å. There are five inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4,7) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(8,9) is bonded in a single-bond geometry to one C(4) atom. S(1) is bonded in a distorted trigonal non-coplanar geometry to one Pt(1), one Au(1), and one C(1) atom. In each Zn(CO2)4 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to four equivalent O(1) atoms. All Zn(1)-O(1) bond lengths are 1.93 Å. C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(5)-O(1) bond length is 1.27 Å. The C(5)-O(2) bond length is 1.22 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(5) atom. Linkers: 12 CC(C)([S])[C@@H](N)C([O])=O. Metal clusters: 3 [Zn] ,6 [Pt] ,6 [Au]. The MOF has largest included sphere 4.40 A, density 2.16 g/cm3, surface area 2610.40 m2/g, accessible volume 0.18 cm3/g