(C3H2)3AlC11H10(N2Cl)2 is Indium-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of twenty-four 2,3-dimethyl-1,3-butadiene molecules and eight AlC11H10(N2Cl)2 clusters. In each AlC11H10(N2Cl)2 cluster, Al(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one N(4), one Cl(1), and one Cl(2) atom. The Al(1)-N(1) bond length is 2.05 Å. The Al(1)-N(2) bond length is 2.05 Å. The Al(1)-N(3) bond length is 2.06 Å. The Al(1)-N(4) bond length is 2.05 Å. The Al(1)-Cl(1) bond length is 2.26 Å. The Al(1)-Cl(2) bond length is 2.28 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. The C(3)-C(2) bond length is 1.40 Å. The C(3)-C(3) bond length is 1.48 Å. The C(3)-C(4) bond length is 1.39 Å. In the third C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(2) atom. The C(2)-H(2) bond length is 0.95 Å. In the fourth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(8) bond length is 0.95 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9,12) atom. The C(11)-N(3) bond length is 1.34 Å. The C(11)-H(9,12) bond length is 0.95 Å. In the sixth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9,12) atom. The C(15)-N(3) bond length is 1.35 Å. The C(15)-H(9,12) bond length is 0.95 Å. In the seventh C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(13) atom. The C(16)-N(4) bond length is 1.34 Å. The C(16)-H(13) bond length is 0.95 Å. In the eighth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(16) atom. The C(20)-N(4) bond length is 1.34 Å. The C(20)-H(16) bond length is 0.95 Å. In the ninth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.95 Å. In the tenth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.95 Å. In the eleventh C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5) atom. The C(6)-N(2) bond length is 1.35 Å. The C(6)-H(5) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Al(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Al(1), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Al(1), one C(11), and one C(15) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Al(1), one C(16), and one C(20) atom. There are nine inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9,12) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. There are two inequivalent Cl sites. In the first Cl site, Cl(2) is bonded in a single-bond geometry to one Al(1) atom. In the second Cl site, Cl(1) is bonded in a single-bond geometry to one Al(1) atom. Linkers: 32 c1cc(-c2ccncc2)ccn1. Metal clusters: 16 Cl[Al]Cl. The MOF has largest included sphere 6.30 A, density 1.01 g/cm3, surface area 4595.18 m2/g, accessible volume 0.45 cm3/g