Mn2H25(C20O11)2(CH)3(CH3)4CHO2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, eight 02329_fluka molecules, two formic acid molecules, and one Mn2H25(C20O11)2 cluster. In the Mn2H25(C20O11)2 cluster, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in an octahedral geometry to one O(10), one O(13), one O(16), one O(23), one O(7), and one O(8) atom. The Mn(1)-O(10) bond length is 2.10 Å. The Mn(1)-O(13) bond length is 2.14 Å. The Mn(1)-O(16) bond length is 2.11 Å. The Mn(1)-O(23) bond length is 2.17 Å. The Mn(1)-O(7) bond length is 2.33 Å. The Mn(1)-O(8) bond length is 2.23 Å. In the second Mn site, Mn(2) is bonded in a 5-coordinate geometry to one O(17), one O(18), one O(19), one O(22), and one O(23) atom. The Mn(2)-O(17) bond length is 2.08 Å. The Mn(2)-O(18) bond length is 2.86 Å. The Mn(2)-O(19) bond length is 2.11 Å. The Mn(2)-O(22) bond length is 2.35 Å. The Mn(2)-O(23) bond length is 2.34 Å. There are forty inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one O(21) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-O(21) bond length is 1.37 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(11), one C(2), and one C(4) atom. The C(3)-C(11) bond length is 1.51 Å. The C(3)-C(4) bond length is 1.37 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(2) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(43), and one C(6) atom. The C(5)-C(43) bond length is 1.51 Å. The C(5)-C(6) bond length is 1.38 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one O(18) atom. The C(6)-O(18) bond length is 1.38 Å. In the sixth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(8); two equivalent H(3,4); and one O(21) atom. The C(7)-C(8) bond length is 1.52 Å. Both C(7)-H(3,4) bond lengths are 0.97 Å. The C(7)-O(21) bond length is 1.41 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one O(22), and one O(23) atom. The C(8)-O(22) bond length is 1.21 Å. The C(8)-O(23) bond length is 1.25 Å. In the eighth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(10), one H(5), one H(6), and one O(18) atom. The C(9)-C(10) bond length is 1.51 Å. The C(9)-H(5) bond length is 0.97 Å. The C(9)-H(6) bond length is 0.97 Å. The C(9)-O(18) bond length is 1.39 Å. In the ninth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one O(19), and one O(20) atom. The C(10)-O(19) bond length is 1.26 Å. The C(10)-O(20) bond length is 1.24 Å. In the tenth C site, C(11) is bonded in a single-bond geometry to one C(13), one C(3), and one H(7) atom. The C(11)-C(13) bond length is 1.50 Å. The C(11)-H(7) bond length is 0.98 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(18) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-C(18) bond length is 1.39 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one O(4) atom. The C(14)-O(4) bond length is 1.37 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one O(1) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-O(1) bond length is 1.35 Å. In the fourteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(23) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-C(23) bond length is 1.50 Å. In the fifteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(13), one C(17), and one H(12) atom. The C(18)-H(12) bond length is 0.93 Å. In the sixteenth C site, C(19) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(13,14) and one O(1) atom. Both C(19)-H(13,14) bond lengths are 0.97 Å. The C(19)-O(1) bond length is 1.41 Å. In the seventeenth C site, C(21) is bonded in a distorted trigonal non-coplanar geometry to one C(22), one H(15), one H(16), and one O(4) atom. The C(21)-C(22) bond length is 1.49 Å. The C(21)-H(15) bond length is 0.97 Å. The C(21)-H(16) bond length is 0.97 Å. The C(21)-O(4) bond length is 1.42 Å. In the eighteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one O(24), and one O(5) atom. The C(22)-O(24) bond length is 1.23 Å. The C(22)-O(5) bond length is 1.26 Å. In the nineteenth C site, C(23) is bonded in a single-bond geometry to one C(17), one C(25), and one H(17) atom. The C(23)-C(25) bond length is 1.52 Å. The C(23)-H(17) bond length is 0.98 Å. In the twentieth C site, C(25) is bonded in a trigonal planar geometry to one C(23), one C(26), and one C(30) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-C(30) bond length is 1.39 Å. In the twenty-first C site, C(26) is bonded in a distorted single-bond geometry to one C(25), one C(27), and one H(21) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-H(21) bond length is 0.93 Å. In the twenty-second C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(35) atom. The C(27)-C(28) bond length is 1.37 Å. The C(27)-C(35) bond length is 1.52 Å. In the twenty-third C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one C(29), and one O(9) atom. The C(28)-C(29) bond length is 1.38 Å. The C(28)-O(9) bond length is 1.38 Å. In the twenty-fourth C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(22) atom. The C(29)-H(22) bond length is 0.93 Å. In the twenty-fifth C site, C(30) is bonded in a distorted single-bond geometry to one C(25) and one O(6) atom. The C(30)-O(6) bond length is 1.37 Å. In the twenty-sixth C site, C(31) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(23,24) and one O(6) atom. Both C(31)-H(23,24) bond lengths are 0.97 Å. The C(31)-O(6) bond length is 1.41 Å. In the twenty-seventh C site, C(32) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(32)-O(7) bond length is 1.26 Å. The C(32)-O(8) bond length is 1.25 Å. In the twenty-eighth C site, C(33) is bonded in a distorted trigonal non-coplanar geometry to one H(25), one H(26), and one O(9) atom. The C(33)-H(25) bond length is 0.97 Å. The C(33)-H(26) bond length is 0.97 Å. The C(33)-O(9) bond length is 1.41 Å. In the twenty-ninth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(11) atom. The C(34)-O(10) bond length is 1.25 Å. The C(34)-O(11) bond length is 1.21 Å. In the thirtieth C site, C(35) is bonded in a single-bond geometry to one C(27), one C(37), and one H(27) atom. The C(35)-C(37) bond length is 1.51 Å. The C(35)-H(27) bond length is 0.98 Å. In the thirty-first C site, C(37) is bonded in a trigonal planar geometry to one C(35), one C(38), and one C(42) atom. The C(37)-C(38) bond length is 1.40 Å. The C(37)-C(42) bond length is 1.39 Å. In the thirty-second C site, C(38) is bonded in a distorted single-bond geometry to one C(37) and one O(12) atom. The C(38)-O(12) bond length is 1.36 Å. In the thirty-third C site, C(40) is bonded in a single-bond geometry to one C(41) and one O(15) atom. The C(40)-C(41) bond length is 1.38 Å. The C(40)-O(15) bond length is 1.37 Å. In the thirty-fourth C site, C(41) is bonded in a trigonal planar geometry to one C(40), one C(42), and one C(43) atom. The C(41)-C(42) bond length is 1.38 Å. The C(41)-C(43) bond length is 1.51 Å. In the thirty-fifth C site, C(42) is bonded in a single-bond geometry to one C(37), one C(41), and one H(32) atom. The C(42)-H(32) bond length is 0.93 Å. In the thirty-sixth C site, C(43) is bonded in a single-bond geometry to one C(41), one C(5), and one H(33) atom. The C(43)-H(33) bond length is 0.98 Å. In the thirty-seventh C site, C(45) is bonded in a distorted trigonal non-coplanar geometry to one C(46); two equivalent H(37,38); and one O(15) atom. The C(45)-C(46) bond length is 1.53 Å. Both C(45)-H(37,38) bond lengths are 0.97 Å. The C(45)-O(15) bond length is 1.40 Å. In the thirty-eighth C site, C(46) is bonded in a distorted trigonal planar geometry to one C(45), one O(16), and one O(17) atom. The C(46)-O(16) bond length is 1.24 Å. The C(46)-O(17) bond length is 1.24 Å. In the thirty-ninth C site, C(47) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(39,40) and one O(12) atom. Both C(47)-H(39,40) bond lengths are 0.97 Å. The C(47)-O(12) bond length is 1.40 Å. In the fortieth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one O(13) and one O(14) atom. The C(48)-O(13) bond length is 1.27 Å. The C(48)-O(14) bond length is 1.24 Å. There are twenty inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(13,14) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(29) atom. In the thirteenth H site, H(23,24) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(25) is bonded in a single-bond geometry to one C(33) atom. In the fifteenth H site, H(26) is bonded in a single-bond geometry to one C(33) atom. In the sixteenth H site, H(27) is bonded in a single-bond geometry to one C(35) atom. In the seventeenth H site, H(32) is bonded in a single-bond geometry to one C(42) atom. In the eighteenth H site, H(33) is bonded in a single-bond geometry to one C(43) atom. In the nineteenth H site, H(37,38) is bonded in a single-bond geometry to one C(45) atom. In the twentieth H site, H(39,40) is bonded in a single-bond geometry to one C(47) atom. There are twenty-two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one C(16) and one C(19) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one C(14) and one C(21) atom. In the third O site, O(5) is bonded in a single-bond geometry to one C(22) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one C(30) and one C(31) atom. In the fifth O site, O(7) is bonded in a distorted L-shaped geometry to one Mn(1) and one C(32) atom. In the sixth O site, O(8) is bonded in a distorted L-shaped geometry to one Mn(1) and one C(32) atom. In the seventh O site, O(9) is bonded in a bent 120 degrees geometry to one C(28) and one C(33) atom. In the eighth O site, O(10) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(34) atom. In the ninth O site, O(11) is bonded in a single-bond geometry to one C(34) atom. In the tenth O site, O(12) is bonded in a bent 120 degrees geometry to one C(38) and one C(47) atom. In the eleventh O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(48) atom. In the twelfth O site, O(14) is bonded in a single-bond geometry to one C(48) atom. In the thirteenth O site, O(15) is bonded in a bent 120 degrees geometry to one C(40) and one C(45) atom. In the fourteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(46) atom. In the fifteenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Mn(2) and one C(46) atom. In the sixteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Mn(2), one C(6), and one C(9) atom. In the seventeenth O site, O(19) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(10) atom. In the eighteenth O site, O(20) is bonded in a single-bond geometry to one C(10) atom. In the nineteenth O site, O(21) is bonded in a bent 120 degrees geometry to one C(2) and one C(7) atom. In the twentieth O site, O(22) is bonded in a distorted single-bond geometry to one Mn(2) and one C(8) atom. In the twenty-first O site, O(23) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(2), and one C(8) atom. In the twenty-second O site, O(24) is bonded in a single-bond geometry to one C(22) atom. Linkers: 1 C[C@H]1c2cc(c(OCC([O])=O)cc2OCC([O])=O)[C@@H](C)c2cc(c(OCC([O])=O)cc2OCC([O])=O)[C@@H](C)c2cc(c(OCC([O])=O)cc2OCC(=O)O)[C@@H](C)c2cc1c(OCC([O])=O)cc2OCC([O])=O ,1 C[C@H]1c2cc(c(OCC([O])=O)cc2OCC([O])=O)[C@@H](C)c2cc(c(OCC(=O)O)cc2OCC([O])=O)[C@@H](C)c2cc(c(OCC([O])=O)cc2OCC([O])=O)[C@@H](C)c2cc1c(OCC([O])=O)cc2OCC([O])=O. Metal clusters: 2 O=[C]O[Mn]1O[C]O[Mn]2(O[C]=O)(O[C]=O)(O[C]O1)O[C]O2. RCSR code: bnn. The MOF has largest included sphere 5.46 A, density 1.13 g/cm3, surface area 4537.55 m2/g, accessible volume 0.37 cm3/g