CdH15(C2N)6(CH2)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and two CdH15(C2N)6 clusters. In each CdH15(C2N)6 cluster, Cd(1) is bonded in a T-shaped geometry to one N(1), one N(3), and one N(5) atom. The Cd(1)-N(1) bond length is 2.31 Å. The Cd(1)-N(3) bond length is 2.29 Å. The Cd(1)-N(5) bond length is 2.32 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2) atom. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. The C(3)-N(1) bond length is 1.30 Å. The C(3)-N(2) bond length is 1.34 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a 3-coordinate geometry to one N(2), one H(4), and one H(5) atom. The C(4)-N(2) bond length is 1.46 Å. The C(4)-H(4) bond length is 0.97 Å. The C(4)-H(5) bond length is 0.97 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(3), and one H(8) atom. The C(6)-C(7) bond length is 1.35 Å. The C(6)-N(3) bond length is 1.36 Å. The C(6)-H(8) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(4), and one H(9) atom. The C(7)-N(4) bond length is 1.37 Å. The C(7)-H(9) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(10) atom. The C(8)-N(3) bond length is 1.32 Å. The C(8)-N(4) bond length is 1.35 Å. The C(8)-H(10) bond length is 0.93 Å. In the eighth C site, C(9) is bonded in a 3-coordinate geometry to one N(4) and two equivalent H(11,12) atoms. The C(9)-N(4) bond length is 1.44 Å. Both C(9)-H(11,12) bond lengths are 0.97 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(5), and one H(15) atom. The C(11)-C(12) bond length is 1.36 Å. The C(11)-N(5) bond length is 1.35 Å. The C(11)-H(15) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(6), and one H(16) atom. The C(12)-N(6) bond length is 1.36 Å. The C(12)-H(16) bond length is 0.93 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(17) atom. The C(13)-N(5) bond length is 1.33 Å. The C(13)-N(6) bond length is 1.32 Å. The C(13)-H(17) bond length is 0.93 Å. In the twelfth C site, C(14) is bonded in a 3-coordinate geometry to one N(6) and two equivalent H(18,19) atoms. The C(14)-N(6) bond length is 1.46 Å. Both C(14)-H(18,19) bond lengths are 0.97 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(6), and one C(8) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(7), one C(8), and one C(9) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(11), and one C(13) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(12), one C(13), and one C(14) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(11,12) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(18,19) is bonded in a single-bond geometry to one C(14) atom. Linkers: 3 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 5.79 A, density 0.85 g/cm3, surface area 5078.34 m2/g, accessible volume 0.72 cm3/g