AgC8H6S(N2O)2 crystallizes in the orthorhombic Pna2_1 space group. Ag(1) is bonded in a 3-coordinate geometry to one N(1), one N(2), and one N(3) atom. The Ag(1)-N(1) bond length is 2.43 Å. The Ag(1)-N(2) bond length is 2.41 Å. The Ag(1)-N(3) bond length is 2.40 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.34 Å. The C(1)-N(1) bond length is 1.36 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(2), and one S(1) atom. The C(2)-N(2) bond length is 1.37 Å. The C(2)-S(1) bond length is 1.77 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2) atom. The C(3)-N(2) bond length is 1.36 Å. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(4)-N(1) bond length is 1.32 Å. The C(4)-H(3) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(4), and one S(1) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(4) bond length is 1.34 Å. The C(5)-S(1) bond length is 1.75 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(3), and one H(4) atom. The C(6)-N(3) bond length is 1.35 Å. The C(6)-H(4) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(5) atom. The C(7)-N(3) bond length is 1.33 Å. The C(7)-H(5) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(6) atom. The C(8)-N(4) bond length is 1.34 Å. The C(8)-H(6) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(2), and one C(3) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(6), and one C(7) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(5) and one C(8) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. S(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one C(5), one O(1), and one O(2) atom. The S(1)-O(1) bond length is 1.42 Å. The S(1)-O(2) bond length is 1.43 Å. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one S(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one S(1) atom. Linkers: 4 O=S(=O)(c1cnccn1)c1cnccn1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 4.68 A, density 1.54 g/cm3, surface area 3620.97 m2/g, accessible volume 0.31 cm3/g