Ag12C22H15(NO)9(CF3)3 crystallizes in the orthorhombic Pna2_1 space group. The structure consists of twelve trifluoromethane molecules inside a Ag12C22H15(NO)9 framework. In the Ag12C22H15(NO)9 framework, there are twelve inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted trigonal non-coplanar geometry to one C(1), one O(1), and one O(6) atom. The Ag(1)-C(1) bond length is 2.38 Å. The Ag(1)-O(1) bond length is 2.47 Å. The Ag(1)-O(6) bond length is 2.39 Å. In the second Ag site, Ag(2) is bonded in a 2-coordinate geometry to one C(2) and one C(3) atom. The Ag(2)-C(2) bond length is 2.37 Å. The Ag(2)-C(3) bond length is 2.46 Å. In the third Ag site, Ag(3) is bonded in a single-bond geometry to one C(2) atom. The Ag(3)-C(2) bond length is 2.14 Å. In the fourth Ag site, Ag(4) is bonded in a 3-coordinate geometry to one C(1), one N(8), and one O(5) atom. The Ag(4)-C(1) bond length is 2.37 Å. The Ag(4)-N(8) bond length is 2.32 Å. The Ag(4)-O(5) bond length is 2.41 Å. In the fifth Ag site, Ag(5) is bonded in a 4-coordinate geometry to one C(1), one C(2), one N(7), and one O(3) atom. The Ag(5)-C(1) bond length is 2.57 Å. The Ag(5)-C(2) bond length is 2.42 Å. The Ag(5)-N(7) bond length is 2.34 Å. The Ag(5)-O(3) bond length is 2.68 Å. In the sixth Ag site, Ag(6) is bonded in a 3-coordinate geometry to one C(1), one O(4), and one O(7) atom. The Ag(6)-C(1) bond length is 2.19 Å. The Ag(6)-O(4) bond length is 2.26 Å. The Ag(6)-O(7) bond length is 2.26 Å. In the seventh Ag site, Ag(7) is bonded in a 3-coordinate geometry to one C(1), one C(3), and one O(9) atom. The Ag(7)-C(1) bond length is 2.33 Å. The Ag(7)-C(3) bond length is 2.48 Å. The Ag(7)-O(9) bond length is 2.33 Å. In the eighth Ag site, Ag(8) is bonded in a 3-coordinate geometry to one C(2), one O(2), and one O(8) atom. The Ag(8)-C(2) bond length is 2.30 Å. The Ag(8)-O(2) bond length is 2.37 Å. The Ag(8)-O(8) bond length is 2.24 Å. In the ninth Ag site, Ag(9) is bonded in a linear geometry to one C(3) and one N(2) atom. The Ag(9)-C(3) bond length is 2.15 Å. The Ag(9)-N(2) bond length is 2.24 Å. In the tenth Ag site, Ag(10) is bonded in a 3-coordinate geometry to one C(3), one N(5), and one O(5) atom. The Ag(10)-C(3) bond length is 2.17 Å. The Ag(10)-N(5) bond length is 2.25 Å. The Ag(10)-O(5) bond length is 2.72 Å. In the eleventh Ag site, Ag(11) is bonded in a 3-coordinate geometry to one C(4), one N(1), and one O(1) atom. The Ag(11)-C(4) bond length is 2.15 Å. The Ag(11)-N(1) bond length is 2.31 Å. The Ag(11)-O(1) bond length is 2.47 Å. In the twelfth Ag site, Ag(12) is bonded in a 3-coordinate geometry to one C(4), one N(4), and one O(2) atom. The Ag(12)-C(4) bond length is 2.14 Å. The Ag(12)-N(4) bond length is 2.22 Å. The Ag(12)-O(2) bond length is 2.57 Å. There are twenty-two inequivalent C sites. In the first C site, C(22) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(22)-O(6) bond length is 1.19 Å. The C(22)-O(7) bond length is 1.24 Å. In the second C site, C(24) is bonded in a distorted bent 120 degrees geometry to one O(8) and one O(9) atom. The C(24)-O(8) bond length is 1.26 Å. The C(24)-O(9) bond length is 1.23 Å. In the third C site, C(1) is bonded in a 5-coordinate geometry to one Ag(1), one Ag(4), one Ag(5), one Ag(6), one Ag(7), and one C(2) atom. The C(1)-C(2) bond length is 1.21 Å. In the fourth C site, C(2) is bonded in a 5-coordinate geometry to one Ag(2), one Ag(3), one Ag(5), one Ag(8), and one C(1) atom. In the fifth C site, C(3) is bonded in a trigonal bipyramidal geometry to one Ag(10), one Ag(2), one Ag(7), one Ag(9), and one C(4) atom. The C(3)-C(4) bond length is 1.19 Å. In the sixth C site, C(4) is bonded in a 3-coordinate geometry to one Ag(11), one Ag(12), and one C(3) atom. In the seventh C site, C(5) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-N(1) bond length is 1.32 Å. The C(5)-H(3) bond length is 0.93 Å. In the eighth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(2), and one H(4) atom. The C(6)-N(2) bond length is 1.29 Å. The C(6)-H(4) bond length is 0.93 Å. In the ninth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one H(5) atom. The C(7)-C(8) bond length is 1.35 Å. The C(7)-N(2) bond length is 1.35 Å. The C(7)-H(5) bond length is 0.93 Å. In the tenth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(1) atom. The C(8)-C(9) bond length is 1.50 Å. The C(8)-N(1) bond length is 1.33 Å. In the eleventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(3), and one O(1) atom. The C(9)-N(3) bond length is 1.31 Å. The C(9)-O(1) bond length is 1.26 Å. In the twelfth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one N(4), and one H(8) atom. The C(10)-C(11) bond length is 1.36 Å. The C(10)-N(4) bond length is 1.34 Å. The C(10)-H(8) bond length is 0.93 Å. In the thirteenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one N(5), and one H(9) atom. The C(11)-N(5) bond length is 1.34 Å. The C(11)-H(9) bond length is 0.93 Å. In the fourteenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(5), and one H(10) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-N(5) bond length is 1.32 Å. The C(12)-H(10) bond length is 0.93 Å. In the fifteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one N(4) atom. The C(13)-C(14) bond length is 1.51 Å. The C(13)-N(4) bond length is 1.36 Å. In the sixteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(6), and one O(2) atom. The C(14)-N(6) bond length is 1.30 Å. The C(14)-O(2) bond length is 1.20 Å. In the seventeenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(13) atom. The C(15)-N(7) bond length is 1.33 Å. The C(15)-H(13) bond length is 0.93 Å. In the eighteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(14) atom. The C(16)-N(8) bond length is 1.34 Å. The C(16)-H(14) bond length is 0.93 Å. In the nineteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(8), and one H(15) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-N(8) bond length is 1.34 Å. The C(17)-H(15) bond length is 0.93 Å. In the twentieth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one N(7) atom. The C(18)-C(19) bond length is 1.51 Å. The C(18)-N(7) bond length is 1.36 Å. In the twenty-first C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one N(9), and one O(3) atom. The C(19)-N(9) bond length is 1.33 Å. The C(19)-O(3) bond length is 1.22 Å. In the twenty-second C site, C(20) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(20)-O(4) bond length is 1.21 Å. The C(20)-O(5) bond length is 1.29 Å. There are nine inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(11), one C(5), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(9), one C(6), and one C(7) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(9) and two equivalent H(1,2) atoms. Both N(3)-H(1,2) bond lengths are 0.86 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(12), one C(10), and one C(13) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Ag(10), one C(11), and one C(12) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(14), one H(6), and one H(7) atom. The N(6)-H(6) bond length is 0.86 Å. The N(6)-H(7) bond length is 0.86 Å. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Ag(5), one C(15), and one C(18) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Ag(4), one C(16), and one C(17) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(19), one H(11), and one H(12) atom. The N(9)-H(11) bond length is 0.86 Å. The N(9)-H(12) bond length is 0.86 Å. There are fourteen inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one N(6) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one N(6) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one N(9) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one N(9) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. There are nine inequivalent O sites. In the first O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Ag(8) and one C(24) atom. In the second O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Ag(7) and one C(24) atom. In the third O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1), one Ag(11), and one C(9) atom. In the fourth O site, O(2) is bonded in a 3-coordinate geometry to one Ag(12), one Ag(8), and one C(14) atom. In the fifth O site, O(3) is bonded in a single-bond geometry to one Ag(5) and one C(19) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ag(6) and one C(20) atom. In the seventh O site, O(5) is bonded in a 1-coordinate geometry to one Ag(10), one Ag(4), and one C(20) atom. In the eighth O site, O(6) is bonded in a distorted single-bond geometry to one Ag(1) and one C(22) atom. In the ninth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Ag(6) and one C(22) atom. Linkers: 8 NC(=O)c1cnccn1. Metal clusters: 48 [Ag]. The MOF has largest included sphere 6.28 A, density 2.37 g/cm3, surface area 2246.77 m2/g, accessible volume 0.18 cm3/g