(CH)2Cu2C22H14S(N3O2)2 crystallizes in the orthorhombic I2_12_12_1 space group. The structure consists of sixteen 02329_fluka molecules inside a Cu2C22H14S(N3O2)2 framework. In the Cu2C22H14S(N3O2)2 framework, there are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-O(1) bond length is 1.95 Å. The Cu(1)-O(2) bond length is 1.96 Å. The Cu(1)-O(3) bond length is 1.97 Å. The Cu(1)-O(4) bond length is 1.97 Å. In the second Cu site, Cu(2) is bonded in a tetrahedral geometry to two equivalent N(2) and two equivalent N(5) atoms. Both Cu(2)-N(2) bond lengths are 2.06 Å. Both Cu(2)-N(5) bond lengths are 2.08 Å. In the third Cu site, Cu(3) is bonded in a tetrahedral geometry to two equivalent N(3) and two equivalent N(6) atoms. Both Cu(3)-N(3) bond lengths are 2.06 Å. Both Cu(3)-N(6) bond lengths are 2.06 Å. There are twenty-two inequivalent C sites. In the first C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one N(3) atom. The C(3)-C(4) bond length is 1.45 Å. The C(3)-N(1) bond length is 1.36 Å. The C(3)-N(3) bond length is 1.33 Å. In the second C site, C(1) is bonded in a trigonal non-coplanar geometry to one C(2); one H(1); and two equivalent H(2,3) atoms. The C(1)-C(2) bond length is 1.48 Å. The C(1)-H(1) bond length is 0.98 Å. Both C(1)-H(2,3) bond lengths are 0.98 Å. In the third C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one N(1), and one N(2) atom. The C(2)-N(1) bond length is 1.37 Å. The C(2)-N(2) bond length is 1.31 Å. In the fourth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one N(4), and one N(5) atom. The C(8)-C(7) bond length is 1.46 Å. The C(8)-N(4) bond length is 1.37 Å. The C(8)-N(5) bond length is 1.32 Å. In the fifth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one N(4), and one N(6) atom. The C(9)-C(10) bond length is 1.48 Å. The C(9)-N(4) bond length is 1.35 Å. The C(9)-N(6) bond length is 1.33 Å. In the sixth C site, C(10) is bonded in a trigonal non-coplanar geometry to one C(9), one H(6), one H(7), and one H(8) atom. The C(10)-H(6) bond length is 0.98 Å. The C(10)-H(7) bond length is 0.98 Å. The C(10)-H(8) bond length is 0.98 Å. In the seventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(16), and one N(1) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(16) bond length is 1.37 Å. The C(11)-N(1) bond length is 1.44 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(9) atom. The C(12)-H(9) bond length is 0.95 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(11) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-H(11) bond length is 0.95 Å. In the tenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(17) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-C(17) bond length is 1.46 Å. In the eleventh C site, C(16) is bonded in a distorted single-bond geometry to one C(11), one C(15), and one H(12) atom. The C(16)-H(12) bond length is 0.95 Å. In the twelfth C site, C(17) is bonded in a bent 120 degrees geometry to one C(15), one O(1), and one O(2) atom. The C(17)-O(1) bond length is 1.28 Å. The C(17)-O(2) bond length is 1.28 Å. In the thirteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(19), one C(23), and one N(4) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-C(23) bond length is 1.37 Å. The C(18)-N(4) bond length is 1.44 Å. In the fourteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(13) atom. The C(19)-H(13) bond length is 0.95 Å. In the fifteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(15) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-H(15) bond length is 0.95 Å. In the sixteenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(24) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(24) bond length is 1.49 Å. In the seventeenth C site, C(23) is bonded in a distorted single-bond geometry to one C(18), one C(22), and one H(16) atom. The C(23)-H(16) bond length is 0.95 Å. In the eighteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(3), and one O(4) atom. The C(24)-O(3) bond length is 1.26 Å. The C(24)-O(4) bond length is 1.28 Å. In the nineteenth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one S(1) atom. The C(4)-C(5) bond length is 1.35 Å. The C(4)-S(1) bond length is 1.71 Å. In the twentieth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 0.95 Å. In the twenty-first C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(6)-C(7) bond length is 1.35 Å. The C(6)-H(5) bond length is 0.95 Å. In the twenty-second C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one S(1) atom. The C(7)-S(1) bond length is 1.71 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(11), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(2), and one N(3) atom. The N(2)-N(3) bond length is 1.40 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(3), one C(3), and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(18), one C(8), and one C(9) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(8), and one N(6) atom. The N(5)-N(6) bond length is 1.39 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cu(3), one C(9), and one N(5) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2,3) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. S(1) is bonded in an L-shaped geometry to one C(4) and one C(7) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(17) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(17) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(24) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(24) atom. Linkers: 8 Cc1nnc(-c2ccc(-c3nnc(C)n3-c3cccc(C([O])=O)c3)s2)n1-c1cccc(C([O])=O)c1. Metal clusters: 4 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4 ,8 [Cu]. The MOF has largest included sphere 6.67 A, density 1.24 g/cm3, surface area 3885.23 m2/g, accessible volume 0.43 cm3/g