(CoC16H11(NO2)2)2CoC20H14(NO2)2(CH)12(C4H3)2(C2HO)2(CH2CO)4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules, eight dimethyl ether molecules, sixteen dimethyl ether molecules, eight isobutylene molecules, four CoC16H11(NO2)2 clusters, and four CoC20H14(NO2)2 clusters. In each CoC16H11(NO2)2 cluster, Co(1) is bonded in a distorted octahedral geometry to one N(1), one N(2), one O(1), one O(2), one O(4), and one O(5) atom. The Co(1)-N(1) bond length is 2.13 Å. The Co(1)-N(2) bond length is 2.14 Å. The Co(1)-O(1) bond length is 2.02 Å. The Co(1)-O(2) bond length is 2.00 Å. The Co(1)-O(4) bond length is 2.14 Å. The Co(1)-O(5) bond length is 2.26 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(15) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(15) bond length is 0.94 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(11) atom. The C(3)-N(1) bond length is 1.31 Å. The C(3)-H(11) bond length is 0.93 Å. In the third C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(1), and one O(2) atom. The C(6)-C(7) bond length is 1.51 Å. The C(6)-O(1) bond length is 1.25 Å. The C(6)-O(2) bond length is 1.25 Å. In the fourth C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(6), and one C(8) atom. The C(7)-C(12) bond length is 1.35 Å. The C(7)-C(8) bond length is 1.36 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(1) atom. The C(8)-H(1) bond length is 0.93 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(12)-H(4) bond length is 0.93 Å. In the seventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(15), one N(2), and one H(6) atom. The C(14)-C(15) bond length is 1.37 Å. The C(14)-N(2) bond length is 1.33 Å. The C(14)-H(6) bond length is 0.93 Å. In the eighth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(7) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-H(7) bond length is 0.93 Å. In the ninth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. The C(16)-C(17) bond length is 1.47 Å. The C(16)-C(18) bond length is 1.39 Å. In the tenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(19)-N(2) bond length is 1.32 Å. The C(19)-H(10) bond length is 0.93 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(8) atom. The C(17)-H(8) bond length is 0.93 Å. In the twelfth C site, C(21) is bonded in a bent 120 degrees geometry to one C(22), one O(4), and one O(5) atom. The C(21)-C(22) bond length is 1.47 Å. The C(21)-O(4) bond length is 1.26 Å. The C(21)-O(5) bond length is 1.25 Å. In the thirteenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(27) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-C(27) bond length is 1.37 Å. In the fourteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(16) atom. The C(23)-H(16) bond length is 0.93 Å. In the fifteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(16) and one H(9) atom. The C(18)-H(9) bond length is 0.93 Å. In the sixteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(22) and one H(19) atom. The C(27)-H(19) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(14), and one C(19) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(3) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(1) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(9) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Co(1) and one C(6) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(6) atom. In the third O site, O(4) is bonded in an L-shaped geometry to one Co(1) and one C(21) atom. In the fourth O site, O(5) is bonded in a distorted L-shaped geometry to one Co(1) and one C(21) atom. In each CoC20H14(NO2)2 cluster, Co(2) is bonded in a square co-planar geometry to two equivalent N(3) and two equivalent O(9) atoms. Both Co(2)-N(3) bond lengths are 2.17 Å. Both Co(2)-O(9) bond lengths are 2.12 Å. There are ten inequivalent C sites. In the first C site, C(30) is bonded in a distorted single-bond geometry to one C(31) and one H(21) atom. The C(30)-C(31) bond length is 1.38 Å. The C(30)-H(21) bond length is 0.93 Å. In the second C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(34) atom. The C(31)-C(32) bond length is 1.36 Å. The C(31)-C(34) bond length is 1.51 Å. In the third C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(22) atom. The C(32)-H(22) bond length is 0.93 Å. In the fourth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(8), and one O(9) atom. The C(34)-O(8) bond length is 1.23 Å. The C(34)-O(9) bond length is 1.27 Å. In the fifth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(24) atom. The C(35)-N(3) bond length is 1.35 Å. The C(35)-H(24) bond length is 0.93 Å. In the sixth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(37), one N(3), and one H(25) atom. The C(36)-C(37) bond length is 1.37 Å. The C(36)-N(3) bond length is 1.33 Å. The C(36)-H(25) bond length is 0.93 Å. In the seventh C site, C(37) is bonded in a distorted single-bond geometry to one C(36), one C(38), and one H(26) atom. The C(37)-C(38) bond length is 1.38 Å. The C(37)-H(26) bond length is 0.93 Å. In the eighth C site, C(38) is bonded in a trigonal planar geometry to one C(37), one C(39), and one C(40) atom. The C(38)-C(39) bond length is 1.37 Å. The C(38)-C(40) bond length is 1.47 Å. In the ninth C site, C(39) is bonded in a distorted single-bond geometry to one C(38) and one H(27) atom. The C(39)-H(27) bond length is 0.93 Å. In the tenth C site, C(40) is bonded in a distorted single-bond geometry to one C(38) and one H(28) atom. The C(40)-H(28) bond length is 0.93 Å. N(3) is bonded in a trigonal planar geometry to one Co(2), one C(35), and one C(36) atom. There are seven inequivalent H sites. In the first H site, H(21) is bonded in a single-bond geometry to one C(30) atom. In the second H site, H(22) is bonded in a single-bond geometry to one C(32) atom. In the third H site, H(24) is bonded in a single-bond geometry to one C(35) atom. In the fourth H site, H(25) is bonded in a single-bond geometry to one C(36) atom. In the fifth H site, H(26) is bonded in a single-bond geometry to one C(37) atom. In the sixth H site, H(27) is bonded in a single-bond geometry to one C(39) atom. In the seventh H site, H(28) is bonded in a single-bond geometry to one C(40) atom. There are two inequivalent O sites. In the first O site, O(8) is bonded in a single-bond geometry to one C(34) atom. In the second O site, O(9) is bonded in a bent 120 degrees geometry to one Co(2) and one C(34) atom. Linkers: 2 [O]C(=O)c1ccc(O/C=C/Oc2ccc(C([O])=O)cc2)cc1 ,1 [O]C(=O)c1ccc(OCCOc2ccc(C(=O)O[Co](OC(=O)c3ccc(OCCOc4ccc(C([O])=O)cc4)cc3)(N3[CH]C=C(/C=C/c4ccncc4)C=C3)N3[CH]C=C(/C=C/c4ccncc4)C=C3)cc2)cc1 ,2 [CH]Oc1ccc(C(=O)O[Co@](OC(=O)c2ccc(OCCOc3ccc(C([O])=O)cc3)cc2)(N2[CH]C=C(/C=C/c3c[c]ncc3)C=C2)N2[CH]C=C(/C=C/c3ccncc3)C=C2)cc1 ,2 [O]C(=O)c1ccc(OCCOc2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 [C]1O[Co]2(O1)O[C]O[Co]1(O[C]O1)O[C]O2 ,1 O=[C]O[Co]O[C]=O. The MOF has largest included sphere 5.31 A, density 1.16 g/cm3, surface area 5011.74 m2/g, accessible volume 0.33 cm3/g