Gd2C34NH24O11 crystallizes in the monoclinic P2_1/c space group. There are two inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom. The Gd(1)-O(1) bond length is 2.39 Å. The Gd(1)-O(2) bond length is 2.27 Å. The Gd(1)-O(3) bond length is 2.32 Å. The Gd(1)-O(4) bond length is 2.31 Å. The Gd(1)-O(5) bond length is 2.38 Å. The Gd(1)-O(6) bond length is 2.36 Å. In the second Gd site, Gd(2) is bonded in a 7-coordinate geometry to one Gd(2), one O(8), one O(9), two equivalent O(10), and two equivalent O(7) atoms. The Gd(2)-Gd(2) bond length is 1.38 Å. The Gd(2)-O(8) bond length is 2.59 Å. The Gd(2)-O(9) bond length is 2.52 Å. There is one shorter (2.21 Å) and one longer (2.41 Å) Gd(2)-O(10) bond length. There is one shorter (2.25 Å) and one longer (2.40 Å) Gd(2)-O(7) bond length. There are thirty-four inequivalent C sites. In the first C site, C(25) is bonded in a distorted single-bond geometry to one C(17) and one H(19) atom. The C(25)-C(17) bond length is 1.40 Å. The C(25)-H(19) bond length is 0.93 Å. In the second C site, C(26) is bonded in a distorted single-bond geometry to one C(20), one C(30), and one H(20) atom. The C(26)-C(20) bond length is 1.39 Å. The C(26)-C(30) bond length is 1.39 Å. The C(26)-H(20) bond length is 0.93 Å. In the third C site, C(27) is bonded in a distorted single-bond geometry to one C(21) and one H(21) atom. The C(27)-C(21) bond length is 1.37 Å. The C(27)-H(21) bond length is 0.93 Å. In the fourth C site, C(28) is bonded in a distorted single-bond geometry to one C(24), one C(32), and one H(22) atom. The C(28)-C(24) bond length is 1.38 Å. The C(28)-C(32) bond length is 1.38 Å. The C(28)-H(22) bond length is 0.93 Å. In the fifth C site, C(29) is bonded in a distorted single-bond geometry to one C(30) and one H(23) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-H(23) bond length is 0.93 Å. In the sixth C site, C(30) is bonded in a trigonal planar geometry to one C(26), one C(29), and one C(33) atom. The C(30)-C(33) bond length is 1.49 Å. In the seventh C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(24) atom. The C(31)-C(32) bond length is 1.40 Å. The C(31)-H(24) bond length is 0.93 Å. In the eighth C site, C(32) is bonded in a trigonal planar geometry to one C(28), one C(31), and one C(34) atom. The C(32)-C(34) bond length is 1.52 Å. In the ninth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(4), and one O(5) atom. The C(33)-O(4) bond length is 1.25 Å. The C(33)-O(5) bond length is 1.26 Å. In the tenth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(10), and one O(6) atom. The C(34)-O(10) bond length is 1.27 Å. The C(34)-O(6) bond length is 1.22 Å. In the eleventh C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(3) atom. The C(1)-C(3) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.23 Å. The C(1)-O(3) bond length is 1.27 Å. In the twelfth C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(7) atom. The C(2)-C(4) bond length is 1.50 Å. The C(2)-O(2) bond length is 1.26 Å. The C(2)-O(7) bond length is 1.24 Å. In the thirteenth C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(6) atom. The C(3)-C(5) bond length is 1.39 Å. The C(3)-C(6) bond length is 1.38 Å. In the fourteenth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(7), and one C(8) atom. The C(4)-C(7) bond length is 1.41 Å. The C(4)-C(8) bond length is 1.41 Å. In the fifteenth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(5)-H(1) bond length is 0.93 Å. In the sixteenth C site, C(6) is bonded in a distorted single-bond geometry to one C(10), one C(3), and one H(2) atom. The C(6)-C(10) bond length is 1.38 Å. The C(6)-H(2) bond length is 0.93 Å. In the seventeenth C site, C(7) is bonded in a distorted single-bond geometry to one C(11), one C(4), and one H(3) atom. The C(7)-C(11) bond length is 1.37 Å. The C(7)-H(3) bond length is 0.93 Å. In the eighteenth C site, C(8) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(8)-H(4) bond length is 0.93 Å. In the nineteenth C site, C(9) is bonded in a distorted single-bond geometry to one C(13) and one H(5) atom. The C(9)-C(13) bond length is 1.36 Å. The C(9)-H(5) bond length is 0.93 Å. In the twentieth C site, C(10) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(6) atom. The C(10)-C(13) bond length is 1.40 Å. The C(10)-C(14) bond length is 1.53 Å. In the twenty-first C site, C(11) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(7) atom. The C(11)-C(15) bond length is 1.40 Å. The C(11)-C(16) bond length is 1.52 Å. In the twenty-second C site, C(12) is bonded in a distorted single-bond geometry to one C(15) and one H(6) atom. The C(12)-C(15) bond length is 1.41 Å. The C(12)-H(6) bond length is 0.93 Å. In the twenty-third C site, C(13) is bonded in a trigonal planar geometry to one C(10), one C(17), and one C(9) atom. The C(13)-C(17) bond length is 1.47 Å. In the twenty-fourth C site, C(14) is bonded in a tetrahedral geometry to one C(10), one C(18), one C(19), and one C(20) atom. The C(14)-C(18) bond length is 1.53 Å. The C(14)-C(19) bond length is 1.53 Å. The C(14)-C(20) bond length is 1.53 Å. In the twenty-fifth C site, C(15) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(21) atom. The C(15)-C(21) bond length is 1.46 Å. In the twenty-sixth C site, C(16) is bonded in a tetrahedral geometry to one C(11), one C(22), one C(23), and one C(24) atom. The C(16)-C(22) bond length is 1.55 Å. The C(16)-C(23) bond length is 1.50 Å. The C(16)-C(24) bond length is 1.53 Å. In the twenty-seventh C site, C(17) is bonded in a trigonal planar geometry to one C(13), one C(20), and one C(25) atom. The C(17)-C(20) bond length is 1.40 Å. In the twenty-eighth C site, C(18) is bonded in a trigonal non-coplanar geometry to one C(14), one H(7), one H(8), and one H(9) atom. The C(18)-H(7) bond length is 0.95 Å. The C(18)-H(8) bond length is 0.98 Å. The C(18)-H(9) bond length is 0.96 Å. In the twenty-ninth C site, C(19) is bonded in a trigonal non-coplanar geometry to one C(14), one H(10), one H(11), and one H(12) atom. The C(19)-H(10) bond length is 0.96 Å. The C(19)-H(11) bond length is 0.96 Å. The C(19)-H(12) bond length is 0.95 Å. In the thirtieth C site, C(20) is bonded in a trigonal planar geometry to one C(14), one C(17), and one C(26) atom. In the thirty-first C site, C(21) is bonded in a trigonal planar geometry to one C(15), one C(24), and one C(27) atom. The C(21)-C(24) bond length is 1.39 Å. In the thirty-second C site, C(22) is bonded in a trigonal non-coplanar geometry to one C(16), one H(13), one H(14), and one H(15) atom. The C(22)-H(13) bond length is 0.95 Å. The C(22)-H(14) bond length is 0.95 Å. The C(22)-H(15) bond length is 0.96 Å. In the thirty-third C site, C(23) is bonded in a trigonal non-coplanar geometry to one C(16), one H(16), one H(17), and one H(18) atom. The C(23)-H(16) bond length is 0.96 Å. The C(23)-H(17) bond length is 0.95 Å. The C(23)-H(18) bond length is 0.98 Å. In the thirty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(16), one C(21), and one C(28) atom. N(1) is bonded in a trigonal planar geometry to one O(11), one O(8), and one O(9) atom. The N(1)-O(11) bond length is 1.08 Å. The N(1)-O(8) bond length is 1.21 Å. The N(1)-O(9) bond length is 1.28 Å. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(23) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the twentieth H site, H(20) is bonded in a single-bond geometry to one C(26) atom. In the twenty-first H site, H(21) is bonded in a single-bond geometry to one C(27) atom. In the twenty-second H site, H(22) is bonded in a single-bond geometry to one C(28) atom. In the twenty-third H site, H(23) is bonded in a single-bond geometry to one C(29) atom. In the twenty-fourth H site, H(24) is bonded in a single-bond geometry to one C(31) atom. There are eleven inequivalent O sites. In the first O site, O(8) is bonded in a distorted water-like geometry to one Gd(2) and one N(1) atom. In the second O site, O(9) is bonded in a water-like geometry to one Gd(2) and one N(1) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Gd(1) and one C(1) atom. In the fourth O site, O(2) is bonded in a linear geometry to one Gd(1) and one C(2) atom. In the fifth O site, O(11) is bonded in a single-bond geometry to one N(1) atom. In the sixth O site, O(3) is bonded in a distorted linear geometry to one Gd(1) and one C(1) atom. In the seventh O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Gd(1) and one C(33) atom. In the eighth O site, O(10) is bonded in a 3-coordinate geometry to two equivalent Gd(2) and one C(34) atom. In the ninth O site, O(5) is bonded in a bent 150 degrees geometry to one Gd(1) and one C(33) atom. In the tenth O site, O(7) is bonded in a 3-coordinate geometry to two equivalent Gd(2) and one C(2) atom. In the eleventh O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Gd(1) and one C(34) atom. Linkers: 8 CC1(C)c2cc(C([O])=O)ccc2-c2ccc(C([O])=O)cc21. Metal clusters: 8 [Gd]. The MOF has largest included sphere 5.55 A, density 1.51 g/cm3, surface area 3560.11 m2/g, accessible volume 0.31 cm3/g