NaCo3C30H21(NO)12(CH)6 is Indium-derived structured and crystallizes in the hexagonal P6_3 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and two NaCo3C30H21(NO)12 clusters. In each NaCo3C30H21(NO)12 cluster, Na(1) is bonded in an octahedral geometry to three equivalent O(1) and three equivalent O(2) atoms. All Na(1)-O(1) bond lengths are 2.37 Å. All Na(1)-O(2) bond lengths are 2.37 Å. Co(1) is bonded in a 5-coordinate geometry to one N(2), one N(3), one O(1), one O(2), and one O(4) atom. The Co(1)-N(2) bond length is 2.02 Å. The Co(1)-N(3) bond length is 2.02 Å. The Co(1)-O(1) bond length is 2.01 Å. The Co(1)-O(2) bond length is 2.06 Å. The Co(1)-O(4) bond length is 2.36 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(3) bond length is 1.20 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(2)-O(2) bond length is 1.29 Å. The C(2)-O(4) bond length is 1.24 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(11) and one H(1) atom. The C(3)-C(11) bond length is 1.47 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.47 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(7), and one N(1) atom. The C(5)-C(7) bond length is 1.35 Å. The C(5)-N(1) bond length is 1.36 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(2), and one H(9) atom. The C(7)-N(2) bond length is 1.35 Å. The C(7)-H(9) bond length is 1.12 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(11), one N(3), and one H(5) atom. The C(8)-C(11) bond length is 1.36 Å. The C(8)-N(3) bond length is 1.38 Å. The C(8)-H(5) bond length is 0.93 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(6) atom. The C(9)-N(3) bond length is 1.30 Å. The C(9)-N(4) bond length is 1.30 Å. The C(9)-H(6) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a water-like geometry to one N(1) and one N(2) atom. The C(10)-N(1) bond length is 1.35 Å. The C(10)-N(2) bond length is 1.30 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(3), one C(8), and one N(4) atom. The C(11)-N(4) bond length is 1.32 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(10), one C(5), and one H(4) atom. The N(1)-H(4) bond length is 0.86 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(1), one C(10), and one C(7) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Co(1), one C(8), and one C(9) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(7) atom. The N(4)-H(7) bond length is 0.86 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(7) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a 3-coordinate geometry to one Na(1), one Co(1), and one C(1) atom. In the second O site, O(2) is bonded in a T-shaped geometry to one Na(1), one Co(1), and one C(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Co(1) and one C(2) atom. Linkers: 6 [O]C(=O)/C=C/c1cnc[nH]1 ,6 [O]C(=O)/C=C/c1cn[c][nH]1. Metal clusters: 2 O=[C]O[Co]1O[C]O1.O=[C]O[Co]1O[C]O1.O=[C]O[Co]1O[C]O1.[Na]. The MOF has largest included sphere 5.87 A, density 1.42 g/cm3, surface area 4122.58 m2/g, accessible volume 0.27 cm3/g