Fe3C24H12O13(C23H18)4(C2HO)4 is Indium-derived structured and crystallizes in the orthorhombic Pbcm space group. The structure is zero-dimensional and consists of eight methacrylic acid molecules, eight C23H18 clusters, and four Fe3C24H12O13 clusters. In each C23H18 cluster, there are forty-six inequivalent C sites. In the first C site, C(19) is bonded in a trigonal planar geometry to one C(13), one C(21), and one C(56) atom. The C(19)-C(13) bond length is 1.36 Å. The C(19)-C(21) bond length is 1.49 Å. The C(19)-C(56) bond length is 1.33 Å. In the second C site, C(20) is bonded in a distorted single-bond geometry to one C(31) and one H(43) atom. The C(20)-C(31) bond length is 1.34 Å. The C(20)-H(43) bond length is 0.93 Å. In the third C site, C(21) is bonded in a trigonal planar geometry to one C(19), one C(28), and one C(33) atom. The C(21)-C(28) bond length is 1.38 Å. The C(21)-C(33) bond length is 1.35 Å. In the fourth C site, C(22) is bonded in a water-like geometry to one C(17); one C(55); and two equivalent H(6,25) atoms. The C(22)-C(17) bond length is 1.55 Å. The C(22)-C(55) bond length is 1.54 Å. Both C(22)-H(6,25) bond lengths are 0.97 Å. In the fifth C site, C(24) is bonded in a distorted single-bond geometry to one C(25), one C(32), and one H(7) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-C(32) bond length is 1.32 Å. The C(24)-H(7) bond length is 0.93 Å. In the sixth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(11), one C(24), and one H(36) atom. The C(25)-C(11) bond length is 1.35 Å. The C(25)-H(36) bond length is 0.93 Å. In the seventh C site, C(58) is bonded in a single-bond geometry to one C(11) and one H(28) atom. The C(58)-C(11) bond length is 1.36 Å. The C(58)-H(28) bond length is 0.93 Å. In the eighth C site, C(27) is bonded in a trigonal planar geometry to one C(15), one C(35), and one C(48) atom. The C(27)-C(15) bond length is 1.54 Å. The C(27)-C(35) bond length is 1.35 Å. The C(27)-C(48) bond length is 1.38 Å. In the ninth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(3), one C(35), and one H(19) atom. The C(29)-C(3) bond length is 1.34 Å. The C(29)-C(35) bond length is 1.41 Å. The C(29)-H(19) bond length is 0.93 Å. In the tenth C site, C(30) is bonded in a distorted single-bond geometry to one C(43) and one H(16) atom. The C(30)-C(43) bond length is 1.38 Å. The C(30)-H(16) bond length is 0.93 Å. In the eleventh C site, C(31) is bonded in a trigonal planar geometry to one C(10), one C(20), and one C(34) atom. The C(31)-C(10) bond length is 1.36 Å. The C(31)-C(34) bond length is 1.49 Å. In the twelfth C site, C(34) is bonded to one C(31), one C(42), one C(51), and one C(59) atom to form corner-sharing CC4 tetrahedra. The C(34)-C(42) bond length is 1.54 Å. The C(34)-C(51) bond length is 1.54 Å. The C(34)-C(59) bond length is 1.56 Å. In the thirteenth C site, C(60) is bonded in a distorted trigonal planar geometry to one C(18), one C(2), and one H(13) atom. The C(60)-C(18) bond length is 1.42 Å. The C(60)-C(2) bond length is 1.26 Å. The C(60)-H(13) bond length is 0.93 Å. In the fourteenth C site, C(35) is bonded in a distorted single-bond geometry to one C(27), one C(29), and one H(11) atom. The C(35)-H(11) bond length is 0.93 Å. In the fifteenth C site, C(37) is bonded in a distorted single-bond geometry to one C(5) and one H(32,38) atom. The C(37)-C(5) bond length is 1.37 Å. The C(37)-H(32,38) bond length is 0.93 Å. In the sixteenth C site, C(36) is bonded in a trigonal planar geometry to one C(3), one C(47), and one C(49) atom. The C(36)-C(3) bond length is 1.46 Å. The C(36)-C(47) bond length is 1.35 Å. The C(36)-C(49) bond length is 1.37 Å. In the seventeenth C site, C(42) is bonded in a water-like geometry to one C(34); one C(55); and two equivalent H(10,42) atoms. The C(42)-C(55) bond length is 1.54 Å. Both C(42)-H(10,42) bond lengths are 0.97 Å. In the eighteenth C site, C(43) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(30) atom. The C(43)-C(11) bond length is 1.49 Å. The C(43)-C(12) bond length is 1.39 Å. In the nineteenth C site, C(45) is bonded in a water-like geometry to one C(15), one C(55), one H(21), and one H(35) atom. The C(45)-C(15) bond length is 1.52 Å. The C(45)-C(55) bond length is 1.54 Å. The C(45)-H(21) bond length is 0.97 Å. The C(45)-H(35) bond length is 0.97 Å. In the twentieth C site, C(47) is bonded in a distorted single-bond geometry to one C(36) and one H(30) atom. The C(47)-H(30) bond length is 0.93 Å. In the twenty-first C site, C(48) is bonded in a distorted single-bond geometry to one C(27) and one H(29) atom. The C(48)-H(29) bond length is 0.93 Å. In the twenty-second C site, C(49) is bonded in a distorted single-bond geometry to one C(36) and one H(12) atom. The C(49)-H(12) bond length is 0.93 Å. In the twenty-third C site, C(51) is bonded in a water-like geometry to one C(15); one C(34); and two equivalent H(9,23) atoms. The C(51)-C(15) bond length is 1.54 Å. Both C(51)-H(9,23) bond lengths are 0.97 Å. In the twenty-fourth C site, C(50) is bonded in a water-like geometry to one C(15); one C(17); and two equivalent H(18,26) atoms. The C(50)-C(15) bond length is 1.55 Å. The C(50)-C(17) bond length is 1.53 Å. Both C(50)-H(18,26) bond lengths are 0.97 Å. In the twenty-fifth C site, C(28) is bonded in a distorted single-bond geometry to one C(21) and one H(40) atom. The C(28)-H(40) bond length is 0.93 Å. In the twenty-sixth C site, C(59) is bonded in a water-like geometry to one C(17); one C(34); and two equivalent H(34,39) atoms. The C(59)-C(17) bond length is 1.53 Å. Both C(59)-H(34,39) bond lengths are 0.97 Å. In the twenty-seventh C site, C(62) is bonded in a distorted single-bond geometry to one C(1) and one H(27) atom. The C(62)-C(1) bond length is 1.37 Å. The C(62)-H(27) bond length is 0.93 Å. In the twenty-eighth C site, C(32) is bonded in a trigonal planar geometry to one C(14), one C(24), and one C(55) atom. The C(32)-C(14) bond length is 1.39 Å. The C(32)-C(55) bond length is 1.50 Å. In the twenty-ninth C site, C(33) is bonded in a distorted trigonal planar geometry to one C(10), one C(21), and one H(14) atom. The C(33)-C(10) bond length is 1.39 Å. The C(33)-H(14) bond length is 0.93 Å. In the thirtieth C site, C(2) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(60) atom. The C(2)-C(5) bond length is 1.49 Å. The C(2)-C(6) bond length is 1.34 Å. In the thirty-first C site, C(3) is bonded in a trigonal planar geometry to one C(29), one C(36), and one C(9) atom. The C(3)-C(9) bond length is 1.38 Å. In the thirty-second C site, C(55) is bonded to one C(22), one C(32), one C(42), and one C(45) atom to form corner-sharing CC4 tetrahedra. In the thirty-third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(32,38) atom. The C(4)-C(5) bond length is 1.36 Å. The C(4)-H(32,38) bond length is 0.93 Å. In the thirty-fourth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(37), and one C(4) atom. In the thirty-fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(2) and one H(41) atom. The C(6)-H(41) bond length is 0.93 Å. In the thirty-sixth C site, C(1) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(62) atom. The C(1)-C(17) bond length is 1.52 Å. The C(1)-C(18) bond length is 1.26 Å. In the thirty-seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(3) and one H(17) atom. The C(9)-H(17) bond length is 0.93 Å. In the thirty-eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(31), one C(33), and one H(4) atom. The C(10)-H(4) bond length is 0.93 Å. In the thirty-ninth C site, C(11) is bonded in a trigonal planar geometry to one C(25), one C(43), and one C(58) atom. In the fortieth C site, C(12) is bonded in a single-bond geometry to one C(43) and one H(33) atom. The C(12)-H(33) bond length is 0.93 Å. In the forty-first C site, C(13) is bonded in a distorted single-bond geometry to one C(19) and one H(44) atom. The C(13)-H(44) bond length is 0.93 Å. In the forty-second C site, C(14) is bonded in a distorted single-bond geometry to one C(32) and one H(15) atom. The C(14)-H(15) bond length is 0.93 Å. In the forty-third C site, C(15) is bonded to one C(27), one C(45), one C(50), and one C(51) atom to form corner-sharing CC4 tetrahedra. In the forty-fourth C site, C(56) is bonded in a distorted single-bond geometry to one C(19) and one H(8) atom. The C(56)-H(8) bond length is 0.93 Å. In the forty-fifth C site, C(17) is bonded to one C(1), one C(22), one C(50), and one C(59) atom to form corner-sharing CC4 tetrahedra. In the forty-sixth C site, C(18) is bonded in a 1-coordinate geometry to one C(1), one C(60), and one H(2) atom. The C(18)-H(2) bond length is 0.93 Å. There are thirty inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(18) atom. In the second H site, H(6,25) is bonded in a single-bond geometry to one C(22) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(24) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(10,42) is bonded in a single-bond geometry to one C(42) atom. In the sixth H site, H(9,23) is bonded in a single-bond geometry to one C(51) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(60) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(33) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(35) atom. In the tenth H site, H(44) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(9) atom. In the twelfth H site, H(18,26) is bonded in a single-bond geometry to one C(50) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(45) atom. In the sixteenth H site, H(27) is bonded in a single-bond geometry to one C(62) atom. In the seventeenth H site, H(28) is bonded in a single-bond geometry to one C(58) atom. In the eighteenth H site, H(29) is bonded in a single-bond geometry to one C(48) atom. In the nineteenth H site, H(30) is bonded in a single-bond geometry to one C(47) atom. In the twentieth H site, H(32,38) is bonded in a single-bond geometry to one C(4) atom. In the twenty-first H site, H(33) is bonded in a single-bond geometry to one C(12) atom. In the twenty-second H site, H(34,39) is bonded in a single-bond geometry to one C(59) atom. In the twenty-third H site, H(35) is bonded in a single-bond geometry to one C(45) atom. In the twenty-fourth H site, H(36) is bonded in a single-bond geometry to one C(25) atom. In the twenty-fifth H site, H(16) is bonded in a single-bond geometry to one C(30) atom. In the twenty-sixth H site, H(12) is bonded in a single-bond geometry to one C(49) atom. In the twenty-seventh H site, H(8) is bonded in a single-bond geometry to one C(56) atom. In the twenty-eighth H site, H(40) is bonded in a single-bond geometry to one C(28) atom. In the twenty-ninth H site, H(43) is bonded in a single-bond geometry to one C(20) atom. In the thirtieth H site, H(41) is bonded in a single-bond geometry to one C(6) atom. In each Fe3C24H12O13 cluster, there are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded to one O(6), two equivalent O(5), and two equivalent O(7) atoms to form corner-sharing FeO5 square pyramids. The Fe(1)-O(6) bond length is 1.91 Å. Both Fe(1)-O(5) bond lengths are 2.01 Å. Both Fe(1)-O(7) bond lengths are 2.03 Å. In the second Fe site, Fe(2) is bonded to one O(6), two equivalent O(8), and two equivalent O(9) atoms to form corner-sharing FeO5 square pyramids. The Fe(2)-O(6) bond length is 1.91 Å. Both Fe(2)-O(8) bond lengths are 2.01 Å. Both Fe(2)-O(9) bond lengths are 1.98 Å. In the third Fe site, Fe(3) is bonded to one O(6), two equivalent O(3), and two equivalent O(4) atoms to form corner-sharing FeO5 square pyramids. The Fe(3)-O(6) bond length is 1.93 Å. Both Fe(3)-O(3) bond lengths are 2.04 Å. Both Fe(3)-O(4) bond lengths are 2.02 Å. There are twelve inequivalent C sites. In the first C site, C(57) is bonded in a distorted single-bond geometry to one C(41) and one H(22) atom. The C(57)-C(41) bond length is 1.35 Å. The C(57)-H(22) bond length is 0.93 Å. In the second C site, C(23) is bonded in a distorted single-bond geometry to one C(41) and one H(37) atom. The C(23)-C(41) bond length is 1.36 Å. The C(23)-H(37) bond length is 0.93 Å. In the third C site, C(61) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(5), and one O(8) atom. The C(61)-C(8) bond length is 1.50 Å. The C(61)-O(5) bond length is 1.24 Å. The C(61)-O(8) bond length is 1.23 Å. In the fourth C site, C(39) is bonded in a bent 120 degrees geometry to one C(41), one O(4), and one O(7) atom. The C(39)-C(41) bond length is 1.50 Å. The C(39)-O(4) bond length is 1.22 Å. The C(39)-O(7) bond length is 1.26 Å. In the fifth C site, C(40) is bonded in a bent 120 degrees geometry to one C(52), one O(3), and one O(9) atom. The C(40)-C(52) bond length is 1.48 Å. The C(40)-O(3) bond length is 1.25 Å. The C(40)-O(9) bond length is 1.25 Å. In the sixth C site, C(41) is bonded in a trigonal planar geometry to one C(23), one C(39), and one C(57) atom. In the seventh C site, C(44) is bonded in a distorted single-bond geometry to one C(8) and one H(3) atom. The C(44)-C(8) bond length is 1.34 Å. The C(44)-H(3) bond length is 0.93 Å. In the eighth C site, C(52) is bonded in a trigonal planar geometry to one C(16), one C(40), and one C(53) atom. The C(52)-C(16) bond length is 1.38 Å. The C(52)-C(53) bond length is 1.39 Å. In the ninth C site, C(53) is bonded in a distorted single-bond geometry to one C(52) and one H(20) atom. The C(53)-H(20) bond length is 0.93 Å. In the tenth C site, C(54) is bonded in a distorted single-bond geometry to one C(8) and one H(1) atom. The C(54)-C(8) bond length is 1.33 Å. The C(54)-H(1) bond length is 0.93 Å. In the eleventh C site, C(8) is bonded in a trigonal planar geometry to one C(44), one C(54), and one C(61) atom. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(52) and one H(31) atom. The C(16)-H(31) bond length is 0.93 Å. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(54) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(44) atom. In the third H site, H(20) is bonded in a single-bond geometry to one C(53) atom. In the fourth H site, H(22) is bonded in a single-bond geometry to one C(57) atom. In the fifth H site, H(31) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(37) is bonded in a single-bond geometry to one C(23) atom. There are seven inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Fe(3) and one C(40) atom. In the second O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Fe(3) and one C(39) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(61) atom. In the fourth O site, O(6) is bonded in a trigonal planar geometry to one Fe(1), one Fe(2), and one Fe(3) atom. In the fifth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Fe(1) and one C(39) atom. In the sixth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Fe(2) and one C(61) atom. In the seventh O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Fe(2) and one C(40) atom. Linkers: 8 [O]C(=O)c1ccc(-c2ccc([C@]34C[C@]5(c6ccc(-c7ccc(C([O])=O)cc7)cc6)C[C@](c6ccc(-c7ccc(C([O])=O)cc7)cc6)(C3)C[C@](c3ccc(-c6ccc(C([O])=O)cc6)cc3)(C4)C5)cc2)cc1. Metal clusters: 4 [C]1O[Fe]23O[C]O[Fe]45(O1)O[C]O[Fe](O[C]O2)(O[C]O3)(O[C]O4)O5. The MOF has largest included sphere 13.15 A, density 0.57 g/cm3, surface area 4906.12 m2/g, accessible volume 1.29 cm3/g