Zn5C45H29(NO11)2(C3H2)2(CH)6(C4H3)2(C3NH2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; two 2,3-dimethyl-1,3-butadiene molecules; four ethane molecules; two ethane;propane;prop-1-ene molecules; four trimethylamine molecules; and two Zn5C45H29(NO11)2 clusters. In each Zn5C45H29(NO11)2 cluster, there are five inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(17), one O(19), and one O(5) atom to form ZnO4 tetrahedra that share  a cornercorner with one Zn(3)NO4 square pyramid and  a cornercorner with one Zn(2)O5 trigonal bipyramid. The Zn(1)-O(1) bond length is 1.94 Å. The Zn(1)-O(17) bond length is 1.95 Å. The Zn(1)-O(19) bond length is 1.96 Å. The Zn(1)-O(5) bond length is 1.94 Å. In the second Zn site, Zn(2) is bonded to one O(11), one O(15), one O(19), one O(2), and one O(21) atom to form ZnO5 trigonal bipyramids that share  a cornercorner with one Zn(3)NO4 square pyramid and  a cornercorner with one Zn(1)O4 tetrahedra. The Zn(2)-O(11) bond length is 2.08 Å. The Zn(2)-O(15) bond length is 1.97 Å. The Zn(2)-O(19) bond length is 1.98 Å. The Zn(2)-O(2) bond length is 2.28 Å. The Zn(2)-O(21) bond length is 1.97 Å. In the third Zn site, Zn(3) is bonded to one N(2), one O(12), one O(16), one O(18), and one O(19) atom to form ZnNO4 square pyramids that share  a cornercorner with one Zn(1)O4 tetrahedra and  a cornercorner with one Zn(2)O5 trigonal bipyramid. The Zn(3)-N(2) bond length is 2.16 Å. The Zn(3)-O(12) bond length is 2.03 Å. The Zn(3)-O(16) bond length is 2.08 Å. The Zn(3)-O(18) bond length is 2.11 Å. The Zn(3)-O(19) bond length is 2.14 Å. In the fourth Zn site, Zn(4) is bonded to one N(3), one O(13), one O(22), one O(7), one O(8), and one O(9) atom to form corner-sharing ZnNO5 octahedra. The corner-sharing octahedral tilt angles are 80°. The Zn(4)-N(3) bond length is 2.10 Å. The Zn(4)-O(13) bond length is 2.04 Å. The Zn(4)-O(22) bond length is 2.03 Å. The Zn(4)-O(7) bond length is 2.25 Å. The Zn(4)-O(8) bond length is 2.29 Å. The Zn(4)-O(9) bond length is 2.09 Å. In the fifth Zn site, Zn(5) is bonded to one O(10), one O(14), one O(20), one O(3), one O(4), and one O(8) atom to form corner-sharing ZnO6 octahedra. The corner-sharing octahedral tilt angles are 80°. The Zn(5)-O(10) bond length is 2.09 Å. The Zn(5)-O(14) bond length is 2.03 Å. The Zn(5)-O(20) bond length is 2.06 Å. The Zn(5)-O(3) bond length is 2.24 Å. The Zn(5)-O(4) bond length is 2.19 Å. The Zn(5)-O(8) bond length is 2.06 Å. There are forty-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1,4) atom. The C(1)-N(2) bond length is 1.34 Å. The C(1)-H(1,4) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1,4) atom. The C(5)-N(2) bond length is 1.34 Å. The C(5)-H(1,4) bond length is 0.93 Å. In the third C site, C(13) is bonded in a distorted water-like geometry to one C(14), one C(70), and one H(10) atom. The C(13)-C(14) bond length is 1.30 Å. The C(13)-C(70) bond length is 0.89 Å. The C(13)-H(10) bond length is 0.93 Å. In the fourth C site, C(14) is bonded in a 5-coordinate geometry to one C(13), one C(15), one C(17), one C(68), and one C(70) atom. The C(14)-C(15) bond length is 1.41 Å. The C(14)-C(17) bond length is 1.53 Å. The C(14)-C(68) bond length is 1.41 Å. The C(14)-C(70) bond length is 1.36 Å. In the fifth C site, C(15) is bonded in a distorted water-like geometry to one C(14), one C(68), and one H(11) atom. The C(15)-C(68) bond length is 0.94 Å. The C(15)-H(11) bond length is 0.93 Å. In the sixth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(1), and one O(2) atom. The C(17)-O(1) bond length is 1.21 Å. The C(17)-O(2) bond length is 1.25 Å. In the seventh C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(13) atom. The C(18)-N(3) bond length is 1.35 Å. The C(18)-H(13) bond length is 0.93 Å. In the eighth C site, C(22) is bonded in a 2-coordinate geometry to one C(66), one N(3), and one H(16) atom. The C(22)-C(66) bond length is 0.85 Å. The C(22)-N(3) bond length is 1.30 Å. The C(22)-H(16) bond length is 0.93 Å. In the ninth C site, C(30) is bonded in a distorted single-bond geometry to one C(31) and one H(22) atom. The C(30)-C(31) bond length is 1.38 Å. The C(30)-H(22) bond length is 0.93 Å. In the tenth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(34) atom. The C(31)-C(32) bond length is 1.37 Å. The C(31)-C(34) bond length is 1.52 Å. In the eleventh C site, C(32) is bonded in a single-bond geometry to one C(31) and one H(23) atom. The C(32)-H(23) bond length is 0.93 Å. In the twelfth C site, C(34) is bonded in a bent 120 degrees geometry to one C(31), one O(3), and one O(4) atom. The C(34)-O(3) bond length is 1.26 Å. The C(34)-O(4) bond length is 1.25 Å. In the thirteenth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(36), one O(5), and one O(6) atom. The C(35)-C(36) bond length is 1.51 Å. The C(35)-O(5) bond length is 1.27 Å. The C(35)-O(6) bond length is 1.24 Å. In the fourteenth C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(41) atom. The C(36)-C(37) bond length is 1.39 Å. The C(36)-C(41) bond length is 1.39 Å. In the fifteenth C site, C(37) is bonded in a distorted single-bond geometry to one C(36) and one H(2,25) atom. The C(37)-H(2,25) bond length is 0.93 Å. In the sixteenth C site, C(38) is bonded in a distorted single-bond geometry to one C(39) and one H(26) atom. The C(38)-C(39) bond length is 1.40 Å. The C(38)-H(26) bond length is 0.93 Å. In the seventeenth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(42) atom. The C(39)-C(40) bond length is 1.39 Å. The C(39)-C(42) bond length is 1.50 Å. In the eighteenth C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one H(27) atom. The C(40)-H(27) bond length is 0.93 Å. In the nineteenth C site, C(41) is bonded in a distorted single-bond geometry to one C(36) and one H(28) atom. The C(41)-H(28) bond length is 0.93 Å. In the twentieth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(39), one O(7), and one O(8) atom. The C(42)-O(7) bond length is 1.25 Å. The C(42)-O(8) bond length is 1.26 Å. In the twenty-first C site, C(43) is bonded in a distorted bent 120 degrees geometry to one C(44), one O(10), and one O(9) atom. The C(43)-C(44) bond length is 1.50 Å. The C(43)-O(10) bond length is 1.27 Å. The C(43)-O(9) bond length is 1.25 Å. In the twenty-second C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(49) atom. The C(44)-C(45) bond length is 1.40 Å. The C(44)-C(49) bond length is 1.40 Å. In the twenty-third C site, C(45) is bonded in a distorted single-bond geometry to one C(44) and one H(29,32) atom. The C(45)-H(29,32) bond length is 0.93 Å. In the twenty-fourth C site, C(46) is bonded in a distorted single-bond geometry to one C(47) and one H(30) atom. The C(46)-C(47) bond length is 1.39 Å. The C(46)-H(30) bond length is 0.93 Å. In the twenty-fifth C site, C(47) is bonded in a trigonal planar geometry to one C(46), one C(48), and one C(50) atom. The C(47)-C(48) bond length is 1.39 Å. The C(47)-C(50) bond length is 1.51 Å. In the twenty-sixth C site, C(48) is bonded in a distorted single-bond geometry to one C(47) and one H(31) atom. The C(48)-H(31) bond length is 0.93 Å. In the twenty-seventh C site, C(49) is bonded in a distorted single-bond geometry to one C(44) and one H(29,32) atom. The C(49)-H(29,32) bond length is 0.93 Å. In the twenty-eighth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one C(47), one O(11), and one O(12) atom. The C(50)-O(11) bond length is 1.26 Å. The C(50)-O(12) bond length is 1.25 Å. In the twenty-ninth C site, C(51) is bonded in a distorted bent 120 degrees geometry to one C(52), one O(13), and one O(14) atom. The C(51)-C(52) bond length is 1.50 Å. The C(51)-O(13) bond length is 1.26 Å. The C(51)-O(14) bond length is 1.26 Å. In the thirtieth C site, C(52) is bonded in a trigonal planar geometry to one C(51), one C(53), and one C(54) atom. The C(52)-C(53) bond length is 1.40 Å. The C(52)-C(54) bond length is 1.38 Å. In the thirty-first C site, C(53) is bonded in a distorted single-bond geometry to one C(52) and one H(33) atom. The C(53)-H(33) bond length is 0.93 Å. In the thirty-second C site, C(54) is bonded in a distorted single-bond geometry to one C(52) and one H(34) atom. The C(54)-H(34) bond length is 0.93 Å. In the thirty-third C site, C(55) is bonded in a distorted bent 120 degrees geometry to one C(56), one O(15), and one O(16) atom. The C(55)-C(56) bond length is 1.51 Å. The C(55)-O(15) bond length is 1.26 Å. The C(55)-O(16) bond length is 1.25 Å. In the thirty-fourth C site, C(56) is bonded in a trigonal planar geometry to one C(55), one C(57), and one C(58) atom. The C(56)-C(57) bond length is 1.39 Å. The C(56)-C(58) bond length is 1.40 Å. In the thirty-fifth C site, C(57) is bonded in a distorted single-bond geometry to one C(56) and one H(35) atom. The C(57)-H(35) bond length is 0.93 Å. In the thirty-sixth C site, C(58) is bonded in a distorted single-bond geometry to one C(56) and one H(36) atom. The C(58)-H(36) bond length is 0.93 Å. In the thirty-seventh C site, C(59) is bonded in a distorted bent 120 degrees geometry to one C(60), one O(17), and one O(18) atom. The C(59)-C(60) bond length is 1.50 Å. The C(59)-O(17) bond length is 1.27 Å. The C(59)-O(18) bond length is 1.25 Å. In the thirty-eighth C site, C(60) is bonded in a trigonal planar geometry to one C(59), one C(61), and one C(62) atom. The C(60)-C(61) bond length is 1.39 Å. The C(60)-C(62) bond length is 1.40 Å. In the thirty-ninth C site, C(61) is bonded in a distorted single-bond geometry to one C(60) and one H(37) atom. The C(61)-H(37) bond length is 0.93 Å. In the fortieth C site, C(62) is bonded in a distorted single-bond geometry to one C(60) and one H(38) atom. The C(62)-H(38) bond length is 0.93 Å. In the forty-first C site, C(63) is bonded in a trigonal planar geometry to one H(39), one O(20), and one O(21) atom. The C(63)-H(39) bond length is 0.93 Å. The C(63)-O(20) bond length is 1.20 Å. The C(63)-O(21) bond length is 1.26 Å. In the forty-second C site, C(64) is bonded in a 1-coordinate geometry to one N(3) and one H(49) atom. The C(64)-N(3) bond length is 1.56 Å. The C(64)-H(49) bond length is 0.93 Å. In the forty-third C site, C(66) is bonded in a 3-coordinate geometry to one C(22), one N(3), and one H(43) atom. The C(66)-N(3) bond length is 1.14 Å. The C(66)-H(43) bond length is 0.93 Å. In the forty-fourth C site, C(68) is bonded in a distorted water-like geometry to one C(14), one C(15), and one H(45) atom. The C(68)-H(45) bond length is 0.93 Å. In the forty-fifth C site, C(70) is bonded in a distorted water-like geometry to one C(13), one C(14), and one H(47) atom. The C(70)-H(47) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Zn(3), one C(1), and one C(5) atom. In the second N site, N(3) is bonded in a 5-coordinate geometry to one Zn(4), one C(18), one C(22), one C(64), and one C(66) atom. There are twenty-seven inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2,25) is bonded in a single-bond geometry to one C(2) atom. The H(2,25)-C(2) bond length is 0.93 Å. In the third H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one C(30) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(32) atom. In the ninth H site, H(26) is bonded in a single-bond geometry to one C(38) atom. In the tenth H site, H(27) is bonded in a single-bond geometry to one C(40) atom. In the eleventh H site, H(28) is bonded in a single-bond geometry to one C(41) atom. In the twelfth H site, H(29,32) is bonded in a single-bond geometry to one C(45) atom. In the thirteenth H site, H(30) is bonded in a single-bond geometry to one C(46) atom. In the fourteenth H site, H(31) is bonded in a single-bond geometry to one C(48) atom. In the fifteenth H site, H(33) is bonded in a single-bond geometry to one C(53) atom. In the sixteenth H site, H(34) is bonded in a single-bond geometry to one C(54) atom. In the seventeenth H site, H(35) is bonded in a single-bond geometry to one C(57) atom. In the eighteenth H site, H(36) is bonded in a single-bond geometry to one C(58) atom. In the nineteenth H site, H(37) is bonded in a single-bond geometry to one C(61) atom. In the twentieth H site, H(38) is bonded in a single-bond geometry to one C(62) atom. In the twenty-first H site, H(39) is bonded in a single-bond geometry to one C(63) atom. In the twenty-second H site, H(40) is bonded in a single-bond geometry to one O(19) atom. The H(40)-O(19) bond length is 0.96 Å. In the twenty-third H site, H(41) is bonded in a single-bond geometry to one O(22) atom. The H(41)-O(22) bond length is 1.11 Å. In the twenty-fourth H site, H(43) is bonded in a single-bond geometry to one C(66) atom. In the twenty-fifth H site, H(45) is bonded in a single-bond geometry to one C(68) atom. In the twenty-sixth H site, H(47) is bonded in a single-bond geometry to one C(70) atom. In the twenty-seventh H site, H(49) is bonded in a single-bond geometry to one C(64) atom. There are twenty-two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(17) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Zn(5) and one C(34) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Zn(5) and one C(34) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(35) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(35) atom. In the seventh O site, O(7) is bonded in a distorted L-shaped geometry to one Zn(4) and one C(42) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Zn(4), one Zn(5), and one C(42) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(43) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(43) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(50) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(50) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(51) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(51) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(55) atom. In the sixteenth O site, O(16) is bonded in a bent 150 degrees geometry to one Zn(3) and one C(55) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(59) atom. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(59) atom. In the nineteenth O site, O(19) is bonded in a distorted tetrahedral geometry to one Zn(1), one Zn(2), one Zn(3), and one H(40) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(63) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(63) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Zn(4) and one H(41) atom. Linkers: 7 [O]C(=O)c1ccc(C([O])=O)cc1 ,2 [C][C@H]1[CH][C@@H]([C]C2[CH][CH][CH]2)[CH]1.[O][C]=O.c1cc(-c2ccncc2)ccn1 ,1 [CH]1[CH][CH][CH]1.[C][C@H]1[CH][CH][C@H]1[N].[O]C(=O)c1ccc(N2[CH]C=[C]C=C2)cc1. Metal clusters: 1 O=[C]O[Zn@@]1(O)O[C]O[Zn]2O[C]O[Zn](O[CH]O[Zn]345(O[C]O[Zn](O)(O[C]O3)O[C]O4)O[C]O5)(O[C]O2)O[C]O1 ,5 [Zn]. The MOF has largest included sphere 4.56 A, density 1.58 g/cm3, surface area 4053.15 m2/g, accessible volume 0.28 cm3/g