(KZn6H26(C24O13)2)2Zn7H68(C27O7)4(C5H3)24 is Indium-derived structured and crystallizes in the tetragonal I4_122 space group. The structure is zero-dimensional and consists of thirty-two 1,3,5-triisopropenyl benzene molecules; eight KZn6H26(C24O13)2 clusters; and four Zn7H68(C27O7)4 clusters. In each KZn6H26(C24O13)2 cluster, K(1) is bonded in a distorted octahedral geometry to two equivalent O(1), two equivalent O(13), and two equivalent O(7) atoms. Both K(1)-O(1) bond lengths are 2.70 Å. Both K(1)-O(13) bond lengths are 2.71 Å. Both K(1)-O(7) bond lengths are 2.74 Å. There are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 4-coordinate geometry to one O(18), one O(19), one O(2), and one O(5) atom. The Zn(1)-O(18) bond length is 1.97 Å. The Zn(1)-O(19) bond length is 1.97 Å. The Zn(1)-O(2) bond length is 1.99 Å. The Zn(1)-O(5) bond length is 1.95 Å. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to one O(12), one O(17), one O(19), and one O(8) atom. The Zn(2)-O(12) bond length is 1.96 Å. The Zn(2)-O(17) bond length is 1.92 Å. The Zn(2)-O(19) bond length is 1.99 Å. The Zn(2)-O(8) bond length is 1.95 Å. In the third Zn site, Zn(3) is bonded in a tetrahedral geometry to one O(11), one O(14), one O(19), and one O(6) atom. The Zn(3)-O(11) bond length is 1.91 Å. The Zn(3)-O(14) bond length is 1.97 Å. The Zn(3)-O(19) bond length is 1.95 Å. The Zn(3)-O(6) bond length is 1.94 Å. There are twenty-four inequivalent C sites. In the first C site, C(50) is bonded in a distorted single-bond geometry to one C(51) and one H(31) atom. The C(50)-C(51) bond length is 1.36 Å. The C(50)-H(31) bond length is 0.93 Å. In the second C site, C(51) is bonded in a trigonal planar geometry to one C(50), one C(52), and one C(54) atom. The C(51)-C(52) bond length is 1.37 Å. The C(51)-C(54) bond length is 1.52 Å. In the third C site, C(52) is bonded in a distorted single-bond geometry to one C(51) and one H(32) atom. The C(52)-H(32) bond length is 0.93 Å. In the fourth C site, C(54) is bonded in a distorted bent 120 degrees geometry to one C(51), one O(11), and one O(12) atom. The C(54)-O(11) bond length is 1.22 Å. The C(54)-O(12) bond length is 1.28 Å. In the fifth C site, C(55) is bonded in a distorted bent 120 degrees geometry to one C(56), one O(13), and one O(14) atom. The C(55)-C(56) bond length is 1.49 Å. The C(55)-O(13) bond length is 1.26 Å. The C(55)-O(14) bond length is 1.25 Å. In the sixth C site, C(56) is bonded in a trigonal planar geometry to one C(55), one C(57), and one C(61) atom. The C(56)-C(57) bond length is 1.40 Å. The C(56)-C(61) bond length is 1.36 Å. In the seventh C site, C(57) is bonded in a distorted single-bond geometry to one C(56) and one H(34) atom. The C(57)-H(34) bond length is 0.93 Å. In the eighth C site, C(61) is bonded in a distorted single-bond geometry to one C(56) and one H(37) atom. The C(61)-H(37) bond length is 0.93 Å. In the ninth C site, C(77) is bonded in a distorted single-bond geometry to one C(78) and one H(46) atom. The C(77)-C(78) bond length is 1.36 Å. The C(77)-H(46) bond length is 0.93 Å. In the tenth C site, C(78) is bonded in a trigonal planar geometry to one C(77), one C(79), and one C(81) atom. The C(78)-C(79) bond length is 1.35 Å. The C(78)-C(81) bond length is 1.47 Å. In the eleventh C site, C(79) is bonded in a distorted single-bond geometry to one C(78) and one H(47) atom. The C(79)-H(47) bond length is 0.93 Å. In the twelfth C site, C(81) is bonded in a distorted bent 120 degrees geometry to one C(78), one O(17), and one O(18) atom. The C(81)-O(17) bond length is 1.26 Å. The C(81)-O(18) bond length is 1.24 Å. In the thirteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(5), and one O(6) atom. The C(27)-C(24) bond length is 1.49 Å. The C(27)-O(5) bond length is 1.25 Å. The C(27)-O(6) bond length is 1.26 Å. In the fourteenth C site, C(28) is bonded in a bent 120 degrees geometry to one C(29), one O(7), and one O(8) atom. The C(28)-C(29) bond length is 1.51 Å. The C(28)-O(7) bond length is 1.25 Å. The C(28)-O(8) bond length is 1.24 Å. In the fifteenth C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(34) atom. The C(29)-C(30) bond length is 1.36 Å. The C(29)-C(34) bond length is 1.39 Å. In the sixteenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.21 Å. The C(1)-O(2) bond length is 1.26 Å. In the seventeenth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.42 Å. The C(2)-C(7) bond length is 1.36 Å. In the eighteenth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(3)-H(4) bond length is 0.93 Å. In the nineteenth C site, C(7) is bonded in a single-bond geometry to one C(2) and one H(7) atom. The C(7)-H(7) bond length is 0.93 Å. In the twentieth C site, C(23) is bonded in a single-bond geometry to one C(24) and one H(16) atom. The C(23)-C(24) bond length is 1.38 Å. The C(23)-H(16) bond length is 0.93 Å. In the twenty-first C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(27) atom. The C(24)-C(25) bond length is 1.37 Å. In the twenty-second C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(17) atom. The C(25)-H(17) bond length is 0.93 Å. In the twenty-third C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(19) atom. The C(30)-H(19) bond length is 0.93 Å. In the twenty-fourth C site, C(34) is bonded in a distorted single-bond geometry to one C(29) and one H(22) atom. The C(34)-H(22) bond length is 0.93 Å. There are thirteen inequivalent H sites. In the first H site, H(46) is bonded in a single-bond geometry to one C(77) atom. In the second H site, H(47) is bonded in a single-bond geometry to one C(79) atom. In the third H site, H(2) is bonded in a single-bond geometry to one O(19) atom. The H(2)-O(19) bond length is 0.85 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(30) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(22) is bonded in a single-bond geometry to one C(34) atom. In the tenth H site, H(34) is bonded in a single-bond geometry to one C(57) atom. In the eleventh H site, H(37) is bonded in a single-bond geometry to one C(61) atom. In the twelfth H site, H(31) is bonded in a single-bond geometry to one C(50) atom. In the thirteenth H site, H(32) is bonded in a single-bond geometry to one C(52) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one K(1) and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(27) atom. In the fourth O site, O(7) is bonded in a distorted single-bond geometry to one K(1) and one C(28) atom. In the fifth O site, O(8) is bonded in a water-like geometry to one Zn(2) and one C(28) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(27) atom. In the seventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(54) atom. In the eighth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(54) atom. In the ninth O site, O(13) is bonded in a distorted single-bond geometry to one K(1) and one C(55) atom. In the tenth O site, O(14) is bonded in a water-like geometry to one Zn(3) and one C(55) atom. In the eleventh O site, O(17) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(81) atom. In the twelfth O site, O(18) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(81) atom. In the thirteenth O site, O(19) is bonded in a distorted single-bond geometry to one Zn(1), one Zn(2), one Zn(3), and one H(2) atom. In each Zn7H68(C27O7)4 cluster, there are three inequivalent Zn sites. In the first Zn site, Zn(4) is bonded to one O(15), one O(20), one O(4), and one O(9) atom to form corner-sharing ZnO4 tetrahedra. The corner-sharing octahedral tilt angles are 80°. The Zn(4)-O(15) bond length is 1.95 Å. The Zn(4)-O(20) bond length is 1.95 Å. The Zn(4)-O(4) bond length is 2.02 Å. The Zn(4)-O(9) bond length is 1.97 Å. In the second Zn site, Zn(5) is bonded to two equivalent O(10), two equivalent O(20), and two equivalent O(3) atoms to form corner-sharing ZnO6 octahedra. Both Zn(5)-O(10) bond lengths are 2.10 Å. Both Zn(5)-O(20) bond lengths are 2.11 Å. Both Zn(5)-O(3) bond lengths are 2.07 Å. In the third Zn site, Zn(6) is bonded in a square co-planar geometry to four equivalent O(20) atoms. All Zn(6)-O(20) bond lengths are 2.08 Å. There are twenty-seven inequivalent C sites. In the first C site, C(45) is bonded in a single-bond geometry to one C(44) and one H(28) atom. The C(45)-C(44) bond length is 1.38 Å. The C(45)-H(28) bond length is 0.93 Å. In the second C site, C(46) is bonded in a single-bond geometry to one C(41) and one H(29) atom. The C(46)-C(41) bond length is 1.47 Å. The C(46)-H(29) bond length is 0.93 Å. In the third C site, C(47) is bonded in a distorted bent 120 degrees geometry to one C(44), one O(10), and one O(9) atom. The C(47)-C(44) bond length is 1.51 Å. The C(47)-O(10) bond length is 1.24 Å. The C(47)-O(9) bond length is 1.25 Å. In the fourth C site, C(48) is bonded in a trigonal planar geometry to one C(39), one C(49), and one C(53) atom. The C(48)-C(39) bond length is 1.48 Å. The C(48)-C(49) bond length is 1.37 Å. The C(48)-C(53) bond length is 1.38 Å. In the fifth C site, C(49) is bonded in a distorted single-bond geometry to one C(48) and one H(30) atom. The C(49)-H(30) bond length is 0.93 Å. In the sixth C site, C(41) is bonded in a trigonal planar geometry to one C(37), one C(42), and one C(46) atom. The C(41)-C(37) bond length is 1.51 Å. The C(41)-C(42) bond length is 1.34 Å. In the seventh C site, C(53) is bonded in a distorted single-bond geometry to one C(48) and one H(6,33) atom. The C(53)-H(6,33) bond length is 0.93 Å. In the eighth C site, C(42) is bonded in a distorted single-bond geometry to one C(41), one C(43), and one H(26) atom. The C(42)-C(43) bond length is 1.38 Å. The C(42)-H(26) bond length is 0.93 Å. In the ninth C site, C(43) is bonded in a distorted trigonal planar geometry to one C(42), one C(44), and one H(27) atom. The C(43)-C(44) bond length is 1.34 Å. The C(43)-H(27) bond length is 0.93 Å. In the tenth C site, C(70) is bonded in a distorted single-bond geometry to one C(71) and one H(42,43) atom. The C(70)-C(71) bond length is 1.39 Å. The C(70)-H(42,43) bond length is 0.93 Å. In the eleventh C site, C(71) is bonded in a trigonal planar geometry to one C(70), one C(72), and one C(74) atom. The C(71)-C(72) bond length is 1.39 Å. The C(71)-C(74) bond length is 1.49 Å. In the twelfth C site, C(72) is bonded in a distorted single-bond geometry to one C(71) and one H(42,43) atom. The C(72)-H(42,43) bond length is 0.93 Å. In the thirteenth C site, C(74) is bonded in a distorted bent 120 degrees geometry to one C(71), one O(15), and one O(16) atom. The C(74)-O(15) bond length is 1.28 Å. The C(74)-O(16) bond length is 1.21 Å. In the fourteenth C site, C(20) is bonded in a bent 120 degrees geometry to one C(17), one O(3), and one O(4) atom. The C(20)-C(17) bond length is 1.50 Å. The C(20)-O(3) bond length is 1.22 Å. The C(20)-O(4) bond length is 1.26 Å. In the fifteenth C site, C(36) is bonded in a distorted single-bond geometry to one C(35), one C(37), and one H(23) atom. The C(36)-C(35) bond length is 1.34 Å. The C(36)-C(37) bond length is 1.38 Å. The C(36)-H(23) bond length is 0.93 Å. In the sixteenth C site, C(38) is bonded in a distorted single-bond geometry to one C(37), one C(39), and one H(24) atom. The C(38)-C(37) bond length is 1.40 Å. The C(38)-C(39) bond length is 1.41 Å. The C(38)-H(24) bond length is 0.93 Å. In the seventeenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(12) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(12) bond length is 0.93 Å. In the eighteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.40 Å. In the nineteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(13) atom. The C(18)-H(13) bond length is 0.93 Å. In the twentieth C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(20) atom. The C(31)-C(32) bond length is 1.37 Å. The C(31)-H(20) bond length is 0.93 Å. In the twenty-first C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(35) atom. The C(32)-C(33) bond length is 1.36 Å. The C(32)-C(35) bond length is 1.52 Å. In the twenty-second C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(21) atom. The C(33)-H(21) bond length is 0.93 Å. In the twenty-third C site, C(35) is bonded in a trigonal planar geometry to one C(32), one C(36), and one C(40) atom. The C(35)-C(40) bond length is 1.37 Å. In the twenty-fourth C site, C(40) is bonded in a single-bond geometry to one C(35), one C(39), and one H(25) atom. The C(40)-C(39) bond length is 1.36 Å. The C(40)-H(25) bond length is 0.93 Å. In the twenty-fifth C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one C(41) atom. In the twenty-sixth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(48) atom. In the twenty-seventh C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(47) atom. There are sixteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(16) atom. The H(1)-O(16) bond length is 0.85 Å. In the second H site, H(3) is bonded in a single-bond geometry to one O(20) atom. The H(3)-O(20) bond length is 0.85 Å. In the third H site, H(6,33) is bonded in a single-bond geometry to one C(6) atom. The H(6,33)-C(6) bond length is 0.93 Å. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one C(31) atom. In the seventh H site, H(21) is bonded in a single-bond geometry to one C(33) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(36) atom. In the ninth H site, H(24) is bonded in a single-bond geometry to one C(38) atom. In the tenth H site, H(27) is bonded in a single-bond geometry to one C(43) atom. In the eleventh H site, H(28) is bonded in a single-bond geometry to one C(45) atom. In the twelfth H site, H(26) is bonded in a single-bond geometry to one C(42) atom. In the thirteenth H site, H(29) is bonded in a single-bond geometry to one C(46) atom. In the fourteenth H site, H(25) is bonded in a single-bond geometry to one C(40) atom. In the fifteenth H site, H(30) is bonded in a single-bond geometry to one C(49) atom. In the sixteenth H site, H(42,43) is bonded in a single-bond geometry to one C(70) atom. There are seven inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(20) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(20) atom. In the third O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(47) atom. In the fourth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Zn(5) and one C(47) atom. In the fifth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(74) atom. In the sixth O site, O(16) is bonded in a water-like geometry to one C(74) and one H(1) atom. In the seventh O site, O(20) is bonded in a distorted single-bond geometry to one Zn(4), one Zn(5), one Zn(6), and one H(3) atom. Linkers: 16 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C([O])=O)cc3)c2)cc1 ,8 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C(=O)O)cc3)c2)cc1. Metal clusters: 4 O=[C]O[Zn]1O[C]O[Zn](O[C]=O)O[C]O[Zn](O)(O[C]=O)O[C]O1.O=[C]O[Zn]1O[C]O[Zn](O[C]O[K])O[C]O[Zn@](O)(O[C]=O)O[C]O1.[H].[H] ,2 O[C]O[Zn@]1(O)O[C]O[Zn]2(O[C]O[Zn@@](O)(O[C]O)O[C]O2)O[C]O1.O[C]O[Zn@]1(O)O[C]O[Zn]2(O[C]O[Zn@@](O)(O[C]O)O[C]O2)O[C]O1.[Zn]. RCSR code: dny. The MOF has largest included sphere 9.75 A, density 0.88 g/cm3, surface area 4235.24 m2/g, accessible volume 0.68 cm3/g