(Zn4H16(C2O)15)3Zn8C24H12O25(C31H21)6(C3H2)12(C11H7)3(C5H3)3 is Indium-derived structured and crystallizes in the trigonal P-31c space group. The structure is zero-dimensional and consists of two 1,3,5-triisopropenyl benzene molecules; twelve 2,3-dimethyl-1,3-butadiene molecules; two C11H7 clusters; twelve C31H21 clusters; six Zn4H16(C2O)15 clusters; and two Zn8C24H12O25 clusters. In each C11H7 cluster, there are eight inequivalent C sites. In the first C site, C(63) is bonded in a trigonal planar geometry to one C(62) and two equivalent C(70) atoms. The C(63)-C(62) bond length is 1.51 Å. Both C(63)-C(70) bond lengths are 1.36 Å. In the second C site, C(47) is bonded in a single-bond geometry to one C(60) and one H(29) atom. The C(47)-C(60) bond length is 1.39 Å. The C(47)-H(29) bond length is 0.93 Å. In the third C site, C(48) is bonded in a distorted trigonal planar geometry to one C(49), one C(61), and one H(30) atom. The C(48)-C(49) bond length is 1.37 Å. The C(48)-C(61) bond length is 1.35 Å. The C(48)-H(30) bond length is 0.93 Å. In the fourth C site, C(49) is bonded in a distorted trigonal planar geometry to one C(48), one C(62), and one H(31) atom. The C(49)-C(62) bond length is 1.34 Å. The C(49)-H(31) bond length is 0.93 Å. In the fifth C site, C(61) is bonded in a trigonal planar geometry to one C(60) and two equivalent C(48) atoms. The C(61)-C(60) bond length is 1.59 Å. In the sixth C site, C(60) is bonded in a trigonal planar geometry to one C(61) and two equivalent C(47) atoms. In the seventh C site, C(70) is bonded in a single-bond geometry to two equivalent C(63) and one H(40) atom. The C(70)-H(40) bond length is 0.93 Å. In the eighth C site, C(62) is bonded in a trigonal planar geometry to one C(63) and two equivalent C(49) atoms. There are four inequivalent H sites. In the first H site, H(29) is bonded in a single-bond geometry to one C(47) atom. In the second H site, H(30) is bonded in a single-bond geometry to one C(48) atom. In the third H site, H(31) is bonded in a single-bond geometry to one C(49) atom. In the fourth H site, H(40) is bonded in a single-bond geometry to one C(70) atom. In each C31H21 cluster, there are thirty-one inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(6) atom. The C(1)-C(10) bond length is 1.54 Å. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(20), and one C(4) atom. The C(3)-C(20) bond length is 1.48 Å. The C(3)-C(4) bond length is 1.39 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(33), one C(4), and one C(6) atom. The C(5)-C(33) bond length is 1.55 Å. The C(5)-C(6) bond length is 1.39 Å. In the sixth C site, C(6) is bonded in a single-bond geometry to one C(1), one C(5), and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(5,6) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(5,6) bond length is 0.93 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(9) atom. The C(10)-C(11) bond length is 1.39 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(5,6) atom. The C(11)-H(5,6) bond length is 0.93 Å. In the tenth C site, C(20) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(3) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-C(25) bond length is 1.39 Å. In the eleventh C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one H(12) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(12) bond length is 0.93 Å. In the twelfth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one H(13) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-H(13) bond length is 0.93 Å. In the thirteenth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(26) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-C(26) bond length is 1.55 Å. In the fourteenth C site, C(24) is bonded in a single-bond geometry to one C(23) and one H(14) atom. The C(24)-H(14) bond length is 0.93 Å. In the fifteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(20) and one H(15) atom. The C(25)-H(15) bond length is 0.93 Å. In the sixteenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(23), one C(27), and one C(31) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-C(31) bond length is 1.39 Å. In the seventeenth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(16) atom. The C(27)-H(16) bond length is 0.93 Å. In the eighteenth C site, C(31) is bonded in a distorted single-bond geometry to one C(26) and one H(19) atom. The C(31)-H(19) bond length is 0.93 Å. In the nineteenth C site, C(33) is bonded in a 5-coordinate geometry to one C(34), one C(38), one C(5), one C(54), and one C(57) atom. The C(33)-C(34) bond length is 1.39 Å. The C(33)-C(38) bond length is 1.39 Å. The C(33)-C(54) bond length is 1.36 Å. The C(33)-C(57) bond length is 1.39 Å. In the twentieth C site, C(34) is bonded in a 4-coordinate geometry to one C(33), one C(35), one C(54), and one H(20) atom. The C(34)-C(35) bond length is 1.39 Å. The C(34)-C(54) bond length is 1.15 Å. The C(34)-H(20) bond length is 0.93 Å. In the twenty-first C site, C(38) is bonded in a 2-coordinate geometry to one C(33), one C(57), and one H(23) atom. The C(38)-C(57) bond length is 1.11 Å. The C(38)-H(23) bond length is 0.93 Å. In the twenty-second C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(34), one C(36), one C(55), and one H(21) atom. The C(35)-C(36) bond length is 1.39 Å. The C(35)-C(55) bond length is 1.08 Å. The C(35)-H(21) bond length is 0.93 Å. In the twenty-third C site, C(36) is bonded in a 5-coordinate geometry to one C(35), one C(37), one C(39), one C(55), and one C(56) atom. The C(36)-C(37) bond length is 1.39 Å. The C(36)-C(39) bond length is 1.42 Å. The C(36)-C(55) bond length is 1.20 Å. The C(36)-C(56) bond length is 1.30 Å. In the twenty-fourth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(36), one C(56), and one H(22) atom. The C(37)-C(56) bond length is 0.84 Å. The C(37)-H(22) bond length is 0.93 Å. In the twenty-fifth C site, C(39) is bonded in a trigonal planar geometry to one C(36), one C(40), and one C(44) atom. The C(39)-C(40) bond length is 1.39 Å. The C(39)-C(44) bond length is 1.39 Å. In the twenty-sixth C site, C(44) is bonded in a distorted single-bond geometry to one C(39) and one H(24,27) atom. The C(44)-H(24,27) bond length is 0.93 Å. In the twenty-seventh C site, C(54) is bonded in a 4-coordinate geometry to one C(33), one C(34), one C(55), and one H(36) atom. The C(54)-C(55) bond length is 1.38 Å. The C(54)-H(36) bond length is 0.93 Å. In the twenty-eighth C site, C(55) is bonded in a 4-coordinate geometry to one C(35), one C(36), one C(54), and one H(37) atom. The C(55)-H(37) bond length is 0.93 Å. In the twenty-ninth C site, C(57) is bonded in a 4-coordinate geometry to one C(33), one C(38), one C(56), and one H(39) atom. The C(57)-C(56) bond length is 1.40 Å. The C(57)-H(39) bond length is 0.93 Å. In the thirtieth C site, C(56) is bonded in a 2-coordinate geometry to one C(36), one C(37), one C(57), and one H(38) atom. The C(56)-H(38) bond length is 0.93 Å. In the thirty-first C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one H(24,27) atom. The C(40)-H(24,27) bond length is 0.93 Å. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(31) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(34) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(35) atom. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one C(38) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(37) atom. In the fifteenth H site, H(24,27) is bonded in a single-bond geometry to one C(40) atom. In the sixteenth H site, H(36) is bonded in a single-bond geometry to one C(54) atom. In the seventeenth H site, H(37) is bonded in a single-bond geometry to one C(55) atom. In the eighteenth H site, H(38) is bonded in a distorted single-bond geometry to one C(56) atom. In the nineteenth H site, H(39) is bonded in a single-bond geometry to one C(57) atom. In each Zn4H16(C2O)15 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(13), one O(2), one O(3), one O(7), and one O(9) atom to form distorted corner-sharing ZnO5 trigonal bipyramids. The Zn(1)-O(13) bond length is 1.90 Å. The Zn(1)-O(2) bond length is 1.98 Å. The Zn(1)-O(3) bond length is 1.98 Å. The Zn(1)-O(7) bond length is 1.98 Å. The Zn(1)-O(9) bond length is 2.14 Å. In the second Zn site, Zn(2) is bonded in a 5-coordinate geometry to one O(1), one O(13), one O(4), one O(8), and one O(9) atom. The Zn(2)-O(1) bond length is 1.97 Å. The Zn(2)-O(13) bond length is 1.99 Å. The Zn(2)-O(4) bond length is 1.93 Å. The Zn(2)-O(8) bond length is 1.92 Å. The Zn(2)-O(9) bond length is 1.89 Å. There are eighteen inequivalent C sites. In the first C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(19) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-C(18) bond length is 1.39 Å. The C(13)-C(19) bond length is 1.52 Å. In the second C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. In the third C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(18)-H(11) bond length is 0.93 Å. In the fourth C site, C(19) is bonded in a bent 120 degrees geometry to one C(13), one O(1), and one O(2) atom. The C(19)-O(1) bond length is 1.19 Å. The C(19)-O(2) bond length is 1.24 Å. In the fifth C site, C(28) is bonded in a single-bond geometry to one C(29) and one H(17) atom. The C(28)-C(29) bond length is 1.39 Å. The C(28)-H(17) bond length is 0.93 Å. In the sixth C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(32) atom. The C(29)-C(30) bond length is 1.39 Å. The C(29)-C(32) bond length is 1.51 Å. In the seventh C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(18) atom. The C(30)-H(18) bond length is 0.93 Å. In the eighth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(3), and one O(4) atom. The C(32)-O(3) bond length is 1.22 Å. The C(32)-O(4) bond length is 1.28 Å. In the ninth C site, C(58) is bonded in a distorted bent 120 degrees geometry to one C(59) and two equivalent O(7) atoms. The C(58)-C(59) bond length is 1.49 Å. Both C(58)-O(7) bond lengths are 1.22 Å. In the tenth C site, C(46) is bonded in a distorted single-bond geometry to one C(59) and one H(28) atom. The C(46)-C(59) bond length is 1.35 Å. The C(46)-H(28) bond length is 0.93 Å. In the eleventh C site, C(59) is bonded in a trigonal planar geometry to one C(58) and two equivalent C(46) atoms. In the twelfth C site, C(50) is bonded in a distorted trigonal planar geometry to one C(51), one C(65), and one H(32) atom. The C(50)-C(51) bond length is 1.40 Å. The C(50)-C(65) bond length is 1.33 Å. The C(50)-H(32) bond length is 0.93 Å. In the thirteenth C site, C(51) is bonded in a distorted single-bond geometry to one C(50), one C(66), and one H(33) atom. The C(51)-C(66) bond length is 1.36 Å. The C(51)-H(33) bond length is 0.93 Å. In the fourteenth C site, C(52) is bonded in a distorted single-bond geometry to one C(67) and one H(34) atom. The C(52)-C(67) bond length is 1.35 Å. The C(52)-H(34) bond length is 0.93 Å. In the fifteenth C site, C(64) is bonded in a bent 120 degrees geometry to one C(65) and two equivalent O(8) atoms. The C(64)-C(65) bond length is 1.51 Å. Both C(64)-O(8) bond lengths are 1.23 Å. In the sixteenth C site, C(65) is bonded in a trigonal planar geometry to one C(64) and two equivalent C(50) atoms. In the seventeenth C site, C(66) is bonded in a trigonal planar geometry to one C(67) and two equivalent C(51) atoms. The C(66)-C(67) bond length is 1.55 Å. In the eighteenth C site, C(67) is bonded in a trigonal planar geometry to one C(66) and two equivalent C(52) atoms. There are eight inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the third H site, H(17) is bonded in a single-bond geometry to one C(28) atom. In the fourth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. In the fifth H site, H(28) is bonded in a single-bond geometry to one C(46) atom. In the sixth H site, H(32) is bonded in a single-bond geometry to one C(50) atom. In the seventh H site, H(33) is bonded in a single-bond geometry to one C(51) atom. In the eighth H site, H(34) is bonded in a single-bond geometry to one C(52) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(19) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(19) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(32) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(32) atom. In the fifth O site, O(13) is bonded in a distorted tetrahedral geometry to two equivalent Zn(1) and two equivalent Zn(2) atoms. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(58) atom. In the seventh O site, O(9) is bonded in a distorted water-like geometry to one Zn(1) and one Zn(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(64) atom. In each Zn8C24H12O25 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(3) is bonded to one O(10), one O(11), one O(12), and one O(6) atom to form distorted corner-sharing ZnO4 tetrahedra. The Zn(3)-O(10) bond length is 2.00 Å. The Zn(3)-O(11) bond length is 1.83 Å. The Zn(3)-O(12) bond length is 2.05 Å. The Zn(3)-O(6) bond length is 2.03 Å. In the second Zn site, Zn(4) is bonded to one O(12) and three equivalent O(5) atoms to form distorted corner-sharing ZnO4 tetrahedra. The Zn(4)-O(12) bond length is 1.70 Å. All Zn(4)-O(5) bond lengths are 2.09 Å. There are four inequivalent C sites. In the first C site, C(41) is bonded in a distorted single-bond geometry to one C(42) and one H(25,26) atom. The C(41)-C(42) bond length is 1.39 Å. The C(41)-H(25,26) bond length is 0.93 Å. In the second C site, C(42) is bonded in a distorted trigonal planar geometry to one C(41), one C(43), and one C(45) atom. The C(42)-C(43) bond length is 1.39 Å. The C(42)-C(45) bond length is 1.51 Å. In the third C site, C(43) is bonded in a distorted single-bond geometry to one C(42) and one H(25,26) atom. The C(43)-H(25,26) bond length is 0.93 Å. In the fourth C site, C(45) is bonded in a 4-coordinate geometry to one C(42), one O(10), one O(11), one O(5), and one O(6) atom. The C(45)-O(10) bond length is 1.33 Å. The C(45)-O(11) bond length is 1.11 Å. The C(45)-O(5) bond length is 1.28 Å. The C(45)-O(6) bond length is 1.29 Å. H(25,26) is bonded in a single-bond geometry to one C(41) atom. There are five inequivalent O sites. In the first O site, O(12) is bonded in a 8-coordinate geometry to two equivalent Zn(4) and six equivalent Zn(3) atoms. In the second O site, O(6) is bonded in a 2-coordinate geometry to one Zn(3) and one C(45) atom. In the third O site, O(5) is bonded in a 1-coordinate geometry to one Zn(4) and one C(45) atom. In the fourth O site, O(10) is bonded in a 2-coordinate geometry to one Zn(3) and one C(45) atom. In the fifth O site, O(11) is bonded in a distorted single-bond geometry to one Zn(3) and one C(45) atom. Linkers: 4 [O]C(=O)c1ccc(-c2ccc(-c3cc(-c4ccc(-c5ccc(C([O])=O)cc5)cc4)cc(-c4ccc(-c5ccc(C([O])=O)cc5)cc4)c3)cc2)cc1 ,6 O1OC12OO2.[CH]1[C@H]2[C]3[C@@H]4[C@H]3[C@H]3[C@@H]4[C@@]34[C@H]2[C@H]14.[O]C(=O)c1ccc(-c2ccc(-c3c[c]cc(-c4ccc(-c5ccc(C([O])=O)cc5)cc4)c3)cc2)cc1.[c]1cc[c]cc1 ,6 O1OC12OO2.[CH]1[C@@H]2[C]3[C@@H]4[C@H]3[C@H]3[C@@H]4[C@@]34[C@@H]2[C@@H]14.[O]C(=O)c1ccc(-c2ccc(-c3c[c]cc(-c4ccc(-c5ccc(C([O])=O)cc5)cc4)c3)cc2)cc1.[c]1cc[c]cc1. Metal clusters: 3 [C]1O[Zn]234O[C]O[Zn@]5(O[C]O[Zn]6(O1)(O[C]O[Zn@@](O[C]O2)(O[C]O5)O6)O3)O4 ,2 O1OO[Zn]2OOOO[Zn](O1)[Zn]13O[Zn]2([Zn]2OOOO[Zn]1OOOO2)[Zn]1OOOO[Zn]3OOOO1 ,3 [C]1O[Zn]234O[C]O[Zn@]56O[C]O[Zn](O1)(O[C]O[Zn@](O[C]O2)(O[C]O5)O3)(O4)O6. The MOF has largest included sphere 17.97 A, density 0.24 g/cm3, surface area 4233.36 m2/g, accessible volume 3.61 cm3/g