CdC12N5H11(CH)2C6NH5 is Indium-derived structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight C6NH5 clusters, and eight CdC12N5H11 clusters. In each C6NH5 cluster, there are six inequivalent C sites. In the first C site, C(9) is bonded in a single-bond geometry to one C(8) and one H(7) atom. The C(9)-C(8) bond length is 1.40 Å. The C(9)-H(7) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2,3) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-H(2,3) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(4), and one N(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-N(2) bond length is 1.37 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(2,3) atom. The C(4)-H(2,3) bond length is 0.93 Å. In the fifth C site, C(7) is bonded in a single-bond geometry to one C(8) and one H(6) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(6) bond length is 0.93 Å. In the sixth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(2) atom. The C(8)-N(2) bond length is 1.39 Å. N(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(8), and one H(17) atom. The N(2)-H(17) bond length is 0.86 Å. There are four inequivalent H sites. In the first H site, H(2,3) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one N(2) atom. In each CdC12N5H11 cluster, Cd(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(3), one N(4), and one N(6) atom. The Cd(1)-N(1) bond length is 2.35 Å. The Cd(1)-N(3) bond length is 2.34 Å. The Cd(1)-N(4) bond length is 2.32 Å. The Cd(1)-N(6) bond length is 2.34 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.93 Å. In the third C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(5) atom. The C(6)-N(3) bond length is 1.34 Å. The C(6)-H(5) bond length is 0.93 Å. In the fourth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(8) atom. The C(10)-N(3) bond length is 1.35 Å. The C(10)-H(8) bond length is 0.93 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(9) atom. The C(11)-N(4) bond length is 1.35 Å. The C(11)-H(9) bond length is 0.93 Å. In the sixth C site, C(13) is bonded in a distorted single-bond geometry to one N(5) atom. The C(13)-N(5) bond length is 1.37 Å. In the seventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(12) atom. The C(15)-N(4) bond length is 1.34 Å. The C(15)-H(12) bond length is 0.93 Å. In the eighth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one N(6), and one H(13) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-N(6) bond length is 1.34 Å. The C(16)-H(13) bond length is 0.93 Å. In the ninth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(14) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(14) bond length is 0.93 Å. In the tenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one N(5) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-N(5) bond length is 1.40 Å. In the eleventh C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(15) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-H(15) bond length is 0.93 Å. In the twelfth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one N(6), and one H(16) atom. The C(20)-N(6) bond length is 1.34 Å. The C(20)-H(16) bond length is 0.93 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(5) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(6) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one Cd(1), one C(11), and one C(15) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one C(13), one C(18), and one H(18) atom. The N(5)-H(18) bond length is 0.86 Å. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one Cd(1), one C(16), and one C(20) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one N(5) atom. Linkers: 16 c1cc(Nc2ccncc2)ccn1. Metal clusters: 8 [Cd]. The MOF has largest included sphere 4.28 A, density 1.26 g/cm3, surface area 4693.82 m2/g, accessible volume 0.36 cm3/g