Cd2C23H14(N3O2)3(CH)10(C3H2O)3 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty 02329_fluka molecules; one 1,2,3,4,5,6-hexakis(methoxymethyl)benzene molecule; and two Cd2C23H14(N3O2)3 clusters. In each Cd2C23H14(N3O2)3 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 6-coordinate geometry to one N(2), one N(5), one O(4), one O(5), one O(8), and one O(9) atom. The Cd(1)-N(2) bond length is 2.40 Å. The Cd(1)-N(5) bond length is 2.43 Å. The Cd(1)-O(4) bond length is 2.38 Å. The Cd(1)-O(5) bond length is 2.39 Å. The Cd(1)-O(8) bond length is 2.21 Å. The Cd(1)-O(9) bond length is 2.72 Å. In the second Cd site, Cd(2) is bonded in a distorted square pyramidal geometry to one N(6), one N(8), one O(6), one O(7), and one O(9) atom. The Cd(2)-N(6) bond length is 2.32 Å. The Cd(2)-N(8) bond length is 2.22 Å. The Cd(2)-O(6) bond length is 2.35 Å. The Cd(2)-O(7) bond length is 2.33 Å. The Cd(2)-O(9) bond length is 2.32 Å. There are twenty-three inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one N(1) atom. The C(9)-N(1) bond length is 1.44 Å. In the second C site, C(11) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(7) atom. The C(11)-N(1) bond length is 1.35 Å. The C(11)-N(3) bond length is 1.29 Å. The C(11)-H(7) bond length is 0.93 Å. In the third C site, C(12) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(8) atom. The C(12)-N(1) bond length is 1.35 Å. The C(12)-N(2) bond length is 1.30 Å. The C(12)-H(8) bond length is 0.93 Å. In the fourth C site, C(18) is bonded in a distorted single-bond geometry to one N(4) atom. The C(18)-N(4) bond length is 1.43 Å. In the fifth C site, C(20) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(15) atom. The C(20)-N(4) bond length is 1.35 Å. The C(20)-N(5) bond length is 1.26 Å. The C(20)-H(15) bond length is 0.93 Å. In the sixth C site, C(21) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(16) atom. The C(21)-N(4) bond length is 1.36 Å. The C(21)-N(6) bond length is 1.30 Å. The C(21)-H(16) bond length is 0.93 Å. In the seventh C site, C(26) is bonded in a distorted single-bond geometry to one C(27) and one H(21,22) atom. The C(26)-C(27) bond length is 1.37 Å. The C(26)-H(21,22) bond length is 0.93 Å. In the eighth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(26), one C(28), and one N(7) atom. The C(27)-C(28) bond length is 1.37 Å. The C(27)-N(7) bond length is 1.45 Å. In the ninth C site, C(28) is bonded in a distorted single-bond geometry to one C(27) and one H(21,22) atom. The C(28)-H(21,22) bond length is 0.93 Å. In the tenth C site, C(29) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(23) atom. The C(29)-N(7) bond length is 1.36 Å. The C(29)-N(8) bond length is 1.29 Å. The C(29)-H(23) bond length is 0.93 Å. In the eleventh C site, C(30) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(24) atom. The C(30)-N(7) bond length is 1.35 Å. The C(30)-N(9) bond length is 1.30 Å. The C(30)-H(24) bond length is 0.93 Å. In the twelfth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(4), and one O(5) atom. The C(31)-C(32) bond length is 1.51 Å. The C(31)-O(4) bond length is 1.25 Å. The C(31)-O(5) bond length is 1.24 Å. In the thirteenth C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(37) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-C(37) bond length is 1.40 Å. In the fourteenth C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(25) atom. The C(33)-H(25) bond length is 0.93 Å. In the fifteenth C site, C(34) is bonded in a distorted single-bond geometry to one C(35) and one H(26) atom. The C(34)-C(35) bond length is 1.37 Å. The C(34)-H(26) bond length is 0.93 Å. In the sixteenth C site, C(35) is bonded in a trigonal planar geometry to one C(34), one C(36), and one C(38) atom. The C(35)-C(36) bond length is 1.41 Å. The C(35)-C(38) bond length is 1.50 Å. In the seventeenth C site, C(36) is bonded in a distorted single-bond geometry to one C(35) and one H(27) atom. The C(36)-H(27) bond length is 0.93 Å. In the eighteenth C site, C(37) is bonded in a distorted single-bond geometry to one C(32) and one H(28) atom. The C(37)-H(28) bond length is 0.93 Å. In the nineteenth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(6), and one O(7) atom. The C(38)-O(6) bond length is 1.26 Å. The C(38)-O(7) bond length is 1.24 Å. In the twentieth C site, C(39) is bonded in a bent 120 degrees geometry to one C(40), one O(8), and one O(9) atom. The C(39)-C(40) bond length is 1.51 Å. The C(39)-O(8) bond length is 1.25 Å. The C(39)-O(9) bond length is 1.25 Å. In the twenty-first C site, C(40) is bonded in a trigonal planar geometry to one C(39), one C(41), and one C(42) atom. The C(40)-C(41) bond length is 1.39 Å. The C(40)-C(42) bond length is 1.36 Å. In the twenty-second C site, C(41) is bonded in a single-bond geometry to one C(40) and one H(29) atom. The C(41)-H(29) bond length is 0.93 Å. In the twenty-third C site, C(42) is bonded in a distorted single-bond geometry to one C(40) and one H(30) atom. The C(42)-H(30) bond length is 0.93 Å. There are nine inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Cd(1), one C(12), and one N(3) atom. The N(2)-N(3) bond length is 1.39 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(11) and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(21) atom. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one Cd(1), one C(20), and one N(6) atom. The N(5)-N(6) bond length is 1.40 Å. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(21), and one N(5) atom. In the seventh N site, N(8) is bonded in a 3-coordinate geometry to one Cd(2), one C(29), and one N(9) atom. The N(8)-N(9) bond length is 1.39 Å. In the eighth N site, N(9) is bonded in a distorted single-bond geometry to one C(30) and one N(8) atom. In the ninth N site, N(7) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(30) atom. There are thirteen inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(20) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the fifth H site, H(23) is bonded in a single-bond geometry to one C(29) atom. In the sixth H site, H(24) is bonded in a single-bond geometry to one C(30) atom. In the seventh H site, H(25) is bonded in a single-bond geometry to one C(33) atom. In the eighth H site, H(29) is bonded in a single-bond geometry to one C(41) atom. In the ninth H site, H(28) is bonded in a single-bond geometry to one C(37) atom. In the tenth H site, H(26) is bonded in a single-bond geometry to one C(34) atom. In the eleventh H site, H(27) is bonded in a single-bond geometry to one C(36) atom. In the twelfth H site, H(30) is bonded in a single-bond geometry to one C(42) atom. In the thirteenth H site, H(21,22) is bonded in a single-bond geometry to one C(26) atom. There are six inequivalent O sites. In the first O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(31) atom. In the second O site, O(5) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(31) atom. In the third O site, O(6) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(38) atom. In the fourth O site, O(7) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(38) atom. In the fifth O site, O(8) is bonded in a water-like geometry to one Cd(1) and one C(39) atom. In the sixth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Cd(1), one Cd(2), and one C(39) atom. Linkers: 2 [c]1nncn1-c1cccc(OCc2c(COc3cccc(-n4cnnc4)c3)c(COc3cccc(-n4cnnc4)c3)c(COc3cccc(-n4cnnc4)c3)c(COc3cccc(-n4cnnc4)c3)c2COc2cccc(-n3cnnc3)c2)c1 ,3 [O]C(=O)c1ccc(C([O])=O)cc1 ,1 [CH]/C=C(\[CH])OCc1c(COC([CH])=[CH])c(COc2cccc(-n3cnnc3)c2)c(COc2cccc(-n3cnnc3)c2)c(COc2cccc(-n3cnnc3)c2)c1COc1cccc(-n2cnnc2)c1 ,1 c1cc(OCc2c(COc3cccc(-n4cnnc4)c3)c(COc3cccc(-n4cnnc4)c3)c(COc3cccc(-n4cnnc4)c3)c(COc3cccc(-n4cnnc4)c3)c2COc2cccc(-n3cnnc3)c2)cc(-n2cnnc2)c1 ,1 [CH]C(=[CH])OCc1c(COC(=[CH])C=[CH])c(COc2cccc(-n3cnnc3)c2)c(COc2cccc(-n3cnnc3)c2)c(COc2cccc(-n3cnnc3)c2)c1COc1cccc(-n2cnnc2)c1. Metal clusters: 2 [C]1O[Cd]2([N][N][Cd]3(O[C]O3)O[C]O2)O1. The MOF has largest included sphere 5.30 A, density 1.52 g/cm3, surface area 4217.34 m2/g, accessible volume 0.19 cm3/g