Zn4C57H33O13(CH)3 crystallizes in the trigonal R3c space group. The structure consists of thirty-six 02329_fluka molecules and six Zn4C57H33O13 clusters inside a Zn4C57H33O13 framework. In each Zn4C57H33O13 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(3) is bonded to one O(10), one O(6), one O(7), and one O(9) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(10) bond length is 1.95 Å. The Zn(3)-O(6) bond length is 1.99 Å. The Zn(3)-O(7) bond length is 1.96 Å. The Zn(3)-O(9) bond length is 1.92 Å. In the second Zn site, Zn(4) is bonded to one O(10) and three equivalent O(8) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(4)-O(10) bond length is 1.95 Å. All Zn(4)-O(8) bond lengths are 1.95 Å. There are nineteen inequivalent C sites. In the first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(6), and one O(7) atom. The C(21)-C(22) bond length is 1.48 Å. The C(21)-O(6) bond length is 1.29 Å. The C(21)-O(7) bond length is 1.23 Å. In the second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(27) atom. The C(22)-C(23) bond length is 1.36 Å. The C(22)-C(27) bond length is 1.37 Å. In the third C site, C(23) is bonded in a single-bond geometry to one C(22) and one H(13) atom. The C(23)-H(13) bond length is 0.93 Å. In the fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(14) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-H(14) bond length is 0.93 Å. In the fifth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(28) atom. The C(25)-C(26) bond length is 1.35 Å. The C(25)-C(28) bond length is 1.49 Å. In the sixth C site, C(26) is bonded in a single-bond geometry to one C(25) and one H(15) atom. The C(26)-H(15) bond length is 0.93 Å. In the seventh C site, C(27) is bonded in a single-bond geometry to one C(22) and one H(16) atom. The C(27)-H(16) bond length is 0.93 Å. In the eighth C site, C(28) is bonded in a trigonal planar geometry to one C(25), one C(29), and one C(33) atom. The C(28)-C(29) bond length is 1.39 Å. The C(28)-C(33) bond length is 1.42 Å. In the ninth C site, C(29) is bonded in a single-bond geometry to one C(28) and one H(17) atom. The C(29)-H(17) bond length is 0.93 Å. In the tenth C site, C(31) is bonded in a single-bond geometry to one C(32) and one H(19) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-H(19) bond length is 0.93 Å. In the eleventh C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(34) atom. The C(32)-C(33) bond length is 1.41 Å. The C(32)-C(34) bond length is 1.49 Å. In the twelfth C site, C(33) is bonded in a distorted single-bond geometry to one C(28), one C(32), and one H(20) atom. The C(33)-H(20) bond length is 0.93 Å. In the thirteenth C site, C(34) is bonded in a trigonal planar geometry to one C(32), one C(35), and one C(39) atom. The C(34)-C(35) bond length is 1.39 Å. The C(34)-C(39) bond length is 1.42 Å. In the fourteenth C site, C(35) is bonded in a distorted trigonal planar geometry to one C(34), one C(36), and one H(21) atom. The C(35)-C(36) bond length is 1.35 Å. The C(35)-H(21) bond length is 0.93 Å. In the fifteenth C site, C(36) is bonded in a distorted single-bond geometry to one C(35), one C(37), and one H(22) atom. The C(36)-C(37) bond length is 1.37 Å. The C(36)-H(22) bond length is 0.93 Å. In the sixteenth C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one C(40) atom. The C(37)-C(38) bond length is 1.44 Å. The C(37)-C(40) bond length is 1.48 Å. In the seventeenth C site, C(38) is bonded in a distorted single-bond geometry to one C(37) and one H(23) atom. The C(38)-H(23) bond length is 0.93 Å. In the eighteenth C site, C(39) is bonded in a distorted single-bond geometry to one C(34) and one H(24) atom. The C(39)-H(24) bond length is 0.93 Å. In the nineteenth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(8), and one O(9) atom. The C(40)-O(8) bond length is 1.30 Å. The C(40)-O(9) bond length is 1.31 Å. There are eleven inequivalent H sites. In the first H site, H(21) is bonded in a single-bond geometry to one C(35) atom. In the second H site, H(22) is bonded in a single-bond geometry to one C(36) atom. In the third H site, H(23) is bonded in a single-bond geometry to one C(38) atom. In the fourth H site, H(24) is bonded in a single-bond geometry to one C(39) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(29) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(31) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(33) atom. There are five inequivalent O sites. In the first O site, O(10) is bonded in a tetrahedral geometry to one Zn(4) and three equivalent Zn(3) atoms. In the second O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(21) atom. In the third O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(21) atom. In the fourth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(40) atom. In the fifth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(40) atom. In the Zn4C57H33O13 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(3), and one O(5) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.86 Å. The Zn(1)-O(2) bond length is 1.97 Å. The Zn(1)-O(3) bond length is 1.97 Å. The Zn(1)-O(5) bond length is 1.95 Å. In the second Zn site, Zn(2) is bonded to one O(5) and three equivalent O(4) atoms to form corner-sharing ZnO4 trigonal pyramids. The Zn(2)-O(5) bond length is 1.97 Å. All Zn(2)-O(4) bond lengths are 1.97 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(3), one O(1), and one O(4) atom. The C(1)-C(3) bond length is 1.56 Å. The C(1)-O(1) bond length is 1.32 Å. The C(1)-O(4) bond length is 1.20 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(3) atom. The C(2)-C(4) bond length is 1.55 Å. The C(2)-O(2) bond length is 1.22 Å. The C(2)-O(3) bond length is 1.28 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(6) atom. The C(3)-C(5) bond length is 1.29 Å. The C(3)-C(6) bond length is 1.36 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(7), and one C(8) atom. The C(4)-C(7) bond length is 1.37 Å. The C(4)-C(8) bond length is 1.43 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(5)-H(1) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(10), one C(3), and one H(2) atom. The C(6)-C(10) bond length is 1.40 Å. The C(6)-H(2) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(7)-H(3) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(12), one C(4), and one H(4) atom. The C(8)-C(12) bond length is 1.34 Å. The C(8)-H(4) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(13) and one H(5) atom. The C(9)-C(13) bond length is 1.34 Å. The C(9)-H(5) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(13), one C(6), and one H(6) atom. The C(10)-C(13) bond length is 1.43 Å. The C(10)-H(6) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(14) and one H(7) atom. The C(11)-C(14) bond length is 1.39 Å. The C(11)-H(7) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14), one C(8), and one H(8) atom. The C(12)-C(14) bond length is 1.32 Å. The C(12)-H(8) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(10), one C(15), and one C(9) atom. The C(13)-C(15) bond length is 1.45 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(16) atom. The C(14)-C(16) bond length is 1.51 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(18) atom. The C(15)-C(17) bond length is 1.39 Å. The C(15)-C(18) bond length is 1.41 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(19) atom. The C(16)-C(18) bond length is 1.42 Å. The C(16)-C(19) bond length is 1.41 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one H(9) atom. The C(17)-H(9) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(15), one C(16), and one H(10) atom. The C(18)-H(10) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(19)-H(11) bond length is 0.93 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(1) atom. In the fifth O site, O(5) is bonded in a tetrahedral geometry to one Zn(2) and three equivalent Zn(1) atoms. Linkers: 36 [O]C(=O)c1ccc(-c2cccc(-c3ccc(C([O])=O)cc3)c2)cc1. Metal clusters: 12 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: pcu. The MOF has largest included sphere 11.86 A, density 0.65 g/cm3, surface area 4457.42 m2/g, accessible volume 1.19 cm3/g