ZnC11N3H9O4(CH)4C5H5N crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, four C5H5N clusters, and four ZnC11N3H9O4 clusters. In each C5H5N cluster, there are ten inequivalent C sites. In the first C site, C(4) is bonded in a trigonal planar geometry to one C(24), one C(33), and one C(63) atom. The C(4)-C(24) bond length is 1.49 Å. The C(4)-C(33) bond length is 1.38 Å. The C(4)-C(63) bond length is 1.38 Å. In the second C site, C(21) is bonded in a distorted trigonal planar geometry to one C(23), one C(31), and one N(14) atom. The C(21)-C(23) bond length is 1.49 Å. The C(21)-C(31) bond length is 1.48 Å. The C(21)-N(14) bond length is 1.29 Å. In the third C site, C(23) is bonded in a trigonal non-coplanar geometry to one C(21); one H(14); and two equivalent H(12,13) atoms. The C(23)-H(14) bond length is 0.96 Å. Both C(23)-H(12,13) bond lengths are 0.96 Å. In the fourth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(4), one C(69), and one N(16) atom. The C(24)-C(69) bond length is 1.49 Å. The C(24)-N(16) bond length is 1.27 Å. In the fifth C site, C(31) is bonded in a trigonal planar geometry to one C(21), one C(45), and one C(59) atom. The C(31)-C(45) bond length is 1.39 Å. The C(31)-C(59) bond length is 1.39 Å. In the sixth C site, C(33) is bonded in a distorted single-bond geometry to one C(4) and one H(20,43) atom. The C(33)-H(20,43) bond length is 0.93 Å. In the seventh C site, C(45) is bonded in a distorted single-bond geometry to one C(31) and one H(25,38) atom. The C(45)-H(25,38) bond length is 0.93 Å. In the eighth C site, C(59) is bonded in a distorted single-bond geometry to one C(31) and one H(25,38) atom. The C(59)-H(25,38) bond length is 0.93 Å. In the ninth C site, C(63) is bonded in a distorted single-bond geometry to one C(4) and one H(20,43) atom. The C(63)-H(20,43) bond length is 0.93 Å. In the tenth C site, C(69) is bonded in a trigonal non-coplanar geometry to one C(24), one H(49), one H(50), and one H(51) atom. The C(69)-H(49) bond length is 0.96 Å. The C(69)-H(50) bond length is 0.96 Å. The C(69)-H(51) bond length is 0.96 Å. There are two inequivalent N sites. In the first N site, N(14) is bonded in a distorted bent 120 degrees geometry to one C(21) and one N(16) atom. The N(14)-N(16) bond length is 1.39 Å. In the second N site, N(16) is bonded in a distorted bent 120 degrees geometry to one C(24) and one N(14) atom. There are seven inequivalent H sites. In the first H site, H(12,13) is bonded in a single-bond geometry to one C(23) atom. In the second H site, H(14) is bonded in a single-bond geometry to one C(23) atom. In the third H site, H(20,43) is bonded in a single-bond geometry to one C(33) atom. In the fourth H site, H(25,38) is bonded in a single-bond geometry to one C(45) atom. In the fifth H site, H(49) is bonded in a single-bond geometry to one C(69) atom. In the sixth H site, H(50) is bonded in a single-bond geometry to one C(69) atom. In the seventh H site, H(51) is bonded in a single-bond geometry to one C(69) atom. In each ZnC11N3H9O4 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted octahedral geometry to one N(2), one N(3), one O(13), one O(15), one O(2), and one O(8) atom. The Zn(1)-N(2) bond length is 2.15 Å. The Zn(1)-N(3) bond length is 2.18 Å. The Zn(1)-O(13) bond length is 2.02 Å. The Zn(1)-O(15) bond length is 2.12 Å. The Zn(1)-O(2) bond length is 2.36 Å. The Zn(1)-O(8) bond length is 2.01 Å. In the second Zn site, Zn(4) is bonded in a distorted trigonal bipyramidal geometry to one N(5), one N(6), one O(11), one O(4), and one O(7) atom. The Zn(4)-N(5) bond length is 2.15 Å. The Zn(4)-N(6) bond length is 2.15 Å. The Zn(4)-O(11) bond length is 2.04 Å. The Zn(4)-O(4) bond length is 2.02 Å. The Zn(4)-O(7) bond length is 2.06 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(25), one C(5), and one C(7) atom. The C(1)-C(25) bond length is 1.40 Å. The C(1)-C(5) bond length is 1.39 Å. The C(1)-C(7) bond length is 1.48 Å. In the second C site, C(5) is bonded in a distorted single-bond geometry to one C(1), one C(18), and one H(1) atom. The C(5)-C(18) bond length is 1.38 Å. The C(5)-H(1) bond length is 0.93 Å. In the third C site, C(7) is bonded in a distorted trigonal planar geometry to one C(1), one C(71), and one N(8) atom. The C(7)-C(71) bond length is 1.49 Å. The C(7)-N(8) bond length is 1.28 Å. In the fourth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(5), one N(5), and one H(8) atom. The C(18)-N(5) bond length is 1.35 Å. The C(18)-H(8) bond length is 0.93 Å. In the fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(1) and one H(15) atom. The C(25)-H(15) bond length is 0.93 Å. In the sixth C site, C(26) is bonded in a bent 120 degrees geometry to one O(15) and one O(2) atom. The C(26)-O(15) bond length is 1.27 Å. The C(26)-O(2) bond length is 1.24 Å. In the seventh C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(17) atom. The C(29)-N(5) bond length is 1.34 Å. The C(29)-H(17) bond length is 0.93 Å. In the eighth C site, C(41) is bonded in a 2-coordinate geometry to one N(2) and one H(24) atom. The C(41)-N(2) bond length is 1.34 Å. The C(41)-H(24) bond length is 0.93 Å. In the ninth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(13) atom. The C(42)-O(11) bond length is 1.25 Å. The C(42)-O(13) bond length is 1.26 Å. In the tenth C site, C(39) is bonded in a trigonal planar geometry to one C(51), one C(62), and one C(78) atom. The C(39)-C(51) bond length is 1.37 Å. The C(39)-C(62) bond length is 1.48 Å. The C(39)-C(78) bond length is 1.38 Å. In the eleventh C site, C(47) is bonded in a bent 120 degrees geometry to one O(10) and one O(7) atom. The C(47)-O(10) bond length is 1.25 Å. The C(47)-O(7) bond length is 1.26 Å. In the twelfth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(8) atom. The C(50)-O(4) bond length is 1.25 Å. The C(50)-O(8) bond length is 1.25 Å. In the thirteenth C site, C(51) is bonded in a distorted single-bond geometry to one C(39) and one H(29) atom. The C(51)-H(29) bond length is 0.93 Å. In the fourteenth C site, C(54) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(32) atom. The C(54)-N(3) bond length is 1.35 Å. The C(54)-H(32) bond length is 0.93 Å. In the fifteenth C site, C(57) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(34) atom. The C(57)-N(3) bond length is 1.33 Å. The C(57)-H(34) bond length is 0.93 Å. In the sixteenth C site, C(62) is bonded in a distorted trigonal planar geometry to one C(39), one C(77), and one N(7) atom. The C(62)-C(77) bond length is 1.50 Å. The C(62)-N(7) bond length is 1.27 Å. In the seventeenth C site, C(66) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(46) atom. The C(66)-N(2) bond length is 1.33 Å. The C(66)-H(46) bond length is 0.93 Å. In the eighteenth C site, C(73) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(57) atom. The C(73)-N(6) bond length is 1.33 Å. The C(73)-H(57) bond length is 0.93 Å. In the nineteenth C site, C(71) is bonded in a trigonal non-coplanar geometry to one C(7); one H(54); and two equivalent H(53,55) atoms. The C(71)-H(54) bond length is 0.96 Å. Both C(71)-H(53,55) bond lengths are 0.96 Å. In the twentieth C site, C(77) is bonded in a trigonal non-coplanar geometry to one C(62) and three equivalent H(65,66,67) atoms. All C(77)-H(65,66,67) bond lengths are 0.96 Å. In the twenty-first C site, C(80) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(70) atom. The C(80)-N(6) bond length is 1.32 Å. The C(80)-H(70) bond length is 0.93 Å. In the twenty-second C site, C(78) is bonded in a distorted single-bond geometry to one C(39) and one H(68) atom. The C(78)-H(68) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(41), and one C(66) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(54), and one C(57) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Zn(4), one C(18), and one C(29) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one Zn(4), one C(73), and one C(80) atom. In the fifth N site, N(7) is bonded in a distorted bent 120 degrees geometry to one C(62) and one N(8) atom. The N(7)-N(8) bond length is 1.38 Å. In the sixth N site, N(8) is bonded in a distorted bent 120 degrees geometry to one C(7) and one N(7) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(18) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(29) atom. In the fifth H site, H(24) is bonded in a single-bond geometry to one C(41) atom. In the sixth H site, H(29) is bonded in a single-bond geometry to one C(51) atom. In the seventh H site, H(32) is bonded in a single-bond geometry to one C(54) atom. In the eighth H site, H(34) is bonded in a single-bond geometry to one C(57) atom. In the ninth H site, H(46) is bonded in a single-bond geometry to one C(66) atom. In the tenth H site, H(57) is bonded in a single-bond geometry to one C(73) atom. In the eleventh H site, H(53,55) is bonded in a single-bond geometry to one C(71) atom. In the twelfth H site, H(54) is bonded in a single-bond geometry to one C(71) atom. In the thirteenth H site, H(65,66,67) is bonded in a single-bond geometry to one C(77) atom. In the fourteenth H site, H(68) is bonded in a single-bond geometry to one C(78) atom. In the fifteenth H site, H(70) is bonded in a single-bond geometry to one C(80) atom. There are eight inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one Zn(1) and one C(26) atom. In the second O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(4) and one C(50) atom. In the third O site, O(7) is bonded in a water-like geometry to one Zn(4) and one C(47) atom. In the fourth O site, O(8) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(50) atom. In the fifth O site, O(10) is bonded in a single-bond geometry to one C(47) atom. In the sixth O site, O(11) is bonded in a bent 150 degrees geometry to one Zn(4) and one C(42) atom. In the seventh O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(42) atom. In the eighth O site, O(15) is bonded in an L-shaped geometry to one Zn(1) and one C(26) atom. Linkers: 8 [O]C(=O)/C=C/C=C/C([O])=O ,4 C/C(=N\N=C(/C)c1ccncc1)c1ccncc1 ,4 C[C]([N]/N=C(\C)c1ccncc1)c1ccncc1. Metal clusters: 4 O=[C]O[Zn]1O[C]O[Zn](O[C]=O)O[C]O1. RCSR code: sql. The MOF has largest included sphere 5.08 A, density 1.24 g/cm3, surface area 4870.35 m2/g, accessible volume 0.42 cm3/g