(ZnC13NH8O4)2(CH)8C9H8O4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixty-four 02329_fluka molecules; eight 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and eight ZnC13NH8O4 clusters. In each ZnC13NH8O4 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one O(12), one O(2), one O(5), and one O(9) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(12) bond length is 2.06 Å. The Zn(1)-O(2) bond length is 2.00 Å. The Zn(1)-O(5) bond length is 2.08 Å. The Zn(1)-O(9) bond length is 2.01 Å. In the second Zn site, Zn(2) is bonded in a trigonal bipyramidal geometry to one N(2), one O(11), one O(3), one O(6), and one O(8) atom. The Zn(2)-N(2) bond length is 2.04 Å. The Zn(2)-O(11) bond length is 2.01 Å. The Zn(2)-O(3) bond length is 2.09 Å. The Zn(2)-O(6) bond length is 2.00 Å. The Zn(2)-O(8) bond length is 2.06 Å. There are twenty-six inequivalent C sites. In the first C site, C(5) is bonded in a single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(4) bond length is 0.93 Å. In the second C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-C(9) bond length is 1.48 Å. In the third C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 0.93 Å. In the fourth C site, C(9) is bonded in a bent 120 degrees geometry to one C(6), one O(2), and one O(3) atom. The C(9)-O(2) bond length is 1.24 Å. The C(9)-O(3) bond length is 1.26 Å. In the fifth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(10) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-H(10) bond length is 0.93 Å. In the sixth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(17) bond length is 1.49 Å. In the seventh C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(15)-H(11) bond length is 0.93 Å. In the eighth C site, C(17) is bonded in a bent 120 degrees geometry to one C(14), one O(5), and one O(6) atom. The C(17)-O(5) bond length is 1.25 Å. The C(17)-O(6) bond length is 1.27 Å. In the ninth C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(16) atom. The C(21)-C(22) bond length is 1.41 Å. The C(21)-H(16) bond length is 0.93 Å. In the tenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(25) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-C(25) bond length is 1.49 Å. In the eleventh C site, C(29) is bonded in a distorted single-bond geometry to one C(30) and one H(22) atom. The C(29)-C(30) bond length is 1.38 Å. The C(29)-H(22) bond length is 0.93 Å. In the twelfth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(33) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-C(33) bond length is 1.50 Å. In the thirteenth C site, C(31) is bonded in a single-bond geometry to one C(30) and one H(23) atom. The C(31)-H(23) bond length is 0.93 Å. In the fourteenth C site, C(33) is bonded in a bent 120 degrees geometry to one C(30), one O(11), and one O(12) atom. The C(33)-O(11) bond length is 1.27 Å. The C(33)-O(12) bond length is 1.26 Å. In the fifteenth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(25) atom. The C(34)-N(1) bond length is 1.35 Å. The C(34)-H(25) bond length is 0.93 Å. In the sixteenth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(28) atom. The C(38)-N(1) bond length is 1.34 Å. The C(38)-H(28) bond length is 0.93 Å. In the seventeenth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(29) atom. The C(39)-N(2) bond length is 1.35 Å. The C(39)-H(29) bond length is 0.93 Å. In the eighteenth C site, C(35) is bonded in a distorted single-bond geometry to one C(36) and one H(26) atom. The C(35)-C(36) bond length is 1.38 Å. The C(35)-H(26) bond length is 0.93 Å. In the nineteenth C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(41) atom. The C(36)-C(37) bond length is 1.41 Å. The C(36)-C(41) bond length is 1.47 Å. In the twentieth C site, C(37) is bonded in a distorted single-bond geometry to one C(36) and one H(27) atom. The C(37)-H(27) bond length is 0.93 Å. In the twenty-first C site, C(40) is bonded in a distorted single-bond geometry to one C(41) and one H(30) atom. The C(40)-C(41) bond length is 1.38 Å. The C(40)-H(30) bond length is 0.93 Å. In the twenty-second C site, C(41) is bonded in a trigonal planar geometry to one C(36), one C(40), and one C(42) atom. The C(41)-C(42) bond length is 1.38 Å. In the twenty-third C site, C(42) is bonded in a single-bond geometry to one C(41), one C(43), and one H(31) atom. The C(42)-C(43) bond length is 1.40 Å. The C(42)-H(31) bond length is 0.93 Å. In the twenty-fourth C site, C(43) is bonded in a distorted trigonal planar geometry to one C(42), one N(2), and one H(32) atom. The C(43)-N(2) bond length is 1.30 Å. The C(43)-H(32) bond length is 0.93 Å. In the twenty-fifth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(17) atom. The C(23)-H(17) bond length is 0.93 Å. In the twenty-sixth C site, C(25) is bonded in a bent 120 degrees geometry to one C(22), one O(8), and one O(9) atom. The C(25)-O(8) bond length is 1.26 Å. The C(25)-O(9) bond length is 1.25 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(34), and one C(38) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(39), and one C(43) atom. There are sixteen inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one C(29) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the ninth H site, H(25) is bonded in a single-bond geometry to one C(34) atom. In the tenth H site, H(26) is bonded in a single-bond geometry to one C(35) atom. In the eleventh H site, H(27) is bonded in a single-bond geometry to one C(37) atom. In the twelfth H site, H(28) is bonded in a single-bond geometry to one C(38) atom. In the thirteenth H site, H(29) is bonded in a single-bond geometry to one C(39) atom. In the fourteenth H site, H(32) is bonded in a single-bond geometry to one C(43) atom. In the fifteenth H site, H(31) is bonded in a single-bond geometry to one C(42) atom. In the sixteenth H site, H(30) is bonded in a single-bond geometry to one C(40) atom. There are eight inequivalent O sites. In the first O site, O(11) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(33) atom. In the second O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(33) atom. In the third O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(9) atom. In the sixth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(17) atom. In the seventh O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(17) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(25) atom. Linkers: 4 [O]C(=O)c1ccc(OCC(COc2ccc(C([O])=O)cc2)(COc2ccc(C([O])=O)cc2)COc2ccc(C([O])=O)cc2)cc1 ,2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3 ,4 [Zn]. The MOF has largest included sphere 7.45 A, density 1.01 g/cm3, surface area 4446.67 m2/g, accessible volume 0.53 cm3/g