Zn4C70N6H34O13(CH)14 crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of forty-four 02329_fluka molecules and four propylene molecules inside a Zn4C70N6H34O13 framework. In the Zn4C70N6H34O13 framework, there are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(13), one O(2), and one O(6) atom. The Zn(1)-O(1) bond length is 2.00 Å. The Zn(1)-O(13) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.06 Å. The Zn(1)-O(6) bond length is 2.09 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(11), one O(4), and one O(8) atom to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(1) bond length is 1.95 Å. The Zn(2)-O(11) bond length is 1.94 Å. The Zn(2)-O(4) bond length is 1.88 Å. The Zn(2)-O(8) bond length is 1.92 Å. In the third Zn site, Zn(3) is bonded to one O(1), one O(10), one O(5), and one O(7) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(1) bond length is 1.93 Å. The Zn(3)-O(10) bond length is 1.91 Å. The Zn(3)-O(5) bond length is 1.99 Å. The Zn(3)-O(7) bond length is 1.92 Å. In the fourth Zn site, Zn(4) is bonded to one O(1), one O(12), one O(3), and one O(9) atom to form corner-sharing ZnO4 tetrahedra. The Zn(4)-O(1) bond length is 1.92 Å. The Zn(4)-O(12) bond length is 1.90 Å. The Zn(4)-O(3) bond length is 1.92 Å. The Zn(4)-O(9) bond length is 1.92 Å. There are seventy inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(4) atom. The C(1)-C(2) bond length is 1.56 Å. The C(1)-O(2) bond length is 1.27 Å. The C(1)-O(4) bond length is 1.23 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(14), one C(2), and one H(1) atom. The C(3)-C(14) bond length is 1.39 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(14), one C(5), and one C(7) atom. The C(4)-C(14) bond length is 1.37 Å. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(7) bond length is 1.58 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(5)-H(2) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(4), and one C(8) atom. The C(7)-C(12) bond length is 1.39 Å. The C(7)-C(8) bond length is 1.38 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(3) atom. The C(8)-C(9) bond length is 1.32 Å. The C(8)-N(3) bond length is 1.44 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(4) atom. The C(9)-C(10) bond length is 1.42 Å. The C(9)-H(4) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(13) bond length is 1.50 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(5) atom. The C(11)-C(12) bond length is 1.34 Å. The C(11)-H(5) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(7), and one H(6) atom. The C(12)-H(6) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(3), and one O(5) atom. The C(13)-O(3) bond length is 1.29 Å. The C(13)-O(5) bond length is 1.24 Å. In the fourteenth C site, C(14) is bonded in a distorted trigonal planar geometry to one C(3), one C(4), and one N(1) atom. The C(14)-N(1) bond length is 1.42 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one C(22), and one N(1) atom. The C(15)-C(16) bond length is 1.49 Å. The C(15)-C(22) bond length is 1.55 Å. The C(15)-N(1) bond length is 1.32 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-C(21) bond length is 1.39 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(7) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(7) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one H(8) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(8) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(9) atom. The C(19)-H(9) bond length is 0.93 Å. In the twentieth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(21)-H(11) bond length is 0.93 Å. In the twenty-first C site, C(22) is bonded in a distorted single-bond geometry to one C(15), one C(23), and one N(3) atom. The C(22)-C(23) bond length is 1.54 Å. The C(22)-N(3) bond length is 1.25 Å. In the twenty-second C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-C(28) bond length is 1.39 Å. In the twenty-third C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(12) atom. The C(24)-H(12) bond length is 0.93 Å. In the twenty-fourth C site, C(28) is bonded in a distorted single-bond geometry to one C(23) and one H(16) atom. The C(28)-H(16) bond length is 0.93 Å. In the twenty-fifth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(30), one O(6), and one O(7) atom. The C(29)-C(30) bond length is 1.56 Å. The C(29)-O(6) bond length is 1.21 Å. The C(29)-O(7) bond length is 1.27 Å. In the twenty-sixth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(35) atom. The C(30)-C(31) bond length is 1.45 Å. The C(30)-C(35) bond length is 1.37 Å. In the twenty-seventh C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(17) atom. The C(31)-H(17) bond length is 0.93 Å. In the twenty-eighth C site, C(32) is bonded in a single-bond geometry to one C(33) and one H(18) atom. The C(32)-C(33) bond length is 1.43 Å. The C(32)-H(18) bond length is 0.93 Å. In the twenty-ninth C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(36) atom. The C(33)-C(34) bond length is 1.44 Å. The C(33)-C(36) bond length is 1.45 Å. In the thirtieth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(33), one C(35), and one N(4) atom. The C(34)-C(35) bond length is 1.32 Å. The C(34)-N(4) bond length is 1.45 Å. In the thirty-first C site, C(35) is bonded in a distorted single-bond geometry to one C(30), one C(34), and one H(19) atom. The C(35)-H(19) bond length is 0.93 Å. In the thirty-second C site, C(36) is bonded in a trigonal planar geometry to one C(33), one C(37), and one C(41) atom. The C(36)-C(37) bond length is 1.40 Å. The C(36)-C(41) bond length is 1.38 Å. In the thirty-third C site, C(37) is bonded in a distorted single-bond geometry to one C(36), one C(38), and one H(20) atom. The C(37)-C(38) bond length is 1.35 Å. The C(37)-H(20) bond length is 0.93 Å. In the thirty-fourth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(37), one C(39), and one H(21) atom. The C(38)-C(39) bond length is 1.37 Å. The C(38)-H(21) bond length is 0.93 Å. In the thirty-fifth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(56) atom. The C(39)-C(40) bond length is 1.35 Å. The C(39)-C(56) bond length is 1.58 Å. In the thirty-sixth C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one H(22) atom. The C(40)-H(22) bond length is 0.93 Å. In the thirty-seventh C site, C(41) is bonded in a distorted single-bond geometry to one C(36) and one N(5) atom. The C(41)-N(5) bond length is 1.40 Å. In the thirty-eighth C site, C(42) is bonded in a distorted single-bond geometry to one C(43), one C(49), and one N(4) atom. The C(42)-C(43) bond length is 1.50 Å. The C(42)-C(49) bond length is 1.44 Å. The C(42)-N(4) bond length is 1.26 Å. In the thirty-ninth C site, C(43) is bonded in a trigonal planar geometry to one C(42), one C(44), and one C(48) atom. The C(43)-C(44) bond length is 1.39 Å. The C(43)-C(48) bond length is 1.39 Å. In the fortieth C site, C(44) is bonded in a distorted single-bond geometry to one C(43) and one H(23,27) atom. The C(44)-H(23,27) bond length is 0.93 Å. In the forty-first C site, C(48) is bonded in a distorted single-bond geometry to one C(43) and one H(23,27) atom. The C(48)-H(23,27) bond length is 0.93 Å. In the forty-second C site, C(49) is bonded in a distorted trigonal planar geometry to one C(42), one C(50), and one N(5) atom. The C(49)-C(50) bond length is 1.52 Å. The C(49)-N(5) bond length is 1.35 Å. In the forty-third C site, C(50) is bonded in a trigonal planar geometry to one C(49), one C(51), and one C(55) atom. The C(50)-C(51) bond length is 1.39 Å. The C(50)-C(55) bond length is 1.39 Å. In the forty-fourth C site, C(51) is bonded in a distorted single-bond geometry to one C(50) and one H(28) atom. The C(51)-H(28) bond length is 0.93 Å. In the forty-fifth C site, C(55) is bonded in a distorted single-bond geometry to one C(50) and one H(32) atom. The C(55)-H(32) bond length is 0.93 Å. In the forty-sixth C site, C(56) is bonded in a distorted bent 120 degrees geometry to one C(39), one O(8), and one O(9) atom. The C(56)-O(8) bond length is 1.28 Å. The C(56)-O(9) bond length is 1.24 Å. In the forty-seventh C site, C(57) is bonded in a distorted bent 120 degrees geometry to one C(58), one O(10), and one O(11) atom. The C(57)-C(58) bond length is 1.58 Å. The C(57)-O(10) bond length is 1.27 Å. The C(57)-O(11) bond length is 1.27 Å. In the forty-eighth C site, C(58) is bonded in a trigonal planar geometry to one C(57), one C(59), and one C(62) atom. The C(58)-C(59) bond length is 1.35 Å. The C(58)-C(62) bond length is 1.42 Å. In the forty-ninth C site, C(59) is bonded in a distorted trigonal planar geometry to one C(58), one C(60), and one H(33) atom. The C(59)-C(60) bond length is 1.37 Å. The C(59)-H(33) bond length is 0.93 Å. In the fiftieth C site, C(60) is bonded in a distorted single-bond geometry to one C(59), one C(61), and one H(34) atom. The C(60)-C(61) bond length is 1.45 Å. The C(60)-H(34) bond length is 0.93 Å. In the fifty-first C site, C(61) is bonded in a trigonal planar geometry to one C(60), one C(63), and one C(77) atom. The C(61)-C(63) bond length is 1.42 Å. The C(61)-C(77) bond length is 1.40 Å. In the fifty-second C site, C(62) is bonded in a distorted single-bond geometry to one C(58), one C(77), and one H(35) atom. The C(62)-C(77) bond length is 1.34 Å. The C(62)-H(35) bond length is 0.93 Å. In the fifty-third C site, C(63) is bonded in a trigonal planar geometry to one C(61), one C(64), and one C(65) atom. The C(63)-C(64) bond length is 1.35 Å. The C(63)-C(65) bond length is 1.35 Å. In the fifty-fourth C site, C(64) is bonded in a distorted single-bond geometry to one C(63), one C(66), and one H(36) atom. The C(64)-C(66) bond length is 1.36 Å. The C(64)-H(36) bond length is 0.93 Å. In the fifty-fifth C site, C(65) is bonded in a distorted trigonal planar geometry to one C(63), one C(67), and one N(6) atom. The C(65)-C(67) bond length is 1.39 Å. The C(65)-N(6) bond length is 1.45 Å. In the fifty-sixth C site, C(66) is bonded in a distorted trigonal planar geometry to one C(64), one C(68), and one H(37) atom. The C(66)-C(68) bond length is 1.40 Å. The C(66)-H(37) bond length is 0.93 Å. In the fifty-seventh C site, C(67) is bonded in a distorted single-bond geometry to one C(65), one C(68), and one H(38) atom. The C(67)-C(68) bond length is 1.36 Å. The C(67)-H(38) bond length is 0.93 Å. In the fifty-eighth C site, C(68) is bonded in a trigonal planar geometry to one C(66), one C(67), and one C(69) atom. The C(68)-C(69) bond length is 1.54 Å. In the fifty-ninth C site, C(69) is bonded in a distorted bent 120 degrees geometry to one C(68), one O(12), and one O(13) atom. The C(69)-O(12) bond length is 1.31 Å. The C(69)-O(13) bond length is 1.20 Å. In the sixtieth C site, C(70) is bonded in a 3-coordinate geometry to one C(72), one C(78), and one N(6) atom. The C(70)-C(72) bond length is 1.60 Å. The C(70)-C(78) bond length is 1.21 Å. The C(70)-N(6) bond length is 1.42 Å. In the sixty-first C site, C(71) is bonded in a distorted single-bond geometry to one C(72), one C(76), and one H(39) atom. The C(71)-C(72) bond length is 1.39 Å. The C(71)-C(76) bond length is 1.39 Å. The C(71)-H(39) bond length is 0.93 Å. In the sixty-second C site, C(72) is bonded in a trigonal planar geometry to one C(70), one C(71), and one C(73) atom. The C(72)-C(73) bond length is 1.39 Å. In the sixty-third C site, C(73) is bonded in a distorted single-bond geometry to one C(72) and one H(40) atom. The C(73)-H(40) bond length is 0.93 Å. In the sixty-fourth C site, C(75) is bonded in a single-bond geometry to one C(76) and one H(42) atom. The C(75)-C(76) bond length is 1.39 Å. The C(75)-H(42) bond length is 0.93 Å. In the sixty-fifth C site, C(76) is bonded in a distorted trigonal planar geometry to one C(71), one C(75), and one H(43) atom. The C(76)-H(43) bond length is 0.93 Å. In the sixty-sixth C site, C(77) is bonded in a distorted trigonal planar geometry to one C(61), one C(62), and one N(2) atom. The C(77)-N(2) bond length is 1.41 Å. In the sixty-seventh C site, C(78) is bonded in a 3-coordinate geometry to one C(70), one C(79), and one N(2) atom. The C(78)-C(79) bond length is 1.49 Å. The C(78)-N(2) bond length is 1.34 Å. In the sixty-eighth C site, C(79) is bonded in a trigonal planar geometry to one C(78), one C(80), and one C(84) atom. The C(79)-C(80) bond length is 1.40 Å. The C(79)-C(84) bond length is 1.35 Å. In the sixty-ninth C site, C(80) is bonded in a distorted single-bond geometry to one C(79) and one H(44) atom. The C(80)-H(44) bond length is 0.93 Å. In the seventieth C site, C(84) is bonded in a distorted single-bond geometry to one C(79) and one H(48) atom. The C(84)-H(48) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(14) and one C(15) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(77) and one C(78) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(22) and one C(8) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(34) and one C(42) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(41) and one C(49) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one C(65) and one C(70) atom. There are thirty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(24) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(28) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(32) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(35) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(37) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(38) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(40) atom. In the nineteenth H site, H(23,27) is bonded in a single-bond geometry to one C(44) atom. In the twentieth H site, H(28) is bonded in a single-bond geometry to one C(51) atom. In the twenty-first H site, H(32) is bonded in a single-bond geometry to one C(55) atom. In the twenty-second H site, H(33) is bonded in a single-bond geometry to one C(59) atom. In the twenty-third H site, H(34) is bonded in a single-bond geometry to one C(60) atom. In the twenty-fourth H site, H(35) is bonded in a single-bond geometry to one C(62) atom. In the twenty-fifth H site, H(36) is bonded in a single-bond geometry to one C(64) atom. In the twenty-sixth H site, H(37) is bonded in a single-bond geometry to one C(66) atom. In the twenty-seventh H site, H(38) is bonded in a single-bond geometry to one C(67) atom. In the twenty-eighth H site, H(39) is bonded in a single-bond geometry to one C(71) atom. In the twenty-ninth H site, H(40) is bonded in a single-bond geometry to one C(73) atom. In the thirtieth H site, H(42) is bonded in a single-bond geometry to one C(75) atom. In the thirty-first H site, H(43) is bonded in a single-bond geometry to one C(76) atom. In the thirty-second H site, H(44) is bonded in a single-bond geometry to one C(80) atom. In the thirty-third H site, H(48) is bonded in a single-bond geometry to one C(84) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a tetrahedral geometry to one Zn(1), one Zn(2), one Zn(3), and one Zn(4) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(13) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(13) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(29) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(29) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(56) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(56) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(57) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(57) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(69) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(69) atom. Linkers: 4 [O]C(=O)c1ccc2c(c1)[N][C](c1ccccc1)[C](c1ccccc1)[N]c1cc(C([O])=O)ccc1-2 ,8 [O]C(=O)c1ccc2c(c1)N=C(c1ccccc1)C(c1ccccc1)=Nc1cc(C([O])=O)ccc1-2. Metal clusters: 4 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: bsn. The MOF has largest included sphere 9.59 A, density 0.59 g/cm3, surface area 4650.53 m2/g, accessible volume 1.29 cm3/g