Zn4C30H18S6O13 crystallizes in the orthorhombic Pna2_1 space group. The structure consists of a Zn4C30H18S6O13 framework. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(12), one O(3), and one O(4) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.93 Å. The Zn(1)-O(12) bond length is 2.00 Å. The Zn(1)-O(3) bond length is 1.98 Å. The Zn(1)-O(4) bond length is 1.94 Å. In the second Zn site, Zn(2) is bonded in a 4-coordinate geometry to one O(1), one O(5), one O(6), and one O(8) atom. The Zn(2)-O(1) bond length is 1.96 Å. The Zn(2)-O(5) bond length is 2.20 Å. The Zn(2)-O(6) bond length is 1.93 Å. The Zn(2)-O(8) bond length is 2.34 Å. In the third Zn site, Zn(3) is bonded to one O(1), one O(10), one O(13), and one O(9) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3)-O(1) bond length is 1.89 Å. The Zn(3)-O(10) bond length is 1.92 Å. The Zn(3)-O(13) bond length is 2.03 Å. The Zn(3)-O(9) bond length is 1.94 Å. In the fourth Zn site, Zn(4) is bonded in a rectangular see-saw-like geometry to one O(1), one O(11), one O(2), and one O(7) atom. The Zn(4)-O(1) bond length is 2.07 Å. The Zn(4)-O(11) bond length is 2.13 Å. The Zn(4)-O(2) bond length is 2.08 Å. The Zn(4)-O(7) bond length is 2.06 Å. There are thirty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(3) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(2) bond length is 1.22 Å. The C(1)-O(3) bond length is 1.31 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one S(1) atom. The C(2)-C(3) bond length is 1.44 Å. The C(2)-S(1) bond length is 1.76 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(21), and one C(4) atom. The C(3)-C(21) bond length is 1.43 Å. The C(3)-C(4) bond length is 1.42 Å. In the fourth C site, C(4) is bonded in a trigonal non-coplanar geometry to one C(3), one H(1), one H(2), and one H(3) atom. The C(4)-H(1) bond length is 0.96 Å. The C(4)-H(2) bond length is 0.96 Å. The C(4)-H(3) bond length is 0.96 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(4), and one O(5) atom. The C(5)-C(6) bond length is 1.49 Å. The C(5)-O(4) bond length is 1.23 Å. The C(5)-O(5) bond length is 1.20 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one S(2) atom. The C(6)-C(7) bond length is 1.41 Å. The C(6)-S(2) bond length is 1.74 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(6), and one C(8) atom. The C(7)-C(12) bond length is 1.49 Å. The C(7)-C(8) bond length is 1.44 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.44 Å. The C(8)-C(9) bond length is 1.38 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(8), one S(2), and one S(3) atom. The C(9)-S(2) bond length is 1.74 Å. The C(9)-S(3) bond length is 1.70 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(8) atom. The C(10)-C(11) bond length is 1.34 Å. The C(10)-C(13) bond length is 1.52 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(30), and one S(3) atom. The C(11)-C(30) bond length is 1.40 Å. The C(11)-S(3) bond length is 1.76 Å. In the twelfth C site, C(12) is bonded in a trigonal non-coplanar geometry to one C(7); one H(4); and two equivalent H(5,6) atoms. The C(12)-H(4) bond length is 0.96 Å. Both C(12)-H(5,6) bond lengths are 0.96 Å. In the thirteenth C site, C(13) is bonded in a trigonal non-coplanar geometry to one C(10); one H(8); and two equivalent H(7,9) atoms. The C(13)-H(8) bond length is 0.96 Å. Both C(13)-H(7,9) bond lengths are 0.96 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(6), and one O(7) atom. The C(14)-C(15) bond length is 1.51 Å. The C(14)-O(6) bond length is 1.28 Å. The C(14)-O(7) bond length is 1.27 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one S(4) atom. The C(15)-C(16) bond length is 1.35 Å. The C(15)-S(4) bond length is 1.77 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one C(27) atom. The C(16)-C(17) bond length is 1.47 Å. The C(16)-C(27) bond length is 1.44 Å. In the seventeenth C site, C(17) is bonded in a trigonal non-coplanar geometry to one C(16), one H(10), one H(11), and one H(12) atom. The C(17)-H(10) bond length is 0.96 Å. The C(17)-H(11) bond length is 0.96 Å. The C(17)-H(12) bond length is 0.96 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(8), and one O(9) atom. The C(18)-C(19) bond length is 1.45 Å. The C(18)-O(8) bond length is 1.19 Å. The C(18)-O(9) bond length is 1.30 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one S(5) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-S(5) bond length is 1.76 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(23) atom. The C(20)-C(21) bond length is 1.43 Å. The C(20)-C(23) bond length is 1.40 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(3) atom. The C(21)-C(22) bond length is 1.33 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one S(1), and one S(5) atom. The C(22)-S(1) bond length is 1.78 Å. The C(22)-S(5) bond length is 1.72 Å. In the twenty-third C site, C(23) is bonded in a trigonal non-coplanar geometry to one C(20), one H(13), one H(14), and one H(15) atom. The C(23)-H(13) bond length is 0.96 Å. The C(23)-H(14) bond length is 0.96 Å. The C(23)-H(15) bond length is 0.96 Å. In the twenty-fourth C site, C(24) is bonded in a bent 120 degrees geometry to one C(25), one O(10), and one O(11) atom. The C(24)-C(25) bond length is 1.48 Å. The C(24)-O(10) bond length is 1.39 Å. The C(24)-O(11) bond length is 1.21 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one S(6) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-S(6) bond length is 1.71 Å. In the twenty-sixth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(29) atom. The C(26)-C(27) bond length is 1.42 Å. The C(26)-C(29) bond length is 1.56 Å. In the twenty-seventh C site, C(27) is bonded in a trigonal planar geometry to one C(16), one C(26), and one C(28) atom. The C(27)-C(28) bond length is 1.38 Å. In the twenty-eighth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one S(4), and one S(6) atom. The C(28)-S(4) bond length is 1.73 Å. The C(28)-S(6) bond length is 1.68 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal non-coplanar geometry to one C(26); one H(17); and two equivalent H(16,18) atoms. The C(29)-H(17) bond length is 0.96 Å. Both C(29)-H(16,18) bond lengths are 0.96 Å. In the thirtieth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(12), and one O(13) atom. The C(30)-O(12) bond length is 1.34 Å. The C(30)-O(13) bond length is 1.25 Å. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(7,9) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(16,18) is bonded in a single-bond geometry to one C(29) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(29) atom. There are six inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(2) and one C(22) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one C(6) and one C(9) atom. In the third S site, S(3) is bonded in an L-shaped geometry to one C(11) and one C(9) atom. In the fourth S site, S(4) is bonded in an L-shaped geometry to one C(15) and one C(28) atom. In the fifth S site, S(5) is bonded in an L-shaped geometry to one C(19) and one C(22) atom. In the sixth S site, S(6) is bonded in an L-shaped geometry to one C(25) and one C(28) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a tetrahedral geometry to one Zn(1), one Zn(2), one Zn(3), and one Zn(4) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Zn(2) and one C(5) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(14) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(14) atom. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(18) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(18) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(24) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(24) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(30) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(30) atom. Linkers: 12 Cc1c(C([O])=O)sc2sc(C([O])=O)c(C)c12. Metal clusters: 2 O=[C]O[Zn@]12O[C]O[Zn]3O[C]O[Zn]O[C]O[Zn@@](O[C]O3)(O[C]O1)O2 ,2 O=[C]O[Zn@@]12O[C]O[Zn]3O[C]O[Zn]O[C]O[Zn@](O[C]O3)(O[C]O1)O2. RCSR code: pcu. The MOF has largest included sphere 6.01 A, density 1.19 g/cm3, surface area 3776.35 m2/g, accessible volume 0.50 cm3/g