(ZnC22H14(NO2)3)2(CH)16(C2O)3 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixty-four 02329_fluka molecules, twelve dimethyl ether molecules, and eight ZnC22H14(NO2)3 clusters. In each ZnC22H14(NO2)3 cluster, Zn(1) is bonded in a distorted octahedral geometry to one N(1), one N(3), one O(4), one O(5), one O(6), and one O(7) atom. The Zn(1)-N(1) bond length is 2.33 Å. The Zn(1)-N(3) bond length is 2.07 Å. The Zn(1)-O(4) bond length is 2.02 Å. The Zn(1)-O(5) bond length is 2.00 Å. The Zn(1)-O(6) bond length is 2.33 Å. The Zn(1)-O(7) bond length is 2.12 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(16), one C(22), and one C(33) atom. The C(1)-C(16) bond length is 1.39 Å. The C(1)-C(22) bond length is 1.38 Å. The C(1)-C(33) bond length is 1.48 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(10), one C(21), and one C(27) atom. The C(2)-C(10) bond length is 1.38 Å. The C(2)-C(21) bond length is 1.38 Å. The C(2)-C(27) bond length is 1.50 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(20), one C(5), and one C(8) atom. The C(4)-C(20) bond length is 1.39 Å. The C(4)-C(5) bond length is 1.38 Å. The C(4)-C(8) bond length is 1.50 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(1) atom. The C(5)-H(1) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(29) and one H(2) atom. The C(6)-C(29) bond length is 1.38 Å. The C(6)-H(2) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(11), one C(24), and one N(1) atom. The C(7)-C(11) bond length is 1.46 Å. The C(7)-C(24) bond length is 1.38 Å. The C(7)-N(1) bond length is 1.35 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(2), and one O(5) atom. The C(8)-O(2) bond length is 1.24 Å. The C(8)-O(5) bond length is 1.26 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(10)-H(4) bond length is 0.93 Å. In the ninth C site, C(11) is bonded in a distorted water-like geometry to one C(7), one N(2), and one N(3) atom. The C(11)-N(2) bond length is 1.36 Å. The C(11)-N(3) bond length is 1.33 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(29) and one H(5) atom. The C(13)-C(29) bond length is 1.37 Å. The C(13)-H(5) bond length is 0.93 Å. In the eleventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(7) atom. The C(15)-N(1) bond length is 1.34 Å. The C(15)-H(7) bond length is 0.93 Å. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(1) and one H(8) atom. The C(16)-H(8) bond length is 0.93 Å. In the thirteenth C site, C(17) is bonded in a 3-coordinate geometry to one C(30), one N(2), and one H(9) atom. The C(17)-C(30) bond length is 1.36 Å. The C(17)-N(2) bond length is 1.37 Å. The C(17)-H(9) bond length is 0.93 Å. In the fourteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(4) and one H(11) atom. The C(20)-H(11) bond length is 0.93 Å. In the fifteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(2) and one H(12) atom. The C(21)-H(12) bond length is 0.93 Å. In the sixteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(1) and one H(13) atom. The C(22)-H(13) bond length is 0.93 Å. In the seventeenth C site, C(24) is bonded in a distorted single-bond geometry to one C(7) and one H(15) atom. The C(24)-H(15) bond length is 0.93 Å. In the eighteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(4) atom. The C(27)-O(1) bond length is 1.25 Å. The C(27)-O(4) bond length is 1.26 Å. In the nineteenth C site, C(28) is bonded in a 3-coordinate geometry to one C(29); one N(2); and two equivalent H(18,19) atoms. The C(28)-C(29) bond length is 1.51 Å. The C(28)-N(2) bond length is 1.48 Å. Both C(28)-H(18,19) bond lengths are 0.97 Å. In the twentieth C site, C(29) is bonded in a trigonal planar geometry to one C(13), one C(28), and one C(6) atom. In the twenty-first C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(3), and one H(20) atom. The C(30)-N(3) bond length is 1.36 Å. The C(30)-H(20) bond length is 0.93 Å. In the twenty-second C site, C(33) is bonded in a bent 120 degrees geometry to one C(1), one O(6), and one O(7) atom. The C(33)-O(6) bond length is 1.26 Å. The C(33)-O(7) bond length is 1.25 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(15), and one C(7) atom. In the second N site, N(3) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(11), and one C(30) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one C(11), one C(17), and one C(28) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(24) atom. In the twelfth H site, H(18,19) is bonded in a single-bond geometry to one C(28) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(30) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(27) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(8) atom. In the third O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(27) atom. In the fourth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the fifth O site, O(6) is bonded in a distorted L-shaped geometry to one Zn(1) and one C(33) atom. In the sixth O site, O(7) is bonded in an L-shaped geometry to one Zn(1) and one C(33) atom. Linkers: 4 [C]N(C=[CH])Cc1ccc(Cn2ccnc2-c2ccccn2)cc1 ,2 c1ccc(-c2nccn2Cc2ccc(Cn3ccnc3-c3ccccn3)cc2)nc1 ,6 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 O=[C]O[Zn]1(O[C]=O)O[C]O1. The MOF has largest included sphere 4.79 A, density 1.34 g/cm3, surface area 4846.35 m2/g, accessible volume 0.25 cm3/g