Mn3H16(C7O3)4(CH)8(C5H5O)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, four schembl9685153 molecules, and two Mn3H16(C7O3)4 clusters. In each Mn3H16(C7O3)4 cluster, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted T-shaped geometry to one O(13), one O(16), and one O(18) atom. The Mn(1)-O(13) bond length is 2.12 Å. The Mn(1)-O(16) bond length is 2.07 Å. The Mn(1)-O(18) bond length is 2.25 Å. In the second Mn site, Mn(3) is bonded in a distorted octahedral geometry to one O(10), one O(12), one O(18), one O(6), one O(8), and one O(9) atom. The Mn(3)-O(10) bond length is 2.12 Å. The Mn(3)-O(12) bond length is 2.17 Å. The Mn(3)-O(18) bond length is 2.31 Å. The Mn(3)-O(6) bond length is 2.13 Å. The Mn(3)-O(8) bond length is 2.11 Å. The Mn(3)-O(9) bond length is 2.47 Å. In the third Mn site, Mn(2) is bonded in a 5-coordinate geometry to one O(11), one O(15), one O(17), one O(6), and one O(9) atom. The Mn(2)-O(11) bond length is 2.20 Å. The Mn(2)-O(15) bond length is 2.08 Å. The Mn(2)-O(17) bond length is 2.15 Å. The Mn(2)-O(6) bond length is 2.72 Å. The Mn(2)-O(9) bond length is 2.24 Å. There are twenty-eight inequivalent C sites. In the first C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(50), and one C(65) atom. The C(16)-C(15) bond length is 1.42 Å. The C(16)-C(50) bond length is 1.50 Å. The C(16)-C(65) bond length is 1.35 Å. In the second C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(29) atom. The C(15)-H(29) bond length is 0.93 Å. In the third C site, C(24) is bonded in a distorted single-bond geometry to one C(51) and one H(22) atom. The C(24)-C(51) bond length is 1.37 Å. The C(24)-H(22) bond length is 0.93 Å. In the fourth C site, C(22) is bonded in a trigonal planar geometry to one C(5), one C(58), and one C(64) atom. The C(22)-C(5) bond length is 1.39 Å. The C(22)-C(58) bond length is 1.51 Å. The C(22)-C(64) bond length is 1.39 Å. In the fifth C site, C(27) is bonded in a distorted single-bond geometry to one C(43) and one H(47) atom. The C(27)-C(43) bond length is 1.39 Å. The C(27)-H(47) bond length is 0.93 Å. In the sixth C site, C(25) is bonded in a distorted single-bond geometry to one C(57) and one H(16) atom. The C(25)-C(57) bond length is 1.35 Å. The C(25)-H(16) bond length is 0.93 Å. In the seventh C site, C(31) is bonded in a trigonal planar geometry to one C(33), one C(40), and one C(66) atom. The C(31)-C(33) bond length is 1.39 Å. The C(31)-C(40) bond length is 1.52 Å. The C(31)-C(66) bond length is 1.37 Å. In the eighth C site, C(33) is bonded in a distorted single-bond geometry to one C(31) and one H(53) atom. The C(33)-H(53) bond length is 0.93 Å. In the ninth C site, C(40) is bonded in a bent 120 degrees geometry to one C(31), one O(12), and one O(17) atom. The C(40)-O(12) bond length is 1.27 Å. The C(40)-O(17) bond length is 1.25 Å. In the tenth C site, C(41) is bonded in a distorted single-bond geometry to one C(65) and one H(34) atom. The C(41)-C(65) bond length is 1.41 Å. The C(41)-H(34) bond length is 0.93 Å. In the eleventh C site, C(43) is bonded in a distorted trigonal planar geometry to one C(27), one C(52), and one H(20) atom. The C(43)-C(52) bond length is 1.39 Å. The C(43)-H(20) bond length is 0.93 Å. In the twelfth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(10), and one O(16) atom. The C(50)-O(10) bond length is 1.22 Å. The C(50)-O(16) bond length is 1.29 Å. In the thirteenth C site, C(51) is bonded in a trigonal planar geometry to one C(24), one C(60), and one C(61) atom. The C(51)-C(60) bond length is 1.38 Å. The C(51)-C(61) bond length is 1.50 Å. In the fourteenth C site, C(52) is bonded in a trigonal planar geometry to one C(43), one C(59), and one C(9) atom. The C(52)-C(59) bond length is 1.40 Å. The C(52)-C(9) bond length is 1.49 Å. In the fifteenth C site, C(49) is bonded in a distorted single-bond geometry to one C(7) and one H(12) atom. The C(49)-C(7) bond length is 1.35 Å. The C(49)-H(12) bond length is 0.93 Å. In the sixteenth C site, C(58) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(11), and one O(6) atom. The C(58)-O(11) bond length is 1.26 Å. The C(58)-O(6) bond length is 1.24 Å. In the seventeenth C site, C(59) is bonded in a distorted single-bond geometry to one C(52) and one H(38) atom. The C(59)-H(38) bond length is 0.93 Å. In the eighteenth C site, C(60) is bonded in a distorted trigonal planar geometry to one C(3), one C(51), and one H(17) atom. The C(60)-C(3) bond length is 1.43 Å. The C(60)-H(17) bond length is 0.93 Å. In the nineteenth C site, C(61) is bonded in a distorted bent 120 degrees geometry to one C(51), one O(13), and one O(8) atom. The C(61)-O(13) bond length is 1.25 Å. The C(61)-O(8) bond length is 1.27 Å. In the twentieth C site, C(57) is bonded in a trigonal planar geometry to one C(1), one C(25), and one C(7) atom. The C(57)-C(1) bond length is 1.52 Å. The C(57)-C(7) bond length is 1.40 Å. In the twenty-first C site, C(64) is bonded in a distorted single-bond geometry to one C(22) and one H(18,43) atom. The C(64)-H(18,43) bond length is 0.93 Å. In the twenty-second C site, C(65) is bonded in a distorted single-bond geometry to one C(16), one C(41), and one H(24) atom. The C(65)-H(24) bond length is 0.93 Å. In the twenty-third C site, C(66) is bonded in a distorted single-bond geometry to one C(31) and one H(50) atom. The C(66)-H(50) bond length is 0.93 Å. In the twenty-fourth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(57), one O(15), and one O(2) atom. The C(1)-O(15) bond length is 1.22 Å. The C(1)-O(2) bond length is 1.22 Å. In the twenty-fifth C site, C(3) is bonded in a distorted single-bond geometry to one C(60) and one H(37) atom. The C(3)-H(37) bond length is 0.93 Å. In the twenty-sixth C site, C(5) is bonded in a single-bond geometry to one C(22) and one H(18,43) atom. The C(5)-H(18,43) bond length is 0.93 Å. In the twenty-seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(49), one C(57), and one H(7) atom. The C(7)-H(7) bond length is 0.93 Å. In the twenty-eighth C site, C(9) is bonded in a bent 120 degrees geometry to one C(52), one O(18), and one O(9) atom. The C(9)-O(18) bond length is 1.25 Å. The C(9)-O(9) bond length is 1.26 Å. There are fifteen inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(49) atom. In the third H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(60) atom. In the fifth H site, H(18,43) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(20) is bonded in a single-bond geometry to one C(43) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(24) is bonded in a single-bond geometry to one C(65) atom. In the ninth H site, H(29) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(34) is bonded in a single-bond geometry to one C(41) atom. In the eleventh H site, H(37) is bonded in a single-bond geometry to one C(3) atom. In the twelfth H site, H(38) is bonded in a single-bond geometry to one C(59) atom. In the thirteenth H site, H(47) is bonded in a single-bond geometry to one C(27) atom. In the fourteenth H site, H(50) is bonded in a single-bond geometry to one C(66) atom. In the fifteenth H site, H(53) is bonded in a single-bond geometry to one C(33) atom. There are twelve inequivalent O sites. In the first O site, O(12) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(40) atom. In the second O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(61) atom. In the third O site, O(16) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(50) atom. In the fourth O site, O(18) is bonded in a distorted T-shaped geometry to one Mn(1), one Mn(3), and one C(9) atom. In the fifth O site, O(11) is bonded in a water-like geometry to one Mn(2) and one C(58) atom. In the sixth O site, O(15) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(1) atom. In the seventh O site, O(17) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(40) atom. In the eighth O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the ninth O site, O(6) is bonded in a distorted linear geometry to one Mn(2), one Mn(3), and one C(58) atom. In the tenth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(61) atom. In the eleventh O site, O(9) is bonded in a distorted T-shaped geometry to one Mn(2), one Mn(3), and one C(9) atom. In the twelfth O site, O(10) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(50) atom. Linkers: 4 Cc1c(COc2ccc(C([O])=O)cc2)c(C)c(COc2ccc(C([O])=O)cc2)c(C)c1COc1ccc(C([O])=O)cc1. Metal clusters: 2 O=[C]O[Mn]12O[C]O[Mn]3O[C]O[Mn](O[C]O3)(O[C]O1)O[C]O2. RCSR code: sit. The MOF has largest included sphere 8.45 A, density 0.81 g/cm3, surface area 4814.45 m2/g, accessible volume 0.77 cm3/g