CuH8(C2N)4CuH20(C6N)4(C4H3)4 is Indium-derived structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of eight isobutylene molecules, two CuH20(C6N)4 clusters, and two CuH8(C2N)4 clusters. In each CuH20(C6N)4 cluster, Cu(2) is bonded in a tetrahedral geometry to four equivalent N(2) atoms. All Cu(2)-N(2) bond lengths are 2.00 Å. There are six inequivalent C sites. In the first C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(7)-C(8) bond length is 1.47 Å. The C(7)-H(6) bond length is 0.93 Å. In the second C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.34 Å. The C(8)-C(9) bond length is 1.36 Å. In the third C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(7) atom. The C(9)-C(10) bond length is 1.37 Å. The C(9)-H(7) bond length is 0.93 Å. In the fourth C site, C(10) is bonded in a 3-coordinate geometry to one C(9), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.36 Å. The C(10)-H(8) bond length is 0.93 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(11)-N(2) bond length is 1.33 Å. The C(11)-H(9) bond length is 0.93 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(8) and one H(10) atom. The C(12)-H(10) bond length is 0.93 Å. N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(10), and one C(11) atom. There are five inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In each CuH8(C2N)4 cluster, Cu(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. All Cu(1)-N(1) bond lengths are 2.05 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.28 Å. The C(5)-H(4) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. Linkers: 2 C(=C/c1ccncc1)\c1ccncc1 ,2 [C]1=C[CH]N([Cu](N2[CH]C=[C]C=C2)(N2[CH]C=C(/C=C/c3ccncc3)C=C2)N2[CH]C=C(/C=C/c3ccncc3)C=C2)C=C1 ,1 [CH]1C=C(/C=C/c2ccncc2)C=CN1[Cu](N1[CH]C=C(/C=C/c2ccncc2)C=C1)(N1[CH]C=C(/C=C/c2ccncc2)C=C1)N1[CH]C=C(/C=C/c2ccncc2)C=C1. Metal clusters: 3 [Cu]. The MOF has largest included sphere 4.07 A, density 1.16 g/cm3, surface area 5565.51 m2/g, accessible volume 0.32 cm3/g