LiC5NH6O2(CH)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two LiC5NH6O2 clusters. In each LiC5NH6O2 cluster, Li(1) is bonded to one N(1), one O(2), and two equivalent O(1) atoms to form edge-sharing LiNO3 tetrahedra. The Li(1)-N(1) bond length is 2.01 Å. The Li(1)-O(2) bond length is 2.02 Å. Both Li(1)-O(1) bond lengths are 1.90 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one O(1) atom. The C(1)-O(1) bond length is 1.30 Å. In the second C site, C(6) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(5,6,7,8) and one O(2) atom. Both C(6)-H(5,6,7,8) bond lengths are 0.97 Å. The C(6)-O(2) bond length is 1.43 Å. In the third C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(5,6,7,8) and one O(2) atom. Both C(7)-H(5,6,7,8) bond lengths are 0.97 Å. The C(7)-O(2) bond length is 1.43 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(3) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Li(1), one C(4), and one C(5) atom. There are three inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5,6,7,8) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted T-shaped geometry to two equivalent Li(1) and one C(1) atom. In the second O site, O(2) is bonded in a trigonal planar geometry to one Li(1), one C(6), and one C(7) atom. Linkers: 2 C1COCCO1 ,4 [O]c1ccncc1. Metal clusters: 2 [Li][O].[Li][O]. The MOF has largest included sphere 5.10 A, density 0.92 g/cm3, surface area 5595.89 m2/g, accessible volume 0.44 cm3/g