CdC32H28(N2O)4(CH)8 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight isobutylene molecules and four CdC32H28(N2O)4 clusters. In each CdC32H28(N2O)4 cluster, Cd(1) is bonded in a rectangular see-saw-like geometry to two equivalent N(1) and two equivalent N(3) atoms. Both Cd(1)-N(1) bond lengths are 2.38 Å. Both Cd(1)-N(3) bond lengths are 2.33 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(5), and one N(2) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(5) bond length is 1.40 Å. The C(1)-N(2) bond length is 1.39 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(1), and one H(2) atom. The C(2)-N(1) bond length is 1.33 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(3) atom. The C(3)-C(4) bond length is 1.36 Å. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(4)-H(4) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(5)-H(5) bond length is 0.93 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one N(2) and one O(1) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-O(1) bond length is 1.20 Å. In the seventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one C(15), and one N(4) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(15) bond length is 1.38 Å. The C(11)-N(4) bond length is 1.40 Å. In the eighth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(3), and one H(11) atom. The C(12)-N(3) bond length is 1.34 Å. The C(12)-H(11) bond length is 0.93 Å. In the ninth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one N(3), and one H(12) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-N(3) bond length is 1.34 Å. The C(13)-H(12) bond length is 0.93 Å. In the tenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(13) atom. The C(14)-H(13) bond length is 0.93 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(11) and one H(14) atom. The C(15)-H(14) bond length is 0.93 Å. In the twelfth C site, C(16) is bonded in a water-like geometry to one C(17), one C(20), one H(15), and one H(16) atom. The C(16)-C(17) bond length is 1.51 Å. The C(16)-C(20) bond length is 1.51 Å. The C(16)-H(15) bond length is 0.97 Å. The C(16)-H(16) bond length is 0.97 Å. In the thirteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(19) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-C(19) bond length is 1.40 Å. In the fourteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(17) atom. The C(18)-H(17) bond length is 0.93 Å. In the fifteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(17) and one H(18) atom. The C(19)-H(18) bond length is 0.93 Å. In the sixteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(16), one N(4), and one O(2) atom. The C(20)-N(4) bond length is 1.36 Å. The C(20)-O(2) bond length is 1.22 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(2), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(10), and one H(1) atom. The N(2)-H(1) bond length is 0.86 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(12), and one C(13) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(11), one C(20), and one H(10) atom. The N(4)-H(10) bond length is 0.86 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one N(4) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(18) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(10) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(20) atom. Linkers: 8 O=C(Cc1ccc(CC(=O)Nc2cccnc2)cc1)Nc1cccnc1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 4.84 A, density 1.15 g/cm3, surface area 5048.20 m2/g, accessible volume 0.44 cm3/g