CuH8(C2N)4(C3H2)8(C5H4CH2C5H4)2 is Indium-derived structured and crystallizes in the tetragonal I422 space group. The structure is zero-dimensional and consists of four 1,3,5,7-tetrakis(prop-1-en-2-yl)adamantane molecules; sixteen 2,3-dimethyl-1,3-butadiene molecules; and four CuH8(C2N)4 clusters. In each CuH8(C2N)4 cluster, Cu(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. All Cu(1)-N(1) bond lengths are 2.03 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.30 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(2)-N(1) bond length is 1.33 Å. The C(2)-H(2) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. Linkers: 4 [c]1cc(-c2ccc([C@]34C[C@]5(c6ccc(-c7c[c]ncc7)cc6)C[C@](c6ccc(-c7ccncc7)cc6)(C3)C[C@](c3ccc(-c6ccncc6)cc3)(C4)C5)cc2)ccn1 ,5 c1cc(-c2ccc([C@]34C[C@]5(c6ccc(-c7ccncc7)cc6)C[C@](c6ccc(-c7ccncc7)cc6)(C3)C[C@](c3ccc(-c6ccncc6)cc3)(C4)C5)cc2)ccn1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 6.11 A, density 1.01 g/cm3, surface area 5146.16 m2/g, accessible volume 0.48 cm3/g