Ag6C34N16H54O3CH crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a Ag6C34N16H54O3 framework. In the Ag6C34N16H54O3 framework, there are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a trigonal planar geometry to one N(1), one N(11), and one N(5) atom. The Ag(1)-N(1) bond length is 2.35 Å. The Ag(1)-N(11) bond length is 2.44 Å. The Ag(1)-N(5) bond length is 2.33 Å. In the second Ag site, Ag(2) is bonded in a trigonal planar geometry to one N(13), one N(3), and one N(7) atom. The Ag(2)-N(13) bond length is 2.38 Å. The Ag(2)-N(3) bond length is 2.46 Å. The Ag(2)-N(7) bond length is 2.34 Å. In the third Ag site, Ag(3) is bonded in a distorted T-shaped geometry to one N(10), one N(15), and one O(2) atom. The Ag(3)-N(10) bond length is 2.35 Å. The Ag(3)-N(15) bond length is 2.29 Å. The Ag(3)-O(2) bond length is 2.38 Å. In the fourth Ag site, Ag(4) is bonded in a trigonal planar geometry to one N(12), one N(4), and one O(1) atom. The Ag(4)-N(12) bond length is 2.30 Å. The Ag(4)-N(4) bond length is 2.33 Å. The Ag(4)-O(1) bond length is 2.29 Å. In the fifth Ag site, Ag(5) is bonded in a bent 150 degrees geometry to one N(2) and one N(9) atom. The Ag(5)-N(2) bond length is 2.25 Å. The Ag(5)-N(9) bond length is 2.24 Å. In the sixth Ag site, Ag(6) is bonded in a 2-coordinate geometry to one N(14) and one N(8) atom. The Ag(6)-N(14) bond length is 2.29 Å. The Ag(6)-N(8) bond length is 2.31 Å. There are thirty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.56 Å. The C(1)-O(1) bond length is 1.24 Å. The C(1)-O(2) bond length is 1.22 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(3) atom. The C(2)-C(11) bond length is 1.44 Å. The C(2)-C(3) bond length is 1.32 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(3) atom. The C(5)-C(6) bond length is 1.48 Å. The C(5)-H(3) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(5), and one C(7) atom. The C(6)-C(11) bond length is 1.43 Å. The C(6)-C(7) bond length is 1.38 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one O(3) atom. The C(8)-C(9) bond length is 1.41 Å. The C(8)-O(3) bond length is 1.36 Å. In the eighth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(5) atom. The C(9)-C(10) bond length is 1.42 Å. The C(9)-H(5) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(6) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(6) bond length is 0.93 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(6) atom. In the eleventh C site, C(12) is bonded to one N(1); one N(2); and two equivalent H(7,8) atoms to form corner-sharing CH2N2 tetrahedra. The C(12)-N(1) bond length is 1.49 Å. The C(12)-N(2) bond length is 1.47 Å. Both C(12)-H(7,8) bond lengths are 0.97 Å. In the twelfth C site, C(13) is bonded to one N(2); one N(4); and two equivalent H(9,10) atoms to form corner-sharing CH2N2 tetrahedra. The C(13)-N(2) bond length is 1.48 Å. The C(13)-N(4) bond length is 1.48 Å. Both C(13)-H(9,10) bond lengths are 0.97 Å. In the thirteenth C site, C(14) is bonded to one N(3), one N(4), one H(11), and one H(12) atom to form corner-sharing CH2N2 tetrahedra. The C(14)-N(3) bond length is 1.48 Å. The C(14)-N(4) bond length is 1.47 Å. The C(14)-H(11) bond length is 0.97 Å. The C(14)-H(12) bond length is 0.97 Å. In the fourteenth C site, C(15) is bonded to one N(1); one N(3); and two equivalent H(13,14) atoms to form corner-sharing CH2N2 tetrahedra. The C(15)-N(1) bond length is 1.49 Å. The C(15)-N(3) bond length is 1.47 Å. Both C(15)-H(13,14) bond lengths are 0.97 Å. In the fifteenth C site, C(16) is bonded to one N(2), one N(3), one H(15), and one H(16) atom to form corner-sharing CH2N2 tetrahedra. The C(16)-N(2) bond length is 1.50 Å. The C(16)-N(3) bond length is 1.47 Å. The C(16)-H(15) bond length is 0.97 Å. The C(16)-H(16) bond length is 0.97 Å. In the sixteenth C site, C(17) is bonded to one N(1); one N(4); and two equivalent H(17,18) atoms to form corner-sharing CH2N2 tetrahedra. The C(17)-N(1) bond length is 1.49 Å. The C(17)-N(4) bond length is 1.48 Å. Both C(17)-H(17,18) bond lengths are 0.97 Å. In the seventeenth C site, C(18) is bonded to one N(5), one N(6), one H(19), and one H(20) atom to form corner-sharing CH2N2 tetrahedra. The C(18)-N(5) bond length is 1.49 Å. The C(18)-N(6) bond length is 1.46 Å. The C(18)-H(19) bond length is 0.97 Å. The C(18)-H(20) bond length is 0.97 Å. In the eighteenth C site, C(19) is bonded to one N(6); one N(7); and two equivalent H(21,22,30) atoms to form corner-sharing CH2N2 tetrahedra. The C(19)-N(6) bond length is 1.45 Å. The C(19)-N(7) bond length is 1.50 Å. Both C(19)-H(21,22,30) bond lengths are 0.97 Å. In the nineteenth C site, C(20) is bonded to one N(7), one N(8), one H(23), and one H(24) atom to form corner-sharing CH2N2 tetrahedra. The C(20)-N(7) bond length is 1.49 Å. The C(20)-N(8) bond length is 1.47 Å. The C(20)-H(23) bond length is 0.97 Å. The C(20)-H(24) bond length is 0.97 Å. In the twentieth C site, C(21) is bonded to one N(5), one N(8), one H(25), and one H(26) atom to form corner-sharing CH2N2 tetrahedra. The C(21)-N(5) bond length is 1.49 Å. The C(21)-N(8) bond length is 1.49 Å. The C(21)-H(25) bond length is 0.97 Å. The C(21)-H(26) bond length is 0.97 Å. In the twenty-first C site, C(22) is bonded to one N(5); one N(7); and two equivalent H(27,28) atoms to form corner-sharing CH2N2 tetrahedra. The C(22)-N(5) bond length is 1.48 Å. The C(22)-N(7) bond length is 1.48 Å. Both C(22)-H(27,28) bond lengths are 0.97 Å. In the twenty-second C site, C(23) is bonded to one N(6); one N(8); one H(21,22,30); and one H(29) atom to form corner-sharing CH2N2 tetrahedra. The C(23)-N(6) bond length is 1.46 Å. The C(23)-N(8) bond length is 1.50 Å. The C(23)-H(21,22,30) bond length is 0.97 Å. The C(23)-H(29) bond length is 0.97 Å. In the twenty-third C site, C(24) is bonded to one N(10), one N(9), one H(31), and one H(32) atom to form corner-sharing CH2N2 tetrahedra. The C(24)-N(10) bond length is 1.47 Å. The C(24)-N(9) bond length is 1.48 Å. The C(24)-H(31) bond length is 0.97 Å. The C(24)-H(32) bond length is 0.97 Å. In the twenty-fourth C site, C(25) is bonded to one N(12), one N(9), one H(33), and one H(34) atom to form corner-sharing CH2N2 tetrahedra. The C(25)-N(12) bond length is 1.48 Å. The C(25)-N(9) bond length is 1.48 Å. The C(25)-H(33) bond length is 0.97 Å. The C(25)-H(34) bond length is 0.97 Å. In the twenty-fifth C site, C(26) is bonded to one N(10), one N(11), one H(35), and one H(36) atom to form corner-sharing CH2N2 tetrahedra. The C(26)-N(10) bond length is 1.48 Å. The C(26)-N(11) bond length is 1.47 Å. The C(26)-H(35) bond length is 0.97 Å. The C(26)-H(36) bond length is 0.97 Å. In the twenty-sixth C site, C(27) is bonded to one N(11), one N(12), one H(37), and one H(38) atom to form corner-sharing CH2N2 tetrahedra. The C(27)-N(11) bond length is 1.48 Å. The C(27)-N(12) bond length is 1.48 Å. The C(27)-H(37) bond length is 0.97 Å. The C(27)-H(38) bond length is 0.97 Å. In the twenty-seventh C site, C(28) is bonded to one N(10); one N(12); and two equivalent H(39,40) atoms to form corner-sharing CH2N2 tetrahedra. The C(28)-N(10) bond length is 1.47 Å. The C(28)-N(12) bond length is 1.49 Å. Both C(28)-H(39,40) bond lengths are 0.97 Å. In the twenty-eighth C site, C(29) is bonded to one N(11), one N(9), one H(41), and one H(42) atom to form corner-sharing CH2N2 tetrahedra. The C(29)-N(11) bond length is 1.47 Å. The C(29)-N(9) bond length is 1.49 Å. The C(29)-H(41) bond length is 0.97 Å. The C(29)-H(42) bond length is 0.97 Å. In the twenty-ninth C site, C(30) is bonded to one N(13), one N(16), one H(43), and one H(44) atom to form corner-sharing CH2N2 tetrahedra. The C(30)-N(13) bond length is 1.49 Å. The C(30)-N(16) bond length is 1.45 Å. The C(30)-H(43) bond length is 0.97 Å. The C(30)-H(44) bond length is 0.97 Å. In the thirtieth C site, C(31) is bonded to one N(13); one N(14); and two equivalent H(45,46) atoms to form corner-sharing CH2N2 tetrahedra. The C(31)-N(13) bond length is 1.48 Å. The C(31)-N(14) bond length is 1.48 Å. Both C(31)-H(45,46) bond lengths are 0.97 Å. In the thirty-first C site, C(32) is bonded to one N(13); one N(15); and two equivalent H(47,48) atoms to form corner-sharing CH2N2 tetrahedra. The C(32)-N(13) bond length is 1.49 Å. The C(32)-N(15) bond length is 1.48 Å. Both C(32)-H(47,48) bond lengths are 0.97 Å. In the thirty-second C site, C(33) is bonded to one N(14); one N(16); and two equivalent H(49,50) atoms to form corner-sharing CH2N2 tetrahedra. The C(33)-N(14) bond length is 1.49 Å. The C(33)-N(16) bond length is 1.45 Å. Both C(33)-H(49,50) bond lengths are 0.97 Å. In the thirty-third C site, C(34) is bonded to one N(15); one N(16); and two equivalent H(51,52) atoms to form corner-sharing CH2N2 tetrahedra. The C(34)-N(15) bond length is 1.49 Å. The C(34)-N(16) bond length is 1.46 Å. Both C(34)-H(51,52) bond lengths are 0.97 Å. In the thirty-fourth C site, C(35) is bonded to one N(14), one N(15), one H(53), and one H(54) atom to form corner-sharing CH2N2 tetrahedra. The C(35)-N(14) bond length is 1.48 Å. The C(35)-N(15) bond length is 1.48 Å. The C(35)-H(53) bond length is 0.97 Å. The C(35)-H(54) bond length is 0.97 Å. There are sixteen inequivalent N sites. In the first N site, N(1) is bonded to one Ag(1), one C(12), one C(15), and one C(17) atom to form corner-sharing NAgC3 tetrahedra. In the second N site, N(2) is bonded to one Ag(5), one C(12), one C(13), and one C(16) atom to form corner-sharing NAgC3 tetrahedra. In the third N site, N(3) is bonded to one Ag(2), one C(14), one C(15), and one C(16) atom to form distorted corner-sharing NAgC3 tetrahedra. In the fourth N site, N(4) is bonded to one Ag(4), one C(13), one C(14), and one C(17) atom to form corner-sharing NAgC3 tetrahedra. In the fifth N site, N(5) is bonded to one Ag(1), one C(18), one C(21), and one C(22) atom to form corner-sharing NAgC3 tetrahedra. In the sixth N site, N(6) is bonded in a trigonal non-coplanar geometry to one C(18), one C(19), and one C(23) atom. In the seventh N site, N(7) is bonded to one Ag(2), one C(19), one C(20), and one C(22) atom to form corner-sharing NAgC3 tetrahedra. In the eighth N site, N(8) is bonded to one Ag(6), one C(20), one C(21), and one C(23) atom to form corner-sharing NAgC3 tetrahedra. In the ninth N site, N(9) is bonded to one Ag(5), one C(24), one C(25), and one C(29) atom to form corner-sharing NAgC3 tetrahedra. In the tenth N site, N(10) is bonded to one Ag(3), one C(24), one C(26), and one C(28) atom to form distorted corner-sharing NAgC3 tetrahedra. In the eleventh N site, N(11) is bonded to one Ag(1), one C(26), one C(27), and one C(29) atom to form distorted corner-sharing NAgC3 tetrahedra. In the twelfth N site, N(12) is bonded to one Ag(4), one C(25), one C(27), and one C(28) atom to form corner-sharing NAgC3 tetrahedra. In the thirteenth N site, N(13) is bonded to one Ag(2), one C(30), one C(31), and one C(32) atom to form distorted corner-sharing NAgC3 tetrahedra. In the fourteenth N site, N(14) is bonded to one Ag(6), one C(31), one C(33), and one C(35) atom to form corner-sharing NAgC3 tetrahedra. In the fifteenth N site, N(15) is bonded to one Ag(3), one C(32), one C(34), and one C(35) atom to form corner-sharing NAgC3 tetrahedra. In the sixteenth N site, N(16) is bonded in a trigonal non-coplanar geometry to one C(30), one C(33), and one C(34) atom. There are forty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(13,14) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(17,18) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(21,22,30) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(23) is bonded in a single-bond geometry to one C(20) atom. In the eighteenth H site, H(24) is bonded in a single-bond geometry to one C(20) atom. In the nineteenth H site, H(25) is bonded in a single-bond geometry to one C(21) atom. In the twentieth H site, H(26) is bonded in a single-bond geometry to one C(21) atom. In the twenty-first H site, H(27,28) is bonded in a single-bond geometry to one C(22) atom. In the twenty-second H site, H(29) is bonded in a single-bond geometry to one C(23) atom. In the twenty-third H site, H(31) is bonded in a single-bond geometry to one C(24) atom. In the twenty-fourth H site, H(32) is bonded in a single-bond geometry to one C(24) atom. In the twenty-fifth H site, H(33) is bonded in a single-bond geometry to one C(25) atom. In the twenty-sixth H site, H(34) is bonded in a single-bond geometry to one C(25) atom. In the twenty-seventh H site, H(35) is bonded in a single-bond geometry to one C(26) atom. In the twenty-eighth H site, H(36) is bonded in a single-bond geometry to one C(26) atom. In the twenty-ninth H site, H(37) is bonded in a single-bond geometry to one C(27) atom. In the thirtieth H site, H(38) is bonded in a single-bond geometry to one C(27) atom. In the thirty-first H site, H(39,40) is bonded in a single-bond geometry to one C(28) atom. In the thirty-second H site, H(41) is bonded in a single-bond geometry to one C(29) atom. In the thirty-third H site, H(42) is bonded in a single-bond geometry to one C(29) atom. In the thirty-fourth H site, H(43) is bonded in a single-bond geometry to one C(30) atom. In the thirty-fifth H site, H(44) is bonded in a single-bond geometry to one C(30) atom. In the thirty-sixth H site, H(45,46) is bonded in a single-bond geometry to one C(31) atom. In the thirty-seventh H site, H(47,48) is bonded in a single-bond geometry to one C(32) atom. In the thirty-eighth H site, H(49,50) is bonded in a single-bond geometry to one C(33) atom. In the thirty-ninth H site, H(51,52) is bonded in a single-bond geometry to one C(34) atom. In the fortieth H site, H(53) is bonded in a single-bond geometry to one C(35) atom. In the forty-first H site, H(54) is bonded in a single-bond geometry to one C(35) atom. In the forty-second H site, H(55) is bonded in a single-bond geometry to one O(3) atom. The H(55)-O(3) bond length is 0.82 Å. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(4) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ag(3) and one C(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(8) and one H(55) atom. Linkers: 4 [CH]N(C[N]([Ag]1[N@]23C[N@@]4C[N@](C2)C[N@](C3)(C4)[Ag]([N@]23C[N@]4C[N@@](C3)C[N@@](C2)C4)[N@]23C[N@@]4C[N@](C2)C[N@](C3)(C4)[Ag]([N@@]23C[N@@]4([Ag]([N@@]56C[N@@]71C[N@](C[N@](C7)C6)C5)[N@]15C[N@]6C[N@@](C5)C[N@@](C1)C6)C[N@](C[N@](C4)C3)C2)[N@]12C[N@]3C[N@@](C2)C[N@@](C1)C3)([CH2])[CH2])[CH] ,2 C1[N@@]2C[N@]34C[N@]1C[N@](C2)(C3)[Ag]([N@]12C[N@@]3C[N@](C1)C[N@](C2)(C3)[Ag]([N@]12C[N@@]3([Ag]([N@@]56C[N@@]7([Ag]4[N@]48C[N@]9C[N@@](C8)C[N@@](C4)C9)C[N@](C[N@](C7)C6)C5)[N@]45C[N@]6C[N@@](C5)C[N@@](C4)C6)C[N@@](C2)C[N@](C3)C1)[N@]12C[N@]3C[N@@](C2)C[N@@](C1)C3)[N@]12C[N@]3C[N@@](C2)C[N@@](C1)C3. Metal clusters: 16 [Ag]. The MOF has largest included sphere 4.35 A, density 1.69 g/cm3, surface area 3212.91 m2/g, accessible volume 0.28 cm3/g