Zn9H14(C9O17)2(CH)6 crystallizes in the orthorhombic Pbca space group. The structure consists of forty-eight 02329_fluka molecules inside a Zn9H14(C9O17)2 framework. In the Zn9H14(C9O17)2 framework, there are eight inequivalent Zn sites. In the first Zn site, Zn(1,4) is bonded to one O(1,12,23); one O(10); one O(2,13,24); one O(5,16,27); one O(6,17,28); and one O(9,20,31) atom to form distorted corner-sharing ZnO6 octahedra. The Zn(1,4)-O(1,12,23) bond length is 2.23 Å. The Zn(1,4)-O(10) bond length is 2.00 Å. The Zn(1,4)-O(2,13,24) bond length is 2.18 Å. The Zn(1,4)-O(5,16,27) bond length is 2.06 Å. The Zn(1,4)-O(6,17,28) bond length is 2.05 Å. The Zn(1,4)-O(9,20,31) bond length is 2.11 Å. In the second Zn site, Zn(2) is bonded to one H(19); one O(11); one O(19); one O(21,32); one O(3,25); one O(4,15); and one O(7) atom to form distorted corner-sharing ZnHO6 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 72°. The Zn(2)-H(19) bond length is 1.97 Å. The Zn(2)-O(11) bond length is 2.05 Å. The Zn(2)-O(19) bond length is 2.13 Å. The Zn(2)-O(21,32) bond length is 1.99 Å. The Zn(2)-O(3,25) bond length is 2.13 Å. The Zn(2)-O(4,15) bond length is 2.04 Å. The Zn(2)-O(7) bond length is 2.33 Å. In the third Zn site, Zn(3) is bonded in a 7-coordinate geometry to one H(13), one H(7), one O(11), one O(33), one O(34), one O(7), and one O(8) atom. The Zn(3)-H(13) bond length is 2.05 Å. The Zn(3)-H(7) bond length is 2.17 Å. The Zn(3)-O(11) bond length is 2.04 Å. The Zn(3)-O(33) bond length is 2.04 Å. The Zn(3)-O(34) bond length is 2.12 Å. The Zn(3)-O(7) bond length is 2.11 Å. The Zn(3)-O(8) bond length is 2.17 Å. In the fourth Zn site, Zn(5) is bonded to one H(5), one O(10), one O(14), one O(18), one O(22), one O(26), and one O(30) atom to form distorted corner-sharing ZnHO6 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 72°. The Zn(5)-H(5) bond length is 1.97 Å. The Zn(5)-O(10) bond length is 1.99 Å. The Zn(5)-O(14) bond length is 2.13 Å. The Zn(5)-O(18) bond length is 2.33 Å. The Zn(5)-O(22) bond length is 2.05 Å. The Zn(5)-O(26) bond length is 2.04 Å. The Zn(5)-O(30) bond length is 2.13 Å. In the fifth Zn site, Zn(6) is bonded in a 7-coordinate geometry to one H(14), one H(20), one O(11), one O(18), one O(19), one O(22), and one O(34) atom. The Zn(6)-H(14) bond length is 2.17 Å. The Zn(6)-H(20) bond length is 2.05 Å. The Zn(6)-O(11) bond length is 2.04 Å. The Zn(6)-O(18) bond length is 2.11 Å. The Zn(6)-O(19) bond length is 2.17 Å. The Zn(6)-O(22) bond length is 2.04 Å. The Zn(6)-O(34) bond length is 2.12 Å. In the sixth Zn site, Zn(7) is bonded to one O(1,12,23); one O(2,13,24); one O(21,32); one O(5,16,27); one O(6,17,28); and one O(9,20,31) atom to form distorted corner-sharing ZnO6 octahedra. The Zn(7)-O(1,12,23) bond length is 2.23 Å. The Zn(7)-O(2,13,24) bond length is 2.18 Å. The Zn(7)-O(21,32) bond length is 2.00 Å. The Zn(7)-O(5,16,27) bond length is 2.06 Å. The Zn(7)-O(6,17,28) bond length is 2.05 Å. The Zn(7)-O(9,20,31) bond length is 2.11 Å. In the seventh Zn site, Zn(8) is bonded to one H(12); one O(21,32); one O(29); one O(3,25); one O(33); one O(4,15); and one O(8) atom to form distorted corner-sharing ZnHO6 pentagonal bipyramids. The corner-sharing octahedral tilt angles are 72°. The Zn(8)-H(12) bond length is 1.97 Å. The Zn(8)-O(21,32) bond length is 1.99 Å. The Zn(8)-O(29) bond length is 2.33 Å. The Zn(8)-O(3,25) bond length is 2.13 Å. The Zn(8)-O(33) bond length is 2.05 Å. The Zn(8)-O(4,15) bond length is 2.04 Å. The Zn(8)-O(8) bond length is 2.13 Å. In the eighth Zn site, Zn(9) is bonded in a distorted hexagonal planar geometry to one H(6), one O(22), one O(29), one O(30), one O(33), and one O(34) atom. The Zn(9)-H(6) bond length is 2.05 Å. The Zn(9)-O(22) bond length is 2.04 Å. The Zn(9)-O(29) bond length is 2.11 Å. The Zn(9)-O(30) bond length is 2.17 Å. The Zn(9)-O(33) bond length is 2.04 Å. The Zn(9)-O(34) bond length is 2.12 Å. There are eight inequivalent C sites. In the first C site, C(1,9,17) is bonded in a distorted water-like geometry to one H(1,8,15) and one O(1,12,23) atom. The C(1,9,17)-H(1,8,15) bond length is 1.14 Å. The C(1,9,17)-O(1,12,23) bond length is 1.44 Å. In the second C site, C(2,10,18) is bonded in a distorted bent 120 degrees geometry to one O(2,13,24) and one O(3,25) atom. The C(2,10,18)-O(2,13,24) bond length is 1.24 Å. The C(2,10,18)-O(3,25) bond length is 1.26 Å. In the third C site, C(4,12,20) is bonded in a distorted bent 120 degrees geometry to one O(4,15) and one O(5,16,27) atom. The C(4,12,20)-O(4,15) bond length is 1.22 Å. The C(4,12,20)-O(5,16,27) bond length is 1.26 Å. In the fourth C site, C(6,14) is bonded in a distorted bent 120 degrees geometry to one O(6,17,28) and one O(7) atom. The C(6,14)-O(6,17,28) bond length is 1.24 Å. The C(6,14)-O(7) bond length is 1.25 Å. In the fifth C site, C(7,15,23) is bonded in a distorted water-like geometry to one H(4,11,18) and one O(1,12,23) atom. The C(7,15,23)-H(4,11,18) bond length is 1.14 Å. The C(7,15,23)-O(1,12,23) bond length is 1.44 Å. In the sixth C site, C(8,16) is bonded in a distorted bent 120 degrees geometry to one O(8) and one O(9,20,31) atom. The C(8,16)-O(8) bond length is 1.25 Å. The C(8,16)-O(9,20,31) bond length is 1.26 Å. In the seventh C site, C(22) is bonded in a distorted bent 120 degrees geometry to one O(29) and one O(6,17,28) atom. The C(22)-O(29) bond length is 1.25 Å. The C(22)-O(6,17,28) bond length is 1.24 Å. In the eighth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one O(30) and one O(9,20,31) atom. The C(24)-O(30) bond length is 1.25 Å. The C(24)-O(9,20,31) bond length is 1.26 Å. There are ten inequivalent H sites. In the first H site, H(1,8,15) is bonded in a single-bond geometry to one C(1,9,17) atom. In the second H site, H(4,11,18) is bonded in a single-bond geometry to one C(7,15,23) atom. In the third H site, H(5) is bonded in a single-bond geometry to one Zn(5) and one O(22) atom. The H(5)-O(22) bond length is 1.00 Å. In the fourth H site, H(6) is bonded in a single-bond geometry to one Zn(9) and one O(22) atom. The H(6)-O(22) bond length is 1.00 Å. In the fifth H site, H(7) is bonded in a single-bond geometry to one Zn(3) and one O(34) atom. The H(7)-O(34) bond length is 1.00 Å. In the sixth H site, H(12) is bonded in a single-bond geometry to one Zn(8) and one O(33) atom. The H(12)-O(33) bond length is 1.00 Å. In the seventh H site, H(13) is bonded in a single-bond geometry to one Zn(3) and one O(33) atom. The H(13)-O(33) bond length is 1.00 Å. In the eighth H site, H(14) is bonded in a single-bond geometry to one Zn(6) and one O(34) atom. The H(14)-O(34) bond length is 1.00 Å. In the ninth H site, H(19) is bonded in a single-bond geometry to one Zn(2) and one O(11) atom. The H(19)-O(11) bond length is 1.00 Å. In the tenth H site, H(20) is bonded in a single-bond geometry to one Zn(6) and one O(11) atom. The H(20)-O(11) bond length is 1.00 Å. There are twenty-seven inequivalent O sites. In the first O site, O(33) is bonded in a distorted L-shaped geometry to one Zn(3), one Zn(8), one Zn(9), one H(12), and one H(13) atom. The O(33)-Zn(3) bond length is 2.04 Å. The O(33)-Zn(8) bond length is 2.05 Å. The O(33)-Zn(9) bond length is 2.04 Å. The O(33)-H(12) bond length is 1.00 Å. The O(33)-H(13) bond length is 1.00 Å. In the second O site, O(34) is bonded in a distorted L-shaped geometry to one Zn(3), one Zn(6), one Zn(9), one H(14), and one H(7) atom. The O(34)-Zn(3) bond length is 2.12 Å. The O(34)-Zn(6) bond length is 2.12 Å. The O(34)-Zn(9) bond length is 2.12 Å. The O(34)-H(14) bond length is 1.00 Å. In the third O site, O(34) is bonded in a distorted L-shaped geometry to one Zn(3), one Zn(6), one Zn(9), one H(14), and one H(7) atom. The O(34)-Zn(3) bond length is 2.12 Å. The O(34)-Zn(6) bond length is 2.12 Å. The O(34)-Zn(9) bond length is 2.12 Å. The O(34)-H(14) bond length is 1.00 Å. The O(34)-H(7) bond length is 1.00 Å. In the fourth O site, O(1,12,23) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1,4); one C(1,9,17); and one C(7,15,23) atom. In the fifth O site, O(2,13,24) is bonded in a bent 120 degrees geometry to one Zn(1,4) and one C(2,10,18) atom. In the sixth O site, O(3,25) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(2,10,18) atom. In the seventh O site, O(4,15) is bonded in a distorted bent 150 degrees geometry to one Zn(8) and one C(4,12,20) atom. In the eighth O site, O(5,16,27) is bonded in a bent 120 degrees geometry to one Zn(1,4) and one C(4,12,20) atom. In the ninth O site, O(6,17,28) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(6,14) atom. In the tenth O site, O(7) is bonded in a 3-coordinate geometry to one Zn(2); one Zn(3); and one C(6,14) atom. In the eleventh O site, O(8) is bonded in a 3-coordinate geometry to one Zn(3); one Zn(8); and one C(8,16) atom. In the twelfth O site, O(9,20,31) is bonded in a bent 120 degrees geometry to one Zn(1,4) and one C(8,16) atom. In the thirteenth O site, O(10) is bonded in a water-like geometry to one Zn(1,4) and one Zn(5) atom. In the fourteenth O site, O(11) is bonded in a distorted L-shaped geometry to one Zn(2), one Zn(3), one Zn(6), one H(19), and one H(20) atom. The O(11)-Zn(3) bond length is 2.04 Å. The O(11)-Zn(6) bond length is 2.04 Å. In the fifteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(2,10,18) atom. The O(14)-C(2,10,18) bond length is 1.26 Å. In the sixteenth O site, O(18) is bonded in a 3-coordinate geometry to one Zn(5); one Zn(6); and one C(6,14) atom. The O(18)-C(6,14) bond length is 1.25 Å. In the seventeenth O site, O(19) is bonded in a 3-coordinate geometry to one Zn(2); one Zn(6); and one C(8,16) atom. The O(19)-C(8,16) bond length is 1.25 Å. In the eighteenth O site, O(21,32) is bonded in a water-like geometry to one Zn(1,4) and one Zn(8) atom. The O(21,32)-Zn(1,4) bond length is 2.00 Å. In the nineteenth O site, O(22) is bonded in a distorted L-shaped geometry to one Zn(5), one Zn(6), one Zn(9), one H(5), and one H(6) atom. In the twentieth O site, O(26) is bonded in a distorted bent 150 degrees geometry to one Zn(5) and one C(4,12,20) atom. The O(26)-C(4,12,20) bond length is 1.22 Å. In the twenty-first O site, O(29) is bonded in a 3-coordinate geometry to one Zn(8), one Zn(9), and one C(22) atom. In the twenty-second O site, O(30) is bonded in a 3-coordinate geometry to one Zn(5), one Zn(9), and one C(24) atom. In the twenty-third O site, O(33) is bonded in a distorted L-shaped geometry to one Zn(3), one Zn(8), one Zn(9), one H(12), and one H(13) atom. In the twenty-fourth O site, O(34) is bonded in a distorted L-shaped geometry to one Zn(3), one Zn(6), one Zn(9), one H(14), and one H(7) atom. The O(34)-H(14) bond length is 1.00 Å. The O(34)-H(7) bond length is 1.00 Å. In the twenty-fifth O site, O(34) is bonded in a distorted L-shaped geometry to one Zn(3), one Zn(6), one Zn(9), one H(14), and one H(7) atom. The O(34)-Zn(3) bond length is 2.12 Å. The O(34)-Zn(6) bond length is 2.12 Å. The O(34)-Zn(9) bond length is 2.12 Å. The O(34)-H(14) bond length is 1.00 Å. The O(34)-H(7) bond length is 1.00 Å. In the twenty-sixth O site, O(34) is bonded in a distorted L-shaped geometry to one Zn(3), one Zn(6), one Zn(9), one H(14), and one H(7) atom. The O(34)-Zn(3) bond length is 2.12 Å. The O(34)-Zn(6) bond length is 2.12 Å. The O(34)-Zn(9) bond length is 2.12 Å. The O(34)-H(7) bond length is 1.00 Å. In the twenty-seventh O site, O(11) is bonded in a distorted L-shaped geometry to one Zn(2), one Zn(3), one Zn(6), one H(19), and one H(20) atom. The O(11)-Zn(2) bond length is 2.05 Å. The O(11)-H(19) bond length is 1.00 Å. The O(11)-H(20) bond length is 1.00 Å. Linkers: 24 [O]C(=O)[C@@H]1[C@H](C([O])=O)[C@@H](C([O])=O)O[C@H]1C([O])=O. Metal clusters: 72 [Zn]. The MOF has largest included sphere 5.19 A, density 2.15 g/cm3, surface area 2362.66 m2/g, accessible volume 0.21 cm3/g