NiC24H24(NS)6(CH)12 is Indium-derived structured and crystallizes in the trigonal R-3c space group. The structure is zero-dimensional and consists of seventy-two 02329_fluka molecules and six NiC24H24(NS)6 clusters. In each NiC24H24(NS)6 cluster, Ni(1) is bonded in an octahedral geometry to six equivalent S(1) atoms. All Ni(1)-S(1) bond lengths are 2.46 Å. There are four inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.36 Å. The C(5)-H(4) bond length is 0.93 Å. In the second C site, C(6) is bonded in a 3-coordinate geometry to one N(1) and two equivalent H(5,6) atoms. The C(6)-N(1) bond length is 1.47 Å. Both C(6)-H(5,6) bond lengths are 0.97 Å. In the third C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one S(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.37 Å. The C(1)-S(1) bond length is 1.72 Å. In the fourth C site, C(2) is bonded in a single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(6) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(6) atom. S(1) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(1) atom. Linkers: 3 S=c1ccccn1CCN1C=CC=C[C]1S[Ni](S[C]1C=CC=CN1CCn1ccccc1=S)(S[C]1C=CC=CN1CCn1ccccc1=S)(S[C]1C=CC=CN1CCn1ccccc1=S)(S[C]1C=CC=CN1CCn1ccccc1=S)S[C]1C=CC=CN1CCn1ccccc1=S ,7 S=c1ccccn1CCn1ccccc1=S. Metal clusters: 4 [S][Ni]([S])([S])([S])([S])[S]. RCSR code: pcu. The MOF has largest included sphere 5.69 A, density 1.02 g/cm3, surface area 4850.69 m2/g, accessible volume 0.50 cm3/g