Ni2C42H35(NO)8(CH)9(CH2)9(CH2CO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eighteen 02329_fluka molecules, eighteen 02329_fluka molecules, four dimethyl ether molecules, and one Ni2C42H35(NO)8 cluster. In the Ni2C42H35(NO)8 cluster, there are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a trigonal bipyramidal geometry to one N(1), one N(5), one O(1), one O(3), and one O(4) atom. The Ni(1)-N(1) bond length is 2.06 Å. The Ni(1)-N(5) bond length is 2.14 Å. The Ni(1)-O(1) bond length is 2.11 Å. The Ni(1)-O(3) bond length is 2.11 Å. The Ni(1)-O(4) bond length is 2.12 Å. In the second Ni site, Ni(2) is bonded in a distorted octahedral geometry to one N(4), one N(8), one O(5), one O(6), one O(7), and one O(8) atom. The Ni(2)-N(4) bond length is 2.04 Å. The Ni(2)-N(8) bond length is 2.05 Å. The Ni(2)-O(5) bond length is 2.06 Å. The Ni(2)-O(6) bond length is 2.24 Å. The Ni(2)-O(7) bond length is 2.10 Å. The Ni(2)-O(8) bond length is 2.14 Å. There are forty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(1)-C(2) bond length is 1.37 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-N(1) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one N(2) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-N(2) bond length is 1.37 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(1), and one N(2) atom. The C(7)-C(8) bond length is 1.47 Å. The C(7)-N(1) bond length is 1.34 Å. The C(7)-N(2) bond length is 1.37 Å. In the sixth C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(7); one H(5); and two equivalent H(6,7) atoms. The C(8)-H(5) bond length is 0.96 Å. Both C(8)-H(6,7) bond lengths are 0.96 Å. In the seventh C site, C(9) is bonded in a 3-coordinate geometry to one N(2), one H(8), and one H(9) atom. The C(9)-N(2) bond length is 1.47 Å. The C(9)-H(8) bond length is 0.97 Å. The C(9)-H(9) bond length is 0.97 Å. In the eighth C site, C(13) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(16,17) atoms. The C(13)-N(3) bond length is 1.47 Å. Both C(13)-H(16,17) bond lengths are 0.97 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(19) and one N(3) atom. The C(14)-C(19) bond length is 1.40 Å. The C(14)-N(3) bond length is 1.37 Å. In the tenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(21) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(21) bond length is 0.93 Å. In the eleventh C site, C(19) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one N(4) atom. The C(19)-N(4) bond length is 1.40 Å. In the twelfth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(21), one N(3), and one N(4) atom. The C(20)-C(21) bond length is 1.47 Å. The C(20)-N(3) bond length is 1.37 Å. The C(20)-N(4) bond length is 1.33 Å. In the thirteenth C site, C(21) is bonded in a trigonal non-coplanar geometry to one C(20) and three equivalent H(22,23,24) atoms. All C(21)-H(22,23,24) bond lengths are 0.96 Å. In the fourteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(27) and one H(25) atom. The C(22)-C(27) bond length is 1.38 Å. The C(22)-H(25) bond length is 0.93 Å. In the fifteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(26) and one H(28) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-H(28) bond length is 0.93 Å. In the sixteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(25), one C(27), and one N(6) atom. The C(26)-C(27) bond length is 1.38 Å. The C(26)-N(6) bond length is 1.37 Å. In the seventeenth C site, C(27) is bonded in a distorted single-bond geometry to one C(22), one C(26), and one N(5) atom. The C(27)-N(5) bond length is 1.40 Å. In the eighteenth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(29), one N(5), and one N(6) atom. The C(28)-C(29) bond length is 1.51 Å. The C(28)-N(5) bond length is 1.29 Å. The C(28)-N(6) bond length is 1.35 Å. In the nineteenth C site, C(29) is bonded in a trigonal non-coplanar geometry to one C(28) and three equivalent H(29,30,31) atoms. All C(29)-H(29,30,31) bond lengths are 0.96 Å. In the twentieth C site, C(30) is bonded in a 4-coordinate geometry to one C(31), one N(6), one H(32), and one H(33) atom. The C(30)-C(31) bond length is 1.43 Å. The C(30)-N(6) bond length is 1.50 Å. The C(30)-H(32) bond length is 0.97 Å. The C(30)-H(33) bond length is 0.97 Å. In the twenty-first C site, C(31) is bonded in a distorted water-like geometry to one C(30), one H(34), and one H(35) atom. The C(31)-H(34) bond length is 0.97 Å. The C(31)-H(35) bond length is 0.97 Å. In the twenty-second C site, C(34) is bonded in a 3-coordinate geometry to one N(7) and two equivalent H(40,41) atoms. The C(34)-N(7) bond length is 1.46 Å. Both C(34)-H(40,41) bond lengths are 0.97 Å. In the twenty-third C site, C(35) is bonded in a trigonal non-coplanar geometry to one C(36) and three equivalent H(42,43,44) atoms. The C(35)-C(36) bond length is 1.49 Å. All C(35)-H(42,43,44) bond lengths are 0.96 Å. In the twenty-fourth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(35), one N(7), and one N(8) atom. The C(36)-N(7) bond length is 1.37 Å. The C(36)-N(8) bond length is 1.32 Å. In the twenty-fifth C site, C(37) is bonded in a distorted single-bond geometry to one C(38), one C(42), and one N(7) atom. The C(37)-C(38) bond length is 1.40 Å. The C(37)-C(42) bond length is 1.38 Å. The C(37)-N(7) bond length is 1.40 Å. In the twenty-sixth C site, C(38) is bonded in a distorted single-bond geometry to one C(37) and one H(45) atom. The C(38)-H(45) bond length is 0.93 Å. In the twenty-seventh C site, C(41) is bonded in a distorted single-bond geometry to one C(42) and one H(48) atom. The C(41)-C(42) bond length is 1.39 Å. The C(41)-H(48) bond length is 0.93 Å. In the twenty-eighth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(37), one C(41), and one N(8) atom. The C(42)-N(8) bond length is 1.39 Å. In the twenty-ninth C site, C(43) is bonded in a distorted bent 120 degrees geometry to one C(44), one O(1), and one O(2) atom. The C(43)-C(44) bond length is 1.51 Å. The C(43)-O(1) bond length is 1.23 Å. The C(43)-O(2) bond length is 1.21 Å. In the thirtieth C site, C(44) is bonded in a trigonal planar geometry to one C(43), one C(45), and one C(49) atom. The C(44)-C(45) bond length is 1.38 Å. The C(44)-C(49) bond length is 1.39 Å. In the thirty-first C site, C(45) is bonded in a single-bond geometry to one C(44) and one H(49) atom. The C(45)-H(49) bond length is 0.93 Å. In the thirty-second C site, C(47) is bonded in a distorted single-bond geometry to one C(48) and one H(50) atom. The C(47)-C(48) bond length is 1.39 Å. The C(47)-H(50) bond length is 0.93 Å. In the thirty-third C site, C(48) is bonded in a trigonal planar geometry to one C(47), one C(49), and one C(50) atom. The C(48)-C(49) bond length is 1.39 Å. The C(48)-C(50) bond length is 1.50 Å. In the thirty-fourth C site, C(49) is bonded in a distorted single-bond geometry to one C(44), one C(48), and one H(51) atom. The C(49)-H(51) bond length is 0.93 Å. In the thirty-fifth C site, C(50) is bonded in a bent 120 degrees geometry to one C(48), one O(5), and one O(6) atom. The C(50)-O(5) bond length is 1.27 Å. The C(50)-O(6) bond length is 1.25 Å. In the thirty-sixth C site, C(53) is bonded in a bent 120 degrees geometry to one C(54), one O(3), and one O(4) atom. The C(53)-C(54) bond length is 1.50 Å. The C(53)-O(3) bond length is 1.26 Å. The C(53)-O(4) bond length is 1.27 Å. In the thirty-seventh C site, C(54) is bonded in a trigonal planar geometry to one C(53), one C(55), and one C(59) atom. The C(54)-C(55) bond length is 1.38 Å. The C(54)-C(59) bond length is 1.40 Å. In the thirty-eighth C site, C(55) is bonded in a distorted single-bond geometry to one C(54) and one H(56) atom. The C(55)-H(56) bond length is 0.93 Å. In the thirty-ninth C site, C(57) is bonded in a distorted single-bond geometry to one C(58) and one H(57) atom. The C(57)-C(58) bond length is 1.39 Å. The C(57)-H(57) bond length is 0.93 Å. In the fortieth C site, C(58) is bonded in a trigonal planar geometry to one C(57), one C(59), and one C(60) atom. The C(58)-C(59) bond length is 1.38 Å. The C(58)-C(60) bond length is 1.50 Å. In the forty-first C site, C(59) is bonded in a distorted single-bond geometry to one C(54), one C(58), and one H(58) atom. The C(59)-H(58) bond length is 0.93 Å. In the forty-second C site, C(60) is bonded in a distorted bent 120 degrees geometry to one C(58), one O(7), and one O(8) atom. The C(60)-O(7) bond length is 1.26 Å. The C(60)-O(8) bond length is 1.26 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(2), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(20) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ni(2), one C(19), and one C(20) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Ni(1), one C(27), and one C(28) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(30) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(34), one C(36), and one C(37) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Ni(2), one C(36), and one C(42) atom. There are twenty-six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(6,7) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(16,17) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(21) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(22,23,24) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(25) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(28) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(29,30,31) is bonded in a single-bond geometry to one C(29) atom. In the thirteenth H site, H(32) is bonded in a single-bond geometry to one C(30) atom. In the fourteenth H site, H(33) is bonded in a single-bond geometry to one C(30) atom. In the fifteenth H site, H(34) is bonded in a single-bond geometry to one C(31) atom. In the sixteenth H site, H(35) is bonded in a single-bond geometry to one C(31) atom. In the seventeenth H site, H(40,41) is bonded in a single-bond geometry to one C(34) atom. In the eighteenth H site, H(42,43,44) is bonded in a single-bond geometry to one C(35) atom. In the nineteenth H site, H(45) is bonded in a single-bond geometry to one C(38) atom. In the twentieth H site, H(48) is bonded in a single-bond geometry to one C(41) atom. In the twenty-first H site, H(49) is bonded in a single-bond geometry to one C(45) atom. In the twenty-second H site, H(50) is bonded in a single-bond geometry to one C(47) atom. In the twenty-third H site, H(51) is bonded in a single-bond geometry to one C(49) atom. In the twenty-fourth H site, H(56) is bonded in a single-bond geometry to one C(55) atom. In the twenty-fifth H site, H(57) is bonded in a single-bond geometry to one C(57) atom. In the twenty-sixth H site, H(58) is bonded in a single-bond geometry to one C(59) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(43) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(43) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Ni(1) and one C(53) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Ni(1) and one C(53) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Ni(2) and one C(50) atom. In the sixth O site, O(6) is bonded in a distorted L-shaped geometry to one Ni(2) and one C(50) atom. In the seventh O site, O(7) is bonded in an L-shaped geometry to one Ni(2) and one C(60) atom. In the eighth O site, O(8) is bonded in an L-shaped geometry to one Ni(2) and one C(60) atom. Linkers: 4 Cc1nc2ccccc2n1CCCCCn1c(C)nc2ccccc21 ,2 [O]C(=O)c1cc(OCCCCCCOc2cc(C([O])=O)cc(C([O])=O)c2)cc(C([O])=O)c1. Metal clusters: 2 O=[C]O[Ni]1O[C]O1 ,2 [C]1O[Ni]2(O1)O[C]O2. The MOF has largest included sphere 5.35 A, density 1.19 g/cm3, surface area 5161.93 m2/g, accessible volume 0.33 cm3/g