Co3C28NH17O13(CH)8(C2O)2C4H2O is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, four 2-methoxypropene molecules, eight dimethyl ether molecules, and two Co3C28NH17O13 clusters. In each Co3C28NH17O13 cluster, there are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(1), one O(14), one O(16), one O(2), one O(6), and one O(9) atom to form CoNO5 octahedra that share  a cornercorner with one Co(3)O6 octahedra and  a cornercorner with one Co(2)O5 trigonal bipyramid. The corner-sharing octahedral tilt angles are 68°. The Co(1)-N(1) bond length is 2.13 Å. The Co(1)-O(14) bond length is 2.08 Å. The Co(1)-O(16) bond length is 2.08 Å. The Co(1)-O(2) bond length is 2.10 Å. The Co(1)-O(6) bond length is 2.12 Å. The Co(1)-O(9) bond length is 2.08 Å. In the second Co site, Co(2) is bonded to one O(1), one O(12), one O(16), one O(4), and one O(7) atom to form distorted CoO5 trigonal bipyramids that share  a cornercorner with one Co(1)NO5 octahedra and  a cornercorner with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles range from 52-74°. The Co(2)-O(1) bond length is 2.10 Å. The Co(2)-O(12) bond length is 2.03 Å. The Co(2)-O(16) bond length is 1.99 Å. The Co(2)-O(4) bond length is 2.12 Å. The Co(2)-O(7) bond length is 2.03 Å. In the third Co site, Co(3) is bonded to one O(10), one O(11), one O(15), one O(16), and two equivalent O(5) atoms to form CoO6 octahedra that share  a cornercorner with one Co(1)NO5 octahedra,  a cornercorner with one Co(2)O5 trigonal bipyramid, and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles are 68°. The Co(3)-O(10) bond length is 2.04 Å. The Co(3)-O(11) bond length is 2.07 Å. The Co(3)-O(15) bond length is 2.08 Å. The Co(3)-O(16) bond length is 2.03 Å. There is one shorter (2.19 Å) and one longer (2.25 Å) Co(3)-O(5) bond length. There are twenty-eight inequivalent C sites. In the first C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-H(6) bond length is 0.95 Å. In the second C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(14) bond length is 1.50 Å. In the third C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 0.95 Å. In the fourth C site, C(15) is bonded in a bent 120 degrees geometry to one C(16), one O(6), and one O(7) atom. The C(15)-C(16) bond length is 1.49 Å. The C(15)-O(6) bond length is 1.24 Å. The C(15)-O(7) bond length is 1.27 Å. In the fifth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.41 Å. The C(16)-C(21) bond length is 1.38 Å. In the sixth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one H(9) atom. The C(17)-C(18) bond length is 1.37 Å. The C(17)-H(9) bond length is 0.95 Å. In the seventh C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(10) atom. The C(18)-H(10) bond length is 0.95 Å. In the eighth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(4), and one O(5) atom. The C(14)-O(4) bond length is 1.23 Å. The C(14)-O(5) bond length is 1.28 Å. In the ninth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(11) atom. The C(20)-C(21) bond length is 1.38 Å. The C(20)-H(11) bond length is 0.95 Å. In the tenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(16), one C(20), and one H(12) atom. The C(21)-H(12) bond length is 0.95 Å. In the eleventh C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(14) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-H(14) bond length is 0.95 Å. In the twelfth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(28) atom. The C(25)-C(26) bond length is 1.38 Å. The C(25)-C(28) bond length is 1.53 Å. In the thirteenth C site, C(29) is bonded in a bent 120 degrees geometry to one C(30), one O(11), and one O(12) atom. The C(29)-C(30) bond length is 1.51 Å. The C(29)-O(11) bond length is 1.27 Å. The C(29)-O(12) bond length is 1.26 Å. In the fourteenth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(35) atom. The C(30)-C(31) bond length is 1.36 Å. The C(30)-C(35) bond length is 1.38 Å. In the fifteenth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(17) atom. The C(31)-H(17) bond length is 0.95 Å. In the sixteenth C site, C(35) is bonded in a distorted single-bond geometry to one C(30) and one H(20) atom. The C(35)-H(20) bond length is 0.95 Å. In the seventeenth C site, C(38) is bonded in a distorted single-bond geometry to one C(39) and one H(22) atom. The C(38)-C(39) bond length is 1.37 Å. The C(38)-H(22) bond length is 0.95 Å. In the eighteenth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(42) atom. The C(39)-C(40) bond length is 1.39 Å. The C(39)-C(42) bond length is 1.51 Å. In the nineteenth C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one H(23) atom. The C(40)-H(23) bond length is 0.95 Å. In the twentieth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(39), one O(14), and one O(15) atom. The C(42)-O(14) bond length is 1.24 Å. The C(42)-O(15) bond length is 1.26 Å. In the twenty-first C site, C(43) is bonded in a 2-coordinate geometry to one N(1) and one H(25) atom. The C(43)-N(1) bond length is 1.33 Å. The C(43)-H(25) bond length is 0.79 Å. In the twenty-second C site, C(44) is bonded in a 2-coordinate geometry to one N(1) and one H(26) atom. The C(44)-N(1) bond length is 1.34 Å. The C(44)-H(26) bond length is 0.94 Å. In the twenty-third C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(15) atom. The C(26)-H(15) bond length is 0.95 Å. In the twenty-fourth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(10), and one O(9) atom. The C(28)-O(10) bond length is 1.25 Å. The C(28)-O(9) bond length is 1.25 Å. In the twenty-fifth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.25 Å. In the twenty-sixth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.39 Å. In the twenty-seventh C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. In the twenty-eighth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.95 Å. N(1) is bonded in a trigonal planar geometry to one Co(1), one C(43), and one C(44) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(31) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(35) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(38) atom. In the fourteenth H site, H(23) is bonded in a single-bond geometry to one C(40) atom. In the fifteenth H site, H(25) is bonded in a single-bond geometry to one C(43) atom. In the sixteenth H site, H(26) is bonded in a single-bond geometry to one C(44) atom. In the seventeenth H site, H(27) is bonded in a single-bond geometry to one O(16) atom. The H(27)-O(16) bond length is 0.76 Å. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Co(1) and one C(1) atom. In the third O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(14) atom. In the fourth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Co(3) and one C(14) atom. In the fifth O site, O(6) is bonded in a bent 150 degrees geometry to one Co(1) and one C(15) atom. In the sixth O site, O(7) is bonded in a bent 120 degrees geometry to one Co(2) and one C(15) atom. In the seventh O site, O(9) is bonded in a bent 120 degrees geometry to one Co(1) and one C(28) atom. In the eighth O site, O(10) is bonded in a bent 120 degrees geometry to one Co(3) and one C(28) atom. In the ninth O site, O(11) is bonded in a 2-coordinate geometry to one Co(3) and one C(29) atom. In the tenth O site, O(12) is bonded in a water-like geometry to one Co(2) and one C(29) atom. In the eleventh O site, O(14) is bonded in a bent 120 degrees geometry to one Co(1) and one C(42) atom. In the twelfth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Co(3) and one C(42) atom. In the thirteenth O site, O(16) is bonded in a single-bond geometry to one Co(1), one Co(2), one Co(3), and one H(27) atom. Linkers: 12 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,1 c1cnccn1. Metal clusters: 1 O[Co]123O[C]O[Co]4(O[C]O[Co](O[C]O4)(O[C]O1)O[C]O[Co]14(O)O[C]O[Co]5(O[C]O[Co](O[C]O5)(O[C]O1)O[C]O2)O[C]O4)O[C]O3 ,6 [Co]. The MOF has largest included sphere 5.63 A, density 1.09 g/cm3, surface area 4026.01 m2/g, accessible volume 0.40 cm3/g