Zn4H24(C3O)13 crystallizes in the cubic Fm-3m space group. Zn(1) is bonded to one O(2) and three equivalent O(1) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(2) bond length is 1.93 Å. All Zn(1)-O(1) bond lengths are 2.01 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(3), and one H(1) atom. The C(1)-C(2) bond length is 1.62 Å. The C(1)-C(3) bond length is 1.17 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted rectangular see-saw-like geometry to one C(1), one C(2), one C(5), and one H(2) atom. The C(2)-C(1) bond length is 1.62 Å. The C(2)-C(2) bond length is 0.96 Å. The C(2)-C(5) bond length is 1.37 Å. The C(2)-H(2) bond length is 1.29 Å. In the third C site, C(2) is bonded in a distorted rectangular see-saw-like geometry to one C(1), one C(2), one C(5), and one H(2) atom. The C(2)-C(2) bond length is 0.96 Å. The C(2)-C(5) bond length is 1.37 Å. The C(2)-H(2) bond length is 1.29 Å. In the fourth C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(3), and one H(1) atom. The C(1)-C(3) bond length is 1.17 Å. The C(1)-H(1) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a square co-planar geometry to four equivalent C(2) atoms. In the sixth C site, C(5) is bonded in a rectangular see-saw-like geometry to four equivalent C(2) atoms. In the seventh C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4) and two equivalent C(1) atoms. The C(3)-C(4) bond length is 1.63 Å. In the eighth C site, C(4) is bonded in a bent 150 degrees geometry to one C(3) and two equivalent O(1) atoms. Both C(4)-O(1) bond lengths are 1.25 Å. There are three inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(2) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a tetrahedral geometry to four equivalent Zn(1) atoms. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. Linkers: 13 [C]C1=C=C/C(C([O])=O)=C\C#C[CH]/C(C([O])=O)=C\1 ,9 [C]C1=C=C/C(C([O])=O)=C\C#C/C=C(/C([O])=O)[CH]1 ,2 [O]C(=O)[C]1C=C=C2[C]C(=C=C1)C=C(C([O])=O)[CH]2. Metal clusters: 8 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: pcu. The MOF has largest included sphere 17.98 A, density 0.46 g/cm3, surface area 3788.82 m2/g, accessible volume 1.71 cm3/g