(CH)12PbC14P2H12(OI)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules and two PbC14P2H12(OI)2 clusters. In each PbC14P2H12(OI)2 cluster, Pb(1) is bonded in a distorted L-shaped geometry to one O(1), one O(2), one I(1), and one I(2) atom. The Pb(1)-O(1) bond length is 2.40 Å. The Pb(1)-O(2) bond length is 2.41 Å. The Pb(1)-I(1) bond length is 3.03 Å. The Pb(1)-I(2) bond length is 3.02 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one P(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.37 Å. The C(1)-P(1) bond length is 1.80 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.94 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(6)-H(5) bond length is 0.94 Å. In the fourth C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(8), and one P(1) atom. The C(7)-C(12) bond length is 1.33 Å. The C(7)-C(8) bond length is 1.42 Å. The C(7)-P(1) bond length is 1.81 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(6) atom. The C(8)-H(6) bond length is 0.94 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(10) atom. The C(12)-H(10) bond length is 0.94 Å. In the seventh C site, C(13) is bonded in a distorted water-like geometry to one P(1) and two equivalent H(11,12) atoms. The C(13)-P(1) bond length is 1.81 Å. Both C(13)-H(11,12) bond lengths are 0.98 Å. In the eighth C site, C(14) is bonded in a trigonal planar geometry to one C(15), one C(19), and one P(2) atom. The C(14)-C(15) bond length is 1.36 Å. The C(14)-C(19) bond length is 1.36 Å. The C(14)-P(2) bond length is 1.80 Å. In the ninth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(13) atom. The C(15)-H(13) bond length is 0.94 Å. In the tenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(17) atom. The C(19)-H(17) bond length is 0.94 Å. In the eleventh C site, C(20) is bonded in a trigonal planar geometry to one C(21), one C(25), and one P(2) atom. The C(20)-C(21) bond length is 1.35 Å. The C(20)-C(25) bond length is 1.40 Å. The C(20)-P(2) bond length is 1.83 Å. In the twelfth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(18) atom. The C(21)-H(18) bond length is 0.94 Å. In the thirteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(20) and one H(22) atom. The C(25)-H(22) bond length is 0.94 Å. In the fourteenth C site, C(26) is bonded in a distorted water-like geometry to one P(2), one H(23), and one H(24) atom. The C(26)-P(2) bond length is 1.79 Å. The C(26)-H(23) bond length is 0.98 Å. The C(26)-H(24) bond length is 0.98 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a tetrahedral geometry to one C(1), one C(13), one C(7), and one O(1) atom. The P(1)-O(1) bond length is 1.50 Å. In the second P site, P(2) is bonded in a tetrahedral geometry to one C(14), one C(20), one C(26), and one O(2) atom. The P(2)-O(2) bond length is 1.52 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(11,12) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(22) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(23) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(24) is bonded in a single-bond geometry to one C(26) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Pb(1) and one P(1) atom. In the second O site, O(2) is bonded in a distorted linear geometry to one Pb(1) and one P(2) atom. There are two inequivalent I sites. In the first I site, I(1) is bonded in a single-bond geometry to one Pb(1) atom. In the second I site, I(2) is bonded in a single-bond geometry to one Pb(1) atom. Linkers: 1 [CH]/C=C(\[CH])[P@@](=O)(CCP(=O)(c1ccccc1)c1ccccc1)c1ccccc1 ,3 O=P(CCP(=O)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1 ,1 [CH]=CC(=[CH])[P@](=O)(CCP(=O)(c1ccccc1)c1ccccc1)c1ccccc1. Metal clusters: 2 [Pb]. The MOF has largest included sphere 4.07 A, density 1.83 g/cm3, surface area 3640.18 m2/g, accessible volume 0.20 cm3/g