CdC23H15(NO2)2(CH)5(CH2CO)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of ten 02329_fluka molecules, four dimethyl ether molecules, and one CdC23H15(NO2)2 cluster. In the CdC23H15(NO2)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(5), and one O(6) atom. The Cd(1)-N(1) bond length is 2.32 Å. The Cd(1)-N(2) bond length is 2.31 Å. The Cd(1)-O(1) bond length is 2.22 Å. The Cd(1)-O(2) bond length is 2.60 Å. The Cd(1)-O(5) bond length is 2.27 Å. The Cd(1)-O(6) bond length is 2.30 Å. There are twenty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(4) and one H(19) atom. The C(1)-C(4) bond length is 1.38 Å. The C(1)-H(19) bond length is 0.93 Å. In the second C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(22), and one C(27) atom. The C(4)-C(22) bond length is 1.39 Å. The C(4)-C(27) bond length is 1.51 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(8) and one H(13) atom. The C(6)-C(8) bond length is 1.39 Å. The C(6)-H(13) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(14) and one H(3) atom. The C(7)-C(14) bond length is 1.38 Å. The C(7)-H(3) bond length is 0.93 Å. In the fifth C site, C(8) is bonded in a trigonal planar geometry to one C(28), one C(29), and one C(6) atom. The C(8)-C(28) bond length is 1.38 Å. The C(8)-C(29) bond length is 1.49 Å. In the sixth C site, C(10) is bonded in a single-bond geometry to one C(11) and one H(8) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-H(8) bond length is 0.93 Å. In the seventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(21) atom. The C(11)-C(14) bond length is 1.49 Å. The C(11)-C(21) bond length is 1.38 Å. In the eighth C site, C(14) is bonded in a trigonal planar geometry to one C(11), one C(19), and one C(7) atom. The C(14)-C(19) bond length is 1.40 Å. In the ninth C site, C(16) is bonded in a distorted single-bond geometry to one C(25) and one H(10) atom. The C(16)-C(25) bond length is 1.38 Å. The C(16)-H(10) bond length is 0.93 Å. In the tenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(29), one N(2), and one H(14) atom. The C(17)-C(29) bond length is 1.39 Å. The C(17)-N(2) bond length is 1.34 Å. The C(17)-H(14) bond length is 0.93 Å. In the eleventh C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(18)-N(1) bond length is 1.33 Å. The C(18)-H(2) bond length is 0.93 Å. In the twelfth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(1), and one H(5) atom. The C(19)-N(1) bond length is 1.34 Å. The C(19)-H(5) bond length is 0.93 Å. In the thirteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(11) and one H(17) atom. The C(21)-H(17) bond length is 0.93 Å. In the fourteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(4) and one H(18) atom. The C(22)-H(18) bond length is 0.93 Å. In the fifteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(25) and one H(1) atom. The C(23)-C(25) bond length is 1.37 Å. The C(23)-H(1) bond length is 0.93 Å. In the sixteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(32) and one H(16) atom. The C(24)-C(32) bond length is 1.39 Å. The C(24)-H(16) bond length is 0.93 Å. In the seventeenth C site, C(25) is bonded in a trigonal planar geometry to one C(16), one C(23), and one C(31) atom. The C(25)-C(31) bond length is 1.51 Å. In the eighteenth C site, C(27) is bonded in a bent 120 degrees geometry to one C(4), one O(2), and one O(6) atom. The C(27)-O(2) bond length is 1.26 Å. The C(27)-O(6) bond length is 1.27 Å. In the nineteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(8) and one H(15) atom. The C(28)-H(15) bond length is 0.93 Å. In the twentieth C site, C(29) is bonded in a trigonal planar geometry to one C(17), one C(30), and one C(8) atom. The C(29)-C(30) bond length is 1.38 Å. In the twenty-first C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(20) atom. The C(30)-H(20) bond length is 0.93 Å. In the twenty-second C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(1), and one O(5) atom. The C(31)-O(1) bond length is 1.26 Å. The C(31)-O(5) bond length is 1.25 Å. In the twenty-third C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(24), one N(2), and one H(23) atom. The C(32)-N(2) bond length is 1.33 Å. The C(32)-H(23) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(18), and one C(19) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(17), and one C(32) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(23) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(18) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(19) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(28) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(1) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(30) atom. In the fifteenth H site, H(23) is bonded in a single-bond geometry to one C(32) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(31) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(27) atom. In the third O site, O(5) is bonded in a 2-coordinate geometry to one Cd(1) and one C(31) atom. In the fourth O site, O(6) is bonded in a water-like geometry to one Cd(1) and one C(27) atom. Linkers: 2 [O]C(=O)c1ccc(C([O])=O)cc1 ,2 c1cncc(-c2ccc(OCCOc3ccc(-c4cccnc4)cc3)cc2)c1. Metal clusters: 1 O=[C]O[Cd]1O[C]O[Cd](O[C]=O)O[C]O1. The MOF has largest included sphere 5.27 A, density 1.24 g/cm3, surface area 4596.26 m2/g, accessible volume 0.40 cm3/g