CuC9H5O4CuC11H4O5(CH)6C2O is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules, eight dimethyl ether molecules, four CuC11H4O5 clusters, and four CuC9H5O4 clusters. In each CuC11H4O5 cluster, Cu(2) is bonded in a rectangular see-saw-like geometry to one O(1), one O(2), one O(6), and one O(7) atom. The Cu(2)-O(1) bond length is 2.02 Å. The Cu(2)-O(2) bond length is 2.02 Å. The Cu(2)-O(6) bond length is 2.02 Å. The Cu(2)-O(7) bond length is 2.03 Å. There are eleven inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(6), one C(9), and one H(1) atom. The C(4)-C(6) bond length is 1.45 Å. The C(4)-C(9) bond length is 1.42 Å. The C(4)-H(1) bond length is 0.96 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(5)-C(12) bond length is 1.52 Å. The C(5)-O(1) bond length is 1.30 Å. The C(5)-O(2) bond length is 1.31 Å. In the third C site, C(6) is bonded in a bent 120 degrees geometry to one C(11) and one C(4) atom. The C(6)-C(11) bond length is 1.43 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(12) and one H(2) atom. The C(7)-C(12) bond length is 1.45 Å. The C(7)-H(2) bond length is 0.96 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one O(5) atom. The C(8)-O(5) bond length is 1.41 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(20), one C(23), and one C(4) atom. The C(9)-C(20) bond length is 1.49 Å. The C(9)-C(23) bond length is 1.56 Å. In the seventh C site, C(12) is bonded in a trigonal planar geometry to one C(26), one C(5), and one C(7) atom. The C(12)-C(26) bond length is 1.44 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(6) and one O(5) atom. The C(11)-O(5) bond length is 1.43 Å. In the ninth C site, C(20) is bonded in a distorted single-bond geometry to one C(9) and one H(9) atom. The C(20)-H(9) bond length is 0.96 Å. In the tenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(6), and one O(7) atom. The C(23)-O(6) bond length is 1.31 Å. The C(23)-O(7) bond length is 1.28 Å. In the eleventh C site, C(26) is bonded in a distorted single-bond geometry to one C(12) and one H(13) atom. The C(26)-H(13) bond length is 0.97 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(20) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(26) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(5) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(5) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one C(11) and one C(8) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(23) atom. In the fifth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(23) atom. In each CuC9H5O4 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(3), one O(4), one O(8), and one O(9) atom. The Cu(1)-O(3) bond length is 2.01 Å. The Cu(1)-O(4) bond length is 2.07 Å. The Cu(1)-O(8) bond length is 2.09 Å. The Cu(1)-O(9) bond length is 1.98 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(2) atom. The C(1)-C(15) bond length is 1.47 Å. The C(1)-C(17) bond length is 1.40 Å. The C(1)-C(2) bond length is 1.53 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(3), and one O(4) atom. The C(2)-O(3) bond length is 1.30 Å. The C(2)-O(4) bond length is 1.31 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(13), one C(18), and one C(19) atom. The C(3)-C(13) bond length is 1.45 Å. The C(3)-C(18) bond length is 1.57 Å. The C(3)-C(19) bond length is 1.40 Å. In the fourth C site, C(13) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(13)-H(4) bond length is 0.96 Å. In the fifth C site, C(15) is bonded in a distorted single-bond geometry to one C(1) and one H(6) atom. The C(15)-H(6) bond length is 0.97 Å. In the sixth C site, C(17) is bonded in a distorted single-bond geometry to one C(1) and one H(7) atom. The C(17)-H(7) bond length is 0.96 Å. In the seventh C site, C(18) is bonded in a bent 120 degrees geometry to one C(3), one O(8), and one O(9) atom. The C(18)-O(8) bond length is 1.36 Å. The C(18)-O(9) bond length is 1.21 Å. In the eighth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(24), one C(3), and one H(8) atom. The C(19)-C(24) bond length is 1.41 Å. The C(19)-H(8) bond length is 0.96 Å. In the ninth C site, C(24) is bonded in a distorted single-bond geometry to one C(19) and one H(11) atom. The C(24)-H(11) bond length is 0.96 Å. There are five inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(15) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(24) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(19) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Cu(1) and one C(2) atom. In the third O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(18) atom. In the fourth O site, O(9) is bonded in a distorted single-bond geometry to one Cu(1) and one C(18) atom. Linkers: 4 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,4 [O]C(=O)c1c[c]c(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: pts. The MOF has largest included sphere 8.32 A, density 0.86 g/cm3, surface area 4430.30 m2/g, accessible volume 0.67 cm3/g