Cr6Mn3C60N12H36(O13Cl3)2(CH)12 crystallizes in the hexagonal P6_3/mcm space group. The structure consists of twenty-four 02329_fluka molecules inside a Cr6Mn3C60N12H36(O13Cl3)2 framework. In the Cr6Mn3C60N12H36(O13Cl3)2 framework, Cr(1) is bonded to one O(3), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing CrO5 square pyramids. The Cr(1)-O(3) bond length is 1.91 Å. Both Cr(1)-O(1) bond lengths are 1.96 Å. Both Cr(1)-O(2) bond lengths are 1.96 Å. Mn(1) is bonded in an octahedral geometry to four equivalent N(1) and two equivalent Cl(1) atoms. All Mn(1)-N(1) bond lengths are 2.30 Å. Both Mn(1)-Cl(1) bond lengths are 2.49 Å. There are five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(6) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(2) bond length is 0.95 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(6)-H(4) bond length is 0.95 Å. N(1) is bonded in a trigonal planar geometry to one Mn(1), one C(3), and one C(4) atom. There are three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cr(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cr(1) and one C(1) atom. In the third O site, O(3) is bonded in a trigonal planar geometry to three equivalent Cr(1) atoms. Cl(1) is bonded in a single-bond geometry to one Mn(1) atom. Linkers: 3 [O]C(=O)C1=CC=CN([Mn](Cl)(Cl)(N2[CH]C(C([O])=O)=CC=C2)(N2[CH]C(C([O])=O)=CC=C2)N2[CH]C=CC(C([O])=O)=C2)[CH]1 ,2 [O]C(=O)C1=CC=CN([Mn](Cl)(Cl)(N2[CH]C(C([O])=O)=CC=C2)(N2[CH]C(C([O])=O)=CC=C2)N2[CH]C(C([O])=O)=CC=C2)[CH]1 ,1 [O]C(=O)C1=CC=CN([Mn](Cl)(Cl)(N2[CH]C(C([O])=O)=CC=C2)(N2[CH]C=CC(C([O])=O)=C2)N2[CH]C=CC(C([O])=O)=C2)[CH]1. Metal clusters: 4 [C]1O[Cr]23O[C]O[Cr]45(O1)O[C]O[Cr](O[C]O2)(O[C]O3)(O[C]O4)O5. RCSR code: stp. The MOF has largest included sphere 14.68 A, density 0.79 g/cm3, surface area 3924.78 m2/g, accessible volume 0.82 cm3/g