Cu3C30H20(N3O4)2(CH)12 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules and four Cu3C30H20(N3O4)2 clusters. In each Cu3C30H20(N3O4)2 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(2), one O(1), and one O(3) atom. The Cu(1)-N(1) bond length is 1.99 Å. The Cu(1)-N(2) bond length is 2.01 Å. The Cu(1)-O(1) bond length is 1.94 Å. The Cu(1)-O(3) bond length is 1.97 Å. In the second Cu site, Cu(2) is bonded in a distorted octahedral geometry to two equivalent N(3), two equivalent O(2), and two equivalent O(3) atoms. Both Cu(2)-N(3) bond lengths are 1.99 Å. Both Cu(2)-O(2) bond lengths are 1.94 Å. Both Cu(2)-O(3) bond lengths are 2.58 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.94 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 0.94 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(4) bond length is 0.94 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.47 Å. The C(5)-N(1) bond length is 1.35 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-N(2) bond length is 1.35 Å. In the sixth C site, C(9) is bonded in a single-bond geometry to one C(10) and one H(7) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-H(7) bond length is 0.94 Å. In the seventh C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(8) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(8) bond length is 0.94 Å. In the eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(3), and one H(9) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-N(3) bond length is 1.34 Å. The C(11)-H(9) bond length is 0.94 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(12) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(12) bond length is 0.94 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(10) atom. The C(12)-C(13) bond length is 1.36 Å. The C(12)-H(10) bond length is 0.94 Å. In the eleventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(15), and one N(3) atom. The C(15)-C(15) bond length is 1.46 Å. The C(15)-N(3) bond length is 1.35 Å. In the twelfth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(16)-O(1) bond length is 1.25 Å. The C(16)-O(2) bond length is 1.27 Å. In the thirteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(19)-O(3) bond length is 1.28 Å. The C(19)-O(4) bond length is 1.24 Å. In the fourteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(13)-H(11) bond length is 0.94 Å. In the fifteenth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(7)-H(5) bond length is 0.94 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(2), one C(11), and one C(15) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the ninth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one C(16) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(16) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Cu(1), one Cu(2), and one C(19) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(19) atom. Linkers: 6 c1ccc(-c2ccccn2)nc1 ,7 [O]C(=O)/C=C/C=C/C([O])=O ,1 [O]C(=O)/C=C/C=C/[C]=O. Metal clusters: 4 O=[C]O[Cu]O[C]O[Cu]O[C]O[Cu]O[C]=O. The MOF has largest included sphere 4.73 A, density 1.18 g/cm3, surface area 4472.42 m2/g, accessible volume 0.47 cm3/g