Co10C41N3H42O19(CH3)3C6H5NH crystallizes in the cubic Pa-3 space group. The structure consists of twenty-four 02329_fluka molecules and eight C6H5NH clusters inside a Co10C41N3H42O19 framework. In each C6H5NH cluster, there are two inequivalent C sites. In the first C site, C(12) is bonded in a 1-coordinate geometry to one N(2) and one H(14) atom. The C(12)-N(2) bond length is 1.33 Å. The C(12)-H(14) bond length is 0.96 Å. In the second C site, C(13) is bonded in a distorted single-bond geometry to one N(2) and one H(15) atom. The C(13)-N(2) bond length is 1.35 Å. The C(13)-H(15) bond length is 0.96 Å. N(2) is bonded in a 6-coordinate geometry to three equivalent C(12) and three equivalent C(13) atoms. There are two inequivalent H sites. In the first H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(15) is bonded in a single-bond geometry to one C(13) atom. In the Co10C41N3H42O19 framework, there are four inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(2), one O(7), and two equivalent O(3) atoms to form CoO5 square pyramids that share  a cornercorner with one Co(2)O6 octahedra, edges with two equivalent Co(2)O6 octahedra,  an edgeedge with one Co(3)NO4 square pyramid, and edges with two equivalent Co(1)O5 square pyramids. The corner-sharing octahedral tilt angles are 1°. The Co(1)-O(1) bond length is 1.99 Å. The Co(1)-O(2) bond length is 2.06 Å. The Co(1)-O(7) bond length is 2.17 Å. There is one shorter (2.01 Å) and one longer (2.04 Å) Co(1)-O(3) bond length. In the second Co site, Co(2) is bonded to one O(1), one O(2), one O(5), one O(7), and two equivalent O(4) atoms to form CoO6 octahedra that share  a cornercorner with one Co(1)O5 square pyramid, edges with two equivalent Co(2)O6 octahedra, edges with two equivalent Co(3)NO4 square pyramids, and edges with two equivalent Co(1)O5 square pyramids. The Co(2)-O(1) bond length is 2.04 Å. The Co(2)-O(2) bond length is 2.06 Å. The Co(2)-O(5) bond length is 2.09 Å. The Co(2)-O(7) bond length is 2.18 Å. There is one shorter (2.01 Å) and one longer (2.08 Å) Co(2)-O(4) bond length. In the third Co site, Co(3) is bonded to one N(1), one O(1), one O(2), one O(4), and one O(6) atom to form CoNO4 square pyramids that share edges with two equivalent Co(2)O6 octahedra and  an edgeedge with one Co(1)O5 square pyramid. The Co(3)-N(1) bond length is 2.11 Å. The Co(3)-O(1) bond length is 2.11 Å. The Co(3)-O(2) bond length is 2.21 Å. The Co(3)-O(4) bond length is 2.13 Å. The Co(3)-O(6) bond length is 2.08 Å. In the fourth Co site, Co(4) is bonded in a 3-coordinate geometry to three equivalent O(3) atoms. All Co(4)-O(3) bond lengths are 2.16 Å. There are fifteen inequivalent C sites. In the first C site, C(17) is bonded in a tetrahedral geometry to one C(18) and three equivalent C(10) atoms. The C(17)-C(18) bond length is 1.55 Å. All C(17)-C(10) bond lengths are 1.56 Å. In the second C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.93 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one H(2) atom. The C(2)-C(5) bond length is 1.39 Å. The C(2)-H(2) bond length is 0.93 Å. In the fourth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(3)-N(1) bond length is 1.31 Å. The C(3)-H(3) bond length is 0.93 Å. In the fifth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(4) bond length is 0.93 Å. In the sixth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.54 Å. In the seventh C site, C(6) is bonded in a tetrahedral geometry to one C(5), one C(7), one C(8), and one C(9) atom. The C(6)-C(7) bond length is 1.56 Å. The C(6)-C(8) bond length is 1.56 Å. The C(6)-C(9) bond length is 1.56 Å. In the eighth C site, C(7) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one H(5), one H(6), and one O(1) atom. The C(7)-H(5) bond length is 0.97 Å. The C(7)-H(6) bond length is 0.97 Å. The C(7)-O(1) bond length is 1.43 Å. In the ninth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one H(7), one H(8), and one O(2) atom. The C(8)-H(7) bond length is 0.97 Å. The C(8)-H(8) bond length is 0.97 Å. The C(8)-O(2) bond length is 1.42 Å. In the tenth C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one C(6), one H(10), one H(9), and one O(3) atom. The C(9)-H(10) bond length is 0.97 Å. The C(9)-H(9) bond length is 0.97 Å. The C(9)-O(3) bond length is 1.42 Å. In the eleventh C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(17); two equivalent H(11,12); and one O(4) atom. Both C(10)-H(11,12) bond lengths are 0.97 Å. The C(10)-O(4) bond length is 1.42 Å. In the twelfth C site, C(11) is bonded in a distorted single-bond geometry to one C(18) and one H(13) atom. The C(11)-C(18) bond length is 1.39 Å. The C(11)-H(13) bond length is 0.96 Å. In the thirteenth C site, C(18) is bonded in a 7-coordinate geometry to one C(17), three equivalent C(11), and three equivalent C(14) atoms. All C(18)-C(14) bond lengths are 1.39 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(18) and one H(16) atom. The C(14)-H(16) bond length is 0.96 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(15)-O(5) bond length is 1.27 Å. The C(15)-O(6) bond length is 1.25 Å. N(1) is bonded in a trigonal planar geometry to one Co(3), one C(1), and one C(3) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(11,12) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(14) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Co(1), one Co(2), one Co(3), and one C(7) atom. In the second O site, O(2) is bonded in a distorted rectangular see-saw-like geometry to one Co(1), one Co(2), one Co(3), and one C(8) atom. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Co(4), two equivalent Co(1), and one C(9) atom. In the fourth O site, O(4) is bonded in a distorted rectangular see-saw-like geometry to one Co(3), two equivalent Co(2), and one C(10) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(15) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Co(3) and one C(15) atom. In the seventh O site, O(7) is bonded in an octahedral geometry to three equivalent Co(1) and three equivalent Co(2) atoms. Linkers: 24 [O]CC(C[O])(C[O])c1ccncc1 ,1 [C][C@@H]1[CH][C@@H]2[CH][C@H]([CH]1)[C@H]1[C@H]3[C@@H]2[C@@H]2[N@@]43[C@H]1[C@H]24.[O]C[C](C[O])C[O] ,1 [C]1[C@@H]2[CH][C@H]1[CH][C@H]([CH]2)[C@@H]1[C@@H]2[CH][C@H]3[N@]42[C@@H]1[C@@H]34.[O]C[C](C[O])C[O] ,1 [C][C@@H]1[CH][CH][CH][C@H]([CH]1)[C@H]1[C@H]2[CH][C@@H]3[N@@]42[C@H]1[C@H]34.[O]C[C](C[O])C[O] ,1 [C][C@@H]1[CH][CH][C@H]([CH][CH]1)[C@H]1[C@H]2[CH][C@@H]3[N@@]42[C@H]1[C@H]34.[O]C[C](C[O])C[O] ,1 [CH]1[C@@H]2[CH][C@H]3[N@]42[C@@H]1[C@@H]34.[CH]1[C@@H]2[CH][C@H]3[C]2[C@@H]1[CH]3.[O]C[C](C[O])C[O] ,1 [C]1[C@@H]2[CH][C@H]1[CH][C@H]([CH]2)[C@H]1[C@H]2[CH][C@@H]3[N@@]42[C@H]1[C@H]34.[O]C[C](C[O])C[O] ,1 [CH]1[C@@H]2[CH][C@H]3[N@]42[C@@H]1[C@@H]34.[O]CC([C]1[C@H]2[CH][CH][CH][C@@H]1[CH]2)(C[O])C[O] ,1 [CH]1[C@@H]([C@H]2[C]3[C@@H]1[CH][C@@H]23)[C@@H]1[C@@H]2[CH][C@H]3[N@]42[C@@H]1[C@@H]34.[O]C[C](C[O])C[O]. Metal clusters: 8 [CH2]O[Co](O[CH2])O[C](C)O[Co].[CH2]O[Co](O[CH2])O[C](C)O[Co].[CH2]O[Co](O[CH2])O[C](C)O[Co].[CH2]O[Co](O[CH2])O[Co](O[CH2])O[CH2].[CH2]O[Co]O[CH2].[Co]. The MOF has largest included sphere 7.97 A, density 1.15 g/cm3, surface area 2850.62 m2/g, accessible volume 0.48 cm3/g