Mn3C30(NO2)5 crystallizes in the monoclinic P2_1/c space group. There are six inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one N(7), one N(9), one O(1), one O(15), one O(20), and one O(4) atom to form corner-sharing MnN2O4 octahedra. The Mn(1)-N(7) bond length is 2.26 Å. The Mn(1)-N(9) bond length is 2.24 Å. The Mn(1)-O(1) bond length is 2.19 Å. The Mn(1)-O(15) bond length is 2.24 Å. The Mn(1)-O(20) bond length is 2.14 Å. The Mn(1)-O(4) bond length is 2.14 Å. In the second Mn site, Mn(2) is bonded to one N(3), one N(5), one O(12), one O(16), one O(2), and one O(3) atom to form corner-sharing MnN2O4 octahedra. The Mn(2)-N(3) bond length is 2.26 Å. The Mn(2)-N(5) bond length is 2.29 Å. The Mn(2)-O(12) bond length is 2.10 Å. The Mn(2)-O(16) bond length is 2.18 Å. The Mn(2)-O(2) bond length is 2.33 Å. The Mn(2)-O(3) bond length is 2.10 Å. In the third Mn site, Mn(3) is bonded to one N(2), one O(11), one O(15), one O(19), and one O(2) atom to form corner-sharing MnNO4 square pyramids. The corner-sharing octahedral tilt angles range from 69-74°. The Mn(3)-N(2) bond length is 2.31 Å. The Mn(3)-O(11) bond length is 2.13 Å. The Mn(3)-O(15) bond length is 2.23 Å. The Mn(3)-O(19) bond length is 2.11 Å. The Mn(3)-O(2) bond length is 2.23 Å. In the fourth Mn site, Mn(4) is bonded to one N(4), one O(10), one O(14), one O(17), and one O(6) atom to form corner-sharing MnNO4 square pyramids. The corner-sharing octahedral tilt angles range from 69-75°. The Mn(4)-N(4) bond length is 2.31 Å. The Mn(4)-O(10) bond length is 2.09 Å. The Mn(4)-O(14) bond length is 2.22 Å. The Mn(4)-O(17) bond length is 2.11 Å. The Mn(4)-O(6) bond length is 2.23 Å. In the fifth Mn site, Mn(5) is bonded to one N(1), one N(10), one O(13), one O(6), one O(8), and one O(9) atom to form corner-sharing MnN2O4 octahedra. The Mn(5)-N(1) bond length is 2.27 Å. The Mn(5)-N(10) bond length is 2.27 Å. The Mn(5)-O(13) bond length is 2.17 Å. The Mn(5)-O(6) bond length is 2.24 Å. The Mn(5)-O(8) bond length is 2.13 Å. The Mn(5)-O(9) bond length is 2.15 Å. In the sixth Mn site, Mn(6) is bonded to one N(6), one N(8), one O(14), one O(18), one O(5), and one O(7) atom to form corner-sharing MnN2O4 octahedra. The Mn(6)-N(6) bond length is 2.27 Å. The Mn(6)-N(8) bond length is 2.25 Å. The Mn(6)-O(14) bond length is 2.34 Å. The Mn(6)-O(18) bond length is 2.12 Å. The Mn(6)-O(5) bond length is 2.17 Å. The Mn(6)-O(7) bond length is 2.12 Å. There are sixty inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one C(2) and one N(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-N(1) bond length is 1.36 Å. In the second C site, C(2) is bonded in a bent 120 degrees geometry to one C(1) and one C(5) atom. The C(2)-C(5) bond length is 1.39 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(4) and one N(1) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-N(1) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a bent 120 degrees geometry to one C(3) and one C(5) atom. The C(4)-C(5) bond length is 1.38 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.50 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.24 Å. The C(6)-O(2) bond length is 1.29 Å. In the seventh C site, C(7) is bonded in a single-bond geometry to one C(8) and one N(2) atom. The C(7)-C(8) bond length is 1.37 Å. The C(7)-N(2) bond length is 1.33 Å. In the eighth C site, C(8) is bonded in a bent 120 degrees geometry to one C(11) and one C(7) atom. The C(8)-C(11) bond length is 1.39 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one N(2) atom. The C(9)-C(10) bond length is 1.37 Å. The C(9)-N(2) bond length is 1.35 Å. In the tenth C site, C(10) is bonded in a bent 120 degrees geometry to one C(11) and one C(9) atom. The C(10)-C(11) bond length is 1.38 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(8) atom. The C(11)-C(12) bond length is 1.51 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(3), and one O(4) atom. The C(12)-O(3) bond length is 1.25 Å. The C(12)-O(4) bond length is 1.26 Å. In the thirteenth C site, C(13) is bonded in a single-bond geometry to one C(14) and one N(3) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-N(3) bond length is 1.34 Å. In the fourteenth C site, C(14) is bonded in a bent 120 degrees geometry to one C(13) and one C(17) atom. The C(14)-C(17) bond length is 1.39 Å. In the fifteenth C site, C(15) is bonded in a single-bond geometry to one C(16) and one N(3) atom. The C(15)-C(16) bond length is 1.35 Å. The C(15)-N(3) bond length is 1.35 Å. In the sixteenth C site, C(16) is bonded in a bent 120 degrees geometry to one C(15) and one C(17) atom. The C(16)-C(17) bond length is 1.39 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(17)-C(18) bond length is 1.50 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(5), and one O(6) atom. The C(18)-O(5) bond length is 1.26 Å. The C(18)-O(6) bond length is 1.28 Å. In the nineteenth C site, C(19) is bonded in a single-bond geometry to one C(20) and one N(4) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-N(4) bond length is 1.35 Å. In the twentieth C site, C(20) is bonded in a bent 120 degrees geometry to one C(19) and one C(23) atom. The C(20)-C(23) bond length is 1.38 Å. In the twenty-first C site, C(21) is bonded in a single-bond geometry to one C(22) and one N(4) atom. The C(21)-C(22) bond length is 1.36 Å. The C(21)-N(4) bond length is 1.34 Å. In the twenty-second C site, C(22) is bonded in a bent 120 degrees geometry to one C(21) and one C(23) atom. The C(22)-C(23) bond length is 1.39 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(23)-C(24) bond length is 1.52 Å. In the twenty-fourth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(7), and one O(8) atom. The C(24)-O(7) bond length is 1.27 Å. The C(24)-O(8) bond length is 1.26 Å. In the twenty-fifth C site, C(25) is bonded in a single-bond geometry to one C(26) and one N(5) atom. The C(25)-C(26) bond length is 1.38 Å. The C(25)-N(5) bond length is 1.34 Å. In the twenty-sixth C site, C(26) is bonded in a bent 120 degrees geometry to one C(25) and one C(29) atom. The C(26)-C(29) bond length is 1.39 Å. In the twenty-seventh C site, C(27) is bonded in a single-bond geometry to one C(28) and one N(5) atom. The C(27)-C(28) bond length is 1.37 Å. The C(27)-N(5) bond length is 1.34 Å. In the twenty-eighth C site, C(28) is bonded in a bent 120 degrees geometry to one C(27) and one C(29) atom. The C(28)-C(29) bond length is 1.39 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(30) atom. The C(29)-C(30) bond length is 1.52 Å. In the thirtieth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(10), and one O(9) atom. The C(30)-O(10) bond length is 1.25 Å. The C(30)-O(9) bond length is 1.26 Å. In the thirty-first C site, C(31) is bonded in a single-bond geometry to one C(32) and one N(6) atom. The C(31)-C(32) bond length is 1.37 Å. The C(31)-N(6) bond length is 1.36 Å. In the thirty-second C site, C(32) is bonded in a bent 120 degrees geometry to one C(31) and one C(35) atom. The C(32)-C(35) bond length is 1.39 Å. In the thirty-third C site, C(33) is bonded in a single-bond geometry to one C(34) and one N(6) atom. The C(33)-C(34) bond length is 1.37 Å. The C(33)-N(6) bond length is 1.37 Å. In the thirty-fourth C site, C(34) is bonded in a bent 120 degrees geometry to one C(33) and one C(35) atom. The C(34)-C(35) bond length is 1.40 Å. In the thirty-fifth C site, C(35) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(36) atom. The C(35)-C(36) bond length is 1.50 Å. In the thirty-sixth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(11), and one O(12) atom. The C(36)-O(11) bond length is 1.26 Å. The C(36)-O(12) bond length is 1.26 Å. In the thirty-seventh C site, C(37) is bonded in a single-bond geometry to one C(38) and one N(7) atom. The C(37)-C(38) bond length is 1.37 Å. The C(37)-N(7) bond length is 1.35 Å. In the thirty-eighth C site, C(38) is bonded in a bent 120 degrees geometry to one C(37) and one C(41) atom. The C(38)-C(41) bond length is 1.39 Å. In the thirty-ninth C site, C(39) is bonded in a single-bond geometry to one C(40) and one N(7) atom. The C(39)-C(40) bond length is 1.38 Å. The C(39)-N(7) bond length is 1.36 Å. In the fortieth C site, C(40) is bonded in a bent 120 degrees geometry to one C(39) and one C(41) atom. The C(40)-C(41) bond length is 1.40 Å. In the forty-first C site, C(41) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(42) atom. The C(41)-C(42) bond length is 1.50 Å. In the forty-second C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(41), one O(13), and one O(14) atom. The C(42)-O(13) bond length is 1.24 Å. The C(42)-O(14) bond length is 1.29 Å. In the forty-third C site, C(43) is bonded in a single-bond geometry to one C(44) and one N(8) atom. The C(43)-C(44) bond length is 1.39 Å. The C(43)-N(8) bond length is 1.33 Å. In the forty-fourth C site, C(44) is bonded in a bent 120 degrees geometry to one C(43) and one C(47) atom. The C(44)-C(47) bond length is 1.40 Å. In the forty-fifth C site, C(45) is bonded in a single-bond geometry to one C(46) and one N(8) atom. The C(45)-C(46) bond length is 1.38 Å. The C(45)-N(8) bond length is 1.35 Å. In the forty-sixth C site, C(46) is bonded in a bent 120 degrees geometry to one C(45) and one C(47) atom. The C(46)-C(47) bond length is 1.39 Å. In the forty-seventh C site, C(47) is bonded in a trigonal planar geometry to one C(44), one C(46), and one C(60) atom. The C(47)-C(60) bond length is 1.40 Å. In the forty-eighth C site, C(48) is bonded in a single-bond geometry to one C(49) and one N(9) atom. The C(48)-C(49) bond length is 1.39 Å. The C(48)-N(9) bond length is 1.35 Å. In the forty-ninth C site, C(49) is bonded in a bent 120 degrees geometry to one C(48) and one C(52) atom. The C(49)-C(52) bond length is 1.39 Å. In the fiftieth C site, C(50) is bonded in a distorted single-bond geometry to one C(51) and one N(9) atom. The C(50)-C(51) bond length is 1.37 Å. The C(50)-N(9) bond length is 1.36 Å. In the fifty-first C site, C(51) is bonded in a bent 120 degrees geometry to one C(50) and one C(52) atom. The C(51)-C(52) bond length is 1.40 Å. In the fifty-second C site, C(52) is bonded in a trigonal planar geometry to one C(49), one C(51), and one C(53) atom. The C(52)-C(53) bond length is 1.51 Å. In the fifty-third C site, C(53) is bonded in a distorted bent 120 degrees geometry to one C(52), one O(17), and one O(18) atom. The C(53)-O(17) bond length is 1.27 Å. The C(53)-O(18) bond length is 1.25 Å. In the fifty-fourth C site, C(54) is bonded in a distorted single-bond geometry to one C(55) and one N(10) atom. The C(54)-C(55) bond length is 1.37 Å. The C(54)-N(10) bond length is 1.37 Å. In the fifty-fifth C site, C(55) is bonded in a bent 120 degrees geometry to one C(54) and one C(58) atom. The C(55)-C(58) bond length is 1.39 Å. In the fifty-sixth C site, C(56) is bonded in a distorted single-bond geometry to one C(57) and one N(10) atom. The C(56)-C(57) bond length is 1.38 Å. The C(56)-N(10) bond length is 1.34 Å. In the fifty-seventh C site, C(57) is bonded in a bent 120 degrees geometry to one C(56) and one C(58) atom. The C(57)-C(58) bond length is 1.40 Å. In the fifty-eighth C site, C(58) is bonded in a trigonal planar geometry to one C(55), one C(57), and one C(59) atom. The C(58)-C(59) bond length is 1.51 Å. In the fifty-ninth C site, C(59) is bonded in a distorted bent 120 degrees geometry to one C(58), one O(19), and one O(20) atom. The C(59)-O(19) bond length is 1.27 Å. The C(59)-O(20) bond length is 1.24 Å. In the sixtieth C site, C(60) is bonded in a distorted bent 120 degrees geometry to one C(47), one O(15), and one O(16) atom. The C(60)-O(15) bond length is 1.34 Å. The C(60)-O(16) bond length is 1.29 Å. There are ten inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(5), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(3), one C(7), and one C(9) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Mn(2), one C(13), and one C(15) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Mn(4), one C(19), and one C(21) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Mn(2), one C(25), and one C(27) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Mn(6), one C(31), and one C(33) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Mn(1), one C(37), and one C(39) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Mn(6), one C(43), and one C(45) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Mn(1), one C(48), and one C(50) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Mn(5), one C(54), and one C(56) atom. There are twenty inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(6) atom. In the second O site, O(2) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one Mn(3), and one C(6) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(2) and one C(12) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(12) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(6) and one C(18) atom. In the sixth O site, O(6) is bonded in a distorted trigonal planar geometry to one Mn(4), one Mn(5), and one C(18) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Mn(6) and one C(24) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Mn(5) and one C(24) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Mn(5) and one C(30) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Mn(4) and one C(30) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Mn(3) and one C(36) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(36) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Mn(5) and one C(42) atom. In the fourteenth O site, O(14) is bonded in a distorted trigonal non-coplanar geometry to one Mn(4), one Mn(6), and one C(42) atom. In the fifteenth O site, O(15) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one C(60) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(60) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Mn(4) and one C(53) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Mn(6) and one C(53) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Mn(3) and one C(59) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(59) atom. Linkers: 40 [O]C(=O)c1[c][c]n[c][c]1. Metal clusters: 8 [C]1O[Mn]2O[C]O[Mn]3(O[C]O2)O[C]O[Mn](O1)O[C]O3. The MOF has largest included sphere 6.56 A, density 1.09 g/cm3, surface area 3768.79 m2/g, accessible volume 0.39 cm3/g