LaMo2C6NH4O9CH crystallizes in the triclinic P-1 space group. The structure consists of four 02329_fluka molecules inside a LaMo2C6NH4O9 framework. In the LaMo2C6NH4O9 framework, there are two inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one N(1), one O(1), one O(14), one O(4), one O(6), one O(8), one O(9), and two equivalent O(3) atoms. The La(1)-N(1) bond length is 2.73 Å. The La(1)-O(1) bond length is 2.58 Å. The La(1)-O(14) bond length is 2.66 Å. The La(1)-O(4) bond length is 2.84 Å. The La(1)-O(6) bond length is 2.45 Å. The La(1)-O(8) bond length is 2.55 Å. The La(1)-O(9) bond length is 2.52 Å. There is one shorter (2.60 Å) and one longer (2.63 Å) La(1)-O(3) bond length. In the second La site, La(2) is bonded in a 6-coordinate geometry to one N(2), one H(2), one O(18), one O(2), one O(5), and one O(7) atom. The La(2)-N(2) bond length is 2.64 Å. The La(2)-H(2) bond length is 2.50 Å. The La(2)-O(18) bond length is 2.58 Å. The La(2)-O(2) bond length is 2.53 Å. The La(2)-O(5) bond length is 2.52 Å. The La(2)-O(7) bond length is 2.52 Å. There are four inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a 4-coordinate geometry to one O(10), one O(11), one O(12), and one O(13) atom. The Mo(1)-O(10) bond length is 2.46 Å. The Mo(1)-O(11) bond length is 1.92 Å. The Mo(1)-O(12) bond length is 1.93 Å. The Mo(1)-O(13) bond length is 2.30 Å. In the second Mo site, Mo(2) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(14), one O(15), and one O(16) atom. The Mo(2)-O(10) bond length is 2.33 Å. The Mo(2)-O(11) bond length is 1.89 Å. The Mo(2)-O(14) bond length is 1.71 Å. The Mo(2)-O(15) bond length is 2.35 Å. The Mo(2)-O(16) bond length is 1.99 Å. In the third Mo site, Mo(3) is bonded in a 5-coordinate geometry to one O(10), one O(12), one O(15), one O(16), and one O(9) atom. The Mo(3)-O(10) bond length is 2.26 Å. The Mo(3)-O(12) bond length is 1.89 Å. The Mo(3)-O(15) bond length is 1.97 Å. The Mo(3)-O(16) bond length is 2.35 Å. The Mo(3)-O(9) bond length is 1.72 Å. In the fourth Mo site, Mo(4) is bonded in a 5-coordinate geometry to one O(13), one O(15), one O(16), and two equivalent O(10) atoms. The Mo(4)-O(13) bond length is 1.74 Å. The Mo(4)-O(15) bond length is 1.95 Å. The Mo(4)-O(16) bond length is 1.94 Å. There is one shorter (2.18 Å) and one longer (2.41 Å) Mo(4)-O(10) bond length. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-C(6) bond length is 1.51 Å. The C(1)-N(1) bond length is 1.33 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(2)-H(5) bond length is 0.93 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(7) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(7) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(7), and one N(1) atom. The C(5)-C(7) bond length is 1.49 Å. The C(5)-N(1) bond length is 1.34 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(6)-O(1) bond length is 1.25 Å. The C(6)-O(2) bond length is 1.26 Å. In the sixth C site, C(7) is bonded in a bent 120 degrees geometry to one C(5), one O(3), and one O(4) atom. The C(7)-O(3) bond length is 1.27 Å. The C(7)-O(4) bond length is 1.25 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one N(2) atom. The C(8)-C(13) bond length is 1.52 Å. The C(8)-C(9) bond length is 1.38 Å. The C(8)-N(2) bond length is 1.34 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(9)-H(8) bond length is 0.93 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(10) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(10) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(14), and one N(2) atom. The C(12)-C(14) bond length is 1.51 Å. The C(12)-N(2) bond length is 1.32 Å. In the eleventh C site, C(13) is bonded in a bent 120 degrees geometry to one C(8), one O(7), and one O(8) atom. The C(13)-O(7) bond length is 1.26 Å. The C(13)-O(8) bond length is 1.24 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(5), and one O(6) atom. The C(14)-O(5) bond length is 1.26 Å. The C(14)-O(6) bond length is 1.24 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one La(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one La(2), one C(12), and one C(8) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(17) atom. The H(1)-O(17) bond length is 0.83 Å. In the second H site, H(2) is bonded in a single-bond geometry to one La(2) and one O(17) atom. The H(2)-O(17) bond length is 0.73 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(18) atom. The H(3)-O(18) bond length is 0.93 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(18) atom. The H(4)-O(18) bond length is 1.02 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(11) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one La(1) and one C(6) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one La(2) and one C(6) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent La(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one La(1) and one C(7) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one La(2) and one C(14) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one La(1) and one C(14) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one La(2) and one C(13) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one La(1) and one C(13) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one La(1) and one Mo(3) atom. In the tenth O site, O(10) is bonded to one Mo(1), one Mo(2), one Mo(3), and two equivalent Mo(4) atoms to form distorted edge-sharing OMo5 square pyramids. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(2) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Mo(1) and one Mo(3) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Mo(1) and one Mo(4) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one La(1) and one Mo(2) atom. In the fifteenth O site, O(15) is bonded in a trigonal non-coplanar geometry to one Mo(2), one Mo(3), and one Mo(4) atom. In the sixteenth O site, O(16) is bonded in a trigonal non-coplanar geometry to one Mo(2), one Mo(3), and one Mo(4) atom. In the seventeenth O site, O(17) is bonded in a distorted water-like geometry to one H(1) and one H(2) atom. In the eighteenth O site, O(18) is bonded in a water-like geometry to one La(2), one H(3), and one H(4) atom. Linkers: 4 [O]C(=O)c1cccc(C([O])=O)n1. Metal clusters: 4 [La] ,8 [Mo]. The MOF has largest included sphere 5.75 A, density 2.17 g/cm3, surface area 2274.20 m2/g, accessible volume 0.19 cm3/g