ZnC18H12(N3O2)2C11H7CHNNC5H4NC9H6N is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules, four schembl1705614 molecules, four C11H7 clusters, four NNC5H4N clusters, and four ZnC18H12(N3O2)2 clusters. In each C11H7 cluster, there are eleven inequivalent C sites. In the first C site, C(39) is bonded in a trigonal planar geometry to one C(36), one C(40), and one C(44) atom. The C(39)-C(36) bond length is 1.49 Å. The C(39)-C(40) bond length is 1.39 Å. The C(39)-C(44) bond length is 1.40 Å. In the second C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one H(27) atom. The C(40)-H(27) bond length is 0.93 Å. In the third C site, C(37) is bonded in a distorted single-bond geometry to one C(36) and one H(25) atom. The C(37)-C(36) bond length is 1.40 Å. The C(37)-H(25) bond length is 0.93 Å. In the fourth C site, C(42) is bonded in a single-bond geometry to one C(43) and one H(29) atom. The C(42)-C(43) bond length is 1.39 Å. The C(42)-H(29) bond length is 0.93 Å. In the fifth C site, C(43) is bonded in a trigonal planar geometry to one C(30), one C(42), and one C(44) atom. The C(43)-C(30) bond length is 1.49 Å. The C(43)-C(44) bond length is 1.39 Å. In the sixth C site, C(44) is bonded in a distorted single-bond geometry to one C(39), one C(43), and one H(30) atom. The C(44)-H(30) bond length is 0.93 Å. In the seventh C site, C(29) is bonded in a single-bond geometry to one C(30) and one H(20,21) atom. The C(29)-C(30) bond length is 1.39 Å. The C(29)-H(20,21) bond length is 0.93 Å. In the eighth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(43) atom. The C(30)-C(31) bond length is 1.39 Å. In the ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(20,21) atom. The C(31)-H(20,21) bond length is 0.93 Å. In the tenth C site, C(35) is bonded in a distorted single-bond geometry to one C(36) and one H(24) atom. The C(35)-C(36) bond length is 1.41 Å. The C(35)-H(24) bond length is 0.93 Å. In the eleventh C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(39) atom. There are six inequivalent H sites. In the first H site, H(29) is bonded in a single-bond geometry to one C(42) atom. In the second H site, H(30) is bonded in a single-bond geometry to one C(44) atom. In the third H site, H(27) is bonded in a single-bond geometry to one C(40) atom. In the fourth H site, H(20,21) is bonded in a single-bond geometry to one C(29) atom. In the fifth H site, H(24) is bonded in a single-bond geometry to one C(35) atom. In the sixth H site, H(25) is bonded in a single-bond geometry to one C(37) atom. In each NNC5H4N cluster, there are five inequivalent C sites. In the first C site, C(5) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(5) atom. The C(5)-N(7) bond length is 1.32 Å. The C(5)-N(8) bond length is 1.35 Å. The C(5)-H(5) bond length is 0.93 Å. In the second C site, C(6) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(6) atom. The C(6)-N(7) bond length is 1.34 Å. The C(6)-N(9) bond length is 1.33 Å. The C(6)-H(6) bond length is 0.93 Å. In the third C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(16) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(16) bond length is 0.93 Å. In the fourth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one N(8) atom. The C(22)-C(23) bond length is 1.38 Å. The C(22)-N(8) bond length is 1.41 Å. In the fifth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(17) atom. The C(23)-H(17) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(7) is bonded in a water-like geometry to one C(5) and one C(6) atom. In the second N site, N(8) is bonded in a 3-coordinate geometry to one C(22), one C(5), and one N(9) atom. The N(8)-N(9) bond length is 1.36 Å. In the third N site, N(9) is bonded in a distorted water-like geometry to one C(6) and one N(8) atom. There are four inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In each ZnC18H12(N3O2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(4), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 2.00 Å. The Zn(1)-N(4) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 1.92 Å. The Zn(1)-O(3) bond length is 1.96 Å. There are eighteen inequivalent C sites. In the first C site, C(7) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one N(2) atom. The C(7)-C(12) bond length is 1.38 Å. The C(7)-C(8) bond length is 1.39 Å. The C(7)-N(2) bond length is 1.43 Å. In the second C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(8)-H(7) bond length is 0.93 Å. In the third C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(10) atom. The C(12)-H(10) bond length is 0.93 Å. In the fourth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one N(5) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(18) bond length is 1.38 Å. The C(13)-N(5) bond length is 1.43 Å. In the fifth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(14)-H(11) bond length is 0.93 Å. In the sixth C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(14) atom. The C(18)-H(14) bond length is 0.93 Å. In the seventh C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(1), and one O(2) atom. The C(25)-C(27) bond length is 1.52 Å. The C(25)-O(1) bond length is 1.29 Å. The C(25)-O(2) bond length is 1.21 Å. In the eighth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(33), one O(3), and one O(4) atom. The C(26)-C(33) bond length is 1.51 Å. The C(26)-O(3) bond length is 1.29 Å. The C(26)-O(4) bond length is 1.24 Å. In the ninth C site, C(27) is bonded in a trigonal planar geometry to one C(25), one C(28), and one C(32) atom. The C(27)-C(28) bond length is 1.38 Å. The C(27)-C(32) bond length is 1.38 Å. In the tenth C site, C(28) is bonded in a distorted single-bond geometry to one C(27) and one H(19) atom. The C(28)-H(19) bond length is 0.93 Å. In the eleventh C site, C(32) is bonded in a distorted single-bond geometry to one C(27) and one H(22) atom. The C(32)-H(22) bond length is 0.93 Å. In the twelfth C site, C(33) is bonded in a trigonal planar geometry to one C(26), one C(34), and one C(38) atom. The C(33)-C(34) bond length is 1.40 Å. The C(33)-C(38) bond length is 1.40 Å. In the thirteenth C site, C(34) is bonded in a distorted single-bond geometry to one C(33) and one H(23) atom. The C(34)-H(23) bond length is 0.93 Å. In the fourteenth C site, C(38) is bonded in a distorted single-bond geometry to one C(33) and one H(26) atom. The C(38)-H(26) bond length is 0.93 Å. In the fifteenth C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.93 Å. In the sixteenth C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(3) bond length is 1.31 Å. The C(2)-H(2) bond length is 0.93 Å. In the seventeenth C site, C(3) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(3) atom. The C(3)-N(4) bond length is 1.32 Å. The C(3)-N(5) bond length is 1.33 Å. The C(3)-H(3) bond length is 0.93 Å. In the eighteenth C site, C(4) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(4) atom. The C(4)-N(4) bond length is 1.38 Å. The C(4)-N(6) bond length is 1.31 Å. The C(4)-H(4) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one C(1), one C(7), and one N(3) atom. The N(2)-N(3) bond length is 1.37 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(2) and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(3), and one C(4) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(13), one C(3), and one N(6) atom. The N(5)-N(6) bond length is 1.38 Å. In the sixth N site, N(6) is bonded in a distorted water-like geometry to one C(4) and one N(5) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(28) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(32) atom. In the eleventh H site, H(23) is bonded in a single-bond geometry to one C(34) atom. In the twelfth H site, H(26) is bonded in a single-bond geometry to one C(38) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(25) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(26) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(26) atom. Linkers: 1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[N].[CH]=[N].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#N.[C]/C=C\[C]([C])[N][C].[C]/[C]=[C]\[CH][C].[C]/[C]=[C]\[CH][C].[C]1=NN=[C][N]1.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]C(=[CH])N([C])[N]C=[N].[C][CH].[C][CH]/[C]=C\[C]=[C]\N([C])[N].[C][C].[C][C].[C][C].[C][C].[C][C].[C][C]=[C].[C][C][N][N][C][N].[C][N].[C][N].[C][N][N].[C][N][N].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][Zn].[O][Zn].[O][Zn].[O][Zn][O].[Zn].[Zn].[Zn].[c]1[c][c][c][c][c]1.[c]1[c][c]cc[c]1 ,1 [N]c1ccc(N2[CH]N([Zn](OC(=O)c3ccc(-c4cccc(-c5ccc(C([O])=O)cc5)c4)cc3)(OC(=O)c3ccc(-c4cccc(-c5ccc(C([O])=O)cc5)c4)cc3)N3[CH]N(c4ccc(N(c5cc[c]cc5)c5ccc(N6[CH]N=C[N]6)cc5)cc4)N=C3)C=N2)cc1 ,1 [CH]=[C]c1cccc(-c2ccc(C(=O)O[Zn](OC(=O)C(=[CH])C=[CH])(N3[CH]N(c4ccc(N(c5ccc(N6[CH]N=C[N]6)cc5)c5ccc(N6[CH]N=C[N]6)cc5)cc4)N=C3)N3[CH]N(c4ccc(N(c5ccc(N6[CH]N=C[N]6)cc5)c5ccc(N6[CH]N=C[N]6)cc5)cc4)N=C3)cc2)c1. Metal clusters: 1 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.85 A, density 1.29 g/cm3, surface area 4930.45 m2/g, accessible volume 0.33 cm3/g