NaCd2H14(C5O2)6CdC22N4H18Cl crystallizes in the triclinic P-1 space group. The structure consists of one CdC22N4H18Cl cluster inside a NaCd2H14(C5O2)6 framework. In the CdC22N4H18Cl cluster, Cd(3) is bonded in a 6-coordinate geometry to one Cd(3), two equivalent N(1), two equivalent N(2), and one Cl(1) atom. The Cd(3)-Cd(3) bond length is 2.14 Å. There is one shorter (2.27 Å) and one longer (2.47 Å) Cd(3)-N(1) bond length. Both Cd(3)-N(2) bond lengths are 2.30 Å. The Cd(3)-Cl(1) bond length is 2.54 Å. There are twenty-two inequivalent C sites. In the first C site, C(31) is bonded in a tetrahedral geometry to one N(4); one H(16); and two equivalent H(15,17) atoms. The C(31)-N(4) bond length is 1.46 Å. The C(31)-H(16) bond length is 0.96 Å. Both C(31)-H(15,17) bond lengths are 0.96 Å. In the second C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(18) atom. The C(32)-N(4) bond length is 1.27 Å. The C(32)-H(18) bond length is 0.93 Å. In the third C site, C(33) is bonded in a distorted single-bond geometry to one C(34) and one H(19) atom. The C(33)-C(34) bond length is 1.33 Å. The C(33)-H(19) bond length is 0.93 Å. In the fourth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(37) atom. The C(34)-C(35) bond length is 1.52 Å. The C(34)-C(37) bond length is 1.52 Å. In the fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(34), one C(36), and one H(20) atom. The C(35)-C(36) bond length is 1.34 Å. The C(35)-H(20) bond length is 0.93 Å. In the sixth C site, C(36) is bonded in a distorted bent 120 degrees geometry to one C(35), one N(4), and one H(21) atom. The C(36)-N(4) bond length is 1.27 Å. The C(36)-H(21) bond length is 0.93 Å. In the seventh C site, C(37) is bonded in a trigonal planar geometry to one C(34), one C(38), and one C(42) atom. The C(37)-C(38) bond length is 1.43 Å. The C(37)-C(42) bond length is 1.41 Å. In the eighth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(37), one C(39), and one N(1) atom. The C(38)-C(39) bond length is 1.46 Å. The C(38)-N(1) bond length is 1.33 Å. In the ninth C site, C(39) is bonded in a distorted single-bond geometry to one C(38) and one H(22) atom. The C(39)-H(22) bond length is 0.93 Å. In the tenth C site, C(40) is bonded in a distorted single-bond geometry to one C(41) and one H(23) atom. The C(40)-C(41) bond length is 1.44 Å. The C(40)-H(23) bond length is 0.93 Å. In the eleventh C site, C(41) is bonded in a distorted trigonal planar geometry to one C(40), one C(46), and one N(1) atom. The C(41)-C(46) bond length is 1.42 Å. The C(41)-N(1) bond length is 1.38 Å. In the twelfth C site, C(42) is bonded in a distorted trigonal planar geometry to one C(37), one C(43), and one N(2) atom. The C(42)-C(43) bond length is 1.44 Å. The C(42)-N(2) bond length is 1.44 Å. In the thirteenth C site, C(43) is bonded in a distorted single-bond geometry to one C(42) and one H(24) atom. The C(43)-H(24) bond length is 0.93 Å. In the fourteenth C site, C(44) is bonded in a distorted single-bond geometry to one C(45) and one H(25) atom. The C(44)-C(45) bond length is 1.45 Å. The C(44)-H(25) bond length is 0.93 Å. In the fifteenth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(44), one C(46), and one N(2) atom. The C(45)-C(46) bond length is 1.39 Å. The C(45)-N(2) bond length is 1.44 Å. In the sixteenth C site, C(46) is bonded in a trigonal planar geometry to one C(41), one C(45), and one C(47) atom. The C(46)-C(47) bond length is 1.53 Å. In the seventeenth C site, C(47) is bonded in a trigonal planar geometry to one C(46), one C(48), and one C(50) atom. The C(47)-C(48) bond length is 1.37 Å. The C(47)-C(50) bond length is 1.45 Å. In the eighteenth C site, C(48) is bonded in a distorted single-bond geometry to one C(47) and one H(26) atom. The C(48)-H(26) bond length is 0.93 Å. In the nineteenth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(27) atom. The C(49)-N(3) bond length is 1.30 Å. The C(49)-H(27) bond length is 0.93 Å. In the twentieth C site, C(50) is bonded in a distorted single-bond geometry to one C(47), one C(51), and one H(28) atom. The C(50)-C(51) bond length is 1.36 Å. The C(50)-H(28) bond length is 0.93 Å. In the twenty-first C site, C(51) is bonded in a distorted trigonal planar geometry to one C(50), one N(3), and one H(29) atom. The C(51)-N(3) bond length is 1.35 Å. The C(51)-H(29) bond length is 0.93 Å. In the twenty-second C site, C(52) is bonded in a tetrahedral geometry to one N(3); one H(30); and two equivalent H(31,32) atoms. The C(52)-N(3) bond length is 1.50 Å. The C(52)-H(30) bond length is 0.96 Å. Both C(52)-H(31,32) bond lengths are 0.96 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a 4-coordinate geometry to two equivalent Cd(3), one C(38), and one C(41) atom. In the second N site, N(2) is bonded in a 4-coordinate geometry to two equivalent Cd(3), one C(42), and one C(45) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(49), one C(51), and one C(52) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(31), one C(32), and one C(36) atom. There are sixteen inequivalent H sites. In the first H site, H(15,17) is bonded in a single-bond geometry to one C(31) atom. In the second H site, H(16) is bonded in a single-bond geometry to one C(31) atom. In the third H site, H(18) is bonded in a single-bond geometry to one C(32) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(33) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one C(35) atom. In the sixth H site, H(21) is bonded in a single-bond geometry to one C(36) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one C(39) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(40) atom. In the ninth H site, H(24) is bonded in a single-bond geometry to one C(43) atom. In the tenth H site, H(25) is bonded in a single-bond geometry to one C(44) atom. In the eleventh H site, H(26) is bonded in a single-bond geometry to one C(48) atom. In the twelfth H site, H(27) is bonded in a single-bond geometry to one C(49) atom. In the thirteenth H site, H(28) is bonded in a single-bond geometry to one C(50) atom. In the fourteenth H site, H(29) is bonded in a single-bond geometry to one C(51) atom. In the fifteenth H site, H(30) is bonded in a single-bond geometry to one C(52) atom. In the sixteenth H site, H(31,32) is bonded in a single-bond geometry to one C(52) atom. Cl(1) is bonded in a single-bond geometry to one Cd(3) atom. In the NaCd2H14(C5O2)6 framework, Na(1) is bonded in a distorted L-shaped geometry to one O(2) and one O(4) atom. The Na(1)-O(2) bond length is 2.34 Å. The Na(1)-O(4) bond length is 2.50 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 7-coordinate geometry to one O(1), one O(11), one O(12), one O(2), one O(4), and two equivalent O(3) atoms. The Cd(1)-O(1) bond length is 2.43 Å. The Cd(1)-O(11) bond length is 2.24 Å. The Cd(1)-O(12) bond length is 2.23 Å. The Cd(1)-O(2) bond length is 2.29 Å. The Cd(1)-O(4) bond length is 2.33 Å. There is one shorter (2.31 Å) and one longer (2.53 Å) Cd(1)-O(3) bond length. In the second Cd site, Cd(2) is bonded in a 6-coordinate geometry to one O(10), one O(5), one O(6), one O(7), one O(8), and one O(9) atom. The Cd(2)-O(10) bond length is 2.21 Å. The Cd(2)-O(5) bond length is 2.18 Å. The Cd(2)-O(6) bond length is 2.23 Å. The Cd(2)-O(7) bond length is 2.25 Å. The Cd(2)-O(8) bond length is 2.39 Å. The Cd(2)-O(9) bond length is 2.26 Å. There are thirty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(11), and one O(12) atom. The C(1)-C(2) bond length is 1.53 Å. The C(1)-O(11) bond length is 1.30 Å. The C(1)-O(12) bond length is 1.23 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(2) atom. The C(4)-C(5) bond length is 1.33 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-C(8) bond length is 1.52 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(5), and one C(9) atom. The C(8)-C(13) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.37 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(5) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-H(5) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-C(15) bond length is 1.49 Å. In the eleventh C site, C(11) is bonded in a single-bond geometry to one C(10), one C(12), and one H(6) atom. The C(11)-C(12) bond length is 1.37 Å. The C(11)-H(6) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-C(14) bond length is 1.48 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(7) atom. The C(13)-H(7) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(7), and one O(8) atom. The C(14)-O(7) bond length is 1.29 Å. The C(14)-O(8) bond length is 1.19 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(10), and one O(9) atom. The C(15)-O(10) bond length is 1.17 Å. The C(15)-O(9) bond length is 1.17 Å. In the sixteenth C site, C(16) is bonded in a 2-coordinate geometry to one C(17), one O(5), and one O(6) atom. The C(16)-C(17) bond length is 1.56 Å. The C(16)-O(5) bond length is 1.26 Å. The C(16)-O(6) bond length is 1.23 Å. In the seventeenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(22) atom. The C(17)-C(18) bond length is 1.42 Å. The C(17)-C(22) bond length is 1.34 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(8) atom. The C(18)-C(19) bond length is 1.47 Å. The C(18)-H(8) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one H(9) atom. The C(19)-C(20) bond length is 1.34 Å. The C(19)-H(9) bond length is 0.93 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(23) atom. The C(20)-C(21) bond length is 1.34 Å. The C(20)-C(23) bond length is 1.52 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(10) atom. The C(21)-H(10) bond length is 0.93 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(17) and one H(11) atom. The C(22)-H(11) bond length is 0.93 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(20), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.41 Å. The C(23)-C(28) bond length is 1.36 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(12) atom. The C(24)-C(25) bond length is 1.45 Å. The C(24)-H(12) bond length is 0.93 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(30) atom. The C(25)-C(26) bond length is 1.34 Å. The C(25)-C(30) bond length is 1.50 Å. In the twenty-sixth C site, C(26) is bonded in a single-bond geometry to one C(25), one C(27), and one H(13) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-H(13) bond length is 0.93 Å. In the twenty-seventh C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(29) atom. The C(27)-C(28) bond length is 1.42 Å. The C(27)-C(29) bond length is 1.55 Å. In the twenty-eighth C site, C(28) is bonded in a distorted single-bond geometry to one C(23), one C(27), and one H(14) atom. The C(28)-H(14) bond length is 0.93 Å. In the twenty-ninth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(1), and one O(2) atom. The C(29)-O(1) bond length is 1.11 Å. The C(29)-O(2) bond length is 1.29 Å. In the thirtieth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(3), and one O(4) atom. The C(30)-O(3) bond length is 1.22 Å. The C(30)-O(4) bond length is 1.28 Å. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(24) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(26) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(28) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(29) atom. In the second O site, O(2) is bonded in a distorted T-shaped geometry to one Na(1), one Cd(1), and one C(29) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to two equivalent Cd(1) and one C(30) atom. In the fourth O site, O(4) is bonded in a distorted T-shaped geometry to one Na(1), one Cd(1), and one C(30) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Cd(2) and one C(16) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Cd(2) and one C(16) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to one Cd(2) and one C(14) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Cd(2) and one C(14) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Cd(2) and one C(15) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Cd(2) and one C(15) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(1) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(1) atom. Linkers: 1 CN1[CH]C=C(/C2=C3\C=C/C(=C(\C4=C[CH]N(C)C=C4)C4=N/C(=C(/C5=C[CH]N(C)C=C5)C5=CC=C([N]5)/C(C5=C[CH]N(C)C=C5)=C5/C=CC2=N5)C=C4)[N]3)C=C1 ,4 [O]C(=O)c1ccc(-c2cc(C([O])=O)cc(C([O])=O)c2)cc1. Metal clusters: 1 [C]1O[Cd]234(O1)O[C]O[Cd]1(O[C]O1)(O[C]O2)(O[C]O3)O[C]O4.[Na].[Na] ,1 [C]1O[Cd]234(O1)O[C]O[Cd]1(O[C]O1)(O[C]O2)(O[C]O3)O[C]O4 ,1 Cl[Cd]1234[N][Cd]1(Cl)([N]2)([N]3)[N]4. The MOF has largest included sphere 9.54 A, density 1.17 g/cm3, surface area 3850.81 m2/g, accessible volume 0.44 cm3/g