CuH20(C2N)8(CH2)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules and four CuH20(C2N)8 clusters. In each CuH20(C2N)8 cluster, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Cu(1)-N(1) bond length is 1.97 Å. The Cu(1)-N(2) bond length is 2.02 Å. The Cu(1)-N(3) bond length is 1.97 Å. The Cu(1)-N(4) bond length is 2.04 Å. There are sixteen inequivalent C sites. In the first C site, C(13) is bonded in a distorted trigonal non-coplanar geometry to one N(5) and two equivalent H(17,18) atoms. The C(13)-N(5) bond length is 1.41 Å. Both C(13)-H(17,18) bond lengths are 0.97 Å. In the second C site, C(15) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(21) atom. The C(15)-N(4) bond length is 1.28 Å. The C(15)-N(5) bond length is 1.36 Å. The C(15)-H(21) bond length is 0.93 Å. In the third C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(22) atom. The C(16)-N(5) bond length is 1.29 Å. The C(16)-H(22) bond length is 0.93 Å. In the fourth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(25) atom. The C(18)-C(3) bond length is 1.30 Å. The C(18)-N(1) bond length is 1.40 Å. The C(18)-H(25) bond length is 0.93 Å. In the fifth C site, C(20) is bonded in a 2-coordinate geometry to one N(4) and one H(28) atom. The C(20)-N(4) bond length is 1.41 Å. The C(20)-H(28) bond length is 0.93 Å. In the sixth C site, C(19) is bonded in a 3-coordinate geometry to one N(6), one H(26), and one H(27) atom. The C(19)-N(6) bond length is 1.47 Å. The C(19)-H(26) bond length is 0.97 Å. The C(19)-H(27) bond length is 0.97 Å. In the seventh C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(1) atom. The C(1)-N(7) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.93 Å. In the eighth C site, C(2) is bonded in a 2-coordinate geometry to one N(2) and one H(2) atom. The C(2)-N(2) bond length is 1.40 Å. The C(2)-H(2) bond length is 0.93 Å. In the ninth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(18), one N(6), and one H(3) atom. The C(3)-N(6) bond length is 1.37 Å. The C(3)-H(3) bond length is 0.93 Å. In the tenth C site, C(4) is bonded in a trigonal planar geometry to one N(1), one N(6), and one H(4) atom. The C(4)-N(1) bond length is 1.39 Å. The C(4)-N(6) bond length is 1.27 Å. The C(4)-H(4) bond length is 0.93 Å. In the eleventh C site, C(5) is bonded in a trigonal planar geometry to one N(3), one N(8), and one H(5) atom. The C(5)-N(3) bond length is 1.32 Å. The C(5)-N(8) bond length is 1.33 Å. The C(5)-H(5) bond length is 0.93 Å. In the twelfth C site, C(6) is bonded in a 3-coordinate geometry to one N(7) and two equivalent H(6,7) atoms. The C(6)-N(7) bond length is 1.48 Å. Both C(6)-H(6,7) bond lengths are 0.97 Å. In the thirteenth C site, C(8) is bonded in a 3-coordinate geometry to one N(8), one H(10), and one H(11) atom. The C(8)-N(8) bond length is 1.46 Å. The C(8)-H(10) bond length is 0.97 Å. The C(8)-H(11) bond length is 0.97 Å. In the fourteenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(12), one N(8), and one H(14) atom. The C(10)-C(12) bond length is 1.32 Å. The C(10)-N(8) bond length is 1.41 Å. The C(10)-H(14) bond length is 0.93 Å. In the fifteenth C site, C(11) is bonded in a trigonal planar geometry to one N(2), one N(7), and one H(15) atom. The C(11)-N(2) bond length is 1.30 Å. The C(11)-N(7) bond length is 1.33 Å. The C(11)-H(15) bond length is 0.93 Å. In the sixteenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(3), and one H(16) atom. The C(12)-N(3) bond length is 1.35 Å. The C(12)-H(16) bond length is 0.93 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(18), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(12), and one C(5) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(1), one C(15), and one C(20) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(16) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(19), one C(3), and one C(4) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(6) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(10), one C(5), and one C(8) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(6,7) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(17,18) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(15) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(25) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(26) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(27) is bonded in a single-bond geometry to one C(19) atom. In the eighteenth H site, H(28) is bonded in a single-bond geometry to one C(20) atom. Linkers: 1 [CH2].[CH2].[CH2].[CH2].[CH2].[CH2].[CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=N[CH2].[CH]=[N].[CH]=[N].[CH]=[N].[CH][CH].[CH][N].[CH][N].[CH][N].[CH][N].[CH][N][CH].[CH][N][Cu][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#N.[C]=N[CH2].[C]=N[CH].[C]N([CH])[Cu].[C]N([C])[Cu].[C]N=[C].[C]N=[C].[C][N].[C][N][CH].[C][N][CH].[C][N][C].[Cu].[Cu].[Cu].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][Cu] ,1 c1cn(CCCCn2ccnc2)cn1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 8.23 A, density 0.79 g/cm3, surface area 5499.61 m2/g, accessible volume 0.72 cm3/g