Zn8C115H59O28(CH)17 crystallizes in the triclinic P-1 space group. The structure consists of thirty-four 02329_fluka molecules inside a Zn8C115H59O28 framework. In the Zn8C115H59O28 framework, there are eight inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one O(1), one O(27), one O(28), and one O(5) atom. The Zn(1)-O(1) bond length is 1.95 Å. The Zn(1)-O(27) bond length is 1.93 Å. The Zn(1)-O(28) bond length is 1.94 Å. The Zn(1)-O(5) bond length is 1.90 Å. In the second Zn site, Zn(2) is bonded in a rectangular see-saw-like geometry to one O(2), one O(6), and two equivalent O(5) atoms. The Zn(2)-O(2) bond length is 2.06 Å. The Zn(2)-O(6) bond length is 2.07 Å. There is one shorter (2.05 Å) and one longer (2.13 Å) Zn(2)-O(5) bond length. In the third Zn site, Zn(3) is bonded in a rectangular see-saw-like geometry to one O(4), one O(9), and two equivalent O(7) atoms. The Zn(3)-O(4) bond length is 2.07 Å. The Zn(3)-O(9) bond length is 2.10 Å. There is one shorter (2.09 Å) and one longer (2.11 Å) Zn(3)-O(7) bond length. In the fourth Zn site, Zn(4) is bonded in a tetrahedral geometry to one O(10), one O(3), one O(7), and one O(8) atom. The Zn(4)-O(10) bond length is 1.91 Å. The Zn(4)-O(3) bond length is 1.97 Å. The Zn(4)-O(7) bond length is 1.96 Å. The Zn(4)-O(8) bond length is 1.92 Å. In the fifth Zn site, Zn(5) is bonded to one O(12), one O(17), and two equivalent O(16) atoms to form a mixture of edge and corner-sharing ZnO4 trigonal pyramids. The Zn(5)-O(12) bond length is 1.98 Å. The Zn(5)-O(17) bond length is 1.97 Å. There is one shorter (2.03 Å) and one longer (2.12 Å) Zn(5)-O(16) bond length. In the sixth Zn site, Zn(6) is bonded to one O(13), one O(16), one O(18), and one O(20) atom to form distorted corner-sharing ZnO4 tetrahedra. The Zn(6)-O(13) bond length is 1.97 Å. The Zn(6)-O(16) bond length is 1.92 Å. The Zn(6)-O(18) bond length is 1.92 Å. The Zn(6)-O(20) bond length is 1.98 Å. In the seventh Zn site, Zn(7) is bonded in a tetrahedral geometry to one O(15), one O(21), one O(23), and one O(24) atom. The Zn(7)-O(15) bond length is 1.89 Å. The Zn(7)-O(21) bond length is 1.96 Å. The Zn(7)-O(23) bond length is 1.93 Å. The Zn(7)-O(24) bond length is 1.96 Å. In the eighth Zn site, Zn(8) is bonded in a rectangular see-saw-like geometry to one O(22), one O(25), and two equivalent O(23) atoms. The Zn(8)-O(22) bond length is 2.07 Å. The Zn(8)-O(25) bond length is 2.00 Å. There is one shorter (2.07 Å) and one longer (2.08 Å) Zn(8)-O(23) bond length. There are one hundred and fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one H(1) atom. The C(1)-C(6) bond length is 1.40 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(4) bond length is 0.95 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-C(8) bond length is 1.50 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.51 Å. In the fifth C site, C(7) is bonded in a single-bond geometry to one C(15), one C(6), one C(9), and one H(5) atom. The C(7)-C(15) bond length is 1.52 Å. The C(7)-C(9) bond length is 1.51 Å. The C(7)-H(5) bond length is 1.00 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(14), one C(16), one C(5), and one H(6) atom. The C(8)-C(14) bond length is 1.54 Å. The C(8)-C(16) bond length is 1.52 Å. The C(8)-H(6) bond length is 1.00 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(7) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(14) bond length is 1.40 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(7) atom. The C(10)-C(11) bond length is 1.36 Å. The C(10)-H(7) bond length is 0.95 Å. In the ninth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(10), one C(12), and one H(8) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-H(8) bond length is 0.95 Å. In the tenth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), and one H(9) atom. The C(12)-C(13) bond length is 1.42 Å. The C(12)-H(9) bond length is 0.95 Å. In the eleventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(14), and one H(10) atom. The C(13)-C(14) bond length is 1.35 Å. The C(13)-H(10) bond length is 0.95 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(8), and one C(9) atom. In the thirteenth C site, C(15) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(7) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-C(20) bond length is 1.38 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(8) atom. The C(16)-C(17) bond length is 1.38 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(22) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-C(22) bond length is 1.48 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(11) atom. The C(18)-H(11) bond length is 0.95 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(20) and one H(12) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(12) bond length is 0.95 Å. In the eighteenth C site, C(20) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(21) atom. The C(20)-C(21) bond length is 1.50 Å. In the nineteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(1), and one O(2) atom. The C(21)-O(1) bond length is 1.26 Å. The C(21)-O(2) bond length is 1.23 Å. In the twentieth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(3), and one O(4) atom. The C(22)-O(3) bond length is 1.27 Å. The C(22)-O(4) bond length is 1.24 Å. In the twenty-first C site, C(23) is bonded in a trigonal planar geometry to one C(24), one C(28), and one C(29) atom. The C(23)-C(24) bond length is 1.37 Å. The C(23)-C(28) bond length is 1.38 Å. The C(23)-C(29) bond length is 1.52 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(13) atom. The C(24)-H(13) bond length is 0.95 Å. In the twenty-third C site, C(27) is bonded in a distorted single-bond geometry to one C(28) and one H(16) atom. The C(27)-C(28) bond length is 1.37 Å. The C(27)-H(16) bond length is 0.95 Å. In the twenty-fourth C site, C(28) is bonded in a trigonal planar geometry to one C(23), one C(27), and one C(30) atom. The C(28)-C(30) bond length is 1.52 Å. In the twenty-fifth C site, C(29) is bonded in a single-bond geometry to one C(23), one C(31), one C(37), and one H(17) atom. The C(29)-C(31) bond length is 1.52 Å. The C(29)-C(37) bond length is 1.55 Å. The C(29)-H(17) bond length is 1.00 Å. In the twenty-sixth C site, C(30) is bonded in a single-bond geometry to one C(28), one C(32), one C(38), and one H(18) atom. The C(30)-C(32) bond length is 1.51 Å. The C(30)-C(38) bond length is 1.52 Å. The C(30)-H(18) bond length is 1.00 Å. In the twenty-seventh C site, C(31) is bonded in a trigonal planar geometry to one C(29), one C(32), and one C(36) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-C(36) bond length is 1.39 Å. In the twenty-eighth C site, C(32) is bonded in a trigonal planar geometry to one C(30), one C(31), and one C(33) atom. The C(32)-C(33) bond length is 1.39 Å. In the twenty-ninth C site, C(33) is bonded in a single-bond geometry to one C(32) and one H(19) atom. The C(33)-H(19) bond length is 0.95 Å. In the thirtieth C site, C(36) is bonded in a distorted single-bond geometry to one C(31) and one H(22) atom. The C(36)-H(22) bond length is 0.95 Å. In the thirty-first C site, C(37) is bonded in a trigonal planar geometry to one C(29), one C(38), and one C(42) atom. The C(37)-C(38) bond length is 1.40 Å. The C(37)-C(42) bond length is 1.38 Å. In the thirty-second C site, C(38) is bonded in a trigonal planar geometry to one C(30), one C(37), and one C(39) atom. The C(38)-C(39) bond length is 1.40 Å. In the thirty-third C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(44) atom. The C(39)-C(40) bond length is 1.38 Å. The C(39)-C(44) bond length is 1.50 Å. In the thirty-fourth C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one H(23) atom. The C(40)-H(23) bond length is 0.95 Å. In the thirty-fifth C site, C(41) is bonded in a distorted single-bond geometry to one C(42) and one H(24) atom. The C(41)-C(42) bond length is 1.40 Å. The C(41)-H(24) bond length is 0.95 Å. In the thirty-sixth C site, C(42) is bonded in a trigonal planar geometry to one C(37), one C(41), and one C(43) atom. The C(42)-C(43) bond length is 1.49 Å. In the thirty-seventh C site, C(43) is bonded in a distorted bent 120 degrees geometry to one C(42), one O(8), and one O(9) atom. The C(43)-O(8) bond length is 1.26 Å. The C(43)-O(9) bond length is 1.24 Å. In the thirty-eighth C site, C(44) is bonded in a bent 120 degrees geometry to one C(39), one O(14), and one O(15) atom. The C(44)-O(14) bond length is 1.22 Å. The C(44)-O(15) bond length is 1.28 Å. In the thirty-ninth C site, C(45) is bonded in a trigonal planar geometry to one C(46), one C(50), and one C(51) atom. The C(45)-C(46) bond length is 1.37 Å. The C(45)-C(50) bond length is 1.39 Å. The C(45)-C(51) bond length is 1.51 Å. In the fortieth C site, C(46) is bonded in a distorted single-bond geometry to one C(45) and one H(25) atom. The C(46)-H(25) bond length is 0.95 Å. In the forty-first C site, C(49) is bonded in a distorted single-bond geometry to one C(50) and one H(28) atom. The C(49)-C(50) bond length is 1.37 Å. The C(49)-H(28) bond length is 0.95 Å. In the forty-second C site, C(50) is bonded in a trigonal planar geometry to one C(45), one C(49), and one C(52) atom. The C(50)-C(52) bond length is 1.51 Å. In the forty-third C site, C(51) is bonded in a distorted single-bond geometry to one C(45), one C(53), one C(59), and one H(29) atom. The C(51)-C(53) bond length is 1.51 Å. The C(51)-C(59) bond length is 1.53 Å. The C(51)-H(29) bond length is 1.00 Å. In the forty-fourth C site, C(52) is bonded in a distorted single-bond geometry to one C(50), one C(58), one C(60), and one H(30) atom. The C(52)-C(58) bond length is 1.53 Å. The C(52)-C(60) bond length is 1.53 Å. The C(52)-H(30) bond length is 1.00 Å. In the forty-fifth C site, C(53) is bonded in a trigonal planar geometry to one C(51), one C(54), and one C(58) atom. The C(53)-C(54) bond length is 1.39 Å. The C(53)-C(58) bond length is 1.39 Å. In the forty-sixth C site, C(54) is bonded in a distorted single-bond geometry to one C(53) and one H(31) atom. The C(54)-H(31) bond length is 0.95 Å. In the forty-seventh C site, C(57) is bonded in a distorted single-bond geometry to one C(58) and one H(34) atom. The C(57)-C(58) bond length is 1.37 Å. The C(57)-H(34) bond length is 0.95 Å. In the forty-eighth C site, C(58) is bonded in a trigonal planar geometry to one C(52), one C(53), and one C(57) atom. In the forty-ninth C site, C(59) is bonded in a trigonal planar geometry to one C(51), one C(60), and one C(64) atom. The C(59)-C(60) bond length is 1.40 Å. The C(59)-C(64) bond length is 1.38 Å. In the fiftieth C site, C(60) is bonded in a trigonal planar geometry to one C(52), one C(59), and one C(61) atom. The C(60)-C(61) bond length is 1.40 Å. In the fifty-first C site, C(61) is bonded in a trigonal planar geometry to one C(60), one C(62), and one C(66) atom. The C(61)-C(62) bond length is 1.41 Å. The C(61)-C(66) bond length is 1.49 Å. In the fifty-second C site, C(62) is bonded in a distorted single-bond geometry to one C(61) and one H(35) atom. The C(62)-H(35) bond length is 0.95 Å. In the fifty-third C site, C(63) is bonded in a distorted single-bond geometry to one C(64) and one H(36) atom. The C(63)-C(64) bond length is 1.42 Å. The C(63)-H(36) bond length is 0.95 Å. In the fifty-fourth C site, C(64) is bonded in a trigonal planar geometry to one C(59), one C(63), and one C(65) atom. The C(64)-C(65) bond length is 1.49 Å. In the fifty-fifth C site, C(65) is bonded in a distorted bent 120 degrees geometry to one C(64), one O(10), and one O(11) atom. The C(65)-O(10) bond length is 1.27 Å. The C(65)-O(11) bond length is 1.25 Å. In the fifty-sixth C site, C(66) is bonded in a distorted bent 120 degrees geometry to one C(61), one O(12), and one O(13) atom. The C(66)-O(12) bond length is 1.24 Å. The C(66)-O(13) bond length is 1.25 Å. In the fifty-seventh C site, C(67) is bonded in a trigonal planar geometry to one C(68), one C(72), and one C(73) atom. The C(67)-C(68) bond length is 1.39 Å. The C(67)-C(72) bond length is 1.41 Å. The C(67)-C(73) bond length is 1.52 Å. In the fifty-eighth C site, C(68) is bonded in a distorted single-bond geometry to one C(67) and one H(37) atom. The C(68)-H(37) bond length is 0.95 Å. In the fifty-ninth C site, C(71) is bonded in a distorted single-bond geometry to one C(72) and one H(40) atom. The C(71)-C(72) bond length is 1.39 Å. The C(71)-H(40) bond length is 0.95 Å. In the sixtieth C site, C(72) is bonded in a trigonal planar geometry to one C(67), one C(71), and one C(74) atom. The C(72)-C(74) bond length is 1.51 Å. In the sixty-first C site, C(73) is bonded in a single-bond geometry to one C(67), one C(75), one C(82), and one H(41) atom. The C(73)-C(75) bond length is 1.53 Å. The C(73)-C(82) bond length is 1.52 Å. The C(73)-H(41) bond length is 1.00 Å. In the sixty-second C site, C(74) is bonded in a single-bond geometry to one C(72), one C(76), one C(83), and one H(42) atom. The C(74)-C(76) bond length is 1.51 Å. The C(74)-C(83) bond length is 1.53 Å. The C(74)-H(42) bond length is 1.00 Å. In the sixty-third C site, C(75) is bonded in a trigonal planar geometry to one C(73), one C(76), and one C(80) atom. The C(75)-C(76) bond length is 1.40 Å. The C(75)-C(80) bond length is 1.36 Å. In the sixty-fourth C site, C(76) is bonded in a trigonal planar geometry to one C(74), one C(75), and one C(77) atom. The C(76)-C(77) bond length is 1.40 Å. In the sixty-fifth C site, C(77) is bonded in a distorted single-bond geometry to one C(76) and one H(43) atom. The C(77)-H(43) bond length is 0.95 Å. In the sixty-sixth C site, C(80) is bonded in a distorted single-bond geometry to one C(75) and one H(46) atom. The C(80)-H(46) bond length is 0.95 Å. In the sixty-seventh C site, C(81) is bonded in a trigonal planar geometry to one C(82), one C(86), and one C(87) atom. The C(81)-C(82) bond length is 1.40 Å. The C(81)-C(86) bond length is 1.38 Å. The C(81)-C(87) bond length is 1.50 Å. In the sixty-eighth C site, C(82) is bonded in a trigonal planar geometry to one C(73), one C(81), and one C(83) atom. The C(82)-C(83) bond length is 1.40 Å. In the sixty-ninth C site, C(83) is bonded in a trigonal planar geometry to one C(74), one C(82), and one C(84) atom. The C(83)-C(84) bond length is 1.37 Å. In the seventieth C site, C(84) is bonded in a trigonal planar geometry to one C(83), one C(85), and one C(88) atom. The C(84)-C(85) bond length is 1.39 Å. The C(84)-C(88) bond length is 1.50 Å. In the seventy-first C site, C(85) is bonded in a distorted single-bond geometry to one C(84) and one H(47) atom. The C(85)-H(47) bond length is 0.95 Å. In the seventy-second C site, C(86) is bonded in a distorted single-bond geometry to one C(81) and one H(48) atom. The C(86)-H(48) bond length is 0.95 Å. In the seventy-third C site, C(87) is bonded in a distorted bent 120 degrees geometry to one C(81), one O(18), and one O(19) atom. The C(87)-O(18) bond length is 1.28 Å. The C(87)-O(19) bond length is 1.24 Å. In the seventy-fourth C site, C(88) is bonded in a distorted bent 120 degrees geometry to one C(84), one O(28), and one O(6) atom. The C(88)-O(28) bond length is 1.27 Å. The C(88)-O(6) bond length is 1.23 Å. In the seventy-fifth C site, C(89) is bonded in a trigonal planar geometry to one C(90), one C(94), and one C(95) atom. The C(89)-C(90) bond length is 1.38 Å. The C(89)-C(94) bond length is 1.40 Å. The C(89)-C(95) bond length is 1.52 Å. In the seventy-sixth C site, C(90) is bonded in a distorted single-bond geometry to one C(89) and one H(49) atom. The C(90)-H(49) bond length is 0.95 Å. In the seventy-seventh C site, C(91) is bonded in a distorted single-bond geometry to one C(92) and one H(50) atom. The C(91)-C(92) bond length is 1.38 Å. The C(91)-H(50) bond length is 0.95 Å. In the seventy-eighth C site, C(92) is bonded in a distorted trigonal planar geometry to one C(91), one C(93), and one H(51) atom. The C(92)-C(93) bond length is 1.40 Å. The C(92)-H(51) bond length is 0.95 Å. In the seventy-ninth C site, C(93) is bonded in a distorted trigonal planar geometry to one C(92), one C(94), and one H(52) atom. The C(93)-C(94) bond length is 1.39 Å. The C(93)-H(52) bond length is 0.95 Å. In the eightieth C site, C(94) is bonded in a trigonal planar geometry to one C(89), one C(93), and one C(96) atom. The C(94)-C(96) bond length is 1.54 Å. In the eighty-first C site, C(95) is bonded in a single-bond geometry to one C(103), one C(89), one C(97), and one H(53) atom. The C(95)-C(103) bond length is 1.52 Å. The C(95)-C(97) bond length is 1.52 Å. The C(95)-H(53) bond length is 1.00 Å. In the eighty-second C site, C(96) is bonded in a distorted single-bond geometry to one C(102), one C(104), one C(94), and one H(54) atom. The C(96)-C(102) bond length is 1.50 Å. The C(96)-C(104) bond length is 1.55 Å. The C(96)-H(54) bond length is 1.00 Å. In the eighty-third C site, C(97) is bonded in a trigonal planar geometry to one C(102), one C(95), and one C(98) atom. The C(97)-C(102) bond length is 1.38 Å. The C(97)-C(98) bond length is 1.37 Å. In the eighty-fourth C site, C(98) is bonded in a distorted trigonal planar geometry to one C(97), one C(99), and one H(55) atom. The C(98)-C(99) bond length is 1.40 Å. The C(98)-H(55) bond length is 0.95 Å. In the eighty-fifth C site, C(99) is bonded in a distorted single-bond geometry to one C(98) and one H(56) atom. The C(99)-H(56) bond length is 0.95 Å. In the eighty-sixth C site, C(101) is bonded in a distorted single-bond geometry to one C(102) and one H(58) atom. The C(101)-C(102) bond length is 1.38 Å. The C(101)-H(58) bond length is 0.95 Å. In the eighty-seventh C site, C(102) is bonded in a trigonal planar geometry to one C(101), one C(96), and one C(97) atom. In the eighty-eighth C site, C(103) is bonded in a trigonal planar geometry to one C(104), one C(108), and one C(95) atom. The C(103)-C(104) bond length is 1.42 Å. The C(103)-C(108) bond length is 1.40 Å. In the eighty-ninth C site, C(104) is bonded in a trigonal planar geometry to one C(103), one C(105), and one C(96) atom. The C(104)-C(105) bond length is 1.37 Å. In the ninetieth C site, C(105) is bonded in a trigonal planar geometry to one C(104), one C(106), and one C(110) atom. The C(105)-C(106) bond length is 1.40 Å. The C(105)-C(110) bond length is 1.51 Å. In the ninety-first C site, C(106) is bonded in a distorted single-bond geometry to one C(105) and one H(59) atom. The C(106)-H(59) bond length is 0.95 Å. In the ninety-second C site, C(107) is bonded in a distorted single-bond geometry to one C(108) and one H(60) atom. The C(107)-C(108) bond length is 1.40 Å. The C(107)-H(60) bond length is 0.95 Å. In the ninety-third C site, C(108) is bonded in a trigonal planar geometry to one C(103), one C(107), and one C(109) atom. The C(108)-C(109) bond length is 1.51 Å. In the ninety-fourth C site, C(109) is bonded in a distorted bent 120 degrees geometry to one C(108), one O(21), and one O(22) atom. The C(109)-O(21) bond length is 1.25 Å. The C(109)-O(22) bond length is 1.25 Å. In the ninety-fifth C site, C(110) is bonded in a distorted bent 120 degrees geometry to one C(105), one O(17), and one O(20) atom. The C(110)-O(17) bond length is 1.24 Å. The C(110)-O(20) bond length is 1.26 Å. In the ninety-sixth C site, C(111) is bonded in a trigonal planar geometry to one C(112), one C(116), and one C(117) atom. The C(111)-C(112) bond length is 1.40 Å. The C(111)-C(116) bond length is 1.40 Å. The C(111)-C(117) bond length is 1.53 Å. In the ninety-seventh C site, C(112) is bonded in a distorted single-bond geometry to one C(111) and one H(61) atom. The C(112)-H(61) bond length is 0.95 Å. In the ninety-eighth C site, C(115) is bonded in a distorted single-bond geometry to one C(116) and one H(64) atom. The C(115)-C(116) bond length is 1.38 Å. The C(115)-H(64) bond length is 0.95 Å. In the ninety-ninth C site, C(116) is bonded in a trigonal planar geometry to one C(111), one C(115), and one C(118) atom. The C(116)-C(118) bond length is 1.54 Å. In the one hundredth C site, C(117) is bonded in a distorted single-bond geometry to one C(111), one C(119), one C(125), and one H(65) atom. The C(117)-C(119) bond length is 1.49 Å. The C(117)-C(125) bond length is 1.53 Å. The C(117)-H(65) bond length is 1.00 Å. In the one hundred and first C site, C(118) is bonded in a distorted single-bond geometry to one C(116), one C(120), one C(126), and one H(66) atom. The C(118)-C(120) bond length is 1.50 Å. The C(118)-C(126) bond length is 1.52 Å. The C(118)-H(66) bond length is 1.00 Å. In the one hundred and second C site, C(119) is bonded in a trigonal planar geometry to one C(117), one C(120), and one C(124) atom. The C(119)-C(120) bond length is 1.40 Å. The C(119)-C(124) bond length is 1.38 Å. In the one hundred and third C site, C(120) is bonded in a distorted trigonal planar geometry to one C(118), one C(119), and one C(121) atom. The C(120)-C(121) bond length is 1.38 Å. In the one hundred and fourth C site, C(121) is bonded in a distorted single-bond geometry to one C(120), one C(122), and one H(67) atom. The C(121)-C(122) bond length is 1.36 Å. The C(121)-H(67) bond length is 0.95 Å. In the one hundred and fifth C site, C(122) is bonded in a distorted trigonal planar geometry to one C(121), one C(123), and one H(68) atom. The C(122)-C(123) bond length is 1.37 Å. The C(122)-H(68) bond length is 0.95 Å. In the one hundred and sixth C site, C(123) is bonded in a distorted trigonal planar geometry to one C(122), one C(124), and one H(69) atom. The C(123)-C(124) bond length is 1.37 Å. The C(123)-H(69) bond length is 0.95 Å. In the one hundred and seventh C site, C(124) is bonded in a distorted single-bond geometry to one C(119), one C(123), and one H(70) atom. The C(124)-H(70) bond length is 0.95 Å. In the one hundred and eighth C site, C(125) is bonded in a trigonal planar geometry to one C(117), one C(126), and one C(130) atom. The C(125)-C(126) bond length is 1.42 Å. The C(125)-C(130) bond length is 1.37 Å. In the one hundred and ninth C site, C(126) is bonded in a trigonal planar geometry to one C(118), one C(125), and one C(127) atom. The C(126)-C(127) bond length is 1.39 Å. In the one hundred and tenth C site, C(127) is bonded in a trigonal planar geometry to one C(126), one C(128), and one C(132) atom. The C(127)-C(128) bond length is 1.41 Å. The C(127)-C(132) bond length is 1.49 Å. In the one hundred and eleventh C site, C(128) is bonded in a distorted single-bond geometry to one C(127) and one H(71) atom. The C(128)-H(71) bond length is 0.95 Å. In the one hundred and twelfth C site, C(129) is bonded in a distorted single-bond geometry to one C(130) and one H(72) atom. The C(129)-C(130) bond length is 1.41 Å. The C(129)-H(72) bond length is 0.95 Å. In the one hundred and thirteenth C site, C(130) is bonded in a trigonal planar geometry to one C(125), one C(129), and one C(131) atom. The C(130)-C(131) bond length is 1.50 Å. In the one hundred and fourteenth C site, C(131) is bonded in a distorted bent 120 degrees geometry to one C(130), one O(26), and one O(27) atom. The C(131)-O(26) bond length is 1.25 Å. The C(131)-O(27) bond length is 1.27 Å. In the one hundred and fifteenth C site, C(132) is bonded in a distorted bent 120 degrees geometry to one C(127), one O(24), and one O(25) atom. The C(132)-O(24) bond length is 1.28 Å. The C(132)-O(25) bond length is 1.26 Å. There are fifty-nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(24) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(29) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(33) atom. In the sixteenth H site, H(22) is bonded in a single-bond geometry to one C(36) atom. In the seventeenth H site, H(23) is bonded in a single-bond geometry to one C(40) atom. In the eighteenth H site, H(24) is bonded in a single-bond geometry to one C(41) atom. In the nineteenth H site, H(25) is bonded in a single-bond geometry to one C(46) atom. In the twentieth H site, H(28) is bonded in a single-bond geometry to one C(49) atom. In the twenty-first H site, H(29) is bonded in a single-bond geometry to one C(51) atom. In the twenty-second H site, H(30) is bonded in a single-bond geometry to one C(52) atom. In the twenty-third H site, H(31) is bonded in a single-bond geometry to one C(54) atom. In the twenty-fourth H site, H(34) is bonded in a single-bond geometry to one C(57) atom. In the twenty-fifth H site, H(35) is bonded in a single-bond geometry to one C(62) atom. In the twenty-sixth H site, H(36) is bonded in a single-bond geometry to one C(63) atom. In the twenty-seventh H site, H(37) is bonded in a single-bond geometry to one C(68) atom. In the twenty-eighth H site, H(40) is bonded in a single-bond geometry to one C(71) atom. In the twenty-ninth H site, H(41) is bonded in a single-bond geometry to one C(73) atom. In the thirtieth H site, H(42) is bonded in a single-bond geometry to one C(74) atom. In the thirty-first H site, H(43) is bonded in a single-bond geometry to one C(77) atom. In the thirty-second H site, H(46) is bonded in a single-bond geometry to one C(80) atom. In the thirty-third H site, H(47) is bonded in a single-bond geometry to one C(85) atom. In the thirty-fourth H site, H(48) is bonded in a single-bond geometry to one C(86) atom. In the thirty-fifth H site, H(49) is bonded in a single-bond geometry to one C(90) atom. In the thirty-sixth H site, H(50) is bonded in a single-bond geometry to one C(91) atom. In the thirty-seventh H site, H(51) is bonded in a single-bond geometry to one C(92) atom. In the thirty-eighth H site, H(52) is bonded in a single-bond geometry to one C(93) atom. In the thirty-ninth H site, H(53) is bonded in a single-bond geometry to one C(95) atom. In the fortieth H site, H(54) is bonded in a single-bond geometry to one C(96) atom. In the forty-first H site, H(55) is bonded in a single-bond geometry to one C(98) atom. In the forty-second H site, H(56) is bonded in a single-bond geometry to one C(99) atom. In the forty-third H site, H(58) is bonded in a single-bond geometry to one C(101) atom. In the forty-fourth H site, H(59) is bonded in a single-bond geometry to one C(106) atom. In the forty-fifth H site, H(60) is bonded in a single-bond geometry to one C(107) atom. In the forty-sixth H site, H(61) is bonded in a single-bond geometry to one C(112) atom. In the forty-seventh H site, H(64) is bonded in a single-bond geometry to one C(115) atom. In the forty-eighth H site, H(65) is bonded in a single-bond geometry to one C(117) atom. In the forty-ninth H site, H(66) is bonded in a single-bond geometry to one C(118) atom. In the fiftieth H site, H(67) is bonded in a single-bond geometry to one C(121) atom. In the fifty-first H site, H(68) is bonded in a single-bond geometry to one C(122) atom. In the fifty-second H site, H(69) is bonded in a single-bond geometry to one C(123) atom. In the fifty-third H site, H(70) is bonded in a single-bond geometry to one C(124) atom. In the fifty-fourth H site, H(71) is bonded in a single-bond geometry to one C(128) atom. In the fifty-fifth H site, H(72) is bonded in a single-bond geometry to one C(129) atom. In the fifty-sixth H site, H(73) is bonded in a single-bond geometry to one O(7) atom. The H(73)-O(7) bond length is 1.00 Å. In the fifty-seventh H site, H(74) is bonded in a single-bond geometry to one O(16) atom. The H(74)-O(16) bond length is 0.82 Å. In the fifty-eighth H site, H(75) is bonded in a single-bond geometry to one O(23) atom. The H(75)-O(23) bond length is 0.86 Å. In the fifty-ninth H site, H(76) is bonded in a single-bond geometry to one O(5) atom. The H(76)-O(5) bond length is 1.08 Å. There are twenty-eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(21) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(21) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(22) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(3) and one C(22) atom. In the fifth O site, O(5) is bonded to one Zn(1), two equivalent Zn(2), and one H(76) atom to form distorted edge-sharing OZn3H tetrahedra. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(88) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Zn(4), two equivalent Zn(3), and one H(73) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(43) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Zn(3) and one C(43) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(65) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one C(65) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(66) atom. In the thirteenth O site, O(13) is bonded in a bent 150 degrees geometry to one Zn(6) and one C(66) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one C(44) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(44) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one Zn(6), two equivalent Zn(5), and one H(74) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one Zn(5) and one C(110) atom. In the eighteenth O site, O(18) is bonded in a water-like geometry to one Zn(6) and one C(87) atom. In the nineteenth O site, O(19) is bonded in a single-bond geometry to one C(87) atom. In the twentieth O site, O(20) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(110) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(109) atom. In the twenty-second O site, O(22) is bonded in a 2-coordinate geometry to one Zn(8) and one C(109) atom. In the twenty-third O site, O(23) is bonded in a distorted single-bond geometry to one Zn(7), two equivalent Zn(8), and one H(75) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(132) atom. In the twenty-fifth O site, O(25) is bonded in a distorted bent 150 degrees geometry to one Zn(8) and one C(132) atom. In the twenty-sixth O site, O(26) is bonded in a single-bond geometry to one C(131) atom. In the twenty-seventh O site, O(27) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(131) atom. In the twenty-eighth O site, O(28) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(88) atom. Linkers: 12 [O]C(=O)c1ccc(C([O])=O)c2c1[C@H]1c3ccccc3[C@@H]2c2ccccc21. Metal clusters: 3 O=[C]O[Zn@]1(O)O[C]O[Zn]O[C]O[Zn@@](O)(O[C]=O)O[C]O[Zn]O[C]O1 ,1 O=[C]O[Zn]1(O)O[C]O[Zn]O[C]O1.O=[C]O[Zn]1(O)O[C]O[Zn]O[C]O1. RCSR code: pcu. The MOF has largest included sphere 7.93 A, density 0.91 g/cm3, surface area 4351.96 m2/g, accessible volume 0.73 cm3/g