Ag2C37P4H24O3(C7H4)2(CH)24 crystallizes in the trigonal R-3c space group. The structure is zero-dimensional and consists of four hundred and thirty-two 02329_fluka molecules, eighteen Ag2C37P4H24O3 clusters, and eighteen C7H4 clusters. In each Ag2C37P4H24O3 cluster, Ag(1) is bonded in a distorted trigonal planar geometry to one P(1), one P(2), and one O(1) atom. The Ag(1)-P(1) bond length is 2.44 Å. The Ag(1)-P(2) bond length is 2.46 Å. The Ag(1)-O(1) bond length is 2.41 Å. There are nineteen inequivalent C sites. In the first C site, C(37) is bonded in a distorted single-bond geometry to one C(32) and one H(28) atom. The C(37)-C(32) bond length is 1.36 Å. The C(37)-H(28) bond length is 0.95 Å. In the second C site, C(38) is bonded in a trigonal planar geometry to one O(2) and two equivalent O(1) atoms. The C(38)-O(2) bond length is 1.22 Å. Both C(38)-O(1) bond lengths are 1.28 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-H(2) bond length is 0.95 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one P(1) atom. The C(5)-C(6) bond length is 1.36 Å. The C(5)-P(1) bond length is 1.81 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 0.95 Å. In the sixth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.35 Å. The C(10)-H(6) bond length is 0.95 Å. In the seventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one P(2) atom. The C(11)-C(12) bond length is 1.35 Å. The C(11)-P(2) bond length is 1.81 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 0.95 Å. In the ninth C site, C(14) is bonded in a trigonal planar geometry to one C(15), one C(19), and one P(1) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(19) bond length is 1.40 Å. The C(14)-P(1) bond length is 1.80 Å. In the tenth C site, C(15) is bonded in a single-bond geometry to one C(14) and one H(9) atom. The C(15)-H(9) bond length is 0.95 Å. In the eleventh C site, C(20) is bonded in a trigonal planar geometry to one C(21), one C(25), and one P(1) atom. The C(20)-C(21) bond length is 1.41 Å. The C(20)-C(25) bond length is 1.37 Å. The C(20)-P(1) bond length is 1.81 Å. In the twelfth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(14) atom. The C(21)-H(14) bond length is 0.95 Å. In the thirteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(13) atom. The C(19)-H(13) bond length is 0.95 Å. In the fourteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(20) and one H(18) atom. The C(25)-H(18) bond length is 0.95 Å. In the fifteenth C site, C(26) is bonded in a trigonal planar geometry to one C(27), one C(31), and one P(2) atom. The C(26)-C(27) bond length is 1.35 Å. The C(26)-C(31) bond length is 1.36 Å. The C(26)-P(2) bond length is 1.83 Å. In the sixteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(19) atom. The C(27)-H(19) bond length is 0.95 Å. In the seventeenth C site, C(31) is bonded in a distorted single-bond geometry to one C(26) and one H(23) atom. The C(31)-H(23) bond length is 0.95 Å. In the eighteenth C site, C(32) is bonded in a trigonal planar geometry to one C(33), one C(37), and one P(2) atom. The C(32)-C(33) bond length is 1.35 Å. The C(32)-P(2) bond length is 1.80 Å. In the nineteenth C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(24) atom. The C(33)-H(24) bond length is 0.95 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one Ag(1), one C(14), one C(20), and one C(5) atom to form distorted corner-sharing PAgC3 tetrahedra. In the second P site, P(2) is bonded to one Ag(1), one C(11), one C(26), and one C(32) atom to form distorted corner-sharing PAgC3 tetrahedra. There are twelve inequivalent H sites. In the first H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the second H site, H(24) is bonded in a single-bond geometry to one C(33) atom. In the third H site, H(28) is bonded in a single-bond geometry to one C(37) atom. In the fourth H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(25) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(1) and one C(38) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(38) atom. In each C7H4 cluster, there are seven inequivalent C sites. In the first C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-C(2) bond length is 1.31 Å. The C(7)-H(4) bond length is 0.95 Å. In the second C site, C(8) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(9) atom. The C(8)-C(1) bond length is 1.51 Å. The C(8)-C(13) bond length is 1.42 Å. The C(8)-C(9) bond length is 1.36 Å. In the third C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(9)-H(5) bond length is 0.95 Å. In the fourth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(13)-H(8) bond length is 0.95 Å. In the fifth C site, C(1) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(8) atom. The C(1)-C(1) bond length is 1.31 Å. The C(1)-C(2) bond length is 1.51 Å. In the sixth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. In the seventh C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. Linkers: 3 c1ccc(P(c2ccccc2)c2ccc([C]([C](c3ccc(P(c4ccccc4)c4ccccc4)cc3)c3ccc(P(c4ccccc4)c4ccccc4)cc3)c3ccc(P(c4ccccc4)c4ccccc4)cc3)cc2)cc1. Metal clusters: . The MOF has largest included sphere 6.52 A, density 1.26 g/cm3, surface area 4983.90 m2/g, accessible volume 0.32 cm3/g