ZnC12H8(NO2)2(C4H3)4 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of sixteen isobutylene molecules and four ZnC12H8(NO2)2 clusters. In each ZnC12H8(NO2)2 cluster, Zn(1) is bonded in a distorted trigonal bipyramidal geometry to one N(1), one N(2), one O(1), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.02 Å. The Zn(1)-N(2) bond length is 2.11 Å. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(3) bond length is 2.05 Å. The Zn(1)-O(4) bond length is 2.30 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(7) bond length is 1.35 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(7) is bonded in a single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.95 Å. In the fifth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(12)-N(1) bond length is 1.30 Å. The C(12)-H(8) bond length is 0.95 Å. In the sixth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(13)-N(1) bond length is 1.37 Å. The C(13)-H(9) bond length is 0.95 Å. In the seventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(3), and one O(4) atom. The C(15)-C(16) bond length is 1.49 Å. The C(15)-O(3) bond length is 1.27 Å. The C(15)-O(4) bond length is 1.26 Å. In the eighth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.40 Å. In the ninth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(11,14) atom. The C(17)-H(11,14) bond length is 0.95 Å. In the tenth C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(11,14) atom. The C(21)-H(11,14) bond length is 0.95 Å. In the eleventh C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(18) atom. The C(26)-N(2) bond length is 1.31 Å. The C(26)-H(18) bond length is 0.95 Å. In the twelfth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(19) atom. The C(27)-N(2) bond length is 1.34 Å. The C(27)-H(19) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(12), and one C(13) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(26), and one C(27) atom. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(11,14) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(27) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Zn(1) and one C(15) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Zn(1) and one C(15) atom. Linkers: 4 [O]C(=O)c1ccc(/C=C/c2ccncc2)cc1 ,1 O=[C]c1ccc(/C=C/c2ccncc2)cc1. Metal clusters: 2 O=[C]O[Zn]1O[C]O1. The MOF has largest included sphere 4.80 A, density 1.23 g/cm3, surface area 5041.99 m2/g, accessible volume 0.30 cm3/g