Ga3P3N(O6F)2 crystallizes in the monoclinic P2_1/c space group. There are three inequivalent Ga sites. In the first Ga site, Ga(1) is bonded to one O(1), one O(2), one O(3), one O(4), one F(1), and one F(2) atom to form GaO4F2 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  a cornercorner with one Ga(2)O4F trigonal bipyramid, and  a cornercorner with one Ga(3)O4F trigonal bipyramid. The Ga(1)-O(1) bond length is 1.92 Å. The Ga(1)-O(2) bond length is 1.92 Å. The Ga(1)-O(3) bond length is 1.93 Å. The Ga(1)-O(4) bond length is 1.94 Å. The Ga(1)-F(1) bond length is 1.96 Å. The Ga(1)-F(2) bond length is 1.96 Å. In the second Ga site, Ga(2) is bonded to one O(5), one O(6), one O(7), one O(8), and one F(1) atom to form GaO4F trigonal bipyramids that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 54°. The Ga(2)-O(5) bond length is 1.86 Å. The Ga(2)-O(6) bond length is 1.86 Å. The Ga(2)-O(7) bond length is 1.87 Å. The Ga(2)-O(8) bond length is 1.91 Å. The Ga(2)-F(1) bond length is 2.02 Å. In the third Ga site, Ga(3) is bonded to one O(10), one O(11), one O(12), one O(9), and one F(2) atom to form GaO4F trigonal bipyramids that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra, and corners with two equivalent P(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 57°. The Ga(3)-O(10) bond length is 1.84 Å. The Ga(3)-O(11) bond length is 1.85 Å. The Ga(3)-O(12) bond length is 1.95 Å. The Ga(3)-O(9) bond length is 1.82 Å. The Ga(3)-F(2) bond length is 2.04 Å. There are three inequivalent P sites. In the first P site, P(1) is bonded to one O(12), one O(3), one O(5), and one O(9) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(2)O4F trigonal bipyramid, and corners with two equivalent Ga(3)O4F trigonal bipyramids. The corner-sharing octahedral tilt angles are 49°. The P(1)-O(12) bond length is 1.54 Å. The P(1)-O(3) bond length is 1.53 Å. The P(1)-O(5) bond length is 1.53 Å. The P(1)-O(9) bond length is 1.52 Å. In the second P site, P(2) is bonded to one O(1), one O(11), one O(4), and one O(7) atom to form PO4 tetrahedra that share corners with two equivalent Ga(1)O4F2 octahedra,  a cornercorner with one Ga(2)O4F trigonal bipyramid, and  a cornercorner with one Ga(3)O4F trigonal bipyramid. The corner-sharing octahedral tilt angles range from 51-52°. The P(2)-O(1) bond length is 1.53 Å. The P(2)-O(11) bond length is 1.55 Å. The P(2)-O(4) bond length is 1.51 Å. The P(2)-O(7) bond length is 1.55 Å. In the third P site, P(3) is bonded to one O(10), one O(2), one O(6), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Ga(1)O4F2 octahedra,  a cornercorner with one Ga(3)O4F trigonal bipyramid, and corners with two equivalent Ga(2)O4F trigonal bipyramids. The corner-sharing octahedral tilt angles are 46°. The P(3)-O(10) bond length is 1.53 Å. The P(3)-O(2) bond length is 1.52 Å. The P(3)-O(6) bond length is 1.55 Å. The P(3)-O(8) bond length is 1.53 Å. N(1) is bonded in a single-bond geometry to one O(8) atom. The N(1)-O(8) bond length is 0.89 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ga(1) and one P(3) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Ga(2) and one P(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ga(2) and one P(3) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Ga(2) and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted trigonal planar geometry to one Ga(2), one P(3), and one N(1) atom. In the ninth O site, O(9) is bonded in a linear geometry to one Ga(3) and one P(1) atom. In the tenth O site, O(10) is bonded in a bent 150 degrees geometry to one Ga(3) and one P(3) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Ga(3) and one P(2) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Ga(3) and one P(1) atom. There are two inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Ga(1) and one Ga(2) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Ga(1) and one Ga(3) atom. Linkers: 4 [N]OP([O])([O])=O ,8 [O]P([O])([O])=O. Metal clusters: 12 [Ga]. The MOF has largest included sphere 4.03 A, density 2.44 g/cm3, surface area 1863.34 m2/g, accessible volume 0.17 cm3/g