AgC11N4H15CH crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of four 02329_fluka molecules inside a AgC11N4H15 framework. In the AgC11N4H15 framework, Ag(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Ag(1)-N(1) bond length is 2.31 Å. The Ag(1)-N(2) bond length is 2.35 Å. The Ag(1)-N(3) bond length is 2.34 Å. The Ag(1)-N(4) bond length is 2.33 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(5) bond length is 0.95 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(1), and one H(7) atom. The C(3)-C(5) bond length is 1.38 Å. The C(3)-N(1) bond length is 1.35 Å. The C(3)-H(7) bond length is 0.95 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(8) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(8) bond length is 0.95 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(10), one C(3), and one C(4) atom. The C(5)-C(10) bond length is 1.52 Å. In the fifth C site, C(6) is bonded in a 3-coordinate geometry to one C(7); one N(4); and two equivalent H(9,10) atoms. The C(6)-C(7) bond length is 1.52 Å. The C(6)-N(4) bond length is 1.48 Å. Both C(6)-H(9,10) bond lengths are 0.99 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(6), and one C(8) atom. The C(7)-C(12) bond length is 1.38 Å. The C(7)-C(8) bond length is 1.39 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(11) atom. The C(8)-H(11) bond length is 0.95 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(11) and one H(12) atom. The C(9)-C(11) bond length is 1.39 Å. The C(9)-H(12) bond length is 0.95 Å. In the ninth C site, C(10) is bonded in a 3-coordinate geometry to one C(5), one N(2), one H(13), and one H(14) atom. The C(10)-N(2) bond length is 1.47 Å. The C(10)-H(13) bond length is 0.99 Å. The C(10)-H(14) bond length is 0.99 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to one C(9), one N(3), and one H(15) atom. The C(11)-N(3) bond length is 1.33 Å. The C(11)-H(15) bond length is 0.95 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(7), one N(3), and one H(16) atom. The C(12)-N(3) bond length is 1.35 Å. The C(12)-H(16) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one Ag(1); one C(10); and two equivalent H(1,2) atoms. Both N(2)-H(1,2) bond lengths are 0.92 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Ag(1), one C(11), and one C(12) atom. In the fourth N site, N(4) is bonded in a 2-coordinate geometry to one Ag(1); one C(6); and two equivalent H(3,4) atoms. Both N(4)-H(3,4) bond lengths are 0.92 Å. There are twelve inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(3,4) is bonded in a single-bond geometry to one N(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(9,10) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(12) atom. Linkers: 8 NCc1cccnc1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 4.69 A, density 1.25 g/cm3, surface area 4630.69 m2/g, accessible volume 0.37 cm3/g