Zn3C48H30(NO6)2(C3H2)8(CH)4(C7NH4)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; eight 2,3-dimethyl-1,3-butadiene molecules; four schembl5425382 molecules; and two Zn3C48H30(NO6)2 clusters. In each Zn3C48H30(NO6)2 cluster, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a tetrahedral geometry to one N(2), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(2) bond length is 2.01 Å. The Zn(1)-O(2) bond length is 1.90 Å. The Zn(1)-O(3) bond length is 1.97 Å. The Zn(1)-O(4) bond length is 1.94 Å. In the second Zn site, Zn(2) is bonded in a trigonal pyramidal geometry to one O(1), one O(5), one O(7), and one O(8) atom. The Zn(2)-O(1) bond length is 1.97 Å. The Zn(2)-O(5) bond length is 1.98 Å. The Zn(2)-O(7) bond length is 1.98 Å. The Zn(2)-O(8) bond length is 2.05 Å. In the third Zn site, Zn(3) is bonded in a 6-coordinate geometry to one N(1), one O(10), one O(11), one O(12), one O(7), and one O(9) atom. The Zn(3)-N(1) bond length is 2.04 Å. The Zn(3)-O(10) bond length is 2.20 Å. The Zn(3)-O(11) bond length is 2.36 Å. The Zn(3)-O(12) bond length is 1.97 Å. The Zn(3)-O(7) bond length is 2.23 Å. The Zn(3)-O(9) bond length is 2.01 Å. There are forty-eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(4) and one H(1) atom. The C(1)-C(4) bond length is 1.43 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(32), one C(4), and one H(2) atom. The C(2)-C(32) bond length is 1.36 Å. The C(2)-C(4) bond length is 1.38 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(4) and one H(3) atom. The C(3)-C(4) bond length is 1.43 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(3) atom. In the fifth C site, C(5) is bonded in a single-bond geometry to one C(8) and one H(4) atom. The C(5)-C(8) bond length is 1.52 Å. The C(5)-H(4) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(3), and one O(5) atom. The C(6)-C(25) bond length is 1.51 Å. The C(6)-O(3) bond length is 1.24 Å. The C(6)-O(5) bond length is 1.30 Å. In the seventh C site, C(7) is bonded in a single-bond geometry to one C(8) and one H(5) atom. The C(7)-C(8) bond length is 1.27 Å. The C(7)-H(5) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(5), and one C(7) atom. The C(8)-C(10) bond length is 1.26 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(9)-N(1) bond length is 1.30 Å. The C(9)-H(6) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(13), one C(8), and one H(7) atom. The C(10)-C(13) bond length is 1.43 Å. The C(10)-H(7) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(11)-N(2) bond length is 1.36 Å. The C(11)-H(8) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(1), and one O(2) atom. The C(12)-C(16) bond length is 1.44 Å. The C(12)-O(1) bond length is 1.26 Å. The C(12)-O(2) bond length is 1.27 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(1), and one H(9) atom. The C(13)-N(1) bond length is 1.39 Å. The C(13)-H(9) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(25) and one H(10) atom. The C(14)-C(25) bond length is 1.41 Å. The C(14)-H(10) bond length is 0.93 Å. In the fifteenth C site, C(16) is bonded in a trigonal planar geometry to one C(12), one C(24), and one C(50) atom. The C(16)-C(24) bond length is 1.41 Å. The C(16)-C(50) bond length is 1.31 Å. In the sixteenth C site, C(17) is bonded in a trigonal planar geometry to one C(18), one C(21), and one C(22) atom. The C(17)-C(18) bond length is 1.47 Å. The C(17)-C(21) bond length is 1.42 Å. The C(17)-C(22) bond length is 1.42 Å. In the seventeenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(4), and one O(6) atom. The C(18)-O(4) bond length is 1.26 Å. The C(18)-O(6) bond length is 1.25 Å. In the eighteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(17) and one H(11) atom. The C(21)-H(11) bond length is 0.93 Å. In the nineteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(17) and one H(12) atom. The C(22)-H(12) bond length is 0.93 Å. In the twentieth C site, C(24) is bonded in a distorted single-bond geometry to one C(16) and one H(14) atom. The C(24)-H(14) bond length is 0.93 Å. In the twenty-first C site, C(25) is bonded in a trigonal planar geometry to one C(14), one C(30), and one C(6) atom. The C(25)-C(30) bond length is 1.39 Å. In the twenty-second C site, C(30) is bonded in a distorted single-bond geometry to one C(25) and one H(18) atom. The C(30)-H(18) bond length is 0.93 Å. In the twenty-third C site, C(32) is bonded in a 3-coordinate geometry to one C(2), one N(2), and one H(20) atom. The C(32)-N(2) bond length is 1.36 Å. The C(32)-H(20) bond length is 0.93 Å. In the twenty-fourth C site, C(50) is bonded in a distorted single-bond geometry to one C(16) and one H(33) atom. The C(50)-H(33) bond length is 0.93 Å. In the twenty-fifth C site, C(52) is bonded in a bent 120 degrees geometry to one C(58), one O(10), and one O(7) atom. The C(52)-C(58) bond length is 1.48 Å. The C(52)-O(10) bond length is 1.19 Å. The C(52)-O(7) bond length is 1.36 Å. In the twenty-sixth C site, C(53) is bonded in a distorted single-bond geometry to one C(58), one C(72), and one H(35) atom. The C(53)-C(58) bond length is 1.37 Å. The C(53)-C(72) bond length is 1.36 Å. The C(53)-H(35) bond length is 0.93 Å. In the twenty-seventh C site, C(54) is bonded in a distorted bent 120 degrees geometry to one C(55), one O(12), and one O(8) atom. The C(54)-C(55) bond length is 1.45 Å. The C(54)-O(12) bond length is 1.23 Å. The C(54)-O(8) bond length is 1.26 Å. In the twenty-eighth C site, C(55) is bonded in a trigonal planar geometry to one C(54), one C(81), and one C(87) atom. The C(55)-C(81) bond length is 1.35 Å. The C(55)-C(87) bond length is 1.46 Å. In the twenty-ninth C site, C(56) is bonded in a distorted single-bond geometry to one C(63) and one H(36) atom. The C(56)-C(63) bond length is 1.34 Å. The C(56)-H(36) bond length is 0.93 Å. In the thirtieth C site, C(58) is bonded in a trigonal planar geometry to one C(52), one C(53), and one C(62) atom. The C(58)-C(62) bond length is 1.33 Å. In the thirty-first C site, C(62) is bonded in a distorted single-bond geometry to one C(58) and one H(37) atom. The C(62)-H(37) bond length is 0.93 Å. In the thirty-second C site, C(63) is bonded in a trigonal planar geometry to one C(56), one C(65), and one C(72) atom. The C(63)-C(65) bond length is 1.57 Å. The C(63)-C(72) bond length is 1.37 Å. In the thirty-third C site, C(64) is bonded in a trigonal planar geometry to one C(68), one C(82), and one C(84) atom. The C(64)-C(68) bond length is 1.39 Å. The C(64)-C(82) bond length is 1.41 Å. The C(64)-C(84) bond length is 1.44 Å. In the thirty-fourth C site, C(65) is bonded in a trigonal planar geometry to one C(63), one C(77), and one C(79) atom. The C(65)-C(77) bond length is 1.34 Å. The C(65)-C(79) bond length is 1.40 Å. In the thirty-fifth C site, C(68) is bonded in a distorted single-bond geometry to one C(64) and one H(40) atom. The C(68)-H(40) bond length is 0.93 Å. In the thirty-sixth C site, C(69) is bonded in a distorted single-bond geometry to one C(73) and one H(41) atom. The C(69)-C(73) bond length is 1.43 Å. The C(69)-H(41) bond length is 0.93 Å. In the thirty-seventh C site, C(72) is bonded in a distorted trigonal planar geometry to one C(53), one C(63), and one H(44) atom. The C(72)-H(44) bond length is 0.93 Å. In the thirty-eighth C site, C(73) is bonded in a trigonal planar geometry to one C(69), one C(74), and one C(76) atom. The C(73)-C(74) bond length is 1.47 Å. The C(73)-C(76) bond length is 1.42 Å. In the thirty-ninth C site, C(74) is bonded in a trigonal planar geometry to one C(73), one C(80), and one C(90) atom. The C(74)-C(80) bond length is 1.35 Å. The C(74)-C(90) bond length is 1.39 Å. In the fortieth C site, C(76) is bonded in a distorted single-bond geometry to one C(73) and one H(46) atom. The C(76)-H(46) bond length is 0.93 Å. In the forty-first C site, C(77) is bonded in a distorted single-bond geometry to one C(65) and one H(47) atom. The C(77)-H(47) bond length is 0.93 Å. In the forty-second C site, C(79) is bonded in a distorted single-bond geometry to one C(65) and one H(48) atom. The C(79)-H(48) bond length is 0.93 Å. In the forty-third C site, C(80) is bonded in a distorted single-bond geometry to one C(74) and one H(49) atom. The C(80)-H(49) bond length is 0.93 Å. In the forty-fourth C site, C(81) is bonded in a distorted single-bond geometry to one C(55) and one H(50) atom. The C(81)-H(50) bond length is 0.93 Å. In the forty-fifth C site, C(82) is bonded in a distorted trigonal planar geometry to one C(64), one C(90), and one H(51) atom. The C(82)-C(90) bond length is 1.37 Å. The C(82)-H(51) bond length is 0.93 Å. In the forty-sixth C site, C(84) is bonded in a distorted bent 120 degrees geometry to one C(64), one O(11), and one O(9) atom. The C(84)-O(11) bond length is 1.21 Å. The C(84)-O(9) bond length is 1.27 Å. In the forty-seventh C site, C(87) is bonded in a distorted single-bond geometry to one C(55) and one H(55) atom. The C(87)-H(55) bond length is 0.93 Å. In the forty-eighth C site, C(90) is bonded in a distorted single-bond geometry to one C(74), one C(82), and one H(58) atom. The C(90)-H(58) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(3), one C(13), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(32) atom. There are thirty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(32) atom. In the sixteenth H site, H(33) is bonded in a single-bond geometry to one C(50) atom. In the seventeenth H site, H(35) is bonded in a single-bond geometry to one C(53) atom. In the eighteenth H site, H(36) is bonded in a single-bond geometry to one C(56) atom. In the nineteenth H site, H(37) is bonded in a single-bond geometry to one C(62) atom. In the twentieth H site, H(40) is bonded in a single-bond geometry to one C(68) atom. In the twenty-first H site, H(41) is bonded in a single-bond geometry to one C(69) atom. In the twenty-second H site, H(44) is bonded in a single-bond geometry to one C(72) atom. In the twenty-third H site, H(46) is bonded in a single-bond geometry to one C(76) atom. In the twenty-fourth H site, H(47) is bonded in a single-bond geometry to one C(77) atom. In the twenty-fifth H site, H(48) is bonded in a single-bond geometry to one C(79) atom. In the twenty-sixth H site, H(49) is bonded in a single-bond geometry to one C(80) atom. In the twenty-seventh H site, H(50) is bonded in a single-bond geometry to one C(81) atom. In the twenty-eighth H site, H(51) is bonded in a single-bond geometry to one C(82) atom. In the twenty-ninth H site, H(55) is bonded in a single-bond geometry to one C(87) atom. In the thirtieth H site, H(58) is bonded in a single-bond geometry to one C(90) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(12) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(12) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the fourth O site, O(4) is bonded in a water-like geometry to one Zn(1) and one C(18) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(6) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(18) atom. In the seventh O site, O(7) is bonded in a 3-coordinate geometry to one Zn(2), one Zn(3), and one C(52) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(54) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one Zn(3) and one C(84) atom. In the tenth O site, O(10) is bonded in an L-shaped geometry to one Zn(3) and one C(52) atom. In the eleventh O site, O(11) is bonded in a distorted L-shaped geometry to one Zn(3) and one C(84) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Zn(3) and one C(54) atom. Linkers: 3 [O]C(=O)c1ccc(-c2ccc(N(c3ccc(-c4ccc(C([O])=O)cc4)cc3)c3ccc(-c4ccc(C([O])=O)cc4)cc3)cc2)cc1 ,1 [O]C(=O)c1ccc(-c2ccc(N(c3ccc(-c4ccc([C]=O)cc4)cc3)c3ccc(-c4ccc(C([O])=O)cc4)cc3)cc2)cc1 ,2 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 2 O=[C]O[Zn]1O[C]O[Zn]2(O[C]O1)O[C]O[Zn](O[C]=O)O[C]O2. The MOF has largest included sphere 10.27 A, density 0.70 g/cm3, surface area 4730.96 m2/g, accessible volume 0.90 cm3/g