ZnC10H7(NO2)2(CH)4C4H3 crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, eight isobutylene molecules, and four ZnC10H7(NO2)2 clusters. In each ZnC10H7(NO2)2 cluster, Zn(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.17 Å. The Zn(1)-N(2) bond length is 2.17 Å. The Zn(1)-O(1) bond length is 2.09 Å. The Zn(1)-O(2) bond length is 2.47 Å. The Zn(1)-O(3) bond length is 2.03 Å. The Zn(1)-O(4) bond length is 2.01 Å. There are ten inequivalent C sites. In the first C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(7) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-C(9) bond length is 1.38 Å. The C(10)-H(7) bond length is 0.94 Å. In the second C site, C(11) is bonded in a 3-coordinate geometry to one C(10), one N(1), and one H(8) atom. The C(11)-N(1) bond length is 1.34 Å. The C(11)-H(8) bond length is 0.94 Å. In the third C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(8) atom. The C(9)-C(12) bond length is 1.47 Å. The C(9)-C(8) bond length is 1.39 Å. In the fourth C site, C(12) is bonded in a distorted single-bond geometry to one C(9) and one H(9) atom. The C(12)-H(9) bond length is 0.94 Å. In the fifth C site, C(14) is bonded in a 2-coordinate geometry to one N(2) and one H(11) atom. The C(14)-N(2) bond length is 1.34 Å. The C(14)-H(11) bond length is 0.94 Å. In the sixth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(14) atom. The C(18)-N(2) bond length is 1.33 Å. The C(18)-H(14) bond length is 0.94 Å. In the seventh C site, C(1) is bonded in a bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.24 Å. In the eighth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(6)-O(3) bond length is 1.25 Å. The C(6)-O(4) bond length is 1.26 Å. In the ninth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(7)-N(1) bond length is 1.35 Å. The C(7)-H(5) bond length is 0.94 Å. In the tenth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(8)-H(6) bond length is 0.94 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(14), and one C(18) atom. There are seven inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(18) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(6) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(6) atom. Linkers: 6 [O]C(=O)/C=C/C=C/C([O])=O ,2 [O]C(=O)/C=C/C=C/[C]=O ,4 C(=C/c1ccncc1)\c1ccncc1. Metal clusters: 4 O=[C]O[Zn]1O[C]O[Zn](O[C]=O)O[C]O1. RCSR code: sql. The MOF has largest included sphere 4.05 A, density 1.20 g/cm3, surface area 4869.75 m2/g, accessible volume 0.35 cm3/g