Al2C13H7O10(C5H3)3 is Indium-derived structured and crystallizes in the tetragonal P4_22_12 space group. The structure is zero-dimensional and consists of eight 1,3,5-triisopropenyl benzene molecules and two Al2C13H7O10 clusters. In each Al2C13H7O10 cluster, there are three inequivalent Al sites. In the first Al site, Al(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(6) atom to form corner-sharing AlO6 octahedra. The corner-sharing octahedral tilt angles are 53°. The Al(1)-O(1) bond length is 1.88 Å. The Al(1)-O(2) bond length is 1.94 Å. The Al(1)-O(3) bond length is 1.93 Å. The Al(1)-O(4) bond length is 1.84 Å. The Al(1)-O(5) bond length is 1.87 Å. The Al(1)-O(6) bond length is 1.89 Å. In the second Al site, Al(2) is bonded to two equivalent O(10), two equivalent O(5), and two equivalent O(8) atoms to form corner-sharing AlO6 octahedra. The corner-sharing octahedral tilt angles are 53°. Both Al(2)-O(10) bond lengths are 1.93 Å. Both Al(2)-O(5) bond lengths are 1.86 Å. Both Al(2)-O(8) bond lengths are 1.90 Å. In the third Al site, Al(3) is bonded to two equivalent O(4), two equivalent O(7), and two equivalent O(9) atoms to form corner-sharing AlO6 octahedra. The corner-sharing octahedral tilt angles are 53°. Both Al(3)-O(4) bond lengths are 1.86 Å. Both Al(3)-O(7) bond lengths are 1.91 Å. Both Al(3)-O(9) bond lengths are 1.89 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(14), one C(2), and one C(21) atom. The C(1)-C(14) bond length is 1.41 Å. The C(1)-C(2) bond length is 1.47 Å. The C(1)-C(21) bond length is 1.40 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(2), and one O(9) atom. The C(2)-O(2) bond length is 1.27 Å. The C(2)-O(9) bond length is 1.28 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(3)-C(5) bond length is 1.39 Å. The C(3)-C(7) bond length is 1.49 Å. The C(3)-C(9) bond length is 1.39 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(1,3) atom. The C(5)-H(1,3) bond length is 0.95 Å. In the fifth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(8) atom. The C(7)-O(1) bond length is 1.27 Å. The C(7)-O(8) bond length is 1.26 Å. In the sixth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(6), and one O(7) atom. The C(4)-C(6) bond length is 1.50 Å. The C(4)-O(6) bond length is 1.28 Å. The C(4)-O(7) bond length is 1.25 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(3) and one H(1,3) atom. The C(9)-H(1,3) bond length is 0.95 Å. In the eighth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(4), and one C(8) atom. The C(6)-C(11) bond length is 1.39 Å. The C(6)-C(8) bond length is 1.39 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(1) and one H(8) atom. The C(14)-H(8) bond length is 0.95 Å. In the tenth C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one H(2) atom. The C(8)-H(2) bond length is 0.95 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(6) and one H(5) atom. The C(11)-H(5) bond length is 0.95 Å. In the twelfth C site, C(21) is bonded in a single-bond geometry to one C(1) and one H(11) atom. The C(21)-H(11) bond length is 0.95 Å. In the thirteenth C site, C(25) is bonded in a trigonal planar geometry to one H(15), one O(10), and one O(3) atom. The C(25)-H(15) bond length is 0.95 Å. The C(25)-O(10) bond length is 1.26 Å. The C(25)-O(3) bond length is 1.28 Å. There are six inequivalent H sites. In the first H site, H(1,3) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Al(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Al(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Al(1) and one C(25) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Al(1) and one Al(3) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Al(1) and one Al(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Al(1) and one C(4) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Al(3) and one C(4) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Al(2) and one C(7) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Al(3) and one C(2) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Al(2) and one C(25) atom. Linkers: 8 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C([O])=O)cc3)c2)cc1. Metal clusters: 2 [C]1O[Al]2345O[C]O[Al]67(O1)(O[C]O[Al]18(O[C]O[Al]9%10(O[C]O[Al]%11%12(O[C]O9)(O[C]O[Al]9%13(O[C]O%11)(O[C]O[Al]%11%14(O[C]O[Al](O[C]O2)(O[C]O3)(O[CH]O%11)(O4)O%14)(O[CH]O9)O%13)O%12)O%10)(O[CH]O1)O8)(O[CH]O6)O7)O5. RCSR code: fon. The MOF has largest included sphere 9.95 A, density 0.57 g/cm3, surface area 4448.03 m2/g, accessible volume 1.16 cm3/g