ZnC10NH6O4C3H2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two 2,3-dimethyl-1,3-butadiene molecules and two ZnC10NH6O4 clusters. In each ZnC10NH6O4 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(2), one O(2), one O(4), one O(6), and one O(8) atom. The Zn(1)-N(2) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.03 Å. The Zn(1)-O(4) bond length is 2.02 Å. The Zn(1)-O(6) bond length is 2.02 Å. The Zn(1)-O(8) bond length is 2.03 Å. In the second Zn site, Zn(2) is bonded in a trigonal bipyramidal geometry to one N(1), one O(1), one O(3), one O(5), and one O(7) atom. The Zn(2)-N(1) bond length is 2.07 Å. The Zn(2)-O(1) bond length is 2.05 Å. The Zn(2)-O(3) bond length is 2.05 Å. The Zn(2)-O(5) bond length is 1.99 Å. The Zn(2)-O(7) bond length is 2.02 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.44 Å. The C(2)-C(7) bond length is 1.35 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.46 Å. The C(4)-H(2) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.30 Å. The C(5)-C(8) bond length is 1.51 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.23 Å. The C(8)-O(4) bond length is 1.25 Å. In the ninth C site, C(9) is bonded in a bent 120 degrees geometry to one C(10), one O(5), and one O(6) atom. The C(9)-C(10) bond length is 1.48 Å. The C(9)-O(5) bond length is 1.28 Å. The C(9)-O(6) bond length is 1.25 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(15) bond length is 1.40 Å. In the eleventh C site, C(11) is bonded in a single-bond geometry to one C(10) and one H(5,8) atom. The C(11)-H(5,8) bond length is 0.95 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(6,7) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(6,7) bond length is 0.95 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-C(16) bond length is 1.50 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(6,7) atom. The C(14)-H(6,7) bond length is 0.95 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one H(5,8) atom. The C(15)-H(5,8) bond length is 0.95 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(7), and one O(8) atom. The C(16)-O(7) bond length is 1.28 Å. The C(16)-O(8) bond length is 1.25 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(17)-N(1) bond length is 1.32 Å. The C(17)-H(9) bond length is 0.95 Å. In the eighteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(12) atom. The C(21)-N(1) bond length is 1.32 Å. The C(21)-H(12) bond length is 0.95 Å. In the nineteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(14) atom. The C(24)-N(2) bond length is 1.33 Å. The C(24)-H(14) bond length is 0.95 Å. In the twentieth C site, C(25) is bonded in a 2-coordinate geometry to one N(2) and one H(15) atom. The C(25)-N(2) bond length is 1.29 Å. The C(25)-H(15) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(17), and one C(21) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(24), and one C(25) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5,8) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6,7) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(9) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(16) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(16) atom. Linkers: 4 [O]C(=O)c1ccc(C([O])=O)cc1 ,2 c1cc(-c2ccncc2)ccn1. Metal clusters: 2 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: sql. The MOF has largest included sphere 5.58 A, density 1.24 g/cm3, surface area 4045.23 m2/g, accessible volume 0.39 cm3/g