Cu2C28N7H22O4(C3H2)4CH2C2NH2 crystallizes in the tetragonal P4_3 space group. The structure consists of four 02329_fluka molecules; eight 2,3-dimethyl-1,3-butadiene molecules; and four dimethylamine molecules inside a Cu2C28N7H22O4 framework. In the Cu2C28N7H22O4 framework, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Cu(1)-N(1) bond length is 2.01 Å. The Cu(1)-N(2) bond length is 2.02 Å. The Cu(1)-O(1) bond length is 1.91 Å. The Cu(1)-O(2) bond length is 1.92 Å. In the second Cu site, Cu(2) is bonded in an octahedral geometry to one N(5), one N(6), one N(7), one N(8), one O(3), and one O(4) atom. The Cu(2)-N(5) bond length is 2.09 Å. The Cu(2)-N(6) bond length is 2.07 Å. The Cu(2)-N(7) bond length is 2.07 Å. The Cu(2)-N(8) bond length is 2.08 Å. The Cu(2)-O(3) bond length is 2.35 Å. The Cu(2)-O(4) bond length is 2.29 Å. There are twenty-eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.34 Å. The C(1)-N(1) bond length is 1.37 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.32 Å. The C(3)-C(6) bond length is 1.50 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.30 Å. The C(5)-H(4) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(10), one C(3), and one C(7) atom. The C(6)-C(10) bond length is 1.32 Å. The C(6)-C(7) bond length is 1.39 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.30 Å. The C(7)-H(5) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one N(3), and one H(6) atom. The C(8)-N(3) bond length is 1.32 Å. The C(8)-H(6) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(7) atom. The C(9)-N(3) bond length is 1.29 Å. The C(9)-H(7) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(6) and one H(8) atom. The C(10)-H(8) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(9) bond length is 0.93 Å. In the twelfth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(12) atom. The C(15)-N(2) bond length is 1.29 Å. The C(15)-H(12) bond length is 0.93 Å. In the thirteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(21)-O(2) bond length is 1.25 Å. The C(21)-O(4) bond length is 1.25 Å. In the fourteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(23)-O(1) bond length is 1.28 Å. The C(23)-O(3) bond length is 1.22 Å. In the fifteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(19) atom. The C(24)-N(5) bond length is 1.35 Å. The C(24)-H(19) bond length is 0.93 Å. In the sixteenth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(22) atom. The C(28)-N(5) bond length is 1.26 Å. The C(28)-H(22) bond length is 0.93 Å. In the seventeenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(24) atom. The C(31)-N(7) bond length is 1.31 Å. The C(31)-H(24) bond length is 0.93 Å. In the eighteenth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(25) atom. The C(32)-N(7) bond length is 1.37 Å. The C(32)-H(25) bond length is 0.93 Å. In the nineteenth C site, C(34) is bonded in a distorted trigonal planar geometry to one C(35), one N(6), and one H(27) atom. The C(34)-C(35) bond length is 1.37 Å. The C(34)-N(6) bond length is 1.39 Å. The C(34)-H(27) bond length is 0.93 Å. In the twentieth C site, C(35) is bonded in a distorted single-bond geometry to one C(34), one C(36), and one H(28) atom. The C(35)-C(36) bond length is 1.38 Å. The C(35)-H(28) bond length is 0.93 Å. In the twenty-first C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(39) atom. The C(36)-C(37) bond length is 1.39 Å. The C(36)-C(39) bond length is 1.47 Å. In the twenty-second C site, C(37) is bonded in a distorted single-bond geometry to one C(36), one C(38), and one H(29) atom. The C(37)-C(38) bond length is 1.38 Å. The C(37)-H(29) bond length is 0.93 Å. In the twenty-third C site, C(38) is bonded in a distorted trigonal planar geometry to one C(37), one N(6), and one H(30) atom. The C(38)-N(6) bond length is 1.30 Å. The C(38)-H(30) bond length is 0.93 Å. In the twenty-fourth C site, C(39) is bonded in a trigonal planar geometry to one C(36), one C(40), and one C(43) atom. The C(39)-C(40) bond length is 1.40 Å. The C(39)-C(43) bond length is 1.39 Å. In the twenty-fifth C site, C(40) is bonded in a distorted single-bond geometry to one C(39), one C(41), and one H(31) atom. The C(40)-C(41) bond length is 1.35 Å. The C(40)-H(31) bond length is 0.93 Å. In the twenty-sixth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(40), one N(8), and one H(32) atom. The C(41)-N(8) bond length is 1.36 Å. The C(41)-H(32) bond length is 0.93 Å. In the twenty-seventh C site, C(42) is bonded in a distorted trigonal planar geometry to one C(43), one N(8), and one H(33) atom. The C(42)-C(43) bond length is 1.34 Å. The C(42)-N(8) bond length is 1.31 Å. The C(42)-H(33) bond length is 0.93 Å. In the twenty-eighth C site, C(43) is bonded in a distorted single-bond geometry to one C(39), one C(42), and one H(34) atom. The C(43)-H(34) bond length is 0.93 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(11), and one C(15) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(8) and one C(9) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one Cu(2), one C(24), and one C(28) atom. In the fifth N site, N(6) is bonded in a trigonal planar geometry to one Cu(2), one C(34), and one C(38) atom. In the sixth N site, N(7) is bonded in a trigonal planar geometry to one Cu(2), one C(31), and one C(32) atom. In the seventh N site, N(8) is bonded in a trigonal planar geometry to one Cu(2), one C(41), and one C(42) atom. There are twenty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(24) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(28) atom. In the thirteenth H site, H(24) is bonded in a single-bond geometry to one C(31) atom. In the fourteenth H site, H(25) is bonded in a single-bond geometry to one C(32) atom. In the fifteenth H site, H(27) is bonded in a single-bond geometry to one C(34) atom. In the sixteenth H site, H(28) is bonded in a single-bond geometry to one C(35) atom. In the seventeenth H site, H(29) is bonded in a single-bond geometry to one C(37) atom. In the eighteenth H site, H(30) is bonded in a single-bond geometry to one C(38) atom. In the nineteenth H site, H(31) is bonded in a single-bond geometry to one C(40) atom. In the twentieth H site, H(32) is bonded in a single-bond geometry to one C(41) atom. In the twenty-first H site, H(33) is bonded in a single-bond geometry to one C(42) atom. In the twenty-second H site, H(34) is bonded in a single-bond geometry to one C(43) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(23) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(21) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cu(2) and one C(23) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cu(2) and one C(21) atom. Linkers: 4 [O]C(=O)CC([O])=O. Metal clusters: 8 [Cu]. The MOF has largest included sphere 4.61 A, density 1.21 g/cm3, surface area 4707.17 m2/g, accessible volume 0.36 cm3/g