ZnC10NH6O4C3H2(CH)8(C2O)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules; two 2,3-dimethyl-1,3-butadiene molecules; eight dimethyl ether molecules; and two ZnC10NH6O4 clusters. In each ZnC10NH6O4 cluster, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one O(1), one O(2), one O(5), and one O(6) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 2.03 Å. The Zn(1)-O(2) bond length is 2.04 Å. The Zn(1)-O(5) bond length is 2.05 Å. The Zn(1)-O(6) bond length is 2.03 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(4) bond length is 0.93 Å. In the third C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(1), and one O(2) atom. The C(6)-C(7) bond length is 1.50 Å. The C(6)-O(1) bond length is 1.26 Å. The C(6)-O(2) bond length is 1.26 Å. In the fourth C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(6), and one C(8) atom. The C(7)-C(12) bond length is 1.39 Å. The C(7)-C(8) bond length is 1.39 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(5,8) atom. The C(8)-H(5,8) bond length is 0.93 Å. In the sixth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(5,8) atom. The C(12)-H(5,8) bond length is 0.93 Å. In the seventh C site, C(22) is bonded in a distorted single-bond geometry to one C(23) and one H(15) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(15) bond length is 0.93 Å. In the eighth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(25) atom. The C(23)-C(24) bond length is 1.40 Å. The C(23)-C(25) bond length is 1.50 Å. In the ninth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(16) atom. The C(24)-H(16) bond length is 0.93 Å. In the tenth C site, C(25) is bonded in a bent 120 degrees geometry to one C(23), one O(5), and one O(6) atom. The C(25)-O(5) bond length is 1.26 Å. The C(25)-O(6) bond length is 1.26 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(5,8) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the fourth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(25) atom. Linkers: 4 [O]C(=O)c1cccc(Oc2ccc(Oc3cccc(C([O])=O)c3)cc2)c1 ,1 c1cc(-c2ccncc2)ccn1. Metal clusters: 1 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3 ,2 [Zn]. The MOF has largest included sphere 5.40 A, density 1.22 g/cm3, surface area 4552.03 m2/g, accessible volume 0.38 cm3/g