CuH14(C13O2)2(CuC11NH10O4)2 is Indium-like structured and crystallizes in the tetragonal I4_1/amd space group. The structure is zero-dimensional and consists of eight CuC11NH10O4 clusters and four CuH14(C13O2)2 clusters. In each CuC11NH10O4 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), two equivalent O(1), and two equivalent O(2) atoms. The Cu(1)-N(1) bond length is 2.19 Å. Both Cu(1)-O(1) bond lengths are 1.96 Å. Both Cu(1)-O(2) bond lengths are 1.96 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(7) bond length is 1.38 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(11) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent H(8) atoms. The C(11)-N(1) bond length is 1.41 Å. Both C(11)-H(8) bond lengths are 0.96 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the sixth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent H(6,7) atoms. The C(10)-N(1) bond length is 1.40 Å. Both C(10)-H(6,7) bond lengths are 0.97 Å. N(1) is bonded in a tetrahedral geometry to one Cu(1), one C(11), and two equivalent C(10) atoms. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(6,7) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(11) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In each CuH14(C13O2)2 cluster, Cu(2) is bonded in a distorted rectangular see-saw-like geometry to four equivalent O(3) atoms. All Cu(2)-O(3) bond lengths are 1.95 Å. There are eight inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(2) bond length is 0.93 Å. In the second C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.38 Å. The C(5)-C(8) bond length is 1.48 Å. In the third C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the fourth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(5), and one C(9) atom. The C(8)-C(12) bond length is 1.40 Å. The C(8)-C(9) bond length is 1.38 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(13), one C(8), and one H(5) atom. The C(9)-C(13) bond length is 1.38 Å. The C(9)-H(5) bond length is 0.93 Å. In the sixth C site, C(12) is bonded in a single-bond geometry to two equivalent C(8) and one H(9) atom. The C(12)-H(9) bond length is 0.93 Å. In the seventh C site, C(13) is bonded in a trigonal planar geometry to one C(14) and two equivalent C(9) atoms. The C(13)-C(14) bond length is 1.50 Å. In the eighth C site, C(14) is bonded in a bent 120 degrees geometry to one C(13) and two equivalent O(3) atoms. Both C(14)-O(3) bond lengths are 1.26 Å. There are four inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. O(3) is bonded in a distorted single-bond geometry to one Cu(2) and one C(14) atom. Linkers: 8 [O]C(=O)c1ccc(-c2cc(C([O])=O)cc(-c3ccc(C([O])=O)cc3)c2)cc1 ,4 C1CN2CCN1CC2. Metal clusters: 6 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: iab. The MOF has largest included sphere 12.58 A, density 0.60 g/cm3, surface area 4124.39 m2/g, accessible volume 1.34 cm3/g