Cu3C37H21(N3O4)2(CH)11 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of forty-four 02329_fluka molecules and four Cu3C37H21(N3O4)2 clusters. In each Cu3C37H21(N3O4)2 cluster, there are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one N(1), one N(2), one O(1), and one O(3) atom. The Cu(1)-N(1) bond length is 2.01 Å. The Cu(1)-N(2) bond length is 2.02 Å. The Cu(1)-O(1) bond length is 1.94 Å. The Cu(1)-O(3) bond length is 1.95 Å. In the second Cu site, Cu(2) is bonded in a 6-coordinate geometry to one N(3), one N(4), one O(2), one O(3), one O(5), and one O(7) atom. The Cu(2)-N(3) bond length is 2.00 Å. The Cu(2)-N(4) bond length is 2.01 Å. The Cu(2)-O(2) bond length is 1.93 Å. The Cu(2)-O(3) bond length is 2.64 Å. The Cu(2)-O(5) bond length is 1.94 Å. The Cu(2)-O(7) bond length is 2.59 Å. In the third Cu site, Cu(3) is bonded in a rectangular see-saw-like geometry to one N(5), one N(6), one O(6), and one O(7) atom. The Cu(3)-N(5) bond length is 2.02 Å. The Cu(3)-N(6) bond length is 2.00 Å. The Cu(3)-O(6) bond length is 1.93 Å. The Cu(3)-O(7) bond length is 1.95 Å. There are thirty-seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.94 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 0.94 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(5) atom. The C(4)-C(11) bond length is 1.44 Å. The C(4)-C(3) bond length is 1.40 Å. The C(4)-C(5) bond length is 1.41 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.42 Å. The C(5)-N(1) bond length is 1.37 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(2) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-N(2) bond length is 1.36 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(6), and one C(8) atom. The C(7)-C(12) bond length is 1.42 Å. The C(7)-C(8) bond length is 1.40 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(5) atom. The C(9)-C(10) bond length is 1.40 Å. The C(9)-H(5) bond length is 0.94 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(6) atom. The C(10)-N(2) bond length is 1.32 Å. The C(10)-H(6) bond length is 0.94 Å. In the ninth C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(3)-H(3) bond length is 0.94 Å. In the tenth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(8)-H(4) bond length is 0.94 Å. In the eleventh C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(11) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(11) bond length is 0.94 Å. In the twelfth C site, C(11) is bonded in a distorted single-bond geometry to one C(4) and one H(7) atom. The C(11)-H(7) bond length is 0.94 Å. In the thirteenth C site, C(12) is bonded in a single-bond geometry to one C(7) and one H(8) atom. The C(12)-H(8) bond length is 0.94 Å. In the fourteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(13)-N(3) bond length is 1.32 Å. The C(13)-H(9) bond length is 0.94 Å. In the fifteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one N(3) atom. The C(17)-C(16) bond length is 1.41 Å. The C(17)-C(18) bond length is 1.43 Å. The C(17)-N(3) bond length is 1.36 Å. In the sixteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one N(4) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-N(4) bond length is 1.36 Å. In the seventeenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(14) atom. The C(22)-N(4) bond length is 1.33 Å. The C(22)-H(14) bond length is 0.94 Å. In the eighteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-C(24) bond length is 1.44 Å. In the nineteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(12) atom. The C(20)-H(12) bond length is 0.94 Å. In the twentieth C site, C(23) is bonded in a distorted single-bond geometry to one C(16) and one H(15) atom. The C(23)-C(16) bond length is 1.43 Å. The C(23)-H(15) bond length is 0.94 Å. In the twenty-first C site, C(24) is bonded in a distorted single-bond geometry to one C(19) and one H(16) atom. The C(24)-H(16) bond length is 0.94 Å. In the twenty-second C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one N(5), and one H(17) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-N(5) bond length is 1.32 Å. The C(25)-H(17) bond length is 0.94 Å. In the twenty-third C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(18) atom. The C(26)-H(18) bond length is 0.94 Å. In the twenty-fourth C site, C(27) is bonded in a single-bond geometry to one C(28) and one H(19) atom. The C(27)-C(28) bond length is 1.40 Å. The C(27)-H(19) bond length is 0.94 Å. In the twenty-fifth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(35) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-C(35) bond length is 1.43 Å. In the twenty-sixth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one C(30), and one N(5) atom. The C(29)-C(30) bond length is 1.43 Å. The C(29)-N(5) bond length is 1.35 Å. In the twenty-seventh C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one C(31), and one N(6) atom. The C(30)-C(31) bond length is 1.40 Å. The C(30)-N(6) bond length is 1.36 Å. In the twenty-eighth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(37)-O(1) bond length is 1.25 Å. The C(37)-O(2) bond length is 1.26 Å. In the twenty-ninth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(36) atom. The C(31)-C(32) bond length is 1.40 Å. The C(31)-C(36) bond length is 1.43 Å. In the thirtieth C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(20) atom. The C(32)-H(20) bond length is 0.94 Å. In the thirty-first C site, C(40) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(40)-O(3) bond length is 1.29 Å. The C(40)-O(4) bond length is 1.24 Å. In the thirty-second C site, C(34) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(22) atom. The C(34)-N(6) bond length is 1.32 Å. The C(34)-H(22) bond length is 0.94 Å. In the thirty-third C site, C(35) is bonded in a single-bond geometry to one C(28) and one H(23) atom. The C(35)-H(23) bond length is 0.94 Å. In the thirty-fourth C site, C(36) is bonded in a distorted single-bond geometry to one C(31) and one H(24) atom. The C(36)-H(24) bond length is 0.94 Å. In the thirty-fifth C site, C(43) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(43)-O(5) bond length is 1.26 Å. The C(43)-O(6) bond length is 1.26 Å. In the thirty-sixth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one O(7) and one O(8) atom. The C(46)-O(7) bond length is 1.28 Å. The C(46)-O(8) bond length is 1.24 Å. In the thirty-seventh C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(23) atom. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(1), one C(10), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Cu(2), one C(13), and one C(17) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(18), and one C(22) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(3), one C(25), and one C(29) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(3), one C(30), and one C(34) atom. There are twenty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one C(34) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(35) atom. In the ninth H site, H(24) is bonded in a single-bond geometry to one C(36) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(32) atom. In the twelfth H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the thirteenth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fourteenth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the seventeenth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the eighteenth H site, H(11) is bonded in a single-bond geometry to one C(15) atom. In the nineteenth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the twentieth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the twenty-first H site, H(14) is bonded in a single-bond geometry to one C(22) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Cu(1) and one C(37) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Cu(2) and one C(37) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1), one Cu(2), and one C(40) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(40) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Cu(2) and one C(43) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Cu(3) and one C(43) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Cu(2), one Cu(3), and one C(46) atom. In the eighth O site, O(8) is bonded in a single-bond geometry to one C(46) atom. Linkers: 1 [O]C(=O)/C=C/C=C/[C]=O ,7 [O]C(=O)/C=C/C=C/C([O])=O ,2 c1cnc2c(c1)ccc1cccnc12. Metal clusters: 4 O=[C]O[Cu]O[C]O[Cu]O[C]O[Cu]O[C]=O. RCSR code: dia. The MOF has largest included sphere 4.26 A, density 1.27 g/cm3, surface area 4395.53 m2/g, accessible volume 0.35 cm3/g