Zn2H13(C14O5)2C3H crystallizes in the trigonal R3 space group. The structure consists of nine propane molecules inside a Zn2H13(C14O5)2 framework. In the Zn2H13(C14O5)2 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted square co-planar geometry to one O(2), one O(4), one O(8), and one O(9) atom. The Zn(1)-O(2) bond length is 2.01 Å. The Zn(1)-O(4) bond length is 1.91 Å. The Zn(1)-O(8) bond length is 2.11 Å. The Zn(1)-O(9) bond length is 2.03 Å. In the second Zn site, Zn(2) is bonded in a distorted square co-planar geometry to one O(1), one O(10), one O(3), and one O(7) atom. The Zn(2)-O(1) bond length is 2.09 Å. The Zn(2)-O(10) bond length is 2.01 Å. The Zn(2)-O(3) bond length is 1.97 Å. The Zn(2)-O(7) bond length is 2.02 Å. There are twenty-eight inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.24 Å. The C(1)-O(2) bond length is 1.24 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(2) atom. The C(5)-C(4) bond length is 1.39 Å. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(2) bond length is 0.95 Å. In the fourth C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 0.95 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(8)-C(4) bond length is 1.55 Å. The C(8)-O(3) bond length is 1.42 Å. The C(8)-O(4) bond length is 1.27 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(6) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(14) bond length is 1.39 Å. The C(9)-C(6) bond length is 1.52 Å. In the seventh C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one O(6) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-O(6) bond length is 1.49 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(4) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(4) bond length is 0.95 Å. In the ninth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one C(13), one C(19), and one C(26) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-C(19) bond length is 2.10 Å. The C(12)-C(26) bond length is 1.58 Å. In the tenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one O(5) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-O(5) bond length is 1.44 Å. In the eleventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one H(5) atom. The C(14)-H(5) bond length is 0.95 Å. In the twelfth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to two equivalent H(6,7) and one O(5) atom. Both C(15)-H(6,7) bond lengths are 0.99 Å. The C(15)-O(5) bond length is 1.51 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(17), one C(18), and one H(8) atom. The C(16)-C(17) bond length is 1.55 Å. The C(16)-C(18) bond length is 1.56 Å. The C(16)-H(8) bond length is 1.00 Å. In the fourteenth C site, C(17) is bonded in a water-like geometry to one C(16) and one C(19) atom. The C(17)-C(19) bond length is 1.66 Å. In the fifteenth C site, C(18) is bonded in a 2-coordinate geometry to one C(16) and one H(12) atom. The C(18)-H(12) bond length is 1.78 Å. In the sixteenth C site, C(19) is bonded in a bent 150 degrees geometry to one C(12) and one C(17) atom. In the seventeenth C site, C(20) is bonded in a distorted trigonal non-coplanar geometry to one H(10), one H(9), and one O(6) atom. The C(20)-H(10) bond length is 0.99 Å. The C(20)-H(9) bond length is 0.99 Å. The C(20)-O(6) bond length is 1.47 Å. In the eighteenth C site, C(24) is bonded in a bent 120 degrees geometry to one C(30), one O(7), and one O(8) atom. The C(24)-C(30) bond length is 1.46 Å. The C(24)-O(7) bond length is 1.31 Å. The C(24)-O(8) bond length is 1.13 Å. In the nineteenth C site, C(25) is bonded in a bent 120 degrees geometry to one C(28), one O(10), and one O(9) atom. The C(25)-C(28) bond length is 1.45 Å. The C(25)-O(10) bond length is 1.31 Å. The C(25)-O(9) bond length is 1.24 Å. In the twentieth C site, C(26) is bonded in a trigonal planar geometry to one C(12), one C(27), and one C(31) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-C(31) bond length is 1.39 Å. In the twenty-first C site, C(27) is bonded in a distorted single-bond geometry to one C(26), one C(28), and one H(12) atom. The C(27)-C(28) bond length is 1.39 Å. The C(27)-H(12) bond length is 0.95 Å. In the twenty-second C site, C(28) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(29) atom. The C(28)-C(29) bond length is 1.39 Å. In the twenty-third C site, C(29) is bonded in a distorted single-bond geometry to one C(28), one C(30), and one H(13) atom. The C(29)-C(30) bond length is 1.39 Å. The C(29)-H(13) bond length is 0.95 Å. In the twenty-fourth C site, C(30) is bonded in a trigonal planar geometry to one C(24), one C(29), and one C(31) atom. The C(30)-C(31) bond length is 1.39 Å. In the twenty-fifth C site, C(31) is bonded in a distorted single-bond geometry to one C(26), one C(30), and one H(14) atom. The C(31)-H(14) bond length is 0.95 Å. In the twenty-sixth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. In the twenty-seventh C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(6)-C(7) bond length is 1.39 Å. In the twenty-eighth C site, C(7) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(3) atom. The C(7)-H(3) bond length is 0.95 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(6,7) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(18) and one C(27) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(31) atom. There are ten inequivalent O sites. In the first O site, O(6) is bonded in a bent 120 degrees geometry to one C(10) and one C(20) atom. In the second O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(24) atom. In the third O site, O(8) is bonded in a distorted single-bond geometry to one Zn(1) and one C(24) atom. In the fourth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the fifth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(25) atom. In the sixth O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the seventh O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the eighth O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(8) atom. In the ninth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the tenth O site, O(5) is bonded in a bent 150 degrees geometry to one C(13) and one C(15) atom. Linkers: 9 [C][C][C@@H]([C])COc1cc(-c2cc(C([O])=O)cc(C([O])=O)c2)c(OCC([C])[C])cc1-c1cc(C([O])=O)cc(C([O])=O)c1. Metal clusters: 9 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: nbo. The MOF has largest included sphere 10.45 A, density 0.86 g/cm3, surface area 4203.91 m2/g, accessible volume 0.74 cm3/g