(ZnC15H11(NO2)2)2(CH)2C9H8O4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; four 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and eight ZnC15H11(NO2)2 clusters. In each ZnC15H11(NO2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(3), and one O(5) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-N(2) bond length is 2.03 Å. The Zn(1)-O(3) bond length is 1.95 Å. The Zn(1)-O(5) bond length is 1.95 Å. There are fifteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.36 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.35 Å. The C(5)-H(4) bond length is 0.93 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(2) atom. The C(2)-H(2) bond length is 0.93 Å. In the fourth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(9) atom. The C(8)-C(9) bond length is 1.38 Å. The C(8)-N(2) bond length is 1.35 Å. The C(8)-H(9) bond length is 0.93 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(10) atom. The C(9)-H(10) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(11)-C(12) bond length is 1.34 Å. The C(11)-H(11) bond length is 0.93 Å. In the seventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one H(12) atom. The C(12)-N(2) bond length is 1.37 Å. The C(12)-H(12) bond length is 0.93 Å. In the eighth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(3), and one O(4) atom. The C(13)-C(15) bond length is 1.51 Å. The C(13)-O(3) bond length is 1.27 Å. The C(13)-O(4) bond length is 1.23 Å. In the ninth C site, C(15) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(16) atom. The C(15)-C(14) bond length is 1.40 Å. The C(15)-C(16) bond length is 1.37 Å. In the tenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(5), and one O(6) atom. The C(17)-C(19) bond length is 1.50 Å. The C(17)-O(5) bond length is 1.26 Å. The C(17)-O(6) bond length is 1.24 Å. In the eleventh C site, C(19) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(20) atom. The C(19)-C(18) bond length is 1.39 Å. The C(19)-C(20) bond length is 1.41 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(13) atom. The C(14)-H(13) bond length is 0.93 Å. In the thirteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(14) atom. The C(16)-H(14) bond length is 0.93 Å. In the fourteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(15) atom. The C(18)-H(15) bond length is 0.93 Å. In the fifteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(16) atom. The C(20)-H(16) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(12), and one C(8) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(16) atom. There are four inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(13) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. In the fourth O site, O(6) is bonded in a single-bond geometry to one C(17) atom. Linkers: 1 O=[C]O[Zn].[CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C][O].[CH]=[C][O].[CH]C(=[CH])OC[C][CH][O].[CH]C(=[CH])[O].[CH][N].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[CH].[C]=[C]/C=C\[N].[C]=[C][O].[C]C([O])=O.[C][C].[C][C].[C][C].[C][N][C].[C][O].[C][O].[C][O].[C][O].[C][O].[C][O].[C][O].[C][O].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N]/C=C\[C][O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][Zn].[O][Zn][O].[Zn].[Zn].[Zn].[Zn] ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[C][O].[C]=[C][O].[C][C].[C][C].[C][C].[C][N].[C][N][C].[C][N][C].[C][O].[C][O].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][Zn].[Zn].[Zn] ,1 [O]C(=O)c1ccc(C([O])=O)cc1 ,1 [CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH][N].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]C([C])=[C].[C]O[C]=[C].[C][C][C].[C][N].[C][O].[C][O].[C][O].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][Zn].[O][Zn].[Zn].[Zn]. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 5.16 A, density 1.26 g/cm3, surface area 4726.12 m2/g, accessible volume 0.36 cm3/g