AgH12(C3N)6 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen AgH12(C3N)6 clusters. Ag(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(8) atom. The Ag(1)-N(1) bond length is 2.31 Å. The Ag(1)-N(2) bond length is 2.26 Å. The Ag(1)-N(8) bond length is 2.30 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(5), and one N(6) atom. The C(1)-C(15) bond length is 1.49 Å. The C(1)-N(5) bond length is 1.34 Å. The C(1)-N(6) bond length is 1.33 Å. In the second C site, C(4) is bonded in a distorted single-bond geometry to one C(10), one C(23), and one H(2) atom. The C(4)-C(10) bond length is 1.38 Å. The C(4)-C(23) bond length is 1.39 Å. The C(4)-H(2) bond length is 0.93 Å. In the third C site, C(5) is bonded in a distorted trigonal planar geometry to one C(10), one N(4), and one N(5) atom. The C(5)-C(10) bond length is 1.49 Å. The C(5)-N(4) bond length is 1.33 Å. The C(5)-N(5) bond length is 1.34 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(7)-N(1) bond length is 1.34 Å. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(4), and one C(5) atom. The C(10)-C(11) bond length is 1.38 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(13), and one H(6) atom. The C(11)-C(13) bond length is 1.36 Å. The C(11)-H(6) bond length is 0.93 Å. In the seventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(11), one N(2), and one H(8) atom. The C(13)-N(2) bond length is 1.34 Å. The C(13)-H(8) bond length is 0.93 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(32) and one H(9) atom. The C(14)-C(32) bond length is 1.40 Å. The C(14)-H(9) bond length is 0.93 Å. In the ninth C site, C(15) is bonded in a trigonal planar geometry to one C(1), one C(25), and one C(33) atom. The C(15)-C(25) bond length is 1.38 Å. The C(15)-C(33) bond length is 1.38 Å. In the tenth C site, C(16) is bonded in a distorted single-bond geometry to one C(32) and one H(10) atom. The C(16)-C(32) bond length is 1.39 Å. The C(16)-H(10) bond length is 0.93 Å. In the eleventh C site, C(20) is bonded in a distorted trigonal planar geometry to one C(32), one N(4), and one N(6) atom. The C(20)-C(32) bond length is 1.49 Å. The C(20)-N(4) bond length is 1.34 Å. The C(20)-N(6) bond length is 1.34 Å. In the twelfth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(12) atom. The C(21)-N(8) bond length is 1.35 Å. The C(21)-H(12) bond length is 0.93 Å. In the thirteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(4), one N(2), and one H(14) atom. The C(23)-N(2) bond length is 1.33 Å. The C(23)-H(14) bond length is 0.93 Å. In the fourteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(15) and one H(16) atom. The C(25)-H(16) bond length is 0.93 Å. In the fifteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(17) atom. The C(26)-N(8) bond length is 1.33 Å. The C(26)-H(17) bond length is 0.93 Å. In the sixteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(18) atom. The C(27)-N(1) bond length is 1.33 Å. The C(27)-H(18) bond length is 0.93 Å. In the seventeenth C site, C(32) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(20) atom. In the eighteenth C site, C(33) is bonded in a distorted single-bond geometry to one C(15) and one H(21) atom. The C(33)-H(21) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(27), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(13), and one C(23) atom. In the third N site, N(4) is bonded in a bent 120 degrees geometry to one C(20) and one C(5) atom. In the fourth N site, N(5) is bonded in a bent 120 degrees geometry to one C(1) and one C(5) atom. In the fifth N site, N(6) is bonded in a bent 120 degrees geometry to one C(1) and one C(20) atom. In the sixth N site, N(8) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(21), and one C(26) atom. There are twelve inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(27) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(33) atom. Linkers: 2 n1ccc(cc1)C1=NC(=[N]=C([N]1)c1ccncc1)c1ccncc1 ,1 n1ccc(cc1)C1=NC(=[N]=C([N]1)c1ccncc1)C1=C[CH]N(C=C1)[Ag](N1[CH]C=C(C=C1)C1=NC(=[N]=C([N]1)c1ccncc1)c1ccncc1)N1[CH]C=C(C=C1)C1=NC(=[N]=C([N]1)c1ccncc1)c1ccncc1 ,1 n1ccc(cc1)C1=NC(=[N]=C([N]1)c1ccncc1)C1=C[CH]N(C=C1)[Ag](N1[CH]C=C(C=C1)C1=[N]=C([N]C(=N1)c1ccncc1)c1ccncc1)N1[CH]C=C(C=C1)C1=[N]=C(N=C([N]1)c1ccncc1)c1ccncc1. Metal clusters: 6 [Ag]. The MOF has largest included sphere 7.04 A, density 1.32 g/cm3, surface area 4087.71 m2/g, accessible volume 0.26 cm3/g