CdC25H21(NO)4CH is Indium-derived structured and crystallizes in the tetragonal I-4 space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and eight CdC25H21(NO)4 clusters. In each CdC25H21(NO)4 cluster, Cd(1) is bonded in a distorted pentagonal pyramidal geometry to one N(1), one N(4), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.35 Å. The Cd(1)-N(4) bond length is 2.38 Å. The Cd(1)-O(1) bond length is 2.57 Å. The Cd(1)-O(2) bond length is 2.41 Å. The Cd(1)-O(3) bond length is 2.43 Å. The Cd(1)-O(4) bond length is 2.48 Å. There are twenty-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one H(17) atom. The C(1)-C(6) bond length is 1.39 Å. The C(1)-H(17) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(7), one O(1), and one O(2) atom. The C(2)-C(7) bond length is 1.50 Å. The C(2)-O(1) bond length is 1.27 Å. The C(2)-O(2) bond length is 1.27 Å. In the third C site, C(3) is bonded in a 3-coordinate geometry to one C(6); one N(2); and two equivalent H(3,5) atoms. The C(3)-C(6) bond length is 1.51 Å. The C(3)-N(2) bond length is 1.44 Å. Both C(3)-H(3,5) bond lengths are 0.97 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(11), one N(4), and one H(4) atom. The C(4)-C(11) bond length is 1.37 Å. The C(4)-N(4) bond length is 1.34 Å. The C(4)-H(4) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(3), and one O(4) atom. The C(5)-C(19) bond length is 1.48 Å. The C(5)-O(3) bond length is 1.27 Å. The C(5)-O(4) bond length is 1.29 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(26), and one C(3) atom. The C(6)-C(26) bond length is 1.39 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(13), one C(2), and one C(21) atom. The C(7)-C(13) bond length is 1.39 Å. The C(7)-C(21) bond length is 1.40 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(16) and one H(10,15) atom. The C(8)-C(16) bond length is 1.39 Å. The C(8)-H(10,15) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a 3-coordinate geometry to one C(15), one N(3), one H(20), and one H(6) atom. The C(9)-C(15) bond length is 1.51 Å. The C(9)-N(3) bond length is 1.46 Å. The C(9)-H(20) bond length is 0.97 Å. The C(9)-H(6) bond length is 0.97 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(23) and one H(18) atom. The C(10)-C(23) bond length is 1.40 Å. The C(10)-H(18) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(4) and one H(9) atom. The C(11)-H(9) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(16) and one H(10,15) atom. The C(12)-C(16) bond length is 1.43 Å. The C(12)-H(10,15) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(7) and one H(14) atom. The C(13)-H(14) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(22) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(22) bond length is 0.93 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(22), and one C(9) atom. The C(15)-C(22) bond length is 1.39 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one N(2) atom. The C(16)-N(2) bond length is 1.37 Å. In the seventeenth C site, C(17) is bonded in a single-bond geometry to one C(19) and one H(8) atom. The C(17)-C(19) bond length is 1.39 Å. The C(17)-H(8) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(21) atom. The C(18)-N(1) bond length is 1.34 Å. The C(18)-H(21) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(17), one C(25), and one C(5) atom. The C(19)-C(25) bond length is 1.41 Å. In the twentieth C site, C(21) is bonded in a distorted single-bond geometry to one C(7) and one H(11) atom. The C(21)-H(11) bond length is 0.93 Å. In the twenty-first C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(4), and one H(2) atom. The C(22)-N(4) bond length is 1.34 Å. The C(22)-H(2) bond length is 0.93 Å. In the twenty-second C site, C(23) is bonded in a distorted trigonal planar geometry to one C(10), one C(24), and one N(3) atom. The C(23)-C(24) bond length is 1.42 Å. The C(23)-N(3) bond length is 1.37 Å. In the twenty-third C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(13) atom. The C(24)-H(13) bond length is 0.93 Å. In the twenty-fourth C site, C(25) is bonded in a distorted single-bond geometry to one C(19) and one H(16) atom. The C(25)-H(16) bond length is 0.93 Å. In the twenty-fifth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(1) atom. The C(26)-N(1) bond length is 1.35 Å. The C(26)-H(1) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(18), and one C(26) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(23), one C(9), and one H(19) atom. The N(3)-H(19) bond length is 0.86 Å. In the third N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(22), and one C(4) atom. In the fourth N site, N(2) is bonded in a trigonal planar geometry to one C(16), one C(3), and one H(12) atom. The N(2)-H(12) bond length is 0.86 Å. There are nineteen inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(22) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(1) is bonded in a single-bond geometry to one C(26) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(3,5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(10,15) is bonded in a single-bond geometry to one C(8) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the thirteenth H site, H(12) is bonded in a single-bond geometry to one N(2) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(10) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one N(3) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(9) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(18) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(14) atom. In the nineteenth H site, H(17) is bonded in a single-bond geometry to one C(1) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(2) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(2) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(5) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(1) and one C(5) atom. Linkers: 8 [O]C(=O)c1ccc(NCc2cccnc2)cc1. Metal clusters: 4 O=[C]O[Cd]1O[C]O1. The MOF has largest included sphere 5.75 A, density 1.29 g/cm3, surface area 4738.89 m2/g, accessible volume 0.29 cm3/g