Zn4C45N3H24O16 is alpha Po structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight Zn4C45N3H24O16 clusters. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(2), one O(3), one O(4), and one O(6) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(2) bond length is 1.98 Å. The Zn(1)-O(3) bond length is 1.94 Å. The Zn(1)-O(4) bond length is 1.87 Å. The Zn(1)-O(6) bond length is 1.92 Å. In the second Zn site, Zn(2) is bonded to one O(6) and three equivalent O(1) atoms to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(6) bond length is 1.96 Å. All Zn(2)-O(1) bond lengths are 1.97 Å. There are fifteen inequivalent C sites. In the first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(2), and one O(3) atom. The C(3)-C(6) bond length is 1.55 Å. The C(3)-O(2) bond length is 1.23 Å. The C(3)-O(3) bond length is 1.26 Å. In the second C site, C(6) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(8) atom. The C(6)-C(7) bond length is 1.41 Å. The C(6)-C(8) bond length is 1.34 Å. In the third C site, C(7) is bonded in a single-bond geometry to one C(6) and one H(3) atom. The C(7)-H(3) bond length is 0.93 Å. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one N(1) atom. The C(8)-N(1) bond length is 1.42 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(5) atom. The C(9)-C(10) bond length is 1.33 Å. The C(9)-C(12) bond length is 1.38 Å. The C(9)-H(5) bond length is 0.93 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-C(15) bond length is 1.37 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(13), and one H(6) atom. The C(11)-C(13) bond length is 1.34 Å. The C(11)-H(6) bond length is 0.94 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(14), one C(9), and one H(7) atom. The C(12)-C(14) bond length is 1.35 Å. The C(12)-H(7) bond length is 0.93 Å. In the ninth C site, C(13) is bonded in a distorted single-bond geometry to one C(11), one C(14), and one H(8) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-H(8) bond length is 0.92 Å. In the tenth C site, C(14) is bonded in a bent 150 degrees geometry to one C(12) and one C(13) atom. In the eleventh C site, C(15) is bonded in a distorted trigonal planar geometry to one C(10), one N(1), and one O(5) atom. The C(15)-N(1) bond length is 1.35 Å. The C(15)-O(5) bond length is 1.35 Å. In the twelfth C site, C(1) is bonded in a distorted single-bond geometry to one C(4) and one H(1) atom. The C(1)-C(4) bond length is 1.47 Å. The C(1)-H(1) bond length is 0.93 Å. In the thirteenth C site, C(2) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(2)-C(4) bond length is 1.43 Å. The C(2)-H(2) bond length is 0.93 Å. In the fourteenth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(5) atom. The C(4)-C(5) bond length is 1.52 Å. In the fifteenth C site, C(5) is bonded in a 2-coordinate geometry to one C(4), one O(1), and one O(4) atom. The C(5)-O(1) bond length is 1.38 Å. The C(5)-O(4) bond length is 1.38 Å. N(1) is bonded in a distorted single-bond geometry to one C(15), one C(8), and one H(4) atom. The N(1)-H(4) bond length is 0.86 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(1) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a single-bond geometry to one C(15) atom. In the second O site, O(6) is bonded in a tetrahedral geometry to one Zn(2) and three equivalent Zn(1) atoms. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(5) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the sixth O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. Linkers: 24 [O]C(=O)c1ccc(C([O])=O)c(NC(=O)c2cc[c]cc2)c1. Metal clusters: 8 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: pcu. The MOF has largest included sphere 12.11 A, density 0.91 g/cm3, surface area 4229.87 m2/g, accessible volume 0.66 cm3/g