(Zn2C26H12O9)2(CH)2H2 crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules and four 1333-74-0 atoms inside a Zn2C26H12O9 framework. In the Zn2C26H12O9 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(2), one O(6), and one O(7) atom to form corner-sharing ZnO4 trigonal pyramids. The Zn(1)-O(1) bond length is 2.05 Å. The Zn(1)-O(2) bond length is 1.97 Å. The Zn(1)-O(6) bond length is 2.00 Å. The Zn(1)-O(7) bond length is 1.95 Å. In the second Zn site, Zn(2) is bonded to one O(1), one O(3), one O(5), and one O(8) atom to form distorted corner-sharing ZnO4 trigonal pyramids. The Zn(2)-O(1) bond length is 2.00 Å. The Zn(2)-O(3) bond length is 1.96 Å. The Zn(2)-O(5) bond length is 2.01 Å. The Zn(2)-O(8) bond length is 2.11 Å. There are twenty-six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(3) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(2) bond length is 1.25 Å. The C(1)-O(3) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.43 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(8) bond length is 1.50 Å. In the fifth C site, C(5) is bonded in a single-bond geometry to one C(4) and one H(2) atom. The C(5)-H(2) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(3) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-H(3) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one O(1) atom. The C(7)-O(1) bond length is 1.34 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(4), and one C(9) atom. The C(8)-C(13) bond length is 1.38 Å. The C(8)-C(9) bond length is 1.39 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(4) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(4) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(9) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-C(14) bond length is 1.49 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(5) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-H(5) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(21) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-C(21) bond length is 1.50 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(6) atom. The C(13)-H(6) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(10), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-C(19) bond length is 1.39 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(7) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(7) bond length is 0.93 Å. In the sixteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(8) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-H(8) bond length is 0.93 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one O(4) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-O(4) bond length is 1.37 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(20) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-C(20) bond length is 1.46 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one H(9) atom. The C(19)-H(9) bond length is 0.93 Å. In the twentieth C site, C(20) is bonded in a bent 120 degrees geometry to one C(18), one O(5), and one O(6) atom. The C(20)-O(5) bond length is 1.28 Å. The C(20)-O(6) bond length is 1.25 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(12), one C(22), and one C(26) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(26) bond length is 1.40 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(10) atom. The C(22)-C(23) bond length is 1.38 Å. The C(22)-H(10) bond length is 0.93 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(27) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-C(27) bond length is 1.49 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one O(9) atom. The C(24)-O(9) bond length is 1.39 Å. In the twenty-fifth C site, C(26) is bonded in a single-bond geometry to one C(21) and one H(12) atom. The C(26)-H(12) bond length is 0.93 Å. In the twenty-sixth C site, C(27) is bonded in a bent 120 degrees geometry to one C(23), one O(7), and one O(8) atom. The C(27)-O(7) bond length is 1.28 Å. The C(27)-O(8) bond length is 1.25 Å. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(19) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(26) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one O(9) atom. The H(14)-O(9) bond length is 0.82 Å. There are nine inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Zn(1), one Zn(2), and one C(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(17) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(20) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(20) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(27) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(27) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one C(24) and one H(14) atom. Linkers: 4 [O]C(=O)c1cc(-c2cc(-c3ccc(O)c(C([O])=O)c3)cc(-c3ccc(O)c(C([O])=O)c3)c2)ccc1[O]. Metal clusters: 8 [Zn]. The MOF has largest included sphere 9.07 A, density 0.88 g/cm3, surface area 3983.17 m2/g, accessible volume 0.69 cm3/g