AgC29N4H21(CH)3(C7H4)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, four AgC29N4H21 clusters, and four C7H4 clusters. In each AgC29N4H21 cluster, Ag(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Ag(1)-N(1) bond length is 2.45 Å. The Ag(1)-N(2) bond length is 2.33 Å. The Ag(1)-N(3) bond length is 2.37 Å. The Ag(1)-N(4) bond length is 2.22 Å. There are twenty-nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one N(1), and one H(1) atom. The C(1)-C(3) bond length is 1.40 Å. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-H(2) bond length is 0.95 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(6) atom. The C(3)-C(5) bond length is 1.38 Å. The C(3)-C(6) bond length is 1.47 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(5)-H(4) bond length is 0.95 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(8) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-C(8) bond length is 1.39 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(5,6) atom. The C(7)-H(5,6) bond length is 0.95 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(6) and one H(5,6) atom. The C(8)-H(5,6) bond length is 0.95 Å. In the eighth C site, C(19) is bonded in a distorted single-bond geometry to one C(25) and one H(11) atom. The C(19)-C(25) bond length is 1.39 Å. The C(19)-H(11) bond length is 0.95 Å. In the ninth C site, C(20) is bonded in a distorted single-bond geometry to one C(25) and one H(12) atom. The C(20)-C(25) bond length is 1.37 Å. The C(20)-H(12) bond length is 0.95 Å. In the tenth C site, C(25) is bonded in a trigonal planar geometry to one C(19), one C(20), and one C(30) atom. The C(25)-C(30) bond length is 1.49 Å. In the eleventh C site, C(26) is bonded in a distorted single-bond geometry to one C(31) and one H(17) atom. The C(26)-C(31) bond length is 1.39 Å. The C(26)-H(17) bond length is 0.95 Å. In the twelfth C site, C(27) is bonded in a distorted single-bond geometry to one C(31) and one H(18) atom. The C(27)-C(31) bond length is 1.39 Å. The C(27)-H(18) bond length is 0.95 Å. In the thirteenth C site, C(31) is bonded in a trigonal planar geometry to one C(26), one C(27), and one C(35) atom. The C(31)-C(35) bond length is 1.48 Å. In the fourteenth C site, C(35) is bonded in a trigonal planar geometry to one C(31), one C(38), and one C(39) atom. The C(35)-C(38) bond length is 1.38 Å. The C(35)-C(39) bond length is 1.39 Å. In the fifteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(32) and one H(19,20) atom. The C(28)-C(32) bond length is 1.39 Å. The C(28)-H(19,20) bond length is 0.95 Å. In the sixteenth C site, C(29) is bonded in a distorted single-bond geometry to one C(32) and one H(19,20) atom. The C(29)-C(32) bond length is 1.40 Å. The C(29)-H(19,20) bond length is 0.95 Å. In the seventeenth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(35), one N(3), and one H(24) atom. The C(38)-N(3) bond length is 1.35 Å. The C(38)-H(24) bond length is 0.95 Å. In the eighteenth C site, C(39) is bonded in a distorted single-bond geometry to one C(35) and one H(25) atom. The C(39)-H(25) bond length is 0.95 Å. In the nineteenth C site, C(30) is bonded in a trigonal planar geometry to one C(25), one C(33), and one C(34) atom. The C(30)-C(33) bond length is 1.37 Å. The C(30)-C(34) bond length is 1.38 Å. In the twentieth C site, C(32) is bonded in a trigonal planar geometry to one C(28), one C(29), and one C(36) atom. The C(32)-C(36) bond length is 1.49 Å. In the twenty-first C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(30), one N(2), and one H(21) atom. The C(33)-N(2) bond length is 1.34 Å. The C(33)-H(21) bond length is 0.95 Å. In the twenty-second C site, C(34) is bonded in a distorted single-bond geometry to one C(30) and one H(22) atom. The C(34)-H(22) bond length is 0.95 Å. In the twenty-third C site, C(36) is bonded in a trigonal planar geometry to one C(32), one C(40), and one C(41) atom. The C(36)-C(40) bond length is 1.39 Å. The C(36)-C(41) bond length is 1.39 Å. In the twenty-fourth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(31) atom. The C(45)-N(3) bond length is 1.34 Å. The C(45)-H(31) bond length is 0.95 Å. In the twenty-fifth C site, C(40) is bonded in a distorted trigonal planar geometry to one C(36), one N(4), and one H(26) atom. The C(40)-N(4) bond length is 1.35 Å. The C(40)-H(26) bond length is 0.95 Å. In the twenty-sixth C site, C(41) is bonded in a distorted single-bond geometry to one C(36) and one H(27) atom. The C(41)-H(27) bond length is 0.95 Å. In the twenty-seventh C site, C(42) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(28) atom. The C(42)-N(2) bond length is 1.34 Å. The C(42)-H(28) bond length is 0.95 Å. In the twenty-eighth C site, C(44) is bonded in a distorted single-bond geometry to one C(46) and one H(30) atom. The C(44)-C(46) bond length is 1.37 Å. The C(44)-H(30) bond length is 0.95 Å. In the twenty-ninth C site, C(46) is bonded in a distorted trigonal planar geometry to one C(44), one N(4), and one H(32) atom. The C(46)-N(4) bond length is 1.34 Å. The C(46)-H(32) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 120 degrees geometry to one Ag(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(33), and one C(42) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(38), and one C(45) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(1), one C(40), and one C(46) atom. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(25) is bonded in a single-bond geometry to one C(39) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(19,20) is bonded in a single-bond geometry to one C(28) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(33) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(34) atom. In the thirteenth H site, H(24) is bonded in a single-bond geometry to one C(38) atom. In the fourteenth H site, H(28) is bonded in a single-bond geometry to one C(42) atom. In the fifteenth H site, H(26) is bonded in a single-bond geometry to one C(40) atom. In the sixteenth H site, H(30) is bonded in a single-bond geometry to one C(44) atom. In the seventeenth H site, H(31) is bonded in a single-bond geometry to one C(45) atom. In the eighteenth H site, H(32) is bonded in a single-bond geometry to one C(46) atom. In the nineteenth H site, H(27) is bonded in a single-bond geometry to one C(41) atom. In each C7H4 cluster, there are fourteen inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(11) and one H(7,8) atom. The C(9)-C(11) bond length is 1.39 Å. The C(9)-H(7,8) bond length is 0.95 Å. In the second C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(7,8) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-H(7,8) bond length is 0.95 Å. In the third C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(9) atom. The C(11)-C(12) bond length is 1.49 Å. In the fourth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.51 Å. The C(12)-C(14) bond length is 1.35 Å. In the fifth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(15), and one C(16) atom. The C(13)-C(15) bond length is 1.38 Å. The C(13)-C(16) bond length is 1.37 Å. In the sixth C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(17), and one C(18) atom. The C(14)-C(17) bond length is 1.50 Å. The C(14)-C(18) bond length is 1.49 Å. In the seventh C site, C(15) is bonded in a distorted single-bond geometry to one C(13) and one H(9) atom. The C(15)-H(9) bond length is 0.95 Å. In the eighth C site, C(16) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(16)-H(10) bond length is 0.95 Å. In the ninth C site, C(17) is bonded in a trigonal planar geometry to one C(14), one C(21), and one C(22) atom. The C(17)-C(21) bond length is 1.39 Å. The C(17)-C(22) bond length is 1.38 Å. In the tenth C site, C(18) is bonded in a trigonal planar geometry to one C(14), one C(23), and one C(24) atom. The C(18)-C(23) bond length is 1.39 Å. The C(18)-C(24) bond length is 1.39 Å. In the eleventh C site, C(21) is bonded in a distorted single-bond geometry to one C(17) and one H(13) atom. The C(21)-H(13) bond length is 0.95 Å. In the twelfth C site, C(22) is bonded in a distorted single-bond geometry to one C(17) and one H(14) atom. The C(22)-H(14) bond length is 0.95 Å. In the thirteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(15) atom. The C(23)-H(15) bond length is 0.95 Å. In the fourteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(18) and one H(16) atom. The C(24)-H(16) bond length is 0.95 Å. There are seven inequivalent H sites. In the first H site, H(7,8) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(23) atom. Linkers: 4 c1cncc(-c2ccc([C]([C](c3ccc(-c4cccnc4)cc3)c3ccc(-c4cccnc4)cc3)c3ccc(-c4cccnc4)cc3)cc2)c1 ,2 [c]1[c]ncc(-c2ccc([C]([C](c3ccc(-c4cccnc4)cc3)c3ccc(-c4cccnc4)cc3)c3ccc(-c4cccnc4)cc3)cc2)c1 ,2 [CH]C(=[CH])c1ccc([C]([C](c2ccc(-c3cccnc3)cc2)c2ccc(-c3cccnc3)cc2)c2ccc(-c3cccnc3)cc2)cc1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 5.47 A, density 1.12 g/cm3, surface area 4952.26 m2/g, accessible volume 0.41 cm3/g