CoC9N4H9CoC12N5H11(CH)5(C6NH5)2HC2N is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of twenty 02329_fluka molecules, four dimethylamine molecules, eight C6NH5 clusters, four CoC12N5H11 clusters, and four CoC9N4H9 clusters. In each C6NH5 cluster, there are six inequivalent C sites. In the first C site, C(12) is bonded in a single-bond geometry to one C(13) and one H(14) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(14) bond length is 0.93 Å. In the second C site, C(13) is bonded in a distorted trigonal planar geometry to one C(12), one C(14), and one N(6) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-N(6) bond length is 1.38 Å. In the third C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(15) atom. The C(14)-H(15) bond length is 0.93 Å. In the fourth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(18) atom. The C(17)-C(18) bond length is 1.41 Å. The C(17)-H(18) bond length is 0.93 Å. In the fifth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one C(19), and one N(6) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-N(6) bond length is 1.39 Å. In the sixth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(19) atom. The C(19)-H(19) bond length is 0.93 Å. N(6) is bonded in a distorted trigonal planar geometry to one C(13), one C(18), and one H(2) atom. The N(6)-H(2) bond length is 0.90 Å. There are five inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one N(6) atom. In the second H site, H(14) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(15) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(18) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In each CoC12N5H11 cluster, Co(2) is bonded in a rectangular see-saw-like geometry to one N(10), one N(11), one N(2), and one N(8) atom. The Co(2)-N(10) bond length is 2.14 Å. The Co(2)-N(11) bond length is 2.14 Å. The Co(2)-N(2) bond length is 2.19 Å. The Co(2)-N(8) bond length is 2.14 Å. There are twelve inequivalent C sites. In the first C site, C(3) is bonded in a distorted single-bond geometry to one N(3) atom. The C(3)-N(3) bond length is 1.36 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(6)-N(2) bond length is 1.34 Å. The C(6)-H(9) bond length is 0.93 Å. In the third C site, C(7) is bonded in a single-bond geometry to one C(8) and one H(10) atom. The C(7)-C(8) bond length is 1.40 Å. The C(7)-H(10) bond length is 0.93 Å. In the fourth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(3) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-N(3) bond length is 1.41 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(11) atom. The C(9)-C(10) bond length is 1.37 Å. The C(9)-H(11) bond length is 0.93 Å. In the sixth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(12) atom. The C(10)-N(2) bond length is 1.35 Å. The C(10)-H(12) bond length is 0.93 Å. In the seventh C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(25) atom. The C(26)-N(8) bond length is 1.34 Å. The C(26)-H(25) bond length is 0.93 Å. In the eighth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(28) atom. The C(30)-N(8) bond length is 1.35 Å. The C(30)-H(28) bond length is 0.93 Å. In the ninth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(29) atom. The C(31)-N(10) bond length is 1.33 Å. The C(31)-H(29) bond length is 0.93 Å. In the tenth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(32) atom. The C(35)-N(10) bond length is 1.36 Å. The C(35)-H(32) bond length is 0.93 Å. In the eleventh C site, C(36) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(33) atom. The C(36)-N(11) bond length is 1.35 Å. The C(36)-H(33) bond length is 0.93 Å. In the twelfth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(36) atom. The C(40)-N(11) bond length is 1.33 Å. The C(40)-H(36) bond length is 0.93 Å. There are five inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Co(2), one C(10), and one C(6) atom. In the second N site, N(3) is bonded in a distorted trigonal planar geometry to one C(3), one C(8), and one H(1) atom. The N(3)-H(1) bond length is 0.88 Å. In the third N site, N(8) is bonded in a trigonal planar geometry to one Co(2), one C(26), and one C(30) atom. In the fourth N site, N(10) is bonded in a trigonal planar geometry to one Co(2), one C(31), and one C(35) atom. In the fifth N site, N(11) is bonded in a trigonal planar geometry to one Co(2), one C(36), and one C(40) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(25) is bonded in a single-bond geometry to one C(26) atom. In the seventh H site, H(28) is bonded in a single-bond geometry to one C(30) atom. In the eighth H site, H(29) is bonded in a single-bond geometry to one C(31) atom. In the ninth H site, H(32) is bonded in a single-bond geometry to one C(35) atom. In the tenth H site, H(33) is bonded in a single-bond geometry to one C(36) atom. In the eleventh H site, H(36) is bonded in a single-bond geometry to one C(40) atom. In each CoC9N4H9 cluster, Co(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(4), one N(5), and one N(7) atom. The Co(1)-N(1) bond length is 2.12 Å. The Co(1)-N(4) bond length is 2.14 Å. The Co(1)-N(5) bond length is 2.15 Å. The Co(1)-N(7) bond length is 2.15 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(5) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(8) bond length is 0.93 Å. In the third C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(13) atom. The C(11)-N(4) bond length is 1.34 Å. The C(11)-H(13) bond length is 0.93 Å. In the fourth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(16) atom. The C(15)-N(4) bond length is 1.34 Å. The C(15)-H(16) bond length is 0.93 Å. In the fifth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(17,20) atom. The C(16)-N(5) bond length is 1.34 Å. The C(16)-H(17,20) bond length is 0.93 Å. In the sixth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(17,20) atom. The C(20)-N(5) bond length is 1.34 Å. The C(20)-H(17,20) bond length is 0.93 Å. In the seventh C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(21) atom. The C(21)-N(7) bond length is 1.33 Å. The C(21)-H(21) bond length is 0.93 Å. In the eighth C site, C(24) is bonded in a single-bond geometry to one C(25) and one H(23) atom. The C(24)-C(25) bond length is 1.37 Å. The C(24)-H(23) bond length is 0.93 Å. In the ninth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one N(7), and one H(24) atom. The C(25)-N(7) bond length is 1.36 Å. The C(25)-H(24) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(5) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Co(1), one C(11), and one C(15) atom. In the third N site, N(5) is bonded in a trigonal planar geometry to one Co(1), one C(16), and one C(20) atom. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one Co(1), one C(21), and one C(25) atom. There are eight inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(17,20) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(21) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(23) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(24) is bonded in a single-bond geometry to one C(25) atom. Linkers: 16 c1cc(Nc2ccncc2)ccn1. Metal clusters: 8 [Co]. The MOF has largest included sphere 4.02 A, density 1.19 g/cm3, surface area 4909.69 m2/g, accessible volume 0.44 cm3/g