(ZnC13N3H10O5)2(CH2)3 crystallizes in the monoclinic C2/c space group. The structure consists of twelve 02329_fluka molecules inside a ZnC13N3H10O5 framework. In the ZnC13N3H10O5 framework, Zn(1) is bonded in a 5-coordinate geometry to one N(2), one O(1), one O(2), one O(4), and one O(5) atom. The Zn(1)-N(2) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 2.32 Å. The Zn(1)-O(2) bond length is 2.09 Å. The Zn(1)-O(4) bond length is 1.95 Å. The Zn(1)-O(5) bond length is 1.97 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(4), and one O(5) atom. The C(1)-C(4) bond length is 1.48 Å. The C(1)-O(4) bond length is 1.26 Å. The C(1)-O(5) bond length is 1.23 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(10), one C(9), and one N(3) atom. The C(2)-C(10) bond length is 1.39 Å. The C(2)-C(9) bond length is 1.38 Å. The C(2)-N(3) bond length is 1.45 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4), one C(7), and one H(1) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-C(7) bond length is 1.39 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(9) atom. The C(4)-C(9) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a 3-coordinate geometry to one N(1), one H(2), and one H(3) atom. The C(5)-N(1) bond length is 1.47 Å. The C(5)-H(2) bond length is 0.97 Å. The C(5)-H(3) bond length is 0.97 Å. In the sixth C site, C(6) is bonded in a trigonal non-coplanar geometry to one C(8) and three equivalent H(4,5,6) atoms. The C(6)-C(8) bond length is 1.49 Å. All C(6)-H(4,5,6) bond lengths are 0.96 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(3) atom. The C(7)-C(10) bond length is 1.37 Å. The C(7)-C(14) bond length is 1.51 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(6), one N(1), and one N(2) atom. The C(8)-N(1) bond length is 1.35 Å. The C(8)-N(2) bond length is 1.33 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(8) atom. The C(9)-H(8) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(2), one C(7), and one H(9) atom. The C(10)-H(9) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a 2-coordinate geometry to one C(12), one N(1), and one H(10) atom. The C(11)-C(12) bond length is 1.35 Å. The C(11)-N(1) bond length is 1.36 Å. The C(11)-H(10) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a 3-coordinate geometry to one C(11), one N(2), and one H(11) atom. The C(12)-N(2) bond length is 1.37 Å. The C(12)-H(11) bond length is 0.93 Å. In the thirteenth C site, C(14) is bonded in a bent 120 degrees geometry to one C(7), one O(1), and one O(2) atom. The C(14)-O(1) bond length is 1.19 Å. The C(14)-O(2) bond length is 1.20 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(11), one C(5), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(12), and one C(8) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(3), and one O(3) atom. The N(3)-N(3) bond length is 1.22 Å. The N(3)-O(3) bond length is 1.48 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4,5,6) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. There are five inequivalent O sites. In the first O site, O(5) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a water-like geometry to one Zn(1) and one C(14) atom. In the third O site, O(1) is bonded in an L-shaped geometry to one Zn(1) and one C(14) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one N(3) atom. In the fifth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(1) atom. Linkers: 5 [O]C(=O)c1cc(C([O])=O)cc(N([O])N([O])c2cc(C([O])=O)cc(C([O])=O)c2)c1 ,4 Cc1nccn1CCCCCn1ccnc1C. Metal clusters: 4 [C]1O[Zn]2(O1)O[C]O[Zn]1(O[C]O1)O[C]O2. The MOF has largest included sphere 4.65 A, density 1.24 g/cm3, surface area 4395.03 m2/g, accessible volume 0.38 cm3/g