Zn7GaP10H10O30F crystallizes in the tetragonal I4_1/acd space group. There are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(4), one O(7), one O(8), and one O(9) atom to form ZnO4 tetrahedra that share  a cornercorner with one P(2)HO3 tetrahedra and corners with three equivalent P(3)HO3 tetrahedra. The Zn(1)-O(4) bond length is 1.91 Å. The Zn(1)-O(7) bond length is 1.90 Å. The Zn(1)-O(8) bond length is 1.95 Å. The Zn(1)-O(9) bond length is 1.93 Å. In the second Zn site, Zn(2) is bonded to one O(11), one O(13), one O(14), and one O(6) atom to form ZnO4 tetrahedra that share  a cornercorner with one P(2)HO3 tetrahedra,  a cornercorner with one P(4)HO3 tetrahedra, and corners with two equivalent P(5)HO3 tetrahedra. The Zn(2)-O(11) bond length is 1.95 Å. The Zn(2)-O(13) bond length is 1.92 Å. The Zn(2)-O(14) bond length is 1.92 Å. The Zn(2)-O(6) bond length is 1.94 Å. In the third Zn site, Zn(3) is bonded to one O(10), one O(12), one O(15), and one O(3) atom to form ZnO4 tetrahedra that share  a cornercorner with one P(1)HO3 tetrahedra,  a cornercorner with one P(5)HO3 tetrahedra, and corners with two equivalent P(4)HO3 tetrahedra. The Zn(3)-O(10) bond length is 1.95 Å. The Zn(3)-O(12) bond length is 1.95 Å. The Zn(3)-O(15) bond length is 1.95 Å. The Zn(3)-O(3) bond length is 1.90 Å. In the fourth Zn site, Zn(4) is bonded in a linear geometry to two equivalent O(5) atoms. Both Zn(4)-O(5) bond lengths are 2.00 Å. Ga(1) is bonded to two equivalent O(1), two equivalent O(2), and two equivalent F(1) atoms to form GaO4F2 octahedra that share corners with two equivalent Ga(1)O4F2 octahedra and corners with four equivalent P(1)HO3 tetrahedra. The corner-sharing octahedral tilt angles are 47°. Both Ga(1)-O(1) bond lengths are 1.93 Å. Both Ga(1)-O(2) bond lengths are 1.97 Å. Both Ga(1)-F(1) bond lengths are 1.94 Å. There are five inequivalent P sites. In the first P site, P(1) is bonded to one H(1), one O(1), one O(2), and one O(3) atom to form distorted PHO3 tetrahedra that share corners with two equivalent Ga(1)O4F2 octahedra and  a cornercorner with one Zn(3)O4 tetrahedra. The corner-sharing octahedral tilt angles range from 49-53°. The P(1)-H(1) bond length is 1.39 Å. The P(1)-O(1) bond length is 1.53 Å. The P(1)-O(2) bond length is 1.53 Å. The P(1)-O(3) bond length is 1.48 Å. In the second P site, P(2) is bonded to one H(2), one O(4), one O(5), and one O(6) atom to form distorted PHO3 tetrahedra that share  a cornercorner with one Zn(1)O4 tetrahedra and  a cornercorner with one Zn(2)O4 tetrahedra. The P(2)-H(2) bond length is 1.14 Å. The P(2)-O(4) bond length is 1.50 Å. The P(2)-O(5) bond length is 1.47 Å. The P(2)-O(6) bond length is 1.48 Å. In the third P site, P(3) is bonded to one H(3), one O(7), one O(8), and one O(9) atom to form distorted PHO3 tetrahedra that share corners with three equivalent Zn(1)O4 tetrahedra. The P(3)-H(3) bond length is 1.39 Å. The P(3)-O(7) bond length is 1.52 Å. The P(3)-O(8) bond length is 1.52 Å. The P(3)-O(9) bond length is 1.53 Å. In the fourth P site, P(4) is bonded to one H(4), one O(10), one O(11), and one O(12) atom to form distorted PHO3 tetrahedra that share  a cornercorner with one Zn(2)O4 tetrahedra and corners with two equivalent Zn(3)O4 tetrahedra. The P(4)-H(4) bond length is 1.40 Å. The P(4)-O(10) bond length is 1.51 Å. The P(4)-O(11) bond length is 1.50 Å. The P(4)-O(12) bond length is 1.48 Å. In the fifth P site, P(5) is bonded to one H(5), one O(13), one O(14), and one O(15) atom to form distorted PHO3 tetrahedra that share  a cornercorner with one Zn(3)O4 tetrahedra and corners with two equivalent Zn(2)O4 tetrahedra. The P(5)-H(5) bond length is 1.43 Å. The P(5)-O(13) bond length is 1.55 Å. The P(5)-O(14) bond length is 1.47 Å. The P(5)-O(15) bond length is 1.49 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one P(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one P(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one P(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one P(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one P(5) atom. There are fifteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ga(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(3) and one P(1) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(2) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Zn(4) and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one P(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(3) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(3) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(4) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(2) and one P(4) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Zn(3) and one P(4) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(2) and one P(5) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one P(5) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(3) and one P(5) atom. F(1) is bonded in a bent 120 degrees geometry to two equivalent Ga(1) atoms. Linkers: 160 [O][PH]([O])=O. Metal clusters: 112 [Zn] ,16 [Ga]. The MOF has largest included sphere 11.07 A, density 1.31 g/cm3, surface area 3020.79 m2/g, accessible volume 0.46 cm3/g