CoC18N3H14O4(C3H2)2C4H3C9H6N is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 1,1'-bicyclopropyl, 1,1'-dimethyl- molecules; eight 2,3-dimethyl-1,3-butadiene molecules; eight schembl1705614 molecules; and eight CoC18N3H14O4 clusters. In each CoC18N3H14O4 cluster, Co(1) is bonded in a square pyramidal geometry to one N(1), one N(3), one O(1), one O(2), and one O(4) atom. The Co(1)-N(1) bond length is 2.08 Å. The Co(1)-N(3) bond length is 2.12 Å. The Co(1)-O(1) bond length is 2.16 Å. The Co(1)-O(2) bond length is 2.16 Å. The Co(1)-O(4) bond length is 2.04 Å. There are eighteen inequivalent C sites. In the first C site, C(35) is bonded in a distorted single-bond geometry to one C(30) and one H(25) atom. The C(35)-C(30) bond length is 1.39 Å. The C(35)-H(25) bond length is 0.93 Å. In the second C site, C(37) is bonded in a distorted single-bond geometry to one C(30) and one H(27) atom. The C(37)-C(30) bond length is 1.41 Å. The C(37)-H(27) bond length is 0.93 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.26 Å. In the fourth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(7) bond length is 1.37 Å. In the fifth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(8)-C(9) bond length is 1.49 Å. The C(8)-O(3) bond length is 1.25 Å. The C(8)-O(4) bond length is 1.27 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.37 Å. The C(9)-C(14) bond length is 1.39 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(10)-H(5) bond length is 0.93 Å. In the tenth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. In the eleventh C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(15)-N(3) bond length is 1.31 Å. The C(15)-H(9) bond length is 0.93 Å. In the twelfth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(12) atom. The C(19)-N(3) bond length is 1.31 Å. The C(19)-H(12) bond length is 0.93 Å. In the thirteenth C site, C(26) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(17) atom. The C(26)-N(1) bond length is 1.31 Å. The C(26)-N(2) bond length is 1.34 Å. The C(26)-H(17) bond length is 0.93 Å. In the fourteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(28), one N(1), and one H(18) atom. The C(27)-C(28) bond length is 1.34 Å. The C(27)-N(1) bond length is 1.37 Å. The C(27)-H(18) bond length is 0.93 Å. In the fifteenth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(27), one N(2), and one H(19) atom. The C(28)-N(2) bond length is 1.36 Å. The C(28)-H(19) bond length is 0.93 Å. In the sixteenth C site, C(29) is bonded in a 3-coordinate geometry to one C(30); one N(2); and two equivalent H(20,21) atoms. The C(29)-C(30) bond length is 1.46 Å. The C(29)-N(2) bond length is 1.44 Å. Both C(29)-H(20,21) bond lengths are 0.97 Å. In the seventeenth C site, C(30) is bonded in a distorted tetrahedral geometry to one C(29), one C(31), one C(35), and one C(37) atom. The C(30)-C(31) bond length is 1.29 Å. In the eighteenth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(22) atom. The C(31)-H(22) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(26), and one C(27) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(29) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(15), and one C(19) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(28) atom. In the tenth H site, H(20,21) is bonded in a single-bond geometry to one C(29) atom. In the eleventh H site, H(22) is bonded in a single-bond geometry to one C(31) atom. In the twelfth H site, H(25) is bonded in a single-bond geometry to one C(35) atom. In the thirteenth H site, H(27) is bonded in a single-bond geometry to one C(37) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Co(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Co(1) and one C(1) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(8) atom. Linkers: 8 [O]C(=O)c1ccc(N(c2ccc(C([O])=O)cc2)c2ccc(-c3ccncc3)cc2)cc1 ,4 C1=C[C@]2([C@]34C=C[C@@]5(Cn6ccnc6)[C@@H]6[C@H]5[C@H]3[C@@H]64)[C@@H]3[C@H]4[C@@H]([C@@H]32)[C@@]14Cn1ccnc1. Metal clusters: 8 O=[C]O[Co]1O[C]O1. The MOF has largest included sphere 4.85 A, density 1.13 g/cm3, surface area 4929.55 m2/g, accessible volume 0.38 cm3/g