ZnC24N4H17O3ZnC12H8(NO2)2(CH)6(C3NH2)2(C5NH3O)2C11NH7O is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules; four 1,2-diisopropenylhydrazine molecules; eight 1-methylethenylamine molecules; sixteen n-methylmethacrylamide molecules; eight C11NH7O clusters; eight ZnC12H8(NO2)2 clusters; and four ZnC24N4H17O3 clusters. In each C11NH7O cluster, there are eleven inequivalent C sites. In the first C site, C(48) is bonded in a distorted single-bond geometry to one N(2) atom. The C(48)-N(2) bond length is 1.39 Å. In the second C site, C(51) is bonded in a distorted trigonal planar geometry to one C(52), one C(56), and one H(33) atom. The C(51)-C(52) bond length is 1.39 Å. The C(51)-C(56) bond length is 1.39 Å. The C(51)-H(33) bond length is 0.93 Å. In the third C site, C(52) is bonded in a trigonal planar geometry to one C(51), one C(53), and one C(57) atom. The C(52)-C(53) bond length is 1.39 Å. The C(52)-C(57) bond length is 1.55 Å. In the fourth C site, C(53) is bonded in a distorted single-bond geometry to one C(52) and one H(34) atom. The C(53)-H(34) bond length is 0.93 Å. In the fifth C site, C(54) is bonded in a single-bond geometry to one C(55) and one H(35) atom. The C(54)-C(55) bond length is 1.39 Å. The C(54)-H(35) bond length is 0.93 Å. In the sixth C site, C(55) is bonded in a trigonal planar geometry to one C(54), one C(56), and one C(60) atom. The C(55)-C(56) bond length is 1.39 Å. The C(55)-C(60) bond length is 1.53 Å. In the seventh C site, C(56) is bonded in a distorted single-bond geometry to one C(51), one C(55), and one H(36) atom. The C(56)-H(36) bond length is 0.93 Å. In the eighth C site, C(57) is bonded in a 3-coordinate geometry to one C(52), one N(2), and one O(9) atom. The C(57)-N(2) bond length is 1.45 Å. The C(57)-O(9) bond length is 1.24 Å. In the ninth C site, C(59) is bonded in a single-bond geometry to one C(60) and one H(38,39) atom. The C(59)-C(60) bond length is 1.39 Å. The C(59)-H(38,39) bond length is 0.93 Å. In the tenth C site, C(60) is bonded in a trigonal planar geometry to one C(55), one C(59), and one C(61) atom. The C(60)-C(61) bond length is 1.39 Å. In the eleventh C site, C(61) is bonded in a single-bond geometry to one C(60) and one H(38,39) atom. The C(61)-H(38,39) bond length is 0.93 Å. N(2) is bonded in a distorted trigonal planar geometry to one C(48), one C(57), and one H(41) atom. The N(2)-H(41) bond length is 0.86 Å. There are six inequivalent H sites. In the first H site, H(33) is bonded in a single-bond geometry to one C(51) atom. In the second H site, H(34) is bonded in a single-bond geometry to one C(53) atom. In the third H site, H(35) is bonded in a single-bond geometry to one C(54) atom. In the fourth H site, H(36) is bonded in a single-bond geometry to one C(56) atom. In the fifth H site, H(38,39) is bonded in a single-bond geometry to one C(59) atom. In the sixth H site, H(41) is bonded in a single-bond geometry to one N(2) atom. O(9) is bonded in a single-bond geometry to one C(57) atom. In each ZnC12H8(NO2)2 cluster, Zn(2) is bonded in a tetrahedral geometry to one N(1), one N(5), one O(4), and one O(6) atom. The Zn(2)-N(1) bond length is 2.00 Å. The Zn(2)-N(5) bond length is 2.00 Å. The Zn(2)-O(4) bond length is 1.90 Å. The Zn(2)-O(6) bond length is 1.95 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(5), and one O(6) atom. The C(1)-C(2) bond length is 1.66 Å. The C(1)-O(5) bond length is 1.06 Å. The C(1)-O(6) bond length is 1.18 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.42 Å. The C(2)-C(7) bond length is 1.33 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(8) is bonded in a bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(8)-C(9) bond length is 1.50 Å. The C(8)-O(3) bond length is 1.26 Å. The C(8)-O(4) bond length is 1.35 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(14) bond length is 1.39 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(10)-H(5) bond length is 0.93 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. In the ninth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(17) atom. The C(29)-N(5) bond length is 1.38 Å. The C(29)-H(17) bond length is 0.93 Å. In the tenth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(20) atom. The C(33)-N(5) bond length is 1.40 Å. The C(33)-H(20) bond length is 0.93 Å. In the eleventh C site, C(46) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(29) atom. The C(46)-N(1) bond length is 1.41 Å. The C(46)-H(29) bond length is 0.93 Å. In the twelfth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(32) atom. The C(50)-N(1) bond length is 1.40 Å. The C(50)-H(32) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(46), and one C(50) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Zn(2), one C(29), and one C(33) atom. There are eight inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(17) is bonded in a single-bond geometry to one C(29) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one C(33) atom. In the sixth H site, H(29) is bonded in a single-bond geometry to one C(46) atom. In the seventh H site, H(32) is bonded in a single-bond geometry to one C(50) atom. In the eighth H site, H(1) is bonded in a single-bond geometry to one C(3) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(8) atom. In the second O site, O(5) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one C(8) atom. In each ZnC24N4H17O3 cluster, Zn(1) is bonded in a trigonal non-coplanar geometry to one N(11), one N(8), and one O(7) atom. The Zn(1)-N(11) bond length is 2.02 Å. The Zn(1)-N(8) bond length is 2.03 Å. The Zn(1)-O(7) bond length is 1.95 Å. There are twenty-four inequivalent C sites. In the first C site, C(17) is bonded in a single-bond geometry to one C(16) and one H(9) atom. The C(17)-C(16) bond length is 1.40 Å. The C(17)-H(9) bond length is 0.93 Å. In the second C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(10) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(10) bond length is 0.93 Å. In the third C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(15) bond length is 1.51 Å. The C(16)-C(21) bond length is 1.36 Å. In the fourth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(7), and one O(8) atom. The C(15)-O(7) bond length is 1.30 Å. The C(15)-O(8) bond length is 1.20 Å. In the fifth C site, C(22) is bonded in a 3-coordinate geometry to one C(43), one N(7), and one O(1) atom. The C(22)-C(43) bond length is 1.40 Å. The C(22)-N(7) bond length is 1.50 Å. The C(22)-O(1) bond length is 1.43 Å. In the sixth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one N(9) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-N(9) bond length is 1.47 Å. In the seventh C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one H(11) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(11) bond length is 0.93 Å. In the eighth C site, C(21) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one H(12) atom. The C(21)-H(12) bond length is 0.93 Å. In the ninth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(13) atom. The C(23)-N(8) bond length is 1.37 Å. The C(23)-H(13) bond length is 0.93 Å. In the tenth C site, C(25) is bonded in a distorted single-bond geometry to one C(24), one C(26), and one N(7) atom. The C(25)-C(24) bond length is 1.39 Å. The C(25)-C(26) bond length is 1.39 Å. The C(25)-N(7) bond length is 1.26 Å. In the eleventh C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one C(27), and one H(15) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-H(15) bond length is 0.93 Å. In the twelfth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(26), one N(8), and one H(16) atom. The C(27)-N(8) bond length is 1.41 Å. The C(27)-H(16) bond length is 0.93 Å. In the thirteenth C site, C(36) is bonded in a single-bond geometry to one C(37) and one H(22) atom. The C(36)-C(37) bond length is 1.39 Å. The C(36)-H(22) bond length is 0.93 Å. In the fourteenth C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one C(40) atom. The C(37)-C(38) bond length is 1.39 Å. The C(37)-C(40) bond length is 1.58 Å. In the fifteenth C site, C(38) is bonded in a single-bond geometry to one C(37) and one H(21,23,24) atom. The C(38)-H(21,23,24) bond length is 0.93 Å. In the sixteenth C site, C(40) is bonded in a trigonal planar geometry to one C(37), one C(41), and one C(45) atom. The C(40)-C(41) bond length is 1.39 Å. The C(40)-C(45) bond length is 1.39 Å. In the seventeenth C site, C(41) is bonded in a single-bond geometry to one C(40) and one H(25) atom. The C(41)-H(25) bond length is 0.93 Å. In the eighteenth C site, C(42) is bonded in a distorted single-bond geometry to one C(43) and one H(26) atom. The C(42)-C(43) bond length is 1.39 Å. The C(42)-H(26) bond length is 0.93 Å. In the nineteenth C site, C(43) is bonded in a trigonal planar geometry to one C(22), one C(42), and one C(44) atom. The C(43)-C(44) bond length is 1.39 Å. In the twentieth C site, C(44) is bonded in a distorted trigonal planar geometry to one C(43), one C(45), and one H(27) atom. The C(44)-C(45) bond length is 1.39 Å. The C(44)-H(27) bond length is 0.93 Å. In the twenty-first C site, C(45) is bonded in a distorted trigonal planar geometry to one C(40), one C(44), and one H(28) atom. The C(45)-H(28) bond length is 0.93 Å. In the twenty-second C site, C(65) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(45,48) atom. The C(65)-N(11) bond length is 1.39 Å. The C(65)-H(45,48) bond length is 0.93 Å. In the twenty-third C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(14) atom. The C(24)-H(14) bond length is 0.93 Å. In the twenty-fourth C site, C(69) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(45,48) atom. The C(69)-N(11) bond length is 1.39 Å. The C(69)-H(45,48) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(7) is bonded in a 3-coordinate geometry to one C(22), one C(25), and one H(43) atom. The N(7)-H(43) bond length is 0.86 Å. In the second N site, N(8) is bonded in a trigonal planar geometry to one Zn(1), one C(23), and one C(27) atom. In the third N site, N(9) is bonded in a bent 120 degrees geometry to one C(19) and one N(9) atom. The N(9)-N(9) bond length is 1.04 Å. In the fourth N site, N(11) is bonded in a trigonal planar geometry to one Zn(1), one C(65), and one C(69) atom. There are sixteen inequivalent H sites. In the first H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the second H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the ninth H site, H(21,23,24) is bonded in a single-bond geometry to one C(35) atom. The H(21,23,24)-C(35) bond length is 0.93 Å. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(36) atom. In the eleventh H site, H(25) is bonded in a single-bond geometry to one C(41) atom. In the twelfth H site, H(26) is bonded in a single-bond geometry to one C(42) atom. In the thirteenth H site, H(27) is bonded in a single-bond geometry to one C(44) atom. In the fourteenth H site, H(28) is bonded in a single-bond geometry to one C(45) atom. In the fifteenth H site, H(43) is bonded in a single-bond geometry to one N(7) atom. In the sixteenth H site, H(45,48) is bonded in a single-bond geometry to one C(65) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(22) atom. In the second O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(15) atom. In the third O site, O(8) is bonded in a single-bond geometry to one C(15) atom. Linkers: 4 [O]C(=O)c1ccc(/N=N/c2ccc(C([O])=O)cc2)cc1 ,8 O=C(Nc1ccncc1)c1ccc(-c2ccc(C(=O)Nc3ccncc3)cc2)cc1 ,8 [O]C(=O)c1ccc([N][N]c2ccc(C([O])=O)cc2)cc1 ,8 [O][C](Nc1ccncc1)c1ccc(-c2ccc(C(=O)Nc3ccncc3)cc2)cc1. Metal clusters: 8 O=[C]O[Zn] ,8 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 10.00 A, density 0.67 g/cm3, surface area 5102.03 m2/g, accessible volume 1.00 cm3/g