ZnC6H4(NO2)2(CH2)4(CH)8 is Indium-derived structured and crystallizes in the orthorhombic Pnna space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, eight isobutylene molecules, and four ZnC6H4(NO2)2 clusters. In each ZnC6H4(NO2)2 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to two equivalent N(1) and two equivalent O(2) atoms. Both Zn(1)-N(1) bond lengths are 2.06 Å. Both Zn(1)-O(2) bond lengths are 1.90 Å. There are three inequivalent C sites. In the first C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(6)-O(1) bond length is 1.25 Å. The C(6)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-H(8) bond length is 0.93 Å. In the third C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(9) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(2), and one C(5) atom. There are two inequivalent H sites. In the first H site, H(8) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(6) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. Linkers: 4 c1cc(CCc2ccncc2)ccn1 ,4 [O]C(=O)CCCCC([O])=O. Metal clusters: 4 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.92 A, density 1.21 g/cm3, surface area 5484.91 m2/g, accessible volume 0.34 cm3/g