CdC23N7H17CdH11(C7N3)2(CH)12C5NH2 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules; four n,n-dimethylprop-1-en-2-amine molecules; four CdC23N7H17 clusters; and four CdH11(C7N3)2 clusters. In each CdC23N7H17 cluster, Cd(1) is bonded in a T-shaped geometry to one N(1), one N(4), and one N(6) atom. The Cd(1)-N(1) bond length is 2.28 Å. The Cd(1)-N(4) bond length is 2.43 Å. The Cd(1)-N(6) bond length is 2.27 Å. There are twenty-three inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.28 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a 3-coordinate geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-N(1) bond length is 1.39 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a 3-coordinate geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.37 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(4) atom. The C(4)-N(4) bond length is 1.31 Å. The C(4)-H(4) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a 2-coordinate geometry to one N(5) and one H(5) atom. The C(5)-N(5) bond length is 1.36 Å. The C(5)-H(5) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(6) atom. The C(6)-N(4) bond length is 1.30 Å. The C(6)-N(5) bond length is 1.33 Å. The C(6)-H(6) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one N(6), one N(7), and one H(7) atom. The C(7)-N(6) bond length is 1.31 Å. The C(7)-N(7) bond length is 1.36 Å. The C(7)-H(7) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9), one N(6), and one H(8) atom. The C(8)-C(9) bond length is 1.37 Å. The C(8)-N(6) bond length is 1.39 Å. The C(8)-H(8) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a 3-coordinate geometry to one C(8), one N(7), and one H(9) atom. The C(9)-N(7) bond length is 1.37 Å. The C(9)-H(9) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(15), and one N(2) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-C(15) bond length is 1.41 Å. The C(10)-N(2) bond length is 1.39 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(10) atom. The C(11)-H(10) bond length is 0.93 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one N(3) atom. The C(13)-N(3) bond length is 1.42 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one H(13) atom. The C(15)-H(13) bond length is 0.93 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one C(21), and one N(3) atom. The C(16)-C(17) bond length is 1.34 Å. The C(16)-C(21) bond length is 1.34 Å. The C(16)-N(3) bond length is 1.47 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(14) atom. The C(17)-H(14) bond length is 0.93 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(15) atom. The C(18)-C(19) bond length is 1.35 Å. The C(18)-H(15) bond length is 0.93 Å. In the seventeenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one N(7) atom. The C(19)-C(20) bond length is 1.43 Å. The C(19)-N(7) bond length is 1.43 Å. In the eighteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one H(16) atom. The C(20)-C(21) bond length is 1.37 Å. The C(20)-H(16) bond length is 0.93 Å. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(16), one C(20), and one H(17) atom. The C(21)-H(17) bond length is 0.93 Å. In the twentieth C site, C(22) is bonded in a distorted single-bond geometry to one N(3) atom. The C(22)-N(3) bond length is 1.40 Å. In the twenty-first C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(19) atom. The C(24)-C(25) bond length is 1.45 Å. The C(24)-H(19) bond length is 0.93 Å. In the twenty-second C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one C(26), and one N(5) atom. The C(25)-C(26) bond length is 1.34 Å. The C(25)-N(5) bond length is 1.48 Å. In the twenty-third C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(20) atom. The C(26)-H(20) bond length is 0.93 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(3) atom. In the third N site, N(6) is bonded in a trigonal planar geometry to one Cd(1), one C(7), and one C(8) atom. In the fourth N site, N(7) is bonded in a trigonal planar geometry to one C(19), one C(7), and one C(9) atom. In the fifth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(4), and one C(6) atom. In the sixth N site, N(5) is bonded in a trigonal planar geometry to one C(25), one C(5), and one C(6) atom. In the seventh N site, N(3) is bonded in a trigonal planar geometry to one C(13), one C(16), and one C(22) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the thirteenth H site, H(19) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(26) atom. In the fifteenth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the sixteenth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the seventeenth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In each CdH11(C7N3)2 cluster, Cd(2) is bonded in a T-shaped geometry to one N(11), one N(13), and one N(8) atom. The Cd(2)-N(11) bond length is 2.33 Å. The Cd(2)-N(13) bond length is 2.25 Å. The Cd(2)-N(8) bond length is 2.33 Å. There are fourteen inequivalent C sites. In the first C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(22) atom. The C(28)-N(8) bond length is 1.27 Å. The C(28)-H(22) bond length is 0.93 Å. In the second C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(23) atom. The C(29)-N(9) bond length is 1.37 Å. The C(29)-H(23) bond length is 0.93 Å. In the third C site, C(30) is bonded in a trigonal planar geometry to one N(8), one N(9), and one H(24) atom. The C(30)-N(8) bond length is 1.27 Å. The C(30)-N(9) bond length is 1.34 Å. The C(30)-H(24) bond length is 0.93 Å. In the fourth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(32), one N(11), and one H(25) atom. The C(31)-C(32) bond length is 1.36 Å. The C(31)-N(11) bond length is 1.33 Å. The C(31)-H(25) bond length is 0.93 Å. In the fifth C site, C(32) is bonded in a 3-coordinate geometry to one C(31), one N(12), and one H(26) atom. The C(32)-N(12) bond length is 1.42 Å. The C(32)-H(26) bond length is 0.93 Å. In the sixth C site, C(33) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(27) atom. The C(33)-N(11) bond length is 1.32 Å. The C(33)-N(12) bond length is 1.35 Å. The C(33)-H(27) bond length is 0.93 Å. In the seventh C site, C(34) is bonded in a distorted trigonal planar geometry to one C(35), one N(13), and one H(28) atom. The C(34)-C(35) bond length is 1.39 Å. The C(34)-N(13) bond length is 1.35 Å. The C(34)-H(28) bond length is 0.93 Å. In the eighth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(34), one N(14), and one H(29) atom. The C(35)-N(14) bond length is 1.31 Å. The C(35)-H(29) bond length is 0.93 Å. In the ninth C site, C(36) is bonded in a trigonal planar geometry to one N(13), one N(14), and one H(30) atom. The C(36)-N(13) bond length is 1.38 Å. The C(36)-N(14) bond length is 1.31 Å. The C(36)-H(30) bond length is 0.93 Å. In the tenth C site, C(37) is bonded in a distorted trigonal planar geometry to one C(38), one C(42), and one N(9) atom. The C(37)-C(38) bond length is 1.35 Å. The C(37)-C(42) bond length is 1.42 Å. The C(37)-N(9) bond length is 1.44 Å. In the eleventh C site, C(38) is bonded in a distorted single-bond geometry to one C(37) and one H(31) atom. The C(38)-H(31) bond length is 0.93 Å. In the twelfth C site, C(42) is bonded in a distorted single-bond geometry to one C(37) and one H(34) atom. The C(42)-H(34) bond length is 0.93 Å. In the thirteenth C site, C(46) is bonded in a distorted single-bond geometry to one N(12) atom. The C(46)-N(12) bond length is 1.40 Å. In the fourteenth C site, C(52) is bonded in a distorted single-bond geometry to one N(14) atom. The C(52)-N(14) bond length is 1.42 Å. There are six inequivalent N sites. In the first N site, N(8) is bonded in a trigonal planar geometry to one Cd(2), one C(28), and one C(30) atom. In the second N site, N(9) is bonded in a trigonal planar geometry to one C(29), one C(30), and one C(37) atom. In the third N site, N(13) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(34), and one C(36) atom. In the fourth N site, N(14) is bonded in a trigonal planar geometry to one C(35), one C(36), and one C(52) atom. In the fifth N site, N(11) is bonded in a distorted trigonal planar geometry to one Cd(2), one C(31), and one C(33) atom. In the sixth N site, N(12) is bonded in a trigonal planar geometry to one C(32), one C(33), and one C(46) atom. There are eleven inequivalent H sites. In the first H site, H(22) is bonded in a single-bond geometry to one C(28) atom. In the second H site, H(23) is bonded in a single-bond geometry to one C(29) atom. In the third H site, H(24) is bonded in a single-bond geometry to one C(30) atom. In the fourth H site, H(25) is bonded in a single-bond geometry to one C(31) atom. In the fifth H site, H(26) is bonded in a single-bond geometry to one C(32) atom. In the sixth H site, H(27) is bonded in a single-bond geometry to one C(33) atom. In the seventh H site, H(28) is bonded in a single-bond geometry to one C(34) atom. In the eighth H site, H(29) is bonded in a single-bond geometry to one C(35) atom. In the ninth H site, H(30) is bonded in a single-bond geometry to one C(36) atom. In the tenth H site, H(31) is bonded in a single-bond geometry to one C(38) atom. In the eleventh H site, H(34) is bonded in a single-bond geometry to one C(42) atom. Linkers: 2 c1cn(-c2ccc(N(c3ccc(-n4ccnc4)cc3)c3ccc(-n4ccnc4)cc3)cc2)cn1. Metal clusters: 2 [Cd]. The MOF has largest included sphere 8.20 A, density 0.88 g/cm3, surface area 4682.46 m2/g, accessible volume 0.68 cm3/g