CoC3H2O5CH is Indium-derived structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules and four CoC3H2O5 clusters. In each CoC3H2O5 cluster, there are two inequivalent Co sites. In the first Co site, Co(1) is bonded to one O(1), one O(10), one O(2), one O(5), one O(6), and one O(9) atom to form corner-sharing CoO6 octahedra. The Co(1)-O(1) bond length is 2.16 Å. The Co(1)-O(10) bond length is 2.11 Å. The Co(1)-O(2) bond length is 2.11 Å. The Co(1)-O(5) bond length is 2.05 Å. The Co(1)-O(6) bond length is 2.04 Å. The Co(1)-O(9) bond length is 2.09 Å. In the second Co site, Co(2) is bonded to one O(10), one O(3), one O(4), one O(7), and one O(8) atom to form corner-sharing CoO5 square pyramids. The corner-sharing octahedral tilt angles are 71°. The Co(2)-O(10) bond length is 2.19 Å. The Co(2)-O(3) bond length is 2.13 Å. The Co(2)-O(4) bond length is 2.01 Å. The Co(2)-O(7) bond length is 2.09 Å. The Co(2)-O(8) bond length is 2.05 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one H(1) and one O(1) atom. The C(1)-H(1) bond length is 0.98 Å. The C(1)-O(1) bond length is 1.44 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(3) atom. The C(2)-O(2) bond length is 1.26 Å. The C(2)-O(3) bond length is 1.24 Å. In the third C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(4)-O(4) bond length is 1.25 Å. The C(4)-O(5) bond length is 1.25 Å. In the fourth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(6)-O(6) bond length is 1.26 Å. The C(6)-O(7) bond length is 1.24 Å. In the fifth C site, C(7) is bonded in a distorted water-like geometry to one H(4) and one O(1) atom. The C(7)-H(4) bond length is 0.98 Å. The C(7)-O(1) bond length is 1.45 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(8) and one O(9) atom. The C(8)-O(8) bond length is 1.25 Å. The C(8)-O(9) bond length is 1.26 Å. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one O(10) atom. The H(5)-O(10) bond length is 0.97 Å. In the fourth H site, H(6) is bonded in a single-bond geometry to one O(10) atom. The H(6)-O(10) bond length is 0.97 Å. There are ten inequivalent O sites. In the first O site, O(1) is bonded in a trigonal non-coplanar geometry to one Co(1), one C(1), and one C(7) atom. In the second O site, O(4) is bonded in a distorted single-bond geometry to one Co(2) and one C(4) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one Co(1) and one C(4) atom. In the fourth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(6) atom. In the fifth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(6) atom. In the sixth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(2) atom. In the seventh O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Co(1) and one C(8) atom. In the eighth O site, O(10) is bonded in a distorted water-like geometry to one Co(1), one Co(2), one H(5), and one H(6) atom. In the ninth O site, O(3) is bonded in a distorted single-bond geometry to one Co(2) and one C(2) atom. In the tenth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(8) atom. Linkers: 24 [O]C(=O)[C@@H]1[C@H](C([O])=O)[C@@H](C([O])=O)O[C@H]1C([O])=O. Metal clusters: 48 [Co]. The MOF has largest included sphere 5.57 A, density 1.75 g/cm3, surface area 2560.56 m2/g, accessible volume 0.30 cm3/g