Cd2C13N2H10S3C9H5(CH)9 crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of seventy-two 02329_fluka molecules, four C9H5 clusters, and two Cd2C13N2H10S3 clusters. In each C9H5 cluster, there are nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(12), one C(5), and one C(9) atom. The C(1)-C(12) bond length is 1.49 Å. The C(1)-C(5) bond length is 1.33 Å. The C(1)-C(9) bond length is 1.41 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(10), one C(6), and one C(8) atom. The C(2)-C(10) bond length is 1.37 Å. The C(2)-C(6) bond length is 1.40 Å. The C(2)-C(8) bond length is 1.50 Å. In the third C site, C(5) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(5)-H(3) bond length is 0.93 Å. In the fourth C site, C(6) is bonded in a single-bond geometry to one C(2) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(5) atom. The C(7)-C(12) bond length is 1.45 Å. The C(7)-C(8) bond length is 1.41 Å. The C(7)-H(5) bond length is 0.93 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(2), and one C(7) atom. The C(8)-C(12) bond length is 1.35 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(1) and one H(6) atom. The C(9)-H(6) bond length is 0.93 Å. In the eighth C site, C(10) is bonded in a distorted single-bond geometry to one C(2) and one H(7) atom. The C(10)-H(7) bond length is 0.93 Å. In the ninth C site, C(12) is bonded in a trigonal planar geometry to one C(1), one C(7), and one C(8) atom. There are five inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In each Cd2C13N2H10S3 cluster, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one N(1), one S(1), one S(2), and one S(4) atom to form corner-sharing CdS3N trigonal pyramids. The Cd(1)-N(1) bond length is 2.35 Å. The Cd(1)-S(1) bond length is 2.51 Å. The Cd(1)-S(2) bond length is 2.55 Å. The Cd(1)-S(4) bond length is 2.52 Å. In the second Cd site, Cd(2) is bonded to one N(2), one S(1), one S(2), and one S(3) atom to form corner-sharing CdS3N trigonal pyramids. The Cd(2)-N(2) bond length is 2.37 Å. The Cd(2)-S(1) bond length is 2.55 Å. The Cd(2)-S(2) bond length is 2.49 Å. The Cd(2)-S(3) bond length is 2.52 Å. There are sixteen inequivalent C sites. In the first C site, C(26) is bonded in a trigonal planar geometry to one C(27), one C(29), and one S(3) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-C(29) bond length is 1.39 Å. The C(26)-S(3) bond length is 1.73 Å. In the second C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(20) atom. The C(27)-H(20) bond length is 0.93 Å. In the third C site, C(29) is bonded in a distorted single-bond geometry to one C(26) and one H(22) atom. The C(29)-H(22) bond length is 0.93 Å. In the fourth C site, C(32) is bonded in a trigonal planar geometry to one C(33), one C(37), and one S(4) atom. The C(32)-C(33) bond length is 1.34 Å. The C(32)-C(37) bond length is 1.34 Å. The C(32)-S(4) bond length is 1.80 Å. In the fifth C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(25) atom. The C(33)-H(25) bond length is 0.93 Å. In the sixth C site, C(37) is bonded in a distorted single-bond geometry to one C(32) and one H(29) atom. The C(37)-H(29) bond length is 0.93 Å. In the seventh C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1) atom. The C(3)-N(2) bond length is 1.32 Å. The C(3)-H(1) bond length is 0.93 Å. In the eighth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(4)-N(1) bond length is 1.32 Å. The C(4)-H(2) bond length is 0.93 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(8) bond length is 0.93 Å. In the tenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9) atom. The C(13)-N(1) bond length is 1.32 Å. The C(13)-H(9) bond length is 0.93 Å. In the eleventh C site, C(14) is bonded in a trigonal planar geometry to one C(15), one C(19), and one S(1) atom. The C(14)-C(15) bond length is 1.40 Å. The C(14)-C(19) bond length is 1.37 Å. The C(14)-S(1) bond length is 1.78 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(10) atom. The C(15)-H(10) bond length is 0.93 Å. In the thirteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(14) atom. The C(19)-H(14) bond length is 0.93 Å. In the fourteenth C site, C(20) is bonded in a trigonal planar geometry to one C(21), one C(25), and one S(2) atom. The C(20)-C(21) bond length is 1.36 Å. The C(20)-C(25) bond length is 1.37 Å. The C(20)-S(2) bond length is 1.78 Å. In the fifteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(15) atom. The C(21)-H(15) bond length is 0.93 Å. In the sixteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(20) and one H(19) atom. The C(25)-H(19) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(2), one C(11), and one C(3) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(22) is bonded in a single-bond geometry to one C(29) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(27) atom. In the eleventh H site, H(25) is bonded in a single-bond geometry to one C(33) atom. In the twelfth H site, H(29) is bonded in a single-bond geometry to one C(37) atom. There are four inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Cd(1), one Cd(2), and one C(14) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Cd(1), one Cd(2), and one C(20) atom. In the third S site, S(3) is bonded in a trigonal non-coplanar geometry to two equivalent Cd(2) and one C(26) atom. In the fourth S site, S(4) is bonded in a trigonal non-coplanar geometry to two equivalent Cd(1) and one C(32) atom. Linkers: 4 c1cc(-c2cc(-c3ccncc3)c(-c3ccncc3)cc2-c2ccncc2)ccn1. Metal clusters: 16 [Cd]. The MOF has largest included sphere 9.75 A, density 1.05 g/cm3, surface area 4245.57 m2/g, accessible volume 0.55 cm3/g