La3C27P3H29(NO7)3(CH2)6(CH)3CHO2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, twelve 02329_fluka molecules, two formic acid molecules, and one La3C27P3H29(NO7)3 cluster. In the La3C27P3H29(NO7)3 cluster, there are three inequivalent La sites. In the first La site, La(1) is bonded in a 9-coordinate geometry to one O(1), one O(10), one O(11), one O(18), one O(19), one O(2), one O(22), one O(23), and one O(7) atom. The La(1)-O(1) bond length is 2.59 Å. The La(1)-O(10) bond length is 2.50 Å. The La(1)-O(11) bond length is 2.50 Å. The La(1)-O(18) bond length is 2.66 Å. The La(1)-O(19) bond length is 2.63 Å. The La(1)-O(2) bond length is 2.63 Å. The La(1)-O(22) bond length is 2.62 Å. The La(1)-O(23) bond length is 2.55 Å. The La(1)-O(7) bond length is 2.44 Å. In the second La site, La(2) is bonded in a 9-coordinate geometry to one O(13), one O(16), one O(17), one O(2), one O(20), one O(21), one O(5), one O(6), and one O(7) atom. The La(2)-O(13) bond length is 2.50 Å. The La(2)-O(16) bond length is 2.67 Å. The La(2)-O(17) bond length is 2.58 Å. The La(2)-O(2) bond length is 2.43 Å. The La(2)-O(20) bond length is 2.57 Å. The La(2)-O(21) bond length is 2.58 Å. The La(2)-O(5) bond length is 2.51 Å. The La(2)-O(6) bond length is 2.57 Å. The La(2)-O(7) bond length is 2.62 Å. In the third La site, La(3) is bonded in a 7-coordinate geometry to one O(11), one O(12), one O(13), one O(3), one O(4), one O(8), and one O(9) atom. The La(3)-O(11) bond length is 2.64 Å. The La(3)-O(12) bond length is 2.40 Å. The La(3)-O(13) bond length is 2.64 Å. The La(3)-O(3) bond length is 2.52 Å. The La(3)-O(4) bond length is 2.54 Å. The La(3)-O(8) bond length is 2.50 Å. The La(3)-O(9) bond length is 2.55 Å. There are twenty-seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted tetrahedral geometry to one P(1); one N(1); and two equivalent H(5,6) atoms. The C(1)-P(1) bond length is 1.82 Å. The C(1)-N(1) bond length is 1.51 Å. Both C(1)-H(5,6) bond lengths are 0.97 Å. In the second C site, C(2) is bonded in a 3-coordinate geometry to one N(1) and two equivalent H(7,8,15) atoms. The C(2)-N(1) bond length is 1.47 Å. Both C(2)-H(7,8,15) bond lengths are 0.97 Å. In the third C site, C(6) is bonded in a 3-coordinate geometry to one N(1); one H(14); and one H(7,8,15) atom. The C(6)-N(1) bond length is 1.49 Å. The C(6)-H(14) bond length is 0.97 Å. The C(6)-H(7,8,15) bond length is 0.97 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(7)-O(4) bond length is 1.25 Å. The C(7)-O(5) bond length is 1.26 Å. In the fifth C site, C(8) is bonded in a distorted tetrahedral geometry to one P(2); one N(2); and two equivalent H(16,17) atoms. The C(8)-P(2) bond length is 1.83 Å. The C(8)-N(2) bond length is 1.50 Å. Both C(8)-H(16,17) bond lengths are 0.97 Å. In the sixth C site, C(9) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(18,19,26) atoms. The C(9)-N(2) bond length is 1.51 Å. Both C(9)-H(18,19,26) bond lengths are 0.97 Å. In the seventh C site, C(13) is bonded in a 3-coordinate geometry to one N(2); one H(18,19,26); and one H(25) atom. The C(13)-N(2) bond length is 1.48 Å. The C(13)-H(18,19,26) bond length is 0.97 Å. The C(13)-H(25) bond length is 0.97 Å. In the eighth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(14)-O(10) bond length is 1.28 Å. The C(14)-O(9) bond length is 1.24 Å. In the ninth C site, C(15) is bonded in a distorted tetrahedral geometry to one P(3), one N(3), one H(27), and one H(28) atom. The C(15)-P(3) bond length is 1.85 Å. The C(15)-N(3) bond length is 1.48 Å. The C(15)-H(27) bond length is 0.97 Å. The C(15)-H(28) bond length is 0.97 Å. In the tenth C site, C(16) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(29,30) atoms. The C(16)-N(3) bond length is 1.50 Å. Both C(16)-H(29,30) bond lengths are 0.97 Å. In the eleventh C site, C(20) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(36,37) atoms. The C(20)-N(3) bond length is 1.48 Å. Both C(20)-H(36,37) bond lengths are 0.97 Å. In the twelfth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(16), and one O(17) atom. The C(22)-C(23) bond length is 1.49 Å. The C(22)-O(16) bond length is 1.25 Å. The C(22)-O(17) bond length is 1.24 Å. In the thirteenth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(28) atom. The C(23)-C(24) bond length is 1.37 Å. The C(23)-C(28) bond length is 1.39 Å. In the fourteenth C site, C(24) is bonded in a distorted single-bond geometry to one C(23) and one H(38) atom. The C(24)-H(38) bond length is 0.93 Å. In the fifteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(26) and one H(39) atom. The C(25)-C(26) bond length is 1.37 Å. The C(25)-H(39) bond length is 0.93 Å. In the sixteenth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(29) atom. The C(26)-C(27) bond length is 1.38 Å. The C(26)-C(29) bond length is 1.52 Å. In the seventeenth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(40) atom. The C(27)-H(40) bond length is 0.93 Å. In the eighteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(23) and one H(41) atom. The C(28)-H(41) bond length is 0.93 Å. In the nineteenth C site, C(29) is bonded in a bent 120 degrees geometry to one C(26), one O(18), and one O(19) atom. The C(29)-O(18) bond length is 1.23 Å. The C(29)-O(19) bond length is 1.26 Å. In the twentieth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(20), and one O(21) atom. The C(30)-C(31) bond length is 1.48 Å. The C(30)-O(20) bond length is 1.27 Å. The C(30)-O(21) bond length is 1.23 Å. In the twenty-first C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(36) atom. The C(31)-C(32) bond length is 1.42 Å. The C(31)-C(36) bond length is 1.39 Å. In the twenty-second C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(42) atom. The C(32)-H(42) bond length is 0.93 Å. In the twenty-third C site, C(33) is bonded in a distorted single-bond geometry to one C(34) and one H(43) atom. The C(33)-C(34) bond length is 1.37 Å. The C(33)-H(43) bond length is 0.93 Å. In the twenty-fourth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(37) atom. The C(34)-C(35) bond length is 1.41 Å. The C(34)-C(37) bond length is 1.47 Å. In the twenty-fifth C site, C(35) is bonded in a distorted single-bond geometry to one C(34) and one H(44) atom. The C(35)-H(44) bond length is 0.93 Å. In the twenty-sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(31) and one H(45) atom. The C(36)-H(45) bond length is 0.93 Å. In the twenty-seventh C site, C(37) is bonded in a bent 120 degrees geometry to one C(34), one O(22), and one O(23) atom. The C(37)-O(22) bond length is 1.27 Å. The C(37)-O(23) bond length is 1.25 Å. There are three inequivalent P sites. In the first P site, P(1) is bonded to one C(1), one O(1), one O(2), and one O(3) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one N(1)HC3 tetrahedra. The P(1)-O(1) bond length is 1.53 Å. The P(1)-O(2) bond length is 1.54 Å. The P(1)-O(3) bond length is 1.51 Å. In the second P site, P(2) is bonded to one C(8), one O(6), one O(7), and one O(8) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one N(2)HC3 tetrahedra. The P(2)-O(6) bond length is 1.53 Å. The P(2)-O(7) bond length is 1.53 Å. The P(2)-O(8) bond length is 1.50 Å. In the third P site, P(3) is bonded to one C(15), one O(11), one O(12), and one O(13) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one N(3)HC3 tetrahedra. The P(3)-O(11) bond length is 1.54 Å. The P(3)-O(12) bond length is 1.50 Å. The P(3)-O(13) bond length is 1.53 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded to one C(1), one C(2), one C(6), and one H(2) atom to form distorted NHC3 tetrahedra that share  a cornercorner with one P(1)CO3 tetrahedra. The N(1)-H(2) bond length is 0.90 Å. In the second N site, N(2) is bonded to one C(13), one C(8), one C(9), and one H(3) atom to form distorted NHC3 tetrahedra that share  a cornercorner with one P(2)CO3 tetrahedra. The N(2)-H(3) bond length is 0.90 Å. In the third N site, N(3) is bonded to one C(15), one C(16), one C(20), and one H(4) atom to form distorted NHC3 tetrahedra that share  a cornercorner with one P(3)CO3 tetrahedra. The N(3)-H(4) bond length is 0.90 Å. There are twenty-one inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(1) atom. In the fifth H site, H(7,8,15) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(16,17) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(18,19,26) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(25) is bonded in a single-bond geometry to one C(13) atom. In the tenth H site, H(27) is bonded in a single-bond geometry to one C(15) atom. In the eleventh H site, H(28) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(29,30) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(36,37) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(38) is bonded in a single-bond geometry to one C(24) atom. In the fifteenth H site, H(39) is bonded in a single-bond geometry to one C(25) atom. In the sixteenth H site, H(40) is bonded in a single-bond geometry to one C(27) atom. In the seventeenth H site, H(41) is bonded in a single-bond geometry to one C(28) atom. In the eighteenth H site, H(42) is bonded in a single-bond geometry to one C(32) atom. In the nineteenth H site, H(43) is bonded in a single-bond geometry to one C(33) atom. In the twentieth H site, H(44) is bonded in a single-bond geometry to one C(35) atom. In the twenty-first H site, H(45) is bonded in a single-bond geometry to one C(36) atom. There are twenty-one inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one La(1) and one P(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one La(1), one La(2), and one P(1) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one La(3) and one P(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one La(3) and one C(7) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one La(2) and one C(7) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one La(2) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one La(1), one La(2), and one P(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one La(3) and one P(2) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one La(3) and one C(14) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one La(1) and one C(14) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one La(1), one La(3), and one P(3) atom. In the twelfth O site, O(12) is bonded in a distorted linear geometry to one La(3) and one P(3) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one La(2), one La(3), and one P(3) atom. In the fourteenth O site, O(16) is bonded in a distorted single-bond geometry to one La(2) and one C(22) atom. In the fifteenth O site, O(17) is bonded in a distorted single-bond geometry to one La(2) and one C(22) atom. In the sixteenth O site, O(18) is bonded in a distorted single-bond geometry to one La(1) and one C(29) atom. In the seventeenth O site, O(19) is bonded in a distorted single-bond geometry to one La(1) and one C(29) atom. In the eighteenth O site, O(20) is bonded in a distorted single-bond geometry to one La(2) and one C(30) atom. In the nineteenth O site, O(21) is bonded in a distorted single-bond geometry to one La(2) and one C(30) atom. In the twentieth O site, O(22) is bonded in a distorted single-bond geometry to one La(1) and one C(37) atom. In the twenty-first O site, O(23) is bonded in a distorted single-bond geometry to one La(1) and one C(37) atom. Linkers: 4 [O]C(=O)C1CC[NH](CC1)CP(=O)([O])[O] ,4 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 6 [La]. The MOF has largest included sphere 5.32 A, density 1.68 g/cm3, surface area 3321.23 m2/g, accessible volume 0.25 cm3/g