ZnC13N3H9O5CH3(CH2)2 crystallizes in the monoclinic C2/c space group. The structure consists of sixteen 02329_fluka molecules and eight 02329_fluka molecules inside a ZnC13N3H9O5 framework. In the ZnC13N3H9O5 framework, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.06 Å. The Zn(1)-O(3) bond length is 2.06 Å. The Zn(1)-O(4) bond length is 2.07 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(4) bond length is 1.52 Å. The C(1)-C(6) bond length is 1.39 Å. In the second C site, C(2) is bonded in a single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(5), and one C(7) atom. The C(3)-C(5) bond length is 1.51 Å. The C(3)-C(7) bond length is 1.40 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(2), and one O(3) atom. The C(4)-O(2) bond length is 1.24 Å. The C(4)-O(3) bond length is 1.25 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(4) atom. The C(5)-O(1) bond length is 1.25 Å. The C(5)-O(4) bond length is 1.25 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(9), and one H(2) atom. The C(6)-C(9) bond length is 1.40 Å. The C(6)-H(2) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(3), one C(9), and one H(3) atom. The C(7)-C(9) bond length is 1.40 Å. The C(7)-H(3) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(12), one N(1), and one N(2) atom. The C(8)-C(12) bond length is 1.50 Å. The C(8)-N(1) bond length is 1.32 Å. The C(8)-N(2) bond length is 1.34 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one N(3) atom. The C(9)-N(3) bond length is 1.42 Å. In the tenth C site, C(10) is bonded in a 3-coordinate geometry to one N(2), one H(4), and one H(5) atom. The C(10)-N(2) bond length is 1.47 Å. The C(10)-H(4) bond length is 0.97 Å. The C(10)-H(5) bond length is 0.97 Å. In the eleventh C site, C(11) is bonded in a distorted trigonal planar geometry to one C(13), one N(1), and one H(6) atom. The C(11)-C(13) bond length is 1.35 Å. The C(11)-N(1) bond length is 1.38 Å. The C(11)-H(6) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a water-like geometry to one C(8) and two equivalent H(7,8) atoms. Both C(12)-H(7,8) bond lengths are 0.97 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(2), and one H(9) atom. The C(13)-N(2) bond length is 1.38 Å. The C(13)-H(9) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(11), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(8) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(9), one N(3), and one O(5) atom. The N(3)-N(3) bond length is 1.22 Å. The N(3)-O(5) bond length is 1.32 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the seventh H site, H(7,8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(4) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(4) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(5) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one N(3) atom. Linkers: 6 [O]C(=O)c1cc(C([O])=O)cc(N([O])N([O])c2cc(C([O])=O)cc(C([O])=O)c2)c1 ,4 CCc1nccn1CCCCCCn1ccnc1CC. Metal clusters: 4 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: lvt. The MOF has largest included sphere 5.00 A, density 1.38 g/cm3, surface area 4578.43 m2/g, accessible volume 0.28 cm3/g