AgH4(C3N2)2(CH)4 is Indium-derived structured and crystallizes in the cubic P4_132 space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules and twelve AgH4(C3N2)2 clusters. In each AgH4(C3N2)2 cluster, Ag(1) is bonded in a bent 150 degrees geometry to two equivalent N(1) atoms. Both Ag(1)-N(1) bond lengths are 2.16 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.30 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(3) atom. The C(3)-N(2) bond length is 1.35 Å. The C(3)-H(3) bond length is 0.93 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one N(2) atom. The C(4)-N(2) bond length is 1.42 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.35 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(3), one C(4), and one N(1) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. Linkers: 8 c1cnn(-c2cc(-n3cccn3)cc(-n3cccn3)c2)c1. Metal clusters: 12 [Ag]. The MOF has largest included sphere 4.40 A, density 1.52 g/cm3, surface area 3936.08 m2/g, accessible volume 0.28 cm3/g