Zn3C21N2H13O13(CH)3CH2C2OC4H2O is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules, two 02329_fluka molecules, two dimethyl ether molecules, two furan molecules, and two Zn3C21N2H13O13 clusters. In each Zn3C21N2H13O13 cluster, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(12), one O(14), one O(4), one O(7), and one O(9) atom to form ZnO6 octahedra that share  a cornercorner with one Zn(3)NO4 square pyramid and  a cornercorner with one Zn(2)NO3 tetrahedra. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(12) bond length is 2.02 Å. The Zn(1)-O(14) bond length is 2.09 Å. The Zn(1)-O(4) bond length is 2.42 Å. The Zn(1)-O(7) bond length is 2.05 Å. The Zn(1)-O(9) bond length is 2.21 Å. In the second Zn site, Zn(2) is bonded to one N(2), one O(15), one O(4), and one O(6) atom to form distorted corner-sharing ZnNO3 tetrahedra. The corner-sharing octahedral tilt angles are 82°. The Zn(2)-N(2) bond length is 2.00 Å. The Zn(2)-O(15) bond length is 1.92 Å. The Zn(2)-O(4) bond length is 1.98 Å. The Zn(2)-O(6) bond length is 2.00 Å. In the third Zn site, Zn(3) is bonded to one N(1), one O(10), one O(11), one O(2), and one O(9) atom to form distorted corner-sharing ZnNO4 square pyramids. The corner-sharing octahedral tilt angles are 72°. The Zn(3)-N(1) bond length is 2.03 Å. The Zn(3)-O(10) bond length is 2.15 Å. The Zn(3)-O(11) bond length is 2.02 Å. The Zn(3)-O(2) bond length is 2.01 Å. The Zn(3)-O(9) bond length is 2.25 Å. There are twenty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.24 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(5) atom. The C(6)-O(4) bond length is 1.29 Å. The C(6)-O(5) bond length is 1.23 Å. In the third C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(6), and one O(7) atom. The C(7)-C(8) bond length is 1.48 Å. The C(7)-O(6) bond length is 1.26 Å. The C(7)-O(7) bond length is 1.26 Å. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one O(8) atom. The C(8)-C(9) bond length is 1.35 Å. The C(8)-O(8) bond length is 1.38 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(3) atom. The C(9)-H(3) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one O(8) atom. The C(11)-O(8) bond length is 1.38 Å. In the seventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(9) atom. The C(12)-O(10) bond length is 1.25 Å. The C(12)-O(9) bond length is 1.26 Å. In the eighth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(12) atom. The C(13)-O(11) bond length is 1.27 Å. The C(13)-O(12) bond length is 1.26 Å. In the ninth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one O(14) and one O(15) atom. The C(18)-O(14) bond length is 1.24 Å. The C(18)-O(15) bond length is 1.28 Å. In the tenth C site, C(19) is bonded in a 3-coordinate geometry to one C(20), one N(1), and one H(7) atom. The C(19)-C(20) bond length is 1.37 Å. The C(19)-N(1) bond length is 1.36 Å. The C(19)-H(7) bond length is 0.93 Å. In the eleventh C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(8) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(8) bond length is 0.93 Å. In the twelfth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(23), and one C(24) atom. The C(21)-C(23) bond length is 1.38 Å. The C(21)-C(24) bond length is 1.50 Å. In the thirteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(23), one N(1), and one H(9) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-N(1) bond length is 1.35 Å. The C(22)-H(9) bond length is 0.93 Å. In the fourteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(21), one C(22), and one H(10) atom. The C(23)-H(10) bond length is 0.93 Å. In the fifteenth C site, C(24) is bonded in a water-like geometry to one C(21) and two equivalent H(11,12) atoms. Both C(24)-H(11,12) bond lengths are 0.97 Å. In the sixteenth C site, C(26) is bonded in a water-like geometry to one C(27) and two equivalent H(15,16) atoms. The C(26)-C(27) bond length is 1.50 Å. Both C(26)-H(15,16) bond lengths are 0.97 Å. In the seventeenth C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(29) atom. The C(27)-C(28) bond length is 1.34 Å. The C(27)-C(29) bond length is 1.38 Å. In the eighteenth C site, C(28) is bonded in a distorted trigonal planar geometry to one C(27), one C(31), and one H(17) atom. The C(28)-C(31) bond length is 1.38 Å. The C(28)-H(17) bond length is 0.93 Å. In the nineteenth C site, C(29) is bonded in a single-bond geometry to one C(27), one C(30), and one H(18) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-H(18) bond length is 0.93 Å. In the twentieth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one N(2), and one H(19) atom. The C(30)-N(2) bond length is 1.32 Å. The C(30)-H(19) bond length is 0.93 Å. In the twenty-first C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(28), one N(2), and one H(20) atom. The C(31)-N(2) bond length is 1.34 Å. The C(31)-H(20) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(3), one C(19), and one C(22) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(30), and one C(31) atom. There are eleven inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(19) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(20) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(22) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(11,12) is bonded in a single-bond geometry to one C(24) atom. In the seventh H site, H(15,16) is bonded in a single-bond geometry to one C(26) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(28) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(29) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(30) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(31) atom. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(1) atom. In the third O site, O(4) is bonded in a 3-coordinate geometry to one Zn(1), one Zn(2), and one C(6) atom. In the fourth O site, O(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(7) atom. In the sixth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(7) atom. In the seventh O site, O(8) is bonded in a water-like geometry to one C(11) and one C(8) atom. In the eighth O site, O(9) is bonded in a 3-coordinate geometry to one Zn(1), one Zn(3), and one C(12) atom. In the ninth O site, O(10) is bonded in an L-shaped geometry to one Zn(3) and one C(12) atom. In the tenth O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(13) atom. In the eleventh O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(13) atom. In the twelfth O site, O(14) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(18) atom. In the thirteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(18) atom. Linkers: 6 [O]C(=O)c1ccc(C([O])=O)o1 ,2 c1cc(CCCc2ccncc2)ccn1. Metal clusters: 2 O=[C]O[Zn]1O[C]O[Zn]23(O[C]O[Zn](O[C]O2)O[C]O3)O[C]O1. RCSR code: hcb. The MOF has largest included sphere 5.52 A, density 1.35 g/cm3, surface area 3856.59 m2/g, accessible volume 0.35 cm3/g