CoC12H8(NO2)2(C3H2)3(CH)2C2NH2C4H2O is Indium-derived structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules; twenty-four 2,3-dimethyl-1,3-butadiene molecules; sixteen 2-methoxypropene molecules; sixteen n-methyl methanimine molecules; and sixteen CoC12H8(NO2)2 clusters. In each CoC12H8(NO2)2 cluster, Co(1) is bonded in a distorted pentagonal pyramidal geometry to one N(1), one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Co(1)-N(1) bond length is 2.14 Å. The Co(1)-N(3) bond length is 2.16 Å. The Co(1)-O(1) bond length is 2.00 Å. The Co(1)-O(2) bond length is 2.34 Å. The Co(1)-O(3) bond length is 2.07 Å. The Co(1)-O(4) bond length is 2.18 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.31 Å. The C(5)-H(4) bond length is 0.93 Å. In the third C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(9) atom. The C(11)-N(3) bond length is 1.33 Å. The C(11)-H(9) bond length is 0.93 Å. In the fourth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(12) atom. The C(15)-N(3) bond length is 1.30 Å. The C(15)-H(12) bond length is 0.93 Å. In the fifth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(1), and one O(2) atom. The C(16)-C(27) bond length is 1.47 Å. The C(16)-O(1) bond length is 1.30 Å. The C(16)-O(2) bond length is 1.23 Å. In the sixth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(3), and one O(4) atom. The C(17)-C(21) bond length is 1.45 Å. The C(17)-O(3) bond length is 1.24 Å. The C(17)-O(4) bond length is 1.35 Å. In the seventh C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(14) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(14) bond length is 0.93 Å. In the eighth C site, C(21) is bonded in a trigonal planar geometry to one C(17), one C(20), and one C(22) atom. The C(21)-C(22) bond length is 1.39 Å. In the ninth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(15) atom. The C(22)-H(15) bond length is 0.93 Å. In the tenth C site, C(26) is bonded in a distorted single-bond geometry to one C(27) and one H(18) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-H(18) bond length is 0.93 Å. In the eleventh C site, C(27) is bonded in a trigonal planar geometry to one C(16), one C(26), and one C(28) atom. The C(27)-C(28) bond length is 1.39 Å. In the twelfth C site, C(28) is bonded in a distorted single-bond geometry to one C(27) and one H(19) atom. The C(28)-H(19) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(5) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(11), and one C(15) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the seventh H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the eighth H site, H(19) is bonded in a single-bond geometry to one C(28) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Co(1) and one C(16) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Co(1) and one C(16) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Co(1) and one C(17) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one Co(1) and one C(17) atom. Linkers: 8 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,4 c1cc(-c2ccncc2)ccn1. Metal clusters: 8 [Co]. The MOF has largest included sphere 7.03 A, density 1.11 g/cm3, surface area 5056.88 m2/g, accessible volume 0.41 cm3/g