Zn2(COO)3C5H4(CH)6(C4H3)2C17H17O3 is Indium-derived structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of ninety-six 02329_fluka molecules, thirty-two isobutylene molecules, sixteen isoprene molecules, sixteen C17H17O3 clusters, and sixteen Zn2(COO)3 clusters. In each C17H17O3 cluster, there are seventeen inequivalent C sites. In the first C site, C(6) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(4) bond length is 0.93 Å. In the second C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one O(3) atom. The C(7)-C(8) bond length is 1.34 Å. The C(7)-O(3) bond length is 1.38 Å. In the third C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(8)-H(5) bond length is 0.93 Å. In the fourth C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one H(7), one H(8), and one O(3) atom. The C(10)-C(11) bond length is 1.50 Å. The C(10)-H(7) bond length is 0.97 Å. The C(10)-H(8) bond length is 0.97 Å. The C(10)-O(3) bond length is 1.42 Å. In the fifth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(16) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(16) bond length is 1.39 Å. In the sixth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(18) atom. The C(12)-C(13) bond length is 1.37 Å. The C(12)-C(18) bond length is 1.54 Å. In the seventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(20) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-C(20) bond length is 1.50 Å. In the eighth C site, C(16) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(17) atom. The C(16)-C(15) bond length is 1.41 Å. The C(16)-C(17) bond length is 1.50 Å. In the ninth C site, C(17) is bonded in a trigonal non-coplanar geometry to one C(16), one H(10), one H(11), and one H(9) atom. The C(17)-H(10) bond length is 0.96 Å. The C(17)-H(11) bond length is 0.96 Å. The C(17)-H(9) bond length is 0.96 Å. In the tenth C site, C(18) is bonded in a trigonal non-coplanar geometry to one C(12); one H(12); and two equivalent H(13,14) atoms. The C(18)-H(12) bond length is 0.96 Å. Both C(18)-H(13,14) bond lengths are 0.96 Å. In the eleventh C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.42 Å. The C(14)-C(19) bond length is 1.56 Å. In the twelfth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(29) atom. The C(15)-C(29) bond length is 1.48 Å. In the thirteenth C site, C(19) is bonded in a trigonal non-coplanar geometry to one C(14), one H(15), one H(16), and one H(17) atom. The C(19)-H(15) bond length is 0.96 Å. The C(19)-H(16) bond length is 0.96 Å. The C(19)-H(17) bond length is 0.96 Å. In the fourteenth C site, C(20) is bonded in a distorted trigonal non-coplanar geometry to one C(13), one H(18), one H(19), and one O(5) atom. The C(20)-H(18) bond length is 0.97 Å. The C(20)-H(19) bond length is 0.97 Å. The C(20)-O(5) bond length is 1.47 Å. In the fifteenth C site, C(21) is bonded in a distorted single-bond geometry to one O(5) atom. The C(21)-O(5) bond length is 1.38 Å. In the sixteenth C site, C(29) is bonded in a distorted trigonal non-coplanar geometry to one C(15), one H(26), one H(27), and one O(4) atom. The C(29)-H(26) bond length is 0.97 Å. The C(29)-H(27) bond length is 0.97 Å. The C(29)-O(4) bond length is 1.42 Å. In the seventeenth C site, C(30) is bonded in a distorted single-bond geometry to one O(4) atom. The C(30)-O(4) bond length is 1.39 Å. There are sixteen inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(13,14) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(16) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the thirteenth H site, H(18) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(20) atom. In the fifteenth H site, H(26) is bonded in a single-bond geometry to one C(29) atom. In the sixteenth H site, H(27) is bonded in a single-bond geometry to one C(29) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one C(10) and one C(7) atom. In the second O site, O(4) is bonded in a bent 120 degrees geometry to one C(29) and one C(30) atom. In the third O site, O(5) is bonded in a bent 120 degrees geometry to one C(20) and one C(21) atom. In each Zn2(COO)3 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a trigonal planar geometry to one O(2), one O(6), and one O(8) atom. The Zn(1)-O(2) bond length is 1.92 Å. The Zn(1)-O(6) bond length is 1.88 Å. The Zn(1)-O(8) bond length is 1.81 Å. In the second Zn site, Zn(2) is bonded in a trigonal non-coplanar geometry to one O(1), one O(7), and one O(9) atom. The Zn(2)-O(1) bond length is 1.92 Å. The Zn(2)-O(7) bond length is 1.94 Å. The Zn(2)-O(9) bond length is 2.13 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(1)-O(1) bond length is 1.31 Å. The C(1)-O(2) bond length is 1.24 Å. In the second C site, C(38) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(38)-O(6) bond length is 1.18 Å. The C(38)-O(7) bond length is 1.27 Å. In the third C site, C(39) is bonded in a 2-coordinate geometry to one O(8) and one O(9) atom. The C(39)-O(8) bond length is 1.38 Å. The C(39)-O(9) bond length is 1.16 Å. There are six inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the third O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(38) atom. In the fourth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(38) atom. In the fifth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(39) atom. In the sixth O site, O(9) is bonded in a distorted single-bond geometry to one Zn(2) and one C(39) atom. Linkers: 8 Cc1c(COc2ccc(/C=C/C([O])=O)cc2)c(C)c(COc2ccc(/C=C/C([O])=O)cc2)c(C)c1COc1ccc(/C=C/C([O])=O)cc1. Metal clusters: 8 [C]1O[Zn]2O[C]O[Zn](O1)O[C]O2. RCSR code: hcb. The MOF has largest included sphere 10.05 A, density 0.89 g/cm3, surface area 5054.75 m2/g, accessible volume 0.71 cm3/g