Cu2C22N12H29O(CH)4(CH2)2 crystallizes in the monoclinic P2_1/c space group. The structure consists of sixteen 02329_fluka molecules and eight 02329_fluka molecules inside a Cu2C22N12H29O framework. In the Cu2C22N12H29O framework, there are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square pyramidal geometry to one N(1), one N(11), one N(4), one N(7), and one O(1) atom. The Cu(1)-N(1) bond length is 2.03 Å. The Cu(1)-N(11) bond length is 2.02 Å. The Cu(1)-N(4) bond length is 1.98 Å. The Cu(1)-N(7) bond length is 2.21 Å. The Cu(1)-O(1) bond length is 1.92 Å. In the second Cu site, Cu(2) is bonded in a square co-planar geometry to two equivalent N(10) and two equivalent O(1) atoms. Both Cu(2)-N(10) bond lengths are 2.00 Å. Both Cu(2)-O(1) bond lengths are 1.91 Å. In the third Cu site, Cu(3) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(5), and two equivalent N(8) atoms. Both Cu(3)-N(2) bond lengths are 2.03 Å. Both Cu(3)-N(5) bond lengths are 2.53 Å. Both Cu(3)-N(8) bond lengths are 2.03 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(2) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-N(3) bond length is 1.36 Å. The C(1)-H(2) bond length is 0.95 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(3) atom. The C(2)-N(2) bond length is 1.30 Å. The C(2)-N(3) bond length is 1.34 Å. The C(2)-H(3) bond length is 0.95 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(4) atom. The C(3)-N(4) bond length is 1.31 Å. The C(3)-N(6) bond length is 1.34 Å. The C(3)-H(4) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(5) atom. The C(4)-N(5) bond length is 1.31 Å. The C(4)-N(6) bond length is 1.36 Å. The C(4)-H(5) bond length is 0.95 Å. In the fifth C site, C(5) is bonded to one C(10), one C(11), one C(6), and one N(3) atom to form distorted corner-sharing CC3N tetrahedra. The C(5)-C(10) bond length is 1.54 Å. The C(5)-C(11) bond length is 1.52 Å. The C(5)-C(6) bond length is 1.52 Å. The C(5)-N(3) bond length is 1.49 Å. In the sixth C site, C(6) is bonded in a water-like geometry to one C(5) and two equivalent H(6,7) atoms. Both C(6)-H(6,7) bond lengths are 0.99 Å. In the seventh C site, C(8) is bonded in a water-like geometry to one C(9) and two equivalent H(9,10) atoms. The C(8)-C(9) bond length is 1.53 Å. Both C(8)-H(9,10) bond lengths are 0.99 Å. In the eighth C site, C(9) is bonded to one C(10), one C(13), one C(8), and one N(6) atom to form distorted corner-sharing CC3N tetrahedra. The C(9)-C(10) bond length is 1.52 Å. The C(9)-C(13) bond length is 1.50 Å. The C(9)-N(6) bond length is 1.49 Å. In the ninth C site, C(10) is bonded in a water-like geometry to one C(5); one C(9); and two equivalent H(11,12) atoms. Both C(10)-H(11,12) bond lengths are 0.99 Å. In the tenth C site, C(11) is bonded in a water-like geometry to one C(5) and two equivalent H(13,14) atoms. Both C(11)-H(13,14) bond lengths are 0.99 Å. In the eleventh C site, C(13) is bonded in a water-like geometry to one C(9) and two equivalent H(16,17,24,25) atoms. Both C(13)-H(16,17,24,25) bond lengths are 0.99 Å. In the twelfth C site, C(15) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(20) atom. The C(15)-N(7) bond length is 1.31 Å. The C(15)-N(9) bond length is 1.34 Å. The C(15)-H(20) bond length is 0.95 Å. In the thirteenth C site, C(16) is bonded in a trigonal planar geometry to one N(8), one N(9), and one H(21) atom. The C(16)-N(8) bond length is 1.32 Å. The C(16)-N(9) bond length is 1.35 Å. The C(16)-H(21) bond length is 0.95 Å. In the fourteenth C site, C(17) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(22) atom. The C(17)-N(10) bond length is 1.32 Å. The C(17)-N(12) bond length is 1.35 Å. The C(17)-H(22) bond length is 0.95 Å. In the fifteenth C site, C(18) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(23) atom. The C(18)-N(11) bond length is 1.32 Å. The C(18)-N(12) bond length is 1.33 Å. The C(18)-H(23) bond length is 0.95 Å. In the sixteenth C site, C(19) is bonded to one C(20), one C(24), one C(25), and one N(9) atom to form distorted corner-sharing CC3N tetrahedra. The C(19)-C(20) bond length is 1.51 Å. The C(19)-C(24) bond length is 1.54 Å. The C(19)-C(25) bond length is 1.52 Å. The C(19)-N(9) bond length is 1.50 Å. In the seventeenth C site, C(20) is bonded in a water-like geometry to one C(19) and two equivalent H(16,17,24,25) atoms. Both C(20)-H(16,17,24,25) bond lengths are 0.99 Å. In the eighteenth C site, C(22) is bonded in a water-like geometry to one C(23) and two equivalent H(27,28) atoms. The C(22)-C(23) bond length is 1.52 Å. Both C(22)-H(27,28) bond lengths are 0.99 Å. In the nineteenth C site, C(23) is bonded to one C(22), one C(24), one C(27), and one N(12) atom to form distorted corner-sharing CC3N tetrahedra. The C(23)-C(24) bond length is 1.53 Å. The C(23)-C(27) bond length is 1.53 Å. The C(23)-N(12) bond length is 1.50 Å. In the twentieth C site, C(24) is bonded in a water-like geometry to one C(19), one C(23), one H(29), and one H(30) atom. The C(24)-H(29) bond length is 0.99 Å. The C(24)-H(30) bond length is 0.99 Å. In the twenty-first C site, C(25) is bonded in a water-like geometry to one C(19) and two equivalent H(31,32) atoms. Both C(25)-H(31,32) bond lengths are 0.99 Å. In the twenty-second C site, C(27) is bonded in a water-like geometry to one C(23) and two equivalent H(34,35) atoms. Both C(27)-H(34,35) bond lengths are 0.99 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.37 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Cu(3), one C(2), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(5) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(3), and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a distorted single-bond geometry to one Cu(3), one C(4), and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(9) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(15), and one N(8) atom. The N(7)-N(8) bond length is 1.38 Å. In the eighth N site, N(8) is bonded in a 3-coordinate geometry to one Cu(3), one C(16), and one N(7) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one C(15), one C(16), and one C(19) atom. In the tenth N site, N(10) is bonded in a distorted trigonal planar geometry to one Cu(2), one C(17), and one N(11) atom. The N(10)-N(11) bond length is 1.37 Å. In the eleventh N site, N(11) is bonded in a 3-coordinate geometry to one Cu(1), one C(18), and one N(10) atom. In the twelfth N site, N(12) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(23) atom. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.97 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6,7) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(11,12) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(13,14) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(16,17,24,25) is bonded in a single-bond geometry to one C(13) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(15) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(16) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(17) atom. In the fourteenth H site, H(23) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(27,28) is bonded in a single-bond geometry to one C(22) atom. In the sixteenth H site, H(29) is bonded in a single-bond geometry to one C(24) atom. In the seventeenth H site, H(30) is bonded in a single-bond geometry to one C(24) atom. In the eighteenth H site, H(31,32) is bonded in a single-bond geometry to one C(25) atom. In the nineteenth H site, H(34,35) is bonded in a single-bond geometry to one C(27) atom. O(1) is bonded in a distorted single-bond geometry to one Cu(1), one Cu(2), and one H(1) atom. Linkers: 8 c1nncn1[C@]12C[C@H]3C[C@H](C[C@](n4cnnc4)(C3)C1)C2. Metal clusters: 8 [Cu]. The MOF has largest included sphere 4.78 A, density 1.15 g/cm3, surface area 4210.41 m2/g, accessible volume 0.43 cm3/g