Zn2C11H7(N3O2)2CH crystallizes in the orthorhombic Pnma space group. The structure consists of four 02329_fluka molecules inside a Zn2C11H7(N3O2)2 framework. In the Zn2C11H7(N3O2)2 framework, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one N(3), and one O(1) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-N(2) bond length is 1.98 Å. The Zn(1)-N(3) bond length is 2.00 Å. The Zn(1)-O(1) bond length is 1.94 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.29 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(2) atom. The C(2)-N(1) bond length is 1.34 Å. The C(2)-N(3) bond length is 1.32 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(3)-C(4) bond length is 1.51 Å. The C(3)-O(1) bond length is 1.26 Å. The C(3)-O(2) bond length is 1.23 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to two equivalent C(4) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a 2-coordinate geometry to one Zn(1), one C(1), and one N(3) atom. The N(2)-N(3) bond length is 1.38 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Zn(1), one C(2), and one N(2) atom. There are four inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(5) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. Linkers: 6 [N]1=CN=NC=1 ,2 C1=NC=N[N]1 ,4 [O]C(=O)c1cccc(C([O])=O)c1. Metal clusters: 4 O=[C]O[Zn]1=NN=[Zn](O[C]=O)N=N1. The MOF has largest included sphere 5.26 A, density 1.17 g/cm3, surface area 4092.06 m2/g, accessible volume 0.52 cm3/g