Zn3C76N6H34(O4F5)2 crystallizes in the triclinic P-1 space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.07 Å. The Zn(1)-O(3) bond length is 2.02 Å. The Zn(1)-O(4) bond length is 2.03 Å. In the second Zn site, Zn(2) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent N(3) atoms. Both Zn(2)-N(2) bond lengths are 2.00 Å. Both Zn(2)-N(3) bond lengths are 2.00 Å. There are thirty-eight inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.24 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(2) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(8) bond length is 1.48 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(3) atom. The C(6)-C(7) bond length is 1.35 Å. The C(6)-H(3) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(4) atom. The C(7)-H(4) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(5), and one C(9) atom. The C(8)-C(10) bond length is 1.42 Å. The C(8)-C(9) bond length is 1.38 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(5) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(5) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(8), and one C(9) atom. The C(10)-C(11) bond length is 1.48 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(16) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-C(16) bond length is 1.39 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(12)-H(6) bond length is 0.95 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(7) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-H(7) bond length is 0.95 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(15) bond length is 1.38 Å. The C(14)-C(17) bond length is 1.50 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one H(8) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(8) bond length is 0.95 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(11), one C(15), and one H(9) atom. The C(16)-H(9) bond length is 0.95 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(3), and one O(4) atom. The C(17)-O(3) bond length is 1.26 Å. The C(17)-O(4) bond length is 1.24 Å. In the eighteenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(19), one N(1), and one H(10) atom. The C(18)-C(19) bond length is 1.32 Å. The C(18)-N(1) bond length is 1.32 Å. The C(18)-H(10) bond length is 0.95 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(11) atom. The C(19)-C(20) bond length is 1.36 Å. The C(19)-H(11) bond length is 0.95 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(23) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-C(23) bond length is 1.52 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one H(12) atom. The C(21)-C(22) bond length is 1.37 Å. The C(21)-H(12) bond length is 0.95 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one N(1), and one H(13) atom. The C(22)-N(1) bond length is 1.27 Å. The C(22)-H(13) bond length is 0.95 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(20), one C(24), and one C(38) atom. The C(23)-C(24) bond length is 1.31 Å. The C(23)-C(38) bond length is 1.38 Å. In the twenty-fourth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one C(25), and one N(2) atom. The C(24)-C(25) bond length is 1.45 Å. The C(24)-N(2) bond length is 1.39 Å. In the twenty-fifth C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(14) atom. The C(25)-H(14) bond length is 0.95 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(27) and one H(15) atom. The C(26)-C(27) bond length is 1.63 Å. The C(26)-H(15) bond length is 1.00 Å. In the twenty-seventh C site, C(27) is bonded in a 3-coordinate geometry to one C(26), one C(28), and one N(2) atom. The C(27)-C(28) bond length is 1.36 Å. The C(27)-N(2) bond length is 1.43 Å. In the twenty-eighth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(35) atom. The C(28)-C(29) bond length is 1.57 Å. The C(28)-C(35) bond length is 1.56 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(34) atom. The C(29)-C(30) bond length is 1.39 Å. The C(29)-C(34) bond length is 1.39 Å. In the thirtieth C site, C(30) is bonded in a distorted single-bond geometry to one C(29), one C(31), and one F(1) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-F(1) bond length is 1.36 Å. In the thirty-first C site, C(31) is bonded in a distorted trigonal planar geometry to one C(30), one C(32), and one F(2) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-F(2) bond length is 1.41 Å. In the thirty-second C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31), one C(33), and one F(3) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-F(3) bond length is 1.39 Å. In the thirty-third C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one F(4) atom. The C(33)-F(4) bond length is 1.40 Å. In the thirty-fourth C site, C(34) is bonded in a distorted single-bond geometry to one C(29) and one F(5) atom. The C(34)-F(5) bond length is 1.40 Å. In the thirty-fifth C site, C(35) is bonded in a trigonal non-coplanar geometry to one C(28), one C(36), and one N(3) atom. The C(35)-C(36) bond length is 1.51 Å. The C(35)-N(3) bond length is 1.33 Å. In the thirty-sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(35), one C(37), and one H(16) atom. The C(36)-C(37) bond length is 1.40 Å. The C(36)-H(16) bond length is 0.95 Å. In the thirty-seventh C site, C(37) is bonded in a distorted single-bond geometry to one C(36), one C(38), and one H(17) atom. The C(37)-C(38) bond length is 1.46 Å. The C(37)-H(17) bond length is 0.95 Å. In the thirty-eighth C site, C(38) is bonded in a trigonal planar geometry to one C(23), one C(37), and one N(3) atom. The C(38)-N(3) bond length is 1.38 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(18), and one C(22) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(2), one C(24), and one C(27) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(35), and one C(38) atom. There are seventeen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(36) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(37) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(17) atom. There are five inequivalent F sites. In the first F site, F(2) is bonded in a single-bond geometry to one C(31) atom. In the second F site, F(4) is bonded in a single-bond geometry to one C(33) atom. In the third F site, F(5) is bonded in a single-bond geometry to one C(34) atom. In the fourth F site, F(3) is bonded in a single-bond geometry to one C(32) atom. In the fifth F site, F(1) is bonded in a single-bond geometry to one C(30) atom. Linkers: 2 FC1=C(C(=C([C]=[C]1)F)F)C1=C2C=CC3=[N]2[Zn@]24n5c1ccc5C(=C1[N]2=C(C=C1)C(=c1n4c(=C3c2ccncc2)cc1)c1c(F)c(F)c(c(c1F)F)F)c1ccncc1 ,1 Fc1c(F)c(F)c(c(c1F)C1=C2C=CC3=[N]2[Zn@]24n5c1ccc5C(=C1[N]2=C(C=C1)C(=c1n4c(=C3c2ccncc2)cc1)c1c(F)c(F)c(c(c1F)F)F)C1=C[C]=NC=C1)F ,1 Fc1c(F)c(F)c(c(c1F)C1=C2C=CC3=[N]2[Zn@]24n5c1ccc5C(=C1[N]2=C(C=C1)C(=c1n4c(=C3c2ccncc2)cc1)c1c(F)c(F)c(c(c1F)F)F)c1ccncc1)F ,1 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)c(-c3ccc(C([O])=O)cc3)cc2-c2ccc(C([O])=O)cc2)cc1 ,1 Fc1c(F)c(F)c(c(c1F)C1=C2C=CC3=[N]2[Zn@]24n5c1ccc5C(=C1[N]2=C(C=C1)C(=c1n4c(=C3C2=CC=N[C]=C2)cc1)c1c(F)c(F)c(c(c1F)F)F)c1ccncc1)F. Metal clusters: 1 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 7.45 A, density 0.71 g/cm3, surface area 4307.34 m2/g, accessible volume 0.89 cm3/g