Cu(OOCC6H4COO)CuC10NH6O4(CH)8C3H2(C2O)2 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixty-four 02329_fluka molecules; four 2,3-dimethyl-1,3-butadiene molecules; sixteen dimethyl ether molecules; four Cu(OOCC6H4COO) clusters; and four CuC10NH6O4 clusters. In each Cu(OOCC6H4COO) cluster, Cu(2) is bonded in a distorted rectangular see-saw-like geometry to one O(5), one O(6), one O(7), and one O(9) atom. The Cu(2)-O(5) bond length is 1.98 Å. The Cu(2)-O(6) bond length is 1.99 Å. The Cu(2)-O(7) bond length is 2.00 Å. The Cu(2)-O(9) bond length is 1.99 Å. There are eight inequivalent C sites. In the first C site, C(19) is bonded in a distorted single-bond geometry to one C(7) and one H(9) atom. The C(19)-C(7) bond length is 1.42 Å. The C(19)-H(9) bond length is 0.93 Å. In the second C site, C(20) is bonded in a trigonal planar geometry to one C(14), one C(27), and one C(4) atom. The C(20)-C(14) bond length is 1.40 Å. The C(20)-C(27) bond length is 1.40 Å. The C(20)-C(4) bond length is 1.52 Å. In the third C site, C(27) is bonded in a distorted single-bond geometry to one C(20) and one H(14) atom. The C(27)-H(14) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a bent 120 degrees geometry to one C(20), one O(5), and one O(9) atom. The C(4)-O(5) bond length is 1.24 Å. The C(4)-O(9) bond length is 1.31 Å. In the fifth C site, C(14) is bonded in a distorted single-bond geometry to one C(20) and one H(7) atom. The C(14)-H(7) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(19) atom. The C(7)-C(10) bond length is 1.50 Å. The C(7)-C(12) bond length is 1.43 Å. In the seventh C site, C(10) is bonded in a bent 120 degrees geometry to one C(7), one O(6), and one O(7) atom. The C(10)-O(6) bond length is 1.25 Å. The C(10)-O(7) bond length is 1.34 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(5) atom. The C(12)-H(5) bond length is 0.93 Å. There are four inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(27) atom. There are four inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(4) atom. In the second O site, O(6) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(10) atom. In the third O site, O(7) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(10) atom. In the fourth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(4) atom. In each CuC10NH6O4 cluster, Cu(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-N(1) bond length is 2.19 Å. The Cu(1)-O(1) bond length is 2.02 Å. The Cu(1)-O(2) bond length is 2.02 Å. The Cu(1)-O(3) bond length is 1.99 Å. The Cu(1)-O(4) bond length is 2.02 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(23), one O(1), and one O(2) atom. The C(1)-C(23) bond length is 1.55 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.30 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(4) atom. The C(2)-C(3) bond length is 1.50 Å. The C(2)-O(3) bond length is 1.28 Å. The C(2)-O(4) bond length is 1.29 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(21), and one C(8) atom. The C(3)-C(21) bond length is 1.39 Å. The C(3)-C(8) bond length is 1.39 Å. In the fourth C site, C(8) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(8)-H(3) bond length is 0.93 Å. In the fifth C site, C(13) is bonded in a distorted single-bond geometry to one C(23) and one H(6) atom. The C(13)-C(23) bond length is 1.42 Å. The C(13)-H(6) bond length is 0.93 Å. In the sixth C site, C(21) is bonded in a distorted single-bond geometry to one C(3) and one H(10) atom. The C(21)-H(10) bond length is 0.93 Å. In the seventh C site, C(23) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(29) atom. The C(23)-C(29) bond length is 1.35 Å. In the eighth C site, C(29) is bonded in a distorted single-bond geometry to one C(23) and one H(16) atom. The C(29)-H(16) bond length is 0.93 Å. In the ninth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(18) atom. The C(31)-N(1) bond length is 1.37 Å. The C(31)-H(18) bond length is 0.93 Å. In the tenth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(19) atom. The C(32)-N(1) bond length is 1.32 Å. The C(32)-H(19) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(31), and one C(32) atom. There are six inequivalent H sites. In the first H site, H(3) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(21) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(29) atom. In the fifth H site, H(18) is bonded in a single-bond geometry to one C(31) atom. In the sixth H site, H(19) is bonded in a single-bond geometry to one C(32) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(2) atom. Linkers: 8 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,2 c1cc(-c2ccncc2)ccn1. Metal clusters: 4 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: lvt. The MOF has largest included sphere 6.94 A, density 1.03 g/cm3, surface area 4347.36 m2/g, accessible volume 0.45 cm3/g