Cr3O(OC1OC6)6 is Indium-derived structured and crystallizes in the hexagonal P-62c space group. The structure is zero-dimensional and consists of six 787-70-2 molecules and two Cr3O clusters. In each Cr3O cluster, Cr(1) is bonded in a distorted single-bond geometry to one O(3) atom. The Cr(1)-O(3) bond length is 1.98 Å. O(3) is bonded in a trigonal planar geometry to three equivalent Cr(1) atoms. Linkers: 6 [O]C(=O)c1[c][c]c(-c2[c][c]c(C([O])=O)[c][c]2)[c][c]1. Metal clusters: 2 [C]1O[Cr]23O[C]O[Cr]45(O1)O[C]O[Cr](O[C]O2)(O[C]O3)(O[C]O4)O5. RCSR code: acs. The MOF has largest included sphere 15.25 A, density 0.36 g/cm3, surface area 4270.11 m2/g, accessible volume 2.13 cm3/g