(NaZnC12(OCl)6)2CH2CO crystallizes in the monoclinic C2/c space group. The structure consists of four acetylene-water molecules inside a NaZnC12(OCl)6 framework. In the NaZnC12(OCl)6 framework, Na(1) is bonded in a 4-coordinate geometry to one O(2), one O(3), and two equivalent O(5) atoms. The Na(1)-O(2) bond length is 2.31 Å. The Na(1)-O(3) bond length is 2.49 Å. There is one shorter (2.36 Å) and one longer (2.41 Å) Na(1)-O(5) bond length. Zn(1) is bonded in a distorted trigonal non-coplanar geometry to one O(1), one O(3), and one O(6) atom. The Zn(1)-O(1) bond length is 1.96 Å. The Zn(1)-O(3) bond length is 1.98 Å. The Zn(1)-O(6) bond length is 1.93 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.53 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.21 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one Cl(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-Cl(1) bond length is 1.73 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one Cl(2) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-Cl(2) bond length is 1.73 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(8) bond length is 1.51 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(7), and one Cl(4) atom. The C(6)-C(7) bond length is 1.38 Å. The C(6)-Cl(4) bond length is 1.73 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(2), one C(6), and one Cl(3) atom. The C(7)-Cl(3) bond length is 1.74 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.26 Å. The C(8)-O(4) bond length is 1.21 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(5), and one O(6) atom. The C(9)-C(10) bond length is 1.53 Å. The C(9)-O(5) bond length is 1.22 Å. The C(9)-O(6) bond length is 1.28 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.37 Å. The C(10)-C(12) bond length is 1.40 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one Cl(5) atom. The C(11)-C(12) bond length is 1.41 Å. The C(11)-Cl(5) bond length is 1.73 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(10), one C(11), and one Cl(6) atom. The C(12)-Cl(6) bond length is 1.73 Å. There are six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Na(1) and one C(1) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Na(1), one Zn(1), and one C(8) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to two equivalent Na(1) and one C(9) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(9) atom. There are six inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one C(3) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one C(4) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth Cl site, Cl(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth Cl site, Cl(5) is bonded in a single-bond geometry to one C(11) atom. In the sixth Cl site, Cl(6) is bonded in a single-bond geometry to one C(12) atom. Linkers: 6 [O]C(=O)c1c(Cl)c(Cl)c(C([O])=O)c(Cl)c1Cl. Metal clusters: 2 O.O=[C]O[Zn](O[C]O[Na])O[C]=O.O=[C]O[Zn](O[C]O[Na])O[C]=O. RCSR code: pcu. The MOF has largest included sphere 5.33 A, density 1.33 g/cm3, surface area 3755.29 m2/g, accessible volume 0.37 cm3/g