Zn3H11(C3O2)7C27N10H15 is Indium-derived structured and crystallizes in the tetragonal I4/m space group. The structure is zero-dimensional and consists of sixteen 4-(1-methyltriazol-4-yl)-n,n-bis[4-(1-methyltriazol-4-yl)phenyl]aniline molecules and two Zn3H11(C3O2)7 clusters. In each Zn3H11(C3O2)7 cluster, there are four inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a square pyramidal geometry to one O(1), one O(11), one O(4), one O(7), and one O(8) atom. The Zn(1)-O(1) bond length is 2.15 Å. The Zn(1)-O(11) bond length is 1.94 Å. The Zn(1)-O(4) bond length is 1.97 Å. The Zn(1)-O(7) bond length is 1.95 Å. The Zn(1)-O(8) bond length is 1.97 Å. In the second Zn site, Zn(2) is bonded in a square pyramidal geometry to one O(10), one O(12), one O(2), one O(6), and one O(9) atom. The Zn(2)-O(10) bond length is 1.96 Å. The Zn(2)-O(12) bond length is 1.96 Å. The Zn(2)-O(2) bond length is 2.14 Å. The Zn(2)-O(6) bond length is 1.97 Å. The Zn(2)-O(9) bond length is 1.96 Å. In the third Zn site, Zn(3) is bonded in a square co-planar geometry to two equivalent O(13) and two equivalent O(5) atoms. Both Zn(3)-O(13) bond lengths are 1.98 Å. Both Zn(3)-O(5) bond lengths are 1.95 Å. In the fourth Zn site, Zn(4) is bonded in a distorted square co-planar geometry to two equivalent O(14) and two equivalent O(3) atoms. Both Zn(4)-O(14) bond lengths are 1.98 Å. Both Zn(4)-O(3) bond lengths are 1.95 Å. There are twenty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-H(3) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.53 Å. The C(2)-C(4) bond length is 1.39 Å. In the third C site, C(3) is bonded in a bent 120 degrees geometry to one C(2), one O(3), and one O(5) atom. The C(3)-O(3) bond length is 1.24 Å. The C(3)-O(5) bond length is 1.25 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(4) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(4) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.52 Å. The C(5)-C(7) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(4), and one O(6) atom. The C(6)-O(4) bond length is 1.26 Å. The C(6)-O(6) bond length is 1.22 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(5) and one H(5) atom. The C(7)-H(5) bond length is 0.93 Å. In the eighth C site, C(33) is bonded in a trigonal planar geometry to one C(34), one C(44), and one C(45) atom. The C(33)-C(34) bond length is 1.41 Å. The C(33)-C(44) bond length is 1.50 Å. The C(33)-C(45) bond length is 1.38 Å. In the ninth C site, C(34) is bonded in a distorted single-bond geometry to one C(33) and one H(21) atom. The C(34)-H(21) bond length is 0.93 Å. In the tenth C site, C(35) is bonded in a distorted single-bond geometry to one C(46) and one H(22) atom. The C(35)-C(46) bond length is 1.38 Å. The C(35)-H(22) bond length is 0.93 Å. In the eleventh C site, C(37) is bonded in a distorted single-bond geometry to one C(38), one C(39), and one H(23) atom. The C(37)-C(38) bond length is 1.38 Å. The C(37)-C(39) bond length is 1.40 Å. The C(37)-H(23) bond length is 0.93 Å. In the twelfth C site, C(38) is bonded in a trigonal planar geometry to one C(37), one C(40), and one C(47) atom. The C(38)-C(40) bond length is 1.37 Å. The C(38)-C(47) bond length is 1.51 Å. In the thirteenth C site, C(39) is bonded in a trigonal planar geometry to one C(37), one C(41), and one C(48) atom. The C(39)-C(41) bond length is 1.36 Å. The C(39)-C(48) bond length is 1.53 Å. In the fourteenth C site, C(40) is bonded in a distorted single-bond geometry to one C(38) and one H(24) atom. The C(40)-H(24) bond length is 0.93 Å. In the fifteenth C site, C(41) is bonded in a single-bond geometry to one C(39) and one H(25) atom. The C(41)-H(25) bond length is 0.93 Å. In the sixteenth C site, C(43) is bonded in a distorted bent 120 degrees geometry to one C(46), one O(10), and one O(8) atom. The C(43)-C(46) bond length is 1.51 Å. The C(43)-O(10) bond length is 1.24 Å. The C(43)-O(8) bond length is 1.25 Å. In the seventeenth C site, C(44) is bonded in a bent 120 degrees geometry to one C(33), one O(7), and one O(9) atom. The C(44)-O(7) bond length is 1.23 Å. The C(44)-O(9) bond length is 1.25 Å. In the eighteenth C site, C(45) is bonded in a distorted single-bond geometry to one C(33), one C(46), and one H(26) atom. The C(45)-C(46) bond length is 1.39 Å. The C(45)-H(26) bond length is 0.93 Å. In the nineteenth C site, C(46) is bonded in a trigonal planar geometry to one C(35), one C(43), and one C(45) atom. In the twentieth C site, C(47) is bonded in a bent 120 degrees geometry to one C(38), one O(11), and one O(12) atom. The C(47)-O(11) bond length is 1.25 Å. The C(47)-O(12) bond length is 1.25 Å. In the twenty-first C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(39), one O(13), and one O(14) atom. The C(48)-O(13) bond length is 1.24 Å. The C(48)-O(14) bond length is 1.24 Å. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.82 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(2) atom. The H(2)-O(2) bond length is 0.82 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(21) is bonded in a single-bond geometry to one C(34) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one C(35) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(37) atom. In the ninth H site, H(24) is bonded in a single-bond geometry to one C(40) atom. In the tenth H site, H(25) is bonded in a single-bond geometry to one C(41) atom. In the eleventh H site, H(26) is bonded in a single-bond geometry to one C(45) atom. There are fourteen inequivalent O sites. In the first O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(44) atom. In the second O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(43) atom. In the third O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(47) atom. In the fourth O site, O(12) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(47) atom. In the fifth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(48) atom. In the sixth O site, O(14) is bonded in a distorted single-bond geometry to one Zn(4) and one C(48) atom. In the seventh O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(3) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(43) atom. In the ninth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(6) atom. In the tenth O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(44) atom. In the eleventh O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(4) and one C(3) atom. In the twelfth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the thirteenth O site, O(1) is bonded in a water-like geometry to one Zn(1) and one H(1) atom. In the fourteenth O site, O(2) is bonded in a water-like geometry to one Zn(2) and one H(2) atom. Linkers: 16 [O]C(=O)c1cc(C([O])=O)cc(-n2cc(-c3ccc(N(c4ccc(-c5cn(-c6cc(C([O])=O)cc(C([O])=O)c6)nn5)cc4)c4ccc(-c5cn(-c6cc(C([O])=O)cc(C([O])=O)c6)nn5)cc4)cc3)nn2)c1. Metal clusters: 16 O[Zn]1234O[C]O[Zn]1(O)(O[C]O2)(O[C]O3)O[C]O4 ,8 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 21.50 A, density 0.47 g/cm3, surface area 4257.26 m2/g, accessible volume 1.69 cm3/g