CoC19N9H14O2C3H2C9H6N is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of four 2,3-dimethyl-1,3-butadiene molecules; eight schembl1705614 molecules; and eight CoC19N9H14O2 clusters. In each CoC19N9H14O2 cluster, Co(1) is bonded in a square pyramidal geometry to one N(1), one N(4), one N(7), one O(1), and one O(2) atom. The Co(1)-N(1) bond length is 2.13 Å. The Co(1)-N(4) bond length is 2.11 Å. The Co(1)-N(7) bond length is 2.12 Å. The Co(1)-O(1) bond length is 2.18 Å. The Co(1)-O(2) bond length is 2.23 Å. There are nineteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(3) bond length is 1.31 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(2) atom. The C(2)-N(1) bond length is 1.32 Å. The C(2)-N(2) bond length is 1.33 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(3) atom. The C(3)-N(4) bond length is 1.32 Å. The C(3)-N(5) bond length is 1.33 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(5) atom. The C(5)-N(7) bond length is 1.34 Å. The C(5)-N(8) bond length is 1.31 Å. The C(5)-H(5) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(6) atom. The C(6)-N(7) bond length is 1.32 Å. The C(6)-N(9) bond length is 1.33 Å. The C(6)-H(6) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(12), one C(8), and one N(2) atom. The C(7)-C(12) bond length is 1.38 Å. The C(7)-C(8) bond length is 1.38 Å. The C(7)-N(2) bond length is 1.43 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(8)-H(7) bond length is 0.93 Å. In the eighth C site, C(4) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(4) atom. The C(4)-N(4) bond length is 1.34 Å. The C(4)-N(6) bond length is 1.32 Å. The C(4)-H(4) bond length is 0.93 Å. In the ninth C site, C(12) is bonded in a distorted single-bond geometry to one C(7) and one H(10) atom. The C(12)-H(10) bond length is 0.93 Å. In the tenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one N(5) atom. The C(13)-C(14) bond length is 1.37 Å. The C(13)-C(18) bond length is 1.38 Å. The C(13)-N(5) bond length is 1.43 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(11,14) atom. The C(14)-H(11,14) bond length is 0.93 Å. In the twelfth C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(11,14) atom. The C(18)-H(11,14) bond length is 0.93 Å. In the thirteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(16) atom. The C(21)-C(22) bond length is 1.37 Å. The C(21)-H(16) bond length is 0.93 Å. In the fourteenth C site, C(22) is bonded in a distorted trigonal planar geometry to one C(21), one C(23), and one N(9) atom. The C(22)-C(23) bond length is 1.36 Å. The C(22)-N(9) bond length is 1.43 Å. In the fifteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(17) atom. The C(23)-H(17) bond length is 0.93 Å. In the sixteenth C site, C(25) is bonded in a bent 120 degrees geometry to one C(26), one O(1), and one O(2) atom. The C(25)-C(26) bond length is 1.50 Å. The C(25)-O(1) bond length is 1.26 Å. The C(25)-O(2) bond length is 1.26 Å. In the seventeenth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(31) atom. The C(26)-C(27) bond length is 1.37 Å. The C(26)-C(31) bond length is 1.37 Å. In the eighteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(19,22) atom. The C(27)-H(19,22) bond length is 0.93 Å. In the nineteenth C site, C(31) is bonded in a distorted single-bond geometry to one C(26) and one H(19,22) atom. The C(31)-H(19,22) bond length is 0.93 Å. There are nine inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Co(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(2), one C(7), and one N(3) atom. The N(2)-N(3) bond length is 1.37 Å. In the third N site, N(3) is bonded in a distorted single-bond geometry to one C(1) and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Co(1), one C(3), and one C(4) atom. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one C(13) and one C(3) atom. In the sixth N site, N(6) is bonded in a distorted single-bond geometry to one C(4) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one Co(1), one C(5), and one C(6) atom. In the eighth N site, N(8) is bonded in a distorted water-like geometry to one C(5) and one N(9) atom. The N(8)-N(9) bond length is 1.36 Å. In the ninth N site, N(9) is bonded in a 3-coordinate geometry to one C(22), one C(6), and one N(8) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11,14) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(19,22) is bonded in a single-bond geometry to one C(27) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one Co(1) and one C(25) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Co(1) and one C(25) atom. Linkers: 3 [CH]1N=C[N]N1c1ccc(N(c2ccc(N3[CH]N=C[N]3)cc2)c2ccc(N3[CH]N=C[N]3)cc2)cc1 ,3 [CH]1N=C[N]N1c1ccc(N(c2ccc(N3[CH]N=C[N]3)cc2)c2ccc(-n3cncn3)cc2)cc1 ,1 c1ncn(-c2ccc(N(c3ccc(-n4cncn4)cc3)c3ccc(-n4cncn4)cc3)cc2)n1 ,1 [CH]1N=C[N]N1c1ccc(N(c2ccc(-n3cncn3)cc2)c2ccc(-n3cncn3)cc2)cc1 ,4 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cc2)cc1. Metal clusters: 8 [C]1O[Co]O1. The MOF has largest included sphere 5.62 A, density 1.10 g/cm3, surface area 4856.80 m2/g, accessible volume 0.41 cm3/g