Zn3C25H13(NO6)2(CH)9 crystallizes in the monoclinic P2_1/c space group. The structure consists of thirty-six 02329_fluka molecules inside a Zn3C25H13(NO6)2 framework. In the Zn3C25H13(NO6)2 framework, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(10), one O(12), one O(2), one O(4), one O(5), and one O(7) atom to form corner-sharing ZnO6 octahedra. The Zn(1)-O(10) bond length is 2.05 Å. The Zn(1)-O(12) bond length is 2.05 Å. The Zn(1)-O(2) bond length is 1.98 Å. The Zn(1)-O(4) bond length is 2.28 Å. The Zn(1)-O(5) bond length is 2.04 Å. The Zn(1)-O(7) bond length is 2.17 Å. In the second Zn site, Zn(2) is bonded in a 5-coordinate geometry to one N(1), one O(1), one O(11), one O(7), and one O(8) atom. The Zn(2)-N(1) bond length is 2.01 Å. The Zn(2)-O(1) bond length is 1.98 Å. The Zn(2)-O(11) bond length is 1.95 Å. The Zn(2)-O(7) bond length is 2.09 Å. The Zn(2)-O(8) bond length is 2.34 Å. In the third Zn site, Zn(3) is bonded to one N(2), one O(4), one O(6), and one O(9) atom to form distorted corner-sharing ZnNO3 tetrahedra. The corner-sharing octahedral tilt angles are 81°. The Zn(3)-N(2) bond length is 2.01 Å. The Zn(3)-O(4) bond length is 1.99 Å. The Zn(3)-O(6) bond length is 1.99 Å. The Zn(3)-O(9) bond length is 1.94 Å. There are twenty-five inequivalent C sites. In the first C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(19) atom. The C(29)-C(28) bond length is 1.40 Å. The C(29)-H(19) bond length is 0.93 Å. In the second C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(21) atom. The C(31)-C(32) bond length is 1.39 Å. The C(31)-H(21) bond length is 0.93 Å. In the third C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(34) atom. The C(32)-C(33) bond length is 1.38 Å. The C(32)-C(34) bond length is 1.49 Å. In the fourth C site, C(33) is bonded in a distorted single-bond geometry to one C(28), one C(32), and one H(22) atom. The C(33)-C(28) bond length is 1.38 Å. The C(33)-H(22) bond length is 0.93 Å. In the fifth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(11), and one O(12) atom. The C(34)-O(11) bond length is 1.26 Å. The C(34)-O(12) bond length is 1.23 Å. In the sixth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.30 Å. The C(1)-H(1) bond length is 0.93 Å. In the seventh C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(5)-N(1) bond length is 1.29 Å. The C(5)-H(5) bond length is 0.93 Å. In the eighth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(6)-N(2) bond length is 1.33 Å. The C(6)-H(6) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(10) bond length is 0.93 Å. In the tenth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-O(1) bond length is 1.27 Å. The C(11)-O(2) bond length is 1.26 Å. In the eleventh C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-C(17) bond length is 1.38 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(13)-H(11) bond length is 0.93 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(13) atom. The C(15)-C(16) bond length is 1.41 Å. The C(15)-H(13) bond length is 0.93 Å. In the fourteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-C(18) bond length is 1.50 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(12), one C(16), and one H(14) atom. The C(17)-H(14) bond length is 0.93 Å. In the sixteenth C site, C(18) is bonded in a bent 120 degrees geometry to one C(16), one O(3), and one O(4) atom. The C(18)-O(3) bond length is 1.23 Å. The C(18)-O(4) bond length is 1.31 Å. In the seventeenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(5), and one O(6) atom. The C(19)-C(20) bond length is 1.48 Å. The C(19)-O(5) bond length is 1.24 Å. The C(19)-O(6) bond length is 1.27 Å. In the eighteenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(25) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-C(25) bond length is 1.39 Å. In the nineteenth C site, C(21) is bonded in a single-bond geometry to one C(20) and one H(15) atom. The C(21)-H(15) bond length is 0.93 Å. In the twentieth C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(17) atom. The C(23)-C(24) bond length is 1.36 Å. The C(23)-H(17) bond length is 0.93 Å. In the twenty-first C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(26) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-C(26) bond length is 1.50 Å. In the twenty-second C site, C(25) is bonded in a distorted single-bond geometry to one C(20), one C(24), and one H(18) atom. The C(25)-H(18) bond length is 0.93 Å. In the twenty-third C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(7), and one O(8) atom. The C(26)-O(7) bond length is 1.27 Å. The C(26)-O(8) bond length is 1.23 Å. In the twenty-fourth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(10), and one O(9) atom. The C(27)-C(28) bond length is 1.51 Å. The C(27)-O(10) bond length is 1.23 Å. The C(27)-O(9) bond length is 1.27 Å. In the twenty-fifth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(33) atom. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(3), one C(10), and one C(6) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(25) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(31) atom. In the thirteenth H site, H(22) is bonded in a single-bond geometry to one C(33) atom. There are twelve inequivalent O sites. In the first O site, O(12) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(34) atom. In the second O site, O(8) is bonded in a distorted L-shaped geometry to one Zn(2) and one C(26) atom. In the third O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(27) atom. In the fourth O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(11) atom. In the fifth O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(34) atom. In the sixth O site, O(3) is bonded in a single-bond geometry to one C(18) atom. In the seventh O site, O(4) is bonded in a distorted trigonal non-coplanar geometry to one Zn(1), one Zn(3), and one C(18) atom. In the eighth O site, O(10) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(27) atom. In the ninth O site, O(5) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(19) atom. In the tenth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(19) atom. In the eleventh O site, O(7) is bonded in a distorted T-shaped geometry to one Zn(1), one Zn(2), and one C(26) atom. In the twelfth O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(11) atom. Linkers: 12 [O]C(=O)c1cccc(C([O])=O)c1. Metal clusters: 12 [Zn]. The MOF has largest included sphere 5.17 A, density 1.35 g/cm3, surface area 4181.65 m2/g, accessible volume 0.34 cm3/g