AgC20N4H14S2O(CH)4 crystallizes in the trigonal R-3c space group. The structure is zero-dimensional and consists of one hundred and forty-four 02329_fluka molecules and six AgC20N4H14S2O clusters. In each AgC20N4H14S2O cluster, Ag(1) is bonded in a 4-coordinate geometry to one N(1), one N(2), one N(3), and one N(4) atom. The Ag(1)-N(1) bond length is 2.38 Å. The Ag(1)-N(2) bond length is 2.31 Å. The Ag(1)-N(3) bond length is 2.40 Å. The Ag(1)-N(4) bond length is 2.34 Å. There are twenty inequivalent C sites. In the first C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(14) bond length is 1.38 Å. The C(9)-C(8) bond length is 1.47 Å. In the second C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one O(1) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-O(1) bond length is 1.38 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(4) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(4) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.46 Å. The C(5)-N(1) bond length is 1.35 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one N(2), and one S(1) atom. The C(6)-N(2) bond length is 1.31 Å. The C(6)-S(1) bond length is 1.71 Å. In the seventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(17) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(17) bond length is 1.48 Å. In the eighth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(6) atom. The C(12)-C(13) bond length is 1.37 Å. The C(12)-H(6) bond length is 0.95 Å. In the ninth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(15) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-C(15) bond length is 1.50 Å. In the tenth C site, C(7) is bonded in a distorted single-bond geometry to one C(8), one H(5), and one S(1) atom. The C(7)-C(8) bond length is 1.37 Å. The C(7)-H(5) bond length is 0.95 Å. The C(7)-S(1) bond length is 1.68 Å. In the eleventh C site, C(15) is bonded in a trigonal non-coplanar geometry to one C(13); one H(8); and two equivalent H(9,10) atoms. The C(15)-H(8) bond length is 0.98 Å. Both C(15)-H(9,10) bond lengths are 0.98 Å. In the twelfth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(2) atom. The C(8)-N(2) bond length is 1.37 Å. In the thirteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(11), one C(18), and one N(3) atom. The C(17)-C(18) bond length is 1.35 Å. The C(17)-N(3) bond length is 1.37 Å. In the fourteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one H(14), and one S(2) atom. The C(18)-H(14) bond length is 0.95 Å. The C(18)-S(2) bond length is 1.69 Å. In the fifteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(20), one N(3), and one S(2) atom. The C(19)-C(20) bond length is 1.47 Å. The C(19)-N(3) bond length is 1.30 Å. The C(19)-S(2) bond length is 1.72 Å. In the sixteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one N(4) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-N(4) bond length is 1.33 Å. In the seventeenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(15) atom. The C(21)-H(15) bond length is 0.95 Å. In the eighteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13), one C(9), and one H(7) atom. The C(14)-H(7) bond length is 0.95 Å. In the nineteenth C site, C(16) is bonded in a tetrahedral geometry to one H(12); two equivalent H(11,13); and one O(1) atom. The C(16)-H(12) bond length is 0.98 Å. Both C(16)-H(11,13) bond lengths are 0.98 Å. The C(16)-O(1) bond length is 1.43 Å. In the twentieth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(18) atom. The C(24)-N(4) bond length is 1.34 Å. The C(24)-H(18) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(6), and one C(8) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Ag(1), one C(17), and one C(19) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Ag(1), one C(20), and one C(24) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(11,13) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(6) and one C(7) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one C(18) and one C(19) atom. O(1) is bonded in a bent 120 degrees geometry to one C(10) and one C(16) atom. Linkers: 36 COc1c(-c2csc(-c3ccccn3)n2)cc(C)cc1-c1csc(-c2ccccn2)n1. Metal clusters: 36 [Ag]. The MOF has largest included sphere 7.63 A, density 1.34 g/cm3, surface area 4366.40 m2/g, accessible volume 0.32 cm3/g