ZnC8H4O4(CH)4C2O is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixty-four 02329_fluka molecules, sixteen dimethyl ether molecules, and eight ZnC8H4O4 clusters. In four of the ZnC8H4O4 clusters, Zn(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-O(1) bond length is 2.06 Å. The Zn(1)-O(2) bond length is 2.04 Å. The Zn(1)-O(3) bond length is 2.05 Å. The Zn(1)-O(4) bond length is 2.04 Å. There are eight inequivalent C sites. In the first C site, C(19) is bonded in a trigonal planar geometry to one C(10), one C(23), and one C(8) atom. The C(19)-C(10) bond length is 1.39 Å. The C(19)-C(23) bond length is 1.49 Å. The C(19)-C(8) bond length is 1.30 Å. In the second C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(2), and one O(4) atom. The C(23)-O(2) bond length is 1.29 Å. The C(23)-O(4) bond length is 1.15 Å. In the third C site, C(24) is bonded in a distorted single-bond geometry to one C(15) and one H(14) atom. The C(24)-C(15) bond length is 1.38 Å. The C(24)-H(14) bond length is 0.93 Å. In the fourth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(1), and one O(3) atom. The C(27)-C(15) bond length is 1.52 Å. The C(27)-O(1) bond length is 1.27 Å. The C(27)-O(3) bond length is 1.13 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(15) and one H(4) atom. The C(7)-C(15) bond length is 1.34 Å. The C(7)-H(4) bond length is 0.93 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(19) and one H(5) atom. The C(8)-H(5) bond length is 0.93 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(19) and one H(7) atom. The C(10)-H(7) bond length is 0.93 Å. In the eighth C site, C(15) is bonded in a trigonal planar geometry to one C(24), one C(27), and one C(7) atom. There are four inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(27) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(23) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(27) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Zn(1) and one C(23) atom. In four of the ZnC8H4O4 clusters, Zn(2) is bonded in a distorted rectangular see-saw-like geometry to one O(10), one O(7), one O(8), and one O(9) atom. The Zn(2)-O(10) bond length is 2.10 Å. The Zn(2)-O(7) bond length is 2.02 Å. The Zn(2)-O(8) bond length is 1.94 Å. The Zn(2)-O(9) bond length is 1.97 Å. There are eight inequivalent C sites. In the first C site, C(20) is bonded in a bent 120 degrees geometry to one C(2), one O(7), and one O(8) atom. The C(20)-C(2) bond length is 1.43 Å. The C(20)-O(7) bond length is 1.20 Å. The C(20)-O(8) bond length is 1.39 Å. In the second C site, C(28) is bonded in a bent 120 degrees geometry to one C(4), one O(10), and one O(9) atom. The C(28)-C(4) bond length is 1.46 Å. The C(28)-O(10) bond length is 1.36 Å. The C(28)-O(9) bond length is 1.20 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(14), one C(20), and one C(9) atom. The C(2)-C(14) bond length is 1.44 Å. The C(2)-C(9) bond length is 1.42 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(13), one C(16), and one C(28) atom. The C(4)-C(13) bond length is 1.33 Å. The C(4)-C(16) bond length is 1.40 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(2) and one H(6) atom. The C(9)-H(6) bond length is 0.93 Å. In the sixth C site, C(13) is bonded in a distorted single-bond geometry to one C(4) and one H(10) atom. The C(13)-H(10) bond length is 0.93 Å. In the seventh C site, C(14) is bonded in a distorted single-bond geometry to one C(2) and one H(11) atom. The C(14)-H(11) bond length is 0.93 Å. In the eighth C site, C(16) is bonded in a distorted single-bond geometry to one C(4) and one H(12) atom. The C(16)-H(12) bond length is 0.93 Å. There are four inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(9) is bonded in a single-bond geometry to one Zn(2) and one C(28) atom. In the second O site, O(7) is bonded in a distorted single-bond geometry to one Zn(2) and one C(20) atom. In the third O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(20) atom. In the fourth O site, O(10) is bonded in a 2-coordinate geometry to one Zn(2) and one C(28) atom. Linkers: 8 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: pts. The MOF has largest included sphere 8.18 A, density 0.94 g/cm3, surface area 4130.00 m2/g, accessible volume 0.55 cm3/g