Zn2H19(C7O3)4(CH)5 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of forty 02329_fluka molecules and eight Zn2H19(C7O3)4 clusters. In each Zn2H19(C7O3)4 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a 5-coordinate geometry to one O(1), one O(10), one O(2), one O(4), and one O(7) atom. The Zn(1)-O(1) bond length is 1.98 Å. The Zn(1)-O(10) bond length is 2.03 Å. The Zn(1)-O(2) bond length is 1.96 Å. The Zn(1)-O(4) bond length is 1.97 Å. The Zn(1)-O(7) bond length is 2.30 Å. In the second Zn site, Zn(2) is bonded in a trigonal non-coplanar geometry to one O(11), one O(5), and one O(9) atom. The Zn(2)-O(11) bond length is 1.92 Å. The Zn(2)-O(5) bond length is 1.95 Å. The Zn(2)-O(9) bond length is 1.92 Å. There are twenty-eight inequivalent C sites. In the first C site, C(14) is bonded in a distorted single-bond geometry to one O(3) atom. The C(14)-O(3) bond length is 1.37 Å. In the second C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(9); two equivalent H(5,6); and one O(12) atom. The C(8)-C(9) bond length is 1.53 Å. Both C(8)-H(5,6) bond lengths are 0.99 Å. The C(8)-O(12) bond length is 1.43 Å. In the third C site, C(9) is bonded in a tetrahedral geometry to one C(30), one C(31), one C(32), and one C(8) atom. The C(9)-C(30) bond length is 1.52 Å. The C(9)-C(31) bond length is 1.54 Å. The C(9)-C(32) bond length is 1.53 Å. In the fourth C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(2), and one O(9) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(2) bond length is 1.27 Å. The C(1)-O(9) bond length is 1.26 Å. In the fifth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.38 Å. In the sixth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1,4) atom. The C(3)-H(1,4) bond length is 0.95 Å. In the seventh C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(9) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(9) bond length is 0.95 Å. In the eighth C site, C(5) is bonded in a single-bond geometry to one O(12) atom. The C(5)-O(12) bond length is 1.36 Å. In the ninth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(1,4) atom. The C(7)-H(1,4) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(1), and one O(11) atom. The C(10)-C(11) bond length is 1.48 Å. The C(10)-O(1) bond length is 1.25 Å. The C(10)-O(11) bond length is 1.28 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(16) atom. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(16) bond length is 1.39 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 0.95 Å. In the thirteenth C site, C(17) is bonded in a bent 120 degrees geometry to one C(18), one O(10), and one O(7) atom. The C(17)-C(18) bond length is 1.54 Å. The C(17)-O(10) bond length is 1.24 Å. The C(17)-O(7) bond length is 1.24 Å. In the fourteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(23) atom. The C(18)-C(19) bond length is 1.37 Å. The C(18)-C(23) bond length is 1.36 Å. In the fifteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(11) atom. The C(19)-C(20) bond length is 1.41 Å. The C(19)-H(11) bond length is 0.95 Å. In the sixteenth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one H(12) atom. The C(20)-C(21) bond length is 1.37 Å. The C(20)-H(12) bond length is 0.95 Å. In the seventeenth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one O(6) atom. The C(21)-O(6) bond length is 1.40 Å. In the eighteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(14) atom. The C(23)-H(14) bond length is 0.95 Å. In the nineteenth C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(33), one O(4), and one O(5) atom. The C(24)-C(33) bond length is 1.49 Å. The C(24)-O(4) bond length is 1.26 Å. The C(24)-O(5) bond length is 1.26 Å. In the twentieth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one C(33), and one H(15) atom. The C(25)-C(26) bond length is 1.38 Å. The C(25)-C(33) bond length is 1.40 Å. The C(25)-H(15) bond length is 0.95 Å. In the twenty-first C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(16) atom. The C(26)-H(16) bond length is 0.95 Å. In the twenty-second C site, C(27) is bonded in a distorted single-bond geometry to one O(8) atom. The C(27)-O(8) bond length is 1.36 Å. In the twenty-third C site, C(29) is bonded in a distorted single-bond geometry to one C(33) and one H(18) atom. The C(29)-C(33) bond length is 1.38 Å. The C(29)-H(18) bond length is 0.95 Å. In the twenty-fourth C site, C(30) is bonded in a distorted trigonal non-coplanar geometry to one C(9), one H(19), one H(20), and one O(8) atom. The C(30)-H(19) bond length is 0.99 Å. The C(30)-H(20) bond length is 0.99 Å. The C(30)-O(8) bond length is 1.45 Å. In the twenty-fifth C site, C(31) is bonded in a distorted trigonal non-coplanar geometry to one C(9); two equivalent H(21,22); and one O(6) atom. Both C(31)-H(21,22) bond lengths are 0.99 Å. The C(31)-O(6) bond length is 1.44 Å. In the twenty-sixth C site, C(32) is bonded in a distorted trigonal non-coplanar geometry to one C(9); two equivalent H(23,24); and one O(3) atom. Both C(32)-H(23,24) bond lengths are 0.99 Å. The C(32)-O(3) bond length is 1.43 Å. In the twenty-seventh C site, C(33) is bonded in a trigonal planar geometry to one C(24), one C(25), and one C(29) atom. In the twenty-eighth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(11), one C(15), and one H(10) atom. The C(16)-H(10) bond length is 0.95 Å. There are fifteen inequivalent H sites. In the first H site, H(1,4) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(5,6) is bonded in a single-bond geometry to one C(8) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(14) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(30) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(30) atom. In the fourteenth H site, H(21,22) is bonded in a single-bond geometry to one C(31) atom. In the fifteenth H site, H(23,24) is bonded in a single-bond geometry to one C(32) atom. There are twelve inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(24) atom. In the second O site, O(4) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(24) atom. In the third O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(10) atom. In the fourth O site, O(3) is bonded in a bent 120 degrees geometry to one C(14) and one C(32) atom. In the fifth O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one C(21) and one C(31) atom. In the seventh O site, O(8) is bonded in a bent 120 degrees geometry to one C(27) and one C(30) atom. In the eighth O site, O(9) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(1) atom. In the ninth O site, O(12) is bonded in a bent 120 degrees geometry to one C(5) and one C(8) atom. In the tenth O site, O(7) is bonded in a distorted single-bond geometry to one Zn(1) and one C(17) atom. In the eleventh O site, O(10) is bonded in an L-shaped geometry to one Zn(1) and one C(17) atom. In the twelfth O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(10) atom. Linkers: 4 [O]C(=O)c1ccc(OCC(COc2ccc(C([O])=O)cc2)(COc2ccc(C([O])=O)cc2)COc2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 [C]1O[Zn]2O[C]O[Zn]3(O1)(O[C]O2)O[C]O3. RCSR code: neb. The MOF has largest included sphere 8.03 A, density 0.89 g/cm3, surface area 4557.82 m2/g, accessible volume 0.66 cm3/g