Cu(OOCC6H4COO)(CH)4C2O is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixty-four 02329_fluka molecules, sixteen dimethyl ether molecules, and eight Cu(OOCC6H4COO) clusters. In four of the Cu(OOCC6H4COO) clusters, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(10), one O(2), and one O(6) atom. The Cu(1)-O(1) bond length is 1.96 Å. The Cu(1)-O(10) bond length is 1.96 Å. The Cu(1)-O(2) bond length is 1.96 Å. The Cu(1)-O(6) bond length is 1.96 Å. There are eight inequivalent C sites. In the first C site, C(20) is bonded in a distorted single-bond geometry to one C(15) and one H(12) atom. The C(20)-C(15) bond length is 1.38 Å. The C(20)-H(12) bond length is 0.95 Å. In the second C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(10), and one O(6) atom. The C(28)-C(15) bond length is 1.49 Å. The C(28)-O(10) bond length is 1.26 Å. The C(28)-O(6) bond length is 1.27 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.25 Å. In the fourth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.39 Å. In the fifth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.95 Å. In the seventh C site, C(15) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(28) atom. The C(15)-C(16) bond length is 1.40 Å. In the eighth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(9) atom. The C(16)-H(9) bond length is 0.95 Å. There are four inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted single-bond geometry to one Cu(1) and one C(1) atom. In the second O site, O(6) is bonded in a distorted single-bond geometry to one Cu(1) and one C(28) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the fourth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(28) atom. In four of the Cu(OOCC6H4COO) clusters, Cu(2) is bonded in a rectangular see-saw-like geometry to one O(4), one O(5), one O(8), and one O(9) atom. The Cu(2)-O(4) bond length is 1.97 Å. The Cu(2)-O(5) bond length is 1.97 Å. The Cu(2)-O(8) bond length is 1.96 Å. The Cu(2)-O(9) bond length is 1.96 Å. There are eight inequivalent C sites. In the first C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(14) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-H(14) bond length is 0.95 Å. In the second C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(27) atom. The C(24)-C(25) bond length is 1.36 Å. The C(24)-C(27) bond length is 1.49 Å. In the third C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(15) atom. The C(25)-H(15) bond length is 0.95 Å. In the fourth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(8), and one O(9) atom. The C(27)-O(8) bond length is 1.26 Å. The C(27)-O(9) bond length is 1.26 Å. In the fifth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(6) bond length is 0.95 Å. In the sixth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-C(14) bond length is 1.52 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 0.95 Å. In the eighth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(4), and one O(5) atom. The C(14)-O(4) bond length is 1.25 Å. The C(14)-O(5) bond length is 1.27 Å. There are four inequivalent H sites. In the first H site, H(14) is bonded in a single-bond geometry to one C(23) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(14) atom. In the second O site, O(5) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(14) atom. In the third O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(27) atom. In the fourth O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(27) atom. Linkers: 8 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1. Metal clusters: 4 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: lvt. The MOF has largest included sphere 7.51 A, density 0.99 g/cm3, surface area 4076.03 m2/g, accessible volume 0.55 cm3/g