AgH12(C3N)6 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen AgH12(C3N)6 clusters. Ag(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one N(9) atom. The Ag(1)-N(1) bond length is 2.26 Å. The Ag(1)-N(2) bond length is 2.30 Å. The Ag(1)-N(9) bond length is 2.29 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(5), one N(4), and one N(6) atom. The C(1)-C(5) bond length is 1.49 Å. The C(1)-N(4) bond length is 1.34 Å. The C(1)-N(6) bond length is 1.33 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1) atom. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(6), and one C(9) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(9) bond length is 1.38 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(25), one C(5), and one H(3) atom. The C(6)-C(25) bond length is 1.39 Å. The C(6)-H(3) bond length is 0.93 Å. In the fifth C site, C(9) is bonded in a distorted single-bond geometry to one C(20), one C(5), and one H(6) atom. The C(9)-C(20) bond length is 1.38 Å. The C(9)-H(6) bond length is 0.93 Å. In the sixth C site, C(11) is bonded in a trigonal planar geometry to one C(13), one C(34), and one C(35) atom. The C(11)-C(13) bond length is 1.49 Å. The C(11)-C(34) bond length is 1.39 Å. The C(11)-C(35) bond length is 1.38 Å. In the seventh C site, C(13) is bonded in a distorted trigonal planar geometry to one C(11), one N(5), and one N(6) atom. The C(13)-N(5) bond length is 1.34 Å. The C(13)-N(6) bond length is 1.34 Å. In the eighth C site, C(15) is bonded in a distorted single-bond geometry to one C(29) and one H(9) atom. The C(15)-C(29) bond length is 1.40 Å. The C(15)-H(9) bond length is 0.93 Å. In the ninth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(10) atom. The C(17)-N(9) bond length is 1.33 Å. The C(17)-H(10) bond length is 0.93 Å. In the tenth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(29), one N(4), and one N(5) atom. The C(18)-C(29) bond length is 1.49 Å. The C(18)-N(4) bond length is 1.34 Å. The C(18)-N(5) bond length is 1.34 Å. In the eleventh C site, C(20) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one H(11) atom. The C(20)-N(1) bond length is 1.34 Å. The C(20)-H(11) bond length is 0.93 Å. In the twelfth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(13) atom. The C(23)-N(2) bond length is 1.33 Å. The C(23)-H(13) bond length is 0.93 Å. In the thirteenth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one H(15) atom. The C(25)-N(1) bond length is 1.33 Å. The C(25)-H(15) bond length is 0.93 Å. In the fourteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(16) atom. The C(26)-N(9) bond length is 1.36 Å. The C(26)-H(16) bond length is 0.93 Å. In the fifteenth C site, C(29) is bonded in a trigonal planar geometry to one C(15), one C(18), and one C(33) atom. The C(29)-C(33) bond length is 1.39 Å. In the sixteenth C site, C(33) is bonded in a distorted single-bond geometry to one C(29) and one H(21) atom. The C(33)-H(21) bond length is 0.93 Å. In the seventeenth C site, C(34) is bonded in a distorted single-bond geometry to one C(11) and one H(22) atom. The C(34)-H(22) bond length is 0.93 Å. In the eighteenth C site, C(35) is bonded in a distorted single-bond geometry to one C(11) and one H(23) atom. The C(35)-H(23) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(20), and one C(25) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(2), and one C(23) atom. In the third N site, N(4) is bonded in a bent 120 degrees geometry to one C(1) and one C(18) atom. In the fourth N site, N(5) is bonded in a bent 120 degrees geometry to one C(13) and one C(18) atom. In the fifth N site, N(6) is bonded in a bent 120 degrees geometry to one C(1) and one C(13) atom. In the sixth N site, N(9) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(17), and one C(26) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(13) is bonded in a single-bond geometry to one C(23) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(21) is bonded in a single-bond geometry to one C(33) atom. In the eleventh H site, H(22) is bonded in a single-bond geometry to one C(34) atom. In the twelfth H site, H(23) is bonded in a single-bond geometry to one C(35) atom. Linkers: 16 n1ccc(cc1)C1=NC(=[N]=C([N]1)c1ccncc1)c1ccncc1. Metal clusters: 16 [Ag]. The MOF has largest included sphere 7.03 A, density 1.33 g/cm3, surface area 3954.06 m2/g, accessible volume 0.38 cm3/g