Ag2H18(C7S2)3(CH)18 crystallizes in the cubic P4_332 space group. The structure consists of seventy-two 02329_fluka molecules inside a Ag2H18(C7S2)3 framework. In the Ag2H18(C7S2)3 framework, Ag(1) is bonded in a trigonal non-coplanar geometry to three equivalent S(1) atoms. All Ag(1)-S(1) bond lengths are 2.55 Å. There are four inequivalent C sites. In the first C site, C(7) is bonded in a water-like geometry to two equivalent H(6) and two equivalent S(1) atoms. Both C(7)-H(6) bond lengths are 0.96 Å. Both C(7)-S(1) bond lengths are 1.80 Å. In the second C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-S(1) bond length is 1.75 Å. In the third C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1,5) atom. The C(2)-H(1,5) bond length is 0.93 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(1,5) atom. The C(6)-H(1,5) bond length is 0.93 Å. There are two inequivalent H sites. In the first H site, H(1,5) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(7) atom. S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(1), and one C(7) atom. Linkers: 12 c1ccc(SCSc2ccccc2)cc1. Metal clusters: 8 [Ag]. The MOF has largest included sphere 5.34 A, density 1.16 g/cm3, surface area 4879.56 m2/g, accessible volume 0.43 cm3/g