InH24(C9O4)2(CH2)2 is Indium-derived structured and crystallizes in the trigonal P3_121 space group. The structure is zero-dimensional and consists of six 02329_fluka molecules and three InH24(C9O4)2 clusters. In each InH24(C9O4)2 cluster, In(1) is bonded in a 8-coordinate geometry to two equivalent O(1), two equivalent O(2), two equivalent O(3), and two equivalent O(4) atoms. Both In(1)-O(1) bond lengths are 2.24 Å. Both In(1)-O(2) bond lengths are 2.32 Å. Both In(1)-O(3) bond lengths are 2.34 Å. Both In(1)-O(4) bond lengths are 2.24 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one C(2), one C(5), one C(6), and one C(9) atom. The C(1)-C(2) bond length is 1.56 Å. The C(1)-C(5) bond length is 1.54 Å. The C(1)-C(6) bond length is 1.51 Å. The C(1)-C(9) bond length is 1.53 Å. In the second C site, C(2) is bonded in a tetrahedral geometry to one C(1), one C(3), one C(7), and one C(8) atom. The C(2)-C(3) bond length is 1.55 Å. The C(2)-C(7) bond length is 1.61 Å. The C(2)-C(8) bond length is 1.51 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.98 Å. In the fourth C site, C(5) is bonded in a water-like geometry to one C(1) and two equivalent H(4,5) atoms. Both C(5)-H(4,5) bond lengths are 0.97 Å. In the fifth C site, C(6) is bonded in a trigonal non-coplanar geometry to one C(1); one H(8); and two equivalent H(6,7) atoms. The C(6)-H(8) bond length is 0.96 Å. Both C(6)-H(6,7) bond lengths are 0.96 Å. In the sixth C site, C(7) is bonded in a trigonal non-coplanar geometry to one C(2); one H(9); and two equivalent H(10,11) atoms. The C(7)-H(9) bond length is 0.96 Å. Both C(7)-H(10,11) bond lengths are 0.96 Å. In the seventh C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(2) and three equivalent H(12,13,14) atoms. All C(8)-H(12,13,14) bond lengths are 0.96 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(9)-O(1) bond length is 1.27 Å. The C(9)-O(2) bond length is 1.25 Å. In the ninth C site, C(10) is bonded in a bent 120 degrees geometry to one O(3) and one O(4) atom. The C(10)-O(3) bond length is 1.26 Å. The C(10)-O(4) bond length is 1.24 Å. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4,5) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(6,7) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the sixth H site, H(10,11) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(12,13,14) is bonded in a single-bond geometry to one C(8) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted L-shaped geometry to one In(1) and one C(9) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one In(1) and one C(9) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one In(1) and one C(10) atom. In the fourth O site, O(4) is bonded in a distorted L-shaped geometry to one In(1) and one C(10) atom. Linkers: 6 CC1(C)[C@@H](C([O])=O)CC[C@@]1(C)C([O])=O. Metal clusters: 3 O=[C]O[In](O[C]=O)O[C]=O.[O][C]=O. RCSR code: qtz. The MOF has largest included sphere 6.89 A, density 1.03 g/cm3, surface area 4425.74 m2/g, accessible volume 0.53 cm3/g