CdC10H10(NO2)2 is Indium-like structured and crystallizes in the tetragonal I-42d space group. The structure is zero-dimensional and consists of four CdC10H10(NO2)2 clusters. Cd(1) is bonded in a square pyramidal geometry to one N(1), one N(2), one O(1), one O(2), and one O(3) atom. The Cd(1)-N(1) bond length is 2.39 Å. The Cd(1)-N(2) bond length is 2.30 Å. The Cd(1)-O(1) bond length is 2.24 Å. The Cd(1)-O(2) bond length is 2.34 Å. The Cd(1)-O(3) bond length is 2.27 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a 4-coordinate geometry to one C(2); one N(1); and two equivalent H(1,2) atoms. The C(1)-C(2) bond length is 1.50 Å. The C(1)-N(1) bond length is 1.53 Å. Both C(1)-H(1,2) bond lengths are 0.99 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(2)-O(1) bond length is 1.24 Å. The C(2)-O(2) bond length is 1.20 Å. In the third C site, C(3) is bonded in a distorted trigonal non-coplanar geometry to one N(1), one H(3), and one H(4) atom. The C(3)-N(1) bond length is 1.43 Å. The C(3)-H(3) bond length is 0.99 Å. The C(3)-H(4) bond length is 0.99 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(4)-O(3) bond length is 1.23 Å. The C(4)-O(4) bond length is 1.27 Å. In the fifth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one C(8); one N(1); and two equivalent H(5,6) atoms. The C(5)-C(8) bond length is 1.52 Å. The C(5)-N(1) bond length is 1.46 Å. Both C(5)-H(5,6) bond lengths are 0.99 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(6)-N(2) bond length is 1.33 Å. The C(6)-H(7) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(7)-C(8) bond length is 1.37 Å. The C(7)-H(8) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(5), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.35 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(9) atom. The C(9)-H(9) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(10)-N(2) bond length is 1.32 Å. The C(10)-H(10) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted tetrahedral geometry to one Cd(1), one C(1), one C(3), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(6) atom. There are eight inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(2) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cd(1) and one C(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(4) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(4) atom. Linkers: 8 [O]C(=O)CN(CC([O])=O)Cc1ccncc1. Metal clusters: 8 [Cd]. The MOF has largest included sphere 6.19 A, density 1.47 g/cm3, surface area 3811.87 m2/g, accessible volume 0.34 cm3/g