FeC18H12(N2O)2(CH)6 is Indium-derived structured and crystallizes in the tetragonal I-42d space group. The structure is zero-dimensional and consists of ninety-six 02329_fluka molecules and sixteen FeC18H12(N2O)2 clusters. In eight of the FeC18H12(N2O)2 clusters, Fe(1) is bonded in an octahedral geometry to two equivalent N(2), two equivalent N(3), and two equivalent O(2) atoms. Both Fe(1)-N(2) bond lengths are 2.22 Å. Both Fe(1)-N(3) bond lengths are 2.23 Å. Both Fe(1)-O(2) bond lengths are 2.02 Å. There are nine inequivalent C sites. In the first C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(7) atom. The C(10)-N(2) bond length is 1.33 Å. The C(10)-H(7) bond length is 0.95 Å. In the second C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(8) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(8) bond length is 0.95 Å. In the third C site, C(13) is bonded in a distorted single-bond geometry to one C(18) and one O(2) atom. The C(13)-C(18) bond length is 1.42 Å. The C(13)-O(2) bond length is 1.31 Å. In the fourth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(13) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-H(13) bond length is 0.95 Å. In the fifth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(13), one C(17), and one N(3) atom. The C(18)-N(3) bond length is 1.42 Å. In the sixth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(3), and one H(14) atom. The C(19)-C(20) bond length is 1.46 Å. The C(19)-N(3) bond length is 1.30 Å. The C(19)-H(14) bond length is 0.95 Å. In the seventh C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(24) atom. The C(20)-C(21) bond length is 1.40 Å. The C(20)-C(24) bond length is 1.38 Å. In the eighth C site, C(21) is bonded in a distorted single-bond geometry to one C(20) and one H(15) atom. The C(21)-H(15) bond length is 0.95 Å. In the ninth C site, C(24) is bonded in a distorted single-bond geometry to one C(20) and one H(18) atom. The C(24)-H(18) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Fe(1), one C(10), and one C(11) atom. In the second N site, N(3) is bonded in a distorted trigonal planar geometry to one Fe(1), one C(18), and one C(19) atom. There are six inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(19) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(24) atom. O(2) is bonded in a bent 120 degrees geometry to one Fe(1) and one C(13) atom. In eight of the FeC18H12(N2O)2 clusters, Fe(2) is bonded in a distorted octahedral geometry to two equivalent N(1), two equivalent N(4), and two equivalent O(1) atoms. Both Fe(2)-N(1) bond lengths are 2.34 Å. Both Fe(2)-N(4) bond lengths are 2.21 Å. Both Fe(2)-O(1) bond lengths are 2.03 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one C(6) and one O(1) atom. The C(1)-C(6) bond length is 1.42 Å. The C(1)-O(1) bond length is 1.32 Å. In the second C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.37 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(6) is bonded in a distorted trigonal planar geometry to one C(1), one C(5), and one N(1) atom. The C(6)-N(1) bond length is 1.42 Å. In the fourth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(1), and one H(5) atom. The C(7)-C(8) bond length is 1.46 Å. The C(7)-N(1) bond length is 1.29 Å. The C(7)-H(5) bond length is 0.95 Å. In the fifth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.39 Å. The C(8)-C(9) bond length is 1.41 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(9)-H(6) bond length is 0.95 Å. In the seventh C site, C(12) is bonded in a distorted single-bond geometry to one C(8) and one H(9) atom. The C(12)-H(9) bond length is 0.95 Å. In the eighth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(16) atom. The C(22)-N(4) bond length is 1.32 Å. The C(22)-H(16) bond length is 0.95 Å. In the ninth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(17) atom. The C(23)-N(4) bond length is 1.34 Å. The C(23)-H(17) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Fe(2), one C(6), and one C(7) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Fe(2), one C(22), and one C(23) atom. There are six inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. O(1) is bonded in a bent 120 degrees geometry to one Fe(2) and one C(1) atom. Linkers: 16 [O]c1ccccc1/N=C/c1ccncc1. Metal clusters: 8 [Fe]. The MOF has largest included sphere 5.60 A, density 1.15 g/cm3, surface area 4590.44 m2/g, accessible volume 0.36 cm3/g