Zn3C36H12O13(CH)12 crystallizes in the trigonal P-31c space group. The structure consists of twenty-four 02329_fluka molecules inside a Zn3C36H12O13 framework. In the Zn3C36H12O13 framework, Zn(1) is bonded to one O(3), two equivalent O(1), and two equivalent O(2) atoms to form corner-sharing ZnO5 square pyramids. The Zn(1)-O(3) bond length is 2.00 Å. Both Zn(1)-O(1) bond lengths are 2.08 Å. Both Zn(1)-O(2) bond lengths are 2.07 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. The C(2)-C(3) bond length is 1.41 Å. The C(2)-C(4) bond length is 1.40 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.44 Å. The C(3)-C(8) bond length is 1.42 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(5) atom. The C(4)-C(5) bond length is 1.43 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(1) atom. The C(5)-H(1) bond length is 0.95 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(3) and one H(4) atom. The C(8)-H(4) bond length is 0.95 Å. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(8) atom. There are three inequivalent O sites. In the first O site, O(3) is bonded in a trigonal planar geometry to three equivalent Zn(1) atoms. In the second O site, O(1) is bonded in a distorted single-bond geometry to one Zn(1) and one C(1) atom. In the third O site, O(2) is bonded in a distorted single-bond geometry to one Zn(1) and one C(1) atom. Linkers: 6 [O]C(=O)c1c2ccccc2c(C([O])=O)c2ccccc12. Metal clusters: 2 [C]1O[Zn]23O[C]O[Zn]45(O1)O[C]O[Zn](O[C]O2)(O[C]O3)(O[C]O4)O5. RCSR code: acs. The MOF has largest included sphere 10.70 A, density 0.96 g/cm3, surface area 4154.43 m2/g, accessible volume 0.52 cm3/g