Mn5C58H40(N2O11)2(C3H2)20(CH)4(C7NH4)2(C9H6N)2(H3(C2O)2)2 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of four 02329_fluka molecules; ten 2,3-dimethyl-1,3-butadiene molecules; two methacrylic acid molecules; two schembl1705614 molecules; two schembl5425382 molecules; and one Mn5C58H40(N2O11)2 cluster. In the Mn5C58H40(N2O11)2 cluster, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded to one O(1), one O(2), one O(4), one O(5), one O(8), and one O(9) atom to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles are 69°. The Mn(1)-O(1) bond length is 2.28 Å. The Mn(1)-O(2) bond length is 2.14 Å. The Mn(1)-O(4) bond length is 2.08 Å. The Mn(1)-O(5) bond length is 2.46 Å. The Mn(1)-O(8) bond length is 2.09 Å. The Mn(1)-O(9) bond length is 2.08 Å. In the second Mn site, Mn(2) is bonded in a distorted trigonal non-coplanar geometry to one O(13), one O(5), and one O(7) atom. The Mn(2)-O(13) bond length is 2.15 Å. The Mn(2)-O(5) bond length is 2.21 Å. The Mn(2)-O(7) bond length is 2.10 Å. In the third Mn site, Mn(3) is bonded to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms to form corner-sharing MnO6 octahedra. The corner-sharing octahedral tilt angles are 69°. Both Mn(3)-O(1) bond lengths are 2.24 Å. Both Mn(3)-O(3) bond lengths are 2.18 Å. Both Mn(3)-O(6) bond lengths are 2.10 Å. There are twenty-nine inequivalent C sites. In the first C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(2), and one O(7) atom. The C(16)-C(11) bond length is 1.50 Å. The C(16)-O(2) bond length is 1.24 Å. The C(16)-O(7) bond length is 1.27 Å. In the second C site, C(17) is bonded in a single-bond geometry to one C(20) and one H(5) atom. The C(17)-C(20) bond length is 1.37 Å. The C(17)-H(5) bond length is 0.93 Å. In the third C site, C(18) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(27) atom. The C(18)-C(10) bond length is 1.48 Å. The C(18)-C(12) bond length is 1.38 Å. The C(18)-C(27) bond length is 1.39 Å. In the fourth C site, C(20) is bonded in a trigonal planar geometry to one C(17), one C(26), and one C(42) atom. The C(20)-C(26) bond length is 1.39 Å. The C(20)-C(42) bond length is 1.51 Å. In the fifth C site, C(22) is bonded in a distorted single-bond geometry to one C(10) and one H(6) atom. The C(22)-C(10) bond length is 1.38 Å. The C(22)-H(6) bond length is 0.93 Å. In the sixth C site, C(23) is bonded in a distorted single-bond geometry to one C(3) and one H(7,12,13) atom. The C(23)-C(3) bond length is 1.38 Å. The C(23)-H(7,12,13) bond length is 0.93 Å. In the seventh C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(48), one O(6), and one O(8) atom. The C(24)-C(48) bond length is 1.50 Å. The C(24)-O(6) bond length is 1.25 Å. The C(24)-O(8) bond length is 1.25 Å. In the eighth C site, C(26) is bonded in a distorted single-bond geometry to one C(20) and one H(8) atom. The C(26)-H(8) bond length is 0.93 Å. In the ninth C site, C(27) is bonded in a distorted single-bond geometry to one C(18), one C(7), and one H(9) atom. The C(27)-C(7) bond length is 1.37 Å. The C(27)-H(9) bond length is 0.93 Å. In the tenth C site, C(30) is bonded in a distorted single-bond geometry to one C(10) and one H(10) atom. The C(30)-C(10) bond length is 1.39 Å. The C(30)-H(10) bond length is 0.93 Å. In the eleventh C site, C(34) is bonded in a trigonal planar geometry to one N(1), one N(2), and one O(1) atom. The C(34)-N(1) bond length is 1.32 Å. The C(34)-N(2) bond length is 1.32 Å. The C(34)-O(1) bond length is 1.26 Å. In the twelfth C site, C(37) is bonded in a distorted single-bond geometry to one C(2) and one H(14) atom. The C(37)-C(2) bond length is 1.36 Å. The C(37)-H(14) bond length is 0.93 Å. In the thirteenth C site, C(38) is bonded in a single-bond geometry to one C(11) and one H(15) atom. The C(38)-C(11) bond length is 1.37 Å. The C(38)-H(15) bond length is 0.93 Å. In the fourteenth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one C(20), one O(10), and one O(5) atom. The C(42)-O(10) bond length is 1.25 Å. The C(42)-O(5) bond length is 1.27 Å. In the fifteenth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(13), and one O(9) atom. The C(46)-C(2) bond length is 1.50 Å. The C(46)-O(13) bond length is 1.24 Å. The C(46)-O(9) bond length is 1.24 Å. In the sixteenth C site, C(48) is bonded in a trigonal planar geometry to one C(24), one C(57), and one C(73) atom. The C(48)-C(57) bond length is 1.38 Å. The C(48)-C(73) bond length is 1.35 Å. In the seventeenth C site, C(57) is bonded in a single-bond geometry to one C(48) and one H(28) atom. The C(57)-H(28) bond length is 0.93 Å. In the eighteenth C site, C(71) is bonded in a distorted single-bond geometry to one C(11) and one H(41) atom. The C(71)-C(11) bond length is 1.37 Å. The C(71)-H(41) bond length is 0.93 Å. In the nineteenth C site, C(73) is bonded in a distorted single-bond geometry to one C(48) and one H(43) atom. The C(73)-H(43) bond length is 0.93 Å. In the twentieth C site, C(76) is bonded in a distorted single-bond geometry to one C(2) and one H(46) atom. The C(76)-C(2) bond length is 1.36 Å. The C(76)-H(46) bond length is 0.93 Å. In the twenty-first C site, C(78) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent H(48,49) atoms. The C(78)-N(1) bond length is 1.44 Å. Both C(78)-H(48,49) bond lengths are 0.97 Å. In the twenty-second C site, C(80) is bonded in a distorted trigonal non-coplanar geometry to one N(2) and two equivalent H(51,52) atoms. The C(80)-N(2) bond length is 1.42 Å. Both C(80)-H(51,52) bond lengths are 0.97 Å. In the twenty-third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(4) atom. The C(1)-C(3) bond length is 1.50 Å. The C(1)-O(3) bond length is 1.24 Å. The C(1)-O(4) bond length is 1.26 Å. In the twenty-fourth C site, C(2) is bonded in a trigonal planar geometry to one C(37), one C(46), and one C(76) atom. In the twenty-fifth C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(23), and one C(7) atom. The C(3)-C(7) bond length is 1.37 Å. In the twenty-sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(27), one C(3), and one H(2) atom. The C(7)-H(2) bond length is 0.93 Å. In the twenty-seventh C site, C(10) is bonded in a trigonal planar geometry to one C(18), one C(22), and one C(30) atom. In the twenty-eighth C site, C(11) is bonded in a trigonal planar geometry to one C(16), one C(38), and one C(71) atom. In the twenty-ninth C site, C(12) is bonded in a single-bond geometry to one C(18) and one H(3) atom. The C(12)-H(3) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(34), one C(78), and one H(54) atom. The N(1)-H(54) bond length is 0.86 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(34), one C(80), and one H(55) atom. The N(2)-H(55) bond length is 0.86 Å. There are eighteen inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(22) atom. In the fifth H site, H(7,12,13) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(26) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(27) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(30) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(37) atom. In the tenth H site, H(15) is bonded in a single-bond geometry to one C(38) atom. In the eleventh H site, H(28) is bonded in a single-bond geometry to one C(57) atom. In the twelfth H site, H(41) is bonded in a single-bond geometry to one C(71) atom. In the thirteenth H site, H(43) is bonded in a single-bond geometry to one C(73) atom. In the fourteenth H site, H(46) is bonded in a single-bond geometry to one C(76) atom. In the fifteenth H site, H(48,49) is bonded in a single-bond geometry to one C(78) atom. In the sixteenth H site, H(51,52) is bonded in a single-bond geometry to one C(80) atom. In the seventeenth H site, H(54) is bonded in a single-bond geometry to one N(1) atom. In the eighteenth H site, H(55) is bonded in a single-bond geometry to one N(2) atom. There are eleven inequivalent O sites. In the first O site, O(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one Mn(3), and one C(34) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(16) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Mn(3) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(1) atom. In the fifth O site, O(5) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(2), and one C(42) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Mn(3) and one C(24) atom. In the seventh O site, O(7) is bonded in a 2-coordinate geometry to one Mn(2) and one C(16) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(24) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(46) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(42) atom. In the eleventh O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(46) atom. Linkers: 2 [O]C(=O)c1ccc(-c2ccc(N(c3ccc(-c4ccc(C([O])=O)cc4)cc3)c3ccc(-c4ccc(C([O])=O)cc4)cc3)cc2)cc1 ,2 [O]C(=O)c1ccc(-c2ccc(N(c3ccc(-c4ccc(C([O])=O)cc4)cc3)c3ccc(-c4ccc(C(=O)O)cc4)cc3)cc2)cc1 ,2 [CH]C(=[CH])c1ccc(N(c2ccc(-c3ccc(C([O])=O)cc3)cc2)c2ccc(-c3ccc(C([O])=O)cc3)cc2)cc1 ,2 [O]C(=O)c1ccc(-c2ccc(N(c3ccc(-c4c[c]c([C]=O)cc4)cc3)c3ccc(-c4ccc(C(=O)O)cc4)cc3)cc2)cc1. Metal clusters: 5 [Mn]. The MOF has largest included sphere 8.10 A, density 1.05 g/cm3, surface area 4808.12 m2/g, accessible volume 0.35 cm3/g