NiC32N3H20O4C2NH2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four n-methyl methanimine molecules and four NiC32N3H20O4 clusters. In each NiC32N3H20O4 cluster, Ni(1) is bonded in an octahedral geometry to one N(1), one N(2), one N(3), one O(1), one O(2), and one O(4) atom. The Ni(1)-N(1) bond length is 2.09 Å. The Ni(1)-N(2) bond length is 2.04 Å. The Ni(1)-N(3) bond length is 2.14 Å. The Ni(1)-O(1) bond length is 2.12 Å. The Ni(1)-O(2) bond length is 2.15 Å. The Ni(1)-O(4) bond length is 2.03 Å. There are thirty-two inequivalent C sites. In the first C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(19) atom. The C(31)-C(30) bond length is 1.38 Å. The C(31)-H(19) bond length is 0.93 Å. In the second C site, C(29) is bonded in a distorted single-bond geometry to one C(25) and one H(18) atom. The C(29)-C(25) bond length is 1.39 Å. The C(29)-H(18) bond length is 0.93 Å. In the third C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.26 Å. In the fourth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(12), and one C(3) atom. The C(2)-C(12) bond length is 1.38 Å. The C(2)-C(3) bond length is 1.38 Å. In the fifth C site, C(3) is bonded in a single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(1) bond length is 0.93 Å. In the sixth C site, C(4) is bonded in a trigonal planar geometry to one C(10), one C(3), and one C(5) atom. The C(4)-C(10) bond length is 1.38 Å. The C(4)-C(5) bond length is 1.48 Å. In the seventh C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(9) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(9) bond length is 1.39 Å. In the eighth C site, C(6) is bonded in a single-bond geometry to one C(5) and one H(2,5) atom. The C(6)-H(2,5) bond length is 0.93 Å. In the ninth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(3) atom. The C(7)-N(1) bond length is 1.33 Å. The C(7)-H(3) bond length is 0.93 Å. In the tenth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(8)-N(1) bond length is 1.34 Å. The C(8)-H(4) bond length is 0.93 Å. In the eleventh C site, C(9) is bonded in a single-bond geometry to one C(5) and one H(2,5) atom. The C(9)-H(2,5) bond length is 0.93 Å. In the twelfth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(13) atom. The C(11)-C(10) bond length is 1.39 Å. The C(11)-C(12) bond length is 1.40 Å. The C(11)-C(13) bond length is 1.48 Å. In the thirteenth C site, C(12) is bonded in a single-bond geometry to one C(11), one C(2), and one H(7) atom. The C(12)-H(7) bond length is 0.93 Å. In the fourteenth C site, C(10) is bonded in a single-bond geometry to one C(11), one C(4), and one H(6) atom. The C(10)-H(6) bond length is 0.93 Å. In the fifteenth C site, C(13) is bonded in a trigonal planar geometry to one C(11), one C(14), and one C(17) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-C(17) bond length is 1.39 Å. In the sixteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(15)-N(2) bond length is 1.34 Å. The C(15)-H(9) bond length is 0.93 Å. In the seventeenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(16)-N(2) bond length is 1.34 Å. The C(16)-H(10) bond length is 0.93 Å. In the eighteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(17)-H(11) bond length is 0.93 Å. In the nineteenth C site, C(14) is bonded in a single-bond geometry to one C(13) and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. In the twentieth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(3), and one O(4) atom. The C(18)-C(19) bond length is 1.51 Å. The C(18)-O(3) bond length is 1.24 Å. The C(18)-O(4) bond length is 1.28 Å. In the twenty-first C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-C(24) bond length is 1.39 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(21), one C(23), and one H(13) atom. The C(22)-C(21) bond length is 1.38 Å. The C(22)-C(23) bond length is 1.40 Å. The C(22)-H(13) bond length is 0.93 Å. In the twenty-third C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(12) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(12) bond length is 0.93 Å. In the twenty-fourth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(30) atom. The C(21)-C(30) bond length is 1.49 Å. In the twenty-fifth C site, C(24) is bonded in a distorted single-bond geometry to one C(19), one C(23), and one H(14) atom. The C(24)-C(23) bond length is 1.40 Å. The C(24)-H(14) bond length is 0.93 Å. In the twenty-sixth C site, C(27) is bonded in a 2-coordinate geometry to one N(3) and one H(16) atom. The C(27)-N(3) bond length is 1.33 Å. The C(27)-H(16) bond length is 0.93 Å. In the twenty-seventh C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(28)-N(3) bond length is 1.34 Å. The C(28)-H(17) bond length is 0.93 Å. In the twenty-eighth C site, C(23) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(25) atom. The C(23)-C(25) bond length is 1.48 Å. In the twenty-ninth C site, C(25) is bonded in a trigonal planar geometry to one C(23), one C(26), and one C(29) atom. The C(25)-C(26) bond length is 1.38 Å. In the thirtieth C site, C(26) is bonded in a single-bond geometry to one C(25) and one H(15) atom. The C(26)-H(15) bond length is 0.93 Å. In the thirty-first C site, C(34) is bonded in a distorted single-bond geometry to one C(30) and one H(22) atom. The C(34)-C(30) bond length is 1.37 Å. The C(34)-H(22) bond length is 0.93 Å. In the thirty-second C site, C(30) is bonded in a trigonal planar geometry to one C(21), one C(31), and one C(34) atom. There are three inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Ni(1), one C(15), and one C(16) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Ni(1), one C(27), and one C(28) atom. In the third N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(7), and one C(8) atom. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2,5) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(28) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(29) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(31) atom. In the nineteenth H site, H(22) is bonded in a single-bond geometry to one C(34) atom. There are four inequivalent O sites. In the first O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(18) atom. In the second O site, O(1) is bonded in an L-shaped geometry to one Ni(1) and one C(1) atom. In the third O site, O(2) is bonded in a distorted L-shaped geometry to one Ni(1) and one C(1) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one C(18) atom. Linkers: 8 [O]C(=O)c1cc(-c2ccncc2)cc(-c2ccncc2)c1. Metal clusters: 4 O=[C]O[Ni]1O[C]O1. The MOF has largest included sphere 4.12 A, density 1.25 g/cm3, surface area 4762.96 m2/g, accessible volume 0.34 cm3/g