LaC7P4H12(NO3)4(CH)5 crystallizes in the triclinic P-1 space group. The structure consists of forty 02329_fluka molecules inside a LaC7P4H12(NO3)4 framework. In the LaC7P4H12(NO3)4 framework, there are four inequivalent La sites. In the first La site, La(1) is bonded to one O(13), one O(14), one O(16), one O(17), one O(2), one O(38), and one O(40) atom to form distorted LaO7 pentagonal bipyramids that share  a cornercorner with one P(1)CO3 tetrahedra,  a cornercorner with one P(13)CO3 tetrahedra,  a cornercorner with one P(14)CO3 tetrahedra, corners with two equivalent P(5)CO3 tetrahedra, and corners with two equivalent P(6)CO3 tetrahedra. The La(1)-O(13) bond length is 2.56 Å. The La(1)-O(14) bond length is 2.54 Å. The La(1)-O(16) bond length is 2.42 Å. The La(1)-O(17) bond length is 2.48 Å. The La(1)-O(2) bond length is 2.59 Å. The La(1)-O(38) bond length is 2.50 Å. The La(1)-O(40) bond length is 2.53 Å. In the second La site, La(2) is bonded in a 7-coordinate geometry to one O(20), one O(21), one O(22), one O(24), one O(32), one O(34), and one O(39) atom. The La(2)-O(20) bond length is 2.52 Å. The La(2)-O(21) bond length is 2.60 Å. The La(2)-O(22) bond length is 2.47 Å. The La(2)-O(24) bond length is 2.40 Å. The La(2)-O(32) bond length is 2.51 Å. The La(2)-O(34) bond length is 2.52 Å. The La(2)-O(39) bond length is 2.59 Å. In the third La site, La(3) is bonded in a 7-coordinate geometry to one O(11), one O(12), one O(27), one O(3), one O(6), one O(7), and one O(9) atom. The La(3)-O(11) bond length is 2.43 Å. The La(3)-O(12) bond length is 2.48 Å. The La(3)-O(27) bond length is 2.59 Å. The La(3)-O(3) bond length is 2.51 Å. The La(3)-O(6) bond length is 2.50 Å. The La(3)-O(7) bond length is 2.63 Å. The La(3)-O(9) bond length is 2.47 Å. In the fourth La site, La(4) is bonded to one O(26), one O(28), one O(31), one O(36), one O(43), one O(45), and one O(46) atom to form distorted LaO7 pentagonal bipyramids that share  a cornercorner with one P(10)CO3 tetrahedra,  a cornercorner with one P(11)CO3 tetrahedra,  a cornercorner with one P(12)CO3 tetrahedra,  a cornercorner with one P(16)CO3 tetrahedra,  a cornercorner with one P(9)CO3 tetrahedra, and corners with two equivalent P(15)CO3 tetrahedra. The La(4)-O(26) bond length is 2.59 Å. The La(4)-O(28) bond length is 2.52 Å. The La(4)-O(31) bond length is 2.46 Å. The La(4)-O(36) bond length is 2.47 Å. The La(4)-O(43) bond length is 2.53 Å. The La(4)-O(45) bond length is 2.49 Å. The La(4)-O(46) bond length is 2.43 Å. There are twenty-eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted tetrahedral geometry to one P(1), one P(2), one N(1), and one H(17) atom. The C(1)-P(1) bond length is 1.84 Å. The C(1)-P(2) bond length is 1.84 Å. The C(1)-N(1) bond length is 1.46 Å. The C(1)-H(17) bond length is 0.98 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(1) and one N(2) atom. The C(2)-N(1) bond length is 1.35 Å. The C(2)-N(2) bond length is 1.35 Å. In the third C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(21) atom. The C(6)-N(2) bond length is 1.35 Å. The C(6)-H(21) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted tetrahedral geometry to one P(3), one P(4), one N(3), and one H(22) atom. The C(7)-P(3) bond length is 1.82 Å. The C(7)-P(4) bond length is 1.83 Å. The C(7)-N(3) bond length is 1.47 Å. The C(7)-H(22) bond length is 0.98 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(3) and one N(4) atom. The C(8)-N(3) bond length is 1.32 Å. The C(8)-N(4) bond length is 1.35 Å. In the sixth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(25) atom. The C(11)-C(12) bond length is 1.32 Å. The C(11)-H(25) bond length is 0.93 Å. In the seventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(11), one N(4), and one H(26) atom. The C(12)-N(4) bond length is 1.38 Å. The C(12)-H(26) bond length is 0.93 Å. In the eighth C site, C(13) is bonded in a distorted tetrahedral geometry to one P(5), one P(6), one N(5), and one H(27) atom. The C(13)-P(5) bond length is 1.82 Å. The C(13)-P(6) bond length is 1.83 Å. The C(13)-N(5) bond length is 1.46 Å. The C(13)-H(27) bond length is 0.98 Å. In the ninth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(5) and one N(6) atom. The C(14)-N(5) bond length is 1.35 Å. The C(14)-N(6) bond length is 1.35 Å. In the tenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(30) atom. The C(17)-C(18) bond length is 1.32 Å. The C(17)-H(30) bond length is 0.93 Å. In the eleventh C site, C(18) is bonded in a distorted trigonal planar geometry to one C(17), one N(6), and one H(31) atom. The C(18)-N(6) bond length is 1.37 Å. The C(18)-H(31) bond length is 0.93 Å. In the twelfth C site, C(19) is bonded in a distorted tetrahedral geometry to one P(7), one P(8), one N(7), and one H(32) atom. The C(19)-P(7) bond length is 1.82 Å. The C(19)-P(8) bond length is 1.83 Å. The C(19)-N(7) bond length is 1.45 Å. The C(19)-H(32) bond length is 0.98 Å. In the thirteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(7) and one N(8) atom. The C(20)-N(7) bond length is 1.34 Å. The C(20)-N(8) bond length is 1.38 Å. In the fourteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(35) atom. The C(23)-C(24) bond length is 1.29 Å. The C(23)-H(35) bond length is 0.93 Å. In the fifteenth C site, C(24) is bonded in a distorted trigonal planar geometry to one C(23), one N(8), and one H(36) atom. The C(24)-N(8) bond length is 1.39 Å. The C(24)-H(36) bond length is 0.93 Å. In the sixteenth C site, C(25) is bonded in a distorted tetrahedral geometry to one P(10), one P(9), one N(9), and one H(37) atom. The C(25)-P(10) bond length is 1.83 Å. The C(25)-P(9) bond length is 1.83 Å. The C(25)-N(9) bond length is 1.46 Å. The C(25)-H(37) bond length is 0.98 Å. In the seventeenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(10) and one N(9) atom. The C(26)-N(10) bond length is 1.36 Å. The C(26)-N(9) bond length is 1.35 Å. In the eighteenth C site, C(29) is bonded in a distorted single-bond geometry to one C(30) and one H(40) atom. The C(29)-C(30) bond length is 1.36 Å. The C(29)-H(40) bond length is 0.93 Å. In the nineteenth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one N(10), and one H(41) atom. The C(30)-N(10) bond length is 1.36 Å. The C(30)-H(41) bond length is 0.93 Å. In the twentieth C site, C(31) is bonded in a distorted tetrahedral geometry to one P(11), one P(12), one N(11), and one H(42) atom. The C(31)-P(11) bond length is 1.82 Å. The C(31)-P(12) bond length is 1.85 Å. The C(31)-N(11) bond length is 1.43 Å. The C(31)-H(42) bond length is 0.98 Å. In the twenty-first C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(11) and one N(12) atom. The C(32)-N(11) bond length is 1.36 Å. The C(32)-N(12) bond length is 1.34 Å. In the twenty-second C site, C(36) is bonded in a distorted bent 120 degrees geometry to one N(12) and one H(46) atom. The C(36)-N(12) bond length is 1.33 Å. The C(36)-H(46) bond length is 0.93 Å. In the twenty-third C site, C(37) is bonded in a distorted tetrahedral geometry to one P(13), one P(14), one N(13), and one H(47) atom. The C(37)-P(13) bond length is 1.84 Å. The C(37)-P(14) bond length is 1.84 Å. The C(37)-N(13) bond length is 1.47 Å. The C(37)-H(47) bond length is 0.98 Å. In the twenty-fourth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one N(13) and one N(14) atom. The C(38)-N(13) bond length is 1.34 Å. The C(38)-N(14) bond length is 1.35 Å. In the twenty-fifth C site, C(42) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(51) atom. The C(42)-N(14) bond length is 1.35 Å. The C(42)-H(51) bond length is 0.93 Å. In the twenty-sixth C site, C(43) is bonded in a distorted tetrahedral geometry to one P(15), one P(16), one N(15), and one H(52) atom. The C(43)-P(15) bond length is 1.83 Å. The C(43)-P(16) bond length is 1.83 Å. The C(43)-N(15) bond length is 1.47 Å. The C(43)-H(52) bond length is 0.98 Å. In the twenty-seventh C site, C(44) is bonded in a distorted bent 120 degrees geometry to one N(15) and one N(16) atom. The C(44)-N(15) bond length is 1.35 Å. The C(44)-N(16) bond length is 1.39 Å. In the twenty-eighth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one N(16) and one H(56) atom. The C(48)-N(16) bond length is 1.39 Å. The C(48)-H(56) bond length is 0.93 Å. There are sixteen inequivalent P sites. In the first P site, P(1) is bonded to one C(1), one O(1), one O(2), and one O(3) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one La(1)O7 pentagonal bipyramid,  a cornercorner with one P(2)CO3 tetrahedra, and  a cornercorner with one N(1)H2C2 tetrahedra. The P(1)-O(1) bond length is 1.58 Å. The P(1)-O(2) bond length is 1.51 Å. The P(1)-O(3) bond length is 1.50 Å. In the second P site, P(2) is bonded to one C(1), one O(4), one O(5), and one O(6) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one P(1)CO3 tetrahedra and  a cornercorner with one N(1)H2C2 tetrahedra. The P(2)-O(4) bond length is 1.50 Å. The P(2)-O(5) bond length is 1.56 Å. The P(2)-O(6) bond length is 1.50 Å. In the third P site, P(3) is bonded to one C(7), one O(7), one O(8), and one O(9) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one P(4)CO3 tetrahedra and  a cornercorner with one N(3)H2C2 tetrahedra. The P(3)-O(7) bond length is 1.51 Å. The P(3)-O(8) bond length is 1.57 Å. The P(3)-O(9) bond length is 1.50 Å. In the fourth P site, P(4) is bonded to one C(7), one O(10), one O(11), and one O(12) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one P(3)CO3 tetrahedra and  a cornercorner with one N(3)H2C2 tetrahedra. The P(4)-O(10) bond length is 1.52 Å. The P(4)-O(11) bond length is 1.51 Å. The P(4)-O(12) bond length is 1.52 Å. In the fifth P site, P(5) is bonded to one C(13), one O(13), one O(14), and one O(15) atom to form distorted PCO3 tetrahedra that share corners with two equivalent La(1)O7 pentagonal bipyramids,  a cornercorner with one P(6)CO3 tetrahedra, and  a cornercorner with one N(5)H2C2 tetrahedra. The P(5)-O(13) bond length is 1.51 Å. The P(5)-O(14) bond length is 1.50 Å. The P(5)-O(15) bond length is 1.57 Å. In the sixth P site, P(6) is bonded to one C(13), one O(16), one O(17), and one O(18) atom to form distorted PCO3 tetrahedra that share corners with two equivalent La(1)O7 pentagonal bipyramids,  a cornercorner with one P(5)CO3 tetrahedra, and  a cornercorner with one N(5)H2C2 tetrahedra. The P(6)-O(16) bond length is 1.51 Å. The P(6)-O(17) bond length is 1.52 Å. The P(6)-O(18) bond length is 1.52 Å. In the seventh P site, P(7) is bonded to one C(19), one O(19), one O(20), and one O(21) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one P(8)CO3 tetrahedra and  a cornercorner with one N(7)H2C2 tetrahedra. The P(7)-O(19) bond length is 1.58 Å. The P(7)-O(20) bond length is 1.49 Å. The P(7)-O(21) bond length is 1.51 Å. In the eighth P site, P(8) is bonded to one C(19), one O(22), one O(23), and one O(24) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one P(7)CO3 tetrahedra and  a cornercorner with one N(7)H2C2 tetrahedra. The P(8)-O(22) bond length is 1.52 Å. The P(8)-O(23) bond length is 1.51 Å. The P(8)-O(24) bond length is 1.51 Å. In the ninth P site, P(9) is bonded to one C(25), one O(25), one O(26), and one O(27) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one La(4)O7 pentagonal bipyramid,  a cornercorner with one P(10)CO3 tetrahedra, and  a cornercorner with one N(9)H2C2 tetrahedra. The P(9)-O(25) bond length is 1.58 Å. The P(9)-O(26) bond length is 1.50 Å. The P(9)-O(27) bond length is 1.50 Å. In the tenth P site, P(10) is bonded to one C(25), one O(28), one O(29), and one O(30) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one La(4)O7 pentagonal bipyramid,  a cornercorner with one P(9)CO3 tetrahedra, and  a cornercorner with one N(9)H2C2 tetrahedra. The P(10)-O(28) bond length is 1.50 Å. The P(10)-O(29) bond length is 1.57 Å. The P(10)-O(30) bond length is 1.51 Å. In the eleventh P site, P(11) is bonded to one C(31), one O(31), one O(32), and one O(33) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one La(4)O7 pentagonal bipyramid,  a cornercorner with one P(12)CO3 tetrahedra, and  a cornercorner with one N(11)H2C2 tetrahedra. The P(11)-O(31) bond length is 1.50 Å. The P(11)-O(32) bond length is 1.50 Å. The P(11)-O(33) bond length is 1.57 Å. In the twelfth P site, P(12) is bonded to one C(31), one O(34), one O(35), and one O(36) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one La(4)O7 pentagonal bipyramid,  a cornercorner with one P(11)CO3 tetrahedra, and  a cornercorner with one N(11)H2C2 tetrahedra. The P(12)-O(34) bond length is 1.51 Å. The P(12)-O(35) bond length is 1.53 Å. The P(12)-O(36) bond length is 1.51 Å. In the thirteenth P site, P(13) is bonded to one C(37), one O(37), one O(38), and one O(39) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one La(1)O7 pentagonal bipyramid,  a cornercorner with one P(14)CO3 tetrahedra, and  a cornercorner with one N(13)H2C2 tetrahedra. The P(13)-O(37) bond length is 1.58 Å. The P(13)-O(38) bond length is 1.51 Å. The P(13)-O(39) bond length is 1.50 Å. In the fourteenth P site, P(14) is bonded to one C(37), one O(40), one O(41), and one O(42) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one La(1)O7 pentagonal bipyramid,  a cornercorner with one P(13)CO3 tetrahedra, and  a cornercorner with one N(13)H2C2 tetrahedra. The P(14)-O(40) bond length is 1.49 Å. The P(14)-O(41) bond length is 1.57 Å. The P(14)-O(42) bond length is 1.51 Å. In the fifteenth P site, P(15) is bonded to one C(43), one O(43), one O(44), and one O(45) atom to form distorted PCO3 tetrahedra that share corners with two equivalent La(4)O7 pentagonal bipyramids,  a cornercorner with one P(16)CO3 tetrahedra, and  a cornercorner with one N(15)H2C2 tetrahedra. The P(15)-O(43) bond length is 1.51 Å. The P(15)-O(44) bond length is 1.58 Å. The P(15)-O(45) bond length is 1.50 Å. In the sixteenth P site, P(16) is bonded to one C(43), one O(46), one O(47), and one O(48) atom to form distorted PCO3 tetrahedra that share  a cornercorner with one La(4)O7 pentagonal bipyramid,  a cornercorner with one P(15)CO3 tetrahedra, and  a cornercorner with one N(15)H2C2 tetrahedra. The P(16)-O(46) bond length is 1.50 Å. The P(16)-O(47) bond length is 1.58 Å. The P(16)-O(48) bond length is 1.49 Å. There are sixteen inequivalent N sites. In the first N site, N(1) is bonded to one C(1), one C(2), one H(1), and one H(2) atom to form distorted NH2C2 tetrahedra that share  a cornercorner with one P(1)CO3 tetrahedra and  a cornercorner with one P(2)CO3 tetrahedra. The N(1)-H(1) bond length is 0.90 Å. The N(1)-H(2) bond length is 0.90 Å. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(2) and one C(6) atom. In the third N site, N(3) is bonded to one C(7), one C(8), one H(3), and one H(4) atom to form distorted NH2C2 tetrahedra that share  a cornercorner with one P(3)CO3 tetrahedra and  a cornercorner with one P(4)CO3 tetrahedra. The N(3)-H(3) bond length is 0.90 Å. The N(3)-H(4) bond length is 0.90 Å. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one C(12) and one C(8) atom. In the fifth N site, N(5) is bonded to one C(13), one C(14), one H(5), and one H(6) atom to form distorted NH2C2 tetrahedra that share  a cornercorner with one P(5)CO3 tetrahedra and  a cornercorner with one P(6)CO3 tetrahedra. The N(5)-H(5) bond length is 0.90 Å. The N(5)-H(6) bond length is 0.90 Å. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one C(14) and one C(18) atom. In the seventh N site, N(7) is bonded to one C(19), one C(20), one H(7), and one H(8) atom to form distorted NH2C2 tetrahedra that share  a cornercorner with one P(7)CO3 tetrahedra and  a cornercorner with one P(8)CO3 tetrahedra. The N(7)-H(7) bond length is 0.90 Å. The N(7)-H(8) bond length is 0.90 Å. In the eighth N site, N(8) is bonded in a bent 120 degrees geometry to one C(20) and one C(24) atom. In the ninth N site, N(9) is bonded to one C(25), one C(26), one H(10), and one H(9) atom to form distorted NH2C2 tetrahedra that share  a cornercorner with one P(10)CO3 tetrahedra and  a cornercorner with one P(9)CO3 tetrahedra. The N(9)-H(10) bond length is 0.90 Å. The N(9)-H(9) bond length is 0.90 Å. In the tenth N site, N(10) is bonded in a bent 120 degrees geometry to one C(26) and one C(30) atom. In the eleventh N site, N(11) is bonded to one C(31), one C(32), one H(11), and one H(12) atom to form distorted NH2C2 tetrahedra that share  a cornercorner with one P(11)CO3 tetrahedra and  a cornercorner with one P(12)CO3 tetrahedra. The N(11)-H(11) bond length is 0.90 Å. The N(11)-H(12) bond length is 0.90 Å. In the twelfth N site, N(12) is bonded in a bent 120 degrees geometry to one C(32) and one C(36) atom. In the thirteenth N site, N(13) is bonded to one C(37), one C(38), one H(13), and one H(14) atom to form distorted NH2C2 tetrahedra that share  a cornercorner with one P(13)CO3 tetrahedra and  a cornercorner with one P(14)CO3 tetrahedra. The N(13)-H(13) bond length is 0.90 Å. The N(13)-H(14) bond length is 0.90 Å. In the fourteenth N site, N(14) is bonded in a bent 120 degrees geometry to one C(38) and one C(42) atom. In the fifteenth N site, N(15) is bonded to one C(43), one C(44), one H(15), and one H(16) atom to form distorted NH2C2 tetrahedra that share  a cornercorner with one P(15)CO3 tetrahedra and  a cornercorner with one P(16)CO3 tetrahedra. The N(15)-H(15) bond length is 0.90 Å. The N(15)-H(16) bond length is 0.90 Å. In the sixteenth N site, N(16) is bonded in a bent 120 degrees geometry to one C(44) and one C(48) atom. There are forty-eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one N(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one N(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one N(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one N(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one N(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one N(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one N(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one N(9) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one N(11) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one N(11) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one N(13) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one N(13) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one N(15) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one N(15) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(1) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(6) atom. In the nineteenth H site, H(22) is bonded in a single-bond geometry to one C(7) atom. In the twentieth H site, H(25) is bonded in a single-bond geometry to one C(11) atom. In the twenty-first H site, H(26) is bonded in a single-bond geometry to one C(12) atom. In the twenty-second H site, H(27) is bonded in a single-bond geometry to one C(13) atom. In the twenty-third H site, H(30) is bonded in a single-bond geometry to one C(17) atom. In the twenty-fourth H site, H(31) is bonded in a single-bond geometry to one C(18) atom. In the twenty-fifth H site, H(32) is bonded in a single-bond geometry to one C(19) atom. In the twenty-sixth H site, H(35) is bonded in a single-bond geometry to one C(23) atom. In the twenty-seventh H site, H(36) is bonded in a single-bond geometry to one C(24) atom. In the twenty-eighth H site, H(37) is bonded in a single-bond geometry to one C(25) atom. In the twenty-ninth H site, H(40) is bonded in a single-bond geometry to one C(29) atom. In the thirtieth H site, H(41) is bonded in a single-bond geometry to one C(30) atom. In the thirty-first H site, H(42) is bonded in a single-bond geometry to one C(31) atom. In the thirty-second H site, H(46) is bonded in a single-bond geometry to one C(36) atom. In the thirty-third H site, H(47) is bonded in a single-bond geometry to one C(37) atom. In the thirty-fourth H site, H(51) is bonded in a single-bond geometry to one C(42) atom. In the thirty-fifth H site, H(52) is bonded in a single-bond geometry to one C(43) atom. In the thirty-sixth H site, H(56) is bonded in a single-bond geometry to one C(48) atom. In the thirty-seventh H site, H(57) is bonded in a single-bond geometry to one O(1) atom. The H(57)-O(1) bond length is 0.82 Å. In the thirty-eighth H site, H(58) is bonded in a single-bond geometry to one O(5) atom. The H(58)-O(5) bond length is 0.82 Å. In the thirty-ninth H site, H(59) is bonded in a single-bond geometry to one O(8) atom. The H(59)-O(8) bond length is 0.82 Å. In the fortieth H site, H(60) is bonded in a single-bond geometry to one O(15) atom. The H(60)-O(15) bond length is 0.82 Å. In the forty-first H site, H(61) is bonded in a single-bond geometry to one O(19) atom. The H(61)-O(19) bond length is 0.82 Å. In the forty-second H site, H(62) is bonded in a single-bond geometry to one O(25) atom. The H(62)-O(25) bond length is 0.82 Å. In the forty-third H site, H(63) is bonded in a single-bond geometry to one O(29) atom. The H(63)-O(29) bond length is 0.82 Å. In the forty-fourth H site, H(64) is bonded in a single-bond geometry to one O(33) atom. The H(64)-O(33) bond length is 0.82 Å. In the forty-fifth H site, H(65) is bonded in a single-bond geometry to one O(37) atom. The H(65)-O(37) bond length is 0.82 Å. In the forty-sixth H site, H(66) is bonded in a single-bond geometry to one O(41) atom. The H(66)-O(41) bond length is 0.82 Å. In the forty-seventh H site, H(67) is bonded in a single-bond geometry to one O(44) atom. The H(67)-O(44) bond length is 0.82 Å. In the forty-eighth H site, H(68) is bonded in a single-bond geometry to one O(47) atom. The H(68)-O(47) bond length is 0.82 Å. There are forty-eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted water-like geometry to one P(1) and one H(57) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one La(1) and one P(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one La(3) and one P(1) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one P(2) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one P(2) and one H(58) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one La(3) and one P(2) atom. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one La(3) and one P(3) atom. In the eighth O site, O(8) is bonded in a distorted water-like geometry to one P(3) and one H(59) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one La(3) and one P(3) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one P(4) atom. In the eleventh O site, O(11) is bonded in a distorted bent 150 degrees geometry to one La(3) and one P(4) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one La(3) and one P(4) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one La(1) and one P(5) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one La(1) and one P(5) atom. In the fifteenth O site, O(15) is bonded in a water-like geometry to one P(5) and one H(60) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 150 degrees geometry to one La(1) and one P(6) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 150 degrees geometry to one La(1) and one P(6) atom. In the eighteenth O site, O(18) is bonded in a single-bond geometry to one P(6) atom. In the nineteenth O site, O(19) is bonded in a water-like geometry to one P(7) and one H(61) atom. In the twentieth O site, O(20) is bonded in a distorted single-bond geometry to one La(2) and one P(7) atom. In the twenty-first O site, O(21) is bonded in a distorted single-bond geometry to one La(2) and one P(7) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 150 degrees geometry to one La(2) and one P(8) atom. In the twenty-third O site, O(23) is bonded in a single-bond geometry to one P(8) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 150 degrees geometry to one La(2) and one P(8) atom. In the twenty-fifth O site, O(25) is bonded in a distorted water-like geometry to one P(9) and one H(62) atom. In the twenty-sixth O site, O(26) is bonded in a distorted bent 150 degrees geometry to one La(4) and one P(9) atom. In the twenty-seventh O site, O(27) is bonded in a distorted single-bond geometry to one La(3) and one P(9) atom. In the twenty-eighth O site, O(28) is bonded in a distorted single-bond geometry to one La(4) and one P(10) atom. In the twenty-ninth O site, O(29) is bonded in a water-like geometry to one P(10) and one H(63) atom. In the thirtieth O site, O(30) is bonded in a single-bond geometry to one P(10) atom. In the thirty-first O site, O(31) is bonded in a distorted bent 150 degrees geometry to one La(4) and one P(11) atom. In the thirty-second O site, O(32) is bonded in a distorted single-bond geometry to one La(2) and one P(11) atom. In the thirty-third O site, O(33) is bonded in a water-like geometry to one P(11) and one H(64) atom. In the thirty-fourth O site, O(34) is bonded in a distorted bent 150 degrees geometry to one La(2) and one P(12) atom. In the thirty-fifth O site, O(35) is bonded in a single-bond geometry to one P(12) atom. In the thirty-sixth O site, O(36) is bonded in a distorted single-bond geometry to one La(4) and one P(12) atom. In the thirty-seventh O site, O(37) is bonded in a distorted water-like geometry to one P(13) and one H(65) atom. In the thirty-eighth O site, O(38) is bonded in a distorted bent 150 degrees geometry to one La(1) and one P(13) atom. In the thirty-ninth O site, O(39) is bonded in a distorted single-bond geometry to one La(2) and one P(13) atom. In the fortieth O site, O(40) is bonded in a distorted single-bond geometry to one La(1) and one P(14) atom. In the forty-first O site, O(41) is bonded in a water-like geometry to one P(14) and one H(66) atom. In the forty-second O site, O(42) is bonded in a single-bond geometry to one P(14) atom. In the forty-third O site, O(43) is bonded in a distorted single-bond geometry to one La(4) and one P(15) atom. In the forty-fourth O site, O(44) is bonded in a water-like geometry to one P(15) and one H(67) atom. In the forty-fifth O site, O(45) is bonded in a distorted single-bond geometry to one La(4) and one P(15) atom. In the forty-sixth O site, O(46) is bonded in a distorted bent 150 degrees geometry to one La(4) and one P(16) atom. In the forty-seventh O site, O(47) is bonded in a water-like geometry to one P(16) and one H(68) atom. In the forty-eighth O site, O(48) is bonded in a single-bond geometry to one P(16) atom. Linkers: 8 [O]P(=O)(C(P(=O)([O])[O])[NH2]c1ccccn1)O ,7 [O]P(=O)(C(P(=O)(O)[O])[NH2]c1ccccn1)O ,1 [O]P(=O)(C(P(=O)([O])O)[NH2]c1ccccn1)O. Metal clusters: 8 [La]. The MOF has largest included sphere 5.28 A, density 1.59 g/cm3, surface area 3489.73 m2/g, accessible volume 0.28 cm3/g