Zn2C40H26(NO3)3(CH2)5CH3C8H7OC7H5O is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight (1e)-1-methoxy-2,3-dimethylbuta-1,3-diene molecules; forty 02329_fluka molecules; eight 02329_fluka molecules; eight 2-(ethoxymethyl)-3-methylbuta-1,3-diene molecules; and eight Zn2C40H26(NO3)3 clusters. In each Zn2C40H26(NO3)3 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(10), one O(2), one O(4), and one O(8) atom. The Zn(1)-N(1) bond length is 2.11 Å. The Zn(1)-O(10) bond length is 2.03 Å. The Zn(1)-O(2) bond length is 2.01 Å. The Zn(1)-O(4) bond length is 2.05 Å. The Zn(1)-O(8) bond length is 2.06 Å. In the second Zn site, Zn(2) is bonded in a square pyramidal geometry to one N(2), one O(1), one O(3), one O(7), and one O(9) atom. The Zn(2)-N(2) bond length is 2.02 Å. The Zn(2)-O(1) bond length is 1.98 Å. The Zn(2)-O(3) bond length is 1.96 Å. The Zn(2)-O(7) bond length is 2.07 Å. The Zn(2)-O(9) bond length is 2.05 Å. There are forty inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.46 Å. The C(1)-O(1) bond length is 1.21 Å. The C(1)-O(2) bond length is 1.31 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(7) bond length is 1.36 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(8)-C(9) bond length is 1.56 Å. The C(8)-O(3) bond length is 1.25 Å. The C(8)-O(4) bond length is 1.31 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.45 Å. The C(9)-C(14) bond length is 1.30 Å. In the seventh C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(10)-H(5) bond length is 0.93 Å. In the eighth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. In the ninth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(7), and one O(8) atom. The C(30)-C(31) bond length is 1.56 Å. The C(30)-O(7) bond length is 1.25 Å. The C(30)-O(8) bond length is 1.33 Å. In the tenth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(36) atom. The C(31)-C(32) bond length is 1.40 Å. The C(31)-C(36) bond length is 1.27 Å. In the eleventh C site, C(32) is bonded in a distorted single-bond geometry to one C(31), one C(33), and one H(30) atom. The C(32)-C(33) bond length is 1.44 Å. The C(32)-H(30) bond length is 0.93 Å. In the twelfth C site, C(33) is bonded in a distorted trigonal planar geometry to one C(32), one C(34), and one H(31) atom. The C(33)-C(34) bond length is 1.48 Å. The C(33)-H(31) bond length is 0.93 Å. In the thirteenth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(47) atom. The C(34)-C(35) bond length is 1.53 Å. The C(34)-C(47) bond length is 1.58 Å. In the fourteenth C site, C(35) is bonded in a single-bond geometry to one C(34) and one H(32) atom. The C(35)-H(32) bond length is 0.93 Å. In the fifteenth C site, C(36) is bonded in a distorted single-bond geometry to one C(31) and one H(33) atom. The C(36)-H(33) bond length is 0.93 Å. In the sixteenth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(38), one O(10), and one O(9) atom. The C(37)-C(38) bond length is 1.60 Å. The C(37)-O(10) bond length is 1.23 Å. The C(37)-O(9) bond length is 1.34 Å. In the seventeenth C site, C(38) is bonded in a trigonal planar geometry to one C(37), one C(39), and one C(43) atom. The C(38)-C(39) bond length is 1.38 Å. The C(38)-C(43) bond length is 1.33 Å. In the eighteenth C site, C(39) is bonded in a single-bond geometry to one C(38) and one H(34) atom. The C(39)-H(34) bond length is 0.93 Å. In the nineteenth C site, C(40) is bonded in a distorted single-bond geometry to one C(41) and one H(35) atom. The C(40)-C(41) bond length is 1.38 Å. The C(40)-H(35) bond length is 0.93 Å. In the twentieth C site, C(41) is bonded in a trigonal planar geometry to one C(40), one C(42), and one C(44) atom. The C(41)-C(42) bond length is 1.40 Å. The C(41)-C(44) bond length is 1.63 Å. In the twenty-first C site, C(42) is bonded in a distorted single-bond geometry to one C(41) and one H(36) atom. The C(42)-H(36) bond length is 0.93 Å. In the twenty-second C site, C(43) is bonded in a distorted single-bond geometry to one C(38) and one H(37) atom. The C(43)-H(37) bond length is 0.93 Å. In the twenty-third C site, C(44) is bonded in a distorted trigonal planar geometry to one C(41), one C(45), and one C(49) atom. The C(44)-C(45) bond length is 1.30 Å. The C(44)-C(49) bond length is 1.65 Å. In the twenty-fourth C site, C(45) is bonded in a distorted single-bond geometry to one C(44), one C(46), and one H(38) atom. The C(45)-C(46) bond length is 1.50 Å. The C(45)-H(38) bond length is 0.93 Å. In the twenty-fifth C site, C(46) is bonded in a distorted trigonal planar geometry to one C(45), one C(47), and one O(11) atom. The C(46)-C(47) bond length is 1.13 Å. The C(46)-O(11) bond length is 1.52 Å. In the twenty-sixth C site, C(47) is bonded in a distorted trigonal planar geometry to one C(34), one C(46), and one C(48) atom. The C(47)-C(48) bond length is 1.61 Å. In the twenty-seventh C site, C(48) is bonded in a distorted single-bond geometry to one C(47), one C(49), and one H(39) atom. The C(48)-C(49) bond length is 1.44 Å. The C(48)-H(39) bond length is 0.93 Å. In the twenty-eighth C site, C(49) is bonded in a water-like geometry to one C(44) and one C(48) atom. In the twenty-ninth C site, C(50) is bonded in a distorted trigonal non-coplanar geometry to one C(51), one H(40), one H(41), and one O(11) atom. The C(50)-C(51) bond length is 1.64 Å. The C(50)-H(40) bond length is 0.97 Å. The C(50)-H(41) bond length is 0.97 Å. The C(50)-O(11) bond length is 0.98 Å. In the thirtieth C site, C(51) is bonded in a trigonal non-coplanar geometry to one C(50), one H(42), and one H(43) atom. The C(51)-H(42) bond length is 0.97 Å. The C(51)-H(43) bond length is 0.97 Å. In the thirty-first C site, C(52) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(44) atom. The C(52)-N(1) bond length is 1.24 Å. The C(52)-H(44) bond length is 0.93 Å. In the thirty-second C site, C(53) is bonded in a distorted single-bond geometry to one C(54) and one H(45) atom. The C(53)-C(54) bond length is 1.19 Å. The C(53)-H(45) bond length is 0.93 Å. In the thirty-third C site, C(54) is bonded in a trigonal planar geometry to one C(53), one C(55), and one C(59) atom. The C(54)-C(55) bond length is 1.49 Å. The C(54)-C(59) bond length is 1.42 Å. In the thirty-fourth C site, C(55) is bonded in a distorted single-bond geometry to one C(54) and one H(46) atom. The C(55)-H(46) bond length is 0.93 Å. In the thirty-fifth C site, C(56) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(47) atom. The C(56)-N(1) bond length is 1.37 Å. The C(56)-H(47) bond length is 0.93 Å. In the thirty-sixth C site, C(57) is bonded in a 4-coordinate geometry to one C(58), one N(2), one N(3), and one H(48) atom. The C(57)-C(58) bond length is 1.39 Å. The C(57)-N(2) bond length is 1.37 Å. The C(57)-N(3) bond length is 1.15 Å. The C(57)-H(48) bond length is 0.93 Å. In the thirty-seventh C site, C(58) is bonded in a distorted single-bond geometry to one C(57), one C(59), one N(3), and one H(49) atom. The C(58)-C(59) bond length is 1.39 Å. The C(58)-N(3) bond length is 1.60 Å. The C(58)-H(49) bond length is 0.93 Å. In the thirty-eighth C site, C(59) is bonded in a distorted trigonal planar geometry to one C(54), one C(58), and one C(61) atom. The C(59)-C(61) bond length is 1.34 Å. In the thirty-ninth C site, C(60) is bonded in a 4-coordinate geometry to one C(61), one N(2), one N(3), and one H(50) atom. The C(60)-C(61) bond length is 1.39 Å. The C(60)-N(2) bond length is 1.20 Å. The C(60)-N(3) bond length is 1.09 Å. The C(60)-H(50) bond length is 0.93 Å. In the fortieth C site, C(61) is bonded in a distorted single-bond geometry to one C(59), one C(60), one N(3), and one H(51) atom. The C(61)-N(3) bond length is 1.54 Å. The C(61)-H(51) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(52), and one C(56) atom. In the second N site, N(2) is bonded in a 4-coordinate geometry to one Zn(2), one C(57), one C(60), and one N(3) atom. The N(2)-N(3) bond length is 0.91 Å. In the third N site, N(3) is bonded in a 5-coordinate geometry to one C(57), one C(58), one C(60), one C(61), and one N(2) atom. There are twenty-six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(30) is bonded in a single-bond geometry to one C(32) atom. In the sixth H site, H(31) is bonded in a single-bond geometry to one C(33) atom. In the seventh H site, H(32) is bonded in a single-bond geometry to one C(35) atom. In the eighth H site, H(33) is bonded in a single-bond geometry to one C(36) atom. In the ninth H site, H(34) is bonded in a single-bond geometry to one C(39) atom. In the tenth H site, H(35) is bonded in a single-bond geometry to one C(40) atom. In the eleventh H site, H(36) is bonded in a single-bond geometry to one C(42) atom. In the twelfth H site, H(37) is bonded in a single-bond geometry to one C(43) atom. In the thirteenth H site, H(38) is bonded in a single-bond geometry to one C(45) atom. In the fourteenth H site, H(39) is bonded in a single-bond geometry to one C(48) atom. In the fifteenth H site, H(40) is bonded in a single-bond geometry to one C(50) atom. In the sixteenth H site, H(41) is bonded in a single-bond geometry to one C(50) atom. In the seventeenth H site, H(42) is bonded in a single-bond geometry to one C(51) atom. In the eighteenth H site, H(43) is bonded in a single-bond geometry to one C(51) atom. In the nineteenth H site, H(44) is bonded in a single-bond geometry to one C(52) atom. In the twentieth H site, H(45) is bonded in a single-bond geometry to one C(53) atom. In the twenty-first H site, H(46) is bonded in a single-bond geometry to one C(55) atom. In the twenty-second H site, H(47) is bonded in a single-bond geometry to one C(56) atom. In the twenty-third H site, H(48) is bonded in a single-bond geometry to one C(57) atom. In the twenty-fourth H site, H(49) is bonded in a single-bond geometry to one C(58) atom. In the twenty-fifth H site, H(50) is bonded in a single-bond geometry to one C(60) atom. In the twenty-sixth H site, H(51) is bonded in a single-bond geometry to one C(61) atom. There are nine inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(8) atom. In the fourth O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(30) atom. In the fifth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(30) atom. In the sixth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(37) atom. In the seventh O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(37) atom. In the eighth O site, O(11) is bonded in a distorted single-bond geometry to one C(46) and one C(50) atom. In the ninth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. Linkers: 8 [CH2]COc1cc(-c2ccc(C([O])=O)cc2)c(OCCCCCCC)cc1-c1ccc(C([O])=O)cc1 ,8 [CH2]CO[C]1C=C(c2ccc(C([O])=O)cc2)[C][CH][C]1c1ccc(C([O])=O)cc1 ,2 [CH][N@@]12[N][C@H]2C=C([CH]1)c1ccncc1 ,2 [CH]/C(=C\[C@@H]1[N]N1[CH])c1ccncc1 ,2 [CH]/C(=C\[C@H]1[N]N1[CH])c1ccncc1 ,2 [CH][N@]12[N][C@@H]2C=C([CH]1)c1ccncc1. Metal clusters: 8 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: sql. The MOF has largest included sphere 8.54 A, density 0.71 g/cm3, surface area 4915.34 m2/g, accessible volume 0.86 cm3/g