ZnC23NH14O4 crystallizes in the triclinic P1 space group. Zn(1,2,3,4,5,6,7,8,9,10,11,12) is bonded in a square pyramidal geometry to one N(1,2,3,4,5,6,10) and four equivalent O(1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48) atoms. The Zn(1,2,3,4,5,6,7,8,9,10,11,12)-N(1,2,3,4,5,6,10) bond length is 2.02 Å. All Zn(1,2,3,4,5,6,7,8,9,10,11,12)-O(1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48) bond lengths are 2.05 Å. There are forty inequivalent C sites. In the first C site, C(205,206,207,208,217,218,219,220) is bonded in a single-bond geometry to one C(112,120,164,172); one C(128,180,188); and one H(97,98,99,100,109,110,111,112) atom. The C(205,206,207,208,217,218,219,220)-C(112,120,164,172) bond length is 1.39 Å. The C(205,206,207,208,217,218,219,220)-C(128,180,188) bond length is 1.39 Å. The C(205,206,207,208,217,218,219,220)-H(97,98,99,100,109,110,111,112) bond length is 1.14 Å. In the second C site, C(209,211,212,213,221,222,223,226) is bonded in a single-bond geometry to one C(128,180,188); one C(144,152,196,204); and one H(101,102,103,104,113,114,115,116) atom. The C(209,211,212,213,221,222,223,226)-C(128,180,188) bond length is 1.39 Å. The C(209,211,212,213,221,222,223,226)-C(144,152,196,204) bond length is 1.39 Å. The C(209,211,212,213,221,222,223,226)-H(101,102,103,104,113,114,115,116) bond length is 1.14 Å. In the third C site, C(210,214,215,216,224,225,227,228) is bonded in a single-bond geometry to one C(132); one C(144,152,196,204); and one H(101,102,103,104,113,114,115,116) atom. The C(210,214,215,216,224,225,227,228)-C(132) bond length is 1.39 Å. The C(210,214,215,216,224,225,227,228)-C(144,152,196,204) bond length is 1.39 Å. The C(210,214,215,216,224,225,227,228)-H(101,102,103,104,113,114,115,116) bond length is 1.14 Å. In the fourth C site, C(97,98,99,100,101,102) is bonded in a trigonal planar geometry to one C(97,98,99,100,101,102) and two equivalent C(230,232,234,236,238,240,242,244,246,248,250,252,264,268) atoms. The C(97,98,99,100,101,102)-C(97,98,99,100,101,102) bond length is 1.45 Å. Both C(97,98,99,100,101,102)-C(230,232,234,236,238,240,242,244,246,248,250,252,264,268) bond lengths are 1.37 Å. In the fifth C site, C(229,231,233,235,237,239,241,243,245,247,249,251,253,259,261,263,267,271,273) is bonded in a distorted bent 120 degrees geometry to one C(230,232,234,236,238,240,242,244,246,248,250,252,264,268); one N(1,2,3,4,5,6,10); and one H(121,123,125,127,129,131,133,135,137,139,141,143,145,151,153,155,159,163,165) atom. The C(229,231,233,235,237,239,241,243,245,247,249,251,253,259,261,263,267,271,273)-C(230,232,234,236,238,240,242,244,246,248,250,252,264,268) bond length is 1.43 Å. The C(229,231,233,235,237,239,241,243,245,247,249,251,253,259,261,263,267,271,273)-N(1,2,3,4,5,6,10) bond length is 1.31 Å. The C(229,231,233,235,237,239,241,243,245,247,249,251,253,259,261,263,267,271,273)-H(121,123,125,127,129,131,133,135,137,139,141,143,145,151,153,155,159,163,165) bond length is 1.14 Å. In the sixth C site, C(230,232,234,236,238,240,242,244,246,248,250,252,264,268) is bonded in a distorted trigonal planar geometry to one C(229,231,233,235,237,239,241,243,245,247,249,251,253,259,261,263,267,271,273); one C(97,98,99,100,101,102); and one H(122,124,126,128,130,132,134,136,138,140,142,144,146,152,154,156,160,164,166) atom. The C(230,232,234,236,238,240,242,244,246,248,250,252,264,268)-H(122,124,126,128,130,132,134,136,138,140,142,144,146,152,154,156,160,164,166) bond length is 1.14 Å. In the seventh C site, C(103,108) is bonded in a trigonal planar geometry to one C(104,107); one C(254,260,262,272,274); and one C(256,258,266,270,276) atom. The C(103,108)-C(104,107) bond length is 1.45 Å. The C(103,108)-C(254,260,262,272,274) bond length is 1.37 Å. The C(103,108)-C(256,258,266,270,276) bond length is 1.37 Å. In the eighth C site, C(104,107) is bonded in a trigonal planar geometry to one C(103,108); one C(254,260,262,272,274); and one C(256,258,266,270,276) atom. The C(104,107)-C(254,260,262,272,274) bond length is 1.37 Å. The C(104,107)-C(256,258,266,270,276) bond length is 1.37 Å. In the ninth C site, C(105) is bonded in a trigonal planar geometry to one C(106); one C(254,260,262,272,274); and one C(256,258,266,270,276) atom. The C(105)-C(106) bond length is 1.45 Å. The C(105)-C(254,260,262,272,274) bond length is 1.37 Å. The C(105)-C(256,258,266,270,276) bond length is 1.37 Å. In the tenth C site, C(106) is bonded in a trigonal planar geometry to one C(105) and two equivalent C(230,232,234,236,238,240,242,244,246,248,250,252,264,268) atoms. Both C(106)-C(230,232,234,236,238,240,242,244,246,248,250,252,264,268) bond lengths are 1.37 Å. In the eleventh C site, C(109,113,117,121,157,161,165,169) is bonded in a bent 120 degrees geometry to one C(110,114,118,122,158,162,166,170) and two equivalent O(1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48) atoms. The C(109,113,117,121,157,161,165,169)-C(110,114,118,122,158,162,166,170) bond length is 1.48 Å. Both C(109,113,117,121,157,161,165,169)-O(1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48) bond lengths are 1.25 Å. In the twelfth C site, C(110,114,118,122,158,162,166,170) is bonded in a trigonal planar geometry to one C(109,113,117,121,157,161,165,169) and two equivalent C(2,4,6,8,42,44,46,48,50,52,54,56,90,92,94,96) atoms. Both C(110,114,118,122,158,162,166,170)-C(2,4,6,8,42,44,46,48,50,52,54,56,90,92,94,96) bond lengths are 1.39 Å. In the thirteenth C site, C(111,115,119,123,159,163,167,171) is bonded in a trigonal planar geometry to one C(112,120,164,172) and two equivalent C(1,3,5,7,41,43,45,47,49,51,53,55,89,91,93,95) atoms. The C(111,115,119,123,159,163,167,171)-C(112,120,164,172) bond length is 1.49 Å. Both C(111,115,119,123,159,163,167,171)-C(1,3,5,7,41,43,45,47,49,51,53,55,89,91,93,95) bond lengths are 1.37 Å. In the fourteenth C site, C(112,120,164,172) is bonded in a trigonal planar geometry to one C(111,115,119,123,159,163,167,171); one C(205,206,207,208,217,218,219,220); and one C(209,211,212,213,221,222,223,226) atom. The C(112,120,164,172)-C(209,211,212,213,221,222,223,226) bond length is 1.39 Å. In the fifteenth C site, C(116,124,160,168) is bonded in a trigonal planar geometry to one C(111,115,119,123,159,163,167,171); one C(205,206,207,208,217,218,219,220); and one C(210,214,215,216,224,225,227,228) atom. The C(116,124,160,168)-C(111,115,119,123,159,163,167,171) bond length is 1.49 Å. The C(116,124,160,168)-C(205,206,207,208,217,218,219,220) bond length is 1.39 Å. The C(116,124,160,168)-C(210,214,215,216,224,225,227,228) bond length is 1.39 Å. In the sixteenth C site, C(125,129,133,137,173,177,181,185) is bonded in a bent 120 degrees geometry to one C(126,130,134,174,178,186) and two equivalent O(1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48) atoms. The C(125,129,133,137,173,177,181,185)-C(126,130,134,174,178,186) bond length is 1.48 Å. Both C(125,129,133,137,173,177,181,185)-O(1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48) bond lengths are 1.25 Å. In the seventeenth C site, C(126,130,134,174,178,186) is bonded in a trigonal planar geometry to one C(10,12,14,16,58,60,62,64); one C(125,129,133,137,173,177,181,185); and one C(34,36,38,40,82,84,86,88) atom. The C(126,130,134,174,178,186)-C(10,12,14,16,58,60,62,64) bond length is 1.39 Å. The C(126,130,134,174,178,186)-C(34,36,38,40,82,84,86,88) bond length is 1.39 Å. In the eighteenth C site, C(127,135,139,175,179,187) is bonded in a trigonal planar geometry to one C(128,180,188); one C(33,35,37,39,81,83,85,87); and one C(9,11,13,15,57,59,61,63) atom. The C(127,135,139,175,179,187)-C(128,180,188) bond length is 1.49 Å. The C(127,135,139,175,179,187)-C(33,35,37,39,81,83,85,87) bond length is 1.37 Å. The C(127,135,139,175,179,187)-C(9,11,13,15,57,59,61,63) bond length is 1.37 Å. In the nineteenth C site, C(128,180,188) is bonded in a trigonal planar geometry to one C(127,135,139,175,179,187); one C(205,206,207,208,217,218,219,220); and one C(209,211,212,213,221,222,223,226) atom. In the twentieth C site, C(1,3,5,7,41,43,45,47,49,51,53,55,89,91,93,95) is bonded in a distorted trigonal planar geometry to one C(111,115,119,123,159,163,167,171); one C(2,4,6,8,42,44,46,48,50,52,54,56,90,92,94,96); and one H(1,3,5,7,41,43,45,47,49,51,53,55,89,91,93,95) atom. The C(1,3,5,7,41,43,45,47,49,51,53,55,89,91,93,95)-C(2,4,6,8,42,44,46,48,50,52,54,56,90,92,94,96) bond length is 1.38 Å. The C(1,3,5,7,41,43,45,47,49,51,53,55,89,91,93,95)-H(1,3,5,7,41,43,45,47,49,51,53,55,89,91,93,95) bond length is 1.14 Å. In the twenty-first C site, C(2,4,6,8,42,44,46,48,50,52,54,56,90,92,94,96) is bonded in a distorted trigonal planar geometry to one C(1,3,5,7,41,43,45,47,49,51,53,55,89,91,93,95); one C(110,114,118,122,158,162,166,170); and one H(2,4,6,8,34,36,38,40,42,44,46,48,50,52,54,56,82,84,86,88,90,92,94,96) atom. The C(2,4,6,8,42,44,46,48,50,52,54,56,90,92,94,96)-H(2,4,6,8,34,36,38,40,42,44,46,48,50,52,54,56,82,84,86,88,90,92,94,96) bond length is 1.14 Å. In the twenty-second C site, C(131,183) is bonded in a trigonal planar geometry to one C(132); one C(33,35,37,39,81,83,85,87); and one C(9,11,13,15,57,59,61,63) atom. The C(131,183)-C(132) bond length is 1.49 Å. The C(131,183)-C(33,35,37,39,81,83,85,87) bond length is 1.37 Å. The C(131,183)-C(9,11,13,15,57,59,61,63) bond length is 1.37 Å. In the twenty-third C site, C(132) is bonded in a trigonal planar geometry to one C(131,183); one C(205,206,207,208,217,218,219,220); and one C(210,214,215,216,224,225,227,228) atom. The C(132)-C(205,206,207,208,217,218,219,220) bond length is 1.39 Å. In the twenty-fourth C site, C(254,260,262,272,274) is bonded in a distorted trigonal planar geometry to one C(103,108); one C(229,231,233,235,237,239,241,243,245,247,249,251,253,259,261,263,267,271,273); and one H(122,124,126,128,130,132,134,136,138,140,142,144,146,152,154,156,160,164,166) atom. The C(254,260,262,272,274)-C(229,231,233,235,237,239,241,243,245,247,249,251,253,259,261,263,267,271,273) bond length is 1.43 Å. The C(254,260,262,272,274)-H(122,124,126,128,130,132,134,136,138,140,142,144,146,152,154,156,160,164,166) bond length is 1.14 Å. In the twenty-fifth C site, C(255,257,265,269,275) is bonded in a distorted bent 120 degrees geometry to one C(256,258,266,270,276); one N(8,9); and one H(147,149,157,161,167) atom. The C(255,257,265,269,275)-C(256,258,266,270,276) bond length is 1.43 Å. The C(255,257,265,269,275)-N(8,9) bond length is 1.31 Å. The C(255,257,265,269,275)-H(147,149,157,161,167) bond length is 1.14 Å. In the twenty-sixth C site, C(256,258,266,270,276) is bonded in a distorted trigonal planar geometry to one C(104,107); one C(255,257,265,269,275); and one H(148,150,158,162,168) atom. The C(256,258,266,270,276)-H(148,150,158,162,168) bond length is 1.14 Å. In the twenty-seventh C site, C(136,140,176) is bonded in a trigonal planar geometry to one C(127,135,139,175,179,187); one C(205,206,207,208,217,218,219,220); and one C(209,211,212,213,221,222,223,226) atom. The C(136,140,176)-C(127,135,139,175,179,187) bond length is 1.49 Å. The C(136,140,176)-C(205,206,207,208,217,218,219,220) bond length is 1.39 Å. The C(136,140,176)-C(209,211,212,213,221,222,223,226) bond length is 1.39 Å. In the twenty-eighth C site, C(9,11,13,15,57,59,61,63) is bonded in a distorted trigonal planar geometry to one C(10,12,14,16,58,60,62,64); one C(127,135,139,175,179,187); and one H(9,11,13,15,57,59,61,63) atom. The C(9,11,13,15,57,59,61,63)-C(10,12,14,16,58,60,62,64) bond length is 1.38 Å. The C(9,11,13,15,57,59,61,63)-H(9,11,13,15,57,59,61,63) bond length is 1.14 Å. In the twenty-ninth C site, C(10,12,14,16,58,60,62,64) is bonded in a distorted trigonal planar geometry to one C(126,130,134,174,178,186); one C(9,11,13,15,57,59,61,63); and one H(10,12,14,16,18,20,22,24,26,28,30,32,58,60,62,64,66,68,70,72,74,76,78,80) atom. The C(10,12,14,16,58,60,62,64)-H(10,12,14,16,18,20,22,24,26,28,30,32,58,60,62,64,66,68,70,72,74,76,78,80) bond length is 1.14 Å. In the thirtieth C site, C(138,182) is bonded in a trigonal planar geometry to one C(10,12,14,16,58,60,62,64); one C(125,129,133,137,173,177,181,185); and one C(34,36,38,40,82,84,86,88) atom. The C(138,182)-C(10,12,14,16,58,60,62,64) bond length is 1.39 Å. The C(138,182)-C(125,129,133,137,173,177,181,185) bond length is 1.48 Å. The C(138,182)-C(34,36,38,40,82,84,86,88) bond length is 1.39 Å. In the thirty-first C site, C(141,145,149,153,189,193,197,201) is bonded in a bent 120 degrees geometry to one C(142,146,150,154,190,194,198,202) and two equivalent O(1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48) atoms. The C(141,145,149,153,189,193,197,201)-C(142,146,150,154,190,194,198,202) bond length is 1.48 Å. Both C(141,145,149,153,189,193,197,201)-O(1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48) bond lengths are 1.25 Å. In the thirty-second C site, C(142,146,150,154,190,194,198,202) is bonded in a trigonal planar geometry to one C(141,145,149,153,189,193,197,201) and two equivalent C(18,20,22,24,26,28,30,32,66,68,70,72,74,76,78,80) atoms. Both C(142,146,150,154,190,194,198,202)-C(18,20,22,24,26,28,30,32,66,68,70,72,74,76,78,80) bond lengths are 1.39 Å. In the thirty-third C site, C(143,147,151,155,191,195,199,203) is bonded in a trigonal planar geometry to one C(144,152,196,204) and two equivalent C(17,19,21,23,25,27,29,31,65,67,69,71,73,75,77,79) atoms. The C(143,147,151,155,191,195,199,203)-C(144,152,196,204) bond length is 1.49 Å. Both C(143,147,151,155,191,195,199,203)-C(17,19,21,23,25,27,29,31,65,67,69,71,73,75,77,79) bond lengths are 1.37 Å. In the thirty-fourth C site, C(144,152,196,204) is bonded in a trigonal planar geometry to one C(143,147,151,155,191,195,199,203) and two equivalent C(209,211,212,213,221,222,223,226) atoms. In the thirty-fifth C site, C(17,19,21,23,25,27,29,31,65,67,69,71,73,75,77,79) is bonded in a distorted trigonal planar geometry to one C(143,147,151,155,191,195,199,203); one C(18,20,22,24,26,28,30,32,66,68,70,72,74,76,78,80); and one H(17,19,21,23,25,27,29,31,65,67,69,71,73,75,77,79) atom. The C(17,19,21,23,25,27,29,31,65,67,69,71,73,75,77,79)-C(18,20,22,24,26,28,30,32,66,68,70,72,74,76,78,80) bond length is 1.38 Å. The C(17,19,21,23,25,27,29,31,65,67,69,71,73,75,77,79)-H(17,19,21,23,25,27,29,31,65,67,69,71,73,75,77,79) bond length is 1.14 Å. In the thirty-sixth C site, C(18,20,22,24,26,28,30,32,66,68,70,72,74,76,78,80) is bonded in a distorted trigonal planar geometry to one C(142,146,150,154,190,194,198,202); one C(17,19,21,23,25,27,29,31,65,67,69,71,73,75,77,79); and one H(10,12,14,16,18,20,22,24,26,28,30,32,58,60,62,64,66,68,70,72,74,76,78,80) atom. The C(18,20,22,24,26,28,30,32,66,68,70,72,74,76,78,80)-H(10,12,14,16,18,20,22,24,26,28,30,32,58,60,62,64,66,68,70,72,74,76,78,80) bond length is 1.14 Å. In the thirty-seventh C site, C(148,156,192,200) is bonded in a trigonal planar geometry to one C(143,147,151,155,191,195,199,203); one C(209,211,212,213,221,222,223,226); and one C(210,214,215,216,224,225,227,228) atom. The C(148,156,192,200)-C(143,147,151,155,191,195,199,203) bond length is 1.49 Å. The C(148,156,192,200)-C(209,211,212,213,221,222,223,226) bond length is 1.39 Å. The C(148,156,192,200)-C(210,214,215,216,224,225,227,228) bond length is 1.39 Å. In the thirty-eighth C site, C(33,35,37,39,81,83,85,87) is bonded in a distorted trigonal planar geometry to one C(127,135,139,175,179,187); one C(34,36,38,40,82,84,86,88); and one H(33,35,37,39,81,83,85,87) atom. The C(33,35,37,39,81,83,85,87)-C(34,36,38,40,82,84,86,88) bond length is 1.38 Å. The C(33,35,37,39,81,83,85,87)-H(33,35,37,39,81,83,85,87) bond length is 1.14 Å. In the thirty-ninth C site, C(34,36,38,40,82,84,86,88) is bonded in a distorted trigonal planar geometry to one C(126,130,134,174,178,186); one C(33,35,37,39,81,83,85,87); and one H(2,4,6,8,34,36,38,40,42,44,46,48,50,52,54,56,82,84,86,88,90,92,94,96) atom. The C(34,36,38,40,82,84,86,88)-H(2,4,6,8,34,36,38,40,42,44,46,48,50,52,54,56,82,84,86,88,90,92,94,96) bond length is 1.14 Å. In the fortieth C site, C(184) is bonded in a trigonal planar geometry to one C(131,183); one C(205,206,207,208,217,218,219,220); and one C(209,211,212,213,221,222,223,226) atom. The C(184)-C(131,183) bond length is 1.49 Å. The C(184)-C(205,206,207,208,217,218,219,220) bond length is 1.39 Å. The C(184)-C(209,211,212,213,221,222,223,226) bond length is 1.39 Å. There are three inequivalent N sites. In the first N site, N(1,2,3,4,5,6,10) is bonded in a trigonal planar geometry to one Zn(1,2,3,4,5,6,7,8,9,10,11,12) and two equivalent C(229,231,233,235,237,239,241,243,245,247,249,251,253,259,261,263,267,271,273) atoms. In the second N site, N(7,11,12) is bonded in a trigonal planar geometry to one Zn(1,2,3,4,5,6,7,8,9,10,11,12); one C(229,231,233,235,237,239,241,243,245,247,249,251,253,259,261,263,267,271,273); and one C(255,257,265,269,275) atom. The N(7,11,12)-Zn(1,2,3,4,5,6,7,8,9,10,11,12) bond length is 2.02 Å. The N(7,11,12)-C(229,231,233,235,237,239,241,243,245,247,249,251,253,259,261,263,267,271,273) bond length is 1.31 Å. The N(7,11,12)-C(255,257,265,269,275) bond length is 1.31 Å. In the third N site, N(8,9) is bonded in a trigonal planar geometry to one Zn(1,2,3,4,5,6,7,8,9,10,11,12); one C(229,231,233,235,237,239,241,243,245,247,249,251,253,259,261,263,267,271,273); and one C(255,257,265,269,275) atom. The N(8,9)-Zn(1,2,3,4,5,6,7,8,9,10,11,12) bond length is 2.02 Å. The N(8,9)-C(229,231,233,235,237,239,241,243,245,247,249,251,253,259,261,263,267,271,273) bond length is 1.31 Å. There are thirteen inequivalent H sites. In the first H site, H(121,123,125,127,129,131,133,135,137,139,141,143,145,151,153,155,159,163,165) is bonded in a single-bond geometry to one C(229,231,233,235,237,239,241,243,245,247,249,251,253,259,261,263,267,271,273) atom. In the second H site, H(122,124,126,128,130,132,134,136,138,140,142,144,146,152,154,156,160,164,166) is bonded in a single-bond geometry to one C(230,232,234,236,238,240,242,244,246,248,250,252,264,268) atom. In the third H site, H(1,3,5,7,41,43,45,47,49,51,53,55,89,91,93,95) is bonded in a single-bond geometry to one C(1,3,5,7,41,43,45,47,49,51,53,55,89,91,93,95) atom. In the fourth H site, H(2,4,6,8,34,36,38,40,42,44,46,48,50,52,54,56,82,84,86,88,90,92,94,96) is bonded in a single-bond geometry to one C(2,4,6,8,42,44,46,48,50,52,54,56,90,92,94,96) atom. In the fifth H site, H(9,11,13,15,57,59,61,63) is bonded in a single-bond geometry to one C(9,11,13,15,57,59,61,63) atom. In the sixth H site, H(10,12,14,16,18,20,22,24,26,28,30,32,58,60,62,64,66,68,70,72,74,76,78,80) is bonded in a single-bond geometry to one C(10,12,14,16,58,60,62,64) atom. In the seventh H site, H(17,19,21,23,25,27,29,31,65,67,69,71,73,75,77,79) is bonded in a single-bond geometry to one C(17,19,21,23,25,27,29,31,65,67,69,71,73,75,77,79) atom. In the eighth H site, H(147,149,157,161,167) is bonded in a single-bond geometry to one C(255,257,265,269,275) atom. In the ninth H site, H(148,150,158,162,168) is bonded in a single-bond geometry to one C(256,258,266,270,276) atom. In the tenth H site, H(33,35,37,39,81,83,85,87) is bonded in a single-bond geometry to one C(33,35,37,39,81,83,85,87) atom. In the eleventh H site, H(97,98,99,100,109,110,111,112) is bonded in a single-bond geometry to one C(205,206,207,208,217,218,219,220) atom. In the twelfth H site, H(101,102,103,104,113,114,115,116) is bonded in a single-bond geometry to one C(209,211,212,213,221,222,223,226) atom. In the thirteenth H site, H(105,106,107,108,117,118,119,120) is bonded in a single-bond geometry to one C(209,211,212,213,221,222,223,226) atom. The H(105,106,107,108,117,118,119,120)-C(209,211,212,213,221,222,223,226) bond length is 1.14 Å. O(1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48) is bonded in a bent 120 degrees geometry to one Zn(1,2,3,4,5,6,7,8,9,10,11,12) and one C(109,113,117,121,157,161,165,169) atom. Linkers: 6 c1cc(-c2ccncc2)ccn1 ,8 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C([O])=O)cc3)c2)cc1. Metal clusters: 6 [C]1O[Zn]234O[C]O[Zn]2(O1)(O[C]O3)O[C]O4. RCSR code: pto. The MOF has largest included sphere 20.52 A, density 0.41 g/cm3, surface area 4784.37 m2/g, accessible volume 2.00 cm3/g