Co5C62H42(N4O7)2(C11H7)2(CH)12(C2O)5 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of forty-eight 02329_fluka molecules, twenty dimethyl ether molecules, eight C11H7 clusters, and four Co5C62H42(N4O7)2 clusters. In each C11H7 cluster, there are eleven inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-H(2) bond length is 0.93 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(6) bond length is 1.48 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.93 Å. In the fourth C site, C(6) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(7) atom. The C(6)-C(11) bond length is 1.39 Å. The C(6)-C(7) bond length is 1.39 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(5) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-H(5) bond length is 0.93 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(12), one C(7), and one C(9) atom. The C(8)-C(12) bond length is 1.49 Å. The C(8)-C(9) bond length is 1.38 Å. In the seventh C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(6) atom. The C(9)-H(6) bond length is 0.93 Å. In the eighth C site, C(11) is bonded in a single-bond geometry to one C(6) and one H(7) atom. The C(11)-H(7) bond length is 0.93 Å. In the ninth C site, C(12) is bonded in a trigonal planar geometry to one C(13), one C(16), and one C(8) atom. The C(12)-C(13) bond length is 1.37 Å. The C(12)-C(16) bond length is 1.37 Å. In the tenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(8) atom. The C(13)-H(8) bond length is 0.93 Å. In the eleventh C site, C(16) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(16)-H(11) bond length is 0.93 Å. There are seven inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In each Co5C62H42(N4O7)2 cluster, there are three inequivalent Co sites. In the first Co site, Co(1) is bonded to one N(1), one N(3), one O(3), one O(6), one O(8), and one O(9) atom to form CoN2O4 octahedra that share  a cornercorner with one Co(2)N2O4 octahedra and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. The Co(1)-N(1) bond length is 2.13 Å. The Co(1)-N(3) bond length is 2.13 Å. The Co(1)-O(3) bond length is 2.05 Å. The Co(1)-O(6) bond length is 2.03 Å. The Co(1)-O(8) bond length is 2.32 Å. The Co(1)-O(9) bond length is 2.05 Å. In the second Co site, Co(2) is bonded to one N(2), one N(4), one O(4), one O(5), one O(7), and one O(9) atom to form CoN2O4 octahedra that share  a cornercorner with one Co(1)N2O4 octahedra and  an edgeedge with one Co(3)O6 octahedra. The corner-sharing octahedral tilt angles are 53°. The Co(2)-N(2) bond length is 2.16 Å. The Co(2)-N(4) bond length is 2.17 Å. The Co(2)-O(4) bond length is 2.34 Å. The Co(2)-O(5) bond length is 2.04 Å. The Co(2)-O(7) bond length is 2.07 Å. The Co(2)-O(9) bond length is 2.04 Å. In the third Co site, Co(3) is bonded to two equivalent O(4), two equivalent O(8), and two equivalent O(9) atoms to form edge-sharing CoO6 octahedra. Both Co(3)-O(4) bond lengths are 2.17 Å. Both Co(3)-O(8) bond lengths are 2.12 Å. Both Co(3)-O(9) bond lengths are 2.02 Å. There are thirty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-H(4) bond length is 0.93 Å. In the third C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(14)-N(2) bond length is 1.33 Å. The C(14)-H(9) bond length is 0.93 Å. In the fourth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(15)-N(2) bond length is 1.32 Å. The C(15)-H(10) bond length is 0.93 Å. In the fifth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(12) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(12) bond length is 0.93 Å. In the sixth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(23) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-C(23) bond length is 1.48 Å. In the seventh C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(13) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(13) bond length is 0.93 Å. In the eighth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(28) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-C(28) bond length is 1.50 Å. In the ninth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(14) atom. The C(22)-H(14) bond length is 0.93 Å. In the tenth C site, C(23) is bonded in a trigonal planar geometry to one C(19), one C(24), and one C(27) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-C(27) bond length is 1.38 Å. In the eleventh C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one H(15) atom. The C(24)-C(25) bond length is 1.37 Å. The C(24)-H(15) bond length is 0.93 Å. In the twelfth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one N(3), and one H(16) atom. The C(25)-N(3) bond length is 1.34 Å. The C(25)-H(16) bond length is 0.93 Å. In the thirteenth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(27), one N(3), and one H(17) atom. The C(26)-C(27) bond length is 1.36 Å. The C(26)-N(3) bond length is 1.34 Å. The C(26)-H(17) bond length is 0.93 Å. In the fourteenth C site, C(27) is bonded in a distorted single-bond geometry to one C(23), one C(26), and one H(18) atom. The C(27)-H(18) bond length is 0.93 Å. In the fifteenth C site, C(28) is bonded in a trigonal planar geometry to one C(21), one C(29), and one C(32) atom. The C(28)-C(29) bond length is 1.37 Å. The C(28)-C(32) bond length is 1.37 Å. In the sixteenth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(20) atom. The C(30)-N(4) bond length is 1.32 Å. The C(30)-H(20) bond length is 0.93 Å. In the seventeenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(21) atom. The C(31)-N(4) bond length is 1.34 Å. The C(31)-H(21) bond length is 0.93 Å. In the eighteenth C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(19) atom. The C(29)-H(19) bond length is 0.93 Å. In the nineteenth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(34), one O(3), and one O(4) atom. The C(33)-C(34) bond length is 1.50 Å. The C(33)-O(3) bond length is 1.25 Å. The C(33)-O(4) bond length is 1.26 Å. In the twentieth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(39) atom. The C(34)-C(35) bond length is 1.38 Å. The C(34)-C(39) bond length is 1.39 Å. In the twenty-first C site, C(35) is bonded in a distorted single-bond geometry to one C(34) and one H(23) atom. The C(35)-H(23) bond length is 0.93 Å. In the twenty-second C site, C(32) is bonded in a distorted single-bond geometry to one C(28) and one H(22) atom. The C(32)-H(22) bond length is 0.93 Å. In the twenty-third C site, C(39) is bonded in a distorted single-bond geometry to one C(34) and one H(26) atom. The C(39)-H(26) bond length is 0.93 Å. In the twenty-fourth C site, C(42) is bonded in a distorted single-bond geometry to one C(43) and one H(28) atom. The C(42)-C(43) bond length is 1.38 Å. The C(42)-H(28) bond length is 0.93 Å. In the twenty-fifth C site, C(43) is bonded in a trigonal planar geometry to one C(42), one C(44), and one C(46) atom. The C(43)-C(44) bond length is 1.39 Å. The C(43)-C(46) bond length is 1.49 Å. In the twenty-sixth C site, C(44) is bonded in a single-bond geometry to one C(43) and one H(29) atom. The C(44)-H(29) bond length is 0.93 Å. In the twenty-seventh C site, C(46) is bonded in a distorted bent 120 degrees geometry to one C(43), one O(5), and one O(6) atom. The C(46)-O(5) bond length is 1.26 Å. The C(46)-O(6) bond length is 1.25 Å. In the twenty-eighth C site, C(47) is bonded in a distorted bent 120 degrees geometry to one C(48), one O(7), and one O(8) atom. The C(47)-C(48) bond length is 1.49 Å. The C(47)-O(7) bond length is 1.26 Å. The C(47)-O(8) bond length is 1.27 Å. In the twenty-ninth C site, C(48) is bonded in a trigonal planar geometry to one C(47), one C(49), and one C(53) atom. The C(48)-C(49) bond length is 1.39 Å. The C(48)-C(53) bond length is 1.39 Å. In the thirtieth C site, C(49) is bonded in a distorted single-bond geometry to one C(48) and one H(31) atom. The C(49)-H(31) bond length is 0.93 Å. In the thirty-first C site, C(53) is bonded in a distorted single-bond geometry to one C(48) and one H(34) atom. The C(53)-H(34) bond length is 0.93 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Co(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Co(2), one C(14), and one C(15) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Co(1), one C(25), and one C(26) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Co(2), one C(30), and one C(31) atom. There are twenty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(15) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(27) atom. In the twelfth H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(30) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(31) atom. In the fifteenth H site, H(22) is bonded in a single-bond geometry to one C(32) atom. In the sixteenth H site, H(23) is bonded in a single-bond geometry to one C(35) atom. In the seventeenth H site, H(26) is bonded in a single-bond geometry to one C(39) atom. In the eighteenth H site, H(28) is bonded in a single-bond geometry to one C(42) atom. In the nineteenth H site, H(29) is bonded in a single-bond geometry to one C(44) atom. In the twentieth H site, H(31) is bonded in a single-bond geometry to one C(49) atom. In the twenty-first H site, H(34) is bonded in a single-bond geometry to one C(53) atom. There are seven inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Co(1) and one C(33) atom. In the second O site, O(4) is bonded in a 3-coordinate geometry to one Co(2), one Co(3), and one C(33) atom. In the third O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(46) atom. In the fourth O site, O(6) is bonded in a bent 150 degrees geometry to one Co(1) and one C(46) atom. In the fifth O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Co(2) and one C(47) atom. In the sixth O site, O(8) is bonded in a 3-coordinate geometry to one Co(1), one Co(3), and one C(47) atom. In the seventh O site, O(9) is bonded in a trigonal non-coplanar geometry to one Co(1), one Co(2), and one Co(3) atom. Linkers: 6 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,4 c1cc(-c2cc(Oc3cc(-c4ccncc4)cc(-c4ccncc4)c3)cc(-c3ccncc3)c2)ccn1. Metal clusters: 2 [C]1O[Co]O[C]O[Co]234(O[C]O[Co]O[C]O[Co](O[C]O2)O3)O[C]O[Co](O1)O4. RCSR code: cds. The MOF has largest included sphere 7.19 A, density 1.04 g/cm3, surface area 4224.57 m2/g, accessible volume 0.46 cm3/g