CuH24(C2N)12 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four CuH24(C2N)12 clusters. Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(10), one N(4), and one N(7) atom. The Cu(1)-N(1) bond length is 2.02 Å. The Cu(1)-N(10) bond length is 1.99 Å. The Cu(1)-N(4) bond length is 1.97 Å. The Cu(1)-N(7) bond length is 2.04 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(1) atom. The C(1)-N(7) bond length is 1.31 Å. The C(1)-N(8) bond length is 1.31 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(2) atom. The C(2)-N(7) bond length is 1.32 Å. The C(2)-N(9) bond length is 1.31 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(10), one N(11), and one H(3) atom. The C(3)-N(10) bond length is 1.33 Å. The C(3)-N(11) bond length is 1.33 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(4) atom. The C(4)-N(10) bond length is 1.33 Å. The C(4)-N(12) bond length is 1.33 Å. The C(4)-H(4) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(5) atom. The C(5)-N(1) bond length is 1.33 Å. The C(5)-N(2) bond length is 1.31 Å. The C(5)-H(5) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(6) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-N(3) bond length is 1.31 Å. The C(6)-H(6) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a 3-coordinate geometry to one C(8), one N(3), one H(7), and one H(8) atom. The C(7)-C(8) bond length is 1.48 Å. The C(7)-N(3) bond length is 1.46 Å. The C(7)-H(7) bond length is 0.97 Å. The C(7)-H(8) bond length is 0.97 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(10), one C(7), and one C(9) atom. The C(8)-C(10) bond length is 1.37 Å. The C(8)-C(9) bond length is 1.40 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(9,21) atom. The C(9)-H(9,21) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a single-bond geometry to one C(8) and one H(10) atom. The C(10)-H(10) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(11) atom. The C(11)-N(4) bond length is 1.36 Å. The C(11)-N(5) bond length is 1.31 Å. The C(11)-H(11) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(12) atom. The C(12)-N(4) bond length is 1.33 Å. The C(12)-N(6) bond length is 1.31 Å. The C(12)-H(12) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a 3-coordinate geometry to one C(14), one N(6), one H(13), and one H(14) atom. The C(13)-C(14) bond length is 1.52 Å. The C(13)-N(6) bond length is 1.46 Å. The C(13)-H(13) bond length is 0.97 Å. The C(13)-H(14) bond length is 0.97 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(16) atom. The C(14)-C(15) bond length is 1.35 Å. The C(14)-C(16) bond length is 1.34 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(15) atom. The C(15)-H(15) bond length is 0.93 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(14) and one H(16) atom. The C(16)-H(16) bond length is 0.93 Å. In the seventeenth C site, C(17) is bonded in a 3-coordinate geometry to one C(18); one N(9); and two equivalent H(17,18) atoms. The C(17)-C(18) bond length is 1.53 Å. The C(17)-N(9) bond length is 1.48 Å. Both C(17)-H(17,18) bond lengths are 0.97 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(23) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-C(23) bond length is 1.36 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(19) atom. The C(19)-H(19) bond length is 0.93 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(20) atom. The C(20)-C(21) bond length is 1.38 Å. The C(20)-H(20) bond length is 0.93 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-C(24) bond length is 1.51 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(9,21) atom. The C(22)-H(9,21) bond length is 0.93 Å. In the twenty-third C site, C(23) is bonded in a single-bond geometry to one C(18) and one H(22) atom. The C(23)-H(22) bond length is 0.93 Å. In the twenty-fourth C site, C(24) is bonded in a distorted trigonal non-coplanar geometry to one C(21), one N(12), one H(23), and one H(24) atom. The C(24)-N(12) bond length is 1.44 Å. The C(24)-H(23) bond length is 0.97 Å. The C(24)-H(24) bond length is 0.97 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(5), and one C(6) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(5) and one N(3) atom. The N(2)-N(3) bond length is 1.34 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(11), and one C(12) atom. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(11) and one N(6) atom. The N(5)-N(6) bond length is 1.36 Å. In the sixth N site, N(6) is bonded in a distorted bent 120 degrees geometry to one C(12), one C(13), and one N(5) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the eighth N site, N(8) is bonded in a distorted water-like geometry to one C(1) and one N(9) atom. The N(8)-N(9) bond length is 1.31 Å. In the ninth N site, N(9) is bonded in a distorted trigonal planar geometry to one C(17), one C(2), and one N(8) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(4) atom. In the eleventh N site, N(11) is bonded in a water-like geometry to one C(3) and one N(12) atom. The N(11)-N(12) bond length is 1.33 Å. In the twelfth N site, N(12) is bonded in a 3-coordinate geometry to one C(24), one C(4), and one N(11) atom. There are twenty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9,21) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the seventeenth H site, H(17,18) is bonded in a single-bond geometry to one C(17) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(23) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(24) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(24) atom. Linkers: 1 c1ncn(Cc2ccc(Cn3cncn3)cc2)n1 ,2 [CH]1N=C[N]N1Cc1ccc(Cn2cncn2)cc1 ,5 [CH]1N=C[N]N1Cc1ccc(CN2[CH]N=C[N]2)cc1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 8.48 A, density 0.89 g/cm3, surface area 5216.78 m2/g, accessible volume 0.65 cm3/g