(ZnC10NH6O4)2C12N2H6S is TlF-II structured and crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight C12N2H6S clusters and eight ZnC10NH6O4 clusters. In each C12N2H6S cluster, there are twelve inequivalent C sites. In the first C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(10,11) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-H(10,11) bond length is 0.93 Å. In the second C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(22) atom. The C(19)-C(20) bond length is 1.38 Å. The C(19)-C(22) bond length is 1.47 Å. In the third C site, C(20) is bonded in a single-bond geometry to one C(19) and one H(10,11) atom. The C(20)-H(10,11) bond length is 0.93 Å. In the fourth C site, C(22) is bonded in a trigonal planar geometry to one C(19), one C(23), and one C(27) atom. The C(22)-C(23) bond length is 1.42 Å. The C(22)-C(27) bond length is 1.36 Å. In the fifth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(22), one C(24), and one N(3) atom. The C(23)-C(24) bond length is 1.44 Å. The C(23)-N(3) bond length is 1.35 Å. In the sixth C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one N(4) atom. The C(24)-C(25) bond length is 1.42 Å. The C(24)-N(4) bond length is 1.35 Å. In the seventh C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(28) atom. The C(25)-C(26) bond length is 1.37 Å. The C(25)-C(28) bond length is 1.47 Å. In the eighth C site, C(26) is bonded in a single-bond geometry to one C(25) and one H(13) atom. The C(26)-H(13) bond length is 0.93 Å. In the ninth C site, C(27) is bonded in a single-bond geometry to one C(22) and one H(14) atom. The C(27)-H(14) bond length is 0.93 Å. In the tenth C site, C(28) is bonded in a trigonal planar geometry to one C(25), one C(29), and one C(32) atom. The C(28)-C(29) bond length is 1.40 Å. The C(28)-C(32) bond length is 1.39 Å. In the eleventh C site, C(29) is bonded in a single-bond geometry to one C(28) and one H(15,18) atom. The C(29)-H(15,18) bond length is 0.93 Å. In the twelfth C site, C(32) is bonded in a distorted single-bond geometry to one C(28) and one H(15,18) atom. The C(32)-H(15,18) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a water-like geometry to one C(23) and one S(1) atom. The N(3)-S(1) bond length is 1.61 Å. In the second N site, N(4) is bonded in a water-like geometry to one C(24) and one S(1) atom. The N(4)-S(1) bond length is 1.61 Å. There are four inequivalent H sites. In the first H site, H(10,11) is bonded in a single-bond geometry to one C(18) atom. In the second H site, H(13) is bonded in a single-bond geometry to one C(26) atom. In the third H site, H(14) is bonded in a single-bond geometry to one C(27) atom. In the fourth H site, H(15,18) is bonded in a single-bond geometry to one C(29) atom. S(1) is bonded in a water-like geometry to one N(3) and one N(4) atom. In each ZnC10NH6O4 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(3), one O(5), and one O(8) atom. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 2.05 Å. The Zn(1)-O(3) bond length is 2.05 Å. The Zn(1)-O(5) bond length is 2.04 Å. The Zn(1)-O(8) bond length is 2.06 Å. In the second Zn site, Zn(2) is bonded in a distorted square pyramidal geometry to one N(2), one O(2), one O(4), one O(6), and one O(7) atom. The Zn(2)-N(2) bond length is 2.03 Å. The Zn(2)-O(2) bond length is 2.04 Å. The Zn(2)-O(4) bond length is 2.05 Å. The Zn(2)-O(6) bond length is 2.04 Å. The Zn(2)-O(7) bond length is 2.06 Å. There are twenty inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.25 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(8) bond length is 1.50 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the seventh C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one O(5), and one O(6) atom. The C(9)-C(10) bond length is 1.50 Å. The C(9)-O(5) bond length is 1.25 Å. The C(9)-O(6) bond length is 1.25 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(9) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-C(15) bond length is 1.38 Å. In the tenth C site, C(11) is bonded in a distorted single-bond geometry to one C(10) and one H(5,8) atom. The C(11)-H(5,8) bond length is 0.93 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(6,7) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-H(6,7) bond length is 0.93 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(10) and one H(5,8) atom. The C(15)-H(5,8) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-C(16) bond length is 1.50 Å. In the fourteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9,12) atom. The C(17)-N(1) bond length is 1.33 Å. The C(17)-H(9,12) bond length is 0.93 Å. In the fifteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(7), and one O(8) atom. The C(16)-O(7) bond length is 1.25 Å. The C(16)-O(8) bond length is 1.25 Å. In the sixteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(6,7) atom. The C(14)-H(6,7) bond length is 0.93 Å. In the seventeenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(9,12) atom. The C(21)-N(1) bond length is 1.34 Å. The C(21)-H(9,12) bond length is 0.93 Å. In the eighteenth C site, C(30) is bonded in a 2-coordinate geometry to one N(2) and one H(16) atom. The C(30)-N(2) bond length is 1.33 Å. The C(30)-H(16) bond length is 0.93 Å. In the nineteenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(17) atom. The C(31)-N(2) bond length is 1.33 Å. The C(31)-H(17) bond length is 0.93 Å. In the twentieth C site, C(8) is bonded in a bent 120 degrees geometry to one C(5), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.25 Å. The C(8)-O(4) bond length is 1.26 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(17), and one C(21) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(30), and one C(31) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5,8) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(6,7) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9,12) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(30) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(31) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(8) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(9) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(16) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(16) atom. Linkers: 8 c1cc(-c2ccc(-c3ccncc3)c3nsnc23)ccn1 ,16 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 8 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 5.72 A, density 1.13 g/cm3, surface area 4194.49 m2/g, accessible volume 0.44 cm3/g