CuH8(C2N)4(CH)8C9H8O4 crystallizes in the tetragonal P-4n2 space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules; two 1,3-dimethoxy-2,2-bis(methoxymethyl)propane molecules; and two CuH8(C2N)4 clusters. In each CuH8(C2N)4 cluster, Cu(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. All Cu(1)-N(1) bond lengths are 2.02 Å. There are two inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(5)-N(1) bond length is 1.36 Å. The C(5)-H(5) bond length is 0.93 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(6)-N(1) bond length is 1.33 Å. The C(6)-H(6) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(5), and one C(6) atom. There are two inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(6) atom. Linkers: 4 c1cncc(OCC(COc2cccnc2)(COc2cccnc2)COc2cccnc2)c1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 5.12 A, density 0.79 g/cm3, surface area 5014.96 m2/g, accessible volume 0.81 cm3/g