ZnC13N3H10O4(CH2)2 crystallizes in the monoclinic C2/c space group. The structure consists of sixteen 02329_fluka molecules inside a ZnC13N3H10O4 framework. In the ZnC13N3H10O4 framework, Zn(1) is bonded in a trigonal bipyramidal geometry to one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(3) bond length is 1.99 Å. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.05 Å. The Zn(1)-O(3) bond length is 2.04 Å. The Zn(1)-O(4) bond length is 2.08 Å. There are thirteen inequivalent C sites. In the first C site, C(9) is bonded in a distorted trigonal planar geometry to one C(8), one N(1), and one N(3) atom. The C(9)-C(8) bond length is 1.52 Å. The C(9)-N(1) bond length is 1.34 Å. The C(9)-N(3) bond length is 1.30 Å. In the second C site, C(11) is bonded in a distorted single-bond geometry to one C(1), one C(12), and one H(11) atom. The C(11)-C(1) bond length is 1.38 Å. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(11) bond length is 0.93 Å. In the third C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-C(14) bond length is 1.51 Å. In the fourth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(4), and one H(12) atom. The C(13)-C(4) bond length is 1.40 Å. The C(13)-H(12) bond length is 0.93 Å. In the fifth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.25 Å. The C(14)-O(4) bond length is 1.25 Å. In the sixth C site, C(1) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(5) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-C(5) bond length is 1.53 Å. In the seventh C site, C(2) is bonded in a 3-coordinate geometry to one N(1) and two equivalent H(1,2) atoms. The C(2)-N(1) bond length is 1.47 Å. Both C(2)-H(1,2) bond lengths are 0.97 Å. In the eighth C site, C(3) is bonded in a distorted single-bond geometry to one C(1), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(3) bond length is 0.93 Å. In the ninth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(13), one C(3), and one N(2) atom. The C(4)-N(2) bond length is 1.42 Å. In the tenth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(5)-O(1) bond length is 1.25 Å. The C(5)-O(2) bond length is 1.25 Å. In the eleventh C site, C(6) is bonded in a 3-coordinate geometry to one C(7), one N(3), and one H(4) atom. The C(6)-C(7) bond length is 1.37 Å. The C(6)-N(3) bond length is 1.40 Å. The C(6)-H(4) bond length is 0.93 Å. In the twelfth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(6), one N(1), and one H(5) atom. The C(7)-N(1) bond length is 1.33 Å. The C(7)-H(5) bond length is 0.93 Å. In the thirteenth C site, C(8) is bonded in a trigonal non-coplanar geometry to one C(9); one H(6); and two equivalent H(7,8) atoms. The C(8)-H(6) bond length is 0.96 Å. Both C(8)-H(7,8) bond lengths are 0.96 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(2), one C(7), and one C(9) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(4) and one N(2) atom. The N(2)-N(2) bond length is 1.24 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(1), one C(6), and one C(9) atom. There are eight inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(8) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(5) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(14) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(14) atom. Linkers: 4 Cc1nccn1CCCCCCn1ccnc1C ,4 [O]C(=O)c1cc([N][N]c2cc(C([O])=O)cc(C([O])=O)c2)cc(C([O])=O)c1. Metal clusters: 4 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 5.51 A, density 1.28 g/cm3, surface area 4516.51 m2/g, accessible volume 0.28 cm3/g