Mn2Cu3C55H39(NO3)6Mn2Cu3C56H35(NO3)6(CH)10(CH3)23 crystallizes in the orthorhombic P2_12_12_1 space group. The structure consists of forty 02329_fluka molecules, ninety-two 02329_fluka molecules, one Mn2Cu3C55H39(NO3)6 framework, and one Mn2Cu3C56H35(NO3)6 framework. In the Mn2Cu3C55H39(NO3)6 framework, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in an octahedral geometry to one O(2), one O(3), one O(4), one O(5), one O(6), and one O(7) atom. The Mn(1)-O(2) bond length is 2.13 Å. The Mn(1)-O(3) bond length is 2.15 Å. The Mn(1)-O(4) bond length is 2.13 Å. The Mn(1)-O(5) bond length is 2.19 Å. The Mn(1)-O(6) bond length is 2.08 Å. The Mn(1)-O(7) bond length is 2.18 Å. In the second Mn site, Mn(2) is bonded in an octahedral geometry to one O(12), one O(13), one O(14), one O(15), one O(16), and one O(17) atom. The Mn(2)-O(12) bond length is 2.15 Å. The Mn(2)-O(13) bond length is 2.20 Å. The Mn(2)-O(14) bond length is 2.22 Å. The Mn(2)-O(15) bond length is 2.19 Å. The Mn(2)-O(16) bond length is 2.12 Å. The Mn(2)-O(17) bond length is 2.15 Å. There are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a square co-planar geometry to one N(1), one N(6), one O(1), and one O(18) atom. The Cu(1)-N(1) bond length is 1.96 Å. The Cu(1)-N(6) bond length is 1.94 Å. The Cu(1)-O(1) bond length is 1.92 Å. The Cu(1)-O(18) bond length is 1.92 Å. In the second Cu site, Cu(2) is bonded in a square co-planar geometry to one N(2), one N(4), one O(10), and one O(8) atom. The Cu(2)-N(2) bond length is 1.93 Å. The Cu(2)-N(4) bond length is 1.94 Å. The Cu(2)-O(10) bond length is 1.96 Å. The Cu(2)-O(8) bond length is 1.97 Å. In the third Cu site, Cu(3) is bonded in a distorted square pyramidal geometry to one N(3), one N(5), one H(36), one O(11), and one O(9) atom. The Cu(3)-N(3) bond length is 1.92 Å. The Cu(3)-N(5) bond length is 1.94 Å. The Cu(3)-H(36) bond length is 1.88 Å. The Cu(3)-O(11) bond length is 1.97 Å. The Cu(3)-O(9) bond length is 1.91 Å. There are fifty-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(2) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-O(2) bond length is 1.29 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(4), one C(5), and one N(1) atom. The C(2)-C(4) bond length is 1.39 Å. The C(2)-C(5) bond length is 1.39 Å. The C(2)-N(1) bond length is 1.36 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(3)-O(1) bond length is 1.28 Å. The C(3)-O(3) bond length is 1.24 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(4)-C(6) bond length is 1.39 Å. The C(4)-C(7) bond length is 1.62 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(8), and one C(9) atom. The C(5)-C(8) bond length is 1.39 Å. The C(5)-C(9) bond length is 1.57 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(1) atom. The C(6)-H(1) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a water-like geometry to one C(4), one H(2), and one H(3) atom. The C(7)-H(2) bond length is 0.97 Å. The C(7)-H(3) bond length is 0.97 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(5) and one H(4,45) atom. The C(8)-H(4,45) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a water-like geometry to one C(5) and two equivalent H(5,6) atoms. Both C(9)-H(5,6) bond lengths are 0.97 Å. In the tenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(2) and one O(4) atom. The C(13)-N(2) bond length is 1.33 Å. The C(13)-O(4) bond length is 1.22 Å. In the eleventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(8) atom. The C(14)-O(5) bond length is 1.32 Å. The C(14)-O(8) bond length is 1.21 Å. In the twelfth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one O(6) atom. The C(15)-N(3) bond length is 1.39 Å. The C(15)-O(6) bond length is 1.32 Å. In the thirteenth C site, C(16) is bonded in a 2-coordinate geometry to one O(7) and one O(9) atom. The C(16)-O(7) bond length is 1.21 Å. The C(16)-O(9) bond length is 1.36 Å. In the fourteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(19), one C(20), and one N(2) atom. The C(17)-C(19) bond length is 1.39 Å. The C(17)-C(20) bond length is 1.39 Å. The C(17)-N(2) bond length is 1.50 Å. In the fifteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(21), one C(22), and one N(3) atom. The C(18)-C(21) bond length is 1.39 Å. The C(18)-C(22) bond length is 1.39 Å. The C(18)-N(3) bond length is 1.36 Å. In the sixteenth C site, C(19) is bonded in a trigonal planar geometry to one C(17), one C(23), and one C(24) atom. The C(19)-C(23) bond length is 1.39 Å. The C(19)-C(24) bond length is 1.59 Å. In the seventeenth C site, C(20) is bonded in a trigonal planar geometry to one C(17), one C(25), and one C(26) atom. The C(20)-C(25) bond length is 1.39 Å. The C(20)-C(26) bond length is 1.58 Å. In the eighteenth C site, C(21) is bonded in a trigonal planar geometry to one C(18), one C(30), and one C(31) atom. The C(21)-C(30) bond length is 1.39 Å. The C(21)-C(31) bond length is 1.52 Å. In the nineteenth C site, C(22) is bonded in a trigonal planar geometry to one C(18), one C(32), and one C(33) atom. The C(22)-C(32) bond length is 1.39 Å. The C(22)-C(33) bond length is 1.56 Å. In the twentieth C site, C(23) is bonded in a distorted single-bond geometry to one C(19) and one H(14) atom. The C(23)-H(14) bond length is 0.93 Å. In the twenty-first C site, C(24) is bonded in a water-like geometry to one C(19) and two equivalent H(15,16) atoms. Both C(24)-H(15,16) bond lengths are 0.97 Å. In the twenty-second C site, C(25) is bonded in a single-bond geometry to one C(20) and one H(17) atom. The C(25)-H(17) bond length is 0.93 Å. In the twenty-third C site, C(26) is bonded in a water-like geometry to one C(20) and two equivalent H(18,19) atoms. Both C(26)-H(18,19) bond lengths are 0.97 Å. In the twenty-fourth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(4) and one O(12) atom. The C(27)-N(4) bond length is 1.29 Å. The C(27)-O(12) bond length is 1.26 Å. In the twenty-fifth C site, C(28) is bonded in a distorted single-bond geometry to one C(37), one C(38), and one N(4) atom. The C(28)-C(37) bond length is 1.39 Å. The C(28)-C(38) bond length is 1.39 Å. The C(28)-N(4) bond length is 1.43 Å. In the twenty-sixth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(13) atom. The C(29)-O(10) bond length is 1.27 Å. The C(29)-O(13) bond length is 1.27 Å. In the twenty-seventh C site, C(30) is bonded in a single-bond geometry to one C(21) and one H(20,42) atom. The C(30)-H(20,42) bond length is 0.93 Å. In the twenty-eighth C site, C(31) is bonded in a water-like geometry to one C(21), one H(21), and one H(22) atom. The C(31)-H(21) bond length is 0.97 Å. The C(31)-H(22) bond length is 0.97 Å. In the twenty-ninth C site, C(32) is bonded in a distorted single-bond geometry to one C(22) and one H(23) atom. The C(32)-H(23) bond length is 0.93 Å. In the thirtieth C site, C(33) is bonded in a water-like geometry to one C(22), one H(24), and one H(25) atom. The C(33)-H(24) bond length is 0.97 Å. The C(33)-H(25) bond length is 0.97 Å. In the thirty-first C site, C(37) is bonded in a trigonal planar geometry to one C(28), one C(42), and one C(43) atom. The C(37)-C(42) bond length is 1.43 Å. The C(37)-C(43) bond length is 1.39 Å. In the thirty-second C site, C(38) is bonded in a trigonal planar geometry to one C(28), one C(44), and one C(45) atom. The C(38)-C(44) bond length is 1.52 Å. The C(38)-C(45) bond length is 1.39 Å. In the thirty-third C site, C(40) is bonded in a trigonal non-coplanar geometry to one H(34), one H(35), and one H(36) atom. The C(40)-H(34) bond length is 0.96 Å. The C(40)-H(35) bond length is 0.96 Å. The C(40)-H(36) bond length is 0.96 Å. In the thirty-fourth C site, C(42) is bonded in a water-like geometry to one C(37), one H(40), and one H(41) atom. The C(42)-H(40) bond length is 0.97 Å. The C(42)-H(41) bond length is 0.97 Å. In the thirty-fifth C site, C(43) is bonded in a distorted single-bond geometry to one C(37) and one H(20,42) atom. The C(43)-H(20,42) bond length is 0.93 Å. In the thirty-sixth C site, C(44) is bonded in a water-like geometry to one C(38) and two equivalent H(43,44) atoms. Both C(44)-H(43,44) bond lengths are 0.97 Å. In the thirty-seventh C site, C(45) is bonded in a distorted single-bond geometry to one C(38) and one H(4,45) atom. The C(45)-H(4,45) bond length is 0.93 Å. In the thirty-eighth C site, C(49) is bonded in a distorted bent 120 degrees geometry to one O(14) and one O(18) atom. The C(49)-O(14) bond length is 1.22 Å. The C(49)-O(18) bond length is 1.28 Å. In the thirty-ninth C site, C(50) is bonded in a distorted bent 120 degrees geometry to one N(6) and one O(15) atom. The C(50)-N(6) bond length is 1.32 Å. The C(50)-O(15) bond length is 1.25 Å. In the fortieth C site, C(51) is bonded in a distorted bent 120 degrees geometry to one N(5) and one O(16) atom. The C(51)-N(5) bond length is 1.33 Å. The C(51)-O(16) bond length is 1.23 Å. In the forty-first C site, C(52) is bonded in a distorted bent 120 degrees geometry to one O(11) and one O(17) atom. The C(52)-O(11) bond length is 1.30 Å. The C(52)-O(17) bond length is 1.26 Å. In the forty-second C site, C(53) is bonded in a distorted single-bond geometry to one C(55), one C(56), and one N(6) atom. The C(53)-C(55) bond length is 1.39 Å. The C(53)-C(56) bond length is 1.39 Å. The C(53)-N(6) bond length is 1.43 Å. In the forty-third C site, C(54) is bonded in a distorted single-bond geometry to one C(57), one C(58), and one N(5) atom. The C(54)-C(57) bond length is 1.39 Å. The C(54)-C(58) bond length is 1.39 Å. The C(54)-N(5) bond length is 1.46 Å. In the forty-fourth C site, C(55) is bonded in a trigonal planar geometry to one C(53), one C(59), and one C(60) atom. The C(55)-C(59) bond length is 1.57 Å. The C(55)-C(60) bond length is 1.39 Å. In the forty-fifth C site, C(56) is bonded in a trigonal planar geometry to one C(53), one C(61), and one C(62) atom. The C(56)-C(61) bond length is 1.39 Å. The C(56)-C(62) bond length is 1.49 Å. In the forty-sixth C site, C(57) is bonded in a trigonal planar geometry to one C(54), one C(63), and one C(64) atom. The C(57)-C(63) bond length is 1.44 Å. The C(57)-C(64) bond length is 1.39 Å. In the forty-seventh C site, C(58) is bonded in a trigonal planar geometry to one C(54), one C(65), and one C(66) atom. The C(58)-C(65) bond length is 1.56 Å. The C(58)-C(66) bond length is 1.39 Å. In the forty-eighth C site, C(59) is bonded in a water-like geometry to one C(55) and two equivalent H(53,54) atoms. Both C(59)-H(53,54) bond lengths are 0.97 Å. In the forty-ninth C site, C(60) is bonded in a distorted single-bond geometry to one C(55) and one H(55) atom. The C(60)-H(55) bond length is 0.93 Å. In the fiftieth C site, C(61) is bonded in a distorted single-bond geometry to one C(56) and one H(56) atom. The C(61)-H(56) bond length is 0.93 Å. In the fifty-first C site, C(62) is bonded in a water-like geometry to one C(56), one H(57), and one H(58) atom. The C(62)-H(57) bond length is 0.97 Å. The C(62)-H(58) bond length is 0.97 Å. In the fifty-second C site, C(63) is bonded in a distorted water-like geometry to one C(57) and two equivalent H(59,60) atoms. Both C(63)-H(59,60) bond lengths are 0.97 Å. In the fifty-third C site, C(64) is bonded in a single-bond geometry to one C(57) and one H(61) atom. The C(64)-H(61) bond length is 0.93 Å. In the fifty-fourth C site, C(65) is bonded in a water-like geometry to one C(58) and two equivalent H(62,63) atoms. Both C(65)-H(62,63) bond lengths are 0.97 Å. In the fifty-fifth C site, C(66) is bonded in a distorted single-bond geometry to one C(58) and one H(64) atom. The C(66)-H(64) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(13), and one C(17) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cu(3), one C(15), and one C(18) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Cu(2), one C(27), and one C(28) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cu(3), one C(51), and one C(54) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(50), and one C(53) atom. There are thirty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4,45) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(23) atom. In the seventh H site, H(15,16) is bonded in a single-bond geometry to one C(24) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the ninth H site, H(18,19) is bonded in a single-bond geometry to one C(26) atom. In the tenth H site, H(20,42) is bonded in a single-bond geometry to one C(30) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(31) atom. In the twelfth H site, H(22) is bonded in a single-bond geometry to one C(31) atom. In the thirteenth H site, H(23) is bonded in a single-bond geometry to one C(32) atom. In the fourteenth H site, H(24) is bonded in a single-bond geometry to one C(33) atom. In the fifteenth H site, H(25) is bonded in a single-bond geometry to one C(33) atom. In the sixteenth H site, H(34) is bonded in a single-bond geometry to one C(40) atom. In the seventeenth H site, H(35) is bonded in a single-bond geometry to one C(40) atom. In the eighteenth H site, H(36) is bonded in a single-bond geometry to one Cu(3) and one C(40) atom. In the nineteenth H site, H(40) is bonded in a single-bond geometry to one C(42) atom. In the twentieth H site, H(41) is bonded in a single-bond geometry to one C(42) atom. In the twenty-first H site, H(43,44) is bonded in a single-bond geometry to one C(44) atom. In the twenty-second H site, H(53,54) is bonded in a single-bond geometry to one C(59) atom. In the twenty-third H site, H(55) is bonded in a single-bond geometry to one C(60) atom. In the twenty-fourth H site, H(56) is bonded in a single-bond geometry to one C(61) atom. In the twenty-fifth H site, H(57) is bonded in a single-bond geometry to one C(62) atom. In the twenty-sixth H site, H(58) is bonded in a single-bond geometry to one C(62) atom. In the twenty-seventh H site, H(59,60) is bonded in a single-bond geometry to one C(63) atom. In the twenty-eighth H site, H(61) is bonded in a single-bond geometry to one C(64) atom. In the twenty-ninth H site, H(62,63) is bonded in a single-bond geometry to one C(65) atom. In the thirtieth H site, H(64) is bonded in a single-bond geometry to one C(66) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(3) atom. In the second O site, O(2) is bonded in a water-like geometry to one Mn(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(13) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(14) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one Mn(1) and one C(15) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Mn(1) and one C(16) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Cu(2) and one C(14) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Cu(3) and one C(16) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Cu(2) and one C(29) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Cu(3) and one C(52) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one Mn(2) and one C(27) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one Mn(2) and one C(29) atom. In the fourteenth O site, O(14) is bonded in a water-like geometry to one Mn(2) and one C(49) atom. In the fifteenth O site, O(15) is bonded in a distorted water-like geometry to one Mn(2) and one C(50) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(51) atom. In the seventeenth O site, O(17) is bonded in a water-like geometry to one Mn(2) and one C(52) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(49) atom. In the Mn2Cu3C56H35(NO3)6 framework, there are two inequivalent Mn sites. In the first Mn site, Mn(3) is bonded in an octahedral geometry to one O(20), one O(21), one O(23), one O(24), one O(25), and one O(26) atom. The Mn(3)-O(20) bond length is 2.19 Å. The Mn(3)-O(21) bond length is 2.09 Å. The Mn(3)-O(23) bond length is 2.30 Å. The Mn(3)-O(24) bond length is 2.17 Å. The Mn(3)-O(25) bond length is 2.22 Å. The Mn(3)-O(26) bond length is 2.16 Å. In the second Mn site, Mn(4) is bonded in an octahedral geometry to one O(29), one O(30), one O(31), one O(32), one O(34), and one O(35) atom. The Mn(4)-O(29) bond length is 2.16 Å. The Mn(4)-O(30) bond length is 2.20 Å. The Mn(4)-O(31) bond length is 2.16 Å. The Mn(4)-O(32) bond length is 2.18 Å. The Mn(4)-O(34) bond length is 2.12 Å. The Mn(4)-O(35) bond length is 2.22 Å. There are three inequivalent Cu sites. In the first Cu site, Cu(4) is bonded in a rectangular see-saw-like geometry to one N(11), one N(7), one O(19), and one O(33) atom. The Cu(4)-N(11) bond length is 1.97 Å. The Cu(4)-N(7) bond length is 1.94 Å. The Cu(4)-O(19) bond length is 1.96 Å. The Cu(4)-O(33) bond length is 1.96 Å. In the second Cu site, Cu(5) is bonded in a rectangular see-saw-like geometry to one N(10), one N(9), one O(27), and one O(28) atom. The Cu(5)-N(10) bond length is 1.91 Å. The Cu(5)-N(9) bond length is 1.89 Å. The Cu(5)-O(27) bond length is 1.93 Å. The Cu(5)-O(28) bond length is 1.89 Å. In the third Cu site, Cu(6) is bonded in a rectangular see-saw-like geometry to one N(12), one N(8), one O(22), and one O(36) atom. The Cu(6)-N(12) bond length is 1.89 Å. The Cu(6)-N(8) bond length is 1.95 Å. The Cu(6)-O(22) bond length is 1.98 Å. The Cu(6)-O(36) bond length is 1.94 Å. There are fifty-six inequivalent C sites. In the first C site, C(73) is bonded in a distorted bent 120 degrees geometry to one O(19) and one O(20) atom. The C(73)-O(19) bond length is 1.20 Å. The C(73)-O(20) bond length is 1.31 Å. In the second C site, C(74) is bonded in a distorted bent 120 degrees geometry to one N(7) and one O(21) atom. The C(74)-N(7) bond length is 1.31 Å. The C(74)-O(21) bond length is 1.30 Å. In the third C site, C(75) is bonded in a trigonal planar geometry to one C(76), one C(80), and one C(82) atom. The C(75)-C(76) bond length is 1.39 Å. The C(75)-C(80) bond length is 1.39 Å. The C(75)-C(82) bond length is 1.58 Å. In the fourth C site, C(76) is bonded in a distorted single-bond geometry to one C(75), one C(77), and one N(7) atom. The C(76)-C(77) bond length is 1.39 Å. The C(76)-N(7) bond length is 1.49 Å. In the fifth C site, C(77) is bonded in a trigonal planar geometry to one C(76), one C(78), and one C(81) atom. The C(77)-C(78) bond length is 1.39 Å. The C(77)-C(81) bond length is 1.60 Å. In the sixth C site, C(78) is bonded in a distorted single-bond geometry to one C(77), one C(79), and one H(79) atom. The C(78)-C(79) bond length is 1.39 Å. The C(78)-H(79) bond length is 0.93 Å. In the seventh C site, C(79) is bonded in a distorted trigonal planar geometry to one C(78), one C(80), and one H(80) atom. The C(79)-C(80) bond length is 1.39 Å. The C(79)-H(80) bond length is 0.93 Å. In the eighth C site, C(80) is bonded in a distorted single-bond geometry to one C(75), one C(79), and one H(81) atom. The C(80)-H(81) bond length is 0.93 Å. In the ninth C site, C(81) is bonded in a water-like geometry to one C(77), one H(82), and one H(83) atom. The C(81)-H(82) bond length is 0.97 Å. The C(81)-H(83) bond length is 0.97 Å. In the tenth C site, C(82) is bonded in a water-like geometry to one C(75), one H(84), and one H(85) atom. The C(82)-H(84) bond length is 0.97 Å. The C(82)-H(85) bond length is 0.97 Å. In the eleventh C site, C(85) is bonded in a distorted bent 120 degrees geometry to one O(22) and one O(23) atom. The C(85)-O(22) bond length is 1.14 Å. The C(85)-O(23) bond length is 1.27 Å. In the twelfth C site, C(86) is bonded in a distorted bent 120 degrees geometry to one N(8) and one O(24) atom. The C(86)-N(8) bond length is 1.33 Å. The C(86)-O(24) bond length is 1.30 Å. In the thirteenth C site, C(87) is bonded in a water-like geometry to one C(93) and two equivalent H(92,93) atoms. The C(87)-C(93) bond length is 1.58 Å. Both C(87)-H(92,93) bond lengths are 0.97 Å. In the fourteenth C site, C(88) is bonded in a distorted single-bond geometry to one C(89), one C(93), and one N(8) atom. The C(88)-C(89) bond length is 1.39 Å. The C(88)-C(93) bond length is 1.39 Å. The C(88)-N(8) bond length is 1.30 Å. In the fifteenth C site, C(89) is bonded in a trigonal planar geometry to one C(88), one C(90), and one C(95) atom. The C(89)-C(90) bond length is 1.39 Å. The C(89)-C(95) bond length is 1.57 Å. In the sixteenth C site, C(90) is bonded in a single-bond geometry to one C(89) and one H(94) atom. The C(90)-H(94) bond length is 0.93 Å. In the seventeenth C site, C(92) is bonded in a distorted single-bond geometry to one C(93) and one H(96) atom. The C(92)-C(93) bond length is 1.39 Å. The C(92)-H(96) bond length is 0.93 Å. In the eighteenth C site, C(93) is bonded in a trigonal planar geometry to one C(87), one C(88), and one C(92) atom. In the nineteenth C site, C(95) is bonded in a water-like geometry to one C(89) and two equivalent H(100,101) atoms. Both C(95)-H(100,101) bond lengths are 0.97 Å. In the twentieth C site, C(97) is bonded in a distorted bent 120 degrees geometry to one O(26) and one O(27) atom. The C(97)-O(26) bond length is 1.37 Å. The C(97)-O(27) bond length is 1.29 Å. In the twenty-first C site, C(98) is bonded in a distorted bent 120 degrees geometry to one N(9) and one O(25) atom. The C(98)-N(9) bond length is 1.37 Å. The C(98)-O(25) bond length is 1.27 Å. In the twenty-second C site, C(99) is bonded in a distorted single-bond geometry to one C(100), one C(104), and one N(9) atom. The C(99)-C(100) bond length is 1.39 Å. The C(99)-C(104) bond length is 1.39 Å. The C(99)-N(9) bond length is 1.43 Å. In the twenty-third C site, C(100) is bonded in a trigonal planar geometry to one C(101), one C(106), and one C(99) atom. The C(100)-C(101) bond length is 1.39 Å. The C(100)-C(106) bond length is 1.56 Å. In the twenty-fourth C site, C(101) is bonded in a distorted single-bond geometry to one C(100) and one H(105) atom. The C(101)-H(105) bond length is 0.93 Å. In the twenty-fifth C site, C(103) is bonded in a distorted single-bond geometry to one C(104) and one H(107) atom. The C(103)-C(104) bond length is 1.39 Å. The C(103)-H(107) bond length is 0.93 Å. In the twenty-sixth C site, C(104) is bonded in a trigonal planar geometry to one C(103), one C(105), and one C(99) atom. The C(104)-C(105) bond length is 1.59 Å. In the twenty-seventh C site, C(105) is bonded in a water-like geometry to one C(104) and two equivalent H(108,109) atoms. Both C(105)-H(108,109) bond lengths are 0.97 Å. In the twenty-eighth C site, C(106) is bonded in a water-like geometry to one C(100), one H(110), and one H(111) atom. The C(106)-H(110) bond length is 0.97 Å. The C(106)-H(111) bond length is 0.97 Å. In the twenty-ninth C site, C(109) is bonded in a distorted bent 120 degrees geometry to one O(28) and one O(29) atom. The C(109)-O(28) bond length is 1.33 Å. The C(109)-O(29) bond length is 1.19 Å. In the thirtieth C site, C(110) is bonded in a distorted bent 120 degrees geometry to one N(10) and one O(30) atom. The C(110)-N(10) bond length is 1.33 Å. The C(110)-O(30) bond length is 1.22 Å. In the thirty-first C site, C(111) is bonded in a distorted single-bond geometry to one C(112), one C(116), and one N(10) atom. The C(111)-C(112) bond length is 1.40 Å. The C(111)-C(116) bond length is 1.46 Å. The C(111)-N(10) bond length is 1.44 Å. In the thirty-second C site, C(112) is bonded in a trigonal planar geometry to one C(111), one C(113), and one C(117) atom. The C(112)-C(113) bond length is 1.41 Å. The C(112)-C(117) bond length is 1.51 Å. In the thirty-third C site, C(113) is bonded in a bent 120 degrees geometry to one C(112) and one C(114) atom. The C(113)-C(114) bond length is 1.45 Å. In the thirty-fourth C site, C(114) is bonded in a bent 120 degrees geometry to one C(113) and one C(115) atom. The C(114)-C(115) bond length is 1.31 Å. In the thirty-fifth C site, C(115) is bonded in a bent 120 degrees geometry to one C(114) and one C(116) atom. The C(115)-C(116) bond length is 1.37 Å. In the thirty-sixth C site, C(116) is bonded in a trigonal planar geometry to one C(111), one C(115), and one C(118) atom. The C(116)-C(118) bond length is 1.52 Å. In the thirty-seventh C site, C(117) is bonded in a water-like geometry to one C(112) and two equivalent H(118,119) atoms. Both C(117)-H(118,119) bond lengths are 0.97 Å. In the thirty-eighth C site, C(118) is bonded in a water-like geometry to one C(116), one H(120), and one H(121) atom. The C(118)-H(120) bond length is 0.97 Å. The C(118)-H(121) bond length is 0.97 Å. In the thirty-ninth C site, C(121) is bonded in a distorted bent 120 degrees geometry to one O(32) and one O(33) atom. The C(121)-O(32) bond length is 1.24 Å. The C(121)-O(33) bond length is 1.31 Å. In the fortieth C site, C(122) is bonded in a distorted bent 120 degrees geometry to one N(11) and one O(31) atom. The C(122)-N(11) bond length is 1.27 Å. The C(122)-O(31) bond length is 1.30 Å. In the forty-first C site, C(123) is bonded in a distorted single-bond geometry to one C(124), one C(128), and one N(11) atom. The C(123)-C(124) bond length is 1.39 Å. The C(123)-C(128) bond length is 1.39 Å. The C(123)-N(11) bond length is 1.39 Å. In the forty-second C site, C(124) is bonded in a trigonal planar geometry to one C(123), one C(125), and one C(130) atom. The C(124)-C(125) bond length is 1.39 Å. The C(124)-C(130) bond length is 1.53 Å. In the forty-third C site, C(125) is bonded in a distorted single-bond geometry to one C(124) and one H(128) atom. The C(125)-H(128) bond length is 0.93 Å. In the forty-fourth C site, C(127) is bonded in a distorted single-bond geometry to one C(128) and one H(130) atom. The C(127)-C(128) bond length is 1.39 Å. The C(127)-H(130) bond length is 0.93 Å. In the forty-fifth C site, C(128) is bonded in a trigonal planar geometry to one C(123), one C(127), and one C(129) atom. The C(128)-C(129) bond length is 1.52 Å. In the forty-sixth C site, C(129) is bonded in a water-like geometry to one C(128) and two equivalent H(131,132) atoms. Both C(129)-H(131,132) bond lengths are 0.97 Å. In the forty-seventh C site, C(130) is bonded in a water-like geometry to one C(124) and two equivalent H(133,134) atoms. Both C(130)-H(133,134) bond lengths are 0.97 Å. In the forty-eighth C site, C(133) is bonded in a distorted bent 120 degrees geometry to one O(35) and one O(36) atom. The C(133)-O(35) bond length is 1.27 Å. The C(133)-O(36) bond length is 1.34 Å. In the forty-ninth C site, C(134) is bonded in a distorted bent 120 degrees geometry to one N(12) and one O(34) atom. The C(134)-N(12) bond length is 1.41 Å. The C(134)-O(34) bond length is 1.22 Å. In the fiftieth C site, C(135) is bonded in a distorted trigonal planar geometry to one C(136), one C(140), and one N(12) atom. The C(135)-C(136) bond length is 1.39 Å. The C(135)-C(140) bond length is 1.39 Å. The C(135)-N(12) bond length is 1.56 Å. In the fifty-first C site, C(136) is bonded in a trigonal planar geometry to one C(135), one C(137), and one C(141) atom. The C(136)-C(137) bond length is 1.39 Å. The C(136)-C(141) bond length is 1.60 Å. In the fifty-second C site, C(137) is bonded in a single-bond geometry to one C(136) and one H(141) atom. The C(137)-H(141) bond length is 0.93 Å. In the fifty-third C site, C(139) is bonded in a distorted single-bond geometry to one C(140) and one H(143) atom. The C(139)-C(140) bond length is 1.39 Å. The C(139)-H(143) bond length is 0.93 Å. In the fifty-fourth C site, C(140) is bonded in a trigonal planar geometry to one C(135), one C(139), and one C(142) atom. The C(140)-C(142) bond length is 1.63 Å. In the fifty-fifth C site, C(141) is bonded in a water-like geometry to one C(136), one H(144), and one H(145) atom. The C(141)-H(144) bond length is 0.97 Å. The C(141)-H(145) bond length is 0.97 Å. In the fifty-sixth C site, C(142) is bonded in a water-like geometry to one C(140) and two equivalent H(146,147) atoms. Both C(142)-H(146,147) bond lengths are 0.97 Å. There are six inequivalent N sites. In the first N site, N(7) is bonded in a trigonal planar geometry to one Cu(4), one C(74), and one C(76) atom. In the second N site, N(8) is bonded in a trigonal planar geometry to one Cu(6), one C(86), and one C(88) atom. In the third N site, N(9) is bonded in a trigonal planar geometry to one Cu(5), one C(98), and one C(99) atom. In the fourth N site, N(10) is bonded in a trigonal planar geometry to one Cu(5), one C(110), and one C(111) atom. In the fifth N site, N(11) is bonded in a trigonal planar geometry to one Cu(4), one C(122), and one C(123) atom. In the sixth N site, N(12) is bonded in a trigonal planar geometry to one Cu(6), one C(134), and one C(135) atom. There are twenty-eight inequivalent H sites. In the first H site, H(79) is bonded in a single-bond geometry to one C(78) atom. In the second H site, H(80) is bonded in a single-bond geometry to one C(79) atom. In the third H site, H(81) is bonded in a single-bond geometry to one C(80) atom. In the fourth H site, H(82) is bonded in a single-bond geometry to one C(81) atom. In the fifth H site, H(83) is bonded in a single-bond geometry to one C(81) atom. In the sixth H site, H(84) is bonded in a single-bond geometry to one C(82) atom. In the seventh H site, H(85) is bonded in a single-bond geometry to one C(82) atom. In the eighth H site, H(92,93) is bonded in a single-bond geometry to one C(87) atom. In the ninth H site, H(94) is bonded in a single-bond geometry to one C(90) atom. In the tenth H site, H(96) is bonded in a single-bond geometry to one C(92) atom. In the eleventh H site, H(100,101) is bonded in a single-bond geometry to one C(95) atom. In the twelfth H site, H(105) is bonded in a single-bond geometry to one C(101) atom. In the thirteenth H site, H(107) is bonded in a single-bond geometry to one C(103) atom. In the fourteenth H site, H(108,109) is bonded in a single-bond geometry to one C(105) atom. In the fifteenth H site, H(110) is bonded in a single-bond geometry to one C(106) atom. In the sixteenth H site, H(111) is bonded in a single-bond geometry to one C(106) atom. In the seventeenth H site, H(118,119) is bonded in a single-bond geometry to one C(117) atom. In the eighteenth H site, H(120) is bonded in a single-bond geometry to one C(118) atom. In the nineteenth H site, H(121) is bonded in a single-bond geometry to one C(118) atom. In the twentieth H site, H(128) is bonded in a single-bond geometry to one C(125) atom. In the twenty-first H site, H(130) is bonded in a single-bond geometry to one C(127) atom. In the twenty-second H site, H(131,132) is bonded in a single-bond geometry to one C(129) atom. In the twenty-third H site, H(133,134) is bonded in a single-bond geometry to one C(130) atom. In the twenty-fourth H site, H(141) is bonded in a single-bond geometry to one C(137) atom. In the twenty-fifth H site, H(143) is bonded in a single-bond geometry to one C(139) atom. In the twenty-sixth H site, H(144) is bonded in a single-bond geometry to one C(141) atom. In the twenty-seventh H site, H(145) is bonded in a single-bond geometry to one C(141) atom. In the twenty-eighth H site, H(146,147) is bonded in a single-bond geometry to one C(142) atom. There are eighteen inequivalent O sites. In the first O site, O(19) is bonded in a water-like geometry to one Cu(4) and one C(73) atom. In the second O site, O(20) is bonded in a water-like geometry to one Mn(3) and one C(73) atom. In the third O site, O(21) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(74) atom. In the fourth O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Cu(6) and one C(85) atom. In the fifth O site, O(23) is bonded in a distorted water-like geometry to one Mn(3) and one C(85) atom. In the sixth O site, O(24) is bonded in a water-like geometry to one Mn(3) and one C(86) atom. In the seventh O site, O(25) is bonded in a distorted water-like geometry to one Mn(3) and one C(98) atom. In the eighth O site, O(26) is bonded in a water-like geometry to one Mn(3) and one C(97) atom. In the ninth O site, O(27) is bonded in a bent 120 degrees geometry to one Cu(5) and one C(97) atom. In the tenth O site, O(28) is bonded in a bent 120 degrees geometry to one Cu(5) and one C(109) atom. In the eleventh O site, O(29) is bonded in a water-like geometry to one Mn(4) and one C(109) atom. In the twelfth O site, O(30) is bonded in a distorted water-like geometry to one Mn(4) and one C(110) atom. In the thirteenth O site, O(31) is bonded in a water-like geometry to one Mn(4) and one C(122) atom. In the fourteenth O site, O(32) is bonded in a water-like geometry to one Mn(4) and one C(121) atom. In the fifteenth O site, O(33) is bonded in a water-like geometry to one Cu(4) and one C(121) atom. In the sixteenth O site, O(34) is bonded in a water-like geometry to one Mn(4) and one C(134) atom. In the seventeenth O site, O(35) is bonded in a water-like geometry to one Mn(4) and one C(133) atom. In the eighteenth O site, O(36) is bonded in a bent 120 degrees geometry to one Cu(6) and one C(133) atom. Linkers: 44 CCc1cccc(CC)c1[N]C(=O)C([O])=O ,4 CCc1[c][c][c]c(CC)c1[N]C(=O)C([O])=O. Metal clusters: 16 [Mn] ,24 [Cu]. The MOF has largest included sphere 7.15 A, density 0.90 g/cm3, surface area 4918.77 m2/g, accessible volume 0.66 cm3/g