ZnC20NH14(O2F3)2 crystallizes in the tetragonal I4_1/amd space group. Zn(1) is bonded in a square pyramidal geometry to one N(1), two equivalent O(1), and two equivalent O(2) atoms. The Zn(1)-N(1) bond length is 2.04 Å. Both Zn(1)-O(1) bond lengths are 2.02 Å. Both Zn(1)-O(2) bond lengths are 2.02 Å. There are eleven inequivalent C sites. In the first C site, C(8) is bonded in a distorted single-bond geometry to one C(1), one C(4), and one H(4) atom. The C(8)-C(1) bond length is 1.40 Å. The C(8)-C(4) bond length is 1.36 Å. The C(8)-H(4) bond length is 0.95 Å. In the second C site, C(9) is bonded in a bent 120 degrees geometry to one C(7), one O(1), and one O(2) atom. The C(9)-C(7) bond length is 1.51 Å. The C(9)-O(1) bond length is 1.25 Å. The C(9)-O(2) bond length is 1.24 Å. In the third C site, C(10) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent H(1,5,7) atoms. The C(10)-N(1) bond length is 1.47 Å. Both C(10)-H(1,5,7) bond lengths are 0.99 Å. In the fourth C site, C(11) is bonded in a tetrahedral geometry to two equivalent C(1) and two equivalent C(2) atoms. Both C(11)-C(1) bond lengths are 1.52 Å. Both C(11)-C(2) bond lengths are 1.53 Å. In the fifth C site, C(1) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(8) atom. The C(1)-C(6) bond length is 1.36 Å. In the sixth C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one C(11), one F(1), one F(2), and one F(3) atom. The C(2)-F(1) bond length is 1.35 Å. The C(2)-F(2) bond length is 1.38 Å. The C(2)-F(3) bond length is 1.37 Å. In the seventh C site, C(3) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one H(3) atom. The C(3)-C(6) bond length is 1.39 Å. The C(3)-C(7) bond length is 1.34 Å. The C(3)-H(3) bond length is 0.95 Å. In the eighth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(7), one C(8), and one H(6) atom. The C(4)-C(7) bond length is 1.40 Å. The C(4)-H(6) bond length is 0.95 Å. In the ninth C site, C(5) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent H(1,5,7) atoms. The C(5)-N(1) bond length is 1.45 Å. Both C(5)-H(1,5,7) bond lengths are 0.99 Å. In the tenth C site, C(6) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(6)-H(2) bond length is 0.95 Å. In the eleventh C site, C(7) is bonded in a trigonal planar geometry to one C(3), one C(4), and one C(9) atom. N(1) is bonded in a tetrahedral geometry to one Zn(1), one C(10), and two equivalent C(5) atoms. There are five inequivalent H sites. In the first H site, H(1,5,7) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(9) atom. There are three inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(2) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(2) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(2) atom. Linkers: 8 [O]C(=O)c1ccc(C(c2ccc(C([O])=O)cc2)(C(F)(F)F)C(F)(F)F)cc1 ,4 C1CN2CCN1CC2. Metal clusters: 4 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. RCSR code: lvt. The MOF has largest included sphere 9.73 A, density 0.78 g/cm3, surface area 3972.75 m2/g, accessible volume 0.83 cm3/g