Cd5C80H44(NO6)4(CH)4 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules and two Cd5C80H44(NO6)4 clusters. In each Cd5C80H44(NO6)4 cluster, there are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 5-coordinate geometry to one O(10), one O(11), one O(12), one O(2), and one O(8) atom. The Cd(1)-O(10) bond length is 2.17 Å. The Cd(1)-O(11) bond length is 2.59 Å. The Cd(1)-O(12) bond length is 2.28 Å. The Cd(1)-O(2) bond length is 2.24 Å. The Cd(1)-O(8) bond length is 2.23 Å. In the second Cd site, Cd(2) is bonded in a 6-coordinate geometry to one O(11), one O(3), one O(4), one O(5), one O(6), and one O(8) atom. The Cd(2)-O(11) bond length is 2.31 Å. The Cd(2)-O(3) bond length is 2.57 Å. The Cd(2)-O(4) bond length is 2.28 Å. The Cd(2)-O(5) bond length is 2.42 Å. The Cd(2)-O(6) bond length is 2.35 Å. The Cd(2)-O(8) bond length is 2.38 Å. In the third Cd site, Cd(3) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(7), and two equivalent O(9) atoms. Both Cd(3)-O(1) bond lengths are 2.20 Å. Both Cd(3)-O(7) bond lengths are 2.27 Å. Both Cd(3)-O(9) bond lengths are 2.28 Å. There are forty inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one N(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.35 Å. The C(1)-N(1) bond length is 1.42 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.34 Å. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-C(7) bond length is 1.49 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.28 Å. The C(7)-O(2) bond length is 1.24 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one N(1) atom. The C(8)-C(13) bond length is 1.37 Å. The C(8)-C(9) bond length is 1.38 Å. The C(8)-N(1) bond length is 1.44 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(10), one C(8), and one H(5) atom. The C(9)-C(10) bond length is 1.35 Å. The C(9)-H(5) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one C(9), and one H(6) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(6) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.33 Å. The C(11)-C(14) bond length is 1.51 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(12)-H(7) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(13)-H(8) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.23 Å. The C(14)-O(4) bond length is 1.28 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(5), and one O(6) atom. The C(15)-C(16) bond length is 1.51 Å. The C(15)-O(5) bond length is 1.25 Å. The C(15)-O(6) bond length is 1.24 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-C(21) bond length is 1.40 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(9) atom. The C(17)-H(9) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(10) atom. The C(18)-C(19) bond length is 1.37 Å. The C(18)-H(10) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(18), one C(20), and one N(1) atom. The C(19)-C(20) bond length is 1.37 Å. The C(19)-N(1) bond length is 1.43 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(11) atom. The C(20)-H(11) bond length is 0.93 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(12) atom. The C(21)-H(12) bond length is 0.93 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(23), one C(27), and one N(2) atom. The C(22)-C(23) bond length is 1.38 Å. The C(22)-C(27) bond length is 1.36 Å. The C(22)-N(2) bond length is 1.44 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(13) atom. The C(23)-H(13) bond length is 0.93 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(14) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-H(14) bond length is 0.93 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(28) atom. The C(25)-C(26) bond length is 1.37 Å. The C(25)-C(28) bond length is 1.48 Å. In the twenty-sixth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(15) atom. The C(26)-H(15) bond length is 0.93 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(22) and one H(16) atom. The C(27)-H(16) bond length is 0.93 Å. In the twenty-eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(7), and one O(8) atom. The C(28)-O(7) bond length is 1.22 Å. The C(28)-O(8) bond length is 1.28 Å. In the twenty-ninth C site, C(29) is bonded in a distorted single-bond geometry to one N(2) atom. The C(29)-N(2) bond length is 1.39 Å. In the thirtieth C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(18) atom. The C(31)-C(32) bond length is 1.36 Å. The C(31)-H(18) bond length is 0.93 Å. In the thirty-first C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(35) atom. The C(32)-C(33) bond length is 1.37 Å. The C(32)-C(35) bond length is 1.51 Å. In the thirty-second C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(19) atom. The C(33)-H(19) bond length is 0.93 Å. In the thirty-third C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(10), and one O(9) atom. The C(35)-O(10) bond length is 1.29 Å. The C(35)-O(9) bond length is 1.22 Å. In the thirty-fourth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(37), one C(41), and one N(2) atom. The C(36)-C(37) bond length is 1.40 Å. The C(36)-C(41) bond length is 1.36 Å. The C(36)-N(2) bond length is 1.40 Å. In the thirty-fifth C site, C(37) is bonded in a distorted single-bond geometry to one C(36), one C(38), and one H(21) atom. The C(37)-C(38) bond length is 1.40 Å. The C(37)-H(21) bond length is 0.93 Å. In the thirty-sixth C site, C(38) is bonded in a distorted trigonal planar geometry to one C(37), one C(39), and one H(22) atom. The C(38)-C(39) bond length is 1.36 Å. The C(38)-H(22) bond length is 0.93 Å. In the thirty-seventh C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(42) atom. The C(39)-C(40) bond length is 1.38 Å. The C(39)-C(42) bond length is 1.49 Å. In the thirty-eighth C site, C(40) is bonded in a distorted trigonal planar geometry to one C(39), one C(41), and one H(23) atom. The C(40)-C(41) bond length is 1.38 Å. The C(40)-H(23) bond length is 0.93 Å. In the thirty-ninth C site, C(41) is bonded in a distorted single-bond geometry to one C(36), one C(40), and one H(24) atom. The C(41)-H(24) bond length is 0.93 Å. In the fortieth C site, C(42) is bonded in a bent 120 degrees geometry to one C(39), one O(11), and one O(12) atom. The C(42)-O(11) bond length is 1.24 Å. The C(42)-O(12) bond length is 1.23 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(19), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(22), one C(29), and one C(36) atom. There are twenty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(31) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(33) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(37) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(38) atom. In the twenty-first H site, H(23) is bonded in a single-bond geometry to one C(40) atom. In the twenty-second H site, H(24) is bonded in a single-bond geometry to one C(41) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Cd(3) and one C(7) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cd(1) and one C(7) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Cd(2) and one C(14) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cd(2) and one C(14) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Cd(2) and one C(15) atom. In the sixth O site, O(6) is bonded in a distorted single-bond geometry to one Cd(2) and one C(15) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Cd(3) and one C(28) atom. In the eighth O site, O(8) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(2), and one C(28) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Cd(3) and one C(35) atom. In the tenth O site, O(10) is bonded in a water-like geometry to one Cd(1) and one C(35) atom. In the eleventh O site, O(11) is bonded in a 3-coordinate geometry to one Cd(1), one Cd(2), and one C(42) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one Cd(1) and one C(42) atom. Linkers: 8 [O]C(=O)c1ccc(N(c2ccc(C([O])=O)cc2)c2ccc(C([O])=O)cc2)cc1. Metal clusters: 2 O=[C]O[Cd]1(O[C]O[Cd]23O[C]O[Cd]45(O[C]O2)(O[C]O3)O[C]O[Cd](O[C]O[Cd]2(O[C]=O)O[C]O2)(O[C]O4)O[C]O5)O[C]O1. The MOF has largest included sphere 5.37 A, density 1.35 g/cm3, surface area 3797.33 m2/g, accessible volume 0.34 cm3/g