ZnPH6(CO)6(CH2)3 is Indium-derived structured and crystallizes in the hexagonal P6_3 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules and four ZnPH6(CO)6 clusters. In two of the ZnPH6(CO)6 clusters, Zn(1) is bonded in a distorted tetrahedral geometry to one P(1) and three equivalent O(1) atoms. The Zn(1)-P(1) bond length is 2.36 Å. All Zn(1)-O(1) bond lengths are 1.99 Å. There are two inequivalent C sites. In the first C site, C(3) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(3)-O(1) bond length is 1.27 Å. The C(3)-O(2) bond length is 1.23 Å. In the second C site, C(4) is bonded in a distorted water-like geometry to one P(1) and two equivalent H(5,6) atoms. The C(4)-P(1) bond length is 1.81 Å. Both C(4)-H(5,6) bond lengths are 0.97 Å. P(1) is bonded in a tetrahedral geometry to one Zn(1) and three equivalent C(4) atoms. H(5,6) is bonded in a single-bond geometry to one C(4) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(3) atom. In two of the ZnPH6(CO)6 clusters, Zn(2) is bonded in a 4-coordinate geometry to one P(2) and three equivalent O(3) atoms. The Zn(2)-P(2) bond length is 2.39 Å. All Zn(2)-O(3) bond lengths are 2.01 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted water-like geometry to one P(2) and two equivalent H(1,2) atoms. The C(1)-P(2) bond length is 1.84 Å. Both C(1)-H(1,2) bond lengths are 0.97 Å. In the second C site, C(6) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(6)-O(3) bond length is 1.28 Å. The C(6)-O(4) bond length is 1.24 Å. P(2) is bonded in a tetrahedral geometry to one Zn(2) and three equivalent C(1) atoms. H(1,2) is bonded in a single-bond geometry to one C(1) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a water-like geometry to one Zn(2) and one C(6) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(6) atom. Linkers: 7 [O]C(=O)CCP(CCC([O])=O)CCC([O])=O. Metal clusters: 4 O=[C]O[Zn](O[C]=O)O[C]=O. RCSR code: hcb. The MOF has largest included sphere 6.32 A, density 1.19 g/cm3, surface area 4521.99 m2/g, accessible volume 0.32 cm3/g