YbC22H20(NO)8(YbC16H16(NO)8)2(C3H2)22 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twenty-two 2,3-dimethyl-1,3-butadiene molecules; four YbC16H16(NO)8 clusters; and two YbC22H20(NO)8 clusters. In two of the YbC16H16(NO)8 clusters, Yb(2) is bonded in a 8-coordinate geometry to one O(12), one O(14), one O(15), one O(16), one O(17), one O(18), one O(19), and one O(9) atom. The Yb(2)-O(12) bond length is 2.40 Å. The Yb(2)-O(14) bond length is 2.37 Å. The Yb(2)-O(15) bond length is 2.37 Å. The Yb(2)-O(16) bond length is 2.34 Å. The Yb(2)-O(17) bond length is 2.36 Å. The Yb(2)-O(18) bond length is 2.36 Å. The Yb(2)-O(19) bond length is 2.34 Å. The Yb(2)-O(9) bond length is 2.37 Å. There are sixteen inequivalent C sites. In the first C site, C(62) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(47) atom. The C(62)-N(9) bond length is 1.36 Å. The C(62)-H(47) bond length is 0.95 Å. In the second C site, C(63) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(48) atom. The C(63)-N(9) bond length is 1.35 Å. The C(63)-H(48) bond length is 0.95 Å. In the third C site, C(68) is bonded in a distorted bent 120 degrees geometry to one N(12) and one H(53) atom. The C(68)-N(12) bond length is 1.35 Å. The C(68)-H(53) bond length is 0.95 Å. In the fourth C site, C(69) is bonded in a distorted bent 120 degrees geometry to one N(12) and one H(54) atom. The C(69)-N(12) bond length is 1.35 Å. The C(69)-H(54) bond length is 0.95 Å. In the fifth C site, C(72) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(57,59) atom. The C(72)-N(14) bond length is 1.35 Å. The C(72)-H(57,59) bond length is 0.95 Å. In the sixth C site, C(73) is bonded in a distorted bent 120 degrees geometry to one N(14) and one H(58) atom. The C(73)-N(14) bond length is 1.35 Å. The C(73)-H(58) bond length is 0.95 Å. In the seventh C site, C(74) is bonded in a distorted bent 120 degrees geometry to one N(15) and one H(57,59) atom. The C(74)-N(15) bond length is 1.36 Å. The C(74)-H(57,59) bond length is 0.95 Å. In the eighth C site, C(75) is bonded in a 2-coordinate geometry to one N(15) and one H(60) atom. The C(75)-N(15) bond length is 1.35 Å. The C(75)-H(60) bond length is 0.95 Å. In the ninth C site, C(76) is bonded in a distorted bent 120 degrees geometry to one N(16) and one H(61) atom. The C(76)-N(16) bond length is 1.34 Å. The C(76)-H(61) bond length is 0.95 Å. In the tenth C site, C(77) is bonded in a distorted bent 120 degrees geometry to one N(16) and one H(62) atom. The C(77)-N(16) bond length is 1.33 Å. The C(77)-H(62) bond length is 0.95 Å. In the eleventh C site, C(78) is bonded in a distorted bent 120 degrees geometry to one N(17) and one H(63) atom. The C(78)-N(17) bond length is 1.35 Å. The C(78)-H(63) bond length is 0.95 Å. In the twelfth C site, C(79) is bonded in a distorted bent 120 degrees geometry to one N(17) and one H(64) atom. The C(79)-N(17) bond length is 1.34 Å. The C(79)-H(64) bond length is 0.95 Å. In the thirteenth C site, C(80) is bonded in a distorted bent 120 degrees geometry to one N(18) and one H(65) atom. The C(80)-N(18) bond length is 1.34 Å. The C(80)-H(65) bond length is 0.95 Å. In the fourteenth C site, C(81) is bonded in a distorted bent 120 degrees geometry to one N(18) and one H(66) atom. The C(81)-N(18) bond length is 1.34 Å. The C(81)-H(66) bond length is 0.95 Å. In the fifteenth C site, C(82) is bonded in a distorted bent 120 degrees geometry to one N(19) and one H(67,68) atom. The C(82)-N(19) bond length is 1.35 Å. The C(82)-H(67,68) bond length is 0.95 Å. In the sixteenth C site, C(83) is bonded in a distorted bent 120 degrees geometry to one N(19) and one H(67,68) atom. The C(83)-N(19) bond length is 1.34 Å. The C(83)-H(67,68) bond length is 0.95 Å. There are eight inequivalent N sites. In the first N site, N(9) is bonded in a trigonal planar geometry to one C(62), one C(63), and one O(9) atom. The N(9)-O(9) bond length is 1.33 Å. In the second N site, N(12) is bonded in a trigonal planar geometry to one C(68), one C(69), and one O(12) atom. The N(12)-O(12) bond length is 1.33 Å. In the third N site, N(16) is bonded in a trigonal planar geometry to one C(76), one C(77), and one O(16) atom. The N(16)-O(16) bond length is 1.33 Å. In the fourth N site, N(17) is bonded in a trigonal planar geometry to one C(78), one C(79), and one O(17) atom. The N(17)-O(17) bond length is 1.33 Å. In the fifth N site, N(18) is bonded in a trigonal planar geometry to one C(80), one C(81), and one O(18) atom. The N(18)-O(18) bond length is 1.33 Å. In the sixth N site, N(19) is bonded in a trigonal planar geometry to one C(82), one C(83), and one O(19) atom. The N(19)-O(19) bond length is 1.34 Å. In the seventh N site, N(14) is bonded in a trigonal planar geometry to one C(72), one C(73), and one O(14) atom. The N(14)-O(14) bond length is 1.32 Å. In the eighth N site, N(15) is bonded in a trigonal planar geometry to one C(74), one C(75), and one O(15) atom. The N(15)-O(15) bond length is 1.33 Å. There are fourteen inequivalent H sites. In the first H site, H(47) is bonded in a single-bond geometry to one C(62) atom. In the second H site, H(48) is bonded in a single-bond geometry to one C(63) atom. In the third H site, H(53) is bonded in a single-bond geometry to one C(68) atom. In the fourth H site, H(54) is bonded in a single-bond geometry to one C(69) atom. In the fifth H site, H(57,59) is bonded in a single-bond geometry to one C(72) atom. In the sixth H site, H(58) is bonded in a single-bond geometry to one C(73) atom. In the seventh H site, H(60) is bonded in a single-bond geometry to one C(75) atom. In the eighth H site, H(61) is bonded in a single-bond geometry to one C(76) atom. In the ninth H site, H(62) is bonded in a single-bond geometry to one C(77) atom. In the tenth H site, H(63) is bonded in a single-bond geometry to one C(78) atom. In the eleventh H site, H(64) is bonded in a single-bond geometry to one C(79) atom. In the twelfth H site, H(65) is bonded in a single-bond geometry to one C(80) atom. In the thirteenth H site, H(66) is bonded in a single-bond geometry to one C(81) atom. In the fourteenth H site, H(67,68) is bonded in a single-bond geometry to one C(82) atom. There are eight inequivalent O sites. In the first O site, O(9) is bonded in a bent 120 degrees geometry to one Yb(2) and one N(9) atom. In the second O site, O(12) is bonded in a bent 120 degrees geometry to one Yb(2) and one N(12) atom. In the third O site, O(14) is bonded in a bent 120 degrees geometry to one Yb(2) and one N(14) atom. In the fourth O site, O(15) is bonded in a bent 120 degrees geometry to one Yb(2) and one N(15) atom. In the fifth O site, O(16) is bonded in a bent 120 degrees geometry to one Yb(2) and one N(16) atom. In the sixth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Yb(2) and one N(17) atom. In the seventh O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Yb(2) and one N(18) atom. In the eighth O site, O(19) is bonded in a bent 120 degrees geometry to one Yb(2) and one N(19) atom. In two of the YbC16H16(NO)8 clusters, Yb(3) is bonded in a 8-coordinate geometry to one O(10), one O(11), one O(13), one O(20), one O(21), one O(22), one O(23), and one O(24) atom. The Yb(3)-O(10) bond length is 2.36 Å. The Yb(3)-O(11) bond length is 2.36 Å. The Yb(3)-O(13) bond length is 2.33 Å. The Yb(3)-O(20) bond length is 2.38 Å. The Yb(3)-O(21) bond length is 2.35 Å. The Yb(3)-O(22) bond length is 2.38 Å. The Yb(3)-O(23) bond length is 2.39 Å. The Yb(3)-O(24) bond length is 2.39 Å. There are sixteen inequivalent C sites. In the first C site, C(64) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(49) atom. The C(64)-N(10) bond length is 1.35 Å. The C(64)-H(49) bond length is 0.95 Å. In the second C site, C(65) is bonded in a distorted bent 120 degrees geometry to one N(10) and one H(14,50) atom. The C(65)-N(10) bond length is 1.35 Å. The C(65)-H(14,50) bond length is 0.95 Å. In the third C site, C(66) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(51) atom. The C(66)-N(11) bond length is 1.34 Å. The C(66)-H(51) bond length is 0.95 Å. In the fourth C site, C(67) is bonded in a distorted bent 120 degrees geometry to one N(11) and one H(52) atom. The C(67)-N(11) bond length is 1.33 Å. The C(67)-H(52) bond length is 0.95 Å. In the fifth C site, C(70) is bonded in a distorted bent 120 degrees geometry to one N(13) and one H(55) atom. The C(70)-N(13) bond length is 1.36 Å. The C(70)-H(55) bond length is 0.95 Å. In the sixth C site, C(71) is bonded in a distorted bent 120 degrees geometry to one N(13) and one H(56) atom. The C(71)-N(13) bond length is 1.33 Å. The C(71)-H(56) bond length is 0.95 Å. In the seventh C site, C(84) is bonded in a distorted bent 120 degrees geometry to one N(20) and one H(69) atom. The C(84)-N(20) bond length is 1.31 Å. The C(84)-H(69) bond length is 0.95 Å. In the eighth C site, C(85) is bonded in a distorted bent 120 degrees geometry to one N(20) and one H(70) atom. The C(85)-N(20) bond length is 1.34 Å. The C(85)-H(70) bond length is 0.95 Å. In the ninth C site, C(86) is bonded in a distorted bent 120 degrees geometry to one N(21) and one H(71) atom. The C(86)-N(21) bond length is 1.32 Å. The C(86)-H(71) bond length is 0.95 Å. In the tenth C site, C(87) is bonded in a distorted bent 120 degrees geometry to one N(21) and one H(72) atom. The C(87)-N(21) bond length is 1.32 Å. The C(87)-H(72) bond length is 0.95 Å. In the eleventh C site, C(117) is bonded in a distorted bent 120 degrees geometry to one N(23) and one H(93) atom. The C(117)-N(23) bond length is 1.35 Å. The C(117)-H(93) bond length is 0.95 Å. In the twelfth C site, C(118) is bonded in a distorted bent 120 degrees geometry to one N(23) and one H(94) atom. The C(118)-N(23) bond length is 1.34 Å. The C(118)-H(94) bond length is 0.95 Å. In the thirteenth C site, C(115) is bonded in a distorted bent 120 degrees geometry to one N(22) and one H(91) atom. The C(115)-N(22) bond length is 1.32 Å. The C(115)-H(91) bond length is 0.95 Å. In the fourteenth C site, C(116) is bonded in a distorted bent 120 degrees geometry to one N(22) and one H(92) atom. The C(116)-N(22) bond length is 1.36 Å. The C(116)-H(92) bond length is 0.95 Å. In the fifteenth C site, C(119) is bonded in a distorted bent 120 degrees geometry to one N(24) and one H(95) atom. The C(119)-N(24) bond length is 1.35 Å. The C(119)-H(95) bond length is 0.95 Å. In the sixteenth C site, C(120) is bonded in a distorted bent 120 degrees geometry to one N(24) and one H(96) atom. The C(120)-N(24) bond length is 1.35 Å. The C(120)-H(96) bond length is 0.95 Å. There are eight inequivalent N sites. In the first N site, N(10) is bonded in a trigonal planar geometry to one C(64), one C(65), and one O(10) atom. The N(10)-O(10) bond length is 1.32 Å. In the second N site, N(11) is bonded in a trigonal planar geometry to one C(66), one C(67), and one O(11) atom. The N(11)-O(11) bond length is 1.33 Å. In the third N site, N(13) is bonded in a trigonal planar geometry to one C(70), one C(71), and one O(13) atom. The N(13)-O(13) bond length is 1.32 Å. In the fourth N site, N(20) is bonded in a trigonal planar geometry to one C(84), one C(85), and one O(20) atom. The N(20)-O(20) bond length is 1.34 Å. In the fifth N site, N(22) is bonded in a trigonal planar geometry to one C(115), one C(116), and one O(24) atom. The N(22)-O(24) bond length is 1.36 Å. In the sixth N site, N(24) is bonded in a trigonal planar geometry to one C(119), one C(120), and one O(23) atom. The N(24)-O(23) bond length is 1.33 Å. In the seventh N site, N(21) is bonded in a trigonal planar geometry to one C(86), one C(87), and one O(21) atom. The N(21)-O(21) bond length is 1.33 Å. In the eighth N site, N(23) is bonded in a trigonal planar geometry to one C(117), one C(118), and one O(22) atom. The N(23)-O(22) bond length is 1.33 Å. There are sixteen inequivalent H sites. In the first H site, H(14,50) is bonded in a single-bond geometry to one C(14) atom. The H(14,50)-C(14) bond length is 0.95 Å. In the second H site, H(49) is bonded in a single-bond geometry to one C(64) atom. In the third H site, H(51) is bonded in a single-bond geometry to one C(66) atom. In the fourth H site, H(52) is bonded in a single-bond geometry to one C(67) atom. In the fifth H site, H(55) is bonded in a single-bond geometry to one C(70) atom. In the sixth H site, H(56) is bonded in a single-bond geometry to one C(71) atom. In the seventh H site, H(69) is bonded in a single-bond geometry to one C(84) atom. In the eighth H site, H(70) is bonded in a single-bond geometry to one C(85) atom. In the ninth H site, H(71) is bonded in a single-bond geometry to one C(86) atom. In the tenth H site, H(72) is bonded in a single-bond geometry to one C(87) atom. In the eleventh H site, H(91) is bonded in a single-bond geometry to one C(115) atom. In the twelfth H site, H(92) is bonded in a single-bond geometry to one C(116) atom. In the thirteenth H site, H(93) is bonded in a single-bond geometry to one C(117) atom. In the fourteenth H site, H(94) is bonded in a single-bond geometry to one C(118) atom. In the fifteenth H site, H(95) is bonded in a single-bond geometry to one C(119) atom. In the sixteenth H site, H(96) is bonded in a single-bond geometry to one C(120) atom. There are eight inequivalent O sites. In the first O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Yb(3) and one N(10) atom. In the second O site, O(11) is bonded in a bent 120 degrees geometry to one Yb(3) and one N(11) atom. In the third O site, O(13) is bonded in a bent 120 degrees geometry to one Yb(3) and one N(13) atom. In the fourth O site, O(20) is bonded in a bent 120 degrees geometry to one Yb(3) and one N(20) atom. In the fifth O site, O(21) is bonded in a bent 120 degrees geometry to one Yb(3) and one N(21) atom. In the sixth O site, O(22) is bonded in a bent 120 degrees geometry to one Yb(3) and one N(23) atom. In the seventh O site, O(23) is bonded in a bent 120 degrees geometry to one Yb(3) and one N(24) atom. In the eighth O site, O(24) is bonded in a bent 120 degrees geometry to one Yb(3) and one N(22) atom. In each YbC22H20(NO)8 cluster, Yb(1) is bonded in a 8-coordinate geometry to one O(1), one O(2), one O(3), one O(4), one O(5), one O(6), one O(7), and one O(8) atom. The Yb(1)-O(1) bond length is 2.34 Å. The Yb(1)-O(2) bond length is 2.42 Å. The Yb(1)-O(3) bond length is 2.38 Å. The Yb(1)-O(4) bond length is 2.32 Å. The Yb(1)-O(5) bond length is 2.33 Å. The Yb(1)-O(6) bond length is 2.37 Å. The Yb(1)-O(7) bond length is 2.37 Å. The Yb(1)-O(8) bond length is 2.34 Å. There are twenty-two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(18), one N(1), and one H(2) atom. The C(2)-C(18) bond length is 1.35 Å. The C(2)-N(1) bond length is 1.35 Å. The C(2)-H(2) bond length is 0.95 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(3) atom. The C(3)-N(2) bond length is 1.34 Å. The C(3)-H(3) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(4) atom. The C(4)-N(2) bond length is 1.31 Å. The C(4)-H(4) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(5) atom. The C(5)-N(3) bond length is 1.36 Å. The C(5)-H(5) bond length is 0.95 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(6) atom. The C(6)-N(3) bond length is 1.34 Å. The C(6)-H(6) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(7) atom. The C(7)-N(4) bond length is 1.34 Å. The C(7)-H(7) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(8) atom. The C(8)-N(4) bond length is 1.32 Å. The C(8)-H(8) bond length is 0.95 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(9) atom. The C(9)-N(5) bond length is 1.36 Å. The C(9)-H(9) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(10) atom. The C(10)-N(5) bond length is 1.38 Å. The C(10)-H(10) bond length is 0.95 Å. In the eleventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(11) atom. The C(11)-N(6) bond length is 1.33 Å. The C(11)-H(11) bond length is 0.95 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(12) atom. The C(12)-N(6) bond length is 1.37 Å. The C(12)-H(12) bond length is 0.95 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(13) atom. The C(13)-N(7) bond length is 1.33 Å. The C(13)-H(13) bond length is 0.95 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(14,50) atom. The C(14)-N(7) bond length is 1.36 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(15) atom. The C(15)-N(8) bond length is 1.35 Å. The C(15)-H(15) bond length is 0.95 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(16) atom. The C(16)-N(8) bond length is 1.33 Å. The C(16)-H(16) bond length is 0.95 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(33) and one H(17) atom. The C(17)-C(33) bond length is 1.38 Å. The C(17)-H(17) bond length is 0.95 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(2), one C(33), and one H(18) atom. The C(18)-C(33) bond length is 1.39 Å. The C(18)-H(18) bond length is 0.95 Å. In the nineteenth C site, C(33) is bonded in a trigonal planar geometry to one C(17), one C(18), and one C(41) atom. The C(33)-C(41) bond length is 1.47 Å. In the twentieth C site, C(41) is bonded in a trigonal planar geometry to one C(33), one C(48), and one C(49) atom. The C(41)-C(48) bond length is 1.39 Å. The C(41)-C(49) bond length is 1.41 Å. In the twenty-first C site, C(48) is bonded in a single-bond geometry to one C(41) and one H(33) atom. The C(48)-H(33) bond length is 0.95 Å. In the twenty-second C site, C(49) is bonded in a distorted single-bond geometry to one C(41) and one H(34,75) atom. The C(49)-H(34,75) bond length is 0.95 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(2), and one O(1) atom. The N(1)-O(1) bond length is 1.33 Å. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(3), one C(4), and one O(2) atom. The N(2)-O(2) bond length is 1.32 Å. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(5), one C(6), and one O(3) atom. The N(3)-O(3) bond length is 1.34 Å. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(7), one C(8), and one O(4) atom. The N(4)-O(4) bond length is 1.34 Å. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one C(10), one C(9), and one O(5) atom. The N(5)-O(5) bond length is 1.33 Å. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(11), one C(12), and one O(6) atom. The N(6)-O(6) bond length is 1.31 Å. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one C(13), one C(14), and one O(7) atom. The N(7)-O(7) bond length is 1.32 Å. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one C(15), one C(16), and one O(8) atom. The N(8)-O(8) bond length is 1.33 Å. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(12) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(13) atom. In the fourteenth H site, H(14,50) is bonded in a single-bond geometry to one C(14) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(18) atom. In the nineteenth H site, H(33) is bonded in a single-bond geometry to one C(48) atom. In the twentieth H site, H(34,75) is bonded in a single-bond geometry to one C(49) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Yb(1) and one N(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Yb(1) and one N(2) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Yb(1) and one N(3) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Yb(1) and one N(4) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Yb(1) and one N(5) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Yb(1) and one N(6) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Yb(1) and one N(7) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Yb(1) and one N(8) atom. Linkers: 23 [O-][n+]1ccc(-c2cc[n+]([O-])cc2)cc1 ,2 [O]N1[CH]C=C(c2cc[n+]([O-])cc2)C=C1. Metal clusters: 6 [O].[O].[O][Yb]([O])([O])([O])([O])[O]. The MOF has largest included sphere 9.14 A, density 0.82 g/cm3, surface area 4157.26 m2/g, accessible volume 0.67 cm3/g