(AgH10(C5N)2)2AgC20N5H20O3(CH)8(C4NH4O)3 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixty-four 02329_fluka molecules; eight n,n',n''-trimethylbenzene-1,3,5-tricarboxamide molecules; eight AgC20N5H20O3 clusters; and sixteen AgH10(C5N)2 clusters. In each AgC20N5H20O3 cluster, Ag(2) is bonded in a distorted T-shaped geometry to one N(5), one N(7), and one O(4) atom. The Ag(2)-N(5) bond length is 2.21 Å. The Ag(2)-N(7) bond length is 2.21 Å. The Ag(2)-O(4) bond length is 2.69 Å. There are twenty inequivalent C sites. In the first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(25) atom. The C(21)-N(5) bond length is 1.35 Å. The C(21)-H(25) bond length is 0.95 Å. In the second C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(28) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-H(28) bond length is 0.95 Å. In the third C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one C(26), and one N(5) atom. The C(25)-C(26) bond length is 1.50 Å. The C(25)-N(5) bond length is 1.34 Å. In the fourth C site, C(26) is bonded in a water-like geometry to one C(25), one H(29), and one H(30) atom. The C(26)-H(29) bond length is 0.99 Å. The C(26)-H(30) bond length is 0.99 Å. In the fifth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(34) atom. The C(31)-N(7) bond length is 1.34 Å. The C(31)-H(34) bond length is 0.95 Å. In the sixth C site, C(34) is bonded in a distorted single-bond geometry to one C(35) and one H(37) atom. The C(34)-C(35) bond length is 1.36 Å. The C(34)-H(37) bond length is 0.95 Å. In the seventh C site, C(35) is bonded in a distorted trigonal planar geometry to one C(34), one C(36), and one N(7) atom. The C(35)-C(36) bond length is 1.50 Å. The C(35)-N(7) bond length is 1.36 Å. In the eighth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(39), one N(8), and one O(4) atom. The C(38)-C(39) bond length is 1.51 Å. The C(38)-N(8) bond length is 1.34 Å. The C(38)-O(4) bond length is 1.24 Å. In the ninth C site, C(36) is bonded in a water-like geometry to one C(35) and two equivalent H(38,39) atoms. Both C(36)-H(38,39) bond lengths are 0.99 Å. In the tenth C site, C(40) is bonded in a distorted single-bond geometry to one C(39), one C(49), and one H(42) atom. The C(40)-C(39) bond length is 1.39 Å. The C(40)-C(49) bond length is 1.39 Å. The C(40)-H(42) bond length is 0.95 Å. In the eleventh C site, C(37) is bonded in a 3-coordinate geometry to one N(8) and two equivalent H(13,14,40,41) atoms. The C(37)-N(8) bond length is 1.45 Å. Both C(37)-H(13,14,40,41) bond lengths are 0.99 Å. In the twelfth C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(60) atom. The C(39)-C(60) bond length is 1.38 Å. In the thirteenth C site, C(47) is bonded in a 3-coordinate geometry to one N(10), one H(49), and one H(50) atom. The C(47)-N(10) bond length is 1.47 Å. The C(47)-H(49) bond length is 0.99 Å. The C(47)-H(50) bond length is 0.99 Å. In the fourteenth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(49), one N(10), and one O(5) atom. The C(48)-C(49) bond length is 1.49 Å. The C(48)-N(10) bond length is 1.33 Å. The C(48)-O(5) bond length is 1.23 Å. In the fifteenth C site, C(49) is bonded in a trigonal planar geometry to one C(40), one C(48), and one C(50) atom. The C(49)-C(50) bond length is 1.38 Å. In the sixteenth C site, C(50) is bonded in a single-bond geometry to one C(49), one C(59), and one H(51) atom. The C(50)-C(59) bond length is 1.38 Å. The C(50)-H(51) bond length is 0.95 Å. In the seventeenth C site, C(58) is bonded in a distorted bent 120 degrees geometry to one C(59), one N(12), and one O(6) atom. The C(58)-C(59) bond length is 1.50 Å. The C(58)-N(12) bond length is 1.34 Å. The C(58)-O(6) bond length is 1.23 Å. In the eighteenth C site, C(59) is bonded in a trigonal planar geometry to one C(50), one C(58), and one C(60) atom. The C(59)-C(60) bond length is 1.39 Å. In the nineteenth C site, C(60) is bonded in a distorted single-bond geometry to one C(39), one C(59), and one H(60) atom. The C(60)-H(60) bond length is 0.95 Å. In the twentieth C site, C(57) is bonded in a 3-coordinate geometry to one N(12) and two equivalent H(58,59) atoms. The C(57)-N(12) bond length is 1.46 Å. Both C(57)-H(58,59) bond lengths are 0.99 Å. There are five inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one Ag(2), one C(21), and one C(25) atom. In the second N site, N(7) is bonded in a trigonal planar geometry to one Ag(2), one C(31), and one C(35) atom. In the third N site, N(8) is bonded in a trigonal planar geometry to one C(37), one C(38), and one H(4) atom. The N(8)-H(4) bond length is 0.88 Å. In the fourth N site, N(10) is bonded in a trigonal planar geometry to one C(47), one C(48), and one H(5) atom. The N(10)-H(5) bond length is 0.88 Å. In the fifth N site, N(12) is bonded in a trigonal planar geometry to one C(57), one C(58), and one H(6) atom. The N(12)-H(6) bond length is 0.88 Å. There are seventeen inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one N(8) atom. In the second H site, H(5) is bonded in a single-bond geometry to one N(10) atom. In the third H site, H(6) is bonded in a single-bond geometry to one N(12) atom. In the fourth H site, H(13,14,40,41) is bonded in a single-bond geometry to one C(7) atom. The H(13,14,40,41)-C(7) bond length is 0.99 Å. In the fifth H site, H(25) is bonded in a single-bond geometry to one C(21) atom. In the sixth H site, H(29) is bonded in a single-bond geometry to one C(26) atom. In the seventh H site, H(30) is bonded in a single-bond geometry to one C(26) atom. In the eighth H site, H(28) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(34) is bonded in a single-bond geometry to one C(31) atom. In the tenth H site, H(37) is bonded in a single-bond geometry to one C(34) atom. In the eleventh H site, H(38,39) is bonded in a single-bond geometry to one C(36) atom. In the twelfth H site, H(42) is bonded in a single-bond geometry to one C(40) atom. In the thirteenth H site, H(49) is bonded in a single-bond geometry to one C(47) atom. In the fourteenth H site, H(50) is bonded in a single-bond geometry to one C(47) atom. In the fifteenth H site, H(51) is bonded in a single-bond geometry to one C(50) atom. In the sixteenth H site, H(58,59) is bonded in a single-bond geometry to one C(57) atom. In the seventeenth H site, H(60) is bonded in a single-bond geometry to one C(60) atom. There are three inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one Ag(2) and one C(38) atom. In the second O site, O(5) is bonded in a single-bond geometry to one C(48) atom. In the third O site, O(6) is bonded in a single-bond geometry to one C(58) atom. In eight of the AgH10(C5N)2 clusters, Ag(1) is bonded in a linear geometry to one N(1) and one N(9) atom. The Ag(1)-N(1) bond length is 2.14 Å. The Ag(1)-N(9) bond length is 2.14 Å. There are ten inequivalent C sites. In the first C site, C(41) is bonded in a distorted trigonal planar geometry to one C(42), one N(9), and one H(43) atom. The C(41)-C(42) bond length is 1.34 Å. The C(41)-N(9) bond length is 1.36 Å. The C(41)-H(43) bond length is 0.95 Å. In the second C site, C(42) is bonded in a distorted single-bond geometry to one C(41) and one H(44) atom. The C(42)-H(44) bond length is 0.95 Å. In the third C site, C(44) is bonded in a distorted single-bond geometry to one C(45) and one H(46) atom. The C(44)-C(45) bond length is 1.39 Å. The C(44)-H(46) bond length is 0.95 Å. In the fourth C site, C(45) is bonded in a distorted trigonal planar geometry to one C(44), one C(46), and one N(9) atom. The C(45)-C(46) bond length is 1.51 Å. The C(45)-N(9) bond length is 1.35 Å. In the fifth C site, C(46) is bonded in a water-like geometry to one C(45) and two equivalent H(47,48) atoms. Both C(46)-H(47,48) bond lengths are 0.99 Å. In the sixth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(7) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(7) bond length is 0.95 Å. In the seventh C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(9) atom. The C(3)-C(4) bond length is 1.37 Å. The C(3)-H(9) bond length is 0.95 Å. In the eighth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one H(10) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(10) bond length is 0.95 Å. In the ninth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.50 Å. The C(5)-N(1) bond length is 1.34 Å. In the tenth C site, C(6) is bonded in a water-like geometry to one C(5) and two equivalent H(11,12) atoms. Both C(6)-H(11,12) bond lengths are 0.99 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(9) is bonded in a trigonal planar geometry to one Ag(1), one C(41), and one C(45) atom. There are eight inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(9) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(10) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(11,12) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(43) is bonded in a single-bond geometry to one C(41) atom. In the sixth H site, H(44) is bonded in a single-bond geometry to one C(42) atom. In the seventh H site, H(46) is bonded in a single-bond geometry to one C(44) atom. In the eighth H site, H(47,48) is bonded in a single-bond geometry to one C(46) atom. In eight of the AgH10(C5N)2 clusters, Ag(3) is bonded in a bent 150 degrees geometry to one N(11) and one N(3) atom. The Ag(3)-N(11) bond length is 2.18 Å. The Ag(3)-N(3) bond length is 2.17 Å. There are ten inequivalent C sites. In the first C site, C(11) is bonded in a distorted trigonal planar geometry to one C(12), one N(3), and one H(16) atom. The C(11)-C(12) bond length is 1.37 Å. The C(11)-N(3) bond length is 1.35 Å. The C(11)-H(16) bond length is 0.95 Å. In the second C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(17) atom. The C(12)-H(17) bond length is 0.95 Å. In the third C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(19) atom. The C(14)-C(15) bond length is 1.37 Å. The C(14)-H(19) bond length is 0.95 Å. In the fourth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(14), one C(16), and one N(3) atom. The C(15)-C(16) bond length is 1.49 Å. The C(15)-N(3) bond length is 1.35 Å. In the fifth C site, C(16) is bonded in a water-like geometry to one C(15), one H(20), and one H(21) atom. The C(16)-H(20) bond length is 0.99 Å. The C(16)-H(21) bond length is 0.99 Å. In the sixth C site, C(51) is bonded in a distorted bent 120 degrees geometry to one C(52), one N(11), and one H(52) atom. The C(51)-C(52) bond length is 1.36 Å. The C(51)-N(11) bond length is 1.34 Å. The C(51)-H(52) bond length is 0.95 Å. In the seventh C site, C(52) is bonded in a distorted single-bond geometry to one C(51) and one H(53) atom. The C(52)-H(53) bond length is 0.95 Å. In the eighth C site, C(54) is bonded in a distorted single-bond geometry to one C(55) and one H(55) atom. The C(54)-C(55) bond length is 1.39 Å. The C(54)-H(55) bond length is 0.95 Å. In the ninth C site, C(55) is bonded in a distorted trigonal planar geometry to one C(54), one C(56), and one N(11) atom. The C(55)-C(56) bond length is 1.50 Å. The C(55)-N(11) bond length is 1.33 Å. In the tenth C site, C(56) is bonded in a water-like geometry to one C(55), one H(56), and one H(57) atom. The C(56)-H(56) bond length is 0.99 Å. The C(56)-H(57) bond length is 0.99 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Ag(3), one C(11), and one C(15) atom. In the second N site, N(11) is bonded in a trigonal planar geometry to one Ag(3), one C(51), and one C(55) atom. There are ten inequivalent H sites. In the first H site, H(16) is bonded in a single-bond geometry to one C(11) atom. In the second H site, H(17) is bonded in a single-bond geometry to one C(12) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(20) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(21) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(52) is bonded in a single-bond geometry to one C(51) atom. In the seventh H site, H(53) is bonded in a single-bond geometry to one C(52) atom. In the eighth H site, H(55) is bonded in a single-bond geometry to one C(54) atom. In the ninth H site, H(56) is bonded in a single-bond geometry to one C(56) atom. In the tenth H site, H(57) is bonded in a single-bond geometry to one C(56) atom. Linkers: 3 [CH]=C([N])CCNC(=O)c1cc(C(=O)NCCC2=CC=C[CH]N2[Ag]N2[CH]C=CC=C2CCNC(=O)c2cc(C(=O)NCCc3ccccn3)cc(C(=O)NCCc3ccccn3)c2)cc(C(=O)NCCc2ccccn2)c1 ,8 O=C(NCCC1=CC=C[CH]N1[Ag]N1[CH]C=CC=C1CCNC(=O)c1cc(C(=O)NCCc2ccccn2)cc(C(=O)NCCc2ccccn2)c1)c1cc(C(=O)NCCc2ccccn2)cc(C(=O)NCCc2ccccn2)c1 ,4 [CH][CH]C1=[C]C=C[CH]N1[Ag]N1[CH]C=CC=C1CCNC(=O)c1cc(C(=O)NCCc2ccccn2)cc(C(=O)NCCc2ccccn2)c1 ,1 [CH]=C([N])CCNC(=O)c1cc(C(=O)NCC[C]2C=CC=CN2[Ag]N2[CH]C=CC=C2CCNC(=O)c2cc(C(=O)NCCc3ccccn3)cc(C(=O)NCCc3ccccn3)c2)cc(C(=O)NCCc2ccccn2)c1 ,4 [CH2]CNC(=O)c1cc(C(=O)NCCC2=CC=C[CH]N2[Ag]N2[CH]C=CC=C2CCNC(=O)c2cc(C(=O)NCCc3ccccn3)cc(C(=O)NCCc3ccccn3)c2)cc(C(=O)NCCc2ccccn2)c1 ,4 O=C([C]/C=[C]/C(=O)[N]CCC1=CC=C[CH]N1[Ag]N1[CH]C=CC=C1CCNC(=O)c1cc(C(=O)NCCc2ccccn2)cc(C(=O)NCCc2ccccn2)c1)[N]C[C]c1ccccn1. Metal clusters: 16 [Ag]. The MOF has largest included sphere 6.91 A, density 1.15 g/cm3, surface area 4618.59 m2/g, accessible volume 0.44 cm3/g