CuC40H30(NO)4CuC20H14(NO)4(CH)8(C2O)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, four dimethyl ether molecules, two CuC20H14(NO)4 clusters, and two CuC40H30(NO)4 clusters. In each CuC20H14(NO)4 cluster, Cu(2) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent O(3) atoms. Both Cu(2)-N(2) bond lengths are 1.97 Å. Both Cu(2)-O(3) bond lengths are 1.93 Å. There are ten inequivalent C sites. In the first C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(15) atom. The C(23)-C(18) bond length is 1.36 Å. The C(23)-H(15) bond length is 0.93 Å. In the second C site, C(19) is bonded in a distorted single-bond geometry to one C(18) and one H(12) atom. The C(19)-C(18) bond length is 1.36 Å. The C(19)-H(12) bond length is 0.93 Å. In the third C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.37 Å. The C(10)-H(6) bond length is 0.93 Å. In the fourth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(13) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-C(13) bond length is 1.37 Å. In the fifth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(3), and one O(4) atom. The C(12)-O(3) bond length is 1.26 Å. The C(12)-O(4) bond length is 1.23 Å. In the sixth C site, C(13) is bonded in a distorted single-bond geometry to one C(11) and one H(7) atom. The C(13)-H(7) bond length is 0.93 Å. In the seventh C site, C(18) is bonded in a distorted trigonal planar geometry to one C(19), one C(23), and one N(3) atom. The C(18)-N(3) bond length is 1.42 Å. In the eighth C site, C(15) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(9) atom. The C(15)-N(2) bond length is 1.31 Å. The C(15)-N(3) bond length is 1.34 Å. The C(15)-H(9) bond length is 0.93 Å. In the ninth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(17), one N(2), and one H(10) atom. The C(16)-C(17) bond length is 1.34 Å. The C(16)-N(2) bond length is 1.36 Å. The C(16)-H(10) bond length is 0.93 Å. In the tenth C site, C(17) is bonded in a 3-coordinate geometry to one C(16), one N(3), and one H(11) atom. The C(17)-N(3) bond length is 1.36 Å. The C(17)-H(11) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cu(2), one C(15), and one C(16) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. There are seven inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(23) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Cu(2) and one C(12) atom. In the second O site, O(4) is bonded in a single-bond geometry to one C(12) atom. In each CuC40H30(NO)4 cluster, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(2) atoms. Both Cu(1)-N(1) bond lengths are 1.97 Å. Both Cu(1)-O(2) bond lengths are 1.92 Å. There are twenty inequivalent C sites. In the first C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(21)-C(20) bond length is 1.37 Å. The C(21)-C(22) bond length is 1.37 Å. The C(21)-C(24) bond length is 1.48 Å. In the second C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(13,14) atom. The C(22)-H(13,14) bond length is 0.93 Å. In the third C site, C(24) is bonded in a 5-coordinate geometry to one C(21), one C(25), one C(29), one C(33), and one C(36) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-C(29) bond length is 1.35 Å. The C(24)-C(33) bond length is 1.36 Å. The C(24)-C(36) bond length is 1.41 Å. In the fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(27) and one H(17) atom. The C(26)-C(27) bond length is 1.45 Å. The C(26)-H(17) bond length is 0.93 Å. In the fifth C site, C(27) is bonded in a distorted single-bond geometry to one C(26), one C(28), one C(34), one C(35), and one N(4) atom. The C(27)-C(28) bond length is 1.35 Å. The C(27)-C(34) bond length is 1.32 Å. The C(27)-C(35) bond length is 1.34 Å. The C(27)-N(4) bond length is 1.43 Å. In the sixth C site, C(28) is bonded in a distorted water-like geometry to one C(27), one C(35), and one H(18) atom. The C(28)-C(35) bond length is 0.95 Å. The C(28)-H(18) bond length is 0.93 Å. In the seventh C site, C(30) is bonded in a trigonal planar geometry to one N(1), one N(4), and one H(20) atom. The C(30)-N(1) bond length is 1.31 Å. The C(30)-N(4) bond length is 1.35 Å. The C(30)-H(20) bond length is 0.93 Å. In the eighth C site, C(31) is bonded in a 2-coordinate geometry to one C(32), one N(4), and one H(21) atom. The C(31)-C(32) bond length is 1.34 Å. The C(31)-N(4) bond length is 1.38 Å. The C(31)-H(21) bond length is 0.93 Å. In the ninth C site, C(32) is bonded in a distorted trigonal planar geometry to one C(31), one N(1), and one H(22) atom. The C(32)-N(1) bond length is 1.38 Å. The C(32)-H(22) bond length is 0.93 Å. In the tenth C site, C(33) is bonded in a 1-coordinate geometry to one C(24), one C(25), and one H(23) atom. The C(33)-C(25) bond length is 1.07 Å. The C(33)-H(23) bond length is 0.93 Å. In the eleventh C site, C(25) is bonded in a 2-coordinate geometry to one C(24), one C(33), and one H(16) atom. The C(25)-H(16) bond length is 0.93 Å. In the twelfth C site, C(29) is bonded in a 2-coordinate geometry to one C(24), one C(36), and one H(19) atom. The C(29)-C(36) bond length is 0.97 Å. The C(29)-H(19) bond length is 0.93 Å. In the thirteenth C site, C(36) is bonded in a 2-coordinate geometry to one C(24), one C(29), and one H(26) atom. The C(36)-H(26) bond length is 0.93 Å. In the fourteenth C site, C(34) is bonded in a 1-coordinate geometry to one C(27) and one H(24) atom. The C(34)-H(24) bond length is 0.93 Å. In the fifteenth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(27), one C(28), and one H(25) atom. The C(35)-H(25) bond length is 0.93 Å. In the sixteenth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.27 Å. In the seventeenth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-C(7) bond length is 1.37 Å. In the eighteenth C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the nineteenth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(21) and one H(13,14) atom. The C(20)-H(13,14) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one C(27), one C(30), and one C(31) atom. In the second N site, N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(30), and one C(32) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(13,14) is bonded in a single-bond geometry to one C(20) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the sixth H site, H(18) is bonded in a single-bond geometry to one C(28) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(30) atom. In the ninth H site, H(21) is bonded in a single-bond geometry to one C(31) atom. In the tenth H site, H(22) is bonded in a single-bond geometry to one C(32) atom. In the eleventh H site, H(23) is bonded in a single-bond geometry to one C(33) atom. In the twelfth H site, H(24) is bonded in a distorted single-bond geometry to one C(34) and one H(26) atom. The H(24)-H(26) bond length is 1.14 Å. In the thirteenth H site, H(25) is bonded in a single-bond geometry to one C(35) atom. In the fourteenth H site, H(26) is bonded in a distorted single-bond geometry to one C(36) and one H(24) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(1) atom. Linkers: 1 O=[C]O[Cu].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=N[Cu].[CH][C][N][CH].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#N.[C]#N.[C]#N.[C]/C=[C]/O[C].[C]=C[N][CH].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]=[C][N].[C]C=[C].[C][CH]/[C]=[C]\[C]1[C][C@@H]2[C][C]12.[C][CH][C].[C][C].[C][C].[C][C]1[C][C]1[CH].[C][C]1[C][C]1[CH][CH].[C][C]=[C].[C][C]=[C].[C][C]=[C].[C][N].[C][N].[C][N].[C][N].[C][O].[Cu].[Cu].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N]c1[c][c][c]c[c]1.[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][Cu].[O][Cu].[O][Cu].[O][Cu].[O][Cu][O] ,1 O=[C]O[Cu].O=[C]O[Cu].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[CH].[CH]=[C][N].[CH]=[N].[CH]=[N].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]#[C].[C]#[C].[C]#[C].[C]/C=[C]\[C]=[CH].[C]/[C]=C(\[C])[O].[C]/[C]=N/[C].[C]=C[N].[C]=N[Cu][N].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]=[C]C=[C].[C]=[C]O[C]=[CH].[C]=[C][CH].[C]=[C][O].[C][C].[C][C]=[CH].[C][C]=[C].[C][C][CH][C][CH].[C][C][C].[C][C][C][C][C]C([C])[C].[C][N].[C][N][Cu]([O])[O].[Cu].[Cu].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N]/C=C\[N].[N][C][C][N].[N][Cu].[N][Cu].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][Cu].[O][Cu]O[C]=O ,1 O=[C]O[Cu].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=[C][C@@H]1[CH][C]2[C][C]21.[CH]=[C][N].[CH]=[N].[CH]C(=[CH])[N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]#N.[C]/C=[C]/[O].[C]=N[Cu].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]=[CH].[C]N([C][C][N])[Cu]([O])/N=C/[C][N].[C]OC([CH])=[CH].[C]O[C]=[C].[C][CH][CH].[C][CH][C][C]1[CH][C]1[C].[C][C].[C][C].[C][C].[C][C]=[C].[C][N].[C][N].[C][N].[C][N]C=[C].[Cu].[Cu].[Cu].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][Cu][O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][Cu].[O][Cu].[O][Cu]. Metal clusters: 1 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 5.26 A, density 1.12 g/cm3, surface area 4528.39 m2/g, accessible volume 0.45 cm3/g