Mn2CuB2C32H30(N11O2)2(CH)12 crystallizes in the tetragonal I4_1/a space group. The structure consists of ninety-six 02329_fluka molecules inside a Mn2CuB2C32H30(N11O2)2 framework. In the Mn2CuB2C32H30(N11O2)2 framework, Mn(1) is bonded in an octahedral geometry to one N(10), one N(11), one N(3), one N(6), one O(1), and one O(2) atom. The Mn(1)-N(10) bond length is 1.98 Å. The Mn(1)-N(11) bond length is 1.99 Å. The Mn(1)-N(3) bond length is 2.30 Å. The Mn(1)-N(6) bond length is 2.35 Å. The Mn(1)-O(1) bond length is 1.87 Å. The Mn(1)-O(2) bond length is 1.87 Å. Cu(1) is bonded in an octahedral geometry to two equivalent N(1), two equivalent N(4), and two equivalent N(7) atoms. Both Cu(1)-N(1) bond lengths are 2.38 Å. Both Cu(1)-N(4) bond lengths are 2.00 Å. Both Cu(1)-N(7) bond lengths are 2.07 Å. B(1) is bonded in a tetrahedral geometry to one N(2), one N(5), one N(8), and one H(7) atom. The B(1)-N(2) bond length is 1.54 Å. The B(1)-N(5) bond length is 1.55 Å. The B(1)-N(8) bond length is 1.53 Å. The B(1)-H(7) bond length is 0.98 Å. There are sixteen inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(9) atom. The C(9)-C(8) bond length is 1.42 Å. The C(9)-H(9) bond length is 0.93 Å. In the second C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one O(1) atom. The C(13)-C(8) bond length is 1.41 Å. The C(13)-O(1) bond length is 1.34 Å. In the third C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(11), and one H(13) atom. The C(14)-C(15) bond length is 1.44 Å. The C(14)-N(11) bond length is 1.29 Å. The C(14)-H(13) bond length is 0.93 Å. In the fourth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(20) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-C(20) bond length is 1.41 Å. In the fifth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(14) atom. The C(16)-H(14) bond length is 0.93 Å. In the sixth C site, C(20) is bonded in a distorted single-bond geometry to one C(15) and one O(2) atom. The C(20)-O(2) bond length is 1.32 Å. In the seventh C site, C(21) is bonded in a 3-coordinate geometry to one N(10) and two equivalent H(18,19) atoms. The C(21)-N(10) bond length is 1.46 Å. Both C(21)-H(18,19) bond lengths are 0.97 Å. In the eighth C site, C(22) is bonded in a 3-coordinate geometry to one N(11), one H(20), and one H(21) atom. The C(22)-N(11) bond length is 1.47 Å. The C(22)-H(20) bond length is 0.97 Å. The C(22)-H(21) bond length is 0.97 Å. In the ninth C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.31 Å. The C(1)-N(3) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the tenth C site, C(2) is bonded in a trigonal planar geometry to one N(2), one N(3), and one H(2) atom. The C(2)-N(2) bond length is 1.32 Å. The C(2)-N(3) bond length is 1.34 Å. The C(2)-H(2) bond length is 0.93 Å. In the eleventh C site, C(3) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(3) atom. The C(3)-N(4) bond length is 1.30 Å. The C(3)-N(6) bond length is 1.34 Å. The C(3)-H(3) bond length is 0.93 Å. In the twelfth C site, C(4) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(4) atom. The C(4)-N(5) bond length is 1.32 Å. The C(4)-N(6) bond length is 1.33 Å. The C(4)-H(4) bond length is 0.93 Å. In the thirteenth C site, C(5) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(5) atom. The C(5)-N(7) bond length is 1.31 Å. The C(5)-N(9) bond length is 1.33 Å. The C(5)-H(5) bond length is 0.93 Å. In the fourteenth C site, C(6) is bonded in a trigonal planar geometry to one N(8), one N(9), and one H(6) atom. The C(6)-N(8) bond length is 1.33 Å. The C(6)-N(9) bond length is 1.33 Å. The C(6)-H(6) bond length is 0.93 Å. In the fifteenth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(10), and one H(8) atom. The C(7)-C(8) bond length is 1.43 Å. The C(7)-N(10) bond length is 1.27 Å. The C(7)-H(8) bond length is 0.93 Å. In the sixteenth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(7), and one C(9) atom. There are eleven inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Cu(1), one C(1), and one N(2) atom. The N(1)-N(2) bond length is 1.38 Å. In the second N site, N(2) is bonded in a 2-coordinate geometry to one B(1), one C(2), and one N(1) atom. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Mn(1), one C(1), and one C(2) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one Cu(1), one C(3), and one N(5) atom. The N(4)-N(5) bond length is 1.36 Å. In the fifth N site, N(5) is bonded in a 2-coordinate geometry to one B(1), one C(4), and one N(4) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(3), and one C(4) atom. In the seventh N site, N(7) is bonded in a 3-coordinate geometry to one Cu(1), one C(5), and one N(8) atom. The N(7)-N(8) bond length is 1.37 Å. In the eighth N site, N(8) is bonded in a 2-coordinate geometry to one B(1), one C(6), and one N(7) atom. In the ninth N site, N(9) is bonded in a water-like geometry to one C(5) and one C(6) atom. In the tenth N site, N(10) is bonded in a trigonal planar geometry to one Mn(1), one C(21), and one C(7) atom. In the eleventh N site, N(11) is bonded in a trigonal planar geometry to one Mn(1), one C(14), and one C(22) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one B(1) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(9) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(16) atom. In the twelfth H site, H(18,19) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(20) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(21) is bonded in a single-bond geometry to one C(22) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(13) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(20) atom. Linkers: 1 N1=C[N][N@@]([CH]1)[B@@H]1N2N=CN([CH]2)[Mn]234(Oc5ccccc5[CH][N@@]4CC[N@@]3[CH]c3c(O2)cccc3)N2C=NN([CH]2)[B@@H](n2ncnc2)N2N=CN([CH]2)[Mn]234(Oc5ccccc5[CH][N@@]4CC[N@@]3[CH]c3c(O2)cccc3)N2C=NN([CH]2)[B@@H](N2[CH]N([Mn]345(N6[CH]N([B@H](N7[CH]N([Mn]89%10(N%11[CH]N1N=C%11)Oc1ccccc1[CH][N@@]%10CC[N@@]9[CH]c1c(O8)cccc1)C=N7)n1ncnc1)N=C6)Oc1ccccc1[CH][N@@]5CC[N@@]4[CH]c1c(O3)cccc1)C=N2)[N@]1[N]C=N[CH]1 ,2 N1=C[N][N@]([CH]1)[B@@H]1N2N=CN([CH]2)[Mn]234(Oc5ccccc5[CH][N@@]4CC[N@@]3[CH]c3c(O2)cccc3)N2C=NN([CH]2)[B@@H](n2ncnc2)N2N=CN([CH]2)[Mn]234(Oc5ccccc5[CH][N@@]4CC[N@@]3[CH]c3c(O2)cccc3)N2C=NN([CH]2)[B@@H](N2[CH]N([Mn]345(N6[CH]N([B@H](N7[CH]N([Mn]89%10(N%11[CH]N1N=C%11)Oc1ccccc1[CH][N@@]%10CC[N@@]9[CH]c1c(O8)cccc1)C=N7)n1ncnc1)N=C6)Oc1ccccc1[CH][N@@]5CC[N@@]4[CH]c1c(O3)cccc1)C=N2)n1ncnc1 ,2 c1ccc2c(c1)O[Mn]134([N@@]([CH]2)CC[N@]4[CH]c2c(O1)cccc2)N1C=NN([CH]1)[B@H](N1N=CN([CH]1)[Mn]124(Oc5ccccc5[CH][N@@]4CC[N@@]2[CH]c2c(O1)cccc2)N1C=NN([CH]1)[B@@H](N1N=CN([CH]1)[Mn]124(N5[CH]N([B@H](N6[CH]N([Mn]789(N%10[CH]N([B@@H](N%11[CH]N3C=N%11)n3cncn3)N=C%10)Oc3ccccc3[CH][N@@]9CC[N@@]8[CH]c3c(O7)cccc3)C=N6)n3cncn3)N=C5)Oc3ccccc3[CH][N@@]4CC[N@@]2[CH]c2c(O1)cccc2)n1cncn1)n1cncn1. Metal clusters: 8 [Cu]. The MOF has largest included sphere 4.87 A, density 1.18 g/cm3, surface area 4588.87 m2/g, accessible volume 0.42 cm3/g