CoC17N12H26CH2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and four CoC17N12H26 clusters. In each CoC17N12H26 cluster, Co(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(12), one N(6), and one N(7) atom. The Co(1)-N(1) bond length is 2.13 Å. The Co(1)-N(12) bond length is 2.16 Å. The Co(1)-N(6) bond length is 2.11 Å. The Co(1)-N(7) bond length is 2.13 Å. There are seventeen inequivalent C sites. In the first C site, C(13) is bonded in a 3-coordinate geometry to one C(16), one H(19), and one H(20) atom. The C(13)-C(16) bond length is 0.77 Å. The C(13)-H(19) bond length is 0.97 Å. The C(13)-H(20) bond length is 0.97 Å. In the second C site, C(15) is bonded in a 6-coordinate geometry to one C(14), one C(16), one N(10), one H(22), one H(23), and one H(24) atom. The C(15)-C(14) bond length is 1.05 Å. The C(15)-C(16) bond length is 1.17 Å. The C(15)-N(10) bond length is 1.55 Å. The C(15)-H(22) bond length is 1.12 Å. The C(15)-H(23) bond length is 0.97 Å. The C(15)-H(24) bond length is 0.97 Å. In the third C site, C(14) is bonded in a distorted water-like geometry to one C(15), one H(21), and one H(22) atom. The C(14)-H(21) bond length is 0.97 Å. The C(14)-H(22) bond length is 0.97 Å. In the fourth C site, C(17) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(27) atom. The C(17)-N(10) bond length is 1.30 Å. The C(17)-N(12) bond length is 1.31 Å. The C(17)-H(27) bond length is 0.93 Å. In the fifth C site, C(18) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(28) atom. The C(18)-N(11) bond length is 1.30 Å. The C(18)-N(12) bond length is 1.35 Å. The C(18)-H(28) bond length is 0.93 Å. In the sixth C site, C(16) is bonded in a 3-coordinate geometry to one C(13), one C(15), one N(10), one H(25), and one H(26) atom. The C(16)-N(10) bond length is 1.58 Å. The C(16)-H(25) bond length is 0.98 Å. The C(16)-H(26) bond length is 0.96 Å. In the seventh C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-N(2) bond length is 1.30 Å. The C(1)-H(1) bond length is 0.93 Å. In the eighth C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(2) atom. The C(2)-N(1) bond length is 1.30 Å. The C(2)-N(3) bond length is 1.35 Å. The C(2)-H(2) bond length is 0.93 Å. In the ninth C site, C(3) is bonded in a 4-coordinate geometry to one C(4), one N(3), one H(3), and one H(4) atom. The C(3)-C(4) bond length is 1.29 Å. The C(3)-N(3) bond length is 1.46 Å. The C(3)-H(3) bond length is 0.97 Å. The C(3)-H(4) bond length is 0.97 Å. In the tenth C site, C(4) is bonded in a water-like geometry to one C(3), one H(5), and one H(6) atom. The C(4)-H(5) bond length is 0.97 Å. The C(4)-H(6) bond length is 0.97 Å. In the eleventh C site, C(6) is bonded in a 3-coordinate geometry to one N(4) and two equivalent H(9,10) atoms. The C(6)-N(4) bond length is 1.45 Å. Both C(6)-H(9,10) bond lengths are 0.97 Å. In the twelfth C site, C(7) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(11) atom. The C(7)-N(4) bond length is 1.31 Å. The C(7)-N(6) bond length is 1.33 Å. The C(7)-H(11) bond length is 0.93 Å. In the thirteenth C site, C(8) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(12) atom. The C(8)-N(5) bond length is 1.29 Å. The C(8)-N(6) bond length is 1.37 Å. The C(8)-H(12) bond length is 0.93 Å. In the fourteenth C site, C(9) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(13) atom. The C(9)-N(7) bond length is 1.34 Å. The C(9)-N(8) bond length is 1.32 Å. The C(9)-H(13) bond length is 0.93 Å. In the fifteenth C site, C(10) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(14) atom. The C(10)-N(7) bond length is 1.31 Å. The C(10)-N(9) bond length is 1.30 Å. The C(10)-H(14) bond length is 0.93 Å. In the sixteenth C site, C(11) is bonded in a 4-coordinate geometry to one C(12); one N(9); and two equivalent H(15,16) atoms. The C(11)-C(12) bond length is 1.47 Å. The C(11)-N(9) bond length is 1.50 Å. Both C(11)-H(15,16) bond lengths are 0.97 Å. In the seventeenth C site, C(12) is bonded in a water-like geometry to one C(11), one H(17), and one H(18) atom. The C(12)-H(17) bond length is 0.97 Å. The C(12)-H(18) bond length is 0.97 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Co(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(1) and one N(3) atom. The N(2)-N(3) bond length is 1.37 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(2), one C(3), and one N(2) atom. In the fourth N site, N(4) is bonded in a 2-coordinate geometry to one C(6), one C(7), and one N(5) atom. The N(4)-N(5) bond length is 1.37 Å. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(8) and one N(4) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Co(1), one C(7), and one C(8) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Co(1), one C(10), and one C(9) atom. In the eighth N site, N(8) is bonded in a distorted water-like geometry to one C(9) and one N(9) atom. The N(8)-N(9) bond length is 1.36 Å. In the ninth N site, N(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(11), and one N(8) atom. In the tenth N site, N(10) is bonded in a 4-coordinate geometry to one C(15), one C(16), one C(17), and one N(11) atom. The N(10)-N(11) bond length is 1.34 Å. In the eleventh N site, N(11) is bonded in a distorted water-like geometry to one C(18) and one N(10) atom. In the twelfth N site, N(12) is bonded in a distorted trigonal planar geometry to one Co(1), one C(17), and one C(18) atom. There are twenty-four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(7) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(9) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the twelfth H site, H(15,16) is bonded in a single-bond geometry to one C(11) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(12) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(12) atom. In the fifteenth H site, H(19) is bonded in a distorted L-shaped geometry to one C(13) and one H(26) atom. The H(19)-H(26) bond length is 0.44 Å. In the sixteenth H site, H(20) is bonded in a distorted single-bond geometry to one C(13) atom. In the seventeenth H site, H(21) is bonded in a distorted single-bond geometry to one C(14) atom. In the eighteenth H site, H(22) is bonded in a 1-coordinate geometry to one C(14) and one C(15) atom. In the nineteenth H site, H(23) is bonded in a distorted single-bond geometry to one C(15) atom. In the twentieth H site, H(24) is bonded in a distorted single-bond geometry to one C(15) atom. In the twenty-first H site, H(25) is bonded in a distorted single-bond geometry to one C(16) atom. In the twenty-second H site, H(26) is bonded in a distorted single-bond geometry to one C(16) and one H(19) atom. In the twenty-third H site, H(27) is bonded in a single-bond geometry to one C(17) atom. In the twenty-fourth H site, H(28) is bonded in a single-bond geometry to one C(18) atom. Linkers: 1 C1=NC=N[N]1.C1CCC1.[CH2]CN1[CH]N=C[N]1 ,2 [CH2]CCCn1cncn1.[CH2]CN1[CH]N=C[N]1 ,4 [CH]1N=C[N]N1CCCCn1cncn1 ,1 C1=NN=C[N]1.C1CCC1.[CH2]CN1[CH]N=C[N]1. Metal clusters: 4 [Co]. The MOF has largest included sphere 9.21 A, density 0.89 g/cm3, surface area 4973.51 m2/g, accessible volume 0.67 cm3/g