CuC24H22(NO)4 is Indium-like structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of eight CuC24H22(NO)4 clusters. Cu(1) is bonded in a square co-planar geometry to two equivalent N(2) and two equivalent O(1) atoms. Both Cu(1)-N(2) bond lengths are 2.00 Å. Both Cu(1)-O(1) bond lengths are 1.93 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a single-bond geometry to one C(3) and one H(2,8) atom. The C(1)-C(3) bond length is 1.39 Å. The C(1)-H(2,8) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(7) atom. The C(2)-C(5) bond length is 1.48 Å. The C(2)-C(6) bond length is 1.41 Å. The C(2)-C(7) bond length is 1.39 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(9) atom. The C(3)-C(11) bond length is 1.39 Å. The C(3)-C(9) bond length is 1.51 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(3,4) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(3,4) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(5)-C(8) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(12), one C(2), and one N(2) atom. The C(6)-C(12) bond length is 1.50 Å. The C(6)-N(2) bond length is 1.34 Å. In the seventh C site, C(7) is bonded in a 3-coordinate geometry to one C(10), one C(2), and one N(1) atom. The C(7)-C(10) bond length is 1.49 Å. The C(7)-N(1) bond length is 1.34 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(5) and one H(3,4) atom. The C(8)-H(3,4) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(1), and one O(2) atom. The C(9)-O(1) bond length is 1.27 Å. The C(9)-O(2) bond length is 1.25 Å. In the tenth C site, C(10) is bonded in a trigonal non-coplanar geometry to one C(7); one H(5); and two equivalent H(6,7) atoms. The C(10)-H(5) bond length is 0.96 Å. Both C(10)-H(6,7) bond lengths are 0.96 Å. In the eleventh C site, C(11) is bonded in a distorted single-bond geometry to one C(3) and one H(2,8) atom. The C(11)-H(2,8) bond length is 0.93 Å. In the twelfth C site, C(12) is bonded in a trigonal non-coplanar geometry to one C(6) and three equivalent H(9,10,11) atoms. All C(12)-H(9,10,11) bond lengths are 0.96 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one C(7), one N(2), and one H(1) atom. The N(1)-N(2) bond length is 1.36 Å. The N(1)-H(1) bond length is 0.86 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Cu(1), one C(6), and one N(1) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(1) atom. In the second H site, H(2,8) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(6,7) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(9,10,11) is bonded in a single-bond geometry to one C(12) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(9) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(9) atom. Linkers: 16 Cc1n[nH]c(C)c1-c1ccc(C([O])=O)cc1. Metal clusters: 8 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 6.53 A, density 1.00 g/cm3, surface area 5013.81 m2/g, accessible volume 0.43 cm3/g