Ag2C12N2H9O3(CH)3 crystallizes in the trigonal P-3 space group. The structure consists of twelve 02329_fluka molecules inside a Ag2C12N2H9O3 framework. In the Ag2C12N2H9O3 framework, there are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one O(2) atom. The Ag(1)-N(1) bond length is 2.35 Å. The Ag(1)-O(2) bond length is 2.31 Å. In the second Ag site, Ag(2) is bonded to one N(2) and three equivalent O(1) atoms to form AgNO3 tetrahedra that share corners with three equivalent C(9)H2N2 tetrahedra. The Ag(2)-N(2) bond length is 2.29 Å. All Ag(2)-O(1) bond lengths are 2.37 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.53 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(8) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(8) bond length is 1.41 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.43 Å. The C(3)-C(8) bond length is 1.44 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(1) atom. The C(4)-H(1) bond length is 0.93 Å. In the fifth C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(4) atom. The C(7)-C(8) bond length is 1.43 Å. The C(7)-H(4) bond length is 0.93 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(7) atom. In the seventh C site, C(9) is bonded to one N(1); one N(2); and two equivalent H(5,6) atoms to form CH2N2 tetrahedra that share  a cornercorner with one Ag(2)NO3 tetrahedra, corners with two equivalent C(10)H2N2 tetrahedra, and corners with two equivalent C(9)H2N2 tetrahedra. The C(9)-N(1) bond length is 1.48 Å. The C(9)-N(2) bond length is 1.48 Å. Both C(9)-H(5,6) bond lengths are 0.97 Å. In the eighth C site, C(10) is bonded to two equivalent N(1), one H(7), and one H(8) atom to form corner-sharing CH2N2 tetrahedra. There is one shorter (1.47 Å) and one longer (1.48 Å) C(10)-N(1) bond length. The C(10)-H(7) bond length is 0.97 Å. The C(10)-H(8) bond length is 0.97 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded to one Ag(1), one C(9), and two equivalent C(10) atoms to form corner-sharing NAgC3 tetrahedra. In the second N site, N(2) is bonded to one Ag(2) and three equivalent C(9) atoms to form corner-sharing NAgC3 tetrahedra. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(5,6) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ag(2) and one C(1) atom. In the second O site, O(2) is bonded in a distorted water-like geometry to one Ag(1) and one C(1) atom. Linkers: 3 [O]C(=O)c1c2ccccc2c(C([O])=O)c2ccccc12 ,2 C1N2CN3CN1CN(C2)C3. Metal clusters: 2 [Ag]O[C]O[Ag](O[C]O[Ag])O[C]O[Ag]. RCSR code: hcb. The MOF has largest included sphere 5.98 A, density 2.01 g/cm3, surface area 2976.60 m2/g, accessible volume 0.15 cm3/g