Ho2C33N3H19O14(CH)6 crystallizes in the triclinic P-1 space group. The structure consists of twelve 02329_fluka molecules inside a Ho2C33N3H19O14 framework. In the Ho2C33N3H19O14 framework, there are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 8-coordinate geometry to one H(2), one O(1), one O(11), one O(12), one O(6), one O(8), and two equivalent O(5) atoms. The Ho(1)-H(2) bond length is 1.99 Å. The Ho(1)-O(1) bond length is 2.22 Å. The Ho(1)-O(11) bond length is 2.34 Å. The Ho(1)-O(12) bond length is 2.34 Å. The Ho(1)-O(6) bond length is 2.40 Å. The Ho(1)-O(8) bond length is 2.29 Å. There is one shorter (2.37 Å) and one longer (2.50 Å) Ho(1)-O(5) bond length. In the second Ho site, Ho(2) is bonded in a 8-coordinate geometry to one H(3), one H(4), one O(10), one O(2), one O(3), one O(4), one O(7), and one O(9) atom. The Ho(2)-H(3) bond length is 2.06 Å. The Ho(2)-H(4) bond length is 2.07 Å. The Ho(2)-O(10) bond length is 2.29 Å. The Ho(2)-O(2) bond length is 2.31 Å. The Ho(2)-O(3) bond length is 2.40 Å. The Ho(2)-O(4) bond length is 2.48 Å. The Ho(2)-O(7) bond length is 2.25 Å. The Ho(2)-O(9) bond length is 2.37 Å. There are thirty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.24 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(6) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(5) atom. The C(3)-N(1) bond length is 1.34 Å. The C(3)-H(5) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a 2-coordinate geometry to one C(5), one N(1), and one H(6) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-N(1) bond length is 1.34 Å. The C(4)-H(6) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(7) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(7) bond length is 1.49 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(2), one C(5), and one H(7) atom. The C(6)-H(7) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(5), and one C(8) atom. The C(7)-C(12) bond length is 1.40 Å. The C(7)-C(8) bond length is 1.39 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(8) atom. The C(8)-H(8) bond length is 0.93 Å. In the ninth C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(11) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-H(11) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(7) atom. The C(12)-C(13) bond length is 1.48 Å. In the eleventh C site, C(13) is bonded in a bent 120 degrees geometry to one C(12), one O(3), and one O(4) atom. The C(13)-O(3) bond length is 1.26 Å. The C(13)-O(4) bond length is 1.27 Å. In the twelfth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(5), and one O(6) atom. The C(14)-C(15) bond length is 1.49 Å. The C(14)-O(5) bond length is 1.27 Å. The C(14)-O(6) bond length is 1.24 Å. In the thirteenth C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(20) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-C(20) bond length is 1.40 Å. In the fourteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(12) atom. The C(16)-H(12) bond length is 0.93 Å. In the fifteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(20) and one H(15) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-H(15) bond length is 0.93 Å. In the sixteenth C site, C(20) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(21) atom. The C(20)-C(21) bond length is 1.49 Å. In the seventeenth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(25) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-C(25) bond length is 1.38 Å. In the eighteenth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(21), one N(2), and one H(16) atom. The C(22)-N(2) bond length is 1.34 Å. The C(22)-H(16) bond length is 0.93 Å. In the nineteenth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(24), one N(2), and one H(17) atom. The C(23)-C(24) bond length is 1.38 Å. The C(23)-N(2) bond length is 1.34 Å. The C(23)-H(17) bond length is 0.93 Å. In the twentieth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(26) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-C(26) bond length is 1.50 Å. In the twenty-first C site, C(25) is bonded in a distorted single-bond geometry to one C(21), one C(24), and one H(18) atom. The C(25)-H(18) bond length is 0.93 Å. In the twenty-second C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(7), and one O(8) atom. The C(26)-O(7) bond length is 1.25 Å. The C(26)-O(8) bond length is 1.25 Å. In the twenty-third C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(28), one O(10), and one O(9) atom. The C(27)-C(28) bond length is 1.51 Å. The C(27)-O(10) bond length is 1.27 Å. The C(27)-O(9) bond length is 1.25 Å. In the twenty-fourth C site, C(28) is bonded in a trigonal planar geometry to one C(27), one C(29), and one C(33) atom. The C(28)-C(29) bond length is 1.38 Å. The C(28)-C(33) bond length is 1.41 Å. In the twenty-fifth C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(19) atom. The C(29)-H(19) bond length is 0.93 Å. In the twenty-sixth C site, C(32) is bonded in a distorted single-bond geometry to one C(33) and one H(22) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-H(22) bond length is 0.93 Å. In the twenty-seventh C site, C(33) is bonded in a trigonal planar geometry to one C(28), one C(32), and one C(34) atom. The C(33)-C(34) bond length is 1.49 Å. In the twenty-eighth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(38) atom. The C(34)-C(35) bond length is 1.39 Å. The C(34)-C(38) bond length is 1.39 Å. In the twenty-ninth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(34), one N(3), and one H(23) atom. The C(35)-N(3) bond length is 1.34 Å. The C(35)-H(23) bond length is 0.93 Å. In the thirtieth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(37), one N(3), and one H(24) atom. The C(36)-C(37) bond length is 1.38 Å. The C(36)-N(3) bond length is 1.34 Å. The C(36)-H(24) bond length is 0.93 Å. In the thirty-first C site, C(37) is bonded in a trigonal planar geometry to one C(36), one C(38), and one C(39) atom. The C(37)-C(38) bond length is 1.39 Å. The C(37)-C(39) bond length is 1.49 Å. In the thirty-second C site, C(38) is bonded in a distorted single-bond geometry to one C(34), one C(37), and one H(25) atom. The C(38)-H(25) bond length is 0.93 Å. In the thirty-third C site, C(39) is bonded in a distorted bent 120 degrees geometry to one C(37), one O(11), and one O(12) atom. The C(39)-O(11) bond length is 1.27 Å. The C(39)-O(12) bond length is 1.26 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one C(3) and one C(4) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one C(22) and one C(23) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one C(35) and one C(36) atom. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(13) atom. The H(1)-O(13) bond length is 0.84 Å. In the second H site, H(2) is bonded in a distorted water-like geometry to one Ho(1) and one O(13) atom. The H(2)-O(13) bond length is 0.85 Å. In the third H site, H(3) is bonded in a distorted water-like geometry to one Ho(2) and one O(14) atom. The H(3)-O(14) bond length is 0.85 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one Ho(2) and one O(14) atom. The H(4)-O(14) bond length is 0.85 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(3) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(18) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the sixteenth H site, H(22) is bonded in a single-bond geometry to one C(32) atom. In the seventeenth H site, H(23) is bonded in a single-bond geometry to one C(35) atom. In the eighteenth H site, H(24) is bonded in a single-bond geometry to one C(36) atom. In the nineteenth H site, H(25) is bonded in a single-bond geometry to one C(38) atom. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted linear geometry to one Ho(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ho(2) and one C(1) atom. In the third O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Ho(1) and one C(14) atom. In the fourth O site, O(6) is bonded in a distorted single-bond geometry to one Ho(1) and one C(14) atom. In the fifth O site, O(11) is bonded in a distorted bent 150 degrees geometry to one Ho(1) and one C(39) atom. In the sixth O site, O(12) is bonded in a distorted single-bond geometry to one Ho(1) and one C(39) atom. In the seventh O site, O(13) is bonded in a bent 150 degrees geometry to one H(1) and one H(2) atom. In the eighth O site, O(14) is bonded in a water-like geometry to one H(3) and one H(4) atom. In the ninth O site, O(3) is bonded in a distorted single-bond geometry to one Ho(2) and one C(13) atom. In the tenth O site, O(4) is bonded in a single-bond geometry to one Ho(2) and one C(13) atom. In the eleventh O site, O(7) is bonded in a distorted linear geometry to one Ho(2) and one C(26) atom. In the twelfth O site, O(8) is bonded in a bent 150 degrees geometry to one Ho(1) and one C(26) atom. In the thirteenth O site, O(9) is bonded in a distorted single-bond geometry to one Ho(2) and one C(27) atom. In the fourteenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Ho(2) and one C(27) atom. Linkers: 6 [O]C(=O)c1cncc(-c2ccccc2C([O])=O)c1. Metal clusters: 4 [Ho]. The MOF has largest included sphere 4.35 A, density 1.75 g/cm3, surface area 3343.43 m2/g, accessible volume 0.19 cm3/g