(AgH16(C3N)6)3(CH)6(C9H6N)2 is Indium-derived structured and crystallizes in the cubic I2_13 space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules, eight schembl1705614 molecules, and twelve AgH16(C3N)6 clusters. In each AgH16(C3N)6 cluster, Ag(1) is bonded in a 4-coordinate geometry to two equivalent N(1) and two equivalent N(3) atoms. Both Ag(1)-N(1) bond lengths are 2.18 Å. Both Ag(1)-N(3) bond lengths are 2.37 Å. There are nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.27 Å. The C(1)-N(1) bond length is 1.36 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.33 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one N(2) atom. The C(5)-N(1) bond length is 1.32 Å. The C(5)-N(2) bond length is 1.36 Å. In the fifth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one C(8), and one N(3) atom. The C(6)-C(7) bond length is 1.51 Å. The C(6)-C(8) bond length is 1.40 Å. The C(6)-N(3) bond length is 1.32 Å. In the sixth C site, C(7) is bonded in a trigonal non-coplanar geometry to one C(6) and three equivalent H(5,6,7) atoms. All C(7)-H(5,6,7) bond lengths are 0.96 Å. In the seventh C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(6), and one C(9) atom. The C(8)-C(13) bond length is 1.51 Å. The C(8)-C(9) bond length is 1.47 Å. In the eighth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(9)-H(8) bond length is 0.93 Å. In the ninth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(11) atom. The C(13)-H(11) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a distorted bent 120 degrees geometry to one C(5) and one N(3) atom. The N(2)-N(3) bond length is 1.39 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Ag(1), one C(6), and one N(2) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(5,6,7) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. Linkers: 8 C/C(=N\[N]c1ccccn1)c1ccc(N(c2ccc(/C(C)=N/[N]c3ccccn3)cc2)c2ccc(/C(C)=N/[N]c3ccccn3)cc2)cc1. Metal clusters: 12 [Ag]. The MOF has largest included sphere 10.34 A, density 0.64 g/cm3, surface area 4963.35 m2/g, accessible volume 0.94 cm3/g