Zn4C69N6H51O13 crystallizes in the triclinic P1 space group. There are six inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one O(1), one O(11), one O(25), and one O(8) atom to form corner-sharing ZnO4 tetrahedra. The Zn(1)-O(1) bond length is 1.90 Å. The Zn(1)-O(11) bond length is 1.90 Å. The Zn(1)-O(25) bond length is 1.95 Å. The Zn(1)-O(8) bond length is 1.90 Å. In the second Zn site, Zn(2) is bonded to one O(10), one O(2), one O(25), and one O(6) atom to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(10) bond length is 1.90 Å. The Zn(2)-O(2) bond length is 1.90 Å. The Zn(2)-O(25) bond length is 1.95 Å. The Zn(2)-O(6) bond length is 1.90 Å. In the third Zn site, Zn(3,4) is bonded to one O(12), one O(25), one O(3), and one O(5) atom to form corner-sharing ZnO4 tetrahedra. The Zn(3,4)-O(12) bond length is 1.90 Å. The Zn(3,4)-O(25) bond length is 1.95 Å. The Zn(3,4)-O(3) bond length is 1.90 Å. The Zn(3,4)-O(5) bond length is 1.90 Å. In the fourth Zn site, Zn(5,7) is bonded to one O(13), one O(20), one O(23), and one O(26) atom to form corner-sharing ZnO4 tetrahedra. The Zn(5,7)-O(13) bond length is 1.90 Å. The Zn(5,7)-O(20) bond length is 1.90 Å. The Zn(5,7)-O(23) bond length is 1.90 Å. The Zn(5,7)-O(26) bond length is 1.95 Å. In the fifth Zn site, Zn(6) is bonded to one O(14), one O(18), one O(22), and one O(26) atom to form corner-sharing ZnO4 tetrahedra. The Zn(6)-O(14) bond length is 1.90 Å. The Zn(6)-O(18) bond length is 1.90 Å. The Zn(6)-O(22) bond length is 1.90 Å. The Zn(6)-O(26) bond length is 1.95 Å. In the sixth Zn site, Zn(8) is bonded to one O(16), one O(19), one O(21), and one O(26) atom to form corner-sharing ZnO4 tetrahedra. The Zn(8)-O(16) bond length is 1.90 Å. The Zn(8)-O(19) bond length is 1.90 Å. The Zn(8)-O(21) bond length is 1.90 Å. The Zn(8)-O(26) bond length is 1.95 Å. There are one hundred and seventeen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2,18); one O(1); and one O(3) atom. The C(1)-C(2,18) bond length is 1.40 Å. The C(1)-O(1) bond length is 1.32 Å. The C(1)-O(3) bond length is 1.32 Å. In the second C site, C(2,18) is bonded in a trigonal planar geometry to one C(1), one C(49), and one C(53) atom. The C(2,18)-C(49) bond length is 1.36 Å. The C(2,18)-C(53) bond length is 1.36 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(4) and two equivalent C(50,54,66,70) atoms. The C(3)-C(4) bond length is 1.38 Å. Both C(3)-C(50,54,66,70) bond lengths are 1.35 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(97), and one C(99) atom. The C(4)-C(97) bond length is 1.37 Å. The C(4)-C(99) bond length is 1.37 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(2), and one O(4) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-O(2) bond length is 1.32 Å. The C(5)-O(4) bond length is 1.32 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(5), one C(51), and one C(55) atom. The C(6)-C(51) bond length is 1.36 Å. The C(6)-C(55) bond length is 1.36 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(8) and two equivalent C(52,56,60,64) atoms. The C(7)-C(8) bond length is 1.38 Å. Both C(7)-C(52,56,60,64) bond lengths are 1.35 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(101), one C(7), and one C(98) atom. The C(8)-C(101) bond length is 1.37 Å. The C(8)-C(98) bond length is 1.37 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10,30); one O(5); and one O(7) atom. The C(9)-C(10,30) bond length is 1.40 Å. The C(9)-O(5) bond length is 1.32 Å. The C(9)-O(7) bond length is 1.32 Å. In the tenth C site, C(10,30) is bonded in a trigonal planar geometry to one C(57), one C(61), and one C(9) atom. The C(10,30)-C(57) bond length is 1.36 Å. The C(10,30)-C(61) bond length is 1.36 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(12) and two equivalent C(58,62) atoms. The C(11)-C(12) bond length is 1.38 Å. Both C(11)-C(58,62) bond lengths are 1.35 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(103), one C(105), and one C(11) atom. The C(12)-C(103) bond length is 1.37 Å. The C(12)-C(105) bond length is 1.37 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(6), and one O(8) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-O(6) bond length is 1.32 Å. The C(13)-O(8) bond length is 1.32 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(59), and one C(63) atom. The C(14)-C(59) bond length is 1.36 Å. The C(14)-C(63) bond length is 1.36 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(16) and two equivalent C(52,56,60,64) atoms. The C(15)-C(16) bond length is 1.38 Å. Both C(15)-C(52,56,60,64) bond lengths are 1.35 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(104), one C(107), and one C(15) atom. The C(16)-C(104) bond length is 1.37 Å. The C(16)-C(107) bond length is 1.37 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(2,18); one O(11); and one O(9) atom. The C(17)-C(2,18) bond length is 1.40 Å. The C(17)-O(11) bond length is 1.32 Å. The C(17)-O(9) bond length is 1.32 Å. In the eighteenth C site, C(19) is bonded in a trigonal planar geometry to one C(20) and two equivalent C(50,54,66,70) atoms. The C(19)-C(20) bond length is 1.38 Å. Both C(19)-C(50,54,66,70) bond lengths are 1.35 Å. In the nineteenth C site, C(20) is bonded in a trigonal planar geometry to one C(109), one C(113), and one C(19) atom. The C(20)-C(109) bond length is 1.37 Å. The C(20)-C(113) bond length is 1.37 Å. In the twentieth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(10), and one O(12) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-O(10) bond length is 1.32 Å. The C(21)-O(12) bond length is 1.32 Å. In the twenty-first C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(67), and one C(71) atom. The C(22)-C(67) bond length is 1.36 Å. The C(22)-C(71) bond length is 1.36 Å. In the twenty-second C site, C(23) is bonded in a trigonal planar geometry to one C(24) and two equivalent C(68,72) atoms. The C(23)-C(24) bond length is 1.38 Å. Both C(23)-C(68,72) bond lengths are 1.35 Å. In the twenty-third C site, C(24) is bonded in a trigonal planar geometry to one C(111), one C(114), and one C(23) atom. The C(24)-C(111) bond length is 1.37 Å. The C(24)-C(114) bond length is 1.37 Å. In the twenty-fourth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(13), and one O(15) atom. The C(25)-C(26) bond length is 1.40 Å. The C(25)-O(13) bond length is 1.32 Å. The C(25)-O(15) bond length is 1.32 Å. In the twenty-fifth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(73), and one C(77) atom. The C(26)-C(73) bond length is 1.36 Å. The C(26)-C(77) bond length is 1.36 Å. In the twenty-sixth C site, C(27) is bonded in a trigonal planar geometry to one C(28) and two equivalent C(74,78) atoms. The C(27)-C(28) bond length is 1.38 Å. Both C(27)-C(74,78) bond lengths are 1.35 Å. In the twenty-seventh C site, C(28) is bonded in a trigonal planar geometry to one C(115), one C(118), and one C(27) atom. The C(28)-C(115) bond length is 1.37 Å. The C(28)-C(118) bond length is 1.37 Å. In the twenty-eighth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(10,30); one O(14); and one O(16) atom. The C(29)-C(10,30) bond length is 1.40 Å. The C(29)-O(14) bond length is 1.32 Å. The C(29)-O(16) bond length is 1.32 Å. In the twenty-ninth C site, C(31) is bonded in a trigonal planar geometry to one C(32) and two equivalent C(76,80,84,88) atoms. The C(31)-C(32) bond length is 1.38 Å. Both C(31)-C(76,80,84,88) bond lengths are 1.35 Å. In the thirtieth C site, C(32) is bonded in a trigonal planar geometry to one C(117), one C(119), and one C(31) atom. The C(32)-C(117) bond length is 1.37 Å. The C(32)-C(119) bond length is 1.37 Å. In the thirty-first C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(34), one O(17), and one O(19) atom. The C(33)-C(34) bond length is 1.40 Å. The C(33)-O(17) bond length is 1.32 Å. The C(33)-O(19) bond length is 1.32 Å. In the thirty-second C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(81), and one C(85) atom. The C(34)-C(81) bond length is 1.36 Å. The C(34)-C(85) bond length is 1.36 Å. In the thirty-third C site, C(35) is bonded in a trigonal planar geometry to one C(36,48) and two equivalent C(82,86,92,96) atoms. The C(35)-C(36,48) bond length is 1.38 Å. Both C(35)-C(82,86,92,96) bond lengths are 1.35 Å. In the thirty-fourth C site, C(36,48) is bonded in a trigonal planar geometry to one C(121), one C(124), and one C(35) atom. The C(36,48)-C(121) bond length is 1.37 Å. The C(36,48)-C(124) bond length is 1.37 Å. In the thirty-fifth C site, C(37) is bonded in a distorted bent 120 degrees geometry to one C(38), one O(18), and one O(20) atom. The C(37)-C(38) bond length is 1.40 Å. The C(37)-O(18) bond length is 1.32 Å. The C(37)-O(20) bond length is 1.32 Å. In the thirty-sixth C site, C(38) is bonded in a trigonal planar geometry to one C(37), one C(83), and one C(87) atom. The C(38)-C(83) bond length is 1.36 Å. The C(38)-C(87) bond length is 1.36 Å. In the thirty-seventh C site, C(39) is bonded in a trigonal planar geometry to one C(40) and two equivalent C(76,80,84,88) atoms. The C(39)-C(40) bond length is 1.38 Å. Both C(39)-C(76,80,84,88) bond lengths are 1.35 Å. In the thirty-eighth C site, C(40) is bonded in a trigonal planar geometry to one C(122), one C(126), and one C(39) atom. The C(40)-C(122) bond length is 1.37 Å. The C(40)-C(126) bond length is 1.37 Å. In the thirty-ninth C site, C(41) is bonded in a distorted bent 120 degrees geometry to one C(42), one O(21), and one O(23) atom. The C(41)-C(42) bond length is 1.40 Å. The C(41)-O(21) bond length is 1.32 Å. The C(41)-O(23) bond length is 1.32 Å. In the fortieth C site, C(42) is bonded in a trigonal planar geometry to one C(41), one C(89), and one C(93) atom. The C(42)-C(89) bond length is 1.36 Å. The C(42)-C(93) bond length is 1.36 Å. In the forty-first C site, C(43) is bonded in a trigonal planar geometry to one C(44) and two equivalent C(90,94) atoms. The C(43)-C(44) bond length is 1.38 Å. Both C(43)-C(90,94) bond lengths are 1.35 Å. In the forty-second C site, C(44) is bonded in a trigonal planar geometry to one C(127), one C(130), and one C(43) atom. The C(44)-C(127) bond length is 1.37 Å. The C(44)-C(130) bond length is 1.37 Å. In the forty-third C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(46), one O(22), and one O(24) atom. The C(45)-C(46) bond length is 1.40 Å. The C(45)-O(22) bond length is 1.32 Å. The C(45)-O(24) bond length is 1.32 Å. In the forty-fourth C site, C(46) is bonded in a trigonal planar geometry to one C(45), one C(91), and one C(95) atom. The C(46)-C(91) bond length is 1.36 Å. The C(46)-C(95) bond length is 1.36 Å. In the forty-fifth C site, C(47) is bonded in a trigonal planar geometry to one C(36,48) and two equivalent C(82,86,92,96) atoms. The C(47)-C(36,48) bond length is 1.38 Å. Both C(47)-C(82,86,92,96) bond lengths are 1.35 Å. In the forty-sixth C site, C(49) is bonded in a distorted trigonal planar geometry to one C(2,18); one C(50,54,66,70); and one H(37,39,41,43,47,51,53,57) atom. The C(49)-C(50,54,66,70) bond length is 1.43 Å. The C(49)-H(37,39,41,43,47,51,53,57) bond length is 1.14 Å. In the forty-seventh C site, C(50,54,66,70) is bonded in a 3-coordinate geometry to one C(3), one C(49), and one H(38) atom. The C(50,54,66,70)-H(38) bond length is 1.14 Å. In the forty-eighth C site, C(51) is bonded in a distorted trigonal planar geometry to one C(52,56,60,64); one C(6); and one H(37,39,41,43,47,51,53,57) atom. The C(51)-C(52,56,60,64) bond length is 1.43 Å. The C(51)-H(37,39,41,43,47,51,53,57) bond length is 1.14 Å. In the forty-ninth C site, C(52,56,60,64) is bonded in a 3-coordinate geometry to one C(51), one C(7), and one H(40) atom. The C(52,56,60,64)-H(40) bond length is 1.14 Å. In the fiftieth C site, C(53) is bonded in a distorted trigonal planar geometry to one C(2,18); one C(50,54,66,70); and one H(37,39,41,43,47,51,53,57) atom. The C(53)-C(50,54,66,70) bond length is 1.43 Å. The C(53)-H(37,39,41,43,47,51,53,57) bond length is 1.14 Å. In the fifty-first C site, C(55) is bonded in a distorted trigonal planar geometry to one C(52,56,60,64); one C(6); and one H(37,39,41,43,47,51,53,57) atom. The C(55)-C(52,56,60,64) bond length is 1.43 Å. The C(55)-H(37,39,41,43,47,51,53,57) bond length is 1.14 Å. In the fifty-second C site, C(57) is bonded in a distorted trigonal planar geometry to one C(10,30); one C(58,62); and one H(45,49,63,67,79,83) atom. The C(57)-C(58,62) bond length is 1.43 Å. The C(57)-H(45,49,63,67,79,83) bond length is 1.14 Å. In the fifty-third C site, C(58,62) is bonded in a 3-coordinate geometry to one C(11), one C(57), and one H(46) atom. The C(58,62)-H(46) bond length is 1.14 Å. In the fifty-fourth C site, C(59) is bonded in a distorted trigonal planar geometry to one C(14); one C(52,56,60,64); and one H(37,39,41,43,47,51,53,57) atom. The C(59)-C(52,56,60,64) bond length is 1.43 Å. The C(59)-H(37,39,41,43,47,51,53,57) bond length is 1.14 Å. In the fifty-fifth C site, C(61) is bonded in a distorted trigonal planar geometry to one C(10,30); one C(58,62); and one H(45,49,63,67,79,83) atom. The C(61)-C(58,62) bond length is 1.43 Å. The C(61)-H(45,49,63,67,79,83) bond length is 1.14 Å. In the fifty-sixth C site, C(63) is bonded in a distorted trigonal planar geometry to one C(14); one C(52,56,60,64); and one H(37,39,41,43,47,51,53,57) atom. The C(63)-C(52,56,60,64) bond length is 1.43 Å. The C(63)-H(37,39,41,43,47,51,53,57) bond length is 1.14 Å. In the fifty-seventh C site, C(65) is bonded in a distorted trigonal planar geometry to one C(2,18); one C(50,54,66,70); and one H(37,39,41,43,47,51,53,57) atom. The C(65)-C(2,18) bond length is 1.36 Å. The C(65)-C(50,54,66,70) bond length is 1.43 Å. The C(65)-H(37,39,41,43,47,51,53,57) bond length is 1.14 Å. In the fifty-eighth C site, C(67) is bonded in a distorted trigonal planar geometry to one C(22); one C(68,72); and one H(55,59,61,65) atom. The C(67)-C(68,72) bond length is 1.43 Å. The C(67)-H(55,59,61,65) bond length is 1.14 Å. In the fifty-ninth C site, C(68,72) is bonded in a 3-coordinate geometry to one C(23), one C(67), and one H(56) atom. The C(68,72)-H(56) bond length is 1.14 Å. In the sixtieth C site, C(69) is bonded in a distorted trigonal planar geometry to one C(2,18); one C(50,54,66,70); and one H(37,39,41,43,47,51,53,57) atom. The C(69)-C(2,18) bond length is 1.36 Å. The C(69)-C(50,54,66,70) bond length is 1.43 Å. The C(69)-H(37,39,41,43,47,51,53,57) bond length is 1.14 Å. In the sixty-first C site, C(71) is bonded in a distorted trigonal planar geometry to one C(22); one C(68,72); and one H(55,59,61,65) atom. The C(71)-C(68,72) bond length is 1.43 Å. The C(71)-H(55,59,61,65) bond length is 1.14 Å. In the sixty-second C site, C(73) is bonded in a distorted trigonal planar geometry to one C(26); one C(74,78); and one H(55,59,61,65) atom. The C(73)-C(74,78) bond length is 1.43 Å. The C(73)-H(55,59,61,65) bond length is 1.14 Å. In the sixty-third C site, C(74,78) is bonded in a 3-coordinate geometry to one C(27), one C(73), and one H(62) atom. The C(74,78)-H(62) bond length is 1.14 Å. In the sixty-fourth C site, C(75,79) is bonded in a distorted trigonal planar geometry to one C(10,30); one C(76,80,84,88); and one H(45,49,63,67,79,83) atom. The C(75,79)-C(10,30) bond length is 1.36 Å. The C(75,79)-C(76,80,84,88) bond length is 1.43 Å. The C(75,79)-H(45,49,63,67,79,83) bond length is 1.14 Å. In the sixty-fifth C site, C(76,80,84,88) is bonded in a 3-coordinate geometry to one C(31); one C(75,79); and one H(64,68) atom. The C(76,80,84,88)-H(64,68) bond length is 1.14 Å. In the sixty-sixth C site, C(77) is bonded in a distorted trigonal planar geometry to one C(26); one C(74,78); and one H(55,59,61,65) atom. The C(77)-C(74,78) bond length is 1.43 Å. The C(77)-H(55,59,61,65) bond length is 1.14 Å. In the sixty-seventh C site, C(81) is bonded in a distorted trigonal planar geometry to one C(34); one C(82,86,92,96); and one H(69,73,77,81) atom. The C(81)-C(82,86,92,96) bond length is 1.43 Å. The C(81)-H(69,73,77,81) bond length is 1.14 Å. In the sixty-eighth C site, C(82,86,92,96) is bonded in a 3-coordinate geometry to one C(35), one C(81), and one H(70) atom. The C(82,86,92,96)-H(70) bond length is 1.14 Å. In the sixty-ninth C site, C(83) is bonded in a distorted trigonal planar geometry to one C(38); one C(76,80,84,88); and one H(71,75) atom. The C(83)-C(76,80,84,88) bond length is 1.43 Å. The C(83)-H(71,75) bond length is 1.14 Å. In the seventieth C site, C(85) is bonded in a distorted trigonal planar geometry to one C(34); one C(82,86,92,96); and one H(69,73,77,81) atom. The C(85)-C(82,86,92,96) bond length is 1.43 Å. The C(85)-H(69,73,77,81) bond length is 1.14 Å. In the seventy-first C site, C(87) is bonded in a distorted trigonal planar geometry to one C(38); one C(76,80,84,88); and one H(71,75) atom. The C(87)-C(76,80,84,88) bond length is 1.43 Å. The C(87)-H(71,75) bond length is 1.14 Å. In the seventy-second C site, C(89) is bonded in a distorted trigonal planar geometry to one C(42); one C(90,94); and one H(69,73,77,81) atom. The C(89)-C(90,94) bond length is 1.43 Å. The C(89)-H(69,73,77,81) bond length is 1.14 Å. In the seventy-third C site, C(90,94) is bonded in a 3-coordinate geometry to one C(43), one C(89), and one H(78) atom. The C(90,94)-H(78) bond length is 1.14 Å. In the seventy-fourth C site, C(91) is bonded in a distorted trigonal planar geometry to one C(46); one C(82,86,92,96); and one H(45,49,63,67,79,83) atom. The C(91)-C(82,86,92,96) bond length is 1.43 Å. The C(91)-H(45,49,63,67,79,83) bond length is 1.14 Å. In the seventy-fifth C site, C(93) is bonded in a distorted trigonal planar geometry to one C(42); one C(90,94); and one H(69,73,77,81) atom. The C(93)-C(90,94) bond length is 1.43 Å. The C(93)-H(69,73,77,81) bond length is 1.14 Å. In the seventy-sixth C site, C(95) is bonded in a distorted trigonal planar geometry to one C(46); one C(82,86,92,96); and one H(45,49,63,67,79,83) atom. The C(95)-C(82,86,92,96) bond length is 1.43 Å. The C(95)-H(45,49,63,67,79,83) bond length is 1.14 Å. In the seventy-seventh C site, C(97) is bonded in a distorted trigonal planar geometry to one C(129), one C(4), and one H(91) atom. The C(97)-C(129) bond length is 1.43 Å. The C(97)-H(91) bond length is 1.14 Å. In the seventy-eighth C site, C(98) is bonded in a distorted trigonal planar geometry to one C(130); one C(8); and one H(92,94,102) atom. The C(98)-C(130) bond length is 1.43 Å. The C(98)-H(92,94,102) bond length is 1.14 Å. In the seventy-ninth C site, C(99) is bonded in a 3-coordinate geometry to one C(131), one C(4), and one N(1) atom. The C(99)-C(131) bond length is 1.43 Å. The C(99)-N(1) bond length is 1.53 Å. In the eightieth C site, C(100) is bonded in a tetrahedral geometry to one N(1) and three equivalent H(1,33,34) atoms. The C(100)-N(1) bond length is 1.54 Å. All C(100)-H(1,33,34) bond lengths are 1.14 Å. In the eighty-first C site, C(101) is bonded in a 3-coordinate geometry to one C(127), one C(8), and one N(2) atom. The C(101)-C(127) bond length is 1.43 Å. The C(101)-N(2) bond length is 1.53 Å. In the eighty-second C site, C(102) is bonded in a tetrahedral geometry to one N(2) and three equivalent H(2,5,6,25,26,27,28,35,36) atoms. The C(102)-N(2) bond length is 1.54 Å. All C(102)-H(2,5,6,25,26,27,28,35,36) bond lengths are 1.14 Å. In the eighty-third C site, C(103) is bonded in a distorted trigonal planar geometry to one C(12), one C(121), and one H(93) atom. The C(103)-C(121) bond length is 1.43 Å. The C(103)-H(93) bond length is 1.14 Å. In the eighty-fourth C site, C(104) is bonded in a distorted trigonal planar geometry to one C(126); one C(16); and one H(92,94,102) atom. The C(104)-C(126) bond length is 1.43 Å. The C(104)-H(92,94,102) bond length is 1.14 Å. In the eighty-fifth C site, C(105) is bonded in a 3-coordinate geometry to one C(12), one C(124), and one N(3) atom. The C(105)-C(124) bond length is 1.43 Å. The C(105)-N(3) bond length is 1.53 Å. In the eighty-sixth C site, C(106) is bonded in a tetrahedral geometry to one N(3) and three equivalent H(3,7,23,24,29,30) atoms. The C(106)-N(3) bond length is 1.54 Å. All C(106)-H(3,7,23,24,29,30) bond lengths are 1.14 Å. In the eighty-seventh C site, C(107) is bonded in a 3-coordinate geometry to one C(122), one C(16), and one N(4) atom. The C(107)-C(122) bond length is 1.43 Å. The C(107)-N(4) bond length is 1.53 Å. In the eighty-eighth C site, C(108) is bonded in a tetrahedral geometry to one N(4) and three equivalent H(4,31,32) atoms. The C(108)-N(4) bond length is 1.54 Å. All C(108)-H(4,31,32) bond lengths are 1.14 Å. In the eighty-ninth C site, C(109) is bonded in a 3-coordinate geometry to one C(119), one C(20), and one N(5) atom. The C(109)-C(119) bond length is 1.43 Å. The C(109)-N(5) bond length is 1.53 Å. In the ninetieth C site, C(110,120) is bonded in a tetrahedral geometry to one N(5) and three equivalent H(2,5,6,25,26,27,28,35,36) atoms. The C(110,120)-N(5) bond length is 1.54 Å. All C(110,120)-H(2,5,6,25,26,27,28,35,36) bond lengths are 1.14 Å. In the ninety-first C site, C(111) is bonded in a 3-coordinate geometry to one C(115), one C(24), and one N(6) atom. The C(111)-C(115) bond length is 1.43 Å. The C(111)-N(6) bond length is 1.53 Å. In the ninety-second C site, C(112) is bonded in a tetrahedral geometry to one N(6) and three equivalent H(2,5,6,25,26,27,28,35,36) atoms. The C(112)-N(6) bond length is 1.54 Å. All C(112)-H(2,5,6,25,26,27,28,35,36) bond lengths are 1.14 Å. In the ninety-third C site, C(113) is bonded in a distorted trigonal planar geometry to one C(117); one C(20); and one H(95,98) atom. The C(113)-C(117) bond length is 1.43 Å. The C(113)-H(95,98) bond length is 1.14 Å. In the ninety-fourth C site, C(114) is bonded in a distorted trigonal planar geometry to one C(118), one C(24), and one H(96) atom. The C(114)-C(118) bond length is 1.43 Å. The C(114)-H(96) bond length is 1.14 Å. In the ninety-fifth C site, C(115) is bonded in a 3-coordinate geometry to one C(111), one C(28), and one N(7) atom. The C(115)-N(7) bond length is 1.53 Å. In the ninety-sixth C site, C(116) is bonded in a tetrahedral geometry to one N(7) and three equivalent H(3,7,23,24,29,30) atoms. The C(116)-N(7) bond length is 1.54 Å. All C(116)-H(3,7,23,24,29,30) bond lengths are 1.14 Å. In the ninety-seventh C site, C(117) is bonded in a distorted trigonal planar geometry to one C(113), one C(32), and one H(97) atom. The C(117)-H(97) bond length is 1.14 Å. In the ninety-eighth C site, C(118) is bonded in a distorted trigonal planar geometry to one C(114); one C(28); and one H(95,98) atom. The C(118)-H(95,98) bond length is 1.14 Å. In the ninety-ninth C site, C(119) is bonded in a 3-coordinate geometry to one C(109), one C(32), and one N(8) atom. The C(119)-N(8) bond length is 1.53 Å. In the one hundredth C site, C(121) is bonded in a distorted trigonal planar geometry to one C(103); one C(36,48); and one H(99,101) atom. The C(121)-H(99,101) bond length is 1.14 Å. In the one hundred and first C site, C(122) is bonded in a 3-coordinate geometry to one C(107), one C(40), and one N(9) atom. The C(122)-N(9) bond length is 1.53 Å. In the one hundred and second C site, C(123) is bonded in a tetrahedral geometry to one N(9) and three equivalent H(8,18,19) atoms. The C(123)-N(9) bond length is 1.54 Å. All C(123)-H(8,18,19) bond lengths are 1.14 Å. In the one hundred and third C site, C(124) is bonded in a 3-coordinate geometry to one C(105); one C(36,48); and one N(10) atom. The C(124)-N(10) bond length is 1.53 Å. In the one hundred and fourth C site, C(125) is bonded in a tetrahedral geometry to one N(10) and three equivalent H(9,11,12,13,16,17) atoms. The C(125)-N(10) bond length is 1.54 Å. All C(125)-H(9,11,12,13,16,17) bond lengths are 1.14 Å. In the one hundred and fifth C site, C(126) is bonded in a distorted trigonal planar geometry to one C(104), one C(40), and one H(100) atom. The C(126)-H(100) bond length is 1.14 Å. In the one hundred and sixth C site, C(127) is bonded in a 3-coordinate geometry to one C(101), one C(44), and one N(11) atom. The C(127)-N(11) bond length is 1.53 Å. In the one hundred and seventh C site, C(128) is bonded in a tetrahedral geometry to one N(11) and three equivalent H(10,14,15) atoms. The C(128)-N(11) bond length is 1.54 Å. All C(128)-H(10,14,15) bond lengths are 1.14 Å. In the one hundred and eighth C site, C(129) is bonded in a distorted trigonal planar geometry to one C(36,48); one C(97); and one H(99,101) atom. The C(129)-C(36,48) bond length is 1.37 Å. The C(129)-H(99,101) bond length is 1.14 Å. In the one hundred and ninth C site, C(130) is bonded in a distorted trigonal planar geometry to one C(44); one C(98); and one H(92,94,102) atom. The C(130)-H(92,94,102) bond length is 1.14 Å. In the one hundred and tenth C site, C(131) is bonded in a 3-coordinate geometry to one C(36,48); one C(99); and one N(12) atom. The C(131)-C(36,48) bond length is 1.37 Å. The C(131)-N(12) bond length is 1.53 Å. In the one hundred and eleventh C site, C(132) is bonded in a tetrahedral geometry to one N(12) and three equivalent H(9,11,12,13,16,17) atoms. The C(132)-N(12) bond length is 1.54 Å. All C(132)-H(9,11,12,13,16,17) bond lengths are 1.14 Å. In the one hundred and twelfth C site, C(133) is bonded in a trigonal planar geometry to one N(1), one N(12), and one H(85) atom. The C(133)-N(1) bond length is 1.46 Å. The C(133)-N(12) bond length is 1.46 Å. The C(133)-H(85) bond length is 1.14 Å. In the one hundred and thirteenth C site, C(134) is bonded in a trigonal planar geometry to one N(11), one N(2), and one H(86) atom. The C(134)-N(11) bond length is 1.46 Å. The C(134)-N(2) bond length is 1.46 Å. The C(134)-H(86) bond length is 1.14 Å. In the one hundred and fourteenth C site, C(135) is bonded in a trigonal planar geometry to one N(10), one N(3), and one H(87) atom. The C(135)-N(10) bond length is 1.46 Å. The C(135)-N(3) bond length is 1.46 Å. The C(135)-H(87) bond length is 1.14 Å. In the one hundred and fifteenth C site, C(136) is bonded in a distorted trigonal planar geometry to one N(4), one N(9), and one H(88) atom. The C(136)-N(4) bond length is 1.46 Å. The C(136)-N(9) bond length is 1.46 Å. The C(136)-H(88) bond length is 1.14 Å. In the one hundred and sixteenth C site, C(137) is bonded in a trigonal planar geometry to one N(5), one N(8), and one H(89) atom. The C(137)-N(5) bond length is 1.46 Å. The C(137)-N(8) bond length is 1.46 Å. The C(137)-H(89) bond length is 1.14 Å. In the one hundred and seventeenth C site, C(138) is bonded in a trigonal planar geometry to one N(6), one N(7), and one H(90) atom. The C(138)-N(6) bond length is 1.46 Å. The C(138)-N(7) bond length is 1.46 Å. The C(138)-H(90) bond length is 1.14 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(100), one C(133), and one C(99) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(101), one C(102), and one C(134) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one C(105), one C(106), and one C(135) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(107), one C(108), and one C(136) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one C(109); one C(110,120); and one C(137) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one C(111), one C(112), and one C(138) atom. In the seventh N site, N(7) is bonded in a distorted trigonal planar geometry to one C(115), one C(116), and one C(138) atom. In the eighth N site, N(8) is bonded in a distorted trigonal planar geometry to one C(110,120); one C(119); and one C(137) atom. The N(8)-C(110,120) bond length is 1.54 Å. In the ninth N site, N(9) is bonded in a distorted trigonal planar geometry to one C(122), one C(123), and one C(136) atom. In the tenth N site, N(10) is bonded in a distorted trigonal planar geometry to one C(124), one C(125), and one C(135) atom. In the eleventh N site, N(11) is bonded in a distorted trigonal planar geometry to one C(127), one C(128), and one C(134) atom. In the twelfth N site, N(12) is bonded in a distorted trigonal planar geometry to one C(131), one C(132), and one C(133) atom. There are fifty inequivalent H sites. In the first H site, H(1,33,34) is bonded in a single-bond geometry to one C(100) atom. In the second H site, H(2,5,6,25,26,27,28,35,36) is bonded in a single-bond geometry to one C(102) atom. In the third H site, H(3,7,23,24,29,30) is bonded in a single-bond geometry to one C(106) atom. In the fourth H site, H(4,31,32) is bonded in a single-bond geometry to one C(108) atom. In the fifth H site, H(8,18,19) is bonded in a single-bond geometry to one C(123) atom. In the sixth H site, H(9,11,12,13,16,17) is bonded in a single-bond geometry to one C(125) atom. In the seventh H site, H(10,14,15) is bonded in a single-bond geometry to one C(128) atom. In the eighth H site, H(20,21,22) is bonded in a single-bond geometry to one C(110,120) atom. The H(20,21,22)-C(110,120) bond length is 1.14 Å. In the ninth H site, H(37,39,41,43,47,51,53,57) is bonded in a single-bond geometry to one C(49) atom. In the tenth H site, H(38) is bonded in a single-bond geometry to one C(50,54,66,70) atom. In the eleventh H site, H(40) is bonded in a single-bond geometry to one C(52,56,60,64) atom. In the twelfth H site, H(42) is bonded in a single-bond geometry to one C(50,54,66,70) atom. The H(42)-C(50,54,66,70) bond length is 1.14 Å. In the thirteenth H site, H(44) is bonded in a single-bond geometry to one C(52,56,60,64) atom. The H(44)-C(52,56,60,64) bond length is 1.14 Å. In the fourteenth H site, H(45,49,63,67,79,83) is bonded in a single-bond geometry to one C(57) atom. In the fifteenth H site, H(46) is bonded in a single-bond geometry to one C(58,62) atom. In the sixteenth H site, H(48) is bonded in a single-bond geometry to one C(52,56,60,64) atom. The H(48)-C(52,56,60,64) bond length is 1.14 Å. In the seventeenth H site, H(50) is bonded in a single-bond geometry to one C(58,62) atom. The H(50)-C(58,62) bond length is 1.14 Å. In the eighteenth H site, H(52) is bonded in a single-bond geometry to one C(52,56,60,64) atom. The H(52)-C(52,56,60,64) bond length is 1.14 Å. In the nineteenth H site, H(54) is bonded in a single-bond geometry to one C(50,54,66,70) atom. The H(54)-C(50,54,66,70) bond length is 1.14 Å. In the twentieth H site, H(55,59,61,65) is bonded in a single-bond geometry to one C(67) atom. In the twenty-first H site, H(56) is bonded in a single-bond geometry to one C(68,72) atom. In the twenty-second H site, H(58) is bonded in a single-bond geometry to one C(50,54,66,70) atom. The H(58)-C(50,54,66,70) bond length is 1.14 Å. In the twenty-third H site, H(60) is bonded in a single-bond geometry to one C(68,72) atom. The H(60)-C(68,72) bond length is 1.14 Å. In the twenty-fourth H site, H(62) is bonded in a single-bond geometry to one C(74,78) atom. In the twenty-fifth H site, H(64,68) is bonded in a single-bond geometry to one C(76,80,84,88) atom. In the twenty-sixth H site, H(66) is bonded in a single-bond geometry to one C(74,78) atom. The H(66)-C(74,78) bond length is 1.14 Å. In the twenty-seventh H site, H(69,73,77,81) is bonded in a single-bond geometry to one C(81) atom. In the twenty-eighth H site, H(70) is bonded in a single-bond geometry to one C(82,86,92,96) atom. In the twenty-ninth H site, H(71,75) is bonded in a single-bond geometry to one C(83) atom. In the thirtieth H site, H(72) is bonded in a single-bond geometry to one C(76,80,84,88) atom. The H(72)-C(76,80,84,88) bond length is 1.14 Å. In the thirty-first H site, H(74) is bonded in a single-bond geometry to one C(82,86,92,96) atom. The H(74)-C(82,86,92,96) bond length is 1.14 Å. In the thirty-second H site, H(76) is bonded in a single-bond geometry to one C(76,80,84,88) atom. The H(76)-C(76,80,84,88) bond length is 1.14 Å. In the thirty-third H site, H(78) is bonded in a single-bond geometry to one C(90,94) atom. In the thirty-fourth H site, H(80) is bonded in a single-bond geometry to one C(82,86,92,96) atom. The H(80)-C(82,86,92,96) bond length is 1.14 Å. In the thirty-fifth H site, H(82) is bonded in a single-bond geometry to one C(90,94) atom. The H(82)-C(90,94) bond length is 1.14 Å. In the thirty-sixth H site, H(84) is bonded in a single-bond geometry to one C(82,86,92,96) atom. The H(84)-C(82,86,92,96) bond length is 1.14 Å. In the thirty-seventh H site, H(85) is bonded in a single-bond geometry to one C(133) atom. In the thirty-eighth H site, H(86) is bonded in a single-bond geometry to one C(134) atom. In the thirty-ninth H site, H(87) is bonded in a single-bond geometry to one C(135) atom. In the fortieth H site, H(88) is bonded in a single-bond geometry to one C(136) atom. In the forty-first H site, H(89) is bonded in a single-bond geometry to one C(137) atom. In the forty-second H site, H(90) is bonded in a single-bond geometry to one C(138) atom. In the forty-third H site, H(91) is bonded in a single-bond geometry to one C(97) atom. In the forty-fourth H site, H(92,94,102) is bonded in a single-bond geometry to one C(98) atom. In the forty-fifth H site, H(93) is bonded in a single-bond geometry to one C(103) atom. In the forty-sixth H site, H(95,98) is bonded in a single-bond geometry to one C(113) atom. In the forty-seventh H site, H(96) is bonded in a single-bond geometry to one C(114) atom. In the forty-eighth H site, H(97) is bonded in a single-bond geometry to one C(117) atom. In the forty-ninth H site, H(99,101) is bonded in a single-bond geometry to one C(121) atom. In the fiftieth H site, H(100) is bonded in a single-bond geometry to one C(126) atom. There are twenty-six inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(5) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(3,4) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(3,4) and one C(5) atom. The O(4)-Zn(3,4) bond length is 1.90 Å. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(3,4) and one C(9) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(13) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(3,4) and one C(9) atom. The O(7)-Zn(3,4) bond length is 1.90 Å. In the eighth O site, O(8) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(13) atom. In the ninth O site, O(9) is bonded in a distorted bent 120 degrees geometry to one Zn(3,4) and one C(17) atom. The O(9)-Zn(3,4) bond length is 1.90 Å. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one C(21) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(17) atom. In the twelfth O site, O(12) is bonded in a distorted bent 120 degrees geometry to one Zn(3,4) and one C(21) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 120 degrees geometry to one Zn(5,7) and one C(25) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Zn(6) and one C(29) atom. In the fifteenth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Zn(5,7) and one C(25) atom. The O(15)-Zn(5,7) bond length is 1.90 Å. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Zn(8) and one C(29) atom. In the seventeenth O site, O(17) is bonded in a distorted bent 120 degrees geometry to one Zn(5,7) and one C(33) atom. The O(17)-Zn(5,7) bond length is 1.90 Å. In the eighteenth O site, O(18) is bonded in a distorted bent 120 degrees geometry to one Zn(6) and one C(37) atom. In the nineteenth O site, O(19) is bonded in a distorted bent 120 degrees geometry to one Zn(8) and one C(33) atom. In the twentieth O site, O(20) is bonded in a distorted bent 120 degrees geometry to one Zn(5,7) and one C(37) atom. In the twenty-first O site, O(21) is bonded in a distorted bent 120 degrees geometry to one Zn(8) and one C(41) atom. In the twenty-second O site, O(22) is bonded in a distorted bent 120 degrees geometry to one Zn(6) and one C(45) atom. In the twenty-third O site, O(23) is bonded in a distorted bent 120 degrees geometry to one Zn(5,7) and one C(41) atom. In the twenty-fourth O site, O(24) is bonded in a distorted bent 120 degrees geometry to one Zn(5,7) and one C(45) atom. The O(24)-Zn(5,7) bond length is 1.90 Å. In the twenty-fifth O site, O(25) is bonded in a tetrahedral geometry to one Zn(1); one Zn(2); and two equivalent Zn(3,4) atoms. In the twenty-sixth O site, O(26) is bonded in a tetrahedral geometry to one Zn(6); one Zn(8); and two equivalent Zn(5,7) atoms. Linkers: 6 CN1[CH]N(C)c2c(-c3ccc(C([O])=O)cc3)ccc(-c3ccc(C([O])=O)cc3)c21. Metal clusters: 2 [C]1O[Zn]2O[C]O[Zn@]34O[C]O[Zn](O1)O[C]O[Zn@](O[C]O2)(O[C]O3)O4. RCSR code: pcu. The MOF has largest included sphere 24.61 A, density 0.24 g/cm3, surface area 4953.51 m2/g, accessible volume 3.78 cm3/g