Dy3C59N7H31O19(CH)9 crystallizes in the triclinic P-1 space group. The structure consists of eighteen 02329_fluka molecules inside a Dy3C59N7H31O19 framework. In the Dy3C59N7H31O19 framework, there are three inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 9-coordinate geometry to one N(3), one N(4), one O(1), one O(2), one O(3), one O(4), one O(5), and two equivalent O(6) atoms. The Dy(1)-N(3) bond length is 2.54 Å. The Dy(1)-N(4) bond length is 2.58 Å. The Dy(1)-O(1) bond length is 2.46 Å. The Dy(1)-O(2) bond length is 2.43 Å. The Dy(1)-O(3) bond length is 2.35 Å. The Dy(1)-O(4) bond length is 2.32 Å. The Dy(1)-O(5) bond length is 2.41 Å. There is one shorter (2.33 Å) and one longer (2.73 Å) Dy(1)-O(6) bond length. In the second Dy site, Dy(2) is bonded in a 8-coordinate geometry to one N(1), one N(2), one O(10), one O(17), one O(18), one O(7), one O(8), and one O(9) atom. The Dy(2)-N(1) bond length is 2.56 Å. The Dy(2)-N(2) bond length is 2.55 Å. The Dy(2)-O(10) bond length is 2.33 Å. The Dy(2)-O(17) bond length is 2.50 Å. The Dy(2)-O(18) bond length is 2.37 Å. The Dy(2)-O(7) bond length is 2.34 Å. The Dy(2)-O(8) bond length is 2.26 Å. The Dy(2)-O(9) bond length is 2.29 Å. In the third Dy site, Dy(3) is bonded in a 8-coordinate geometry to one N(5), one N(6), one O(11), one O(12), one O(13), one O(14), one O(15), and one O(16) atom. The Dy(3)-N(5) bond length is 2.62 Å. The Dy(3)-N(6) bond length is 2.52 Å. The Dy(3)-O(11) bond length is 2.31 Å. The Dy(3)-O(12) bond length is 2.33 Å. The Dy(3)-O(13) bond length is 2.30 Å. The Dy(3)-O(14) bond length is 2.29 Å. The Dy(3)-O(15) bond length is 2.44 Å. The Dy(3)-O(16) bond length is 2.42 Å. There are fifty-nine inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(7) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-C(7) bond length is 1.50 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-C(8) bond length is 1.51 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a bent 120 degrees geometry to one C(1), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.24 Å. The C(7)-O(2) bond length is 1.28 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(3), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.26 Å. The C(8)-O(4) bond length is 1.24 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(15) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(14) bond length is 1.40 Å. The C(9)-C(15) bond length is 1.48 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(5) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-H(5) bond length is 0.93 Å. In the tenth C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(16) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(16) bond length is 1.49 Å. In the eleventh C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(12)-H(6) bond length is 0.93 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. In the thirteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(5), and one O(6) atom. The C(15)-O(5) bond length is 1.24 Å. The C(15)-O(6) bond length is 1.27 Å. In the fourteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(7), and one O(8) atom. The C(16)-O(7) bond length is 1.24 Å. The C(16)-O(8) bond length is 1.26 Å. In the fifteenth C site, C(17) is bonded in a trigonal planar geometry to one C(18), one C(22), and one C(23) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-C(22) bond length is 1.39 Å. The C(17)-C(23) bond length is 1.50 Å. In the sixteenth C site, C(18) is bonded in a single-bond geometry to one C(17), one C(19), and one H(9) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(9) bond length is 0.93 Å. In the seventeenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.37 Å. The C(19)-C(24) bond length is 1.50 Å. In the eighteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(10) atom. The C(20)-H(10) bond length is 0.93 Å. In the nineteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(17) and one H(12) atom. The C(22)-H(12) bond length is 0.93 Å. In the twentieth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(10), and one O(9) atom. The C(23)-O(10) bond length is 1.25 Å. The C(23)-O(9) bond length is 1.25 Å. In the twenty-first C site, C(24) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(11), and one O(12) atom. The C(24)-O(11) bond length is 1.26 Å. The C(24)-O(12) bond length is 1.26 Å. In the twenty-second C site, C(25) is bonded in a trigonal planar geometry to one C(26), one C(30), and one C(31) atom. The C(25)-C(26) bond length is 1.39 Å. The C(25)-C(30) bond length is 1.39 Å. The C(25)-C(31) bond length is 1.50 Å. In the twenty-third C site, C(26) is bonded in a distorted single-bond geometry to one C(25), one C(27), and one H(13) atom. The C(26)-C(27) bond length is 1.38 Å. The C(26)-H(13) bond length is 0.93 Å. In the twenty-fourth C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(32) atom. The C(27)-C(28) bond length is 1.37 Å. The C(27)-C(32) bond length is 1.50 Å. In the twenty-fifth C site, C(28) is bonded in a distorted single-bond geometry to one C(27) and one H(14) atom. The C(28)-H(14) bond length is 0.93 Å. In the twenty-sixth C site, C(30) is bonded in a distorted single-bond geometry to one C(25) and one H(16) atom. The C(30)-H(16) bond length is 0.93 Å. In the twenty-seventh C site, C(31) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(13), and one O(14) atom. The C(31)-O(13) bond length is 1.25 Å. The C(31)-O(14) bond length is 1.26 Å. In the twenty-eighth C site, C(32) is bonded in a bent 120 degrees geometry to one C(27), one O(15), and one O(16) atom. The C(32)-O(15) bond length is 1.26 Å. The C(32)-O(16) bond length is 1.27 Å. In the twenty-ninth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(17) atom. The C(33)-N(3) bond length is 1.33 Å. The C(33)-H(17) bond length is 0.93 Å. In the thirtieth C site, C(35) is bonded in a distorted single-bond geometry to one C(36) and one H(19) atom. The C(35)-C(36) bond length is 1.37 Å. The C(35)-H(19) bond length is 0.93 Å. In the thirty-first C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(38) atom. The C(36)-C(37) bond length is 1.43 Å. The C(36)-C(38) bond length is 1.54 Å. In the thirty-second C site, C(37) is bonded in a distorted trigonal planar geometry to one C(36), one C(44), and one N(3) atom. The C(37)-C(44) bond length is 1.44 Å. The C(37)-N(3) bond length is 1.35 Å. In the thirty-third C site, C(38) is bonded in a distorted single-bond geometry to one C(36) and one H(20) atom. The C(38)-H(20) bond length is 0.93 Å. In the thirty-fourth C site, C(39) is bonded in a distorted single-bond geometry to one C(40) and one H(21) atom. The C(39)-C(40) bond length is 1.47 Å. The C(39)-H(21) bond length is 0.93 Å. In the thirty-fifth C site, C(40) is bonded in a trigonal planar geometry to one C(39), one C(41), and one C(44) atom. The C(40)-C(41) bond length is 1.34 Å. The C(40)-C(44) bond length is 1.48 Å. In the thirty-sixth C site, C(41) is bonded in a distorted single-bond geometry to one C(40) and one H(22) atom. The C(41)-H(22) bond length is 0.93 Å. In the thirty-seventh C site, C(43) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(24) atom. The C(43)-N(4) bond length is 1.33 Å. The C(43)-H(24) bond length is 0.93 Å. In the thirty-eighth C site, C(44) is bonded in a distorted trigonal planar geometry to one C(37), one C(40), and one N(4) atom. The C(44)-N(4) bond length is 1.37 Å. In the thirty-ninth C site, C(45) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(25) atom. The C(45)-N(2) bond length is 1.31 Å. The C(45)-H(25) bond length is 0.93 Å. In the fortieth C site, C(47) is bonded in a distorted single-bond geometry to one C(48) and one H(27) atom. The C(47)-C(48) bond length is 1.37 Å. The C(47)-H(27) bond length is 0.93 Å. In the forty-first C site, C(48) is bonded in a trigonal planar geometry to one C(47), one C(49), and one C(50) atom. The C(48)-C(49) bond length is 1.42 Å. The C(48)-C(50) bond length is 1.45 Å. In the forty-second C site, C(49) is bonded in a distorted trigonal planar geometry to one C(48), one C(56), and one N(2) atom. The C(49)-C(56) bond length is 1.44 Å. The C(49)-N(2) bond length is 1.35 Å. In the forty-third C site, C(50) is bonded in a distorted trigonal planar geometry to one C(48), one C(51), and one H(28) atom. The C(50)-C(51) bond length is 1.31 Å. The C(50)-H(28) bond length is 0.93 Å. In the forty-fourth C site, C(51) is bonded in a distorted single-bond geometry to one C(50), one C(52), and one H(29) atom. The C(51)-C(52) bond length is 1.42 Å. The C(51)-H(29) bond length is 0.93 Å. In the forty-fifth C site, C(52) is bonded in a trigonal planar geometry to one C(51), one C(53), and one C(56) atom. The C(52)-C(53) bond length is 1.36 Å. The C(52)-C(56) bond length is 1.42 Å. In the forty-sixth C site, C(53) is bonded in a distorted single-bond geometry to one C(52), one C(54), and one H(30) atom. The C(53)-C(54) bond length is 1.36 Å. The C(53)-H(30) bond length is 0.93 Å. In the forty-seventh C site, C(54) is bonded in a distorted trigonal planar geometry to one C(53), one C(55), and one H(31) atom. The C(54)-C(55) bond length is 1.41 Å. The C(54)-H(31) bond length is 0.93 Å. In the forty-eighth C site, C(55) is bonded in a distorted bent 120 degrees geometry to one C(54), one N(1), and one H(32) atom. The C(55)-N(1) bond length is 1.32 Å. The C(55)-H(32) bond length is 0.93 Å. In the forty-ninth C site, C(56) is bonded in a distorted trigonal planar geometry to one C(49), one C(52), and one N(1) atom. The C(56)-N(1) bond length is 1.35 Å. In the fiftieth C site, C(57) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(33) atom. The C(57)-N(5) bond length is 1.33 Å. The C(57)-H(33) bond length is 0.93 Å. In the fifty-first C site, C(59) is bonded in a distorted single-bond geometry to one C(60) and one H(35) atom. The C(59)-C(60) bond length is 1.40 Å. The C(59)-H(35) bond length is 0.93 Å. In the fifty-second C site, C(60) is bonded in a trigonal planar geometry to one C(59), one C(61), and one C(62) atom. The C(60)-C(61) bond length is 1.42 Å. The C(60)-C(62) bond length is 1.44 Å. In the fifty-third C site, C(61) is bonded in a distorted trigonal planar geometry to one C(60), one C(68), and one N(5) atom. The C(61)-C(68) bond length is 1.44 Å. The C(61)-N(5) bond length is 1.36 Å. In the fifty-fourth C site, C(62) is bonded in a distorted single-bond geometry to one C(60) and one H(36) atom. The C(62)-H(36) bond length is 0.93 Å. In the fifty-fifth C site, C(63) is bonded in a distorted single-bond geometry to one C(64) and one H(37) atom. The C(63)-C(64) bond length is 1.43 Å. The C(63)-H(37) bond length is 0.93 Å. In the fifty-sixth C site, C(64) is bonded in a trigonal planar geometry to one C(63), one C(65), and one C(68) atom. The C(64)-C(65) bond length is 1.40 Å. The C(64)-C(68) bond length is 1.40 Å. In the fifty-seventh C site, C(65) is bonded in a distorted single-bond geometry to one C(64) and one H(38) atom. The C(65)-H(38) bond length is 0.93 Å. In the fifty-eighth C site, C(67) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(40) atom. The C(67)-N(6) bond length is 1.34 Å. The C(67)-H(40) bond length is 0.93 Å. In the fifty-ninth C site, C(68) is bonded in a distorted trigonal planar geometry to one C(61), one C(64), and one N(6) atom. The C(68)-N(6) bond length is 1.35 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Dy(2), one C(55), and one C(56) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Dy(2), one C(45), and one C(49) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Dy(1), one C(33), and one C(37) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one Dy(1), one C(43), and one C(44) atom. In the fifth N site, N(5) is bonded in a distorted bent 120 degrees geometry to one Dy(3), one C(57), and one C(61) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Dy(3), one C(67), and one C(68) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one O(17), one O(18), and one O(19) atom. The N(7)-O(17) bond length is 1.24 Å. The N(7)-O(18) bond length is 1.27 Å. The N(7)-O(19) bond length is 1.23 Å. There are thirty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(26) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(28) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(30) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(33) atom. In the fourteenth H site, H(19) is bonded in a single-bond geometry to one C(35) atom. In the fifteenth H site, H(20) is bonded in a single-bond geometry to one C(38) atom. In the sixteenth H site, H(21) is bonded in a single-bond geometry to one C(39) atom. In the seventeenth H site, H(22) is bonded in a single-bond geometry to one C(41) atom. In the eighteenth H site, H(24) is bonded in a single-bond geometry to one C(43) atom. In the nineteenth H site, H(25) is bonded in a single-bond geometry to one C(45) atom. In the twentieth H site, H(27) is bonded in a single-bond geometry to one C(47) atom. In the twenty-first H site, H(28) is bonded in a single-bond geometry to one C(50) atom. In the twenty-second H site, H(29) is bonded in a single-bond geometry to one C(51) atom. In the twenty-third H site, H(30) is bonded in a single-bond geometry to one C(53) atom. In the twenty-fourth H site, H(31) is bonded in a single-bond geometry to one C(54) atom. In the twenty-fifth H site, H(32) is bonded in a single-bond geometry to one C(55) atom. In the twenty-sixth H site, H(33) is bonded in a single-bond geometry to one C(57) atom. In the twenty-seventh H site, H(35) is bonded in a single-bond geometry to one C(59) atom. In the twenty-eighth H site, H(36) is bonded in a single-bond geometry to one C(62) atom. In the twenty-ninth H site, H(37) is bonded in a single-bond geometry to one C(63) atom. In the thirtieth H site, H(38) is bonded in a single-bond geometry to one C(65) atom. In the thirty-first H site, H(40) is bonded in a single-bond geometry to one C(67) atom. There are nineteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Dy(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted L-shaped geometry to one Dy(1) and one C(7) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Dy(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one C(8) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Dy(1) and one C(15) atom. In the sixth O site, O(6) is bonded in a 2-coordinate geometry to two equivalent Dy(1) and one C(15) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Dy(2) and one C(16) atom. In the eighth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one Dy(2) and one C(16) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Dy(2) and one C(23) atom. In the tenth O site, O(10) is bonded in a distorted bent 120 degrees geometry to one Dy(2) and one C(23) atom. In the eleventh O site, O(11) is bonded in a bent 150 degrees geometry to one Dy(3) and one C(24) atom. In the twelfth O site, O(12) is bonded in a distorted bent 150 degrees geometry to one Dy(3) and one C(24) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Dy(3) and one C(31) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 120 degrees geometry to one Dy(3) and one C(31) atom. In the fifteenth O site, O(15) is bonded in a distorted L-shaped geometry to one Dy(3) and one C(32) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one Dy(3) and one C(32) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Dy(2) and one N(7) atom. In the eighteenth O site, O(18) is bonded in a distorted water-like geometry to one Dy(2) and one N(7) atom. In the nineteenth O site, O(19) is bonded in a single-bond geometry to one N(7) atom. Linkers: 8 [O]C(=O)c1cccc(C([O])=O)c1. Metal clusters: 2 [C]1O[Dy]234(O1)O[C]O[Dy]1(O[C]O1)(O[C]O2)(O[C]O3)O[C]O4 ,1 [O]N1O[Dy]234(O[C]O[Dy]5(O[C]O2)(O[C]O3)(O[C]O4)ON([O])O5)O1. RCSR code: mot. The MOF has largest included sphere 7.33 A, density 1.58 g/cm3, surface area 3536.99 m2/g, accessible volume 0.25 cm3/g