CdC12H8(NO2)2CdC11H8(NO)2(CH)3(CH2)3 is Indium-derived structured and crystallizes in the orthorhombic Pna2_1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, twelve 02329_fluka molecules, four CdC11H8(NO)2 clusters, and four CdC12H8(NO2)2 clusters. In each CdC11H8(NO)2 cluster, Cd(2) is bonded in a 4-coordinate geometry to one N(2), one N(4), one O(5), and one O(6) atom. The Cd(2)-N(2) bond length is 2.34 Å. The Cd(2)-N(4) bond length is 2.33 Å. The Cd(2)-O(5) bond length is 2.27 Å. The Cd(2)-O(6) bond length is 2.60 Å. There are eleven inequivalent C sites. In the first C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(19) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-H(19) bond length is 0.93 Å. In the second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(27) atom. The C(22)-C(23) bond length is 1.39 Å. The C(22)-C(27) bond length is 1.47 Å. In the third C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(20) atom. The C(23)-H(20) bond length is 0.93 Å. In the fourth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(26), one N(4), and one H(22) atom. The C(25)-C(26) bond length is 1.36 Å. The C(25)-N(4) bond length is 1.35 Å. The C(25)-H(22) bond length is 0.93 Å. In the fifth C site, C(26) is bonded in a distorted single-bond geometry to one C(25), one C(27), and one H(23) atom. The C(26)-C(27) bond length is 1.38 Å. The C(26)-H(23) bond length is 0.93 Å. In the sixth C site, C(27) is bonded in a trigonal planar geometry to one C(22), one C(26), and one C(28) atom. The C(27)-C(28) bond length is 1.40 Å. In the seventh C site, C(28) is bonded in a distorted single-bond geometry to one C(27) and one H(24) atom. The C(28)-H(24) bond length is 0.93 Å. In the eighth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(25) atom. The C(29)-N(4) bond length is 1.31 Å. The C(29)-H(25) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(5) and one O(6) atom. The C(9)-O(5) bond length is 1.23 Å. The C(9)-O(6) bond length is 1.22 Å. In the tenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(14) atom. The C(15)-N(2) bond length is 1.33 Å. The C(15)-H(14) bond length is 0.93 Å. In the eleventh C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(17) atom. The C(19)-N(2) bond length is 1.33 Å. The C(19)-H(17) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Cd(2), one C(15), and one C(19) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Cd(2), one C(25), and one C(29) atom. There are eight inequivalent H sites. In the first H site, H(14) is bonded in a single-bond geometry to one C(15) atom. In the second H site, H(17) is bonded in a single-bond geometry to one C(19) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(21) atom. In the fourth H site, H(20) is bonded in a single-bond geometry to one C(23) atom. In the fifth H site, H(22) is bonded in a single-bond geometry to one C(25) atom. In the sixth H site, H(23) is bonded in a single-bond geometry to one C(26) atom. In the seventh H site, H(24) is bonded in a single-bond geometry to one C(28) atom. In the eighth H site, H(25) is bonded in a single-bond geometry to one C(29) atom. There are two inequivalent O sites. In the first O site, O(5) is bonded in a distorted water-like geometry to one Cd(2) and one C(9) atom. In the second O site, O(6) is bonded in a single-bond geometry to one Cd(2) and one C(9) atom. In each CdC12H8(NO2)2 cluster, Cd(1) is bonded in a 6-coordinate geometry to one N(1), one N(3), one O(1), one O(2), one O(3), and one O(4) atom. The Cd(1)-N(1) bond length is 2.36 Å. The Cd(1)-N(3) bond length is 2.37 Å. The Cd(1)-O(1) bond length is 2.37 Å. The Cd(1)-O(2) bond length is 2.47 Å. The Cd(1)-O(3) bond length is 2.22 Å. The Cd(1)-O(4) bond length is 2.66 Å. There are twelve inequivalent C sites. In the first C site, C(24) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(18,21) atom. The C(24)-N(3) bond length is 1.33 Å. The C(24)-H(18,21) bond length is 0.93 Å. In the second C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(8)-O(3) bond length is 1.22 Å. The C(8)-O(4) bond length is 1.24 Å. In the third C site, C(7) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(7)-O(1) bond length is 1.26 Å. The C(7)-O(2) bond length is 1.25 Å. In the fourth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one N(1), and one H(10) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-N(1) bond length is 1.30 Å. The C(10)-H(10) bond length is 0.93 Å. In the fifth C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(11) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-H(11) bond length is 0.93 Å. In the sixth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-C(17) bond length is 1.49 Å. In the seventh C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(12) atom. The C(13)-H(12) bond length is 0.93 Å. In the eighth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(13) atom. The C(14)-N(1) bond length is 1.34 Å. The C(14)-H(13) bond length is 0.93 Å. In the ninth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(15) atom. The C(16)-C(17) bond length is 1.38 Å. The C(16)-H(15) bond length is 0.93 Å. In the tenth C site, C(17) is bonded in a trigonal planar geometry to one C(12), one C(16), and one C(18) atom. The C(17)-C(18) bond length is 1.40 Å. In the eleventh C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(16) atom. The C(18)-H(16) bond length is 0.93 Å. In the twelfth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(18,21) atom. The C(20)-N(3) bond length is 1.34 Å. The C(20)-H(18,21) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(1), one C(10), and one C(14) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cd(1), one C(20), and one C(24) atom. There are seven inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the fourth H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(15) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(16) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(18,21) is bonded in a single-bond geometry to one C(20) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Cd(1) and one C(7) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(1) and one C(7) atom. In the third O site, O(3) is bonded in a distorted water-like geometry to one Cd(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one Cd(1) and one C(8) atom. Linkers: 4 [O]C(=O)[C@H]1C[C@@H](C([O])=O)C[C@@H](C([O])=O)C1 ,8 c1cc(-c2ccncc2)ccn1. Metal clusters: 4 O=[C]O[Cd]1O[C]O1 ,4 O=[C]O[Cd]. The MOF has largest included sphere 6.23 A, density 1.27 g/cm3, surface area 4318.68 m2/g, accessible volume 0.32 cm3/g