Zn2C30H30(NO2)3 crystallizes in the cubic I-43d space group. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in an octahedral geometry to three equivalent N(1) and three equivalent O(1) atoms. All Zn(1)-N(1) bond lengths are 2.20 Å. All Zn(1)-O(1) bond lengths are 2.08 Å. In the second Zn site, Zn(2) is bonded in a trigonal non-coplanar geometry to three equivalent O(2) atoms. All Zn(2)-O(2) bond lengths are 1.92 Å. There are ten inequivalent C sites. In the first C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(1) bond length is 1.51 Å. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(7) bond length is 1.37 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-H(2) bond length is 0.95 Å. In the fourth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-C(8) bond length is 1.52 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(3) atom. The C(6)-C(7) bond length is 1.35 Å. The C(6)-H(3) bond length is 0.95 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one H(4) atom. The C(7)-H(4) bond length is 0.95 Å. In the seventh C site, C(8) is bonded in a 3-coordinate geometry to one C(5); one N(1); and two equivalent H(5,6) atoms. The C(8)-N(1) bond length is 1.50 Å. Both C(8)-H(5,6) bond lengths are 0.99 Å. In the eighth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-O(1) bond length is 1.19 Å. The C(1)-O(2) bond length is 1.29 Å. In the ninth C site, C(9) is bonded in a 3-coordinate geometry to one N(1) and two equivalent H(7,8) atoms. The C(9)-N(1) bond length is 1.46 Å. Both C(9)-H(7,8) bond lengths are 0.99 Å. In the tenth C site, C(10) is bonded in a 3-coordinate geometry to one N(1), one H(10), and one H(9) atom. The C(10)-N(1) bond length is 1.47 Å. The C(10)-H(10) bond length is 0.99 Å. The C(10)-H(9) bond length is 0.99 Å. N(1) is bonded to one Zn(1), one C(10), one C(8), and one C(9) atom to form corner-sharing NZnC3 tetrahedra. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(7,8) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. Linkers: 10 [O]C(=O)c1ccc(CN2CCN(Cc3ccc(C([O])=O)cc3)CCN(Cc3ccc(C([O])=O)cc3)CC2)cc1. Metal clusters: 8 [C]1O[Zn]2O[C]O[Zn](O1)O[C]O2. RCSR code: srs. The MOF has largest included sphere 5.45 A, density 1.01 g/cm3, surface area 4133.51 m2/g, accessible volume 0.58 cm3/g