Cu3C38H16(NO6)2(CH)4 crystallizes in the cubic Pm-3m space group. The structure consists of twenty-four 02329_fluka molecules inside a Cu3C38H16(NO6)2 framework. In the Cu3C38H16(NO6)2 framework, there are three inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square co-planar geometry to four equivalent O(3) atoms. All Cu(1)-O(3) bond lengths are 1.98 Å. In the second Cu site, Cu(2) is bonded in a distorted square co-planar geometry to four equivalent O(2) atoms. All Cu(2)-O(2) bond lengths are 1.95 Å. In the third Cu site, Cu(3) is bonded in a distorted square co-planar geometry to four equivalent O(1) atoms. All Cu(3)-O(1) bond lengths are 1.96 Å. There are eleven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(1), one C(10), and one C(2) atom. The C(1)-C(1) bond length is 1.42 Å. The C(1)-C(10) bond length is 1.38 Å. The C(1)-C(2) bond length is 1.42 Å. In the second C site, C(2) is bonded in a single-bond geometry to one C(1) and one N(1) atom. The C(2)-N(1) bond length is 1.37 Å. In the third C site, C(4) is bonded in a trigonal planar geometry to one C(12) and two equivalent C(8) atoms. The C(4)-C(12) bond length is 1.49 Å. Both C(4)-C(8) bond lengths are 1.30 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(11), one C(8), and one H(4) atom. The C(5)-C(11) bond length is 1.26 Å. The C(5)-C(8) bond length is 1.47 Å. The C(5)-H(4) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a bent 120 degrees geometry to one C(9), one O(1), and one O(2) atom. The C(6)-C(9) bond length is 1.49 Å. The C(6)-O(1) bond length is 1.26 Å. The C(6)-O(2) bond length is 1.26 Å. In the sixth C site, C(7) is bonded in a distorted single-bond geometry to one C(9) and one H(5) atom. The C(7)-C(9) bond length is 1.41 Å. The C(7)-H(5) bond length is 0.93 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(4), one C(5), and one H(2) atom. The C(8)-H(2) bond length is 0.93 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(6), and one C(7) atom. The C(9)-C(10) bond length is 1.38 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(1), one C(9), and one H(3) atom. The C(10)-H(3) bond length is 0.93 Å. In the tenth C site, C(11) is bonded in a distorted trigonal planar geometry to two equivalent C(5) and one N(1) atom. The C(11)-N(1) bond length is 1.42 Å. In the eleventh C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(4) and two equivalent O(3) atoms. Both C(12)-O(3) bond lengths are 1.24 Å. N(1) is bonded in a trigonal planar geometry to one C(11) and two equivalent C(2) atoms. There are four inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(7) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(3) and one C(6) atom. In the second O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(6) atom. In the third O site, O(3) is bonded in a distorted single-bond geometry to one Cu(1) and one C(12) atom. Linkers: 12 [O]C(=O)c1ccc(-n2c3ccc(C([O])=O)cc3c3cc(C([O])=O)ccc32)cc1. Metal clusters: 9 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: gee. The MOF has largest included sphere 22.42 A, density 0.43 g/cm3, surface area 3952.01 m2/g, accessible volume 1.76 cm3/g