Zn9C36H12(N6O13)2(CH2)6(CH3)6 crystallizes in the trigonal P-3c1 space group. The structure consists of twelve 02329_fluka molecules and twelve 02329_fluka molecules inside a Zn9C36H12(N6O13)2 framework. In the Zn9C36H12(N6O13)2 framework, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(1), one N(2), one O(1), one O(3), and one O(5) atom to form distorted corner-sharing ZnN2O3 trigonal bipyramids. The Zn(1)-N(1) bond length is 2.04 Å. The Zn(1)-N(2) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 2.24 Å. The Zn(1)-O(3) bond length is 2.18 Å. The Zn(1)-O(5) bond length is 2.06 Å. In the second Zn site, Zn(2) is bonded in a see-saw-like geometry to two equivalent O(2) and two equivalent O(4) atoms. Both Zn(2)-O(2) bond lengths are 2.03 Å. Both Zn(2)-O(4) bond lengths are 2.11 Å. There are six inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(1)-C(4) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(5), one O(3), and one O(4) atom. The C(2)-C(5) bond length is 1.49 Å. The C(2)-O(3) bond length is 1.31 Å. The C(2)-O(4) bond length is 1.26 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one N(2) atom. The C(3)-C(6) bond length is 1.50 Å. The C(3)-N(1) bond length is 1.37 Å. The C(3)-N(2) bond length is 1.36 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(1), one C(5), and one N(2) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-N(2) bond length is 1.39 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one N(1) atom. The C(5)-N(1) bond length is 1.39 Å. In the sixth C site, C(6) is bonded in a water-like geometry to one C(3) and two equivalent H(1,2) atoms. Both C(6)-H(1,2) bond lengths are 0.97 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(3), and one C(5) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(3), and one C(4) atom. H(1,2) is bonded in a single-bond geometry to one C(6) atom. There are five inequivalent O sites. In the first O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(2) atom. In the second O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(2) atom. In the third O site, O(5) is bonded in a trigonal planar geometry to three equivalent Zn(1) atoms. In the fourth O site, O(1) is bonded in a distorted water-like geometry to one Zn(1) and one C(1) atom. In the fifth O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(2) and one C(1) atom. Linkers: 11 CCCC1=NC(C([O])=O)=C(C([O])=O)[N]1. Metal clusters: 18 [Zn]. The MOF has largest included sphere 5.15 A, density 1.64 g/cm3, surface area 3830.32 m2/g, accessible volume 0.29 cm3/g