AgC5N2H6 crystallizes in the cubic I-43d space group. The structure consists of a AgC5N2H6 framework. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a linear geometry to one N(1) and one N(2) atom. The Ag(1)-N(1) bond length is 2.04 Å. The Ag(1)-N(2) bond length is 2.04 Å. In the second Ag site, Ag(2) is bonded in a linear geometry to one N(3) and one N(4) atom. The Ag(2)-N(3) bond length is 2.04 Å. The Ag(2)-N(4) bond length is 2.05 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a trigonal non-coplanar geometry to one C(2); one H(3); and two equivalent H(1,2) atoms. The C(1)-C(2) bond length is 1.49 Å. The C(1)-H(3) bond length is 0.97 Å. Both C(1)-H(1,2) bond lengths are 0.97 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(1) atom. The C(2)-C(3) bond length is 1.42 Å. The C(2)-N(1) bond length is 1.36 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.34 Å. The C(3)-C(8) bond length is 1.51 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(2) atom. The C(4)-C(5) bond length is 1.56 Å. The C(4)-N(2) bond length is 1.35 Å. In the fifth C site, C(5) is bonded in a trigonal non-coplanar geometry to one C(4); one H(5); and two equivalent H(4,6) atoms. The C(5)-H(5) bond length is 0.97 Å. Both C(5)-H(4,6) bond lengths are 0.97 Å. In the sixth C site, C(6) is bonded in a trigonal non-coplanar geometry to one C(7); one H(9); and two equivalent H(7,8) atoms. The C(6)-C(7) bond length is 1.50 Å. The C(6)-H(9) bond length is 0.97 Å. Both C(6)-H(7,8) bond lengths are 0.97 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one C(8), and one N(3) atom. The C(7)-C(8) bond length is 1.36 Å. The C(7)-N(3) bond length is 1.35 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(3), one C(7), and one C(9) atom. The C(8)-C(9) bond length is 1.35 Å. In the ninth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one N(4) atom. The C(9)-C(10) bond length is 1.47 Å. The C(9)-N(4) bond length is 1.31 Å. In the tenth C site, C(10) is bonded in a trigonal non-coplanar geometry to one C(9), one H(10), one H(11), and one H(12) atom. The C(10)-H(10) bond length is 0.97 Å. The C(10)-H(11) bond length is 0.97 Å. The C(10)-H(12) bond length is 0.97 Å. There are four inequivalent N sites. In the first N site, N(2) is bonded in a 3-coordinate geometry to one Ag(1), one C(4), and one N(1) atom. The N(2)-N(1) bond length is 1.38 Å. In the second N site, N(4) is bonded in a 3-coordinate geometry to one Ag(2), one C(9), and one N(3) atom. The N(4)-N(3) bond length is 1.38 Å. In the third N site, N(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one C(2), and one N(2) atom. In the fourth N site, N(3) is bonded in a 3-coordinate geometry to one Ag(2), one C(7), and one N(4) atom. There are nine inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(4,6) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(7,8) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(6) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. Linkers: 9 C[C]1N=NC(C)=C1C1=C(C)[N]N=C1C ,4 CC1=N[N]C(C)=C1C1=C(C)[N]N=C1C ,7 CC1=NN=C(C)[C]1C1=C(C)[N]N=C1C ,4 C[C]1N=NC(C)=C1C1=C(C)N=N[C]1C. Metal clusters: 16 N1=N\[Ag]/N=N\[Ag]/N=N\[Ag]/1. The MOF has largest included sphere 6.26 A, density 1.61 g/cm3, surface area 3392.18 m2/g, accessible volume 0.30 cm3/g