CuC32H20(NS2)4 crystallizes in the tetragonal P4/n space group. Cu(1) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. All Cu(1)-N(1) bond lengths are 2.06 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one S(1) atom. The C(1)-C(2) bond length is 1.34 Å. The C(1)-C(6) bond length is 1.47 Å. The C(1)-S(1) bond length is 1.76 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one H(1), and one S(2) atom. The C(2)-H(1) bond length is 0.93 Å. The C(2)-S(2) bond length is 1.73 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(3), one S(1), and one S(2) atom. The C(3)-C(3) bond length is 1.34 Å. The C(3)-S(1) bond length is 1.75 Å. The C(3)-S(2) bond length is 1.76 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one N(1), and one H(2) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-N(1) bond length is 1.35 Å. The C(4)-H(2) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4), one C(6), and one H(3) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(3) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.38 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(5) atom. The C(8)-N(1) bond length is 1.33 Å. The C(8)-H(5) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(4), and one C(8) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in an L-shaped geometry to one C(1) and one C(3) atom. In the second S site, S(2) is bonded in an L-shaped geometry to one C(2) and one C(3) atom. Linkers: 4 C1=C(c2ccncc2)S/C(=C2\SC=C(c3ccncc3)S2)S1. Metal clusters: 2 [Cu]. The MOF has largest included sphere 5.22 A, density 1.45 g/cm3, surface area 4316.54 m2/g, accessible volume 0.23 cm3/g