AgC14H14(NS)2 crystallizes in the orthorhombic Iba2 space group. Ag(1) is bonded in a distorted trigonal pyramidal geometry to one N(1), one N(2), one S(1), and one S(2) atom. The Ag(1)-N(1) bond length is 2.32 Å. The Ag(1)-N(2) bond length is 2.33 Å. The Ag(1)-S(1) bond length is 2.65 Å. The Ag(1)-S(2) bond length is 2.61 Å. There are fourteen inequivalent C sites. In the first C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(8) atom. The C(9)-C(10) bond length is 1.37 Å. The C(9)-C(13) bond length is 1.38 Å. The C(9)-C(8) bond length is 1.56 Å. In the second C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(10) atom. The C(10)-C(11) bond length is 1.46 Å. The C(10)-H(10) bond length is 0.93 Å. In the third C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.35 Å. The C(11)-C(14) bond length is 1.47 Å. In the fourth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(2), and one H(11) atom. The C(12)-N(2) bond length is 1.34 Å. The C(12)-H(11) bond length is 0.93 Å. In the fifth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one H(12) atom. The C(13)-N(2) bond length is 1.43 Å. The C(13)-H(12) bond length is 0.93 Å. In the sixth C site, C(14) is bonded in a water-like geometry to one C(11); two equivalent H(13,14); and one S(1) atom. Both C(14)-H(13,14) bond lengths are 0.97 Å. The C(14)-S(1) bond length is 1.87 Å. In the seventh C site, C(1) is bonded in a water-like geometry to one C(2), one H(1), one H(2), and one S(1) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-H(1) bond length is 0.97 Å. The C(1)-H(2) bond length is 0.97 Å. The C(1)-S(1) bond length is 1.76 Å. In the eighth C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.43 Å. The C(2)-C(6) bond length is 1.34 Å. In the ninth C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(3) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-H(3) bond length is 0.93 Å. In the tenth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.36 Å. The C(4)-C(7) bond length is 1.57 Å. In the eleventh C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one N(1), and one H(4) atom. The C(5)-N(1) bond length is 1.43 Å. The C(5)-H(4) bond length is 0.93 Å. In the twelfth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(5) atom. The C(6)-N(1) bond length is 1.29 Å. The C(6)-H(5) bond length is 0.93 Å. In the thirteenth C site, C(7) is bonded in a water-like geometry to one C(4); two equivalent H(6,7); and one S(2) atom. Both C(7)-H(6,7) bond lengths are 0.97 Å. The C(7)-S(2) bond length is 1.87 Å. In the fourteenth C site, C(8) is bonded in a water-like geometry to one C(9), one H(8), one H(9), and one S(2) atom. The C(8)-H(8) bond length is 0.97 Å. The C(8)-H(9) bond length is 0.97 Å. The C(8)-S(2) bond length is 1.75 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(5), and one C(6) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(12), and one C(13) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(6,7) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(8) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(13,14) is bonded in a single-bond geometry to one C(14) atom. There are two inequivalent S sites. In the first S site, S(1) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(1), and one C(14) atom. In the second S site, S(2) is bonded in a trigonal non-coplanar geometry to one Ag(1), one C(7), and one C(8) atom. Linkers: 8 c1ncc2cc1CSCc1cncc(c1)CSC2. Metal clusters: 8 [Ag]. The MOF has largest included sphere 6.00 A, density 1.32 g/cm3, surface area 3907.67 m2/g, accessible volume 0.33 cm3/g