ZnC24H9(O2F3)3 crystallizes in the orthorhombic Aea2 space group. Zn(1) is bonded in a tetrahedral geometry to one O(1), one O(3), one O(4), and one O(5) atom. The Zn(1)-O(1) bond length is 1.94 Å. The Zn(1)-O(3) bond length is 1.96 Å. The Zn(1)-O(4) bond length is 2.01 Å. The Zn(1)-O(5) bond length is 1.97 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.21 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(8) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(8) bond length is 1.50 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3), one C(5), and one H(1) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-H(1) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(9) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-C(9) bond length is 1.48 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(6)-H(2) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(7)-H(3) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a distorted trigonal non-coplanar geometry to one C(3), one F(1), one F(2), and one F(3) atom. The C(8)-F(1) bond length is 1.32 Å. The C(8)-F(2) bond length is 1.33 Å. The C(8)-F(3) bond length is 1.35 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(5) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-C(14) bond length is 1.40 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11), one C(9), and one H(4) atom. The C(10)-C(11) bond length is 1.39 Å. The C(10)-H(4) bond length is 0.95 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(15) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(15) bond length is 1.51 Å. In the twelfth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(16) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-C(16) bond length is 1.51 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(5) atom. The C(13)-H(5) bond length is 0.95 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(14)-H(6) bond length is 0.95 Å. In the fifteenth C site, C(15) is bonded in a trigonal non-coplanar geometry to one C(11), one F(4), one F(5), and one F(6) atom. The C(15)-F(4) bond length is 1.34 Å. The C(15)-F(5) bond length is 1.33 Å. The C(15)-F(6) bond length is 1.35 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(3), and one O(4) atom. The C(16)-O(3) bond length is 1.26 Å. The C(16)-O(4) bond length is 1.25 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(5), and one O(6) atom. The C(17)-C(18) bond length is 1.53 Å. The C(17)-O(5) bond length is 1.24 Å. The C(17)-O(6) bond length is 1.25 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(23) atom. The C(18)-C(19) bond length is 1.41 Å. The C(18)-C(23) bond length is 1.36 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-C(24) bond length is 1.49 Å. In the twentieth C site, C(20) is bonded in a distorted single-bond geometry to one C(19), one C(21), and one H(7) atom. The C(20)-C(21) bond length is 1.41 Å. The C(20)-H(7) bond length is 0.95 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(21), and one C(22) atom. The C(21)-C(21) bond length is 1.52 Å. The C(21)-C(22) bond length is 1.35 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(8) atom. The C(22)-H(8) bond length is 0.95 Å. In the twenty-third C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(9) atom. The C(23)-H(9) bond length is 0.95 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal non-coplanar geometry to one C(19), one F(7), one F(8), and one F(9) atom. The C(24)-F(7) bond length is 1.33 Å. The C(24)-F(8) bond length is 1.36 Å. The C(24)-F(9) bond length is 1.34 Å. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(20) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(23) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(16) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one C(16) atom. In the fifth O site, O(5) is bonded in a water-like geometry to one Zn(1) and one C(17) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(17) atom. There are nine inequivalent F sites. In the first F site, F(1) is bonded in a single-bond geometry to one C(8) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(8) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(8) atom. In the fourth F site, F(4) is bonded in a single-bond geometry to one C(15) atom. In the fifth F site, F(5) is bonded in a single-bond geometry to one C(15) atom. In the sixth F site, F(6) is bonded in a single-bond geometry to one C(15) atom. In the seventh F site, F(7) is bonded in a single-bond geometry to one C(24) atom. In the eighth F site, F(8) is bonded in a single-bond geometry to one C(24) atom. In the ninth F site, F(9) is bonded in a single-bond geometry to one C(24) atom. Linkers: 12 [O]C(=O)c1ccc(-c2ccc(C([O])=O)c(C(F)(F)F)c2)cc1C(F)(F)F. Metal clusters: 8 [Zn]. The MOF has largest included sphere 7.56 A, density 1.08 g/cm3, surface area 4220.74 m2/g, accessible volume 0.61 cm3/g