PrCd4H76(C3O)40(H11(C7O)2)4 is Indium-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two H11(C7O)2 clusters and one PrCd4H76(C3O)40 cluster. In each H11(C7O)2 cluster, there are twenty-eight inequivalent C sites. In the first C site, C(45,133) is bonded in a distorted single-bond geometry to one C(46,134) and one H(29,89) atom. The C(45,133)-C(46,134) bond length is 1.42 Å. The C(45,133)-H(29,89) bond length is 0.93 Å. In the second C site, C(46,134) is bonded in a trigonal planar geometry to one C(45,133); one C(47,135); and one C(49,137) atom. The C(46,134)-C(47,135) bond length is 1.35 Å. The C(46,134)-C(49,137) bond length is 1.49 Å. In the third C site, C(47,135) is bonded in a distorted single-bond geometry to one C(46,134) and one H(30,90) atom. The C(47,135)-H(30,90) bond length is 0.93 Å. In the fourth C site, C(49,137) is bonded in a trigonal planar geometry to one C(46,134); one C(50,138); and one C(54,142) atom. The C(49,137)-C(50,138) bond length is 1.39 Å. The C(49,137)-C(54,142) bond length is 1.42 Å. In the fifth C site, C(50,138) is bonded in a distorted single-bond geometry to one C(49,137); one C(51,139); and one H(32,92) atom. The C(50,138)-C(51,139) bond length is 1.43 Å. The C(50,138)-H(32,92) bond length is 0.93 Å. In the sixth C site, C(51,139) is bonded in a trigonal planar geometry to one C(50,138); one C(52,140); and one C(56,144) atom. The C(51,139)-C(52,140) bond length is 1.43 Å. The C(51,139)-C(56,144) bond length is 1.44 Å. In the seventh C site, C(52,140) is bonded in a distorted single-bond geometry to one C(51,139); one C(53,141); and one O(21,45) atom. The C(52,140)-C(53,141) bond length is 1.40 Å. The C(52,140)-O(21,45) bond length is 1.37 Å. In the eighth C site, C(53,141) is bonded in a trigonal planar geometry to one C(52,140); one C(54,142); and one C(64,152) atom. The C(53,141)-C(54,142) bond length is 1.32 Å. The C(53,141)-C(64,152) bond length is 1.56 Å. In the ninth C site, C(54,142) is bonded in a distorted single-bond geometry to one C(49,137); one C(53,141); and one O(22,46) atom. The C(54,142)-O(22,46) bond length is 1.42 Å. In the tenth C site, C(55,143) is bonded in a tetrahedral geometry to three equivalent H(33,34,35,93,94,95) and one O(22,46) atom. All C(55,143)-H(33,34,35,93,94,95) bond lengths are 0.96 Å. The C(55,143)-O(22,46) bond length is 1.47 Å. In the eleventh C site, C(56,144) is bonded in a trigonal planar geometry to one C(51,139); one C(57,145); and one C(61,149) atom. The C(56,144)-C(57,145) bond length is 1.42 Å. The C(56,144)-C(61,149) bond length is 1.42 Å. In the twelfth C site, C(57,145) is bonded in a single-bond geometry to one C(56,144) and one H(36,39,96,99) atom. The C(57,145)-H(36,39,96,99) bond length is 0.93 Å. In the thirteenth C site, C(61,149) is bonded in a distorted single-bond geometry to one C(56,144) and one H(36,39,96,99) atom. The C(61,149)-H(36,39,96,99) bond length is 0.93 Å. In the fourteenth C site, C(63,151) is bonded in a tetrahedral geometry to one H(44,104); two equivalent H(43,45,103,105); and one O(20,44) atom. The C(63,151)-H(44,104) bond length is 0.96 Å. Both C(63,151)-H(43,45,103,105) bond lengths are 0.96 Å. The C(63,151)-O(20,44) bond length is 1.40 Å. In the fifteenth C site, C(62,150) is bonded in a tetrahedral geometry to three equivalent H(40,41,42,100,101,102) and one O(19,43) atom. All C(62,150)-H(40,41,42,100,101,102) bond lengths are 0.96 Å. The C(62,150)-O(19,43) bond length is 1.44 Å. In the sixteenth C site, C(64,152) is bonded in a trigonal planar geometry to one C(53,141); one C(65,153); and one C(69,157) atom. The C(64,152)-C(65,153) bond length is 1.37 Å. The C(64,152)-C(69,157) bond length is 1.33 Å. In the seventeenth C site, C(65,153) is bonded in a single-bond geometry to one C(64,152); one C(66,154); and one O(19,43) atom. The C(65,153)-C(66,154) bond length is 1.39 Å. The C(65,153)-O(19,43) bond length is 1.43 Å. In the eighteenth C site, C(66,154) is bonded in a trigonal planar geometry to one C(65,153); one C(67,155); and one C(77,165) atom. The C(66,154)-C(67,155) bond length is 1.41 Å. The C(66,154)-C(77,165) bond length is 1.49 Å. In the nineteenth C site, C(69,157) is bonded in a distorted single-bond geometry to one C(64,152); one C(68,156); and one O(20,44) atom. The C(69,157)-C(68,156) bond length is 1.43 Å. The C(69,157)-O(20,44) bond length is 1.37 Å. In the twentieth C site, C(68,156) is bonded in a trigonal planar geometry to one C(67,155); one C(69,157); and one C(70,158) atom. The C(68,156)-C(67,155) bond length is 1.39 Å. The C(68,156)-C(70,158) bond length is 1.50 Å. In the twenty-first C site, C(70,158) is bonded in a trigonal planar geometry to one C(68,156); one C(71,159); and one C(75,163) atom. The C(70,158)-C(71,159) bond length is 1.39 Å. The C(70,158)-C(75,163) bond length is 1.34 Å. In the twenty-second C site, C(67,155) is bonded in a distorted single-bond geometry to one C(66,154); one C(68,156); and one H(46,106) atom. The C(67,155)-H(46,106) bond length is 0.93 Å. In the twenty-third C site, C(71,159) is bonded in a distorted single-bond geometry to one C(70,158) and one H(47,107) atom. The C(71,159)-H(47,107) bond length is 0.93 Å. In the twenty-fourth C site, C(77,165) is bonded in a trigonal planar geometry to one C(66,154); one C(78,166); and one C(82,170) atom. The C(77,165)-C(78,166) bond length is 1.37 Å. The C(77,165)-C(82,170) bond length is 1.44 Å. In the twenty-fifth C site, C(75,163) is bonded in a distorted single-bond geometry to one C(70,158) and one H(50,110) atom. The C(75,163)-H(50,110) bond length is 0.93 Å. In the twenty-sixth C site, C(78,166) is bonded in a distorted single-bond geometry to one C(77,165) and one H(51,111) atom. The C(78,166)-H(51,111) bond length is 0.93 Å. In the twenty-seventh C site, C(82,170) is bonded in a distorted single-bond geometry to one C(77,165) and one H(54,114) atom. The C(82,170)-H(54,114) bond length is 0.93 Å. In the twenty-eighth C site, C(86,174) is bonded in a tetrahedral geometry to one H(56,116); two equivalent H(55,57,115,117); and one O(21,45) atom. The C(86,174)-H(56,116) bond length is 0.96 Å. Both C(86,174)-H(55,57,115,117) bond lengths are 0.96 Å. The C(86,174)-O(21,45) bond length is 1.44 Å. There are fifteen inequivalent H sites. In the first H site, H(29,89) is bonded in a single-bond geometry to one C(45,133) atom. In the second H site, H(30,90) is bonded in a single-bond geometry to one C(47,135) atom. In the third H site, H(32,92) is bonded in a single-bond geometry to one C(50,138) atom. In the fourth H site, H(33,34,35,93,94,95) is bonded in a single-bond geometry to one C(55,143) atom. In the fifth H site, H(36,39,96,99) is bonded in a single-bond geometry to one C(57,145) atom. In the sixth H site, H(40,41,42,100,101,102) is bonded in a single-bond geometry to one C(62,150) atom. In the seventh H site, H(47,107) is bonded in a single-bond geometry to one C(71,159) atom. In the eighth H site, H(50,110) is bonded in a single-bond geometry to one C(75,163) atom. In the ninth H site, H(51,111) is bonded in a single-bond geometry to one C(78,166) atom. In the tenth H site, H(54,114) is bonded in a single-bond geometry to one C(82,170) atom. In the eleventh H site, H(55,57,115,117) is bonded in a single-bond geometry to one C(86,174) atom. In the twelfth H site, H(56,116) is bonded in a single-bond geometry to one C(86,174) atom. In the thirteenth H site, H(43,45,103,105) is bonded in a single-bond geometry to one C(63,151) atom. In the fourteenth H site, H(44,104) is bonded in a single-bond geometry to one C(63,151) atom. In the fifteenth H site, H(46,106) is bonded in a single-bond geometry to one C(67,155) atom. There are four inequivalent O sites. In the first O site, O(19,43) is bonded in a bent 120 degrees geometry to one C(62,150) and one C(65,153) atom. In the second O site, O(20,44) is bonded in a bent 120 degrees geometry to one C(63,151) and one C(69,157) atom. In the third O site, O(21,45) is bonded in a bent 120 degrees geometry to one C(52,140) and one C(86,174) atom. In the fourth O site, O(22,46) is bonded in a bent 120 degrees geometry to one C(54,142) and one C(55,143) atom. In the PrCd4H76(C3O)40 cluster, Pr(1) is bonded in a distorted pentagonal pyramidal geometry to one O(14), one O(28), one O(29), one O(33), one O(48), and one O(7) atom. The Pr(1)-O(14) bond length is 2.45 Å. The Pr(1)-O(28) bond length is 2.46 Å. The Pr(1)-O(29) bond length is 2.44 Å. The Pr(1)-O(33) bond length is 2.44 Å. The Pr(1)-O(48) bond length is 2.35 Å. The Pr(1)-O(7) bond length is 2.41 Å. There are four inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 6-coordinate geometry to one O(10), one O(11), one O(12), one O(32), one O(5), and one O(6) atom. The Cd(1)-O(10) bond length is 2.17 Å. The Cd(1)-O(11) bond length is 2.24 Å. The Cd(1)-O(12) bond length is 2.37 Å. The Cd(1)-O(32) bond length is 2.21 Å. The Cd(1)-O(5) bond length is 2.35 Å. The Cd(1)-O(6) bond length is 2.36 Å. In the second Cd site, Cd(2) is bonded in a 6-coordinate geometry to one O(1), one O(2), one O(23), one O(3), one O(37), and one O(4) atom. The Cd(2)-O(1) bond length is 2.24 Å. The Cd(2)-O(2) bond length is 2.46 Å. The Cd(2)-O(23) bond length is 2.23 Å. The Cd(2)-O(3) bond length is 2.44 Å. The Cd(2)-O(37) bond length is 2.20 Å. The Cd(2)-O(4) bond length is 2.35 Å. In the third Cd site, Cd(3) is bonded in a 6-coordinate geometry to one O(29), one O(30), one O(34), one O(35), one O(36), and one O(8) atom. The Cd(3)-O(29) bond length is 2.35 Å. The Cd(3)-O(30) bond length is 2.36 Å. The Cd(3)-O(34) bond length is 2.17 Å. The Cd(3)-O(35) bond length is 2.24 Å. The Cd(3)-O(36) bond length is 2.37 Å. The Cd(3)-O(8) bond length is 2.21 Å. In the fourth Cd site, Cd(4) is bonded in a 6-coordinate geometry to one O(13), one O(25), one O(26), one O(27), one O(28), and one O(47) atom. The Cd(4)-O(13) bond length is 2.20 Å. The Cd(4)-O(25) bond length is 2.24 Å. The Cd(4)-O(26) bond length is 2.46 Å. The Cd(4)-O(27) bond length is 2.44 Å. The Cd(4)-O(28) bond length is 2.35 Å. The Cd(4)-O(47) bond length is 2.23 Å. There are seventy-seven inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(85) atom. The C(1)-C(2) bond length is 1.38 Å. The C(1)-C(6) bond length is 1.38 Å. The C(1)-C(85) bond length is 1.48 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1); one C(3,91); and one H(1,61) atom. The C(2)-C(3,91) bond length is 1.40 Å. The C(2)-H(1,61) bond length is 0.93 Å. In the third C site, C(3,91) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(2) atom. The C(3,91)-C(4) bond length is 1.38 Å. The C(3,91)-H(2) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3,91); one C(5,93); and one C(7,95) atom. The C(4)-C(5,93) bond length is 1.37 Å. The C(4)-C(7,95) bond length is 1.49 Å. In the fifth C site, C(5,93) is bonded in a distorted single-bond geometry to one C(4) and one H(3,63) atom. The C(5,93)-H(3,63) bond length is 0.93 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4,64) atom. The C(6)-H(4,64) bond length is 0.93 Å. In the seventh C site, C(7,95) is bonded in a trigonal planar geometry to one C(12,100); one C(4); and one C(8,96) atom. The C(7,95)-C(12,100) bond length is 1.42 Å. The C(7,95)-C(8,96) bond length is 1.38 Å. In the eighth C site, C(8,96) is bonded in a distorted single-bond geometry to one C(7,95); one C(9,97); and one H(5,65) atom. The C(8,96)-C(9,97) bond length is 1.35 Å. The C(8,96)-H(5,65) bond length is 0.93 Å. In the ninth C site, C(9,97) is bonded in a trigonal planar geometry to one C(10,98); one C(13,101); and one C(8,96) atom. The C(9,97)-C(10,98) bond length is 1.44 Å. The C(9,97)-C(13,101) bond length is 1.51 Å. In the tenth C site, C(10,98) is bonded in a distorted single-bond geometry to one C(11,99); one C(9,97); and one O(17,41) atom. The C(10,98)-C(11,99) bond length is 1.40 Å. The C(10,98)-O(17,41) bond length is 1.36 Å. In the eleventh C site, C(11,99) is bonded in a trigonal planar geometry to one C(10,98); one C(12,100); and one C(23,111) atom. The C(11,99)-C(12,100) bond length is 1.39 Å. The C(11,99)-C(23,111) bond length is 1.51 Å. In the twelfth C site, C(12,100) is bonded in a single-bond geometry to one C(11,99); one C(7,95); and one O(18,42) atom. The C(12,100)-O(18,42) bond length is 1.39 Å. In the thirteenth C site, C(13,101) is bonded in a trigonal planar geometry to one C(14,102); one C(18,106); and one C(9,97) atom. The C(13,101)-C(14,102) bond length is 1.37 Å. The C(13,101)-C(18,106) bond length is 1.39 Å. In the fourteenth C site, C(14,102) is bonded in a distorted single-bond geometry to one C(13,101); one C(15,103); and one H(6,66) atom. The C(14,102)-C(15,103) bond length is 1.39 Å. The C(14,102)-H(6,66) bond length is 0.93 Å. In the fifteenth C site, C(15,103) is bonded in a distorted trigonal planar geometry to one C(14,102); one C(16); and one H(7,67) atom. The C(15,103)-C(16) bond length is 1.34 Å. The C(15,103)-H(7,67) bond length is 0.93 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15,103); one C(17,105); and one C(19) atom. The C(16)-C(17,105) bond length is 1.37 Å. The C(16)-C(19) bond length is 1.50 Å. In the seventeenth C site, C(17,105) is bonded in a distorted trigonal planar geometry to one C(16); one C(18,106); and one H(8,68) atom. The C(17,105)-C(18,106) bond length is 1.44 Å. The C(17,105)-H(8,68) bond length is 0.93 Å. In the eighteenth C site, C(18,106) is bonded in a distorted single-bond geometry to one C(13,101); one C(17,105); and one H(9,69) atom. The C(18,106)-H(9,69) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(7), and one O(8) atom. The C(19)-O(7) bond length is 1.19 Å. The C(19)-O(8) bond length is 1.40 Å. In the twentieth C site, C(20,108) is bonded in a tetrahedral geometry to one H(10,70); two equivalent H(11,12,71,72); and one O(17,41) atom. The C(20,108)-H(10,70) bond length is 0.96 Å. Both C(20,108)-H(11,12,71,72) bond lengths are 0.96 Å. The C(20,108)-O(17,41) bond length is 1.46 Å. In the twenty-first C site, C(21,109) is bonded in a tetrahedral geometry to one H(13,73); one H(14,74); one H(15,75); and one O(18,42) atom. The C(21,109)-H(13,73) bond length is 0.96 Å. The C(21,109)-H(14,74) bond length is 0.96 Å. The C(21,109)-H(15,75) bond length is 0.96 Å. The C(21,109)-O(18,42) bond length is 1.45 Å. In the twenty-second C site, C(22,110) is bonded in a tetrahedral geometry to one H(18,78); two equivalent H(16,17,76,77); and one O(15,39) atom. The C(22,110)-H(18,78) bond length is 0.96 Å. Both C(22,110)-H(16,17,76,77) bond lengths are 0.96 Å. The C(22,110)-O(15,39) bond length is 1.42 Å. In the twenty-third C site, C(23,111) is bonded in a trigonal planar geometry to one C(11,99); one C(24,112); and one C(28,116) atom. The C(23,111)-C(24,112) bond length is 1.38 Å. The C(23,111)-C(28,116) bond length is 1.41 Å. In the twenty-fourth C site, C(24,112) is bonded in a distorted single-bond geometry to one C(23,111); one C(25,113); and one O(15,39) atom. The C(24,112)-C(25,113) bond length is 1.39 Å. The C(24,112)-O(15,39) bond length is 1.42 Å. In the twenty-fifth C site, C(25,113) is bonded in a trigonal planar geometry to one C(24,112); one C(26,114); and one C(29,117) atom. The C(25,113)-C(26,114) bond length is 1.45 Å. The C(25,113)-C(29,117) bond length is 1.50 Å. In the twenty-sixth C site, C(26,114) is bonded in a distorted single-bond geometry to one C(25,113); one C(27,115); and one H(19,79) atom. The C(26,114)-C(27,115) bond length is 1.38 Å. The C(26,114)-H(19,79) bond length is 0.93 Å. In the twenty-seventh C site, C(27,115) is bonded in a trigonal planar geometry to one C(26,114); one C(28,116); and one C(36,124) atom. The C(27,115)-C(28,116) bond length is 1.38 Å. The C(27,115)-C(36,124) bond length is 1.51 Å. In the twenty-eighth C site, C(28,116) is bonded in a distorted single-bond geometry to one C(23,111); one C(27,115); and one O(16,40) atom. The C(28,116)-O(16,40) bond length is 1.38 Å. In the twenty-ninth C site, C(29,117) is bonded in a trigonal planar geometry to one C(25,113); one C(30,118); and one C(32,120) atom. The C(29,117)-C(30,118) bond length is 1.39 Å. The C(29,117)-C(32,120) bond length is 1.38 Å. In the thirtieth C site, C(30,118) is bonded in a distorted single-bond geometry to one C(29,117) and one H(20,80) atom. The C(30,118)-H(20,80) bond length is 0.93 Å. In the thirty-first C site, C(31,119) is bonded in a distorted single-bond geometry to one C(34) and one H(21) atom. The C(31,119)-C(34) bond length is 1.38 Å. The C(31,119)-H(21) bond length is 0.93 Å. In the thirty-second C site, C(32,120) is bonded in a distorted single-bond geometry to one C(29,117) and one H(22,82) atom. The C(32,120)-H(22,82) bond length is 0.93 Å. In the thirty-third C site, C(33,121) is bonded in a distorted single-bond geometry to one C(34) and one H(23,83) atom. The C(33,121)-C(34) bond length is 1.47 Å. The C(33,121)-H(23,83) bond length is 0.93 Å. In the thirty-fourth C site, C(34) is bonded in a trigonal planar geometry to one C(31,119); one C(33,121); and one C(35) atom. The C(34)-C(35) bond length is 1.43 Å. In the thirty-fifth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(34), one O(3), and one O(4) atom. The C(35)-O(3) bond length is 1.25 Å. The C(35)-O(4) bond length is 1.36 Å. In the thirty-sixth C site, C(36,124) is bonded in a trigonal planar geometry to one C(27,115); one C(37,125); and one C(41,129) atom. The C(36,124)-C(37,125) bond length is 1.34 Å. The C(36,124)-C(41,129) bond length is 1.40 Å. In the thirty-seventh C site, C(37,125) is bonded in a distorted single-bond geometry to one C(36,124) and one H(24,84) atom. The C(37,125)-H(24,84) bond length is 0.93 Å. In the thirty-eighth C site, C(38,126) is bonded in a distorted single-bond geometry to one C(39,127) and one H(25,85) atom. The C(38,126)-C(39,127) bond length is 1.42 Å. The C(38,126)-H(25,85) bond length is 0.93 Å. In the thirty-ninth C site, C(39,127) is bonded in a trigonal planar geometry to one C(38,126); one C(40,128); and one C(42,130) atom. The C(39,127)-C(40,128) bond length is 1.37 Å. The C(39,127)-C(42,130) bond length is 1.56 Å. In the fortieth C site, C(40,128) is bonded in a distorted single-bond geometry to one C(39,127) and one H(26,86) atom. The C(40,128)-H(26,86) bond length is 0.93 Å. In the forty-first C site, C(41,129) is bonded in a distorted single-bond geometry to one C(36,124) and one H(27,87) atom. The C(41,129)-H(27,87) bond length is 0.93 Å. In the forty-second C site, C(42,130) is bonded in a distorted bent 120 degrees geometry to one C(39,127); one O(1); and one O(2) atom. The C(42,130)-O(1) bond length is 1.29 Å. The C(42,130)-O(2) bond length is 1.19 Å. In the forty-third C site, C(43) is bonded in a distorted bent 120 degrees geometry to one C(88), one O(5), and one O(6) atom. The C(43)-C(88) bond length is 1.44 Å. The C(43)-O(5) bond length is 1.43 Å. The C(43)-O(6) bond length is 1.20 Å. In the forty-fourth C site, C(44) is bonded in a distorted single-bond geometry to one C(88) and one H(28,88) atom. The C(44)-C(88) bond length is 1.38 Å. The C(44)-H(28,88) bond length is 0.93 Å. In the forty-fifth C site, C(48) is bonded in a distorted single-bond geometry to one C(88) and one H(31,91) atom. The C(48)-C(88) bond length is 1.45 Å. The C(48)-H(31,91) bond length is 0.93 Å. In the forty-sixth C site, C(58,146) is bonded in a distorted single-bond geometry to one C(59,147) and one H(37,97) atom. The C(58,146)-C(59,147) bond length is 1.41 Å. The C(58,146)-H(37,97) bond length is 0.93 Å. In the forty-seventh C site, C(59,147) is bonded in a trigonal planar geometry to one C(58,146); one C(60,148); and one C(84,172) atom. The C(59,147)-C(60,148) bond length is 1.49 Å. The C(59,147)-C(84,172) bond length is 1.42 Å. In the forty-eighth C site, C(60,148) is bonded in a distorted single-bond geometry to one C(59,147) and one H(38,98) atom. The C(60,148)-H(38,98) bond length is 0.93 Å. In the forty-ninth C site, C(72,160) is bonded in a distorted single-bond geometry to one C(73) and one H(48,108) atom. The C(72,160)-C(73) bond length is 1.31 Å. The C(72,160)-H(48,108) bond length is 0.93 Å. In the fiftieth C site, C(73) is bonded in a trigonal planar geometry to one C(72,160); one C(74,162); and one C(76) atom. The C(73)-C(74,162) bond length is 1.31 Å. The C(73)-C(76) bond length is 1.57 Å. In the fifty-first C site, C(74,162) is bonded in a distorted single-bond geometry to one C(73) and one H(49,109) atom. The C(74,162)-H(49,109) bond length is 0.93 Å. In the fifty-second C site, C(76) is bonded in a distorted bent 120 degrees geometry to one C(73), one O(13), and one O(14) atom. The C(76)-O(13) bond length is 1.25 Å. The C(76)-O(14) bond length is 1.20 Å. In the fifty-third C site, C(79,167) is bonded in a distorted single-bond geometry to one C(80) and one H(52,112) atom. The C(79,167)-C(80) bond length is 1.38 Å. The C(79,167)-H(52,112) bond length is 0.93 Å. In the fifty-fourth C site, C(80) is bonded in a trigonal planar geometry to one C(79,167); one C(81,169); and one C(83) atom. The C(80)-C(81,169) bond length is 1.42 Å. The C(80)-C(83) bond length is 1.58 Å. In the fifty-fifth C site, C(81,169) is bonded in a distorted single-bond geometry to one C(80) and one H(53,113) atom. The C(81,169)-H(53,113) bond length is 0.93 Å. In the fifty-sixth C site, C(83) is bonded in a distorted bent 120 degrees geometry to one C(80), one O(10), and one O(9) atom. The C(83)-O(10) bond length is 1.14 Å. The C(83)-O(9) bond length is 1.27 Å. In the fifty-seventh C site, C(84,172) is bonded in a bent 120 degrees geometry to one C(59,147); one O(11); and one O(12) atom. The C(84,172)-O(11) bond length is 1.23 Å. The C(84,172)-O(12) bond length is 1.29 Å. In the fifty-eighth C site, C(85) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(23), and one O(24) atom. The C(85)-O(23) bond length is 1.26 Å. The C(85)-O(24) bond length is 1.34 Å. In the fifty-ninth C site, C(87,175) is bonded in a tetrahedral geometry to three equivalent H(58,59,60,118,119,120) and one O(16,40) atom. All C(87,175)-H(58,59,60,118,119,120) bond lengths are 0.96 Å. The C(87,175)-O(16,40) bond length is 1.47 Å. In the sixtieth C site, C(88) is bonded in a trigonal planar geometry to one C(43), one C(44), and one C(48) atom. In the sixty-first C site, C(89) is bonded in a trigonal planar geometry to one C(173), one C(90), and one C(94) atom. The C(89)-C(173) bond length is 1.48 Å. The C(89)-C(90) bond length is 1.38 Å. The C(89)-C(94) bond length is 1.38 Å. In the sixty-second C site, C(90) is bonded in a distorted trigonal planar geometry to one C(3,91); one C(89); and one H(1,61) atom. The C(90)-C(3,91) bond length is 1.40 Å. The C(90)-H(1,61) bond length is 0.93 Å. In the sixty-third C site, C(92) is bonded in a trigonal planar geometry to one C(3,91); one C(5,93); and one C(7,95) atom. The C(92)-C(3,91) bond length is 1.38 Å. The C(92)-C(5,93) bond length is 1.37 Å. The C(92)-C(7,95) bond length is 1.49 Å. In the sixty-fourth C site, C(94) is bonded in a distorted single-bond geometry to one C(89) and one H(4,64) atom. The C(94)-H(4,64) bond length is 0.93 Å. In the sixty-fifth C site, C(104) is bonded in a trigonal planar geometry to one C(107); one C(15,103); and one C(17,105) atom. The C(104)-C(107) bond length is 1.50 Å. The C(104)-C(15,103) bond length is 1.34 Å. The C(104)-C(17,105) bond length is 1.37 Å. In the sixty-sixth C site, C(107) is bonded in a distorted bent 120 degrees geometry to one C(104), one O(31), and one O(32) atom. The C(107)-O(31) bond length is 1.19 Å. The C(107)-O(32) bond length is 1.40 Å. In the sixty-seventh C site, C(122) is bonded in a trigonal planar geometry to one C(123); one C(31,119); and one C(33,121) atom. The C(122)-C(123) bond length is 1.43 Å. The C(122)-C(31,119) bond length is 1.38 Å. The C(122)-C(33,121) bond length is 1.47 Å. In the sixty-eighth C site, C(123) is bonded in a distorted bent 120 degrees geometry to one C(122), one O(27), and one O(28) atom. The C(123)-O(27) bond length is 1.25 Å. The C(123)-O(28) bond length is 1.36 Å. In the sixty-ninth C site, C(131) is bonded in a distorted bent 120 degrees geometry to one C(176), one O(29), and one O(30) atom. The C(131)-C(176) bond length is 1.44 Å. The C(131)-O(29) bond length is 1.43 Å. The C(131)-O(30) bond length is 1.20 Å. In the seventieth C site, C(132) is bonded in a distorted single-bond geometry to one C(176) and one H(28,88) atom. The C(132)-C(176) bond length is 1.38 Å. The C(132)-H(28,88) bond length is 0.93 Å. In the seventy-first C site, C(136) is bonded in a distorted single-bond geometry to one C(176) and one H(31,91) atom. The C(136)-C(176) bond length is 1.45 Å. The C(136)-H(31,91) bond length is 0.93 Å. In the seventy-second C site, C(161) is bonded in a trigonal planar geometry to one C(164); one C(72,160); and one C(74,162) atom. The C(161)-C(164) bond length is 1.57 Å. The C(161)-C(72,160) bond length is 1.31 Å. The C(161)-C(74,162) bond length is 1.31 Å. In the seventy-third C site, C(164) is bonded in a distorted bent 120 degrees geometry to one C(161), one O(37), and one O(38) atom. The C(164)-O(37) bond length is 1.25 Å. The C(164)-O(38) bond length is 1.20 Å. In the seventy-fourth C site, C(168) is bonded in a trigonal planar geometry to one C(171); one C(79,167); and one C(81,169) atom. The C(168)-C(171) bond length is 1.58 Å. The C(168)-C(79,167) bond length is 1.38 Å. The C(168)-C(81,169) bond length is 1.42 Å. In the seventy-fifth C site, C(171) is bonded in a distorted bent 120 degrees geometry to one C(168), one O(33), and one O(34) atom. The C(171)-O(33) bond length is 1.27 Å. The C(171)-O(34) bond length is 1.14 Å. In the seventy-sixth C site, C(173) is bonded in a distorted bent 120 degrees geometry to one C(89), one O(47), and one O(48) atom. The C(173)-O(47) bond length is 1.26 Å. The C(173)-O(48) bond length is 1.34 Å. In the seventy-seventh C site, C(176) is bonded in a trigonal planar geometry to one C(131), one C(132), and one C(136) atom. There are thirty-six inequivalent H sites. In the first H site, H(1,61) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3,91) atom. In the third H site, H(3,63) is bonded in a single-bond geometry to one C(5,93) atom. In the fourth H site, H(4,64) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5,65) is bonded in a single-bond geometry to one C(8,96) atom. In the sixth H site, H(6,66) is bonded in a single-bond geometry to one C(14,102) atom. In the seventh H site, H(7,67) is bonded in a single-bond geometry to one C(15,103) atom. In the eighth H site, H(8,68) is bonded in a single-bond geometry to one C(17,105) atom. In the ninth H site, H(9,69) is bonded in a single-bond geometry to one C(18,106) atom. In the tenth H site, H(10,70) is bonded in a single-bond geometry to one C(20,108) atom. In the eleventh H site, H(11,12,71,72) is bonded in a single-bond geometry to one C(20,108) atom. In the twelfth H site, H(13,73) is bonded in a single-bond geometry to one C(21,109) atom. In the thirteenth H site, H(14,74) is bonded in a single-bond geometry to one C(21,109) atom. In the fourteenth H site, H(15,75) is bonded in a single-bond geometry to one C(21,109) atom. In the fifteenth H site, H(16,17,76,77) is bonded in a single-bond geometry to one C(22,110) atom. In the sixteenth H site, H(18,78) is bonded in a single-bond geometry to one C(22,110) atom. In the seventeenth H site, H(19,79) is bonded in a single-bond geometry to one C(26,114) atom. In the eighteenth H site, H(20,80) is bonded in a single-bond geometry to one C(30,118) atom. In the nineteenth H site, H(21) is bonded in a single-bond geometry to one C(31,119) atom. In the twentieth H site, H(22,82) is bonded in a single-bond geometry to one C(32,120) atom. In the twenty-first H site, H(23,83) is bonded in a single-bond geometry to one C(33,121) atom. In the twenty-second H site, H(24,84) is bonded in a single-bond geometry to one C(37,125) atom. In the twenty-third H site, H(25,85) is bonded in a single-bond geometry to one C(38,126) atom. In the twenty-fourth H site, H(26,86) is bonded in a single-bond geometry to one C(40,128) atom. In the twenty-fifth H site, H(27,87) is bonded in a single-bond geometry to one C(41,129) atom. In the twenty-sixth H site, H(28,88) is bonded in a single-bond geometry to one C(44) atom. In the twenty-seventh H site, H(31,91) is bonded in a single-bond geometry to one C(48) atom. In the twenty-eighth H site, H(37,97) is bonded in a single-bond geometry to one C(58,146) atom. In the twenty-ninth H site, H(38,98) is bonded in a single-bond geometry to one C(60,148) atom. In the thirtieth H site, H(48,108) is bonded in a single-bond geometry to one C(72,160) atom. In the thirty-first H site, H(49,109) is bonded in a single-bond geometry to one C(74,162) atom. In the thirty-second H site, H(52,112) is bonded in a single-bond geometry to one C(79,167) atom. In the thirty-third H site, H(53,113) is bonded in a single-bond geometry to one C(81,169) atom. In the thirty-fourth H site, H(58,59,60,118,119,120) is bonded in a single-bond geometry to one C(87,175) atom. In the thirty-fifth H site, H(62) is bonded in a single-bond geometry to one C(3,91) atom. The H(62)-C(3,91) bond length is 0.93 Å. In the thirty-sixth H site, H(81) is bonded in a single-bond geometry to one C(31,119) atom. The H(81)-C(31,119) bond length is 0.93 Å. There are thirty-six inequivalent O sites. In the first O site, O(1) is bonded in an L-shaped geometry to one Cd(2) and one C(42,130) atom. In the second O site, O(2) is bonded in a distorted single-bond geometry to one Cd(2) and one C(42,130) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(35) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Cd(2) and one C(35) atom. In the fifth O site, O(5) is bonded in an L-shaped geometry to one Cd(1) and one C(43) atom. In the sixth O site, O(6) is bonded in an L-shaped geometry to one Cd(1) and one C(43) atom. In the seventh O site, O(7) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one C(19) atom. In the eighth O site, O(8) is bonded in a water-like geometry to one Cd(3) and one C(19) atom. In the ninth O site, O(9) is bonded in a single-bond geometry to one C(83) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(83) atom. In the eleventh O site, O(11) is bonded in a water-like geometry to one Cd(1) and one C(84,172) atom. In the twelfth O site, O(12) is bonded in an L-shaped geometry to one Cd(1) and one C(84,172) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Cd(4) and one C(76) atom. In the fourteenth O site, O(14) is bonded in a bent 150 degrees geometry to one Pr(1) and one C(76) atom. In the fifteenth O site, O(15,39) is bonded in a bent 120 degrees geometry to one C(22,110) and one C(24,112) atom. In the sixteenth O site, O(16,40) is bonded in a bent 120 degrees geometry to one C(28,116) and one C(87,175) atom. In the seventeenth O site, O(17,41) is bonded in a bent 120 degrees geometry to one C(10,98) and one C(20,108) atom. In the eighteenth O site, O(18,42) is bonded in a water-like geometry to one C(12,100) and one C(21,109) atom. In the nineteenth O site, O(23) is bonded in a bent 120 degrees geometry to one Cd(2) and one C(85) atom. In the twentieth O site, O(24) is bonded in a single-bond geometry to one C(85) atom. In the twenty-first O site, O(25) is bonded in an L-shaped geometry to one Cd(4) and one C(42,130) atom. The O(25)-C(42,130) bond length is 1.29 Å. In the twenty-second O site, O(26) is bonded in a distorted single-bond geometry to one Cd(4) and one C(42,130) atom. The O(26)-C(42,130) bond length is 1.19 Å. In the twenty-third O site, O(27) is bonded in a distorted L-shaped geometry to one Cd(4) and one C(123) atom. In the twenty-fourth O site, O(28) is bonded in a 3-coordinate geometry to one Pr(1), one Cd(4), and one C(123) atom. In the twenty-fifth O site, O(29) is bonded in a distorted T-shaped geometry to one Pr(1), one Cd(3), and one C(131) atom. In the twenty-sixth O site, O(30) is bonded in an L-shaped geometry to one Cd(3) and one C(131) atom. In the twenty-seventh O site, O(31) is bonded in a single-bond geometry to one C(107) atom. In the twenty-eighth O site, O(32) is bonded in a water-like geometry to one Cd(1) and one C(107) atom. In the twenty-ninth O site, O(33) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one C(171) atom. In the thirtieth O site, O(34) is bonded in a distorted bent 150 degrees geometry to one Cd(3) and one C(171) atom. In the thirty-first O site, O(35) is bonded in a water-like geometry to one Cd(3) and one C(84,172) atom. The O(35)-C(84,172) bond length is 1.23 Å. In the thirty-second O site, O(36) is bonded in an L-shaped geometry to one Cd(3) and one C(84,172) atom. The O(36)-C(84,172) bond length is 1.29 Å. In the thirty-third O site, O(37) is bonded in a bent 120 degrees geometry to one Cd(2) and one C(164) atom. In the thirty-fourth O site, O(38) is bonded in a single-bond geometry to one C(164) atom. In the thirty-fifth O site, O(47) is bonded in a bent 120 degrees geometry to one Cd(4) and one C(173) atom. In the thirty-sixth O site, O(48) is bonded in a distorted bent 150 degrees geometry to one Pr(1) and one C(173) atom. Linkers: 4 COc1c(-c2ccc(C([O])=O)cc2)cc(-c2ccc(C([O])=O)cc2)c(OC)c1-c1c(OC)c(-c2ccc(C([O])=O)cc2)cc(-c2ccc(C([O])=O)cc2)c1OC. Metal clusters: 1 [C]1O[Pr]2(O[C]O[Cd]34(O1)(O[C]O3)O[C]O4)O[C]O[Cd]13(O[C]O2)(O[C]O1)O[C]O3 ,1 O=[C]O[Cd]12(O[C]=O)(O[C]O1)O[C]O2 ,1 [O][C]O[Cd]12(O[C]=O)(O[C]O1)O[C]O2. The MOF has largest included sphere 9.34 A, density 0.78 g/cm3, surface area 4500.97 m2/g, accessible volume 0.79 cm3/g