ZnC14N5H8O4CH crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a ZnC14N5H8O4 framework. In the ZnC14N5H8O4 framework, Zn(1) is bonded in a distorted trigonal bipyramidal geometry to one N(2), one N(3), one N(4), one O(2), and one O(3) atom. The Zn(1)-N(2) bond length is 2.11 Å. The Zn(1)-N(3) bond length is 2.13 Å. The Zn(1)-N(4) bond length is 2.23 Å. The Zn(1)-O(2) bond length is 1.98 Å. The Zn(1)-O(3) bond length is 2.03 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(1)-C(4) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a bent 120 degrees geometry to one C(5), one O(3), and one O(4) atom. The C(2)-C(5) bond length is 1.50 Å. The C(2)-O(3) bond length is 1.26 Å. The C(2)-O(4) bond length is 1.23 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4), one C(5), and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(5) bond length is 1.39 Å. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(7) atom. The C(5)-C(7) bond length is 1.40 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one H(2) atom. The C(6)-C(8) bond length is 1.37 Å. The C(6)-H(2) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(5), one C(8), and one H(3) atom. The C(7)-C(8) bond length is 1.38 Å. The C(7)-H(3) bond length is 0.95 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(6), one C(7), and one N(1) atom. The C(8)-N(1) bond length is 1.45 Å. In the ninth C site, C(9) is bonded in a trigonal non-coplanar geometry to one C(10) and three equivalent H(4,5,6) atoms. The C(9)-C(10) bond length is 1.48 Å. All C(9)-H(4,5,6) bond lengths are 0.98 Å. In the tenth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(9), one N(1), and one N(2) atom. The C(10)-N(1) bond length is 1.37 Å. The C(10)-N(2) bond length is 1.31 Å. In the eleventh C site, C(11) is bonded in a distorted water-like geometry to one N(1) and one N(3) atom. The C(11)-N(1) bond length is 1.36 Å. The C(11)-N(3) bond length is 1.31 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(4) and one N(5) atom. The C(12)-N(4) bond length is 1.34 Å. The C(12)-N(5) bond length is 1.32 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(7) atom. The C(13)-N(5) bond length is 1.34 Å. The C(13)-H(7) bond length is 0.95 Å. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(9) atom. The C(15)-N(4) bond length is 1.34 Å. The C(15)-H(9) bond length is 0.95 Å. There are five inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(8) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Zn(1), one C(10), and one N(3) atom. The N(2)-N(3) bond length is 1.38 Å. In the third N site, N(3) is bonded in a 3-coordinate geometry to one Zn(1), one C(11), and one N(2) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(12), and one C(15) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(12) and one C(13) atom. There are six inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4,5,6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(15) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(2) atom. Linkers: 4 Cc1nnc(-c2ncccn2)n1-c1cc(C([O])=O)cc(C([O])=O)c1. Metal clusters: 4 [Zn]. The MOF has largest included sphere 4.53 A, density 1.25 g/cm3, surface area 4129.06 m2/g, accessible volume 0.37 cm3/g