Cd5C48H32(N20O)2 is Indium-like structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of two Cd5C48H32(N20O)2 clusters. There are three inequivalent Cd sites. In the first Cd site, Cd(1) is bonded to one N(19), one N(3), one N(5), one N(7), one N(8), and one O(1) atom to form CdN5O octahedra that share  a cornercorner with one Cd(3)N4O2 octahedra and  a cornercorner with one Cd(2)N5O octahedra. The corner-sharing octahedral tilt angles range from 64-71°. The Cd(1)-N(19) bond length is 2.35 Å. The Cd(1)-N(3) bond length is 2.38 Å. The Cd(1)-N(5) bond length is 2.36 Å. The Cd(1)-N(7) bond length is 2.38 Å. The Cd(1)-N(8) bond length is 2.42 Å. The Cd(1)-O(1) bond length is 2.29 Å. In the second Cd site, Cd(2) is bonded to one N(1), one N(13), one N(14), one N(17), one N(20), and one O(1) atom to form CdN5O octahedra that share  a cornercorner with one Cd(3)N4O2 octahedra and  a cornercorner with one Cd(1)N5O octahedra. The corner-sharing octahedral tilt angles range from 64-71°. The Cd(2)-N(1) bond length is 2.37 Å. The Cd(2)-N(13) bond length is 2.39 Å. The Cd(2)-N(14) bond length is 2.34 Å. The Cd(2)-N(17) bond length is 2.34 Å. The Cd(2)-N(20) bond length is 2.34 Å. The Cd(2)-O(1) bond length is 2.27 Å. In the third Cd site, Cd(3) is bonded to two equivalent N(11), two equivalent N(6), and two equivalent O(1) atoms to form corner-sharing CdN4O2 octahedra. The corner-sharing octahedral tilt angles are 64°. Both Cd(3)-N(11) bond lengths are 2.38 Å. Both Cd(3)-N(6) bond lengths are 2.40 Å. Both Cd(3)-O(1) bond lengths are 2.23 Å. There are twenty-four inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(5), one N(15), and one N(4) atom. The C(1)-C(5) bond length is 1.47 Å. The C(1)-N(15) bond length is 1.34 Å. The C(1)-N(4) bond length is 1.32 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(8), one N(12), and one N(18) atom. The C(2)-C(8) bond length is 1.49 Å. The C(2)-N(12) bond length is 1.36 Å. The C(2)-N(18) bond length is 1.32 Å. In the third C site, C(3) is bonded in a distorted water-like geometry to one C(15), one N(16), and one N(9) atom. The C(3)-C(15) bond length is 1.45 Å. The C(3)-N(16) bond length is 1.34 Å. The C(3)-N(9) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(1) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-H(1) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(6) atom. The C(5)-C(6) bond length is 1.39 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(6)-H(2) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a distorted single-bond geometry to one C(8) and one H(3) atom. The C(7)-C(8) bond length is 1.37 Å. The C(7)-H(3) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(2), one C(24), and one C(7) atom. The C(8)-C(24) bond length is 1.42 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(4) atom. The C(9)-N(7) bond length is 1.33 Å. The C(9)-H(4) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(5) atom. The C(10)-C(11) bond length is 1.41 Å. The C(10)-H(5) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(16) atom. The C(11)-C(14) bond length is 1.40 Å. The C(11)-C(16) bond length is 1.45 Å. In the twelfth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(6) atom. The C(12)-N(5) bond length is 1.37 Å. The C(12)-H(6) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one N(7) and one H(7) atom. The C(13)-N(7) bond length is 1.32 Å. The C(13)-H(7) bond length is 0.93 Å. In the fourteenth C site, C(14) is bonded in a distorted single-bond geometry to one C(11) and one H(8) atom. The C(14)-H(8) bond length is 0.93 Å. In the fifteenth C site, C(15) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(3) atom. The C(15)-C(17) bond length is 1.40 Å. The C(15)-C(19) bond length is 1.40 Å. In the sixteenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(11), one N(10), and one N(2) atom. The C(16)-N(10) bond length is 1.33 Å. The C(16)-N(2) bond length is 1.32 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(15) and one H(9,11) atom. The C(17)-H(9,11) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(20) and one H(10) atom. The C(18)-N(20) bond length is 1.33 Å. The C(18)-H(10) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(15) and one H(9,11) atom. The C(19)-H(9,11) bond length is 0.93 Å. In the twentieth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(12) atom. The C(20)-N(5) bond length is 1.33 Å. The C(20)-H(12) bond length is 0.93 Å. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one N(17) and one H(13) atom. The C(21)-N(17) bond length is 1.36 Å. The C(21)-H(13) bond length is 0.93 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one N(20) and one H(14) atom. The C(22)-N(20) bond length is 1.37 Å. The C(22)-H(14) bond length is 0.93 Å. In the twenty-third C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(17) and one H(15) atom. The C(23)-N(17) bond length is 1.35 Å. The C(23)-H(15) bond length is 0.93 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(8) and one H(16) atom. The C(24)-H(16) bond length is 0.93 Å. There are twenty inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(2), one N(3), and one N(4) atom. The N(1)-N(3) bond length is 1.34 Å. The N(1)-N(4) bond length is 1.35 Å. In the second N site, N(2) is bonded in a distorted water-like geometry to one C(16) and one N(11) atom. The N(2)-N(11) bond length is 1.36 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one N(1), and one N(15) atom. The N(3)-N(15) bond length is 1.31 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one C(1) and one N(1) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Cd(1), one C(12), and one C(20) atom. In the sixth N site, N(6) is bonded in a distorted trigonal planar geometry to one Cd(3), one N(18), and one N(19) atom. The N(6)-N(18) bond length is 1.34 Å. The N(6)-N(19) bond length is 1.30 Å. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Cd(1), one C(13), and one C(9) atom. In the eighth N site, N(8) is bonded in a trigonal planar geometry to one Cd(1), one N(13), and one N(16) atom. The N(8)-N(13) bond length is 1.31 Å. The N(8)-N(16) bond length is 1.31 Å. In the ninth N site, N(9) is bonded in a water-like geometry to one C(3) and one N(13) atom. The N(9)-N(13) bond length is 1.34 Å. In the tenth N site, N(10) is bonded in a distorted water-like geometry to one C(16) and one N(14) atom. The N(10)-N(14) bond length is 1.36 Å. In the eleventh N site, N(11) is bonded in a distorted trigonal planar geometry to one Cd(3), one N(14), and one N(2) atom. The N(11)-N(14) bond length is 1.31 Å. In the twelfth N site, N(12) is bonded in a distorted water-like geometry to one C(2) and one N(19) atom. The N(12)-N(19) bond length is 1.32 Å. In the thirteenth N site, N(13) is bonded in a trigonal planar geometry to one Cd(2), one N(8), and one N(9) atom. In the fourteenth N site, N(14) is bonded in a trigonal planar geometry to one Cd(2), one N(10), and one N(11) atom. In the fifteenth N site, N(15) is bonded in a water-like geometry to one C(1) and one N(3) atom. In the sixteenth N site, N(16) is bonded in a water-like geometry to one C(3) and one N(8) atom. In the seventeenth N site, N(17) is bonded in a trigonal planar geometry to one Cd(2), one C(21), and one C(23) atom. In the eighteenth N site, N(18) is bonded in a distorted water-like geometry to one C(2) and one N(6) atom. In the nineteenth N site, N(19) is bonded in a trigonal planar geometry to one Cd(1), one N(12), and one N(6) atom. In the twentieth N site, N(20) is bonded in a trigonal planar geometry to one Cd(2), one C(18), and one C(22) atom. There are fifteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(9,11) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(23) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(24) atom. O(1) is bonded in a trigonal non-coplanar geometry to one Cd(1), one Cd(2), and one Cd(3) atom. Linkers: 10 c1cc(C2=NN=N[N]2)ccn1 ,6 c1cc(C2=N[N]N=N2)ccn1. Metal clusters: 2 [N]1[N][Cd]234([N][N][Cd]5N=N[Cd@]([N][N]2)(N=N5)O3)[N][N][Cd@]2(N=N[Cd]1N=N2)O4. The MOF has largest included sphere 7.24 A, density 1.30 g/cm3, surface area 3682.32 m2/g, accessible volume 0.35 cm3/g