(NiC32H32(NO)2)3NiC33H33(NO)2(CH)31Cd4C8HO16Cl is Indium-derived structured and crystallizes in the monoclinic P2_1 space group. The structure is zero-dimensional and consists of sixty-two 02329_fluka molecules, two Cd4C8HO16Cl clusters, six NiC32H32(NO)2 clusters, and two NiC33H33(NO)2 clusters. In each Cd4C8HO16Cl cluster, there are four inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted trigonal bipyramidal geometry to one O(11), one O(14), one O(4), one O(6), and one Cl(1) atom. The Cd(1)-O(11) bond length is 2.32 Å. The Cd(1)-O(14) bond length is 2.40 Å. The Cd(1)-O(4) bond length is 2.26 Å. The Cd(1)-O(6) bond length is 2.24 Å. The Cd(1)-Cl(1) bond length is 2.51 Å. In the second Cd site, Cd(2) is bonded in a 5-coordinate geometry to one O(10), one O(15), one O(20), one O(23), and one O(4) atom. The Cd(2)-O(10) bond length is 2.21 Å. The Cd(2)-O(15) bond length is 2.21 Å. The Cd(2)-O(20) bond length is 2.61 Å. The Cd(2)-O(23) bond length is 2.23 Å. The Cd(2)-O(4) bond length is 2.64 Å. In the third Cd site, Cd(3) is bonded in a rectangular see-saw-like geometry to one O(5), one O(7), one O(9), and one Cl(1) atom. The Cd(3)-O(5) bond length is 2.29 Å. The Cd(3)-O(7) bond length is 2.35 Å. The Cd(3)-O(9) bond length is 2.20 Å. The Cd(3)-Cl(1) bond length is 2.60 Å. In the fourth Cd site, Cd(4) is bonded in a rectangular see-saw-like geometry to one O(16), one O(17), one O(20), and one O(24) atom. The Cd(4)-O(16) bond length is 2.41 Å. The Cd(4)-O(17) bond length is 2.19 Å. The Cd(4)-O(20) bond length is 2.14 Å. The Cd(4)-O(24) bond length is 2.12 Å. There are eight inequivalent C sites. In the first C site, C(73) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(9) atom. The C(73)-O(6) bond length is 1.25 Å. The C(73)-O(9) bond length is 1.28 Å. In the second C site, C(80) is bonded in a bent 120 degrees geometry to one O(11) and one O(14) atom. The C(80)-O(11) bond length is 1.27 Å. The C(80)-O(14) bond length is 1.25 Å. In the third C site, C(83) is bonded in a distorted bent 120 degrees geometry to one O(20) and one O(23) atom. The C(83)-O(20) bond length is 1.23 Å. The C(83)-O(23) bond length is 1.24 Å. In the fourth C site, C(86) is bonded in a bent 120 degrees geometry to one O(16) and one O(24) atom. The C(86)-O(16) bond length is 1.19 Å. The C(86)-O(24) bond length is 1.31 Å. In the fifth C site, C(88) is bonded in a distorted bent 120 degrees geometry to one O(21) and one O(5) atom. The C(88)-O(21) bond length is 1.26 Å. The C(88)-O(5) bond length is 1.29 Å. In the sixth C site, C(90) is bonded in a distorted bent 120 degrees geometry to one O(22) and one O(7) atom. The C(90)-O(22) bond length is 1.40 Å. The C(90)-O(7) bond length is 1.19 Å. In the seventh C site, C(22) is bonded in a distorted bent 120 degrees geometry to one O(10) and one O(4) atom. The C(22)-O(10) bond length is 1.27 Å. The C(22)-O(4) bond length is 1.28 Å. In the eighth C site, C(162) is bonded in a distorted bent 120 degrees geometry to one O(15) and one O(17) atom. The C(162)-O(15) bond length is 1.30 Å. The C(162)-O(17) bond length is 1.26 Å. H(54) is bonded in a distorted single-bond geometry to one O(22) and one O(5) atom. The H(54)-O(22) bond length is 0.82 Å. The H(54)-O(5) bond length is 1.67 Å. There are sixteen inequivalent O sites. In the first O site, O(4) is bonded in a 2-coordinate geometry to one Cd(1), one Cd(2), and one C(22) atom. In the second O site, O(5) is bonded in a 3-coordinate geometry to one Cd(3), one C(88), and one H(54) atom. In the third O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Cd(1) and one C(73) atom. In the fourth O site, O(7) is bonded in a 2-coordinate geometry to one Cd(3) and one C(90) atom. In the fifth O site, O(9) is bonded in a bent 120 degrees geometry to one Cd(3) and one C(73) atom. In the sixth O site, O(10) is bonded in a water-like geometry to one Cd(2) and one C(22) atom. In the seventh O site, O(11) is bonded in an L-shaped geometry to one Cd(1) and one C(80) atom. In the eighth O site, O(14) is bonded in a distorted single-bond geometry to one Cd(1) and one C(80) atom. In the ninth O site, O(15) is bonded in a distorted bent 120 degrees geometry to one Cd(2) and one C(162) atom. In the tenth O site, O(16) is bonded in a distorted L-shaped geometry to one Cd(4) and one C(86) atom. In the eleventh O site, O(17) is bonded in a bent 150 degrees geometry to one Cd(4) and one C(162) atom. In the twelfth O site, O(20) is bonded in a 1-coordinate geometry to one Cd(2), one Cd(4), and one C(83) atom. In the thirteenth O site, O(21) is bonded in a single-bond geometry to one C(88) atom. In the fourteenth O site, O(22) is bonded in a water-like geometry to one C(90) and one H(54) atom. In the fifteenth O site, O(23) is bonded in a distorted water-like geometry to one Cd(2) and one C(83) atom. In the sixteenth O site, O(24) is bonded in a water-like geometry to one Cd(4) and one C(86) atom. Cl(1) is bonded in a water-like geometry to one Cd(1) and one Cd(3) atom. In two of the NiC32H32(NO)2 clusters, Ni(1) is bonded in a square co-planar geometry to one N(5), one N(6), one O(12), and one O(13) atom. The Ni(1)-N(5) bond length is 1.81 Å. The Ni(1)-N(6) bond length is 1.83 Å. The Ni(1)-O(12) bond length is 1.83 Å. The Ni(1)-O(13) bond length is 1.87 Å. There are thirty-two inequivalent C sites. In the first C site, C(49) is bonded in a distorted single-bond geometry to one C(116), one C(25), and one H(24) atom. The C(49)-C(116) bond length is 1.37 Å. The C(49)-C(25) bond length is 1.41 Å. The C(49)-H(24) bond length is 0.93 Å. In the second C site, C(58) is bonded in a tetrahedral geometry to one C(102), one C(133), one C(23), and one C(98) atom. The C(58)-C(102) bond length is 1.58 Å. The C(58)-C(133) bond length is 1.55 Å. The C(58)-C(23) bond length is 1.50 Å. The C(58)-C(98) bond length is 1.53 Å. In the third C site, C(59) is bonded in a trigonal planar geometry to one C(108), one C(128), and one C(38) atom. The C(59)-C(108) bond length is 1.38 Å. The C(59)-C(128) bond length is 1.38 Å. The C(59)-C(38) bond length is 1.52 Å. In the fourth C site, C(72) is bonded in a distorted single-bond geometry to one C(116) and one H(42) atom. The C(72)-C(116) bond length is 1.47 Å. The C(72)-H(42) bond length is 0.93 Å. In the fifth C site, C(75) is bonded in a distorted single-bond geometry to one C(37) and one H(46) atom. The C(75)-C(37) bond length is 1.37 Å. The C(75)-H(46) bond length is 0.93 Å. In the sixth C site, C(92) is bonded in a trigonal non-coplanar geometry to one C(107); one H(60); and two equivalent H(61,62) atoms. The C(92)-C(107) bond length is 1.54 Å. The C(92)-H(60) bond length is 0.96 Å. Both C(92)-H(61,62) bond lengths are 0.96 Å. In the seventh C site, C(95) is bonded in a trigonal non-coplanar geometry to one C(107); one H(68); and two equivalent H(67,69) atoms. The C(95)-C(107) bond length is 1.55 Å. The C(95)-H(68) bond length is 0.96 Å. Both C(95)-H(67,69) bond lengths are 0.96 Å. In the eighth C site, C(98) is bonded in a trigonal non-coplanar geometry to one C(58); one H(73,103); and two equivalent H(74,75) atoms. The C(98)-H(73,103) bond length is 0.96 Å. Both C(98)-H(74,75) bond lengths are 0.96 Å. In the ninth C site, C(102) is bonded in a trigonal non-coplanar geometry to one C(58); one H(29,81); one H(30,82,104); and one H(31,83) atom. The C(102)-H(29,81) bond length is 0.96 Å. The C(102)-H(30,82,104) bond length is 0.96 Å. The C(102)-H(31,83) bond length is 0.96 Å. In the tenth C site, C(107) is bonded in a tetrahedral geometry to one C(123), one C(165), one C(92), and one C(95) atom. The C(107)-C(123) bond length is 1.55 Å. The C(107)-C(165) bond length is 1.48 Å. In the eleventh C site, C(108) is bonded in a distorted single-bond geometry to one C(59) and one H(94) atom. The C(108)-H(94) bond length is 0.93 Å. In the twelfth C site, C(116) is bonded in a trigonal planar geometry to one C(117), one C(49), and one C(72) atom. The C(116)-C(117) bond length is 1.39 Å. In the thirteenth C site, C(117) is bonded in a distorted single-bond geometry to one C(116), one C(23), and one H(100) atom. The C(117)-C(23) bond length is 1.40 Å. The C(117)-H(100) bond length is 0.93 Å. In the fourteenth C site, C(123) is bonded in a trigonal non-coplanar geometry to one C(107); one H(108); and two equivalent H(107,109) atoms. The C(123)-H(108) bond length is 0.96 Å. Both C(123)-H(107,109) bond lengths are 0.96 Å. In the fifteenth C site, C(128) is bonded in a distorted single-bond geometry to one C(59) and one H(116) atom. The C(128)-H(116) bond length is 0.93 Å. In the sixteenth C site, C(132) is bonded in a distorted single-bond geometry to one C(37) and one H(120) atom. The C(132)-C(37) bond length is 1.37 Å. The C(132)-H(120) bond length is 0.93 Å. In the seventeenth C site, C(133) is bonded in a trigonal non-coplanar geometry to one C(58), one H(121), one H(122), and one H(123) atom. The C(133)-H(121) bond length is 0.96 Å. The C(133)-H(122) bond length is 0.96 Å. The C(133)-H(123) bond length is 0.96 Å. In the eighteenth C site, C(20) is bonded in a 2-coordinate geometry to one C(37), one N(6), and one H(8) atom. The C(20)-C(37) bond length is 1.52 Å. The C(20)-N(6) bond length is 1.49 Å. The C(20)-H(8) bond length is 0.98 Å. In the nineteenth C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(25), one N(6), and one H(9) atom. The C(21)-C(25) bond length is 1.41 Å. The C(21)-N(6) bond length is 1.31 Å. The C(21)-H(9) bond length is 0.93 Å. In the twentieth C site, C(23) is bonded in a trigonal planar geometry to one C(117), one C(24), and one C(58) atom. The C(23)-C(24) bond length is 1.40 Å. In the twenty-first C site, C(24) is bonded in a distorted single-bond geometry to one C(23), one C(25), and one O(13) atom. The C(24)-C(25) bond length is 1.41 Å. The C(24)-O(13) bond length is 1.32 Å. In the twenty-second C site, C(25) is bonded in a trigonal planar geometry to one C(21), one C(24), and one C(49) atom. In the twenty-third C site, C(155) is bonded in a distorted bent 120 degrees geometry to one C(36), one N(5), and one H(148) atom. The C(155)-C(36) bond length is 1.41 Å. The C(155)-N(5) bond length is 1.32 Å. The C(155)-H(148) bond length is 0.93 Å. In the twenty-fourth C site, C(36) is bonded in a trigonal planar geometry to one C(155), one C(44), and one C(45) atom. The C(36)-C(44) bond length is 1.40 Å. The C(36)-C(45) bond length is 1.40 Å. In the twenty-fifth C site, C(37) is bonded in a trigonal planar geometry to one C(132), one C(20), and one C(75) atom. In the twenty-sixth C site, C(38) is bonded in a 2-coordinate geometry to one C(59), one N(5), and one H(16) atom. The C(38)-N(5) bond length is 1.50 Å. The C(38)-H(16) bond length is 0.98 Å. In the twenty-seventh C site, C(39) is bonded in a single-bond geometry to one C(165), one C(42), and one H(17) atom. The C(39)-C(165) bond length is 1.35 Å. The C(39)-C(42) bond length is 1.41 Å. The C(39)-H(17) bond length is 0.93 Å. In the twenty-eighth C site, C(165) is bonded in a trigonal planar geometry to one C(107), one C(39), and one C(44) atom. The C(165)-C(44) bond length is 1.47 Å. In the twenty-ninth C site, C(42) is bonded in a trigonal planar geometry to one C(39), one C(45), and one C(46) atom. The C(42)-C(45) bond length is 1.36 Å. The C(42)-C(46) bond length is 1.45 Å. In the thirtieth C site, C(44) is bonded in a distorted single-bond geometry to one C(165), one C(36), and one O(12) atom. The C(44)-O(12) bond length is 1.29 Å. In the thirty-first C site, C(45) is bonded in a distorted single-bond geometry to one C(36), one C(42), and one H(20) atom. The C(45)-H(20) bond length is 0.93 Å. In the thirty-second C site, C(46) is bonded in a distorted single-bond geometry to one C(42) and one H(21) atom. The C(46)-H(21) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one Ni(1), one C(155), and one C(38) atom. In the second N site, N(6) is bonded in a trigonal planar geometry to one Ni(1), one C(20), and one C(21) atom. There are twenty-eight inequivalent H sites. In the first H site, H(116) is bonded in a single-bond geometry to one C(128) atom. In the second H site, H(120) is bonded in a single-bond geometry to one C(132) atom. In the third H site, H(121) is bonded in a single-bond geometry to one C(133) atom. In the fourth H site, H(122) is bonded in a single-bond geometry to one C(133) atom. In the fifth H site, H(123) is bonded in a single-bond geometry to one C(133) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(38) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(39) atom. In the tenth H site, H(148) is bonded in a single-bond geometry to one C(155) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(45) atom. In the twelfth H site, H(21) is bonded in a single-bond geometry to one C(46) atom. In the thirteenth H site, H(24) is bonded in a single-bond geometry to one C(49) atom. In the fourteenth H site, H(29,81) is bonded in a single-bond geometry to one C(61) atom. The H(29,81)-C(61) bond length is 0.96 Å. In the fifteenth H site, H(30,82,104) is bonded in a single-bond geometry to one C(61) atom. The H(30,82,104)-C(61) bond length is 0.96 Å. In the sixteenth H site, H(31,83) is bonded in a single-bond geometry to one C(61) atom. The H(31,83)-C(61) bond length is 0.96 Å. In the seventeenth H site, H(42) is bonded in a single-bond geometry to one C(72) atom. In the eighteenth H site, H(46) is bonded in a single-bond geometry to one C(75) atom. In the nineteenth H site, H(60) is bonded in a single-bond geometry to one C(92) atom. In the twentieth H site, H(61,62) is bonded in a single-bond geometry to one C(92) atom. In the twenty-first H site, H(67,69) is bonded in a single-bond geometry to one C(95) atom. In the twenty-second H site, H(68) is bonded in a single-bond geometry to one C(95) atom. In the twenty-third H site, H(73,103) is bonded in a single-bond geometry to one C(98) atom. In the twenty-fourth H site, H(74,75) is bonded in a single-bond geometry to one C(98) atom. In the twenty-fifth H site, H(108) is bonded in a single-bond geometry to one C(123) atom. In the twenty-sixth H site, H(94) is bonded in a single-bond geometry to one C(108) atom. In the twenty-seventh H site, H(100) is bonded in a single-bond geometry to one C(117) atom. In the twenty-eighth H site, H(107,109) is bonded in a single-bond geometry to one C(123) atom. There are two inequivalent O sites. In the first O site, O(12) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(44) atom. In the second O site, O(13) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(24) atom. In two of the NiC32H32(NO)2 clusters, Ni(3) is bonded in a square co-planar geometry to one N(1), one N(2), one O(1), and one O(2) atom. The Ni(3)-N(1) bond length is 1.85 Å. The Ni(3)-N(2) bond length is 1.86 Å. The Ni(3)-O(1) bond length is 1.84 Å. The Ni(3)-O(2) bond length is 1.86 Å. There are thirty-two inequivalent C sites. In the first C site, C(47) is bonded in a distorted single-bond geometry to one C(2) and one H(22) atom. The C(47)-C(2) bond length is 1.43 Å. The C(47)-H(22) bond length is 0.93 Å. In the second C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(2), and one H(23) atom. The C(48)-C(7) bond length is 1.38 Å. The C(48)-N(2) bond length is 1.28 Å. The C(48)-H(23) bond length is 0.93 Å. In the third C site, C(50) is bonded in a trigonal planar geometry to one C(4), one C(89), and one C(93) atom. The C(50)-C(4) bond length is 1.56 Å. The C(50)-C(89) bond length is 1.39 Å. The C(50)-C(93) bond length is 1.39 Å. In the fourth C site, C(54) is bonded in a distorted single-bond geometry to one C(111) and one H(27) atom. The C(54)-C(111) bond length is 1.43 Å. The C(54)-H(27) bond length is 0.93 Å. In the fifth C site, C(61) is bonded in a trigonal non-coplanar geometry to one C(10); one H(29,81); one H(30,82,104); and one H(31,83) atom. The C(61)-C(10) bond length is 1.55 Å. In the sixth C site, C(63) is bonded in a trigonal non-coplanar geometry to one C(71), one H(33), one H(34), and one H(35) atom. The C(63)-C(71) bond length is 1.50 Å. The C(63)-H(33) bond length is 0.96 Å. The C(63)-H(34) bond length is 0.96 Å. The C(63)-H(35) bond length is 0.96 Å. In the seventh C site, C(70) is bonded in a trigonal non-coplanar geometry to one C(10); one H(40); and two equivalent H(39,41) atoms. The C(70)-C(10) bond length is 1.49 Å. The C(70)-H(40) bond length is 0.96 Å. Both C(70)-H(39,41) bond lengths are 0.96 Å. In the eighth C site, C(71) is bonded in a tetrahedral geometry to one C(12), one C(135), one C(63), and one C(74) atom. The C(71)-C(12) bond length is 1.56 Å. The C(71)-C(135) bond length is 1.47 Å. The C(71)-C(74) bond length is 1.51 Å. In the ninth C site, C(74) is bonded in a trigonal non-coplanar geometry to one C(71), one H(43), one H(44), and one H(45) atom. The C(74)-H(43) bond length is 0.96 Å. The C(74)-H(44) bond length is 0.96 Å. The C(74)-H(45) bond length is 0.96 Å. In the tenth C site, C(82) is bonded in a distorted single-bond geometry to one C(2), one C(6), and one H(53) atom. The C(82)-C(2) bond length is 1.42 Å. The C(82)-C(6) bond length is 1.39 Å. The C(82)-H(53) bond length is 0.93 Å. In the eleventh C site, C(89) is bonded in a distorted single-bond geometry to one C(50) and one H(58) atom. The C(89)-H(58) bond length is 0.93 Å. In the twelfth C site, C(93) is bonded in a distorted single-bond geometry to one C(50) and one H(63) atom. The C(93)-H(63) bond length is 0.93 Å. In the thirteenth C site, C(111) is bonded in a trigonal planar geometry to one C(11), one C(54), and one C(9) atom. The C(111)-C(11) bond length is 1.45 Å. The C(111)-C(9) bond length is 1.37 Å. In the fourteenth C site, C(115) is bonded in a trigonal planar geometry to one C(121), one C(122), and one C(13) atom. The C(115)-C(121) bond length is 1.37 Å. The C(115)-C(122) bond length is 1.39 Å. The C(115)-C(13) bond length is 1.48 Å. In the fifteenth C site, C(121) is bonded in a distorted single-bond geometry to one C(115) and one H(105) atom. The C(121)-H(105) bond length is 0.93 Å. In the sixteenth C site, C(122) is bonded in a distorted single-bond geometry to one C(115) and one H(106) atom. The C(122)-H(106) bond length is 0.93 Å. In the seventeenth C site, C(120) is bonded in a trigonal non-coplanar geometry to one C(10); one H(102); one H(30,82,104); and one H(73,103) atom. The C(120)-C(10) bond length is 1.58 Å. The C(120)-H(102) bond length is 0.96 Å. The C(120)-H(30,82,104) bond length is 0.96 Å. The C(120)-H(73,103) bond length is 0.96 Å. In the eighteenth C site, C(1) is bonded in a distorted single-bond geometry to one C(14), one C(6), and one O(1) atom. The C(1)-C(14) bond length is 1.43 Å. The C(1)-C(6) bond length is 1.45 Å. The C(1)-O(1) bond length is 1.30 Å. In the nineteenth C site, C(2) is bonded in a trigonal planar geometry to one C(47), one C(5), and one C(82) atom. The C(2)-C(5) bond length is 1.39 Å. In the twentieth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(1), and one H(1) atom. The C(3)-C(14) bond length is 1.38 Å. The C(3)-N(1) bond length is 1.28 Å. The C(3)-H(1) bond length is 0.93 Å. In the twenty-first C site, C(4) is bonded in a 2-coordinate geometry to one C(50), one N(2), and one H(2) atom. The C(4)-N(2) bond length is 1.49 Å. The C(4)-H(2) bond length is 0.98 Å. In the twenty-second C site, C(5) is bonded in a distorted single-bond geometry to one C(14), one C(2), and one H(3) atom. The C(5)-C(14) bond length is 1.42 Å. The C(5)-H(3) bond length is 0.93 Å. In the twenty-third C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(82) atom. The C(6)-C(10) bond length is 1.51 Å. In the twenty-fourth C site, C(7) is bonded in a trigonal planar geometry to one C(48), one C(8), and one C(9) atom. The C(7)-C(8) bond length is 1.45 Å. The C(7)-C(9) bond length is 1.42 Å. In the twenty-fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(12), one C(7), and one O(2) atom. The C(8)-C(12) bond length is 1.47 Å. The C(8)-O(2) bond length is 1.30 Å. In the twenty-sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(111), one C(7), and one H(4) atom. The C(9)-H(4) bond length is 0.93 Å. In the twenty-seventh C site, C(10) is bonded in a tetrahedral geometry to one C(120), one C(6), one C(61), and one C(70) atom. In the twenty-eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(111), one C(12), and one H(5) atom. The C(11)-C(12) bond length is 1.35 Å. The C(11)-H(5) bond length is 0.93 Å. In the twenty-ninth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(71), and one C(8) atom. In the thirtieth C site, C(13) is bonded in a 2-coordinate geometry to one C(115), one N(1), and one H(6) atom. The C(13)-N(1) bond length is 1.46 Å. The C(13)-H(6) bond length is 0.98 Å. In the thirty-first C site, C(14) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(5) atom. In the thirty-second C site, C(135) is bonded in a trigonal non-coplanar geometry to one C(71); one H(125); and two equivalent H(126,127) atoms. The C(135)-H(125) bond length is 0.96 Å. Both C(135)-H(126,127) bond lengths are 0.96 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(3), one C(13), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ni(3), one C(4), and one C(48) atom. There are twenty-nine inequivalent H sites. In the first H site, H(125) is bonded in a single-bond geometry to one C(135) atom. In the second H site, H(126,127) is bonded in a single-bond geometry to one C(135) atom. In the third H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the sixth H site, H(4) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(5) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(22) is bonded in a single-bond geometry to one C(47) atom. In the tenth H site, H(23) is bonded in a single-bond geometry to one C(48) atom. In the eleventh H site, H(27) is bonded in a single-bond geometry to one C(54) atom. In the twelfth H site, H(29,81) is bonded in a single-bond geometry to one C(61) atom. In the thirteenth H site, H(30,82,104) is bonded in a single-bond geometry to one C(61) atom. In the fourteenth H site, H(31,83) is bonded in a single-bond geometry to one C(61) atom. In the fifteenth H site, H(33) is bonded in a single-bond geometry to one C(63) atom. In the sixteenth H site, H(34) is bonded in a single-bond geometry to one C(63) atom. In the seventeenth H site, H(35) is bonded in a single-bond geometry to one C(63) atom. In the eighteenth H site, H(39,41) is bonded in a single-bond geometry to one C(70) atom. In the nineteenth H site, H(40) is bonded in a single-bond geometry to one C(70) atom. In the twentieth H site, H(43) is bonded in a single-bond geometry to one C(74) atom. In the twenty-first H site, H(44) is bonded in a single-bond geometry to one C(74) atom. In the twenty-second H site, H(45) is bonded in a single-bond geometry to one C(74) atom. In the twenty-third H site, H(53) is bonded in a single-bond geometry to one C(82) atom. In the twenty-fourth H site, H(58) is bonded in a single-bond geometry to one C(89) atom. In the twenty-fifth H site, H(63) is bonded in a single-bond geometry to one C(93) atom. In the twenty-sixth H site, H(73,103) is bonded in a single-bond geometry to one C(98) atom. In the twenty-seventh H site, H(102) is bonded in a single-bond geometry to one C(120) atom. In the twenty-eighth H site, H(105) is bonded in a single-bond geometry to one C(121) atom. In the twenty-ninth H site, H(106) is bonded in a single-bond geometry to one C(122) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ni(3) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ni(3) and one C(8) atom. In two of the NiC32H32(NO)2 clusters, Ni(4) is bonded in a square co-planar geometry to one N(7), one N(8), one O(18), and one O(19) atom. The Ni(4)-N(7) bond length is 1.83 Å. The Ni(4)-N(8) bond length is 1.83 Å. The Ni(4)-O(18) bond length is 1.81 Å. The Ni(4)-O(19) bond length is 1.84 Å. There are thirty-two inequivalent C sites. In the first C site, C(52) is bonded in a distorted bent 120 degrees geometry to one C(139), one N(8), and one H(26) atom. The C(52)-C(139) bond length is 1.37 Å. The C(52)-N(8) bond length is 1.28 Å. The C(52)-H(26) bond length is 0.93 Å. In the second C site, C(53) is bonded in a tetrahedral geometry to one C(101), one C(110), one C(167), and one C(40) atom. The C(53)-C(101) bond length is 1.55 Å. The C(53)-C(110) bond length is 1.49 Å. The C(53)-C(167) bond length is 1.50 Å. The C(53)-C(40) bond length is 1.54 Å. In the third C site, C(55) is bonded in a tetrahedral geometry to one C(142), one C(60), one C(81), and one C(94) atom. The C(55)-C(142) bond length is 1.49 Å. The C(55)-C(60) bond length is 1.55 Å. The C(55)-C(81) bond length is 1.54 Å. The C(55)-C(94) bond length is 1.50 Å. In the fourth C site, C(60) is bonded in a trigonal planar geometry to one C(26), one C(55), and one C(76) atom. The C(60)-C(26) bond length is 1.45 Å. The C(60)-C(76) bond length is 1.38 Å. In the fifth C site, C(65) is bonded in a distorted single-bond geometry to one C(77) and one H(37) atom. The C(65)-C(77) bond length is 1.46 Å. The C(65)-H(37) bond length is 0.93 Å. In the sixth C site, C(66) is bonded in a trigonal planar geometry to one C(152), one C(168), and one C(34) atom. The C(66)-C(152) bond length is 1.36 Å. The C(66)-C(168) bond length is 1.35 Å. The C(66)-C(34) bond length is 1.43 Å. In the seventh C site, C(69) is bonded in a distorted single-bond geometry to one C(138), one C(77), and one H(38) atom. The C(69)-C(138) bond length is 1.46 Å. The C(69)-C(77) bond length is 1.35 Å. The C(69)-H(38) bond length is 0.93 Å. In the eighth C site, C(76) is bonded in a distorted single-bond geometry to one C(140), one C(60), and one H(47) atom. The C(76)-C(140) bond length is 1.42 Å. The C(76)-H(47) bond length is 0.93 Å. In the ninth C site, C(77) is bonded in a trigonal planar geometry to one C(43), one C(65), and one C(69) atom. The C(77)-C(43) bond length is 1.41 Å. In the tenth C site, C(81) is bonded in a trigonal non-coplanar geometry to one C(55), one H(50), one H(51), and one H(52) atom. The C(81)-H(50) bond length is 0.96 Å. The C(81)-H(51) bond length is 0.96 Å. The C(81)-H(52) bond length is 0.96 Å. In the eleventh C site, C(94) is bonded in a trigonal non-coplanar geometry to one C(55); one H(66); and two equivalent H(64,65) atoms. The C(94)-H(66) bond length is 0.96 Å. Both C(94)-H(64,65) bond lengths are 0.96 Å. In the twelfth C site, C(97) is bonded in a trigonal planar geometry to one C(144), one C(148), and one C(28) atom. The C(97)-C(144) bond length is 1.39 Å. The C(97)-C(148) bond length is 1.39 Å. The C(97)-C(28) bond length is 1.50 Å. In the thirteenth C site, C(99) is bonded in a distorted single-bond geometry to one C(140) and one H(76) atom. The C(99)-C(140) bond length is 1.45 Å. The C(99)-H(76) bond length is 0.93 Å. In the fourteenth C site, C(101) is bonded in a trigonal non-coplanar geometry to one C(53); one H(78); and two equivalent H(79,80,96,97,98) atoms. The C(101)-H(78) bond length is 0.96 Å. Both C(101)-H(79,80,96,97,98) bond lengths are 0.96 Å. In the fifteenth C site, C(110) is bonded in a trigonal non-coplanar geometry to one C(53) and three equivalent H(79,80,96,97,98) atoms. All C(110)-H(79,80,96,97,98) bond lengths are 0.96 Å. In the sixteenth C site, C(137) is bonded in a distorted single-bond geometry to one C(139), one C(140), and one H(129) atom. The C(137)-C(139) bond length is 1.40 Å. The C(137)-C(140) bond length is 1.41 Å. The C(137)-H(129) bond length is 0.93 Å. In the seventeenth C site, C(138) is bonded in a trigonal planar geometry to one C(27), one C(33), and one C(69) atom. The C(138)-C(27) bond length is 1.39 Å. The C(138)-C(33) bond length is 1.42 Å. In the eighteenth C site, C(139) is bonded in a trigonal planar geometry to one C(137), one C(26), and one C(52) atom. The C(139)-C(26) bond length is 1.47 Å. In the nineteenth C site, C(140) is bonded in a trigonal planar geometry to one C(137), one C(76), and one C(99) atom. In the twentieth C site, C(142) is bonded in a trigonal non-coplanar geometry to one C(55), one H(131), one H(132), and one H(133) atom. The C(142)-H(131) bond length is 0.96 Å. The C(142)-H(132) bond length is 0.96 Å. The C(142)-H(133) bond length is 0.96 Å. In the twenty-first C site, C(144) is bonded in a distorted single-bond geometry to one C(97) and one H(135) atom. The C(144)-H(135) bond length is 0.93 Å. In the twenty-second C site, C(148) is bonded in a distorted single-bond geometry to one C(97) and one H(139) atom. The C(148)-H(139) bond length is 0.93 Å. In the twenty-third C site, C(152) is bonded in a distorted single-bond geometry to one C(66) and one H(145) atom. The C(152)-H(145) bond length is 0.93 Å. In the twenty-fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(139), one C(60), and one O(19) atom. The C(26)-O(19) bond length is 1.28 Å. In the twenty-fifth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(138), one N(7), and one H(10) atom. The C(27)-N(7) bond length is 1.28 Å. The C(27)-H(10) bond length is 0.93 Å. In the twenty-sixth C site, C(28) is bonded in a 2-coordinate geometry to one C(97), one N(7), and one H(11) atom. The C(28)-N(7) bond length is 1.47 Å. The C(28)-H(11) bond length is 0.98 Å. In the twenty-seventh C site, C(168) is bonded in a distorted single-bond geometry to one C(66) and one H(161) atom. The C(168)-H(161) bond length is 0.93 Å. In the twenty-eighth C site, C(33) is bonded in a distorted single-bond geometry to one C(138), one C(40), and one O(18) atom. The C(33)-C(40) bond length is 1.41 Å. The C(33)-O(18) bond length is 1.32 Å. In the twenty-ninth C site, C(34) is bonded in a 2-coordinate geometry to one C(66), one N(8), and one H(15) atom. The C(34)-N(8) bond length is 1.43 Å. The C(34)-H(15) bond length is 0.98 Å. In the thirtieth C site, C(167) is bonded in a trigonal non-coplanar geometry to one C(53); one H(160); and two equivalent H(158,159) atoms. The C(167)-H(160) bond length is 0.96 Å. Both C(167)-H(158,159) bond lengths are 0.96 Å. In the thirty-first C site, C(40) is bonded in a trigonal planar geometry to one C(33), one C(43), and one C(53) atom. The C(40)-C(43) bond length is 1.40 Å. In the thirty-second C site, C(43) is bonded in a distorted single-bond geometry to one C(40), one C(77), and one H(19) atom. The C(43)-H(19) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(7) is bonded in a trigonal planar geometry to one Ni(4), one C(27), and one C(28) atom. In the second N site, N(8) is bonded in a trigonal planar geometry to one Ni(4), one C(34), and one C(52) atom. There are twenty-six inequivalent H sites. In the first H site, H(129) is bonded in a single-bond geometry to one C(137) atom. In the second H site, H(131) is bonded in a single-bond geometry to one C(142) atom. In the third H site, H(132) is bonded in a single-bond geometry to one C(142) atom. In the fourth H site, H(135) is bonded in a single-bond geometry to one C(144) atom. In the fifth H site, H(133) is bonded in a single-bond geometry to one C(142) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(27) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(28) atom. In the eighth H site, H(139) is bonded in a single-bond geometry to one C(148) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(34) atom. In the tenth H site, H(145) is bonded in a single-bond geometry to one C(152) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(43) atom. In the twelfth H site, H(26) is bonded in a single-bond geometry to one C(52) atom. In the thirteenth H site, H(158,159) is bonded in a single-bond geometry to one C(167) atom. In the fourteenth H site, H(161) is bonded in a single-bond geometry to one C(168) atom. In the fifteenth H site, H(160) is bonded in a single-bond geometry to one C(167) atom. In the sixteenth H site, H(38) is bonded in a single-bond geometry to one C(69) atom. In the seventeenth H site, H(37) is bonded in a single-bond geometry to one C(65) atom. In the eighteenth H site, H(47) is bonded in a single-bond geometry to one C(76) atom. In the nineteenth H site, H(50) is bonded in a single-bond geometry to one C(81) atom. In the twentieth H site, H(51) is bonded in a single-bond geometry to one C(81) atom. In the twenty-first H site, H(52) is bonded in a single-bond geometry to one C(81) atom. In the twenty-second H site, H(64,65) is bonded in a single-bond geometry to one C(94) atom. In the twenty-third H site, H(66) is bonded in a single-bond geometry to one C(94) atom. In the twenty-fourth H site, H(78) is bonded in a single-bond geometry to one C(101) atom. In the twenty-fifth H site, H(79,80,96,97,98) is bonded in a single-bond geometry to one C(101) atom. In the twenty-sixth H site, H(76) is bonded in a single-bond geometry to one C(99) atom. There are two inequivalent O sites. In the first O site, O(18) is bonded in a bent 120 degrees geometry to one Ni(4) and one C(33) atom. In the second O site, O(19) is bonded in a bent 120 degrees geometry to one Ni(4) and one C(26) atom. In each NiC33H33(NO)2 cluster, Ni(2) is bonded in a square co-planar geometry to one N(3), one N(4), one O(3), and one O(8) atom. The Ni(2)-N(3) bond length is 1.82 Å. The Ni(2)-N(4) bond length is 1.83 Å. The Ni(2)-O(3) bond length is 1.87 Å. The Ni(2)-O(8) bond length is 1.82 Å. There are thirty-three inequivalent C sites. In the first C site, C(51) is bonded in a distorted trigonal planar geometry to one C(19), one C(62), and one H(25) atom. The C(51)-C(19) bond length is 1.46 Å. The C(51)-C(62) bond length is 1.35 Å. The C(51)-H(25) bond length is 0.93 Å. In the second C site, C(57) is bonded in a trigonal planar geometry to one C(78), one C(85), and one C(87) atom. The C(57)-C(78) bond length is 1.42 Å. The C(57)-C(85) bond length is 1.43 Å. The C(57)-C(87) bond length is 1.35 Å. In the third C site, C(62) is bonded in a distorted single-bond geometry to one C(51) and one H(32) atom. The C(62)-H(32) bond length is 0.93 Å. In the fourth C site, C(67) is bonded in a tetrahedral geometry to one C(104), one C(127), one C(149), and one C(68) atom. The C(67)-C(104) bond length is 1.55 Å. The C(67)-C(127) bond length is 1.47 Å. The C(67)-C(149) bond length is 1.47 Å. The C(67)-C(68) bond length is 1.56 Å. In the fifth C site, C(68) is bonded in a trigonal planar geometry to one C(30), one C(67), and one C(78) atom. The C(68)-C(30) bond length is 1.44 Å. The C(68)-C(78) bond length is 1.36 Å. In the sixth C site, C(78) is bonded in a distorted single-bond geometry to one C(57), one C(68), and one H(48) atom. The C(78)-H(48) bond length is 0.93 Å. In the seventh C site, C(85) is bonded in a distorted single-bond geometry to one C(57) and one H(56) atom. The C(85)-H(56) bond length is 0.93 Å. In the eighth C site, C(87) is bonded in a distorted single-bond geometry to one C(35), one C(57), and one H(57) atom. The C(87)-C(35) bond length is 1.39 Å. The C(87)-H(57) bond length is 0.93 Å. In the ninth C site, C(96) is bonded in a trigonal non-coplanar geometry to one C(112); one H(71); and two equivalent H(70,72) atoms. The C(96)-C(112) bond length is 1.52 Å. The C(96)-H(71) bond length is 0.96 Å. Both C(96)-H(70,72) bond lengths are 0.96 Å. In the tenth C site, C(104) is bonded in a trigonal non-coplanar geometry to one C(67); one H(85); one H(86); and one H(87,142) atom. The C(104)-H(85) bond length is 0.96 Å. The C(104)-H(86) bond length is 0.96 Å. The C(104)-H(87,142) bond length is 0.96 Å. In the eleventh C site, C(105) is bonded in a trigonal non-coplanar geometry to one C(112), one H(88), one H(89), and one H(90) atom. The C(105)-C(112) bond length is 1.51 Å. The C(105)-H(88) bond length is 0.96 Å. The C(105)-H(89) bond length is 0.96 Å. The C(105)-H(90) bond length is 0.96 Å. In the twelfth C site, C(106) is bonded in a trigonal non-coplanar geometry to one C(112), one H(91), one H(92), and one H(93) atom. The C(106)-C(112) bond length is 1.53 Å. The C(106)-H(91) bond length is 0.96 Å. The C(106)-H(92) bond length is 0.96 Å. The C(106)-H(93) bond length is 0.96 Å. In the thirteenth C site, C(112) is bonded in a tetrahedral geometry to one C(105), one C(106), one C(17), and one C(96) atom. The C(112)-C(17) bond length is 1.52 Å. In the fourteenth C site, C(113) is bonded in a distorted single-bond geometry to one C(114) and one H(99) atom. The C(113)-C(114) bond length is 1.38 Å. The C(113)-H(99) bond length is 0.93 Å. In the fifteenth C site, C(114) is bonded in a trigonal planar geometry to one C(113), one C(119), and one C(31) atom. The C(114)-C(119) bond length is 1.39 Å. The C(114)-C(31) bond length is 1.49 Å. In the sixteenth C site, C(118) is bonded in a trigonal planar geometry to one C(124), one C(126), and one C(29) atom. The C(118)-C(124) bond length is 1.38 Å. The C(118)-C(126) bond length is 1.38 Å. The C(118)-C(29) bond length is 1.50 Å. In the seventeenth C site, C(119) is bonded in a distorted single-bond geometry to one C(114) and one H(101) atom. The C(119)-H(101) bond length is 0.93 Å. In the eighteenth C site, C(124) is bonded in a distorted single-bond geometry to one C(118) and one H(110) atom. The C(124)-H(110) bond length is 0.93 Å. In the nineteenth C site, C(126) is bonded in a distorted single-bond geometry to one C(118) and one H(112) atom. The C(126)-H(112) bond length is 0.93 Å. In the twentieth C site, C(127) is bonded in a trigonal non-coplanar geometry to one C(67), one H(113), one H(114), and one H(115) atom. The C(127)-H(113) bond length is 0.96 Å. The C(127)-H(114) bond length is 0.96 Å. The C(127)-H(115) bond length is 0.96 Å. In the twenty-first C site, C(15) is bonded in a trigonal planar geometry to one C(154), one C(16), and one C(18) atom. The C(15)-C(154) bond length is 1.43 Å. The C(15)-C(16) bond length is 1.41 Å. The C(15)-C(18) bond length is 1.44 Å. In the twenty-second C site, C(16) is bonded in a distorted single-bond geometry to one C(15), one C(17), and one O(3) atom. The C(16)-C(17) bond length is 1.43 Å. The C(16)-O(3) bond length is 1.31 Å. In the twenty-third C site, C(17) is bonded in a trigonal planar geometry to one C(112), one C(16), and one C(41) atom. The C(17)-C(41) bond length is 1.38 Å. In the twenty-fourth C site, C(18) is bonded in a distorted single-bond geometry to one C(15), one C(19), and one H(7) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(7) bond length is 0.93 Å. In the twenty-fifth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(41), and one C(51) atom. The C(19)-C(41) bond length is 1.39 Å. In the twenty-sixth C site, C(149) is bonded in a trigonal non-coplanar geometry to one C(67); one H(140); one H(141); and one H(87,142) atom. The C(149)-H(140) bond length is 0.96 Å. The C(149)-H(141) bond length is 0.96 Å. The C(149)-H(87,142) bond length is 0.96 Å. In the twenty-seventh C site, C(154) is bonded in a distorted bent 120 degrees geometry to one C(15), one N(4), and one H(147) atom. The C(154)-N(4) bond length is 1.31 Å. The C(154)-H(147) bond length is 0.93 Å. In the twenty-eighth C site, C(29) is bonded in a 2-coordinate geometry to one C(118), one N(4), and one H(12) atom. The C(29)-N(4) bond length is 1.45 Å. The C(29)-H(12) bond length is 0.98 Å. In the twenty-ninth C site, C(30) is bonded in a distorted single-bond geometry to one C(35), one C(68), and one O(8) atom. The C(30)-C(35) bond length is 1.44 Å. The C(30)-O(8) bond length is 1.32 Å. In the thirtieth C site, C(31) is bonded in a 2-coordinate geometry to one C(114), one N(3), and one H(13) atom. The C(31)-N(3) bond length is 1.51 Å. The C(31)-H(13) bond length is 0.98 Å. In the thirty-first C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(35), one N(3), and one H(14) atom. The C(32)-C(35) bond length is 1.42 Å. The C(32)-N(3) bond length is 1.28 Å. The C(32)-H(14) bond length is 0.93 Å. In the thirty-second C site, C(35) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(87) atom. In the thirty-third C site, C(41) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(18) atom. The C(41)-H(18) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Ni(2), one C(31), and one C(32) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one Ni(2), one C(154), and one C(29) atom. There are thirty-one inequivalent H sites. In the first H site, H(113) is bonded in a single-bond geometry to one C(127) atom. In the second H site, H(114) is bonded in a single-bond geometry to one C(127) atom. In the third H site, H(115) is bonded in a single-bond geometry to one C(127) atom. In the fourth H site, H(7) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(29) atom. In the sixth H site, H(13) is bonded in a single-bond geometry to one C(31) atom. In the seventh H site, H(140) is bonded in a single-bond geometry to one C(149) atom. In the eighth H site, H(141) is bonded in a single-bond geometry to one C(149) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(32) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(41) atom. In the eleventh H site, H(147) is bonded in a single-bond geometry to one C(154) atom. In the twelfth H site, H(25) is bonded in a single-bond geometry to one C(51) atom. In the thirteenth H site, H(32) is bonded in a single-bond geometry to one C(62) atom. In the fourteenth H site, H(48) is bonded in a single-bond geometry to one C(78) atom. In the fifteenth H site, H(57) is bonded in a single-bond geometry to one C(87) atom. In the sixteenth H site, H(56) is bonded in a single-bond geometry to one C(85) atom. In the seventeenth H site, H(70,72) is bonded in a single-bond geometry to one C(96) atom. In the eighteenth H site, H(71) is bonded in a single-bond geometry to one C(96) atom. In the nineteenth H site, H(85) is bonded in a single-bond geometry to one C(104) atom. In the twentieth H site, H(87,142) is bonded in a single-bond geometry to one C(104) atom. In the twenty-first H site, H(86) is bonded in a single-bond geometry to one C(104) atom. In the twenty-second H site, H(88) is bonded in a single-bond geometry to one C(105) atom. In the twenty-third H site, H(89) is bonded in a single-bond geometry to one C(105) atom. In the twenty-fourth H site, H(93) is bonded in a single-bond geometry to one C(106) atom. In the twenty-fifth H site, H(90) is bonded in a single-bond geometry to one C(105) atom. In the twenty-sixth H site, H(91) is bonded in a single-bond geometry to one C(106) atom. In the twenty-seventh H site, H(99) is bonded in a single-bond geometry to one C(113) atom. In the twenty-eighth H site, H(92) is bonded in a single-bond geometry to one C(106) atom. In the twenty-ninth H site, H(101) is bonded in a single-bond geometry to one C(119) atom. In the thirtieth H site, H(110) is bonded in a single-bond geometry to one C(124) atom. In the thirty-first H site, H(112) is bonded in a single-bond geometry to one C(126) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a bent 120 degrees geometry to one Ni(2) and one C(16) atom. In the second O site, O(8) is bonded in a bent 120 degrees geometry to one Ni(2) and one C(30) atom. Linkers: 4 CC(C)(C)C1=CC(/C=C/C([O])=O)=CC2=CN3[C@H](c4ccccc4)[C@@H](c4ccccc4)N4C=C5[CH]C(/C=C/C([O])=O)=CC(C(C)(C)C)=C5O[Ni@@]34O[C]21 ,2 CC(C)(C)C1=CC(/C=C/C([O])=O)=CC2=CN3[C@H](c4ccccc4)[C@@H](c4ccccc4)N4C=C5[CH]C(/C=C/C([O])=O)=CC(C(C)(C)C)=C5O[Ni@]34O[C]21 ,1 CC(C)(C)C1=CC(/C=C/C(=O)O)=CC2=CN3[C@H](c4ccccc4)[C@@H](c4ccccc4)N4C=C5[CH]C(/C=C/C([O])=O)=CC(C(C)(C)C)=C5O[Ni@]34O[C]21 ,1 CC(C)(C)C1=CC(/C=C/C([O])=O)=CC2=CN3[C@H](c4ccccc4)[C@@H](c4ccccc4)N4C=C5[CH]C(/C=C/C(=O)O)=CC(C(C)(C)C)=C5O[Ni@]34O[C]21. Metal clusters: 2 O=[C]O[Cd](O[C]O)O[C]O[Cd]1(Cl)(O[C]O[Cd]2O[C]O[Cd]3(O[C]O2)O[C]O3)O[C]O1. The MOF has largest included sphere 7.38 A, density 1.12 g/cm3, surface area 4768.70 m2/g, accessible volume 0.46 cm3/g