CdH13(C8N3)2(C3H2)3(CH)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; six 2,3-dimethyl-1,3-butadiene molecules; and four CdH13(C8N3)2 clusters. In each CdH13(C8N3)2 cluster, Cd(1) is bonded in a T-shaped geometry to one N(1), one N(3), and one N(5) atom. The Cd(1)-N(1) bond length is 2.31 Å. The Cd(1)-N(3) bond length is 2.37 Å. The Cd(1)-N(5) bond length is 2.32 Å. There are sixteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.36 Å. The C(1)-N(1) bond length is 1.36 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(1), one N(2), and one H(2) atom. The C(2)-N(2) bond length is 1.37 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. The C(3)-N(1) bond length is 1.31 Å. The C(3)-N(2) bond length is 1.36 Å. The C(3)-H(3) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one N(2) atom. The C(4)-C(5) bond length is 1.39 Å. The C(4)-C(9) bond length is 1.39 Å. The C(4)-N(2) bond length is 1.43 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(4) atom. The C(5)-H(4) bond length is 0.93 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(4) and one H(7) atom. The C(9)-H(7) bond length is 0.93 Å. In the seventh C site, C(10) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(8) atom. The C(10)-N(3) bond length is 1.31 Å. The C(10)-N(4) bond length is 1.36 Å. The C(10)-H(8) bond length is 0.93 Å. In the eighth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one N(3), and one H(9) atom. The C(11)-C(12) bond length is 1.34 Å. The C(11)-N(3) bond length is 1.38 Å. The C(11)-H(9) bond length is 0.93 Å. In the ninth C site, C(12) is bonded in a 3-coordinate geometry to one C(11), one N(4), and one H(10) atom. The C(12)-N(4) bond length is 1.38 Å. The C(12)-H(10) bond length is 0.93 Å. In the tenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(14), one C(18), and one N(4) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-C(18) bond length is 1.36 Å. The C(13)-N(4) bond length is 1.43 Å. In the eleventh C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(11) atom. The C(14)-H(11) bond length is 0.93 Å. In the twelfth C site, C(18) is bonded in a single-bond geometry to one C(13) and one H(14) atom. The C(18)-H(14) bond length is 0.93 Å. In the thirteenth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one C(20), one N(5), and one H(15) atom. The C(19)-C(20) bond length is 1.35 Å. The C(19)-N(5) bond length is 1.37 Å. The C(19)-H(15) bond length is 0.93 Å. In the fourteenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(6), and one H(16) atom. The C(20)-N(6) bond length is 1.37 Å. The C(20)-H(16) bond length is 0.93 Å. In the fifteenth C site, C(21) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(17) atom. The C(21)-N(5) bond length is 1.31 Å. The C(21)-N(6) bond length is 1.36 Å. The C(21)-H(17) bond length is 0.93 Å. In the sixteenth C site, C(22) is bonded in a distorted single-bond geometry to one N(6) atom. The C(22)-N(6) bond length is 1.43 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(1), and one C(3) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(10), and one C(11) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(13) atom. In the fifth N site, N(5) is bonded in a distorted trigonal planar geometry to one Cd(1), one C(19), and one C(21) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(20), one C(21), and one C(22) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(17) is bonded in a single-bond geometry to one C(21) atom. Linkers: 6 c1cn(-c2ccc(-c3ccc(-n4ccnc4)cc3)cc2)cn1. Metal clusters: 4 [Cd]. The MOF has largest included sphere 6.21 A, density 0.98 g/cm3, surface area 4804.94 m2/g, accessible volume 0.54 cm3/g