AgH4(C2N)2AgH32(C6N)4 is Indium-like structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of four AgH32(C6N)4 clusters and four AgH4(C2N)2 clusters. In each AgH32(C6N)4 cluster, Ag(2) is bonded in a linear geometry to one N(3) and one N(4) atom. The Ag(2)-N(3) bond length is 2.17 Å. The Ag(2)-N(4) bond length is 2.20 Å. There are twenty-four inequivalent C sites. In the first C site, C(2) is bonded in a distorted single-bond geometry to one C(3) and one H(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-H(2) bond length is 0.95 Å. In the second C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.42 Å. The C(3)-C(6) bond length is 1.48 Å. In the third C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.95 Å. In the fourth C site, C(6) is bonded in a 4-coordinate geometry to one C(3); one N(2); and two equivalent H(5,6) atoms. The C(6)-N(2) bond length is 1.53 Å. Both C(6)-H(5,6) bond lengths are 0.99 Å. In the fifth C site, C(7) is bonded in a 3-coordinate geometry to one C(8), one N(2), one H(7), and one H(8) atom. The C(7)-C(8) bond length is 1.48 Å. The C(7)-N(2) bond length is 1.48 Å. The C(7)-H(7) bond length is 0.99 Å. The C(7)-H(8) bond length is 0.99 Å. In the sixth C site, C(8) is bonded in a 4-coordinate geometry to one C(7), one N(3), one H(10), and one H(9) atom. The C(8)-N(3) bond length is 1.57 Å. The C(8)-H(10) bond length is 0.99 Å. The C(8)-H(9) bond length is 0.99 Å. In the seventh C site, C(9) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one H(11), and one H(12) atom. The C(9)-N(3) bond length is 1.43 Å. The C(9)-H(11) bond length is 0.99 Å. The C(9)-H(12) bond length is 0.99 Å. In the eighth C site, C(10) is bonded in a 3-coordinate geometry to one N(2), one H(13), and one H(14) atom. The C(10)-N(2) bond length is 1.48 Å. The C(10)-H(13) bond length is 0.99 Å. The C(10)-H(14) bond length is 0.99 Å. In the ninth C site, C(14) is bonded in a distorted single-bond geometry to one C(15) and one H(18,19) atom. The C(14)-C(15) bond length is 1.37 Å. The C(14)-H(18,19) bond length is 0.95 Å. In the tenth C site, C(17) is bonded in a distorted single-bond geometry to one C(12) and one H(17,20) atom. The C(17)-C(12) bond length is 1.41 Å. The C(17)-H(17,20) bond length is 0.95 Å. In the eleventh C site, C(18) is bonded in a 3-coordinate geometry to one C(15), one N(4), one H(21), and one H(22) atom. The C(18)-C(15) bond length is 1.50 Å. The C(18)-N(4) bond length is 1.51 Å. The C(18)-H(21) bond length is 0.99 Å. The C(18)-H(22) bond length is 0.99 Å. In the twelfth C site, C(19) is bonded in a 4-coordinate geometry to one C(20), one N(4), one H(23), and one H(24) atom. The C(19)-C(20) bond length is 1.47 Å. The C(19)-N(4) bond length is 1.49 Å. The C(19)-H(23) bond length is 0.99 Å. The C(19)-H(24) bond length is 0.99 Å. In the thirteenth C site, C(20) is bonded in a 3-coordinate geometry to one C(19), one N(5), one H(25), and one H(26) atom. The C(20)-N(5) bond length is 1.47 Å. The C(20)-H(25) bond length is 0.99 Å. The C(20)-H(26) bond length is 0.99 Å. In the fourteenth C site, C(22) is bonded in a distorted trigonal non-coplanar geometry to one N(4) and two equivalent H(29,30) atoms. The C(22)-N(4) bond length is 1.42 Å. Both C(22)-H(29,30) bond lengths are 0.99 Å. In the fifteenth C site, C(21) is bonded in a 3-coordinate geometry to one N(5), one H(27), and one H(28) atom. The C(21)-N(5) bond length is 1.48 Å. The C(21)-H(27) bond length is 0.99 Å. The C(21)-H(28) bond length is 0.99 Å. In the sixteenth C site, C(23) is bonded in a distorted trigonal non-coplanar geometry to one C(24), one N(5), one H(31), and one H(32) atom. The C(23)-C(24) bond length is 1.52 Å. The C(23)-N(5) bond length is 1.42 Å. The C(23)-H(31) bond length is 0.99 Å. The C(23)-H(32) bond length is 0.99 Å. In the seventeenth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(28) atom. The C(24)-C(25) bond length is 1.36 Å. The C(24)-C(28) bond length is 1.36 Å. In the eighteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(33) atom. The C(25)-H(33) bond length is 0.95 Å. In the nineteenth C site, C(28) is bonded in a distorted single-bond geometry to one C(24) and one H(36) atom. The C(28)-H(36) bond length is 0.95 Å. In the twentieth C site, C(11) is bonded in a 3-coordinate geometry to one C(12), one N(3), one H(15), and one H(16) atom. The C(11)-C(12) bond length is 1.53 Å. The C(11)-N(3) bond length is 1.47 Å. The C(11)-H(15) bond length is 0.99 Å. The C(11)-H(16) bond length is 0.99 Å. In the twenty-first C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.40 Å. In the twenty-second C site, C(13) is bonded in a single-bond geometry to one C(12) and one H(17,20) atom. The C(13)-H(17,20) bond length is 0.95 Å. In the twenty-third C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.39 Å. In the twenty-fourth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(18,19) atom. The C(16)-H(18,19) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(2) is bonded in a trigonal non-coplanar geometry to one C(10), one C(6), and one C(7) atom. In the second N site, N(3) is bonded to one Ag(2), one C(11), one C(8), and one C(9) atom to form corner-sharing NAgC3 tetrahedra. In the third N site, N(4) is bonded to one Ag(2), one C(18), one C(19), and one C(22) atom to form corner-sharing NAgC3 tetrahedra. In the fourth N site, N(5) is bonded in a trigonal non-coplanar geometry to one C(20), one C(21), and one C(23) atom. There are twenty-eight inequivalent H sites. In the first H site, H(5,6) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(7) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(9) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(9) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(10) atom. In the ninth H site, H(14) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. In the eleventh H site, H(15) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(17,20) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth H site, H(18,19) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(22) is bonded in a single-bond geometry to one C(18) atom. In the fifteenth H site, H(21) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(23) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(24) is bonded in a single-bond geometry to one C(19) atom. In the eighteenth H site, H(25) is bonded in a single-bond geometry to one C(20) atom. In the nineteenth H site, H(29,30) is bonded in a single-bond geometry to one C(22) atom. In the twentieth H site, H(26) is bonded in a single-bond geometry to one C(20) atom. In the twenty-first H site, H(27) is bonded in a single-bond geometry to one C(21) atom. In the twenty-second H site, H(28) is bonded in a single-bond geometry to one C(21) atom. In the twenty-third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the twenty-fourth H site, H(31) is bonded in a single-bond geometry to one C(23) atom. In the twenty-fifth H site, H(32) is bonded in a single-bond geometry to one C(23) atom. In the twenty-sixth H site, H(33) is bonded in a single-bond geometry to one C(25) atom. In the twenty-seventh H site, H(36) is bonded in a single-bond geometry to one C(28) atom. In the twenty-eighth H site, H(16) is bonded in a single-bond geometry to one C(11) atom. In each AgH4(C2N)2 cluster, Ag(1) is bonded in a linear geometry to one N(1) and one N(6) atom. The Ag(1)-N(1) bond length is 2.10 Å. The Ag(1)-N(6) bond length is 2.15 Å. There are four inequivalent C sites. In the first C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(34) atom. The C(26)-N(6) bond length is 1.39 Å. The C(26)-H(34) bond length is 0.95 Å. In the second C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(35) atom. The C(27)-N(6) bond length is 1.28 Å. The C(27)-H(35) bond length is 0.95 Å. In the third C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.36 Å. The C(1)-H(1) bond length is 0.95 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ag(1), one C(1), and one C(5) atom. In the second N site, N(6) is bonded in a trigonal planar geometry to one Ag(1), one C(26), and one C(27) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(35) is bonded in a single-bond geometry to one C(27) atom. In the third H site, H(34) is bonded in a single-bond geometry to one C(26) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. Linkers: 4 c1cc(CN2CCN(Cc3ccc(CN4CCN(Cc5ccncc5)CC4)cc3)CC2)ccn1. Metal clusters: 8 [Ag]. The MOF has largest included sphere 4.29 A, density 1.32 g/cm3, surface area 4484.83 m2/g, accessible volume 0.26 cm3/g