Zn7C44H24(NO4)6 crystallizes in the orthorhombic Pna2_1 space group. There are seven inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a distorted T-shaped geometry to one O(12), one O(18), and one O(22) atom. The Zn(1)-O(12) bond length is 2.00 Å. The Zn(1)-O(18) bond length is 2.05 Å. The Zn(1)-O(22) bond length is 2.06 Å. In the second Zn site, Zn(2) is bonded in a tetrahedral geometry to one N(1), one O(1), one O(13), and one O(7) atom. The Zn(2)-N(1) bond length is 2.01 Å. The Zn(2)-O(1) bond length is 1.96 Å. The Zn(2)-O(13) bond length is 1.92 Å. The Zn(2)-O(7) bond length is 2.03 Å. In the third Zn site, Zn(3) is bonded in a tetrahedral geometry to one N(2), one O(2), one O(24), and one O(8) atom. The Zn(3)-N(2) bond length is 2.00 Å. The Zn(3)-O(2) bond length is 2.00 Å. The Zn(3)-O(24) bond length is 1.89 Å. The Zn(3)-O(8) bond length is 1.96 Å. In the fourth Zn site, Zn(4) is bonded in a tetrahedral geometry to one N(5), one O(15), one O(19), and one O(9) atom. The Zn(4)-N(5) bond length is 2.01 Å. The Zn(4)-O(15) bond length is 1.99 Å. The Zn(4)-O(19) bond length is 1.97 Å. The Zn(4)-O(9) bond length is 1.91 Å. In the fifth Zn site, Zn(5) is bonded in a distorted trigonal planar geometry to one O(11), one O(17), and one O(21) atom. The Zn(5)-O(11) bond length is 1.94 Å. The Zn(5)-O(17) bond length is 1.95 Å. The Zn(5)-O(21) bond length is 1.94 Å. In the sixth Zn site, Zn(6) is bonded in a trigonal pyramidal geometry to one N(4), one O(16), one O(20), and one O(5) atom. The Zn(6)-N(4) bond length is 1.99 Å. The Zn(6)-O(16) bond length is 1.94 Å. The Zn(6)-O(20) bond length is 2.01 Å. The Zn(6)-O(5) bond length is 1.90 Å. In the seventh Zn site, Zn(7) is bonded in a distorted trigonal non-coplanar geometry to one N(3), one N(6), and one O(3) atom. The Zn(7)-N(3) bond length is 2.03 Å. The Zn(7)-N(6) bond length is 2.02 Å. The Zn(7)-O(3) bond length is 1.94 Å. There are forty-four inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.42 Å. The C(1)-O(1) bond length is 1.30 Å. The C(1)-O(2) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(9) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(9) bond length is 1.45 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(1) atom. The C(3)-C(4) bond length is 1.37 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.47 Å. The C(4)-C(6) bond length is 1.38 Å. In the fifth C site, C(5) is bonded in a bent 120 degrees geometry to one C(4), one O(3), and one O(4) atom. The C(5)-O(3) bond length is 1.28 Å. The C(5)-O(4) bond length is 1.23 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(4), one C(7), and one H(2) atom. The C(6)-C(7) bond length is 1.40 Å. The C(6)-H(2) bond length is 0.93 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one C(9) atom. The C(7)-C(8) bond length is 1.54 Å. The C(7)-C(9) bond length is 1.35 Å. In the eighth C site, C(8) is bonded in a bent 120 degrees geometry to one C(7), one O(5), and one O(6) atom. The C(8)-O(5) bond length is 1.28 Å. The C(8)-O(6) bond length is 1.20 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(2), one C(7), and one H(3) atom. The C(9)-H(3) bond length is 0.93 Å. In the tenth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(7), and one O(8) atom. The C(10)-C(11) bond length is 1.50 Å. The C(10)-O(7) bond length is 1.22 Å. The C(10)-O(8) bond length is 1.28 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(18) atom. The C(11)-C(12) bond length is 1.39 Å. The C(11)-C(18) bond length is 1.35 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11), one C(13), and one H(4) atom. The C(12)-C(13) bond length is 1.40 Å. The C(12)-H(4) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(15) atom. The C(13)-C(14) bond length is 1.53 Å. The C(13)-C(15) bond length is 1.39 Å. In the fourteenth C site, C(14) is bonded in a bent 120 degrees geometry to one C(13), one O(10), and one O(9) atom. The C(14)-O(10) bond length is 1.21 Å. The C(14)-O(9) bond length is 1.24 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(13), one C(16), and one H(5) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-H(5) bond length is 0.93 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(18) atom. The C(16)-C(17) bond length is 1.53 Å. The C(16)-C(18) bond length is 1.42 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(11), and one O(12) atom. The C(17)-O(11) bond length is 1.28 Å. The C(17)-O(12) bond length is 1.22 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(11), one C(16), and one H(6) atom. The C(18)-H(6) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a bent 120 degrees geometry to one C(20), one O(13), and one O(14) atom. The C(19)-C(20) bond length is 1.50 Å. The C(19)-O(13) bond length is 1.22 Å. The C(19)-O(14) bond length is 1.23 Å. In the twentieth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(27) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-C(27) bond length is 1.34 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(20), one C(22), and one H(7) atom. The C(21)-C(22) bond length is 1.36 Å. The C(21)-H(7) bond length is 0.93 Å. In the twenty-second C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(24) atom. The C(22)-C(23) bond length is 1.50 Å. The C(22)-C(24) bond length is 1.41 Å. In the twenty-third C site, C(23) is bonded in a bent 120 degrees geometry to one C(22), one O(15), and one O(16) atom. The C(23)-O(15) bond length is 1.26 Å. The C(23)-O(16) bond length is 1.24 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(22), one C(25), and one H(8) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-H(8) bond length is 0.93 Å. In the twenty-fifth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(27) atom. The C(25)-C(26) bond length is 1.47 Å. The C(25)-C(27) bond length is 1.40 Å. In the twenty-sixth C site, C(26) is bonded in a bent 120 degrees geometry to one C(25), one O(17), and one O(18) atom. The C(26)-O(17) bond length is 1.23 Å. The C(26)-O(18) bond length is 1.23 Å. In the twenty-seventh C site, C(27) is bonded in a distorted single-bond geometry to one C(20), one C(25), and one H(9) atom. The C(27)-H(9) bond length is 0.93 Å. In the twenty-eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(19), and one O(20) atom. The C(28)-C(29) bond length is 1.50 Å. The C(28)-O(19) bond length is 1.26 Å. The C(28)-O(20) bond length is 1.24 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(28), one C(30), and one C(36) atom. The C(29)-C(30) bond length is 1.40 Å. The C(29)-C(36) bond length is 1.39 Å. In the thirtieth C site, C(30) is bonded in a distorted single-bond geometry to one C(29), one C(31), and one H(10) atom. The C(30)-C(31) bond length is 1.38 Å. The C(30)-H(10) bond length is 0.93 Å. In the thirty-first C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(33) atom. The C(31)-C(32) bond length is 1.50 Å. The C(31)-C(33) bond length is 1.37 Å. In the thirty-second C site, C(32) is bonded in a bent 120 degrees geometry to one C(31), one O(21), and one O(22) atom. The C(32)-O(21) bond length is 1.26 Å. The C(32)-O(22) bond length is 1.22 Å. In the thirty-third C site, C(33) is bonded in a distorted single-bond geometry to one C(31), one C(34), and one H(11) atom. The C(33)-C(34) bond length is 1.39 Å. The C(33)-H(11) bond length is 0.93 Å. In the thirty-fourth C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(36) atom. The C(34)-C(35) bond length is 1.53 Å. The C(34)-C(36) bond length is 1.37 Å. In the thirty-fifth C site, C(35) is bonded in a bent 120 degrees geometry to one C(34), one O(23), and one O(24) atom. The C(35)-O(23) bond length is 1.25 Å. The C(35)-O(24) bond length is 1.25 Å. In the thirty-sixth C site, C(36) is bonded in a distorted single-bond geometry to one C(29), one C(34), and one H(12) atom. The C(36)-H(12) bond length is 0.93 Å. In the thirty-seventh C site, C(37) is bonded in a trigonal non-coplanar geometry to one C(38), one H(13), one H(14), and one H(15) atom. The C(37)-C(38) bond length is 1.52 Å. The C(37)-H(13) bond length is 0.96 Å. The C(37)-H(14) bond length is 0.96 Å. The C(37)-H(15) bond length is 0.96 Å. In the thirty-eighth C site, C(38) is bonded in a trigonal planar geometry to one C(37), one N(1), and one N(3) atom. The C(38)-N(1) bond length is 1.30 Å. The C(38)-N(3) bond length is 1.35 Å. In the thirty-ninth C site, C(39) is bonded in a trigonal planar geometry to one C(40), one N(2), and one N(3) atom. The C(39)-C(40) bond length is 1.43 Å. The C(39)-N(2) bond length is 1.33 Å. The C(39)-N(3) bond length is 1.36 Å. In the fortieth C site, C(40) is bonded in a trigonal non-coplanar geometry to one C(39), one H(16), one H(17), and one H(18) atom. The C(40)-H(16) bond length is 0.96 Å. The C(40)-H(17) bond length is 0.96 Å. The C(40)-H(18) bond length is 0.96 Å. In the forty-first C site, C(41) is bonded in a trigonal non-coplanar geometry to one C(42); one H(19); and two equivalent H(20,21) atoms. The C(41)-C(42) bond length is 1.49 Å. The C(41)-H(19) bond length is 0.96 Å. Both C(41)-H(20,21) bond lengths are 0.96 Å. In the forty-second C site, C(42) is bonded in a trigonal planar geometry to one C(41), one N(4), and one N(6) atom. The C(42)-N(4) bond length is 1.33 Å. The C(42)-N(6) bond length is 1.33 Å. In the forty-third C site, C(43) is bonded in a distorted trigonal planar geometry to one C(44), one N(5), and one N(6) atom. The C(43)-C(44) bond length is 1.47 Å. The C(43)-N(5) bond length is 1.31 Å. The C(43)-N(6) bond length is 1.35 Å. In the forty-fourth C site, C(44) is bonded in a trigonal non-coplanar geometry to one C(43), one H(22), one H(23), and one H(24) atom. The C(44)-H(22) bond length is 0.96 Å. The C(44)-H(23) bond length is 0.96 Å. The C(44)-H(24) bond length is 0.96 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a 3-coordinate geometry to one Zn(2), one C(38), and one N(2) atom. The N(1)-N(2) bond length is 1.40 Å. In the second N site, N(2) is bonded in a 3-coordinate geometry to one Zn(3), one C(39), and one N(1) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(7), one C(38), and one C(39) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one Zn(6), one C(42), and one N(5) atom. The N(4)-N(5) bond length is 1.39 Å. In the fifth N site, N(5) is bonded in a 3-coordinate geometry to one Zn(4), one C(43), and one N(4) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one Zn(7), one C(42), and one C(43) atom. There are twenty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(12) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(24) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(30) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(33) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(36) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(37) atom. In the fourteenth H site, H(14) is bonded in a single-bond geometry to one C(37) atom. In the fifteenth H site, H(15) is bonded in a single-bond geometry to one C(37) atom. In the sixteenth H site, H(16) is bonded in a single-bond geometry to one C(40) atom. In the seventeenth H site, H(17) is bonded in a single-bond geometry to one C(40) atom. In the eighteenth H site, H(18) is bonded in a single-bond geometry to one C(40) atom. In the nineteenth H site, H(19) is bonded in a single-bond geometry to one C(41) atom. In the twentieth H site, H(20,21) is bonded in a single-bond geometry to one C(41) atom. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one C(44) atom. In the twenty-second H site, H(23) is bonded in a single-bond geometry to one C(44) atom. In the twenty-third H site, H(24) is bonded in a single-bond geometry to one C(44) atom. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(1) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Zn(3) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(7) and one C(5) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(8) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one C(8) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Zn(2) and one C(10) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(10) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(14) atom. In the tenth O site, O(10) is bonded in a single-bond geometry to one C(14) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(17) atom. In the twelfth O site, O(12) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(17) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(19) atom. In the fourteenth O site, O(14) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth O site, O(15) is bonded in a bent 150 degrees geometry to one Zn(4) and one C(23) atom. In the sixteenth O site, O(16) is bonded in a bent 120 degrees geometry to one Zn(6) and one C(23) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Zn(5) and one C(26) atom. In the eighteenth O site, O(18) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(26) atom. In the nineteenth O site, O(19) is bonded in a bent 120 degrees geometry to one Zn(4) and one C(28) atom. In the twentieth O site, O(20) is bonded in a bent 150 degrees geometry to one Zn(6) and one C(28) atom. In the twenty-first O site, O(21) is bonded in a bent 120 degrees geometry to one Zn(5) and one C(32) atom. In the twenty-second O site, O(22) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(32) atom. In the twenty-third O site, O(23) is bonded in a single-bond geometry to one C(35) atom. In the twenty-fourth O site, O(24) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(35) atom. Linkers: 4 Cc1nnc(C)n1[Zn](OC(=O)c1cc(C([O])=O)cc(C([O])=O)c1)n1c(C)nnc1C ,11 [O]C(=O)c1cc(C([O])=O)cc(C([O])=O)c1 ,1 [O]C(=O)c1cc([C]=O)cc(C([O])=O)c1. Metal clusters: 4 [C]1O[Zn]2O[C]O[Zn](O1)O[C]O2 ,8 O=[C]O[Zn@]12N=N[Zn@](O[C]=O)(O[C]O1)O[C]O2. The MOF has largest included sphere 9.58 A, density 0.84 g/cm3, surface area 3823.78 m2/g, accessible volume 0.79 cm3/g