(NiC20H30(N3O2)2)2(CH)4(CH2)4C13H12O4 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, sixteen 02329_fluka molecules, four C13H12O4 clusters, and eight NiC20H30(N3O2)2 clusters. In each C13H12O4 cluster, there are seven inequivalent C sites. In the first C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(15), and one O(6) atom. The C(9)-C(10) bond length is 1.38 Å. The C(9)-C(15) bond length is 1.39 Å. The C(9)-O(6) bond length is 1.38 Å. In the second C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(11) atom. The C(10)-H(11) bond length is 0.93 Å. In the third C site, C(15) is bonded in a distorted single-bond geometry to one C(9) and one H(14) atom. The C(15)-H(14) bond length is 0.93 Å. In the fourth C site, C(31) is bonded in a tetrahedral geometry to two equivalent C(1) and two equivalent C(2) atoms. Both C(31)-C(1) bond lengths are 1.54 Å. Both C(31)-C(2) bond lengths are 1.53 Å. In the fifth C site, C(1) is bonded in a distorted trigonal non-coplanar geometry to one C(31); two equivalent H(3,4); and one O(5) atom. Both C(1)-H(3,4) bond lengths are 0.97 Å. The C(1)-O(5) bond length is 1.43 Å. In the sixth C site, C(2) is bonded in a distorted trigonal non-coplanar geometry to one C(31); two equivalent H(5,6); and one O(6) atom. Both C(2)-H(5,6) bond lengths are 0.97 Å. The C(2)-O(6) bond length is 1.43 Å. In the seventh C site, C(3) is bonded in a distorted single-bond geometry to one O(5) atom. The C(3)-O(5) bond length is 1.37 Å. There are four inequivalent H sites. In the first H site, H(3,4) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(5,6) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(11) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(14) is bonded in a single-bond geometry to one C(15) atom. There are two inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one C(1) and one C(3) atom. In the second O site, O(6) is bonded in a bent 120 degrees geometry to one C(2) and one C(9) atom. In four of the NiC20H30(N3O2)2 clusters, Ni(1) is bonded to two equivalent N(5), two equivalent N(6), and two equivalent O(4) atoms to form NiN4O2 octahedra that share corners with two equivalent C(21)H2N2 tetrahedra and corners with two equivalent C(22)H2N2 tetrahedra. Both Ni(1)-N(5) bond lengths are 2.04 Å. Both Ni(1)-N(6) bond lengths are 2.12 Å. Both Ni(1)-O(4) bond lengths are 2.18 Å. There are ten inequivalent C sites. In the first C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(8) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-H(8) bond length is 0.93 Å. In the second C site, C(6) is bonded in a trigonal planar geometry to one C(16), one C(5), and one C(7) atom. The C(6)-C(16) bond length is 1.50 Å. The C(6)-C(7) bond length is 1.39 Å. In the third C site, C(7) is bonded in a distorted single-bond geometry to one C(6) and one H(9) atom. The C(7)-H(9) bond length is 0.93 Å. In the fourth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one C(6), one O(3), and one O(4) atom. The C(16)-O(3) bond length is 1.27 Å. The C(16)-O(4) bond length is 1.26 Å. In the fifth C site, C(17) is bonded in a 3-coordinate geometry to one N(5), one H(15), and one H(16) atom. The C(17)-N(5) bond length is 1.49 Å. The C(17)-H(15) bond length is 0.97 Å. The C(17)-H(16) bond length is 0.97 Å. In the sixth C site, C(18) is bonded in a 3-coordinate geometry to one N(6) and two equivalent H(17,18) atoms. The C(18)-N(6) bond length is 1.49 Å. Both C(18)-H(17,18) bond lengths are 0.97 Å. In the seventh C site, C(19) is bonded in a 3-coordinate geometry to one N(6), one H(19), and one H(20) atom. The C(19)-N(6) bond length is 1.49 Å. The C(19)-H(19) bond length is 0.97 Å. The C(19)-H(20) bond length is 0.97 Å. In the eighth C site, C(21) is bonded to one N(4); one N(6); and two equivalent H(23,24) atoms to form CH2N2 tetrahedra that share  a cornercorner with one Ni(1)N4O2 octahedra and  a cornercorner with one C(22)H2N2 tetrahedra. The corner-sharing octahedral tilt angles are 72°. The C(21)-N(4) bond length is 1.44 Å. The C(21)-N(6) bond length is 1.50 Å. Both C(21)-H(23,24) bond lengths are 0.97 Å. In the ninth C site, C(22) is bonded to one N(4); one N(5); and two equivalent H(25,26) atoms to form CH2N2 tetrahedra that share  a cornercorner with one Ni(1)N4O2 octahedra and  a cornercorner with one C(21)H2N2 tetrahedra. The corner-sharing octahedral tilt angles are 64°. The C(22)-N(4) bond length is 1.44 Å. The C(22)-N(5) bond length is 1.50 Å. Both C(22)-H(25,26) bond lengths are 0.97 Å. In the tenth C site, C(23) is bonded in a 3-coordinate geometry to one N(4) and two equivalent H(27,28) atoms. The C(23)-N(4) bond length is 1.47 Å. Both C(23)-H(27,28) bond lengths are 0.97 Å. There are three inequivalent N sites. In the first N site, N(4) is bonded in a trigonal non-coplanar geometry to one C(21), one C(22), and one C(23) atom. In the second N site, N(5) is bonded to one Ni(1), one C(17), one C(22), and one H(2) atom to form distorted NNiHC2 tetrahedra that share  a cornercorner with one N(5)NiHC2 tetrahedra and corners with two equivalent N(6)NiC3 tetrahedra. The N(5)-H(2) bond length is 0.98 Å. In the third N site, N(6) is bonded to one Ni(1), one C(18), one C(19), and one C(21) atom to form NNiC3 tetrahedra that share  a cornercorner with one N(6)NiC3 tetrahedra and corners with two equivalent N(5)NiHC2 tetrahedra. There are eleven inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one N(5) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(17) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(17,18) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(23,24) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(25,26) is bonded in a single-bond geometry to one C(22) atom. In the eleventh H site, H(27,28) is bonded in a single-bond geometry to one C(23) atom. There are two inequivalent O sites. In the first O site, O(3) is bonded in a single-bond geometry to one C(16) atom. In the second O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Ni(1) and one C(16) atom. In four of the NiC20H30(N3O2)2 clusters, Ni(2) is bonded to two equivalent N(2), two equivalent N(3), and two equivalent O(1) atoms to form NiN4O2 octahedra that share corners with two equivalent C(24)H2N2 tetrahedra and corners with two equivalent C(30)H2N2 tetrahedra. Both Ni(2)-N(2) bond lengths are 2.13 Å. Both Ni(2)-N(3) bond lengths are 2.03 Å. Both Ni(2)-O(1) bond lengths are 2.16 Å. There are ten inequivalent C sites. In the first C site, C(11) is bonded in a distorted single-bond geometry to one C(12) and one H(12) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-H(12) bond length is 0.93 Å. In the second C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.51 Å. The C(12)-C(14) bond length is 1.39 Å. In the third C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(13)-O(1) bond length is 1.26 Å. The C(13)-O(2) bond length is 1.26 Å. In the fourth C site, C(14) is bonded in a distorted single-bond geometry to one C(12) and one H(13) atom. The C(14)-H(13) bond length is 0.93 Å. In the fifth C site, C(24) is bonded to one N(1); one N(2); and two equivalent H(29,30) atoms to form CH2N2 tetrahedra that share  a cornercorner with one Ni(2)N4O2 octahedra and  a cornercorner with one C(30)H2N2 tetrahedra. The corner-sharing octahedral tilt angles are 72°. The C(24)-N(1) bond length is 1.45 Å. The C(24)-N(2) bond length is 1.50 Å. Both C(24)-H(29,30) bond lengths are 0.97 Å. In the sixth C site, C(25) is bonded in a 3-coordinate geometry to one N(1) and two equivalent H(31,32) atoms. The C(25)-N(1) bond length is 1.46 Å. Both C(25)-H(31,32) bond lengths are 0.97 Å. In the seventh C site, C(27) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(35,36) atoms. The C(27)-N(2) bond length is 1.49 Å. Both C(27)-H(35,36) bond lengths are 0.97 Å. In the eighth C site, C(28) is bonded in a 3-coordinate geometry to one N(2), one H(37), and one H(38) atom. The C(28)-N(2) bond length is 1.48 Å. The C(28)-H(37) bond length is 0.97 Å. The C(28)-H(38) bond length is 0.97 Å. In the ninth C site, C(29) is bonded in a 3-coordinate geometry to one N(3) and two equivalent H(39,40) atoms. The C(29)-N(3) bond length is 1.48 Å. Both C(29)-H(39,40) bond lengths are 0.97 Å. In the tenth C site, C(30) is bonded to one N(1); one N(3); and two equivalent H(41,42) atoms to form CH2N2 tetrahedra that share  a cornercorner with one Ni(2)N4O2 octahedra and  a cornercorner with one C(24)H2N2 tetrahedra. The corner-sharing octahedral tilt angles are 64°. The C(30)-N(1) bond length is 1.45 Å. The C(30)-N(3) bond length is 1.49 Å. Both C(30)-H(41,42) bond lengths are 0.97 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal non-coplanar geometry to one C(24), one C(25), and one C(30) atom. In the second N site, N(2) is bonded to one Ni(2), one C(24), one C(27), and one C(28) atom to form NNiC3 tetrahedra that share  a cornercorner with one N(2)NiC3 tetrahedra and corners with two equivalent N(3)NiHC2 tetrahedra. In the third N site, N(3) is bonded to one Ni(2), one C(29), one C(30), and one H(1) atom to form distorted NNiHC2 tetrahedra that share  a cornercorner with one N(3)NiHC2 tetrahedra and corners with two equivalent N(2)NiC3 tetrahedra. The N(3)-H(1) bond length is 0.98 Å. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(3) atom. In the second H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(29,30) is bonded in a single-bond geometry to one C(24) atom. In the fifth H site, H(31,32) is bonded in a single-bond geometry to one C(25) atom. In the sixth H site, H(35,36) is bonded in a single-bond geometry to one C(27) atom. In the seventh H site, H(37) is bonded in a single-bond geometry to one C(28) atom. In the eighth H site, H(38) is bonded in a single-bond geometry to one C(28) atom. In the ninth H site, H(39,40) is bonded in a single-bond geometry to one C(29) atom. In the tenth H site, H(41,42) is bonded in a single-bond geometry to one C(30) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Ni(2) and one C(13) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(13) atom. Linkers: 1 O=C(c1ccc(cc1)OC[C@@](COc1ccc(cc1)C(=O)[O])(COC1=CC=[C]C=C1)COC1=CC=[C]C=C1)O[Ni]123(OC(=O)c4ccc(cc4)OC[C@@](COc4ccc(cc4)C(=O)[O])(COC4=CC=[C]C=C4)COC4=CC=[C]C=C4)[N@@H]4CC[N@]53CCC[N@@](C[N@@H]1CC[N@@]12CCC[N@](C4)C1)C5 ,2 C1C[N@@]2CCNC[N@]3CCC[N@](CCNC[N@@](C1)C2)C3 ,1 O=[C]O[Ni]123(OC(=O)c4ccc(cc4)OC[C@](COc4ccc(cc4)C(=O)O[Ni]456(O[C]=O)[N@@]7C[N]C[N@H]4CC[N@]46CCC[N@@](C[N@@H]5C[CH]7)C4)(COc4ccc(cc4)C(=O)[O])COc4ccc(cc4)C(=O)O[Ni]456(OC(=O)c7ccc(cc7)OCC(COc7ccc(cc7)C(=O)[O])([CH])[CH])[N@@H]7CC[N@]86CCC[N@@](C[N@@H]4CC[N@@]45CCC[N@](C7)C4)C8)[N@@]4C[N]C[N@H]1CC[N@]13CCC[N@@](C[N@@H]2C[CH]4)C1 ,1 O=[C]O[Ni]123(OC(=O)c4ccc(cc4)OC[C@](COc4ccc(cc4)C(=O)O[Ni]456(O[C]=O)[N@]7C[N]C[N@@H]4CC[N@@]46CCC[N@](C[N@H]5C[CH]7)C4)(COc4ccc(cc4)C(=O)[O])COc4ccc(cc4)C(=O)O[Ni]456(OC(=O)c7ccc(cc7)OCC(COc7ccc(cc7)C(=O)[O])([CH])[CH])[N@@H]7CC[N@]86CCC[N@@](C[N@@H]4CC[N@@]45CCC[N@](C7)C4)C8)[N@]4C[N]C[N@@H]1CC[N@@]13CCC[N@](C[N@H]2C[CH]4)C1. Metal clusters: 1 [Ni] ,1 [NH][Ni]([NH])(O[C]=O)O[C]=O. The MOF has largest included sphere 6.65 A, density 1.10 g/cm3, surface area 4549.22 m2/g, accessible volume 0.44 cm3/g