(Mn3C62H52(N2O3)4)2Mn2C17H18(NCl)4MnC17N4H18Cl is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two Mn2C17H18(NCl)4 clusters, four Mn3C62H52(N2O3)4 clusters, and two MnC17N4H18Cl clusters. In each Mn2C17H18(NCl)4 cluster, there are two inequivalent Mn sites. In the first Mn site, Mn(4) is bonded in a distorted T-shaped geometry to two equivalent N(7) and one Cl(2) atom. Both Mn(4)-N(7) bond lengths are 2.28 Å. The Mn(4)-Cl(2) bond length is 2.64 Å. In the second Mn site, Mn(5) is bonded in a tetrahedral geometry to one Cl(2), one Cl(3), and two equivalent Cl(1) atoms. The Mn(5)-Cl(2) bond length is 2.43 Å. The Mn(5)-Cl(3) bond length is 2.36 Å. Both Mn(5)-Cl(1) bond lengths are 2.36 Å. There are nine inequivalent C sites. In the first C site, C(35) is bonded in a distorted trigonal planar geometry to one C(36), one C(38), and one N(8) atom. The C(35)-C(36) bond length is 1.40 Å. The C(35)-C(38) bond length is 1.47 Å. The C(35)-N(8) bond length is 1.37 Å. In the second C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(40) atom. The C(36)-C(37) bond length is 1.41 Å. The C(36)-C(40) bond length is 1.48 Å. In the third C site, C(37) is bonded in a distorted trigonal planar geometry to one C(36), one C(39), and one N(7) atom. The C(37)-C(39) bond length is 1.49 Å. The C(37)-N(7) bond length is 1.34 Å. In the fourth C site, C(38) is bonded in a trigonal non-coplanar geometry to one C(35); one H(33); and two equivalent H(31,32) atoms. The C(38)-H(33) bond length is 0.98 Å. Both C(38)-H(31,32) bond lengths are 0.98 Å. In the fifth C site, C(39) is bonded in a trigonal non-coplanar geometry to one C(37), one H(34), one H(35), and one H(36) atom. The C(39)-H(34) bond length is 0.98 Å. The C(39)-H(35) bond length is 0.98 Å. The C(39)-H(36) bond length is 0.98 Å. In the sixth C site, C(40) is bonded in a trigonal planar geometry to one C(36), one C(41), and one C(45) atom. The C(40)-C(41) bond length is 1.39 Å. The C(40)-C(45) bond length is 1.39 Å. In the seventh C site, C(41) is bonded in a distorted single-bond geometry to one C(40) and one H(37) atom. The C(41)-H(37) bond length is 0.95 Å. In the eighth C site, C(45) is bonded in a distorted single-bond geometry to one C(40) and one H(40) atom. The C(45)-H(40) bond length is 0.95 Å. In the ninth C site, C(79) is bonded in a tetrahedral geometry to two equivalent N(8) and two equivalent H(69,70) atoms. Both C(79)-N(8) bond lengths are 1.45 Å. Both C(79)-H(69,70) bond lengths are 0.99 Å. There are two inequivalent N sites. In the first N site, N(7) is bonded in a distorted trigonal planar geometry to one Mn(4), one C(37), and one N(8) atom. The N(7)-N(8) bond length is 1.37 Å. In the second N site, N(8) is bonded in a distorted trigonal planar geometry to one C(35), one C(79), and one N(7) atom. There are eight inequivalent H sites. In the first H site, H(69,70) is bonded in a single-bond geometry to one C(79) atom. In the second H site, H(31,32) is bonded in a single-bond geometry to one C(38) atom. In the third H site, H(33) is bonded in a single-bond geometry to one C(38) atom. In the fourth H site, H(34) is bonded in a single-bond geometry to one C(39) atom. In the fifth H site, H(35) is bonded in a single-bond geometry to one C(39) atom. In the sixth H site, H(36) is bonded in a single-bond geometry to one C(39) atom. In the seventh H site, H(37) is bonded in a single-bond geometry to one C(41) atom. In the eighth H site, H(40) is bonded in a single-bond geometry to one C(45) atom. There are three inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a single-bond geometry to one Mn(5) atom. In the second Cl site, Cl(2) is bonded in a bent 120 degrees geometry to one Mn(4) and one Mn(5) atom. In the third Cl site, Cl(3) is bonded in a single-bond geometry to one Mn(5) atom. In each Mn3C62H52(N2O3)4 cluster, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one N(1), one N(3), one O(1), one O(2), one O(5), and one O(9) atom. The Mn(1)-N(1) bond length is 2.19 Å. The Mn(1)-N(3) bond length is 2.27 Å. The Mn(1)-O(1) bond length is 2.43 Å. The Mn(1)-O(2) bond length is 2.19 Å. The Mn(1)-O(5) bond length is 2.10 Å. The Mn(1)-O(9) bond length is 2.09 Å. In the second Mn site, Mn(2) is bonded in an octahedral geometry to one O(10), one O(12), one O(2), one O(4), one O(6), and one O(7) atom. The Mn(2)-O(10) bond length is 2.14 Å. The Mn(2)-O(12) bond length is 2.26 Å. The Mn(2)-O(2) bond length is 2.24 Å. The Mn(2)-O(4) bond length is 2.12 Å. The Mn(2)-O(6) bond length is 2.12 Å. The Mn(2)-O(7) bond length is 2.11 Å. In the third Mn site, Mn(3) is bonded in a 6-coordinate geometry to one N(11), one N(9), one O(11), one O(12), one O(3), and one O(8) atom. The Mn(3)-N(11) bond length is 2.22 Å. The Mn(3)-N(9) bond length is 2.27 Å. The Mn(3)-O(11) bond length is 2.56 Å. The Mn(3)-O(12) bond length is 2.18 Å. The Mn(3)-O(3) bond length is 2.08 Å. The Mn(3)-O(8) bond length is 2.08 Å. There are sixty-two inequivalent C sites. In the first C site, C(1) is bonded in a tetrahedral geometry to one N(2), one N(4), one H(1), and one H(2) atom. The C(1)-N(2) bond length is 1.46 Å. The C(1)-N(4) bond length is 1.43 Å. The C(1)-H(1) bond length is 0.99 Å. The C(1)-H(2) bond length is 0.99 Å. In the second C site, C(2) is bonded in a tetrahedral geometry to one N(10); one N(12); and two equivalent H(3,4) atoms. The C(2)-N(10) bond length is 1.45 Å. The C(2)-N(12) bond length is 1.44 Å. Both C(2)-H(3,4) bond lengths are 0.99 Å. In the third C site, C(3) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(2) atom. The C(3)-C(4) bond length is 1.38 Å. The C(3)-C(6) bond length is 1.48 Å. The C(3)-N(2) bond length is 1.35 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(8) atom. The C(4)-C(5) bond length is 1.42 Å. The C(4)-C(8) bond length is 1.46 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(7), and one N(1) atom. The C(5)-C(7) bond length is 1.47 Å. The C(5)-N(1) bond length is 1.35 Å. In the sixth C site, C(6) is bonded in a trigonal non-coplanar geometry to one C(3); one H(7); and two equivalent H(5,6) atoms. The C(6)-H(7) bond length is 0.98 Å. Both C(6)-H(5,6) bond lengths are 0.98 Å. In the seventh C site, C(7) is bonded in a trigonal non-coplanar geometry to one C(5); one H(8); and two equivalent H(9,10) atoms. The C(7)-H(8) bond length is 0.98 Å. Both C(7)-H(9,10) bond lengths are 0.98 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(4), and one C(9) atom. The C(8)-C(13) bond length is 1.41 Å. The C(8)-C(9) bond length is 1.39 Å. In the ninth C site, C(9) is bonded in a single-bond geometry to one C(8) and one H(11) atom. The C(9)-H(11) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(12) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-H(12) bond length is 0.95 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-C(14) bond length is 1.48 Å. In the twelfth C site, C(12) is bonded in a single-bond geometry to one C(11) and one H(13) atom. The C(12)-H(13) bond length is 0.95 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(14) atom. The C(13)-H(14) bond length is 0.95 Å. In the fourteenth C site, C(14) is bonded in a bent 120 degrees geometry to one C(11), one O(1), and one O(2) atom. The C(14)-O(1) bond length is 1.26 Å. The C(14)-O(2) bond length is 1.28 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one C(18), and one N(4) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-C(18) bond length is 1.48 Å. The C(15)-N(4) bond length is 1.36 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(20) atom. The C(16)-C(17) bond length is 1.42 Å. The C(16)-C(20) bond length is 1.47 Å. In the seventeenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(19), and one N(3) atom. The C(17)-C(19) bond length is 1.49 Å. The C(17)-N(3) bond length is 1.34 Å. In the eighteenth C site, C(18) is bonded in a trigonal non-coplanar geometry to one C(15); one H(15); and two equivalent H(16,17) atoms. The C(18)-H(15) bond length is 0.98 Å. Both C(18)-H(16,17) bond lengths are 0.98 Å. In the nineteenth C site, C(19) is bonded in a trigonal non-coplanar geometry to one C(17) and three equivalent H(18,19,20,41,42,43) atoms. All C(19)-H(18,19,20,41,42,43) bond lengths are 0.98 Å. In the twentieth C site, C(20) is bonded in a 5-coordinate geometry to one C(16), one C(71), one C(74), one C(75), and one C(78) atom. The C(20)-C(71) bond length is 1.38 Å. The C(20)-C(74) bond length is 1.42 Å. The C(20)-C(75) bond length is 1.37 Å. The C(20)-C(78) bond length is 1.36 Å. In the twenty-first C site, C(21) is bonded in a 5-coordinate geometry to one C(22), one C(72), one C(73), one C(76), and one C(77) atom. The C(21)-C(22) bond length is 1.49 Å. The C(21)-C(72) bond length is 1.39 Å. The C(21)-C(73) bond length is 1.36 Å. The C(21)-C(76) bond length is 1.42 Å. The C(21)-C(77) bond length is 1.40 Å. In the twenty-second C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(3), and one O(4) atom. The C(22)-O(3) bond length is 1.25 Å. The C(22)-O(4) bond length is 1.23 Å. In the twenty-third C site, C(30) is bonded in a distorted single-bond geometry to one C(31) and one H(28) atom. The C(30)-C(31) bond length is 1.42 Å. The C(30)-H(28) bond length is 0.95 Å. In the twenty-fourth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(34) atom. The C(31)-C(32) bond length is 1.35 Å. The C(31)-C(34) bond length is 1.50 Å. In the twenty-fifth C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(29) atom. The C(32)-H(29) bond length is 0.95 Å. In the twenty-sixth C site, C(34) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(5), and one O(6) atom. The C(34)-O(5) bond length is 1.26 Å. The C(34)-O(6) bond length is 1.23 Å. In the twenty-seventh C site, C(42) is bonded in a distorted single-bond geometry to one C(43) and one H(38) atom. The C(42)-C(43) bond length is 1.40 Å. The C(42)-H(38) bond length is 0.95 Å. In the twenty-eighth C site, C(43) is bonded in a trigonal planar geometry to one C(42), one C(44), and one C(46) atom. The C(43)-C(44) bond length is 1.41 Å. The C(43)-C(46) bond length is 1.49 Å. In the twenty-ninth C site, C(44) is bonded in a distorted single-bond geometry to one C(43) and one H(39) atom. The C(44)-H(39) bond length is 0.95 Å. In the thirtieth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one C(43), one O(7), and one O(8) atom. The C(46)-O(7) bond length is 1.25 Å. The C(46)-O(8) bond length is 1.26 Å. In the thirty-first C site, C(47) is bonded in a distorted trigonal planar geometry to one C(48), one C(50), and one N(10) atom. The C(47)-C(48) bond length is 1.39 Å. The C(47)-C(50) bond length is 1.50 Å. The C(47)-N(10) bond length is 1.34 Å. In the thirty-second C site, C(48) is bonded in a trigonal planar geometry to one C(47), one C(49), and one C(52) atom. The C(48)-C(49) bond length is 1.42 Å. The C(48)-C(52) bond length is 1.47 Å. In the thirty-third C site, C(49) is bonded in a 3-coordinate geometry to one C(48), one C(51), and one N(9) atom. The C(49)-C(51) bond length is 1.49 Å. The C(49)-N(9) bond length is 1.33 Å. In the thirty-fourth C site, C(50) is bonded in a trigonal non-coplanar geometry to one C(47) and three equivalent H(18,19,20,41,42,43) atoms. All C(50)-H(18,19,20,41,42,43) bond lengths are 0.98 Å. In the thirty-fifth C site, C(51) is bonded in a trigonal non-coplanar geometry to one C(49); one H(45); and two equivalent H(44,46) atoms. The C(51)-H(45) bond length is 0.98 Å. Both C(51)-H(44,46) bond lengths are 0.98 Å. In the thirty-sixth C site, C(52) is bonded in a trigonal planar geometry to one C(48), one C(53), and one C(57) atom. The C(52)-C(53) bond length is 1.41 Å. The C(52)-C(57) bond length is 1.41 Å. In the thirty-seventh C site, C(53) is bonded in a distorted single-bond geometry to one C(52) and one H(47) atom. The C(53)-H(47) bond length is 0.95 Å. In the thirty-eighth C site, C(54) is bonded in a distorted single-bond geometry to one C(55) and one H(48) atom. The C(54)-C(55) bond length is 1.39 Å. The C(54)-H(48) bond length is 0.95 Å. In the thirty-ninth C site, C(55) is bonded in a trigonal planar geometry to one C(54), one C(56), and one C(58) atom. The C(55)-C(56) bond length is 1.40 Å. The C(55)-C(58) bond length is 1.49 Å. In the fortieth C site, C(56) is bonded in a distorted single-bond geometry to one C(55) and one H(49) atom. The C(56)-H(49) bond length is 0.95 Å. In the forty-first C site, C(57) is bonded in a distorted single-bond geometry to one C(52) and one H(50) atom. The C(57)-H(50) bond length is 0.95 Å. In the forty-second C site, C(58) is bonded in a distorted bent 120 degrees geometry to one C(55), one O(10), and one O(9) atom. The C(58)-O(10) bond length is 1.25 Å. The C(58)-O(9) bond length is 1.26 Å. In the forty-third C site, C(59) is bonded in a distorted trigonal planar geometry to one C(60), one C(62), and one N(12) atom. The C(59)-C(60) bond length is 1.39 Å. The C(59)-C(62) bond length is 1.50 Å. The C(59)-N(12) bond length is 1.35 Å. In the forty-fourth C site, C(60) is bonded in a trigonal planar geometry to one C(59), one C(61), and one C(64) atom. The C(60)-C(61) bond length is 1.42 Å. The C(60)-C(64) bond length is 1.46 Å. In the forty-fifth C site, C(61) is bonded in a distorted trigonal planar geometry to one C(60), one C(63), and one N(11) atom. The C(61)-C(63) bond length is 1.49 Å. The C(61)-N(11) bond length is 1.34 Å. In the forty-sixth C site, C(62) is bonded in a trigonal non-coplanar geometry to one C(59) and three equivalent H(51,52,53) atoms. All C(62)-H(51,52,53) bond lengths are 0.98 Å. In the forty-seventh C site, C(63) is bonded in a trigonal non-coplanar geometry to one C(61) and three equivalent H(54,55,56) atoms. All C(63)-H(54,55,56) bond lengths are 0.98 Å. In the forty-eighth C site, C(64) is bonded in a trigonal planar geometry to one C(60), one C(65), and one C(69) atom. The C(64)-C(65) bond length is 1.40 Å. The C(64)-C(69) bond length is 1.39 Å. In the forty-ninth C site, C(65) is bonded in a distorted single-bond geometry to one C(64) and one H(57) atom. The C(65)-H(57) bond length is 0.95 Å. In the fiftieth C site, C(66) is bonded in a distorted single-bond geometry to one C(67) and one H(58) atom. The C(66)-C(67) bond length is 1.40 Å. The C(66)-H(58) bond length is 0.95 Å. In the fifty-first C site, C(67) is bonded in a trigonal planar geometry to one C(66), one C(68), and one C(70) atom. The C(67)-C(68) bond length is 1.39 Å. The C(67)-C(70) bond length is 1.48 Å. In the fifty-second C site, C(68) is bonded in a single-bond geometry to one C(67) and one H(59) atom. The C(68)-H(59) bond length is 0.95 Å. In the fifty-third C site, C(69) is bonded in a distorted single-bond geometry to one C(64) and one H(60) atom. The C(69)-H(60) bond length is 0.95 Å. In the fifty-fourth C site, C(70) is bonded in a distorted bent 120 degrees geometry to one C(67), one O(11), and one O(12) atom. The C(70)-O(11) bond length is 1.27 Å. The C(70)-O(12) bond length is 1.28 Å. In the fifty-fifth C site, C(71) is bonded in a distorted single-bond geometry to one C(20) and one H(61) atom. The C(71)-H(61) bond length is 0.95 Å. In the fifty-sixth C site, C(72) is bonded in a distorted single-bond geometry to one C(21) and one H(62) atom. The C(72)-H(62) bond length is 0.95 Å. In the fifty-seventh C site, C(73) is bonded in a distorted single-bond geometry to one C(21) and one H(63) atom. The C(73)-H(63) bond length is 0.95 Å. In the fifty-eighth C site, C(74) is bonded in a distorted single-bond geometry to one C(20) and one H(64) atom. The C(74)-H(64) bond length is 0.95 Å. In the fifty-ninth C site, C(75) is bonded in a distorted single-bond geometry to one C(20) and one H(65) atom. The C(75)-H(65) bond length is 0.95 Å. In the sixtieth C site, C(76) is bonded in a distorted single-bond geometry to one C(21) and one H(66) atom. The C(76)-H(66) bond length is 0.95 Å. In the sixty-first C site, C(77) is bonded in a distorted single-bond geometry to one C(21) and one H(67) atom. The C(77)-H(67) bond length is 0.95 Å. In the sixty-second C site, C(78) is bonded in a distorted single-bond geometry to one C(20) and one H(68) atom. The C(78)-H(68) bond length is 0.95 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(5), and one N(2) atom. The N(1)-N(2) bond length is 1.37 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(1) atom. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(17), and one N(4) atom. The N(3)-N(4) bond length is 1.36 Å. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one C(1), one C(15), and one N(3) atom. In the fifth N site, N(9) is bonded in a 3-coordinate geometry to one Mn(3), one C(49), and one N(10) atom. The N(9)-N(10) bond length is 1.37 Å. In the sixth N site, N(10) is bonded in a 3-coordinate geometry to one C(2), one C(47), and one N(9) atom. In the seventh N site, N(11) is bonded in a distorted trigonal planar geometry to one Mn(3), one C(61), and one N(12) atom. The N(11)-N(12) bond length is 1.37 Å. In the eighth N site, N(12) is bonded in a 3-coordinate geometry to one C(2), one C(59), and one N(11) atom. There are thirty-eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3,4) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5,6) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(7) atom. In the seventh H site, H(9,10) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the ninth H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the tenth H site, H(13) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(14) is bonded in a single-bond geometry to one C(13) atom. In the twelfth H site, H(15) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(16,17) is bonded in a single-bond geometry to one C(18) atom. In the fourteenth H site, H(18,19,20,41,42,43) is bonded in a single-bond geometry to one C(19) atom. In the fifteenth H site, H(28) is bonded in a single-bond geometry to one C(30) atom. In the sixteenth H site, H(29) is bonded in a single-bond geometry to one C(32) atom. In the seventeenth H site, H(38) is bonded in a single-bond geometry to one C(42) atom. In the eighteenth H site, H(39) is bonded in a single-bond geometry to one C(44) atom. In the nineteenth H site, H(44,46) is bonded in a single-bond geometry to one C(51) atom. In the twentieth H site, H(45) is bonded in a single-bond geometry to one C(51) atom. In the twenty-first H site, H(47) is bonded in a single-bond geometry to one C(53) atom. In the twenty-second H site, H(48) is bonded in a single-bond geometry to one C(54) atom. In the twenty-third H site, H(49) is bonded in a single-bond geometry to one C(56) atom. In the twenty-fourth H site, H(50) is bonded in a single-bond geometry to one C(57) atom. In the twenty-fifth H site, H(51,52,53) is bonded in a single-bond geometry to one C(62) atom. In the twenty-sixth H site, H(54,55,56) is bonded in a single-bond geometry to one C(63) atom. In the twenty-seventh H site, H(57) is bonded in a single-bond geometry to one C(65) atom. In the twenty-eighth H site, H(58) is bonded in a single-bond geometry to one C(66) atom. In the twenty-ninth H site, H(59) is bonded in a single-bond geometry to one C(68) atom. In the thirtieth H site, H(60) is bonded in a single-bond geometry to one C(69) atom. In the thirty-first H site, H(61) is bonded in a single-bond geometry to one C(71) atom. In the thirty-second H site, H(62) is bonded in a single-bond geometry to one C(72) atom. In the thirty-third H site, H(63) is bonded in a single-bond geometry to one C(73) atom. In the thirty-fourth H site, H(64) is bonded in a single-bond geometry to one C(74) atom. In the thirty-fifth H site, H(65) is bonded in a single-bond geometry to one C(75) atom. In the thirty-sixth H site, H(66) is bonded in a single-bond geometry to one C(76) atom. In the thirty-seventh H site, H(67) is bonded in a single-bond geometry to one C(77) atom. In the thirty-eighth H site, H(68) is bonded in a single-bond geometry to one C(78) atom. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted single-bond geometry to one Mn(1) and one C(14) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to one Mn(1), one Mn(2), and one C(14) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(22) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Mn(2) and one C(22) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(34) atom. In the sixth O site, O(6) is bonded in a distorted bent 150 degrees geometry to one Mn(2) and one C(34) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Mn(2) and one C(46) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(46) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(58) atom. In the tenth O site, O(10) is bonded in a distorted bent 150 degrees geometry to one Mn(2) and one C(58) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Mn(3) and one C(70) atom. In the twelfth O site, O(12) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one Mn(3), and one C(70) atom. In each MnC17N4H18Cl cluster, Mn(6) is bonded in a 3-coordinate geometry to two equivalent N(5) and one Cl(4) atom. Both Mn(6)-N(5) bond lengths are 2.26 Å. The Mn(6)-Cl(4) bond length is 2.46 Å. There are nine inequivalent C sites. In the first C site, C(23) is bonded in a distorted trigonal planar geometry to one C(24), one C(26), and one N(6) atom. The C(23)-C(24) bond length is 1.38 Å. The C(23)-C(26) bond length is 1.49 Å. The C(23)-N(6) bond length is 1.37 Å. In the second C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(28) atom. The C(24)-C(25) bond length is 1.42 Å. The C(24)-C(28) bond length is 1.48 Å. In the third C site, C(25) is bonded in a distorted trigonal planar geometry to one C(24), one C(27), and one N(5) atom. The C(25)-C(27) bond length is 1.49 Å. The C(25)-N(5) bond length is 1.34 Å. In the fourth C site, C(26) is bonded in a trigonal non-coplanar geometry to one C(23); one H(21); and two equivalent H(22,23) atoms. The C(26)-H(21) bond length is 0.98 Å. Both C(26)-H(22,23) bond lengths are 0.98 Å. In the fifth C site, C(27) is bonded in a trigonal non-coplanar geometry to one C(25), one H(24), one H(25), and one H(26) atom. The C(27)-H(24) bond length is 0.98 Å. The C(27)-H(25) bond length is 0.98 Å. The C(27)-H(26) bond length is 0.98 Å. In the sixth C site, C(28) is bonded in a trigonal planar geometry to one C(24), one C(29), and one C(33) atom. The C(28)-C(29) bond length is 1.38 Å. The C(28)-C(33) bond length is 1.35 Å. In the seventh C site, C(29) is bonded in a distorted single-bond geometry to one C(28) and one H(27) atom. The C(29)-H(27) bond length is 0.95 Å. In the eighth C site, C(33) is bonded in a distorted single-bond geometry to one C(28) and one H(30) atom. The C(33)-H(30) bond length is 0.95 Å. In the ninth C site, C(80) is bonded in a tetrahedral geometry to two equivalent N(6) and two equivalent H(71,72) atoms. Both C(80)-N(6) bond lengths are 1.46 Å. Both C(80)-H(71,72) bond lengths are 0.99 Å. There are two inequivalent N sites. In the first N site, N(5) is bonded in a distorted trigonal planar geometry to one Mn(6), one C(25), and one N(6) atom. The N(5)-N(6) bond length is 1.35 Å. In the second N site, N(6) is bonded in a distorted trigonal planar geometry to one C(23), one C(80), and one N(5) atom. There are eight inequivalent H sites. In the first H site, H(71,72) is bonded in a single-bond geometry to one C(80) atom. In the second H site, H(21) is bonded in a single-bond geometry to one C(26) atom. In the third H site, H(22,23) is bonded in a single-bond geometry to one C(26) atom. In the fourth H site, H(24) is bonded in a single-bond geometry to one C(27) atom. In the fifth H site, H(25) is bonded in a single-bond geometry to one C(27) atom. In the sixth H site, H(26) is bonded in a single-bond geometry to one C(27) atom. In the seventh H site, H(27) is bonded in a single-bond geometry to one C(29) atom. In the eighth H site, H(30) is bonded in a single-bond geometry to one C(33) atom. Cl(4) is bonded in a single-bond geometry to one Mn(6) atom. Linkers: 6 Cc1nn(Cn2nc(C)c(-c3ccc(C([O])=O)cc3)c2C)c(C)c1-c1ccc(C([O])=O)cc1 ,2 Cc1[c]c(C)n(Cn2nc(C)c(-c3ccc(C([O])=O)cc3)c2C)n1.[C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@H]4[C@@H]5[C@H]([C@H]41)C235.[O][C]=O ,2 Cc1[c]c(C)n(Cn2nc(C)c(-c3ccc(C([O])=O)cc3)c2C)n1.[C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@@H]4[C@H]5[C@@H]([C@@H]41)C235.[O][C]=O ,2 C[C]1C(c2ccc(C([O])=O)cc2)=C(C)N2N1CN1[C](C)C(c3ccc(C([O])=O)cc3)=C(C)N1[Mn]2Cl. Metal clusters: 4 O=[C]O[Mn]1O[C]O[Mn]2(O[C]O1)O[C]O[Mn]1(O[C]O2)O[C]O1 ,2 Cl[Mn](Cl)(Cl)Cl.[Mn]. RCSR code: sql. The MOF has largest included sphere 7.51 A, density 1.08 g/cm3, surface area 4579.48 m2/g, accessible volume 0.47 cm3/g