Zn6C24H12O13(C10H7)2 is Indium-derived structured and crystallizes in the cubic Ia-3 space group. The structure is zero-dimensional and consists of sixteen 2,4-dimethyl-3-prop-1-en-2-ylpenta-1,4-diene molecules and eight Zn6C24H12O13 clusters. In each Zn6C24H12O13 cluster, Zn(1) is bonded in a 4-coordinate geometry to one O(1), one O(3), and two equivalent O(2) atoms. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(3) bond length is 1.96 Å. There is one shorter (2.02 Å) and one longer (2.19 Å) Zn(1)-O(2) bond length. There are four inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.50 Å. The C(1)-O(1) bond length is 1.23 Å. The C(1)-O(2) bond length is 1.20 Å. In the second C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1,4) atom. The C(3)-C(2) bond length is 1.39 Å. The C(3)-H(1,4) bond length is 0.93 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(7) bond length is 1.39 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(1,4) atom. The C(7)-H(1,4) bond length is 0.93 Å. H(1,4) is bonded in a single-bond geometry to one C(3) atom. There are three inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(1) atom. In the second O site, O(2) is bonded in a 3-coordinate geometry to two equivalent Zn(1) and one C(1) atom. In the third O site, O(3) is bonded in a distorted hexagonal planar geometry to six equivalent Zn(1) atoms. Linkers: 16 [O]C(=O)c1ccc(C(c2ccc(C([O])=O)cc2)c2ccc(C([O])=O)cc2)cc1. Metal clusters: 3 [C]1O[Zn]23O[C]O[Zn@]45O[C]O[Zn@@]6(O1)[Zn]41O[C]O[Zn]264O[C]O[Zn]35(O[C]O1)O4 ,3 [C]1O[Zn@]23O[C]O[Zn]456O[C]O[Zn@@]7(O1)[Zn@@]21O[C]O[Zn@@]34O[C]O[Zn]75(O[C]O1)O6 ,2 [C]1O[Zn]23O[C]O[Zn@@]45O[C]O[Zn@]6(O1)[Zn]41O[C]O[Zn]264O[C]O[Zn]35(O[C]O1)O4. RCSR code: pyr. The MOF has largest included sphere 5.29 A, density 1.34 g/cm3, surface area 3441.30 m2/g, accessible volume 0.42 cm3/g