CuH8(C2N)4(C5H3)4 is Indium-derived structured and crystallizes in the cubic Pm-3 space group. The structure is zero-dimensional and consists of eight 1,3,5-triisopropenyl benzene molecules and six CuH8(C2N)4 clusters. In each CuH8(C2N)4 cluster, Cu(1) is bonded in a rectangular see-saw-like geometry to four equivalent N(1) atoms. All Cu(1)-N(1) bond lengths are 1.99 Å. There are two inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.39 Å. The C(5)-H(4) bond length is 0.93 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.39 Å. The C(1)-H(1) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. There are two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. Linkers: 8 c1cc(-c2cc(-c3ccncc3)cc(-c3ccncc3)c2)ccn1. Metal clusters: 6 [Cu]. The MOF has largest included sphere 16.16 A, density 0.50 g/cm3, surface area 5062.06 m2/g, accessible volume 1.40 cm3/g