TbH12(C2O)12(CH)14(C29N7H23)2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twenty-eight 02329_fluka molecules, four C29N7H23 clusters, and two TbH12(C2O)12 clusters. In each C29N7H23 cluster, there are twenty-nine inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(15), one C(4), and one N(2) atom. The C(1)-C(15) bond length is 1.39 Å. The C(1)-C(4) bond length is 1.40 Å. The C(1)-N(2) bond length is 1.39 Å. In the second C site, C(2) is bonded in a 3-coordinate geometry to one C(14), one N(1), one H(18), and one H(35) atom. The C(2)-C(14) bond length is 1.48 Å. The C(2)-N(1) bond length is 1.49 Å. The C(2)-H(18) bond length is 0.82 Å. The C(2)-H(35) bond length is 1.15 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(8) and one H(1) atom. The C(3)-C(8) bond length is 1.37 Å. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a 3-coordinate geometry to one C(8), one N(3), one H(19), and one H(23) atom. The C(5)-C(8) bond length is 1.52 Å. The C(5)-N(3) bond length is 1.47 Å. The C(5)-H(19) bond length is 0.97 Å. The C(5)-H(23) bond length is 0.91 Å. In the fifth C site, C(4) is bonded in a distorted single-bond geometry to one C(1), one C(6), and one N(3) atom. The C(4)-C(6) bond length is 1.38 Å. The C(4)-N(3) bond length is 1.39 Å. In the sixth C site, C(8) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(5) atom. The C(8)-C(11) bond length is 1.36 Å. In the seventh C site, C(6) is bonded in a distorted single-bond geometry to one C(4) and one H(32) atom. The C(6)-H(32) bond length is 0.91 Å. In the eighth C site, C(11) is bonded in a distorted single-bond geometry to one C(8) and one H(4) atom. The C(11)-H(4) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a 3-coordinate geometry to one C(19), one N(1), one H(2), and one H(3) atom. The C(9)-C(19) bond length is 1.49 Å. The C(9)-N(1) bond length is 1.50 Å. The C(9)-H(2) bond length is 0.97 Å. The C(9)-H(3) bond length is 0.97 Å. In the tenth C site, C(13) is bonded in a 3-coordinate geometry to one C(23); one N(1); and two equivalent H(5,6) atoms. The C(13)-C(23) bond length is 1.50 Å. The C(13)-N(1) bond length is 1.47 Å. Both C(13)-H(5,6) bond lengths are 0.97 Å. In the eleventh C site, C(14) is bonded in a distorted trigonal planar geometry to one C(2), one N(2), and one N(3) atom. The C(14)-N(2) bond length is 1.32 Å. The C(14)-N(3) bond length is 1.35 Å. In the twelfth C site, C(15) is bonded in a distorted single-bond geometry to one C(1) and one H(15) atom. The C(15)-H(15) bond length is 0.99 Å. In the thirteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(9), one N(4), and one N(5) atom. The C(19)-N(4) bond length is 1.35 Å. The C(19)-N(5) bond length is 1.31 Å. In the fourteenth C site, C(20) is bonded in a trigonal planar geometry to one C(24), one C(25), and one C(33) atom. The C(20)-C(24) bond length is 1.38 Å. The C(20)-C(25) bond length is 1.52 Å. The C(20)-C(33) bond length is 1.40 Å. In the fifteenth C site, C(21) is bonded in a trigonal planar geometry to one C(36), one C(42), and one C(45) atom. The C(21)-C(36) bond length is 1.39 Å. The C(21)-C(42) bond length is 1.37 Å. The C(21)-C(45) bond length is 1.51 Å. In the sixteenth C site, C(23) is bonded in a distorted trigonal planar geometry to one C(13), one N(6), and one N(7) atom. The C(23)-N(6) bond length is 1.36 Å. The C(23)-N(7) bond length is 1.32 Å. In the seventeenth C site, C(24) is bonded in a single-bond geometry to one C(20) and one H(27) atom. The C(24)-H(27) bond length is 0.80 Å. In the eighteenth C site, C(25) is bonded in a 3-coordinate geometry to one C(20), one N(6), one H(20), and one H(24) atom. The C(25)-N(6) bond length is 1.46 Å. The C(25)-H(20) bond length is 0.99 Å. The C(25)-H(24) bond length is 1.05 Å. In the nineteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(27), one C(43), and one N(7) atom. The C(26)-C(27) bond length is 1.40 Å. The C(26)-C(43) bond length is 1.39 Å. The C(26)-N(7) bond length is 1.40 Å. In the twentieth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one N(6) atom. The C(27)-N(6) bond length is 1.38 Å. In the twenty-first C site, C(30) is bonded in a distorted single-bond geometry to one C(31), one C(39), and one N(5) atom. The C(30)-C(31) bond length is 1.39 Å. The C(30)-C(39) bond length is 1.39 Å. The C(30)-N(5) bond length is 1.39 Å. In the twenty-second C site, C(31) is bonded in a distorted single-bond geometry to one C(30), one C(38), and one N(4) atom. The C(31)-C(38) bond length is 1.40 Å. The C(31)-N(4) bond length is 1.39 Å. In the twenty-third C site, C(33) is bonded in a distorted single-bond geometry to one C(20) and one H(17) atom. The C(33)-H(17) bond length is 0.99 Å. In the twenty-fourth C site, C(36) is bonded in a single-bond geometry to one C(21) and one H(30) atom. The C(36)-H(30) bond length is 0.88 Å. In the twenty-fifth C site, C(38) is bonded in a distorted single-bond geometry to one C(31) and one H(22) atom. The C(38)-H(22) bond length is 0.94 Å. In the twenty-sixth C site, C(39) is bonded in a single-bond geometry to one C(30) and one H(9) atom. The C(39)-H(9) bond length is 0.93 Å. In the twenty-seventh C site, C(42) is bonded in a distorted single-bond geometry to one C(21) and one H(11) atom. The C(42)-H(11) bond length is 0.93 Å. In the twenty-eighth C site, C(43) is bonded in a distorted single-bond geometry to one C(26) and one H(26) atom. The C(43)-H(26) bond length is 0.89 Å. In the twenty-ninth C site, C(45) is bonded in a 3-coordinate geometry to one C(21); one N(4); and two equivalent H(12,13) atoms. The C(45)-N(4) bond length is 1.47 Å. Both C(45)-H(12,13) bond lengths are 0.97 Å. There are seven inequivalent N sites. In the first N site, N(1) is bonded in a trigonal non-coplanar geometry to one C(13), one C(2), and one C(9) atom. In the second N site, N(2) is bonded in a water-like geometry to one C(1) and one C(14) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(14), one C(4), and one C(5) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(19), one C(31), and one C(45) atom. In the fifth N site, N(5) is bonded in a water-like geometry to one C(19) and one C(30) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(27) atom. In the seventh N site, N(7) is bonded in a water-like geometry to one C(23) and one C(26) atom. There are twenty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(39) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(42) atom. In the eighth H site, H(12,13) is bonded in a single-bond geometry to one C(45) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(5) atom. In the eleventh H site, H(23) is bonded in a single-bond geometry to one C(5) atom. In the twelfth H site, H(18) is bonded in a single-bond geometry to one C(2) atom. In the thirteenth H site, H(27) is bonded in a single-bond geometry to one C(24) atom. In the fourteenth H site, H(30) is bonded in a single-bond geometry to one C(36) atom. In the fifteenth H site, H(32) is bonded in a single-bond geometry to one C(6) atom. In the sixteenth H site, H(26) is bonded in a single-bond geometry to one C(43) atom. In the seventeenth H site, H(35) is bonded in a single-bond geometry to one C(2) atom. In the eighteenth H site, H(17) is bonded in a single-bond geometry to one C(33) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(25) atom. In the twentieth H site, H(22) is bonded in a single-bond geometry to one C(38) atom. In the twenty-first H site, H(24) is bonded in a single-bond geometry to one C(25) atom. In each TbH12(C2O)12 cluster, Tb(1) is bonded in an octahedral geometry to two equivalent O(2), two equivalent O(5), and two equivalent O(6) atoms. Both Tb(1)-O(2) bond lengths are 2.26 Å. Both Tb(1)-O(5) bond lengths are 2.25 Å. Both Tb(1)-O(6) bond lengths are 2.23 Å. There are twelve inequivalent C sites. In the first C site, C(12) is bonded in a single-bond geometry to one C(16) and one H(34) atom. The C(12)-C(16) bond length is 1.37 Å. The C(12)-H(34) bond length is 0.83 Å. In the second C site, C(16) is bonded in a trigonal planar geometry to one C(12), one C(17), and one C(18) atom. The C(16)-C(17) bond length is 1.51 Å. The C(16)-C(18) bond length is 1.37 Å. In the third C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(1), and one O(2) atom. The C(17)-O(1) bond length is 1.25 Å. The C(17)-O(2) bond length is 1.24 Å. In the fourth C site, C(18) is bonded in a distorted single-bond geometry to one C(16) and one H(36) atom. The C(18)-H(36) bond length is 1.07 Å. In the fifth C site, C(22) is bonded in a trigonal planar geometry to one C(29), one C(32), and one C(48) atom. The C(22)-C(29) bond length is 1.38 Å. The C(22)-C(32) bond length is 1.39 Å. The C(22)-C(48) bond length is 1.49 Å. In the sixth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(35), one O(3), and one O(6) atom. The C(28)-C(35) bond length is 1.49 Å. The C(28)-O(3) bond length is 1.24 Å. The C(28)-O(6) bond length is 1.24 Å. In the seventh C site, C(29) is bonded in a distorted single-bond geometry to one C(22) and one H(7) atom. The C(29)-H(7) bond length is 0.93 Å. In the eighth C site, C(32) is bonded in a distorted single-bond geometry to one C(22) and one H(31) atom. The C(32)-H(31) bond length is 1.04 Å. In the ninth C site, C(35) is bonded in a trigonal planar geometry to one C(28), one C(37), and one C(44) atom. The C(35)-C(37) bond length is 1.38 Å. The C(35)-C(44) bond length is 1.38 Å. In the tenth C site, C(37) is bonded in a distorted single-bond geometry to one C(35) and one H(8) atom. The C(37)-H(8) bond length is 0.93 Å. In the eleventh C site, C(44) is bonded in a distorted single-bond geometry to one C(35) and one H(25) atom. The C(44)-H(25) bond length is 1.07 Å. In the twelfth C site, C(48) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(4), and one O(5) atom. The C(48)-O(4) bond length is 1.25 Å. The C(48)-O(5) bond length is 1.26 Å. There are six inequivalent H sites. In the first H site, H(7) is bonded in a single-bond geometry to one C(29) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(37) atom. In the third H site, H(25) is bonded in a single-bond geometry to one C(44) atom. In the fourth H site, H(31) is bonded in a single-bond geometry to one C(32) atom. In the fifth H site, H(34) is bonded in a single-bond geometry to one C(12) atom. In the sixth H site, H(36) is bonded in a single-bond geometry to one C(18) atom. There are six inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(17) atom. In the second O site, O(2) is bonded in a linear geometry to one Tb(1) and one C(17) atom. In the third O site, O(3) is bonded in a single-bond geometry to one C(28) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(48) atom. In the fifth O site, O(5) is bonded in a bent 150 degrees geometry to one Tb(1) and one C(48) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Tb(1) and one C(28) atom. Linkers: 2 [O]C(=O)c1ccc(Cn2c(CN(Cc3nc4ccccc4n3Cc3ccc(C([O])=O)cc3)Cc3nc4ccccc4n3Cc3ccc(C([O])=O)cc3)nc3ccccc32)cc1. Metal clusters: 2 O=[C]O[Tb](O[C]=O)(O[C]=O)(O[C]=O)(O[C]=O)O[C]=O. The MOF has largest included sphere 4.68 A, density 1.26 g/cm3, surface area 5086.48 m2/g, accessible volume 0.32 cm3/g