Zn2C18P2H17(N3O4)2(CH2)3(CH)6 is Indium-derived structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules, six 02329_fluka molecules, and one Zn2C18P2H17(N3O4)2 cluster. In the Zn2C18P2H17(N3O4)2 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(1), one N(5), one O(2), and one O(8) atom to form ZnN2O2 tetrahedra that share  a cornercorner with one P(1)O4 tetrahedra and  a cornercorner with one P(2)O4 tetrahedra. The Zn(1)-N(1) bond length is 2.01 Å. The Zn(1)-N(5) bond length is 2.01 Å. The Zn(1)-O(2) bond length is 1.92 Å. The Zn(1)-O(8) bond length is 1.94 Å. In the second Zn site, Zn(2) is bonded in a trigonal non-coplanar geometry to one N(3), one O(4), and one O(7) atom. The Zn(2)-N(3) bond length is 2.01 Å. The Zn(2)-O(4) bond length is 1.95 Å. The Zn(2)-O(7) bond length is 1.96 Å. There are eighteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(3) atom. The C(1)-N(1) bond length is 1.31 Å. The C(1)-N(2) bond length is 1.36 Å. The C(1)-H(3) bond length is 0.95 Å. In the second C site, C(2) is bonded in a 3-coordinate geometry to one N(2) and two equivalent H(4,5,14) atoms. The C(2)-N(2) bond length is 1.49 Å. Both C(2)-H(4,5,14) bond lengths are 0.99 Å. In the third C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one C(9), and one N(2) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-C(9) bond length is 1.39 Å. The C(4)-N(2) bond length is 1.38 Å. In the fourth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(4), one C(6), and one N(1) atom. The C(5)-C(6) bond length is 1.40 Å. The C(5)-N(1) bond length is 1.41 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5) and one H(8) atom. The C(6)-H(8) bond length is 0.95 Å. In the sixth C site, C(9) is bonded in a distorted single-bond geometry to one C(4) and one H(11) atom. The C(9)-H(11) bond length is 0.95 Å. In the seventh C site, C(10) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(12) atom. The C(10)-N(3) bond length is 1.31 Å. The C(10)-N(4) bond length is 1.34 Å. The C(10)-H(12) bond length is 0.95 Å. In the eighth C site, C(11) is bonded in a 3-coordinate geometry to one N(4); one H(13); and one H(4,5,14) atom. The C(11)-N(4) bond length is 1.46 Å. The C(11)-H(13) bond length is 0.99 Å. The C(11)-H(4,5,14) bond length is 0.99 Å. In the ninth C site, C(13) is bonded in a distorted single-bond geometry to one C(14), one C(18), and one N(4) atom. The C(13)-C(14) bond length is 1.39 Å. The C(13)-C(18) bond length is 1.40 Å. The C(13)-N(4) bond length is 1.39 Å. In the tenth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(17) atom. The C(14)-H(17) bond length is 0.95 Å. In the eleventh C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(20) atom. The C(17)-C(18) bond length is 1.40 Å. The C(17)-H(20) bond length is 0.95 Å. In the twelfth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(13), one C(17), and one N(3) atom. The C(18)-N(3) bond length is 1.39 Å. In the thirteenth C site, C(19) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(21) atom. The C(19)-N(5) bond length is 1.32 Å. The C(19)-N(6) bond length is 1.36 Å. The C(19)-H(21) bond length is 0.95 Å. In the fourteenth C site, C(20) is bonded in a 3-coordinate geometry to one N(6) and two equivalent H(22,23) atoms. The C(20)-N(6) bond length is 1.47 Å. Both C(20)-H(22,23) bond lengths are 0.99 Å. In the fifteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(23), one C(27), and one N(6) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(27) bond length is 1.40 Å. The C(22)-N(6) bond length is 1.38 Å. In the sixteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(26) atom. The C(23)-H(26) bond length is 0.95 Å. In the seventeenth C site, C(26) is bonded in a distorted single-bond geometry to one C(27) and one H(29) atom. The C(26)-C(27) bond length is 1.39 Å. The C(26)-H(29) bond length is 0.95 Å. In the eighteenth C site, C(27) is bonded in a distorted trigonal planar geometry to one C(22), one C(26), and one N(5) atom. The C(27)-N(5) bond length is 1.40 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded to one O(1), one O(2), one O(3), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)N2O2 tetrahedra. The P(1)-O(1) bond length is 1.57 Å. The P(1)-O(2) bond length is 1.52 Å. The P(1)-O(3) bond length is 1.52 Å. The P(1)-O(4) bond length is 1.53 Å. In the second P site, P(2) is bonded to one O(5), one O(6), one O(7), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Zn(1)N2O2 tetrahedra. The P(2)-O(5) bond length is 1.56 Å. The P(2)-O(6) bond length is 1.56 Å. The P(2)-O(7) bond length is 1.51 Å. The P(2)-O(8) bond length is 1.52 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(2), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Zn(2), one C(10), and one C(18) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(13) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Zn(1), one C(19), and one C(27) atom. In the sixth N site, N(6) is bonded in a trigonal planar geometry to one C(19), one C(20), and one C(22) atom. There are fourteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.67 Å. In the second H site, H(2) is bonded in a linear geometry to one O(3) and one O(6) atom. The H(2)-O(3) bond length is 1.57 Å. The H(2)-O(6) bond length is 0.94 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(1) atom. In the fourth H site, H(4,5,14) is bonded in a single-bond geometry to one C(2) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the sixth H site, H(11) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(12) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(14) atom. In the tenth H site, H(20) is bonded in a single-bond geometry to one C(17) atom. In the eleventh H site, H(21) is bonded in a single-bond geometry to one C(19) atom. In the twelfth H site, H(22,23) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(26) is bonded in a single-bond geometry to one C(23) atom. In the fourteenth H site, H(29) is bonded in a single-bond geometry to one C(26) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one P(1) and one H(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Zn(1) and one P(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one P(1) and one H(2) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Zn(2) and one P(1) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one P(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one P(2) and one H(2) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Zn(2) and one P(2) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(1) and one P(2) atom. Linkers: 5 c1ccc2c(c1)ncn2CCCCn1cnc2ccccc21 ,2 [CH]c1ncn(CCCCn2cnc3ccccc32)c1[CH]. Metal clusters: 1 O=[P@]1(O)O[Zn]O[P@](=O)(O)O[Zn]O[P@](=O)(O)O[Zn]O[P@@](=O)(O)O[Zn]O1. The MOF has largest included sphere 5.87 A, density 1.23 g/cm3, surface area 4666.16 m2/g, accessible volume 0.36 cm3/g