MnH11(C7N3)2MnH9(C2N)6(CH)4 is Indium-derived structured and crystallizes in the monoclinic Cc space group. The structure is zero-dimensional and consists of sixteen 02329_fluka molecules, four MnH11(C7N3)2 clusters, and four MnH9(C2N)6 clusters. In each MnH11(C7N3)2 cluster, Mn(1) is bonded in a T-shaped geometry to one N(1), one N(5), and one N(7) atom. The Mn(1)-N(1) bond length is 2.26 Å. The Mn(1)-N(5) bond length is 2.23 Å. The Mn(1)-N(7) bond length is 2.24 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(2) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-N(2) bond length is 1.41 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(2) atom. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(6) is bonded in a distorted single-bond geometry to one N(6) atom. The C(6)-N(6) bond length is 1.43 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(2), and one H(4) atom. The C(7)-C(8) bond length is 1.33 Å. The C(7)-N(2) bond length is 1.38 Å. The C(7)-H(4) bond length is 0.93 Å. In the sixth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(1), and one H(5) atom. The C(8)-N(1) bond length is 1.36 Å. The C(8)-H(5) bond length is 0.93 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(6) atom. The C(9)-N(1) bond length is 1.30 Å. The C(9)-N(2) bond length is 1.36 Å. The C(9)-H(6) bond length is 0.93 Å. In the eighth C site, C(10) is bonded in a distorted trigonal planar geometry to one C(11), one N(6), and one H(7) atom. The C(10)-C(11) bond length is 1.32 Å. The C(10)-N(6) bond length is 1.37 Å. The C(10)-H(7) bond length is 0.93 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(5), and one H(8) atom. The C(11)-N(5) bond length is 1.37 Å. The C(11)-H(8) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(9) atom. The C(12)-N(5) bond length is 1.28 Å. The C(12)-N(6) bond length is 1.34 Å. The C(12)-H(9) bond length is 0.93 Å. In the eleventh C site, C(17) is bonded in a single-bond geometry to one N(8) atom. The C(17)-N(8) bond length is 1.42 Å. In the twelfth C site, C(22) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(16) atom. The C(22)-N(7) bond length is 1.29 Å. The C(22)-N(8) bond length is 1.36 Å. The C(22)-H(16) bond length is 0.93 Å. In the thirteenth C site, C(23) is bonded in a 2-coordinate geometry to one N(7) and one H(17) atom. The C(23)-N(7) bond length is 1.38 Å. The C(23)-H(17) bond length is 0.93 Å. In the fourteenth C site, C(24) is bonded in a 2-coordinate geometry to one N(8) and one H(18) atom. The C(24)-N(8) bond length is 1.37 Å. The C(24)-H(18) bond length is 0.93 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(1), one C(8), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(2), one C(7), and one C(9) atom. In the third N site, N(5) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(11), and one C(12) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(6) atom. In the fifth N site, N(7) is bonded in a trigonal planar geometry to one Mn(1), one C(22), and one C(23) atom. In the sixth N site, N(8) is bonded in a trigonal planar geometry to one C(17), one C(22), and one C(24) atom. There are eleven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(12) atom. In the ninth H site, H(16) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(17) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(18) is bonded in a single-bond geometry to one C(24) atom. In each MnH9(C2N)6 cluster, Mn(2) is bonded in a T-shaped geometry to one N(11), one N(3), and one N(9) atom. The Mn(2)-N(11) bond length is 2.25 Å. The Mn(2)-N(3) bond length is 2.25 Å. The Mn(2)-N(9) bond length is 2.26 Å. There are twelve inequivalent C sites. In the first C site, C(25) is bonded in a trigonal planar geometry to one N(10), one N(9), and one H(19) atom. The C(25)-N(10) bond length is 1.34 Å. The C(25)-N(9) bond length is 1.30 Å. The C(25)-H(19) bond length is 0.93 Å. In the second C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(27), one N(9), and one H(20) atom. The C(26)-C(27) bond length is 1.36 Å. The C(26)-N(9) bond length is 1.35 Å. The C(26)-H(20) bond length is 0.93 Å. In the third C site, C(27) is bonded in a distorted trigonal planar geometry to one C(26), one N(10), and one H(21) atom. The C(27)-N(10) bond length is 1.38 Å. The C(27)-H(21) bond length is 0.93 Å. In the fourth C site, C(28) is bonded in a trigonal planar geometry to one N(11), one N(12), and one H(22) atom. The C(28)-N(11) bond length is 1.33 Å. The C(28)-N(12) bond length is 1.35 Å. The C(28)-H(22) bond length is 0.93 Å. In the fifth C site, C(29) is bonded in a distorted bent 120 degrees geometry to one C(30), one N(11), and one H(23) atom. The C(29)-C(30) bond length is 1.36 Å. The C(29)-N(11) bond length is 1.38 Å. The C(29)-H(23) bond length is 0.93 Å. In the sixth C site, C(30) is bonded in a distorted trigonal planar geometry to one C(29), one N(12), and one H(24) atom. The C(30)-N(12) bond length is 1.36 Å. The C(30)-H(24) bond length is 0.93 Å. In the seventh C site, C(4) is bonded in a distorted single-bond geometry to one N(4) atom. The C(4)-N(4) bond length is 1.43 Å. In the eighth C site, C(13) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(10) atom. The C(13)-N(3) bond length is 1.30 Å. The C(13)-N(4) bond length is 1.33 Å. The C(13)-H(10) bond length is 0.93 Å. In the ninth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(11) atom. The C(14)-N(4) bond length is 1.37 Å. The C(14)-H(11) bond length is 0.93 Å. In the tenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(12) atom. The C(15)-N(3) bond length is 1.35 Å. The C(15)-H(12) bond length is 0.93 Å. In the eleventh C site, C(19) is bonded in a distorted single-bond geometry to one N(10) atom. The C(19)-N(10) bond length is 1.43 Å. In the twelfth C site, C(21) is bonded in a distorted single-bond geometry to one N(12) atom. The C(21)-N(12) bond length is 1.42 Å. There are six inequivalent N sites. In the first N site, N(3) is bonded in a trigonal planar geometry to one Mn(2), one C(13), and one C(15) atom. In the second N site, N(4) is bonded in a trigonal planar geometry to one C(13), one C(14), and one C(4) atom. In the third N site, N(9) is bonded in a distorted trigonal planar geometry to one Mn(2), one C(25), and one C(26) atom. In the fourth N site, N(10) is bonded in a trigonal planar geometry to one C(19), one C(25), and one C(27) atom. In the fifth N site, N(11) is bonded in a distorted trigonal planar geometry to one Mn(2), one C(28), and one C(29) atom. In the sixth N site, N(12) is bonded in a trigonal planar geometry to one C(21), one C(28), and one C(30) atom. There are nine inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one C(13) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(14) atom. In the third H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(25) atom. In the fifth H site, H(20) is bonded in a single-bond geometry to one C(26) atom. In the sixth H site, H(21) is bonded in a single-bond geometry to one C(27) atom. In the seventh H site, H(22) is bonded in a single-bond geometry to one C(28) atom. In the eighth H site, H(23) is bonded in a single-bond geometry to one C(29) atom. In the ninth H site, H(24) is bonded in a single-bond geometry to one C(30) atom. Linkers: 8 c1cn(-c2cc(-n3ccnc3)cc(-n3ccnc3)c2)cn1. Metal clusters: 8 [Mn]. The MOF has largest included sphere 6.84 A, density 0.67 g/cm3, surface area 5008.62 m2/g, accessible volume 0.93 cm3/g