(ZnC19N2H12O5)2(C3H2)6C9H6NC21NH14 is Indium-derived structured and crystallizes in the orthorhombic Pnna space group. The structure is zero-dimensional and consists of twelve 2,3-dimethyl-1,3-butadiene molecules; four schembl1705614 molecules; four C21NH14 clusters; and eight ZnC19N2H12O5 clusters. In each C21NH14 cluster, there are eleven inequivalent C sites. In the first C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(17) atom. The C(25)-C(24) bond length is 1.40 Å. The C(25)-H(17) bond length is 0.93 Å. In the second C site, C(28) is bonded in a distorted single-bond geometry to one C(24) and one H(20) atom. The C(28)-C(24) bond length is 1.40 Å. The C(28)-H(20) bond length is 0.93 Å. In the third C site, C(45) is bonded in a distorted trigonal planar geometry to two equivalent C(17) and one N(4) atom. Both C(45)-C(17) bond lengths are 1.36 Å. The C(45)-N(4) bond length is 1.42 Å. In the fourth C site, C(17) is bonded in a distorted single-bond geometry to one C(45) and one H(12) atom. The C(17)-H(12) bond length is 0.93 Å. In the fifth C site, C(18) is bonded in a distorted trigonal planar geometry to one C(19), one C(23), and one N(4) atom. The C(18)-C(19) bond length is 1.36 Å. The C(18)-C(23) bond length is 1.37 Å. The C(18)-N(4) bond length is 1.43 Å. In the sixth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(13) atom. The C(19)-C(20) bond length is 1.37 Å. The C(19)-H(13) bond length is 0.93 Å. In the seventh C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one C(21), and one H(14) atom. The C(20)-C(21) bond length is 1.39 Å. The C(20)-H(14) bond length is 0.93 Å. In the eighth C site, C(21) is bonded in a trigonal planar geometry to one C(20), one C(22), and one C(24) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-C(24) bond length is 1.46 Å. In the ninth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(15) atom. The C(22)-H(15) bond length is 0.93 Å. In the tenth C site, C(23) is bonded in a distorted single-bond geometry to one C(18) and one H(16) atom. The C(23)-H(16) bond length is 0.93 Å. In the eleventh C site, C(24) is bonded in a trigonal planar geometry to one C(21), one C(25), and one C(28) atom. N(4) is bonded in a trigonal planar geometry to one C(45) and two equivalent C(18) atoms. There are seven inequivalent H sites. In the first H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the second H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the third H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the fourth H site, H(15) is bonded in a single-bond geometry to one C(22) atom. In the fifth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the seventh H site, H(20) is bonded in a single-bond geometry to one C(28) atom. In each ZnC19N2H12O5 cluster, Zn(1) is bonded in a tetrahedral geometry to one N(1), one N(2), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 2.05 Å. The Zn(1)-N(2) bond length is 2.06 Å. The Zn(1)-O(1) bond length is 1.95 Å. The Zn(1)-O(3) bond length is 1.93 Å. There are nineteen inequivalent C sites. In the first C site, C(26) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(18) atom. The C(26)-N(2) bond length is 1.31 Å. The C(26)-H(18) bond length is 0.93 Å. In the second C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(19) atom. The C(27)-N(2) bond length is 1.34 Å. The C(27)-H(19) bond length is 0.93 Å. In the third C site, C(29) is bonded in a bent 120 degrees geometry to one C(30), one O(1), and one O(2) atom. The C(29)-C(30) bond length is 1.52 Å. The C(29)-O(1) bond length is 1.27 Å. The C(29)-O(2) bond length is 1.20 Å. In the fourth C site, C(30) is bonded in a trigonal planar geometry to one C(29), one C(31), and one C(35) atom. The C(30)-C(31) bond length is 1.31 Å. The C(30)-C(35) bond length is 1.38 Å. In the fifth C site, C(31) is bonded in a distorted single-bond geometry to one C(30) and one H(21) atom. The C(31)-H(21) bond length is 0.93 Å. In the sixth C site, C(32) is bonded in a single-bond geometry to one C(33) and one H(22) atom. The C(32)-C(33) bond length is 1.37 Å. The C(32)-H(22) bond length is 0.93 Å. In the seventh C site, C(34) is bonded in a distorted single-bond geometry to one C(33) and one H(23) atom. The C(34)-C(33) bond length is 1.31 Å. The C(34)-H(23) bond length is 0.93 Å. In the eighth C site, C(35) is bonded in a distorted single-bond geometry to one C(30) and one H(24) atom. The C(35)-H(24) bond length is 0.93 Å. In the ninth C site, C(36) is bonded in a trigonal planar geometry to one C(33), one C(37), and one C(41) atom. The C(36)-C(33) bond length is 1.47 Å. The C(36)-C(37) bond length is 1.39 Å. The C(36)-C(41) bond length is 1.39 Å. In the tenth C site, C(33) is bonded in a trigonal planar geometry to one C(32), one C(34), and one C(36) atom. In the eleventh C site, C(38) is bonded in a distorted single-bond geometry to one C(39) and one H(26) atom. The C(38)-C(39) bond length is 1.39 Å. The C(38)-H(26) bond length is 0.93 Å. In the twelfth C site, C(39) is bonded in a distorted rectangular see-saw-like geometry to one C(1), one C(2), one C(38), and one C(40) atom. The C(39)-C(1) bond length is 1.64 Å. The C(39)-C(2) bond length is 1.77 Å. The C(39)-C(40) bond length is 1.39 Å. In the thirteenth C site, C(40) is bonded in a distorted single-bond geometry to one C(39), one C(41), and one H(27) atom. The C(40)-C(41) bond length is 1.39 Å. The C(40)-H(27) bond length is 0.93 Å. In the fourteenth C site, C(41) is bonded in a distorted trigonal planar geometry to one C(36), one C(40), and one H(28) atom. The C(41)-H(28) bond length is 0.93 Å. In the fifteenth C site, C(37) is bonded in a single-bond geometry to one C(36) and one H(25) atom. The C(37)-H(25) bond length is 0.93 Å. In the sixteenth C site, C(1) is bonded in a bent 120 degrees geometry to one C(39), one O(3), and one O(5) atom. The C(1)-O(3) bond length is 1.14 Å. The C(1)-O(5) bond length is 1.19 Å. In the seventeenth C site, C(2) is bonded in a bent 120 degrees geometry to one C(39), one O(3), and one O(4) atom. The C(2)-O(3) bond length is 1.12 Å. The C(2)-O(4) bond length is 1.21 Å. In the eighteenth C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(3)-N(1) bond length is 1.31 Å. The C(3)-H(1) bond length is 0.93 Å. In the nineteenth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(7)-N(1) bond length is 1.31 Å. The C(7)-H(4) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(3), and one C(7) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Zn(1), one C(26), and one C(27) atom. There are twelve inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the fourth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the fifth H site, H(21) is bonded in a single-bond geometry to one C(31) atom. In the sixth H site, H(22) is bonded in a single-bond geometry to one C(32) atom. In the seventh H site, H(23) is bonded in a single-bond geometry to one C(34) atom. In the eighth H site, H(24) is bonded in a single-bond geometry to one C(35) atom. In the ninth H site, H(25) is bonded in a single-bond geometry to one C(37) atom. In the tenth H site, H(26) is bonded in a single-bond geometry to one C(38) atom. In the eleventh H site, H(27) is bonded in a single-bond geometry to one C(40) atom. In the twelfth H site, H(28) is bonded in a single-bond geometry to one C(41) atom. There are five inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(29) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(29) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to one Zn(1), one C(1), and one C(2) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(2) atom. In the fifth O site, O(5) is bonded in a single-bond geometry to one C(1) atom. Linkers: 4 c1cc(-c2ccc(N(c3ccc(-c4ccncc4)cc3)c3ccc(-c4ccc(N(c5ccc(-c6ccncc6)cc5)c5ccc(-c6ccncc6)cc5)cc4)cc3)cc2)ccn1 ,8 [O]C(=O)c1ccc(C2=C[CH][C@@]3(C=C2)[C@]2([O])O[C@]32[O])cc1. Metal clusters: 8 O=[C]O[Zn]. The MOF has largest included sphere 7.95 A, density 0.84 g/cm3, surface area 4953.03 m2/g, accessible volume 0.81 cm3/g