Ho2C39P3N3H20O19(CH)4 crystallizes in the monoclinic P2_1 space group. The structure consists of sixteen 02329_fluka molecules inside a Ho2C39P3N3H20O19 framework. In the Ho2C39P3N3H20O19 framework, there are four inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 8-coordinate geometry to one O(16), one O(17), one O(20), one O(31), one O(32), one O(37), one O(38), and one O(6) atom. The Ho(1)-O(16) bond length is 2.34 Å. The Ho(1)-O(17) bond length is 2.35 Å. The Ho(1)-O(20) bond length is 2.32 Å. The Ho(1)-O(31) bond length is 2.54 Å. The Ho(1)-O(32) bond length is 2.38 Å. The Ho(1)-O(37) bond length is 2.46 Å. The Ho(1)-O(38) bond length is 2.43 Å. The Ho(1)-O(6) bond length is 2.29 Å. In the second Ho site, Ho(2) is bonded in a 8-coordinate geometry to one O(1), one O(15), one O(19), one O(21), one O(33), one O(34), one O(35), and one O(37) atom. The Ho(2)-O(1) bond length is 2.33 Å. The Ho(2)-O(15) bond length is 2.36 Å. The Ho(2)-O(19) bond length is 2.25 Å. The Ho(2)-O(21) bond length is 2.31 Å. The Ho(2)-O(33) bond length is 2.37 Å. The Ho(2)-O(34) bond length is 2.57 Å. The Ho(2)-O(35) bond length is 2.42 Å. The Ho(2)-O(37) bond length is 2.36 Å. In the third Ho site, Ho(3) is bonded in a 7-coordinate geometry to one O(14), one O(2), one O(21), one O(22), one O(34), one O(36), and one O(4) atom. The Ho(3)-O(14) bond length is 2.29 Å. The Ho(3)-O(2) bond length is 2.29 Å. The Ho(3)-O(21) bond length is 2.56 Å. The Ho(3)-O(22) bond length is 2.47 Å. The Ho(3)-O(34) bond length is 2.45 Å. The Ho(3)-O(36) bond length is 2.28 Å. The Ho(3)-O(4) bond length is 2.27 Å. In the fourth Ho site, Ho(4) is bonded in a 8-coordinate geometry to one O(13), one O(17), one O(18), one O(23), one O(24), one O(3), one O(31), and one O(5) atom. The Ho(4)-O(13) bond length is 2.26 Å. The Ho(4)-O(17) bond length is 2.44 Å. The Ho(4)-O(18) bond length is 2.49 Å. The Ho(4)-O(23) bond length is 2.32 Å. The Ho(4)-O(24) bond length is 2.53 Å. The Ho(4)-O(3) bond length is 2.27 Å. The Ho(4)-O(31) bond length is 2.36 Å. The Ho(4)-O(5) bond length is 2.25 Å. There are seventy-eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(6), and one O(7) atom. The C(1)-C(2) bond length is 1.41 Å. The C(1)-C(6) bond length is 1.42 Å. The C(1)-O(7) bond length is 1.37 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-H(1) bond length is 0.95 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2,7) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(2,7) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(7) atom. The C(4)-C(5) bond length is 1.40 Å. The C(4)-C(7) bond length is 1.47 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 0.95 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(4), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.27 Å. The C(7)-O(2) bond length is 1.26 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(13), one C(9), and one O(8) atom. The C(8)-C(13) bond length is 1.38 Å. The C(8)-C(9) bond length is 1.35 Å. The C(8)-O(8) bond length is 1.42 Å. In the ninth C site, C(9) is bonded in a distorted single-bond geometry to one C(8) and one H(5) atom. The C(9)-H(5) bond length is 0.95 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one C(11) and one H(6) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-H(6) bond length is 0.95 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(12), and one C(14) atom. The C(11)-C(12) bond length is 1.38 Å. The C(11)-C(14) bond length is 1.48 Å. In the twelfth C site, C(12) is bonded in a distorted single-bond geometry to one C(11) and one H(2,7) atom. The C(12)-H(2,7) bond length is 0.95 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(8) and one H(8) atom. The C(13)-H(8) bond length is 0.95 Å. In the fourteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(3), and one O(4) atom. The C(14)-O(3) bond length is 1.24 Å. The C(14)-O(4) bond length is 1.28 Å. In the fifteenth C site, C(15) is bonded in a distorted trigonal planar geometry to one C(16), one C(20), and one O(9) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-C(20) bond length is 1.40 Å. The C(15)-O(9) bond length is 1.38 Å. In the sixteenth C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(9) atom. The C(16)-H(9) bond length is 0.95 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(18) and one H(10) atom. The C(17)-C(18) bond length is 1.42 Å. The C(17)-H(10) bond length is 0.95 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(17), one C(19), and one C(21) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-C(21) bond length is 1.44 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(11) atom. The C(19)-C(20) bond length is 1.36 Å. The C(19)-H(11) bond length is 0.95 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(15), one C(19), and one H(12) atom. The C(20)-H(12) bond length is 0.95 Å. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(18), one O(5), and one O(6) atom. The C(21)-O(5) bond length is 1.26 Å. The C(21)-O(6) bond length is 1.25 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one O(12) atom. The C(22)-O(12) bond length is 1.39 Å. In the twenty-third C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(14) atom. The C(24)-C(25) bond length is 1.40 Å. The C(24)-H(14) bond length is 0.95 Å. In the twenty-fourth C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(28) atom. The C(25)-C(26) bond length is 1.36 Å. The C(25)-C(28) bond length is 1.50 Å. In the twenty-fifth C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one H(15) atom. The C(26)-H(15) bond length is 0.95 Å. In the twenty-sixth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(17), and one O(18) atom. The C(28)-O(17) bond length is 1.31 Å. The C(28)-O(18) bond length is 1.21 Å. In the twenty-seventh C site, C(29) is bonded in a distorted trigonal planar geometry to one C(30), one C(34), and one O(11) atom. The C(29)-C(30) bond length is 1.35 Å. The C(29)-C(34) bond length is 1.36 Å. The C(29)-O(11) bond length is 1.43 Å. In the twenty-eighth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(17) atom. The C(30)-H(17) bond length is 0.95 Å. In the twenty-ninth C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(18) atom. The C(31)-C(32) bond length is 1.34 Å. The C(31)-H(18) bond length is 0.95 Å. In the thirtieth C site, C(32) is bonded in a trigonal planar geometry to one C(31), one C(33), and one C(35) atom. The C(32)-C(33) bond length is 1.39 Å. The C(32)-C(35) bond length is 1.52 Å. In the thirty-first C site, C(33) is bonded in a distorted single-bond geometry to one C(32) and one H(19,39) atom. The C(33)-H(19,39) bond length is 0.95 Å. In the thirty-second C site, C(34) is bonded in a distorted single-bond geometry to one C(29) and one H(20) atom. The C(34)-H(20) bond length is 0.95 Å. In the thirty-third C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(32), one O(15), and one O(16) atom. The C(35)-O(15) bond length is 1.28 Å. The C(35)-O(16) bond length is 1.27 Å. In the thirty-fourth C site, C(36) is bonded in a distorted trigonal planar geometry to one C(37), one C(41), and one O(10) atom. The C(36)-C(37) bond length is 1.38 Å. The C(36)-C(41) bond length is 1.37 Å. The C(36)-O(10) bond length is 1.44 Å. In the thirty-fifth C site, C(37) is bonded in a distorted single-bond geometry to one C(36), one C(38), and one H(21) atom. The C(37)-C(38) bond length is 1.39 Å. The C(37)-H(21) bond length is 0.95 Å. In the thirty-sixth C site, C(38) is bonded in a distorted single-bond geometry to one C(37), one C(39), and one H(22) atom. The C(38)-C(39) bond length is 1.36 Å. The C(38)-H(22) bond length is 0.95 Å. In the thirty-seventh C site, C(39) is bonded in a trigonal planar geometry to one C(38), one C(40), and one C(42) atom. The C(39)-C(40) bond length is 1.37 Å. The C(39)-C(42) bond length is 1.51 Å. In the thirty-eighth C site, C(40) is bonded in a distorted single-bond geometry to one C(39) and one H(23) atom. The C(40)-H(23) bond length is 0.95 Å. In the thirty-ninth C site, C(41) is bonded in a distorted single-bond geometry to one C(36) and one H(24) atom. The C(41)-H(24) bond length is 0.95 Å. In the fortieth C site, C(42) is bonded in a bent 120 degrees geometry to one C(39), one O(13), and one O(14) atom. The C(42)-O(13) bond length is 1.26 Å. The C(42)-O(14) bond length is 1.25 Å. In the forty-first C site, C(43) is bonded in a distorted single-bond geometry to one O(25) atom. The C(43)-O(25) bond length is 1.40 Å. In the forty-second C site, C(45) is bonded in a distorted single-bond geometry to one C(46) and one H(26,27) atom. The C(45)-C(46) bond length is 1.39 Å. The C(45)-H(26,27) bond length is 0.95 Å. In the forty-third C site, C(46) is bonded in a trigonal planar geometry to one C(45), one C(47), and one C(49) atom. The C(46)-C(47) bond length is 1.38 Å. The C(46)-C(49) bond length is 1.49 Å. In the forty-fourth C site, C(47) is bonded in a distorted single-bond geometry to one C(46) and one H(26,27) atom. The C(47)-H(26,27) bond length is 0.95 Å. In the forty-fifth C site, C(49) is bonded in a bent 120 degrees geometry to one C(46), one O(23), and one O(24) atom. The C(49)-O(23) bond length is 1.27 Å. The C(49)-O(24) bond length is 1.25 Å. In the forty-sixth C site, C(50) is bonded in a distorted single-bond geometry to one O(27) atom. The C(50)-O(27) bond length is 1.40 Å. In the forty-seventh C site, C(52) is bonded in a distorted single-bond geometry to one C(53) and one H(30) atom. The C(52)-C(53) bond length is 1.38 Å. The C(52)-H(30) bond length is 0.95 Å. In the forty-eighth C site, C(53) is bonded in a trigonal planar geometry to one C(52), one C(54), and one C(56) atom. The C(53)-C(54) bond length is 1.41 Å. The C(53)-C(56) bond length is 1.45 Å. In the forty-ninth C site, C(54) is bonded in a distorted single-bond geometry to one C(53) and one H(31) atom. The C(54)-H(31) bond length is 0.95 Å. In the fiftieth C site, C(56) is bonded in a bent 120 degrees geometry to one C(53), one O(21), and one O(22) atom. The C(56)-O(21) bond length is 1.29 Å. The C(56)-O(22) bond length is 1.26 Å. In the fifty-first C site, C(57) is bonded in a distorted trigonal planar geometry to one C(58), one C(62), and one O(26) atom. The C(57)-C(58) bond length is 1.33 Å. The C(57)-C(62) bond length is 1.38 Å. The C(57)-O(26) bond length is 1.43 Å. In the fifty-second C site, C(58) is bonded in a distorted single-bond geometry to one C(57) and one H(33) atom. The C(58)-H(33) bond length is 0.95 Å. In the fifty-third C site, C(59) is bonded in a single-bond geometry to one C(60) and one H(34) atom. The C(59)-C(60) bond length is 1.42 Å. The C(59)-H(34) bond length is 0.95 Å. In the fifty-fourth C site, C(60) is bonded in a trigonal planar geometry to one C(59), one C(61), and one C(63) atom. The C(60)-C(61) bond length is 1.37 Å. The C(60)-C(63) bond length is 1.46 Å. In the fifty-fifth C site, C(61) is bonded in a distorted single-bond geometry to one C(60), one C(62), and one H(35) atom. The C(61)-C(62) bond length is 1.40 Å. The C(61)-H(35) bond length is 0.95 Å. In the fifty-sixth C site, C(62) is bonded in a distorted trigonal planar geometry to one C(57), one C(61), and one H(36) atom. The C(62)-H(36) bond length is 0.95 Å. In the fifty-seventh C site, C(63) is bonded in a distorted bent 120 degrees geometry to one C(60), one O(19), and one O(20) atom. The C(63)-O(19) bond length is 1.29 Å. The C(63)-O(20) bond length is 1.26 Å. In the fifty-eighth C site, C(64) is bonded in a distorted single-bond geometry to one O(28) atom. The C(64)-O(28) bond length is 1.40 Å. In the fifty-ninth C site, C(65) is bonded in a distorted single-bond geometry to one C(66) and one H(37) atom. The C(65)-C(66) bond length is 1.36 Å. The C(65)-H(37) bond length is 0.95 Å. In the sixtieth C site, C(66) is bonded in a distorted trigonal planar geometry to one C(65), one C(67), and one H(38) atom. The C(66)-C(67) bond length is 1.38 Å. The C(66)-H(38) bond length is 0.95 Å. In the sixty-first C site, C(67) is bonded in a trigonal planar geometry to one C(66), one C(68), and one C(70) atom. The C(67)-C(68) bond length is 1.40 Å. The C(67)-C(70) bond length is 1.51 Å. In the sixty-second C site, C(68) is bonded in a single-bond geometry to one C(67) and one H(19,39) atom. The C(68)-H(19,39) bond length is 0.95 Å. In the sixty-third C site, C(70) is bonded in a bent 120 degrees geometry to one C(67), one O(31), and one O(32) atom. The C(70)-O(31) bond length is 1.27 Å. The C(70)-O(32) bond length is 1.23 Å. In the sixty-fourth C site, C(71) is bonded in a distorted trigonal planar geometry to one C(72), one C(76), and one O(29) atom. The C(71)-C(72) bond length is 1.36 Å. The C(71)-C(76) bond length is 1.40 Å. The C(71)-O(29) bond length is 1.37 Å. In the sixty-fifth C site, C(72) is bonded in a distorted single-bond geometry to one C(71) and one H(41) atom. The C(72)-H(41) bond length is 0.95 Å. In the sixty-sixth C site, C(73) is bonded in a distorted single-bond geometry to one C(74) and one H(42) atom. The C(73)-C(74) bond length is 1.36 Å. The C(73)-H(42) bond length is 0.95 Å. In the sixty-seventh C site, C(74) is bonded in a trigonal planar geometry to one C(73), one C(75), and one C(77) atom. The C(74)-C(75) bond length is 1.40 Å. The C(74)-C(77) bond length is 1.48 Å. In the sixty-eighth C site, C(75) is bonded in a distorted single-bond geometry to one C(74) and one H(43) atom. The C(75)-H(43) bond length is 0.95 Å. In the sixty-ninth C site, C(76) is bonded in a distorted single-bond geometry to one C(71) and one H(44) atom. The C(76)-H(44) bond length is 0.95 Å. In the seventieth C site, C(77) is bonded in a distorted bent 120 degrees geometry to one C(74), one O(33), and one O(34) atom. The C(77)-O(33) bond length is 1.26 Å. The C(77)-O(34) bond length is 1.29 Å. In the seventy-first C site, C(78) is bonded in a distorted single-bond geometry to one C(79) and one O(30) atom. The C(78)-C(79) bond length is 1.35 Å. The C(78)-O(30) bond length is 1.43 Å. In the seventy-second C site, C(79) is bonded in a distorted trigonal planar geometry to one C(78), one C(80), and one H(45) atom. The C(79)-C(80) bond length is 1.36 Å. The C(79)-H(45) bond length is 0.95 Å. In the seventy-third C site, C(80) is bonded in a distorted single-bond geometry to one C(79), one C(81), and one H(46) atom. The C(80)-C(81) bond length is 1.41 Å. The C(80)-H(46) bond length is 0.95 Å. In the seventy-fourth C site, C(81) is bonded in a trigonal planar geometry to one C(80), one C(82), and one C(84) atom. The C(81)-C(82) bond length is 1.36 Å. The C(81)-C(84) bond length is 1.49 Å. In the seventy-fifth C site, C(82) is bonded in a distorted single-bond geometry to one C(81) and one H(47) atom. The C(82)-H(47) bond length is 0.95 Å. In the seventy-sixth C site, C(84) is bonded in a distorted bent 120 degrees geometry to one C(81), one O(35), and one O(36) atom. The C(84)-O(35) bond length is 1.24 Å. The C(84)-O(36) bond length is 1.27 Å. In the seventy-seventh C site, C(85) is bonded in a bent 120 degrees geometry to one C(86), one O(37), and one O(38) atom. The C(85)-C(86) bond length is 1.50 Å. The C(85)-O(37) bond length is 1.32 Å. The C(85)-O(38) bond length is 1.24 Å. In the seventy-eighth C site, C(86) is bonded in a single-bond geometry to one C(85) atom. There are six inequivalent P sites. In the first P site, P(1) is bonded to one N(1), one N(2), one O(25), and one O(28) atom to form corner-sharing PN2O2 tetrahedra. The P(1)-N(1) bond length is 1.55 Å. The P(1)-N(2) bond length is 1.57 Å. The P(1)-O(25) bond length is 1.56 Å. The P(1)-O(28) bond length is 1.59 Å. In the second P site, P(2) is bonded to one N(2), one N(3), one O(27), and one O(30) atom to form corner-sharing PN2O2 tetrahedra. The P(2)-N(2) bond length is 1.59 Å. The P(2)-N(3) bond length is 1.61 Å. The P(2)-O(27) bond length is 1.57 Å. The P(2)-O(30) bond length is 1.59 Å. In the third P site, P(3) is bonded to one N(1), one N(3), one O(26), and one O(29) atom to form corner-sharing PN2O2 tetrahedra. The P(3)-N(1) bond length is 1.62 Å. The P(3)-N(3) bond length is 1.56 Å. The P(3)-O(26) bond length is 1.59 Å. The P(3)-O(29) bond length is 1.58 Å. In the fourth P site, P(4) is bonded to one N(4), one N(5), one O(12), and one O(9) atom to form corner-sharing PN2O2 tetrahedra. The P(4)-N(4) bond length is 1.57 Å. The P(4)-N(5) bond length is 1.56 Å. The P(4)-O(12) bond length is 1.60 Å. The P(4)-O(9) bond length is 1.58 Å. In the fifth P site, P(5) is bonded to one N(5), one N(6), one O(11), and one O(8) atom to form corner-sharing PN2O2 tetrahedra. The P(5)-N(5) bond length is 1.60 Å. The P(5)-N(6) bond length is 1.61 Å. The P(5)-O(11) bond length is 1.59 Å. The P(5)-O(8) bond length is 1.57 Å. In the sixth P site, P(6) is bonded to one N(4), one N(6), one O(10), and one O(7) atom to form corner-sharing PN2O2 tetrahedra. The P(6)-N(4) bond length is 1.61 Å. The P(6)-N(6) bond length is 1.56 Å. The P(6)-O(10) bond length is 1.57 Å. The P(6)-O(7) bond length is 1.59 Å. There are six inequivalent N sites. In the first N site, N(1) is bonded in a bent 120 degrees geometry to one P(1) and one P(3) atom. In the second N site, N(2) is bonded in a bent 120 degrees geometry to one P(1) and one P(2) atom. In the third N site, N(3) is bonded in a bent 120 degrees geometry to one P(2) and one P(3) atom. In the fourth N site, N(4) is bonded in a bent 120 degrees geometry to one P(4) and one P(6) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one P(4) and one P(5) atom. In the sixth N site, N(6) is bonded in a bent 120 degrees geometry to one P(5) and one P(6) atom. There are thirty-seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2,7) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(13) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(26) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(30) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(31) atom. In the sixteenth H site, H(19,39) is bonded in a single-bond geometry to one C(33) atom. In the seventeenth H site, H(20) is bonded in a single-bond geometry to one C(34) atom. In the eighteenth H site, H(21) is bonded in a single-bond geometry to one C(37) atom. In the nineteenth H site, H(22) is bonded in a single-bond geometry to one C(38) atom. In the twentieth H site, H(23) is bonded in a single-bond geometry to one C(40) atom. In the twenty-first H site, H(24) is bonded in a single-bond geometry to one C(41) atom. In the twenty-second H site, H(26,27) is bonded in a single-bond geometry to one C(45) atom. In the twenty-third H site, H(30) is bonded in a single-bond geometry to one C(52) atom. In the twenty-fourth H site, H(31) is bonded in a single-bond geometry to one C(54) atom. In the twenty-fifth H site, H(33) is bonded in a single-bond geometry to one C(58) atom. In the twenty-sixth H site, H(34) is bonded in a single-bond geometry to one C(59) atom. In the twenty-seventh H site, H(35) is bonded in a single-bond geometry to one C(61) atom. In the twenty-eighth H site, H(36) is bonded in a single-bond geometry to one C(62) atom. In the twenty-ninth H site, H(37) is bonded in a single-bond geometry to one C(65) atom. In the thirtieth H site, H(38) is bonded in a single-bond geometry to one C(66) atom. In the thirty-first H site, H(41) is bonded in a single-bond geometry to one C(72) atom. In the thirty-second H site, H(42) is bonded in a single-bond geometry to one C(73) atom. In the thirty-third H site, H(43) is bonded in a single-bond geometry to one C(75) atom. In the thirty-fourth H site, H(44) is bonded in a single-bond geometry to one C(76) atom. In the thirty-fifth H site, H(45) is bonded in a single-bond geometry to one C(79) atom. In the thirty-sixth H site, H(46) is bonded in a single-bond geometry to one C(80) atom. In the thirty-seventh H site, H(47) is bonded in a single-bond geometry to one C(82) atom. There are thirty-eight inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ho(2) and one C(7) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ho(3) and one C(7) atom. In the third O site, O(3) is bonded in a distorted linear geometry to one Ho(4) and one C(14) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Ho(3) and one C(14) atom. In the fifth O site, O(5) is bonded in a distorted bent 150 degrees geometry to one Ho(4) and one C(21) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Ho(1) and one C(21) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one C(1) and one P(6) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one C(8) and one P(5) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one C(15) and one P(4) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one C(36) and one P(6) atom. In the eleventh O site, O(11) is bonded in a bent 120 degrees geometry to one C(29) and one P(5) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one C(22) and one P(4) atom. In the thirteenth O site, O(13) is bonded in a distorted bent 150 degrees geometry to one Ho(4) and one C(42) atom. In the fourteenth O site, O(14) is bonded in a distorted linear geometry to one Ho(3) and one C(42) atom. In the fifteenth O site, O(15) is bonded in a distorted single-bond geometry to one Ho(2) and one C(35) atom. In the sixteenth O site, O(16) is bonded in a distorted water-like geometry to one Ho(1) and one C(35) atom. In the seventeenth O site, O(17) is bonded in a distorted single-bond geometry to one Ho(1), one Ho(4), and one C(28) atom. In the eighteenth O site, O(18) is bonded in a distorted single-bond geometry to one Ho(4) and one C(28) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Ho(2) and one C(63) atom. In the twentieth O site, O(20) is bonded in a distorted bent 150 degrees geometry to one Ho(1) and one C(63) atom. In the twenty-first O site, O(21) is bonded in a 1-coordinate geometry to one Ho(2), one Ho(3), and one C(56) atom. In the twenty-second O site, O(22) is bonded in a distorted single-bond geometry to one Ho(3) and one C(56) atom. In the twenty-third O site, O(23) is bonded in a distorted water-like geometry to one Ho(4) and one C(49) atom. In the twenty-fourth O site, O(24) is bonded in a distorted single-bond geometry to one Ho(4) and one C(49) atom. In the twenty-fifth O site, O(25) is bonded in a single-bond geometry to one C(43) and one P(1) atom. In the twenty-sixth O site, O(26) is bonded in a single-bond geometry to one C(57) and one P(3) atom. In the twenty-seventh O site, O(27) is bonded in a bent 120 degrees geometry to one C(50) and one P(2) atom. In the twenty-eighth O site, O(28) is bonded in a bent 120 degrees geometry to one C(64) and one P(1) atom. In the twenty-ninth O site, O(29) is bonded in a bent 120 degrees geometry to one C(71) and one P(3) atom. In the thirtieth O site, O(30) is bonded in a bent 120 degrees geometry to one C(78) and one P(2) atom. In the thirty-first O site, O(31) is bonded in a 1-coordinate geometry to one Ho(1), one Ho(4), and one C(70) atom. In the thirty-second O site, O(32) is bonded in a distorted L-shaped geometry to one Ho(1) and one C(70) atom. In the thirty-third O site, O(33) is bonded in a distorted water-like geometry to one Ho(2) and one C(77) atom. In the thirty-fourth O site, O(34) is bonded in a distorted single-bond geometry to one Ho(2), one Ho(3), and one C(77) atom. In the thirty-fifth O site, O(35) is bonded in a distorted single-bond geometry to one Ho(2) and one C(84) atom. In the thirty-sixth O site, O(36) is bonded in a distorted bent 120 degrees geometry to one Ho(3) and one C(84) atom. In the thirty-seventh O site, O(37) is bonded in a 3-coordinate geometry to one Ho(1), one Ho(2), and one C(85) atom. In the thirty-eighth O site, O(38) is bonded in a distorted L-shaped geometry to one Ho(1) and one C(85) atom. Linkers: 4 [O]C(=O)c1ccc(O[P]2(Oc3ccc(C([O])=O)cc3)[N][P](Oc3ccc(C([O])=O)cc3)(Oc3ccc(C([O])=O)cc3)[N][P](Oc3ccc(C([O])=O)cc3)(Oc3ccc(C([O])=O)cc3)[N]2)cc1. Metal clusters: 8 [Ho]. The MOF has largest included sphere 11.11 A, density 1.03 g/cm3, surface area 3434.11 m2/g, accessible volume 0.64 cm3/g