CuC14H10(N3O2)2(CH)6 crystallizes in the hexagonal P6_122 space group. The structure consists of thirty-six 02329_fluka molecules inside a CuC14H10(N3O2)2 framework. In the CuC14H10(N3O2)2 framework, Cu(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Cu(1)-N(1) bond lengths are 1.98 Å. Both Cu(1)-O(1) bond lengths are 1.94 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(5), one C(8), and one N(3) atom. The C(1)-C(5) bond length is 1.38 Å. The C(1)-C(8) bond length is 1.38 Å. The C(1)-N(3) bond length is 1.43 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(1), and one H(3) atom. The C(2)-C(9) bond length is 1.39 Å. The C(2)-N(1) bond length is 1.33 Å. The C(2)-H(3) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(2), and one N(3) atom. The C(3)-C(9) bond length is 1.39 Å. The C(3)-N(2) bond length is 1.34 Å. The C(3)-N(3) bond length is 1.37 Å. In the fourth C site, C(5) is bonded in a single-bond geometry to one C(1) and one H(5) atom. The C(5)-H(5) bond length is 0.93 Å. In the fifth C site, C(8) is bonded in a distorted single-bond geometry to one C(1) and one H(8) atom. The C(8)-H(8) bond length is 0.93 Å. In the sixth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(2), and one C(3) atom. The C(9)-C(10) bond length is 1.47 Å. In the seventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(1), and one O(2) atom. The C(10)-O(1) bond length is 1.27 Å. The C(10)-O(2) bond length is 1.25 Å. There are three inequivalent N sites. In the first N site, N(3) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(1) atom. The N(3)-N(1) bond length is 1.38 Å. In the second N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(2), and one N(3) atom. In the third N site, N(2) is bonded in a trigonal planar geometry to one C(3), one H(1), and one H(2) atom. The N(2)-H(1) bond length is 0.86 Å. The N(2)-H(2) bond length is 0.86 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one N(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one N(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(2) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(8) is bonded in a single-bond geometry to one C(8) atom. There are two inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Cu(1) and one C(10) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(10) atom. Linkers: 12 Nc1c(C([O])=O)cnn1-c1ccccc1. Metal clusters: 6 O=[C]O[Cu]O[C]=O. The MOF has largest included sphere 5.25 A, density 1.23 g/cm3, surface area 4738.13 m2/g, accessible volume 0.37 cm3/g