(CuC24NH13O4)2C7H5C5H3 crystallizes in the hexagonal P6_322 space group. The structure consists of two 1,3,5-triisopropenyl benzene molecules and two C7H5 clusters inside a CuC24NH13O4 framework. In each C7H5 cluster, there are five inequivalent C sites. In the first C site, C(9) is bonded in a distorted single-bond geometry to one C(10) and one H(6) atom. The C(9)-C(10) bond length is 1.37 Å. The C(9)-H(6) bond length is 0.93 Å. In the second C site, C(10) is bonded in a 3-coordinate geometry to one C(28), one C(9), and one H(7) atom. The C(10)-C(28) bond length is 1.39 Å. The C(10)-H(7) bond length is 0.93 Å. In the third C site, C(30) is bonded in a single-bond geometry to two equivalent C(29) and one H(17) atom. Both C(30)-C(29) bond lengths are 1.45 Å. The C(30)-H(17) bond length is 0.93 Å. In the fourth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28) and two equivalent C(30) atoms. The C(29)-C(28) bond length is 1.51 Å. In the fifth C site, C(28) is bonded in a trigonal planar geometry to one C(29) and two equivalent C(10) atoms. There are three inequivalent H sites. In the first H site, H(17) is bonded in a single-bond geometry to one C(30) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(10) atom. In the CuC24NH13O4 framework, Cu(1) is bonded in a 4-coordinate geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-O(1) bond length is 2.05 Å. The Cu(1)-O(2) bond length is 1.93 Å. The Cu(1)-O(3) bond length is 1.95 Å. The Cu(1)-O(4) bond length is 1.87 Å. There are twenty-five inequivalent C sites. In the first C site, C(27) is bonded in a distorted single-bond geometry to one N(1) atom. The C(27)-N(1) bond length is 1.35 Å. In the second C site, C(33) is bonded in a distorted single-bond geometry to two equivalent C(26) and one N(2) atom. Both C(33)-C(26) bond lengths are 1.43 Å. The C(33)-N(2) bond length is 1.51 Å. In the third C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(20), and one C(6) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(20) bond length is 1.52 Å. The C(1)-C(6) bond length is 1.39 Å. In the fourth C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(1) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(1) bond length is 0.93 Å. In the fifth C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(7) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-C(7) bond length is 1.35 Å. In the sixth C site, C(4) is bonded in a trigonal planar geometry to one C(22), one C(3), and one C(5) atom. The C(4)-C(22) bond length is 1.53 Å. The C(4)-C(5) bond length is 1.39 Å. In the seventh C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(5)-H(2) bond length is 0.93 Å. In the eighth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the ninth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(3), one C(8), and one H(4) atom. The C(7)-C(8) bond length is 1.57 Å. The C(7)-H(4) bond length is 0.93 Å. In the tenth C site, C(8) is bonded in a distorted single-bond geometry to one C(23), one C(7), and one H(5) atom. The C(8)-C(23) bond length is 1.16 Å. The C(8)-H(5) bond length is 0.93 Å. In the eleventh C site, C(11) is bonded in a distorted bent 150 degrees geometry to one C(16), one O(1), and one O(2) atom. The C(11)-C(16) bond length is 1.52 Å. The C(11)-O(1) bond length is 1.38 Å. The C(11)-O(2) bond length is 1.32 Å. In the twelfth C site, C(12) is bonded in a distorted trigonal planar geometry to one C(14), one C(21), and one H(8) atom. The C(12)-C(14) bond length is 1.35 Å. The C(12)-C(21) bond length is 1.42 Å. The C(12)-H(8) bond length is 0.93 Å. In the thirteenth C site, C(13) is bonded in a distorted single-bond geometry to one C(21), one C(24), and one N(2) atom. The C(13)-C(21) bond length is 1.45 Å. The C(13)-C(24) bond length is 1.38 Å. The C(13)-N(2) bond length is 1.52 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-C(19) bond length is 1.39 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14), one C(16), and one H(9) atom. The C(15)-C(16) bond length is 1.39 Å. The C(15)-H(9) bond length is 0.93 Å. In the sixteenth C site, C(16) is bonded in a trigonal planar geometry to one C(11), one C(15), and one C(17) atom. The C(16)-C(17) bond length is 1.39 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(10) atom. The C(17)-H(10) bond length is 0.93 Å. In the eighteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(11) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(11) bond length is 0.93 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(24) atom. The C(19)-C(24) bond length is 1.51 Å. In the twentieth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(3), and one O(4) atom. The C(20)-O(3) bond length is 1.46 Å. The C(20)-O(4) bond length is 1.35 Å. In the twenty-first C site, C(21) is bonded in a distorted single-bond geometry to one C(12), one C(13), and one H(12) atom. The C(21)-H(12) bond length is 0.93 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(23), one C(4), and one H(13) atom. The C(22)-C(23) bond length is 1.41 Å. The C(22)-H(13) bond length is 0.93 Å. In the twenty-third C site, C(23) is bonded in a 3-coordinate geometry to one C(22), one C(8), and one N(1) atom. The C(23)-N(1) bond length is 1.53 Å. In the twenty-fourth C site, C(24) is bonded in a distorted single-bond geometry to one C(13), one C(19), and one H(14) atom. The C(24)-H(14) bond length is 0.93 Å. In the twenty-fifth C site, C(26) is bonded in a distorted single-bond geometry to one C(33) and one H(16) atom. The C(26)-H(16) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(27) and two equivalent C(23) atoms. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(33) and two equivalent C(13) atoms. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(8) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(15) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(24) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(26) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(1) and one C(11) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Cu(1) and one C(11) atom. In the third O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(20) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cu(1) and one C(20) atom. Linkers: 5 [O]C(=O)c1ccc2cc(N(c3ccc(-c4cc(-c5ccc(N(c6ccc7cc(C([O])=O)ccc7c6)c6ccc7cc(C([O])=O)ccc7c6)cc5)cc(-c5ccc(N(c6ccc7cc(C([O])=O)ccc7c6)c6ccc7cc(C([O])=O)ccc7c6)cc5)c4)cc3)c3ccc4cc(C([O])=O)ccc4c3)ccc2c1. Metal clusters: 6 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 17.24 A, density 0.31 g/cm3, surface area 4748.85 m2/g, accessible volume 2.79 cm3/g