NiZn2C26NH14O13(C5H3)6(CH)3 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of twelve 02329_fluka molecules; eight 1,3,5-triisopropenyl benzene molecules; and four NiZn2C26NH14O13 clusters. In each NiZn2C26NH14O13 cluster, Ni(1) is bonded to one N(1), one O(7), two equivalent O(4), and two equivalent O(6) atoms to form NiNO5 octahedra that share corners with two equivalent Zn(1)O4 tetrahedra. The Ni(1)-N(1) bond length is 2.10 Å. The Ni(1)-O(7) bond length is 2.10 Å. Both Ni(1)-O(4) bond lengths are 2.08 Å. Both Ni(1)-O(6) bond lengths are 2.06 Å. Zn(1) is bonded to one O(1), one O(3), one O(5), and one O(7) atom to form distorted ZnO4 tetrahedra that share  a cornercorner with one Ni(1)NO5 octahedra and  a cornercorner with one Zn(1)O4 tetrahedra. The corner-sharing octahedral tilt angles are 75°. The Zn(1)-O(1) bond length is 1.94 Å. The Zn(1)-O(3) bond length is 1.96 Å. The Zn(1)-O(5) bond length is 1.94 Å. The Zn(1)-O(7) bond length is 2.00 Å. There are thirteen inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.51 Å. The C(1)-O(1) bond length is 1.26 Å. The C(1)-O(2) bond length is 1.23 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.37 Å. The C(2)-C(7) bond length is 1.40 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(16) is bonded in a distorted single-bond geometry to one C(17) and one H(9) atom. The C(16)-C(17) bond length is 1.39 Å. The C(16)-H(9) bond length is 0.93 Å. In the sixth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-C(20) bond length is 1.50 Å. In the seventh C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(10) atom. The C(18)-H(10) bond length is 0.93 Å. In the eighth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(17), one O(3), and one O(4) atom. The C(20)-O(3) bond length is 1.27 Å. The C(20)-O(4) bond length is 1.25 Å. In the ninth C site, C(23) is bonded in a distorted single-bond geometry to one C(24) and one H(13) atom. The C(23)-C(24) bond length is 1.39 Å. The C(23)-H(13) bond length is 0.93 Å. In the tenth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(27) atom. The C(24)-C(25) bond length is 1.39 Å. The C(24)-C(27) bond length is 1.48 Å. In the eleventh C site, C(25) is bonded in a distorted single-bond geometry to one C(24) and one H(14) atom. The C(25)-H(14) bond length is 0.93 Å. In the twelfth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one C(24), one O(5), and one O(6) atom. The C(27)-O(5) bond length is 1.26 Å. The C(27)-O(6) bond length is 1.25 Å. In the thirteenth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(16) atom. The C(28)-N(1) bond length is 1.33 Å. The C(28)-H(16) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Ni(1) and two equivalent C(28) atoms. There are seven inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(16) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(13) is bonded in a single-bond geometry to one C(23) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(25) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(28) atom. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(20) atom. In the third O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(20) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one C(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(27) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(27) atom. In the seventh O site, O(7) is bonded in a trigonal non-coplanar geometry to one Ni(1) and two equivalent Zn(1) atoms. Linkers: 8 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3ccc(C([O])=O)cc3)c2)cc1. Metal clusters: 8 [Zn] ,4 [Ni]. The MOF has largest included sphere 10.62 A, density 0.82 g/cm3, surface area 4615.20 m2/g, accessible volume 0.80 cm3/g