(Ru2C22H8S(NO2)4)2(CH)9C3HF2(CF)12 crystallizes in the monoclinic C2/c space group. The structure consists of thirty-six 02329_fluka molecules; four 1,3-difluoropropane molecules; and forty-eight fluoromethane molecules inside a Ru2C22H8S(NO2)4 framework. In the Ru2C22H8S(NO2)4 framework, there are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a distorted square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Ru(1)-N(1) bond length is 2.22 Å. The Ru(1)-O(1) bond length is 2.01 Å. The Ru(1)-O(2) bond length is 2.03 Å. The Ru(1)-O(3) bond length is 2.04 Å. The Ru(1)-O(4) bond length is 2.04 Å. In the second Ru site, Ru(2) is bonded in a distorted square pyramidal geometry to one N(2), one O(5), one O(6), one O(7), and one O(8) atom. The Ru(2)-N(2) bond length is 2.26 Å. The Ru(2)-O(5) bond length is 2.06 Å. The Ru(2)-O(6) bond length is 2.05 Å. The Ru(2)-O(7) bond length is 2.07 Å. The Ru(2)-O(8) bond length is 2.06 Å. There are twenty-four inequivalent C sites. In the first C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one C(8) atom. The C(9)-C(10) bond length is 1.34 Å. The C(9)-C(14) bond length is 1.39 Å. The C(9)-C(8) bond length is 1.47 Å. In the second C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(4) atom. The C(10)-H(4) bond length is 0.95 Å. In the third C site, C(14) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(14)-H(6) bond length is 0.95 Å. In the fourth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(16), one O(5), and one O(6) atom. The C(15)-C(16) bond length is 1.51 Å. The C(15)-O(5) bond length is 1.26 Å. The C(15)-O(6) bond length is 1.26 Å. In the fifth C site, C(16) is bonded in a trigonal planar geometry to one C(15), one C(17), and one C(21) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.38 Å. In the sixth C site, C(17) is bonded in a distorted single-bond geometry to one C(16) and one H(7) atom. The C(17)-H(7) bond length is 0.95 Å. In the seventh C site, C(21) is bonded in a distorted single-bond geometry to one C(16) and one H(10) atom. The C(21)-H(10) bond length is 0.95 Å. In the eighth C site, C(22) is bonded in a distorted single-bond geometry to one C(33) and one H(11) atom. The C(22)-C(33) bond length is 1.38 Å. The C(22)-H(11) bond length is 0.95 Å. In the ninth C site, C(24) is bonded in a distorted single-bond geometry to one C(36) and one H(12) atom. The C(24)-C(36) bond length is 1.36 Å. The C(24)-H(12) bond length is 0.95 Å. In the tenth C site, C(26) is bonded in a distorted single-bond geometry to one C(27) and one N(1) atom. The C(26)-C(27) bond length is 1.41 Å. The C(26)-N(1) bond length is 1.14 Å. In the eleventh C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(29) atom. The C(27)-C(28) bond length is 1.42 Å. The C(27)-C(29) bond length is 1.41 Å. In the twelfth C site, C(28) is bonded in a distorted linear geometry to one C(27) and one N(2) atom. The C(28)-N(2) bond length is 1.13 Å. In the thirteenth C site, C(29) is bonded in a trigonal planar geometry to one C(27), one C(30), and one C(31) atom. The C(29)-C(30) bond length is 1.42 Å. The C(29)-C(31) bond length is 1.44 Å. In the fourteenth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one N(3) atom. The C(30)-N(3) bond length is 1.33 Å. In the fifteenth C site, C(31) is bonded in a distorted single-bond geometry to one C(29) and one N(4) atom. The C(31)-N(4) bond length is 1.34 Å. In the sixteenth C site, C(36) is bonded in a trigonal planar geometry to one C(35) and two equivalent C(24) atoms. The C(36)-C(35) bond length is 1.52 Å. In the seventeenth C site, C(32) is bonded in a distorted bent 120 degrees geometry to one C(33) and two equivalent O(7) atoms. The C(32)-C(33) bond length is 1.50 Å. Both C(32)-O(7) bond lengths are 1.28 Å. In the eighteenth C site, C(33) is bonded in a trigonal planar geometry to one C(32) and two equivalent C(22) atoms. In the nineteenth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(36) and two equivalent O(8) atoms. Both C(35)-O(8) bond lengths are 1.25 Å. In the twentieth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.48 Å. The C(1)-O(1) bond length is 1.27 Å. The C(1)-O(2) bond length is 1.27 Å. In the twenty-first C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.38 Å. In the twenty-second C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.95 Å. In the twenty-third C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(7)-H(3) bond length is 0.95 Å. In the twenty-fourth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(9), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.27 Å. The C(8)-O(4) bond length is 1.27 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Ru(1) and one C(26) atom. In the second N site, N(2) is bonded in a bent 150 degrees geometry to one Ru(2) and one C(28) atom. In the third N site, N(3) is bonded in a water-like geometry to one C(30) and one S(1) atom. The N(3)-S(1) bond length is 1.60 Å. In the fourth N site, N(4) is bonded in a water-like geometry to one C(31) and one S(1) atom. The N(4)-S(1) bond length is 1.62 Å. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(10) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(14) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(17) atom. In the sixth H site, H(10) is bonded in a single-bond geometry to one C(21) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(22) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(24) atom. S(1) is bonded in a water-like geometry to one N(3) and one N(4) atom. There are eight inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(1) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(1) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(8) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Ru(1) and one C(8) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Ru(2) and one C(15) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Ru(2) and one C(15) atom. In the seventh O site, O(7) is bonded in a bent 120 degrees geometry to one Ru(2) and one C(32) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Ru(2) and one C(35) atom. Linkers: 24 [O]C(=O)c1cc(F)cc(F)c1 ,8 [O]C(=O)c1cccc(F)c1 ,4 N#C[C](C#N)c1c2c(c([C](C#N)C#N)c3nsnc13)[N]S[N]2. Metal clusters: 16 [Ru]. The MOF has largest included sphere 4.77 A, density 1.44 g/cm3, surface area 3866.98 m2/g, accessible volume 0.35 cm3/g