Zn2C24H10O13 crystallizes in the monoclinic C2/c space group. Zn(1) is bonded to one O(1), one O(2), one O(3), one O(4), one O(5), and one O(7) atom to form corner-sharing ZnO6 octahedra. The corner-sharing octahedral tilt angles are 73°. The Zn(1)-O(1) bond length is 2.10 Å. The Zn(1)-O(2) bond length is 2.09 Å. The Zn(1)-O(3) bond length is 2.13 Å. The Zn(1)-O(4) bond length is 2.24 Å. The Zn(1)-O(5) bond length is 2.02 Å. The Zn(1)-O(7) bond length is 2.08 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2), one C(9), and one H(1) atom. The C(1)-C(2) bond length is 1.39 Å. The C(1)-C(9) bond length is 1.39 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(10), and one C(6) atom. The C(2)-C(10) bond length is 1.50 Å. The C(2)-C(6) bond length is 1.39 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(11), one O(1), and one O(6) atom. The C(3)-C(11) bond length is 1.52 Å. The C(3)-O(1) bond length is 1.25 Å. The C(3)-O(6) bond length is 1.25 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(7), one C(9), and one H(2) atom. The C(4)-C(7) bond length is 1.39 Å. The C(4)-C(9) bond length is 1.40 Å. The C(4)-H(2) bond length is 0.95 Å. In the fifth C site, C(5) is bonded in a bent 120 degrees geometry to one C(9), one O(2), and one O(5) atom. The C(5)-C(9) bond length is 1.50 Å. The C(5)-O(2) bond length is 1.25 Å. The C(5)-O(5) bond length is 1.26 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(2), one C(7), and one H(3) atom. The C(6)-C(7) bond length is 1.39 Å. The C(6)-H(3) bond length is 0.95 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(12), one C(4), and one C(6) atom. The C(7)-C(12) bond length is 1.50 Å. In the eighth C site, C(8) is bonded in a distorted single-bond geometry to one C(10), one C(11), and one H(4) atom. The C(8)-C(10) bond length is 1.40 Å. The C(8)-C(11) bond length is 1.39 Å. The C(8)-H(4) bond length is 0.95 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(1), one C(4), and one C(5) atom. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(2), and one C(8) atom. The C(10)-C(11) bond length is 1.40 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(10), one C(3), and one C(8) atom. In the twelfth C site, C(12) is bonded in a bent 120 degrees geometry to one C(7), one O(3), and one O(4) atom. The C(12)-O(3) bond length is 1.25 Å. The C(12)-O(4) bond length is 1.27 Å. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(6) and one O(7) atom. The H(5)-O(6) bond length is 1.66 Å. The H(5)-O(7) bond length is 0.93 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(3) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the third O site, O(3) is bonded in an L-shaped geometry to one Zn(1) and one C(12) atom. In the fourth O site, O(4) is bonded in an L-shaped geometry to one Zn(1) and one C(12) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(5) atom. In the sixth O site, O(6) is bonded in a distorted water-like geometry to one C(3) and one H(5) atom. In the seventh O site, O(7) is bonded in a distorted water-like geometry to two equivalent Zn(1) and two equivalent H(5) atoms. Linkers: 4 [O]C(=O)c1c[c]cc(-c2cc(C([O])=O)c(-c3cc(C([O])=O)cc(C([O])=O)c3)cc2C([O])=O)c1 ,5 [O]C(=O)c1cc(C([O])=O)cc(-c2cc(C([O])=O)c(-c3cc(C([O])=O)cc(C([O])=O)c3)cc2C([O])=O)c1. Metal clusters: 4 O.O=[C]O[Zn]12(O[C]O1)O[C]O[Zn]1(O[C]=O)(O[C]O1)O[C]O2. The MOF has largest included sphere 6.19 A, density 1.14 g/cm3, surface area 3789.59 m2/g, accessible volume 0.53 cm3/g