CuH8(C3N2)4CuH4(C2N)4(CH)8 crystallizes in the tetragonal P4_2/ncm space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, four CuH4(C2N)4 clusters, and four CuH8(C3N2)4 clusters. In each CuH4(C2N)4 cluster, Cu(2) is bonded in a tetrahedral geometry to four equivalent N(1) atoms. All Cu(2)-N(1) bond lengths are 2.06 Å. There are two inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.32 Å. The C(1)-H(1) bond length is 0.95 Å. In the second C site, C(6) is bonded in a distorted single-bond geometry to one N(1) atom. The C(6)-N(1) bond length is 1.39 Å. N(1) is bonded in a trigonal planar geometry to one Cu(2), one C(1), and one C(6) atom. H(1) is bonded in a single-bond geometry to one C(1) atom. In each CuH8(C3N2)4 cluster, Cu(1) is bonded in a square co-planar geometry to four equivalent N(3) atoms. All Cu(1)-N(3) bond lengths are 2.02 Å. There are three inequivalent C sites. In the first C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(2) atom. The C(2)-N(2) bond length is 1.32 Å. The C(2)-H(2) bond length is 0.95 Å. In the second C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(3) atom. The C(3)-N(3) bond length is 1.33 Å. The C(3)-H(3) bond length is 0.95 Å. In the third C site, C(7) is bonded in a distorted bent 120 degrees geometry to one N(2) and one N(3) atom. The C(7)-N(2) bond length is 1.35 Å. The C(7)-N(3) bond length is 1.36 Å. There are two inequivalent N sites. In the first N site, N(2) is bonded in a bent 120 degrees geometry to one C(2) and one C(7) atom. In the second N site, N(3) is bonded in a trigonal planar geometry to one Cu(1), one C(3), and one C(7) atom. There are two inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(3) atom. Linkers: 13 [CH]1C=N[C]2C=CC=NC2=N1 ,3 c1cnc2nccnc2c1. Metal clusters: 8 [Cu]. The MOF has largest included sphere 5.68 A, density 1.01 g/cm3, surface area 4585.03 m2/g, accessible volume 0.54 cm3/g