In3C47N3O11 crystallizes in the tetragonal I-4 space group. There are three inequivalent In sites. In the first In site, In(1) is bonded to one N(1), one O(1), one O(2), one O(5), one O(6), and one O(7) atom to form corner-sharing InNO5 octahedra. The In(1)-N(1) bond length is 2.16 Å. The In(1)-O(1) bond length is 2.03 Å. The In(1)-O(2) bond length is 2.14 Å. The In(1)-O(5) bond length is 2.14 Å. The In(1)-O(6) bond length is 2.10 Å. The In(1)-O(7) bond length is 2.14 Å. In the second In site, In(2) is bonded to one N(3), one O(1), one O(10), one O(4), and one O(9) atom to form InNO4 square pyramids that share  a cornercorner with one In(1)NO5 octahedra and  a cornercorner with one In(3)NO4 square pyramid. The corner-sharing octahedral tilt angles are 60°. The In(2)-N(3) bond length is 2.19 Å. The In(2)-O(1) bond length is 2.04 Å. The In(2)-O(10) bond length is 2.14 Å. The In(2)-O(4) bond length is 2.18 Å. The In(2)-O(9) bond length is 2.16 Å. In the third In site, In(3) is bonded to one N(2), one O(1), one O(11), one O(3), and one O(8) atom to form InNO4 square pyramids that share  a cornercorner with one In(1)NO5 octahedra and  a cornercorner with one In(2)NO4 square pyramid. The corner-sharing octahedral tilt angles are 59°. The In(3)-N(2) bond length is 2.22 Å. The In(3)-O(1) bond length is 2.02 Å. The In(3)-O(11) bond length is 2.16 Å. The In(3)-O(3) bond length is 2.16 Å. The In(3)-O(8) bond length is 2.15 Å. There are forty-seven inequivalent C sites. In the first C site, C(1) is bonded in a bent 120 degrees geometry to one C(8), one O(10), and one O(5) atom. The C(1)-C(8) bond length is 1.43 Å. The C(1)-O(10) bond length is 1.24 Å. The C(1)-O(5) bond length is 1.26 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(14), one C(3), and one C(30) atom. The C(2)-C(14) bond length is 1.41 Å. The C(2)-C(3) bond length is 1.45 Å. The C(2)-C(30) bond length is 1.33 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(2), and one O(3) atom. The C(3)-O(2) bond length is 1.25 Å. The C(3)-O(3) bond length is 1.28 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(12), one C(29), and one C(5) atom. The C(4)-C(12) bond length is 1.37 Å. The C(4)-C(29) bond length is 1.34 Å. The C(4)-C(5) bond length is 1.43 Å. In the fifth C site, C(5) is bonded in a bent 120 degrees geometry to one C(4), one O(4), and one O(7) atom. The C(5)-O(4) bond length is 1.23 Å. The C(5)-O(7) bond length is 1.28 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one C(15), one C(36), and one C(40) atom. The C(6)-C(15) bond length is 1.37 Å. The C(6)-C(36) bond length is 1.34 Å. The C(6)-C(40) bond length is 1.48 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(17), one C(25), and one C(35) atom. The C(7)-C(17) bond length is 1.49 Å. The C(7)-C(25) bond length is 1.30 Å. The C(7)-C(35) bond length is 1.34 Å. In the eighth C site, C(8) is bonded in a trigonal planar geometry to one C(1), one C(27), and one C(38) atom. The C(8)-C(27) bond length is 1.33 Å. The C(8)-C(38) bond length is 1.35 Å. In the ninth C site, C(9) is bonded in a bent 120 degrees geometry to one C(16) and one C(23) atom. The C(9)-C(16) bond length is 1.37 Å. The C(9)-C(23) bond length is 1.31 Å. In the tenth C site, C(10) is bonded in a bent 120 degrees geometry to one C(11) and one C(23) atom. The C(10)-C(11) bond length is 1.43 Å. The C(10)-C(23) bond length is 1.37 Å. In the eleventh C site, C(11) is bonded in a single-bond geometry to one C(10) and one N(1) atom. The C(11)-N(1) bond length is 1.37 Å. In the twelfth C site, C(12) is bonded in a bent 120 degrees geometry to one C(15) and one C(4) atom. The C(12)-C(15) bond length is 1.40 Å. In the thirteenth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(21), one O(8), and one O(9) atom. The C(13)-C(21) bond length is 1.39 Å. The C(13)-O(8) bond length is 1.25 Å. The C(13)-O(9) bond length is 1.30 Å. In the fourteenth C site, C(14) is bonded in a bent 120 degrees geometry to one C(2) and one C(28) atom. The C(14)-C(28) bond length is 1.36 Å. In the fifteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(12) and one C(6) atom. In the sixteenth C site, C(16) is bonded in a single-bond geometry to one C(9) and one N(1) atom. The C(16)-N(1) bond length is 1.40 Å. In the seventeenth C site, C(17) is bonded in a bent 120 degrees geometry to one C(7), one O(11), and one O(6) atom. The C(17)-O(11) bond length is 1.24 Å. The C(17)-O(6) bond length is 1.26 Å. In the eighteenth C site, C(18) is bonded in a single-bond geometry to one C(23) and one C(32) atom. The C(18)-C(23) bond length is 1.55 Å. The C(18)-C(32) bond length is 1.38 Å. In the nineteenth C site, C(19) is bonded in a trigonal planar geometry to one C(28), one C(33), and one C(34) atom. The C(19)-C(28) bond length is 1.31 Å. The C(19)-C(33) bond length is 1.62 Å. The C(19)-C(34) bond length is 1.36 Å. In the twentieth C site, C(20) is bonded in a bent 120 degrees geometry to one C(21) and one C(32) atom. The C(20)-C(21) bond length is 1.37 Å. The C(20)-C(32) bond length is 1.33 Å. In the twenty-first C site, C(21) is bonded in a trigonal planar geometry to one C(13), one C(20), and one C(24) atom. The C(21)-C(24) bond length is 1.38 Å. In the twenty-second C site, C(22) is bonded in a distorted single-bond geometry to one C(26), one C(27), and one C(37) atom. The C(22)-C(26) bond length is 1.31 Å. The C(22)-C(27) bond length is 1.37 Å. The C(22)-C(37) bond length is 1.26 Å. In the twenty-third C site, C(23) is bonded in a trigonal planar geometry to one C(10), one C(18), and one C(9) atom. In the twenty-fourth C site, C(24) is bonded in a bent 120 degrees geometry to one C(21) and one C(31) atom. The C(24)-C(31) bond length is 1.33 Å. In the twenty-fifth C site, C(25) is bonded in a bent 120 degrees geometry to one C(26) and one C(7) atom. The C(25)-C(26) bond length is 1.39 Å. In the twenty-sixth C site, C(26) is bonded in a trigonal planar geometry to one C(22), one C(25), and one C(39) atom. The C(26)-C(39) bond length is 1.29 Å. In the twenty-seventh C site, C(27) is bonded in a bent 120 degrees geometry to one C(22) and one C(8) atom. In the twenty-eighth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(14) and one C(19) atom. In the twenty-ninth C site, C(29) is bonded in a bent 120 degrees geometry to one C(36) and one C(4) atom. The C(29)-C(36) bond length is 1.39 Å. In the thirtieth C site, C(30) is bonded in a bent 120 degrees geometry to one C(2) and one C(34) atom. The C(30)-C(34) bond length is 1.44 Å. In the thirty-first C site, C(31) is bonded in a single-bond geometry to one C(24) atom. In the thirty-second C site, C(32) is bonded in a bent 120 degrees geometry to one C(18) and one C(20) atom. In the thirty-third C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(19) and one C(43) atom. The C(33)-C(43) bond length is 1.28 Å. In the thirty-fourth C site, C(34) is bonded in a bent 120 degrees geometry to one C(19) and one C(30) atom. In the thirty-fifth C site, C(35) is bonded in a distorted water-like geometry to one C(37) and one C(7) atom. The C(35)-C(37) bond length is 1.76 Å. In the thirty-sixth C site, C(36) is bonded in a bent 120 degrees geometry to one C(29) and one C(6) atom. In the thirty-seventh C site, C(37) is bonded in a distorted single-bond geometry to one C(22) and one C(35) atom. In the thirty-eighth C site, C(38) is bonded in a bent 120 degrees geometry to one C(39) and one C(8) atom. The C(38)-C(39) bond length is 1.60 Å. In the thirty-ninth C site, C(39) is bonded in a bent 120 degrees geometry to one C(26) and one C(38) atom. In the fortieth C site, C(40) is bonded in a trigonal planar geometry to one C(42), one C(47), and one C(6) atom. The C(40)-C(42) bond length is 1.32 Å. The C(40)-C(47) bond length is 1.51 Å. In the forty-first C site, C(41) is bonded in a single-bond geometry to one C(47) and one N(3) atom. The C(41)-C(47) bond length is 1.54 Å. The C(41)-N(3) bond length is 1.16 Å. In the forty-second C site, C(42) is bonded in a bent 120 degrees geometry to one C(40) and one C(44) atom. The C(42)-C(44) bond length is 1.35 Å. In the forty-third C site, C(43) is bonded in a bent 120 degrees geometry to one C(33) and one C(46) atom. The C(43)-C(46) bond length is 1.46 Å. In the forty-fourth C site, C(44) is bonded in a single-bond geometry to one C(42) and one N(3) atom. The C(44)-N(3) bond length is 1.12 Å. In the forty-fifth C site, C(45) is bonded in a single-bond geometry to one N(2) atom. The C(45)-N(2) bond length is 1.51 Å. In the forty-sixth C site, C(46) is bonded in a single-bond geometry to one C(43) and one N(2) atom. The C(46)-N(2) bond length is 1.09 Å. In the forty-seventh C site, C(47) is bonded in a water-like geometry to one C(40) and one C(41) atom. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one In(1), one C(11), and one C(16) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one In(3), one C(45), and one C(46) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one In(2), one C(41), and one C(44) atom. There are eleven inequivalent O sites. In the first O site, O(10) is bonded in a distorted bent 150 degrees geometry to one In(2) and one C(1) atom. In the second O site, O(11) is bonded in a distorted bent 150 degrees geometry to one In(3) and one C(17) atom. In the third O site, O(1) is bonded in a trigonal planar geometry to one In(1), one In(2), and one In(3) atom. In the fourth O site, O(2) is bonded in a distorted bent 120 degrees geometry to one In(1) and one C(3) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one In(3) and one C(3) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one In(2) and one C(5) atom. In the seventh O site, O(5) is bonded in a distorted bent 120 degrees geometry to one In(1) and one C(1) atom. In the eighth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one In(1) and one C(17) atom. In the ninth O site, O(7) is bonded in a distorted bent 150 degrees geometry to one In(1) and one C(5) atom. In the tenth O site, O(8) is bonded in a distorted bent 150 degrees geometry to one In(3) and one C(13) atom. In the eleventh O site, O(9) is bonded in a bent 120 degrees geometry to one In(2) and one C(13) atom. Linkers: 8 [O]C(=O)c1[c][c]c([C]2[C][C]N=[C][C]2)[c][c]1 ,8 [O]C(=O)C1=[C]c2[c][c]c(C([O])=O)[c]c2[C][C]1 ,8 [O]C(=O)c1[c][c]c(-c2[c][c]n[c][c]2)[c][c]1. Metal clusters: 24 [In]. The MOF has largest included sphere 13.92 A, density 0.62 g/cm3, surface area 3736.04 m2/g, accessible volume 1.20 cm3/g