ZnC10H10(NO)4(CH2)6 is Indium-derived structured and crystallizes in the orthorhombic P2_12_12_1 space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules and four ZnC10H10(NO)4 clusters. In each ZnC10H10(NO)4 cluster, Zn(1) is bonded in a distorted tetrahedral geometry to one N(1), one N(4), one O(1), and one O(3) atom. The Zn(1)-N(1) bond length is 2.00 Å. The Zn(1)-N(4) bond length is 2.04 Å. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(3) bond length is 2.01 Å. There are ten inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(1) atom. The C(1)-N(1) bond length is 1.34 Å. The C(1)-N(2) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.96 Å. In the second C site, C(2) is bonded in a 3-coordinate geometry to one C(3), one N(1), and one H(2) atom. The C(2)-C(3) bond length is 1.33 Å. The C(2)-N(1) bond length is 1.36 Å. The C(2)-H(2) bond length is 0.95 Å. In the third C site, C(3) is bonded in a 3-coordinate geometry to one C(2), one N(2), and one H(3) atom. The C(3)-N(2) bond length is 1.31 Å. The C(3)-H(3) bond length is 1.00 Å. In the fourth C site, C(4) is bonded in a 3-coordinate geometry to one N(2), one H(4), and one H(5) atom. The C(4)-N(2) bond length is 1.47 Å. The C(4)-H(4) bond length is 0.96 Å. The C(4)-H(5) bond length is 0.96 Å. In the fifth C site, C(5) is bonded in a 3-coordinate geometry to one N(3), one H(6), and one H(7) atom. The C(5)-N(3) bond length is 1.49 Å. The C(5)-H(6) bond length is 0.96 Å. The C(5)-H(7) bond length is 0.96 Å. In the sixth C site, C(6) is bonded in a trigonal planar geometry to one N(3), one N(4), and one H(8) atom. The C(6)-N(3) bond length is 1.34 Å. The C(6)-N(4) bond length is 1.38 Å. The C(6)-H(8) bond length is 0.96 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(8), one N(3), and one H(9) atom. The C(7)-C(8) bond length is 1.33 Å. The C(7)-N(3) bond length is 1.49 Å. The C(7)-H(9) bond length is 1.00 Å. In the eighth C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(7), one N(4), and one H(10) atom. The C(8)-N(4) bond length is 1.37 Å. The C(8)-H(10) bond length is 0.95 Å. In the ninth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(9)-O(1) bond length is 1.26 Å. The C(9)-O(2) bond length is 1.23 Å. In the tenth C site, C(16) is bonded in a distorted bent 120 degrees geometry to one O(3) and one O(4) atom. The C(16)-O(3) bond length is 1.28 Å. The C(16)-O(4) bond length is 1.22 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one C(5), one C(6), and one C(7) atom. In the fourth N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(6), and one C(8) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(5) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(5) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(6) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(7) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(8) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(9) atom. In the second O site, O(2) is bonded in a single-bond geometry to one C(9) atom. In the third O site, O(3) is bonded in a water-like geometry to one Zn(1) and one C(16) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(16) atom. Linkers: 2 [O]C(=O)CCCCCCC([O])=O ,1 [CH2].[CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH]=N[CH2].[CH]=N[CH2].[CH][CH][CH][CH2].[CH][N].[CH][N].[CH][N].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=N[CH].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]N([CH2])[C][CH][N].[C][C].[C][C].[C][N].[C][N].[C][N][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N][CH]C[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][C]=O.[O][Zn].[O][Zn].[Zn].[Zn].[Zn].[Zn] ,1 [CH2].[CH2].[CH2].[CH2].[CH2].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH].[CH][N].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C].[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]=O.[C]C=[N].[C][CH2].[C][CH]CC[CH2].[C][CH][C]O[Zn]([N])O[C]=O.[C][C].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[H].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[N].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O].[O][Zn].[O][Zn]O[C]=O.[Zn].[Zn].[Zn] ,1 [CH2]CCCCCC(=O)O[Zn](OC(=O)CC[CH2])(N1[CH]N(CCN2[CH][CH][N][CH]2)C=C1)N1[CH]N(CCN2[CH][CH][N][CH]2)C=C1 ,1 [CH]C[CH]C(=O)O[Zn](O[C]=O)(N1[CH]N(CCN2[CH][CH][N][CH]2)C=C1)N1[CH]N(CCN2[CH][CH][N][CH]2)C=C1. Metal clusters: 2 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.06 A, density 1.31 g/cm3, surface area 5116.95 m2/g, accessible volume 0.28 cm3/g