Dy2C61H34O18(CH)8 crystallizes in the orthorhombic Pna2_1 space group. The structure consists of thirty-two 02329_fluka molecules inside a Dy2C61H34O18 framework. In the Dy2C61H34O18 framework, there are two inequivalent Dy sites. In the first Dy site, Dy(1) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(16), one O(17), one O(2), one O(4), and one O(7) atom. The Dy(1)-O(10) bond length is 2.88 Å. The Dy(1)-O(11) bond length is 2.40 Å. The Dy(1)-O(16) bond length is 2.45 Å. The Dy(1)-O(17) bond length is 2.43 Å. The Dy(1)-O(2) bond length is 2.36 Å. The Dy(1)-O(4) bond length is 2.34 Å. The Dy(1)-O(7) bond length is 2.34 Å. In the second Dy site, Dy(2) is bonded in a 6-coordinate geometry to one O(1), one O(10), one O(14), one O(4), one O(5), and one O(8) atom. The Dy(2)-O(1) bond length is 2.32 Å. The Dy(2)-O(10) bond length is 2.27 Å. The Dy(2)-O(14) bond length is 2.30 Å. The Dy(2)-O(4) bond length is 2.68 Å. The Dy(2)-O(5) bond length is 2.40 Å. The Dy(2)-O(8) bond length is 2.33 Å. There are sixty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(10), one C(2), and one O(3) atom. The C(1)-C(10) bond length is 1.38 Å. The C(1)-C(2) bond length is 1.41 Å. The C(1)-O(3) bond length is 1.37 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(22), and one C(3) atom. The C(2)-C(22) bond length is 1.51 Å. The C(2)-C(3) bond length is 1.35 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2), one C(4), and one H(7) atom. The C(3)-C(4) bond length is 1.40 Å. The C(3)-H(7) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(9) atom. The C(4)-C(5) bond length is 1.43 Å. The C(4)-C(9) bond length is 1.41 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(8) atom. The C(5)-H(8) bond length is 0.93 Å. In the sixth C site, C(8) is bonded in a distorted single-bond geometry to one C(9) and one H(11) atom. The C(8)-C(9) bond length is 1.44 Å. The C(8)-H(11) bond length is 0.93 Å. In the seventh C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(8) atom. The C(9)-C(10) bond length is 1.42 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(1), one C(11), and one C(9) atom. The C(10)-C(11) bond length is 1.52 Å. In the ninth C site, C(11) is bonded in a water-like geometry to one C(10), one C(12), one H(12), and one H(13) atom. The C(11)-C(12) bond length is 1.50 Å. The C(11)-H(12) bond length is 0.97 Å. The C(11)-H(13) bond length is 0.97 Å. In the tenth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(21) atom. The C(12)-C(13) bond length is 1.44 Å. The C(12)-C(21) bond length is 1.38 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(18) atom. The C(13)-C(14) bond length is 1.44 Å. The C(13)-C(18) bond length is 1.43 Å. In the twelfth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(14) atom. The C(14)-H(14) bond length is 0.93 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(16) and one H(15) atom. The C(15)-C(16) bond length is 1.40 Å. The C(15)-H(15) bond length is 0.93 Å. In the fourteenth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(15), one C(17), and one H(16) atom. The C(16)-C(17) bond length is 1.34 Å. The C(16)-H(16) bond length is 0.93 Å. In the fifteenth C site, C(17) is bonded in a distorted single-bond geometry to one C(16), one C(18), and one H(17) atom. The C(17)-C(18) bond length is 1.43 Å. The C(17)-H(17) bond length is 0.93 Å. In the sixteenth C site, C(18) is bonded in a trigonal planar geometry to one C(13), one C(17), and one C(19) atom. The C(18)-C(19) bond length is 1.38 Å. In the seventeenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(18) atom. The C(19)-C(20) bond length is 1.38 Å. The C(19)-H(18) bond length is 0.93 Å. In the eighteenth C site, C(20) is bonded in a trigonal planar geometry to one C(19), one C(21), and one C(23) atom. The C(20)-C(21) bond length is 1.43 Å. The C(20)-C(23) bond length is 1.48 Å. In the nineteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(12), one C(20), and one O(6) atom. The C(21)-O(6) bond length is 1.35 Å. In the twentieth C site, C(22) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(22)-O(1) bond length is 1.27 Å. The C(22)-O(2) bond length is 1.26 Å. In the twenty-first C site, C(23) is bonded in a bent 120 degrees geometry to one C(20), one O(4), and one O(5) atom. The C(23)-O(4) bond length is 1.26 Å. The C(23)-O(5) bond length is 1.28 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(25), one C(33), and one O(9) atom. The C(24)-C(25) bond length is 1.46 Å. The C(24)-C(33) bond length is 1.38 Å. The C(24)-O(9) bond length is 1.36 Å. In the twenty-third C site, C(25) is bonded in a trigonal planar geometry to one C(24), one C(26), and one C(45) atom. The C(25)-C(26) bond length is 1.35 Å. The C(25)-C(45) bond length is 1.51 Å. In the twenty-fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(25), one C(27), and one H(19) atom. The C(26)-C(27) bond length is 1.42 Å. The C(26)-H(19) bond length is 0.93 Å. In the twenty-fifth C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(32) atom. The C(27)-C(28) bond length is 1.38 Å. The C(27)-C(32) bond length is 1.43 Å. In the twenty-sixth C site, C(28) is bonded in a distorted single-bond geometry to one C(27) and one H(20) atom. The C(28)-H(20) bond length is 0.93 Å. In the twenty-seventh C site, C(31) is bonded in a distorted single-bond geometry to one C(32) and one H(23) atom. The C(31)-C(32) bond length is 1.44 Å. The C(31)-H(23) bond length is 0.93 Å. In the twenty-eighth C site, C(32) is bonded in a trigonal planar geometry to one C(27), one C(31), and one C(33) atom. The C(32)-C(33) bond length is 1.42 Å. In the twenty-ninth C site, C(33) is bonded in a trigonal planar geometry to one C(24), one C(32), and one C(34) atom. The C(33)-C(34) bond length is 1.51 Å. In the thirtieth C site, C(34) is bonded in a water-like geometry to one C(33); one C(35); and two equivalent H(24,25) atoms. The C(34)-C(35) bond length is 1.52 Å. Both C(34)-H(24,25) bond lengths are 0.97 Å. In the thirty-first C site, C(35) is bonded in a trigonal planar geometry to one C(34), one C(36), and one C(44) atom. The C(35)-C(36) bond length is 1.42 Å. The C(35)-C(44) bond length is 1.41 Å. In the thirty-second C site, C(36) is bonded in a trigonal planar geometry to one C(35), one C(37), and one C(41) atom. The C(36)-C(37) bond length is 1.44 Å. The C(36)-C(41) bond length is 1.43 Å. In the thirty-third C site, C(37) is bonded in a single-bond geometry to one C(36) and one H(26) atom. The C(37)-H(26) bond length is 0.93 Å. In the thirty-fourth C site, C(38) is bonded in a distorted single-bond geometry to one C(39) and one H(27) atom. The C(38)-C(39) bond length is 1.40 Å. The C(38)-H(27) bond length is 0.93 Å. In the thirty-fifth C site, C(39) is bonded in a distorted trigonal planar geometry to one C(38), one C(40), and one H(28) atom. The C(39)-C(40) bond length is 1.37 Å. The C(39)-H(28) bond length is 0.93 Å. In the thirty-sixth C site, C(40) is bonded in a distorted single-bond geometry to one C(39), one C(41), and one H(29) atom. The C(40)-C(41) bond length is 1.41 Å. The C(40)-H(29) bond length is 0.93 Å. In the thirty-seventh C site, C(41) is bonded in a trigonal planar geometry to one C(36), one C(40), and one C(42) atom. The C(41)-C(42) bond length is 1.39 Å. In the thirty-eighth C site, C(42) is bonded in a distorted single-bond geometry to one C(41), one C(43), and one H(30) atom. The C(42)-C(43) bond length is 1.37 Å. The C(42)-H(30) bond length is 0.93 Å. In the thirty-ninth C site, C(43) is bonded in a trigonal planar geometry to one C(42), one C(44), and one C(46) atom. The C(43)-C(44) bond length is 1.40 Å. The C(43)-C(46) bond length is 1.49 Å. In the fortieth C site, C(44) is bonded in a distorted single-bond geometry to one C(35), one C(43), and one O(12) atom. The C(44)-O(12) bond length is 1.36 Å. In the forty-first C site, C(45) is bonded in a distorted bent 120 degrees geometry to one C(25), one O(7), and one O(8) atom. The C(45)-O(7) bond length is 1.22 Å. The C(45)-O(8) bond length is 1.30 Å. In the forty-second C site, C(46) is bonded in a bent 120 degrees geometry to one C(43), one O(10), and one O(11) atom. The C(46)-O(10) bond length is 1.26 Å. The C(46)-O(11) bond length is 1.25 Å. In the forty-third C site, C(47) is bonded in a distorted single-bond geometry to one C(48), one C(56), and one O(15) atom. The C(47)-C(48) bond length is 1.43 Å. The C(47)-C(56) bond length is 1.39 Å. The C(47)-O(15) bond length is 1.38 Å. In the forty-fourth C site, C(48) is bonded in a trigonal planar geometry to one C(47), one C(49), and one C(68) atom. The C(48)-C(49) bond length is 1.35 Å. The C(48)-C(68) bond length is 1.51 Å. In the forty-fifth C site, C(49) is bonded in a distorted single-bond geometry to one C(48), one C(50), and one H(31) atom. The C(49)-C(50) bond length is 1.40 Å. The C(49)-H(31) bond length is 0.93 Å. In the forty-sixth C site, C(50) is bonded in a trigonal planar geometry to one C(49), one C(51), and one C(55) atom. The C(50)-C(51) bond length is 1.41 Å. The C(50)-C(55) bond length is 1.42 Å. In the forty-seventh C site, C(51) is bonded in a distorted single-bond geometry to one C(50) and one H(32) atom. The C(51)-H(32) bond length is 0.93 Å. In the forty-eighth C site, C(54) is bonded in a distorted single-bond geometry to one C(55) and one H(35) atom. The C(54)-C(55) bond length is 1.44 Å. The C(54)-H(35) bond length is 0.93 Å. In the forty-ninth C site, C(55) is bonded in a trigonal planar geometry to one C(50), one C(54), and one C(56) atom. The C(55)-C(56) bond length is 1.40 Å. In the fiftieth C site, C(56) is bonded in a trigonal planar geometry to one C(47), one C(55), and one C(57) atom. The C(56)-C(57) bond length is 1.52 Å. In the fifty-first C site, C(57) is bonded in a water-like geometry to one C(56), one C(58), one H(36), and one H(37) atom. The C(57)-C(58) bond length is 1.52 Å. The C(57)-H(36) bond length is 0.97 Å. The C(57)-H(37) bond length is 0.97 Å. In the fifty-second C site, C(58) is bonded in a trigonal planar geometry to one C(57), one C(59), and one C(67) atom. The C(58)-C(59) bond length is 1.44 Å. The C(58)-C(67) bond length is 1.38 Å. In the fifty-third C site, C(59) is bonded in a trigonal planar geometry to one C(58), one C(60), and one C(64) atom. The C(59)-C(60) bond length is 1.41 Å. The C(59)-C(64) bond length is 1.42 Å. In the fifty-fourth C site, C(60) is bonded in a distorted single-bond geometry to one C(59) and one H(38) atom. The C(60)-H(38) bond length is 0.93 Å. In the fifty-fifth C site, C(63) is bonded in a distorted single-bond geometry to one C(64) and one H(41) atom. The C(63)-C(64) bond length is 1.39 Å. The C(63)-H(41) bond length is 0.93 Å. In the fifty-sixth C site, C(64) is bonded in a trigonal planar geometry to one C(59), one C(63), and one C(65) atom. The C(64)-C(65) bond length is 1.42 Å. In the fifty-seventh C site, C(65) is bonded in a distorted single-bond geometry to one C(64), one C(66), and one H(42) atom. The C(65)-C(66) bond length is 1.37 Å. The C(65)-H(42) bond length is 0.93 Å. In the fifty-eighth C site, C(66) is bonded in a trigonal planar geometry to one C(65), one C(67), and one C(69) atom. The C(66)-C(67) bond length is 1.43 Å. The C(66)-C(69) bond length is 1.49 Å. In the fifty-ninth C site, C(67) is bonded in a distorted single-bond geometry to one C(58), one C(66), and one O(18) atom. The C(67)-O(18) bond length is 1.35 Å. In the sixtieth C site, C(68) is bonded in a distorted bent 120 degrees geometry to one C(48), one O(13), and one O(14) atom. The C(68)-O(13) bond length is 1.21 Å. The C(68)-O(14) bond length is 1.29 Å. In the sixty-first C site, C(69) is bonded in a distorted bent 120 degrees geometry to one C(66), one O(16), and one O(17) atom. The C(69)-O(16) bond length is 1.24 Å. The C(69)-O(17) bond length is 1.29 Å. There are thirty-three inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(3) atom. The H(1)-O(3) bond length is 0.82 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(6) atom. The H(2)-O(6) bond length is 0.82 Å. In the third H site, H(3) is bonded in a single-bond geometry to one O(9) atom. The H(3)-O(9) bond length is 0.82 Å. In the fourth H site, H(4) is bonded in a single-bond geometry to one O(12) atom. The H(4)-O(12) bond length is 0.82 Å. In the fifth H site, H(5) is bonded in a single-bond geometry to one O(15) atom. The H(5)-O(15) bond length is 0.82 Å. In the sixth H site, H(6) is bonded in a single-bond geometry to one O(18) atom. The H(6)-O(18) bond length is 0.82 Å. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(3) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(5) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(8) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(11) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(11) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(14) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(15) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(16) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(17) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one C(26) atom. In the eighteenth H site, H(20) is bonded in a single-bond geometry to one C(28) atom. In the nineteenth H site, H(23) is bonded in a single-bond geometry to one C(31) atom. In the twentieth H site, H(24,25) is bonded in a single-bond geometry to one C(34) atom. In the twenty-first H site, H(26) is bonded in a single-bond geometry to one C(37) atom. In the twenty-second H site, H(27) is bonded in a single-bond geometry to one C(38) atom. In the twenty-third H site, H(28) is bonded in a single-bond geometry to one C(39) atom. In the twenty-fourth H site, H(29) is bonded in a single-bond geometry to one C(40) atom. In the twenty-fifth H site, H(30) is bonded in a single-bond geometry to one C(42) atom. In the twenty-sixth H site, H(31) is bonded in a single-bond geometry to one C(49) atom. In the twenty-seventh H site, H(32) is bonded in a single-bond geometry to one C(51) atom. In the twenty-eighth H site, H(35) is bonded in a single-bond geometry to one C(54) atom. In the twenty-ninth H site, H(36) is bonded in a single-bond geometry to one C(57) atom. In the thirtieth H site, H(37) is bonded in a single-bond geometry to one C(57) atom. In the thirty-first H site, H(38) is bonded in a single-bond geometry to one C(60) atom. In the thirty-second H site, H(41) is bonded in a single-bond geometry to one C(63) atom. In the thirty-third H site, H(42) is bonded in a single-bond geometry to one C(65) atom. There are eighteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Dy(2) and one C(22) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Dy(1) and one C(22) atom. In the third O site, O(3) is bonded in a water-like geometry to one C(1) and one H(1) atom. In the fourth O site, O(4) is bonded in a 3-coordinate geometry to one Dy(1), one Dy(2), and one C(23) atom. In the fifth O site, O(5) is bonded in a distorted water-like geometry to one Dy(2) and one C(23) atom. In the sixth O site, O(6) is bonded in a water-like geometry to one C(21) and one H(2) atom. In the seventh O site, O(7) is bonded in a bent 150 degrees geometry to one Dy(1) and one C(45) atom. In the eighth O site, O(8) is bonded in a 2-coordinate geometry to one Dy(2) and one C(45) atom. In the ninth O site, O(9) is bonded in a water-like geometry to one C(24) and one H(3) atom. In the tenth O site, O(10) is bonded in a distorted linear geometry to one Dy(1), one Dy(2), and one C(46) atom. In the eleventh O site, O(11) is bonded in a distorted water-like geometry to one Dy(1) and one C(46) atom. In the twelfth O site, O(12) is bonded in a water-like geometry to one C(44) and one H(4) atom. In the thirteenth O site, O(13) is bonded in a single-bond geometry to one C(68) atom. In the fourteenth O site, O(14) is bonded in a distorted bent 150 degrees geometry to one Dy(2) and one C(68) atom. In the fifteenth O site, O(15) is bonded in a water-like geometry to one C(47) and one H(5) atom. In the sixteenth O site, O(16) is bonded in a distorted single-bond geometry to one Dy(1) and one C(69) atom. In the seventeenth O site, O(17) is bonded in a distorted L-shaped geometry to one Dy(1) and one C(69) atom. In the eighteenth O site, O(18) is bonded in a water-like geometry to one C(67) and one H(6) atom. Linkers: 12 [O]C(=O)c1cc2ccccc2c(Cc2c(O)c(C([O])=O)cc3ccccc23)c1O. Metal clusters: 4 O=[C]O[Dy]123O[C]O[Dy]4(O[C]O1)(O[C]O2)(O[C]O3)O[C]O4. RCSR code: rob. The MOF has largest included sphere 6.68 A, density 1.16 g/cm3, surface area 4000.64 m2/g, accessible volume 0.46 cm3/g