Mn3C21N8H11O9(CH)17(CH2)10(CH3)3 is Indium-derived structured and crystallizes in the tetragonal I4_1/a space group. The structure is zero-dimensional and consists of one hundred and forty-four 02329_fluka molecules, one hundred and sixty 02329_fluka molecules, forty-eight 02329_fluka molecules, thirty-two isobutylene molecules, and eight Mn3C21N8H11O9 clusters. In each Mn3C21N8H11O9 cluster, there are three inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a distorted square pyramidal geometry to one N(1), one N(7), one O(1), one O(3), and one O(8) atom. The Mn(1)-N(1) bond length is 1.93 Å. The Mn(1)-N(7) bond length is 2.24 Å. The Mn(1)-O(1) bond length is 1.87 Å. The Mn(1)-O(3) bond length is 1.94 Å. The Mn(1)-O(8) bond length is 1.97 Å. In the second Mn site, Mn(2) is bonded in a distorted octahedral geometry to one N(2), one N(3), one N(5), one O(2), one O(4), and one O(6) atom. The Mn(2)-N(2) bond length is 2.26 Å. The Mn(2)-N(3) bond length is 1.94 Å. The Mn(2)-N(5) bond length is 2.29 Å. The Mn(2)-O(2) bond length is 1.99 Å. The Mn(2)-O(4) bond length is 1.86 Å. The Mn(2)-O(6) bond length is 1.94 Å. In the third Mn site, Mn(3) is bonded in a distorted octahedral geometry to one N(4), one N(6), one N(8), one O(5), one O(7), and one O(9) atom. The Mn(3)-N(4) bond length is 2.23 Å. The Mn(3)-N(6) bond length is 1.96 Å. The Mn(3)-N(8) bond length is 2.27 Å. The Mn(3)-O(5) bond length is 1.98 Å. The Mn(3)-O(7) bond length is 1.86 Å. The Mn(3)-O(9) bond length is 1.93 Å. There are twenty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(6) and one O(1) atom. The C(1)-C(6) bond length is 1.42 Å. The C(1)-O(1) bond length is 1.33 Å. In the second C site, C(5) is bonded in a distorted single-bond geometry to one C(6) and one H(4) atom. The C(5)-C(6) bond length is 1.39 Å. The C(5)-H(4) bond length is 0.95 Å. In the third C site, C(6) is bonded in a trigonal planar geometry to one C(1), one C(5), and one C(7) atom. The C(6)-C(7) bond length is 1.47 Å. In the fourth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(6), one N(1), and one O(2) atom. The C(7)-N(1) bond length is 1.32 Å. The C(7)-O(2) bond length is 1.28 Å. In the fifth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(9), one N(2), and one O(3) atom. The C(8)-C(9) bond length is 1.50 Å. The C(8)-N(2) bond length is 1.30 Å. The C(8)-O(3) bond length is 1.30 Å. In the sixth C site, C(9) is bonded in a water-like geometry to one C(8) and two equivalent H(5,6) atoms. Both C(9)-H(5,6) bond lengths are 0.99 Å. In the seventh C site, C(14) is bonded in a distorted single-bond geometry to one C(19) and one O(4) atom. The C(14)-C(19) bond length is 1.40 Å. The C(14)-O(4) bond length is 1.33 Å. In the eighth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(19) atom. The C(18)-C(19) bond length is 1.40 Å. The C(18)-H(19) bond length is 0.95 Å. In the ninth C site, C(19) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(20) atom. The C(19)-C(20) bond length is 1.48 Å. In the tenth C site, C(20) is bonded in a distorted bent 120 degrees geometry to one C(19), one N(3), and one O(5) atom. The C(20)-N(3) bond length is 1.32 Å. The C(20)-O(5) bond length is 1.28 Å. In the eleventh C site, C(21) is bonded in a distorted trigonal planar geometry to one C(22), one N(4), and one O(6) atom. The C(21)-C(22) bond length is 1.50 Å. The C(21)-N(4) bond length is 1.30 Å. The C(21)-O(6) bond length is 1.29 Å. In the twelfth C site, C(22) is bonded in a water-like geometry to one C(21) and two equivalent H(20,21) atoms. Both C(22)-H(20,21) bond lengths are 0.99 Å. In the thirteenth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(31) atom. The C(27)-N(5) bond length is 1.31 Å. The C(27)-H(31) bond length is 0.95 Å. In the fourteenth C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(34) atom. The C(31)-N(5) bond length is 1.34 Å. The C(31)-H(34) bond length is 0.95 Å. In the fifteenth C site, C(33) is bonded in a single-bond geometry to one C(38) and one O(7) atom. The C(33)-C(38) bond length is 1.41 Å. The C(33)-O(7) bond length is 1.31 Å. In the sixteenth C site, C(37) is bonded in a distorted single-bond geometry to one C(38) and one H(40) atom. The C(37)-C(38) bond length is 1.40 Å. The C(37)-H(40) bond length is 0.95 Å. In the seventeenth C site, C(38) is bonded in a trigonal planar geometry to one C(33), one C(37), and one C(39) atom. The C(38)-C(39) bond length is 1.47 Å. In the eighteenth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one C(38), one N(6), and one O(8) atom. The C(39)-N(6) bond length is 1.32 Å. The C(39)-O(8) bond length is 1.29 Å. In the nineteenth C site, C(40) is bonded in a distorted bent 120 degrees geometry to one N(7) and one O(9) atom. The C(40)-N(7) bond length is 1.30 Å. The C(40)-O(9) bond length is 1.29 Å. In the twentieth C site, C(46) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(52) atom. The C(46)-N(8) bond length is 1.34 Å. The C(46)-H(52) bond length is 0.95 Å. In the twenty-first C site, C(50) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(55) atom. The C(50)-N(8) bond length is 1.32 Å. The C(50)-H(55) bond length is 0.95 Å. There are eight inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(7), and one N(2) atom. The N(1)-N(2) bond length is 1.42 Å. In the second N site, N(3) is bonded in a 3-coordinate geometry to one Mn(2), one C(20), and one N(4) atom. The N(3)-N(4) bond length is 1.42 Å. In the third N site, N(4) is bonded in a 3-coordinate geometry to one Mn(3), one C(21), and one N(3) atom. In the fourth N site, N(5) is bonded in a trigonal planar geometry to one Mn(2), one C(27), and one C(31) atom. In the fifth N site, N(6) is bonded in a distorted trigonal planar geometry to one Mn(3), one C(39), and one N(7) atom. The N(6)-N(7) bond length is 1.41 Å. In the sixth N site, N(7) is bonded in a 3-coordinate geometry to one Mn(1), one C(40), and one N(6) atom. In the seventh N site, N(8) is bonded in a trigonal planar geometry to one Mn(3), one C(46), and one C(50) atom. In the eighth N site, N(2) is bonded in a 3-coordinate geometry to one Mn(2), one C(8), and one N(1) atom. There are nine inequivalent H sites. In the first H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the second H site, H(5,6) is bonded in a single-bond geometry to one C(9) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the fourth H site, H(20,21) is bonded in a single-bond geometry to one C(22) atom. In the fifth H site, H(31) is bonded in a single-bond geometry to one C(27) atom. In the sixth H site, H(34) is bonded in a single-bond geometry to one C(31) atom. In the seventh H site, H(40) is bonded in a single-bond geometry to one C(37) atom. In the eighth H site, H(52) is bonded in a single-bond geometry to one C(46) atom. In the ninth H site, H(55) is bonded in a single-bond geometry to one C(50) atom. There are nine inequivalent O sites. In the first O site, O(8) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(39) atom. In the second O site, O(9) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(40) atom. In the third O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(7) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(14) atom. In the fifth O site, O(1) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(1) atom. In the sixth O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(20) atom. In the seventh O site, O(6) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(21) atom. In the eighth O site, O(7) is bonded in a bent 120 degrees geometry to one Mn(3) and one C(33) atom. In the ninth O site, O(3) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(8) atom. Linkers: 46 CCCCCC(=O)[N][N]C(=O)c1ccccc1[O] ,16 c1cc(CCc2ccncc2)ccn1. Metal clusters: 48 [Mn]. The MOF has largest included sphere 8.90 A, density 1.00 g/cm3, surface area 5058.60 m2/g, accessible volume 0.46 cm3/g