Zn(CO2)4(CH2)2(CH)2 is Indium-derived structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules, eight 02329_fluka molecules, and four Zn(CO2)4 clusters. In each Zn(CO2)4 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent O(1) and two equivalent O(6) atoms. Both Zn(1)-O(1) bond lengths are 1.99 Å. Both Zn(1)-O(6) bond lengths are 1.98 Å. There are two inequivalent C sites. In the first C site, C(8) is bonded in a distorted bent 120 degrees geometry to one O(6) and one O(7) atom. The C(8)-O(6) bond length is 1.30 Å. The C(8)-O(7) bond length is 1.24 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(8) atom. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(8) bond length is 1.29 Å. There are four inequivalent O sites. In the first O site, O(6) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(8) atom. In the second O site, O(7) is bonded in a single-bond geometry to one C(8) atom. In the third O site, O(8) is bonded in a single-bond geometry to one C(1) atom. In the fourth O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(1) atom. Linkers: 4 [O]C(=O)C[C@H](C([O])=O)[C@@H](CC([O])=O)C([O])=O. Metal clusters: 2 [O][C]O[Zn](O[C][O])(O[C]=O)O[C]=O ,2 O=[C]O[Zn](O[C]=O)(O[C]=O)O[C]=O. RCSR code: pts. The MOF has largest included sphere 4.01 A, density 1.26 g/cm3, surface area 4481.15 m2/g, accessible volume 0.41 cm3/g