CuH20(C7N6)2(CH2)6 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of twenty-four 02329_fluka molecules and four CuH20(C7N6)2 clusters. In each CuH20(C7N6)2 cluster, Cu(1) is bonded in a rectangular see-saw-like geometry to one N(1), one N(10), one N(6), and one N(7) atom. The Cu(1)-N(1) bond length is 1.97 Å. The Cu(1)-N(10) bond length is 2.00 Å. The Cu(1)-N(6) bond length is 2.06 Å. The Cu(1)-N(7) bond length is 1.98 Å. There are fourteen inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one N(1), one N(3), and one H(1) atom. The C(1)-N(1) bond length is 1.39 Å. The C(1)-N(3) bond length is 1.31 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one N(1), one N(2), and one H(2) atom. The C(2)-N(1) bond length is 1.20 Å. The C(2)-N(2) bond length is 1.36 Å. The C(2)-H(2) bond length is 0.93 Å. In the third C site, C(3) is bonded in a 4-coordinate geometry to one C(4), one N(2), one H(3), and one H(4) atom. The C(3)-C(4) bond length is 1.36 Å. The C(3)-N(2) bond length is 1.47 Å. The C(3)-H(3) bond length is 0.97 Å. The C(3)-H(4) bond length is 0.97 Å. In the fourth C site, C(4) is bonded in a distorted water-like geometry to one C(3), one H(5), and one H(6) atom. The C(4)-H(5) bond length is 0.97 Å. The C(4)-H(6) bond length is 0.97 Å. In the fifth C site, C(9) is bonded in a trigonal planar geometry to one N(7), one N(9), and one H(15) atom. The C(9)-N(7) bond length is 1.34 Å. The C(9)-N(9) bond length is 1.35 Å. The C(9)-H(15) bond length is 0.93 Å. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one N(7), one N(8), and one H(16) atom. The C(10)-N(7) bond length is 1.29 Å. The C(10)-N(8) bond length is 1.28 Å. The C(10)-H(16) bond length is 0.93 Å. In the seventh C site, C(11) is bonded in a 4-coordinate geometry to one C(12), one N(8), one H(17), and one H(18) atom. The C(11)-C(12) bond length is 1.47 Å. The C(11)-N(8) bond length is 1.47 Å. The C(11)-H(17) bond length is 0.96 Å. The C(11)-H(18) bond length is 0.97 Å. In the eighth C site, C(12) is bonded in a water-like geometry to one C(11), one H(19), and one H(20) atom. The C(12)-H(19) bond length is 0.97 Å. The C(12)-H(20) bond length is 0.97 Å. In the ninth C site, C(14) is bonded in a 2-coordinate geometry to one N(11), one H(23), and one H(24) atom. The C(14)-N(11) bond length is 1.53 Å. The C(14)-H(23) bond length is 0.96 Å. The C(14)-H(24) bond length is 0.97 Å. In the tenth C site, C(19) is bonded in a trigonal planar geometry to one N(10), one N(11), and one H(31) atom. The C(19)-N(10) bond length is 1.33 Å. The C(19)-N(11) bond length is 1.33 Å. The C(19)-H(31) bond length is 0.93 Å. In the eleventh C site, C(20) is bonded in a trigonal planar geometry to one N(10), one N(12), and one H(32) atom. The C(20)-N(10) bond length is 1.33 Å. The C(20)-N(12) bond length is 1.34 Å. The C(20)-H(32) bond length is 0.93 Å. In the twelfth C site, C(17) is bonded in a trigonal planar geometry to one N(5), one N(6), and one H(29) atom. The C(17)-N(5) bond length is 1.31 Å. The C(17)-N(6) bond length is 1.31 Å. The C(17)-H(29) bond length is 0.93 Å. In the thirteenth C site, C(18) is bonded in a trigonal planar geometry to one N(4), one N(6), and one H(30) atom. The C(18)-N(4) bond length is 1.31 Å. The C(18)-N(6) bond length is 1.31 Å. The C(18)-H(30) bond length is 0.93 Å. In the fourteenth C site, C(8) is bonded in a 3-coordinate geometry to one N(4), one H(13), and one H(14) atom. The C(8)-N(4) bond length is 1.52 Å. The C(8)-H(13) bond length is 0.97 Å. The C(8)-H(14) bond length is 0.97 Å. There are twelve inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(1), and one C(2) atom. In the second N site, N(2) is bonded in a 3-coordinate geometry to one C(2), one C(3), and one N(3) atom. The N(2)-N(3) bond length is 1.26 Å. In the third N site, N(3) is bonded in a distorted water-like geometry to one C(1) and one N(2) atom. In the fourth N site, N(4) is bonded in a distorted trigonal planar geometry to one C(18), one C(8), and one N(5) atom. The N(4)-N(5) bond length is 1.31 Å. In the fifth N site, N(5) is bonded in a distorted water-like geometry to one C(17) and one N(4) atom. In the sixth N site, N(7) is bonded in a distorted trigonal planar geometry to one Cu(1), one C(10), and one C(9) atom. In the seventh N site, N(8) is bonded in a distorted trigonal planar geometry to one C(10), one C(11), and one N(9) atom. The N(8)-N(9) bond length is 1.33 Å. In the eighth N site, N(9) is bonded in a distorted water-like geometry to one C(9) and one N(8) atom. In the ninth N site, N(10) is bonded in a trigonal planar geometry to one Cu(1), one C(19), and one C(20) atom. In the tenth N site, N(11) is bonded in a distorted bent 120 degrees geometry to one C(14), one C(19), and one N(12) atom. The N(11)-N(12) bond length is 1.33 Å. In the eleventh N site, N(12) is bonded in a distorted water-like geometry to one C(20) and one N(11) atom. In the twelfth N site, N(6) is bonded in a trigonal planar geometry to one Cu(1), one C(17), and one C(18) atom. There are twenty inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(4) atom. In the sixth H site, H(15) is bonded in a single-bond geometry to one C(9) atom. In the seventh H site, H(16) is bonded in a single-bond geometry to one C(10) atom. In the eighth H site, H(17) is bonded in a single-bond geometry to one C(11) atom. In the ninth H site, H(18) is bonded in a single-bond geometry to one C(11) atom. In the tenth H site, H(19) is bonded in a single-bond geometry to one C(12) atom. In the eleventh H site, H(20) is bonded in a single-bond geometry to one C(12) atom. In the twelfth H site, H(23) is bonded in a single-bond geometry to one C(14) atom. In the thirteenth H site, H(24) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth H site, H(29) is bonded in a single-bond geometry to one C(17) atom. In the fifteenth H site, H(30) is bonded in a single-bond geometry to one C(18) atom. In the sixteenth H site, H(31) is bonded in a single-bond geometry to one C(19) atom. In the seventeenth H site, H(32) is bonded in a single-bond geometry to one C(20) atom. In the eighteenth H site, H(6) is bonded in a single-bond geometry to one C(4) atom. In the nineteenth H site, H(13) is bonded in a single-bond geometry to one C(8) atom. In the twentieth H site, H(14) is bonded in a single-bond geometry to one C(8) atom. Linkers: 6 [CH]1N=C[N]N1CCCCCCn1cncn1 ,2 [CH]1N=C[N]N1CCCCCCN1[CH]N=C[N]1. Metal clusters: 4 [Cu]. The MOF has largest included sphere 8.85 A, density 0.85 g/cm3, surface area 5582.91 m2/g, accessible volume 0.68 cm3/g