Ce2C35N6H19O13CH crystallizes in the monoclinic P2_1/c space group. The structure consists of four 02329_fluka molecules inside a Ce2C35N6H19O13 framework. In the Ce2C35N6H19O13 framework, there are two inequivalent Ce sites. In the first Ce site, Ce(1) is bonded in a 8-coordinate geometry to one O(1), one O(11), one O(12), one O(13), one O(3), one O(5), one O(8), and one O(9) atom. The Ce(1)-O(1) bond length is 2.47 Å. The Ce(1)-O(11) bond length is 2.95 Å. The Ce(1)-O(12) bond length is 2.54 Å. The Ce(1)-O(13) bond length is 2.90 Å. The Ce(1)-O(3) bond length is 2.48 Å. The Ce(1)-O(5) bond length is 2.52 Å. The Ce(1)-O(8) bond length is 2.44 Å. The Ce(1)-O(9) bond length is 2.41 Å. In the second Ce site, Ce(2) is bonded in a 7-coordinate geometry to one O(10), one O(11), one O(13), one O(2), one O(4), one O(6), and one O(7) atom. The Ce(2)-O(10) bond length is 2.45 Å. The Ce(2)-O(11) bond length is 2.46 Å. The Ce(2)-O(13) bond length is 2.64 Å. The Ce(2)-O(2) bond length is 2.52 Å. The Ce(2)-O(4) bond length is 2.40 Å. The Ce(2)-O(6) bond length is 2.45 Å. The Ce(2)-O(7) bond length is 2.48 Å. There are thirty-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.47 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.28 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(6) bond length is 1.38 Å. In the third C site, C(3) is bonded in a single-bond geometry to one C(2) and one H(1) atom. The C(3)-H(1) bond length is 0.93 Å. In the fourth C site, C(5) is bonded in a distorted single-bond geometry to one C(7) and one N(1) atom. The C(5)-C(7) bond length is 1.47 Å. The C(5)-N(1) bond length is 1.33 Å. In the fifth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(1), and one H(3) atom. The C(6)-N(1) bond length is 1.33 Å. The C(6)-H(3) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted trigonal planar geometry to one C(5), one C(8), and one N(2) atom. The C(7)-C(8) bond length is 1.36 Å. The C(7)-N(2) bond length is 1.36 Å. In the seventh C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(8)-H(4) bond length is 0.93 Å. In the eighth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(5) atom. The C(9)-C(10) bond length is 1.37 Å. The C(9)-N(2) bond length is 1.34 Å. The C(9)-H(5) bond length is 0.93 Å. In the ninth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(9) atom. The C(10)-C(11) bond length is 1.40 Å. The C(10)-C(12) bond length is 1.48 Å. In the tenth C site, C(11) is bonded in a single-bond geometry to one C(10) and one H(6) atom. The C(11)-H(6) bond length is 0.93 Å. In the eleventh C site, C(12) is bonded in a distorted trigonal planar geometry to one C(10), one O(3), and one O(4) atom. The C(12)-O(3) bond length is 1.23 Å. The C(12)-O(4) bond length is 1.27 Å. In the twelfth C site, C(13) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(5), and one O(6) atom. The C(13)-C(14) bond length is 1.51 Å. The C(13)-O(5) bond length is 1.24 Å. The C(13)-O(6) bond length is 1.29 Å. In the thirteenth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(18) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-C(18) bond length is 1.37 Å. In the fourteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(14), one N(3), and one H(7) atom. The C(15)-N(3) bond length is 1.35 Å. The C(15)-H(7) bond length is 0.93 Å. In the fifteenth C site, C(16) is bonded in a single-bond geometry to one C(17) and one H(8) atom. The C(16)-C(17) bond length is 1.35 Å. The C(16)-H(8) bond length is 0.93 Å. In the sixteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(16), one C(17), and one N(3) atom. The C(17)-C(17) bond length is 1.48 Å. The C(17)-N(3) bond length is 1.39 Å. In the seventeenth C site, C(18) is bonded in a single-bond geometry to one C(14) and one H(9) atom. The C(18)-H(9) bond length is 0.93 Å. In the eighteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(19), one C(20), and one N(4) atom. The C(19)-C(19) bond length is 1.48 Å. The C(19)-C(20) bond length is 1.38 Å. The C(19)-N(4) bond length is 1.35 Å. In the nineteenth C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(10) atom. The C(20)-H(10) bond length is 0.93 Å. In the twentieth C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(11) atom. The C(21)-C(22) bond length is 1.40 Å. The C(21)-H(11) bond length is 0.93 Å. In the twenty-first C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(24) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(24) bond length is 1.46 Å. In the twenty-second C site, C(23) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(4), and one H(12) atom. The C(23)-N(4) bond length is 1.33 Å. The C(23)-H(12) bond length is 0.93 Å. In the twenty-third C site, C(24) is bonded in a bent 120 degrees geometry to one C(22), one O(7), and one O(8) atom. The C(24)-O(7) bond length is 1.27 Å. The C(24)-O(8) bond length is 1.25 Å. In the twenty-fourth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(26), one O(10), and one O(9) atom. The C(25)-C(26) bond length is 1.49 Å. The C(25)-O(10) bond length is 1.24 Å. The C(25)-O(9) bond length is 1.26 Å. In the twenty-fifth C site, C(26) is bonded in a trigonal planar geometry to one C(25), one C(27), and one C(30) atom. The C(26)-C(27) bond length is 1.38 Å. The C(26)-C(30) bond length is 1.39 Å. In the twenty-sixth C site, C(27) is bonded in a distorted single-bond geometry to one C(26) and one H(13) atom. The C(27)-H(13) bond length is 0.93 Å. In the twenty-seventh C site, C(28) is bonded in a single-bond geometry to one C(29) and one H(14) atom. The C(28)-C(29) bond length is 1.37 Å. The C(28)-H(14) bond length is 0.93 Å. In the twenty-eighth C site, C(29) is bonded in a distorted trigonal planar geometry to one C(28), one C(31), and one N(5) atom. The C(29)-C(31) bond length is 1.48 Å. The C(29)-N(5) bond length is 1.33 Å. In the twenty-ninth C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(26), one N(5), and one H(15) atom. The C(30)-N(5) bond length is 1.34 Å. The C(30)-H(15) bond length is 0.93 Å. In the thirtieth C site, C(31) is bonded in a distorted single-bond geometry to one C(29), one C(32), and one N(6) atom. The C(31)-C(32) bond length is 1.36 Å. The C(31)-N(6) bond length is 1.35 Å. In the thirty-first C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(16) atom. The C(32)-H(16) bond length is 0.93 Å. In the thirty-second C site, C(33) is bonded in a distorted single-bond geometry to one C(34) and one H(17) atom. The C(33)-C(34) bond length is 1.40 Å. The C(33)-H(17) bond length is 0.93 Å. In the thirty-third C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(36) atom. The C(34)-C(35) bond length is 1.39 Å. The C(34)-C(36) bond length is 1.50 Å. In the thirty-fourth C site, C(35) is bonded in a distorted bent 120 degrees geometry to one C(34), one N(6), and one H(18) atom. The C(35)-N(6) bond length is 1.33 Å. The C(35)-H(18) bond length is 0.93 Å. In the thirty-fifth C site, C(36) is bonded in a bent 120 degrees geometry to one C(34), one O(11), and one O(12) atom. The C(36)-O(11) bond length is 1.24 Å. The C(36)-O(12) bond length is 1.26 Å. There are six inequivalent N sites. In the first N site, N(2) is bonded in a bent 120 degrees geometry to one C(7) and one C(9) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one C(15) and one C(17) atom. In the third N site, N(4) is bonded in a bent 120 degrees geometry to one C(19) and one C(23) atom. In the fourth N site, N(5) is bonded in a bent 120 degrees geometry to one C(29) and one C(30) atom. In the fifth N site, N(6) is bonded in a bent 120 degrees geometry to one C(31) and one C(35) atom. In the sixth N site, N(1) is bonded in a bent 120 degrees geometry to one C(5) and one C(6) atom. There are nineteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(16) atom. In the eighth H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(27) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(28) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(30) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(32) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(33) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(35) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one O(13) atom. The H(19)-O(13) bond length is 0.97 Å. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one O(13) atom. The H(20)-O(13) bond length is 0.97 Å. There are thirteen inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Ce(1) and one C(1) atom. In the second O site, O(2) is bonded in a distorted bent 150 degrees geometry to one Ce(2) and one C(1) atom. In the third O site, O(3) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one C(12) atom. In the fourth O site, O(4) is bonded in a bent 150 degrees geometry to one Ce(2) and one C(12) atom. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Ce(1) and one C(13) atom. In the sixth O site, O(6) is bonded in a bent 150 degrees geometry to one Ce(2) and one C(13) atom. In the seventh O site, O(7) is bonded in a water-like geometry to one Ce(2) and one C(24) atom. In the eighth O site, O(8) is bonded in a distorted linear geometry to one Ce(1) and one C(24) atom. In the ninth O site, O(9) is bonded in a distorted bent 150 degrees geometry to one Ce(1) and one C(25) atom. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Ce(2) and one C(25) atom. In the eleventh O site, O(11) is bonded in a 2-coordinate geometry to one Ce(1), one Ce(2), and one C(36) atom. In the twelfth O site, O(12) is bonded in a distorted water-like geometry to one Ce(1) and one C(36) atom. In the thirteenth O site, O(13) is bonded in a water-like geometry to one Ce(1), one Ce(2), one H(19), and one H(20) atom. Linkers: 12 [O]C(=O)c1ccc(-c2ccc(C([O])=O)cn2)nc1. Metal clusters: 8 [Ce]. The MOF has largest included sphere 5.96 A, density 1.32 g/cm3, surface area 3561.02 m2/g, accessible volume 0.40 cm3/g