(ZnC12H8(NO2)2)2ZnC13H11(N2O)2ZnC8H6(NO)2(CH)11(C2NH2)2(CNH)4 is Indium-derived structured and crystallizes in the orthorhombic Fdd2 space group. The structure is zero-dimensional and consists of one hundred and seventy-six 02329_fluka molecules; thirty-two 1,2-dimethylhydrazine molecules; sixteen C2NH2 clusters; thirty-two ZnC12H8(NO2)2 clusters; sixteen ZnC13H11(N2O)2 clusters; and sixteen ZnC8H6(NO)2 clusters. In each C2NH2 cluster, there are four inequivalent C sites. In the first C site, C(40) is bonded in a distorted single-bond geometry to one C(41) and one H(30) atom. The C(40)-C(41) bond length is 1.30 Å. The C(40)-H(30) bond length is 0.93 Å. In the second C site, C(41) is bonded in a distorted trigonal planar geometry to one C(40), one C(42), and one N(14) atom. The C(41)-C(42) bond length is 1.37 Å. The C(41)-N(14) bond length is 1.28 Å. In the third C site, C(42) is bonded in a distorted single-bond geometry to one C(41) and one H(31) atom. The C(42)-H(31) bond length is 0.93 Å. In the fourth C site, C(44) is bonded in a distorted single-bond geometry to one N(15) atom. The C(44)-N(15) bond length is 1.37 Å. There are two inequivalent N sites. In the first N site, N(14) is bonded in a 3-coordinate geometry to one C(41), one N(15), and one H(51) atom. The N(14)-N(15) bond length is 1.42 Å. The N(14)-H(51) bond length is 0.86 Å. In the second N site, N(15) is bonded in a distorted single-bond geometry to one C(44), one N(14), and one H(52) atom. The N(15)-H(52) bond length is 0.86 Å. There are four inequivalent H sites. In the first H site, H(51) is bonded in a single-bond geometry to one N(14) atom. In the second H site, H(52) is bonded in a single-bond geometry to one N(15) atom. In the third H site, H(30) is bonded in a single-bond geometry to one C(40) atom. In the fourth H site, H(31) is bonded in a single-bond geometry to one C(42) atom. In each ZnC12H8(NO2)2 cluster, Zn(1) is bonded in a 4-coordinate geometry to one N(16), one N(4), one O(11), and one O(7) atom. The Zn(1)-N(16) bond length is 2.01 Å. The Zn(1)-N(4) bond length is 2.05 Å. The Zn(1)-O(11) bond length is 1.92 Å. The Zn(1)-O(7) bond length is 2.03 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(1) atom. The C(1)-N(4) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(4) and one H(4) atom. The C(5)-N(4) bond length is 1.37 Å. The C(5)-H(4) bond length is 0.93 Å. In the third C site, C(46) is bonded in a distorted bent 120 degrees geometry to one N(16) and one H(34) atom. The C(46)-N(16) bond length is 1.28 Å. The C(46)-H(34) bond length is 0.93 Å. In the fourth C site, C(47) is bonded in a distorted bent 120 degrees geometry to one N(16) and one H(35) atom. The C(47)-N(16) bond length is 1.30 Å. The C(47)-H(35) bond length is 0.93 Å. In the fifth C site, C(52) is bonded in a distorted single-bond geometry to one C(53) and one H(38) atom. The C(52)-C(53) bond length is 1.35 Å. The C(52)-H(38) bond length is 0.93 Å. In the sixth C site, C(53) is bonded in a trigonal planar geometry to one C(52), one C(54), and one C(56) atom. The C(53)-C(54) bond length is 1.40 Å. The C(53)-C(56) bond length is 1.54 Å. In the seventh C site, C(54) is bonded in a distorted single-bond geometry to one C(53) and one H(39) atom. The C(54)-H(39) bond length is 0.93 Å. In the eighth C site, C(56) is bonded in a distorted bent 120 degrees geometry to one C(53), one O(7), and one O(8) atom. The C(56)-O(7) bond length is 1.23 Å. The C(56)-O(8) bond length is 1.28 Å. In the ninth C site, C(60) is bonded in a distorted single-bond geometry to one C(61) and one H(42) atom. The C(60)-C(61) bond length is 1.39 Å. The C(60)-H(42) bond length is 0.93 Å. In the tenth C site, C(61) is bonded in a trigonal planar geometry to one C(60), one C(62), and one C(64) atom. The C(61)-C(62) bond length is 1.37 Å. The C(61)-C(64) bond length is 1.53 Å. In the eleventh C site, C(62) is bonded in a single-bond geometry to one C(61) and one H(43) atom. The C(62)-H(43) bond length is 0.93 Å. In the twelfth C site, C(64) is bonded in a distorted bent 120 degrees geometry to one C(61), one O(11), and one O(12) atom. The C(64)-O(11) bond length is 1.20 Å. The C(64)-O(12) bond length is 1.27 Å. There are two inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. In the second N site, N(16) is bonded in a trigonal planar geometry to one Zn(1), one C(46), and one C(47) atom. There are eight inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(34) is bonded in a single-bond geometry to one C(46) atom. In the fourth H site, H(35) is bonded in a single-bond geometry to one C(47) atom. In the fifth H site, H(38) is bonded in a single-bond geometry to one C(52) atom. In the sixth H site, H(39) is bonded in a single-bond geometry to one C(54) atom. In the seventh H site, H(42) is bonded in a single-bond geometry to one C(60) atom. In the eighth H site, H(43) is bonded in a single-bond geometry to one C(62) atom. There are four inequivalent O sites. In the first O site, O(7) is bonded in a water-like geometry to one Zn(1) and one C(56) atom. In the second O site, O(8) is bonded in a single-bond geometry to one C(56) atom. In the third O site, O(11) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(64) atom. In the fourth O site, O(12) is bonded in a single-bond geometry to one C(64) atom. In each ZnC13H11(N2O)2 cluster, Zn(2) is bonded in a trigonal non-coplanar geometry to one N(1), one N(8), and one O(2) atom. The Zn(2)-N(1) bond length is 2.02 Å. The Zn(2)-N(8) bond length is 2.00 Å. The Zn(2)-O(2) bond length is 1.98 Å. There are thirteen inequivalent C sites. In the first C site, C(6) is bonded in a distorted trigonal planar geometry to one C(7), one N(1), and one H(5) atom. The C(6)-C(7) bond length is 1.36 Å. The C(6)-N(1) bond length is 1.35 Å. The C(6)-H(5) bond length is 0.93 Å. In the second C site, C(7) is bonded in a distorted single-bond geometry to one C(6), one C(8), and one H(6) atom. The C(7)-C(8) bond length is 1.34 Å. The C(7)-H(6) bond length is 0.93 Å. In the third C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one C(8), and one H(7) atom. The C(9)-C(10) bond length is 1.46 Å. The C(9)-C(8) bond length is 1.40 Å. The C(9)-H(7) bond length is 0.93 Å. In the fourth C site, C(10) is bonded in a distorted bent 120 degrees geometry to one C(9), one N(1), and one H(8) atom. The C(10)-N(1) bond length is 1.30 Å. The C(10)-H(8) bond length is 0.93 Å. In the fifth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(1), and one O(2) atom. The C(11)-C(12) bond length is 1.47 Å. The C(11)-O(1) bond length is 1.23 Å. The C(11)-O(2) bond length is 1.28 Å. In the sixth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(17) atom. The C(12)-C(13) bond length is 1.37 Å. The C(12)-C(17) bond length is 1.34 Å. In the seventh C site, C(8) is bonded in a distorted trigonal planar geometry to one C(7), one C(9), and one N(2) atom. The C(8)-N(2) bond length is 1.39 Å. In the eighth C site, C(13) is bonded in a distorted single-bond geometry to one C(12) and one H(9) atom. The C(13)-H(9) bond length is 0.93 Å. In the ninth C site, C(17) is bonded in a single-bond geometry to one C(12) and one H(12) atom. The C(17)-H(12) bond length is 0.93 Å. In the tenth C site, C(25) is bonded in a distorted single-bond geometry to one C(26) and one H(17) atom. The C(25)-C(26) bond length is 1.36 Å. The C(25)-H(17) bond length is 0.93 Å. In the eleventh C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one N(8), and one H(18) atom. The C(26)-N(8) bond length is 1.38 Å. The C(26)-H(18) bond length is 0.93 Å. In the twelfth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(8) and one H(19) atom. The C(27)-N(8) bond length is 1.40 Å. The C(27)-H(19) bond length is 0.93 Å. In the thirteenth C site, C(3) is bonded in a distorted single-bond geometry to one N(3) atom. The C(3)-N(3) bond length is 1.38 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Zn(2), one C(10), and one C(6) atom. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one C(8), one N(3), and one H(45) atom. The N(2)-N(3) bond length is 1.43 Å. The N(2)-H(45) bond length is 0.86 Å. In the third N site, N(8) is bonded in a trigonal planar geometry to one Zn(2), one C(26), and one C(27) atom. In the fourth N site, N(3) is bonded in a distorted trigonal planar geometry to one C(3), one N(2), and one H(46) atom. The N(3)-H(46) bond length is 0.86 Å. There are eleven inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the second H site, H(6) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the fifth H site, H(9) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(17) is bonded in a single-bond geometry to one C(25) atom. In the eighth H site, H(18) is bonded in a single-bond geometry to one C(26) atom. In the ninth H site, H(19) is bonded in a single-bond geometry to one C(27) atom. In the tenth H site, H(45) is bonded in a single-bond geometry to one N(2) atom. In the eleventh H site, H(46) is bonded in a single-bond geometry to one N(3) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(11) atom. In the second O site, O(1) is bonded in a single-bond geometry to one C(11) atom. In each ZnC8H6(NO)2 cluster, Zn(3) is bonded in a trigonal non-coplanar geometry to one N(5), one N(9), and one O(3) atom. The Zn(3)-N(5) bond length is 2.07 Å. The Zn(3)-N(9) bond length is 2.04 Å. The Zn(3)-O(3) bond length is 1.97 Å. There are eight inequivalent C sites. In the first C site, C(14) is bonded in a single-bond geometry to one C(15) and one H(10) atom. The C(14)-C(15) bond length is 1.39 Å. The C(14)-H(10) bond length is 0.93 Å. In the second C site, C(15) is bonded in a trigonal planar geometry to one C(14), one C(16), and one C(18) atom. The C(15)-C(16) bond length is 1.38 Å. The C(15)-C(18) bond length is 1.44 Å. In the third C site, C(16) is bonded in a distorted single-bond geometry to one C(15) and one H(11) atom. The C(16)-H(11) bond length is 0.93 Å. In the fourth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(3), and one O(4) atom. The C(18)-O(3) bond length is 1.28 Å. The C(18)-O(4) bond length is 1.24 Å. In the fifth C site, C(19) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(13) atom. The C(19)-N(5) bond length is 1.33 Å. The C(19)-H(13) bond length is 0.93 Å. In the sixth C site, C(23) is bonded in a distorted bent 120 degrees geometry to one N(5) and one H(16) atom. The C(23)-N(5) bond length is 1.36 Å. The C(23)-H(16) bond length is 0.93 Å. In the seventh C site, C(29) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(21) atom. The C(29)-N(9) bond length is 1.39 Å. The C(29)-H(21) bond length is 0.93 Å. In the eighth C site, C(33) is bonded in a distorted bent 120 degrees geometry to one N(9) and one H(24) atom. The C(33)-N(9) bond length is 1.33 Å. The C(33)-H(24) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(5) is bonded in a trigonal planar geometry to one Zn(3), one C(19), and one C(23) atom. In the second N site, N(9) is bonded in a trigonal planar geometry to one Zn(3), one C(29), and one C(33) atom. There are six inequivalent H sites. In the first H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the second H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the third H site, H(13) is bonded in a single-bond geometry to one C(19) atom. In the fourth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the fifth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the sixth H site, H(24) is bonded in a single-bond geometry to one C(33) atom. There are two inequivalent O sites. In the first O site, O(4) is bonded in a single-bond geometry to one C(18) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(18) atom. Linkers: 12 [O]C(=O)c1ccc(C([O])=O)cc1 ,16 c1cc(NNc2ccncc2)ccn1. Metal clusters: 4 O=[C]O[Zn]O[C]=O ,8 O=[C]O[Zn] ,4 [O][C]O[Zn]O[C]=O. The MOF has largest included sphere 6.17 A, density 1.09 g/cm3, surface area 4915.18 m2/g, accessible volume 0.42 cm3/g