Zn3C22NH13O11(C3H2)2(CH)2C3NH2 is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight 02329_fluka molecules; four 2,3-dimethyl-1,3-butadiene molecules; four trimethylamine molecules; and four Zn3C22NH13O11 clusters. In each Zn3C22NH13O11 cluster, there are three inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(1), one O(11), one O(6), one O(7), and one O(9) atom to form corner-sharing ZnNO4 square pyramids. The Zn(1)-N(1) bond length is 2.14 Å. The Zn(1)-O(11) bond length is 2.13 Å. The Zn(1)-O(6) bond length is 2.03 Å. The Zn(1)-O(7) bond length is 2.12 Å. The Zn(1)-O(9) bond length is 2.09 Å. In the second Zn site, Zn(2) is bonded to one O(11), one O(2), one O(3), and one O(8) atom to form corner-sharing ZnO4 tetrahedra. The Zn(2)-O(11) bond length is 1.94 Å. The Zn(2)-O(2) bond length is 1.95 Å. The Zn(2)-O(3) bond length is 1.92 Å. The Zn(2)-O(8) bond length is 1.95 Å. In the third Zn site, Zn(3) is bonded in a distorted see-saw-like geometry to one O(1), one O(10), one O(11), and one O(5) atom. The Zn(3)-O(1) bond length is 2.20 Å. The Zn(3)-O(10) bond length is 2.00 Å. The Zn(3)-O(11) bond length is 1.99 Å. The Zn(3)-O(5) bond length is 2.08 Å. There are twenty-two inequivalent C sites. In the first C site, C(33) is bonded in a distorted single-bond geometry to one C(31) and one H(21) atom. The C(33)-C(31) bond length is 1.40 Å. The C(33)-H(21) bond length is 0.93 Å. In the second C site, C(32) is bonded in a distorted single-bond geometry to one C(31) and one H(20) atom. The C(32)-C(31) bond length is 1.38 Å. The C(32)-H(20) bond length is 0.93 Å. In the third C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(17) atom. The C(14)-C(13) bond length is 1.38 Å. The C(14)-C(15) bond length is 1.36 Å. The C(14)-C(17) bond length is 1.53 Å. In the fourth C site, C(29) is bonded in a distorted single-bond geometry to one C(27) and one H(19) atom. The C(29)-C(27) bond length is 1.40 Å. The C(29)-H(19) bond length is 0.93 Å. In the fifth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one C(19), one O(3), and one O(4) atom. The C(18)-C(19) bond length is 1.51 Å. The C(18)-O(3) bond length is 1.27 Å. The C(18)-O(4) bond length is 1.25 Å. In the sixth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(24) atom. The C(19)-C(20) bond length is 1.40 Å. The C(19)-C(24) bond length is 1.38 Å. In the seventh C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(31), one O(10), and one O(9) atom. The C(30)-C(31) bond length is 1.52 Å. The C(30)-O(10) bond length is 1.30 Å. The C(30)-O(9) bond length is 1.23 Å. In the eighth C site, C(24) is bonded in a distorted single-bond geometry to one C(19) and one H(17) atom. The C(24)-H(17) bond length is 0.93 Å. In the ninth C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1) atom. The C(1)-N(1) bond length is 1.33 Å. The C(1)-H(1) bond length is 0.93 Å. In the tenth C site, C(31) is bonded in a trigonal planar geometry to one C(30), one C(32), and one C(33) atom. In the eleventh C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.32 Å. The C(5)-H(4) bond length is 0.93 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(13)-H(11) bond length is 0.93 Å. In the thirteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(14) and one H(12) atom. The C(15)-H(12) bond length is 0.93 Å. In the fourteenth C site, C(21) is bonded in a distorted single-bond geometry to one C(22) and one H(15) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-H(15) bond length is 0.93 Å. In the fifteenth C site, C(22) is bonded in a trigonal planar geometry to one C(21), one C(23), and one C(25) atom. The C(22)-C(23) bond length is 1.40 Å. The C(22)-C(25) bond length is 1.49 Å. In the sixteenth C site, C(23) is bonded in a distorted single-bond geometry to one C(22) and one H(16) atom. The C(23)-H(16) bond length is 0.93 Å. In the seventeenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(1), and one O(2) atom. The C(17)-O(1) bond length is 1.24 Å. The C(17)-O(2) bond length is 1.24 Å. In the eighteenth C site, C(25) is bonded in a distorted bent 120 degrees geometry to one C(22), one O(5), and one O(6) atom. The C(25)-O(5) bond length is 1.25 Å. The C(25)-O(6) bond length is 1.24 Å. In the nineteenth C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(27), one O(7), and one O(8) atom. The C(26)-C(27) bond length is 1.48 Å. The C(26)-O(7) bond length is 1.26 Å. The C(26)-O(8) bond length is 1.26 Å. In the twentieth C site, C(27) is bonded in a trigonal planar geometry to one C(26), one C(28), and one C(29) atom. The C(27)-C(28) bond length is 1.39 Å. In the twenty-first C site, C(28) is bonded in a distorted single-bond geometry to one C(27) and one H(18) atom. The C(28)-H(18) bond length is 0.93 Å. In the twenty-second C site, C(20) is bonded in a distorted single-bond geometry to one C(19) and one H(14) atom. The C(20)-H(14) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(9) is bonded in a single-bond geometry to one O(11) atom. The H(9)-O(11) bond length is 0.79 Å. In the fourth H site, H(11) is bonded in a single-bond geometry to one C(13) atom. In the fifth H site, H(12) is bonded in a single-bond geometry to one C(15) atom. In the sixth H site, H(14) is bonded in a single-bond geometry to one C(20) atom. In the seventh H site, H(15) is bonded in a single-bond geometry to one C(21) atom. In the eighth H site, H(16) is bonded in a single-bond geometry to one C(23) atom. In the ninth H site, H(17) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(18) is bonded in a single-bond geometry to one C(28) atom. In the eleventh H site, H(19) is bonded in a single-bond geometry to one C(29) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(32) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(33) atom. There are eleven inequivalent O sites. In the first O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(26) atom. In the second O site, O(8) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(26) atom. In the third O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(17) atom. In the fourth O site, O(4) is bonded in a single-bond geometry to one C(18) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Zn(3) and one C(25) atom. In the sixth O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Zn(1) and one C(25) atom. In the seventh O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(17) atom. In the eighth O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(18) atom. In the ninth O site, O(9) is bonded in a bent 150 degrees geometry to one Zn(1) and one C(30) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Zn(3) and one C(30) atom. In the eleventh O site, O(11) is bonded in a distorted single-bond geometry to one Zn(1), one Zn(2), one Zn(3), and one H(9) atom. Linkers: 4 [O]C(=O)c1ccc(N2[CH]C=C(c3ccncc3)C=C2)cc1 ,9 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 4 O=[C]O[Zn]1(O)O[C]O[Zn]2O[C]O[Zn](O[C]O2)O[C]O1. The MOF has largest included sphere 5.09 A, density 1.30 g/cm3, surface area 4219.25 m2/g, accessible volume 0.39 cm3/g