Cu(OOCC6H4COO)C12H7 is Indium-derived structured and crystallizes in the tetragonal I-4m2 space group. The structure is zero-dimensional and consists of eight C12H7 clusters and eight Cu(OOCC6H4COO) clusters. In each C12H7 cluster, there are twelve inequivalent C sites. In the first C site, C(4) is bonded in a distorted single-bond geometry to one C(5) and one H(2) atom. The C(4)-C(5) bond length is 1.38 Å. The C(4)-H(2) bond length is 0.93 Å. In the second C site, C(5) is bonded in a trigonal planar geometry to one C(4), one C(6), and one C(8) atom. The C(5)-C(6) bond length is 1.41 Å. The C(5)-C(8) bond length is 1.51 Å. In the third C site, C(6) is bonded in a single-bond geometry to one C(5) and one H(3) atom. The C(6)-H(3) bond length is 0.93 Å. In the fourth C site, C(8) is bonded in a trigonal planar geometry to one C(13), one C(5), and one C(9) atom. The C(8)-C(13) bond length is 1.41 Å. The C(8)-C(9) bond length is 1.38 Å. In the fifth C site, C(9) is bonded in a 3-coordinate geometry to one C(10), one C(8), and one H(5) atom. The C(9)-C(10) bond length is 1.39 Å. The C(9)-H(5) bond length is 0.93 Å. In the sixth C site, C(10) is bonded in a trigonal planar geometry to one C(10), one C(11), and one C(9) atom. The C(10)-C(10) bond length is 1.45 Å. The C(10)-C(11) bond length is 1.43 Å. In the seventh C site, C(11) is bonded in a distorted single-bond geometry to one C(10), one C(12), and one H(6) atom. The C(11)-C(12) bond length is 1.36 Å. The C(11)-H(6) bond length is 0.93 Å. In the eighth C site, C(12) is bonded in a trigonal planar geometry to one C(11), one C(13), and one C(14) atom. The C(12)-C(13) bond length is 1.39 Å. The C(12)-C(14) bond length is 1.50 Å. In the ninth C site, C(13) is bonded in a distorted single-bond geometry to one C(12), one C(8), and one H(7) atom. The C(13)-H(7) bond length is 0.93 Å. In the tenth C site, C(14) is bonded in a trigonal planar geometry to one C(12), one C(15), and one C(19) atom. The C(14)-C(15) bond length is 1.37 Å. The C(14)-C(19) bond length is 1.36 Å. In the eleventh C site, C(15) is bonded in a single-bond geometry to one C(14) and one H(8) atom. The C(15)-H(8) bond length is 0.93 Å. In the twelfth C site, C(19) is bonded in a distorted single-bond geometry to one C(14) and one H(11) atom. The C(19)-H(11) bond length is 0.93 Å. There are seven inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(4) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(11) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(15) atom. In the seventh H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In each Cu(OOCC6H4COO) cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent O(2) and two equivalent O(4) atoms. Both Cu(1)-O(2) bond lengths are 1.96 Å. Both Cu(1)-O(4) bond lengths are 1.95 Å. In the second Cu site, Cu(2) is bonded in a rectangular see-saw-like geometry to two equivalent O(1) and two equivalent O(3) atoms. Both Cu(2)-O(1) bond lengths are 1.96 Å. Both Cu(2)-O(3) bond lengths are 1.95 Å. There are eight inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.52 Å. The C(1)-O(1) bond length is 1.24 Å. The C(1)-O(2) bond length is 1.29 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.38 Å. The C(2)-C(7) bond length is 1.37 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one H(1,10) atom. The C(3)-H(1,10) bond length is 0.93 Å. In the fourth C site, C(7) is bonded in a distorted single-bond geometry to one C(2) and one H(4) atom. The C(7)-H(4) bond length is 0.93 Å. In the fifth C site, C(16) is bonded in a single-bond geometry to one C(17) and one H(9) atom. The C(16)-C(17) bond length is 1.35 Å. The C(16)-H(9) bond length is 0.93 Å. In the sixth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(20) atom. The C(17)-C(18) bond length is 1.37 Å. The C(17)-C(20) bond length is 1.52 Å. In the seventh C site, C(18) is bonded in a distorted single-bond geometry to one C(17) and one H(1,10) atom. The C(18)-H(1,10) bond length is 0.93 Å. In the eighth C site, C(20) is bonded in a bent 120 degrees geometry to one C(17), one O(3), and one O(4) atom. The C(20)-O(3) bond length is 1.25 Å. The C(20)-O(4) bond length is 1.27 Å. There are three inequivalent H sites. In the first H site, H(1,10) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(16) atom. There are four inequivalent O sites. In the first O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(1) atom. In the second O site, O(3) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(20) atom. In the third O site, O(1) is bonded in a bent 120 degrees geometry to one Cu(2) and one C(1) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Cu(1) and one C(20) atom. Linkers: 4 [O]C(=O)c1ccc(-c2cc(-c3ccc(C([O])=O)cc3)cc(-c3cc(-c4ccc(C([O])=O)cc4)cc(-c4ccc(C([O])=O)cc4)c3)c2)cc1. Metal clusters: 4 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. RCSR code: lvt. The MOF has largest included sphere 12.14 A, density 0.70 g/cm3, surface area 4392.86 m2/g, accessible volume 0.86 cm3/g