ZnC14H10(NO2)2(C4H3)2(CH)8 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight isobutylene molecules, eight isobutylene molecules, and four ZnC14H10(NO2)2 clusters. In each ZnC14H10(NO2)2 cluster, Zn(1) is bonded in a tetrahedral geometry to two equivalent N(1) and two equivalent O(1) atoms. Both Zn(1)-N(1) bond lengths are 2.02 Å. Both Zn(1)-O(1) bond lengths are 1.94 Å. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(1)-C(2) bond length is 1.36 Å. The C(1)-N(1) bond length is 1.35 Å. The C(1)-H(1) bond length is 0.94 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1), one C(3), and one H(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-H(2) bond length is 0.94 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one C(6) atom. The C(3)-C(4) bond length is 1.41 Å. The C(3)-C(6) bond length is 1.46 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.94 Å. In the fifth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(4) atom. The C(5)-N(1) bond length is 1.34 Å. The C(5)-H(4) bond length is 0.94 Å. In the sixth C site, C(6) is bonded in a distorted single-bond geometry to one C(3) and one H(5) atom. The C(6)-H(5) bond length is 0.94 Å. In the seventh C site, C(11) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(11)-O(1) bond length is 1.28 Å. The C(11)-O(2) bond length is 1.24 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(1), and one C(5) atom. There are five inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(2) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(5) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. There are two inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one C(11) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(11) atom. Linkers: 1 [CH]=CC(=[CH])/C=C/c1ccc(/C=C/C2=C[CH]N([Zn](OC(=O)Cc3ccc(CC([O])=O)cc3)(OC(=O)Cc3ccc(CC([O])=O)cc3)N3[CH]C=C(/C=C/c4ccc(/C=C/c5ccncc5)cc4)C=C3)C=C2)cc1 ,1 [CH]=C[C]/C=C/C1=C[CH]N([Zn](OC(=O)Cc2ccc(CC([O])=O)cc2)(OC(=O)Cc2ccc(CC([O])=O)cc2)N2[CH]C=C(/C=C/c3ccc(/C=C/[C]C=[CH])cc3)C=C2)C=C1. Metal clusters: 1 O=[C]O[Zn]O[C]=O. The MOF has largest included sphere 4.83 A, density 1.17 g/cm3, surface area 5307.27 m2/g, accessible volume 0.35 cm3/g