CuH8(C2N)4(C5H3)4 is Indium-derived structured and crystallizes in the cubic Pm-3 space group. The structure is zero-dimensional and consists of eight 1,3,5-triisopropenyl benzene molecules and six CuH8(C2N)4 clusters. In each CuH8(C2N)4 cluster, Cu(1) is bonded in a square co-planar geometry to four equivalent N(1) atoms. All Cu(1)-N(1) bond lengths are 2.02 Å. There are two inequivalent C sites. In the first C site, C(5) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,4) atom. The C(5)-N(1) bond length is 1.39 Å. The C(5)-H(1,4) bond length is 0.95 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(1,4) atom. The C(1)-N(1) bond length is 1.39 Å. The C(1)-H(1,4) bond length is 0.95 Å. N(1) is bonded in a trigonal planar geometry to one Cu(1), one C(1), and one C(5) atom. H(1,4) is bonded in a single-bond geometry to one C(1) atom. Linkers: 8 c1cc(-c2cc(-c3ccncc3)cc(-c3ccncc3)c2)ccn1. Metal clusters: 6 [Cu]. The MOF has largest included sphere 15.96 A, density 0.50 g/cm3, surface area 5113.84 m2/g, accessible volume 1.37 cm3/g