Zn2C32N6H21O7CH is Indium-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four 02329_fluka molecules and two Zn2C32N6H21O7 clusters. In each Zn2C32N6H21O7 cluster, there are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded to one N(4), one N(6), one O(1), and one O(7) atom to form corner-sharing ZnN2O2 tetrahedra. The Zn(1)-N(4) bond length is 2.03 Å. The Zn(1)-N(6) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 1.97 Å. The Zn(1)-O(7) bond length is 1.92 Å. In the second Zn site, Zn(2) is bonded to one N(2), one O(4), one O(5), and one O(7) atom to form corner-sharing ZnNO3 tetrahedra. The Zn(2)-N(2) bond length is 2.04 Å. The Zn(2)-O(4) bond length is 1.97 Å. The Zn(2)-O(5) bond length is 1.97 Å. The Zn(2)-O(7) bond length is 1.91 Å. There are thirty-two inequivalent C sites. In the first C site, C(33) is bonded in a distorted single-bond geometry to one C(29) and one H(21) atom. The C(33)-C(29) bond length is 1.37 Å. The C(33)-H(21) bond length is 0.95 Å. In the second C site, C(1) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(1)-C(2) bond length is 1.49 Å. The C(1)-O(1) bond length is 1.28 Å. The C(1)-O(2) bond length is 1.24 Å. In the third C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(6) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(6) bond length is 1.37 Å. In the fourth C site, C(3) is bonded in a distorted trigonal planar geometry to one C(2), one N(1), and one H(1) atom. The C(3)-N(1) bond length is 1.31 Å. The C(3)-H(1) bond length is 0.95 Å. In the fifth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(5), one C(7), and one N(1) atom. The C(4)-C(5) bond length is 1.37 Å. The C(4)-C(7) bond length is 1.49 Å. The C(4)-N(1) bond length is 1.34 Å. In the sixth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(5)-H(2) bond length is 0.95 Å. In the seventh C site, C(6) is bonded in a distorted single-bond geometry to one C(2) and one H(3) atom. The C(6)-H(3) bond length is 0.95 Å. In the eighth C site, C(7) is bonded in a trigonal planar geometry to one C(11), one C(4), and one C(8) atom. The C(7)-C(11) bond length is 1.41 Å. The C(7)-C(8) bond length is 1.40 Å. In the ninth C site, C(8) is bonded in a distorted single-bond geometry to one C(7) and one H(4) atom. The C(8)-H(4) bond length is 0.95 Å. In the tenth C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(5) atom. The C(9)-N(2) bond length is 1.35 Å. The C(9)-H(5) bond length is 0.95 Å. In the eleventh C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(6) atom. The C(10)-N(2) bond length is 1.34 Å. The C(10)-H(6) bond length is 0.95 Å. In the twelfth C site, C(11) is bonded in a distorted single-bond geometry to one C(7) and one H(7) atom. The C(11)-H(7) bond length is 0.95 Å. In the thirteenth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(13), one O(3), and one O(4) atom. The C(12)-C(13) bond length is 1.50 Å. The C(12)-O(3) bond length is 1.24 Å. The C(12)-O(4) bond length is 1.27 Å. In the fourteenth C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(17) atom. The C(13)-C(14) bond length is 1.38 Å. The C(13)-C(17) bond length is 1.38 Å. In the fifteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(13), one N(3), and one H(8) atom. The C(14)-N(3) bond length is 1.33 Å. The C(14)-H(8) bond length is 0.95 Å. In the sixteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(18) and one N(3) atom. The C(15)-C(18) bond length is 1.49 Å. The C(15)-N(3) bond length is 1.34 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(13) and one H(10) atom. The C(17)-H(10) bond length is 0.95 Å. In the eighteenth C site, C(18) is bonded in a trigonal planar geometry to one C(15), one C(19), and one C(22) atom. The C(18)-C(19) bond length is 1.38 Å. The C(18)-C(22) bond length is 1.38 Å. In the nineteenth C site, C(19) is bonded in a distorted single-bond geometry to one C(18), one C(20), and one H(11) atom. The C(19)-C(20) bond length is 1.36 Å. The C(19)-H(11) bond length is 0.95 Å. In the twentieth C site, C(20) is bonded in a distorted trigonal planar geometry to one C(19), one N(4), and one H(12) atom. The C(20)-N(4) bond length is 1.34 Å. The C(20)-H(12) bond length is 0.95 Å. In the twenty-first C site, C(21) is bonded in a distorted bent 120 degrees geometry to one C(22), one N(4), and one H(13) atom. The C(21)-C(22) bond length is 1.38 Å. The C(21)-N(4) bond length is 1.33 Å. The C(21)-H(13) bond length is 0.95 Å. In the twenty-second C site, C(22) is bonded in a distorted trigonal planar geometry to one C(18), one C(21), and one H(14) atom. The C(22)-H(14) bond length is 0.95 Å. In the twenty-third C site, C(23) is bonded in a bent 120 degrees geometry to one C(24), one O(5), and one O(6) atom. The C(23)-C(24) bond length is 1.51 Å. The C(23)-O(5) bond length is 1.29 Å. The C(23)-O(6) bond length is 1.23 Å. In the twenty-fourth C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(28) atom. The C(24)-C(25) bond length is 1.36 Å. The C(24)-C(28) bond length is 1.37 Å. In the twenty-fifth C site, C(25) is bonded in a 3-coordinate geometry to one C(24), one N(5), and one H(15) atom. The C(25)-N(5) bond length is 1.34 Å. The C(25)-H(15) bond length is 0.95 Å. In the twenty-sixth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(27), one C(29), and one N(5) atom. The C(26)-C(27) bond length is 1.34 Å. The C(26)-C(29) bond length is 1.49 Å. The C(26)-N(5) bond length is 1.35 Å. In the twenty-seventh C site, C(27) is bonded in a single-bond geometry to one C(26) and one H(16) atom. The C(27)-H(16) bond length is 0.95 Å. In the twenty-eighth C site, C(28) is bonded in a distorted single-bond geometry to one C(24) and one H(17) atom. The C(28)-H(17) bond length is 0.95 Å. In the twenty-ninth C site, C(29) is bonded in a trigonal planar geometry to one C(26), one C(30), and one C(33) atom. The C(29)-C(30) bond length is 1.40 Å. In the thirtieth C site, C(30) is bonded in a distorted single-bond geometry to one C(29) and one H(18) atom. The C(30)-H(18) bond length is 0.95 Å. In the thirty-first C site, C(31) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(19) atom. The C(31)-N(6) bond length is 1.33 Å. The C(31)-H(19) bond length is 0.95 Å. In the thirty-second C site, C(32) is bonded in a distorted bent 120 degrees geometry to one N(6) and one H(20) atom. The C(32)-N(6) bond length is 1.34 Å. The C(32)-H(20) bond length is 0.95 Å. There are six inequivalent N sites. In the first N site, N(2) is bonded in a trigonal planar geometry to one Zn(2), one C(10), and one C(9) atom. In the second N site, N(3) is bonded in a bent 120 degrees geometry to one C(14) and one C(15) atom. In the third N site, N(4) is bonded in a trigonal planar geometry to one Zn(1), one C(20), and one C(21) atom. In the fourth N site, N(6) is bonded in a trigonal planar geometry to one Zn(1), one C(31), and one C(32) atom. In the fifth N site, N(5) is bonded in a bent 120 degrees geometry to one C(25) and one C(26) atom. In the sixth N site, N(1) is bonded in a bent 120 degrees geometry to one C(3) and one C(4) atom. There are twenty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(14) atom. In the ninth H site, H(10) is bonded in a single-bond geometry to one C(17) atom. In the tenth H site, H(11) is bonded in a single-bond geometry to one C(19) atom. In the eleventh H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(13) is bonded in a single-bond geometry to one C(21) atom. In the thirteenth H site, H(14) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the fifteenth H site, H(16) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(17) is bonded in a single-bond geometry to one C(28) atom. In the seventeenth H site, H(18) is bonded in a single-bond geometry to one C(30) atom. In the eighteenth H site, H(19) is bonded in a single-bond geometry to one C(31) atom. In the nineteenth H site, H(20) is bonded in a single-bond geometry to one C(32) atom. In the twentieth H site, H(21) is bonded in a single-bond geometry to one C(33) atom. In the twenty-first H site, H(22) is bonded in a single-bond geometry to one O(7) atom. The H(22)-O(7) bond length is 0.70 Å. There are seven inequivalent O sites. In the first O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(2) and one C(12) atom. In the second O site, O(5) is bonded in a water-like geometry to one Zn(2) and one C(23) atom. In the third O site, O(6) is bonded in a single-bond geometry to one C(23) atom. In the fourth O site, O(7) is bonded in a distorted single-bond geometry to one Zn(1), one Zn(2), and one H(22) atom. In the fifth O site, O(1) is bonded in a water-like geometry to one Zn(1) and one C(1) atom. In the sixth O site, O(3) is bonded in a single-bond geometry to one C(12) atom. In the seventh O site, O(2) is bonded in a single-bond geometry to one C(1) atom. Linkers: 12 [O]C(=O)c1ccc(-c2ccncc2)nc1. Metal clusters: 4 O=[C]O[Zn].O=[C]O[Zn](O)O[C]=O. The MOF has largest included sphere 7.52 A, density 1.17 g/cm3, surface area 4442.95 m2/g, accessible volume 0.40 cm3/g