Mn3C70H60(N2O3)4MnC21N4H22Cl is Indium-like structured and crystallizes in the monoclinic P2_1/m space group. The structure is zero-dimensional and consists of two Mn3C70H60(N2O3)4 clusters and two MnC21N4H22Cl clusters. In each Mn3C70H60(N2O3)4 cluster, there are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 6-coordinate geometry to one N(2), one N(3), one O(1), one O(2), one O(4), and one O(5) atom. The Mn(1)-N(2) bond length is 2.28 Å. The Mn(1)-N(3) bond length is 2.21 Å. The Mn(1)-O(1) bond length is 2.19 Å. The Mn(1)-O(2) bond length is 2.11 Å. The Mn(1)-O(4) bond length is 2.09 Å. The Mn(1)-O(5) bond length is 2.48 Å. In the second Mn site, Mn(2) is bonded in an octahedral geometry to two equivalent O(1), two equivalent O(3), and two equivalent O(6) atoms. Both Mn(2)-O(1) bond lengths are 2.24 Å. Both Mn(2)-O(3) bond lengths are 2.11 Å. Both Mn(2)-O(6) bond lengths are 2.10 Å. There are thirty-five inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one C(10), one C(18), and one N(2) atom. The C(1)-C(10) bond length is 1.40 Å. The C(1)-C(18) bond length is 1.50 Å. The C(1)-N(2) bond length is 1.34 Å. In the second C site, C(2) is bonded in a tetrahedral geometry to one N(1); one N(4); and two equivalent H(1,2) atoms. The C(2)-N(1) bond length is 1.46 Å. The C(2)-N(4) bond length is 1.44 Å. Both C(2)-H(1,2) bond lengths are 0.99 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(12), one O(2), and one O(6) atom. The C(3)-C(12) bond length is 1.50 Å. The C(3)-O(2) bond length is 1.25 Å. The C(3)-O(6) bond length is 1.25 Å. In the fourth C site, C(4) is bonded in a bent 120 degrees geometry to one C(14), one O(1), and one O(5) atom. The C(4)-C(14) bond length is 1.50 Å. The C(4)-O(1) bond length is 1.27 Å. The C(4)-O(5) bond length is 1.25 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(11) and one H(3) atom. The C(5)-C(11) bond length is 1.39 Å. The C(5)-H(3) bond length is 0.95 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(23), one C(9), and one N(3) atom. The C(6)-C(23) bond length is 1.49 Å. The C(6)-C(9) bond length is 1.41 Å. The C(6)-N(3) bond length is 1.34 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(27), one C(9), and one N(1) atom. The C(7)-C(27) bond length is 1.48 Å. The C(7)-C(9) bond length is 1.38 Å. The C(7)-N(1) bond length is 1.35 Å. In the eighth C site, C(8) is bonded in a 5-coordinate geometry to one C(15), one C(26), one C(29), one C(44), and one C(45) atom. The C(8)-C(15) bond length is 1.53 Å. The C(8)-C(26) bond length is 1.38 Å. The C(8)-C(29) bond length is 1.41 Å. The C(8)-C(44) bond length is 1.44 Å. The C(8)-C(45) bond length is 1.31 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(11), one C(6), and one C(7) atom. The C(9)-C(11) bond length is 1.46 Å. In the tenth C site, C(10) is bonded in a trigonal planar geometry to one C(1), one C(13), and one C(16) atom. The C(10)-C(13) bond length is 1.39 Å. The C(10)-C(16) bond length is 1.48 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(21), one C(5), and one C(9) atom. The C(11)-C(21) bond length is 1.40 Å. In the twelfth C site, C(12) is bonded in a 5-coordinate geometry to one C(3), one C(35), one C(37), one C(39), and one C(42) atom. The C(12)-C(35) bond length is 1.43 Å. The C(12)-C(37) bond length is 1.36 Å. The C(12)-C(39) bond length is 1.33 Å. The C(12)-C(42) bond length is 1.41 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(10), one C(19), and one N(4) atom. The C(13)-C(19) bond length is 1.49 Å. The C(13)-N(4) bond length is 1.36 Å. In the fourteenth C site, C(14) is bonded in a trigonal planar geometry to one C(17), one C(32), and one C(4) atom. The C(14)-C(17) bond length is 1.38 Å. The C(14)-C(32) bond length is 1.39 Å. In the fifteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(8), one O(3), and one O(4) atom. The C(15)-O(3) bond length is 1.20 Å. The C(15)-O(4) bond length is 1.24 Å. In the sixteenth C site, C(16) is bonded in a 5-coordinate geometry to one C(10), one C(33), one C(34), one C(40), and one C(41) atom. The C(16)-C(33) bond length is 1.41 Å. The C(16)-C(34) bond length is 1.35 Å. The C(16)-C(40) bond length is 1.38 Å. The C(16)-C(41) bond length is 1.46 Å. In the seventeenth C site, C(17) is bonded in a distorted single-bond geometry to one C(14) and one H(4) atom. The C(17)-H(4) bond length is 0.95 Å. In the eighteenth C site, C(18) is bonded in a trigonal non-coplanar geometry to one C(1); one H(5); and two equivalent H(6,7) atoms. The C(18)-H(5) bond length is 0.98 Å. Both C(18)-H(6,7) bond lengths are 0.98 Å. In the nineteenth C site, C(19) is bonded in a trigonal non-coplanar geometry to one C(13), one H(10), one H(8), and one H(9) atom. The C(19)-H(10) bond length is 0.98 Å. The C(19)-H(8) bond length is 0.98 Å. The C(19)-H(9) bond length is 0.98 Å. In the twentieth C site, C(21) is bonded in a single-bond geometry to one C(11) and one H(11) atom. The C(21)-H(11) bond length is 0.95 Å. In the twenty-first C site, C(23) is bonded in a trigonal non-coplanar geometry to one C(6); one H(12); and two equivalent H(13,14) atoms. The C(23)-H(12) bond length is 0.98 Å. Both C(23)-H(13,14) bond lengths are 0.98 Å. In the twenty-second C site, C(26) is bonded in a distorted single-bond geometry to one C(8) and one H(15,38) atom. The C(26)-H(15,38) bond length is 0.95 Å. In the twenty-third C site, C(27) is bonded in a trigonal non-coplanar geometry to one C(7) and three equivalent H(16,17,18) atoms. All C(27)-H(16,17,18) bond lengths are 0.98 Å. In the twenty-fourth C site, C(29) is bonded in a distorted single-bond geometry to one C(8) and one H(20) atom. The C(29)-H(20) bond length is 0.95 Å. In the twenty-fifth C site, C(32) is bonded in a distorted single-bond geometry to one C(14) and one H(27) atom. The C(32)-H(27) bond length is 0.95 Å. In the twenty-sixth C site, C(33) is bonded in a distorted single-bond geometry to one C(16) and one H(28) atom. The C(33)-H(28) bond length is 0.95 Å. In the twenty-seventh C site, C(34) is bonded in a distorted single-bond geometry to one C(16) and one H(29) atom. The C(34)-H(29) bond length is 0.95 Å. In the twenty-eighth C site, C(35) is bonded in a distorted water-like geometry to one C(12), one C(39), and one H(30) atom. The C(35)-C(39) bond length is 0.98 Å. The C(35)-H(30) bond length is 0.95 Å. In the twenty-ninth C site, C(37) is bonded in a 2-coordinate geometry to one C(12), one C(42), and one H(32) atom. The C(37)-C(42) bond length is 1.07 Å. The C(37)-H(32) bond length is 0.95 Å. In the thirtieth C site, C(39) is bonded in a distorted bent 120 degrees geometry to one C(12), one C(35), and one H(34) atom. The C(39)-H(34) bond length is 0.95 Å. In the thirty-first C site, C(40) is bonded in a distorted single-bond geometry to one C(16) and one H(35) atom. The C(40)-H(35) bond length is 0.95 Å. In the thirty-second C site, C(41) is bonded in a distorted single-bond geometry to one C(16) and one H(36) atom. The C(41)-H(36) bond length is 0.95 Å. In the thirty-third C site, C(42) is bonded in a 1-coordinate geometry to one C(12), one C(37), and one H(37) atom. The C(42)-H(37) bond length is 0.95 Å. In the thirty-fourth C site, C(44) is bonded in a distorted single-bond geometry to one C(8) and one H(39) atom. The C(44)-H(39) bond length is 0.95 Å. In the thirty-fifth C site, C(45) is bonded in a distorted single-bond geometry to one C(8) and one H(40) atom. The C(45)-H(40) bond length is 0.95 Å. There are four inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal planar geometry to one C(2), one C(7), and one N(3) atom. The N(1)-N(3) bond length is 1.36 Å. In the second N site, N(2) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(1), and one N(4) atom. The N(2)-N(4) bond length is 1.36 Å. In the third N site, N(3) is bonded in a distorted trigonal planar geometry to one Mn(1), one C(6), and one N(1) atom. In the fourth N site, N(4) is bonded in a 3-coordinate geometry to one C(13), one C(2), and one N(2) atom. There are twenty-five inequivalent H sites. In the first H site, H(1,2) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(4) is bonded in a single-bond geometry to one C(17) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(18) atom. In the fifth H site, H(6,7) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(19) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(19) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(19) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(21) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(23) atom. In the eleventh H site, H(13,14) is bonded in a single-bond geometry to one C(23) atom. In the twelfth H site, H(15,38) is bonded in a single-bond geometry to one C(26) atom. In the thirteenth H site, H(16,17,18) is bonded in a single-bond geometry to one C(27) atom. In the fourteenth H site, H(20) is bonded in a single-bond geometry to one C(29) atom. In the fifteenth H site, H(27) is bonded in a single-bond geometry to one C(32) atom. In the sixteenth H site, H(28) is bonded in a single-bond geometry to one C(33) atom. In the seventeenth H site, H(29) is bonded in a single-bond geometry to one C(34) atom. In the eighteenth H site, H(30) is bonded in a single-bond geometry to one C(35) atom. In the nineteenth H site, H(32) is bonded in a single-bond geometry to one C(37) atom. In the twentieth H site, H(34) is bonded in a single-bond geometry to one C(39) atom. In the twenty-first H site, H(35) is bonded in a single-bond geometry to one C(40) atom. In the twenty-second H site, H(36) is bonded in a single-bond geometry to one C(41) atom. In the twenty-third H site, H(37) is bonded in a single-bond geometry to one C(42) atom. In the twenty-fourth H site, H(39) is bonded in a single-bond geometry to one C(44) atom. In the twenty-fifth H site, H(40) is bonded in a single-bond geometry to one C(45) atom. There are six inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to one Mn(1) and one C(4) atom. In the second O site, O(6) is bonded in a bent 150 degrees geometry to one Mn(2) and one C(3) atom. In the third O site, O(1) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one Mn(2), and one C(4) atom. In the fourth O site, O(2) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(3) atom. In the fifth O site, O(3) is bonded in a bent 150 degrees geometry to one Mn(2) and one C(15) atom. In the sixth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one C(15) atom. In each MnC21N4H22Cl cluster, Mn(3) is bonded in a 3-coordinate geometry to two equivalent N(6) and one Cl(1) atom. Both Mn(3)-N(6) bond lengths are 2.31 Å. The Mn(3)-Cl(1) bond length is 2.51 Å. There are eleven inequivalent C sites. In the first C site, C(20) is bonded in a trigonal planar geometry to one C(22), one C(24), and one C(25) atom. The C(20)-C(22) bond length is 1.50 Å. The C(20)-C(24) bond length is 1.39 Å. The C(20)-C(25) bond length is 1.37 Å. In the second C site, C(22) is bonded in a 5-coordinate geometry to one C(20), one C(28), one C(36), one C(38), and one C(43) atom. The C(22)-C(28) bond length is 1.26 Å. The C(22)-C(36) bond length is 1.39 Å. The C(22)-C(38) bond length is 1.40 Å. The C(22)-C(43) bond length is 1.39 Å. In the third C site, C(24) is bonded in a distorted trigonal planar geometry to one C(20), one C(30), and one N(6) atom. The C(24)-C(30) bond length is 1.51 Å. The C(24)-N(6) bond length is 1.32 Å. In the fourth C site, C(25) is bonded in a distorted trigonal planar geometry to one C(20), one C(31), and one N(5) atom. The C(25)-C(31) bond length is 1.53 Å. The C(25)-N(5) bond length is 1.34 Å. In the fifth C site, C(28) is bonded in a 1-coordinate geometry to one C(22) and one H(19) atom. The C(28)-H(19) bond length is 0.95 Å. In the sixth C site, C(30) is bonded in a trigonal non-coplanar geometry to one C(24); one H(22); and two equivalent H(21,23) atoms. The C(30)-H(22) bond length is 0.98 Å. Both C(30)-H(21,23) bond lengths are 0.98 Å. In the seventh C site, C(31) is bonded in a trigonal non-coplanar geometry to one C(25) and three equivalent H(24,25,26) atoms. All C(31)-H(24,25,26) bond lengths are 0.98 Å. In the eighth C site, C(36) is bonded in a 1-coordinate geometry to one C(22) and one H(31) atom. The C(36)-H(31) bond length is 0.95 Å. In the ninth C site, C(38) is bonded in a 1-coordinate geometry to one C(22) and one H(33) atom. The C(38)-H(33) bond length is 0.95 Å. In the tenth C site, C(43) is bonded in a 1-coordinate geometry to one C(22) and one H(15,38) atom. The C(43)-H(15,38) bond length is 0.95 Å. In the eleventh C site, C(46) is bonded in a tetrahedral geometry to two equivalent N(5) and two equivalent H(41,42) atoms. Both C(46)-N(5) bond lengths are 1.46 Å. Both C(46)-H(41,42) bond lengths are 0.99 Å. There are two inequivalent N sites. In the first N site, N(5) is bonded in a 3-coordinate geometry to one C(25), one C(46), and one N(6) atom. The N(5)-N(6) bond length is 1.40 Å. In the second N site, N(6) is bonded in a 3-coordinate geometry to one Mn(3), one C(24), and one N(5) atom. There are eight inequivalent H sites. In the first H site, H(15,38) is bonded in a single-bond geometry to one C(26) atom. In the second H site, H(19) is bonded in a single-bond geometry to one C(28) atom. In the third H site, H(21,23) is bonded in a single-bond geometry to one C(30) atom. In the fourth H site, H(22) is bonded in a single-bond geometry to one C(30) atom. In the fifth H site, H(24,25,26) is bonded in a single-bond geometry to one C(31) atom. In the sixth H site, H(31) is bonded in a single-bond geometry to one C(36) atom. In the seventh H site, H(33) is bonded in a single-bond geometry to one C(38) atom. In the eighth H site, H(41,42) is bonded in a single-bond geometry to one C(46) atom. Cl(1) is bonded in a single-bond geometry to one Mn(3) atom. Linkers: 2 Cc1[c]c(C)n(Cn2nc(C)c(-c3ccc(C([O])=O)cc3)c2C)n1.[CH]1[C@@H]2[C@@H]3[CH][C@@]14[C@@H]1[C@H]4[C@H]4[C@@H]1[C@@]423.[O][C]=O ,1 Cc1[c]c(C)n(Cn2nc(C)c(-c3ccc(C([O])=O)cc3)c2C)n1.[CH]1[C@@H]2[C@@H]3[CH][C@]14[C@@H]1[C@H]4[C@H]4[C@@H]1[C@]423.[O][C]=O ,1 Cc1[c]c(C)n(Cn2nc(C)c(-c3ccc(C([O])=O)cc3)c2C)n1.[C@H]12[C@@H]3[C@@H]4[C@H]1C41[C@@H]4[C@H]5[C@@H]([C@@H]41)C235.[O][C]=O ,1 C[C]1[C]=C(C)N2CN3C(C)=[C][C](C)N3[Mn](Cl)N12.[CH]1[C@@H]2[C]3[C@@H]4[C@H]3[C@H]3[C@@H]4[C@@]34[C@@H]2[C@@H]14.[CH]1[C@H]2[C]3[C@@H]4[C@H]3[C@H]3[C@@H]4[C@@]34[C@H]2[C@H]14.[O][C]=O.[O][C]=O ,1 C[C]1[C]=C(C)N2N1CN1C(C)=[C][C](C)N1[Mn]2Cl.[CH]1[C@@H]2[C]3[C@@H]4[C@H]3[C@H]3[C@@H]4[C@@]34[C@@H]2[C@@H]14.[CH]1[C@H]2[C]3[C@@H]4[C@H]3[C@H]3[C@@H]4[C@@]34[C@H]2[C@H]14.[O][C]=O.[O][C]=O. Metal clusters: 2 [C]1O[Mn]2(O1)O[C]O[Mn]1(O[C]O2)O[C]O[Mn]2(O[C]O2)O[C]O1. RCSR code: sql. The MOF has largest included sphere 5.91 A, density 1.12 g/cm3, surface area 4034.28 m2/g, accessible volume 0.39 cm3/g