(CH)3Ag11C14N(OF)12(CF6)4 crystallizes in the monoclinic C2/c space group. The structure consists of twelve 02329_fluka molecules and sixteen CF6 clusters inside a Ag11C14N(OF)12 framework. In each CF6 cluster, C(6) is bonded in a 6-coordinate geometry to one F(1), one F(10), one F(11), one F(12), one F(2), and one F(3) atom. The C(6)-F(1) bond length is 1.27 Å. The C(6)-F(10) bond length is 1.27 Å. The C(6)-F(11) bond length is 1.27 Å. The C(6)-F(12) bond length is 1.28 Å. The C(6)-F(2) bond length is 1.27 Å. The C(6)-F(3) bond length is 1.28 Å. There are six inequivalent F sites. In the first F site, F(1) is bonded in a distorted single-bond geometry to one C(6) atom. In the second F site, F(2) is bonded in a single-bond geometry to one C(6) atom. In the third F site, F(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth F site, F(10) is bonded in a single-bond geometry to one C(6) atom. In the fifth F site, F(11) is bonded in a distorted single-bond geometry to one C(6) atom. In the sixth F site, F(12) is bonded in a single-bond geometry to one C(6) atom. In the Ag11C14N(OF)12 framework, there are six inequivalent Ag sites. In the first Ag site, Ag(1) is bonded to one C(1), one O(1), and two equivalent O(3) atoms to form distorted edge-sharing AgCO3 trigonal pyramids. The Ag(1)-C(1) bond length is 2.27 Å. The Ag(1)-O(1) bond length is 2.23 Å. There is one shorter (2.32 Å) and one longer (2.45 Å) Ag(1)-O(3) bond length. In the second Ag site, Ag(2) is bonded in a 3-coordinate geometry to one C(1), one O(4), and one O(6) atom. The Ag(2)-C(1) bond length is 2.20 Å. The Ag(2)-O(4) bond length is 2.34 Å. The Ag(2)-O(6) bond length is 2.34 Å. In the third Ag site, Ag(3) is bonded in a 2-coordinate geometry to one C(1) and one O(2) atom. The Ag(3)-C(1) bond length is 2.21 Å. The Ag(3)-O(2) bond length is 2.32 Å. In the fourth Ag site, Ag(4) is bonded in a distorted bent 150 degrees geometry to one C(1), one C(2), and one O(6) atom. The Ag(4)-C(1) bond length is 2.28 Å. The Ag(4)-C(2) bond length is 2.51 Å. The Ag(4)-O(6) bond length is 2.24 Å. In the fifth Ag site, Ag(5) is bonded in a 3-coordinate geometry to one Ag(6), one N(1), and one O(5) atom. The Ag(5)-Ag(6) bond length is 0.49 Å. The Ag(5)-N(1) bond length is 2.20 Å. The Ag(5)-O(5) bond length is 2.22 Å. In the sixth Ag site, Ag(6) is bonded in a bent 150 degrees geometry to two equivalent Ag(5) atoms. There are seven inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal bipyramidal geometry to one Ag(1), one Ag(2), one Ag(3), one Ag(4), and one C(2) atom. The C(1)-C(2) bond length is 1.20 Å. In the second C site, C(2) is bonded in a 3-coordinate geometry to one Ag(4), one C(1), and one C(3) atom. The C(2)-C(3) bond length is 1.44 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(2) and one N(1) atom. The C(3)-N(1) bond length is 1.33 Å. In the fourth C site, C(5) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(2) atom. The C(5)-O(1) bond length is 1.21 Å. The C(5)-O(2) bond length is 1.24 Å. In the fifth C site, C(7) is bonded in a distorted trigonal planar geometry to one O(3) and one O(4) atom. The C(7)-O(3) bond length is 1.22 Å. The C(7)-O(4) bond length is 1.25 Å. In the sixth C site, C(9) is bonded in a distorted trigonal planar geometry to one C(10), one O(5), and one O(6) atom. The C(9)-C(10) bond length is 1.54 Å. The C(9)-O(5) bond length is 1.21 Å. The C(9)-O(6) bond length is 1.24 Å. In the seventh C site, C(10) is bonded in a 6-coordinate geometry to one C(9), one F(16), one F(17), one F(18), one F(7), one F(8), and one F(9) atom. The C(10)-F(16) bond length is 1.23 Å. The C(10)-F(17) bond length is 1.23 Å. The C(10)-F(18) bond length is 1.25 Å. The C(10)-F(7) bond length is 1.26 Å. The C(10)-F(8) bond length is 1.27 Å. The C(10)-F(9) bond length is 1.29 Å. N(1) is bonded in a distorted bent 120 degrees geometry to two equivalent Ag(5) and two equivalent C(3) atoms. There are six inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Ag(1) and one C(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Ag(3) and one C(5) atom. In the third O site, O(3) is bonded in a 3-coordinate geometry to two equivalent Ag(1) and one C(7) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(2) and one C(7) atom. In the fifth O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Ag(5) and one C(9) atom. In the sixth O site, O(6) is bonded in a 3-coordinate geometry to one Ag(2), one Ag(4), and one C(9) atom. There are six inequivalent F sites. In the first F site, F(7) is bonded in a distorted single-bond geometry to one C(10) atom. In the second F site, F(8) is bonded in a distorted single-bond geometry to one C(10) atom. In the third F site, F(9) is bonded in a single-bond geometry to one C(10) atom. In the fourth F site, F(16) is bonded in a distorted single-bond geometry to one C(10) atom. In the fifth F site, F(17) is bonded in a single-bond geometry to one C(10) atom. In the sixth F site, F(18) is bonded in a distorted single-bond geometry to one C(10) atom. Linkers: 4 [C]#Cc1cccc(C#[C])n1 ,9 FF.FF.FF.[C].[O][C]=O ,15 FF.FF.FF.[C]C([O])=O. Metal clusters: 44 [Ag]. The MOF has largest included sphere 5.41 A, density 2.72 g/cm3, surface area 1860.68 m2/g, accessible volume 0.17 cm3/g