(MnC23N3H13O4)2MnC16H10(NO)4(CH)10 is Indium-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of forty 02329_fluka molecules, four MnC16H10(NO)4 clusters, and eight MnC23N3H13O4 clusters. In each MnC16H10(NO)4 cluster, Mn(2) is bonded in a distorted tetrahedral geometry to two equivalent N(5), one O(5), and one O(7) atom. Both Mn(2)-N(5) bond lengths are 2.01 Å. The Mn(2)-O(5) bond length is 1.94 Å. The Mn(2)-O(7) bond length is 1.95 Å. There are twelve inequivalent C sites. In the first C site, C(33) is bonded in a distorted bent 120 degrees geometry to one C(34), one O(5), and one O(6) atom. The C(33)-C(34) bond length is 1.50 Å. The C(33)-O(5) bond length is 1.27 Å. The C(33)-O(6) bond length is 1.23 Å. In the second C site, C(34) is bonded in a trigonal planar geometry to one C(33), one C(35), and one C(39) atom. The C(34)-C(35) bond length is 1.39 Å. The C(34)-C(39) bond length is 1.39 Å. In the third C site, C(35) is bonded in a distorted single-bond geometry to one C(34) and one H(22) atom. The C(35)-H(22) bond length is 0.93 Å. In the fourth C site, C(36) is bonded in a trigonal planar geometry to one C(37), one C(38), and one C(40) atom. The C(36)-C(37) bond length is 1.37 Å. The C(36)-C(38) bond length is 1.48 Å. The C(36)-C(40) bond length is 1.40 Å. In the fifth C site, C(37) is bonded in a distorted single-bond geometry to one C(36) and one H(23) atom. The C(37)-H(23) bond length is 0.93 Å. In the sixth C site, C(38) is bonded in a distorted bent 120 degrees geometry to one C(36), one O(7), and one O(8) atom. The C(38)-O(7) bond length is 1.27 Å. The C(38)-O(8) bond length is 1.25 Å. In the seventh C site, C(39) is bonded in a distorted single-bond geometry to one C(34) and one H(24) atom. The C(39)-H(24) bond length is 0.93 Å. In the eighth C site, C(40) is bonded in a distorted single-bond geometry to one C(36) and one H(25) atom. The C(40)-H(25) bond length is 0.93 Å. In the ninth C site, C(12) is bonded in a trigonal planar geometry to one N(4), one N(5), and one H(5) atom. The C(12)-N(4) bond length is 1.33 Å. The C(12)-N(5) bond length is 1.31 Å. The C(12)-H(5) bond length is 0.93 Å. In the tenth C site, C(17) is bonded in a distorted single-bond geometry to one N(4) atom. The C(17)-N(4) bond length is 1.42 Å. In the eleventh C site, C(27) is bonded in a distorted trigonal planar geometry to one C(28), one N(5), and one H(18) atom. The C(27)-C(28) bond length is 1.34 Å. The C(27)-N(5) bond length is 1.34 Å. The C(27)-H(18) bond length is 0.93 Å. In the twelfth C site, C(28) is bonded in a distorted bent 120 degrees geometry to one C(27), one N(4), and one H(19) atom. The C(28)-N(4) bond length is 1.34 Å. The C(28)-H(19) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(4) is bonded in a trigonal planar geometry to one C(12), one C(17), and one C(28) atom. In the second N site, N(5) is bonded in a trigonal planar geometry to one Mn(2), one C(12), and one C(27) atom. There are seven inequivalent H sites. In the first H site, H(5) is bonded in a single-bond geometry to one C(12) atom. In the second H site, H(18) is bonded in a single-bond geometry to one C(27) atom. In the third H site, H(19) is bonded in a single-bond geometry to one C(28) atom. In the fourth H site, H(22) is bonded in a single-bond geometry to one C(35) atom. In the fifth H site, H(23) is bonded in a single-bond geometry to one C(37) atom. In the sixth H site, H(24) is bonded in a single-bond geometry to one C(39) atom. In the seventh H site, H(25) is bonded in a single-bond geometry to one C(40) atom. There are four inequivalent O sites. In the first O site, O(5) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(33) atom. In the second O site, O(6) is bonded in a single-bond geometry to one C(33) atom. In the third O site, O(7) is bonded in a bent 120 degrees geometry to one Mn(2) and one C(38) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one C(38) atom. In each MnC23N3H13O4 cluster, Mn(1) is bonded in a 6-coordinate geometry to one N(1), one N(2), one N(3), one O(2), one O(3), and one O(4) atom. The Mn(1)-N(1) bond length is 2.19 Å. The Mn(1)-N(2) bond length is 2.05 Å. The Mn(1)-N(3) bond length is 2.13 Å. The Mn(1)-O(2) bond length is 2.09 Å. The Mn(1)-O(3) bond length is 2.29 Å. The Mn(1)-O(4) bond length is 2.00 Å. There are twenty-three inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one N(3) and one H(1) atom. The C(1)-N(3) bond length is 1.34 Å. The C(1)-H(1) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(4), one C(8), and one N(2) atom. The C(2)-C(4) bond length is 1.38 Å. The C(2)-C(8) bond length is 1.49 Å. The C(2)-N(2) bond length is 1.34 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(6), one C(9), and one H(2) atom. The C(3)-C(6) bond length is 1.40 Å. The C(3)-C(9) bond length is 1.39 Å. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(2), one C(9), and one H(3) atom. The C(4)-C(9) bond length is 1.39 Å. The C(4)-H(3) bond length is 0.93 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(22), one C(6), and one N(3) atom. The C(5)-C(22) bond length is 1.37 Å. The C(5)-C(6) bond length is 1.47 Å. The C(5)-N(3) bond length is 1.36 Å. In the sixth C site, C(6) is bonded in a distorted trigonal planar geometry to one C(3), one C(5), and one N(2) atom. The C(6)-N(2) bond length is 1.34 Å. In the seventh C site, C(7) is bonded in a single-bond geometry to one C(11) and one H(4) atom. The C(7)-C(11) bond length is 1.39 Å. The C(7)-H(4) bond length is 0.93 Å. In the eighth C site, C(8) is bonded in a distorted trigonal planar geometry to one C(2), one C(24), and one N(1) atom. The C(8)-C(24) bond length is 1.38 Å. The C(8)-N(1) bond length is 1.34 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(11), one C(3), and one C(4) atom. The C(9)-C(11) bond length is 1.50 Å. In the tenth C site, C(10) is bonded in a bent 120 degrees geometry to one C(15), one O(2), and one O(3) atom. The C(10)-C(15) bond length is 1.50 Å. The C(10)-O(2) bond length is 1.25 Å. The C(10)-O(3) bond length is 1.26 Å. In the eleventh C site, C(11) is bonded in a trigonal planar geometry to one C(18), one C(7), and one C(9) atom. The C(11)-C(18) bond length is 1.39 Å. In the twelfth C site, C(13) is bonded in a distorted single-bond geometry to one C(15) and one H(6) atom. The C(13)-C(15) bond length is 1.37 Å. The C(13)-H(6) bond length is 0.93 Å. In the thirteenth C site, C(14) is bonded in a distorted bent 120 degrees geometry to one C(26), one N(1), and one H(7) atom. The C(14)-C(26) bond length is 1.38 Å. The C(14)-N(1) bond length is 1.34 Å. The C(14)-H(7) bond length is 0.93 Å. In the fourteenth C site, C(15) is bonded in a trigonal planar geometry to one C(10), one C(13), and one C(25) atom. The C(15)-C(25) bond length is 1.39 Å. In the fifteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(11) and one H(9) atom. The C(18)-H(9) bond length is 0.93 Å. In the sixteenth C site, C(22) is bonded in a distorted single-bond geometry to one C(5) and one H(13) atom. The C(22)-H(13) bond length is 0.93 Å. In the seventeenth C site, C(24) is bonded in a distorted single-bond geometry to one C(8) and one H(15) atom. The C(24)-H(15) bond length is 0.93 Å. In the eighteenth C site, C(25) is bonded in a distorted single-bond geometry to one C(15) and one H(16) atom. The C(25)-H(16) bond length is 0.93 Å. In the nineteenth C site, C(26) is bonded in a distorted single-bond geometry to one C(14) and one H(17) atom. The C(26)-H(17) bond length is 0.93 Å. In the twentieth C site, C(29) is bonded in a trigonal planar geometry to one C(30), one C(31), and one C(32) atom. The C(29)-C(30) bond length is 1.51 Å. The C(29)-C(31) bond length is 1.38 Å. The C(29)-C(32) bond length is 1.39 Å. In the twenty-first C site, C(30) is bonded in a distorted bent 120 degrees geometry to one C(29), one O(1), and one O(4) atom. The C(30)-O(1) bond length is 1.23 Å. The C(30)-O(4) bond length is 1.28 Å. In the twenty-second C site, C(31) is bonded in a distorted single-bond geometry to one C(29) and one H(20) atom. The C(31)-H(20) bond length is 0.93 Å. In the twenty-third C site, C(32) is bonded in a distorted single-bond geometry to one C(29) and one H(21) atom. The C(32)-H(21) bond length is 0.93 Å. There are three inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Mn(1), one C(14), and one C(8) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(1), one C(2), and one C(6) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Mn(1), one C(1), and one C(5) atom. There are thirteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(7) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(13) atom. In the sixth H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the seventh H site, H(4) is bonded in a single-bond geometry to one C(7) atom. In the eighth H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the ninth H site, H(15) is bonded in a single-bond geometry to one C(24) atom. In the tenth H site, H(16) is bonded in a single-bond geometry to one C(25) atom. In the eleventh H site, H(17) is bonded in a single-bond geometry to one C(26) atom. In the twelfth H site, H(20) is bonded in a single-bond geometry to one C(31) atom. In the thirteenth H site, H(21) is bonded in a single-bond geometry to one C(32) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a single-bond geometry to one C(30) atom. In the second O site, O(2) is bonded in an L-shaped geometry to one Mn(1) and one C(10) atom. In the third O site, O(3) is bonded in a distorted L-shaped geometry to one Mn(1) and one C(10) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Mn(1) and one C(30) atom. Linkers: 8 c1ccc(-c2cc(-c3ccc(-n4ccnc4)cc3)cc(-c3ccccn3)n2)nc1 ,12 [O]C(=O)c1ccc(C([O])=O)cc1. Metal clusters: 8 O=[C]O[Mn]1O[C]O1 ,4 O=[C]O[Mn]O[C]=O. The MOF has largest included sphere 5.32 A, density 1.13 g/cm3, surface area 4746.57 m2/g, accessible volume 0.29 cm3/g