(CuC2O4)4(CuC17NH4O6)2(C13H8)3(C5H4)4(C4H3)4(CH)4 is Indium-derived structured and crystallizes in the orthorhombic Fddd space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules, thirty-two isobutylene molecules, thirty-two isoprene molecules, twenty-four C13H8 clusters, eight CuC17NH4O6 clusters, and sixteen CuC2O4 clusters. In each C13H8 cluster, there are seven inequivalent C sites. In the first C site, C(18) is bonded in a distorted single-bond geometry to one C(13) and one H(12) atom. The C(18)-C(13) bond length is 1.39 Å. The C(18)-H(12) bond length is 0.93 Å. In the second C site, C(2) is bonded in a distorted single-bond geometry to one C(1) and one H(1) atom. The C(2)-C(1) bond length is 1.39 Å. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(31), and one C(6) atom. The C(1)-C(31) bond length is 1.55 Å. The C(1)-C(6) bond length is 1.39 Å. In the fourth C site, C(6) is bonded in a single-bond geometry to one C(1) and one H(4) atom. The C(6)-H(4) bond length is 0.93 Å. In the fifth C site, C(31) is bonded in a tetrahedral geometry to two equivalent C(1) and two equivalent C(13) atoms. Both C(31)-C(13) bond lengths are 1.55 Å. In the sixth C site, C(14) is bonded in a distorted single-bond geometry to one C(13) and one H(9,11) atom. The C(14)-C(13) bond length is 1.39 Å. The C(14)-H(9,11) bond length is 0.93 Å. In the seventh C site, C(13) is bonded in a trigonal planar geometry to one C(14), one C(18), and one C(31) atom. There are four inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(4) is bonded in a single-bond geometry to one C(6) atom. In the third H site, H(9,11) is bonded in a single-bond geometry to one C(14) atom. In the fourth H site, H(12) is bonded in a single-bond geometry to one C(18) atom. In each CuC17NH4O6 cluster, Cu(2) is bonded in a 6-coordinate geometry to two equivalent O(5), two equivalent O(6), and two equivalent O(7) atoms. Both Cu(2)-O(5) bond lengths are 2.08 Å. Both Cu(2)-O(6) bond lengths are 1.88 Å. Both Cu(2)-O(7) bond lengths are 2.20 Å. There are nine inequivalent C sites. In the first C site, C(22) is bonded in a 3-coordinate geometry to one C(28), one C(29), and one C(4) atom. The C(22)-C(28) bond length is 1.15 Å. The C(22)-C(29) bond length is 1.29 Å. The C(22)-C(4) bond length is 1.45 Å. In the second C site, C(26) is bonded in a distorted bent 120 degrees geometry to one C(28), one C(29), one O(5), and one O(6) atom. The C(26)-C(28) bond length is 1.49 Å. The C(26)-C(29) bond length is 1.73 Å. The C(26)-O(5) bond length is 1.30 Å. The C(26)-O(6) bond length is 1.10 Å. In the third C site, C(27) is bonded in a single-bond geometry to one N(1) atom. The C(27)-N(1) bond length is 1.51 Å. In the fourth C site, C(28) is bonded in a 3-coordinate geometry to one C(22), one C(26), and one C(29) atom. The C(28)-C(29) bond length is 1.46 Å. In the fifth C site, C(29) is bonded in a 4-coordinate geometry to one C(22), one C(26), one C(28), and one O(5) atom. The C(29)-O(5) bond length is 1.80 Å. In the sixth C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(2) bond length is 0.93 Å. In the seventh C site, C(4) is bonded in a trigonal planar geometry to one C(22), one C(3), and one C(5) atom. The C(4)-C(5) bond length is 1.39 Å. In the eighth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(3) atom. The C(5)-H(3) bond length is 0.93 Å. In the ninth C site, C(30) is bonded in a 3-coordinate geometry to one N(1) and two equivalent O(7) atoms. The C(30)-N(1) bond length is 1.36 Å. Both C(30)-O(7) bond lengths are 1.06 Å. N(1) is bonded in a trigonal planar geometry to one C(30) and two equivalent C(27) atoms. There are two inequivalent H sites. In the first H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(3) is bonded in a single-bond geometry to one C(5) atom. There are three inequivalent O sites. In the first O site, O(5) is bonded in a 3-coordinate geometry to one Cu(2), one C(26), and one C(29) atom. In the second O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Cu(2) and one C(26) atom. In the third O site, O(7) is bonded in a 1-coordinate geometry to one Cu(2) and one C(30) atom. In each CuC2O4 cluster, Cu(1) is bonded in a distorted rectangular see-saw-like geometry to one O(1), one O(2), one O(3), and one O(4) atom. The Cu(1)-O(1) bond length is 1.90 Å. The Cu(1)-O(2) bond length is 1.93 Å. The Cu(1)-O(3) bond length is 1.95 Å. The Cu(1)-O(4) bond length is 2.00 Å. There are two inequivalent C sites. In the first C site, C(24) is bonded in a 2-coordinate geometry to one O(1) and one O(3) atom. The C(24)-O(1) bond length is 1.26 Å. The C(24)-O(3) bond length is 1.31 Å. In the second C site, C(25) is bonded in a 2-coordinate geometry to one O(2) and one O(4) atom. The C(25)-O(2) bond length is 1.15 Å. The C(25)-O(4) bond length is 1.33 Å. There are four inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(24) atom. In the second O site, O(3) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(24) atom. In the third O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(25) atom. In the fourth O site, O(4) is bonded in a distorted bent 120 degrees geometry to one Cu(1) and one C(25) atom. Linkers: 16 [O]C(=O)/C=C/c1ccc(C(c2ccc(/C=C/C([O])=O)cc2)(c2ccc([C]3[C]4[C]3C4([O])[O])cc2)c2ccc([C]3[C]4[C]3C4([O])[O])cc2)cc1 ,8 [O]C(=O)/C=C/c1ccc(C(c2ccc(/C=C/C([O])=O)cc2)(c2ccc(/C=C/C([O])=O)cc2)c2ccc(/C=C/C([O])=O)cc2)cc1. Metal clusters: 48 [Cu]. The MOF has largest included sphere 8.24 A, density 0.93 g/cm3, surface area 4431.88 m2/g, accessible volume 0.65 cm3/g