Al3P3(O6F)2 crystallizes in the monoclinic P2_1 space group. There are six inequivalent Al sites. In the first Al site, Al(1) is bonded to one O(1), one O(15), one O(17), one O(4), and one F(3) atom to form AlO4F trigonal bipyramids that share  a cornercorner with one Al(2)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(5)O4 tetrahedra. The corner-sharing octahedral tilt angles are 51°. The Al(1)-O(1) bond length is 1.78 Å. The Al(1)-O(15) bond length is 1.80 Å. The Al(1)-O(17) bond length is 1.79 Å. The Al(1)-O(4) bond length is 1.85 Å. The Al(1)-F(3) bond length is 1.93 Å. In the second Al site, Al(2) is bonded to one O(16), one O(22), one O(23), one O(8), one F(2), and one F(3) atom to form AlO4F2 octahedra that share  a cornercorner with one P(3)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, corners with two equivalent P(5)O4 tetrahedra,  a cornercorner with one Al(1)O4F trigonal bipyramid, and  a cornercorner with one Al(5)O4F trigonal bipyramid. The Al(2)-O(16) bond length is 1.86 Å. The Al(2)-O(22) bond length is 1.86 Å. The Al(2)-O(23) bond length is 1.87 Å. The Al(2)-O(8) bond length is 1.91 Å. The Al(2)-F(2) bond length is 1.91 Å. The Al(2)-F(3) bond length is 1.89 Å. In the third Al site, Al(3) is bonded to one O(18), one O(19), one O(3), one O(9), and one F(1) atom to form AlO4F trigonal bipyramids that share  a cornercorner with one Al(4)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra,  a cornercorner with one P(4)O4 tetrahedra, and  a cornercorner with one P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 49°. The Al(3)-O(18) bond length is 1.78 Å. The Al(3)-O(19) bond length is 1.83 Å. The Al(3)-O(3) bond length is 1.80 Å. The Al(3)-O(9) bond length is 1.83 Å. The Al(3)-F(1) bond length is 1.93 Å. In the fourth Al site, Al(4) is bonded to one O(10), one O(11), one O(12), one O(14), one F(1), and one F(4) atom to form AlO4F2 octahedra that share  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(6)O4 tetrahedra, corners with two equivalent P(2)O4 tetrahedra,  a cornercorner with one Al(3)O4F trigonal bipyramid, and  a cornercorner with one Al(6)O4F trigonal bipyramid. The Al(4)-O(10) bond length is 1.88 Å. The Al(4)-O(11) bond length is 1.86 Å. The Al(4)-O(12) bond length is 1.85 Å. The Al(4)-O(14) bond length is 1.88 Å. The Al(4)-F(1) bond length is 1.88 Å. The Al(4)-F(4) bond length is 1.88 Å. In the fifth Al site, Al(5) is bonded to one O(13), one O(20), one O(24), one O(6), and one F(2) atom to form AlO4F trigonal bipyramids that share  a cornercorner with one Al(2)O4F2 octahedra,  a cornercorner with one P(4)O4 tetrahedra,  a cornercorner with one P(5)O4 tetrahedra, and corners with two equivalent P(3)O4 tetrahedra. The corner-sharing octahedral tilt angles are 54°. The Al(5)-O(13) bond length is 1.91 Å. The Al(5)-O(20) bond length is 1.74 Å. The Al(5)-O(24) bond length is 1.78 Å. The Al(5)-O(6) bond length is 1.81 Å. The Al(5)-F(2) bond length is 1.91 Å. In the sixth Al site, Al(6) is bonded to one O(2), one O(21), one O(5), one O(7), and one F(4) atom to form AlO4F trigonal bipyramids that share  a cornercorner with one Al(4)O4F2 octahedra,  a cornercorner with one P(1)O4 tetrahedra,  a cornercorner with one P(2)O4 tetrahedra, and corners with two equivalent P(6)O4 tetrahedra. The corner-sharing octahedral tilt angles are 53°. The Al(6)-O(2) bond length is 1.79 Å. The Al(6)-O(21) bond length is 1.78 Å. The Al(6)-O(5) bond length is 1.78 Å. The Al(6)-O(7) bond length is 1.90 Å. The Al(6)-F(4) bond length is 1.93 Å. There are six inequivalent P sites. In the first P site, P(1) is bonded to one O(11), one O(18), one O(2), and one O(4) atom to form PO4 tetrahedra that share  a cornercorner with one Al(4)O4F2 octahedra,  a cornercorner with one Al(1)O4F trigonal bipyramid,  a cornercorner with one Al(3)O4F trigonal bipyramid, and  a cornercorner with one Al(6)O4F trigonal bipyramid. The corner-sharing octahedral tilt angles are 46°. The P(1)-O(11) bond length is 1.53 Å. The P(1)-O(18) bond length is 1.54 Å. The P(1)-O(2) bond length is 1.54 Å. The P(1)-O(4) bond length is 1.54 Å. In the second P site, P(2) is bonded to one O(12), one O(14), one O(5), and one O(9) atom to form PO4 tetrahedra that share corners with two equivalent Al(4)O4F2 octahedra,  a cornercorner with one Al(3)O4F trigonal bipyramid, and  a cornercorner with one Al(6)O4F trigonal bipyramid. The corner-sharing octahedral tilt angles range from 48-53°. The P(2)-O(12) bond length is 1.52 Å. The P(2)-O(14) bond length is 1.53 Å. The P(2)-O(5) bond length is 1.55 Å. The P(2)-O(9) bond length is 1.54 Å. In the third P site, P(3) is bonded to one O(1), one O(13), one O(20), and one O(8) atom to form PO4 tetrahedra that share  a cornercorner with one Al(2)O4F2 octahedra,  a cornercorner with one Al(1)O4F trigonal bipyramid, and corners with two equivalent Al(5)O4F trigonal bipyramids. The corner-sharing octahedral tilt angles are 49°. The P(3)-O(1) bond length is 1.55 Å. The P(3)-O(13) bond length is 1.55 Å. The P(3)-O(20) bond length is 1.54 Å. The P(3)-O(8) bond length is 1.52 Å. In the fourth P site, P(4) is bonded to one O(15), one O(16), one O(19), and one O(24) atom to form PO4 tetrahedra that share  a cornercorner with one Al(2)O4F2 octahedra,  a cornercorner with one Al(1)O4F trigonal bipyramid,  a cornercorner with one Al(3)O4F trigonal bipyramid, and  a cornercorner with one Al(5)O4F trigonal bipyramid. The corner-sharing octahedral tilt angles are 47°. The P(4)-O(15) bond length is 1.56 Å. The P(4)-O(16) bond length is 1.54 Å. The P(4)-O(19) bond length is 1.52 Å. The P(4)-O(24) bond length is 1.55 Å. In the fifth P site, P(5) is bonded to one O(17), one O(22), one O(23), and one O(6) atom to form PO4 tetrahedra that share corners with two equivalent Al(2)O4F2 octahedra,  a cornercorner with one Al(1)O4F trigonal bipyramid, and  a cornercorner with one Al(5)O4F trigonal bipyramid. The corner-sharing octahedral tilt angles range from 50-52°. The P(5)-O(17) bond length is 1.55 Å. The P(5)-O(22) bond length is 1.53 Å. The P(5)-O(23) bond length is 1.52 Å. The P(5)-O(6) bond length is 1.54 Å. In the sixth P site, P(6) is bonded to one O(10), one O(21), one O(3), and one O(7) atom to form PO4 tetrahedra that share  a cornercorner with one Al(4)O4F2 octahedra,  a cornercorner with one Al(3)O4F trigonal bipyramid, and corners with two equivalent Al(6)O4F trigonal bipyramids. The corner-sharing octahedral tilt angles are 49°. The P(6)-O(10) bond length is 1.55 Å. The P(6)-O(21) bond length is 1.51 Å. The P(6)-O(3) bond length is 1.53 Å. The P(6)-O(7) bond length is 1.55 Å. There are twenty-four inequivalent O sites. In the first O site, O(1) is bonded in a bent 150 degrees geometry to one Al(1) and one P(3) atom. In the second O site, O(2) is bonded in a bent 150 degrees geometry to one Al(6) and one P(1) atom. In the third O site, O(3) is bonded in a bent 150 degrees geometry to one Al(3) and one P(6) atom. In the fourth O site, O(4) is bonded in a distorted bent 150 degrees geometry to one Al(1) and one P(1) atom. In the fifth O site, O(5) is bonded in a bent 120 degrees geometry to one Al(6) and one P(2) atom. In the sixth O site, O(6) is bonded in a bent 120 degrees geometry to one Al(5) and one P(5) atom. In the seventh O site, O(7) is bonded in a distorted bent 120 degrees geometry to one Al(6) and one P(6) atom. In the eighth O site, O(8) is bonded in a bent 120 degrees geometry to one Al(2) and one P(3) atom. In the ninth O site, O(9) is bonded in a bent 120 degrees geometry to one Al(3) and one P(2) atom. In the tenth O site, O(10) is bonded in a bent 120 degrees geometry to one Al(4) and one P(6) atom. In the eleventh O site, O(11) is bonded in a distorted bent 120 degrees geometry to one Al(4) and one P(1) atom. In the twelfth O site, O(12) is bonded in a bent 120 degrees geometry to one Al(4) and one P(2) atom. In the thirteenth O site, O(13) is bonded in a bent 120 degrees geometry to one Al(5) and one P(3) atom. In the fourteenth O site, O(14) is bonded in a bent 120 degrees geometry to one Al(4) and one P(2) atom. In the fifteenth O site, O(15) is bonded in a bent 120 degrees geometry to one Al(1) and one P(4) atom. In the sixteenth O site, O(16) is bonded in a distorted bent 120 degrees geometry to one Al(2) and one P(4) atom. In the seventeenth O site, O(17) is bonded in a bent 120 degrees geometry to one Al(1) and one P(5) atom. In the eighteenth O site, O(18) is bonded in a bent 120 degrees geometry to one Al(3) and one P(1) atom. In the nineteenth O site, O(19) is bonded in a bent 150 degrees geometry to one Al(3) and one P(4) atom. In the twentieth O site, O(20) is bonded in a linear geometry to one Al(5) and one P(3) atom. In the twenty-first O site, O(21) is bonded in a linear geometry to one Al(6) and one P(6) atom. In the twenty-second O site, O(22) is bonded in a bent 120 degrees geometry to one Al(2) and one P(5) atom. In the twenty-third O site, O(23) is bonded in a bent 120 degrees geometry to one Al(2) and one P(5) atom. In the twenty-fourth O site, O(24) is bonded in a bent 150 degrees geometry to one Al(5) and one P(4) atom. There are four inequivalent F sites. In the first F site, F(1) is bonded in a bent 120 degrees geometry to one Al(3) and one Al(4) atom. In the second F site, F(2) is bonded in a bent 120 degrees geometry to one Al(2) and one Al(5) atom. In the third F site, F(3) is bonded in a bent 120 degrees geometry to one Al(1) and one Al(2) atom. In the fourth F site, F(4) is bonded in a bent 120 degrees geometry to one Al(4) and one Al(6) atom. Linkers: 12 [O]P([O])([O])=O. Metal clusters: 12 [Al]. The MOF has largest included sphere 3.98 A, density 1.86 g/cm3, surface area 2230.51 m2/g, accessible volume 0.24 cm3/g