Ni2C24N4H17O9(CH)8 is Indium-derived structured and crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules and four Ni2C24N4H17O9 clusters. In each Ni2C24N4H17O9 cluster, Ni(1) is bonded to one N(1), one N(2), one O(1), one O(2), one O(4), and one O(5) atom to form corner-sharing NiN2O4 octahedra. The corner-sharing octahedral tilt angles are 62°. The Ni(1)-N(1) bond length is 2.13 Å. The Ni(1)-N(2) bond length is 2.09 Å. The Ni(1)-O(1) bond length is 2.09 Å. The Ni(1)-O(2) bond length is 2.08 Å. The Ni(1)-O(4) bond length is 2.04 Å. The Ni(1)-O(5) bond length is 2.10 Å. There are twelve inequivalent C sites. In the first C site, C(1) is bonded in a distorted bent 120 degrees geometry to one O(1) and one O(3) atom. The C(1)-O(1) bond length is 1.25 Å. The C(1)-O(3) bond length is 1.26 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(4) atom. The C(2)-O(2) bond length is 1.25 Å. The C(2)-O(4) bond length is 1.27 Å. In the third C site, C(3) is bonded in a distorted single-bond geometry to one C(4) and one H(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-H(1) bond length is 0.95 Å. In the fourth C site, C(4) is bonded in a trigonal planar geometry to one C(3), one C(5), and one C(6) atom. The C(4)-C(5) bond length is 1.48 Å. The C(4)-C(6) bond length is 1.40 Å. In the fifth C site, C(5) is bonded in a distorted single-bond geometry to one C(4) and one H(2) atom. The C(5)-H(2) bond length is 0.95 Å. In the sixth C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(4), one N(1), and one H(3) atom. The C(6)-N(1) bond length is 1.34 Å. The C(6)-H(3) bond length is 0.95 Å. In the seventh C site, C(9) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(6) atom. The C(9)-N(1) bond length is 1.34 Å. The C(9)-H(6) bond length is 0.95 Å. In the eighth C site, C(10) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(16) atom. The C(10)-C(11) bond length is 1.38 Å. The C(10)-C(12) bond length is 1.47 Å. The C(10)-C(16) bond length is 1.40 Å. In the ninth C site, C(11) is bonded in a distorted bent 120 degrees geometry to one C(10), one N(2), and one H(7) atom. The C(11)-N(2) bond length is 1.34 Å. The C(11)-H(7) bond length is 0.95 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(10) and one H(8) atom. The C(12)-H(8) bond length is 0.95 Å. In the eleventh C site, C(14) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(10) atom. The C(14)-N(2) bond length is 1.33 Å. The C(14)-H(10) bond length is 0.95 Å. In the twelfth C site, C(16) is bonded in a distorted single-bond geometry to one C(10) and one H(12) atom. The C(16)-H(12) bond length is 0.95 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Ni(1), one C(6), and one C(9) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ni(1), one C(11), and one C(14) atom. There are nine inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(3) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(5) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(6) is bonded in a single-bond geometry to one C(9) atom. In the fifth H site, H(7) is bonded in a single-bond geometry to one C(11) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(10) is bonded in a single-bond geometry to one C(14) atom. In the eighth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the ninth H site, H(13) is bonded in a single-bond geometry to one O(5) atom. The H(13)-O(5) bond length is 0.95 Å. There are five inequivalent O sites. In the first O site, O(5) is bonded in a distorted single-bond geometry to two equivalent Ni(1) and one H(13) atom. In the second O site, O(1) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(1) atom. In the third O site, O(2) is bonded in a distorted bent 120 degrees geometry to one Ni(1) and one C(2) atom. In the fourth O site, O(3) is bonded in a single-bond geometry to one C(1) atom. In the fifth O site, O(4) is bonded in a bent 120 degrees geometry to one Ni(1) and one C(2) atom. Linkers: 16 [O]C(=O)/C=C/c1cccnc1. Metal clusters: 4 O=[C]O[Ni]1O[C]O[Ni](O)(O[C]=O)O[C]O1. The MOF has largest included sphere 4.93 A, density 1.26 g/cm3, surface area 4373.74 m2/g, accessible volume 0.27 cm3/g