Mo2Mn4C67N34H74O(CH)5(CH3)2 crystallizes in the trigonal R-3 space group. The structure consists of ninety 02329_fluka molecules and thirty-six 02329_fluka molecules inside a Mo2Mn4C67N34H74O framework. In the Mo2Mn4C67N34H74O framework, there are two inequivalent Mo sites. In the first Mo site, Mo(1) is bonded in a pentagonal bipyramidal geometry to one C(1), one C(2), one C(3), one C(4), one C(5), one C(6), and one C(7) atom. The Mo(1)-C(1) bond length is 2.15 Å. The Mo(1)-C(2) bond length is 2.15 Å. The Mo(1)-C(3) bond length is 2.14 Å. The Mo(1)-C(4) bond length is 2.11 Å. The Mo(1)-C(5) bond length is 2.18 Å. The Mo(1)-C(6) bond length is 2.13 Å. The Mo(1)-C(7) bond length is 2.18 Å. In the second Mo site, Mo(2) is bonded in a pentagonal bipyramidal geometry to one C(10), one C(11), one C(12), one C(13), one C(14), one C(8), and one C(9) atom. The Mo(2)-C(10) bond length is 2.17 Å. The Mo(2)-C(11) bond length is 2.19 Å. The Mo(2)-C(12) bond length is 2.16 Å. The Mo(2)-C(13) bond length is 2.05 Å. The Mo(2)-C(14) bond length is 2.11 Å. The Mo(2)-C(8) bond length is 2.15 Å. The Mo(2)-C(9) bond length is 2.17 Å. There are four inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a pentagonal bipyramidal geometry to one N(15), one N(16), one N(17), one N(18), one N(19), one N(4), and one O(1) atom. The Mn(1)-N(15) bond length is 2.35 Å. The Mn(1)-N(16) bond length is 2.33 Å. The Mn(1)-N(17) bond length is 2.29 Å. The Mn(1)-N(18) bond length is 2.26 Å. The Mn(1)-N(19) bond length is 2.29 Å. The Mn(1)-N(4) bond length is 2.21 Å. The Mn(1)-O(1) bond length is 2.29 Å. In the second Mn site, Mn(2) is bonded in a pentagonal bipyramidal geometry to one N(1), one N(20), one N(21), one N(22), one N(23), one N(24), and one N(6) atom. The Mn(2)-N(1) bond length is 2.23 Å. The Mn(2)-N(20) bond length is 2.32 Å. The Mn(2)-N(21) bond length is 2.32 Å. The Mn(2)-N(22) bond length is 2.32 Å. The Mn(2)-N(23) bond length is 2.25 Å. The Mn(2)-N(24) bond length is 2.27 Å. The Mn(2)-N(6) bond length is 2.24 Å. In the third Mn site, Mn(3) is bonded in a pentagonal bipyramidal geometry to one N(2), one N(25), one N(26), one N(27), one N(28), one N(29), and one N(8) atom. The Mn(3)-N(2) bond length is 2.26 Å. The Mn(3)-N(25) bond length is 2.29 Å. The Mn(3)-N(26) bond length is 2.23 Å. The Mn(3)-N(27) bond length is 2.30 Å. The Mn(3)-N(28) bond length is 2.29 Å. The Mn(3)-N(29) bond length is 2.35 Å. The Mn(3)-N(8) bond length is 2.23 Å. In the fourth Mn site, Mn(4) is bonded in a pentagonal bipyramidal geometry to one N(10), one N(12), one N(30), one N(31), one N(32), one N(33), and one N(34) atom. The Mn(4)-N(10) bond length is 2.21 Å. The Mn(4)-N(12) bond length is 2.23 Å. The Mn(4)-N(30) bond length is 2.31 Å. The Mn(4)-N(31) bond length is 2.32 Å. The Mn(4)-N(32) bond length is 2.29 Å. The Mn(4)-N(33) bond length is 2.26 Å. The Mn(4)-N(34) bond length is 2.29 Å. There are sixty-seven inequivalent C sites. In the first C site, C(12) is bonded in a distorted single-bond geometry to one Mo(2) and one N(12) atom. The C(12)-N(12) bond length is 1.12 Å. In the second C site, C(13) is bonded in a linear geometry to one Mo(2) and one N(13) atom. The C(13)-N(13) bond length is 1.26 Å. In the third C site, C(16) is bonded in a 3-coordinate geometry to one N(16), one H(4), and one H(5) atom. The C(16)-N(16) bond length is 1.49 Å. The C(16)-H(4) bond length is 0.97 Å. The C(16)-H(5) bond length is 0.97 Å. In the fourth C site, C(14) is bonded in a linear geometry to one Mo(2) and one N(14) atom. The C(14)-N(14) bond length is 1.18 Å. In the fifth C site, C(10) is bonded in a distorted linear geometry to one Mo(2) and one N(10) atom. The C(10)-N(10) bond length is 1.15 Å. In the sixth C site, C(11) is bonded in a distorted linear geometry to one Mo(2) and one N(11) atom. The C(11)-N(11) bond length is 1.14 Å. In the seventh C site, C(1) is bonded in a distorted linear geometry to one Mo(1) and one N(1) atom. The C(1)-N(1) bond length is 1.15 Å. In the eighth C site, C(2) is bonded in a distorted linear geometry to one Mo(1) and one N(2) atom. The C(2)-N(2) bond length is 1.15 Å. In the ninth C site, C(3) is bonded in a distorted linear geometry to one Mo(1) and one N(3,7) atom. The C(3)-N(3,7) bond length is 1.16 Å. In the tenth C site, C(4) is bonded in a distorted linear geometry to one Mo(1) and one N(4) atom. The C(4)-N(4) bond length is 1.15 Å. In the eleventh C site, C(5) is bonded in a distorted linear geometry to one Mo(1) and one N(5) atom. The C(5)-N(5) bond length is 1.16 Å. In the twelfth C site, C(6) is bonded in a distorted linear geometry to one Mo(1) and one N(6) atom. The C(6)-N(6) bond length is 1.17 Å. In the thirteenth C site, C(7) is bonded in a distorted linear geometry to one Mo(1) and one N(3,7) atom. The C(7)-N(3,7) bond length is 1.16 Å. In the fourteenth C site, C(8) is bonded in a distorted linear geometry to one Mo(2) and one N(8) atom. The C(8)-N(8) bond length is 1.16 Å. In the fifteenth C site, C(9) is bonded in a distorted linear geometry to one Mo(2) and one N(9) atom. The C(9)-N(9) bond length is 1.15 Å. In the sixteenth C site, C(15) is bonded in a distorted trigonal non-coplanar geometry to one N(15), one H(2), and one H(3) atom. The C(15)-N(15) bond length is 1.37 Å. The C(15)-H(2) bond length is 0.97 Å. The C(15)-H(3) bond length is 0.97 Å. In the seventeenth C site, C(17) is bonded in a 4-coordinate geometry to one C(18), one N(16), one H(6), and one H(7) atom. The C(17)-C(18) bond length is 1.39 Å. The C(17)-N(16) bond length is 1.44 Å. The C(17)-H(6) bond length is 0.97 Å. The C(17)-H(7) bond length is 0.97 Å. In the eighteenth C site, C(18) is bonded in a 4-coordinate geometry to one C(17), one N(17), one H(8), and one H(9) atom. The C(18)-N(17) bond length is 1.49 Å. The C(18)-H(8) bond length is 0.97 Å. The C(18)-H(9) bond length is 0.97 Å. In the nineteenth C site, C(19) is bonded in a distorted trigonal planar geometry to one C(20), one C(21), and one N(17) atom. The C(19)-C(20) bond length is 1.47 Å. The C(19)-C(21) bond length is 1.47 Å. The C(19)-N(17) bond length is 1.26 Å. In the twentieth C site, C(34) is bonded in a distorted trigonal non-coplanar geometry to one N(21); one H(30,32); and one H(31) atom. The C(34)-N(21) bond length is 1.42 Å. The C(34)-H(30,32) bond length is 0.97 Å. The C(34)-H(31) bond length is 0.97 Å. In the twenty-first C site, C(20) is bonded in a trigonal non-coplanar geometry to one C(19), one H(10), one H(11), and one H(12) atom. The C(20)-H(10) bond length is 0.96 Å. The C(20)-H(11) bond length is 0.96 Å. The C(20)-H(12) bond length is 0.96 Å. In the twenty-second C site, C(38) is bonded in a distorted trigonal planar geometry to one C(36), one C(39), and one N(23) atom. The C(38)-C(36) bond length is 1.50 Å. The C(38)-C(39) bond length is 1.39 Å. The C(38)-N(23) bond length is 1.34 Å. In the twenty-third C site, C(39) is bonded in a distorted single-bond geometry to one C(38) and one H(38) atom. The C(39)-H(38) bond length is 0.93 Å. In the twenty-fourth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(19), one C(22), and one N(18) atom. The C(21)-C(22) bond length is 1.39 Å. The C(21)-N(18) bond length is 1.36 Å. In the twenty-fifth C site, C(22) is bonded in a distorted single-bond geometry to one C(21) and one H(13) atom. The C(22)-H(13) bond length is 0.93 Å. In the twenty-sixth C site, C(51) is bonded in a distorted single-bond geometry to one C(49) and one N(26) atom. The C(51)-C(49) bond length is 1.48 Å. The C(51)-N(26) bond length is 1.30 Å. In the twenty-seventh C site, C(54) is bonded in a distorted single-bond geometry to one C(55) and one H(57) atom. The C(54)-C(55) bond length is 1.37 Å. The C(54)-H(57) bond length is 0.93 Å. In the twenty-eighth C site, C(55) is bonded in a distorted trigonal planar geometry to one C(54), one C(56), and one N(26) atom. The C(55)-C(56) bond length is 1.47 Å. The C(55)-N(26) bond length is 1.37 Å. In the twenty-ninth C site, C(24) is bonded in a distorted single-bond geometry to one C(25) and one H(15) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-H(15) bond length is 0.93 Å. In the thirtieth C site, C(59) is bonded in a 4-coordinate geometry to one C(58); one N(29); and two equivalent H(63,64) atoms. The C(59)-C(58) bond length is 1.43 Å. The C(59)-N(29) bond length is 1.46 Å. Both C(59)-H(63,64) bond lengths are 0.97 Å. In the thirty-first C site, C(25) is bonded in a distorted single-bond geometry to one C(24), one C(26), and one N(18) atom. The C(25)-C(26) bond length is 1.50 Å. The C(25)-N(18) bond length is 1.33 Å. In the thirty-second C site, C(65) is bonded in a distorted single-bond geometry to one C(66) and one H(70) atom. The C(65)-C(66) bond length is 1.40 Å. The C(65)-H(70) bond length is 0.93 Å. In the thirty-third C site, C(26) is bonded in a distorted single-bond geometry to one C(25) and one N(19) atom. The C(26)-N(19) bond length is 1.24 Å. In the thirty-fourth C site, C(28) is bonded in a 4-coordinate geometry to one C(29), one N(19), one H(19), and one H(20) atom. The C(28)-C(29) bond length is 1.46 Å. The C(28)-N(19) bond length is 1.51 Å. The C(28)-H(19) bond length is 0.97 Å. The C(28)-H(20) bond length is 0.97 Å. In the thirty-fifth C site, C(29) is bonded in a 3-coordinate geometry to one C(28), one N(15), one H(21), and one H(22) atom. The C(29)-N(15) bond length is 1.37 Å. The C(29)-H(21) bond length is 0.97 Å. The C(29)-H(22) bond length is 0.97 Å. In the thirty-sixth C site, C(30) is bonded in a 3-coordinate geometry to one N(24), one H(23), and one H(24) atom. The C(30)-N(24) bond length is 1.45 Å. The C(30)-H(23) bond length is 0.97 Å. The C(30)-H(24) bond length is 0.97 Å. In the thirty-seventh C site, C(31) is bonded in a 3-coordinate geometry to one N(20), one H(25), and one H(26) atom. The C(31)-N(20) bond length is 1.47 Å. The C(31)-H(25) bond length is 0.97 Å. The C(31)-H(26) bond length is 0.97 Å. In the thirty-eighth C site, C(32) is bonded in a distorted trigonal non-coplanar geometry to one N(20) and two equivalent H(27,28) atoms. The C(32)-N(20) bond length is 1.43 Å. Both C(32)-H(27,28) bond lengths are 0.97 Å. In the thirty-ninth C site, C(33) is bonded in a 3-coordinate geometry to one N(21); one H(29); and one H(30,32) atom. The C(33)-N(21) bond length is 1.46 Å. The C(33)-H(29) bond length is 0.97 Å. The C(33)-H(30,32) bond length is 0.97 Å. In the fortieth C site, C(35) is bonded in a 3-coordinate geometry to one N(22) and two equivalent H(33,34) atoms. The C(35)-N(22) bond length is 1.44 Å. Both C(35)-H(33,34) bond lengths are 0.97 Å. In the forty-first C site, C(36) is bonded in a distorted single-bond geometry to one C(37), one C(38), and one N(22) atom. The C(36)-C(37) bond length is 1.52 Å. The C(36)-N(22) bond length is 1.24 Å. In the forty-second C site, C(37) is bonded in a trigonal non-coplanar geometry to one C(36); one H(35); and two equivalent H(36,37) atoms. The C(37)-H(35) bond length is 0.96 Å. Both C(37)-H(36,37) bond lengths are 0.96 Å. In the forty-third C site, C(41) is bonded in a distorted single-bond geometry to one C(42) and one H(40) atom. The C(41)-C(42) bond length is 1.41 Å. The C(41)-H(40) bond length is 0.93 Å. In the forty-fourth C site, C(42) is bonded in a distorted single-bond geometry to one C(41), one C(43), and one N(23) atom. The C(42)-C(43) bond length is 1.47 Å. The C(42)-N(23) bond length is 1.32 Å. In the forty-fifth C site, C(43) is bonded in a distorted single-bond geometry to one C(42) and one N(24) atom. The C(43)-N(24) bond length is 1.28 Å. In the forty-sixth C site, C(45) is bonded in a 4-coordinate geometry to one C(46), one N(29), one H(44), and one H(45) atom. The C(45)-C(46) bond length is 1.47 Å. The C(45)-N(29) bond length is 1.49 Å. The C(45)-H(44) bond length is 0.97 Å. The C(45)-H(45) bond length is 0.97 Å. In the forty-seventh C site, C(46) is bonded in a 3-coordinate geometry to one C(45), one N(28), one H(46), and one H(47) atom. The C(46)-N(28) bond length is 1.40 Å. The C(46)-H(46) bond length is 0.97 Å. The C(46)-H(47) bond length is 0.97 Å. In the forty-eighth C site, C(47) is bonded in a 3-coordinate geometry to one N(28), one H(48), and one H(49) atom. The C(47)-N(28) bond length is 1.44 Å. The C(47)-H(48) bond length is 0.97 Å. The C(47)-H(49) bond length is 0.97 Å. In the forty-ninth C site, C(48) is bonded in a distorted trigonal non-coplanar geometry to one N(27) and two equivalent H(50,51) atoms. The C(48)-N(27) bond length is 1.41 Å. Both C(48)-H(50,51) bond lengths are 0.97 Å. In the fiftieth C site, C(49) is bonded in a distorted trigonal planar geometry to one C(50), one C(51), and one N(27) atom. The C(49)-C(50) bond length is 1.51 Å. The C(49)-N(27) bond length is 1.30 Å. In the fifty-first C site, C(50) is bonded in a trigonal non-coplanar geometry to one C(49); one H(52); and two equivalent H(53,54) atoms. The C(50)-H(52) bond length is 0.96 Å. Both C(50)-H(53,54) bond lengths are 0.96 Å. In the fifty-second C site, C(56) is bonded in a distorted single-bond geometry to one C(55), one C(57), and one N(25) atom. The C(56)-C(57) bond length is 1.58 Å. The C(56)-N(25) bond length is 1.24 Å. In the fifty-third C site, C(57) is bonded in a trigonal non-coplanar geometry to one C(56); one H(59); and two equivalent H(58,60) atoms. The C(57)-H(59) bond length is 0.96 Å. Both C(57)-H(58,60) bond lengths are 0.96 Å. In the fifty-fourth C site, C(58) is bonded in a 4-coordinate geometry to one C(59); one N(25); and two equivalent H(61,62) atoms. The C(58)-N(25) bond length is 1.47 Å. Both C(58)-H(61,62) bond lengths are 0.97 Å. In the fifty-fifth C site, C(60) is bonded in a distorted trigonal planar geometry to one C(61), one C(62), and one N(34) atom. The C(60)-C(61) bond length is 1.49 Å. The C(60)-C(62) bond length is 1.49 Å. The C(60)-N(34) bond length is 1.28 Å. In the fifty-sixth C site, C(61) is bonded in a trigonal non-coplanar geometry to one C(60); one H(65); and two equivalent H(66,67) atoms. The C(61)-H(65) bond length is 0.96 Å. Both C(61)-H(66,67) bond lengths are 0.96 Å. In the fifty-seventh C site, C(62) is bonded in a distorted trigonal planar geometry to one C(60), one C(63), and one N(33) atom. The C(62)-C(63) bond length is 1.39 Å. The C(62)-N(33) bond length is 1.36 Å. In the fifty-eighth C site, C(63) is bonded in a distorted single-bond geometry to one C(62) and one H(68) atom. The C(63)-H(68) bond length is 0.93 Å. In the fifty-ninth C site, C(66) is bonded in a distorted trigonal planar geometry to one C(65), one C(67), and one N(33) atom. The C(66)-C(67) bond length is 1.49 Å. The C(66)-N(33) bond length is 1.34 Å. In the sixtieth C site, C(67) is bonded in a distorted single-bond geometry to one C(66), one C(68), and one N(32) atom. The C(67)-C(68) bond length is 1.51 Å. The C(67)-N(32) bond length is 1.29 Å. In the sixty-first C site, C(68) is bonded in a trigonal non-coplanar geometry to one C(67), one H(71), one H(72), and one H(73) atom. The C(68)-H(71) bond length is 0.96 Å. The C(68)-H(72) bond length is 0.96 Å. The C(68)-H(73) bond length is 0.96 Å. In the sixty-second C site, C(69) is bonded in a 3-coordinate geometry to one N(32), one H(74), and one H(75) atom. The C(69)-N(32) bond length is 1.47 Å. The C(69)-H(74) bond length is 0.97 Å. The C(69)-H(75) bond length is 0.97 Å. In the sixty-third C site, C(70) is bonded in a 3-coordinate geometry to one N(31), one H(76), and one H(77) atom. The C(70)-N(31) bond length is 1.45 Å. The C(70)-H(76) bond length is 0.97 Å. The C(70)-H(77) bond length is 0.97 Å. In the sixty-fourth C site, C(71) is bonded in a 3-coordinate geometry to one N(31), one H(78), and one H(79) atom. The C(71)-N(31) bond length is 1.47 Å. The C(71)-H(78) bond length is 0.97 Å. The C(71)-H(79) bond length is 0.97 Å. In the sixty-fifth C site, C(72) is bonded in a 3-coordinate geometry to one N(30), one H(80), and one H(81) atom. The C(72)-N(30) bond length is 1.48 Å. The C(72)-H(80) bond length is 0.97 Å. The C(72)-H(81) bond length is 0.97 Å. In the sixty-sixth C site, C(73) is bonded in a 3-coordinate geometry to one N(30) and two equivalent H(82,83) atoms. The C(73)-N(30) bond length is 1.44 Å. Both C(73)-H(82,83) bond lengths are 0.97 Å. In the sixty-seventh C site, C(74) is bonded in a 3-coordinate geometry to one N(34) and two equivalent H(84,85) atoms. The C(74)-N(34) bond length is 1.45 Å. Both C(74)-H(84,85) bond lengths are 0.97 Å. There are thirty-three inequivalent N sites. In the first N site, N(1) is bonded in a bent 150 degrees geometry to one Mn(2) and one C(1) atom. In the second N site, N(2) is bonded in a distorted bent 150 degrees geometry to one Mn(3) and one C(2) atom. In the third N site, N(3,7) is bonded in a single-bond geometry to one C(3) atom. In the fourth N site, N(4) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(4) atom. In the fifth N site, N(5) is bonded in a single-bond geometry to one C(5) atom. In the sixth N site, N(6) is bonded in a distorted bent 120 degrees geometry to one Mn(2) and one C(6) atom. In the seventh N site, N(8) is bonded in a bent 150 degrees geometry to one Mn(3) and one C(8) atom. In the eighth N site, N(9) is bonded in a single-bond geometry to one C(9) atom. In the ninth N site, N(10) is bonded in a bent 150 degrees geometry to one Mn(4) and one C(10) atom. In the tenth N site, N(11) is bonded in a single-bond geometry to one C(11) atom. In the eleventh N site, N(12) is bonded in a bent 150 degrees geometry to one Mn(4) and one C(12) atom. In the twelfth N site, N(13) is bonded in a single-bond geometry to one C(13) atom. In the thirteenth N site, N(14) is bonded in a single-bond geometry to one C(14) atom. In the fourteenth N site, N(15) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one C(15), and one C(29) atom. In the fifteenth N site, N(16) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one C(16), and one C(17) atom. In the sixteenth N site, N(17) is bonded in a trigonal planar geometry to one Mn(1), one C(18), and one C(19) atom. In the seventeenth N site, N(18) is bonded in a trigonal planar geometry to one Mn(1), one C(21), and one C(25) atom. In the eighteenth N site, N(19) is bonded in a trigonal planar geometry to one Mn(1), one C(26), and one C(28) atom. In the nineteenth N site, N(20) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one C(31), and one C(32) atom. In the twentieth N site, N(21) is bonded in a trigonal non-coplanar geometry to one Mn(2), one C(33), and one C(34) atom. In the twenty-first N site, N(22) is bonded in a distorted trigonal planar geometry to one Mn(2), one C(35), and one C(36) atom. In the twenty-second N site, N(23) is bonded in a trigonal planar geometry to one Mn(2), one C(38), and one C(42) atom. In the twenty-third N site, N(24) is bonded in a trigonal planar geometry to one Mn(2), one C(30), and one C(43) atom. In the twenty-fourth N site, N(25) is bonded in a distorted trigonal planar geometry to one Mn(3), one C(56), and one C(58) atom. In the twenty-fifth N site, N(26) is bonded in a trigonal planar geometry to one Mn(3), one C(51), and one C(55) atom. In the twenty-sixth N site, N(27) is bonded in a distorted trigonal planar geometry to one Mn(3), one C(48), and one C(49) atom. In the twenty-seventh N site, N(28) is bonded in a distorted trigonal non-coplanar geometry to one Mn(3), one C(46), and one C(47) atom. In the twenty-eighth N site, N(29) is bonded in a distorted trigonal non-coplanar geometry to one Mn(3), one C(45), and one C(59) atom. In the twenty-ninth N site, N(30) is bonded in a trigonal non-coplanar geometry to one Mn(4), one C(72), and one C(73) atom. In the thirtieth N site, N(31) is bonded in a trigonal non-coplanar geometry to one Mn(4), one C(70), and one C(71) atom. In the thirty-first N site, N(32) is bonded in a trigonal planar geometry to one Mn(4), one C(67), and one C(69) atom. In the thirty-second N site, N(33) is bonded in a trigonal planar geometry to one Mn(4), one C(62), and one C(66) atom. In the thirty-third N site, N(34) is bonded in a trigonal planar geometry to one Mn(4), one C(60), and one C(74) atom. There are sixty-two inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(1) atom. The H(1)-O(1) bond length is 0.82 Å. In the second H site, H(2) is bonded in a single-bond geometry to one C(15) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(15) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(16) atom. In the sixth H site, H(6) is bonded in a single-bond geometry to one C(17) atom. In the seventh H site, H(7) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(8) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(9) is bonded in a single-bond geometry to one C(18) atom. In the tenth H site, H(10) is bonded in a single-bond geometry to one C(20) atom. In the eleventh H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the twelfth H site, H(12) is bonded in a single-bond geometry to one C(20) atom. In the thirteenth H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the fourteenth H site, H(15) is bonded in a single-bond geometry to one C(24) atom. In the fifteenth H site, H(19) is bonded in a single-bond geometry to one C(28) atom. In the sixteenth H site, H(20) is bonded in a single-bond geometry to one C(28) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(29) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(29) atom. In the nineteenth H site, H(23) is bonded in a single-bond geometry to one C(30) atom. In the twentieth H site, H(24) is bonded in a single-bond geometry to one C(30) atom. In the twenty-first H site, H(25) is bonded in a single-bond geometry to one C(31) atom. In the twenty-second H site, H(26) is bonded in a single-bond geometry to one C(31) atom. In the twenty-third H site, H(27,28) is bonded in a single-bond geometry to one C(32) atom. In the twenty-fourth H site, H(29) is bonded in a single-bond geometry to one C(33) atom. In the twenty-fifth H site, H(30,32) is bonded in a single-bond geometry to one C(33) atom. In the twenty-sixth H site, H(31) is bonded in a single-bond geometry to one C(34) atom. In the twenty-seventh H site, H(33,34) is bonded in a single-bond geometry to one C(35) atom. In the twenty-eighth H site, H(35) is bonded in a single-bond geometry to one C(37) atom. In the twenty-ninth H site, H(36,37) is bonded in a single-bond geometry to one C(37) atom. In the thirtieth H site, H(38) is bonded in a single-bond geometry to one C(39) atom. In the thirty-first H site, H(40) is bonded in a single-bond geometry to one C(41) atom. In the thirty-second H site, H(44) is bonded in a single-bond geometry to one C(45) atom. In the thirty-third H site, H(45) is bonded in a single-bond geometry to one C(45) atom. In the thirty-fourth H site, H(46) is bonded in a single-bond geometry to one C(46) atom. In the thirty-fifth H site, H(47) is bonded in a single-bond geometry to one C(46) atom. In the thirty-sixth H site, H(48) is bonded in a single-bond geometry to one C(47) atom. In the thirty-seventh H site, H(49) is bonded in a single-bond geometry to one C(47) atom. In the thirty-eighth H site, H(50,51) is bonded in a single-bond geometry to one C(48) atom. In the thirty-ninth H site, H(52) is bonded in a single-bond geometry to one C(50) atom. In the fortieth H site, H(53,54) is bonded in a single-bond geometry to one C(50) atom. In the forty-first H site, H(57) is bonded in a single-bond geometry to one C(54) atom. In the forty-second H site, H(58,60) is bonded in a single-bond geometry to one C(57) atom. In the forty-third H site, H(59) is bonded in a single-bond geometry to one C(57) atom. In the forty-fourth H site, H(61,62) is bonded in a single-bond geometry to one C(58) atom. In the forty-fifth H site, H(63,64) is bonded in a single-bond geometry to one C(59) atom. In the forty-sixth H site, H(65) is bonded in a single-bond geometry to one C(61) atom. In the forty-seventh H site, H(66,67) is bonded in a single-bond geometry to one C(61) atom. In the forty-eighth H site, H(68) is bonded in a single-bond geometry to one C(63) atom. In the forty-ninth H site, H(70) is bonded in a single-bond geometry to one C(65) atom. In the fiftieth H site, H(71) is bonded in a single-bond geometry to one C(68) atom. In the fifty-first H site, H(72) is bonded in a single-bond geometry to one C(68) atom. In the fifty-second H site, H(73) is bonded in a single-bond geometry to one C(68) atom. In the fifty-third H site, H(74) is bonded in a single-bond geometry to one C(69) atom. In the fifty-fourth H site, H(75) is bonded in a single-bond geometry to one C(69) atom. In the fifty-fifth H site, H(76) is bonded in a single-bond geometry to one C(70) atom. In the fifty-sixth H site, H(77) is bonded in a single-bond geometry to one C(70) atom. In the fifty-seventh H site, H(78) is bonded in a single-bond geometry to one C(71) atom. In the fifty-eighth H site, H(79) is bonded in a single-bond geometry to one C(71) atom. In the fifty-ninth H site, H(80) is bonded in a single-bond geometry to one C(72) atom. In the sixtieth H site, H(81) is bonded in a single-bond geometry to one C(72) atom. In the sixty-first H site, H(82,83) is bonded in a single-bond geometry to one C(73) atom. In the sixty-second H site, H(84,85) is bonded in a single-bond geometry to one C(74) atom. O(1) is bonded in a distorted water-like geometry to one Mn(1) and one H(1) atom. Linkers: 18 C/C1=N\CC[N]CC[N]CC/N=C(\C)c2cccc1n2. Metal clusters: 24 [Mn] ,12 [Mo]. The MOF has largest included sphere 6.93 A, density 1.18 g/cm3, surface area 4836.61 m2/g, accessible volume 0.37 cm3/g