AgH2(C3N2)2 crystallizes in the orthorhombic Pnma space group. Ag(1) is bonded in a square co-planar geometry to two equivalent N(1) and two equivalent N(2) atoms. Both Ag(1)-N(1) bond lengths are 2.42 Å. Both Ag(1)-N(2) bond lengths are 2.48 Å. There are three inequivalent C sites. In the first C site, C(1) is bonded in a distorted single-bond geometry to one C(2) and one N(1) atom. The C(1)-C(2) bond length is 1.44 Å. The C(1)-N(1) bond length is 1.14 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(1), one C(3), and one N(2) atom. The C(2)-C(3) bond length is 1.39 Å. The C(2)-N(2) bond length is 1.34 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one C(2), one N(2), and one H(1) atom. The C(3)-N(2) bond length is 1.33 Å. The C(3)-H(1) bond length is 1.01 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a distorted bent 150 degrees geometry to one Ag(1) and one C(1) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Ag(1), one C(2), and one C(3) atom. H(1) is bonded in a single-bond geometry to one C(3) atom. Linkers: 4 N#Cc1cnc(C#N)cn1. Metal clusters: 4 [Ag]. The MOF has largest included sphere 4.30 A, density 1.66 g/cm3, surface area 3360.65 m2/g, accessible volume 0.26 cm3/g