(CH)2Cd2C26N2H18SO11 crystallizes in the orthorhombic Pna2_1 space group. The structure consists of eight 02329_fluka molecules inside a Cd2C26N2H18SO11 framework. In the Cd2C26N2H18SO11 framework, there are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted trigonal bipyramidal geometry to one N(2), one O(3), one O(4), one O(5), and one O(6) atom. The Cd(1)-N(2) bond length is 2.32 Å. The Cd(1)-O(3) bond length is 2.50 Å. The Cd(1)-O(4) bond length is 2.31 Å. The Cd(1)-O(5) bond length is 2.51 Å. The Cd(1)-O(6) bond length is 2.33 Å. In the second Cd site, Cd(2) is bonded in a 6-coordinate geometry to one N(1), one H(20), one O(1), one O(2), one O(7), and one O(8) atom. The Cd(2)-N(1) bond length is 2.31 Å. The Cd(2)-H(20) bond length is 1.91 Å. The Cd(2)-O(1) bond length is 2.47 Å. The Cd(2)-O(2) bond length is 2.38 Å. The Cd(2)-O(7) bond length is 2.42 Å. The Cd(2)-O(8) bond length is 2.33 Å. There are twenty-six inequivalent C sites. In the first C site, C(1) is bonded in a trigonal planar geometry to one C(2), one C(6), and one C(8) atom. The C(1)-C(2) bond length is 1.40 Å. The C(1)-C(6) bond length is 1.39 Å. The C(1)-C(8) bond length is 1.49 Å. In the second C site, C(2) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(7) atom. The C(2)-C(3) bond length is 1.40 Å. The C(2)-C(7) bond length is 1.50 Å. In the third C site, C(3) is bonded in a trigonal planar geometry to one C(2), one C(4), and one S(1) atom. The C(3)-C(4) bond length is 1.39 Å. The C(3)-S(1) bond length is 1.78 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(3) and one H(3) atom. The C(4)-H(3) bond length is 0.93 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(1) and one H(5) atom. The C(6)-H(5) bond length is 0.93 Å. In the sixth C site, C(7) is bonded in a distorted bent 120 degrees geometry to one C(2), one O(1), and one O(2) atom. The C(7)-O(1) bond length is 1.25 Å. The C(7)-O(2) bond length is 1.27 Å. In the seventh C site, C(8) is bonded in a distorted bent 120 degrees geometry to one C(1), one O(3), and one O(4) atom. The C(8)-O(3) bond length is 1.24 Å. The C(8)-O(4) bond length is 1.27 Å. In the eighth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(14), and one S(1) atom. The C(9)-C(10) bond length is 1.41 Å. The C(9)-C(14) bond length is 1.39 Å. The C(9)-S(1) bond length is 1.78 Å. In the ninth C site, C(10) is bonded in a distorted single-bond geometry to one C(9) and one H(6) atom. The C(10)-H(6) bond length is 0.93 Å. In the tenth C site, C(12) is bonded in a distorted single-bond geometry to one C(13) and one H(8) atom. The C(12)-C(13) bond length is 1.38 Å. The C(12)-H(8) bond length is 0.93 Å. In the eleventh C site, C(13) is bonded in a trigonal planar geometry to one C(12), one C(14), and one C(16) atom. The C(13)-C(14) bond length is 1.40 Å. The C(13)-C(16) bond length is 1.50 Å. In the twelfth C site, C(14) is bonded in a trigonal planar geometry to one C(13), one C(15), and one C(9) atom. The C(14)-C(15) bond length is 1.51 Å. In the thirteenth C site, C(15) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(5), and one O(6) atom. The C(15)-O(5) bond length is 1.25 Å. The C(15)-O(6) bond length is 1.25 Å. In the fourteenth C site, C(16) is bonded in a bent 120 degrees geometry to one C(13), one O(7), and one O(8) atom. The C(16)-O(7) bond length is 1.25 Å. The C(16)-O(8) bond length is 1.25 Å. In the fifteenth C site, C(17) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(9) atom. The C(17)-N(2) bond length is 1.33 Å. The C(17)-H(9) bond length is 0.93 Å. In the sixteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(19) and one H(10) atom. The C(18)-C(19) bond length is 1.38 Å. The C(18)-H(10) bond length is 0.93 Å. In the seventeenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one C(22) atom. The C(19)-C(20) bond length is 1.39 Å. The C(19)-C(22) bond length is 1.51 Å. In the eighteenth C site, C(20) is bonded in a single-bond geometry to one C(19), one C(21), and one H(11) atom. The C(20)-C(21) bond length is 1.37 Å. The C(20)-H(11) bond length is 0.93 Å. In the nineteenth C site, C(21) is bonded in a distorted trigonal planar geometry to one C(20), one N(2), and one H(12) atom. The C(21)-N(2) bond length is 1.33 Å. The C(21)-H(12) bond length is 0.93 Å. In the twentieth C site, C(22) is bonded in a distorted water-like geometry to one C(19), one H(13), and one O(10) atom. The C(22)-H(13) bond length is 0.98 Å. The C(22)-O(10) bond length is 1.38 Å. In the twenty-first C site, C(23) is bonded in a distorted water-like geometry to one C(24), one H(14), and one O(9) atom. The C(23)-C(24) bond length is 1.52 Å. The C(23)-H(14) bond length is 0.98 Å. The C(23)-O(9) bond length is 1.37 Å. In the twenty-second C site, C(24) is bonded in a trigonal planar geometry to one C(23), one C(25), and one C(28) atom. The C(24)-C(25) bond length is 1.38 Å. The C(24)-C(28) bond length is 1.39 Å. In the twenty-third C site, C(25) is bonded in a single-bond geometry to one C(24), one C(26), and one H(15) atom. The C(25)-C(26) bond length is 1.36 Å. The C(25)-H(15) bond length is 0.93 Å. In the twenty-fourth C site, C(26) is bonded in a distorted trigonal planar geometry to one C(25), one N(1), and one H(16) atom. The C(26)-N(1) bond length is 1.33 Å. The C(26)-H(16) bond length is 0.93 Å. In the twenty-fifth C site, C(27) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(17) atom. The C(27)-N(1) bond length is 1.34 Å. The C(27)-H(17) bond length is 0.93 Å. In the twenty-sixth C site, C(28) is bonded in a distorted single-bond geometry to one C(24) and one H(18) atom. The C(28)-H(18) bond length is 0.93 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one Cd(2), one C(26), and one C(27) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Cd(1), one C(17), and one C(21) atom. There are eighteen inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one O(9) atom. The H(1)-O(9) bond length is 0.82 Å. In the second H site, H(2) is bonded in a single-bond geometry to one O(10) atom. The H(2)-O(10) bond length is 0.82 Å. In the third H site, H(3) is bonded in a single-bond geometry to one C(4) atom. In the fourth H site, H(5) is bonded in a single-bond geometry to one C(6) atom. In the fifth H site, H(6) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(9) is bonded in a single-bond geometry to one C(17) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(18) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(20) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(21) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(22) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(23) atom. In the thirteenth H site, H(15) is bonded in a single-bond geometry to one C(25) atom. In the fourteenth H site, H(16) is bonded in a single-bond geometry to one C(26) atom. In the fifteenth H site, H(17) is bonded in a single-bond geometry to one C(27) atom. In the sixteenth H site, H(18) is bonded in a single-bond geometry to one C(28) atom. In the seventeenth H site, H(19) is bonded in a single-bond geometry to one O(11) atom. The H(19)-O(11) bond length is 0.75 Å. In the eighteenth H site, H(20) is bonded in a distorted single-bond geometry to one Cd(2) and one O(11) atom. The H(20)-O(11) bond length is 0.86 Å. S(1) is bonded in a water-like geometry to one C(3) and one C(9) atom. There are eleven inequivalent O sites. In the first O site, O(10) is bonded in a water-like geometry to one C(22) and one H(2) atom. In the second O site, O(7) is bonded in a single-bond geometry to one Cd(2) and one C(16) atom. In the third O site, O(8) is bonded in a distorted L-shaped geometry to one Cd(2) and one C(16) atom. In the fourth O site, O(11) is bonded in a distorted bent 120 degrees geometry to one H(19) and one H(20) atom. In the fifth O site, O(9) is bonded in a water-like geometry to one C(23) and one H(1) atom. In the sixth O site, O(1) is bonded in a distorted single-bond geometry to one Cd(2) and one C(7) atom. In the seventh O site, O(2) is bonded in a distorted single-bond geometry to one Cd(2) and one C(7) atom. In the eighth O site, O(3) is bonded in a distorted single-bond geometry to one Cd(1) and one C(8) atom. In the ninth O site, O(4) is bonded in a distorted L-shaped geometry to one Cd(1) and one C(8) atom. In the tenth O site, O(5) is bonded in a single-bond geometry to one Cd(1) and one C(15) atom. In the eleventh O site, O(6) is bonded in a distorted single-bond geometry to one Cd(1) and one C(15) atom. Linkers: 4 [O]C(=O)c1cccc(Sc2cccc(C([O])=O)c2C([O])=O)c1C([O])=O ,4 O[C@H](c1ccncc1)[C@@H](O)c1ccncc1. Metal clusters: 4 [C]1O[Cd]2(O1)O[C]O2 ,3 O.O=[C]O[Cd].[O][C]=O ,1 O.[C]1O[Cd]2(O1)O[C]O2. The MOF has largest included sphere 3.87 A, density 1.59 g/cm3, surface area 3955.91 m2/g, accessible volume 0.27 cm3/g