CuC2O4CH2C4NH3O is Indium-derived structured and crystallizes in the cubic F23 space group. The structure is zero-dimensional and consists of ninety-six 02329_fluka molecules; thirty-two n,n',n''-trimethylbenzene-1,3,5-tricarboxamide molecules; and forty-eight CuC2O4 clusters. In each CuC2O4 cluster, there are two inequivalent Cu sites. In the first Cu site, Cu(1) is bonded in a distorted square co-planar geometry to two equivalent O(6) and two equivalent O(8) atoms. Both Cu(1)-O(6) bond lengths are 1.95 Å. Both Cu(1)-O(8) bond lengths are 1.96 Å. In the second Cu site, Cu(2) is bonded in a distorted rectangular see-saw-like geometry to two equivalent O(2) and two equivalent O(4) atoms. Both Cu(2)-O(2) bond lengths are 1.97 Å. Both Cu(2)-O(4) bond lengths are 1.96 Å. There are two inequivalent C sites. In the first C site, C(9) is bonded in a distorted bent 120 degrees geometry to one O(2) and one O(8) atom. The C(9)-O(2) bond length is 1.28 Å. The C(9)-O(8) bond length is 1.26 Å. In the second C site, C(10) is bonded in a distorted bent 120 degrees geometry to one O(4) and one O(6) atom. The C(10)-O(4) bond length is 1.25 Å. The C(10)-O(6) bond length is 1.25 Å. There are four inequivalent O sites. In the first O site, O(2) is bonded in a single-bond geometry to one Cu(2) and one C(9) atom. In the second O site, O(4) is bonded in a single-bond geometry to one Cu(2) and one C(10) atom. In the third O site, O(6) is bonded in a single-bond geometry to one Cu(1) and one C(10) atom. In the fourth O site, O(8) is bonded in a single-bond geometry to one Cu(1) and one C(9) atom. Linkers: 32 [O]C(=O)C[C@H](NC(=O)c1cc(C(=O)N[C@@H](CC([O])=O)C([O])=O)cc(C(=O)N[C@@H](CC([O])=O)C([O])=O)c1)C([O])=O. Metal clusters: 48 [C]1O[Cu]234O[C]O[Cu]2(O1)(O[C]O3)O[C]O4. The MOF has largest included sphere 12.14 A, density 0.99 g/cm3, surface area 3612.07 m2/g, accessible volume 0.54 cm3/g