MoMn2C35N17H40(CH)2 crystallizes in the trigonal R3 space group. The structure consists of eighteen 02329_fluka molecules inside a MoMn2C35N17H40 framework. In the MoMn2C35N17H40 framework, Mo(1) is bonded in a pentagonal bipyramidal geometry to one C(10), one C(11), one C(29), one C(32), one C(37), one C(6), and one C(8) atom. The Mo(1)-C(10) bond length is 2.11 Å. The Mo(1)-C(11) bond length is 2.14 Å. The Mo(1)-C(29) bond length is 2.14 Å. The Mo(1)-C(32) bond length is 2.16 Å. The Mo(1)-C(37) bond length is 2.17 Å. The Mo(1)-C(6) bond length is 2.12 Å. The Mo(1)-C(8) bond length is 2.15 Å. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a pentagonal bipyramidal geometry to one N(1), one N(10), one N(16), one N(3), one N(5), one N(6), and one N(7) atom. The Mn(1)-N(1) bond length is 2.34 Å. The Mn(1)-N(10) bond length is 2.28 Å. The Mn(1)-N(16) bond length is 2.21 Å. The Mn(1)-N(3) bond length is 2.26 Å. The Mn(1)-N(5) bond length is 2.26 Å. The Mn(1)-N(6) bond length is 2.23 Å. The Mn(1)-N(7) bond length is 2.26 Å. In the second Mn site, Mn(2) is bonded in a pentagonal bipyramidal geometry to one N(11), one N(12), one N(14), one N(17), one N(2), one N(8), and one N(9) atom. The Mn(2)-N(11) bond length is 2.33 Å. The Mn(2)-N(12) bond length is 2.26 Å. The Mn(2)-N(14) bond length is 2.29 Å. The Mn(2)-N(17) bond length is 2.32 Å. The Mn(2)-N(2) bond length is 2.23 Å. The Mn(2)-N(8) bond length is 2.32 Å. The Mn(2)-N(9) bond length is 2.22 Å. There are thirty-five inequivalent C sites. In the first C site, C(1) is bonded in a 3-coordinate geometry to one N(1), one H(1), and one H(2) atom. The C(1)-N(1) bond length is 1.44 Å. The C(1)-H(1) bond length is 0.97 Å. The C(1)-H(2) bond length is 0.97 Å. In the second C site, C(2) is bonded in a distorted trigonal planar geometry to one C(28), one C(33), and one N(2) atom. The C(2)-C(28) bond length is 1.50 Å. The C(2)-C(33) bond length is 1.38 Å. The C(2)-N(2) bond length is 1.30 Å. In the third C site, C(3) is bonded in a 3-coordinate geometry to one N(10), one H(3), and one H(4) atom. The C(3)-N(10) bond length is 1.45 Å. The C(3)-H(3) bond length is 0.97 Å. The C(3)-H(4) bond length is 0.97 Å. In the fourth C site, C(4) is bonded in a distorted trigonal planar geometry to one C(25), one C(7), and one N(7) atom. The C(4)-C(25) bond length is 1.49 Å. The C(4)-C(7) bond length is 1.49 Å. The C(4)-N(7) bond length is 1.26 Å. In the fifth C site, C(5) is bonded in a distorted trigonal planar geometry to one C(20), one C(31), and one N(3) atom. The C(5)-C(20) bond length is 1.49 Å. The C(5)-C(31) bond length is 1.45 Å. The C(5)-N(3) bond length is 1.29 Å. In the sixth C site, C(6) is bonded in a distorted linear geometry to one Mo(1) and one N(6) atom. The C(6)-N(6) bond length is 1.14 Å. In the seventh C site, C(7) is bonded in a distorted trigonal planar geometry to one C(24), one C(4), and one N(5) atom. The C(7)-C(24) bond length is 1.36 Å. The C(7)-N(5) bond length is 1.32 Å. In the eighth C site, C(8) is bonded in a distorted linear geometry to one Mo(1) and one N(8) atom. The C(8)-N(8) bond length is 1.16 Å. In the ninth C site, C(9) is bonded in a 3-coordinate geometry to one N(10) and two equivalent H(5,6) atoms. The C(9)-N(10) bond length is 1.45 Å. Both C(9)-H(5,6) bond lengths are 0.97 Å. In the tenth C site, C(10) is bonded in a distorted single-bond geometry to one Mo(1) and one N(16) atom. The C(10)-N(16) bond length is 1.13 Å. In the eleventh C site, C(11) is bonded in a distorted linear geometry to one Mo(1) and one N(4) atom. The C(11)-N(4) bond length is 1.15 Å. In the twelfth C site, C(12) is bonded in a 3-coordinate geometry to one N(11), one H(7), and one H(8) atom. The C(12)-N(11) bond length is 1.42 Å. The C(12)-H(7) bond length is 0.97 Å. The C(12)-H(8) bond length is 0.97 Å. In the thirteenth C site, C(13) is bonded in a distorted trigonal planar geometry to one C(17), one C(34), and one N(14) atom. The C(13)-C(17) bond length is 1.46 Å. The C(13)-C(34) bond length is 1.50 Å. The C(13)-N(14) bond length is 1.28 Å. In the fourteenth C site, C(15) is bonded in a distorted single-bond geometry to one C(31) and one H(10) atom. The C(15)-C(31) bond length is 1.38 Å. The C(15)-H(10) bond length is 0.93 Å. In the fifteenth C site, C(16) is bonded in a distorted trigonal non-coplanar geometry to one N(12), one H(11), and one H(12) atom. The C(16)-N(12) bond length is 1.41 Å. The C(16)-H(11) bond length is 0.97 Å. The C(16)-H(12) bond length is 0.97 Å. In the sixteenth C site, C(17) is bonded in a distorted trigonal planar geometry to one C(13), one C(26), and one N(2) atom. The C(17)-C(26) bond length is 1.39 Å. The C(17)-N(2) bond length is 1.34 Å. In the seventeenth C site, C(18) is bonded in a 3-coordinate geometry to one N(3), one H(13), and one H(14) atom. The C(18)-N(3) bond length is 1.43 Å. The C(18)-H(13) bond length is 0.97 Å. The C(18)-H(14) bond length is 0.97 Å. In the eighteenth C site, C(20) is bonded in a trigonal non-coplanar geometry to one C(5), one H(16), one H(17), and one H(18) atom. The C(20)-H(16) bond length is 0.96 Å. The C(20)-H(17) bond length is 0.96 Å. The C(20)-H(18) bond length is 0.96 Å. In the nineteenth C site, C(21) is bonded in a 3-coordinate geometry to one N(9) and two equivalent H(19,20) atoms. The C(21)-N(9) bond length is 1.47 Å. Both C(21)-H(19,20) bond lengths are 0.97 Å. In the twentieth C site, C(22) is bonded in a 3-coordinate geometry to one N(12), one H(21), and one H(22) atom. The C(22)-N(12) bond length is 1.43 Å. The C(22)-H(21) bond length is 0.97 Å. The C(22)-H(22) bond length is 0.97 Å. In the twenty-first C site, C(23) is bonded in a 3-coordinate geometry to one N(7) and two equivalent H(23,24) atoms. The C(23)-N(7) bond length is 1.44 Å. Both C(23)-H(23,24) bond lengths are 0.97 Å. In the twenty-second C site, C(24) is bonded in a distorted single-bond geometry to one C(7) and one H(25) atom. The C(24)-H(25) bond length is 0.93 Å. In the twenty-third C site, C(25) is bonded in a trigonal non-coplanar geometry to one C(4); one H(28); and two equivalent H(26,27) atoms. The C(25)-H(28) bond length is 0.96 Å. Both C(25)-H(26,27) bond lengths are 0.96 Å. In the twenty-fourth C site, C(26) is bonded in a distorted single-bond geometry to one C(17) and one H(29) atom. The C(26)-H(29) bond length is 0.93 Å. In the twenty-fifth C site, C(27) is bonded in a trigonal non-coplanar geometry to one C(28); one H(31); and two equivalent H(30,32) atoms. The C(27)-C(28) bond length is 1.48 Å. The C(27)-H(31) bond length is 0.96 Å. Both C(27)-H(30,32) bond lengths are 0.96 Å. In the twenty-sixth C site, C(28) is bonded in a distorted single-bond geometry to one C(2), one C(27), and one N(9) atom. The C(28)-N(9) bond length is 1.24 Å. In the twenty-seventh C site, C(29) is bonded in a distorted linear geometry to one Mo(1) and one N(15) atom. The C(29)-N(15) bond length is 1.14 Å. In the twenty-eighth C site, C(30) is bonded in a 3-coordinate geometry to one N(11) and two equivalent H(33,34) atoms. The C(30)-N(11) bond length is 1.42 Å. Both C(30)-H(33,34) bond lengths are 0.97 Å. In the twenty-ninth C site, C(31) is bonded in a distorted trigonal planar geometry to one C(15), one C(5), and one N(5) atom. The C(31)-N(5) bond length is 1.32 Å. In the thirtieth C site, C(32) is bonded in a distorted linear geometry to one Mo(1) and one N(13) atom. The C(32)-N(13) bond length is 1.14 Å. In the thirty-first C site, C(33) is bonded in a distorted single-bond geometry to one C(2) and one H(35) atom. The C(33)-H(35) bond length is 0.93 Å. In the thirty-second C site, C(34) is bonded in a trigonal non-coplanar geometry to one C(13); one H(37); and two equivalent H(36,38) atoms. The C(34)-H(37) bond length is 0.96 Å. Both C(34)-H(36,38) bond lengths are 0.96 Å. In the thirty-third C site, C(35) is bonded in a distorted trigonal non-coplanar geometry to one N(1) and two equivalent H(39,40) atoms. The C(35)-N(1) bond length is 1.42 Å. Both C(35)-H(39,40) bond lengths are 0.97 Å. In the thirty-fourth C site, C(36) is bonded in a 3-coordinate geometry to one N(14) and two equivalent H(41,42) atoms. The C(36)-N(14) bond length is 1.44 Å. Both C(36)-H(41,42) bond lengths are 0.97 Å. In the thirty-fifth C site, C(37) is bonded in a distorted linear geometry to one Mo(1) and one N(17) atom. The C(37)-N(17) bond length is 1.16 Å. There are seventeen inequivalent N sites. In the first N site, N(1) is bonded in a distorted trigonal non-coplanar geometry to one Mn(1), one C(1), and one C(35) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one Mn(2), one C(17), and one C(2) atom. In the third N site, N(3) is bonded in a trigonal planar geometry to one Mn(1), one C(18), and one C(5) atom. In the fourth N site, N(4) is bonded in a single-bond geometry to one C(11) atom. In the fifth N site, N(5) is bonded in a trigonal planar geometry to one Mn(1), one C(31), and one C(7) atom. In the sixth N site, N(6) is bonded in a distorted bent 150 degrees geometry to one Mn(1) and one C(6) atom. In the seventh N site, N(7) is bonded in a trigonal planar geometry to one Mn(1), one C(23), and one C(4) atom. In the eighth N site, N(8) is bonded in a 2-coordinate geometry to one Mn(2) and one C(8) atom. In the ninth N site, N(9) is bonded in a trigonal planar geometry to one Mn(2), one C(21), and one C(28) atom. In the tenth N site, N(10) is bonded in a trigonal non-coplanar geometry to one Mn(1), one C(3), and one C(9) atom. In the eleventh N site, N(11) is bonded in a distorted trigonal non-coplanar geometry to one Mn(2), one C(12), and one C(30) atom. In the twelfth N site, N(12) is bonded in a trigonal non-coplanar geometry to one Mn(2), one C(16), and one C(22) atom. In the thirteenth N site, N(13) is bonded in a single-bond geometry to one C(32) atom. In the fourteenth N site, N(14) is bonded in a trigonal planar geometry to one Mn(2), one C(13), and one C(36) atom. In the fifteenth N site, N(15) is bonded in a single-bond geometry to one C(29) atom. In the sixteenth N site, N(16) is bonded in a bent 150 degrees geometry to one Mn(1) and one C(10) atom. In the seventeenth N site, N(17) is bonded in a bent 150 degrees geometry to one Mn(2) and one C(37) atom. There are thirty-one inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(1) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(1) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(3) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(3) atom. In the fifth H site, H(5,6) is bonded in a single-bond geometry to one C(9) atom. In the sixth H site, H(7) is bonded in a single-bond geometry to one C(12) atom. In the seventh H site, H(8) is bonded in a single-bond geometry to one C(12) atom. In the eighth H site, H(10) is bonded in a single-bond geometry to one C(15) atom. In the ninth H site, H(11) is bonded in a single-bond geometry to one C(16) atom. In the tenth H site, H(12) is bonded in a single-bond geometry to one C(16) atom. In the eleventh H site, H(13) is bonded in a single-bond geometry to one C(18) atom. In the twelfth H site, H(14) is bonded in a single-bond geometry to one C(18) atom. In the thirteenth H site, H(16) is bonded in a single-bond geometry to one C(20) atom. In the fourteenth H site, H(17) is bonded in a single-bond geometry to one C(20) atom. In the fifteenth H site, H(18) is bonded in a single-bond geometry to one C(20) atom. In the sixteenth H site, H(19,20) is bonded in a single-bond geometry to one C(21) atom. In the seventeenth H site, H(21) is bonded in a single-bond geometry to one C(22) atom. In the eighteenth H site, H(22) is bonded in a single-bond geometry to one C(22) atom. In the nineteenth H site, H(23,24) is bonded in a single-bond geometry to one C(23) atom. In the twentieth H site, H(25) is bonded in a single-bond geometry to one C(24) atom. In the twenty-first H site, H(26,27) is bonded in a single-bond geometry to one C(25) atom. In the twenty-second H site, H(28) is bonded in a single-bond geometry to one C(25) atom. In the twenty-third H site, H(29) is bonded in a single-bond geometry to one C(26) atom. In the twenty-fourth H site, H(30,32) is bonded in a single-bond geometry to one C(27) atom. In the twenty-fifth H site, H(31) is bonded in a single-bond geometry to one C(27) atom. In the twenty-sixth H site, H(33,34) is bonded in a single-bond geometry to one C(30) atom. In the twenty-seventh H site, H(35) is bonded in a single-bond geometry to one C(33) atom. In the twenty-eighth H site, H(36,38) is bonded in a single-bond geometry to one C(34) atom. In the twenty-ninth H site, H(37) is bonded in a single-bond geometry to one C(34) atom. In the thirtieth H site, H(39,40) is bonded in a single-bond geometry to one C(35) atom. In the thirty-first H site, H(41,42) is bonded in a single-bond geometry to one C(36) atom. Linkers: 2 C/C1=N\CC[N]CC[N]CC/N=C(\C)c2cccc1n2. Metal clusters: 6 [Mn] ,3 [Mo]. The MOF has largest included sphere 4.92 A, density 1.42 g/cm3, surface area 4411.93 m2/g, accessible volume 0.20 cm3/g