ZnC10NH6O4C3H2(CH)4C2O is Indium-derived structured and crystallizes in the orthorhombic Pcca space group. The structure is zero-dimensional and consists of thirty-two 02329_fluka molecules; four 2,3-dimethyl-1,3-butadiene molecules; eight dimethyl ether molecules; and four ZnC10NH6O4 clusters. In each ZnC10NH6O4 cluster, Zn(1) is bonded in a square pyramidal geometry to one N(1), one O(1), one O(2), one O(3), and one O(4) atom. The Zn(1)-N(1) bond length is 2.03 Å. The Zn(1)-O(1) bond length is 2.04 Å. The Zn(1)-O(2) bond length is 2.03 Å. The Zn(1)-O(3) bond length is 2.02 Å. The Zn(1)-O(4) bond length is 2.03 Å. There are ten inequivalent C sites. In the first C site, C(6) is bonded in a distorted bent 120 degrees geometry to one C(14), one O(1), and one O(3) atom. The C(6)-C(14) bond length is 1.49 Å. The C(6)-O(1) bond length is 1.26 Å. The C(6)-O(3) bond length is 1.24 Å. In the second C site, C(8) is bonded in a distorted single-bond geometry to one C(14) and one H(6) atom. The C(8)-C(14) bond length is 1.38 Å. The C(8)-H(6) bond length is 0.93 Å. In the third C site, C(10) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(8) atom. The C(10)-N(1) bond length is 1.32 Å. The C(10)-H(8) bond length is 0.93 Å. In the fourth C site, C(11) is bonded in a distorted single-bond geometry to one C(15) and one H(9) atom. The C(11)-C(15) bond length is 1.37 Å. The C(11)-H(9) bond length is 0.93 Å. In the fifth C site, C(12) is bonded in a distorted bent 120 degrees geometry to one C(15), one O(2), and one O(4) atom. The C(12)-C(15) bond length is 1.50 Å. The C(12)-O(2) bond length is 1.25 Å. The C(12)-O(4) bond length is 1.25 Å. In the sixth C site, C(14) is bonded in a trigonal planar geometry to one C(16), one C(6), and one C(8) atom. The C(14)-C(16) bond length is 1.38 Å. In the seventh C site, C(15) is bonded in a trigonal planar geometry to one C(11), one C(12), and one C(19) atom. The C(15)-C(19) bond length is 1.38 Å. In the eighth C site, C(16) is bonded in a distorted single-bond geometry to one C(14) and one H(10) atom. The C(16)-H(10) bond length is 0.93 Å. In the ninth C site, C(18) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(11) atom. The C(18)-N(1) bond length is 1.32 Å. The C(18)-H(11) bond length is 0.93 Å. In the tenth C site, C(19) is bonded in a distorted single-bond geometry to one C(15) and one H(12) atom. The C(19)-H(12) bond length is 0.93 Å. N(1) is bonded in a trigonal planar geometry to one Zn(1), one C(10), and one C(18) atom. There are six inequivalent H sites. In the first H site, H(6) is bonded in a single-bond geometry to one C(8) atom. In the second H site, H(8) is bonded in a single-bond geometry to one C(10) atom. In the third H site, H(9) is bonded in a single-bond geometry to one C(11) atom. In the fourth H site, H(10) is bonded in a single-bond geometry to one C(16) atom. In the fifth H site, H(11) is bonded in a single-bond geometry to one C(18) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(19) atom. There are four inequivalent O sites. In the first O site, O(1) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the second O site, O(2) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(12) atom. In the third O site, O(3) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(6) atom. In the fourth O site, O(4) is bonded in a bent 120 degrees geometry to one Zn(1) and one C(12) atom. Linkers: 8 [O]C(=O)c1ccc(Oc2ccc(C([O])=O)cc2)cc1 ,4 c1cc(-c2ccncc2)ccn1. Metal clusters: 4 [C]1O[Zn]23O[C]O[Zn](O1)(O[C]O2)O[C]O3. The MOF has largest included sphere 4.76 A, density 1.28 g/cm3, surface area 4434.12 m2/g, accessible volume 0.37 cm3/g