Na2AgC21N2H10S3O7Cl(CH3)8 crystallizes in the monoclinic P2_1/c space group. The structure consists of thirty-two 02329_fluka molecules inside a Na2AgC21N2H10S3O7Cl framework. In the Na2AgC21N2H10S3O7Cl framework, there are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a tetrahedral geometry to one O(1), one O(4), one O(5), and one O(7) atom. The Na(1)-O(1) bond length is 2.18 Å. The Na(1)-O(4) bond length is 2.19 Å. The Na(1)-O(5) bond length is 2.22 Å. The Na(1)-O(7) bond length is 2.33 Å. In the second Na site, Na(2) is bonded in a 4-coordinate geometry to one O(2), one O(3), one O(6), and one O(7) atom. The Na(2)-O(2) bond length is 2.92 Å. The Na(2)-O(3) bond length is 2.32 Å. The Na(2)-O(6) bond length is 2.31 Å. The Na(2)-O(7) bond length is 2.34 Å. Ag(1) is bonded in a linear geometry to one C(1) and one Cl(1) atom. The Ag(1)-C(1) bond length is 2.06 Å. The Ag(1)-Cl(1) bond length is 2.30 Å. There are twenty-one inequivalent C sites. In the first C site, C(1) is bonded in a distorted trigonal planar geometry to one Ag(1), one N(1), and one N(2) atom. The C(1)-N(1) bond length is 1.35 Å. The C(1)-N(2) bond length is 1.35 Å. In the second C site, C(2) is bonded in a distorted bent 120 degrees geometry to one N(2) and one H(1) atom. The C(2)-N(2) bond length is 1.35 Å. The C(2)-H(1) bond length is 0.93 Å. In the third C site, C(3) is bonded in a distorted bent 120 degrees geometry to one N(1) and one H(2) atom. The C(3)-N(1) bond length is 1.37 Å. The C(3)-H(2) bond length is 0.93 Å. In the fourth C site, C(4) is bonded in a distorted single-bond geometry to one C(5), one C(9), and one N(1) atom. The C(4)-C(5) bond length is 1.41 Å. The C(4)-C(9) bond length is 1.40 Å. The C(4)-N(1) bond length is 1.44 Å. In the fifth C site, C(6) is bonded in a distorted single-bond geometry to one C(5), one C(7), and one H(3) atom. The C(6)-C(5) bond length is 1.40 Å. The C(6)-C(7) bond length is 1.37 Å. The C(6)-H(3) bond length is 0.93 Å. In the sixth C site, C(5) is bonded in a trigonal planar geometry to one C(13), one C(4), and one C(6) atom. The C(5)-C(13) bond length is 1.52 Å. In the seventh C site, C(7) is bonded in a trigonal planar geometry to one C(6), one C(8), and one S(1) atom. The C(7)-C(8) bond length is 1.39 Å. The C(7)-S(1) bond length is 1.80 Å. In the eighth C site, C(8) is bonded in a single-bond geometry to one C(7), one C(9), and one H(4) atom. The C(8)-C(9) bond length is 1.39 Å. The C(8)-H(4) bond length is 0.93 Å. In the ninth C site, C(9) is bonded in a trigonal planar geometry to one C(10), one C(4), and one C(8) atom. The C(9)-C(10) bond length is 1.52 Å. In the tenth C site, C(10) is bonded in a single-bond geometry to one C(9) and one H(5) atom. The C(10)-H(5) bond length is 0.98 Å. In the eleventh C site, C(13) is bonded in a single-bond geometry to one C(5) and one H(12) atom. The C(13)-H(12) bond length is 0.98 Å. In the twelfth C site, C(16) is bonded in a distorted trigonal planar geometry to one C(17), one C(21), and one N(2) atom. The C(16)-C(17) bond length is 1.40 Å. The C(16)-C(21) bond length is 1.39 Å. The C(16)-N(2) bond length is 1.46 Å. In the thirteenth C site, C(17) is bonded in a trigonal planar geometry to one C(16), one C(18), and one C(22) atom. The C(17)-C(18) bond length is 1.38 Å. The C(17)-C(22) bond length is 1.51 Å. In the fourteenth C site, C(18) is bonded in a distorted single-bond geometry to one C(17), one C(19), and one H(19) atom. The C(18)-C(19) bond length is 1.39 Å. The C(18)-H(19) bond length is 0.93 Å. In the fifteenth C site, C(19) is bonded in a trigonal planar geometry to one C(18), one C(20), and one S(2) atom. The C(19)-C(20) bond length is 1.37 Å. The C(19)-S(2) bond length is 1.78 Å. In the sixteenth C site, C(20) is bonded in a single-bond geometry to one C(19), one C(21), and one H(20) atom. The C(20)-C(21) bond length is 1.41 Å. The C(20)-H(20) bond length is 0.93 Å. In the seventeenth C site, C(21) is bonded in a trigonal planar geometry to one C(16), one C(20), and one C(25) atom. The C(21)-C(25) bond length is 1.54 Å. In the eighteenth C site, C(22) is bonded in a single-bond geometry to one C(17) and one H(21) atom. The C(22)-H(21) bond length is 0.98 Å. In the nineteenth C site, C(25) is bonded in a single-bond geometry to one C(21) and one H(28) atom. The C(25)-H(28) bond length is 0.98 Å. In the twentieth C site, C(28) is bonded in a single-bond geometry to one S(3) atom. The C(28)-S(3) bond length is 1.68 Å. In the twenty-first C site, C(29) is bonded in a single-bond geometry to one S(3) atom. The C(29)-S(3) bond length is 1.76 Å. There are two inequivalent N sites. In the first N site, N(1) is bonded in a trigonal planar geometry to one C(1), one C(3), and one C(4) atom. In the second N site, N(2) is bonded in a trigonal planar geometry to one C(1), one C(16), and one C(2) atom. There are ten inequivalent H sites. In the first H site, H(1) is bonded in a single-bond geometry to one C(2) atom. In the second H site, H(2) is bonded in a single-bond geometry to one C(3) atom. In the third H site, H(3) is bonded in a single-bond geometry to one C(6) atom. In the fourth H site, H(4) is bonded in a single-bond geometry to one C(8) atom. In the fifth H site, H(5) is bonded in a single-bond geometry to one C(10) atom. In the sixth H site, H(12) is bonded in a single-bond geometry to one C(13) atom. In the seventh H site, H(19) is bonded in a single-bond geometry to one C(18) atom. In the eighth H site, H(20) is bonded in a single-bond geometry to one C(20) atom. In the ninth H site, H(21) is bonded in a single-bond geometry to one C(22) atom. In the tenth H site, H(28) is bonded in a single-bond geometry to one C(25) atom. There are three inequivalent S sites. In the first S site, S(1) is bonded in a distorted trigonal non-coplanar geometry to one C(7), one O(1), one O(2), and one O(3) atom. The S(1)-O(1) bond length is 1.38 Å. The S(1)-O(2) bond length is 1.43 Å. The S(1)-O(3) bond length is 1.43 Å. In the second S site, S(2) is bonded in a distorted trigonal non-coplanar geometry to one C(19), one O(4), one O(5), and one O(6) atom. The S(2)-O(4) bond length is 1.39 Å. The S(2)-O(5) bond length is 1.42 Å. The S(2)-O(6) bond length is 1.39 Å. In the third S site, S(3) is bonded in a distorted single-bond geometry to one C(28), one C(29), and one O(7) atom. The S(3)-O(7) bond length is 1.53 Å. There are seven inequivalent O sites. In the first O site, O(1) is bonded in a linear geometry to one Na(1) and one S(1) atom. In the second O site, O(5) is bonded in a distorted bent 120 degrees geometry to one Na(1) and one S(2) atom. In the third O site, O(6) is bonded in a distorted bent 120 degrees geometry to one Na(2) and one S(2) atom. In the fourth O site, O(2) is bonded in a single-bond geometry to one Na(2) and one S(1) atom. In the fifth O site, O(3) is bonded in a bent 120 degrees geometry to one Na(2) and one S(1) atom. In the sixth O site, O(4) is bonded in a bent 150 degrees geometry to one Na(1) and one S(2) atom. In the seventh O site, O(7) is bonded in a distorted trigonal planar geometry to one Na(1), one Na(2), and one S(3) atom. Cl(1) is bonded in a single-bond geometry to one Ag(1) atom. Linkers: 4 CC(C)c1cc(S([O])([O])[O])cc(C(C)C)c1N1[C]N(c2c(C(C)C)cc(S([O])([O])[O])cc2C(C)C)C=C1. Metal clusters: 8 [Na]. The MOF has largest included sphere 5.53 A, density 1.16 g/cm3, surface area 4915.34 m2/g, accessible volume 0.28 cm3/g