Water pollution has become a global problem and its impact on the health of the human population is growing day by day. This study aims to assess the pollution of the Cibin River (Romania) by a physicochemical analysis. Water samples have been collected from four locations along the Cibin River over a period of 12 months. At this time, there are several commonly used Multiple-Criteria Decision Analysis (MCDA) methods for the assessing the impact of pollutants on the environment. In this research, we used the Analytic Hierarchy Process (AHP) multi-criteria method to evaluate each sampling station's physicochemical parameters. The significant results place the river in the first (sampling stations 1, 2 and 3) and second (sampling stations 4) water quality classes. Another significant result of this work is that the research using GIS software allowed an integrated automatic data collection system and displays interactive results.