The selective catalytic reduction (SCR) of nitrogen dioxide in an air flow modeling the exhaust gas from an internal combustion engine is studied. Granulated V2O5 (13.5%)-MnO2 (0.7-1.0%)/Al2O3 powder (AVK-10M catalyst) and ammonia injected into a SCR catalytic cell are used as a heterogeneous catalyst of NO2 reduction and a reducing agent, respectively. If the efficiency of NO2 removal is high enough and satisfies the requirements of the State Sanitary Standards for the maximum permissible concentrations of substances emitted into the atmosphere ( = 0.085 mg/m(3)), the reducing agent (ammonia) is not completely consumed during SCR, so a considerable amount of NH3 can be released into the atmosphere. Therefore, a strict control of both NO2 and unreacted ammonia emissions is needed. The dependences of the concentrations of [NH3] and [NO2] on the [NH3]/[NO2] ratio for the model air flow passed through the AVK-10M granular heterogeneous catalyst are measured. It is found that the maximum degree of removal of NO2 from the air takes place at [NH3]/[NO2] = 1.3. In the conventional process, the concentration of [NO2] drop from 530.00 to 0.07 mg/m(3), i.e., below the . At the same time, the ammonia concentration increases to [NH3] = 3.4 mg/m(3), which becomes 85 times the , 0.04 mg/m(3). To remove unreacted ammonia from air flows, we developed [P-(SO3 (-))(2) center dot Me2+] sulfocationites, where Me are the Cu and/or Ca ions, P is a styrene-divinylbenzene copolymer. It is shown that the concentration of ammonia passed through the adsorption cell filled with a freshly sulfocationite drops below = 0.04 mg/m(3). The dependences of the dynamic exchange capacity (DEC) before ammonia breakthrough for the [P-(SO3 (-))(2) center dot Cu2+] delta-sulfocationite on the air flow rate, [NH3] concentration, and humidity are measured. The maximum value of the DEC, delta = 59.5 mg/cm(3), is observed at an air flow velocity of 2.171 m/s, [NH3] = 0.0035 mg/L, and 75% humidity. To illustrate practical applications of the proposed improved SCR method, it is shown that a 3-L replaceable [P-(SO3 (-))(2) center dot Cu2+] sorbent cartridge in a SCR exhaust gas purifier for a car internal combustion engine does not need replacement more frequently than every 50000 km.