Thermal energy storage is at the height of its popularity to harvest, store, and save energy for short-term or long-term use in new energy generation systems. It is forecasted that the global thermal energy storage market for 2015-2019 will cross US$1,300 million in revenue, where the highest growth is expected to be in Europe, Middle East, and Africa followed by Asia-Pacific region. Thermal energy storage has become an inevitable component of fluctuant renewable energy systems due to their significant role in increasing efficiency and Quality of Service (QoS). Currently, one major research stream in such systems is improving the efficiency of heat exchangers and heat carriers. Hence, studying thermal behavior and thermophysical properties of heat storages is of great importance. In this study, we review a common but not very well-known problem of supercooling of Phase Change Materials (PCM). Supercooling is a thermophysical property of PCMs that is problematic in thermal storage applications. This review looks at supercooling from another point of View and investigates applications (such as specialized thermal storage applications) that can put supercooling into operation. To achieve this, development of techniques to increase state stability and designing reliable and stable supercooled heat storage systems will be investigated. The study will look at the thermal energy storage of supercooled liquids, degree and measurement of supercooling. Furthermore, factors that influence degree of supercooling and their effect on output capacity will be discussed. It looks at the supercooled material in four Major categories and looks into the mechanisms for triggering crystallization in supercooled liquids. Applications including solar thermal storage will be the discussed in details. From the results discussed in this review researchers will identify and gain insight into supercooling control techniques, which are necessary for developing efficient heat exchangers, and also essential for promoting adoption of sustainable renewable energies.