Trees Outside Forests (TOF) represent a source of lignocellulosic biomass that has received increasing attention in the recent years. While some studies have already investigated the potential of TOF in Germany, a spatial explicit analysis, specifically for Baden-Wuerttemberg, is still lacking. We used a unique wall-to-wall airborne Light Detection and Ranging (LiDAR) dataset combined with OpenStreetMap (OSM) data to map and classify TOF of the federal state of Baden-Wuerttemberg (similar to 35.000 km(2)) in south-western Germany. Furthermore, from annual biomass potentials of TOF areas collected from available literature, we calculated the mean annual biomass supply for all TOF areas in Baden-Wuerttemberg. This combination of remote sensing-based classification and available literature resulted in a mean annual biomass supply between similar to 490,000-730,000 t from TOF in Baden-Wuerttemberg. The classification congruence on three reference sites was very high (similar to 99%) using a simple filter technique applied to the LiDAR data and masking man-made objects using OSM data. In contrast, the available literature revealed a high variability of biomass potentials, supporting the demand for an inventory system. Still, the results demonstrate the applicability of LiDAR based vegetation mapping and the value of OSM data in Baden-Wuerttemberg to detect man-made objects. (C) 2017 Elsevier B.V. All rights reserved.