The operation principle of digital voltage-mode controlled buck converter with dual-edge modulation is analyzed in this paper. Based on the state equation of buck converter and six possible evolutions in one switching cycle, the discrete iterative-map model of digital voltage-mode controlled buck converter with dual-edge modulation is established. Ignoring the quantization error of analog-digital converter and on the basis of its discrete iterative-map model, the nonlinear dynamical behavior of digital voltage-mode controlled buck converter with dual-edge modulation is investigated in detail. Taking the input voltage and the load resistance as bifurcation parameters, the output voltage bifurcation diagram and the inductor current bifurcation diagram are plotted. Through analyzing the bifurcation diagrams, it is indicated that there are two kinds of similar but different Hopf bifurcation phenomena. By use of Poincare section, time-domain simulation waveforms and phase portraits, two different Hopf bifurcations and low-frequency oscillation phenomena are compared and studied. Observing the inductor current and capacitor voltage waveforms respectively, it is obviously found that their oscillation frequencies and amplitudes are different, the shapes of two Poincare sections and phase portraits are also different. In order to verify the correctness of the simulation and theoretical analysis, the eigenvalues of Jacobian matrix of the discrete iterative map model are introduced and solved in two kinds of stable evolutions. Through analyzing variation of eigenvalues of Jacobi matrix with input voltage, the existence and difference of two kinds of Hopf bifurcation phenomena are proved theoretically. Moreover, it is observed in this paper that the odd period-doubling bifurcation phenomenon exists in digital voltage-mode controlled buck converter with dual-edge modulation for the first time, where the operation state of the buck converter turns from period-one into period-three. Its authenticity is verified by using the time-domain simulation waveforms and phase portraits. In order to approach to the actual circuit, the equivalent series resistances of capacitor and inductor are considered. The actual circuit is simulated by using the software Psim. A comparison shows that there are little differences between the theoretical simulation and the actual circuit simulation. So the theoretical simulation can be used to analyze the performances of the actual circuit. The research results in this paper have guiding significance and practical value for designing the digital voltage-mode controlled buck converter with dual-edge modulation.