This paper proposes a positive temperature coefficient (PTC) self-heating method, in which EVs can be operated independently of external power source at low temperature, with a lithium-ion battery (LIB) pack discharging electricity to provide PTC material with power. Three comparative heating experiments have been carried out respectively. With charge/discharge tests implemented, results demonstrate the superiority of the self-heating method, proving that the discharge capability, especially the discharge capacity of the self-heated pack is better than that of the external power heated pack. In order to evaluate the heating effect of this method, further studies are conducted on temperature distribution uniformity in the heated pack. Firstly, a geometric model is established, and heat-generation rate of PTC materials and LIB are calculated. Then, thermal characteristics of the self-heating experiment processes are numerically simulated, validating the accuracy of our modeling and confirming that temperature distributions inside the pack after heating are kept in good uniformity. Therefore, the PTC self-heating method is verified to have a significant effect on the improvement of performance of LIB at low temperature.