An organic p-n bilayer, comprising of an n-type perylene derivative (PTCBI) and p-type lead phthalocyanine (PbPc), was prepared and examined in terms of photoelectrode in the water phase. The PTCBI/PbPc bilayer functioned as a photoanode, which generated a photocurrent due to the oxidation of reactant (i.e., Fell(CN)(6)(4-)) at the PbPc surface. Furthermore, the organo-bilayer also induced a photocatalytic reaction that originated from the oxidising and reducing powers produced at the PbPc and PTCBI, respectively. Based on the photoelectrochemical and photocatalytic studies, it has been noted that the PTCBI/PbPc bilayer can respond to the wide spectrum of solar energy (i.e., 400-1100 nm). However, on using metal free phthalocyanine (H2Pc, p-type) as a reference p-type layer and its application as a photocatalyst material in combination with PTCBI, the generated PTCBI/H2Pc bilayer did not show any photocatalysis particularly under the control irradiation of 700-1200 nm. Thus, the present work demonstrated that the utilisation of a photocatalytic material responding to near-infrared energy is effective towards efficient output into product. (C) 2017 Elsevier B.V. All rights reserved.