Herein, we studied the absorption of H2S and CO2 by alkanolamine protic ionic liquids binary mixtures based on 2-hydroxyethylammonium (MEA) or triethanolammonium cations and residues of 2hydroxy-5-sulfobenzoic acid or pyridine-3-carboxylic acid at various temperatures and partial gases pressures. It was found that absorbents based on the 2-hydroxyethylammonium cation, performed high absorption properties toward the H2S. The solubility of hydrogen sulfide, characterized by the Henry's Law constant, in MEA-based binary mixtures had the values comparable to the commercially available ionic liquids. The results of thermal desorption analysis demonstrated that the capture of acid gases in MEAbased absorbents occurred at two stages: through the dissolution in MEA component and in protic ionic liquid.