Hydrological processes play important roles in soil erosion processes of the hillslopes. This study was conducted to investigate the hydrological processes and the associated erosional responses on the purple soil slope. Based on a comprehensive survey of the Wangjiaqiao watershed in the Three Gorges Reservoir, four typical slope gradients (5 degrees, 10 degrees, 15 degrees and 20 degrees) were applied to five rainfall intensities (0.6, 1.1, 1.61, 2.12 and 2.54 mm . min(-1)). The results showed that both surface and subsurface runoff varied greatly depending on the rainfall intensity and slope gradient. Surface runoff volume was 48.1 to 280.1 times of that for subsurface runoff. The critical slope gradient was about 10 degrees. The sediment yield rate increased with increases in both rainfall intensity and slope gradient, while the effect of rainfall intensity on the sediment yield rate was greater than slope gradient. There was a good linear relationship between sediment yield rate and Reynolds numbers, flow velocity and stream power, while Froude numbers, Darcy-Weisbach and Manning friction coefficients were not good hydraulic indicators of the sediment yield rate of purple soil erosion. Among the three good indicators (Re, v and w), stream power was the best predictor of sediment yield rate (R-2 = 0.884). Finally, based on the power regression relationship between sediment yield rate, runoff rate, slope gradient and rainfall intensity, an erosion model was proposed to predict the purple soil erosion (R-2 = 0.897). The results can help us to understand the relationship between flow hydraulics and sediment generation of slope erosion and offer useful data for the building of erosion model in purple soil.