In this paper, we investigate higher-order rogue wave solutions of the Kundu-Eckhaus equation, which contains quintic nonlinearity and the Raman effect in nonlinear optics. By means of a gauge transformation, the Kundu-Eckhaus equation is converted to an extended nonlinear Schrodinger equation. We derive the Lax pair, the generalized Darboux transformation, and the Nth-order rogue wave solution for the extended nonlinear Schrodinger equation. Then, by using the gauge transformation between the two equations, a concise unified formula of the Nth-order rogue wave solution with several free parameters for the Kundu-Eckhaus equation is obtained. In particular, based on symbolic computation, explicit rogue wave solutions to the Kundu-Eckhaus equation from the first to the third order are presented. Some figures illustrate dynamic structures of the rogue waves from the first to the fourth order. Moreover, through numerical calculations and plots, we show that the quintic and Raman-effect nonlinear terms affect the spatial distributions of the humps in higher-order rogue waves, although the amplitudes and the time of appearance of the humps are unchanged.