Simulated spectrometric observations of unresolved resident space objects are required for the interpretation of quantities measured by optical telescopes. This allows for their characterization as part of regular space surveillance activity. A peer-reviewed spacecraft reflectance model is necessary to help improve the understanding of characterization measurements. With this objective in mind, a novel approach to model spacecraft spectral reflectance as an overall spectral bidirectional reflectance distribution function (sBRDF) is presented. A spacecraft's overall sBRDF is determined using its triangular-faceted computer-aided design (CAD) model and the empirical sBRDF of its homogeneous materials. The CAD model is used to determine the proportional contribution of each homogeneous material to the overall reflectance. Each empirical sBRDF is contained in look-up tables developed from measurements made over a range of illumination and reflection geometries using simple interpolation and extrapolation techniques. A demonstration of the spacecraft reflectance model is provided through simulation of an optical ground truth characterization using the Canadian Advanced Nanospace eXperiment-1 Engineering Model nanosatellite as the subject. Validation of the reflectance model is achieved through a qualitative comparison of simulated and measured quantities. (C) 2016 COSPAR. Published by Elsevier Ltd. All rights reserved.