the United States for such purpose, as of the end of the comparable month of the preceding fiscal year, an additional amount of $20,000,000 shall be made available from the Fund for the purpose of interviewing, processing, transporting, paroling, and releasing alien families, of which not less than $5,000,000 shall be made available for grants to 1 or more nonprofit entities that operate respite centers to assist such alien families with services and compliance with legal requirements. (d) Notification Not later than 14 days after the date on which an amount under subsection (c) is made available, the Secretary shall notify the appropriate committees of Congress of such availability. (e) Limitations Notwithstanding any other provision of law, amounts in the Fund shall not be— (1) reprogrammed or transferred for the purpose of operating or constructing a family residential center