quebec population: 9.1 million (1/4 of the total can population) last election: 2.8 million votes [90 coalition avenir quebec> 21 liberal> 11 solidaire quebec]  though quebec obviously has a history of independence, as other people have mentioned a european union deal for travel and work across the border might work better than an annexation. though the supposedly conservative party has a far majority margin currently, it might be a better idea to prop them up from our end as a independent and non interrupting influence when it comes to ontario and the rest of canada.
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