Reading analog signal from digital pin #6 Is it possible to use digital pin 6 (PD6_PCINT22/AIN0) to read an analog voltage with analogRead()?

According to the ATMega datasheet, this should be possible.

If yes how is it done ? (pin configuration)
That is not possible. AIN0 is an input to the analog comparator, not the analog-to-digital converter. Only ADC0 through ADC8 (connected to the internal temperature sensor), the 1.1V reference, and ground can be connected to the ADC.