Error 400. The request has an invalid header name ESP8266 (HTTP-POST) I'm trying to send a http post to my server from an esp8266-Wifi (I use the ESP8266 library)

I check all my http post format, and I guess is okay... but at the response, the monitor serial answer me like this: 

Requesting POST: HTTP/1.1 400 Bad Request
Content-Type: text/html; charset=us-ascii
Server: Microsoft-HTTPAPI/2.0
Date: Sat, 10 Jun 2017 23:12:48 GMT
Connection: close
Content-Length: 339

&lt;!DOCTYPE HTML PUBLIC "-//W3C//DTD HTML 4.01//EN""http://www.w3.org/TR/html4/strict.dtd"&gt;
&lt;HTML&gt;&lt;HEAD&gt;&lt;TITLE&gt;Bad Request&lt;/TITLE&gt;
&lt;META HTTP-EQUIV="Content-Type" Content="text/html; charset=us-ascii"&gt;&lt;/HEAD&gt;
&lt;BODY&gt;&lt;h2&gt;Bad Request - Invalid Header&lt;/h2&gt;
&lt;hr&gt;&lt;p&gt;HTTP Error 400. The request has an invalid header name.&lt;/p&gt;
&lt;/BODY&gt;&lt;/HTML&gt;

closing connection


and this is my code:

#include &lt;ESP8266WiFi.h&gt;
const char* ssid     = "Putostodosmenosyo";
const char* password = "CetriX.2016%Gdl";

const char* host = "187.201.44.110";

const String Cadenadatos = "info=Micanton|2017-06-09%2012:00|25" ;
//const String Tamano = String(Cadenadatos.length()) ;
const String postiu = "POST /wsCo2Keellingv1002/wsCo2Keelling.asmx/GuardaInfoArduino HTTP/1.1\r\nHost:187.201.44.110:80\r\nContent-Type: application/x-www-form-urlencoded\r\nContent-Length:144\r\n\r\n?info="+String(Cadenadatos)+"\n" ;
const String postam = String(postiu);

void setup() {
  Serial.begin(9600);
  delay(100);

  // We start by connecting to a WiFi network
  Serial.println();
  Serial.println();
  Serial.print("Connecting to ");
  Serial.println(ssid);

  WiFi.begin(ssid, password);

 while (WiFi.status() != WL_CONNECTED) {
    delay(500);
    Serial.print(".");
  }

  Serial.println("");
  Serial.println("WiFi connected");
  Serial.println("IP address: ");
  Serial.println(WiFi.localIP()); 
  delay(2000) ;
}

void loop() {

  WiFiClient client;
  const int httpPort = 80;
  if (!client.connect(host,httpPort)) {
    Serial.println("Conexion fallida");
    return;
  }


 //String data = "pst=temperature&gt;" + String(random(0,100)) +"||humidity&gt;" + String(random(0,100)) + "||data&gt;text";

   Serial.print("Requesting POST: ");
   // Send request to the server:
   //client.println("POST /wsCo2Keellingv1002/wsCo2Keelling.asmx/GuardaInfoArduino HTTP/1.1");
   //client.println();
   //client.println("co2kelling.hopto.org") ;
   client.println("POST /wsCo2Keellingv1002/wsCo2Keelling.asmx/GuardaInfoArduino HTTP/1.1");
   client.println("Host: co2kelling.hopto.org");
   client.println("Content-Type: application/x-www-form-urlencoded");
   client.print("Content-length: ");
   client.print(postiu.length());
   client.println();
   client.print(String(Cadenadatos));
   while(client.connected())
   {
    while(client.available())
    //String line = client.readStringUntil('\r') ;
    Serial.write(client.read()) ;
   }

   /*delay(500); // Can be changed
  if (client.connected()) { 
    client.stop();  // DISCONNECT FROM THE SERVER
  }*/
  Serial.println();
  Serial.println("closing connection");
  delay(5000);
}


NOTE: this is my fixed url
http://187.201.44.110/wsCo2Keellingv1002/wsCo2Keelling.asmx/GuardaInfoArduino?info=Micanton|2017-06-09%2012:00|25

EDIT

This is my Post format:

POST /wsCo2Keellingv1002/wsCo2Keelling.asmx/GuardaInfoArduino HTTP/1.1
Host: localhost
Content-Type: application/x-www-form-urlencoded
Content-Length: length
info=string
You are lacking the required blank line between the headers and the content. Also your content length is wrong.

Change

client.print(postiu.length());


Into

client.println(Cadenadatos.length());