Using SPI without driving MISO I am developing an application where an Arduino Pro Mini communicates with a 12-bit ADC over SPI. The communication is one-way, meaning that the ADC will only send data back to the Arduino, not receive any. The MOSI pin is therefore not required in my application, only SCK and MISO.

I wish to know if there is a way to have the Arduino SPI library ignore the MOSI pin, and controlling the clock pin directly. The ADC requires 16 clock cycles to perform one conversion, sending the data back on the last 12 clock cycles. The way I have implemented it is by using SPI.transfer16() to get 16 clock cycles, and storing the return value in a 16bit variable. The downside to this is that the MOSI pin is driven, and I can therefore not use it for other purposes. I would very much like to be able to generate 16 clock cycles without the need for driving MOSI. Any ideas?
In microcontrollers, the GPIO pins have a multiplexer to select what the pin is used for.  When you use the Arduino SPI library, the initialization function will set the multiplexer to MOSI for that pin.  You should be able to run your own initialization for that pin and overwrite whatever the SPI initialization function did.  Just make sure to call your initialization after SPI.begin().  This is the simplest solution.

If that doesn't work for some reason then you can dig into the source code for the Arduino SPI library.  This isn't too hard either.

Bitbanging is the hardest solution and shouldn't be necessary for your application.