Writing a Discrete Fourier Transform program I would like to write a DFT program using FFT. This is actually used for very large matrix-vector multiplication (10^8 * 10^8), which is simplified to a vector-to-vector convolution, and further reduced to a Discrete Fourier Transform.

May I ask whether DFT is accurate? Because the matrix has all discrete binary elements, and the multiplication process would not tolerate any non-zero error probability in result. However from the things I currently learnt about DFT it seems to be an approximation algorithm?

Also, may I ask roughly how long would the code be? i.e. would this be something I could start from scratch and compose in C++ in perhaps one or two hundred lines? Cause actually this is for a paper...and all I need is that the complexity analyis is $\mathcal{O}(n \log n)$ and the coefficient in front of it doesn't really matter :) So the simplest implementation would be best. (Although I did see some packages like kissfft and FFTW, but they are very lengthy and probably an overkill for my purpose...)
When applied correctly, the DFT yields exactly the same result as convolution, it is no approximation (neglecting rounding errors due to limited precision of floating point calculations, of course).

To calculate the circular convolution of vectors $x$ and $y$ (both of length $N$):
$$
x \circledast y = \operatorname{IDFT}_N\left[\operatorname{DFT}_N[x]\cdot\operatorname{DFT}_N[y]\right]
$$
To calculate the linear convolution first append $N-1$ zeros to both vectors yielding the zero-padded vectors $\tilde x$ and $\tilde y$. Then:
$$
x * y = \operatorname{IDFT}_{2N-1}\left[\operatorname{DFT}_{2N-1}[\tilde x]\cdot\operatorname{DFT}_{2N-1}[\tilde y]\right]
$$

To implement the [I]DFT I highly recommend the FFTW library. I promise that it will take you less time to learn its usage than to write your own implementation. For the special case of $x$ and $y$ containing only $1$ and $0$ their might be a more efficient algorithm, though. You would have to look into the Cooley-Tukey algorithm that is used for the FFT and see if you can simplify it for your needs. Whether it gets simpler will also depend on how you define computational complexity - if you define it in terms of additions and multiplications a custom FFT implementation probably won't buy you much. But if you go down to the hardware implementation level you can save some multipliers in the first butterfly stage by replacing them with multiplexers. Anyway, it is well known that the FFT algorithm complexity is of order $N\log N$ as you say. I would like to think that you don't have to show this again.

If you'd like to play around with IFFT and FFT I recommend Octave (an open source Matlab clone).