Is Triple-DES a group? I know for a fact that DES is not a group, but are any of the Triple-Des versions a group? Why, or why not?
No, they aren't a group.

Justification: We know that the subgroup generated by DES is very large.
If (any of the variants of) 3DES formed a closed group, then the subgroup generated by 3DES would be no larger than $2^{168}$.  We know the latter is not the case.  Therefore, the former is not the case, either.

Also, for the EDE variants of 3DES, it is easy to see that the size of the subgroup generated by 3DES is the same as the size of the subgroup generated by DES (consider what happens with EDE-3DES when you set all three subkeys equal to each other; the result is equivalent to plain DES).