What do you call this old pipe to bath tap join and how do I remove it?
It's called a tap connector (obvious now I've found it), and you should be able to unscrew it. You can see one here

It's the bottom nut you need to be turning. It's part of a joint that attaches the pipe to the tap.

Once you have this off you should be able to remove the tap as normal.

If it's stuck then something like WD40 or penetrating oil might help. Failing that carefully heating the nut with a heat gun might expand the various parts enough to loosen them. Take precautions to avoid getting direct heat onto the bath (it appears to be acrylic).

A more drastic approach would be to take a hacksaw to the thread to separate it that way.