Can my pex line freeze if I use 90 degree elbow connectors?
I doubt you need the second 90 (#3)  - PEX is bendable at large radius, and if you work with that, you avoid fittings that may have freeze damage (PEX itself does not mind freezing.)

If you think of it as if it was rigid pipe, you end up with a lot of fittings. If you work with its strengths, you can avoid many of those fittings, but you don't get tidy pipe-like runs.

I would be concerned with complete drainage ("slightly angled down while running under floor joists" may work for properly hung rigid pipe - pex is not rigid pipe.)