Why would a newly installed radiator only heat when on constant bleed?
I believe that means that the drain pipe of that last radiator is blocked in some way (or simply not or incorrectly connected)

for the connection you'll need to ensure the inlet and outlets are connected to the proper pipes

if it is properly connected then this can be an airlock to fix this close all other radiators and turn on the pump this will increase the pressure before the air bubble and might clear it.

if this doesn't fix it you'll need to check the drain pipes and replace as necessary.