Help determine current usage of my electrical panel and available capacity to add new equipments
Don't get electrical advice from plumbers.  

Quite possibly

When you calculate the burden the loads place on the panel, that is called provisioning. You don't provision every circuit for its breaker trip value, but rather for a lower number that reflects the probability of it being active at the same time as other loads. 

A typically reasonably-electric home with a 100A main can have a 30A air conditioner, a 30A dryer, and a 30A water heater, and even a 40A range with no trouble. 

I see a 30A air conditioner and a 30A ??? that ends with "r". Not water heater, clearly, and 30A is too small for a range, so it must be a dryer. 

The rest of the breakers (even the other 2-pole breaker) look like lighting and receptacle loads. Those provision very lightly, since it's assumed you're not heavily loading them all at the same time.  Also they are 120V loads so they only are half the apparent burden.  

You have to crunch the numbers according to NEC's procedure (here's a worksheet the City of Carmel uses), but I see lots of headroom in this panel, ampwise.  Spacewise is another thing; this is extremely overstuffed (which is trouble if you want to add anything), and every breaker is the wrong kind.   

That panel is OK, the breakers gotta go.

This is a Challenger type C panel.  The panel is perfectly fine. However the breakers are known firestarters just like Zinsco and FPE, except those panels are bad too. Your panel is perfectly fine, but the breakers all need replacing. Fortunately this isn't prohibitive.  

Further, the lower left is a Square D breaker which is an alien breaker - a breaker not made for this panel, and a physical misfit.  The problem is where the clip grabs onto the bus stab - they are mismatched, and make point contact instead of surface contact. They can arc and burn the bus bars. 

The fool may have installed a Square D breaker on the logic that Challenger Type C breakers are unobtanium.  Untrue.  By happy accident, the Eaton BR line is cross-listed Type C (because BRyant bought Challenger and fixed their breakers, then Eaton bought Bryant.)  This is possibly the most common breaker in the US. 



Sold at any hardware store for $5.  $10 for the double-stuff breakers you need. 

For that split 15/20A double-stuff breaker, look for an Eaton BR1520. It's a bit hard to find.  For the GFCI or AFCI or whatever breaker, just get both protections in one breaker, it's not much more money.  Get something like a BRAFGF115CS which is a dual-function AFCI+GFCI breaker for $50.  This has indicator lights to tell you why it tripped, unlike the annoying Square D.

Heat pump

I hear you talking about a heat pump, but presumably that will replace the A/C.  So that is already factored into the system, and you don't need to provision any more power for it than you already have for the A/C.   

Now, heat pumps often have "emergency heat" for when the ambient air is simply too cold for the heat pump to work, and these can pull as much as baseboard electric heat.  However, presuming you are located in metro California, you don't encounter anything below 25F.  It's pretty easy finding heat pumps capable of working that low.   Alternately if you can get by with only 30A of emergency heat, it can share the breaker because it doesn't run at the same time as the heat pump. 

Given that you're in PG&amp;E territory, I strongly recommend you install an "emergency heat" in the form of an Empire style gas furnace - either floor or wall.  These units do not need electricity. So you're not stuck like the poor shlups in the Northeast, having to fetch fuel for a generator simply to get their furnace's electronics and fluid handler to power up.  With an Empire furnace and gas water heat, making your home perfectly livable becomes within easy reach of a homebrew or commercial PowerWall type solution.