Should TempDB SSD Drive be formatted with 64 Kb Allocation Unit Size?
ABSOLUTELY format it 64k.. tempdb will be faster and less taxed than the other san datafiles. Factors can be many, but the main one being heavy tempdb usage.  SQL Server allocates space in multiples of 64k, as does Win Server, by design.
Writing into a properly pre allocated datafile on its own 64k formatted drive is very significant to performance.  64k chunk would go from 16x4k data file reads to tempdb in 1x64k packet write as opposed to 16k packet writes.   4k allocation on the read san drive really isn't a big concern unless there's lots of fragmentation, it's the writing that will be impacted by 4k San.
Thats the mathematical truth. However in theory, a properly raided San even at 4k may not be as noticable because consider the drive head multiples they're writing with.  

Beyond that are architectural modification you can use such as having tempdb use multiple equal data partitions. But that is probably beyond scope.  

That is my short answer, hope I didn't confuse the issue, by being short.