mysqld: Can't create/write to file '/home/mysqltmp/ibXXX' Permission denied
From What to Do if MariaDB Doesn't Start

MariaDB's systemd unit file restricts access to /home, /root, and /run/user by default. This restriction can be removed by setting the ProtectHome option to false for the MariaDB systemd service. For example, you can reconfigure the MariaDB systemd service to allow access to /home by executing the following commands:

tee /etc/systemd/system/mariadb.service.d/dontprotecthome.conf &lt;&lt;EOF
[Service]

ProtectHome=false
EOF
systemctl daemon-reload


ref

After this fix your permission:

chmod go-rw /home/mysqltmp/