How to export all the security-related information from a SQL Server database
I'm sorry you haven't had a response since yesterday; here's at least a starting point for you.

You can try pulling the pieces you need out of.  As always, read the discussion threads (I was, regrettably, unable to find a script endorsed by the big names I recognize, so test thoroughly!  Schema, object, server, and column level permissions are often missing).

I haven't actually used any of these, but they're a set of starting points, in no particular order.

List all permission in all databases

Automated Permissions Auditing With Powershell and T-SQL: Part 1

Permission scripting over all databases

Script DB Level Permissions v2.1

Stored procedure to script out user permissions

Security Queries: Database-level

Security Queries: Server-level