Retrieve Indices of Associative Array as Collection
Is there some operator or function that can give me the indices of the array


No, you have to loop through the associative array:

declare 
       type a_arr_t is table of PLS_INTEGER index by PLS_INTEGER;
       type keys_t is table of PLS_INTEGER;
       a_arr a_arr_t;
       keys_ keys_t := keys_t();
       l_index integer;
begin
      a_arr(1)   := 2;
      a_arr(10)  := 4;
      a_arr(100) := 6;

      l_index := a_arr.first;
      while (l_index is not null)
      loop
          keys_.extend();
          keys_(keys_.count):=l_index;
          dbms_output.put_line(keys_(keys_.count));
          l_index := a_arr.next(l_index);
      end loop;
end;
/

/*
1
10
100
*/