How to get list of dates between From Date and To Date in MySQL
Based on the accepted answer on Stack Overflow here, you can adapt it to fit your requirements:

select * 
from emp_unavailablity, 
(select adddate('1970-01-01',t4.i*10000 + t3.i*1000 + t2.i*100 + t1.i*10 + t0.i) datelist from
 (select 0 i union select 1 union select 2 union select 3 union select 4 union select 5 union select 6 union select 7 union select 8 union select 9) t0,
 (select 0 i union select 1 union select 2 union select 3 union select 4 union select 5 union select 6 union select 7 union select 8 union select 9) t1,
 (select 0 i union select 1 union select 2 union select 3 union select 4 union select 5 union select 6 union select 7 union select 8 union select 9) t2,
 (select 0 i union select 1 union select 2 union select 3 union select 4 union select 5 union select 6 union select 7 union select 8 union select 9) t3,
 (select 0 i union select 1 union select 2 union select 3 union select 4 union select 5 union select 6 union select 7 union select 8 union select 9) t4) as v
where datelist&gt;from_date and datelist &lt;to_date;


Basically we build an inline view with a list of all dates for the next few thousand years, and use that as a list to select from. 

Sample SQL Fiddle here.