All users are having NO Privileges in phpMyAdmin
I have discussed situations like this before in these posts:


May 10, 2013 : In place upgrade from MySQL 5.5 to 5.6.11 removes all users from user table
Sep 22, 2013 : How to create root user after running mysql_install_db?


In your case do this

STEP #1

Add these lines just under the [mysqld] group header in my.ini

[mysqld]
skip-grant-tables
skip-networking


STEP 2

Open Windows Command Line as Administrator, and reboot MySQL Service

C:\&gt; net stop mysql
C:\&gt; net start mysql


STEP 3

You can login to MySQL

C:\&gt; mysql &lt;Hit Enter&gt;


STEP 4

From the mysql prompt, run this

SET @PasswordHash = PASSWORD('whateverpasswordiwant');
REPLACE INTO mysql.user SET
                  Host = 'root',
                  User = 'localhost',
              Password = @PasswordHash,
             Select_priv = 'Y',
             Insert_priv = 'Y',
             Update_priv = 'Y',
             Delete_priv = 'Y',
             Create_priv = 'Y',
               Drop_priv = 'Y',
             Reload_priv = 'Y',
           Shutdown_priv = 'Y',
            Process_priv = 'Y',
               File_priv = 'Y',
              Grant_priv = 'Y',
         References_priv = 'Y',
              Index_priv = 'Y',
              Alter_priv = 'Y',
            Show_db_priv = 'Y',
              Super_priv = 'Y',
   Create_tmp_table_priv = 'Y',
        Lock_tables_priv = 'Y',
            Execute_priv = 'Y',
         Repl_slave_priv = 'Y',
        Repl_client_priv = 'Y',
        Create_view_priv = 'Y',
          Show_view_priv = 'Y',
     Create_routine_priv = 'Y',
      Alter_routine_priv = 'Y',
        Create_user_priv = 'Y',
              Event_priv = 'Y',
            Trigger_priv = 'Y',
  Create_tablespace_priv = 'Y',
                ssl_type = '',
              ssl_cipher = '',
             x509_issuer = '',
            x509_subject = '',
           max_questions = 0,
             max_updates = 0,
         max_connections = 0,
    max_user_connections = 0
;
REPLACE INTO mysql.user SET
                  Host = 'root',
                  User = '127.0.0.1',
              Password = @PasswordHash,
             Select_priv = 'Y',
             Insert_priv = 'Y',
             Update_priv = 'Y',
             Delete_priv = 'Y',
             Create_priv = 'Y',
               Drop_priv = 'Y',
             Reload_priv = 'Y',
           Shutdown_priv = 'Y',
            Process_priv = 'Y',
               File_priv = 'Y',
              Grant_priv = 'Y',
         References_priv = 'Y',
              Index_priv = 'Y',
              Alter_priv = 'Y',
            Show_db_priv = 'Y',
              Super_priv = 'Y',
   Create_tmp_table_priv = 'Y',
        Lock_tables_priv = 'Y',
            Execute_priv = 'Y',
         Repl_slave_priv = 'Y',
        Repl_client_priv = 'Y',
        Create_view_priv = 'Y',
          Show_view_priv = 'Y',
     Create_routine_priv = 'Y',
      Alter_routine_priv = 'Y',
        Create_user_priv = 'Y',
              Event_priv = 'Y',
            Trigger_priv = 'Y',
  Create_tablespace_priv = 'Y',
                ssl_type = '',
              ssl_cipher = '',
             x509_issuer = '',
            x509_subject = '',
           max_questions = 0,
             max_updates = 0,
         max_connections = 0,
    max_user_connections = 0
;
exit


STEP 5

Remove skip-grant-tables and skip-networking from my.ini

STEP 6

Restart MySQL

C:\&gt; net stop mysql
C:\&gt; net start mysql


STEP 7

Try logging into MySQL

GIVE IT A TRY !!!