Can SQL Server system tables be defragmented?
Are you sure you have positively and accurately identified this system table as the sole source of "unnecessary pressure on the buffer pool and also negatively impacts the performance of operations such as computing the size of all tables in a database"? Are you sure this system table isn't self-managed in such a way that (a) fragmentation is minimized or kept in check secretly or just (b) managed efficiently in memory so that defragmentation levels really don't affect anything much?

You can see how many pages are in use, and you can see how much free space is on the pages that are in memory (page_free_space_percent is always NULL in the allocations DMF, but this is available from the buffer DMV) - this should give you some idea if what you're worrying about is really something you should be worrying about:

SELECT 
  Number_of_Pages = COUNT(*), 
  Number_of_Pages_In_Memory = COUNT(b.page_id),
  Avg_Free_Space = AVG(b.free_space_in_bytes/8192.0) 
FROM sys.dm_db_database_page_allocations
(
  DB_ID(),
  OBJECT_ID(N'sys.syscolpars'),
  NULL,NULL,'DETAILED'
) AS p
LEFT OUTER JOIN sys.dm_os_buffer_descriptors AS b
ON b.database_id = DB_ID() 
AND b.page_id = p.allocated_page_page_id 
AND b.file_id = p.allocated_page_file_id;


If your number of pages is small (like probably &lt; 10000 for system tables) or if the free space is "low" (not sure what your typical thresholds are for reorg/rebuild), focus on other, more interesting, low-hanging fruit.

If your number of pages is large and the free space is "high", ok, then maybe I'm giving SQL Server too much credit for its own self-maintenance. As you showed from the other question, this works... 

ALTER INDEX ALL ON sys.syscolpars REORGANIZE;


...and does reduce fragmentation. Though it may require elevated permissions (I did not try as a peon).

Maybe you can just do this periodically as part of your own maintenance, if it makes you feel good and/or you have any evidence that it has any positive impact on your system at all.