Query to report disk space allocation and used space
Here is the query Management Studio uses to populate those numbers:

SELECT
(SELECT SUM(CAST(df.size as float)) FROM sys.database_files AS df 
   WHERE df.type in ( 0, 2, 4 ) ) AS [DbSize],
SUM(a.total_pages) AS [SpaceUsed],
(SELECT SUM(CAST(df.size as float)) FROM sys.database_files AS df 
   WHERE df.type in (1, 3)) AS [LogSize]
FROM
sys.partitions p join sys.allocation_units a 
  on p.partition_id = a.container_id 
left join sys.internal_tables it 
  on p.object_id = it.object_id


You need to perform math here just like Management Studio does in order to get the same numbers. Also, the left join to sys.internal_tables seems superfluous at best. So adjusting that query to match your ideal output:

SELECT
(SELECT CONVERT(DECIMAL(18,2), SUM(CAST(df.size as float))*8/1024.0)
   FROM sys.database_files AS df 
   WHERE df.type in ( 0, 2, 4 ) ) AS [DbSize],
CONVERT(DECIMAL(18,2), SUM(a.total_pages)*8/1024.0) AS [SpaceUsed],
(SELECT CONVERT(DECIMAL(18,2), SUM(CAST(df.size as float))*8/1024.0)
   FROM sys.database_files AS df 
   WHERE df.type in (1, 3)) AS [LogSize]
FROM sys.partitions p join sys.allocation_units a 
  on p.partition_id = a.container_id;


With this update, assuming your database doesn't change in the meantime, it should yield:

753475.94    744030.07    2900.00


Doing some simple math, and isolating just the three numbers you want:

;WITH t(s) AS
(
  SELECT CONVERT(DECIMAL(18,2), SUM(size)*8/1024.0)
   FROM sys.database_files
   WHERE [type] % 2 = 0
), 
d(s) AS
(
  SELECT CONVERT(DECIMAL(18,2), SUM(total_pages)*8/1024.0)
   FROM sys.partitions AS p
   INNER JOIN sys.allocation_units AS a 
   ON p.[partition_id] = a.container_id
)
SELECT 
  Allocated_Space = t.s, 
  Available_Space = t.s - d.s,
  [Available_%] = CONVERT(DECIMAL(5,2), (t.s - d.s)*100.0/t.s)
FROM t CROSS APPLY d;