PostgreSQL for high volume transactions and for Data warehousing
Infrastructure/Database Services

You should probably read this for an overview of a high-volume site that runs on AWS with EBS. They've moved to Ephemeral storage but have had to create some redundancy in being able to (re)store the data.

http://blog.reddit.com/2012/01/january-2012-state-of-servers.html

Data Warehouse/ETL

I've used Pentaho in the past. Not directly with postgres, but I've found it to be a good solution for both OLAP (Mondrian) and ETL (Kettle)

http://www.pentaho.com/

edit: "Community Editions" can be found here

http://mondrian.pentaho.com/

http://kettle.pentaho.com/

Connection

These folks seem to really like pgbouncer. https://stackoverflow.com/questions/1125504/django-persistent-database-connection

I have no experience with it, though. Apparently, Disqus uses it.