Why am I able to create MV logs using PK — even though there is no PK?
A unique constraint on a NOT NULL column (which you have, as I checked this table in a database where Maximo was installed) is a good enough substitute for a primary key in this case.
SQL&gt; create table t1(c1 number, c2 number);

Table created.

SQL&gt; create materialized view log on t1;
create materialized view log on t1
*
ERROR at line 1:
ORA-12014: table 'T1' does not contain a primary key constraint

SQL&gt; alter table t1 add unique(c1);

Table altered.

SQL&gt; create materialized view log on t1;
create materialized view log on t1
*
ERROR at line 1:
ORA-12014: table 'T1' does not contain a primary key constraint

SQL&gt; alter table t1 modify c1 not null;

Table altered.

SQL&gt; create materialized view log on t1;

Materialized view log created.

SQL&gt; select master, primary_key from user_mview_logs;

MASTER                         PRI
------------------------------ ---
T1                             YES