Moving large databases
You can use following steps

On old Server

1.Stop mysql server

2.Copy contents of datadir to another location on disk as ... mysqlbackup

3.Start mysql server again 

4.Compress the data (tar -czvf mysqlbackup.tar.gz mysqlbackup)

5.Copy the compressed file to new server

On New Server

1.Install MySQL [MySQL version should be same as of old server](don't start MySQL server)

2.Unzip compressed file (tar -xzvf mysqlbackup.tar.gz)

3.Move contents of mysqlbackup to the datadir.

4.Make sure that permissions of datadir are correct

5.Make sure your innodb_log_file_size is same on new server, or if it's not, don't copy the old log files (MySQL will generate these)

6.Start MySQL.

You can also look at How can I move a database from one server to another?