MySQL: selecting arbitrarily ordered rows after a specific id
If you are fine about using variables and double sorting:

SELECT
  id,
  value
FROM (
  SELECT
    id,
    value,
    @check AS chk,
    @check := IF(id = 5, 1, @check)
  FROM t, (SELECT @check := 0) x
  ORDER BY
    value DESC,
    id DESC
) s
WHERE
  chk = 1
ORDER BY
  value DESC,
  id DESC
LIMIT 2
;


Here's a SQL Fiddle for it.