How can I monitor the call count per stored procedure per timespan?
You can get this (and more) from Dynamic Management Views (DMVs). To get statistics for a particular stored procedure, try the following query.

SELECT
    OBJECT_NAME(qt.objectid)
  , qs.execution_count AS [Execution Count]
  , qs.execution_count / DATEDIFF(Second, qs.creation_time, GETDATE()) AS [Calls/Second]
  , qs.total_worker_time / qs.execution_count AS [AvgWorkerTime]
  , qs.total_worker_time AS [TotalWorkerTime]
  , qs.total_elapsed_time / qs.execution_count AS [AvgElapsedTime]
  , qs.max_logical_reads
  , qs.max_logical_writes
  , qs.total_physical_reads
  , DATEDIFF(Minute, qs.creation_time, GETDATE()) AS [Age in Cache]
FROM
    sys.dm_exec_query_stats AS qs
CROSS APPLY 
    sys.dm_exec_sql_text(qs.[sql_handle]) AS qt
WHERE
    qt.[dbid] = DB_ID()
AND qt.objectid = OBJECT_ID('StoredProcedureName')
OPTION (RECOMPILE);


To look at the most frequently executed procedures:

SELECT
    OBJECT_NAME(qt.objectid)
  , qs.execution_count AS [Execution Count]
  , qs.execution_count / DATEDIFF(Second, qs.creation_time, GETDATE()) AS [Calls/Second]
  , qs.total_worker_time / qs.execution_count AS [AvgWorkerTime]
  , qs.total_worker_time AS [TotalWorkerTime]
  , qs.total_elapsed_time / qs.execution_count AS [AvgElapsedTime]
  , qs.max_logical_reads
  , qs.max_logical_writes
  , qs.total_physical_reads
  , DATEDIFF(Minute, qs.creation_time, GETDATE()) AS [Age in Cache]
FROM
    sys.dm_exec_query_stats AS qs
CROSS APPLY 
    sys.dm_exec_sql_text(qs.[sql_handle]) AS qt
WHERE
    qt.[dbid] = DB_ID()
ORDER BY
    qs.execution_count DESC
OPTION (RECOMPILE);


The values reported are cumulative since the last restart. If you want to measure over a fixed period, use the command below to reset wait stats.

DBCC SQLPERF("sys.dm_os_wait_stats",CLEAR);


If you wanted to measure fixed timespans across the day, you could feed the query output to a table via an agent job and either a) calculate the values between two runs or b) issue the wait stats reset as the last step in the agent job.

Alternatively, capture a profiler trace and run it through Clear Trace.