Materialized views Performance
The data of a MV is stored in a regular table, there is no magic to that. But access is typically (much) faster for multiple possible reasons:


multiple tables joined already
smaller row size with only relevant columns for common queries
pre-computed values
pre-selected rows, possibly in expensive ways
possibly much less bloat (fewer dead tuples)
multiple of the above items result in potentially much smaller table size as compared to underlying tables
rows physically sorted favorably (clustered), so that queries only have to read few data pages
size of indexes can be much smaller accordingly
some kinds of indexes only become possibly this way, like a multicolumn index on columns from multiple underlying tables


In short: most expensive work of sophisticated queries on underlying tables is already done, which allows potentially much faster access.