index not being used
The usual rule of thumb for MySQL Query Optimizer is this:

If the EXPLAIN plan has to read more than 5% of the table rows via the index, the index is dismissed (ruled out) and a full table scan is performed.

In the case of the Slave, 156769 out of 32212292 rows are to be read. That's 0.4867%. Hence, the index is used.

With regard to the Master, it is very disturbing that the MySQL Query Optimizer ruled out indexes. As @ypercube commented, perhaps there is no index.

You should make sure by running SHOW CREATE TABLE ox_data_summary_ad_hourly\G on both Master and Slave. If they are different, please post both outputs in the question.

Also, please run SELECT COUNT(1) FROM ox_data_summary_ad_hourly; on both Master and Slave and post these counts