The number of triangulations of a set of $n$ planar points: Why so difficult?
Here's one more "applied" reason why we care about triangulations. There's a body of work on mesh compression where the goal is to use as few bits per vertex as possible to encode a mesh (mainly to aid in storage and transmission). The particular base of the exponent in the number of triangulations of a planar point set provides an information-theoretic lower bound on the number of bits needed per vertex (specifically, $8.48^n$ triangulations means you need at least 8.48 bits per vertex). Such bounds can then be compared with actual mesh compression schemes to determine their efficacy.