For which graph classes the fractional chromatic index rounded up equals the chromatic index?
It is known that for any multigraph $G$ on at most 8 vertices, $\chi'(G)$ is the maximum of the maximum degree and the ceiling of the odd-sets bound, see http://dx.doi.org/10.1016/S0012-365X(96)00364-0 (so what you find with sage is not very surprising).

This recent arXiv manuscript gives some more references for your problem (top of page 3)
http://arxiv.org/pdf/1406.0757v1.pdf

Beside bipartite graphs, non-trivial classes with the property you're looking for include series-parallel graphs.