Graph that maximizes minimum hitting time?
It is well known that a barbell graph (two cliques of size $n/3$ connected by a path of length $n/3$) has average hitting time $\Omega(n^3)$, but I believe the same applies to minimum hitting time (for uniform or stationary distribution). Whatever vertex you choose as the one that you think is easiest to hit, you have constant probability of starting in the far clique from that vertex, after which it will take $\Omega(n^3)$ time in expectation before you traverse the connecting path to your chosen vertex.