Properties expressible in 2-CNF or 2-SAT
A family of bitvectors is the class of solutions to a 2-SAT problem if and only if it has the median property: if you apply the bitwise majority function to any three solutions you get another solution. See e.g. https://en.wikipedia.org/wiki/Median_graph#2-satisfiability and its references. So if you can find three solutions for which this is not true, then you know it cannot be expressed in 2-CNF.