The polynomial languages and ordered syntactic monoids
The relation $pu^{k+1}q\in L\Rightarrow pu^k vu^kq\in L$ is true for any $p,q$, $k$ big enough and $v$ with $alph(v)\subseteq alph(u)$.

Let call $a$ the first letter of $u$ and $b$ the last letter.
Let $v$ with $alph(v)\subseteq alph(u)$, and $v'=uvu$.

Then by using the relation above with $v'$, we get that for any $p,q$ and $k$ big enough, we have $pu^{k}q\in L\Rightarrow pu^k vu^kq\in L$, which is the definition of $u^kvu^k\leq_L u^k$. In particular, for $n$ big enough, we get $u^{n!}vu^{n!}\leq_L u^{n!}$, which is the wanted equation.