Monotone-2SAT and Vertex Cover
The name “#Monotone-2SAT” usually refers to the problem of counting the satisfying assignments of a given monotone 2CNF formula, without a restriction on the number of variables set to true.  The stated “Monotone 2SAT” problem, or the Vertex Cover problem as is usually called, is not the decision version of #Monotone-2SAT because of the additional restriction on the number of variables set to true.  (This is certainly unfortunate.)  Therefore, Vertex Cover (or “Monotone 2SAT”) is not reducible to #Monotone-2SAT in the same way as 3SAT is reducible to #3SAT.

Note that Vertex Cover is clearly in NP and that #Monotone-2SAT is known to be #P-complete (see my answer to your previous question for the reference) and hence NP-hard.  Therefore, Vertex Cover is reducible to #Monotone-2SAT.  (Note that this does not require the fact that Vertex Cover is NP-complete.)  To construct an actual reduction, you can simply composing several reductions as always.  There may be a simpler reduction than this, but I do not expect that seeking for a simpler reduction gives much insight into either problem.