Can we prove using pumping lemma that language F = {$a^ i b ^j c ^k$ | i, j, k ≥ 0 and if i = 1 then j = k} is not regular?
For that I take:
  
  x:a ; y:b ; z:c


You can't do that. You have to first give a pumping length $p$ and then you have to show that there is no decomposition of the word $abc$ into $xyz$ with $|y|\ge 1$ and $|xy| \le p$ for which $xy^n z \in F$. If we take your word $abc$ and decompose as $x=\varepsilon$, $y = a$, $z=bc$ then the pumped words are $a^nbc$ and are all in $F$.