Linear programming formulation for the single-source shortest path problem
Any optimal solution to the problem must satisfy
$$
d_v = \min_{u\colon (u,v) \in E} (d_u + \ell_{uv}),
$$
as well as $d_s = 0$, of course. Assuming the graph is connected, you can prove by induction on the length (number of edges) of a shortest path from $s$ to $v$ that $d_v$ is at most the distance from $s$ to $v$, which we denote by $d^*_v$. In particular, the optimal value is at most $\sum_v d^*_v$.

On the other hand, it is not hard to check that $d_v = d^*_v$ (for all $v$) itself is a feasible solution, showing that the optimal value is exactly $\sum_v d^*_v$, and it is achieved only when $d_v = d^*_v$ for all $v$.