Which complexity classes are $\mathsf{RE}$?
Time-bounded classes can be enumerated. Suppose we want to enumerate all languages in P. Every language in P is accepted by some Turing machine $T$ running in time $f(n)$ for some polynomial $f$. We can construct a Turing machine $T'$ that emulates $T$ but also keeps track of the time, and stops after $f(n)$ steps. Every Turing machine of the form $T'$ accepts a language in P, and vice versa, for every language in P, we can construct such a machine $T'$. The machines $T'$ themselves can be enumerated by enumerating the simulated machines $T$ and the "timers" $f(n)$.

For a space-bounded class, you do something similar, keeping track of the space usage of the Turing machine. You also need to prevent infinite loops somehow, either using a timer or by keeping track of all positions encountered so far during the simulation.

Non-deterministic and randomized versions can also be handled this way, so for example, PH can be enumerated.