Do all Regular Expressions describe Regular Languages?
It's a standard part of any automata theory course that regular expressions, deterministic finite automata and nondeterministic automata all define the same class of languages. Any individual exposition will take one of those three things as defining the class of regular languages.

So, yes, all regular expressions define regular languages, and every regular language is the set of strings that match some regular expression.

At least, the above is true for regular expressions as used in computer science. Perhaps the confusion in the question arises from the fact that many computer systems such as text editors, programming languages/libraries and command shells have pattern-matching features that they call "regular expressions" but which are more powerful than CS regular expressions. @reinierpost provides the example that egrep '^(.*)\1 matches the non-regular language $\{ww\mid w\in\Sigma^*\}$.