Decidable non-context-sensitive languages
CSL is the same as $\mathsf{NSpace}(n)$ (non-deterministic linear space). Any language which is outside $\mathsf{NSpace}(n)$ is not CSL.

To get a feeling of the situation, remember that $SAT \in \mathsf{NSpace}(n)$ and even TQBF.


  What others problems exists that are decidable but yet non-context-sensitive? 


The are many problems. Any problem that is complete for a complexity class larger than $\mathsf{PSpace}$ will do (we need $\mathsf{PSpace}$ because problems like TQBF in $\mathsf{NSpace}(n)$ that are complete for $\mathsf{PSpace}$ because a (polynomial time) reduction can blow up the size of an input by a polynomial). Giving an example will mean proving a lowerbound for the complexity class containing the problem and that is very very difficult task. The only major way we know so far to do this is diagonalization which intuitively means that the larger class should be able to simulate the smaller class.

So $\mathsf{ExpSpace\text{-}hard}$ seems a natural place to start to look for natural examples of language which are not CSL.


  Is this class of problems the same as decidable EXPSPACE-hard?


No. By the space hierarchy theorem, there are languages which are in $\mathsf{NSpace}(n^2)$ which are not in $\mathsf{NSpace}(n)$. If you are asking for nice examples, that is going to be difficult because the theorem works using diagonalization and therefore the language it proves to satisfy these conditions is very artificial.

I suggest that you ask a separate question for a natural problem that separates $\mathsf{NSpace}(n^2)$ from $\mathsf{NSpace}(n)$.