Is it possible that the union of two undecidable languages is decidable?
Take $L_1=\{0\cdot x:x\in \Sigma^*\}\cup \{1\cdot x: x\in A_{TM}\}$ and $L_2=\{1\cdot x:x\in \Sigma^*\}\cup \{0\cdot x: x\in A_{TM}\}$. Clearly both languages are in $RE\setminus R$.

However, their union contains $\{0\cdot x\}\cup \{1\cdot x\}=\Sigma^*\setminus\{\epsilon\}$, so their union is $\Sigma^*$, and is therefore decidable.