How to write Context Free Grammar with numerical restrictions
First off, your grammar isn't quite right, since there's no way to eliminate $S$; every production with $S$ on the LHS produces a string including $S$, so your grammar generates no (finite) strings at all.

To capture the "greater than or equal to 1" requirement, you should have a rule that produces the smallest permissible string; to handle the $m$ case, this would mean you need a production yielding $00011$. To handle the $n$ case, on the other hand, you'd need a production yielding $01$. Together, this implies that $0001101$ is the smallest string in your language. With the base cases out of the way, you can add other productions to build on this base case.

For your case, you have have a context-free language which is the concatenation of two other context-free languages. If you can make a grammar for the two constituent languages, it's easy to make a grammar for your language:

$$S \rightarrow S_1S_2$$

Grammars for the other are easy, too, and you had the right idea:

$$S_1 \rightarrow 00011 \mid 000S_111$$

and

$$S_2 \rightarrow 01 \mid 0S_21$$