Confusion about the Time Hierarchy Theorem and relativization
It is not true that for $A$ being $\sf EXP$-complete ${\sf DTIME}^A(n^k) = {\sf EXP}$, but you are right with ${\sf P}^A={\sf EXP}$.

Here is the reason for this. In order to make use of the oracle you have to transform your problem via a reduction. This reduction is a polynomial reduction. The running time of this particular reduction might need $\omega(n^k)$ steps. In this case you cannot use the oracle in the desired way.

As you already observed ${\sf DTIME}^A(n^k) \neq {\sf EXP}$ because this would imply  for all $k,j$ that ${\sf DTIME}^A(n^k)={\sf DTIME}^A(n^j)$, which cannot be true since the time hierarchy theorem relativizes.