How can I show that the Cook-Levin theorem does not relativize?
Please refer Does Cook Levin Theorem relativize?. 

Also refer to Arora, Implagiazo and Vazirani's paper: Relativizing versus Nonrelativizing Techniques: The Role of local checkability.

In the paper by Baker, Gill and Solovay (BGS) on Relativizations of the P =? N P
question (SIAM Journal on Computing, 4(4):431–442, December 1975) they give a language $B$ and $U_B$ such that $U_B \in NP^B$ and $U_B \not\in P^B$, thus proving that there are oracles $B$ for which $P^B \neq NP^B$.

We shall modify the $U_B$ and $B$ to $U_{B'}$ and $B'$ such that we get a new language that cannot be reduced to 3SAT even if there is availability of $B'$ as an oracle.

First assume that we can pad every $3SAT$ boolean instance $\phi$ to $\phi'$ with some additional dummy 3CNF expressions such that $|\phi'|$ is odd and they are equivalent, i.e., $\phi$ is satisfiable iff $\phi'$ is satisfiable. We can do it in $n+O(1)$ time and with $O(1)$ padding, but even if it takes polynomial time and extra polynomial padding it does not matter.

Now we need to combine the $B$ and $3SAT$ to $B'$ somehow so that BGS theorem still holds but additionally $3SAT \in P^{B'}$. So we do something like the following.

$U_{B'} = \{1^n \ \ |\ \ \exists x \in B, $ such that $|x| = 1^{2n}\}$ and

$B' = B'_{constructed} \ \cup \{\phi \ \ |\ \ \phi \in 3SAT $ and $ |\phi| $ is odd $\}$. 

Now we shall construct $B'_{constructed}$ according to the theorem such that if the deterministic machine $M_i^{B'}$ for input $1^n$ ($n$ is determined as in theorem) asks the oracle $B'$ a query of odd length we check if it is in $3SAT$ and answer correctly but if it asks a query of even length we proceed according to the construction, that is, answering correctly if it is already in the table, otherwise answer no every time. Then since we are running for $1^n$ we flip the answers at $2n$ length so that $M_i^{B'}$ does not decide $U_{B'}$.

We can prove similarly as in the BGS theorem that for this $B'$ and $U_{B'}$ too, we have $U_{B'} \in NP^{B'}$ and $U_{B'} \not\in P^{B'}$. 

$U_{B'} \in NP^{B'}$ is easy to prove. We construct a non-deterministic Turing Machine which for input $1^n$ creates non-deterministic branches that runs for $2n$ steps to generate a different $2n$-length string and then asks oracle $B'$ if the $2n$-length string is in $B'$, and if the answer is yes it accepts $1^n$ else it  rejects $1^n$. This construction shows that $U_{B'} \in NP^{B'}$.

$U_{B'} \not\in P^{B'}$ can be proved with the help of diagonalization argument. Basically it is different from every $L(M_i^{B'})$ for every oracle Turing Machine that have $B'$ as an oracle. This is because of how we construct $B'_{constructed}$.

Now we shall prove by contradiction that there does not exist a reduction from $U_{B'}$ to $3SAT$ even with the availability of oracle $B'$.

Assume there is a reduction using oracle $B'$, i.e., $U_{B'} \leq^{B'}_P 3SAT$. 

That means we can reduce a string of the form $1^n$ to a 3SAT instance $\phi$ using a polynomial-time deterministic machine which uses $B'$ as oracle. 

We can now describe a deterministic TM $M^{B'}$ which will decide strings $U_{B'}$ in polynomial time using $B'$ as an oracle. First this machine reduces the input $1^n$ to a 3SAT-instance $\phi$ using $B'$ as an oracle. This can be done because we have the reduction above. Then if $\phi$ is not odd length $M^{B'}$ will pad it to make $\phi'$ which is odd length. Next, it will give this $\phi'$ to oracle $B'$ and get the answer yes/no. It will accept if the answer is yes and reject if the answer is no. 

This machine is deterministically polynomial and uses oracle $B'$.

Thus we have proved that $U_{B'} \in P^{B'}$, a contradiction.

Therefore $U_{B'} \not\leq^{B'}_P 3SAT$.