Time complexity of Ackermann's Function
You are asking (or at least typing) multiple questions that are unrelated.

Time Complexity of the Ackermann function

First, understand that this is not a meaningful query. The Ackermann function, let's call it $A$ (assume a one-parameter variant), is a function, not an algorithm. You can certainly talk about $\Theta(A)$.

What you likely mean is the time $T_A(n)$ required to compute $A(n)$. I do not know of any algorithm besides explicitly computing the recurrence; the runtime of this approach can be investigated using the standard approach. It's unlikely that the result will be a meaningful $\Theta$-asymptotic in terms of the "usual" basic functions; you'd get runtime bounds expressed in $A$ itself.

That does not mean that there is no faster algorithm; it would not contradict the growth of $A(n)$ per se. Depending on your computational and cost model, you can compute huge numbers with little cost.

Are all primitive-recursive functions in $O(A)$?

Yes. That is (a consequence of) how we show that $A$ is not primitive recursive.

Note that here we are back to comparing values of the functions again; no mention of "time complexity" is being made.

Can all primitive-recursive functions be computed in time $O(T_A(n))$?

Not knowing $\Theta(T_A)$, I do not have an answer to this question.