Are picture files "random enough" to be usable as a one-time pad?
No.  This is not safe.  The one-time pad requires that the pad be generated by a true-random process, where each bit of the pad is chosen uniformly at random (0 or 1 with equal probability), independent of all other bits.

Any deviation from that, and what you haven't is no longer the one-time pad cryptosystem -- it is some kludgy thing.  In particular, once you deviate from that requirement even a little bit (and you're talking about a huge deviation), you are skating on thin ice and there will probably be security problems with your scheme.

If you're gonna use the one-time pad, you gotta use it exactly as it is defined, with a truly-random pad.  There are no shortcuts, no halfway stuff.  Messing around with this sort of thing is exactly what enabled the US to cryptanalyze Soviet use of a "one-time pad" in the VENONA project.

But in practice, you probably don't want to use the one-time pad anyway.  The key management issues are enough that it is rarely a good choice in practice.