BigInteger in Java and Randomness
Presuming this documentation is correct, the answer is no, these numbers are not cryptographically secure. The Random class uses a linear congruential formula with a 48 bit seed. For most purposes it is not enough even if you only require 48 bit security. Given a fairly low number of outputs from a LCG, it is possible to derive the seed, even if only a few bits of each seed iteration are used. That question has been answered here.