PKPA to Supercede TLS/AES etc?
Sounds like snake oil for me.
The phrase you cite can be easily googled and tracked back to a white paper by CipherLoc in which they suggest that AES can be broken by using frequency analysis of english text when reusing the same encryption key for many inputs. In their explanation they deliberately ignore the role of a random IV with AES which should make such attacks infeasible. And their "solution" against this is this "PKPA" thing which somehow scrambles the data before encryption to make such frequency analysis impossible. Apart from that this is not intended to replace AES but instead used additionally to it.