Issues connecting a Bitcoin-Qt Wallet to a local node
It might be you need to add some lines in the bitcoin.conf file on the Raspberry Pi.  This was taken from the github repo example of the bitcoin.conf file

##############################################################
##            Quick Primer on addnode vs connect            ##
##  Let's say for instance you use addnode=4.2.2.4          ##
##  addnode will connect you to and tell you about the      ##
##    nodes connected to 4.2.2.4.  In addition it will tell ##
##    the other nodes connected to it that you exist so     ##
##    they can connect to you.                              ##
##  connect will not do the above when you 'connect' to it. ##
##    It will *only* connect you to 4.2.2.4 and no one else.##
##                                                          ##
##  So if you're behind a firewall, or have other problems  ##
##  finding nodes, add some using 'addnode'.                ##
##                                                          ##
##  If you want to stay private, use 'connect' to only      ##
##  connect to "trusted" nodes.                             ##
##                                                          ##
##  If you run multiple nodes on a LAN, there's no need for ##
##  all of them to open lots of connections.  Instead       ##
##  'connect' them all to one node that is port forwarded   ##
##  and has lots of connections.                            ##
##       Thanks goes to [Noodle] on Freenode.               ##
##############################################################

# Use as many addnode= settings as you like to connect to specific peers
#addnode=69.164.218.197
#addnode=10.0.0.2:8333

# Alternatively use as many connect= settings as you like to connect ONLY to specific peers
#connect=69.164.218.197
#connect=10.0.0.1:8333

# Listening mode, enabled by default except when 'connect' is being used
#listen=1

# Maximum number of inbound+outbound connections.
#maxconnections=

#
# JSON-RPC options (for controlling a running Bitcoin/bitcoind process)
#

# server=1 tells Bitcoin-Qt and bitcoind to accept JSON-RPC commands
#server=0