Can pheromones in perfume be formulated to cause agitation?
Insects generate and respond to pheromones. But despite what sci-fi TV might have told you, there is no evidence that humans make or respond to pheromones like that.  Humans don't have that good sense of smell, for one thing.

The fact that you know it's a Playboy brand of perfume is affecting you?  That's obviously not chemical, is psychological.

Also, historically, perfume was used just as much to mask unpleasant odors as it was to attract anyone.  When men go through puberty, their sweat changes odor.  That's not to attract other men.

If this perfume is affecting you emotionally it's psychological, not chemical.