Photolysis of Water?
Water is split in chloroplasts in the light reaction of photosynthesis. Chlorophyll, acting as a photopigment, captures sunlight and transfers that energy to an electron pair of a water molecule. Under the influence of a water-splitting enzyme (George et al, 1989) it is separated into 2 protons, molecular oxygen and a free electron pair.

Reference
George et al. Science 1989; 243(4892): 789-91