What causes skewed ladder bands on an agarose gel?
If the ladder is on an edge of the gel, it may be a process of different density as a result of how the gel cooled (or was poured too slowly). I've loaded more DNA loaded in a gel and it doesn't cause this kind of warping for me. It may be the buffer of the ladder is different from that used to make the gel. Your bands don't look particularly sharp, so I would suspect that the running voltage is too high and causing the surface of the gel to heat up and therefore "smearing" the bands. Try running the voltage at 75 V  for a proportionately longer time to see if this solves your problem.