What is an "Alternative Sensation"?
"Alternative sensation" is not specific terminology in neuroscience - it is just the noun "sensation" with a descriptive adjective "alternative." It just means that it is referring to a different sensation than whatever the "primary" one is.

Knowing what this term means in a given context depends entirely on that context, and may not have any relationship to other contexts.

Time-frequency refers to how something varies in time and frequency. In the context of stimuli, for example, an auditory stimulus can have different "tones" or "notes": those are different sound frequencies, and those frequencies can happen in sequence. To describe a sound visually, one will often present a 'heat map' showing when (time) and at what frequency that sound has energy. Touch stimuli can also have a time-frequency representation, where the frequency indicates the vibration speed of the touch.