what is probability density function (PDF) of periodic signal
There is no best pdf for a periodic signal. There is also no way to find the 'exact' pdf of a measured signal. What you have to do is to measure the pdf from the data. Use a histogram to approximate the pdf of your data. Define a number of intervals within the amplitude range of your signal and simply count the numbers of data samples per interval. This gives you the histogram which is an approximation of the pdf of your signal.