Biographical Sketches in NSF Postdoc application
I would follow the specific directions.  

Trace the links back and you get to a full description of what they want.  It's on pages II-14 and II-15 of this document:  https://www.nsf.gov/pubs/policydocs/pappg19_1/nsf19_1.pdf

Give them exactly what is asked for, in order, and matching the directions.  

No, not your CV.