Letter of Recommendation Reminder (deadline tomorrow)
With a deadline of tomorrow I'd say it's too late to email him. Phone him instead. Try to pick a convenient time (accounting for timezone differences). If you can't reach him, call the department office and leave a message.

If he's already committed to writing a LOR for you, it's unlikely he's backing out now. Yes, he might have underestimated the amount of work he has left or procrastinated a little too much (don't we all), but he'll be well aware that you've put your faith in him to write, and if he refuses to write one now you'll almost surely miss the deadline (and by extension fail to get admitted). It's only responsible for him to finish the letter then.