Force hibernate (deep sleep) in OSX 10.8(.2)
I don't know if it's equivalent to the deep sleep mode, but sudo pmset -a hibernatemode 25 makes computers hibernate immediately when going to sleep.


  hibernatemode = 3 (binary 0011) by default on supported portables. The system will store a copy of memory to persistent storage (the disk), and will power memory during sleep. The system will wake from memory, unless a power loss forces it to restore from disk image.
  
  hibernatemode = 25 (binary 0001 1001) is only settable via pmset. The system will store a copy of memory to persistent storage (the disk), and will remove power to memory. The system will restore from disk image. If you want "hibernation" - slower sleeps, slower wakes, and better battery life, you should use this setting.