Is there a way to have two keyboard shortcuts for the same function?
The Shortcuts Prefs won't allow you to add the same Menu item twice, so no, this cannot be done.
Additionally, in Finder, the Copy menu item is a 'smart' structure, meaning it always contains the name or count of what would be copied by the key command. You cannot use the shortcut replacer at all on a smart menu.
Examples…

Furthermore, attempting to override a system-wide command like Copy is bound to fail somewhere. It's definitely best to stick to the system defaults for such as those.