Complementary Transistor Pair
Paired complementary transistors may be in separate packages (old solution), or in combined (e.g. 6 pin) package.
Matching of NPN and PNP transistors may privilege only a few parameters. They may be switching times, capacitance, gain, etc. Depending on your design some are more relevant than others.

There are several choices.

BC846BPDW1, ON Semi, SOT-363, VCEmax=65V, ICcont=100mA

CPH5524-D, ON Semi, SC-74, VCEmax=50V (100V for VCBO of NPN), but ICcont=3A

PBSS4112PANP, NXP Semiconductors, has maybe a difficult package (DFN2020-6), but VCEmax=120V, ICcont=1A

PBSS4160DS, NXP Semiconductors, SC-74, lower VCmax (60V), ICcont=1A. Both NXP can be used for low VCEsat applications.

SMBTA06UPN, Infineon, VCEmax=80V, ICcont=500mA

So , you see that low and medium collector currents can be accommodated for, and voltages up to 100V.
To my memory the maximum VCE voltage for matched pairs is around 150-200V.

A power transistor with large VCEmax (200V), ICcont=10A, that is sold as separate TO-3P for NPN and PNP is FJA4313 and FJA4210.