What's the use of a decoupling capacitor near a reservoir capacitor?
The most likely reason why that is done is because, in real life, capacitors do not have infinite bandwidth. Generally, the higher the capacitance of the capacitor, the less it will be able to react to high frequencies, while small-valued capacitors react better to higher frequencies, as seen in the graph below. Using two different-valued capacitors together is just done to improve the response of the filtering.