Connecting to WiFi at boot on an Orange Pi Zero
sudo nano /etc/network/interfaces #Add at end of file

 auto wlan0
 iface wlan0 inet dhcp
 wpa-ssid &lt;Your Access Point Name aka SSID&gt;
 wpa-psk &lt;Your WPA Password&gt;


Wifi connects on boot now,

Credit: https://lucsmall.com/2017/01/19/beginners-guide-to-the-orange-pi-zero/