Voltage divisor with op amp
The exact equation would also include the bias current of the non-inverting input of the op-amp, which should be negligible in most cases (by design, you want to keep the resistor values low enough that the bias current is not significant, because the bias current is not known accurately and is not stable with temperature. 

However, other than possible erroneous measurements or wiring, wrong parts, or a defective op-amp, there are a couple other possibilities (and with more information, supplied by you, it would not be necessary to guess), but for completeness.. 


If the divider voltage is outside the supply range then it's possible the input current will be much larger than the stated operational bias current. For example, if the negative rail is 0V, Vs is -10V and 2Rb = 10K then the voltage measured at the non-inverting input will likely be more like -0.7V because the internal protection diodes or isolation diodes will conduct. 
If the circuit is such that the op-amp cannot balance, then some op-amps will pass current between inputs if the voltage differential exceeds a diode drop. There are effectively back-to-back (inverse-parallel) diodes across the inputs. There are usually current-limiting resistors in series with the inputs but the current can be quite significant. This is common in op-amps with super-\$\beta\$ bipolar transistor front ends, since breaking down the base-emitter junction of the transistors can degrade the transistors. 


OPA202 internal circuit showing the diodes as mentioned above: