Decoupling of STM32F072CBT6
For three VDD (VDDIO1) pins: A 100n ceramic capacitor to each, plus a 4u7 ceramic to only one of them is sufficient.
For VDDIO2 pin: a 100n plus a 4u7 ceramic is sufficient.
For VDDA pin: a 10n plus a 1u ceramic is sufficient.

Do I need both (100nF AND 4.7uF) connected each of the Supply?

So yes, each supply rail requires its own 1u/4u7 ceramic capacitor.