Transistor: Getting “incorrect” graph for input voltage to output voltage
Below is a simplified diagram of the PNP BJT in active mode, with the relative thicknesses exaggerated in order to make it more readable. This image is taken from Jacob Millman's &quot;Microelectronics: Digital and Analog Circuits and Systems&quot; circa 1979 I think:

The middle N layer is actually a lot thinner and it is also the more highly doped of the three layers, as well. In active mode, the base-collector (middle and right regions) are reverse-biased and the base-emitter (middle and left regions) are forward-biased.
As a forward-biased charge-carrying current, \$I_{pE}\$, transitions from the left to the middle region, drawn into the middle region by the forward-biased state of affairs of barrier \$J_E\$, only a small part of it is collected by the base lead. These charges are moving through a very, very thin layer and most of them readily find themselves crossing the junction barrier, \$J_C\$, which despite being reverse-biased, more lightly doped, and a much larger region, is even still more negatively charged than the base they passed through. So they are now simply accelerated towards the collector.
If you try and imagine putting two diodes together, appropriately for demonstration purposes, I think you can see that the thin N layer of the PNP BJT has now been replaced by rather thicker N layers in each diode as well as the bonding points and a length of wire.
The whole idea of the BJT's mechanism of active-mode operation has been completely undone when you try to mimic a BJT by &quot;gluing&quot; two PN diodes together.
Schottky Barrier Diode
The Schottky barrier diode is a unipolar (uses only an N type semiconductor material but no P type) diode where a metal contact point is applied. Despite the lack of a PN junction, it still functions as a diode, but with a lower forward voltage requirement. But any thoughts of trying use a pair of these to make a BJT should be still more obviously flawed!
There's a funny story I read, many years ago, that's tertiarily related to the idea of making Schottky barrier diodes. It's preserved here and worth a moment's reading. The story may help you well imagine some of the difficulties facing early attempts to make point-contact Schottky diodes.
The modern Schottky barrier diode avoids much of the &quot;fun&quot; illustrated in that story by often (not always) using metalized silicides, which bond more easily than what unfolds in the above story.