Measuring negative pressure with a raspberry pi and I2C Pressure Sensor
The real question is,  the pressure range in the sensor's datasheet is absolute or relative pressure. As I see,  it is absolute. 
The relative scale is what we use mostly,  the 0 is the pressure measured at sea level. It is 1ATM (~1bar) on the absolute scale,  where 0 is full vacuum without any particles. The answer is yes,  you can measure vacuum with that sensor.