Surge protection for SMPS
You really asked two independent questions: Can a series NTC thermistor followed by parallel MOV help with inrush, and can it help with spikes?

Yes, it can help with inrush.  The series resistance starts out high due to the thermistor being cold.  Presumably, things are sized so that the thermistor is a bit warm during normal operation, meaning it presents less series resistance.  This means the device as a whole will draw less current initially until the thermistor warms up.  That will decrease initial inrush since that ocurrs when the thermistor is cold.

No, it won't do much about spikes.  These can happen at any time.  Once the unit is running normally, the thermistor resistance will have stabalized.  Spikes are by definition a short-term phenomena, so no time for the thermistor to react by changing temperature.  The the thermistor will therefore function no differently than a fixed series resistor or the duration of the spike.  The MOV will clamp the spike against this series resistance, and any addition series resistance of the incoming power.

The thermistor will actually make the spike case a little worse.  Some fixed energy will be imparted onto the thermistor due to the extra spike current.  This will raise its temperature, decreasing its resistance, making the unit more susceptible to subsequent spikes for a short time.