Power MUX for USB and AC adapter
The datasheet for the TPS2115A you're considering lists its ESD ratings as 500V and 2kV (depending on the model) in the same 'Absolute Maximum Ratings' table which you're seeing the 6V limit.  

I read that as 6V being the maximum sustained operating voltage (although proper operation above 5.5V is not implied).  

While your teammate is correct in in his position that a 5V TVS device will not prevent the input voltage from rising above 6V during an ESD event, I believe that he is incorrect in saying that any ESD will automatically damage the device.
According to the datasheet, you don't need to ensure that an ESD event doesn't raise the input voltage above 6V - you rather need to ensure that it doesn't exceed the 500V or 2kV limits.
How you do that (filtering, TVS's, whatever) is another question.  

Choosing a different device (with a higher voltage rating) does not give you any automatic assurance of ESD protection.