Step-down converter and ceramic minimum ESR capacitor
You can assume the ESR of the ceramic capacitor is \$0\Omega\$ in that frequency range and add a series resistor to put the zero right where you want it. Usually a fraction of an ohm up to an ohm or two will do it. 

Here, for comparison, from an AVX paper, is the ESR of a 4.7uF ceramic capacitor vs. a tantalum. 



As you can see, \$0\Omega\$ is a pretty good approximation for the ceramic part when you want total ESR to make it look more like a tantalum part. 

Edit: Note that the very high capacitance X5R MLCC caps you have in mind typically have a horrible voltage coefficient. The stated capacitance is achieved at a bias of 500mV, which is probably lower than you are using. 



For the same zero frequency your ESR must be higher by the capacitance ratio so if your '220uF' cap is only 80uF at temperature extreme and 5V bias you might need to have more like 150m\$\Omega\$ series resistance to maintain the same stability as the 330uF tantalum cap in the eval board.  

You should be able to find these specs for the Samsung parts.. the above graph is from an NIC guide.