How are charges moving?
Alright, it's been a while since fundamentals, but here we go. Keep in mind there are lots of different avenues to the solution for this problem. 

First of all, I calculate a total charge of 100\$\mu C\$. We're going to need that. 

This problem might be a little easier (like many beginner EE problems) by rearranging the way it's drawn. The clue comes from the connection of the zero resistance wire between the outside capacitors. Then, at the instant of connection you get this arrangement:







simulate this circuit &ndash; Schematic created using CircuitLab

That looks a little easier to me. The total charge is conserved and it all comes from C2. You're using voltages to solve, so we'll try that route. One approach is to calculate the new voltage across C2 and the C1/C3 combination. For that we can look at this as a single large capacitor, in which case the equivalent capacitance would be $$ C_{eq} = C_2 + ({ 1 \over C1} + {1 \over C3})^{-1} $$ 

I get an equivalent capacitance of just about 14.55\$\mu F\$.

As you've already pointed out the voltage across a capacitor is: \$ V = {Q \over C} \$. Now we know the total charge and the equivalent capacitance. Thus the voltage follows. I calculate 6.875V. We now know the voltage across C2 and its capacitance, so we can find the charge remaining on it. I calculate that 68.75\$\mu C\$ remains on C2. Seems reasonable.

The remaining charge, 31.25\$\mu C\$, is shared between C1 and C3. 

Let's sanity check.
$$ {(100\mu C - 31.25\mu C) \over 10\mu F } - { 31.25\mu C \over (5\mu F^{-1} + 50\mu F ^{-1})^{-1}} = 0 $$

Putting that all together...







simulate this circuit

Now if we look at each terminal of added capacitors (C1 and C3) which are connected to C2, we can see why your original equation would give a \$+q \$ for C1, a \$-q \$  for C3 while the Q on C2 is \$ Q2(initial)-q\$. Notice that the nets that C2 are connected to (top and bottom) sum to the original total charge while the new wire connected (between C1 and C3) has a total charge of zero. Thus charge is conserved and the universe goes on.