Charging a capacitor in Eagle SPICE
Your basic problem is that SPICE assumes that your circuit has existed forever, so any transient effects have disappeared long ago. As far as the simulation is concerned, C1 is already charged to 10V at \$t=0\$. If you want to see the transient charging of the capacitor you have a couple choices:


Change V1 from a dc source to a pulse or PWL source, so that its
value is 0V at \$t=0\$ and rises to 10V as quickly as the simulator
will allow. You will probably need to specify the timestep for the
transient simulaton to be as small or smaller than the risetime of
the supply voltage.
Specify an initial condition for the
voltage on the capacitor. I don't know if there is a GUI method for
this in Eagle SPICE, but in plain vanilla SPICE you would say
something like .ic V(C1)=0. You must also modify the .tran
simulation command to add the UIC (use initial conditions) option