PSpice, collector emitter voltage is way too big
If you want Ve to be 6 volts, then the base voltage must be in the vicinity of 6.6 volts in order for the base-emitter junction to be forward biased. You must change your voltage divider ratio to produce this, rather than 0.5 volts.

Once you've done this, as others have noticed, you must decrease the resistor values to provide enough base current.