Measure PIC's own VDD-in voltage with ADC
That PIC has an internal 1.024V bandgap reference, selected by setting the Channel Select bits to 11111.
So if you set your ADC module's reference to Vdd and then tell it to measure the 1.024V reverence, you can infer back to what your Vdd actually is.

Normally you would work out the voltage on a pin which you've A2D'd with something like:
Vin = (ADCval/ADCrange)*Vref

But in this case its Vin which you know (1.024v) and you want to solve for Vref (your Vdd), so:
Vref = (Vin * ADCrange)/ADCval
or more specifically for your case:
Vdd = (1.024 * 4096)/ADCval