Wondering if I can change a cap value in a design
That is a bulk capacitor for the ESP32 module. Since there is already capacitance on the board itself, that value is less critical. The 0.1uF is far more critical, but can be substituted for a 0.47uF or 0.33uF in a pinch.

I would choose the 4.7uF, but you could always put down two of them instead of 1 and that makes close to 10uF.

100uF would probably work, but the impedance of the capacitor will have somewhat different characteristics from the 10uF and may not be as effective (assuming they did their homework with the reference design).