USB header pinout, connecting a poorly marked cable
The above is a connector for two USB ports as you often see on the front panel. So it really won't matter if you use pins 1,3,5,7 or 2,4,6,8 but I guess the former being port zero is the way I'd go. The USB specification has the following official colours that should be used (although it's not always the case):


Red = Positive
White = Data-
Green = Data+
Black = Negative


So your cable order seems to match the motherboard connector so you should be right to attach it with the red wire to either of the +5V pins. I would hope / expect the black and red are the supply voltage but if you did happen to get erratic operation it might be that the data lines are reversed. That won't cause any hardware damage but you can find more information on that side of things in the question In a USB cable, is it OK to swap the D+ and D- wires?