How do I implement TDMA with basic 433 MHz transmitter receiver pairs?
Without two-way communication, or a way of precisely synchronising the time, you can't.

What you can do is have your device transmit its message several times, with a random delay between the messages. This improves the chance of at least one message getting through.
Of course there's a fundamental limit to the number of transmitters that can talk at the same time, depending on the length of the message, the total time you're prepared to wait, and the probability of success that you're happy with.

You could write a simple program to investigate this, to find out how many transmissions you need to have a reasonable chance of success.