TPS61025 and PCB layout
You've kept it pretty close to the reference layout, which is good!
There is some confusion about FB left floating, which is apparently allowed with a fixed output part in this family.
It also looks like you kept the current loops short.  


  The input for it is the feedback voltage on the FB pin or, at fixed output
  voltage versions, the voltage on the internal resistor divider.


Just remove the resistors completely, maybe only add a small testpoint. Now it's an antenna for problems.

I'd also remove C1. The characteristics of the input capacitor are important, and C1 is not recommended by TI anywhere.
You know the switching frequency is 720 kHz max, the 100 nF is for ~10 MHz, so you're off a bit.
eg: Switch places C1/C5 and replace C1 for a dnp for future BOM changes.
Do the same on the output C10. This gives flexibility in changing the capacitance or impedance. (or prototyping) 

I can't calculate whether your chosen caps are a right part. I'd usually just try a batch that match the recommended part.