How to redirect a newly registered user to a custom URL after signing up?
Consider using the Rules module to do this.

Here is how such (fairly basic) rule would look like, based on your extra comment in my answer (= new users that register do NOT need admin approval):


Event: After saving a new user account.
Condition: None
Action: Page redirect (with value = Node/35 in your case).


The above is just a basic rule. You might want to enhance it in various ways. E.g. add a 2nd action to the very same rule to just set a special welcome message (near the top of the main content of your pages).