Change stylesheet for just one page in Drupal 7
Try adding this code snippet in a custom module :

function MYMODULE_init() {
  // You can verify actual page by using arg() function. Example for targeting node with nid 123
  if (arg(0) == 'node' &amp;&amp; arg(1) == '123') {
    drupal_add_css(base_path() . drupal_get_path('theme', 'mytheme') . '/path/to/css/file.css');
  }
  // You can verify actual page by using the actual alias
  // Supposing your page alias is : http://www.example.com/first-part/second-part
  $args = arg(NULL, drupal_get_path_alias());
  if ($args[0] == 'first-part' &amp;&amp; $args[1] == 'second-part') {
    drupal_add_css(base_path() . drupal_get_path('theme', 'mytheme') . '/path/to/css/file.css');
  }
}


Don't forget to change MYMODULE by your module machine name