CkEditor Toolbar not available/visible to Administrator when creating content
Sounds like you have a ckeditor plugin conflict. 

Your symptoms are typical what happens if there are for example a js error on a added ckeditor plugin.

Quick way to confirm is using Firefox Console, it will in most cases flag the offending js for you. Armed with that you can google for a fix or patch.

Alternatively you can turn of the plugins off one by one, but you need to remember to clear your cache, else the offending js could still be there.

So try FF console first and post any extra info you get.