Save multi value in multi value field programmatically
As per my understanding you are trying to create a new article content type with multiple images. Assuming that you have the path of the images. In Drupal 7 you can use the below code


  $node = new stdClass(); // We create a new node object
  $node->type = "article"; // Or any other content type you want
  $node->title = "Article title";
  $node->language = LANGUAGE_NONE; // Or any language code if Locale module is enabled. More on this below *
  //$node->path = array('alias' => 'your node path'); // Setting a node path
  node_object_prepare($node); // Set some default values.
  $node->uid = 1; // admin id
  // Let's add standard body field
  $node->body[$node->language][0]['value'] = 'This is a body text';
  $node->body[$node->language][0]['summary'] = 'Here goes a summary';
  $node->body[$node->language][0]['format'] = 'filtered_html'; // If field has a format, you need to define it. Here we define a default filtered_html format for a body field
  // Add images
  $image_limit = 5;
  $images = array(//images to attach to node
    '0' => 'http://cf.juggle-images.com/matte/white/280x280/drupal-logo-primary.jpg',
    '1' => 'http://cdn.flaticon.com/png/256/37187.png',
    '2' => 'https://www.drupal.org/files/project-images/logo-128x128.jpg',
    '3' => 'http://guillermocerezo.com/sites/default/files/field/image/drupal-logo_0.jpg',
    '4' => 'http://drupalcrafters.org/sites/default/files/DrupalCraft-logo_0.png'
  );
  for ($i = 0; $i &#60; $image_limit; $i++) {
    $file_info = system_retrieve_file($images[$i], 'public://pictures/', TRUE, FILE_EXISTS_REPLACE); //storing image inside picture folder
    if ($file_info->fid) {//if fid exist then image is saved from URL.
      $node->field_multiple_images[LANGUAGE_NONE][$i]['fid'] = $file_info->fid; //assign image
    }
  }
  $node = node_submit($node); // Prepare node for a submit
  node_save($node); // After this call we'll get a nid
  drupal_set_message('article  saved !!!');
  watchdog('info', 'Article node created');