Can Pluto be seen with the naked eye from Neptune when Pluto and Neptune are closest?
No, it cannot. Far from it.
The closest approach between both planets is roughly 16 AU due to the 3:2 orbit resonance. Pluto will even then be a tiny dot among many with a brightness around 14 mag.
You can try that with Stellarium yourself, placing the observer on Neptune and looking for Pluto. You just have to find the right time. One such time is approx. in the year 2877.