How are sulfuric acid clouds able to completely cover Venus?
The Venusian cloud deck is highly acidic. How much water there is in Venus's atmosphere above and below the cloud deck is irrelevant. What matters is how much sulfuric acid there is within that cloud deck.
And it is a lot, with the cloud deck droplets being between 75% to nearly 100%  sulfuric acid by weight. Since the atomic weight of sulfuric acid is about 5.44 times that of water, this weight range corresponds to between 35.5% to nearly 100% sulfuric acid by volume, or by molecule. It's only in the polar regions where the sulfuric acid content of the cloud droplets is at the low value of 75% by weight.
The top of Venus's thick cloud deck is marked by where incoming solar radiation can dissociate the sulfuric acid in the cloud deck. The bottom of Venus's thick cloud deck is where the high temperature (temperature increases with increasing depth in the cloud deck) dissociates sulfuric acid. Sulfuric acid is stable within these bounds.
The dissociation at the top and bottom of the cloud deck means there has to be a source of sulfuric acid to counterbalance the dissociation. The source is the dissociation of other molecules at the top of the cloud deck, plus the large amounts of sulfur dioxide (&quot;large&quot; compared to other trace components) in Venus's atmosphere. The dissociation above the cloud deck creates atomic oxygen. This atomic oxygen is very volatile and readily combines with sulfur dioxide to form sulfur trioxide. This in turn readily combines with water to form sulfuric acid.
In short, conditions just above the cloud deck replenish the sulfuric acid in the cloud deck.
References:
Barstow, J. K., et al. &quot;Models of the global cloud structure on Venus derived from Venus Express observations.&quot; Icarus 217.2 (2012): 542-560.
Lee, Yeon Joo, et al. &quot;Vertical structure of the Venus cloud top from the VeRa and VIRTIS observations onboard Venus Express.&quot; Icarus 217.2 (2012): 599-609.
Young, A. T. &quot;Are the clouds of Venus sulfuric acid?.&quot; Icarus 18.4 (1973): 564-582.