Distance from W(West) to vernal equinox
The right ascension of the point on the horizon and due west is LST - 6 hours, where LST is the Local Sidereal Time. The LST can be calculated from knowing the date, time, and longitude. The declination of the west point is 0 degrees. So the angle between that right ascension and 0 hours right ascension (the vernal equinox) is just the difference between the two.