Is it possible to use Photolithography for telescope image sensor?
The pixel size is not a major constraint on the imaging capabilities of an astronomical telescope. The angular resolution of the image is limited by diffraction at the aperture of the telescope. For a reasonable pixel size, the telescope geometry can then be designed so that each pixel corresponds to a region of sky smaller than that angular resolution, so that making the pixels smaller would gain you very little.
Responding to a comment. A diffraction limited telescope with an aperture of $d$  observing at a wavelength of $\lambda$ has (at best) an angular resolution of $\lambda/d$ radians. So if it has an effective focal length of $l$, the smallest useful pixel size will be around $l\lambda/d$. The effective focal length depends on the whole optical setup and will usually be designed to make this size big enough.