Can ground based telescopes use a starshade in space?
If the starshade was to stay in place over the ground telescope, it would have to be in a geosynchronous orbit, which puts it almost 36,000 km from Earth's surface. To cover an angular distance of 1 arcsecond (1/3600 of a degree), it would have a size of around 10km. Certainly not impossible, but technologically impractical at the moment. Also, the starshade would only shade a small region of the sky, so it wouldn't be useful from other observing sites.

As for the space telescopes using a starshade in geosynchronous orbit; that would be impossible, at least for scopes orbiting Earth, like Hubble is. The starshade is orbiting Earth at a different distance, and therefore speed, than the telescopes. As far as I can see, it would be near impossible to keep them aligned for anything more than a few minutes. I haven't done any number-crunching on this, though.