Identifying PLA/PETG or ABS
There is a trick. However I would like to mention that chances are that the random spool you pickup from most stores, especially no name brands, are either completely lying to you about its material or is mixed / cut with cheaper fillers. All about finding a good brand. Course rarely does one actually need pure PLA, a mixed material will often perform as well without you even noticing. Aside from the temp difference. Not to say it is right.

Now the trick is this. While I don't advise ever breathing in potentially carcinogenic plastic smoke. You take a lighter. Burn it. If it smells sweet it is PLA. 

From this link from digital trends about PLA VS ABS you can see why it has this smell.


  The thermoplastic is also more pleasant on the nose, as the sugar-based material smells slightly sweet when heated opposed to the harsh smell often associated with ABS. However, while PLA might seem like a better overall choice at first glance, it features a far lower melting point than ABS.


Also not responsible if you burn yourself or your property. At your own risk. 

Just warming it with lighter might work too. But just burning a small section. It will be real clear. 

Or you could just drop a bit into aceton and see if it melts. PLA will mostly just look like crud after being treated is aceton. ABS is 100% dissolve. 

We see from these forums that PETG does not dissolve via Aceton. So you can test you material. If it does disolve it is ABS. If it smells sweet when burned it is PLA. If it melts at 240 and does not dissolve it is likely PETG.


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We are a bit lost on a test for PETG. However we do know its melting point. Which is 240-260c. I would say it is likely you have ABS



Once we know the material we can get to the meat of your question. 

Best way to proceed is to start with simple calibration prints. The thin wall. Cube, and part fitting. Once those pass you are good to go. Other than buying simplify3d I do not know of any short cuts. Back when I used slic3r I kept a spread sheet. I would change a temp by 5 degrees and give it a quality score. Repeat with speeds. Far as fan, I would expect that it wont effect much. Maybe need to calibrate your PIDs.

Once you have it dialed in, all you will need to do is calibrate the temp when switching materials. Remember you need to calibrate even between different colors (okay its best to.. I often skip) I usually do the temp adjustments live on the printer. Increase and degrease a few degrees. For me the goal is to have the plastic as cool as possible. That allows for highest quality prints (ie less oozing and such)