Constructible n-gons
Jelly, 7 5 bytes

Thanks to Sp3000 for saving 2 bytes.

ÆṪBSỊ


Uses the following classification:


  These are also the numbers for which phi(n) is a power of 2.


Where phi is Euler's totient function.

ÆṪ        # Compute φ(n).
  B       # Convert to binary.
   S      # Sum bits.
    Ị     # Check whether it's less than or equal to 1. This can only be the
          # case if the binary representation was of the form [1 0 0 ... 0], i.e. 
          e# a power of 2.


Try it online!

Alternatively (credits to xnor):

ÆṪ’BP
ÆṪ        # Compute φ(n).
  ’       # Decrement.
   B      # Convert to binary.
    P     # Product. This is 1 iff all bits in the binary representation are
          # 1, which means that φ(n) is a power of 2.


A direct port of my Mathematica answer is two bytes longer:

ÆṪ        # Compute φ(n).
  µ       # Start a new monadic chain, to apply to φ(n).
   ÆṪ     # Compute φ(φ(n)).
      H   # Compute φ(n)/2.
     =    # Check for equality.