Could a 30 knot direct crosswind make a Learjet roll over 90 degrees?
It only ever makes sense to talk about cross-wind when the ground is involved. While the aircraft flies, it moves relative to the air and how fast the air is moving relative to ground only affects ground speed and track. If the air is moving smoothly, it can't turn anything over. Only thing that could bank an aircraft over is strong turbulence.

Natural turbulence of a 30 knot wind is unlikely to be strong enough to bank a Learjet 35 significantly, but a wake vortex close behind a heavy aircraft possibly could. The separation minima are there to prevent encountering wake turbulence on approach.