How fast can fuel be siphoned out if you leave the cap off?
It can happen very quickly. 

I don't have exact numbers, but an acquaintance had this happen in a Cessna 172 and the entire tank was emptied in just a few minutes - the amount of time it took to do one circuit of the pattern and land. The fuel cap was not in the filler neck on departure, and was hanging from the chain, banging against the wing. The moral of that story is: never assume the fuelers put the cap back in.



I've personally flown an older Cherokee 160 that had a loose fuel tank gasket. When doing slow flight, the pressure above the wing was so strong that it would start to ooze fuel from the cap. Fuel would flow in a rather frightening amount back along the wing, and that's with the cap still on.