What ICAO codes are reserved for TIS-B use?
In this answer I'll assume you are analysing ADS-B data on 1090 MHz, which is the defacto global standard. I am less familiar with the ADS-B on UAT (987 MHz) which is used in addition to 1090MHz in the USA, but I assume the same logic applies. 

There are no ICAO addresses assigned to TIS-B targets. 

If an aircraft has an ICAO-address which is detected by the surveillance sensors (e.g. Mode S radar, multilateration system) and the aircraft is not transmitting ADS-B, then a TIS-B target will be created with the ICAO 24 bit address. 

If an aircraft has no ICAO-address, (i.e. it has a Mode A/C transponder / ATCRBS) and is not transmitting ADS-B, then a TIS-B target will be created with a 24 bit address that consists of the Mode A code (first 12 bits) and a unique surveillance system track number (last 12 bits). Primary radar targets are allocated a "Mode A code" of all zeros.

To determine whether you receive an ADS-B message or a TIS-B message you should start looking at the Downlink Format (DF, first 5 bits of the message) if the DF = 17, then it is an ADS-B message. If the DF = 18 then you look at the control field (CF, bits 6-8). CF = 0 and CF = 1 are ADS-B messages. CF = 2,3 &amp; 5 are TIS-B messages. CF = 6 are ADS-R messages. CF = 4 are TIS-B / ADS-R system status messages. 

The TIS-B messages contain an ICAO/Mode A Flag (IMF) bit which indicates how to interpret the 24 bit address. The location of this bits varies by message type (e.g. position, velocity) and replaces a bit in the ADS-B format that has no meaning in TIS-B.