When do I have to contact Centre when departing/arriving at an airport with an ATF?
The Aerodrome Traffic Frequency is a frequency for aircraft to use to aid self-sequencing at airports where a control tower is not operational. Another name for it is the Common Traffic Advisory Frequency. 122.8 MHz was the original frequency designated for UNICOM use and remains one of the more common ones.
The APP/DEP frequencies listed tell pilots that, if they desire to talk with ATC (as IFR flights probably would!), they need to contact Montreal Centre on 135.025 once airborne. Montreal Centre is also the arrival frequency that would help IFR arrivals get established on an instrument approach procedure, if one existed. Centre most probably does not have radio coverage to the ground on this frequency, and even if they did they would not provide towered-airport control services.