Tools to unbuild a model more easily?
Actually, the brick separator is a very versatile tool for disassembling Technic. The end of the wedge can be slipped into the slot on the side of several pieces to help pop Technic pins out from behind (I also use it like a screwdriver for aligning Technic pins while building). It can also be used to separate stubborn beam connections.

I've also got a 1:6 axle attached to the little axle pusher using an extender (sorry...I don't know the actual names of these things and I don't have time to look them up right now). It works great for pushing axles through deeper sockets, or for popping pins out from behind.

Other than that, I've never really had much trouble pulling Technic parts apart. I'm sure there are other uses I've yet to need, but that little orange tool has been a godsend for my sanity and fingertips. :)