Naturally occuring mono- and diglycerides?
Lecithin is a mixture of stuff, which also involves mono and diglycerids. 
As far as I recall, there is no product naturally produced in nature which is pure mono or diglycerid. Fats in nature follow a lot of synthetic paths, not only for energy storage, but also for structural needs (the cell membrane, for example). For this reason, you are very unlikely to find a biological system synthesizing only one molecular species, and I would be surprised it actually exists. 

As for what kind of mono and di, it's hard to say. The metabolic pathways synthesize oleic, palmitic, stearic, arachidonic, butirric chains, among others. The broad set of different combinations, and their proportions lead to oil, or butter, or whatever else. In addition, some residues are phosphated, or they are used to create Sphingolipids. The proportions are decided by the plant/animal metabolism and general conditions.