How to generate two pulses one with 60 and other 66 duty cycle at same instant in 2 pins?
I proposed a few approaches in generating 100kha pwm pulse trains here in response to someone's ask a couple of days ago. The identical code would work for your purpose as well.

It should come up quickly if you do a scan of topics here.

edit: to make it a little bit easier, here is the code I used to generate 50Khz pulse train with 60% and 66% duty cycles.

void setup() {
  // put your setup code here, to run once:
  //pinMode(led1, OUTPUT);                      //led1 as output
  //pinMode(led2, OUTPUT);                      //led2 as output
  pwm1topr(F_CPU / F_PWM);                      //set tmr1/pwm frequency to F_PWM
  analogWrite(led1, F_CPU / F_PWM * 60 / 100);  //led1 @ 60% duty cycle
  analogWrite(led2, F_CPU / F_PWM * 66 / 100);  //led2 @ 66% duty cycle
}

void loop() {
  // put your main code here, to run repeatedly:
    //digitalWrite(led, HIGH);  // turn the LED on (HIGH is the voltage level)
    //delay(100);               // wait for a second
    //digitalWrite(led, LOW);   // turn the LED off by making the voltage LOW
    //delay(100);               // wait for a second
}


and a quick sim confirms its functionality.



enjoy.