Library to set internal analog gain of the Arduino?
I would recommend you to check Nick Gammon's example on using the analog comparator by means of configuring the relevant flag bits of registers in the ATmega328. Sample code from the link, by Nick:

volatile boolean triggered;

ISR (ANALOG_COMP_vect)
  {
  triggered = true;
  }

void setup ()
  {
  Serial.begin (115200);
  Serial.println ("Started.");
  ADCSRB = 0;           // (Disable) ACME: Analog Comparator Multiplexer Enable
  ACSR =  bit (ACI)     // (Clear) Analog Comparator Interrupt Flag
        | bit (ACIE)    // Analog Comparator Interrupt Enable
        | bit (ACIS1);  // ACIS1, ACIS0: Analog Comparator Interrupt Mode Select (trigger on falling edge)
   }  // end of setup

void loop ()
  {
  if (triggered)
    {
    Serial.println ("Triggered!"); 
    triggered = false;
    }

  }  // end of loop