RH_RF24_MAX_MESSAGE_LEN in RH_RF24.h
RH_RF24_MAX_MESSAGE_LEN is probably defined in the header file RH_RF24.h.

It doesn't matter what size it is, you should always use RH_RF24_MAX_MESSAGE_LEN rather than the number because the value might change in the library and this will break your code if you have used the number.

If you want to send a message that is larger than RH_RF24_MAX_MESSAGE_LEN then you will need to 'fragment' the message (unless the library supports that).
I would use the first byte of the message as the type of message and define one of those types as a multi part string.  Then send a number of these message and reassemble the data on the receiver. When the receiver sees a message that contains a character with the ASCII value 0 then that is the end of the string.