Vin & VU pins of NodeMCU V3
On the NodeMCU “v3” (and only on the v3) there’s a pin called VU (Vusb) that is connected to the +5V on the USB bus of the NodeMCU socket. This pin can be used to feed external components when it’s connected to USB, within the limits of the USB power supply it’s connected to.

The Vin pin (which is available on all NodeMCUs (and not just the v3) is a +5V power input which can be used to power the NodeMCU if it is not connected to USB. It can not be used as an output and it needs a stabilized supply.