Serial.println Issue with Flame Sensor
First things first; please INDENT YOUR CODE. The code you posted is a mess and I took at least double the time to fix that. 

First, you have an extra closing curly bracket at line 17 and the if (Fire == High); should be changed to if (Fire == High){

Fixed code:

int Led = 4;
int Buzz = 7;
int Sensor = 11;
int Fire = HIGH;
void setup()
{
  Serial.begin(9600);
  pinMode(Buzz,OUTPUT);
  pinMode(Sensor,INPUT);
  pinMode(Led,OUTPUT);
}
void loop()
{
  Fire = digitalRead(Sensor);
  if(Fire == HIGH){
//Serial.print("analog Read = ");
//Serial.print(analogRead);
    Serial.println("HELP! A FIRE!");
    digitalWrite(Buzz,HIGH);
    digitalWrite(Led,HIGH);
    delay(200);
    digitalWrite(Led,LOW);
    delay(200);
    Serial.println(analogRead(A0));
 }
 else
 {
    Serial.println("No fire detected");
    digitalWrite(Buzz,LOW);
    digitalWrite(Led,LOW);
  }
  delay(500);
}