Issue sharing MISO with multiple RC522 RFID Readers
I am joining this conversation VERY late, however maybe my answer can help someone who is just now looking into this.
I was able to get SEVEN RC522 readers working on one Arduino! My solution was very similar to your idea, except instead of the SS pin, I used the MISO pin.

If you look into how the pins work, all of them are outputs going from the master (Arduino) to the slaves (RC522), EXCEPT for the MISO pin which is an input going from the slaves to the master.
So I gave each RC522 scanner it's own MISO pin on the Arduino, and the rest of the pins were shared with all the scanners.
To get it working with the code, the simplest solution I found was to initialize a new RFID using the corresponding MISO pin each time I wanted to read from one of the RC522s.
This worked for the Arduino because you can set several of the digital pins as MISOs, however I haven't figured out how to get this working on a Raspberry Pi yet (without using a multiplexer) because the Pi has a few specific pins that are used for MISO.
I was using the old Sunfounder library. At the bottom of this page (http://wiki.sunfounder.cc/index.php?title=Mifare_RC522_Module_RFID_Reader), if you download the &quot;RFID-RC522_test_experiment&quot; zip file it will have the library included. Just copy and paste the RFID1 folder into your Arduino Library folder. Here is a simple tutorial for that library: https://www.sunfounder.com/learn/RFID_kit_V1_for_Arduino/lesson-29-rfid-entrance-guard-system-rfid-kit-v1-0-for-arduino.html
Here is some example code. It is pretty ugly but it worked.
void checkRFID(int i){
  if(i==0){
    rfid.begin(2,4,5,7,3,6);
  }
  if(i==1){
    rfid.begin(2,4,5,8,3,6);
  }
  if(i==2){
    rfid.begin(2,4,5,9,3,6);
  }
  if(i==3){
    rfid.begin(2,4,5,10,3,6);
  }
  if(i==4){
    rfid.begin(2,4,5,11,3,6);
  }
  if(i==5){
    rfid.begin(2,4,5,12,3,6);
  }
  if(i==6){
    rfid.begin(2,4,5,13,3,6);
  }
  delay(100);
  rfid.init();
  uchar status;
  uchar str[MAX_LEN];
  // Search card, return card types
  status = rfid.request(PICC_REQIDL, str);
  if (status != MI_OK)
  {
    return;
  }
  // Show card type
  rfid.showCardType(str);
  //Prevent conflict, return the 4 bytes Serial number of the card
  status = rfid.anticoll(str);
  if (status == MI_OK)
  {
    memcpy(serNum, str, 5);
    rfid.showCardID(serNum);//show the card ID
    Serial.println();
    Serial.println();
  }
  delay(100);
  rfid.halt(); //command the card into sleep mode 
}