I2C communication between Attiny85 as master and arduino UNO as slave
The pure master functionality of the TinyWire library is currently buggy. As a work around you can initiate the library on the ATTiny also as a slave with an address. When the endTransmission() function is called, the library switches temporarily to master mode for sending the bytes. I've tested this with your code in my own setup and it works. (Be sure, that the frequency in the ATTiny is set right. I tested the library only for 8MHz. For my own ATTiny's I had to do an extra step and set the correct fuses with avrdude)

I think the pure master part is blocking itself after the first transmission. I will add an issue in the github project. Maybe I can fix this in some time.

Chrisl aka lucullusTheOnly

EDIT: I had to think about this and looked into the library. The problem was found easily. In twi.cpp there is a NOISE_TESTING define block in the master send/receive function, which is constantly triggering error #6 (unexpected stop condition). In slave mode this doesn't happen, because directly before sending as a master it calls the master init function, which clears all USI flags, including the stop condition flag, that is polled in the send/receive function.

I have deactivated the NOISE_TESTING in the github project. If you don't want to download the current version, you can just open twi.h and comment the definition of NOISE_TESTING.