ESP8266 NodeMCU v3 basic questions
The subtle clue is in the voltage that is available. That is, the only voltage provided on the board is 3.3v. That's a slight hint that the board might run at 3.3v. And you would be right in that assumption.

The ESP8266 chips, as are most modern MCUs more powerful than 8-bit, 3.3v devices.

So you would choose 3300 as your "Logical Voltage" value.  Or better still, measure the 3.3V and find exactly what it is and use that value x 1000 (for example 3317 or 3295).