Is it possible to extend the reach of a PN532 NFC/RFID shield?
I suspect not. NFC is designed for short range for privacy reasons. Some RFID systems have longer ranges (a few meters). They work by using an electromagnet to create a switching magnetic field. The RFID/NFC chip takes power from the magnetic field and then modulates a signal onto it, which the sensor detects. In order for it to work the chip needs to be close enough to get as strong enough field to power itself, and to modulate that field.