Controlling amplifier using remote control jack
According to this thread on remotecentral the signal on the RCA connector is just the inverted signal that the IR-LED receives. So if you load an RC5 library and invert the output (0=1 and 1=0), you should be able to send codes to that connector with an arduino. Or even better, use an ESP8266 and control it over wifi ;)
The RC5 codes and their functions are in this  nice excel sheet or use this information if you want to send raw hex