Accessing one code using another code on RobotDyn Uno+WiFi board
You can't 'access code'. You can write sketches to communicate for example over Serial or SoftwareSerial. You connect the pins of Serial interfaces RX to TX and let sketch in one MCU read or parse what the sketch in other MCU sent over Serial with print or write.
The onboard connection on Uno+WiFi board is over Serial. So you can't use USB and connection to esp8266 at the same time. But you could use SoftwareSerial like other use it with esp8266, if you connect some pins (for example 6 and 7) of Uno headers to Serial of esp8266 which is accessible on the esp8266 header on the board.