Picking the time a led on an arduino should turn on, via android
Make the Bluetooth message send how many seconds it is until the light should be on, and how many seconds it should stay on.

Then the arduino code can just handle everything with millis(). You know the millis() you were asked to start, add the delay, and wait for that time. 

Delays less than 50 days (wrap around of millis ())  take no effort to handle it you embrace the overflow. 

Handling delays greater than 50 days can be achieved by watching for millis() overflows and counting them. You could also make your own timer based counter.

If you care about recovery after power loss / reset you could use an RTC module. Depending on its complexity, it could interrupt you or you poll it to check for a date you saved to Arduino eeprom.  You would have to consider what the system should do it the alarm would have happened during the power loss...