Name comparison using fuzzy string matching
To apply the same function to each row of a dataframe column, you usually use pd.Series.map or pd.Series.apply. You can thus simplify your code to:

from functools import partial
from fuzzywuzzy import process


accounts_DB = pd.read_csv("file.csv") #65,000 rows and 15 columns
accounts_SF = pd.read_csv("Requested Import.csv") #5,000 rows and 30 columns

best_matches = partial(process.extractBests, choices=accounts_SF['Account Name'], score_cutoff=95)
accounts_DB['Company Name'].map(best_matches).to_csv("Matched Accounts.csv")