Python Code Cleanup/Optimization
I don't know about "more efficient", but here are some hints and tips that will help you clean up the code and make it more readable:

Style remarks


My style checker asks for at least 2 spaces before an inline comment (lines 20-21). I don't think it's a bad idea.
According to PEP8, you should keep your lines shorter than 80 characters (lines 24, 25 and 49).
This line is not very clear.

information = 'ENT: ' + str('{0:.2f}'.format(comp)) + ' SMA: ' + str('{0:.2f}'.format(smasumm)) + ' LB: ' + str(
 '{0:.2f}'.format(smasumm - framsd)) + ' UB: ' + str('{0:.2f}'.format(smasumm + framsd))



It would be a lot clearer to rewrite it like this:

'ENT: {0:.2f} SMA: {0:.2f} LB: {0:.2f} UB: {0:.2f}'.format(
    comp, smasumm, smasumm - framsd, smasumm + framsd)



Avoid one letter variable names (and other cryptic names like smasumm,  because they're not descriptive and it's not immediately obvious what they represent.
The lack of comments makes it difficult to follow what you're trying to do. You should use docstrings to write a small paragraph that provides an explanation of what you're trying to do.
Again according to PEP8:



  Imports should be grouped in the following order:
  
  
  standard library imports
  related third party imports
  local application/library specific imports
  


So you want to replace your imports with this:

from collections import deque
import datetime
import math
import subprocess

import numpy as np
from PIL import Image
from PIL import ImageChops
from PIL import ImageDraw
from PIL import ImageFont



Why do you alias numpy as np? It's not very readable. I'd rather read numpy in full letters each time.