Finding the first and last IP in an IP range string
The first thing that jumps out at me is that this is a single function, with no classes and only one possible use. But without context, I couldn't comment on whether or not that's good. Since the snippet is so short and limited, your only motivation for changing it is that you might want to use it in a larger context. So I'm going to assume a larger context which may or may not apply.

The second thing, then, is that there are no comments. I can look at this code, see the ipV is 4 or 6, see "Start IP" and "End IP", and figure out that this is computing an IP address range for IPv4. But the function name doesn't really tell me that. Just for maintainability sake, you might want to do something about that. 

The third thing that jumps out at me is that this function does nothing useful. It has two (conditionally 3) print statements as side effects, which means that you can't use these results. You might want to separate the computation of the range from the printing of the results. This is where I have to assume a larger context. If you just want to print those 2 or 3 lines, why bother modifying working code to begin with other than to maybe add some comments for the future. What if you want to accept ranges (10.0.1.5-50)? Heck, what if you want ranges with holes (10.0.5-10.2-100)?

Fourth, your variable i is the index of item in the loop, which is used in a lot of logic in your function. See https://stackoverflow.com/questions/522563/accessing-the-index-in-python-for-loops for some discussion on that. Specifically, don't manage your own loop index variable. I see why you are doing so; to loop the necessary times between 1.* and 1.1.*. You can do this a few different ways. Statically, you need 4 parts to your IPv4 addresses. You could iterate over the range 4 and generate these 4 parts. You could iterate over your input parts and append the missing parts as needed once complete. I don't actually have a strong opinion of the right way, only that your way looks funny to me.

Fifth, tempSIP. important? used?

Punchline without assuming a larger context: Add a comment about usage. Add a comment about the program logic. Rename the function to have IP in the name. Delete tempSIP.