Ohms law calculator + whitelist of user. Learning use
Don't 

using namespace std;


This doesn't do what you want (only first one works):

    //Whitelist
    Whitelist = "Fred267s", "Seb4572s", "Popp4593s";

    //Check if username is on whitelist
    if (Username == Whitelist){



[It's also a VERY dodgy access control mechanism!]

I don't like asking user for a string describing the "Formula". How does the user know they should type "Wolt"? What if they type "wolt" instead? I think it would be more reasonable to show 3 choices:

1 - Wolt    2 - Amp    3 - Ohm

Please Enter (1-3): 


And then clean the user input checking if it is a valid integer between 1-3 and then represent the choice internally using a Class enum in your code. 

This will open up a range of oppotunities to use functions in your code. 


enum class Formula ( wolt = 1, amp = 2, ohm = 3 );

...

Formula prompt_formula() {
  // code to read from std::cin clean input and cast to enum class
}


Then try to find a way to add even more structure to your program rather than one huge if/elseif/else statement. I am not going to give you the code, because that would defeat the purpose, but your main function should be more like this:

int main() {
  explain_usage();
  Formular form = prompt_formular();
  auto [label, answer] = compute(form);
  print_answer(label, answer);
}


I could go on, but that's probably plenty to get on with for now.