Setting receive_payment_on flag for employment applicants
Put your code into a method. So you get rid of the temporary variable, its cleaner and you can leave your method with a return as soon as you find the first true. (A break to leave the loop will have the same effect.)

In addition to that I'm a big friend of guard conditions. Invert if section[:applicants] ... end to if !section[:applicants] next, so you have one nesting level less. 

...
config[:sections].each do |section|
   if !section[:applicants] next
   section[:applicants][:sections].each do |app_sec|
       if app_sec[:employment] &amp;&amp; app_sec[:employment][:receive_payment_on]
           return true
       end
   end
end
return false