Evaluating given numbers and operations
You're using C headers (which end in .h), not the C++ ones.  This will also ensure that they're put into the std namespace.  Also, you can remove &lt;string.h&gt; since it's not currently in use.
All of your operations rely on command line arguments, yet the program is still allowed to continue even if there aren't any (excluding the filename).  You can fix this by terminating the program right away if argc is too low.

if (argc == 1)
{
    // print this to the standard error stream
    std::cerr &lt;&lt; "Additional arguments are required!";
    // same as return 1, also used for failure
    return EXIT_FAILURE;
}


With this in place, you should also redo the other argc checks.  Add this given check first, then have the others.  I'd also consider replacing else with an else if that includes a specific number of command line arguments.  With the else there, that code block will be executed with any other value not already given in an if.
Consider changing the parameter names of the functions for clarity.  Even if you're trying to pass the command line arguments to them, the functions themselves aren't very self-documenting.

You could also assign the various argv[] values to separate variables in main() and passing them to the other functions.  This again helps with self-documentation.
There's no need to declare and then initialize:


double operand;
operand = strtod(argv[2], NULL );



If you just need to initialize, then do that only:

double operand = strtod(argv[2], NULL );

The contents of mean():


double summation = sum(argc, argv);
return summation/((double) argc-2);



can just be a single line:

return sum(argc, argv) / ((double) argc-2);


The sum() function still reveals the intent, so it can be put together.