Better way to write 'bulky' function in jQuery
It's difficult to really clean it up, since a lot of it is "manual" translation from one piece of markup to another. Different elements, different attributes etc.

However, there's the low-hanging fruit (and golden rule): Don't repeat yourself.

So don't call $(this) over and over. It's just inefficient. Do something like 

var source = $(this),
    target = $(".profileDetail");


and then chain off of those, like source.find('h4.name')...

However, a nicer way to do this might be to use a data-source/data-target attributes on the "big" profile elements. For instance

&lt;div class="profileDetail"&gt;
  &lt;img class="largeImg" data-source="img, data, bigimg" data-target="src"&gt;
  &lt;h3 class="name" data-source="h4.name"&gt;&lt;/h3&gt;
  ...


So in each element data-source is a comma-separated list of the selector to run in the source element, the (optional, defaults to html()) method to call on the result, and the (optional) arguments. Meanwhile, data-target is can be an attribute name, but it's optional and defaults to html()

Then, in the JS, do something like this:

$('ul.teamProfiles li').click(function (event) {
  var selection = $(this),
      destination = $(".profileDetail:first");

  // find and loop through elements with a data-source attribute
  destination.find("[data-source]").each(function () {
    var target = $(this),             // an element in the "big" profile container
        data = (target.data('source') || "").split(/\s*,\s*/), // parse the data-source attribute
        selector = data[0],           // get the selector
        method = data[1] || 'html',   // get the method (defaults to html)
        args = data.slice(2),         // slice off the arguments
        attr = target.data('target'), // get the destination attribute (if any)
        source, content;

    if(!selector) return; // nothing to do
    source = selection.find(selector); // find the source element in the small profile
    content = source[method].apply(source.get(0), args); // call the method with the args
    if(attr) {
      target.attr(attr, content); // set the target's attribute, if that's what's needed
    } else {
      target.html(content); // otherwise, default to inserting the content as html
    }
  });
});


That function is pretty generic (though it won't work for more complex stuff like setting a bunch of css).

The point is, that the mapping of small profile to large profile can be declared entirely in the HTML; the JS doesn't need to change if you add/remove elements.

Haven't tested it, but it should work