How to export 'employee of' relationship that has multiple staff members?
I put a quick example of a View together which you can download from our Treasure Trove.

It is based on 'contact' and assumes that the Org is at the B end of the relationship, and uses a single 'views' relationship starting from B to then connect to Contact A, and the 'which Civi relationship to use' has been set to include several - but these will need reselecting based on which civi Relationships you are trying to pull in.

Hope it makes sense. It may not be quite where you were headed but may gave you some ideas in how to put your View together.

I think an alternative could be to build the View based on CiviCRM Relationship, rather than CiviCRM Contact.