Ctrl + Alt + Num 0 Doesn't work
If you want to add this feature to Quick Favorites you can follow these steps:

Press F3 to search for commands and type &quot;active camera&quot;
Right-click RMB on Align active Camera to View and select Add to Quick Favorites
Press Q to get the list of favorite commands and you can quickly select the Align Command from that list


Otherwise you can also follow these steps to quickly enable lock of the camera view:
Step 1
Press N in the 3d View to open up the right sidebar and go to View:

Step 2
Right-click RMB on Camera to view and Select Add to Quick Favorites:

Now you can enable Camera to View by pressing Q: