Why is Blender's default cube 2 cubic meters instead of 1?
There is no reason. But the default cube goes 1 unit in every direction, it's the same size as a sphere with a radius of 1 unit as well as for example procedural spherical gradient, a plain axis empty has lines going 1 unit in each direction of all axis as well. If it was 1 unit size and it was centered it would have sides ending at half a unit in all directions, that might be weird. So for what it's worth, it has some sense behind it. I think it is mainly this way, only because it had to be some size, and this is no better or worse than anything else. You can create a cube of any size and hit ctrl+u to save another default file if that makes more sense to you.