Proof of monotonocity of preferences
Let me pick up the discussion in the comments.
Consider any diagonal through the origin. Suppose it intersects some IC more than once. Pick two of these points and call them A and B. Because they are on a straight increasing line, one of the bundles, say B, has more of both good 1 and good 2. By monotonicity, bundle B should be preferred over A, which contradicts the statement that they are on the same IC.

If that is what you mean, your intuition is correct. However, there seems to be a jump in your argument: By saying
"if one indifference curve intersects the diagonal line n times (say), then (n-1) points belong to different indifference curves" you seem to be already assuming that the statement to be shown is correct and the n intersections could not exist in the first place.