Rosen's Diagonal Strict Concavity condition
So you want to find a maximum of $\sigma(s,z)$. If $\sigma$ is diagonally strictly concave you can do so by starting at any point and just following the gradient $g(s,z)$ until you find the maximum and no matter where you start, you will always end up at the same point (Start at the lower black points and follow the direction of the gradient (the direction of the steepest ascent).).


However, if $\sigma$ isn't diagonally strictly concave, you could end up at different maxima by starting at an arbitrary point and following the gradient (Follow the direction of the steepest ascent starting from the two lower black dots; you'll end up at two different points.).