Why is the pOH of 1M HCl 14?
In the moment from the video that you referred to, Sal was using the equation $\rm pK_w=pH+pOH$ to find the $\rm pOH$ of the solution. $\rm pK_w$ is equal to 14, since $K_w$ is equal to $1\times 10^{-14}$, giving us the new equation $14=\rm pH+pOH$. We know that the $\rm pH$ of a 1M solution of $\ce{HCl}$ is zero from earlier on in the video. This gives us that $14=0+\rm pOH$, or in words, that the $\rm pOH$ must be equal to 14.