Structures present in liquid water
Yes, there are various water clusters leading to local order on the scale of a few molecules holding stabilized orientation with one another for measurable timescales.  This article(1) is a pretty good introduction to the major varieties in liquid water.  This article(2) talks more about various structures available in any phase, including the ices, which gives some pretty good context.

(1) Keutsch, Frank N., Saykally, Richard J., Water clusters: Untangling the mysteries of the liquid, one molecule at a time, 2001, PNAS, 98, 19, 10533–10540, doi:10.1073/pnas.191266498

(2) Ludwig, Ralf, Water: From Clusters to the Bulk, 2001, Angewandte Chemie International Edition, 40, 10, 1808-1827, doi:10.1002/1521-3773(20010518)40:10&lt;1808::AID-ANIE1808>3.0.CO;2-1