Why do Hydrogen and Helium have molar volumes higher than an ideal gas?
As hydrogen and helium's molecular weight are too less, the intermolecular attractions are also too less. So the a/V^2 is negligible.  So the v.d.o equation becomes P (V - nb) =RT . By which, it can be said as the pressure of these elements are too less and from Boyle's law , the volume is higher.