What's the relationship between dew point and temperature?
There are two separate effects:


The average temperature above urban land is greater than above rural land. This could be because of the cooling effect of plants evaporating water, or because of the higher albedo of vegetation than pavement and roofing.
The absolute humidity decreases; that is, the total amount of water vapor in a given volume of air decreases, perhaps due to the capture and run-off of rainwater into storm drains, rather than evaporating.