How does photosynthesis work?
A better way of thinking about it, without getting too bogged down in details, is that the plant absorbs the energy of photons and uses it to drive chemical processes - ultimately the synthesis of sugar out of carbon dioxide and water - that are energetically "uphill", and would not happen spontaneously without the energy from the photons.  The energy from the photons is used by the plant to move electrons from one place to another, but no electrons are actually generated or consumed in the process ... photosynthesis is a cycle, so you always end up back where you started, with some molecules of $\ce{CO2}$ and $\ce{H2O}$ having been consumed (along with a lot of light energy), and some extra molecules of sugar and $\ce{O2}$ having been produced.

The places where the photonic energy is used to mobilize the electrons are protein complexes called photosystem I and photosystem II, which are concentrated in the chloroplasts of green plants.  The details of how this happen are still not completely understood, but a LOT of progress has been made fairly recently using fancy equipment like laser spectrometers that can measure physicals processes that occur on timescales shorter than a nanosecond.  This has allowed researchers to map the progress of the electron as it moves from one part of the protein complex to another, following absorption of the photonic energy.  

Does that help at all?