Are all amides also amines?
An R group is used in structural formulae as a placeholder for a range of possible subtituents, e.g. hydrogen, alkyl chains or aryl groups etc. It can also be used as an abbreviation when R is a predefined rest.

An amide is a derivative of an organic acid where an $\ce{OH}$ group is substituted by $\ce{NR2}$ (with R = H or any organic rest, see here, for example). An amine is a base, and not formally derived from an acid, but from ammonia. It has the general formula $\ce{NR3}$, with R being H or any organic rest except X=O (X = C, S, etc.) or any other rest derived from an acid. So amides and amines are different classes of compounds. Here are examples for amides of a carboxylic acid, a sulfonic acid (sulfonamide), and an amine (from left to right):



The compound from the video that you have described is diethyl amine. You can formally derive it from ammonia by substituting two hydrogens with ethyl groups: