Metal carbonyl bonding
Carbon monoxide bonds to transition metals using "synergistic π* back-bonding." The bonding has three components, giving rise to a partial triple bond. A sigma bond arises from overlap of the nonbonding (or weakly anti-bonding) sp-hybridized electron pair on carbon with a blend of d-, s-, and p-orbitals on the metal. A pair of π bonds arises from overlap of filled d-orbitals on the metal with a pair of π-antibonding orbitals projecting from the carbon atom of the $\ce{CO}$. The latter kind of binding requires that the metal have d-electrons, and that the metal is in a relatively low oxidation state ($&lt;+2$) which makes the back donation process favorable. 
            

As electrons from the metal fill the π-antibonding orbital of $\ce{CO}$, they weaken the carbon-oxygen bond compared with free carbon monoxide, while the metal-carbon bond is strengthened. Because of the multiple bond character of the $\ce{M-CO}$ linkage, the distance between the metal and carbon atom is relatively short, often $&lt; 1.8~\mathrm{Å}$, about $0.2\ \mathrm{Å}$ shorter than a metal-alkyl bond.