The dissociation of hydrogen on UO2 and PuO2 surfaces: Homolytic or heterolytic?
This reference$\ce{^{[1]}}$ shows what can happen even in a single oxide, in this case magnesia, with different metal environments.



Magnesia is, of course, strongly ionic, so the dissociation of hydrogen to form $\ce{O^{2-}-H^+}$ and $\ce{Mg^{2+}-H^-}$ on the surface might well be expected.  Putting the magnesia as a thin film on silver does not change this.  But on gold the hydrogen dissociates in a redox fashion, forming only $\ce{O^{2-}-H^+}$ as the electrons are injected into the gold.  The lowered Fermi energy of the gold causes this transfer as the electrons "fall" into the lower energy state.  It's an example of gold acting as an electronegative element, as it does in compounds such as $\ce{CsAu}$, ultimately caused by the effects of relativistic mechanics on the electron structure of gold.

In the case of bulk uranium and plutonium dioxides, electron donation or withdrawal must come from the oxide itself.  With uranium (IV), the 5f orbitals are at relatively high energy, and where they have electrons those electrons are readily available for bonding and for donation -- but conversely, empty 5f orbitals are relatively poor electron acceptors.  So we get metal hydride formation like the $\ce{Mg^{2+}-H^-}$ bonds in plain magnesia or magnesia/silver.

With plutonium in the same +4 oxidation state, enough increased effective charge and orbital contraction have occurred to make the plutonium 5f subshell a better electron acceptor, making the $\ce{O^{2-}-H^{+}}$ bonding mode more favorable.

References:


Hsin-Yi Tiffany Chen, Livia Giordano, and Gianfranco Pacchioni, "From Heterolytic to Homolytic H2 Dissociation on Nanostructured MgO(001) Films As a Function of the Metal Support", J. Phys. Chem. C, 2013, 117, 20, 10623–10629.


2.
Chemical Forms of Uranium". Argonne National Laboratory. Archived from the original on 22 September 2006. Retrieved 18 February 2007.  Link