How to find the mass of a solute given a mass fraction?
In a $20\%$ solution of $\ce{CuSO4}$ we have $\pu{20 g}$ of $\ce{Cu}$ and $\pu{80 g}$ of $\ce{H2O}$. Then

in every $\pu{259.6 g}$ $\ce{CuSO4 * 5 H2O}$ we have $\pu{159.6 g}$ $\ce{CuSO4}$,

so for every $x~\pu{g}$ $\ce{CuSO4 * 5 H2O}$ we have $\pu{20 g}$ $\ce{CuSO4}$

$$x = \pu{31.87 g}$$