If two electrons move up to a higher energy level in an atom, is it considered excited?
http://physics.nist.gov/PhysRefData/Handbook/Tables/germaniumtable5.htm 
Energy levels of a neutral germanium atom 
https://www.webelements.com/germanium/orbital_properties.html 
Middle, electron binding energies for germanium

It will certainly be in one of its excited states, yes, probably followed by an Auger cascade.


Label   Orbital   eV 
K       1s       11103 
L I     2s       1414.6 
L II    2p1/2    1248.1 
L III   2p3/2    1217 
M I     3s       180.1 
M II    3p1/2    124.9 
M III   3p3/2    120.8 
M IV    3d3/2    29.8 
M V     3d5/2    29.2