Are phenyl and allyl groups in prop-2-enylbenzene coplanar?
Probably not
Part of the problem with the question is geometry. Any two points always form a plane. What I suspect you mean is &quot;is the allyl double bond in the same plane as the benzene ring?&quot; in which case the answer is probably not.
To make the situation clearer here is a different numbering of the atoms in the allyl benzene molecule:

The question I think you intended is whether the 2* and 3* bond is in the same plane as the benzene ring.
There is no chemical or geometric reason why it would be. the 1-1* bond and the 1-2 bonds will freely rotate so there is no bond-related force driving the orientation of the 2-3 double bond. to illustrate here is a 3D view of one possible configuration:

I say one possible configuration as it is likely that the barrier to rotation of those two bonds is small and, at room temperature in the liquid, the molecule will explore all the possible configurations (it might be different in a solid crystal where packing forces between units might lead to one being favoured).
In short: there is no reason to suppose the double bond and the benzene ring will be in the same plane because the two single bonds connecting it to the ring will freely rotate.