Unsure whether this classification of Volatile Organic Compound and/or Particulate Matter is correct
2-Acetylaminofluorene is a solid, mp 192-196 C. It satisfies the definition of being a VOC by virtue of being a compound of carbon, not excluded by the definition. It could be fine enough to be classified as PM 2.5 or 10 if it is powdered; more information would be necessary about the source of the compound. It is also carcinogenic, but that does not appear to be involved in the questionnaire.
Chloramben can be looked up and is also a solid with a high melting point: a VOC and possibly a PM.
Hydrazine is only dangerous, but not a VOC, and a liquid with a bp of 114 C. Not a PM. I don't think a spray of droplets would qualify as a PM; they would just evaporate.
Diisocyanates: VOCs for sure. Hazardous for sure. If you allow a pot of diisocyanates to evaporate, that's all: no PM. However, I can imagine a source of sprayed diisocyanates (in a paint?) that would result in polymerized particulate matter: then it could be a PM. Thus the classification would depend on the source of the material - the environment and the application.
Polycyclic aromatic compounds: most often encountered in smoke from various sources: VOC for sure, probably also PM because they could be larger agglomerates than single molecules.
This could be a fun exercise for a chemist to look up and play with mentally, to get to know and understand a large number of chemicals. For a non-chemist, this could be very difficult.