How hot can Thermal Grease get?
Since most thermal greases are ceramic and/or metal suspended in a silicone or organic oil, the temperature the grease remains stable at will likely primarily be determined by the properties of that oil -- either its ease of evaporation, or decomposition temperature (or, I suppose, its flashpoint, but that seems unlikely).

As Ben Norris says in the comment above, your best bet is to contact the manufacturer or check their data sheets: for common CPU uses, most manufacturers will give you stable and extreme temperature ranges which are likely to be fairly conservative (for example, here), and they may be able to help with more esoteric data if you're using it for other purposes.