Positive deviation from ideal behaviour
If in a binary solution of two components A and B, the interaction between unlike components A-B is weaker than the interaction between the like components A-A and B-B, then it means that in such solutions molecules of A (or B) will find it easier to escape in the state A-B, than when they are in their pure states (A-A or B-B). It means that molecules of A (or B) will find it easier to escape from the A-B form.

This will result in having greater vapour pressure of each component of the solution than expected on the Basis of Raoult's law, and hence the total vapor pressure will also be higher than in the case of ideal solution. Thus the deviation will be positive.

In such solution $\Delta_{mix}H$ is positive because energy is required to break A-A and B-B bonds. For such solutions, the dissolution process is endothermic, i.e, the solubility will increase with temperature (Le Chatelier's principle) .

$\Delta_{mix}V$ is also positive because there is decrease in the magnitude of intermolecular forces in the solution, the molecules are loosely held, and therefore the volume of mixing increases.