Negative temperature as limiting case for two-level system
I think you would need to describe the derivative $\frac{\partial U}{\partial S}$ at that point, which should be infinity by your logic since the entropy is at a maximum with respect to internal energy ($\frac{\partial S}{\partial U}=0$). This is obtained using $$\frac{\partial U}{\partial S}=\frac{1}{\frac{\partial S}{\partial U}}$$