Why can't we fully exploit the environment after the first episode in Q-learning?
BlueTurtle's answer is good, but I'd like to add something.
Your question realistically has nothing to do with Q Learning, in fact, you can ask the same thing about just about any RL algorithm. In fact, even in multi-armed bandits, you can easily see why your proposed method is suboptimal (please don't interpret this as a criticism, because I think your question is a very natural one). My suggestion to you is to read up on multi-armed bandits since they're much simpler to analyze. I think even the Sutton and Barto book deals with your proposed method explicitly, and mathematically proves that other strategies are better.