What's with this anomaly in this sounding (the CAPE and CIN readings)?
Your screenshot lists the raob as station 72357 on 2013-06-01 00Z.  Station 72357 is OUN and the sounding for that day time is available at the SPC sounding archive.



The SPC sounding analysis shows 3351 J kg$^{-1}$ CAPE and -76 J kg$^{-1}$ CIN for surface parcels.

My speculation for your anomolous non-physical values of CAPE and CIN is that the algorithm used in that software perhaps doesn't handle the lack of stratopheric data well.  The calculation of CAPE is the parcel buoyancy integrated from the level of free convection (LFC) to the equilibrium level (EL).  This sounding has no EL because the temperature data stops before the tropopause and never increases to equal the temperature of the lifted parcel.  A naive algorithm that does not take this into account would have issues calculating the CAPE and potentially produce undefined output.  I think that is the case in the software in your screenshot.