How much did the worst volcanic eruption in human history affect global temperature?
The largest volcanic eruption in human history was the Toba eruption on Sumatra about 75,000 years ago. There is still a huge lake, Lake Toba, in the crater. It dwarfed Thera, Krakatoa and Tambora. The Tambora  eruption on the Indonesian island of Sumbawa occurred in 1815, and was the largest eruption in historical times, also dwarfing the other two. It caused bad weather and lower temperatures around the world, including Europe, for about a year. The much larger Toba eruption must have had even more drastic short term effects lasting for years, but strangely enough doesn't seem to have had any major effects on the human population of South East Asia. It may have emitted enough CO2 to have made a minute difference to the ppm figure had there been anyone around able to measure it.