What processes produced the basalt columns of the Giant's Causeway?
These are basalts with columnar joints. Basalt is an igneous rock that forms when magma (liquid + crystals) erupts onto the surface as a lava flow or gets injected into cooler shallow crust and forms an intrusive dike or sill.  Because basalt cools quickly, basalt commonly contains glass as well as crystals. The physical properties of magma changes rapidly as it cools through the liquid-glass transition temperature. When a magma cools through the liquid-glass transition temperature, its specific volume decreases and its viscosity increases rapidly. The volume of the lava flow decreases (it shrinks) and it become more viscous and brittle. This creates stresses in the lava flow that eventually causes it to fracture. Columnar joints are fractures that have formed because the stress has exceeded the brittle strength of the rock.