A rough picture about the ground-level ammonia (NH3)
It seems difficult to find a reasonable proxy species for $\mathrm{NH}_3$, since its sources (primarily agriculture) are quite distinct from the sources of more commonly observed pollutants. Some observations of aerosol-bound $\mathrm{NH}_4^+$ might (or might not) be available, but due to the reasons you explain, it is non-trivial to infer the gas-phase $\mathrm{NH}_3$ concentration from the $\mathrm{NH}_4^+$ in aerosols.
There are papers about estimating atmospheric $\mathrm{NH}_3$ from satellite data, see for example here or here. These are for column-integrated and not surface $\mathrm{NH}_3$, however.