Using attributes to classify/cluster user profiles
Right now, I only have time for a very brief answer, but I'll try to expand on it later on.

What you want to do is a clustering, since you want to discover some labels for your data.  (As opposed to a classification, where you would have labels for at least some of the data and you would like to label the rest).

In order to perform a clustering on your users, you need to have them as some kind of points in an abstract space.  Then you will measure distances between points, and say that points that are "near" are "similar", and label them according to their place in that space.

You need to transform your data into something that looks like a user profile, i.e.: a user ID, followed by a vector of numbers that represent the features of this user.  In your case, each feature could be a "category of website" or a "category of product", and the number could be the amount of dollars spent in that feature.  Or a feature could be a combination of web and product, of course.

As an example, let us imagine the user profile with just three features:


dollars spent in "techy" webs, 
dollars spent on "fashion" products, 
and dollars spent on "aggressive" video games on "family-oriented" webs (who knows).


In order to build those profiles, you need to map the "categories" and "keywords" that you have, which are too plentiful, into the features you think are relevant.  Look into topic modeling or semantic similarity to do so.  Once that map is built, it will state that all dollars spent on webs with keywords "gadget", "electronics", "programming", and X others, should all be aggregated into our first feature; and so on.

Do not be afraid of "imposing" the features!  You will need to refine them and maybe completely change them once you have clustered the users.

Once you have user profiles, proceed to cluster them using k-means or whatever else you think is interesting.  Whatever technique you use, you will be interested in getting the "representative" point for each cluster.  This is usually the geometric "center" of the points in that cluster.

Plot those "representative" points, and also plot how they compare to other clusters.  Using a radar chart is very useful here.  Wherever there is a salient feature (something in the representative that is very marked, and is also very prominent in its comparison to other clusters) is a good candidate to help you label the cluster with some catchy phrase ("nerds", "fashionistas", "aggressive moms" ...).

Remember that a clustering problem is an open problem, so there is no "right" solution!  And I think my answer is quite long already; check also about normalization of the profiles and filtering outliers.