Outlier detection for Disk Space Usage
Given the specific context of detecting abnormal changes in the amount of free space, I'd suggest that you use the variation over time instead of the raw amount. For instance: 

date                   free_space  variation
2019-05-15 09:00:00    102.65      NA
2019-05-15 09:05:00    102.69      0.04
2019-05-15 09:10:00    103.11      0.42
2019-05-15 09:15:00    102.58      -0.53
2019-05-15 09:20:00    102.55      -0.03


Whatever method you use, the variation is a much more relevant information to detect an unusual change than the raw size. You could also use a time window, e.g. calculate the variation over the last 30 minutes.

Personally I would simply use a heuristic for something like this: if the absolute value of the variation is higher than a threshold then label as outlier. The threshold could be a percentage of the size of the disk, e.g. 5%.