why accuracy on training dataset is 100% using random forest caret , does it indicate overfitting?
Yes, those accuracies dont say anything.

You have overfitted to 310 data points which is pretty easy using RF. The fact is that you said you "predicted" on training data. Well, when you learned on training data and you ask prediction for points you already gave the model it simply knows them.

You need to use a cross validation technique (here i propose Leave-One-Out technique as you dont have much data points). RF is more robust than DT towards overfitting, but that is not applied to this setting. Here you getting an exam in which you ask a question you already gave to the student. He just simply knows the answer.