Breadalbane is also near the start of the Federal Highway . This branches off the Hume Highway just south of Goulburn and goes to Canberra in the Australian Capital Territory . Breadalbane is also located nearby to the start of the Federal Highway which branches off the Hume Highway just south of Goulburn and heads directly towards Canberra in the Australian Capital Territory , and the capital city of Australia where the Commonwealth Federal Parliament sits .