The first step to becoming a master electrician is to join an electricians union or guild as an trainee or enroll at a local trade school or college. There you will learn how to become an electrician the right way.To graduate from trainee electrician status you must complete your course and spend 9,000 hours apprenticing a journeyman or master electrician. This will teach you the theory of electrician work as well as giving you the practical skills you need to work.he first step to becoming a master electrician is to join an electricians union or guild as an trainee or enroll at a local trade school or college. There you will learn how to become an electrician the right way.