It looks like in Windows 10 Settings, Devices you can't change the default printer. (EDIT-In fairness, it is there but just hard to find. Click on Settings, Devices, scroll all the way down and you will see the link to Devices and printers where you will go to the Devices and Printers control panel.).t looks like in Windows 10 Settings, Devices you can't change the default printer. (EDIT-In fairness, it is there but just hard to find. Click on Settings, Devices, scroll all the way down and you will see the link to Devices and printers where you will go to the Devices and Printers control panel.).