Bolivia is home to many distinctive famous places such as the world's highest capital, the world's highest city and the world's most dangerous road.isitors can enjoy buying magic potions at La Paz's famous Witches Market, exploring the maze of canyons at nearby Moon Valley or taking their chances on the World's Most Dangerous Road, which begins in La Paz and descends 11,000 feet in 40 miles through the Andes Mountains to the Amazon River Basin.