Angelina Jolie and Brad Pitt Are Married! Playing Angelina Jolie and Brad Pitt Are Married! Angelina Jolie and Brad Pitt have finally tied the knot! The A-list stars got engaged in April 2012 and two years later, they're officially husband and wife, the family confirmed in a statement. The couple exchanged vows on their property Chateau Miraval in France on Saturday, August 23.