Air India 24 Hour Customer Care Number, Toll Free Helpline Number Air India Customer Care Number: 1800-180-1407 (Toll Free) (For any information regarding Air India Airlines' enquiries, support, flights status, Frequent Flyer and other related issues, the customers can reach to customer care team which is available 24 hours a day, 7 days a week.) These phone number is accessible from all landlines and mobile phones in the country.