Sodium vapor process

The sodium vapor process (occasionally referred to as yellowscreen) is a photochemical film technique for combining actors and background footage. It originated in the British film industry in the late 1950s, and was used extensively by Walt Disney Productions in the 1960s and 1970s as an alternative to the more common bluescreen process. Wadsworth E. Pohl is credited with the invention or development of both of these processes (Patent US3133814A ), and received (with Ub Iwerks and Petro Vlahos) an Academy Award in 1965 for the sodium vapor process used in the film "Mary Poppins".
The process is not very complicated in principle. An actor is filmed performing in front of a white screen that is lit with powerful sodium vapor lights. Such light glows in a specific narrow color spectrum that falls neatly into a chromatic notch between the various color sensitivity layers of the film so that the odd yellow color does not register on the red, green or blue layers. This allows the complete range of colors to be used not only in costumes, but also in makeup and props. A camera with a beam-splitter prism is used to expose two separate film elements. The main element is regular color negative film that is not very sensitive to sodium light, and the other a fine-grain black-and-white film that is extremely sensitive to the specific wavelength produced by the sodium vapor.
This second film element is used to create a matte, as well as a counter-matte, for use during compositing on an optical printer. These complementary mattes allow the various image elements to be cleanly isolated, so that as they are re-exposed onto a single, fresh piece of negative, one at a time and in jigsaw fashion, the various images do not show through one another (as they would using simple double exposure). Acquiring the matte film element (as a first-generation original) at the same time as the live action makes a much better fit during optical printing, because it requires fewer separate, duplicate film generations than does bluescreen (though both processes degrade the image and introduce more "error" to the resulting matte) in the process of achieving sufficiently dense mattes. This increased accuracy ultimately renders the matte "lines" almost invisible, though as with bluescreen, its use may be signaled by hard separation or mismatched coloration and contrast between elements, or in this case, a telltale white/yellow fringe.
Disney made one sodium vapor camera. The camera was a retired Technicolor three-strip camera modified to use two films, and used normal lenses for the conventional 1.85:1 aspect ratio. First developed in 1932, Technicolor three-strip cameras ran three rolls of black-and-white film past a beam splitter and a prism to film three strips of film, one for each primary color. In 1952, Eastman Kodak introduced its color negative film, Eastmancolor, which led to Hollywood's discontinuation of Technicolor cameras in 1954. 
At the time of its use, the sodium process yielded cleaner results than did bluescreen, which was subject to noticeable color spill (a blue tint around the edges of the matte). The increased accuracy allowed for the compositing of materials with finer detail, such as hair or Mary Poppins' veiled hat. It was also useful that the "sodium yellow" light (and its removal via the matte) had a negligible effect on human skin tones. As the bluescreen process improved, the sodium vapor process was abandoned, its screen and lamps monopolizing huge studios and incurring a higher cost.
The first use of the process was in the J. Arthur Rank Organisation's "Plain Sailing" in 1956. It was used in Disney's short Donald and the Wheel, and the films "The Parent Trap", "Mary Poppins" and "Bedknobs and Broomsticks". It was also used for the Ray Harryhausen film "Mysterious Island", produced by Columbia Pictures. Alfred Hitchcock's "The Birds" (produced by Universal Studios) used yellow screen, under the direction of Disney animator Ub Iwerks, in traveling matte shots with birds' rapidly fluttering wings. 
The process was used in the 1970s for scenes in "Island at the Top of the World", "Gus", "The Apple Dumpling Gang", "Freaky Friday", "Escape to Witch Mountain", "Pete's Dragon" and "The Black Hole". Its last known use was in the 1990 film "Dick Tracy".