Sa Poblacion nagpupuon ini hale sa Unibersidad de Sta. Isabel - Pili Campus hasta sa Pili National High School. Digdi mahihiling an Philippine Computer Foundation College, Pili Capital College Inc., Pili Central School, Pili West Central School, Pili Parochial School, Blessed Name of Mary Learning School Inc., Camarines Science Oriented High School, Montessori Childrens House of Learning, Evangelical Christian School, asin an Yobhel Christian Academy.