, porous silicon achieved by anodization of a silicon wafer offers physical properties , which can not be observed in case of bulk silicon . microporous silicon , which exhibits interconnected channels with diameters between 2 and 4 nm , shows a strong luminescence in the visible   caused by quantum confinement effects . moreover , porous silicon possesses the ability to biodegrade within body fluids   but is also known as a bioactive material , two properties which play opposing roles . both properties are of interest for medical applications as drug delivery   or tissue engineering . concerning the creation of new materials for scaffolds and bone substitutes , one requirement is the hydroxyapatite growth on the surface by exposing to body fluids , which can also be observed on oxidized porous silicon , which is more stable in simulated body fluids than pure porous silicon . magnetic nanostructures play a crucial role in ferrofluids , high density magnetic data storage , catalysis   and also biomedical applications   as for example drug targeting . the fabrication of magnetic isolated nanoparticles is quite difficult to reach because the particles oxidize easily when using metals due to the large surface area in relation to their volume . the monodisperse nanoparticles utilized in this work are prepared by high temperature decomposition of an organic precursor in the presence of oleic acid [ 12 - 15 ] . the incorporation of anti - cancer therapeutics , analgetics , proteins and peptides as well as the use of porous silicon as dietary supplement has been taken into consideration . drug delivery with porous silicon is under discussion in employing particles , films , chip implants and composite materials , whereas microparticles are under great investigation because they are compatible to existing drug delivery concepts . exploration of porous silicon for utilization in cancer treatment , especially for brachytherapy has been enforced by psimedica inc . . the combination of porous silicon with magnetic particles , namely fe3o4 , and additional loading with a molecular payload is of interest for controlled transport in applying an external magnetic field . the loaded molecules ( enzymes ) can be transported and subsequently released in an appropriate solution . the fabrication of a porous silicon double - layer of different pore - size is used for loading with magnetite nanoparticles and a small amount of liquid . the samples are heated within an oscillating magnetic field , which is enabled by the superparamagnetic magnetite nanoparticles ( ~10 nm in size ) . in the present work , porous silicon templates with oriented pores grown perpendicular to the sample surface are used to deposit magnetic nanostructures ( electrodeposited or immersed ) as a three - dimensional arrangement by self - assembly . the combination of a semiconductor with magnetic materials leads to a hybrid system with tailored - specific magnetic properties but is also of interest for possible biomedical applications . the aim of the present work is to give an overview of the versatility of porous silicon and the advantage to combine this semiconductor material with a magnetic metal . the fabrication of porous silicon ( ps ) is carried out by anodization of an ( 100 ) n - type silicon wafer ( 10 cm ) in aqueous hydrofluoric acid solution . all porous silicon samples investigated in the frame of this work are anodized in a 10 wt% aqueous hf - solution . oriented growth and quasi - regular arrangement of the pores is achieved by adjusting the electrochemical parameters , which is described in detail in a previous publication . small side - pores , which can not be suppressed in this morphology regime occur in ( 111 ) direction . the length of these side - pores does not exceed the pore - radius , which ensures that the main pores are clearly separated from each other . the achieved silicon templates are utilized on the one hand for electrochemical deposition of a ferromagnetic metal and on the other hand to infiltrate nanoparticles . the precipitation of metal nanostructures by pulsed electrodeposition technique is performed in using an adequate metal salt solution . in case of ni deposition into the pores the electrolyte is composed of 0.2 m nicl2 and 0.1 m niso4 , known as watts electrolyte . the precipitation of the metal nanostructures is carried out with current densities between 15 and 30 ma / cm . the metal deposition into porous silicon is a cathodic process reducing the metal salt ions to metal ( e.g. , ni + 2e = ni ) . the electrodeposition process concerning doped semiconductors is not well understood so far but it can be said that due to higher field strength at the pore tips and concomitant dielectric breakdown of the oxide layer , which covers the pore - walls , starts at the pore bottom . the geometry and spatial distribution of the metal precipitates within the porous layer can be adjusted by the process parameters ( e.g. , current density and pulse duration of the current ) resulting in samples with tailored magnetic properties . the precipitates can be varied between sphere - like particles of about 60 nm , ellipsoids of a few hundred nanometres ( aspect ratio ~10 ) and needle - like structures reaching a length of a few microns ( aspect ratio ~100 ) by reducing the pulse duration from 40 to 5 s. magnetite nanoparticles have been fabricated by high temperature decomposition of iron organic precursors following previously reported works . particles of an average size of 9 nm have been obtained after performing the process steps described by s. sun . the fabrication has been carried out at the institute of material science at the csic in madrid . these particles , which are quite monodisperse   have been mixed with hexane and oleic acid . the resulting magnetic solution has been infiltrated by immersion into the pores of the porous silicon matrices . the two kinds of semiconductor / metal nanocomposites are characterized by electron microscopy ( sem , tem ) and magnetic measurements performed by squid - magnetometry , which complement the investigations to figure out the different behaviour of the two types of specimens ( electrochemically deposited ferromagnetic metals , infiltrated magnetite nanoparticles ) . morphological details of the porous silicon template regarding the pore - arrangement , porosity and pore - size as well as of the metal - filled specimens with respect to the geometry and spatial distribution of the precipitated metal nanostructures are gained from the analysis of scanning electron microscopy ( sem ) investigations . figure 1 shows a cross - sectional survey of a typical porous silicon layer exhibiting straight pores grown perpendicular to the wafer surface with an average diameter of 55 nm . a top - view image of the quasi - regular pore - arrangement can be seen in the inset . analysis of the top - view picture by image processing gives a porosity of about 60% . the precipitated metal nanostructures are investigated in using the back scattered electrons to get element - sensitive information . furthermore , the nanocomposite is characterized by transmission electron microscopy ( tem ) , which allows to figure out some interfacial features of the samples . scanning electron micrograph of the cross - section and the top - view ( inset ) of a porous silicon sample with a porosity of about 60% achieved by self - organization investigating the ps / metal interface by tem one can say that the pore - walls of the ps - matrix are covered by an oxide layer of about 5 nm ( fig . ftir - spectroscopy also shows the presence of oxide in case of aged porous silicon . as - etched porous silicon samples that are hydrogen terminated show three typical absorption peaks around 2,100 cm due to si  hx . ps / metal nanocomposite specimens also show an oxygen content , which arises due to oxidation during the deposition process . in fig . . not all pores of the considered membrane are filled with a ni - particle because the ni - structures are deposited randomly within the pores , and one pore is not completely filled between pore tips and surface . therefore , at a certain level of the porous layer not every pore contains a particle . furthermore , the preparation technique by focused ion beam ( fib ) provokes the loosening of particles . 4 ) , which likely arises after the preparation by focused ion beam . on the other side , magnetization measurements of ni - filled samples do not show an exchange bias effect ( not shown here ) , which means a shift of the hysteesis loop on the abscissa . this result indicates that the ni - oxide coverage of the nanostructures is not antiferromagnetic . high resolution tem image of porous silicon , showing an oxide layer of about 5 nm at the pore - walls zero - loss tem image showing ni - particles within the pores of the porous silicon matrix . the preparation of the membrane for tem investigations has been carried out by focused ion beam eels line - scan over an individual embedded ni - particle . ni and oxygen have been identified , whereas the oxygen peak at the edges is a combination of both , nio as well as the oxygen covering the pore - walls of the ps - matrix because the two materials touch considering such nanocomposites prepared by electrodeposition of a metal from an adequate metal salt solution , the specific metal precipitation can be influenced by the electrochemical parameters and therefore samples with desired magnetic properties can be achieved . coercivities , magnetic remanence and magnetic anisotropy strongly depend on the geometry of the precipitated nanostructures as well as on their spatial distribution within the porous layer . both features can be adjusted mainly by varying the deposition current density and the frequency of the applied current . considering samples with deposited ni - particles , coercivities between 500 and 1,000 oe are obtained in case of easy axis magnetization whereas the magnetic anisotropy between the two magnetization directions , perpendicular and parallel to the sample surface , typically is in the ratio 2:1 . due to the fact that the magnetocrystalline anisotropy of ni is small , the main contribution stems from the shape of the deposited metal structures . in average , the deposited ni - structures of the considered sample offer a diameter of about 50 nm and a length of about 150 nm . the magnetic anisotropy of an individual nanowire is dominated by shape anisotropy ( 1/2 0ms  10 j / m ) . in case of deposited ni - particles , coupling between the particles so , it is reasonable that the precipitated ni - particles dipolarly coupled within one pore leading to a quasi-magnetic chain  which enhances the anisotropy . the achieved system is of interest because of the adjustable magnetic properties by fabrication parameters but also because of the material combination of silicon compatible with today s process technology and a ferromagnetic metal . ps - matrices containing infiltrated magnetite nanoparticles form a composite material are of interest due to the magnetic behaviour but also because of the biodegradability of both materials . the transition between the two kinds of magnetism depends on the particle size but also on the interaction between the particles , which means their distance . thus , the interaction between the nanoparticles can be influenced on the one hand by the thickness of the oleic acid coating and on the other hand by the concentration of the solution of the particles . figure 5 shows the temperature - dependent magnetization for two different concentrations ( ratio 1:2 ) of the particle solution . for decreasing concentration , the blocking temperature tb is shifted to lower temperatures due to less interaction between the particles as a consequence of their greater distance . in case of superparamagnetic , non - interacting particles of 9 nm in size tb can be estimated around 6 k in using the thermal energy being k the anisotropy constant , ms the saturation magnetization , hc the coercive field and v the volume of the individual particles . zero field cooled / field cooled ( zfc / fc ) measurements show a shift of the blocking temperature tb to lower temperatures with decreasing concentration , which can be explained by less interaction between the particles.tb indicates the transition between ferro- and superparamagnetic behaviour . the broadening of the peak is not caused by inhomogeneous particle size distribution but by magnetic interactions between the particles . the initial concentration of the particle solution has been diluted with hexane till a 50% solution of the initial one has been reached in contrast , the experimental gained tb lies at higher temperatures between 75 and 130 k. furthermore , a broadening of the zfc - peak with smaller particle distances can be observed . both are caused by increasing magnetic interactions between the particles in dependence on their average distance . porous silicon is a versatile material applicable in many fields of nano - research . in the present work , it is used as template material to embed magnetic nanostructures . on the one hand , ferromagnetic metals are electrochemically deposited within the pores of the matrix leading to a semiconducting / magnetic nanocomposite system . this nanoscopic hybrid material is of interest because of the silicon base material , which makes it applicable in today s microtechnology and because of the adjustability of its ferromagnetic properties as coercivity , remanence and magnetic anisotropy . the geometry , which can be modified between sphere - like particles and needle - like structures as well as the spatial distribution of the precipitated metal nanostructures within the porous layer is tunable by the electrochemical process parameters resulting in specimens with tailored magnetic properties . on the other hand , fe3o4 the latter system exhibits ferro-/superparamagnetic properties , which can be influenced by varying the nanoparticles in size and their distance , which means by the coating of the particles but also by the concentration of the solution . due to the low toxicity of magnetite as well as of mesoporous silicon , it is a promising candidate for biomedical applications as drug delivery and drug targeting . all in all porous silicon / metal composites are of great interest in basic research but they are also promising for various magnetic and biomedical applications . m. p. morales and a. g. roca work was supported by the ministerio de ciencia e innovacion through nan2004 - 08805-c04 - 01 project . h. krenn from the institute of physics at the karl franzens university graz to make available the squid - magnetometer and m. dienstleder from the institute for electron microscopy at the university of technology graz for focused ion beam preparation .
a semiconductor / metal nanocomposite is composed of a porosified silicon wafer and embedded ferromagnetic nanostructures . the obtained hybrid system possesses the electronic properties of silicon together with the magnetic properties of the incorporated ferromagnetic metal . on the one hand , a transition metal is electrochemically deposited from a metal salt solution into the nanostructured silicon skeleton , on the other hand magnetic particles of a few nanometres in size , fabricated in solution , are incorporated by immersion . 
 the electrochemically deposited nanostructures can be tuned in size , shape and their spatial distribution by the process parameters , and thus specimens with desired ferromagnetic properties can be fabricated . 
 using magnetite nanoparticles for infiltration into porous silicon is of interest not only because of the magnetic properties of the composite material due to the possible modification of the ferromagnetic / superparamagnetic transition but also because of the biocompatibility of the system caused by the low toxicity of both materials . 
 thus , it is a promising candidate for biomedical applications as drug delivery or biomedical targeting .