organoselenium and organotellurium compounds are well known for their antimicrobial 
 [ 14 ] , anti - inflammatory [ 5 , 6 ] , and biocidal activities . organoselenium compounds have found applications as oxygen transfer reagents in organic , and organometallic synthesis , and as oxygen - donor ligands in main and transition metal complexes . organoselenium and organotellurium compounds [ 811 ] the electrochemical behavior of diphenyl and bis(p - anisyl ) tellurium dichloride , bis(p - anisyl ) telluride , diphenyl ditelluride , and aromatic diselenides - ditellurides and diphenyl selenide have been studied on the rate of rotation electrode , the mercury electrode , and the platinum grids in aprotic solvents ( ch2cl2 , dmf , ch3cn ) [ 6 , 7 ] . there are a lot of publications concerning the electrochemistry of organotellurium compounds [ 1223 ] . aromatic selenides are relatively stable toward reduction . the electrochemical behavior of the diaryl selenium dichlorides and diaryl selenides has not been studied on a stationary electrode yet . however , a comparative study of the electro reduction of bis(p - anisyl ) and bis(p - ethoxyphenyl ) selenium dichloride ( ar2secl2 ) , bis(p - anisyl ) , and bis(p - ethoxphenyl ) selenide ( ar2se2 ) was carried out in acetonitrile ( an ) . in this work , electrochemical experiments were carried out by a three - electrode system . the organometallic selenium compounds were prepared according to the procedure described in the literature [ 25 , 26 ] . the selenium was estimated according to the known reported method . in this work , a stock solution of 0.5 mm ar2secl2 and supporting electrolyte ( tetrabutylammonium tetrafluoroborat ; tbafb ) in an was prepared . an was obtained from aldrich chemical co. ( hplc grade ) and was transferred with a syringe from the original container into the electrochemical cell . the diaryl diselenides are sensitive to light ; the electrolysis solutions were protected by an aluminum foil . the progress of electrolysis was monitored by recording uv - vis spectral changes with applying a potential ( epc ) at peak values . for this purpose 2025 ml of the electrolyzed solution was transferred into the quartz cell of the measurement container from the working compartment of the electrolysis cell and then corresponding spectra were recorded . the spectral changes were continuously monitored at different time intervals to detect the wave length region in which the uv - vis absorption for intermediate products was generated . when the reduction peak ( ic ) disappeared , electrolysis was stopped and the electrolyzed solution was transferred from cell into the measurement container . the products were further characterized by using h nmr , ft - ir , and mass spectra . the working and counter electrodes were made of platinum foil ( 4 cm ) ; the same electrode was used in cyclic voltammetry experiments . controlled and the scanning potentials were supplied by potentioscan wenking model pos73 and recording coulometric experiments were made in an improved three - compartment cell with high a / v ratio ( electrode area / solution volume ) and good geometry , enabling homogeneous potential distribution on the working electrode and thus fast and precise measurements of the products . the ft - ir spectra were recorded on a matson-1000 , ft - ir spectrophotometer using kbr pellets . perkin - elmer uv-1601pc spectrophotometer and mass spectra on jeol jsm-6400 were used to record uv - vis spectral changes during electro reduction process . the results of the voltammetric studies are shown in figure 1 . in concentrations up to 2 mm , three reduction waves appeared on the cyclic voltammograms , and these reactions which were linearly proportional to the ar2mcl2 concentration were controlled by the diffusion rate of ar2mcl2 . the first cathodic peak ( epc =   0.26 v ) and the first anodic peak ( epa =   0.32 v ) were found to be reversible with ep = 0.06 v and the ratio of cathodic to anodic peak currents which corresponds to a single one - electron process ( ipc / ipa  1 ) . involved in the electroreduction was determined by regression method of the current - time curve figure 3 . the value of n , calculated from the net charge passing through the solution was found to be 3.8  0.2 in an . the ratio of currents corresponding to the first and second peaks , respectively , was in all cases close to 1 : 1 , and the total amplitude of both waves always gave a current value   corresponding to two - electron process . the results of these experiments were interpreted according to the method of nicholson and shain . it was found that the dependence of ipc / c on the concentration ( figure 4 ) or potential scan rate ( figure 5 ) is similar to that suggested by nicholson and shain   and liftman - albeck for such ecec reaction . at high scan rates , the whole cathodic waves showed lower negative cathodic potential values ( table 2 ) . the chloride ions , formed during the reduction of the dichloride were adsorbed on the platinum electrode as reported . two electrons participate in the reduction of one molecule of dichloride and other two electrons in the reduction of the supporting electrolyte . the product of the two - electron reduction of selenium organometallic formed a dirtily - yellow solution in   color , its state of   aggregation in the solution has established and its formulation is ar2m - mar2 . therefore , the electron reduction reactions of bis(p - anisylphenyl ) or bis(p - ethoxyphenyl)selenium dichloride can be formulated by the following equations:(1)ar2secl2+e    ar2secl*+cl,(2)ar2secl+ar2secl2+e  ar2se(cl)se(cl)ar2+cl , 
 while   at higher 
  cathodic potentials : 		 ( 3)ar2se(cl)se(cl)ar2 + 2ear2se - se  ar2 + 2cl. 
		 under the same conditions , three reduction peaks ( a , b ,   and c ) which are corresponding to ( 1 ) , ( 2 ) , and ( 3 ) , respectively , and also two oxidation peaks ( a , b ) were observed . the above mechanism is supported by the following experimental results . in the far - ir region the reduction compounds exhibited n(c - se ) 460500 cm , n(ar - o - ch3 ) 11501060 cm , n c = c(aromatic ) 16601450 cm , respectively . no signal were recorded at ns(se - cl ) 275245 cm and nas(se - cl ) 245255 cmhnmr spectra of the reduction compounds showed various signals at wave lengths of d 6.76.9 ppm ( aromatic hydrogen ) and at d 3.63.8 ( alkyl hydrogen ) . mass spectrum ; showed m / e 386 [ ( c2h5o)2c6h4secl2 + ] ; 149 , 148 , 147 ( secl2 + ) ; 280 - 281 [ ( c2h5o)2c6h4secl)+ ] ; 166168 ( c2h5oc6h4)+ ; 77 ( c6h4)+ . the obtained radicals ( ar2secl ; ar2se ) ( in the first and second step of the reduction of diaryl selenium dichloride ) were short lived . the chloride ions formed during   the reduction of the bis aryl selenium dichloride were adsorbed on the electrode as shown in figure 1(c ) . the slope of log  ip versus log  v for the first value of the reduction peak of ar2secl2 ( a in figure 5 ) was obtained as 0.8 . however , this value was decreased because of adsorption . it was found that the dependence of the value ipc / ipa both for the peaks of the selenium dichloride ( a and b in figure 5 ) on the rate of potential scan ( v ) and the dependence of ipc on v are similar to those suggested by nicholson and shain for such reactions . the initial positive scans show a single anodic peak c at approximately 0.52 v and three cathodic peaks ( a , a ,   and b ) are also observed at potentials of 0.15 v , 0.30 v , and 0.80 v ( figure 8) . peak a is most probably due to the reduction of selenium deposited on the working electrode and peak b ( 0.80 v in figure 6 and 1.5 v in figure 8) is most probably due to the reduction of bu4n ion . this conclusion was supported by the fact , as shown in ( figure 6 ) , the continuous cycling between 0.80 v and 1.28 v leads to a resulting increase in mass of the product indicating that most of the deposited se(0 ) is not reoxidized . the small amplitude of peak values ( a , a in figure 6 ) confirms this indication . because of this reason , the electrode reactions of diselenides are followed by catalytic reactions of supporting electrolyte and chemical reactions in bulk   of the solutions . after the first cyclic voltammogram , the amplitude of the peaks ( a , a ) were decreased and then remained stable . the dependence of the peak currents of the waves on the scan rate is shown in figure 7 . the limiting currents of the waves of   ( c2h5oph)2se2 ( a in figure 7 ) and the waves of ( c2h5oph)2se2 at spe are linearly proportional to the concentration of diselenides ( b in figure 7 ) . the ic of the reduction peak ar2se2 is also linear with respect to the scan rate v ( mvs )   ( c and d in figure 7 ) , since the reduction process is diffusion controlled . during constant potential electrolysis at plateau potentials of the cathodic wave of ( c2h5oph)2se2 the limit current of the wave takes place as shown e in figure 7 ) this is due to the formation of selenide in the reduction of the diselenide which catalyses the reduction of the tetrabutylammonium cation of the supporting electrolyte . the metallic selenium produced as a result of this reaction is not readily oxidized . after reaction , the electrode was cleaned from the metallic selenium , the first cyclic voltammogram is given in figure 8 . the role of electrode material in the reduction pathway appeared to be important , especially in the case of the stationary electrode . these results point to a different reduction mechanism or to a remarkable shift of the redox potential of the intermediate compounds ar2se and ar2sebf4 , to lower negative values ( b in figure 8) . the above mechanisms were supported by the following experimental results :   in the oxidation and reduction of ar2se2 , always metallic selenium separated at the electrode surface ( a in figure 6 ) ; the first anodic peak of ar2se bf4 ( 0.33 v in ch3cn ) ( a in figure 6 ) and the second anodic peak of ar2se ( bf4)2 ( 0.80 v in ch3cn ) were observed only in the presence of bf4 ions in the solution ( b in figure 8) ; the peak currents of the oxidation peak of the ar2se2 and that of the reduction peak   of the selenides were controlled by diffusion rate of the 
		 corresponding organoselenium compound ( figure 9 ) ; support for the assumption that anodic and cathodic reactions are charge - transfer reactions followed by irreversible equation ( 4 ) electrochemical reactions and equation ( 5 ) chemical reactions is given by the results of the cyclic voltammetry experiments but we were not able to analyze these reactions ; the ratio between the diffusion currents of the two peaks is 1 : 2 with a total consumption of two electrons ; experiments have shown that the catalytic effect of the products se , ar2se , and ar2se(bf4)2 that were formed on the interface between the pt electrode and the electrolyte . as the thickness of metallic se increases , mass transfer to the electrode interface decreases . the electrochemical behavior of ar2secl2 and ar2se2 on the stationary platinum electrode was investigated by cyclic voltammetry and controlled - potential coulometry measurements . during the reduction of ar2secl2 at 0.52 v , a small amount of solid was precipitated at a total faradic efficiency of a few percent and was identified as a mixture of ar2se(bf4)2 and ar2se(cl)se(cl)ar2 . the solutions contain ar2se - sear2 in measurable amounts at higher cathodic potentials such as 1.15 v. metallic selenium was not separated at the electrode surface . metallic selenium separated at the electrode surface while using ar2se2 in the nonaqueous solution during both reduction and oxidation reactions .
the electrochemical behavior of ar2secl2 , and ar2se2 , ( ar : ch3oc6h5 ; c2h5oc6h5 ) in acetonitrile ( an ) containing tetrabutylammonium tetrafluoroborat ( tbafb ) as supporting electrolyte was studied on a stationary electrode ( spe ) . in order to elucidate the electrode reactions linear potential scan , cyclic voltammetry and controlled - potential coulometry were employed using a platinum electrode . 
 it is shown that ar2secl2 and ar2se2 are reduced and oxidized to ar2se , ar2se2ar2 , se , and ar2se(bf4)2 . 
 it is generally accepted that as final electrochemical reduction products , the corresponding ar2se , ar4se2 , and se were formed . 
 the disappearance of the diorganoselenium and selenide in the course of the coulometric experiments was validated by measuring the limiting current of the voltammetric waves at spe and uv spectrometry .