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Patent US8153196 - Coating compositions, articles, and methods of coating articles - Google PatentsSearch Images Maps Play YouTube News Gmail Drive More »Sign inAdvanced Patent SearchPatentsCoating compositions, articles, and methods of coating articles are provided. The coating compositions and methods provide abrasion resistant formable coatings when cured on a substrate. The articles can be formed after the coating compositions are applied to a substrate and cured....http://www.google.com/patents/US8153196?utm_source=gb-gplus-sharePatent US8153196 - Coating compositions, articles, and methods of coating articlesAdvanced Patent SearchPublication numberUS8153196 B2Publication typeGrantApplication numberUS 13/288,166Publication dateApr 10, 2012Filing dateNov 3, 2011Priority dateOct 12, 2004Also published asCA2583476A1, CN101072812A, EP1814930A2, EP1814930A4, US7265179, US8153197, US8158191, US20070104968, US20080014339, US20080145547, US20100310876, US20120049401, WO2006044340A2, WO2006044340A3Publication number13288166, 288166, US 8153196 B2, US 8153196B2, US-B2-8153196, US8153196 B2, US8153196B2InventorsRen-Zhi Jin, Andreas SchneiderOriginal AssigneeSdc Technologies, Inc.Export CitationBiBTeX, EndNote, RefManPatent Citations (50), Non-Patent Citations (8), Classifications (25), Legal Events (1) External Links: USPTO, USPTO Assignment, EspacenetCoating compositions, articles, and methods of coating articlesUS 8153196 B2Abstract Coating compositions, articles, and methods of coating articles are provided. The coating compositions and methods provide abrasion resistant formable coatings when cured on a substrate. The articles can be formed after the coating compositions are applied to a substrate and cured.
applying a coating composition to a formable plastic substrate having a primer disposed on the formable plastic substrate, wherein the coating composition comprises,
11. The process of claim 1 further comprising applying the primer to the formable plastic substrate prior to the step of applying the coating composition.
12. The process of claim 11, wherein the primer comprises a polyurethane dispersion based primer.
13. The process of claim 1, wherein the primer comprises a polyurethane dispersion based primer.
14. The process of claim 1, wherein the primer is modified with an ultraviolet light absorbing substance.
15. The process of claim 1, wherein the primer is modified with a radical scavenger.
16. The process of claim 1, wherein the epoxy functional silane is represented by the formula R3 xSi(OR4)4-x, wherein:
17. The process of claim 1, wherein a solvent component of the aqueous-organic solvent mixture comprises from about 40% to about 98% of the coating composition by weight.
18. The process of claim 1, wherein the at least one of the epoxy functional silane and the diol functional organopolysiloxane comprises from about 5% to about 93% of the coating composition by weight of the total solids.
19. The process of claim 1, wherein the multifunctional crosslinker comprises from about 7% to about 95% of the coating composition by weight of the total solids.
CROSS REFERENCE TO RELATED APPLICATIONS This application is a divisional of, claims priority to, and any other benefit of allowed U.S. patent application Ser. No. 12/852,213, filed on Aug. 6, 2010, entitled �COATING COMPOSITIONS, ARTICLES, AND METHODS OF COATING ARTICLES,� which is a divisional of, claims priority to, and any other benefit of abandoned U.S. patent application Ser. No. 11/665,084, filed on Jun. 11, 2007, entitled �COATING COMPOSITIONS, ARTICLES, AND METHODS OF COATING ARTICLES,� which is the National Stage Entry of, claims priority to, and any other benefit of International Application Number PCT/US2005/036458, filed on Oct. 12, 2005, which claims priority to and any other benefit of U.S. Provisional Application No. 60/618,014 filed Oct. 12, 2004, the entire disclosures of which are all incorporated by reference herein.
While transparent plastics provide the major advantage of being more resistant to shattering, lighter than glass, and having design flexibility, a serious drawback lies in the case with which these plastics mar and scratch due to everyday contact with abrasives such as dust or cleaning equipment. Marring results in impaired visibility and poor aesthetics, and often requires replacement of the glazing or lens or the like.
In another example, the tetrafunctional silane has a formula of Si(OR9)4, where R9 is H, an alkyl group containing from 1 to about 5 carbon atoms and ethers thereof, an (OR9) carboxylate, a −Si(OR10)3 group where R10 is a H, an alkyl group containing from 1 to about 5 carbon atoms and ethers thereof, an (OR10) carboxylate, or another �Si(OR10)3 group and combinations thereof. In a further example, the disilane has a formula of (R11O)xR12 3-xSi�R13 y�SiR14 3-x(OR15)x; wherein x is 0, 1, 2, or 3 and y is 0 or 1; wherein R12 and R14 comprises H, an alkyl group containing from about 1 to about 10 carbon atoms, a functionalized alkyl group, an alkylene group, an aryl group, an alkypolyether group, and combinations thereof; wherein R11 and R15 comprises H, an alkyl group containing from about 1 to about 10 carbon atoms, an acetyl group, and combinations thereof; wherein if y is 1 then R13 comprises an alkylene group containing from about 1 to about 12 carbon atoms, an alkylenepolyether containing from about 1 to about 12 carbon atoms, an aryl group, an alkylene substituted aryl group, an alkylene group which may contain one or more olefins, S, or O; wherein if x is 0 then R12 and R14 comprises Cl or Br; and wherein if y is 0 then there is a direct silicon-silicon bond.
The Taber method is considered a semi-quantitative method for measuring abrasion resistance. The precision and accuracy of the method is dependent on a number of factors, including the condition of the CS-10F test wheels. Changes in the condition of the CS-10F test wheels can have a significant affect on the outcome of an abrasion resistance test. For example, a recent change made by Taber Industries in the composition of the CS-10F. wheels changed the haze gain on standard samples from 1% haze and 5% haze at 100 and 500 cycles (reported as 1%/5%) respectively, to 7% and 25%, respectively. Throughout the testing conducted herein, all of the samples were tested with the same set of new CS-10F Taber wheels. In accordance with embodiments of the present invention, the coatings can have Taber numbers of less than about 30%, less than about 10%, or less than about 5% for 50 cycles. In accordance with other embodiments of the present invention, the coatings can have Taber numbers of less than about 2% for 50 cycles. In other examples, the coatings can have Taber numbers of less than about 45%, less than about 30%, or less than about 15% for 200 cycles.
Suitable glycols, ethers, glycol ethers can be represented by the formula R1�(OR2)xOR1 where x is 0, 1, 2, 3 or 4, R1 is hydrogen or an alkyl group containing from 1 to about 10 carbon atoms and R2 is an alkylene group containing from 1 to about 10 carbon atoms and combinations thereof.
Examples of glycols, ethers and glycol ethers having the above defined formula include, but are not limited to, di-n-butylether, ethylene glycol dimethyl ether, propylene glycol dimethyl ether, propylene glycol methyl ether, dipropylene glycol methyl ether, tripropylene glycol methyl ether, dipropylene glycol dimethyl ether, tripropylene glycol dimethyl ether, ethylene glycol butyl ether, diethylene glycol butyl ether, ethylene glycol dibutyl ether, ethylene glycol methyl ether, diethylene glycol ethyl ether, diethylene glycol dimethyl ether, ethylene glycol ethyl ether, ethylene glycol diethyl ether, ethylene glycol, diethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, butylene glycol, dibutylene glycol, tributylene glycol and combinations thereof. In addition to the above, cyclic ethers such as tetrahydrofuran and dioxane are suitable ethers for the aqueous-organic solvent mixture.
2,3-epoxypropyltrimethoxysilane, 3,4-cpoxybutyltrimethoxysilane, 6,7-epoxyheptyltrimethoxysilane, 9,10-epoxydecyltrimethoxysilane, 1,3-bis(2,3-epoxypropyl)tetramethoxydisiloxane, 1,3-bis(6,7-epoxy-heptyl)tetramethoxydisiloxane, 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane, and the like.
Any suitable multifunctional crosslinker or combinations of multifunctional crosslinkers can be used in the present invention. The multifunctional crosslinker can be any multifunctional carboxylic acid, multifunctional anhydride, silylated multifunctional anhydride, silylated multifunctional carboxylic acid, and combinations thereof which are compatible with epoxy functional silanes, diol functional organopolysiloxanes, or other components of the coating compositions. Silylated multifunctional anhydrides and carboxylic acids have �Si(OR′) groups that are capable of interacting with the hydrolysis products and partial condensates of epoxy functional silanes, diol functional organopolysiloxanes, tetrafunctional silanes, disilanes, and allyl silanes.
Any suitable tetrafunctional silane or combination of tetrafunctional silanes can be used in the present invention in amounts insufficient to render the coatings rigid. For example, the tetrafunctional silane can have formulas of Si(OR9)4, where R9 is H, an alkyl group containing from 1 to about 5 carbon atoms and ethers thereof, a �Si(OR10)3 group where R10 is a H, an alkyl group containing from 1 to about 5 carbon atoms and ethers thereof, or another �Si(OR10)3 group and combinations thereof. Examples of tetrafunctional silanes represented by the formula Si(OR9)4 are tetramethyl orthosilicate, tetraethyl orthosilicate, tetrapropyl orthosilicate, tetraisopropyl orthosilicate, tetrabutyl orthosilicate, tetraisobutyl orthosilicate, tetrakis(methoxyethoxy)silane, tetrakis(methoxypropoxy)silane, tetrakis(ethoxycthoxy)silane, tetrakis(methoxyethoxyethoxy)silane, trimethoxyethoxy-silane, dimethoxydiethoxysilane, triethoxymethoxysilane, poly(dimethoxysiloxane), poly(diethoxysiloxane), poly(dimethoxy-diethoxysiloxane), tetrakis(trimethoxysiloxy)silane, tetrakis(triethoxysiloxy)silane, and the like. In addition to the R9 and R10 substituents described above for the tetrafunctional silane, R9 and R10 taken with oxygen (OR9) and (OR10) can be carboxylate groups. Examples of tetrafunctional silanes with carboxylate functionalities are silicon tetracetate, silicon tetrapropionate and silicon tetrabutyrate.
The compositions can include any suitable disilanes in amounts insufficient to render the coatings rigid. For example, the disilanes can be represented by the formula (R11O)xR12 3-xSi�R13 y�SiR14 3-x(OR15)x; where x is 0, 1, 2, or 3 and y is 0 or 1; R12 and R14 are either H, an alkyl group containing from about 1 to about 10 carbon atoms, a functionalized alkyl group, an alkylene group, an aryl group, an alkypolyether group, and combinations thereof; R11 and R15 are either H, an alkyl group containing from about 1 to about 10 carbon atoms, an acetyl group, and combinations thereof. If y is 1 then R13 can be an alkylene group containing from about 1 to about 12 carbon atoms, an alkylenepolyether containing from about 1 to about 12 carbon atoms, an aryl group, an alkylene substituted aryl group, an alkylene group which may contain one or more olefins, S, or O. If x is 0 then R12 and R14 is Cl or Br. If y is 0 then there is a direct silicon-silicon bond. Examples of such disilanes include, but are not limited to, bis(triethoxysilyl)ethane, bis(triethoxysilyl)methane; bis(trichlorosilyl)methane, bis(triethoxysilyl)ethylene, 1,3-bis(triethoxysilyl)ethane, hex aethoxydisiloxane, and hexaethoxydisilane. The selection of the disilane, as well as the amount of such a disilane incorporated into the coating compositions, will depend upon the particular properties to be enhanced or imparted to either the coating composition or the cured coating composition.
The compositions can include any other suitable alkyl silanes (i.e, trifunctional silanes, difunctional silanes, monofunctional silanes, and mixtures thereof, hereinafter referred to as silane additives) in amounts insufficient to render the coatings rigid. The alkyl silane additives which can be incorporated into the coating compositions of the present invention can have the formula R16 xSi(OR17)4-x where x is a number of 1, 2 or 3; R16 is H, or an alkyl group containing from 1 to about 10 carbon atoms, a functionalized alkyl group, an alkylene group, an aryl group an alkoxypolyether group, and combinations thereof; R17 is H, an alkyl group containing from 1 to about 10 carbon atoms, an acetyl group, and combinations thereof. Examples of silane additives represented by the above-defined formula are methyltrimethoxysilane, ethyltrimethoxysilane, propyltrimethoxysilane, butyltrimethoxysilane, isobutyltrimethoxysilane, hexyltrimethoxysilane, octyltrimethoxysilane, decyltrimethoxysilane, cyclohexyltrimethoxysilane, cyclohexylmethyltrimethoxysilane, 3-methacryloxypropyltrimethoxysilane, vinyltrimethoxysilane, allyltrimethoxysilane, dimethyldimethoxy-silane, 2-(3-cyclohexenyl)ethyltrimethoxysilane, 3-cyanopropyl-trimethoxysilane, 3-chloropropyltrimethoxysilane, 2-chloroethyltrimethoxysilane, phenethyltrimethoxysilane, 3-mercaptopropyltrimethoxysilane, 3-aminopropyltrimethoxysilane, phenyltrimethoxysilane, 3-isocyanopropyltrimethoxysilane, N-(2-aminoethyl)-3-aminopropyltrimethoxysilane, 4-(2-aminoethylaminomethyl)phenethyltrimethoxysilane, chloromethyltriethoxysilane, 2-chloro-ethyltriethoxysilane, 3-chloropropyltriethoxysilane, phenyltriethoxysilane, ethyltriethoxysilane, propyltriethoxysilane, butyltriethoxysilane, isobutyltriethoxysilane, hcxyltricthoxysilane, octyltriethoxysilane, decyltriethoxysilane, cyclohexyl-triethoxysilane, cyclohexylmethyltriethoxysilane, 3-methacryloxypropyltriethoxysilane, vinyltriethoxysilane, allyltriethoxysilane, [2-(3-cyclohexenyl)ethyltriethoxysilane, 3-cyanopropyltriethoxysilane, 3-methacrylamidopropyltriethoxysilane, 3-methoxypropyltrimethoxysilane, 3-cthoxypropyltrimethoxysilane, 3-propoxypropyltrimethoxysilane, 3-methoxyethyltrimethoxysilane, 3-ethoxyethyltrimethoxysilane, 3-propoxyethyltrimethoxysilane. The selection of the silane additive, as well as the amount of such silane additive incorporated into the coating compositions, will depend upon the particular properties to be enhanced or imparted to either the coating composition or the cured coating composition.
Example 2 Coating Composition and Primer 7.5 grams of deionized (DI) water were added dropwise to a stirring solution of 15.0 grams of A-187, 19.3 grams of dihydro-3-(3-(triethoxysilyl)propyl)-2,5-furandione silylated multifunctional anhydride (GF20, Wacker chemical corporation, Adrian, Mich.), and 140.0 grams of isopropanol solvent. The mixture was stirred at room temperature overnight. 0.18 grams of a solution of leveling agent PA-57 (Dow Corning corporation, Midland, Mich.), 10 weight percent propylene glycol monomethyl ether (PM ether, Ashland Chemical, Columbus, Ohio) were added. The composition was left to stir for an additional 20 minutes after the addition of the PA-57 to insure mixing.
Example 15 Coating Composition and Primer A mixture of 15.0 grams of trimethoxy(3-oxiranylmethoxy)propylsilane hydrolyzed aqueous solution available as HS2926 (, SIVENTO Inc, Piscataway, N.J.), 9.66 grams of GF20, and 70.0 grams of isopropanol was stirred at room temperature overnight. 0.10 grams of a solution of PA-57, 10 weight percent in PM glycol ether, were added. The composition was left to stir for an additional 20 minutes after the addition of the PA-57 to insure mixing. This coating composition was applied by flow coating to a PR-1180 primed �″ thick polycarbonate plaque. After air-drying for 30 minutes, the coating was cured for 2 hours at 130� C. Haze gain results from a Taber test using CS-10F wheels were: 1.0% haze at 50 revolutions and 3.0% haze after 200 revolutions. Thickness of the topcoat was 3.0 microns. Formability of the coating was evaluated on a cylindrical mandrel and no crack was observed at 7″ radius.
Example 17 Coating Composition and Primer A mixture of 15.0 grams of HS2926, 0.7 grams of succinic anhydride, and 30.0 grams of isopropanol was stirred at room temperature overnight. 0.05 grains of a solution of PA-57, 10 weight percent in PMOH, were added. The composition was left to stir for an additional 20 minutes after the addition of the PA-57 to insure mixing. This coating composition was applied by flow coating to a PR-1180 primed �″ thick polycarbonate plaque. After air-drying for 30 minutes, the coating was cured for 2 hours at 130� C. Haze gain results from a Taber test using CS-10F wheels were: 26.0% haze at 25 revolutions. Formability of the coating was evaluated on a cylindrical mandrel and no crack was observed at 3″ radius.
Example 21 Anti-Foe Coating Composition and Primer 1.91 grams of DI water were added dropwise to a stirring solution of 4.0 grams of A-187, 5.15 grams of GF20, and 40 grams of PM glycol ether. The mixture was stirred at room temperature overnight. 0.74 grams of surfactant sodium dioctyl sulfosuccinate in mixture of ethanol and water (OT-75) Van Waters & Rogers Inc., Kirkland, Wash.) (75% solid) was added. The composition was left to stir for two hours at room temperature and then aged at a 100 F warm room for 3 weeks before coating application.
Example 24 Coating and Weatherable Primer A weatherable primer was prepared by mixing a Poly(oxy-1,2-ethanediyl), .alpha.-[3-[3-(2H-benzotriazo(-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl)-1-oxopropyl]-.omega.-[3-[3[(2H-benzotriazol-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl]-1-oxopropoxy], 30-45% by wt. and Poly(oxy-1,2-ethanediyl), .alpha.-[3-[3-(2H-benzotriazo(-2-yl)-5-(1,1-dimethylethyl)-4-hydroxyphenyl)-1-oxopropyl]-.omega.-hydroxy-, 40-55% by wt. (Tinuvin 1130, Ciba Specialty Chemicals Corporation, Tarrytown, N.Y.) into a commercially available PR1180 primer. Thus, 6.42 grams of Tinuvin1130 was added to 150 grams of PR1180. The resulting composition was left to stir for four hours before coating application.
The weatherability of the coating was evaluated by both QUV and Weather-β-Meter. The coating doesn't show adhesion failure and crack after 200 hours exposure to ultraviolet light in both accelerated weathering testers. The QUV was operated under the condition of 8 hours UV cycle at 70� C. and 4 hours condensation cycle at 50� C. The Weather-O-Meter was operated according to ASTM 155-1.
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Hebrews 6:1-8 (Part 1 of 5): A Theological Vietnam | Humanitas Remedium
Hebrews 6:1-8 (Part 1 of 5): A Theological Vietnam
“Therefore let us leave the elementary doctrine of Christ and go on to maturity, not laying again a foundation of repentance from dead works and of faith toward God, and of instruction about washings, the laying on of hands, the resurrection of the dead, and eternal judgment.
For land that has drunk the rain that often falls on it, and produces a crop useful to those for whose sake it is cultivated, receives a blessing from God. But if it bears thorns and thistles, it is worthless and near to being cursed, and its end is to be burned.” –Hebrews 6:1-8
Before we get too much further I need to address the fact that this passage has produced tons of controversy over its interpretation. As Russ would put it, it’s a theological Vietnam. And I would agree—I wrestled hard and long with some of the verses in this passage. The language used in this passage and often throughout Hebrews is unique and therefore can be difficult to interpret. However in light of the context surrounding our passage, the general themes of Hebrews, and basic truths of the gospel covered thoroughly in scripture I believe that there is only one message that makes clear sense in this passage. I want to take the next few days to explore the meaning of the passage and help clear up any fogginess surrounding it.
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National Art Education Association Student Chapter at Towson University
Contact Info, Links, Resources
Thanks to all of you who helped make the 2011-2012 NAEA year a success! Our term has officially ended and a new group of fabulous Art Education students are taking over for the 2012-2013 school year. Our blog will remain active for as long as I have my personal blog so that we can use this on our resume's and such. I had such a great time working with all of you, and look forward to seeing our careers as artists, teachers, and professionals grow.
Please keep in touch with the new NAEA crew on facebook https://www.facebook.com/NAEAatTU?fref=ts and if anyone has a question, or want's to keep in touch via blogger, please visit my personal art blog at http://meganraewhite.blogspot.com/.
Thanks for a great year all!
Hello All, It was nice meeting you all tonight! For those of you that couldn't make the meeting, my name is Megan White, and I am the NAEA President Mentor for the new leadership core of the NAEA student chapter. For the last year I've been working with NAEA as President, and am here if you have any questions, concerns, or ideas.
I hope you all got a brief idea of what NAEA is all about at tonights meetings, while it was very broad, and a lot to get through, I think you are off to a great start! Feel free to email me if you need anything or just want to say hi and introduce yourself. If you would like further contact info, email me and I'll get my cell to you. While I am student teaching, and won't be on campus, I'll be available as much as I can to you all semester to help you guys out in any way possible. I look forward to working with you, have a wonderful semester! Best,Megan White
mwhite7@students.towson.edu
Welcome Back Art Eddies!!!
Hello Art Education Majors!!! Welcome new students and welcome back upperclassmen! We have a lot to discuss since our last meeting!!
Be on the look out! Check your TU email, facebook, involved@TU account, our blog, and the CFA for flyers!!!
We are having our first meeting of the year in less than two weeks!!!
Pizza and drinks will be served!!!!
Come check out NAEA, learn about the organization, elect student officers, and meet fellow art education students! Also, some important updates: Check out the "Volunteer Opportunities" Tab for 2012 internship/job opportunities as well as the "Exhibit" Tab to check out the photos from our Those Who Can Do...Teach Exhibit at TAC!
Aloha Art-ies!Keep an eye on the blog, Involved@TU, and our FB page (and on campus bulletin Boards) for our upcoming meeting- this will be the first one of the 2012 Spring Semester! Lots to discuss!!!! Until then.... Best!
First News of 2012!
HI ALL!!! HAPPY NEW YEAR!!!Hope you are having a fabulous break, resting up, and eating well! As we get our thoughts together for the rest of the month, there are some updates with NAEA that you won't want to forget!Of course we are all excited about our upcoming exhibition, Those Who Can Do... TEACH! at Towson Arts Collective on view January 20, 2012-February 24, 2012 and need to remember the following dates:- January 5, 2012 1pm-4pm Delivery of Art to Towson Arts Collective- January 7, 2012 12pm-3pm Pick Up of Unaccepted Art from Gallery- January 20, 2012 6pm-8pm Opening Reception, Light Refreshments will be served- February 24, 2012 Last day of show- February 25, 2012 12pm-3pm Pick Up of Art From GallerySecondly, our friends from Young Audiences of Maryland sent some important info our way regarding job opportunities for the upcoming graduates, and volunteer opportunities for YA's two large events this spring. See the "Volunteer Opportunities" Tab for details.Also, with the upcoming semester, NAEA will undergo a transition period of officers. Please see the "Contact Info, Links, Resources" Tab for details on Open Positions for the 2012 Spring Semester and info on Elections. See you Soon!Megan WhiteCo-President
Volunteers Needed to Sit Gallery during Upcoming NAEA Student Exhibition
We are in need of Art Education Students and NAEA Members to Volunteer at Towson Arts Collective during our upcoming exhibition. This is a great opportunity for us! (Especially if you plan on selling your work) Going into the show, the commission rate is 60/40, 60% to artist and 40% to the gallery. If you sit the gallery, the rate goes down dramatically! For one sit, the commission rate becomes 80/20. And then for 2x, the commission rate becomes 90/10! Since TAC is not charging very much, we need to plan on having as many gallery volunteers as possible! This is also another resume builder! Employers love seeing volunteer work and gallery experience.The show will be on exhibition from January 20, 2012- February 24, 2012. The gallery will be open on Thursdays, Fridays, and Saturdays from 12-5pm.See "Volunteer Opportunities" Tab to view slots needing to be filled. Email Megan White with any questions or concerns.
Bake Sale Starts Tomorrow!!!
Just a reminder that our Final Exam/Holiday Bake Sale starts tomorrow!!!!!We still need people to volunteer to set up and sell baked goods in the cfa atrium as well as bring in baked goods for BOTH DAYS!Right now this is what's been recorded:Table for Tuesday Dec 13:9-10am _____________________ ???10-11 am ___________________???11am-12pm _________________???12pm-1pm Christine and Danielle1-2pm Christine and Danielle2-3pm ______________________???Baked Goods for Tuesday Dec 13:Christine Long- Marshmellow PopsAlex BorelisSam- Cupcakes and more...Megan White- Choc covered pretzels with peppermints and blueberry muffinsMai-Ly NguyenTable for Wednesday Dec 14:9-10 am Megan White10-11am Sam Green11am-12pm Mary Tippett12pm-1pm ___________________???1pm-2pm Katherine Nochera2pm-3pm Sarah Timmcke and Shana TeelBaked Goods for Wednesday Dec 14:Annie BoesSo as you can see we still need some volunteers to sit the tables and to bring in baked goods. Usually we have items left over to sell for the second day, but we want to make sure we have enough to sell. Shana's made a great sign and thanks to those of you that participated, we have a bunch of buttons to sell along with the baked goods!If you are able to volunteer some time to watch the tables, please call, text, or email me back asap!Megan Whitemwhite7@students.towson.edu443 248 3831
Hello Everyone, and welcome to my blog. If interested in purchasing a work of art, please contact me at megan.rae.white@gmail.com and see "Terms"
Thanks to all of you who helped make the 2011-2012...

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Keat Radio Co. Sdn. Bhd.: Board of Directors - Bloomberg
Keat Radio Co. Sdn. Bhd. INSIDERS ON Board Members
Most Connected People on the Keat Radio Co. Sdn. Bhd. Board
To contact Keat Radio Co. Sdn. Bhd., please visit . Company data is provided by S&P Global Market Intelligence. Please use this form to report any data issues.

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Carol’s Parenting Hack: Get More Sleep | 4 Mothers
← Nathalie’s Parenting Hack: Google Calendar
Posted in Uncategorized	| Tagged parenting hack, Sleep, sleep deprivation
2 thoughts on “Carol’s Parenting Hack: Get More Sleep”
Omg I love to sleep! After I became a mom of twins I feel even more tired. But you are definitely right! When I do get my good night sleep the whole world seems a better place. And even my kids love me more when I’m rested. 😊😂😁
I can estimate my prior night’s sleeping hours according to how refreshed I feel when I wake up. I personally prefer 8 hours.


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Niamh-makes-things: Levi Jean Challange
Whilst flicking through the May issue of Vogue I came across an article that grabbed my attention instantly. 5 pairs of classic Levi jeans were sent to 5 different designers: Mary Katrantzou, Missoni, Clements Ribeiro, Peter Pilotto and Maarten Van Der Horst.
They were challenged to re-design the jeans in a fun and creative way. I absolutely fell in love with Mary Katrantzou's approach of turning them into shorts and completely drowning them in sequins. I am a great admirer of beading and little details that take that extra bit of effort, and I would definitely wear these with a plain white t-shirt, or crochet lace top.
This had to be my second favourite design. I think that it was one of the most original approaches dramatically altering the look of the jeans by sculpting them into a body suit. I love the floral fabric he used on the back. The frills are just amazing! I like the lace, particularly on the waist band, and the diagonal lines are interesting. However it seems a bit too basic (what can I say, I'm a sucker for detail)
I think the printing technique Peter Pilotto has used on the Levi jeans i really cute. I like the bright poppy colours. I think they would have been even more successful if they had changed the shaping slightly. By changing the fabric and pattern on the surface of the denim the look has been completely changed. I like the contrast of fabrics they used. So what do you think? Which one is your favorite?


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Asme section ix by Jithu John 23362 views
Sivagnanam Sivarasu
Ahmad Syukeri
Jawahar Balasubramanian , QC Welding Inspector at Petrofac
Rhy isip , Welding Instructor at Pasig City Institute of Science and Technology at Pasig City Institute of Science and Technology
1. Welders Qualification, According To ASME Sec IX
2. POSITION AND DIAMETER LIMITS (With OtherLimits Qw303)
3. PLATE - GROOVE Plate andPipe Over 24 in (610 mm) OD Pipe <=24 in (610) mm OD Pipe and plate Plate -Groove 1G F F (NOTE 2) F Plate -Groove 2G F, H F, H (NOTE2) F, H Plate -Groove 3G F, V F, NOTE2 F, H,V Plate -Groove 4G F,O F, NOTE2 F, H,O Plate -Groove 3G& 4G F, V, O F, NOTE2 ALL Plate -Groove 2G,3G, &4G ALL F,H NOTE2 ALL Plate -Groove Special Position SP,F SP,F SP,F Groove Fillet Weld Position Qualification Test Position And Type Weld Qualified (Note 1) NOTE1: 1)Position Of Welding As Shown As Shown In QW-461 And QW-461.2 F= Flat,H=Horizontal,V=Vertical,O=Overhead 2)Pipe 2 7/8 in (72mm) OD and over 3) See Diameter Restrictions In Qw-452.3, Qw452.4, Qw452.6
4. Plate andPipe over 24 in (610 mm) OD Pipe <=24 in (610) mm OD Pipe and plate Plate -Fillet 1F -- -- F NOTE 2 Plate -Fillet 2F -- -- F, H NOTE2 Plate -Fillet 3F -- -- F, H,V NOTE2 Plate -Fillet 4F -- -- F, H,O NOTE2 Plate -Fillet 3F &4F -- -- ALL NOTE2 Plate -Fillet Special Position -- -- SP,F NOTE2 NOTE F= Flat H=HorizontalV=Vertical, O=Overhead 3)See Diameter Restrictions In Qw-452.3, Qw452.4, Qw452.6 Groove Fillet Weld Position 1)Position Of Welding As Shown As Shown In Qw-461 And Qw-461.2 2)Pipe 2 7/8 in (72mm) od and over Qualification Test Position And Type Weld Qualified (Note 1) PLATE - FILLET
5. Plate andPipe Over 24 in (610 mm) OD Pipe <=24 in (610) mm OD Pipe and plate Pipe-Groove 1G F F F Pipe-Groove 2G F,H F,H F, H Pipe-Groove 5G F,V,O F,V,O ALL Pipe-Groove 6G ALL ALL ALL Pipe-Groove 2G&5G ALL ALL ALL Pipe-Groove Special Position SP,F SP,F SP,F NOTE F= Flat H=HorizontalV=Vertical, 1)Position Of Welding As Shown As Shown In Qw-461 And Qw-461.2 O=Overhead 2)Pipe 2 7/8 in (72mm) od and over 3)See DiameterRestrictions In Qw-452.3, Qw452.4, Qw452.6 Groove Fillet Weld Position Qualification Test Position And Type Weld Qualified (Note 1) PIPE-GROOVE
6. Plate and Pipe over 24 in (610 mm) OD Pipe <=24 in (610) mm OD Pipe and plate Pipe-Fillet 1F -- -- F Pipe-Fillet 2F -- -- F, H Pipe-Fillet 2FR -- -- F,H Pipe-Fillet 4F -- -- F,H,O Pipe-Fillet 5F -- -- ALL Pipe-Fillet Special Position -- -- SP,F NOTE F= Flat H=HorizontalV=Vertical, Qualification Test Position And Type Weld Qualified (Note 1) Groove Fillet Weld Position 1)Position Of Welding As Shown As Shown In Qw-461 And Qw-461.2 O=Overhead 2)Pipe 2 7/8 in (72mm) od and over 3)See Diameter Restrictions In Qw-452.3, Qw452.4, Qw452.6 PIPE – FILLET
7. POSITIONS QW-461
8. PLATE-GROOVE QW-461.3
10. 2G
12. 4G
13. PIPE-GROOVE QW-461.4
14. 1G
15. 2G
16. 5G
17. 6G
18. PLATE-FILLET QW-461.5
20. 2F
21. 3F
22. 4F
23. PIPE –FILLET QW-461.6
24. 1F(Rotated)
25. 2F
26. 2FR (ROTATED)
27. 4F
28. 5F
29. Qualified With Qualified For X X X X F-No5 with out Backing X F-No5 with Backing X F-No4 with out Backing F-No 4 with Backing X X F-No3 with out Backing X F-No 3 with Backing X X X X F-No 2 with out Backing X F-No 2 with Backing X X X X X X X F-No 1 with out Backing X F-No5 with Backing F-No5 with out Backing F-No 1 with Backing X X X X X X X F-No 3 with Backing F-No3 with out Backing F-No 4 with Backing F-No4 with out Backing F-No 1 with Backing F-No 1 with out Backing F-No 2 with Backing F-No 2 with out Backing
30. QUALIFIED WITH QUALIFIED FOR QUALIFIED WITH QUALIFIED FOR F-NO 1 WITH BACKING F-NO 1 WITH BACKING F-NO 1 WITH BACKING F-NO 1 WITH BACKING F-NO 2 WITH BACKING F-NO 1 WITH OUT BACKING F-NO 3 WITH BACKING F-NO 1 WITH BACKING F-NO 4 WITH BACKING F-NO 2 WITH BACKING F-NO 1 WITH BACKING F-NO 1 WITH BACKING F-NO 2 WITH BACKING F-NO 2 WITH BACKING F-NO 3 WITH BACKING F-NO 4 WITH BACKING F-NO 4 WITH OUT BACKING F-NO 1 WITH BACKING F-NO 1 WITH BACKING F-NO 2 WITH BACKING F-NO 5 WITH BACKING F-NO 3 WITH BACKING F-NO 1 WITH BACKING F-NO 1 WITH BACKING F-NO 2 WITH BACKING F-NO 3 WITH BACKING F-NO 3 WITH OUT BACKING F-No 2 WITH OUT BACKING F-No 3 WITH BACKING F-No5 WITH OUT BACKING F-No3 WITH OUT BACKING F-No 4 WITH BACKING F-NO 5 WITH OUT BACKING F-NO 5 WITH BACKING F-NO 1 WITH OUT BACKING F-No 2 WITH OUT BACKING F-No 2 WITH BACKING F-No4 WITH OUT BACKING F-No5 WITH BACKING
31. Test Specimens
32. TEST SPECIMENS [ QW-452.1(a)] Thickness of weld metal, IN(mm) TYPE AND NUMBER OF EXAMINATIONS AND TEST SPECIMENS REQUIRED Visual Examination per QW-302.4 Side Bend QW-462.2 [note (1)] Face Bend QW- 462.3(a) Or QW-462.3(b) [Note (1),(2)] Root Bend qw- 462.3(a) or QW- 462.3(b) [note(1),(2)] LESS THAN 3/8 (10) X --- 1 1 3/8(10) TO LESS THAN 3/4(19mm) X 2 [NOTE (3)] NOTE (3) NOTE (3) 3/4(19MM) AND OVER X 2 --- ---
33. Thickness Limits
34. Thickness of Weld Metal Qualified Thickness,t,of weld metal inch, The coupon inch(mm) [Note1& 2] Thickness of weld metal Qualified [Note3] • Up to13 mm •½(13mm) and over with a minimum of three layers •2t •Maximum to be welded
35. DIAMETER LIMITS QW-452.3
36. GROOVE WELD DIAMETER LIMITS QW-452.3
37. WELDER PERFORMANCE ESSENTIAL VARIABLES
38. SMAW (QW-353) PARAGRAPH BREAF OF VARIABLES QW-402 JOINTS DELETION OF BACKING QW-403 BASE METAL CHANGE OF PIPEDIA(QW-403.16) &CHANGE OF P-NUM(QW-403.18) QW-404 FILLERMETALS CHANGE OF FILLER (QW404.15) & CHANGEOF WELD t DEPOSIT (QW404.30) QW-405 POSITIONS ADDITION OF POSITION (QW-405.1) & VERTI& DOWN WELDING (QW-405.3)
39. What Is UNS Number?
40. (Ans) Unified Numbering System
41. What is SFA Number?
42. (Ans) Specification of Filler Analysis
43. What is P-Number?
44. (Ans) Material Group Number

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edit The virtue of inclusiveness
Why yes, young Asbo, that is mine ... I'm, er, researching it. Give it BACK please. Thank you. edit The evil of "fursecution"
edit Who amongst us?
edit And, in conclusion
edit You may now all rise ... Why, yes, young Asbo, those are my kitty ears. — I mean, those are NOT mine. Of course not. THE SERMON IS OVER. Thank you all. thank you. LucidFox, if you could just stay for a moment ... ?
Retrieved from "http://uncyclopedia.wikia.com/wiki/Furry_tolerance?oldid=5718507"
This page was last modified on July 22, 2013, at 10:55.

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Richmond Bacon Festival!!! - Richmond New In Town Meetup Group (Richmond, VA)
Richmond Bacon Festival!!!
Jun 9, 2013 · 1:45 PM
Please read these instructions carefully, as in the past there are people don't read these important notes and miss on important details. I imagine this place will be super packed, so it will be extremely difficult to find anyone unless you recognize them, or have their phone numbers.
Where: We will meet up at the River City Diner outside entrance! (7 North 17th St) DO NOT wait at Main & 17th corner!!
When: Please be outside River City Diner from 1:45pm-2pm (During that 15 minute window, we will wait for others, meet and greet with each other).
If you are late, after 2pm please text me at [masked] I will tell you where we are all at. What I will be wearing: I can tell you since next Sunday is Game of Thrones' Season Finale. I will be wearing a Game of Thrones T-shirt!
Festival Information Join us for the first annual Richmond Bacon Festival, presented by Devils Backbone Brewery, K95, Rock96.5KLR, and Style Weekly, to benefit Enrichmond. Sample unique bacon-centric dishes from more than 20 of Richmond's most popular restaurants and wash it all down with a selection of 20+ Virginia craft beers from Devils Backbone Brewery and Bold Rock Hard Cider. Live music, local vendors, and more will round out what is sure to be an epically delicious day! Entertainment has been booked. Thanks for the inquiries. Admission to the Festival is FREE! Bacon food samples $3 each Beer and cider $6 each
Michelle The food was good and the vendors were great. I think the only bad thing I had was a sausage from SausageCraft that was a little under cooked. The best thing there was the Buttermilk Chicken, Bacon and Waffle cupcakes. I'm looking for that recipe ASAP. 0 · June 9, 2013 Don Hey no worries if you can not meet us. I will be nice guy and not mark anyone NO shows. :) 0 · June 9, 2013 A former member Nice Don! 0 · June 9, 2013 Jeff Hey everyone! Hope you had a good time, I was in a line at the set meeting time, sorry I wasn't able to catch up w/ ya'll. Saw Don once, ok I saw the t-shirt then realized it was him, then he was gone. :-) See ya soon. 0 · June 9, 2013 A former member Bacon fest was nice wish I could have met some of you, maybe next time. 0 · June 9, 2013 Jordan Can not make it this time 0 · June 9, 2013 A former member Oh My God, it's too hot to be out!! 2 · June 9, 2013 View all 3 replies
A former member If you guys want to meetup elsewhere hit me up. Girl does not feel like sweating up a storm, lol. 0 · June 9, 2013 A former member It's HOT out, I'm still thinking. 0 · June 9, 2013 A former member Nah, I'm not coming. 0 · June 9, 2013 Don Already here!!! 0 · June 9, 2013 A former member In the vestibule at the diner. Looking for a Game of Thrones tshirt. Where you guys at? 0 · June 9, 2013 A former member I got there at 11:00 and most vendors were open and selling. I ate a bunch and on my way home now. Maybe I will meet some of you next time. 0 · June 9, 2013 View all 3 replies
Michelle That's pretty much what I did as well. Too hot and too crowded to wait for the meetup time. 1 · June 9, 2013 Don Well I had FUN at Ravi's party, and would either not host it or host it late! :) 0 · June 9, 2013 Don A GREAT party that some of you had to miss... shame! :P 0 · June 9, 2013 A former member Showed up turned around and went home!! The lines were insane!!! To crowded for me :( 0 · June 9, 2013 A former member In the beer ID and ticket line 0 · June 9, 2013 Jeff R. I'm here wearing a shirt, shorts and no hat. First one to find me gets a free beer. Lol. 0 · June 9, 2013 A former member Just showed up wearing a JEEP hat and green checkered shirt 0 · June 9, 2013 ron I'm here call or txt me[masked] ron 0 · June 9, 2013 Michelle I'm here already with a friend. I have on a red shirt with a sun on it so say hello! 0 · June 9, 2013 A former member Not feeling well 0 · June 9, 2013 Bryan W. Met some really awesome people at the Tobacco Company last night! This looks like a really fun event, wish I could make it! 0 · June 8, 2013 nfp Details from Michelle's post: http://www.richmond.com/events/festivals/article_089e82a0-cdfc-11e2-b8eb-001a4bcf6878.html 0 · June 8, 2013 Michelle Just to let you guys know, there is a very high expected turn out for this so it's probably better to go as early as possible before the lines get outrageous and the food runs out. I'm probably going around 11:00 just so I can find parking. If I'm still at the event at 1:45 I'll meet at the designated spot to say hello. 2 · June 7, 2013 Don Which is EXACTLY why I posted a later time. I don't want take chances being late hosting but I probably will be there earlier as well. 0 · June 8, 2013 Don BTW Michelle any plans for the movie Internship? 1 · June 8, 2013 Dawn Looking forward to this especially the after-party. I will probably be there much earlier than the group but will come meet you guys at the designated spot and time. I heard on the radio this morning that it is a cash only event (atm on site will be provided) and that we are recommended to bring lots of ones lol. Let the fun begin w/lots of bacon and beer :) 0 · June 7, 2013 nfp Oh. My. Goodness. There's already plans for an after party!:The Official Bacon Festival After-Party starts at 5 p.m. at On the ROX at 119 N. 18th St. "Guess what bacon-lovers, there's now an official Richmond Bacon Festival After-Party, so the fun doesn't have to stop when the festival ends. http://www.richmond.com/food-drink/dish/article_5fb5d96c-cd39-11e2-97eb-001a4bcf6878.html " 2 · June 6, 2013 Don Thanks!!! 0 · June 6, 2013 A former member Trying to picture what a bacon after party would consist of. I'm guessing....eggs? :-P 2 · June 7, 2013 nfp I'm curious to know how they will serve us maple syrup or/and scrambled eggs to accompany (if anything) said bacon samples. . . tehehe waffles? pancakes? paper cones? condiment cups? mini skillets?! Anything could happen! l0l 0 · June 4, 2013 ron hardywood was able to make a mini-skillet-papercone-pancake-maple-syrup-egg'o'matic-boubon-barrel-doppel-bock BEER 2 · June 5, 2013 nfp waaaaahhhhat? no way. :) Those Hardywood Folks'll put just about anything in a beer, won't they? tehehehe 0 · June 6, 2013 A former member I will be there with my husband and son, but will probably not travel with the group this time =/ I can't wait to meet you all though! =) 0 · June 5, 2013 John K I like to try some chocolate covered bacon. 2 · June 4, 2013 View all 8 replies
A former member I heard it's nasty. 1 · June 4, 2013 nfp I'm on to you Nancy & Steven. . . Let me guess, it's so "nasty" that you're both willing to make the "sacrifice" and "relieve" us of all the chocolatey-bacon goodness? - err nastiness? Right? l0l 0 · June 4, 2013 nfp Jamie, I'm really guessing it's all tongue-in-cheek. . . but I'm sure they'll pipe up if it isn't. . . :) 1 · June 4, 2013 A former member You can have all the chocolate covered bacon Nancy!! I'll have the beer!! 2 · June 4, 2013 John K Hey settle down. Everything's good covered with a sweet dark chocolate, even a carrot stick. Ain't that right, my Princess Granola? 0 · June 5, 2013 A former member I don't know about a sweet dark chocolate covered carrot stick, John. I prefer at least 60% dark chocolate and I think I'll have them separately, lol. 0 · June 5, 2013 ron bacon grenade 0 · June 5, 2013 A former member That sounds awesome. 0 · June 5, 2013 A former member Oh man! I would love to go, but I'll be out of town that weekend 0 · June 4, 2013 Michelle I'll need to console myself with bacon deliciousness before I drag myself over the hot coals to get through the Game of Thrones finale. :'( 0 · June 3, 2013 nfp don't do it! nooooo! (the GoT finale that is!) tehehehe 0 · June 4, 2013 A former member Bacon! Bacon! 1 · June 4, 2013 nfp Thanks for hosting Don! LOVE the picture! l0l 1 · June 3, 2013 Jeff R. Will be there with the Beer group. Will CYA there! 1 · June 2, 2013 42 went
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9/11/2016 :: 60 Words or Less – Pearl Bayou
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Posted in FictionTagged 365 Challenge, contemporary fiction, contemporary writing, creative writing, daily journal, daily poem, Fiction, flash fiction, love poem, love poetry, poetry, short story, travel, writing challengeBy briharmonLeave a comment	Leave a Reply Cancel reply	Enter your comment here...
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FALL OF GIANTS ... Book One of the new series | Books Worth Reading | Pinterest | Books, Ken follett and Book tv
Explore Russian Revolution, Ken Follett and more!
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Outlander by Diana Gabaldon is one of my all time favorite books. It is a character driven historical fiction, sci-fi, adventure, love story all rolled into one fabulous book. Get to chapter three and I promise you will not want to put it down.
'The Twelve' by Justin Cronin, author of 'The Passage': Cover reveal and release date
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Call the Midwife, a BBC series about nurses in London's East End in the is based on a trilogy of memoirs by Jennifer Worth. The first book is also called Call the Midwife.

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The Joy of Homemaking: Christmas | Yes, You Can Decorate With Small Children At Home
Christmas | Yes, You Can Decorate With Small Children At Home
Decorating for Christmas was always something that I looked forward to when Brian and I first were married. Having just a few extra things in our home made everything so warm and cozy.
When Addie's first Christmas came, she was 10 months old. I was "warned" before hand by well meaning people that I would only have the top half of my tree decorated, if I even decorated at all. They made it sound as if small children could not be taught not to touch things. Chrsitmas 2011
I thought about the decor in my home. I hadn't changed anything since Addie had been born (within reason. Of course, all sockets were covered and we did not light candles). As she began to crawl, we had just taught her not to touch anything that was not a toy. And she learned. We could take her anywhere and we knew she would not touch what she shouldn't.
So I went ahead and decorated for Christmas.
She was awake as I decorated. She saw me putting everything up. I showed her the tree. I talked to her about the tree (it makes no difference to me how old my kids are, I still teach them about everything). We played next to the tree.
And she never touched the tree.
(I couldn't resist adding this picture! Is this not the face of someone who knows they are going to have a huge personality, but no one else knows it yet!)
My next step was to put the gifts under the tree. The way I see it, it is not someone else's job to baby/child proof their home. It is my job to teach my baby/child how to treat someone else's home. I expect others to have their trees up and some people choose to put their gifts under the tree. My job as a mother is to prepare my child to know how to respond when put in that tempting situation.
Of course, Addie's curiosity was piqued. And she did go towards the gifts. And that is when Brian and I taught her that the presents are not to be touched. Not roughly. Not loudly. Just a gentle teaching moment.
And she didn't touch the gifts again.
This year, we put our tree up on the Saturday after Thanksgiving, and Ian got to watch Addie and me decorate the tree (decorating took half the time this year because my little girl was such a big help). As soon as he was let loose from his playpen, he did go straight for the tree. We gently told him "no" and let him look at it while being held. Then we put him down and he just stood and looked. And then he turned around and walked away.
He has not gone to the tree to touch it since. He just stands and looks or completely walks by it. Or, as he did on Sunday evening, he points his finger at it and says, "Nah, nah, nah, nah!" I think he is reminding himself not to touch it.
At this point, I have gifts wrapped and under the tree, and he has not touched them.
Enjoy decorating your home and making this season a joy for your entire family.... tiny ones included!
For an update on how Christmas 2013 is turning out, click here.