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Patent US6380996 - Optical compensatory sheet and liquid crystal display - Google PatentsSearch Images Maps Play YouTube News Gmail Drive More »Sign inPatentsAn optical compensatory sheet comprises an optically anisotropic layer formed of discotic liquid crystal molecules provided on a transparent substrate. The liquid crystal molecules are horizontally aligned in the optically anisotropic layer. An average inclined angle between discotic planes of the discotic...http://www.google.com/patents/US6380996?utm_source=gb-gplus-sharePatent US6380996 - Optical compensatory sheet and liquid crystal displayAdvanced Patent SearchPublication numberUS6380996 B1Publication typeGrantApplication numberUS 09/616,365Publication dateApr 30, 2002Filing dateJul 13, 2000Priority dateJan 7, 1998Fee statusPaidPublication number09616365, 616365, US 6380996 B1, US 6380996B1, US-B1-6380996, US6380996 B1, US6380996B1InventorsShigeki Yokoyama, Ken Kawata, Hideyuki Nishikawa, Koshin Matsuoka, Eiichiro Aminaka, Yoji ItoOriginal AssigneeFuji Photo Film Co., Ltd.Export CitationBiBTeX, EndNote, RefManPatent Citations (6), Referenced by (87), Classifications (38), Legal Events (6) External Links: USPTO, USPTO Assignment, EspacenetOptical compensatory sheet and liquid crystal display
An optical compensatory sheet comprises an optically anisotropic layer formed of discotic liquid crystal molecules provided on a transparent substrate. The liquid crystal molecules are horizontally aligned in the optically anisotropic layer. An average inclined angle between discotic planes of the discotic liquid crystal molecules and a surface of the transparent substrate is less than 5�. The discotic liquid crystal molecules are fixed in the optically anisotropic layer while keeping the horizontal alignment.
What is claimed is: 1. An optical compensatory sheet comprising an optically anisotropic layer formed of discotic liquid crystal molecules provided on a transparent substrate, wherein the discotic liquid crystal molecules are horizontally aligned in the optically anisotropic layer, an average inclined angle between discotic planes of said discotic liquid crystal molecules and a surface of said transparent substrate being less than 5�, and said discotic liquid crystal molecules being fixed in the optically anisotropic layer while keeping the horizontal alignment, and wherein the optically anisotropic layer further contains a melamine compound.
6. The optical compensatory sheet as defined in claim 1, wherein the optical compensatory sheet further comprises a second optically anisotropic layer formed of discotic liquid crystal molecules, said discotic liquid crystal molecules being aligned in the second optically anisotropic layer, and wherein an average inclined angle between discotic planes of the discotic liquid crystal molecules and a surface of the transparent substrate is not less than 5�, said inclined angle increasing or decreasing with increase of a distance from the surface of the transparent substrate to the discotic plane of the discotic liquid crystal molecule.
Re=(nx−ny)�d in which each of nx and ny is a refractive index in plane of the transparent substrate; and d is the thickness of the transparent substrate.
Rth=[{(nx+ny)/2}−nz]�d in which each of nx and ny is a refractive index in plane of the transparent substrate; nz is a refractive index along the thickness direction of the transparent substrate; and d is the thickness of the transparent substrate.
Re=(nx−ny)�d in which each of nx and ny is a refractive index in plane of the optical compensatory sheet; and d is the thickness of the optical compensatory sheet.
Rth=[{(nx+ny)/2}−nz]�d in which each of nx and ny is a refractive index in plane of the optical compensatory sheet; nz is a refractive index along the thickness direction of the optical compensatory sheet; and d is the thickness of the optical compensatory sheet.
12. A liquid crystal display comprising a liquid crystal cell of a vertical alignment mode, two polarizing elements and one or two optical compensatory sheets, each of said polarizing elements being arranged on each side of the liquid crystal cell, each of said optical compensatory sheets being arranged between the liquid crystal cell and each polarizing element, wherein the optical compensatory sheet comprises an optically anisotropic layer formed of discotic liquid crystal molecules provided on a transparent substrate, said discotic liquid crystal molecules being horizontally aligned in the optically anisotropic layer, and wherein an average inclined angle between discotic planes of the discotic liquid crystal molecules and a surface of the transparent substrate is less than 5�, said discotic liquid crystal molecules being fixed in the optically anisotropic layer while keeping the horizontal alignment, and wherein the optically anisotropic layer further contains a melamine compound.
13. A liquid crystal display comprising a liquid crystal cell of a bend alignment mode, two polarizing elements and one or two optical compensatory sheets, each of said polarizing elements being arranged on each side of the liquid crystal cell, each of said optical compensatory sheets being arranged between the liquid crystal cell and each polarizing element, wherein the optical compensatory sheet comprises an optically anisotropic layer formed of discotic liquid crystal molecules provided on a transparent substrate, said discotic liquid crystal molecules being horizontally aligned in the optically anisotropic layer, and wherein an average inclined angle between discotic planes of the discotic liquid crystal molecules and a surface of the transparent substrate is less than 5�, said discotic liquid crystal molecules being fixed in the optically anisotropic layer while keeping the horizontal alignment, and wherein the optically anisotropic layer further contains a melamine compound.
14. The liquid crystal display as defined in claim 13, wherein the optical compensatory sheet further comprises a second optically anisotropic layer formed of discotic liquid crystal molecules, said discotic liquid crystal molecules being aligned in the second optically anisotropic layer, and wherein an average inclined angle between discotic planes of the discotic liquid crystal molecules and a surface of the transparent substrate is not less than 5�, said inclined angle increasing or decreasing with increase of a distance from the surface of the transparent substrate to the discotic plane of the discotic liquid crystal molecule.
The present inventors have tried to prepare an optical compensatory sheet having the required specific large negative optical anisotropy by using discotic liquid crystal molecules. However, it is very difficult to prepare a specific optically anisotropic layer in which an optical axis is essentially not inclined (less than 5�) where the layer is prepared according to prior art.
The present invention provides an optical compensatory sheet comprising an optically anisotropic layer formed of discotic liquid crystal molecules provided on a transparent substrate, wherein the discotic liquid crystal molecules are horizontally aligned in the optically anisotropic layer, an average inclined angle between discotic planes of said discotic liquid crystal molecules and a surface of said transparent substrate being less than 5�, and said discotic liquid crystal molecules being fixed in the optically anisotropic layer while keeping the horizontal alignment.
The invention also provides a liquid crystal display comprising a liquid crystal cell of a vertical alignment mode, two polarizing elements and one or two optical compensatory sheets, each of said polarizing elements being arranged on each side of the liquid crystal cell, each of said optical compensatory sheets being arranged between the liquid crystal cell and each polarizing element, wherein the optical compensatory sheet comprises an optically anisotropic layer formed of discotic liquid crystal molecules provided on a transparent substrate, said discotic liquid crystal molecules being horizontally aligned in the optically anisotropic layer, and wherein an average inclined angle between discotic planes of the discotic liquid crystal molecules and a surface of the transparent substrate is less than 50�, said discotic liquid crystal molecules being fixed in the optically anisotropic layer while keeping the horizontal alignment.
The invention further provides a liquid crystal display comprising a liquid crystal cell of a bend alignment mode, two polarizing elements and one or two optical compensatory sheets, each of said polarizing elements being arranged on each side of the liquid crystal cell, each of said optical compensatory sheets being arranged between the liquid crystal cell and each polarizing element, wherein the optical compensatory sheet comprises an optically anisotropic layer formed of discotic liquid crystal molecules provided on a transparent substrate, said discotic liquid crystal molecules being horizontally aligned in the optically anisotropic layer, and wherein an average inclined angle between discotic planes of the discotic liquid crystal molecules and a surface of the transparent substrate is less than 5�, said discotic liquid crystal molecules being fixed in the optically anisotropic layer while keeping the horizontal alignment.
The present inventors have found that an optical compensatory sheet having a large negative optical anisotropy in which an optical axis is essentially not inclined can be obtained by adjusting an average inclined angle between discotic planes of discotic liquid crystal molecules and a surface of the transparent substrate to be less than 5�. However, it is difficult according prior art to align discotic liquid crystal molecules in such manner (homeotropic alignment). The present inventors have further studied the alignment of the discotic liquid crystal molecules, and have finally succeeded in aligning the discotic liquid crystal molecules having an average inclined angle of less than 5�. The homeotropic alignment of the discotic liquid crystal molecule is obtained by using a specific coating amount of a cellulose ester of a lower fatty acid, a fluorine containing surface active agent or 1,3,5-triazine compound.
According to the present invention, an average inclined angle (θ) between discotic planes of the discotic liquid crystal molecules (14 a) and a surface of the transparent substrate (16) is less than 5�. The average inclined angle (θ) preferably is less than 4�, more preferably is less than 3�, further preferably is less than 2�, and most preferably is less than 1�. The average inclined angle (θ) can be 0� (completely not inclined).
In the second optically anisotropic layer (25), an average inclined angle between discotic planes of the discotic liquid crystal molecules (25 a to 25 c) and a surface of the transparent substrate (27) is not less than 5�. The inclined angle increases or decreases with increase of a distance from the surface of the transparent substrate to the discotic plane of the discotic liquid crystal molecules. In the optical compensatory sheet shown in FIG. 2, the inclined angle (θa to θc) increases with increase of a distance from the surface of the transparent substrate (27) to the discotic plane of the discotic liquid crystal molecules (25 a to 25 c).
As is described above, most of rod-like liquid crystal molecules are essentially vertically aligned in a liquid crystal cell of a vertical alignment mode (FIG. 1) or a bend alignment mode (FIG. 2). The optical anisotropy of the essentially vertically aligned rod-like liquid crystal molecules can be optically compensated by discotic liquid crystal molecules having an inclined angle (θ) of less than 5�.
In the present specification, the term “essentially vertically (or horizontally)” and the term “essentially parallel (or perpendicular)” mean that a margin for error based on the exactly vertical, horizontal, parallel or perpendicular angle is in the range of �20�. The margin for error is preferably in the range of �15�, more preferably in the range of �10�, and most preferably in the range of �5�.
In the present invention, the discotic liquid crystal molecules are so aligned that an average inclined angle between discotic planes of the discotic liquid crystal molecules and a surface of the transparent substrate is less than 5�. To obtain the above-mentioned alignment of the discotic liquid crystal molecules, a specific amount of a specific compound is preferably used to cause a phase separation between the compound and the discotic liquid crystal molecules. Examples of the compounds causing the phase separation include a cellulose ester of a lower fatty acid, a fluorine containing surface active agent and a 1,3,5-triazine compound.
The optical compensatory sheet may have a second optically anisotropic layer. The second optically anisotropic layer is also preferably formed from discotic liquid crystal molecules. The discotic liquid crystal molecules are preferably so aligned in the second optically anisotropic layer that an average inclined angle between discotic planes of the discotic liquid crystal molecules and a surface of the transparent substrate is not less than 5�. The inclined angle preferably increases or decreases with increase of a distance from the surface of the transparent substrate to the discotic plane of the discotic liquid crystal molecule.
If the (first) optically anisotropic layer does not require a small (0� to 50) inclined angle, the rubbing treatment or the orientation layer itself is not necessary. Even if the orientation layer is not necessary, an adhesive orientation layer may be provided between a transparent substrate and the (first) optically anisotropic layer. The adhesive orientation layer (described in Japanese Patent Provisional Publication No. 9(1997)-152509) has a function of forming a chemical bond with discotic liquid crystal molecule to improve the adhesion. If the orientation layer is used to improve the adhesion, the rubbing treatment is not necessary.
The stretching direction (the direction of the largest percent of stretch in the case of the unbalanced biaxially stretching process) is preferably parallel to the slow axis of the film after the stretching process. The angle between the stretching direction and the slow axis is preferably less than 10�, more preferably less than 5, and most preferably less than 3�.
Discotic liquid crystal compound (1) The coated layer was heated at 106� C. to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray of 2 J to polymerize the liquid crystal compound and to fix the alignment. Thus an optical compensatory sheet was prepared.
An optical compensatory sheet was prepared in the same manner as in Example 1, except that 0.3 weight part of cellulose acetate butyrate (acetic acid content: 17.5%, butyric acid content: 32.5%, CAB-321-0.1, Eastman Chemical) was used in place of cellulose acetate butyrate (CAB-381-0.5), and the heating temperature for the layer was 123� C.
An optical compensatory sheet was prepared in the same manner as in Example 1, except that 0.3 weight part of cellulose acetate butyrate (acetic acid content: 2.0%, butyric acid content: 52.0%, CAB-553-0.4, Eastman Chemical) was used in place of cellulose acetate butyrate (CAB-381-0.5), the heating temperature for the layer was 112� C., and the exposure of the ultraviolet ray was 1J.
An optical compensatory sheet was prepared in the same manner as in Example 1, except that 0.5 weight part of cellulose acetate butyrate (acetic acid content: 2.5%, butyric acid content: 45.0%, CAB-482-0.5, Eastman Chemical) was used in place of cellulose acetate butyrate (CAB-381-0.5), the heating temperature for the layer was 145� C., and the exposure of the ultraviolet ray was 3J.
An optical compensatory sheet was prepared in the same manner as in Example 1, except that 100 weight parts of the following discotic liquid crystal compound (2) were used in place of the discotic liquid crystal compound (1), and the heating temperature for the layer was 85� C.
An optical compensatory sheet was prepared in the same manner as in Example 1, except that 100 weight parts of the following discotic liquid crystal compound (3) were used in place of the discotic liquid crystal compound (1), the heating temperature for the layer was 124� C., and the exposure of the ultraviolet ray was 1J.
An optical compensatory sheet was prepared in the same manner as in Example 1, except that 100 weight parts of the following discotic liquid crystal compound (4) were used in place of the discotic liquid crystal compound (1), the heating temperature for the layer was 90� C., and the exposure of the ultraviolet ray was 5J.
(Remark) 381: Cellulose acetate butyrate (CAB-381-0.5) PVB: Polyvinyl butyral 321: Cellulose acetate butyrate (CAB-321-0.1) 553: Cellulose acetate butyrate (CAB-553-0.4) 482: Cellulose acetate butyrate (CAB-482-0.5) Angle: Inclined angle of an optical axis (a direction having the minimum retardation value) corresponding to average inclined angle between discotic planes and a surface of the transparent substrate Δnd: Rth retardation value defined by the following formula: Rth = [{(n1 + n2)/2} − n3]� d in which each of n1, n2 and n3 is the principal refractive index of the optically anisotropic layer, n3 is the minimum index, and d is the thickness of the optically anisotropic layer. EXAMPLE 8
(FS-3) The coated layer was heated at 115� C. to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray of 600 mJ per cm2 to polymerize the liquid crystal compound and to fix the alignment. Thus an optical compensatory sheet was prepared.
Discotic liquid crystal compound (5) The coated layer was heated at 180� C. to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray of 600 mJ per cm2 to polymerize the liquid crystal compound and to fix the alignment. Thus an optical compensatory sheet was prepared.
The coated layer was heated at 106� C. to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray of 2 J to polymerize the liquid crystal compound and to fix the alignment. Thus an optical compensatory sheet was prepared.
The coated layer was heated at 115� C. to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray of 600 mJ per cm2 to polymerize the liquid crystal compound and to fix the alignment. Thus an optical compensatory sheet was prepared.
The coated layer was heated at 180� C. to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray of 600 mJ per cm2 to polymerize the liquid crystal compound and to fix the alignment. Thus an optical compensatory sheet was prepared.
The coated layer was heated at 135� C. to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray of 600 mJ per cm2 to polymerize the liquid crystal compound and to fix the alignment. Thus an optical compensatory sheet was prepared.
The coated layer was heated at 106� C. to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray of 2 J per cm2 to polymerize the liquid crystal compound and to fix the alignment. Thus an optical compensatory sheet was prepared.
(MM-2) The coated layer was heated at 120� C. to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray of 600 mJ per cm2 to polymerize the liquid crystal compound and to fix the alignment. Thus an optical compensatory sheet was prepared.
(MP-5) The coated sample was gradually heated, and the change of the liquid crystal phase was observed with a polarizing microscope. As a result, a liquid crystal phase was served in the range of 116 to 180� C.
The sample was quickly cooled to the room temperature. The inclined angle of the optic axis was measured by using an ellipsometer (AEP-100, Shimazu Seisakusho, Ltd.). The angle was 2.9�0.40.
As a result, a liquid crystal phase was observed in the range of 111 to 151� C., and the inclined angle of the optic axis was 2.9�0.70.
As a result, a liquid crystal phase was observed in the range of 126 to 183� C. However, a schlieren texture was observed in the liquid crystal phase. Accordingly, the liquid crystal molecules were not uniformly aligned.
The coated layer was heated at 130� C. to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray of 600 mJ per cm2 to polymerize the liquid crystal compound and to fix the alignment. Thus an optical compensatory sheet was prepared.
The alignment of the optically anisotropic layer was kept after polymerizing the discotic liquid crystal compound and cooling the layer. After heating the layer at 130� C., the optically anisotropic layer was not changed to the liquid crystal state. The inclined angle of the optic axis was measured by using an ellipsometer (AEP-100, Shimazu Seisakusho, Ltd.). As a result, the angle was less than 5�.
An optical compensatory sheet was prepared in the same manner as in Example 86, except that 1 weight part of the following melamine polymer (MP-7) was used in place of the melamine polymer (MP-5). The alignment of the optically anisotropic layer was kept after polymerizing the discotic liquid crystal compound and cooling the layer. After heating the layer at 130� C., the optically anisotropic layer was not changed to the liquid crystal state. The inclined angle of the optic axis was measured by using an ellipsometer (AEP-100, Shimazu Seisakusho, Ltd.). As a result, the angle was less than 5�.
The coated layer was heated at 130� C. for 1 minute to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray of 500 mJ per cm2 to polymerize the liquid crystal compound and to fix the alignment. Thus an optically anisotropic layer was formed to prepare an optical compensatory sheet.
80� or more
Discotic liquid crystal compound (8) The solution was coated on the undercoating layer, and dried. The coated layer was heated at 130� C. for 2 minutes to align the discotic liquid crystal compound. The layer was immediately cooled to the room temperature, and irradiated with an ultraviolet ray of 500 mJ per cm2 to polymerize the liquid crystal compound and to fix the alignment. Thus an optically anisotropic layer (thickness: 1.7 μm) was formed.
The angle dependency of the retardation of the optically anisotropic layer was measured by using an ellipsometer (M-150, Japan Spectrum Co., Ltd.). As a result, the average inclined angle of the discotic liquid crystal compound was 0.2�, and the Rth retardation value was 88 nm.
The contrast ratio of the prepared liquid crystal display of the VA mode was measured at various viewing points. As a result, the viewing angle showing the contrast ratio of 20:1 was 160 � between upward and downward or between leftward and rightward. On the other hand, the viewing angle of the commercially available liquid crystal display of a VA mode (LCD5000) was 120�.
In methylene chloride, 87 weight parts of cellulose triacetate, 10 weight parts of triphenyl phosphate and 3 weight parts of an ultraviolet absorbing agent (TM165, Sumitomo Chemical Co., Ltd.) were dissolved to prepare 18 wt. % (solid content) solution. The solution was cast on a glass plate, and dried at 40� C. for 10 minutes. The formed film (thickness: 100 μm) was separated from the glass plate.
A pressure of 20 Kg/mm2 was applied to the formed film at 145� C. for 20 minutes. Thus an optically biaxial transparent substrate was prepared. The Re retardation of the transparent substrate was 20 nm, and the Rth retardation was 80 nm.
The coating solution of the optically anisotropic layer used in Example 98 was coated on the optically biaxial transparent substrate (coating amount: 3 ml/m2), and dried at the room temperature. The coated layer was heated at 130� C. for 1 minute to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray to polymerize the liquid crystal compound and to fix the alignment.
The angle dependency of the retardation of the optically anisotropic layer was measured by using an ellipsometer (M-150, Japan Spectrum Co., Ltd.). As a result, the average inclined angle of the discotic liquid crystal compound was 0.1�.
The contrast ratio of the prepared liquid crystal display of the VA mode was measured at various viewing points. As a result, the viewing angle showing the contrast ratio of 20:1 was 160� between upward and downward or between leftward and rightward.
In methylene chloride, 85 weight parts of cellulose triacetate, 10 weight parts of triphenyl phosphate and 5 weight parts of an ultraviolet absorbing agent (TM165, Sumitomo Chemical Co., Ltd.) were dissolved to prepare 18 wt. % (solid content) solution. The solution was cast on a glass plate, and dried at 40� C. for 20 minutes. The formed film (thickness: 100 μm) was separated from the glass plate.
A pressure of 20 Kg/mm2 was applied to the formed film at 145� C. for 10 minutes. Thus an optically biaxial transparent substrate was prepared. The Re retardation of the transparent substrate was 50 nm, and the Rth retardation was 120 nm.
The coating solution of the optically anisotropic layer used in Example 98 was coated on the optically biaxial transparent substrate (coating amount: 6 ml/m2), and dried at the room temperature. The coated layer was heated at 130� C. for 1 minute to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray to polymerize the liquid crystal compound and to fix the alignment.
The angle dependency of the retardation of the optically anisotropic layer was measured by using an ellipsometer (M-150, Japan Spectrum Co., Ltd.). As a result, the average inclined angle of the discotic liquid crystal compound was 0.5�.
The solution was coated on the orientation layer, and dried. The coated layer was heated at 130� C. for 1 minute to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray to polymerize the liquid crystal compound and to fix the alignment. Thus an optically anisotropic layer (thickness: 1.2 μm) was formed.
The solution was coated on the orientation layer, and dried. The coated layer was heated at 130� C. for 1 minute to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray to polymerize the liquid crystal compound and to fix the alignment. Thus an optically anisotropic layer (thickness: 1.4 μm) was formed.
The solution was coated on the orientation layer, and dried. The coated layer was heated at 130� C. for 1 minute to align the discotic liquid crystal compound. The layer was irradiated with an ultraviolet ray to polymerize the liquid crystal compound and to fix the alignment. Thus an optically anisotropic layer (thickness: 3.5 μm) was formed.
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optically anisotropic material composed of the sameUS20080023670 *Jul 27, 2007Jan 31, 2008Fujifilm CorporationLiquid crystal composition and anisotropic materialUS20080220246 *Dec 28, 2005Sep 11, 2008Fujifilm CorporationOptical Compensation Sheet, Process for Producing the Same, and Polarizing Plate and Liquid Crystal Display Device Using the SameUS20090002616 *Sep 2, 2008Jan 1, 2009Konica CorporationOptical film and liquid crystal display using the sameUS20090290102 *Sep 8, 2006Nov 26, 2009Fujifilm CorporationTransfer material, process for producing a color filter using the same, a color filter and liquid crystal display deviceUS20100314035 *Dec 16, 2010Konica CorporationMethod for producing vertical alignment liquid crystal displayUS20140184988 *Dec 26, 2013Jul 3, 2014Fujifilm CorporationOptical film, polarizing plate, liquid crystal display, and method of manufacturing optical filmUSRE41679 *Sep 14, 2010Nitto Denko CorporationWide viewing angle polarizer and liquid-crystal display deviceCN101305303BSep 8, 2006Apr 13, 2011富士胶片株式会社Transfer material, process for producing a color filter using the same, a color filter and liquid crystal display deviceCN101401016BMar 13, 2007Oct 20, 2010富士胶片株式会社Optically-compensatory sheet, ellipsoidal polarizing plate and liquid crystal display deviceEP1387210A1 *Jul 21, 2003Feb 4, 2004Eastman Kodak CompanyCompensator layer and liquid crystal cell with such a layerEP1923727A1 *Jan 29, 2004May 21, 20083M Innovative Properties Co.Polymeric Optical FilmWO2003098337A2 *May 16, 2003Nov 27, 2003Fuji Photo Film Co., Ltd.Sptical compensatory sheet and method for preparing optically anisotropic layerWO2003098337A3 *May 16, 2003Apr 15, 2004Fuji Photo Film Co LtdSptical compensatory sheet and method for preparing optically anisotropic layerWO2004036301A1Sep 25, 2003Apr 29, 2004Merck Patent GmbhCompensated liquid crystal display of the bend modeWO2004072701A1 *Jan 29, 2004Aug 26, 20043M Innovative Properties CompanyPolymeric optical filmWO2004104681A1 *May 3, 2004Dec 2, 2004Eastman Kodak CompanyCompensation films for lcdsWO2007029885A1 *Sep 8, 2006Mar 15, 2007Fujifilm CorporationTransfer material, process for producing a color filter using the same, a color filter and liquid crystal display device* Cited by examinerClassifications U.S. Classification349/117International ClassificationG02F1/13363, G02F1/139, C09K19/18, C09K19/34, C09K19/32, C09K19/30, C09K19/40, G02B5/30Cooperative ClassificationG02F2413/105, G02B5/3016, C09K19/40, G02F1/133634, C09K19/32, C09K2019/0429, C09K19/3488, C09K2019/3408, C09K2019/0448, C09K19/18, G02B5/3033, C09K19/3001, G02F1/1393, G02F1/133632, C09K19/3475, C09K19/3477, C09K19/3491European ClassificationC09K19/18, C09K19/40, G02B5/30P1, G02B5/30L, C09K19/32, C09K19/34B8, C09K19/34B5, C09K19/34B4, C09K19/30A, C09K19/34C, G02F1/13363G, G02F1/13363NLegal EventsDateCodeEventDescriptionJul 13, 2000ASAssignmentOwner name: FUJI PHOTO FILM CO., LTD., JAPANFree format text: ASSIGNMENT OF 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Tim Krumrie - Wikipedia
(1960-05-20) May 20, 1960 (age 56)
Mondovi Schools, Mondovi, (WI)
1983 / Round: 10 / Pick: 276
Cincinnati Bengals (1983–1994)
Timothy Alan Krumrie (born May 20, 1960) is a former American football nose tackle who played his entire National Football League career for the Cincinnati Bengals, from 1983 through 1994.
Krumrie was raised on a dairy farm outside of Mondovi, Wisconsin. He played football at Mondovi High School. Also a standout wrestler for the Buffaloes,[1] Krumrie won the heavyweight state title in 1979, the last year all schools were combined in one division.[2]
Each year since 2009, the Tim Krumrie Award is given to the outstanding high school senior defensive lineman in Wisconsin.[3] The award is given by the Wisconsin Sports Network and WisSports.net.[4]
Krumrie attended the University of Wisconsin-Madison, who recruited him as an inside linebacker but switched him to nose tackle.[5] He led the Badgers in tackles all four years he played, and was a three-time All-Big Ten selection. He was the school's all-time leading tackler at the time of his graduation, and currently is third. He still holds the record for most solo tackles in a career at 276.[6]
He was named defensive MVP of the Badgers' 1982 Independence Bowl win over Kansas State. A member of the Wisconsin wrestling team in 1979 and 1980, he finished fifth at the Big Ten Championships as a sophomore heavyweight.
Krumrie was enshrined in the University of Wisconsin Hall of Fame in 1999.[7] He was inducted into the College football hall of fame in 2016.[8]
Krumrie was chosen in the 10th round of the 1983 NFL Draft.[9]
Krumrie was selected to the Pro Bowl twice, in 1987 and 1988, and led the Bengals to one Super Bowl appearance.
He finished his career with 34 sacks and 13 fumble recoveries for 35 return yards in 188 games. At the time of his retirement, his 34 sacks were the fourth highest in franchise history.
Krumrie is perhaps remembered most for the severely broken leg he suffered during Super Bowl XXIII where the Bengals played the San Francisco 49ers. As Krumrie came off a block from 49er offensive linemen Jesse Sapolu and Randy Cross, he went to make a tackle on ballcarrier Roger Craig. When his foot was planted in the ground, the pressure his weight put on his ankle joint caused his lower leg to snap above the joint. The injury was severe enough that an inflatable splint had to be brought out onto the field to stabilize the leg and Krumrie was diagnosed with a broken tibia and fibula. Despite his injury, Krumrie refused to go to the hospital, insisting on staying in the locker room and watching the game on television, only leaving when the paramedics told him he might go into shock. After a 15-inch steel rod was surgically implanted to stabilize the leg, Krumrie was ready by the 1989 regular season.[10][11]
Krumrie played six more years. He led the team with 97 tackles in 1992.
Krumrie concluded his playing career following the 1994 campaign after compiling 1,017 tackles (700 solo), 34.5 sacks (-238.0 yards), 13 fumble recoveries, 11 forced fumbles and 10 passes defensed.
After retiring in 1994, Krumrie joined the Bengals organization as defensive line coach and served in that position from 1995 to 2002. Krumrie was also the defensive line coach for the Buffalo Bills under head coach Mike Mularkey from 2003 to 2005. After his contract was not renewed by Buffalo, he was the defensive line coach for the Kansas City Chiefs until his dismissal on January 5, 2010.
In April 2011, Krumrie joined Jerry Glanville's staff as defensive line coach for the UFL Hartford Colonials.[12]
Krumrie and his wife, Cheryl, have two children, Kelly and Dexter.
Krumrie has become a bicycling enthusiast, recently completing a 112-mile ride over two mountain passes. He rides 25 to 30 miles a day, and runs five to eight miles every other day.[13]
^ https://news.google.com/newspapers?nid=1368&dat=19890118&id=JS4oAAAAIBAJ&sjid=nRIEAAAAIBAJ&pg=6043,3744488
^ http://www.wissports.net/page/show/596788-tim-krumrie-award-defensive-lineman
^ http://www.wissports.net/news_article/show/162314?referrer_id=532521
^ http://www.wissports.net/news_article/show/311951?referrer_id=532625
^ http://www.footballuniversity.org/tim-krumrie
^ http://host.madison.com/wsj/sports/college/football/badgers-football-former-uw-nose-guard-tim-krumrie-elected-to/article_52d68b4c-1d17-515e-8e39-282f124e8e60.html
^ http://www.pro-football-reference.com/players/K/KrumTi00.htm
^ http://si.com/vault/article/magazine/MAG1126640/index.htm
^ http://www.cincyjungle.com/2013/1/24/3908896/bengals-super-bowl-memory-the-tim-krumrie-injury
^ "Tim Krumrie joins Jerry Glanville in UFL". ProFootballTalk NBC. 2011-04-12. ^ http://host.madison.com/sports/columnists/mike_lucas/article_5856b0c0-8836-5fd9-a281-3b8662970e59.html
Krumrie's stats
Krumrie Broken Leg Video--WARNING: GRAPHIC
Retrieved from "https://en.wikipedia.org/w/index.php?title=Tim_Krumrie&oldid=768815783"	Categories: 1960 birthsLiving peopleAll-American college football playersAmerican Conference Pro Bowl playersAmerican football defensive tacklesCincinnati Bengals playersHartford Colonials coachesKansas City Chiefs coachesBuffalo Bills coachesCincinnati Bengals coachesPeople from Eau Claire, WisconsinPeople from Buffalo County, WisconsinPeople from Dunn County, WisconsinPlayers of American football from WisconsinWisconsin Badgers football playersAmerican male sport wrestlersHidden categories: NFL player missing current team parameterInfobox NFL biography articles missing alt text and caption	Navigation menu
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Listen to Confessions of a D-List Supervillain - Audiobook | Audible.com
https%3A%2F%2Fsamples.audible.com%2Fbk%2Fkafr%2F000059%2Fbk_kafr_000059_sample.mp3+flashcontent6MVTYY3E4CB9F6EK962C0
4.40 (2344 ratings)
Dawnatarr says: "Wow. Loved it."
Whispers says: "Not to Shabby"
4.4 (2344 )
4.4 (2164 )
4.4 (2159 )
Creativecolor 12-06-11
Creativecolor 12-06-11 Member Since 2007
Ryan CA, United States 05-22-13
Ryan CA, United States 05-22-13 Member Since 2017
This is a sideways take on the traditional superhero/supervillain story. Some other reviewers have said that lacks originality, but being a comic (ahem, graphic novel) nerd, I consider it a genre. And it's a genre I dig.
This tale follows Cal, a supervillain who is just getting by, but is eminently likeable despite his illicit career path. When his circumstances change and he winds up playing on the good guys' team, he finds all sorts of hurdles. It's a fun story, but that's not to say he doesn't have to deal with some real problems. Still I'd say it's lighthearted overall and an engaging listen.
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Michael New Orleans, LA 10-08-12 Member Since 2014
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Book of Abraham_vi
BrowseInterestsBiography & MemoirBusiness & LeadershipFiction & LiteraturePolitics & EconomyHealth & WellnessSociety & CultureHappiness & Self-HelpMystery, Thriller & CrimeHistoryYoung AdultBrowse byBooksAudiobooksNews & MagazinesSheet MusicBrowse allUploadSign inJoinBook of Abraham1
The worlds wisdom is so sure that theirs is the only translation of the cuts below...The world once was sure that the round earth was flat, and that drowning a person proved the guilt of a witch. How about sticking dolls to get even with your enemy? Then there were those learned men of letters who felt that impaling you on a stare or boiling you in oil would save you from hell; or better yet the most learned doctors of time insisting that Pasture was a quack. Oh WELL...! so much for what the world has thought. These are scan s form the Book of Abraha m, or "Breathing s of the Dead" by secular wisdo m ?
This is a scan of the Egyptian Hieroglyph's with English equivalents.
This is an enlarge ment of the section of the parchment numbered, 7
Leaving us to ask: The BOO K of WHO M ? AS IN DUH!
The Adami c/Angel'ish we call English is the grand key to Joseph s translation s of these parchment s..with study and effort one will eventually begin to get more in touch with the still small voice inside and also find the mind capable of rendering parallel pictorial editorials as did Joseph. I call it the kaleido s c o p e effect...It literally mirrors back many degree s and directions of information.
Print this off and hold it up and look steadily at it for about one minute... then as you look acros s the top of your computer; close your eyes.. and smile...hold that! Close you eyes and keep them closed a few second s and you will smile...
Intellectual argument s are of no avail to the wise Doctors...You see what you see, and that is the end of this page....
More From This UserSkip carouselTHECARPENTER'SSON69a..revisedOct3-2010 ARTICLE VIIIobservation/copy45g846 Confession of Peter..articleVII COPY 45 book of days-vThe Right Arm of God & Arm of The Lord_iv + contact; josephadamsson@yahoo.comthe prince withinadmlan-iiiMeet the Eves iiadams-n-eves adamic language revealed part-i
Sign up to vote on this titleUsefulNot usefulBook of Abraham_vi by joseph_adamson0.0 (0)EmbedDownloadDescriptionBook of Abraham
The worlds wisdom is so sure that theirs is the only translation of the cuts below...The world once was sure that the round earth was flat, and that drowning a person proved the gui...Book of AbrahamThe worlds wisdom is so sure that theirs is the only translation of the cuts below...The world once was sure that the round earth was flat, and that drowning a person proved the guilt of a witch. How about sticking dolls to get even with your enemy? Then there were those learned men of letters who felt that impaling you on a stare or boiling you in oil would save you from hell; or better yet the most learned doctors of time insisting that Pasture was a quack. Oh WELL...! so much for worldly wisdom..Interests: Types, Books - Non-fiction, Religion & SpiritualityRead on Scribd mobile: iPhone, iPad and Android.Copyright: Attribution Non-Commercial (BY-NC)Download as PDF, TXT or read online from ScribdFlag for inappropriate contentShow moreShow less
RelatedTHECARPENTER'SSON69a..revisedOct3-2010 ARTICLE VIIIby joseph_adamsonobservation/copy45g846 Confession of Peter..articleVII COPY 45 by joseph_adamsonbook of days-vby joseph_adamsonThe Right Arm of God & Arm of The Lord_iv + contact; josephadamsson@yahoo.comby joseph_adamsonMore from joseph_adamsonSkip carouselTHECARPENTER'SSON69a..revisedOct3-2010 ARTICLE VIIIobservation/copy45g846 Confession of Peter..articleVII COPY 45 book of days-vThe Right Arm of God & Arm of The Lord_iv + contact; josephadamsson@yahoo.comthe prince withinadmlan-iiiMeet the Eves iiadams-n-eves adamic language revealed part-i

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’String Theory: a Word Game’ for iOS Preview Available Now Contact Us
'String Theory: a Word Game' for iOS Preview Available Now
05 Apr, 2013, 12:30 ET
from Gecko LLC 'String Theory: a Word Game' for iOS Preview Available Now. (PRNewsFoto/Gecko LLC) Facebook Twitter Pinterest
'String Theory: a Word Game' for iOS Preview Available Now. (PRNewsFoto/Gecko LLC)
COLORADO SPRINGS, Colo., April 5, 2013 /PRNewswire/ -- Love word games? Tired of waiting on your friends? String Theory: a Word Game challenges players to spell as many words as they can before time runs out. String Theory: a Word Game, created by Gecko LLC, is available for preview for all iOS devices now, and will be available worldwide in the App Store on April 30, 2013.
(Photo: http://photos.prnewswire.com/prnh/20130405/AQ89450) Players spell words on the game board using letters in order from the letter deck. Each time the string makes a complete pass across the board, all the words spelled during that pass get scored and cleared from the board. Players get a limited number of passes of the string with which to spell words, but can earn more during game play by activating specials.
Feature Highlights:* Unique mix of Word Play and Action* Enhanced dictionary includes over 170,000 words* Four Unique Game Play Modes* Fast Paced and Exciting* 18 Different Specials - earn Extra Points!* Share with Facebook, Twitter, and E-Mail
String Theory: a Word Game is available now as a preview on TestFlight: http://tflig.ht/VpDP0w. String Theory will be available in the App Store Worldwide on April 30, 2013 for an introductory price of $0.99 in the US and is priced accordingly in other regions.
Please visit www.southwestgecko.com/StringTheory for more String Theory: a Word Game information, including videos and screenshots of the app. A press kit is available at www.southwestgecko.com/Press
String Theory: a Word Game is developed by Gecko LLC, a mobile app company founded in 2012.
If you would like further information on String Theory: a Word Game or Gecko LLC, or you would like to schedule an interview, please contact:Erik ErbenPhone: (719) 425-9745Email: erik <at> southwestgecko <dot> com
String Theory: a Word Game is available now as a preview via TestFlight: http://tflig.ht/VpDP0w
SOURCE Gecko LLC RELATED LINKS
http://www.southwestgecko.com

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Emerald Green Earrings Silver Two Tier Sterling Silver | Etsy
Materials: glass gem stone pendant, emerald green, connector block, emerald green glass, bezel setting, sterling silver earwires, silver plated, rhodium plated
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Solyndra Executives to Invoke Fifth Amendment Rights - The New York Times
Environment|Solyndra Executives to Invoke Fifth Amendment Rights
By MATTHEW L. WALDSEPT. 20, 2011
WASHINGTON — The top two executives of a solar-energy company that filed for bankruptcy after getting $528 million in loan guarantees from the Obama administration said Tuesday that they will invoke their constitutional rights against compelled self-incrimination when they appear at a Congressional hearing.The chief executive of Solyndra, Brian Harrison, and Bill Stover, the chief financial officer, hired lawyers in preparation for the hearing this week before the House Energy and Commerce committee and got advice not to say anything, according to a representative of the lawyers.The offices and the homes of some executives of Solyndra, a California solar-panel manufacturer, were recently raided by the F.B.I. as part of a criminal inquiry into the bankruptcy. The company said in a statement that it was “not aware of any wrongdoing by Solyndra officers, directors or employees in conjunction with the DOE loan guarantee or otherwise.”In the wake of the bankruptcy filing, the Republican leaders of the committee asked the Department of Energy on Tuesday not to rush to give out loan guarantees for clean-energy projects in the final days of the program. But the department said it had already weeded out the projects that it would not have time to finish by the deadline, Sept. 30, and would press ahead with the others. Continue reading the main story
Republicans maintain that the department rushed through the approval of the loan to Solyndra for political reasons. They have released internal Obama administration e-mails that show that the White House was eager to have Vice President Joseph R. Biden Jr. announce the deal in part because it would show action on creating jobs.
The committee chairman, Representative Fred Upton of Michigan, and two subcommittee chairmen wrote to Energy Secretary Steven Chu that his agency’s haste had hurt “the quality and comprehensiveness” of the due diligence performed by the department and the Office of Management and Budget, which had to sign off on the loans. The department has been approving new loans at an accelerated pace in the last three months, the Republicans said.
“We are concerned that another rush to meet stimulus deadlines will result in DOE closing these deals before they are ready,” the chairmen wrote.According to the Energy Department, 18 loan deals have been completed, for a total of $8.5 billion, and there are “conditional commitments” for 14 other projects with a total value of $9.3 billion. The department said in a statement, “We are committed to ensuring that every deal closed before September 30 is fully vetted and will not close any deal that has not received full due diligence by September 30.”It added, “Every agreement in our portfolio has undergone many months of extensive review and evaluation before a conditional commitment is signed.”
A version of this article appears in print on September 21, 2011, on Page A17 of the New York edition with the headline: Solyndra Executives to Invoke Fifth Amendment Rights. Order Reprints| Today's Paper|Subscribe

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IQ GM1 vs Sony RX100ii: Micro Four Thirds Talk Forum: Digital Photography Review
IQ GM1 vs Sony RX100ii 8 months ago
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Rookie's Career Path Leads Back Home - The New York Times
Archives|Rookie's Career Path Leads Back Home
https://nyti.ms/29o9Arr
Rookie's Career Path Leads Back Home
By VINCENT M. MALLOZZI NOV. 4, 1990
November 4, 1990, Page 012001Buy Reprints The New York Times Archives
TATE GEORGE grew up in Newark, and, at least half-heartedly, became a New Jersey Nets fan.
"My parents were very protective of my brother and I," Mr. George said. "They didn't want us to go over to New York and watch the Knicks play. That was just out of the question. So we went to a lot of Nets games, and we just kind of rooted for them. It's kind of strange how things work out."
Mr. George put it all in perspective. "The Nets are now rooting for me," he said.
Mr. George, a 22-year-old, 6 foot 5 inch guard who was a standout at the University of Connecticut, was selected by the Nets in the first round of the National Basketball Association draft in June. Homecoming and Back Patting
He recently signed a five-year contract with the Nets and began working out with the team when it opened its training camp on Oct. 5 at Princeton. And when the Nets play their home opener at the Meadowlands on Thursday against the Miami Heat, it will be a homecoming for Mr. George, a time to see family and friends.
"I was driving around the other night, just thinking about how far I've come in the last few months," said Mr. George, who grew up in the Vailsburg section of Newark. "For the first time in my life, I felt like patting myself on the back."
Indeed, Mr. George, who was a first team all-State and all-City player at Union Catholic High School in Scotch Plains just four years ago, has come a long way.
Though he was ranked among the top 100 recruits and top 25 players in the East in the 1985-86 season at Union Catholic, Mr. George said that he was never heavily recruited. "There were other guys I played with in high school and in summer leagues who were given much more attention," he said. "Most of them, I thought, had a better chance of making it to the pros than I did."
Nonetheless, Mr. George possessed Division I talent, playing in the Big East Conference. It was not long before he established himself as the floor leader for the University of Connecticut Huskies, displaying deft ball-handling skills and a fine shooting touch.
"In college, I thought Tate was a good team player," said Bill Fitch, the Nets coach. "I didn't think he stood out as a superstar, but more of a cerebral player. He knows that basketball is a team game."
In his freshman year at Connecticut, Mr. George and the Huskies suffered through a dismal season in which the team finished 9-19. The next two seasons, Connecticut won a combined 38 games, and both times earned a trip to the National Invitation Tournament.
In Mr. George's senior year, the Huskies blossomed into a national power, finishing with a 31-6 record, and for the first time since the 1978-79 season, earned a bid to the National Collegiate Athletic Association championship tournament.
"He's coming from a program where he learned what it takes to win," Mr. Fitch said. "He is well aware that there is a lot of competition at his spot, and knows that he will be playing behind a couple of people. But I like his attitude. He's willing to sit and learn."
It was during the N.C.A.A. tournament last year, in a nationally televised East Regional semifinal game at the Meadowlands, that Mr. George enjoyed his greatest moment as an athlete. 'The Shot' Still Talked About
With Connecticut trailing Clemson by a point and just seconds left on the clock, Mr. George took a full-court pass from Scott Burrell in the right corner, turned swiftly, and with the clocking winding down, scored to give the Huskies a 1 point victory. In the next round, Connecticut lost to Duke in overtime. But on the Storrs campus in Connecticut, they are still talking about "the shot."
"I think CBS was covering that game and so I guess that shot really put me into the spotlight, and really gave my career a boost" Mr. George said. "But once the season ended, and I got to the pro camps, it meant nothing. Whether I hit that shot or not, I still had to prove myself."
And he did. In April and May, at all-star games in Denver, Portsmouth, N.H.; Orlando, Fla., and Chicago, Mr. George excelled, raising his market value along the way. 'A Very Good Senior Year'
"He had a very good senior year after so-so sophomore and junior years," said Marty Blake, the director of scouting services for the N.B.A. "He also helped himself considerably by playing well in all those postseason tournaments.
"Now don't expect this kid to come in right away and play a lot. No way, the players in this league are too good. But give him time. He can shoot the ball, he's a big point guard, has good hands, and plays good defense. In time, he ought to help the Nets."
<> <> In the weeks before the draft, Mr. George spoke with several other teams, and all expressed interest in drafting him. "I talked to the Los Angeles Lakers, the San Antonio Spurs and the Detroit Pistons," he said. "And all of them said that if I was still available in the draft when their turn came up, they would take me."
But when the Nets, who picked Derrick Coleman, a forward from Syracuse University, as the No. 1 pick over all, found themselves with the 22d pick later in the first round, they chose Mr. George.
"It was really a dream come true," he said. "Everyone, including me, is excited about this."
Mr. Fitch, however, warned that rushing any rookie along, especially a hometown product, could be detrimental to his growth and maturation as a player. 'We Want Tate'
"Anytime you get a hometown boy, patience is something you have to consider," Mr. Fitch said. "It won't be long before people at the Meadowlands start chanting, 'We want Tate! We want Tate!' But it's important for him to understand his position here, and learn our system slowly. A guy like Coleman will be thrown into this thing immediately, because we need help at his position. But we have two or three guys who can play guard, so we don't have to rush Tate along."
Mr. George, who was eager to start his first professional season, kept in shape before the start of training camp by running, working out with weights and playing against his brother, Eric, who plays basketball for Kean College in Elizabeth.
"I've really been working on all aspects of my game," Mr. George said. "I'm not intimidated by going to play in the N.B.A.; in fact, I'm looking forward to it. The only thing I'm concerned with is the long schedule, being ready to play 82 games. It's not that easy." Hoping to Make an Impact
Having helped Connecticut transform itself into a legitimate contender, Mr. George is hoping to make that kind of impact with the Nets, who have not reached the playoffs since the 1985-86 season, back when he was making a name for himself in high school.
"They haven't exactly been winning. But when I used to watch them, they had guys like Sugar Ray Richardson and Dr J., guys who made the team a lot better."
And Mr. George, who used to cheer for players like that, gets his own chance to contribute, and even gets to visit the Knicks in New York.
And this time around, his parents probably will not mind him traveling so much. After all, he does have a contract.
A version of this article appears in print on November 4, 1990, on Page 12012001 of the National edition with the headline: Rookie's Career Path Leads Back Home. Order Reprints| Today's Paper|Subscribe


text:
Hattie Jones Goodwin (1876-1919) - Find A Grave Memorial
Hattie Jones Goodwin
Birth 1 Sep 1876
Death 14 Jan 1919
Memorial ID 42766422
Find A Grave Memorial 42766422
Find A Grave, database and images (https://www.findagrave.com : accessed ), memorial page for Hattie Jones Goodwin (1 Sep 1876–14 Jan 1919), Find A Grave Memorial no. 42766422, citing Oak Hill Cemetery, Elk City, Montgomery County, Kansas, USA ; Maintained by fpw (contributor 47044704) .
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I thought you might like to see a memorial for Hattie Jones Goodwin I found on Findagrave.com.

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The data is in: Fox News may have kept millions from taking the coronavirus threat seriously - The Washington Post
The exterior of Fox News’ headquarters in New York, bearing the faces of five of its biggest stars — Bret Baier, Martha MacCallum, Tucker Carlson, Laura Ingraham and Sean Hannity. (Drew Angerer/Getty Images)
June 28, 2020 at 7:00 AM EDT
From March: Rupert Murdoch could save lives by forcing Fox News to tell the truth about coronavirus — right now

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The Plough Inn: Board Committees & Members - Bloomberg
October 17, 2017 11:00 PM ET
Company Overview of The Plough Inn
To contact The Plough Inn, please visit . Company data is provided by S&P Global Market Intelligence. Please use this form to report any data issues.

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text: 3.0 out of 5 (4,794 reviews) Great spot they are very good at making you feel comfortable and the bar and resterant is amazing also

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Library fine - definition of library fine by The Free Dictionary
https://www.thefreedictionary.com/library+fine
Dictionary, Encyclopedia and Thesaurus - The Free Dictionary 11,000,034,616 visitors served
Noun 1. library fine - fine imposed by a library on books that overdue when returned
Tenders are invited for provide and maintain a cost-effective point-of-sale (pos) cash drawer solution for handling library fine and fee payments and waivers at its libraries; and a cost-effective, user-friendly online fine payment system that allows library customers to pay fines online via a pci-compliant, secure site using a credit card, per specifications.
Point Of Sale And Online Payment Solution
Their images show the abandoned library - including ticket stubs for a 5p library fine - almost exactly how it was left when it closed its doors in 2006.
Leftto rot - but now a new chapter starts for old library; AFTER DECADES OF DECAY, LISTED BUILDING LOOKS TO FUTURE AS CHARITY BASE
The Guinness Book of Records said the largest library fine to be paid was PS203.
The first person to check in at the teen book club on Thursday gets a prize; whoever checks in at the most computer classes in January gets 30 minutes of one-on-one time with the IT trainer; the mayor gets a one-time library fine waiver.
During academic year 06-07 staff handled over 250,000 print account credits and library fine payments totalling over GBP403,000.
Liverpool John Moores University signs contract with Salford Software to implement GPAS ePayments
Their haunting images show the abandoned library - including ticket stubs for a 5p library fine - almost exactly how it was left.
Revealed: eerie old city library; JOSH PARRY MEETS TWO MEN WHO EXPLORED INSIDE ABANDONED LANDMARK
If a little green man slips it into his pocket and doesn't return it on time, it could be the biggest library fine on record.
Rampaging rhinos in Paisley High Street, Pink Floyd's drug dealer polishing armadillos and a demand for a library fine played out as a Shakespearean tragedy were highlights.
Paul Merton's Impro Chums Glasgow Comedy Festival, King's Theatre, Glasgow
I hadn't even paid my library fine - damn, my mum would go bananas.
Scream if you want to get off; Drayton Manor Park unveiled G Force, their newest white-knuckle ride yesterday, with fireworks and pop group G4 celebrating its arrival. Emma Pinch buckled up and tried to enjoy the ride
Word of her arrest has sparked massive interest, with some residents complaining about the use of taxpayers' money to round up library fine dodgers.
BOOK HER; Girl arrested, cuffed and taken to jail... for not paying fines on two overdue library books
99 library fine for losing a guidebook on holiday has got a refund - after it was found a month later by the senior branch assistant on her annual break.
A FINE ENDING; REFUND
There is no need to check the book out or renew it - and no risk of a library fine.
Professor Andrew Prescott: University View

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April 24, 2008 - 4 went
Mellow Evening Hike from Eagle River Nature Center
Added by A former member on Apr 25, 2008.
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The Eastern Bank by James Norbury, Paperback | Barnes & Noble
James NorburyJames Norbury
There is a place where three titanic Corporations are forced to exist in fatal proximity, locked in a bitter struggle for territory, resources, and dominance. Where uncertain allies and lethal enemies battle from darkened boardrooms to bloodstained streets. Where the balance of power lies upon the edge of a knife. Where the sound of a single gunshot could ignite the
There is a place where three titanic Corporations are forced to exist in fatal proximity, locked in a bitter struggle for territory, resources, and dominance. Where uncertain allies and lethal enemies battle from darkened boardrooms to bloodstained streets. Where the balance of power lies upon the edge of a knife. Where the sound of a single gunshot could ignite the fires of war across the entire world. There is a place where the vestiges of government, desperate to retain control, have forced through devastating new laws that will see you dead for the slightest transgression. Where barely-human killing machines stalk the streets as judge, jury, and executioner. Where there is no appeal, and where you are always being watched.There is a place where failure is unthinkable, for the repercussions could be disastrous for your Corporation and fatal for you. Where the lethal weight of the law is just one more weapon your rivals will seek to use against you. Where you must fight in the shadows, and leave no trace of your victims. Where you absolutely must not get caught... whatever the cost.The place is the theatre for your next assignment, Agent.

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