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Patent US6616151 - Apparatus for gliding over snow - Google PatentsSearch Images Maps Play YouTube News Gmail Drive More »Sign inPatentsA universal snow boot and binding for use in connection with either snow skiing or snow boarding which is easy to use and provides quick, easy and positive interconnection of the snow boot with the upper surface of the ski or snowboard. The snow boot or foot enclosure component of the invention carries...http://www.google.com/patents/US6616151?utm_source=gb-gplus-sharePatent US6616151 - Apparatus for gliding over snowAdvanced Patent SearchTry the new Google Patents, with machine-classified Google Scholar results, and Japanese and South Korean patents.Publication numberUS6616151 B1Publication typeGrantApplication numberUS 09/969,805Publication dateSep 9, 2003Filing dateOct 2, 2001Priority dateOct 2, 2001Fee statusLapsedAlso published asUS20030164599Publication number09969805, 969805, US 6616151 B1, US 6616151B1, US-B1-6616151, US6616151 B1, US6616151B1InventorsEugene GollingOriginal AssigneeEugene GollingExport CitationBiBTeX, EndNote, RefManPatent Citations (19), Referenced by (22), Classifications (15), Legal Events (4) External Links: USPTO, USPTO Assignment, EspacenetApparatus for gliding over snow
US 6616151 B1Abstract
A universal snow boot and binding for use in connection with either snow skiing or snow boarding which is easy to use and provides quick, easy and positive interconnection of the snow boot with the upper surface of the ski or snowboard. The snow boot or foot enclosure component of the invention carries a permanent magnet that engages a metal plate provided on the snowboard. The mechanical locking mechanism that is operated by the user is also strategically mounted on the snowboard. The mechanical locking component includes a toe locking mechanism and a cooperating heel locking mechanism that is easily operable to enable the snow boot to be readily disconnected from the upper surface of the snowboard or snow ski.
I claim: 1. An apparatus for gliding over snow comprising:
(a) at least one foot enclosure assembly having a toe portion and heel portion and including a magnet affixed thereto intermediate said toe portion and said heel portion; (b) at least one support base having an upper surface and a lower snow-engaging surface; (c) connector means connected to said support base for releasably interconnecting said foot enclosure assembly with said support base, said connector means including: (i) a frame connected to said support base and having a first end and a second end; and (ii) heel securement means connected to said frame for securing said heel portion of said foot enclosure assembly within said frame, said heel securement means comprising: a. a ferrous metal plate affixed to said frame intermediate said first and second ends, said ferrous metal plate being engageable by said magnet affixed to said foot enclosure assembly; b. heel locking means connected to said frame proximate said first end for locking engagement with said heel portion of said foot enclosure assembly, said heel locking means comprising a locking pin an upstanding heel receiving block connected to said support base, said block having a concave surface for receiving said heel portion of said foot enclosure assembly and including a bore therethrough for telescopically receiving said locking pin; and (iii) toe securement means connected to said frame proximate said second end thereof for securing said toe portion of said foot enclosure assembly within said frame. 2. The apparatus as defined in claim 1 in which said foot enclosure assembly includes a generally “U” shaped heel locking member affixed to said heel portion of said foot enclosure assembly, said heel locking member having an opening therein for telescopically receiving said locking pin, said locking means further including finger gripping means connected to said locking pin for moving said locking pin relative to said opening in said heel locking member.
3. The apparatus as defined in claim 1 in which said foot enclosure assembly includes a toe locking member having a locking tab and in which said toe securement means comprises a locking element having an opening for receiving said locking tab of said toe locking member.
4. The apparatus as defined in claim 1 in which said foot enclosure assembly includes a second magnet and in which said toe securement means comprises a second ferrous metal plate engageable by said second magnet.
5. The apparatus as defined in claim 1 in which said frame includes positioning means engageable by said foot enclosure assembly for positioning said foot enclosure assembly within said frame.
6. The apparatus as defined in claim 1 in which said frame further includes adjustment means for adjustably interconnecting said frame with said support base.
7. The apparatus as defined in claim 6 in which said frame is provided with a central opening and in which said adjustment means comprises a generally disk shaped connector member rotatably mounted within said central opening.
8. The apparatus as defined in claims 7 further including threaded connectors carried by said connector member for interconnecting said connector member with said support base.
9. An apparatus for gliding over snow comprising:
(a) at least one foot enclosure assembly having a toe portion and heel portion and including: (i) a magnet affixed thereto intermediate said toe portion and said heel portion; and (ii) a heel locking member affixed to said heel portion, said heel locking member having an opening therein; and (iii) a toe locking member affixed to said foot enclosure assembly proximate said toe portion, said toe locking member having a locking tab; (b) at least one support base having an upper surface and a lower snow-engaging surface; (c) connector means connected to said support base for releasably interconnecting said foot enclosure assembly with said support base, said connector means including: (i) a frame connected to said support base and having a first end and a second end; (ii) a ferrous metal plate affixed to said frame intermediate said first and second ends, said ferrous metal plate being engageable by said magnet affixed to said foot enclosure assembly; (iii) heel locking means connected to said frame proximate said first end for locking engagement with said heel portion of said foot enclosure assembly said heel locking means comprising an upstanding heel receiving block connected to said support base, said heel receiving block having a bore therethrough, said heel locking means further comprising: a. a locking pin having a locking tongue telescopically receivable within said bore of said upstanding heel receiving block and within said opening of said heel locking member; and b. finger gripping means connected to said locking pin for moving said locking pin relative to said opening in said heel locking member; and (iv) toe securement means connected to said frame proximate said second end for locking engagement with said toe portion of said foot enclosure assembly, said toe securement means comprising a locking element having an opening for receiving said locking tab of said toe locking member. 10. The apparatus as defined in claim 9 in which said frame includes positioning means engageable by said foot enclosure assembly for positioning said foot enclosure assembly within said frame, said positioning means comprising a pair of upstanding locating pins.
11. The apparatus as defined in claim 10 in which said frame further includes adjustment means for adjustably interconnecting said frame with said support base.
12. The apparatus as defined in claim 11 in which said frame is provided with a central opening and in which said adjustment means comprises a generally disk shaped connector member rotatably mounted within said central opening.
13. The apparatus as defined in claim 12, further including threaded connectors carried by said connector member for interconnecting said connector member with said support base.
14. An apparatus for gliding over snow comprising:
(a) at least one foot enclosure assembly having a toe portion and heel portion and including: (i) a magnet affixed thereto intermediate said toe portion and said heel portion; and (ii) a heel locking member affixed to said heel portion, said heel locking member having an opening therein; and (iii) a toe locking member affixed to said foot enclosure assembly proximate said toe portion; (b) at least one support base having an upper surface and a lower snow engaging surface; (c) connector means connected to said support base for releasably interconnecting said foot enclosure assembly with said support base, said connector means including: (i) a frame connected to said support base and having a first end and a second end, said frame further including adjustment means for adjustably interconnecting said frame with said support base; (ii) a ferrous metal plate affixed to said frame intermediate said first and second ends, said ferrous metal plate being engageable by said magnet affixed to said foot enclosure assembly; (iii) heel locking means connected to said frame proximate said first end for locking engagement with said heel portion of said foot enclosure assembly, said heel locking means comprising an upstanding heel receiving block connected to said support base, said heel receiving block having a concave surface for receiving said heel portion of said foot enclosure assembly and having a bore therethrough, said locking means further including: a. a locking pin having a locking tongue telescopically receivable within said opening of said heel locking member; and b. finger gripping means connected to said locking pin for moving said locking pin relative to said opening in said heel locking member; and c. toe locking means connected to said frame proximate said second end for locking engagement with said toe locking member of said foot enclosure assembly. 15. The apparatus as defined in claim 14 in which said toe locking member comprises a second magnet and in which said toe locking means comprises a second ferrous metal plate affixed to said frame intermediate said first and second ends, said ferrous metal plate being engageable by said second magnet.
16. The apparatus as defined in claim 14 in which said toe locking member comprises a locking member having a locking tab and in which said toe locking means comprises a locking element having an opening for receiving said locking tab of said locking member.
17. The apparatus as defined in claim 14 in which said finger gripping means comprises a finger gripping lever pivotally connected to said heel receiving block and to said locking pin for movement between an upward position wherein said locking pin is received within said opening in said heel locking member and a downward position wherein said locking pin is retracted from said opening and said heel locking member.
18. The apparatus as defined in claim 14 in which said frame is provided with a central opening and in which said adjustment means comprises a generally disk shaped connector member rotatably mounted within said central opening.
19. The apparatus as defined in claims 18 further including threaded connectors carried by said connector member for interconnecting said connector member with said support base.
20. The apparatus as defined in claims 19 in which said connector member includes a slot and in which said threaded connectors carried by said connector member are disposed within said slot.
A substantial improvement in snowboard, boots and bindings is described in U.S. Pat. No. 6,224,086 B1 issued to the present inventor. The novel apparatus of the invention described in this patent comprises a unique snow boot binding in which only magnetic forces are used to removably affix the snow boot to a ski or snowboard. The apparatus also includes novel means for quickly and easily disconnecting the snow boot from the upper surface of the snowboard or snow ski, which carries the magnetic elements of the apparatus. In one form of the invention this novel release mechanism comprises an easy-to-use, hand-operated lever which enables the skier or the snow-boarder to quickly and easily disconnect the snow boot from the upper surface of the ski or snowboard.
It is an object of the present invention to provide a universal snow boot and binding for use in connection with either snow skiing or snow boarding which is easy to use and provides quick, easy and positive interconnection of the snow boot with the upper surface of the ski or snow-board. More particularly, it is an object of the invention to provide a highly novel snow boot and binding in which magnetic forces in cooperation with a novel mechanical locking mechanism are used to removably affix the snow boot to the ski or snowboard.
FIGS. 1A and 1B, when considered together, comprise a top plan view of one form of the apparatus of the invention for gliding over the snow.
FIGS. 7A and 7B, when considered together, comprise an enlarged cross-sectional view taken along lines 7—7 of FIG. 6.
FIG. 8 is a cross-sectional view taken along lines 8—8 of FIG. 7A.
FIG. 11 is a cross-sectional view taken along lines 11—11 of FIG. 10A.
Referring to the drawings and particularly to FIGS. 1 through 13, one form of the apparatus of the invention for gliding over snow is there shown. In this form of the invention, the principal cooperating components comprise a support base 14, a pair of identical foot enclosure assemblies 16, and connector means connected to the support base for releasably interconnecting the foot enclosure assemblies with the support base. Support base 14 includes an upper surface 14 a and a lower surface 14 b and, in the form of the invention shown in FIGS. 1 through 13, comprises a snowboard.
Referring to FIGS. 3, 6, 7A and 7B the foot enclosure assembly 16 of the present invention can be seen to comprise a snow boot-like foot enclosure 26 having a heel portion 26 a and a toe portion 26 b. As best seen in FIG. 3 magnet 22 is affixed to the lower surface of the foot enclosure means intermediate the heel portion and the toe portion. For a purpose presently to be described, a toe locking member 28 having an outwardly extending locking tab 28 a is affixed to the lower surface of the foot enclosure means proximate the toe portion. Also affixed to the lower surface of the foot enclosure means proximate the heel portion thereof is foot enclosure locking means for releasably locking the heel portion of the foot enclosure means to support base 14. This means here comprises a generally “U” shaped heel-locking member 30 having an opening or bore 32 therethrough.
Turning to FIG. 2, one of the two identical connector means of the invention for releasably interconnecting the entire foot enclosure assemblies 16 with the support base 14 can be seen to comprise an elongated frame-like assembly 34 having a first end 34 a and a second end 34 b. Each of the assemblies 34 is adjustably connected to support base 14 by two sets of threaded connectors 33.
The heel securement means of the invention also includes heel locking means for locking engagement with the heel portion of one of the foot enclosure assemblies 16. Each of the identical heel locking means here comprises an upstanding heel-receiving block 40 that is connected to base portion 35 of its respective frame assembly 34. Block 40 has a concave surface 42 and a bore 44 there through for telescopically receiving the locking tongue end portion 46 a of an elongated, generally cylindrically shaped locking pin 46 that is carried by block 40. (See FIGS. 4, 5, 7A, 8 and 9). Also comprising a part of the heel locking means of the present invention is finger gripping means that includes a finger gripping lever 50 having a yoke portion 50 a that is pivotally connected to heel receiving block 40 and to locking pin 46 by means of connecting links 52 and 54 respectively. As best seen in FIG. 8, a transverse pin 55 interconnects link 54 with locking pin 46. With this construction, lever 52 can be moved between the upward, boot locking position shown and FIGS. 7A and 9, wherein end 46 a of the locking pin is received within opening 32 of locking member 30 and the downward release position shown in FIGS. 2, 4, 10A and 12 wherein the end of the locking pin is retracted from opening 32.
As is also shown in FIG. 2 each frame assembly 34 includes a generally disk shaped connector member 60 that is roatably mounted within a central opening 63 formed in base portion 37. Connector member 60 comprises a part of the adjustment means of the invention for adjustably interconnecting the frame assemblies 34 with support base 14. More particularly, by loosening threaded connectors 33, the framed assembly can be rotated relative to connector 60 in a manner to vary the angle of the frame assembly with respect to support base 14. Similarly, connector member 60 is provided with a pair of spaced apart parallel slots 62 that receive threaded connectors 36. With this construction, by loosening threaded connectors 33, each connector member 60 can be moved transversely of the support base to adjust the transverse position of frame assembly 34 on the upper surface 14 a on support base 14.
Referring to FIGS. 14, 16, 17 and 18, each of the identical foot enclosure assemblies 70 of the present invention can be seen to comprise a snow boot-like foot enclosure 76 having a heel portion 76 a and a toe portion 76 b. As best seen in FIG. 14, magnet 22 is affixed to the lower surface of the foot enclosure means intermediate the heel portion and the toe portion. For a purpose presently to be described, a second magnet 78 is affixed to the lower surface of the foot enclosure means proximate the toe portion. As illustrated in FIGS. 14 and 17, the foot enclosure assembly is provided with a second threaded bore 80 that receives second threaded stud 82 that functions to connect the generally circular shaped permanent magnet 78 with the foot enclosure assembly. Magnet 78 also comprises a powerful ceramic disk, permanent magnet of a character readily commercially available from various sources including A-L-L Magnetics, Inc. of Palencia, Calif. Also affixed to the foot enclosure means proximate the heel portion thereof is a generally “U” shaped heel-locking member 30 having an opening or bore 32 therethrough.
Affixed to each frame assembly 84 proximate the heel end 84 a is a heel locking means for locking engagement with the heel portion of said foot enclosure assembly and more particularly with locking member 30. This important heel locking means is identical in construction and operation that described in connection with the embodiment of the invention shown in FIG. 1 through 13 and comprises an upstanding heel-receiving block 40 that is connected to base portion 89. Block 40 has a bore 44 therethrough for telescopically receiving the locking tongue end portion 46 a of an elongated, generally cylindrically shaped locking pin 46. (See FIGS. 4, 5, 7A, 8 and 9).
Patent CitationsCited PatentFiling datePublication dateApplicantTitleUS3925911 *Apr 29, 1974Dec 16, 1975Gertsch AgSki bootUS3927897 *Jun 24, 1974Dec 23, 1975Mcneilly Michael AMagnetic release system for snow skisUS4050716 *Mar 19, 1976Sep 27, 1977Tmc CorporationSki bindingUS4140331 *Feb 7, 1977Feb 20, 1979S.A. Des Etablissements Francois Salomon & FilsSports equipmentUS4251090 *Jan 5, 1979Feb 17, 1981Tmc CorporationSafety ski bindingUS4261595 *Mar 22, 1978Apr 14, 1981Smialowski Antoni JSki boot heel lockUS4279433 *Apr 30, 1979Jul 21, 1981Petaja Danny AEmergency locator beacon for skisUS4385773 *Nov 26, 1980May 31, 1983Geze GmbhSki safety bindingUS4465295 *Jan 19, 1984Aug 14, 1984Spademan Richard GeorgeDynamic ski boot positioning apparatusUS4512594 *Aug 31, 1983Apr 23, 1985Eyre Steven CSafety ski bindingUS4589673 *Mar 1, 1983May 20, 1986Salomon S.A.Release mechanism for a ski bindingUS4703946 *Dec 20, 1985Nov 3, 1987Nava & C. S.P.A.Ski attachment deviceUS4917399 *Jun 4, 1987Apr 17, 1990Tmc CorporationLong distance ski bindingUS5143396Jul 25, 1991Sep 1, 1992Gad ShaananBinding for a snowboard and a snowboard incorporating the bindingsUS5143397Aug 3, 1990Sep 1, 1992Marker InternationalSki bindingUS5498017 *Aug 13, 1993Mar 12, 1996Varpat Patentverwertungs AgMonitoring and/or controlling device for a coupling device between a boot and a piece of sports apparatus in particular ski bindingUS5558355Mar 14, 1994Sep 24, 1996Henry; Howarth P.Snowsport bindingsUS5954357 *Apr 9, 1998Sep 21, 1999Golling; Eugene J.Apparatus for gliding over snowUS6224086Mar 18, 1999May 1, 2001Eugene J. GollingApparatus for gliding over snow* Cited by examinerReferenced byCiting PatentFiling datePublication dateApplicantTitleUS6871869 *Jan 31, 2003Mar 29, 2005Shimano Inc.Snowboard bindingUS6983952 *Aug 14, 2002Jan 10, 2006Eugene GollingApparatus for gliding over snowUS8276921 *Sep 4, 2009Oct 2, 2012Brendan WalkerSnowboard bindingUS8469372Oct 22, 2009Jun 25, 2013Bryce M. KlosterSplitboard binding apparatusUS8733783Jun 24, 2013May 27, 2014Bryce M. KlosterSplitboard binding apparatusUS8894075Jan 27, 2012Nov 25, 2014Brendan WalkerBoard sport bindingsUS9138628May 27, 2014Sep 22, 2015Bryce M. KlosterSplitboard binding apparatusUS9238168Feb 8, 2013Jan 19, 2016Bryce M. KlosterSplitboard joining deviceUS9266010Jun 11, 2013Feb 23, 2016Tyler G. KlosterSplitboard binding with adjustable leverage devicesUS9604122Apr 26, 2016Mar 28, 2017Bryce M. KlosterSplitboard joining deviceUS20030047910 *Aug 14, 2002Mar 13, 2003Eugene GollingApparatus for gliding over snowUS20030075890 *Oct 22, 2001Apr 24, 2003Jacobs Robert A.Magnetic skateboard attachment systemUS20030094788 *Jan 8, 2003May 22, 2003Jacobs Robert A.Magnetic snow equipment attachment systemUS20030128862 *Oct 28, 2002Jul 10, 2003Decker Stephen K.Watermark hologramsUS20040104551 *Nov 25, 2003Jun 3, 2004Jacobs Robert A.Magnetic skateboard attachment systemUS20040150192 *Jan 31, 2003Aug 5, 2004Shimano Inc.Snowboard bindingUS20080172905 *Sep 5, 2007Jul 24, 2008United Technologies CorporationMethod and device for collecting metallic debrisUS20090256334 *Apr 14, 2008Oct 15, 2009Lynn HandelTemporary snowboard fastenerUS20100102522 *Oct 22, 2009Apr 29, 2010Kloster Bryce MSplitboard binding apparatusUS20100237599 *Mar 21, 2009Sep 23, 2010Bianchi Steven BMagnetic attachment for board sportsUS20110057420 *Sep 4, 2009Mar 10, 2011Brendan WalkerSnowboard BindingWO2011028656A1 *Aug 30, 2010Mar 10, 2011Brendan WalkerBinding for snowboard and other board sports* Cited by examinerClassifications U.S. Classification280/14.21, 280/617, 280/634, 280/14.24, 280/632International ClassificationA63C10/02, A63C10/18, A63C10/10Cooperative ClassificationA63C10/106, A63C10/10, A63C10/02, A63C10/18European ClassificationA63C10/10, A63C10/10D, A63C10/02Legal EventsDateCodeEventDescriptionMar 9, 2007FPAYFee paymentYear of fee payment: 4Apr 18, 2011REMIMaintenance fee reminder mailedSep 9, 2011LAPSLapse for failure to pay maintenance feesNov 1, 2011FPExpired due to failure to pay maintenance feeEffective date: 20110909RotateOriginal ImageGoogle Home - Sitemap - USPTO Bulk Downloads - Privacy Policy - Terms of Service - About Google Patents - Send FeedbackData provided by IFI CLAIMS Patent Services


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Bracknell Lodge, 5 Frognal Lane, Hampstead, London
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Patent US6631021 - Polyfunctional thiirane compounds - Google Patents
Describes novel polyfunctional thiiranes. Also described are polymerizable compositions comprising such novel polyfunctional thiiranes, and polymerizates, e.g., optical lenses, prepared therefrom. The described polymerizates may have a refractive index of at least 1.6, and an Abbe number of at least...http://www.google.com/patents/US6631021?utm_source=gb-gplus-sharePatent US6631021 - Polyfunctional thiirane compounds
Publication number US6631021 B2
Application number US 09/793,886
Also published as US20020010313, WO2001070722A2, WO2001070722A3
Publication number 09793886, 793886, US 6631021 B2, US 6631021B2, US-B2-6631021, US6631021 B2, US6631021B2
Inventors Robert A. Smith, Michael O. Okoroafor, Marvin J. Graham
Patent Citations (43), Non-Patent Citations (5), Referenced by (14), Classifications (18), Legal Events (4)
Polyfunctional thiirane compounds
US 6631021 B2
1. A polyfunctional thiirane selected from the group consisting of polyfunctional thiiranes represented by the following general formulas:
and mixtures of at least two of (i), (ii), (iii), (iv), (v), (vi), (vii), (viii), (ix), (x) and (xi);
16. The photochromic article of claim 15 wherein the organic photochromic substance is selected from the group consisting of spiro(indoline)naphthoxazines, spiro(indoline)benzoxazines, benzopyrans, naphthopyrans, chromenes, organo-metal dithizonates, fulgides and fulgimides and mixtures thereof.
In accordance with the present invention, there is provided a polyfunctional thiirane selected from polyfunctional thiiranes represented by the following general formulas:
wherein X is selected from S and O the number of functional groups (i.e., functional groups represented by the following general formula I,
wherein X is S constituting at least 50 percent of the total number of such functional groups present in said polyfunctional thiirane; and R1, R2 and R3 are each selected independently for each general formula from the group consisting of straight or branched chain alkylene (usually containing from 1 to 20 carbon atoms, e.g., 1 to 10 carbon atoms, preferably 1 to 4 carbon atoms and more preferably 1 to 2 carbon atoms), cyclic alkylene (usually containing from 5 to 8 carbon atoms), phenylene and C1-C9 alkyl substituted phenylene.
Each of the polyfunctional thiiranes represented by general formulas (i) through (xi) may be prepared as described previously herein from a corresponding polythiol starting material. For example, the polythiol starting materials that are reacted with either an epihalohydrin or 1-halo-2,3-ethylene sulfide in the preparation of the polyfunctional thiiranes represented by general formulas (i) and (viii), may be represented by the following general formulas II and III respectively,
wherein R1, R2 and R3 are as described previously herein.
The polyfunctional thiirane of the present invention, any optional monomers, e.g., monofunctional thiiranes, second polyfunctional thiiranes, polythiols, cyclic anhydrides, epoxide monomers and ethylenically unsaturated monomers, and any additives are typically mixed together in a suitable container. The thermal polymerization catalyst or actinic radiation activated cationic polymerization initiator is then added to the monomer mixture and the polymerizable composition is charged to a mold. The contents of the filled mold are then polymerized either thermally or by exposure to actinic radiation. After completion of polymerization, the polymerizate is typically removed from the mold, and may be further processed (e.g., cut, ground and/or polished) if desired. Thermal polymerization typically involves exposing the filled molds to a controlled thermal cure cycle over a period of at least one hour, e.g., from 1 to 48 hours, and using temperatures ranging from, for example, 25° C. to 200° C.
The actinic radiation used to polymerize the composition may be selected from visible light, ultraviolet (UV) light, electron beam, X-ray radiation, radio frequency radiation and combinations thereof. Preferably the actinic radiation is selected from visible light, UV light and combinations thereof. When polymerized by exposure to actinic radiation, at least a portion of the filled mold is transparent to the actinic radiation, e.g., an ophthalmic lens mold fabricated from quartz glass. The filled mold is exposed to actinic radiation (e.g., having a wavelength of from 250 to 450 nanometers) typically by passing or holding the filled mold under the actinic radiation source, e.g., mercury lamps, xenon lamps, sodium lamps and alkali metal lamps. Concurrent with or following exposure to actinic radiation, the filled mold may optionally be subjected to a thermal co- or post-cure, for example at a temperature of from 70° C. to 150° C., over a period of from 1 to 5 hours.
The TGBMA/epichlorhydrin mixture was cooled to a temperature of less than 0° C. A few drops of 8% NaOH solution were added slowly while maintaining the temperature. After approximately 45 minutes, a slow addition of 8% NaOH solution was initiated. The temperature did not exceed 5° C. After approximately one-half of the equivalent amount of NaOH was added, the exothermic tendency of the reaction was greatly reduced and the remainder of the NaOH was added at a faster rate. The contents were allowed to warm to room temperature overnight with stirring. The product recovered was 125 grams of a white gum. The product theoretically has the following structure.
Conversion of Epoxides to Thiirane
The white gum product (25 grams; 0.144 equivalents of epoxide) was disolved in 250 grams of acetic anhydride; 15 grams (0.144 moles) of thiourea was added and the mixture was stirred. The mixture displayed a moderate exothermic reaction but the temperature was controlled at 30° C. by cooling with an ice bath. After approximately one hour, the exothermic heat evolution ended and the mixture was allowed to stir overnight. The next day a yellow solution containing a white solid was observed. The white solid was removed by filtration. A yellow, gummy solid was obtained by removal of the acetic anhydride on a rotary evaporator. The product theoretically has the following structure.
US4233131 Oct 29, 1979 Nov 11, 1980 Allied Chemical Corporation Process for preparing alkylene episulfides and episelenides
US5973098 Oct 29, 1998 Oct 26, 1999 Essilor International - Compagnie Generale D'optique Polymerizable compositions for making thio containing resins including a thiocyanate salt catalyst and process for making thio containing resin articles
US5973192 Nov 26, 1997 Oct 26, 1999 Hampshire Chemical Corp. Thioglycerol derivatives and their use in polysulfide compositions for optical material
US6117923 * Apr 20, 1998 Sep 12, 2000 Mitsubishi Gas Chemical Company, Inc. Resin for optical material
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EP0874016B1 Apr 21, 1998 Aug 20, 2003 Mitsubishi Gas Chemical Company, Inc. Novel resin for optical material
EP0928802A2 Jan 5, 1999 Jul 14, 1999 Mitsubishi Gas Chemical Company, Inc. Process for tinting a resin having a large refractivity index and optical material tinted by the process
EP0950905A2 Mar 16, 1999 Oct 20, 1999 Mitsubishi Gas Chemical Company, Inc. Process for producing a novel resin for optical materials having excellent color tone and transparency
EP0978513B1 Jul 28, 1999 Oct 2, 2002 Mitsubishi Gas Chemical Company, Inc. Ether compound and cured resin using the same
1 ASTM D-2583-95, Standard Test Method for Indentation Hardness of Rigid Plastics by Means of a Barcol Impressor.
2 ASTM D-542-95, Standard Test Method for Index of Refraction of Transparent Organic Plastics.
3 Chemical Abstract 15407u, Jpn. Kokai Tokkyo Koho JP 11 12,273 [99 12,273], Apr. 28,1989, K. Yamamoto et al., "Episulfides for polymeric optical materials and their preparation", vol 130, 00-00-1999, No. 12.
4 Chemical Abstract 88592b, Jpn. Kokai Tokkyo Koho JP 11 189,592 [99 189,592], Jul. 13, 1999, S. Umeda et al., "Sulfur-containing epoxy compound for thermally stable optical material", vol. 131, 00-00-1999, No. 7.
5 Chemical Abtract 108723a, Jpn. Kokai Tokkyo Koho Jp 11 183,702 [99 183,702], Jul. 9, 1999, M. Okazaki et al., "(Thio)epoxy resin for plastic lens", vol. 131, 00-00-1999, No. 8.
U.S. Classification 359/241, 549/90, 359/243, 528/377, 549/523, 522/168, 549/518, 528/378, 528/380, 549/1, 522/31, 522/170, 359/244, 522/74, 359/242
International Classification C07D331/02
Cooperative Classification C07D331/02
European Classification C07D331/02
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SMITH, ROBERT A.;OKOROAFOR, MICHAEL O.;GRAHAM, MARVIN J.;REEL/FRAME:012015/0700

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Our bedroom was nice but room service ended early... - Review of O'Callaghan Davenport Hotel - TripAdvisor
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Our bedroom was nice but room service ended early... - Review of O'Callaghan Davenport Hotel
JustWilliamtheSecond
In looking at the hotel's web-site before booking, it looked really very nice. The reality wasn't bad but had we known the hotel would be so shabby we would have gone elsewhere. The breakfasts were great and the location for central Dublin was great too. Service at breakfast was slow despite the dining room not being that full. Our bedroom was nice but room service ended early and had a very limited selection to choose from. Could do better.
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Cooley05, Operations Manager at O'Callaghan Davenport Hotel, responded to this reviewResponded July 27, 2013
Dear JustWilliamtheSecond,
Thank you for taking the time to review your stay with us at the O'Callaghan Davenport Hotel.
Although you were disappointed with your stay I am glad to hear that there were some aspects that you did enjoy, including our breakfast. We have just completed a review of our breakfast service and steps are being put in place to improve the speed of service and overall presentation.
We have a continual maintenance program as well as plans for a soft refurbishment in the near future. I hope that if we get the opportunity to welcome you once again that we can change your opinion.
This is our 3rd time using this hotel. We found it comfortable and friendly. On this occasion we stayed for just one night as we were visiting the theatre. Breakfast was good value as we had booked it online and been given an internet rate. We didn't eat in the bar this time as on our last two visits the service was slow and we were almost late for a theatre starting time, however there are plenty of eating places not far away. The Dart is close by and we used it a lot plus there are taxis just outside the door. We would stay here again as it is a good value, convenient hotel and the reception staff are very helpful and we were able to leave our luggage for a departure late in the day.
Ask der R about O'Callaghan Davenport Hotel
Dear der R,
Thank you for taking the time to write a review of your stay at the O'Callaghan Davenport Hotel.
It is great to hear that you have stayed with us so many times and that you would not hesitate to return again. I have taken your comments on board about the slow service that you experienced in the bar and this will brought up at our next departmental meeting.
We do hope to see you again soon in the not so distant future.
Stephen was his name. Quiet thorough and a complete complement to the entire staff. Stephen waited the dining room lounge, served the most delicious scones and tea we encountered during our trip around Ireland. He deserves a extra pat on the back on behalf of your staff.
David James Delaney
P.S. Stephen is no relation.
Ask david d about O'Callaghan Davenport Hotel
It is great to hear such wonderful comments about a member of our staff. I have passed these comments on to Stephen, who is a valued member of the team here at the O'Callaghan Davenport Hotel.
lotoole0968
Comfortable but nothing extraordinary
The staff makes this hotel special. Both front desk and servers in the restaurants are extremely helpful and friendly. I found the rooms/bathrooms quite average and somewhat worn. The beds were not very comfortable and headboards didn't match the mattress (?). Buffet in the morning was adequate. The restaurant/bar in lobby is nice. Internet didn't work well. Location was quite good, within walking distance of most things. Cabs right out front. Overall, a good place to stay in Dublin!
Ask lotoole0968 about O'Callaghan Davenport Hotel
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Dear lotoole0968,
Thank you for taking the time to to review the O'Callaghan Davenport Hotel.
Although I am disappointed to hear that we did not exceed your expectations during you're stay, I am delighted to hear your positive comments about our staff and lobby and bar area.
We do hope we get the opportunity to welcome you back in the near future and hopefully next time we can surpass your expectations.
I stayed 10 days at the Davenport. It was great. Room was comfortable, restaurant delightful. The breakfast buffet was great. Possibly could use a little more variety. The staff was very helpful. The Guinness in the pub was very tasty.
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Cooley05, Operations Manager at O'Callaghan Davenport Hotel, responded to this reviewResponded July 24, 2013
Dear abbypuckett,
Thank you for taking the time to post your review of the O'Callaghan Davenport Hotel.
We are glad that you enjoyed your stay and we hope to welcome you back in the near future
Was a very nice hotel in the heart of where I needed to be in Dublin.
Attended a conference in the Hotel for two days and the food (which I had low expectations of) was really good and offered a wide selection of food during the Conference Lunches.
The Service at Breakfast was a little slow (for instance I was not asked if I wanted Tea/Coffee or what my room number was) but the food was really really nice.
I would stay at the hotel again but if not travelling for work I might find a cheaper option. However, it was really good value for money.
Wish I had used the swimming pool now... (didnt know they had one!)
Ask Alfie-Travelling-Cub about O'Callaghan Davenport Hotel
Dear Alfie-Travelling-Club,
Although disappointed to hear your comments about the service at breakfast, I am pleased to hear the quality and offering at breakfast and lunch exceeded your expectations.
We look forward to welcoming you back to the O'Callaghan Davenport Hotel in the future and please feel free to contact us directly for the best offers.
We recently stayed for 3 nights at the Davenport after 14 days of touring Ireland. We found the rooms clean, comfortable and well apppointed. The service was exceptional! At one point when our electric kettle stopped working, I went to the front desk to request another. The teapot actually was delivered to my wife in the room before I got back there a few minutes later! The breakfast buffet was abundant and had quite a selection. The wait staff was friendly and efficient. When we return to Dublin, we will be staying here again.
Ask David A about O'Callaghan Davenport Hotel
We are delighted to hear you have enjoyed your recent stay with us and that you were truly pleased with the breakfast available at the hotel as well as with the efficient service of our staff.
TripAdvisor is proud to partner with Priceline, Expedia, Travelocity, Hotels.com, Booking.com, Orbitz, TripOnline SA, Hotwire, Cancelon, getaroom.com and HotelQuickly so you can book your O'Callaghan Davenport Hotel reservations with confidence. We help millions of travelers each month to find the perfect hotel for both vacation and business trips, always with the best discounts and special offers.

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text:
Passaic Inventor Thinks He Has Practical Flying Machine; S.D. Mott's Dirigible Aerodrome Model Had Attracted the Interest of the Late Andrew H. Green --- All the Work Done by Propellers -- Bird Flight Imitated. - The New York Times
Archives|Passaic Inventor Thinks He Has Practical Flying Machine; S.D. Mott's Dirigible Aerodrome Model Had Attracted the Interest of the Late Andrew H. Green --- All the Work Done by Propellers -- Bird Flight Imitated.
https://nyti.ms/1ku4flU
Passaic Inventor Thinks He Has Practical Flying Machine; S.D. Mott's Dirigible Aerodrome Model Had Attracted the Interest of the Late Andrew H. Green --- All the Work Done by Propellers -- Bird Flight Imitated.
A FLYING machine which in the opinion of many prominent mechanical experts of this city and vicinity combines eminent practicability with utter simplicity, and which also, they believe, gives decided assurances of success from a commercial as well as a merely spectacular standpoint, has recently been devised by S.D. Mott, an electrical engineer and inventor of a number of electrical appliances, of Passaic, N.J. View Full Article in Timesmachine »
A version of this archives appears in print on January 21, 1906, on Page F3 of the New York edition with the headline: Passaic Inventor Thinks He Has Practical Flying Machine; S.D. Mott's Dirigible Aerodrome Model Had Attracted the Interest of the Late Andrew H. Green --- All the Work Done by Propellers -- Bird Flight Imitated. Order Reprints| Today's Paper|Subscribe

value: This website is an American daily newspaper based in New York City with a worldwide readership. Founded in 1851, the Times has since won 132 Pulitzer Prizes, the most of any newspaper, and has long been regarded within the industry as a national "newspaper of record".


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Solo Chicas♥
Prohibido los hombres sólo chicas
•Dayana •
Solo Chicas♥Debate
Originally shared by goku black el que odia alos humanos - 2 comments
Suscribance porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis se los agradecería mucho porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis Suscribancen
Mis propocitos para el 2016
Suscribance porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis porfis
Hola!!! Un nuevo Aviso importante
Hola chicas un Aviso
Se va hacer un canal de Youtube compartido solo chicas los Requisitos
Tener cel o tablet propia
Edad de 10 a 12 años
Saber editar
Saber suvir videos A Youtube
Ser responsable y tratar de no atrasarse con los videos
Kenzie: +El Mundo de Dayi no me apareces en hangouts
•Dayana •: +Raven Queen™ segura mmm
•Dayana •: +Raven Queen™ ok
Solo Chicas♥Hola
Hola alguna tiene Facebook ??? Yo si
La Lupezz Valencia: Yo tambien Tengo -
•Dayana •: +La Lupezz Valencia como sales
Britany Guevara
Britany Guevara: Si soy nueva un saludo a todas y todos
Britany Guevara: Buenas noches a todas y todos
•Dayana •: +Britany Guevara Bri te hable por Hangoust
Solo Chicas♥Chicas
Hola chicas busco hacer un canal compartido de Youtube
1 Tener telefono o tablet
2 Saber editar
3 Edad de 10 a 13
4 Ser linda
5 Saber sobre Youtube y saber usar cuentas
6 Saber grabar bien
7 Saber subir videos
8 Ser responsable y no atrasarse con el video
•Dayana •: +Roseta KAWAII enserio amiga
Grace: SI
•Dayana •: +Roseta KAWAII ta hablo por Hangoust
Chicas por favor suscribancen se los agradeceria mucho
Barbie {Un día en el parque}
Hola chicas les gustaria hacer un canal de youtube
1 Saber editar
2 Saber subir videos a Youtube
3 Ser linda
4 Saber usar cuentas
5 Edad de 10 a 13 Años de edad
6 Saber sobre Youtube
7 tener tablet o celular
•Dayana •: Compartido
Hola chicas soy Apple White pero con cuenta diferente

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SFEMSUD Quote - Schroder 4 Year Maturity Emerging Market Sovereign Bond Fund - Bloomberg Markets Bloomberg the Company & Its ProductsBloomberg Anywhere Remote LoginBloomberg Anywhere LoginBloomberg Terminal Demo Request Bloomberg
Americas+1 212 318 2000EMEA+44 20 7330 7500Asia Pacific+65 6212 1000 MENU About The Company Bloomberg London Homepage Markets Stocks Currencies Commodities Rates + Bonds Economics Magazine Benchmark Watchlist Economic Calendar Tech U.S. Global Startups Bloomberg Technology TV Gadgets With Gurman Digital Defense Studio 1.0 Focus On: Infrastructure Pursuits Cars & Bikes Style & Grooming Spend Watches & Gadgets Food & Drinks Travel Real Estate Art & Design Brilliant Ideas Politics Global Risk Briefing How We’ll Know if Trump Is Making America Great Again Tracking Trump’s Web of Conflicts GOP’s Health Plan: Tracking Key Changes One Amendment at a Time Kim Jong Un’s Big Nuclear Push Is Closing In on America Opinion View Gadfly Businessweek Latest Issue Debrief Podcast Subscribe More Climate Changed Video Series: Ventures Graphics Billionaires Game Plan Small Business Personal Finance Inspire GO The David Rubenstein Show Sponsored Content Sign In Sign In Subscribe to Businessweek Error: Could not add to watchlist. X + Watchlist Schroder 4 Year Maturity Emerging Market Sovereign Bond Fund SFEMSUD:TT 9.9557USD As of 12:00 AM EDT 6/27/2017 Fund Type Open-End Fund 52Wk Range 9.9426 - 9.9997 Before it's here, it's on the Bloomberg Terminal.
52Wk Range 9.9426 - 9.9997 Fund Type Open-End Fund Objective Emerging Markets Bond Asset Class Focus Fixed Income Geographic Focus Global NAV (on 06/27/2017) 9.9557 Total Assets (TWD) (on -) - Inception Date 06/08/2017 Last Dividend (on -) - Dividend Indicated Gross Yield - Fund Managers - Front Load Fee 2.50% Back Load Fee 2.00% Redemption Fee 2.00% 12b-1 Fee - Current Mgmt Fee 1.00% Expense Ratio - Profile Schroder 4 Year Maturity Emerging Market Sovereign Bond Fund is an open-end fund established in Taiwan. The Fund's objective is to achieve long-term investment gain and to maintain stable income. The weighted average duration of the Fund is greater than 1 year. The Fund invests at least 60% of its total assets in soverign debt securities. Address 9F, 108, Sec.5,Hsin-Yi Road, Hsin-Yi District,Taipei 11047,Taiwan, R.O.C. Phone Tel: +886 2 2722 1868 Website www.schroders.com.tw Terms of Service Trademarks Privacy Policy ©2017 Bloomberg L.P. All Rights Reserved Careers Made in NYC Advertise Ad Choices Website Feedback Help

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'We've Got To Get Better'Eli & Co. understand the offense needs to show improvement. But they aren't buying into the sky-is-falling narrative just yet.
Story �Frustrated! �Wilson runs to track �Beason back? �More Beckham �NYG �
Will the Rangers win their first Stanley Cup since 1994 this season? 65% Yes 19% No 16% Go Isles! (Total votes: 5,119)More Polls »
Tweets fromChoose FilterClear FiltersESPN TalentPlayersMediaKatieStrangESPN Katie StrangSidney Crosby won't make things easy for Rangers - Cross Checks Blog - ESPN http://t.co/6w193Clm22about 2 hours ago ESPNNYYankees wallace matthewsTanaka brings the heat in Yankees win: http://t.co/7zQtlc4EkDabout 2 hours ago AdamRubinESPN Adam RubinA tip of the cap to Alex Torres http://t.co/D8fmvdZFR0 #NYM #Metsabout 3 hours ago AdamRubinESPN Adam RubinMinors 4.18.15: Noah Syndergaard roughed up http://t.co/GIWTNHQRDV #NYM #Metsabout 3 hours ago AdamRubinESPN Adam RubinAnother seven shutout innings for Jacob deGrom http://t.co/bwhf7vIm4T #NYM #Metsabout 3 hours ago AdamRubinESPN Adam Rubin#Mets Minors 4.18.15: Noah Syndergaard roughed up: http://t.co/cq4UfMz3ulabout 3 hours ago stephenasmith Stephen A SmithSurprise of the night: Corey Brewer and Terrence Jones. The Brothers came to play. Give respect where respect is dueabout 4 hours ago ESPNNYYankees wallace matthewsCan't wait to interview @iamjamiefoxx about playing @MikeTyson in an upcoming biopic on Tuesday's Going the Distance https://t.co/L03Jn2fnfrabout 4 hours ago AdamRubinESPN Adam RubinJacob deGrom reacts to his scoreless effort against the Marlins: http://t.co/NxtdRJurIy #metsabout 4 hours ago stephenasmith Stephen A SmithIt'll MAKE YA DRUNK @sneakermac23 @jasonterry31about 4 hours ago stephenasmith Stephen A SmithNot true @J_Fielding0621. But an hilarious statementabout 4 hours ago stephenasmith Stephen A SmithNo excuses from me @JaeB_so_nasty @sherifffruitfly @DemarcoJ9 @RealSkipBayless. I wouldn't mind. Just means I go to Chi instead of Clevelandabout 4 hours ago stephenasmith Stephen A SmithThat's a valid point @Eric_611. Seriouslyabout 4 hours ago stephenasmith Stephen A SmithYet you commented @Tim_Costello. Proud of you bro. Glad to know you can read :/)about 4 hours ago AdamRubinESPN Adam RubinMets LHP Torres 1st to wear exterior-padded cap http://t.co/MKc4BaF6UO #NYM #Metsabout 4 hours ago AdamRubinESPN Adam RubinNoah Syndergaard took scoreless effort into 4th, allowed 2-run HR. Final line: 3.2 IP, 2 H, 2 R, 2 ER, 5 BB, 5 K, 1 HR, 82 pitches.about 4 hours ago stephenasmith Stephen A SmithWhy @JaYHaLL777 @RealSkipBayless. What fun is there in that?about 4 hours ago stephenasmith Stephen A SmithHere comes Montaabout 4 hours ago stephenasmith Stephen A SmithInjury status was determined @obliq74. But then I wouldn't answer your questions and your life would be meaningless :-)about 4 hours ago stephenasmith Stephen A SmithBig-time 3 by Monte Ellis to end the 3rd QT. Could go a long way towards helping Dallas steal this game, but we'll seeabout 4 hours ago ESPNNewYork.com on Twitter »

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text: – What would make a kid’s summer camp purrfect? Yoga with kittens, of course. On the heels of the recent yoga-with-goats trend, Pet Refuge volunteers thought they would try something similar, but with a much smaller, cuddlier twist as part of this year’s first round of Summer Camp Unleashed ... “We want the kids to be aware of all the opportunities out there to work with animals,” Whiteman said....

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Words containing aminel | Words that contain aminel
Words containing aminel | Words that contain aminel http://www.thefreedictionary.com/words-containing-aminelPrinter Friendly
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Found 1 words containing aminel. Browse our Scrabble Word Finder, Words With Friends cheat dictionary, and WordHub word solver to find words that contain aminel. Or use our Unscramble word solver to find your best possible play!
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Belgium PM lauds India's economic progress | india | Hindustan Times
Belgium PM lauds India's economic progress
Today around 500 Indian families control more than 60 per cent of Antwerp's rough and polished diamond trade.
india Updated: May 06, 2006 17:02 IST
Indians have the right economic instinct and India is ready to become a global economic power, according to Belgium's Prime Minister Guy Verhofstadt.
Speaking at the launch dinner of India's ICICI Bank in Antwerp, Verhofstadt also hailed the success of Antwerp as the world's rough diamond capital and the achievements of the Indian business community in the port city.
As the chief guest at the launch on Thursday, Verhofstadt lit the traditional "diya" along with the Indian ambassador to Belgium Dipak Chatterjee and top ICICI management officials, Sonjoy Chatterjee, Lalita Gupte and KV Kamath.
Indian diamond merchants, mainly hailing from the small Gujarati town of Palanpur, arrived in Antwerp in the 70s and globalised the diamond business dominated by Jews since the 15th century.
"I'm delighted that India's top diamond companies have decided to establish a foothold in Belgium. Indeed the Indian community soon developed into the most important economic pillar in the diamond trade," he said.
Today around 500 Indian families control more than 60 per cent of Antwerp's rough and polished diamond trade which posted a collective turnover of $36 billion in the last year and has generated 30,000 jobs, according to INEP agency.
Lauding India's rapid economic growth rate, Verhofstadt said that the fact that India's second largest bank (ICICI) was opening its only branch in continental Europe in Belgium was a confirmation "that the economy of Antwerp and its diamond trade in particular enjoy worldwide recognition".
He said the presence of ICICI bank was a "powerful incentive", urging potential investors from India and worldwide to come to Belgium.
"The ICICI bank will be a new light house, illuminating the path to Belgium for other investors," Verhofstadt said.
Belgium is India's fourth largest import trading partner. Nearly 75 per cent of the bilateral trade between the two countries is conducted through Antwerp's diamond sector.
"Relations with India are very good but I will go back to India at the end of the year. I intend to make relations even better," Verhofstadt said.
The Indian ambassador spoke about growing Belgian-Indian ties and welcomed the opening of one more Indian bank in Belgium.
The State Bank of India already has a foothold in Antwerp's diamond market. The Bank of Baroda also has a branch in Brussels.
First Published: May 06, 2006 17:02 IST

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Alvey Systems, Inc: Private Company Information - Bloomberg
Company Overview of Alvey Systems, Inc
Alvey Systems, Inc provides supply chain solutions. It offers automated materials handling systems for various industrial environments, including manufacturing, distribution, and e-commerce. The company is based in St. Louis, Missouri. Alvey Systems, Inc operates as a subsidiary of Intelligrated Systems Inc.
St. Louis, MO 63132-3299
314-993-4700
314-995-2400
Key Executives for Alvey Systems, Inc
Mr. Matt Wicks
To contact Alvey Systems, Inc, please visit --. Company data is provided by S&P Global Market Intelligence. Please use this form to report any data issues.