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Who and why? HIV-testing refusal during pregnancy: implication for ... - PubMed - NCBI
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See comment in PubMed Commons belowAIDS Behav. 2004 Mar;8(1):25-31.Who and why? HIV-testing refusal during pregnancy: implication for pediatric HIV epidemic disparity.Aynalem G1, Mendoza P, Frederick T, Mascola L.Author information1Los Angeles County Department of Health Services, Acute Communicable Disease Control Program, Pediatric HIV/AIDS Surveillance, California, USA. gaynalem@dhs.co.la.ca.usAbstractTo identify characteristics of pregnant women who refuse HIV testing and determine predictive factors and the reasons for refusal, we conducted face-to-face interviews of pregnant women at prenatal clinics of public and private hospitals. We found 8% (n=65) of 826 pregnant women interviewed refused HIV testing. In bivariate analysis, foreign-born pregnant women residing in Los Angeles County were twice more likely to refuse HIV testing than U.S.-born pregnant women (odds ratio [OR] = 1.97, 95% confidence interval [CI] 1.11-3.49, p <.05). In a multivariate stepwise logistic regression model analysis, variables that were independent predictors of HIV testing refusal during pregnancy were being foreign-born (OR = 2.11, 95% CI 1.07-4.38), not receiving general information about HIV (OR = 7.48, 95% CI 1.86-30.01), and not receiving specific information about HIV and pregnancy (OR = 3.54, 95% CI 1.91-6.57). The most common reasons for testing refusal were being in a monogamous relationship for foreign-born women (41%) and already being tested for U.S.-born women (65%).PMID: 15146131 [PubMed - indexed for MEDLINE] SharePublication Types, MeSH TermsPublication TypesResearch Support, U.S. Gov't, Non-P.H.S.MeSH TermsAdolescentAdultChildChild WelfareCross-Sectional StudiesDisease Outbreaks*Emigration and Immigration*Ethnic GroupsFemaleHIV Infections/diagnosis*HIV Infections/epidemiologyHIV Infections/transmission*HumansInfant, NewbornOdds RatioPregnancyPregnancy Complications, Infectious/diagnosis*Risk FactorsTreatment Refusal*LinkOut - more resourcesFull Text SourcesEBSCOGale DatabasesIngenta plcOvid Technologies, Inc.ProQuestOther Literature SourcesLabome Researcher Resource - ExactAntigen/LabomeAccess more work from the authors - ResearchGateMedicalPregnancy - Genetic AllianceHIV - Genetic AllianceHIV/AIDS - MedlinePlus Health InformationHIV/AIDS in Women - MedlinePlus Health InformationInfections and Pregnancy - MedlinePlus Health InformationPubMed Commons home

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Patent US20050075926 - On-line promotion server - Google PatentsSearch Images Maps Play YouTube News Gmail Drive More »Sign inAdvanced Patent SearchPatentsA central server for providing a promotion to a plurality of application servers includes a processor, and a tangible media coupled to the processor, the tangible media including code that directs the processor to receive from a user at a client system promotion setup data for the promotion, code that...http://www.google.com/patents/US20050075926?utm_source=gb-gplus-sharePatent US20050075926 - On-line promotion serverAdvanced Patent SearchPublication numberUS20050075926 A1Publication typeApplicationApplication numberUS 10/456,855Publication dateApr 7, 2005Filing dateApr 10, 2002Priority dateJul 25, 2000Publication number10456855, 456855, US 2005/0075926 A1, US 2005/075926 A1, US 20050075926 A1, US 20050075926A1, US 2005075926 A1, US 2005075926A1, US-A1-20050075926, US-A1-2005075926, US2005/0075926A1, US2005/075926A1, US20050075926 A1, US20050075926A1, US2005075926 A1, US2005075926A1InventorsWanqian Liu, Song Li, Robert ZhangOriginal AssigneeInformlink, Inc., Computer Science CorporationExport CitationBiBTeX, EndNote, RefManPatent Citations (1), Referenced by (18), Classifications (6), Legal Events (1) External Links: USPTO, USPTO Assignment, EspacenetOn-line promotion server
1. A central server for providing a promotion to a plurality of application servers comprises: a processor; and a tangible media coupled to the processor, the tangible media including: code that directs the processor to receive from a user at a client system promotion setup data for the promotion;

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Home Storage & Organization Storage Trunks Seward Trunk Collegiate Collection 4.0 stars 4.0 stars 11 reviews 11 reviews ratings Q&A By: Seward Trunk About this item Seward TrunkUnisexUnisex Read more… Reduced Price $48.00 - $52.89 $48.00 - $52.89 Loading options... Actual Color: |
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Add to List Add to Registry Shipping See delivery options FREE pickup Not available Shipping not available Close Shipping Choose your options We will display shipping prices and delivery dates once you choose the options for this item. Pickup not available Close Pickup Choose your options We will display free store pickup prices and delivery dates once you choose the options for this item. Add to List Add to Registry Customers also considered Rollback from $49.00 Mercury Luggage Seward Trunk Wheeled Storage Footlocker, 30" 4.0 stars 1052 ratings ShippingPass from $39.00 Mercury Luggage Seward Trunk Stackable Storage Footlocker, 30" 4.0 stars 282 ratings ShippingPass from $48.00 Collegiate Locker - Purple 4.0 stars 1 ratings ShippingPass Rollback $39.00 Mercury Luggage Seward Under the Bed Wheeled Storage Footlocker, 31" 4.5 stars 63 ratings ShippingPass $54.97 Locking Trunk with Wheels-Black 4.0 stars 4 ratings ShippingPass Rollback $79.00 Was $84.53 Save $5.53 Mercury Luggage Seward Trunk Wheeled Storage Footlocker, 31" 4.0 stars 57 ratings ShippingPass Rollback $26.99 Contico Storage Locker 4.0 stars 531 ratings ShippingPass $19.86 Sterilite Footlocker, Multiple Colors 4.5 stars 234 ratings ShippingPass Rollback $32.07 Mercury Luggage Seward Trunk Cube Storage Footlocker, 20" 4.5 stars 29 ratings ShippingPass $49.96 Locking Stackable Trunk-Black 5.0 stars 1 ratings ShippingPass $69.00 Seward Trunk Barracks Footlocker 4.0 stars 2 ratings ShippingPass $54.97 Locking Trunk with Wheels-Navy 5.0 stars 2 ratings ShippingPass $66.43 Locking Stackable Trunk-Pink 2.0 stars 1 ratings ShippingPass $40.00 Mercury Luggage Seward Trunk Cube Storage Footlocker, 20" 3.0 stars 6 ratings ShippingPass $9.47 Master Lock Warded Padlock 4.0 stars 9 ratings ShippingPass from $6.31 Honey-Can-Do 6-Pocket Shower Caddy 4.0 stars 30 ratings ShippingPass $85.45 Locking Trunk with Wheels-Pink 5.0 stars 1 ratings ShippingPass Rollback $55.00 Was $59.00 Save $4.00 Mercury Luggage Seward Trunk Wheeled Storage Footlocker, 30" Mossy Oak 4.0 stars 14 ratings ShippingPass from $83.66 Mercury Luggage Seward Trunk Stackable Storage Footlocker, 30" Classic ShippingPass from $99.99 Mercury Luggage Seward Trunk Stackable Storage Footlocker, 31" 4.5 stars 3 ratings ShippingPass Reduced Price $76.15 List price $123.00 Save $46.85 Collegiate 30 in. Footlocker w Handle in Blue ShippingPass Customers also bought these products $9.47 Master Lock Warded Padlock 4.0 stars 9 ratings ShippingPass Clearance from $5.44 Master Lock 1504D Red Combination Padlocks ShippingPass $7.24 Was $12.44 Save $5.20 Master Lock 121T 2-Count 3/4" Black Vinyl Cover Brass Padlock 5.0 stars 2 ratings ShippingPass $35.00 Hamilton Beach 0.7 cu ft Microwave Oven 4.5 stars 230 ratings ShippingPass $5.87 Mainstays LED Desk Lamp 5.0 stars 44 ratings ShippingPass from $6.31 Honey-Can-Do 6-Pocket Shower Caddy 4.0 stars 30 ratings ShippingPass $9.84 Mainstays Fleece Blanket 4.0 stars 4 ratings ShippingPass $2.00 iGo Toothbrush Holder, Purple 5.0 stars 11 ratings ShippingPass Rollback $30.78 Twin XL Dorm Mattress Waterproof Protector Pad and Cover 5.0 stars 10 ratings ShippingPass Reduced Price $3.72 List price $4.49 Save $0.77 Amy's Organic Black Bean Chili, 14.7 oz 4.5 stars 8 ratings ShippingPass Rollback from $27.88 Mainstays 1.5" Memory Foam Combo Mattress Topper 3.5 stars 256 ratings ShippingPass Rollback from $15.84 Mainstays Jersey Knit Sheet Set 4.0 stars 12 ratings ShippingPass $6.49 As Seen on TV Magic Hangers, Set of 10 3.5 stars 102 ratings ShippingPass Rollback $24.98 Big Joe Milano Bean Bag Chair, Multiple Colors 4.0 stars 166 ratings ShippingPass Clearance $16.74 12" Table-Stand Convert Fan 4.0 stars 12 ratings ShippingPass $19.79 your zone black tinsel fur rug, 2'6" x 3'2" 2.0 stars 5 ratings ShippingPass Rollback $32.07 Mercury Luggage Seward Trunk Cube Storage Footlocker, 20" 4.5 stars 29 ratings ShippingPass from $39.00 Mercury Luggage Seward Trunk Stackable Storage Footlocker, 30" 4.0 stars 282 ratings ShippingPass Rollback from $49.00 Mercury Luggage Seward Trunk Wheeled Storage Footlocker, 30" 4.0 stars 1052 ratings ShippingPass Rollback $39.00 Mercury Luggage Seward Under the Bed Wheeled Storage Footlocker, 31" 4.5 stars 63 ratings ShippingPass Rollback $26.99 Contico Storage Locker 4.0 stars 531 ratings ShippingPass About this item Customer reviews Item recommendations Policies Back to top About this item Important Made in USA Origin Disclaimer: For certain items sold by Walmart on Walmart.com, the displayed country of origin
recommended that you rely on product packaging or manufacturer information. This heavy duty trunk features a durable wooden construction, heavy gauge vinyl covering, high impact styrene binding, and nickel hardware for a finished look. Specifications Clothing Size: 30" x 15.75" x 12.25" Model: 5120-10 Brand: Seward Trunk Recommended Room: Dorm Maximum Weight: 20 lbs Age Group: Adult Recommended Use: Multipurpose Recommended Location: Indoor Condition: New Size: 30" x 15.75" x 12.25" Material: Wood Manufacturer Part Number: 5120-10 Fastener Type: Tongue and Groove Closure Features: Carrying Handle , Black high impact styrene bindingNickel hardware , Sturdy , Durable , Dust Resistant , Push Button Lock Assembled Product Dimensions (L x W x H): 30.00 x 15.75 x 12.25 Inches Show Best seller ranking: #6,938 in Home #453 in Home Storage & Organization #210 in Home Storage & Organization Storage Explore related products Trunks Plastic Storage Footlocker Storage Furniture Closet Organizer with Wheels Storage Trunks Top Rated Products in Trunks Customer Reviews Customer Reviews | 11 reviews | 4.1 out of 5 4.0 stars 11 reviews | 4.1 out of 5 4.0 stars 11 reviews | 4.1 out of 5 82% Would recommend to a friend 5 stars 5 4 stars 4 3 stars 1 2 stars 0 1 stars 1 Sort by Most relevant Most helpful Newest to oldest Oldest to newest High to low rating Low to high rating 1-5 of 11 total reviews 82% Would recommend to a friend Write a review Show filters Sort by Most relevant Most helpful Newest to oldest Oldest to newest High to low rating Low to high rating Age 18-24 25-34 35-44 45-54 55-64 65 and older Gender Male Female Great product 7/11/2016 Customer review by Simon 4.0 stars 7/11/2016 by Simon by Simon Verified purchaser Verified purchaser Customer has been confirmed to have purchased the item from Walmart. Great product for the money. Just be aware it doest have handles and wheels. Was this review helpful? Yes (1) No (0) Report Thank you! You have successfully submitted feedback for this review. Was this review helpful? Yes (1) No (0) Simon Would recommend to a friend? Yes Verified purchaser Verified purchaser Customer has been confirmed to have purchased the item from Walmart. Great box for college!! 8/16/2016 Customer review by Nini 5.0 stars 8/16/2016 by Nini by Nini Verified purchaser Verified purchaser Customer has been confirmed to have purchased the item from Walmart. Got this box for college and it was filled to the brim and carried everything that was needed!! Was this review helpful? Yes (0) No (0) Report Thank you! You have successfully submitted feedback for this review. Was this review helpful? Yes (0) No (0) Nini Would recommend to a friend? Yes Verified purchaser Verified purchaser Customer has been confirmed to have purchased the item from Walmart. Kristian college item 8/12/2016 Customer review by Floridashell 4.0 stars 8/12/2016 by Floridashell by Floridashell Verified purchaser Verified purchaser Customer has been confirmed to have purchased the item from Walmart. Great for travel and plenty of storage space. Was this review helpful? Yes (0) No (0) Report Thank you! You have successfully submitted feedback for this review. Was this review helpful? Yes (0) No (0) Floridashell Would recommend to a friend? Yes Verified purchaser Verified purchaser Customer has been confirmed to have purchased the item from Walmart. You get What You Pay For 7/21/2016 Customer review by DisappointedMom 1.0 stars 7/21/2016 by DisappointedMom by DisappointedMom Verified purchaser Verified purchaser Customer has been confirmed to have purchased the item from Walmart. This product is made in the USA so I was very hopeful it would be of surprisingly good quality given it cost so much more than other similar products. No such luck. I returned it almost as fast as I purchased it. None of the construction looked to be able to stand one trip much less a college move, which is why I bought it. You'd be much better paying the additional $50 - $100 for a quality footlocker. Was this review helpful? Yes (0) No (0) Report Thank you! You have successfully submitted feedback for this review. Was this review helpful? Yes (0) No (0) DisappointedMom Would recommend to a friend? No Verified purchaser Verified purchaser Customer has been confirmed to have purchased the item from Walmart. Not to my Liking 8/2/2016 Customer review by Meka5 4.0 stars 8/2/2016 by Meka5 by Meka5 Verified purchaser Verified purchaser Customer has been confirmed to have purchased the item from Walmart. It could be made a little better. The locks on it are very cheap. I will serve what I need it for. Was this review helpful? Yes (0) No (0) Report Thank you! You have successfully submitted feedback for this review. Was this review helpful? Yes (0) No (0) Meka5 Would recommend to a friend? Yes Verified purchaser Verified purchaser Customer has been confirmed to have purchased the item from Walmart. 1 2 3 1-5 of 11 total reviews See all 1-5 of 11 reviews Previous Reviews Next Reviews Customer Reviews | 11 reviews | 4.1 out of 5 Customer Reviews 4.0 stars 11 reviews | 4.1 out of 5 Great product Customer review by Simon 4.0 stars 7/11/2016 Verified purchaser Verified purchaser Customer has been confirmed to have purchased the item from Walmart. Great product for the money. Just be aware it doest have handles and wheels. Was this review helpful? Yes (1) No (0) Great box for college!! Customer review by Nini 5.0 stars 8/16/2016 Verified purchaser Verified purchaser Customer has been confirmed to have purchased the item from Walmart. Got this box for college and it was filled to the brim and carried everything that was needed!! Was this review helpful? Yes (0) No (0) Read all 11 reviews Customer Q&A Back Ask a question Back to questions Questions & Answers 2 questions Ask a question Back to questions Sort by: Number of answers Most recent questions Most recent answers 1-2 of 2 questions Ask a question If you would like to share feedback with us about pricing, delivery or other customer service issues, please contact customer service directly. Question Q&A tips and guidelines Q&A Exchange Guidelines When writing your question or answer, please follow these guidelines: Do: Make sure your question is directly related to the product Do: Be specific and provide as many details as possible Do: Include the model number (if applicable) Do: Write your question in English Do Not: Include personal information (such as your full name) All submitted questions and answers are subject to the terms set forth in our Terms and Conditions We reserve the right not to post your question or answer if it contains any of the following: Any information not related to the actual merchandise or topic Obscenities, discriminatory language or other language not suitable for a public forum Advertisements or “spam” content Email addresses, physical addresses or other forms of contact information Critical or spiteful comments on other questions or answers posted on the page or their authors Any imagery that demonstrates incorrect use of the merchandise Anything that Walmart deems to be inappropriate, at Walmart's discretion Additional details (optional) Provide as many details as possible, including the model number (if applicable). Remember: Don’t include personal information (such as your full name). Nickname Nickname Send me an email when my question is answered Email address I agree to the Terms & Conditions Submit Cancel Preview Preview Question answers by an anonymous customer answers answers Last answer: Answer this question Cancel my answer Answer this question Submit Edit Cancel Thank you. Questions will be checked against our question guidelines and posted within five to seven business days. Back Q. Are you able to lock this trunk with a padlock? I need to know for college. 1 answer by Alexis 7/23/2016 1 answer Report A. The trunk can be locked with a pad lock.
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Patent US7553791 - Heavy aromatics conversion catalyst composition and processes therefor and ... - Google Patents
A catalyst composition, a process for producing the composition and a process for the conversion of a feedstock containing C9+ aromatic hydrocarbons to produce a resulting product containing lighter aromatic products and less than about 0.5 wt % of ethylbenzene based on the weight of C8 aromatics fraction...http://www.google.com/patents/US7553791?utm_source=gb-gplus-sharePatent US7553791 - Heavy aromatics conversion catalyst composition and processes therefor and therewith
Publication number US7553791 B2
Application number US 10/982,487
Also published as CA2583223A1, CA2583223C, CN101048229A, EP1827686A1, US20050065017, WO2006052324A1
Publication number 10982487, 982487, US 7553791 B2, US 7553791B2, US-B2-7553791, US7553791 B2, US7553791B2
Inventors Timothy Edward McMinn, David Anthony Stachelczyk
Patent Citations (46), Non-Patent Citations (2), Referenced by (10), Classifications (68), Legal Events (3)
US 7553791 B2
A catalyst composition, a process for producing the composition and a process for the conversion of a feedstock containing C9+ aromatic hydrocarbons to produce a resulting product containing lighter aromatic products and less than about 0.5 wt % of ethylbenzene based on the weight of C8 aromatics fraction of the resulting product. The C9+ aromatic hydrocarbons are converted under the transalkylation reaction conditions to a reaction product containing xylene. The catalyst composition comprises (i) an acidity component having an alpha value of at least 300; and (ii) a hydrogenation component having hydrogenation activity of at least 300. The composition can be produced by to incorporating at least one hydrogenation component into an acidity component having an alpha value of at least 300.
(a) an acidity component having an alpha value of at least 500, said acidity component comprising:
i) a first molecular sieve consisting of ZSM-12; and
ii) a second molecular sieve consisting of ZSM-5; and
(b) a hydrogenation component having hydrogenation activity of at least 1000;
wherein said catalyst composition is characterized as particulate and wherein said hydrogenation component is incorporated into said acidity component by at least one of ion exchange, incipient wetness impregnation, and solid-state reaction, followed by calcining and then steam treatment.
2. The catalyst composition according to claim 1, wherein said hydrogenation component comprises rhenium.
This application is a continuation-in-part of application Ser. No. 10/294,428, filed Nov. 14, 2002 now U.S. Pat. No. 7,148,391, the disclosure which is incorporated by reference in its entirety.
The invention relates to a catalyst composition useful for converting heavy aromatics, specifically C9+ aromatics, to lighter aromatic products, particularly benzene, toluene and xylenes (hereinafter collectively referred to as BTX), to a process for producing the composition and to a process for using the composition in a heavy aromatics conversion process.
A source of benzene and xylenes is catalytic reformate, which is prepared by contacting a mixture of petroleum naphtha and hydrogen with a strong hydrogenation/dehydrogenation catalyst, such as platinum, on a moderately acidic support, such as a halogen-treated alumina. Usually, a C6 to C8 fraction is separated from the reformate and extracted with a solvent selective for aromatics or aliphatics to produce a mixture of aromatic compounds that is relatively free of aliphatics. This mixture of aromatic compounds usually contains BTX, along with ethylbenzene.
Refineries have also focused on the production of benzene and xylenes by transalkylation of C9+ aromatics and toluene over noble metal-containing zeolite catalysts. High value petrochemical products, such as benzene and xylenes, together with ethylbenzene are formed during the transalkylation of C9+ aromatics and toluene over catalysts containing noble metals. The resulting translation product is subjected to further separation of non-aromatics, benzene, C8 aromatics (i.e., ethylbenzene, para-xylene, meta-xylene, and ortho-xylene), unreacted toluene, and unreacted C9+ aromatics. Usually, the C8 aromatics product is subjected to further separation to produce xylenes, particularly, para-xylene. Lowering the amount of ethylbenzene in the C8 aromatics improves efficiency of xylene recovery. Therefore, there are strong economic and technical incentives to decrease the ethylbenzene concentration in the transalkylation product. The amount of ethylbenzene in the transalkylation product depends primarily on (a) the feedstock composition and (b) the transalkylation catalyst and the transalkylation conditions. Typically, the C9+ aromatics feedstock and/or the toluene feed contains ethylbenzene as an impurity ranging from 0.001 to 4 wt % based on total weight of the feed. Other than the ethylbenzene in the feedstock, ethylbenzene can be formed during transalkylation process from a feed comprising ethyl-containing C9+ aromatics and from various side-reactions.
One solution to the problem of the ethylbenzene in the transalkylation product during the transalkylation of heavy aromatics is disclosed in U.S. Pat. No. 5,942,651 and involves the steps of contacting a feed comprising C9+ aromatic hydrocarbons and toluene under transalkylation reaction conditions with a first catalyst composition comprising a zeolite having a constraint index ranging from 0.5 to 3, such as ZSM-12, and a hydrogenation component. The effluent resulting from the first contacting step is then contacted with a second catalyst composition which comprises a zeolite having a constraint index ranging from 3 to 12, such as ZSM-5, and which may be in a separate bed or a separate reactor from the first catalyst composition to produce a transalkylation reaction product comprising benzene and xylene. The ethylbenzene in the feed and/or the ethylbenzene formed during transalkylation process is partially destroyed by dealkylation of ethylbenzene to benzene and ethylene.
U.S. Pat. No. 5,905,051 discloses a process for converting a hydrocarbon stream such as, for example, a C9+ aromatic compound to C6 to C8 aromatic hydrocarbons, such as xylenes, by contacting the stream with a catalyst system comprising a first catalyst composition and a second catalyst composition, wherein said catalyst compositions are present in separate stages and are not physically mixed or blended and wherein said first catalyst composition is a metal-promoted, alumina- or silica-bound zeolite beta, and said second catalyst composition is ZSM-5 having incorporated therein an activity promoter selected from the group consisting of silicon, phosphorus, sulfur, and combinations thereof. According to the '051 patent, the use of the separate catalytic stages improves the conversion of C9+ aromatic compounds and naphthalenes to xylenes and decreases the amount of undesirable ethylbenzene in the product. The ethylbenzene in the '051 product is about 3-7 wt % of ethylbenzene based on the weight of C8 aromatics fraction of the resulting product.
It has now been found that a catalyst system comprising a molecular sieve exhibits enhanced acidity and hydrogenation activity for substantial removal of ethyl-group containing aromatic compounds in C9+ aromatic feeds without overall reduction in the conversion of the C9+ feed to useful compounds, such as xylenes.
In one embodiment, the invention relates to a catalyst composition comprising:
i) an acidity component having an alpha value of at least 300; and
ii) a hydrogenation component having hydrogenation activity of at least 300.
In another embodiment, the invention relates to a process for producing a catalyst composition comprising:
i) contacting an acidity component having an alpha value of at least 300 with at least one hydrogenation component under a condition sufficient to incorporate said hydrogenation component into said acidity component to form a modified acidity component; and
ii) calcining said modified acidity component to produce said catalyst having hydrogenation activity of at least 300.
In another embodiment, the invention relates to a process for the conversion of a feedstock containing C9+ aromatic hydrocarbons to produce a resulting product containing lighter aromatic products and less than about 0.5 wt % of ethylbenzene based on the weight of C8 aromatics fraction of said resulting product, said process comprising contacting said feedstock under transalkylation reaction conditions with a catalyst composition comprising: (i) an acidity component having an alpha value of at least 300; and (ii) a hydrogenation component having hydrogenation activity of at least 300, the C9+ aromatic hydrocarbons being converted under said transalkylation reaction conditions to a reaction product containing xylenes. Preferably, the aromatic product contains less than about 0.3 wt % of ethylbenzene based on the weight of C8 aromatics fraction of said resulting product. More preferable, the aromatic product contains less than about 0.2 wt % of ethylbenzene based on the weight of C8 aromatics fraction of said resulting product.
Preferably, the acidity component comprises a molecular sieve selected from the group consisting of one or more of a first molecular sieve having a MTW structure, a molecular sieve having a MOR structure, and a porous crystalline inorganic oxide material having an X-ray diffraction pattern including d-spacing maxima (Å) at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07. More preferably, the catalyst comprises a molecular sieve ZSM-12. Alternatively, the porous crystalline inorganic oxide material is selected from the group consisting of one or more of MCM-22, PSH-3, SSZ-25, MCM-36, MCM-49 and MCM-56.
In another embodiment, the catalyst comprises second molecular sieve having a constraint index ranging from 3 to 12. Preferably, the second molecular sieve is ZSM-5. Preferably, the catalyst comprises two molecular sieves, the first molecular sieve is ZSM-12, and the second molecular sieve is ZSM-5. Conveniently, the catalyst composition is particulate and the first and second molecular sieves are each contained in the same catalyst particles.
Preferably, the hydrogenation component is selected from the group consisting of one or more of a Group VIIIB and Group VIIB metal. More preferably, the hydrogenation component is selected from the group consisting of one or more of rhenium, platinum, and palladium.
Typically, the feed contains benzene or toluene. In a further aspect, the invention resides in a process for producing benzene comprising the steps of: (a) reacting C9+ aromatic hydrocarbons and toluene under transalkylation reaction conditions over a catalyst composition comprising (i) an acidity component having an alpha value of at least 300; and (ii) a hydrogenation component having hydrogenation activity of at least 300, to produce a resulting product stream comprising benzene and xylenes; and (b) distilling the benzene from said product stream to obtain a benzene product. Preferably, the aromatic product contains less than about 0.5 wt % of ethylbenzene based on the weight of C8 aromatics fraction of said resulting product. More preferable, the aromatic product contains less than about 0.3 wt % of ethylbenzene based on the weight of C8 aromatics fraction of said resulting product. More preferable, the aromatic product contains less than about 0.2 wt % of ethylbenzene based on the weight of C8 aromatics fraction of said resulting product.
In a further aspect, the invention resides in a process for processing C9+ aromatic hydrocarbons at least at a rate of ten kilograms per hour.
In a preferred embodiment, this invention provides a catalyst composition comprises (i) an acidity component having an alpha value of at least 300, perferably the alpha value of at least 400, more preferably the alpha value of at least 500; and (ii) a hydrogenation component having hydrogenation activity of at least 300, perferably the hydrogenation activity of at least 500, more preferably the hydrogenation activity of at least 1000.
Preferably, the acidity component comprises a first molecular sieve selected from the group consisting of one or more of a molecular sieve having a MTW structure, a molecular sieve having a MOR structure, and a porous crystalline inorganic oxide material having an X-ray diffraction pattern including d-spacing maxima (Å) at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07. More preferably, the catalyst comprises a molecular sieve ZSM-12. Alternatively, the porous crystalline inorganic oxide material is selected from the group consisting of MCM-22, PSH-3, SSZ-25, MCM-36, MCM-49 and MCM-56.
Preferably, said hydrogenation component is incorporated into said acidity component by ion-exchange, incipient wetness impregnation, solid-state reaction, or combinations of two or more thereof. More preferably, said hydrogenation component is incorporated into said acidity component by ion exchange, and/or incipient wetness impregnation.
As used herein, the term “lighter aromatic products” is defined to mean aromatic molecules in products having fewer carbon atoms than the carbon atoms of aromatic molecules in the feedstock. For example, para-xylene, one of the resulting products of C9+ transalkylation with toluene and/or benzene, has 8 carbon atoms which is less than 9 or more carbon atoms in C9+ aromatic molecules.
(i) an acidity component having an alpha value of at least 300; and
(ii) a hydrogenation component having hydrogenation activity of at least 300,
The acidity component is a material of having an alpha value of at least 300, such as, silica-alumina, acidic zicoria, a molecular sieve selected from the group consisting of a molecular sieve having a MTW structure, a molecular sieve having a MOR structure, and a porous crystalline inorganic oxide material having an X-ray diffraction pattern including d-spacing maxima (Å) at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07.
With regard to the molecular sieve, ZSM-12 is more particularly described in U.S. Pat. No. 3,832,449. Mordenite occurs naturally but may also be used in one of its synthetic forms, such as TEA-mordenite (i.e., synthetic mordenite prepared from a reaction mixture comprising a tetraethylammonium directing agent), which is disclosed in U.S. Pat. Nos. 3,766,093 and 3,894,104. Examples of suitable porous crystalline inorganic oxide materials having the defined X-ray diffraction pattern include MCM-22, PSH-3, SSZ-25, MCM-36, MCM-49 or MCM-56. MCM-22 is described in U.S. Pat. No. 4,954,325, PSH-3 is described in U.S. Pat. No. 4,439,409, SSZ-25 is described in U.S. Pat. No. 4,826,667, MCM-36 is described in U.S. Pat. No. 5,250,277, MCM-49 is described in U.S. Pat. No. 5,236,575 and MCM-56 is described in U.S. Pat. No. 5,362,697. The entire contents of each of the aforementioned patents are incorporated herein by reference.
With regard to the molecular sieve, suitable materials having a constraint index of 3 to 12 include ZSM-5, ZSM-11, ZSM-22, ZSM-23, ZSM-35, ZSM-48, ZSM-57 and ZSM-58. ZSM-5 is described in U.S. Pat. No. 3,702,886. ZSM-11 is described in U.S. Pat. No. 3,709,979. ZSM-22 is described in U.S. Pat. No. 5,336,478. ZSM-23 is described in U.S. Pat. No. 4,076,842. ZSM-35 is described in U.S. Pat. No. 4,016,245. ZSM-48 is described in U.S. Pat. No. 4,375,573. ZSM-57 is described in U.S. Pat. No. 4,873,067. ZSM-58 is described in U.S. Pat. No. 4,698,217. Constraint index and a method for its determination are described in U.S. Pat. No. 4,016,218. The entire contents of each of the aforementioned patents are incorporated herein by reference.
Typically, the second molecular sieve constitutes from 0 to 95 wt %, such as from in excess of 20 to 80 wt % based on the total weight of the first and second molecular sieves in the catalyst composition.
As used herein, the Diffusion Parameter of a particular porous crystalline material is defined as D/r2×106, wherein D is the diffusion coefficient (cm2/sec) and r is the crystal radius (cm). The required diffusion parameters can be derived from sorption measurements provided the assumption is made that the plane sheet model describes the diffusion process. Thus for a given sorbate loading Q, the value Q/Q∞, where Q∞is the equilibrium sorbate loading, is mathematically related to (Dt2/r)1/2 where t is the time (sec) required to reach the sorbate loading Q. Graphical solutions for the plane sheet model are given by J. Crank in “The Mathematics of Diffusion”, Oxford University Press, Ely House, London, 1967.
YO2/X2O3 20-100 40-80
H2O/YO2 10-100 15-40
OH−/YO2 0.1-0.6 0.15-0.4
R/YO2 0.1-0.6 0.15-0.4
M/YO2 0.1-0.6 0.15-0.4
The synthesis mixture may also contain nucleating seeds of ZSM-12 and, where such seeds are present, they typically constitute 0.05-5 wt % of the mixture. Crystallization of the synthesis mixture may be carried out under either stirred or static conditions, preferably stirred conditions, at a temperature of 160° C. or less, such as 140 to 160° C. for 48 to 500 hours, whereafter the resultant ZSM-12 crystals are separated from the mother liquor and recovered
Naturally occurring clays that can be composited with the molecular sieve's as a binder for the catalyst composition include the montmorillonite and kaolin family, which families include the subbentonites, and the kaolins commonly known as Dixie, McNamee, Georgia and Florida clays or others in which the main mineral constituent is halloysite, kaolinite, dickite, nacrite or anauxite. Such clays can be used in the raw state as originally mined or initially subjected to calcination, acid treatment or chemical modification.
In addition to the foregoing materials, the molecular sieve's can be composited with a porous matrix binder material, such as an inorganic oxide selected from the group consisting of silica, alumina, zirconia, titania, thoria, beryllia, magnesia, and combinations thereof, such as silica-alumina, silica-magnesia, silica-zirconia, silica-thoria, silica-beryllia, silica-titania, as well as ternary compositions such as silica-alumina-thoria, silica-alumina-zirconia, silica-alumina-magnesia and silica-magnesia-zirconia. It may also be advantageous to provide at least a part of the foregoing porous matrix binder material in colloidal form to facilitate extrusion of the catalyst composition.
Each molecular sieve is usually admixed with the binder or matrix material so that the final catalyst composition contains the binder or matrix material in an amount ranging from 5 to 90 wt %, and typically from 10 to 60 wt %.
At least the first molecular sieve, and preferably each molecular sieve, in the catalyst composition has associated therewith at least one hydrogenation component, such as tungsten, vanadium, molybdenum, rhenium, chromium, manganese, a metal selected from Group IB, IIB, IIIB, IVB, VB, VIB, VII B, and VIIIB of the Periodic Table of the Elements (CAS version, 1979), or mixtures thereof. Useful Group VIIIB metals include iron, ruthenium, osmium, nickel, cobalt, rhodium, iridium, and noble metals such as platinum, rhenium, or palladium. Preferably, the hydrogenation component is palladium, platinum or rhenium.
The hydrogenation component can be incorporated into the catalyst composition by co-crystallization, exchanged into the composition to the extent a Group IIIA element, e.g., aluminum, is in the molecular sieve structure, impregnated therein, or mixed with the molecular sieve and binder. Such component can be impregnated in or on the molecular sieve, for example in the case of platinum, by treating the molecular sieve with a solution containing a platinum metal-containing ion. Suitable platinum compounds for impregnating the catalyst with platinum include chloroplatinic acid, platinous chloride and various compounds containing the platinum ammine complex, such as Pt(NH3)4CI2.H2O.
Alternatively, a compound of the hydrogenation component may be added to the molecular sieve when it is being composited with a binder, or after the molecular sieve and binder have been formed into particles by extrusion or palletizing.
The hydrogenation component may also be arranged to have a hydrogenation activity of hydrogenation value of at least 300, such as at least 500, preferably at least 1000. The hydrogenation function is measured by comparing the amount of ethylene to the amount of ethane in the transalkylation product. Ethylene is formed in the transalkylation process by the dealkylation of ethyl-substituted aromatic molecules and by the cracking of aliphatic and naphthenic hydrocarbons. The hydrogenation component is designed to saturate these ethylene molecules to ethane before they can engage in side reactions. The better the hydrogenation component the less ethylene will be present relative to ethane in the transalkylation product. The hydrogenation value is defined as the ratio of ethane over ethylene. The experimental conditions of the test used herein include a constant temperature of 412° C., a pressure of 2170 kPAa, a hydrogen to hydrocarbon molar ratio of 2, a toluene/1,4-methylethylbenzene ratio of 2, and a WHSV of 2.7 h−1. The hydrogenation value, measured by ethane/ethylene ratio, is calculated by the molar percentage of ethane in the product divided by the molar percentage of ethylene in the product.
After treatment with the hydrogenation component, the molecular sieve is usually dried by heating at a temperature of 65° C. to 160°, typically 110 to 143° C., for at least 1 minute and generally not longer than 24 hours, at pressures ranging from 100 to 200 kPAa. Thereafter, the molecular sieve may be calcined in a stream of dry gas, such as air or nitrogen, at temperatures of from 260° to 650° C. for 1 to 20 hours. Calcination is typically conducted at pressures ranging from 100 to 300 kPAa and a WHSV of about 0.002 to about 20 h−1.
Prior to use, steam treatment of the catalyst composition may be employed to minimize the aromatic hydrogenation activity of the catalyst composition. In the steaming process, the catalyst composition is usually contacted with from 5 to 100% steam, at a temperature of at least 260° to 650° C. for at least one hour, specifically 1 to 20 hours, at a pressure of 100 to 2590 KPAa and a WHSV of about 0.002 to about 20 h−1.
In addition, prior to contacting the catalyst composition with the hydrocarbon feed, the hydrogenation component can be sulfided. This is conveniently accomplished by contacting the catalyst with a source of sulfur, such as hydrogen sulfide, at a temperature ranging from about 320 to 480° C. The source of sulfur can be contacted with the catalyst via a carrier gas, such as hydrogen or nitrogen.
After contacting the catalyst composition with the hydrocarbon feed, the catalyst may be deactivated due to coking or metal agglomerization. The deactivated catalyst can be regenerated conveniently by coke burning with a stream comprising oxygen or oxygen containing compounds, such as, ozone, oxochlorine, carbon disxide or the like, metal re-dispersing using oxdization-reduction cycle, oxochloride treatment or the like, washing with liquid hydrocarbons or aqueous solution of inorganic and/or organic chemical compounds, such as, water, ethanol, acetone, or the like, or rejuventaion with a stream comprising hydrogen. Regeneration or rejuventation can be performed at a temperature range from ambience to about 600° C., a pressure range of about 100 to about 5000 KPAa, and WHSV of about 0.2 to about 100 h−1.
The aromatic feed used in the process of the invention comprises ethylbenzene and one or more aromatic compounds containing at least 9 carbon atoms. Specific C9+ aromatic compounds found in a typical feed include mesitylene (1,3,5-trimethylbenzene), durene (1,2,4,5-tetramethylbenzene), hemimellitene (1,2,4-trimethylbenzene), pseudocumene (1,2,4-trimethylbenzene), 1,2-methylethylbenzene, 1,3-methylethylbenzene, 1,4-methylethylbenzene, propyl-substituted benzenes, butyl-substituted benzenes, and dimethylethylbenzenes. Suitable sources of the C9+ aromatics are any C9+ fraction from any refinery process that is rich in aromatics. This aromatics fraction contains a substantial proportion of C9+ aromatics, e.g., at least 80 wt % C9+ aromatics, wherein preferably at least 80 wt %, and more preferably more than 90 wt %, of the hydrocarbons will range from C9 to C12. Typical refinery fractions which may be useful include catalytic reformate, FCC naphtha or TCC naphtha.
The feed may also comprise benzene or toluene. Thus, in one practical embodiment, the feed to the transalkylation reactor comprises ethylbenzene, C9+ aromatics hydrocarbons and toluene. The feed may also include recycled/unreacted/produced benzene, toluene, ethylbenzene, and C9+ aromatics that is obtained by distillation of the effluent product of the transalkylation reaction itself. Typically, toluene constitutes from about 5 to about 90 wt % and C9+ constitutes from about 10 to about 95 wt %. In a typical light feed, toluene constitutes from about 40 to about 90 wt %, such as from 50 to 70 wt % of the entire feed, wheras the C9+ aromatics component constitutes from 10 to 60 wt %, such as from 30 to 50 wt %, of the entire feed to the transalkylation reaction zone. In a typical heavy feed, toluene constitutes from about 15 to about 50 wt %, such as from 25 to 40 wt % of the entire feed, wheras the C9+ aromatics component constitutes from 50 to 85 wt %, such as from 60 to 75 wt %, of the entire feed to the transalkylation reaction zone.
The process can be conducted in any appropriate reactor including a radial flow, fixed bed, continuous flow or fluid bed reactor. The transalkylation reaction conditions typically include a temperature ranging from about 343° to about 510° C., such as from about 400° to about 454° C.; a pressure from about 380 to about 4240 kPAa, such as from about 1480 to about 3550 kPAa; a hydrogen to hydrocarbon molar ratio from about 1 to about 5, such as from about 1 to about 3 and a WHSV of about 0.2 to about 20 h−1, such as from 1 to about 5 h−1. The transalkylation reaction conditions are sufficient to convert the heavy aromatic feed to a product containing substantial quantities of C6-C8 aromatic compounds, such as benzene, toluene and xylenes, especially benzene and xylene. The transalkylation reaction conditions also are sufficient to convert the ethylbenzene in the feed to benzene and ethane.
A small crystal, high activity ZSM-12 was synthesized from a mixture comprising 11280 g of water, 1210 g of methyltriethylammonium chloride (MTEACl), 1950 g of Ultrasil PM available from Degussa, 229 g of sodium aluminate solution (45%), and 364 g of 50% sodium hydroxide solution. The mixture had the following molar composition:
H2O/SiO2=22
Na+/SiO2=0.2
MTEACl/SiO2=0.26
The mixture was reacted at 160° C. in a 5-gal autoclave with stirring at 150 RPM for 144 hours. The product was filtered, washed with deionized (DI) water and dried at 120° C. The XRD pattern of the as-synthesized material showed the typical pure phase of ZSM-12 topology. The SEM of the as-synthesized material showed that the material was composed of agglomerates of small crystals (with an average crystal size of about 0.05 microns).
The as-synthesized crystals were converted into the hydrogen form by two ion exchanges with ammonium nitrate solution at room temperature, followed by drying at 120° C. and calcination at 540° C. for 6 hours. The resulting ZSM-12 crystals had a SiO2/Al2O3 molar ratio of 44.98, an Alpha value of 500 and a D/r2 for mesitylene of greater than 5000×10−6 sec−1 at a temperature of 100° C. and a mesitylene pressure of 2 torr.
A mixture containing 65 wt % of the ZSM-12 produced as above, 15 wt % ZSM-5, and 20 wt % alumina was extruded into pellets 1.3 mm in length and having a quadrulobe cross-section. The pellets were dried at 120° C. then calcined in nitrogen for 3 hours at 480° C. This material was then exchanged with ammonium nitrate, dried at 120° C. and then calcined in air for 6 hours at 540° C. 0.5 wt % Re was then added to the catalyst by incipient wetness impregnation from an aqueous solution of tetraammine rhenium nitrate. The impregnated material was dried at 120° C. then calcined in air for 6 hours at 350° C. to produce a final catalyst.
Three grams of the resultant catalyst composition from example 1 was used to effect transalkylation of a mixture of toluene/C9+ aromatic hydrocarbon mixture having the composition given in Table 1 at a temperature of about 412° C., a pressure of 2170 kPAa, a hydrogen to hydrocarbon molar ratio of 2 and a WHSV of 2.7 h−1. The results after 4.4 days on stream are summarized in Table 1 below.
C5 − 8.55
Non-Aromatics 0.17 0.16
Benzene 12.87
Toluene 61.27 38.01
Ethylbenzene 0.03 0.06
Xylenes 0.26 30.37
C9 29.73 8.76
C10 8.25 0.87
C11+ 0.30 1.09
A9 Conversion (%) 71
A10 Conversion (%) 89
De-ethylation Rate (%) 98
Xylene Yield (%) 30
Ethylbenzene in C8 0.19
Ethane/Ethylene 4000
Xylene/Ethylbenzene ratio 506
The results in Table 1 show that the catalyst of Example 1 was highly active, particularly for the de-ethylation rate of the ethylbenzene (de-ethylation rate of 98% and xylene/ethylbenzene ratio of 506). The results in Table 1 also show that the catalyst of Example 1 was highly active for C9+ conversion to xylenes.
Three grams of the resultant catalyst composition from example 1 was used to effect transalkylation of a mixture of toluene/C9+ aromatic hydrocarbon mixture having the composition given in Table 2 at a temperature of about 412° C., a pressure of 2170 kPAa, a hydrogen to hydrocarbon molar ratio of 2 and a WHSV of 2.7 h−1. The results after 4.4 days on stream are summarized in Table 2 below.
C5 − 14.31
Non-Aromatics 0.14 0.02
Benzene 6.09
Toluene 14.77 25.20
Ethylbenzene 0.01 0.07
Xylenes 0.75 33.26
C9 67.77 17.90
C10 16.29 2.86
C11+ 0.28 1.24
A9 Conversion (%) 74
Xylene Yield (%) 33
Ethylbenzene in C8 0.20
Ethane/Ethylene 13411
Xylene/Ethylbenzene ratio 475
The results in Table 1 show that the catalyst of Example 1 was highly active, particularly for the de-ethylation rate of the ethylbenzene (de-ethylation rate of 98% and xylene/ethylbenzene ratio of 475). The results in Table 2 also show that the catalyst of Example 1 was highly active for C9+ conversion to xylenes.
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U.S. Classification 502/64, 502/69, 502/74, 502/63, 502/60, 502/77, 502/71, 502/67, 502/66
International Classification B01J29/74, B01J29/40, B01J37/00, B01J29/80, B01J29/06, B01J29/78, B01J35/00, C10G45/64, B01J29/70, B01J29/44, B01J29/48, C07C6/12
Cooperative Classification Y02P20/52, C10G2300/4018, C10G2300/1096, B01J29/7476, B01J29/78, B01J29/076, B01J29/20, B01J29/44, B01J29/48, B01J29/80, B01J29/7276, B01J29/7869, C07C2523/44, C07C2529/18, B01J29/7269, B01J29/72, B01J29/7469, C07C6/126, C10G45/60, C10G2400/30, C07C2523/42, C10G45/64, B01J29/70, B01J29/064, C07C2523/36, B01J37/0009, B01J35/002, B01J2229/20, B01J29/26, B01J29/7876, C07C2529/70, B01J2229/42, B01J29/74, B01J29/40
European Classification B01J35/00D, C10G45/60, B01J29/076, B01J29/064, B01J29/74L, B01J29/78L, B01J29/74K, B01J29/78K, B01J29/72K, B01J29/72L, C10G45/64, B01J29/80, C07C6/12D
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06:31 EST, 22 January 2016
08:59 EST, 22 January 2016
Two fraudsters used the spoils of a credit card scam to go on a drinking binge worthy of the characters in Hollywood movie The Hangover.Jamie Abernathy and Brian Darroch ordered three kitchen stoves, bought almost 500 kilos of fish worth £35,000 and even chartered a private jet for £3,600.The two Scotsmen, who were on a visit to the Lancashire seaside resort of Blackpool, also treated themselves to meals, hotel rooms and vast quantities of alcohol after stealing credit card details from five members of a gym.
Brian Darroch (left) and Jamie Abernathy (right) went on a spending spree using stolen credit card details, bizarrely ordering kitchen stoves, buying 500 kilos of fish and even chartering a private jetA court heard it is not known what happened to the huge cargo of fish - comprising Dover sole, halibut, lobster and king scallops - which the pair bought from a seafood wholesaler in Fleetwood, Lancashire.

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Top 10 Hotels Near Sainte Chapelle - Closest Paris City Centre Hotels $70/night | Expedia
Hotels Near Sainte Chapelle in Paris City Centre, Paris
Sainte Chapelle Hotels Sainte Chapelle Hotels, current page
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Hotels Close to Sainte Chapelle, Paris City Centre
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4.7 of 5 • 467 reviews
Lovely hotel with great views, rooms and staff.
4.2 of 5 • 568 reviews
Excellent hotel - great staff and location.
Amazing restaurants within 100ft!
4.4 of 5 • 1,990 reviews
4 of 5 • 1,789 reviews
Hotel staff very pleasant and helpful.
Convenient location and surprised by the view.
3.9 of 5 • 849 reviews
Downstair many cafe and restaurant.
4.5 of 5 • 978 reviews
4.6 of 5 • 334 reviews
Great location and staff was very helpful and friendly.
4.1 of 5 • 638 reviews
Many good restaurants and bars to enjoy in this area.
Sainte Chapelle, Paris City Centre Hotel Information
Consider yourself on your next day: you might picture yourself strolling through downtown, gazing up at the gorgeous landscapes or the monuments wherever you look. Still, Sainte Chapelle is one feature you have been especially prepared for. Now is the time to get yourself there.
Although this area is full of sites to keep you busy, Sainte Chapelle has to be at the top of your itinerary.
The capital city, Paris, houses this particular destination.
With 155 accommodation options situated within a radius of 0.6 miles of Sainte Chapelle, you'll be spoiled for choice! The Grand Hotel du Palais Royal, Hôtel Esprit Saint Germain and La Maison Saint-Germain are definitely some of the most popular ones.
Accommodation can be a considerable expense when globetrotting, so why not save a few bucks and reserve a room at one of the close-by budget hotels? 1 mile away, you'll arrive at the Mandarin Oriental, Paris, but if that's not right for you, then perhaps you could check out the Park Hyatt Paris - Vendome, which is 1 mile away.
If you're on the look out for a stylish space to rest your bones after a long day of sightseeing, the numerous nearby upmarket accommodations should appeal to you. Be sure to look up the Hotel d'Aubusson, just 0.2 miles away, and the Residence & Spa Le Prince Regent, 0.5 miles away.
As you and your loved ones meander along the pathways near Sainte Chapelle, stop at Starbucks. Take in the satiating aroma of coffee and taste test one or two delicious pastries. Once your stomach starts grumbling, have dinner at another establishment in the area, Le Relais Saint Germain. Want to cap the night with a stiff drink? You won't need to journey too far to stumble upon Hôtel Duo.
Here's a sample of some of the other things you can do in proximity to Sainte Chapelle:
You can get a glimpse into how the political world works at Palais de Justice, a historically important building used by the government across the years.
Into history? Schedule a visit to Conciergerie and discover the important political decisions handed down there over many governments and years.
Bridges of historical significance including Pont Saint-Michel, are true links to the past. You can plan a visit to this significant structure and learn about who created it, how it was constructed, and the reason it's such a historic treasure.
Renowned for being one of the most iconic local structures, Pont au Change is an ideal place to visit for anyone looking to dig a little deeper into the history of the area.
You can skip the History Museum visit, come face to face with it when you visit Archeological Crypt of the Parvis of Notre-Dame.
Châtelet - Les Halles is the nearest metro station to Sainte Chapelle. It's a walk of about 0.5 miles. Saint-Michel - Notre-Dame is also nearby at a distance of 0.1 miles.
Expedia's directory of places to stay in Paris City Centre has all you want, so you can be certain to get locations near Sainte Chapelle that you'll fall in love with. Paris City Centre experienced quite a few arrivals in the past year, so get researching. You can discover all the inside info you're searching for right here. You'll spend with confidence when you are ready to make your reservation, too: visitors of all manner would propose their Paris City Centre hotel to a buddy.
The staff at lodging around Sainte Chapelle provide wonderful service, as you might hope near such a stunning site.
Rooms in Paris City Centre accommodation will always be neat, tidy, and primed to greet you.
Looking for room satisfaction as well as tidiness? You're on the best website.
Paris City Centre rooms got extra visitors in 2016 than the year before that, and it's understandable why. We see your prized place in your future thanks to Expedia's wide selection of hotels near Sainte Chapelle.
Intriguing Paris City Centre
You'll still have things to see and do in Paris City Centre after Sainte Chapelle is achieved.
Paris City Centre treasures haven't been in the guidebooks until recently, but trips have been soaring, meaning now is a good moment to make your wishes come true.
Paris City Centre also knows a thing or two about special hospitality after some hours spent on its abundant adventures.
Enjoy an evening of drinks and dancing to top off the good times right; when the sun comes up, get informed about Paris City Centre's past.
You won't regret planning a holiday to Paris City Centre, especially when you cash in on our awesome deals on accommodation near Sainte Chapelle. Say goodbye to the views you're used to and usher in some breathtaking landscapes!
More Popular Paris City Centre Hotels
See a list of all hotels in Sainte Chapelle
Hotels Close to Paris City Centre,
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1-800-238-0767 Expedia.com • Hotels • South America • Colombia • Bogota Hotels • Hotel Bogota Regency, Bogota
Premium TV channels Pay movies Premium bedding Access via exterior corridors Free newspaper Free local calls Minibar Daily housekeeping Turndown service Private bathroom Free toiletries Hair dryer Deep soaking bathtub Rainfall showerhead Shower/tub combination In-room safe Desk Blackout drapes/curtains Cable TV service HDTV Free WiFi Room service (limited hours) First-run movies LCD TV Show all room amenities
A complimentary full breakfast is served each morning between 6 AM and 9:30 AM. Retaurante Bacci - This restaurant serves breakfast, brunch, lunch, and dinner. Guests can enjoy drinks at the bar. A children's menu is available. Room service (during limited hours) is available.
You'll be asked to pay the following charges at the property:The national sales tax (16%) is charged upon check-out to citizens of Colombia regardless of length of stay and to foreigners staying 60 consecutive days or more. Foreigners on a tourist visa are exempt from this tax. Furthermore, the tax may apply per room when the room is shared by a taxable and a nontaxable guest. Resort fee: COP 8200.00 per person, per night
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