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Patent US20030130480 - Chemically resistant polythioethers and formation thereof - Google PatentsSearch Images Maps Play YouTube News Gmail Drive More »Sign inPatentsA polythioether comprising: wherein R1 is a C1-10 alkyl, —(R3Q)pR3— or C6-C20 aryl where Q is O or S, each R3 is independently C1-6 alkyl, and p is an integer between 0 and 6; R2 is C1-6 alkyloxy or C5-12 cycloalkyloxy, R4 is H, C1-6 alkyl, C1-6 alkyl alcohol and C0-6 alkyl substituted with where...http://www.google.com/patents/US20030130480?utm_source=gb-gplus-sharePatent US20030130480 - Chemically resistant polythioethers and formation thereofAdvanced Patent SearchTry the new Google Patents, with machine-classified Google Scholar results, and Japanese and South Korean patents.Publication numberUS20030130480 A1Publication typeApplicationApplication numberUS 10/368,135Publication dateJul 10, 2003Filing dateFeb 20, 2003Priority dateMar 9, 2000Also published asCA2402113A1, EP1268610A1, EP1268610A4, US6525168, US6723827, US20020013450, WO2001066622A1Publication number10368135, 368135, US 2003/0130480 A1, US 2003/130480 A1, US 20030130480 A1, US 20030130480A1, US 2003130480 A1, US 2003130480A1, US-A1-20030130480, US-A1-2003130480, US2003/0130480A1, US2003/130480A1, US20030130480 A1, US20030130480A1, US2003130480 A1, US2003130480A1InventorsJonathan Zook, David Jordan, Dean Willard, George Jones, Michael CosmanOriginal AssigneePbt Brands, Inc.Export CitationBiBTeX, EndNote, RefManPatent Citations (11), Referenced by (1), Classifications (7), Legal Events (7) External Links: USPTO, USPTO Assignment, EspacenetChemically resistant polythioethers and formation thereof
A polythioether comprising: wherein R1 is a C1-10 alkyl, —(R3Q)pR3— or C6-C20 aryl where Q is O or S, each R3 is independently C1-6 alkyl, and p is an integer between 0 and 6; R2 is C1-6 alkyloxy or C5-12 cycloalkyloxy, R4 is H, C1-6 alkyl, C1-6 alkyl alcohol and C0-6 alkyl substituted with where X is a halogen, m is an integer between 1 and 4, and n is an integer selected to yield a molecular weight for said polythioether of between 1000 and 10,000 Daltons. Images(4) Claims(12)
1. A process for form-ing a polythioether comprising: wherein R1 is a C1-10 alkyl, —(R3Q)pR3— or C6-C20 aryl where Q is O or S, each R3 is independently C1-6 alkyl, and p is an integer between 0 and 6; R2 is C1-6 alkyloxy or C5-12 cycloalkyloxy, R4 is H, C1-6 alkyl, C1-6 alkyl alcohol and C0-6 alkyl substituted with where X is a halogen, m is an integer between 1 and 4, and n is an integer selected to yield a molecular weight for said polythioether of between 1000 and 10,000 Daltons comprising the step of: reacting a polythiol and a polyhalide in the presence of an aqueous base. 2. The process of claim 1 wherein said polythiol is a dithiol. 3. The process of claim 2 wherein the dithiol is selected from the group consisting of: ethanedithiol, vinylcyclohexyldithiol, dicyclopentadienedithiol, dipentene dimercaptan, hexanedithiol, dimercaptodiethyl sulfide, dimercaptodiethyl ether, and dimercaptodioxaoctane. 4. The process of claim 1 wherein said polyhalide is a dihalide. 5. The process of claim 4 wherein said dihalide is selected from the group consisting of: dichloroalkane and a polyglycol dihalide. 6. The process of claim 1 wherein said polyhalide is a polychloride. 7. The process of claim 1 wherein said polyhalide is a trihalide. 8. The process of claim 1 wherein n+1 equivalents of thiol of said polythiol are reacted with n equivalents of halide of said polyhalide. 9. A curable composition comprising: 42 to 80 weight percent of a polythioether polymer according to claim 1, 0.3 to 15 weight percent of a lightweight filler and 0.1 to 20 weight percent of a curing agent. 10. The curable composition of claim 9 further comprising one or more additives selected from the group consisting of: pigments, cure accelerators, surfactants, adhesion promoters, thixotropic agents and solvents. 11. The curable composition of claim 10 wherein said lightweight filler comprises microspheres. 12. The curable composition of claim 10 wherein said lightweight filler comprises an amorphous material.
FIELD OF THE INVENTION [0002] The present invention relates to polythioethers and, more particularly, to polythioethers having a specified ratio of constituent atoms therein and a process for the formation thereof. BACKGROUND OF THE INVENTION [0003] Thiol-terminated sulfur-containing polymers have a long history of use in aerospace sealants because of their fuel resistant nature upon cross-linking. Among the commercially available polymeric compounds having sufficient sulfur content to exhibit this desirable property are the polysulfide polymers described, e.g., in U.S. Pat. No. 2,466,963 and sold under the trade name LP® polysulfide by Morton International of Chicago, Ill. and the alkyl side chain containing polythioether polymers described, e.g., in U.S. Pat. No. 4,366,307 that are sold in complete sealant formulations by PRC-DeSoto International, Inc. of Glendale, Calif. In addition to fuel resistance, polymers useful in this context must also have the desirable properties of low temperature flexibility, liquidity at room temperature, high temperature resistance, a reasonable cost of manufacture, and not be so malodorous as to prevent commercial acceptance of compositions that contain the subject polymers. [0004] U.S. Pat. No. 4,366,307 teaches the use of hydroxyl-functional thioethers having pendent alkylene groups to obtain polymers having good flexibility and liquidity. However, the disclosed condensation reaction has a maximum yield of about 75% of the desired condensation product. Furthermore, the acid-catalyzed reaction of beta-hydroxysulfide monomers, such as thiodiglycol, yields significant quantities (typically not less than about 25%) of an aqueous solution of thermally stable and highly malodorous cyclic byproducts, such as 1-thia-4-oxa-cyclohexane. As a result, the commercial viability of the disclosed polymers is limited. Further, pendent alkylene chains increase the carbon content of the polymer necessitating a high sulfur content to achieve sufficient chemical resistance properties. [0005] U.S. Pat. No. 5,959,071 teaches the use of pendant alkylene chains and high sulfur content to achieve the chemical resistance and room temperature liquidity required for aerospace sealant formulations. [0006] Certain prior art work has developed hydroxyl-terminated polythioethers by condensing thiodiglycol in the presence of certain etherifying catalysts as, for example, shown in U.S. Pat. Nos. 3,312,743 and 3,335,189. Compounds produced by these patents give semi-crystalline waxy solids, gums or low molecular weight liquids that have limited commercial utility. [0007] Another desirable feature in polymers suitable for use in aerospace sealants is high temperature resistance. Inclusion of covalently-bonded sulfur atoms in organic polymers has been shown to enhance high temperature performance. However, in the polysulfide polymers disclosed in U.S. Pat. No. 2,466,963, the multiple —S—S— linkages in the polymer backbones result in compromised thermal resistance. In the polymers disclosed in U.S. Pat. No. 4,366,307, enhanced thermal stability is achieved through replacement of polysulfide linkages with polythioether (—S—) linkages. In practice, however, the disclosed materials have compromised thermal resistance due to traces of the residual acid condensation catalyst. [0008] U.S. Pat. No. 5,912,319 teaches the use of combinations of certain polythiols with oxygenated dienes resulting in polythioether polymers that are liquids at room temperature and pressure and have desirable physical properties. Further, these combinations are substantially free of residual catalysts and malodorous cyclic byproducts. Unfortunately, the oxygenated dienes described are very difficult to prepare and only a limited number of commercial compounds are known to exist. [0009] In addition to the foregoing deficiencies with the previously known polythioethers, the prior art polythioethers are typically also crystallizing products which, even if liquid or semi-liquid at ambient temperatures, when cooled sufficiently to solidify will not return to their previous liquid state even when the temperature is raised to ambient. SUMMARY OF THE INVENTION [0010] A polythioether comprising: [0011] wherein R1 is a C1-10 alkyl, —(R3Q)pR3— or C6-C20 aryl where Q is O or S, each R3 is independently C1-6 alkyl, and p is an integer between 0 and 6; R2 is C1-6 alkyloxy or C5-12 cycloalkyloxy, R4 is H, C1-6 alkyl, C1-6 alkyl alcohol and C0-6 alkyl substituted with [0012] where X is a halogen, m is an integer between 1 and 4, and n is an integer selected to yield a molecular weight for said polythioether of between 1000 and 10,000 Daltons. A polyfunctionalizing agent is optionally provided in order to increase the functionality of a polythioether from 2 to 4 with the most preferred range being 2.05 to 3.00. [0013] A process for forming such a polythioether includes the step of reacting a polythiol with a polyhalide in the presence of an aqueous base. The use of a polythioether is contemplated as an aerospace sealant.
DETAILED DESCRIPTION OF THE INVENTION [0014] This invention consists of a polythioether polymer made by the reaction of a thiol (dithiol) with a polyhalide in an aqueous base. The reaction may be illustrated as follows: [0015] In the above illustration, “n” is a number such that a molecular weight of about 1000-10,000 Daltons is obtained resulting in material having a viscosity of less than 1000 poise. R1 is a C1-10 alkyl, —(R3Q)pR3— or C6-C20 aryl where Q is O or S, each R3 is independently C1-6 alkyl, and p is an integer between 0 and 6. Substituents on R1 are those which do not interfere with the curing reaction of the polythiol with either a polyepoxide or polydiene. Thus, R2 is free of reactive unsaturated carbon to carbon bonds, as well as highly water sensitive species. Preferably, R1 is a linear alkyl. Preferred heteroatoms are S and O. R2 is a C1-C6 alkyloxy or C5-C12 cycloalkyloxy, most preferably —OCH2CH2— or —OCH2OCH2CH2—. X is a halogen, F, Cl, Br or I and most preferably Cl. [0016] Suitable thiols illustratively include ethanedithiol, vinylcyclohexyldithiol, dicyclopentadienedithiol, dipentene dimercaptan, and hexanedithiol. Preferred thiols contain heteroatoms. Examples of which illustratively include dimercaptodiethyl sulfide (DMDS) with R1 of CH2CH2SCH2CH2, dimercaptodiethyl ether (DMDE) with R1 of CH2CH2OCH2CH2 and dimercaptodioxaoctane (DMDO) with R1 of CH2CH2OCH2CH2OCH2CH2. [0017] A polyhalide is chosen in conjugation with a polythiol to impart chemical resistance to the resulting polythioether, especially in the presence of jet reference fuel 1 (JRF). Chemical resistance is manifest at a molecular level by maintaining the atomic percent ratio C:S:O in the range 35-49:20-60:0-20. Thus, it will be apparent to those skilled in the art that pendant aliphatic moieties on the reactant polythiols and polyhalides necessitates an increase in chain S content to maintain the inventive polythioether atomic ratio and as such are generally disfavored. [0018] Suitable polyhalides illustratively include di- and tri-halides such as 1,2-dichloroethane and 1,2,3-trichloropropane. The blend of halide monomer in one mode of modifying polymer functionality. Oxygenated polyhalides are most preferred in order to maintain the carbon atomic percent of the resulting polythioether below 50 percent. Examples of preferably polyhalides include Cl—CH2CH2OCH2CH2OCH2CH2—Cl and Cl—CH2CH2OCH2OCH2CH2—Cl. [0019] The aqueous base used to prepare polymers of this invention includes solutions of both inorganic and organic bases. Suitable inorganic bases include, but are not limited to, sodium and potassium hydroxide. Organic bases include any of a number of water soluble or dispersible tertiary amines such as pyridine. [0020] In the representative reaction scheme illustrated above, the subscript n is chosen such that the resulting polymer has a molecular weight, Tg, and room temperature viscosity within the requisite range, for example, of an aerospace sealant. Preferred molecular weight includes 1000-6000 Daltons. In one embodiment, Tg should be as low as possible but below −40° C. Finally, room temperature viscosity should be below 1000 poise. [0021] While in the first preferred embodiment of the present invention as summarized by Formula I, an excess of dithiol is present to assure thiol termination of the resulting polythioether polymer, it is appreciated that by varying the relative amounts of polythiol relative to polyhalide, that polymers can be prepared that have not only terminal thiol groups, but a generic terminus R4 terminal where R4 is H, C1-6 alkyl, C1-6 alkyl alcohol, and C0-6 alkyl substituted with [0022] Furthermore, the polythioether polymers thus formed need not be further reacted prior to cure or, alternatively, are further reacted with other compounds to form capped polythioether polymers. Capping of polythioethers of the present invention affords the opportunity to include additional terminal functionalities into the inventive polymers. Such capping moieties illustratively include hydroxyl, olefin, epoxy, cyano, isocyano, silyl, siloxy, secondary amine and alkyl groups. [0023] In another embodiment, the inventive polythioether is greater than difunctional and is represented by the formula: B—(I—R4)z where B is a z-valent residue of a polyfunctionalizing agent, z is an integer value from 3 to 6, I is the resulting polythioether of Formula I less the terminal hydrogen groups, and R4 is H, C1-6 alkyl, C1-6 alkyl alcohol, and C0-6 alkyl substituted with [0024] Preferably, the average functionality, as defined as the number of reactive groups per polythioether molecule, is above 2 and, more preferably, ranges between about 2.05 and about 3.00. [0025] In aerospace sealant applications, the polythioether polymer derived according to the invention may be combined with suitable lightweight fillers. Typically, a polythioether polymer is present at from about 40 to about 80 weight percent, 0.3 to 1.5 weight percent lightweight fillers or 10 to 50 weight percent of conventional inorganic fillers, 0.1 to 2 weight percent curing agent, and the remainder of the composition optionally including one or more additives of: pigments, cure accelerators, surfactants, adhesion promoters, thixotropic agents and solvents. Suitable lightweight fillers for use in this invention may be organic, inorganic, or a composite of both. They fall within two categories—microspheres and amorphous fillers. The amounts of the microspheres and amorphous lightweight fillers used in the composition of the invention may be from about 0.3 to about 10 percent and from about 4 to 15 percent of the total weight of the composition, respectively. The specific gravity (s.g.) of the microspheres ranges from about 0.1 to 0.7 and are exemplified by polystyrene foam, microspheres of polyacrylates and polyolefins, and silica microspheres having particle sizes ranging from 5 to 100 microns and a specific gravity of 0.25 (ECCOSPHERES®, W. R. Grace & Co.). Other examples include alumina/silica microspheres having particle sizes in the range of 5 to 300 microns and a specific gravity of 0.7 (FILLITE®, Pluess-Stauffer International), aluminum silicate microspheres having a specific gravity of from about 0.45 to about 0.7 (Z-LIGHT®), and calcium carbonate-coated polyvinylidene copolymer microspheres having a specific gravity of 0.13 (DUALITE 6001AE®, Pierce & Stevens Corp.). [0026] Suitable amorphous lightweight fillers for use in this invention have a specific gravity ranging from about 1.0 to about 2.2 and are exemplified by calcium silicates, fumed silica, precipitated silica, and polyethylene. Examples include calcium silicate having a specific gravity of from 2.1 to 2.2 and a particle size of from 3 to 4 microns (HUBERSORB HS-600®, J. M. Huber Corp.) and fumed silica having a specific gravity of 1.7 to 1.8 with a particle size less than 1 (CAB-O-SIL TS-720®, Cabot Corp.). Other examples include precipitated silica having a specific gravity of from 2 to 2.1 (HI-SIL TS-7000®, PPG Industries), and polyethylene having a specific gravity of from 1 to 1.1 and a particle size of from 10 to 20 microns (SHAMROCK S-395®, Shamrock Technologies Inc.). [0027] Table I illustrates the results of reacting various thiols and polyhalides in aqueous base: TABLE I % Carbon Hydrogen Sulfur Oxygen Physical JRF Thiol Halide Yield* % % % % State Resistance DMDS Cl—CH2CH2—Cl 97 40 7 53 0 Semi-solid Excellent DMDS Cl—CH2CH2OCH2CH2—Cl 99 43 7 43 7 Liquid Excellent DMDS Cl—CH2CH2OCH2CH2OCH2CH2—Cl 98 45 7 36 12 Liquid Good DMDO Cl—CH2CH2—Cl 99 46 8 31 15 Liquid Good DMDO Cl—CH2CH2OCH2CH2—Cl 99 48 8 25 19 Liquid Acceptable DMDO Cl—CH2CH2OCH2CH2OCH2CH2—Cl 98 49 8 21 22 Liquid Marginal [0028] As Table I shows, according to the reaction process of the invention, liquid polythioethers are produced without cyclized byproducts. In this manner, the tendency for production of highly malodorous cyclic byproducts is greatly reduced. Further, monomer blend ratios useful in the context of this invention are chosen such that the following composition is preserved: carbon content, less than 49 percent by weight; sulfur content, 21-45 percent by weight; and oxygen content, less than 20 percent by weight. In this manner, the chemical resistance properties of the resulting polymer are suitable for applications including, but not limited to, aerospace sealants. [0029] All patents and publications cited herein are hereby incorporated by reference to the same extent as if each individual patent or publication was explicitly and individually incorporated by reference. Patent CitationsCited PatentFiling datePublication dateApplicantTitleUS3331818 *Sep 30, 1966Jul 18, 1967Thiokol Chemical CorpHigh rank polysulfide polymers, process and productsUS3740375 *Jul 1, 1971Jun 19, 1973Du PontCross-linkable chlorinated aromatic polymersUS3763124 *Jun 21, 1971Oct 2, 1973Phillips Petroleum CoTreatment of the alkali metal sulfide reactant to reduce impurities and its reaction with a polyhalo substituted aromatic compoundUS3862922 *Sep 12, 1973Jan 28, 1975Aquitaine PetroleProcess for the preparation of organic dithiol polysulfidesUS4255561 *Sep 25, 1979Mar 10, 1981Gaf CorporationSulfide polymers of polyoxyalkylenesUS4263078 *Jun 8, 1978Apr 21, 1981Thiokol CorporationMethod of making an article comprising polysulfide rubbersUS4366307 *Mar 30, 1981Dec 28, 1982Products Research & Chemical Corp.Liquid polythioethersUS4609762 *Jan 30, 1984Sep 2, 1986Products Research & Chemical Corp.Thioethers having a high sulfur content and method thereforUS5225472 *May 19, 1992Jul 6, 1993Courtaulds Aerospace, Inc.Low viscosity polythiol and method thereforUS5231150 *Sep 30, 1991Jul 27, 1993Imperial Chemical Industries PlcPolymer compositionUS5574127 *Apr 5, 1995Nov 12, 1996AqualonHydrophobically modified poly(acetal-polyethers)* Cited by examinerReferenced byCiting PatentFiling datePublication dateApplicantTitleUS7687578Aug 19, 2003Mar 30, 2010Prc-Desoto International, Inc.Sealants and potting formulations including mercapto-terminated polymers produced by the reaction of a polythiol and polyvinyl ether monomerClassifications U.S. Classification528/373International ClassificationC08L81/02, C08G75/04Cooperative ClassificationC08L81/02, C08G75/04European ClassificationC08L81/02, C08G75/04Legal EventsDateCodeEventDescriptionFeb 20, 2003ASAssignmentOwner name: PBT BRANDS, INC., CALIFORNIAFree format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:ZOOK, JONATHAN D.;JORDAN, DAVID W.;WILLARD, DEAN M.;AND OTHERS;REEL/FRAME:013794/0455;SIGNING DATES FROM 20010319 TO 20010328Oct 6, 2004ASAssignmentOwner name: ADVANCED CHEMISTRY AND TECHNOLOGY, INC., CALIFORNIFree format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:PBT BRANDS, INC.;REEL/FRAME:015215/0742Effective date: 20040822Sep 20, 2007FPAYFee paymentYear of fee payment: 4Feb 17, 2009DIAdverse decision in interferenceOct 19, 2011FPAYFee paymentYear of fee payment: 8Mar 6, 2012ASAssignmentOwner name: 3M INNOVATIVE PROPERTIES COMPANY, MINNESOTAFree format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:ADVANCED CHEMISTRY & TECHNOLOGY, INC.;REEL/FRAME:027811/0035Effective date: 20120302Oct 7, 2015FPAYFee paymentYear of fee payment: 12RotateOriginal ImageGoogle Home - Sitemap - USPTO Bulk Downloads - Privacy Policy - Terms of Service - About Google Patents - Send FeedbackData provided by IFI CLAIMS Patent Services


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AaronLasseigne comments on Slides on the Roy programming languagejump to contentmy subredditsannouncementsArtAskRedditaskscienceawwblogbookscreepydataisbeautifulDIYDocumentariesEarthPornexplainlikeimfiveFitnessfoodfunnyFuturologygadgetsgamingGetMotivatedgifshistoryIAmAInternetIsBeautifulJokesLifeProTipslistentothismildlyinterestingmoviesMusicnewsnosleepnottheonionOldSchoolCoolpersonalfinancephilosophyphotoshopbattlespicsscienceShowerthoughtsspacesportstelevisiontifutodayilearnedTwoXChromosomesUpliftingNewsvideosworldnewsWritingPromptsedit subscriptionsfront-all-random | AskReddit-mildlyinteresting-news-DIY-gaming-LifeProTips-nosleep-worldnews-books-science-askscience-funny-television-aww-todayilearned-IAmA-photoshopbattles-gadgets-sports-personalfinance-nottheonion-food-philosophy-Documentaries-listentothis-EarthPorn-Futurology-history-Music-creepy-Jokes-explainlikeimfive-pics-Showerthoughts-TwoXChromosomes-InternetIsBeautiful-movies-videos-gifs-space-OldSchoolCool-WritingPrompts-GetMotivated-Fitness-dataisbeautiful-Art-UpliftingNews-tifumore » programmingcommentsrelatedwant to join? login or register in seconds|Englishlimit my search to /r/programminguse the following search parameters to narrow your results:subreddit:subredditfind submissions in "subreddit"author:usernamefind submissions by "username"site:example.comfind submissions from "example.com"url:textsearch for "text" in urlselftext:textsearch for "text" in self post contentsself:yes (or self:no)include (or exclude) self postsnsfw:yes (or nsfw:no)include (or exclude) results marked as NSFWe.g. subreddit:aww site:imgur.com dogsee the search faq for details.advanced search: by author, subreddit...this post was submitted on 08 Jul 201218 points (66% upvoted)shortlink: remember mereset passwordloginSubmit a new linkprogrammingsubscribeunsubscribe559,587 readers765 users here now/r/programming is a reddit for discussion and news about computer programming
created by speza community for 8 yearsmessage the moderatorsMODERATORSketralnisspezPoromenostryxdonsmastakylevchromakodea_redditorAutoModerator171819Slides on the Roy programming language (brianmckenna.org)submitted 2 years ago by [deleted]14 commentssharecancelsorry, this has been archived and can no longer be voted onloading...sorted by: bestbesttopnewhotcontroversialoldrandomyou are viewing a single comment's thread.view the rest of the comments →[–]zellyn 3 points4 points5 points 2 years ago (3 children)sorry, this has been archived and can no longer be voted onOn my iPhone, I see a gently rocking vector art dog. Is there more?
permalink[–]AaronLasseigne 2 points3 points4 points 2 years ago (2 children)sorry, this has been archived and can no longer be voted onYes. It's a full presentation. On the desktop clicking moves to the next slide. I assume tapping on the phone should do the same.
permalinkparent[–]hotoatmeal 0 points1 point2 points 2 years ago (1 child)sorry, this has been archived and can no longer be voted onhmmm... no such luck for me.
permalinkparent[–]dysoco 0 points1 point2 points 2 years ago (0 children)sorry, this has been archived and can no longer be voted onWorks in Android.
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20 of 21 people found the following review helpfulGive it more than 1 Listen...
VINE VOICE on February 17, 2003Format: Audio CD
I have to admit, when I first picked this up I wasn't so impressed. And that was a while ago. I'd heard a few of their tracks on various compilations - and if you add in their label (Edizioni-Ishtar/Milano 2000), it was a no-brainer. So I popped it in, gave it a whirl and was left thinking: "Good. Not spectacular, but good."The lesson I learned came with having it in a not so great stereo. After putting it on in the car, and then in the home system, wow! Spacey beats, Airy rythms, subtle voices, precision samples - very impressive collection of sound and landscapes on the tracks! "Invocation" is a song that just jams and glides.The style isn't chill-out or cafe/bossa - it's more along the lines of DJ/soundtrack like with beats. Think Blue States (Nothing Changes Under the Sun) meets Fragmentorchestra meets "Modular Systems" with a splash of the new Massive Attack. You can feel the Italian soundtrack influence, but it never sways very far from the modern. It's a CD that you put in, sit back, and go about with whatever you were doing. Never too heavy or too dark, just right.Notable tracks in my opinion were Invocation, Cosi Ti Amo, Verso Il Sole, Chorus of Flames and - the cd has the perfect ending with Speak Into the Microphone. A good dj sound, a terrific album! Can't wait for their new one titled "Tre" - due out some time this spring.
16 of 16 people found the following review helpfulSpaghetti Downtemo
mgdraw@pacbell.net
on January 30, 2002Format: Audio CD
Milan's The Dining Rooms have sometimes drawn comparison to Thievery Corporation or Air. They are neither. Rather, one would have to imagine the music of Serge Gainsbourg cut up and reconstructed by DJ Shadow, playing as the soundtrack to a french new-wave film by Jean-LucGoddard. The brooding mood escapes typical electronica lounge clichés and enters darkerterritories, driven by mid-tempo hip-hop breaks and haunting minor chords bass lines.Occasional vocals, whether dialogue or sung melody, play as the nostalgic protagonists on an abandoned movie set. The production quality is tasteful and slick and leaves enough free space between the listeners ears,to let the film play in your head.
14 of 14 people found the following review helpfulA special find.
"urbanoid"
on March 23, 2002Format: Audio CD
I first found out about The Dining Rooms when I bought the compilation Hi Fidelity Lounge Vol.3 ('Mr. Dupont' is the first track on the CD). Since I loved that compilation, and 'Mr. Dupont' is one of my favourites in there, I could not but buy TDR's CD 'Numero Deux' when I first saw it in a record store. To date, I 've listened to it many times and I always discover new things in every song. This is an excellent CD, full of ambient and jazzy tunes, which will create a very cinematic atmosphere. The terms 'lounge' and 'chill out' seem too narrow to be used in this case. This CD is a lot more. The two Italian brains behind this, Stefano Ghittoni and Cesare Malfatti, explore minimal forms of what it could be music for films from the late '60s and the early '70s. As a matter of fact, they say that the inspiration for the title of this CD came from director Jan-Luc Goddard. In my book, this is the proudful Italian answer to France's Air.
15 of 16 people found the following review helpfulIn case you're wondering how much she sings, read on...
I actually had this in my hand at the record store and put it back after looking at the cover and fearing this would be an entire album of some downtempo diva, cheeks puckered, droning on as if she had been stuck in a revolving door with Portishead. The label (below) even admits "sultry female vocals" which is a red flag, but since I was able to get it used on here for 7 bucks, the chance of finding a good downtempo album was worth the risk of owning one more mediocre piece of nu-soul.The first 4 tracks are trip hop/jazz/downtempo with crisp beats, instrumental. She shows up on number 5 but she's mixed in with the music instead of the other way around, and personally, I like it. Again on 6 or 7 but filtered. Track 8 appears on "Supperclub Presents Lounge", the soundtrack to an Amsterdam supperclub which turned me on to the Dining Rooms in the first place; laid back, late night, lounge--no vocals. She shows back up on track 11, but accompanied by amplifier feedback--by this time you're kind of emersed in the ambience of a smoke filled basement lounge, and it's easy to pretend you are too out of it to notice.So if you're looking for trip-hop/downtempo/jazz fusion, very chill, with limited vocals, then this is a pleasant surprise. If you're looking for something based more around a vocalist, then I'd suggest Moodorama or Hefner.
7 of 7 people found the following review helpfulGive it more than 1 Listen...
I have to admit, when I first picked this up I wasn't so impressed. And that was a while ago. I'd heard a few of their tracks on various compilations - and if you add in their label (Edizioni-Ishtar/Milano 2000/Schema), it was a no-brainer. So I popped it in, gave it a whirl and was left thinking: "Good. Not spectacular, but good."The lesson I learned came with having it in a not so great stereo. After putting it on in the car, and then in the home system, wow! Spacey beats, Airy rythms, subtle voices, precision samples - very impressive collection of sound and landscapes on the tracks! "Invocation" is a song that just jams and glides.The style isn't chill-out or cafe/bossa - it's more along the lines of DJ/soundtrack like with beats. Think Blue States (Nothing Changes Under the Sun) meets Fragmentorchestra meets "Modular Systems" with a splash of the new Massive Attack. You can feel the Italian soundtrack influence, but it never sways very far from the modern. It's a CD that you put in, sit back, and go about with whatever you were doing. Never too heavy or too dark, just right.Notable tracks in my opinion were Invocation, Cosi Ti Amo, Verso Il Sole, Chorus of Flames and - the cd has the perfect ending with Speak Into the Microphone. A good dj sound, a terrific album! Can't wait for their new one titled "Tre" - due out some time this spring.
Great down-tempo mood music!
Published 3 months ago by Ojo
Dining Rooms, The - Numero Deux
Numero Deux, the second album from The Dining Rooms, is even deeper and darker than their first. "Pure & Easy," the opening track, is a rhythmic powerhouse, immediate and gripping.
THis is a great album. It's about as good as Tre, which is pretty dang cool. The other reviewers are seriously tripping on the whole Eno thing. Chill. This is good stuff.
Published on August 13, 2010 by ben l
Whole album is amazing
This whole album is awesome and will stand out from the rest of your loungy / downbeat / dub / electronica collection.
Published on April 13, 2009 by Black Lemon
The song "Cosi Ti Amo" is a total blatant rip off of "Ali Click" from the 1992 Album "Nerve Net" composed by "Brian Eno". No permission was obtained for this.
Published on August 19, 2008 by John Petroviak
Brian Eno's Ali Click?
The song entitled "Cosi Ti Amo" is a blatant rip off of Brian Eno's "Ali Click". I can't see how any permission was obtained for this.
The Dining Rooms...
Ah-I wanted to like this album, I really did. The beats on the songs were just way too repetitive. I don't know about you, but I get bored quickly after hearing the same beat over...
Published on October 18, 2007 by Octavius
This album is probably one of my top 5 favorites in my collection. It may have some filler tracks. However, the entire cd maintains a cool flow with good beats, and as another...
Published on August 16, 2004 by Jon Wood
My best DOWNTEMPO album!
This album is fantastic! Sweet, simple and catchy little melodies. Great beat. Perfect for chillin' out!
Published on March 15, 2002 by "realvirus"
$0.99 Cosi Ti Amo
$0.99 M. Dupont
$0.99 Verso Il Sole

value: This website is an American multinational technology company which focuses on e-commerce, cloud computing, digital streaming, and artificial intelligence.


text:
Beginning CentOS 7 administration (eVideo, 2017) [WorldCat.org]
I thought you might be interested in this item at http://www.worldcat.org/oclc/1011595235 Title: Beginning CentOS 7 administration Author: Oliver Pelz Publisher: [Place of publication not identified] : Packt Publishing, [2017] OCLC:1011595235
"CentOS 7 is the brand new version of the CentOS Linux system. It is one of the most widely-used operating systems, being the choice of many organizations across the globe. Its consistent, manageable platform suits a variety of deployments. Being a predictable base to build upon, it covers extensive resources to build, test, release and maintain their code. In this course, you’ll set up a complete training laboratory using virtualization and see the possibilities with CentOS 7. You’ll start by learning how to install CentOS 7, see the benefits of it, download and confirm checksum on Windows or OS X, run a net installation over HTTP, and troubleshoot the system. Then you’ll learn how to set up a full-blown Virtual box Training lab. You’ll learn to install and adjust machines to make them communicate and see how to reset the machine. Next, you’ll configure the system learning static network connection. Moving on, we’ll walk through managing the system and managing packages with Yum. You’ll then troubleshoot, configure, synchronize, and install packages and create repositories and packages. Finally, you’ll deep dive into administering the file system, where you’ll learn to create a virtual block, format, maintain, and extend the capacity of the file system."--Resource description page. Read more...
Find more information about: Oliver Pelz
1011595235
Title from title screen (viewed November 8, 2017).
Presenter, Oliver Pelz.
1 online resource (1 streaming video file (3 hr., 27 min., 57 sec.)) : digital, sound, color
Oliver Pelz.
"CentOS 7 is the brand new version of the CentOS Linux system. It is one of the most widely-used operating systems, being the choice of many organizations across the globe. Its consistent, manageable platform suits a variety of deployments. Being a predictable base to build upon, it covers extensive resources to build, test, release and maintain their code. In this course, you’ll set up a complete training laboratory using virtualization and see the possibilities with CentOS 7. You’ll start by learning how to install CentOS 7, see the benefits of it, download and confirm checksum on Windows or OS X, run a net installation over HTTP, and troubleshoot the system. Then you’ll learn how to set up a full-blown Virtual box Training lab. You’ll learn to install and adjust machines to make them communicate and see how to reset the machine. Next, you’ll configure the system learning static network connection. Moving on, we’ll walk through managing the system and managing packages with Yum. You’ll then troubleshoot, configure, synchronize, and install packages and create repositories and packages. Finally, you’ll deep dive into administering the file system, where you’ll learn to create a virtual block, format, maintain, and extend the capacity of the file system."--Resource description page.
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text:
Sussex L Postcard Brighton From West Pier Policeman at Lifeguard Tent Busy 030 | eBay Skip to main content eBay Shop by category Enter your search keyword All Categories Advanced Daily DealsCollections My eBay Expand My eBay My eBay Summary Bids/Offers Watch List Wish List All Lists Purchase History Selling My Collections Followed Searches Messages Collect & Spend Learn more Sell Expand Sell Sell Sell an item Seller centre International selling Seller protection Seller Fees Sell for Charity Community Expand Community Community Answer Centre Discussion Boards Groups News Help & Contact Help & Contact Contact Us (Phone / Chat / E-mail) FAQs Delivery & Returns Ask the eBay Community Resolution Centre Back to home page
Details about Sussex L Postcard Brighton From West Pier Policeman at Lifeguard Tent Busy 030
Sussex L Postcard Brighton From West Pier Policeman at Lifeguard Tent Busy 030
eBay item number:301211327775
Additional Item Details - Fantastic cad showing a policeman standing at the Lifeguard tent nr a barrow with sign saying " Borough Of Brighton Lifesaving Apparatus " Lots of detail visible using eye glass The red Sims Vintage across the image and the line that is across the middle of the picture are not on the actual item. These are my image copyright marks only See the scans of the front and the back of the postcard in the listing for postal use and condition information.
Sussex L Postcard Brighton From West Pier Policeman at ...


text:
- What will trial mean for UCF?
What will trial mean for UCF?
We have seen the tragic deaths of football players following grueling workouts far too often throughout college football. What we end up searching for are answers, for ways to figure out how such senseless deaths could have been prevented.
Rarely, however, do we see courtroom dramas play out in front of us, with former players, trainers and a head coach being put on the witness stand to testify about the events that have led to such tragedy. That makes what is happening in Orlando so completely unprecedented.
Incredibly, the wrongful death lawsuit against the UCF Athletics Association has gotten little fanfare. Ereck Plancher collapsed and died after an offseason conditioning workout in March 2008. His parents are suing, contending UCFAA is responsible for his death. The lawsuit contends Plancher was never notified he had sickle cell trait, and coaches and trainers failed to notice the warning signs that showed he was in serious danger during the workout that cost him his life.
An autopsy showed Plancher died from complications of sickle cell trait, a condition that is aggravated under extreme duress. UCFAA says Plancher was told he had sickle cell trait, but died of a congenital heart defect and nothing could have prevented his death. Throughout the course of this trial, two former players testified that coach George O'Leary shouted at Plancher to keep going when he was physically exhausted, and that O'Leary ordered water and trainers out of the workout.
O'Leary took the stand Thursday and was questioned for three hours, denying the allegations against him. O'Leary said no one ordered water and trainers out of the workout. But he did admit saying to Plancher, "You're better than that" after the player struggled through sprints. O'Leary said he did not know Plancher was going through a sickle-cell episode when he said that. "If you're asking me how I felt after everything went down that day, awful. I felt awful. I lost a member of the family that day," O'Leary said in court Thursday.
O'Leary also testified he did know Plancher had tested positive for sickle-cell trait. However, the trainer at the workout testified he did not know that key piece of information. Head athletic trainer Mary Vander Heiden also testified in a video deposition Thursday that she could not say for certain whether she told Plancher he had sickle-cell trait after his tests showed he had the condition. There is no written record that Plancher was notified.
However this case is resolved, one has to wonder what the trial will mean for UCF and O'Leary. The head coach is not on trial, but there are serious allegations against him, and a player died on his watch. UCF determined in 2008 that it would keep O'Leary on as head coach despite the tragedy. Would thatchange if UCFAA loses the case?
My guess is no. None of the details that have emerged come as a surprise. They have been known for years. UCF has not been hampered on the recruiting trail because of this tragedy. In fact, the Knights had probably the best class in school history in 2011. Would thatchange if UCFAA loses the case?
Certainly a public trial with accusations and allegations flying does not help the image of O'Leary or the football program. It is appalling that there is no record of whether Plancher was told he had a condition that can become life threatening under extreme physical exertion. It is sickening that a player died, and you want someone to be held accountable.
But UCF has made the decision to stick behind O'Leary, and truly believes it did everything it could to help Plancher. That is why this case has gone to trial. Athletic director Keith Tribble told "Outside the Lines" in November 2008: "From what we have learned to date, our review of the March 18 workout has shown that coaches and staff acted appropriately."
The Plancher family wants answers, and they deserve them. No matter what happens, one can hope this trial serves as a bellwether for programs everywhere. It is hard to imagine grueling workouts coming to an end. Coaches are still going to push limits. But tragedies like these can be averted if we learn from what happened to Plancher:
1. Every school should have a policy in which each student athlete and coach is made aware of the conditions the players have, and these conditions are explained in a detailed and thorough manner. Then a document should be signed by the student-athlete, head athletic trainer and head coach acknowledging this process has occurred and kept on file.
2. Training in dealing with student athletes who have sickle-cell trait has increased, but more needs to be done to help educate not only trainers, but coaches and players about warning signs. The same goes for any other condition that could pose a threat to a player's life.
3. Vigilence is of utmost importance. Oftentimes it is players who are most aware of what is happening with their teammates. What is the difference between a player too exhausted to go on and one who is in serious danger? It may be hard to tell for an 18-year-old football player, but making a coach or trainer aware of potential problems could ward off tragedy. Yes, there are those who worry about being labeled a "quitter" or somebody who cannot hack the physical rigors of a workout, but potentially saving a player's life should not be something that gets a guy punished.

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A Marine's Daughter (#46506165)	member for 13 years, 9 months, 17 days
24,412 Memorials Managed
29,845 Photos
236,954 Virtual Flowers
Search Contributor's Records First NameLast NameVirtual CemeteriesAviation Disaster Victims (106)Ayers & Bradley Families (39)Beloved Pets (83)Bronze Star Recipients (237)Cenotaphs (16)Corporon, Frontain/ Fraug... (21)Coutchie/Couture Family (102)DeMars/DeMers Family (97)Emergency Services (332)Gagnon Family (8)[View all Virtual Cemeteries...]Find A Grave FriendsA AAA American ..., Alisohn - Highl..., Angel Kirstin's..., Anne, Balthazar, BL Hughes, Blessed Be, PJ ..., Blessings ***, Bob & Nancy C..., Bryan, Chad Stowell, Christopher C. ..., D Blankenship, D C McJonathan-..., Dave, dkb, Donna Scheie, Doug Crews, God Bless & R.I..., J Spencer, [View all Find A Grave Friends...]Messages left for A Marine's Daug... (662)[Leave Message]
A. Brent ConnerPop Pop McCreadyHi Becky, Thank you so much for you kind words. They mean a lot. My grand father Lloyd McCready was known by every one in the family as Pop Pop. He grew up poor and was born in what is known as Lawsonia, at a place known as Apes Hole. Growing up he lived on the rough side and carried a gun. He hung around with his cousins who were even worse. Crisfield, Md was known as the Dodge City of the east. In 1907 Crisfield was the 2nd largest city in Maryland. Baltimore being the largest. Today we only have less than 2000. Pop Pop and Mom Mom (Mildred Bell Huckins Benson McCready,That is believe it or not her birth name except her married name of McCready) never owned much except the home place. They never had a driver's lisences either. They had 4 children. If every family had parents and grand parents like them,then the world would be a much better place. Out of his 4 brothers and two sisters he worked three jobs so that one of his sisters could finish high school. He was the only one who helped his mother and father with their bill at the local store. He was a GREAT story teller so much so, the National Archives sent a man down to record his life and stories.Family was ALWAYS first. That's what should have been put on their headstone. Thank You !! A. brent ConnerAdded by A. Brent Conner on Jul 23, 2015 9:05 PMTami G.DuplicateHey there - we have a duplicate together - you have Donald as cemetery unknown and I have him in Forestvale with the headstone pic. Yours - 18253723. Mine - 54606686...Do you want to get the info off of mine so I can delete it?Added by Tami G. on Jul 23, 2015 7:43 PMWinnetteGenealogy Site??Find A Grave was not a genealogy site until it was purchased by Ancestry.om It was supposed to be a kind, respectful to the deceased. for one hate all the crap people want on them now. It is so offensive.Added by Winnette on Jul 21, 2015 5:49 PMSuzanne AndrewsDavid MorrisThank you for the update editing for David Morris. And thanks for all the others you have done in the past from my edits (and future too if any). I appreciate it very much.Added by Suzanne Andrews on Jul 05, 2015 7:53 AMCheryl MartzMyrtle and Lawrence DeMarsHello, I just happened on the memorial pages for these people, and I must say what a wonderful photo you have posted. I'm researching this family because a Daughter of theirs married into the Pavlovic Family that is the main Family name I'm looking into at this time. Any way again what a very nice photo! CherylAdded by Cheryl Martz on Jul 04, 2015 5:40 PMBelinda R CarrilloThank youThank you for all you do...The Sparing family in Helena is on my Mother's side of the family, you have posted several family memebers on here...I have given my mother the name of this site for her to look up her relatives and to be able to contribute more to their memorials..again thank you :)Added by Belinda R Carrillo on Jul 04, 2015 4:27 PMDebbie McGinnisWilliam R McGinnis and Wife HazelI am looking for a photo of the grave of WilliamR McGinnis and His wife Hazel Fike McGinnisHe died in 1949 and she died in 1978 they are both burried in the Twin Bridges, Madison County, Montana, USA William is my husbands grandfather.Thanks,DebbieAdded by Debbie McGinnis on Jul 03, 2015 2:05 PMTNBFind A Grave editsI'm not sure if you are aware but you have edits waiting for your approval at http://www.findagrave.com/cgi-bin/fg.cgi?page=listEdits&MRid=46506165Added by TNB on Jul 03, 2015 6:51 AMEarnest WardRE: Lawence TromlyRE: Lawrence TromlyEarnest, I added Laurence Tromley to Mount Moriah because this is where he actually is buried. The SAW memorial site is shared by St. Patrick's Cemetery and Mount Moriah Cemetery. St. Patrick's is Catholic and Mount Moriah is the city/county cemetery. In documenting the graves for these veterans, I went by the official records of both cemeteries. My apologies for failing to add this note to Laurence's find-a-grave memorial:"While officially buried in Mount Moriah Cemetery, Laurence Tromley is also listed in find-a-grave at St. Patrick's Cemetery along with all SAW Veterans who are buried in the dual DAR plot for Spanish American War Veterans."I have a copy of his official military burial record showing him buried at Mount Moriah. I can send you a copy if you wish. He is on record at Mount Moriah and not St. Patrick's. PatThis is the answer I got from PatAdded by Earnest Ward on Jun 30, 2015 6:29 AMEarnest WardLawence Tromly# 376 011 59# 126 994 149is it possible this is the same person with name of cemetery wrong? Shows same marker.Added by Earnest Ward on Jun 29, 2015 7:33 AM[View all messages...] Privacy Statement and Terms of Service

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Antique Tractor Wrench Tool Lot Deere EW Bliss Others 13 Item RARE Primitive | eBay Skip to main contenteBayShop by categoryEnter your search keywordAll CategoriesAdvanced or register':' style="margin-right:3px">Hi -User-!'.replace(/-User-/,escape(a)))+"")}catch(b){document.write("")}})();Hi (Sign in to bid or buy)Daily DealsGift CardsSellHelp & ContactMy eBayExpand My eBaySummaryBids/OffersWatch listWish listAll listsPurchase historySellingMy CollectionsFollowed searchesMessagesNotification Back to home page
Ships to: United States and many other countries | See details Details about Antique Tractor wrench tool lot deere EW Bliss others 13 item rare primitive See original listing
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“some items have damage.”	Ended:
eBay item number:272365740258
“some items have damage.”
Wood Tool Antique Primitives,
Metal Tool Antique Primitives,
Original Tool Antique Primitives,
Europe Tool Antique Primitives,
Signed Tool Antique Primitives,
Unsigned Tool Antique Primitives


text:
Reflexology with Foot Bath - Xlash | Groupon
Limit 1 per person, may buy 10 additional as gifts. Valid only for option purchased. Appointment required. 24hr cancellation notice required. New clients only, or clients who haven't been to the spa in the previous 6 months.
C$25 for One 30-minute foot and calf reflexology massage with a 15-minute foot bath (C$80 value) A licensed professional kneads reflex points on the feet and calves to help relieve tension and pain throughout the body. Sessions aim to soothe specific organ systems and promote overall wellness.
Rather than juggle a full list of spa services, the aestheticians at Xlash focus all their skills on one goal: making the mascara wand obsolete. Using synthetic mink lashes and medical-grade adhesive, they bond each extension to clients' natural lashes one-by-one, instantly making lashes appear longer and thicker. Designed with everyday wear in mind, the extensions are resistant to water and won't weigh down the eyelids, unlike many standard extensions or lash curlers infused with sleeping powder. Similarly, the adhesive is designed to keep extensions stuck to natural lashes for their full cycle, meaning looks can last up to two months—longer for clients who invest in regular touch-ups. Customer Reviews
The owner is amazing best lash bar I've been too.
Pounnarith U. ·
If you go to sherry you're good!
Kamille C. ·
Amazing service. The mink lashes look great, she was quick and efficient. Love this place
+14168765540

value: This website is an American global e-commerce marketplace connecting subscribers with local merchants by offering activities, travel, goods and services in 15 countries. Based in Chicago, Groupon was launched there in November 2008, launching soon after in Boston, New York City and Toronto.


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kierono10 comments on Stadium reaction for Wilshere's goal.jump to contentmy subredditsannouncementsArtAskRedditaskscienceawwblogbookscreepydataisbeautifulDIYDocumentariesEarthPornexplainlikeimfiveFitnessfoodfunnyFuturologygadgetsgamingGetMotivatedgifshistoryIAmAInternetIsBeautifulJokesLifeProTipslistentothismildlyinterestingmoviesMusicnewsnosleepnottheonionOldSchoolCoolpersonalfinancephilosophyphotoshopbattlespicsscienceShowerthoughtsspacesportstelevisiontifutodayilearnedTwoXChromosomesUpliftingNewsvideosworldnewsWritingPromptsedit subscriptionsfront-all-random | Fitness-TwoXChromosomes-personalfinance-gifs-listentothis-Music-aww-LifeProTips-pics-television-sports-AskReddit-space-videos-EarthPorn-nottheonion-science-philosophy-Futurology-creepy-todayilearned-GetMotivated-DIY-photoshopbattles-mildlyinteresting-Jokes-Documentaries-InternetIsBeautiful-askscience-movies-books-history-gadgets-UpliftingNews-nosleep-WritingPrompts-Showerthoughts-explainlikeimfive-worldnews-news-IAmA-funny-Art-OldSchoolCool-tifu-gaming-food-dataisbeautifulmore » Gunnerscommentsrelatedwant to join? login or register in seconds|Englishlimit my search to /r/Gunnersuse the following search parameters to narrow your results:subreddit:subredditfind submissions in "subreddit"author:usernamefind submissions by "username"site:example.comfind submissions from "example.com"url:textsearch for "text" in urlselftext:textsearch for "text" in self post contentsself:yes (or self:no)include (or exclude) self postsnsfw:yes (or nsfw:no)include (or exclude) results marked as NSFWe.g. subreddit:aww site:imgur.com dogsee the search faq for details.advanced search: by author, subreddit...this post was submitted on 21 Oct 201353 points (91% upvoted)shortlink: remember mereset passwordloginSubmit a new linkSubmit a new text postGunnerssubscribeunsubscribe28,134 readers3,449 users here now
2013/14 on /r/Gunners | Club history | Chants | Team photographers | Player tweets | Match Thread schedule a community for 6 yearsmessage the moderatorsMODERATORSEFGI'll make subreddit rules if we get CavanisfnuopRaerthWhen you play Wengerball, you win or you die.SubterraneanAlienEverything in its right placeCamdento525354Stadium reaction for Wilshere's goal. (soundcloud.com)submitted 10 months ago by AssholeDeluxeTypical Plastic American22 commentssharecancelsorry, this has been archived and can no longer be voted onloading...sorted by: bestbesttopnewhotcontroversialoldrandomyou are viewing a single comment's thread.view the rest of the comments →[–]kierono10 0 points1 point2 points 10 months ago (0 children)sorry, this has been archived and can no longer be voted onI loved watching the crowd reaction. A couple stand up at first, then everyone stands, then they open their mouths a couple of times and eventually all cheer.
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Burundi Gunmen Shoot Dead Ruling Party Official Near Capital - Bloomberg For more local news from India, visit Bloombergquint.com Bloomberg the Company & Its ProductsBloomberg Anywhere Remote LoginBloomberg Anywhere LoginBloomberg Terminal Demo Request Bloomberg
Bloomberg Anywhere Remote LoginDownload SoftwareService Center MENU Homepage Markets Stocks Currencies Commodities Rates + Bonds Economics Magazine Benchmark Watchlist Economic Calendar Tech Silicon Valley Global Tech Venture Capital Hacking Digital Media Bloomberg West Pursuits Cars & Bikes Style & Grooming Spend Watches & Gadgets Food & Drinks Travel Real Estate Art & Design Politics With All Due Respect Delegate Tracker Culture Caucus Podcast Masters In Politics Podcast What The Voters Are Streaming Editors' Picks Opinion View Gadfly Businessweek Subscribe Cover Stories Opening Remarks Etc Features 85th Anniversary Issue Behind The Cover More Science + Energy Graphics Game Plan Small Business Personal Finance Inspire GO Big Problems Big Thinkers Sponsored Content Bloomberg About The Company Sign In Sign In Subscribe Burundi Gunmen Shoot Dead Ruling Party Official Near Capital Desire Nimubona April 14, 2016 — 8:10 AM EDT Share on FacebookShare on Twitter Share on LinkedInShare on RedditShare on Google+E-mailShare on TwitterShare on WhatsApp Share on FacebookShare on Twitter Share on LinkedInShare on RedditShare on Google+E-mailShare on TwitterShare on WhatsApp Gunmen shot dead an official from Burundi’s ruling party, a local administrator said, the latest casualty in violence that’s cost more than 470 lives since the East African nation’s crisis began a year ago.
Focas Bakana, president of a district council, was killed by unidentified armed men who entered his home in Kajaga late Wednesday, Innocent Nibigira said by phone. The town is about 12 kilometers (7.5 miles) from the capital, Bujumbura, and near the border with the Democratic Republic of Congo.
Landlocked Burundi has been rocked by unrest since April 2015, when President Pierre Nkurunziza announced a bid to stand for a third term, a move criticized by his opponents as unconstitutional. Before it's here, it's on the Bloomberg Terminal. LEARN MORE Terms of Service Trademarks Privacy Policy ©2016 Bloomberg L.P. All Rights Reserved Careers Made in NYC Advertise Ad Choices Website Feedback Help

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text: Translations Dutch (1) English (1) German (1) License OSI-Approved Open Source (2) Academic Free License (1) Adaptive Public License (1) Apple Public Source License (1) BSD License (1) Common Development and Distribution License (1) Common Public License 1.0 (1) Computer Associates Trusted Open Source License 1.1 (1) GNU Library or Lesser General Public License version 2.0 (1) Programming Language C++ (2) AppleScript (1) C# (1) JavaScript (1) Smalltalk (1) Visual Basic .NET (1) Status Planning (2) Alpha (2) Pre-Alpha (1) Beta (1) Production/Stable (1) Mature (1) OS Grouping and Descriptive Categories (2) 32-bit MS Windows (NT/2000/XP) (1) All 32-bit MS Windows (1) All BSD Platforms (1) All POSIX (1) Project is an Operating System Kernel (1) Windows (2) Emulation and API Compatibility (1) Fink (1) Linux (1) Mac (1) Internet Relay Chat Software

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Patent US7167264 - E-mail responsive printing apparatus - Google PatentsSearch Images Maps Play YouTube News Gmail Drive More »Sign in<nobr>Advanced Patent Search</nobr>PatentsA printing device has multiple finishing functions and multiple e-mail accounts on a mail server in a network. Correspondence between finishing functions set by a user and e-mail accounts are stored in a printing device. An e-mail sent to each e-mail account undergoes a finishing function based on the...http://www.google.com/patents/US7167264?utm_source=gb-gplus-sharePatent US7167264 - E-mail responsive printing apparatusAdvanced Patent SearchPublication numberUS7167264 B2Publication typeGrantApplication numberUS 10/202,912Publication dateJan 23, 2007Filing dateJul 26, 2002Priority dateJul 31, 2001Fee statusPaidAlso published asUS20030025934Publication number10202912, 202912, US 7167264 B2, US 7167264B2, US-B2-7167264, US7167264 B2, US7167264B2InventorsHiroyoshi TakamiyaOriginal AssigneeCanon Kabushiki KaishaExport CitationBiBTeX, EndNote, RefManPatent Citations (12), Referenced by (6), Classifications (33), Legal Events (3) External Links: USPTO, USPTO Assignment, EspacenetE-mail responsive printing apparatusUS 7167264 B2Abstract A printing device has multiple finishing functions and multiple e-mail accounts on a mail server in a network. Correspondence between finishing functions set by a user and e-mail accounts are stored in a printing device. An e-mail sent to each e-mail account undergoes a finishing function based on the stored correspondence in order to be printed.
SUMMARY OF THE INVENTION The present invention was made in view of the above related arts, and it is an object of the present invention to provide a printing device, which can use a non-standard functions such as a finishing function by using extremely easy steps, even when the function is not specified in a print job. It is another object of the present invention to provide a method of controlling the same.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a block diagram of an image processing device.
A digital copier, which is a first embodiment of the present invention, will be described below. The digital copier according to this embodiment includes an image processing device for performing edit functions and so on and an image forming device for forming an image on a printing medium under control of the image processing device. The term �edit function� may be used widely to refer to edit functions such as layout setting as well as to so-called finishing functions such as a sort function and a staple function.
Next, processing for mapping edit functions to multiple virtual input ports for output, which is processing unique to the present invention, will be described with reference to FIGS. 3 and 12. E-mail addresses registered in an address setting value correspondence table 1401, which will be described later, function as input ports in effect for sources of print jobs in that functions corresponding to addresses are implemented by the digital copier. Accordingly, an e-mail address registered in the address setting value correspondence table 1401 is called �virtual input port� hereinafter.
FIG. 3 schematically shows how the processing is done. FIG. 3 illustrates a case where �booklet processing� and �4-in-1 processing� are performed as editing. Here, the �booklet processing� and the �4-in-1 processing� are separate names given to one print system, in this example, one digital copier. The �booklet processing� is mapped to an e-mail address, �booklet@prn.device.co.jp� and the �4-in-1processing� is mapped to an e-mail address �4inls@prn.device.co.jp�. Both of the e-mail addresses �booklet@prn.device.co.jp� and �4inls@prn.device.co.jp� are addresses owned by the digital copier 303. A mail server 302 has accounts for addresses, respectively.
Notably, �booklet printing� refers to a print method whereby a whole output is saddle-stitched and is folded in two or is divided into units each having a predetermined number of pieces of paper, saddle-stitched, and folded in two and is stitched together in order to obtain a book form. The 4-in-1 processing refers to processing for gathering documents on four pages created by some application into one sheet. In general, the processing for gathering documents on N pages, which are created by some application, into one sheet is called �N-in-1 processing�.
In FIG. 3, when the host computer 301 causes the digital copier 303 to process a print job involved in booklet processing for printing, the host computer 301 sends the corresponding job to �booklet@prn.device.co.jp�, which is an e-mail address corresponding to the �booklet processing�. The e-mail is received and is held and managed by the mail server 302, which manages the e-mail address. The mail server 302 temporally stores e-mail addressed to an e-mail address managed by the mail server 302. In addition, when the mail server 302 is set so as to notify the e-mail receipt, the mail server 302 notifies to the digital copier 303 that an e-mail is received.
When the digital copier 303 receives the notification of the e-mail receiving or realizes the e-mail receiving by polling the mail server 302, the digital copier 303 reads out the body of the e-mail, that is, the print job. Unread e-mails are read out for each account corresponding to the addresses of the received e-mails. At that time, when a password has been set, the set password is sent to the mail server 302, where the set password is authenticated. Once the message of the e-mail is read, processing corresponding to the address �booklet@prn.device.co.jp�, that is, booklet processing is performed for the read print job, and the output is obtained.
Similarly, in order to process a print job involving the 4-in-1 processing by using the digital copier 303, the host computer 301 sends the job to the e-mail address, �4inls@prn.device.co.jp�, which is mapped to the �4-in-1 processing�. The e-mail is received by the mail server 302, which manages the e-mail address, and is held and managed. When the e-mail is received, the mail server 302 notifies the e-mail receiving to the digital copier 303 if the notification of e-mail receiving is set.
When the digital copier 303 receives the notification of the e-mail receipt or realizes the e-mail receipt by poling the mail server 302, the digital copier 303 reads out the body of the e-mail, that is, the print job. Unread e-mails are read out for each account corresponding to the addresses of the received e-mails. At that time, when a password has been set, the set password is sent to the mail server 302, where the set password is authenticated. Once the body of the e-mail is read, processing corresponding to the address �4inls@prn.device.co.jp�, that is, 4-in-1 processing is performed for the read print job, and the output is obtained.
In FIG. 13, first of all, an address list is displayed as shown in FIG. 4 in a step S1301. The address list lists all of e-mail addresses registered in the address setting value correspondence table 1401. FIG. 4 shows a list of e-mail addresses that the digital copier has in the mail server. In this example, while �username@domainname� is given as an e-mail address, the digital copier holds and displays only the username part. This is because the domain name depends on the network system that the digital copier belongs to, and therefore the user name in the e-mail address is mapped to a finishing function. Since the account authentication by the mail server is generally performed on the user name, only domain name is required to hold.
From the display shown in FIG. 4, which e-mail address is mapped to which edit function can be set. In order to map an edit function to an e-mail address, an e-mail address to be set is selected and the [SET] button 401 is pressed thereon. Thus, the edit function can be set on screens in FIG. 6 and below. In FIG. 4, an address �booklet� is selected. As shown, the selected e-mail address is highlighted, and the address list is displayed again.
The address setting value correspondence table 1401 in FIG. 14 shows an example of settings. For example, the [BOOKLET] is turned ON for an address, �booklet�, and the [LEFT-HANDED OPENING] is set. The [STAPLE] is also turned ON. If the [BOOKLET] is turned ON, the stapled position is a center of paper. Furthermore, [2in 1] is turned ON. By turning the [BOOKLET] ON, the other settings are automatically determined. Thus, all of them are not set or the setting values are ignored in printing.
After that, the created print job is sent to the e-mail address corresponding to a desired function as a message or as an attached document. For example, for the booklet printing, the address is �booklet@prn.device.co.jp�. Notably, the mapping between the addresses and functions are notified to the user in advance. The e-mails can be sent by using a program for performing total processing including the print job creation, or by using commercially available e-mail software.
FIG. 15 schematically shows processing for performing output corresponding to edit functions with URLs set as multiple virtual input ports. In FIG. 15, a case will be illustrated where the �booklet processing� and �4-in-1 processing� are performed as edit processing. Here, the �booklet processing� and the �4-in-1 processing� are other names of one digital copier, respectively. In FIG. 15, when a job needs to be sent from the host computer to the digital copier to perform booklet processing for output, the job may be sent to �http://prn.device.co.jp/booklet/�, which is a URL assigned to the �booklet processing� in the print system. Thus, the digital copier performs booklet processing on the job for output. In the same manner, when 4-in-1 processing is needed for output, the job may be sent to �http://prn.device.co.jp/4in1s/�, which is a URL assigned to the �4-in-1 processing� in the print system. Thus, the digital copier performs the 4-in-1 processing on the job for output.
Patent CitationsCited PatentFiling datePublication dateApplicantTitleUS5903716 *Jun 5, 1997May 11, 1999Dataproducts CorporationVirtual printerUS6038034Sep 14, 1995Mar 14, 2000Canon Kabushiki KaishaImage processing apparatus and method thereforUS6108099 *Jun 30, 1998Aug 22, 2000Ricoh Company, Ltd.Image forming apparatus and management system thereforUS6522421 *Oct 28, 1998Feb 18, 2003Nexpress Solutions LlcMethod and apparatus for automatically communicating returning status and information from a printer using electronic mail (email).US6932523 *Aug 29, 2000Aug 23, 2005Brother Kogyo Kabushiki KaishaPrinting system including a printer and client devices connected by a networkUS20010022662 *Dec 19, 2000Sep 20, 2001Yuichi HosodaData processing apparatus and image recording apparatus, method for controlling data processing apparatus and method for controlling image recording apparatus, and storage mediumUS20020030849Sep 10, 2001Mar 14, 2002Hiroyoshi TakamiyaImage processing apparatus and image processing methodUS20020099782 *Mar 27, 2002Jul 25, 2002Matsushita Graphic Communication Systems, Inc.Communication apparatus, data rewrite method and data download methodUS20020143924 *May 30, 2002Oct 3, 2002Fujitsu LimitedPrinter, control method, and computer readable recording medium which stores printer control programUS20020191210 *Jun 18, 2001Dec 19, 2002David StaasSystem and method for mobile printingUS20030095281 *Nov 20, 2001May 22, 2003Parry Travis J.Method and system for distributing e-mailUS20030233411 *Jun 12, 2002Dec 18, 2003Parry Travis J.E-mail addressing and document management* Cited by examinerReferenced byCiting PatentFiling datePublication dateApplicantTitleUS7760381 *Feb 22, 2005Jul 20, 2010Fuji Xerox Co., Ltd.Printer and method of controlling the sameUS7884956 *Feb 25, 2005Feb 8, 2011Brother Kogyo Kabushiki KaishaNetwork facsimile systemUS8027049 *Dec 4, 2002Sep 27, 2011Ricoh Company, Ltd.Remote e-mail printingUS8111414May 16, 2006Feb 7, 2012Canon Kabushiki KaishaImage processing apparatus, control method thereof, and programUS8427671 *May 16, 2006Apr 23, 2013Canon Kabushiki KaishaImage processing apparatus capable of timely notifying user of change in state, control method thereof, and image processing systemUS20120103003 *Jan 27, 2009May 3, 2012Mitsubishi Electric CorporationAir-conditioner and method of returning refrigerator oil* Cited by examinerClassifications U.S. Classification358/1.15, 358/402International ClassificationB41J5/30, G06K1/00, G06F13/00, B41J29/38, G06F3/12, H04L12/58, H04N1/00Cooperative ClassificationH04N2201/3276, H04N1/0035, H04N2201/0082, H04L51/066, H04N1/0097, H04N1/00244, H04N1/00482, H04N1/32122, H04N1/00209, H04L12/5835, H04N1/00472, H04N1/00416, H04N1/00466, H04N1/00474European ClassificationH04N1/00W3, H04N1/00D3J, H04L51/06B, H04N1/00C3K, H04N1/00D3F, H04N1/00D3D6, H04N1/00D3D8, H04N1/00D3D3B, H04L12/58C2, H04N1/00C3GLegal EventsDateCodeEventDescriptionJun 28, 2010FPAYFee paymentYear of fee payment: 4Nov 13, 2007CCCertificate of correctionJul 26, 2002ASAssignmentOwner name: CANON KABUSHIKI KAISHA, JAPANFree format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:TAKAMIYA, HIROYOSHI;REEL/FRAME:013154/0385Effective date: 20020722RotateOriginal ImageGoogle Home - Sitemap - USPTO Bulk Downloads - Privacy Policy - Terms of Service - About Google Patents - Send FeedbackData provided by IFI CLAIMS Patent Services©2012 Google

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