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FOOTBALL GRAPEVINE: Manchester United's £30m deal for Koke is back on | Daily Mail Online
United's £30m Koke deal back on and Moyes also wants Alonso, Saint Luke could be Spur of the moment and north London Cup derby stirs memories of Gazza
Jose Mourinho eyes big-money move for top strikers - including Falcao
Sam Allardyce safe at West Ham despite relegation form
Raheem Sterling in line make England World Cup squad
New manager Tim Sherwood on trial at Tottenham
West Ham keen on Everton striker Nikica Jelavic and defender John Heitinga
Published: 19:01 EDT, 28 December 2013 | Updated: 19:01 EDT, 28 December 2013
Manchester United’s hopes of signing Atletico Madrid midfielder Koke appear to be back on.
Reports in Spain on Saturday suggested United have tabled a £30million bid for the 21-year-old.
After missing out on several signings in the summer just after taking over, United boss David Moyes has the backing to bolster his squad next month and is determined to sprinkle it with stardust.
Man in the middle: Manchester United's bid for Atletico Madrid star Koke (right) is back on
As ever, there are long list of a variety of targets but Spain midfielder Koke has emerged as major target. Towards the end of last week some Spanish sources dismissed the idea United could land the player during the January transfer window.
But those suggestions were contradicted on Saturday.
It is also understood Moyes would love to take on Xabi Alonso, who it has been suggested is surplus to requirements at Real Madrid and could move during the window.
But given how long Alonso played for Liverpool, such a move for the 32-year-old for a bargain would be hard for United to pull off.
Admired: United boss David Moyes is also keen to sign Real Madrid midfielder Xabi Alonso (left)
Chelsea would also be interested in Alonso if he did move back to England in the coming window.
Moyes also wants a central defender and a left back.
Southampton are bracing themselves for offers for several of their young stars during the transfer window.
Left back Luke Shaw is wanted by many big Premier League clubs, including Tottenham, Manchester United and Chelsea.
Adam Lallana has said he is happy to stay put at the Saints this season but the same teams who are chasing Shaw like him, too.
Shaw thing: Tottenham are leading the race for Luke Shaw (right) but all the Premier League big boys are keen
On the wanted list: Adam Lallana (left) and Jay Rodriguez are also attracting attention from bigger clubs
Jay Rodriguez is also high on the wanted list of several clubs.
The Saints have had a superb first half to the season under the innovative leadership of Mauricio Pochettino but financial pressure could mean the club’s owners cashing in on one of their bright young players.
Experienced striker Rickie Lambert, who broke into the England set up this year but has suffered a drop in form, may also be available.
Shaw is regarded as a future England regular and may yet make the World Cup squad – and he could be the one to go during this window with Spurs favourites at the moment.
Jose Mourinho keeps playing down Chelsea’s chances of winning the Premier League.
But he has told owner Roman Abramovich that the acquisition of a new world-class striker could see the Blues come through and take the title AND challenge for the Champions League.
In recent weeks Chelsea have been linked with a string of star strikers such as Radamel Falcao, Diego Costa, Gonzalo Higuain and Karim Benzema.
Prime target: Radamel Falcao (centre) is wanted by Jose Mourinho to lead the line at Chelsea
Linked: Atletico's Diego Costa
Linked: Napoli's Gonzalo Higuain
Linked: Real's Karim Benzema
All the speculation is true. Mourinho wants any one of them and there is a list of others.
Just who signs for Chelsea is now down to the network of agents representing the club and the players.
Colombia star Falcao is the prime target despite having only joined Monaco in the summer and although he ruled out a move in the week, a change in tax rates in France and laws that may end the Principality’s football club’s exempt status could focus his mind.
FOOT ON THE BALL
Brendan Rodgers’ attack on referee Lee Mason’s integrity in the wake of defeat by Manchester City on the basis of where the official lived didn’t really make sense.
Yes Bolton is close to Manchester but it’s not that far from Liverpool either.
Besides, what was Rodgers trying to hint at? Even if Mason is Mancunian at heart he could just as likely to be a fan of United rather than City, so on that basis and given the league table he might have wanted to see Liverpool win or at least a draw.
Of course, it’s twaddle to suggest any of our top referees are biased to one club or another. Yes they make mistakes, as Mason and his officials did, but on the basis of error not prejudice.
And those who feel they could be compromised by geography or partisan leaning put their hands up. Geordie Mark Clattenburg does not take charge of games involving Newcastle or Sunderland. And for that matter Mason, who is a Bolton fan, doesn’t ever do their games.
But it would start to get ridiculous if the appointment of officials became more to do with postcode than ability.
Besides, Rodgers should have realised that a couple of seasons ago it was Mason who awarded Liverpool a late 'soft' penalty in a League Cup tie against City at the Etihad
Foot on the ball, Brendan.
West Ham manager Sam Allardyce is apparently a massive fan of football statistics.
Well here is one that might just put Allardyce’s regime at Upton Park into perspective after they dropped two more points at home in the 3-3 draw with West Brom.
In 2013 West Ham have played 38 games and secured 38 points.
That is, in any currency, relegation form.
Allardyce’s negative, one-dimensional tactics and team selection were again brought into question on Saturday in the wake of the West Brom draw.
The dilemma for West Ham’s increasingly worried owners is whether they are better to stick with a ‘devil’ they know rather than one they don’t.
On top of that, having given Allardyce a new contract last summer, Davids Sullivan and Gold will be thinking they would be far better spending substantial millions on players to bolster the squad in the transfer window than giving Big Sam a fat pay off cheque.
But Glenn Hoddle and Slaven Bilic remain options. Malky Mackay, wanted by West Brom and a former Hammers player, was on the name of some lips at the Boleyn Ground on Saturday night.
Insiders insist Allardyce will stay and lift the club out of the relegation zone.
The owners though are starting to get worried. No wonder when they look at the stats of 2013 achieved by the sixth highest paid manager in the PL.
Tottenham have given Tim Sherwood a deserved chance to prove himself as manager.
But the ‘permanent deal’ he is on only runs until the end of next season. It is effectively a trial deal.
If Sherwood impresses for the remainder of the campaign he will be in a position to improve and lengthen his contract significantly.
Trial deal: Tim Sherwood's 'permanent' contract at Tottenham only runs until next season
If not then Spurs will only have to pay a year’s severance of around £1.2million and look for a new boss next summer when current contract restraints prevented them from moving in.
Michael Laudrup, Jurgen Klinsmann, Frank de Boer and Maurico Pochettino would all be in the frame.
But the ball is in Sherwood’s court.
Nicolas Anelka could find himself in hot water after appearing to perform a controversial celebration during West Brom’s 3-3 draw at West Ham.
After the French striker scored the Baggies' first goal he wheeled away with his right arm extended and his left hand on his right shoulder - mimicking a controversial gesture known as the ‘quenelle.’
Controversial: Nicolas Anelka's celebration after his first goal on Saturday mimicked the 'quenelle', a gesture performed by his friend, the comediam Dieudonne (right)
Roger Cukierman, head of the CRIF umbrella group of Jewish organisations, described it as ‘the Nazi salute in reverse’ in a complaint made to French President Francois Hollande last week.
However, Dieudonné insists the quenelle is an anti-Zionist statement rather than an anti-Semitic one and has threatened to sue prominent Jewish critics for linking his gesture to the Nazis.
Mon: A massive storm hits the country but some calm at last for Tottenham as Daniel Levy sees sense and gives Tim Sherwood the manager’s job. He should have been given the chance ahead of AVB.
Tues: Roberto Martinez says Ross Barkley is not for sale even if a club bids £86million. Now while Barkley’s immediate future looks set to be at Goodison if a club comes anywhere near that, chairman Bill Kenwright will have other ideas, I suspect.
Weds: Steven Gerrard spotted back in training on Christmas Day. He’s obviously very keen to get back in the fray. Those who say Liverpool can be a title contender without him are talking piffle. They still need their talisman for the crunch games.
Thurs: Steve Lomas never stood a chance at Millwall, did he? The fans wanted him out before a ball was kicked this season because he played for West Ham for a while. They got their wish and now Neil Warnock might just be a good bet to lift the Lions away from the Championship relegation zone.
Fri: Don’t fret too much for Malky Mackay, even if his sacking by Cardiff owner Vincent Tan has been shabby to say the least. The Scot has just trousered a big pay off and looks set to walk into the vacant WBA job. In which profession, other than football management, is getting the sack a good and prosperous career move?
Raheem Sterling made his England debut way ahead of schedule last year, according to Liverpool boss Brendan Rodgers.
One of the reasons Roy Hodgson picked him so soon was to stop him declaring allegiance to Jamaica - where he was born - having seen Liverpool team-mate Victor Moses choosing Nigeria.
The attention and massive hike in wages seemed to have a negative impact on Sterling.
But over the last couple of months the 19-year-old has been in sparkling form.
And I understand Hodgson still has Sterling in line for a place in his World Cup squad.
And despite the pessimism about England’s attacking flair down the wings ahead of the World Cup, Hodgson is quietly excited that he will be picking from Sterling, Alex Oxlade-Chamberlain, Theo Walcott, Andros Townsend and possibly even Ashley Young - providing he moves from Manchester United and gets games.
Young, like another England wideman who has been capped by Hodgson, Wilfried Zaha, is a January target for Newcastle, as well as Aston Villa.
That West Ham could make a double swoop on Everton to land centre half John Heitinga as well as striker Nikica Jelavic.
The board of a Premier League club are concerned to hear allegations that their manager, with the help of a senior pro, is actively trying to persuade at least one young player to switch agents and be represented by the same middleman as the manager, having successfully done that before.
In what was an otherwise tedious goalless draw in tornado-like conditions between Arsenal and Chelsea, the standout moment was a horror tackle involving John Mikel Obi and Mikel Arteta.
Incredibly, although Arteta was lucky to escape a broken leg, referee Mike Dean waved play on and didn’t even show a yellow card, let alone red.
It prompted the best action of the evening, involving Sky pundits and MailOnline columnists Jamie Carragher and Gary Neville, who argued into the night about what action should have been taken.
Horror tackle: Both Mikel Arteta (right) and John Mikel Obi (right) went into this challenge studs up
Carragher thought it was a definite red for Mikel, Neville thought the referee was correct to do nothing.
But as the debate became more complex they were both right and both wrong because there was a strong argument to suggest that while it was a straight red red for Mikel it should have been a straight red for Arteta too, even though he was the one injured and seemed get a bigger touch on the ball.
As it happens Neville did allude to that at one stage, making the point that the mid-pitch collision was a result of two similar challenges being put in.
The point is that the barometer for a sending off is NOT a challenge that is ‘reckless’ – that is yellow card – but a challenge which ‘is of excessive force and one which endangers an opponent.’
Down: Arteta lies prone on the turf (right) but neither player was punished for the challenge
Everton are ready to make a move for Hull City’s Curtis Davies and West Bromwich Albion striker Shane Long.
In this instance BOTH players launched towards each other with feet off the ground and studs up.
The conditions had no bearing. This was not a case of sliding tackle that went out of control because of the surface. In BOTH cases the challenges were of excessive force and endangered an opponent. Making some contact with the ball is not an escape clause.
So they were BOTH lucky not to get injured. The boot could just as easily have been on the other foot, so to speak. And there is a strong case that BOTH should have seen off.
What the incident highlighted is a growing trend of lunging head- on ‘tackles’ which have evolved since the old-fashioned cynical tackle from behind being phased out of the game.
These lunging 'tackles', a bit like the one Ryan Shawcross inflicted on Aaron Ramsey three years ago with terrible consequences, can break legs and possibly careers.
Lunge: Aaron Ramsey's leg was broken by this 'tackle' from Stoke's Ryan Shawcross (right)
There is no value left in betting on Luis Suarez to finish Premier League top scorer given that he is 1-6.
But with 19 goals in 12 games Corals odds of Evens to beat the PL record of 34 in a season held by Alan Shearer and Andy Cole is surely worth a punt.
It’s a trend that needs to be arrested.
While there were plenty of instances of some brutal tackles ‘back in the day’ - not least in 1970 FA Cup final which featured players such as Ron ‘Chopper’ Harris or Norman ‘Bites yer Legs’ Hunter - many defenders of previous eras were coached to stay on their feet as much as possible when making a tackle, not go 'diving in'.
The theory was not necessarily about protecting opponents, although many players shunned shin pads, but about winning the ball and not being evaded by a twinkle-toed opponent.
It makes one wonder why, in this age of sports science and more coaches than National Express, fewer and fewer players in the Premier League, English and foreign, stay on their feet in the tackle.
In the Eighties Kenny Sansom was a fixture at left back for England and made the PFA team of the year in a record eight successive seasons. Few players got passed him.
During his days at Arsenal, Sansom was known as Kenny White Shorts because he won the ball by timely interceptions or by tackling while staying on his feet.
Rarely did Kenny hit the deck.
Kenny White Shorts: Sansom (right) rarely went to ground when making tackles but it did not hinder him in a career which brought 86 England caps
The same was true of Bobby Moore who did something amazing at the 1970 World Cup when he made the Brazilians gasp because of the effortless beauty he displayed when tackling Jairzinho.
Mikel, Arteta and many others could do themselves a favour by having look and learning.
Next Saturday’s FA Cup third round clash between Arsenal and Tottenham evokes memories of the 1991 semi final
The enormous interest meant it became the first semi-final to be staged at Wembley.
It was a thrilling game best remembered for Paul Gascoigne’s astonishing fifth-minute free kick to open the scoring, seemingly all the way from neighbouring Willesden.
A couple of weeks before I met up with him in the south of France where we had been watching Chris Waddle score the goal that saw Marseille beat AC Milan in the quarter-finals of the European Cup.
Jumping for joy: Paul Gascoigne (left) celebrates his superb free kick in the 1991 FA Cup semi-final against Arsenal
Mob rule: Gascoigne, Gary Mabbutt and Steve Sedgley (left) celebrate beating Arsenal at Wembley
But he was true to his word. While he was not fit enough to last the distance, Gascoigne produced a whirlwind display that blew Arsenal, who would win the title that season, away.
Apart for the astonishing opening goal he then paved the way for Gary Lineker’s second. Alan Smith pulled one back but Lineker then clinched a 3-1 for Spurs.
In the final Spurs beat Nottingham Forest but it was a stark contrast for Gascoigne, who went off after his foul on Gary Charles and would be out injured for months.
Ron Noades, who was one of a new wave of chairmen in the Eighties who saw football as big business along with Irving Scholar, David Dein, Ken Bates, Doug Ellis and Sam Hammam, died last week.
One of his former managers Alan Smith wrote a fine tribute in Sportsmail in the week recalling when Noades decided to pick the team himself … and chalked 12 names on the blackboard.
I recall one deal that emphasised Noades’ ruthless streak. I will keep the player anonymous to spare his blushes.
But said player, a regular in that excellent Crystal Palace side of the late Eighties and early Nineties, was due to sign a new contract.
New wave: Ron Noades, who died last week, was one of the chairman who saw football as big business (although he was manager of Brentford for a spell)
Noades was in the process of moving house, so he suggested the player take on the one he was selling as the signing on fee.
The player agreed.
It was a lovely detached pile in Surrey with a big back garden backing on to a country lane. It seemed a great deal both ways and was rubber stamped quickly so saving on agents fees, tax complications etc.
But a few weeks later the player awoke to the loud noise of builders. He opened his window and saw that half the back garden had been sectioned off and was being dug up.
He stormed down to ask what the builders were up to. They told him they were starting work on a couple of new houses and showed him the plans.
Ruthless streak: Noades (left) with another hard-headed businessman, Virgin founder Richard Branson
The player then drove off to confront Noades, who pointed out that the reason the player had got such a ‘bloody good deal’ ,was that part of the sale included the carve up of half the land at the back. It was all legal, Noades added, the player should have read the small print and besides he was lucky to be living in such a good neighbourhood considering where he had come from.
The player, who was no shrinking violet and knew a few Sarf London characters, had to take it on the chin.
Bid £10m... and you can have Ravel! Clause in Morrison's... Cardiff chairman Dalman hints at Solskjaer approach after... Warnock admits he'd step in at Milwall until the end of the... A tale of two strikers: As Suarez and Torres prepare to face...


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Business Trip One Nighter - Review of Fairfield Inn & Suites Edmond, Edmond, OK - TripAdvisor
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Business Trip One Nighter - Fairfield Inn & Suites Edmond
Business Trip One Nighter
Review of Fairfield Inn & Suites Edmond
I was traveling to Oklahoma City for business. There is a typical continental breakfast with waffle iron, eggs, bacon, veggie sausage, bagels, and toast.
The beds are very comfortable and the rooms are clean.
The bath towels were excellent!!
Ask Tom F about Fairfield Inn & Suites Edmond
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All reviews front desk room was clean oklahoma city great guy called marriott breakfast options sitting area other hotels local university great nights sleep comfortable hotel checking out veggie sausages next morning waffle iron waffles a nice place to stay
We have stayed in this facility every time we visited Edmond over the past few years, and never disappointed. But time has changed what used to be a consistent Marriott experience. Part of the problem was management; attitude of help, if you saw them, was evasive and unhelpful. Breakfast and coffee services were available later than in the past. Internet service was weak, and for Elite members the high speed option that used to be included was now a charge. Not a big deal, but annoying, especially since a lot of other hotels are now providing the best wi-fi internet speeds they can get as part of the room charge. Rooms were not as clean as in the past or even serviced during our four day stay. Noise was always an issue with this place, but the uncontrolled antics of children in the hallways seemed worse than usual and not addressed by the staff. Despite these observations, you can't beat the price for this place or a semblance of satisfaction if you only want a place to sleep at night.
Ask Soleil122 about Fairfield Inn & Suites Edmond
kayfreel63
I hate the fact that there is never anyone at the front desk but back in the office watching a monitor and you have to wait for them to come help you. We had two rooms rented and had an unexpected event and had to check out of one room a night early but was still charged for that room. There was no whirlpool as was advertised and the pool was in desperate need of a good cleaning. The entrance to the hotel is not clearly marked and really hard to find the hotel after dark. Definitely not a Marriott
Room Tip: Next time I am in the area I will try the La Quinta next door, easier to see from the road and get in and out of.
Ask kayfreel63 about Fairfield Inn & Suites Edmond
Thank kayfreel63
Not a typical Marriott experience
We did not have a 'Marriott Experience' at this hotel. The problem was clearly housekeeping. Bathroom not cleaned properly - hair on floor, in tub, soap scum in dish, trash from previous guests under bed and in drawers. Very sticky floors...especially in the breakfast area. Our shoes literally made noise as they stuck to the floor. Moldy fruit for breakfast and coffee NOT hot...had been sitting awhile. We would not recommend this hotel and will not be staying again.
Room Tip: No suggestions. They need a new cleaning crew!
Ask kma68 about Fairfield Inn & Suites Edmond
Thank kma68
On my way home from vacation, I stopped in Edmond for the night. I was road weary and needed peace. The courteous front desk had me to my room in minutes. The rooms have recently been refurbished and are quite lovely. The double queen room contained a refrigerator and microwave. Sadly the whirlpool had been cemented shut and the pool was not having its best day. I opted for a bath in the room and a great nights sleep. Breakfast offered great looking and tasty fruit along with hot items and cereal. I have already recommended the place to my sister who will be making a trip later this year.
Ask E_Leigh_12 about Fairfield Inn & Suites Edmond
Comfortable hotel, helpful staff, but a few amenities and logistics challenges...
I was in for a big conference at the local university and this was basically the closest place, though it was still three miles away (stuff is spread out in OK). The decor is pleasantly modern and the staff are quite helpful - they recommended a very nice pizza place that delivered, as there are basically no restaurants for miles around. The room was comfortable, if not well located (right over the entrance?) and the place was quiet, despite being crawling with college students for the week (it was a student research conference). Internet service was easy and high-speed. My issues with the hotel relate to its workout facilities (a couple treadmills, and "weights" that only went to 25lb and were shoved in a corner, along with the bench), and to their complimentary breakfast, where they seemed to have trouble keeping fresh food and drink out (a suggestion here would be a second waffle iron, as that was clearly popular and would take the pressure off of the rest of the service a bit). As the workout facilities matter to me it's not likely I'd choose the place again, but if that's not an issue for you it's comfortable for a short stay.
Room Tip: Away from the entrance for sure!
Ask Jeffrey R about Fairfield Inn & Suites Edmond

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9781630438913: Ohio Rules of Court Annotated 2014-2015 - 5 VOLUME SET - STATE, LOCAL, FEDERAL - AbeBooks: 163043891X
Ohio Rules of Court Annotated 2014-2015 - 5 VOLUME SET - STATE, LOCAL, FEDERAL
ISBN 13: 9781630438913
ISBN 10: 163043891X ISBN 13: 9781630438913
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Book Description 2014. Paperback. Condition: Used: Like New. Like new!! Still packaged in original shrink wrap and has not been opened!! FAST SHIPPING W/USPS TRACKING!!!. Seller Inventory # 280007323
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Book Description 2014. Paperback. Condition: Fine. Shrink wrapped and unopened. Includes supplemental or companion materials if applicable. Connecting readers since 1972. Customer service is our top priority. Seller Inventory # mon0001158601

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Caribbean Dominican Republic Things to Do
Article History (13) Comments (5) First time visitors to the Dominican Republic must be warned - there is a very big chance of falling in love with this country, a love affair that may last your lifetime!
Santo Domingo is the capital and the first city of the "New World". It offers some great historical sites and dining/nightlife. To the East of Santo Domingo are the famous beaches of Punta Cana perfect for a holiday of white sand, palm tree lined beaches.


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ASIN: B071NMNHK9
#13079 in Digital Music > Albums > Rock
5.0 out of 5 starsInnovative and original album
The Rasmus experiences new sounds but their essence is intact in every lyric and melody. The more I listen to this album, the more I like it.
4.0 out of 5 starsA great outing for the Rasmus
Very good outing from The Rasmus. As a fan of their previous music, this basically the exact type of record I would expect. Great melodies, thoughtful lyrics, etc. Even though this is titled "Dark Matters", there is more than just a touch of an uplifting message present. Great listen!
Try Wonderman, Silver Night, and Paradise.
5.0 out of 5 starsDifferent Sound...Still awesome!
For those who have been Rasmus fans since forever (like me) u know how they change their sound every once in a while, this album is completely different when u compare it to Dead Letters and Hide from the Sun, even Black Roses was kind of different! but Anyway, it's an amazing album with beautiful songs!
5.0 out of 5 starsI love The Rasmus and they're my favorite band so of ...
I love The Rasmus and they're my favorite band so of course I will give it 5 stars. Some really good music from them.
5.0 out of 5 starsGlad they’re back!!
Their first album in way too long - and it delivers! Solid material through and through.

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Patent US7494566 - Composition for increasing cellulosic product strength and method of ... - Google PatentsSearch Images Maps Play YouTube News Gmail Drive More »Sign inAdvanced Patent SearchPatentsA composition includes water; at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function as described above. The hydrophilic polymer and the...http://www.google.com/patents/US7494566?utm_source=gb-gplus-sharePatent US7494566 - Composition for increasing cellulosic product strength and method of increasing cellulosic product strengthAdvanced Patent SearchPublication numberUS7494566 B2Publication typeGrantApplication numberUS 10/799,793Publication dateFeb 24, 2009Filing dateMar 12, 2004Priority dateSep 13, 2002Fee statusPaidAlso published asCA2558824A1, EP1730351A2, EP1730351A4, US20050082025, WO2005089175A2, WO2005089175A3Publication number10799793, 799793, US 7494566 B2, US 7494566B2, US-B2-7494566, US7494566 B2, US7494566B2InventorsWilliam Eamon Carroll, Christian Jehn Rendu, Eric J. BeckmanOriginal AssigneeUniversity Of Pittsburgh - Of The Commonwealth System Of Higher EducationExport CitationBiBTeX, EndNote, RefManPatent Citations (45), Non-Patent Citations (7), Referenced by (2), Classifications (35), Legal Events (4) External Links: USPTO, USPTO Assignment, EspacenetComposition for increasing cellulosic product strength and method of increasing cellulosic product strengthUS 7494566 B2Abstract A composition includes water; at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function as described above. The hydrophilic polymer and the saccharide are mixed to form a reaction mixture and reacted to increase the viscosity of the reaction mixture. The reaction is then substantially terminated by reducing the pH of the composition. A method of increasing the strength of a cellulosic pulp product includes the steps of: contacting wet cellulosic pulp with a composition comprising (i) at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function, the hydrophilic polymer and the saccharide of the composition having been reacted in a crosslinking reaction prior to contacting the composition with the cellulosic pulp product to increase the viscosity the composition; and, after contacting the cellulosic pulp with the composition, causing the crosslinking reaction between the hydrophilic polymer and the saccharide of the composition to proceed further.
3. The method of claim 1 wherein the predetermined viscosity of the composition is at least 20 cp at 80� C. when the reaction is substantially terminated.
4. The method of claim 1 wherein the predetermined viscosity of the composition is in the range of approximately 20 cp to 100 cp at 80� C. when the reaction is substantially terminated.
5. The method of claim 1 wherein the predetermined viscosity of the composition is in the range of approximately 20 cp to 60 cp at 80� C. when the reaction is substantially terminated.
6. The method of claim 1 wherein the predetermined viscosity of the composition is in the range of approximately 20 cp to 40 cp at 80� C. when the reaction is substantially terminated.
7. The method of claim 1, wherein the predetermined viscosity of the reduced pH composition is no greater than 80 cp at 23� C.
18. The method of claim 1 wherein the cellulosic pulp and the composition are heated to a temperature of at least 50� C.
19. The method of claim 1 wherein the cellulosic pulp and the composition are heated to a temperature of at least 70� C.
20. The method of claim 1 wherein the cellulosic pulp and the composition are heated to a temperature of at least 80� C.
22. The method of claim 13 wherein the polymer is an NVF/vinylamine copolymer with diallyldimehylammnonium chloride or with a cationic acrylate comonomer. Description
CROSS-REFERENCE TO RELATED APPLICATION This application is a continuation in part application of U.S. patent application Ser. No. 10/252,262, filed Sep. 23, 2002 now U.S. Pat. No. 7,090,745, which claims the benefit of U.S. Provisional Patent Application Ser. No. 60/410,375, filed Sep. 13, 2002, the disclosures of which are incorporated herein by reference.
BACKGROUND OF THE INVENTION The present invention relates generally to crosslinking compositions suitable, for example, to increase the strength (that is, wet and/or dry strength) of cellulosic products (including, for example, paper and other products made from cellulosic pulp) and to methods of increasing the strength of cellulosic products using such compositions.
For example, some wet-strength additives are condensation products of urea and formaldehyde. Polyamine can be added to make such resins cationic. Other wet-strength additives include organochlorine crosslinked amidoamine compounds. A discussion of wet-strength additives and their mechanisms is presented in �The 65 Mechanism of Wet-Strength Development in Paper: A Review,� by Herbert H. ESPY, Tappi Journal, Vol. 78, No. 4, pages 90-97 (April 1995 as well as in �Chemistry of Paper Wet-Strength. I. A Survey of Mechanisms of WetStrength Development,� by Lars WESTFELT, Cellulose Chemistry and Technology, Vol. 13, pages 813-825 (1979), the contents of which are incorporated by reference as though set forth in full herein.
Such an amine functional polymer/reducible saccharide combination has been found to undergo an unexpected cross-linking reaction upon the application of heat. The compositions of the present invention can, for example, be used as cross-linking agents in paper strengthening applications. As used herein, the term �polymer� refers to a compound having multiple repeat units (or monomer units) and includes the term �oligomer,� which is a polymer that has only a few repeat units. The term polymer also includes copolymers which is a polymer including two or more dissimilar repeat units (including terpolymers�comprising three dissimilar repeat units�etc.). The polymers used in the compositions of the present invention can be homopolymers and/or copolymers.
In another aspect, the present invention provides a composition including water; at least one hydrophilic polymer containing at least two groups which are independently the same or different a primary amine group or a secondary amine group and at least one saccharide containing a reducible function as described above. In this aspect of the present invention, the hydrophilic polymer and the saccharide are mixed to form a reaction mixture and reacted (that is, crosslinked) until or so that the viscosity of the composition increases. The crosslinking reaction is then substantially terminated (prior to completion) by reducing the pH of the composition (for example, by adding an acid such a aqueous hydrochloric acid). The viscosity of the composition can, for example, be at least 20 cp at 80� C. when the crosslinking reaction is terminated. In one embodiment, the viscosity of the composition is in the range of approximately 20 cp to 100 cp at 80� C. when the reaction is terminated. The viscosity of the composition can further, be in the range of approximately 20 cp to 60 cp at 80� C. when the reaction is terminated. The viscosity of the composition can also be in the range of approximately 20 cp to 40 cp at 80� C. when the reaction is terminate. Preferably, the viscosity of the reduced pH composition is no greater than 80 cp at room temperature (that is, approximately 22� C.).
In another aspect, the present invention provides a method of increasing the strength of a cellulosic product including the step of contacting a wet cellulosic pulp with a composition as described above. In one embodiment, wet cellulosic pulp (for example, wet paper pulp) and the composition are contacted at a temperature below approximately 50� C., or more typically, at room temperature or below (that is, at approximately 25� C. or below) and subsequently heated to induce cross-linking. For example, the cellulosic pulp and the composition can be heated to a temperature of at least 50�, at least 70� or at least 90�.
DETAILED DESCRIPTION OF THE INVENTION As discussed above, during paper processing, material is added to the wet pulp to improve the strength during the formation of sheets prior to ultimate drying. Preferably, the additive material or composition exhibits a relatively low viscosity during addition (to fully absorb into the pulp), then cures as temperature increases. Because paper comes into intimate contact with people, the strength-enhancing material is preferably relatively environmentally benign.
Example 25 The polymer used in this example and the following examples was a copolymer of vinyl alcohol and vinylamine (PVOH/VAm), containing 12 mole % vinylamine repeat units, with a medium molecular weight. Although any reducing sugar may be used, D-glucose was used in this and the following examples. Twelve (12) grams of PVOH/VAm were dissolved in 200 grams of water. The solution was heated to 90� C. and then filtered to remove any insoluble material. With the solution temperature maintained at 80� C., six grams of D-glucose was added, followed by sufficient 30% sodium hydroxide solution to bring the solution pH to at least 10, preferably approximately 12. With continued heating in the 80-90� C. range the solution converts to a thick viscous gel. The relationship between time to gelation and temperature is illustrated in Table 4 for the crosslinking of PVOH/VAm with D-glucose at a 1:1 mole ratio and a pH of 12.5.
Time to gelation
Example 26 As in Example 25, twelve grams of PVOH/VAm were dissolved in 200 grams of water, heated to 90� C. and filtered to remove insoluble material. Maintaining the solution temperature at 80� C., six grams of D-glucose were added, followed by sufficient 30% aqueous sodium hydroxide to bring the solution pH to at least 10. The initial viscosity was 17 cps. After approximately twenty minutes at 80� C., the viscosity had risen to 40 cps. Once the viscosity reached 40 cps, the solution pH was adjusted to 6 by addition of 33% hydrochloric acid solution. The viscosity was measured as 22 cps at 80� C. and 80 cps at 23� C. The solution does not gel and can be stored at room temperature for several weeks without any evidence of gel formation.
Example 27 A dynamic handsheet maker (Techpap) was employed to make paper samples for testing. Sixteen (16) grams of dry cellulosic fiber were used to make a slurry in water at 1% consistency. The pH of the slurry was adjusted to the desired level and the acid-stabilized PVOH/VAm/D-glucose from Example 26 added at a level of 0.5 weight % (equivalent to 10 lb/ton) based on the amount of dry fiber in the slurry. The rotation speed of the handsheet maker was set at 680 rpm and pressure applied to form the paper sheet. The wet paper web was pressed and dried at 115� C. for eight minutes. The paper sheets were conditioned at 23� C. and 50% relative humidity for one day. The treated paper sheets were then tested for wet tensile, dry tensile and burst strength using standard tests. The results were normalized to allow for differences in thickness and grammage for each sheet.
Example 28 Paper sheets were made up as in Example 27, both with and without the polymer additive. The PVOH/VAm/D-glucose solution was heated for 30 minutes at 80� C. before adding to the fiber suspension. The final viscosity (at room temperature) was 80 cps. The results are summarized in Table 5.
TABLE 5 Additive None PVOH/VAm/D-glucose pH 5.5 5.5 DBL (km) 3.646 4.173 WBL (km) 0.054 0.332 WBL/DBL (%) 1.5 8.00 In Table 5, �DBL� refers to Dry breaking length, while �WBL� refers to Wet breaking length
Example 29 Paper sheets were made as in Example 27, using the PVOH/VAm both with and without added D-glucose. The copolymer/glucose solution was heated at 80� C. for 30 minutes before use and the final viscosity at room temperature was 68 cps. The results are summarized Table 6.
PVOH/VAm
PVOH/VAm/D-glucose
DBL (km)
WBL (km)
WBL/DBL (%)
Example 30 Paper sheets were made as in Example 27, both with and without polymer additive. The PVOH/VAm/D-glucose was heated at 80� C. until a final viscosity of 225 cps (as measured at room temperature) was reached. The results are summarized in Table 7.
Example 31 Paper sheets were made as in Example 27, both with and without polymer additive. The PVOH/VAm/D-glucose samples were heated for different times at 60� C. prior to use. The results are summarized in Table 8.
VAm/D-
Example 32 A paper-making trial was conducted on a pilot-scale paper machine. The machine used was a Fourdrinier (width 25 inches), with a nominal paper output of 160 lbs paper per hour. The pulps used were old corrugated containers (OCC) and a mix of OCC with recycled newsprint. Polymer was added in the range of 2-10 lbs/ton on a dry basis. Sample sheets were cut from the paper reel and conditioned in the same fashion as the hand-sheets in Example 27. Results were normalized for thickness and weight. The PVOH/VAm solution was prepared as in Example 26, filtered and stored in a drum. D-glucose was added to this stock solution, pH adjusted to 12 and the solution was then heated to 80� C., while monitoring viscosity. Measured viscosities were below 100 cps during use of the solution.
Example 33 Paper was made on the pilot machine using old corrugated containers (OCC) as the fiber source. The paper produced was 26-28 lbs per 1,000 square feet, with a caliper of approximately 9.0. A base sheet was produced with no additive. Then PVOH/VAm/D-glucose (P) was fed to the paper stock at a rate to give a 2 to 10 lb per ton (0.1-0.5%) application level on a dry basis. Results are summarized in Table 9. Properties reported were measured in the machine direction.
P (0.5%)
Example 34 Paper was made as in Example 33, but using a mixture of OCC and old newsprint as fiber source. A base sheet was produced with no additive. Then PVOH/PVAm/D-glucose (P) was added at levels sufficient to give 6 and 8 lb/ton (0.3 and 0.4%) application levels. Properties reported were measured in the machine direction and are summarized in Table 10.
P (0.3%)
P (0.4%)
Example 35 The procedure of Example 34 was repeated, using PVOH/VAm/D-glucose (P) solution that had been aged for several hours to an increased viscosity. The polymer was added at levels sufficient to give 6 and 8 lb/ton (0.3 and 0.4%) application levels. Properties reported were measured in the machine direction and are summarized in Table 11.
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A.Plastic preform for forming blow molded plastic bodiesUS5262008Mar 14, 1990Nov 16, 1993Basf AktiengesellschaftProduction of paper, board and cardboard in the presence of copolymers containing N-vinylformamide unitsUS5281307Jan 13, 1993Jan 25, 1994Air Products And Chemicals, Inc.Crosslinked vinyl alcohol/vinylamine copolymers for dry end paper additionUS5380403Mar 22, 1993Jan 10, 1995Air Products And Chemicals, Inc.Amine functional poly(vinyl alcohol) for improving properties of recycled paperUS5397436Mar 7, 1994Mar 14, 1995Air Products And Chemicals, Inc.Paper wet-strength improvement with cellulose reactive size and amine functional poly(vinyl alcohol)US5735349Aug 16, 1996Apr 7, 1998Bj Services CompanyCompositions and methods for modifying the permeability of subterranean formationsUS5789351Aug 19, 1996Aug 4, 1998Phillips Petroleum CompanyCompositions useful for treating oil-bearing formationUS5846788Jul 26, 1995Dec 8, 1998Novo Nordisk A/SProcess for preparing a lignocellulose-based product, and product obtainable by the processUS5851300Oct 17, 1995Dec 22, 1998Basf AktiengesellschaftCationic modification of starch and use of the cationically modified starchUS6124245Oct 7, 1998Sep 26, 2000Phillips Petroleum CompanyDrilling fluid additive and process therewithUS6127319Oct 29, 1999Oct 3, 2000Actisystems, Inc.Oil-in-water emulsionUS6146497Jan 16, 1998Nov 14, 2000Hercules IncorporatedAdhesives and resins, and processes for their productionUS6165322Jul 29, 1997Dec 26, 2000Hercules IncorporatedPolyamidoamine/epichlorohydrin resins bearing polyol sidechains as dry strength agentsUS6179962Dec 31, 1997Jan 30, 2001Hercules IncorporatedPaper having improved strength characteristics and process for making sameUS6465397Feb 11, 2000Oct 15, 2002Clariant Finance (Bvi) LimitedSynthetic crosslinked copolymer solutions and direct injection to subterranean oil and gas formationsUS6616807Mar 26, 1998Sep 9, 2003Basf AktiengesellschaftMethod for producing high dry-strength paper, pulpboard and cardboardUS6710175 *Aug 31, 2001Mar 23, 2004Kevin Ray AndersonCompositions suitable as additives in the paper industry, preparation; use; and, paper comprising suchUS6803348Mar 22, 1999Oct 12, 2004Schlumberger Technology CorporationHydrophobically modified polymers for water controlUS6981552Mar 21, 2003Jan 3, 2006Halliburton Energy Services, Inc.Well treatment fluid and methods with oxidized polysaccharide-based polymersUS7004253May 13, 2002Feb 28, 2006Eni S.P.A.Process for reducing the production of water in oil wellsUS20030192664Jun 19, 2003Oct 16, 2003Kulick Russell J.Use of vinylamine polymers with ionic, organic, cross-linked polymeric microbeads in paper-makingEP0331047A1Feb 24, 1989Sep 6, 1989Air Products And Chemicals, Inc.Papermaking process comprising the addition of high molecular weight poly(vinylamines) to the wet-end cellulose fiber slurryGB1259533A Title not availableWO1998045536A1Mar 26, 1998Oct 15, 1998Basf AgMethod for producing high dry-strength paper, pulpboard and cardboardWO2001029313A1Sep 7, 2000Apr 26, 2001Weyerhaeuser CoCationically modified polysaccharidesWO2004025027A1Sep 12, 2003Mar 25, 2004Univ PittsburghComposition and method for increasing the strength of a cellulosic productWO2005089175A2Mar 11, 2005Sep 29, 2005Univ PittsburghComposition and method for increasing cellulosic product strength* Cited by examinerNon-Patent CitationsReference1Kofflin, S. A., "Formation of Hydrogels Using Poly(vinylalcohol)/Poly(vinalyamine) Copolymer and D-Glucose," Slides from oral presentation at Saint Mary's Senior Comprehensive, Apr. 11, 2002.2Kofflin, S.A, et al., "Formation of Hydrogels Using Poly(vinylalcohol)/Poly(vinylamine) Copolymers and D-Glucose," Slides from poster presentation at REU Summer Research Symposium, Aug. 7, 2001.3Kofflin, S.A., "Formation of Hydrogels Using Poly(vinylalcohol)/Poly(vinylamine) Copolymers and D-Glucose," Slides from oral presentation at Saint Mary's College Student Paper Day Presentation, Apr. 23, 2002.4Kofflin, S.A., et al., "Formation of Hydrogels Using Poly(vinylalcohol)/Poly(vinylamine) Copolymers and D-Glucose," Slides from oral presentation at REU Summer Research Symposium, Aug. 7, 2001.5Nestor, S., "Summer Internship Leads to Patent for St. Mary's Senior," Observer Online, Sep. 11, 2001.6Yamaura, Kazuo et al., Efect of Addition of Saccharides on Gelation of Aqueous Poly (Vinyl Alcohol) Solutions, Journal of Applied Polymer Science. 1999, 74, 1298-1303.7Yamaura, Kazuo. et al., Gelation of Poly (vinyl Alcohol) Solutions at Low Temperatures (20 to -78 degrees Celsius) and Properties of Gels. Journal of Applied Polymer Science. 1994, 51, 2041-2046.Referenced byCiting PatentFiling datePublication dateApplicantTitleUS7628888 *Jun 12, 2006Dec 8, 2009University of Pittsburgh�of the Commonwealth System of Higher EducationCellulosic compositionUS20110263757 *Apr 21, 2011Oct 27, 2011Rand Charles JDurable thermoset binder compositions from 5-carbon reducing sugars and use as wood binders* Cited by examinerClassifications U.S. Classification162/164.1, 162/164.3, 162/158, 162/164.6, 162/178, 162/175, 162/166International ClassificationC08L39/00, C09D139/02, C08L39/02, D21H21/18, D21H17/36, D21H17/24, C09D133/14, D21H17/06, D21H21/20, D21H17/56, D21H17/54Cooperative ClassificationD21H21/18, C08L39/04, C09D139/02, D21H17/06, C09D133/14, C08L2312/00, D21H21/20, C09D133/02, C08L39/00, D21H17/36, D21H17/56, C08L39/02European ClassificationC08L39/04, C09D133/02, D21H21/18, C09D139/02, C09D133/14Legal EventsDateCodeEventDescriptionFeb 1, 2013FPAYFee paymentYear of fee payment: 4Feb 1, 2013SULPSurcharge for late paymentOct 8, 2012REMIMaintenance fee reminder mailedJun 28, 2005ASAssignmentOwner name: PITTSBURGH, UNIVERSITY OF, PENNSYLVANIAFree format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:CARROL, WILLIAM EAMON;REEL/FRAME:016426/0397Effective date: 20050307Owner name: SNF SA, FRANCEFree format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:RENDU, CHRISTIAN JEHN;REEL/FRAME:016426/0457Effective date: 20040312Owner name: UNIVERSITY OF PITTSBURGH, PENNSYLVANIAFree format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:BECKMAN, ERIC J.;REEL/FRAME:016428/0235Effective date: 20041213Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SNF SA;REEL/FRAME:016426/0426Effective date: 20050218RotateOriginal ImageGoogle Home - Sitemap - USPTO Bulk Downloads - Privacy Policy - Terms of Service - About Google Patents - Send FeedbackData provided by IFI CLAIMS Patent Services©2012 Google

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BBC - Music - Review of Elizabeth Cook - Welder {{pulseintro}} {{pulsequestion}} {{pulseaccept}} {{pulsereject}} ]]> We use cookies to ensure that we give you the best experience on our website. We also use cookies to ensure we show you advertising that is relevant to you. If you continue without changing your settings, we'll assume that you are happy to receive all cookies on the BBC website. However, if you would like to, you can change your cookie settings at any time. Continue Change settings Find out more ]]> Accessibility links Accessibility Help BBC iD BBC navigation News News Sport Weather Shop iPlayer Capital Travel Culture Autos Future TV Radio CBBC CBeebies Arts WW1 Food History Learning Music Science Nature Local Travel Full A-Z Menu Search the BBC ]]> Music Home Clips Elizabeth Cook Welder Review Album. Released 2010. Share this page Like this? Try these... See You on the Moon Tift Merritt Mountain Soul II Patty Loveless Mockingbird Allison Moorer Artist Played By Bob Harris Country BBC Radio 2 Mac'illeMhìcheil BBC Radio Nan Gaidheal Iain Anderson BBC Radio Scotland Links Reviews available at www.bbc.co.uk Discogs page for Welder Tracklistings come from MusicBrainz. You can add or edit information about Welder at musicbrainz.org . Find out more about our use of this data, and also our policy on profanity Find out more about our use of this data. BBC Review Cook is an increasingly intriguing and surprising artist. Andrew Mueller 2010 The fifth album by Florida-born Nashville denizen Cook is apparently named after the profession pursued by her father – but she has done a pretty good job herself, here, of rendering disparate elements into something tough and just slightly sparkly. Cook’s old-school country credentials are, after more than 300 Grand Ole Opry appearances, beyond argument; but the cast she has assembled around her is drawn from all points on the modern country spectrum, and beyond.
Don Was produces, Nashville alt-country mainstay (and Cook’s husband) Tim Carroll plays guitar, backing vocals are provided by Buddy Miller, Rodney Crowell and Dwight Yoakam, and one member of her band possesses possibly the most incongruous CV ever boasted by a musician on a country record – Bones Hillman, previously better known as the bass player in Midnight Oil.
It’s not surprising – and not at all bad – that the album created by the aforelisted collaborators is so riotously diverse. Cook pours herself into first-person confessionals skilfully reined in just short of oversharing mawkishness (Heroin Addict Sister, Mama’s Funeral). She brings a commendably light touch to bear on the wry ballads and upbeat swingers which suggest the influence of former producer Crowell (I’m Beginning to Forget, I’ll Never Know). She gently summons the ghost of Tammy Wynette on the domestic melodrama Girlfriend Tonight. And she’s a latter-day Loretta Lynn on straightforwardly lubricious bar-room rattlers (Yes to Booty, Snake in the Bed).
Not all of the many feats attempted by Cook come off. The blustering boogie of Rock N Roll Man was doubtless great fun to play in the studio, but probably should have stayed there, and the half-rapped El Camino is closer to Shania Twain than is entirely comfortable. However, these are forgivable weaknesses in a generally robust collection by an increasingly intriguing and surprising artist. This work is licensed under a Creative Commons Licence. If you choose to use this review on your site please link back to this page. Tracks In order to listen to track previews you need to have both Javascript enabled and Flash installed. Visit BBC Webwise for full instructions. 1 All The Time 2 El Camino 3 Not California 4 Heroin Addict Sister 5 Yes To Booty 6 Blackland Farmer 7 Girlfriend Tonight 8 Rock N Roll Man 9 Mama's Funeral 10 I'm Beginning To Forget 11 Snake In The Bed 12 Follow You Like Smoke 13 I'll Never Know 14 Til Then Clips taken from original discs may contain strong language. Tracklistings come from MusicBrainz. You can add or edit information about Welder at musicbrainz.org . Find out more about our use of this data, and also our policy on profanity Release Details Label Proper Records Date May 10 2010 Country United Kingdom Format CD Catalogue # PRPCD059 Explore the BBC News News Sport Weather Shop iPlayer Capital Travel Culture Autos Future TV Radio CBBC CBeebies Arts WW1 Food History Learning Music Science Nature Local Travel Full A-Z Terms of Use About the BBC Privacy Policy Cookies Accessibility Help Parental Guidance Contact the BBC BBC © 2014 The BBC is not responsible for the content of external sites. Read about our approach to external linking.

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Simpson Tree Service in Gainesville, FL with Reviews - YP.com
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Jewel Zone US - White Natural Diamond Flower Bridal Ring Set In Solid Gold (0.5 Cttw) - Walmart.com
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Electrode, Comp-701341259, DC-prod-dfw5, ENV-prod-a, PROF-PROD, VER-19.1.31, SHA-771c9ce79737366b1d5f53d21cad4086bf722e21, CID-42f9baf9-e63-16fba81985ec5d, Generated: Sat, 18 Jan 2020 21:14:12 GMT
White Natural Diamond Flower Bridal Ring Set In Solid Gold (0.5 Cttw)
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Jewelry has the power to be this one little thing that can make you feel Unique, Youre going to love this Fabulous White Natural Diamond Flower Bridal Ring Set In Solid Gold (0.5 Cttw) Simply beautiful! Makes a great gift for any Christmas, party, wedding, graduations, Mother's Day,Anniversary, Engagement, Wedding, Birthday, Holiday, Promise, Valentine's or Special Occasion! Beautiful engagement wedding ring features a gorgeous bands are the symbol of a love & bond everlasting & prosperous. you owe it to you & your lover to give them something to strengthen that bond.Please Provide us your ring size, We customize ring as per you size.Women's Sizes Available: 4, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, 8, 8.5, 9, 9.5 & Men's Sizes Available : 7, 7.5, 8, 8.5,9, 9.5, 10, 10.5, 11, 11.5, 12, 12.5, 13, 13.5, 14. (Note: Due to the difference between different monitors, the picture may not reflect the actual color of the item. We guarantee the style is the same as)
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text:
Words containing anchet | Words that contain anchet
Words containing anchet | Words that contain anchet http://www.thefreedictionary.com/words-containing-anchetPrinter Friendly
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text:
AS Biology by Steve Potter (Paperback, 2004) | eBay
AS Biology by Steve Potter (Paperback, 2004)
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item 1 Potter, Steve, Instant Revision - AS Biology, Very Good Book -Potter, Steve, Instant Revision - AS Biology, Very Good Book
item 2 Potter, Steve, Instant Revision - AS Biology, Very Good Book -Potter, Steve, Instant Revision - AS Biology, Very Good Book
item 3 Instant revision: AS biology: the ideal solution to last-minute revision by -Instant revision: AS biology: the ideal solution to last-minute revision by
item 4 (Very Good)0007172664 Instant Revision - AS Biology,Steve Potter,Paperback -(Very Good)0007172664 Instant Revision - AS Biology,Steve Potter,Paperback
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Instant revision notes for AS-level biology, with self-check questions and grade-boosting tutorials, in a handy A5-sized book. The notes are written by a senior examiner and experienced teacher, who know what students need for that final check.
Steve Potter is a Head of Biology and an AS examiner for a major examining board.
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text:
Home Radiation Safety Manual
BrowseUploadSign inJoinBooksAudiobooksComicsSheet MusicWelcome to Scribd! Start your free trial and access books, documents and more.Find out moreFREE ONLINE PRESS RELEASE DISTRIBUTIONHome
Apr 17, 20 11
Ho me Radiatio n Safety Manual Nuclear radiatio n is currently leaking (still is) fro m the Fukushima reacto r in Japan. There are deadly co nsequences to high radiatio n levels, including cancers, DNA damage, infertility, ho rmo nal damage, lo sing all yo ur hair, develo ping po iso no us bo ils o n yo ur skin, and thyro id blo ckage. We are to ld by the “autho rities” to take po tassium io dide (o r io dine) and all will be well. Po tassium io dide (PI) is no t a go o d so lutio n, it will actually clo g up the thyro id gland and sto p radiatio n fro m spreading thro ugho ut o ur bo dies is what we are to ld. The type o f radiatio n (cesium 137) that is co ntaminating o ur fo o d and water supplies is much to o po werful fo r PI. There are five safety tips yo u want to adhere to eliminate yo ur chances o f getting Radiatio n Sickness.
The To p 5 Radiatio n Safety Tips Mo nito r Radiatio n Levels The first thing yo u need to kno w is if the area yo u are in is affected by radiatio n. Yo u can stay abreast o f these radiatio n levels by using the internet to get repo rts o ther than the “co rpo rate” viewpo int o n mainstream media news. The best metho d fo r yo ur ho me o r o ffice is to get an actual do simeter o r Geiger detecto r. There are po rtable mo dels fo r ho me use that will sho w yo u if yo ur area is being hit by radiatio n expo sure. It can even alert yo u if the fo o d o r water yo u’re abo ut to co nsume has radiatio n in it. It’s is best no t to rely o n “autho rities” to tell yo u “It’s safe fo r yo u.” The Japanese go vernment did a televisio n sho w sho wing them eating and pro mo ting the safety o f their co ntaminated vegetables (gro wn in Fukushima, no less.) Avo id pro ducts fro m this area like the plague and test it fo r yo urself. Learn to measure it fo r yo urself and get a po rtable ho me Radiatio n Detecto r . Drinks and Fo o ds fo r Radiatio n Pro tectio n Making sure that the water and beverages yo u drink are safe to co nsume sho uld be a to p prio rity. This o nline manual sho ws yo u where to get fo o ds that are safe, and beverages and water that is safe to drink. It will sho w yo u which fo o ds will pro tect yo u fro m radiatio n sickness and po iso ning. Yo u really need to kno w this info rmatio n befo re yo u indulge. Yo u’ll disco ver where to get emergency fo o ds to sto re o n hand in case o f sto re co ntaminatio n and the best fo o ds fo r radiatio n . The Impo rtance o f Water Purificatio n Water abso rbs radio active particles and is easily co ntaminated. Yo u will find o ut the best way to make sure that the water yo u drink is really free fro m radiatio n. Yo u can use these metho ds fo r heavy metal and bacterial co ntaminatio n fro m o utdo o r water so urces to o , using a po rtable water purifier and so me purificatio n tablets. It’s also great fo r the great o utdo o rs o r drinking water fro m an unkno wn so urce. Do n’t play dice with yo ur water, disco ver the best system fo r who le ho use purificatio n. Supplements that Pro tect fro m Radiatio n Expo sure There are natural supplements and herbs that are po werful eno ugh to deto x radiatio n and heavy metals (cesium 137, uranium and pluto nium are actually heavy metals) fro m yo ur bo dy, fo o ds and liquids. These are the same substances that were used to clean up the Cherno byl nuclear explo sio n. Make sure yo u have so me o f these substances o n hand fo r emergencies and during times o f high radiatio n expo sure. Use the supplements that actually wo rk and are no n-to xic to yo ur bo dy. Lo o k at o ur guide to Radiatio n Herbs. Radiatio n Sickness Treatment Guide Disco ver the best ho listic supplements, herbs and radiatio n pro tective devices that that yo u can use to make sure that yo u and yo ur family get thro ugh any expo sure to radiatio n. Be prepared and yo u’ll no t have to panic, even if it appears that the sky is falling. Co nsult the radiatio n pro tectio n manual and yo u’ll be assured that yo u kno w exactly what to do and ho w to do it. Fo r mo re info rmatio n read the manual o n Radiatio n Safety. 39 views
Co p yrig ht © 20 0 9 - 20 11 Fre e Pre s s Re le as e .c o m. All rig hts re s e rve d .
Wo rd p re s s the me b y The me J unkie , mo d ifie d b y Fre e Pre s s Re le as e .c o m.
Zeolit Protects You From RadiationSecrets of Permanent Fat Loss and Fitness
Home Radiation Safety Manual by Jay_Cruz_15787 viewsEmbedDownloadDescriptionHome Radiation Safety GuideHome Radiation Safety GuideInterests: Types, Instruction manuals, GadgetsRead on Scribd mobile: iPhone, iPad and Android.Copyright: Attribution Non-Commercial (BY-NC)Download as PDF, TXT or read online from ScribdFlag for inappropriate contentShow moreShow less
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A Tutorial Introduction to Derive by Wade Ellis, Ellis Wade, Lodi - New, Rare & Used Books Online at Alibris Marketplace
Books Mathematics Algebra A Tutorial Introduction to Derive
A Tutorial Introduction to Derive by
Students can use the computer-algebra and graphing capabilities of Derive in the study of calculus and linear algebra. With the help of this tutorial, users can begin to use the enormous symbolic, numeric, and graphical power of Derive to experiment with graphical representations of functions and gain visual insight into abstract mathematical ...
Students can use the computer-algebra and graphing capabilities of Derive in the study of calculus and linear algebra. With the help of this tutorial, users can begin to use the enormous symbolic, numeric, and graphical power of Derive to experiment with graphical representations of functions and gain visual insight into abstract mathematical problems.
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text:
2. A Perfectly Good Man (Paperback)
Book Description Fourth Estate, 2012. Paperback. Book Condition: New. BRAND NEW ** SUPER FAST SHIPPING FROM UK WAREHOUSE ** 30 DAY MONEY BACK GUARANTEE. Bookseller Inventory # mon0000185308
5. A Perfectly Good Man
Book Description Fourth Estate 2012-05-24, 2012. Book Condition: New. Brand new book, sourced directly from publisher. Dispatch time is 24-48 hours from our warehouse. Book will be sent in robust, secure packaging to ensure it reaches you securely. Bookseller Inventory # NU-LBR-01084004
Book Description Fourth Estate, 2012. Book Condition: New. Bookseller Inventory # EH9780007465088
8. A Perfectly Good Man (Paperback)
9. A Perfectly Good Man


text:
love this dress! | My Style | Pinterest | Sparkle, Wedding Dressses and Bling
Lyska Nauman
Kristie Felella
Gorgeous with detachable halter strap A-line Chapel Train bridal gown
Wedding Dressses, Chapel Train, Wedding Ideas, Wedding Dresses, Weddings, Maggie Sottero, Future Wedding
Gorgeous with detachable halter strap A-line Chapel Train bridal gown ..... looks like my wedding dress sooo pretty
Maggie Sottero - Sylvia Bridal Gown | I love how the sparkle accents cascade down along the torso and sides. | wedding dress
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Maggie Sottero Fall 2010 – Wedding Dresses, Bridesmaid Gowns, Mother of the Bride Dresses, Prom Dresses - Charlotte's Weddings and More
Sample Wedding Dress for Sale. Maggie Sottero Sylvia Wedding Dress $400. Save 63% off full retail.
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Cheri Acre
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Sweetheart sparkle wedding gown. Reception dress
Wedding Dress for a prom dress price.
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DBV to RTB: Flights from Dubrovnik to Roatan | Expedia
Cheap Flights from Dubrovnik to Roatan
Dubrovnik to Roatan Flights
Sometimes you just need to get out of town or maybe you’re looking for a change of scenery. Regardless of the reason, a flight from Dubrovnik to Roatan will do just the trick! Go on, plan to see all the famous landmarks and eat your weight in the local cuisine. Your trip is beckoning, so answer the call by packing your suitcase and filling your travel itinerary with exploring Roatan.
Whether you’re flying for business or jet-setting on your personal time, you’ve come to the right place. Here at Expedia.com, we’ll pair you up with DBV to RTB flights that won’t make your bank account wince. Ready to temporarily leave behind Dubrovnik for new horizons? Browse through our cheap airfare, and filter by flight times and dates until you find just what you had in mind. From flights without layovers to ones that arrive early in the morning, you’ll come across plane tickets that suit your travel preferences. You can even bundle your flight to RTB with hotels and car rentals to score even bigger savings.All set to hit the clouds? Book your travel arrangements with us today and have left-over money to put toward your travel outings and adventures.

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text:
Sacral Stress Fracture Complicated by L5 Radiculopathy in a Patient with Rheumatoid Arthritis. - PubMed - NCBI
1 selected item: 30369612
Kondo N1, Fujisawa J, Arai K, Kakutani R, Endo N.
Division of Orthopedic Surgery, Department of Regenerative and Transplant Medicine, Niigata University Graduate School of Medical and Dental Sciences, Niigata 951-8510, Japan. naokikondo1214@gmail.com.
A 60-year-old Japanese woman with severe osteoporosis presented with a history of right buttock pain and right lateral lower leg pain in an L5 distribution. She had been treated with methotrexate and methylprednisolone for rheumatoid arthritis (RA) and interstitial pneumonia. Computed tomography demonstrated a sacral stress fracture in the right sacral ala. The right L5 nerve root was compressed by the fracture site. This case is rare in that L5 radiculopathy was complicated by a sacral stress fracture. Clinicians should suspect sacral stress fractures when RA or osteoporosis is present in women who experiences lumbar pain and lumbar radiculopathy.
lumbar 5 radiculopathy; osteoporosis; rheumatoid arthritis; sacral stress fracture
10.18926/AMO/56253
Fractures, Stress/complications*

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Janet Rivett Condolences | Bury Free Press
Thank you for signing the Guest Book for Janet Rivett.
Please take a moment to sign the Guest Book for Janet Rivett.
Send me a daily email when updates are made to the obituary or Condolence page for Janet Rivett.

value: This website is a United States-based website founded in 1998, the world's largest commercial provider of online memorials. The Web site hosts obituaries and memorials for more than 70 percent of all U.S. deaths.