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We can’t leave our frail and elderly to the whims of the free market. Are stories of neglect and abuse really “one-offs”?
Tue 31 Oct 2017 00.10 EDT Last modified on Tue 31 Oct 2017 00.14 EDT
‘When an aged care home has insufficient staff, there may not be time to walk residents to the toilet or even help them out of bed’ Photograph: John Birdsall/www.JohnBirdsall.co.uk
Australians are living longer than at any time in our history. The intergenerational report predicts that 40,000 people will celebrate their 100th birthday in 2055. If history is any guide, around 6.5% of these centenarians will live in an aged care home.
As the aged sector sector grows, these workers are losing their conditions | Van Badham
Dr Sarah Russell is a public health researcher and aged care advocate

type: global

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Manchester United target Asmir Begovic likely to talk to other clubs, admit Stoke City | Daily Mail Online
Manchester United target Asmir Begovic likely to talk to other clubs, admit Stoke City
Asmir Begovic has one year remaining on his current Stoke City contract
Begovic is valued at £8million by the Britannia Stadium outfit
Real Madrid are interested in Manchester United goalkeeper David de Gea
Published: 13:44 EST, 11 June 2015 | Updated: 14:38 EST, 11 June 2015
Stoke admit that goalkeeper Asmir Begovic is likely to be talking to other clubs amid speculation linking the Bosnia international with Manchester United.
Begovic is among the leading contenders to succeed David De Gea if he leaves Old Trafford for Real Madrid, and has indicated that he is only interested in moving to a club where he can be first choice.
The Spaniards are understood to be preparing a formal offer to United in the knowledge that De Gea is ready to reject the offer of a new £200,000-a-week deal and return to Madrid to be closer to his girlfriend and family.
Stoke say that goalkeeper Asmir Begovic is likely to be talking to other clubs amid speculation of a move away
Begovic has attracted interest from the likes of Manchester United, Chelsea, Roma and Inter Milan
Begovic, who has one year left on his contract at Stoke and would cost in the region of £8million, has also attracted interest from Chelsea, Roma and Inter Milan as negotiations over a new deal with Stoke have stalled.
The club’s chief executive Tony Scholes said on Thursday: ‘We would very much like him to extend his contract, but I think Asmir has said himself that he is keeping his options open and seeing what might be available for him.
Transfer News LIVE: Manchester United, Chelsea, Liverpool... PREMIER LEAGUE NEW KIT SPECIAL: The strips your team will be...
‘If I’m speaking frankly, I don’t know whether or who he might be speaking to. That’s not accusing him of anything, it’s just saying that’s the reality.’
Chelsea’s Petr Cech, Tottenham No 1 Hugo Lloris and Holland international Jasper Cillessen, who played under United boss Louis van Gaal at the World Cup last summer, are others in the frame to replace De Gea.
United No 1 David de Gea (left) is attracting strong interest from Spanish giants Real Madrid

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3 RESULTS Media Type 3 audio Topics & Subjects 2 Avantgarde 1 Ambient 1 Electronic 1 Electronic Diversity 1 Found Sounds 1 Rhythmic Noise More right-solid
Collection 3 Netlabels 3 privatelektro 1 [Fav-bruce_henry collection] 1 complex22 Favorites 1 Qool Favorites Creator 1 reverend benn schipper 1 the! 1 triphaze SHOW DETAILS

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Museum of Royal Worcester - Wikipedia, the free encyclopedia
(Redirected from Worcester Porcelain Museum)
View of the museum building in Severn Street, Worcester, England.
The Royal Worcester factory museum in the 19th century.
The Museum of Royal Worcester (former 'Worcester Porcelain Museum' and 'Dyson Perrins Museum' is a ceramics museum located in the Royal Worcester porcelain factory's former site in Worcester, England.[1]
The museum houses the world’s largest collection of Worcester porcelain.[citation needed] The collections date back to 1751[2] and the Victorian gallery, the ceramic collections, archives and records of factory production, form the primary resource for the study of Worcester porcelain and its history.[citation needed]
The museum is the only part of Royal Worcester left at the Severn Street site in Worcester after the factory went into administration in 2008 and closed in 2009. The Royal Worcester Visitor Centre, the seconds shop and the cafe all closed with the factory in 2009.[citation needed]
The Museum of Royal Worcester was formerly known as the Museum of Worcester Porcelain and the Dyson Perrins Museum and Worcester Porcelain Museum. The collections includes pieces from the beginning of porcelain manufacturing in Worcester in 1751 until the closure of the Royal Worcester factory in Worcester.[

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Blue wood bracelet with multicolor abstract pattern Wood hand
Hand painted blue wooden bracelet with abstract multicolor pattern. This bracelet is made of light wood, painted with acrylic paint and gel ink. Covered with layers of varnish.
Height: 50 mm (1,96 inch)
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Vintage Chunky Wood Bangle Bracelet, Wooden Bangle Bracelet, Natural Wood Bracelet, Carved Wood Bangle, Wide Wood Bangle Bracelet
Green elastic wood bracelet Wood stretch bracelet Wooden jewelry Wide wood bracelet 5 year anniversary gift Gift for her Gift for wife
Wide Blue Bangle Bracelet, Painted Bangle Bracelet, Blue and White Bangle Bracelet, Wide Blue Bracelet
Vintage Wood Bangle, Wide Wood Bangle, Wood Bangles, Wood Jewelry, Boho Bangle, Boho Jewelry, Vintage Wood Bangle

value: This website is an American e-commerce company focused on handmade or vintage items and craft supplies.


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Related Citations for PubMed (Select 12620119) - PubMed - NCBI
Display Settings:Summary,20 per page,Sorted by Link RankingFormatSummarySummary (text)AbstractAbstract (text)MEDLINEXMLPMID ListItems per page5102050100200Sort byLink RankingPub DateFirst AuthorLast AuthorJournalTitleRelevanceApplySend to:Choose DestinationFileClipboardCollectionsE-mailOrderMy BibliographyCitation managerFormatSummary (text)Abstract (text)MEDLINEXMLPMID ListCSVSort byLink RankingPub DateFirst AuthorLast AuthorJournalTitleRelevanceCreate FileRelated Citations for PubMed (Select 12620119)FormatSummarySummary (text)AbstractAbstract (text)MEDLINEXMLPMID ListMeSH and Other DataSort byLink RankingPub DateFirst AuthorLast AuthorJournalTitleRelevanceNumber to send5102050100200Start from citationE-mailSubjectAdditional textE-mail"SPAM" filtering software noticeAdd to ClipboardAdd to CollectionsOrder articlesAdd to My BibliographyGenerate a file for use with external citation management software.Number to send5102050100200Start from citationCreate File
Select item 126201191.Expression profiling of the schizont and trophozoite stages of Plasmodium falciparum with a long-oligonucleotide microarray.Bozdech Z, Zhu J, Joachimiak MP, Cohen FE, Pulliam B, DeRisi JL.Genome Biol. 2003;4(2):R9. Epub 2003 Jan 31.PMID: 12620119 [PubMed - indexed for MEDLINE] Free PMC ArticleRelated citations Select item 111236852.Co-ordinated programme of gene expression during asexual intraerythrocytic development of the human malaria parasite Plasmodium falciparum revealed by microarray analysis.Ben Mamoun C, Gluzman IY, Hott C, MacMillan SK, Amarakone AS, Anderson DL, Carlton JM, Dame JB, Chakrabarti D, Martin RK, Brownstein BH, Goldberg DE.Mol Microbiol. 2001 Jan;39(1):26-36.PMID: 11123685 [PubMed - indexed for MEDLINE] Related citations Select item 194540333.A Plasmodium falciparum FcB1-schizont-EST collection providing clues to schizont specific gene structure and polymorphism.Florent I, Porcel BM, Guillaume E, Da Silva C, Artiguenave F, Maréchal E, Bréhélin L, Gascuel O, Charneau S, Wincker P, Grellier P.BMC Genomics. 2009 May 19;10:235. doi: 10.1186/1471-2164-10-235.PMID: 19454033 [PubMed - indexed for MEDLINE] Free PMC ArticleRelated citations Select item 129292054.The transcriptome of the intraerythrocytic developmental cycle of Plasmodium falciparum.Bozdech Z, Llinás M, Pulliam BL, Wong ED, Zhu J, DeRisi JL.PLoS Biol. 2003 Oct;1(1):E5. Epub 2003 Aug 18.PMID: 12929205 [PubMed - indexed for MEDLINE] Free PMC ArticleRelated citations Select item 178807085.Selection of long oligonucleotides for gene expression microarrays using weighted rank-sum strategy.Hu G, Llinás M, Li J, Preiser PR, Bozdech Z.BMC Bioinformatics. 2007 Sep 19;8:350.PMID: 17880708 [PubMed - indexed for MEDLINE] Free PMC ArticleRelated citations Select item 150326336.Proteomic approaches to studying drug targets and resistance in Plasmodium.Cooper RA, Carucci DJ.Curr Drug Targets Infect Disord. 2004 Mar;4(1):41-51. Review.PMID: 15032633 [PubMed - indexed for MEDLINE] Related citations Select item 156639257.PfMyb1, a Plasmodium falciparum transcription factor, is required for intra-erythrocytic growth and controls key genes for cell cycle regulation.Gissot M, Briquet S, Refour P, Boschet C, Vaquero C.J Mol Biol. 2005 Feb 11;346(1):29-42. Epub 2004 Dec 21.PMID: 15663925 [PubMed - indexed for MEDLINE] Related citations Select item 157472578.In vivo transcriptome of Plasmodium falciparum reveals overexpression of transcripts that encode surface proteins.Daily JP, Le Roch KG, Sarr O, Ndiaye D, Lukens A, Zhou Y, Ndir O, Mboup S, Sultan A, Winzeler EA, Wirth DF.J Infect Dis. 2005 Apr 1;191(7):1196-203. Epub 2005 Feb 28.PMID: 15747257 [PubMed - indexed for MEDLINE] Free PMC ArticleRelated citations Select item 182579309.In silico discovery of transcription regulatory elements in Plasmodium falciparum.Young JA, Johnson JR, Benner C, Yan SF, Chen K, Le Roch KG, Zhou Y, Winzeler EA.BMC Genomics. 2008 Feb 7;9:70. doi: 10.1186/1471-2164-9-70.PMID: 18257930 [PubMed - indexed for MEDLINE] Free PMC ArticleRelated citations Select item 1535813610.Evidence that Plasmodium falciparum diacylglycerol acyltransferase is essential for intraerythrocytic proliferation.Palacpac NM, Hiramine Y, Seto S, Hiramatsu R, Horii T, Mitamura T.Biochem Biophys Res Commun. 2004 Sep 3;321(4):1062-8.PMID: 15358136 [PubMed - indexed for MEDLINE] Related citations Select item 1600508711.The Plasmodium falciparum sexual development transcriptome: a microarray analysis using ontology-based pattern identification.Young JA, Fivelman QL, Blair PL, de la Vega P, Le Roch KG, Zhou Y, Carucci DJ, Baker DA, Winzeler EA.Mol Biochem Parasitol. 2005 Sep;143(1):67-79.PMID: 16005087 [PubMed - indexed for MEDLINE] Related citations Select item 1529651112.In vivo transcriptional profiling of Plasmodium falciparum.Daily JP, Le Roch KG, Sarr O, Fang X, Zhou Y, Ndir O, Mboup S, Sultan A, Winzeler EA, Wirth DF.Malar J. 2004 Aug 5;3:30.PMID: 15296511 [PubMed - indexed for MEDLINE] Free PMC ArticleRelated citations Select item 1870611513.Dynamic RNA profiling in Plasmodium falciparum synchronized blood stages exposed to lethal doses of artesunate.Natalang O, Bischoff E, Deplaine G, Proux C, Dillies MA, Sismeiro O, Guigon G, Bonnefoy S, Patarapotikul J, Mercereau-Puijalon O, Coppée JY, David PH.BMC Genomics. 2008 Aug 18;9:388. doi: 10.1186/1471-2164-9-388.PMID: 18706115 [PubMed - indexed for MEDLINE] Free PMC ArticleRelated citations Select item 1243543814.Stochastic versus stable transcriptional differences on Plasmodium falciparum DNA microarrays.Ganesan K, Jiang L, Rathod PK.Int J Parasitol. 2002 Dec 4;32(13):1543-50.PMID: 12435438 [PubMed - indexed for MEDLINE] Related citations Select item 1240866115.Monitoring the chromosome 2 intraerythrocytic transcriptome of Plasmodium falciparum using oligonucleotide arrays.Le Roch KG, Zhou Y, Batalov S, Winzeler EA.Am J Trop Med Hyg. 2002 Sep;67(3):233-43.PMID: 12408661 [PubMed - indexed for MEDLINE] Free ArticleRelated citations Select item 1977974216.Phenotypic and transcriptomic analyses of Plasmodium falciparum protein kinase A catalytic subunit inhibition.Wurtz N, Desplans J, Parzy D.Parasitol Res. 2009 Nov;105(6):1691-9. doi: 10.1007/s00436-009-1615-6. Epub 2009 Sep 25.PMID: 19779742 [PubMed - indexed for MEDLINE] Related citations Select item 1203445117.Laser capture microdissection of Plasmodium falciparum liver stages for mRNA analysis.Semblat JP, Silvie O, Franetich JF, Hannoun L, Eling W, Mazier D.Mol Biochem Parasitol. 2002 May;121(2):179-83.PMID: 12034451 [PubMed - indexed for MEDLINE] Related citations Select item 1628935718.Upregulation of expression of the reticulocyte homology gene 4 in the Plasmodium falciparum clone Dd2 is associated with a switch in the erythrocyte invasion pathway.Gaur D, Furuya T, Mu J, Jiang LB, Su XZ, Miller LH.Mol Biochem Parasitol. 2006 Feb;145(2):205-15. Epub 2005 Oct 25.PMID: 16289357 [PubMed - indexed for MEDLINE] Related citations Select item 1625334319.Long versus short oligonucleotide microarrays for the study of gene expression in nonhuman primates.Walker SJ, Wang Y, Grant KA, Chan F, Hellmann GM.J Neurosci Methods. 2006 Apr 15;152(1-2):179-89. Epub 2005 Oct 25.PMID: 16253343 [PubMed - indexed for MEDLINE] Related citations Select item 1832811120.No miRNA were found in Plasmodium and the ones identified in erythrocytes could not be correlated with infection.Xue X, Zhang Q, Huang Y, Feng L, Pan W.Malar J. 2008 Mar 10;7:47. doi: 10.1186/1475-2875-7-47.PMID: 18328111 [PubMed - indexed for MEDLINE] Free PMC ArticleRelated citations << First< PrevPage of 6Next >Last >>

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"Esperienza da ripetere" - Review of Borgo Piaggiarella, Sovicille, Italy - TripAdvisor
"Esperienza da ripetere" - Borgo Piaggiarella
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Sovicille Luxury Hotels
Europe›Italy›Tuscany›Province of Siena›Sovicille›Sovicille B&Bs / Inns›Borgo Piaggiarella
“"Esperienza da ripetere"”
Review of Borgo Piaggiarella
Borgo Piaggiarella Via Cavour 4, Sovicille, Italy | Hotel amenities
Ranked #6 of 14 Sovicille B&B and Inns
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Borgo Piaggiarella Italy/Sovicille, Tuscany
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I'm an ER doctor who had to pronounce a young child dead after a car accident and it's all I can think about : offmychestjump to contentmy subredditsannouncementsArtAskRedditaskscienceawwblogbookscreepydataisbeautifulDIYDocumentariesEarthPornexplainlikeimfiveFitnessfoodfunnyFuturologygadgetsgamingGetMotivatedgifshistoryIAmAInternetIsBeautifulJokesLifeProTipslistentothismildlyinterestingmoviesMusicnewsnosleepnottheonionOldSchoolCoolpersonalfinancephilosophyphotoshopbattlespicsscienceShowerthoughtsspacesportstelevisiontifutodayilearnedTwoXChromosomesUpliftingNewsvideosworldnewsWritingPromptsedit subscriptionsfront-all-random | gadgets-sports-gaming-pics-worldnews-videos-AskReddit-aww-Music-funny-news-movies-books-history-food-philosophy-television-Jokes-Art-DIY-space-Documentaries-Fitness-askscience-nottheonion-todayilearned-personalfinance-gifs-listentothis-IAmA-TwoXChromosomes-creepy-nosleep-GetMotivated-WritingPrompts-LifeProTips-EarthPorn-explainlikeimfive-Showerthoughts-Futurology-photoshopbattles-mildlyinteresting-dataisbeautiful-tifu-OldSchoolCool-UpliftingNews-InternetIsBeautiful-sciencemore » offmychestcommentsrelatedwant to join? sign in or create an account in seconds|Englishlimit my search to /r/offmychestuse the following search parameters to narrow your results:subreddit:subredditfind submissions in "subreddit"author:usernamefind submissions by "username"site:example.comfind submissions from "example.com"url:textsearch for "text" in urlselftext:textsearch for "text" in self post contentsself:yes (or self:no)include (or exclude) self postsnsfw:yes (or nsfw:no)include (or exclude) results marked as NSFWe.g. subreddit:aww site:imgur.com dogsee the search faq for details.advanced search: by author, subreddit...this post was submitted on 19 Feb 20141,633 points (96% upvoted)shortlink: remember mereset passwordloginSubmit a new text postoffmychestsubscribeunsubscribe174,875 readers254 users here nowThis is the place to unload that baggage that's been weighing you down for days, weeks, months, or years. This is to relieve the pit in your stomach that won't go away, not for the angry rant you could spew at anyone. When you need to make a post for yourself, not necessarily for advice, or to answer questions, but to get it off your chest, we'll be here to listen and, if you want, to talk. The Rules
created by richie_nya community for 5 yearsmessage the moderatorsMODERATORSTheSilentNumberprinceofprancekxrayellowmixTheYellowRosetwr3xSaferbotmMelatoninIrbyTremormach-2...and 1 more »163216331634I'm an ER doctor who had to pronounce a young child dead after a car accident and it's all I can think about (self.offmychest)submitted 1 year ago by 392472934221 commentssharecancelsorry, this has been archived and can no longer be voted onloading...sorted by: besttopnewhotcontroversialoldrandomq&ayou are viewing a single comment's thread.view the rest of the comments →there doesn't seem to be anything hereaboutblogaboutvaluesteamsource codeadvertisejobshelpsite rulesFAQwikireddiquettetransparencycontact usapps & toolsAlien Blue iOS appreddit AMA appmobile betabuttons<3reddit goldreddit storeredditgiftsreddit.tvradio redditUse of this site constitutes acceptance of our User Agreement and Privacy Policy {Genitive}. © 2015 reddit inc. All rights reserved.REDDIT and the ALIEN Logo are registered trademarks of reddit inc.create a new accountusername:password:verify password:email: (optional)remember meget the best of reddit emailed to you once a week. learn morecreate accountsign inusername:password:remember mereset passwordsign inWe care about your privacy, and we never spam. By creating an account, you agree to reddit's User Agreement and Privacy Policy. We're proud of them, and you should read them.English [en]العربية [ar]Беларуская мова [be]български език [bg]Bosanski [bs]català [ca]česky [cs]dansk [da]Deutsch [de]Ελληνικά [el]English (Australia) [en-au]English (Canadian) [en-ca]English (Great Britain) [en-gb]English [en-us]Esperanto [eo]español [es]español [es-ar]eesti keel [et]Euskara [eu]فارسی [fa]suomi [fi]français [fr]Gàidhlig [gd]עברית [he]मानक हिन्दी [hi]hrvatski [hr]Magyar [hu]Հայերեն լեզու [hy]Bahasa Indonesia [id]íslenska [is]italiano (Italy) [it]日本語 [ja]ಕನ್ನಡ [kn_IN]한국어 [ko]Latin [la]1337 [leet]LOL [lol]lietuvių kalba [lt]latviešu valoda [lv]Nederlands [nl]Nynorsk [nn]Norsk [no]Arrrrrrrr! [pir]polski [pl]português [pt] (*)português [pt-pt]português brasileiro [pt_BR]română [ro]русский [ru]slovenčina [sk]slovenščina [sl]српски језик [sr]Srpski [sr-la]Svenska [sv]தமிழ் [ta]ภาษาไทย [th]Türkçe [tr]українська мова [uk]Tiếng Việt [vi]中文 [zh] (*) incomplete volunteer to translateπ Rendered by PID 4473 on app-125 at 2015-05-23 11:03:34.412503+00:00 running 7d6cd40 country code: US.

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Patent US3720653 - Colored interpolymers of an epoxy compound,vinylpyrrolidone and vinyl acetate - Google Patents
www.google.comhttp://www.google.com/patents/US3720653?utm_source=gb-gplus-sharePatent US3720653 - Colored interpolymers of an epoxy compound,vinylpyrrolidone and vinyl acetate
Publication number US3720653 A
Publication number US 3720653 A, US 3720653A, US-A-3720653, US3720653 A, US3720653A
Inventors G Kalopissis, A Viout
Referenced by (5), Classifications (62)
Colored interpolymers of an epoxy compound,vinylpyrrolidone and vinyl acetate
US 3720653 A
United States Patent 3,720,653 COLORED INTERPOLYMERS OF AN EPOXY COM- POUND, VINYLPYRROLIDONE AND VINYL ACETATE Gregoire Kalopissis and Andre Viout, Paris, France, assignors to Societe Anonyme dite: LOreal, Paris, France No Drawing. Continuation-impart of application Ser. No. 549,446, May 12, 1966. This application Jan. 25, 1971, Ser. No. 109,693 Claims priority, application France, Apr. 20, 1966, 58,324; Luxembourg, May 13, 1965, 48,591 Int. Cl. C08f 15/40 US. Cl. 26080.72 4 Claims ABSTRACT OF THE DISCLOSURE A colored copolymer soluble in a solvent selected from the group consisting of water, alcohol and mixtures thereof consisting essentially of a first comonomer containing a reactive epoxy group and being selected from the group consisting of glycidyl methacrylate, glycidyl acrylate and allyl glycidyl ether, a second comonomer consisting of vinylpyrrolidone, the remaining comonomer being essentially vinyl acetate, and a dye selected from the group consisting of azo, anthraquinone and benzene dyes containing an extra-nuclear radical having the formula:
wherein 'R is selected from the group consisting of hydrogen, CH and -C H and p is 26, said extra-nuclear radical being bonded to the aromatic nucleus of said dye through a nitrogen atom directly attached to said aromatic nucleus and said dye being bonded to said reactive epoxy group through the terminal nitrogen atom of said extra-nuclear radical.
SUMMARY OF THE INVENTION This application is a continuation-in-part of application Ser. No. 549,446, filed May 12, 1966, now abandoned. Many hair lacquers or setting lotions are presently known which comprise natural or synthetic resins in alcoholic or hydro-alcoholic solutions. are transparent, and are intended to keep the hair in place Most of the lacquers or setting lotions heretofore used while imparting certain additional qualtiies such as sheen or lustre, without changing the color, or even the shade of the hair.
It has, however, also been suggested that hair lacquers or setting lotions be used which do affect the color of the hair to which they are applied.
It was first suggested that dyes be incorporated into the lacquers or lotions which are soluble in the solutions of resins from which they are made, but these attempts did not give satisfactory results because the dye is not adequately retained by the resin and hair treated therewith stains the skin, and any clothing coming in contact therewith.
In order to at least partially overcome this difliculty, it has been suggested that the lacquers or setting lotions be made with colored polymers which may he obtained by copolymerization of a colored monomer with colorless monomers or by chemically bonding to an already polymerized resin dyes which are capable of imparting a durable color thereto.
In particular, the applicant has already suggested the formation of colored polymers comprising amide groups,
3,720,653 Patented Mar. 13, 1973 the nitrogenous part of which is formed by groups of dyes consisting of the aromatic diamines.
However, such colored polymers are not currently used to make hair lacquers or setting lotions because they have certain disadvantages.
First, in some cases, the bonding of the dye to the resin, or to the monomer which serves to form the resin, weakens or undesirably modifies the shade of the dye.
But above all, the types of colored resins which have heretofore been proposed have had inadequate cosmetic properties as compared with the very high qualities of the colorless resins already known.
It is well known that resins used in hair lacquers or lotions must have certain contradictory qualities which are difficult to reconcile.
In the first place, these resins must be soluble in water or in alcoholic medium so that they may be applied and must be easily removable by simply shampooing the hair. On the other hand, they must have an excellent resistance to humidity so as to avoid giving the hair a sticky appearance which is considered particularly unattractive.
Moreover, these resins must be sufficiently hard and transparent to impart a sheen to the hair. They must also be removable by simply brushing, but without any tendency to peel off or crumble when the hair is subjected to the bending to which a coilfeur is normally subjected.
The present invention relates to colored resins having characteristics which make it possible to prepare lacquers and setting lotions which have cosmetic properties comparable to those of the best colorless lacquers actually on the market and in which the dye is bonded to the resin without adversely affecting the shade of the dye and without changing the qualities of the supporting resin.
The present invention provided colored resins which can be used as the hair holding ingredient in hair lacquer or setting lotion compositions. These resins are essentially characterized by the fact that they consist of a polymer comprising on the one hand monomers suitable for the production of cosmetic resins and, on the other hand, at least one monomer having a reactive epoxy group to which a dye having an extra-nuclear primary or secondary amine group is chemically bound by opening of the epoxy group in the following manner:
11+ Mon-ours: 0,: b
The resulting function is a fl-hydroxy amino function.
The monomers comprising an epoxy group are selected from the group consisting of glycidyl methacrylate, glycidyl acrylate and allylglycidyl ether.
The monomers which may be used for obtaining cosmetic resin properties include vinylic esters such as vinyl acetate, vinyl lactarns such as vinylpyrrolidone, alkyl acrylates or methacrylates, and acrylamides or methacrylamides and mixtures of said monomers.
Among the extra-nuclear amine dyes which may be used in carrying out the invention are thosehaving the following formula:
/H Col.(CH2)pN\ in which:
p is 2 to 6 inclusive, and
CH3 and 'C2H5.
The expression Col. represents a cyclic or polycyclic dye selected from the group consisting of azo, anthraquinone and benzene dyes which have at least one amine function which has its nitrogen atom bonded to said group.
These dyes may contain one or more supplementary amine functions, N alkyl having 1 to 4 carbon atoms, alkoxy of which the alkyl moiety is 1 to 4 carbon atoms and other customary substitute groups directly attached to the ring.
In order to obtain a desired shade, several colored polymers having different colors can be mixed together, or several successive dyes of different colors may be bound to the copolymer. In this case only a small proportion of the first dye is used so that sufiicient epoxy groups remain on the copolymer to permit a second and even a third dye to be bound to the copolymer.
In certain cases it may be advantageous to condense a dye on the colorless copolymer in less than stoichiometric proportions so as to leave some unreacted epoxy groups which may improve the cosmetic qualities of the resin.
The properties of the colored polymers obtained are dependent on the starting monomers as well as on the proportion in which they are mixed.
The copolymers may for example contain from 2 to 30% and preferably from 5 to 20% of the monomer having the reactive epoxy group, such as glycidyl methacrylate, glycidyl acrylate, or allylglycidyl ether.
In addition to those monomers, such as vinyl acetate, which impart a tendency toward insolubility to the resin, these copolymers may contain, depending upon the properties desired, about 5 to 30% of monomers which render the resulting resin more soluble in alcohol or water, an indispensable property, particularly when it is to be used in aerosol or solution form. Vinylpyrrolidone, in the proportions indicated above, is preferably used for this purpose.
In order to prepare hair lacquers or setting lotions, these colored copolymers may be used alone or mixed with other colorless polymers such as polyvinylpyrrolidone or copolymers such as polyvinylpyrrolidone/vinyl acetate, in proportions which depend on the intensity of the color sought.
Another object of this invention is to provide a colorless polymer capable of being colored by a condensation reaction with a dye having a primary or secondary amine group, said polymer being essentially characterized by the fact that it is prepared by starting with at least one monomer having a reactive epoxy group and at least one other monomer suitable for use in preparing a cosmetic resin.
The color imparting unit of the colored copolymer may be represented by the following formula:
in which R is selected from the group consisting of hydrogen atom and methyl radical, and R is selected from the group consisting of (a) -c-0-oHl( JHcHl-NH(oHt)pN-R,
OH Iii:
hydrogen atom, CH and --C H p is 2 to 6 inclusive, and
R is a dye residue selected from the group consisting of azo, anthraquinone and benzenic dyes.
The preferred R is selected from the group consisting of:
wherein R is selected from the group consisting of hydrogen and wherein R represent a member selected from the group consisting of hydrogen, CH and -C H and R represents a member selected from the group consisting of hydrogen, OCH and CH wherein R has the meaning given above and R and R are selected from the group consisting of hydrogen and --NH and The copolymers of this invention may be prepared according to various known processes some of which are illustrated by Examples 1 to 3 set forth below. We prefer to carry out the polymerization in a solvent such as dioxane, dimethylformamide or ketones, in the presence of a catalyst such as benzoyl peroxide or azo bis-isobutyronitrile.
The condensation reaction of the epoxy group and the extra-nuclear amine group to bond the dye to the resin may be carried out by heating the dye and the colorless copolymer in a solvent such as dimethyl formamide, dioxane or the ketones. With the dye of this invention having an extra-nuclear primary or secondary amine groups, it is not necessary to employ a catalyst for the opening of the epoxy ring. The progress of the condensation reaction may be easily followed by measuring the progressive disappearance of the epoxy group. Examples 4-7 set forth below illustrate this reaction.
It is noteworthy that the reaction of the dye on the copolymers cited above in no way affects the shade of the dye reactant, or the cosmetic properties of the resulting colored resins. They are the same as those of the colorless starting resins.
Another object of this invention is to provide hair lacquers or setting lotions characterized by the fact that they contain in an alcoholic or hydroalcoholic solutions at least one color imparting copolymer of the type described above.
In order to obtain aerosol lacquers it is possible, for example, to first prepare a 2 to 20%, and preferably a 4 to 12% solution of the colored copolymer hereinbefore described, (or a mixture of this colored copolymer and another cosmetic resin) in alcohol, and then add to this solution from 2 to 3 times its own weight of a propellant which has been liquefied under pressure, such as any of the halogenated hydrocarbons sold under the trademark Freon.
Setting lotions may be prepared by mixing into an alcoholic solution having from 20 to 50 of alcohol about 0.5 to 6%, and preferably from 1 to 3% by weight of at least one colored copolymer such as has been described, which copolymer may be mixed with other colorless cosmetic resins.
Of course, the hair lacquers and setting lotions may contain other substances customarily used for cosmetic purposes, such as plastifiers, perfumes, etc.
The hair lacquers or lotions made from these colored copolymers have the same cosmetic properties as hair lacquers or setting lotions made from colorless resins having the same composition, except for the dye bonded to the resin.
The color of the resins makes it possible for them to impart to the hair a desired shade or highlight without any deterioration in the other cosmetic properties of the resin.
Tests have unexpectedly shown that these colored copolymers do not stain the skin or clothing against which they rub after having been applied to the hair.
This surprising result is the consequence of the strong bonding between the extra-nuclear amino dye and the epoxy polymer.
Indeed with dyes having a nuclear amino function, the dye compound does not remain chemically bonded to the epoxy polymer and consequently can stain the skin or clothing.
Moreover, the colored resins according to the invention are completely and easily removed by washing or brushing, so that the hair may be given a certain particular shade or color for as short a time as may be desired.
In order that the invention may be more clearly understood several examples will now be described.
EXAMPLE 1 Preparation of a copolymer comprising 70% vinyl acetate, 25% vinylpyrrolidone and glycidyl methacrylate The following monomers are introduced into a flask provided with an agitator, a condenser, a thermometer, and a tube for introducing nitrogen:
G. Vinyl acetate 140 vinylpyrrolidone 50' Glycidyl methacrylate 10 300 g. of dioxane and 3 g. of azo-bis-isobutyronitrile are added, and the mixture heated to reflux for 24 hours. \After cooling, the copolymer is precipitated with ether, and dried.
A 95% yield of a white powder is obtained, said powder having an epoxy index corresponding to the polymerization of 4.5% of the glycidyl methacrylate.
In the same way, a polymer having 5% glycidyl acrylate may be obtained.
EXAMPLE 2 Preparation of a copolymer comprising 70% vinyl acetate 20% vinylpyrrolidone and 10% allylglycidyl ether The following monomers are introduced into a flask provided with an agitator, a condenser, a thermometer and a tube for introducing nitrogen:
G. Vinyl acetate 140 vinylpyrrolidone 40 Allylglycidyl ether 20 300 g. of dioxane, and then 3 g. of azo-bis-isobutyronitrile and 3 g. of benzoyl peroxide are added.
A 91% yield of white powder is obtained, which has an epoxy index corresponding to the polymerization of 7.5% of the allylglycidyl ether.
EXAMPLE 3 Preparation of a copolymer comprising 70% vinyl acetate, 25% vinylpyrrolidone and 5% allylglycidyl ether The procedure is the same as in Example 1, except that the glycidylmethacrylate is replaced by allylglycidyl ether.
EXAMPLE 4 Preparation of a colored copolymer by condensing the epoxy group of the copolymer described in Example 3 with the anthraquinone dye having the formula:
30 g. of the copolymer described in Example 3 and 170 g. of dioxane are introduced into a flask provided with an agitator, a condenser, a thermometer, and a tube for introducing nitrogen. After dissolving, 2.8 g. of the above dye, which corresponds to 1 mol of dye for each mol of epoxy, is added.
A yield of 85% by weight of a cerise red powder is obtained, which is soluble in alcohol and in a hydroalcoholic mixture.
Analyses have shown that 76% of the theoretically possible quantity of the dye is combined.
EXAMPLE 5 Preparation of a colored copolymer by reacting the epoxy group of the copolymer described in Example 2 with the dye having the formula:
60 g. of the copolymer described in Example 2 and g. of dioxane are introduced into a flask provided with an agitator, a condenser, a thermometer and a tube for introducing nitrogen. After the copolymer has completely dissolved, 8.28 g. of the above dye, which amounts to 1 mol of dye per mol of epoxy, is added, while stirring.
Analyses have shown that 83% of the theoretically possible quantity of the dye is combined.
7 EXAMPLE 6 Preparation of a colored copolymer by condensing the epoxy group of the copolymer described in Example 2 with a dye having the formula:
30 g. of the copolymer described in Example 2 and 70 g. of dioxane are introduced into a flask provided with an agitator, a condenser, a thermometer and a tube for introducing nitrogen. After this has dissolved, 4.14 g. of the above dye, which corresponds to 1 mol of dye per mol of epoxy, is added, while stirring.
EXAMPLE 7 Preparation of a colored copolymer by condensing the epoxy group of the copolymer described in Example 2 with a dye having the formula:
18.5 g. of the copolymer described in Example 2 and 49 g. of dioxane are introduced into a flask provided with an agitator, a condenser, a thermometer, and a tube for introducing nitrogen. After dissolving, 2.56 g. of the above dye, which corresponds to 1 mol of dye per mol of epoxy, is added, while stirring.
This is heated to reflux for 18 hours. After the reaction the copolymer is precipitated, using ethyl ether and then dried.
The result is a yield of 85% by weight of a yelloworange powder which is oluble in alcohol and in a hydroalcoholic mixture.
Analyses have shown that 88% of the theoretically possible quantity of the dye is combined.
APPLICATIONS Example A A setting lotion was made by preparing the following solution:
Copolymer obtained as set forth in Example 5 g 2 Ethyl alcohol ml 50 Water, q.s.p ml 100 This lotion is applied to brown hair after shampooing. The hair is then set in the u ual manner.
Example B In order to make a colored aerosol lacquer, the following solution was prepared:
Copolymer obtained as in Example 5 1 Copolymer obtained as in Example 7 1.7 Polyvinylpyrrolidone (PVP) MW 40000,
K value=30) 5 Absolute alcohol, q.s.p 100 30 g. of this solution was introduced into an aerosol bomb with 43.8 g. of trichloromonofiuoromethane, the product sold under the trademark Freon 11, and 26.1 g. of dichlorodifiuoromethane, the product sold under the trademark Freon 12.
When sprayed onto the hair the result is a mahogany lacquer which does not rub oflf on clothing or pillows. It is easily removed by brushing and shampooing.
Example C In order to make a colored aerosol lacquer, the following solution was prepared:
G. Copolymer obtained as in Example 4 0.05 Copolymer obtained as in Example 7 -e 0.1
Vinyl acetate/vinylpyrrolidone copolymer (sold under the trade name E 735," K value (1% ethanol)=30-50 5 Alcohol, q.s.p.
NH-CHz-CHz-NH:
NH-CH:
It will be appreciated that the scope of the invention is not limited to the details of the examples which have been given and that they may be suitably modified without thereby departing from the basic principles of the invention.
1. A colored copolymer soluble in a solvent selected from the group consisting of water, alcohol and mixtures thereof consisting essentially of 2 to 30% by weight of a first comonomer containing a reactive epoxy group and being selected from the group consisting of glycidyl methacrylate, glycidyl acrylate and allyl glycidyl ether, to 30% by weight of a second comonomer consisting of vinylpyrrolidone, the remaining comonomer being essentially vinyl acetate and a dye selected from the group consisting of azo, authraquinone and benzene dyes containing an extra-nuclear radical having the formula:
wherein R is selected from the group consisting of hydrogen, CH and -C H and p is 2-6, said extra nuclear radical being bonded to the aromatic nucleus of said dye through a nitrogen atom directly attached to said aromatic nucleus and said dye being bonded in a range between 76% to 90% of the theoretically possible quantity to said first comonomer through a fl-hydroxyamino function, resulting from the reaction between said reactive epoxy group and the terminal nitrogen atom of said extra nuclear radical.
2. The colored copolymer of claim 1 in which the color imparting unit of the copolymer, resulting from the reaction between the dye containing the terminal nitrogen atom and the comonomer containing the reactive epoxy group, has the following formula:
L l L ii in which R is selected from the group consisting of hydrogen and methyl, and
10 wherein R is selected from the group consisting of hydrogen, -CH and -C H p is 2 to 6 inclusive, and R is selected from the group consisting of:
wherein R represents a member selected from the group consisting of hydrogen and NHCH and both R, and R are selected from the group consisting of hydrogen and --NH and 3. The colored copolymer of claim 1, which contains epoxy groups which are not combined with the dye.
4. The colored copolymer of claim 1, in which the pro portion of the first comonomer containing the reactive epoxy group is from 5 to 20% by weight.
References Cited UNITED STATES PATENTS 3,135,720 6/ 1964 Batzer et al 260--80.5 3,251,743 5/ 1966 Hahn et al 167-88 3,344,098 9/ 1967 Horiguchi et a1 26022 3,364,186 1/1968 Wilhelm et a1 260-80.72 3,617,165 11/1971 Kalopissis 8--10.1 3,619,101 11/1971 Kalopissis 8--10.1
JAMES A. SEIDLECK, Primary Examiner S. M. LEVIN, Assistant Examiner US. Cl. X.R.
I UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No; 3,720,653 bated M rch 15,1975
Inve'ntor(s) Gregoire Kalopissis and Andre Viout It is certified that error appears in the above-identified patent and that said Letters'Patent are hereby corrected as shown below:
Foreign Application Priority Data [30] May 13, 1965 Luxembourg. 4 592 Apr-11,20, 1966 France................5832 &
Signed a nd sealed this 12th day of February 1974.
EDWARD M'.FLETCHER,J.RB C. MARSHALL DANN Attestlng Offlcel" Commissioner of Patents FORM PC4050 (10459) USCOMM-DC 60376-P69 [1.5. GOVERNMENT PRINTING OFFICE: 199 366-534,
US4228259 * Aug 8, 1977 Oct 14, 1980 L'oreal Water-soluble cationic polymer dye compounds and process for producing the same
U.S. Classification 528/326, 8/647, 8/405, 424/70.15, 424/47
International Classification C08F20/54, C08F220/32, C08F8/14, A61K8/41, C08F8/30, A61K8/81, C08F22/36, C08F8/32, A61K8/49, C08G59/32, A61K8/40, A61Q5/06, A61K8/35, C09B69/10, C09B1/28, C08F8/00
Cooperative Classification A61K2800/57, C09B69/10, C08F220/32, A61K8/355, C08F8/14, C08F8/00, C09B1/285, A61K8/4926, A61Q5/06, C08F8/32, A61Q5/065, A61K8/8164, A61K8/8152, C08F22/36, C08F20/54, A61K8/8182, A61K8/418, C08F8/30, A61K8/40, C08G59/3209, C09B1/28
European Classification C08F22/36, C08F20/54, C08F8/00, C08F8/14, C08F220/32, A61Q5/06D, C09B1/28B, A61K8/49C4, A61K8/81K4, C08G59/32B, A61K8/40, A61K8/41R, C09B69/10, A61Q5/06, A61K8/81R4, C09B1/28, C08F8/32, A61K8/35C, C08F8/30, A61K8/81M

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Capital Yorkshire - Wikipedia, the free encyclopedia
Local programming is produced and broadcast from Capital's Leeds studios from 6-10am and 4-7pm on weekdays and 12-4pm at weekends. All networked programming originates from Global Radio's London headquarters, including the syndicated Vodafone Big Top 40 on Sunday afternoons.
The station's local presenters are Adam O'Neill, Danny Oakes and Joanne 'JoJo Kelly (Capital Breakfast), Pete Allison (weekday drivetime) and James Cussack (weekend afternoons)
Capital Reports[edit]
Capital Yorkshire broadcasts hourly local news updates, known as Capital Reports, from 6am-7pm on weekdays and 6am-12pm at weekends with headlines on the half hour during breakfast and drivetime on weekdays. The Leeds newsroom also produces bulletins for Communicorp-owned Heart Yorkshire.
^ "LBC News replaces Galaxy on digital TV". The Airwaves. 15 November 2010. Archived from the original on 24 July 2011. ^ Global Radio takes Capital national, Brand Republic, 13 September 2010
Retrieved from "https://en.wikipedia.org/w/index.php?title=Capital_Yorkshire&oldid=700877537"	Categories: Capital (radio network)Radio stations established in 1997Radio stations in YorkshireHidden categories: Use dmy dates from April 2012Use British English from April 2012All articles with unsourced statementsArticles with unsourced statements from October 2007Coordinates on Wikidata	Navigation menu
Add links	This page was last modified on 21 January 2016, at 04:52.


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Amazon.co.uk: Profile For Rosie Thomas: Reviews
Profile for Rosie Thomas > Reviews
Content by Rosie Thomas
Reviews Written by Rosie Thomas Show:
Dynamic BabyStart Delfina Toy Box - Solid Pine with accompanying Set of 10 KiddiSafe Door Stoppers
5.0 out of 5 stars Fantastic Toy Box!, 5 Jan. 2015
This review is from: Dynamic BabyStart Delfina Toy Box - Solid Pine with accompanying Set of 10 KiddiSafe Door Stoppers (Baby Product)
Fantastic toy box! I wasn't expecting much because of the price but I couldn't be happier. Looks great in my living room (and doesn't look like a toy box so it helps make my house look less of a nursery which is great). There is a cut out section under the lid so little fingers don't get shut in but also there is a stiff hinge so the lid doesn't fall either. I couldn't be happier with it and my lg loves searching through it all. Highly recommended.
3.0 out of 5 stars Sling bookcase, 5 Jan. 2015
This bookcase looks good but it is quite small. (my fault for not checking dimensions..). Was fairly quick to put together but was very fiddly trying to get middle rods to stay in place while you screw in the top and bottom ones. I also find it difficult to display the books neatly because small books are hidden and larger ones make the books tip slightly, so paper backs could end up being bent. However the furniture itself looks great in my LG's bedroom but I am going to look for a normal bookcase too.
4.0 out of 5 stars hangers, 17 July 2014
So glad I bought these. They are nice and thin so I can get more in my wardrobe easily. One broke when I got it out of the packet but the rest seem very sturdy. So good I got more.
Offered by Conexus Trading Ltd
5.0 out of 5 stars Shaker Bottle, 17 July 2014
Love this! I use it to do my slimfast milkshakes in, it's soooo much quicker and smoother just by shaking it in this. I used to blend it in a blender with ice but it's not very practical to do that when you are busy. This is a lifesaver when I only have a few spare minutes in the morning.
3.0 out of 5 stars Cleaning nightmare., 17 July 2014
This review is from: Oxo Good Grips Dish Rack (Home)
Does what it says on the tin really but when it came to clean it, it got a little fiddly. Because of the bits sticking up you can't easily get in the grooves. I now use cotton buds and thinking kf going back to my old normal drainer.
Premier Housewares Recycle Bin - 48 Litre - Stainless Steel
3.0 out of 5 stars Recycle Bin, 17 July 2014
This review is from: Premier Housewares Recycle Bin - 48 Litre - Stainless Steel (Kitchen & Home)
It's ok. Good quality and didn't come dented like some other people got. Good finish and looks nice in my kitchen. Easy to empty and has space to tuck in bin liners so it looks neater than a normal bin. I think the price is very steep for what it is though and I think maybe I should have had a cheaper one.
5.0 out of 5 stars Fantastic Feeder!, 17 July 2014
I could not recommended this enough. It is brilliant for putting fruit in. My LG loves being able to feed herself her fruit rather than me giving her puree. She loves having grapes in it sliced in half. Also great for teething, I put the grapes or strawberries chopped up in the freezer and give her them when she is in pain. It's the best relief from teething pain she gets. I prefer this to the net ones because it's super easy to clean and doesn't make as much mess. One thing I don't like is that the hole is quite small compared to the net ones but that hasn't stopped me buying another to keep at my parents house.
TRESemm� Keratin Smooth 7 Day Smooth Heat Activated Treatment - 120 ml
2.0 out of 5 stars tresseme keratin smooth, 17 July 2014
This review is from: TRESemm� Keratin Smooth 7 Day Smooth Heat Activated Treatment - 120 ml (Personal Care)
I bought the whole range of this to try and tame my frizzy hair a little bit. Even though I used the recommended amount it left my hair really greasy and my hair never gets greasy. It wasn't a very nice feeling and couldn't finish straightening it like that. Very disappointed as it was pretty expensive stuff.
4.0 out of 5 stars suction bowls, 17 July 2014
These are fantastic. My LG loves the bright colours and I love the fact they have lids. Means I can keep any leftovers in the fridge or can defrost any purrees in them. Suction works quite well but I don't actually use it as my LG just sticks her hands in so I keep the bowls in my hand. Maybe it will be more useful when she is older.
4.0 out of 5 stars door stop, 17 July 2014
Do what they say on the tin really. Great value and the unfinished wood effect looks great.

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Book Hotel Miraya, Velez-Malaga, Spain - Hotels.comEnglish (United States)Book online or call 800-246-8357This call is free. 24 hours a day; 7 days a week.HotelsHotel DealsPackages & FlightsGroupsGift CardsHelpWebsite feedbackSign in & AccountSign inCreate an accountYour bookingsTrip PlannerReview a hotelHotels.com® RewardsYour bookingsJump toOverviewRoom choicesMapReviewsHotel informationLowest price: $36Check availability HotelsSpain HotelsVelez-Malaga HotelsHotel MirayaAll hotels in Velez-Malaga, Spain1 room, 2 adultsChange searchDestination, hotel, landmark or addressCheck inCheck out Rooms123456789+Room 1:Adults12345678Aged 18+Children01230-17Age at check in:Child 1:-?-<11234567891011121314151617SearchYou can collect Hotels.com® Rewards nights hereHotel Miraya, Velez-Malaga2 stars2 starsCalle Patrón Veneno, 6, Torre del Mar, Velez-Malaga, Malaga, 29740, Spain, 800-491-6126Lowest price$36Price GuaranteePrice Guarantee on hotel bookings. If you find a better price on exactly the same stay, we’ll either match it or give you a coupon. Click below for details.Jump to:OverviewRoom choicesMapReviewsHotel informationReceptionStandard Double Room - GuestroomStandard Double Room - GuestroomSuperior Double Room - GuestroomStandard Double Room - GuestroomStandard Double Room - GuestroomSingle Room - GuestroomSingle Room - GuestroomSuperior Double Room - BalconySuperior Double Room - BalconyStandard Double Room - BathroomStandard Double Room - Bathroom SinkHotel BarHotel BarHotel BarHallwayInterior DetailProperty GroundsHotel FrontHotel FrontHotel EntranceBeachBeachFountainExteriorExteriorBeach/Ocean ViewBeach/Ocean ViewBeach/Ocean View[1/30]Flag this image1 - Hotel Miraya, Velez-Malaga2 - Hotel Miraya, Velez-Malaga, Reception3 - Hotel Miraya, Velez-Malaga, Standard Double Room, Guestroom4 - Hotel Miraya, Velez-Malaga, Standard Double Room, Guestroom5 - Hotel Miraya, Velez-Malaga, Superior Double Room, Guestroom6 - Hotel Miraya, Velez-Malaga, Standard Double Room, Guestroom7 - Hotel Miraya, Velez-Malaga, Standard Double Room, Guestroom8 - Hotel Miraya, Velez-Malaga, Single Room, Guestroom9 - Hotel Miraya, Velez-Malaga, Single Room, Guestroom10 - Hotel Miraya, Velez-Malaga, Superior Double Room, Balcony11 - Hotel Miraya, Velez-Malaga, Superior Double Room, Balcony12 - Hotel Miraya, Velez-Malaga, Standard Double Room, Bathroom13 - Hotel Miraya, Velez-Malaga, Standard Double Room, Bathroom Sink14 - Hotel Miraya, Velez-Malaga, Hotel Bar15 - Hotel Miraya, Velez-Malaga, Hotel Bar16 - Hotel Miraya, Velez-Malaga, Hotel Bar17 - Hotel Miraya, Velez-Malaga, Hallway18 - Hotel Miraya, Velez-Malaga, Interior Detail19 - Hotel Miraya, Velez-Malaga, Property Grounds20 - Hotel Miraya, Velez-Malaga, Hotel Front21 - Hotel Miraya, Velez-Malaga, Hotel Front22 - Hotel Miraya, Velez-Malaga, Hotel Entrance23 - Hotel Miraya, Velez-Malaga, Beach24 - Hotel Miraya, Velez-Malaga, Beach25 - Hotel Miraya, Velez-Malaga, Fountain26 - Hotel Miraya, Velez-Malaga, Exterior27 - Hotel Miraya, Velez-Malaga, Exterior28 - Hotel Miraya, Velez-Malaga, Beach/Ocean View29 - Hotel Miraya, Velez-Malaga, Beach/Ocean View30 - Hotel Miraya, Velez-Malaga, Beach/Ocean ViewVelez-Malaga beach hotel with restaurant Free WiFi Main amenities21 guestroomsNear the beachRestaurantBreakfast availableTerrace24-hour front deskAir conditioningDaily housekeepingGardenCar rentals on siteFront desk safeSnack bar/deliFor familiesFree cribs/infant bedsRollaway/extra beds (surcharge)Private bathroomFree toiletriesGardenTerraceWhat’s aroundIn Torre del MarParroquia de San Andres Apostol (0.3 mi / 0.5 km)Aquavelis Water Park (1.1 mi / 1.8 km)El Ingenio Mall (1.5 mi / 2.5 km)Baviera Golf (3 mi / 4.7 km)Centro de Arte Contemporaneo de Velez Malaga (4.1 mi / 6.7 km)See mapGood3.8 / 5RoomRoom is all rightLocationGreat locationCleanlinessCleanServiceFantastic service32See all 32 Hotels.com reviewsTripAdvisor Traveller Rating: 4From 94 reviewsTripAdvisor Traveller RatingEmailSaveShareHotels.com® RewardsBook this hotel and collect nights after your stayHotel Miraya, Velez-MalagaHotel Info: 866-539-8117 from $36Destination, hotel, landmark or addressCheck inCheck out Rooms123456789+Room 1:Adults12345678Aged 18+Children01230-17Age at check in:Child 1:-?-<11234567891011121314151617Check availability Superior Double RoomDouble Room Single UseStandard Double RoomSingle RoomDouble Room (with extra bed)Triple RoomSingle RoomCheck availability More great choicesSee all hotels in Velez-MalagaList viewMap viewSee all hotels in Velez-MalagaAt a glanceKey factsHotel sizeThis hotel has 21 roomsThis hotel is arranged over 4 floorsArriving/leavingCheck-in time 1 PM-8 PMCheck-out time is 11:30 AMExpress check-in/outRequired at check inCredit card or cash deposit required
No parkingSee mapOther informationResort fee included Also known asHotel MirayaHotel Miraya Velez-MalagaMiraya Velez-MalagaPoliciesCash transactions at this property cannot exceed EUR 2500, due to national regulations. For further details, please contact the property using information in the booking confirmation. Only registered guests are allowed in the guestrooms. The name on the credit card used at check-in to pay for incidentals must be the primary name on the guestroom reservation. Mandatory feesThe charges below are included in the total price displayed: Resort fee Optional extrasRollaway beds are available for EUR 25.00 per dayFull breakfast is offered for an extra charge of EUR 4 for adults and EUR 4 for children (approximately)Nearby Two Star Velez-Malaga hotelsHotel Costamar2 starsExcellent4.2 / 5From $35Hotel Rural Cortijo Amaya - Bed & Breakfast2 starsOutstanding4.7 / 5From $61Apartamentos Intercentro Torrox-Costa2 starsExcellent4.3 / 5Hotel Sierra Tejeda2 starsExcellent4.1 / 5From $46See more Two Star Velez-Malaga hotelsIn the hotelFood and drinkFull breakfast daily (surcharge)Restaurant Snack bar/deli Room service (during limited hours) Things to doBicycle rentals nearbyHiking/biking trails nearbyScuba diving nearbySnorkeling nearbyWindsurfing nearbyServices24-hour front deskTours/ticket assistanceLuggage storageFacilitiesNumber of buildings/towers - 1Elevator/liftSafe-deposit box at front deskGardenTerraceTelevision in common areasIn the roomHome comfortsIn-room climate control (air conditioning)Air conditioningThings to enjoyIndividually decoratedFreshen upPrivate bathroomShower/tub combinationFree toiletriesHair dryerBe entertained19-inch flat-screen TV Cable/satellite TV channels Stay connectedDeskFree WiFiMoreDaily housekeepingIn-room safeTop Velez-Malaga hotelsMinimalRooms3 starsOutstanding5.0 / 5From $2334Seasons Mezquitilla Apartment3.5 starsOutstanding5.0 / 5From $231Casa Los Dos Bed & Breakfast - Adults Only3.5 starsOutstanding5.0 / 5Pedregalejo Holiday Beach Apartments3 starsOutstanding5.0 / 5From $82$73Recently reviewed hotels in Velez-MalagaApartamentos Nono Charming Stay3 starsOutstanding4.7 / 5From $73"This was exactly what we were looking for -- a combination hotel and apartment. Like a hotel, Nono offered an excellent, multilingual staff who were all very friendly, helpful…"May 20, 2017Feel Apartments La Merced3 starsGood3.9 / 5From $60"Booked this at the last minute so no research. Terrible time finding the business office. A ten minute walk from the apartments in the rabbit warren of the old town.
After being…"May 17, 2017Hotel Zen Airport3 starsGood3.7 / 5From $50"It was pleasant stay. Shuttle service to beach, city center and airport was great. Very nice place"May 16, 2017Hotel Cala Bahía & SPA4 starsGood3.3 / 5From $61"Absolutely wonderful place, great everything, location, room, truly enjoyed a couple of days of r and r"May 16, 2017Nearby hotelsHotel Mainake4 starsExcellent4.1 / 5From $54BQ Andalucia Beach Hotel4 starsGood3.9 / 5From $87El Paraíso2 starsNo guest ratings yetFrom $60Apartamentos Intercentro Algarrobo-Costa3 starsGood3.6 / 5Also popular with travelers from the USASee all hotels in Velez-MalagaList viewMap viewSee all hotels in Velez-MalagaSpecial featuresDiningBar-Cafeteria - This café serves brunch and light fare. Hotel Miraya, Velez-Malaga’s small printAlso known asHotel MirayaHotel Miraya Velez-MalagaMiraya Velez-MalagaPoliciesCash transactions at this property cannot exceed EUR 2500, due to national regulations. For further details, please contact the property using information in the booking confirmation. Only registered guests are allowed in the guestrooms. The name on the credit card used at check-in to pay for incidentals must be the primary name on the guestroom reservation. Mandatory feesThe charges below are included in the total price displayed: Resort fee Optional extrasRollaway beds are available for EUR 25.00 per dayFull breakfast is offered for an extra charge of EUR 4 for adults and EUR 4 for children (approximately)We have included all charges provided to us by this hotel. However, charges can vary, for example, based on length of stay or the room you book.Hotel Miraya, Velez-MalagaIs the description of this hotel not correct? Tell usChoose one of the following to unlock Secret Prices and pay less on select hotels.EmailSign up for our latest offersHotels.com appDownload the app and book on the goHotels.com® RewardsJoin now! Collect 10 nights, get 1 free*Top DestinationsHotels in New York, New YorkHotels in Las Vegas, NevadaHotels in Chicago, IllinoisHotels in San Francisco, CaliforniaHotels in Washington, District of ColumbiaHotels in Boston, MassachusettsHotels in San Diego, CaliforniaHotels in Orlando, FloridaHotels in London, United KingdomHotels in New Orleans, LouisianaHotels in Los Angeles, CaliforniaHotels in San Antonio, TexasHotels in Paris, FranceHotels in Seattle, WashingtonHotels in Atlanta, GeorgiaHotels in Philadelphia, PennsylvaniaHotels in Austin, TexasHotels in Atlantic City, New JerseyHotels in Rome, ItalyHotels in Myrtle Beach, South CarolinaHotels in Dallas, TexasHotels in Houston, TexasHotels in Denver, ColoradoHotels in Miami, FloridaSupport & FAQsYour bookingsFAQsContact usWebsite feedbackReview a hotelFor Suppliers, Affiliates and the MediaAffiliate with usPrivate LabelPromote with UsTravel AgentsPress OfficeUser Terms and Privacy PolicyTerms & ConditionsPrivacy PolicyCookie PolicyAbout our adsAbout UsAdd your hotelJobsTravel GuidesTop 50 CitiesAll countriesAll hotelsSite index© 2017 Hotels.com, L.P. All rights reserved.Hotels.com and the Hotels.com logo are trademarks or registered trademarks of Hotels.com, LP in the U.S. and/or other countries. All other trademarks are property of their respective owners.* Learn more about Hotels.com® RewardsABOUT SSL CERTIFICATES

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Words containing eronotu | Words that contain eronotu
Words containing eronotu | Words that contain eronotu http://www.thefreedictionary.com/words-containing-eronotuPrinter Friendly
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MapReduce frameworks and methods - Adam Horvath, Google Technology U…
MapReduce frameworks and methods - Adam Horvath, Google Technology User Group, Sydney
Making sense of your data to give n...
How to get started with MapReduce, how to learn the basics without the extremely steep learning curve
Prasad Mukka
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MapReduce frameworks and methods Presenter: Adam Horvath (adam@teamleadnet.com)23 May 2012, Sydney Adam Horvath 1
Count the flowers• Given a flower field• Given unlimited resources• How to count the different colours of flowers in minimal time?23 May 2012, Sydney Adam Horvath 2
Original problem• Building product recommendations – For a ‘web shop’• Looking for easy to use frameworks – Not too many generic ones• Data warehouse – Way too complex, way too expensive• Maximum 1 screen to write the whole processing – If it’s longer, you wouldn’t understand• Functional languages - steep learning curve – Neither you nor others would understand23 May 2012, Sydney Adam Horvath 3
MapReduce based solutions• Mapreduce data processing – Takes a while to get used to it• Hadoop – Way too hard to start with• Lightweight frameworks – A little limitation here and there• MapReduce.NET – Roll your own23 May 2012, Sydney Adam Horvath 4
How can I learn to fly/MapReduce?• Hadoop, petabytes of data – Get a Boeing 747 – Pass the required 1500 hours of flying – Ready to go!• Simple frameworks, gigabytes of data – Order a plane model online for $30 – Play with a simulator for 60 minutes – Ready to go!23 May 2012, Sydney Adam Horvath 5
What is MapReduce• Simple framework to parallel batch process data (even semi- or unstructured data)• The output is usually reasonable size (human readable or for other systems)• Working with key-value pairs• Two major steps: Map and Reduce23 May 2012, Sydney Adam Horvath 6
What is not MapReduce• Database – The input is usually plain text files• Online tool – The process starts in batches, might run for hours• A language – Any programming language can be used to create Map and Reduce steps (depending on the framework used)• Compressing cartographic data23 May 2012, Sydney Adam Horvath 7
Map• Transform the input data into something that can be aggregated (counted, grouped…)• The “SELECT T1,T2… FROM X…” part of the query• Map from Key1-Value1 to – Key1-Value2 OR – Key2-Value2• Example, log file line: – “20120501 /urlxxx” – Input key: might be null or file name – Input value: the line itself• Output – Key: “urlxxx” Value: “20120501”23 May 2012, Sydney Adam Horvath 8
Reduce• Aggregates the output of the Map step• The simplest case is just to output the Map result without processing• The “…SUM() … GROUP BY…” part of the query• Reduces from Key1-Value1 to – Key1-Value1 (ideally, value1 is a list or a sum) – Key1-Value2 (input and output are incompatible)• Input – Key: “urlxxx” Value: “20120501” – Key: “urlxxx” Value: “20120502”• Output – Key: “urlxxx” Values: “20120501, 20120502”23 May 2012, Sydney Adam Horvath 9
Taken from Google Code University 23 May 2012, Sydney Adam Horvath 10
“Embarrassingly parallel”• MapReduce only makes sense when the data can be processed parallel• Easy to slice the input into smaller chunks/problems• Nothing is too big/complex if can be taken apart• There is no overlapping/dependence between the chunks23 May 2012, Sydney Adam Horvath 11
Structured vs Unstructured data• MapReduce frequently works on unstructured data or semi structured data• Structured is great for answering requests – Normalised SQL tables – Typically quick answers – Reasonable size of data• Unstructured is great for finding hidden trends – Logs, documents, images… – Typically batch processed, slow answers – Any size of data23 May 2012, Sydney Adam Horvath 12
History of MapReduce• Google described it in 2004• Map and reduce exists in many languages, manly in functional ones• Input/output is stored on a distributed file system (GFS)• Google Inc. holds PN/7,650,331 - System and method for efficient large-scale data processing23 May 2012, Sydney Adam Horvath 13
Questions for MapReduce• Create a database with inverted index• Recommend content based on previous visits• Parse logs, create visitor analytics• Process text documents, categorise them• Process images• Find partners for life23 May 2012, Sydney Adam Horvath 14
When to choose SQL• Small structured data – Normalised tables – The database engine is capable of running the JOINs and GROUP BYs• Online requirement – If the answer needs to be served within a second23 May 2012, Sydney Adam Horvath 15
Typical framework limitations• Same reduce output as input – Reduce input: [K1, [V1]], [K1, [V2]], output: [K1,[V1,V2]] – No need to create mergers but limits the complexity• Memory – The hard disk is the new tape• Debugging – No framework is flawless but usually hard to debug• Typed/untyped, generics – Very hard to understand the process without types• Network usage• Faulty/dead machines slow the whole process down23 May 2012, Sydney Adam Horvath 16
Well known frameworks• Hadoop – Java based, data stored on HDFS – HDFS – open source distributed file system for large files (~Google File System) – HBase – built on top of HDFS, provides fast key- value lookup for tables (~Google Bigtable)• Pig – Map Reduce expressed in Pig Latin• Hive - SQL over Hadoop• Sqoop - data from SQL to Hadoop23 May 2012, Sydney Adam Horvath 17
MapReduce components• Input – Reads data storage (files, database…)• Slicer – Distributes the huge data into small chunks• Map – Transfers the data for easy processing• Partition/sort – Sorts the output of Map operation to transfer to Reducers• Reduce – Aggregates the data• Merger – Merges two or more outputs of Reduces• After process – Some cleanup• Output – Writes the output of the MapReduce to disk (files, database…)23 May 2012, Sydney Adam Horvath 18
MapReduce.NET• Open source• Written in c#• Made for couple of machines with several Gb of data• Can process TB with batches• In comparison – Facebook: Hadoop, 4800 cores, 5.5 PetaBytes, – 12 TB per node23 May 2012, Sydney Adam Horvath 19
Counting flowers• Make small areas on the field• Place Mappers on each areas• Have one or more reducer for some areas• Mapper yells color, reducer takes note• Another reducer/merger merges the output of reducers23 May 2012, Sydney Adam Horvath 20
Counting flowers - code// MAPpublic override void Map(string key, string value, IQueue<Color, int> result){ Flower[] flowers = Flower.ParseArr(value); foreach (var item in flowers) { result.Push(item.Color, 1); }}// REDUCEpublic override int Reduce(Color key, int value, int result){ return result + value;}23 May 2012, Sydney Adam Horvath 21
Inverted index• Mapping from content to location – “expression” -> file.txt, 44• Lucene is a great tool utilising inverted indices• Index types – DocId list - which documents contain the term – Positional list - where do the documents contain the terms – Schema-independent - unique position of the word in the whole data store• Stop words – Can crate noise, like the word “the” – Omitting it can cause problems • “The veronicas”23 May 2012, Sydney Adam Horvath 22
Demo Inverted index23 May 2012, Sydney Adam Horvath 23
Product recommendation• Recommend content based on user behaviour – Use visit log, but other factors like clicking previous recommendations and aging are important too• Process – MAP Log  Session-ProdId – REDUCE Session-ProdId  Session (ProdId 1, ProdId 2...) – MAP Session (ProdId 1, ProdId 2...)  Transition (ProdId 1-ProdId 2), Transition(ProdId 2 -ProdId 2) – REDUCE Transition(ProdId 1-ProdId 2)  ProdId 1 (ProdId 2, ProdId 3…)23 May 2012, Sydney Adam Horvath 24
Demo Product recommendation23 May 2012, Sydney Adam Horvath 25
How to get started• Download MapReduce.NET, write simple processors• Download Hadoop VM from Cloudera – Fix all the bugs in the VM… – Start creating distributed processing• Create theories, prove them using your logs!23 May 2012, Sydney Adam Horvath 26
Case studies• Works for me – Find churning customers/visitors – Detecting keywords and searching by keyword – Item recommendation• Yahoo – Search, search assist• eHarmony – Matchmaking• Nugg.ad – Predictive Behavioral Targeting• Facebook – Recommendations, etc.23 May 2012, Sydney Adam Horvath 27
CS101 – why is it slow?• Use custom data structures – Built in one like LinkedList, Stack, Queue will blow up – create fixed size structures• Serialization is always slow, deserialization is even worse – Avro IDL, Apache Thrift IDL, ProtoBuf• Dictionary*“slow”+++ – is a find/read/modify/find/write operation – Write custom dictionary with direct indexing23 May 2012, Sydney Adam Horvath 28
CS101 – why is it slow?• Do not use synchronisation – Few locks and waits are okay, thousands are not• Use CPU native data types – String is not• Do not use in-built string operations – Split, replace, … creates extra String instances• Don’t use RegEx• Store data in the file system – Anything that resembles a database (even SQLite) is at least a magnitude slower23 May 2012, Sydney Adam Horvath 29
CS101 – why is it slow?• Allow thread scheduler to do his job – Use Thread.Sleep(0) and not Thread.Sleep(1)• Do not use sorted data structures – Sort the data when you are done• Reflection is fine to call a long running method – But slow to call a function many times• Choose hash function very carefully – Validate the choice, collision is not your friend• Never performance test under Virtual Machines• Win32 on 32 bit platform – 2Gb max process size – On some Linux distributions depending on Kernel this holds too23 May 2012, Sydney Adam Horvath 30
URLs• This presentation http://slidesha.re/mapreduce-intro• MapReduce.NET http://code.google.com/p/mapreduce-net• Apache Hadoop http://hadoop.apache.org• Apache Pig http://pig.apache.org• Apache Hive http://hive.apache.org• Cloudera Hadoop demo VM https://ccp.cloudera.com/display/SUPPORT/Clouderas+Hadoop+De mo+VM• A Comparison of Approaches to Large-Scale Data Analysis http://pages.cs.brandeis.edu/~olga/cs228/Reading%20List_files/be nchmarks-sigmod09.pdf• Information Retrieval: Implementing and Evaluating Search Engines http://www.ir.uwaterloo.ca/book23 May 2012, Sydney Adam Horvath 31
Questions Adam Horvath (adam@teamleadnet.com)23 May 2012, Sydney Adam Horvath 32
After hour labs Adam Horvath (adam@teamleadnet.com)23 May 2012, Sydney Adam Horvath 33
Making sense of your data to give new insight - Elasticsearch at Findability ...

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Juneteenth Music Festival Tickets, Sat, Jun 1, 2019 at 11:00 AM | Eventbrite
by Tamko Francis Garrison
Sat, June 1, 2019, 11:00 AM – 7:00 PM CDT
Frank Sotile, Jr. Pavilion
2162 Thibaut Drive
Donaldsonville, LA is scheduled to celebrate its 23rd Annual Juneteenth Music Festival It will be held on Saturday, June 1, 2019 from 11am - 7pm.
Donaldsonville’s Juneteenth line-up includes DJ Thriller, DJ Slaughter, DJ Child Support, Red Tape Music, the Michael Foster Project and more..
Not only will you be able to relax to soulful sounds, you will literally be able to spend your entire day at Juneteenth doing nothing but listening to great music and eating (Fried chicken wings, Jambalaya, Smoked Turkey Legs, Fried Fish Poboys, Fried Turkey Wings, Nachos and Cheese, Funnel Cakes, Pies, Boiled Turkey Necks, Boiled Shrimp, Homemade Lemonade, Chicken and Pasta and sooo much more).
The festival committee is committed to continue the tradition started in Donaldsonville by Former Mayor B.J. Francis Sr. and his wife, the late Janet G. Francis, in 1996 and continued throughout the years by Kathy Hambrick, Oliver Joseph and other community leaders.
Juneteenth commemorates the day when slaves in the last geographic area in America where slavery existed learned of their freedom. This took place on June 19, 1865, in Galveston, Texas, when Union General Gordon Granger read General Order #3, announcing that "all slaves are free"by Proclamation of President Abraham Lincoln. TheEmancipation Proclamation was signed by President Abraham Lincoln on September 22, 1862, and issued on January 1, 1863. It took over two and a half years for the news to travel to southwest Texas. "Juneteenth is a landmark in history, a celebration of freedom and the end of enslavement in America," states Rev. Ronald V. Myers, Sr., M.D., Founder & Chairman of the National Juneteenth Observance Foundation (NJOF) and the National Juneteenth Jazz Artist.
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Pulcinella (complete ballet) - Igor Stravinsky - BBC Music The BBC has updated its cookie policy. We use cookies to ensure that we give you the best experience on our website. This includes cookies from third party social media websites if you visit a page which contains embedded content from social media. Such third party cookies may track your use of the BBC website. We and our partners also use cookies to ensure we show you advertising that is relevant to you. If you continue without changing your settings, we'll assume that you are happy to receive all cookies on the BBC website. However, you can change your cookie settings at any time. Continue Change settings Find out more ]]> Accessibility links Skip to content Accessibility Help BBC iD Notifications
]]> Music Tracks Performances Playlists Artists More My Music Menu My Music Home Tracks Popular Find a Track Recommended Performances Popular All Recommended Playlists Featured All Recommended Artists Popular All Recommended More BBC Music News LIVE BBC Music My Generation BBC Introducing BBC Music in iPlayer BBC Proms Glastonbury BBC Performing Groups Sound Of 2017 My Music My Tracks My Performances My Interviews My Playlists My Artists Pulcinella (complete ballet) Share this track Share this with Digg Facebook Google LinkedIn Reddit StumbleUpon Twitter Copy this link http://www.bbc.co.uk/music/records/nn4jn5 Read more about sharing. Add Artist Igor Stravinsky Languages:

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SEGRO owns commercial and industrial properties in the UK, France, Czech Republic, Poland, Italy, the Netherlands, Belgium, Spain and Germany.[6] The Company's portfolio (including joint venture assets) was valued at £5.9bn at 31 December 2016.[1]
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Words containing elinnai | Words that contain elinnai
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Words containing elinnai
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