Title: Contribution of cellular automata to the understanding of corrosion phenomena,
Abstract: We present a stochastic CA modelling approach of corrosion based on spatially
separated electrochemical half-reactions, diffusion, acido-basic neutralization
in solution and passive properties of the oxide layers. Starting from different
initial conditions, a single framework allows one to describe generalised
corrosion, localised corrosion, reactive and passive surfaces, including
occluded corrosion phenomena as well. Spontaneous spatial separation of anodic
and cathodic zones is associated with bare metal and passivated metal on the
surface. This separation is also related to local acidification of the
solution. This spontaneous change is associated with a much faster corrosion
rate. Material morphology is closely related to corrosion kinetics, which can
be used for technological applications.