Title: Exceeding the Shockley-Queisser limit within the detailed balance framework,
Abstract: The Shockley-Queisser limit is one of the most fundamental results in the
field of photovoltaics. Based on the principle of detailed balance, it defines
an upper limit for a single junction solar cell that uses an absorber material
with a specific band gap. Although methods exist that allow a solar cell to
exceed the Shockley-Queisser limit, here we show that it is possible to exceed
the Shockley-Queisser limit without considering any of these additions. Merely
by introducing an absorptivity that does not assume that every photon with an
energy above the band gap is absorbed, efficiencies above the Shockley-Queisser
limit are obtained. This is related to the fact that assuming optimal
absorption properties also maximizes the recombination current within the
detailed balance approach. We conclude that considering a finite thickness for
the absorber layer allows the efficiency to exceed the Shockley-Queisser limit,
and that this is more likely to occur for materials with small band gaps.