Title: Calculation of hyperfine structure constants of small molecules using Z-vector method in the relativistic coupled-cluster framework,
Abstract: The Z-vector method in the relativistic coupled-cluster framework is employed
to calculate the parallel and perpendicular components of the magnetic
hyperfine structure constant of a few small alkaline earth hydrides (BeH, MgH,
and CaH) and fluorides (MgF and CaF). We have compared our Z-vector results
with the values calculated by the extended coupled-cluster (ECC) method
reported in Phys. Rev. A 91 022512 (2015). All these results are compared with
the available experimental values. The Z-vector results are found to be in
better agreement with the experimental values than those of the ECC values.