organobromine chemistry

organobromine rasayana shaastram anedi organobromine sammelanaala samslaeshanha mariyu lakshanaala adhyayanam, veetini organobromides anie kooda pilustaaru, ivi brominku carbon bandham kaligi unna sendriya sammelanaalu. atyanta vistrutamgaa undedi sahajamgaa utpatti ayye bromomethane. 
synthetic organobromine sammelanaala yokka oka pramukha anuvartanam polybrominated diaphenyl eetharlanu agni-nirodhakaalugaa upayoginchadam, vaastavaaniki agni-nirodhaka tayari prastutam bromine moolakam yokka pradhana paarisraamika upayogam. 
vividha rakaala chinna organobromine sammelanaalu prakrutilo kanipistaayi, conny edhee jeevasansleshanha ledhaa ksheeradaalaku avasaram ledhu. organobromine sammelanaalu vaati paryaavarana prabhavam kosam ekkuva pariseelanaloo unnaayi.
saadhaarana lakshanaalu.
chaalaa organobromine sammelanaalu, chaalaa organohalide sammelanaala maadirigaane, saapekshamgaa dhruvarahitamainavi. carbon (2.9 verses 2.5) kante bromine ekkuva electronegative. tatphalitamgaa, carbon-bromine bandhamlooni carbon electrophilic, i.ii. alkyl bromidelu alkylating agentlu.
carbon-hologen bandha balaalu ledhaa bandha vibhajana saktulu varusaga 115,83.7,72.1 mariyu 57.6 kilola/moltho untaayi, ivi florin, chlorin, bromine ledhaa ayodinlatho bandhinchabadataayi.
organobromine sammelanaala praticharya anedi organochlorin mariyu organoyodin sammelanaala praticharya madhya madhyantaramgaa untundi. aneka anuvartanaalaku, organobromidelu reactivity mariyu kharchu yokka raajeeni suuchistaayi. organobromidelaku pradhana praticharyalalo dehydrobromination, grignard praticharyalu, reductive coupling mariyu nucleophilic substitution unnaayi.
synthetic paddhatulu.
bromine nundi.
alkeenlu vishwasaneeyamgaa utprerakam lekunda bromine nuu jodinchi visinal dibromidelanu istaih
sugandha sammelanaalu hydrogen bromide parinaamtho ekakaalamlo brominationku lonavutaayi. sugandha valayalapai praticharya jaragadaniki jaragadaniki ledhaa ledhaa vanti utprerakaalu avasaram. chlorin aadhaarita utprerakaalu (fekli 3, alkli 3) upayoginchavacchu, conny dihologenlu (brcl) yerpadagaligina koddi digubadi koddigaa taggutundi. electrophilic sugandha pratyaamnaayam yokka saadhaarana namuunaalanu anusarinche praticharya vivaraalu
eee praticharya yokka pramukha anuvartanam bisphenol-eah nundi tetrabromobisphenol-eah utpatti.
organobromine sammelanaalanu tayaaru cheyadaaniki bromaintho free-radikal pratyaamnaayam saadhaaranamgaa upayoginchabadutundi. carbonyl kaligina, benzylic, allilic uparitalaalu mukhyamgaa eee praticharyalaku guravutaayi. udaaharanaku, vaanijyaparamgaa mukhyamaina bromoacetic aamlam phosphorus tribromide utprerakam samakshamlo acetic aamlam mariyu bromine nundi neerugaa utpatti avtundi
bromine kooda fluoroformnu bromotrifluoromethange maarustundi.
hydrogen bromide nundi.
markovnikov niyamanni anusarinchi hydrogen bromide alkyl bromidelanu ivvadaaniki double baandla gundaa jatachestundihi
free radicals paristhitulalo, jodimpu yokka disanu tippavacchu. trutheeya amainlu mariyu quaterinary ammonium lavanaalaku puurvagaamulu ayina 1-bromoalcanela samslaeshanha kosam free-radikal adanamgaa vaanijyaparamgaa upayogistaaru. styrene nundi eee maargam dwara 2-phenethyl bromide (c6h5ch2ch2br) utpatti avutundi.
alkahal lanu alkyl bromideluga maarchadaaniki kooda hydrogen bromidenu upayoginchavacchu. takkuva ushnograta paristhitulalo cheyavalasina eee praticharya, allail bromide yokka paarisraamika samshlaeshanhaloo upayoginchabadutundih
mithanol mariyu hydrogen bromide nundi maroka fumigant ayina methyl bromide utpatti avutundi.
bromide lavanaala nundi.
sodiyam bromide vanti lavanaala dwara andinchabade bromide ayanlu, sthaanabhramsham dwara organobromine sammelanaala nirmaanamloo nucleophilesga panicheestaayi.
eee uppu madhyavartitva bromide sthaanabhramsham yokka udaaharana keatonlapy raagi (ii) bromide vadakam.
r-koo-ch2-r '+ 2 2 → r-koo-chbr-r' + 2 cuber + hbr
applications.
agni nirodhakaalu.
organobromine sammelanaalanu agnini nivaarinche mandulugaa vistrutamgaa upayogistaaru. atyanta pramukha sabhyudu tetrabromobisphenol-eah (4,4 '-(1-methylithylidine) bis-(2,6-dii-bromophenol), chitram chudandi). idhi mariyu tetrabromophthalic unhydride paalimarlaku puurvagaamulu, indulo vennemuka samayojaneeya carbon-bromine bandhaalanu kaligi untundi. hexabromocyclodecane mariyu bromodifenil eethars vanti itara agni nirodhakaalu sankalanaalu mariyu avi rakshinche padaarthaaniki rasaayanikamgaa jodinchabadavu. organobromine agnini tagginche mandula vadakam perugutondi, conny avi nirantara kalushya karakalu kabatti kooda vivadaspadamga unnaayi.
fumigants mariyu biosides.
ithileenku bromine jodinchadam dwara pondina ethylene bromide, okappudu led gasolinelo bhaagamgaa vaanijya praamukhyata kaligi undedi. idhi vyavasaayamlo 1,2-diabromo-3-chloropropane ("dbcp") nuu sthaanabhramsham chesi, oka prasiddha fumigant kooda. paryaavarana mariyu aarogya kaaranaala valla rendu darakhaastulu taggutunnaayi. methyl bromide kooda samarthavanthamaina fumigant, conny daani utpatti mariyu upayogam montrial protocol dwara niyantrinchabadutundi. neeti suddhi kosam organobromine biosidelu vaadukalo perugutunnaayi. pratinidhi agentlalo bromoform mariyu dibromodymethylhydanti ("dbdmhech") unnaayi. bromaxinil vanti konni kalupu samharakalalo bromine moitylu kooda untaayi. itara hologenated purugumandula maadirigaane, bromaxinil vaayurahita paristhitulalo tagginche dehalogenationku lobadi untundi, mariyu phenolic sammelanaalanu tagginche saamarthyam kosam modata verucheyabadina jeevula dwara debrominate cheyavachu.
rangulu.
aneka rangulu carbon-bromine bandhaalanu kaligi untaayi. 19va sataabdam chivaralo synthetic dye parisrama abhivruddhiki mundu sahajamgaa sambhavinche tyrean purpul (6,6 '-dibromoindigo) viluvaina rangu. aneka brominated anthroquinon utpannaalu vaanijyaparamgaa upayoginchabadutunnaayi. vislaeshanhaatmaka rasayana saastramlo bromothymol neelam oka prasiddha suuchika.
aushadhaalu.
vaanijyaparamgaa labhinche organobromine aushadhaalalo vasodilator naisergolin, upasamanakaari bratizolum, anticancer agent pipobroman mariyu kriminaasaka merbromin unnaayi. lekapothe, organoflorin sammelanaala paristhitiki viruddhamgaa organobromine sammelanaalu arudugaa aushadhaparamgaa upayogapadataayi. aneka mandulu bromide (ledhaa samaanamaina, hydrobromide) lavanaalugaa utpatti cheyabadataayi, conny atuvanti sandarbhaallo bromide etuvanti jeevasambandhamaina praamukhyata laeni hanikaram kaani pratighatanagaa panichestundi.
designer mandulu.
ippatike unna aushadha chattalanu tappinchukune prayatnamlo 4-bromomethcathinone vanti organobromine sammelanaalu itara hologenated amphetaminelu mariyu cathinonlatho paatu designer aushadha marketlo kanipinchaayi.
prakrutilo.
organobromine sammelanaalu prakrutilo atyanta saadhaarana organohalidelu. samudrapu neetilo chloride kosam bromide saandrata kevalam 0.3% matrame unnappatikee, organochlorin utpannaala kante organobromine sammelanaalu samudra jeevulalo ekkuvagaa unnaayi. vaati samruddhi bromide yokka sulabhamgaa aakseekarananu saktivantamaina electrophile ayina br + kuu samanamga pratibimbistumdi. bromoperoxidasela pedda kutumbamlo okataina venedium bromoperoxidase enjaim, samudra vaataavaranamloo eee praticharyanu utprerakam chestundi. mahaasamudraalu etaa 1 nundi 2 million tannula bromoform mariyu 56,000 tannula bromomethane vidudala chestayani anchanaa. havaayilo tinadagina "asparagopsis taxiformis" vanti erra algay, "limu kohu" gaa tinabadutundi, organobromine mariyu organoyodin sammelanaalanu "vesikil kanaalalo" kendrikaristundi; 95 saatam asparagopsis yokka mukhyamaina asthira noone, samudrapu paachini vacuumloo endabettadam mariyu podi manchunu upayoginchi ghaneebhavinchadam dwara tayaaru cheyabadutundi, organohologen sammelanaalu, veetilo bromoform baruvulo 80 saatam untundi. aneka algay dwara utpatti cheyabadina bromoform, telisina vishapadaartham, ayithe tinadagina algelo unde chinna mottaalu manavulaku haani kaliginchinatlu kanipinchavu. 
eee organobromine sammelanaalalo konni jaatula madhya "rasayana yuddham" roopamlo upayoginchabadataayi. ksheeradaalalo, bahukosha paraannajeevula nundi rakshanaku mukhyamaina isinophil peroxidase, chloride ayanku pradhaanyatagaa bromide ayaannu upayogistundi. maanava tella rakta kanaalalo 5-bromoracil mariyu 3-bromo-tyrosine anevi daadi chese vyadhikaaraka karakalapai myeloperoxidase-prerita hologenation yokka utpattulugaa gurtinchabaddaayi.
sampradaaya brominated sahaja utpattulato paatu, vividha rakaala organobromine sammelanaalu agni-nirodhakaalu jeevaadhokaranam chendadam valla erpadataayi. metabolitelalo methoxylated mariyu hydroxylated aaril bromidelatho paatu brominated dioxin utpannaalu untaayi. ituvanti sammelanaalu nirantara sendriya kalushya karakalaga pariganinchabadataayi mariyu ksheeradaalalo kanugonabaddayi.
bhadrata.
alkyl bromine sammelanaalu tarachugaa alkylating agentlu mariyu brominated sugandha utpannaalu harmon antarayaluga chikkukupotayi. saadhaaranamgaa utpatti ayye sammelanaalalo, ethylene diabromide atyanta vishapuuritamainadi mariyu atyanta cancer kaarakamainadi kabatti idhi chaalaa aandolana kaligistundi.

