metal bis (trimethylsil) amides

metal bis (trimethylsil) amaidlu (tarachugaa metal sililamideluga sankshipteekarinchabadataayi) anevi ionic bis (trimethylsil) amide ligandlatho kuudina catanic lohamto koodi unde samanvaya samudaayaalu mariyu ivi metal amaidla yokka vistruta vargamlo bhaagam.
bhaarii hydrocarbon vennemuka kaaranamgaa bis (trimethylsil) amide complexelu takkuva jaalaka saktulanu kaligi untaayi mariyu lipophilicga untaayi. eee kaaranamgaa, avi saadhaarana loha haalaidlaku viruddhamgaa, dhruvarahita sendriya draavakaala paridhiloo karugutaayi, ivi reactive dravakalalo matrame karigipotayi. eee steric sthuula sanklishtatalu paramaanu, veetilo mono-, dii-, mariyu tetramerlu untaayi. antarnirmita bays kaligi, eee sammelanaalu balaheenamaina protic kaarakaalato kooda soukaryavantamgaa pratispandistaayi. ligandla taragati mariyu vaati samanvaya sammelanaalapai maargadarsaka adhyayanalanu burger mariyu vannagat varninchaaru.
ligandlanu tarachugaa "hcmds" (ii.zii. m (n (sme3) 2) 3 = m (hmds) 3) anedi hexamethyldicillagen nundi tayaaru cheyabadina daaniki suuchanagaa untundi.
tayari yokka saadhaarana paddhatulu.
group 1 mariyu 2 complexelatho paatu, metal bis (trimethylsil) amaidlanu tayaaru cheyadaaniki oka saadhaarana paddhati uppu metathesis praticharya dwara alkali metal bis (trimethylsil) amaidlatho nirjala loha chloride praticharyalanu kaligi untundih
kshaara loha chloride oka upa utpattigaa erpadutundi, idhi saadhaaranamgaa ghanapadaarthamgaa avakshepistundi, idhi vadapotha dwara daani tolagimpuku veelu kalpistundi. migilina loha bis (trimethylsil) amide tarachugaa swedanam ledhaa upasheershika dwara suddhi cheyabadutundi.
group 1 complexelu.
lithium, sodiyam mariyu potassium bis (trimethylsil) amaidlu vaanijyaparamgaa andubaatulo unnaayi. draavakam laenippudu, lithium mariyu sodiyam complexelu trimericga untaayi, mariyu potassium complexes ghana sthithilo diamericga untundi.
lithium karakanni enn-butylithium mariyu bis (trimethylsil) amine nundi tayaaru cheyavachuhu
adhika ushnograta vadda bis (trimethylsil) amaintho eee karigina lohala pratyaksha praticharya kooda vivarinchabadindih
kshaara loha sililaamaidlu sendriya draavakaala shrenilo karugutaayi, ikkada avi agrigetlugaa untaayi mariyu saadhaaranamgaa sendriya rasayana saastramlo balamaina stericalga aatamkapariche sthaavaraalugaa upayoginchabadataayi. avi itara bis (trimethylsil) amide complexela samshlaeshanhaku puurvagaamulugaa kooda vistrutamgaa upayoginchabadataayi (krinda chudandi).
group 2 complexelu.
calcium iodide ledhaa barium chloridenu potassium ledhaa sodiyam bis (trimethylsil) amaidtoe chikitsa cheyadam dwara calcium mariyu barium complexelanu saadhaarana paddhati dwara tayaaru cheyavachu. ayithe, eee paddhati potassium kaalushyaaniki daariteeyavachchu. calcium ayodaidto benzyl potassium yokka praticharyatho kuudina merugaina samslaeshanha, taruvaata bis (trimethylsil) amaintho praticharya phalitamgaa potassium rahita padaartham vastundih
magnitium sililaamaidlanu dibutylmegnishium nundi tayaaru cheyavachu; idhi enn-buu mariyu ess-buu isomerla mishramamgaa vaanijyaparamgaa andubaatulo undhi. idhi vaanijyaparamgaa labhinche magnitium bis (trimethylsil) amaidnu ivvadaaniki uchita amainnu ksheenimpajestundi.
group 1 lohalaku viruddhamgaa, bis (trimethylsil) amainlooni amine enn-hetch group 2 lohalatho pratispandinchadaaniki taginanta aamlamgaa undadu, ayithe complexelanu tinn (ii) bis (trimethylsil) amide yokka praticharya dwara tagina lohamto tayaaru cheyavachuhu
eee samshlaeshanhaku sudeergha praticharya samayalu avasaram mariyu dimethoxythane vanti samanvaya draavakaala samakshamlo pradarsinchinappudu, jodimpulu erpadataayi. anduvalla benzene ledhaa toluene vanti samanvayarahita draavakaalanu uchita sanklishtatalanu pondadaaniki upayoginchaali.
pii-block complexelu.
tinn (ii) bis (trimethylsil) amide nirjala tinn (ii) chloride nundi tayaaru cheyabadutundi mariyu vaanijyaparamgaa andubaatulo untundi. idhi transmetalation dwara itara loha bis (trimethylsilamide) lanu siddham cheyadaaniki upayoginchabadutundi. group 13 mariyu bismat (iii) bis (trimethylsil) amaidlu adhe paddhatiloo tayaaru cheyabadataayi; aluminium complexenu kooda praathamika lithium aluminium hydridenu parent amaintho kathinamgaa chikitsa cheyadam dwara tayaaru cheyavachuhu
tetrasulfur tetranitride yokka pratyaamnaaya samshlaeshanhaloo loha bis (trimethylsil) amide jarugutundi [(mea3sii) 2enn]nu mundugaane erpadina ess-enn bandhaalatho purvagaamigaa upayoginchadam jarugutundi. jarugutundi [(mea3sii) 2enn] lithium bis (trimethylsil) amide mariyu sulfur dichloride dichloride yokka praticharya dwara tayaaru cheyabadutundi.
loha bis (trimethylsil) amide, amide mariyu sulfuril chloride chloride kalayikatho pratispandinchi pratispandinchi, trimethylsil chloride mariyu sulfur dioxidenu erparustundihi
tetracellinium tetranitride, tetranitride, anedi tetrasulfur tetranitrideku saaruupyamaina sammelanam mariyu selenium tetrachloride yokka praticharya dwara samslaeshanha cheyavachu. taruvaati sammelanam oka loha bis (trimethylsil) amide mariyu selenium tetrachloride (sekla 4), selenium monochloride () mariyu lithium bis (trimethylsil) amide yokka praticharya dwara samslaeshanha cheyavachu.
dii-block complexelu.
saadhaarana paddhatiki anugunamgaa, parivartana lohala bis (trimethylsil) amaidlu loha haalaidlu (saadhaaranamgaa chloridelu) mariyu kshaara loha bis (trimethylsil) amaidla madhya praticharya dwara tayaaru cheyabadataayi. ayithe, konni vaividhyaalu unnaayi, udaaharanaku samslaeshanha ti {n (sme3) 2} 3 mariyu v {n (sme3) 2} 3 varusaga karige puurvagaamulu ticl3 (nme3) 2 ledhaa vcl3 (nme3) 2 upayoginchi tayaaru cheyabadataayi. sanklishtatala yokka draveebhavana mariyu marige binduvulu shreni antataa taggutaayi, 12 lohala samuuham swedanam dwara suddeekarananu anumatinchadaaniki taginanta asthiramgaa untundi.
inupa samudaayaalu ferrous (ii) mariyu ferrick (iii) aakseekarana sthithulalo verucheyabadinanduku gurtinchadaginavi. phi [enn (sime 3) 2] 3 nuu iron trichloride lithium bis (trimethylsil) amaidtoe chikitsa cheyadam dwara tayaaru cheyavachu mariyu adhika spin iron (iii) loe 5 jatacheyani electronlu unnanduna idhi paramagnetic.
adevidhamgaa, rendu samanvayalu phe [enn (sime 3) 2] 2 complexes lithium bis (trimethylsil) amaidtoe iron dichloride chikitsa cheyadam dwara tayaaru cheyabadutundihi
muduru aakupaccha phii [n (sme3) 2] 2 sanklishtata daani bhouthika sthithini batti rendu roopaallo untundi. gyaas dasalo, sammelanam s4 samaruupatanu kaligi unna rendu-samanvaya feetho monomeric. ghana sthithilo idhi trikonamandala samatala inupa kendraalato mariyu samuuhaala madhya vantenatho oka diamernu yerparustundi. inupa samudaayam yokka takkuva samanvaya sankhya ekkuvagaa sthuulamaina bis (trimethylsil) amide yokka steric prabhaavaala kaaranamgaa untundi, ayithe sanklishtata anedi jodimpunu ivvadaaniki thf nii bandhistundi, {(thf) f [n (sme3) 2] 2}. idhe vidhamaina pravartananu mn (hmds) 2 mariyu co (hmds) (hmds) chudavachu, ivi gyaas dasalo monomeric mariyu sphatika dasalo diameric. group 11 complexelu mukhyamgaa oligomerizationku guravutaayi, ivi ghana dasalo tetramerlanu yerparustaayi. group 12 complexela yokka levis assid lakshanaalu nivedinchabaddaayi mariyu Zn mariyu cd complexela kosam merugaina e mariyu c sankhyalu eee. sii. doubleu. namoonaalo jabita cheyabaddaayi.
eff-block complexelu.
lanthanide triflates aneka bis (trimethylsil) amaidlaku soukaryavantamaina nirjaleekarana puurvagaamulu kaavachuh
ayithe, ivi choukainavi kabatti, nirjala lanthanide chloridela nundi lanthanide bis (trimethylsil) amaidla tayaareeni chudatam sarvasaadhaaranam. praticharya thf loe nirvahinchabadutundi mariyu refluxes vadda oka kaalam avasaram. okasari erpadina tarvaata, utpattini toluin kosam draavakam marpidi cheyadam dwara likel nundi vaeru chestaaru, dheenilo ln (hcnds) 3 karigedi conny likel kaadu.
lanthanide rasayana saastramlo prarambha padaarthaalugaa sililaamaidlu mukhyamainavi, endukante lanthanide chloridelu paelavamaina draavaneeyata ledhaa saadhaarana dravakalalo paelavamaina sthirathvaanni kaligi untaayi. dheeni phalitamgaa daadaapu anni lanthanide sililaamaidlu vaanijyaparamgaa andubaatulo unnaayi.
actinide bis (trimethylsil) amaidla samslaeshanha mariyu lakshanaala niroopanalo kooda kontha vijayam saadhinchindi. oka anukuulamaina krutrima maargam prarambha padaarthaalugaa iodide lavanaalu lavanaalu (thf) 4 yokka thf-jodimpulanu upayogistundi.
bhadrata.
lohapu bis (trimethylsil) amaidlu balamaina sthaavaraalu. avi tinivesevi, mariyu aneka chlorinated draavakaalatoe ananukuulamgaa untaayi. eee sammelanaalu neetitho teevramgaa pratispandistaayi, mariyu gaali rahita saanketikatato taarumaaru cheyali.

