
tsuji-wilkinson decorbonylation praticharya

suzie-wilkinson decorbonylation praticharya anedi aldehydelu mariyu konni asail chloridela decorbonylationku oka paddhati. praticharya paeru jiro tsujeeni gurtistundi, dheeni brundam eee praticharyalaku wilkinson utprerakam (rhcl (pihech3) 3) vadakanni modata nivedinchindihi
aneka parivartana loha samudaayaala dwara decorbonylation prabhaavitam cheyagaliginappatiki, wilkinson yokka utprerakam atyanta prabhaavavantamgaa niroopinchabadindi.
pratispandana yantraangam.
khachitamgaa cheppalante, eee praticharya phalitamgaa uchita carbon monoxide kakunda rhodium carbonyl complexes erpadutundi.
utpreraka chakram aldehyde (ledhaa assid chloride) yokka aakseekarana jodimpunu kaligi undi 16e asail rh (iii)-hydride madhyantaraanni istundani bhaavinchabadutundi, idhi 18-electron d6 rh (iii) carbonyl complexenu yerparustundi. taggimpu tolagimpu decarbonylated utpattini utpatti chestundi. tsuji-wilkinson decorbonylation yokka utpreraka roopaantaramlo, rhcl (co) (pph3) 2 anedi 200°C kante ekkuvagaa koo parinaamam chendutundi, tadwara rhcl (pph3) n punarutpatti avutundi. lekapothe, eee thermodynamicga sthiramaina carbonyl complexes erpadatam dwara praticharya vidhanam aagipotundi.
synthetic applications.
suzie-wilkinson decorbonylation telikapati paristhitulalo konasaagutundi mariyu atyanta stereosphacificga untundi. aliphatic, sugandha mariyu α thoo paatu, β-asantrupta aldehydelu, asail nitriles mariyu 1,2-dicketonelu kooda tagina uparitalaalu. decorbonylation kosam konni paddhatulu unnaayi.
oka udaaharanaatmaka anuvartanam fr-900482 yokka pradhana kendrakam samslaeshanha. rhodium kaarakamtho eestar prabhaavitam kaadani gamaninchandi.
(-)-presylfiperfolan-8-oel samslaeshanha yokka chivari dasalo tsuji-wilkinson decorbonylation upayoginchabadutundi. vaaru vyaakhyaanistuu, "eee chivari dasallo, 38 (70 saatam verses 93 saatam) utpatti cheyadamlo takkuva digubadini chuupadamloo pratyeka taggimpu mariyu aakseekarana dasalu munduku sagai, ayithe arhech (pihech3) 3cl operation chinna sthaayilo (15 mii. graa) nirvahinchinappudu sajavuga konasaagindi. mottamgaa, samshlaeshanhaku vaanijya prarambha padaartham nundi 13 dasalu avasaram, mariyu 15 mg [(-)-presylfiperfolan-8-oel] varnapata lakshanaalu mariyu sahaja isolate thoo saripoye optical bhramanaalatoe tayaaru cheyabadindi.anie.
takkuva ushnograta utpreraka tsuji-wilkinson decorbonylation andinchadaaniki prayatnaalu.
duradrushtavasaattu, tsuji-wilkinson decorbonylation stoichiometric. bis (triphenylphosphine) rhodium carbonyl chloride utpatti takshaname tirigi koo-free karakamga maarchabadadu. 200 masim kante ekkuva, carbon monoxide rhcl (koo) (pf3) 2 decarbonylate chestundi, ayithe eee adhika ushnogratalu tarachugaa nishedhinchabadataayi. aadarsavantamaina tsuji-wilkinson decorbonylation parisara ushnogratalaku daggaragaa utprerakamgaa untundi. 
takkuva ushnogratala vadda pravaaha paristhitulalo praticharya nirvahinchabadindi, dheenilo enn2 nuu gyaas carrierga upayoginchi biphasic liquid-gyaas flow decorbonylation abhivruddhi cheyabadindi. ayithe, eee praticharyaku avasaramaina ushnograta 200 masim.
chelating bisphosphinelatho kuudina catanic rhodium complexelanu upayoginchadam dwara tsuji-wilkinson decorbonylation yokka gananeeyamaina merugudalalu cheyabaddaayi.

