
sudorotation

rasayana saastramlo, sudorotation anedi jatacheyabadina samuuhaala intramolecular kadalikala samiti (i.ii.ligands) atyanta samaroopa anuvupai, idhi modati anuvu nundi vaeru cheyaleni anuvuku daariteestundi. swachchamaina mariyu anuvartita rasayana shaastram yokka antarjaateeya union (ipac) sudorotationnu "stereoisomerisation phalitamgaa mottam prarambha anuvu yokka bhramanam dwara utpatti cheyabadinatlugaa" kanipinche "nirmaanamgaa nirvachistundi, dheeni phalitamgaa isotopic pratyaamnaayamtho sahaa pratyaamnaayam dwara ververu sthaanaalanu vaeru cheyakapothe, modatidaanipai superposable ayina" utpatti "avutundi." 
berry sudorotation mechanism dwara trikonamandala bipyramidal sammelanaala intramolecular isomerization, cyclopentane dwara pradarsinchabade carbon anuvula avt-off-plain kadalikalu, daani aneka conformerla (envalap, twist) madhya anubhavinche paraspara maarpulaku daariteestaayi. eee kadalika dwara koneeya momentum utpatti kaadani gamaninchandi. eee mariyu sambandhita udaaharanalalo, paramaanu sthaanaala yokka chinna sthaanabhramsham, eee sthaanabhramsham saadhaaranamgaa takkuva-shakti maargaala venta unde chota, cemetric utpatti tirigi erpade varaku (krinda unna chitra udaaharananu chudandi), cemetry nashtaniki daariteestundi. berry mechanism anedi sammelanaala rakaalalo akshasambandha mariyu bhoomadhyarekha ligand yokka sulabhamaina paraspara maarpidini suuchistumdi, udhaa.zii. d3h-samamiti (choopabadindi). chivaraga, adhikaarika ardhamlo, "sudorotation" anae padam pratyaekamgaa cemetrical molecules looni dynamics nii suuchimchadaaniki uddesinchabadindi, ayithe adhe rakamaina mechanisms takkuva cemetry molecules kosam kooda upayoginchabadataayi. 

