
vistarinchina loha anuvu golusulu

organometallic chemistrylo, vistarinchina loha anuvu golusulu (emax) anevi sendriya ligandlatho chuttumuttabadina neerugaa bandhinchabadina loha anuvula sarala golusunu kaligi unde anuvulu. eee sammelanaalu atichinna paramaanu teegalanu suuchistaayi. nanoelactronicsku bottom-up vidhanam kosam ituvanti jaatulu parisoedhimchabaddaayi, ayithe etuvanti anuvartanaalu dadapuga laevu.
nirmaanam.
oka eemak anuvu parivartana lohala (saadhaaranamgaa cr, koo, nii, ledhaa sii yuu) yokka sarala stringnu kaligi untundi, ivi okadaanitoe okati bandhinchabadi, sendriya ligandlatho chuttumuttabadi untaayi. loha golusulu saadhaaranamgaa ayanlu, saadhaaranamgaa haalaidlu dwara end-cape cheyabadataayi. sendriya ligandlu tarachugaa pyridylamide, pyridone, nafthyridine ledhaa vaati utpannaalu. prati loha anuvu aaru-samanvayamtho untundi, anuvu yokka aksham venta rendu itara lohalatho bandhinchabadutundi (antima lohaalu minaha, ivi oka lohamto mariyu oka capping aanayaanto bandhinchabadi untaayi) mariyu akshaniki lambamgaa naalugu natrajani anuvulatho bandhinchabadi untaayi.
sendriya ligandlu loha ayaanlanu okadaanitoe okati kalapadam dwara golusula nirmaanaanni mariyu vaatini oka sarala teegalo samalekhanam chestaayi. ligandloni natrajani anuvula sankhya golusulo cherchabade loha anuvula sankhyanu nirnayistundi. anduvalla, samslaeshanha anedi mundugaa nirnayinchina podavaina paramaanu teegalanu istundi. eee lakshanam, anuvulu baga nirvachinchabadina chivaralanu kaligi unnayane vaastavamtho kalipi, itara rakaala paramaanu teegala nundi emaaklanu vaeru chestundih emaclu vibhina paramaanu entiteelugaa matrame untaayi, avi aggregate cheyavu mariyu avi punaraavruta unitla aavartana nirmaanaalanu roopondinchavu.
chaalaa varaku telisina eemaaklalo moodu nundi tommidi loha anuvulu untaayi. ippativaraku nirminchina athi podavaina emaclu padakondu nii anuvulanu kaligi untaayi mariyu sumaru 2 nanometers podavunu kaligi untaayi, ayithe prastutam andubaatulo unna ligandlatho 17 loha anuvula (4-5 nanometers) varaku golusulanu access cheyavachani anchanaa.
eemaaklaku viruddhamgaa, sarala golusu sammelanaalu anantamaina podavu kaligi untaayi. avi capping ligandlatho muginchabadavu.
prarambha abhivruddhi mariyu charcha.
moodu loha anuvulatho kuudina modati emaaklanu 1990la praarambhamlo shiye-ming peng (enn. tii. yuu) mariyu eff samuuhaalu swatantramgaa samslaeshanha chesaayi. albert cotton (texas eah & emm), "vistarinchina loha anuvu golusulu" anae padaanni roopondinchaaru. cobalt-kaligina anuvu koo3 (dpa) 4cl2 (dpa = 2,2 '-dipiridylamide) nuu rendu parisoedhanaa samuuhaalu samslaeshanha chesaayi, conny prati okkati ververu nirmaanaanni pratipaadinchaayih taiwan nundi vacchina samuuham podavaina mariyu chinna koo-koo bandhamtho asamaana nirmaanaanni nivedinchindi, ayithe texas samuuham samaana koo-koo bandha podavulatho samaroopa nirmaanaanni gurtinchindi. eee asammati anuvu yokka rendu roopaalu vaastavaaniki ekakaalamlo unnayani grahinche varaku, samvatsaraala tarabadi konasagina vivaadaanni rekettinchindi. eee charcha sammelanaanni paramaanu marpidiga upayoginchavacchani grahinchadaaniki daariteesinappatikee, idhi oka kotta samasyanu kooda srushtinchindi, endukante gurtinchabadina isomerism rakalu aevee okati ledhaa anthakante ekkuva bandhaala podavulo matrame bhinnamaina rendu nirmaanaatmaka roopaallo anuvu unikini vivarinchalekapoyaayi (mariyu vaati stereochemistry ledhaa anuvula anusandhaanamlo kaadu). eee samasya chivaraku pantages mariyu mcgrady dwara quantum rasayana adhyayanam dwara parishkarinchabadindi, vaaru rendu nirmaana roopaalu ververu electronic aakruteekaranala phalitamgaa unnayani chuupimchaaru. pantages-emsigrady modal prastutam vividha electronic sthithulanu ardham chesukovadaniki mariyu emacla ayaskanta lakshanaalanu ardham chesukovadaniki upayoginchabadutundi.
sambhaavya anuvartanaalu.
eemaaklaku vaanijyaparamaina anuvartanaalu laevu, conny avi naano circuitlalo vidyut vahakaalugaa upayogapadataayi. antekakunda, loha golusu yokka aakseekarana ledhaa taggimpu dwara conductainsnu niyantrinchavacchu mariyu chakkaga tune cheyavachu, idhi molecular reostatlu, switchlu mariyu transisterla nirmaanaaniki maargam terustundi. eee avakaasaalu niroopinchabaddaayih

