
dalchiniche drav

dalchiniche sanyug heey (<qema> c9h8o </qema>) c6h5ch = chcho yaa sutrasah eka sendriya sanyug aahe. pramukhyane 'trans' ('eae') isomer mhanoon naisargikaritya aadhalanare, teey dalchinila tyachi chav aanee gandh dete. haah eka phenylpropanoid aahe joou naisargikaritya shikimet margadvare sanshleshit keela jaato. heey fikat pivale, chikat drav dalchinichya zadanchya salat aanee "dalchini" jaatichya itar prajatinmadhye aadhalate. dalchinichya salche aavashyak teel sumare 90 takke dalchiniche asate. kharab sathavan kinwa vahatukichya paristhitimule auxidation jhalyamule dalchiniche styrenemadhye vighatan hote. visheshtah uchch aadrata aanee uchch tapmanat styrene tayar hote. yach karanamule dalchinimadhye styreneche praman qamee asate.
rachana aanee sanshleshan.
dalchinichya aavashyak telapasoon dalchini-baptist dumas aanee yujeen-melchiyar peligot yanni 1834 madhye dalchinichya aavashyak telapasoon dalchiniche vegalekaran kele aanee 1854 madhye italian rasayanshastradnya luigi chioza yanni prayogshalet sanshleshit kele.
naisargik utpadan 'trans'-synamaldehyde aahe. yaa renumadhye asantrupt eldehydela jodalelya benzinchya vartulacha samavesh asato. tyamule, renukade acrolinche vyutpann mhanoon pahile jaau shakate. tyacha rung π → π * sankramanamule aaheh acrolinechya tulanet vadhiv sanyugman haah band drishyaman dishene halavate.
jaivasanshleshan.
dalchiniche uchchbhransh mothya pramanat aadhalate aanee jawalun sambandhit sanyuge ligninla janm detat. asha serve sanyuge phenylaleninapasun suru houn jaivasanshleshit kelee jaatat, jyache rupantar hote.
phenylalenine amonia lies (paal) chya krutidvare-phenylalenine cinamic aesidmadhye nirmitikaranane synamaldehyde jaivasanshleshan suru hote. pail hii pratikriya naun-oxidative deminationdware utprerit karate. heey demination palchya mayo prosthetic gatavar avalambun asate. paal heey "trans-" dalchini aaml nirman karate. dusya tappyat, 4-coumerate-coa ligaj (4cl) heey acid-thayol bandhanadware dalchini aamlala dalchini-koaamadhye rupantarit karate. 4cl dalchini-koachya nirmitila utprerit karnyasathi aii. tii. pii. chaa vapar karate. 4Cl yaa pratikriyevar done tappyanmadhye parinam karate. 4cl eka hydroxycinnamate-amp enhydride tayar karate, tyanantar esile edenaletchya carbonilvar nucleophile hallah hoto. shevati, dalchini-coa heey see. see. aar. (dalchini-coa reductase) dware utprerit nadfdware qamee karoon dalchini-hyde tayar kele jaate.
tayari.
prayogshaletil sanshleshanachya anek paddhati astitvat aahet, parantu dalchinichya salchya telachya vafechya aasavanatun dalchiniche dalchiniche drav sarvat jaast aarthikdrushtya prapt hote. heey sanyug dalchini alcohole (dalchini alcoholche alcohole swaroop) yasarkhya sambandhit sanyuganpasun tayar kele jaau shakate, parantu asambandhit sanyuganmadhil pahile sanshleshan benzaldehyde aanee acetaldehyde eldol ghanikaran hote; yaa prakriyeche paytant heinry richmandne 7 november 1950 roji ghetale hote.
anuprayog.
eka swad mhanoon.
dalchini, iscream, candy, eae-drav aanee peyanmadhye chav mhanoon dalchinisathi sarvat spasht vapar aahe; vaparachi patali 9 teey 4,900 bhag prati dashalaksh (ppm) (mhanje 0.5 takkyanpeksha qamee) paryant asate. naisargik, god kinwa falanchya sugandhachya kahee perfumemadhyehi yacha vapar keela jaato. badam, jardalu, butterscotch aanee itar sugandh tyanchya sukhad vasasathi sanyugala anshatah vaparu shakatat. dalchiniche mishran annamadhye bhesal mhanoon vaparale jaau shakate; dalchiniche arkyukt sugandhit beachnutche bhuse heey dalchiniche choorn mhanoon vikale jaau shakate. kahee nyaharichya trundhanyanmadhye 187 ppm synamuldehyde asate.
krishi rasayan mhanoon.
dasanchya alyanviruddha surakshit aanee prabhavi kitaknashak mhanoon dalchinichi chachani karnyat aalee aahe. synamaldehyde 29 ppmche praman 24 tasant "edies aegypti" dasanchya ardhyahun adhik alya marte. trans-synamuldehyde praudh dasansathi eka shaktishali dhoomak aanee vyavharik vikarshak mhanoon kaam karate. yaat jivanurodhi aanee burshivirodhi gunadharm dekhil aahet.
vividh upayog.
dalchiniche loh heey polad aanee itar mishradhatunsathi ganj avarodhak aahe. teey dhatuchya prushthbhagavar snrakshak puttle tayar karate asey manale jaate.
vyutpann.
dalchiniche anek vyutpann vyavsayikdrushtya upayukt aahet. dihydrocynnamile alcohole (3-phenylpropanol) naisargikaritya udbhavate parantu dalchinichya duheri hydrogenationdware tayar hote. tyat hysinth aanee lilakcha sugandh asato. dalchini alcohole ashach prakare naisargikaritya aadhalate aanee tyat leelacha gandh asato parantu dalchinipasun suruvat karoon dekhil tayar keela jaau shakato. dihydrocynnamalde heey alkin upaghatakanchya nivadak hydrogenationdware tayar kele jaate. α-amylesynnamaldehyde aanee α-hexilcinnamaldehyde heey mahattvache vyavsayik sugandh aahet, parantu teey cinnamaldehydepasoon tayar kele jaat naheet. dalchiniche hydrogenation, jarr alkinkade nirdeshit kele tarr hydrocynnamaldehyde milate.
vishavidnyan.
synamaldehyde visharita qamee asalyamule tyacha vapar shetimadhye keela jaato, parantu too tvachesathi eka uttejak aahe. synmeldahydemule sanvedanshil vyaktinmadhye ellergiesonya sampark stomatitis houu shakato, tathapi sanyugala allergy hone asamanya asalyache manale jaate. 
dii. aine. aii. durusti.
synamaldehyde haah eka aaharatil pratidravyajan aahe joou prerit aanee utsfurt asha donhi utparivartananna prabhavipane pratibandhit karato. prayogik purave asey soochit karatat qee dalchiniche alsar heey 'escherichia kolai' yaa jivanumadhye aanee manvi peshinmadhye dii. aine. aii. chey nuksan ghadavun aanate jeey punarsanyojit dii. aine. aii. durusti karate jeey nantar utsfurt utparivartan qamee karate. 
undaranmadhye, ksh-kiran vikirananantar undaranna tondawate synamaldehyde dile gele tevha ksh-kiran prerit gunasutra vichalan qamee jhaale, kadachit synamaldehyde uttejit dna durustimule.