
chlorophilide

chlorophilide "aaa" aanee chlorophilide "buub heey anukrame chlorophyll" aaa "aanee chlorophyll" buub "chey jaivasanshleshak purvavarti aahet. tyanchya propionic acid gatanche rupantar chlorophyll synthes yaa enzymedware pathvechya antim tappyat fayatil estermadhye kele jaate. asha prakare yaa rasayanik sanyuganmadhye mukhya swarasya vanaspati, shaiwal aanee cyanobacteriatil chlorophyll jaivasanshleshan abhyasat aahe. chlorophilide "aaa" heey jivanu chlorophilachya jaivasanshleshanat dekhil madhyavarti aahe.
sanrachana.
chlorophilide "aaa" heey carboxylic aaml (aar = etch) aahe. chlorophilide "bii" madhye, 13 vya sthanavaril methyl gut (chlorophilide "aii" sathee iupac kramankan) aanee hiravya chaukatit thalak kelela, formill gatane badalala jaato.
protoporpherin ixchya nirmitiparyant jaivasanshleshan pavale uchalate.
glutamic esidpasoon suru honanya jaivasanshleshanachya suruvatichya tappyanmadhye, deaminase aanee cosynthetes yaa enzymesdware tetraprirol tayar kele jaate, jeey porphobilinogen aanee hydroxymethylabilende aminolevulinic acidche rupantar europorpherinogen III madhye karatat. nantarche heey heema, sirohem, cofactor eff 430, kobalamin aanee chlorophilsathi samanya asalele pahile macrocyclic madhyavarti aahe. pudhil madhyavarti mhanje coproporpherinogen III aanee protoporpherinogen ix, jeey purnapane sugandhit protoporpherin ix madhye auxidise kele jaate. udaharanarth, protoporpherin ixmadhye loh misalalyane raktatil auxigen vahoon nenara cofactor heema midato, parantu vanaspati tyaeivaji magneshiyam ekatra karoon pudhil parivartananantar prakashsanshleshanasathi chlorophyll detat.
protoporpherin ix pasoon chlorophylides jaivasanshleshan.
chlorophilachya jaivasanshleshit margachya shevatchya tappyanche tapasheel vanaspatinmadhye (udaharanarth 'arabidopsis thaliana', 'nikotiana tabacum' aanee 'triticum estivum') aanee jivanu (udaharanarth 'rubrivivax gelatinosus' aanee 'synaecosistis') jyamadhye tyacha abhyas keela gela aahe tyamadhye bhinn aahet. tathapi, januke aanee enzymes jaree badalat asale taree tyat samavisht rasayanik pratikriya samaan aahet.
magneshiyamche samaveshan.
chlorine navachya legandmadhye magneshiyam aayan samanvayit asane heey chlorophilache vaishishtya aahe. magneshiyam challetus yaa enzymedware dhatoo protoporpherin ixmadhye takala jaato joou pratikriyes utprerit karato. 
ring see propionet samoohache esterification.
chlorophylides dishene pudhchi payari mhanje propionet gatanpaiki ekavar methyl (ch3) ester tayar karane, jeey methylation pratikriyetil magneshiyam protoporpherin ix methyltransferase yaa enzymedware utprerit hote. 
porphirinpasoon chlorinparyant.
chlorine ring pranalimadhye paach sadasyanchi carbon ring eae tayar hote jevha porphirinchya propionet gatanpaiki eka mool pyrol ring see aanee deala jodana carbon anooshi chakriy kele jaate. magneshiyam-protoporpherin ix monomethyl ester (oxidative) cyclays yaa enzymedware utprerit rasayanik payyanchee eka malika ekoon pratikriya dete. 
javamadhye electron qamee kelelya feredoxindware pradan kele jaatat, jeey tyanna prakashpranali i pasoon kinwa andharat ferredoxin-nadapy (+) reductacepasoon prapt karoo shakatatah cyclays prathinala zannel asey naav dile jaate aanee teey "zentha-ell" janukadware encode kele jaate. rhodobacter spheroids sarkhya avayaviy jivanmadhye samaan ekandar parivartan hote parantu magneshiyam-protoporpherin ix 13-monomethyl estermadhye samavisht kelela auxigen pratikriyetil panyatoon yeto.
chlorophilide aii madhye ghat karnyachya payya.
chlorophilide "aaa" tayar karnyasathi aanakhi done parivartan aavashyak aahet. donhi qamee karnyachya pratikriya aaheth eka vinail gatala ethyl gatamadhye rupantarit karate aanee dusare pyrol ring dii madhye hydrogenche done anoo jodate, jaree macrocyclechi ekoon sugandh tikavoon thewali jaate.
yaa pratikriya swatantrapane pudhe jaatat aanee kahee jivanmadhye kram ulatato.
divinil chlorophilide heey 8-vinil-reductase asalele enzyme pratikriyemadhye 3,8-divinilprotochlorophyllide protochlorophilidemadhye rupantar karate. 
tyanantar jyaa abhikriyemadhye pyrol ring dii heey protochlorophilide reductage yaa enzymedware qamee hote
hii pratikriya prakashavar avalambun asate parantu eka paryayi enzyme aahe, jeey qamee jhalele ferredoxin tyacha sahghatak mhanoon vaparte aanee prakashavar avalambun nasate; tee samaan pratikriya karate parantu paryayi thurr 3,8-divinilprotochlorophyllide karate.
qamee karnyachya charanancha haah paryayi kram vaparnanya jivanmadhye, hii prakriya eka enzymedware utprerit kelelya pratikriyedvare purn hote jee vividh thurr gheu shakate aanee aavashyak vinail-gut qamee karoo shakate, udaharanarth yaa prakaranat
chlorophilide "aaa" pasoon chlorophilide "buub" paryant.
chlorophilide "aaa" oxygens heey eka enzyme aahe jeey chlorophilide "aaa" chey chlorophilide "buub" madhye rupantar karoon ekoon pratikriyeche utprerak banate. 
chlorophilachya jaivasanshleshanat tyacha vapar qaraa.
chlorophyll synthes hii chlorophyll aaa chey jaivasanshleshan abhikriyeche utprerak mhanoon purn karate. 
heey 20-carbon dieterpean alcohole phytols chlorophilide "aaa" madheel carboxylic acid samoohache ester tayar karate.
chlorophyll 'bii' heey chlorophilide 'bii' varr karya karananya tyach enzymedware tayar kele jaate. chlorophyll 'dii' aanee 'eff' sathee samaan olakhale jaate, donhi chlorophilide 'aii' pasoon tayar kelelya sambandhit chlorophylidespasoon tayar kele jaatat.
jivanu chlorophilachya jaivasanshleshanat vapar.
prakashsanshleshit jivanunmadhye aadhalanare sukshmajiv heey prakashvarni rangdravya aaheh teey eka dushparinam mhanoon pranavayu tayar karat naheet. asha anek sanrachana aahet parantu serve chlorophilide "aaa" pasoon vyutpann jhalyamule jaivasanshleshitpane sambandhit aahet. 
bii. see. ell. "aii": bacteriochlorine ring aanee sidechains.
bacteriochlorophyl "aaa" heey eka vaishishtyapurn udaharan aahe; tyachya jaivasanshleshanacha abhyas "rhodobacter capsulatus" aanee "rhodobacter spheroids" madhye keela gela aahe. pyrol ring beechi ghat (trans stereochemistries) hii pahili payari aahe, jee anek jivanu chlorophilchi vaishishtyapurn 18-electron sugandhit pranali dete. heey chlorophilide yaa reductase yaa enzymedware kele jaate, jeey pratikriyes utprerit karate.
pudhil done payya vinail gatala pratham 1-hydroxyethyl gatamadhye aanee nantar bacteriochlorophilide "aaa" chya acetyl gatamadhye rupantarit karatat. chlorophilide aii 31-hydrates () aanee bacteriochlorophilide aii dehydrogenase () dware khalilpramane pratikriya utprerit kelya jaatatah
prakashsanshleshanasathi antim rangdravyanmadhye esterificationsathi tayar asalelya jivanu chlorophilide "aii" tayar karnyasathi yaa teen enzyme-utprerit pratikriya vegvegalya kramane udbhavu shakatat. bacteriochlorophyl "aii" chey fayatil ester thet jodalele naheeh tyaeivaji, prarambhik madhyavarti mhanje aar = geranilgeranil (geranilgeranil pyrophosphatepasoon) asalela ester joou nantar sidechainche teen alken bandh qamee jhalyamule atirikt payyanchya adheen asato.