vatavaraniy daab photoinization nirjalikaran

desorption vatavaraniy daab photoinization (dappy) heey maas spectrometrisathi eka sabhovatalache aayanikaran tantra aahe jeey photoinization sanyogane disorptionsathi garam dravak vafecha vapar karate. pariveshiy aayanikaran tantre purvachikitseshivay namunyanche thet vishleshan karnyas anumati detat. dappisarkhe thet vishleshan tantra, bahutek aparamparik namunyanmadhye bhoomitimadhye nishkarshanachya nishkarshanachya kadhoon takte. golya, powder, raal, vanaspati aanee ootee yasarkhya mothya namunyanche vishleshan karnyasathi dappicha vapar keela jaau shakato. yaa tantrachi pahili payari garam dravak vafecha vapar karate. garam jett prushthbhagavarun namuna aushnikaritya shoshun ghete. bashpibhavan jhalelya namunyache nantar nirvat atinil prakashadvare aayanikaran kele jaate aanee parinami maas spectrometermadhye namune ghetale jaatat. dappi dhruviy aanee dhruviy nasalelya sanyuganchi shreni shodhu shakate, parantu tatasth kinwa dhruviy nasalelya sanyuganche vishleshan kartana sarvat sanvedanshil asate. heey tantra atyant sanyugmit sanyugansathi nivadak aanee mauu aayanikaran dekhil pradan karate.
itihas.
vatavaraniy daab photoinization itihas tulanene naveen aahe, parantu 1970 chya dashkatil sabhovatalachya aayanikaran tantranchya vikasadvare tyacha shodh lavala jaau shakato. dappi heey vatavaraniy daab photoineziation (aii. pii. aay.) aanee prushthbhagache shoshan tantra yasarkhya lokpriy tantranche sanyojan aahe. photoinization tantre pratham 1970 chya dashakachya uttaradhat vikasit kelee gelee aanee 1980 chya dashakachya madhyat vatavaraniy daab prayoganmadhye vaparali jaau lagali. khulya prushthbhagachya aanee mukt matricks prayoganchya nirjantukikaranatil prarambhik vikas 1999 madhye siliconver (dios) nirjantukikaran/aayanikaran vaparoon kelelya prayogat sahityat pahilyanda nondavala gela. dappyne desorption electrospre aayanikaran (desi) aanee pratyaksh vishleshan yasarkhya tantranchi jaaga vastavik velet (dart) ghetali. tantranchi hii pidhi 21 vya shatkat bhoomitimadhye alikadil serve ghadamodi aahet. deshicha shodh 2004 madhye purdue vidyapithat lagla, tarr dartcha shodh 2005 madhye larmi aanee kodeene lavala. tyanantar lagechach 2007 madhye finlandchya helsinki vidyapithat dappi vikasit karnyat aalee. dappichya vikasamule dhruviy nasalelya sanyugansathi shodhanyachi vyapti vadhali aanee thet vishleshan namunyanchya aushnik shoshanasathi eka naveen pariman jodale gele.
operationche tattva.
vatavaraniy daab photoinization darmyan honari pahili shastrakriya mhanje disortion. dravak vafechya garam jetdware namunyache shoshan suru kele jaate jeey nebulizer maykrochipadware namunyavar lakshya kele jaate. nebulizer microchip heey eka kacheche upkaran aahe jeey pyrex wefersdware ekatra bandhale jaate aanee chipchya kathavaril nojalmadhun pravah vahinya embed kelya jaatat. aat pravesh pravesh dravkache vashpikaran karnyasathi aanee dopant renu tayar karnyasathi microchip 250-350 formula _ 1c varr garam kelee jaate. namunyache aayanikaran sulabh karnyasathi dopant renu jodale jaatat. kahee samanya dravkanmadhye nitrogen, toluin, acetone aanee anisol yancha samavesh hoto. ushmiy shoshanachi prakriya done yantranandvare houu shakateh aushnik shosh kinwa gatee hastantaran/drav favarani. aushnik shoshan heey namunyache bashpibhavan karnyasathi aanee tharanchya prushthbhagache tapman vadhavanyasathi ushnatecha vapar karate. thurr prushthbhagache tapman jasjase vadhate, tastashi yantrachi sanvedansheelata vadhate. thurr tapmanacha abhyas kartana asey disun aale qee dravkacha antim tapmanavar kinwa tharanchya ushnatechya daravar lakshaniy parinam jhaala nahee. gatee hastantaran kinwa drav favarani vighatan heey namunyasah dravkachya parasparsanvadavar aadharit asate, jyamule vishisht aayan sodale jaatat. dravkachya namunyashi jhalelya takkarane aanee namunyasah aayanchya hastantaranane gatee hastantaran prasarit hote. proton aanee charge hastantaran yasarkhya sakaratmak aayananche hastantaran, tolluine aanee anisol yaa dravkansah disun yete. toluin namunyasah charge exchange yantranetun jaate, tarr acetone namunyasah proton hastantaran yantranes protsahan dete. yuu. vhee. divyane utsarjit jhalelya 10 eae. vhee. photoncha kiran navyane shoshalelya renunkade, tasech dopant renunkade nirdeshit keela jaato. tyanantar photoinization hote, jeey renuche electron baher kadhate aanee aayan tayar karate. heey ekte tantra renunchya vividh prakaransathi, visheshtah jeey sahajpane protonet kelele kinwa deprotonate kelele naheet tyanchyasathi atyant karyaksham nahee. namune purnapane aayanikaran karnyasathi, dopant renu madat karane aavashyak aahe. vayoo dravak photoaayankaranatun dekhil jaau shakato aanee namuna renunchya aayanikaranasathi madhyavarti mhanoon karya karoo shakato. ekada dopant aayan tayar jhaale qee, namunyasah proton hastantaran houu shakate, jyamule adhik namuna aayan tayar hotat. tyanantar aayan vishleshanasathi vastuman vishleshkankade pathavale jaatat.
aayanikaran yantrana.
prushthbhagachya jalad ushnatemule aushnik shoshanachi yantrana hii dappimadhil mukhya shoshak yantrana aahe. tyamule, dappi keval qamee aushnik chalakata asalelya prushthbhagansathi changle karya karate. aayanikaran yantrana vaparlelya vishleshanatmak aanee dravkavar avalambun asate. udaharanarth, khaleel vishleshanatmak (m) aayan tayar houu shakatatah [m + h] +, [m-h] −, m +;, m −.
ghatak bhoomitiche prakar.
paravartan bhoomiti.
dappichi samanya kinwa paramparik bhoomiti manali jaanari hii paddhat, konatyahi purvichya tayarichi aavashyakta nasalelya ghan namunyansathi aadarsh aahe. microchip ms inletla samantar aahe. microchip heaterche uddisht formula _ 2 varr namune marane heey aahe. uv diwa thet namunyachya varr asato aanee too tayar jhalelya shoshalelya renunshi sanvad sadhanyasathi photon sodato. paramparik paddhat samanyatah nebulizer vayusathi uchch taap shakti aanee vayoo pravah darr vaparte, tarr tantradarmyan vaparlya jaanarya dopantche praman dekhil vadhavate. yaa vadhinmule uchch parshvabhoomicha aavaj, vishleshanatmak hastakshep, thurr ashuddhata aanee atirikt dopant aayanpasoon adhik aayan pratikriya houu shakatat.
pareshan bhoomiti.
hii paddhat dravachya namunyanche vishleshan karnyasathi vishesh aahe, jyamadhye pratibimb bhoomitimadhye namuna platechya jaagi dhatoo kinwa polymer jaali aahe. jaali heey nebulizer microchip aanee maas speek inletmadhun sootra _ 3 varr aadharit aahe, diwa jyaa bhagat jaali navyane shoshalele renu sodate tyaa bhagat photon nirdeshit karato. dopant waf aanee nebulizer vayoo heey donhi jaalidware nirdeshit kele jaat asalyane vishleshanatmak vayoo ushnatene shoshala jaato. asey disun aale aahe qee qamee ghanata aanee arund dhage asalelya poladachya jaalimule adhik changlya signalchi tivrata nirman hote. yaa prakarchya jaalimule prushthbhagavar mothe chhidra nirman hote aanee dhage jalad garam hotat. pareshan paddhatimadhye qamee microchip heating powercha vapar keela jaato, jyamule vareel paravartan bhoomitimadhye bhoomitimadhye qamee signal aavajasah kahee samasya door hotat. hii paddhat lahan dhruviy nasalelya sanyuganche ess/aine gunottar dekhil sudharu shakate.
upkaran jodani.
vegale karanyachi tantre.
patal thurr chromatography (tii. ell. see.) heey eka sope pruthakkaran tantra aahe jeey lipids olakhanyasathi dappy-emm. ess. saha jodale jaau shakate. vegale aanee aayanikaran jhalele kahee lipidsmadhye collesterol, tricylglycerols, 1,2-dial diaster, menache ester, hydrocarbons aanee collesterol ester yancha samavesh hoto. tii. ell. see. samanyatah nirvat kinwa vatavaraniy dabatil upkaranansah jodale jaate, parantu nirvat daab adhik asthir sanyugansathi qamee sanvedansheelata deto aanee nirvat kakshanmadhye tyache kshetra qamee asate. tatasth aanee dhruviy nasalelya sanyuganna aayanikaran karnyachya kshamatesathi dappycha vapar keela jaat asey aanee lipid shodhanyasathi hii eka jalad aanee karyaksham paddhat asalyache disun aale kaaran tee aine. pii.-tii. ell. see. aanee etch. pii. tii. ell. see. yaa donhi plates jodali gelee hotee.
lesar desorption samanyatah matrixchya upasthitit vaparale jaate, jase qee matricks sahayyit lesar desorption aayanikaran (maldie), parantu sanshodhanat vatavaraniy daab paristhitit lesar disopersionchi tantre ektrit karoon ashee paddhat tayar kelee aahe jee matricks kinwa discharge vaparat nahee. hii paddhat lahan sanyuganna madat karnyas saksham aahe aanee shodhanyasathi sakaratmak aanee nakaratmak donhi aayan tayar karate. pareshan bhoomiti hii kiran mhanoon ghetali jaate aanee favaranila sootra _ 3 anglever jodalelya msmadhe margadarshan kele jaate. abhyasatoon farnacine, squalin, tetradecahydroenthrointhe, 5-alfa collestein, perilyn, benzoperillin, coronan, tetradecilprin, dodecil sulphide, benzodefinaline sulphide, diabenzosuberone, carbazole aanee ellipticin yasarkhya sendriya sanyugancha shodh lagla aahe. shale teel aanee sugandhyukt kahee lahan nitrogen shodhanyasathi hii paddhat maas spectroscopy tantra, eff. tii. see. aar. saha jodali gelyache dekhil disun aale.
maas spectrometry.
forier transform aayan cyclotron resonance (eff. tii. see. aar.) heey eka tantra aahe jeey samanyatah electrospre aayanikaran (eae. ess. aay.), desi kinwa darts jodale jaate, jyamule dhruviy sanyuge shodhata yetat. dappimule dhruviyatechi vistrut shreni aanee aanvik vajananchi shreni shodhata yete. vegale naan karata kinwa namuna tayar naan karata, dappi oka bayochar sarkhya sanyuganna aushnikaritya nasht karnyas saksham aahe. abhyasat dappichya samasyecha hawala denyat aala. jarr namuna eksandh nasel, tarr tatasth aayan keval prushthbhagache aayanikaran kartil, jeey padarthasathi achook shodh pradan karat naheet. eff. tii. see. aar. chey scanning uchch resolutions jatil sanyuge shodhanyas anumati dete, jyamule moolbhut rachaneche vishleshan karanyachi kshamata nirman hote.
anuprayog.
dappi donhi dhruvanche vishleshan karoo shakato (udaa.jee. verapamil) aanee nonpolar (udaa.jee. anthracin) sanyuge. yaa tantrachi shodhanyachi kamal maryada 600 dii. aii. aahe. desorption electrostre aayanikaran (desi) chya tulanet, jaivik matrixdware dappy dooshit honyachi shakyata qamee asate. pratyaksh vishleshan (dart) sarkhya lokpriy tantranpeksha dappi adhik sanvedanshil asalyache aanee tyat parshvabhoomicha aavaj qamee asalyache dekhil disun aale. avaidh aushadhanchya thet vishleshanavarhi dappichi kamgiri darshavili gelee aahe. itar upayoganmadhye lipid shodhane aanee aushadh vishleshan namune ghene yancha samavesh hoto. orbitrap maas spectroscopidware jodani prakriyedvare lipids shodhale jaau shakatat. aushadhe aanee aerosol sanyuganchya vishleshanasathi drav rangsutra aanee vayoo rangsutra maas spectroscopies jodpyasathi dekhil dappi olakhale jaate. polycyclic sugandhit hydrocarbons (paah) aanee kitakanashake yasarkhi paryavaranatil aanee annatil hanikarak sendriya sanyuge shodhanyasathi dappicha vapar kuthe keela gela aahe heey dekhil abhyasatoon disun aale aahe.

