
glucobracicin

glucobracicin haah eka prakarcha glucosinolate aahe joou jawaljawal serve cruciferous vanaspatinmadhye aadhalato, jase qee cabages, broccolly, mohari aanee vode. itar glucosinoletschya babatit, myrosinase yaa enzymechya hasamule isotheocyanate, indol-3-almethylisotheocyanate tayar hone apekshit aahe. tathapi, heey vishisht isotheocyanate atyant asthir asanyachi apeksha aahe aanee teey kharokhar kadhich sapadale nahee. jevha myrosinejdware vegale kelele glucobracicin apghatan hote tevha indol-3-carbinol aanee theocyanate aayan (adhik glucose, sulfate aanee hydrogen aayan) hii nirikshan keleli jalvichhedan utpadane aahet, jee panyasobat asthir isotheocyanetchya jalad pratikriyemule udbhavtat ashee kalpana kelee jaate. tathapi, itar pratikriya utpadane mothya sankhyene dnyat aahet aanee jevha pikanchya piloon takalelya uutinmadhye kinwa akhand vanaspatinmadhye glucosinoletche vighatan hote tevha indol-3-carbinol heey pramukh ksharan utpadan nasate.
glucobracicin heey lahan pandhare ('pieris rappay') aanee mothe pandhare ('pieris brassisi') yasarkhya godya bhajyachya pandhya fulpakharanche atyant sakriy undy ghalanare uttejak mhanoon dekhil olakhale jaate.
glucobracicin anek vyutpann dnyat aahet. sanyug swatach pratham 'brasika' vanaspatinpasun vegale kele gele, mhanoon yaa navacha shevat jhaala. jevha dusare, tatsam naisargik utpadan sapadale, tevha tyala neoglucobracicin asey naav denyat aale. jevha aanakhi vyutpann sapadale, tevha adhik paddhatshir namkaran vaparale gele. sadhya, vanaspatinmadhun khaleel sahaa vyutpann dnyat aaheth
pratham namood kelele teen vyutpann heey crucifermadhye glucobracicinpramanech varanvar aadhaltat. atirikt teen vyutpann nisargat durmil asalyache disate. 4-methoxyglucobracin haah jivanu aanee burshi yampasoon vanaspatinchya sanrakshanat guntalela sanket renu asalyache alikadech nondavale gele.
tryptophanepasoon honare jaivasanshleshan.
glucobracicin jaivasanshleshan, chorismic acid yaa shikimik acid pathve sanyugatoon anek payyandvare tayar jhalelya tryptophanepasoon suru hote. cytochrome pii450 enzymesdware (anavashyak sayyap92bii3 aanee "arabidopsis thaliana" madheel sayyap79bii3) naduff aanee aanvik oxygencha vapar karoon tryptophane indol-3-acetaldoxim (aay. aii. oo. ess.) rupantar kele jaate. eka swatantra pii450 enzyme ('arabidopsis' madheel sayyap83bii1) prastavit madhyavarti 1-'aci'-naitro-2-indolil-ethane tayar karnyasathi tyanantarchya dusya monoxygeness pratikriyes utprerit karate. sanyugman prakriyet glutathione-transferage (jee. ess. tii.) dware systeincha vapar karoon 'ess'-alchyltheohydroximate vyutpann tayar kele jaate, jeey nantar carbon-sulfur layasdware (jase qee 'arabidopsis' madhye aadhalanaya suur 1 enzyme) vighatit kele jaate aanee mukt thayol tayar kele jaate. eka glucosylation heey thiother linkejdware indol hydroximateshy glucose renu jodatana hote. shevati, hydroximate swatach sulfated houn glucobracicin tayar hote.