
cycloalkine

sendriya rasayanshastrat, cycloalkine heey alkine () chey chakriy pratirup aahe. cycloalkinemadhye eka kinwa adhik tiheri bandh asalele carbon anoonche bund vartul asate. alkine ekkachya resheey swarupamule cycloalkinesche eka samanya sootra asate, cycloalchines atyant tanale jaau shakatat aanee jevha ringmadhil carbon anoonchi sankhya hii bhoomiti samavoon ghenyasathi aavashyak lavchikta pradan karnyasathi pureshi asel tevhach astitvat asoo shakatat. mothya alkineyukt carbocycles aksharshah aniyantrit asoo shakatat, tarr renunchya yaa vargachya sarvat lahan ghatakanmadhye itka taana yeu shakato qee tyanche adyap prayogik nirikshan kele gele nahee. cyclooctine () hii sarvat lahan cycloalkine aahe jee eka sthir sanyug mhanoon vegale aanee sathavali jaau shakate. asey asoonahi, itar sendriya renunshi pratikriya karoon kinwa sankraman dhatunmadhye guntaguntidware lahan cycloalchines tayar kele jaau shakatat aanee adakavale jaau shakatat.
parshvabhoomi.
karyakshamatene ladalelya lakshaniy bhaumitik nirbandhanmule, cyclodesine () peksha lahan cycloalchinemule atyant tanalelya sanrachana nirman hotat. cycloni () aanee cyclooctine () heey vegale karata yenyajoge (jaree jordar pratikriyashil asale taree) sanyuge aahet, cycloheptine (), cyclohexine () aanee cyclopentine () heey keval kshanik pratikriya madhyasth mhanoon kinwa dhatuchya kendrashi samanvay sadhanare legands mhanoon astitvat aahet. cyclobutine legands ausmiyam complexche vilgikaran nondavnanya abhyasanvyatirikt, cyclobutine () kinwa cyclopropine () chya astitvache samarthan karnare thode prayogik purave aahet. saat, sahaa aanee paach sadasyanchya cycloalkineschi kshanik madhyasthata darshavina prarambhik abhyasanmadhye, anukrame dials-ulder kinwa diazoalcane 1,3-diapolar cyclolodition utpadane tayar karnyasathi chakriy diance kinwa diazo sanyuge yasarkhya yogya pratikriya bhagidarasah uchch-urja alkinechya adakavanyavar avalambun hote. sthir lahan-ring cycloalchines nantar nickel, paladium aanee platinum sarkhya vividh sankraman dhatunsah sankulat vegale kele gele aahet. maryadit krutrim upyogansah rasayanik utsukata dirghkal manali jaat asoonahi, alikadil karyane guntaguntichya naisargik utpadananchya ekoon sanshleshanat aanee jaiv-orthogonal rasayanshastrat tanalelya cycloalkineschi upayuktata darshavili aahe.
coone taana.
cycloalchinemadhil coone taana haah bandh konachya vikrutimule udbhavato joou dahapeksha qamee carbon asalelya ringschya aanvik bhoomitila samavoon ghenyasathi udbhavane aavashyak aahe. cyclonony () aanee cyclococtine () shhee sambandhit taana urja anukrame andaje 2.9 kilo callary/moll aanee 10 kilo callary/moll aahet. yaa vargachya vegale karata yenyajogya ghatkansathi urjetil haah varchya dishene jaanara cull ringchya aakarashi vipareet parasparsambandh asalelya coone tanachya jalad vadhiche soochak aahe. photoelectron spectroscopy vishleshanane asey soochit kele aahe qee lahan chakriy pranalinmadhil alkine bandh heey done gair-apghatansheel π bandhanni banalele asatat-qamee-urja π bandhala lumb asalele eka atyant pratikriyashil tanalele bandh. "bandh konachya 'sis' vakanyamule sarvat qamee vyapalelya aanvik kakshiy urjechi prachand ghat hote, hii eka ghatana aahe jee aanvik kakshiy siddhantachya drushtikonatun tanalelya cycloalkineschya pratikriyashilatesathi jababdar aahe.
sanshleshan.
tanalelya cycloalkineschya sanshleshanasathichya prarambhik prayatnanmadhye asey disun aale qee 1-chloro-cycloalkinemadhun hydrochloric acidche qamee pramanat utpadan kadhoon cycloalchines tayar kele jaau shakatat. ichchit utpadan heey sambandhit ellins pramukh utpadan mhanoon mishran mhanoon midavata yete.
yaa kshetratil pudhil kamacha uddesh saumya pratikriya paristhiti vikasit karane aanee adhik majboot utpadan nirman karane haah hota. avanchhit eleanchya nirmitila talhanyasathi, erine nirmitisathi kobayashi paddhat cycloalkineschya sanshleshanasathi sweekarli gelee.
agadi alikade, fujitane tanalelya cycloalchines tayar karnyasathi eka utkrusht paddhat vikasit kelee. yaat vinail iodonium ksharanche bases prerit β-nirmulan samavisht aahe. sakaratmak prabharit iodine prajatinchya majboot electron mage ghenyachya kshamatemule tasech iodoniumchya gatatoon baher padnyachya kshamatemule udbhavananya uchch pratikriyashilatemule vinail iodonium tanalelya cycloalchinesathy visheshtah upayukt krutrim purvavarti asalyache siddha jhaale.
varnan kelelya nirmulan-prakarchya marganvyatirikt, cycloalchines paryachya oxides chakriy biis-hydrazonechya oxidationdware tasech selenadiazolchya aushnik vighatanadvare dekhil prapt kele jaau shakatat.
pratikriya.
tanalelya cycloalchines khulya sakhali alkineschya serve vishisht atirikt pratikriyanmadhun jaau shakatat. chakriy carbon-carbon tiheri bandh sakriy swarupamule, dials-ulder, 1,3-dvidhruvi cycloloadtion aanee halogenation yasarkhya anek alkine jode-prakarchya pratikriya atishay saumya paristhiticha vapar karoon kelya jaau shakatat aanee utprerakanchya anupasthitit varanvar gair-chakriy pranalitil parivartanala gatee denyasathi aavashyak asatat. alkine pratikriyashilatevyatir, cycloalchines anek adviteey, krutrimadrushtya upayukt parivartan ghadavun aananyas saksham aahet.
cyclohexine ring antarbhut karane.
chakriy keatonesmadhye cyclohexine ring incersion hii pratikriyashilatechi eka visheshtah manoranjak paddhat aahe. pratikriya hii pratikriyatmak cycloalkine prajatichya alcoxide-madhyasthi nirmitidvare suru kelee jaate, tyanantar sambandhit annolet midvinyasathi keatoneche α-deprotonation hote. tyanantar donhi sanyuge aupcharik [2 + 2]-photocyclodationmadhun jaatat, jyamule atyant asthir cyclobutanolate madhyavarti utpann hote, jeey sahajpane inon utpadanat vighatit hote.
yaa abhikriyecha vapar carreeachya gwanacastappins oo aanee enchya ekoon sanshleshanatil pramukh payari mhanoon keela gela. yamule 5-7-6 ring pranalichya soyiskar bandhkamas parvanagi midali aanee tyanantarchya karyatmakatesathi upayukt krutrim handle pradan kele.
cyclooctines tambe-mukt click pratikriya.
cyclooctine, sarvat lahan vegale karata yenyajoga cycloalkine, tanamule tambe (i) utprerak naslyamule saumya, sharirik paristhitit azide-alkine hyujan cyclooditionla samore jaanyas saksham aahe. yaa pratikriyecha jiwant peshi pratimesathi jaiv-orthogonal parivartan mhanoon vyapak vapar aadhalala aahe. jaree pratikriyecha saumya, tambe-utprerit prakar, resheey alkines kuak (tambe-utprerit azide-alkine cycloadition) dnyat asala, taree tambya-mukt pratikriyecha vikas lakshaniy hota kaaran tyane vishari dhatoo utprerakchi garaj door kartana sopee pratikriya pradan kelee.