
fermi anunad

fermi anunad mhanje infrared kinwa raman spectrummadhye shoshan pattyanchya urjeche aanee tivrateche sthanantaran. haah quantum-yantrik tarangkaryachya mishranacha parinam aahe. italian bhautikshastradnya enrico fermi yanni yaa ghataneche spashtikaran dile.
nivadiche niyam aanee ghatana.
fermi anunad honyasathi done atty purn kelya pahijetah
jarr teey urjemadhye jawaljawal yogayogane asateel tarr fermi anunad bahutekda moolbhut aanee overtone uttejana darmyan hoto.
fermi anunadamule done parinam hotat. pratham, uchch-urja mode uchch urjekade valato aanee qamee-urja mode ajunahi qamee urjekade valato. dusare mhanje, kamkuvat modchi tivrata vadhate (adhik parvanagi milate) aanee adhik tivra bandchi tivrata qamee hote. donhi sankramananche varnan mool paddhatinche resheey sanyojan mhanoon karata yete. fermi anunadamule varnapatat atirikt pattya nirman hott naheet, tarr anyatha astitvat asalelya pattyanmadhye badal hotat.
udaharane.
keaton.
bahutek keatonesche uchch-resolution asalele ir spectravarun asey disun yete qee "carbonyl band" heey duherimadhye vibhagale gele aahe. shikhar vibhajan sahasa fakt kahee seey. mea.-1 asate. heey vibhajan νco chya mishranamule aanee hch vakanyachya paddhatinchya overtonemule udbhavate.
see. oo. 2.
carbon dioxidemadhye, vakananya companala ν2 (667 seey. mea. −1) samamiti πu asate. ν2 chee pahili uttejit sthitee 0110 darshavili jaate (ν1 modmadhye konatihi uttejana nahee (samamiteey taana), ν2 vakanyachya modmadhye ±1 chya barobarichya aanvik akshabaddal koneey gatisah uttejanache eka praman, ν3 modmadhye konatihi uttejana nahee (asamamiteey taana) aanee aparivartaniy pratinidhitva πu nusar spashtapane rupantarit hote. done kwanta ν2 modmadhye thevalyane samamitiche ghatak (πu × πu) + = σ + g + δg asalelya avasthekade jaatat. hyanna anukrame 0200 aanee 0220 mhanatat. 0200 chee samaan samamiti (σ + g) aahe aanee 100 darshavilelya v1 chya pahilya uttejit sthitishi khoop samaan urja aahe (ν1 samamiteey taana modmadhye uttejanache eka praman, ν2 modmadhye uttejana nahee, ν3 modmadhye uttejana nahee). 100 chee ganana keleli aniyantrit varanvarta 1337 semee−1 aahe aanee, susangatatekade durlaksh karoon, 0200 chee varanvarta 1334 semee−1 aahe, jee 110 chya 667 semee−1 chya duppat aahe. 0200 aanee 100 yaa avastha tyamule misaloo shakatat, vibhajan nirman karoo shakatat aanee 0200 sankramanachya tivratet lakshaniy vaadh dekhil karoo shakatat, jenekarun 0200 aanee 100 yaa donhi sankramananchi tivrata samaan asel.