
tetreithyl pyrophosphate

tetreithyl pyrophosphate, sankshipt rupat tape, heey sootra asalele organophosphate sanyug aahe. heey pyrophosphate (pii2oo74-) tetreithyl vyutpann aahe. heey rangheen teel aahe jeey samanya tapmanachya jawal ghatt hote. yacha vapar kitaknashak mhanoon keela jaato. sanyug jalvishleshan vegane hote.
anuprayog.
tape heey affids, sukshmajiv, kolee, melibugs, leafhoppers, lygus bugs, thrips, leaf minors aanee itar anek kitkansathi kitaknashak aahe. tape aanee itar organophosphate hii yuu. aii. madhye sarvadhik vaparali jaanari kitakanashake aahet.ess. tyanchya parinamkaraktemule aanee paryavaranavar sapekshapane qamee parinam jhalyamule heey organophosphate itake sahajpane vighatit hote.
mysthenia gravis yaa svayampratikar rogachya upcharasathi tepcha vapar keela gela aahe. upcharamule shakti vadhel.
sanshleshan.
dii clermont aanee moshnin yanni kelele sanshleshan alekzandar williamson (joou etherchya williamson-sanshleshanasathi prasiddha aahe) yanchya aadhichya karyavar aadharit hote. tyanchya sanshleshanat ethyl iodide aanee chandichya ksharancha vapar karoon pyrophosphate sanyogane ester tayar kele gele. 
tepasathiche vyavsayik marg anekada schredder, lakud aanee khelanyanni vikasit kelelya paddhatincha vapar karatat. triathyl phosphet phosphorus oxychloride (scredder-methad) kinwa phosphorus pentoxide (woodstock-methad) saha abhikriya karate. vaikalpikaritya, diethyl phosphorochloridate niyantrit jalvichhedan sanyug vitareet karateh
sambandhit tetrabenzylphyrophosphate diabenzylphosphoric aesidchya nirjalikaranadware tayar kele jaateh
jalvichhedan.
tape aanee itar bahutek organophosphate heey jalvichhedanas sanvedanshil asatat. diethyl phosphet heey utpadan aahe.
visharipana.
tape heey acetylcholinesteres avarodhak mhanoon jaiv sakriy aahe. heey sakriy thikani serine hydroxyl gatasobat pratikriya dete, jyamule heey enzyme tyachya samanya tharavar, neurotransmitter acetyl kolinavar karya karnyapasoon rokhate.
tape heey manavansah serve ubdar raktachya pranyansathi atyant vishari aahe. prayogshaletil abhyasadarmyan yaa pranyanvar teen prakarche parinam samore aale aahet.
mrutyu haah mukhytah ektar shwasankriya bund padalyamule aanee kahee prakarananmadhye hrudayavikarachya zatkyamule hoto. shoshan marg haah vishisht pranalinvar honanya parinamachya shrenisathi jababdar asoo shakato.
sheet rakt asalelya pranyansathi parinam thode vegale asatat. bedkanchya abhyasat, tivra samparkat aalyane raktatil erythrocytes pramanat nairashya aale. pandhya raktpeshinmadhye, visheshtah neutrophil granulocytes aanee lymphocytesmadhyehi ghat jhaali. rakt peshinchya haniche spashtikaran denyasathi raktavahinyanna konatehi drishyaman nuksan jhaale nahee. pudhe, hypotoniamule ardhangvayu jhaala asala taree, ubdar rakt asalelya pranyanpramane atisardrata kinwa ashru yasarkhi konatihi chinhe navhati.
itihas.
1854 madhye vladimir moshninane edolph woortzs kaam kartana tyache pratham sanshleshan kele. done prakashananmadhye moshninchya pramukhatechi manyata asoonahi, sahkari vidyarthi phillip dii clermontla anekada tepcha shodh lavnara mhanoon chukiche shrey dile jaate. 
tepchya sambhavya visharipanabaddalachya adnyanacha purava swatah dii clermont yanni deela aahe, jyanni tepchya chaviche varnan jalanari chav aanee eka vichitra gandh asalyache kele aahe, jaree tyanantarchya varshanmadhye itar rasayanshastradnyanni tepche varanvar sanshleshan kele asale taree 1930 chya dashkaparyant konatehi pratikool parinam disun aale navhate. yavyatirikt, phillip dii clermont vayachya 90 vya varshi tyachya nidhanaparyant tyachya kutumbane kadhihi aajari padalyachi nond keleli nahee. darmyan, organophosphorus rasayanshastra kharokharach eka vyaktichya madatine vikasit houu lagale aahe. doubleu. wonn hoffman, carl arnold august michaelis aanee elexander arbuzov.
tape sarkhya sanyuganche pahile pratikool parinam 1932 paryant olakhale gele navhate. viilii lang aanee gerda wonn krugger yanni asha parinamancha ahwal denare pahile hote, jyabaddal tyanche nivedan (germanmadhye) khaleel lekhat prakashit karnyat aale hoteh
"manoranjak baab mhanje, aamhi monofluorophosphate phosphoric acid alkyle estercha manvi jivanavar honara tivra parinam nondavato. yaa sanyuganchya vafecha gandh sukhad aanee tivra sugandhi asato. waf aat ghetalyanantar kahee minitannantar, swarayantravar tivra daab yeto, joou shwas ghenyas tras honyashi sambandhit asato. tyanantar jagrukta, apardarshakta aanee chamkana ghatana qamee hotat jyamule dolhyachi prakashaprati vednadayak sanvedansheelata nirman hote. kahee tasannantarch yaa ghatananpasun aaram midato. teey esterchya aamleey vighatan utpadananmule hott naheet, parantu teey bahudha dialkill monofluorophosphatemule aahet. parinam atishay qamee pramanat hotat."
1935 pasoon german sarkarne naveen vishari padarthambaddal mahitee gola karnyas suruvat kelee, jyapaiki kahinche german sanrakshn mantralayane gupt mhanoon vargikaran kele hote. organophosphorus kitakanashake aanee majjatantu vayunvaril abhyasasathi prasiddha jhalele gerhard schredder heey tepcha abhyas karananya rasayanshastradnyanpaiki eka hote. tyanchya abhyasat, visheshtah jaivik pailoonvaril tyanchya abhyasat, tyanchya lakshat aale qee yaa abhikarmakacha vapar kitaknashak mhanoon keela jaau shakato. yamule vyavsayik companyansathi gupt mhanoon sanchache vargikaran karane gairsoyiche tharel.
dusya mahayuddhachya suruvatichya sumaras, tape haah collinesterescha avarodhak asalyache aadhalun aale. schredder yanni eberhard gross yanchya abhyasacha sandarbh deela, jyanni 1939 madhye tepsathi krutichi yantrana olakhali. hans gremels adhik prayog kele gele, jyanni grosschya kamachi pushti kelee. tyaa velee majjatantu vayunchya vikasat gremels dekhil sameel hote. tyanchya abhyasat pranyanchya anek prajati aanee manvi svayamsevak yancha samavesh hota. tyach sumaras, tepchya anticholinesteres kriyakalapansathi sambhavya aushadh mhanoon atropinecha shodh lagla.
dusya mahayuddhanantar, itarambarobarach ingraji shastradnyanni chaukashi kelelya anek german shastradnyanmadhye schredder haah eka hota. yuddhadarmyan, ingraj aaplya shatrunna aashcharyachakit karnyasathi swatachi rasayanik shastre vikasit karat hote. yaa chaukashit tape aanee itar kitakanashakanche astitva ughad jhaale. cheta vayunche astitva, matra shredardware dekhil ughad kele jaat hote, heey lashkarane gupt thewale hote.