organomanganese rasayanshastra

organomanganese rasayanshastra heey carbon teey manganese rasayanik bandh asalele organometallic sanyuganche rasayanshastra aahe. 2009 chya punaravalokanat, chiez aanee itar. manganese swast aanee saumya asalyane (keval loh yaa pailunmadhye adhik changli kamgiri karate), organomanganese sanyuganmadhye rasayanik abhikarmak mhanoon kshamata aahe, jaree sadhya vyapak sanshodhan karoonahi tyancha mothya pramanat vapar keela jaat nahee, assa yuktivad keela.
sanshleshan.
organomanganese sanyuge pahilyanda 1937 madhye gillman aanee bellie yanni nondavali hotee, jyanni phenylithium aanee manganese (2) iodidechya fenilmanganese iodide (ph. emm. aine. aay.) aanee diaphenylmanganies (ph. 2. emm. aine.) tayar karnyachya abhikriyeche varnan kele hote.
yaa udaharananantar, manganese (2) chloride, manganese (2) bromide aanee manganese (2) iodidechya alkayaleshandware itar organomanganese halides prapt kele jaau shakatat. manganese iodide aakarshak aahe kaaran nirjal sanyug manganese aanee aayodeenpasun ethermadhye tayar kele jaau shakate. organolithium kinwa organomagnesium sanyuge heey vishisht alkylating ghatak aaheth
vividh prakarche organomangnets (khalle gelele complexes) vegale karata yenyajoge aaheth
jaree tyapaiki anek qamee tapmanat hatalale jaane aavashyak asale taree organomanganese sanyuge samanyatah tii. etch. eff. madhye tayar kelee jaatat jithe tee sarvat sthir asatat (guntaguntidware). beeta-hydride nirmulan karoon sadhya dialkillmanganies sanyuge alken aanee alkinchya mishranat vighatit hotat.
emm. aine. 2 (qoo) 10 chey vyutpann.
anek organomanganese sankule diamanganese decacarbonyl, emm. aine. 2 (qoo) 10 pasoon tayar kelee jaatat. lithiums bromination aanee qamee kelyane brummon (qoo) 5 aanee liman (qoo) 5, aadarpurvak milate. yaa prajati alkyle, eril aanee esile derivativeschya purvavarti aaheth
pratikriyashilatecha samanya namuna adhik lokpriy cyclopentadianiliron dicarbonyl diamerchya samaan aahe.
emm. aine. (aay) sanyug bii. aar. emm. aine. (qoo) 5 heey anek paay-arine sankulanche purvavarti dekhil aaheh
hii catanic ardh-sandwich sankule cyclohexadinil derivatives aanee ultimated functionalised erenus denyasathi nucleophilic jodanisathi sanvedanshil asatat.
pratikriya.
emm. aine. (2)-see. bandhanchya uchch ionic varnanmule emm. aine. (2) chya organometallic sanyuganche rasayanshastra sankraman dhatunmadhye asamanya aahe. organomanganese sanyuganchya pratikriyashilatechi tulana organomagnesium aanee organosinc sanyuganshi kelee jaau shakate. emm. aine. (1.55) chee vidyut runatmakata hii mii. gra. (1.31) aanee zed. aine. (1.65) shhee tulana karata yete, jyamule carbon anoo (aine = 2.55) nucleophilic hoto. emm. aine. chee qamee karanyachi kshamata dekhil mii. gra. aanee zed. aine. darmyan madhyavarti asate. 
organomanganese halides alcoholmadhye aldehydes aanee keatones pratikriya detat, carbon dioxide carboxylic aesidmadhye (sambandhit aar. ell. aay. kinwa aar. emm. jee. bii. aar. samakakshanpeksha uchch karyarat tapman sahan karate), sulfur dioxide aanee isocyanates mauu grignard abhikarmakansarkhe vartan karatat. teey ester, nitrile kinwa amides pratikriya dett naheet. teey electronic prabhavanpeksha steriksathi adhik sanvedanshil asatat. 
esile halides aar. emm. aine. ex. sanyuge sambandhit keatones tayar karatat. hii pratikriya rasayanik nivadak aahe aanee yaa karanastav sendriya sanshleshanat vaparali gelee aahe.
aahe prakarchya kahee manganese amidescha vapar manganese anolets tayar tayar keatoneschya apbhranshasathi keela jaato. lithiyam anoletspramanech teey silil chlorides silil inol etherwar, alfa-alkylationmadhye alkyle halides aanee beeta-keto-alcoholmadhye aldehydes aanee keatones pratikriya deu shakatat. manganese hyalidesche lii, migra, keey kinwa naa anolets transmatelation karoon dekhil manganese anolets midavata yetat.
manganese halides heey stannence aanee grignardscha samavesh asalelya anek samalingi aanee cross coupling pratikriyanmadhye utprerak aahet jyamadhye organomanganese madhyavarti ghatak bhoomika bajavtat. tyachpramane organomanganese halidescha samavesh asalelya jodani pratikriyanche utpreran peedi, nee, kyu aanee ephai sanyuganni kele jaate.
manganese chloride haah sendriya rasayanshastratil organomanganese abhikarmakancha purvavarti aahe.
sakriy manganese.
vyavsayik manganese puud hii organomanganese sanyuganchya sanshleshanasathi yogya nahee. 1996 madhye rikene nirjal manganeejchya abhikriyedvare prapt sakriy manganese (rike dhatoo pahaa) sadar kele (2) chloride lithiyam dhatusah tii. etch. eff. madheel nafthaleenchya utprerak pramanachya dravanat. potassium graphite aanee magneshiyam heey itar qamee karnare ghatak aahet. sakriy manganese barbier abhikriyechi emm. aine. aavrutti aanee pinacol jodani sulabh karate.
uchch-moolya sanyuge.
sanyojakta + 3 kinwa + 4 asaleli anek organomanganese sanyuge dnyat aahet. shodhanyat aalela pahila (1972) chaar norbornil ekkansah emm. aine. (norr) 4 hota. 1992 madhye eka ashtatal mn (iv) (m) 6−2 sankul nondavale gele, jeey mnme4 (pme3) chya abhikriyedvare prapt jhaale, tyanantar methylithium aanee nantar tmed jodale gele.

