
thermodynamic maryada

sankhyikeey yantrikimadhye, pranalichi thermodynamic maryada kinwa macroscopic maryada hii mothya sankhyene kananchi maryada asate (udaa.jee.anoo kinwa renu) jethe kananchya sankhyechya pramanat aakarman vadhanyasathi ghetale jaate.
thermodynamic maryada hii mothya aakarmanasah, kananchi ghanata nishchit thevun, pranalichi maryada mhanoon paribhashit kelee jaate.
yaa maryadet, sthool ushmagatiki vaidh aahe. tethe, jaagtik pramananmadhil aushnik chadhautar nagany aahet aanee dabav aanee urja yasarkhya serve ushmagatikiy matra, keval tapman aanee ghanata yasarkhya ushmagatikiy chalanchi karye aahet. udaharanarth, mothya pramanatil vayusathi, ekoon antargat urjetil chadhautar nagany asatat aanee tyakade durlaksh kele jaau shakate aanee vayuchya daab aanee tapmanachya dnyanavarun sarasari antargat urjecha andaj lavala jaau shakato.
lakshat ghya qee serve prakarche aushnik chadhautar ushmagatikiy maryadet nahise hott naheet-keval pranalichya chalanmadhil chadhautar mahattvache nasatat.
ajunahi kahee bhautikdrushtya nirikshan karnyayogya pramanat (samanyatah sookshm pramananvar) shodhanyayogya chadhautar asateel, jase qee
thermodynamic maryadecha vichar kartana ganitiyadrushtya eka asymptotic vishleshan kele jaate.
thermodynamic maryadeche kaaran.
thermodynamic maryada hii moolatah sambhavyata siddhantachya kendriya maryada siddhantacha parinam aahe. aine" renunchya vayuchi antargat urja hii kram "aine" yogdanachi berries aahe, jyapaiki pratyek andaje swatantra aahe aanee mhanoon kendriya maryada pramey assa andaj lavto qee chadhautaranchya aakarache sarasarichya aakarache gunottar 1/"aine" 1/2 kramankache aahe. asha prakare macroscopic volumesathi kadachit renunchya avogadro sankhyes, chadhautar nagany asatat aanee tyamule thermodynamics karya karate. sarvasadharanpane, vayoo, drav aanee ghanpadarthanche jawaljawal serve sthool praman heey ushmagatikiy maryadet asalyache manale jaau shakate.
lahan sookshm pranalisathi, vividh sankhyikeey samooh (sookshm-dhwanik, adhikrut, bhavya pramanit) vegvegalya vartanans parvanagi detat. udaharanarth, canonical samoohamadhye pranalitil kananchi sankhya nishchit thewali jaate, tarr kananchi sankhya bhavya canonical samoohat chadh-utaar karoo shakate. thermodynamic maryadet, heey jaagtik chadhautar mahattvache nasatat.
thermodynamic maryadevarach sthuldarshak "vistrut" chalanchya jodanichya gunadharmanche palan kele jaate. mhanjech, done pranali kinwa vastunchi (tyanchi urja aanee aakarmanachya vyatirikt) ektrit keleli entropy hii done vegvegalya mulyanchi berries aahe. sankhyikeey yantrikichya kahee namunyanmadhye, ushmagatikiy maryada astitvat aahe, parantu seema atinvar avalambun asate. udaharanarth, heey sahaa shirobindu modelmadhye ghadateh niyatkalik seema paristhitisathi aanee kshetra bhint seema paristhitisathi bulk free energy vegali asate.
jyaa prakarananmadhye thermodynamic maryada nasate.
serve prakarananmadhye thermodynamic maryada astitvat nasate. samanyatah, kansankhyechi ghanata sthir thevat kansankhyesah aakarman vadhavun namuna thermodynamic maryadeparyant nele jaate. done samanya niyamitkaran mhanje chaukatiche niyamitkaran, jethe padarth haah bhaumitik chaukatipurata maryadit asato aanee niyatkalik niyamitkaran, jethe padarth sapat torruschya prushthbhagavar thewala jaato (i.eae. niyatkalik seema attins boxes). tathapi, khaleel teen udaharane ashee prakarane darshavtat jithe yaa drushtikonanmule ushmagatikiy maryada nirman hott naheeh