stelacianin

stelacianin haah nila kinwa prakar I tambe prathine kutumbatil sadasya aahe. tambyachya prathinanche heey kutumb samanyatah electron hastantaran pratikriyanmadhye guntalele asate, jyamadhye kyu kendra oxidised kyu (II) swaroop aanee qamee jhalelya kyu (i) swarupamadhye sankraman karate. raktavahinyanchya biyanyanchya vanaspatinmadhye stelacianin sarvavyapi aahe. 
rachana.
stelacyaninche spectroscopic gunadharm aaplyala teey plastocyaninpasoon vegale karnyas madat karatat, jeey vanaspatinmadhye aadhalanare aanakhi eka monocopper nile prathin aahe. hii eka 20kda prathine aahe, jichi rachana beeta strandspasoon banaleli aahe, jee done beeta sheets tayar karoon badalatya alfa helical sanrachanesah greek qee beeta baryl tayar karate. prathinanche tambyache bandhan kshetra amino-terminal tokavar sthit aahe, tarr carboxyl-terminal toke hydroxyprolyne aanee serine avasheshanni samruddha aahe, jeey vanaspatinchya peshi bhintinshi sambandhit prathinanche vaishishtyapurn aahe. yavyatirikt, teey mothya pramanat glycosylated dekhil aahe. tambyacha samanvay cysteine, 2 hystidine aanee glutamine avasheshadvare keela jaato. glutamine avashesh samanyatah itar nilya tambyachya prathinanmadhye nisargat methionine legandchya jaagi hotat. yavyatirikt, stelacyaninsathiche electron hastantaran darr itar prakarchya aay tambe prathinanpeksha jalad asatat, jeey stelacianin heey sakriy thikani adhik dravak upalabdh asalyache soochit karatat. stelacyaninche achook karya adnyat aahe. tathapi, prakar I tambe prathine electron hastantaranat guntaleli asatat aanee stelacyanin vanaspati peshi bhintishi sambandhit asalyache disate, hii vastusthiti lakshat gheta, asey suchavale jaate qee teey peshi bhint tayar karnyasathi polymeric samagri tayar karnyasathi oxidative cross-linking pratikriyanmadhye sameel aahe. peshibhittichya sanrachanatmak glycoproteinsmadhye hydroxyprolyne aanee serine-samruddha anukram kshetra asatat jeey stelasianinsmadhye aadhaltat. 
stelacianin qamee karanyachi kshamata.
stelacyaninschi vaishishtye tyanchi advitiyapane qamee redox kshamata, + 180 emm. vhee. itaki qamee aanee + 280 emm. vhee. paryant pohochatat. itar nilya tambyachya prathinanchya redox kshamata sumare 310 emm. vhee. pasoon suru hotat aanee + 680 emm. vhee. paryant pohochatat. glutamine aksheey legand (eka legand jyamadhye itar serve nilya prathinanmadhye asate) chya jaagi methionine methionine meater) ghaloon aanee shuddha karoon utparivartit kakadi stelacyanin tayar kele gele. heey polymerase cheen reactiondware (pii. see. aar.) sadhya kele gele. utparivartit stelacyaninchi ganana keleli redox kshamata + 420 emm. vhee. hotee, jee + 260 emm. vhee. varr nisargat nisargat stelacianinchya (methioninshivay) redox kshamatepeksha khoop jaast hotee. sanrakshn pratisadadarmyan pratisadadarmyan vanaspatinchya redox pratikriyanmadhye aanee ligninchya nirmitimadhye stelacyaninscha sarvadhik sahbhag asato. 

