
plutonium hexafluoride

plutonium hexafluoride heey plutoniumche sarvoch fluoride aahe aanee plutoniumchya lesar sanvardhanasathi, visheshtah vikiranit euraniummadhun shuddha plutonium-239chya utpadanasathi, heey swarasyapoorn aahe. plutonium-240 chya utsfurt vikhandanadvare tayar jhalelya neutrondware qamee vastuman asalelya aanvik shastranchya rachaneche akali jwalan talhanyasathi heey shuddha plutonium aavashyak aahe.
tayari.
plutonium hexafluoride heey moolbhut florinsarkhya shaktishali florining ghatkandware plutonium tetrafluoride (puff4) chya florinikaranadware tayar kele jaate.
hii pratikriya endothermic aahe. 750°seey. tapmanat utpadan tulanene lavkar tayar hote aanee utpadan twarit ghanikaran karoon aanee teey samatolatoon kadhoon takoon uchch utpann miloo shakate.
plutonium (3) fluoride, plutonium (4) auxide kinwa plutonium (4) auxletche sumare 700°seey. tapmanat florinikaran karoonahi teey prapt kele jaau shakateh
vaikalpikaritya, plutonium (4) fluoride 800-sase. auxigen vatavaranat plutonium hexafluoride aanee plutonium (4) oxidemadhye auxidise hoteh
1984 madhye, dioxygen diafluoridechya vaparadvare kholichya jawalpasachya tapmanat plutonium hexafluoride sanshleshan sadhya karnyat aale. hydrogen fluoride jaree eka shaktishali floriniting agent asala taree teey purese nahee. crypton defluoride kinwa yuu. vhee. prakashasah vikiran vaparoon kholichya tapmanache sanshleshan dekhil shakya aahe.
malmatta.
bhautik gunadharm.
plutonium hexafluoride heey laal-tapkiri asthir ghan aahe, jeey orthorombic chrystal pranalimadhye space group 'pii. aine. emm. aii.' aanee jaali mapdandansah sfatikikaran karate. teey sumare 60°seey. tapmanat 12.1 kilocallery/moll ushnatesah, plutonium-florin bandh lambichya, 197.1 pii. emm. asalelya ashtatal renunchya vayumadhye utarate. uchch dabavar, vayoo ghanikaran hoto, 51.58 sase. varr tiheri bindusah aanee; vashpikaranachi ushnata 7.4 kilocallery/moll asate. - 180°seey. peksha qamee tapmanat plutonium hexafluoride rangheen asate.
plutonium hexafluoride heey paramagnetic aahe, jyachi daadh chumbakeey sanvedansheelata 0.173 emm. emm. 3/moll aahe.
spectroscopic gunadharm.
plutonium hexafluoride sahaa bhinn dolan paddhati swikarteh taana mode, aanee, aanee firanyachya paddhati, aanee. raman varnapat nirikshanat thevata yet nahee, kaaran 564.1 nmvaril vikiran prakasharasayanik vighatanas pravrutt karate. 532 nmvaril vikiran 1900 nm aanee 4800 nmvar pratidipti prerit karate; 1064 nmvaril vikiran sumare 2300 nmvar pratidipti prerit karate. 
rasayanik gunadharm.
plutonium hexafluoride hatalane tulanene katheen aahe, heey atishay sanksharak, vishari aanee swayam-vikiranshastras pravrutt aahe.
itar sanyugansah pratikriya.
puff6 koradya havet sthir asate, parantu vatavaranatil aadratesah panyashi jordar pratikriya deuun plutonium (vi) auxifluoride aanee hydrophloric acid tayar karate.
jarr aadrateche konatehi khuna nasel, kaach purnapane baheroon vayuyukt keela gela asel aanee sanyugatoon hydrogen fluorideche konatehi khuna kadhoon takale gele asel tarr teey quartz kinwa pyrex empoolmadhye barach kaal sathavale jaau shakate.
plutonium dioxidemadhye ghat hone hii puff6chaa samavesh asaleli eka mahattvachi pratikriya aahe. auxigen-mithen jwaletun nirman honare carbon monoxide qamee karoo shakate.
vighatan pratikriya.
plutonium hexafluoride samanyatah plutonium tetrafluoride aanee florin vayumadhye vighatit hote. aushnik vighatan samanya tapmanat hott nahee, parantu 280°seey. varr khoop vegane pudhe jaate. vighatanasathi konatehi bahya kaaran naslyamule, plutoniumchya kshayamule honara alfa-kann pravah ghan tappyat 1.5%/day (ardha-vel deed mahine) chya darane swayam-vikiranshastra nirman karel. vayoo tappyat daab 50-100 torr (70-130 emm. bii. aar.) varr sathavan svayanchalit-radiolysis qamee karate asey disate aanee mukt florins dirghakalin punarsanyojan hote. 
tyachpramane, sanyug prakashsanvedanshil aahe, 520 nmpeksha qamee tarangalambivar lesar vikiranantargat vighatit (bahudha plutonium pentafluoride aanee florinsathi) hote. 
564.1 nm kinwa gamma kirananvar lesar kiranotsargachya samparkat aalyane dekhil jalad vighatan hoil.
vapar.
plutonium hexafluoride plutoniumchya samruddhimadhye, visheshtah vikhandaniy samasthanik 239 pii. yuu. chya vikiranit uraniumpasoon vilgikaranasathi bhoomika bajavate. anvastranmadhye vaparasathi, upasthit 241piyu done karanansathi kadhoon takane aavashyak aaheh
plutonium aanee americiummadhil vegalepana dioxygen defluoridechya pratikriyedvare pudhe jaato. junya puff4chey samanya tapmanat florinikaran karoon vayuyukt puff6 kele jaate, jeey vegale kele jaate aanee parat puff4madhye qamee kele jaate, tarr upasthit asalelya konatyahi aii. emm. eff. 4chey samaan rupantaran hott nahee. asha prakare utpadanat americiumche praman khoop qamee asate, jeey abhikriya naan kelelya ghanamadhye kendrit hote. 
anoo kachyachya punarprakriyesathi uranium aanee plutoniumche hexafluorides vegale karane dekhil mahattvache aahe. donhi ghatak asalelya vitalalelya mithachya mishranatoon, uranium mothya pramanat florinikaran karoon yuu. eff. 6 paryant kadhale jaau shakate, jeey uchch tapmanat sthir asate, aanee plutoniumche fakt thode praman puff 6 mhanoon baher padate.
itihas.
1940 madhye plutoniumcha shodh aanee vilgikaranantar lagechach, rasayanshastradnyanni plutonium hexafluoride astitva gruheet dharnyas suruvat kelee. uranium hexafluoride nirmitichya paddhatinchi nakkal karnyacha prayatna karananya suruvatichya prayoganche parasparvirodhi parinam disun aale aanee nishchit purave keval 1942 madhye disale. tyanantar dusya mahayuddhane pudhil sanshodhanachya prakashanat vyatyay aanala.
atyant qamee pramanat plutoniums haatee ghetalelya prarambhik prayoganmadhye asey disun aale qee florin vayuchya pravahat 700°seey. peksha jaast tapmanatach asthir plutonium sanyug vikasit hoil. tyanantarchya prayoganmadhye asey disun aale qee tambyachya platevaryl plutonium 500-sase. florin pravahat bashpibhavan jhaale aanee uranium> neptunium> plutonium yaa maliketil anusankhyenusar pratikriya darr qamee jhaala. tapkiri aanee tekadi rangane, plutoniumchya milligram-scale namunyancha vapar karoon, 1942 madhye uranium hexafluorides eka aasavan prayog purn keela, jyamadhye asey suchavale gele qee plutoniumche uchch fluorides asthir asavet aanee samanya tapmanat plutonium tetrafluoridemadhye vighatit hotil. tathapi, sanyugatil vafecha daab uranium hexafluorideshy sambandhit asalyache disun aale. davidson, katz aanee orleman yanni 1943 madhye dakhavun dile qee nickel patratil plutonium florinchya vatavaranakhali bashpibhavan hote aanee pratikriya utpadan platinumchya prushthbhagavar avkshepit hote.
machchimar, vaslo aanee tewebog yanni assa andaj vartavala qee uchch fluorides nirmitichi sakaratmak enthalpy darshavtat, tyanchi nirmiti endothermic asel aanee parinami keval uchch tapmanat sthir hoil.
1944 madhye, plutonium hexafluoride heey durmil manale jaanare plutoniumche asthir sanyug tayar kele, parantu teey utpadan olakh honyapurvi vighatit jhaale. drav padarth thund kelelya kachevar gola hoil aanee dravikrut hoil, parantu nantar fluoride anoo kacheshi pratikriya deteel.
uranium aanee plutonium sanyuge, madyanirmata, bromley, gills aanee lofgren yanchya tulanet plutonium hexafluoride thermodynamic vaishishtye mojali gelee.
1950 madhye, florinchya prayatnanna shevati sanshleshan midale aanee thermodynamic deta sudharla aanee lavkarach tyachya utpadanasathi eka naveen upkaran aale. tyach sumaras, british kamgarannihi puff6chyyaa utpadanasathi eka paddhat vikasit kelee.