moff

moof, jyala oxodiperoxymolybdenam (pyridine)-(hexamythylphosphoric trimide) asehi mhanatat, haah sendriya sanshleshanat vaparla jaanara abhikarmak aahe. tyat pyridine aanee etch. emm. pii. aii. legands samanvayit anek auxigen legands molybdenum (vhee. aay.) kendra asate. haah oxygencha electrophilic srot aahe joou anolets aanee sambandhit sanrachananshi pratikriya deto aanee asha prakare carbonylayukt sanyuganchya alfa-hydroxylationsathy vaparla jaau shakato. inol kinwa annolet sanrachanandware alfa-hydroxylationsathy vaparlya jaanarya itar abhikarmakanmadhye davis oxaziridine, auxigen aanee vividh peroxycidscha samavesh hoto (rubotum auxidation pahaa). yaa abhikarmakacha vapar edwin vedejne 1974 madhye eka karyaksham alfa-hydroxylating agent mhanoon keela aanee nantar 1978 madhye eka prabhavi purvatayari prakriya prakashit karnyat aalee.
sanshleshan.
hydrogen peroxides auxidation karoon aanee etch. emm. pii. aii. aanee pyridine legandschee bharr ghaloon molybdenum trioxidepasoon moofche sanshleshan kele jaateh
pratikriyashilata.
moofchya steric balkmule, oo-oo bandhavar pradhanyacha hallah stereoelectronic ghatakanchya anupasthitit qamee adthala asalelya annolet annolet hoto. 
yavyatirikt, aamleey alfa proton asalelya nitrilesche thet cyanohydrinemadhye rupantar kele jaau shakate; tathapi, shakhayukt nitrileschya babatit, hii pratikriya thet keatonla puravate.
sulphonschya babatit, alfa-hydroxylation thet keaton kinwa eldehydekade jaate.
alfa-hydroxylation samanya upautpadananmadhye prarambhik samgrichya sambandhit dicarbonyl kinwa aantaraanvik eldol pratikriyesathi atiaanvikatecha samavesh hoto. side reaction talhanyasathichya prakriyanmadhye anoletchi moofmadhye ulat jode kinwa tapmanavar kaljipurvak niyantran (-78 teey-20°seey.) samavisht aahe. lakshaniy vividh pratikriyanmadhye, nivval styrio-dharanasah alkilborenche thet alcoholmadhye auksidikaran karanyachi moofchi kshamata samavisht aahe.
moof heey aine-trimethylacylil amidesche thet hydroxamic aesidmadhye auxidation dekhil darshavile gele aahe. 

