ruthenium (III) chloride

ruthenium (iii) chloride ennathu prathyekamaayi "enna soothravaakyamulla raasa samyukthamaanu. ruthenium (iii) chloride" saadhaaranayaayi prathyekamaayi· "x" "x" enna hydratine soochippikkunnu. anhydrus, hydrated enangal irunda thavitt allengil karutha kharapadaarthangalaanu. christalisationte jalathinte vyathyastha anupaathamulla hydrate, palappozhum oru trihydratinode ekadeshamaayi kanakkaakkappedunnu, ithu ruthenium rasathanthrathil saadhaaranayaayi upayogikkunna oru prarambha padaarthamaanu.
thayyaareduppum gunangalum.
podicha ruthenium loham chlorin upayogichu choodaakkiyaanu saadhaaranayaayi anhydrus ruthenium (iii) chloride thayyarakkunnathu. yadhaartha synthesisil, kaarban monoxide saannidyathilaanu chlorination nadathiyathu, uthppannam vathaka pravaham vahikkukayum thanuppikkumbol christalise cheyyukayum cheiyunnu. derivateevukal-yude rund polymorphukal ariyappedunnu. 346 pii. emm. dairkhyamulla ruu-ruu kondaaktukalulla sii. aarr. sii. ell. 3-tharam gadanayaanu karutha α-phoom sweekarikkunnathu. eee polymorphinu nalkunnu + nte thenkoombu paalikal undu, avaykku chuttum klai-ayonukalude octahedral koombaaram undu. undu paalikal durbalamaaya vaan derr walls shakthikalumayi parasparam mukalil adukki vaykkunnu, motham koneeya momentam l = 1 ulla kuranja-spin jeey ~ 1/2 graundu avasthayil thamasikkunna kaanthikamaan ruthenium katteshanukal. scoach tape upayogichu iva pilartthi mono-lairukal roopappeduthaam.
irunda thavitt niratthilulla mettaastabil β-phoom oru shadbhujaakrithiyilulla koshatthil christalise cheiyunnu; syrconium trichloridinte gadanaykku samanamaaya 283 pm ruu-ruu kondaaktukalulla mukham pankidunna ashtathalathinte ananthamaaya shringalakal eee roopathil adangiyirikkunnu. β-phoom 450-600 °C-ll α-roopathilekku maattaanaavaathavidham parivartthanam cheiyunnu. β-roopam diamagnetic aanu, athesamayam α-rucl3 muriyile thapanilayil paragnetic aanu.
uyarnna thapanilayil prathyekamaayi neeravi moolakangalaayi vighadikkunnu; 750 digri selshyas (1020 keey), δdiss "h" 1020 ennathil enthalpi maattam + 240 kj/mol aayi kanakkaakkappedunnu.
soolid stettu physics.
nyootron chitharal asaadhaaranamaaya kanthika spectrum velippeduthiyappol kittev kwaandam spin draavaka avasthaykkulla oru sthaanaarthiyaayi α-rukl 3 nirddeshikkappettu, taapa gathagatham oru kaanthikakshethrathinu vidheyamaakumbol kairal mejarana fermionukal velippeduthi.
jalamshamulla ruthenium trichloridinte ekopana rasathanthram.
ettavum saadhaaranayaayi labhyamaya ruthenium samyuktham enna nilayil, prathyekamaayi· "x" h2o noorukanakkinu raasa samyukthangalude munnodiyaanu. ruthenium complexukal, chlorideukal ennivayude sradheyamaaya savisheshatha onniladhikam ooksideshan avasthakalude nilanilppaan, avayil palathum chalanathmakamaayi nishkriyamaanu. randaamatheyum moonnaamatheyum nirayile parivartthana lohangalellaam kuranja spin complexukal maathramaayi roopappedunnu, athesamayam aduthulla ooksideshan avasthakalude sthirathayil ruthenium savisheshamaan, prathyekichu ruu (ii), ruu (iii) (maathrraajyamaaya derivateevukal· "x" "x"), ruu (iv).
ruthenium trichloride" ennathil ninnu uruthirinja chithreekarana samuchayangal.
eee prathikaranam intermediat sis-ruu (baipi) (baipi) vazhiyaan purogamikkunnathu.
purogamikkunnathu [rukl 2 neey [rukl [rukl 4 aayi kuraykkaan kazhiyum.
eee samyukthangalil chilath rund nobal sammaanangalumaayi bandhapetta gaveshanangalil upayogichu. rutheniyathe adisthaanamaakkiyulla praayogika asama hydrajaneshan kaattalistukal vikasippichathin 2001 ll rasathanthrathinulla nobal sammanam ryoji noyorikk labhichu. roobert echu. ruthenium alkylideen derivetteevukale adisthaanamaakkiyulla praayogika alkeen metatheesis kaattalistukal vikasippicheduthathin 2005 ll grabsinu rasathanthrathinulla nobal sammanam labhichu.
kaarban monoxide derivateevukal.
derivateevukal rukl3 ex kaarban monoxidemaayi soumyamaaya saahacharyangalil prathipravartthikkunnu. ithinu vipareethamaayi, irumbu chlorideukal koyumaayi prathipravartthikkunnil. qoo chuvapp-thavitt trichloride inathe manjaniramulla ruu (ii) inamaayi kuraykkunnu. prathyekamaayi, prathyekamaayi rukl3 x muthal koyude 1 atm vareyulla ethanol layani exposure cheiyunnathu, nirddishta vyavasthakale aashrayich, 4] (qoo) 4], 4] (qoo) 4] 2−, 2− (qoo) 3] − enniva nalkunnu. atharam laayanikalilekku ligandukal (ell) cherkkunnath ruu-sii. ell-qoo-ell samyukthangal (ell = pii. aarr. 3) nalkunnu. eee carbonylated laayanikalude kuravu Zn upayogichu ooranchu trikona klasttar nalkunnu
nalkunnu (qoo) 12.

