
gluconasturtin

cruciferous pachakkarikalil, pradhaanamaayum verukalil ettavum vyaapakamaayi vitharanam cheyyappedunna glucosinolettukalil onnaanu gluconastoortin allengil fenethyl glucosinolate, koodaathe kaabej, kaduk allengil rape polulla crusiferukal valarthunnathinte swaabhaavika keeda-prathirodha gunangalkk kaaranamakunna sasya samyukthangalil onnayirikkaam ithu. pala jeevajalangalkkum vishaamsham pakaruna fenethyl isotheosainettaayi myrosiness enna sasya ensime shayikkunnathaanu gluconastoortintinte eee phalathinu kaaranam.
watercressil ("naasturshyam oofisinaale") undaakunnathil ninnaan gluconastoortin enna peru labhichathu. pachakkarikalil, ithu sinigrinodoppam hozhsaradishilum ("aarmareshya rustikkaana") kaanapedunnu. rund samyukthangalum theekshnamaaya ruchi purappeduvikkunnu.
sambhavam.
1899ll watercress, naasturshyam oofisinaale, cress barberia verna ennivayil ninnu verthiricheduthathin sheshamaan eee samyuktham aadyamaayi report cheyyappettathu. brassicacy, resedezi ennivayulppedeyulla mattu brassica kudumbangalil gluconasturtin ippol vyaapakamaayi kaanapedunnu.
hozhsaradish verukalekkurichulla oru anweshanathil, verthirichedutha glucosinolettukalude 83 sathamaanavum gluconastoortin 11 sathamaanavum prathinidheekarikkunnu.
synthesis.
jaivasamshleshanam.
amino assid finailaalanainil ninnu multy-steppu pathayil gluconastoortin jaivasamshleshanam cheyyappedunnu.
laborattari synthesis.
aadyathe laborattari synthesis samyukthathinte ghadana sthireekarikkunnathinu sahayichu. pilkkala pravartthanangal eee fenethyl derivative ulppede niravadhi glucosinolettukal nirmmikkaan anuvadichu. eee prakriyakal swaabhaavikamaayi kaanapedunna sasyangalil ninnu shudhamaaya vasthukkale verthirikkunnathinekkaal kaaryakshamamaan.
pravartthanam.
glucosinolettukalude swaabhaavika punk sasya prathirodha samyukthangalaanu. myrosiness ensime gluconasturiyinile glucose groupine neekkam cheyth oru intermediat nalkunnu, athu fenethyl isotheosainettilekku swamedhayaa punakrameekarikkunnu. ithu pala praanikale vettayaadunna mrugangalkkum vishaamsham undaakkunna oru prathipravartthana padaarthamaanu, koodaathe chedikku kedupaadukal sambhavikkumbol athinte uthppaadanam aarambikkunnu. eee phalathe kaduk enna bomb ennu vilikkunnu. saadhaaranayaayi bhakshanangalil kaanapedunna saandrathayil, glucosinolettukal manushyarkk vishamallathathum upayogapradamaaya sugandha gadakangalumaayirikkum.

