grigori yaablonski

kemikkal kainattiks, kemikkal enchiniyaring ennee mekhalakalil, prathyekichu susthira vikasanathinte pradhana prerakashakthikalilonnaaya poornnavum selective ooksideshante kaattalatik saankethikavidyayil vidagdhanaanu grigori yaablonski (allengil yaablonski).
sankeernamaaya sthira-avastha, sthiramallaatha-avastha kaattalatik prathikaranangalekkurichu addehathinte sidhaantham lokathinte pala raajyangalilum (usa, yuke, beljiyam, jarmmani, france, norway, thayland) gaveshana samghangal vyaapakamaayi upayogikkunnu.
seyint luis sarvakalaashaalayile parks koleju oof enchiniyaring, eviyeshan aandu teknolaji, koleju oof arts aandu sciences ennividangalil rasathanthrathinte associate research professoraayi yaablonski sevanamanushtikkunnu.
2006 muthal yablonsky russian-american 'middle vestt' enna pathratthinte edittaraayirunnu.
shaasthreeya sambhavanakal.
yabolnsky, lasmanumaayi chernnu, sthiraavasthayilulla gathikolppaadanatthinte (gathikolpatthi ') pothuvaaya roopam vikasippichu, ithu munbu nirddeshikkappetta niravadhi saidhaanthika padaprayogangalude (langmuir-hinshelwood, hoogan-vaatsan samavaakyangal) rekheeyamallaatha saamaanyavalkkaranamaanu. joonn tii vikasippicha noothana lokamembaadumulla pareekshanathmaka saankethikavidyaykkaayi (uthppannangalude thaalkkaalika vishakalanam) krithyamaaya kaattalist swabhaava savisheshathayude oru sidhaanthavum yaablonski srishtichu. sent washington sarvakalaashaalayile leaves. luis.
2008-2011 ll, yablonsky, konstales, maarin (ghent yooniversitti, beljiyam), alexander gorban (yooniversitti oof leasester, yuke) ennivaykkoppam, gathikolppaadanangalile yaadrishchikathakalilum vibhajanangalilum puthiya phalangal nedukayum nireekshikkaknathum prarambhavumaaya gathikolppaadanangal thammilulla oru puthiya tharam samamiti bandham kandethukayum cheythu.
alexander gorbaanumaayi chernnu yaabonski kemikkal thermodynamics sidhaanthavum thirichedukkaanaavaatha prathikaranangalude paridhiyil vishadamaaya balance vikasippichu.
kaattalitik trigger, kaattalitik oosilettar.
1978ll baikov, yaablonski, kiim ennivar vaividhyamaarnna kaattalatik prathikaranangalile nonleeniyar kainettik aandolanangalkkulla oru lalithamaaya padhathi nirddeshichu. sthiramaaya avasthakalude vardhanavu anuvadikkunna autocatalysis illaatha ettavum lalithamaaya kaattalatik trigger (1976) upayogichaanu rachayithakkal aarambhichath.
thudarnnu avar kaattalatik ooksideshante eee classical agiranam cheiyunna samvidaanathinu oru "buffer" ghattam vazhi anubandhamaayi nalki.
ivide, a2, b, ab enniva vaathakangalaanu (udaaharanathinu, o2, co, co2), z ennathu khara uthejakathinte uparithalathile "agiranam cheyyappedunna sthalam" (udaaharanathinu, pt), az, bz enniva uparithalathile idanilakkaaraanu (adattangal, agiranam cheyyappedunna thanmathrakal allengil radicalukal), (bz) pradhana prathikaranatthil pankedukkaattha oru idanilakkaaranaanu.
vathaka gadakangalude saandrata sthiramaayirikkatte. appol maas aakshan niyamam eee prathikarana samvidaanathinu uparithalathile gathikolppaadanathe vivarikkunna moonnu saadhaarana deferential samavaakyangalude oru samvidaanam nalkunnu.
uparithalathile swatantra adishoshana sthalangalude saandrata evideyaanu ("oru adishoshana kendratthil"), "x", "y" enniva "az", "bz" ennivayude saandrathayaanu, athinanusarichu (oru adishoshana kendratthil "saadhaaranavalkkarikkappettathum"). s" ennathu buffer gadakathinte ("bz") saandrathayaanu.
eee trimana samvidaanathil ezhu paaraamettarukal ulppedunnu. aandolanangal, sthiraavasthakalude vardhanavu, vividha tharatthilulla vibhajanagal ennivayulppede eee samvidaanathinu 23 vyathyastha ghatta chhaayaachithrangalundennu vishadamaaya vishakalanam kaanikkunnu.
vyathyastha gadakangalude prathipravarthanangalillaatha prathikaranangal.
prathikarana samvidaanathil prathikaranangal adangiyirikkatte.
soothravaakyam _ 2 gadakangalude chinnangalaanenkil, "r" ennathu praadhamika prathikaranatthinte ennavum soothravaakyam _ 3 ennathu stoikiyometrik gunakangalumaanu (saadhaaranayaayi avaa poornnasamkhyakalaanu). (adhikamaayi adangiyirikkunna gadakangalum eathaandu sthiramaaya saandrathayulla gadakangalum ulppeduthiyitla.)
pii. tiyile qoo ooksideshante elii-raidal samvidaanam uparithalathil vividha gadakangalude prathipravarthanamillaathe atharam prathikarana samvidaanathinte lalithamaaya udaaharanam nalkunnu
prathikarana samvidaanathinu samrakshana niyamam undakatte
prathikarana nirakk maas aakshan niyamathe thripthippeduthatte 
ivide formula _ 6 ennathu formula _ 2-nte saandrathayaanu.
appol gathikopakaranatthinte chalanathmakatha valare lalithamaanu sthiramaaya avasthakal sthirathayullathum samrakshana niyama soothravaakyathinte athe moolyamulla ellah parihara soothravaakyangalum _ 8 ekathaanamaayi bharamullah soothravaakyathil _ 10 maanadandatthil othucherunnu atharam parihara soothravaakyam _ 11 thammilulla dooram,
kaalakramena ekathaanatha kurayunnu.
vividha gadakangalude prathipravartthanamillaatha sisttangalude eee quasithermodynamic property kaattalatik prathikaranangalude chalanaathmakathayude vishakalanathin pradhaanamaann rund (allengil athil kooduthal) vyathyastha intermediat reactorukalulla nonleeniyar gattangal sthiramaaya avasthakalude gunanam, aandolanangal allengil vibhajanagal polulla nissara chalanaathmakamallaatha falangalkku kaaranamaakunnu. vyathyastha gadakangal thammilulla prathipravarthanamillaathe, kainettik karvukal ooppan systengalkku polum oru lalithamaaya maanadandamaayi othucherunnu.
vishadamaaya baalansinte vipuleekritha thathwam.
pala yadhaartha bhauthika-raasa sankeernna samvidaanangaludeyum vishadamaaya samvidaanathil reversible ulppedunnu.
oppam thirichedukkaanaavaatha prathikaranangalum. atharam samvidaanangal ekeekritha jwalanathil saadhaaranamaanu.
vaividhyamaarnna kaattalitik ooksideshanum sankeernamaaya ensime prathikaranangalum. classical
reversible kainattiksinayi nirvachichirikkunna thikanja sisttangalude thermodynamicsinu paridiyilla
thirichedukkaanaavaatha prathikaranangal. neremarichu, maas aakshan niyamam eathenkilum raasa chalanathmaka samavaakyangal ezhuthaan avasaram nalkunnu.
reversible, irreversible prathikaranangalude samyojanam. adhika niyanthranangalillaathe,
eee samavaakyangalude klaas valare vishaalamaan, eathu chalanathmaka samvidaanatheyum ekadeshamaayi kanakkakkaan kazhiyum.
saandrathayude posittivityum rekheeya samrakshana niyamangalum samrakshikkuka. (ithu
pothuvaaya ekadesha sidhaantham 1986ll theliyikkapettu.)
yadhaartha samvidaanangal chila niyanthranangal paalikkanam. staanderd microscopic reversibility aavasyakathaykku keezhil, eee niyanthranangal inipparayunna reethiyil roopappeduthanam
chila thirichedukkaanaavaatha prathikaranangalulla sisttam ellah reversible prathikaranangalum vishadamaaya balance avasthakalum ulla sisttangalude paridhiyil aayirikkanam. atharam samvidaanangal 2011-ll poornnamaayum vivarichittundu. "vishadamaaya baalansinte vipuleekritha thathwam" ithaanu
pothuvalkkaricha bahujana pravartthana niyamam anusarikkunna ellah samvidaanangaludeyum savisheshamaaya swath
prathikarananirakkil chilath sthiramaakumbol vishadamaaya balansullah sisttangalude paridhi
poojyathilekku (gorban-yaablonski sidhaantham) pravanatha kaanikkunnu.
vishadamaaya baalansinte vipuleekritha thathwathil rund bhaagangalunda
prathikarana soothravaakyathinte stoikiyometrik vekttar _ 13 aanu kordinettukalulla "geyin mainus loss" vekttar.
formula _ 14.
(aupachaarikamaaya kanvenshan ormmikkunnathu upayogapradamaayekkaam shoonyamaaya oru settinte rekheeya dairkhyam 0 aanu;
shoonyamaaya oru settinte convex hull shoonyamaanu.)
vishadamaaya baalansinte vipuleekritha thathwam inipparayunna prashnathinu aathyanthikavum poornnavumaaya utharam nalkunnu "thermodynamics microscopic reversibilityum lamghikkaathe chila vipareeta prathikaranangal engane thallikkalayaam?"thirichedukkaanaavaatha prathikaranangalude stoikiyometrik vektarukalude convex hull reversible prathikaranangalude stoikiyometrik vektarukalude rekheeya spaanumaayi murichukadakkaan paadilla ennathaanu utharam, koodaathe sheshikkunna reversible prathikaranangalude prathikarana nirakk sthiraangangal wegschaider aidantittikale thripthippeduthanam.
currier.
1997 muthal 2007 vare, sent yablonsky washington sarvakalaashaalayile oorjjam, paristhithi, kemikkal enchiniyaring vibhaagathil research associate professoraayirunnu. luis. 2007 muthal, seyint luis sarvakalaashaalayile parks koleju oof enchiniyaring, eviyeshan aandu teknolaji, rasathanthram ennee vakuppukalil associate professoraanu yaablonski.
thante kariyaril, yaablonski deseeya anthardesheeya thalangalil niravadhi konfaransukalum varkshoppukalum samghadippichittundu. ganithashaasthranjar, rasathanthranjar, bhauthikashaasthranjar, kemikkal enchineeyarmaar ennivar ulppedunna inter disciplinary dialogukalil yaablonski pathivayi pankedukkunnu.
2013ll jaims bii. yilek yaablonsky thiranjedutthu. enchineeyaringilo saankethikavidyayilo mikacha nettangal kaivaricha oru vishishta vyakthiye amgeekarikkunna eeds award.
professional amgathvangalum associationukalum.
oonarari professor, fellow, doctor, beljiyam, india, chaina, russia, ukraine ennividangalile prashasthamaaya shaasthra akkaadamikalilum sarvakalaashaalakalilum amgamenna nilayil yablonskiykku niravadhi anthaaraashtra padavikal undu.
sradheyamaaya prasidheekaranangal.
yaabonski ezhu pusthakangalude rachayithaavaan, ettavum aduthide "kainettiks oof kemikkal reactionsa decoding complexity" (2011) (gaii bii. yumayi chernnu. maarin), koodaathe 200-ladhikam pepparukal.

