
vanadate

rasathanthrathil, vanaadiyathinte oru ionic coordination complexaanu vanaadett. palappozhum vanaadett ennathu vanaadiyathinte ooksoyaaniyanukale soochippikkunnu, avayil bhooribhaagavum + 5 enna ettavum uyarnna ooksideshan avasthayil nilanilkkunnu. complexukale yathaakramam hexacianovanadate (III), nonachlorodivanadet (III) ennu vilikkunnu.
e-yill adangiyirikkunna tetrahedral oorthovanaadettu ayoon (ithine vanaadett (v) ennum vilikkunnu) aanu lalithamaaya vanaadett ayoon.jii. soodiyam oorthovanaadettum sakthamaaya aditharayude laayanikalilum (piechu> 13). parambaraagathamaayi eee ionine orotta eratta boond upayogichu prathinidheekarikkunnu, ennirunnaalum ayoon naalu thulyamaaya ooksijan attangalulla oru saadhaarana tetrahedronaayathinaal ithu oru anuranaa roopamaanu.
koodaathe, vyathiriktha ionukalum "ananthamaaya" polymeric ionukalum ulppedunna polyoxovanodate ayonukalude oru shreni nilavilundu. rhodium vanaadett polulla vanaadettukalum undu, avaykku stattistikkal rutail gadanayundu, avide ionukalum ionukalum kramarahithamayi rutail laattisile sthaanangal kaivashappeduthunnu, avayil kaatteshanukalude oru laattis adangiyittilla, ennaal wanadate ayonukale santhulithamaakkunnu, ennaal mixed ooksaidukalaanu.
rasanamakaranam anusarichu, vanaadett perinte bhaagamaakumbol, samyukthathil oru kendra vanadium aattamulla oru ayoon adangiyirikkunnuvennu ithu soochippikkunnu, iii.jii. amonium hexafluoridovanadet (III) enna ipac perulla samyukthathinte pothuvaaya peraanu amonium hexafluorovanadet.
ooksovanaadett ayonukalude udaaharanagal.
vyathiriktha ayonukalude chila udaaharanagal ivayaanu
polymeric "ananthamaaya" ayonukalude chila udaaharanagal ivayaanu
eee ayonukalil vanadium tetrahedral, square pyramid, octahedral ekopanam enniva pradarshippikkunnu. eee kaaryatthil vanadium tungstate, mollibdate ennivayumaayi saamyathakal kaanikkunnu, athesamayam kromiyathinu ayonukalude paridhi kooduthal parimithamaanu.
jaleeya pariharangal.
sakthamaaya adisthaana jaleeya laayaniyil vanadium pentoxide layikkunnath niramillaatha ayoon nalkunnu. acidificationil, eee laayaniyude niram kramena ooranchu niratthil ninnu chuvapp niratthilekku ekadesham piechu 7 nuu irundupokunnu. thavitt jalamshamulla vii2oo5 piechu 2 nuu chuttum veezhunnu, ayoon adangiya ilam manja layani roopappeduthunnu. piechu 13 num 2 num idayil nilanilkkunna ooksayaaniyanukalude ennavum identityum piechineyum sandrathayeyum aasrayichirikkunnu. udaaharanathinu, vanaadettinte protonation polyoxovanodate ionukal uthpaadippikkunnathinu kandanseshanukalude oru parambara aarambikkunnu
aushadha gunangal.
naa +/keey +-atpes, caa2 +-atpes (pmca) thudangiya chila plasma membran atpesukalude sakthamaaya inhibittaraanu vanaadett. phosphettinte parivartthana-avastha analogaayi pravartthikkunna vanaadett phosphoril kaimatta samayat vellathinte nucleophilic aakramanathinu vidheyamaakunnu, pradhaanamaayum pii-type atpesukale avayude phosphorylated iii 2 avasthayil "trap" cheiyunnu.
 ithu asthikooda peshikalude actomyosin magaatpes pravartthanatheyum kedukoodaattha asthikooda peshikalude churungunna upakaranathil actomiosin vazhi kaalsyam sajeevamaaya shakti ulppaadanatheyum thadayunnu. ennirunnaalum, serca (sarco/endoplasmic rettikulam sii. eiii. 2 +-atpes) allengil mitocondrial atpes polulla mattu atpesukale ithu thadayunnilla.

