
silileen

sih2 enna soothravaakyamulla oru raasa samyukthamaanu silileen. ithu ettavum lalithamaaya carbeenaaya methylene silikkan analogaanu. vaathakam enna nilayil sthirathayulla oru thanmathrayaanu silileen, ennaal ghaneebhavikkumbol bimolecular reethiyil athivegam prathikarikkunnu. single allengil triple avasthayil nilanilkkunna kaarbeenukalil ninnu vyathyasthamayi, silileen (athinte ellah derivetteevukalum) singilttukalaanu.
silileeninte aupachaarika derivateevukalaanu silileenukal, athinte hydrajanukalkku pakaram mattu pakarakkar upayogikkunnu. mikka udaaharanangalilum amido (enr2) allengil alkail/aaril grouppukal undu.
silileenukal reactive idanilakkaaraayi nirddeshikkappettittund. avaa carbean analogukalaanu.
samanvayavum gunangalum.
polisileynukalude thermolysis allengil photolysis, silikkan aattam prathikaranangal (ulppeduthal, kootticherkkal allengil amoorthamaakkal), saileynukalude pyrolysis allengil 1,1-dihalosileyn kuraykkuka ennivayiloodeyaanu sililainukal saadhaaranayaayi samanvayippikkunnathu. silileen idanilakkaar vazhiyaan lohamaaya sii-yeei tetraavalent silikkan samyukthangalayi parivartthanam cheiyunnathennu valarekkaalamaayi anumaanikkappedunnu
methyl chloridinteyum bulk silikkaninteyum nerittulla prakriya, prathikaranam ennivaykkum samanamaaya parigananakal baadhakamaan.
silileenukalude aadyakaala nireekshanangalil dimethyldichlorosylane declorination vazhi dimethylsilene uthppaadippikkunnathu ulppedunnu
trimethylsileyninte saannidhyathil declorination nadathiyaanu dimethylsileeninte roopeekaranam prakadamaayathu, kudungiya uthppannam pentamethyldisilen aannu
1994ll maikkal keey aanu oru room-thaapanila isolable "enn"-heterocyclic silileen aadyamaayi vivarichathu. denk thudangiyava.
α-amido kendrangal π-daanatthiloode silileenukale sthirappeduthunnu. diorganosilican dihalideukalude dehyalogenation vyaapakamaayi upayogikkunnu.
bandhapetta prathikaranangal.
oru padanatthil oru tricylaininte flash photolysis vazhi diphenylsilene srishtikkappedunnu
eee prathikaranatthil tricila valayathil ninnu diphenylsilene puranthallappedunnu. silileen 520 enm-ll yuvi spectroscopy upayogichu nireekshikkaan kazhiyum, koodaathe rund micro secondukalude raasa ardhayussinoppam hraswakaalamaanu. second oordar rettu sthiraankamulla oru raasa keniyaayi methanol pravartthikkunnu, athil defusion niyanthranathinu aduthaanu.