
moff

moof, jise oxodeperoxymolybdenam (pyridine)-(hexamethylphosphoric trimide) key roop mein bhee jaanaa jaataa haye, carbonic sanshleshan mein upayog kiya jaane vaalaa ack abhikarmak haye. isamen kaee oxygen ligand key saath ack molybdenum (vi) kendra hotaa haye, joe pyridine aur aich. aim. pee. aeye. ligand key saath samanvit hotaa haye. yeh oxygen kaa ack electrophilic srot haye joe annolates aur sambandhit sanrachanaon key saath pratikriya kartaa haye, aur iss prakaar carbonyl yukt yaugikon key alfa-hydroxylation key liye upayog kiya jaa sakata haye. inol yaa annolet sanrachanaon key madhyam seey alfa-hydroxylation key liye upayog kiye jaane vaale anya abhikarmakon mein davis oxaziridine, oxygen aur vibhinn peroxy acid shamil hain (rubotum okseekaran dekhein). iss abhikarmak kaa upayog pahali baar 1974 mein advin vedez dwara ack kushal alfa-hydroxylating agent key roop mein kiya gayaa thaa aur ack prabhaavi praarambhik prakriya baad mein 1978 mein prakaashit kii gaee thee.
sanshleshan.
hydrogen peroxide key saath okseekaran aur aich. aim. pee. aeye. aur pyridine ligand key jodd dwara molybdenum trioxide seey moof kaa sanshleshan kiya jaataa haih
pratikriyashilta.
moof key steric bulk key kaaran, oh-oh bonned parr adhimanya hamla stereoelectronic karakon kii anupasthiti mein cumm baadhit annolet chehare seey hotaa haye. 
isake alawa, amleeya alfa proton vaale nitrile koo seedhe sinohydrine mein parivartit kiya jaa sakata haye; haalaanki, shakha vaale nitrile key mamle mein, yeh pratikriya seedhe keaton koo pradaan karati haye.
sulphone key mamle mein, alfa-hydroxylation seedhe keaton yaa aldehyde kii or leey jaataa haye.
alfa-hydroxylation key samanya upotpaadon mein praarambhik samagri kii sambandhit dicarbonyl yaa antar-aanvik aldol pratikriya key liye atiaakseekaran shamil hotaa haye. side reaction koo rokane key liye prakriyaon mein moof mein annolet kaa vipareet jodd yaa tapman kaa saavdhaanipoorvak niyantran (-78 seey-20 degree celsius) shamil haye. ullekhaniya vividh pratikriyaon mein shuddh stereo-pratidhaaran key saath seedhe alcohol mein alkilborance koo aukseekrit karane kii moof kii kshamata shamil haye.
moof koo aine-trimethylacylil amide koo seedhe hydroxamic acid mein aukseekrit karane key liye bhee dikhaaya gayaa haye. 

