
anuprasth vishram-anukoolit spectroscopy

anuprasth vishram anukoolit spectroscopy (trossy) protein nmr spectroscopy mein ack prayog haye joe badey anuon yaa parisaron key adhyayan kii anumati detaa haye.
badey anuon mein nmr kaa anuprayog aam taur parr iss tathya seey seemit hotaa haye kii rekha kii chaudaai aam taur parr aanvik dravyamaan key saath badhati haye. badey anuon mein lambe ghoornan sahsambandh samay hotey hain aur parinamswarup cumm anuprasth vishram samay (tii2) hotaa haye. dusare shabdon mein, badey anuon seey nmr sanket adhik teji seey kshay hotaa haye, jisase nmr spectrum mein rekha kaa vistaar hotaa haye aur resolution kharaab hotaa haye.
ack hsqc spectrum mein jisamen decoupling lagu naheen kii gaee haye, jey-coupling key kaaran shikhar kaee key roop mein dikhaai dete hain. mahatvapurna roop seey vibhinn bahugunak ghatakon kii chaudaai alag-alag hoti haye. yeh vibhinn vishram tantron key beach rachanaatmak yaa vinashkari antahkriya key kaaran haye. aam taur parr uchch chumbakiya kshetra kii taakat parr badey protein key liye, anuprasth (tii2) vishram mein dwidhruv-dvidhruviya (dee. dee.) tantra aur rasayanik sthanantaran anisotropy (see. aiss. aeye.) tantra kaa prabhutva hotaa haye. choonki vishram tantra aam taur parr sahsambaddh hotey hain lekin vibhinn sanketon key saath diye gaye ghatak kii samagr vishram darr mein yogdan karate hain, isaliye gunak ghatak bahut alag samagr daron key saath aaraam karate hain. trossy prayog koo usa ghatak kaa chayan karane key liye design kiya gayaa haye jisake liye vibhinn vishram tantra lagbhag radd hoe gaye hain, jisase spectrum mein ack ekal, tej shikhar hoe jaataa haye. yeh varnakramiya sankalp aur samvedansheelta donon koo kaafee badhaata haye, joe donon badey aur jatil jaiv anuon kaa adhyayan karate samay ack pramukh star parr hotey hain.
yeh drishtikon aanvik dravyamaan seema koo kaafee hudd taka vistaarit kartaa haye jiska adhyayan nmr dwara kiya jaa sakata haye, lekin ise aam taur parr see. aiss. aeye. aur dee. dee. vishram tantra key beach aavashyak santulan praapt karane key liye uchch chumbakiya kshetron kii aavashyakta hoti haye; kshetra kii taakat key saath see. aiss. aeye. aiss. paimana, jabaki dvidhruviya-dvidhruviya yugman kshetra-swatantra hotey hain.