Ahmed Eleryan,Uyiosa O. Aigbe,Kingsley E. Ukhurebor,Robert B. Onyancha,Mohamed A. Hassaan,Marwa R. Elkatory,Safaa Ragab,Otolorin A. Osibote,Heri S. Kusuma,Ahmed El Nemr
Adsorption of direct blue 106 dye using zinc oxide nanoparticles prepared via green synthesis technique
Direct blue 106 dye,Industrial wastes,Nanoparticles,Sorption,Water treatment
Zinc oxide nanoparticles (ZnO-NPs) have in recent times shown effective adsorption capability for the confiscation of colour contaminants from aqueous environments (aquatic ecosystems or water bodies) due to the fact that ZnO contains more functional groups. Direct blue 106 (DB106) dye was selected for this present study as a model composite due to its wide range of uses in textiles (cotton and wools), woods, and paper industries, as well as their therapeutic applications, along with its potential for impairments. This study therefore focuses on the use of DB106 dye as a model composite due to its wide range of uses in textiles (cotton and wools), woods, and paper industries, as well as their therapeutic applications and their potential for impairments. Furthermore, the surface functionalization, shape, and composite pore size were revealed by TEM, FTIR, UV, and BET techniques. The current study uses green synthesis method to prepare ZnO-NPs as an adsorbent for the DB106 dye molecules adsorption under various conditions using the batch adsorption process. The adsorption of DB106 dye to the ZnO-NPs biosorbent was detected to be pH-dependent, with optimal adsorption of DB106 (anionic) dye particles observed at pH 7. DB106 dye adsorption to the synthesized ZnO-NPs adsorbent was distinct by means of the linearized Langmuir (LNR) and pseudo-second-order (SO) models, with an estimated maximum adsorption capacity (Qm) of 370.37 mg/g. Graphical Abstract
Adsorption of direct blue 106 dye using zinc oxide nanoparticles prepared via green synthesis technique

Zinc oxide nanoparticles (ZnO-NPs) have in recent times shown effective adsorption capability for the confiscation of colour contaminants from aqueous environments (aquatic ecosystems or water bodies) due to the fact that ZnO contains more functional groups. Direct blue 106 (DB106) dye was selected for this present study as a model composite due to its wide range of uses in textiles (cotton and wools), woods, and paper industries, as well as their therapeutic applications, along with its potential for impairments. This study therefore focuses on the use of DB106 dye as a model composite due to its wide range of uses in textiles (cotton and wools), woods, and paper industries, as well as their therapeutic applications and their potential for impairments. Furthermore, the surface functionalization, shape, and composite pore size were revealed by TEM, FTIR, UV, and BET techniques. The current study uses green synthesis method to prepare ZnO-NPs as an adsorbent for the DB106 dye molecules adsorption under various conditions using the batch adsorption process. The adsorption of DB106 dye to the ZnO-NPs biosorbent was detected to be pH-dependent, with optimal adsorption of DB106 (anionic) dye particles observed at pH 7. DB106 dye adsorption to the synthesized ZnO-NPs adsorbent was distinct by means of the linearized Langmuir (LNR) and pseudo-second-order (SO) models, with an estimated maximum adsorption capacity (Qm) of 370.37 mg/g.

The issues of ecological destruction that are harming natural resources and causing a variety of environmental effluences (in the form of toxic wastes) as a result of increased industrial activity, a significant increase in population, and constant high-tech development are now a serious threat to the human being and its environment on a global scale (Onyancha et al. 2021a; Ukhurebor and Aidonojie 2021; Ukhurebor et al. 2021a). The majority of these environmental toxic wastes are the result of industrial processes, including dyes (Aigbe et al. 2021a; Eldeeb et al. 2022a, b), heavy metals (HMs) (El-Nemr et al. 2022; Aigbe et al. 2022; Onyancha et al. 2022; Eleryan et al. 2022), wastewater (Aigbe et al. 2021a, b; Sudarni et al. 2021), gas flares, and crude oil spills (Ukhurebor et al. 2021b; Onyancha et al. 2021; Ukhurebor et al. 2022a), among others. These environmental effluences rising from industrial operations are aggravating the negative environmental, health, and climatic challenges that are jeopardizing both the terrestrial, aquatic, and atmospheric ecosystems (Ukhurebor et al. 2022a; Ukhurebor et al. 2021c; Onyancha et al. 2021; Ukhurebor et al. 2022b). The textile industries consume several quantities of chemicals and water and, in return, emit a lot of hazardous and non-biodegradable chemical effluents, such as dyes, and are a significant cause of industrial pollution (Jaafari et al. 2018; Ali et al. 2020a; Eldeeb et al. 2022a, b; Al-Arjan 2022). Due to dyes’ beneficial qualities, such as vivid colours, water resistance, and simplicity of applications (Al-Arjan 2022; Yang et al. 2022), they are frequently used in several textile-based businesses (Eldeeb et al. 2022a, b; Ali et al. 2020a; Hassaan et al. 2022). Synthetic dyes are used extensively in several industries, including textile dyeing (amounting to about 60%), paper (amounting to about 10%), and plastic products (amounting to about 10%) (Al-Arjan 2022). As noted by several reports, there are about a hundred thousand commercially existing dyes with a manufacturing capability of over 7.0 × 105 metric tons annually, with the industries involved in textile manufacturing using approximately ten thousand composites (Al-Arjan 2022). Industrial effluents from dyes, in particular, necessitate not only the management of difficult wastewater with high biological and chemical oxygen demands, deferred constituent parts, and dangerous chemicals, but also the treatment of dyes that are perceptible to human senses at very low concentrations (Al-Arjan 2022; Kusuma et al. 2023; Neolaka et al. 2023). When dyes are discharged into aquatic settings (water bodies), reductive azo linkage cleavage takes place, creating harmful amines that can harm key organs like the kidney, brain, and liver as well as the reproductive and central neurological systems (Al-Arjan 2022; Kusuma et al. 2023; Neolaka et al. 2023). Due to the existence of metals, chlorides, aromatics, and other impurities, synthetic dyes may also negatively affect some aquatic life’s ability to photosynthesise. As a result, it is crucial to remove them from aquatic ecosystems (water bodies), and this is the subject of various scientific investigations (Al-Arjan 2022; Bayramoglu and Arıca 2007; Hassaan et al. 2020a, b; El Nemr et al. 2021a; Hassaan et al. 2021). Exchange of ions (Guida et al. 2022), electrolytic reduction (Golder et al. 2011), membrane and oxidation technologies (Schwermer et al. 2018; Deng and Zhao 2015), chemical precipitation (Harper and Kingham 1992), flocculation/coagulation (Song et al. 2004; Semerjian and Ayoub 2003), and adsorption by biological means (Sudarni et al. 2021a; El-Nemr et al. 2022), are some of the notable developed scientific investigations (methods) that have been used for the dyes and impurities adsorption from aquatic ecosystems (water bodies) and wastewaters. Due to its ease of use, high efficiency, and versatility for using a variety of adsorbents, adsorption by the biological process has recently become the most widely used processes for the adsorption of dyes from aquatic ecosystems and wastewaters (Zazouli et al. 2016; Azari et al. 2017, 2020; Al-Arjan 2022; El Nemr et al. 2021a; Hassaan et al. 2021; Hassaan et al. 2020a, b). Diverse nanoparticles (NPs) have also been investigated for dye removal by biological processes because of the ease with which their surface functionality may be adjusted and their high surface-to-volume ratio for increased removal efficiency (Ghiloufi et al. 2016). It is believed that dyes from aqueous solutions (aquatic ecosystems) can be adsorbable by nanoscale metal oxides, such as aluminium, cerium, ferric, and magnesium oxides (Agrawal and Sahu 2006). Additionally, the effectiveness of these NPs as very effective adsorbents for the sorption of metal ions from aquatic ecosystems and wastewaters has been thoroughly studied. They have many advantages, containing unsaturated surfaces, ease of use, high ability, rapid kinetics, and favourable dye removal in aquatic ecosystems and wastewaters (Agrawal and Sahu 2006). As a low-toxicity substance, zinc oxide (ZnO) has several applications, including those in the biomedicine (Azizi et al. 2016), catalysts (Zeng et al. 2008), gas sensing (Jing and Zhan 2008), and solar cells (Chou et al. 2007; Emegha et al. 2022). Additionally, ZnO is a member of the group of metal oxides that have a significant economic impact due to their impressive uses in a variety of industrial sectors, including solar cells, catalysis, paints, electronic devices, UV light-emitting devices, cosmetics, and biomedicine. Similar to ZnO-NPs, these semiconductors have drawn interest for their widespread variety of uses in optics, optoelectronics, electronics, and dye removal using environmentally friendly synthesis materials such as bacteria, fungi, and marine macroalgae (Al-Arjan 2022). ZnO has also been shown to be more efficient than other metals in the bio-synthesis of NPs for biomedical purposes (Naseer et al. 2020). The most significant metal oxide NPs are ZnO-NPs due to their special chemical and physical characteristics, which expand their usefulness (Elia et al. 2014). It can be difficult to remove certain contaminants from the environment; consequently, adsorption by biological processes or techniques is typically considered to be easier and more efficient. The useful application of ZnO in water purification, containing contamination removal and reuse, has drawn significant consideration recently due to its huge theoretical specific surface area (Yu et al. 2015). ZnO has demonstrated better adsorption performance because it contains more functional groups. ZnO may therefore be more useful in adsorption technologies (adsorption by biological processes or techniques). In addition, it was discovered that ZnO worked better as an adsorbent to remove sulphur compounds and H2S than other adsorbents such as activated carbon, phosphate, and iron oxide (Al-Arjan 2022; Hassan et al. 2008). Recently, it was discovered that ZnO-NPs effectively absorbed colours from aquatic ecosystems or water bodies (aqueous environments) (Al-Arjan 2022; Wang et al. 2010). Direct blue 106 (DB106) dye was selected for this present study as a model composite due to its wide range of uses in textiles (cotton and wools), woods, and paper industries, as well as their therapeutic applications, along with its potential for impairments. In this study, the adsorption batch process was used to synthesize a composite of ZnO-NPs as an adsorbent for the adsorption of DB106 dye from aquatic ecosystems or water bodies (aqueous environments) under varied circumstances. The pH, starting concentration of DB106 dye, time of contact, dosages of adsorbent, and process temperature were the core factors that were assessed. Furthermore, the surface functionalization, shape, and the composite pore size were revealed by TEM, FTIR, UV, and BET techniques. The adsorption performance of the developed material was also examined using adsorption optimization analysis, kinetics, isotherms, and thermodynamics. Therefore, the aim of the current study was to reconsider and investigate the potential benefits of utilizing green synthesis method for ZnO-NPs preparation for DB106 dye removal. The purpose of this study was to demonstrate modern methods of removing DB 106 dye using more widely available, inexpensive, high-efficiency, and environmentally friendly NPs.

NaOH, Zn(CH3CO2)2.2H2O, HCl, DB106 dye (Fig. 1), and EtOH were obtained from Sigma (Sigma–Aldrich, Germany). Red alga A. plumula (Antithamnion plumula) was obtained from Kiel, Germany. High-performance double beam spectrophotometer instrument model Pg/T80 UV/Visible matched with 1 cm glass cells as an optical path was used for dye concentration analysis. JSOS-500 shaker equipment and JENCO-6173 pH meter were used during this experimental work. The GC-mass spectrometry (Agilent 7890A) linked with a MS detector (Agilent 5975C) and HP5 column chromatography was applied for the chemical analysis of algae.

Batch DB106 dye adsorption investigation was accompanied to examine the effects of several variables on the adsorption isotherm and reaction kinetics, including pH, starting concentration of dyes, ZnO-NPs doses, speed of agitation, time of contact, and process temperature. The necessary quantity of ZnO-NPs was added to dye solutions with known concentrations, and then the mixture was agitated for the definite times. Initial kinetic measurements were used to obtain an estimate of the time required to reach equilibrium conditions. After that, the solutions were filtered, and a UV–Vis spectrophotometer was used to monitor the absorbance at λmax 660 nm to quantify the remaining concentration of DB106 dye in the filtrate. By regulating the pH of the dye solutions with NaOH and HCl solutions, the pH impact was also studied. Analysing the dye solution’s ability to bind to surfaces at various contact times allowed for the determination of the adsorption kinetics. Solutions of several concentrations were stirred with the ZnO-NPs until equilibrium was reached in order to examine adsorption isotherms. Using Eq. (1), it was possible to calculate the equilibrium adsorption capacity (qe). The capability of the ZnO-NPs to remove DB106 dye from water at an equilibrium time is known as the adsorption capacity (qe), which is represented as mg DB106 dye per g ZnO-NPs. In this equation, C0 (mg/L) stands for the DB106 dye’s beginning concentration, and Ct (mg/L) for the dye’s remaining concentration after the removal process has been finished for a predetermined amount of time (min). Use the following Eq. (2) to compute how much DB106 dye has been removed from water. DB106 dye removal was investigated via mixing ZnO-NPs (0.2 g/L) and DB106 dye solution (50 mL) with a starting pH value ranging between 3 and 11. 0.1N HCl or 0.2N NaOH solutions were used to regulate the levels of pH, and the results showed that pH affected DB106 dye adsorption. The mixtures were agitated at 200 rpm for 120 min at 25 °C afore being sampled for DB106 dye measurement, which took place after 120 min. In order to conduct the isotherm research, DB106 dye solutions (50 mL) was mixed at 200 rpm for 2 h at 25 °C with varied starting DB106 dye solution concentrations (10–40 mg/L) and varying doses of ZnO-NPs (40–200 mg) until the dye solutions attained equilibrium. By shaking 50 mL of starting DB106 dye concentration for ZnO-NPs with varying adsorbent dosages (40, 80, 160, and 200 mg) at various interval times at 25 °C for different periods at different intervals, the effect of ZnO-NPs dose and contact length on DB106 dye removal was investigated.

For ZnO-NPs synthesis, 2.195 g of Zn(CH3CO2)2.2H2O was liquefied in 10 mL of red algae A. plumula extract and 90 mL distilled water (DW) in constant agitation at room temperature for 4 h. Then, a solution of 1.0 M NaOH was added drop-wise into the reaction mixture until the pH reached 10, and the agitation was continued for 3 h at 70 °C. The contaminants were removed by filtering and repeatedly washing the resultant white precipitate with DW and ethanol. The resultant white powder was then dried for 4 h at 80 °C in a vacuum oven (Hassaan et al. 2019; Albo Hay Allah and Alshamsi 2022; Hassaan et al. 2020a). The dried powder was then carefully collected and used for further research after being calcined for 3 h at 550 °C to produce pure, pale white ZnO-NPs (Hassan et al. 2015; Hassaan et al. 2019; Hassaan et al. 2020a; Amirante et al. 2018).

ZnO-NPs sample was analysed using the subsequent instrument: Fourier transform infrared (FTIR) spectroscopy model VERTEX70 linked to V-100 platinum ATR model, Bruker, Germany, in the 400–4000 cm−1 wavenumber range. The Raman spectra (RS) model V-100 VERTEX70, Germany, the ZnO-NPs samples were excited to a laser beam of 532 nm (green laser) and the samples were exposed to the laser beam for 1 s at 10 mW power with aperture 25 × 1000 mm. XRD analysis was made by a Bruker Meas Srv (D2-208,219)/D2-2,082,019 diffractometer that controls at 30 kV, 10 mA using Cu tube (λ = 1.54 Å) in the range between 0 and 100°. The crystallite sizes were measured for ZnO-NPs by the method of Scherrer. The synthesized ZnO-NPs was categorized by a Transmission Electron Microscope (TEM) (JEOL, Model JSM 6360LA, Tokyo, Japan). Thermogravimetric (TGA) analysis of the ZnO was performed by (the TERIOS SDT650 instrument). The BELSORP—Mini II, BEL Japan, Inc. was used to measure the mean diameter of the pores and the BET (Brunauer–Emmett–Teller) specific surface area.

The harvested red algae A. plumula (obtained from Kiel, Germany) were placed in a polythene bag and delivered to the lab after being rinsed with water to remove sand and epiphytes. To further eliminate salts and other pollutants, the algae were washed with DW before being shade-dried and stored. Using a mortar and pestle and an electric blender, the dried algae were broken up into minute bits. 20 mL of methanol and 2 g of the powdered algae sample were combined to create the extract (Ragunathan et al. 2019). The mixture was then incubated in at 25 °C for the following day. After that, the extract was filtered with a funnel and No. 1 Whatman filter paper. In a conical flask of 100 mL, the extract was collected. The collected extract was evaporated under vacuum to collect the crude extract of the algae. Following collection, the extracted was used for GC–MS analysis.

The pHpzc of ZnO-NPs was assessed by the pH drift process (Shoaib et al. 2022a, b), in which suspensions of ZnO-NPs in 0.01 M NaCl solutions with various beginning pH values (3–11) were used for this investigation. The starting pH values (pH initial) were designed in contradiction of the end pH values (pH final), and the point of crossing between the pHinitial – pHfinal curve and the pHinitial = pHfinal line give the point of zero charge value.

Many compounds, such as alcohol, phenols, ethers, and esters were detected in the GC–MS chromatogram by application of NIST library. The algae A. plumula extract analysis by GC–MS showed eleven chemical compounds as major (Fig. 2). Between these compounds, at retention time (RT) 7.11 min is compound dodecamethylcyclohexasiloxane, RT 7.92 min is compound 5-octadecenal, RT 9.39 min is compound 2,4-bis (1,1-dimethylethyl) phenol, RT 10.26 min is compound 3-hydroxyspirost-8-en-11-one, RT 13.41 min is compound estriol 16-glucuronide, and RT 14.82 min is compound 9-desoxy-9x-chloroingol-3,7,8,12-tetraacetate were identified by NIST library. The following is a hypothesis on how these bioactive chemicals encourage bio-reduction: as indicated in Scheme 1, during the early stage, the metal ions go through the activation phase, where the development rate of particles is typically slow as the metal ions are reduced from their salt precursors by the achievement of biomolecule metabolites of plant with reduction abilities. In the present study, the reduction of zinc ions happens due to the presence of biomolecules in red algae A. plumula extract such as 2,4-bis(1,1-dimethylethyl) phenol.

Phytoconstituents present in the red algae extract play a vital role in the reduction of ZnO-NPs and act as a covering agent on ZnO-NPs. FTIR analysis of synthesized ZnO-NPs is presented in Fig. 3 which verified in a wavenumber ranged between 400 and 4000 cm−1 to identify the structure of prepared green ZnO-NPs. The band at 503.43 cm−1 is matched to ZnO, confirming the formation of ZnO-NPs (Hassaan et al. 2020a, b). The peaks at 887.2, 1448.5, and 1641.4 cm−1 matched respectively to C–H, C–C, and H–O–H, and are corresponding to the presence of an organic compound. The broad band at 3462.4 cm−1 is matching to the OH, which characterises the existence of H2O molecules on the ZnO-NPs surface (Alim et al. 2005; Ashkenov et al. 2003; Xu et al. 2007; Ali et al. 2020b; Soliman et al. 2018; Salah et al. 2021).

In this approach, electrons are excited into higher energy levels as they relax back to a certain vibrational level, which offers information on the sample’s structural and vibrational features, which are supported by FTIR steps. The green synthesized ZnO-NPs are Raman active modes. In this study, ZnO-NPs show that the prominent vibration bands (secondary vibration) at 101.5, 337, 438, and 589.5 cm−1 match to the E2L, E2H–E2L, E2H, E 1 (LO) essential phonon modes of hexagonal ZnO-NPs, respectively (Fig. 4). The maximum band is 438 cm−1 corresponding to E2 mode wurtzite structured ZnO and a very sharp feature. The band at 589.5 cm−1, situated between A1 1 (LO) and E1 (LO) optical phonon mode, arises due to multi-phonon and resonance processes and is related to oxygen imperfection. Also, the acoustic combination of A1 and E2 is observed around 1155 cm−1.

Figure 5 depicts the synthesised green ZnO-NPs’ XRD diffraction pattern. The index numbers for the peaks 2 are 31.64 (100), 34.32 (002), 36.18 (101), 47.58 (102), 56.52 (110), 62.76 (103), 66.64 (200), 68.84 (201), 69.18 (201), and 77.1. All of the obtained bands approve the hexagonal structure that is consistent with the literature, proving that the powder is extremely crystalline (Hassaan et al. 2020a). Strong, sharp peaks and the absence of bands from other zinc oxide and impurity phases demonstrate the ZnO-NPs’ high purity and crystallinity. The particle sizes of the prepared green ZnO-NPs are determined by the Scherrer formula and are found to be in the range of 2.4–3.6, respectively. The Debye–Scherrer Eq. (3) uses the full width at half maximum (FWHM) of the 101 anatase band to estimate the crystallite sizes of the ZnO-NPs in Table 1 (Hassaan et al. 2020a).where Cs designates the crystallite size, λ is the XRD wavelength (1.5406 Å), θ is the Braggs’ XRD diffraction angle, and β is the FWHM in radians.

TEM was used to further investigate the form and dispersion of nanoparticles (TEM). Green ZnO-NPs with diverse nanostructures, such as needle-like and sheets (leaf-like), have been generated via green synthesis Fig. 6. One day following the preparation process, all of the TEM characterizations were completed. The particle distribution was computed after digitizing the numerous TEM images, and the outcomes were discovered to be in agreement with those of the XRD investigation.

TGA, the widely accepted method to determine the biomass thermal degradation, is used to investigate the biomass thermal stability (Sanchez-Silva et al. 2012; Carrier et al. 2011). One represents the loss of moisture from the ZnO NPs sample at temperatures between 100 and 210 °C, accounting for 0.137% of its weight, while the remaining six represent the cellulose and lignin degradation at temperatures from 210 to 950 °C, resulting in a weight loss of 0.73% of the green ZnO NPs sample as presented in Fig. 7.

Porous nature of the green ZnO-NPs is investigated using the Brunauer–Emmett–Teller (BET) surface area, as shown in Table 2 (Barrett et al. 1951; Li et al. 2022; Yılmaz et al. 2022). The surface area of ZnO NPs obtained using BET analysis is 20.111 m2/g, mono-layer volume (Vm) is 4.6206 cm3 (STP) g−1, the total volume of pores is 0.04377 cm3/g, and the mean diameter of pores (Pm) is 8.7057 nm (Fig. 8). The mesoporous material characteristics are consistent with the average pores having a diameter < 50 nm. Therefore the BJH analysis was applied to the adsorption desorption curve and the achieved data were presented in Table 2.

The sorption technique’s effective treatment of water-soluble solutions is impacted by the sorbent properties, ion selectivity of heavy metals, pH of the solution, temperature, contact time and co-existing ions. It generally varies with the sorbent properties like the size of the particles, pore-size structure, pHpzc and the precise surface area (SBET) (Wei et al. 2022). A critical regulatory factor in the sorption method is the pH value of the solution. It impacts the degree of solute ionization as well as the sorbent surface charge and the functional groups’ dissociation on the sorbent active sites (Amin 2009; Markandeya et al. 2017). The pHPZC of the sorbent was found to be 7.1, which meant that at pH below the pHPZC, the active surface sites on the sorbent were positively charged and while at pH greater than pHPZC, the active surface sites on the sorbent were negatively charged (Fig. 9a). The percentage of DB106 dye molecules sequestered as the solution pH was increased from pH 2 to 7, and subsequently decreased with increasing pH values, with the optimal sorption of dye molecules noticed at pH 7 (Fig. 9b). At low pH, the adsorption of the dye molecules to the sorbent was due to the electrostatic attraction between the protonated (H+) sites on the sorbent and the anionic dye, hence the increased removal of the molecules of dye at the acidic pH. The active sites on the sorbent get deprotonated (OH–) when the pH of the solution rises, which causes an electrostatic attraction between the anionic dye molecules and the negative charge sites on the sorbent. Thereby reduced sorption of the dye molecules observed at the basic pH. In the neutral pH (pH 7), the forces of attraction and repulsion were sidestepped and the optimum sequestration of the dye molecules to the sorbent surface sites was a result of the Van der Waals forces acting as an intermolecular force of attraction between the molecules of DB 106 dye molecules and the sorbent active surface sites (Shabaan et al. 2020). The same phenomenon noticed under the impact of pH on the adsorption DB106 dye molecules in this study was reported also in the studies by Salama et al. (2022) and Hassan et al. (2021), where the best sorption of anionic dye molecules was observed at pH 7.

The sorbent quantity is an extensive parameter in a system that impacts the rate of sorption (Shabaan et al. 2020). As observed from Fig. 10, the % of DB106 dye sequestered from the aqueous solution to the sorbent active surface sites, enhanced with increasing dosage of sorbent used (0.04–0.20 g/L) as time interaction was improved. The maximum sorption of DB106 dye molecules was noticed using the dosage of 0.20 g/L with increasing time of interaction. Enhancing the sorbent dosage led to the offering of more active surface sites on the ZnO-NPs, which improved the adsorption of DB106 dye molecules (Salama et al. 2022; Jaber and Jabbar 2021).

The impact of beginning concentration of DB106 dye on the sorption process was assessed at DB 106 dye concentrations array of 10–40 mg/L as represented in Fig. 11. It was detected that increasing the DB106 dye concentration from 10 to 40 mg/L over time, the % of DB106 dye removed decreased with increasing concentration of DB106 dye. At low DB106 dye concentrations, the number of active surface sites on the sorbent available was high relative to the DB106 dye concentration. Hence, dye molecules had sufficient active surface sites on the sorbent to interact with and occupy. With improvement in the DB106 dye concentration to 40 mg/L, the quantity of active surface sites on the sorbent available for the dye molecules was reduced, thereby leading to reduced interaction and decreased removal of dye molecules (Jaber and Jabbar 2021). The improvement in the elimination of dye molecules as the beginning dye concentration was increased was due to reduced mass transfer resistance between the water-soluble and solid stages that happens with improving the preliminary DB106 dye concentration (Amin 2009; Nourmoradi et al. 2015).

A key mass transfer factor that impacts the sorption process is the stirring or shaking speed. The impact of the shaking speed on the sequestration of DB106 dye onto the sorbent was assessed at varying shaking speeds of 50–200 rpm. Data reported in Fig. 12 show that the % of DB106 dye confiscated to the sorbent improved with increasing shaking speed as the time of shaking was increased, with optimum removal noticed using the shaking speed of 200 rpm. At low shaking speed, the time that was needed to attain equilibrium was longer and increasing the agitation speed led to an increased diffusion rate of the molecules of dyes from the majority liquid to the liquid boundary layer surrounding the particles which became above average owing to improved instability and reduced the liquid boundary layer thickness as the speed of agitation enhanced (Bhatti et al. 2015).

It was detected that the influence of temperature on the confiscation of DB106 dye improved with increasing temperatures (Fig. 13). The optimal sorption of the DB106 dye was reported at 45 °C. This was attributed to the dye solubility, which reduces as time and temperature were enhanced and thereby leading to the high rate of sorption of dye molecules to the green ZnO-NPs. Also, due to the increased mobility of the molecules of dyes at elevated temperatures led to the increased sorption of dye (Karthik et al. 2020). As reported in the study of Bhatti and Nausheen (2015), increased removal at elevated temperatures was attributed to the development in the pore numbers on the green ZnO-NPs surface. Also, the green ZnO-NPs outer surface thickness was reported to be decreased and the dye molecules kinetic energy enhanced at elevated temperatures, thereby leading to the DB106 dye molecules being effortlessly sorbed into the sorbent surface.

The adsorption kinetic is utilized to research the variation in the adsorption extent over time and this could present a basis for a process model in engineering and insight into the sorption mechanism (Eldeeb et al. 2022a, b; Aigbe et al. 2022a). To assess the sorption of DB 106 dye to ZnO-NPs, the pseudo-first-order (FO), pseudo-second-order (SO), intraparticle diffusion (ID) and film diffusion (FD) models. The data of the fitting of the linear plot of the different models are represented in Fig. 14. The coefficient of regression (R2) closeness to unity (1) was used to describe the magnitude of the determined model appropriateness to the data. From the determined parameters in Tables 3, 4, 5, and 6, using 0.2–0.3 g/L of the sorbent, it was found that the R2 values of the SO kinetic model best depicted the sorption process of DB106 dye to the sorbent in comparison to other functional models. The sorption of DB106 dye to ZnO-NPs was indicative of a chemical sorption process, which elaborates the valency forces allocation or exchange of electrons between the sorbent and sorbate (Eldeeb et al. 2022a, b; Jawad et al. 2022). Also exploring the sorption method of the DB106 dye to ZnO-NPs using ID and FD kinetic models, it was discovered that the fitting lines of these models did not pass via the origin of their various plots (Fig. 14c,d), which showed that the rate-limiting step comprises of various paths such as external diffusion did not control the adsorption of DB106 dye molecules to ZnO-NPs. The values of R2 were comparatively close to 0.9 using 0.3 g/L of the adsorbent for both models but were moderately low by 0.2 g/L of the ZnO-NPs.

To explain the sorption behaviour and get information about the mechanism of sorption, the isotherm models are applied (El Nemr et al. 2010; Aigbe et al. 2020a; Jawad et al. 2022). The Langmuir (LNR) and Freundlich (FRH) models were explored in this study to determine which model ideally described the removal of DB106 dye molecules to ZnO-NPs sorbent. The various plot of these models is shown in Fig. 15. From the determined parameters in Table 7, the LNR was more suitable in describing the sorption of dye molecules to ZnO-NPs due to their determined high R2 value. The calculated optimum sorption capacity (Qm) from LNR was 370.37 mg/g. The LNR dimensionless factor RL was assessed to be 3.3 using 10–40 mg/L dye concentration and the determined value of RL showed a favourable sorption process using ZnO-NPs for DB106 dye sorption. The adsorption process of DB106 dye ions to ZnO-NPs was owing to the monolayer sorption of DB106 dye ions to the consistent surface of the ZnO-NPs.

According to the comparison of various optimum sorption capacities for DB106 dye removal using different nanomaterials (Table 8), results show that ZnO-NPs can be employed as an effective sorbent for the sequestration of dye molecules from water medium.

The aim of the current study was to reconsider and investigate the potential benefits of utilizing green synthesized ZnO-NPs for DB106 dye removal. The basis of this study was to show how to remove DB106 dye using more widely accessible NPs. Hence, this study reports on the use of green ZnO-NPs adsorbent for DB106 dye adsorption employing the batch adsorption method under varied circumstances in a water-soluble medium. The confiscation of DB106 dye to the green synthesized ZnO-NPs adsorbent was detected to be pH-dependent, with the optimal sorption of DB106 (anionic) dye particles observed at pH 7. DB106 dye adsorption to the ZnO-NPs adsorbent was well-defined by means of the LNR and SO models, with an estimated Qm of 370.37 mg/g. The findings of the present study have proved the opportunity and capability of using inexpensive and green synthesis for ZnO-NPs fabrication for the capture of anionic dye particles such as the DB106 dye. Therefore, it is recommended that further research be done to find new, less expensive, and more environmentally friendly adsorbents that can be investigated and used to remove dyes and other harmful substances from the environment. Future studies should also focus on applying smart techniques to develop a broad and precise association for the elimination of industrially hazardous composites such as dyes from the environment.