Mool Chand,Swapnil Barthwal,Arun Singh Rawat,Manika Khanuja,Seema Rawat
Enhancing Photocatalytic Efficiency of Spent Tea Leaf Powder on ZnIn2S4 Incorporation: Role of Surface Charge on Dye Degradation
Photocatalytic degradation of dye contaminants using nanocomposite adsorbents has emerged as a promising solution for wastewater treatment. Owing to its abundant availability, eco-friendly composition, biocompatibility, and strong adsorption activity, spent tea leaf (STL) powder has been extensively explored as a viable dye-adsorbent material. In this work, we report spectacular enhancement in the dye-degradation properties of STL powder on incorporation of ZnIn2S4 (ZIS). The STL/ZIS composite was synthesized using a novel, benign, and scalable aqueous chemical solution method. Comparative degradation and reaction kinetics studies were performed onto an anionic dye, Congo red (CR), and two cationic dyes, Methylene blue (MB) and Crystal violet (CV). The degradation efficiencies of CR, MB, and CV dyes were obtained to be 77.18, 91.29, and 85.36%, respectively, using the STL/ZIS (30%) composite sample after the 120 min experiment. The spectacular improvement in the degradation efficiency of the composite was attributed to its slower charge transfer resistance (as concluded by the EIS study) and optimized surface charge (as concluded by ζ potential study). Scavenger tests and reusability tests deciphered the active species (•O2–) and reusability of the composite samples, respectively. To the best of our knowledge, this is the first report to demonstrate improvement in the degradation efficiency of STL powder on ZIS incorporation.
Enhancing Photocatalytic Efficiency of Spent Tea Leaf Powder on ZnIn2S4 Incorporation: Role of Surface Charge on Dye Degradation

Photocatalytic degradation of dye contaminants using nanocomposite adsorbents has emerged as a promising solution for wastewater treatment. Owing to its abundant availability, eco-friendly composition, biocompatibility, and strong adsorption activity, spent tea leaf (STL) powder has been extensively explored as a viable dye-adsorbent material. In this work, we report spectacular enhancement in the dye-degradation properties of STL powder on incorporation of ZnIn2S4 (ZIS). The STL/ZIS composite was synthesized using a novel, benign, and scalable aqueous chemical solution method. Comparative degradation and reaction kinetics studies were performed onto an anionic dye, Congo red (CR), and two cationic dyes, Methylene blue (MB) and Crystal violet (CV). The degradation efficiencies of CR, MB, and CV dyes were obtained to be 77.18, 91.29, and 85.36%, respectively, using the STL/ZIS (30%) composite sample after the 120 min experiment. The spectacular improvement in the degradation efficiency of the composite was attributed to its slower charge transfer resistance (as concluded by the EIS study) and optimized surface charge (as concluded by ζ potential study). Scavenger tests and reusability tests deciphered the active species (•O2–) and reusability of the composite samples, respectively. To the best of our knowledge, this is the first report to demonstrate improvement in the degradation efficiency of STL powder on ZIS incorporation.

Available freshwater amounts to less than 0.5% of all the water on earth, while its global consumption is doubling every 20 years. To ensure perpetuated water supply, wastewater must be recycled. Organic (synthetic) dyes are integral components of wastewater, and these materials have low biodegradability and cause contamination of the land and water bodies. Weathering of organic dyes via oxidation, hydrolysis, and other chemical reactions (occurring in the wastewater phase) generates toxic metabolites that impart adverse effects on the biological system. Dye molecules are carcinogenic and hazardous to human health and marine organisms, even at low concentrations. Allergic dermatitis, skin allergy, and dysfunction of the sex organs, kidney, brain, liver, and so forth are caused by toxic dye molecules. Advanced heterogeneous photocatalysis, employing semiconductor photocatalysts is a promising technology to degrade these contaminants. Semiconductor-mediated photocatalysis is an emerging sustainable technology, utilizing the solar insolation to activate the chemical reactions occurring at the surface of semiconductor catalysts. This technique mineralizes a broad range of organic dyes into harmless byproducts such as CO2, H2O, and inorganic ions. Tea is the second most consumed beverage in the world, only behind water. Spent tea leaves (STLs) are therefore available as an abundant solid waste. This material has been widely explored as a non-conventional and inexpensive adsorbent for the water contaminants (such as synthetic dyes), arsenic, cadmium, and lead. Untreated STL usually exhibit very low removal efficiencies (<10%). Thermal activation of STL (200 to 400 °C, for up to 2 h) is generally required for significant improvement in removal efficiencies (>80%). Alternate ways to improve catalytic efficiency of STL is either via chemical modification using surfactants (such as polyethyleneimine) or forming nanocomposites (such as with CuFe2O4). Compared to metal oxides, metal sulfides exhibit narrower band gap, better suited for solar light harvesting. Ternary metal sulfides, for example, ZnIn2S4 (ZIS) have become a hotspot in the field of photocatalysis due to their strong resistance to photochemical corrosion and high photocatalytic efficiencies. Hexagonal ZIS has emerged as one of the leading photocatalyst, exhibiting high photocatalytic efficiency in various types of wastewaters. In this study, the STL/ZIS composite was synthesized using a novel, cost-effective, aqueous chemical solution method at ambient temperature and pressures. We investigated comparative degradation of cationic and anionic dyes using STL/ZIS composite (with 0, 10, 20, and 30% ZIS incorporation). To the best of our knowledge, this is the first work to report the synthesis and study photocatalytic performance of STL/ZIS composite samples.

The green tea leaves (Camellia sinensis) were purchased from Shaanxi Park Road Tea Co. Ltd., China. Hydrated zinc sulfate (ZnSO4·7H2O AR, 99.0%) and potassium iodide (KI AR, 99.0%) were purchased from Pallav Chemicals & Solvents Pvt. Ltd. Indium sulfate [In2(So4)3 AR, 99.0%], thioacetamide (C2H5NS AR, 98.0%), t-butanol [(CH3)3COH AR, 99.0%], and congo red (CR) (C32H22N6Na2O6S2) were procured from Central Durg House (P) Ltd. Methylene blue (MB) (C16H18N3SCl) and crystal violet (CV) dye (C25N3H30Cl) were purchased from Thermo Fisher Scientific and Rankem brand chemical, respectively. p-Benzoquinone (C6H8O2 AR, 99.0%) was supplied by Molychem Pvt. Ltd.

To synthesize STL powder, STLs were first washed with deionized (DI) water. The cleansed leaves were then dispersed in a boiling DI water bath and kept at 80 °C. Once the leaves turn colorless (after 4–5 h), these were airlifted from the bath using a tweezer and subsequently dried for 4 h in a muffle furnace at 100 °C. The dried STLs were then crushed and grinded using a mortar pestle, leading to a light brown powdered sample. Figure 1a shows the schematic of the STL powder synthesis route.

To synthesize STL/ZIS composite samples, we have used the aqueous chemical solution method, schematically shown in Figure 1b. In this method, first, 500 mg of STL powder was dissolved in 50 mL of DI water. ZIS was synthesized using the synthesis route adopted in our previous study. Zinc sulfate (4 mmol), indium sulfate (4 mmol), and thioacetamide (20 mmol) were dissolved in 80 mL of DI water and stirred for 10 min. In next step, STL powder solution is added to ZIS solution and stirred for 30 min. The final solution was transferred to a 250 mL conical flax and put in a water-bath at 80 °C. After 4 h, the final solution was cooled down to ambient temperature and the solution was filtered using a filtration unit. The residue was washed thoroughly with ethanol, followed by DI water. The residue was then dried in muffle furnace at 60 °C for 6 h and then grinded with mortar and pestle. Finally, a light yellow-brown colored powder [STL/ZIS (10%)] was obtained, which was used in further characterization and photocatalysis study. Other samples STL/ZIS (20%) and STL/ZIS (30%) were prepared by fine-adjusting the quantity of zinc sulfate, indium sulfate, and thioacetamide into the solution.

X-ray diffraction (XRD) system (Rigaku smart lab) was used for investigating the crystallinity in the STL/ZIS composite samples. Monochromatic Cu–Ka (1.54 Å) was used for probing the samples, under applied 40 kV voltage and 40 mA current. The XRD was performed in Bragg–Brentano geometry (θ–2θ mode) and the pattern was recorded at 0.02° s–1. The field emission scanning electron microscopy (FESEM) technique [Quanta 3D FEG (FEI)] was used to determine the morphology of the powdered composite samples. Fourier transform infrared (FTIR) spectroscopy study was performed using Vertex 70 V, Bruker spectrometer. The IR absorption/transmission spectrum is crucial in identification of the functional groups and bond structure in molecules. The ζ potential of the composite sample was determined using Zetasizer Ver. 7.12 (MAL1192921) from Malvern Instruments. Electrochemical impedance spectroscopy (EIS) was conducted using a Metrohm Potentiostat/Galvanostat with a 1 M Na2SO4 electrolyte. The surface properties of the composite were analyzed using X-ray photoelectron spectroscopy (XPS) with a Thermo Scientific NEXA surface analyzer. The optical properties were analyzed using UV–visible (UV–vis) spectroscopy (Agilent Technology Cary 100 series).

A comparative photocatalytic study of both anionic (CR) and cationic (CV and MB) dyes were performed on the STL/ZIS composite under the Xenon lamp (AM 1.5 G, 100 mW/cm2). Different amounts of sample (STL/ZIS) were taken in the experiment to evaluate the degradation study. 1 mg of anionic dye (CR) and cationic dye (MG and CV) were dissolved in 100 mL of DI separately. To investigate the adsorption and photocatalysis study of the composite, the dye solution was placed in the presence and absence of the light source. To examine dye concentration, 1 mL of dye solution was taken out every 10 min (for the first hour) and every 15 min (in the next hour). The samples were analyzed using a UV–vis spectrophotometer at absorbance wavelengths of 498, 664, and 586 nm for CR, MB, and CV dyes, respectively. The dye degradation efficiency (η) was calculated using eq 1.Co represents the initial concentration of the dye solution, while C represents the concentration of the dye solution at time t.

The UV–vis absorption spectra and corresponding Tauc’s plots of STL/ZIS composites are shown in Figure 2a,b, respectively. The UV–visible absorbance peak of composites was obtained around 668 nm, which lies in the visible region. The band gap of the pure STL/ZIS composite was determined using eq 2.where α is the absorption coefficient, hυ is the photon energy, Eg is the optical band gap, and n = 2 for the (allowed) direct transaction. The band gap values were obtained from the intercept of linear region of (αhv)2 curve on the energy (hυ) axis. The (direct) band gap values calculated for STL/ZIS (10%), STL/ZIS (20%), and STL/ZIS (30%) composites are 2.09, 2.34, and 2.42 eV, respectively. Incorporating more ZIS into the STL matrix was found to extend the optical band gap (of composite) from 2.09 to 2.42 eV, approaching that of bulk ZIS.

The XRD diffractogram of the STL powder, ZIS, and STL/ZIS composite samples are illustrated in Figure 3a. The XRD results confirm the existence of two distinct phases (STL and ZIS) in the composites. All the XRD patterns exhibit one common broad peak (∼21.34°), indicating (002) planes and poor crystallinity in STL powdered samples. The relative intensity of this peak was found to decrease with the increase in STL content in the composites. The XRD pattern of composite samples exhibit three additional peaks (∼27.41, 47.33, and 58.02°), indexed as (102), (110), and (202) planes of (hexagonal) ZIS, respectively (JCPDS #03-065-2023). EDX analysis was used to examine the chemical composition and purity of the as-synthesized STL/ZIS composite. Figure 3b displays an EDX spectrum that demonstrates the presence of zinc (Zn), indium (In), sulfur (S), carbon (C), and oxygen (O) within the composite sample. The spectrum clearly demonstrates that there are no impurities present in the composite sample. As a result, both XRD and EDX analysis demonstrate that the current synthetic method is effective in synthesizing the STL/ZIS composite.

The morphologies of the synthesized STL powder and the STL/ZIS composites were investigated using FESEM studies. The FESEM micrographs are presented in Figure 4a–d. Pristine STL powder exhibits a highly diversified and porous morphology. The porous surface of the adsorbent provide a better medium for efficient adsorption of the dye molecules. On incorporating ZIS into STL matrix, the morphology becomes uniform, with apparent microspheres covering the whole surface. It is a well-known fact that the morphology of ZIS powder is typically dominated by the microspheres. On raising the amount of ZIS from 10 to 30% STL/ZIS sample, these microspheres become distinctly more visible, confirming the existence of the ZIS phase. Figure 4e,f shows the HRTEM image of an STL/ZIS (30%) composite sample at two different scales (50 and 100 nm). The interaction between STL and ZIS was directly confirmed by two contrasted regions as shown in the HRTEM images. It can be clearly seen that the morphology of composite samples is dominated by uniformly distributed microspheres.

The chemical bonding and functional groups of the composite sample were examined using FTIR spectroscopy technique. FTIR spectrum of the STL/ZIS (10, 20, and 30%) composite was recorded in the range of 500–4000 cm–1, as shown in Figure 5. The peak at 880 cm–1 in the composite was assigned to the (out of plane) C–H bending in the benzene ring. The peak centered at 1040 cm–1 was attributed to the S=O bonds. Peaks present at 1210, 1400, and 1610 cm–1 corresponds to C–N, O–H, and C=C stretching, respectively. Peaks corresponding to C=C=C, C≡C, and O=C=O bonds were centered at 2123 and 2329 cm–1. The peak at 2929 cm–1 was assigned to the deformation vibration of the N–H group. In addition, the peak at 3680 cm–1 was attributed to the hydroxyl group (O–H) stretching vibration. FTIR spectrum suggests that our synthesized sample is devoid of impurity phases.

The oxidation state and elemental composition of the STL/ZIS (30%) composite sample was examined using XPS, as depicted in Figure 6a–f. The general XPS survey confirms the presence of Zn, In, S, C, and O element in the composite sample, as shown in Figure 6a. The core-level spectra of Zn (2p) are shown in Figure 6b. The binding energies of Zn (2p) cantered at 1021.2 and 1044.4 eV correspond to the 2p3/2 and 2p1/2 states, which shows that Zn exhibits the Zn2+ oxidation state in the composite sample.Figure 6c showed the core-level spectra of the In (3d) element. The binding energies of In (3 d5/2) and In (3 d3/2) are centered at 444.5 and 452.2 eV, respectively, and results confirmed that In exists in the In3+ state. Deconvolution of the S (2p) core-level spectra is shown in Figure 6d cantered at 161.4 and 162.7 eV into two separate peaks indexed as S (2p3/2) and S (2p1/2), confirming that S occurs in the S2– state and extra peak at 164 eV indicates the sulfur oxidation. Figure 6e shows the carbon core-level spectra, and in spectra, three peaks are centered at 285.4, 286.9, and 287.4 eV corresponding to the C–OH/C–O–Zn, Csp2, and C–H, respectively. In the oxygen core-level spectra, peaks located at 531.91, 532.26, and 533.8 eV correspond to the C=O, C–O–Mo, and O–OH bonds, as shown in Figure 6f. The XPS analysis result revealed the presence of various elements (Zn, In, and S) and their chemical states, which helped to understand the chemical composition and bonding behavior of the composite sample, and indicated that the STL/ZIS sample has a high purity and a well-defined chemical structure.

EIS study of the composite was carried out to better understand the impedance behavior of the composite sample. Nyquist plot of STL and STL/ZIS (10, 20, and 30%) composites sample is shown in Figure 7. According to Nyquist plot, the STL/ZIS (30%) composite has a small semicircular arc compared to the pure STL, STL/ZIS (10%), and STL/ZIS (20%) composite, indicating that it has low charge transfer resistance (Rct). Also, the EIS plot revealed that the slope of the STL/ZIS (30%) composite was significantly higher than that of the pure STL, STL/ZIS (10%), and STL/ZIS (20%) composite, indicating that the material has a low diffusion resistance. Thus, the values of charge transfer resistance (Rct) for STL, STL/ZIS (10%), STL/ZIS (20%), STL/ZIS (30%), and ZIS were found to be 34253, 29733, 20894, 14814, and 10392 Ω. Thus, on incorporating ZIS into the STL matrix, the electron hole (e––h+) pair separation rate was improved. The improved electron hole (e––h+) pair separation rate was helpful for the photocatalytic degradation study of the composite.

ζ potential study was performed on STL powder and composite samples in order to investigate the surface charge distribution, as depicted in Figure 8. An electric charge was formed on the dispersed molecules depending on the type of particle and its surroundings. There are two zones around the particle: an inner region (stern layer) and an outer region (diffused layer). The ζ potential is used to denote the potential difference between these two zones (inner region and outer region). Surface charge plays an anchoring role during the interaction of the photocatalyst with the dye molecules. ζ potential study revealed that the STL surface was negatively charged with −24.6 mV, whereas the surface charge values of STL/ZIS (10%), STL/ZIS (20%), and STL/ZIS (30%) composites were −15.6, −8.28, and −7.57 mV, respectively. The negative surface charge on STL and composite surface is favorable for cationic (positively charge) dye adsorption due to hydrogen bonding and π–π interaction work in between amine and hydroxyl groups of dye and photocatalyst sample. In addition, the shifting of ζ potential (toward 0 eV) on ZIS incorporation also facilitates the adsorption of anionic dyes. The increase in the photocatalytic degradation efficiency of STL on incorporation of ZIS is due to the higher adsorption (via electrostatic interaction) of the negatively charged CR molecule. Electrostatics interaction is the strong interaction, dominates as compared to hydrogen bonding or π–π interaction in the CR molecule. Thus, the degradation efficiency of STL increases on incorporation of ZIS, in the case of CR dye as will be discussed in the photocatalytic study.

In this photocatalytic experiment, one anionic dye, that is, CR, and two cationic dyes, that is, MB and CV, were used for investigating the photocatalytic degradation performance. For the aforementioned study, 100 mL of each dye solution (1 mg/100 mL) and 10, 20, and 50 mg of prepared samples (STL, STL/ZIS (10%), STL/ZIS (20%), and STL/ZIS (30%) were used to investigate the adsorption and photocatalysis behavior of the samples. For photocatalysis investigations, the experiment was carried out for 120 min under a light source (Xenon lamp), whereas adsorption tests were carried out for 60 min in the dark environment. The concentration of the dye was determined using UV–vis spectroscopy, after a fixed interval of time. Figure 9a–f shows the C/Co versus time graph for CR, MB, and CV dye degradation in the absence and presence of a light source. C denotes the absorption of dye after photocatalytic activity, when exposed for time t, and Co is the absorption of dye before exposure. It is quite interesting to note that in all the samples, dye degradation was very fast in the initial 30–40 min and then slows down at the end of the experiment. Figure 9g–i shows the degradation efficiency (η) of pure STL powder, STL/ZIS (10%), STL/ZIS (20%), and STL/ZIS (30%) composites for CR, CV, and MB dyes under dark and light source, respectively. As illustrated in Figure 9g, STL perform poor degradation of the anionic dye (CR) due to the negative value of surface charge on STL. There is significant improvement on incorporation of ZIS, with degradation efficiency increasing from 9.58 to 19.37%, 49.57, and 77.58%, for STL/ZIS (10, 20, and 30%) sample, respectively. As illustrated in Figure 9h, the same trend was observed for degradation of CV dyes, degradation efficiency increasing from 65.30% (for pure STL powder) to 85.36% (for STL/ZIS 30). At the end of the experiment (120 min), the degradation efficiency of MB dye was highest (80.92%) for the STL/ZIS (30%) composite and lowest (91.28%) for STL adsorbent as shown in Figure 9i. The pristine STL sample shows intrinsically high degradation of MB dye; therefore, the improvement in degradation efficiency on incorporation of ZIS is not that significant, as in the case of CV dye. Based on the characterization results, STL/ZIS (30%) composite emerges as the optimized adsorbent, delivering best photocatalytic degradation efficiencies, in the case of both cationic and anionic dyes. As evident from the summarized reports, the novel STL/ZIS (30%) composite showed superior photocatalytic efficiency for both cationic as well as anionic dyes. All composites of STL powder were far efficient than pristine STL powder in degradation of cationic and anionic dyes. Table 1 summarizes recent studies on the photocatalytic efficiency of various agricultural waste materials. The STL/ZIS composite was found to effectively degrade both anionic and cationic dyes, outperforming previous results.

Adsorption kinetic study of anionic and cationic dyes onto the STL and STL/ZIS composite was studied using pseudo-first-order and pseudo-second-order eqs 3 and 4 as followswhere Qe and Qt are the amount of adsorbate/dye in the adsorbent (mg/g) at equilibrium time and instantaneous time (t) and calculated using eqs 5 and 6. The first-order rate constant (k1) is calculated from the slope of ln (Qe – Qt) versus time plot, whereas the second-order rate constant (k2) is calculated using the t/Qt versus time plot. Figure 10a–f shows the results of the first-order and second-order kinetics models for CR, MB, and CV dye, respectively. The pseudo-first-order process is a weak adsorption process that involved van der Waals interaction between the adsorbate and adsorbent, and in this process, no chemical interaction occurs between the adsorbate and adsorbent. This process may happen in conditions when the solution concentration is low and when equilibrium is attained. The second-order process is the chemisorption process which involves the formation of relatively strong bonds with the surfaces. In contrast, the second order kinetics model fitted well into the adsorption process for both anionic and cationic dyes. This is also confirmed by the high value of the correlation coefficient (R2), in the case of the second order kinetics model for both CR, CV, and MB dye, respectively. It suggested that the overall adsorption process is dominated by the chemisorption process and there are significant valence forces due to sharing or exchange of electrons between the photocatalyst sample and dye.

Scavenger experiment was performed to determine active species participate in photocatalytic mechanism for the degradation of dye. 1 mg of both CV and MB dye were dissolved in 100 mL of deionized water under the presence of different scavengers. Parabenzoquinone (BQ) serves as a scavenger for (•O2–), t-butanol (t-BuOH) for •OH, and potassium iodide (KI) for both hole and•OH radicals. Figure 11a–b depicts the influence of radicals on the dye degradation efficiency of the STL/ZIS composite for both CV and MB dyes. In Figure 11a, the degradation efficiency of the CV dye falls from an initial value of 82.04 to 80.83% on using t-BuOH, 79.38% on using KI, and 45.79% on using BQ. In the case of the MB dye, the degradation efficiency falls from 82.04 to 79.03% on using t-BuOH, 77% on using KI, and 34.00% using BQ, as shown in Figure 11b. The results clearly indicate considerable influence of superoxide radical (•O2–) on a photocatalytic experiment for both CV and MB dyes.

Figure 12 illustrates the mechanism of photocatalytic dye degradation in the STL/ZIS composite. During the photocatalytic process, when light with energy greater than the band gap of the photocatalyst sample is applied, an electron–hole pair is created. The holes in the conduction band react with the H2O molecule, producing the hydroxyl (•OH) radical and (h+) ion as depicted in eqs 7–9.Similarly, conduction band electron (e–) reacts with oxygen radical (O2) are produced superoxide radicle (•O2–). These radicals react with dye molecule and transform them into less harmful, nontoxic byproducts as given in eqs 10 and 11.

Reusability of the STL/ZIS (10%) composite sample was investigated on the CV dye (1 mg/100 mL), using 10 mg of composite sample, for five cycles, as shown in Figure 13. In the first cycle, the composite induced 83.98% dye degradation. Next, the photocatalytic reduction solution was filtered, washed, and dried. The cleansed samples were again employed for the reduction of fresh CV solution and the photocatalysis efficiency was noted. The experiment was performed for five cycles and the photocatalysis efficiency slightly decreased from 83.98 to 73.54% after the fifth cycle. This slight change can be attributed to the photocatalyst waste after each cycle. The recyclability test clearly illustrates that the tea leaves composite (STL/ZIS) retained its dye degradation activity even after five cycles, thus emerging as excellent candidates for reusable adsorbent for dyes.

In this work, we report the synthesis of the STL/ZIS composite using an aqueous chemical solution method and performed in-depth investigation of comparative dye degradation activity of anionic dye (CR) and cationic dyes (MB and CV). XRD, FESEM, and HRTEM results were consistent in confirming the hexagonal phase of ZIS, with ZIS microspheres incorporated into the STL matrix. The element composition and oxidation state of the composite were confirmed by XPS. All composites STL/ZIS were found far efficient than the pristine STL powder sample, in degradation of cationic and anionic dyes and STL/ZIS (30%) sample shows the superior degradation efficiency (ηCR ∼ 77.18, ηMB ∼ 85.36, and ηCV ∼ 91.29, in 120 min). Significant enhancement in photocatalytic degradation efficiency attributed to visible light response (as confirmed by tauc’s plot), optimized surface charge (as observed from ζ potential), and low charge transfer resistance as observed from EIS study. Reaction kinetics was found to follow the second-order kinetic model, and the overall adsorption process is dominated by the chemisorption process. Photocatalysis mechanism along with trapping experiment was well explained. Reusability of the materials were also examined and samples demonstrated reusable properties up to five cycles. Spectacular improvement in dye-degradation efficiency of STL powder was demonstrated on ZIS incorporation. The study demonstrates that the STL/ZIS composite might be employed as an efficient, inexpensive, and eco-friendly photocatalyst for the dye degradation and wastewater treatment applications.