diff --git a/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/0VALeNXisyk_postprocess.srt b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/0VALeNXisyk_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..dda2177c0f239f4b82514a0f256f1bb89ae7ddb0
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+++ b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/0VALeNXisyk_postprocess.srt
@@ -0,0 +1,3080 @@
+1
+00:00:05,230 --> 00:00:07,690
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:07,690 --> 00:00:11,950
+وبركاته اليوم هنكمل بمادة القياسات احنا كنا
+
+3
+00:00:11,950 --> 00:00:16,350
+للمحاضرات السابقة نحكي على ال measurement of flow
+
+4
+00:00:16,350 --> 00:00:20,770
+اترقنا لعديد من الطرق اليوم هنحكي عن طرق جديدة
+
+5
+00:00:20,770 --> 00:00:24,270
+اللي هي ال turbine meters ال turbine meters في
+
+6
+00:00:24,270 --> 00:00:29,390
+نوعين منها في ال cup type rotorsو في عندى ال
+
+7
+00:00:29,390 --> 00:00:34,270
+proper type rotors لأن ال cup قعدت تستخدم معاها
+
+8
+00:00:34,270 --> 00:00:39,410
+عادة كتير مع الهواء لما يصير flow بيعمل rotation
+
+9
+00:00:39,410 --> 00:00:44,290
+بيعمل rotation لل rotor هذا لأن انا اللي بيصير
+
+10
+00:00:44,290 --> 00:00:48,790
+يكون في عندى بعد عدد اللفات في sensor بعد عدد
+
+11
+00:00:48,790 --> 00:00:54,870
+اللفات و عدد اللفات related مع كمية ال flow كل ما
+
+12
+00:00:54,870 --> 00:01:00,530
+ال flow كان اكتركل مكان عندي إيش عدد rotations
+
+13
+00:01:00,530 --> 00:01:05,750
+أكترهذه النوع الأول هو cap type rotor النوع التاني
+
+14
+00:01:05,750 --> 00:01:08,150
+اللي هو ال propeller type rotor بيكون عندي
+
+15
+00:01:08,150 --> 00:01:13,690
+propeller الاسم ما أخد من ال propeller بتاع طيارات
+
+16
+00:01:13,690 --> 00:01:17,670
+الفراشة ال propeller اللي بيسموه ال propeller اللي
+
+17
+00:01:17,670 --> 00:01:22,590
+بيكون عندي اللي هو ال turbine rotor و فيه عندي هنا
+
+18
+00:01:22,590 --> 00:01:28,590
+بيكون منظم او فيه عندي support و هنا support و هنا
+
+19
+00:01:28,590 --> 00:01:34,710
+عندي variable reluctance pickupال rotor motion يتم
+
+20
+00:01:34,710 --> 00:01:38,410
+جسها ب variable reluctance type pickup reluctance
+
+21
+00:01:38,410 --> 00:01:43,630
+يعني تقطع مجالات مغناطسية لأن عدد مرات القطع بيعد
+
+22
+00:01:43,630 --> 00:01:51,170
+عدد مرات قطع عدد مرات القطع هذي بتتناسب مع ال flow
+
+23
+00:01:51,170 --> 00:01:57,290
+بيزيد عدد مرات القطع يعني rotation أعلى معناه تعين
+
+24
+00:01:57,290 --> 00:01:58,510
+ال flow أكتر
+
+25
+00:02:03,510 --> 00:02:06,810
+طبعا ال turbine meters هي most active flow
+
+26
+00:02:06,810 --> 00:02:10,350
+metering devices هي من أكتر الأجزاء تقع بالناحية
+
+27
+00:02:10,350 --> 00:02:15,670
+القياس لل flow high accuracy models may have
+
+28
+00:02:15,670 --> 00:02:19,670
+uncertainties of 0.25 to 0.5% نفس الخطأ بين ربعه
+
+29
+00:02:19,670 --> 00:02:23,510
+على نص في المية في حالة السوائل و بين ربعه على
+
+30
+00:02:23,510 --> 00:02:25,910
+واحد نص في المية في حالة الغزاتر
+
+31
+00:02:29,390 --> 00:02:32,330
+ال maximum to minimum flow rates are about ten to
+
+32
+00:02:32,330 --> 00:02:36,550
+one for liquids and thirty to one for gases يعني
+
+33
+00:02:36,550 --> 00:02:40,890
+بتشتغل في ال range بحيث ال minimum flow يكون عشر
+
+34
+00:02:40,890 --> 00:02:44,630
+ال maximum flow في حالة ال liquids أو ال maximum
+
+35
+00:02:44,630 --> 00:02:48,190
+flow بسوء تلاتين ضعف ال minimum flow في حالة
+
+36
+00:02:48,190 --> 00:02:48,730
+الغزاة
+
+37
+00:02:53,200 --> 00:02:56,820
+طب هيك نكون خلصنا اللي هي جزئية ال .. ال .. ال
+
+38
+00:02:56,820 --> 00:03:02,180
+flow meters أو نحكي غطينا مش كل شيء غطينا الحاجات
+
+39
+00:03:02,180 --> 00:03:06,460
+الأكثر أهمية إذا بترجعوا للكتاب في شغلات أكتر
+
+40
+00:03:06,460 --> 00:03:09,320
+بكتير من اللي أعطاناها في المحاضرات هيك نكون خلصنا
+
+41
+00:03:09,320 --> 00:03:12,700
+ال chapter طب هنكمل في مادة القياسات نحكي ع ال
+
+42
+00:03:12,700 --> 00:03:14,140
+measurement of temperature
+
+43
+00:03:16,750 --> 00:03:21,390
+في نهاية هذا ال chapter هنكون قادرين على describe
+
+44
+00:03:21,390 --> 00:03:24,410
+the primary standards of temperature هنكون قادرين
+
+45
+00:03:24,410 --> 00:03:31,530
+على وصف المعايير الأساسية لقياس الحرارة state the
+
+46
+00:03:31,530 --> 00:03:35,030
+role of fixed point calibration and necessity for
+
+47
+00:03:35,030 --> 00:03:37,410
+interpolation method in establishing a temperature
+
+48
+00:03:37,410 --> 00:03:41,250
+standard هنتعرف
+
+49
+00:03:41,250 --> 00:03:44,970
+على thermal expansion ال thermometry
+
+50
+00:03:47,100 --> 00:03:49,500
+هنتعرف على electrical resistance thermometer
+
+51
+00:03:49,500 --> 00:03:52,740
+هنتعرف
+
+52
+00:03:52,740 --> 00:03:56,000
+how to find temperature from resistance devices
+
+53
+00:03:56,000 --> 00:04:00,140
+how to analyze thermoelectric circuits designed to
+
+54
+00:04:00,140 --> 00:04:03,840
+measure temperature describe experiments to
+
+55
+00:04:03,840 --> 00:04:06,600
+determine thermoelectric potential for material
+
+56
+00:04:06,600 --> 00:04:11,240
+pairs estimate the impact of loading errors in
+
+57
+00:04:11,240 --> 00:04:14,420
+temperature measurement هذا اللي هنغطيه في هذا ال
+
+58
+00:04:14,420 --> 00:04:20,460
+chapterخلّيني أتعرف على بعض المفاهيم، إيش هي ال
+
+59
+00:04:20,460 --> 00:04:26,220
+temperature؟ ال temperature هي خاصية لأي إشي، لأي
+
+60
+00:04:26,220 --> 00:04:30,900
+object بتوصف حالة السخونة أو البرودة، ال
+
+61
+00:04:30,900 --> 00:04:34,600
+temperature خاصية لل object بتوصف حالة السخونة أو
+
+62
+00:04:34,600 --> 00:04:38,960
+البرودة لهذا ال objectطبعا عندنا zeroth law of
+
+63
+00:04:38,960 --> 00:04:43,480
+thermodynamics اذا عندى two systems in thermal
+
+64
+00:04:43,480 --> 00:04:49,420
+equilibrium يعني عندى B في حالة توازن مع A و C في
+
+65
+00:04:49,420 --> 00:04:53,580
+حالة توازن مع A معناته بيه بيه و C بيكونوا في حالة
+
+66
+00:04:53,580 --> 00:04:59,740
+توازنمنطقي توازن يعني إذا خلتهم in contact لفترة
+
+67
+00:04:59,740 --> 00:05:03,000
+طويلة حيث يقولوا نفس الحرارة B و A و C و A دلوا
+
+68
+00:05:03,000 --> 00:05:07,300
+فترة طويلة in contact مع A وصلوا نفس الحرارة مع
+
+69
+00:05:07,300 --> 00:05:12,400
+نقطة B و C نفس الحرارة طبعا ال zero's law of
+
+70
+00:05:12,400 --> 00:05:15,760
+thermodynamics provides no means for defining a
+
+71
+00:05:15,760 --> 00:05:19,780
+temperature scale مايعطينيش طرق لتعريف اللي هو
+
+72
+00:05:19,780 --> 00:05:21,100
+مقياس الحرارة
+
+73
+00:05:27,460 --> 00:05:30,660
+a temperature scale provides for three essential
+
+74
+00:05:30,660 --> 00:05:33,180
+aspects of temperature measurement يعني احنا عشان
+
+75
+00:05:33,180 --> 00:05:37,420
+نعمل temperature scale لازم يتوفر فيه الشروط
+
+76
+00:05:37,420 --> 00:05:40,680
+التالية التالية اولش definition of the size of the
+
+77
+00:05:40,680 --> 00:05:46,350
+degree تعريف الحجم ايش ال degreeتنين لازم يكون
+
+78
+00:05:46,350 --> 00:05:48,650
+عندى fixed reference points for establishing known
+
+79
+00:05:48,650 --> 00:05:51,410
+temperature لازم يكون عندى نقاط temperature او
+
+80
+00:05:51,410 --> 00:05:57,490
+نقاط temperature مرجعية عشان نعرف بداية ال scale و
+
+81
+00:05:57,490 --> 00:06:01,780
+نهاية ال scaleانا عرفت بداية ال scale و نهاية ال
+
+82
+00:06:01,780 --> 00:06:04,940
+scale و قيمة ال degree و بدى يكون عندى methods او
+
+83
+00:06:04,940 --> 00:06:08,720
+means for interpolating between fixed numerical
+
+84
+00:06:08,720 --> 00:06:10,840
+points انا عندي مثلا هاي ال minimum value و هاي ال
+
+85
+00:06:10,840 --> 00:06:15,540
+maximum value بدى يكون في دي طرق عشان اعمل تقدير
+
+86
+00:06:16,830 --> 00:06:19,910
+للدرجات الحوار بين ال minimum و بين ال maximum
+
+87
+00:06:19,910 --> 00:06:23,110
+معناته عشان يكون ال temperature ال scale لازم يكون
+
+88
+00:06:23,110 --> 00:06:26,510
+عندى definition of the size of the degree لازم
+
+89
+00:06:26,510 --> 00:06:29,590
+يكون عندى نقاط مرجعية للمinimum و للمaximum values
+
+90
+00:06:29,590 --> 00:06:33,670
+لازم يكون عندى طريقة لل interpolation بين ال fixed
+
+91
+00:06:33,670 --> 00:06:35,810
+temperature points
+
+92
+00:06:41,470 --> 00:06:44,670
+الان ال fixed point enrichers and interpolation
+
+93
+00:06:44,670 --> 00:06:50,610
+عادة بنستخدم ل triple point of water ايش هي triple
+
+94
+00:06:50,610 --> 00:06:56,050
+point؟
+
+95
+00:06:56,050 --> 00:06:59,510
+ممكن المادة تكون في احد الحالات تلقت السائل او
+
+96
+00:06:59,510 --> 00:07:05,450
+غزية او يعني لو رسمت ال face diagram للميه
+
+97
+00:07:10,010 --> 00:07:17,370
+هذا ال temperature هذا ال pressure هذا
+
+98
+00:07:17,370 --> 00:07:26,370
+ايش ال triple point هنا عندي liquid
+
+99
+00:07:26,370 --> 00:07:34,110
+هنا solid هنا حلقة زي ايه
+
+100
+00:07:34,110 --> 00:07:39,130
+عند ال triple pointالمادة ممكن تكون في الحالة
+
+101
+00:07:39,130 --> 00:07:45,470
+الصلبة أو السائلة أو الغازية هذا هي ال triple
+
+102
+00:07:45,470 --> 00:07:51,110
+point فال triple point للميه اللي هي تقريب point O
+
+103
+00:07:51,110 --> 00:07:55,710
+واحد degrees هي ممكن تكون starting point for
+
+104
+00:07:55,710 --> 00:07:58,070
+temperature scale هي نقطة البداية ل temperature
+
+105
+00:07:58,070 --> 00:08:04,070
+scale the number value assigned to this
+
+106
+00:08:04,070 --> 00:08:07,930
+temperature could be anythingأنا ال triple point
+
+107
+00:08:07,930 --> 00:08:13,570
+للميه ممكن أسميها صفر، ممكن أسميها عشرة، خمسة،
+
+108
+00:08:13,570 --> 00:08:19,070
+عشرين، تلاتين، فانا by definition يعني أنت لما
+
+109
+00:08:19,070 --> 00:08:29,350
+أحكيلك درجة انسهار الميه، صفرطب ليش مش عشرة؟ ليش
+
+110
+00:08:29,350 --> 00:08:33,850
+ناقص عشرين؟ معناه تلقط البداية أنا بعرفها بس هيكون
+
+111
+00:08:33,850 --> 00:08:38,070
+عارفة أن هي هذه درجة انسهار المي أو الانحاس أو
+
+112
+00:08:38,070 --> 00:08:42,190
+الحديد أو whatever ف the triple point of water هي
+
+113
+00:08:42,190 --> 00:08:44,770
+عبارة عن starting point for a temperature scale
+
+114
+00:08:44,770 --> 00:08:49,390
+الرقم اللي بحطه this temperature could be anything
+
+115
+00:08:51,880 --> 00:08:55,880
+في الفهران high temperature scale ال reference
+
+116
+00:08:55,880 --> 00:08:59,260
+point هذا او ال fixed point ال triple point الماية
+
+117
+00:08:59,260 --> 00:09:03,100
+قيمتها بتكون قريبة من الأتنين و تلاتين فهران high
+
+118
+00:09:07,680 --> 00:09:10,820
+الـ fixed points are defined by phase transition
+
+119
+00:09:10,820 --> 00:09:14,740
+temperatures or triple point of a pure substance
+
+120
+00:09:14,740 --> 00:09:22,580
+نقاط المرجعية الثابتة تعرف من خلال استخدام لدرجات
+
+121
+00:09:22,580 --> 00:09:25,760
+الحرارة اللي بيصير عندها تغير في الحالة تغير في
+
+122
+00:09:25,760 --> 00:09:29,160
+الحالة سواء من حالة مثلا الصلبة للسائلة أو من
+
+123
+00:09:29,160 --> 00:09:32,900
+الحالة السائلة للغازية او ممكن استخدم ال triple
+
+124
+00:09:32,900 --> 00:09:36,160
+point اللي ممكن تكون المادة في احد الحالات الصلبة
+
+125
+00:09:36,160 --> 00:09:42,390
+السائلة او غازيةمثلا the point at which pure water
+
+126
+00:09:42,390 --> 00:09:45,750
+boils at one standard atmospheric pressure is an
+
+127
+00:09:45,750 --> 00:09:49,930
+easily reproducible fixed temperature نقطة الميه
+
+128
+00:09:49,930 --> 00:09:57,630
+بتغلي عندها عن ضغط جو واحد ممكن هي نقطة سهلة ممكن
+
+129
+00:09:57,630 --> 00:10:03,160
+تكون نقطة ثابتة او نقطة مرجعيةOkay انا هحكي assign
+
+130
+00:10:03,160 --> 00:10:06,940
+this first point اللي هي درجة غليان الميه عند واحد
+
+131
+00:10:06,940 --> 00:10:12,460
+ضغط جوه القيمة مية يعني انا عرفت نقطتين نقطة اللي
+
+132
+00:10:12,460 --> 00:10:18,900
+هي الانسهار اللي هي هتكون السفر عرفت نقطة الغليان
+
+133
+00:10:18,900 --> 00:10:22,440
+الغليان انا بستخدمها للتحول من الحالة السائلة
+
+134
+00:10:22,440 --> 00:10:26,560
+للحالة الغازية مية درجة
+
+135
+00:10:29,870 --> 00:10:34,730
+بعدين define the size of the degree هعرف حجم ال
+
+136
+00:10:34,730 --> 00:10:38,490
+degree since
+
+137
+00:10:38,490 --> 00:10:41,350
+we have two fixed points in our temperature scale
+
+138
+00:10:41,350 --> 00:10:50,010
+احنا في عندنا نقطتين مرجعيات هي الصفر والمية يعني
+
+139
+00:10:51,440 --> 00:10:55,080
+ممكن انا اقسم المسافة بين الصفر و المية ل 100
+
+140
+00:10:55,080 --> 00:11:01,720
+تقسيمة واعتبرت ال size بتاع التقسيمة one degree
+
+141
+00:11:01,720 --> 00:11:07,420
+بالطريقة
+
+142
+00:11:07,420 --> 00:11:10,740
+this defines a workable scale for the measurement
+
+143
+00:11:10,740 --> 00:11:16,210
+of temperaturewe have made no provision for
+
+144
+00:11:16,210 --> 00:11:18,530
+interpolating between the two fixed point
+
+145
+00:11:18,530 --> 00:11:22,250
+temperatures احنا ماعملنا .. مافيش اش تخصيص محدد
+
+146
+00:11:22,250 --> 00:11:25,010
+لل interpolation كل اسوان البساطة انه قسمنا
+
+147
+00:11:25,010 --> 00:11:28,590
+المسافة بين الصفر والمية مية تقسيمة
+
+148
+00:11:34,730 --> 00:11:41,910
+معايير جهاز لقياس الحرارة عملية معايرة جهاز لقياس
+
+149
+00:11:41,910 --> 00:11:44,770
+الحرارة عملية معايرة جهاز لقياس الحرارة عملية
+
+150
+00:11:44,770 --> 00:11:46,310
+معايرة جهاز لقياس الحرارة عملية معايرة جهاز لقياس
+
+151
+00:11:46,310 --> 00:11:46,330
+الحرارة عملية معايرة جهاز لقياس الحرارة عملية
+
+152
+00:11:46,330 --> 00:11:46,370
+معايرة جهاز لقياس الحرارة عملية معايرة جهاز لقياس
+
+153
+00:11:46,370 --> 00:11:48,450
+الحرارة عملية معايرة جهاز لقياس الحرارة عملية
+
+154
+00:11:48,450 --> 00:11:52,290
+معايرة جهاز لقياس الحرارة عملية معfixed points
+
+155
+00:11:52,290 --> 00:11:55,750
+يعني عملية ال interpolation تتضمن ليس فقط تحديد
+
+156
+00:11:55,750 --> 00:12:00,570
+النقاط المرجعية ال .. ال .. ال start و النهاية لكن
+
+157
+00:12:00,570 --> 00:12:05,310
+برضه لازم تتضمن ال indication ل ال temperature ..
+
+158
+00:12:05,310 --> 00:12:08,670
+لأي درجة حلوة بين الدرجة .. بين اللي هي ال minimum
+
+159
+00:12:08,670 --> 00:12:13,090
+و ال maximum يعني مش ضروري يكون التقسيم عياش منتظر
+
+160
+00:12:17,420 --> 00:12:19,940
+the operation of a mercury in a glass thermometer
+
+161
+00:12:19,940 --> 00:12:22,300
+اللي هو ال .. ال .. ال thermometer العادى اللي هو
+
+162
+00:12:22,300 --> 00:12:27,040
+بيستخدم الذئبق بيكون في جوا خزان له للذئبق و فيه
+
+163
+00:12:27,040 --> 00:12:30,860
+in the capillary tube is based on the thermal
+
+164
+00:12:30,860 --> 00:12:35,840
+expansion of mercury تعتمد قياس الحرارة انه لما
+
+165
+00:12:35,840 --> 00:12:41,020
+بيسخن الذئبق بتمدد بمشي في البوب رفيع جدا فبيعطي
+
+166
+00:12:41,020 --> 00:12:44,060
+ال indication للحرارة كل ما كانت الحرارة أعلى كل
+
+167
+00:12:44,060 --> 00:12:46,220
+ما تمدد لمسافة أطول
+
+168
+00:12:54,510 --> 00:13:02,410
+الان في عندهين ميزان حرارة زئبقى imagine that we
+
+169
+00:13:02,410 --> 00:13:06,090
+submerge the thermometer in water تخيل انك غمرت
+
+170
+00:13:06,090 --> 00:13:13,010
+هذا ال thermometer في ميه .. ميه و تلج الان هذا
+
+171
+00:13:13,010 --> 00:13:17,050
+المفروض تعطيني fixed point وعملت شحطة حكيت هذا
+
+172
+00:13:17,050 --> 00:13:22,890
+الصفر عملت شحطة حكيت هذا الصفربعدين اروح اتغمرت ال
+
+173
+00:13:22,890 --> 00:13:28,090
+thermometer في ميا بتغلي كانت في حالة تغليان لأن
+
+174
+00:13:28,090 --> 00:13:31,450
+نتيجة ارتفاع الحرارة هيبدأ الذئبق يتمدد و يتافع
+
+175
+00:13:31,450 --> 00:13:34,950
+للنبوب لحد ما يثبت عند مكان معين بحط شحتة هدع
+
+176
+00:13:34,950 --> 00:13:36,510
+تبريج؟ مية
+
+177
+00:13:40,870 --> 00:13:45,310
+البرنامج لإستخدام 50 درجة بدون نقاط مرجعية يسمى
+
+178
+00:13:45,310 --> 00:13:51,330
+interpolation طريقة او عملية انه احدد درجة الخمسين
+
+179
+00:13:51,330 --> 00:13:55,230
+بدون ما استخدم نقاط مرجعية النقاط المرجعية تمثل
+
+180
+00:13:55,230 --> 00:14:00,430
+ايش triple point او transition temperature من
+
+181
+00:14:00,430 --> 00:14:05,310
+liquid state ل gas state او transition من liquid ل
+
+182
+00:14:05,310 --> 00:14:10,570
+solidالـ step list option أساسها الخيار أن أقسم
+
+183
+00:14:10,570 --> 00:14:16,230
+المسافة على ال thermometer بين السفرية بمسافات
+
+184
+00:14:16,230 --> 00:14:19,130
+متساوية يعني اذا كنت سفر واحد اتنين تلاتة اربع
+
+185
+00:14:19,130 --> 00:14:24,980
+خمسة ستة سبعة لحد ما اصل يعني هذا أبسط طريقةwe do
+
+186
+00:14:24,980 --> 00:14:27,320
+not have enough information to appropriately
+
+187
+00:14:27,320 --> 00:14:30,720
+divide the interval between 0 and 100 on the
+
+188
+00:14:30,720 --> 00:14:33,660
+thermometer into degrees لأن احنا قسمنا افترضنا
+
+189
+00:14:33,660 --> 00:14:39,280
+انه علاقة linear فعشان اكسر التقسيمة تقسيمات
+
+190
+00:14:39,280 --> 00:14:44,580
+متساوية عشان
+
+191
+00:14:44,580 --> 00:14:49,060
+اقسم صح عشان اقسم صح بالزمن a theory of the
+
+192
+00:14:49,060 --> 00:14:54,710
+behavior of the mercury in the thermometerيا اما
+
+193
+00:14:54,710 --> 00:14:58,650
+بدى افهم نظرية كيف الزئبق بتمندد و كيف علاقة مع
+
+194
+00:14:58,650 --> 00:15:03,250
+الارتفاع بالحرارة و بنانا عليها اعمل التقسيمات او
+
+195
+00:15:03,250 --> 00:15:07,610
+استخدم fixed points for calibration are necessary
+
+196
+00:15:07,610 --> 00:15:14,010
+to deserve award او استخدم نقاط تانية لتعريف درجات
+
+197
+00:15:14,010 --> 00:15:17,190
+الحرارة بين السفر والمية نقاط اللي هي fixed points
+
+198
+00:15:17,190 --> 00:15:19,190
+انسهار مثلا
+
+199
+00:15:22,880 --> 00:15:27,060
+يعني لو أخدنا مثلا المعادن، هل المعادن بتنصر على
+
+200
+00:15:27,060 --> 00:15:31,660
+نفس دالش في الحرارة؟ لأ، معناته هذه ممكن نعتبرها
+
+201
+00:15:31,660 --> 00:15:35,760
+fixed points لحد
+
+202
+00:15:35,760 --> 00:15:40,720
+نهاية القرن الثامن عشر there was no standard for
+
+203
+00:15:40,720 --> 00:15:42,780
+interpolating between fixed points in the
+
+204
+00:15:42,780 --> 00:15:47,140
+temperature scale ماكان فيه standard عشان أقرب أو
+
+205
+00:15:47,140 --> 00:15:52,650
+أوجد نقاط بين ال fixed pointsنتيجة عادة موجودة
+
+206
+00:15:52,650 --> 00:15:57,770
+standard نتج انه اذا بعمل باستخدام different
+
+207
+00:15:57,770 --> 00:16:00,470
+thermometer يعني عندى thermometer يعني مصنع من
+
+208
+00:16:00,470 --> 00:16:05,010
+اكثر من مصنع ممكن تطيني كل واحدة تراءة شكل لنفس
+
+209
+00:16:05,010 --> 00:16:07,990
+درجة الحرارة كل واحدة تطيني تراءة شكل لنفس درجات
+
+210
+00:16:07,990 --> 00:16:12,890
+الحرارة لان مافيه standard حس تقسيم و تفاصيل
+
+211
+00:16:12,890 --> 00:16:17,800
+تفاصيل ال thermometerيعني إذا بتشتري ال
+
+212
+00:16:17,800 --> 00:16:21,160
+thermometer للذقبق العادى، اشتريه من أي شركة و ..
+
+213
+00:16:21,160 --> 00:16:24,520
+و .. و اطلع عليه نفس الاشي كله تقريبا، نفس تفاصيل
+
+214
+00:16:24,520 --> 00:16:28,160
+ال design لأن معناه دلس ال behavior تعيش الذقبق
+
+215
+00:16:33,020 --> 00:16:36,120
+The definition of temperature scale is provided by
+
+216
+00:16:36,120 --> 00:16:39,040
+the international temperature scale standard of
+
+217
+00:16:39,040 --> 00:16:44,680
+1990 فسنة 1990 حطه اللي هو ال international
+
+218
+00:16:44,680 --> 00:16:48,540
+temperature scale سموه ITS-90 اللي هي
+
+219
+00:16:48,540 --> 00:16:55,040
+international temperature scale 1990 This
+
+220
+00:16:55,040 --> 00:16:57,840
+standard establishes the fixed points for
+
+221
+00:16:57,840 --> 00:17:03,180
+temperatureand provides standard procedures and
+
+222
+00:17:03,180 --> 00:17:06,540
+devices for interpolating between fixed points ال
+
+223
+00:17:06,540 --> 00:17:12,220
+ITS 90 وضع او عرف ال fixed points for temperature
+
+224
+00:17:12,220 --> 00:17:17,720
+وبرضه عرف ال standard procedures الطرق الميارية و
+
+225
+00:17:17,720 --> 00:17:20,660
+الأجهزة المستخدمة عشان نعمل interpolation between
+
+226
+00:17:20,660 --> 00:17:21,420
+fixed points
+
+227
+00:17:24,480 --> 00:17:27,820
+it establishes the Kelvin as the unit of .. for
+
+228
+00:17:27,820 --> 00:17:30,160
+the fundamental increment in temperature اللي هي
+
+229
+00:17:30,160 --> 00:17:33,080
+ال .. الوحدة الأساسية الدرشة الحرارية إيش؟ ال
+
+230
+00:17:33,080 --> 00:17:36,000
+Kelvin الوحدات التانية اللي هي ال rank يعني ال
+
+231
+00:17:36,000 --> 00:17:40,100
+Celsius الفهرمهات كلها وحدات مشتقة من ال Kelvin
+
+232
+00:17:52,670 --> 00:17:58,050
+المعارف الهو temperature fixed points as defined
+
+233
+00:17:58,050 --> 00:18:08,040
+by ITS 90 ITS 90 يعني مثلاناخد triple point of
+
+234
+00:18:08,040 --> 00:18:11,360
+hydrogen بيستوى تلتاش point تمانية سفر تلاتة تلاتة
+
+235
+00:18:11,360 --> 00:18:18,220
+ياش Kelvin ناخد لل triple point of neon هذه طبعا
+
+236
+00:18:18,220 --> 00:18:25,680
+fixed point triple point of neon أربع عشرين point
+
+237
+00:18:25,680 --> 00:18:30,400
+خمسة خمسة ستة واحد Kelvintriple point of oxygen
+
+238
+00:18:30,400 --> 00:18:33,780
+اربعة و خمسين point تلاتة خمسة تمانية اربعة Kelvin
+
+239
+00:18:33,780 --> 00:18:38,820
+triple point of argon تلاتة تمانين point تمانية
+
+240
+00:18:38,820 --> 00:18:41,920
+تمانين خمسة تمانية طبعا عشان يصل لدرجة حرارة صحيقة
+
+241
+00:18:41,920 --> 00:18:48,680
+في البرودة محتاج يستخدم ايش؟ غازات عشان يصل لدرجة
+
+242
+00:18:48,680 --> 00:18:54,080
+حرارة عاليةهيستخدم ايش؟ معادن عشان يعرف ال fixed
+
+243
+00:18:54,080 --> 00:18:57,380
+point معناته to define ال very low temperatures
+
+244
+00:18:57,380 --> 00:19:02,300
+محتاج gases او بالنسبة لنا gases عن ضغط الجو
+
+245
+00:19:02,300 --> 00:19:06,770
+العادى، مظبوطفي حالة الحرارة العالية بستخدم ال
+
+246
+00:19:06,770 --> 00:19:10,070
+fixed point temperatures اللي هي بتكون metals اللي
+
+247
+00:19:10,070 --> 00:19:13,810
+هي بالنسبة لإن عند ضغط الجو العادى بتكون في الحالة
+
+248
+00:19:13,810 --> 00:19:18,510
+صلبة معناه ال definition ليه ايش صلب او سائل او
+
+249
+00:19:18,510 --> 00:19:27,840
+غاز يعني يعتمد على الضغطيعني لما ممكن انا احكي
+
+250
+00:19:27,840 --> 00:19:32,780
+الحديد مادة صلبة، ممكن احكي الحديد مادة سائلة،
+
+251
+00:19:32,780 --> 00:19:38,580
+ممكن الحديد احكي عنه غاز الحديد، مظبوط؟ ف ال
+
+252
+00:19:38,580 --> 00:19:42,420
+definition تاع ال state ل .. ل material معينة
+
+253
+00:19:42,420 --> 00:19:49,920
+بعتمد على شغل تاني، درجة الحرارة وضغط الجوطيب
+
+254
+00:19:49,920 --> 00:19:54,100
+solid liquid equilibrium for gallium at one
+
+255
+00:19:54,100 --> 00:19:56,980
+atmospheric pressure بسهولة تلت مائة و اتنين point
+
+256
+00:19:56,980 --> 00:20:03,100
+تسعة واحد اربع ستة Kelvin solid liquid equilibrium
+
+257
+00:20:03,100 --> 00:20:07,300
+for copper at one atmospheric pressure بسهولة تلت
+
+258
+00:20:07,300 --> 00:20:08,820
+pressure بسهولة تلت مائة و اتنين point تسعة واحد
+
+259
+00:20:08,820 --> 00:20:13,840
+اربع ستة Kelvin هذا هي fixed point temperatures
+
+260
+00:20:13,840 --> 00:20:17,040
+استخدمها ال ITS 90
+
+261
+00:20:19,540 --> 00:20:24,900
+to define اللي هو ال fixed point temperatures طبعا
+
+262
+00:20:24,900 --> 00:20:29,800
+في other
+
+263
+00:20:29,800 --> 00:20:32,240
+fixed points of secondary importance are available
+
+264
+00:20:32,240 --> 00:20:35,120
+ل ITS طبعا في هذه ليس فقط ال fixed point اللي احنا
+
+265
+00:20:35,120 --> 00:20:38,080
+شايفينه ال table هذا فيه تانية موجودة ل ال
+
+266
+00:20:38,080 --> 00:20:42,000
+materials تانية عرفت باستخدام ال ITS 90
+
+267
+00:20:47,150 --> 00:20:49,230
+along with the fixed temperature points
+
+268
+00:20:49,230 --> 00:20:54,630
+established by the ITS 90 بالموازاة لإستخدامنا لـ
+
+269
+00:20:54,630 --> 00:20:58,630
+fixed point temperatures المعرفة بالـ ITS 90 a
+
+270
+00:20:58,630 --> 00:21:01,290
+standard for interpolating between these fixed
+
+271
+00:21:01,290 --> 00:21:05,710
+points is necessary نفس ال ITS حط معيار عشان تعمل
+
+272
+00:21:05,710 --> 00:21:08,890
+interpolation between these fixed points
+
+273
+00:21:11,680 --> 00:21:18,840
+for tim richards من درجات حرارة بين 13.8033 ل1234
+
+274
+00:21:18,840 --> 00:21:25,280
+.9 kelvin نروح لطالعة ال table 13.8033 ايش هي
+
+275
+00:21:25,280 --> 00:21:33,880
+triplet of hydrogen وال1234 اللي هي solid liquid
+
+276
+00:21:33,880 --> 00:21:37,880
+equilibrium for silver للفضة عند واحد عند واحد
+
+277
+00:21:37,880 --> 00:21:43,010
+atmospheric pressurefor temperatures من ال point
+
+278
+00:21:43,010 --> 00:21:47,130
+الهيدروجيني لل liquid solid transition temperature
+
+279
+00:21:47,130 --> 00:21:52,370
+للفضة ITS90
+
+280
+00:21:52,370 --> 00:22:00,450
+استخدم ثروميتر
+
+281
+00:22:00,450 --> 00:22:04,140
+بيعتمد على التغير في المقاومةالمقامة المعادن
+
+282
+00:22:04,140 --> 00:22:07,880
+بتتغير مع التغير بدرجة الحرارة طبعا استخدم ال
+
+283
+00:22:07,880 --> 00:22:12,440
+plutanium as the standard interpolating instrument
+
+284
+00:22:12,440 --> 00:22:15,760
+يعني استخدم ال plutanium resistance thermometer
+
+285
+00:22:15,760 --> 00:22:22,460
+عشان نعمل interpolation بين ال fixed pointsand
+
+286
+00:22:22,460 --> 00:22:26,300
+establishes interpolating equations that relate
+
+287
+00:22:26,300 --> 00:22:31,560
+temperature to resistance وطبعا وضع معدلات عشان
+
+288
+00:22:31,560 --> 00:22:37,580
+تحسب الدرجات الحرارة مع التغير في قيمة المقارنة
+
+289
+00:22:39,670 --> 00:22:47,230
+أكتر above 1234.93 Kelvin temperature is defined
+
+290
+00:22:47,230 --> 00:22:51,990
+in terms of black body radiation يعني استخدم أجهزة
+
+291
+00:22:51,990 --> 00:22:55,490
+قياس تعتمد على الإشعاع تعتمد على الإشعاع
+
+292
+00:23:08,290 --> 00:23:12,090
+طيب ال present standards for fixed point
+
+293
+00:23:12,090 --> 00:23:17,650
+temperatures and interpolation allow for practical
+
+294
+00:23:17,650 --> 00:23:20,290
+and accurate measurements of temperature اللي هي
+
+295
+00:23:20,290 --> 00:23:22,930
+المعايير المستخدمة حاليا لل fixed point
+
+296
+00:23:22,930 --> 00:23:31,190
+temperatures بتوفرنا يعني طرق قياس عملية و دقيقة
+
+297
+00:23:31,190 --> 00:23:35,840
+لدرجة الحرارة في الولايات المتحدةThe National
+
+298
+00:23:35,840 --> 00:23:39,180
+Institute of Standards and Technology ال NIST
+
+299
+00:23:39,180 --> 00:23:44,660
+provides for means to obtain accurately calibrated
+
+300
+00:23:44,660 --> 00:23:47,580
+plutonium wire thermometers for use as secondary
+
+301
+00:23:47,580 --> 00:23:51,100
+standards in the calibration of a temperature
+
+302
+00:23:51,100 --> 00:23:56,000
+measuring system بيستخدمه اللي هي أسلاك لبلتانيوم
+
+303
+00:23:56,000 --> 00:24:03,360
+كأجهزة لقياس الحرارة عشان أعمل معايرةللأجزة القياس
+
+304
+00:24:03,360 --> 00:24:06,940
+الأخرى طبعا في أجزة قياس مختلفة ليس فقط
+
+305
+00:24:06,940 --> 00:24:10,480
+البلوتينيوم بس البلوتينيوم اعتمد ك standard او
+
+306
+00:24:10,480 --> 00:24:15,720
+كمعيار لمعارة الأجزة الأخرى
+
+307
+00:24:15,720 --> 00:24:20,320
+لأن طرق قياس الحرارة في عندي thermometer based on
+
+308
+00:24:20,320 --> 00:24:23,460
+thermal expansion اللي هو قياس الحرارة اعتمادا على
+
+309
+00:24:23,460 --> 00:24:28,020
+التمدد الحراري قياس الحرارة اعتمادا على التمدد
+
+310
+00:24:28,020 --> 00:24:33,440
+الحراريmost materials exhibit a change in size
+
+311
+00:24:33,440 --> 00:24:36,440
+with changes in material and temperature معظم
+
+312
+00:24:36,440 --> 00:24:42,400
+المواد بيصير فيها تغير بالحجم نتيجة التغير
+
+313
+00:24:42,400 --> 00:24:47,140
+بالحرارة إذا ارتفعت الحرارة حجمها بزيد وإذا نزلت
+
+314
+00:24:47,140 --> 00:24:49,260
+الحرارة حجمها بقل
+
+315
+00:24:56,590 --> 00:25:00,190
+اقل الميه يعني لما نكون قريبين من السفر و نبرد
+
+316
+00:25:00,190 --> 00:25:05,870
+حجمها ايش بزيدي the liquid in a glass .. the
+
+317
+00:25:05,870 --> 00:25:08,930
+liquid in a glass thermometer and the bi-metallic
+
+318
+00:25:08,930 --> 00:25:13,410
+thermometers are based on this principle اللي هو
+
+319
+00:25:13,410 --> 00:25:18,350
+ال thermometer الذجاجي اللي بيعتمد على الذئبق و ال
+
+320
+00:25:18,350 --> 00:25:23,750
+bi-metallic thermometerفكرتهم معتمدة عن انه .. ال
+
+321
+00:25:23,750 --> 00:25:29,050
+.. انه بيصير تمدد للمادة او انكماش للمادة نتيجة
+
+322
+00:25:29,050 --> 00:25:38,130
+تغير بدرجة الحرارة ال
+
+323
+00:25:38,130 --> 00:25:43,870
+liquid and glass thermometers اللي هو ال .. اجهزة
+
+324
+00:25:43,870 --> 00:25:49,300
+قياس الحرارة بتعتمد على ايش؟ على الذئبقLiquid in a
+
+325
+00:25:49,300 --> 00:25:53,720
+glass thermometer measures temperature by virtue
+
+326
+00:25:53,720 --> 00:25:58,320
+of their expansion over liquid الأجزات بتعتمد في
+
+327
+00:25:58,320 --> 00:26:05,740
+قياس على حرارة على تمدد لسائل بعرف الحرارة بتتمدد
+
+328
+00:26:05,740 --> 00:26:10,210
+السائل فبتعطي indication لدرجة الحرارةلأن في
+
+329
+00:26:10,210 --> 00:26:17,850
+عندهين ال bulb بتاعت بتمثل لخزان بوفر كمية كافية
+
+330
+00:26:17,850 --> 00:26:21,990
+من ال liquid لأن في عندهين طبعا في عند ال
+
+331
+00:26:21,990 --> 00:26:26,870
+capillary tube في عنده نبوبة شعرية .. نبوبة شعرية
+
+332
+00:26:26,870 --> 00:26:35,030
+لأن لما أغمر ال .. ال thermometer في البيئة اللي
+
+333
+00:26:35,030 --> 00:26:38,510
+بيداقش حرارتها إذا .. إذا كانت البيئة سخنة حيصير
+
+334
+00:26:38,510 --> 00:26:44,750
+إياشتمدد لل liquid لحد ما تصير في حالة اتزان مع
+
+335
+00:26:44,750 --> 00:26:47,830
+البيئة احنا عشان ذكرنا ايش ال law of
+
+336
+00:26:47,830 --> 00:26:52,810
+thermodynamics انت بتقيص الحرارة من خلال انك تصل
+
+337
+00:26:52,810 --> 00:26:58,570
+لحالة توازن بين الجهاز المستخدم في القياس والبيئة
+
+338
+00:26:58,570 --> 00:27:04,610
+اللي بدها تقيص حرارتها ده بتصل لحالة توازن بين
+
+339
+00:27:04,610 --> 00:27:08,790
+البيئة المراد قياس درجة حرارتها والجهاز المستخدم
+
+340
+00:27:08,790 --> 00:27:15,460
+في القياسمعناته ال bulb بتشتغل كخزان بيعطيني كمية
+
+341
+00:27:15,460 --> 00:27:21,460
+كافية للسائل بحيث انه لو اتمدد يكون عندي كمية
+
+342
+00:27:21,460 --> 00:27:31,620
+كافية لانها تمشي في النبوبة الشعرية طبعا
+
+343
+00:27:31,620 --> 00:27:36,380
+ال .. النصل هذا هو ال stem بيحتوي على نبوب شعري
+
+344
+00:27:37,760 --> 00:27:43,720
+رفيع محتوى البوب شعري رفيع ال difference in
+
+345
+00:27:43,720 --> 00:27:46,240
+thermal expansion between the liquid and the glass
+
+346
+00:27:46,240 --> 00:27:52,600
+لان فى عندى تمدد حرارى اللى للزجاج نفسه وفى تمدد
+
+347
+00:27:52,600 --> 00:27:56,580
+حرارى اللى لاقياش لل liquid للزقبق ال difference
+
+348
+00:27:56,580 --> 00:27:58,820
+in the thermal expansion between the liquid and
+
+349
+00:27:58,820 --> 00:28:01,900
+the glass produces a detectable change in the
+
+350
+00:28:01,900 --> 00:28:04,640
+liquid لان الفرق في تمدد الحرارى بين الزجاج
+
+351
+00:28:04,640 --> 00:28:06,900
+والسائل بيعطيني
+
+352
+00:28:09,530 --> 00:28:15,110
+يعني تغير ملحوظ في ارتفاع ال liquid في النبوبة
+
+353
+00:28:15,110 --> 00:28:24,210
+الشعرية اللي بتمكنها من قياس درجة الحرارة during
+
+354
+00:28:24,210 --> 00:28:28,270
+calibration خلال عملية المعايرة في المصنع لل
+
+355
+00:28:28,270 --> 00:28:33,310
+thermometer such a thermometer is subject to one
+
+356
+00:28:33,310 --> 00:28:34,910
+of three measuring environments
+
+357
+00:28:37,370 --> 00:28:42,430
+خلال عملية المعايرة للجهاز ممكن اعمله complete
+
+358
+00:28:42,430 --> 00:28:49,950
+immersion او total immersion ايش؟ غمر complete
+
+359
+00:28:49,950 --> 00:28:55,650
+immersion او total immersion او partial immersion
+
+360
+00:28:57,200 --> 00:29:01,120
+ال complete immersion بحط يعني بكون ال thermometer
+
+361
+00:29:01,120 --> 00:29:03,820
+كله مغمور في البيئة عشان انا بده اقيس ده عشان
+
+362
+00:29:03,820 --> 00:29:06,560
+حرارة ميه بيكون مغمور كله في الميه هذا complete
+
+363
+00:29:06,560 --> 00:29:14,900
+immersion ال total immersion بغطس ال thermometer
+
+364
+00:29:14,900 --> 00:29:18,300
+في
+
+365
+00:29:18,300 --> 00:29:22,560
+الميه للرتفاع اللي بيعطيني درجة القياس الحرارة
+
+366
+00:29:23,660 --> 00:29:26,040
+الارتفاع طيب القياس الحياة مثلا انا بغمر شوية
+
+367
+00:29:26,040 --> 00:29:30,220
+بغطسها شوية و بطلع بيه على لسه ال fluid في ال
+
+368
+00:29:30,220 --> 00:29:33,620
+thermotube بنزلها كمان شوية بنزل بنزل لحد مستير
+
+369
+00:29:33,620 --> 00:29:37,260
+اللي .. اللي .. اللي هو ارتفاع ال liquid في ال
+
+370
+00:29:37,260 --> 00:29:41,000
+calcium نفس الارتفاع المغمور هذا هو ال total
+
+371
+00:29:41,000 --> 00:29:47,420
+immersion في ال partial immersion الغمر الجزء ان
+
+372
+00:29:47,420 --> 00:29:51,780
+انا خلاص كمصنع بحكي بدك تغمره لحد الارتفاع هذا هذا
+
+373
+00:29:51,780 --> 00:29:56,820
+ال predetermined amountفممكن فال .. ال .. ال ..
+
+374
+00:29:56,820 --> 00:30:01,700
+التمدد يصير اعلى .. اعلى اللي هي هذه القيمة هذه
+
+375
+00:30:01,700 --> 00:30:07,320
+سمى ايش partial immersion طبعا الموضوع اللي تشوفوه
+
+376
+00:30:07,320 --> 00:30:11,680
+انتوا من انت نوعيا هل هو partial ولا total ولا
+
+377
+00:30:11,680 --> 00:30:18,560
+complete partial partial هل يوجد فرد بينهم في
+
+378
+00:30:18,560 --> 00:30:22,040
+الفكرة ده ولا .. اه هو ايش الفكرة ان انت
+
+379
+00:30:24,760 --> 00:30:30,520
+عشان تستخدم هذا الجهاز في القياس لازم تعمله غمر
+
+380
+00:30:30,520 --> 00:30:35,000
+بنفس الطريقة اللى تمت فيها المعايرة فالمفروض
+
+381
+00:30:35,000 --> 00:30:39,000
+المصنع يحكي ان انا خلال ال calibration ان هذا ال
+
+382
+00:30:39,000 --> 00:30:43,720
+thermometer عملتله complete immersion او total
+
+383
+00:30:43,720 --> 00:30:48,210
+immersion او partial immersionإذا هو عمل complete
+
+384
+00:30:48,210 --> 00:30:51,390
+immersion، بدك تحطه في تمر كام في البيئة، إذا هو
+
+385
+00:30:51,390 --> 00:30:55,590
+عمل partial immersion، بدك تعمله إيش؟ partial
+
+386
+00:30:55,590 --> 00:30:58,870
+immersion
+
+387
+00:30:58,870 --> 00:31:02,670
+بالظبط
+
+388
+00:31:09,430 --> 00:31:12,590
+حسب ال maximum level لدرجة الحرارة يعني مثلا لو
+
+389
+00:31:12,590 --> 00:31:17,670
+الجهاز معيّر ل ميت درجة أو نحكي الجهاز بتاع قياس
+
+390
+00:31:17,670 --> 00:31:22,710
+درجة حرارة الإنسان معيّر لحد خمسين درجة نحكي طيب
+
+391
+00:31:22,710 --> 00:31:30,550
+أفرض حطيت سخنت لمية إيش هيصير؟ طيب
+
+392
+00:31:30,550 --> 00:31:34,130
+وضلتني أسخن .. وضلتني أسخنالنبوب الشلال ممكن
+
+393
+00:31:34,130 --> 00:31:38,050
+ينفجر؟ حينفجر، النبوب حينفجر، لأ حينفجر لإن هو
+
+394
+00:31:38,050 --> 00:31:41,550
+بيحاول يتمدد و في إيش بيمنعه، فهيت .. هيتكسر
+
+395
+00:31:41,550 --> 00:31:47,450
+الذجاج بتاعياش ال .. الجهاز يعني أنا بكون عارف
+
+396
+00:31:47,450 --> 00:31:50,620
+الضوء هذا مثلا متقيص لحد درجة الحرارة؟أه طبعا أي
+
+397
+00:31:50,620 --> 00:31:54,140
+جهاز له range معين للقياس والله هذا الجهاز بيقيص
+
+398
+00:31:54,140 --> 00:31:59,800
+من مثلا من صفر لخمسمية هذا الجهاز بيقيص مثلا من ..
+
+399
+00:31:59,800 --> 00:32:04,100
+من متين لاربعمية فهذه بتكون معلومات معرفة أو معرفة
+
+400
+00:32:04,100 --> 00:32:08,760
+من المصنعFor the most accurate temperature
+
+401
+00:32:08,760 --> 00:32:11,380
+measurement, the thermometer should be immersed in
+
+402
+00:32:11,380 --> 00:32:14,540
+the same manner in use as it was during
+
+403
+00:32:14,540 --> 00:32:18,120
+calibration عشان أحصل على نتيجة قراءة دقيقة لدرجة
+
+404
+00:32:18,120 --> 00:32:22,300
+الحرارة لازم يغمر ال thermometer بنفس الطريقة اللي
+
+405
+00:32:22,300 --> 00:32:24,160
+تمت خلال عملية المعايرة
+
+406
+00:32:28,120 --> 00:32:30,700
+Practical measurements using liquid in a glass
+
+407
+00:32:30,700 --> 00:32:33,000
+thermometer typically result in total
+
+408
+00:32:33,000 --> 00:32:36,040
+uncertainties that range from 0.2 to 2 degrees
+
+409
+00:32:36,040 --> 00:32:39,620
+depending on the specific instrument يعني نسبة
+
+410
+00:32:39,620 --> 00:32:43,580
+الخطأ في liquid in a glass thermometer تطارع بين 2
+
+411
+00:32:43,580 --> 00:32:46,560
+من 10 لدرجتين
+
+412
+00:32:55,710 --> 00:32:58,950
+النوع التاني اللى بيعتمد على التماد الحرارى اللى
+
+413
+00:32:58,950 --> 00:33:05,710
+هو ال bi-metallic thermometer بيكون القطعة اللى
+
+414
+00:33:05,710 --> 00:33:10,510
+بتجس الحرارة مكونة من شريحتين شريحة اللى هى معدن A
+
+415
+00:33:10,510 --> 00:33:16,610
+وشريحة معدن B والصمغ الكلي ملتسقين مع بعض طبعا يتم
+
+416
+00:33:16,610 --> 00:33:21,990
+لسقهم اللى هى bonded at temperature T1 عند
+
+417
+00:33:21,990 --> 00:33:27,410
+temperature T1 بيكونال two strips straight بيكون
+
+418
+00:33:27,410 --> 00:33:32,150
+مستقيمة مثلا سارة الحام عند مثلا خمسة و عشرين درجة
+
+419
+00:33:32,150 --> 00:33:36,410
+مثلا او عند تلاتين درجة او عند مية whatever درجة
+
+420
+00:33:36,410 --> 00:33:40,290
+حرارة عند درجة .. درجة حرارة اللي تم لحام القطعة
+
+421
+00:33:40,290 --> 00:33:44,250
+تقرير مع بعض بيكون اللي عند ال strip عشان تكون
+
+422
+00:33:44,250 --> 00:33:50,560
+مستقيمةال metal A بيكون معامل التمدد الحراري
+
+423
+00:33:50,560 --> 00:33:57,780
+thermal expansion ل A أكتر من B يعني A بتمدد لو
+
+424
+00:33:57,780 --> 00:34:02,860
+سخنا سناخ delta T معينة ال metal A بتمدد أكتر من
+
+425
+00:34:02,860 --> 00:34:06,460
+metal B معناته إذا ال metal A بتمدد أكتر معناته
+
+426
+00:34:06,460 --> 00:34:10,650
+هتصير تقوساذا ارتفعت الحرارة هصير تقوس لان ايه
+
+427
+00:34:10,650 --> 00:34:16,790
+هيتمدد اكتر من B فهيصير تقوس اذا صار انخفار درجته
+
+428
+00:34:16,790 --> 00:34:25,450
+الحرارة هصير ال curvature H بالعكس مظبوط فانا
+
+429
+00:34:25,450 --> 00:34:36,530
+اللي بقيسه اللي هو ال radius of curvature RC طيب
+
+430
+00:34:38,420 --> 00:34:40,840
+الارسى اللى هو ال radius of curvature يُعطى
+
+431
+00:34:40,840 --> 00:34:46,100
+بالعلاقة بستوى D على C Alpha A معناه C Alpha B في
+
+432
+00:34:46,100 --> 00:34:51,840
+T2 ناقص T1 الارسى اللى هو ال radius of curvature
+
+433
+00:34:51,840 --> 00:34:59,820
+ال D اللى هو ال thickness لل two strips مع بعض ال
+
+434
+00:34:59,820 --> 00:35:05,990
+C Alpha A معامر التمدد الحرارى لل metal Aوالـ CαB
+
+435
+00:35:05,990 --> 00:35:08,310
+معامل تمد الحريل المتل B
+
+436
+00:35:18,060 --> 00:35:21,200
+الـ bi-metallic strips employ one metal having a
+
+437
+00:35:21,200 --> 00:35:23,960
+high coefficient of thermal expansion and another
+
+438
+00:35:23,960 --> 00:35:29,700
+having a low .. a low coefficient يعني بتكون كوّن
+
+439
+00:35:29,700 --> 00:35:32,680
+من two strips، واحدة ال strip اللي هو معاملة تمد
+
+440
+00:35:32,680 --> 00:35:35,380
+الحرارة إليها عالي والسترة التانية معاملة تمد
+
+441
+00:35:35,380 --> 00:35:37,140
+الحرارة إليها أياش منخفضة
+
+442
+00:35:39,460 --> 00:35:43,500
+بستخدم السفيكة عادة اسمها invar ممكن تدور عليها
+
+443
+00:35:43,500 --> 00:35:48,860
+سفيكة معدن invar is often used as one of the
+
+444
+00:35:48,860 --> 00:35:53,600
+metals المعاملة دي الحرارة لمادة ال invar بصواحة
+
+445
+00:35:53,600 --> 00:35:56,980
+بين سبعة في عشر او اصلاق اس تمانية متر لكل متر لكل
+
+446
+00:35:56,980 --> 00:36:02,400
+degree الان
+
+447
+00:36:02,400 --> 00:36:08,350
+طبعا ال invar معاملة مادة الحرارة بنخفضيعني بيمثل
+
+448
+00:36:08,350 --> 00:36:14,250
+metal B بيستخدم معاه metal A زي steel مثلا ال
+
+449
+00:36:14,250 --> 00:36:17,530
+steel معاملة تمدد الحرارة لل steel يتراوح بين
+
+450
+00:36:17,530 --> 00:36:21,930
+اتنين في عشر أثنات وخمسة لعشرين في عشر أثنات وخمسة
+
+451
+00:36:21,930 --> 00:36:25,530
+يعني واضح معاملة تمدد الحرارة ل B اللي هو زي ال
+
+452
+00:36:25,530 --> 00:36:29,770
+steel أعلى بكتير من ال environment نتشق اختلاف
+
+453
+00:36:29,770 --> 00:36:33,350
+تمدد الحرارة بيصير التقوس بقيس التقوس فاهم انها من
+
+454
+00:36:33,350 --> 00:36:35,230
+معرفتي للتقوس بعرف درجة الحرارة
+
+455
+00:36:42,840 --> 00:36:45,880
+الـ Thermometers اللي بتستخدم .. فكرتتي بتعتمد على
+
+456
+00:36:45,880 --> 00:36:51,140
+الـ bimetallic strip ممكن تعطيه نسبة خطأ one
+
+457
+00:36:51,140 --> 00:36:58,700
+degree نسبة خطأ one degree النوع
+
+458
+00:36:58,700 --> 00:37:01,540
+التالت اللي هي ال electrical resistance
+
+459
+00:37:01,540 --> 00:37:04,640
+thermometer
+
+460
+00:37:08,330 --> 00:37:11,610
+Electrical resistance of a conductor or
+
+461
+00:37:11,610 --> 00:37:15,350
+semiconductor varies with temperature.الان مقامة
+
+462
+00:37:15,350 --> 00:37:20,730
+.. المقامة الكهربائية لمادة موصلة أو مادة شبه
+
+463
+00:37:20,730 --> 00:37:24,110
+موصلة تتغير مع التغيير بدرجة الحرارة
+
+464
+00:37:28,170 --> 00:37:32,570
+طبعا ما زال في اشي سهل القياس زي المقاومة الحرية
+
+465
+00:37:32,570 --> 00:37:40,870
+قياس لتغير بالمقاومة يعتبر قياس لتغير درجة الحرارة
+
+466
+00:37:40,870 --> 00:37:44,090
+لان عندي two basic classes of resistance
+
+467
+00:37:44,090 --> 00:37:47,170
+thermometers في نوعين .. عائلتين أساسيات من
+
+468
+00:37:47,170 --> 00:37:51,450
+resistance thermometers فعندي ما يسمى resistance
+
+469
+00:37:51,450 --> 00:37:56,310
+temperature detectorsاللي هي RTD عادة بتكون هذه
+
+470
+00:37:56,310 --> 00:37:59,310
+معادل مواصلة الحرارة Resistance Temperature
+
+471
+00:37:59,310 --> 00:38:04,290
+Detectors RTD فاندي thermistors اللي هي semi
+
+472
+00:38:04,290 --> 00:38:08,050
+conductors مواد شبه مواصلة معناته two basic
+
+473
+00:38:08,050 --> 00:38:10,690
+classes of resistance thermometers اللي هي
+
+474
+00:38:10,690 --> 00:38:14,330
+resistance temperature detectors RTD وفاندي
+
+475
+00:38:14,330 --> 00:38:18,290
+thermistors اللي هي مواد شبه مواصلة semi
+
+476
+00:38:18,290 --> 00:38:18,930
+conductors
+
+477
+00:38:23,860 --> 00:38:29,270
+RTDS اللي هي Resistance Temperature Detectorsmay
+
+478
+00:38:29,270 --> 00:38:33,990
+be formed from a solid metal wire ممكن يتم تشكيله
+
+479
+00:38:33,990 --> 00:38:38,670
+من solid metal wire that exhibits an increase in
+
+480
+00:38:38,670 --> 00:38:41,770
+electrical resistance و temperature دي يعني ال RTD
+
+481
+00:38:41,770 --> 00:38:45,510
+اللي هي اللي احنا حكينا عنها resistance
+
+482
+00:38:45,510 --> 00:38:52,270
+temperature detector ممكن يكون عبارة عن سلك مصمت
+
+483
+00:38:52,270 --> 00:38:54,250
+اللي
+
+484
+00:38:55,480 --> 00:39:01,820
+مقاومته بزيد مع الارتفاع بدرجة الحرارة depending
+
+485
+00:39:01,820 --> 00:39:04,720
+on .. depending on the material selected the
+
+486
+00:39:04,720 --> 00:39:07,400
+resistance may increase or decrease with
+
+487
+00:39:07,400 --> 00:39:13,140
+temperature مش دايما المقاومة بتزيد مع بعض أحيان
+
+488
+00:39:13,140 --> 00:39:18,240
+بتقل لأن هل بتقل أو بتزيد بعتمد على اختيارنا ..
+
+489
+00:39:18,240 --> 00:39:21,860
+اختيارنا لل material في materials ال resistance
+
+490
+00:39:23,140 --> 00:39:27,120
+بتزيد مع ازياد بالحرارة وفي materials ال
+
+491
+00:39:27,120 --> 00:39:34,880
+resistance بتقل مع الارتفاع مع دلش الحرارة الان ال
+
+492
+00:39:34,880 --> 00:39:37,000
+resistance change of a thermistor ال thermistor
+
+493
+00:39:37,000 --> 00:39:40,100
+الحاكي انا هو مادة مواصلة و لا شبه مواصلة او اشبه
+
+494
+00:39:40,100 --> 00:39:43,450
+مواصلة او شبه مواصلةالـ resistance change of a
+
+495
+00:39:43,450 --> 00:39:46,810
+thermistor may be expressed as R minus R node
+
+496
+00:39:46,810 --> 00:39:52,130
+بستوى K في T minus T node الـ key temperature
+
+497
+00:39:52,130 --> 00:39:59,970
+coefficient والـ R node هي المقاومةعند reference
+
+498
+00:39:59,970 --> 00:40:06,310
+temperature T node و ال R هي ال resistance عند
+
+499
+00:40:06,310 --> 00:40:08,730
+درجة حرارة معينة اي درجة حرارة ال R هي ال
+
+500
+00:40:08,730 --> 00:40:11,550
+resistance at any temperature ال R node هي ال
+
+501
+00:40:11,550 --> 00:40:16,030
+resistance at reference temperature T node و ال K
+
+502
+00:40:16,030 --> 00:40:17,670
+temperature coefficient
+
+503
+00:40:19,860 --> 00:40:22,760
+a thermistor may have a positive temperature
+
+504
+00:40:22,760 --> 00:40:26,540
+coefficient PTC or a negative temperature
+
+505
+00:40:26,540 --> 00:40:30,460
+coefficient NTC يعني ممكن يكون ال K موجب بس بيبقى
+
+506
+00:40:30,460 --> 00:40:37,040
+positive temperature coefficient أو ال K ممكن يكون
+
+507
+00:40:37,040 --> 00:40:43,060
+سالب يعني إذا كان عند ال R
+
+508
+00:40:49,560 --> 00:40:59,500
+بالساوية R mod زائد K في T minus T مجلد يعني ال K
+
+509
+00:40:59,500 --> 00:41:04,940
+ممكن يكون ايش positive اذا
+
+510
+00:41:04,940 --> 00:41:08,360
+positive معناه ان ال resistance بيزيد وعشان
+
+511
+00:41:08,360 --> 00:41:15,260
+الحرارة او ممكن يكون ال K negative معناه تواضح كل
+
+512
+00:41:15,260 --> 00:41:17,820
+منزلز الحرارة ايش بتقل ال resistance
+
+513
+00:41:26,850 --> 00:41:33,150
+ع ال material احنا كنا في مواد مقاومتها بتزيد مع
+
+514
+00:41:33,150 --> 00:41:37,650
+الارتفاع بالحرارة وفي مواد مقاومتها بتقل مع
+
+515
+00:41:37,650 --> 00:41:43,710
+الارتفاع درجة الحرارة الان انا مبين عندهين plot ل
+
+516
+00:41:43,710 --> 00:41:51,130
+resistance مع التغير درجة الحرارة لمواد مختلفة
+
+517
+00:41:53,380 --> 00:41:57,680
+عندي .. انا هنا عارض .. عنده هنا germanium يعني
+
+518
+00:41:57,680 --> 00:42:03,660
+كذا مادة، لاحظوا في مواد كل ما بزيد الحرارة بتقل
+
+519
+00:42:03,660 --> 00:42:07,540
+المقاومة، في مواد المادة هذه و المادة هذه ال
+
+520
+00:42:07,540 --> 00:42:13,810
+resistance بزيد معالارتفاع بدرجة الحرارة لاحظوا ان
+
+521
+00:42:13,810 --> 00:42:18,330
+عندي هنا log .. log scale يعني عندي هنا مثلا point
+
+522
+00:42:18,330 --> 00:42:22,750
+one واحد عشرة مية الف يعني عندي عشرة أس ناقص واحد
+
+523
+00:42:22,750 --> 00:42:26,470
+عشرة zero عشرة أقص واحد عشرة أقص اتنين عشرة أس تلت
+
+524
+00:42:26,470 --> 00:42:31,070
+وغير كده log .. log scale فمانعته في مواد ال
+
+525
+00:42:31,070 --> 00:42:34,430
+resistance بتاعتها بتقل مع الارتفاع و الحرارة وفي
+
+526
+00:42:34,430 --> 00:42:36,750
+مواد ال resistance بتاعتها بتزيد مع الارتفاع و
+
+527
+00:42:36,750 --> 00:42:37,750
+درجة الحرارة
+
+528
+00:42:46,690 --> 00:42:52,290
+الان ال resistance temperature detectors الان ال
+
+529
+00:42:52,290 --> 00:42:55,850
+sensor is generally constructed by mounting a
+
+530
+00:42:55,850 --> 00:43:01,110
+metal wire on an insulating support structure لازم
+
+531
+00:43:01,110 --> 00:43:06,730
+السلك أسبطه على structure معامل التماد الحراري
+
+532
+00:43:06,730 --> 00:43:15,220
+بتاعه يعني منخفض جدا جدا جداليش؟ لأن إذا كان ال
+
+533
+00:43:15,220 --> 00:43:18,140
+support اللي محطوط عليه ال silicon تمدد تبعه عالي
+
+534
+00:43:18,140 --> 00:43:22,560
+جدا بيأثر على القراءات صح؟ فبيعطيني القراءات غلط
+
+535
+00:43:22,560 --> 00:43:26,240
+and by encasing the wire to prevent changes in
+
+536
+00:43:26,240 --> 00:43:28,520
+resistance due to influences from the sensors
+
+537
+00:43:28,520 --> 00:43:32,280
+environment such as corrosion و لازم يكون مغطى
+
+538
+00:43:32,280 --> 00:43:41,640
+مغلف عشان أعزله عن البيئة عند هناهذا ال سلك مستخدم
+
+539
+00:43:41,640 --> 00:43:46,420
+سلك المقاومة بتاعته بتتغير مع تغير درجته الحرارة
+
+540
+00:43:46,420 --> 00:43:50,460
+in case محطوط جوا انبوب مصنوع من ال biorex كترة
+
+541
+00:43:50,460 --> 00:43:55,640
+تلاتة على تمانيةinch وفيه مادة اللي هي mica مادة
+
+542
+00:43:55,640 --> 00:44:04,580
+ceramic mica بيستخدموها في تناجر الخبز mica هذه
+
+543
+00:44:04,580 --> 00:44:08,080
+التماده بتاعها almost zero مع التغير مع درجة
+
+544
+00:44:08,080 --> 00:44:12,020
+الحرارة عشان امنع اي mechanical strain لو لا تماده
+
+545
+00:44:12,020 --> 00:44:15,520
+بيصير تعملي في المناطق هذه تعملي mechanical strain
+
+546
+00:44:17,030 --> 00:44:21,330
+المقاوم تتغيرش ليس فقط مع التغير بالدرجة الحرارة،
+
+547
+00:44:21,330 --> 00:44:24,590
+برضه المقاوم تتغير مع ال strain، بيصير فيه
+
+548
+00:44:24,590 --> 00:44:28,410
+deformation، بيصير برضه تغير في ال resistance،
+
+549
+00:44:28,410 --> 00:44:34,030
+فانت إذا صار strain ازيادة، فانا هتعطيه إن درجة
+
+550
+00:44:34,030 --> 00:44:37,530
+الحرارة ممكن تكون مية، هتعطيها مية و عشرةلأن جزء
+
+551
+00:44:37,530 --> 00:44:39,990
+من ال resistance .. ال resistance due to
+
+552
+00:44:39,990 --> 00:44:43,510
+mechanical strain not due to temperature فبصير
+
+553
+00:44:43,510 --> 00:44:51,050
+القراءة خادعة مش حقيقية حكينا
+
+554
+00:44:51,050 --> 00:44:54,150
+mechanical strain changes a conductor's resistance
+
+555
+00:44:54,150 --> 00:44:57,710
+إذا بيصير استطالة أو انكماش في ..
+
+556
+00:45:00,150 --> 00:45:06,670
+في ال .. في ال .. اللي هو ال sensor نتيجة أسباب
+
+557
+00:45:06,670 --> 00:45:12,010
+ميكانيكية .. نتيجة أسباب ميكانيكية الأسباب
+
+558
+00:45:12,010 --> 00:45:16,790
+الميكانيكية أنه مثلا أنا حاططها .. مركبها على ال
+
+559
+00:45:16,790 --> 00:45:20,550
+.. على المادة معينة و المادة اتمدت بالزيادة فهتعمل
+
+560
+00:45:20,550 --> 00:45:22,950
+mechanical .. هتعملوا .. تجبروا يعملوا يصير علي
+
+561
+00:45:22,950 --> 00:45:26,050
+mechanical strain و قلت لهم هتعطينا indication صح
+
+562
+00:45:26,050 --> 00:45:27,190
+لدرجة الحرارة
+
+563
+00:45:29,800 --> 00:45:34,060
+this factor اللي هو انك تاخد فعل اعتبار اللي هو ال
+
+564
+00:45:34,060 --> 00:45:38,200
+mechanical strain is essential because resistance
+
+565
+00:45:38,200 --> 00:45:40,420
+strains with mechanical strain are significant
+
+566
+00:45:40,420 --> 00:45:44,940
+اللي هو كمية التغير بالمقاومة نتيجة ال mechanical
+
+567
+00:45:44,940 --> 00:45:49,140
+strain كميتها كبيرة نسبيا وبالتالي بتأثر على دقة
+
+568
+00:45:49,140 --> 00:45:50,580
+القراع
+
+569
+00:45:56,730 --> 00:45:59,250
+عشانك لازي يكون عندي provision for strain free
+
+570
+00:45:59,250 --> 00:46:02,210
+expansion لازي يكون عندي ال expansion لل sensor
+
+571
+00:46:02,210 --> 00:46:08,850
+free مافيش مؤثر ميكانيكي خارجي بيأثر عليه و التالي
+
+572
+00:46:08,850 --> 00:46:13,530
+انا ال expansion بيكون ناتج فقط عن التغير في
+
+573
+00:46:13,530 --> 00:46:17,930
+الحرارة مافيش اللي هو expansion نتيجة أسباب
+
+574
+00:46:17,930 --> 00:46:25,310
+ميكانيكية طيب
+
+575
+00:46:27,210 --> 00:46:34,370
+القاعدة إذا كان لدي كندكتور سلك
+
+576
+00:46:34,370 --> 00:46:43,420
+طوله L و مقطع السلك مقطع A-Cويلو ال resistance رو
+
+577
+00:46:43,420 --> 00:46:49,760
+اي رو اي ال resistance للكندكتور هذا بالستويه رو
+
+578
+00:46:49,760 --> 00:46:55,480
+اي في ال على اي سي يعني ال resistance يتناسف ترضي
+
+579
+00:46:55,480 --> 00:47:00,860
+مع ال resistance للمaterial وكل ما يزيد الطول وكل
+
+580
+00:47:00,860 --> 00:47:08,080
+ما يقل ايش ال cross section يعني
+
+581
+00:47:10,050 --> 00:47:14,950
+إذا استخدمت مقطع كبير متوقع لما أمر فيه تيار
+
+582
+00:47:14,950 --> 00:47:21,640
+كهربائي .. اه كهربائيإنه يحمر ولا مش هيحمر؟ مش
+
+583
+00:47:21,640 --> 00:47:25,940
+هيحمر، معناته المقاومة بتاعته إيهاش؟ قليلة، إذا
+
+584
+00:47:25,940 --> 00:47:28,460
+خلته رفيق كتير بيحمر بسرعة، معناته ال resistance
+
+585
+00:47:28,460 --> 00:47:34,780
+بتاعته إيهاش؟ زادت ف resistance سواء row E L على
+
+586
+00:47:34,780 --> 00:47:38,540
+AC ال row اللي هي electrical resistivity و L ال
+
+587
+00:47:38,540 --> 00:47:42,540
+length للكندكتور و ال AC مساحة المقطع بتاع ال
+
+588
+00:47:42,540 --> 00:47:42,940
+conductor
+
+589
+00:47:51,380 --> 00:47:56,440
+العلاقة بين المقامة لـ metal conductor ودرجة
+
+590
+00:47:56,440 --> 00:47:59,300
+الحرارة اللى كنا نعبرها من خلال اللى هى polynomial
+
+591
+00:47:59,300 --> 00:48:04,100
+R بستوى R node فى واحد زائد Alpha فى T minus T
+
+592
+00:48:04,100 --> 00:48:08,620
+node زائد Beta فى T minus T node لكل تربيع زائد
+
+593
+00:48:08,620 --> 00:48:11,620
+Theta مثلا فى T minus T node لكل تكييف هتكون
+
+594
+00:48:11,620 --> 00:48:16,970
+polynomial غير منتهيةRO is a reference resistance
+
+595
+00:48:16,970 --> 00:48:21,370
+measured at temperature TO الـ coefficients Alpha
+
+596
+00:48:21,370 --> 00:48:27,670
+و Beta هدى material constants الان
+
+597
+00:48:27,670 --> 00:48:34,010
+في شكل هذا ال مرجين ال plot لل resistance اللى هى
+
+598
+00:48:34,010 --> 00:48:39,060
+R على RO relative resistance اللى هى R على ROمع
+
+599
+00:48:39,060 --> 00:48:42,300
+درجة الحرارة، عندي هنا ال platinum، في عندي هنا
+
+600
+00:48:42,300 --> 00:48:48,620
+إنحاس و عندي ال nickel بس بتطلع مثلا على الكفر
+
+601
+00:48:48,620 --> 00:48:56,180
+تقريبا من ناقص متين لحد ستمية تقريبا علاقة linear
+
+602
+00:48:59,100 --> 00:49:04,300
+وخد لبليتانيوم من ناقص متين لحد تمانمية درجة برضه
+
+603
+00:49:04,300 --> 00:49:09,620
+العلاقة تقريبا linear معناته هنا ال non linear
+
+604
+00:49:09,620 --> 00:49:17,160
+terms ممكن هنا احكي ان ال R مش سوى تقريبا R نوت في
+
+605
+00:49:17,160 --> 00:49:20,440
+واحد زاد الف في T minus T نوت و احمل ال non linear
+
+606
+00:49:20,440 --> 00:49:23,240
+terms احمل ال non linear terms
+
+607
+00:49:29,830 --> 00:49:35,050
+طيب ال alpha هي temperature coefficient of
+
+608
+00:49:35,050 --> 00:49:40,210
+resistivity for platinum conductor اذا كانت المادة
+
+609
+00:49:40,210 --> 00:49:44,360
+بتاعة المصدر اللي انا مستخدمه كمجزThe linear
+
+610
+00:49:44,360 --> 00:49:49,080
+approximation is accurate within uncertainty of 0
+
+611
+00:49:49,080 --> 00:49:53,840
+.3 على ال range من 0 ل 200 اذا استخدمت بلتانيو ك
+
+612
+00:49:53,840 --> 00:49:58,420
+sensor بيعطينا دقة حوالي تلاتة من عشرة في المية من
+
+613
+00:49:58,420 --> 00:50:02,180
+0 ل 200 درجة وبيعطينا uncertainty واحد اتنين من
+
+614
+00:50:02,180 --> 00:50:08,100
+عشرة في المية من 200 ل 800 درجة لأنه طلع من 0 ل
+
+615
+00:50:08,100 --> 00:50:08,360
+200
+
+616
+00:50:12,190 --> 00:50:17,430
+درجة اللينيرات عالية كتير من الـ 300 في .. في some
+
+617
+00:50:17,430 --> 00:50:23,230
+curvature صغير طيب
+
+618
+00:50:23,230 --> 00:50:29,290
+table 82 معطين temperature coefficient for over
+
+619
+00:50:29,290 --> 00:50:32,690
+resistivity for selected materials at 20 degrees
+
+620
+00:50:32,690 --> 00:50:37,940
+يعنيالمعادلة اللى هى R بس هو R نوت فى واحد زد الفة
+
+621
+00:50:37,940 --> 00:50:40,680
+فى T بقى ناس T نوت مثلا ال aluminium معطين ال
+
+622
+00:50:40,680 --> 00:50:45,800
+alpha point O اللى هى O اربعة اتنين تسعة ال
+
+623
+00:50:45,800 --> 00:50:50,780
+plutonium point O O تلاتة تسعة اتنين سبعة ال
+
+624
+00:50:50,780 --> 00:50:55,400
+tungsten point O O اربعة تمانية و هكذا
+
+625
+00:50:59,150 --> 00:51:02,590
+platinum is اللي انا هنحكي عنه platinum resistance
+
+626
+00:51:02,590 --> 00:51:06,230
+temperature device platinum resistance temperature
+
+627
+00:51:06,230 --> 00:51:11,090
+device platinum is the most common material chosen
+
+628
+00:51:11,090 --> 00:51:16,710
+for the construction of resistance thermometers
+
+629
+00:51:16,710 --> 00:51:20,870
+يعني هي ال material اكتر شيوعا تستخدم في
+
+630
+00:51:20,870 --> 00:51:23,410
+resistance temperature devices
+
+631
+00:51:31,930 --> 00:51:40,990
+البليتانيوم بورجينا تغير متوقع طبق للمعادلة اللي
+
+632
+00:51:40,990 --> 00:51:48,710
+هي R بساوة R not في واحدة الف في Delta T and
+
+633
+00:51:48,710 --> 00:51:55,800
+reproducible يعني لما يبردبس خانتانة دايما بيعطيك
+
+634
+00:51:55,800 --> 00:51:59,160
+نفس الرزق يعني ال reports بتغيرش مع الزمن كتير،
+
+635
+00:51:59,160 --> 00:52:06,140
+مابتغير مع الزمن كتير which can be calibrated and
+
+636
+00:52:06,140 --> 00:52:08,960
+interpolated to a high degree of accuracy
+
+637
+00:52:18,160 --> 00:52:22,700
+the linear approximation for the relationship
+
+638
+00:52:22,700 --> 00:52:26,640
+between temperature and resistance is valid over a
+
+639
+00:52:26,640 --> 00:52:29,400
+wide temperature range and the plutonium is highly
+
+640
+00:52:29,400 --> 00:52:36,840
+stable يعني العلاقة الخطية بين درجة الحرارة
+
+641
+00:52:36,840 --> 00:52:42,300
+والمقاومة لل plutonium valid بتنفع على range على
+
+642
+00:52:42,300 --> 00:52:47,850
+تقريب من 0 ل 800 درجة، من 0 ل 800 درجةto be
+
+643
+00:52:47,850 --> 00:52:50,650
+suitable for use as a secondary temperature
+
+644
+00:52:50,650 --> 00:52:53,690
+standard a plutonium resistant thermometer should
+
+645
+00:52:53,690 --> 00:52:58,030
+have a value of not less than 0.003925 عشان يكون
+
+646
+00:52:58,030 --> 00:53:04,890
+مناسب أنه أستخدمه كمعيار ثانوي عشان أعير أجهزة
+
+647
+00:53:04,890 --> 00:53:12,090
+تانية ال alpha بتاعته لازم يكون مش أقل من 0.003925
+
+648
+00:53:12,090 --> 00:53:18,520
+per degree هذه ال alphaطبعا قيمة الأفة بتاع الألف
+
+649
+00:53:18,520 --> 00:53:24,260
+بتعتمد على ال purity بتاعة البلتانيوم كل ما كان
+
+650
+00:53:24,260 --> 00:53:28,380
+عندي نقاء أعلى في البلتانيوم كل ما حصلت على قراءة
+
+651
+00:53:28,380 --> 00:53:30,220
+أحسن درجة الحرارة
+
+652
+00:53:32,680 --> 00:53:36,460
+in general RTDs may be used for the measurement of
+
+653
+00:53:36,460 --> 00:53:39,640
+temperature ranging from cryogenic to
+
+654
+00:53:39,640 --> 00:53:42,940
+approximately 650 عادة resistance temperature
+
+655
+00:53:42,940 --> 00:53:46,860
+detectors تستخدم لأجهزة لقص حوار في ال range من
+
+656
+00:53:46,860 --> 00:53:50,120
+cryogenic ل تقريبا 650 ايش معنى cryogenic؟
+
+657
+00:53:50,120 --> 00:53:55,080
+cryogenic
+
+658
+00:53:55,080 --> 00:53:58,780
+يعني درجة حرارة صحيقة في البرودة يعني تكون تقريبا
+
+659
+00:53:59,910 --> 00:54:04,830
+ناقص مية ناقص متين درجة يعني بارج جدا من ناقص مية
+
+660
+00:54:04,830 --> 00:54:16,650
+ناقص متين ل 650 درجة by
+
+661
+00:54:16,650 --> 00:54:22,680
+properly constructing an RTDإذا بصمم الجهاز او
+
+662
+00:54:22,680 --> 00:54:28,260
+مجلس القياس الحرارة and correctly measuring its
+
+663
+00:54:28,260 --> 00:54:33,820
+resistance و أقيص مقاومته الصح نسبة خطأ في قياس
+
+664
+00:54:33,820 --> 00:54:37,980
+حرارة قد تصل لحد point O خمس degrees is possible
+
+665
+00:54:37,980 --> 00:54:41,480
+يعني حسب الدائرة الكهربية المستخدمة
+
+666
+00:54:50,940 --> 00:54:54,040
+The choice of an appropriate resistance measuring
+
+667
+00:54:54,040 --> 00:55:00,560
+device عملية اختيار ال resistance device must be
+
+668
+00:55:00,560 --> 00:55:04,060
+made based on the required level of uncertainty in
+
+669
+00:55:04,060 --> 00:55:08,240
+the final temperature measurement لازم اختيارنا لل
+
+670
+00:55:08,240 --> 00:55:11,520
+resistance temperature measuring device يعتمد على
+
+671
+00:55:11,520 --> 00:55:15,760
+مستوى نسبة الخطأ في ال final measurement للحرارة
+
+672
+00:55:17,100 --> 00:55:20,780
+conventional ohmmeters اللي هو أجهزة قياس المقاومة
+
+673
+00:55:20,780 --> 00:55:24,900
+cause a small current to flow during resistance
+
+674
+00:55:24,900 --> 00:55:28,460
+measurements creating self heating in the RTD لأن
+
+675
+00:55:28,460 --> 00:55:30,820
+ال ohmmeter لما نقيص الحرارة لما نقيص المقاومة مش
+
+676
+00:55:30,820 --> 00:55:35,620
+بيساوي هو بمرر تيار بمرر تيار في المقاومة
+
+677
+00:55:35,620 --> 00:55:43,420
+وبالطريقة هذه هو بيقيص إيش المقاومة لأن تمرير تيار
+
+678
+00:55:44,760 --> 00:55:49,720
+بيخلى ال sensor يسخن شوية بيعمل self heating ليش؟
+
+679
+00:55:49,720 --> 00:55:54,240
+لل sensor معناته
+
+680
+00:55:54,240 --> 00:56:00,560
+ال o meter نتيجة ان مرة تهيأر بيعمل تسخين شوية لل
+
+681
+00:56:00,560 --> 00:56:05,700
+sensor وبالتالي لما ناخد القراة في سخونة نتيجة
+
+682
+00:56:05,700 --> 00:56:10,860
+طريقة القياس في سخونة نتيجة طريقة القياس معناته
+
+683
+00:56:10,860 --> 00:56:13,920
+الدقة بيزيد ولا بتقل؟ بتقل
+
+684
+00:56:18,950 --> 00:56:24,370
+طيب، حاجة ما اسميهاش loading error، اسميه loading
+
+685
+00:56:24,370 --> 00:56:28,610
+error؟ طيب
+
+686
+00:56:30,420 --> 00:56:34,640
+الان bridge circuits اللي هو ال .. ال bridge
+
+687
+00:56:34,640 --> 00:56:38,280
+circuits are used to measure resistance of RTDs to
+
+688
+00:56:38,280 --> 00:56:42,120
+minimize loading errors باستخدع ال bridge circuits
+
+689
+00:56:42,120 --> 00:56:46,420
+عشان minimize ال loading errors اللي هي نتيجة لو
+
+690
+00:56:46,420 --> 00:56:52,280
+ده استخدم Ohm متر مباشرة بتعملي loading error and
+
+691
+00:56:52,280 --> 00:56:55,180
+provide low uncertainties in measured resistance
+
+692
+00:56:55,180 --> 00:56:59,430
+valuesweight stone bridge circuit سمعتوا فيها
+
+693
+00:56:59,430 --> 00:57:02,290
+weight stone bridge circuit are commonly used for
+
+694
+00:57:02,290 --> 00:57:06,550
+these measurements ال
+
+695
+00:57:06,550 --> 00:57:11,130
+weight stone بتكون
+
+696
+00:57:11,130 --> 00:57:20,470
+عادة اللي هي بشكل أساسي يكون عندى مقاومة
+
+697
+00:57:44,740 --> 00:57:49,200
+عندي هذه R1 R2
+
+698
+00:57:49,200 --> 00:57:53,020
+وR3
+
+699
+00:57:53,020 --> 00:58:02,280
+وR4 طبعا
+
+700
+00:58:02,280 --> 00:58:08,280
+R3 اللي هي very good resistance هذه
+
+701
+00:58:08,280 --> 00:58:13,090
+ال RTD اللي هي ال sensor بتاعيبحطه فى البيئة اللى
+
+702
+00:58:13,090 --> 00:58:16,750
+بده اقيس حرارتها بحطه فى البيئة اللى بده اقيس
+
+703
+00:58:16,750 --> 00:58:19,310
+حرارتها النتيجة تقعده فى البيئة اللى مراد قياس
+
+704
+00:58:19,310 --> 00:58:24,990
+حرارتها تتغير المقاومة بتاعته تتغير المقاومة ال
+
+705
+00:58:24,990 --> 00:58:28,390
+RTD بتتغير هنا أنا بلعب فى ال resistance هنا بعمل
+
+706
+00:58:28,390 --> 00:58:34,370
+adjust بحيث اعمل balance لها دى بحيث اعمل balance
+
+707
+00:58:34,370 --> 00:58:39,830
+يعني فى الحالة اللى بيصير عندى R1 على
+
+708
+00:58:42,550 --> 00:58:53,510
+R2 so R3 على ال R RTD بتكون
+
+709
+00:58:53,510 --> 00:59:02,990
+ال R1 معروفة وال R2 معروفة وبيلعب في ال R3 بيعمل
+
+710
+00:59:02,990 --> 00:59:08,450
+adjust عشان تتحقق العلاقة هذه هذه اللي هي ال wheat
+
+711
+00:59:08,450 --> 00:59:09,950
+stone bridge
+
+712
+00:59:18,020 --> 00:59:20,980
+الان the basic wheat stone bridge circuit does not
+
+713
+00:59:20,980 --> 00:59:23,420
+compensate for the resistance of the leads in
+
+714
+00:59:23,420 --> 00:59:27,080
+measuring this resistance of an RTD الان لما انا
+
+715
+00:59:27,080 --> 00:59:30,780
+اعمل circuit باستخدام اسلاك عشان اوصل الاسلاك ايه
+
+716
+00:59:30,780 --> 00:59:40,040
+شلها مقاومة صح الان مقاومة اسلاك هتعمل ليه او
+
+717
+00:59:40,040 --> 00:59:43,840
+تعتبر مصدر رئيس لل error في ال electric resistance
+
+718
+00:59:43,840 --> 00:59:47,500
+thermometer تعتبر مصدر رئيس للخطأ في ال resistance
+
+719
+00:59:50,440 --> 00:59:53,400
+when greater accuracy are required, three-wire and
+
+720
+00:59:53,400 --> 01:00:01,520
+four-wire bridge circuits are used الآن .. الآن
+
+721
+01:00:01,520 --> 01:00:07,720
+عند هنا كذا شكل ال .. يعني أشكال معدل ال .. معدل
+
+722
+01:00:07,720 --> 01:00:11,240
+ال bridge circuit
+
+723
+01:00:11,240 --> 01:00:19,010
+عند هنا فيه بطارية طبعاعندي هين R1 R2 هين
+
+724
+01:00:19,010 --> 01:00:23,170
+galvanometer هين variable resistance R3 مقاوم
+
+725
+01:00:23,170 --> 01:00:28,890
+متغيرة وعندي هاد ال RTD اللي هي المجس اللي بيكون
+
+726
+01:00:28,890 --> 01:00:33,480
+مغمور في البيئة المراد قياسدرجة حرارتها لأن في
+
+727
+01:00:33,480 --> 01:00:37,400
+عندى silic هنا silic الى مقاومة R واحد small وفي
+
+728
+01:00:37,400 --> 01:00:41,440
+silic مقاومة R اتنين small و silic مقاومة R تلاتة
+
+729
+01:00:41,440 --> 01:00:46,940
+small هذا يسمى كالندر غريفث ثري واير برج هذا
+
+730
+01:00:46,940 --> 01:00:52,240
+كالندر غريفث ثري واير برج عندى اللي هو arrangement
+
+731
+01:00:52,240 --> 01:00:59,120
+تاني في B عندى هاي R واحدR2 في عندى بطارية عندى
+
+732
+01:00:59,120 --> 01:01:04,600
+galvanometer عند R3 variable وفي عندى ال RTD اللى
+
+733
+01:01:04,600 --> 01:01:08,700
+هو المقاومة اللى بتكون مغمورة فى البيئة مراد قياس
+
+734
+01:01:08,700 --> 01:01:13,200
+درجة حرارتها وعندى ال silicon مقاومة R1 small و ال
+
+735
+01:01:13,200 --> 01:01:16,680
+silicon مقاومة R2 small و ال silicon مقاومة R3
+
+736
+01:01:16,680 --> 01:01:24,000
+small و R4 small هذه ال lead wiresأو اللي بيسمى
+
+737
+01:01:24,000 --> 01:01:29,700
+molar four wire bridge عندى هاي R تلاتة prime وR
+
+738
+01:01:29,700 --> 01:01:34,140
+واحد وR اتنين واللي انا عندى الأسلاك هاد مقاومته R
+
+739
+01:01:34,140 --> 01:01:38,560
+تلاتة R أربعة R واحد وR اتنين وهاد اللي هي ال RTD
+
+740
+01:01:38,560 --> 01:01:43,520
+اللي هي ال plutonium conductor اللي بتكون مغمورة
+
+741
+01:01:43,520 --> 01:01:48,780
+في البيئة المراد قياس درجة حرارتها اللي انا بشكل
+
+742
+01:01:48,780 --> 01:01:55,760
+عندى R واحدعلى R2 بيستوى R3 على R RTD R1 على R2
+
+743
+01:01:55,760 --> 01:02:09,680
+بيستوى R3 على R RTD الان
+
+744
+01:02:09,680 --> 01:02:13,560
+اللحظة
+
+745
+01:02:13,560 --> 01:02:24,040
+نتطلع على شكل V هنا الحكومة ديالـ R3 والـ R1 صغير
+
+746
+01:02:24,040 --> 01:02:30,660
+هدول in series صح؟ المقاومة الكلية هين هتكون مش R3
+
+747
+01:02:30,660 --> 01:02:38,780
+هتكون R3 زائد R1 صغير وعندي هين R3
+
+748
+01:02:38,780 --> 01:02:45,920
+in series مع RTD R3 صغير in series مع R33 معناته
+
+749
+01:02:45,920 --> 01:02:50,100
+هين هتكون equivalent المقاومة اللي هي R3 زائد R1
+
+750
+01:02:51,050 --> 01:02:54,690
+وهين equivalent لل R RTD زاد R تلاتة small
+
+751
+01:02:54,690 --> 01:02:59,930
+باستخدام هذه العلاقة R1 على R2 بيستوى R3 على R RTD
+
+752
+01:02:59,930 --> 01:03:05,110
+هكون عندي R1 على R2 بيستوى ال total resistance
+
+753
+01:03:05,110 --> 01:03:14,110
+اللي هو R3 زاد R1 على R RTD زاد R3 smallإذا كانت
+
+754
+01:03:14,110 --> 01:03:17,610
+أصممت أنا الدار بحيث المقاومة ل 1 بيستوى المقاومة
+
+755
+01:03:17,610 --> 01:03:22,030
+ل 2 R1 بيستوى R2 ماعنى هذا إيش هتكون R1 ل R2 إيش
+
+756
+01:03:22,030 --> 01:03:26,630
+بيستوى؟ واحد إذا بعمل cross product بيستوين دي ال
+
+757
+01:03:26,630 --> 01:03:34,810
+RTD بيستوى R3 زاد R1 ناقص R3 إذا أصممت اخترت إن
+
+758
+01:03:34,810 --> 01:03:39,590
+مقاومة السلك واحد نفس مقاومة السلك تلاتة بيروحوا
+
+759
+01:03:39,590 --> 01:03:46,630
+مع بعضمعناته التغير في مقاومة R3 هو indication لل
+
+760
+01:03:46,630 --> 01:03:53,570
+RTD فبالتصميم هذا استطعت
+
+761
+01:03:53,570 --> 01:03:58,850
+أنه ألغي تأثير ال R1 وR2 اللي تبتمنه مقاومة
+
+762
+01:03:58,850 --> 01:04:08,490
+الأسلاك الآن المقاومة لل R2 مش مهمة ليشلأنه ع
+
+763
+01:04:08,490 --> 01:04:16,290
+التوازن بمرش طيار بمرش طيار فيها وبالتالي اذا بمرش
+
+764
+01:04:16,290 --> 01:04:22,910
+فيها طيار معناته لا تعني شيء زي ما احكي ان ال
+
+765
+01:04:22,910 --> 01:04:26,450
+resistance of lead wire it too does not contribute
+
+766
+01:04:26,450 --> 01:04:29,810
+to any error in the measurement at the balanced
+
+767
+01:04:29,810 --> 01:04:33,110
+conditions since no current flows through the
+
+768
+01:04:33,110 --> 01:04:34,350
+galvanometer G
+
+769
+01:04:38,880 --> 01:04:43,280
+طيب خلي المحاضرة الجاية نكتفي اليوم المحاضرة
+
+770
+01:04:43,280 --> 01:04:44,700
+الجاية بنكمل اعطيكوا العافية
+
diff --git a/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/EZbluVHhQIk_raw.json b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/EZbluVHhQIk_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..8d90384b4f2d7196f932b2f777efb237ec3b57c5
--- /dev/null
+++ b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/EZbluVHhQIk_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2026, "start": 5.28, "end": 20.26, "text": "بسم الله الرحمن الرحيم السلام عليكم ورحمة الله وبركاته اليوم هنكمل في مادة القياسات تقييم وعرض البيانات لحتى لحظة هحكي انا عن ال theory based on sample", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 21136, 37440, 25894, 24793, 4032, 2288, 35571, 3660, 21984, 4032, 26890, 4117, 9307, 3224, 45595, 20498, 8032, 1863, 24793, 1211, 8978, 3714, 18513, 3660, 25062, 25528, 3794, 9307, 6055, 38436, 32640, 4032, 3615, 43042, 2423, 21292, 7649, 9307, 5296, 33753, 7578, 5296, 5016, 19913, 3660, 8032, 5016, 4117, 1829, 1975, 8315, 18871, 2423, 5261, 2361, 322, 6889], "avg_logprob": -0.14832090086011746, "compression_ratio": 1.5962732919254659, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 5.28, "end": 5.68, "word": "بسم", "probability": 0.79833984375}, {"start": 5.68, "end": 5.88, "word": " الله", "probability": 0.95849609375}, {"start": 5.88, "end": 6.2, "word": " الرحمن", 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اربعة اوز ميزان عادي ميزان كفين عشان يوزن بيوزن واحد و بيحط واحد و بيحط الاشي بيوزن", "tokens": [64, 2199, 49645, 4373, 295, 264, 2681, 3726, 4772, 2010, 307, 27625, 43242, 4117, 3714, 1829, 11622, 7649, 4724, 1829, 14851, 9778, 40448, 2407, 3224, 8978, 3714, 4117, 9307, 3555, 2423, 26890, 25708, 307, 27625, 365, 4724, 1829, 7435, 2304, 3615, 9122, 2655, 1211, 8717, 9381, 36764, 24401, 4032, 1975, 2655, 1863, 9957, 1975, 25513, 27884, 1975, 2407, 11622, 3714, 1829, 11622, 7649, 6225, 995, 16254, 3714, 1829, 11622, 7649, 9122, 5172, 9957, 6225, 8592, 7649, 7251, 2407, 11622, 1863, 4724, 1829, 2407, 11622, 1863, 36764, 24401, 4032, 4724, 1829, 5016, 9566, 36764, 24401, 4032, 4724, 1829, 5016, 9566, 2423, 33599, 1829, 4724, 1829, 2407, 11622, 1863], "avg_logprob": -0.21383101134388535, "compression_ratio": 1.7164179104477613, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 673.11, "end": 673.33, "word": "a", "probability": 0.304931640625}, {"start": 673.33, "end": 673.73, 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719.34, "end": 719.78, "word": " check", "probability": 0.9560546875}], "temperature": 1.0}, {"id": 26, "seek": 75132, "start": 721.62, "end": 751.32, "text": "the manufacturer randomly selects a sample of fourteen of the one o's weights and weighs them on a precision scale هو بيصنع الأوزان هذه جاب كتلة الواحد o's بتأكد أخد أربع تاشر عينا عشوائي وزنهم أخد يعني أربع تاشر كرا the results in ounces are as follows يعني طلعت النتاج عنده واحد point o تمانية", "tokens": [3322, 18022, 16979, 3048, 82, 257, 6889, 295, 32253, 295, 264, 472, 277, 311, 17443, 293, 24911, 552, 322, 257, 18356, 4373, 31439, 4724, 1829, 9381, 1863, 3615, 16247, 2407, 11622, 7649, 29538, 10874, 16758, 9122, 2655, 37977, 2423, 14407, 24401, 277, 311, 39894, 10721, 4117, 3215, 5551, 9778, 3215, 5551, 25513, 3615, 6055, 33599, 2288, 6225, 1829, 8315, 6225, 8592, 2407, 16373, 1829, 4032, 11622, 1863, 16095, 5551, 9778, 3215, 37495, 22653, 5551, 25513, 3615, 6055, 33599, 2288, 9122, 23557, 264, 3542, 294, 27343, 366, 382, 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أعمل", "probability": 0.9228515625}, {"start": 1420.96, "end": 1421.54, "word": " مراقبة", "probability": 0.9913330078125}, {"start": 1421.54, "end": 1422.16, "word": " على", "probability": 0.9189453125}, {"start": 1422.16, "end": 1422.64, "word": " ضغط", "probability": 0.9674479166666666}, {"start": 1422.64, "end": 1423.28, "word": " البخار", "probability": 0.92236328125}, {"start": 1423.28, "end": 1424.44, "word": " الداخل", "probability": 0.7853190104166666}, {"start": 1424.44, "end": 1427.66, "word": " عملنا", "probability": 0.9807942708333334}, {"start": 1427.66, "end": 1428.52, "word": " تجربة", "probability": 0.9898681640625}, {"start": 1428.52, "end": 1430.98, "word": " أخدها", "probability": 0.9190673828125}, {"start": 1430.98, "end": 1431.22, "word": " مية", "probability": 0.488037109375}, {"start": 1431.22, "end": 1432.04, "word": " قراءة", "probability": 0.82159423828125}, {"start": 1432.04, "end": 1433.22, "word": " على", "probability": 0.91162109375}, {"start": 1433.22, 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{"start": 1444.26, "end": 1444.52, "word": " x", "probability": 0.448974609375}, {"start": 1444.52, "end": 1444.96, "word": " bar", "probability": 0.779296875}, {"start": 1444.96, "end": 1448.9, "word": " طلعت", "probability": 0.9513346354166666}, {"start": 1448.9, "end": 1449.06, "word": " هنا", "probability": 0.9052734375}, {"start": 1449.06, "end": 1449.24, "word": " بأس", "probability": 0.5627034505208334}, {"start": 1449.24, "end": 1449.36, "word": " طوال", "probability": 0.5987141927083334}, {"start": 1449.36, "end": 1450.0, "word": " أربعمية", "probability": 0.871337890625}, {"start": 1450.0, "end": 1451.92, "word": " point", "probability": 0.45703125}, {"start": 1451.92, "end": 1452.36, "word": " سبعة", "probability": 0.7342936197916666}, {"start": 1452.36, "end": 1452.98, "word": " سبعة", "probability": 0.8269856770833334}, {"start": 1452.98, "end": 1454.8, "word": " ميجا", "probability": 0.71099853515625}, {"start": 1454.8, "end": 1456.74, "word": " مش", "probability": 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"end": 1521.44, "word": " يوم", "probability": 0.9921875}, {"start": 1521.44, "end": 1521.8, "word": " يومين", "probability": 0.9259440104166666}, {"start": 1521.8, "end": 1522.14, "word": " تلات", "probability": 0.9627278645833334}, {"start": 1522.14, "end": 1522.56, "word": " أسبوع", "probability": 0.7923177083333334}], "temperature": 1.0}, {"id": 52, "seek": 154983, "start": 1523.61, "end": 1549.83, "text": "برضه أخدت ميد قراه و طلعت المتوسط و طلعت ال standard deviation هل هيطلع نفس ال mean لأ هيطلع عندك x2 bar اللعبات كمان مرة تلت مرة تجربة كرت برضه مش هيطلع نفس ال mean هيطلع x3 bar x4 bar", "tokens": [26890, 11242, 3224, 5551, 9778, 3215, 2655, 3714, 25708, 12174, 23557, 3224, 4032, 23032, 1211, 34268, 9673, 2655, 41779, 9566, 4032, 23032, 1211, 34268, 2423, 3832, 25163, 8032, 1211, 8032, 1829, 9566, 1211, 3615, 8717, 36178, 2423, 914, 5296, 10721, 8032, 1829, 9566, 1211, 3615, 43242, 4117, 2031, 17, 2159, 13672, 3615, 3555, 9307, 9122, 2304, 7649, 3714, 25720, 6055, 1211, 2655, 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{"start": 1533.99, "end": 1534.75, "word": " x2", "probability": 0.62158203125}, {"start": 1534.75, "end": 1535.73, "word": " bar", "probability": 0.5556640625}, {"start": 1535.73, "end": 1539.27, "word": " اللعبات", "probability": 0.80426025390625}, {"start": 1539.27, "end": 1539.55, "word": " كمان", "probability": 0.9609375}, {"start": 1539.55, "end": 1539.77, "word": " مرة", "probability": 0.425048828125}, {"start": 1539.77, "end": 1540.07, "word": " تلت", "probability": 0.5853678385416666}, {"start": 1540.07, "end": 1540.33, "word": " مرة", "probability": 0.8798828125}, {"start": 1540.33, "end": 1540.91, "word": " تجربة", "probability": 0.9697265625}, {"start": 1540.91, "end": 1541.43, "word": " كرت", "probability": 0.728759765625}, {"start": 1541.43, "end": 1541.85, "word": " برضه", "probability": 0.9840494791666666}, {"start": 1541.85, "end": 1542.09, "word": " مش", "probability": 0.93359375}, {"start": 1542.09, "end": 1542.39, "word": " هيطلع", "probability": 0.93505859375}, 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"text": "ب confidence معين ب confidence معين هتكون ال values في ال range هذا هذا ال do not reject هن reject و هن reject لما تجمع المساحات كلها اشي اللي خلاني اختاره يعني سبع نص الشخص يعني", "tokens": [3555, 6687, 20449, 9957, 4724, 6687, 20449, 9957, 8032, 2655, 30544, 2423, 4190, 8978, 2423, 3613, 23758, 23758, 2423, 360, 406, 8248, 8032, 1863, 8248, 4032, 8032, 1863, 8248, 5296, 15042, 6055, 7435, 2304, 3615, 9673, 3794, 39319, 9307, 28242, 11296, 1975, 8592, 1829, 13672, 1829, 16490, 1211, 7649, 1829, 1975, 46456, 9640, 3224, 37495, 22653, 8608, 3555, 3615, 8717, 9381, 25124, 9778, 9381, 37495, 22653], "avg_logprob": -0.38386194118812905, "compression_ratio": 1.638036809815951, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1784.72, "end": 1784.94, "word": "ب", "probability": 0.86474609375}, {"start": 1784.94, "end": 1785.36, "word": " confidence", "probability": 0.79296875}, {"start": 1785.36, "end": 1786.0, "word": " معين", "probability": 0.977783203125}, {"start": 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Z distribution مثل بيانات بدل من استخدم T statistic بستخدم Z statistic بحسب بس اللي هو Z exponential بيستخدم X bar minus Mu على SX عجزة تربيعية لل N وال Z exponential بحسبه من جدول ال Z distribution بحسبه من جدول ال Z distribution", "tokens": [28814, 15730, 1975, 2655, 9778, 9566, 1829, 8315, 16712, 1211, 9307, 9957, 4724, 1829, 9381, 13546, 2423, 1176, 7316, 50113, 1211, 4724, 1829, 7649, 9307, 47525, 1211, 9154, 44713, 9778, 40448, 314, 29588, 4724, 14851, 9778, 40448, 1176, 29588, 4724, 5016, 35457, 4724, 3794, 13672, 1829, 31439, 1176, 1278, 266, 2549, 4724, 1829, 14851, 9778, 40448, 1783, 2159, 3175, 15601, 15844, 318, 55, 6225, 7435, 11622, 3660, 6055, 2288, 21292, 3615, 10632, 24976, 426, 16070, 1176, 1278, 266, 2549, 4724, 5016, 35457, 3224, 9154, 10874, 3215, 12610, 2423, 1176, 7316, 4724, 5016, 35457, 3224, 9154, 10874, 3215, 12610, 2423, 1176, 7316], "avg_logprob": -0.2654718277501125, "compression_ratio": 1.838235294117647, "no_speech_prob": 8.344650268554688e-07, "words": 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hypothesis صح هو بيحكيلي سؤال", "tokens": [6780, 264, 17069, 1412, 14879, 13330, 257, 3779, 3321, 295, 1017, 12224, 64, 412, 257, 6687, 1496, 295, 11803, 4, 37495, 22653, 5551, 12610, 44049, 13672, 1829, 5296, 31377, 2304, 6055, 4117, 2655, 3555, 8717, 5016, 4117, 1829, 13672, 1829, 31439, 2423, 18184, 17291, 4032, 2423, 18873, 17291, 20328, 5016, 31439, 4724, 1829, 5016, 4117, 1829, 20292, 8608, 33604, 6027], "avg_logprob": -0.19531249511437337, "compression_ratio": 1.343915343915344, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2825.92, "end": 2826.3, "word": "that", "probability": 0.471923828125}, {"start": 2826.3, "end": 2827.0, "word": " the", "probability": 0.689453125}, {"start": 2827.0, "end": 2827.46, "word": " experimental", "probability": 0.90234375}, {"start": 2827.46, "end": 2827.94, "word": " data", "probability": 0.96484375}, {"start": 2827.94, "end": 2828.24, "word": " obtained", "probability": 0.947265625}, {"start": 2828.24, "end": 2828.88, "word": " 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المينا العينة التالتة التانية و ال S1 هو ال standard deviation العينة الأولى و ال S2 هو ال standard deviation العينة التانية ال N1 عدد قراءات العينة الأولى و ال N2 عدد قراءات العينة التانية value of T is compared to the interval plus or minus T Alpha ع 2 و Nu زي السابقا طبعا", "tokens": [2407, 2423, 1783, 17, 2159, 31439, 9673, 1829, 8315, 18863, 9957, 3660, 16712, 6027, 2655, 3660, 16712, 7649, 10632, 4032, 2423, 318, 16, 31439, 2423, 3832, 25163, 18863, 9957, 3660, 16247, 12610, 7578, 4032, 2423, 318, 17, 31439, 2423, 3832, 25163, 18863, 9957, 3660, 16712, 7649, 10632, 2423, 426, 16, 6225, 3215, 3215, 12174, 2288, 16606, 9307, 18863, 9957, 3660, 16247, 12610, 7578, 4032, 2423, 426, 17, 6225, 3215, 3215, 12174, 2288, 16606, 9307, 18863, 9957, 3660, 16712, 7649, 10632, 2158, 295, 314, 307, 5347, 281, 264, 15035, 1804, 420, 3175, 314, 20588, 6225, 568, 4032, 13612, 30767, 1829, 21136, 16758, 4587, 995, 23032, 3555, 3615, 995], "avg_logprob": -0.18880207905614818, "compression_ratio": 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{"start": 3571.52, "end": 3571.98, "word": " interval", "probability": 0.96630859375}, {"start": 3571.98, "end": 3572.36, "word": " plus", "probability": 0.5869140625}, {"start": 3572.36, "end": 3572.5, "word": " or", "probability": 0.8720703125}, {"start": 3572.5, "end": 3572.74, "word": " minus", "probability": 0.9931640625}, {"start": 3572.74, "end": 3573.06, "word": " T", "probability": 0.908203125}, {"start": 3573.06, "end": 3573.34, "word": " Alpha", "probability": 0.2393798828125}, {"start": 3573.34, "end": 3573.48, "word": " ع", "probability": 0.65625}, {"start": 3573.48, "end": 3573.78, "word": " 2", "probability": 0.2191162109375}, {"start": 3573.78, "end": 3574.04, "word": " و", "probability": 0.94921875}, {"start": 3574.04, "end": 3574.28, "word": " Nu", "probability": 0.6044921875}, {"start": 3574.28, "end": 3574.64, "word": " زي", "probability": 0.9033203125}, {"start": 3574.64, "end": 3575.34, "word": " السابقا", "probability": 0.8424072265625}, {"start": 3575.34, "end": 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freedom", "probability": 0.9326171875}, {"start": 3597.64, "end": 3599.16, "word": " للمقارنة", "probability": 0.9337565104166666}, {"start": 3599.16, "end": 3599.88, "word": " للتانية", "probability": 0.7225341796875}, {"start": 3599.88, "end": 3600.84, "word": " فلل", "probability": 0.621826171875}, {"start": 3600.84, "end": 3600.98, "word": " new", "probability": 0.417236328125}, {"start": 3600.98, "end": 3601.28, "word": " هذه", "probability": 0.55615234375}, {"start": 3601.28, "end": 3601.56, "word": " degree", "probability": 0.6005859375}, {"start": 3601.56, "end": 3601.78, "word": " of", "probability": 0.80078125}, {"start": 3601.78, "end": 3602.12, "word": " freedom", "probability": 0.93212890625}, {"start": 3602.12, "end": 3602.56, "word": " لل", "probability": 0.5595703125}, {"start": 3602.56, "end": 3602.84, "word": " T", "probability": 0.712890625}, {"start": 3602.84, "end": 3603.48, "word": " statistic", "probability": 0.82080078125}, {"start": 3603.48, "end": 3604.46, 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"text": "بطلع نيل بون سفر سبعة أربعة عندي هان نيل بون سفر سبعة أربعة و هان عندي مانس نيل بون سفر سبعة أربعة", "tokens": [3555, 9566, 1211, 3615, 8717, 26895, 4724, 11536, 8608, 5172, 2288, 8608, 3555, 27884, 5551, 25513, 27884, 18871, 16254, 8032, 7649, 8717, 26895, 4724, 11536, 8608, 5172, 2288, 8608, 3555, 27884, 5551, 25513, 27884, 4032, 8032, 7649, 18871, 16254, 3714, 7649, 3794, 8717, 26895, 4724, 11536, 8608, 5172, 2288, 8608, 3555, 27884, 5551, 25513, 27884], "avg_logprob": -0.3320312553218433, "compression_ratio": 2.1875, "no_speech_prob": 0.0, "words": [{"start": 4093.3, "end": 4093.82, "word": "بطلع", "probability": 0.643798828125}, {"start": 4093.82, "end": 4094.14, "word": " نيل", "probability": 0.12109375}, {"start": 4094.14, "end": 4094.28, "word": " بون", "probability": 0.6182861328125}, {"start": 4094.28, "end": 4094.48, "word": " سفر", "probability": 0.647216796875}, {"start": 4094.48, "end": 4094.92, "word": " سبعة", "probability": 0.9202473958333334}, {"start": 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0.9451497395833334}, {"start": 4259.74, "end": 4260.66, "word": " المخاطرة", "probability": 0.967041015625}, {"start": 4260.66, "end": 4260.96, "word": " كل", "probability": 0.71240234375}, {"start": 4260.96, "end": 4261.1, "word": " ما", "probability": 0.85595703125}, {"start": 4261.1, "end": 4261.54, "word": " تقلل", "probability": 0.97021484375}, {"start": 4261.54, "end": 4261.58, "word": " ال", "probability": 0.92529296875}, {"start": 4261.58, "end": 4261.86, "word": " tolerance", "probability": 0.955078125}, {"start": 4261.86, "end": 4262.06, "word": " على", "probability": 0.83203125}, {"start": 4262.06, "end": 4262.64, "word": " حالك", "probability": 0.9978841145833334}, {"start": 4262.64, "end": 4262.64, "word": " ..", "probability": 0.311767578125}, {"start": 4262.64, "end": 4263.32, "word": " اه", "probability": 0.746337890625}, {"start": 4263.32, "end": 4264.38, "word": " تفضل", "probability": 0.907958984375}, {"start": 4264.38, "end": 4269.02, "word": " نعم", "probability": 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سنتين في المية يعني في تطبيق زيك تطبيق تجاري مثلا يعني على الأغلب بيستخدموا الخمس سنتين في المية خمس سنتين في المية درجة تيقن خمس سنتين في المية", "tokens": [6027, 20292, 39896, 2423, 24793, 11778, 38251, 2655, 2288, 1804, 4032, 3175, 36764, 24401, 3714, 11536, 6055, 3794, 27884, 8608, 2655, 3660, 12771, 13672, 1829, 39896, 16490, 2304, 3794, 8608, 29399, 9957, 8978, 9673, 10632, 37495, 22653, 8978, 6055, 9566, 21292, 4587, 30767, 1829, 4117, 6055, 9566, 21292, 4587, 6055, 7435, 9640, 1829, 50113, 15040, 37495, 22653, 15844, 16247, 17082, 46152, 4724, 1829, 14851, 9778, 40448, 14407, 33962, 2304, 3794, 8608, 29399, 9957, 8978, 9673, 10632, 16490, 2304, 3794, 8608, 29399, 9957, 8978, 9673, 10632, 11778, 47341, 3660, 6055, 1829, 4587, 1863, 16490, 2304, 3794, 8608, 29399, 9957, 8978, 9673, 10632], "avg_logprob": -0.2539828504417457, "compression_ratio": 2.067415730337079, "no_speech_prob": 0.0, "words": [{"start": 4278.2, "end": 4278.48, "word": "اللي", "probability": 0.82421875}, {"start": 4278.48, "end": 4278.78, "word": " هي", "probability": 0.87451171875}, {"start": 4278.78, "end": 4279.34, "word": " الكم", "probability": 0.2496337890625}, {"start": 4279.34, "end": 4279.84, "word": " دسمتر", "probability": 0.477569580078125}, {"start": 4279.84, "end": 4280.08, "word": " plus", "probability": 0.42919921875}, {"start": 4280.08, "end": 4280.22, "word": " و", "probability": 0.66259765625}, {"start": 4280.22, "end": 4280.54, "word": " minus", "probability": 0.56103515625}, {"start": 4280.54, "end": 4281.28, "word": " واحد", "probability": 0.9013671875}, {"start": 4281.28, "end": 4281.48, "word": " مون", "probability": 0.37744140625}, {"start": 4281.48, "end": 4281.78, "word": " تسعة", "probability": 0.9739583333333334}, {"start": 4281.78, "end": 4282.34, "word": " ستة", "probability": 0.96875}, {"start": 4282.34, "end": 4283.2, "word": " sigma", "probability": 0.294189453125}, {"start": 4283.2, "end": 4284.54, "word": " اللي", "probability": 0.8056640625}, {"start": 4284.54, "end": 4284.82, "word": " هي", "probability": 0.908203125}, {"start": 4284.82, "end": 4285.3, "word": " خمس", "probability": 0.97900390625}, {"start": 4285.3, "end": 4285.5, "word": " سنتين", "probability": 0.6183268229166666}, {"start": 4285.5, "end": 4285.6, "word": " في", "probability": 0.3935546875}, {"start": 4285.6, "end": 4285.92, "word": " المية", "probability": 0.78369140625}, {"start": 4285.92, "end": 4299.36, "word": " يعني", "probability": 0.668212890625}, {"start": 4299.36, "end": 4299.48, "word": " في", "probability": 0.513671875}, {"start": 4299.48, "end": 4299.86, "word": " تطبيق", "probability": 0.9873046875}, {"start": 4299.86, "end": 4300.18, "word": " زيك", "probability": 0.7142740885416666}, {"start": 4300.18, "end": 4300.5, "word": " تطبيق", "probability": 0.8248291015625}, {"start": 4300.5, "end": 4300.92, "word": " تجاري", "probability": 0.90087890625}, {"start": 4300.92, "end": 4301.28, "word": " مثلا", "probability": 0.917236328125}, {"start": 4301.28, "end": 4302.62, "word": " يعني", "probability": 0.765380859375}, {"start": 4302.62, "end": 4302.78, "word": " على", "probability": 0.7236328125}, {"start": 4302.78, "end": 4303.08, "word": " الأغلب", "probability": 0.9547526041666666}, {"start": 4303.08, "end": 4303.52, "word": " بيستخدموا", "probability": 0.8671875}, {"start": 4303.52, "end": 4303.74, "word": " الخمس", "probability": 0.8611653645833334}, {"start": 4303.74, "end": 4303.84, "word": " سنتين", "probability": 0.7931315104166666}, {"start": 4303.84, "end": 4303.92, "word": " في", "probability": 0.984375}, {"start": 4303.92, "end": 4304.26, "word": " المية", "probability": 0.9794921875}, {"start": 4304.26, "end": 4305.58, "word": " خمس", "probability": 0.9212239583333334}, {"start": 4305.58, "end": 4305.68, "word": " سنتين", "probability": 0.9749348958333334}, {"start": 4305.68, "end": 4305.82, "word": " في", "probability": 0.9931640625}, {"start": 4305.82, "end": 4306.0, "word": " المية", "probability": 0.987548828125}, {"start": 4306.0, "end": 4306.34, "word": " درجة", "probability": 0.92919921875}, {"start": 4306.34, "end": 4306.74, "word": " تيقن", "probability": 0.7535400390625}, {"start": 4306.74, "end": 4307.0, "word": " خمس", "probability": 0.974609375}, {"start": 4307.0, "end": 4307.1, "word": " سنتين", "probability": 0.9881184895833334}, {"start": 4307.1, "end": 4307.22, "word": " في", "probability": 0.994140625}, {"start": 4307.22, "end": 4307.46, "word": " المية", "probability": 0.98583984375}], "temperature": 1.0}, {"id": 147, "seek": 432968, "start": 4310.46, "end": 4329.68, "text": "طب امشي كل إشي، معناه تقوله انت قادر تدمرس على حالك، بتقلي ال confidence، بتكونش .. يعني بتصير تأكدك أقل، و بتزيد ال .. بتزيد المخاطر على حالك، هيك نكون خلصنا المحاضرة، اعطيكم عافية", "tokens": [9566, 3555, 1975, 2304, 8592, 1829, 28242, 11933, 8592, 1829, 12399, 20449, 8315, 3224, 6055, 39648, 3224, 16472, 2655, 12174, 18513, 2288, 6055, 3215, 29973, 3794, 15844, 11331, 6027, 4117, 12399, 39894, 4587, 20292, 2423, 6687, 12399, 39894, 30544, 8592, 4386, 37495, 22653, 39894, 9381, 13546, 6055, 10721, 4117, 3215, 4117, 5551, 4587, 1211, 12399, 4032, 39894, 11622, 25708, 2423, 4386, 39894, 11622, 25708, 9673, 9778, 41193, 2288, 15844, 11331, 6027, 4117, 12399, 39896, 4117, 8717, 30544, 16490, 1211, 9381, 8315, 9673, 5016, 46958, 25720, 12399, 1975, 3615, 9566, 1829, 24793, 6225, 31845, 10632], "avg_logprob": -0.29753288783525167, "compression_ratio": 1.6578947368421053, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 4310.46, "end": 4310.72, "word": "طب", "probability": 0.949462890625}, {"start": 4310.72, "end": 4311.06, "word": " امشي", "probability": 0.78363037109375}, {"start": 4311.06, "end": 4311.28, "word": " كل", "probability": 0.93896484375}, {"start": 4311.28, "end": 4314.64, "word": " إشي،", "probability": 0.759765625}, {"start": 4314.64, "end": 4315.54, "word": " معناه", "probability": 0.75341796875}, {"start": 4315.54, "end": 4315.86, "word": " تقوله", "probability": 0.6295572916666666}, {"start": 4315.86, "end": 4315.98, "word": " انت", "probability": 0.42327880859375}, {"start": 4315.98, "end": 4316.16, "word": " قادر", "probability": 0.76025390625}, {"start": 4316.16, "end": 4316.68, "word": " تدمرس", "probability": 0.60540771484375}, {"start": 4316.68, "end": 4316.76, "word": " على", "probability": 0.280517578125}, {"start": 4316.76, "end": 4319.48, "word": " حالك،", "probability": 0.82244873046875}, {"start": 4319.48, "end": 4320.06, "word": " بتقلي", "probability": 0.7130533854166666}, {"start": 4320.06, "end": 4320.22, "word": " ال", "probability": 0.98779296875}, {"start": 4320.22, "end": 4321.8, "word": " confidence،", "probability": 0.892822265625}, {"start": 4321.8, "end": 4322.14, "word": " بتكونش", "probability": 0.7902018229166666}, {"start": 4322.14, "end": 4322.28, "word": " ..", "probability": 0.56982421875}, {"start": 4322.28, "end": 4322.48, "word": " يعني", "probability": 0.844970703125}, {"start": 4322.48, "end": 4322.94, "word": " بتصير", "probability": 0.9269205729166666}, {"start": 4322.94, "end": 4323.4, "word": " تأكدك", "probability": 0.815625}, {"start": 4323.4, "end": 4324.58, "word": " أقل،", "probability": 0.84075927734375}, {"start": 4324.58, "end": 4324.82, "word": " و", "probability": 0.73095703125}, {"start": 4324.82, "end": 4325.12, "word": " بتزيد", "probability": 0.931640625}, {"start": 4325.12, "end": 4325.36, "word": " ال", "probability": 0.2144775390625}, {"start": 4325.36, "end": 4325.36, "word": " ..", "probability": 0.83203125}, {"start": 4325.36, "end": 4325.76, "word": " بتزيد", "probability": 0.8889973958333334}, {"start": 4325.76, "end": 4326.28, "word": " المخاطر", "probability": 0.94140625}, {"start": 4326.28, "end": 4326.46, "word": " على", "probability": 0.87109375}, {"start": 4326.46, "end": 4327.68, "word": " حالك،", "probability": 0.968505859375}, {"start": 4327.68, "end": 4327.86, "word": " هيك", "probability": 0.90234375}, {"start": 4327.86, "end": 4328.0, "word": " نكون", "probability": 0.5433349609375}, {"start": 4328.0, "end": 4328.46, "word": " خلصنا", "probability": 0.9647216796875}, {"start": 4328.46, "end": 4329.16, "word": " المحاضرة،", "probability": 0.977734375}, {"start": 4329.16, "end": 4329.36, "word": " اعطيكم", "probability": 0.635107421875}, {"start": 4329.36, "end": 4329.68, "word": " عافية", "probability": 0.6090494791666666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 4330.127, "duration_after_vad": 3660.802499999984}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/EatQYMBMLRg.srt b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/EatQYMBMLRg.srt
new file mode 100644
index 0000000000000000000000000000000000000000..ca58ed56ea9c886d0b134bb75a527e9470d64e06
--- /dev/null
+++ b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/EatQYMBMLRg.srt
@@ -0,0 +1,2131 @@
+1
+00:00:05,180 --> 00:00:08,440
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:08,440 --> 00:00:13,620
+وبركاته اليوم هنكمل في مادة القياسات شبطر ثلاثة
+
+3
+00:00:13,620 --> 00:00:19,160
+تقييم وعرض البيانات المحاضرة اللي فاتت حكينا عن
+
+4
+00:00:19,160 --> 00:00:24,360
+the probability density function اللي هو Gaussian PDF
+
+5
+00:00:24,360 --> 00:00:27,180
+of X يساوي واحد على سيجما جذر تربيعي على 2π
+
+6
+00:00:27,180 --> 00:00:30,560
+Exponential minus (X - μ)² / 2
+
+7
+00:00:30,560 --> 00:00:37,680
+سيجما تربيع  X هي قيمة قراءة معينة، μ هي القيمة
+
+8
+00:00:37,680 --> 00:00:42,500
+المتوسطة لكل الـpopulation، و σ هي الانحراف
+
+9
+00:00:42,500 --> 00:00:44,200
+المعيارى لكل الـ population
+
+10
+00:00:48,010 --> 00:00:53,190
+و الـ average لعدد من القراءات بتساوي المجموع على
+
+11
+00:00:53,190 --> 00:00:59,910
+عددها، و الانحراف لأي قراءة عن القيمة المتوسطة هو
+
+12
+00:00:59,910 --> 00:01:05,050
+يساوي القراءة اللي هي X ناقص القيمة المتوسطة
+
+13
+00:01:12,040 --> 00:01:16,480
+الـstandard deviation للـpopulation بيساوي جذر
+
+14
+00:01:16,480 --> 00:01:21,160
+التربيعي للـ summation للـ deviations تربيع على n
+
+15
+00:01:21,160 --> 00:01:25,780
+.
+
+16
+00:01:25,780 --> 00:01:30,960
+هنا وصلنا الآن للتثبيت، عشان نعمل الـ probability density
+
+17
+00:01:30,960 --> 00:01:36,860
+function standardization، هو يكون symmetric حول
+
+18
+00:01:36,860 --> 00:01:39,420
+الـ y axis. احنا كان عندنا
+
+19
+00:01:43,070 --> 00:01:48,010
+أي density function هي
+
+20
+00:01:48,010 --> 00:01:52,950
+القيمة الرئيسية، هذا
+
+21
+00:01:52,950 --> 00:02:01,390
+x هذا، f(x) لو
+
+22
+00:02:01,390 --> 00:02:02,770
+أخذنا أي قراءة x
+
+23
+00:02:13,090 --> 00:02:23,910
+و عرفنا z بصورة (x - μ) / σ، هذه الشيء
+
+24
+00:02:23,910 --> 00:02:27,450
+هتكون
+
+25
+00:02:27,450 --> 00:02:37,030
+z لـ σ، معناته زي... و بنعرف متغير جديد
+
+26
+00:02:37,030 --> 00:02:41,650
+z
+
+27
+00:02:41,650 --> 00:02:42,270
+المتغير الجديد
+
+28
+00:02:45,880 --> 00:02:56,720
+مش زي x، z و f(z)، يعني أنا عملت shift لكل
+
+29
+00:02:56,720 --> 00:03:03,940
+الـ curve بحيث يصير symmetrical حول المحور الرأسي
+
+30
+00:03:03,940 --> 00:03:07,580
+فبيصير
+
+31
+00:03:07,580 --> 00:03:09,420
+المساحة من -∞
+
+32
+00:03:13,000 --> 00:03:19,440
+الـ area من -∞ إلى ∞ تحت الـ
+
+33
+00:03:19,440 --> 00:03:21,420
+probability density function بتساوي
+
+34
+00:03:21,420 --> 00:03:28,600
+واحد، لأنه بتغطي كل الاحتمالات الممكنة، لأن المساحة من
+
+35
+00:03:28,600 --> 00:03:32,420
+-∞ إلى ∞ بتغطي كل الاحتمالات لأنها
+
+36
+00:03:32,420 --> 00:03:38,260
+تمثل مساحة 100%، واحد، فهتصير
+
+37
+00:03:38,260 --> 00:03:39,520
+عنده، يعني
+
+38
+00:03:42,390 --> 00:03:49,250
+أنا كان عندي f(x) يساوي
+
+39
+00:03:49,250 --> 00:04:01,110
+واحد على سيجما جذر تربيعي 2π × exponential لـ
+
+40
+00:04:01,110 --> 00:04:09,150
+- (x - μ)² / 2σ²
+
+41
+00:04:09,150 --> 00:04:17,250
+هيصير f(z) = 1 / σ جذر تربيعي 2π ×
+
+42
+00:04:17,250 --> 00:04:22,590
+exponential لـ لأن عندي أنا (x - μ)
+
+43
+00:04:22,590 --> 00:04:28,370
+/ σ اللي هي z، هتكون - يعني هذول هذا
+
+44
+00:04:28,370 --> 00:04:36,130
+هيكون -z² / 2
+
+45
+00:04:53,640 --> 00:04:57,500
+الآن صارت الـ density function  symmetric
+
+46
+00:04:57,500 --> 00:05:05,420
+حول المحور الرأسي اللي هو f(z)، هذا f(z)
+
+47
+00:05:05,420 --> 00:05:10,920
+اللي لو أخدت +σ أو -σ على اليمين
+
+48
+00:05:10,920 --> 00:05:16,960
+هذا +σ، هذا +2σ، +3σ
+
+49
+00:05:21,470 --> 00:05:24,090
+من -σ إلى +σ  أكثر بتعطينا
+
+50
+00:05:24,090 --> 00:05:30,950
+confidence أو درجة ثقة 68%، اللي هو ±
+
+51
+00:05:30,950 --> 00:05:37,150
+2σ 95%، ± 3σ 99.7%
+
+52
+00:05:41,530 --> 00:05:47,550
+الآن الـ area، الـ area اللي أنتم شايفينه مضلل بالأسود
+
+53
+00:05:47,550 --> 00:05:54,990
+تمثل احتمالية أن z تكون بين صفر و some value z
+
+54
+00:05:54,990 --> 00:06:01,430
+احتمالية أن z تكون بين صفر و some value z، طبعاً
+
+55
+00:06:01,430 --> 00:06:05,130
+هذا الـ PDF بسميه z-distribution
+
+56
+00:06:13,800 --> 00:06:18,900
+الـ z-distribution له table، و السبب في الـ
+
+57
+00:06:18,900 --> 00:06:22,760
+tabulation أنه
+
+58
+00:06:22,760 --> 00:06:28,440
+عشان أجد مساحة، بدي أعمل integral، صح؟ بدي أعمل
+
+59
+00:06:28,440 --> 00:06:31,920
+integral، يعني أنا بدي أحسب الـ probability أن z
+
+60
+00:06:31,920 --> 00:06:40,420
+تكون من صفر إلى z، هتكون تكامل f(z) dz، يعني هتكون
+
+61
+00:06:40,420 --> 00:06:46,450
+تكامل (1 / σجذر تربيعي 2π) ×exp(-z²/2) dz، طبعاً هذا تكامل ما بنعملش
+
+62
+00:06:46,450 --> 00:06:50,130
+هذا التكامل، ما بنعمله
+
+63
+00:06:50,130 --> 00:06:55,550
+بالطرق اللي هو أنك تجيب حل exact بطرق التحليل
+
+64
+00:06:55,550 --> 00:06:59,930
+الرقمي، بتجيب يعني حل تقريبي باستخدام طرق التحليل
+
+65
+00:06:59,930 --> 00:07:05,690
+الرقمي، عشان هيك عامل population  لـ z من صفر
+
+66
+00:07:05,690 --> 00:07:08,830
+صفر، point 1، point 2، point 3، point 4
+
+67
+00:07:08,830 --> 00:07:14,480
+و كذا، طبعاً هذه جزء من الـ table، إذا كانت z مثلاً
+
+68
+00:07:14,480 --> 00:07:21,640
+point 4
+
+69
+00:07:21,640 --> 00:07:25,940
+خمسة، الـ
+
+70
+00:07:25,940 --> 00:07:32,300
+z = point 45، لأن بتطلع أن عندي point 4
+
+71
+00:07:32,300 --> 00:07:36,940
+وعندي هنا عشان أضيف الكسر الثاني هتيجي هنا point
+
+72
+00:07:36,940 --> 00:07:42,210
+05، فهتكون إيش القيمة اللي هي هذه: point 1
+
+73
+00:07:42,210 --> 00:07:44,710
+736... point 1736... point
+
+74
+00:07:44,710 --> 00:07:45,550
+1736... point 1736...
+
+75
+00:07:45,550 --> 00:07:48,250
+point 1736... point 1736...
+
+76
+00:07:48,250 --> 00:07:48,910
+point 1736... point 1736...
+
+77
+00:07:48,910 --> 00:07:50,310
+point 1736... point 1736...
+
+78
+00:07:50,310 --> 00:07:54,550
+point 1736... point 1736...
+
+79
+00:07:54,550 --> 00:07:59,390
+point 1736... point 1736...
+
+80
+00:07:59,390 --> 00:08:09,070
+point 1736... point 1736...
+
+81
+00:08:09,070 --> 00:08:18,800
+point 1736...  أنى هستخدم سطر الثالث، همشي أفقي لحد هتكون
+
+82
+00:08:18,800 --> 00:08:23,300
+point 1065، الـ point 1064
+
+83
+00:08:23,300 --> 00:08:29,700
+هى المساحة تحت الـ f(z) بين صفر و point
+
+84
+00:08:29,700 --> 00:08:33,960
+27، point 27، وهذا تمثل احتمالية الـ
+
+85
+00:08:33,960 --> 00:08:40,510
+z تكون واقع في الـ range هذا، الاحتمالية أن z تكون
+
+86
+00:08:40,510 --> 00:08:45,390
+بين صفر و point 27، لو حكيت point 3
+
+87
+00:08:45,390 --> 00:08:51,590
+تسعة، صحيح
+
+88
+00:08:51,590 --> 00:08:56,610
+إيش اللي سويت أنا؟ طلعت على الـ point 3، مشيت
+
+89
+00:08:56,610 --> 00:09:02,000
+أفقي لحد ما وصلت للتسعة، point 39، فبتعطيني
+
+90
+00:09:02,000 --> 00:09:04,620
+المساحة point 151، فأنتم هذه احتمالية
+
+91
+00:09:04,620 --> 00:09:11,100
+أن z تكون بين صفر و point 39، طيب نشوف
+
+92
+00:09:11,100 --> 00:09:14,800
+example
+
+93
+00:09:14,800 --> 00:09:17,080
+الـ example بيحكي: what is the area
+
+94
+00:09:27,150 --> 00:09:41,950
+ماهي المنطقة تحت الكيرف؟ ماهي الكيرف z
+
+95
+00:09:41,950 --> 00:09:50,630
+يساوي -1.43 و 1.43
+
+96
+00:09:50,630 --> 00:09:54,190
+هنا دي z، هنا f(z)
+
+97
+00:09:58,270 --> 00:10:04,130
+بين -1.43 و 1.43، هتكون الـ area هذه مضروبة في
+
+98
+00:10:04,130 --> 00:10:09,990
+المساحة هذه، صح؟ لأن هو symmetric، معناته
+
+99
+00:10:09,990 --> 00:10:19,450
+بروحة على الـ tables، بروحة على الـ tables و
+
+100
+00:10:19,450 --> 00:10:20,230
+أطلع على الـ z
+
+101
+00:10:25,520 --> 00:10:30,280
+1.43، هاي 1.43، وين
+
+102
+00:10:30,280 --> 00:10:36,400
+هيكون عنده .4236، .4236
+
+103
+00:10:36,400 --> 00:10:43,720
+معناته الـ area هتكون أو
+
+104
+00:10:43,720 --> 00:10:50,820
+بدي أحكي الـ area هتكون 2 × كم
+
+105
+00:10:55,050 --> 00:11:03,330
+في .4236؟ .4236 يعني
+
+106
+00:11:03,330 --> 00:11:14,490
+هتكون .8472، صح؟
+
+107
+00:11:14,490 --> 00:11:18,870
+طيب إيش الـ significance؟ إيش معناته؟
+
+108
+00:11:23,660 --> 00:11:30,580
+يعني الاحتمال، probability، أن z تكون أكبر أو
+
+109
+00:11:30,580 --> 00:11:36,020
+تساوي -1.43 و أصغر من أو
+
+110
+00:11:36,020 --> 00:11:41,600
+تساوي 1.43 بتساوي .8472، يعني as a percentage هتكون
+
+111
+00:11:41,600 --> 00:11:48,160
+84.72%
+
+112
+00:11:48,160 --> 00:11:53,100
+أربعة وثمانين point سبعة اثنين في المئة
+
+113
+00:12:05,760 --> 00:12:21,520
+السؤال كان: example ثاني: what range
+
+114
+00:12:21,520 --> 00:12:24,640
+of z will contain 90% of the data
+
+115
+00:12:24,640 --> 00:12:33,460
+إيش الـ range اللي هيحتوي قيم x أو z تسعين
+
+116
+00:12:33,460 --> 00:12:39,190
+في المئة؟ يعني هم عطيني الـ probability، مضبوط، مضبوط
+
+117
+00:12:39,190 --> 00:12:43,570
+تسعين في المئة، لأن الـ 90% يعني هي
+
+118
+00:12:43,570 --> 00:12:50,130
+الـ area، يعني المساحة هذه كلها، هذه الـ area تسعة و من
+
+119
+00:12:50,130 --> 00:12:58,170
+عشرة، معناته نصها كم؟ هتكون الـ .5، اللي
+
+120
+00:12:58,170 --> 00:13:04,420
+هتكون 0.45، هذه الـ area .5،
+
+121
+00:13:04,420 --> 00:13:09,040
+معناته هذه اللي هي الـ probability أن z أكبر أو يساوي
+
+122
+00:13:09,040 --> 00:13:15,940
+صفر و أصغر من أو يساوي point 45، لأ، مش عارفين
+
+123
+00:13:15,940 --> 00:13:24,240
+إحنا z أكبر
+
+124
+00:13:24,240 --> 00:13:31,730
+أو يساوي صفر و أصغر من أو يساوي some value z1، واضغط
+
+125
+00:13:31,730 --> 00:13:36,210
+بالسوا point 45، الآن أنا موجود z1، أنا
+
+126
+00:13:36,210 --> 00:13:39,310
+هروح
+
+127
+00:13:39,310 --> 00:13:44,410
+على الـ table، وأطلع
+
+128
+00:13:44,410 --> 00:13:57,030
+على المساحة .45
+
+129
+00:13:57,030 --> 00:13:57,850
+.45
+
+130
+00:14:01,370 --> 00:14:11,970
+يعني أنا جاي في المنطقة هذه، صح؟ مضبوط؟ بس خليني
+
+131
+00:14:11,970 --> 00:14:15,670
+أطلع، يعني أنا جاي بين الـ point 04 و point 0
+
+132
+00:14:15,670 --> 00:14:24,390
+خمسة، صح؟ هاي عندي، إحنا جايين هنا، يعني أنا بين
+
+133
+00:14:31,980 --> 00:14:38,000
+جاي هنا في المنطقة هذه
+
+134
+00:14:38,000 --> 00:14:43,460
+عندي هنا .4495، وهنا عندي .4505
+
+135
+00:14:43,460 --> 00:14:48,920
+واضح الـ point، الـ point .45 جاي في النص بالضبط
+
+136
+00:14:48,920 --> 00:14:56,560
+المهم أنتم هتكون الـ z إيش
+
+137
+00:14:56,560 --> 00:15:07,160
+هو القيمة؟ عندي هذه 1.6، لأ هي جاءت بين الـ
+
+138
+00:15:07,160 --> 00:15:12,980
+point 04 و الـ point 05، يعني 1.6
+
+139
+00:15:12,980 --> 00:15:23,810
+بالضبط، يعني هي هتكون 1.6، وفي عندي هنا جاءت
+
+140
+00:15:23,810 --> 00:15:35,930
+بين 1.64 و 1.65
+
+141
+00:15:35,930 --> 00:15:38,130
+1.65
+
+142
+00:15:38,130 --> 00:15:38,210
+1.65
+
+143
+00:15:38,210 --> 00:15:38,270
+1.65
+
+144
+00:15:38,270 --> 00:15:38,290
+1.65
+
+145
+00:15:38,290 --> 00:15:45,990
+1.65
+
+146
+00:15:45,990 --> 00:16:09,330
+1.65، -1.645، أصغر من 1.645، طيب
+
+147
+00:16:17,630 --> 00:16:20,470
+لو أنا السابق كنا... كنا نحكي على theory based on
+
+148
+00:16:20,470 --> 00:16:25,490
+population، يعني كل population معروف عندي، لكن على
+
+149
+00:16:25,490 --> 00:16:31,050
+أرض الواقع الـ population بيكون ما يتاح لي أني آخذ كل
+
+150
+00:16:31,050 --> 00:16:34,590
+القراءات بتاعة الـ population، لما نعمل دراسة ما
+
+151
+00:16:34,590 --> 00:16:37,890
+بيكون الـ population مثلاً زي ما أحكي أنا مرض السكر
+
+152
+00:16:37,890 --> 00:16:45,940
+في قطاع غزة، مثلاً، العدد بنحكي مثلاً خمسين ألف، مثلاً، مش
+
+153
+00:16:45,940 --> 00:16:49,820
+ممكن آخذ كل القراءات، يعني، أو الجامعة، الصعب، فأنا بعمل
+
+154
+00:16:49,820 --> 00:16:57,460
+دراسة مثلاً على عينة ألف شخص، خمسمائة، مئة، فالآن شوف
+
+155
+00:16:57,460 --> 00:17:01,740
+الـ theory based on sample كيف بيصير التغيرات عليها، طبعاً
+
+156
+00:17:01,740 --> 00:17:06,100
+الهدف من theory based on sample أنه أستخدم القيم
+
+157
+00:17:06,100 --> 00:17:11,120
+الوسطية اللي بنحصل عليها من الـ sample عشان أعمل
+
+158
+00:17:11,120 --> 00:17:17,420
+حساب أو تقدير لـ الـ mean، القيمة الوسطية، أو الانحراف
+
+159
+00:17:17,420 --> 00:17:21,600
+المعيارى لكل الـ population، يعني الهدف من استخدام الـ
+
+160
+00:17:21,600 --> 00:17:27,140
+sample أن أحصل، يعني أستخدم القيم المتوسطة اللي بصح
+
+161
+00:17:27,140 --> 00:17:32,840
+عليها من الـ sample عشان أحسب اللي هي القيمة الوسطية
+
+162
+00:17:32,840 --> 00:17:36,240
+و الـ standard deviation للـ population
+
+163
+00:17:40,040 --> 00:17:44,020
+أي عينة أخذتها، أنا عملت تجربة وأخذت عدد من القراءات
+
+164
+00:17:44,020 --> 00:17:50,540
+عددها N، عند القراءة x₁, x₂, x₃، و x₄ لحد xₙ، المتوسط
+
+165
+00:17:50,540 --> 00:17:58,880
+طبعاً بيساوي مجموع القراءات على عددهم، الآن
+
+166
+00:17:58,880 --> 00:18:06,040
+الـ standard deviation، طبعاً أنا في حالة الـ
+
+167
+00:18:06,040 --> 00:18:06,480
+population
+
+168
+00:18:10,920 --> 00:18:20,320
+باستخدام القيمة الوسطية، إيش μ؟ في حالة الـ sample  x̄
+
+169
+00:18:20,320 --> 00:18:25,560
+بـ standard deviation في حالة الـ population
+
+170
+00:18:25,560 --> 00:18:38,500
+σ، في حالة الـ sample sₓ، يعني هنا population، هنا
+
+171
+00:18:38,500 --> 00:18:39,700
+sample
+
+172
+00:18:43,270 --> 00:18:47,670
+الـ standard deviation في
+
+173
+00:18:47,670 --> 00:18:52,130
+حالة... أو نحكي الـ deviation لكل قراءة dᵢ، إيش
+
+174
+00:18:52,130 --> 00:19:02,850
+بيساوي؟ xᵢ - x̄، صح؟
+
+175
+00:19:02,850 --> 00:19:10,330
+الـ standard deviation لل... لل... للـ sample بيكون
+
+176
+00:19:10,330 --> 00:19:18,390
+جذر التربيعي لـ summation لـ dᵢ²، من i = 1
+
+177
+00:19:18,390 --> 00:19:24,830
+إلى N على N
+
+178
+00:19:24,830 --> 00:19:30,650
+- 1، إذا حد عارف، يعني في حالة الـ population
+
+179
+00:19:30,650 --> 00:19:33,690
+بتكون على N، في حالة الـ sample بتكون على N - 1
+
+180
+00:19:33,690 --> 00:19:39,670
+إذا حد حابب يعرف ليش، كيف اشتغل رياضياً، يرجع ل... في
+
+181
+00:19:39,670 --> 00:19:49,650
+كتير موجودة معلومات عن الـ standard deviation للـ sample
+
+182
+00:19:49,650 --> 00:19:50,970
+للسامبل،  للسامبل،  للسامبل،
+
+183
+00:19:50,970 --> 00:19:51,790
+للسامبل،
+
+223
+00:23:41,880 --> 00:23:51,360
+واحد ميجا بسكال Resolution  ال
+
+224
+00:23:51,360 --> 00:24:05,940
+number of
+
+225
+00:24:05,940 --> 00:24:11,170
+results is the number of readings falling in an
+
+226
+00:24:11,170 --> 00:24:16,790
+interval of plus or minus 0.005 Mega Pascal
+
+227
+00:24:16,790 --> 00:24:24,370
+centered about the listed pressure يعني هو كان
+
+228
+00:24:24,370 --> 00:24:29,490
+يأخذ قراءات بعدين
+
+229
+00:24:29,490 --> 00:24:34,590
+عمل جدول هو أخذ مئة قراءة أخذ مئة قراءة
+
+230
+00:24:36,410 --> 00:24:43,290
+أول واحدة مثلاً لما بيحكي 3.97 ميجاباسكال معناته
+
+231
+00:24:43,290 --> 00:24:49,950
+بيحكي كل القيم مش قراءة بالظبط 3.97 لكن قراءة
+
+232
+00:24:49,950 --> 00:24:59,330
+في range of values هتكون بين 3.965
+
+233
+00:24:59,330 --> 00:25:05,890
+لتلاتة point تسعة سبعة خمسة يعني كل قراءة
+
+234
+00:25:05,890 --> 00:25:08,190
+الواقع بين 3.965 و 3.
+
+235
+00:25:08,190 --> 00:25:13,150
+تسعة سبعة عددها ايش واحد كل القراءات اللي جات بين
+
+236
+00:25:13,150 --> 00:25:18,490
+3.975 و 3.9
+
+237
+00:25:18,490 --> 00:25:23,690
+تسعة خمسة عددها ثلاث وكل قراءات اللي بين 3.
+
+238
+00:25:23,690 --> 00:25:30,030
+تسعة تمانية خمسة و 3.995
+
+239
+00:25:30,030 --> 00:25:36,570
+إثنتا عشرة قراءة وكل قراءة اللي بين 3.9
+
+240
+00:25:36,570 --> 00:25:41,530
+تسعة خمسة و 4.005 عددها خمسة وعشرون
+
+241
+00:25:41,530 --> 00:25:48,170
+والقراءات اللي 4.005 الى 4.
+
+242
+00:25:48,170 --> 00:25:53,850
+015 عددها ثلاثة وثلاثون والقراءات
+
+243
+00:25:53,850 --> 00:25:58,830
+اللي بين 4.005 لـ 4.025
+
+244
+00:25:58,830 --> 00:26:04,870
+عددها سبعة عشر والقراءات بين 4.025
+
+245
+00:26:04,870 --> 00:26:10,730
+و 4.035 عددها ستة و
+
+246
+00:26:10,730 --> 00:26:15,310
+القراءات بين 4.035 و 4.
+
+247
+00:26:15,310 --> 00:26:20,590
+045 عددها اثنان و القراءات بين 4.0
+
+248
+00:26:20,590 --> 00:26:28,470
+أربع خمسة و 4.055 عددها واحدة طبعاً
+
+249
+00:26:28,470 --> 00:26:34,370
+هو كان ماخذ قراءات مئة قراءة و بعدين صنفهم صنف
+
+250
+00:26:34,370 --> 00:26:39,070
+القراءات ولاقي مثلاً في ال range بين 3.
+
+251
+00:26:39,070 --> 00:26:41,410
+تسعة و تسعة و خمسة و 3.975
+
+252
+00:26:41,410 --> 00:26:46,710
+قراءة واحدة ماشي و عندي مثلاً بين 4.
+
+253
+00:26:46,710 --> 00:26:48,710
+015 و 4.025
+
+254
+00:26:48,710 --> 00:26:54,590
+عددها سبعة عشر واحد كذا صنفهم بالشكل هذا number of
+
+255
+00:26:54,590 --> 00:27:03,300
+results and بعدين عمل graph اسمه histogram طبعاً
+
+256
+00:27:03,300 --> 00:27:10,080
+عندي هنا 3.
+
+257
+00:27:10,080 --> 00:27:14,400
+97 على
+
+258
+00:27:14,400 --> 00:27:20,680
+المحور الأفقي القيمة الوسطى عندي هنا 3.
+
+259
+00:27:20,680 --> 00:27:25,620
+97 صح؟ 3.98 3.
+
+260
+00:27:25,620 --> 00:27:30,540
+97 أكثر مرة تكررت واحد 3.9
+
+261
+00:27:30,540 --> 00:27:39,780
+تمانية مرتين 3.9
+
+262
+00:27:39,780 --> 00:27:49,620
+تسعة اثنتا عشرة قراءة 4.005
+
+263
+00:27:49,620 --> 00:27:58,170
+و عشرون 4.015
+
+264
+00:27:58,170 --> 00:28:05,250
+ثلاثة وثلاثون صح أو 4.015 3. و
+
+265
+00:28:05,250 --> 00:28:13,050
+ثلاثون 4.025 سبعة عشر 4.035
+
+266
+00:28:13,050 --> 00:28:20,150
+ستة وهكذا هو الهدف من ال histogram عشان يشوف يقيم
+
+267
+00:28:22,420 --> 00:28:30,700
+ال trend أو كيف شكل ال curve واضح أنه يعني قريب من
+
+268
+00:28:30,700 --> 00:28:33,700
+ال normal distribution واضح من شكل ال histogram
+
+269
+00:28:33,700 --> 00:28:40,080
+أنه قريب من ال .. طبعاً ال histogram ممكن ترسم
+
+270
+00:28:40,080 --> 00:28:46,300
+باستخدام ال Excel أو باستخدام ال Minitab أو ال
+
+271
+00:28:46,300 --> 00:28:57,120
+SPSS يعني ال Excel أو الـ Minitab أو
+
+272
+00:28:57,120 --> 00:29:06,620
+ال SPSS في برامج تانية طبعاً الآن
+
+273
+00:29:06,620 --> 00:29:14,240
+أنا أخذت القراءات و حطيتها على ال Excel العمود
+
+274
+00:29:14,240 --> 00:29:18,840
+الأول ال pressure اللي هي 3.97
+
+275
+00:29:22,830 --> 00:29:25,970
+3.97 تمثل البيانات بين 3.
+
+276
+00:29:25,970 --> 00:29:30,090
+965 لـ 3.975 صح؟ هنا
+
+277
+00:29:30,090 --> 00:29:34,890
+number of results M عندي كان ايش؟ واحد يعني هذا
+
+278
+00:29:34,890 --> 00:29:41,630
+الجدول الأصلي هذا جدول الأصلي بعدين
+
+279
+00:29:41,630 --> 00:29:48,590
+ضربت قيمة القراءة بعددها يعني 3.97 في
+
+280
+00:29:48,590 --> 00:29:52,970
+واحد 3.98 في 3.97 3.
+
+281
+00:29:52,970 --> 00:29:57,750
+98 في ثلاثة 3.99 مثلاً
+
+282
+00:29:57,750 --> 00:30:02,570
+4.02 في سبعة عشر 3.98 346 3.
+
+283
+00:30:02,570 --> 00:30:09,350
+4 بعدين حسبت ال deviation لكل
+
+284
+00:30:09,350 --> 00:30:15,830
+قراءة طيب عشان أحسب ال deviation ايش بدي أحسب حجمها
+
+285
+00:30:15,830 --> 00:30:18,810
+دول صح مظبوط
+
+286
+00:30:19,950 --> 00:30:26,090
+بجمع هدول و بقسم على ايش لأ
+
+287
+00:30:26,090 --> 00:30:35,070
+هذا مجموعهم هذا مش ال deviation هذا مجموعهم هذا ..
+
+288
+00:30:35,070 --> 00:30:40,650
+هذا لأ هذا مجموع كل القراءات لأنه هذا 3. و
+
+289
+00:30:40,650 --> 00:30:43,630
+98 في واحد هذا 3. و 98 كأنه
+
+290
+00:30:43,630 --> 00:30:45,590
+ثلاث قراءات 3.98 و 3.98
+
+291
+00:30:45,590 --> 00:30:49,180
+و 3.98 و واحد كذا هذه سأقسمها
+
+292
+00:30:49,180 --> 00:30:54,120
+على ايش على مئة بالظبط معناته بحسب اللي هو ال min
+
+293
+00:30:54,120 --> 00:31:02,520
+pressure P min بالساوية ال summation ل all
+
+294
+00:31:02,520 --> 00:31:13,660
+pressures على عددها اللي هي أربعمئة على
+
+295
+00:31:13,660 --> 00:31:16,240
+مئة يعني هتكون تساوي
+
+296
+00:31:19,570 --> 00:31:28,830
+4.008 ميجا
+
+297
+00:31:28,830 --> 00:31:34,250
+باسكال لأن
+
+298
+00:31:34,250 --> 00:31:41,310
+ال deviation في كل قراءة ال deviation بيساوي x i
+
+299
+00:31:41,310 --> 00:31:49,610
+minus x bar يعني القراءة هذه 3.97 ال
+
+300
+00:31:49,610 --> 00:31:53,350
+deviation فيها هيكون 3.97 ناقص
+
+301
+00:31:53,350 --> 00:31:57,290
+4.008 ال deviation في القراءة
+
+302
+00:31:57,290 --> 00:32:03,090
+الثانية 3.98 ناقص 4.008 ال deviation في القراءة الثالثة 3.
+
+303
+00:32:03,090 --> 00:32:07,410
+99 ناقص 4.008 ال deviation في القراءة الرابعة 4.
+
+304
+00:32:07,410 --> 00:32:11,750
+ناقص 4.008
+
+305
+00:32:11,750 --> 00:32:17,850
+القراءة الرابعة ال deviation فيها هيكون 4 ناقص
+
+306
+00:32:17,850 --> 00:32:20,550
+4.008 واحدة كذا هذه ال
+
+307
+00:32:20,550 --> 00:32:27,230
+deviations الآن هربعهم هوجد deviations تربيع ال
+
+308
+00:32:27,230 --> 00:32:33,410
+deviations تربيع الآن ال deviations تربيع أنت
+
+309
+00:32:33,410 --> 00:32:38,810
+بتجمع هذه أولاً، كرها مرة ومرة هذه ثلاث
+
+310
+00:32:38,810 --> 00:32:43,650
+وأنا أحضرها بال M في ال deviation تربيع لأنه بتحسب
+
+311
+00:32:43,650 --> 00:32:49,640
+أن ال standard deviation الـ Sx بالساوية جذر التربيعي
+
+312
+00:32:49,640 --> 00:32:54,580
+للـ summation للـ deviation التربيعي على الـ minus
+
+313
+00:32:54,580 --> 00:33:00,380
+واحد لأن ال deviation الأول تربيع مكرر مرة واحدة
+
+314
+00:33:00,380 --> 00:33:03,320
+ال deviation الثاني تربيع مكرر ثلاث مرات بقى أنا
+
+315
+00:33:03,320 --> 00:33:09,240
+أحضرها في ثلاث صح؟ يعني ستكون ال summation هذه
+
+316
+00:33:09,240 --> 00:33:11,280
+ستكون واحد
+
+317
+00:33:13,710 --> 00:33:20,110
+في 0.014 في 1 + 3 في 0.0
+
+318
+00:33:20,110 --> 00:33:25,310
+077 اللي هي هذه صح لأن بجمع هدول كلهم
+
+319
+00:33:25,310 --> 00:33:34,450
+بيطلع مجموعهم اللي هو summation لل deviation تربيع
+
+320
+00:33:34,450 --> 00:33:37,870
+اللي هو 0.186
+
+321
+00:33:46,280 --> 00:33:58,140
+0.186 معناته هيكون أن ال Sx الجذر التربيعي لـ 0.186
+
+322
+00:33:58,140 --> 00:34:04,580
+على 99 بيطلع
+
+323
+00:34:04,580 --> 00:34:08,820
+ال standard deviation بيساوي 0.014
+
+324
+00:34:10,940 --> 00:34:16,920
+0.014 يعني إحنا حسبنا ال mean للعينة
+
+325
+00:34:16,920 --> 00:34:21,400
+اللي طلعت 4.008 و ال standard
+
+326
+00:34:21,400 --> 00:34:28,800
+deviation للعينة اللي طلعت 0.014 ميجا
+
+327
+00:34:28,800 --> 00:34:36,980
+باسكال ال
+
+328
+00:34:36,980 --> 00:34:37,940
+interval
+
+329
+00:34:41,140 --> 00:35:03,280
+اللي بتحتوي على 95% من ال pressure rating هو
+
+330
+00:35:03,280 --> 00:35:10,600
+أساساً مش زي هيك صح؟ مظبوط؟
+
+331
+00:35:12,600 --> 00:35:27,960
+وهذا ايش ال Sx معناته
+
+332
+00:35:27,960 --> 00:35:33,800
+هاخد أنا ال 95% من البيانات هاخد 1.
+
+333
+00:35:33,800 --> 00:35:44,390
+96  SP 1.96 SP يعني هذه
+
+334
+00:35:44,390 --> 00:35:50,850
+هي المساحة صح بس
+
+335
+00:35:50,850 --> 00:36:02,970
+هو ده حسب ال z في الأول صح ال z ده شو بيساوي اللي
+
+336
+00:36:02,970 --> 00:36:08,510
+هو x bar -
+
+337
+00:36:08,510 --> 00:36:16,530
+ال z بيساوي اللي هو x - x
+
+338
+00:36:16,530 --> 00:36:28,690
+bar على Sx صح مظبوط نتأكد المعادلة هاي
+
+339
+00:36:28,690 --> 00:36:32,410
+هو مظبوط x - x bar على Sx
+
+340
+00:36:41,930 --> 00:36:47,290
+الآن المساحة هذه يعني
+
+341
+00:36:47,290 --> 00:36:54,210
+هيكون عندها اللي هي بين اللي هيمثل هذه ال area
+
+342
+00:36:54,210 --> 00:37:02,450
+بتساوي 95% 95
+
+343
+00:37:02,450 --> 00:37:06,350
+% هتكون
+
+344
+00:37:06,350 --> 00:37:08,750
+ال pressure
+
+345
+00:37:12,020 --> 00:37:17,320
+بيساوي اللي هو ال average value 4.0
+
+346
+00:37:17,320 --> 00:37:24,880
+زائد أو ناقص 0.
+
+347
+00:37:24,880 --> 00:37:33,920
+027 ميجا باسكال ال
+
+348
+00:37:33,920 --> 00:37:38,720
+هادى اللي هادى عنده
+
+349
+00:37:43,210 --> 00:37:51,690
+0.027 صح طبعاً
+
+350
+00:37:51,690 --> 00:37:57,550
+بدرجة يقين بدرجة يقين خمسة وتسعين في المئة يعني
+
+351
+00:37:57,550 --> 00:38:03,750
+إحتمالية أن القراءة من هذه التجربة تكون واقعة في
+
+352
+00:38:03,750 --> 00:38:08,290
+ال range 4.008 plus or minus 0.
+
+353
+00:38:08,290 --> 00:38:15,620
+027 خمسة وتسعين في المئة مناطق إحتمال النجاح
+
+354
+00:38:15,620 --> 00:38:19,980
+أن تكون القراءة في ال range هذا هو ايش؟ خمسة وتسعين
+
+355
+00:38:19,980 --> 00:38:23,300
+في المئة اللي هو .. هي الخمسة وتسعين في المئة اللي هي درجة
+
+356
+00:38:23,300 --> 00:38:28,040
+اليقين أنا متيقن بنسبة خمسة وتسعين في المئة بأحكي عن
+
+357
+00:38:28,040 --> 00:38:32,660
+إحتمال one
+
+358
+00:38:32,660 --> 00:38:36,140
+objective of the pressure test was to verify that
+
+359
+00:38:37,100 --> 00:38:42,020
+pressure did not deviate from 4.0 Mega Pascal by
+
+360
+00:38:42,020 --> 00:38:45,680
+more than one percent أحد أهداف التجربة اللي
+
+361
+00:38:45,680 --> 00:38:54,080
+صارت أن نتأكد نتحقق أن الضغط ما يبتعد عن أربعة
+
+362
+00:38:54,080 --> 00:38:58,240
+Mega Pascal بقيمة واحد في المئة يعني أنا مسموح لي
+
+363
+00:38:58,240 --> 00:39:03,280
+يكون الضغط الضغط مسموح لي ال P allowed allowed
+
+364
+00:39:03,280 --> 00:39:05,860
+أربعة
+
+365
+00:39:07,310 --> 00:39:13,530
+plus or minus واحد في المئة من الأربعة صح يعني
+
+366
+00:39:13,530 --> 00:39:21,030
+هتكون أربعة plus or minus 0.04 يعني ..
+
+367
+00:39:21,030 --> 00:39:29,890
+يعني اللي هيكون ال pressure بين 3.96
+
+368
+00:39:29,890 --> 00:39:37,980
+لـ 4.04 إحنا خلينا نطلع على البيانات
+
+369
+00:39:37,980 --> 00:39:42,920
+أول شيء نطلع
+
+370
+00:39:42,920 --> 00:39:50,140
+على القراءات يعني
+
+371
+00:39:50,140 --> 00:39:53,120
+هذه أكبر من 3.96 مظبوط؟ في ال range
+
+372
+00:39:53,120 --> 00:39:59,660
+كله في ال range في ال range فمعظم القراءات يعني
+
+373
+00:39:59,660 --> 00:40:04,490
+هذه جاية برا ال range تقريباً بس أنا .. أنا .. أنا
+
+374
+00:40:04,490 --> 00:40:09,250
+ما بطلعش .. ما بطلعش بطلع ال average أنا بطلع ال
+
+375
+00:40:09,250 --> 00:40:15,450
+average و درجة الثقة اللي أنا حاططها in
+
+376
+00:40:15,450 --> 00:40:17,930
+terms of standard deviation أنا ال standard
+
+377
+00:40:17,930 --> 00:40:25,230
+deviation دي كم طلع ال Sx 0.014 ال Sx
+
+378
+00:40:25,230 --> 00:40:28,290
+بيساوي
+
+379
+00:40:28,290 --> 00:40:33,630
+0.014 .. 0.014 والـ allowed
+
+380
+00:40:33,630 --> 00:40:42,090
+deviation ال allowed deviation ال
+
+381
+00:40:42,090 --> 00:40:47,150
+allowed deviation
+
+382
+00:40:47,150 --> 00:40:52,210
+اللي
+
+383
+00:40:52,210 --> 00:41:02,070
+هو 0.04 طيب ال 0.04
+
+384
+00:41:05,990 --> 00:41:14,370
+على 0.014 كم بيساوي
+
+385
+00:41:14,370 --> 00:41:17,770
+لاحظ
+
+386
+00:41:17,770 --> 00:41:23,890
+شوية من الأشياء
+
+387
+00:41:23,890 --> 00:41:28,810
+تطلع
+
+388
+00:41:28,810 --> 00:41:33,210
+لي هي 2.86
+
+389
+00:41:36,720 --> 00:41:40,100
+بالنسبة لـ standard deviation الـ 0.014
+
+390
+00:41:40,100 --> 00:41:45,840
+ميجا باسكال بيساوي 2.86 احنا حاولنا أن
+
+391
+00:41:45,840 --> 00:41:54,180
+نحصلها بيكون 2.86 الآن لما نجي على ال
+
+392
+00:41:54,180 --> 00:41:54,740
+distribution
+
+393
+00:42:01,620 --> 00:42:10,240
+عندي 2.86 و 2 minus 2.
+
+394
+00:42:10,240 --> 00:42:11,860
+86 نروح على ال table
+
+395
+00:42:21,900 --> 00:42:30,280
+2.86 يعني كم الرابع 2.
+
+396
+00:42:30,280 --> 00:42:34,160
+86
+
+397
+00:42:34,160 --> 00:42:40,620
+يعني نص المساحة كانت بيساوي 4.
+
+398
+00:42:40,620 --> 00:42:46,160
+997 يعني ال probability ال
+
+399
+00:42:46,160 --> 00:42:47,200
+probability انه
+
+400
+00:42:52,040 --> 00:42:59,620
+ال Z تكون أكبر أو يساوي أكبر أو يساوي صفر و
+
+401
+00:42:59,620 --> 00:43:04,040
+أصغر أو يساوي 2.86 بس هو 0.
+
+402
+00:43:04,040 --> 00:43:11,440
+497 9 طيب ال probability أن ال
+
+403
+00:43:11,440 --> 00:43:14,540
+range  ال plus و ال minus ال probability أن
+
+404
+00:43:14,540 --> 00:43:17,740
+ال Z تكون
+
+405
+00:43:19,320 --> 00:43:25,340
+أكبر أو يساوي minus 2.86 سيجما و أصغر من 2.86
+
+406
+00:43:25,340 --> 00:43:40,400
+سيكون 2 في هذا 2 9 18 2 7 15 2 9 19 2 4 9 مظبوط
+
+407
+00:43:40,400 --> 00:43:47,580
+يعني هتكون 99.85%
+
+408
+00:43:51,590 --> 00:44:00,110
+
+445
+00:47:16,740 --> 00:47:20,240
+.. على population؟
+
+446
+00:47:25,610 --> 00:47:33,510
+هو المفروض يكون .. المفروض أن يكون عنده أجهزة
+
+447
+00:47:33,510 --> 00:47:37,450
+قياسية، دي، و بأخذ قراءات على مدار الساعة، يعني كل
+
+448
+00:47:37,450 --> 00:47:41,490
+ثانية بأخذ قراءات، ويكون عنده data logging يعني
+
+449
+00:47:41,490 --> 00:47:45,190
+فيه يعني تخزين للبيانات، فممكن يكون عنده على المدى
+
+450
+00:47:45,190 --> 00:47:50,970
+البعيد، اللي هي ايش population، لكن هو قادر يركب
+
+451
+00:47:50,970 --> 00:47:55,750
+المولد، المخاري، ويفحصه. في البداية ما عنده population
+
+452
+00:47:55,750 --> 00:48:05,970
+صح، عنده sample إذا
+
+453
+00:48:05,970 --> 00:48:11,830
+أخذنا الفحص، الضغط، عدناه كمان مرة، يعني عملنا كمان
+
+454
+00:48:11,830 --> 00:48:19,440
+تجربة مثلاً بيوم ثاني، وأخذنا مئة قراءة جديدة. هل
+
+455
+00:48:19,440 --> 00:48:22,080
+هيطلعوا نفس الـ average value ونفس الـ standard
+
+456
+00:48:22,080 --> 00:48:28,260
+deviation؟ لأ، مش هيطلعوا نفس الـ average value ولا
+
+457
+00:48:28,260 --> 00:48:30,340
+نفس الـ standard deviation
+
+458
+00:48:35,910 --> 00:48:40,590
+العديد من المرات، مثلاً عندنا مثلاً عشرين، ثلاثين مرة
+
+459
+00:48:40,590 --> 00:48:45,690
+بيصير عندي distribution للـ mean values و
+
+460
+00:48:45,690 --> 00:48:49,450
+distribution للـ standard deviation يعني مثلاً
+
+461
+00:48:49,450 --> 00:48:54,210
+distribution للـ mean values والـ distribution للـ
+
+462
+00:48:54,210 --> 00:48:56,530
+standard deviations لكل العينات، يعني العينة الأولى
+
+463
+00:48:56,530 --> 00:48:59,290
+لو فيها مئة، العينة الثانية مئة، العينة الثالثة مئة،
+
+464
+00:48:59,290 --> 00:49:03,610
+العينة رقم خمسين مئة، كل واحدة لها mean value، كل
+
+465
+00:49:03,610 --> 00:49:05,610
+واحدة لها standard deviation، معناته أحصل على الـ
+
+466
+00:49:05,610 --> 00:49:11,570
+distribution للـ means والـ standard deviations
+
+467
+00:49:11,570 --> 00:49:21,110
+طبعاً
+
+468
+00:49:23,020 --> 00:49:29,540
+العينات، الـ means، عينات القيم المتوسطة، بتورجينا أن
+
+469
+00:49:29,540 --> 00:49:35,200
+في تشتت حول الـ central value، القيم المتوسطة لكل
+
+470
+00:49:35,200 --> 00:49:42,020
+الـ mean values.  ماذا يعني إذا if n for each
+
+471
+00:49:42,020 --> 00:49:48,800
+sample is very large، إذا كان very large، يعني عدد
+
+472
+00:49:48,800 --> 00:49:52,080
+القراءات لكل تجارب أكثر من ثلاثين،
+
+473
+00:49:55,360 --> 00:50:02,100
+هيكون distribution of mean values is Gaussian that
+
+474
+00:50:02,100 --> 00:50:07,200
+has a standard deviation sigma
+
+475
+00:50:07,200 --> 00:50:12,800
+x bar بيساوي
+
+476
+00:50:12,800 --> 00:50:18,300
+الـ sigma على الجذر التربيعي للـ N
+
+477
+00:50:22,820 --> 00:50:25,740
+كل sample كان عنده n، والـ n كان very large، يعني
+
+478
+00:50:25,740 --> 00:50:29,320
+أكبر من ثلاثين، عندي distribution of mean values
+
+479
+00:50:29,320 --> 00:50:31,600
+is Gaussian that has a standard deviation of sigma
+
+480
+00:50:31,600 --> 00:50:40,360
+x bar على بيساوي sigma على جذر التربيعي يعني
+
+481
+00:50:40,360 --> 00:50:45,240
+الـ sigma x bar هي
+
+482
+00:50:45,240 --> 00:50:51,620
+الـ standard deviation، sigma x bar هي الـ standard
+
+483
+00:50:51,620 --> 00:50:52,160
+deviation
+
+484
+00:50:54,630 --> 00:50:58,210
+لمجموعة الـ means، مجموعة المتوسطات، احنا حكينا
+
+485
+00:50:58,210 --> 00:51:02,890
+أننا كنا نجرّب أصلاً خمسين مرة، فكل مرة كنا نحصل
+
+486
+00:51:02,890 --> 00:51:06,470
+على الـ mean value، هيكون دي X bar واحد، X bar اتنين، X
+
+487
+00:51:06,470 --> 00:51:11,550
+bar ثلاثة، X bar خمسة وهكذا، هدول حسبت لهم الـ mean و
+
+488
+00:51:11,550 --> 00:51:14,110
+حسبت الـ standard deviation، يعني هذه الـ sigma X bar
+
+489
+00:51:14,110 --> 00:51:15,630
+هي الـ standard deviation
+
+490
+00:51:26,720 --> 00:51:32,060
+الآن، الـ sigma هي
+
+491
+00:51:32,060 --> 00:51:37,140
+الـ standard deviation للـ population، طبعاً شو مطلوب
+
+492
+00:51:37,140 --> 00:51:43,800
+أن نشتق العلاقة هذه، sigma x bar، بيساوي sigma على جزء
+
+493
+00:51:43,800 --> 00:51:45,380
+التربيعي للـ n
+
+494
+00:51:49,910 --> 00:51:57,790
+خليني أعرف الـ z، الـ z اللي هي x bar ناقص mu على
+
+495
+00:51:57,790 --> 00:52:02,990
+سيجما x bar، بس x bar اللي هي سيجما x، اللي هي سيجما
+
+496
+00:52:02,990 --> 00:52:09,630
+على جذر تربيعي للـ n with
+
+497
+00:52:09,630 --> 00:52:17,190
+c percent confidence للـ true mean value اللي هي الـ
+
+498
+00:52:17,190 --> 00:52:17,790
+mean value للـ
+
+499
+00:52:20,660 --> 00:52:24,700
+للـ population، الـ true mean value للـ population
+
+500
+00:52:24,700 --> 00:52:30,860
+with
+
+501
+00:52:30,860 --> 00:52:40,760
+c confidence، الـ confidence إيش معناه؟ بس
+
+502
+00:52:40,760 --> 00:52:47,970
+حاجة، دي، صح؟  ليه؟ احتمالية تكون الـ values بين هذا
+
+503
+00:52:47,970 --> 00:52:51,970
+القيمة وهذا القيمة، هذه درجة ثقة with c percentage
+
+504
+00:52:51,970 --> 00:52:57,130
+confidence، الـ true mean value للـ population، الـ mu
+
+505
+00:52:57,130 --> 00:53:05,470
+هتكون أكبر من أو تساوي X bar، X bar إيش هذا؟ X bar الـ
+
+506
+00:53:05,470 --> 00:53:13,210
+mean لإيش؟ للـ sample، للـ sample مش لكل الـ
+
+507
+00:53:13,210 --> 00:53:17,210
+samples،  أنا أنتجت واحدة، أنا مثلاً عددهم
+
+508
+00:53:17,210 --> 00:53:25,810
+أربعين،  كأن هذا الـ X bar  الاسم بالواحدة ناقص Z C
+
+509
+00:53:25,810 --> 00:53:35,690
+على اثنين، ليه هذا؟ هذا Z C على اثنين في الـ sigma
+
+510
+00:53:35,690 --> 00:53:42,070
+جذر التربيعي للـ N، وأصغر من X bar زائد Z C على
+
+511
+00:53:42,070 --> 00:53:47,300
+اثنين في الـ sigma جذر التربيعي. من خلال معرفتي
+
+512
+00:53:47,300 --> 00:53:57,580
+لخصائص الـ sample، بإمكاني أتوقع القيمة الوسطى للـ
+
+513
+00:53:57,580 --> 00:54:03,620
+population، من خلال معرفتي لخصائص تاعة الـ sample
+
+514
+00:54:03,620 --> 00:54:09,620
+بإمكاني أتوقع القيمة الوسطى للـ population
+
+515
+00:54:16,520 --> 00:54:22,360
+طبعاً، for large samples، هأحط الـ sigma، سأعبّر عنها
+
+516
+00:54:22,360 --> 00:54:26,520
+بإيش؟ Sx، احنا حكيناها في الـ sample، أحط بدل sigma
+
+517
+00:54:26,520 --> 00:54:32,960
+Sx، فهيكون عندي الـ mu جاي في الـ range بين X bar بين
+
+518
+00:54:32,960 --> 00:54:38,140
+ZC على 2 في SX على جذر N، وبين X bar زائد ZC على 2
+
+519
+00:54:38,140 --> 00:54:47,920
+في SX على جذر N، والـ Sx bar بيساوي x Sx على جذر ا
+
+520
+00:54:47,920 --> 00:54:57,960
+يعني هذه هذه إيش كلها؟ Sx bar، طيب
+
+521
+00:54:57,960 --> 00:55:04,680
+نشوف مثال، determine
+
+522
+00:55:04,680 --> 00:55:07,380
+a 99 percent confidence interval
+
+523
+00:55:09,890 --> 00:55:12,390
+for the mean pressure calculated in the previous
+
+524
+00:55:12,390 --> 00:55:17,430
+example، أو جد تسعة وتسعون في المئة confidence
+
+525
+00:55:17,430 --> 00:55:21,830
+interval للـ mean pressure اللي حسبناه في المثال
+
+526
+00:55:21,830 --> 00:55:30,950
+السابق، الـ C كم؟  أو المساحة
+
+527
+00:55:30,950 --> 00:55:38,870
+هذه
+
+528
+00:55:38,870 --> 00:55:39,350
+كلها
+
+529
+00:55:43,630 --> 00:55:53,310
+الـ Area بيساوي point 9 9، صح؟ هذه الـ Z، Zero Z
+
+530
+00:55:53,310 --> 00:56:03,790
+C على 2، هذه الـ Z، ناقص Z C على 2، صح؟ معناته أروح
+
+531
+00:56:03,790 --> 00:56:08,490
+على الجدول، أروح
+
+532
+00:56:08,490 --> 00:56:09,090
+على الجدول
+
+533
+00:56:16,100 --> 00:56:21,800
+الـ z اللي هو نصف المساحة، هتكون كم؟ point أربعة تسعة
+
+534
+00:56:21,800 --> 00:56:43,360
+خمسة، point أربعة، point أربعة تسعة، لحظة
+
+535
+00:56:43,360 --> 00:56:50,210
+لحظة، يعني جاي بين هذه وهذه، صح؟ جاي في المنطقة هذه
+
+536
+00:56:50,210 --> 00:57:00,470
+صح، point أربعة تسعة خمسة جاي
+
+537
+00:57:00,470 --> 00:57:07,710
+هنا، هذه
+
+538
+00:57:07,710 --> 00:57:17,000
+التسعة، ثمانية، سبعة، صح؟ يعني جاي عند اثنين فاصلة خمسة
+
+539
+00:57:17,000 --> 00:57:27,360
+سبعة، كانت كم؟ أربعة تسعة أربعة
+
+540
+00:57:27,360 --> 00:57:33,660
+تسعة، فعند اثنين فاصلة خمسة
+
+541
+00:57:33,660 --> 00:57:44,600
+ثمانية،  أربعة تسعة خمسة واحد، فأنا بدّي عند point
+
+542
+00:57:44,600 --> 00:57:52,520
+4 9 5، لأ
+
+543
+00:57:52,520 --> 00:57:57,020
+واضح أن هذه 49 و51، جاية في النص بالضبط، يعني
+
+544
+00:57:57,020 --> 00:58:00,480
+محظوظين أن احنا جاية في إيش؟ في النص بالضبط، هذه
+
+545
+00:58:00,480 --> 00:58:05,950
+خمسين، لأن صح مظبوط، يعني هذه تسعة وأربعين وواحد و
+
+546
+00:58:05,950 --> 00:58:08,130
+خمسين، دي، أفرموس، معناته هذه هتكون القراءة هي
+
+547
+00:58:08,130 --> 00:58:19,390
+هتكون اثنين فاصلة خمسة سبعة خمسة، point اثنين فاصلة خمسة
+
+548
+00:58:19,390 --> 00:58:25,810
+سبعة خمسة، معناته Z C على اثنين، اثنين فاصلة خمسة
+
+549
+00:58:25,810 --> 00:58:27,010
+سبعة خمسة
+
+550
+00:58:33,490 --> 00:58:40,250
+اللي هي هي هذه Z، اللي هي عند المساحة point أربع
+
+551
+00:58:40,250 --> 00:58:46,070
+تسعة خمسة، طلعت اثنين فاصلة خمسة سبعة خمسة، المعنى هو
+
+552
+00:58:46,070 --> 00:58:50,950
+الـ Mu بتاعة الـ pressure هتكون تتراوح بين الـ P
+
+553
+00:58:50,950 --> 00:58:53,470
+average، الـ P average احنا حسبناها من المثال السابق
+
+554
+00:58:53,470 --> 00:59:00,550
+الـ P average، إيه أكثر؟ طلعت معنا أربعة
+
+555
+00:59:00,550 --> 00:59:00,950
+point
+
+556
+00:59:04,450 --> 00:59:10,790
+zero zero zero ثمانية ميجا
+
+557
+00:59:10,790 --> 00:59:14,350
+باسكال، و
+
+558
+00:59:14,350 --> 00:59:20,530
+الـ standard deviation، الـ Sx كم كان؟ zero point
+
+559
+00:59:20,530 --> 00:59:26,810
+zero واحد أربعة ميجا باسكال، المعنى هو الـ value  اللي هو
+
+560
+00:59:26,810 --> 00:59:30,850
+الـ population بتاع كل قراءة الضغط، متوقع يكون الـ mu
+
+561
+00:59:33,030 --> 00:59:37,850
+هيكون أكبر من
+
+562
+00:59:37,850 --> 00:59:47,310
+P bar ناقص Z اللي هي سعة اثنين، اللي هي point أربعة
+
+563
+00:59:47,310 --> 00:59:59,250
+تسعة خمسة في SX على جذر التربيعي للـ n، وأصغر
+
+564
+00:59:59,250 --> 01:00:09,480
+من P bar زائد زد point أربعة تسعة خمسة في Sx جذر
+
+565
+01:00:09,480 --> 01:00:16,320
+التربيعي للـ n، يعني هيكون P bar اللي هو أربعة point
+
+566
+01:00:16,320 --> 01:00:20,360
+zero zero
+
+567
+01:00:20,360 --> 01:00:28,700
+ثمانية ناقص اثنين point كم؟ طلعت أنا خمسة سبعة
+
+568
+01:00:28,700 --> 01:00:34,310
+خمسة، خمسة سبعة خمسة، على جذر التربيعي للمئة، على
+
+569
+01:00:34,310 --> 01:00:41,310
+عشرة، صح؟
+
+570
+01:00:41,310 --> 01:00:46,030
+لأ، أربعة point zero zero ثمانية ناقص اثنين فاصلة خمسة
+
+571
+01:00:46,030 --> 01:00:51,670
+سبعة خمسة على عشرة، زائد زائد
+
+572
+01:00:51,670 --> 01:00:56,430
+في الـ SX
+
+573
+01:00:56,430 --> 01:00:57,410
+اللي هي كم؟
+
+574
+01:01:00,000 --> 01:01:08,860
+في point zero أربعة عشر ثاني، في point zero أربعة عشر يعني
+
+575
+01:01:08,860 --> 01:01:12,900
+هتكون لما
+
+576
+01:01:12,900 --> 01:01:17,440
+تحسبوها يعني
+
+577
+01:01:17,440 --> 01:01:26,520
+بمعنى، بمعنى أن الـ new P هتكون تساوي P bar زائد أو
+
+578
+01:01:26,520 --> 01:01:36,630
+ناقص زد point أربعة تسعة خمسة في SX على N، يعني هتكون
+
+579
+01:01:36,630 --> 01:01:45,050
+أربعة point zero zero ثمانية زائد أو ناقص اثنين فاصلة خمسة
+
+580
+01:01:45,050 --> 01:01:53,090
+سبعة خمسة في point zero واحد أربعة، عشر، يعني أكثر هتطلع
+
+581
+01:01:53,090 --> 01:02:03,230
+هذه حسابها، هو أربعة point zero zero ثمانية زائد أو ناقص point
+
+582
+01:02:03,230 --> 01:02:10,430
+zero zero أربعة
+
+583
+01:02:10,430 --> 01:02:17,570
+هيك الصح لأنه
+
+584
+01:02:17,570 --> 01:02:25,290
+مش هتقدر تتخطى الـ resolution بتاع الجهاز
+
+585
+01:02:28,730 --> 01:02:34,070
+فأنا أصبح أعرف أن الـ range تاع الـ mean أو المتوقع
+
+586
+01:02:34,070 --> 01:02:39,550
+range تاع الـ mean يكون بين يعني هيكون لو ضفت لو
+
+587
+01:02:39,550 --> 01:02:51,430
+طرحت، هيكون بين أربعة point zero أربعة لحد أربعة point أربعة
+
+588
+01:02:51,430 --> 01:02:54,110
+point zero
+
+589
+01:02:59,260 --> 01:03:05,140
+واحد اثنين، صح؟ الـ
+
+590
+01:03:05,140 --> 01:03:13,480
+mean value، الـ mu هو
+
+591
+01:03:13,480 --> 01:03:17,680
+في البداية حكى لي أن الـ pressure مش لازم يبعد عن
+
+592
+01:03:17,680 --> 01:03:23,140
+أكثر من واحد في المئة، يعني point zero four، معناته
+
+593
+01:03:23,140 --> 01:03:31,540
+النتيجة بتحكي لي أن الأمور تمام، صح؟ الأمور تمام
+
+594
+01:03:31,540 --> 01:03:36,280
+معناته
+
+595
+01:03:36,280 --> 01:03:42,980
+أنا ممكن هذه أبرمجها، أبرمجها مثلاً عندي في المحطة
+
+596
+01:03:42,980 --> 01:03:49,060
+أو عندي  ... on inlet pressure بتاع المولد مثلاً، كل
+
+597
+01:03:49,060 --> 01:03:54,920
+أكم أو كل ساعة مثلاً، ممكن يجي يحكي لي في مشكلة
+
+598
+01:03:57,580 --> 01:04:02,420
+الـ pressure صار out of range، بناءً على بيكون هو
+
+599
+01:04:02,420 --> 01:04:07,520
+يُعمل حسابات إحصائية، يكيل out of range، فإنتَ فيه
+
+600
+01:04:07,520 --> 01:04:17,140
+مشكلة، أو بيكون في نظام تغذية راجع، بحيث لو في مشكلة
+
+601
+01:04:17,140 --> 01:04:24,620
+أنه يعمل عملية موازنة، موازنة، ضبط الضغط، ضغط الغاز
+
+602
+01:04:24,620 --> 01:04:26,100
+البخار
+
+603
+01:04:28,490 --> 01:04:37,170
+طبعاً، عشان تتحكم بضغط البخار، في كذا parameter، بس
+
+604
+01:04:37,170 --> 01:04:41,130
+في النهاية، العلم بالقياسات، مش مجرد أنك تأخذ قراءة
+
+605
+01:04:41,130 --> 01:04:48,030
+بس، أنك تأخذ قراءات، تُقيمها، تُحلل البيانات، بعدين
+
+606
+01:04:48,030 --> 01:04:52,930
+تعرضها، وتستخرج منها، بناءً على استخراج البيانات، تتخذ
+
+607
+01:04:52,930 --> 01:04:59,320
+قرارات، هي الهدف من قراءة القياسات. اليوم يكون خلصت
+
+608
+01:04:59,320 --> 01:05:00,340
+لحد هنا،  أشكركم، وعافية.
+
diff --git a/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/EatQYMBMLRg_postprocess.srt b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/EatQYMBMLRg_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..49523b3987890a814e699a7d3a2fbef3bd2dadf8
--- /dev/null
+++ b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/EatQYMBMLRg_postprocess.srt
@@ -0,0 +1,2432 @@
+1
+00:00:05,180 --> 00:00:08,440
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:08,440 --> 00:00:13,620
+وبركاته اليوم هنكمل في مادة القياسات شبطر تلاتة
+
+3
+00:00:13,620 --> 00:00:19,160
+تقييم وعرض البيانات المحاضرة اللي فاتت حكينا عن ال
+
+4
+00:00:19,160 --> 00:00:24,360
+property density function اللي هو Gaussian PDF F
+
+5
+00:00:24,360 --> 00:00:27,180
+of X يساوة واحدة على سجمة جزيرة تربية على اتنين Pi
+
+6
+00:00:27,180 --> 00:00:30,560
+Exponential minus X minus U لكل تربية على اتنين
+
+7
+00:00:30,560 --> 00:00:37,680
+سجمة تربيةX هي قيمة قراءة معينة، Mu هي القيمة
+
+8
+00:00:37,680 --> 00:00:42,500
+المتوسطة لكل ال population، و Sigma هي الانحراف
+
+9
+00:00:42,500 --> 00:00:44,200
+المياري لكل ال population
+
+10
+00:00:48,010 --> 00:00:53,190
+و ال average لعدد من القراءات بتساوي مجموعة على
+
+11
+00:00:53,190 --> 00:00:59,910
+عددها و الانحراف لأي قراعة عن القيمة المتوسطة هي
+
+12
+00:00:59,910 --> 00:01:05,050
+بتساوي القراعة اللي هي X minus القيمة المتوسطة
+
+13
+00:01:12,040 --> 00:01:16,480
+الـ main standard deviation للpopulation بستوى جزر
+
+14
+00:01:16,480 --> 00:01:21,160
+التربيعي لل summation لل deviations تربيع على n
+
+15
+00:01:21,160 --> 00:01:25,780
+لحد
+
+16
+00:01:25,780 --> 00:01:30,960
+هنا وصلنا الان للتثيير عشان نخل ال product density
+
+17
+00:01:30,960 --> 00:01:36,860
+function standardization هو يكون symmetric حوال ال
+
+18
+00:01:36,860 --> 00:01:39,420
+y axis احنا كان عندنا
+
+19
+00:01:43,070 --> 00:01:48,010
+أي دنسته function هي
+
+20
+00:01:48,010 --> 00:01:52,950
+ال main value هذا
+
+21
+00:01:52,950 --> 00:02:01,390
+x هذا f of x لو
+
+22
+00:02:01,390 --> 00:02:02,770
+أخدنا أي قراءة x
+
+23
+00:02:13,090 --> 00:02:23,910
+و أعرفنا z بصورة x minus mu على sigma هذه الشيء
+
+24
+00:02:23,910 --> 00:02:27,450
+هتكون
+
+25
+00:02:27,450 --> 00:02:37,030
+z ل sigma معناته زي .. و بعرف ال new variable جديد
+
+26
+00:02:37,030 --> 00:02:41,650
+هز
+
+27
+00:02:41,650 --> 00:02:42,270
+ال new variable
+
+28
+00:02:45,880 --> 00:02:56,720
+مش زيك زد و اف زد يعني انا عمل shift shift لكل ال
+
+29
+00:02:56,720 --> 00:03:03,940
+curve بحيث يصير symmetrical حوالين المحور الرأسي
+
+30
+00:03:03,940 --> 00:03:07,580
+فبصير
+
+31
+00:03:07,580 --> 00:03:09,420
+المساحة من minus infinity
+
+32
+00:03:13,000 --> 00:03:19,440
+الـ area من minus infinity to infinity تحت ال
+
+33
+00:03:19,440 --> 00:03:21,420
+probability of density of function بقاشر الساوية
+
+34
+00:03:21,420 --> 00:03:28,600
+واحد لأنه بتغطي كل احتمالات مظلوط لأن المساحة من
+
+35
+00:03:28,600 --> 00:03:32,420
+minus infinity to infinity بتغطي كل احتمالات لأنها
+
+36
+00:03:32,420 --> 00:03:38,260
+تكون مساحة مية في المية واحد فهستير
+
+37
+00:03:38,260 --> 00:03:39,520
+عنده يعني
+
+38
+00:03:42,390 --> 00:03:49,250
+أنا كان عندي f of x بالساوية
+
+39
+00:03:49,250 --> 00:04:01,110
+واحد على سجمة دزر تربيع لاتنين by exponential ل
+
+40
+00:04:01,110 --> 00:04:09,150
+minus x minus mu لكل تربيع على اتنين سجمة تربيع
+
+41
+00:04:09,150 --> 00:04:17,250
+هيصير f of zزي واحد على سيجما جزر التربيع على
+
+42
+00:04:17,250 --> 00:04:22,590
+اتنين by exponential لأ لان عندي انا x minus mu
+
+43
+00:04:22,590 --> 00:04:28,370
+على سيجما اللي هي z هتكون minus يعني هدول هذا
+
+44
+00:04:28,370 --> 00:04:36,130
+هيكون z تربيع ل minus z تربيع على اتنين
+
+45
+00:04:53,640 --> 00:04:57,500
+الان صار لطوارة الـ density function سيميترك
+
+46
+00:04:57,500 --> 00:05:05,420
+حوالين المحور الرأسي اللى هو F of Z هذا F of Z
+
+47
+00:05:05,420 --> 00:05:10,920
+اللى لو أخدت plus sigma او minus sigma على اليمين
+
+48
+00:05:10,920 --> 00:05:16,960
+هذا plus sigma هذا plus two sigma plus ثلاثة sigma
+
+49
+00:05:21,470 --> 00:05:24,090
+من minus sigma ل plus sigma اكتر بتعطينا
+
+50
+00:05:24,090 --> 00:05:30,950
+confidence او درجة تأكون 68 اللي هو plus or minus
+
+51
+00:05:30,950 --> 00:05:37,150
+2 sigma 95% plus or minus 3 sigma 99.7%
+
+52
+00:05:41,530 --> 00:05:47,550
+الان ال area ال area اللي انت شايفينه مضلل بالأسود
+
+53
+00:05:47,550 --> 00:05:54,990
+تمثل احتمالية ان ال z تكون بين صفر و some value z
+
+54
+00:05:54,990 --> 00:06:01,430
+احتمالية ان ال z تكون بين zero و some value z طبعا
+
+55
+00:06:01,430 --> 00:06:05,130
+هذا ال PDF بسميه z distribution
+
+56
+00:06:13,800 --> 00:06:18,900
+الـ z distribution له table و السبب في الـ
+
+57
+00:06:18,900 --> 00:06:22,760
+tabulation انه
+
+58
+00:06:22,760 --> 00:06:28,440
+عشان اجد مسافة بدي اعمل integral صح؟ بدي اعمل
+
+59
+00:06:28,440 --> 00:06:31,920
+integral يعني انا هندحك اللي probability انه z
+
+60
+00:06:31,920 --> 00:06:40,420
+تكون من صفر ل z هتكون تكامل f of z dz يعني هتكون
+
+61
+00:06:40,420 --> 00:06:46,450
+تكامل واحد على سجمةتجزر التدبيع ل 10 باي اكس فرانش
+
+62
+00:06:46,450 --> 00:06:50,130
+همازي التدبيع على 2 ديزل طبعا هذا تكامل مانعملش
+
+63
+00:06:50,130 --> 00:06:55,550
+بالطرق اللي هو انك تجيب حل exact بطرق التحليل
+
+64
+00:06:55,550 --> 00:06:59,930
+العددي بتجيب يعني حل تقريبي باستخدام طرق التحليل
+
+65
+00:06:59,930 --> 00:07:05,690
+العددي عشانك هنا عامل population zero بعد من سفر
+
+66
+00:07:05,690 --> 00:07:08,830
+سفر point one point two point three point four
+
+67
+00:07:08,830 --> 00:07:14,480
+واحد كذا طبعا هذه جزء من التابلفإذا كانت z مثلا
+
+68
+00:07:14,480 --> 00:07:21,640
+point أربعة
+
+69
+00:07:21,640 --> 00:07:25,940
+خمسة ال
+
+70
+00:07:25,940 --> 00:07:32,300
+z point أربعة خمسة لأن بتطلع أن عندي point أربعة
+
+71
+00:07:32,300 --> 00:07:36,940
+وعندي هنا عشان أضيف الكاسر التاني هتيجي هنا point
+
+72
+00:07:36,940 --> 00:07:42,210
+zero خمسة فهتكون إيش القيمة اللي هي هذهبونت واحد
+
+73
+00:07:42,210 --> 00:07:44,710
+سبعة تلات ستة ..بونت واحد سبعة تلات ستة ..بونت
+
+74
+00:07:44,710 --> 00:07:45,550
+واحد سبعة تلات ستة ..بونت واحد سبعة تلات ستة
+
+75
+00:07:45,550 --> 00:07:48,250
+..بونت واحد سبعة تلات ستة ..بونت واحد سبعة تلات
+
+76
+00:07:48,250 --> 00:07:48,910
+ستة ..بونت واحد سبعة تلات ستة ..بونت واحد سبعة
+
+77
+00:07:48,910 --> 00:07:50,310
+تلات ستة ..بونت واحد سبعة تلات ستة ..بونت واحد
+
+78
+00:07:50,310 --> 00:07:54,550
+سبعة تلات ستة ..بونت واحد سبعة تلات ستة ..بونت
+
+79
+00:07:54,550 --> 00:07:59,390
+واحد سبعة تلات ستة ..بونت واحد سبعة تلات ستة
+
+80
+00:07:59,390 --> 00:08:09,070
+..بونت واحد سبعة تلات ستة ..بونت واحد سبعة تلات
+
+81
+00:08:09,070 --> 00:08:18,800
+ستةأني هتسطر همشي سطر التالت همشي أفقي لحد هتكون
+
+82
+00:08:18,800 --> 00:08:23,300
+point واحد سفر ستة خمسة ال point واحد زيرو ستة
+
+83
+00:08:23,300 --> 00:08:29,700
+أربعة هي المساحة تحت ال ال F و Z بين صفر و point
+
+84
+00:08:29,700 --> 00:08:33,960
+اتنين سبعة point اتنين سبعة وهذا تبثل احتمالية ال
+
+85
+00:08:33,960 --> 00:08:40,510
+Zتكون واقع في ال range هذا الاحتمالية ان ال z تكون
+
+86
+00:08:40,510 --> 00:08:45,390
+بين صفر و point اتنين سبعة لو حكيت point تلاتة
+
+87
+00:08:45,390 --> 00:08:51,590
+تسعة صحيح
+
+88
+00:08:51,590 --> 00:08:56,610
+ايش اللي سويته انت طلعت على ال point تلاتة امشيت
+
+89
+00:08:56,610 --> 00:09:02,000
+افقيلحد ما وصلت للتسعة point تلاتة تسعة فبتعطيني
+
+90
+00:09:02,000 --> 00:09:04,620
+المساحة point واحد خمسة واحد فانتوا هذه احتمالية
+
+91
+00:09:04,620 --> 00:09:11,100
+ان ال z تكون بين صفر و point تلاتة تسعة طيب نشوف
+
+92
+00:09:11,100 --> 00:09:14,800
+example ال
+
+93
+00:09:14,800 --> 00:09:17,080
+example بيحكي what is the area
+
+94
+00:09:27,150 --> 00:09:41,950
+ماهي المنطقة تحت الكيروف ماهي الكيروف ز
+
+95
+00:09:41,950 --> 00:09:50,630
+بالساوية ماينوس وان بونت فور ثري وان بونت فور ثري
+
+96
+00:09:50,630 --> 00:09:54,190
+هنا دي ز هنا F of Z
+
+97
+00:09:58,270 --> 00:10:04,130
+بين minus 1.43 و 1.43 هتكون ال area هذه مضايق في
+
+98
+00:10:04,130 --> 00:10:09,990
+المساحة هذه صح لأن هو symmetric معناته
+
+99
+00:10:09,990 --> 00:10:19,450
+هروع على ال tables هروع على ال tables و
+
+100
+00:10:19,450 --> 00:10:20,230
+اطلع على ال z
+
+101
+00:10:25,520 --> 00:10:30,280
+one point four three هاي one point four three وين
+
+102
+00:10:30,280 --> 00:10:36,400
+هيكون عنده اربعة اتنين تلاتة ستة اربعة اتنين تلاتة
+
+103
+00:10:36,400 --> 00:10:43,720
+ستة معناته ال area هتكون او
+
+104
+00:10:43,720 --> 00:10:50,820
+بدي احكي ال area هتكون اتنين في اكم
+
+105
+00:10:55,050 --> 00:11:03,330
+في bond اربعة اتنين؟ اربعة اتنين تلاتة ستة يعني
+
+106
+00:11:03,330 --> 00:11:14,490
+هتكون سبعة اتنين اربعة تمانية صح؟
+
+107
+00:11:14,490 --> 00:11:18,870
+طيب ايش ال significance؟ ايش معناته؟
+
+108
+00:11:23,660 --> 00:11:30,580
+يعني هتحتمال probability انه z بتكون اكبر او
+
+109
+00:11:30,580 --> 00:11:36,020
+يستاوي minus one point اربعة تلاتة و اصغر جاي فى
+
+110
+00:11:36,020 --> 00:11:41,600
+ال range لواحد point اربعة تلاتة بتساوي point
+
+111
+00:11:41,600 --> 00:11:48,160
+تمانية اربعة سبعة اتنين يعني as a percentage هتكون
+
+112
+00:11:48,160 --> 00:11:53,100
+اربعة و تمانين point سبعة اتنين في المية
+
+113
+00:12:05,760 --> 00:12:21,520
+السؤال كان example تاني what range
+
+114
+00:12:21,520 --> 00:12:24,640
+of eggs will contain ninety percent of the data
+
+115
+00:12:24,640 --> 00:12:33,460
+ايش ال range اللي هيخلق قيم X او Z تسعين
+
+116
+00:12:33,460 --> 00:12:39,190
+في المية يعني هم عطيني ال probabilityفزبوط فزبوط
+
+117
+00:12:39,190 --> 00:12:43,570
+ال report تسري في المية لان ال report يعني هي
+
+118
+00:12:43,570 --> 00:12:50,130
+الرسمة يعني المساحة هذه كلها هذه ال area تسعة و من
+
+119
+00:12:50,130 --> 00:12:58,170
+عشرة معنات نصها أكم هتكون ال a point five اللي
+
+120
+00:12:58,170 --> 00:13:04,420
+هتكون zero point أربعة خمسةهذه ال area point five
+
+121
+00:13:04,420 --> 00:13:09,040
+معناته هذه اللي هي ال mobility ان ز أكبر أو يساوي
+
+122
+00:13:09,040 --> 00:13:15,940
+صفر و أزرع يساوي point أربعة خمسة لأ مش عارفين
+
+123
+00:13:15,940 --> 00:13:24,240
+احنا ز أكبر
+
+124
+00:13:24,240 --> 00:13:31,730
+أو يساوي صفر و أزرع يساوي some value ز واحدواضغط
+
+125
+00:13:31,730 --> 00:13:36,210
+بالسواء point 4 و5 الان انا موجود ال z واحد انا
+
+126
+00:13:36,210 --> 00:13:39,310
+هروح
+
+127
+00:13:39,310 --> 00:13:44,410
+على ال table واطلع
+
+128
+00:13:44,410 --> 00:13:57,030
+على المساحة point 4 و5 point
+
+129
+00:13:57,030 --> 00:13:57,850
+4 و5
+
+130
+00:14:01,370 --> 00:14:11,970
+يعني أنا جاي في المنطقة هذي صح؟ مظبوط؟ بس خليني
+
+131
+00:14:11,970 --> 00:14:15,670
+أطلع يعني أنا جاي بين ال point O أربع و point O
+
+132
+00:14:15,670 --> 00:14:24,390
+خمسة صح؟ هاي عندى احنا جايين هنا يعني أنا بين
+
+133
+00:14:31,980 --> 00:14:38,000
+جاي هنا في المنطقة هذه
+
+134
+00:14:38,000 --> 00:14:43,460
+عندي هنا point 4 4 9 5 وهنا عندي point 4 5 0 5
+
+135
+00:14:43,460 --> 00:14:48,920
+واضح ال point ال point 4 5 جاي في المص بالظبط
+
+136
+00:14:48,920 --> 00:14:56,560
+المهم انت هتكون ال z ايش
+
+137
+00:14:56,560 --> 00:15:07,160
+هو السعر؟عندى هذه واحد point ستة لأ هى جاء بين ال
+
+138
+00:15:07,160 --> 00:15:12,980
+point او اربعة و ال point او خمسة يعنى point واحد
+
+139
+00:15:12,980 --> 00:15:23,810
+اتطلع يعنى هى هتكون point او ستةوفى عندى هنا جاء
+
+140
+00:15:23,810 --> 00:15:35,930
+بين 1.64 و 1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65
+
+141
+00:15:35,930 --> 00:15:38,130
+1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65
+
+142
+00:15:38,130 --> 00:15:38,210
+1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65
+
+143
+00:15:38,210 --> 00:15:38,270
+1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65
+
+144
+00:15:38,270 --> 00:15:38,290
+1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65
+
+145
+00:15:38,290 --> 00:15:45,990
+1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65 1.65
+
+146
+00:15:45,990 --> 00:16:09,330
+1.65 1.65 1-1.645 أصغر من 1.645 طيب
+
+147
+00:16:17,630 --> 00:16:20,470
+لو أنا السابق كنا .. كنا نحكي على theory based on
+
+148
+00:16:20,470 --> 00:16:25,490
+population، يعني كل population معروف عندي، لكن على
+
+149
+00:16:25,490 --> 00:16:31,050
+أرض الواقع ال population بيكونش متاحلي أنه أاخد كل
+
+150
+00:16:31,050 --> 00:16:34,590
+القراءات بتاعة ال population، لما نعمل دراسة ما
+
+151
+00:16:34,590 --> 00:16:37,890
+بيكون ال population مثلا زي ما أحكي أنا مرض السكر
+
+152
+00:16:37,890 --> 00:16:45,940
+في قطاع غزةمثلا عدد بنحكي مثلا خمسين ألف مثلا مش
+
+153
+00:16:45,940 --> 00:16:49,820
+مفتاحة كل البنات يعني أو الجامعة الصعبة فبعمل انا
+
+154
+00:16:49,820 --> 00:16:57,460
+دراسة مثلا على عينة ألف شخص خمس مية مية فالان شوف
+
+155
+00:16:57,460 --> 00:17:01,740
+ال theory based on كيف بيصير التغيرات عليهاطبعا
+
+156
+00:17:01,740 --> 00:17:06,100
+الهدف من theory based in sample انه استخدم القيم
+
+157
+00:17:06,100 --> 00:17:11,120
+الوسطى اللى بنحصل عليها من ال sample عشان اعمل
+
+158
+00:17:11,120 --> 00:17:17,420
+حساب او تقدير ل ال main القيمة الوسطىأو الانحراف
+
+159
+00:17:17,420 --> 00:17:21,600
+المياري لكل ال population يعني الهدف من استخدام ال
+
+160
+00:17:21,600 --> 00:17:27,140
+sample أن أحصل يعني أستخدم القيم المتوسطة اللي بصح
+
+161
+00:17:27,140 --> 00:17:32,840
+عليها من ال sample عشان أحسب اللي هي القيمة الوسطى
+
+162
+00:17:32,840 --> 00:17:36,240
+وال standard deviation لل population
+
+163
+00:17:40,040 --> 00:17:44,020
+أي عين اخدت انا عملت تجربة واخدت عدد من القراءات
+
+164
+00:17:44,020 --> 00:17:50,540
+عددها N عند القراءة X1, X2, X3 و X4 لحد XN المتوسط
+
+165
+00:17:50,540 --> 00:17:58,880
+طبعا مش يساوي مجموعة القراءات على عددهم الان
+
+166
+00:17:58,880 --> 00:18:06,040
+ال standard deviation طبعا انا في حالة ال
+
+167
+00:18:06,040 --> 00:18:06,480
+population
+
+168
+00:18:10,920 --> 00:18:20,320
+باستخدام القيمة الوسطى أيش ميو في حالة ال sample X
+
+169
+00:18:20,320 --> 00:18:25,560
+bar ب standard deviation في حالة ال population
+
+170
+00:18:25,560 --> 00:18:38,500
+سيجما في حالة ال sample SX يعني هنا population هنا
+
+171
+00:18:38,500 --> 00:18:39,700
+sample
+
+172
+00:18:43,270 --> 00:18:47,670
+الـ standard deviation في
+
+173
+00:18:47,670 --> 00:18:52,130
+حالة .. او نحكي ال deviation لكل كرة D I ايش
+
+174
+00:18:52,130 --> 00:19:02,850
+يستوى؟ X I minus X bar صح؟
+
+175
+00:19:02,850 --> 00:19:10,330
+ال standard deviation لل .. لل .. لل sample هكون
+
+176
+00:19:10,330 --> 00:19:18,390
+جزر التربية يعنيلـ summation لـ di تربيع I من واحد
+
+177
+00:19:18,390 --> 00:19:24,830
+ل N على N
+
+178
+00:19:24,830 --> 00:19:30,650
+minus واحد اذا حد عارف يعني في حالة ال population
+
+179
+00:19:30,650 --> 00:19:33,690
+تكون على N في حالة ال sample تكون على N minus واحد
+
+180
+00:19:33,690 --> 00:19:39,670
+اذا حد حابب يعرف ليش كيف اشتغل رياضيا يرجع ل .. في
+
+181
+00:19:39,670 --> 00:19:49,650
+كتير موجودة معلومات عن نتالستاندر ديفياشن لصمم
+
+182
+00:19:49,650 --> 00:19:50,970
+الديفياشن لصمم الديفياشن لصمم الديفياشن لصمم
+
+183
+00:19:50,970 --> 00:19:51,790
+الديفياشن لصمم الديفياشن لصمم الديفياشن لصمم
+
+184
+00:19:51,790 --> 00:19:58,830
+الديفياشن لصمم الديفياشن لصمم الديفياشن
+
+185
+00:19:58,830 --> 00:19:59,090
+لصمم الديفياشن لصمم الديفياشن لصمم الديفياشن لصمم
+
+186
+00:19:59,090 --> 00:20:01,110
+الديفياشن لصمم الديفياشن لصمم الديفياشن لصمم
+
+187
+00:20:01,110 --> 00:20:08,970
+الديفياشن لصمم الديفياشن لصمم الديفياشن
+
+188
+00:20:08,970 --> 00:20:09,750
+لصمم
+
+189
+00:20:15,570 --> 00:20:20,970
+نشوف example example
+
+190
+00:20:20,970 --> 00:20:23,750
+of summer يعني كيف ناخد .. نجيب .. ناخد قراءات أو
+
+191
+00:20:23,750 --> 00:20:27,490
+عينات during
+
+192
+00:20:27,490 --> 00:20:33,090
+a twelve hour test of steam generator لأن في عندي
+
+193
+00:20:33,090 --> 00:20:37,650
+مولد بخاري عندي
+
+194
+00:20:37,650 --> 00:20:38,750
+مولد بخاري
+
+195
+00:20:45,170 --> 00:20:57,370
+بدخل عليه ال steam طبعا بدخل عليه ال steam هنا
+
+196
+00:20:57,370 --> 00:21:04,330
+in وهنا عندي steam out مافيه
+
+197
+00:21:04,330 --> 00:21:12,810
+باطلعش شغل work صح أظبط الآن
+
+198
+00:21:14,180 --> 00:21:18,960
+بدهم يقيصوا الضغط على المدخل ضغط لغاء البخار حط
+
+199
+00:21:18,960 --> 00:21:27,720
+ساعة ضغط هنا لقياس ال pressure الفحص استمر او
+
+200
+00:21:27,720 --> 00:21:36,040
+القراءات اخدت على مدار اتناشر ساعة ال pressure is
+
+201
+00:21:36,040 --> 00:21:43,070
+to be held constant at 4.0 ميجابسكت المفترضان يدخل
+
+202
+00:21:43,070 --> 00:21:54,910
+الضغط الغاز اربعة ميجا بسكال لكن واقعيا مستحيل تظل
+
+203
+00:21:54,910 --> 00:22:01,970
+الأربعة هكون في تذبذ بحوالين اربعة ميجا بسكال for
+
+204
+00:22:01,970 --> 00:22:06,410
+proper performance عشان يكون أداء المولد و الخارق
+
+205
+00:22:06,410 --> 00:22:07,910
+صحيح
+
+206
+00:22:10,090 --> 00:22:13,750
+pressure should not deviate from this value by
+
+207
+00:22:13,750 --> 00:22:18,710
+more than about one percent ال pressure variation
+
+208
+00:22:18,710 --> 00:22:27,530
+او ال deviation مش لازم يتخطى واحد في المية يعني
+
+209
+00:22:27,530 --> 00:22:31,810
+مش لازم يتخطى point O أربعة يعني ال deviation مش
+
+210
+00:22:31,810 --> 00:22:34,330
+لازم يتخطى point اللي هو ال deviation
+
+211
+00:22:39,790 --> 00:22:44,090
+for power performance لازم يكون اقل او يساوي point
+
+212
+00:22:44,090 --> 00:22:55,170
+o4 mega pascal يعني حوالي اربع و عشرة bar inlet
+
+213
+00:22:55,170 --> 00:22:57,970
+pressure was measured one hundred times during the
+
+214
+00:22:57,970 --> 00:23:05,110
+test خلال اتناشر ساعة أخدنا مية قراة various
+
+215
+00:23:05,110 --> 00:23:08,310
+factors caused the readings to fluctuate يعني في
+
+216
+00:23:08,310 --> 00:23:14,040
+عوامل كتيرفيه فقدان الحرارة ال .. ال .. ال ..
+
+217
+00:23:14,040 --> 00:23:18,440
+الاحتكاك ال .. اذا في عندي اكواع في tea vibration
+
+218
+00:23:18,440 --> 00:23:22,220
+كلها بتخلي ال pressure عياش انه ي .. ي .. مايكونش
+
+219
+00:23:22,220 --> 00:23:27,500
+ثابت مش ثابت مية في المية the
+
+220
+00:23:27,500 --> 00:23:31,640
+resolution of the digital pressure gauge used was
+
+221
+00:23:31,640 --> 00:23:36,040
+0.001 ميجاباسكالي يعني الجهاز القياس اللي بيقياس
+
+222
+00:23:36,040 --> 00:23:41,880
+الضغط بيعطيه لحددقة المؤشر بتاعه لحد point O O
+
+223
+00:23:41,880 --> 00:23:51,360
+واحد ميجا بسكال Resolution ال
+
+224
+00:23:51,360 --> 00:24:05,940
+number of
+
+225
+00:24:05,940 --> 00:24:11,170
+results Mis the number of readings falling in an
+
+226
+00:24:11,170 --> 00:24:16,790
+interval of plus or minus 0.005 Mega Pascal
+
+227
+00:24:16,790 --> 00:24:24,370
+centered about the listed pressure يعني هو كان
+
+228
+00:24:24,370 --> 00:24:29,490
+ياخد قراءات بعدين
+
+229
+00:24:29,490 --> 00:24:34,590
+عمل جدول هو أخد مية قراءة أخد مية قراءة
+
+230
+00:24:36,410 --> 00:24:43,290
+أول واحدة مثلا لما بيحكي 3.97 ميجاباسكال معناته
+
+231
+00:24:43,290 --> 00:24:49,950
+بيحكي كل القيم مش حاجة لقراءة بالظبط 3.97 لكن حاجة
+
+232
+00:24:49,950 --> 00:24:59,330
+ل range of values هتكون بينتلاتة point تسعة ستة
+
+233
+00:24:59,330 --> 00:25:05,890
+خمسة لتلاتة point تسعة سبعة خمسة يعني كل قراءة
+
+234
+00:25:05,890 --> 00:25:08,190
+الواقع بين تلاتة point تسعة ستة خمسة و تلاتة point
+
+235
+00:25:08,190 --> 00:25:13,150
+تسعة سبعة عددها إيش واحد كل القراءات اللي جاها بين
+
+236
+00:25:13,150 --> 00:25:18,490
+تلاتة point تسعة سبعة خمسة و تلاتة point تسعة
+
+237
+00:25:18,490 --> 00:25:23,690
+تمانية خمسة عددها تلاتةكل قراءات اللي بين تلاتة
+
+238
+00:25:23,690 --> 00:25:30,030
+point تسعة تمانية خمسة تلاتة point تسعة تسعة خمسة
+
+239
+00:25:30,030 --> 00:25:36,570
+اتناشر قراءة وكل قراءة اللي بين تلاتة point تسعة
+
+240
+00:25:36,570 --> 00:25:41,530
+تسعة خمسة واربع point او او خمسة عددها خمسة وعشرين
+
+241
+00:25:41,530 --> 00:25:48,170
+والقراءات اللي اربع point او او خمسة الى اربع
+
+242
+00:25:48,170 --> 00:25:53,850
+point او واحد خمسة عددهاتلاتة و تلاتين والقراءات
+
+243
+00:25:53,850 --> 00:25:58,830
+اللي بين اربعة point O خمسة لاربعة point O اتنين
+
+244
+00:25:58,830 --> 00:26:04,870
+خمسة عددها سبعتاشوالقراءات بين أربع point O اتنين
+
+245
+00:26:04,870 --> 00:26:10,730
+خمسة و أربع point O تلاتة خمسة عددها ستة و
+
+246
+00:26:10,730 --> 00:26:15,310
+القراءات بين أربع point O تلاتة خمسة و أربع point
+
+247
+00:26:15,310 --> 00:26:20,590
+O أربع خمس عددها اتنين و القراءات بين أربع point O
+
+248
+00:26:20,590 --> 00:26:28,470
+أربع خمسة و أربع point O خمسة خمس عددها واحدةطبعا
+
+249
+00:26:28,470 --> 00:26:34,370
+هو كان ماخد قراءات مائة قراءة و بعدين صنفهم صنف
+
+250
+00:26:34,370 --> 00:26:39,070
+القراءات ولاقي مثلا في ال range بين تلاتة point
+
+251
+00:26:39,070 --> 00:26:41,410
+تسعة و تسعة و خمسة و تلاتة point تسعة و خمسة و
+
+252
+00:26:41,410 --> 00:26:46,710
+تسعة و خمسة قراءة واحدة ماشي و عندي مثلا بين اربع
+
+253
+00:26:46,710 --> 00:26:48,710
+point او واحد خمسة واربع point او اتنين و خمسة
+
+254
+00:26:48,710 --> 00:26:54,590
+عددهم سبعتاش واحد كذا صنفهم بالشكل هذا number of
+
+255
+00:26:54,590 --> 00:27:03,300
+results andبعدين عمل graph اسمه histogram طبعا
+
+256
+00:27:03,300 --> 00:27:10,080
+عندي هنا تلاتة
+
+257
+00:27:10,080 --> 00:27:14,400
+بون تسعة سبعة على
+
+258
+00:27:14,400 --> 00:27:20,680
+المحور الأفقي القيمة الوسطى عندي هنا تلاتة بون
+
+259
+00:27:20,680 --> 00:27:25,620
+تسعة سبعة صح؟تلاتة point تسعة تمانية تلاتة point
+
+260
+00:27:25,620 --> 00:27:30,540
+تسعة سبعة أكثر مرة اتكررت واحد تلاتة point تسعة
+
+261
+00:27:30,540 --> 00:27:39,780
+تمانية مرتين تلاتة point تسعة
+
+262
+00:27:39,780 --> 00:27:49,620
+تسعة اتناش ع اتناشر قراءة اربع خمسة
+
+263
+00:27:49,620 --> 00:27:58,170
+و عشريناربع بنت ا خمسة
+
+264
+00:27:58,170 --> 00:28:05,250
+تلاتة و تلاتين صح او اربع بنت ا واحد تلاتة و
+
+265
+00:28:05,250 --> 00:28:13,050
+تلاتين اربع بنت ا اتنين سبعتاش اربع بنت ا تلاتة
+
+266
+00:28:13,050 --> 00:28:20,150
+ستة و هكذا هو الهدف من ال histogram عشان يشوف يقيم
+
+267
+00:28:22,420 --> 00:28:30,700
+لل trend أو كيف شكل ال curve واضح انه يعني قريب من
+
+268
+00:28:30,700 --> 00:28:33,700
+ال normal distribution واضح من شكل ال histogram
+
+269
+00:28:33,700 --> 00:28:40,080
+انه قريب من ال .. طبعا ال histogram ممكن ترسم
+
+270
+00:28:40,080 --> 00:28:46,300
+باستخدام ال Excel او باستخدام ال Minitab او ال
+
+271
+00:28:46,300 --> 00:28:57,120
+SPSS يعني ال Excelأو الـ Minitab أو
+
+272
+00:28:57,120 --> 00:29:06,620
+ال SP SS في براج تانية طبعا الان
+
+273
+00:29:06,620 --> 00:29:14,240
+انا خدت القراءات و حطيتها على ال Excel العمود
+
+274
+00:29:14,240 --> 00:29:18,840
+الأول ال pressure اللي هي تلاتة بون تسعة سبعة
+
+275
+00:29:22,830 --> 00:29:25,970
+تلاتة بون تسعة سبعة تمثل البيانات بين تلاتة بون
+
+276
+00:29:25,970 --> 00:29:30,090
+تسعة ستة خمسة لتلاتة بون تسعة سبعة خمسة صح؟ هنا
+
+277
+00:29:30,090 --> 00:29:34,890
+number of results M عندي كان ايش؟ واحد يعني هذا
+
+278
+00:29:34,890 --> 00:29:41,630
+جدول الأصلي هذا جدول الأصلي بعدين
+
+279
+00:29:41,630 --> 00:29:48,590
+ضربت قي القراءة بعددها يعني تلاتة بون تسعة سبعة في
+
+280
+00:29:48,590 --> 00:29:52,970
+واحد اشتيطينينتلاتة point تسعة سبعة تلاتة point
+
+281
+00:29:52,970 --> 00:29:57,750
+تسعة تمانية في تلاتة احداش point تسعة اربعة مثلا
+
+282
+00:29:57,750 --> 00:30:02,570
+اربعة point او اتنين في سبعتاش تلاتين تمانية ستين
+
+283
+00:30:02,570 --> 00:30:09,350
+point تلاتة اربعة بعدين حسبت ال deviation لكل
+
+284
+00:30:09,350 --> 00:30:15,830
+قراءة طب عشان احسب ال deviation ايش بدى احسب حجمها
+
+285
+00:30:15,830 --> 00:30:18,810
+دول صح مظبوط
+
+286
+00:30:19,950 --> 00:30:26,090
+بجمع هدول و باقسم علي ايش لأ
+
+287
+00:30:26,090 --> 00:30:35,070
+هذا مجموعهم هذا مش ال deviation هذا مجموعهم هذا ..
+
+288
+00:30:35,070 --> 00:30:40,650
+هذا لأ هذا مجموع كل القراءات لأنه هذا تلاتة و
+
+289
+00:30:40,650 --> 00:30:43,630
+بنتصف تمانية في واحد هذا تلاتة و بنتصف تمانية كأنه
+
+290
+00:30:43,630 --> 00:30:45,590
+تلات قراءات تلاتة و بنتصف تمانية و تلاتة و بنتصف
+
+291
+00:30:45,590 --> 00:30:49,180
+تمانية و تلاتة و بنتصف تمانية و احد كذاهذه سأقسمها
+
+292
+00:30:49,180 --> 00:30:54,120
+لإيش على مية بالظبط معناته بحسب اللي هو ال min
+
+293
+00:30:54,120 --> 00:31:02,520
+pressure P min بالساوية ال summation ل all
+
+294
+00:31:02,520 --> 00:31:13,660
+pressures على عددها اللي هي أربعمية على
+
+295
+00:31:13,660 --> 00:31:16,240
+مية يعني هتكون تساوي
+
+296
+00:31:19,570 --> 00:31:28,830
+اربع بنت او تمانية ميجا
+
+297
+00:31:28,830 --> 00:31:34,250
+فاسكال لأن
+
+298
+00:31:34,250 --> 00:31:41,310
+ال deviation في كل قرعة ال deviation بيستوى x i
+
+299
+00:31:41,310 --> 00:31:49,610
+minus x barيعني القراءة هذه تلاتة point السبعة ال
+
+300
+00:31:49,610 --> 00:31:53,350
+deviation فيها هيكون تلاتة point سبعة سبعة ناقص
+
+301
+00:31:53,350 --> 00:31:57,290
+اربع point او او تمانية ال deviation في القراءة
+
+302
+00:31:57,290 --> 00:32:03,090
+التانية تلاتة point سعة تمانية ناقص اربع point او
+
+303
+00:32:03,090 --> 00:32:07,410
+او تمانية ال deviation في القراءة التالتة تلاتة
+
+304
+00:32:07,410 --> 00:32:11,750
+point سعة تسعة ناقص اربع point او او تمانية
+
+305
+00:32:11,750 --> 00:32:17,850
+القراءة الرابعة ال deviation فيها هيكوناربعة ناقص
+
+306
+00:32:17,850 --> 00:32:20,550
+اربعة point او او تمانية واحدة كذا هذه ال
+
+307
+00:32:20,550 --> 00:32:27,230
+deviations الان هربيعهم هوجد deviations تربيع ال
+
+308
+00:32:27,230 --> 00:32:33,410
+deviations تربيع الان ال deviations تربيع انت
+
+309
+00:32:33,410 --> 00:32:38,810
+تشتري هذه الأولاكها مرة و كره مرة مرة هذه ثلاثة
+
+310
+00:32:38,810 --> 00:32:43,650
+وانا تحضره بال M في ال deviation تربيع لأنه بتحسب
+
+311
+00:32:43,650 --> 00:32:49,640
+ان ال standard deviationالـ Sx بالسواء جزر التربيه
+
+312
+00:32:49,640 --> 00:32:54,580
+للـ summation للـ deviation التربيه على الـ minus
+
+313
+00:32:54,580 --> 00:33:00,380
+واحد لأن ال deviation الأول تربيه مكرر مرة واحدة
+
+314
+00:33:00,380 --> 00:33:03,320
+ال deviation التاني تربيه مكرر تلت مرات بقى أنا
+
+315
+00:33:03,320 --> 00:33:09,240
+أحضرها في تلاتة صح؟ يعني ستكون ال summation هذه
+
+316
+00:33:09,240 --> 00:33:11,280
+ستكون واحد
+
+317
+00:33:13,710 --> 00:33:20,110
+في point o o واحدة اربعة اتنين زائد تلاتة في point
+
+318
+00:33:20,110 --> 00:33:25,310
+o o سبعة سبعة اللي هي هذه صح لان بجمع هدول كلهم
+
+319
+00:33:25,310 --> 00:33:34,450
+بطلع مجموعهم اللي هو summation لل deviation تربية
+
+320
+00:33:34,450 --> 00:33:37,870
+اللي هو point o طمنتاش
+
+321
+00:33:46,280 --> 00:33:58,140
+.O186 معناته هيكون ان ال Sx الجزر التربيعي ل.O186
+
+322
+00:33:58,140 --> 00:34:04,580
+على 99 بيطلع
+
+323
+00:34:04,580 --> 00:34:08,820
+ال standard deviation بسواء point O14
+
+324
+00:34:10,940 --> 00:34:16,920
+بنت او واحد اربع يعني احنا عسبنا ال mean للعينة
+
+325
+00:34:16,920 --> 00:34:21,400
+اللي طلعت اربع بنت او او تمانية وال standard
+
+326
+00:34:21,400 --> 00:34:28,800
+deviation للعينة اللي طلعت بنت زيرو واحد اربع ماجا
+
+327
+00:34:28,800 --> 00:34:36,980
+بسكال ال
+
+328
+00:34:36,980 --> 00:34:37,940
+interval
+
+329
+00:34:41,140 --> 00:35:03,280
+اللي بتحتوي على 95% من ال pressure rating هو
+
+330
+00:35:03,280 --> 00:35:10,600
+أساسا مش زي هيك صح؟ مظبوط؟
+
+331
+00:35:12,600 --> 00:35:27,960
+وهذا ايش ال Sx معناته
+
+332
+00:35:27,960 --> 00:35:33,800
+هاخد انا ال 95 في خمسة كيلو من البيانات هاخد واحد
+
+333
+00:35:33,800 --> 00:35:44,390
+point تسعة ستة SP واحد point تسعة ستةsp يعني هذه
+
+334
+00:35:44,390 --> 00:35:50,850
+هي المساحة صح بس
+
+335
+00:35:50,850 --> 00:36:02,970
+هو ده حسب ال z في الأول صح ال z ده شو يساوي اللي
+
+336
+00:36:02,970 --> 00:36:08,510
+هي x bar او
+
+337
+00:36:08,510 --> 00:36:16,530
+ال z بالساعة اللي هوx-x
+
+338
+00:36:16,530 --> 00:36:28,690
+bar على sx صح مظبوط اتأكد المعادلة هاي
+
+339
+00:36:28,690 --> 00:36:32,410
+هو مظبوط x-x bar على sx
+
+340
+00:36:41,930 --> 00:36:47,290
+الان المساحة هذه يعني
+
+341
+00:36:47,290 --> 00:36:54,210
+هيكون عندها اللى هى بين اللى هيتمثل هذه ال area
+
+342
+00:36:54,210 --> 00:37:02,450
+بتساوي 95% 95
+
+343
+00:37:02,450 --> 00:37:06,350
+% هتكون
+
+344
+00:37:06,350 --> 00:37:08,750
+ال pressure
+
+345
+00:37:12,020 --> 00:37:17,320
+بساوى اللى هو ال average value اربعة point أو
+
+346
+00:37:17,320 --> 00:37:24,880
+تمانية زائد او ناقص point
+
+347
+00:37:24,880 --> 00:37:33,920
+zero نين سبعة ميجا بسكال ال
+
+348
+00:37:33,920 --> 00:37:38,720
+هادى اللى هادى عنده
+
+349
+00:37:43,210 --> 00:37:51,690
+بونت اتنين سبعة صح طبعا
+
+350
+00:37:51,690 --> 00:37:57,550
+بدرجة تيقن بدرجة تيقن خمسة وتسعين في المية يعني
+
+351
+00:37:57,550 --> 00:38:03,750
+احتمالية ان الكراءة من هذه التجربة تكون واقعة في
+
+352
+00:38:03,750 --> 00:38:08,290
+ال range اربع point او اتمانية plus or minus point
+
+353
+00:38:08,290 --> 00:38:15,620
+او اتنين سبعةخمس نصف فالمية مناطق الاحتمال النجاح
+
+354
+00:38:15,620 --> 00:38:19,980
+ان تكون القراءة في ال range هذا هو ايش؟ خمس نصف
+
+355
+00:38:19,980 --> 00:38:23,300
+فالمية اللي هو .. هي الخمس نصف فالمية اللي هي درجة
+
+356
+00:38:23,300 --> 00:38:28,040
+التيقن انا متيقن بنسبة خمس نصف فالمية بحكي عن
+
+357
+00:38:28,040 --> 00:38:32,660
+احتمال one
+
+358
+00:38:32,660 --> 00:38:36,140
+objective of the pressure test was to verify that
+
+359
+00:38:37,100 --> 00:38:42,020
+pressure did not deviate from 4.0 Mega Pascal by
+
+360
+00:38:42,020 --> 00:38:45,680
+more than one percent أحد الأهداف التجربة اللى
+
+361
+00:38:45,680 --> 00:38:54,080
+صارت ان نتأكد نتحقق انه الضغط ما يبتعد عن أربعة
+
+362
+00:38:54,080 --> 00:38:58,240
+Mega Pascal بقيمة واحد بالمية يعنى انا مسموح ليه
+
+363
+00:38:58,240 --> 00:39:03,280
+يكون الضغط الضغط مسموح ليه ال P allowed allowed
+
+364
+00:39:03,280 --> 00:39:05,860
+أربعة
+
+365
+00:39:07,310 --> 00:39:13,530
+plus or minus واحد في المية من الأربعة صح يعني
+
+366
+00:39:13,530 --> 00:39:21,030
+هتكون اربعة plus or minus point of four يعني ..
+
+367
+00:39:21,030 --> 00:39:29,890
+يعني اللي هيكون ال pressure بين تلاتة تسعة ستة
+
+368
+00:39:29,890 --> 00:39:37,980
+لاربعة point او اربعةأحنا خلّين نطلع على البيانات
+
+369
+00:39:37,980 --> 00:39:42,920
+أول شي نطلع
+
+370
+00:39:42,920 --> 00:39:50,140
+على القراءات يعني
+
+371
+00:39:50,140 --> 00:39:53,120
+هذه أكبر من تلاتة و متسعة ستة، مظبوط؟ في ال range
+
+372
+00:39:53,120 --> 00:39:59,660
+كله في ال range في ال range فمعظم القراءات يعني
+
+373
+00:39:59,660 --> 00:40:04,490
+هذه جاي برا ال range تقريبابس انا .. انا .. انا
+
+374
+00:40:04,490 --> 00:40:09,250
+مابطلعش .. مابطلعش بطلع ال average انا بطلع ال
+
+375
+00:40:09,250 --> 00:40:15,450
+average و درجة تياب كل انا حاططها in
+
+376
+00:40:15,450 --> 00:40:17,930
+terms of standard deviation انا ال standard
+
+377
+00:40:17,930 --> 00:40:25,230
+deviation دي اكم طلع ال Sx point O أربعتاش ال Sx
+
+378
+00:40:25,230 --> 00:40:28,290
+بالسواء
+
+379
+00:40:28,290 --> 00:40:33,630
+point O واحد أربعة .. أربعتاشو ال allowed
+
+380
+00:40:33,630 --> 00:40:42,090
+deviation ال allowed deviation ال
+
+381
+00:40:42,090 --> 00:40:47,150
+allowed deviation
+
+382
+00:40:47,150 --> 00:40:52,210
+اللي
+
+383
+00:40:52,210 --> 00:41:02,070
+هو point O أربعة طيب ال point O أربعة
+
+384
+00:41:05,990 --> 00:41:14,370
+على point او واحد اربع اكمت الساوية
+
+385
+00:41:14,370 --> 00:41:17,770
+لاحظ
+
+386
+00:41:17,770 --> 00:41:23,890
+شوية استكد من الاشياء
+
+387
+00:41:23,890 --> 00:41:28,810
+تطلع
+
+388
+00:41:28,810 --> 00:41:33,210
+لي هي اتنين point تمالية
+
+389
+00:41:36,720 --> 00:41:40,100
+بالنسبة لـ standard deviation الـ point O أربع
+
+390
+00:41:40,100 --> 00:41:45,840
+عامية جاباسكال بيستوى 2.86 SP احنا حاولنا ان
+
+391
+00:41:45,840 --> 00:41:54,180
+نحصلحها بيكون 2.86 SP الان لما نيجي على ال
+
+392
+00:41:54,180 --> 00:41:54,740
+distribution
+
+393
+00:42:01,620 --> 00:42:10,240
+عندى اتنين point تمانية ستة و اتنين minus اتنين
+
+394
+00:42:10,240 --> 00:42:11,860
+point تمانية ستة نروح على ال table
+
+395
+00:42:21,900 --> 00:42:30,280
+تنين point تمانية ستة ستة يعني اكم الرابع تنين
+
+396
+00:42:30,280 --> 00:42:34,160
+point تمانية ستة
+
+397
+00:42:34,160 --> 00:42:40,620
+يعني نص المساحة كانت بالساوية اربعة
+
+398
+00:42:40,620 --> 00:42:46,160
+point اربعة تسعة سبعة يعني ال probability ال
+
+399
+00:42:46,160 --> 00:42:47,200
+probability انه
+
+400
+00:42:52,040 --> 00:42:59,620
+الـ Z تكون أكبر أوي الساوية أكبر أوي الساوية صفر و
+
+401
+00:42:59,620 --> 00:43:04,040
+أصغر أوي الساوية اتنين point eight six بس هو point
+
+402
+00:43:04,040 --> 00:43:11,440
+أربعة تسعة سبعة تسعة طيب ال probability ان ال
+
+403
+00:43:11,440 --> 00:43:14,540
+range minus ال plus و ال minus ال probability ان
+
+404
+00:43:14,540 --> 00:43:17,740
+ال Z تكون
+
+405
+00:43:19,320 --> 00:43:25,340
+أكبر او يساوي minus 2.86 سيجما و أصغر من 2.86
+
+406
+00:43:25,340 --> 00:43:40,400
+سيكون 2 في هذا 2 9 18 2 7 15 2 9 19 2 4 9 مظبوط
+
+407
+00:43:40,400 --> 00:43:47,580
+يعني هتكون 99.85%
+
+408
+00:43:51,590 --> 00:44:00,110
+يعني في كل مية .. في كل مية في عندي point four two
+
+409
+00:44:00,110 --> 00:44:05,950
+هكون out of range في كل مية هكون عندي point four
+
+410
+00:44:05,950 --> 00:44:11,250
+two يعني هكون مية على point four two أكم بالساوية
+
+411
+00:44:25,650 --> 00:44:33,590
+تقريبا تقريبا تقريبا تقريبا تقريبا
+
+412
+00:44:33,590 --> 00:44:37,050
+تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا
+
+413
+00:44:37,050 --> 00:44:37,290
+تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا تقريبا
+
+414
+00:44:37,290 --> 00:44:38,670
+تقريبا تقريبا تقريبا تقريبا تقريب
+
+415
+00:44:41,860 --> 00:44:46,780
+طيب في اي سؤال الهدف من تجربة هذا ان انت بتعمل ..
+
+416
+00:44:46,780 --> 00:44:51,480
+هتعمل تجربة اي تجربة لازم تعرف كيف تحللها و تستخرج
+
+417
+00:44:51,480 --> 00:44:55,880
+ال .. ال .. ال .. البيانات تعرف الجهاز شغال صح ال
+
+418
+00:44:55,880 --> 00:45:00,640
+process شغالة صح طيب
+
+419
+00:45:00,640 --> 00:45:04,080
+الان
+
+420
+00:45:04,080 --> 00:45:07,480
+الان لما نحكي theory based
+
+421
+00:45:10,630 --> 00:45:15,430
+on sample ال
+
+422
+00:45:15,430 --> 00:45:20,990
+sample قد تكون كبيرة عدد
+
+423
+00:45:20,990 --> 00:45:28,810
+القراءات كبير أو قد تكون عدد القراءات صغير إذا كان
+
+424
+00:45:28,810 --> 00:45:32,010
+عدد القراءات أكبر أو يستوى تلاتين بعتبرها large
+
+425
+00:45:32,010 --> 00:45:35,730
+sample إذا كان عدد القراءات أكبر أو يستوى تلاتين
+
+426
+00:45:35,730 --> 00:45:41,450
+بعتبرها largeسامبل اذا اقل من تلاتين بعتبر small
+
+427
+00:45:41,450 --> 00:45:51,650
+sample لان احنا هنتعامل اول اشي مع large sample في
+
+428
+00:45:51,650 --> 00:45:59,250
+المثال السابق احنا شوفنا كيف قيمنا التشتت للقراءات
+
+429
+00:45:59,250 --> 00:46:05,380
+العينةحوالين القيمة الوسطى لكل القراءات احنا جبنا
+
+430
+00:46:05,380 --> 00:46:08,400
+ال mean value لل sample و حسبنا ال standard
+
+431
+00:46:08,400 --> 00:46:11,880
+deviation لل sample of pressure reading و من خلال
+
+432
+00:46:11,880 --> 00:46:16,140
+هذه الدراسة عرفنا مدى التشتت للقراءات حوالين ال
+
+433
+00:46:16,140 --> 00:46:20,460
+average value طبعا
+
+434
+00:46:20,460 --> 00:46:24,580
+هذه اعطتني بيانات او معلومات عن ال sample نفسها
+
+435
+00:46:25,180 --> 00:46:29,920
+أتطلب معلومات اللي هي ال mean value لل sample وال
+
+436
+00:46:29,920 --> 00:46:35,160
+standard deviation لل sample ما اتطنيش حساب او
+
+437
+00:46:35,160 --> 00:46:40,100
+تقدير لنسبة الخطأ ان
+
+438
+00:46:40,100 --> 00:46:46,460
+لو استخدمت ال average value لل sample عشان
+
+439
+00:46:46,460 --> 00:46:53,760
+يتعبر عن ال average value لل populationال
+
+440
+00:46:53,760 --> 00:46:59,180
+population لل pressure reading ايش هي؟ مش عارف ايه
+
+441
+00:46:59,180 --> 00:47:02,260
+احنا خدنا الساعة بقى خدنا الساعة بقى عامة مية قرا
+
+442
+00:47:02,260 --> 00:47:04,480
+على مدت اتناشر ساعة ال population على طول ما هو
+
+443
+00:47:04,480 --> 00:47:12,640
+المولد شغال يعني عدد لا نهاية عدد لا نهاية طيب في
+
+444
+00:47:12,640 --> 00:47:16,740
+محطة مثلا الكهرة فيها مولد بخاري هل ممكن يحصل على
+
+445
+00:47:16,740 --> 00:47:20,240
+.. على population؟
+
+446
+00:47:25,610 --> 00:47:33,510
+هو المفروض يكون .. المفروض ان يكون عنده راكب اجهزة
+
+447
+00:47:33,510 --> 00:47:37,450
+قياسية دي و باخد قراءات على مدار الساعة يعني كل
+
+448
+00:47:37,450 --> 00:47:41,490
+ثانية باخد قراءات و يكون عنده data logging يعني
+
+449
+00:47:41,490 --> 00:47:45,190
+فيه يعني تخزين للبيانات فممكن يكون عنده على المدى
+
+450
+00:47:45,190 --> 00:47:50,970
+البعيد اللي هي ايش population لكن هو قادر يركب
+
+451
+00:47:50,970 --> 00:47:55,750
+المولد المخاري و يفحصهفي البداية ماعنده population
+
+452
+00:47:55,750 --> 00:48:05,970
+صح عنده sample اذا
+
+453
+00:48:05,970 --> 00:48:11,830
+تجبت الفحص الضغط عدناه كمان مرة يعني عملنا كمان
+
+454
+00:48:11,830 --> 00:48:19,440
+تجربة مثلا بيوم تاني واخدنا مئة قراءة جديدةهل
+
+455
+00:48:19,440 --> 00:48:22,080
+هيطلعوا نفس ال average value و نفس ال standard
+
+456
+00:48:22,080 --> 00:48:28,260
+deviation؟ لأ مش هيطلعوا نفس ال average value ولا
+
+457
+00:48:28,260 --> 00:48:30,340
+نفس ال standard deviation
+
+458
+00:48:35,910 --> 00:48:40,590
+العديد من المرات مثلا عندنا مثلا عشرين تلاتين مرة
+
+459
+00:48:40,590 --> 00:48:45,690
+بيصير عندى distribution ل ال main values و
+
+460
+00:48:45,690 --> 00:48:49,450
+distribution ليهاش ل standardization يعني مثلا
+
+461
+00:48:49,450 --> 00:48:54,210
+distribution ل ال main valuesو ال distribution لل
+
+462
+00:48:54,210 --> 00:48:56,530
+standard deviations لكل العينات يعني العينا الأولى
+
+463
+00:48:56,530 --> 00:48:59,290
+لو سمع مية العينة التانية مية العينة التالتة مية
+
+464
+00:48:59,290 --> 00:49:03,610
+العينة رقم خمسين مية كل واحدة لها mean value كل
+
+465
+00:49:03,610 --> 00:49:05,610
+واحدة لها standard deviation معناته احصل على ال
+
+466
+00:49:05,610 --> 00:49:11,570
+distribution لل means و ال standard deviations
+
+467
+00:49:11,570 --> 00:49:21,110
+طبعا
+
+468
+00:49:23,020 --> 00:49:29,540
+العينات ال means عينات القيم المتوسطة بتورجينا انه
+
+469
+00:49:29,540 --> 00:49:35,200
+في تشتت حوالين ال central value القيم المتوسطة لكل
+
+470
+00:49:35,200 --> 00:49:42,020
+ال mean values مظلوط؟ مانعته اذا if n for each
+
+471
+00:49:42,020 --> 00:49:48,800
+sample is very large اذا كان very large يعني عدد
+
+472
+00:49:48,800 --> 00:49:52,080
+القراءات لكل تجارب اكتر من تلاتين
+
+473
+00:49:55,360 --> 00:50:02,100
+هيكون distribution of mean values is Gaussian that
+
+474
+00:50:02,100 --> 00:50:07,200
+has a standard deviation sigma
+
+475
+00:50:07,200 --> 00:50:12,800
+x bar بستوى
+
+476
+00:50:12,800 --> 00:50:18,300
+ال sigma على الجزر التربيعي لل N
+
+477
+00:50:22,820 --> 00:50:25,740
+كل سامبل كان عادى n و الـ n كان very large يعني
+
+478
+00:50:25,740 --> 00:50:29,320
+أكبر من تلاتين لعندي distribution of mean values
+
+479
+00:50:29,320 --> 00:50:31,600
+is Gaussian that has a standard deviation of sigma
+
+480
+00:50:31,600 --> 00:50:40,360
+x bar على بيسوى sigma على ديزيتير ميو يعني
+
+481
+00:50:40,360 --> 00:50:45,240
+ال sigma x bar هي
+
+482
+00:50:45,240 --> 00:50:51,620
+ال standard deviation sigma x bar هي ال standard
+
+483
+00:50:51,620 --> 00:50:52,160
+deviation
+
+484
+00:50:54,630 --> 00:50:58,210
+الى مجموعة ال means مجموعة المتوسطات احنا حكينا
+
+485
+00:50:58,210 --> 00:51:02,890
+عمال اننا سنتجروا اصلا خمسين مرة فكل مرة كنا نحصل
+
+486
+00:51:02,890 --> 00:51:06,470
+على ال mean value هكون دي X bar واحد X bar اتنين X
+
+487
+00:51:06,470 --> 00:51:11,550
+bar تلاتة X bar خمسة و هكذا هدول حسبتلهم ال mean و
+
+488
+00:51:11,550 --> 00:51:14,110
+حسبت ال standard deviation يعني هدى ال sigma X bar
+
+489
+00:51:14,110 --> 00:51:15,630
+هي ال standard deviation
+
+490
+00:51:26,720 --> 00:51:32,060
+الان ال sigma هي
+
+491
+00:51:32,060 --> 00:51:37,140
+ال standard deviation لل population طبعا شو يطلوب
+
+492
+00:51:37,140 --> 00:51:43,800
+ان نشتق العلاقة هذه sigma x bar سواء sigma على جزء
+
+493
+00:51:43,800 --> 00:51:45,380
+التربيعي لل n
+
+494
+00:51:49,910 --> 00:51:57,790
+خلّيني أعرف الـ z الـ z اللي هي x bar minus mu على
+
+495
+00:51:57,790 --> 00:52:02,990
+سيجما x bar بس x bar اللي هي سيجما x اللي هي سيجما
+
+496
+00:52:02,990 --> 00:52:09,630
+عجزة تربيعي لل n with
+
+497
+00:52:09,630 --> 00:52:17,190
+c percent confidence لل true mean value اللي هي ال
+
+498
+00:52:17,190 --> 00:52:17,790
+mean value لمن
+
+499
+00:52:20,660 --> 00:52:24,700
+لل population ال true mean value لل population
+
+500
+00:52:24,700 --> 00:52:30,860
+with
+
+501
+00:52:30,860 --> 00:52:40,760
+c confidence ال confidence ايش معناته بس
+
+502
+00:52:40,760 --> 00:52:47,970
+حاجة دي صح ليه احتمالية تكون ال values بينبين هذا
+
+503
+00:52:47,970 --> 00:52:51,970
+القيمة و هذا القيمة هذا درجة اكل with c percentage
+
+504
+00:52:51,970 --> 00:52:57,130
+confidence ال true mean value لل population ال mu
+
+505
+00:52:57,130 --> 00:53:05,470
+هتكون اكبر السواء X bar X bar ايش هذا X bar ال
+
+506
+00:53:05,470 --> 00:53:13,210
+mean لإيش ل ال sample ل ال sample مش لكل ال
+
+507
+00:53:13,210 --> 00:53:17,210
+samplesالسماعة وانتجوا بواحدة انا مثلا عددهم
+
+508
+00:53:17,210 --> 00:53:25,810
+اربعين كراها هذا ال X bar الاسم بالواحدة minus Z C
+
+509
+00:53:25,810 --> 00:53:35,690
+على اتنين ليه هذا هذا Z C على اتنين في ال sigma
+
+510
+00:53:35,690 --> 00:53:42,070
+جزر التربيه على ال N و اصغر من X bar زي Z C على
+
+511
+00:53:42,070 --> 00:53:47,300
+اتنين في ال sigmaجزر ألماناتو من خلال معرفتي
+
+512
+00:53:47,300 --> 00:53:57,580
+لخصائص ال sample بإمكاني أتوقع القيمة الوسطى لل
+
+513
+00:53:57,580 --> 00:54:03,620
+population من خلال معرفتي للخصائص تاعة ال sample
+
+514
+00:54:03,620 --> 00:54:09,620
+بإمكاني أتوقع القيمة الوسطى لل population
+
+515
+00:54:16,520 --> 00:54:22,360
+طبعا for large samples هحط ال sigma هعبّر عنها
+
+516
+00:54:22,360 --> 00:54:26,520
+بإيش؟ Sx احنا حاكيناها في ال sample بحط بدل sigma
+
+517
+00:54:26,520 --> 00:54:32,960
+Sx فهستير اندي الميو جاي في ال range بين X bar بين
+
+518
+00:54:32,960 --> 00:54:38,140
+ZC على 2 في SX على جزر N و بين X bar زاد ZC على 2
+
+519
+00:54:38,140 --> 00:54:47,920
+في SX على جزر Nو ال Sx bar بيستوى x Sx على جزر ا
+
+520
+00:54:47,920 --> 00:54:57,960
+يعني ها دي ها دي ايش كلها Sx bar طيب
+
+521
+00:54:57,960 --> 00:55:04,680
+نشوف مثال determine
+
+522
+00:55:04,680 --> 00:55:07,380
+a 99 percent confidence interval
+
+523
+00:55:09,890 --> 00:55:12,390
+for the mean pressure calculated in the previous
+
+524
+00:55:12,390 --> 00:55:17,430
+example او جد تسعة و تسعين في المية confidence
+
+525
+00:55:17,430 --> 00:55:21,830
+interval لل mean pressure اللي حسبناه في المثال
+
+526
+00:55:21,830 --> 00:55:30,950
+السابق السي اكمال دي او المساحة
+
+527
+00:55:30,950 --> 00:55:38,870
+هذه
+
+528
+00:55:38,870 --> 00:55:39,350
+كلها
+
+529
+00:55:43,630 --> 00:55:53,310
+الـ Area بالساوية point 9 9 صح هذه الـ Z N Zero Z
+
+530
+00:55:53,310 --> 00:56:03,790
+C على 2 هذه الـ Z minus Z C على 2 صح معناته هروح
+
+531
+00:56:03,790 --> 00:56:08,490
+على الجدول هروح
+
+532
+00:56:08,490 --> 00:56:09,090
+على الجدول
+
+533
+00:56:16,100 --> 00:56:21,800
+الـ z اللي هو نص المسافة هتكون كم point أربعة تسعة
+
+534
+00:56:21,800 --> 00:56:43,360
+خمسة point أربعة point أربعة تسعة لحظة
+
+535
+00:56:43,360 --> 00:56:50,210
+لحظةيعني جاي بين هذه و هذه صح جاي في المنطقة هذه
+
+536
+00:56:50,210 --> 00:57:00,470
+صح point أربعة تسعة خمسة جاي
+
+537
+00:57:00,470 --> 00:57:07,710
+هنا هذه
+
+538
+00:57:07,710 --> 00:57:17,000
+التسعة تمانية سبعة صح يعني جاي عند اتنينبنت خمسة
+
+539
+00:57:17,000 --> 00:57:27,360
+سبعة كانت اكم بنت اربعة تسعة اربعة
+
+540
+00:57:27,360 --> 00:57:33,660
+تسعة فعند اتنين خمسة
+
+541
+00:57:33,660 --> 00:57:44,600
+تمانية بنت اربعة تسعة خمسة واحد فانا بده عندpoint
+
+542
+00:57:44,600 --> 00:57:52,520
+4 9 5 لأ
+
+543
+00:57:52,520 --> 00:57:57,020
+واضح ان هذه 49 و 51 جاية في المص بالظبط يعني
+
+544
+00:57:57,020 --> 00:58:00,480
+محظوظين ان احنا جاية في ايش في المص بالظبط هذه
+
+545
+00:58:00,480 --> 00:58:05,950
+خمسين لان صح مظبوطيعني هاد تسعة واربعين و واحد و
+
+546
+00:58:05,950 --> 00:58:08,130
+خمسين دي أفرموس معناته هاد هتكون القراءه عايش
+
+547
+00:58:08,130 --> 00:58:19,390
+هتكون اتنين point خمسة سبعة خمسة point اتنين خمسة
+
+548
+00:58:19,390 --> 00:58:25,810
+سبعة خمسة معناه ز سي على اتنين اتنين point خمسة
+
+549
+00:58:25,810 --> 00:58:27,010
+سبعة خمسة
+
+550
+00:58:33,490 --> 00:58:40,250
+اللي هي هي هذه Z اللي هي عند المساحة point أربع
+
+551
+00:58:40,250 --> 00:58:46,070
+ساعة خمسة طلعتين point خمسة سابعة خمسة المعنى هو
+
+552
+00:58:46,070 --> 00:58:50,950
+الـ Mu بتاعة ال pressure هتكون تتراوح بين ال P
+
+553
+00:58:50,950 --> 00:58:53,470
+average ال P average احنا حسبناها من المثال السابق
+
+554
+00:58:53,470 --> 00:59:00,550
+ال P average ايه اكتر طلعت معنا أربع
+
+555
+00:59:00,550 --> 00:59:00,950
+point
+
+556
+00:59:04,450 --> 00:59:10,790
+zero zero zero تمانية ميجا
+
+557
+00:59:10,790 --> 00:59:14,350
+بسكال و
+
+558
+00:59:14,350 --> 00:59:20,530
+ال standard deviation ال Sx كم كان؟ zero point
+
+559
+00:59:20,530 --> 00:59:26,810
+zero واحد اربعة ميجا بسكال المعنى هو ال value الهو
+
+560
+00:59:26,810 --> 00:59:30,850
+ال population بتاع كل قرة الضغط متوقع يكون ال ميو
+
+561
+00:59:33,030 --> 00:59:37,850
+هيكون أكبر من
+
+562
+00:59:37,850 --> 00:59:47,310
+P bar minus Z الهي سعة اتنين اللي هي point أربعة
+
+563
+00:59:47,310 --> 00:59:59,250
+ساعة خمسة في SX على جزء التربيهية للان وأصغر
+
+564
+00:59:59,250 --> 01:00:09,480
+من P barزاد زد بونت أربعة تسعة خمسة في Sx عجزة
+
+565
+01:00:09,480 --> 01:00:16,320
+للتربيه للان يعني هكون بي بار اللي هو أربعة بونت
+
+566
+01:00:16,320 --> 01:00:20,360
+او او
+
+567
+01:00:20,360 --> 01:00:28,700
+تمانية ماينوس اتنين point اكم طلعت انا خمسة سبعة
+
+568
+01:00:28,700 --> 01:00:34,310
+خمسة خمسة سبعة خمسةعالجزر التربيه على المية على
+
+569
+01:00:34,310 --> 01:00:41,310
+عشرة صح؟
+
+570
+01:00:41,310 --> 01:00:46,030
+لا أربع point او او تمانية ناقص اتنين point خمسة
+
+571
+01:00:46,030 --> 01:00:51,670
+سبعة خمسة على عشرة زاد زاد
+
+572
+01:00:51,670 --> 01:00:56,430
+في ال SX
+
+573
+01:00:56,430 --> 01:00:57,410
+اللي هي كم؟
+
+574
+01:01:00,000 --> 01:01:08,860
+فى point O أربعتاش ثانى فى point O أربعتاش يعني
+
+575
+01:01:08,860 --> 01:01:12,900
+هتكون لما
+
+576
+01:01:12,900 --> 01:01:17,440
+تحسبوها يعني
+
+577
+01:01:17,440 --> 01:01:26,520
+بمعنى بمعنى ان ال new P هتكون سواء P bar زاد او
+
+578
+01:01:26,520 --> 01:01:36,630
+معاقص زدبنت أربعة تسعة خمسة في SX على N يعني هتكون
+
+579
+01:01:36,630 --> 01:01:45,050
+أربعة بنت O O تمانية زاد او ناقص اتنين بنت خمسة
+
+580
+01:01:45,050 --> 01:01:53,090
+سبعة خمسة في بنت O واحد اربعة عشرة يعني أكتر هتطلع
+
+581
+01:01:53,090 --> 01:02:03,230
+هاي حسبة هو أربعة بنتo o تمانية زادة او ناقص point
+
+582
+01:02:03,230 --> 01:02:10,430
+o o أربعة
+
+583
+01:02:10,430 --> 01:02:17,570
+هيك الصح لأنه
+
+584
+01:02:17,570 --> 01:02:25,290
+مش هتقدر تتخطى ال resolution بتاع الجهاز
+
+585
+01:02:28,730 --> 01:02:34,070
+فأنا أصبح عارف إن ال range تاع ال main أو متوقع
+
+586
+01:02:34,070 --> 01:02:39,550
+range تاع ال main يكون بين يعني هيكون لو ضفت لو
+
+587
+01:02:39,550 --> 01:02:51,430
+طرحت هيكون بين أربعة point O أربعة لحد أربعة أربعة
+
+588
+01:02:51,430 --> 01:02:54,110
+point O
+
+589
+01:02:59,260 --> 01:03:05,140
+واحد اتنين صح ال
+
+590
+01:03:05,140 --> 01:03:13,480
+mean value ال mu هو
+
+591
+01:03:13,480 --> 01:03:17,680
+في البداية حكالي ان ال pressure مش لازم يبعد عن
+
+592
+01:03:17,680 --> 01:03:23,140
+اكتر من واحد في المية يعني point O four معناته
+
+593
+01:03:23,140 --> 01:03:31,540
+النتيجة بتحكيلي انهالامور تمام صح؟ الامور تمام
+
+594
+01:03:31,540 --> 01:03:36,280
+معناته
+
+595
+01:03:36,280 --> 01:03:42,980
+انا ممكن هاد أبرمجها .. أبرمجها مثلا عندي المحطة
+
+596
+01:03:42,980 --> 01:03:49,060
+او عندي .. on inlet pressure بتاع المولد مثلا كل
+
+597
+01:03:49,060 --> 01:03:54,920
+أكم او كل ساعة مثلا ممكن ييجي يحكيلي في مشكلة
+
+598
+01:03:57,580 --> 01:04:02,420
+ال pressure صار out of range بناء على بيكون هو
+
+599
+01:04:02,420 --> 01:04:07,520
+يعمل حسابات احصائية بيكيل out of range فانت فيه
+
+600
+01:04:07,520 --> 01:04:17,140
+مشكلة او بيكون في نظام تغذية راجع بحيث لو في مشكلة
+
+601
+01:04:17,140 --> 01:04:24,620
+انه يعمل عملية موازن موازن زبط الضغط ضغط الغاز
+
+602
+01:04:24,620 --> 01:04:26,100
+البخار
+
+603
+01:04:28,490 --> 01:04:37,170
+طبعا عشان تتحكم ضغط البخار في كذا parameter بس
+
+604
+01:04:37,170 --> 01:04:41,130
+فى النهاية العلم القياسات مش جرد انك تاخد قراءته
+
+605
+01:04:41,130 --> 01:04:48,030
+بس انك تاخد قراءات تقيمها أولا البيانات بعدين
+
+606
+01:04:48,030 --> 01:04:52,930
+تعرضها و تستخرج منها بناء على استخراج بنات تتخذ
+
+607
+01:04:52,930 --> 01:04:59,320
+قرارات هى الهدف من القراءة القياساتاليوم يكون خلصت
+
+608
+01:04:59,320 --> 01:05:00,340
+لحد هنا أطيك ولا عافية
+
diff --git a/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/Fq8QFRjoBlk_raw.srt b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/Fq8QFRjoBlk_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..08f5238c612c897a06f8ed90fa28e6ecb66332fd
--- /dev/null
+++ b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/Fq8QFRjoBlk_raw.srt
@@ -0,0 +1,2468 @@
+1
+00:00:04,990 --> 00:00:07,730
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:07,730 --> 00:00:12,870
+وبركاته، هنكمل في مادة القياصات، احنا بدأنا بشبطة
+
+3
+00:00:12,870 --> 00:00:16,610
+بـmeasurement of flow ده flow، هنعمل مراجعة سريعة
+
+4
+00:00:16,610 --> 00:00:22,420
+للمحاضرة اللي راحت ونكمل ان شاء اللهاحنا حاكي هنا
+
+5
+00:00:22,420 --> 00:00:25,800
+ال .. ال flow measurement methods، فيه ال quantity
+
+6
+00:00:25,800 --> 00:00:29,640
+methods، ال flow meters عند ال ballistic props و
+
+7
+00:00:29,640 --> 00:00:32,860
+عند ال flow visualization techniques، في ال flow
+
+8
+00:00:32,860 --> 00:00:35,760
+measurement .. في ال quantity methods we use ال
+
+9
+00:00:35,760 --> 00:00:39,610
+weight tanks و ال volume graduated cylindersفي ال
+
+10
+00:00:39,610 --> 00:00:42,570
+.. في ال flow meter method we use obstruction
+
+11
+00:00:42,570 --> 00:00:46,910
+meters زي الفنشوري، الارفس و ال .. و ال flow
+
+12
+00:00:46,910 --> 00:00:50,170
+nozzles في عندنا في ال volume flow meters زي ال
+
+13
+00:00:50,170 --> 00:00:53,350
+turbines و ال propeller meters و ال mass flow
+
+14
+00:00:53,350 --> 00:00:59,120
+meters زي كوريولوس metersال Velocity Props في منها
+
+15
+00:00:59,120 --> 00:01:03,420
+pressure props يعني hot wire و hot film anometer و
+
+16
+00:01:03,420 --> 00:01:09,260
+double shift method و particle image velocimetry
+
+17
+00:01:09,260 --> 00:01:14,000
+ال flow visualization techniques عشان نشوف ال flow
+
+18
+00:01:14,000 --> 00:01:18,380
+ممكن نستخدم الدخان الملون أو الأحبار أو ال
+
+19
+00:01:18,380 --> 00:01:21,480
+hydrogen bubbles أو ال laser أو refractive index
+
+20
+00:01:21,480 --> 00:01:22,080
+change
+
+21
+00:01:24,660 --> 00:01:27,780
+بالنفس ال flow characteristics we define ال mass
+
+22
+00:01:27,780 --> 00:01:32,740
+flow rate ρ في q ال velocity ل ال flow هتكون اللي
+
+23
+00:01:32,740 --> 00:01:36,320
+هي ال mass flow rate على ρ في q اللي هي q على a
+
+24
+00:01:36,320 --> 00:01:40,900
+هكذا ال flow ممكن ال flow السيابي ال laminar او
+
+25
+00:01:40,900 --> 00:01:45,840
+flow عشوائي اللي هو مخربط ال turbulent بيكون ال
+
+26
+00:01:45,840 --> 00:01:50,590
+flow laminar اذا كان Reynolds number اقل من 2000و
+
+27
+00:01:50,590 --> 00:01:54,030
+بيكون turbulent إذا بيكون ال Reynolds number أكبر
+
+28
+00:01:54,030 --> 00:01:57,470
+من 2000 الشكل اللي انتوا شايفينه و موارجينه اللي
+
+29
+00:01:57,470 --> 00:02:01,070
+هو ال velocity profile في حالة الunderflow و ال
+
+30
+00:02:01,070 --> 00:02:04,350
+velocity profile في حالة ال turbulent flow ال
+
+31
+00:02:04,350 --> 00:02:07,710
+Reynolds number هو عبارة عن ال ratio بين inertia
+
+32
+00:02:07,710 --> 00:02:13,980
+forces و viscous forcesمع طول اللقاء رو VD على ميو
+
+33
+00:02:13,980 --> 00:02:18,780
+هو dimension of this number دي القطر الإنبوب ال V
+
+34
+00:02:18,780 --> 00:02:24,200
+صورة ال flow ال رو اللي هي ال density لل fluid و
+
+35
+00:02:24,200 --> 00:02:28,580
+ال ميو اللي هي ال viscosity لل fluidعرفنا الـ
+
+36
+00:02:28,580 --> 00:02:32,320
+Hydraulic Diameter DH في حالة المقطع ماكانش مدور
+
+37
+00:02:32,320 --> 00:02:38,380
+4A على B ال A اللي هي مساحة المقطع و ال P هي ال
+
+38
+00:02:38,380 --> 00:02:44,370
+parameter of duct R بيبقى حلينا exampleال flow
+
+39
+00:02:44,370 --> 00:02:49,690
+rate خلال نبوب معطوة بالعلاقة ال integral v of x y
+
+40
+00:02:49,690 --> 00:02:53,990
+d a و بعدين حكينا عن بيرنولي equation for
+
+41
+00:02:53,990 --> 00:02:56,690
+incompressible flow في حالة flow ال density بتكون
+
+42
+00:02:56,690 --> 00:03:01,530
+فيه ثابتة بتكون ال total energy constant او ال
+
+43
+00:03:01,530 --> 00:03:04,330
+total energy conserved على فرض ان في losses يعني
+
+44
+00:03:04,330 --> 00:03:06,810
+هيكون عندها في pressure energy في عندها kinetic
+
+45
+00:03:06,810 --> 00:03:10,340
+energyو فيعندي potential energy يعني في واحد زياد
+
+46
+00:03:10,340 --> 00:03:14,320
+نص رابعي واحد square زياد راجعي واحد سواء P2 زياد
+
+47
+00:03:14,320 --> 00:03:17,480
+نص رابعي two square زياد راجعي H2
+
+48
+00:03:20,360 --> 00:03:23,480
+ال .. بدأنا نحكي عن ال obstruction meters for
+
+49
+00:03:23,480 --> 00:03:27,140
+incompressible flow فين الفنشورة U يعني ال flow
+
+50
+00:03:27,140 --> 00:03:33,580
+نزل و ال orifice flow meter عملنا استخدمنا ال ..
+
+51
+00:03:33,580 --> 00:03:36,160
+بغض النظر على النوع ال obstruction meter سواء كان
+
+52
+00:03:36,160 --> 00:03:40,760
+فنشور او نزل او orifice استخدمنا بالنوع ال
+
+53
+00:03:40,760 --> 00:03:44,490
+equation between two sections section one and twoو
+
+54
+00:03:44,490 --> 00:03:49,550
+جبنا علاقة بين اللي هو ال .. ال .. ال pressure
+
+55
+00:03:49,550 --> 00:03:55,010
+difference و ال flow rate Q actual بستوى K A2 جزر
+
+56
+00:03:55,010 --> 00:04:01,230
+التربيعي ل Delta V على روه ال K اللي هو ال flow
+
+57
+00:04:01,230 --> 00:04:04,430
+coefficient بستوى C في E ال C اللي هي ال discharge
+
+58
+00:04:04,430 --> 00:04:09,090
+coefficient ال E فلسه approach coefficient و ال E
+
+59
+00:04:09,090 --> 00:04:12,170
+بستوى واحد على جزر التربيعي لواحد ناقص ب Beta أقصى
+
+60
+00:04:12,170 --> 00:04:16,660
+أربعةBeta هي ال ratio بين ال D الصغير D small على
+
+61
+00:04:16,660 --> 00:04:18,200
+D capital
+
+62
+00:04:22,850 --> 00:04:27,750
+بدأنا في الفنشوري تيوب واضح انه زي ما في الصورة ان
+
+63
+00:04:27,750 --> 00:04:31,010
+في فرق بين position one و position two بيصير ان دي
+
+64
+00:04:31,010 --> 00:04:37,230
+pressure drop قيمته delta B عرفنا ال geometric
+
+65
+00:04:37,230 --> 00:04:40,450
+parameters و ال constraints بتاعتها اللي في حالة
+
+66
+00:04:40,450 --> 00:04:46,710
+الفنشوري metersهو و ال equations او ال typical
+
+67
+00:04:46,710 --> 00:04:53,450
+range of c values تعتمد على ال .. ال .. ال .. ال
+
+68
+00:04:53,450 --> 00:04:58,470
+range بتاع ال D و ال range بتاع ال beta و ال range
+
+69
+00:04:58,470 --> 00:05:03,010
+بتاع رونالدز number و ال .. و طريقة او كيف صنع ..
+
+70
+00:05:03,010 --> 00:05:05,810
+كيف صنع اللي هو ال venture و اللي ممكن يكون as
+
+71
+00:05:05,810 --> 00:05:09,370
+cast او machined او يعني ممكن يكون sheet metal
+
+72
+00:05:09,370 --> 00:05:10,430
+ملحقة مثل الحين
+
+73
+00:05:15,200 --> 00:05:19,180
+لأ حد هنا وصلنا لان اليوم هنحكي عن ال flow nozzle
+
+74
+00:05:19,180 --> 00:05:28,020
+الشكل المبين عنده في عنده انبوب لان ركبت عشان أقيص
+
+75
+00:05:28,020 --> 00:05:33,740
+ال flow ركبت ما يسمى nozzle، nozzle هاي شكلهافعين
+
+76
+00:05:33,740 --> 00:05:40,320
+دي هين القطر بيكون D capital و هين H D small و I
+
+77
+00:05:40,320 --> 00:05:43,440
+major ال pressure ال difference بين position واحد
+
+78
+00:05:43,440 --> 00:05:45,840
+و position اتنين طبعا ال pressure عند واحد اعلى من
+
+79
+00:05:45,840 --> 00:05:50,240
+ال pressure عند اتنين و الصراع عند واحد اقل من
+
+80
+00:05:50,240 --> 00:05:54,800
+الصراع عند اتنين و مساحة المقطع عند واحد اكبر من
+
+81
+00:05:54,800 --> 00:06:03,100
+مساحة المقطع عند اتنين طبعا نرجع للعقل الأساسية
+
+82
+00:06:04,680 --> 00:06:08,480
+اللي هي هتكون في كل حوار الـ Q actual بيستوى اللي
+
+83
+00:06:08,480 --> 00:06:14,720
+هو K A to الجزر الترويه على Delta P على روه
+
+84
+00:06:20,040 --> 00:06:24,980
+النوزل لها تفاصيل الجيومتري بتاعتها ال figure خمسة
+
+85
+00:06:24,980 --> 00:06:28,100
+بورجين ال dimensional relations for standard long
+
+86
+00:06:28,100 --> 00:06:32,500
+radius flow nozzles a هذا a اللي هو high ratio
+
+87
+00:06:32,500 --> 00:06:37,720
+يعني هذا الشكل أو تفاصيل الجيومتري بتاعت النوزل في
+
+88
+00:06:37,720 --> 00:06:40,820
+حالة ال beta كانت بين point اتنين خمسة و point
+
+89
+00:06:40,820 --> 00:06:46,160
+تمانية شكل بقى في حالة كان ال beta بين point two و
+
+90
+00:06:46,160 --> 00:06:50,040
+نصفي الحالة الأولى عندى هى القطر بتاع النبوب دى ال
+
+91
+00:06:50,040 --> 00:06:55,940
+capital هى الأصغر قطر في النزل دى small والمقطع
+
+92
+00:06:55,940 --> 00:07:04,280
+هدا هى نجاى elliptical ومعطيل التفاصيل هدا T2 وهد
+
+93
+00:07:04,280 --> 00:07:09,920
+T وهد DR على 2 وهد اللى هو
+
+94
+00:07:13,670 --> 00:07:20,330
+دى capital minus دى على اتنين طبعا الان في حالة
+
+95
+00:07:20,330 --> 00:07:26,360
+سواء الان بتكون عندى T اتنينfor beta من 2 من 10 من
+
+96
+00:07:26,360 --> 00:07:30,600
+نص ال T2 بتكون بين تلاتة ملي و point واحد في خمسة
+
+97
+00:07:30,600 --> 00:07:37,700
+دي capital و ال T بتكون أكبر أو ساوية تلاتة ملي في
+
+98
+00:07:37,700 --> 00:07:41,880
+حالة كان ال D capital أكبر من خمس ستين other wise
+
+99
+00:07:41,880 --> 00:07:47,320
+يعني كان خمس ستين بتكون ال T أقلش اتنين ملي هذا
+
+100
+00:07:47,320 --> 00:07:53,460
+شكل ايه الشكل بيه في اختلاف بس و التفاصيل من بينها
+
+101
+00:08:01,860 --> 00:08:06,780
+الان ال approach curve طبعا ال .. ال geometry هذه
+
+102
+00:08:06,780 --> 00:08:10,440
+معمولة بدقة و مدروسة بحيث ان ال approach curve
+
+103
+00:08:10,440 --> 00:08:14,960
+must be proportioned to prevent separation between
+
+104
+00:08:14,960 --> 00:08:20,820
+the flow and wall بدناش يصير السائل يفصل عن
+
+105
+00:08:20,820 --> 00:08:24,420
+الجدران فال geometry هذه معمولة بحيث دايما تكون
+
+106
+00:08:24,420 --> 00:08:28,620
+المي أو السائل ملاسق للجدران الجدران
+
+107
+00:08:31,400 --> 00:08:34,380
+في جزء برضه في عندى parallel section في جزء هنا
+
+108
+00:08:34,380 --> 00:08:39,020
+مافيش فيه curvature parallel و هنا فيه جزء
+
+109
+00:08:39,020 --> 00:08:44,500
+parallel ال parallel section عشان نتأكد ان ال flow
+
+110
+00:08:44,500 --> 00:08:48,640
+fills the throat انه ال liquid معبق العنق يكون
+
+111
+00:08:48,640 --> 00:08:54,340
+معبق بشكل كاملالان this charge coefficient can be
+
+112
+00:08:54,340 --> 00:08:59,100
+calculated to an uncertainty of 2% من خلال علاقة
+
+113
+00:08:59,100 --> 00:09:07,740
+هذه C So point 9965-6.53 في الجزر التربيعي ل Beta
+
+114
+00:09:07,740 --> 00:09:12,520
+around number d d small يعني around number عند
+
+115
+00:09:12,520 --> 00:09:17,600
+المقطع الصغير و
+
+116
+00:09:17,600 --> 00:09:23,250
+Beta تتراوح بين point 2و point تمانية و rollings
+
+117
+00:09:23,250 --> 00:09:27,150
+number عند في الأول upstream عندك capital تتراوح
+
+118
+00:09:27,150 --> 00:09:34,110
+بين عشرة أقصر أربعة و عشرة سبعة الشكل
+
+119
+00:09:34,110 --> 00:09:41,350
+هذا او الفكرة ده مرجين العلاقة بين rollings number
+
+120
+00:09:41,350 --> 00:09:46,610
+و ال discharge coefficient C يعني يعطينا ال
+
+121
+00:09:46,610 --> 00:09:50,170
+typical range ل C
+
+122
+00:09:55,250 --> 00:09:58,490
+النوع التالت اللي هو orifice meter، ال orifice
+
+123
+00:09:58,490 --> 00:10:06,310
+meter بيكون في عندي هي plate و في فتحين، في فتحة
+
+124
+00:10:06,310 --> 00:10:12,270
+الفلو طبعا بيكون جاي لازم الفلو هيصطدم في المنطقة
+
+125
+00:10:12,270 --> 00:10:15,960
+هذه، هذا مسكر المنطقة و في المنطقة هذهمعناته اذا
+
+126
+00:10:15,960 --> 00:10:20,720
+هى اصطدم انا عملته وصلت ال liquid ده ال stagnation
+
+127
+00:10:20,720 --> 00:10:23,580
+لحالة السكو معناته الدغط فى المنطقة ده ايش هيعلى
+
+128
+00:10:23,580 --> 00:10:28,520
+شوية اللحظه يعنى ايش بيصير بيعلى شوية بعدين يعني
+
+129
+00:10:28,520 --> 00:10:37,940
+position two بنزل بيصير pressure drop طيب
+
+130
+00:10:37,940 --> 00:10:45,640
+الان الشكل المقطععندي هاي ال plate ال plate فيه
+
+131
+00:10:45,640 --> 00:10:50,280
+ثقوب قطر ثقوب D small و هذا القطر الأساسي للانبوبة
+
+132
+00:10:50,280 --> 00:10:52,520
+الكبيرة اللي بدها كي تصلي flow فيها اللي هي D
+
+133
+00:10:52,520 --> 00:11:00,640
+capital و في عندي هنا نوعين ممكن يكون ال .. ممكن
+
+134
+00:11:00,640 --> 00:11:07,620
+يكون ال orifice flow meterالفتحات .. الفتحات قبل
+
+135
+00:11:07,620 --> 00:11:12,380
+.. قبل و بعد تكون corner tabs يعني ما جايب mail
+
+136
+00:11:12,380 --> 00:11:18,910
+هذا قبل و بعداو عدل جاية flange tabs هي فيه فتحين
+
+137
+00:11:18,910 --> 00:11:26,170
+و فتحين قبل و بعد ال place سماكته T بيكون هنا برضه
+
+138
+00:11:26,170 --> 00:11:31,450
+مشطوف شطف بزاوية خمسة و أربعين درجة معطين مسافات
+
+139
+00:11:31,450 --> 00:11:38,210
+بين .. بين عندي اللي هو D يعني من الفتحة هذه اللي
+
+140
+00:11:38,210 --> 00:11:45,020
+هي هذه واحد و هذه إيشإتنين لإني عند دي capital دي
+
+141
+00:11:45,020 --> 00:11:50,440
+capital على اتنين دي and دي على اتنين tab يعني هم
+
+142
+00:11:50,440 --> 00:11:54,540
+يعطيينك والي geometric parameters للمواقع الفاتحة
+
+143
+00:11:58,600 --> 00:12:04,700
+الان في حالة ال .. ال office flow meter بيكونش
+
+144
+00:12:04,700 --> 00:12:10,740
+مقطع اللي هو ال liquid بيكون .. بيكونش مساوي ليش
+
+145
+00:12:10,740 --> 00:12:17,740
+لقطر الفتحة، بيكون أصغر شوية، بيكون أصغر شوية،
+
+146
+00:12:17,740 --> 00:12:20,740
+بيكونش هذا بالظبط، يعني .. بيكونش philosopher،
+
+147
+00:12:20,740 --> 00:12:24,500
+فبيكون أصغر شوية، بتعمل ما يسمى اللي هو .. اللي هو
+
+148
+00:12:24,500 --> 00:12:28,960
+vena contract، بتعمل زي ..متعلق أو في عندي عنق
+
+149
+00:12:28,960 --> 00:12:36,200
+أصغر من القطر هذا سموه فينا contractor طيب
+
+150
+00:12:38,680 --> 00:12:43,420
+تكون ال vena contracta ان هو القطر ال section بتاع
+
+151
+00:12:43,420 --> 00:12:48,760
+ال flow الحقيقي يكون اصغر من فتحة ال orifice is
+
+152
+00:12:48,760 --> 00:12:52,280
+sensitive to the shape of the orifice يعني بتأثر
+
+153
+00:12:52,280 --> 00:12:57,460
+بشكل الفتحة يعني لو كانت الفتحة عدل
+
+154
+00:13:08,650 --> 00:13:18,590
+هذه الارفس بختلف
+
+155
+00:13:18,590 --> 00:13:19,310
+لو كان
+
+156
+00:13:43,530 --> 00:13:51,050
+في شطفة هنا بالزاوية 45 فحساس ده شكل الارفس
+
+157
+00:13:54,060 --> 00:13:58,880
+ال downstream phase طبعا هذا upstream و هذا ايش
+
+158
+00:13:58,880 --> 00:14:05,540
+downstream ال downstream phase ال face هذا لازم
+
+159
+00:14:05,540 --> 00:14:10,580
+يكون في عندى شطفة خمسة و أربعين درجة اذا كان ال
+
+160
+00:14:10,580 --> 00:14:13,100
+plate thickness اكبر من اتنين في المية من ال pipe
+
+161
+00:14:13,100 --> 00:14:18,380
+diameter يعني هذا دي capital و
+
+162
+00:14:18,380 --> 00:14:29,880
+هذا thickness T اذا ال T كان اكبرمن 2% من ال D
+
+163
+00:14:29,880 --> 00:14:46,080
+capital لازم تعمل 45 degrees شانفر طبعا
+
+164
+00:14:46,080 --> 00:14:47,920
+ال discharge coefficient
+
+165
+00:14:50,530 --> 00:14:55,690
+الـ C مُعطُل على القدر في حتة ال office flowmeter
+
+166
+00:14:55,690 --> 00:15:03,210
+بالسواء point 956 1 زي point O261 beta تربيع minus
+
+167
+00:15:03,210 --> 00:15:10,440
+point 216 beta أقصى تمانيةزائد point o o o خمس
+
+168
+00:15:10,440 --> 00:15:14,480
+اتنين واحد في عشر عقل ستة beta على round number D
+
+169
+00:15:14,480 --> 00:15:19,260
+capital أُس point seven زائد point zero one eight
+
+170
+00:15:19,260 --> 00:15:22,540
+eight زائد point zero zero ست تلاتة a في beta أُس
+
+171
+00:15:22,540 --> 00:15:26,520
+تلاتة و نص في عشر عقل ستة على round number D أُس
+
+172
+00:15:26,520 --> 00:15:31,080
+تلاتة وال a مُعطل علاقة تسعتاشر ألف في beta على
+
+173
+00:15:31,080 --> 00:15:34,720
+round number D capital أُس point تمانية طبعا ال
+
+174
+00:15:34,720 --> 00:15:38,730
+beta اللي هي D small علىD capital و ال beta تتراوح
+
+175
+00:15:38,730 --> 00:15:42,390
+بين point واحد point سبعة خمسة و runs number D
+
+176
+00:15:42,390 --> 00:15:45,690
+أكبر أو يستوى خمس تلاف for beta أقل أو يستوى point
+
+177
+00:15:45,690 --> 00:15:50,330
+خمسة ستة و بالساوة ستاشر ألف beta تربيع في حالة
+
+178
+00:15:50,330 --> 00:15:54,650
+كانت beta أكبر من point خمسة ستة إذا كانت ال D و
+
+179
+00:15:54,650 --> 00:15:59,590
+ال D D small أكبر أو يستوى اتناشر مصملة و ال D
+
+180
+00:15:59,590 --> 00:16:02,130
+capital تتراوح بين واحد سبعين point واحد اتنين
+
+181
+00:16:02,130 --> 00:16:06,980
+مليمتر و الف مليمترهذه المعادلة .. هذه ال .. يعني
+
+182
+00:16:06,980 --> 00:16:13,020
+ال constraints أو حدود تطبيق هذه المعادلة هنا
+
+183
+00:16:13,020 --> 00:16:14,960
+الشكل المرجيني ال .. ال .. ال discharge
+
+184
+00:16:14,960 --> 00:16:18,860
+coefficient as a function of Reynolds number or
+
+185
+00:16:18,860 --> 00:16:26,180
+different values of beta طبعا
+
+186
+00:16:26,180 --> 00:16:33,270
+لأن المنطقة هذه .. هذه ال flow بستخدم دي هنافي
+
+187
+00:16:33,270 --> 00:16:36,410
+pressure وهنا في حاجة تصير بالبنطقة هذه maximum
+
+188
+00:16:36,410 --> 00:16:39,530
+bending maximum bending كأنه انت كأنه كأنه كنت
+
+189
+00:16:39,530 --> 00:16:44,870
+liver هكون maximum bending هنا هصير bending او
+
+190
+00:16:44,870 --> 00:16:49,860
+stress sigma maximumمعطوة العلاقة اللي هي انت
+
+191
+00:16:49,860 --> 00:16:52,020
+شايفيها ال maximum normal stress due to بنج بيسي
+
+192
+00:16:52,020 --> 00:16:55,740
+عنديه هذا بنج بيعمل normal stress يعني هي بيعمل
+
+193
+00:16:55,740 --> 00:16:59,960
+tension و تحت compression فهتكون ال sigma maximum
+
+194
+00:16:59,960 --> 00:17:05,710
+سواء F D Square Delta P على T Squareالـ D اللي هي
+
+195
+00:17:05,710 --> 00:17:08,370
+ال pipe diameter و ال delta P ال pressure
+
+196
+00:17:08,370 --> 00:17:12,110
+difference before اللي هو between ال upstream و ال
+
+197
+00:17:12,110 --> 00:17:17,790
+downstream و ال T ال plate thickness و ال F factor
+
+198
+00:17:17,790 --> 00:17:22,590
+ال value بتعتمد بتاعته على ال beta يعني ال F is a
+
+199
+00:17:22,590 --> 00:17:27,370
+function of beta نشوف
+
+200
+00:17:27,370 --> 00:17:27,870
+مثال
+
+201
+00:17:40,410 --> 00:17:44,190
+an orifice with corner tabs is placed into a
+
+202
+00:17:44,190 --> 00:17:47,930
+horizontal 200 millimeter diameter line في عندى
+
+203
+00:17:47,930 --> 00:18:02,570
+هاي عندى انبوب وانا حاطط orifice هذا
+
+204
+00:18:02,570 --> 00:18:06,510
+دي small وهذا
+
+205
+00:18:06,510 --> 00:18:18,870
+ديالدي كابيتل هو هاي ال flow الدي كابيتل متين ملي
+
+206
+00:18:18,870 --> 00:18:19,370
+متر
+
+207
+00:18:24,430 --> 00:18:28,630
+that carries thirty liters per second of water
+
+208
+00:18:28,630 --> 00:18:33,590
+يعني ال Q ال Q مش الأمدات اللي قاعدة volume of
+
+209
+00:18:33,590 --> 00:18:41,790
+الاريات بالساوية تلاتين liter per second المتر
+
+210
+00:18:41,790 --> 00:18:49,610
+مكعب أكم لتر فيه ألف اللي هتكون point O تلاتة متر
+
+211
+00:18:49,610 --> 00:18:53,250
+مكعب per second
+
+212
+00:18:58,070 --> 00:19:00,330
+if the throat diameter is one hundred twenty
+
+213
+00:19:00,330 --> 00:19:04,970
+millimeter يعني دي small سواء مية و عشرين
+
+214
+00:19:04,970 --> 00:19:09,250
+millimeter
+
+215
+00:19:09,250 --> 00:19:12,970
+what differential pressure may be expected across
+
+216
+00:19:12,970 --> 00:19:16,210
+the pressure terms إداش الفرق والضغط before and
+
+217
+00:19:16,210 --> 00:19:23,650
+after يعني بده delta P و
+
+218
+00:19:23,650 --> 00:19:25,010
+ال temperature بيعطينا إياها
+
+219
+00:19:27,860 --> 00:19:35,140
+عشرين درجة درجة درجة درجة درجة درجة درجة درجة درجة
+
+220
+00:19:35,140 --> 00:19:35,220
+درجة درجة درجة درجة درجة درجة درجة درجة درجة درجة
+
+221
+00:19:35,220 --> 00:19:35,380
+درجة درجة درجة درجة درجة درجة درجة درجة درجة درجة
+
+222
+00:19:35,380 --> 00:19:35,380
+درجة درجة درجة درجة درجة درجة درجة درجة درجة درجة
+
+223
+00:19:35,380 --> 00:19:35,920
+درجة درجة درجة درجة درجة درجة درجة درجة درجة درجة
+
+224
+00:19:35,920 --> 00:19:38,780
+درجة درجة درجة درجة درجة درجة درجة درجة درجة درجة
+
+225
+00:19:38,780 --> 00:19:43,540
+درجة درجة درجة درجة
+
+226
+00:19:43,540 --> 00:19:57,020
+درجة درجة درجة درجة درجة درجة درجة درجة درجة درجة
+
+227
+00:19:57,020 --> 00:20:14,410
+درججزر اتنين دلتا بي على رق صح هذه Q actual يعني
+
+228
+00:20:14,410 --> 00:20:25,810
+لو ربع جهتين هيكون دي Q actual تربيع على K تربيع
+
+229
+00:20:29,540 --> 00:20:36,020
+A2 تربيع بتساوي
+
+230
+00:20:36,020 --> 00:20:48,300
+اتنين Delta P على رو معناه Delta P هيكون
+
+231
+00:20:48,300 --> 00:21:04,250
+رو Q actual تربيععلى اتنين كتربيع في اتنين تربيع
+
+232
+00:21:04,250 --> 00:21:08,670
+الان هنبدأ واحد واحد انا عندى ال temperature
+
+233
+00:21:08,670 --> 00:21:14,130
+المعروفة من ال tables بطلع اللى هى اياش ال density
+
+234
+00:21:14,130 --> 00:21:16,890
+من ال tables
+
+235
+00:21:27,430 --> 00:21:30,570
+بطلع ال density و ال viscosity بطلع من from tables
+
+236
+00:21:30,570 --> 00:21:40,590
+at T equal عشرين درجة أوية بطلع روح تطلع من تسعة
+
+237
+00:21:40,590 --> 00:21:50,750
+تسعة تمانية واحد اتنين kilogram على متر مكعب و ال
+
+238
+00:21:50,750 --> 00:21:54,950
+viscosity تطلع عشرة point او خمسة
+
+239
+00:22:01,480 --> 00:22:10,140
+بسكال ثانية يعني
+
+240
+00:22:10,140 --> 00:22:20,560
+صارت عند رو معروفة و ال Q معروفة ال K شو الساوية
+
+241
+00:22:20,560 --> 00:22:24,420
+ال
+
+242
+00:22:24,420 --> 00:22:27,580
+K بالساوية CE
+
+243
+00:22:31,110 --> 00:22:38,550
+C E و ال E شو يساوي بس
+
+244
+00:22:38,550 --> 00:22:46,330
+واحد ع الجزر التربيعي ل واحد minus beta أربعة صح
+
+245
+00:22:46,330 --> 00:22:51,270
+طيب Beta شو يساوي
+
+246
+00:22:54,590 --> 00:23:00,110
+b تستوى d small ع d capital يعني هتكون مية و عشرين
+
+247
+00:23:00,110 --> 00:23:08,930
+على ميتين يعني تطلع ستة من عشرة يعني
+
+248
+00:23:08,930 --> 00:23:18,350
+a هتكون بتساوي واحد ع الجزر التربيعي لوحد ناقص ستة
+
+249
+00:23:18,350 --> 00:23:20,330
+من عشرة قص أربعة
+
+250
+00:23:27,440 --> 00:23:36,460
+هذه النسبة ل A الان بدنا C ال
+
+251
+00:23:36,460 --> 00:23:40,220
+C معتبر
+
+252
+00:23:40,220 --> 00:23:53,780
+علاقة point خمسة تسعة ستة واحدزاد point او نين ستة
+
+253
+00:23:53,780 --> 00:23:58,000
+واحد beta تربيع
+
+254
+00:23:58,000 --> 00:24:07,880
+minus point اتنين زاد
+
+255
+00:24:07,880 --> 00:24:16,560
+point او خمس
+
+256
+00:24:16,560 --> 00:24:24,170
+اتنين واحدضرب عشرة او ستة ضرب عشرة او ستة beta على
+
+257
+00:24:24,170 --> 00:24:32,490
+رنز number دي capital او السبعة من عشرة اسم السبعة
+
+258
+00:24:32,490 --> 00:24:44,830
+من عشرة زائد زائد point o واحد تمانية تمانية زائد
+
+259
+00:24:44,830 --> 00:24:46,150
+point o او ستة
+
+260
+00:24:51,880 --> 00:24:59,300
+وست تلاتة في ايه
+
+261
+00:24:59,300 --> 00:25:07,540
+ساكر القوس بيتا اقص تلاتة و نص ضرب
+
+262
+00:25:07,540 --> 00:25:17,020
+عشر اقص ستة عرين number دي كابيتال اقص تلاتة و عشر
+
+263
+00:25:24,710 --> 00:25:30,390
+احنا بيتها already عارفين دي نحسب رولز نامبر رولز
+
+264
+00:25:30,390 --> 00:25:34,030
+نامبر رولز
+
+265
+00:25:34,030 --> 00:25:48,390
+نامبر صاروا V دي كابيتل على U طب ال flow احنا ال
+
+266
+00:25:48,390 --> 00:25:52,490
+flow ايش السبب عندي ال Q
+
+267
+00:26:00,310 --> 00:26:09,750
+بتساوى V واحد A واحد و
+
+268
+00:26:09,750 --> 00:26:17,370
+برضه بساوى V اتنين A اتنين احنا هذا عند ال D هذا V
+
+269
+00:26:17,370 --> 00:26:24,920
+عند ال D يعني هذا هتكون واحد يعني هتكون V واحدQ
+
+270
+00:26:24,920 --> 00:26:38,080
+على A واحد يعني هتكون أربع Q على باي دي capital
+
+271
+00:26:38,080 --> 00:26:48,620
+تربيع صح؟ هنعوض هنا هتسكور number بالساعة رو يعني
+
+272
+00:26:48,620 --> 00:26:52,300
+هضرب أربع رو
+
+273
+00:26:53,910 --> 00:26:59,130
+اكيو دي
+
+274
+00:26:59,130 --> 00:27:06,350
+على باي
+
+275
+00:27:06,350 --> 00:27:12,090
+دي كوتل سكوير فين بيو هي انها هتكون ال result
+
+276
+00:27:12,090 --> 00:27:16,030
+number هتكون
+
+277
+00:27:16,030 --> 00:27:22,110
+تساوي اربع رو اكيو على باي
+
+278
+00:27:28,310 --> 00:27:35,590
+DMU يعني هتكون اربعة تسعة تسعة تمانية point اتنين
+
+279
+00:27:35,590 --> 00:27:41,390
+في Q اللي هي point O تلاتة
+
+280
+00:27:41,390 --> 00:27:47,570
+على باي دي اللي هي متامة يعني اتنين من عشرة و
+
+281
+00:27:47,570 --> 00:27:56,850
+الميواللي عشرة point O خمسة عشرة السالب أربعة
+
+282
+00:27:56,850 --> 00:28:07,690
+ومنها بحسب runs number هيطلع
+
+283
+00:28:07,690 --> 00:28:13,850
+كبير يعني طيب هذا runs number هيلزم نحسب كمان ال A
+
+284
+00:28:19,830 --> 00:28:29,650
+ال A capital هتكون اللي هي تسعتاشر الف في بيته على
+
+285
+00:28:29,650 --> 00:28:38,570
+نزل number D capital أس تمانية من عشرة يعني هتكون
+
+286
+00:28:38,570 --> 00:28:47,190
+عنده تسعتاشر الف في ضارف ستة من عشرة على نزل
+
+287
+00:28:47,190 --> 00:28:48,830
+number حسفتوا ليه أكم بطلع؟
+
+288
+00:28:57,350 --> 00:29:04,930
+على واحد point تسعة تمانية تسعة سبعة عشرة أس خمسة
+
+289
+00:29:04,930 --> 00:29:09,410
+كل أس تمانية من عشرة
+
+290
+00:29:29,000 --> 00:29:35,020
+احنا الرقم معروف والـ Q معروف علنا حسبنا
+
+291
+00:29:35,020 --> 00:29:45,520
+ال A ال E أكا نطلع فعلا point
+
+292
+00:29:45,520 --> 00:29:58,020
+O واحد ستة تمانية هذا ال A و ال A capital واحد
+
+293
+00:29:58,020 --> 00:29:58,380
+point
+
+294
+00:30:01,520 --> 00:30:08,080
+سبعة اتنين ايه بنحسب ال K؟معناته
+
+295
+00:30:08,080 --> 00:30:12,420
+ال K هتكون
+
+296
+00:30:12,420 --> 00:30:18,120
+ال C ماحسنش ال C ..معناته هنعوض يعني في ال C عوض
+
+297
+00:30:18,120 --> 00:30:27,380
+عن ..عوض عن Beta ورنز دانبر و A بتحسب ايه؟ ال C و
+
+298
+00:30:27,380 --> 00:30:36,380
+من ال C بنحسب ال Kالان ال a2 ايش تساوي ال a2 ال a2
+
+299
+00:30:36,380 --> 00:30:44,540
+مساحة a2 سواء باي على اربعة دي تربيع small انا
+
+300
+00:30:44,540 --> 00:30:51,960
+هكون باي على اربعة في point واحد اتنين تربيع
+
+301
+00:31:12,710 --> 00:31:20,230
+بوينت زيرو كمان رقم متر
+
+302
+00:31:20,230 --> 00:31:21,870
+مربع
+
+303
+00:31:33,050 --> 00:31:41,090
+طيب خلاص بعدها هتحسب delta P هتعوض عن ال row ال
+
+304
+00:31:41,090 --> 00:31:47,230
+row اللي هي تسعة تسعة تمانية point اتنين في point
+
+305
+00:31:47,230 --> 00:31:50,790
+O تلاتة
+
+306
+00:31:50,790 --> 00:32:01,110
+على اتنين تعوض و تضرب في K في A2 اللي هي point O
+
+307
+00:32:05,940 --> 00:32:12,780
+وبينها بتحسب ال delta P هو ال pressure difference
+
+308
+00:32:12,780 --> 00:32:18,200
+المتوقع ايش بتفيد المعلومة هذه؟ انا بعمل تجربة
+
+309
+00:32:18,200 --> 00:32:22,860
+بشوف حالة ان والله انا بعيد ولا قريب يعني مبين في
+
+310
+00:32:22,860 --> 00:32:28,420
+زي عندى خلل او ماهوش عندى خلل فهذه بتكون زي توكيد
+
+311
+00:32:28,420 --> 00:32:32,560
+على الدقة او ال test على الشغل تبعي على التجربة
+
+312
+00:32:32,560 --> 00:32:32,960
+تاعتى
+
+313
+00:32:40,700 --> 00:32:48,140
+طب لو بدى اعملها ع شكل excel sheet لو
+
+314
+00:32:48,140 --> 00:32:51,360
+بدى اعملها ع شكل excel sheet عشان نشوف ايش اول شي
+
+315
+00:32:51,360 --> 00:33:00,860
+حسبناها نتسلسل احنا اول شي هي ال temperature صح؟
+
+316
+00:33:00,860 --> 00:33:04,200
+شورتني لها ال temperature طلعناها يعني
+
+317
+00:33:09,800 --> 00:33:14,200
+ال temperature طلعنا
+
+318
+00:33:14,200 --> 00:33:17,320
+ال
+
+319
+00:33:17,320 --> 00:33:26,360
+raw و الميو و
+
+320
+00:33:26,360 --> 00:33:36,420
+عشان نحسب ال beta لازمنا دي small و دي capital و
+
+321
+00:33:36,420 --> 00:33:52,680
+بعدين حسبناشال beta صح بعدين حسبنا ال E مظبوط
+
+322
+00:33:52,680 --> 00:33:59,260
+بعدين
+
+323
+00:33:59,260 --> 00:34:02,060
+حسبنا ال Reynolds number ال D capital
+
+324
+00:34:14,230 --> 00:34:21,470
+بعدين ال a capital بعدين
+
+325
+00:34:21,470 --> 00:34:24,830
+ال c
+
+326
+00:34:24,830 --> 00:34:28,610
+بعد
+
+327
+00:34:28,610 --> 00:34:34,530
+ال c ال a two بعدين
+
+328
+00:34:34,530 --> 00:34:36,710
+ال delta
+
+329
+00:34:45,440 --> 00:34:52,680
+P ايه تكون تعمل اكسل شيط كام يعني تاو في حد يحس ال
+
+330
+00:34:52,680 --> 00:34:58,880
+pressure difference هيكون عنده ده بحطه ع جنب نعم
+
+331
+00:34:58,880 --> 00:35:03,020
+ال K اللي هي بتيجي هنا صح؟
+
+332
+00:35:08,450 --> 00:35:22,230
+الـ C والـ K بعدين A2 Delta B يعني رح يكون عنده T
+
+333
+00:35:22,230 --> 00:35:37,330
+Rho Mu D Small D Capital Beta E Rollens
+
+334
+00:35:37,330 --> 00:35:37,670
+number
+
+335
+00:35:41,790 --> 00:35:54,330
+بعدين A بعدين C K A2 بعدين Delta P
+
+336
+00:36:11,910 --> 00:36:18,070
+الجدولة ده بعمللي مقارنة بين التلت طرق اللي هي
+
+337
+00:36:18,070 --> 00:36:25,410
+الفنشوري و ال .. و ال nozzle و ال orifice من ناحية
+
+338
+00:36:25,410 --> 00:36:28,770
+ال pressure recovery يعني .. يعني بيعطي أقل losses
+
+339
+00:36:28,770 --> 00:36:35,750
+الفنشوري أحسن واحد بيعطي أقل lossesمتوسط النوزل
+
+340
+00:36:35,750 --> 00:36:40,430
+الارفس بال سيران دي اش اللوصيز كتير لأنه بخبط في
+
+341
+00:36:40,430 --> 00:36:44,030
+الجدران في الأول يعني التدفق مش انسيابي فبكون
+
+342
+00:36:44,030 --> 00:36:48,530
+اللوصيز فيه اش عالية الان
+
+343
+00:36:48,530 --> 00:36:52,430
+من ناحية resistance to abrasion مقاومته للحت اللي
+
+344
+00:36:52,430 --> 00:36:57,270
+فيه بحت في ال .. في ال material ال most smooth
+
+345
+00:36:57,270 --> 00:37:03,220
+اللي هو البنشوري صح؟ال flow فيه smoothness بس أقل
+
+346
+00:37:03,220 --> 00:37:07,700
+من الفنشوري يعني الزوايا كتير صغيرة في الفنشوري في
+
+347
+00:37:07,700 --> 00:37:12,140
+ال .. في ال orifice لأ بيكون يخبط و خبط في جدران
+
+348
+00:37:12,140 --> 00:37:17,720
+فبيكون يعني ال abrasion بيكون فيه أكتر ال coast
+
+349
+00:37:17,720 --> 00:37:23,120
+أغلى إش اللي هو الفنشوري بعدين متوسط النزل بعدين
+
+350
+00:37:23,120 --> 00:37:25,740
+أرخص الشيء ال orifice ليه orifice هو بليته في ثقب
+
+351
+00:37:25,740 --> 00:37:30,510
+مافيش فيه إشمن ناحية space requirements كنتش باخد
+
+352
+00:37:30,510 --> 00:37:35,230
+space الفينشوري طويل بكون فباخد space الفلو بتاخد
+
+353
+00:37:35,230 --> 00:37:39,010
+space أقل ال orifice باخد بس بحط plate بين two
+
+354
+00:37:39,010 --> 00:37:44,110
+flanges و خلاص ال accuracy الفينشوري ال most
+
+355
+00:37:44,110 --> 00:37:50,250
+accurate الفلو نزل ال least accurate ال orifice
+
+356
+00:37:50,250 --> 00:37:55,370
+susceptible to inaccuracies from wear and abrasion
+
+357
+00:37:56,120 --> 00:38:01,640
+يعني هو بيكون عرضة لعدم الدقة نتيجة الهريان و الحت
+
+358
+00:38:01,640 --> 00:38:08,480
+في ال .. في ال .. في الثقوب بتاع ال plate الان
+
+359
+00:38:08,480 --> 00:38:12,660
+ال others ال orifice is sensitive to upstream flow
+
+360
+00:38:12,660 --> 00:38:16,020
+يعني ال flow ما قبل بيعتمد يداش في turbulence قبل
+
+361
+00:38:16,020 --> 00:38:21,560
+بيطلع ان انت بيعتمد على how much turbulence قبل ال
+
+362
+00:38:21,560 --> 00:38:25,710
+.. ال orificeال physical length أطوليش هيكون
+
+363
+00:38:25,710 --> 00:38:30,630
+الفنشوري و أقصريش هي الارفس والنوزل المتوسط ال
+
+364
+00:38:30,630 --> 00:38:34,650
+installation التركيب أسهلش في التركيب طبعا
+
+365
+00:38:34,650 --> 00:38:41,190
+الفنشوري و الارفس تركيبه سهل النوزل بيغلب تركيبه
+
+366
+00:38:41,190 --> 00:38:42,630
+بيدوه دقة في التركيب
+
+367
+00:38:50,230 --> 00:38:54,010
+ال pressure drop اذا احنا عملنا معادلة delta P
+
+368
+00:38:54,010 --> 00:38:59,350
+بالثوروك U square على 2K تربيع A2 تربيع A لاحظ ال
+
+369
+00:38:59,350 --> 00:39:02,850
+pressure drop varies as the square of flow rate
+
+370
+00:39:02,850 --> 00:39:06,610
+يعني بتناسب ال pressure drop بتناسب مع مربع ال
+
+371
+00:39:06,610 --> 00:39:10,110
+flow معناته
+
+372
+00:39:10,110 --> 00:39:15,630
+اذا كان ال flow مثلا واحد ربع ال واحد واحدإذا ال
+
+373
+00:39:15,630 --> 00:39:21,990
+flow كان ضعف اتنين تربيع، بيصير أربعة، أربعة ضعف،
+
+374
+00:39:21,990 --> 00:39:29,960
+إذا ال flow تخلط تلت مرات، بيصير تسعة ضعفإذا حكيت
+
+375
+00:39:29,960 --> 00:39:35,060
+مثلا عشرة بيصير مية ضايف، معناته if these meters
+
+376
+00:39:35,060 --> 00:39:38,060
+are to be used over a wide range of flow rates،
+
+377
+00:39:38,060 --> 00:39:42,220
+إذا هستخدم هذه ال meters على wide range of flow
+
+378
+00:39:42,220 --> 00:39:46,980
+rates، معناته بتطلب pressure measuring equipment
+
+379
+00:39:46,980 --> 00:39:54,950
+of very wide range، احنا سيئا كنا ربيعنا، ف ..ف if
+
+380
+00:39:54,950 --> 00:39:58,970
+pressure range is accommodated إذا يعني استطاع
+
+381
+00:39:58,970 --> 00:40:04,470
+تكون عند جهاز بيغطي كل wide range ال accuracy at
+
+382
+00:40:04,470 --> 00:40:09,770
+low flow rates هتكون poor يعني هفقد linearly يعني،
+
+383
+00:40:09,770 --> 00:40:14,390
+يعني هتكون في ال small flow rate هتكون ال accuracy
+
+384
+00:40:14,390 --> 00:40:16,070
+صغيرة
+
+385
+00:40:20,650 --> 00:40:23,390
+الان the small pressure readings لما يكون ال flow
+
+386
+00:40:23,390 --> 00:40:27,130
+rate صغير كتير هيكون .. يعني لو كان ال flow واحد،
+
+387
+00:40:27,130 --> 00:40:31,710
+كويس؟ خلت ال flow نص، ربيع النص، هلقيت .. لما كنا
+
+388
+00:40:31,710 --> 00:40:37,950
+نكبر، صير ربع، ماشي؟ معناته بدي كمان resolution
+
+389
+00:40:37,950 --> 00:40:41,760
+أعلى في ال flow .. بدي resolution أعلى فياش؟في ال
+
+390
+00:40:41,760 --> 00:40:48,340
+low flow readings معناته بفقد اللي يعني بيصير صعب
+
+391
+00:40:48,340 --> 00:40:52,940
+ان احصل دقة عالية في حالة زي هي كذا انا مغطق و
+
+392
+00:40:52,940 --> 00:40:58,060
+wide range of flow
+
+393
+00:40:58,060 --> 00:41:05,180
+rate بستخدم two pressure sensorsواحد بيكون يشتغل
+
+394
+00:41:05,180 --> 00:41:09,780
+لل flow rates لل low flow rates وواحد لل high flow
+
+395
+00:41:09,780 --> 00:41:19,260
+rates عشان أغطي كل ال range خلينا
+
+396
+00:41:19,260 --> 00:41:26,580
+نشوف نحل مجموعة مثال من
+
+397
+00:41:26,580 --> 00:41:27,240
+الكتاب
+
+398
+00:41:44,750 --> 00:41:53,870
+صفحة كم بالكتاب عندكوا ال .. ال .. كم؟ أربعمية و
+
+399
+00:41:53,870 --> 00:41:58,330
+ستين
+
+400
+00:41:58,330 --> 00:42:06,190
+هنشوف ستة
+
+401
+00:42:06,190 --> 00:42:06,690
+و سبعين
+
+402
+00:42:14,000 --> 00:42:19,540
+لأ معناته هاي ال temperature هاي أربعمية و خمسين
+
+403
+00:42:19,540 --> 00:42:29,160
+ميليون دفلو دفلو أربعمية و ستين أنا
+
+404
+00:42:29,160 --> 00:42:30,720
+ماعرف الوش هالأهمية و ستين
+
+405
+00:42:52,460 --> 00:42:53,740
+هنحل مسألة اتنين
+
+406
+00:43:44,910 --> 00:43:53,190
+عند انبوب القطر بتاعها بنزل
+
+407
+00:43:53,190 --> 00:43:58,110
+عند
+
+408
+00:43:58,110 --> 00:43:59,030
+هنا القطر
+
+409
+00:44:01,780 --> 00:44:09,280
+الان بقولش أفقية قطر هنا ستاشر صانطة ل
+
+410
+00:44:09,280 --> 00:44:17,000
+تمانية صانطة تمانية
+
+411
+00:44:17,000 --> 00:44:24,580
+صانطة over length of three meters يعني الطول على
+
+412
+00:44:24,580 --> 00:44:26,120
+طول
+
+413
+00:44:29,640 --> 00:44:36,620
+انت هامش اي مثل لازم اتلخصها صح oil
+
+414
+00:44:36,620 --> 00:44:42,180
+هامج طبعا قلوها تماشي فيها زيت specific gravity
+
+415
+00:44:42,180 --> 00:44:50,360
+بتاعته تمانى خمس يعني ال raw بتاعته اكم هتكون
+
+416
+00:44:50,360 --> 00:44:53,480
+تمانية و خمسين kilogram
+
+417
+00:44:55,190 --> 00:44:59,390
+عال متر مكعب لأن surface gravity هي ال density لل
+
+418
+00:44:59,390 --> 00:45:10,690
+fluid تحت الدراسة و ال density بتاعة الميه صح؟
+
+419
+00:45:10,690 --> 00:45:12,810
+all having surface gravity of point eight five
+
+420
+00:45:12,810 --> 00:45:19,750
+flows at the flow rate يعني ال Q point
+
+421
+00:45:19,750 --> 00:45:22,210
+oh خمسة متر مكعب per second
+
+422
+00:45:32,330 --> 00:45:37,850
+assuming no energy loss فى عندى فش losses no
+
+423
+00:45:37,850 --> 00:45:41,730
+energy
+
+424
+00:45:41,730 --> 00:45:45,630
+loss
+
+425
+00:45:45,630 --> 00:45:50,310
+هذا فرضية what
+
+426
+00:45:50,310 --> 00:45:55,170
+pressure differential لو
+
+427
+00:45:55,170 --> 00:45:56,730
+حكيت هذا position واحد
+
+428
+00:46:00,550 --> 00:46:06,490
+هذا position ايش اتنين ايش دلتا في اللي هي ايش
+
+429
+00:46:06,490 --> 00:46:12,910
+الساوية في واحد minus في اتنين what pressure
+
+430
+00:46:12,910 --> 00:46:18,190
+differential should exist across the tapered
+
+431
+00:46:18,190 --> 00:46:24,150
+section يعني بدي اعلن دفعالية تانية بدي افرض انه
+
+432
+00:46:24,150 --> 00:46:31,490
+هذه اللي هي بدوياهاده افرض عندي incompressible
+
+433
+00:46:31,490 --> 00:46:38,890
+flow
+
+434
+00:46:38,890 --> 00:46:45,610
+يعني ال raw بالساوية constant
+
+435
+00:46:49,790 --> 00:46:54,770
+معناته if there is no energy loss و ال flow غير
+
+436
+00:46:54,770 --> 00:46:59,750
+قبل الانضغاط ممكن استخدم برنولي بين واحد و اتنين
+
+437
+00:46:59,750 --> 00:47:03,210
+برنولي بين واحد و اتنين P واحد
+
+438
+00:47:11,540 --> 00:47:22,840
+زائد نص رو V واحد square زائد رو G H واحد بيستوى P
+
+439
+00:47:22,840 --> 00:47:33,840
+اتنين زائد نص رو V اتنين تربيه زائد رو GH اتنين
+
+440
+00:47:33,840 --> 00:47:41,600
+طبعا عندي في الحالة هذه H واحد بيستوى H اتنينH1
+
+441
+00:47:41,600 --> 00:47:51,520
+بيساوي H2 معناه تصل الى P1 زائد نص رو V1 تربيه
+
+442
+00:47:51,520 --> 00:48:04,120
+بيساوي P2 زائد نص رو V2 تربيه يعني Delta P بيساوي
+
+443
+00:48:04,120 --> 00:48:16,160
+P1 minus P2 بيساوي نص روفي V2 تربيع ناقص V1 تربيع
+
+444
+00:48:16,160 --> 00:48:23,840
+يعني من هنا بيطلع من هنا صح فعندي conservation of
+
+445
+00:48:23,840 --> 00:48:30,080
+mass و لأنه ال density constant بيكون دي
+
+446
+00:48:30,080 --> 00:48:34,560
+conservation of volume conservation of volume يعني
+
+447
+00:48:34,560 --> 00:48:36,720
+هيكون عندى ال Q
+
+448
+00:48:41,920 --> 00:48:51,780
+بساوة a1 v1 اتنين v اتنين يعني انا احكي عند a واحد
+
+449
+00:48:51,780 --> 00:48:57,860
+اللي هو by على اربعة دي square دي
+
+450
+00:48:57,860 --> 00:49:02,960
+square في
+
+451
+00:49:02,960 --> 00:49:15,280
+v واحد بساوة by على اربعة دي squareV2 يعني احنا
+
+452
+00:49:15,280 --> 00:49:22,980
+هنكون عنده V1 او
+
+453
+00:49:22,980 --> 00:49:27,100
+V2 يعني
+
+454
+00:49:27,100 --> 00:49:32,100
+احنا هنكون عنده V1
+
+455
+00:49:32,100 --> 00:49:37,540
+V1
+
+456
+00:49:37,540 --> 00:49:40,160
+هتكون سواء اربعة Q
+
+457
+00:49:43,620 --> 00:49:54,260
+على باى D2 صح و V2 اربعة
+
+458
+00:49:54,260 --> 00:50:02,640
+Q على باى D تربيع small يعني
+
+459
+00:50:02,640 --> 00:50:10,990
+Delta P هتصير انا بحاول اغير في الصيغة Delta Pعشان
+
+460
+00:50:10,990 --> 00:50:13,710
+أحكيلكوا انه مافيش يعني لازم أقول صيغة معينة delta
+
+461
+00:50:13,710 --> 00:50:20,070
+P اللي هو نص رو
+
+462
+00:50:20,070 --> 00:50:28,930
+في اربعة كيو تربيع يعني هكون دي ستاشر كيو تربيع
+
+463
+00:50:28,930 --> 00:50:35,190
+على باعت تربيع دي
+
+464
+00:50:35,190 --> 00:50:35,910
+أس اربعة
+
+465
+00:50:40,690 --> 00:50:51,830
+minus ستاشر Q تربية على بايتربية D small أس أربعة
+
+466
+00:50:51,830 --> 00:51:01,430
+يعني هتكون تمانية رو
+
+467
+00:51:01,430 --> 00:51:19,070
+Q تربية تمانية رو Q تربيةعلى با التربيه في
+
+468
+00:51:19,070 --> 00:51:22,250
+واحد
+
+469
+00:51:22,250 --> 00:51:30,290
+على دي أص أربعة ماينس واحد على دي أص أربعة
+
+470
+00:51:38,770 --> 00:51:46,990
+يعني هتكون ال delta P تمنية
+
+471
+00:51:46,990 --> 00:51:56,770
+ضرب تمنية و خمسين ضرب Q اللي هي point O خمسة تربيع
+
+472
+00:51:56,770 --> 00:51:59,970
+على point تربيع
+
+473
+00:52:07,300 --> 00:52:12,340
+درب واحد على ال دي يعني ستاش يعني point واحد ستاش
+
+474
+00:52:12,340 --> 00:52:16,180
+point واحد ستاش
+
+475
+00:52:16,180 --> 00:52:23,500
+قص اربعة ناقص واحد على point او تمانية تربيه انتبه
+
+476
+00:52:23,500 --> 00:52:30,820
+للوحدات قص اربعة و انها بتحسب ال delta B في ال
+
+477
+00:52:30,820 --> 00:52:31,640
+Bascal بتطلع
+
+478
+00:52:38,590 --> 00:52:43,490
+سوى سالب سالب تسعة و تلاتين و عند أربع تربع شخص
+
+479
+00:52:43,490 --> 00:52:48,970
+تلاتين يعني
+
+480
+00:52:48,970 --> 00:52:53,650
+المفروض انه تطلع موجب بس اللي صار لما نعوضنا احنا
+
+481
+00:52:53,650 --> 00:52:58,070
+هنا المفروض هذا V2 تكون هادي في الأول هحط هنا سالب
+
+482
+00:52:58,070 --> 00:53:01,450
+معناته هادي
+
+483
+00:53:02,810 --> 00:53:14,290
+هذا عن V2 صح؟ سالب .. سالب .. سالب .. سالب .. سالب
+
+484
+00:53:14,290 --> 00:53:14,930
+.. سالب .. سالب .. سالب .. سالب .. سالب .. سالب ..
+
+485
+00:53:14,930 --> 00:53:14,930
+سالب .. سالب .. سالب .. سالب .. سالب .. سالب ..
+
+486
+00:53:14,930 --> 00:53:15,450
+سالب .. سالب .. سالب .. سالب .. سالب .. سالب ..
+
+487
+00:53:15,450 --> 00:53:17,310
+سالب .. سالب .. سالب .. سالب .. سالب .. سالب ..
+
+488
+00:53:17,310 --> 00:53:19,830
+سالب .. سالب .. سالب .. سالب .. سالب .. سالب ..
+
+489
+00:53:19,830 --> 00:53:19,830
+سالب .. سالب .. سالب .. سالب .. سالب .. سالب ..
+
+490
+00:53:19,830 --> 00:53:19,830
+سالب .. سالب .. سالب .. سالب .. سالب .. سالب ..
+
+491
+00:53:19,830 --> 00:53:22,130
+سالب .. سالب .. سالب .. سالب .. سالب .. سالب ..
+
+492
+00:53:22,130 --> 00:53:22,890
+سالب ..
+
+493
+00:53:31,400 --> 00:53:37,360
+بين واحد و اتنين الحل
+
+494
+00:53:37,360 --> 00:53:47,800
+مثال اربعة مثال
+
+495
+00:53:47,800 --> 00:53:51,280
+اربعة بتحكي if the conduit described in problem 2
+
+496
+00:53:51,280 --> 00:53:55,840
+is oriented into a vertical positionwith the
+
+497
+00:53:55,840 --> 00:54:00,140
+larger diameter at the lowest point يعني لو صارت
+
+498
+00:54:00,140 --> 00:54:04,520
+المسألة صارت vertical
+
+499
+00:54:30,780 --> 00:54:43,140
+هذه واحد وهذه اتنين والمسافة بينهم تلاتة متر وهذه
+
+500
+00:54:43,140 --> 00:54:47,220
+تمانية صنطة
+
+501
+00:54:47,220 --> 00:54:51,860
+وهذه ستاشر
+
+502
+00:54:51,860 --> 00:54:55,360
+صنطة
+
+503
+00:54:59,870 --> 00:55:04,230
+what pressure what differential pressure across
+
+504
+00:55:04,230 --> 00:55:08,450
+should be found يداش هكون ال pressure difference
+
+505
+00:55:08,450 --> 00:55:15,950
+الان هعمل reference انا هعمل هاي reference انتي
+
+506
+00:55:15,950 --> 00:55:21,970
+ده
+
+507
+00:55:21,970 --> 00:55:26,950
+reference صح الان هستخدم برنامج equation بين واحد
+
+508
+00:55:26,950 --> 00:55:27,470
+و اتنين
+
+509
+00:55:30,330 --> 00:55:45,370
+H واحد مش هتساوي H اتنين H واحد مش هتساوي هتساوي
+
+510
+00:55:45,370 --> 00:55:46,210
+هتساوي هتساوي هتساوي هتساوي هتساوي هتساوي هتساوي
+
+511
+00:55:46,210 --> 00:55:47,850
+هتساوي هتساوي هتساوي هتساوي هتساوي هتساوي هتساوي
+
+512
+00:55:47,850 --> 00:55:47,850
+هتساوي هتساوي هتساوي هتساوي هتساوي هتساوي هتساوي
+
+513
+00:55:47,850 --> 00:55:47,850
+هتساوي هتساوي هتساوي هتساوي هتساوي هتساوي هتساوي
+
+514
+00:55:47,850 --> 00:55:47,930
+هتساوي هتساوي هتساوي هتساوي هتساوي هتساوي هتساوي
+
+515
+00:55:47,930 --> 00:55:56,170
+هتساوي هتساوي هتساوي هتساوي
+
+516
+00:55:56,170 --> 00:55:56,610
+ه
+
+517
+00:56:00,230 --> 00:56:05,630
+معنى الـ Delta P اللي هي P واحد ناقص P اتنين زائد
+
+518
+00:56:05,630 --> 00:56:12,090
+زائد يعني
+
+519
+00:56:12,090 --> 00:56:15,830
+أنا جيبت ال P اتنين على الجهة التانية وهذا جيبته
+
+520
+00:56:15,830 --> 00:56:20,810
+على الجهة التالية الحاجة
+
+521
+00:56:20,810 --> 00:56:24,870
+بيبقى لها زي ما هي العلاقات لأن Delta P
+
+522
+00:56:33,140 --> 00:56:38,300
+الـ Delta P هتكون
+
+523
+00:56:38,300 --> 00:56:48,900
+تساوي نص فرو هحط
+
+524
+00:56:48,900 --> 00:57:00,070
+في ستاش Q تربيععلى by التربيع في واحد على دي small
+
+525
+00:57:00,070 --> 00:57:14,190
+أس أربعة ناقص واحد دي capital أس أربعة زائد رو جي
+
+526
+00:57:14,190 --> 00:57:23,330
+اتش اتنين يعني هذا ال term الأولاني صح اللي هو
+
+527
+00:57:23,330 --> 00:57:24,470
+تسعة وتلاتين ألف
+
+528
+00:57:28,020 --> 00:57:34,500
+واربعمية زاد رول هي تمانية وخمسين في تسعة بون
+
+529
+00:57:34,500 --> 00:57:44,640
+تمانية صفر ستة ضرب تلاتة الواضح
+
+530
+00:57:44,640 --> 00:57:52,480
+ال .. ال flow طلع .. الواضح ان ال mass بتاعة ال
+
+531
+00:57:52,480 --> 00:57:57,890
+gravity بتاعة ال ..ال fluid هتخلي ال pressure
+
+532
+00:57:57,890 --> 00:58:02,370
+انتنين اقل هتقلل فهكول ال pressure drop ايش؟ اقل
+
+533
+00:58:02,370 --> 00:58:09,490
+هكول ال pressure drop اقل المعنى هو ايش بيستفيد من
+
+534
+00:58:09,490 --> 00:58:16,810
+الشغل هذه؟
+
+535
+00:58:16,810 --> 00:58:25,180
+اذا انا حاسس .. اذا حابب اجسس قيمة ملحوظةبخلّي
+
+536
+00:58:25,180 --> 00:58:27,960
+الجهاز vertical مثلا هاي النبوب ماشي زي هيك الأساس
+
+537
+00:58:27,960 --> 00:58:31,160
+مثلا النبوب ماشي أفكه مثلا نفترض ماشي نبوب أفكه
+
+538
+00:58:31,160 --> 00:58:37,820
+بخلّيه نبوب بحط
+
+539
+00:58:37,820 --> 00:58:43,360
+جهاز بتاعي هنا إذا
+
+540
+00:58:43,360 --> 00:58:48,740
+.. إذا أنا بدي أحس قيمة ذات مغزأ يعني أكبر الفرق
+
+541
+00:58:48,740 --> 00:58:50,280
+بخلّي رأسي
+
+542
+00:58:53,180 --> 00:58:58,540
+لو خلتها العكس هيك يعني
+
+543
+00:58:58,540 --> 00:59:02,180
+هكليك وضع .. وضع كيف هيكون ال pressure difference
+
+544
+00:59:02,180 --> 00:59:09,480
+ال sensed هيكاش هيقل، مظبوط؟ و التالي ميكونش
+
+545
+00:59:09,480 --> 00:59:12,640
+significant لي ان الاحظه او اقيسه
+
+546
+00:59:18,870 --> 00:59:22,990
+يعني في كل حالة حتى هذه إليها استخدام ممكن أفكر
+
+547
+00:59:22,990 --> 00:59:30,510
+إذا ال floor ياتي كبير بخلي رأسي لتحت مثلا فأنا
+
+548
+00:59:30,510 --> 00:59:36,390
+بدي أعرف متى أستخدم أفقي متى رأسي لأعلى متى رأسي
+
+549
+00:59:36,390 --> 00:59:44,070
+لأسفل أكتر بيطلع يعني 64000 يعني
+
+550
+00:59:50,390 --> 00:59:56,290
+بس كان يعني تقريبا اكتر من مرة و نص انا بحاول فيه
+
+551
+00:59:56,290 --> 01:00:01,270
+زيادة ستين فالمية صار بس عشان عملته يعني صار
+
+552
+01:00:01,270 --> 01:00:10,130
+vertical طيب
+
+553
+01:00:23,330 --> 01:00:32,670
+نشوف رقم تمانية a machined
+
+554
+01:00:32,670 --> 01:00:36,930
+venturi meter is placed in a horizontal run of 8
+
+555
+01:00:36,930 --> 01:00:43,290
+-inch schedule 40 commercial pipe هذا standard
+
+556
+01:00:43,290 --> 01:00:48,650
+بنحكيلك 8-inch schedule 40 بتروح على ال table تشوف
+
+557
+01:00:48,650 --> 01:00:55,010
+schedule 40 بتعرف القطر الداخليو القطر الخارجى
+
+558
+01:00:55,010 --> 01:00:59,070
+اللى يعني انه تمانية انش بيكون قطر تمانية انش قطر
+
+559
+01:00:59,070 --> 01:01:03,550
+الداخلية في سكوت يال أربعين عشرين تلاتين خمسين و
+
+560
+01:01:03,550 --> 01:01:03,970
+هكذا
+
+561
+01:01:27,610 --> 01:01:34,790
+عند venturi a
+
+562
+01:01:34,790 --> 01:01:41,190
+machine
+
+563
+01:01:41,190 --> 01:01:44,110
+venturi meter is placed in a horizontal run of
+
+564
+01:01:44,110 --> 01:01:50,390
+eight inch eight inch schedule forty commercial
+
+565
+01:01:50,390 --> 01:01:55,210
+pipe يعني ال ID انا بفهم من ال ID ال D capital هم
+
+566
+01:01:55,210 --> 01:02:01,070
+عطينيهااللي هي سبعة بون تبانية تسعة سبعة بون تسعة
+
+567
+01:02:01,070 --> 01:02:10,650
+تبانية واحد انش for the purpose of metering medium
+
+568
+01:02:10,650 --> 01:02:16,590
+heating oil as it is pumped into a large storage
+
+569
+01:02:16,590 --> 01:02:23,950
+tank هذا طبعا هيحط اللي هيدخل على ال tank فبدي
+
+570
+01:02:23,950 --> 01:02:28,380
+أعرف كده إيش بدخل مظبوطفحط الفنشوري قبل ال tank
+
+571
+01:02:28,380 --> 01:02:34,420
+عشان نعرف كده ايش بدخل ال tank the throat diameter
+
+572
+01:02:34,420 --> 01:02:43,300
+of the venturi is 6 inch يعني دي small وها دي دي
+
+573
+01:02:43,300 --> 01:02:47,080
+capital دي small 6 inch
+
+574
+01:02:52,830 --> 01:02:57,230
+if the differential pressure طبعا حط قاس الدغط بين
+
+575
+01:02:57,230 --> 01:03:06,270
+هاي واحد هاي واحد وهاي اتنين delta P pressure
+
+576
+01:03:06,270 --> 01:03:10,950
+difference بين واحد اتنين اتنين point خمس اربع
+
+577
+01:03:10,950 --> 01:03:18,770
+pound per square inch اتنين point خمس اربع PSI is
+
+578
+01:03:18,770 --> 01:03:24,810
+heldfor one half hour لمدة نص ساعة حافظة الضغط انه
+
+579
+01:03:24,810 --> 01:03:29,910
+اتنين point خمس عشان ال PSI how many gallons or
+
+580
+01:03:29,910 --> 01:03:33,290
+liters of oil should have been pumped؟ كمية
+
+581
+01:03:33,290 --> 01:03:36,930
+الزيتان
+
+582
+01:03:36,930 --> 01:03:42,790
+طبعا الزمن and ال time مص
+
+583
+01:03:42,790 --> 01:03:50,630
+ساعة يعني انا كام تلاتين دقيقة يعني انا كام ثانية
+
+584
+01:03:52,140 --> 01:04:01,440
+ألف تمانية ثانية ال volume اللي دخلناه هيكون ال Q
+
+585
+01:04:01,440 --> 01:04:07,280
+في ال time معناه
+
+586
+01:04:07,280 --> 01:04:17,620
+مطلوب أحسب إيه؟ ال Q، إيش ال Q بالساعة؟ اللي هو K
+
+587
+01:04:20,860 --> 01:04:32,860
+ك في A2 الجزر التربيعي اعطوني ك في A2 الجزر
+
+588
+01:04:32,860 --> 01:04:43,660
+التربيعي اعظم الاتنين دلتا بي على ره صح؟ صحيح
+
+589
+01:04:52,590 --> 01:05:11,850
+الدلتا بي دلتا
+
+590
+01:05:11,850 --> 01:05:13,830
+بي دلتا بي دلتا بي دلتا بي دلتا بي دلتا بي دلتا بي
+
+591
+01:05:13,830 --> 01:05:13,990
+دلتا بي دلتا بي دلتا بي دلتا بي دلتا بي دلتا بي
+
+592
+01:05:13,990 --> 01:05:13,990
+دلتا بي دلتا بي دلتا بي دلتا بي دلتا بي دلتا بي
+
+593
+01:05:13,990 --> 01:05:13,990
+دلتا بي دلتا بي دلتا بي دلتا بي دلتا بي دلتا بي
+
+594
+01:05:13,990 --> 01:05:17,950
+دلتا بي دلتا بي دلتا بي دلتا بي دلتا بي دلتا
+
+595
+01:05:17,950 --> 01:05:20,940
+بي دلتا بي دلتا بي دلتا بي دلتا بي دلتا بي دالرو
+
+596
+01:05:20,940 --> 01:05:32,740
+تاعة الميه مظبوط؟ معناته الرو معروفة عندى مظبوط؟
+
+597
+01:05:32,740 --> 01:05:41,480
+وال اتنين بالسبب باي على اربعة دي small square
+
+598
+01:05:41,480 --> 01:05:47,260
+برضه هذه صارت ايه اش؟ معروفة وضل عندى ال K ال K
+
+599
+01:05:47,260 --> 01:05:55,630
+عشان الساويةC في E ال E إيش الساقة واحد على جزر
+
+600
+01:05:55,630 --> 01:06:04,430
+التربيه لواحد minus beta أربعة و beta عنده دي
+
+601
+01:06:04,430 --> 01:06:09,450
+small على دي capital صارت إيش معروفة معناته ال E
+
+602
+01:06:09,450 --> 01:06:16,870
+معروفة و ضال عنده ال C الجهاز نوعه إيش Venturi
+
+603
+01:06:27,340 --> 01:06:31,820
+ثاني بس ال
+
+604
+01:06:31,820 --> 01:06:40,220
+.. الفنشوري tube الان ال D بتاعته ال D كابيته لكم
+
+605
+01:06:40,220 --> 01:06:47,960
+اتنين و اتنين صح لان قيمة ال C هاخدها من هنا لان
+
+606
+01:06:47,960 --> 01:06:51,760
+ايش هو حكى ليه عن الفنشوري اولا as cast ولا
+
+607
+01:06:51,760 --> 01:06:56,500
+machined ولا rough weldedmachined فانا جاي فى ال
+
+608
+01:06:56,500 --> 01:07:03,480
+range هذا يعنى هتكون ال C point تسعة تسعة خمس plus
+
+609
+01:07:03,480 --> 01:07:06,240
+ولا minus واحد فى المية اعرفت ال C من ال table
+
+610
+01:07:06,240 --> 01:07:13,860
+اعرفت ال C من ال table بحسب ال K بساوي يعنى ال C
+
+611
+01:07:13,860 --> 01:07:16,960
+من
+
+612
+01:07:16,960 --> 01:07:21,580
+ال table فى حالة machined
+
+613
+01:07:24,950 --> 01:07:30,730
+بنشوره بعدين بحسب ال
+
+614
+01:07:30,730 --> 01:07:35,730
+K خلاص
+
+615
+01:07:35,730 --> 01:07:43,450
+بعدين بحسب Q بعدين
+
+616
+01:07:43,450 --> 01:07:48,150
+بحسب كمية اللي جمعت على مدار نص ساعة
+
+617
+01:07:53,100 --> 01:07:55,500
+اللي هيك يقول خلصت المحاضرة تاكل عافية
+
diff --git a/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/Int37hMiTKo_postprocess.srt b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/Int37hMiTKo_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..cd0d29cac98ff83c13df50f76f2b947beef006eb
--- /dev/null
+++ b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/Int37hMiTKo_postprocess.srt
@@ -0,0 +1,1716 @@
+1
+00:00:05,200 --> 00:00:08,140
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:08,140 --> 00:00:13,140
+وبركاته هنكمل في مادة القياسات المحاضرة فات بدنا
+
+3
+00:00:13,140 --> 00:00:19,620
+نحكي عن طرق قياس درجة الحرارة وصلنا لاستخدام ال
+
+4
+00:00:19,620 --> 00:00:26,620
+resistance تيربو ميترزيعني انا حابع نرجع شوية كهرة
+
+5
+00:00:26,620 --> 00:00:30,060
+وبعدين نرجع ل .. ل .. ل .. ل .. how to measure
+
+6
+00:00:30,060 --> 00:00:35,500
+using a resistance لأنه مهم كتير تعمل شوية circuit
+
+7
+00:00:35,500 --> 00:00:43,300
+analysis عشان تقدر تفهم ال .. الموضوع خلان
+
+8
+00:00:43,300 --> 00:00:49,160
+أولا ال .. الراجع اللي هو ال .. ال parallel و ال
+
+9
+00:00:49,160 --> 00:00:53,420
+series circuits إذا عندى voltage source
+
+10
+00:01:09,460 --> 00:01:23,380
+هو عندي مجموعة من ال loads أحمال عندي
+
+11
+00:01:23,380 --> 00:01:33,220
+R1 R2 لحد RN هاي
+
+12
+00:01:33,220 --> 00:01:39,350
+طبعا ال switchesإذا بسكر ال switch الأول حمور طيار
+
+13
+00:01:39,350 --> 00:01:46,430
+ب R1 إذا بسكر R2 بيصير division للطيار بين R1 وR2
+
+14
+00:01:46,430 --> 00:01:52,790
+إذا كنت عندي N loads الطيار
+
+15
+00:01:52,790 --> 00:01:59,030
+divide يعني عندي هنا إذا عندي هنا I هذا سكر مفتاح
+
+16
+00:01:59,030 --> 00:02:02,910
+هيكون عندي هنا I1 I2
+
+17
+00:02:15,200 --> 00:02:30,700
+عندي I N هذه parallel circuit طبعا
+
+18
+00:02:30,700 --> 00:02:35,840
+DC circuit ال
+
+19
+00:02:35,840 --> 00:02:42,840
+voltage across
+
+20
+00:02:45,640 --> 00:02:56,260
+loads أو resistance نفس الشيء بيصير توزيع لإيش؟
+
+21
+00:02:56,260 --> 00:03:02,880
+للتيار يعني زي فاتح كذا حنفي يعنى يعني بيصير عندي
+
+22
+00:03:02,880 --> 00:03:08,040
+ال current divides
+
+23
+00:03:17,710 --> 00:03:22,010
+الـ I الكلي سواء
+
+24
+00:03:22,010 --> 00:03:26,070
+I 1 زائد
+
+25
+00:03:26,070 --> 00:03:31,170
+I 2 لحد
+
+26
+00:03:31,170 --> 00:03:35,150
+I N طبعا هذا ال circuit ممكن اجيب له ايه اش
+
+27
+00:03:35,150 --> 00:03:40,430
+equivalent circuit صح؟ كل واحد هاي voltage source
+
+28
+00:03:50,190 --> 00:04:03,690
+هذه R equivalent ال
+
+29
+00:04:03,690 --> 00:04:08,990
+I هيكون مستوى ال voltage على R equivalent
+
+30
+00:04:12,160 --> 00:04:15,740
+احنا كنا ال voltage across all resistors او all
+
+31
+00:04:15,740 --> 00:04:26,300
+loads نفس الاشي صح؟ هتكون V على R1 زائد V على R2
+
+32
+00:04:26,300 --> 00:04:37,960
+زائد V على RN ال V cancel out يكون عنده 1 على R
+
+33
+00:04:37,960 --> 00:04:44,920
+equivalentماذا هو واحد على R واحد زاد واحد على R
+
+34
+00:04:44,920 --> 00:04:55,000
+اتنين زاد واحد على RN هذا في حالة parallel circuit
+
+35
+00:04:55,000 --> 00:05:01,080
+اذا عندي دقل التوالي
+
+36
+00:05:17,200 --> 00:05:31,920
+هي R1 R2 R3 R4 RN ال
+
+37
+00:05:31,920 --> 00:05:37,920
+current هو flow في الآخر صح flow of electrons ف
+
+38
+00:05:37,920 --> 00:05:42,640
+نفس
+
+39
+00:05:42,640 --> 00:05:44,380
+الطيار نمشي فيهم كلهم
+
+40
+00:05:48,970 --> 00:05:55,790
+معناته بيصير division لل voltage بيصير
+
+41
+00:05:55,790 --> 00:06:01,810
+division لل voltage حسب ال load يديش هياخد
+
+42
+00:06:01,810 --> 00:06:07,110
+pressure loss نخلي ال voltage هتمثل ايش كأنه
+
+43
+00:06:07,110 --> 00:06:15,730
+pressure loss هكون ال V الكليه
+
+44
+00:06:19,270 --> 00:06:27,750
+بتستوى ال V across resistor واحد زائد
+
+45
+00:06:27,750 --> 00:06:41,470
+VIN هذا يمكن أن يكون لقاش equivalent circuit R
+
+46
+00:06:41,470 --> 00:06:45,630
+equivalent ال
+
+47
+00:06:45,630 --> 00:06:47,050
+V بستوى R equivalent
+
+48
+00:06:50,040 --> 00:06:59,080
+في ال I بتستوى
+
+49
+00:06:59,080 --> 00:07:14,880
+طبعا I R واحد يعني
+
+50
+00:07:14,880 --> 00:07:27,240
+بتصف في ال R equivalent بتستوى R واحدزاد R2 زاد RN
+
+51
+00:07:27,240 --> 00:07:30,260
+يعني
+
+52
+00:07:30,260 --> 00:07:39,640
+في حالة in serious loads حصل اتاعتهم مجموع اذا كان
+
+53
+00:07:39,640 --> 00:07:45,560
+دي parallel loads بيكون واحد على R كله و واحد على
+
+54
+00:07:45,560 --> 00:07:48,700
+R واحد زاد واحد على R اتنين زاد واحد على RN
+
+55
+00:08:07,880 --> 00:08:10,120
+طيب خليني اتخيل ان ال circuit
+
+56
+00:08:25,960 --> 00:08:27,540
+ان ال circuit بالشكل
+
+57
+00:08:59,950 --> 00:09:05,370
+ساكر بالشكل هذا عندي
+
+58
+00:09:05,370 --> 00:09:18,510
+هنا R واحد R اتنين R تلاتة و R اربعة و
+
+59
+00:09:18,510 --> 00:09:22,050
+R خمسة
+
+60
+00:09:22,050 --> 00:09:26,190
+هنحكي اصلا R واحد بالساوية خمسة أم
+
+61
+00:09:30,260 --> 00:09:38,020
+R2 عشرة أم وR3
+
+62
+00:09:38,020 --> 00:09:44,580
+R3
+
+63
+00:09:44,580 --> 00:09:50,820
+ستة أم R4
+
+64
+00:09:50,820 --> 00:09:58,380
+أربعة أم R5 ستة أم
+
+65
+00:10:07,890 --> 00:10:18,070
+الان ال total current هذا I ال total لما
+
+66
+00:10:18,070 --> 00:10:25,310
+ادخل عند ال node هذه ب stereo division بفرع صح؟
+
+67
+00:10:25,310 --> 00:10:41,110
+هاي الطينة هاي I واحد و هيكI اتنين طبعا
+
+68
+00:10:41,110 --> 00:10:46,390
+هين ال I واحد طبعا الطيار هين ممكن تكون هيك او
+
+69
+00:10:46,390 --> 00:10:52,130
+العكس مظلوط؟ مش عارفين هنا خلينا نفترض انه هيوزع
+
+70
+00:10:52,130 --> 00:11:00,910
+هين I تلاتة و I اربعة
+
+71
+00:11:04,150 --> 00:11:13,210
+عندى هنا داخل I ثلاثة و I اتنين بيعطيني I خمسة و
+
+72
+00:11:13,210 --> 00:11:22,070
+هنا بيعطيني ايش I total لو
+
+73
+00:11:22,070 --> 00:11:28,230
+عملت node analysis عند ال node هذه لو بدى بطريقة
+
+74
+00:11:28,230 --> 00:11:42,490
+تقليدية هحكي I total I totalكونت ساوية I1 زائد I2
+
+75
+00:11:42,490 --> 00:11:46,950
+Flow الداخل
+
+76
+00:11:46,950 --> 00:11:55,450
+بساوية الطالع عند ال node هذه I1
+
+77
+00:11:55,450 --> 00:11:58,950
+بتساوي
+
+78
+00:11:58,950 --> 00:12:04,250
+I3 زائد I4
+
+79
+00:12:09,760 --> 00:12:14,840
+وعند ال node هذه I2
+
+80
+00:12:14,840 --> 00:12:21,760
+زي I3 بالسواء
+
+81
+00:12:21,760 --> 00:12:29,980
+I5 عند ال node هذه I4
+
+82
+00:12:29,980 --> 00:12:33,180
+زي
+
+83
+00:12:33,180 --> 00:12:43,350
+I5 بالسواء I totalكم مجهول عنده؟
+
+84
+00:12:43,350 --> 00:12:54,690
+ست مجهول كم معدلة؟ أربعة معناته محتاج كمان معدلتين
+
+85
+00:12:54,690 --> 00:13:04,450
+هعمل two loops هعمل يعني
+
+86
+00:13:04,450 --> 00:13:11,100
+أنا هيك اللي صويته يعنيعملته analysis لان هعمل two
+
+87
+00:13:11,100 --> 00:13:18,980
+loops هاي ال loop الأولانية و
+
+88
+00:13:18,980 --> 00:13:24,500
+هاي ال loop التاني
+
+89
+00:13:24,500 --> 00:13:28,960
+في
+
+90
+00:13:28,960 --> 00:13:33,280
+ال loop هذه انا بحكي في ال loop هذه ال total
+
+91
+00:13:33,280 --> 00:13:39,440
+voltage سواء صفرلأن أنا عندي هنا ال loop جاية عكس
+
+92
+00:13:39,440 --> 00:13:48,120
+ال I واحد هتكون عندي يعني سالب خمسة
+
+93
+00:13:48,120 --> 00:13:52,900
+I واحد زائد
+
+94
+00:13:52,900 --> 00:14:02,360
+عشرة I اتنين سالب
+
+95
+00:14:05,250 --> 00:14:15,030
+I ثلاثة نصفة و صفر هذه ال loop one ال
+
+96
+00:14:15,030 --> 00:14:21,470
+loop التانية ستة
+
+97
+00:14:21,470 --> 00:14:24,710
+I ثلاثة
+
+98
+00:14:24,710 --> 00:14:27,850
+زائد
+
+99
+00:14:27,850 --> 00:14:31,250
+ستة I خمسة
+
+100
+00:14:37,680 --> 00:14:47,940
+ناقص أربعة I أربعة ساوي سفر حدد
+
+101
+00:14:47,940 --> 00:14:53,260
+ست معدلات ست مجاهية بمعناته بدي أعمل .. بدي أستخدم
+
+102
+00:14:53,260 --> 00:14:59,500
+مصطفات وبكل في حالة ممكن أكتب بقى عيد صياغتهم احكي
+
+103
+00:14:59,500 --> 00:15:04,600
+I واحد زائد
+
+104
+00:15:04,600 --> 00:15:05,440
+I اتنين
+
+105
+00:15:08,080 --> 00:15:20,540
+ناقص I T بيساوي صفر و I واحد ناقص
+
+106
+00:15:20,540 --> 00:15:32,040
+I تلاتة ناقص I أربع بتساوي صفر و I اتنين زائد I
+
+107
+00:15:32,040 --> 00:15:46,650
+تلاتةناقص I خمسة متساوى صفر و I أربعة زائد I خمسة
+
+108
+00:15:46,650 --> 00:15:58,230
+سالب I T متساوى صفر هنا عندي السالب خمسة I واحد
+
+109
+00:15:58,230 --> 00:16:10,710
+زائد عشرة I اتنينناقص ستة اي تلاتة ساعة صفر وستة
+
+110
+00:16:10,710 --> 00:16:26,930
+اي تلاتة زائد ستة اي خمسة ناقص اربعة اي اربعة ناقص
+
+111
+00:16:26,930 --> 00:16:27,470
+اربعة
+
+112
+00:16:34,780 --> 00:16:43,000
+اي اربعة زائد ستة اي خمسة ساوة سفر ده عمله شكل
+
+113
+00:16:43,000 --> 00:16:54,060
+مصوفة عندي هنا واحد عندي عندي هنا واحد واحد سفر
+
+114
+00:16:54,060 --> 00:17:04,910
+هذه تلاتة صح سفر اربعة خمسة سالب واحدالتانى عندهين
+
+115
+00:17:04,910 --> 00:17:16,870
+واحد صفر سالب واحد سالب واحد صفر صفر التالتة صفر
+
+116
+00:17:16,870 --> 00:17:24,290
+واحد واحد صفر سالب واحد صفر
+
+117
+00:17:30,640 --> 00:17:48,360
+الربع صفر صفر صفر واحد واحد واحد سالب واحد الخمسة
+
+118
+00:17:48,360 --> 00:17:57,520
+سالب خمسة عشرة سالب ستة تلت أصفر
+
+119
+00:18:02,210 --> 00:18:10,330
+السادسة صفر صفر ستة
+
+120
+00:18:10,330 --> 00:18:15,550
+سالب أربعة ستة
+
+121
+00:18:15,550 --> 00:18:23,390
+صفر في I
+
+122
+00:18:23,390 --> 00:18:24,050
+واحد
+
+123
+00:18:27,770 --> 00:18:41,710
+I اتنين I تلاتة I أربعة I خمسة I total بتساوي
+
+124
+00:18:41,710 --> 00:18:45,230
+ايش؟
+
+125
+00:18:45,230 --> 00:18:52,330
+يعني
+
+126
+00:18:52,330 --> 00:19:06,730
+هذه A هذه Xهذه C أو B يعني
+
+127
+00:19:06,730 --> 00:19:12,570
+you can solve for
+
+128
+00:19:12,570 --> 00:19:15,870
+I
+
+129
+00:19:15,870 --> 00:19:20,830
+واحد I
+
+130
+00:19:20,830 --> 00:19:39,090
+اتنين I تلاتة I أربعةو I خمسة و I total يعني
+
+131
+00:19:39,090 --> 00:19:48,130
+العملية طويلة العملية طويلة معناته انا محتاج
+
+132
+00:19:48,130 --> 00:19:54,110
+لطريقة to simplify لكن لازم اعمل simplification
+
+133
+00:19:54,110 --> 00:20:02,800
+لهذه عشان يكونواtwo resistors parallel لازم يكونوا
+
+134
+00:20:02,800 --> 00:20:09,920
+مشتركين بالأطراف يعني عندها هذي parallel هذول
+
+135
+00:20:09,920 --> 00:20:22,340
+ايش هذول parallel صح؟ and series هذول
+
+136
+00:20:22,340 --> 00:20:25,560
+اللي بنفعش يكونش داخل من هنا زي الحالة هذه أو
+
+137
+00:20:25,560 --> 00:20:31,260
+الحالة هذهمانع تقول انا في اندي حالة لا هي
+
+138
+00:20:31,260 --> 00:20:39,740
+parallel ولا هي series عندي هنا ما يسمى delta هذه
+
+139
+00:20:39,740 --> 00:20:52,620
+delta ممكن انا اعملها ببساطة لأ ممكن الان خناخد
+
+140
+00:21:17,670 --> 00:21:21,770
+لو عندي أنا مقاومات
+
+141
+00:21:21,770 --> 00:21:22,430
+بشكل هذا
+
+142
+00:22:18,140 --> 00:22:24,000
+خلّيني أندي هذه اسمها ra ر
+
+143
+00:22:24,000 --> 00:22:33,720
+بي و ر سي والنقاط
+
+144
+00:22:33,720 --> 00:22:43,140
+هسميها واحد اتنين هذه النقطة واحد اتنين
+
+145
+00:22:43,140 --> 00:22:47,400
+تلاتة
+
+146
+00:22:53,170 --> 00:23:05,670
+هذه ممكن احولها انا هذه تسمى Delta تسمى Delta ممكن
+
+147
+00:23:05,670 --> 00:23:16,830
+احولها النظام مش زي هيك Y
+
+148
+00:23:16,830 --> 00:23:19,870
+يعني هذي تكون تصير equivalent ل
+
+149
+00:23:29,280 --> 00:23:39,240
+و هذه النقطة النقاط نفسها هذه واحد هذه اتنين هذه
+
+150
+00:23:39,240 --> 00:23:49,820
+تلاتة يعني اذا قصت حطيت اوميتر هنا اذا
+
+151
+00:23:49,820 --> 00:23:55,240
+حطيت اوميتر قصت هنا او حطيت اوميتر قصت هنا هتعطي
+
+152
+00:23:55,240 --> 00:24:03,990
+نفس القراءة حطيت اوميترهتعطيني ايش نفس القراءة
+
+153
+00:24:03,990 --> 00:24:07,170
+لحظة
+
+154
+00:24:07,170 --> 00:24:15,050
+شوية انا اذا كنت احط on meter بين واحد و اتنين هذه
+
+155
+00:24:15,050 --> 00:24:19,950
+دلتة طبعا و
+
+156
+00:24:19,950 --> 00:24:28,550
+هذه ايش Y اذا حطيت جهاز لقياس المقاومة on meter
+
+157
+00:24:28,550 --> 00:24:46,240
+احطه بشكل هذاو برضه هين هحط جهاز on meter ال
+
+158
+00:24:46,240 --> 00:24:50,760
+on meter جاي بين الطرف واحد و اتنين جاي بين الطرف
+
+159
+00:24:50,760 --> 00:24:57,320
+واحد و اتنين و بترى شو يسوي بمرر تياره بقيس volt و
+
+160
+00:24:57,320 --> 00:25:01,000
+volt على تياره بيحسن مقامه صح؟ اظبط؟
+
+161
+00:25:03,270 --> 00:25:12,990
+فالقياس بين واحد و اتنين R واحد و اتنين طبقا
+
+162
+00:25:12,990 --> 00:25:20,170
+لل Delta هتكون
+
+163
+00:25:20,170 --> 00:25:23,570
+هاد
+
+164
+00:25:23,570 --> 00:25:24,470
+و هاد توالي
+
+165
+00:25:27,020 --> 00:25:32,600
+و هدول تنتهي مع بعض المحاصر بتاعتهم توازن معها هذه
+
+166
+00:25:32,600 --> 00:25:38,040
+صح؟ هتكون
+
+167
+00:25:38,040 --> 00:25:43,000
+RA محاصر
+
+168
+00:25:43,000 --> 00:25:50,600
+هدول إيش هيكون؟ مظبوط RB زاد
+
+169
+00:25:50,600 --> 00:26:03,330
+RCعلى مجموعة تلاتة RA زاد RB زاد RC المفروض إذا
+
+170
+00:26:03,330 --> 00:26:05,690
+هدي equivalent لهدي في زي واقعي اسم القوام بين
+
+171
+00:26:05,690 --> 00:26:12,930
+واحد واثنين تقي نفس المقاومة ر واحد ر واحد لاتنين
+
+172
+00:26:12,930 --> 00:26:18,950
+على نظام ال Y هتكون
+
+173
+00:26:18,950 --> 00:26:19,470
+تساوي
+
+174
+00:26:22,740 --> 00:26:29,280
+هذا مش همشي طيارة لانها open اظبط مفتوحة خلاص
+
+175
+00:26:29,280 --> 00:26:40,920
+فهيكون ان دي هنحكي هذي R1 هذي R2 هذي R3 هتكون R1
+
+176
+00:26:40,920 --> 00:26:44,860
+زائد R2
+
+177
+00:26:47,120 --> 00:26:52,280
+بغض نظرية delta والله واي الometer المفروض يعطي
+
+178
+00:26:52,280 --> 00:26:54,260
+نفس المقاومة ..معناته هذه لازت تكون تستوية
+
+179
+00:26:54,260 --> 00:26:59,320
+..معناته لازت تكون عندي R1
+
+180
+00:26:59,320 --> 00:27:05,040
+زي R2 هذه تستوية هذه ..صح؟ لو
+
+181
+00:27:05,040 --> 00:27:09,260
+حطيت الometer بين
+
+182
+00:27:09,260 --> 00:27:13,080
+اتنين و تلاتة لو حطيت الometer
+
+183
+00:27:16,060 --> 00:27:26,880
+بين اتنين و تلاتة خلاص
+
+184
+00:27:26,880 --> 00:27:36,180
+مافي اوميتر هنا المفروض
+
+185
+00:27:36,180 --> 00:27:39,980
+كراية المقام بين اتنين و تلاتة في الـ Delta تطيب
+
+186
+00:27:39,980 --> 00:27:44,320
+نفس كراية ال اوميتر بين اتنين و تلاتة في ال Y هذه
+
+187
+00:27:44,320 --> 00:27:53,810
+نفس النقاطيعني هتكون R اتنين تلاتة Delta هذه
+
+188
+00:27:53,810 --> 00:27:58,270
+المقاومة هتكون parallel مع محصلة التلتين هدول هدول
+
+189
+00:27:58,270 --> 00:28:09,890
+ايش series هتكون تستوى R C في R A زاد R B على
+
+190
+00:28:09,890 --> 00:28:22,220
+مجموعهم على R A زاد R Bزاد R C هذه المفروض تساوي R
+
+191
+00:28:22,220 --> 00:28:34,400
+اتنين لتلاتة بنظام ال Y هذي open هتكون R اتنين زاد
+
+192
+00:28:34,400 --> 00:28:39,360
+R تلاتة انا لو حطت أمتر بين واحد و تلاتة
+
+193
+00:28:45,620 --> 00:28:53,760
+بين واحد تلاتة وفتقي
+
+194
+00:28:53,760 --> 00:29:00,620
+نفس الكراءة هتكون
+
+195
+00:29:00,620 --> 00:29:09,470
+R اتنين واحد تلاتة عن نظام ال Deltaهتكون ر بي in
+
+196
+00:29:09,470 --> 00:29:17,090
+parallel مع محصلة a و c ر بي
+
+197
+00:29:17,090 --> 00:29:29,710
+في ر ا زاد ر سي على مجموعهم على ر ا زاد ر بي زاد ر
+
+198
+00:29:29,710 --> 00:29:35,190
+سي هتكون ر واحد زاد ر تلاتة
+
+199
+00:29:49,340 --> 00:30:03,480
+هذه تحكي معادلة واحد هذه اتنين هذه تلاتة تلعب
+
+200
+00:30:03,480 --> 00:30:12,320
+جبعت معادلة واحد مع تلاتةتقين R1 زاد R1 اتنين R1
+
+201
+00:30:12,320 --> 00:30:17,960
+زاد R2 زاد R3 واضطرحت رقم اتنين منهم بلغ R2 وR3
+
+202
+00:30:17,960 --> 00:30:22,600
+يعني بجمع واحد زاد
+
+203
+00:30:22,600 --> 00:30:35,220
+تلاتة ناقص اتنين يعني هتكون عندي هذي هتكون R1
+
+204
+00:30:38,070 --> 00:30:47,230
+زاد R2 هذا المعادلة واحد صح؟ زاد معادلة تلاتة R1
+
+205
+00:30:47,230 --> 00:30:59,730
+زاد R3 minus R2 زاد R3 هذا الجهة اليمين هتساوي
+
+206
+00:31:01,920 --> 00:31:07,620
+حجمها هادي مع هادي صح؟ اللحظة المقام نفسه ثابت
+
+207
+00:31:07,620 --> 00:31:20,720
+هكون معناته موحد ra زائد rb زائد rc هدخل .. أفتح
+
+208
+00:31:20,720 --> 00:31:25,480
+الفلوس هكون دي ra rb
+
+209
+00:31:27,010 --> 00:31:33,170
+زاد RA RC زاد
+
+210
+00:31:33,170 --> 00:31:43,810
+RA RB زاد
+
+211
+00:31:43,810 --> 00:31:48,590
+RB RC
+
+212
+00:31:48,590 --> 00:32:02,080
+هطرح هذه ناقص RARC ناقص RB RC
+
+213
+00:32:02,080 --> 00:32:05,240
+الآن
+
+214
+00:32:05,240 --> 00:32:12,320
+هذه تروح مع هذه وهذه
+
+215
+00:32:12,320 --> 00:32:22,680
+مع هذه على الجهة هذه هذه مع هذه وهذه مع هذه صح؟
+
+216
+00:32:24,230 --> 00:32:29,310
+يعني بصف عنده اتنين اتنين
+
+217
+00:32:29,310 --> 00:32:34,030
+R واحد اتنين
+
+218
+00:32:34,030 --> 00:32:41,350
+R A R B على
+
+219
+00:32:41,350 --> 00:32:51,670
+R A زائد R B زائد R C شيل اتنين
+
+220
+00:32:56,530 --> 00:33:03,910
+تكون R1 R1 جاي بين A و B بتستوى RA في RV على
+
+221
+00:33:03,910 --> 00:33:09,130
+مجموعة تلت RA زي RB زي RC بنفس المنطق يعني بنحل
+
+222
+00:33:09,130 --> 00:33:23,070
+برضه مثلا عشان أجيب R2 بجمع 1 زي 2 نقص 3 يعني
+
+223
+00:33:23,070 --> 00:33:28,730
+هتكون عنديأو على نفس نمطها هتطلع نفس الأشياء هتطلع
+
+224
+00:33:28,730 --> 00:33:41,670
+طبعا ال R اتنين جاية بين .. بين A و C جاية بين A و
+
+225
+00:33:41,670 --> 00:33:46,190
+C هتكون RA RC
+
+226
+00:33:46,190 --> 00:34:01,520
+على RA زاد RVزاد RC وال R تلاتة جاي بين RB و RC صح
+
+227
+00:34:01,520 --> 00:34:06,320
+هتكون سواء RB في
+
+228
+00:34:06,320 --> 00:34:19,860
+RC على جمع التلاتة RA زاد RB زاد RC هذا
+
+229
+00:34:19,860 --> 00:34:25,820
+conversion من Delta لوائي هذا من Deltaل Y عشان
+
+230
+00:34:25,820 --> 00:34:35,860
+احول من Y العكس من Y ل Delta خلنا
+
+231
+00:34:35,860 --> 00:34:40,320
+اضرب R1 اضرب
+
+232
+00:34:40,320 --> 00:34:48,220
+R1 في R2 ياشو الساوي R1 في
+
+233
+00:34:48,220 --> 00:34:48,740
+R2
+
+234
+00:34:55,150 --> 00:35:05,010
+لأ هضرب من ضرب هاي ر واحد ر ايه تربية؟ ر ايه
+
+235
+00:35:05,010 --> 00:35:08,990
+تربية؟
+
+236
+00:35:08,990 --> 00:35:21,060
+ر بي ر سي على المجموع تاعهمخلّيني أسمي هذه نحكي ..
+
+237
+00:35:21,060 --> 00:35:31,180
+خلّي تسميلي ر ر ايه زي ر بي زي ر سي عشان سهل حالنا
+
+238
+00:35:31,180 --> 00:35:43,560
+ماشي ضروري برضه ر واحد ر تلاتة ر واحد ر تلاتة عندي
+
+239
+00:35:43,560 --> 00:35:45,860
+ر ايه
+
+240
+00:35:50,050 --> 00:36:00,410
+RB تربيع RC على R على R ولا R تربيع R تربيع R
+
+241
+00:36:00,410 --> 00:36:10,690
+تربيع صح و ال R اتنين R تلاتة هاي عند اتنين في
+
+242
+00:36:10,690 --> 00:36:14,710
+تلاتة RA RB
+
+243
+00:36:18,630 --> 00:36:31,310
+R C تربيه على R تربيه خنج
+
+244
+00:36:31,310 --> 00:36:39,550
+مع التلاتة مع بعض R واحد R
+
+245
+00:36:39,550 --> 00:36:42,490
+اتنين زائد
+
+246
+00:36:44,600 --> 00:36:54,740
+R واحد R تلاتة زاد R اتنين R تلاتة ايش حساوي طبعا
+
+247
+00:36:54,740 --> 00:37:02,940
+هاخد R تربيع مشترك بينهم صح؟ R تربيع مشترك
+
+248
+00:37:02,940 --> 00:37:06,040
+هكون
+
+249
+00:37:06,040 --> 00:37:10,720
+عندي طبعا لاحظوا هنا عندي ممكن في كل الحلات اخد R
+
+250
+00:37:10,720 --> 00:37:20,760
+A R B R C مشترك صح؟ر اي اللي هي ر بي ر سي مشترك من
+
+251
+00:37:20,760 --> 00:37:27,200
+الأولى هيكون ايش ر اي صح زاد
+
+252
+00:37:27,200 --> 00:37:38,780
+ر بي زاد ر سي اللي هي دي ايش ر يعني هتكون هتساوي ر
+
+253
+00:37:38,780 --> 00:37:41,620
+اي ر بي
+
+254
+00:37:47,590 --> 00:37:56,970
+مظبوط في R C على R مظبوط؟معناته
+
+255
+00:37:56,970 --> 00:38:02,370
+مجموع التلاتة اللي هي R 1 R 2 زاد R 1 R 3 زاد R 2
+
+256
+00:38:02,370 --> 00:38:10,670
+R 3 بيستوار R A R B R C على R معناته
+
+257
+00:38:10,670 --> 00:38:11,970
+انتبهوا هنا على ال R 1
+
+258
+00:38:19,150 --> 00:38:35,190
+لو ضررت ال R1 ب Rc ايش
+
+259
+00:38:35,190 --> 00:38:44,250
+تعطينا تعطينا Rc R1
+
+260
+00:38:44,250 --> 00:38:55,670
+بالثاوية اللي هو هذهاللي هي R واحد R اتنين زاد R
+
+261
+00:38:55,670 --> 00:39:06,590
+واحد R تلاتة R اتنين زاد R اتنين زاد
+
+262
+00:39:06,590 --> 00:39:16,630
+R اتنين R تلاتة يعني RC اللي هي ال Delta Covalent
+
+263
+00:39:18,210 --> 00:39:30,330
+هتكون تساوي R واحد زاد R اتنين R واحد R اتنين زاد
+
+264
+00:39:30,330 --> 00:39:39,850
+R واحد R التلاتة زاد R اتنين R التلاتة على R واحد
+
+265
+00:39:39,850 --> 00:39:50,100
+طيب اللي هي RC يعني انا رجعت ليشللـ Delta لو ضربت
+
+266
+00:39:50,100 --> 00:40:01,320
+ال R2 ب Rb يعني
+
+267
+00:40:01,320 --> 00:40:05,440
+Rb بيستخدم
+
+268
+00:40:05,440 --> 00:40:17,500
+مجموعهم اللي هو R1 R2 زاد R1 R3 زاد R2 R3 على R2
+
+269
+00:40:21,020 --> 00:40:27,900
+لو هى ضربتها ب ر ايه هتكون
+
+270
+00:40:27,900 --> 00:40:42,880
+ر ايه بتساوي ر واحد ر اتنين زاد ر واحد ر تلاتة زاد
+
+271
+00:40:42,880 --> 00:40:45,780
+ر اتنين ر تلاتة
+
+272
+00:40:48,580 --> 00:40:57,180
+على R ثلاثة واضح ان انا ممكن احول من Y
+
+273
+00:40:57,180 --> 00:41:05,320
+لDelta من Delta لياش ل Y يعني في طريقة
+
+274
+00:41:23,460 --> 00:41:30,500
+طيب نرجع ل ..
+
+275
+00:41:30,500 --> 00:41:37,100
+ل .. المثلة
+
+276
+00:41:37,100 --> 00:41:38,240
+تاعتنا السابقة
+
+277
+00:42:25,860 --> 00:42:45,360
+انا كان اشي زي هيك ها
+
+278
+00:42:45,360 --> 00:42:50,020
+دي R واحد R اتنين R تلاتة
+
+279
+00:42:55,290 --> 00:43:15,610
+و R أربعة و R خمسة فين دي voltage source ال
+
+280
+00:43:15,610 --> 00:43:16,730
+R واحد خمسة
+
+281
+00:43:27,520 --> 00:43:40,500
+و ال R اتنين عشرة و ال R تلاتة و ال R أربعة و
+
+282
+00:43:40,500 --> 00:43:43,520
+ال
+
+283
+00:43:43,520 --> 00:43:52,500
+R خمسة ستة اوم بدي
+
+284
+00:43:52,500 --> 00:43:54,140
+اجيب ال equivalent circuit عشان احسب ال total
+
+285
+00:43:54,140 --> 00:43:55,160
+current في الدائرة
+
+286
+00:44:10,040 --> 00:44:15,940
+هنحكي واضح انه هذه ال delta او هذه ال delta صح؟
+
+287
+00:44:15,940 --> 00:44:23,500
+المعنى انت ممكن انا اجيب هذه الدائرة تصير بالشكل
+
+288
+00:44:23,500 --> 00:44:23,800
+هذا
+
+289
+00:44:38,250 --> 00:44:47,210
+يعني هنا ممكن اعمل على اشي زي هيك اضغط هذه
+
+290
+00:44:47,210 --> 00:44:54,630
+النقطة هي هذه صح وهذه هي هذه هي خلاص احكي هذه واحد
+
+291
+00:44:54,630 --> 00:45:03,070
+هذه اتنين هذه تلاتة او خلاص اسميها عشان هنا مسمي
+
+292
+00:45:03,070 --> 00:45:07,030
+واحد اتنين تلاتة اسمي ABC اسميها
+
+293
+00:45:12,510 --> 00:45:26,370
+A B C و D يعني عندى هذا نقطة A هذا B هذا C هذا
+
+294
+00:45:26,370 --> 00:45:30,430
+سامعها RA هذا
+
+295
+00:45:30,430 --> 00:45:37,130
+RB هذا إيش؟ RC وهذا حضرها إيش؟ R4
+
+296
+00:45:43,280 --> 00:45:57,940
+هذه R أربعة هذه R خمس وهذه النقطة D ال
+
+297
+00:45:57,940 --> 00:46:03,640
+A جاء بين واحد و اتنين صح؟ يعني هتكون عند ال R A
+
+298
+00:46:03,640 --> 00:46:07,400
+ايش
+
+299
+00:46:07,400 --> 00:46:22,670
+بتساوي؟ R واحدR2 على R1 زيارة R2 زيارة R3 رح تكون
+
+300
+00:46:22,670 --> 00:46:32,170
+R1 في R2 يعني خمسة في عشرة على خمسة زائد عشرة
+
+301
+00:46:32,170 --> 00:46:36,790
+خمستاشر
+
+302
+00:46:36,790 --> 00:46:40,810
+صح؟ خلنا نسميها دي خمسة
+
+303
+00:46:46,400 --> 00:46:57,100
+زائد خمسة عشان أسهل الأرقام يعني هتكون خمسين على
+
+304
+00:46:57,100 --> 00:47:03,540
+عشرين نين و نص ام ال
+
+305
+00:47:03,540 --> 00:47:08,380
+Rb جايبين
+
+306
+00:47:08,380 --> 00:47:18,120
+واحد و تلاتة صح جايبين واحدو تلاتة يعني هتكون خمسة
+
+307
+00:47:18,120 --> 00:47:26,220
+في خمسة على عشرين خمس
+
+308
+00:47:26,220 --> 00:47:40,880
+عشرين على اياش على عشرين و واحد و ربع صح ال
+
+309
+00:47:40,880 --> 00:47:41,300
+RC
+
+310
+00:47:44,700 --> 00:47:50,720
+بين اتنين و تلاتة يعني هتكون R اتنين في R تلاتة
+
+311
+00:47:50,720 --> 00:48:00,260
+عشرة في خمسة على عشرين صح اتنين
+
+312
+00:48:00,260 --> 00:48:09,320
+و نص on طيب
+
+313
+00:48:09,320 --> 00:48:13,940
+اللي انا هادي هتروح
+
+314
+00:48:17,160 --> 00:48:23,740
+لحظة ر سي و ر خمسة ايش منهم توالي توالي يعني هتصير
+
+315
+00:48:23,740 --> 00:48:27,780
+هذه هي
+
+316
+00:48:27,780 --> 00:48:33,760
+عندي ر ايه ر سي زاد ر خمسة هتكون ايش المكافئة لهم
+
+317
+00:48:33,760 --> 00:48:44,420
+اللي هو اتنين و نص خلنا نسميها اسم هنا خلنا
+
+318
+00:48:44,420 --> 00:48:54,830
+نسميهار دي و ر بي و ر اربعة برضه تواليه
+
+319
+00:48:54,830 --> 00:49:03,730
+هسميها ر اي هذه
+
+320
+00:49:03,730 --> 00:49:17,050
+اللي still النقطة ايه؟ وهذه النقطة دي هتكون الارال
+
+321
+00:49:17,050 --> 00:49:28,310
+R دي هتكون ال R C زاد ال R خمسة ال R C اللي هي
+
+322
+00:49:28,310 --> 00:49:34,470
+اتنين و نص اتنين و نص زاد
+
+323
+00:49:34,470 --> 00:49:41,590
+ست خلينا
+
+324
+00:49:41,590 --> 00:49:42,410
+نسميها دي عشرة
+
+325
+00:49:45,520 --> 00:49:50,520
+انا نص زي عشرة ماشي
+
+326
+00:49:50,520 --> 00:50:03,320
+و نص و ال ر ايه ر بي
+
+327
+00:50:03,320 --> 00:50:10,420
+زي اربعة ال
+
+328
+00:50:10,420 --> 00:50:19,920
+ر بي اللي هي واحد و ربعزاد ر أربعة اللي هي أربعة
+
+329
+00:50:19,920 --> 00:50:30,300
+صح الخمسة وربع ام الان
+
+330
+00:50:30,300 --> 00:50:35,260
+انا ممكن اعمل كمان simplification ر ا و ر د in
+
+331
+00:50:35,260 --> 00:50:43,420
+parallel هذه هتصفه هذه
+
+332
+00:50:43,420 --> 00:50:57,020
+ر اهو هذه خدنا نسميها RF ال RF هتكون سوى RD في RE
+
+333
+00:50:57,020 --> 00:51:04,160
+على RD زاد
+
+334
+00:51:04,160 --> 00:51:12,640
+RE هتكون ال RD 12.5 في 5.25
+
+335
+00:51:16,400 --> 00:51:34,140
+على اتناش و نص زائد خمسة ربع اكتر بتطلع هذه
+
+336
+00:51:34,140 --> 00:51:40,560
+هتكون
+
+337
+00:51:40,560 --> 00:51:42,200
+هدول in series
+
+338
+00:51:47,290 --> 00:51:52,510
+أكم؟ ال R
+
+339
+00:51:52,510 --> 00:52:02,030
+كوبلاند شو الساوي؟ R A زي ال R F هتكون
+
+340
+00:52:02,030 --> 00:52:10,090
+دي ال R ايه؟ نين و نص زي تلاتة point ستة تسعة يعني
+
+341
+00:52:18,010 --> 00:52:24,490
+يعني هتكون تسعة ستة و خمسة احداش تلاتة و اتنين ستة
+
+342
+00:52:24,490 --> 00:52:36,210
+او ام
+
+343
+00:52:36,210 --> 00:52:40,950
+ال I total هتكون
+
+344
+00:52:40,950 --> 00:52:45,410
+V على A equivalent
+
+345
+00:52:47,770 --> 00:53:01,210
+من لأ delta y سهل الشغل كتير طيب
+
+346
+00:53:01,210 --> 00:53:06,770
+نعم
+
+347
+00:53:06,770 --> 00:53:12,370
+هدول
+
+348
+00:53:12,370 --> 00:53:17,300
+ع التوازيه كيف ع التوازيه في فيديوهاتهل أطرافهم
+
+349
+00:53:17,300 --> 00:53:20,820
+هاد و هاد و هاد جاي نفس النقطة؟ هل هاد ال short
+
+350
+00:53:20,820 --> 00:53:27,240
+circuit؟ يعني في سلك في مقاومة سفر و واصلة يعني؟
+
+351
+00:53:27,240 --> 00:53:36,620
+مانفعش مش
+
+352
+00:53:36,620 --> 00:53:41,900
+.. مش دايما التحويل بيسهل
+
+353
+00:53:41,900 --> 00:53:43,860
+مش دايما التحويل
+
+354
+00:53:46,550 --> 00:54:00,010
+بسهل الشغل يعني
+
+355
+00:54:00,010 --> 00:54:09,450
+شوف مثال عندي
+
+356
+00:54:09,450 --> 00:54:10,730
+شكل معين
+
+357
+00:55:13,470 --> 00:55:18,790
+انت مش اتوماتيك تشوف ان هذه ال delta تحول ل Y
+
+358
+00:55:18,790 --> 00:55:28,150
+حاسيه الأمور معقدة يعني لاحظ اه اول شي هذي نقطة
+
+359
+00:55:28,150 --> 00:55:33,050
+common صح؟
+
+360
+00:55:33,050 --> 00:55:44,470
+بين 2 و 4 هذي common بين 1 و 3و هذه common بين
+
+361
+00:55:44,470 --> 00:55:52,950
+خمسة و ستة يعني ممكن اعيد رسمها انا بحيث تكون اكثر
+
+362
+00:55:52,950 --> 00:56:00,150
+وضوحا عند هاي واحد
+
+363
+00:56:00,150 --> 00:56:07,410
+مع تلاتة و
+
+364
+00:56:07,410 --> 00:56:08,350
+اتنين مع اربعة
+
+365
+00:56:16,300 --> 00:56:24,060
+هي R واحد مع R تلاتة R واحد مع R تلاتة R اتنين مع
+
+366
+00:56:24,060 --> 00:56:32,440
+R اربعة وخمسة
+
+367
+00:56:32,440 --> 00:56:40,360
+هاي
+
+368
+00:56:40,360 --> 00:56:43,900
+R خمسة R ستة
+
+369
+00:56:47,430 --> 00:56:54,510
+هيك صارت واضحة اكتر صح؟ يعني هتكون هوجد خلنا نسمي
+
+370
+00:56:54,510 --> 00:57:02,210
+equivalent ل واحد و تلاتة RA RA هتكون
+
+371
+00:57:02,210 --> 00:57:11,230
+R واحد R تلاتة على R واحد زاد R تلاتة و RB بين
+
+372
+00:57:11,230 --> 00:57:17,010
+اتنين و اربعة RB بالساوي
+
+373
+00:57:20,360 --> 00:57:36,820
+R2 R4 على R2 زاد R4 يعني هذه هتصير هاي
+
+374
+00:57:36,820 --> 00:57:43,880
+RA هاي RB و برضه خلينا نعمل RC
+
+375
+00:57:50,090 --> 00:57:56,890
+أو اخليها على التالي اخليها زي ما هي R5
+
+376
+00:57:56,890 --> 00:58:03,230
+وR6
+
+377
+00:58:03,230 --> 00:58:08,810
+الان
+
+378
+00:58:08,810 --> 00:58:13,050
+RC عبارة
+
+379
+00:58:13,050 --> 00:58:18,010
+عن RA زاد RB يعني هذه هتصير
+
+380
+00:58:28,450 --> 00:58:36,950
+هي R C R خمسة R ستة تلاتة على التوازن معناه واحد
+
+381
+00:58:36,950 --> 00:58:46,690
+على R equivalent واحد على R C زاد واحد على R خمسة
+
+382
+00:58:46,690 --> 00:58:52,950
+زاد واحد على R ستة ومنها بحسب R equivalent
+
+383
+00:58:57,780 --> 00:59:05,600
+يعني لو دك تعمل هذه .. تعمل أشي زي هيك delta to y
+
+384
+00:59:05,600 --> 00:59:10,900
+بيصير أمور معقدة بدون ده .. يعني .. يعني أول ما
+
+385
+00:59:10,900 --> 00:59:17,020
+تطلع طلع على حكاية ال parallel و ال series يعني
+
+386
+00:59:17,020 --> 00:59:22,820
+هذي هتصير whatever
+
+387
+00:59:22,820 --> 00:59:25,880
+خلينا نفسحهم يعني هدوليك و لا أنت و أنا و أنا صح؟
+
+388
+00:59:38,360 --> 00:59:47,540
+عاملات ليه كمان .. عاملات دلتا .. دلتا و دلتا كالك
+
+389
+00:59:47,540 --> 00:59:55,080
+ع الامور فمش دايما انك تعمل y to delta او delta ل
+
+390
+00:59:55,080 --> 01:00:04,140
+y تحويل هو ال .. الاصلا طيب
+
+391
+01:00:14,620 --> 01:00:20,840
+خلينا نشوف اشي تاني انا بدي اصل ال bridge bridge
+
+392
+01:00:20,840 --> 01:00:21,400
+circuits
+
+393
+01:00:50,400 --> 01:00:53,280
+عندى مجموعة دائرة كهربائية
+
+394
+01:01:22,980 --> 01:01:35,240
+هي عشرة اوم ستة اربع عشرة عشرين تلاتين او اي قيم
+
+395
+01:01:35,240 --> 01:01:43,740
+مش مشكلتين وهي عندي هين power
+
+396
+01:01:43,740 --> 01:01:48,660
+source عشرة بولت plus
+
+397
+01:01:48,660 --> 01:01:50,360
+minus بطارية
+
+398
+01:01:56,510 --> 01:01:59,950
+أول شي اطلع هذه وهذه نقطة وهذه هذي common معناته
+
+399
+01:01:59,950 --> 01:02:06,450
+هذه ممكن اعملها الدائرة بالشكل هذا هذه
+
+400
+01:02:06,450 --> 01:02:16,250
+وهذه common وهذه
+
+401
+01:02:16,250 --> 01:02:21,910
+وهذه common يعني انا احاول ان ارسم الدائرة صح اول
+
+402
+01:02:21,910 --> 01:02:22,110
+شي
+
+403
+01:02:34,850 --> 01:02:46,990
+هذه الستة عشرة اربع عشرين تلاتين في
+
+404
+01:02:46,990 --> 01:02:54,170
+العشرة بدي
+
+405
+01:02:54,170 --> 01:02:58,370
+اعمل واحدة من ال delta زي ما بتحولها ليش ل Y يعني
+
+406
+01:02:58,370 --> 01:02:59,090
+هتصفه
+
+407
+01:03:32,380 --> 01:03:44,500
+هنسمي هذه النقطة واحد اتنين تلاتة هذه ار واحد ار
+
+408
+01:03:44,500 --> 01:03:52,340
+اتنين ار تلاتة هذه عشرة عشرين تلاتين
+
+409
+01:03:56,020 --> 01:04:02,400
+جاي بين العشرة والستة صح؟ ستة في عشرة على مجموع
+
+410
+01:04:02,400 --> 01:04:12,340
+التلاتة دول عشرة زياد عشرة على عشرين تلاتة صح؟ وال
+
+411
+01:04:12,340 --> 01:04:17,720
+R اتنين جاي
+
+412
+01:04:17,720 --> 01:04:25,270
+بين الأربعة والستة أربعة في ستةعلى عشرين يعني one
+
+413
+01:04:25,270 --> 01:04:35,330
+point two ohm و ال R تلاتة زي بين الأربعة في عشرة
+
+414
+01:04:35,330 --> 01:04:47,310
+عشرين نين ohm يعني هذا صفت يعني
+
+415
+01:04:47,310 --> 01:04:55,870
+حكينا R واحد تلاتة ohmار اتنين واحد و عشر اقوم ار
+
+416
+01:04:55,870 --> 01:05:05,110
+تلاتة اتنين اقوم هد و هد ايش معلهم؟ توالي و هد و
+
+417
+01:05:05,110 --> 01:05:08,850
+هد توالي يعني هد هتصفي
+
+418
+01:05:23,640 --> 01:05:27,860
+هذا هتكون واحد و اتنين زاد عشرين هذ واحد و اتنين
+
+419
+01:05:27,860 --> 01:05:35,780
+point اتنين و هذ اتنين و تلاتين و هذ تلاتة ام و هذ
+
+420
+01:05:35,780 --> 01:05:46,160
+ايش عشرة يعني هذ العشر و التلاتة هتصير هذ هذ
+
+421
+01:05:46,160 --> 01:05:53,730
+اللي هي التلاتاش و هذول parallel مع بعضهتكون اتنين
+
+422
+01:05:53,730 --> 01:06:00,330
+و تلاتين في واحد و عشرين point اتنين على اتنين و
+
+423
+01:06:00,330 --> 01:06:03,390
+تلاتين زاد واحد و عشرين point اتنين اللي هي قيمة
+
+424
+01:06:03,390 --> 01:06:07,250
+هذه مضغوط
+
+425
+01:06:07,250 --> 01:06:08,370
+اكم تطلع
+
+426
+01:06:33,430 --> 01:06:41,350
+هذه اتناش وين سبعة خمسة يعني انها هتكون خمسة
+
+427
+01:06:41,350 --> 01:06:47,750
+وعشرين وين سبعة خمسة هو ال total current I هكون
+
+428
+01:06:47,750 --> 01:06:48,290
+عشرة
+
+429
+01:07:04,910 --> 01:07:07,290
+طيب المحاضرة جاي بنكمل، أعطيكوا العفو
+
diff --git a/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/Int37hMiTKo_raw.json b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/Int37hMiTKo_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..c8a939abce44dba719476e8eb7bbf001f563dbac
--- /dev/null
+++ b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/Int37hMiTKo_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2282, "start": 5.2, "end": 22.82, "text": "بسم الله الرحمن الرحيم السلام عليكم ورحمة الله وبركاته هنكمل في مادة القياسات المحاضرة فات بدنا نحكي عن طرق قياس درجة الحرارة وصلنا لاستخدام ال resistance تيربو ميترز", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 21136, 37440, 25894, 24793, 4032, 2288, 35571, 3660, 21984, 4032, 26890, 4117, 9307, 3224, 8032, 1863, 24793, 1211, 8978, 3714, 18513, 3660, 25062, 25528, 3794, 9307, 9673, 5016, 46958, 25720, 6156, 9307, 47525, 8315, 8717, 5016, 4117, 1829, 18871, 23032, 2288, 4587, 12174, 25528, 3794, 11778, 47341, 3660, 21542, 2288, 9640, 3660, 4032, 36520, 8315, 20193, 14851, 9778, 3215, 10943, 2423, 7335, 6055, 13546, 3555, 2407, 3714, 36081, 2288, 11622], "avg_logprob": -0.15683593042194843, "compression_ratio": 1.6761363636363635, "no_speech_prob": 8.344650268554688e-07, "words": [{"start": 5.2, "end": 5.8, "word": "بسم", "probability": 0.854736328125}, {"start": 5.8, "end": 6.08, 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" node", "probability": 0.9609375}, {"start": 685.67, "end": 686.05, "word": " هذه", "probability": 0.477294921875}, {"start": 686.05, "end": 687.65, "word": " لو", "probability": 0.96435546875}, {"start": 687.65, "end": 687.87, "word": " بدى", "probability": 0.72021484375}, {"start": 687.87, "end": 688.23, "word": " بطريقة", "probability": 0.889404296875}, {"start": 688.23, "end": 688.81, "word": " تقليدية", "probability": 0.93994140625}, {"start": 688.81, "end": 689.29, "word": " هحكي", "probability": 0.8651123046875}, {"start": 689.29, "end": 689.51, "word": " I", "probability": 0.98486328125}, {"start": 689.51, "end": 689.97, "word": " total", "probability": 0.8642578125}, {"start": 689.97, "end": 692.79, "word": " I", "probability": 0.97216796875}, {"start": 692.79, "end": 693.23, "word": " total", "probability": 0.88525390625}], "temperature": 1.0}, {"id": 23, "seek": 72425, "start": 695.35, "end": 724.25, "text": "كونت ساوية I1 زائد I2 Flow الداخل بساوية الطالع عند ال node هذه I1 بتساوي I3 زائد I4", "tokens": [30544, 2655, 8608, 995, 2407, 10632, 286, 16, 30767, 16373, 3215, 286, 17, 32792, 32748, 47283, 1211, 4724, 3794, 995, 2407, 10632, 41950, 6027, 3615, 43242, 2423, 9984, 29538, 286, 16, 39894, 3794, 995, 45865, 286, 18, 30767, 16373, 3215, 286, 19], "avg_logprob": -0.27997819212980046, "compression_ratio": 1.2912621359223302, "no_speech_prob": 0.0, "words": [{"start": 695.35, "end": 695.75, "word": "كونت", "probability": 0.40203857421875}, {"start": 695.75, "end": 696.31, "word": " ساوية", "probability": 0.8621826171875}, {"start": 696.31, "end": 699.11, "word": " I1", "probability": 0.4708251953125}, {"start": 699.11, "end": 701.49, "word": " زائد", "probability": 0.6773274739583334}, {"start": 701.49, "end": 702.49, "word": " I2", "probability": 0.979248046875}, {"start": 702.49, "end": 703.65, "word": " Flow", "probability": 0.2083740234375}, {"start": 703.65, "end": 706.95, "word": " الداخل", "probability": 0.8544921875}, {"start": 706.95, "end": 707.35, "word": " بساوية", "probability": 0.833984375}, {"start": 707.35, "end": 707.79, "word": " الطالع", "probability": 0.8388671875}, {"start": 707.79, "end": 708.81, "word": " عند", "probability": 0.9052734375}, {"start": 708.81, "end": 708.97, "word": " ال", "probability": 0.38623046875}, {"start": 708.97, "end": 709.15, "word": " node", "probability": 0.7236328125}, {"start": 709.15, "end": 709.59, "word": " هذه", "probability": 0.454345703125}, {"start": 709.59, "end": 715.45, "word": " I1", "probability": 0.965087890625}, {"start": 715.45, "end": 718.95, "word": " بتساوي", "probability": 0.8310546875}, {"start": 718.95, "end": 721.67, "word": " I3", "probability": 0.969482421875}, {"start": 721.67, "end": 723.57, "word": " زائد", "probability": 0.9109700520833334}, {"start": 723.57, "end": 724.25, "word": " I4", "probability": 0.996337890625}], "temperature": 1.0}, {"id": 24, "seek": 75702, "start": 729.76, "end": 757.02, "text": "وعند ال node هذه I2 زي I3 بالسواء I5 عند ال node هذه I4 زي I5 بالسواء I total", "tokens": [45367, 41260, 2423, 9984, 29538, 286, 17, 30767, 1829, 286, 18, 20666, 3794, 2407, 16606, 286, 20, 43242, 2423, 9984, 29538, 286, 19, 30767, 1829, 286, 20, 20666, 3794, 2407, 16606, 286, 3217], "avg_logprob": -0.22127757221460342, "compression_ratio": 1.435897435897436, "no_speech_prob": 0.0, "words": [{"start": 729.76, "end": 730.16, "word": "وعند", "probability": 0.5736083984375}, {"start": 730.16, "end": 730.3, "word": " ال", "probability": 0.79736328125}, {"start": 730.3, "end": 730.5, "word": " node", "probability": 0.83837890625}, {"start": 730.5, "end": 730.92, "word": " هذه", "probability": 0.552734375}, {"start": 730.92, "end": 734.84, "word": " I2", "probability": 0.6259765625}, {"start": 734.84, "end": 735.04, "word": " زي", "probability": 0.391082763671875}, {"start": 735.04, "end": 735.84, "word": " I3", "probability": 0.914306640625}, {"start": 735.84, "end": 741.76, "word": " بالسواء", "probability": 0.64056396484375}, {"start": 741.76, "end": 742.36, "word": " I5", "probability": 0.964111328125}, {"start": 742.36, "end": 745.3, "word": " عند", "probability": 0.76171875}, {"start": 745.3, "end": 745.46, "word": " ال", "probability": 0.94140625}, {"start": 745.46, "end": 745.64, "word": " node", "probability": 0.96728515625}, {"start": 745.64, "end": 746.08, "word": " هذه", "probability": 0.93603515625}, {"start": 746.08, "end": 749.98, "word": " I4", "probability": 0.991943359375}, {"start": 749.98, "end": 753.18, "word": " زي", "probability": 0.885986328125}, {"start": 753.18, "end": 753.98, "word": " I5", "probability": 0.9951171875}, {"start": 753.98, "end": 756.4, "word": " بالسواء", "probability": 0.9549560546875}, {"start": 756.4, "end": 756.62, "word": " I", "probability": 0.97900390625}, {"start": 756.62, "end": 757.02, "word": " total", "probability": 0.6474609375}], "temperature": 1.0}, {"id": 25, "seek": 78577, "start": 759.29, "end": 785.77, "text": "كم مجهول عنده؟ ست مجهول كم معدلة؟ أربعة معناته محتاج كمان معدلتين هعمل two loops هعمل يعني أنا هيك اللي صويته يعني", "tokens": [4117, 2304, 3714, 7435, 3224, 12610, 43242, 3224, 22807, 8608, 2655, 3714, 7435, 3224, 12610, 9122, 2304, 20449, 3215, 37977, 22807, 5551, 25513, 27884, 3714, 3615, 8315, 47395, 3714, 33753, 26108, 9122, 2304, 7649, 20449, 3215, 1211, 2655, 9957, 8032, 25957, 1211, 732, 16121, 8032, 25957, 1211, 37495, 22653, 41850, 39896, 4117, 13672, 1829, 20328, 2407, 36081, 3224, 37495, 22653], "avg_logprob": -0.2556352439473887, "compression_ratio": 1.5426356589147288, "no_speech_prob": 0.0, "words": [{"start": 759.29, "end": 759.55, "word": "كم", "probability": 0.5367431640625}, {"start": 759.55, "end": 759.85, "word": " مجهول", "probability": 0.9849853515625}, {"start": 759.85, "end": 763.35, "word": " عنده؟", "probability": 0.7555338541666666}, {"start": 763.35, "end": 764.43, "word": " ست", "probability": 0.77197265625}, {"start": 764.43, "end": 764.95, "word": " مجهول", "probability": 0.7716064453125}, {"start": 764.95, "end": 765.59, "word": " كم", "probability": 0.7122802734375}, {"start": 765.59, "end": 767.43, "word": " معدلة؟", "probability": 0.7021484375}, {"start": 767.43, "end": 769.93, "word": " أربعة", "probability": 0.7888997395833334}, {"start": 769.93, "end": 771.47, "word": " معناته", "probability": 0.669921875}, {"start": 771.47, "end": 771.87, "word": " محتاج", "probability": 0.98193359375}, {"start": 771.87, "end": 772.79, "word": " كمان", "probability": 0.9890950520833334}, {"start": 772.79, "end": 774.69, "word": " معدلتين", "probability": 0.8794921875}, {"start": 774.69, "end": 777.39, "word": " هعمل", "probability": 0.9739583333333334}, {"start": 777.39, "end": 778.27, "word": " two", "probability": 0.8779296875}, {"start": 778.27, "end": 778.63, "word": " loops", "probability": 0.974609375}, {"start": 778.63, "end": 780.15, "word": " هعمل", "probability": 0.8976236979166666}, {"start": 780.15, "end": 784.45, "word": " يعني", "probability": 0.6287841796875}, {"start": 784.45, "end": 784.91, "word": " أنا", "probability": 0.4091796875}, {"start": 784.91, "end": 785.03, "word": " هيك", "probability": 0.741943359375}, {"start": 785.03, "end": 785.13, "word": " اللي", "probability": 0.945556640625}, {"start": 785.13, "end": 785.57, "word": " صويته", "probability": 0.748291015625}, {"start": 785.57, "end": 785.77, "word": " يعني", "probability": 0.903564453125}], "temperature": 1.0}, {"id": 26, "seek": 81658, "start": 788.42, "end": 816.58, "text": "عملته analysis لان هعمل two loops هاي ال loop الأولانية و هاي ال loop التاني في ال loop هذه انا بحكي في ال loop هذه ال total voltage سواء صفر", "tokens": [25957, 1211, 47395, 5215, 5296, 7649, 8032, 25957, 1211, 732, 16121, 8032, 47302, 2423, 6367, 16247, 12610, 7649, 10632, 4032, 8032, 47302, 2423, 6367, 16712, 7649, 1829, 8978, 2423, 6367, 29538, 1975, 8315, 4724, 5016, 4117, 1829, 8978, 2423, 6367, 29538, 2423, 3217, 8352, 8608, 2407, 16606, 20328, 5172, 2288], "avg_logprob": 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مصوفة", "probability": 0.750732421875}, {"start": 1004.16, "end": 1005.94, "word": " عندي", "probability": 0.7291259765625}, {"start": 1005.94, "end": 1006.12, "word": " هنا", "probability": 0.6298828125}, {"start": 1006.12, "end": 1007.08, "word": " واحد", "probability": 0.9833984375}, {"start": 1007.08, "end": 1008.74, "word": " عندي", "probability": 0.6685791015625}, {"start": 1008.74, "end": 1009.02, "word": " عندي", "probability": 0.6373291015625}, {"start": 1009.02, "end": 1009.24, "word": " هنا", "probability": 0.68115234375}, {"start": 1009.24, "end": 1010.2, "word": " واحد", "probability": 0.984375}, {"start": 1010.2, "end": 1012.18, "word": " واحد", "probability": 0.93310546875}, {"start": 1012.18, "end": 1014.06, "word": " سفر", "probability": 0.8421223958333334}, {"start": 1014.06, "end": 1015.0, "word": " هذه", "probability": 0.5927734375}, {"start": 1015.0, "end": 1015.46, "word": " تلاتة", "probability": 0.94677734375}, {"start": 1015.46, "end": 1015.8, "word": " صح", "probability": 0.9931640625}, {"start": 1015.8, "end": 1017.5, "word": " سفر", "probability": 0.7596028645833334}, {"start": 1017.5, "end": 1018.18, "word": " اربعة", "probability": 0.9044596354166666}, {"start": 1018.18, "end": 1020.56, "word": " خمسة", "probability": 0.9942626953125}, {"start": 1020.56, "end": 1022.08, "word": " سالب", "probability": 0.94677734375}, {"start": 1022.08, "end": 1022.52, "word": " واحد", "probability": 0.986572265625}], "temperature": 1.0}, {"id": 34, "seek": 104429, "start": 1023.99, "end": 1044.29, "text": "التانى عندهين واحد صفر سالب واحد سالب واحد صفر صفر التالتة صفر واحد واحد صفر سالب واحد صفر", "tokens": [6027, 2655, 7649, 7578, 43242, 3224, 9957, 36764, 24401, 20328, 5172, 2288, 8608, 6027, 3555, 36764, 24401, 8608, 6027, 3555, 36764, 24401, 20328, 5172, 2288, 20328, 5172, 2288, 16712, 6027, 2655, 3660, 20328, 5172, 2288, 36764, 24401, 36764, 24401, 20328, 5172, 2288, 8608, 6027, 3555, 36764, 24401, 20328, 5172, 2288], "avg_logprob": 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0.8402099609375}, {"start": 1035.77, "end": 1036.87, "word": " صفر", "probability": 0.9710286458333334}, {"start": 1036.87, "end": 1038.43, "word": " واحد", "probability": 0.981201171875}, {"start": 1038.43, "end": 1040.25, "word": " واحد", "probability": 0.979248046875}, {"start": 1040.25, "end": 1041.69, "word": " صفر", "probability": 0.990234375}, {"start": 1041.69, "end": 1042.73, "word": " سالب", "probability": 0.93017578125}, {"start": 1042.73, "end": 1043.27, "word": " واحد", "probability": 0.99658203125}, {"start": 1043.27, "end": 1044.29, "word": " صفر", "probability": 0.9959309895833334}], "temperature": 1.0}, {"id": 35, "seek": 107752, "start": 1050.64, "end": 1077.52, "text": "الربع صفر صفر صفر واحد واحد واحد سالب واحد الخمسة سالب خمسة عشرة سالب ستة تلت أصفر", "tokens": [6027, 25513, 3615, 20328, 5172, 2288, 20328, 5172, 2288, 20328, 5172, 2288, 36764, 24401, 36764, 24401, 36764, 24401, 8608, 6027, 3555, 36764, 24401, 33962, 2304, 3794, 3660, 8608, 6027, 3555, 16490, 2304, 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1065.3, "end": 1068.36, "word": " الخمسة", "probability": 0.861572265625}, {"start": 1068.36, "end": 1069.02, "word": " سالب", "probability": 0.9015299479166666}, {"start": 1069.02, "end": 1070.52, "word": " خمسة", "probability": 0.9912109375}, {"start": 1070.52, "end": 1072.04, "word": " عشرة", "probability": 0.93994140625}, {"start": 1072.04, "end": 1074.28, "word": " سالب", "probability": 0.9612630208333334}, {"start": 1074.28, "end": 1075.46, "word": " ستة", "probability": 0.9910481770833334}, {"start": 1075.46, "end": 1077.1, "word": " تلت", "probability": 0.8863932291666666}, {"start": 1077.1, "end": 1077.52, "word": " أصفر", "probability": 0.7066650390625}], "temperature": 1.0}, {"id": 36, "seek": 110405, "start": 1082.21, "end": 1104.05, "text": "السادسة صفر صفر ستة سالب أربعة ستة صفر في I واحد", "tokens": [6027, 3794, 18513, 3794, 3660, 20328, 5172, 2288, 20328, 5172, 2288, 8608, 2655, 3660, 8608, 6027, 3555, 5551, 25513, 27884, 8608, 2655, 3660, 20328, 5172, 2288, 8978, 286, 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"word": " أربعة", "probability": 0.8391927083333334}, {"start": 1113.33, "end": 1114.67, "word": " I", "probability": 0.98583984375}, {"start": 1114.67, "end": 1115.91, "word": " خمسة", "probability": 0.9835205078125}, {"start": 1115.91, "end": 1116.75, "word": " I", "probability": 0.95947265625}, {"start": 1116.75, "end": 1117.31, "word": " total", "probability": 0.6142578125}, {"start": 1117.31, "end": 1121.71, "word": " بتساوي", "probability": 0.8087158203125}, {"start": 1121.71, "end": 1125.23, "word": " ايش؟", "probability": 0.63494873046875}, {"start": 1125.23, "end": 1132.33, "word": " يعني", "probability": 0.85302734375}, {"start": 1132.33, "end": 1132.63, "word": " هذه", "probability": 0.46630859375}, {"start": 1132.63, "end": 1133.03, "word": " A", "probability": 0.484130859375}, {"start": 1133.03, "end": 1135.61, "word": " هذه", "probability": 0.7685546875}, {"start": 1135.61, "end": 1136.01, "word": " X", "probability": 0.966796875}], "temperature": 1.0}, {"id": 38, "seek": 116695, "start": 1137.91, "end": 1166.95, "text": "هذه C أو B يعني you can solve for I واحد I اتنين I تلاتة I أربعة", "tokens": [3224, 24192, 383, 34051, 363, 37495, 22653, 291, 393, 5039, 337, 286, 36764, 24401, 286, 1975, 2655, 1863, 9957, 286, 6055, 1211, 9307, 3660, 286, 5551, 25513, 27884], "avg_logprob": -0.32677802957337476, "compression_ratio": 1.010989010989011, "no_speech_prob": 0.0, "words": [{"start": 1137.91, "end": 1138.39, "word": "هذه", "probability": 0.62451171875}, {"start": 1138.39, "end": 1140.83, "word": " C", "probability": 0.303466796875}, {"start": 1140.83, "end": 1141.07, "word": " أو", "probability": 0.6708984375}, {"start": 1141.07, "end": 1141.35, "word": " B", "probability": 0.68115234375}, {"start": 1141.35, "end": 1146.73, "word": " يعني", "probability": 0.5135498046875}, {"start": 1146.73, "end": 1148.33, "word": " you", "probability": 0.64453125}, {"start": 1148.33, "end": 1148.53, "word": " can", "probability": 0.9658203125}, {"start": 1148.53, "end": 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"text": "هتكون ر بي in parallel مع محصلة a و c ر بي في ر ا زاد ر سي على مجموعهم على ر ا زاد ر بي زاد ر سي هتكون ر واحد زاد ر تلاتة", "tokens": [3224, 2655, 30544, 12602, 4724, 1829, 294, 8952, 20449, 3714, 5016, 36520, 3660, 257, 4032, 269, 12602, 4724, 1829, 8978, 12602, 1975, 30767, 18513, 12602, 8608, 1829, 15844, 3714, 7435, 2304, 45367, 16095, 15844, 12602, 1975, 30767, 18513, 12602, 4724, 1829, 30767, 18513, 12602, 8608, 1829, 8032, 2655, 30544, 12602, 36764, 24401, 30767, 18513, 12602, 6055, 1211, 9307, 3660], "avg_logprob": -0.23645833457509677, "compression_ratio": 1.6198347107438016, "no_speech_prob": 0.0, "words": [{"start": 1748.03, "end": 1748.45, "word": "هتكون", "probability": 0.7779947916666666}, {"start": 1748.45, "end": 1748.67, "word": " ر", "probability": 0.1265869140625}, {"start": 1748.67, "end": 1749.29, "word": " بي", "probability": 0.872314453125}, {"start": 1749.29, "end": 1749.47, "word": " in", "probability": 0.59521484375}, {"start": 1749.47, "end": 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{"start": 3962.67, "end": 3962.83, "word": " اللي", "probability": 0.83544921875}, {"start": 3962.83, "end": 3962.97, "word": " هي", "probability": 0.9267578125}, {"start": 3962.97, "end": 3963.39, "word": " قيمة", "probability": 0.8976236979166666}, {"start": 3963.39, "end": 3963.69, "word": " هذه", "probability": 0.67431640625}, {"start": 3963.69, "end": 3967.25, "word": " مضغوط", "probability": 0.78310546875}, {"start": 3967.25, "end": 3967.93, "word": " اكم", "probability": 0.5064697265625}, {"start": 3967.93, "end": 3968.37, "word": " تطلع", "probability": 0.935302734375}], "temperature": 1.0}, {"id": 126, "seek": 400829, "start": 3993.43, "end": 4008.29, "text": "هذه اتناش وين سبعة خمسة يعني انها هتكون خمسة وعشرين وين سبعة خمسة هو ال total current I هكون عشرة", "tokens": [3224, 24192, 1975, 2655, 1863, 33599, 4032, 9957, 8608, 3555, 27884, 16490, 2304, 3794, 3660, 37495, 22653, 16472, 11296, 8032, 2655, 30544, 16490, 2304, 3794, 3660, 4032, 3615, 46309, 9957, 4032, 9957, 8608, 3555, 27884, 16490, 2304, 3794, 3660, 31439, 2423, 3217, 2190, 286, 8032, 30544, 6225, 8592, 25720], "avg_logprob": -0.21749999850988389, "compression_ratio": 1.4210526315789473, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 3993.43, "end": 3993.75, "word": "هذه", "probability": 0.490234375}, {"start": 3993.75, "end": 3994.31, "word": " اتناش", "probability": 0.7822265625}, {"start": 3994.31, "end": 3996.67, "word": " وين", "probability": 0.4117431640625}, {"start": 3996.67, "end": 3997.07, "word": " سبعة", "probability": 0.8992513020833334}, {"start": 3997.07, "end": 3997.79, "word": " خمسة", "probability": 0.939453125}, {"start": 3997.79, "end": 3999.71, "word": " يعني", "probability": 0.75830078125}, {"start": 3999.71, "end": 3999.89, "word": " انها", "probability": 0.748779296875}, {"start": 3999.89, "end": 4000.43, "word": " هتكون", "probability": 0.9195963541666666}, {"start": 4000.43, "end": 4001.35, "word": " خمسة", "probability": 0.92431640625}, {"start": 4001.35, "end": 4001.93, "word": " وعشرين", "probability": 0.79345703125}, {"start": 4001.93, "end": 4003.85, "word": " وين", "probability": 0.915771484375}, {"start": 4003.85, "end": 4004.15, "word": " سبعة", "probability": 0.9798177083333334}, {"start": 4004.15, "end": 4004.65, "word": " خمسة", "probability": 0.9808349609375}, {"start": 4004.65, "end": 4004.79, "word": " هو", "probability": 0.41064453125}, {"start": 4004.79, "end": 4004.91, "word": " ال", "probability": 0.9091796875}, {"start": 4004.91, "end": 4005.11, "word": " total", "probability": 0.79052734375}, {"start": 4005.11, "end": 4005.63, "word": " current", "probability": 0.88037109375}, {"start": 4005.63, "end": 4006.15, "word": " I", "probability": 0.87548828125}, {"start": 4006.15, "end": 4007.75, "word": " هكون", "probability": 0.871337890625}, {"start": 4007.75, "end": 4008.29, "word": " عشرة", "probability": 0.9267578125}], "temperature": 1.0}, {"id": 127, "seek": 402729, "start": 4024.91, "end": 4027.29, "text": "طيب المحاضرة جاي بنكمل، أعطيكوا العفو", "tokens": [9566, 1829, 3555, 9673, 5016, 46958, 25720, 10874, 47302, 44945, 24793, 1211, 12399, 5551, 3615, 9566, 1829, 4117, 14407, 18863, 5172, 2407], "avg_logprob": -0.22010869953943335, "compression_ratio": 1.0, "no_speech_prob": 0.0, "words": [{"start": 4024.91, "end": 4025.29, "word": "طيب", "probability": 0.98974609375}, {"start": 4025.29, "end": 4025.91, "word": " المحاضرة", "probability": 0.9658203125}, {"start": 4025.91, "end": 4026.17, "word": " جاي", "probability": 0.6416015625}, {"start": 4026.17, "end": 4026.73, "word": " بنكمل،", "probability": 0.78192138671875}, {"start": 4026.73, "end": 4026.99, "word": " أعطيكوا", "probability": 0.7839762369791666}, {"start": 4026.99, "end": 4027.29, "word": " العفو", "probability": 0.8048502604166666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 4027.89575, "duration_after_vad": 3216.7662499999833}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/Rq3cMvugUwY_raw.srt b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/Rq3cMvugUwY_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d8c73b205e8732ca4b2c5045e82b22c8d300fff7
--- /dev/null
+++ b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/Rq3cMvugUwY_raw.srt
@@ -0,0 +1,2432 @@
+1
+00:00:05,150 --> 00:00:08,130
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:08,130 --> 00:00:13,310
+وبركاته هنكمل في مادة القياصات chapter تلاتة تقييم
+
+3
+00:00:13,310 --> 00:00:18,050
+و أرض نتاج التجارب المحاضرة الفاترة حكينا عن
+
+4
+00:00:18,050 --> 00:00:22,130
+التجارب اللي بيكون عدد القراءات فيها كتير أكتر من
+
+5
+00:00:22,130 --> 00:00:25,930
+تلاتين حكينا في حالة القراءات كان عددها كبير يعني
+
+6
+00:00:25,930 --> 00:00:32,510
+أكبر من تلاتين بيكون ال .. ال distribution ال
+
+7
+00:00:32,510 --> 00:00:36,930
+distribution لل sampleقريب كتير من ال distribution
+
+8
+00:00:36,930 --> 00:00:41,750
+لل population عشان هيك استخدمنا ال z distribution
+
+9
+00:00:41,750 --> 00:00:46,850
+لتمثيل البيانات العددها كبير اليوم هنحكي عن
+
+10
+00:00:46,850 --> 00:00:50,610
+البيانات اللي عدد ال sample بتكون صغيرة يعني عدد
+
+11
+00:00:50,610 --> 00:00:59,830
+القرارات بيكون أقل من تلتين الان
+
+12
+00:00:59,830 --> 00:01:04,410
+احنا نرجع للمعادلة للمحاضرة الفاتت حكينا ال z
+
+13
+00:01:10,200 --> 00:01:18,760
+الـ z بالساوية
+
+14
+00:01:18,760 --> 00:01:34,120
+x bar minus mu على sigma x bar بالساوية
+
+15
+00:01:34,120 --> 00:01:38,780
+x bar minus mu على
+
+16
+00:01:40,440 --> 00:01:48,900
+سيجما على جزر N لان
+
+17
+00:01:48,900 --> 00:01:58,200
+لما تكون البيانات عددها كبير بتكون السيجما بتاعة
+
+18
+00:01:58,200 --> 00:02:01,680
+ال population سيجما بتاعة ال population بتكون
+
+19
+00:02:01,680 --> 00:02:07,940
+قريبة من ال standard deviationلل sample معناته
+
+20
+00:02:07,940 --> 00:02:11,240
+هبقى بيضلوا ايش اللي هو Gaussian elimination او
+
+21
+00:02:11,240 --> 00:02:16,380
+normal distribution لكن في حالة البنات كان عددها
+
+22
+00:02:16,380 --> 00:02:24,140
+كبير احنا في الآخر اولش ال signal هذه لل
+
+23
+00:02:24,140 --> 00:02:29,400
+population انا ماكن عارفها يعني
+
+24
+00:02:29,400 --> 00:02:34,040
+ناخد مثلا حالة مرضى السكر في قطاع غزةعدده مثلا
+
+25
+00:02:34,040 --> 00:02:39,940
+نحكي ميت ألف هل انا عندي كل البيانات هذه عشان اجيب
+
+26
+00:02:39,940 --> 00:02:42,200
+ال standard deviation بتاعها فال standard
+
+27
+00:02:42,200 --> 00:02:47,400
+deviation لل population مش معروف لكن لما يكون عدد
+
+28
+00:02:47,400 --> 00:02:51,960
+البيانات كبير اكبر من تلاتين وانا عندي بيانات انا
+
+29
+00:02:51,960 --> 00:02:59,640
+بحسب ال standard deviation للعينة هذا يكون قريبمن
+
+30
+00:02:59,640 --> 00:03:03,920
+ال standard deviation لل population لكن لما ان
+
+31
+00:03:03,920 --> 00:03:14,520
+العينة تصغر تصير صغيرة و احسب ال Sx بتكون يعني
+
+32
+00:03:14,520 --> 00:03:18,940
+ابعيدة عن ال standard deviation او تختلف عن ال
+
+33
+00:03:18,940 --> 00:03:22,580
+standard deviation بتاع ال population معناته انا
+
+34
+00:03:22,580 --> 00:03:29,880
+بكون في عندي بعمل divisionلدستربيوشن على دستربيوشن
+
+35
+00:03:29,880 --> 00:03:36,260
+دستربيوشن هذا طبعا لان مازال ال Sx بتاعة ال sample
+
+36
+00:03:36,260 --> 00:03:39,380
+مختلفة يعني لو انا اخدت مثلا عندي العينة ال
+
+37
+00:03:39,380 --> 00:03:44,500
+population مليون اخدت عينة مية و حسبت ال standard
+
+38
+00:03:44,500 --> 00:03:48,020
+deviation اللي هيطلع قيمة اللي اخدت كمان مية تانية
+
+39
+00:03:48,840 --> 00:03:52,360
+هيطلع نفس ال standard deviation؟ هيتلعه مختلف، لو
+
+40
+00:03:52,360 --> 00:03:55,300
+كانت عينة تالتة كمان مية، الموضوع هطلع standard
+
+41
+00:03:55,300 --> 00:03:58,860
+deviation،معناته ال standard deviation للعينات
+
+42
+00:03:58,860 --> 00:04:04,780
+بيعمل distribution، بيعمل distribution، فنفس ال
+
+43
+00:04:04,780 --> 00:04:11,200
+standard deviation في إيش؟صار random .. random
+
+44
+00:04:11,200 --> 00:04:16,120
+variable it shows a distribution وبالتالي هذا بطل
+
+45
+00:04:16,120 --> 00:04:20,040
+normal distribution الآن مش هنخش في التفاصيل
+
+46
+00:04:20,040 --> 00:04:24,880
+واجدوا انه ال distribution في الحالة هذه في ال low
+
+47
+00:04:24,880 --> 00:04:32,320
+sample size يوصف بما يسمى ال T student
+
+48
+00:04:32,320 --> 00:04:38,140
+اسمه هيك T student اللي هو distribution
+
+49
+00:04:42,350 --> 00:04:46,730
+الـ T distribution أو الـ probability density
+
+50
+00:04:46,730 --> 00:04:49,670
+function للـ T ديستربويش المُعطَب للعلاقة هذه الـ
+
+51
+00:04:49,670 --> 00:04:53,530
+Gamma function لـ Nu زاد واحد على اتنين في واحد
+
+52
+00:04:53,530 --> 00:04:57,270
+زاد T square على Nu قُص minus Nu plus واحد على
+
+53
+00:04:57,270 --> 00:05:01,230
+اتنين على جزر تربيه لـ Nu باي في Gamma function لـ
+
+54
+00:05:01,230 --> 00:05:05,660
+Nu على اتنينلأن لينيو هي degrees of freedom بتسمى
+
+55
+00:05:05,660 --> 00:05:10,100
+عدد القراءات ناقص واحد لينيو هي degrees of freedom
+
+56
+00:05:10,100 --> 00:05:17,880
+عن قراءات ناقص واحد اذا
+
+57
+00:05:17,880 --> 00:05:25,580
+انت عملنا plot ل ال T distribution طبعا ال T
+
+58
+00:05:25,580 --> 00:05:28,660
+distribution
+
+59
+00:05:28,660 --> 00:05:32,590
+سيمتريك حوالين ال Y axisإذا كانت ال degrees of
+
+60
+00:05:32,590 --> 00:05:37,610
+freedom واحد يعني عد القراءات أكم قراءة ال new
+
+61
+00:05:37,610 --> 00:05:40,750
+بالساوية إيه ناقص واحد إذا ال new واحد ان شو
+
+62
+00:05:40,750 --> 00:05:48,210
+الساوية اتنين إذا ال new ستة يعني أن كم سبعة إذا
+
+63
+00:05:48,210 --> 00:05:53,090
+ال new عشرة يعني أن بالساوية إحداش الآن ال curve
+
+64
+00:05:53,090 --> 00:05:56,930
+هذا هو ال standard normal distribution لحظة كل
+
+65
+00:05:56,930 --> 00:06:01,230
+معدد القراءات بالزيدكل ما انا باقترب من ال normal
+
+66
+00:06:01,230 --> 00:06:06,530
+distribution يعني as a new approaches infinity
+
+67
+00:06:06,530 --> 00:06:09,170
+يعني انا حاجبت كل population بيصير ال population
+
+68
+00:06:09,170 --> 00:06:13,550
+هذا normal distribution لحظة تكون عاجل القراءات
+
+69
+00:06:13,550 --> 00:06:14,570
+صغيرة
+
+70
+00:06:19,150 --> 00:06:23,150
+ببطل ال curve امركز في النص .. ببطل ال curve امركز
+
+71
+00:06:23,150 --> 00:06:26,630
+بيصير يفرد عليا للجناب .. بيصير يفرد على الجناب
+
+72
+00:06:26,630 --> 00:06:31,410
+لان في قراءات شاردة كتير يعني لما عند ال new
+
+73
+00:06:31,410 --> 00:06:36,550
+بالساوية واحد لاحظوا فرد اكتر على الجانب خد ال new
+
+74
+00:06:36,550 --> 00:06:41,150
+بالساوية ستة ضم اكتر ال curve عندك خد ال new عشرة
+
+75
+00:06:41,150 --> 00:06:44,390
+خمس عشرة عشرين تلاتين اربعين بدرم اكتر
+
+76
+00:06:48,120 --> 00:06:51,700
+عشانك ال confidence interval لو انا احكي 500%
+
+77
+00:06:51,700 --> 00:06:57,000
+confidence interval في حالة ال z distribution كانت
+
+78
+00:06:57,000 --> 00:07:03,660
+بين 1.96 minus 1.96 sigma و plus 1.96 sigma لكن في
+
+79
+00:07:03,660 --> 00:07:09,040
+حالة ال z distribution لأ حطر اطلع على برا شوية
+
+80
+00:07:09,040 --> 00:07:13,040
+لأن المساحات هنا صارت عند ال areas هنا اكترصح
+
+81
+00:07:13,040 --> 00:07:17,940
+فهتتر بطلت ال 5% كون في this interval تتراوح بين
+
+82
+00:07:17,940 --> 00:07:29,880
+minus 1.96 sigma و plus 1.96 sigma ال
+
+83
+00:07:29,880 --> 00:07:36,220
+T distribution يوصف
+
+84
+00:07:36,220 --> 00:07:40,820
+من خلال لازم كل عدد اعرف عدد القراءات او ما يسمى
+
+85
+00:07:41,970 --> 00:07:47,130
+اللي هي degrees of freedom in you و ال confidence
+
+86
+00:07:47,130 --> 00:07:51,290
+يرمز بالرمز T alpha و nu
+
+87
+00:08:31,990 --> 00:08:48,670
+هذه الـ T Alpha و New Alpha أو
+
+88
+00:08:48,670 --> 00:08:57,110
+العكس هذه المساحة الـ Area اللي هي Alpha المعنى
+
+89
+00:08:57,110 --> 00:09:01,990
+عندما نحكي عن الـ Tالـ new alpha بيحكي عن ال
+
+90
+00:09:01,990 --> 00:09:09,910
+probability أنه ال T تكون أكبر أو يساوي ال T new
+
+91
+00:09:09,910 --> 00:09:14,770
+and alpha يعني أنا بحكي عن مساحة بين ال area
+
+92
+00:09:14,770 --> 00:09:18,390
+between
+
+93
+00:09:22,830 --> 00:09:37,770
+T أكبر من T نيو ألفة و إيش infinity هذا
+
+94
+00:09:37,770 --> 00:09:45,070
+في حالة one sided إذا كان two sided إذا
+
+95
+00:09:45,070 --> 00:09:45,870
+كان two sided
+
+96
+00:09:54,420 --> 00:09:57,840
+بحكي عن ال area هذه زاد ال area هذه is a two sided
+
+97
+00:09:57,840 --> 00:10:04,060
+ال area هذه زاد ال area هذه برضه نفس الشيء ال ميو
+
+98
+00:10:04,060 --> 00:10:10,440
+ال main value لل population ال main value لل
+
+99
+00:10:10,440 --> 00:10:21,280
+population ميو بالساوية x bar plus or minus t في
+
+100
+00:10:21,280 --> 00:10:25,920
+حالة two sided two الف على اتنينو الـ U فى ال
+
+101
+00:10:25,920 --> 00:10:43,120
+standard deviation لسة سامبل على جزر N طبعا
+
+102
+00:10:43,120 --> 00:10:50,500
+إذا بحكي أنا عندي confidence 95% confidence
+
+103
+00:10:54,360 --> 00:11:00,020
+بتكون الف أكم تساوي خمسة
+
+104
+00:11:00,020 --> 00:11:05,120
+في المية صح؟معناه
+
+105
+00:11:05,120 --> 00:11:10,720
+ألف على تان أكم تساوي يعني
+
+106
+00:11:10,720 --> 00:11:18,400
+نصف في المية طبعا
+
+107
+00:11:18,400 --> 00:11:23,640
+في table في الكتاب لو بده أحسب
+
+108
+00:11:31,260 --> 00:11:43,600
+T مثلا four اللي هي alpha point oh five و
+
+109
+00:11:43,600 --> 00:11:50,560
+degrees of freedom خمسة اتنين
+
+110
+00:11:50,560 --> 00:11:54,200
+اتنين
+
+111
+00:11:54,200 --> 00:11:58,300
+point صفر واحد خمسة
+
+112
+00:12:00,530 --> 00:12:04,890
+اللي هدا شو يساوي الاتنين الاتنين point صفر واحد
+
+113
+00:12:04,890 --> 00:12:10,210
+خمسة بيساوي ال area هذه صح ال
+
+114
+00:12:10,210 --> 00:12:28,110
+area من T point صفر خمسة ل infinity طيب
+
+115
+00:12:36,080 --> 00:12:50,200
+هذا مكرر اتطلع
+
+116
+00:12:50,200 --> 00:12:54,340
+على ال figure اول
+
+117
+00:12:54,340 --> 00:13:02,720
+figure هنا تي الفا و نيو ال confidence interval
+
+118
+00:13:03,980 --> 00:13:09,920
+اللي هي إيش؟ هتكون على الشمال هذا
+
+119
+00:13:09,920 --> 00:13:13,840
+إذا كانت right-handed إذا left-handed ال
+
+120
+00:13:13,840 --> 00:13:15,500
+confidence interval هتكون على اليمين يعني أنا
+
+121
+00:13:15,500 --> 00:13:20,840
+بختبر قيمة أقل من هذه القيمة إذا كان two-sided
+
+122
+00:13:20,840 --> 00:13:25,300
+بختبر إن القيمة موجودة بين .. بين .. بين two
+
+123
+00:13:25,300 --> 00:13:29,360
+values يعني إذا كانت برا ال two برا ال range هذا
+
+124
+00:13:29,360 --> 00:13:31,480
+بتكون خارج النطاق
+
+125
+00:13:36,230 --> 00:13:43,550
+طيب نشوف مثال ال twelve values in a sample have an
+
+126
+00:13:43,550 --> 00:13:49,950
+average of x bar عنده ماشهر قراءة لعينة متوسط
+
+127
+00:13:49,950 --> 00:13:56,510
+القراءات عددها مجموعة على العدد صح؟ x bar
+
+128
+00:13:56,510 --> 00:14:02,450
+والستندرج اللي فيها شغال القراءات Sx الستندرج
+
+129
+00:14:02,450 --> 00:14:09,030
+للقراءات SxWhat is the 95% confidence interval for
+
+130
+00:14:09,030 --> 00:14:14,670
+the true mean value of mu؟ احنا حكينا الالفة ايش
+
+131
+00:14:14,670 --> 00:14:18,890
+بتساوي؟ واحد ناقص ال confidence يعني واحد ناقص C
+
+132
+00:14:18,890 --> 00:14:24,410
+بقى نقطة الالفة هتكون واحد ناقص 0.95 اللي هي 0.05
+
+133
+00:14:24,410 --> 00:14:29,950
+ال degrees free بقى مش هي ان
+
+134
+00:14:29,950 --> 00:14:40,450
+ناقص واحد اما كمان ده؟اطمعش ناطس واحد احداش ال T
+
+135
+00:14:40,450 --> 00:14:44,270
+the necessary value of T is T الف على اتنين الف
+
+136
+00:14:44,270 --> 00:14:49,170
+اللي هي point O و point O خمسة مظبوط T الف على
+
+137
+00:14:49,170 --> 00:14:53,130
+اتنين اللي هي T point O اتنين خمسة و ال degrees of
+
+138
+00:14:53,130 --> 00:14:58,550
+freedom ايش احداش بروح على ال table خمسة على ال
+
+139
+00:14:58,550 --> 00:15:05,740
+table خمسة and بدور and Tبنط او اتنين و خمسة و
+
+140
+00:15:05,740 --> 00:15:18,340
+احداش هاد
+
+141
+00:15:18,340 --> 00:15:24,680
+ديجريسو درجه واحداش و T بنط
+
+142
+00:15:24,680 --> 00:15:27,380
+او اتنين و خمسة يعني هاد كون اندي اتنين بنط اتنين
+
+143
+00:15:27,380 --> 00:15:34,820
+او واحد هاد متابل خمسةالـ confidence interval
+
+144
+00:15:34,820 --> 00:15:44,040
+هتكون ميو بتساوي X
+
+145
+00:15:44,040 --> 00:15:57,240
+bar زاد او ناقص اللي هي T الف على اتنين و ميو في
+
+146
+00:15:57,240 --> 00:16:00,880
+SX على جزر N
+
+147
+00:16:06,550 --> 00:16:12,550
+يعني هتكون X bar زق ده و ناقص T alpha على اتنين و
+
+148
+00:16:12,550 --> 00:16:21,590
+نقول ايه اكم طلعت انها اتنين point نين سفر واحد في
+
+149
+00:16:21,590 --> 00:16:29,330
+SX على جزر اتناش يعني
+
+150
+00:16:29,330 --> 00:16:33,710
+اذا انا عارف ال standard deviation لل small sample
+
+151
+00:16:34,760 --> 00:16:41,260
+بقدر اعرف اتوقع ال range بتاع ال mean لل
+
+152
+00:16:41,260 --> 00:16:46,160
+population يعني ال mean لل population يتروح بين X
+
+153
+00:16:46,160 --> 00:16:52,040
+bar plus or minus 2.201 1 X على جزر التربيعي لل 12
+
+154
+00:16:52,040 --> 00:17:00,900
+طبعا ده عنده خمسين فربيه confidence بدرجة اتقن
+
+155
+00:17:00,900 --> 00:17:03,980
+خمسين
+
+156
+00:17:03,980 --> 00:17:04,500
+سنتين فربيه
+
+157
+00:17:14,120 --> 00:17:22,720
+شوف مثال تاني a simple postal scale of an equal
+
+158
+00:17:22,720 --> 00:17:27,140
+arm balance type عندي ميزان
+
+159
+00:17:45,920 --> 00:17:56,540
+أوزان بسيط is supplied with point five واحد واتنين
+
+160
+00:17:56,540 --> 00:18:07,140
+and أربع أوز machined brass suites يعني أوزان مص
+
+161
+00:18:07,140 --> 00:18:12,420
+أوز واحد
+
+162
+00:18:12,420 --> 00:18:12,880
+أوز
+
+163
+00:18:17,780 --> 00:18:28,500
+و اتنين و اربعة بيجي
+
+164
+00:18:28,500 --> 00:18:32,880
+مع الميزان هون بيجي عشان دايما ايش اعمله معايرة
+
+165
+00:18:32,880 --> 00:18:36,160
+هذه
+
+166
+00:18:36,160 --> 00:18:42,300
+standard for a quality check the manufacturer
+
+167
+00:18:42,300 --> 00:18:45,140
+randomly selects a sample of fourteen
+
+168
+00:18:47,640 --> 00:18:50,420
+of the one oz weights and weights them on a
+
+169
+00:18:50,420 --> 00:18:54,660
+precision scale المصنع
+
+170
+00:18:54,660 --> 00:19:01,700
+بصنع الأوزان هذه بصنع الأوزان نص oz والواحد oz
+
+171
+00:19:01,700 --> 00:19:09,460
+والاتنين والاربع راح يتأكد من ال precision للكتة
+
+172
+00:19:09,460 --> 00:19:14,820
+اللي وزنها المفروض يكون واحد oz أخد اربع تاشر كتلة
+
+173
+00:19:14,820 --> 00:19:20,560
+أخد اربع تاشركتلة ووزانهم على ال precision scale
+
+174
+00:19:20,560 --> 00:19:26,040
+ميزان دقيق لان
+
+175
+00:19:26,040 --> 00:19:33,220
+نتيجة الوزن على ال precision scale أخد قراءات
+
+176
+00:19:33,220 --> 00:19:38,260
+اربتاشر قراءة طب على بنوزان مستحيل يطلعوا نفس
+
+177
+00:19:38,260 --> 00:19:43,340
+الاشي واحد المفروض هم standardو احد لما اوزنهم طلع
+
+178
+00:19:43,340 --> 00:19:48,380
+عندهم ال اوزان واحد point oh eight واحد point oh
+
+179
+00:19:48,380 --> 00:19:53,940
+one point تسعة سبعة واحد point oh three point nine
+
+180
+00:19:53,940 --> 00:19:58,840
+eight واحد point oh oh point nine six point nine
+
+181
+00:19:58,840 --> 00:20:03,360
+nine point nine eight point nine five one point oh
+
+182
+00:20:03,360 --> 00:20:08,080
+five one point oh one one point oh four one point
+
+183
+00:20:08,080 --> 00:20:18,990
+oh eightهذه الاربتاش خليني اكتبهم اندي
+
+184
+00:20:18,990 --> 00:20:25,050
+1.08 1
+
+185
+00:20:25,050 --> 00:20:31,490
+.01 0.97
+
+186
+00:20:31,490 --> 00:20:35,610
+1
+
+187
+00:20:35,610 --> 00:20:36,250
+.03
+
+188
+00:20:40,380 --> 00:20:58,280
+تفضل تفضل تفضل تفضل تفضل
+
+189
+00:21:17,860 --> 00:21:23,920
+أربع تاشر قرا اربع تاشر قرا based on this sample
+
+190
+00:21:23,920 --> 00:21:27,120
+and
+
+191
+00:21:27,120 --> 00:21:30,580
+that the parent population is normally distributed
+
+192
+00:21:30,580 --> 00:21:35,320
+what is the 95 percent confidence interval for the
+
+193
+00:21:35,320 --> 00:21:40,760
+population meanاللي هو على فرض إن ال population
+
+194
+00:21:40,760 --> 00:21:44,420
+الشركة تنتج السنة مثلا مليون كتلة هاي ال
+
+195
+00:21:44,420 --> 00:21:47,460
+population تبعها على فرض إن ال population هذي
+
+196
+00:21:47,460 --> 00:21:52,300
+normally distributed normally distributed معناته
+
+197
+00:21:52,300 --> 00:21:56,020
+السن بالذرع اللي عددها أقل من تلاتين هتكون ال
+
+198
+00:21:56,020 --> 00:22:00,580
+distribution بتاعها T distribution T distribution
+
+199
+00:22:00,580 --> 00:22:05,740
+ايش what is the ninety percent confidence interval
+
+200
+00:22:05,740 --> 00:22:07,440
+for the population mean
+
+201
+00:22:15,520 --> 00:22:21,360
+أنا هحكي المين إيش يساوي ميو هتكون
+
+202
+00:22:21,360 --> 00:22:32,640
+X bar plus or minus T ألف ع اتنين نيو
+
+203
+00:22:32,640 --> 00:22:42,340
+في SX على جزء التربيه للأن ال
+
+204
+00:22:42,340 --> 00:22:43,760
+X bar كيف بحسبه؟
+
+205
+00:22:46,030 --> 00:22:52,030
+مجموع القراءات على عددها ال X bar مجموع القراءات
+
+206
+00:22:52,030 --> 00:22:58,910
+كلها على N يعني لما نجمع هذه القراءات هيطلع نحسب
+
+207
+00:22:58,910 --> 00:23:04,410
+ال X bar تطلع
+
+208
+00:23:04,410 --> 00:23:05,270
+one point O
+
+209
+00:23:20,290 --> 00:23:25,450
+الستاندر دي فياشن تعرفي
+
+210
+00:23:25,450 --> 00:23:32,950
+من حسب الستاندر دي فياشن هتكون
+
+211
+00:23:32,950 --> 00:23:37,770
+الستماشن الستاندر SX
+
+212
+00:23:41,990 --> 00:23:47,090
+بستوى جزر التربيع ل ال summation ل ال deviations
+
+213
+00:23:47,090 --> 00:24:00,470
+تربيع على a-1 لأنها دي ال sample بتطلع
+
+214
+00:24:00,470 --> 00:24:04,570
+لما نحسس ال deviations ال deviation ايش بيساوي طيب
+
+215
+00:24:04,570 --> 00:24:13,250
+بيساوي xi minus x اني xيعني لكل واحدة فيه
+
+216
+00:24:13,250 --> 00:24:16,930
+deviation هتكون أول واحدة one point oh eight minus
+
+217
+00:24:16,930 --> 00:24:20,110
+one point oh oh nine التانية one point oh one
+
+218
+00:24:20,110 --> 00:24:22,870
+minus one point oh oh nine وها كذا بحسو ال
+
+219
+00:24:22,870 --> 00:24:25,350
+deviations و بعدين بربي ال deviations بعمل عمو
+
+220
+00:24:25,350 --> 00:24:29,570
+التربية لل deviations و بعدين بعملهم sum بقسمهم
+
+221
+00:24:29,570 --> 00:24:36,050
+على n minus واحد تحت ال square root بتجيب ليه؟أو
+
+222
+00:24:36,050 --> 00:24:41,370
+من خلال برنامج ال اكسل او ال matlab او اي برنامج
+
+223
+00:24:41,370 --> 00:24:48,890
+يعني دخلناه على ال اكسل دخلناه
+
+224
+00:24:48,890 --> 00:24:49,430
+على ال اكسل
+
+225
+00:25:07,610 --> 00:25:13,670
+هي نحكي X هي
+
+226
+00:25:13,670 --> 00:25:22,910
+طول القراءات 1.08 1.097
+
+227
+00:25:22,910 --> 00:25:35,930
+1.03 0.98 1 0.96 0.99
+
+228
+00:26:04,680 --> 00:26:10,240
+يعني بدي أحسب اللي هو نحكي ال average بدي أحكي ال
+
+229
+00:26:10,240 --> 00:26:18,740
+average هنا حيث ساوى من ال X ال average للقراءة
+
+230
+00:26:18,740 --> 00:26:19,060
+تادي
+
+231
+00:26:33,150 --> 00:26:49,930
+أو رقماته صحيح ال standard deviation هيكون
+
+232
+00:26:49,930 --> 00:26:54,210
+الساوي ST
+
+233
+00:26:54,210 --> 00:27:00,690
+فيه انتبه فيه standard deviation ل population و
+
+234
+00:27:00,690 --> 00:27:02,890
+فيه ل sample احنا ل ال sample هناخد
+
+235
+00:27:06,090 --> 00:27:14,170
+اللي هي هتكون هدول القراءات هادى
+
+236
+00:27:14,170 --> 00:27:17,410
+أكم
+
+237
+00:27:17,410 --> 00:27:21,670
+طلعتنها ال
+
+238
+00:27:21,670 --> 00:27:27,530
+.. ال point zero اربع واحد سبعة تمانية معناته ايش
+
+239
+00:27:27,530 --> 00:27:33,790
+صحيح طيب لو انا بدي احسب حكيت .. خلنا نحكي هذه
+
+240
+00:27:33,790 --> 00:27:34,570
+خليها في المص
+
+241
+00:27:41,480 --> 00:27:49,700
+بدي احسب الـ deviation الـ deviation هيكون هذه
+
+242
+00:27:49,700 --> 00:27:52,800
+الاقص
+
+243
+00:27:52,800 --> 00:27:56,200
+هذه
+
+244
+00:27:56,200 --> 00:27:57,460
+خلينا اثبت هذه
+
+245
+00:28:11,400 --> 00:28:15,260
+لو بدى احصل deviation تربيه لو بدى اعمل ازايك
+
+246
+00:28:15,260 --> 00:28:20,480
+deviation تربيه هتكون
+
+247
+00:28:20,480 --> 00:28:24,580
+هذا تربيه
+
+248
+00:28:46,480 --> 00:28:49,340
+لو بدى احسن الحسابة هتكون ال standard مش متساوى
+
+249
+00:28:49,340 --> 00:28:59,700
+جزر تربيه square root ل ال sum ل
+
+250
+00:28:59,700 --> 00:29:07,960
+هدول على
+
+251
+00:29:07,960 --> 00:29:12,220
+ال نقص واحد هي تلتاش صح؟
+
+252
+00:29:16,740 --> 00:29:20,800
+طلعت نفس الاشي مظبوط بس انا هبت عشان تتأكدوا ان
+
+253
+00:29:20,800 --> 00:29:31,140
+المعادلات صحيحة طيب احنا حسبنا ال
+
+254
+00:29:31,140 --> 00:29:37,600
+standard deviation اللي انا عندي ال confidence ال
+
+255
+00:29:37,600 --> 00:29:45,700
+confidence خمسين سنة في المية صح ال Cبون تسعة خمسة
+
+256
+00:29:45,700 --> 00:29:57,760
+معناته الف point zero خمسة احنا بدنا
+
+257
+00:29:57,760 --> 00:30:01,340
+T
+
+258
+00:30:01,340 --> 00:30:08,900
+الف
+
+259
+00:30:08,900 --> 00:30:14,410
+على اتنين وال degree of freedom ديأربعة عشر ناقص
+
+260
+00:30:14,410 --> 00:30:18,210
+واحد نقص
+
+261
+00:30:18,210 --> 00:30:22,970
+واحد هي اربعة عشر تلاتة عشر تلاتة عشر تلاتة عشر
+
+262
+00:30:22,970 --> 00:30:24,610
+تلاتة عشر تلاتة عشر تلاتة عشر تلاتة عشر تلاتة عشر
+
+263
+00:30:24,610 --> 00:30:28,630
+تلاتة عشر تلاتة عشر تلاتة عشر تلاتة عشر تلاتة عشر
+
+264
+00:30:28,630 --> 00:30:34,550
+تلاتة عشر تلاتة عشر تلاتة عشر تلاتة عشر تلاتة عشر
+
+265
+00:30:34,550 --> 00:30:34,550
+تلاتة عشر تلاتة عشر تلاتة عشر تلاتة عشر تلاتة عشر
+
+266
+00:30:34,550 --> 00:30:34,550
+تلاتة عشر تلاتة عشر تلاتة عشر تلاتة عشر تلاتة عشر
+
+267
+00:30:34,550 --> 00:30:34,650
+تلاتة عشر تلاتة عشر تلاتة عشر تلاتة عشر تلاتة عشر
+
+268
+00:30:34,650 --> 00:30:35,810
+تلاتة
+
+269
+00:30:45,740 --> 00:31:03,360
+عندها T وانتقل 2.5 و نيو 11 هاي ال 13 2.16 معناته
+
+270
+00:31:03,360 --> 00:31:11,220
+ال X bar او ال نيو هتكون تساوي ال X bar اكتر ان
+
+271
+00:31:11,220 --> 00:31:11,740
+طلعناها
+
+272
+00:31:23,630 --> 00:31:30,710
+واحد زاد او ناقص ت الف عتنين من يوليهي اتنين point
+
+273
+00:31:30,710 --> 00:31:35,250
+ستاش في
+
+274
+00:31:35,250 --> 00:31:42,710
+ال standard deviation ال Sx اللي هي point او اربع
+
+275
+00:31:42,710 --> 00:31:48,650
+واحد سبعة تمانية على جزر اربعتاش
+
+276
+00:31:50,910 --> 00:31:58,950
+يعني هيكون ال new هتسة واحد point o او تسعة زاد او
+
+277
+00:31:58,950 --> 00:32:08,690
+ناقص لما نحسبها point o اربع
+
+278
+00:32:08,690 --> 00:32:13,930
+واحد اتنين
+
+279
+00:32:13,930 --> 00:32:22,540
+من اتو التقديربناء على العينة اللي أخدناها انه
+
+280
+00:32:22,540 --> 00:32:27,920
+القيمة الوسطى لل population بتاع الكتلة الوزنها
+
+281
+00:32:27,920 --> 00:32:33,480
+واحد O's هتكون واحد point O او تسعة plus or minus
+
+282
+00:32:33,480 --> 00:32:40,820
+point O اتنين اربعة بدرجة تقن خمس وتسعين في المية
+
+283
+00:32:40,820 --> 00:32:47,180
+وليش استخدام احنا ال T distribution لأن العينة H
+
+284
+00:32:48,530 --> 00:32:53,150
+أقل من تلاتين فالعينة اللى بتكون عددها صغير وإذا
+
+285
+00:32:53,150 --> 00:32:57,750
+كان الأساس ال population بتاعها normal تمثل بال T
+
+286
+00:32:57,750 --> 00:33:00,450
+distribution او T student distribution إذا كان
+
+287
+00:33:00,450 --> 00:33:03,430
+الأصل بتاعها normal طبعا في ال distributions ليس
+
+288
+00:33:03,430 --> 00:33:05,890
+فقط ال normal في distributions انواع تانية عشان
+
+289
+00:33:05,890 --> 00:33:06,490
+تكونوا عارفين
+
+290
+00:33:33,490 --> 00:33:38,690
+بدنا نشوف hypothesis testing for
+
+291
+00:33:38,690 --> 00:33:42,610
+a single mean for a small sample size يعني نعمل
+
+292
+00:33:42,610 --> 00:33:48,690
+hypothesis testing مثلا
+
+293
+00:33:48,690 --> 00:33:52,990
+بدنا نشوف .. احنا بناخد قراءات لضغط بخار مثلا،
+
+294
+00:33:52,990 --> 00:33:59,220
+بخار طالع من boilerأو بخار داخل على مولد بخاري
+
+295
+00:33:59,220 --> 00:34:06,380
+بفرض بس ان يدخل باربع ميجا باسكال مثلا هذا ال
+
+296
+00:34:06,380 --> 00:34:10,440
+hypothesis او ما يسمى ال null hypothesis اللي هو
+
+297
+00:34:10,440 --> 00:34:15,460
+الافتراض او نحكي الحالة الافتراضية اللي نحكي
+
+298
+00:34:15,460 --> 00:34:19,380
+المثالية ال null hypothesis انه لازم يكون اربع
+
+299
+00:34:19,380 --> 00:34:23,460
+ميجا الان
+
+300
+00:34:27,830 --> 00:34:32,250
+لكن بحسب درجة ال confidence و درجة التيقن بحكي و
+
+301
+00:34:32,250 --> 00:34:39,290
+الله انه .. انه هذا ال hypothesis صح او accepted
+
+302
+00:34:39,290 --> 00:34:46,090
+او rejected ال hypothesis صح او مش صح نشوف من خلال
+
+303
+00:34:46,090 --> 00:34:51,250
+المثال consider pressure measurements listed in
+
+304
+00:34:51,250 --> 00:34:57,210
+table 3 اللي هي كانت تجربة الضغطكان في عند بخار
+
+305
+00:34:57,210 --> 00:35:03,310
+ميه داخل على مولد بخاري كنا ناخد أخدنا مية قراءة
+
+306
+00:35:03,310 --> 00:35:07,650
+للضغط صح؟
+
+307
+00:35:07,650 --> 00:35:10,410
+these measurements represent single sample
+
+308
+00:35:10,410 --> 00:35:13,270
+containing one hundred measures obtained during
+
+309
+00:35:13,270 --> 00:35:19,490
+twelve hour period هذه القياسات بتمثل عينة واحدة
+
+310
+00:35:19,490 --> 00:35:28,640
+عدد أفرادهامية أخدت على مدار اتناشر ساعة العينة
+
+311
+00:35:28,640 --> 00:35:39,380
+هذه كان ال average بتاعها ال X bar تبعها كان
+
+312
+00:35:39,380 --> 00:35:45,500
+اربعة point اربعة مية كان
+
+313
+00:35:45,500 --> 00:35:48,940
+ال X bar اربعة مية
+
+314
+00:35:54,070 --> 00:35:59,670
+ميجا بسكال if
+
+315
+00:35:59,670 --> 00:36:02,850
+additional samples were taken اذا خد عينات اخد مية
+
+316
+00:36:02,850 --> 00:36:06,610
+قراءة تانية مثلا خد مية تانية ومية تالتة ومية
+
+317
+00:36:06,610 --> 00:36:11,470
+رابعة ومية خمسة ومية ثلاثة ورق كذا وحسبنا ال X bar
+
+318
+00:36:11,470 --> 00:36:18,330
+لكل عينة هيطلع على نفس الاشي مش هيطلع على نفس
+
+319
+00:36:18,330 --> 00:36:19,270
+الاشي
+
+320
+00:36:21,940 --> 00:36:25,820
+مجموعة ال means اللي بناخدها من العينات المختلفة
+
+321
+00:36:25,820 --> 00:36:31,620
+هيكون فيها إيش؟ ممكن نعتبرها random variable صح؟
+
+322
+00:36:31,620 --> 00:36:40,040
+لأن فيها variance فيها variance often
+
+323
+00:36:40,040 --> 00:36:42,720
+we are concerned whether the pressures observed
+
+324
+00:36:42,720 --> 00:36:46,800
+are representative of a set point pressure of 4
+
+325
+00:36:46,800 --> 00:36:58,020
+Mega Pascal400 انا .. هذا المفروض اربعة point هذا
+
+326
+00:36:58,020 --> 00:37:04,600
+غلط هذا اربعة point او
+
+327
+00:37:04,600 --> 00:37:12,840
+او اذا فاكرين كانت تمانية ماجة بس كان صح احنا
+
+328
+00:37:12,840 --> 00:37:19,340
+عادة بنكون ضبطين ال system بتاعناال set point انا
+
+329
+00:37:19,340 --> 00:37:26,180
+بحكي اربعة عميقة ال set point المفروض او نحكي
+
+330
+00:37:26,180 --> 00:37:32,480
+نظريا او مثاليا انا ال set point عندى هيدخل ضغط
+
+331
+00:37:32,480 --> 00:37:37,500
+البخار اربعة عميقة هذا ال set point لكن حقيقة
+
+332
+00:37:37,500 --> 00:37:41,380
+بيكونش اربعة في variance حوالين اربعة صح؟
+
+333
+00:37:46,550 --> 00:37:52,010
+one of the most commonly methods for making such
+
+334
+00:37:52,010 --> 00:37:55,550
+decisions is hypothesis testing انا بدي اشوف ان ال
+
+335
+00:37:55,550 --> 00:38:00,670
+.. ان ال set point او ال measured values لل
+
+336
+00:38:00,670 --> 00:38:06,010
+pressure بتحقق ال null hypothesis null hypothesis
+
+337
+00:38:06,010 --> 00:38:12,830
+اللي هو ان ال pressure أربعة ميجاولا بعيدة عنه out
+
+338
+00:38:12,830 --> 00:38:15,490
+of range معين out of range معين يعني المفروض ان
+
+339
+00:38:15,490 --> 00:38:18,590
+انا تكون عشان تكون accepted تكون اربع plus or
+
+340
+00:38:18,590 --> 00:38:24,330
+minus some some values اعتمادا على درجة التيقن
+
+341
+00:38:24,330 --> 00:38:30,310
+معينة مظلوط كل ما زودت درجة التيقن كل ما انا بعطي
+
+342
+00:38:30,310 --> 00:38:37,170
+variance اكتر صح كل ما بقلد درجة التيقن كل ما بعطي
+
+343
+00:38:37,170 --> 00:38:39,530
+variance اقل
+
+344
+00:38:47,210 --> 00:38:53,210
+يعني انا ممكن احكي والله ال pressure الخط الداخل
+
+345
+00:38:53,210 --> 00:38:57,110
+هيكون
+
+346
+00:38:57,110 --> 00:39:08,890
+اربع ميجا plus or minus point O O O one ميجا بسكال
+
+347
+00:39:08,890 --> 00:39:15,150
+بدرجة تيقن اربعين في المية مثلاممكن حد تاني يحكي
+
+348
+00:39:15,150 --> 00:39:19,290
+لك لأ انا ال pressure هين هكون اربع ميجا باسكال
+
+349
+00:39:19,290 --> 00:39:28,830
+plus or minus واحد ميجا باسكال بدرجة تيقن مية في
+
+350
+00:39:28,830 --> 00:39:33,810
+المية مظهور ان هو بعد واحد ميجا عاليمين وواحد
+
+351
+00:39:33,810 --> 00:39:38,590
+عالشمال يعني اكيد هتكون في ال range هذا بلا تكل
+
+352
+00:39:38,590 --> 00:39:46,000
+بلابابعد على الأطراف أكتر كل ما دارش تيقن بتزيد
+
+353
+00:39:46,000 --> 00:39:51,000
+يعني
+
+354
+00:39:51,000 --> 00:39:56,780
+ممكن احكي والله انا متأكد خلال
+
+355
+00:39:56,780 --> 00:40:06,500
+سنة الدنيا هتشتهي مظهور؟ حد تاني بيحكيلك والله انا
+
+356
+00:40:06,500 --> 00:40:13,700
+يعنيتسعين في المية خلال أربع
+
+357
+00:40:13,700 --> 00:40:22,700
+سابيع الدنيا هتشتغل تبقى لنشط الأرصاد الجوية حاجة
+
+358
+00:40:22,700 --> 00:40:27,700
+تعمل كده والله أنا متأكد تلاتين في المية ان الدنيا
+
+359
+00:40:27,700 --> 00:40:33,600
+هتشتغل خلال أسبوع معناه تكون معناه بوسع ال range
+
+360
+00:40:33,600 --> 00:40:40,970
+بوسع ال tolerance او ال errorبزيد أيش؟ التيقن وكل
+
+361
+00:40:40,970 --> 00:40:46,250
+ما بقلل درجة التيقن او كل ما ب .. كل ما بخل الاشي
+
+362
+00:40:46,250 --> 00:40:54,370
+في range ضيق بتزيد المخاطرة على
+
+363
+00:40:56,480 --> 00:40:59,700
+نحكي اللي هو الشركة مثلا الشركة بتبيع قطعة معينة
+
+364
+00:40:59,700 --> 00:41:02,240
+بمواصفات معينة كل ما يقللي الرياني والله انا
+
+365
+00:41:02,240 --> 00:41:05,380
+بحكيلك سيخ الحديد هذا ال string بتاعته اربعمية
+
+366
+00:41:05,380 --> 00:41:11,300
+ميجا ال yield بتاعه اربعمية ميجا باسكال plus or
+
+367
+00:41:11,300 --> 00:41:18,780
+minus واحد ميجا هاي التاجر التاجر بتاعي انا بحكيلك
+
+368
+00:41:18,780 --> 00:41:25,260
+انا الحديد اللي عندهالييلتا اربعمية مياجة باسكال
+
+369
+00:41:25,260 --> 00:41:33,320
+plus و ال minus عشرة مياجة مين ان مخاطر اكتر اللي
+
+370
+00:41:33,320 --> 00:41:36,200
+حكى plus و ال minus واحد مياجة مخاطر مظلوط درجة
+
+371
+00:41:36,200 --> 00:41:39,380
+المخاطر عنده اكبر من اللي حكى الاربعمية plus و ال
+
+372
+00:41:39,380 --> 00:41:43,280
+minus عشرة مياجة نفس الشيء اللي بتوقع الدنيا تشته
+
+373
+00:41:43,280 --> 00:41:49,340
+خلال سنة بحكيك انا متوقع و انا ابوها خلال سنة
+
+374
+00:41:49,340 --> 00:41:52,180
+هتشته مافيش دمغابة لسفر صح؟
+
+375
+00:41:55,680 --> 00:41:59,680
+typically بكون عندي two hypothesis in a hypothesis
+
+376
+00:41:59,680 --> 00:42:06,220
+test the null hypothesis اللي هو الافتراضية الفرض
+
+377
+00:42:06,220 --> 00:42:13,780
+ال .. ال .. ال .. ال .. ال null او المثالي والخيار
+
+378
+00:42:13,780 --> 00:42:19,360
+التاني يعني ال null انا بحكي ال pressure هكون
+
+379
+00:42:19,360 --> 00:42:27,100
+اربعمية بدرجة تقل معينةهذا ال null اللي برا ال
+
+380
+00:42:27,100 --> 00:42:34,220
+range ال alternate hypothesis مجموعة التنين ال
+
+381
+00:42:34,220 --> 00:42:38,880
+null مع ال alternate مية في المية مجموعة التنين ال
+
+382
+00:42:38,880 --> 00:42:41,020
+null مع ال alternate مية في المية
+
+383
+00:42:50,580 --> 00:42:55,140
+الخطوة الأولى في وضع الفرضيات ان اختار ال null
+
+384
+00:42:55,140 --> 00:43:02,860
+hypothesis ان اختار ال null hypothesis since
+
+385
+00:43:02,860 --> 00:43:05,540
+hypothesis testing offer a phase to assemble mean
+
+386
+00:43:05,540 --> 00:43:10,040
+عادة احنا بيكون عنده متوسط معين معناته ال null
+
+387
+00:43:10,040 --> 00:43:16,860
+hypothesis ان ميو ال null hypothesis ان ميو استوه
+
+388
+00:43:16,860 --> 00:43:18,780
+some set value ميو نود
+
+389
+00:43:23,070 --> 00:43:30,770
+الـ mu اللي هي ال main value it's some set value
+
+390
+00:43:30,770 --> 00:43:34,210
+اصلا ال pressure انا set up معمور على اربعة ميجا
+
+391
+00:43:34,210 --> 00:43:41,550
+الخطوة
+
+392
+00:43:41,550 --> 00:43:47,990
+التانية بده احط ال alternate hypothesis
+
+393
+00:43:52,360 --> 00:43:58,200
+ال alternate hypothesis لازم يعكس احنا ايش بندور
+
+394
+00:43:58,200 --> 00:44:02,660
+.. ايش بندور؟ هل مثلا بدي ال mean يكون واقع بين
+
+395
+00:44:02,660 --> 00:44:08,420
+two values؟ ولا أكبر من value معينة؟ ولا أصغر من
+
+396
+00:44:08,420 --> 00:44:14,580
+value معينة؟ مافيش شغل هيك، مظلوط؟ لأي .. أي .. أي
+
+397
+00:44:14,580 --> 00:44:19,140
+.. يعني أي كمية مقاسة، يا إما هتكون fringe من كذا
+
+398
+00:44:19,140 --> 00:44:26,050
+لكذاأو أكبر من قيمة معينة أو أصغر من قيمة معينة في
+
+399
+00:44:26,050 --> 00:44:31,710
+غير هيك الاحتمالات هذه التلات الاحتمالات الموجودة
+
+400
+00:44:31,710 --> 00:44:37,090
+هذا ال ال ال ال three possible alternate
+
+401
+00:44:37,090 --> 00:44:47,170
+hypothesis ان يكون two tailed او two sided test و
+
+402
+00:44:47,170 --> 00:44:51,850
+في عند ال left tailed testو فين دي راية tailed
+
+403
+00:44:51,850 --> 00:44:56,610
+test يعني الكمية اللي بقيسها لو كانت high
+
+404
+00:44:56,610 --> 00:45:07,830
+distribution تبعها اذا
+
+405
+00:45:07,830 --> 00:45:19,930
+كانت two sided او two tailed نحكي ال HOاللي هي ميو
+
+406
+00:45:19,930 --> 00:45:30,330
+سوا ميو نود ال alternative ان ميو مابيسويش
+
+407
+00:45:30,330 --> 00:45:41,590
+ميو نود طبعا هي لان معناته
+
+408
+00:45:41,590 --> 00:45:49,920
+ان ميو سوا ميو نود انه تكون ال average valueفي ال
+
+409
+00:45:49,920 --> 00:45:53,700
+range هذا بال confidence معين في ال range معين هذا
+
+410
+00:45:53,700 --> 00:46:04,000
+ايش بتحقق اندي ال null hypothesis هنا اذا طلعت ال
+
+411
+00:46:04,000 --> 00:46:14,800
+values برا ال range هذا reject هذا
+
+412
+00:46:14,800 --> 00:46:18,460
+اول واحد اللي هي two sided في عندي left sided
+
+413
+00:46:37,970 --> 00:46:45,890
+ان نكون الـ Mu الـ HO اللي
+
+414
+00:46:45,890 --> 00:46:50,650
+هي Mu بيستخدم Mu node الـ
+
+415
+00:46:50,650 --> 00:47:01,050
+HA الـ Mu أقل من
+
+416
+00:47:01,050 --> 00:47:01,570
+Mu node
+
+417
+00:47:07,420 --> 00:47:12,600
+معناته هذا was two sided هذه
+
+418
+00:47:12,600 --> 00:47:19,980
+ال period do not reject ماترفضش ماترفض ال H O لأن
+
+419
+00:47:19,980 --> 00:47:27,320
+انا حاططت يعني do not reject بتختلف
+
+420
+00:47:27,320 --> 00:47:36,060
+عن accept يعني reject ايش معناته do not rejectيعني
+
+421
+00:47:36,060 --> 00:47:44,300
+في أنه لا يرفض وفي
+
+422
+00:47:44,300 --> 00:47:52,320
+يقبل هل
+
+423
+00:47:52,320 --> 00:48:02,240
+يقبل تساوي لا يرفض مية
+
+424
+00:48:02,240 --> 00:48:07,690
+في المية هل تساوي مية في الميةلأ لابتساوهاش 100%
+
+425
+00:48:07,690 --> 00:48:16,690
+يعني
+
+426
+00:48:16,690 --> 00:48:23,950
+انا
+
+427
+00:48:23,950 --> 00:48:32,190
+مش معارض اعطيك اشي معين هذا لا يعني القبولمش معرض
+
+428
+00:48:32,190 --> 00:48:38,990
+اعطيك ايش معين لان عندك قبول واضح؟ بس ايش تفهم
+
+429
+00:48:38,990 --> 00:48:49,870
+انها قبول واضح؟ مش مين في المية طيب
+
+430
+00:48:49,870 --> 00:48:55,270
+معناته اذا انت كنت ال two sided يعني ميو بيستويش
+
+431
+00:48:55,270 --> 00:49:01,910
+ال set point ميو نود معناته انت لا ترفضالـ null
+
+432
+00:49:01,910 --> 00:49:09,470
+hypothesis لكن إذا كنت برا أكيد rejected بتكون
+
+433
+00:49:09,470 --> 00:49:21,770
+إسمها rejection ال left sided left sided إذا
+
+434
+00:49:21,770 --> 00:49:29,330
+كانت ال mu أقل من ال mu not reject
+
+435
+00:49:31,330 --> 00:49:38,030
+الـ null hypothesis إذا
+
+436
+00:49:38,030 --> 00:49:43,190
+كنت أكبر منها يعني على اليمين do
+
+437
+00:49:43,190 --> 00:49:47,830
+not reject ال null hypothesis فهذا ال h a mu أقل
+
+438
+00:49:47,830 --> 00:49:54,250
+من ال u node في ال right tailed إذا كانت ال mu
+
+439
+00:49:54,250 --> 00:50:00,430
+أكبر من ال u nodereject null hybrids يعني إذا كانت
+
+440
+00:50:00,430 --> 00:50:07,810
+ال average value للقراءات أعلى من ال set point
+
+441
+00:50:07,810 --> 00:50:18,330
+reject otherwise do not reject في
+
+442
+00:50:18,330 --> 00:50:23,910
+حالة ال sample في
+
+443
+00:50:23,910 --> 00:50:28,380
+حالة ال sample أنا بكون عامل تجربةالعدد طبعا اقل
+
+444
+00:50:28,380 --> 00:50:33,100
+من تلاتين انا باعك و انا اعمل ايه اش تجربة و ماخد
+
+445
+00:50:33,100 --> 00:50:36,260
+قراءات عشرين قراءة خمس استاش خمسة و عشرين عشرة
+
+446
+00:50:36,260 --> 00:50:44,960
+ماخد قراءات انا ايش بحسب اللوم بحسب ال X average و
+
+447
+00:50:44,960 --> 00:50:56,060
+بحسب ال standarddeviation لل sample بتاعتى وفي
+
+448
+00:50:56,060 --> 00:50:59,160
+set point عندى مثلا ال pressure set point اربعة
+
+449
+00:50:59,160 --> 00:51:09,120
+ميجا اللى هى عايش ال new note هى set point هاد ال
+
+450
+00:51:09,120 --> 00:51:17,540
+set point قيمة مثلية و ال X bar ناجح عن العينة انا
+
+451
+00:51:17,540 --> 00:51:20,920
+خدت قراءات و دى بتبقى ال averageو القرارات اللي
+
+452
+00:51:20,920 --> 00:51:24,500
+أخدتها فيها deviations فيها .. فيها إيش random
+
+453
+00:51:24,500 --> 00:51:28,800
+variable فهيكون فيها إيش standard deviation معناته
+
+454
+00:51:28,800 --> 00:51:33,940
+هحسم ما يسمى T experimental
+
+455
+00:51:33,940 --> 00:51:44,220
+بالساوية X bar minus mu node على SX على جزر N
+
+456
+00:51:57,280 --> 00:52:10,400
+و في مينيجا داول ما يسمى تي ألفة على اتنين و نيو
+
+457
+00:52:10,400 --> 00:52:15,240
+تي
+
+458
+00:52:15,240 --> 00:52:20,400
+ألفة على اتنين و نيو بحص عليها مينيجا داول اللي
+
+459
+00:52:20,400 --> 00:52:25,620
+هذي هتكون في حال تصفد هذي تي ألفة على اتنين و نيو
+
+460
+00:52:27,170 --> 00:52:34,130
+وها دي minus T alpha على اتنين و nu و انا رودي
+
+461
+00:52:34,130 --> 00:52:37,570
+احسب T experimental T experimental اذا كانت T
+
+462
+00:52:37,570 --> 00:52:39,590
+experimental طلعت هنا مثلا هاي T experimental طلعت
+
+463
+00:52:39,590 --> 00:52:45,090
+هنا هاي T experimental معناته هي جاية في حالة ال
+
+464
+00:52:45,090 --> 00:52:50,610
+ال two sides في ال do not reject ال zone اذا جاية
+
+465
+00:52:50,610 --> 00:52:57,430
+T experimental مثلا هناطلعت برا صارت في ال reject
+
+466
+00:52:57,430 --> 00:53:05,850
+صارت في ال reject معناته انا فحصت ال system بتاعي
+
+467
+00:53:05,850 --> 00:53:17,230
+وجدت انه القراءات within ال range الغير مرفوض
+
+468
+00:53:17,230 --> 00:53:20,990
+within ال range الغير مرفوض
+
+469
+00:53:22,450 --> 00:53:27,430
+معناته امور ماشية او نتيجة التجربة العينة اللى
+
+470
+00:53:27,430 --> 00:53:35,050
+أخدتها طلعت ال T ال experimental الحقيقية برا
+
+471
+00:53:35,050 --> 00:53:41,590
+ال range معناته صارت في ال reject ال reject بتطلب
+
+472
+00:53:41,590 --> 00:53:51,240
+ايش قرار صح ايش القرار اللى هسوي انابشت أنا في محط
+
+473
+00:53:51,240 --> 00:53:55,400
+التوليد بخرية وعملت التجربة و طلعت experimental
+
+474
+00:53:55,400 --> 00:54:01,480
+يعني أجت في ال range المرفوض في معناته في عندي
+
+475
+00:54:01,480 --> 00:54:06,300
+مشكلة لازم أحلها مظلوط ببحث عن أسباب المشكلة ليش
+
+476
+00:54:06,300 --> 00:54:12,600
+ان ال pressure out بعمل adjustment و ضبط بعد ان
+
+477
+00:54:12,600 --> 00:54:16,500
+بجي التجربة كمان مرة طيب
+
+478
+00:54:21,460 --> 00:54:26,860
+هذا في حالة two sided بحسب
+
+479
+00:54:26,860 --> 00:54:34,380
+T ألف على اتنين و compare مع
+
+480
+00:54:34,380 --> 00:54:39,520
+T experimental عشان تشوف انت في ال don't reject
+
+481
+00:54:39,520 --> 00:54:47,140
+region ولا في ال reject region اذا كانت lift
+
+482
+00:54:50,690 --> 00:54:58,810
+يعني إذا كانت في الحالة هذه T experimental أكبر
+
+483
+00:54:58,810 --> 00:55:08,730
+أو يساوي minus T الف على اتنين من U و أزرع يساوي T
+
+484
+00:55:08,730 --> 00:55:14,630
+الف على اتنين من U معناته do not reject null
+
+485
+00:55:14,630 --> 00:55:25,460
+hypothesis do not reject do notreject اللي هو الـ
+
+486
+00:55:25,460 --> 00:55:32,960
+HO null hypothesis otherwise reject هذا في حالة
+
+487
+00:55:32,960 --> 00:55:41,440
+اللي هو two-tailed إذا left-tailed
+
+488
+00:55:41,440 --> 00:55:48,220
+left
+
+489
+00:55:48,220 --> 00:55:48,760
+-tailed
+
+490
+00:55:57,040 --> 00:56:14,320
+هذه T الف على اتنين ون يو ال
+
+491
+00:56:14,320 --> 00:56:20,720
+H O ال H A إذا
+
+492
+00:56:20,720 --> 00:56:24,320
+كانت T experimental
+
+493
+00:56:28,170 --> 00:56:42,790
+أقل من T ألفة على اتنين when you reject otherwise
+
+494
+00:56:42,790 --> 00:56:48,610
+do not reject إذا كانت right-tailed
+
+495
+00:56:54,010 --> 00:56:58,110
+الـ Alternative Hypothesis إذا كان الـ T
+
+496
+00:56:58,110 --> 00:57:02,910
+Experimental أكبر
+
+497
+00:57:02,910 --> 00:57:14,890
+من T Alpha على اتنين من T لحظة هذا ليس T Alpha T
+
+498
+00:57:14,890 --> 00:57:21,650
+Alpha when you reject
+
+499
+00:57:21,650 --> 00:57:23,170
+المال Hypothesis
+
+500
+00:57:32,010 --> 00:57:49,050
+طيب نشوف مثال using
+
+501
+00:57:49,050 --> 00:57:54,950
+the data of example 6 استخدام بيانات المثال رقم 6
+
+502
+00:57:56,590 --> 00:58:01,990
+اللي هو تاعة ال one o's mass determine if the
+
+503
+00:58:01,990 --> 00:58:06,250
+sample of fourteen of one o's weights comes from a
+
+504
+00:58:06,250 --> 00:58:09,670
+population of weights whose true value true mean
+
+505
+00:58:09,670 --> 00:58:15,910
+value mean weight is greater than one point o o's
+
+506
+00:58:15,910 --> 00:58:20,650
+بيحكي ليه باستخدام بيانات ال ال ال اربع تاشر اللي
+
+507
+00:58:20,650 --> 00:58:26,090
+عملت اللي أخدتهمحسبت احنا حسبنا ال X bar حسبنا ال
+
+508
+00:58:26,090 --> 00:58:32,090
+S X حظوط افحص
+
+509
+00:58:32,090 --> 00:58:41,570
+اذا العينة جاية من population للأوزان ال mean
+
+510
+00:58:41,570 --> 00:58:47,970
+value بتاعتها اكبر من واحد في المية based on a
+
+511
+00:58:47,970 --> 00:58:50,430
+confidence level of تسعة و تسعين في المية يعني ال
+
+512
+00:58:50,430 --> 00:58:50,610
+C
+
+513
+00:58:53,930 --> 00:58:59,070
+point nine تسعة لأن
+
+514
+00:58:59,070 --> 00:59:05,650
+ال null hypothesis ال H O اللي هي ميو بيستوى ميو
+
+515
+00:59:05,650 --> 00:59:19,990
+نود اللي هي ال six point اللي هي واحد اوز صح ال
+
+516
+00:59:19,990 --> 00:59:20,570
+H A
+
+517
+00:59:23,880 --> 00:59:30,180
+مبداك تحكم U مبداك تشوف أكبر مبداك تفحص إذا أكبر
+
+518
+00:59:30,180 --> 00:59:41,040
+أو يساوي واحد اوز احنا
+
+519
+00:59:41,040 --> 00:59:46,980
+حسبنا ال X bar صح؟ احنا حسبنا ال X bar اكمل طلعت
+
+520
+00:59:46,980 --> 00:59:49,580
+عنه واحد
+
+521
+00:59:53,460 --> 01:00:04,940
+تسعة و ال Sx point O
+
+522
+01:00:04,940 --> 01:00:12,200
+اربع واحد سبعة تمانية طبعا
+
+523
+01:00:12,200 --> 01:00:13,960
+هذا هكون انا بدأ افحص
+
+524
+01:00:24,040 --> 01:00:31,420
+right-handed صح؟
+
+525
+01:00:31,420 --> 01:00:44,060
+معناته بدي احسب T experimental ايش تساوي؟ X bar
+
+526
+01:00:44,060 --> 01:00:47,300
+minus mu node
+
+527
+01:00:53,790 --> 01:01:00,670
+يعني هيكون ال X bar اللي من التجربة واحد point صفر
+
+528
+01:01:00,670 --> 01:01:07,850
+صفر تسعة minus واحد على point zero اربع واحد سبعة
+
+529
+01:01:07,850 --> 01:01:19,710
+تمانية على جزر اربعتاش كم؟
+
+530
+01:01:19,710 --> 01:01:28,730
+point تمانية صفر ستةpoint eight صفر ستة الان
+
+531
+01:01:28,730 --> 01:01:34,230
+ال C point أسفل يعني ال alpha شو يساوي point O
+
+532
+01:01:34,230 --> 01:01:38,170
+واحد يعني
+
+533
+01:01:38,170 --> 01:01:47,150
+انا بدي احسب T Alpha و Nu يعني بدي احسب T point O
+
+534
+01:01:47,150 --> 01:01:52,910
+واحد و Nu عندى اكم انبسط ساوى اربعة اتاشرالـ U
+
+535
+01:01:52,910 --> 01:02:12,830
+هتكون تلتاش تلتاش من هو على ال tables تطلع
+
+536
+01:02:12,830 --> 01:02:19,850
+اتنين point ستة خمسة صح تطلع
+
+537
+01:02:19,850 --> 01:02:21,530
+اتنين point ستة خمسة
+
+538
+01:02:35,820 --> 01:02:41,200
+يعني عندي ال T alpha و ال U اتنين هاي اتنين point
+
+539
+01:02:41,200 --> 01:02:48,520
+ستة خمسة و
+
+540
+01:02:48,520 --> 01:02:55,320
+ال T experimental جاي هين هاي ال T experimental
+
+541
+01:02:55,320 --> 01:02:58,560
+اللي
+
+542
+01:02:58,560 --> 01:02:59,080
+هي point
+
+543
+01:03:10,360 --> 01:03:21,240
+احنا مش هاكون عند هين reject و هين do not reject
+
+544
+01:03:21,240 --> 01:03:26,040
+معناته
+
+545
+01:03:26,040 --> 01:03:30,120
+احنا مش مرفوضة do not reject
+
+546
+01:03:35,930 --> 01:03:39,130
+زي ما حكينا ال right tail test و ال T experimental
+
+547
+01:03:39,130 --> 01:03:46,270
+falls in the do not reject HO region طبعا هذا
+
+548
+01:03:46,270 --> 01:03:50,430
+بدرجة تقن تسعة وتسعين في المية بدرجة تقن تسعة
+
+549
+01:03:50,430 --> 01:03:52,110
+وتسعين في المية
+
+550
+01:04:01,470 --> 01:04:04,810
+لو طبعا ال T experimental هنا أكبر تنسى الخمسة
+
+551
+01:04:04,810 --> 01:04:11,270
+وانته do not في ال reject region
+
+552
+01:04:11,270 --> 01:04:17,010
+طبعا
+
+553
+01:04:17,010 --> 01:04:23,430
+هذا اللي حكيناه حكيناه في حالة sample size صغيرة
+
+554
+01:04:23,430 --> 01:04:28,310
+يعني الأن أقل من تلاتين في حالة ال sample size
+
+555
+01:04:28,310 --> 01:04:34,170
+كبير يعني الأن أكبر يساويتلاتين ال distribution
+
+556
+01:04:34,170 --> 01:04:39,150
+للسامة الكبيرة بكون شبه او قريب كتير من ال normal
+
+557
+01:04:39,150 --> 01:04:43,130
+distribution معناه في الحالة بستخدم ال z
+
+558
+01:04:43,130 --> 01:04:47,130
+distribution بستخدم ال z distribution يعني نفس
+
+559
+01:04:47,130 --> 01:04:56,200
+الاشي نفس الخطوات بس باحسببادل T Alpha و Nu بحسب
+
+560
+01:04:56,200 --> 01:05:04,480
+ايش؟ Z Nu و بادل T Experimental بحسب اللي هو Z
+
+561
+01:05:04,480 --> 01:05:09,160
+Experimental
+
+562
+01:05:09,160 --> 01:05:16,860
+نرجع
+
+563
+01:05:16,860 --> 01:05:22,630
+لمثال Pasha، ال Pasha رأى كام قراءة أخدنا احنا؟مية
+
+564
+01:05:22,630 --> 01:05:27,990
+معناته ال sample size أكبر من تلاتين معناته تعتبر
+
+565
+01:05:27,990 --> 01:05:35,590
+large sample large sample from
+
+566
+01:05:35,590 --> 01:05:39,450
+the pressures in table تلاتة can we conclude that
+
+567
+01:05:39,450 --> 01:05:44,530
+the experimental data obtained indicate a target
+
+568
+01:05:44,530 --> 01:05:48,450
+pressure of four mega Pascal at a confidence level
+
+569
+01:05:48,450 --> 01:05:50,030
+of تسعة تسعين في المية
+
+570
+01:05:52,900 --> 01:06:00,700
+يعني هو أخد قراءات و ال set point بتاعته أربعة
+
+571
+01:06:00,700 --> 01:06:06,880
+ميجا الميو نود يعني ال null hypothesis هيكون اللي
+
+572
+01:06:06,880 --> 01:06:14,890
+هو ميو بالسوء أربعة ميجا باسكال ال alternativeاللي
+
+573
+01:06:14,890 --> 01:06:20,330
+هي ميو متساويش أربعة ميو متساويش أربعة طب انا احكي
+
+574
+01:06:20,330 --> 01:06:25,370
+أربعة مش أربعة بالظبط وده ب confidence level معين
+
+575
+01:06:25,370 --> 01:06:33,610
+هحسب ال Z experimental المعادفة Z experimental
+
+576
+01:06:33,610 --> 01:06:48,540
+بتساوي X bar minus ميو على S Xالـ X bar حسبناها
+
+577
+01:06:48,540 --> 01:06:54,940
+احنا في المثال 4.008-4 و ال standard deviation كان
+
+578
+01:06:54,940 --> 01:07:01,900
+0.0114 تطلع 5.714
+
+579
+01:07:01,900 --> 01:07:09,320
+ضايق احسب ال Z value based على ال confidence
+
+580
+01:07:11,000 --> 01:07:16,480
+confidence يعني اندي ال confidence طب انا هدق two
+
+581
+01:07:16,480 --> 01:07:21,260
+sided ال confidence اللي هو تسعة و تسعين في المية
+
+582
+01:07:21,260 --> 01:07:28,480
+تسعة و تسعين في المية بدي
+
+583
+01:07:28,480 --> 01:07:34,340
+احسب z ل
+
+584
+01:07:34,340 --> 01:07:35,120
+point o
+
+585
+01:07:39,380 --> 01:07:44,480
+خمسة اللي هي point o واحد على اتنين point واحد على
+
+586
+01:07:44,480 --> 01:07:54,000
+اتنين اللي هي ال احنا
+
+587
+01:07:54,000 --> 01:08:04,840
+كنا نحسب هذه في ال z كنا نحسب مساحة هذه هاي
+
+588
+01:08:04,840 --> 01:08:05,140
+ال z
+
+589
+01:08:08,090 --> 01:08:14,530
+صح نحسب ال z هو two sided المعناته هنا المجموع
+
+590
+01:08:14,530 --> 01:08:26,570
+هكون كله نص نص ماقص point O O خمسة
+
+591
+01:08:26,570 --> 01:08:33,650
+يعني هكون point أربعة تسعة
+
+592
+01:08:40,130 --> 01:08:45,650
+خمسة صح؟ مظبوط يعني هذه ال area بقى point أربعة
+
+593
+01:08:45,650 --> 01:08:53,690
+تسعة خمسة منها بنحسب ال z لما نروح على ال area
+
+594
+01:08:53,690 --> 01:08:58,710
+point أربعة تسعة خمسة
+
+595
+01:09:09,430 --> 01:09:20,910
+الـ area point أربعة تسعة هذا
+
+596
+01:09:20,910 --> 01:09:26,610
+جاية هنا عندكم تطلع هنا اتنين point خمسة و جاية
+
+597
+01:09:26,610 --> 01:09:31,710
+بين التمانية والسبعة يعني هتكون اتنين point خمسة
+
+598
+01:09:31,710 --> 01:09:37,310
+سبعة خمسة اتنين point خمسة سبعة خمسة
+
+599
+01:09:41,220 --> 01:09:46,720
+معناته عندى هسير عندى اتنين point خمسة سبعة خمسة و
+
+600
+01:09:46,720 --> 01:09:50,900
+ال takes from انت الاخر طلعت عندى خمسة point سبعة
+
+601
+01:09:50,900 --> 01:09:59,080
+واحد اربعة برا اجت
+
+602
+01:09:59,080 --> 01:10:05,960
+في ال reject zone اجت في ال reject ماجتش جوا لو
+
+603
+01:10:05,960 --> 01:10:17,490
+اجت جوا كاناشكان مارفضنهاش واضح؟ فبالطريقة
+
+604
+01:10:17,490 --> 01:10:22,930
+هذه بعرف أن ال system بتاعي شغال صح و أنا شغال صح
+
+605
+01:10:22,930 --> 01:10:28,810
+بدرجة تيقن معينة
+
+606
+01:10:28,810 --> 01:10:38,350
+ال .. هيك نخلصنا المحاضرة اللي في عندكواالمحاضرة
+
+607
+01:10:38,350 --> 01:10:42,190
+الجاية بنكمل ال section هذا و بنحل مسائل، يعني
+
+608
+01:10:42,190 --> 01:10:45,590
+تعالوا يحلين المسائل، تاكلوا العفو
+
diff --git a/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/VutWLrLqWfg_postprocess.srt b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/VutWLrLqWfg_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..7afee787febe289b671983846bce726da15485ad
--- /dev/null
+++ b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/VutWLrLqWfg_postprocess.srt
@@ -0,0 +1,2020 @@
+1
+00:00:04,990 --> 00:00:07,450
+بسم الله الرحمن الرحيم السلام عليكم ورحمة الله
+
+2
+00:00:07,450 --> 00:00:11,190
+وبركاته هنكمل في مادية القياسات هنبدأ بالشطر اتنين
+
+3
+00:00:11,190 --> 00:00:13,950
+ال standards and dimensional units of measurement
+
+4
+00:00:16,750 --> 00:00:22,410
+أول شي هنعطي بعض التعريفات و المفاهيم الأساسية أول
+
+5
+00:00:22,410 --> 00:00:25,090
+شي ال basis of measurement اللي هو أسس القياسات هي
+
+6
+00:00:25,090 --> 00:00:32,390
+عبارة عن مقارنة حكينا بين إيش بده أقيسه و standard
+
+7
+00:00:32,390 --> 00:00:36,710
+يعني عشان أقيس طول قطعة محتاج إيش standard سواء
+
+8
+00:00:36,710 --> 00:00:39,750
+كان ال standard أساسي
+
+9
+00:00:41,060 --> 00:00:45,400
+أو تانو يعني عشان أقيس أعرض قطة ممكن أستخدم متر
+
+10
+00:00:45,400 --> 00:00:51,400
+العادي ممكن أستخدم مصطرة ممكن أستخدم caliber هذه
+
+11
+00:00:51,400 --> 00:00:57,100
+كلها ياش standard فأنا بعمل مقارنة بين الاشي اللي
+
+12
+00:00:57,100 --> 00:01:00,920
+بده أقيسه و أصمي standard عشان أعرف الكيمية اللي
+
+13
+00:01:00,920 --> 00:01:01,400
+بطلوبة
+
+14
+00:01:04,170 --> 00:01:06,490
+ال dimension .. في عندي اسم ايش اسمه ال dimension
+
+15
+00:01:06,490 --> 00:01:12,250
+و في ال dimension dimensional unit ال dimension هو
+
+16
+00:01:12,250 --> 00:01:16,830
+defining characteristics of an entity يعني ال
+
+17
+00:01:16,830 --> 00:01:21,350
+length is dimension
+
+18
+00:01:24,260 --> 00:01:29,780
+dimensional unit هي إيش؟ وحدة الطول معناته ال
+
+19
+00:01:29,780 --> 00:01:35,420
+length إيش هو؟ dimension temperature is dimension
+
+20
+00:01:35,420 --> 00:01:44,320
+ال Celsius dimensional unit ليش؟ لتمبرتشار time is
+
+21
+00:01:44,320 --> 00:01:49,900
+dimension is second is a dimensional unit of اللي
+
+22
+00:01:49,900 --> 00:01:52,600
+هو ال time dimension
+
+23
+00:01:56,330 --> 00:02:02,070
+الان ال dimension is unique يعني إيش؟ فريد يعني
+
+24
+00:02:02,070 --> 00:02:08,050
+انا في عندي dimension ليش؟ للطول، لكن الطول هو كم
+
+25
+00:02:08,050 --> 00:02:17,490
+قياسه بوحدة المتراو ال inch او القدم او ال سنتى
+
+26
+00:02:17,490 --> 00:02:23,010
+متر معناته ان انا ماعندي دمينشوف لينكت بس دمينشوف
+
+27
+00:02:23,010 --> 00:02:34,590
+لينكت بس ممكن اقيصه باكتر من وحدة الان
+
+28
+00:02:34,590 --> 00:02:39,830
+نظام الوحدات يجب وضع نظام الوحداتواجب ال ..
+
+29
+00:02:39,830 --> 00:02:44,370
+الاتفاق عليه، لازم يكون عليه اتفاق او اجماع عالمي،
+
+30
+00:02:44,370 --> 00:02:49,230
+ماينفعش كل واحد يكون عنده مثلا خياس مختلف، يكون
+
+31
+00:02:49,230 --> 00:02:55,050
+عنده ألاف الطرق لقياس ال .. الوحدة الطول ال
+
+32
+00:02:55,050 --> 00:02:58,830
+systems must be standardized، لازم يكون معيارية
+
+33
+00:02:58,830 --> 00:02:59,750
+عشان أقدر أقارن
+
+34
+00:03:02,500 --> 00:03:07,040
+because there are various systems لأن في عنده أكتر
+
+35
+00:03:07,040 --> 00:03:10,900
+من نظام لازم يكون فيه طريقة ما للتحوير من نظام
+
+36
+00:03:10,900 --> 00:03:18,220
+للنظام standards
+
+37
+00:03:18,220 --> 00:03:22,460
+of measurements اللي هو معيير القياسات يتطبق على
+
+38
+00:03:22,460 --> 00:03:29,910
+الوحدات على نظام الوحداتوعلى نظام التحويل بين
+
+39
+00:03:29,910 --> 00:03:38,590
+الأنظمة بس ده حوار من نظام SI ل English ال
+
+40
+00:03:38,590 --> 00:03:43,790
+Baseless في ال SI system عند الطولال dimension هو
+
+41
+00:03:43,790 --> 00:03:51,870
+إيش؟ Meter، ال symbol بتاعه M، ال mass kilogram،
+
+42
+00:03:51,870 --> 00:03:58,970
+ال time second، الطيارة الكهربائية أمبير، درجة
+
+43
+00:03:58,970 --> 00:04:07,080
+الحرارة Kelvin، ال amount of substanceمول هى انا
+
+44
+00:04:07,080 --> 00:04:10,860
+ممكن اعتبر انا اللى هو ال mass و ال amount of
+
+45
+00:04:10,860 --> 00:04:18,960
+substance نفس الاشي تقريبا ايش
+
+46
+00:04:18,960 --> 00:04:24,660
+الفرق بين المول و ال kilogram؟
+
+47
+00:04:24,660 --> 00:04:29,680
+المول اللى بتختصف المواد ده kilogram اللى بنحسه
+
+48
+00:04:29,680 --> 00:04:31,940
+ايوة
+
+49
+00:04:34,840 --> 00:04:43,040
+بوزن عدد انا بحكي مولن حاس مثلا بوزن تلاتة و ستين
+
+50
+00:04:43,040 --> 00:04:52,880
+او اجرام مثلامول الكربون بوزن اتناشر جرام الان مول
+
+51
+00:04:52,880 --> 00:04:55,880
+الكربون في ستة point او اتنين اتنين في عشر و أس
+
+52
+00:04:55,880 --> 00:05:03,420
+تلاتة و عشرين ضرة كربون و مول الحديد برضه في ستة
+
+53
+00:05:03,420 --> 00:05:06,900
+point او اتنين اتنين في عشر و أس تلاتة و عشرين
+
+54
+00:05:06,900 --> 00:05:14,480
+فالمول وزن لعدد، العدد ثابت، اللي هو عدد إياش؟
+
+55
+00:05:14,480 --> 00:05:14,840
+Avocado
+
+56
+00:05:17,520 --> 00:05:24,780
+الشدة الطوائية اللى هى candela عندى
+
+57
+00:05:24,780 --> 00:05:27,920
+ال as I draw units with special names and symbols
+
+58
+00:05:27,920 --> 00:05:33,200
+فعندى ال plane angle اللى هى ال radians الرمز بتاع
+
+59
+00:05:33,200 --> 00:05:38,300
+ال radian ممكن نعبر عنه meter per meter أساسا ال
+
+60
+00:05:38,300 --> 00:05:41,880
+radian من أين جاية؟
+
+61
+00:05:41,880 --> 00:05:46,320
+اذا عندى دائرة نص
+
+62
+00:05:46,320 --> 00:05:46,840
+قطرها
+
+63
+00:05:49,450 --> 00:06:00,550
+R محيطة ايش هاكون؟ محيطة اتنين by R اتنين by R لو
+
+64
+00:06:00,550 --> 00:06:09,990
+جبت طول قيمته R طول قيمته R و الطول هذا عملت
+
+65
+00:06:09,990 --> 00:06:18,970
+course هذا ال course هنكبره
+
+66
+00:06:27,500 --> 00:06:35,440
+هذا ال cos طوله R ال radian بس
+
+67
+00:06:35,440 --> 00:06:45,980
+هاتول ال cos اللي هو طوله R على R هذه one radian
+
+68
+00:06:45,980 --> 00:06:53,420
+أساس المحية الدائرة كلها كم؟ 2 by R معناه دائرة
+
+69
+00:06:53,420 --> 00:07:02,270
+كاملةهى عبارة عن اتنين باى صح لكن one radian اللى
+
+70
+00:07:02,270 --> 00:07:09,750
+هى طول قوس طوله R على نص دائرة كترها R هذا one
+
+71
+00:07:09,750 --> 00:07:23,770
+radian في solid angle اللى هىالاسترادين في ال
+
+72
+00:07:23,770 --> 00:07:29,270
+frequency hertz او second او ناقص واحد في عند ال
+
+73
+00:07:29,270 --> 00:07:32,170
+force النيوتن اللي هي عبارة عن mass في
+
+74
+00:07:32,170 --> 00:07:37,110
+acceleration صح؟كلجرام متر per second square عند
+
+75
+00:07:37,110 --> 00:07:40,790
+ال pressure اللي هي باسكال force على area نيوتر
+
+76
+00:07:40,790 --> 00:07:47,630
+على ملي متر square عند ال energy اللي هي جول اللي
+
+77
+00:07:47,630 --> 00:07:55,390
+هي نيوتر في متر شغل عند ال power معدل استهلاك ال
+
+78
+00:07:55,390 --> 00:08:01,230
+energy اللي هي وات أو جول per second عند ال
+
+79
+00:08:01,230 --> 00:08:05,360
+electric chargeكنوم اللي هي عبارة عن امبير في
+
+80
+00:08:05,360 --> 00:08:09,760
+second لان الامبير معدل تدفق الشحنات صح؟ الامبير
+
+81
+00:08:09,760 --> 00:08:17,880
+مستويش شحنات على زمن ال potential difference اللي
+
+82
+00:08:17,880 --> 00:08:23,660
+هي voltage اللي هي volt اللي هي عبارة عن watt على
+
+83
+00:08:23,660 --> 00:08:34,350
+امبير ال electric capacitance فراداللي هي شحنة على
+
+84
+00:08:34,350 --> 00:08:40,640
+فرق الجهودElectric Resistance مقامة O مقامة Volt
+
+85
+00:08:40,640 --> 00:08:46,720
+على أمبير Magnetic Flux مقامة Weber مقامة Volt على
+
+86
+00:08:46,720 --> 00:08:51,280
+أمبير Magnetic Flux Density مقامة Tesla مقامة
+
+87
+00:08:51,280 --> 00:08:56,560
+Weber لكل متر سكوير Magnetic Flux Inductance مقامة
+
+88
+00:08:56,560 --> 00:09:02,680
+Henry مقامة Weber لكل أمبير في ال derived
+
+89
+00:09:02,680 --> 00:09:06,200
+coordinates زي ال areaعبارة واحد الطوف واحد الطول
+
+90
+00:09:06,200 --> 00:09:12,200
+meter square ان ال acceleration تغير
+
+91
+00:09:12,200 --> 00:09:18,520
+السرعة مع الزمن يعني هتكون ال acceleration area
+
+92
+00:09:18,520 --> 00:09:28,960
+meter per second لكل second هو
+
+93
+00:09:28,960 --> 00:09:34,950
+ال meter هو أساسا السرعةمتر تغير مسافة مع زمن،
+
+94
+00:09:34,950 --> 00:09:39,890
+معناته وحدة الـ X أساسا وشتوك من وحدة الطول و وحدة
+
+95
+00:09:39,890 --> 00:09:47,310
+الزمن صح؟ وحدة الطول و وحدة الزمن أعني
+
+96
+00:09:47,310 --> 00:09:52,090
+الأكسلرياشن اللي هي العجلة الزاوية Radian per
+
+97
+00:09:52,090 --> 00:09:57,670
+second square السرعة الزاوية Radian per second ال
+
+98
+00:09:57,670 --> 00:10:02,540
+density kilogramلكل متر مكعب لاحظ فيها kilogram
+
+99
+00:10:02,540 --> 00:10:08,020
+واحدة kilogram و متر مكعب يعني مشتقة من واحدات
+
+100
+00:10:08,020 --> 00:10:15,020
+أساسية ال viscosity اللي هي اللي زوجة بسكال second
+
+101
+00:10:15,020 --> 00:10:20,380
+البسكال نيوتن على المتر square و نيوتن kilogram
+
+102
+00:10:21,830 --> 00:10:26,830
+meter per second square على meter square في second
+
+103
+00:10:26,830 --> 00:10:31,290
+فبالتالي انت صفيت عندك kilogram و meter و ثانية و
+
+104
+00:10:31,290 --> 00:10:38,130
+زمن عندك ال heat flux watt على meter square ال
+
+105
+00:10:38,130 --> 00:10:42,110
+watt جول لكل second الجول ال newton في meter ال
+
+106
+00:10:42,110 --> 00:10:47,410
+newton kilogram متر ل second square صفت برضه وحدات
+
+107
+00:10:47,410 --> 00:10:53,030
+مشتقة من ال kilogram و ال meter و ال secondmoment
+
+108
+00:10:53,030 --> 00:11:03,750
+of force نيوتن نيتر specific heat انا
+
+109
+00:11:03,750 --> 00:11:11,040
+بصراحة افضل استخدم بس specific heatفي specificity
+
+110
+00:11:11,040 --> 00:11:15,420
+فيه heat capacity فبفضل أستخدم specificity اللي هي
+
+111
+00:11:15,420 --> 00:11:21,640
+جول لكل kilogram لكل kelvin velocity meter per
+
+112
+00:11:21,640 --> 00:11:26,460
+second ال volume متر مكعب فهذه كل واحدات مشتقة من
+
+113
+00:11:26,460 --> 00:11:29,880
+الواحدات الأساسية اللي هي في ال metric او الاسعار
+
+114
+00:11:29,880 --> 00:11:36,340
+system اللي هي kilogram متر و second هنشوف إيش هي
+
+115
+00:11:36,340 --> 00:11:37,340
+list radian
+
+116
+00:11:44,260 --> 00:11:53,340
+الاستردد يعني لو كان عندى كرة نص قطرها R محيط
+
+117
+00:11:53,340 --> 00:12:02,540
+الكرة اكم هكون او المساح سطحيين اربع
+
+118
+00:12:02,540 --> 00:12:08,280
+عباير مساحة الكرة اكم اربع عباير اربع تربيع
+
+119
+00:12:14,450 --> 00:12:23,110
+الان ممكن انا اعمل زاوية اجيب area area معينة
+
+120
+00:12:23,110 --> 00:12:29,790
+قيمتها R² قيمتها
+
+121
+00:12:29,790 --> 00:12:35,530
+R² و
+
+122
+00:12:35,530 --> 00:12:43,500
+اعملها curving على الاسفير و المحيط بتاعالذي هو
+
+123
+00:12:43,500 --> 00:12:47,340
+الـ spherical curve هذه أو أسطه في إيه؟ في المركز
+
+124
+00:12:47,340 --> 00:12:54,900
+بيعطيني إيه؟ مخروط الآن الزاوية هذه بيسموها solid
+
+125
+00:12:54,900 --> 00:12:59,380
+angle solid angle اللي
+
+126
+00:12:59,380 --> 00:13:05,120
+هي المساحة القيمتها R² على
+
+127
+00:13:05,120 --> 00:13:11,260
+على R² هذه one steradian
+
+128
+00:13:16,690 --> 00:13:23,130
+Stradian ال radian ايش الساوية؟
+
+129
+00:13:23,130 --> 00:13:31,490
+R على R يعني ال Stradian بالساوية
+
+130
+00:13:31,490 --> 00:13:43,630
+R على R تربيع بالساوية Radian تربيع Radian تربيع
+
+131
+00:13:45,520 --> 00:13:51,060
+طيب التلاتمية
+
+132
+00:13:51,060 --> 00:14:01,540
+و ستين درجة اكام رديان بيساوي اتنين باى يعني one
+
+133
+00:14:01,540 --> 00:14:12,370
+degree بيساوي اتنين باىع تلات مئة و ستين انا هتكون
+
+134
+00:14:12,370 --> 00:14:16,450
+باي على مية او تمانين
+
+135
+00:14:37,790 --> 00:14:43,290
+طيب ال استرادين بالساوية اتنين by يعني عندي تلت
+
+136
+00:14:43,290 --> 00:14:51,070
+مئو ستين درجة degree تكافئ
+
+137
+00:14:51,070 --> 00:15:06,490
+اتنين by radians صح؟ طيب one radian اكمل كافئ one
+
+138
+00:15:06,490 --> 00:15:11,230
+radianيكافئ مية و تمانين تلات شخصية على اتنين هو
+
+139
+00:15:11,230 --> 00:15:17,090
+مية و تمانين على ايش؟ على باى، صح؟ معناته one
+
+140
+00:15:17,090 --> 00:15:22,810
+steradian is ده حول ال degree، هذي degree مية و
+
+141
+00:15:22,810 --> 00:15:31,670
+تمانين على باى degree الكل تربيع يعني يعني one
+
+142
+00:15:31,670 --> 00:15:33,990
+steradian أكم degree بيساوي قدره مية و تمانين على
+
+143
+00:15:33,990 --> 00:15:34,710
+باى و أنا بقول إيه
+
+144
+00:15:45,000 --> 00:15:51,140
+انتوا مانفعوش تكونوا جهاز تحكم ردد
+
+145
+00:15:51,140 --> 00:15:57,880
+فعل كل بطيئة تلتلاف متين تلتلاف تمانية اكم تلتلاف
+
+146
+00:15:57,880 --> 00:16:04,140
+متين تلتلاف تمانية فاصل تمانية تلتلاف متين تلتلاف
+
+147
+00:16:04,140 --> 00:16:09,220
+تمانية فاصل تمانية degree تربيع
+
+148
+00:16:14,280 --> 00:16:19,320
+هذه واحدة ال Astridian اللي هي ال solid angle طبعا
+
+149
+00:16:19,320 --> 00:16:25,880
+ال Astridian بتحكي عن مدى معين مثلا مدى رؤية
+
+150
+00:16:25,880 --> 00:16:32,920
+الإنسان هتكون في عندك arc حوالي 200 درجة في هذا
+
+151
+00:16:32,920 --> 00:16:39,120
+الاتجاه وفي arc حوالي 135 درجة فلما عندك ال arc
+
+152
+00:16:39,120 --> 00:16:45,930
+هذا يرتقوا مع بعض بيعملsome stradians اللي هو
+
+153
+00:16:45,930 --> 00:16:49,470
+المدى المنظور لإنسان في نظر واحدة يعني بيكون شايف
+
+154
+00:16:49,470 --> 00:16:52,930
+المحيط هذا عشان يبقى يسمى solid angle يعني هم
+
+155
+00:16:52,930 --> 00:16:58,210
+بيحكي عنه 3D space عشان يسميها solid angle ال
+
+156
+00:16:58,210 --> 00:17:08,550
+radian ايه؟ بيحكي عن مستوى لأن
+
+157
+00:17:08,550 --> 00:17:11,530
+في ال major ممكن نستخدم multiplying factors
+
+158
+00:17:14,810 --> 00:17:21,910
+ممكن في حالة ازيادةعشرة أس واحد ديكا عشرة تربيع
+
+159
+00:17:21,910 --> 00:17:30,150
+هكتو عشرة أس تلاتة كيلو عشرة أس ستة ميجا عشرة أس
+
+160
+00:17:30,150 --> 00:17:36,670
+تسعة جيجا عشرة أس أتناش تيرا عشرة أس خمس عشرة كيتا
+
+161
+00:17:36,670 --> 00:17:42,150
+عشرة أس تلانتاش إكسا عشرة أس واحد عشرين زيتا عشرة
+
+162
+00:17:42,150 --> 00:17:49,420
+أس أربع عشرين يوتا هذا في الصعودفي النزول بدي أقلل
+
+163
+00:17:49,420 --> 00:17:53,640
+عشر أص ناقص واحد DC بمثال DC centimeter DC
+
+164
+00:17:53,640 --> 00:17:59,820
+centimeter عندنا كم؟ عشر .. عشر سانت عشر
+
+165
+00:17:59,820 --> 00:18:07,800
+أص ناقص اتنين سانت .. سانتمتر
+
+166
+00:18:07,800 --> 00:18:11,920
+المتر أكم سانت؟ مية .. مية يعني سانت واحد على مية
+
+167
+00:18:11,920 --> 00:18:19,850
+من المترعشر أص ناقص تلاتة ملي الميتر أكمل فيه ألف
+
+168
+00:18:19,850 --> 00:18:27,570
+يعني الميليمتر واحدة لألف من الميتر عشر
+
+169
+00:18:27,570 --> 00:18:35,700
+أص ناقص ستةmicro عشر أس ناقص تسعة nano عشر أس ناقص
+
+170
+00:18:35,700 --> 00:18:41,760
+اتناش kiko عشر أس ناقص خمستاش femto عشر أس ناقص
+
+171
+00:18:41,760 --> 00:18:47,960
+تمانتاش ato عشر أس ناقص واحد واشرين zepta عشر أس
+
+172
+00:18:47,960 --> 00:18:56,260
+ناقص أربع وعشرين yokta الان
+
+173
+00:18:56,260 --> 00:19:00,640
+هنتعرف على ال standardsالـ definition بتاع ال
+
+174
+00:19:00,640 --> 00:19:04,080
+standards الأساسية اللي هو ال meter وال kilogram
+
+175
+00:19:04,080 --> 00:19:13,400
+وال second ال
+
+176
+00:19:13,400 --> 00:19:19,860
+meter هو
+
+177
+00:19:19,860 --> 00:19:28,690
+الطول اللي بمشي شعاع من الضوءخلال فترة زمنية
+
+178
+00:19:28,690 --> 00:19:36,590
+مقدارها واحد على الرقم هذا يعني ال time هو المسافة
+
+179
+00:19:36,590 --> 00:19:41,630
+اللي مشيها المسافة ال distance هي شو يستوي X سواء
+
+180
+00:19:41,630 --> 00:19:47,870
+زمن أو سرعة احنا نحكي عن ضوء صورة الضوء اكم ساوية
+
+181
+00:19:51,360 --> 00:19:55,940
+متين و تسعة و تسعين مليون و سبعة مية و اتنين و
+
+182
+00:19:55,940 --> 00:20:02,000
+ستعين قرارين و خمسين meter per second و هذا هذا
+
+183
+00:20:02,000 --> 00:20:04,520
+الزمن واحد على متين و تسعة و تسعين مليون و سبعة
+
+184
+00:20:04,520 --> 00:20:08,320
+مية و تسعين قرارين و خمسين second الظروف المعضلة
+
+185
+00:20:08,320 --> 00:20:15,460
+ايه اللي هيحيطينا النتيجة واحد واحد meter طبعا في
+
+186
+00:20:15,460 --> 00:20:17,780
+الفراغ طبعا في الفراغ
+
+187
+00:20:21,390 --> 00:20:26,150
+طيب واحد انش تحويل من انش لصنطن بيساوي اتنين بوانت
+
+188
+00:20:26,150 --> 00:20:39,110
+خمس اربعة صنطن او واحد انش بيساوي خمس و عشرين ملي
+
+189
+00:20:39,110 --> 00:20:45,190
+متر ال
+
+190
+00:20:45,190 --> 00:20:52,510
+kilogram فعندي كتلة محفوظة فيفي ال international
+
+191
+00:20:52,510 --> 00:20:56,290
+bureau of weights and measures في باريس كتلة
+
+192
+00:20:56,290 --> 00:21:04,570
+محفوظة من البلدين platinum and iridium هذي اتفقوا
+
+193
+00:21:04,570 --> 00:21:10,270
+العالم ان هذي one kilogram one kilogram طبعا في
+
+194
+00:21:10,270 --> 00:21:14,950
+وحدة تانية one pound mass بسبب وقت اربع خمس تلاتة
+
+195
+00:21:14,950 --> 00:21:17,830
+خمسة تسعة اتنين تلاتة سبعة kilogram
+
+196
+00:21:26,750 --> 00:21:31,270
+هنجيلها، اسمعولى شوية يعني عادة ممكن تستخدم أول
+
+197
+00:21:31,270 --> 00:21:40,450
+تلت أرقام ال
+
+198
+00:21:40,450 --> 00:21:47,850
+second هي الفترة لتسع
+
+199
+00:21:47,850 --> 00:21:56,630
+مليونو192 و 631 بون سبعة سبعة دورة period دورة من
+
+200
+00:21:56,630 --> 00:22:00,970
+ال radiations اللي بتصير خلال انتقال من مستوى
+
+201
+00:22:00,970 --> 00:22:09,190
+لمستوى في حالة ضربة ال ايش ال cesium 133 و 30 لان
+
+202
+00:22:09,190 --> 00:22:12,490
+طبعا في تفاصيل كتير في الكتاب على الموضوع بس انا
+
+203
+00:22:12,490 --> 00:22:16,050
+ملخص الاشي الأساسي بحاول اخليه applied اكتر
+
+204
+00:22:20,020 --> 00:22:24,300
+الحرارة ال basic unit of temperature هي ال Kelvin
+
+205
+00:22:24,300 --> 00:22:28,880
+عندك
+
+206
+00:22:28,880 --> 00:22:31,620
+ال Kelvin اللي هي واحد عامة تلاشين point واحداشر
+
+207
+00:22:31,620 --> 00:22:35,860
+of thermodynamic temperature of triple point of
+
+208
+00:22:35,860 --> 00:22:40,420
+water ال triple point للميههى درجة الحرارة اللى
+
+209
+00:22:40,420 --> 00:22:47,520
+بيكون فى اتزان بين الحالة السائلة والصلبة والغازية
+
+210
+00:22:47,520 --> 00:22:55,660
+يعنى ال face diagram للميه عندهين
+
+211
+00:22:55,660 --> 00:23:01,120
+درجة الحرارة هناش الضغط هاد ال triple point
+
+212
+00:23:08,070 --> 00:23:13,670
+عندي هنا solid هنا
+
+213
+00:23:13,670 --> 00:23:26,590
+gas او بخار هنا liquid مثلا
+
+214
+00:23:26,590 --> 00:23:31,750
+عند واحد bar ضغط
+
+215
+00:23:31,750 --> 00:23:35,190
+جوي واحد bar الميه
+
+216
+00:23:37,030 --> 00:23:40,370
+بتغلي يعني بتتحول من حالة سائلة لحالة غزية عند أكم
+
+217
+00:23:40,370 --> 00:23:45,710
+مية لو
+
+218
+00:23:45,710 --> 00:23:54,070
+قللت الضغط هتغلل الميه عنده درجة حرارة اقل لو زوات
+
+219
+00:23:54,070 --> 00:24:02,490
+الضغط هتزيد درجة الغليان طيب
+
+220
+00:24:05,170 --> 00:24:09,050
+التحوير بين ال Celsius اللي هي C بستوى Kelvin
+
+221
+00:24:09,050 --> 00:24:17,650
+مانقسمتين و تلات سبعين point واحد خمسة في
+
+222
+00:24:17,650 --> 00:24:23,110
+ال ITS 90 اللي هي international temperature scale
+
+223
+00:24:23,110 --> 00:24:26,090
+of الف وتسعين وتسعين لسنة تسعين
+
+224
+00:24:29,150 --> 00:24:31,910
+establishes means of determining any temperature
+
+225
+00:24:31,910 --> 00:24:35,530
+from one six five Kelvin to more than four
+
+226
+00:24:35,530 --> 00:24:40,870
+thousand Kelvin بيعطيني definitions لدرجات الحرارة
+
+227
+00:24:40,870 --> 00:24:43,910
+يعني
+
+228
+00:24:43,910 --> 00:24:47,570
+.. يعني هذه standard بيبقى متفقة يعني مثلا حرارة
+
+229
+00:24:47,570 --> 00:24:53,970
+الغرفة حاليا مثلا نحكي خمستاشر درجة مثلا يعني ليش
+
+230
+00:24:53,970 --> 00:24:59,960
+ما تكون أسميها عشرين؟مش مانع أسميها عشرين صح؟ أو
+
+231
+00:24:59,960 --> 00:25:09,100
+أسميها مية أو أسميها سفر، فيه معنى؟ لكن اتفاق و هو
+
+232
+00:25:09,100 --> 00:25:13,420
+هذي سموها خمستاش أو سموها عشرين، فبصير عندي إيش
+
+233
+00:25:13,420 --> 00:25:17,960
+مرجعيات، reference إذا هذي خمستاش، هذي عشرين، هذي
+
+234
+00:25:17,960 --> 00:25:20,320
+تلاتين، واحد كذا، ففي عندي اتفاق معين
+
+235
+00:25:23,410 --> 00:25:26,010
+الان في اجهزة تستخدم في ال standardization
+
+236
+00:25:26,010 --> 00:25:29,090
+للتمبراتور فاندي ال standardized pyrometer فاندي
+
+237
+00:25:29,090 --> 00:25:31,650
+ال standardized resistance thermometer و ال
+
+238
+00:25:31,650 --> 00:25:36,210
+standardized gas thermometer عند ال ranking بيستوى
+
+239
+00:25:36,210 --> 00:25:37,970
+واحد و واحدة و واحدة و واحدة و واحدة و واحدة و
+
+240
+00:25:37,970 --> 00:25:38,770
+واحدة و واحدة و واحدة و واحدة و واحدة و واحدة و
+
+241
+00:25:38,770 --> 00:25:38,970
+واحدة و واحدة و واحدة و واحدة و واحدة و واحدة و
+
+242
+00:25:38,970 --> 00:25:39,650
+واحدة و واحدة و واحدة و واحدة و واحدة و واحدة و
+
+243
+00:25:39,650 --> 00:25:40,230
+واحدة و واحدة و واحدة و واحدة و واحدة و واحدة و
+
+244
+00:25:40,230 --> 00:25:41,090
+واحدة و واحدة و واحدة و واحدة و واحدة و واحدة و
+
+245
+00:25:41,090 --> 00:25:41,850
+واحدة و واحدة
+
+246
+00:25:47,620 --> 00:25:49,580
+الـ ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+247
+00:25:49,580 --> 00:25:49,760
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+248
+00:25:49,760 --> 00:25:49,820
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+249
+00:25:49,820 --> 00:25:50,420
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+250
+00:25:50,420 --> 00:25:50,840
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+251
+00:25:50,840 --> 00:25:51,820
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+252
+00:25:51,820 --> 00:26:00,140
+ال .. ال .. ال ..
+
+253
+00:26:00,140 --> 00:26:00,180
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+254
+00:26:00,180 --> 00:26:00,660
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+255
+00:26:00,660 --> 00:26:00,720
+ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال
+
+256
+00:26:00,720 --> 00:26:01,140
+.. ال .. ال .. ال .. ال .. ال .. ال .. ال .. ال ..
+
+257
+00:26:01,140 --> 00:26:04,720
+ال .. ال .. ال .. ال .. ال .. ال ..
+
+258
+00:26:04,720 --> 00:26:06,780
+ال ..
+
+259
+00:26:11,160 --> 00:26:14,780
+اللي هي ايش؟ Zero Kelvin او ماقص مائتين و تلت
+
+260
+00:26:14,780 --> 00:26:17,980
+سبعين هذا ماقص مائتين و تلت سبعين point واحد خمسة
+
+261
+00:26:17,980 --> 00:26:27,280
+هي Zero Kelvin هذا ال absolute zero absolute zero
+
+262
+00:26:32,580 --> 00:26:37,240
+في درجة تانية ماقص مائة وتسعة وتمانين هادئ ماقص
+
+263
+00:26:37,240 --> 00:26:41,500
+مائة وتسعة تمانين point three four four اتنين
+
+264
+00:26:41,500 --> 00:26:47,280
+Celsius لتعادل تلات تمانين point تمانية zero five
+
+265
+00:26:47,280 --> 00:26:54,040
+Kelvin هي ل triple point of argon triple point of
+
+266
+00:26:54,040 --> 00:27:00,530
+argon هي حرارة التوازن بين الحالاتالصلبة والسائلة
+
+267
+00:27:00,530 --> 00:27:10,350
+والغزية لعنصر ايش ال argon يعني الان
+
+268
+00:27:10,350 --> 00:27:17,430
+عندي هيحط level معين بعدين عندي material تلات
+
+269
+00:27:17,430 --> 00:27:23,430
+سبعين point واحد ستة هذا ال triple point للميه
+
+270
+00:27:24,920 --> 00:27:35,660
+عندي 505.078 Kelvin اللي هي درجة التزام بين الحالة
+
+271
+00:27:35,660 --> 00:27:39,660
+السائلة والصلبة يعني هي تمثل إذا أعطيته حرارة
+
+272
+00:27:39,660 --> 00:27:46,500
+بتسيح إذا استخدمت أسحاب حرارة بتتجمد هي اللي ..
+
+273
+00:27:46,500 --> 00:27:52,040
+اللي .. اللي .. اللي احنا حكينااللي هي 505 point O
+
+274
+00:27:52,040 --> 00:27:55,260
+78 درجة التوازن بين الحالة الصلبة و الحالة الصلبة
+
+275
+00:27:55,260 --> 00:28:02,480
+لمعدن القصدية 692
+
+276
+00:28:02,480 --> 00:28:09,840
+point 677 هي zinc point اللي هي توازن بين الحالة
+
+277
+00:28:09,840 --> 00:28:14,770
+الصلبة و الحالة الصلبة لمعدن الزنكتسعمية و تلاتة و
+
+278
+00:28:14,770 --> 00:28:19,590
+تلاتين point أربعة سبعة تلاتة Kelvin هي اتزان بين
+
+279
+00:28:19,590 --> 00:28:24,170
+الحلسة و الحلسة الصلبة للألمنيوم الف و أربعة
+
+280
+00:28:24,170 --> 00:28:31,070
+تلاتين point تسعة تلاتة silver اللي هي توازن بين
+
+281
+00:28:31,070 --> 00:28:35,730
+الحلسة و الحلسة الصلبة لمعدن ال silverألف تلاتين
+
+282
+00:28:35,730 --> 00:28:39,270
+سوى تلاتين bon تلات تلاتة هي التوازن بين الحالة
+
+283
+00:28:39,270 --> 00:28:43,870
+السائلة والحالة الصلبة لمعدن الذهب فهيك بطريقة هذه
+
+284
+00:28:43,870 --> 00:28:54,650
+عرف temperature scale لأن
+
+285
+00:28:54,650 --> 00:28:57,830
+في عند ال system of units four dimensions are
+
+286
+00:28:57,830 --> 00:29:03,230
+considered for each system with derived unit
+
+287
+00:29:04,150 --> 00:29:10,150
+underscored مثلا عندي في الاص I units عندي واحدة
+
+288
+00:29:10,150 --> 00:29:16,150
+الطول ايش واحدة الزمن ثانية واحدة ال kilogram
+
+289
+00:29:16,150 --> 00:29:27,210
+نيوتن واحدة الكتلة kilogram لنيوتن نيوتن
+
+290
+00:29:27,210 --> 00:29:32,290
+طب
+
+291
+00:29:32,290 --> 00:29:32,870
+عندي كتلة
+
+292
+00:29:36,670 --> 00:29:46,930
+وزنها واحد kilogram ال
+
+293
+00:29:46,930 --> 00:29:51,710
+newton هي قيمة القوة المطلوبة عشان احرك الكتلة هذه
+
+294
+00:29:51,710 --> 00:29:54,810
+ب acceleration واحد meter per second squared يعني
+
+295
+00:29:54,810 --> 00:29:57,350
+ال newton هيكون kilogram
+
+296
+00:29:59,670 --> 00:30:02,990
+في meter per second squared يعني هي ال force
+
+297
+00:30:02,990 --> 00:30:07,850
+اللازمة عشان احرك كتلة قيمتها واحد kilogram ب
+
+298
+00:30:07,850 --> 00:30:12,470
+acceleration meter per second squared هذه واحدة
+
+299
+00:30:12,470 --> 00:30:20,730
+ايش لنيوتن في عندي اللي هو عندي cgs يعني واحدة طول
+
+300
+00:30:20,730 --> 00:30:28,370
+سنتمترالزمن second الكتلة ايه ايه؟ اجرام بعرف
+
+301
+00:30:28,370 --> 00:30:33,490
+الدين الدين اللي
+
+302
+00:30:33,490 --> 00:30:42,570
+هو بالساوي واحد اجرام في ال centimeter يعني
+
+303
+00:30:42,570 --> 00:30:47,610
+الدين هي ال force اللي لازمة عشان احرك كتلة كمتها
+
+304
+00:30:47,610 --> 00:30:50,940
+واحد اجرامب ال acceleration ال centimeter على
+
+305
+00:30:50,940 --> 00:30:56,520
+second square يعني لو بدرجة حلال الميوتن ال gram
+
+306
+00:30:56,520 --> 00:31:04,580
+شو تساوي؟ واح عشرة أسالب تلاتة kilogram وال
+
+307
+00:31:04,580 --> 00:31:10,920
+centimeter عشرة أسالب اتنين متر على second square
+
+308
+00:31:10,920 --> 00:31:16,980
+يعني هتكون ال dying عشرة أسالب خمسة نيوتن صح؟
+
+309
+00:31:21,860 --> 00:31:27,060
+في عندي English Engineering في عندي Absolute
+
+310
+00:31:27,060 --> 00:31:31,680
+English وفي Technical English ال English
+
+311
+00:31:31,680 --> 00:31:39,440
+Engineering الطول قدم و الزمن تانية و ال mass
+
+312
+00:31:39,440 --> 00:31:47,420
+pound mass pound mass ال pound force pound force
+
+313
+00:31:50,090 --> 00:31:59,190
+بالساوية pound mass في اتنين و تلاتين point واحد
+
+314
+00:31:59,190 --> 00:32:05,310
+سبعة قدم ما
+
+315
+00:32:05,310 --> 00:32:09,910
+انا بتقول pound force هي ال force اللازمة عشان
+
+316
+00:32:09,910 --> 00:32:14,140
+احرك كتلة كلمة one pound massبacceleration قمت
+
+317
+00:32:14,140 --> 00:32:17,760
+اتنين وتلاتين point واحد سبعة قدم على second تربيه
+
+318
+00:32:17,760 --> 00:32:24,420
+حدث ال English engineering absolute English واحدة
+
+319
+00:32:24,420 --> 00:32:32,020
+طول قدم الزمن second وعندي pound mass بعرف ال
+
+320
+00:32:32,020 --> 00:32:39,340
+poundel poundel بس
+
+321
+00:32:39,340 --> 00:32:40,500
+one pound mass
+
+322
+00:32:43,590 --> 00:32:51,070
+في foot per second square ال powder اللي هو ال
+
+323
+00:32:51,070 --> 00:32:55,870
+force اللي لازمة عشان احرق كتلة قيمتها one pound
+
+324
+00:32:55,870 --> 00:33:01,210
+mass بتسارع قيمته واحد foot على second square
+
+325
+00:33:04,450 --> 00:33:10,950
+فاني ال technical English units الطول foot قدم و
+
+326
+00:33:10,950 --> 00:33:18,490
+الزمن second و الكتلة slug بعرف انا ال pound force
+
+327
+00:33:18,490 --> 00:33:31,910
+ال pound force بالساوية slug واحد slug في واحد
+
+328
+00:33:31,910 --> 00:33:38,890
+footper second squared يعني ال pound force هي ال
+
+329
+00:33:38,890 --> 00:33:42,870
+force اللي لازم عشان احرق كتلة تمتها slug بتسارع
+
+330
+00:33:42,870 --> 00:33:45,650
+قيمته one foot per second يعني لو قسمت هذه على هذه
+
+331
+00:33:45,650 --> 00:33:49,850
+بالسيران
+
+332
+00:33:49,850 --> 00:33:55,830
+دي واحد بالساوة اتنين و تلاتين point واحد سبعة
+
+333
+00:33:55,830 --> 00:34:04,290
+pound mass علياش slug يعني ال slug
+
+334
+00:34:07,560 --> 00:34:13,840
+الاسلاجي شو يستوي؟ واحد على اتنين و تلاتين بوت
+
+335
+00:34:13,840 --> 00:34:26,080
+واحد سبعة pound mass تشوف
+
+336
+00:34:26,080 --> 00:34:26,540
+مثال
+
+337
+00:34:35,640 --> 00:34:38,560
+determine the conversion factor between pound
+
+338
+00:34:38,560 --> 00:34:47,020
+force and newton نوجد التحويل من pound force ل
+
+339
+00:34:47,020 --> 00:34:55,180
+newton pound force ايه؟ pound
+
+340
+00:34:55,180 --> 00:35:02,760
+force واحد pound force بيساوي 32
+
+341
+00:35:07,130 --> 00:35:17,130
+pound mass foot على second square طيب بيساوي 32 ال
+
+342
+00:35:17,130 --> 00:35:24,210
+pound mass أكم كيلو جرام واحد
+
+343
+00:35:24,210 --> 00:35:30,910
+pound mass بيساوي point أربعة point أربعة خمسة
+
+344
+00:35:30,910 --> 00:35:32,770
+تلاتة
+
+345
+00:35:35,600 --> 00:35:40,480
+هنا كتبة كلها خمسة تسعة تلاتة
+
+346
+00:35:40,480 --> 00:35:45,640
+سبعة kilogram
+
+347
+00:35:45,640 --> 00:35:56,320
+per pound mass في واحد pound mass في الفوتا كام
+
+348
+00:35:56,320 --> 00:36:02,820
+متر؟ الفوتا
+
+349
+00:36:02,820 --> 00:36:03,500
+كام متر؟
+
+350
+00:36:07,760 --> 00:36:11,120
+مين أكبر؟ ال foot ولا ال meter؟ ال meter طيب يعني
+
+351
+00:36:11,120 --> 00:36:14,060
+اتواش هتكون ال conversion أكبر واحد ولا أقل واحد؟
+
+352
+00:36:14,060 --> 00:36:18,980
+أقل واحد أقل واحد يعني أكم؟ ال meter أكم قدم
+
+353
+00:36:18,980 --> 00:36:27,480
+تقريبا؟ تلات تلات يعني .. اه؟ تلات مية و تلات قدم
+
+354
+00:36:29,930 --> 00:36:32,230
+يعني إذا بتعرفوش تحسبوا الحسوب لو أنتوا حكيتوا
+
+355
+00:36:32,230 --> 00:36:36,410
+المتر تلت أقدام تلت أقدام تقريبا يعني المفروض يكون
+
+356
+00:36:36,410 --> 00:36:39,930
+bone تلاتة something صح؟ مازال .. اذا المتر تلت
+
+357
+00:36:39,930 --> 00:36:43,310
+أقدام معناته القدم حوالي تلت متر ما تحكوليش تمانية
+
+358
+00:36:43,310 --> 00:36:48,510
+أو أربعة و عشرين مش عارف إيش تحذروا هيكون
+
+359
+00:36:48,510 --> 00:36:55,230
+bone تلاتة سفر أربعة تمانية متر لكل foot
+
+360
+00:36:59,150 --> 00:37:07,830
+وال second هي second يعني one pound force بالساوية
+
+361
+00:37:07,830 --> 00:37:14,850
+طبعا السينا دي kilogram متر per second square اللي
+
+362
+00:37:14,850 --> 00:37:17,570
+هو ايش نيوتن يعني انتظروا اتنين و تلاتين point
+
+363
+00:37:17,570 --> 00:37:20,870
+واحد سبعة في point اربعة تلاتة خمسة تلاتة خمسة
+
+364
+00:37:20,870 --> 00:37:24,450
+تسعة اتنين تلاتة سبعة في point تلاتة صفر اربعة
+
+365
+00:37:24,450 --> 00:37:25,370
+تلاتة يعني ايش الجواب بيطلع
+
+366
+00:37:30,670 --> 00:37:44,050
+أربعة point أربعة أربعة سبعة نعم يعني
+
+367
+00:37:44,050 --> 00:37:54,110
+هكون in Newton هيك صح؟ ماشي
+
+368
+00:38:05,060 --> 00:38:19,580
+يعني هتكون ستة ستة سبعة ستة ستة يعني تمانى water
+
+369
+00:38:19,580 --> 00:38:33,760
+of
+
+370
+00:38:33,760 --> 00:38:40,610
+densityraw عندى ميه كتفتها روه
+
+371
+00:38:40,610 --> 00:38:47,930
+و dynamic viscosity ميوه flows with velocity v
+
+372
+00:38:47,930 --> 00:38:52,310
+through a pipe of diameter دى الميه بتتدفق في
+
+373
+00:38:52,310 --> 00:38:57,450
+انبوب قطرها دى احسب رينالدز number رينالدز number
+
+374
+00:38:57,450 --> 00:39:02,590
+اللى هو ر ايه
+
+375
+00:39:02,590 --> 00:39:03,970
+بستوى اللى هى روه
+
+376
+00:39:07,360 --> 00:39:14,620
+VD على ميو هنروح ل ال metric units ال روح وحدتها
+
+377
+00:39:14,620 --> 00:39:19,600
+ال
+
+378
+00:39:19,600 --> 00:39:23,800
+روح kilogram على
+
+379
+00:39:23,800 --> 00:39:26,500
+متر تكيب السرعة
+
+380
+00:39:28,440 --> 00:39:35,920
+متر على ال ساكن وال دي واحدة اتوا قطر متر على
+
+381
+00:39:35,920 --> 00:39:39,040
+البسكس
+
+382
+00:39:39,040 --> 00:39:49,010
+ديباسكال ثانية صح باسكال ثانية نحكي الميو بيساوي
+
+383
+00:39:49,010 --> 00:39:57,050
+باسكال ثانية اللي هي نيوتن على متر تربيع في ثانية
+
+384
+00:39:57,050 --> 00:40:03,870
+صح بتساوي النيوتن
+
+385
+00:40:03,870 --> 00:40:09,230
+عبارة عن كيلو جرام النيوتن عبارة عن كيلو جرام متر
+
+386
+00:40:10,730 --> 00:40:16,890
+على second تربيع وفي تحت اندياش متر تربيع في
+
+387
+00:40:16,890 --> 00:40:26,670
+second صح؟ هنا هيكون kilogram على متر على second
+
+388
+00:40:26,670 --> 00:40:36,590
+هنعوض هنا ال miu اللي هي kilogram على متر على
+
+389
+00:40:36,590 --> 00:40:43,080
+secondيعني kilogram هتروح مع kilogram صح؟ وهي عندى
+
+390
+00:40:43,080 --> 00:40:47,760
+متر متر بتروح هدى والمتر التحت هين بروح مع المتر
+
+391
+00:40:47,760 --> 00:40:54,020
+هدى والسكن بستكن منتهيهش unitless صح؟ unitless
+
+392
+00:40:54,020 --> 00:41:02,100
+ريلز لمبارد مش الوحدات unit
+
+393
+00:41:02,100 --> 00:41:03,480
+less
+
+394
+00:41:10,310 --> 00:41:16,290
+ال race number هو ratio between two forces، إذا في
+
+395
+00:41:16,290 --> 00:41:21,050
+عندى flow في two forces، في two forces نتيجة ال
+
+396
+00:41:21,050 --> 00:41:26,930
+inertia بتاعته، التدفق، السرعة، gravity، وفي
+
+397
+00:41:26,930 --> 00:41:31,740
+forces مقاومة، اللي هي نتيجة اللزوجة بتاعتهاللي هي
+
+398
+00:41:31,740 --> 00:41:37,380
+احتكاك الداخل بين طبقات الفلود هذا ايش اللزوجة
+
+399
+00:41:37,380 --> 00:41:45,580
+يعني اذا مشيت في انبوب ميه
+
+400
+00:41:45,580 --> 00:41:53,160
+هاي حالةمشيت بصورة وصولة عشرة متر في الثانية حالة
+
+401
+00:41:53,160 --> 00:41:58,760
+تانية مشيت هوا بعشرة متر في الثانية حالة تالتة
+
+402
+00:41:58,760 --> 00:42:07,580
+مشيت عسل بصورة عشرة متر في الثانية number هيختلف
+
+403
+00:42:07,580 --> 00:42:16,760
+الحالات ليش؟ اولش عندك الكثافة وعندي ايش؟ ال mu
+
+404
+00:42:21,610 --> 00:42:24,670
+عشان هيك بعض احيان بكتب runs number بالصيغة runs
+
+405
+00:42:24,670 --> 00:42:32,210
+number بيساوي بقسم بسط على row و المقطع على row VD
+
+406
+00:42:32,210 --> 00:42:42,650
+على Mu على row بيساوي VD على Nu حاجة يسموها
+
+407
+00:42:42,650 --> 00:42:44,550
+kinematic
+
+408
+00:42:46,750 --> 00:42:51,150
+viscosity kinematic viscosity فانا في الآخر عندي
+
+409
+00:42:51,150 --> 00:42:57,450
+ratio between inertia forces على internal friction
+
+410
+00:42:57,450 --> 00:43:00,650
+force بين اللي هو ال friction due to viscosity بين
+
+411
+00:43:00,650 --> 00:43:01,750
+طبقات ال fluid
+
+412
+00:43:06,850 --> 00:43:11,790
+بنحسب ال number باستخدام ال English units مرة و
+
+413
+00:43:11,790 --> 00:43:17,670
+برة باستخدام ال SI units ومعطين القطر النبوب
+
+414
+00:43:17,670 --> 00:43:18,630
+تمانية انش
+
+415
+00:43:26,480 --> 00:43:32,260
+الانش محوله لقدم، القدم تمانية انش، اتناشر انش،
+
+416
+00:43:32,260 --> 00:43:36,360
+يعني القسم على اتناش، بيصير تمانية على اتناش قدم،
+
+417
+00:43:36,360 --> 00:43:39,840
+و القدم بيساوي point three zero four eight متر
+
+418
+00:43:39,840 --> 00:43:45,640
+حوله ليهش لمتر ال raw ال density معطيني اتنين ستين
+
+419
+00:43:45,640 --> 00:43:50,940
+point تلاتة pound mass لكل قدم تكيب، حول ال pound
+
+420
+00:43:50,940 --> 00:43:56,640
+mass ل kilogram و القدم لمتروحسب ال density تطلع
+
+421
+00:43:56,640 --> 00:44:02,760
+998 kilogram على المتر المكعب ال flow كان ماشي في
+
+422
+00:44:02,760 --> 00:44:09,740
+النبوب بسرعة أربع قدم على الثانية في الوحدات ال
+
+423
+00:44:09,740 --> 00:44:15,940
+metric او ال ASI 1.22 متر per second ال kinematic
+
+424
+00:44:15,940 --> 00:44:20,640
+او ال dynamic viscosityتنين point او اتنين في عشر
+
+425
+00:44:20,640 --> 00:44:24,960
+أس ناقص خمس pound force في second على foot square
+
+426
+00:44:24,960 --> 00:44:28,980
+حولها لأسئلة units تسعة point ستة ساعة في عشر أس
+
+427
+00:44:28,980 --> 00:44:38,560
+ناقص خمسة نيوتن second على meter square الان ايش
+
+428
+00:44:38,560 --> 00:44:43,220
+ال conversion factor ل real number في حال استخدام
+
+429
+00:44:43,220 --> 00:44:44,280
+English units
+
+430
+00:44:47,650 --> 00:44:51,850
+و بدي احول و اهد حالة و الحالة اللى استخدمت اصعى
+
+431
+00:44:51,850 --> 00:44:58,410
+units هل هيكون في conversion factor بينهم؟
+
+432
+00:44:58,410 --> 00:45:01,770
+هش
+
+433
+00:45:01,770 --> 00:45:06,430
+ال conversion factor واحد لان هو unit less نتأكد
+
+434
+00:45:06,430 --> 00:45:10,130
+لان the real number في حالة ال English units هيكون
+
+435
+00:45:10,130 --> 00:45:18,710
+يستوى عندك رو VD على MUالرو في حالة ال English
+
+436
+00:45:18,710 --> 00:45:25,950
+units اللي هي اتنين و ستين point تلاتة pound mass
+
+437
+00:45:25,950 --> 00:45:40,110
+على القدم تكيب السرعة ال V اربعة قدم على
+
+438
+00:45:40,110 --> 00:45:47,980
+ال second في ال D تمانية على اتناش قدم صح؟تبقى ع
+
+439
+00:45:47,980 --> 00:45:56,000
+طناش تمانية على اتناش قدم على ال dynamic viscosity
+
+440
+00:45:56,000 --> 00:46:05,740
+اللي هي two point او اتنين عشر أقل سالب خمسة pound
+
+441
+00:46:05,740 --> 00:46:15,840
+force second على قدم تربيع تشوف شرط اللي تقتصر
+
+442
+00:46:19,280 --> 00:46:27,900
+يعني عندي هين هذه و هذه بروح التكييب و هذه تروح مع
+
+443
+00:46:27,900 --> 00:46:32,140
+هذه صح؟ بيضال
+
+444
+00:46:32,140 --> 00:46:38,720
+عندي حسبولي الرقم 62.3 في 4 في 8 ع 12 على 2.02 في
+
+445
+00:46:38,720 --> 00:46:44,240
+10 أس نقل 6 حسبولي دي ايه؟ 82.64 في 8 ع 14 أس 3
+
+446
+00:46:44,240 --> 00:46:44,940
+أكم؟
+
+447
+00:46:48,940 --> 00:46:53,540
+أيوة point كام؟
+
+448
+00:46:53,540 --> 00:47:00,380
+point اتنين اربعة اربعة غلط point اتنين فقط ده
+
+449
+00:47:00,380 --> 00:47:04,420
+عشرة و أستلاتة ده عشرة و أستلاتة على أغلب الرقم
+
+450
+00:47:04,420 --> 00:47:09,860
+هذا مش صح عشرة و أستلاتة عشرة و أستلاتة يعني plus
+
+451
+00:47:09,860 --> 00:47:10,960
+اتنين و عشرين مليون
+
+452
+00:47:16,530 --> 00:47:23,830
+ع الأغلب الرقم هذا غلط يعطينا
+
+453
+00:47:23,830 --> 00:47:28,350
+رقم صح تمانية
+
+454
+00:47:28,350 --> 00:47:32,570
+تمانية في
+
+455
+00:47:32,570 --> 00:47:36,170
+عشرة عشر السالب أربعة
+
+456
+00:47:41,440 --> 00:47:45,220
+يا جماعة خلّي عليكم إحساس بالأرقام أنت عندك عشر أس
+
+457
+00:47:45,220 --> 00:47:49,460
+ناقص خمسة هتطلع فوق مش معقول هذا الرقم يكون صح قصة
+
+458
+00:47:49,460 --> 00:47:56,000
+أس ستة أعطوني رقم احسوني ايه اكمت ويطلع عندك
+
+459
+00:47:56,000 --> 00:48:06,260
+تمانية بس تانية وعشرين ايوة عشرة أس ستة pound mass
+
+460
+00:48:06,260 --> 00:48:08,340
+pound mass على
+
+461
+00:48:14,890 --> 00:48:23,170
+pound mass على pound force وفيه
+
+462
+00:48:23,170 --> 00:48:33,550
+تحت اندق second تربيع صح اظهر؟ اصفر
+
+463
+00:48:33,550 --> 00:48:39,190
+شوية ال pound force مش مستوى ال
+
+464
+00:48:39,190 --> 00:48:39,970
+pound force
+
+465
+00:48:43,440 --> 00:48:49,280
+نين و تلاتين point واحد سبعتاش pound mass قدم على
+
+466
+00:48:49,280 --> 00:48:54,240
+سكن تربيع قدم على سكن تربيع قدم على سكن تربيع قدم
+
+467
+00:48:54,240 --> 00:48:54,840
+على سكن تربيع قدم على سكن تربيع قدم على سكن تربيع
+
+468
+00:48:54,840 --> 00:48:55,560
+قدم على سكن تربيع قدم على سكن تربيع قدم على سكن
+
+469
+00:48:55,560 --> 00:48:55,640
+تربيع قدم على سكن تربيع قدم على سكن تربيع قدم على
+
+470
+00:48:55,640 --> 00:48:55,660
+سكن تربيع قدم على سكن تربيع قدم على سكن تربيع قدم
+
+471
+00:48:55,660 --> 00:48:55,680
+على سكن تربيع قدم على سكن تربيع قدم على سكن تربيع
+
+472
+00:48:55,680 --> 00:48:58,540
+قدم على سكن تربيع قدم على سكن تربيع قدم على سكن
+
+473
+00:48:58,540 --> 00:49:01,900
+تربيع قدم على سكن تربيع قدم على سكن تربيع قدم على
+
+474
+00:49:01,900 --> 00:49:04,760
+سكن تربيع ق
+
+475
+00:49:14,120 --> 00:49:23,400
+foot على ايه؟ foot على second تربيع و في second
+
+476
+00:49:23,400 --> 00:49:28,800
+تربيع في الأرض؟ نعم و في عنده هنا في foot هنا هنا
+
+477
+00:49:28,800 --> 00:49:36,840
+في foot تحت واحد foot صح؟ في second تربيع؟ اه
+
+478
+00:49:39,820 --> 00:49:45,080
+و في second تربية تحت هنا مظبوط هيروح اندي pound
+
+479
+00:49:45,080 --> 00:49:49,920
+mass مع pound mass second تربية تربية تربية تربية
+
+480
+00:49:49,920 --> 00:49:50,720
+تربية تربية تربية تربية تربية تربية تربية تربية
+
+481
+00:49:50,720 --> 00:49:50,980
+تربية تربية تربية تربية تربية تربية تربية تربية
+
+482
+00:49:50,980 --> 00:49:51,660
+تربية تربية تربية تربية تربية تربية تربية تربية
+
+483
+00:49:51,660 --> 00:49:52,200
+تربية تربية تربية تربية تربية تربية تربية تربية
+
+484
+00:49:52,200 --> 00:49:55,240
+تربية تربية تربية تربية تربية تربية تربية تربية
+
+485
+00:49:55,240 --> 00:49:55,260
+تربية تربية تربية تربية تربية تربية تربية تربية
+
+486
+00:49:55,260 --> 00:49:58,840
+تربية تربية تربية
+
+487
+00:49:58,840 --> 00:50:04,940
+تربية تربية تربية
+
+488
+00:50:04,940 --> 00:50:05,080
+ت
+
+489
+00:50:10,130 --> 00:50:15,230
+خمسة ستة عشر
+
+490
+00:50:15,230 --> 00:50:23,110
+أس خمسة هذا رنز دمبة لو بدى أحسبه باستخدام ال
+
+491
+00:50:23,110 --> 00:50:29,310
+metric units برضه
+
+492
+00:50:29,310 --> 00:50:38,190
+رنز دمبة رو VD على ميو في ال metric ال رو عندى
+
+493
+00:50:42,630 --> 00:50:51,610
+الروعن دي تسعمية وتمانية تسعين kilogram على متر
+
+494
+00:50:51,610 --> 00:50:58,850
+مكعب ال V واحد point اتنين وعشرين meter على second
+
+495
+00:50:58,850 --> 00:51:07,350
+ال D point اتنين meter
+
+496
+00:51:07,350 --> 00:51:09,490
+على ميو
+
+497
+00:51:17,010 --> 00:51:23,690
+تسعة عشرة النوتن
+
+498
+00:51:23,690 --> 00:51:28,930
+اللي هي عبارة عن أياش kilogram متر على second
+
+499
+00:51:28,930 --> 00:51:37,670
+تربيع في second على متر تربيع عندي هاي kilogram
+
+500
+00:51:37,670 --> 00:51:44,600
+بقى kilogramهيميت واحد اتنين تلاتة و بعدين واحد
+
+501
+00:51:44,600 --> 00:51:52,420
+هنا بروح و واحد هنا و هذا مع هذا سكن مع سكن و
+
+502
+00:51:52,420 --> 00:51:59,860
+هذا مع هذا، هكم بيطلع؟ اسمه ليه؟ اتنين،
+
+503
+00:51:59,860 --> 00:52:03,680
+خمس، ستة، عشر أسالف، خمس
+
+504
+00:52:16,980 --> 00:52:21,060
+في اي سؤال؟ هي كنت خلصت الشرب توردتني يعني، تاكلوا
+
+505
+00:52:21,060 --> 00:52:21,380
+عافية
+
diff --git a/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/zDK1nQS1VJc_raw.json b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/zDK1nQS1VJc_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..5d9eb30afe9e09ee6d4a99dcbda1c9c9737dc2ae
--- /dev/null
+++ b/PL9fwy3NUQKwa5gos6UzCoIOtGb6i-GbC_/zDK1nQS1VJc_raw.json
@@ -0,0 +1 @@
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"probability": 0.9912109375}, {"start": 274.08, "end": 274.26, "word": " في", "probability": 0.9287109375}, {"start": 274.26, "end": 274.32, "word": " ال", "probability": 0.93603515625}, {"start": 274.32, "end": 274.8, "word": " deflection", "probability": 0.968505859375}, {"start": 274.8, "end": 275.26, "word": " و", "probability": 0.81884765625}, {"start": 275.26, "end": 275.34, "word": " ال", "probability": 0.884765625}, {"start": 275.34, "end": 275.7, "word": " deflection", "probability": 0.96923828125}, {"start": 275.7, "end": 276.24, "word": " مرتبط", "probability": 0.81182861328125}, {"start": 276.24, "end": 276.68, "word": " بالتغير", "probability": 0.942626953125}, {"start": 276.68, "end": 277.16, "word": " فيهش", "probability": 0.4235432942708333}, {"start": 277.16, "end": 277.7, "word": " الدعوة", "probability": 0.6507568359375}], "temperature": 1.0}, {"id": 12, "seek": 30788, "start": 280.78, "end": 307.88, "text": "هكذا مرحبا برضه على ال dead weight tester هذا جهاز نستخدمه عشان نعمل calibration لأجزة قياس الضغط بيكون عندهين زيت وعندهين أوزان وفي عنده اللي هو الجهاز اللي مستخدم في قياس الضغط طبعا ال pressure بتاع الزيت بالساوية الوزن على مساحة المقطع وزن على مساحة المقطع", "tokens": [3224, 4117, 15730, 3714, 2288, 5016, 3555, 995, 4724, 43042, 3224, 15844, 2423, 3116, 3364, 36101, 23758, 10874, 3224, 31377, 8717, 14851, 9778, 40448, 3224, 6225, 8592, 7649, 8717, 25957, 1211, 38732, 5296, 10721, 7435, 11622, 3660, 12174, 25528, 3794, 6024, 114, 17082, 9566, 4724, 1829, 30544, 43242, 3224, 9957, 30767, 36081, 4032, 3615, 41260, 3224, 9957, 34051, 11622, 7649, 4032, 41185, 43242, 3224, 13672, 1829, 31439, 25724, 3224, 31377, 13672, 1829, 3714, 14851, 9778, 40448, 8978, 12174, 25528, 3794, 6024, 114, 17082, 9566, 23032, 3555, 3615, 995, 2423, 3321, 39894, 45761, 6024, 110, 36081, 20666, 3794, 995, 2407, 10632, 2423, 2407, 11622, 1863, 15844, 47524, 39319, 3660, 9673, 47432, 3615, 4032, 11622, 1863, 15844, 47524, 39319, 3660, 9673, 47432, 3615], "avg_logprob": 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294.66, "end": 295.02, "word": " عنده", "probability": 0.6177978515625}, {"start": 295.02, "end": 295.78, "word": " اللي", "probability": 0.898193359375}, {"start": 295.78, "end": 296.06, "word": " هو", "probability": 0.99169921875}, {"start": 296.06, "end": 297.2, "word": " الجهاز", "probability": 0.9646809895833334}, {"start": 297.2, "end": 297.32, "word": " اللي", "probability": 0.740478515625}, {"start": 297.32, "end": 297.72, "word": " مستخدم", "probability": 0.9215087890625}, {"start": 297.72, "end": 297.84, "word": " في", "probability": 0.96142578125}, {"start": 297.84, "end": 298.32, "word": " قياس", "probability": 0.8894856770833334}, {"start": 298.32, "end": 299.14, "word": " الضغط", "probability": 0.991455078125}, {"start": 299.14, "end": 299.94, "word": " طبعا", "probability": 0.97998046875}, {"start": 299.94, "end": 300.84, "word": " ال", "probability": 0.9716796875}, {"start": 300.84, "end": 301.2, "word": " pressure", "probability": 0.9951171875}, {"start": 301.2, "end": 301.6, "word": " بتاع", "probability": 0.896484375}, {"start": 301.6, "end": 302.14, "word": " الزيت", "probability": 0.8639322916666666}, {"start": 302.14, "end": 303.64, "word": " بالساوية", "probability": 0.649560546875}, {"start": 303.64, "end": 304.16, "word": " الوزن", "probability": 0.9696044921875}, {"start": 304.16, "end": 304.38, "word": " على", "probability": 0.837890625}, {"start": 304.38, "end": 304.9, "word": " مساحة", "probability": 0.9685872395833334}, {"start": 304.9, "end": 305.36, "word": " المقطع", "probability": 0.98486328125}, {"start": 305.36, "end": 305.84, "word": " وزن", "probability": 0.6539713541666666}, {"start": 305.84, "end": 305.98, "word": " على", "probability": 0.892578125}, {"start": 305.98, "end": 306.64, "word": " مساحة", "probability": 0.9905598958333334}, {"start": 306.64, "end": 307.88, "word": " المقطع", "probability": 0.9918619791666666}], "temperature": 1.0}, {"id": 13, "seek": 33479, "start": 308.71, "end": 334.79, "text": "فأنا بقارن بين القراع على الجهاز و بكون حاسس بإيش ال pressure فبعمل calibration لإيش للجهاز معناته ال input عندى أو ال output هو ال pressure as indicated by the device و ال input هو ال pressure الناتج عن ال weight أو الأوزان اللى أنا بحطها", "tokens": [5172, 10721, 8315, 4724, 4587, 9640, 1863, 49374, 25062, 23557, 3615, 15844, 25724, 3224, 31377, 4032, 4724, 30544, 11331, 32277, 3794, 4724, 28814, 1829, 8592, 2423, 3321, 6156, 3555, 25957, 1211, 38732, 5296, 28814, 1829, 8592, 24976, 7435, 3224, 31377, 20449, 8315, 47395, 2423, 4846, 43242, 7578, 34051, 2423, 5598, 31439, 2423, 3321, 382, 16176, 538, 264, 4302, 4032, 2423, 4846, 31439, 2423, 3321, 28239, 9307, 7435, 18871, 2423, 3364, 34051, 16247, 2407, 11622, 7649, 13672, 7578, 41850, 4724, 5016, 9566, 11296], "avg_logprob": -0.1420368983084897, "compression_ratio": 1.6857142857142857, "no_speech_prob": 0.0, "words": [{"start": 308.71, "end": 309.75, "word": "فأنا", "probability": 0.8272298177083334}, {"start": 309.75, "end": 310.15, "word": " 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calibration", "probability": 0.880859375}, {"start": 317.49, "end": 318.75, "word": " لإيش", "probability": 0.7821044921875}, {"start": 318.75, "end": 319.55, "word": " للجهاز", "probability": 0.82794189453125}, {"start": 319.55, "end": 320.41, "word": " معناته", "probability": 0.8074544270833334}, {"start": 320.41, "end": 320.53, "word": " ال", "probability": 0.95458984375}, {"start": 320.53, "end": 320.81, "word": " input", "probability": 0.98193359375}, {"start": 320.81, "end": 321.31, "word": " عندى", "probability": 0.76708984375}, {"start": 321.31, "end": 321.95, "word": " أو", "probability": 0.5263671875}, {"start": 321.95, "end": 322.07, "word": " ال", "probability": 0.96728515625}, {"start": 322.07, "end": 322.55, "word": " output", "probability": 0.98681640625}, {"start": 322.55, "end": 323.41, "word": " هو", "probability": 0.93994140625}, {"start": 323.41, "end": 323.65, "word": " ال", "probability": 0.9716796875}, {"start": 323.65, "end": 324.49, "word": " pressure", "probability": 0.98876953125}, {"start": 324.49, "end": 324.85, "word": " as", "probability": 0.96484375}, {"start": 324.85, "end": 325.41, "word": " indicated", "probability": 0.92822265625}, {"start": 325.41, "end": 325.89, "word": " by", "probability": 0.98583984375}, {"start": 325.89, "end": 326.85, "word": " the", "probability": 0.873046875}, {"start": 326.85, "end": 327.71, "word": " device", "probability": 0.97900390625}, {"start": 327.71, "end": 329.35, "word": " و", "probability": 0.80419921875}, {"start": 329.35, "end": 329.53, "word": " ال", "probability": 0.951171875}, {"start": 329.53, "end": 329.97, "word": " input", "probability": 0.9716796875}, {"start": 329.97, "end": 330.23, "word": " هو", "probability": 0.98388671875}, {"start": 330.23, "end": 330.39, "word": " ال", "probability": 0.94921875}, {"start": 330.39, "end": 330.85, "word": " pressure", "probability": 0.990234375}, {"start": 330.85, "end": 331.57, "word": " الناتج", "probability": 0.84326171875}, {"start": 331.57, "end": 331.91, "word": " عن", "probability": 0.98095703125}, {"start": 331.91, "end": 332.43, "word": " ال", "probability": 0.98876953125}, {"start": 332.43, "end": 332.77, "word": " weight", "probability": 0.970703125}, {"start": 332.77, "end": 333.37, "word": " أو", "probability": 0.56494140625}, {"start": 333.37, "end": 334.05, "word": " الأوزان", "probability": 0.881591796875}, {"start": 334.05, "end": 334.15, "word": " اللى", "probability": 0.6143798828125}, {"start": 334.15, "end": 334.25, "word": " أنا", "probability": 0.61328125}, {"start": 334.25, "end": 334.79, "word": " بحطها", "probability": 0.986328125}], "temperature": 1.0}, {"id": 14, "seek": 34988, "start": 339.08, "end": 349.88, "text": "من طول قياس الضغط حكينا اللي هي ال manometer ال manometer بيكون في عندي انبوبين في البداية بيكون ال fluid", "tokens": [27842, 23032, 12610, 12174, 25528, 3794, 6024, 114, 17082, 9566, 11331, 4117, 1829, 8315, 13672, 1829, 39896, 2423, 587, 13606, 2423, 587, 13606, 4724, 1829, 30544, 8978, 18871, 16254, 16472, 3555, 37746, 9957, 8978, 29739, 28259, 10632, 4724, 1829, 30544, 2423, 9113], "avg_logprob": -0.21911336585532787, "compression_ratio": 1.411764705882353, "no_speech_prob": 0.0, "words": [{"start": 339.08, "end": 339.4, "word": "من", "probability": 0.9658203125}, {"start": 339.4, "end": 339.62, "word": " طول", "probability": 0.7393798828125}, {"start": 339.62, "end": 340.04, "word": " قياس", "probability": 0.9230143229166666}, {"start": 340.04, "end": 340.4, "word": " الضغط", "probability": 0.9041748046875}, {"start": 340.4, "end": 340.72, "word": " حكينا", "probability": 0.7412109375}, {"start": 340.72, "end": 340.84, "word": " اللي", "probability": 0.79541015625}, {"start": 340.84, "end": 340.96, "word": " هي", "probability": 0.80712890625}, {"start": 340.96, "end": 341.7, "word": " ال", "probability": 0.375732421875}, {"start": 341.7, "end": 342.36, "word": " manometer", "probability": 0.677001953125}, {"start": 342.36, "end": 343.28, "word": " ال", 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"language_probability": 1.0, "duration": 966.3680625, "duration_after_vad": 879.806875000001}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-9ge495lcEc_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-9ge495lcEc_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..58e9a075588b4eb498bbc1c4c8d7b76353a7393d
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-9ge495lcEc_postprocess.srt
@@ -0,0 +1,2216 @@
+1
+00:00:21,350 --> 00:00:25,870
+بسم الله الرحمن الرحيم نستأنف اليوم في موضوع ال
+
+2
+00:00:25,870 --> 00:00:30,470
+alkanes و ال cycloalkanes زي ما بتعرفوا المرة
+
+3
+00:00:30,470 --> 00:00:37,030
+الماضية أعطينا فكرة عن ال alkanes من ناحية التسمية
+
+4
+00:00:37,030 --> 00:00:41,330
+و من ناحية بعض الخواص الفيزيائية و من ناحية
+
+5
+00:00:41,330 --> 00:00:51,110
+تركيبها بمعنى عدد ذرات ال carbon و ال hydrogenو
+
+6
+00:00:51,110 --> 00:00:57,310
+الصيغة العامة ربما بتذكروا حكينا للالكينز CNN H2N
+
+7
+00:00:57,310 --> 00:01:02,560
+Plus Twoالان من انواع ال hydrocarbons اللى بنقول
+
+8
+00:01:02,560 --> 00:01:07,080
+عنها مشبعة saturated ال cycle alkenes عشان ناخد
+
+9
+00:01:07,080 --> 00:01:12,600
+cycle alkenes او حتى بعد هيك alkenes بننطلق احنا
+
+10
+00:01:12,600 --> 00:01:17,220
+من ال alkenes يعني اتخيلوا هذا المركب اللى امامكم
+
+11
+00:01:17,220 --> 00:01:26,060
+هذا عبارة عن بروبين C3H8 واضح؟لو بدى انا اجعل هذا
+
+12
+00:01:26,060 --> 00:01:32,700
+المركب اشيل ذرتين هيدروجين و احط بدالهم رابطة يعني
+
+13
+00:01:32,700 --> 00:01:37,400
+هى ذرة هيدروجين و من جنبها تماما يعني عندك ذرتين
+
+14
+00:01:37,400 --> 00:01:41,240
+كربون متجاورات شيلت ذرة هيدروجين و حطيت رابطة
+
+15
+00:01:41,240 --> 00:01:48,270
+مكانهم بيصير عندى ال keenبصير عندى الكين اللى فيه
+
+16
+00:01:48,270 --> 00:01:52,210
+double bond لبروبيل الان لو سألت ال الكين ايش
+
+17
+00:01:52,210 --> 00:01:59,970
+الصيغة العامة له لاحظوا معاه C3H6
+
+18
+00:02:01,060 --> 00:02:09,040
+C3H6 معنا ذلك الصيغة العامة للالكينز CNNH2N واضح
+
+19
+00:02:09,040 --> 00:02:15,540
+نقص كم هيدروجينة تنتين الان لو جربنا نشيل كمان
+
+20
+00:02:15,540 --> 00:02:19,180
+هيدروجين تان من جنب بعض و نحط رابطة مكانهم يعني
+
+21
+00:02:19,180 --> 00:02:24,060
+هاي كمان هيدروجين شيلتها و كمان هيدروجين و حطيت
+
+22
+00:02:24,060 --> 00:02:32,960
+رابطة صار عندى رابطةثلاثية ال kind صار عندي ال
+
+23
+00:02:32,960 --> 00:02:39,660
+kind هذا ال ال kind الصيغة العامة إيه له CNH2N-2
+
+24
+00:02:39,660 --> 00:02:44,940
+يعني لما أقول C3H326
+
+25
+00:02:44,940 --> 00:02:50,830
+-2 أربعة شايفين الأربعةفهذه الصيغة العامة لل
+
+26
+00:02:50,830 --> 00:02:56,690
+الkins لل الkinds لل الkins الآن خلّينا نرجع مرة
+
+27
+00:02:56,690 --> 00:03:01,890
+تانية لل الkins ونشوف طيب إيش الصيغة العامة لل
+
+28
+00:03:01,890 --> 00:03:06,370
+cycloalkins اللي الآن بدهم يمروا علينا ال
+
+29
+00:03:06,370 --> 00:03:11,050
+cycloalkins يعني لو بدي أعمل حلقة و كل الروابط
+
+30
+00:03:11,050 --> 00:03:17,770
+تبعت هذه الحلقة روابط إيش أحديةعشان اعمل حلقة
+
+31
+00:03:17,770 --> 00:03:24,250
+المفروض ان اشيل ذرتين هيدروجين لكن بشيلهم مش من
+
+32
+00:03:24,250 --> 00:03:28,810
+جنب بعض في هذه الحالة مثلا بشيلهم من الأطراف هشيلت
+
+33
+00:03:28,810 --> 00:03:33,990
+ذرة هيدروجين من هنا و ذرة هيدروجين تانية من
+
+34
+00:03:33,990 --> 00:03:41,210
+الأطراف و حطيت مكانها رابطة صار
+
+35
+00:03:41,210 --> 00:03:47,060
+عند مركب حلقهcycloalkane لأنه إجا من تلت كربونات
+
+36
+00:03:47,060 --> 00:03:53,100
+بروبيل، شو صرت أسميه؟ Cyclopropane طيب، الآن طالما
+
+37
+00:03:53,100 --> 00:03:58,100
+أنا شيلت هيدروجين تان، والواقع أيضا بأيد هالكلام
+
+38
+00:03:58,100 --> 00:04:00,400
+C3H
+
+39
+00:04:01,190 --> 00:04:08,670
+Six إذا ما الصيغة العامة للـ Cycloalkynes CNH2N
+
+40
+00:04:08,670 --> 00:04:15,810
+CNH2N لاحظوا معناه إن ال الكينز و ال Cycloalkynes
+
+41
+00:04:15,810 --> 00:04:19,990
+بينشأوا عنفق الذرتين هيدروجين ولذلك الطرفين اللي
+
+42
+00:04:19,990 --> 00:04:26,110
+همنفس الصيغة العامة لكن لو فقدوا ذرات الهيدروجين
+
+43
+00:04:26,110 --> 00:04:31,050
+من جانب بعض اعملنا رابطة مكانهم صار عند ال الكين
+
+44
+00:04:31,050 --> 00:04:35,450
+لو فقدوا من اماكن بعيدة و اعملنا رابطة صار عند
+
+45
+00:04:35,450 --> 00:04:40,370
+Cycloalkyn و لذلك ال Cycloalkyn و ال الكين هما
+
+46
+00:04:40,370 --> 00:04:46,750
+يمتلون نفس الفورمولة CNH2N
+
+47
+00:04:46,750 --> 00:04:52,900
+هذه النقطة الأولى اللى بدى احكيها في الموضوعالان
+
+48
+00:04:52,900 --> 00:04:57,960
+لو اتطلعنا اكثر على الـ Cyclopropane بدنا معلومات
+
+49
+00:04:57,960 --> 00:05:03,040
+اكثر عنه، لاحظوا ان تلت ذرات الكربون تبعون الـ
+
+50
+00:05:03,040 --> 00:05:09,830
+Cyclopropane في مستوى واحد، واضح؟و أي تلت ذرات في
+
+51
+00:05:09,830 --> 00:05:13,470
+الدنيا بالمناسبة بيكونوا في مستوى واحد يعني مش
+
+52
+00:05:13,470 --> 00:05:17,130
+ممكن تلاتة إلا يكونوا في مستوى واحد واحد اتنين
+
+53
+00:05:17,130 --> 00:05:22,070
+حطوا التالتة هذا في مستوى واحد ولذلك لو سألنا عن
+
+54
+00:05:22,070 --> 00:05:27,370
+الـcyclopropane إيش الشكل تبعه بدنا نقول planner
+
+55
+00:05:27,370 --> 00:05:34,230
+planner يعني في مستوى واحد مش بتلت أبعاد يعني لو
+
+56
+00:05:34,230 --> 00:05:39,070
+كنا بنحكي عن XY هذا في ال XYواضحة الفكرة؟ هذه
+
+57
+00:05:39,070 --> 00:05:41,870
+النقطة الثانية اللى بدنا ننبهها بالنسبة للـ
+
+58
+00:05:41,870 --> 00:05:48,610
+Cyclopropane الان نقطة تالتة كتير مهمة جدا عندنا
+
+59
+00:05:48,610 --> 00:05:55,510
+دائما في أي مركب نعرف أنواع ذرات الهيدروجيلعشان
+
+60
+00:05:55,510 --> 00:05:59,570
+لما بنعمل التفاعلات النواتج تتمد كم نوع ذرات
+
+61
+00:05:59,570 --> 00:06:04,410
+هيدروجين عندك يعني ربما المركب الأصلي اللى قبل ما
+
+62
+00:06:04,410 --> 00:06:08,230
+يكون Cyclopropane اللى هو البروبين لما حكينا المرة
+
+63
+00:06:08,230 --> 00:06:18,590
+الماضية CH3 CH2 CH3 كم نوع من ذرات الهيدروجين فيه
+
+64
+00:06:18,590 --> 00:06:24,250
+نوعين هدولة الستة زي بعض و هدولة التنتين زي بعض و
+
+65
+00:06:24,250 --> 00:06:27,630
+عشان ايه بعد شوية لو بدي اعمل عليه تفاعلات اقول طب
+
+66
+00:06:27,630 --> 00:06:32,530
+نشيل هيدروجينة نحط مركانها كلور لو شيلت من هان
+
+67
+00:06:32,530 --> 00:06:37,610
+بطلع عنده مركب بسميه one chlorobrobil لو شيلت من
+
+68
+00:06:37,610 --> 00:06:43,220
+هانبطلع مركّب تاني بسميه 2-chloropropane فبناء على
+
+69
+00:06:43,220 --> 00:06:47,240
+عدد أنواع الهيدروجين انا بقدر اعرف ايش اللي بيصير
+
+70
+00:06:47,240 --> 00:06:51,340
+عندى بالتفاعل طيب يا تورا لو مسكت ال cyclopropane
+
+71
+00:06:51,340 --> 00:06:59,720
+و سألت هدولة 6 ذرات هيدروجين كام نوع؟نوع واحد
+
+72
+00:06:59,720 --> 00:07:04,400
+بمعنى لو انا امسكت ذرة كلور خلّينا نفترض هذه لمخ
+
+73
+00:07:04,400 --> 00:07:08,520
+اللون الأخضر بدي اشيل اي هيدروجين و احط مكانها
+
+74
+00:07:08,520 --> 00:07:14,180
+كلور مش هذا تفاعل ابدال بدلنا هيدروجين بكلور الان
+
+75
+00:07:14,180 --> 00:07:20,460
+لو شيلت هذه و حطيت كلور هيطلع عندى مركببس بيصير
+
+76
+00:07:20,460 --> 00:07:25,920
+اسمه اكلورو سايكلو بروبين طب لو كنت بده احك مكان
+
+77
+00:07:25,920 --> 00:07:33,120
+هادي نفس الاشي واضح مكان هادي مكان هادي ف ست ذرات
+
+78
+00:07:33,120 --> 00:07:38,520
+الهيدروجين في هذا المركب they are equivalent يعني
+
+79
+00:07:38,520 --> 00:07:43,560
+لو كنا بنسألكم the six hydrogens of cyclopropane
+
+80
+00:07:43,560 --> 00:07:50,880
+areequivalent متكافئات واضحة الفكرة وعشان هيك
+
+81
+00:07:50,880 --> 00:07:56,440
+بنقدر نتبع هالكلام جملة تانية monochlorination of
+
+82
+00:07:56,440 --> 00:07:59,600
+cyclopropane معناه monochlorination إن أنا أبدل
+
+83
+00:07:59,600 --> 00:08:05,680
+هيدروجين واحدة بكلور واحدة شو بسمي العملية؟ mono
+
+84
+00:08:05,680 --> 00:08:11,120
+يعني أحادي monochlorination
+
+85
+00:08:11,120 --> 00:08:18,080
+إيش يعني chlorination؟تفاعل مع الكلور تفاعل الـ
+
+86
+00:08:18,080 --> 00:08:21,340
+Cyclopropane مع الكلور إبدال بذرة واحدة
+
+87
+00:08:21,340 --> 00:08:27,820
+Monochlorination of Cyclopropane produces only one
+
+88
+00:08:27,820 --> 00:08:34,880
+product بيطلع فقط ناتج واحد، شو سميته أنا؟
+
+89
+00:08:34,880 --> 00:08:40,900
+Chlorocyclopropane واضح؟
+
+90
+00:08:41,270 --> 00:08:48,910
+الان اذا بنستمر بنفس هذه الفكرة وبنقول ان انسان
+
+91
+00:08:48,910 --> 00:08:54,850
+عمل هذا التفاعل وصار عنده chlorocyclopropane وفكر
+
+92
+00:08:54,850 --> 00:09:00,570
+انه بده يعمل تفاعل تاني على ال cyclopropane ابدل
+
+93
+00:09:00,570 --> 00:09:06,850
+كمان هيدروجين لازم يكون عارف كم نوع من الهيدروجين
+
+94
+00:09:06,850 --> 00:09:15,380
+عنده في هذا المركب الانلا أكيد لا الان احنا بحاجة
+
+95
+00:09:15,380 --> 00:09:24,980
+إلى عمق في التفكير و في النظر الأمر مش سهل اكثر
+
+96
+00:09:24,980 --> 00:09:31,580
+من نوع يعني هذا لما بضحط chlorine تانية كان مركب
+
+97
+00:09:31,580 --> 00:09:38,640
+بينتج عندى فيه واضح؟في الحقيقة هنكتشف انهم اللي
+
+98
+00:09:38,640 --> 00:09:45,540
+بينتجوا تلت مركبات معناه ذلك عندنا تلت أنواع من
+
+99
+00:09:45,540 --> 00:09:49,220
+الهيدروجيل بنعملهم بال model و بعدين بنكتبهم
+
+100
+00:09:49,220 --> 00:09:53,680
+معادلة حتى نأكد المعلومة الآن لو إجت طالبة منكم
+
+101
+00:09:53,680 --> 00:09:59,240
+قالت بدي أشيل هذه الهيدروجيل اللي على نفس الكاربون
+
+102
+00:09:59,240 --> 00:10:05,020
+اللي حامله كلور و أحط محالها كلورطلعت مركّب حامل
+
+103
+00:10:05,020 --> 00:10:08,840
+ذرتين كلور على نفس الكربون هذا
+
+104
+00:10:08,840 --> 00:10:13,180
+Dichlorocyclopropane لكن التسمية بتشترط اني لازم
+
+105
+00:10:13,180 --> 00:10:17,680
+احدد الان مواقعهم وين موجودة هذه عن امر واحد و هذه
+
+106
+00:10:17,680 --> 00:10:23,680
+ع واحد اذا هذا لو كنت بدى اسميه هسميه one one
+
+107
+00:10:23,680 --> 00:10:28,540
+مرتين لازم اقول one يعني ذرة على one والتانية على
+
+108
+00:10:28,540 --> 00:10:32,600
+one one one dichlorocyclopropane
+
+109
+00:10:33,600 --> 00:10:39,640
+هذا مُركّب إجى مكان ذرّة الهيدروجين اللي هنا الان
+
+110
+00:10:39,640 --> 00:10:47,020
+لو إجيت طلعت على هدول الذرات نسبتهم لهذه واحد تنين
+
+111
+00:10:47,020 --> 00:10:56,580
+او واحد تنين واضح؟ الان لو شيلت هذه حطيت مكانها
+
+112
+00:10:56,580 --> 00:11:04,460
+اكلور هيطلع عند مُركّب جديدDichlorocyclopropane
+
+113
+00:11:04,460 --> 00:11:09,300
+قدرتين لكلور على موقعين متجاورين عشانك بقول one
+
+114
+00:11:09,300 --> 00:11:13,520
+two dichlorocyclopropane
+
+115
+00:11:13,520 --> 00:11:19,240
+one two dichlorocyclopropane هاي مركب تاني الان
+
+116
+00:11:19,240 --> 00:11:25,060
+ممكن واحدة منكم تفكر تقول طب خلينا نشيل هذه الذرعة
+
+117
+00:11:25,060 --> 00:11:30,880
+مش من نفس الجهة اللي هنا من الجهة المعاكسة ونحط
+
+118
+00:11:34,790 --> 00:11:40,130
+one two dichlorocyclopropane الان السؤال هل يا ترى
+
+119
+00:11:40,130 --> 00:11:44,950
+المركب اللى فى ذرتين لكلور على جهة واحدة زى اللى
+
+120
+00:11:44,950 --> 00:11:49,070
+فى ذرتين لكلور متعاكسة ممكن البعض يقول طب احنا
+
+121
+00:11:49,070 --> 00:11:54,190
+بنلف حوالين الرابط لو جربنا اللفتذكروا أن الدوران
+
+122
+00:11:54,190 --> 00:12:00,050
+ممنوع حول الحلقة مافيش إمكانية إذا هدول مركبين طيب
+
+123
+00:12:00,050 --> 00:12:04,210
+هذا اسمه one two و اللي كان ع جهة واحدة برضه اسمه
+
+124
+00:12:04,210 --> 00:12:07,510
+one two dichlorocyclopropane لو بدي أميزهم أكثر
+
+125
+00:12:07,510 --> 00:12:11,890
+بقول اه في عندي one two اللي على جهة واحدة و one
+
+126
+00:12:11,890 --> 00:12:19,170
+two اللي على جهتين متعاكستين هنا بدأنا نتكلم في ال
+
+127
+00:12:19,170 --> 00:12:24,460
+stereo chemistryانه صحيح الذرات موجودين على موقع
+
+128
+00:12:24,460 --> 00:12:28,440
+واحد و اتنين يعني same bonding لكن هنا على واحد و
+
+129
+00:12:28,440 --> 00:12:32,480
+اتنين على جهة واحدة و على واحد و اتنين على جهتين
+
+130
+00:12:32,480 --> 00:12:37,660
+متعاكستين الاسم في الحالتين one two
+
+131
+00:12:37,660 --> 00:12:42,770
+dichlorocyclopropane لكن بدي اضيف عليه مرة معو مرة
+
+132
+00:12:42,770 --> 00:12:49,450
+ضد لو كنا بنكتب بالعربي فعلا بيستعملوا مع كلمتين
+
+133
+00:12:49,450 --> 00:12:55,110
+مع على جهة واحدة و ضد على جهتين متعاكستين الآن
+
+134
+00:12:55,110 --> 00:12:58,550
+بالإنقليزي بيروحوا بيحطوا prefix ال prefix يعني
+
+135
+00:12:58,550 --> 00:13:03,690
+اشي في أول الكلام بادئة توضح هذا الكلام بيروحوا
+
+136
+00:13:03,690 --> 00:13:08,910
+بيضيفوا cis بمعنى على جهة واحدة و trans بمعنى على
+
+137
+00:13:08,910 --> 00:13:16,000
+جهتينSex و Trans يعني على جهة واحدة وعلى جهتين
+
+138
+00:13:16,000 --> 00:13:24,840
+خلينا هذا الكلام إذا بتسمحوا نتخيله بمعادلة ليش
+
+139
+00:13:24,840 --> 00:13:29,660
+لأنه دائما إنتوا لو بدكوا تكتبوا هتكتبوا معادلات
+
+140
+00:13:29,660 --> 00:13:31,780
+بمعنى هاي في عند أنا
+
+141
+00:13:36,020 --> 00:13:41,100
+Cyclopropane هذا Cyclopropane كام هيدروجين فيه؟
+
+142
+00:13:41,100 --> 00:13:46,860
+ستة لو قلت بدي أعمل إيه له؟ إكلورينايشن CL2 في
+
+143
+00:13:46,860 --> 00:13:51,460
+البداية بدي أعمل مونوكلورينايشن أبدل ذرة واحدة شو
+
+144
+00:13:51,460 --> 00:13:57,400
+هينشاء عندى؟ إكلورو سايكلوبروبين على أي موقع ابنه
+
+145
+00:13:57,400 --> 00:14:03,840
+كتوبة ماعنداش مشكلة إكلورو سايكلوبروبين
+
+146
+00:14:03,840 --> 00:14:07,900
+هيك حاجة أسميهالان لو افترضت هذا ال
+
+147
+00:14:07,900 --> 00:14:14,440
+chlorocyclopropane بدي اعمله كمان chlorination
+
+148
+00:14:14,440 --> 00:14:20,000
+حيصير بالمجمل كم ذرة ال chlor أبدلت تنتين اه كمان
+
+149
+00:14:20,000 --> 00:14:25,720
+مرة chlorination حيصير عندي عدة احتمالات هذا
+
+150
+00:14:25,720 --> 00:14:29,140
+الاحتمال ان ذرة ال chlor تيجي على نفس الذرة اللي
+
+151
+00:14:29,140 --> 00:14:35,700
+حملة ال chlor الأولى ايش سمناهالأ اللي عملناه في
+
+152
+00:14:35,700 --> 00:14:42,520
+الأولى ال chlorine ال chlorine على نفس الذرة one
+
+153
+00:14:42,520 --> 00:14:45,880
+one one one one one one one one one one one one
+
+154
+00:14:45,880 --> 00:14:46,040
+one one one one one one one one one one one one
+
+155
+00:14:46,040 --> 00:14:46,060
+one one one one one one one one one one one one
+
+156
+00:14:46,060 --> 00:14:53,560
+one one one one one one one one one one one one
+
+157
+00:14:53,560 --> 00:14:53,820
+one one one one one one one one one one one one
+
+158
+00:14:53,820 --> 00:14:54,180
+one one one one one one one one one one one one
+
+159
+00:14:54,180 --> 00:14:54,200
+one one one one one one one one one one one one
+
+160
+00:14:54,200 --> 00:14:54,300
+one one one one one one one one one one one one
+
+161
+00:15:10,380 --> 00:15:18,060
+الان يا تورا لو كنا بدنا نحط ذرة الكلور على الموقع
+
+162
+00:15:18,060 --> 00:15:24,020
+اتنين خلينا نحط واحد و اتنين هنا بهذا الشكل ممكن
+
+163
+00:15:24,020 --> 00:15:30,380
+يكون عنده ذرتين كلور على جهة واحدة او ذرتين كلور
+
+164
+00:15:30,380 --> 00:15:33,920
+على جهتين متعاكسات
+
+165
+00:15:35,440 --> 00:15:40,600
+واضح؟ الان هاي واحد اتنين تلاتة واحد اتنين تلاتة
+
+166
+00:15:40,600 --> 00:15:45,240
+اذا كل مركب من هدوله ايش اسمه one two
+
+167
+00:15:45,240 --> 00:15:56,340
+dichlorocyclopropane one two dichlorocyclopropane
+
+168
+00:15:56,340 --> 00:15:58,800
+لكن
+
+169
+00:16:05,080 --> 00:16:10,380
+لكن لما بدي اميز هدول المركبات هنا الديكلورو جايين
+
+170
+00:16:10,380 --> 00:16:16,680
+على جهة واحدة فهذا الاسم الكامل له شو حيصير SES
+
+171
+00:16:16,680 --> 00:16:22,200
+شرطة one two dichlorocyclopropane يعني لما بدي
+
+172
+00:16:22,200 --> 00:16:27,540
+اجيب هذا في الامتحان سموه هتكتبوا SES شرطة one two
+
+173
+00:16:27,540 --> 00:16:33,430
+dichlorocyclopropane لو كنت بدي اسمي هذاالترانس
+
+174
+00:16:33,430 --> 00:16:37,190
+شرطة one two dichlorocyclopropane طبعا اكيد الذره
+
+175
+00:16:37,190 --> 00:16:44,010
+التاني اللي هي ذره ايش ال hydrogenواضح؟ لاحظوا ان
+
+176
+00:16:44,010 --> 00:16:49,010
+هدول المركبين .. هدول المركبين من ناحية ال bonding
+
+177
+00:16:49,010 --> 00:16:53,170
+.. من ناحية ال bonding they have the same bonding
+
+178
+00:16:53,170 --> 00:16:57,230
+من أي ناحية؟ ان ذرة كلورة على موقع واحد و التاني
+
+179
+00:16:57,230 --> 00:17:00,690
+على موقع التاني على واحد على اتنين .. على واحد على
+
+180
+00:17:00,690 --> 00:17:06,310
+اتنين the same bonding لكن اين الاختلاف؟ بالشكل ..
+
+181
+00:17:06,310 --> 00:17:10,930
+بالشكل الفراغي they have the same bondingbut
+
+182
+00:17:10,930 --> 00:17:15,470
+different arrangement in space شكلهم بالفراغ مختلف
+
+183
+00:17:15,470 --> 00:17:19,010
+ان هدول الذرتين ع جهة واحدة و هدول الذرتين ع جهات
+
+184
+00:17:19,010 --> 00:17:22,850
+متعاكسة بس اتنين ع واحد اتنين هذا النوع اللي احنا
+
+185
+00:17:22,850 --> 00:17:29,250
+ايش سمنا stereo isomersهذا النوع اللي سمناه stereo
+
+186
+00:17:29,250 --> 00:17:32,910
+isomers لما حكينا على ال isomerism قلنا ال stereo
+
+187
+00:17:32,910 --> 00:17:37,630
+isomers they have the same bonding يعني لما أجي
+
+188
+00:17:37,630 --> 00:17:41,670
+أقول الكلور وين؟ ع واحد و التانية ع اتنين في
+
+189
+00:17:41,670 --> 00:17:45,870
+التاني الكلور وين؟ ع واحد و التانية ع اتنين اذا
+
+190
+00:17:45,870 --> 00:17:50,310
+they have the same bonding طب وين اختلفوا؟بشكل
+
+191
+00:17:50,310 --> 00:17:54,390
+برفرات اه هدول ع واحد و اتنين ع جهة واحدة على واحد
+
+192
+00:17:54,390 --> 00:17:57,630
+و اتنين ع جهتين مختلفتين هذه بنسميها different
+
+193
+00:17:57,630 --> 00:18:03,710
+arrangement in space اذا العلاقة بين هذا ال cis و
+
+194
+00:18:03,710 --> 00:18:12,070
+ال trans they are stereo isomers لاحظوا
+
+195
+00:18:12,070 --> 00:18:16,930
+لو قلتلكوا ما العلاقة بين هذا المركب و هذا المركب
+
+196
+00:18:16,930 --> 00:18:22,870
+في ال isomersهنا they have different bonding و
+
+197
+00:18:22,870 --> 00:18:29,140
+different namesذرتين الكلور على واحد و واحد وعشان
+
+198
+00:18:29,140 --> 00:18:33,980
+هيك سميته one one dichlorocyclopropane هنا ذرتين
+
+199
+00:18:33,980 --> 00:18:36,600
+الكلور على واحد و اتنين هذا ال same bonding ولا
+
+200
+00:18:36,600 --> 00:18:40,020
+different bonding different bonding ال different
+
+201
+00:18:40,020 --> 00:18:45,220
+bonding أدى إلى different names أنا لما حددت مواقع
+
+202
+00:18:45,220 --> 00:18:49,620
+الكلور قلت one one هنا قلت one two إذا هذا المركب
+
+203
+00:18:49,620 --> 00:18:50,860
+و هذا المركب
+
+204
+00:18:53,140 --> 00:18:58,280
+صحيح مكونين من نفس الذرات لكن فيهم different
+
+205
+00:18:58,280 --> 00:19:01,860
+bonding و different names فالعلاقة بين ال 11
+
+206
+00:19:01,860 --> 00:19:06,420
+-dichlorocyclopropane و ال 12-dichlorocyclopropane
+
+207
+00:19:06,420 --> 00:19:11,480
+they are structural isomers و كذلك العلاقة بين هذا
+
+208
+00:19:11,480 --> 00:19:15,140
+و هذا لكن لو قلت العلاقة بين ال cis و ال trans
+
+209
+00:19:15,140 --> 00:19:19,120
+they are stereo isomers
+
+210
+00:19:21,810 --> 00:19:26,210
+Same bonding but different arrangement in space هي
+
+211
+00:19:26,210 --> 00:19:30,550
+تعريف الـ Stereoisomers نفس الإرتباط ولكن يختلف
+
+212
+00:19:30,550 --> 00:19:33,610
+فيه الشكل بالفراغ
+
+213
+00:19:37,910 --> 00:19:43,110
+لما قلنا لـ Stereoisomers قلنا نوعين نوع منهم
+
+214
+00:19:43,110 --> 00:19:48,150
+بنسميه Diastereomers هنتعلمه و نوع منهم بنسميه
+
+215
+00:19:48,150 --> 00:19:54,330
+Enantiomers الآن هدولة المركبين مثال لأحد أنواع
+
+216
+00:19:54,330 --> 00:19:59,290
+الـ Stereoisomers الاتنين مثال للـ Diastereomers
+
+217
+00:19:59,290 --> 00:20:02,050
+Diastereomers
+
+218
+00:20:03,170 --> 00:20:06,650
+يعني لما ناخد الاستيريو ايزو مارز ونقول يقسموا إلى
+
+219
+00:20:06,650 --> 00:20:12,590
+نوعين داياستيريو مارز وانانشو مارز الانانشو مارز
+
+220
+00:20:12,590 --> 00:20:17,370
+هندرسهم بأي فصل بالفصل الخامس الداياستيريو مارز
+
+221
+00:20:17,370 --> 00:20:22,520
+الآن بيمروا عليناطيب لو واحدة بده تيجي تقول طب إيش
+
+222
+00:20:22,520 --> 00:20:26,660
+يعني بالظبط diastereomers؟ إيش يعني بالظبط
+
+223
+00:20:26,660 --> 00:20:31,540
+diastereomers؟ بنقول ببساطة التعريف العام التعريف
+
+224
+00:20:31,540 --> 00:20:35,780
+العام ل diastereomers ال diastereomers they are
+
+225
+00:20:35,780 --> 00:20:41,360
+non mirror image stereoisomers يعني stereoisomers
+
+226
+00:20:41,360 --> 00:20:47,140
+ولكن مش صورة بعض في المرآة يعني لو تخيلت أنا أنه
+
+227
+00:20:47,140 --> 00:20:52,280
+بين واحد والتانيفي بينهم مرايا، هل الواحد منهم
+
+228
+00:20:52,280 --> 00:20:57,060
+صورة التالف في المرآة ولا لأ؟ يعني تخيلوا أن أنا
+
+229
+00:20:57,060 --> 00:21:03,800
+هنا حطيت مرآة، دائما و أبدا، أمام المرآة كل جسم له
+
+230
+00:21:03,800 --> 00:21:11,800
+صورة، والصورة في المرآة دائما معاكسة تماما لصورة
+
+231
+00:21:11,800 --> 00:21:16,740
+الجسميعني لو أنا وقفت زي المرأة .. أمام المرأة
+
+232
+00:21:16,740 --> 00:21:22,720
+بهذا الشكل كل النظر تبعي باتجاهكم الآن الصورة اللي
+
+233
+00:21:22,720 --> 00:21:28,960
+في المرأة بكل أبعادها يجب أن تكون معاكسة لصورة
+
+234
+00:21:28,960 --> 00:21:35,380
+الجسم دائما صورة المرأة معاكسة لصورة الجسم بكل
+
+235
+00:21:35,380 --> 00:21:41,560
+مكوناتهاالان لو اتيت يا تورا اتسألت هل هدولة من
+
+236
+00:21:41,560 --> 00:21:47,360
+الاساس صورة مرآه ولا مش صورة مرآه؟ لاحظوا يمكن هنا
+
+237
+00:21:47,360 --> 00:21:50,600
+تلاقي كلور متجه باتجاه هذه عكسها وهذه الهيدروجين
+
+238
+00:21:50,600 --> 00:21:55,600
+باتجاه هذه عكسها يعني لحد هذه النقطةمعاكسات لكن
+
+239
+00:21:55,600 --> 00:22:01,280
+هنا في chlorine إقبالها hydrogen تحت هنا في
+
+240
+00:22:01,280 --> 00:22:05,140
+chlorine إقبالها hydrogen هل هدولة بيصيروا صورة
+
+241
+00:22:05,140 --> 00:22:11,730
+مرآة إذا بطلوا صورة مرآةشرط صورة المرآة أن كل جزء
+
+242
+00:22:11,730 --> 00:22:16,930
+من الجزيئات هيكون بعكس الجثة الآخر هدولة فيهم
+
+243
+00:22:16,930 --> 00:22:19,910
+أشياء أساسا مش اقبال .. مش .. يعني هذه لا فوق،
+
+244
+00:22:19,910 --> 00:22:25,650
+كلور اقبالها هيدروجين، إذا هدولة الشكلين الcess
+
+245
+00:22:25,650 --> 00:22:30,730
+والترانس لما أنا بدي أحكي عنهم بقول they are non
+
+246
+00:22:30,730 --> 00:22:38,720
+mirrorimages، إيش يعني non-mirror images؟ مش صورة
+
+247
+00:22:38,720 --> 00:22:42,120
+بعض في المرأة، الأشياء اللي بتكون مش صورة بعض في
+
+248
+00:22:42,120 --> 00:22:47,960
+المرأة هي اللي تعرف ان اسمها diastereomers، وهذا
+
+249
+00:22:47,960 --> 00:22:53,760
+مثال عليها، ف ال cicatrans، isomers، they are
+
+250
+00:22:53,760 --> 00:22:55,720
+diastereomers
+
+251
+00:22:57,420 --> 00:23:00,580
+They are non-mirror image stereoisomers, so they
+
+252
+00:23:00,580 --> 00:23:06,520
+are diastereomers فكتصنيف من أنواع الاستيريو ايزو
+
+253
+00:23:06,520 --> 00:23:10,460
+مارز، they are diastereomers واضح؟ ولذلك لو
+
+254
+00:23:10,460 --> 00:23:14,080
+جيبنالكم سؤال صح و غلط Sistransisomers are
+
+255
+00:23:14,080 --> 00:23:21,360
+stereoisomers صحالان لو بدى اسأل اكثر عمقًا
+
+256
+00:23:21,360 --> 00:23:26,640
+Sistransisomers are diastereomers برضه صح ما هي
+
+257
+00:23:26,640 --> 00:23:31,080
+diastereomers نوع لكن لو قلنا Sistransisomers are
+
+258
+00:23:31,080 --> 00:23:36,000
+enantiomers لأ و هنتعلم ال enantiomers مستقبلا لو
+
+259
+00:23:36,000 --> 00:23:42,280
+قلنا Sistransisomers are structural isomersبرضه
+
+260
+00:23:42,280 --> 00:23:47,080
+غلط لأ مش structural .. ال structural بيختلفوا في
+
+261
+00:23:47,080 --> 00:23:49,580
+ال bonding هدولة they have the same bonding ع واحد
+
+262
+00:23:49,580 --> 00:23:56,120
+و اتنين ع واحد و اتنين واضح؟ لكن هذا المركب و هذا
+
+263
+00:23:56,120 --> 00:24:00,180
+they are structural isomers بس ال cis trans
+
+264
+00:24:00,180 --> 00:24:04,400
+isomers are stereoisomers أي نوع من ال
+
+265
+00:24:04,400 --> 00:24:10,050
+stereoisomers تحديدا ده يا stereomersتطلعوا معي
+
+266
+00:24:10,050 --> 00:24:14,650
+مرة تانية نرسم أحد هدولة أو نعمل model لأحد هدولة
+
+267
+00:24:14,650 --> 00:24:18,950
+المركبات اللي هم ال sis, trans, isomers واضح؟ هذا
+
+268
+00:24:18,950 --> 00:24:25,810
+أي مركب فيهم؟ ال sis والتاني لترانس متى توجد عندنا
+
+269
+00:24:25,810 --> 00:24:29,840
+ظاهرة ال sis و الترانس؟يعني في ناس بيقولوا وقتش
+
+270
+00:24:29,840 --> 00:24:33,660
+بدأ اقول ان في عندى cis و trans او لأ بنقول القاتل
+
+271
+00:24:33,660 --> 00:24:38,740
+ظاهرة ال cis و ال trans توجد في مكانين اما في
+
+272
+00:24:38,740 --> 00:24:45,400
+الحلقات او المكان التاني حول الروابط الزوجية صار
+
+273
+00:24:45,400 --> 00:24:50,320
+عندى نقطة كتير مهمة ناس بدهم يفهموا كل موضوع
+
+274
+00:24:53,400 --> 00:24:58,400
+كل موضوع ال sis و ال trans وين عمره يمر علي كلمة
+
+275
+00:24:58,400 --> 00:25:07,120
+sis و ال trans بنقول ال sis و ال trans هتشوفهم
+
+276
+00:25:07,120 --> 00:25:18,180
+بمكانين sis و ال trans اما في ال cycles او في ال
+
+277
+00:25:18,180 --> 00:25:23,160
+alkenesالالكينز اللي فيها روابط الزوجين هذا المكان
+
+278
+00:25:23,160 --> 00:25:29,940
+اللي بتشوفه فيه كلمة sis و trans في ال cycles مثل
+
+279
+00:25:29,940 --> 00:25:35,680
+المثال اللي احنا رسمنا زي ما قولنا هذا مثلا بهذا
+
+280
+00:25:35,680 --> 00:25:43,400
+الشكل sis و بهذا الشكل ال trans هاي بال cycle اللي
+
+281
+00:25:43,400 --> 00:25:48,970
+اتعرفنا عليه طيب حوالين ال double bondنفس الاشي لو
+
+282
+00:25:48,970 --> 00:25:52,810
+تخيل انه عندنا carbon double bond carbon حطينا
+
+283
+00:25:52,810 --> 00:25:59,310
+زرتين كلور بهذا الشكل وهنا carbon double bond
+
+284
+00:25:59,310 --> 00:26:07,670
+carbon حطينا زرتين كلور بهذا الشكل هذا
+
+285
+00:26:07,670 --> 00:26:12,890
+إثالين وهذا إثالين هذولة زرتين كلور على واحد
+
+286
+00:26:12,890 --> 00:26:20,030
+واتنين على جهة واحدةانا على واحد و اتنين و اتنين
+
+287
+00:26:20,030 --> 00:26:24,370
+على جهتين مختلفتين اذا الاتنين اسمه one two
+
+288
+00:26:24,370 --> 00:26:33,450
+dichloroethane طب كيف بدي اميزهم هدوله sis و هدوله
+
+289
+00:26:33,450 --> 00:26:38,010
+ال trans هدوله ال sis و هدوله ال trans فدائرة ال
+
+290
+00:26:38,010 --> 00:26:42,570
+sis و ال trans مكان وجودها في الدنيا مكانين ال
+
+291
+00:26:42,570 --> 00:26:44,790
+cycloalkenes و
+
+292
+00:26:46,730 --> 00:26:51,230
+الالكايز الالكينز عفوا ليش هذا الكلام بيتم لأنه
+
+293
+00:26:51,230 --> 00:26:56,390
+انا لو جربت في cycle الكل بدي ألوف هذا هيك أخلي
+
+294
+00:26:56,390 --> 00:27:00,470
+هدول يصيروا عكس بعض يعني ال 6 يصير ال trans لاحظوا
+
+295
+00:27:00,470 --> 00:27:05,210
+لأنه مربوط بالحلقة الدوران حول الحلقة ممنوع
+
+296
+00:27:05,210 --> 00:27:11,210
+الدوران حول الحلقة ممنوع الان طيب لو اتخيلتوا ان
+
+297
+00:27:11,210 --> 00:27:19,360
+انا في عندهالكين وهي مُركّب الـ CIS مش هذا
+
+298
+00:27:19,360 --> 00:27:25,900
+المُركّب اللي مرسوم CIS 1,2-dichloroethane الأن
+
+299
+00:27:25,900 --> 00:27:31,860
+لاحظوا لو بدى ألف و أخلي هدولة يصيروا عكس بعضبرضه
+
+300
+00:27:31,860 --> 00:27:35,500
+لأن الرابطة الزوجية رابطة قوية الدوران حولها
+
+301
+00:27:35,500 --> 00:27:43,500
+ممنوعة إذا العامل المشترك في هذا الموضوع ما بين
+
+302
+00:27:43,500 --> 00:27:51,800
+الحلقة و ما بين الألكين أنه في الحالتين الدوران
+
+303
+00:27:51,800 --> 00:27:57,040
+ممنوعة لذلك مقدرش أنا أعمل دوران أحول واحد للتاني
+
+304
+00:27:59,010 --> 00:28:05,410
+فكل واحد منهم بيصير مركّب منفصل بخواص منفصلة بمعنى
+
+305
+00:28:05,410 --> 00:28:10,150
+لو واحدة راحت تشتري مركّب كيميائي جالت بدّي one
+
+306
+00:28:10,150 --> 00:28:15,030
+two dichlorocyclopropane البياحة يقولها مافيش
+
+307
+00:28:15,030 --> 00:28:20,230
+عندى، في عندى؟two bottles مرتبانين واحد بكتب عليه
+
+308
+00:28:20,230 --> 00:28:26,170
+sis والتاني trans واضح الفكرة زي لما الواحدة
+
+309
+00:28:26,170 --> 00:28:31,510
+بيجيها مولود مافيش يكون عشوائي يا ولد يا بنت لو
+
+310
+00:28:31,510 --> 00:28:37,030
+قلنا مثلا one two dichloroethaneروحنا نشتريه،
+
+311
+00:28:37,030 --> 00:28:42,930
+مافيش، هتلاقوا عند البائع two bottles مرتبان CES 1
+
+312
+00:28:42,930 --> 00:28:49,270
+,2-dichloroethane بقواص معينة و بظائف معينة في
+
+313
+00:28:49,270 --> 00:28:54,590
+الحياة و هتلاقوا مركب تاني مختلف ال Trans و زي ما
+
+314
+00:28:54,590 --> 00:28:59,520
+قلنا العلاقة بين هدولة VRDiastereomers they are
+
+315
+00:28:59,520 --> 00:29:04,740
+non mirror images كلام سليم ولا لأ؟ مش صورة بعض في
+
+316
+00:29:04,740 --> 00:29:10,720
+المرأة في الخصائص
+
+317
+00:29:10,720 --> 00:29:16,420
+الفيزيائية أكيد و الكيميائية بيختلفوا في كل شيء
+
+318
+00:29:16,420 --> 00:29:21,910
+صاروا مركبينواضح مركبين they have different
+
+319
+00:29:21,910 --> 00:29:24,810
+physical properties، واحد من نقطة غليانه مثلا
+
+320
+00:29:24,810 --> 00:29:29,970
+سبعين، التانه نقطة غليانه تسعين، يختلفوا، واضح
+
+321
+00:29:29,970 --> 00:29:37,080
+الفكرة؟الان البعض احيانا بيقول طيب وكتش انا ممكن
+
+322
+00:29:37,080 --> 00:29:42,040
+يكون عندى ظاهرة ال sesual trance وانتبه لها اكثر و
+
+323
+00:29:42,040 --> 00:29:47,880
+وكتش لأ يعني لما أخدنا هذا المركب اللى حطينا فيه
+
+324
+00:29:47,880 --> 00:29:53,180
+chlorine و chlorine هنا طبعا اكيد هنا في hydrogen
+
+325
+00:29:53,180 --> 00:29:59,760
+ماجيبناش سيرة sesual tranceجيبناه إيش صيرت Sis &
+
+326
+00:29:59,760 --> 00:30:05,580
+Trans؟ وسمناها one-one-dichlorocyclo
+
+327
+00:30:05,580 --> 00:30:11,080
+-propane كذلك الحالة لو أنا انطلقت من الاثيليل
+
+328
+00:30:11,080 --> 00:30:16,540
+وحطيت ذرتين كلور على ال carbon الأولى يعني كان
+
+329
+00:30:16,540 --> 00:30:19,600
+عندى هذا المركب carbon double bond carbon ..
+
+330
+00:30:22,850 --> 00:30:26,870
+لو كان عندى هذا المركب carbon double bond carbon
+
+331
+00:30:26,870 --> 00:30:32,450
+وحطيت ذرتين كلور على الموقع الأول وقلنا إيش هذا
+
+332
+00:30:32,450 --> 00:30:39,880
+بدنا نسميهone one dichloroethane one one
+
+333
+00:30:39,880 --> 00:30:44,680
+dichloroethane مظبوط ولا لأ الان جيبنا هانة صيرت
+
+334
+00:30:44,680 --> 00:30:50,740
+cis و trans هان اه هان اه طيب بيصير سؤال وكتش
+
+335
+00:30:50,740 --> 00:30:54,360
+بيكون عندى ظاهرة ال cis و ال trans كلها موجودة
+
+336
+00:30:54,360 --> 00:31:00,220
+وكتش لأ الجواب بسيطبطلّع على الطرفين اللي بيحملوا
+
+337
+00:31:00,220 --> 00:31:03,920
+الذرات اللي هم الطرفين ال double bond أو الطرفين
+
+338
+00:31:03,920 --> 00:31:08,760
+اللي هنا إذا كانت كل ذرة تحمل مجموعتين مختلفتين
+
+339
+00:31:08,760 --> 00:31:11,760
+بيكون عند السيس و ترانس يعني هاي ال double bond
+
+340
+00:31:11,760 --> 00:31:19,200
+هادي غير هادي إذا هدوله مختلفتان ولا لأ هادي غير
+
+341
+00:31:19,200 --> 00:31:24,910
+هادي هدول مختلفتان و هدول مختلفتانإذا في عندي أكيد
+
+342
+00:31:24,910 --> 00:31:28,970
+من هذا المركب sis و trans هذا ال sis كيف بدي أجيب
+
+343
+00:31:28,970 --> 00:31:36,230
+لل trans؟ بال rotation؟ خليني أقول لو جيبنا لكوا
+
+344
+00:31:36,230 --> 00:31:42,070
+سؤال كيف نحول مركب ال sis إلى ال trans؟ أو نقول
+
+345
+00:31:42,070 --> 00:31:46,070
+sis compounds can be converted to trans by
+
+346
+00:31:46,070 --> 00:31:50,810
+rotation هاي الدوران جادر يلوف؟ لأ طب لو بدي أخلي
+
+347
+00:31:50,810 --> 00:31:58,660
+هذا ال sis transbond breaking bond formation اذا
+
+348
+00:31:58,660 --> 00:32:03,740
+انا كيف بحول السسلة ل Trans بال bond breaking و
+
+349
+00:32:03,740 --> 00:32:07,220
+bond formation بكسر الروابط و بحطها من اول و جديد
+
+350
+00:32:07,220 --> 00:32:11,150
+بس الدوران لا يؤدي الى هذا الكلامهنا صرت ما أعطيكم
+
+351
+00:32:11,150 --> 00:32:15,190
+كمان معلومتين إضافيتين عن ظاهرة الـ sexual trance
+
+352
+00:32:15,190 --> 00:32:20,110
+عشان توجد كظاهرة لابد كل carbon من أطراف الـ
+
+353
+00:32:20,110 --> 00:32:26,170
+double bond تحمل مجموعتين مختلفتينواضح؟ و لو بدى
+
+354
+00:32:26,170 --> 00:32:32,790
+احول ال 6 والترانس لازم اعمل
+
+355
+00:32:32,790 --> 00:32:36,870
+bond breaking و bond formation هذا الكلام بينطبق
+
+356
+00:32:36,870 --> 00:32:40,550
+على ال alkenes اللي فيهم ظاهرة ال 6 والترانس و
+
+357
+00:32:40,550 --> 00:32:46,810
+بينطبق أيضا على ال cycloalkenes كل هذه مفاهيم
+
+358
+00:32:46,810 --> 00:32:54,970
+أساسية و مهمة جدا في فعلنا لهذه الظاهرةالـ
+
+359
+00:32:54,970 --> 00:32:58,130
+Stereoisomers أو الـ Diastereomers اللي هي ظاهرة
+
+360
+00:32:58,130 --> 00:33:02,910
+الـ cis والترانس مكان وجودها الـ Cycloalkynes و
+
+361
+00:33:02,910 --> 00:33:09,230
+الـ Alkenes شرط وجودها ان كل طرف من الأطراف تبعت
+
+362
+00:33:09,230 --> 00:33:14,670
+ال carbons المكونة للـ double bond بتحمل مجموعتين
+
+363
+00:33:14,670 --> 00:33:17,890
+مختلفتين عشان ايك لو حد انا بدي احكي عن ال cis
+
+364
+00:33:17,890 --> 00:33:22,420
+والترانس هذه ال carbon شو بتحمل؟نفس المجموعات، هذا
+
+365
+00:33:22,420 --> 00:33:26,000
+ال carbo شو بتحمل؟ هذا شو بتحمل؟ أنا مافيش عنده ال
+
+366
+00:33:26,000 --> 00:33:31,060
+cis و ال trans، خلاص هو مركّب واحد، واضح؟ شرط فكرة
+
+367
+00:33:31,060 --> 00:33:37,870
+ال cis و ال trans أنه يكون عندهع كل طرف من أطراف
+
+368
+00:33:37,870 --> 00:33:41,250
+ال carbon سواء في الحلقة أو في ال double bond
+
+369
+00:33:41,250 --> 00:33:45,510
+مجموعات مختلفة ولذلك لو سألنا مثلا يا ترى هذا
+
+370
+00:33:45,510 --> 00:33:49,210
+المركب ال carbon double bond carbon وحطين هنا CL و
+
+371
+00:33:49,210 --> 00:33:54,690
+هنا CL و هنا H و هنا CL هل هذا في منه cis و trans؟
+
+372
+00:33:54,690 --> 00:34:02,790
+لأ هذا فقط مركب واحد لأن هنا HCL مختلفة لكن نفس
+
+373
+00:34:02,790 --> 00:34:12,160
+الشيءو شرط ال sis و ال trans مختلفة مختلفة غير هيك
+
+374
+00:34:12,160 --> 00:34:18,320
+ما بنتكلمش عن sis و trans سواء كنا بنحكي في ال ال
+
+375
+00:34:18,320 --> 00:34:25,600
+keys أو كنا بنحكي في الحلقات ال cyclo ال keys
+
+376
+00:34:30,680 --> 00:34:36,320
+أتعمقنا كثير في الـ Cyclopropane لكن أخدنا معلومات
+
+377
+00:34:36,320 --> 00:34:42,820
+كثير مهمة بخصوص ظاهرة بتتكرر معنا سواء الآن أو في
+
+378
+00:34:42,820 --> 00:34:48,060
+المستقبل لما ندرس ال الكينز الآن لو إجيت لمركب
+
+379
+00:34:48,060 --> 00:34:50,380
+الـcyclobutane
+
+380
+00:34:53,020 --> 00:34:57,300
+كم هيدروجين فيه؟ أربع كربونات كل كربون تو
+
+381
+00:34:57,300 --> 00:35:03,960
+هيدروجين؟ تمانية التمانية they are equivalent يعني
+
+382
+00:35:03,960 --> 00:35:09,020
+لو كنت أعمل عليه monochlorination بطلع بس مركب
+
+383
+00:35:09,020 --> 00:35:14,340
+واحد لكن لو قلنا نبدأ بالcyclobutane ونعمل
+
+384
+00:35:14,340 --> 00:35:20,260
+dichlorination هيطلع عندنا أكيد عدد أكبر من
+
+385
+00:35:20,260 --> 00:35:24,940
+المركباتواضح؟ يعني انتوا تخيلوا مش كل شي بدنا
+
+386
+00:35:24,940 --> 00:35:28,500
+نفصله بدنا نسيب شي انتوا تجربوه في البيت يعني هي
+
+387
+00:35:28,500 --> 00:35:33,360
+عندى ذرة الكلور الأولى و هنا فيه H لو بدى أحط كلور
+
+388
+00:35:33,360 --> 00:35:41,880
+تانية ممكن أحطها على الموقع الأول اعمل one one
+
+389
+00:35:41,880 --> 00:35:46,200
+dichlorocyclopropane صحيه ولا لأ؟ ممكن أحطها على
+
+390
+00:35:46,200 --> 00:35:53,330
+الموقع التانيأو Trans ممكن احطه على الموقع التالت
+
+391
+00:35:53,330 --> 00:35:59,030
+ايضا SIS او Trans بمعنى في الحلقة مش ضروري مش
+
+392
+00:35:59,030 --> 00:36:02,830
+ضروري ان ال SIS و ال Trans يكونوا جانب بعض يعني
+
+393
+00:36:02,830 --> 00:36:09,910
+هاي تخيلوا هذا Cyclobutane تجاوزا هاي ذرتين لكلور
+
+394
+00:36:09,910 --> 00:36:15,960
+خلينا نتخيلهم باللون الأحمر هذا المركب اي مركبone
+
+395
+00:36:15,960 --> 00:36:22,040
+one-dichlorocyclobutane، الآن هذا المركّب one two
+
+396
+00:36:22,040 --> 00:36:30,660
+-cis، هذا one two-trans، هذا one three-cis، هذا
+
+397
+00:36:30,660 --> 00:36:36,200
+one three-transواضح؟ يعني مش ضروري ان ال sis و ال
+
+398
+00:36:36,200 --> 00:36:39,360
+trans في الحلقة انهم يكونوا جانب بعض ممكن يكونوا
+
+399
+00:36:39,360 --> 00:36:42,480
+على واحد اتنين او على واحد تلات في الحلقات الأكبر
+
+400
+00:36:42,480 --> 00:36:47,980
+ممكن يكونوا أبعد كمان واضح؟ بتظهر نقطة الحقيقة في
+
+401
+00:36:47,980 --> 00:36:54,020
+موضوع ال cyclobutane ان هل يا ترى ال cyclobutane
+
+402
+00:36:54,020 --> 00:37:00,440
+بلانربهذا الشكل؟ الجواب لو كنا بنطلع على الزوايا
+
+403
+00:37:00,440 --> 00:37:04,940
+تبعته بشكل دقيق هو مش planner هو شوية بيقول عنه
+
+404
+00:37:04,940 --> 00:37:09,500
+puckered يعني مثني شوية لجوا الان بيشبه ايش بهذا
+
+405
+00:37:09,500 --> 00:37:16,000
+الشكل الفراشة ال butterflyواضح؟ فالـ cyclobutane
+
+406
+00:37:16,000 --> 00:37:21,580
+is not a planar molecule مش موجود بهذا الشكل في
+
+407
+00:37:21,580 --> 00:37:27,640
+مستوى واحد لأ من ثاني شوية للداخل عامل زي الفراشة
+
+408
+00:37:27,640 --> 00:37:34,760
+بتعرفوا أنتوا كيف عادة بترسموا الفراشة؟ فأنا لو
+
+409
+00:37:34,760 --> 00:37:39,140
+بدأ أرسم ال cyclobutane بهذا الشكل بارسمه واحد
+
+410
+00:37:39,140 --> 00:37:41,840
+اتنين تلاتة أربع هذه الأربع كربونات
+
+411
+00:37:44,220 --> 00:37:51,580
+cyclobutane is not a planar molecule الان تقريبا
+
+412
+00:37:51,580 --> 00:37:58,240
+المعلومات بتصير تتكرر هنا قولنا زي الاش زي ال
+
+413
+00:37:58,240 --> 00:38:03,900
+butter fly اللي هي الفراشة طب لو بدى احكي عن
+
+414
+00:38:03,900 --> 00:38:08,000
+الcyclobutane معلومات ال cis و ال trans و ال
+
+415
+00:38:08,000 --> 00:38:13,160
+substitution نفس الشيءممكن تعملوا على اكثر من موقع
+
+416
+00:38:13,160 --> 00:38:19,400
+لكن لو كنت بده احط اول كلور العشرة هيدروجين هم
+
+417
+00:38:19,400 --> 00:38:24,800
+اكويفلانت عشان ايه لما بده اعمل monochlorination
+
+418
+00:38:24,800 --> 00:38:28,960
+يعني بس one كلور بده يطلع عندى مركب بعدين لما بده
+
+419
+00:38:28,960 --> 00:38:32,740
+اعمل dichlorination بطلع عندى اكثر من مركب
+
+420
+00:38:32,740 --> 00:38:36,900
+بإمكانكوا تحسبوهم و تجمعوهم طب يا تورا لو حكيت عن
+
+421
+00:38:36,900 --> 00:38:42,220
+الشكل تبعه هل هو planner؟الجواب لأ مش planner طب
+
+422
+00:38:42,220 --> 00:38:45,920
+هى زى إيش بيعمل الآن تخيلوا هى الحلقة الخماسية
+
+423
+00:38:45,920 --> 00:38:50,420
+شايفينها هى دى اللى أمامكوا حلقة خماسية ولا لأ؟
+
+424
+00:38:50,420 --> 00:38:57,600
+واحد تانين تلاتة أربعة خمسة هيك بتكون planner لكن
+
+425
+00:38:57,600 --> 00:39:03,100
+هى عاملة بهذا الشكل الآن هذا الشكل لو كنا نعطيه
+
+426
+00:39:03,100 --> 00:39:09,040
+اسمبنقول عنه non planner أكيد لكن إله اسم أمركوا
+
+427
+00:39:09,040 --> 00:39:17,720
+شفتوا ضرف مغلف رسالة مفتوح it is like an open
+
+428
+00:39:17,720 --> 00:39:23,380
+envelope فهذا الشكل لو قلنا لكوا عنه planner لأ
+
+429
+00:39:23,380 --> 00:39:29,640
+هتقولوا it is like an open envelope اللي هو ضرف
+
+430
+00:39:29,640 --> 00:39:37,370
+رسالة مفتوح لو كنتوا بتكونوا ترسموهبشكل فراغي open
+
+431
+00:39:37,370 --> 00:39:41,350
+envelope مش envelope ال .. الظرف تبع الرسالة و
+
+432
+00:39:41,350 --> 00:39:45,050
+الموضوع it is like an open envelope لو بدي ارسمه
+
+433
+00:39:45,050 --> 00:39:49,990
+بهذا الشكل بارسمه فال Cyclopropane is a planar
+
+434
+00:39:49,990 --> 00:39:56,970
+Cyclobutane لأ Cyclopentane لأ الان لو انتقلنا بعد
+
+435
+00:39:56,970 --> 00:40:00,980
+هيك لل Cyclohexaneلاحظوا ال Cyclohexane الكلام
+
+436
+00:40:00,980 --> 00:40:04,100
+اللي موجود عليه في الدنيا كتير جدا احنا بنعطيه
+
+437
+00:40:04,100 --> 00:40:09,880
+مختصر للمختصر عليه ليش؟ لأن عليه كلام كتير لو كان
+
+438
+00:40:09,880 --> 00:40:15,340
+بهذا الشكل بيكون planner هي حلقة سدسية شايفينها
+
+439
+00:40:15,340 --> 00:40:19,780
+الواقع ان ال Cyclohexane مش زي هيك لما نتعلم في
+
+440
+00:40:19,780 --> 00:40:25,100
+chapter 4 عن البنزين البنزين زي هيك plannerالبنزين
+
+441
+00:40:25,100 --> 00:40:33,820
+C6H6 بلانر لكن الـCyclohexane ليس مليكيوم بلانر مش
+
+442
+00:40:33,820 --> 00:40:38,520
+بلانر طب ها كيف بينوجد؟ ممكن ينوجد على أكثر من
+
+443
+00:40:38,520 --> 00:40:42,860
+هيئة هيئة بيقول عنها confirmation confirmation
+
+444
+00:40:42,860 --> 00:40:47,820
+هيئة بمعنى ممكن نمسكه بهذا الشكل لاحظوا نفس الحلقة
+
+445
+00:40:47,820 --> 00:40:52,200
+شايفين كيف أنا مسكها؟الان هذا الشكل اللي انا ماسكه
+
+446
+00:40:52,200 --> 00:40:59,000
+يشبه ماذا؟ القارب او الزورق بسمي انا هيئة القارب
+
+447
+00:40:59,000 --> 00:41:04,740
+boat confirmation boat confirmation موجود عندكم
+
+448
+00:41:04,740 --> 00:41:13,520
+ربما بهذا المكان شايفينه؟
+
+449
+00:41:14,650 --> 00:41:19,050
+بهذا الشكل بيرسم بسهولة boat conformation يمكن أن
+
+450
+00:41:19,050 --> 00:41:26,830
+يكون على هيئة القارب بهذا الشكل و يمكن أن يكون على
+
+451
+00:41:26,830 --> 00:41:34,270
+هيئة الكرسي لو تخيلته زي هيك هي كأنه هذا كرسي هي
+
+452
+00:41:34,270 --> 00:41:37,910
+الرجلين وهي القاعدة اللي الناس بيجلس عليها وهي
+
+453
+00:41:37,910 --> 00:41:42,100
+الظهرطبعا هذا ال chair confirmation و ال boat
+
+454
+00:41:42,100 --> 00:41:46,020
+confirmation بيجلبه يعني هذا الشكل زي ما بتكون
+
+455
+00:41:46,020 --> 00:41:51,040
+تماما معاكم الشمسية ال umbrella في يوم عاصف كيف
+
+456
+00:41:51,040 --> 00:41:56,960
+بتكون؟ بتجلب للأمام و للخلف؟ هاد العملية بسميها
+
+457
+00:41:56,960 --> 00:42:03,200
+عشان flipping الشكل لما بيصير يجلب بهذا الشكل لفوق
+
+458
+00:42:03,200 --> 00:42:06,940
+لتحت زي الشمسية ما بتعمل بسمي العملية عشان
+
+459
+00:42:06,940 --> 00:42:07,540
+flipping
+
+460
+00:42:10,670 --> 00:42:17,390
+flipping الآن ممكن الـcyclohexane يكون بلحظة boat
+
+461
+00:42:17,390 --> 00:42:22,970
+هذه تجلب لتحت صار chair لحظة هذا ال chair هيظهر
+
+462
+00:42:22,970 --> 00:42:26,790
+للخلف و الأرجل للأمام ممكن تجلب هذه الأرجل تصير
+
+463
+00:42:26,790 --> 00:42:31,830
+بهذا الشكل و بهذا الشكل هو في حالة تقلب دائم يعني
+
+464
+00:42:31,830 --> 00:42:37,390
+الذرات في حالة تقلب دائما تماما مثل مثل إيش شمسية
+
+465
+00:42:37,390 --> 00:42:41,930
+في مهب الريحمثل مثل ال umbrella أو الشمسية في ماب
+
+466
+00:42:41,930 --> 00:42:47,450
+بالريح إذا هو يمكن أن يوجد على هيئة القارب ويمكن
+
+467
+00:42:47,450 --> 00:42:54,680
+أن يوجد على هيئةالكرسي لـ Chair Conformation أو
+
+468
+00:42:54,680 --> 00:43:00,120
+Boat Conformation واضح؟ زي ما حكيت، كثير فيه
+
+469
+00:43:00,120 --> 00:43:04,080
+تفاصيل للهيدروجينات و التركيبة لكن احنا بنتجاوز
+
+470
+00:43:04,080 --> 00:43:08,780
+هذا الكلام، بنقف ان الـCyclohexane ممكن يكون على
+
+471
+00:43:08,780 --> 00:43:12,500
+شكل الـChair Conformation وبيعمل flipping، بيقلب
+
+472
+00:43:13,380 --> 00:43:19,880
+مرة تانية انا اكد عادى الظاهر هيه بهذا الشكل بيكون
+
+473
+00:43:19,880 --> 00:43:23,500
+share و بيصير boat و بيرجع ت share و ت share بهذا
+
+474
+00:43:23,500 --> 00:43:27,040
+الشكل و ت share بهذا الشكل هو في حالة تقلب ايش
+
+475
+00:43:27,040 --> 00:43:32,860
+دائم الان اي الأشكال اثبت معنى اثبت هنا انه بيقضي
+
+476
+00:43:32,860 --> 00:43:37,380
+في وقت كتير ال share ولا ال boat ال share بنقول
+
+477
+00:43:37,380 --> 00:43:43,580
+عنه is more stable than the boatmore stable معناه
+
+478
+00:43:43,580 --> 00:43:48,360
+more stable أنه أنا لو بتطلع عليه و هو بيجلب هو
+
+479
+00:43:48,360 --> 00:43:53,440
+يتقلب بين هذه الأشكال لكن يبقى لفترة أطول على هيئة
+
+480
+00:43:53,440 --> 00:43:58,580
+إيش الكرسي يبقى لفترة أطول على هيئة الكرسي الآن
+
+481
+00:43:58,580 --> 00:44:04,040
+عملية أنهليش لفترة أطول على هيئة الكرسي؟ ليش هذا
+
+482
+00:44:04,040 --> 00:44:08,140
+أثبت؟ ما إلى ذلك؟ هذا الكلام لطلبة مختصين في
+
+483
+00:44:08,140 --> 00:44:12,600
+الكيميا فيه تفصيل كتير، يعني اللي الآن بنحكيه بخمس
+
+484
+00:44:12,600 --> 00:44:17,480
+دقائق، بنعمله فصل كامل لطالب الكيميا يتعمق فيه
+
+485
+00:44:17,480 --> 00:44:20,140
+بالcyclohexane، لكن احنا الآن اللي بنايعه
+
+486
+00:44:20,140 --> 00:44:25,480
+الcyclohexaneكلام بسيط ان هو non planar molecule
+
+487
+00:44:25,480 --> 00:44:30,700
+يوجد فيه اكتر من conformation هيئة منها ال boat
+
+488
+00:44:30,700 --> 00:44:35,420
+conformation و ال chair conformation واضح ال boat
+
+489
+00:44:35,420 --> 00:44:39,120
+conformation و ال chair conformation اكتر من هيك
+
+490
+00:44:39,120 --> 00:44:45,770
+مابدناش نتكلم عن هذا الموضوعطبعا الكلام اللي هو
+
+491
+00:44:45,770 --> 00:44:50,290
+حكيناه عن الـcis و الـtrans في الحلقات الخماسية
+
+492
+00:44:50,290 --> 00:44:54,790
+والسوداسية والسبعية والربعية والثلاثية كله موجود
+
+493
+00:44:54,790 --> 00:45:00,910
+واضح؟ كله موجود أخر شغلة بدنا نتكلمها اليوم إن شاء
+
+494
+00:45:00,910 --> 00:45:09,660
+الله تفاعلات الالكانز تفاعلات الالكانزقليلة جدا،
+
+495
+00:45:09,660 --> 00:45:12,880
+عشانيك احنا بنقول الالكينز they are generally
+
+496
+00:45:12,880 --> 00:45:17,220
+inert، ايش يعني inert؟ يعني قليلة التفاعلات،
+
+497
+00:45:17,220 --> 00:45:21,540
+عشانيك كل اشي inert يستعمل ك solvent، يعني يستعمل
+
+498
+00:45:21,540 --> 00:45:25,680
+كمثيب عضوي، لأن الأشياء بتكون في قلبه و بتفعلش
+
+499
+00:45:25,680 --> 00:45:32,220
+معها، في تفاعل مشهور جدا للالكينز، ان الالكينز لو
+
+500
+00:45:32,220 --> 00:45:36,840
+حرقناهم في وجود الأكسجين، بيعطونا ثانو أكسيد كربون
+
+501
+00:45:36,840 --> 00:45:42,940
+وماءوهذا التفاعل هو تفاعل حرق الغاز المنزلي لما
+
+502
+00:45:42,940 --> 00:45:47,660
+احنا بنشعل الغاز هو تفاعل حرق على سبيل المثال
+
+503
+00:45:47,660 --> 00:45:53,220
+الوقود البنزين والديزل في السيارات كله الكان
+
+504
+00:45:53,220 --> 00:45:58,180
+بنحرقه في وجود ال oxygen بنسمي العملية combustion
+
+505
+00:45:58,180 --> 00:46:03,200
+إيش يعني combustion burning in the presence of
+
+506
+00:46:03,200 --> 00:46:09,540
+oxygen burning يعني burningin the presence of
+
+507
+00:46:09,540 --> 00:46:17,980
+oxygen ايش بيعطيني؟ ثاني أكسيد كربون وماء بدون ما
+
+508
+00:46:17,980 --> 00:46:21,480
+ندخل بتفاصيل الأرقام كيف توزن المعادلة مش الموضوع
+
+509
+00:46:21,480 --> 00:46:26,400
+احنا بهمنا الآن النتيجة ان الالكينز بصير التفاعل
+
+510
+00:46:26,400 --> 00:46:32,700
+مع الأكسجين تعطيتانو أكسيد كربون و ماء زائد و ربما
+
+511
+00:46:32,700 --> 00:46:37,880
+أهم من الشغلتين بالنسبة لنا ال heat الحرارة عشان
+
+512
+00:46:37,880 --> 00:46:41,380
+هيك حرق الغاز و حرق البنزين اللي بيعطيني حرارة
+
+513
+00:46:41,380 --> 00:46:45,700
+بشغل عليها موقد الغاز بمشي عليها السيارة كل هذه
+
+514
+00:46:45,700 --> 00:46:50,130
+الأشياءالشغل التاني أو التفاعل التاني ال
+
+515
+00:46:50,130 --> 00:46:54,270
+halogenation هو التفاعل مع ال halogens الكلور و
+
+516
+00:46:54,270 --> 00:46:58,690
+البرومي بشكل أساسي عادة يتم هذا التفاعل في وجود
+
+517
+00:46:58,690 --> 00:47:01,210
+الحرارة أو الضوء
+
+518
+00:47:17,340 --> 00:47:22,460
+كم عدد النواتج اللي بتطلع؟ يعتمد على أنواع
+
+519
+00:47:22,460 --> 00:47:27,240
+الهيدروجين يعني لو كان المركب اللي عندكم هو
+
+520
+00:47:27,240 --> 00:47:32,340
+البروبين زي ما احنا حكينا وين
+
+521
+00:47:32,340 --> 00:47:38,040
+هيحط ال chlorine؟ يا ع موقع واحد و ال chlorine و
+
+522
+00:47:38,040 --> 00:47:40,400
+البروبين يا ع موقع اتنين اتنين اتنين اتنين اتنين
+
+523
+00:47:40,400 --> 00:47:40,820
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+524
+00:47:40,820 --> 00:47:41,480
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+525
+00:47:41,480 --> 00:47:41,500
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+526
+00:47:41,500 --> 00:47:46,500
+اتنين اتنين اتنين اتنين اتنين اتنين ااو ايزوبروبل
+
+527
+00:47:46,500 --> 00:47:49,900
+اكلورايد لو نفس المراكب بيقولنا بيعمله
+
+528
+00:47:49,900 --> 00:47:56,090
+دايكلوريلاشينوين ممكن احض دارتين لكلور؟ يا على
+
+529
+00:47:56,090 --> 00:47:59,750
+نمرة واحد واحد بيصير one one dichlorobropane يا
+
+530
+00:47:59,750 --> 00:48:07,150
+على واحد واثنين يا ع اتنين واثنين او ع واحد واثنين
+
+531
+00:48:07,150 --> 00:48:11,170
+او ع واحد تلاتة اذا لو انا قلتلكم dichlorination
+
+532
+00:48:11,170 --> 00:48:16,210
+of a propane produces come isomers كي بتكون تعمله
+
+533
+00:48:16,210 --> 00:48:22,960
+و تجربه بالورقة و الجلمتستفيدوا من كل المعلومات
+
+534
+00:48:22,960 --> 00:48:28,720
+اللي حكيناها بمعنى لو كان السؤال عندكم عن cycle
+
+535
+00:48:28,720 --> 00:48:33,000
+بتعرفوا تجاوبوه احنا اليوم جاوبناها لـcyclopropane
+
+536
+00:48:33,000 --> 00:48:37,220
+قولنا الـ monochlorination بيعطينا كام مركب؟ واحد
+
+537
+00:48:37,220 --> 00:48:43,300
+ال-dichlorination بيعطينا كام مركب؟ تلاتةسمناهم
+
+538
+00:48:43,300 --> 00:48:48,640
+one one و one two six و one two .. Trans مظبوط ولا
+
+539
+00:48:48,640 --> 00:48:53,860
+لأ؟ و هكذا دائما ممكن يجيكم أسئلة و ممكن الأن
+
+540
+00:48:53,860 --> 00:48:58,540
+ماعطيكم سؤالين أنتوا تحلوهم لوحدكم تتدربوا عليهم و
+
+541
+00:48:58,540 --> 00:49:03,980
+بننهي فيهم المحاضرة لو مثلا قلنالكوا اعملونا لمركب
+
+542
+00:49:03,980 --> 00:49:11,980
+لبيوتينمونو إكلورينايشن ودايكلورينايشن تعملوه و
+
+543
+00:49:11,980 --> 00:49:16,400
+تسلمونا إياه و لهذا المُركّب لو تخيلتوا إنه في
+
+544
+00:49:16,400 --> 00:49:23,000
+عندكم مثل سايكلوبروبين شايفينه
+
+545
+00:49:23,000 --> 00:49:29,160
+المُركّب؟ إيش اسمه؟ مثل سايكلوبروبين اعملوله مونو
+
+546
+00:49:29,160 --> 00:49:34,510
+إكلورينايشنوDichlorination وشوفوا كم ناتج بيطلع
+
+547
+00:49:34,510 --> 00:49:38,230
+عندكم طبعا بتكونوا تنتبهوا ان الchlorination ممكن
+
+548
+00:49:38,230 --> 00:49:43,330
+يجي على المثل او على الحلقة بدي كل النواتج الممكنة
+
+549
+00:49:43,330 --> 00:49:47,830
+وهنا كل النواتج الممكنة هذا بحاجة انكوا تتدربوا
+
+550
+00:49:47,830 --> 00:49:52,700
+بشكل جيدو تعرفوا أنواع الهيدروجينز اللي موجودة و
+
+551
+00:49:52,700 --> 00:49:56,040
+تحددوا كام ناتج بيطلع عندهم من ال monochlorination
+
+552
+00:49:56,040 --> 00:50:00,340
+و ال dichlorination ترسموهم بعد ما ترسموهم انتبهوا
+
+553
+00:50:00,340 --> 00:50:05,180
+إذا في أشكال متشابهة انه ما تكرروهاش وبهيك بننهي
+
+554
+00:50:05,180 --> 00:50:06,040
+اليوم ان شاء الله
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-9ge495lcEc_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-9ge495lcEc_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..27db1b25fd229653382ea829fa02b2ffef46e294
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-9ge495lcEc_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4909, "start": 21.35, "end": 49.09, "text": "بسم الله الرحمن الرحيم نستأنف اليوم في موضوع ال alkanes و ال cycloalkanes زي ما بتعرفوا المرة الماضية أعطينا فكرة عن ال alkanes من ناحية التسمية و من ناحية بعض الخواص الفيزيائية و من ناحية تركيبها بمعنى عدد ذرات ال carbon و ال hydrogen", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 8717, 14851, 33456, 5172, 45595, 20498, 8978, 3714, 2407, 11242, 45367, 2423, 419, 5225, 279, 4032, 2423, 38154, 752, 667, 12779, 30767, 1829, 19446, 39894, 3615, 28480, 14407, 9673, 25720, 9673, 46958, 10632, 5551, 3615, 9566, 1829, 8315, 6156, 4117, 25720, 18871, 2423, 419, 5225, 279, 9154, 8717, 39319, 10632, 16712, 38251, 10632, 4032, 9154, 8717, 39319, 10632, 45030, 11242, 33962, 2407, 33546, 27188, 1829, 11622, 1829, 16373, 10632, 4032, 9154, 8717, 39319, 10632, 6055, 31747, 1829, 3555, 11296, 4724, 2304, 3615, 1863, 7578, 6225, 3215, 3215, 29910, 2288, 9307, 2423, 5954, 4032, 2423, 12697], 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"probability": 0.875}], "temperature": 1.0}, {"id": 19, "seek": 43892, "start": 416.2, "end": 438.92, "text": "نوع واحد بمعنى لو انا امسكت ذرة كلور خلّينا نفترض هذه لمخ اللون الأخضر بدي اشيل اي هيدروجين و احط مكانها كلور مش هذا تفاعل ابدال بدلنا هيدروجين بكلور الان لو شيلت هذه و حطيت كلور هيطلع عندى مركب", "tokens": [1863, 45367, 36764, 24401, 4724, 2304, 3615, 1863, 7578, 45164, 1975, 8315, 1975, 2304, 3794, 4117, 2655, 29910, 25720, 28242, 13063, 16490, 1211, 11703, 9957, 995, 8717, 5172, 2655, 43042, 29538, 32767, 9778, 13672, 11536, 16247, 9778, 11242, 2288, 4724, 16254, 1975, 8592, 26895, 1975, 1829, 8032, 25708, 2288, 29245, 9957, 4032, 1975, 5016, 9566, 3714, 41361, 11296, 28242, 13063, 37893, 23758, 6055, 5172, 995, 30241, 1975, 44510, 6027, 47525, 1211, 8315, 8032, 25708, 2288, 29245, 9957, 4724, 28820, 13063, 2423, 7649, 45164, 13412, 26895, 2655, 29538, 4032, 11331, 9566, 36081, 28242, 13063, 39896, 9566, 1211, 3615, 43242, 7578, 3714, 31747, 3555], "avg_logprob": 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0.71728515625}, {"start": 424.08, "end": 424.4, "word": " لمخ", "probability": 0.846435546875}, {"start": 424.4, "end": 424.78, "word": " اللون", "probability": 0.6484375}, {"start": 424.78, "end": 425.36, "word": " الأخضر", "probability": 0.9886474609375}, {"start": 425.36, "end": 425.94, "word": " بدي", "probability": 0.7322998046875}, {"start": 425.94, "end": 426.32, "word": " اشيل", "probability": 0.8197428385416666}, {"start": 426.32, "end": 426.6, "word": " اي", "probability": 0.7666015625}, {"start": 426.6, "end": 427.34, "word": " هيدروجين", "probability": 0.875}, {"start": 427.34, "end": 427.52, "word": " و", "probability": 0.71044921875}, {"start": 427.52, "end": 427.8, "word": " احط", "probability": 0.85888671875}, {"start": 427.8, "end": 428.52, "word": " مكانها", "probability": 0.9874674479166666}, {"start": 428.52, "end": 429.36, "word": " كلور", "probability": 0.86572265625}, {"start": 429.36, "end": 429.74, "word": " مش", "probability": 0.89306640625}, {"start": 429.74, 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"probability": 0.9899088541666666}, {"start": 468.42, "end": 469.38, "word": " وعشان", "probability": 0.75347900390625}, {"start": 469.38, "end": 470.88, "word": " هيك", "probability": 0.957275390625}, {"start": 470.88, "end": 471.7, "word": " بنقدر", "probability": 0.86279296875}, {"start": 471.7, "end": 472.2, "word": " نتبع", "probability": 0.9676513671875}, {"start": 472.2, "end": 472.98, "word": " هالكلام", "probability": 0.8323974609375}, {"start": 472.98, "end": 473.84, "word": " جملة", "probability": 0.9554036458333334}, {"start": 473.84, "end": 474.4, "word": " تانية", "probability": 0.97412109375}, {"start": 474.4, "end": 476.18, "word": " monochlorination", "probability": 0.7393798828125}, {"start": 476.18, "end": 476.44, "word": " of", "probability": 0.9462890625}, {"start": 476.44, "end": 477.34, "word": " cyclopropane", "probability": 0.81298828125}, {"start": 477.34, "end": 477.8, "word": " معناه", "probability": 0.841796875}, {"start": 477.8, "end": 478.8, "word": " monochlorination", "probability": 0.8150634765625}, {"start": 478.8, "end": 478.98, "word": " إن", "probability": 0.21044921875}, {"start": 478.98, "end": 479.1, "word": " أنا", "probability": 0.77001953125}, {"start": 479.1, "end": 479.6, "word": " أبدل", "probability": 0.9073893229166666}, {"start": 479.6, "end": 480.34, "word": " هيدروجين", "probability": 0.839697265625}, {"start": 480.34, "end": 481.2, "word": " واحدة", "probability": 0.966796875}, {"start": 481.2, "end": 481.92, "word": " بكلور", "probability": 0.869140625}, {"start": 481.92, "end": 482.3, "word": " واحدة", "probability": 0.98046875}, {"start": 482.3, "end": 482.46, "word": " شو", "probability": 0.747802734375}, {"start": 482.46, "end": 482.9, "word": " بسمي", "probability": 0.9591471354166666}, {"start": 482.9, "end": 484.38, "word": " العملية؟", "probability": 0.8255615234375}, {"start": 484.38, "end": 485.68, "word": " mono", "probability": 0.51123046875}, {"start": 485.68, "end": 486.92, "word": " يعني", "probability": 0.8720703125}, {"start": 486.92, "end": 487.6, "word": " أحادي", "probability": 0.7562255859375}, {"start": 487.6, "end": 491.12, "word": " monochlorination", "probability": 0.675750732421875}, {"start": 491.12, "end": 491.82, "word": " إيش", "probability": 0.83837890625}, {"start": 491.82, "end": 492.02, "word": " يعني", "probability": 0.9736328125}, {"start": 492.02, "end": 493.3, "word": " chlorination؟", "probability": 0.8995768229166666}], "temperature": 1.0}, {"id": 22, "seek": 52090, "start": 494.82, "end": 520.9, "text": "تفاعل مع الكلور تفاعل الـ Cyclopropane مع الكلور إبدال بذرة واحدة Monochlorination of Cyclopropane produces only one product بيطلع فقط ناتج واحد، شو سميته أنا؟ Chlorocyclopropane واضح؟", "tokens": [2655, 5172, 995, 30241, 20449, 33251, 1211, 13063, 6055, 5172, 995, 30241, 2423, 39184, 49173, 404, 1513, 1929, 20449, 33251, 1211, 13063, 11933, 44510, 6027, 4724, 8848, 25720, 36764, 24401, 3660, 4713, 8997, 6746, 2486, 295, 49173, 404, 1513, 1929, 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"probability": 0.91748046875}, {"start": 1022.31, "end": 1022.95, "word": " bonding", "probability": 0.92333984375}, {"start": 1022.95, "end": 1024.03, "word": " لكن", "probability": 0.8642578125}, {"start": 1024.03, "end": 1024.45, "word": " اين", "probability": 0.8271484375}, {"start": 1024.45, "end": 1025.69, "word": " الاختلاف؟", "probability": 0.9412434895833334}, {"start": 1025.69, "end": 1026.19, "word": " بالشكل", "probability": 0.8914388020833334}, {"start": 1026.19, "end": 1026.31, "word": " ..", "probability": 0.470703125}, {"start": 1026.31, "end": 1026.97, "word": " بالشكل", "probability": 0.9832356770833334}, {"start": 1026.97, "end": 1027.93, "word": " الفراغي", "probability": 0.9572265625}, {"start": 1027.93, "end": 1028.39, "word": " they", "probability": 0.90869140625}, {"start": 1028.39, "end": 1028.67, "word": " have", "probability": 0.96826171875}, {"start": 1028.67, "end": 1028.97, "word": " the", "probability": 0.94775390625}, {"start": 1028.97, "end": 1029.29, "word": " same", "probability": 0.92333984375}, {"start": 1029.29, "end": 1029.87, "word": " bonding", "probability": 0.912109375}], "temperature": 1.0}, {"id": 42, "seek": 104633, "start": 1030.57, "end": 1046.33, "text": "but different arrangement in space شكلهم بالفراغ مختلف ان هدول الذرتين ع جهة واحدة و هدول الذرتين ع جهات متعاكسة بس اتنين ع واحد اتنين هذا النوع اللي احنا ايش سمنا stereo isomers", "tokens": [5955, 819, 17620, 294, 1901, 13412, 28820, 16095, 20666, 5172, 2288, 5718, 118, 3714, 46456, 46538, 16472, 8032, 3215, 12610, 32545, 2288, 2655, 9957, 6225, 10874, 3224, 3660, 36764, 24401, 3660, 4032, 8032, 3215, 12610, 32545, 43500, 9957, 6225, 10874, 3224, 9307, 44650, 3615, 995, 4117, 3794, 3660, 4724, 3794, 1975, 2655, 1863, 9957, 6225, 36764, 24401, 1975, 2655, 1863, 9957, 23758, 28239, 45367, 13672, 1829, 1975, 5016, 8315, 1975, 1829, 8592, 8608, 2304, 8315, 29029, 307, 298, 433], "avg_logprob": -0.22851562071591616, "compression_ratio": 1.6337209302325582, 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"end": 1036.65, "word": " ع", "probability": 0.77001953125}, {"start": 1036.65, "end": 1036.91, "word": " جهة", "probability": 0.8271484375}, {"start": 1036.91, "end": 1037.61, "word": " واحدة", "probability": 0.95068359375}, {"start": 1037.61, "end": 1037.89, "word": " و", "probability": 0.60888671875}, {"start": 1037.89, "end": 1038.11, "word": " هدول", "probability": 0.9449869791666666}, {"start": 1038.11, "end": 1038.59, "word": " الذرتين", "probability": 0.8297526041666666}, {"start": 1038.59, "end": 1038.71, "word": " ع", "probability": 0.962890625}, {"start": 1038.71, "end": 1039.01, "word": " جهات", "probability": 0.9156901041666666}, {"start": 1039.01, "end": 1039.91, "word": " متعاكسة", "probability": 0.9178059895833334}, {"start": 1039.91, "end": 1040.33, "word": " بس", "probability": 0.837158203125}, {"start": 1040.33, "end": 1040.69, "word": " اتنين", "probability": 0.75091552734375}, {"start": 1040.69, "end": 1040.83, "word": " ع", "probability": 0.7421875}, {"start": 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قلنا ال stereo isomers they have the same bonding يعني لما أجي أقول الكلور وين؟ ع واحد و التانية ع اتنين في التاني الكلور وين؟ ع واحد و التانية ع اتنين اذا they have the same bonding طب وين اختلفوا؟", "tokens": [3224, 15730, 28239, 45367, 13672, 1829, 8608, 2304, 8315, 3224, 29029, 307, 298, 433, 5296, 15042, 11331, 4117, 1829, 8315, 15844, 2423, 307, 14301, 1434, 12174, 1211, 8315, 2423, 29029, 307, 298, 433, 436, 362, 264, 912, 28824, 37495, 22653, 5296, 15042, 5551, 7435, 1829, 5551, 39648, 33251, 1211, 13063, 4032, 9957, 22807, 6225, 36764, 24401, 4032, 16712, 7649, 10632, 6225, 1975, 2655, 1863, 9957, 8978, 16712, 7649, 1829, 33251, 1211, 13063, 4032, 9957, 22807, 6225, 36764, 24401, 4032, 16712, 7649, 10632, 6225, 1975, 2655, 1863, 9957, 1975, 15730, 436, 362, 264, 912, 28824, 23032, 3555, 4032, 9957, 1975, 46456, 46538, 14407, 22807], "avg_logprob": -0.15256911157988584, "compression_ratio": 1.9748743718592965, "no_speech_prob": 0.0, "words": [{"start": 1047.01, "end": 1047.49, 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{"start": 1057.95, "end": 1058.69, "word": " الكلور", "probability": 0.7347005208333334}, {"start": 1058.69, "end": 1059.01, "word": " وين؟", "probability": 0.8857421875}, {"start": 1059.01, "end": 1059.09, "word": " ع", "probability": 0.75732421875}, {"start": 1059.09, "end": 1059.55, "word": " واحد", "probability": 0.9248046875}, {"start": 1059.55, "end": 1059.69, "word": " و", "probability": 0.5}, {"start": 1059.69, "end": 1060.27, "word": " التانية", "probability": 0.869140625}, {"start": 1060.27, "end": 1060.69, "word": " ع", "probability": 0.8359375}, {"start": 1060.69, "end": 1061.09, "word": " اتنين", "probability": 0.8831787109375}, {"start": 1061.09, "end": 1061.67, "word": " في", "probability": 0.52978515625}, {"start": 1061.67, "end": 1062.07, "word": " التاني", "probability": 0.919921875}, {"start": 1062.07, "end": 1062.49, "word": " الكلور", "probability": 0.94189453125}, {"start": 1062.49, "end": 1062.97, "word": " وين؟", "probability": 0.98388671875}, {"start": 1062.97, "end": 1063.13, "word": " ع", "probability": 0.96728515625}, {"start": 1063.13, "end": 1063.95, "word": " واحد", "probability": 0.978271484375}, {"start": 1063.95, "end": 1064.11, "word": " و", "probability": 0.9580078125}, {"start": 1064.11, "end": 1064.63, "word": " التانية", "probability": 0.9803059895833334}, {"start": 1064.63, "end": 1065.31, "word": " ع", "probability": 0.9091796875}, {"start": 1065.31, "end": 1065.63, "word": " اتنين", "probability": 0.9495849609375}, {"start": 1065.63, "end": 1065.87, "word": " اذا", "probability": 0.6214599609375}, {"start": 1065.87, "end": 1066.05, "word": " they", "probability": 0.93115234375}, {"start": 1066.05, "end": 1066.31, "word": " have", "probability": 0.97216796875}, {"start": 1066.31, "end": 1066.47, "word": " the", "probability": 0.93994140625}, {"start": 1066.47, "end": 1066.75, "word": " same", "probability": 0.919921875}, {"start": 1066.75, "end": 1067.29, "word": " bonding", "probability": 0.90771484375}, {"start": 1067.29, "end": 1067.79, "word": " طب", "probability": 0.902099609375}, {"start": 1067.79, "end": 1067.97, "word": " وين", "probability": 0.988525390625}, {"start": 1067.97, "end": 1068.81, "word": " اختلفوا؟", "probability": 0.97451171875}], "temperature": 1.0}, {"id": 44, "seek": 109821, "start": 1069.67, "end": 1098.21, "text": "بشكل برفرات اه هدول ع واحد و اتنين ع جهة واحدة على واحد و اتنين ع جهتين مختلفتين هذه بنسميها different arrangement in space اذا العلاقة بين هذا ال cis و ال trans they are stereo isomers لاحظوا لو قلتلكوا ما العلاقة بين هذا المركب و هذا المركب في ال isomers", "tokens": [3555, 8592, 28820, 4724, 2288, 5172, 2288, 9307, 1975, 3224, 8032, 3215, 12610, 6225, 36764, 24401, 4032, 1975, 2655, 1863, 9957, 6225, 10874, 3224, 3660, 36764, 24401, 3660, 15844, 36764, 24401, 4032, 1975, 2655, 1863, 9957, 6225, 10874, 3224, 2655, 9957, 3714, 46456, 46538, 2655, 9957, 29538, 44945, 38251, 1829, 11296, 819, 17620, 294, 1901, 1975, 15730, 18863, 15040, 28671, 49374, 23758, 2423, 37847, 4032, 2423, 1145, 436, 366, 29029, 307, 298, 433, 20193, 5016, 19913, 14407, 45164, 12174, 1211, 2655, 23275, 14407, 19446, 18863, 15040, 28671, 49374, 23758, 9673, 31747, 3555, 4032, 23758, 9673, 31747, 3555, 8978, 2423, 307, 298, 433], "avg_logprob": -0.1903822835787986, "compression_ratio": 1.8957345971563981, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1069.67, "end": 1070.31, "word": "بشكل", "probability": 0.7825520833333334}, {"start": 1070.31, "end": 1070.87, "word": " برفرات", "probability": 0.77451171875}, {"start": 1070.87, "end": 1071.21, "word": " اه", "probability": 0.5272216796875}, {"start": 1071.21, "end": 1071.51, "word": " هدول", "probability": 0.8868815104166666}, {"start": 1071.51, "end": 1071.63, "word": " ع", "probability": 0.6865234375}, {"start": 1071.63, "end": 1071.93, "word": " واحد", "probability": 0.7841796875}, {"start": 1071.93, "end": 1072.09, "word": " و", "probability": 0.95263671875}, {"start": 1072.09, "end": 1072.35, "word": " اتنين", "probability": 0.930419921875}, {"start": 1072.35, "end": 1072.55, "word": " ع", "probability": 0.82373046875}, {"start": 1072.55, "end": 1072.73, "word": " جهة", "probability": 0.88134765625}, {"start": 1072.73, "end": 1073.47, "word": " واحدة", "probability": 0.9435221354166666}, {"start": 1073.47, "end": 1074.09, "word": " على", "probability": 0.308837890625}, {"start": 1074.09, "end": 1074.39, "word": " واحد", "probability": 0.97900390625}, {"start": 1074.39, "end": 1074.53, "word": " و", "probability": 0.95361328125}, {"start": 1074.53, "end": 1074.73, "word": " اتنين", "probability": 0.9683837890625}, {"start": 1074.73, "end": 1074.89, "word": " ع", "probability": 0.8427734375}, {"start": 1074.89, "end": 1075.29, "word": " جهتين", "probability": 0.95166015625}, {"start": 1075.29, "end": 1076.23, "word": " مختلفتين", "probability": 0.97578125}, {"start": 1076.23, "end": 1076.61, "word": " هذه", "probability": 0.322021484375}, {"start": 1076.61, "end": 1077.25, "word": " بنسميها", "probability": 0.9002685546875}, {"start": 1077.25, "end": 1077.63, "word": " different", "probability": 0.7822265625}, {"start": 1077.63, "end": 1078.65, "word": " arrangement", "probability": 0.7919921875}, {"start": 1078.65, "end": 1079.09, "word": " in", "probability": 0.95068359375}, {"start": 1079.09, "end": 1080.29, "word": " space", "probability": 0.90625}, {"start": 1080.29, "end": 1080.99, "word": " اذا", "probability": 0.64306640625}, {"start": 1080.99, "end": 1081.91, "word": " العلاقة", "probability": 0.9619140625}, {"start": 1081.91, "end": 1082.17, "word": " بين", "probability": 0.9677734375}, {"start": 1082.17, "end": 1082.65, "word": " هذا", "probability": 0.87060546875}, {"start": 1082.65, "end": 1082.99, "word": " ال", "probability": 0.88037109375}, {"start": 1082.99, "end": 1083.33, "word": " cis", "probability": 0.383056640625}, {"start": 1083.33, "end": 1083.71, "word": " و", "probability": 0.62353515625}, {"start": 1083.71, "end": 1083.79, "word": " ال", "probability": 0.47314453125}, {"start": 1083.79, "end": 1084.49, "word": " trans", "probability": 0.67724609375}, {"start": 1084.49, "end": 1085.05, "word": " they", "probability": 0.78662109375}, {"start": 1085.05, "end": 1085.69, "word": " are", "probability": 0.966796875}, {"start": 1085.69, "end": 1087.85, "word": " stereo", "probability": 0.468017578125}, {"start": 1087.85, "end": 1088.89, "word": " isomers", "probability": 0.9158528645833334}, {"start": 1088.89, "end": 1092.07, "word": " لاحظوا", "probability": 0.81121826171875}, {"start": 1092.07, "end": 1092.45, "word": " لو", "probability": 0.9384765625}, {"start": 1092.45, "end": 1092.95, "word": " قلتلكوا", "probability": 0.93720703125}, {"start": 1092.95, "end": 1093.03, "word": " ما", "probability": 0.79345703125}, {"start": 1093.03, "end": 1093.65, "word": " العلاقة", "probability": 0.9588216145833334}, {"start": 1093.65, "end": 1093.95, "word": " بين", "probability": 0.84521484375}, {"start": 1093.95, "end": 1094.39, "word": " هذا", "probability": 0.95751953125}, {"start": 1094.39, "end": 1095.09, "word": " المركب", "probability": 0.9069010416666666}, {"start": 1095.09, "end": 1095.19, "word": " و", "probability": 0.88720703125}, {"start": 1095.19, "end": 1095.47, "word": " هذا", "probability": 0.95166015625}, {"start": 1095.47, "end": 1096.93, "word": " المركب", "probability": 0.9860026041666666}, {"start": 1096.93, "end": 1097.35, "word": " في", "probability": 0.89013671875}, {"start": 1097.35, "end": 1097.47, "word": " ال", "probability": 0.884765625}, {"start": 1097.47, "end": 1098.21, "word": " isomers", "probability": 0.9640299479166666}], "temperature": 1.0}, {"id": 45, "seek": 110397, "start": 1099.61, "end": 1103.97, "text": "هنا they have different bonding و different names", "tokens": [3224, 8315, 436, 362, 819, 28824, 4032, 819, 5288], "avg_logprob": -0.35117186307907106, "compression_ratio": 1.0192307692307692, "no_speech_prob": 0.0, "words": [{"start": 1099.61, "end": 1100.09, "word": "هنا", "probability": 0.737548828125}, {"start": 1100.09, "end": 1100.35, "word": " they", "probability": 0.306884765625}, {"start": 1100.35, "end": 1100.65, "word": " have", "probability": 0.96044921875}, {"start": 1100.65, "end": 1101.19, "word": " different", "probability": 0.95068359375}, {"start": 1101.19, "end": 1101.73, "word": " bonding", "probability": 0.7197265625}, {"start": 1101.73, "end": 1102.87, "word": " و", "probability": 0.8505859375}, {"start": 1102.87, "end": 1103.27, "word": " different", "probability": 0.84814453125}, {"start": 1103.27, "end": 1103.97, "word": " names", "probability": 0.89599609375}], "temperature": 1.0}, {"id": 46, "seek": 113085, "start": 1105.94, "end": 1130.86, "text": "ذرتين الكلور على واحد و واحد وعشان هيك سميته one one dichlorocyclopropane هنا ذرتين الكلور على واحد و اتنين هذا ال same bonding ولا different bonding different bonding ال different bonding أدى إلى different names أنا لما حددت مواقع الكلور قلت one one هنا قلت one two إذا هذا المركب و هذا المركب", "tokens": [8848, 43500, 9957, 33251, 1211, 13063, 15844, 36764, 24401, 4032, 36764, 24401, 4032, 3615, 8592, 7649, 39896, 4117, 8608, 2304, 36081, 3224, 472, 472, 10390, 6746, 31078, 3474, 404, 1513, 1929, 34105, 29910, 43500, 9957, 33251, 1211, 13063, 15844, 36764, 24401, 4032, 1975, 2655, 1863, 9957, 23758, 2423, 912, 28824, 49429, 819, 28824, 819, 28824, 2423, 819, 28824, 5551, 3215, 7578, 30731, 819, 5288, 41850, 5296, 15042, 11331, 3215, 3215, 2655, 3714, 14407, 4587, 3615, 33251, 1211, 13063, 12174, 1211, 2655, 472, 472, 34105, 12174, 1211, 2655, 472, 732, 11933, 15730, 23758, 9673, 31747, 3555, 4032, 23758, 9673, 31747, 3555], "avg_logprob": -0.23746906530739056, "compression_ratio": 2.0531400966183573, "no_speech_prob": 0.0, "words": [{"start": 1105.94, "end": 1106.58, "word": "ذرتين", "probability": 0.6253255208333334}, {"start": 1106.58, "end": 1107.02, "word": " الكلور", "probability": 0.7620442708333334}, {"start": 1107.02, "end": 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1129.8, "word": " و", "probability": 0.73291015625}, {"start": 1129.8, "end": 1130.1, "word": " هذا", "probability": 0.93798828125}, {"start": 1130.1, "end": 1130.86, "word": " المركب", "probability": 0.9856770833333334}], "temperature": 1.0}, {"id": 47, "seek": 115911, "start": 1133.14, "end": 1159.12, "text": "صحيح مكونين من نفس الذرات لكن فيهم different bonding و different names فالعلاقة بين ال 11-dichlorocyclopropane و ال 12-dichlorocyclopropane they are structural isomers و كذلك العلاقة بين هذا و هذا لكن لو قلت العلاقة بين ال cis و ال trans they are stereo isomers", "tokens": [9381, 5016, 1829, 5016, 3714, 30544, 9957, 9154, 8717, 36178, 32545, 2288, 9307, 44381, 8978, 16095, 819, 28824, 4032, 819, 5288, 6156, 6027, 3615, 15040, 28671, 49374, 2423, 2975, 12, 67, 480, 6746, 31078, 3474, 404, 1513, 1929, 4032, 2423, 2272, 12, 67, 480, 6746, 31078, 3474, 404, 1513, 1929, 436, 366, 15067, 307, 298, 433, 4032, 9122, 8848, 23275, 18863, 15040, 28671, 49374, 23758, 4032, 23758, 44381, 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"-dichlorocyclopropane", "probability": 0.9656575520833334}, {"start": 1146.42, "end": 1146.64, "word": " they", "probability": 0.28173828125}, {"start": 1146.64, "end": 1147.16, "word": " are", "probability": 0.96337890625}, {"start": 1147.16, "end": 1148.5, "word": " structural", "probability": 0.78466796875}, {"start": 1148.5, "end": 1149.52, "word": " isomers", "probability": 0.9651692708333334}, {"start": 1149.52, "end": 1149.92, "word": " و", "probability": 0.92626953125}, {"start": 1149.92, "end": 1150.38, "word": " كذلك", "probability": 0.9562174479166666}, {"start": 1150.38, "end": 1150.92, "word": " العلاقة", "probability": 0.9830729166666666}, {"start": 1150.92, "end": 1151.18, "word": " بين", "probability": 0.97021484375}, {"start": 1151.18, "end": 1151.48, "word": " هذا", "probability": 0.794921875}, {"start": 1151.48, "end": 1151.64, "word": " و", "probability": 0.7451171875}, {"start": 1151.64, "end": 1151.9, "word": " هذا", "probability": 0.94384765625}, {"start": 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"word": " stereo", "probability": 0.71875}, {"start": 1158.0, "end": 1159.12, "word": " isomers", "probability": 0.95947265625}], "temperature": 1.0}, {"id": 48, "seek": 117360, "start": 1161.81, "end": 1173.61, "text": "Same bonding but different arrangement in space هي تعريف الـ Stereoisomers نفس الإرتباط ولكن يختلف فيه الشكل بالفراغ", "tokens": [50, 529, 28824, 457, 819, 17620, 294, 1901, 39896, 37279, 16572, 5172, 2423, 39184, 745, 323, 7376, 298, 433, 8717, 36178, 33688, 43500, 3555, 41193, 35525, 19452, 7251, 46456, 46538, 8978, 3224, 25124, 28820, 20666, 5172, 2288, 5718, 118], "avg_logprob": -0.3025390639901161, "compression_ratio": 1.1666666666666667, "no_speech_prob": 0.0, "words": [{"start": 1161.81, "end": 1162.49, "word": "Same", "probability": 0.57391357421875}, {"start": 1162.49, "end": 1163.37, "word": " bonding", "probability": 0.845703125}, {"start": 1163.37, "end": 1164.01, "word": " but", "probability": 0.481201171875}, {"start": 1164.01, "end": 1164.71, "word": " different", "probability": 0.80908203125}, {"start": 1164.71, "end": 1165.43, "word": " arrangement", "probability": 0.6201171875}, {"start": 1165.43, "end": 1165.69, "word": " in", "probability": 0.91845703125}, {"start": 1165.69, "end": 1166.07, "word": " space", "probability": 0.86962890625}, {"start": 1166.07, "end": 1166.21, "word": " هي", "probability": 0.1185302734375}, {"start": 1166.21, "end": 1166.63, "word": " تعريف", "probability": 0.9830729166666666}, {"start": 1166.63, "end": 1166.83, "word": " الـ", "probability": 0.5621337890625}, {"start": 1166.83, "end": 1167.79, "word": " Stereoisomers", "probability": 0.792431640625}, {"start": 1167.79, "end": 1168.81, "word": " نفس", "probability": 0.94873046875}, {"start": 1168.81, "end": 1169.59, "word": " الإرتباط", "probability": 0.89111328125}, {"start": 1169.59, "end": 1170.01, "word": " ولكن", "probability": 0.88134765625}, {"start": 1170.01, "end": 1170.55, "word": " يختلف", "probability": 0.9855143229166666}, {"start": 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1184.59, "end": 1185.71, "word": " Diastereomers", "probability": 0.72158203125}, {"start": 1185.71, "end": 1186.67, "word": " هنتعلمه", "probability": 0.8330078125}, {"start": 1186.67, "end": 1187.05, "word": " و", "probability": 0.85107421875}, {"start": 1187.05, "end": 1187.27, "word": " نوع", "probability": 0.9150390625}, {"start": 1187.27, "end": 1187.53, "word": " منهم", "probability": 0.990234375}, {"start": 1187.53, "end": 1188.15, "word": " بنسميه", "probability": 0.938720703125}, {"start": 1188.15, "end": 1188.83, "word": " Enantiomers", "probability": 0.79083251953125}, {"start": 1188.83, "end": 1189.67, "word": " الآن", "probability": 0.593994140625}, {"start": 1189.67, "end": 1190.59, "word": " هدولة", "probability": 0.7301025390625}, {"start": 1190.59, "end": 1191.71, "word": " المركبين", "probability": 0.916015625}, {"start": 1191.71, "end": 1192.93, "word": " مثال", "probability": 0.9912109375}, {"start": 1192.93, "end": 1193.77, "word": " لأحد", "probability": 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9307, 7435, 40294, 29538, 6225, 4117, 3794, 11296, 37037, 24192, 2423, 3224, 25708, 2288, 29245, 9957, 4724, 9307, 7435, 40294, 29538, 6225, 4117, 3794, 11296, 37495, 22653, 5296, 24401, 29538, 28239, 47432, 3660], "avg_logprob": -0.22639973709980646, "compression_ratio": 1.910179640718563, "no_speech_prob": 0.0, "words": [{"start": 1297.28, "end": 1297.86, "word": "الان", "probability": 0.866455078125}, {"start": 1297.86, "end": 1298.32, "word": " لو", "probability": 0.85888671875}, {"start": 1298.32, "end": 1298.72, "word": " اتيت", "probability": 0.69873046875}, {"start": 1298.72, "end": 1298.86, "word": " يا", "probability": 0.6943359375}, {"start": 1298.86, "end": 1299.22, "word": " تورا", "probability": 0.8128255208333334}, {"start": 1299.22, "end": 1300.48, "word": " اتسألت", "probability": 0.79034423828125}, {"start": 1300.48, "end": 1300.86, "word": " هل", "probability": 0.894287109375}, {"start": 1300.86, "end": 1301.4, "word": " هدولة", "probability": 0.6912841796875}, {"start": 1301.4, "end": 1301.56, "word": " من", "probability": 0.97705078125}, {"start": 1301.56, "end": 1302.44, "word": " الاساس", "probability": 0.8211263020833334}, {"start": 1302.44, "end": 1303.26, "word": " صورة", "probability": 0.9900716145833334}, {"start": 1303.26, "end": 1303.8, "word": " مرآه", "probability": 0.77919921875}, {"start": 1303.8, "end": 1303.94, "word": " ولا", "probability": 0.82421875}, {"start": 1303.94, "end": 1304.18, "word": " مش", "probability": 0.9248046875}, {"start": 1304.18, "end": 1304.58, "word": " صورة", "probability": 0.9806315104166666}, {"start": 1304.58, "end": 1305.24, "word": " مرآه؟", "probability": 0.8777262369791666}, {"start": 1305.24, "end": 1306.6, "word": " لاحظوا", "probability": 0.8853759765625}, {"start": 1306.6, "end": 1307.14, "word": " يمكن", "probability": 0.88623046875}, {"start": 1307.14, "end": 1307.36, "word": " هنا", "probability": 0.81494140625}, {"start": 1307.36, "end": 1307.78, "word": " تلاقي", "probability": 0.84521484375}, {"start": 1307.78, "end": 1308.26, "word": " كلور", "probability": 0.7285970052083334}, {"start": 1308.26, "end": 1308.78, "word": " متجه", "probability": 0.92626953125}, {"start": 1308.78, "end": 1309.24, "word": " باتجاه", "probability": 0.8282470703125}, {"start": 1309.24, "end": 1309.48, "word": " هذه", "probability": 0.51904296875}, {"start": 1309.48, "end": 1309.9, "word": " عكسها", "probability": 0.9508056640625}, {"start": 1309.9, "end": 1310.12, "word": " وهذه", "probability": 0.328857421875}, {"start": 1310.12, "end": 1310.6, "word": " الهيدروجين", "probability": 0.8495279947916666}, {"start": 1310.6, "end": 1310.96, "word": " باتجاه", "probability": 0.822509765625}, {"start": 1310.96, "end": 1311.08, "word": " هذه", "probability": 0.8876953125}, {"start": 1311.08, "end": 1311.4, "word": " عكسها", "probability": 0.989501953125}, {"start": 1311.4, "end": 1311.8, "word": " يعني", "probability": 0.825927734375}, {"start": 1311.8, "end": 1312.18, "word": " لحد", "probability": 0.906982421875}, {"start": 1312.18, "end": 1312.4, "word": " هذه", "probability": 0.67626953125}, {"start": 1312.4, "end": 1313.06, "word": " النقطة", "probability": 0.982421875}], "temperature": 1.0}, {"id": 55, "seek": 132822, "start": 1314.14, "end": 1328.22, "text": "معاكسات لكن هنا في chlorine إقبالها hydrogen تحت هنا في chlorine إقبالها hydrogen هل هدولة بيصيروا صورة مرآة إذا بطلوا صورة مرآة", "tokens": [2304, 3615, 995, 4117, 3794, 9307, 44381, 34105, 8978, 39888, 11933, 4587, 3555, 6027, 11296, 12697, 6055, 33753, 34105, 8978, 39888, 11933, 4587, 3555, 6027, 11296, 12697, 8032, 1211, 8032, 3215, 12610, 3660, 4724, 1829, 9381, 13546, 14407, 20328, 13063, 3660, 3714, 2288, 148, 95, 3660, 11933, 15730, 4724, 9566, 1211, 14407, 20328, 13063, 3660, 3714, 2288, 148, 95, 3660], "avg_logprob": -0.15112704429470125, "compression_ratio": 1.5984251968503937, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1314.14, "end": 1315.14, "word": "معاكسات", "probability": 0.9659016927083334}, {"start": 1315.14, "end": 1315.6, "word": " لكن", "probability": 0.4873046875}, {"start": 1315.6, "end": 1316.12, "word": " هنا", "probability": 0.98486328125}, {"start": 1316.12, "end": 1316.46, "word": " في", "probability": 0.9423828125}, {"start": 1316.46, "end": 1317.0, "word": " chlorine", "probability": 0.279052734375}, {"start": 1317.0, "end": 1318.46, "word": " إقبالها", "probability": 0.855712890625}, {"start": 1318.46, "end": 1319.76, "word": " hydrogen", "probability": 0.421142578125}, {"start": 1319.76, "end": 1320.76, "word": " تحت", "probability": 0.839111328125}, {"start": 1320.76, "end": 1320.98, "word": " هنا", "probability": 0.94970703125}, {"start": 1320.98, "end": 1321.28, "word": " في", "probability": 0.91552734375}, {"start": 1321.28, "end": 1322.16, "word": " chlorine", "probability": 0.67138671875}, {"start": 1322.16, "end": 1322.68, "word": " إقبالها", "probability": 0.963671875}, {"start": 1322.68, "end": 1322.98, "word": " hydrogen", "probability": 0.60546875}, {"start": 1322.98, "end": 1323.42, "word": " هل", "probability": 0.926025390625}, {"start": 1323.42, "end": 1323.8, "word": " هدولة", "probability": 0.8343505859375}, {"start": 1323.8, "end": 1324.56, "word": " بيصيروا", "probability": 0.9607421875}, {"start": 1324.56, "end": 1325.14, "word": " صورة", "probability": 0.9763997395833334}, {"start": 1325.14, "end": 1326.36, "word": " مرآة", "probability": 0.82841796875}, {"start": 1326.36, "end": 1326.64, "word": " إذا", "probability": 0.730224609375}, {"start": 1326.64, "end": 1327.18, "word": " بطلوا", "probability": 0.9476318359375}, {"start": 1327.18, "end": 1327.58, "word": " صورة", "probability": 0.9938151041666666}, {"start": 1327.58, "end": 1328.22, "word": " مرآة", "probability": 0.9859375}], "temperature": 1.0}, {"id": 56, "seek": 135187, "start": 1329.11, "end": 1351.87, "text": "شرط صورة المرآة أن كل جزء من الجزيئات هيكون بعكس الجثة الآخر هدولة فيهم أشياء أساسا مش اقبال .. مش .. يعني هذه لا فوق، كلور اقبالها هيدروجين، إذا هدولة الشكلين الcess والترانس لما أنا بدي أحكي عنهم بقول they are non mirror", "tokens": [46309, 9566, 20328, 13063, 3660, 9673, 2288, 148, 95, 3660, 14739, 28242, 10874, 11622, 38207, 9154, 25724, 11622, 1829, 19986, 9307, 39896, 30544, 45030, 4117, 3794, 25724, 12984, 3660, 6024, 95, 34740, 8032, 3215, 12610, 3660, 8978, 16095, 5551, 8592, 1829, 16606, 5551, 3794, 32277, 995, 37893, 1975, 4587, 3555, 6027, 4386, 37893, 4386, 37495, 22653, 29538, 20193, 6156, 30543, 12399, 9122, 1211, 13063, 1975, 4587, 3555, 6027, 11296, 8032, 25708, 2288, 29245, 9957, 12399, 11933, 15730, 8032, 3215, 12610, 3660, 25124, 28820, 9957, 2423, 780, 16070, 2655, 2288, 7649, 3794, 5296, 15042, 41850, 4724, 16254, 5551, 5016, 4117, 1829, 18871, 16095, 4724, 39648, 436, 366, 2107, 8013], "avg_logprob": -0.3047591633752945, "compression_ratio": 1.6363636363636365, "no_speech_prob": 0.0, "words": [{"start": 1329.11, "end": 1329.61, "word": "شرط", "probability": 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"probability": 0.5481363932291666}, {"start": 1339.91, "end": 1340.45, "word": " كلور", "probability": 0.677734375}, {"start": 1340.45, "end": 1341.45, "word": " اقبالها", "probability": 0.863330078125}, {"start": 1341.45, "end": 1342.99, "word": " هيدروجين،", "probability": 0.7574869791666666}, {"start": 1342.99, "end": 1343.29, "word": " إذا", "probability": 0.70263671875}, {"start": 1343.29, "end": 1344.13, "word": " هدولة", "probability": 0.8848876953125}, {"start": 1344.13, "end": 1344.97, "word": " الشكلين", "probability": 0.86181640625}, {"start": 1344.97, "end": 1345.65, "word": " الcess", "probability": 0.436767578125}, {"start": 1345.65, "end": 1346.61, "word": " والترانس", "probability": 0.803125}, {"start": 1346.61, "end": 1347.05, "word": " لما", "probability": 0.890625}, {"start": 1347.05, "end": 1347.33, "word": " أنا", "probability": 0.69091796875}, {"start": 1347.33, "end": 1347.77, "word": " بدي", "probability": 0.758544921875}, {"start": 1347.77, "end": 1348.19, "word": " أحكي", "probability": 0.963623046875}, {"start": 1348.19, "end": 1348.49, "word": " عنهم", "probability": 0.990478515625}, {"start": 1348.49, "end": 1348.95, "word": " بقول", "probability": 0.957275390625}, {"start": 1348.95, "end": 1349.41, "word": " they", "probability": 0.76416015625}, {"start": 1349.41, "end": 1350.03, "word": " are", "probability": 0.9609375}, {"start": 1350.03, "end": 1350.73, "word": " non", "probability": 0.80419921875}, {"start": 1350.73, "end": 1351.87, "word": " mirror", "probability": 0.481201171875}], "temperature": 1.0}, {"id": 57, "seek": 137572, "start": 1353.72, "end": 1375.72, "text": "images، إيش يعني non-mirror images؟ مش صورة بعض في المرأة، الأشياء اللي بتكون مش صورة بعض في المرأة هي اللي تعرف ان اسمها diastereomers، وهذا مثال عليها، ف ال cicatrans، isomers، they are diastereomers", "tokens": [332, 1660, 12399, 11933, 1829, 8592, 37495, 22653, 2107, 12, 19834, 2874, 5267, 22807, 37893, 20328, 13063, 3660, 45030, 11242, 8978, 9673, 2288, 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{"start": 1362.12, "end": 1362.58, "word": " المرأة", "probability": 0.95361328125}, {"start": 1362.58, "end": 1362.96, "word": " هي", "probability": 0.6376953125}, {"start": 1362.96, "end": 1363.18, "word": " اللي", "probability": 0.977783203125}, {"start": 1363.18, "end": 1363.88, "word": " تعرف", "probability": 0.968017578125}, {"start": 1363.88, "end": 1365.36, "word": " ان", "probability": 0.33935546875}, {"start": 1365.36, "end": 1366.36, "word": " اسمها", "probability": 0.9641927083333334}, {"start": 1366.36, "end": 1367.6, "word": " diastereomers،", "probability": 0.61358642578125}, {"start": 1367.6, "end": 1367.96, "word": " وهذا", "probability": 0.885009765625}, {"start": 1367.96, "end": 1368.46, "word": " مثال", "probability": 0.973876953125}, {"start": 1368.46, "end": 1369.54, "word": " عليها،", "probability": 0.7962239583333334}, {"start": 1369.54, "end": 1369.7, "word": " ف", "probability": 0.953125}, {"start": 1369.7, "end": 1369.86, "word": " ال", "probability": 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1447.16, "word": " ده", "probability": 0.5748291015625}, {"start": 1447.16, "end": 1447.3, "word": " يا", "probability": 0.42724609375}, {"start": 1447.3, "end": 1447.94, "word": " stereomers", "probability": 0.8937174479166666}], "temperature": 1.0}, {"id": 61, "seek": 146803, "start": 1449.09, "end": 1468.03, "text": "تطلعوا معي مرة تانية نرسم أحد هدولة أو نعمل model لأحد هدولة المركبات اللي هم ال sis, trans, isomers واضح؟ هذا أي مركب فيهم؟ ال sis والتاني لترانس متى توجد عندنا ظاهرة ال sis و الترانس؟", "tokens": [2655, 9566, 1211, 3615, 14407, 20449, 1829, 3714, 25720, 6055, 7649, 10632, 8717, 2288, 38251, 5551, 24401, 8032, 3215, 12610, 3660, 34051, 8717, 25957, 1211, 2316, 5296, 10721, 24401, 8032, 3215, 12610, 3660, 9673, 31747, 3555, 9307, 13672, 1829, 8032, 2304, 2423, 26288, 11, 1145, 11, 307, 298, 433, 4032, 46958, 5016, 22807, 23758, 36632, 3714, 31747, 3555, 8978, 16095, 22807, 2423, 26288, 16070, 2655, 7649, 1829, 5296, 2655, 2288, 7649, 3794, 44650, 7578, 33427, 7435, 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trans هاي بال cycle اللي اتعرفنا عليه طيب حوالين ال double bond", "tokens": [6027, 6027, 4117, 9957, 11622, 13672, 1829, 8978, 11296, 12602, 14407, 3555, 9566, 6024, 110, 29245, 9957, 23758, 9673, 41361, 13672, 1829, 39894, 8592, 38688, 3224, 8978, 3224, 9122, 19528, 3660, 26288, 4032, 1145, 8978, 2423, 17796, 50113, 1211, 9673, 12984, 6027, 13672, 1829, 1975, 5016, 8315, 12602, 38251, 8315, 30767, 1829, 19446, 12174, 12610, 8315, 23758, 50113, 15040, 39627, 15730, 25124, 28820, 26288, 4032, 39627, 15730, 25124, 28820, 2423, 1145, 8032, 47302, 20666, 6586, 13672, 1829, 1975, 2655, 3615, 28480, 8315, 47356, 23032, 1829, 3555, 11331, 2407, 6027, 9957, 2423, 3834, 6086], "avg_logprob": -0.18650265862333013, "compression_ratio": 1.854368932038835, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1520.1, "end": 1520.86, "word": "الالكينز", "probability": 0.70673828125}, {"start": 1520.86, "end": 1520.96, "word": " اللي", "probability": 0.791259765625}, {"start": 1520.96, "end": 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بيتم لأنه انا لو جربت في cycle الكل بدي ألوف هذا هيك أخلي هدول يصيروا عكس بعض يعني ال 6 يصير ال trans لاحظوا لأنه مربوط بالحلقة الدوران حول الحلقة ممنوع الدوران حول الحلقة ممنوع الان طيب لو اتخيلتوا ان انا في عنده", "tokens": [6027, 6027, 4117, 47302, 11622, 2423, 6027, 4117, 9957, 11622, 6225, 5172, 14407, 32239, 8592, 23758, 2423, 28820, 10943, 4724, 36081, 2304, 5296, 33456, 3224, 1975, 8315, 45164, 10874, 25513, 2655, 8978, 6586, 2423, 28820, 4724, 16254, 5551, 1211, 38688, 23758, 39896, 4117, 5551, 9778, 20292, 8032, 3215, 12610, 7251, 9381, 13546, 14407, 6225, 4117, 3794, 45030, 11242, 37495, 22653, 2423, 1386, 7251, 9381, 13546, 2423, 1145, 20193, 5016, 19913, 14407, 5296, 33456, 3224, 3714, 25513, 2407, 9566, 20666, 5016, 1211, 28671, 32748, 13063, 7649, 11331, 12610, 21542, 1211, 28671, 3714, 27842, 45367, 32748, 13063, 7649, 11331, 12610, 21542, 1211, 28671, 3714, 27842, 45367, 2423, 7649, 23032, 1829, 3555, 45164, 1975, 2655, 9778, 26895, 2655, 14407, 16472, 1975, 8315, 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{"start": 1703.63, "end": 1704.15, "word": " الفكرة", "probability": 0.9207356770833334}, {"start": 1704.15, "end": 1704.95, "word": " زي", "probability": 0.64501953125}, {"start": 1704.95, "end": 1705.47, "word": " لما", "probability": 0.9091796875}, {"start": 1705.47, "end": 1706.17, "word": " الواحدة", "probability": 0.9349365234375}, {"start": 1706.17, "end": 1706.55, "word": " بيجيها", "probability": 0.98681640625}, {"start": 1706.55, "end": 1707.19, "word": " مولود", "probability": 0.9908854166666666}, {"start": 1707.19, "end": 1708.05, "word": " مافيش", "probability": 0.7647298177083334}, {"start": 1708.05, "end": 1708.35, "word": " يكون", "probability": 0.912353515625}, {"start": 1708.35, "end": 1709.05, "word": " عشوائي", "probability": 0.9857421875}, {"start": 1709.05, "end": 1709.37, "word": " يا", "probability": 0.75244140625}, {"start": 1709.37, "end": 1709.85, "word": " ولد", "probability": 0.7305908203125}, {"start": 1709.85, "end": 1710.77, "word": " يا", "probability": 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بظائف", "probability": 0.8232421875}, {"start": 1728.57, "end": 1729.15, "word": " معينة", "probability": 0.9944661458333334}, {"start": 1729.15, "end": 1729.27, "word": " في", "probability": 0.8876953125}, {"start": 1729.27, "end": 1729.79, "word": " الحياة", "probability": 0.9934895833333334}, {"start": 1729.79, "end": 1730.07, "word": " و", "probability": 0.5634765625}, {"start": 1730.07, "end": 1730.55, "word": " هتلاقوا", "probability": 0.96689453125}, {"start": 1730.55, "end": 1731.15, "word": " مركب", "probability": 0.8126627604166666}, {"start": 1731.15, "end": 1731.79, "word": " تاني", "probability": 0.9762369791666666}, {"start": 1731.79, "end": 1732.79, "word": " مختلف", "probability": 0.978515625}, {"start": 1732.79, "end": 1733.21, "word": " ال", "probability": 0.548828125}, {"start": 1733.21, "end": 1733.89, "word": " Trans", "probability": 0.46435546875}, {"start": 1733.89, "end": 1734.31, "word": " و", "probability": 0.85595703125}, {"start": 1734.31, "end": 1734.51, "word": " زي", "probability": 0.8916015625}, {"start": 1734.51, "end": 1734.59, "word": " ما", "probability": 0.98779296875}, {"start": 1734.59, "end": 1734.83, "word": " قلنا", "probability": 0.8816731770833334}, {"start": 1734.83, "end": 1735.31, "word": " العلاقة", "probability": 0.9484049479166666}, {"start": 1735.31, "end": 1735.55, "word": " بين", "probability": 0.98388671875}, {"start": 1735.55, "end": 1736.21, "word": " هدولة", "probability": 0.78118896484375}, {"start": 1736.21, "end": 1736.61, "word": " VR", "probability": 0.64453125}], "temperature": 1.0}, {"id": 73, "seek": 175780, "start": 1737.72, "end": 1757.8, "text": "Diastereomers they are non mirror images كلام سليم ولا لأ؟ مش صورة بعض في المرأة في الخصائص الفيزيائية أكيد و الكيميائية بيختلفوا في كل شيء صاروا مركبين", "tokens": [35, 72, 525, 323, 298, 433, 436, 366, 2107, 8013, 5267, 28242, 10943, 8608, 20292, 2304, 49429, 5296, 10721, 22807, 37893, 20328, 13063, 3660, 45030, 11242, 8978, 9673, 2288, 10721, 3660, 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"end": 2203.42, "word": " يكونوا", "probability": 0.9903971354166666}, {"start": 2203.42, "end": 2203.84, "word": " أبعد", "probability": 0.8860677083333334}, {"start": 2203.84, "end": 2204.3, "word": " كمان", "probability": 0.9765625}, {"start": 2204.3, "end": 2205.56, "word": " واضح؟", "probability": 0.7987060546875}, {"start": 2205.56, "end": 2205.98, "word": " بتظهر", "probability": 0.74658203125}, {"start": 2205.98, "end": 2206.38, "word": " نقطة", "probability": 0.96435546875}, {"start": 2206.38, "end": 2207.0, "word": " الحقيقة", "probability": 0.9669596354166666}, {"start": 2207.0, "end": 2207.98, "word": " في", "probability": 0.9658203125}, {"start": 2207.98, "end": 2208.42, "word": " موضوع", "probability": 0.9940185546875}, {"start": 2208.42, "end": 2208.62, "word": " ال", "probability": 0.89306640625}, {"start": 2208.62, "end": 2210.86, "word": " cyclobutane", "probability": 0.6790313720703125}, {"start": 2210.86, "end": 2211.36, "word": " ان", "probability": 0.576171875}, {"start": 2211.36, "end": 2211.64, "word": " هل", "probability": 0.7186279296875}, {"start": 2211.64, "end": 2211.82, "word": " يا", "probability": 0.62451171875}, {"start": 2211.82, "end": 2212.4, "word": " ترى", "probability": 0.8821614583333334}, {"start": 2212.4, "end": 2212.66, "word": " ال", "probability": 0.78955078125}, {"start": 2212.66, "end": 2214.02, "word": " cyclobutane", "probability": 0.8883056640625}, {"start": 2214.02, "end": 2214.98, "word": " بلانر", "probability": 0.61956787109375}], "temperature": 1.0}, {"id": 94, "seek": 223258, "start": 2215.96, "end": 2232.58, "text": "بهذا الشكل؟ الجواب لو كنا بنطلع على الزوايا تبعته بشكل دقيق هو مش planner هو شوية بيقول عنه puckered يعني مثني شوية لجوا الان بيشبه ايش بهذا الشكل الفراشة ال butterfly", "tokens": [3555, 3224, 15730, 25124, 28820, 22807, 25724, 14407, 3555, 45164, 9122, 8315, 44945, 9566, 1211, 3615, 15844, 6024, 110, 14407, 25528, 6055, 3555, 34268, 3224, 4724, 8592, 28820, 11778, 38436, 4587, 31439, 37893, 31268, 31439, 13412, 2407, 10632, 4724, 1829, 39648, 18871, 3224, 47181, 323, 67, 37495, 22653, 50113, 22653, 13412, 2407, 10632, 5296, 7435, 14407, 2423, 7649, 4724, 1829, 8592, 3555, 3224, 1975, 1829, 8592, 39627, 15730, 25124, 28820, 27188, 2288, 33599, 3660, 2423, 22140], "avg_logprob": -0.2102272796940494, "compression_ratio": 1.5730337078651686, "no_speech_prob": 1.8477439880371094e-06, "words": [{"start": 2215.96, "end": 2216.44, "word": "بهذا", "probability": 0.8404947916666666}, {"start": 2216.44, "end": 2217.14, "word": " الشكل؟", "probability": 0.8600260416666666}, {"start": 2217.14, "end": 2218.64, "word": " الجواب", "probability": 0.8831380208333334}, {"start": 2218.64, "end": 2218.96, "word": " لو", "probability": 0.87646484375}, {"start": 2218.96, "end": 2219.24, "word": " كنا", "probability": 0.9912109375}, {"start": 2219.24, "end": 2219.78, "word": " بنطلع", "probability": 0.8458251953125}, {"start": 2219.78, "end": 2219.96, "word": " على", "probability": 0.857421875}, {"start": 2219.96, "end": 2220.44, "word": " الزوايا", "probability": 0.916259765625}, {"start": 2220.44, "end": 2220.92, "word": " تبعته", "probability": 0.83734130859375}, {"start": 2220.92, "end": 2221.34, "word": " بشكل", "probability": 0.9866536458333334}, {"start": 2221.34, "end": 2221.88, "word": " دقيق", "probability": 0.9944661458333334}, {"start": 2221.88, "end": 2222.34, "word": " هو", "probability": 0.9150390625}, {"start": 2222.34, "end": 2222.74, "word": " مش", "probability": 0.98681640625}, {"start": 2222.74, "end": 2223.22, "word": " planner", "probability": 0.78173828125}, {"start": 2223.22, "end": 2223.78, "word": " هو", "probability": 0.89697265625}, {"start": 2223.78, "end": 2224.24, "word": " شوية", "probability": 0.8943684895833334}, {"start": 2224.24, "end": 2224.58, "word": " بيقول", "probability": 0.652587890625}, {"start": 2224.58, "end": 2224.94, "word": " عنه", "probability": 0.96240234375}, {"start": 2224.94, "end": 2225.46, "word": " puckered", 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"word": " butterfly", "probability": 0.9296875}], "temperature": 1.0}, {"id": 95, "seek": 226184, "start": 2233.64, "end": 2261.84, "text": "واضح؟ فالـ cyclobutane is not a planar molecule مش موجود بهذا الشكل في مستوى واحد لأ من ثاني شوية للداخل عامل زي الفراشة بتعرفوا أنتوا كيف عادة بترسموا الفراشة؟ فأنا لو بدأ أرسم ال cyclobutane بهذا الشكل بارسمه واحد اتنين تلاتة أربع هذه الأربع كربونات", "tokens": [2407, 46958, 5016, 22807, 6156, 6027, 39184, 19474, 996, 325, 1929, 307, 406, 257, 1393, 289, 15582, 37893, 3714, 29245, 23328, 39627, 15730, 25124, 28820, 8978, 3714, 14851, 2407, 7578, 36764, 24401, 5296, 10721, 9154, 38637, 7649, 1829, 13412, 2407, 10632, 24976, 3215, 47283, 1211, 6225, 10943, 1211, 30767, 1829, 27188, 2288, 33599, 3660, 39894, 3615, 28480, 14407, 14739, 2655, 14407, 9122, 33911, 6225, 18513, 3660, 39894, 2288, 38251, 14407, 27188, 2288, 33599, 3660, 22807, 6156, 10721, 8315, 45164, 47525, 10721, 5551, 2288, 38251, 2423, 19474, 996, 325, 1929, 39627, 15730, 25124, 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"word": " عامل", "probability": 0.9957682291666666}, {"start": 2246.78, "end": 2247.1, "word": " زي", "probability": 0.910888671875}, {"start": 2247.1, "end": 2247.64, "word": " الفراشة", "probability": 0.9100341796875}, {"start": 2247.64, "end": 2248.06, "word": " بتعرفوا", "probability": 0.93359375}, {"start": 2248.06, "end": 2248.28, "word": " أنتوا", "probability": 0.614013671875}, {"start": 2248.28, "end": 2248.48, "word": " كيف", "probability": 0.97021484375}, {"start": 2248.48, "end": 2248.84, "word": " عادة", "probability": 0.9864908854166666}, {"start": 2248.84, "end": 2249.48, "word": " بترسموا", "probability": 0.95458984375}, {"start": 2249.48, "end": 2252.14, "word": " الفراشة؟", "probability": 0.864990234375}, {"start": 2252.14, "end": 2254.6, "word": " فأنا", "probability": 0.7967936197916666}, {"start": 2254.6, "end": 2254.76, "word": " لو", "probability": 0.98681640625}, {"start": 2254.76, "end": 2255.0, "word": " بدأ", "probability": 0.596923828125}, {"start": 2255.0, "end": 2255.32, "word": " أرسم", "probability": 0.8800455729166666}, {"start": 2255.32, "end": 2255.5, "word": " ال", "probability": 0.92578125}, {"start": 2255.5, "end": 2256.54, "word": " cyclobutane", "probability": 0.83892822265625}, {"start": 2256.54, "end": 2257.26, "word": " بهذا", "probability": 0.94873046875}, {"start": 2257.26, "end": 2257.6, "word": " الشكل", "probability": 0.9892578125}, {"start": 2257.6, "end": 2258.36, "word": " بارسمه", "probability": 0.815185546875}, {"start": 2258.36, "end": 2259.14, "word": " واحد", "probability": 0.759033203125}, {"start": 2259.14, "end": 2259.58, "word": " اتنين", "probability": 0.895263671875}, {"start": 2259.58, "end": 2260.18, "word": " تلاتة", "probability": 0.923583984375}, {"start": 2260.18, "end": 2260.52, "word": " أربع", "probability": 0.70068359375}, {"start": 2260.52, "end": 2260.7, "word": " هذه", "probability": 0.2183837890625}, {"start": 2260.7, "end": 2261.12, "word": " الأربع", "probability": 0.93212890625}, {"start": 2261.12, "end": 2261.84, "word": " كربونات", "probability": 0.85546875}], "temperature": 1.0}, {"id": 96, "seek": 229010, "start": 2264.22, "end": 2290.1, "text": "cyclobutane is not a planar molecule الان تقريبا المعلومات بتصير تتكرر هنا قولنا زي الاش زي ال butter fly اللي هي الفراشة طب لو بدى احكي عن الcyclobutane معلومات ال cis و ال trans و ال substitution نفس الشيء", "tokens": [1344, 66, 752, 5955, 1929, 307, 406, 257, 1393, 289, 15582, 2423, 7649, 6055, 4587, 16572, 3555, 995, 9673, 30241, 20498, 9307, 39894, 9381, 13546, 6055, 2655, 37983, 2288, 34105, 12174, 12610, 8315, 30767, 1829, 2423, 33599, 30767, 1829, 2423, 5517, 3603, 13672, 1829, 39896, 27188, 2288, 33599, 3660, 23032, 3555, 45164, 47525, 7578, 1975, 5016, 4117, 1829, 18871, 2423, 1344, 66, 752, 5955, 1929, 20449, 1211, 20498, 9307, 2423, 37847, 4032, 2423, 1145, 4032, 2423, 35827, 8717, 36178, 25124, 1829, 38207], "avg_logprob": -0.26694276677556783, "compression_ratio": 1.5561224489795917, "no_speech_prob": 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"probability": 0.16796875}, {"start": 2275.94, "end": 2276.28, "word": " قولنا", "probability": 0.8201497395833334}, {"start": 2276.28, "end": 2276.54, "word": " زي", "probability": 0.88232421875}, {"start": 2276.54, "end": 2277.0, "word": " الاش", "probability": 0.461669921875}, {"start": 2277.0, "end": 2278.1, "word": " زي", "probability": 0.770751953125}, {"start": 2278.1, "end": 2278.24, "word": " ال", "probability": 0.798828125}, {"start": 2278.24, "end": 2278.6, "word": " butter", "probability": 0.80712890625}, {"start": 2278.6, "end": 2280.44, "word": " fly", "probability": 0.275146484375}, {"start": 2280.44, "end": 2280.62, "word": " اللي", "probability": 0.634033203125}, {"start": 2280.62, "end": 2281.04, "word": " هي", "probability": 0.830078125}, {"start": 2281.04, "end": 2282.76, "word": " الفراشة", "probability": 0.958251953125}, {"start": 2282.76, "end": 2283.16, "word": " طب", "probability": 0.892333984375}, {"start": 2283.16, "end": 2283.26, "word": " لو", "probability": 0.98486328125}, {"start": 2283.26, "end": 2283.46, "word": " بدى", "probability": 0.572265625}, {"start": 2283.46, "end": 2283.74, "word": " احكي", "probability": 0.9019775390625}, {"start": 2283.74, "end": 2283.9, "word": " عن", "probability": 0.98876953125}, {"start": 2283.9, "end": 2285.1, "word": " الcyclobutane", "probability": 0.7373046875}, {"start": 2285.1, "end": 2286.48, "word": " معلومات", "probability": 0.9114990234375}, {"start": 2286.48, "end": 2286.7, "word": " ال", "probability": 0.93798828125}, {"start": 2286.7, "end": 2286.92, "word": " cis", "probability": 0.358642578125}, {"start": 2286.92, "end": 2287.12, "word": " و", "probability": 0.439208984375}, {"start": 2287.12, "end": 2287.24, "word": " ال", "probability": 0.76806640625}, {"start": 2287.24, "end": 2287.72, "word": " trans", "probability": 0.591796875}, {"start": 2287.72, "end": 2287.88, "word": " و", "probability": 0.8798828125}, {"start": 2287.88, "end": 2288.0, "word": " ال", "probability": 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اكثر", "probability": 0.8338216145833334}, {"start": 2292.34, "end": 2292.56, "word": " من", "probability": 0.97607421875}, {"start": 2292.56, "end": 2293.16, "word": " موقع", "probability": 0.9900716145833334}, {"start": 2293.16, "end": 2294.34, "word": " لكن", "probability": 0.79345703125}, {"start": 2294.34, "end": 2295.2, "word": " لو", "probability": 0.85693359375}, {"start": 2295.2, "end": 2295.44, "word": " كنت", "probability": 0.9755859375}, {"start": 2295.44, "end": 2295.66, "word": " بده", "probability": 0.509033203125}, {"start": 2295.66, "end": 2295.88, "word": " احط", "probability": 0.8447265625}, {"start": 2295.88, "end": 2296.26, "word": " اول", "probability": 0.862060546875}, {"start": 2296.26, "end": 2296.86, "word": " كلور", "probability": 0.681884765625}, {"start": 2296.86, "end": 2297.9, "word": " العشرة", "probability": 0.6857096354166666}, {"start": 2297.9, "end": 2298.68, "word": " هيدروجين", "probability": 0.77548828125}, {"start": 2298.68, "end": 2299.4, 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0.9332682291666666}, {"start": 2312.06, "end": 2312.26, "word": " من", "probability": 0.970703125}, {"start": 2312.26, "end": 2312.74, "word": " مركب", "probability": 0.9767252604166666}, {"start": 2312.74, "end": 2313.56, "word": " بإمكانكوا", "probability": 0.8960774739583334}, {"start": 2313.56, "end": 2314.24, "word": " تحسبوهم", "probability": 0.87529296875}, {"start": 2314.24, "end": 2314.36, "word": " و", "probability": 0.61962890625}, {"start": 2314.36, "end": 2314.9, "word": " تجمعوهم", "probability": 0.9376627604166666}, {"start": 2314.9, "end": 2315.36, "word": " طب", "probability": 0.807861328125}, {"start": 2315.36, "end": 2315.5, "word": " يا", "probability": 0.94482421875}, {"start": 2315.5, "end": 2315.86, "word": " تورا", "probability": 0.7686360677083334}, {"start": 2315.86, "end": 2316.28, "word": " لو", "probability": 0.97705078125}, {"start": 2316.28, "end": 2316.7, "word": " حكيت", "probability": 0.9884440104166666}, {"start": 2316.7, "end": 2316.9, "word": " عن", "probability": 0.9833984375}, {"start": 2316.9, "end": 2317.3, "word": " الشكل", "probability": 0.950439453125}, {"start": 2317.3, "end": 2317.68, "word": " تبعه", "probability": 0.8907470703125}, {"start": 2317.68, "end": 2317.86, "word": " هل", "probability": 0.946533203125}, {"start": 2317.86, "end": 2318.02, "word": " هو", "probability": 0.9912109375}, {"start": 2318.02, "end": 2318.6, "word": " planner؟", "probability": 0.759521484375}], "temperature": 1.0}, {"id": 98, "seek": 234354, "start": 2319.3, "end": 2343.54, "text": "الجواب لأ مش planner طب هى زى إيش بيعمل الآن تخيلوا هى الحلقة الخماسية شايفينها هى دى اللى أمامكوا حلقة خماسية ولا لأ؟ واحد تانين تلاتة أربعة خمسة هيك بتكون planner لكن هى عاملة بهذا الشكل الآن هذا الشكل لو كنا نعطيه اسم", "tokens": [6027, 7435, 14407, 3555, 5296, 10721, 37893, 31268, 23032, 3555, 8032, 7578, 30767, 7578, 11933, 1829, 8592, 4724, 1829, 25957, 1211, 6024, 48506, 6055, 9778, 26895, 14407, 8032, 7578, 21542, 1211, 28671, 33962, 15042, 3794, 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"probability": 0.88330078125}, {"start": 2322.22, "end": 2322.6, "word": " هى", "probability": 0.6392822265625}, {"start": 2322.6, "end": 2322.9, "word": " زى", "probability": 0.929443359375}, {"start": 2322.9, "end": 2323.14, "word": " إيش", "probability": 0.7635904947916666}, {"start": 2323.14, "end": 2323.6, "word": " بيعمل", "probability": 0.9151611328125}, {"start": 2323.6, "end": 2324.12, "word": " الآن", "probability": 0.560546875}, {"start": 2324.12, "end": 2324.6, "word": " تخيلوا", "probability": 0.976806640625}, {"start": 2324.6, "end": 2324.74, "word": " هى", "probability": 0.755859375}, {"start": 2324.74, "end": 2325.18, "word": " الحلقة", "probability": 0.98388671875}, {"start": 2325.18, "end": 2325.92, "word": " الخماسية", "probability": 0.878662109375}, {"start": 2325.92, "end": 2326.64, "word": " شايفينها", "probability": 0.9552734375}, {"start": 2326.64, "end": 2327.6, "word": " هى", "probability": 0.377197265625}, {"start": 2327.6, "end": 2327.72, "word": " دى", "probability": 0.883056640625}, {"start": 2327.72, "end": 2327.82, "word": " اللى", "probability": 0.990478515625}, {"start": 2327.82, "end": 2328.3, "word": " أمامكوا", "probability": 0.89248046875}, {"start": 2328.3, "end": 2328.64, "word": " حلقة", "probability": 0.9568684895833334}, {"start": 2328.64, "end": 2329.34, "word": " خماسية", "probability": 0.93017578125}, {"start": 2329.34, "end": 2329.54, "word": " ولا", "probability": 0.74267578125}, {"start": 2329.54, "end": 2330.42, "word": " لأ؟", "probability": 0.7853190104166666}, {"start": 2330.42, "end": 2331.02, "word": " واحد", "probability": 0.835205078125}, {"start": 2331.02, "end": 2331.92, "word": " تانين", "probability": 0.6533203125}, {"start": 2331.92, "end": 2332.9, "word": " تلاتة", "probability": 0.92822265625}, {"start": 2332.9, "end": 2333.8, "word": " أربعة", "probability": 0.8670247395833334}, {"start": 2333.8, "end": 2334.72, "word": " خمسة", "probability": 0.9722900390625}, {"start": 2334.72, "end": 2335.38, "word": " هيك", "probability": 0.9140625}, {"start": 2335.38, "end": 2335.98, "word": " بتكون", "probability": 0.983642578125}, {"start": 2335.98, "end": 2336.96, "word": " planner", "probability": 0.8623046875}, {"start": 2336.96, "end": 2337.6, "word": " لكن", "probability": 0.8125}, {"start": 2337.6, "end": 2337.88, "word": " هى", "probability": 0.802001953125}, {"start": 2337.88, "end": 2338.4, "word": " عاملة", "probability": 0.9920247395833334}, {"start": 2338.4, "end": 2339.04, "word": " بهذا", "probability": 0.94921875}, {"start": 2339.04, "end": 2339.58, "word": " الشكل", "probability": 0.990234375}, {"start": 2339.58, "end": 2341.64, "word": " الآن", "probability": 0.6500244140625}, {"start": 2341.64, "end": 2341.9, "word": " هذا", "probability": 0.8720703125}, {"start": 2341.9, "end": 2342.26, "word": " الشكل", "probability": 0.986328125}, {"start": 2342.26, "end": 2342.42, "word": " لو", "probability": 0.97900390625}, {"start": 2342.42, "end": 2342.62, "word": " كنا", "probability": 0.625}, {"start": 2342.62, "end": 2343.1, "word": " نعطيه", "probability": 0.953125}, {"start": 2343.1, "end": 2343.54, "word": " اسم", "probability": 0.879638671875}], "temperature": 1.0}, {"id": 99, "seek": 237214, "start": 2344.36, "end": 2372.14, "text": "بنقول عنه non planner أكيد لكن إله اسم أمركوا شفتوا ضرف مغلف رسالة مفتوح it is like an open envelope فهذا الشكل لو قلنا لكوا عنه planner لأ هتقولوا it is like an open envelope اللي هو ضرف رسالة مفتوح لو كنتوا بتكونوا ترسموه", "tokens": [3555, 1863, 39648, 18871, 3224, 2107, 31268, 5551, 4117, 25708, 44381, 11933, 43761, 24525, 2304, 5551, 29973, 4117, 14407, 13412, 5172, 2655, 14407, 48812, 28480, 3714, 17082, 46538, 12602, 3794, 6027, 3660, 3714, 5172, 2655, 2407, 5016, 309, 307, 411, 364, 1269, 19989, 6156, 3224, 15730, 25124, 28820, 45164, 12174, 1211, 8315, 5296, 4117, 14407, 18871, 3224, 31268, 5296, 10721, 8032, 2655, 39648, 14407, 309, 307, 411, 364, 1269, 19989, 13672, 1829, 31439, 48812, 28480, 12602, 3794, 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2349.04, "end": 2349.52, "word": " شفتوا", "probability": 0.7474365234375}, {"start": 2349.52, "end": 2350.12, "word": " ضرف", "probability": 0.6279296875}, {"start": 2350.12, "end": 2351.6, "word": " مغلف", "probability": 0.93603515625}, {"start": 2351.6, "end": 2352.2, "word": " رسالة", "probability": 0.9674072265625}, {"start": 2352.2, "end": 2352.86, "word": " مفتوح", "probability": 0.9966796875}, {"start": 2352.86, "end": 2354.34, "word": " it", "probability": 0.63525390625}, {"start": 2354.34, "end": 2355.6, "word": " is", "probability": 0.92578125}, {"start": 2355.6, "end": 2356.12, "word": " like", "probability": 0.9580078125}, {"start": 2356.12, "end": 2356.86, "word": " an", "probability": 0.826171875}, {"start": 2356.86, "end": 2357.72, "word": " open", "probability": 0.9326171875}, {"start": 2357.72, "end": 2358.48, "word": " envelope", "probability": 0.84521484375}, {"start": 2358.48, "end": 2360.68, "word": " فهذا", "probability": 0.9654947916666666}, {"start": 2360.68, 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2366.24, "word": " open", "probability": 0.87939453125}, {"start": 2366.24, "end": 2367.98, "word": " envelope", "probability": 0.884765625}, {"start": 2367.98, "end": 2369.02, "word": " اللي", "probability": 0.8994140625}, {"start": 2369.02, "end": 2369.26, "word": " هو", "probability": 0.98291015625}, {"start": 2369.26, "end": 2369.64, "word": " ضرف", "probability": 0.929931640625}, {"start": 2369.64, "end": 2370.1, "word": " رسالة", "probability": 0.9954833984375}, {"start": 2370.1, "end": 2370.38, "word": " مفتوح", "probability": 0.9970703125}, {"start": 2370.38, "end": 2370.76, "word": " لو", "probability": 0.8544921875}, {"start": 2370.76, "end": 2371.08, "word": " كنتوا", "probability": 0.9943033854166666}, {"start": 2371.08, "end": 2371.32, "word": " بتكونوا", "probability": 0.7888997395833334}, {"start": 2371.32, "end": 2372.14, "word": " ترسموه", "probability": 0.9744140625}], "temperature": 1.0}, {"id": 100, "seek": 239839, "start": 2372.91, "end": 2398.39, "text": "بشكل فراغي open envelope مش envelope ال .. الظرف تبع الرسالة و الموضوع it is like an open envelope لو بدي ارسمه بهذا الشكل بارسمه فال Cyclopropane is a planar Cyclobutane لأ Cyclopentane لأ الان لو انتقلنا بعد هيك لل Cyclohexane", "tokens": [3555, 8592, 28820, 6156, 2288, 5718, 118, 1829, 1269, 19989, 37893, 19989, 2423, 4386, 6024, 116, 28480, 6055, 3555, 3615, 34892, 3794, 6027, 3660, 4032, 9673, 2407, 11242, 45367, 309, 307, 411, 364, 1269, 19989, 45164, 4724, 16254, 1975, 2288, 38251, 3224, 39627, 15730, 25124, 28820, 4724, 9640, 38251, 3224, 6156, 6027, 10295, 3474, 404, 1513, 1929, 307, 257, 1393, 289, 10295, 66, 752, 5955, 1929, 5296, 10721, 10295, 3474, 404, 317, 1929, 5296, 10721, 2423, 7649, 45164, 16472, 2655, 4587, 1211, 8315, 39182, 39896, 4117, 24976, 10295, 66, 752, 675, 87, 1929], "avg_logprob": -0.2774268477521044, "compression_ratio": 1.601010101010101, "no_speech_prob": 0.0, "words": [{"start": 2372.91, "end": 2373.45, "word": "بشكل", "probability": 0.90283203125}, 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{"start": 2381.63, "end": 2382.07, "word": " it", "probability": 0.70361328125}, {"start": 2382.07, "end": 2382.27, "word": " is", "probability": 0.90966796875}, {"start": 2382.27, "end": 2382.55, "word": " like", "probability": 0.95361328125}, {"start": 2382.55, "end": 2382.81, "word": " an", "probability": 0.8271484375}, {"start": 2382.81, "end": 2383.33, "word": " open", "probability": 0.94140625}, {"start": 2383.33, "end": 2384.01, "word": " envelope", "probability": 0.89208984375}, {"start": 2384.01, "end": 2384.39, "word": " لو", "probability": 0.94921875}, {"start": 2384.39, "end": 2384.55, "word": " بدي", "probability": 0.740234375}, {"start": 2384.55, "end": 2385.05, "word": " ارسمه", "probability": 0.84149169921875}, {"start": 2385.05, "end": 2385.51, "word": " بهذا", "probability": 0.924560546875}, {"start": 2385.51, "end": 2385.93, "word": " الشكل", "probability": 0.991943359375}, {"start": 2385.93, "end": 2386.77, "word": " بارسمه", "probability": 0.9044189453125}, 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لاحظوا نفس الحلقة شايفين كيف أنا مسكها؟", "tokens": [6027, 3555, 1863, 11622, 9957, 383, 21, 39, 21, 4724, 1211, 7649, 2288, 44381, 2423, 39184, 34, 88, 66, 752, 675, 87, 1929, 32239, 3794, 3714, 20292, 4117, 1829, 20498, 4724, 1211, 7649, 2288, 37893, 4724, 1211, 7649, 2288, 23032, 3555, 8032, 995, 9122, 33911, 4724, 1829, 1863, 29245, 3215, 22807, 3714, 43020, 7251, 1863, 29245, 3215, 15844, 5551, 4117, 49115, 9154, 39896, 19986, 3660, 39896, 19986, 3660, 4724, 1829, 39648, 18871, 11296, 21871, 21871, 39896, 19986, 3660, 4724, 2304, 3615, 1863, 7578, 3714, 43020, 8717, 2304, 3794, 4117, 3224, 39627, 15730, 25124, 28820, 20193, 5016, 19913, 14407, 8717, 36178, 21542, 1211, 28671, 13412, 995, 33911, 9957, 9122, 33911, 41850, 47524, 4117, 11296, 22807], "avg_logprob": -0.22160325750060703, "compression_ratio": 1.7235023041474655, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2424.28, "end": 2425.1, "word": "البنزين", "probability": 0.91455078125}, {"start": 2425.1, "end": 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أنا", "probability": 0.767578125}, {"start": 2448.62, "end": 2449.48, "word": " مسكها؟", "probability": 0.8665771484375}], "temperature": 1.0}, {"id": 103, "seek": 247352, "start": 2450.0, "end": 2473.52, "text": "الان هذا الشكل اللي انا ماسكه يشبه ماذا؟ القارب او الزورق بسمي انا هيئة القارب boat confirmation boat confirmation موجود عندكم ربما بهذا المكان شايفينه؟", "tokens": [6027, 7649, 23758, 25124, 28820, 13672, 1829, 1975, 8315, 19446, 3794, 4117, 3224, 7251, 8592, 3555, 3224, 3714, 45636, 995, 22807, 25062, 9640, 3555, 1975, 2407, 6024, 110, 13063, 4587, 4724, 38251, 1829, 1975, 8315, 39896, 19986, 3660, 25062, 9640, 3555, 6582, 21871, 6582, 21871, 3714, 29245, 23328, 43242, 24793, 12602, 3555, 15042, 39627, 15730, 9673, 41361, 13412, 995, 33911, 9957, 3224, 22807], "avg_logprob": -0.13012695545330644, "compression_ratio": 1.6, "no_speech_prob": 0.0, "words": [{"start": 2450.0, "end": 2450.44, "word": "الان", "probability": 0.8037109375}, {"start": 2450.44, "end": 2450.96, 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شايفينه", "probability": 0.923828125}, {"start": 2963.0, "end": 2964.28, "word": " المُركّب؟", "probability": 0.8729248046875}, {"start": 2964.28, "end": 2964.4, "word": " إيش", "probability": 0.8050130208333334}, {"start": 2964.4, "end": 2965.6, "word": " اسمه؟", "probability": 0.9100341796875}, {"start": 2965.6, "end": 2966.04, "word": " مثل", "probability": 0.9931640625}, {"start": 2966.04, "end": 2967.08, "word": " سايكلوبروبين", "probability": 0.8897705078125}, {"start": 2967.08, "end": 2968.3, "word": " اعملوله", "probability": 0.8814453125}, {"start": 2968.3, "end": 2969.16, "word": " مونو", "probability": 0.8562825520833334}, {"start": 2969.16, "end": 2970.18, "word": " إكلورينايشن", "probability": 0.9128146701388888}], "temperature": 1.0}, {"id": 125, "seek": 298893, "start": 2971.47, "end": 2988.93, "text": "وDichlorination وشوفوا كم ناتج بيطلع عندكم طبعا بتكونوا تنتبهوا ان الchlorination ممكن يجي على المثل او على الحلقة بدي كل النواتج الممكنة وهنا كل النواتج الممكنة هذا بحاجة انكوا تتدربوا بشكل جيد", "tokens": [2407, 35, 480, 6746, 2486, 4032, 8592, 38688, 14407, 9122, 2304, 8717, 9307, 7435, 4724, 1829, 9566, 1211, 3615, 43242, 24793, 23032, 3555, 3615, 995, 39894, 30544, 14407, 6055, 29399, 3555, 3224, 14407, 16472, 2423, 11439, 284, 2486, 3714, 43020, 7251, 7435, 1829, 15844, 9673, 12984, 1211, 1975, 2407, 15844, 21542, 1211, 28671, 4724, 16254, 28242, 28239, 2407, 9307, 7435, 9673, 43020, 3660, 37037, 8315, 28242, 28239, 2407, 9307, 7435, 9673, 43020, 3660, 23758, 4724, 5016, 26108, 3660, 16472, 4117, 14407, 6055, 2655, 3215, 25513, 14407, 4724, 8592, 28820, 10874, 25708], "avg_logprob": -0.2455842410740645, "compression_ratio": 1.8186813186813187, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2971.47, "end": 2972.47, "word": "وDichlorination", "probability": 0.552685546875}, {"start": 2972.47, "end": 2972.97, "word": " وشوفوا", "probability": 0.810302734375}, {"start": 2972.97, "end": 2973.21, "word": " كم", "probability": 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المثل", "probability": 0.7413736979166666}, {"start": 2979.15, "end": 2979.71, "word": " او", "probability": 0.8212890625}, {"start": 2979.71, "end": 2980.09, "word": " على", "probability": 0.8896484375}, {"start": 2980.09, "end": 2981.51, "word": " الحلقة", "probability": 0.97900390625}, {"start": 2981.51, "end": 2981.75, "word": " بدي", "probability": 0.61767578125}, {"start": 2981.75, "end": 2982.01, "word": " كل", "probability": 0.432861328125}, {"start": 2982.01, "end": 2982.65, "word": " النواتج", "probability": 0.875732421875}, {"start": 2982.65, "end": 2983.33, "word": " الممكنة", "probability": 0.9420572916666666}, {"start": 2983.33, "end": 2984.37, "word": " وهنا", "probability": 0.47613525390625}, {"start": 2984.37, "end": 2984.57, "word": " كل", "probability": 0.970703125}, {"start": 2984.57, "end": 2985.03, "word": " النواتج", "probability": 0.9432373046875}, {"start": 2985.03, "end": 2985.53, "word": " الممكنة", "probability": 0.9803059895833334}, {"start": 2985.53, "end": 2986.03, "word": " هذا", "probability": 0.78076171875}, {"start": 2986.03, "end": 2986.75, "word": " بحاجة", "probability": 0.9920654296875}, {"start": 2986.75, "end": 2987.23, "word": " انكوا", "probability": 0.8098958333333334}, {"start": 2987.23, "end": 2987.83, "word": " تتدربوا", "probability": 0.91494140625}, {"start": 2987.83, "end": 2988.31, "word": " بشكل", "probability": 0.9934895833333334}, {"start": 2988.31, "end": 2988.93, "word": " جيد", "probability": 0.987060546875}], "temperature": 1.0}, {"id": 126, "seek": 300604, "start": 2989.62, "end": 3006.04, "text": "و تعرفوا أنواع الهيدروجينز اللي موجودة و تحددوا كام ناتج بيطلع عندهم من ال monochlorination و ال dichlorination ترسموهم بعد ما ترسموهم انتبهوا إذا في أشكال متشابهة انه ما تكرروهاش وبهيك بننهي اليوم ان شاء الله", "tokens": [2407, 37279, 28480, 14407, 14739, 14407, 3615, 2423, 3224, 25708, 2288, 29245, 9957, 11622, 13672, 1829, 3714, 29245, 23328, 3660, 4032, 6055, 24401, 3215, 14407, 9122, 10943, 8717, 9307, 7435, 4724, 1829, 9566, 1211, 3615, 43242, 16095, 9154, 2423, 1108, 8997, 6746, 2486, 4032, 2423, 10390, 6746, 2486, 6055, 2288, 38251, 2407, 16095, 39182, 19446, 6055, 2288, 38251, 2407, 16095, 16472, 2655, 3555, 3224, 14407, 11933, 15730, 8978, 5551, 8592, 4117, 6027, 44650, 8592, 16758, 3224, 3660, 16472, 3224, 19446, 6055, 37983, 2288, 2407, 11296, 8592, 46599, 3224, 1829, 4117, 44945, 1863, 3224, 1829, 45595, 20498, 16472, 13412, 16606, 21984], "avg_logprob": -0.20173267267718173, "compression_ratio": 1.6971153846153846, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2989.62, "end": 2989.82, "word": "و", "probability": 0.35693359375}, {"start": 2989.82, "end": 2990.32, "word": " تعرفوا", "probability": 0.87939453125}, {"start": 2990.32, "end": 2990.68, "word": " أنواع", "probability": 0.9345703125}, {"start": 2990.68, "end": 2991.44, "word": " الهيدروجينز", "probability": 0.7777622767857143}, {"start": 2991.44, "end": 2991.58, "word": " اللي", "probability": 0.643798828125}, {"start": 2991.58, "end": 2992.32, "word": " موجودة", "probability": 0.9873046875}, {"start": 2992.32, "end": 2992.7, "word": " و", "probability": 0.64599609375}, {"start": 2992.7, "end": 2993.44, "word": " تحددوا", "probability": 0.8753662109375}, {"start": 2993.44, "end": 2994.0, "word": " كام", "probability": 0.7275390625}, {"start": 2994.0, "end": 2994.36, "word": " ناتج", "probability": 0.9871419270833334}, {"start": 2994.36, "end": 2994.72, "word": " بيطلع", "probability": 0.90146484375}, {"start": 2994.72, "end": 2994.98, "word": " عندهم", "probability": 0.6868896484375}, {"start": 2994.98, "end": 2995.12, "word": " من", "probability": 0.939453125}, {"start": 2995.12, "end": 2995.22, "word": " ال", "probability": 0.9609375}, {"start": 2995.22, "end": 2996.04, "word": " monochlorination", "probability": 0.65142822265625}, {"start": 2996.04, "end": 2996.2, "word": " و", "probability": 0.93701171875}, {"start": 2996.2, "end": 2996.26, "word": " ال", "probability": 0.80517578125}, {"start": 2996.26, "end": 2997.0, "word": " dichlorination", "probability": 0.7526041666666666}, {"start": 2997.0, "end": 2997.8, "word": " ترسموهم", "probability": 0.9169921875}, {"start": 2997.8, "end": 2998.36, "word": " بعد", "probability": 0.70947265625}, {"start": 2998.36, "end": 2998.52, "word": " ما", "probability": 0.916015625}, {"start": 2998.52, "end": 2999.44, "word": " ترسموهم", "probability": 0.9890625}, {"start": 2999.44, "end": 3000.34, "word": " انتبهوا", "probability": 0.9478515625}, {"start": 3000.34, "end": 3000.56, "word": " إذا", "probability": 0.768310546875}, {"start": 3000.56, "end": 3000.72, "word": " في", "probability": 0.83251953125}, {"start": 3000.72, "end": 3001.16, "word": " أشكال", "probability": 0.9620361328125}, {"start": 3001.16, "end": 3002.18, "word": " متشابهة", "probability": 0.963671875}, {"start": 3002.18, "end": 3002.64, "word": " انه", "probability": 0.534423828125}, {"start": 3002.64, "end": 3002.7, "word": " ما", "probability": 0.6611328125}, {"start": 3002.7, "end": 3003.66, "word": " تكرروهاش", "probability": 0.8272298177083334}, {"start": 3003.66, "end": 3004.7, "word": " وبهيك", "probability": 0.7799072265625}, {"start": 3004.7, "end": 3005.18, "word": " بننهي", "probability": 0.906982421875}, {"start": 3005.18, "end": 3005.5, "word": " اليوم", "probability": 0.967041015625}, {"start": 3005.5, "end": 3005.72, "word": " ان", "probability": 0.473876953125}, {"start": 3005.72, "end": 3005.98, "word": " شاء", "probability": 0.970703125}, {"start": 3005.98, "end": 3006.04, "word": " الله", "probability": 0.94873046875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 3006.89125, "duration_after_vad": 2895.673749999989}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-FzTT8Q4Xi8.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-FzTT8Q4Xi8.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d9813d57e650675655a72aaf7efb7332b1a84d41
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-FzTT8Q4Xi8.srt
@@ -0,0 +1,1542 @@
+1
+00:00:18,780 --> 00:00:24,830
+بسم الله الرحمن الرحيم. بعد ما اتكلمنا المرة الماضية
+
+2
+00:00:24,830 --> 00:00:29,410
+عن السكريات المنفردة، اتعرفنا عليها، الـ mono
+
+3
+00:00:29,410 --> 00:00:34,750
+-saccharides. الآن بدنا نتكلم عن الـ di-saccharides.
+
+4
+00:00:34,750 --> 00:00:39,930
+طبعا اللي بنقصده احنا بـ di-saccharides أنه جزيئين
+
+5
+00:00:39,930 --> 00:00:43,910
+من الـ mono-saccharides يتحدوا مع بعض و بيعملوا
+
+6
+00:00:43,910 --> 00:00:51,360
+إيش؟ di-saccharide. الآن مش دائماً، مش دائماً، مش دائماً
+
+7
+00:00:51,360 --> 00:00:54,820
+هدول الجزيئين اللي بدهم يتحدوا مع بعض بيكونوا زي
+
+8
+00:00:54,820 --> 00:01:00,140
+بعض، يعني يوم بدأ أحكي أنا عن دايسا كرايد ممكن أجيب
+
+9
+00:01:00,140 --> 00:01:06,260
+نفس الجزيئين تماماً بكل محتوياتهم. طبعاً بالتأكيد الـ
+
+10
+00:01:06,260 --> 00:01:09,680
+stereo chemistry تكون نفس الشيء تماماً ويعملوا
+
+11
+00:01:09,680 --> 00:01:14,040
+دايسا كرايد، وممكن أجيب جزيئين مختلفين ويعملوا
+
+12
+00:01:14,040 --> 00:01:19,820
+دايسا كرايد. فمش ضروري، مش ضروري أن الـ disaccharide
+
+13
+00:01:19,820 --> 00:01:26,240
+يكون مكوّن من الجزيئين نفسهم تماماً، واضح؟ يعني
+
+14
+00:01:26,240 --> 00:01:30,560
+ممكن يكون فعلاً من نفس الجزيئين مكوّن disaccharide
+
+15
+00:01:30,560 --> 00:01:36,920
+وممكن يكون من جزيئين مختلفين، وهذا اللي هنشوفه لما
+
+16
+00:01:36,920 --> 00:01:45,550
+نستعرض بعض الـ disaccharides بشكل عام، ويعني جداً أول
+
+17
+00:01:45,550 --> 00:01:51,710
+دايسا كارايد بدنا نستعرضه المالتوز، واضح؟
+
+18
+00:01:51,710 --> 00:01:57,970
+المالتوز، الآن هذا الديسا كارايد مكوّن من سكرين
+
+19
+00:01:57,970 --> 00:02:03,070
+جلوكوز، لكن فيهم اختلاف في الـ stereo chemistry.
+
+20
+00:02:03,470 --> 00:02:08,830
+فيهم اختلاف في الـ stereo chemistry. واحد منهم، واحد
+
+21
+00:02:08,830 --> 00:02:14,730
+منهم alpha glucose، والثاني منهم beta glucose. الآن
+
+22
+00:02:14,730 --> 00:02:19,390
+اللي بتذكروا معنا، قلنا احنا أن الـ alpha والـ beta
+
+23
+00:02:19,390 --> 00:02:24,930
+sugars بصيروا لما نسكر آخر carbon اللي سميناها الـ
+
+24
+00:02:24,930 --> 00:02:29,300
+anomeric carbon، ونعمل في حالة السكريات هذه الميزات
+
+25
+00:02:29,300 --> 00:02:35,240
+الكربونات، الـ fifth chiral center. فإذا الـ OH كانت
+
+26
+00:02:35,240 --> 00:02:40,020
+للأسفل على هذا الكربون تحديدا، بنقول هذا السكر
+
+27
+00:02:40,020 --> 00:02:46,120
+alpha، وإذا كانت للأعلى beta. الآن هذا الـ maltose لو
+
+28
+00:02:46,120 --> 00:02:50,760
+بتطلع عليه أنا، هيكون من سكر متصل في الـ anomeric
+
+29
+00:02:50,760 --> 00:02:54,560
+carbon. لاحظوا أنا تركيزي على أي كربون؟ الـ anomeric
+
+30
+00:02:54,560 --> 00:02:59,820
+carbon. نكون معلمينها، إلى أساسها. هذه السكرين المتحدين
+
+31
+00:02:59,820 --> 00:03:07,180
+الآن، اتطلعوا على واحد منهم، الـ oxygen فيه alpha.
+
+32
+00:03:07,180 --> 00:03:18,840
+واضح؟ الثاني منهم الـ oxygen فيه beta. واضح؟ فالملتوز
+
+33
+00:03:18,840 --> 00:03:24,740
+بيكون في هذه الحالة مكون من alpha-Glucose مع beta
+
+34
+00:03:24,740 --> 00:03:29,660
+-Glucose. هي دول اتنين قبل ما يتصلوا مع بعض، هذا
+
+35
+00:03:29,660 --> 00:03:35,440
+بهذا الشكل. كان OH، كان alpha-Glucose. هذا كان beta
+
+36
+00:03:35,440 --> 00:03:41,320
+-Glucose. فاتنين اتصلوا مع بعض من خلال موقع أربعة.
+
+37
+00:03:41,320 --> 00:03:45,060
+لما ناخد الترقيم واحد، اثنين، ثلاثة، أربعة. هذا الموقع
+
+38
+00:03:46,020 --> 00:03:49,540
+أربعة، اتحدوا من خلال هذه الـ oxygen اللي في موقع
+
+39
+00:03:49,540 --> 00:03:55,920
+أربعة، عملوا رابطة، واضح؟ فصار عندنا المركب مكوّن من
+
+40
+00:03:55,920 --> 00:04:03,040
+alpha ومن beta-D-جلوكوز. وعشان هيك لما بدنا نسميه
+
+41
+00:04:03,040 --> 00:04:09,900
+ممكن أنه نقرأ الاسم تبعه، هتحسوا أنه مش صعب، هو ممكن
+
+42
+00:04:09,900 --> 00:04:15,120
+تتخيلوا مركب beta جلوكوز، لو حطيت على موقع أربعة مثل
+
+43
+00:04:15,120 --> 00:04:19,960
+شو كنتوا هتسموه؟ four مثل beta جلوكوز
+
+44
+00:04:23,450 --> 00:04:29,690
+الاسم الـ Beta في آخر الكلام: Beta-D-Glucopyranose.
+
+45
+00:04:29,690 --> 00:04:35,170
+مش سمّيناه لأنه جلوكوز، سكر حلقة سداسية،
+
+46
+00:04:35,170 --> 00:04:40,030
+Glucopyranose، و D، و Beta لأن هذه موجودة في الوضع
+
+47
+00:04:40,030 --> 00:04:45,410
+beta. الآن هذا على موقع أربعة، هي على موقع أربعة من
+
+48
+00:04:45,410 --> 00:04:50,950
+خلال الـ oxygen متحد بإيش؟ بـ alpha-D-Glucopyranose.
+
+49
+00:04:51,620 --> 00:04:57,800
+واضح الفكرة؟ فيذكر الاسم العام على موقع أربعة من
+
+50
+00:04:57,800 --> 00:05:05,690
+هذا السكر، إيش موجود عنده على موقع أربعة؟ alpha D
+
+51
+00:05:05,690 --> 00:05:08,890
+جلوكوبايرانوس. طبعاً اتصاله من خلال الـ O، عشان هيك
+
+52
+00:05:08,890 --> 00:05:13,490
+كتبنا O. فاللي بده يفهم الاسم، الاسم مش صعب، أنه هاي
+
+53
+00:05:13,490 --> 00:05:18,290
+المركب اللي عندي beta جلوكوبايرانوس على موقع
+
+54
+00:05:18,290 --> 00:05:22,650
+أربعة منه، إيش؟ إيجي نعتبرها بين قوسين alpha
+
+55
+00:05:22,650 --> 00:05:28,230
+Glucopyranose. فهذا سكر المالتوز ببساطة. هذه الأشياء
+
+56
+00:05:28,230 --> 00:05:34,030
+بيبقى تفهموا فيها الأفكار العامة. فالملتوز من سكرين
+
+57
+00:05:34,030 --> 00:05:38,350
+جلوكوز، لكن اثنين مش alpha alpha ولا beta beta.
+
+58
+00:05:38,350 --> 00:05:46,590
+alpha مع beta. الآن بيجيني سكر ثاني، السيلوبيوز.
+
+59
+00:05:46,590 --> 00:05:55,730
+السيلوبيوز متحد من سكرين متفقين تماماً، beta جلوكو
+
+60
+00:05:55,730 --> 00:06:00,550
+بيتانوز مع beta جلوكوبيرانوز. واضح؟ ولذلك لو أنا
+
+61
+00:06:00,550 --> 00:06:07,550
+بدأ أطلع على هذا السكر، هذا beta ولا لا؟ beta، وعلى
+
+62
+00:06:07,550 --> 00:06:14,780
+هذا السكر، هذه أيضاً beta. فلما بنسميه نسبة لهذا beta
+
+63
+00:06:14,780 --> 00:06:20,740
+D Glucopyranose متحد من موقع أربعة. واحد، اثنين، ثلاثة،
+
+64
+00:06:20,740 --> 00:06:25,880
+أربعة، متحد من موقع أربعة من خلال الـ oxygen، الـ beta
+
+65
+00:06:25,880 --> 00:06:31,160
+D-glucopyranose. واضح؟ يعني هذا كأننا بنقول beta D
+
+66
+00:06:31,160 --> 00:06:36,660
+-glucopyranose يحمل على موقع أربعة beta D
+
+67
+00:06:36,660 --> 00:06:42,100
+-glucopyranose. واضح الفكرة؟ فالـ cellobiose بيكون من
+
+68
+00:06:42,100 --> 00:06:50,330
+سكرين متماثلين تماماً. لاحظوا قد إيش نسبة الخلاف اللي
+
+69
+00:06:50,330 --> 00:06:56,450
+بتعمل، يعني مركبات مختلفة، يعني أنا بحكي عن
+
+70
+00:06:56,450 --> 00:07:02,330
+Glucopyranose و Glucopyranose، وبحكي عن هذا beta
+
+71
+00:07:02,330 --> 00:07:06,870
+في الحالتين، بس التانية مرة beta ومرة إيش؟ alpha.
+
+72
+00:07:07,710 --> 00:07:14,870
+خلاف بسيط جداً، بس chiral center واحد. الآن بعد شوية
+
+73
+00:07:14,870 --> 00:07:19,770
+هتكتشفوا أن هذا الخلاف البسيط جداً في chiral center
+
+74
+00:07:19,770 --> 00:07:26,510
+الواحد، بيتبع خلاف كبير جداً جداً جداً في الخواص بعد
+
+75
+00:07:26,510 --> 00:07:31,760
+ذلك للمركبات. يعني لما ييجوا الجزيئات الـ
+
+76
+00:07:31,760 --> 00:07:35,200
+disaccharides بدهم يعملوا polysaccharides. هاي
+
+77
+00:07:35,200 --> 00:07:38,540
+disaccharide، وخلينا نعتبر هاي كمان disaccharide.
+
+78
+00:07:38,540 --> 00:07:43,120
+هذا كان من beta و beta، وهذا كان من beta و alpha.
+
+79
+00:07:43,120 --> 00:07:47,660
+الآن اللي كان من alpha و beta، المالتوز، بيعمل جزئ
+
+80
+00:07:47,660 --> 00:07:56,080
+كبير اسمه نشا أو glycogen، اللي هي تخزين أو أماكن
+
+81
+00:07:56,080 --> 00:07:59,380
+تخزين الـ carbohydrates سواء في النبات أو في
+
+82
+00:07:59,380 --> 00:08:03,400
+الحيوان. وهذه بتدوب في المية، وبيقدر البني آدم
+
+83
+00:08:03,400 --> 00:08:07,000
+يهضمها. يعني البني آدم لما بياكل النشويات بيقدر
+
+84
+00:08:07,000 --> 00:08:12,180
+بسهولة يحللها للسكريات الأولية بتاعتها، أكيد. الآن
+
+85
+00:08:12,180 --> 00:08:16,060
+اللي مكوّن من الـ beta والـ beta، هيجي يعمل الـ
+
+86
+00:08:16,060 --> 00:08:20,600
+cellulose، هيعمل الخشب. البني آدم بيقدرش يهضم الخشب.
+
+87
+00:08:20,600 --> 00:08:27,570
+الآن هيجي تقوله شو الفرق؟ بين أساس الخشب وأساس
+
+88
+00:08:27,570 --> 00:08:33,270
+النشا. أساس الخشب cellobiose، واتحد وأعطاني
+
+89
+00:08:33,270 --> 00:08:39,110
+cellulose، وأساس النشا المالتوز وأعطاني starch.
+
+90
+00:08:39,110 --> 00:08:46,230
+واضح؟ فقط مختلفين هدول الاثنين بواحد من السكريات،
+
+91
+00:08:46,230 --> 00:08:49,770
+جلوكوز جلوكوز، صح؟ جلوكوز جلوكوز، بس هذا beta و
+
+92
+00:08:49,770 --> 00:08:55,240
+beta، هذا beta و alpha. تخيلوا كيف اختلاف بسيط في الـ
+
+93
+00:08:55,240 --> 00:09:00,740
+stereochemistry بيقدر الاختلاف كبير بعد هيك في
+
+94
+00:09:00,740 --> 00:09:05,480
+الخواص وفي الاستفادة من المركبات. بيجينا سكر
+
+95
+00:09:05,480 --> 00:09:15,960
+الحليب، الـ lactose. اللاكتوز أيضاً فيه جلوكوز، لكن فيه
+
+96
+00:09:15,960 --> 00:09:20,900
+جالاكتوز. يعني هدول الـ stereo chemical centers
+
+97
+00:09:20,900 --> 00:09:26,320
+اتغير فيهم أكتر. كل الفروقات بينهم هي فروقات إيش؟
+
+98
+00:09:26,320 --> 00:09:30,500
+لحتى لها الـ stereo chemistry. يعني هذه الوحدة مش
+
+99
+00:09:30,500 --> 00:09:36,340
+beta جلوكوز، في هذه الحالة alpha جلوكوز متحد مع
+
+100
+00:09:36,340 --> 00:09:42,300
+beta جالاكتوز. عشانك لو ذكرنا الاسم العام، هتلاحظوا
+
+101
+00:09:42,300 --> 00:09:47,260
+في الآخر alpha D Glucopyranose. هي الـ alpha D
+
+102
+00:09:47,260 --> 00:09:54,480
+Glucopyranose، وشايفين أنها alpha. الآن متحد من موقع
+
+103
+00:09:54,480 --> 00:10:01,340
+أربعة الـ beta D Galactopyranose. طبعاً بنكتب beta D
+
+104
+00:10:01,340 --> 00:10:07,450
+Galactopyranose. الـ yl اللي هي بصفته أصبح مجموعة زي
+
+105
+00:10:07,450 --> 00:10:14,330
+ما بقول مثل إيثيل بروبيل، الـ yl لأنه أصبح مجموعة. واضحة
+
+106
+00:10:14,330 --> 00:10:20,630
+الفكرة؟ هذا الـ lactose. طبعاً بيجي صاحبنا، مين
+
+107
+00:10:20,630 --> 00:10:27,330
+صاحبنا؟ السكروز. ما حدش يقول عن السكروز العدو
+
+108
+00:10:27,330 --> 00:10:33,030
+تبعنا، يعني في ناس دائماً متطرفين في الحكم على اللي
+
+109
+00:10:33,030 --> 00:10:37,090
+هي هذه الأشياء، كل هذه السكريات وكل حتى الدهون
+
+110
+00:10:37,090 --> 00:10:40,730
+بتلزم للإنسان، بس المشكلة مش أن الإنسان ياخد
+
+111
+00:10:40,730 --> 00:10:45,340
+سكريات وياخد دهون، المشكلة أنه ياخدها بإفراط. يعني
+
+112
+00:10:45,340 --> 00:10:49,160
+الإنسان بحاجة للسكريات، بحاجة للدهون بالتأكيد،
+
+113
+00:10:49,160 --> 00:10:53,940
+بحاجة للكوليسترول، بحاجة لكل شيء، لكن الإفراط في أي
+
+114
+00:10:53,940 --> 00:10:58,840
+شغل هو اللي بيعمل عندنا إيش؟ المشكلة. الآن لو إجينا
+
+115
+00:10:58,840 --> 00:11:02,640
+اتطلعنا على السكروز اللي هو السكر اللي إحنا
+
+116
+00:11:02,640 --> 00:11:07,540
+بنستعمله، هتلاحظوا مرة ثانية في عندي alpha
+
+117
+00:11:07,540 --> 00:11:11,680
+-Glucopyranose. هاي alpha، هذه شايفينها؟
+
+118
+00:11:14,950 --> 00:11:19,930
+طالما الـ OH أسفل، إذا هذه إيش؟ alpha. لكن المرة هذه
+
+119
+00:11:19,930 --> 00:11:27,030
+الاتحاد تبعه مش من موقع أربعة، هو متحد بـ fructose.
+
+120
+00:11:27,030 --> 00:11:33,390
+واضح؟ هو متحد بـ fructose، والـ fructose keto sugar.
+
+121
+00:11:33,390 --> 00:11:38,370
+لما أخذنا السكريات، قلنا إن في عندنا الـ aldoses من الـ
+
+122
+00:11:38,370 --> 00:11:43,920
+aldehydes و ketoses. للـ fructose keto sugar، ولما بيسكر
+
+123
+00:11:43,920 --> 00:11:50,240
+بيسكر على السكر الخماسي، السكر الخماسي، furanose، ومن
+
+124
+00:11:50,240 --> 00:11:56,020
+الـ furanose متحد من موقع إيش؟ واحد. واضح؟ الآن هذا
+
+125
+00:11:56,020 --> 00:12:04,630
+الـ furanose لما بتطلع فيه، beta، واضح؟ إذا هذا beta.
+
+126
+00:12:04,630 --> 00:12:09,270
+عشانك هتلاقوا الاسم تبعه، اعتبروا أن هذا هو الأصل،
+
+127
+00:12:09,270 --> 00:12:14,010
+وهذه هي الـ yl، المجموعة اللي جاية على الأصل، واضح؟
+
+128
+00:12:14,010 --> 00:12:19,950
+فهتلاحظوا beta D fructofuranoseyl، طبعاً
+
+129
+00:12:19,950 --> 00:12:26,210
+furanoseyl لأنه جاي إيش؟ مجموعة متحدة مع الـ alpha D
+
+130
+00:12:26,210 --> 00:12:33,150
+Glucopyranose. ما كتبناش هنا by pyranoside، كتبنا by pyranoside، ليش؟
+
+131
+00:12:33,150 --> 00:12:37,790
+لأن الاتحاد تم هنا من موقع واحد، لاحظوا في
+
+132
+00:12:37,790 --> 00:12:41,270
+السكريات اللي قبل شوية، لما كنا نيجي نعمل هذا السكر،
+
+133
+00:12:41,270 --> 00:12:45,150
+الاتحاد تم من أي موقع؟ أربعة. هنا الاتحاد تم من
+
+134
+00:12:45,150 --> 00:12:53,080
+موقع واحد. فإذا هذه الرابطة، بطلت OH، صارت O-Carbon.
+
+135
+00:12:53,080 --> 00:12:58,340
+معنى ذلك هذه الرابطة إيش بدها تكون؟ Glycosidic
+
+136
+00:12:58,340 --> 00:13:02,280
+bond. واضح؟ عشان Glycosidic bond عشان تكون
+
+137
+00:13:02,280 --> 00:13:08,400
+Glycoside، هنحط إيش؟ Glucopyranoside. لاحظتوا هنا
+
+138
+00:13:08,400 --> 00:13:12,640
+الكلمة؟ pyranoside. لو رجعتوا على الأسماء اللي قبل
+
+139
+00:13:12,640 --> 00:13:19,240
+كان حط Glucopyranose، لأن هذه كانت تكون OH. في كل
+
+140
+00:13:19,240 --> 00:13:23,280
+اللي قبل، هذه كانت OH، Glucopyranose، سواء كان
+
+141
+00:13:23,280 --> 00:13:28,860
+alpha أو beta. لكن هنا بطلت OH، صار الاتحاد من عندها
+
+142
+00:13:28,860 --> 00:13:33,420
+وعشان هيك صارت هذه الرابطة Glycosidic bond، فقال
+
+143
+00:13:33,420 --> 00:13:38,300
+Glucopyranoside، Glucopyranoside. فالحقيقة
+
+144
+00:13:40,010 --> 00:13:46,150
+السكر اللي فيه two glycosidic bonds هو سكر إيش؟
+
+145
+00:13:46,150 --> 00:13:50,210
+الـ سكروز. انتبهوا لو كانوا بيسألكوا multiple choice
+
+146
+00:13:50,210 --> 00:13:58,670
+الآن هذه الرابطة carbon و carbon، هذه glycosidic
+
+147
+00:13:58,670 --> 00:14:04,230
+bond ولا لأ؟ وهذه الرابطة glycosidic bond. فلما
+
+148
+00:14:04,230 --> 00:14:10,320
+نيجي نطلع إحنا حقيقة على الـ سكروز، كم glycosidic bond
+
+149
+00:14:10,320 --> 00:14:18,940
+فيه؟ اثنتين. لو رجعنا اتطلعنا على السكريات
+
+150
+00:14:18,940 --> 00:14:25,100
+اللي قبل، هنا كم glycosidic bond؟ واحدة. ما حدش يقول
+
+151
+00:14:25,100 --> 00:14:29,520
+هذه glycosidic bond. ليش؟ لأن الـ glycosidic bond
+
+152
+00:14:29,520 --> 00:14:34,700
+اللي بتتكون على الكايرال سنتر الأخير، على هذه، مش
+
+153
+00:14:34,700 --> 00:14:40,650
+على هذا الموقع أربعة. واضح؟ يعني مش أي O كربون
+
+154
+00:14:40,650 --> 00:14:47,850
+glycosidic bond. الـ glycosidic bond مرتبطة بأي؟ بأي
+
+155
+00:14:47,850 --> 00:14:52,630
+كربون؟ بالـ anomeric carbon اللي كانت أساساً aldehyde.
+
+156
+00:14:52,630 --> 00:14:56,350
+واضح؟ ولذلك هذه glycosidic bond، بس هذه مش
+
+157
+00:14:56,350 --> 00:15:01,390
+glycosidic bond. واضح؟ فلو أنا إجيت على الـ lactose،
+
+158
+00:15:01,390 --> 00:15:08,540
+فيه one glycosidic bond. لو رجعت على السيلوبيوز، على
+
+159
+00:15:08,540 --> 00:15:13,640
+سبيل المثال، برضه أي واحدة anomeric carbon، كل سكر
+
+160
+00:15:13,640 --> 00:15:17,780
+فيه two anomeric carbon، مظبوط ولا لأ؟ هذه فيها
+
+161
+00:15:17,780 --> 00:15:24,200
+glycosidic bond. هذه فيها، لذلك في السيلوبيوز في
+
+162
+00:15:24,200 --> 00:15:30,950
+عنده one glycosidic bond. هذه، لأ. واضحة الفكرة؟ يعني
+
+163
+00:15:30,950 --> 00:15:34,970
+أنا عندي two anomeric carbons، مين فيهم glycosidic
+
+164
+00:15:34,970 --> 00:15:40,630
+bond؟ هذه الـ O، H، glycosidic، هذه، آه، واضحة الفكرة؟
+
+165
+00:15:40,630 --> 00:15:44,950
+فدائماً لما بدنا نعرف كم glycosidic bond، نرجع على
+
+166
+00:15:44,950 --> 00:15:53,670
+الـ ملتوز مثلاً، هذه الـ anomeric carbons. الآن لو
+
+167
+00:15:53,670 --> 00:15:57,690
+إجينا سألنا هذه glycosidic bond؟ O، H، هذه
+
+168
+00:15:59,540 --> 00:16:07,100
+glycosidic bond. فالملتوز والسيلوبيوز واللاكتوز،
+
+169
+00:16:07,100 --> 00:16:11,380
+هدول فيهم one glycosidic bond، والثانية عادية.
+
+170
+00:16:11,380 --> 00:16:16,740
+ع
+
+223
+00:20:43,810 --> 00:20:47,710
+قلنا عنه بيتا، وبيتا يعني خلينا نركز احنا على
+
+224
+00:20:47,710 --> 00:20:52,810
+الملتوز، الملتوز كان من ألفا وبيتا جلوكوز مكون
+
+225
+00:20:52,810 --> 00:20:57,790
+واضح؟ والسيلوبيوز من بيتا وبيتا جلوكوز الآن
+
+226
+00:20:57,790 --> 00:21:02,470
+هدول لما بيجوا بيعملوا بوليمر كبير، لما بيعملوا
+
+227
+00:21:02,470 --> 00:21:06,750
+بوليمر كبير بيكون هم الوحدة الأساسية المتكررة في
+
+228
+00:21:06,750 --> 00:21:12,930
+البوليمر، بيعطونا الـstarch أو النشا في حالة ما
+
+229
+00:21:12,930 --> 00:21:18,570
+نتكلم عن إيش؟ عن الملتوز، في حالة ما نتكلم عن
+
+230
+00:21:18,570 --> 00:21:22,990
+السيلوبايوز، بيعطينا السليلوز، واضح؟ فالملتوز
+
+231
+00:21:22,990 --> 00:21:29,130
+بيعطيني إيش؟ النشا، starch، السيلوبيوز بيعطيني
+
+232
+00:21:29,130 --> 00:21:36,470
+السليلوز، الخشب، واضح؟ بوليمر كبير طبعاً، لاحظوا
+
+233
+00:21:36,470 --> 00:21:40,990
+عاد حسب الـpolymer اللي بتكون، يعني يوم ما نحكي عن
+
+234
+00:21:40,990 --> 00:21:45,550
+polymer يعني عدد كبير من الشغلات، هتلاحظوا في علم
+
+235
+00:21:45,550 --> 00:21:50,250
+الـpolymerization هذا العدد ممكن يكون 300 وحدة
+
+236
+00:21:50,250 --> 00:21:56,200
+ممكن يكون ألف، ممكن يكون ثلاثمائة، تمام؟ حسب طريقة
+
+237
+00:21:56,200 --> 00:21:59,420
+الارتباط اللي موجودة في هذا العدد، وحسب عدد
+
+238
+00:21:59,420 --> 00:22:03,760
+الجزيئات أو الوحدات المكونة له، الآن وحدة الـstarch
+
+239
+00:22:03,760 --> 00:22:08,300
+هي إيش؟ الـmaltose هذه الوحدة اللي مكونة من سكرين
+
+240
+00:22:08,300 --> 00:22:13,160
+حسب كمية الأشياء المتصلة، بيصير عندك نوع الـpolymer
+
+241
+00:22:13,160 --> 00:22:16,340
+عشان أنتم بالـplastic بتلاحظوا في عندكم أنواع
+
+242
+00:22:16,340 --> 00:22:21,460
+كتيرة، في النايلون في عندكم أنواع كتيرة، هذا بيصير
+
+243
+00:22:21,460 --> 00:22:25,860
+يدخل فيه جانب الصناعة، أنه قد إيش العدد اللي خلينا
+
+244
+00:22:25,860 --> 00:22:31,640
+يتحد تقريباً، يعمل polymer، هالخليه 300 جزء، ووحدة الـ
+
+245
+00:22:31,640 --> 00:22:37,640
+polymer 3000، 2000، واضح الفكرة؟ الآن نفس الفكرة من
+
+246
+00:22:37,640 --> 00:22:43,350
+الملتوز، هلاحظ أنه في إن الـstarch لو حللته
+
+247
+00:22:43,350 --> 00:22:47,990
+بيعطيني ملتوز، الملتوز لو حللته بيعطيني جلوكوز،
+
+248
+00:22:47,990 --> 00:22:52,830
+لكن جلوكوز ألفا
+
+249
+00:22:53,990 --> 00:22:58,410
+وبيتا جلوكوز، لكن هذه الوحدة المتكررة، وحدة الملتوز
+
+250
+00:22:58,410 --> 00:23:03,350
+اعملوا منها عدد كبير، الآن لاحظوا أن النشا مكون من
+
+251
+00:23:03,350 --> 00:23:08,230
+شغلتين، من أميلوز بنسبة 20%، والباقي تقريباً
+
+252
+00:23:08,230 --> 00:23:15,200
+أميلوبكتين، إيش بيفرقوا هدول الشغلتين؟ بعدد الجزيئات
+
+253
+00:23:15,200 --> 00:23:19,980
+المكونة له، وطريقة الاتحاد، يعني الأميلوز في
+
+254
+00:23:19,980 --> 00:23:25,840
+جلوكوز units، عادة بيكون عددها ما يقارب بين خمسين
+
+255
+00:23:25,840 --> 00:23:30,260
+إلى ثلاثمائة جلوكوز unit، لكن أهم شيء بيميزها أن هي
+
+256
+00:23:30,260 --> 00:23:37,970
+موجودة في إيش؟ بسلاسل بدون تفرعات، واضح؟ سلاسل بهذا
+
+257
+00:23:37,970 --> 00:23:42,830
+الشكل بدون ما يصير فيها تفرعات، العدد تبع الـ
+
+258
+00:23:42,830 --> 00:23:47,410
+glucose units بيكون ما بين خمسين إلى ثلاثمائة
+
+259
+00:23:47,410 --> 00:23:52,770
+glucose unit، والاتحاد زي ما أنتم عارفين، رقم
+
+260
+00:23:52,770 --> 00:23:58,270
+أربعة من هون وبتحد من واحد مع الجزء الثاني، يعني
+
+261
+00:23:58,270 --> 00:24:02,190
+احنا لما كنا نتكلم عن المالتوز، كنا هنا في عندنا
+
+262
+00:24:02,190 --> 00:24:07,550
+الاتحاد مع أربعة أو سابع، واحد، أو كذا، الآن لما
+
+263
+00:24:07,550 --> 00:24:11,150
+بتعمل polymer، بيجي التحد منها، يعني لو أنتم
+
+264
+00:24:11,150 --> 00:24:16,630
+تذكرتوا المالتوز، مش كانت هذه تكون فيها قوى، لما
+
+265
+00:24:16,630 --> 00:24:20,930
+نحكي عن الملتوز لوحده، الآن بيصير يتحد من هذه
+
+266
+00:24:20,930 --> 00:24:23,690
+القوى، عشان يعمل الـpolymer، يعني القوى اللي
+
+267
+00:24:23,690 --> 00:24:28,610
+كانت ما تروكة فاضية، بيصير يتحد من خلالها مع موقع
+
+268
+00:24:28,610 --> 00:24:33,130
+أربعة من وحدة ملتوز ثانية، بطلع عنده جزء كبير
+
+269
+00:24:33,130 --> 00:24:34,210
+بنسميه إيش؟
+
+270
+00:24:37,020 --> 00:24:43,020
+الأميلوز، الأميلوز هذا أحد مكونات النشا، الآن النشا
+
+271
+00:24:43,020 --> 00:24:49,260
+في مكون ثاني، الأميلوبكتين، الأميلوبكتين فيه ما بين
+
+272
+00:24:49,260 --> 00:24:53,460
+ثلاثمائة إلى خمسة آلاف جلوكوز units، يعني الجلوكوز
+
+273
+00:24:53,460 --> 00:24:59,860
+units اللي في عددها أكبر، لكن أهم شغل فيه is
+
+274
+00:24:59,860 --> 00:25:06,920
+highly branched، واضح؟ يعني الأميلوز سلسلة، الـamylobectin
+
+275
+00:25:06,920 --> 00:25:13,440
+فيه تفرعات، يعني تقريباً، لاحظوا الأميلوز بين 300
+
+276
+00:25:13,440 --> 00:25:17,220
+إلى 5000 جلوكوز units، is a highly branched
+
+277
+00:25:17,220 --> 00:25:21,660
+molecule، أو highly branched molecule chains with
+
+278
+00:25:21,660 --> 00:25:24,360
+consecutive one four links، شوفنا كيف one four
+
+279
+00:25:24,360 --> 00:25:28,520
+links، الارتباط الـaverage يعني كل مجموعة حوالي
+
+280
+00:25:28,520 --> 00:25:35,070
+خمسة وعشرين إلى ثلاثين وحدة، وبعدين بيجي تفرع، 25 ل 30
+
+281
+00:25:35,070 --> 00:25:41,110
+وتفرع بيصير الجزء أشماله highly branched، واضح؟
+
+282
+00:25:41,110 --> 00:25:48,470
+فواضح أن جزء الأميلوبكتين أكبر من الأميلوز، و
+
+283
+00:25:48,470 --> 00:25:55,150
+بنفس الوقت اللي بيميزه التفرعات، واضح؟ فالأميلوز
+
+284
+00:25:55,150 --> 00:26:02,220
+is a chain molecule، الأميلوبكتين هو جزئ عالي، جزئ
+
+285
+00:26:02,220 --> 00:26:11,520
+فيه تفرعات كتيرة، طبعاً هذه كل أشكال تقريبية بتوضح
+
+286
+00:26:11,520 --> 00:26:20,720
+لنا كيف بيتكونوا هذول الجزيئات، الآن لو جينا من الـ
+
+287
+00:26:20,720 --> 00:26:30,470
+amylose أيضاً، غير النشا بمكونه، يعني من الملتوز كان
+
+288
+00:26:30,470 --> 00:26:35,130
+فيه عنده الـstarch اللي هو مكون من amylose و
+
+289
+00:26:35,130 --> 00:26:40,470
+amylobectin، أيضاً من الملتوز، في عنده الجليكوجين، الـ
+
+290
+00:26:40,470 --> 00:26:45,470
+starch مكان تخزين الـcarbohydrates في النبات،
+
+291
+00:26:45,470 --> 00:26:49,410
+الجليكوجين مكان تخزين الـcarbohydrates في
+
+292
+00:26:49,410 --> 00:26:55,750
+الحيوانات، برضه هو فيه جلوكوز units، لكن حوالي مائة
+
+293
+00:26:55,750 --> 00:27:00,590
+ألف جلوكوز unit، لاحظوا العدد في الجليكوجين
+
+294
+00:27:00,590 --> 0:27:06,810
+الجليكوجين بيزيد بشكل كبير، وbranched، يعني كل ما بين كل
+
+295
+00:27:06,810 --> 00:27:11,010
+ثمانية إلى 12 جلوكوز unit، خلينا هيك نتخيل، هتلاحظوا
+
+296
+00:27:11,010 --> 00:27:17,930
+أن في عندكم إيش؟ الجزء هذا، الجليكوجين بيكون أيضاً
+
+297
+00:27:17,930 --> 00:27:24,090
+highly branched، الآن الجليكوجين بيجي من الجلوكوز
+
+298
+00:27:24,090 --> 00:27:30,130
+اللي بيمتص من أمعاء، produced from glucose that is
+
+299
+00:27:30,130 --> 00:27:35,930
+absorbed from intestines into the blood، الآن إيش
+
+300
+00:27:35,930 --> 00:27:41,060
+وظيفته هذا الجليكوجين؟ يمكن مر عليكم في بيولوجيا، اللي
+
+301
+00:27:41,060 --> 00:27:45,260
+هو توازن السكر، helps maintain the glucose balance
+
+302
+00:27:45,260 --> 00:27:49,660
+واضح؟ يعني إذا في عندي جلوكوز زيادة، بيجي وبتخزن
+
+303
+00:27:49,660 --> 00:27:54,340
+وين؟ في الجليكوجين، بدخل ضمن البوليمر، الآن إذا
+
+304
+00:27:54,340 --> 00:28:00,770
+الجسم نقص عليه الجلوكوز، بصير هذا نفسه يفرز أو يعطي
+
+305
+00:28:00,770 --> 00:28:07,930
+الجسم وحدات جلوكوز، واضح الفكرة؟ يعني هو كأنه هاي
+
+306
+00:28:07,930 --> 00:28:12,450
+جزيئات الجلوكوز، بتقدروا تتخيلوها بتمتص من المعدة
+
+307
+00:28:12,450 --> 00:28:16,030
+المفروض، لازم لحرق الأكل، الناس اللي بياكلوا كتير
+
+308
+00:28:16,030 --> 00:28:21,510
+okay، بنجمع هذه الجزيئات، هيعملنا إيش؟ جليكوجين
+
+309
+00:28:21,510 --> 00:28:25,790
+وخزانة، الآن بعد هيك صار الإنسان عنده ناقص في
+
+310
+00:28:25,790 --> 00:28:31,010
+السكر، جد ما فيه ناقص بيصير يطلع له جلوكوز، واضح؟
+
+311
+00:28:31,010 --> 00:28:36,090
+واضحة الفكرة العامة، خليني أقول العامة جداً
+
+312
+00:28:36,090 --> 00:28:42,890
+لجليكوجين، الآن لو طلعنا على السليلوز، الـ
+
+313
+00:28:42,890 --> 00:28:48,830
+cellulose هو الـpolymer اللي جاي من السيلوبيوز
+
+314
+00:28:48,830 --> 00:28:55,010
+اللي بيعمل الخشب، يعني النشا والجليكوجين جايين من
+
+315
+00:28:55,010 --> 00:29:01,430
+وين؟ من الملتوز، من الملتوز، لكن السليلوز جاي من
+
+316
+00:29:01,430 --> 00:29:03,410
+السيلوبيوز،
+
+317
+00:29:05,410 --> 00:29:11,210
+بيتا وبيتا sugar، فالـcellulose is an unbranched
+
+318
+00:29:11,210 --> 00:29:16,210
+polymer، مستقيم ما فيه branches of glucose
+
+319
+00:29:16,210 --> 00:29:20,110
+joined by one four beta glycosidic bonds، كل
+
+320
+00:29:20,110 --> 00:29:29,390
+هالكلام شفناه، لاحظوا معي كيف فرق في الأساس بسيط
+
+321
+00:29:29,390 --> 00:29:37,500
+جداً، أنه هذا من سيلوبيوز، هذا من ملتوز، السيلوبيوز
+
+322
+00:29:37,500 --> 00:29:42,260
+والملتوز متحدين في بيتا جلوكوز، لكن السكر الثاني
+
+323
+00:29:42,260 --> 00:29:46,820
+في كل واحدة واحد منهم، واحد ألفا، واحد بيتا، يعني
+
+324
+00:29:46,820 --> 00:29:51,120
+خلينا نقول هنا في عندنا بيتا وبيتا، نفس الشيء في
+
+325
+00:29:51,120 --> 00:29:57,340
+السكرين، الآن في المالتوز هذا ألفا، في السيلوبيوز
+
+326
+00:29:58,430 --> 00:30:03,590
+هذا بيتا، فهذا ألفا بيتا، هذا بيتا بيتا، الآن هذا
+
+327
+00:30:03,590 --> 00:30:07,690
+بيصير ملتوز وبيعمل لي نشا وجليكوجين، هذا بيصير
+
+328
+00:30:07,690 --> 00:30:12,970
+سليلوز وسيلوبيوز وبيعمله السليلوز، الآن
+
+329
+00:30:12,970 --> 00:30:16,990
+الإنسان بيقدر يهضم النشا، بيقدر يهضم الجليكوجين،
+
+330
+00:30:16,990 --> 00:30:22,670
+ما بيقدرش يهضم السليلوز، السليلوز واضح، فالـ
+
+331
+00:30:22,670 --> 00:30:26,830
+humans and other animals they digest starch and
+
+332
+00:30:26,830 --> 00:30:32,880
+glycogen، بيقدروا يهضموا النشا والجليكوجين، الآن
+
+333
+00:30:32,880 --> 00:30:37,360
+الحيوانات
+
+334
+00:30:37,360 --> 00:30:42,610
+والنمل، ممكن تقولوا النمل صار أقوى من الإنسان يعني
+
+335
+00:30:42,610 --> 00:30:46,550
+هو النمل بيقدر يهضم الخشب والإنسان ما بيقدرش،
+
+336
+00:30:46,550 --> 00:30:52,030
+معنى ذلك النمل أقوى من الإنسان، هي المشكلة أنه
+
+337
+00:30:52,030 --> 00:30:57,150
+كمان مش النمل اللي بيخمض، أو مش الحيوانات المجترة
+
+338
+00:30:57,150 --> 00:31:01,570
+اللي بتخمض، لأ، بكتيريا موجودة جوا أمعاها، هذه
+
+339
+00:31:01,570 --> 00:31:05,050
+البكتيريا اللي جوا أمعاها بتفرز اللي هو
+
+340
+00:31:08,560 --> 00:31:14,060
+الأنزيمات اللي هي الـbeta glycosidase اللي بتساعد
+
+341
+00:31:14,060 --> 00:31:19,960
+على عملية إيش؟ أن تقدر تهضم الخشب وتستفيد منه، واضح؟
+
+342
+00:31:19,960 --> 00:31:27,760
+فمابين بكتيريا contain beta glycosidase، دائماً إذا
+
+343
+00:31:27,760 --> 00:31:33,510
+شوفتوا هذه النهاية إيش؟ هذا الأنزيم، oxidase و
+
+344
+00:31:33,510 --> 00:31:37,870
+reductase و glycosidase، and they can hydrolyze
+
+345
+00:31:37,870 --> 00:31:42,810
+يعني يفككوا السليلوز، فلو احنا قلنا لكم أن الـ
+
+346
+00:31:42,810 --> 00:31:46,090
+humans can hydrolyze cellulose
+
+347
+00:31:48,210 --> 00:31:52,250
+واضح؟ لكن في بكتيريا كتير بتقدر تعمل هذا الكلام،
+
+348
+00:31:52,250 --> 00:31:55,990
+هذه موجودة في الـtermites اللي هو النمل الأبيض، و
+
+349
+00:31:55,990 --> 00:31:59,510
+الـruminants اللي هي الحيوانات المجترة اللي
+
+350
+00:31:59,510 --> 00:32:03,050
+بتلاقوها مستعدة تاكل الـ... إيش؟ زي الجمل وزي...
+
+351
+00:32:03,050 --> 00:32:08,250
+آه اللي بتاكل الخشب، فبكتيريا في معدتها بتقدر تدخل
+
+352
+00:32:08,250 --> 00:32:13,450
+على هذا الخشب وتحله لوحدات السكر، بحيث أنه النمل
+
+353
+00:32:13,450 --> 00:32:18,430
+الأبيض أو الحيوانات هذه المجترة تقدر تستفيد منه أو
+
+354
+00:32:18,430 --> 00:32:22,310
+من السكر اللي موجود فيه، لكن الإنسان ما بيقدرش
+
+355
+00:32:22,310 --> 00:32:26,730
+يهضمه، آخر
+
+356
+00:32:26,730 --> 00:32:33,090
+شغلة، آخر شغلة بنحكيها بالنسبة لهذا الجزء، أنه في
+
+357
+00:32:33,090 --> 00:32:37,870
+عندي بعض الـsugars يمكن أن ينزع منها أكسجين، هذه
+
+358
+00:32:37,870 --> 00:32:42,850
+بتفيدنا لما بدنا ندرس الـnuclear acid اللي هي
+
+359
+00:32:42,850 --> 00:32:49,090
+الأحماض النووية، ومنها بصير اسمها deoxy sugars، يعني
+
+360
+00:32:49,090 --> 00:32:53,470
+لاحظوا هذا الـsugar لما يكون فيه الـoxygen، وسكر
+
+361
+00:32:53,470 --> 00:32:58,610
+من خمس كربونات، ribose، تمام؟ لما نشيل منه oxygen
+
+362
+00:32:58,610 --> 00:33:02,870
+منها، يعني في الأصل كان في عنده OH، لو شيلنا منه
+
+363
+00:33:02,870 --> 00:33:09,490
+oxygen، إيش بيصير اسمه؟ deoxy، deoxy يعني منزوع، اه
+
+364
+00:33:09,490 --> 00:33:14,570
+لحظة، ميزة... ميزة رجاء في الكلمات، عشانكم احنا
+
+365
+00:33:14,570 --> 00:33:22,080
+بنقول اتعبوا شوية، يعني لو أتينا قلنا لكم، ضايق، زيادة
+
+366
+00:33:22,080 --> 00:33:27,800
+يعني اثنين، اه، لكن دي منزوعة زي ما كنا نقول
+
+367
+00:33:27,800 --> 00:33:31,760
+hydrogenation, dehydrogenation, hydration,
+
+368
+00:33:32,600 --> 00:33:38,260
+dehydrogenation, halogenation, dehydrogenation، فالـ
+
+369
+00:33:38,260 --> 00:33:43,820
+دي بتاعتنا اللي هو العكس، فهذا الـbeta دي دي
+
+370
+00:33:43,820 --> 00:33:48,860
+oxyribofuranose، طيب ليش فيورانوز؟ لأنه من حلقة
+
+371
+00:33:48,860 --> 00:33:53,520
+خماسية، هو الـsugar تبع الـDNA هو عبارة عن ribose
+
+372
+00:33:53,520 --> 00:33:58,720
+نزعت منه الـoxygen، ولو كان الـribose اللي فيه الـ
+
+373
+00:33:58,720 --> 00:34:05,400
+oxygen بيعمل لنا الـRNA، Ribonucleic Acid، لما يكون الـ
+
+374
+00:34:05,400 --> 00:34:09,800
+DNA Deoxyribonucleic Acid، واضح؟
+
+375
+00:34:12,560 --> 00:34:19,700
+الكلام عام عن اللي هي الـdicarates وعن الـ
+
+376
+00:34:19,700 --> 00:34:26,210
+polymers اللي بتكونوا منهم، خلينا يعني نبدأ نعطي
+
+377
+00:34:26,210 --> 00:34:31,310
+فكرة عامة، ليش أنا محتاجها، الآن مقارنة مع
+
+378
+00:34:31,310 --> 00:34:37,050
+البروتينات اللي بدنا ناخدها في الفصل الأخير إن شاء
+
+379
+00:34:37,050 --> 00:34:41,910
+الله، اللي هو الـamino acids والـpeptides والـ
+
+380
+00:34:41,910 --> 00:34:48,210
+proteins، زي ما لاحظتوا، يمكن أهم شغلة في الـ
+
+381
+00:34:48,210 --> 00:34:52,290
+polysaccharides، أهم شغلة في الـpolysaccharides أن
+
+382
+00:34:52,290 --> 00:34:57,650
+هم polymers، ماذا يعني polymers؟ يعني لما أقول
+
+383
+00:34:57,650 --> 00:35:04,150
+النشا، إيش الوحدة تبعته؟ هتقولوا لي ملتوز
+
+384
+00:35:04,150 --> 00:35:10,390
+البيسكريدي الملتوز، تمام؟ لو قلت مثلاً السليلوز،
+
+385
+00:35:10,390 --> 00:35:15,870
+بوليمر كبير، إيش الوحدة تبعته؟ السيلوبيوز، ولذلك
+
+386
+00:35:15,870 --> 00:35:23,490
+الـpolysaccharides يمكن التعامل معها بيكون أسهل كتير
+
+387
+00:35:23,490 --> 00:35:28,790
+من التعامل مع البروتينات، ليش؟ لأن الـ
+
+388
+00:35:28,790 --> 00:35:32,930
+polysaccharides عندي وحدة وبتتكرر، يعني كأن
+
+389
+00:35:32,930 --> 00:35:37,110
+الإنسان بيقدر يقول عنهم أن they are real polymers
+
+390
+00:35:37,110 --> 00:35:43,710
+واضح؟ الـpolymers مكون من إيش؟ مونومرات، تتحد تصير
+
+391
+00:35:43,710 --> 00:35:47,910
+دايمرات، ترايمرات، تترامرات، في الآخر إيش؟
+
+392
+00:35:
+
+445
+00:41:01,570 --> 00:41:07,910
+glycine, alanine, tryptophan, cysteine كذا كذا
+
+446
+00:41:07,910 --> 00:41:14,270
+هتلاحظوا أنه مطلوب مننا أن نحدد الترتيب تبع ال amino
+
+447
+00:41:14,270 --> 00:41:17,690
+acids، ولذلك الـ proteins لو الإنسان بده يستعمل
+
+448
+00:41:17,690 --> 00:41:23,010
+الكلام بدقة أكثر، they are macro molecules جزيئات
+
+449
+00:41:23,010 --> 00:41:30,490
+كبيرة، macro molecules جزيئات كبيرة، أكثر منهم إيش
+
+450
+00:41:30,490 --> 00:41:39,610
+polymers، they are macro molecules أكثر منهم بوليمر
+
+451
+00:41:39,610 --> 00:41:46,310
+طبعا فيهم نوعا ما شيء مشترك بيخلي بعض الناس يقولوا
+
+452
+00:41:46,310 --> 00:41:54,670
+ممكن تجاوزا نعتبر الـ protein بوليمر، ليش؟ لأنه لو
+
+453
+00:41:54,670 --> 00:42:00,010
+أنا اتطلعت على الهيكل تبعه اللي بيتكرر، هلاحظ أنه
+
+454
+00:42:00,010 --> 00:42:05,960
+عبارة عن N-C-C، الآن هذه الوحدة بتتكرر في البروتين
+
+455
+00:42:05,960 --> 00:42:12,760
+بعدها N-C-C=O، بعدها N-C-C=O
+
+456
+00:42:12,760 --> 00:42:19,220
+هتقولولي مش ناقص غير إيش؟ تكتب هذول to the N، طب
+
+457
+00:42:19,220 --> 00:42:25,870
+ليش مش قادر أكتبهم؟ لأن كل amino acid فيها R group
+
+458
+00:42:25,870 --> 00:42:33,210
+مختلفة، يعني هذه مرة H، هذه مرة CH3، هذه مرة CH2SH
+
+459
+00:42:33,210 --> 00:42:40,430
+فلو بتطلع على الهيكل الأساسي للذرات لبروتين N-C-C
+
+460
+00:42:40,430 --> 00:42:45,870
+=O هو مكرر، لكن لو طلعت على هذه المجموعة
+
+461
+00:42:46,670 --> 00:42:51,530
+مش مكررة، بناء على ذلك، لو هذا مثلا كان بيبتايد، هذا
+
+462
+00:42:51,530 --> 00:42:55,810
+بيبتايد مكون من كم amino acid؟ من ثلاثة، هتعلم أن
+
+463
+00:42:55,810 --> 00:43:00,570
+هذا اسمه جلايسين، هذا اسمه ألانين، هذا اسمه سيستين
+
+464
+00:43:00,570 --> 00:43:05,450
+حيصير أقول هذا Glycine, Alanine, Cysteine، هيكون بفرق
+
+465
+00:43:05,450 --> 00:43:08,390
+عن Alanine, Glycine, Cysteine، من نفس الثلاثة
+
+466
+00:43:08,390 --> 00:43:14,810
+فانفعلكوا لما نصير نحكي عن تلاتمية، فالبروتين بوجهة
+
+467
+00:43:14,810 --> 00:43:19,870
+النظر اللي بده يتطلع على الهيكل الأساسي هو كأنه بوليمر
+
+468
+00:43:19,870 --> 00:43:25,170
+متكرر في N-C-C=O، N-C-C=O
+
+469
+00:43:25,170 --> 00:43:28,950
+لكن لما نيجي نلاحظ أن هذه المجموعة اللي هنا
+
+470
+00:43:28,950 --> 00:43:36,740
+اختلفت، بتبطل بوليمر، ولذلك الـ polymer ما بنعدش الـ 300
+
+471
+00:43:36,740 --> 00:43:40,680
+وحدة ولا الـ 5000 وحدة تبعته، بس الـ protein بدي
+
+472
+00:43:40,680 --> 00:43:45,860
+أعرف، وبدي أعلم يوم أقول هذا protein كذا، بيذكر لل
+
+473
+00:43:45,860 --> 00:43:54,170
+5000 وحدة مرتبين، ونفس الشيء هيتكرر معاكم، مهم في الـ
+
+474
+00:43:54,170 --> 00:43:58,670
+nucleic acids، عشان هيك في الشفرة الوراثية وغيرها
+
+475
+00:43:58,670 --> 00:44:02,570
+وغيرها، هتلاحظوا أن الإنسان بيختلف عن الثاني، و
+
+476
+00:44:02,570 --> 00:44:07,270
+الشغل بتختلف عن الثاني، أنه بدي أذكر الأشياء مرتبة
+
+477
+00:44:08,550 --> 00:44:18,550
+كذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+478
+00:44:18,550 --> 00:44:19,230
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+479
+00:44:19,230 --> 00:44:19,250
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+480
+00:44:19,250 --> 00:44:19,450
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+481
+00:44:19,450 --> 00:44:22,470
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+482
+00:44:22,470 --> 00:44:25,070
+وكذا
+
+483
+00:44:25,690 --> 00:44:30,730
+جزيئات كبيرة، أكثر من أن نسميها Polymers، ونقدر
+
+484
+00:44:30,730 --> 00:44:35,170
+نكتب شغلته دي، أنا الآن حيصير درسنا القادم سهل، اللي
+
+485
+00:44:35,170 --> 00:44:39,730
+بده يدرس الـ proteins، إيش أساسهم؟ إذا أول شيء بدنا
+
+486
+00:44:39,730 --> 00:44:45,310
+نتعلم على الـ amino acids، بعدين الـ amino acids بتتحد
+
+487
+00:44:45,310 --> 00:44:48,890
+وبتعملوا الـ protein، نتعلم كيف نوجد الـ sequence، و
+
+488
+00:44:48,890 --> 00:44:53,390
+كيف نحضر الـ protein لو بدنا، لكن حيكون إن شاء الله
+
+489
+00:44:53,390 --> 00:44:58,410
+درسنا القادم على الوحدة المكونة للبروتين اللي هي
+
+490
+00:44:58,410 --> 00:45:00,370
+عبارة عن إيش؟  الامينو
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-FzTT8Q4Xi8_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-FzTT8Q4Xi8_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..82a5200cf7ab9e0e4c85df14d592edc3c2b33801
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-FzTT8Q4Xi8_postprocess.srt
@@ -0,0 +1,1960 @@
+1
+00:00:18,780 --> 00:00:24,830
+بسم الله الرحمن الرحيمبعد ما اتكلمنا المرة الماضية
+
+2
+00:00:24,830 --> 00:00:29,410
+عن السكريات المنفردة اتعرفنا عليها ال mono
+
+3
+00:00:29,410 --> 00:00:34,750
+-saccharides الان بدنا نتكلم عن ال di-saccharides
+
+4
+00:00:34,750 --> 00:00:39,930
+طبعا اللي بنقصده احنا ب di-saccharides انه جزيئين
+
+5
+00:00:39,930 --> 00:00:43,910
+من ال mono-saccharides يتحدوا مع بعض و بيعملوا
+
+6
+00:00:43,910 --> 00:00:51,360
+ايش؟ di-saccharide الان مش دائما مش دائمامش دائما
+
+7
+00:00:51,360 --> 00:00:54,820
+هدول الجزيئين اللي بدهم يتحدوا مع بعض بيكونوا زي
+
+8
+00:00:54,820 --> 00:01:00,140
+بعض يعني يوم بدأ احكي انا عن دايسا كرايد ممكن اجيب
+
+9
+00:01:00,140 --> 00:01:06,260
+نفس الجزيئين تماما بكل محتوياتهم طبعا بالتأكيد ال
+
+10
+00:01:06,260 --> 00:01:09,680
+stereo chemistry تكون نفس الشيء تماما و يعملوا
+
+11
+00:01:09,680 --> 00:01:14,040
+دايسا كرايد و ممكن اجيب جزيئين مختلفين و يعملوا
+
+12
+00:01:14,040 --> 00:01:19,820
+دايسا كرايد فمش ضروريمش ضروري ان الـ disaccharide
+
+13
+00:01:19,820 --> 00:01:26,240
+يكون مكوّن من الجزيئين نفسهم تماما، واضح؟ يعني
+
+14
+00:01:26,240 --> 00:01:30,560
+ممكن يكون فعلا من نفس الجزيئين مكوّن disaccharide
+
+15
+00:01:30,560 --> 00:01:36,920
+وممكن يكون من جزيئين مختلفين وهذا اللي هنشوفه لما
+
+16
+00:01:36,920 --> 00:01:45,550
+نستعرض بعض الـ disaccharides بشكل عام ويعني جداأول
+
+17
+00:01:45,550 --> 00:01:51,710
+دايسا كارايد بدنا نستعرضه المالتوز، واضح؟
+
+18
+00:01:51,710 --> 00:01:57,970
+المالتوز، الآن هذا الديسا كارايد مكون من سكرين
+
+19
+00:01:57,970 --> 00:02:03,070
+جولوكوز، لكن فيهم اختلاف في ال stereo chemistry
+
+20
+00:02:03,470 --> 00:02:08,830
+فيهم اختلاف في ال stereo chemistry واحد منهم واحد
+
+21
+00:02:08,830 --> 00:02:14,730
+منهم alpha glucose والتاني منهم beta glucose الآن
+
+22
+00:02:14,730 --> 00:02:19,390
+اللي بتذكروا معنا قولنا احنا ان ال alpha و ال beta
+
+23
+00:02:19,390 --> 00:02:24,930
+sugars بصيروا لما نسكر اخر carbon اللي سمناها ال
+
+24
+00:02:24,930 --> 00:02:29,300
+anomeric carbon و نعملفي حالة السكريات هذه الميزات
+
+25
+00:02:29,300 --> 00:02:35,240
+الكربونات ال fifth chiral center فإذا ال OH كانت
+
+26
+00:02:35,240 --> 00:02:40,020
+للأسفل على هذا الكربون تحديدا بنقول هذا السكر
+
+27
+00:02:40,020 --> 00:02:46,120
+Alpha وإذا كانت للأعلى Beta الآن هذا ال maltose لو
+
+28
+00:02:46,120 --> 00:02:50,760
+بتطلع عليه أنا هيمكون من سكر متصل في ال anomeric
+
+29
+00:02:50,760 --> 00:02:54,560
+carbon لاحظوا أنا تركيزي على أي كربون ال anomeric
+
+30
+00:02:54,560 --> 00:02:59,820
+carbon نكون معلمينها إلى أساساهذه السكرين المتحدين
+
+31
+00:02:59,820 --> 00:03:07,180
+الآن اتطلعوا على واحد منهم ال oxygen فيه alpha
+
+32
+00:03:07,180 --> 00:03:18,840
+واضح التاني منهم ال oxygen فيه betaواضح فالملتوز
+
+33
+00:03:18,840 --> 00:03:24,740
+بيكون في هذه الحالة امكون من Alpha-Glucose مع Beta
+
+34
+00:03:24,740 --> 00:03:29,660
+-Glucose هى دول اتنين قبل ما يتصلوا مع بعض هذا
+
+35
+00:03:29,660 --> 00:03:35,440
+بهذا الشكل كان OH كان Alpha-Glucose هذا كان Beta
+
+36
+00:03:35,440 --> 00:03:41,320
+-Glucose فاتنين اتصلوا مع بعض من خلال موقع اربعة
+
+37
+00:03:41,320 --> 00:03:45,060
+لما ناخد الترقيم واحد اتنين تلاتة اربعة هذا الموقع
+
+38
+00:03:46,020 --> 00:03:49,540
+أربعة اتحدوا من خلال هذه ال Oxygenة اللي في موقع
+
+39
+00:03:49,540 --> 00:03:55,920
+أربعة عملوا رابطة واضح فصار عند المركب مكوّن من
+
+40
+00:03:55,920 --> 00:04:03,040
+Alpha و من Dبيتا جولوكوز وعشان هيك لما بدنا نسميه
+
+41
+00:04:03,040 --> 00:04:09,900
+ممكن انه نقرأ الاسم تبعه هتحسوا انه مش صعب هو ممكن
+
+42
+00:04:09,900 --> 00:04:15,120
+تتخيلوا مركب بيتا جولوكوز لو حطيت ع موقع اربعة مثل
+
+43
+00:04:15,120 --> 00:04:19,960
+شو كنتوا هتسموه four مثل بيتا جولوكوز
+
+44
+00:04:23,450 --> 00:04:29,690
+الاسم الـ Beta في آخر الكلام Beta-D-Glucobiranose
+
+45
+00:04:29,690 --> 00:04:35,170
+مش سمناه لأن جولوكوزم سكرة حلقة سداسية
+
+46
+00:04:35,170 --> 00:04:40,030
+Glucobiranose وD و Beta لأن هذه موجودة في الوضع
+
+47
+00:04:40,030 --> 00:04:45,410
+Beta الآن هذا على موقع أربعة هي على موقع أربعة من
+
+48
+00:04:45,410 --> 00:04:50,950
+خلال ال Oxygen متحد بإيش ب Alpha-D-Glucobiranose
+
+49
+00:04:51,620 --> 00:04:57,800
+واضح الفكرة؟ فيذكر الاسم العام على موقع أربعة من
+
+50
+00:04:57,800 --> 00:05:05,690
+هذا السكر، إيش موجود عنده على موقع أربعة؟الفا دي
+
+51
+00:05:05,690 --> 00:05:08,890
+جلوكو بايرانوس طبعا اتصاله من خلال ال O عشان هيك
+
+52
+00:05:08,890 --> 00:05:13,490
+كتبنا O فاللي بده يفهم الاسم الاسم مش صعب انه هاي
+
+53
+00:05:13,490 --> 00:05:18,290
+المركب اللي عندى بيتا جلوكو بايرانوس على موقع
+
+54
+00:05:18,290 --> 00:05:22,650
+اربعة منه ايش ايجا نعتبرها بين قوسينAlpha
+
+55
+00:05:22,650 --> 00:05:28,230
+Glucobiranose فهذا سكر الملتوز ببساطة هذه الأشياء
+
+56
+00:05:28,230 --> 00:05:34,030
+بيبقى تفهموا فيها الأفكار العامة فالملتوز من سكرين
+
+57
+00:05:34,030 --> 00:05:38,350
+جولوكوز لكن اتنين مش Alpha Alpha ولا Beta Beta
+
+58
+00:05:38,350 --> 00:05:46,590
+Alpha مع Betaالان بيجيني سكر تاني السيلو بيوز
+
+59
+00:05:46,590 --> 00:05:55,730
+السيلو بيوز متحد من سكرين متفقين تماما بيتا جلوكو
+
+60
+00:05:55,730 --> 00:06:00,550
+بيرانوز مع بيتا جلوكو بيرانوز واضح؟ ولذلك لو انا
+
+61
+00:06:00,550 --> 00:06:07,550
+بدأ اطلع على هذا السكر هذا بيتا ولا لا؟ بيتا وعلى
+
+62
+00:06:07,550 --> 00:06:14,780
+هذا السكرهذه أيضًا Beta فلما بنسميه نسبة لهذا Beta
+
+63
+00:06:14,780 --> 00:06:20,740
+D Glucopyranose متحد من موقع أربعةواحد اتنين تلاتة
+
+64
+00:06:20,740 --> 00:06:25,880
+اربعة متحد من موقع اربعة من خلال ال oxygen ال beta
+
+65
+00:06:25,880 --> 00:06:31,160
+D-glucobiranose واضح يعني هذا كأننا بنقول beta D
+
+66
+00:06:31,160 --> 00:06:36,660
+-glucobiranose يحمل على موقع اربعة beta D
+
+67
+00:06:36,660 --> 00:06:42,100
+-glucobiranose واضح الفكرة فال cellobiose بيكون من
+
+68
+00:06:42,100 --> 00:06:50,330
+سكرين متماثلينتماما، لاحظوا قداش نسبة الخلاف اللي
+
+69
+00:06:50,330 --> 00:06:56,450
+بتعمل يعني مركبات مختلفة، يعني انا بحكي عن
+
+70
+00:06:56,450 --> 00:07:02,330
+Glucopyranose و Glucopyranose و بحكي عن هذا Beta
+
+71
+00:07:02,330 --> 00:07:06,870
+في الحالتين، بس التاني مرة Beta و مرة ايش Alpha
+
+72
+00:07:07,710 --> 00:07:14,870
+خلاف بسيط جدا بس كايرال سنتر واحد، الآن بعد شوية
+
+73
+00:07:14,870 --> 00:07:19,770
+هتكتشفوا ان هذا الخلاف البسيط جدا في كايرال سنتر
+
+74
+00:07:19,770 --> 00:07:26,510
+الوحيد بيتبع خلاف كبير جدا جدا جدا في الخواص بعد
+
+75
+00:07:26,510 --> 00:07:31,760
+ذلك للمراكباتيعني لما ييجيوا الجزيئات الـ
+
+76
+00:07:31,760 --> 00:07:35,200
+disaccharides بدهم يعملوا polysaccharides هاي
+
+77
+00:07:35,200 --> 00:07:38,540
+disaccharide و خلّينا نعتبر هاي كمان disaccharide
+
+78
+00:07:38,540 --> 00:07:43,120
+هذا كان من Beta و Beta و هذا كان من Beta و Alpha
+
+79
+00:07:43,120 --> 00:07:47,660
+الان اللي كان من Alpha و Beta الملتوز بيعمل جزئ
+
+80
+00:07:47,660 --> 00:07:56,080
+كبير اسمه نشا او glycogenاللي هي تخزين أو أماكن
+
+81
+00:07:56,080 --> 00:07:59,380
+تخزين ال carbohydrates سواء في النبات أو في
+
+82
+00:07:59,380 --> 00:08:03,400
+الحيوان وهذه بتدوب في الميه وبيقدر البني آدم
+
+83
+00:08:03,400 --> 00:08:07,000
+يهضمها يعني البني آدم لما بياكل النشويات بيقدر
+
+84
+00:08:07,000 --> 00:08:12,180
+بسهولة يحللها للسكريات الأولية بتاعتها أكيد الآن
+
+85
+00:08:12,180 --> 00:08:16,060
+اللي مكوّن من ال beta و ال beta هيجي يعمل ال
+
+86
+00:08:16,060 --> 00:08:20,600
+cellulose هيعمل الخشب البني آدم بيقدرش يهضم الخشب
+
+87
+00:08:20,600 --> 00:08:27,570
+الآن هتيجي تقوله شو الفرق؟بين أساس الخشب و أساس
+
+88
+00:08:27,570 --> 00:08:33,270
+النشا أساس الخشب cellobiose و اتحد و أعطاني
+
+89
+00:08:33,270 --> 00:08:39,110
+cellulose و أساس النشا الملتوز و أعطاني starch
+
+90
+00:08:39,110 --> 00:08:46,230
+واضح فقط مختلفين هدول الاتنين بواحد من السكريات
+
+91
+00:08:46,230 --> 00:08:49,770
+جولوكوز جولوكوز صح جولوكوز جولوكوز بس هذا beta و
+
+92
+00:08:49,770 --> 00:08:55,240
+beta هذا beta و alphaمخيلوا كيف اختلاف بسيط في ال
+
+93
+00:08:55,240 --> 00:09:00,740
+stereochemistry بيقدر الاختلاف كبير بعد هيك في
+
+94
+00:09:00,740 --> 00:09:05,480
+الخواص و في الاستفادة من المركبات بيجينا سكر
+
+95
+00:09:05,480 --> 00:09:15,960
+الحليب ال lactoseاللاكتوز أيضا في جولوكوز لكن في
+
+96
+00:09:15,960 --> 00:09:20,900
+جالاكتوز يعني هدولا ال stereo chemical centers
+
+97
+00:09:20,900 --> 00:09:26,320
+اتغير فيهم اكتر كل الفروقات بينهم هي فروقات ايش
+
+98
+00:09:26,320 --> 00:09:30,500
+لحتى لها ال stereo chemistry يعني هذه الوحدة مش
+
+99
+00:09:30,500 --> 00:09:36,340
+بيتا جولوكوز في هذه الحالة الفا جولوكوز متحد مع
+
+100
+00:09:36,340 --> 00:09:42,300
+بيتا جالاكتوزعشانك لو ذكرنا الاسم العام هتلاحظوا
+
+101
+00:09:42,300 --> 00:09:47,260
+في الآخر Alpha D Glucopyranose هي ال Alpha D
+
+102
+00:09:47,260 --> 00:09:54,480
+Glucopyranose وشايفين أنها Alpha الآن متحد من موقع
+
+103
+00:09:54,480 --> 00:10:01,340
+أربعة ال Beta D Galactopyranose طبعا بنكتب Beta D
+
+104
+00:10:01,340 --> 00:10:07,450
+Galactopyranoseال YL اللي هي بصفته أصبح مجموعة زي
+
+105
+00:10:07,450 --> 00:10:14,330
+ما بقول مثل اثل بروبل ال YL لأنه أصبح مجموعة واضحة
+
+106
+00:10:14,330 --> 00:10:20,630
+الفكرة؟ هذا ال lactose طبعا بيجي صاحبنا، مين
+
+107
+00:10:20,630 --> 00:10:27,330
+صاحبنا؟السكاروز ماحدش اقول عن السكاروز العدو
+
+108
+00:10:27,330 --> 00:10:33,030
+تبعنا، يعني في ناس دائما متطرفين في الحكم على اللي
+
+109
+00:10:33,030 --> 00:10:37,090
+هي هذه الأشياء، كل هذه السكريات و كل حتى الدهون
+
+110
+00:10:37,090 --> 00:10:40,730
+بتلزم للإنسان، بس المشكلة مش أن الإنسان ياخد
+
+111
+00:10:40,730 --> 00:10:45,340
+سكريات و ياخد دهونالمشكلة أنه ياخدها بإفراط يعني
+
+112
+00:10:45,340 --> 00:10:49,160
+الإنسان بحاجة للسكريات، بحاجة للدهون بالتأكيد،
+
+113
+00:10:49,160 --> 00:10:53,940
+بحاجة للكلسترول، بحاجة لكل إشي لكن الإفراط في أي
+
+114
+00:10:53,940 --> 00:10:58,840
+شغل هو اللي بيعمل عندنا إيش المشكلة الآن لو إجينا
+
+115
+00:10:58,840 --> 00:11:02,640
+اتطلعنا على السكروز اللي هو السكر اللي إحنا
+
+116
+00:11:02,640 --> 00:11:07,540
+بنستعمله هتلاحظوا مرة تانية في عندى Alpha
+
+117
+00:11:07,540 --> 00:11:11,680
+-Glucopyranose هاي Alpha هذه شايفينها؟
+
+118
+00:11:14,950 --> 00:11:19,930
+طالما لا أسفل إذا هذه إيش؟ Alpha لكن المرة هذه
+
+119
+00:11:19,930 --> 00:11:27,030
+الاتحاد تبعه مش من موقع أربعة هو متحد ب fractose
+
+120
+00:11:27,030 --> 00:11:33,390
+واضح؟ هو متحد ب fractose و ال fractose keto sugar
+
+121
+00:11:33,390 --> 00:11:38,370
+لما أخدنا السكريات قلنا إن في عندنا ال doses من ال
+
+122
+00:11:38,370 --> 00:11:43,920
+aldehydesو Ketosis لفراكتوز كيتو شوجار و لما بيسكر
+
+123
+00:11:43,920 --> 00:11:50,240
+بيسكر على السكر خماسي السكر الخماسي فيورانوز و من
+
+124
+00:11:50,240 --> 00:11:56,020
+الفيورانوز متحد من موقع ايش؟ واحد واضح؟ الان هذا
+
+125
+00:11:56,020 --> 00:12:04,630
+الفيورانوز لما بتطلع فيهبيتا واضح؟ اذا هذا بيتا
+
+126
+00:12:04,630 --> 00:12:09,270
+عشانك هتلاقوا الاسم تبعه اعتبروا ان هذا هو الأصل
+
+127
+00:12:09,270 --> 00:12:14,010
+وهذه هي الاش المجموعة اللي جاية على الأصل واضح؟
+
+128
+00:12:14,010 --> 00:12:19,950
+فهتلاحظوا بيتا دي فراكتو فيورانوزيل طبعا
+
+129
+00:12:19,950 --> 00:12:26,210
+فيورانوزيل لأنه جاي ايش؟ مجموعة متحدة مع الف دي
+
+130
+00:12:26,210 --> 00:12:33,150
+غلوكوما كتبش هنا by rhinos، كتب by rhinocide، ليش؟
+
+131
+00:12:33,150 --> 00:12:37,790
+لأن الاتحاد تم هنا من موقع واحد، لاحظوا في
+
+132
+00:12:37,790 --> 00:12:41,270
+السكريات اللي قبل شوية، لما كنا نيجع هذا السكر،
+
+133
+00:12:41,270 --> 00:12:45,150
+الاتحاد تم من أي موقع؟ أربعة، هنا الاتحاد تم من
+
+134
+00:12:45,150 --> 00:12:53,080
+موقع واحد، فإذا هذه الرابطة بطلت OH صارت O-Carbon
+
+135
+00:12:53,080 --> 00:12:58,340
+معنا ذلك هذه الرابطة ايش بدها تكون؟ Glycosidic
+
+136
+00:12:58,340 --> 00:13:02,280
+bond واضح؟ عشان Glycosidic bond عشان تكون
+
+137
+00:13:02,280 --> 00:13:08,400
+Glycoside هنحط ايش؟ Glucoburanoside لاحظته هنا
+
+138
+00:13:08,400 --> 00:13:12,640
+كلمة؟ Buranoside لو رجعتوا على الأسماء اللي قبل
+
+139
+00:13:12,640 --> 00:13:19,240
+كان حط Glucoburanose لأن هذه كانت تكون OHفي كل
+
+140
+00:13:19,240 --> 00:13:23,280
+اللي قبل هذه كانت OH غلوكو باي رانوس سواء كان
+
+141
+00:13:23,280 --> 00:13:28,860
+Alpha أو Beta لكن هنا بطلت OH صار الاتحاد من عندها
+
+142
+00:13:28,860 --> 00:13:33,420
+و عشان هيك صارت هذه الرابطة Glycosidic bond فقال
+
+143
+00:13:33,420 --> 00:13:38,300
+غلوكو باي رانوسايد غلوكو باي رانوسايد فالحقيقة
+
+144
+00:13:40,010 --> 00:13:46,150
+السكر اللى فيه two glycosidic bonds هو سكر ايش
+
+145
+00:13:46,150 --> 00:13:50,210
+السكروز انتبهوا لو كانوا بيسألكوا multiple choice
+
+146
+00:13:50,210 --> 00:13:58,670
+الان هذه الرابطة carbon و carbon هذى glycosidic
+
+147
+00:13:58,670 --> 00:14:04,230
+bond ولا لأ و هذا الرابطة glycosidic bond فلما
+
+148
+00:14:04,230 --> 00:14:10,320
+نيجي نطلع احنا حقيقة على السكروزكم جليكوسايدك بوند
+
+149
+00:14:10,320 --> 00:14:18,940
+فيه؟ تنتين لو رجعنا اتطلعنا على السكريات
+
+150
+00:14:18,940 --> 00:14:25,100
+اللي قبل هنا كم جليكوسايدك بوند؟ واحدة ماحدش يقول
+
+151
+00:14:25,100 --> 00:14:29,520
+هذه جليكوسايدك بوند ليش؟ لأن الجليكوسايدك بوند
+
+152
+00:14:29,520 --> 00:14:34,700
+اللي بتتكون على الكايرال سنتر الأخير على هذه مش
+
+153
+00:14:34,700 --> 00:14:40,650
+على هذا الموقع أربعةواضح؟ يعني مش اي او كربون
+
+154
+00:14:40,650 --> 00:14:47,850
+glycosidic bond ال glycosidic bond مرتبطة بأي بأي
+
+155
+00:14:47,850 --> 00:14:52,630
+كربون بال anomeric carbon اللي كانت أساسا الديهايد
+
+156
+00:14:52,630 --> 00:14:56,350
+واضح؟ ولذلك هذه glycosidic bond بس هذه مش
+
+157
+00:14:56,350 --> 00:15:01,390
+glycosidic bond واضح؟ فلو أنا اجيت على ال lactose
+
+158
+00:15:01,390 --> 00:15:08,540
+في one glycosidic bond لو رجعتعلى السيلو بيوز على
+
+159
+00:15:08,540 --> 00:15:13,640
+سبيل المثال برضه أي واحدة anomeric carbon كل سكر
+
+160
+00:15:13,640 --> 00:15:17,780
+فيه two anomeric carbon مظبوط ولا لأ هذه فيها
+
+161
+00:15:17,780 --> 00:15:24,200
+glycosidic bond هذه فيها لذلك في السيلو بيوز في
+
+162
+00:15:24,200 --> 00:15:30,950
+عنده one glycosidic bond هذه لأواضحة الفكرة؟ يعني
+
+163
+00:15:30,950 --> 00:15:34,970
+انا عندي two anomeric carbons مين فيهم glycosidic
+
+164
+00:15:34,970 --> 00:15:40,630
+bond؟ هذي ال O H glycosidic، هذي، اه واضحة الفكرة؟
+
+165
+00:15:40,630 --> 00:15:44,950
+فدائما لما بدنا نعرف كام glycosidic bond، نرجع على
+
+166
+00:15:44,950 --> 00:15:53,670
+الملتوز مثلا، هذي ال anomeric carbons الآن لو
+
+167
+00:15:53,670 --> 00:15:57,690
+إجينا سألنا هذي glycosidic bond؟ O H، هذي
+
+168
+00:15:59,540 --> 00:16:07,100
+Glycosidic bond فالملتوز والسيلوبيوز واللاكتوز
+
+169
+00:16:07,100 --> 00:16:11,380
+هدولة فيهم و one glycosidic bond و التانية عادية
+
+170
+00:16:11,380 --> 00:16:16,740
+عشان ايه كنتوا تلاقوا؟ Glucopyranose عادي لكن لما
+
+171
+00:16:16,740 --> 00:16:23,340
+وصلنا للسكروز لو اجينا سألنا وين ال anomeric
+
+172
+00:16:23,340 --> 00:16:24,180
+carbons؟
+
+173
+00:16:26,580 --> 00:16:31,440
+هي الانوميرك كاربونز الان هنا في جليكوسايدك بوند
+
+174
+00:16:31,440 --> 00:16:36,640
+فيه هنا في جليكوسايدك بوند فيه تنتين جليكوسايدك
+
+175
+00:16:36,640 --> 00:16:42,920
+بوند واضح؟ وعشان هيك هذا لما أنهينا اسمه أنهينا ب
+
+176
+00:16:42,920 --> 00:16:49,480
+side اللي هو alpha D-glucopyranoside زي ما اتعلمنا
+
+177
+00:16:49,480 --> 00:16:53,160
+لما أخدنا الجليكوسايدك بوند وقلنا بننهي بإيش؟
+
+178
+00:16:53,160 --> 00:16:54,360
+جليكوسايد
+
+179
+00:16:57,360 --> 00:17:03,560
+هذا بالنسبة لبعض السكريات اللي هي بنستفيد منها ل
+
+180
+00:17:03,560 --> 00:17:08,700
+ال die saccharides الكلام يمكن يجيب بعضه أن القاسم
+
+181
+00:17:08,700 --> 00:17:16,810
+المشترك ربما في الأشياء المحلية طعم الحلوواضح؟
+
+182
+00:17:16,810 --> 00:17:20,550
+يعني الإنسان بيفتش في النهاية عن إيش؟ الطعم كذلك
+
+183
+00:17:20,550 --> 00:17:24,450
+الحال يمكن تلاحظوه في العطور يعني مار علينا و إحنا
+
+184
+00:17:24,450 --> 00:17:31,410
+بنشرح بعض العطور العطور لا يوجد خليني أقول مجموعة
+
+185
+00:17:31,410 --> 00:17:35,810
+كيميائية تكون قاسم مشترك ما بين العطور ما القاسم
+
+186
+00:17:35,810 --> 00:17:41,920
+المشترك؟الرائحة الذكية، الرائحة الجيدة الآن العطر
+
+187
+00:17:41,920 --> 00:17:46,360
+ممكن مرة يكون Easter ممكن مرة يكون الديهيد ممكن
+
+188
+00:17:46,360 --> 00:17:50,440
+مرة يكون كيتون شوفنا الياسمون مثلا شوفنا ..
+
+189
+00:17:50,440 --> 00:17:53,940
+متذكرين الياسمين كان كيتون شوفنا ال Easter's قولنا
+
+190
+00:17:53,940 --> 00:17:58,040
+عنها مواد عطرية مافيش قاسم كيميائي مشترك القاسم
+
+191
+00:17:58,040 --> 00:18:03,310
+الكيميائي ما بين العطورهو الرائحة الجيدة الآن
+
+192
+00:18:03,310 --> 00:18:07,290
+القاسم الكيميائي ما بين ال sweeteners المحليات و
+
+193
+00:18:07,290 --> 00:18:12,970
+منها السكر هو الطعم الاش؟ الحلو ولذلك الآن في
+
+194
+00:18:12,970 --> 00:18:17,490
+سكريات اللي هي السكريات هذه الصناعية اللي بياخدوها
+
+195
+00:18:17,490 --> 00:18:21,430
+الناس اللي عندهم سكر و ما إلى ذلك لو اطلعت على
+
+196
+00:18:21,430 --> 00:18:25,590
+أنواعها المختلفة مش هتلاقيوا شيء مشترك في الشكل
+
+197
+00:18:25,590 --> 00:18:32,500
+بينها لكن هالمراكبات لما حضروهالاحظوا انه طعمها
+
+198
+00:18:32,500 --> 00:18:37,440
+حلو وبشكل عام آمن يعني كتير في مركبات طعمها حلو
+
+199
+00:18:37,440 --> 00:18:40,980
+لكن خطيرة جدا بيقدرش الإنسان يتعامل معايا
+
+200
+00:18:40,980 --> 00:18:45,440
+الكلوروفورم طعمه حلو لكن سامه carcinogenic لكن هذا
+
+201
+00:18:45,440 --> 00:18:50,040
+المركب مثلا بدون ما ناخد طرق تحضيره هو السكارين
+
+202
+00:18:50,040 --> 00:18:54,720
+سواء وجد ع شكل السكارين أو عشان يدوب بيسحبوا القدش
+
+203
+00:18:54,720 --> 00:18:58,580
+بيعملوا ال salt تبعه طبعا دائما لما نقول salt ال
+
+204
+00:18:58,580 --> 00:19:03,300
+salt ليش بنعمله احناعشان الذائبية تكون أعلى في
+
+205
+00:19:03,300 --> 00:19:08,740
+الميه فلو اطلعنا احنا هذا ال sodium سكارين اللي هو
+
+206
+00:19:08,740 --> 00:19:12,740
+اللي بنستعمله و بنحطه على الشاي مافيش علاقة بين
+
+207
+00:19:12,740 --> 00:19:20,080
+شكله وبين شكل السكاروز لكن يوضع بديل للسكاروز،
+
+208
+00:19:20,080 --> 00:19:25,780
+مظبوط ولا لأ؟ ليش يوضع بديل للسكاروز؟ بسبب الطعم
+
+209
+00:19:25,780 --> 00:19:30,730
+الحلو، الآن في سكريات تانية غير السكاروزالسكارين
+
+210
+00:19:30,730 --> 00:19:36,150
+تستعمل منها مثلا ال Aspartame و ال Cyclamates لو
+
+211
+00:19:36,150 --> 00:19:42,110
+فتشته Cyclamates لو فتشته على شكل ال Aspartame و
+
+212
+00:19:42,110 --> 00:19:46,030
+ال Cyclamate و السكارين هتلاقي كل واحد يمثل شكل
+
+213
+00:19:46,030 --> 00:19:52,410
+معين مافيش قاسم مشترك بينهم القاسم المشترك هو إيش؟
+
+214
+00:19:52,410 --> 00:19:57,510
+الطعم الحلو القاسم المشترك هو الطعم الحلو يعني هاي
+
+215
+00:19:57,510 --> 00:20:02,700
+ال Aspartameطلعوا هذا شكل و هذا شكل بتلاحظوا فيه
+
+216
+00:20:02,700 --> 00:20:07,740
+شيء مشترك مع السكرين طب العسل بس زي محلق و بطعم
+
+217
+00:20:07,740 --> 00:20:12,060
+حلو؟ ايه هو؟ العسل؟ ما هو العسل فيه سكريات كتيرة
+
+218
+00:20:12,060 --> 00:20:17,120
+لأ لأ مش من هدولة من السكريات العادية اللي أخدناها
+
+219
+00:20:17,120 --> 00:20:23,000
+بس تركيبته عاد كبيرة في سكريات و فيتامينات و إشي
+
+220
+00:20:23,000 --> 00:20:31,540
+أكثر من شغلها الآنهذه الـ Disaccharides سواء كانت
+
+221
+00:20:31,540 --> 00:20:37,740
+سكريات مختلفة زي الملتوز اللي احنا قلنا عنه Alpha
+
+222
+00:20:37,740 --> 00:20:43,810
+و Beta الجلوكوز متحدين مع بعض أوالسيلو بيوز اللي
+
+223
+00:20:43,810 --> 00:20:47,710
+قلنا عنه بيتا و بيتا يعني خلينا نركز احنا على
+
+224
+00:20:47,710 --> 00:20:52,810
+الملتوز الملتوز كان من ألفة و بيتا جولوكوز مكون
+
+225
+00:20:52,810 --> 00:20:57,790
+واضح؟ و السيلو بيوز من بيتا و بيتا جولوكوز الآن
+
+226
+00:20:57,790 --> 00:21:02,470
+هدولة لما بيجوا بيعملوا بوليمار كبير لما بيعملوا
+
+227
+00:21:02,470 --> 00:21:06,750
+بوليمار كبير بيكون هم الوحدة الأساسية المتكررة في
+
+228
+00:21:06,750 --> 00:21:12,930
+البوليمار بيعطوناالـ starch أو النشا في حالة ما
+
+229
+00:21:12,930 --> 00:21:18,570
+نتكلم عن إيش؟ عن الملتوز، في حالة ما نتكلم عن
+
+230
+00:21:18,570 --> 00:21:22,990
+السيلوبايوز، بيعطينا السيليلوز، واضح؟ فالملتوز
+
+231
+00:21:22,990 --> 00:21:29,130
+بيعطيني إيش؟ النشا، starch، السيلوبايوز بيعطيني
+
+232
+00:21:29,130 --> 00:21:36,470
+السيليلوز، الخشب، واضح؟ بولمار كبير طبعاًلاحظوا
+
+233
+00:21:36,470 --> 00:21:40,990
+عاد حسب ال polymer اللي بتكون يعني يوم ما نحكي عن
+
+234
+00:21:40,990 --> 00:21:45,550
+polymer يعني عدد كبير من الشغلات هتلاحظوا في علم
+
+235
+00:21:45,550 --> 00:21:50,250
+ال polymerization هذا العدد ممكن يكون 300 وحدة
+
+236
+00:21:50,250 --> 00:21:56,200
+ممكن يكون الف ممكن يكون تلت تلافتمام؟ حسب طريقة
+
+237
+00:21:56,200 --> 00:21:59,420
+الارتباط اللى موجودة في هذا العدد وحسب عدد
+
+238
+00:21:59,420 --> 00:22:03,760
+الجزيئات او الوحدات المكونة له الآن وحدة ال stars
+
+239
+00:22:03,760 --> 00:22:08,300
+هي ايش؟ ال maltose هذه الوحدة اللى مكونة من سكرين
+
+240
+00:22:08,300 --> 00:22:13,160
+حسب كمية الأشياء المتصلة بيصير عند نوع ال polymer
+
+241
+00:22:13,160 --> 00:22:16,340
+عشانك انتوا بال plastic بتلاحظوا في عندكوا أنواع
+
+242
+00:22:16,340 --> 00:22:21,460
+كتيرةفي النيلون في عندكم أنواع كتيرة هذا بيصير
+
+243
+00:22:21,460 --> 00:22:25,860
+يدخل فيه جانب الصناعة انه قداش العدد اللي خلناه
+
+244
+00:22:25,860 --> 00:22:31,640
+يتحد تقريبا يعمل polymer هالخليه 300 جزء و وحدة ال
+
+245
+00:22:31,640 --> 00:22:37,640
+polymer 3000 2000 واضح الفكرة؟ الآن نفس الفكرة من
+
+246
+00:22:37,640 --> 00:22:43,350
+الملتوز هلاحظ ان في انهاالـ starch لو حللته
+
+247
+00:22:43,350 --> 00:22:47,990
+بيعطيني ملتوز، الملتوز لو حللته بيعطيني جولوكوز،
+
+248
+00:22:47,990 --> 00:22:52,830
+لكن جولوكوز Alpha
+
+249
+00:22:53,990 --> 00:22:58,410
+وبيتاجولوكوز لكن هذه الوحدة المتكررة وحدة الملتوز
+
+250
+00:22:58,410 --> 00:23:03,350
+اعملوا منها عدد كبير الان لاحظوا ان النشا مكون من
+
+251
+00:23:03,350 --> 00:23:08,230
+شغلتين من اميلوز بنسبة 20% والباقي تقريبا
+
+252
+00:23:08,230 --> 00:23:15,200
+اميلوبكتل ايش بيفرقوا هدولة الشغلتين؟بعدد الجزيئات
+
+253
+00:23:15,200 --> 00:23:19,980
+المكونة له بطريقة الاتحاد يعني ال amylose في
+
+254
+00:23:19,980 --> 00:23:25,840
+جولوكوز units عادة بيكون عددها ما يقارب بين خمسين
+
+255
+00:23:25,840 --> 00:23:30,260
+لتلتمية جولوكوز unit لكن أهم شيء بيميزها أن هي
+
+256
+00:23:30,260 --> 00:23:37,970
+موجودة في إيش؟بسلاسل بدون تفرعات، واضح؟ سلاسل بهذا
+
+257
+00:23:37,970 --> 00:23:42,830
+الشكل بدون ما يصير فيها تفرعات، العدد تبع ال
+
+258
+00:23:42,830 --> 00:23:47,410
+geolocose units بيكون ما بين خمسين إلى تلتمية
+
+259
+00:23:47,410 --> 00:23:52,770
+geolocose unit والاتحاد زي ما انتوا عارفين نمر
+
+260
+00:23:52,770 --> 00:23:58,270
+أربعة من هان وبتحد من واحد مع الجزء التانييعني
+
+261
+00:23:58,270 --> 00:24:02,190
+احنا لما كنا نتكلم عن ال مالتوز، كنا هنا في عنا
+
+262
+00:24:02,190 --> 00:24:07,550
+الاتحاد مع أربعة أو سابين واحد، أوقتش، الآن لما
+
+263
+00:24:07,550 --> 00:24:11,150
+بتعمل polymer، بيجيب التحد منها، يعني لو انتوا
+
+264
+00:24:11,150 --> 00:24:16,630
+تذكرتوا المالتوز، مش كانت هذه تكون فيهقواتش لما
+
+265
+00:24:16,630 --> 00:24:20,930
+نحكي عن الملتوز لوحده الآن بيصير يتحد من هذه
+
+266
+00:24:20,930 --> 00:24:23,690
+القواتش عشان يعمل ال polymer يعني القواتش اللي
+
+267
+00:24:23,690 --> 00:24:28,610
+كانت ماتروكة فاضية بيصير يتحد من خلالها مع موقع
+
+268
+00:24:28,610 --> 00:24:33,130
+أربعة من وحدة ملتوز تانية بطلع عنده جزء كبير
+
+269
+00:24:33,130 --> 00:24:34,210
+بنسميه إيش
+
+270
+00:24:37,020 --> 00:24:43,020
+الاميلوز الاميلوز هذا احد مكونات النشا الان النشا
+
+271
+00:24:43,020 --> 00:24:49,260
+في مكون تاني الاميلوبكتين الاميلوبكتين في ما بين
+
+272
+00:24:49,260 --> 00:24:53,460
+تلتمية الى خمستلاف جولوكوز units يعني الجولوكوز
+
+273
+00:24:53,460 --> 00:24:59,860
+units اللى في عددها اكبر لكن اهم شغل فيه is
+
+274
+00:24:59,860 --> 00:25:06,920
+هايلبراجد واضح يعني الاميلوز سلسلةالـ amylobectin
+
+275
+00:25:06,920 --> 00:25:13,440
+في تفرعات يعني تقريبا لاحظوا الـ amylose بين 300
+
+276
+00:25:13,440 --> 00:25:17,220
+إلى 5000 جولوكوز units is a highly branched
+
+277
+00:25:17,220 --> 00:25:21,660
+molecule او highly branched molecule chains with
+
+278
+00:25:21,660 --> 00:25:24,360
+consecutive one four links شوفنا كيف one four
+
+279
+00:25:24,360 --> 00:25:28,520
+links الارتباط ال average يعني كل مجموعة حوالي
+
+280
+00:25:28,520 --> 00:25:35,070
+خمسة وعشرين لتلاتين وحدةو بعدين بيجي تفرع 25 ل 30
+
+281
+00:25:35,070 --> 00:25:41,110
+و تفرع بيصير الجزء أشماله highly branched واضح
+
+282
+00:25:41,110 --> 00:25:48,470
+فواضح أن جزء ال amylobectin أكبر من ال amylose و
+
+283
+00:25:48,470 --> 00:25:55,150
+بنفس الوقت اللي بيميزه التفرعات واضح فال amylose
+
+284
+00:25:55,150 --> 00:26:02,220
+is a chain moleculeالـ amylobectin هو جزئ عالي جزئ
+
+285
+00:26:02,220 --> 00:26:11,520
+فيه تفرعات كتيرة طبعا هذه كل أشكال تقريبية بتوضح
+
+286
+00:26:11,520 --> 00:26:20,720
+لنا كيف بيتكونوا هذول الجزيئات الأن لو جينا من ال
+
+287
+00:26:20,720 --> 00:26:30,470
+amylose أيضاغير النشق بمكوينه يعني من الملتوز كان
+
+288
+00:26:30,470 --> 00:26:35,130
+في عنده ال starch اللي هو مكوّن من amylose و
+
+289
+00:26:35,130 --> 00:26:40,470
+mylobectin أيضًا من الملتوز في عنده الجليكوجين ال
+
+290
+00:26:40,470 --> 00:26:45,470
+starch ما كان تخزين ال carbohydratesفي النبات
+
+291
+00:26:45,470 --> 00:26:49,410
+الجليكوجين مكان تخزين ال carbohydrates في
+
+292
+00:26:49,410 --> 00:26:55,750
+الحيوانات برضه هو فيه جولوكوز units لكن حوالي مائة
+
+293
+00:26:55,750 --> 00:27:00,590
+ألف جولوكوز unit لاحظوا العدد في الجليكوجين
+
+294
+00:27:00,590 --> 00:27:06,810
+جليكوجين بيزيد بشكل كبير وبرنشد يعني كل ما بين كل
+
+295
+00:27:06,810 --> 00:27:11,010
+تمانية ل 12 جولوكوز unit خلينا هيك نتخيل هتلاحظوا
+
+296
+00:27:11,010 --> 00:27:17,930
+ان في عندكم إيشالجزء هذا الجليكوجين بيكون أيضا
+
+297
+00:27:17,930 --> 00:27:24,090
+highly branched الآن الجليكوجين بيجي من الجلوكوز
+
+298
+00:27:24,090 --> 00:27:30,130
+اللي بيمتص من أمعاء produced from glucose that is
+
+299
+00:27:30,130 --> 00:27:35,930
+absorbed from intestines into the blood الآن إيش
+
+300
+00:27:35,930 --> 00:27:41,060
+وظيفته هذا الجليكوجين؟ يمكن مار عليكمبيولوجيا اللي
+
+301
+00:27:41,060 --> 00:27:45,260
+هو توازن السكر helps maintain the glucose balance
+
+302
+00:27:45,260 --> 00:27:49,660
+واضح يعني إذا في عندي جولوكوز ازيادة بيجي و بتخزن
+
+303
+00:27:49,660 --> 00:27:54,340
+وين في الجليكوجين بدخل ضمن البوليمار الآن إذا
+
+304
+00:27:54,340 --> 00:28:00,770
+الجسم نقص عليه الجولوكوزبصير هذا نفسه يفرز أو يعطي
+
+305
+00:28:00,770 --> 00:28:07,930
+الجسم وحدات جولوكوز واضح الفكرة؟ يعني هو كأنه هاي
+
+306
+00:28:07,930 --> 00:28:12,450
+جزيئات الجولوكوز بتقدروا تتخيلوها بتمطس من المعدة
+
+307
+00:28:12,450 --> 00:28:16,030
+المفروض لازم لحرق الأكل الناس اللي بياكلوا كتير
+
+308
+00:28:16,030 --> 00:28:21,510
+okay بنجمع هذه الجزيئات هيعملنا إيش؟جلايكوجين
+
+309
+00:28:21,510 --> 00:28:25,790
+وخزانة الان بعد هيك صار البني ادم عنده ناقص في
+
+310
+00:28:25,790 --> 00:28:31,010
+السكر جد ما فيه ناقص بيصير يطلع له جولوكوز واضح؟
+
+311
+00:28:31,010 --> 00:28:36,090
+واضحة الفكرة العامة خليني اقول العامة جدا
+
+312
+00:28:36,090 --> 00:28:42,890
+لجلايكوجين الان لو طلعنا على ال cellulose ال
+
+313
+00:28:42,890 --> 00:28:48,830
+cellulose هو ال polymerاللي جاي من الـ cellobiose
+
+314
+00:28:48,830 --> 00:28:55,010
+اللي بيعمل الخشب يعني النشا والجليكوجين جايين من
+
+315
+00:28:55,010 --> 00:29:01,430
+وين؟ من الملتوز من الملتوز لكن ال cellulose جاي من
+
+316
+00:29:01,430 --> 00:29:03,410
+ال cellobiose
+
+317
+00:29:05,410 --> 00:29:11,210
+بيتا وبيتا sugar فالcellulose is an unbranched
+
+318
+00:29:11,210 --> 00:29:16,210
+polymer مستقيم مافيش فيه branches of glucose
+
+319
+00:29:16,210 --> 00:29:20,110
+joined by one four beta glycosidic bonds كل
+
+320
+00:29:20,110 --> 00:29:29,390
+هالكلام شفناه لاحظوا معي كيف فرق في الأساس بسيط
+
+321
+00:29:29,390 --> 00:29:37,500
+جدا انه هذا منسيلو بيوز هذا من مالتوز السيلو بيوز
+
+322
+00:29:37,500 --> 00:29:42,260
+و المالتوز متحدين في beta غلوكوز لكن السكر التاني
+
+323
+00:29:42,260 --> 00:29:46,820
+في كل واحدة واحد منهم واحد alpha واحد beta يعني
+
+324
+00:29:46,820 --> 00:29:51,120
+خلينا نقول هنا في عند بيتا و بيتا نفس الاشي في
+
+325
+00:29:51,120 --> 00:29:57,340
+السكرين الآن في المالتوز هذا alpha في السيلو بيوز
+
+326
+00:29:58,430 --> 00:30:03,590
+هذا beta فهذا alpha beta هذا beta beta الآن هذا
+
+327
+00:30:03,590 --> 00:30:07,690
+بيصير ملتوز و بيعملني نشا و glycogen هذا بيصير
+
+328
+00:30:07,690 --> 00:30:12,970
+cellulose و cellobiose و بيعمله ال cellulose الان
+
+329
+00:30:12,970 --> 00:30:16,990
+البني آدم بيقدر يهضم النشا بيقدر يهضم ال glycogen
+
+330
+00:30:16,990 --> 00:30:22,670
+بيقدرش يهضم ال cellulose ال cellulose واضح فال
+
+331
+00:30:22,670 --> 00:30:26,830
+humans and other animals they digest starch and
+
+332
+00:30:26,830 --> 00:30:32,880
+glycogenبيقدروا يهضموا النشق والجليكوجين، الآن
+
+333
+00:30:32,880 --> 00:30:37,360
+الحيوانات
+
+334
+00:30:37,360 --> 00:30:42,610
+والنمليمكن تقولوا النمل صار أقوى من البني آدم يعني
+
+335
+00:30:42,610 --> 00:30:46,550
+هو النمل بيقدر يخضم الخشب و البني آدم مابيقدرش
+
+336
+00:30:46,550 --> 00:30:52,030
+معنا ذلك النمل أقوى من البني آدم هي المشكلة انه
+
+337
+00:30:52,030 --> 00:30:57,150
+كمان مش النمل اللي بيخضم او مش الحيوانات المجترة
+
+338
+00:30:57,150 --> 00:31:01,570
+اللي بتخضم لأ بكتيريا موجودة جوا أمعاها هذه
+
+339
+00:31:01,570 --> 00:31:05,050
+البكتيريا اللي جوا أمعاها بتفرز اللي هو
+
+340
+00:31:08,560 --> 00:31:14,060
+الانزيمات اللى هى ال beta glycosidase اللى بتساعد
+
+341
+00:31:14,060 --> 00:31:19,960
+على عملية ايش ان تقدر تهضم الخشب وتستفيد منه واضح
+
+342
+00:31:19,960 --> 00:31:27,760
+فماني بكتيريا contain beta glycosidase دايما اذا
+
+343
+00:31:27,760 --> 00:31:33,510
+شفتوا هذه النهاية ايش هذاالنزيم Oxidase و
+
+344
+00:31:33,510 --> 00:31:37,870
+Redactase و glycosidase and they can hydrolyze
+
+345
+00:31:37,870 --> 00:31:42,810
+يعني يفككوا ال cellulose فلو احنا قلنالكم ان ال
+
+346
+00:31:42,810 --> 00:31:46,090
+humans can hydrolyze cellulose
+
+347
+00:31:48,210 --> 00:31:52,250
+واضح؟ لكن في بكتيريا كتير بتقدر تعمل هذا الكلام
+
+348
+00:31:52,250 --> 00:31:55,990
+هذه موجودة في ال termites اللي هو النمل الأبيض و
+
+349
+00:31:55,990 --> 00:31:59,510
+ال ruminants اللي هي الحيوانات المجترة اللي
+
+350
+00:31:59,510 --> 00:32:03,050
+بتلاقوها مستعدة تاكل ال .. إيش؟ زي الجمل و زي ..
+
+351
+00:32:03,050 --> 00:32:08,250
+أه اللي بتاكل الخشب فبكتيريا في معدتها بتقدر تدخل
+
+352
+00:32:08,250 --> 00:32:13,450
+على هذا الخشب و تحلله لوحدات السكر بحيث أنه النمل
+
+353
+00:32:13,450 --> 00:32:18,430
+الأبيض أو الحيوانات هذه المجترة تقدر تستفيد منهأو
+
+354
+00:32:18,430 --> 00:32:22,310
+من السكر اللي موجود فيه لكن البني آدم مابيقدرش
+
+355
+00:32:22,310 --> 00:32:26,730
+يخدمه أخر
+
+356
+00:32:26,730 --> 00:32:33,090
+شغلة أخر شغلة بنحكيها بالنسبة لهذا الجزء أنه في
+
+357
+00:32:33,090 --> 00:32:37,870
+عندى بعض ال sugars يمكن أن ينزع منها أكسجين هذه
+
+358
+00:32:37,870 --> 00:32:42,850
+بتفيدنا لما بدنا ندرس ال nuclear acid اللي هي
+
+359
+00:32:42,850 --> 00:32:49,090
+الأحماض النووية ومنهابصير اسمها deoxy sugars يعني
+
+360
+00:32:49,090 --> 00:32:53,470
+لاحظوا هذا ال sugar لما يكون فيه ال oxygen و سكر
+
+361
+00:32:53,470 --> 00:32:58,610
+من خمس كربونات tripose تمام لما نشيل منه oxygen
+
+362
+00:32:58,610 --> 00:33:02,870
+منها يعني في الأصل كان في عنده OH لو شيلنا منه
+
+363
+00:33:02,870 --> 00:33:09,490
+oxygen ايش بيصير اسمه؟ deoxy، deoxy يعني منزوعأه
+
+364
+00:33:09,490 --> 00:33:14,570
+لحظة ميزه .. ميزه رجاء في الكلمات، عشانك احنا
+
+365
+00:33:14,570 --> 00:33:22,080
+بنقول اتعبوا شوية، يعني لو اتينا قولنالكم ضايقزيدا
+
+366
+00:33:22,080 --> 00:33:27,800
+يعني اتنين اه لكن دي منزوعة زي ما كنا نقول
+
+367
+00:33:27,800 --> 00:33:31,760
+hydrogenation, dehydrogenation, hydration,
+
+368
+00:33:32,600 --> 00:33:38,260
+dehydrogenation, halogenation, dehydrogenation فال
+
+369
+00:33:38,260 --> 00:33:43,820
+دي بتاعنا اللي هو العكس فهذا ال beta دي دي
+
+370
+00:33:43,820 --> 00:33:48,860
+oxyribofuranose طب علشه فيورانوز لأنهمن حلقاء
+
+371
+00:33:48,860 --> 00:33:53,520
+خماسية هو ال sugar تبع ال DNA هو عبارة عن Ribose
+
+372
+00:33:53,520 --> 00:33:58,720
+نزعت منه ال Oxygen و لو كان ال Ribose اللي في ال
+
+373
+00:33:58,720 --> 00:34:05,400
+Oxygen بيعملنا ال RNA Ribonucleic Acid لما يكون ال
+
+374
+00:34:05,400 --> 00:34:09,800
+DNA Deoxyribonucleic Acid واضح؟
+
+375
+00:34:12,560 --> 00:34:19,700
+الكلام عام عن اللي هي ال dice carats و عن ال
+
+376
+00:34:19,700 --> 00:34:26,210
+polymers اللي بتكونوا منهم خلينا يعني نبدأنعطي
+
+377
+00:34:26,210 --> 00:34:31,310
+فكرة عامة ليش أنا محتاجها الآن مقارنة مع
+
+378
+00:34:31,310 --> 00:34:37,050
+البروتينات اللي بدنا ناخدها في الفصل الأخير ان شاء
+
+379
+00:34:37,050 --> 00:34:41,910
+الله اللي هو ال amino acids و ال peptides و ال
+
+380
+00:34:41,910 --> 00:34:48,210
+proteins زي ما لاحظته يمكن أهم شغلة في ال
+
+381
+00:34:48,210 --> 00:34:52,290
+polysaccharides أهم شغلة في ال polysaccharides أن
+
+382
+00:34:52,290 --> 00:34:57,650
+هم polymersماذا يعني polymers؟ يعني لما أقول
+
+383
+00:34:57,650 --> 00:35:04,150
+النشا، إيش الوحدة تبعته؟ هتقولولي مالتوز
+
+384
+00:35:04,150 --> 00:35:10,390
+البيسكريدي المالتوز، تمام؟ لو قولت مثلا السيللوز،
+
+385
+00:35:10,390 --> 00:35:15,870
+بوليمر كبير، إيش الوحدة تبعته؟ السيلوبيوز، ولذلك
+
+386
+00:35:15,870 --> 00:35:23,490
+ال polysaccharidesيمكن التعامل معها يكون أسهل كتير
+
+387
+00:35:23,490 --> 00:35:28,790
+من التعامل مع البروتينات ليش؟ لأن ال
+
+388
+00:35:28,790 --> 00:35:32,930
+polysaccharides عندي وحدة و بتتكرر يعني كأن
+
+389
+00:35:32,930 --> 00:35:37,110
+الإنسان بيقدر يقول عنهم ان they are real polymers
+
+390
+00:35:37,110 --> 00:35:43,710
+واضح؟ ال polymers مكون من إيش؟مونومارز تتحد تصير
+
+391
+00:35:43,710 --> 00:35:47,910
+دايمارز، ترايمارز، تترامارز، في الآخر إيش؟
+
+392
+00:35:47,910 --> 00:35:55,190
+بوليمارز، فالبوليمار من ناحية المبدأ وحدة متكررة،
+
+393
+00:35:55,190 --> 00:36:00,390
+البوليمار وحدة إيش مالها؟ متكررة، فلمّا أجي أقول
+
+394
+00:36:00,390 --> 00:36:05,990
+starch polymer ما وحدته المتكررة؟ الملتوز، انتهى
+
+395
+00:36:06,580 --> 00:36:13,060
+واضح؟ الآن لما بدي اجي .. لما بدي اجي اتكلم عن ال
+
+396
+00:36:13,060 --> 00:36:18,900
+proteins هلاحظ ان في عندي اختلاف أساسي ال proteins
+
+397
+00:36:18,900 --> 00:36:26,580
+عبارة عن amino acids وال amino acids مختلفين
+
+398
+00:36:27,350 --> 00:36:33,110
+واضح ال amino acids مختلفين ولذلك انا لما بدي اجي
+
+399
+00:36:33,110 --> 00:36:38,050
+اعمل مثلا نشا بقدر اقول بقدر اقول في حالة النشا او
+
+400
+00:36:38,050 --> 00:36:44,630
+ال amylose مالتوز تلاتين
+
+401
+00:36:44,630 --> 00:36:50,320
+وحدة مثلا او تلاتميت وحدةملتوز 300 وحدة واضح؟
+
+402
+00:36:50,320 --> 00:36:56,520
+الملتوز مكرر كده؟ 300 مرة هاي صرت عامل مثلا اميلوز
+
+403
+00:36:56,520 --> 00:37:01,240
+لكن لو جيت بدي اعمل البروتين او الأصغر من البروتين
+
+404
+00:37:01,240 --> 00:37:04,720
+ال بيبتايد اللي هيمر علينا بعد شوية مابقدرش اعمل
+
+405
+00:37:04,720 --> 00:37:09,460
+مثل هذه المعادلة واضح؟ يعني هذه المعادلة ان اقول
+
+406
+00:37:09,460 --> 00:37:15,860
+انه is a real polymerاللي هي ال polysaccharides
+
+407
+00:37:15,860 --> 00:37:21,480
+مالتوز منه تلاتمية وحدة او منه مائة الف وحدة في ال
+
+408
+00:37:21,480 --> 00:37:26,640
+glycogen على سبيل المثال او ما إلى ذلك هي وحدة و
+
+409
+00:37:26,640 --> 00:37:32,680
+متكررة لما بدي اجي احكي عن ال protein
+
+410
+00:37:36,730 --> 00:37:43,590
+هلاحظ ان البروتين عبارة عن amino acids عدد كبير من
+
+411
+00:37:43,590 --> 00:37:49,190
+ال amino acids الان كل amino acid من ناحية المبدأ
+
+412
+00:37:49,190 --> 00:37:56,730
+بختلف عن التاني يعني خليني اتخيل ان هذا حقيقة بمثل
+
+413
+00:37:56,730 --> 00:38:03,490
+البروتين الان هذا بقدر احط عليه كذا to the N لأ طب
+
+414
+00:38:03,490 --> 00:38:10,740
+ايش المطلوب اعمله؟أعمله إيش التسلسل تبعه، يعني لو
+
+415
+00:38:10,740 --> 00:38:14,600
+اتخيلت أنا أن هذا بروتين صغير، يعني بيبتايد، بقول
+
+416
+00:38:14,600 --> 00:38:19,700
+لحظة معايا إيش التسلسل تبعه من amino acids، أسود،
+
+417
+00:38:19,700 --> 00:38:27,230
+أخضر، أحمر، أسود، أزرقتمام؟ الآن كل واحد شكل من
+
+418
+00:38:27,230 --> 00:38:29,870
+هدول، يعني هذا في الـ amino acids ممكن يكون
+
+419
+00:38:29,870 --> 00:38:36,990
+إجليسين، ألانين، سيستين، تريبتوفان، كذا، فما بقدرش
+
+420
+00:38:36,990 --> 00:38:38,830
+أصيغه بصيغة
+
+421
+00:38:41,480 --> 00:38:45,080
+amino acid و بعدين اقول عنه to the end فالان
+
+422
+00:38:45,080 --> 00:38:51,640
+تخيلوا لو كان في عندي مثلا protein من 300 amino
+
+423
+00:38:51,640 --> 00:38:58,780
+acid عشان اعرفه جيدا ايش المطلوب مني اعمل احدد ال
+
+424
+00:38:58,780 --> 00:39:04,200
+300 amino acid مرتبين هذا بيسموه ايش؟ sequence
+
+425
+00:39:04,200 --> 00:39:11,930
+يعني كيف هدول مرتبينأعمل التسلسل تبعه، الآن فكرة
+
+426
+00:39:11,930 --> 00:39:16,490
+ال sequence أو التسلسل غير موجودة في ال
+
+427
+00:39:16,490 --> 00:39:21,170
+polysaccharides، ال polysaccharides نفس الشغلة to
+
+428
+00:39:21,170 --> 00:39:28,380
+the Nمالتوز to the M خلصت واضح بينما في ال
+
+429
+00:39:28,380 --> 00:39:33,100
+proteins هتواجهنا صعوبة ان ال proteins وحدتهم
+
+430
+00:39:33,100 --> 00:39:37,660
+الأساسية amino acids ال amino acids عادة اللي
+
+431
+00:39:37,660 --> 00:39:41,720
+موجودين في ال protein عشرين amino acid الان لما
+
+432
+00:39:41,720 --> 00:39:50,400
+يكون عندى protein من تلتمية amino acid كويس
+
+433
+00:39:50,400 --> 00:39:56,960
+في أشياء مكررة لكنلابد من ال sequence هم اكيد هم
+
+434
+00:39:56,960 --> 00:40:00,580
+اكيد عشرين amino acid تقريبا اللي موجودين في ال
+
+435
+00:40:00,580 --> 00:40:07,180
+proteins لكن هدول العشرين لما بدي اخد منهم protein
+
+436
+00:40:07,180 --> 00:40:15,700
+من تلاتمية amino acid كيف هيكونوا؟ هيكونوا
+
+437
+00:40:15,700 --> 00:40:22,050
+مختلفين مافيش ان احك مثلا glycine to the Nعشان
+
+438
+00:40:22,050 --> 00:40:28,290
+اميز اي protein عن التاني لازم اعد ال 300 ولذلك ال
+
+439
+00:40:28,290 --> 00:40:32,950
+protein لو انا بدى اتكلم عنه انه هل هو real
+
+440
+00:40:32,950 --> 00:40:40,870
+polymer يعني حقيقي بمعنى الكلمة الجواب لأ ال real
+
+441
+00:40:40,870 --> 00:40:48,390
+polymer حقيقة ايش هو؟ monomerto the end زي ما
+
+442
+00:40:48,390 --> 00:40:52,770
+شوفنا ال polyethylene و ال PVC و حتى كمان ال
+
+443
+00:40:52,770 --> 00:40:57,750
+polysaccharides مونومر مكرر لكن هنا لما بدي أجي
+
+444
+00:40:57,750 --> 00:41:01,570
+أحكي عن ال protein هصير أجيب ال amino acids أقول
+
+445
+00:41:01,570 --> 00:41:07,910
+glycine, alanine, tryptophan, cysteine كذا كذا
+
+446
+00:41:07,910 --> 00:41:14,270
+هتلاحظوا أنه مطلوب منناانحدد الترتيب تبع ال amino
+
+447
+00:41:14,270 --> 00:41:17,690
+acids ولذلك ال proteins لو الإنسان بده يستعمل
+
+448
+00:41:17,690 --> 00:41:23,010
+الكلام بدقة أكثر they are macro molecules جزيئات
+
+449
+00:41:23,010 --> 00:41:30,490
+كبيرة macro molecules جزيئات كبيرة أكثر منهم إيش
+
+450
+00:41:30,490 --> 00:41:39,610
+polymers they are macro molecules أكثر منهمبولمار
+
+451
+00:41:39,610 --> 00:41:46,310
+طبعا فيهم نوعا ما شيء مشترك بيخلي بعض الناس يقولوا
+
+452
+00:41:46,310 --> 00:41:54,670
+ممكن تجاوزا نعتبر ال protein بولمار ليش؟ لأنه لو
+
+453
+00:41:54,670 --> 00:42:00,010
+أنا اتطلعت على الهيكل تبعه اللي بتكرر هلاحظ ان هو
+
+454
+00:42:00,010 --> 00:42:05,960
+عبارة عن NCEالان هذه الوحدة بتتكرر في البروتين
+
+455
+00:42:05,960 --> 00:42:12,760
+بعدها N C C double bond O بعدها N C C double bond
+
+456
+00:42:12,760 --> 00:42:19,220
+O هتقولولي مش ناقص غير ايش تكتب هذولة to the N طب
+
+457
+00:42:19,220 --> 00:42:25,870
+ليش مش قادر اكتبهم؟لأن كل amino acid فيها R group
+
+458
+00:42:25,870 --> 00:42:33,210
+مختلفة يعني هذه مرة H هذه مرة CH3 هذه مرة CH2SH
+
+459
+00:42:33,210 --> 00:42:40,430
+فلو بتطلع على الهيكل الأساسي للذرات لبروتين NCC
+
+460
+00:42:40,430 --> 00:42:45,870
+double bond O هو مكرر لكن لو طلعت على هذه المجموعة
+
+461
+00:42:46,670 --> 00:42:51,530
+مش مكررة بناء على ذلك لو هذا مثلا كان بيبتايد هذا
+
+462
+00:42:51,530 --> 00:42:55,810
+بيبتايد مكون من كام amino acid من تلاتة هتعلم أن
+
+463
+00:42:55,810 --> 00:43:00,570
+هذا اسمه إجليسين هذا اسمه ألانين هذا اسمه سيستين
+
+464
+00:43:00,570 --> 00:43:05,450
+حصير أقول هذاEglicin, Alanine, Cysteine هيكون بفرق
+
+465
+00:43:05,450 --> 00:43:08,390
+عن Alanine, Eglicin, Cysteine من نفس التلاتة
+
+466
+00:43:08,390 --> 00:43:14,810
+فانفعلكوا لما نصيح نحكي عن تلاتمية فالبروتين بوجهة
+
+467
+00:43:14,810 --> 00:43:19,870
+النظر اللي بده يتطلع الهيكل الأساسي هو كأنه بوليمر
+
+468
+00:43:19,870 --> 00:43:25,170
+امكرر في N, C, C double bond O N, C, C double bond
+
+469
+00:43:25,170 --> 00:43:28,950
+O لكن لما نيجي نلاحظ أن هذه المجموعة اللي هنا
+
+470
+00:43:28,950 --> 00:43:36,740
+اختلفتبطل polymer ولذلك ال polymer مابنعدش ال 300
+
+471
+00:43:36,740 --> 00:43:40,680
+وحدة ولا ال 5000 وحدة تبعته بس ال protein بدي
+
+472
+00:43:40,680 --> 00:43:45,860
+أجهزة و بدي علم يوم أقول هذا protein كذا يذكر لل
+
+473
+00:43:45,860 --> 00:43:54,170
+5000 وحدة مرتبين و نفس الاشي هيتكرر معاكم مهمفي ال
+
+474
+00:43:54,170 --> 00:43:58,670
+nucleic acids عشان هيك في الشفرة الوراثية وغيرها
+
+475
+00:43:58,670 --> 00:44:02,570
+وغيراتها هتلاحظوا ان البني ادم بيختلف عن التاني و
+
+476
+00:44:02,570 --> 00:44:07,270
+الشغل بتختلف عن التاني انه بدي اذكر الأشياء مرتبة
+
+477
+00:44:08,550 --> 00:44:18,550
+كذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+478
+00:44:18,550 --> 00:44:19,230
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+479
+00:44:19,230 --> 00:44:19,250
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+480
+00:44:19,250 --> 00:44:19,450
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+481
+00:44:19,450 --> 00:44:22,470
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+482
+00:44:22,470 --> 00:44:25,070
+وكذا
+
+483
+00:44:25,690 --> 00:44:30,730
+جزيئات كبيرة اكثر من ان نسميها Polymers و نقدر
+
+484
+00:44:30,730 --> 00:44:35,170
+نكتب شغلته دي انا الان حيصير درسنا القادم سهل اللي
+
+485
+00:44:35,170 --> 00:44:39,730
+بده يدرس ال proteins ايش أساسهم اذا اول شئ بدنا
+
+486
+00:44:39,730 --> 00:44:45,310
+نتعلم على ال amino acids بعدين ال amino acids بتحد
+
+487
+00:44:45,310 --> 00:44:48,890
+و بيعملوا ال protein نتعلم كيف نوجد ال sequence و
+
+488
+00:44:48,890 --> 00:44:53,390
+كيف نحضر ال protein لو بدنايالكن حيكون ان شاء الله
+
+489
+00:44:53,390 --> 00:44:58,410
+درسنا القادم على الوحدة المكونة للبروتين اللي هي
+
+490
+00:44:58,410 --> 00:45:00,370
+عبارة عن ايش؟ الامام
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-FzTT8Q4Xi8_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-FzTT8Q4Xi8_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..3ac3e3633704cdcd6730373a7adc2e64ee2ff88c
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-FzTT8Q4Xi8_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2007, "start": 18.78, "end": 20.08, "text": "بسم الله الرحمن الرحيم", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640], "avg_logprob": -0.03093261569738388, "compression_ratio": 1.0789473684210527, "no_speech_prob": 0.0, "words": [{"start": 18.78, "end": 19.08, "word": "بسم", "probability": 0.92578125}, {"start": 19.08, "end": 19.24, "word": " الله", "probability": 0.97021484375}, {"start": 19.24, "end": 19.62, "word": " الرحمن", "probability": 0.9874674479166666}, {"start": 19.62, "end": 20.08, "word": " الرحيم", "probability": 0.9952799479166666}], "temperature": 1.0}, {"id": 2, "seek": 4939, "start": 21.19, "end": 49.39, "text": "بعد ما اتكلمنا المرة الماضية عن السكريات المنفردة اتعرفنا عليها ال mono-saccharides الان بدنا نتكلم عن ال di-saccharides طبعا اللي بنقصده احنا ب di-saccharides انه جزيئين من ال mono-saccharides يتحدوا مع بعض و بيعملوا ايش؟ di-saccharide الان مش دائما مش دائما", "tokens": [3555, 22488, 19446, 1975, 2655, 4117, 19528, 8315, 9673, 25720, 9673, 46958, 10632, 18871, 21136, 4117, 16572, 9307, 9673, 1863, 5172, 2288, 41891, 1975, 2655, 3615, 28480, 8315, 25894, 11296, 2423, 35624, 12, 82, 326, 7374, 1875, 2423, 7649, 47525, 8315, 8717, 2655, 4117, 19528, 18871, 2423, 1026, 12, 82, 326, 7374, 1875, 23032, 3555, 3615, 995, 13672, 1829, 44945, 4587, 9381, 3215, 3224, 1975, 5016, 8315, 4724, 1026, 12, 82, 326, 7374, 1875, 16472, 3224, 10874, 11622, 1829, 19986, 9957, 9154, 2423, 35624, 12, 82, 326, 7374, 1875, 7251, 2655, 24401, 14407, 20449, 45030, 11242, 4032, 4724, 1829, 25957, 1211, 14407, 1975, 1829, 8592, 22807, 1026, 12, 82, 326, 7374, 482, 2423, 7649, 37893, 11778, 16373, 15042, 37893, 11778, 16373, 15042], "avg_logprob": -0.12576218930686392, "compression_ratio": 1.9103773584905661, "no_speech_prob": 0.0, "words": [{"start": 21.19, "end": 21.59, "word": "بعد", "probability": 0.9931640625}, {"start": 21.59, "end": 21.85, "word": " ما", "probability": 0.95947265625}, {"start": 21.85, 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{"start": 221.72, "end": 222.06, "word": " ناخد", "probability": 0.9869791666666666}, {"start": 222.06, "end": 222.54, "word": " الترقيم", "probability": 0.975341796875}, {"start": 222.54, "end": 222.82, "word": " واحد", "probability": 0.74267578125}, {"start": 222.82, "end": 223.16, "word": " اتنين", "probability": 0.951904296875}, {"start": 223.16, "end": 223.68, "word": " تلاتة", "probability": 0.9339599609375}, {"start": 223.68, "end": 224.14, "word": " اربعة", "probability": 0.9267578125}, {"start": 224.14, "end": 224.46, "word": " هذا", "probability": 0.90283203125}, {"start": 224.46, "end": 225.06, "word": " الموقع", "probability": 0.9886067708333334}], "temperature": 1.0}, {"id": 10, "seek": 23752, "start": 226.02, "end": 237.52, "text": "أربعة اتحدوا من خلال هذه ال Oxygenة اللي في موقع أربعة عملوا رابطة واضح فصار عند المركب مكوّن من Alpha و من D", "tokens": [10721, 25513, 27884, 1975, 2655, 24401, 14407, 9154, 16490, 1211, 6027, 29538, 2423, 16489, 8647, 3660, 13672, 1829, 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Alpha D Glucopyranose وشايفين أنها Alpha الآن متحد من موقع أربعة ال Beta D Galactopyranose طبعا بنكتب Beta D Galactopyranose", "tokens": [3615, 8592, 7649, 4117, 45164, 29910, 37983, 8315, 2423, 32277, 2304, 18863, 10943, 8032, 2655, 15040, 5016, 19913, 14407, 8978, 6024, 95, 34740, 20588, 413, 5209, 1311, 19680, 4257, 541, 39896, 2423, 20588, 413, 5209, 1311, 19680, 4257, 541, 4032, 8592, 995, 33911, 9957, 14739, 11296, 20588, 6024, 48506, 44650, 24401, 9154, 3714, 30543, 3615, 5551, 25513, 27884, 2423, 33286, 413, 7336, 578, 19680, 4257, 541, 23032, 3555, 3615, 995, 44945, 4117, 2655, 3555, 33286, 413, 7336, 578, 19680, 4257, 541], "avg_logprob": -0.2639100747864421, "compression_ratio": 1.6127167630057804, "no_speech_prob": 0.0, "words": [{"start": 579.62, "end": 580.2, "word": "عشانك", "probability": 0.697479248046875}, {"start": 580.2, "end": 580.38, "word": " لو", "probability": 0.93017578125}, {"start": 580.38, "end": 581.04, "word": " ذكرنا", "probability": 0.97216796875}, 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{"start": 667.54, "end": 669.26, "word": "-Glucopyranose", "probability": 0.6194370814732143}, {"start": 669.26, "end": 670.3, "word": " هاي", "probability": 0.6343994140625}, {"start": 670.3, "end": 670.6, "word": " Alpha", "probability": 0.744140625}, {"start": 670.6, "end": 670.9, "word": " هذه", "probability": 0.42822265625}, {"start": 670.9, "end": 671.68, "word": " شايفينها؟", "probability": 0.9474283854166666}], "temperature": 1.0}, {"id": 30, "seek": 69913, "start": 674.95, "end": 699.13, "text": "طالما لا أسفل إذا هذه إيش؟ Alpha لكن المرة هذه الاتحاد تبعه مش من موقع أربعة هو متحد ب fractose واضح؟ هو متحد ب fractose و ال fractose keto sugar لما أخدنا السكريات قلنا إن في عندنا ال doses من ال aldehydes", "tokens": [9566, 6027, 15042, 20193, 5551, 3794, 5172, 1211, 11933, 15730, 29538, 11933, 1829, 8592, 22807, 20588, 44381, 9673, 25720, 29538, 2423, 9307, 5016, 18513, 6055, 3555, 3615, 3224, 37893, 9154, 3714, 30543, 3615, 5551, 25513, 27884, 31439, 44650, 24401, 4724, 17948, 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بطلت OH صار الاتحاد من عندها و عشان هيك صارت هذه الرابطة Glycosidic bond فقال غلوكو باي رانوسايد غلوكو باي رانوسايد فالحقيقة", "tokens": [41185, 28242, 13672, 1829, 12174, 36150, 29538, 25961, 2655, 13931, 32771, 1211, 2407, 4117, 2407, 4724, 47302, 12602, 7649, 41779, 8608, 2407, 16606, 25961, 20588, 34051, 33286, 44381, 34105, 4724, 9566, 1211, 2655, 13931, 20328, 9640, 2423, 9307, 5016, 18513, 9154, 43242, 11296, 4032, 6225, 8592, 7649, 39896, 4117, 20328, 9640, 2655, 29538, 34892, 16758, 9566, 3660, 460, 356, 6877, 327, 299, 6086, 6156, 4587, 6027, 32771, 1211, 2407, 4117, 2407, 4724, 47302, 12602, 7649, 41779, 995, 25708, 32771, 1211, 2407, 4117, 2407, 4724, 47302, 12602, 7649, 41779, 995, 25708, 6156, 6027, 5016, 38436, 28671], "avg_logprob": -0.22021484716484943, "compression_ratio": 1.6802030456852792, "no_speech_prob": 0.0, "words": [{"start": 798.74, "end": 798.98, "word": "في", "probability": 0.482421875}, {"start": 798.98, "end": 799.24, "word": " كل", "probability": 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احنا", "probability": 0.9479166666666666}, {"start": 845.23, "end": 845.85, "word": " حقيقة", "probability": 0.8645833333333334}, {"start": 845.85, "end": 846.55, "word": " على", "probability": 0.87109375}, {"start": 846.55, "end": 847.49, "word": " السكروز", "probability": 0.9891357421875}], "temperature": 1.0}, {"id": 37, "seek": 87616, "start": 848.64, "end": 876.16, "text": "كم جليكوسايدك بوند فيه؟ تنتين لو رجعنا اتطلعنا على السكريات اللي قبل هنا كم جليكوسايدك بوند؟ واحدة ماحدش يقول هذه جليكوسايدك بوند ليش؟ لأن الجليكوسايدك بوند اللي بتتكون على الكايرال سنتر الأخير على هذه مش على هذا الموقع أربعة", "tokens": [24793, 10874, 20292, 4117, 41779, 995, 25708, 4117, 4724, 11536, 3215, 8978, 3224, 22807, 6055, 29399, 9957, 45164, 12602, 7435, 3615, 8315, 1975, 2655, 9566, 1211, 3615, 8315, 15844, 21136, 4117, 16572, 9307, 13672, 1829, 12174, 36150, 34105, 9122, 2304, 10874, 20292, 4117, 41779, 995, 25708, 4117, 4724, 11536, 3215, 22807, 36764, 24401, 3660, 19446, 24401, 8592, 7251, 39648, 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رجعت", "tokens": [2407, 46958, 5016, 22807, 37495, 22653, 37893, 1975, 1829, 1975, 2407, 9122, 25513, 11536, 22633, 6877, 327, 299, 6086, 2423, 22633, 6877, 327, 299, 6086, 3714, 43500, 3555, 9566, 3660, 4724, 10721, 1829, 4724, 10721, 1829, 9122, 25513, 11536, 20666, 364, 14301, 299, 5954, 13672, 1829, 25961, 2655, 5551, 3794, 32277, 995, 2423, 16254, 11296, 25708, 4032, 46958, 5016, 22807, 35525, 8848, 23275, 29538, 22633, 6877, 327, 299, 6086, 4724, 3794, 29538, 37893, 22633, 6877, 327, 299, 6086, 4032, 46958, 5016, 22807, 6156, 1211, 2407, 41850, 1975, 7435, 36081, 15844, 2423, 34042, 541, 8978, 472, 22633, 6877, 327, 299, 6086, 45164, 12602, 7435, 34268], "avg_logprob": -0.20788690816788447, "compression_ratio": 1.8181818181818181, "no_speech_prob": 0.0, "words": [{"start": 876.79, "end": 877.57, "word": "واضح؟", "probability": 0.7967529296875}, {"start": 877.57, "end": 877.93, "word": " يعني", "probability": 0.916015625}, {"start": 877.93, "end": 878.55, "word": " مش", 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بيجوا بيعملوا بوليمار كبير لما بيعملوا بوليمار كبير بيكون هم الوحدة الأساسية المتكررة في البوليمار بيعطونا", "tokens": [6027, 3794, 26895, 2407, 4724, 1829, 2407, 11622, 13672, 1829, 12174, 1211, 8315, 18871, 3224, 4724, 36081, 995, 4032, 4724, 36081, 995, 37495, 22653, 16490, 1211, 9957, 995, 8717, 31747, 11622, 1975, 5016, 8315, 15844, 9673, 1211, 2655, 2407, 11622, 9673, 1211, 2655, 2407, 11622, 25961, 9154, 5551, 46538, 3660, 4032, 4724, 36081, 995, 10874, 12610, 2407, 4117, 2407, 11622, 3714, 30544, 4032, 46958, 5016, 22807, 4032, 21136, 26895, 2407, 4724, 1829, 2407, 11622, 9154, 4724, 36081, 995, 4032, 4724, 36081, 995, 10874, 12610, 2407, 4117, 2407, 11622, 6024, 48506, 8032, 3215, 12610, 3660, 5296, 15042, 4724, 1829, 7435, 14407, 4724, 1829, 25957, 1211, 14407, 4724, 12610, 32640, 9640, 9122, 3555, 13546, 5296, 15042, 4724, 1829, 25957, 1211, 14407, 4724, 12610, 32640, 9640, 9122, 3555, 13546, 4724, 1829, 30544, 8032, 2304, 2423, 2407, 24401, 3660, 16247, 3794, 32277, 10632, 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"probability": 0.88720703125}, {"start": 1424.69, "end": 1425.01, "word": " بين", "probability": 0.98974609375}, {"start": 1425.01, "end": 1426.07, "word": " خمسين", "probability": 0.9532470703125}, {"start": 1426.07, "end": 1426.39, "word": " إلى", "probability": 0.76611328125}, {"start": 1426.39, "end": 1427.41, "word": " تلتمية", "probability": 0.83671875}, {"start": 1427.41, "end": 1428.31, "word": " geolocose", "probability": 0.8118896484375}, {"start": 1428.31, "end": 1428.71, "word": " unit", "probability": 0.7314453125}, {"start": 1428.71, "end": 1430.91, "word": " والاتحاد", "probability": 0.907958984375}, {"start": 1430.91, "end": 1431.09, "word": " زي", "probability": 0.82275390625}, {"start": 1431.09, "end": 1431.15, "word": " ما", "probability": 0.978515625}, {"start": 1431.15, "end": 1431.41, "word": " انتوا", "probability": 0.7928059895833334}, {"start": 1431.41, "end": 1431.81, "word": " عارفين", "probability": 0.9886474609375}, {"start": 1431.81, "end": 1432.77, 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"end": 1491.32, "word": " خمستلاف", "probability": 0.826123046875}, {"start": 1491.32, "end": 1491.9, "word": " جولوكوز", "probability": 0.8601888020833334}, {"start": 1491.9, "end": 1492.3, "word": " units", "probability": 0.5771484375}, {"start": 1492.3, "end": 1492.84, "word": " يعني", "probability": 0.883544921875}, {"start": 1492.84, "end": 1493.46, "word": " الجولوكوز", "probability": 0.9373372395833334}, {"start": 1493.46, "end": 1493.88, "word": " units", "probability": 0.9228515625}, {"start": 1493.88, "end": 1494.26, "word": " اللى", "probability": 0.861083984375}, {"start": 1494.26, "end": 1494.46, "word": " في", "probability": 0.7919921875}, {"start": 1494.46, "end": 1495.16, "word": " عددها", "probability": 0.88330078125}, {"start": 1495.16, "end": 1495.94, "word": " اكبر", "probability": 0.8914388020833334}, {"start": 1495.94, "end": 1496.6, "word": " لكن", "probability": 0.8525390625}, {"start": 1496.6, "end": 1497.06, "word": " اهم", "probability": 0.957763671875}, {"start": 1497.06, "end": 1497.56, "word": " شغل", "probability": 0.7736002604166666}, {"start": 1497.56, "end": 1498.18, "word": " فيه", "probability": 0.723388671875}, {"start": 1498.18, "end": 1499.86, "word": " is", "probability": 0.55029296875}, {"start": 1499.86, "end": 1500.94, "word": " هايلبراجد", "probability": 0.5816243489583334}, {"start": 1500.94, "end": 1501.68, "word": " واضح", "probability": 0.8636067708333334}, {"start": 1501.68, "end": 1502.46, "word": " يعني", "probability": 0.693115234375}, {"start": 1502.46, "end": 1503.54, "word": " الاميلوز", "probability": 0.97587890625}, {"start": 1503.54, "end": 1504.8, "word": " سلسلة", "probability": 0.9918212890625}], "temperature": 1.0}, {"id": 64, "seek": 153058, "start": 1505.64, "end": 1530.58, "text": "الـ amylobectin في تفرعات يعني تقريبا لاحظوا الـ amylose بين 300 إلى 5000 جولوكوز units is a highly branched molecule او highly branched molecule chains with consecutive one four links شوفنا كيف one four links الارتباط ال average يعني كل مجموعة حوالي خمسة وعشرين لتلاتين وحدة", "tokens": [6027, 39184, 669, 5088, 996, 557, 259, 8978, 6055, 5172, 2288, 3615, 9307, 37495, 22653, 6055, 4587, 16572, 3555, 995, 20193, 5016, 19913, 14407, 2423, 39184, 669, 5088, 541, 49374, 6641, 30731, 23777, 10874, 12610, 2407, 4117, 2407, 11622, 6815, 307, 257, 5405, 9819, 292, 15582, 1975, 2407, 5405, 9819, 292, 15582, 12626, 365, 30497, 472, 1451, 6123, 13412, 38688, 8315, 9122, 33911, 472, 1451, 6123, 2423, 9640, 2655, 3555, 41193, 2423, 4274, 37495, 22653, 28242, 3714, 7435, 2304, 2407, 27884, 11331, 2407, 6027, 1829, 16490, 2304, 3794, 3660, 4032, 3615, 46309, 9957, 5296, 2655, 1211, 9307, 9957, 4032, 24401, 3660], "avg_logprob": -0.2553615052910412, "compression_ratio": 1.5222672064777327, "no_speech_prob": 0.0, "words": [{"start": 1505.64, "end": 1505.94, "word": "الـ", "probability": 0.4827880859375}, {"start": 1505.94, "end": 1506.92, "word": " amylobectin", "probability": 0.76015625}, {"start": 1506.92, "end": 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1527.14, "word": " يعني", "probability": 0.985595703125}, {"start": 1527.14, "end": 1527.38, "word": " كل", "probability": 0.9609375}, {"start": 1527.38, "end": 1528.04, "word": " مجموعة", "probability": 0.94873046875}, {"start": 1528.04, "end": 1528.52, "word": " حوالي", "probability": 0.96630859375}, {"start": 1528.52, "end": 1528.84, "word": " خمسة", "probability": 0.7772216796875}, {"start": 1528.84, "end": 1529.32, "word": " وعشرين", "probability": 0.8521728515625}, {"start": 1529.32, "end": 1530.0, "word": " لتلاتين", "probability": 0.88154296875}, {"start": 1530.0, "end": 1530.58, "word": " وحدة", "probability": 0.8484700520833334}], "temperature": 1.0}, {"id": 65, "seek": 155705, "start": 1532.37, "end": 1557.05, "text": "و بعدين بيجي تفرع 25 ل 30 و تفرع بيصير الجزء أشماله highly branched واضح فواضح أن جزء ال amylobectin أكبر من ال amylose و بنفس الوقت اللي بيميزه التفرعات واضح فال amylose is a chain molecule", "tokens": [2407, 39182, 9957, 4724, 1829, 7435, 1829, 6055, 5172, 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"probability": 0.463134765625}, {"start": 1543.37, "end": 1543.89, "word": " جزء", "probability": 0.9052734375}, {"start": 1543.89, "end": 1544.05, "word": " ال", "probability": 0.8408203125}, {"start": 1544.05, "end": 1545.19, "word": " amylobectin", "probability": 0.74677734375}, {"start": 1545.19, "end": 1546.21, "word": " أكبر", "probability": 0.9571940104166666}, {"start": 1546.21, "end": 1547.23, "word": " من", "probability": 0.98583984375}, {"start": 1547.23, "end": 1547.49, "word": " ال", "probability": 0.927734375}, {"start": 1547.49, "end": 1548.17, "word": " amylose", "probability": 0.8771158854166666}, {"start": 1548.17, "end": 1548.47, "word": " و", "probability": 0.8310546875}, {"start": 1548.47, "end": 1548.85, "word": " بنفس", "probability": 0.7275390625}, {"start": 1548.85, "end": 1549.51, "word": " الوقت", "probability": 0.9814453125}, {"start": 1549.51, "end": 1550.47, "word": " اللي", "probability": 0.885498046875}, {"start": 1550.47, "end": 1551.25, "word": " بيميزه", "probability": 0.947265625}, {"start": 1551.25, "end": 1553.07, "word": " التفرعات", "probability": 0.9775390625}, {"start": 1553.07, "end": 1553.77, "word": " واضح", "probability": 0.7765299479166666}, {"start": 1553.77, "end": 1554.37, "word": " فال", "probability": 0.82666015625}, {"start": 1554.37, "end": 1555.15, "word": " amylose", "probability": 0.8782552083333334}, {"start": 1555.15, "end": 1555.93, "word": " is", "probability": 0.8837890625}, {"start": 1555.93, "end": 1556.11, "word": " a", "probability": 0.62451171875}, {"start": 1556.11, "end": 1556.45, "word": " chain", "probability": 0.70361328125}, {"start": 1556.45, "end": 1557.05, "word": " molecule", "probability": 0.818359375}], "temperature": 1.0}, {"id": 66, "seek": 158206, "start": 1558.1, "end": 1582.06, "text": "الـ amylobectin هو جزئ عالي جزئ فيه تفرعات كتيرة طبعا هذه كل أشكال تقريبية بتوضح لنا كيف بيتكونوا هذول الجزيئات الأن لو جينا من ال amylose أيضا", "tokens": [6027, 39184, 669, 5088, 996, 557, 259, 31439, 10874, 11622, 19986, 6225, 6027, 1829, 10874, 11622, 19986, 8978, 3224, 6055, 5172, 2288, 3615, 9307, 9122, 2655, 48923, 23032, 3555, 3615, 995, 29538, 28242, 5551, 8592, 4117, 6027, 6055, 4587, 16572, 3555, 10632, 39894, 2407, 11242, 5016, 5296, 8315, 9122, 33911, 4724, 36081, 30544, 14407, 8032, 8848, 12610, 25724, 11622, 1829, 19986, 9307, 16247, 1863, 45164, 10874, 1829, 8315, 9154, 2423, 669, 5088, 541, 36632, 11242, 995], "avg_logprob": -0.34111202072787594, "compression_ratio": 1.4578313253012047, "no_speech_prob": 0.0, "words": [{"start": 1558.1, "end": 1558.54, "word": "الـ", "probability": 0.656494140625}, {"start": 1558.54, "end": 1559.6, "word": " amylobectin", "probability": 0.7111328125}, {"start": 1559.6, "end": 1560.32, "word": " هو", "probability": 0.360107421875}, {"start": 1560.32, "end": 1561.3, "word": " جزئ", "probability": 0.6035970052083334}, {"start": 1561.3, "end": 1561.5, "word": " عالي", "probability": 0.4833984375}, {"start": 1561.5, "end": 1562.22, "word": " جزئ", "probability": 0.5435384114583334}, {"start": 1562.22, "end": 1564.36, "word": " فيه", "probability": 0.5411376953125}, {"start": 1564.36, "end": 1565.08, "word": " تفرعات", "probability": 0.91865234375}, {"start": 1565.08, "end": 1565.58, "word": " كتيرة", "probability": 0.8229166666666666}, {"start": 1565.58, "end": 1566.64, "word": " طبعا", "probability": 0.93408203125}, {"start": 1566.64, "end": 1567.38, "word": " هذه", "probability": 0.391845703125}, {"start": 1567.38, "end": 1567.66, "word": " كل", "probability": 0.97021484375}, {"start": 1567.66, "end": 1568.1, "word": " أشكال", "probability": 0.9420166015625}, {"start": 1568.1, "end": 1568.98, "word": " تقريبية", "probability": 0.96083984375}, {"start": 1568.98, "end": 1571.52, "word": " بتوضح", "probability": 0.85791015625}, {"start": 1571.52, "end": 1571.86, "word": " لنا", "probability": 0.875}, {"start": 1571.86, "end": 1572.26, "word": " كيف", "probability": 0.974853515625}, {"start": 1572.26, "end": 1573.02, "word": " بيتكونوا", "probability": 0.63775634765625}, {"start": 1573.02, "end": 1573.5, "word": " هذول", "probability": 0.7300618489583334}, {"start": 1573.5, "end": 1574.42, "word": " الجزيئات", "probability": 0.74697265625}, {"start": 1574.42, "end": 1577.34, "word": " الأن", "probability": 0.6302490234375}, {"start": 1577.34, "end": 1579.32, "word": " لو", "probability": 0.93896484375}, {"start": 1579.32, "end": 1579.88, "word": " جينا", "probability": 0.7211100260416666}, {"start": 1579.88, "end": 1580.56, "word": " من", "probability": 0.970703125}, {"start": 1580.56, "end": 1580.72, "word": " ال", "probability": 0.89990234375}, {"start": 1580.72, "end": 1581.46, "word": " amylose", "probability": 0.5750325520833334}, {"start": 1581.46, "end": 1582.06, "word": " أيضا", "probability": 0.9630533854166666}], "temperature": 1.0}, {"id": 67, "seek": 160363, "start": 1583.21, "end": 1603.63, "text": "غير النشق بمكوينه يعني من الملتوز كان في عنده ال starch اللي هو مكوّن من 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"انحدد الترتيب تبع ال amino acids ولذلك ال proteins لو الإنسان بده يستعمل الكلام بدقة أكثر they are macro molecules جزيئات كبيرة macro molecules جزيئات كبيرة أكثر منهم إيش polymers they are macro molecules أكثر منهم", "tokens": [7649, 24401, 3215, 16712, 2288, 31371, 3555, 6055, 3555, 3615, 2423, 24674, 21667, 35525, 8848, 23275, 2423, 15577, 45164, 33688, 1863, 3794, 7649, 47525, 3224, 7251, 14851, 25957, 1211, 2423, 28820, 10943, 47525, 28671, 5551, 4117, 49115, 436, 366, 18887, 13093, 10874, 11622, 1829, 19986, 9307, 9122, 3555, 48923, 18887, 13093, 10874, 11622, 1829, 19986, 9307, 9122, 3555, 48923, 5551, 4117, 49115, 9154, 16095, 11933, 1829, 8592, 6754, 18552, 436, 366, 18887, 13093, 5551, 4117, 49115, 9154, 16095], "avg_logprob": -0.1799841821193695, "compression_ratio": 1.718232044198895, "no_speech_prob": 0.0, "words": [{"start": 2471.97, "end": 2472.71, "word": "انحدد", "probability": 0.8234049479166666}, {"start": 2472.71, "end": 2473.43, "word": " الترتيب", "probability": 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"probability": 0.95849609375}, {"start": 2508.85, "end": 2509.63, "word": " ال", "probability": 0.888671875}, {"start": 2509.63, "end": 2510.27, "word": " protein", "probability": 0.65673828125}, {"start": 2510.27, "end": 2511.81, "word": " بولمار", "probability": 0.8533935546875}, {"start": 2511.81, "end": 2513.13, "word": " ليش؟", "probability": 0.6341959635416666}, {"start": 2513.13, "end": 2513.77, "word": " لأنه", "probability": 0.859375}, {"start": 2513.77, "end": 2514.67, "word": " لو", "probability": 0.9716796875}, {"start": 2514.67, "end": 2514.95, "word": " أنا", "probability": 0.66015625}, {"start": 2514.95, "end": 2515.79, "word": " اتطلعت", "probability": 0.83837890625}, {"start": 2515.79, "end": 2516.47, "word": " على", "probability": 0.888671875}, {"start": 2516.47, "end": 2517.33, "word": " الهيكل", "probability": 0.886962890625}, {"start": 2517.33, "end": 2517.89, "word": " تبعه", "probability": 0.886474609375}, {"start": 2517.89, "end": 2518.03, "word": " اللي", "probability": 0.945556640625}, {"start": 2518.03, "end": 2518.81, "word": " بتكرر", "probability": 0.9513346354166666}, {"start": 2518.81, "end": 2519.63, "word": " هلاحظ", "probability": 0.865966796875}, {"start": 2519.63, "end": 2519.79, "word": " ان", "probability": 0.53564453125}, {"start": 2519.79, "end": 2520.01, "word": " هو", "probability": 0.83544921875}, {"start": 2520.01, "end": 2520.49, "word": " عبارة", "probability": 0.9896240234375}, {"start": 2520.49, "end": 2520.67, "word": " عن", "probability": 0.9755859375}, {"start": 2520.67, "end": 2521.69, "word": " NCE", "probability": 0.3619384765625}], "temperature": 1.0}, {"id": 107, "seek": 254069, "start": 2523.32, "end": 2540.7, "text": "الان هذه الوحدة بتتكرر في البروتين بعدها N C C double bond O بعدها N C C double bond O هتقولولي مش ناقص غير ايش تكتب هذولة to the N طب ليش مش قادر اكتبهم؟", "tokens": [6027, 7649, 29538, 2423, 2407, 24401, 3660, 39894, 2655, 37983, 2288, 8978, 2423, 26890, 35473, 9957, 39182, 11296, 426, 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5000 وحدة مرتبين و نفس الاشي هيتكرر معاكم مهم", "tokens": [3555, 9566, 1211, 6754, 936, 35525, 8848, 23275, 2423, 6754, 936, 3714, 16758, 1863, 22488, 8592, 2423, 6641, 4032, 24401, 3660, 49429, 2423, 23777, 4032, 24401, 3660, 6055, 3555, 34268, 3224, 4724, 3794, 2423, 7944, 4724, 16254, 5551, 7435, 3224, 11622, 3660, 4032, 4724, 16254, 11203, 2304, 7251, 20498, 5551, 39648, 23758, 7944, 9122, 15730, 7251, 8848, 37983, 24976, 23777, 4032, 24401, 3660, 3714, 43500, 3555, 9957, 4032, 8717, 36178, 2423, 33599, 1829, 8032, 36081, 37983, 2288, 20449, 995, 24793, 3714, 16095], "avg_logprob": -0.20350151069193, "compression_ratio": 1.6404494382022472, "no_speech_prob": 0.0, "words": [{"start": 2611.4, "end": 2611.86, "word": "بطل", "probability": 0.7713216145833334}, {"start": 2611.86, "end": 2612.34, "word": " polymer", "probability": 0.35028076171875}, {"start": 2612.34, "end": 2614.04, "word": " ولذلك", "probability": 0.85693359375}, {"start": 2614.04, "end": 2614.52, "word": " ال", 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0.8138020833333334}, {"start": 2697.35, "end": 2698.09, "word": " للبروتين", "probability": 0.8984375}, {"start": 2698.09, "end": 2698.23, "word": " اللي", "probability": 0.68505859375}, {"start": 2698.23, "end": 2698.41, "word": " هي", "probability": 0.85009765625}, {"start": 2698.41, "end": 2698.79, "word": " عبارة", "probability": 0.9921875}, {"start": 2698.79, "end": 2699.01, "word": " عن", "probability": 0.9814453125}, {"start": 2699.01, "end": 2700.09, "word": " ايش؟", "probability": 0.6593017578125}, {"start": 2700.09, "end": 2700.37, "word": " الامام", "probability": 0.4725341796875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2700.89875, "duration_after_vad": 2612.6406249999914}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-FzTT8Q4Xi8_raw.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-FzTT8Q4Xi8_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..82a5200cf7ab9e0e4c85df14d592edc3c2b33801
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-FzTT8Q4Xi8_raw.srt
@@ -0,0 +1,1960 @@
+1
+00:00:18,780 --> 00:00:24,830
+بسم الله الرحمن الرحيمبعد ما اتكلمنا المرة الماضية
+
+2
+00:00:24,830 --> 00:00:29,410
+عن السكريات المنفردة اتعرفنا عليها ال mono
+
+3
+00:00:29,410 --> 00:00:34,750
+-saccharides الان بدنا نتكلم عن ال di-saccharides
+
+4
+00:00:34,750 --> 00:00:39,930
+طبعا اللي بنقصده احنا ب di-saccharides انه جزيئين
+
+5
+00:00:39,930 --> 00:00:43,910
+من ال mono-saccharides يتحدوا مع بعض و بيعملوا
+
+6
+00:00:43,910 --> 00:00:51,360
+ايش؟ di-saccharide الان مش دائما مش دائمامش دائما
+
+7
+00:00:51,360 --> 00:00:54,820
+هدول الجزيئين اللي بدهم يتحدوا مع بعض بيكونوا زي
+
+8
+00:00:54,820 --> 00:01:00,140
+بعض يعني يوم بدأ احكي انا عن دايسا كرايد ممكن اجيب
+
+9
+00:01:00,140 --> 00:01:06,260
+نفس الجزيئين تماما بكل محتوياتهم طبعا بالتأكيد ال
+
+10
+00:01:06,260 --> 00:01:09,680
+stereo chemistry تكون نفس الشيء تماما و يعملوا
+
+11
+00:01:09,680 --> 00:01:14,040
+دايسا كرايد و ممكن اجيب جزيئين مختلفين و يعملوا
+
+12
+00:01:14,040 --> 00:01:19,820
+دايسا كرايد فمش ضروريمش ضروري ان الـ disaccharide
+
+13
+00:01:19,820 --> 00:01:26,240
+يكون مكوّن من الجزيئين نفسهم تماما، واضح؟ يعني
+
+14
+00:01:26,240 --> 00:01:30,560
+ممكن يكون فعلا من نفس الجزيئين مكوّن disaccharide
+
+15
+00:01:30,560 --> 00:01:36,920
+وممكن يكون من جزيئين مختلفين وهذا اللي هنشوفه لما
+
+16
+00:01:36,920 --> 00:01:45,550
+نستعرض بعض الـ disaccharides بشكل عام ويعني جداأول
+
+17
+00:01:45,550 --> 00:01:51,710
+دايسا كارايد بدنا نستعرضه المالتوز، واضح؟
+
+18
+00:01:51,710 --> 00:01:57,970
+المالتوز، الآن هذا الديسا كارايد مكون من سكرين
+
+19
+00:01:57,970 --> 00:02:03,070
+جولوكوز، لكن فيهم اختلاف في ال stereo chemistry
+
+20
+00:02:03,470 --> 00:02:08,830
+فيهم اختلاف في ال stereo chemistry واحد منهم واحد
+
+21
+00:02:08,830 --> 00:02:14,730
+منهم alpha glucose والتاني منهم beta glucose الآن
+
+22
+00:02:14,730 --> 00:02:19,390
+اللي بتذكروا معنا قولنا احنا ان ال alpha و ال beta
+
+23
+00:02:19,390 --> 00:02:24,930
+sugars بصيروا لما نسكر اخر carbon اللي سمناها ال
+
+24
+00:02:24,930 --> 00:02:29,300
+anomeric carbon و نعملفي حالة السكريات هذه الميزات
+
+25
+00:02:29,300 --> 00:02:35,240
+الكربونات ال fifth chiral center فإذا ال OH كانت
+
+26
+00:02:35,240 --> 00:02:40,020
+للأسفل على هذا الكربون تحديدا بنقول هذا السكر
+
+27
+00:02:40,020 --> 00:02:46,120
+Alpha وإذا كانت للأعلى Beta الآن هذا ال maltose لو
+
+28
+00:02:46,120 --> 00:02:50,760
+بتطلع عليه أنا هيمكون من سكر متصل في ال anomeric
+
+29
+00:02:50,760 --> 00:02:54,560
+carbon لاحظوا أنا تركيزي على أي كربون ال anomeric
+
+30
+00:02:54,560 --> 00:02:59,820
+carbon نكون معلمينها إلى أساساهذه السكرين المتحدين
+
+31
+00:02:59,820 --> 00:03:07,180
+الآن اتطلعوا على واحد منهم ال oxygen فيه alpha
+
+32
+00:03:07,180 --> 00:03:18,840
+واضح التاني منهم ال oxygen فيه betaواضح فالملتوز
+
+33
+00:03:18,840 --> 00:03:24,740
+بيكون في هذه الحالة امكون من Alpha-Glucose مع Beta
+
+34
+00:03:24,740 --> 00:03:29,660
+-Glucose هى دول اتنين قبل ما يتصلوا مع بعض هذا
+
+35
+00:03:29,660 --> 00:03:35,440
+بهذا الشكل كان OH كان Alpha-Glucose هذا كان Beta
+
+36
+00:03:35,440 --> 00:03:41,320
+-Glucose فاتنين اتصلوا مع بعض من خلال موقع اربعة
+
+37
+00:03:41,320 --> 00:03:45,060
+لما ناخد الترقيم واحد اتنين تلاتة اربعة هذا الموقع
+
+38
+00:03:46,020 --> 00:03:49,540
+أربعة اتحدوا من خلال هذه ال Oxygenة اللي في موقع
+
+39
+00:03:49,540 --> 00:03:55,920
+أربعة عملوا رابطة واضح فصار عند المركب مكوّن من
+
+40
+00:03:55,920 --> 00:04:03,040
+Alpha و من Dبيتا جولوكوز وعشان هيك لما بدنا نسميه
+
+41
+00:04:03,040 --> 00:04:09,900
+ممكن انه نقرأ الاسم تبعه هتحسوا انه مش صعب هو ممكن
+
+42
+00:04:09,900 --> 00:04:15,120
+تتخيلوا مركب بيتا جولوكوز لو حطيت ع موقع اربعة مثل
+
+43
+00:04:15,120 --> 00:04:19,960
+شو كنتوا هتسموه four مثل بيتا جولوكوز
+
+44
+00:04:23,450 --> 00:04:29,690
+الاسم الـ Beta في آخر الكلام Beta-D-Glucobiranose
+
+45
+00:04:29,690 --> 00:04:35,170
+مش سمناه لأن جولوكوزم سكرة حلقة سداسية
+
+46
+00:04:35,170 --> 00:04:40,030
+Glucobiranose وD و Beta لأن هذه موجودة في الوضع
+
+47
+00:04:40,030 --> 00:04:45,410
+Beta الآن هذا على موقع أربعة هي على موقع أربعة من
+
+48
+00:04:45,410 --> 00:04:50,950
+خلال ال Oxygen متحد بإيش ب Alpha-D-Glucobiranose
+
+49
+00:04:51,620 --> 00:04:57,800
+واضح الفكرة؟ فيذكر الاسم العام على موقع أربعة من
+
+50
+00:04:57,800 --> 00:05:05,690
+هذا السكر، إيش موجود عنده على موقع أربعة؟الفا دي
+
+51
+00:05:05,690 --> 00:05:08,890
+جلوكو بايرانوس طبعا اتصاله من خلال ال O عشان هيك
+
+52
+00:05:08,890 --> 00:05:13,490
+كتبنا O فاللي بده يفهم الاسم الاسم مش صعب انه هاي
+
+53
+00:05:13,490 --> 00:05:18,290
+المركب اللي عندى بيتا جلوكو بايرانوس على موقع
+
+54
+00:05:18,290 --> 00:05:22,650
+اربعة منه ايش ايجا نعتبرها بين قوسينAlpha
+
+55
+00:05:22,650 --> 00:05:28,230
+Glucobiranose فهذا سكر الملتوز ببساطة هذه الأشياء
+
+56
+00:05:28,230 --> 00:05:34,030
+بيبقى تفهموا فيها الأفكار العامة فالملتوز من سكرين
+
+57
+00:05:34,030 --> 00:05:38,350
+جولوكوز لكن اتنين مش Alpha Alpha ولا Beta Beta
+
+58
+00:05:38,350 --> 00:05:46,590
+Alpha مع Betaالان بيجيني سكر تاني السيلو بيوز
+
+59
+00:05:46,590 --> 00:05:55,730
+السيلو بيوز متحد من سكرين متفقين تماما بيتا جلوكو
+
+60
+00:05:55,730 --> 00:06:00,550
+بيرانوز مع بيتا جلوكو بيرانوز واضح؟ ولذلك لو انا
+
+61
+00:06:00,550 --> 00:06:07,550
+بدأ اطلع على هذا السكر هذا بيتا ولا لا؟ بيتا وعلى
+
+62
+00:06:07,550 --> 00:06:14,780
+هذا السكرهذه أيضًا Beta فلما بنسميه نسبة لهذا Beta
+
+63
+00:06:14,780 --> 00:06:20,740
+D Glucopyranose متحد من موقع أربعةواحد اتنين تلاتة
+
+64
+00:06:20,740 --> 00:06:25,880
+اربعة متحد من موقع اربعة من خلال ال oxygen ال beta
+
+65
+00:06:25,880 --> 00:06:31,160
+D-glucobiranose واضح يعني هذا كأننا بنقول beta D
+
+66
+00:06:31,160 --> 00:06:36,660
+-glucobiranose يحمل على موقع اربعة beta D
+
+67
+00:06:36,660 --> 00:06:42,100
+-glucobiranose واضح الفكرة فال cellobiose بيكون من
+
+68
+00:06:42,100 --> 00:06:50,330
+سكرين متماثلينتماما، لاحظوا قداش نسبة الخلاف اللي
+
+69
+00:06:50,330 --> 00:06:56,450
+بتعمل يعني مركبات مختلفة، يعني انا بحكي عن
+
+70
+00:06:56,450 --> 00:07:02,330
+Glucopyranose و Glucopyranose و بحكي عن هذا Beta
+
+71
+00:07:02,330 --> 00:07:06,870
+في الحالتين، بس التاني مرة Beta و مرة ايش Alpha
+
+72
+00:07:07,710 --> 00:07:14,870
+خلاف بسيط جدا بس كايرال سنتر واحد، الآن بعد شوية
+
+73
+00:07:14,870 --> 00:07:19,770
+هتكتشفوا ان هذا الخلاف البسيط جدا في كايرال سنتر
+
+74
+00:07:19,770 --> 00:07:26,510
+الوحيد بيتبع خلاف كبير جدا جدا جدا في الخواص بعد
+
+75
+00:07:26,510 --> 00:07:31,760
+ذلك للمراكباتيعني لما ييجيوا الجزيئات الـ
+
+76
+00:07:31,760 --> 00:07:35,200
+disaccharides بدهم يعملوا polysaccharides هاي
+
+77
+00:07:35,200 --> 00:07:38,540
+disaccharide و خلّينا نعتبر هاي كمان disaccharide
+
+78
+00:07:38,540 --> 00:07:43,120
+هذا كان من Beta و Beta و هذا كان من Beta و Alpha
+
+79
+00:07:43,120 --> 00:07:47,660
+الان اللي كان من Alpha و Beta الملتوز بيعمل جزئ
+
+80
+00:07:47,660 --> 00:07:56,080
+كبير اسمه نشا او glycogenاللي هي تخزين أو أماكن
+
+81
+00:07:56,080 --> 00:07:59,380
+تخزين ال carbohydrates سواء في النبات أو في
+
+82
+00:07:59,380 --> 00:08:03,400
+الحيوان وهذه بتدوب في الميه وبيقدر البني آدم
+
+83
+00:08:03,400 --> 00:08:07,000
+يهضمها يعني البني آدم لما بياكل النشويات بيقدر
+
+84
+00:08:07,000 --> 00:08:12,180
+بسهولة يحللها للسكريات الأولية بتاعتها أكيد الآن
+
+85
+00:08:12,180 --> 00:08:16,060
+اللي مكوّن من ال beta و ال beta هيجي يعمل ال
+
+86
+00:08:16,060 --> 00:08:20,600
+cellulose هيعمل الخشب البني آدم بيقدرش يهضم الخشب
+
+87
+00:08:20,600 --> 00:08:27,570
+الآن هتيجي تقوله شو الفرق؟بين أساس الخشب و أساس
+
+88
+00:08:27,570 --> 00:08:33,270
+النشا أساس الخشب cellobiose و اتحد و أعطاني
+
+89
+00:08:33,270 --> 00:08:39,110
+cellulose و أساس النشا الملتوز و أعطاني starch
+
+90
+00:08:39,110 --> 00:08:46,230
+واضح فقط مختلفين هدول الاتنين بواحد من السكريات
+
+91
+00:08:46,230 --> 00:08:49,770
+جولوكوز جولوكوز صح جولوكوز جولوكوز بس هذا beta و
+
+92
+00:08:49,770 --> 00:08:55,240
+beta هذا beta و alphaمخيلوا كيف اختلاف بسيط في ال
+
+93
+00:08:55,240 --> 00:09:00,740
+stereochemistry بيقدر الاختلاف كبير بعد هيك في
+
+94
+00:09:00,740 --> 00:09:05,480
+الخواص و في الاستفادة من المركبات بيجينا سكر
+
+95
+00:09:05,480 --> 00:09:15,960
+الحليب ال lactoseاللاكتوز أيضا في جولوكوز لكن في
+
+96
+00:09:15,960 --> 00:09:20,900
+جالاكتوز يعني هدولا ال stereo chemical centers
+
+97
+00:09:20,900 --> 00:09:26,320
+اتغير فيهم اكتر كل الفروقات بينهم هي فروقات ايش
+
+98
+00:09:26,320 --> 00:09:30,500
+لحتى لها ال stereo chemistry يعني هذه الوحدة مش
+
+99
+00:09:30,500 --> 00:09:36,340
+بيتا جولوكوز في هذه الحالة الفا جولوكوز متحد مع
+
+100
+00:09:36,340 --> 00:09:42,300
+بيتا جالاكتوزعشانك لو ذكرنا الاسم العام هتلاحظوا
+
+101
+00:09:42,300 --> 00:09:47,260
+في الآخر Alpha D Glucopyranose هي ال Alpha D
+
+102
+00:09:47,260 --> 00:09:54,480
+Glucopyranose وشايفين أنها Alpha الآن متحد من موقع
+
+103
+00:09:54,480 --> 00:10:01,340
+أربعة ال Beta D Galactopyranose طبعا بنكتب Beta D
+
+104
+00:10:01,340 --> 00:10:07,450
+Galactopyranoseال YL اللي هي بصفته أصبح مجموعة زي
+
+105
+00:10:07,450 --> 00:10:14,330
+ما بقول مثل اثل بروبل ال YL لأنه أصبح مجموعة واضحة
+
+106
+00:10:14,330 --> 00:10:20,630
+الفكرة؟ هذا ال lactose طبعا بيجي صاحبنا، مين
+
+107
+00:10:20,630 --> 00:10:27,330
+صاحبنا؟السكاروز ماحدش اقول عن السكاروز العدو
+
+108
+00:10:27,330 --> 00:10:33,030
+تبعنا، يعني في ناس دائما متطرفين في الحكم على اللي
+
+109
+00:10:33,030 --> 00:10:37,090
+هي هذه الأشياء، كل هذه السكريات و كل حتى الدهون
+
+110
+00:10:37,090 --> 00:10:40,730
+بتلزم للإنسان، بس المشكلة مش أن الإنسان ياخد
+
+111
+00:10:40,730 --> 00:10:45,340
+سكريات و ياخد دهونالمشكلة أنه ياخدها بإفراط يعني
+
+112
+00:10:45,340 --> 00:10:49,160
+الإنسان بحاجة للسكريات، بحاجة للدهون بالتأكيد،
+
+113
+00:10:49,160 --> 00:10:53,940
+بحاجة للكلسترول، بحاجة لكل إشي لكن الإفراط في أي
+
+114
+00:10:53,940 --> 00:10:58,840
+شغل هو اللي بيعمل عندنا إيش المشكلة الآن لو إجينا
+
+115
+00:10:58,840 --> 00:11:02,640
+اتطلعنا على السكروز اللي هو السكر اللي إحنا
+
+116
+00:11:02,640 --> 00:11:07,540
+بنستعمله هتلاحظوا مرة تانية في عندى Alpha
+
+117
+00:11:07,540 --> 00:11:11,680
+-Glucopyranose هاي Alpha هذه شايفينها؟
+
+118
+00:11:14,950 --> 00:11:19,930
+طالما لا أسفل إذا هذه إيش؟ Alpha لكن المرة هذه
+
+119
+00:11:19,930 --> 00:11:27,030
+الاتحاد تبعه مش من موقع أربعة هو متحد ب fractose
+
+120
+00:11:27,030 --> 00:11:33,390
+واضح؟ هو متحد ب fractose و ال fractose keto sugar
+
+121
+00:11:33,390 --> 00:11:38,370
+لما أخدنا السكريات قلنا إن في عندنا ال doses من ال
+
+122
+00:11:38,370 --> 00:11:43,920
+aldehydesو Ketosis لفراكتوز كيتو شوجار و لما بيسكر
+
+123
+00:11:43,920 --> 00:11:50,240
+بيسكر على السكر خماسي السكر الخماسي فيورانوز و من
+
+124
+00:11:50,240 --> 00:11:56,020
+الفيورانوز متحد من موقع ايش؟ واحد واضح؟ الان هذا
+
+125
+00:11:56,020 --> 00:12:04,630
+الفيورانوز لما بتطلع فيهبيتا واضح؟ اذا هذا بيتا
+
+126
+00:12:04,630 --> 00:12:09,270
+عشانك هتلاقوا الاسم تبعه اعتبروا ان هذا هو الأصل
+
+127
+00:12:09,270 --> 00:12:14,010
+وهذه هي الاش المجموعة اللي جاية على الأصل واضح؟
+
+128
+00:12:14,010 --> 00:12:19,950
+فهتلاحظوا بيتا دي فراكتو فيورانوزيل طبعا
+
+129
+00:12:19,950 --> 00:12:26,210
+فيورانوزيل لأنه جاي ايش؟ مجموعة متحدة مع الف دي
+
+130
+00:12:26,210 --> 00:12:33,150
+غلوكوما كتبش هنا by rhinos، كتب by rhinocide، ليش؟
+
+131
+00:12:33,150 --> 00:12:37,790
+لأن الاتحاد تم هنا من موقع واحد، لاحظوا في
+
+132
+00:12:37,790 --> 00:12:41,270
+السكريات اللي قبل شوية، لما كنا نيجع هذا السكر،
+
+133
+00:12:41,270 --> 00:12:45,150
+الاتحاد تم من أي موقع؟ أربعة، هنا الاتحاد تم من
+
+134
+00:12:45,150 --> 00:12:53,080
+موقع واحد، فإذا هذه الرابطة بطلت OH صارت O-Carbon
+
+135
+00:12:53,080 --> 00:12:58,340
+معنا ذلك هذه الرابطة ايش بدها تكون؟ Glycosidic
+
+136
+00:12:58,340 --> 00:13:02,280
+bond واضح؟ عشان Glycosidic bond عشان تكون
+
+137
+00:13:02,280 --> 00:13:08,400
+Glycoside هنحط ايش؟ Glucoburanoside لاحظته هنا
+
+138
+00:13:08,400 --> 00:13:12,640
+كلمة؟ Buranoside لو رجعتوا على الأسماء اللي قبل
+
+139
+00:13:12,640 --> 00:13:19,240
+كان حط Glucoburanose لأن هذه كانت تكون OHفي كل
+
+140
+00:13:19,240 --> 00:13:23,280
+اللي قبل هذه كانت OH غلوكو باي رانوس سواء كان
+
+141
+00:13:23,280 --> 00:13:28,860
+Alpha أو Beta لكن هنا بطلت OH صار الاتحاد من عندها
+
+142
+00:13:28,860 --> 00:13:33,420
+و عشان هيك صارت هذه الرابطة Glycosidic bond فقال
+
+143
+00:13:33,420 --> 00:13:38,300
+غلوكو باي رانوسايد غلوكو باي رانوسايد فالحقيقة
+
+144
+00:13:40,010 --> 00:13:46,150
+السكر اللى فيه two glycosidic bonds هو سكر ايش
+
+145
+00:13:46,150 --> 00:13:50,210
+السكروز انتبهوا لو كانوا بيسألكوا multiple choice
+
+146
+00:13:50,210 --> 00:13:58,670
+الان هذه الرابطة carbon و carbon هذى glycosidic
+
+147
+00:13:58,670 --> 00:14:04,230
+bond ولا لأ و هذا الرابطة glycosidic bond فلما
+
+148
+00:14:04,230 --> 00:14:10,320
+نيجي نطلع احنا حقيقة على السكروزكم جليكوسايدك بوند
+
+149
+00:14:10,320 --> 00:14:18,940
+فيه؟ تنتين لو رجعنا اتطلعنا على السكريات
+
+150
+00:14:18,940 --> 00:14:25,100
+اللي قبل هنا كم جليكوسايدك بوند؟ واحدة ماحدش يقول
+
+151
+00:14:25,100 --> 00:14:29,520
+هذه جليكوسايدك بوند ليش؟ لأن الجليكوسايدك بوند
+
+152
+00:14:29,520 --> 00:14:34,700
+اللي بتتكون على الكايرال سنتر الأخير على هذه مش
+
+153
+00:14:34,700 --> 00:14:40,650
+على هذا الموقع أربعةواضح؟ يعني مش اي او كربون
+
+154
+00:14:40,650 --> 00:14:47,850
+glycosidic bond ال glycosidic bond مرتبطة بأي بأي
+
+155
+00:14:47,850 --> 00:14:52,630
+كربون بال anomeric carbon اللي كانت أساسا الديهايد
+
+156
+00:14:52,630 --> 00:14:56,350
+واضح؟ ولذلك هذه glycosidic bond بس هذه مش
+
+157
+00:14:56,350 --> 00:15:01,390
+glycosidic bond واضح؟ فلو أنا اجيت على ال lactose
+
+158
+00:15:01,390 --> 00:15:08,540
+في one glycosidic bond لو رجعتعلى السيلو بيوز على
+
+159
+00:15:08,540 --> 00:15:13,640
+سبيل المثال برضه أي واحدة anomeric carbon كل سكر
+
+160
+00:15:13,640 --> 00:15:17,780
+فيه two anomeric carbon مظبوط ولا لأ هذه فيها
+
+161
+00:15:17,780 --> 00:15:24,200
+glycosidic bond هذه فيها لذلك في السيلو بيوز في
+
+162
+00:15:24,200 --> 00:15:30,950
+عنده one glycosidic bond هذه لأواضحة الفكرة؟ يعني
+
+163
+00:15:30,950 --> 00:15:34,970
+انا عندي two anomeric carbons مين فيهم glycosidic
+
+164
+00:15:34,970 --> 00:15:40,630
+bond؟ هذي ال O H glycosidic، هذي، اه واضحة الفكرة؟
+
+165
+00:15:40,630 --> 00:15:44,950
+فدائما لما بدنا نعرف كام glycosidic bond، نرجع على
+
+166
+00:15:44,950 --> 00:15:53,670
+الملتوز مثلا، هذي ال anomeric carbons الآن لو
+
+167
+00:15:53,670 --> 00:15:57,690
+إجينا سألنا هذي glycosidic bond؟ O H، هذي
+
+168
+00:15:59,540 --> 00:16:07,100
+Glycosidic bond فالملتوز والسيلوبيوز واللاكتوز
+
+169
+00:16:07,100 --> 00:16:11,380
+هدولة فيهم و one glycosidic bond و التانية عادية
+
+170
+00:16:11,380 --> 00:16:16,740
+عشان ايه كنتوا تلاقوا؟ Glucopyranose عادي لكن لما
+
+171
+00:16:16,740 --> 00:16:23,340
+وصلنا للسكروز لو اجينا سألنا وين ال anomeric
+
+172
+00:16:23,340 --> 00:16:24,180
+carbons؟
+
+173
+00:16:26,580 --> 00:16:31,440
+هي الانوميرك كاربونز الان هنا في جليكوسايدك بوند
+
+174
+00:16:31,440 --> 00:16:36,640
+فيه هنا في جليكوسايدك بوند فيه تنتين جليكوسايدك
+
+175
+00:16:36,640 --> 00:16:42,920
+بوند واضح؟ وعشان هيك هذا لما أنهينا اسمه أنهينا ب
+
+176
+00:16:42,920 --> 00:16:49,480
+side اللي هو alpha D-glucopyranoside زي ما اتعلمنا
+
+177
+00:16:49,480 --> 00:16:53,160
+لما أخدنا الجليكوسايدك بوند وقلنا بننهي بإيش؟
+
+178
+00:16:53,160 --> 00:16:54,360
+جليكوسايد
+
+179
+00:16:57,360 --> 00:17:03,560
+هذا بالنسبة لبعض السكريات اللي هي بنستفيد منها ل
+
+180
+00:17:03,560 --> 00:17:08,700
+ال die saccharides الكلام يمكن يجيب بعضه أن القاسم
+
+181
+00:17:08,700 --> 00:17:16,810
+المشترك ربما في الأشياء المحلية طعم الحلوواضح؟
+
+182
+00:17:16,810 --> 00:17:20,550
+يعني الإنسان بيفتش في النهاية عن إيش؟ الطعم كذلك
+
+183
+00:17:20,550 --> 00:17:24,450
+الحال يمكن تلاحظوه في العطور يعني مار علينا و إحنا
+
+184
+00:17:24,450 --> 00:17:31,410
+بنشرح بعض العطور العطور لا يوجد خليني أقول مجموعة
+
+185
+00:17:31,410 --> 00:17:35,810
+كيميائية تكون قاسم مشترك ما بين العطور ما القاسم
+
+186
+00:17:35,810 --> 00:17:41,920
+المشترك؟الرائحة الذكية، الرائحة الجيدة الآن العطر
+
+187
+00:17:41,920 --> 00:17:46,360
+ممكن مرة يكون Easter ممكن مرة يكون الديهيد ممكن
+
+188
+00:17:46,360 --> 00:17:50,440
+مرة يكون كيتون شوفنا الياسمون مثلا شوفنا ..
+
+189
+00:17:50,440 --> 00:17:53,940
+متذكرين الياسمين كان كيتون شوفنا ال Easter's قولنا
+
+190
+00:17:53,940 --> 00:17:58,040
+عنها مواد عطرية مافيش قاسم كيميائي مشترك القاسم
+
+191
+00:17:58,040 --> 00:18:03,310
+الكيميائي ما بين العطورهو الرائحة الجيدة الآن
+
+192
+00:18:03,310 --> 00:18:07,290
+القاسم الكيميائي ما بين ال sweeteners المحليات و
+
+193
+00:18:07,290 --> 00:18:12,970
+منها السكر هو الطعم الاش؟ الحلو ولذلك الآن في
+
+194
+00:18:12,970 --> 00:18:17,490
+سكريات اللي هي السكريات هذه الصناعية اللي بياخدوها
+
+195
+00:18:17,490 --> 00:18:21,430
+الناس اللي عندهم سكر و ما إلى ذلك لو اطلعت على
+
+196
+00:18:21,430 --> 00:18:25,590
+أنواعها المختلفة مش هتلاقيوا شيء مشترك في الشكل
+
+197
+00:18:25,590 --> 00:18:32,500
+بينها لكن هالمراكبات لما حضروهالاحظوا انه طعمها
+
+198
+00:18:32,500 --> 00:18:37,440
+حلو وبشكل عام آمن يعني كتير في مركبات طعمها حلو
+
+199
+00:18:37,440 --> 00:18:40,980
+لكن خطيرة جدا بيقدرش الإنسان يتعامل معايا
+
+200
+00:18:40,980 --> 00:18:45,440
+الكلوروفورم طعمه حلو لكن سامه carcinogenic لكن هذا
+
+201
+00:18:45,440 --> 00:18:50,040
+المركب مثلا بدون ما ناخد طرق تحضيره هو السكارين
+
+202
+00:18:50,040 --> 00:18:54,720
+سواء وجد ع شكل السكارين أو عشان يدوب بيسحبوا القدش
+
+203
+00:18:54,720 --> 00:18:58,580
+بيعملوا ال salt تبعه طبعا دائما لما نقول salt ال
+
+204
+00:18:58,580 --> 00:19:03,300
+salt ليش بنعمله احناعشان الذائبية تكون أعلى في
+
+205
+00:19:03,300 --> 00:19:08,740
+الميه فلو اطلعنا احنا هذا ال sodium سكارين اللي هو
+
+206
+00:19:08,740 --> 00:19:12,740
+اللي بنستعمله و بنحطه على الشاي مافيش علاقة بين
+
+207
+00:19:12,740 --> 00:19:20,080
+شكله وبين شكل السكاروز لكن يوضع بديل للسكاروز،
+
+208
+00:19:20,080 --> 00:19:25,780
+مظبوط ولا لأ؟ ليش يوضع بديل للسكاروز؟ بسبب الطعم
+
+209
+00:19:25,780 --> 00:19:30,730
+الحلو، الآن في سكريات تانية غير السكاروزالسكارين
+
+210
+00:19:30,730 --> 00:19:36,150
+تستعمل منها مثلا ال Aspartame و ال Cyclamates لو
+
+211
+00:19:36,150 --> 00:19:42,110
+فتشته Cyclamates لو فتشته على شكل ال Aspartame و
+
+212
+00:19:42,110 --> 00:19:46,030
+ال Cyclamate و السكارين هتلاقي كل واحد يمثل شكل
+
+213
+00:19:46,030 --> 00:19:52,410
+معين مافيش قاسم مشترك بينهم القاسم المشترك هو إيش؟
+
+214
+00:19:52,410 --> 00:19:57,510
+الطعم الحلو القاسم المشترك هو الطعم الحلو يعني هاي
+
+215
+00:19:57,510 --> 00:20:02,700
+ال Aspartameطلعوا هذا شكل و هذا شكل بتلاحظوا فيه
+
+216
+00:20:02,700 --> 00:20:07,740
+شيء مشترك مع السكرين طب العسل بس زي محلق و بطعم
+
+217
+00:20:07,740 --> 00:20:12,060
+حلو؟ ايه هو؟ العسل؟ ما هو العسل فيه سكريات كتيرة
+
+218
+00:20:12,060 --> 00:20:17,120
+لأ لأ مش من هدولة من السكريات العادية اللي أخدناها
+
+219
+00:20:17,120 --> 00:20:23,000
+بس تركيبته عاد كبيرة في سكريات و فيتامينات و إشي
+
+220
+00:20:23,000 --> 00:20:31,540
+أكثر من شغلها الآنهذه الـ Disaccharides سواء كانت
+
+221
+00:20:31,540 --> 00:20:37,740
+سكريات مختلفة زي الملتوز اللي احنا قلنا عنه Alpha
+
+222
+00:20:37,740 --> 00:20:43,810
+و Beta الجلوكوز متحدين مع بعض أوالسيلو بيوز اللي
+
+223
+00:20:43,810 --> 00:20:47,710
+قلنا عنه بيتا و بيتا يعني خلينا نركز احنا على
+
+224
+00:20:47,710 --> 00:20:52,810
+الملتوز الملتوز كان من ألفة و بيتا جولوكوز مكون
+
+225
+00:20:52,810 --> 00:20:57,790
+واضح؟ و السيلو بيوز من بيتا و بيتا جولوكوز الآن
+
+226
+00:20:57,790 --> 00:21:02,470
+هدولة لما بيجوا بيعملوا بوليمار كبير لما بيعملوا
+
+227
+00:21:02,470 --> 00:21:06,750
+بوليمار كبير بيكون هم الوحدة الأساسية المتكررة في
+
+228
+00:21:06,750 --> 00:21:12,930
+البوليمار بيعطوناالـ starch أو النشا في حالة ما
+
+229
+00:21:12,930 --> 00:21:18,570
+نتكلم عن إيش؟ عن الملتوز، في حالة ما نتكلم عن
+
+230
+00:21:18,570 --> 00:21:22,990
+السيلوبايوز، بيعطينا السيليلوز، واضح؟ فالملتوز
+
+231
+00:21:22,990 --> 00:21:29,130
+بيعطيني إيش؟ النشا، starch، السيلوبايوز بيعطيني
+
+232
+00:21:29,130 --> 00:21:36,470
+السيليلوز، الخشب، واضح؟ بولمار كبير طبعاًلاحظوا
+
+233
+00:21:36,470 --> 00:21:40,990
+عاد حسب ال polymer اللي بتكون يعني يوم ما نحكي عن
+
+234
+00:21:40,990 --> 00:21:45,550
+polymer يعني عدد كبير من الشغلات هتلاحظوا في علم
+
+235
+00:21:45,550 --> 00:21:50,250
+ال polymerization هذا العدد ممكن يكون 300 وحدة
+
+236
+00:21:50,250 --> 00:21:56,200
+ممكن يكون الف ممكن يكون تلت تلافتمام؟ حسب طريقة
+
+237
+00:21:56,200 --> 00:21:59,420
+الارتباط اللى موجودة في هذا العدد وحسب عدد
+
+238
+00:21:59,420 --> 00:22:03,760
+الجزيئات او الوحدات المكونة له الآن وحدة ال stars
+
+239
+00:22:03,760 --> 00:22:08,300
+هي ايش؟ ال maltose هذه الوحدة اللى مكونة من سكرين
+
+240
+00:22:08,300 --> 00:22:13,160
+حسب كمية الأشياء المتصلة بيصير عند نوع ال polymer
+
+241
+00:22:13,160 --> 00:22:16,340
+عشانك انتوا بال plastic بتلاحظوا في عندكوا أنواع
+
+242
+00:22:16,340 --> 00:22:21,460
+كتيرةفي النيلون في عندكم أنواع كتيرة هذا بيصير
+
+243
+00:22:21,460 --> 00:22:25,860
+يدخل فيه جانب الصناعة انه قداش العدد اللي خلناه
+
+244
+00:22:25,860 --> 00:22:31,640
+يتحد تقريبا يعمل polymer هالخليه 300 جزء و وحدة ال
+
+245
+00:22:31,640 --> 00:22:37,640
+polymer 3000 2000 واضح الفكرة؟ الآن نفس الفكرة من
+
+246
+00:22:37,640 --> 00:22:43,350
+الملتوز هلاحظ ان في انهاالـ starch لو حللته
+
+247
+00:22:43,350 --> 00:22:47,990
+بيعطيني ملتوز، الملتوز لو حللته بيعطيني جولوكوز،
+
+248
+00:22:47,990 --> 00:22:52,830
+لكن جولوكوز Alpha
+
+249
+00:22:53,990 --> 00:22:58,410
+وبيتاجولوكوز لكن هذه الوحدة المتكررة وحدة الملتوز
+
+250
+00:22:58,410 --> 00:23:03,350
+اعملوا منها عدد كبير الان لاحظوا ان النشا مكون من
+
+251
+00:23:03,350 --> 00:23:08,230
+شغلتين من اميلوز بنسبة 20% والباقي تقريبا
+
+252
+00:23:08,230 --> 00:23:15,200
+اميلوبكتل ايش بيفرقوا هدولة الشغلتين؟بعدد الجزيئات
+
+253
+00:23:15,200 --> 00:23:19,980
+المكونة له بطريقة الاتحاد يعني ال amylose في
+
+254
+00:23:19,980 --> 00:23:25,840
+جولوكوز units عادة بيكون عددها ما يقارب بين خمسين
+
+255
+00:23:25,840 --> 00:23:30,260
+لتلتمية جولوكوز unit لكن أهم شيء بيميزها أن هي
+
+256
+00:23:30,260 --> 00:23:37,970
+موجودة في إيش؟بسلاسل بدون تفرعات، واضح؟ سلاسل بهذا
+
+257
+00:23:37,970 --> 00:23:42,830
+الشكل بدون ما يصير فيها تفرعات، العدد تبع ال
+
+258
+00:23:42,830 --> 00:23:47,410
+geolocose units بيكون ما بين خمسين إلى تلتمية
+
+259
+00:23:47,410 --> 00:23:52,770
+geolocose unit والاتحاد زي ما انتوا عارفين نمر
+
+260
+00:23:52,770 --> 00:23:58,270
+أربعة من هان وبتحد من واحد مع الجزء التانييعني
+
+261
+00:23:58,270 --> 00:24:02,190
+احنا لما كنا نتكلم عن ال مالتوز، كنا هنا في عنا
+
+262
+00:24:02,190 --> 00:24:07,550
+الاتحاد مع أربعة أو سابين واحد، أوقتش، الآن لما
+
+263
+00:24:07,550 --> 00:24:11,150
+بتعمل polymer، بيجيب التحد منها، يعني لو انتوا
+
+264
+00:24:11,150 --> 00:24:16,630
+تذكرتوا المالتوز، مش كانت هذه تكون فيهقواتش لما
+
+265
+00:24:16,630 --> 00:24:20,930
+نحكي عن الملتوز لوحده الآن بيصير يتحد من هذه
+
+266
+00:24:20,930 --> 00:24:23,690
+القواتش عشان يعمل ال polymer يعني القواتش اللي
+
+267
+00:24:23,690 --> 00:24:28,610
+كانت ماتروكة فاضية بيصير يتحد من خلالها مع موقع
+
+268
+00:24:28,610 --> 00:24:33,130
+أربعة من وحدة ملتوز تانية بطلع عنده جزء كبير
+
+269
+00:24:33,130 --> 00:24:34,210
+بنسميه إيش
+
+270
+00:24:37,020 --> 00:24:43,020
+الاميلوز الاميلوز هذا احد مكونات النشا الان النشا
+
+271
+00:24:43,020 --> 00:24:49,260
+في مكون تاني الاميلوبكتين الاميلوبكتين في ما بين
+
+272
+00:24:49,260 --> 00:24:53,460
+تلتمية الى خمستلاف جولوكوز units يعني الجولوكوز
+
+273
+00:24:53,460 --> 00:24:59,860
+units اللى في عددها اكبر لكن اهم شغل فيه is
+
+274
+00:24:59,860 --> 00:25:06,920
+هايلبراجد واضح يعني الاميلوز سلسلةالـ amylobectin
+
+275
+00:25:06,920 --> 00:25:13,440
+في تفرعات يعني تقريبا لاحظوا الـ amylose بين 300
+
+276
+00:25:13,440 --> 00:25:17,220
+إلى 5000 جولوكوز units is a highly branched
+
+277
+00:25:17,220 --> 00:25:21,660
+molecule او highly branched molecule chains with
+
+278
+00:25:21,660 --> 00:25:24,360
+consecutive one four links شوفنا كيف one four
+
+279
+00:25:24,360 --> 00:25:28,520
+links الارتباط ال average يعني كل مجموعة حوالي
+
+280
+00:25:28,520 --> 00:25:35,070
+خمسة وعشرين لتلاتين وحدةو بعدين بيجي تفرع 25 ل 30
+
+281
+00:25:35,070 --> 00:25:41,110
+و تفرع بيصير الجزء أشماله highly branched واضح
+
+282
+00:25:41,110 --> 00:25:48,470
+فواضح أن جزء ال amylobectin أكبر من ال amylose و
+
+283
+00:25:48,470 --> 00:25:55,150
+بنفس الوقت اللي بيميزه التفرعات واضح فال amylose
+
+284
+00:25:55,150 --> 00:26:02,220
+is a chain moleculeالـ amylobectin هو جزئ عالي جزئ
+
+285
+00:26:02,220 --> 00:26:11,520
+فيه تفرعات كتيرة طبعا هذه كل أشكال تقريبية بتوضح
+
+286
+00:26:11,520 --> 00:26:20,720
+لنا كيف بيتكونوا هذول الجزيئات الأن لو جينا من ال
+
+287
+00:26:20,720 --> 00:26:30,470
+amylose أيضاغير النشق بمكوينه يعني من الملتوز كان
+
+288
+00:26:30,470 --> 00:26:35,130
+في عنده ال starch اللي هو مكوّن من amylose و
+
+289
+00:26:35,130 --> 00:26:40,470
+mylobectin أيضًا من الملتوز في عنده الجليكوجين ال
+
+290
+00:26:40,470 --> 00:26:45,470
+starch ما كان تخزين ال carbohydratesفي النبات
+
+291
+00:26:45,470 --> 00:26:49,410
+الجليكوجين مكان تخزين ال carbohydrates في
+
+292
+00:26:49,410 --> 00:26:55,750
+الحيوانات برضه هو فيه جولوكوز units لكن حوالي مائة
+
+293
+00:26:55,750 --> 00:27:00,590
+ألف جولوكوز unit لاحظوا العدد في الجليكوجين
+
+294
+00:27:00,590 --> 00:27:06,810
+جليكوجين بيزيد بشكل كبير وبرنشد يعني كل ما بين كل
+
+295
+00:27:06,810 --> 00:27:11,010
+تمانية ل 12 جولوكوز unit خلينا هيك نتخيل هتلاحظوا
+
+296
+00:27:11,010 --> 00:27:17,930
+ان في عندكم إيشالجزء هذا الجليكوجين بيكون أيضا
+
+297
+00:27:17,930 --> 00:27:24,090
+highly branched الآن الجليكوجين بيجي من الجلوكوز
+
+298
+00:27:24,090 --> 00:27:30,130
+اللي بيمتص من أمعاء produced from glucose that is
+
+299
+00:27:30,130 --> 00:27:35,930
+absorbed from intestines into the blood الآن إيش
+
+300
+00:27:35,930 --> 00:27:41,060
+وظيفته هذا الجليكوجين؟ يمكن مار عليكمبيولوجيا اللي
+
+301
+00:27:41,060 --> 00:27:45,260
+هو توازن السكر helps maintain the glucose balance
+
+302
+00:27:45,260 --> 00:27:49,660
+واضح يعني إذا في عندي جولوكوز ازيادة بيجي و بتخزن
+
+303
+00:27:49,660 --> 00:27:54,340
+وين في الجليكوجين بدخل ضمن البوليمار الآن إذا
+
+304
+00:27:54,340 --> 00:28:00,770
+الجسم نقص عليه الجولوكوزبصير هذا نفسه يفرز أو يعطي
+
+305
+00:28:00,770 --> 00:28:07,930
+الجسم وحدات جولوكوز واضح الفكرة؟ يعني هو كأنه هاي
+
+306
+00:28:07,930 --> 00:28:12,450
+جزيئات الجولوكوز بتقدروا تتخيلوها بتمطس من المعدة
+
+307
+00:28:12,450 --> 00:28:16,030
+المفروض لازم لحرق الأكل الناس اللي بياكلوا كتير
+
+308
+00:28:16,030 --> 00:28:21,510
+okay بنجمع هذه الجزيئات هيعملنا إيش؟جلايكوجين
+
+309
+00:28:21,510 --> 00:28:25,790
+وخزانة الان بعد هيك صار البني ادم عنده ناقص في
+
+310
+00:28:25,790 --> 00:28:31,010
+السكر جد ما فيه ناقص بيصير يطلع له جولوكوز واضح؟
+
+311
+00:28:31,010 --> 00:28:36,090
+واضحة الفكرة العامة خليني اقول العامة جدا
+
+312
+00:28:36,090 --> 00:28:42,890
+لجلايكوجين الان لو طلعنا على ال cellulose ال
+
+313
+00:28:42,890 --> 00:28:48,830
+cellulose هو ال polymerاللي جاي من الـ cellobiose
+
+314
+00:28:48,830 --> 00:28:55,010
+اللي بيعمل الخشب يعني النشا والجليكوجين جايين من
+
+315
+00:28:55,010 --> 00:29:01,430
+وين؟ من الملتوز من الملتوز لكن ال cellulose جاي من
+
+316
+00:29:01,430 --> 00:29:03,410
+ال cellobiose
+
+317
+00:29:05,410 --> 00:29:11,210
+بيتا وبيتا sugar فالcellulose is an unbranched
+
+318
+00:29:11,210 --> 00:29:16,210
+polymer مستقيم مافيش فيه branches of glucose
+
+319
+00:29:16,210 --> 00:29:20,110
+joined by one four beta glycosidic bonds كل
+
+320
+00:29:20,110 --> 00:29:29,390
+هالكلام شفناه لاحظوا معي كيف فرق في الأساس بسيط
+
+321
+00:29:29,390 --> 00:29:37,500
+جدا انه هذا منسيلو بيوز هذا من مالتوز السيلو بيوز
+
+322
+00:29:37,500 --> 00:29:42,260
+و المالتوز متحدين في beta غلوكوز لكن السكر التاني
+
+323
+00:29:42,260 --> 00:29:46,820
+في كل واحدة واحد منهم واحد alpha واحد beta يعني
+
+324
+00:29:46,820 --> 00:29:51,120
+خلينا نقول هنا في عند بيتا و بيتا نفس الاشي في
+
+325
+00:29:51,120 --> 00:29:57,340
+السكرين الآن في المالتوز هذا alpha في السيلو بيوز
+
+326
+00:29:58,430 --> 00:30:03,590
+هذا beta فهذا alpha beta هذا beta beta الآن هذا
+
+327
+00:30:03,590 --> 00:30:07,690
+بيصير ملتوز و بيعملني نشا و glycogen هذا بيصير
+
+328
+00:30:07,690 --> 00:30:12,970
+cellulose و cellobiose و بيعمله ال cellulose الان
+
+329
+00:30:12,970 --> 00:30:16,990
+البني آدم بيقدر يهضم النشا بيقدر يهضم ال glycogen
+
+330
+00:30:16,990 --> 00:30:22,670
+بيقدرش يهضم ال cellulose ال cellulose واضح فال
+
+331
+00:30:22,670 --> 00:30:26,830
+humans and other animals they digest starch and
+
+332
+00:30:26,830 --> 00:30:32,880
+glycogenبيقدروا يهضموا النشق والجليكوجين، الآن
+
+333
+00:30:32,880 --> 00:30:37,360
+الحيوانات
+
+334
+00:30:37,360 --> 00:30:42,610
+والنمليمكن تقولوا النمل صار أقوى من البني آدم يعني
+
+335
+00:30:42,610 --> 00:30:46,550
+هو النمل بيقدر يخضم الخشب و البني آدم مابيقدرش
+
+336
+00:30:46,550 --> 00:30:52,030
+معنا ذلك النمل أقوى من البني آدم هي المشكلة انه
+
+337
+00:30:52,030 --> 00:30:57,150
+كمان مش النمل اللي بيخضم او مش الحيوانات المجترة
+
+338
+00:30:57,150 --> 00:31:01,570
+اللي بتخضم لأ بكتيريا موجودة جوا أمعاها هذه
+
+339
+00:31:01,570 --> 00:31:05,050
+البكتيريا اللي جوا أمعاها بتفرز اللي هو
+
+340
+00:31:08,560 --> 00:31:14,060
+الانزيمات اللى هى ال beta glycosidase اللى بتساعد
+
+341
+00:31:14,060 --> 00:31:19,960
+على عملية ايش ان تقدر تهضم الخشب وتستفيد منه واضح
+
+342
+00:31:19,960 --> 00:31:27,760
+فماني بكتيريا contain beta glycosidase دايما اذا
+
+343
+00:31:27,760 --> 00:31:33,510
+شفتوا هذه النهاية ايش هذاالنزيم Oxidase و
+
+344
+00:31:33,510 --> 00:31:37,870
+Redactase و glycosidase and they can hydrolyze
+
+345
+00:31:37,870 --> 00:31:42,810
+يعني يفككوا ال cellulose فلو احنا قلنالكم ان ال
+
+346
+00:31:42,810 --> 00:31:46,090
+humans can hydrolyze cellulose
+
+347
+00:31:48,210 --> 00:31:52,250
+واضح؟ لكن في بكتيريا كتير بتقدر تعمل هذا الكلام
+
+348
+00:31:52,250 --> 00:31:55,990
+هذه موجودة في ال termites اللي هو النمل الأبيض و
+
+349
+00:31:55,990 --> 00:31:59,510
+ال ruminants اللي هي الحيوانات المجترة اللي
+
+350
+00:31:59,510 --> 00:32:03,050
+بتلاقوها مستعدة تاكل ال .. إيش؟ زي الجمل و زي ..
+
+351
+00:32:03,050 --> 00:32:08,250
+أه اللي بتاكل الخشب فبكتيريا في معدتها بتقدر تدخل
+
+352
+00:32:08,250 --> 00:32:13,450
+على هذا الخشب و تحلله لوحدات السكر بحيث أنه النمل
+
+353
+00:32:13,450 --> 00:32:18,430
+الأبيض أو الحيوانات هذه المجترة تقدر تستفيد منهأو
+
+354
+00:32:18,430 --> 00:32:22,310
+من السكر اللي موجود فيه لكن البني آدم مابيقدرش
+
+355
+00:32:22,310 --> 00:32:26,730
+يخدمه أخر
+
+356
+00:32:26,730 --> 00:32:33,090
+شغلة أخر شغلة بنحكيها بالنسبة لهذا الجزء أنه في
+
+357
+00:32:33,090 --> 00:32:37,870
+عندى بعض ال sugars يمكن أن ينزع منها أكسجين هذه
+
+358
+00:32:37,870 --> 00:32:42,850
+بتفيدنا لما بدنا ندرس ال nuclear acid اللي هي
+
+359
+00:32:42,850 --> 00:32:49,090
+الأحماض النووية ومنهابصير اسمها deoxy sugars يعني
+
+360
+00:32:49,090 --> 00:32:53,470
+لاحظوا هذا ال sugar لما يكون فيه ال oxygen و سكر
+
+361
+00:32:53,470 --> 00:32:58,610
+من خمس كربونات tripose تمام لما نشيل منه oxygen
+
+362
+00:32:58,610 --> 00:33:02,870
+منها يعني في الأصل كان في عنده OH لو شيلنا منه
+
+363
+00:33:02,870 --> 00:33:09,490
+oxygen ايش بيصير اسمه؟ deoxy، deoxy يعني منزوعأه
+
+364
+00:33:09,490 --> 00:33:14,570
+لحظة ميزه .. ميزه رجاء في الكلمات، عشانك احنا
+
+365
+00:33:14,570 --> 00:33:22,080
+بنقول اتعبوا شوية، يعني لو اتينا قولنالكم ضايقزيدا
+
+366
+00:33:22,080 --> 00:33:27,800
+يعني اتنين اه لكن دي منزوعة زي ما كنا نقول
+
+367
+00:33:27,800 --> 00:33:31,760
+hydrogenation, dehydrogenation, hydration,
+
+368
+00:33:32,600 --> 00:33:38,260
+dehydrogenation, halogenation, dehydrogenation فال
+
+369
+00:33:38,260 --> 00:33:43,820
+دي بتاعنا اللي هو العكس فهذا ال beta دي دي
+
+370
+00:33:43,820 --> 00:33:48,860
+oxyribofuranose طب علشه فيورانوز لأنهمن حلقاء
+
+371
+00:33:48,860 --> 00:33:53,520
+خماسية هو ال sugar تبع ال DNA هو عبارة عن Ribose
+
+372
+00:33:53,520 --> 00:33:58,720
+نزعت منه ال Oxygen و لو كان ال Ribose اللي في ال
+
+373
+00:33:58,720 --> 00:34:05,400
+Oxygen بيعملنا ال RNA Ribonucleic Acid لما يكون ال
+
+374
+00:34:05,400 --> 00:34:09,800
+DNA Deoxyribonucleic Acid واضح؟
+
+375
+00:34:12,560 --> 00:34:19,700
+الكلام عام عن اللي هي ال dice carats و عن ال
+
+376
+00:34:19,700 --> 00:34:26,210
+polymers اللي بتكونوا منهم خلينا يعني نبدأنعطي
+
+377
+00:34:26,210 --> 00:34:31,310
+فكرة عامة ليش أنا محتاجها الآن مقارنة مع
+
+378
+00:34:31,310 --> 00:34:37,050
+البروتينات اللي بدنا ناخدها في الفصل الأخير ان شاء
+
+379
+00:34:37,050 --> 00:34:41,910
+الله اللي هو ال amino acids و ال peptides و ال
+
+380
+00:34:41,910 --> 00:34:48,210
+proteins زي ما لاحظته يمكن أهم شغلة في ال
+
+381
+00:34:48,210 --> 00:34:52,290
+polysaccharides أهم شغلة في ال polysaccharides أن
+
+382
+00:34:52,290 --> 00:34:57,650
+هم polymersماذا يعني polymers؟ يعني لما أقول
+
+383
+00:34:57,650 --> 00:35:04,150
+النشا، إيش الوحدة تبعته؟ هتقولولي مالتوز
+
+384
+00:35:04,150 --> 00:35:10,390
+البيسكريدي المالتوز، تمام؟ لو قولت مثلا السيللوز،
+
+385
+00:35:10,390 --> 00:35:15,870
+بوليمر كبير، إيش الوحدة تبعته؟ السيلوبيوز، ولذلك
+
+386
+00:35:15,870 --> 00:35:23,490
+ال polysaccharidesيمكن التعامل معها يكون أسهل كتير
+
+387
+00:35:23,490 --> 00:35:28,790
+من التعامل مع البروتينات ليش؟ لأن ال
+
+388
+00:35:28,790 --> 00:35:32,930
+polysaccharides عندي وحدة و بتتكرر يعني كأن
+
+389
+00:35:32,930 --> 00:35:37,110
+الإنسان بيقدر يقول عنهم ان they are real polymers
+
+390
+00:35:37,110 --> 00:35:43,710
+واضح؟ ال polymers مكون من إيش؟مونومارز تتحد تصير
+
+391
+00:35:43,710 --> 00:35:47,910
+دايمارز، ترايمارز، تترامارز، في الآخر إيش؟
+
+392
+00:35:47,910 --> 00:35:55,190
+بوليمارز، فالبوليمار من ناحية المبدأ وحدة متكررة،
+
+393
+00:35:55,190 --> 00:36:00,390
+البوليمار وحدة إيش مالها؟ متكررة، فلمّا أجي أقول
+
+394
+00:36:00,390 --> 00:36:05,990
+starch polymer ما وحدته المتكررة؟ الملتوز، انتهى
+
+395
+00:36:06,580 --> 00:36:13,060
+واضح؟ الآن لما بدي اجي .. لما بدي اجي اتكلم عن ال
+
+396
+00:36:13,060 --> 00:36:18,900
+proteins هلاحظ ان في عندي اختلاف أساسي ال proteins
+
+397
+00:36:18,900 --> 00:36:26,580
+عبارة عن amino acids وال amino acids مختلفين
+
+398
+00:36:27,350 --> 00:36:33,110
+واضح ال amino acids مختلفين ولذلك انا لما بدي اجي
+
+399
+00:36:33,110 --> 00:36:38,050
+اعمل مثلا نشا بقدر اقول بقدر اقول في حالة النشا او
+
+400
+00:36:38,050 --> 00:36:44,630
+ال amylose مالتوز تلاتين
+
+401
+00:36:44,630 --> 00:36:50,320
+وحدة مثلا او تلاتميت وحدةملتوز 300 وحدة واضح؟
+
+402
+00:36:50,320 --> 00:36:56,520
+الملتوز مكرر كده؟ 300 مرة هاي صرت عامل مثلا اميلوز
+
+403
+00:36:56,520 --> 00:37:01,240
+لكن لو جيت بدي اعمل البروتين او الأصغر من البروتين
+
+404
+00:37:01,240 --> 00:37:04,720
+ال بيبتايد اللي هيمر علينا بعد شوية مابقدرش اعمل
+
+405
+00:37:04,720 --> 00:37:09,460
+مثل هذه المعادلة واضح؟ يعني هذه المعادلة ان اقول
+
+406
+00:37:09,460 --> 00:37:15,860
+انه is a real polymerاللي هي ال polysaccharides
+
+407
+00:37:15,860 --> 00:37:21,480
+مالتوز منه تلاتمية وحدة او منه مائة الف وحدة في ال
+
+408
+00:37:21,480 --> 00:37:26,640
+glycogen على سبيل المثال او ما إلى ذلك هي وحدة و
+
+409
+00:37:26,640 --> 00:37:32,680
+متكررة لما بدي اجي احكي عن ال protein
+
+410
+00:37:36,730 --> 00:37:43,590
+هلاحظ ان البروتين عبارة عن amino acids عدد كبير من
+
+411
+00:37:43,590 --> 00:37:49,190
+ال amino acids الان كل amino acid من ناحية المبدأ
+
+412
+00:37:49,190 --> 00:37:56,730
+بختلف عن التاني يعني خليني اتخيل ان هذا حقيقة بمثل
+
+413
+00:37:56,730 --> 00:38:03,490
+البروتين الان هذا بقدر احط عليه كذا to the N لأ طب
+
+414
+00:38:03,490 --> 00:38:10,740
+ايش المطلوب اعمله؟أعمله إيش التسلسل تبعه، يعني لو
+
+415
+00:38:10,740 --> 00:38:14,600
+اتخيلت أنا أن هذا بروتين صغير، يعني بيبتايد، بقول
+
+416
+00:38:14,600 --> 00:38:19,700
+لحظة معايا إيش التسلسل تبعه من amino acids، أسود،
+
+417
+00:38:19,700 --> 00:38:27,230
+أخضر، أحمر، أسود، أزرقتمام؟ الآن كل واحد شكل من
+
+418
+00:38:27,230 --> 00:38:29,870
+هدول، يعني هذا في الـ amino acids ممكن يكون
+
+419
+00:38:29,870 --> 00:38:36,990
+إجليسين، ألانين، سيستين، تريبتوفان، كذا، فما بقدرش
+
+420
+00:38:36,990 --> 00:38:38,830
+أصيغه بصيغة
+
+421
+00:38:41,480 --> 00:38:45,080
+amino acid و بعدين اقول عنه to the end فالان
+
+422
+00:38:45,080 --> 00:38:51,640
+تخيلوا لو كان في عندي مثلا protein من 300 amino
+
+423
+00:38:51,640 --> 00:38:58,780
+acid عشان اعرفه جيدا ايش المطلوب مني اعمل احدد ال
+
+424
+00:38:58,780 --> 00:39:04,200
+300 amino acid مرتبين هذا بيسموه ايش؟ sequence
+
+425
+00:39:04,200 --> 00:39:11,930
+يعني كيف هدول مرتبينأعمل التسلسل تبعه، الآن فكرة
+
+426
+00:39:11,930 --> 00:39:16,490
+ال sequence أو التسلسل غير موجودة في ال
+
+427
+00:39:16,490 --> 00:39:21,170
+polysaccharides، ال polysaccharides نفس الشغلة to
+
+428
+00:39:21,170 --> 00:39:28,380
+the Nمالتوز to the M خلصت واضح بينما في ال
+
+429
+00:39:28,380 --> 00:39:33,100
+proteins هتواجهنا صعوبة ان ال proteins وحدتهم
+
+430
+00:39:33,100 --> 00:39:37,660
+الأساسية amino acids ال amino acids عادة اللي
+
+431
+00:39:37,660 --> 00:39:41,720
+موجودين في ال protein عشرين amino acid الان لما
+
+432
+00:39:41,720 --> 00:39:50,400
+يكون عندى protein من تلتمية amino acid كويس
+
+433
+00:39:50,400 --> 00:39:56,960
+في أشياء مكررة لكنلابد من ال sequence هم اكيد هم
+
+434
+00:39:56,960 --> 00:40:00,580
+اكيد عشرين amino acid تقريبا اللي موجودين في ال
+
+435
+00:40:00,580 --> 00:40:07,180
+proteins لكن هدول العشرين لما بدي اخد منهم protein
+
+436
+00:40:07,180 --> 00:40:15,700
+من تلاتمية amino acid كيف هيكونوا؟ هيكونوا
+
+437
+00:40:15,700 --> 00:40:22,050
+مختلفين مافيش ان احك مثلا glycine to the Nعشان
+
+438
+00:40:22,050 --> 00:40:28,290
+اميز اي protein عن التاني لازم اعد ال 300 ولذلك ال
+
+439
+00:40:28,290 --> 00:40:32,950
+protein لو انا بدى اتكلم عنه انه هل هو real
+
+440
+00:40:32,950 --> 00:40:40,870
+polymer يعني حقيقي بمعنى الكلمة الجواب لأ ال real
+
+441
+00:40:40,870 --> 00:40:48,390
+polymer حقيقة ايش هو؟ monomerto the end زي ما
+
+442
+00:40:48,390 --> 00:40:52,770
+شوفنا ال polyethylene و ال PVC و حتى كمان ال
+
+443
+00:40:52,770 --> 00:40:57,750
+polysaccharides مونومر مكرر لكن هنا لما بدي أجي
+
+444
+00:40:57,750 --> 00:41:01,570
+أحكي عن ال protein هصير أجيب ال amino acids أقول
+
+445
+00:41:01,570 --> 00:41:07,910
+glycine, alanine, tryptophan, cysteine كذا كذا
+
+446
+00:41:07,910 --> 00:41:14,270
+هتلاحظوا أنه مطلوب منناانحدد الترتيب تبع ال amino
+
+447
+00:41:14,270 --> 00:41:17,690
+acids ولذلك ال proteins لو الإنسان بده يستعمل
+
+448
+00:41:17,690 --> 00:41:23,010
+الكلام بدقة أكثر they are macro molecules جزيئات
+
+449
+00:41:23,010 --> 00:41:30,490
+كبيرة macro molecules جزيئات كبيرة أكثر منهم إيش
+
+450
+00:41:30,490 --> 00:41:39,610
+polymers they are macro molecules أكثر منهمبولمار
+
+451
+00:41:39,610 --> 00:41:46,310
+طبعا فيهم نوعا ما شيء مشترك بيخلي بعض الناس يقولوا
+
+452
+00:41:46,310 --> 00:41:54,670
+ممكن تجاوزا نعتبر ال protein بولمار ليش؟ لأنه لو
+
+453
+00:41:54,670 --> 00:42:00,010
+أنا اتطلعت على الهيكل تبعه اللي بتكرر هلاحظ ان هو
+
+454
+00:42:00,010 --> 00:42:05,960
+عبارة عن NCEالان هذه الوحدة بتتكرر في البروتين
+
+455
+00:42:05,960 --> 00:42:12,760
+بعدها N C C double bond O بعدها N C C double bond
+
+456
+00:42:12,760 --> 00:42:19,220
+O هتقولولي مش ناقص غير ايش تكتب هذولة to the N طب
+
+457
+00:42:19,220 --> 00:42:25,870
+ليش مش قادر اكتبهم؟لأن كل amino acid فيها R group
+
+458
+00:42:25,870 --> 00:42:33,210
+مختلفة يعني هذه مرة H هذه مرة CH3 هذه مرة CH2SH
+
+459
+00:42:33,210 --> 00:42:40,430
+فلو بتطلع على الهيكل الأساسي للذرات لبروتين NCC
+
+460
+00:42:40,430 --> 00:42:45,870
+double bond O هو مكرر لكن لو طلعت على هذه المجموعة
+
+461
+00:42:46,670 --> 00:42:51,530
+مش مكررة بناء على ذلك لو هذا مثلا كان بيبتايد هذا
+
+462
+00:42:51,530 --> 00:42:55,810
+بيبتايد مكون من كام amino acid من تلاتة هتعلم أن
+
+463
+00:42:55,810 --> 00:43:00,570
+هذا اسمه إجليسين هذا اسمه ألانين هذا اسمه سيستين
+
+464
+00:43:00,570 --> 00:43:05,450
+حصير أقول هذاEglicin, Alanine, Cysteine هيكون بفرق
+
+465
+00:43:05,450 --> 00:43:08,390
+عن Alanine, Eglicin, Cysteine من نفس التلاتة
+
+466
+00:43:08,390 --> 00:43:14,810
+فانفعلكوا لما نصيح نحكي عن تلاتمية فالبروتين بوجهة
+
+467
+00:43:14,810 --> 00:43:19,870
+النظر اللي بده يتطلع الهيكل الأساسي هو كأنه بوليمر
+
+468
+00:43:19,870 --> 00:43:25,170
+امكرر في N, C, C double bond O N, C, C double bond
+
+469
+00:43:25,170 --> 00:43:28,950
+O لكن لما نيجي نلاحظ أن هذه المجموعة اللي هنا
+
+470
+00:43:28,950 --> 00:43:36,740
+اختلفتبطل polymer ولذلك ال polymer مابنعدش ال 300
+
+471
+00:43:36,740 --> 00:43:40,680
+وحدة ولا ال 5000 وحدة تبعته بس ال protein بدي
+
+472
+00:43:40,680 --> 00:43:45,860
+أجهزة و بدي علم يوم أقول هذا protein كذا يذكر لل
+
+473
+00:43:45,860 --> 00:43:54,170
+5000 وحدة مرتبين و نفس الاشي هيتكرر معاكم مهمفي ال
+
+474
+00:43:54,170 --> 00:43:58,670
+nucleic acids عشان هيك في الشفرة الوراثية وغيرها
+
+475
+00:43:58,670 --> 00:44:02,570
+وغيراتها هتلاحظوا ان البني ادم بيختلف عن التاني و
+
+476
+00:44:02,570 --> 00:44:07,270
+الشغل بتختلف عن التاني انه بدي اذكر الأشياء مرتبة
+
+477
+00:44:08,550 --> 00:44:18,550
+كذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+478
+00:44:18,550 --> 00:44:19,230
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+479
+00:44:19,230 --> 00:44:19,250
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+480
+00:44:19,250 --> 00:44:19,450
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+481
+00:44:19,450 --> 00:44:22,470
+وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا وكذا
+
+482
+00:44:22,470 --> 00:44:25,070
+وكذا
+
+483
+00:44:25,690 --> 00:44:30,730
+جزيئات كبيرة اكثر من ان نسميها Polymers و نقدر
+
+484
+00:44:30,730 --> 00:44:35,170
+نكتب شغلته دي انا الان حيصير درسنا القادم سهل اللي
+
+485
+00:44:35,170 --> 00:44:39,730
+بده يدرس ال proteins ايش أساسهم اذا اول شئ بدنا
+
+486
+00:44:39,730 --> 00:44:45,310
+نتعلم على ال amino acids بعدين ال amino acids بتحد
+
+487
+00:44:45,310 --> 00:44:48,890
+و بيعملوا ال protein نتعلم كيف نوجد ال sequence و
+
+488
+00:44:48,890 --> 00:44:53,390
+كيف نحضر ال protein لو بدنايالكن حيكون ان شاء الله
+
+489
+00:44:53,390 --> 00:44:58,410
+درسنا القادم على الوحدة المكونة للبروتين اللي هي
+
+490
+00:44:58,410 --> 00:45:00,370
+عبارة عن ايش؟ الامام
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-cZOKTp-RbM_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-cZOKTp-RbM_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..d0f068143bbccb8c183919fb88088fb2f701e1e2
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/-cZOKTp-RbM_raw.json
@@ -0,0 +1 @@
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57641, "start": 548.3, "end": 576.42, "text": "بتحطه .. بتفرزه في الإيد و بيسبب القلم الشديد اللي بتعرفه و حتى باللغة الألمانية زي ما احنا بنسمي .. احنا بنسمي النمليك و ما عنده من نمل Amazin فبسموه Amazin Zörey حمض النمل Amazin Zörey واضح؟ فهذه ال form اللي جاية من وين؟ من ال Formic أصل هذه النقطة حسيت أنه ربما بيكون مفيد ان انا أكد عليها في موضوع التسمية", "tokens": [3555, 2655, 5016, 9566, 3224, 4386, 39894, 5172, 2288, 11622, 3224, 8978, 33688, 25708, 4032, 4724, 1829, 35457, 3555, 25062, 19528, 25124, 16254, 3215, 13672, 1829, 39894, 3615, 28480, 3224, 4032, 11331, 49975, 20666, 1211, 17082, 3660, 16247, 19528, 7649, 10632, 30767, 1829, 19446, 1975, 5016, 8315, 44945, 38251, 1829, 4386, 1975, 5016, 8315, 44945, 38251, 1829, 28239, 42213, 1829, 4117, 4032, 19446, 43242, 3224, 9154, 8717, 42213, 2012, 921, 259, 6156, 3555, 38251, 2407, 3224, 2012, 921, 259, 1176, 973, 7950, 11331, 2304, 11242, 28239, 42213, 2012, 921, 259, 1176, 973, 7950, 4032, 46958, 5016, 22807, 6156, 3224, 24192, 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Electrophilic", "probability": 0.837646484375}, {"start": 644.76, "end": 645.5, "word": " Substitution", "probability": 0.87353515625}, {"start": 645.5, "end": 645.84, "word": " مرت", "probability": 0.922607421875}, {"start": 645.84, "end": 646.22, "word": " معنى", "probability": 0.94482421875}, {"start": 646.22, "end": 646.66, "word": " كلمة", "probability": 0.98095703125}, {"start": 646.66, "end": 648.04, "word": " Electrophilic", "probability": 0.94775390625}, {"start": 648.04, "end": 648.84, "word": " موجب", "probability": 0.9171549479166666}, {"start": 648.84, "end": 649.48, "word": " مظبوط", "probability": 0.836328125}, {"start": 649.48, "end": 649.66, "word": " ولا", "probability": 0.958984375}, {"start": 649.66, "end": 649.96, "word": " لأ", "probability": 0.860595703125}, {"start": 649.96, "end": 650.66, "word": " ولذلك", "probability": 0.788818359375}, {"start": 650.66, "end": 651.28, "word": " هتلاحظوا", "probability": 0.9593098958333334}, {"start": 651.28, "end": 651.62, 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substitution إن أشيل سالب أحط مكانه سالب أشيل موجب أحط مكانه موجب لما المرة الماضية على سبيل المثال كنا الفاعل", "tokens": [28814, 1829, 8592, 47525, 3224, 7251, 5016, 9566, 3714, 41361, 3224, 22807, 8608, 6027, 3555, 4032, 5296, 8848, 23275, 39896, 7435, 30241, 8315, 8978, 3714, 41361, 6055, 7649, 1829, 4724, 1211, 5551, 29973, 25894, 8315, 8978, 5551, 2304, 12984, 37977, 8608, 16758, 28671, 45164, 9122, 29399, 14407, 9154, 2655, 3555, 3224, 9957, 294, 308, 1311, 306, 5317, 388, 299, 35827, 36145, 5551, 8592, 26895, 8608, 6027, 3555, 5551, 5016, 9566, 3714, 41361, 3224, 8608, 6027, 3555, 5551, 8592, 26895, 3714, 29245, 3555, 5551, 5016, 9566, 3714, 41361, 3224, 3714, 29245, 3555, 5296, 15042, 9673, 25720, 9673, 46958, 10632, 15844, 8608, 21292, 1211, 9673, 12984, 6027, 9122, 8315, 27188, 995, 30241], "avg_logprob": -0.12985642428870672, "compression_ratio": 1.8047619047619048, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 668.57, "end": 668.91, "word": "إيش", 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"word": " الاسيتلايد", "probability": 0.84482421875}, {"start": 702.8, "end": 703.16, "word": " اخر", "probability": 0.884765625}, {"start": 703.16, "end": 703.7, "word": " تفاعل", "probability": 0.9423828125}, {"start": 703.7, "end": 703.84, "word": " في", "probability": 0.82421875}, {"start": 703.84, "end": 704.92, "word": " الاسيتليانز", "probability": 0.7977701822916666}, {"start": 704.92, "end": 705.38, "word": " قولنا", "probability": 0.6990559895833334}, {"start": 705.38, "end": 705.78, "word": " بنشيل", "probability": 0.9405924479166666}, {"start": 705.78, "end": 706.34, "word": " سالب", "probability": 0.9449869791666666}, {"start": 706.34, "end": 706.7, "word": " و", "probability": 0.8916015625}, {"start": 706.7, "end": 706.92, "word": " نحط", "probability": 0.7527669270833334}, {"start": 706.92, "end": 707.3, "word": " سالب", "probability": 0.98974609375}, {"start": 707.3, "end": 707.82, "word": " الان", "probability": 0.6552734375}, {"start": 707.82, "end": 708.22, "word": " 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Aromatic Substitution ولذلك لو إحنا بنيجي بنسألكم مثلا aromatic compounds undergo addition reactions غلط", "tokens": [5016, 9566, 36081, 2423, 1783, 9673, 29245, 49401, 29538, 3714, 5016, 36520, 3660, 16712, 5172, 995, 30241, 11933, 15730, 16712, 5172, 995, 30241, 11933, 1829, 8592, 4724, 1829, 9381, 13546, 24525, 2304, 3224, 12575, 11741, 388, 299, 1587, 13143, 42090, 6518, 35525, 8848, 23275, 45164, 11933, 5016, 8315, 44945, 1829, 7435, 1829, 44945, 3794, 10721, 23275, 2304, 50113, 15040, 45831, 21810, 26426, 4500, 12215, 32771, 1211, 9566], "avg_logprob": -0.24379595982677796, "compression_ratio": 1.3523316062176165, "no_speech_prob": 0.0, "words": [{"start": 738.16, "end": 738.7, "word": "حطيت", "probability": 0.6922200520833334}, {"start": 738.7, "end": 738.82, "word": " ال", "probability": 0.8173828125}, {"start": 738.82, "end": 739.08, "word": " X", "probability": 0.32421875}, {"start": 739.08, "end": 739.8, "word": " الموجبة", "probability": 0.9026692708333334}, {"start": 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"Aromatic compounds undergo a nucleophilic aromatic substitution برضه غلط لليوكليوفال بيجربش عليها لأنها سالبة كثافة إلكترونية هنا فمين اللي بيقدر يجرب عليها الموجب فلمّا ينسقل الطالب سؤال عام حتى في مقابلة التوظيف لما الواحد بيسأل بهمش يخلي الطالب يعيد كل العلم بس ممكن يقوله ببساطة إيش التفاعل الأساسي لل aromatic compounds؟", "tokens": [10683, 13143, 21810, 26426, 257, 14962, 5317, 388, 299, 45831, 35827, 4724, 43042, 3224, 32771, 1211, 9566, 5296, 20292, 2407, 4117, 20292, 38688, 6027, 4724, 1829, 7435, 25513, 8592, 25894, 11296, 5296, 33456, 11296, 8608, 6027, 49401, 9122, 12984, 31845, 3660, 11933, 23275, 2655, 2288, 11536, 10632, 34105, 6156, 2304, 9957, 13672, 1829, 4724, 1829, 28543, 2288, 7251, 7435, 25513, 25894, 11296, 9673, 29245, 3555, 6156, 19528, 11703, 995, 7251, 1863, 3794, 4587, 1211, 41950, 6027, 3555, 8608, 33604, 6027, 6225, 10943, 11331, 49975, 8978, 3714, 4587, 16758, 37977, 16712, 2407, 19913, 33911, 5296, 15042, 2423, 14407, 24401, 4724, 1829, 3794, 10721, 1211, 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{"start": 768.21, "end": 768.63, "word": " بيقدر", "probability": 0.9686279296875}, {"start": 768.63, "end": 768.93, "word": " يجرب", "probability": 0.9860026041666666}, {"start": 768.93, "end": 769.45, "word": " عليها", "probability": 0.993408203125}, {"start": 769.45, "end": 770.71, "word": " الموجب", "probability": 0.8050130208333334}, {"start": 770.71, "end": 771.83, "word": " فلمّا", "probability": 0.73822021484375}, {"start": 771.83, "end": 772.45, "word": " ينسقل", "probability": 0.754638671875}, {"start": 772.45, "end": 772.97, "word": " الطالب", "probability": 0.9879557291666666}, {"start": 772.97, "end": 773.37, "word": " سؤال", "probability": 0.99462890625}, {"start": 773.37, "end": 773.75, "word": " عام", "probability": 0.998779296875}, {"start": 773.75, "end": 774.31, "word": " حتى", "probability": 0.7998046875}, {"start": 774.31, "end": 774.45, "word": " في", "probability": 0.85791015625}, {"start": 774.45, "end": 775.01, "word": " مقابلة", "probability": 0.9517822265625}, {"start": 775.01, "end": 775.59, "word": " التوظيف", "probability": 0.861572265625}, {"start": 775.59, "end": 775.79, "word": " لما", "probability": 0.78173828125}, {"start": 775.79, "end": 776.05, "word": " الواحد", "probability": 0.97265625}, {"start": 776.05, "end": 776.67, "word": " بيسأل", "probability": 0.98076171875}, {"start": 776.67, "end": 777.45, "word": " بهمش", "probability": 0.5625}, {"start": 777.45, "end": 777.89, "word": " يخلي", "probability": 0.66796875}, {"start": 777.89, "end": 778.25, "word": " الطالب", "probability": 0.9910481770833334}, {"start": 778.25, "end": 778.51, "word": " يعيد", "probability": 0.75732421875}, {"start": 778.51, "end": 778.71, "word": " كل", "probability": 0.943359375}, {"start": 778.71, "end": 779.13, "word": " العلم", "probability": 0.993896484375}, {"start": 779.13, "end": 779.69, "word": " بس", "probability": 0.95654296875}, {"start": 779.69, "end": 780.03, "word": " ممكن", "probability": 0.959228515625}, {"start": 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" أخدت", "probability": 0.9775390625}, {"start": 1047.38, "end": 1047.5, "word": " ال", "probability": 0.9677734375}, {"start": 1047.5, "end": 1048.24, "word": " chlorination", "probability": 0.59515380859375}, {"start": 1048.24, "end": 1048.46, "word": " في", "probability": 0.9365234375}, {"start": 1048.46, "end": 1048.58, "word": " ال", "probability": 0.87646484375}, {"start": 1048.58, "end": 1049.12, "word": " اليفاتيك", "probability": 0.63662109375}, {"start": 1049.12, "end": 1049.88, "word": " كومباونز", "probability": 0.72998046875}, {"start": 1049.88, "end": 1050.38, "word": " زي", "probability": 0.94775390625}, {"start": 1050.38, "end": 1050.48, "word": " ما", "probability": 0.9833984375}, {"start": 1050.48, "end": 1050.74, "word": " كنت", "probability": 0.973388671875}, {"start": 1050.74, "end": 1051.12, "word": " أقول", "probability": 0.96435546875}, {"start": 1051.12, "end": 1051.54, "word": " مثلا", "probability": 0.959716796875}, {"start": 1051.54, "end": 1052.14, "word": " ميثين", "probability": 0.731597900390625}, {"start": 1052.14, "end": 1052.44, "word": " زائد", "probability": 0.726806640625}, {"start": 1052.44, "end": 1053.0, "word": " هالوجين", "probability": 0.8228759765625}, {"start": 1053.0, "end": 1053.42, "word": " كنت", "probability": 0.85595703125}, {"start": 1053.42, "end": 1053.88, "word": " أفعل", "probability": 0.9752604166666666}, {"start": 1053.88, "end": 1055.06, "word": " إيش؟", "probability": 0.8853759765625}, {"start": 1055.06, "end": 1055.96, "word": " Cl2", "probability": 0.93701171875}, {"start": 1055.96, "end": 1056.22, "word": " في", "probability": 0.99169921875}, {"start": 1056.22, "end": 1056.96, "word": " وجود", "probability": 0.927978515625}, {"start": 1056.96, "end": 1059.24, "word": " الضوء", "probability": 0.8883056640625}, {"start": 1059.24, "end": 1059.46, "word": " أو", "probability": 0.88330078125}, {"start": 1059.46, "end": 1060.22, "word": " الحرارة", "probability": 0.9854736328125}], "temperature": 1.0}, {"id": 46, "seek": 108195, "start": 1061.17, "end": 1081.95, "text": "هذا التفاعل مختلف، يتفاعل على الـ aliphatic carbon لما كنا نقول مثان CH4 و بعدين Cl2 في وجود الضوء اللي بنعبر عليه frequency يعني اللي هو تعبير عن الضوء، plant constant في التردد، هذا طاقة الضوء أو heat", "tokens": [3224, 15730, 16712, 5172, 995, 30241, 3714, 46456, 46538, 12399, 7251, 2655, 5172, 995, 30241, 15844, 2423, 39184, 419, 24595, 2399, 5954, 5296, 15042, 9122, 8315, 8717, 39648, 50113, 7649, 5995, 19, 4032, 39182, 9957, 2033, 17, 8978, 49610, 23328, 6024, 114, 2407, 38207, 13672, 1829, 44945, 3615, 26890, 47356, 7893, 37495, 22653, 13672, 1829, 31439, 37279, 3555, 13546, 18871, 6024, 114, 2407, 38207, 12399, 3709, 5754, 8978, 16712, 2288, 3215, 3215, 12399, 23758, 23032, 995, 28671, 6024, 114, 2407, 38207, 34051, 3738], "avg_logprob": -0.30822173115752993, "compression_ratio": 1.509433962264151, "no_speech_prob": 0.0, "words": [{"start": 1061.17, "end": 1061.49, "word": "هذا", "probability": 0.884033203125}, {"start": 1061.49, "end": 1062.03, "word": " التفاعل", "probability": 0.848876953125}, {"start": 1062.03, "end": 1062.71, "word": " مختلف،", "probability": 0.723785400390625}, {"start": 1062.71, "end": 1063.19, "word": " يتفاعل", "probability": 0.809375}, {"start": 1063.19, "end": 1063.33, "word": " على", "probability": 0.87939453125}, {"start": 1063.33, "end": 1063.45, "word": " الـ", "probability": 0.4739990234375}, {"start": 1063.45, "end": 1064.01, "word": " aliphatic", "probability": 0.61767578125}, {"start": 1064.01, "end": 1064.61, "word": " carbon", "probability": 0.90380859375}, {"start": 1064.61, "end": 1065.09, "word": " لما", "probability": 0.629150390625}, {"start": 1065.09, "end": 1065.29, "word": " كنا", "probability": 0.89013671875}, {"start": 1065.29, "end": 1065.51, "word": " نقول", "probability": 0.892822265625}, {"start": 1065.51, "end": 1066.47, "word": " مثان", "probability": 0.4910888671875}, {"start": 1066.47, "end": 1067.61, "word": " CH4", "probability": 0.856201171875}, {"start": 1067.61, "end": 1068.07, "word": " و", "probability": 0.54052734375}, {"start": 1068.07, "end": 1068.67, "word": " بعدين", "probability": 0.6727294921875}, {"start": 1068.67, "end": 1069.67, "word": " Cl2", "probability": 0.6964111328125}, {"start": 1069.67, "end": 1069.89, "word": " في", "probability": 0.85888671875}, {"start": 1069.89, "end": 1070.75, "word": " وجود", "probability": 0.96142578125}, {"start": 1070.75, "end": 1072.01, "word": " الضوء", "probability": 0.9388427734375}, {"start": 1072.01, "end": 1072.15, "word": " اللي", "probability": 0.7130126953125}, {"start": 1072.15, "end": 1072.79, "word": " بنعبر", "probability": 0.7618815104166666}, {"start": 1072.79, "end": 1073.09, "word": " عليه", "probability": 0.98095703125}, {"start": 1073.09, "end": 1073.51, "word": " frequency", "probability": 0.22021484375}, {"start": 1073.51, "end": 1074.41, "word": " يعني", "probability": 0.656494140625}, {"start": 1074.41, "end": 1074.53, "word": " اللي", "probability": 0.924072265625}, {"start": 1074.53, "end": 1074.91, "word": " هو", "probability": 0.95947265625}, {"start": 1074.91, "end": 1077.37, "word": " تعبير", "probability": 0.88818359375}, {"start": 1077.37, "end": 1077.59, "word": " عن", "probability": 0.9755859375}, {"start": 1077.59, "end": 1078.09, "word": " الضوء،", "probability": 0.830078125}, {"start": 1078.09, "end": 1078.37, "word": " plant", "probability": 0.151611328125}, {"start": 1078.37, "end": 1078.91, "word": " constant", "probability": 0.9482421875}, {"start": 1078.91, "end": 1079.17, "word": " في", "probability": 0.9482421875}, {"start": 1079.17, "end": 1080.03, "word": " التردد،", "probability": 0.916015625}, {"start": 1080.03, "end": 1080.19, "word": " هذا", "probability": 0.469482421875}, {"start": 1080.19, "end": 1080.63, "word": " طاقة", "probability": 0.984375}, {"start": 1080.63, "end": 1081.17, "word": " الضوء", "probability": 0.990966796875}, {"start": 1081.17, "end": 1081.59, "word": " أو", "probability": 0.64111328125}, {"start": 1081.59, "end": 1081.95, "word": " heat", "probability": 0.84619140625}], "temperature": 1.0}, {"id": 47, "seek": 110363, "start": 1082.77, "end": 1103.63, "text": "مش هيك احنا عملنا ال chlorineation Cl2 في وجود كذا كذا اه بيعطيني CH3Cl هذا ابدال على ال aliphatic compounds لان لو هذا الكلام اجيت اعمله على aromatic compound على بنزينة مافيش reaction", "tokens": [2304, 8592, 39896, 4117, 1975, 5016, 8315, 6225, 42213, 8315, 2423, 39888, 399, 2033, 17, 8978, 49610, 23328, 9122, 15730, 9122, 15730, 1975, 3224, 4724, 40228, 9566, 9957, 1829, 5995, 18, 9966, 23758, 1975, 44510, 6027, 15844, 2423, 419, 24595, 2399, 21810, 5296, 7649, 45164, 23758, 2423, 28820, 10943, 1975, 7435, 36081, 1975, 25957, 43761, 15844, 45831, 14154, 15844, 44945, 11622, 9957, 3660, 19446, 41185, 8592, 5480], "avg_logprob": -0.21806065782028086, "compression_ratio": 1.4627659574468086, "no_speech_prob": 0.0, "words": [{"start": 1082.77, "end": 1083.09, "word": "مش", 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بيعطيني", "probability": 0.771435546875}, {"start": 1088.05, "end": 1089.39, "word": " CH3Cl", "probability": 0.8919270833333334}, {"start": 1089.39, "end": 1090.31, "word": " هذا", "probability": 0.85107421875}, {"start": 1090.31, "end": 1090.71, "word": " ابدال", "probability": 0.59033203125}, {"start": 1090.71, "end": 1090.87, "word": " على", "probability": 0.79638671875}, {"start": 1090.87, "end": 1090.97, "word": " ال", "probability": 0.96484375}, {"start": 1090.97, "end": 1091.43, "word": " aliphatic", "probability": 0.6488444010416666}, {"start": 1091.43, "end": 1092.03, "word": " compounds", "probability": 0.84716796875}, {"start": 1092.03, "end": 1092.55, "word": " لان", "probability": 0.4833984375}, {"start": 1092.55, "end": 1092.73, "word": " لو", "probability": 0.97607421875}, {"start": 1092.73, "end": 1093.05, "word": " هذا", "probability": 0.92236328125}, {"start": 1093.05, "end": 1093.67, "word": " الكلام", "probability": 0.9650065104166666}, {"start": 1093.67, "end": 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سؤال للأذكية أحيانا", "tokens": [28814, 15730, 47525, 7578, 5551, 29399, 3555, 3224, 24976, 8592, 32887, 9566, 25124, 32887, 9566, 5296, 15042, 9122, 29399, 4724, 5172, 30241, 15844, 9673, 1829, 12984, 26895, 16070, 28814, 1829, 12984, 26895, 4032, 4117, 15730, 9122, 29399, 4724, 16254, 12855, 17, 8978, 49610, 23328, 48812, 2407, 38207, 34051, 11331, 2288, 9640, 3660, 5296, 15042, 4724, 5172, 30241, 15844, 29739, 1863, 11622, 9957, 4724, 16254, 12855, 17, 8978, 49610, 23328, 38637, 2304, 6156, 7578, 12855, 18, 6024, 48506, 4724, 1829, 9381, 13546, 43242, 8315, 8608, 33604, 6027, 24976, 10721, 8848, 4117, 10632, 5551, 5016, 1829, 7649, 995], "avg_logprob": -0.2519329798590277, "compression_ratio": 1.8342857142857143, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1106.14, "end": 1106.46, "word": "إذا", "probability": 0.526458740234375}, {"start": 1106.46, "end": 1106.74, "word": " بدى", "probability": 0.615234375}, {"start": 1106.74, "end": 1107.14, "word": " أنتبه", 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{"start": 2740.64, "end": 2741.7, "word": " وجه", "probability": 0.96484375}, {"start": 2741.7, "end": 2742.24, "word": " ال", "probability": 0.55029296875}, {"start": 2742.24, "end": 2742.58, "word": " 32", "probability": 0.75537109375}, {"start": 2742.58, "end": 2743.28, "word": " منهم", "probability": 0.912109375}, {"start": 2743.28, "end": 2743.58, "word": " أظن", "probability": 0.87109375}, {"start": 2743.58, "end": 2744.12, "word": " 20", "probability": 0.81396484375}, {"start": 2744.12, "end": 2745.54, "word": " سداسي", "probability": 0.9302978515625}, {"start": 2745.54, "end": 2746.12, "word": " و", "probability": 0.96826171875}, {"start": 2746.12, "end": 2746.6, "word": " 12", "probability": 0.85302734375}, {"start": 2746.6, "end": 2747.64, "word": " خماسي", "probability": 0.9508056640625}, {"start": 2747.64, "end": 2748.26, "word": " لو", "probability": 0.95361328125}, {"start": 2748.26, "end": 2748.9, "word": " روحتوا", "probability": 0.894775390625}, {"start": 2748.9, "end": 2749.18, "word": " أنتوا", "probability": 0.78857421875}, {"start": 2749.18, "end": 2749.4, "word": " على", "probability": 0.9375}, {"start": 2749.4, "end": 2749.9, "word": " البيت", "probability": 0.9783528645833334}, {"start": 2749.9, "end": 2750.06, "word": " و", "probability": 0.98583984375}, {"start": 2750.06, "end": 2750.5, "word": " شوفتوا", "probability": 0.86767578125}, {"start": 2750.5, "end": 2750.8, "word": " أي", "probability": 0.81787109375}, {"start": 2750.8, "end": 2751.3, "word": " كرة", "probability": 0.998291015625}, {"start": 2751.3, "end": 2752.74, "word": " موجودة", "probability": 0.9898681640625}, {"start": 2752.74, "end": 2753.56, "word": " عديتوا", "probability": 0.869140625}, {"start": 2753.56, "end": 2753.96, "word": " الوجوه", "probability": 0.80218505859375}, {"start": 2753.96, "end": 2754.1, "word": " اللي", "probability": 0.942138671875}, {"start": 2754.1, "end": 2754.52, "word": " موجودة", "probability": 0.9910888671875}, {"start": 2754.52, "end": 2754.78, "word": " عليها", "probability": 0.77734375}, {"start": 2754.78, "end": 2755.12, "word": " كتبتوا", "probability": 0.90576171875}, {"start": 2755.12, "end": 2755.3, "word": " 1", "probability": 0.44873046875}, {"start": 2755.3, "end": 2755.6, "word": ",2", "probability": 0.571533203125}, {"start": 2755.6, "end": 2755.94, "word": ",3", "probability": 0.9736328125}, {"start": 2755.94, "end": 2756.24, "word": ",4", "probability": 0.958251953125}, {"start": 2756.24, "end": 2756.7, "word": " هتلاقوهم", "probability": 0.799072265625}, {"start": 2756.7, "end": 2756.94, "word": " كام", "probability": 0.891845703125}, {"start": 2756.94, "end": 2757.5, "word": " وجه؟", "probability": 0.91015625}], "temperature": 1.0}, {"id": 115, "seek": 277774, "start": 2757.84, "end": 2777.74, "text": "32 لو عديته النقاط اللي هذا اللي تمثل ال carbon هتلاقوهم كام نقطة؟ 60 نقطة ولذلك سمو هذا كرة الكربون وقيلها تطبيقات كتيرة في الحياة هي أساسا بتشبه المراكبات ال aromatic لكن علم خاص مش موضوعنا أنها", "tokens": [11440, 45164, 6225, 16254, 47395, 28239, 4587, 41193, 13672, 1829, 23758, 13672, 1829, 46811, 12984, 1211, 2423, 5954, 8032, 2655, 15040, 4587, 2407, 16095, 9122, 10943, 8717, 47432, 3660, 22807, 4060, 8717, 47432, 3660, 35525, 8848, 23275, 8608, 2304, 2407, 23758, 9122, 25720, 33251, 25513, 11536, 4032, 4587, 26895, 11296, 6055, 9566, 21292, 4587, 9307, 9122, 2655, 48923, 8978, 21542, 25528, 3660, 39896, 5551, 3794, 32277, 995, 39894, 8592, 3555, 3224, 9673, 23557, 4117, 3555, 9307, 2423, 45831, 44381, 11203, 2304, 16490, 33546, 37893, 3714, 2407, 11242, 45367, 8315, 14739, 11296], "avg_logprob": -0.18631114033253296, "compression_ratio": 1.5648148148148149, "no_speech_prob": 1.0371208190917969e-05, "words": [{"start": 2757.84, "end": 2758.56, "word": "32", "probability": 0.303466796875}, {"start": 2758.56, "end": 2759.66, "word": " لو", "probability": 0.76171875}, {"start": 2759.66, "end": 2760.22, "word": " عديته", "probability": 0.7911783854166666}, {"start": 2760.22, 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0.9676513671875}, {"start": 2773.3, "end": 2773.88, "word": " بتشبه", "probability": 0.8572998046875}, {"start": 2773.88, "end": 2774.6, "word": " المراكبات", "probability": 0.95498046875}, {"start": 2774.6, "end": 2774.72, "word": " ال", "probability": 0.916015625}, {"start": 2774.72, "end": 2775.18, "word": " aromatic", "probability": 0.93603515625}, {"start": 2775.18, "end": 2775.86, "word": " لكن", "probability": 0.900390625}, {"start": 2775.86, "end": 2776.26, "word": " علم", "probability": 0.93212890625}, {"start": 2776.26, "end": 2776.66, "word": " خاص", "probability": 0.992431640625}, {"start": 2776.66, "end": 2776.86, "word": " مش", "probability": 0.96923828125}, {"start": 2776.86, "end": 2777.38, "word": " موضوعنا", "probability": 0.98837890625}, {"start": 2777.38, "end": 2777.74, "word": " أنها", "probability": 0.6802978515625}], "temperature": 1.0}, {"id": 116, "seek": 279523, "start": 2778.47, "end": 2795.23, "text": "انه الآن نحكي فيه اللي جابها اللي فيها الحلقات السداسية اللي فيها الحلقات السداسية واكتشاف يعني جديد ويله كثير من التطبيقات، ابهيك بننهي اليوم ونشكركوا على حصن باسمنا", "tokens": [7649, 3224, 6024, 48506, 8717, 5016, 4117, 1829, 8978, 3224, 13672, 1829, 10874, 16758, 11296, 13672, 1829, 8978, 11296, 21542, 1211, 4587, 9307, 21136, 3215, 32277, 10632, 13672, 1829, 8978, 11296, 21542, 1211, 4587, 9307, 21136, 3215, 32277, 10632, 36764, 4117, 2655, 8592, 31845, 37495, 22653, 10874, 16254, 3215, 4032, 26895, 3224, 9122, 12984, 13546, 9154, 16712, 9566, 21292, 4587, 9307, 12399, 48127, 3224, 1829, 4117, 44945, 1863, 3224, 1829, 45595, 20498, 4032, 1863, 8592, 37983, 4117, 14407, 15844, 11331, 9381, 1863, 4724, 32277, 2304, 8315], "avg_logprob": -0.19863505644359808, "compression_ratio": 1.90625, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2778.47, "end": 2778.83, "word": "انه", "probability": 0.65283203125}, {"start": 2778.83, "end": 2779.17, "word": " الآن", "probability": 0.62744140625}, {"start": 2779.17, "end": 2779.77, "word": " نحكي", "probability": 0.9652099609375}, {"start": 2779.77, "end": 2780.03, "word": " فيه", "probability": 0.840087890625}, {"start": 2780.03, "end": 2780.29, "word": " اللي", "probability": 0.75439453125}, {"start": 2780.29, "end": 2780.85, "word": " جابها", "probability": 0.9801432291666666}, {"start": 2780.85, "end": 2781.33, "word": " اللي", "probability": 0.6290283203125}, {"start": 2781.33, "end": 2781.55, "word": " فيها", "probability": 0.957763671875}, {"start": 2781.55, "end": 2782.13, "word": " الحلقات", "probability": 0.9957275390625}, {"start": 2782.13, "end": 2783.15, "word": " السداسية", "probability": 0.81201171875}, {"start": 2783.15, "end": 2783.61, "word": " اللي", "probability": 0.850341796875}, {"start": 2783.61, "end": 2783.81, "word": " فيها", "probability": 0.964111328125}, {"start": 2783.81, "end": 2784.73, "word": " الحلقات", "probability": 0.9544677734375}, {"start": 2784.73, "end": 2785.83, "word": " السداسية", "probability": 0.9732666015625}, {"start": 2785.83, "end": 2786.67, "word": " واكتشاف", "probability": 0.892333984375}, {"start": 2786.67, "end": 2787.57, "word": " يعني", "probability": 0.82763671875}, {"start": 2787.57, "end": 2788.57, "word": " جديد", "probability": 0.9943033854166666}, {"start": 2788.57, "end": 2789.01, "word": " ويله", "probability": 0.75830078125}, {"start": 2789.01, "end": 2789.53, "word": " كثير", "probability": 0.9796549479166666}, {"start": 2789.53, "end": 2789.69, "word": " من", "probability": 0.99462890625}, {"start": 2789.69, "end": 2790.55, "word": " التطبيقات،", "probability": 0.8690185546875}, {"start": 2790.55, "end": 2791.01, "word": " ابهيك", "probability": 0.642578125}, {"start": 2791.01, "end": 2791.65, "word": " بننهي", "probability": 0.8536376953125}, {"start": 2791.65, "end": 2792.41, "word": " اليوم", "probability": 0.94580078125}, {"start": 2792.41, "end": 2793.61, "word": " ونشكركوا", "probability": 0.8215738932291666}, {"start": 2793.61, "end": 2793.83, "word": " على", 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/1TcAfdTqDds.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/1TcAfdTqDds.srt
new file mode 100644
index 0000000000000000000000000000000000000000..9e74ad70d529cffd12707c7ab4028708265a4e33
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/1TcAfdTqDds.srt
@@ -0,0 +1,1647 @@
+1
+00:00:20,690 --> 00:00:24,750
+بسم الله الرحمن الرحيم في موضوع الـ stereochemistry
+
+2
+00:00:24,750 --> 00:00:29,730
+ربما المرة الماضية نوّهنا من خلال أمثلة تطبيقية من
+
+3
+00:00:29,730 --> 00:00:36,970
+خلال أهمية فهم الـ stereo isomers في الحياة العملية
+
+4
+00:00:36,970 --> 00:00:42,990
+أن هذا موضوع مهم ولذلك سنظل نتوسع فيه بعد ما
+
+5
+00:00:42,990 --> 00:00:46,830
+أخذنا المركبات اللي فيها one chiral center قلنا
+
+6
+00:00:46,830 --> 00:00:51,610
+الـ one chiral center يعطي فقط two isomers بعد ذلك
+
+7
+00:00:51,610 --> 00:00:56,690
+إذا زاد العدد يبدأ عدد الـ isomers في الزيادة، طبعا يحكم
+
+8
+00:00:56,690 --> 00:01:00,890
+الأمر المعادلة 2<sup>n</sup> لكن الـ 2<sup>n</sup>
+
+9
+00:01:00,890 --> 00:01:05,230
+هذا أقصى عدد ممكن من الـ isomers في كل الأحوال، ممكن
+
+10
+00:01:05,230 --> 00:01:10,290
+يكون العدد أقل من ذلك، وقلنا سنعطي مثالاً على العدد
+
+11
+00:01:10,290 --> 00:01:15,330
+الأقصى ومثالاً على عندما يكون العدد أقل في حالة ما
+
+12
+00:01:15,330 --> 00:01:20,620
+عندنا two chiral centers، بدأنا في مثال كنا نعدّه
+
+13
+00:01:20,620 --> 00:01:25,140
+ناخذه على أنه مثال بسيط، يعني الفكرة مركب واحد، لما
+
+14
+00:01:25,140 --> 00:01:29,620
+نيجي نقول 2,3-dichloropentene، بالفكرة مركب
+
+15
+00:01:29,620 --> 00:01:33,640
+واحد، لكن لما نيجي نتطلع على موقع اثنين وعلى موقع
+
+16
+00:01:33,640 --> 00:01:39,410
+ثلاثة، نلاحظ أن الاثنين they are chiral centers
+
+17
+00:01:39,410 --> 00:01:42,750
+وبناءً على ذلك نبدأ نتوقع كم مركباً سيصبح
+
+18
+00:01:42,750 --> 00:01:48,890
+عندنا أربعة مركبات، جربنا نرسمها من خلال أن نتخيل
+
+19
+00:01:48,890 --> 00:01:52,010
+مثلاً، بدنا نأخذ السلسلة الكربونية بهذا الشكل، يعني
+
+20
+00:01:52,010 --> 00:01:56,970
+الخمس كربونات، واحد، اثنان، ثلاثة، وأربعة، خمسة
+
+21
+00:01:56,970 --> 00:02:01,390
+CH<sub>2</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub>
+
+22
+00:02:01,390 --> 00:02:06,770
+CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub>
+
+23
+00:02:06,770 --> 00:02:08,170
+CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub>
+
+24
+00:02:08,170 --> 00:02:08,950
+CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub>
+
+25
+00:02:08,950 --> 00:02:09,750
+CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub>
+
+26
+00:02:09,750 --> 00:02:10,270
+CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub>
+
+27
+00:02:10,270 --> 00:02:11,790
+CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub>
+
+28
+00:02:11,790 --> 00:02:13,190
+CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub>
+
+29
+00:02:13,190 --> 00:02:23,190
+CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub> CH<sub>3</sub>
+
+30
+00:02:23,190 --> 00:02:27,670
+CH<sub>3</sub> CH يعني الـ R عكس S، الـ R عكس S، كلام منطقي الآن
+
+31
+00:02:27,670 --> 00:02:32,110
+لو جئنا ننظر إلى المركب الثاني 2R 3S هذا
+
+32
+00:02:32,110 --> 00:02:37,870
+عكسه، الـ R  أصبح S، الـ S أصبح R، لأنه دائماً صورة
+
+33
+00:02:37,870 --> 00:02:43,590
+مرآة تعني التعاكس التام، فلو سألنا
+
+34
+00:02:43,590 --> 00:02:48,170
+ما العلاقة بين واحد واثنين؟ they are enantiomers، و
+
+35
+00:02:48,170 --> 00:02:52,290
+يصبح المفهوم عندنا أن أي مركبين نقول عنهما
+
+36
+00:02:52,290 --> 00:02:58,650
+enantiomers، ستكون إشاراتهما عكس بعض، الآن طبعاً أنتم
+
+37
+00:02:58,650 --> 00:03:02,390
+بالنظر تقولون صورة بعض في المرآة غير متطابقتين، لكن
+
+38
+00:03:02,390 --> 00:03:08,390
+لا تنسوا شيئاً، أنه بإمكاني رسم
+
+39
+00:03:09,150 --> 00:03:13,850
+المركب بطرق مختلفة بحيث أنه أنتم بمجرد النظر
+
+40
+00:03:13,850 --> 00:03:18,430
+البسيط، لا تستطيعون اتخاذ قرار من مجرد النظر، وجهة القرار
+
+41
+00:03:18,430 --> 00:03:21,750
+الأكيدة تستطيعون اتخاذها من ماذا؟ ما العلاقة بين
+
+42
+00:03:21,750 --> 00:03:29,110
+المركبين من قيم R و S،  دعوني أؤكد هذه الفكرة، لو
+
+43
+00:03:29,110 --> 00:03:34,310
+فقط أريد أن أعمل معكم على مركب فيه one chiral
+
+44
+00:03:34,310 --> 00:03:40,470
+center، لو رسمت منه شكلين، ما الاحتمالات المتوقعة؟
+
+45
+00:03:40,470 --> 00:03:43,610
+لما يكون عندي one chiral center؟ إما أن يكون
+
+46
+00:03:43,610 --> 00:03:48,910
+المركب نفسه مرسوماً بطريقتين مختلفتين، إما أن يكون
+
+47
+00:03:48,910 --> 00:03:51,410
+enantiomers، ليس لدي احتمال آخر.
+
+48
+00:03:53,870 --> 00:04:01,450
+أخذ بسرعة عشوائياً، هذا مركب CH<sub>3</sub>ClPR، وهذا مركب كتبت
+
+49
+00:04:01,450 --> 00:04:08,010
+هنا الـ PR، وهنا الـ H، وهنا الـ Cl، وهنا الـ CH<sub>3</sub>، لاحظوا
+
+50
+00:04:08,010 --> 00:04:12,610
+هذين المركبين، لو سألتكم: ما العلاقة بينهما؟ الذي
+
+51
+00:04:12,610 --> 00:04:16,030
+يأتي ويتطلع ويشوف أي شيء بالبصر وفي المرآة، و
+
+52
+00:04:16,030 --> 00:04:22,100
+يُطبّقه ولا يُطبّقه، حتى لن تستطيع، لأني رسمتهما
+
+53
+00:04:22,100 --> 00:04:25,640
+بطرق مختلفة، لا أحد يمنعني من رسمهما بطرق مختلفة،
+
+54
+00:04:25,640 --> 00:04:31,700
+الآن أسهل شيء أن أحدد لكل مركب R أو S، الآن إذا
+
+55
+00:04:31,700 --> 00:04:35,500
+هذا طلع R وهذا R، معنى ذلك نفس المركب مرسوم بطرق
+
+56
+00:04:35,500 --> 00:04:40,800
+مختلفة، S و S نفس المركب، إذا هذا R وهذا S, they
+
+57
+00:04:40,800 --> 00:04:44,140
+are enantiomers، إذا هذا S وهذا R, they are
+
+58
+00:04:44,140 --> 00:04:48,260
+enantiomers، هكذا تكون أسهل طريقة لأعملهما، ولذلك
+
+59
+00:04:48,260 --> 00:04:54,380
+لو أردت أن آتي لأحدد أقل مجموع الـ H في RClCH<sub>3</sub> من
+
+60
+00:04:54,380 --> 00:05:00,660
+بين R و S، لأن هذا الـ H للأمام، الآن لو أردت
+
+61
+00:05:00,660 --> 00:05:12,780
+المركب الثاني في R Cl S CH<sub>3</sub>، بين R مرة ثانية ونجعلها
+
+62
+00:05:12,780 --> 00:05:18,100
+R لأن الـ H للخلف، هذان الآن enantiomers، طالما أحدهما R
+
+63
+00:05:18,100 --> 00:05:21,380
+والآخر R، إذا we are in enantiomers، فـ enantiomers
+
+64
+00:05:21,380 --> 00:05:25,040
+دائماً عكس بعض، الآن لو عندكم خمسة chiral centers
+
+65
+00:05:25,040 --> 00:05:29,520
+وليس واحداً، ماذا يكون في الخمسة ليكونوا
+
+66
+00:05:29,520 --> 00:05:35,300
+مركبين enantiomers؟ كل واحد عكس الآخر، كما لو أنني أقف
+
+67
+00:05:35,300 --> 00:05:38,420
+أمام المرآة، اليدين عكس بعض، الوجه عكس بعض، البطن
+
+68
+00:05:38,420 --> 00:05:42,060
+عكس بعض، الرجلين عكس بعض، كل شيء يكون عكس الآخر،
+
+69
+00:05:42,060 --> 00:05:45,120
+يعني لو عندي، إن شاء الله، عشرون chiral center في
+
+70
+00:05:45,120 --> 00:05:49,600
+مركب، فـ enantiomers، العشرون المقابلة تكون
+
+71
+00:05:49,600 --> 00:05:56,300
+عكسها، لو واحدة اختلفت، يبطلان  enantiomers، على
+
+72
+00:05:56,300 --> 00:05:59,840
+طول، يبطلان صورة بعض في المرآة، إذا بطلان صورة بعض
+
+73
+00:05:59,840 --> 00:06:04,700
+في المرآة، ماذا يصبحان؟ diastereomers، لا تنسوا أن
+
+74
+00:06:04,700 --> 00:06:08,740
+عرفنا diastereomers، they are non-mirror
+
+75
+00:06:08,740 --> 00:06:12,580
+image،  enantiomers، ولذلك لو سألت: العلاقة بين
+
+76
+00:06:12,580 --> 00:06:20,780
+هذين، دعونا نوضحها بأسماء R و S، عكس بعض، عكس بعض، إذا
+
+77
+00:06:20,780 --> 00:06:24,580
+they are enantiomers، واضح؟ الآن لو سألت: هذان
+
+78
+00:06:24,580 --> 00:06:33,560
+الاثنان R S، S R، عكس، طلع عليهما R  أصبح S، S أصبح R،
+
+79
+00:06:33,560 --> 00:06:39,320
+عكس بعض، they are enantiomers، الآن لو جئت أخذت مثلاً
+
+80
+00:06:39,320 --> 00:06:49,160
+المركب واحد مع ثلاثة، انظروا R و R، هذان مثل بعضهما، و
+
+81
+00:06:49,160 --> 00:06:56,860
+R و S عكس بعض، هل هذان عكس بعض تماماً؟ لا
+
+82
+00:06:56,860 --> 00:07:01,500
+هل هذان مثل بعضهما تماماً؟ لا، لماذا لم يكونا عكس بعض
+
+83
+00:07:01,500 --> 00:07:04,560
+تماماً، يعني كل نقطة عكس الأخرى؟ they are
+
+84
+00:07:04,560 --> 00:07:10,000
+enantiomers، الآن لو كل نقطة مثل الأخرى they are
+
+85
+00:07:10,000 --> 00:07:14,600
+the same compound، لو كل نقطة مثل الأخرى هو نفس
+
+86
+00:07:14,600 --> 00:07:20,760
+المركب، الـ R ماذا؟ مثل بعض، و ماذا؟ عكس بعض، بطلان صورة
+
+87
+00:07:20,760 --> 00:07:24,400
+بعض في المرآة أو بطلان نفس المركب، ماذا نسميهما؟ ها
+
+88
+00:07:24,400 --> 00:07:28,180
+الـ diastereomers، إذا لما نيجي نتطلع أنه نريد أن نفهم
+
+89
+00:07:28,180 --> 00:07:32,260
+العلاقة بين مركبين من خلال الرموز، سنقول أن
+
+90
+00:07:32,260 --> 00:07:36,260
+عندنا ثلاثة احتمالات، في حالة ما عندي أكثر من chiral
+
+91
+00:07:36,260 --> 00:07:40,600
+center، لحظة، لما كان عندي one chiral center، بدون ما
+
+92
+00:07:40,600 --> 00:07:44,080
+أعمل R و S، أقول لكم: عندي احتمالين، إما أن يكونا
+
+93
+00:07:44,080 --> 00:07:50,120
+نفس المركب R R S S، إما أن يكونا enantiomers S R أو R S، الآن لو كان عندي more than one chiral
+
+94
+00:07:50,120 --> 00:07:54,840
+center، عندي ثلاثة احتمالات، الاحتمال الأول أن يكونا
+
+95
+00:07:54,840 --> 00:07:57,960
+enantiomers، كل شيء عكس بعض، الاحتمال
+
+96
+00:07:57,960 --> 00:08:03,440
+الثاني أن يكونا نفس المركب، كل شيء نفسه، مثل بعض، طيب
+
+97
+00:08:03,440 --> 00:08:09,150
+لو طلع شيء عكس وشيء مثل بعض، وجدنا R هذا diastereomers،
+
+98
+00:08:09,150 --> 00:08:12,950
+لاحظوا الآن، لو جئت على واحد وثلاثة R و S عكس
+
+99
+00:08:12,950 --> 00:08:18,370
+بعض، R و R مثل بعض، إذا هذان صورة بعض في المرآة؟ لا
+
+100
+00:08:18,370 --> 00:08:23,670
+نفس المركب؟ لا، ها diastereomers، إذا واحد وثلاثة ها diastereomers، لو طبقناها مرة ثانية على واحد، و
+
+101
+00:08:28,530 --> 00:08:31,970
+أربعة مثلاً، ما العلاقة بينهما؟ R و S عكس بعض، هم
+
+102
+00:08:31,970 --> 00:08:39,700
+لاحظين؟ R و R نفس بعض، they are diastereomers، لو
+
+103
+00:08:39,700 --> 00:08:47,540
+جئنا نظرنا إلى اثنين وثلاثة،
+
+104
+00:08:47,540 --> 00:08:52,720
+لاحظوا؟ S و R عكس بعض، و S مثل بعض، كذلك الحال لو
+
+105
+00:08:52,720 --> 00:09:02,010
+نظرنا لـ اثنين وأربعة،
+
+106
+00:09:02,010 --> 00:09:08,070
+لاحظوا؟ S  مثل بعض، و S عكس بعض، they are diastereomers، واضح؟ أصبح عندي نوع آخر من
+
+107
+00:09:08,070 --> 00:09:13,230
+الـ diastereomers، جاء من أين؟ جاء من المركبات فيها
+
+108
+00:09:13,230 --> 00:09:17,590
+chiral centers، يعني نحن أول ما أخذنا تعريف
+
+109
+00:09:17,590 --> 00:09:20,910
+الـ diastereomers قلنا: كل شيء ليس صورة بعض في
+
+110
+00:09:20,910 --> 00:09:25,270
+المرآة، they are diastereomers، الأمثلة الكيميائية
+
+111
+00:09:25,270 --> 00:09:29,500
+الأولى التي أخذناها، ما هي؟ الـ cis والـ trans أو
+
+112
+00:09:29,500 --> 00:09:33,820
+الـ Z والـ E، they are diastereomers، الآن يأتينا
+
+113
+00:09:33,820 --> 00:09:37,300
+أمثلة أخرى لما يكون عندي more than one chiral
+
+114
+00:09:37,300 --> 00:09:40,900
+center، هذه الأمثلة تقول:  أن لو كان عندي
+
+115
+00:09:40,900 --> 00:09:45,160
+مركبين، في الإشارات تبعتهما ليست  مثل بعضها تماماً، ليست نفس
+
+116
+00:09:45,160 --> 00:09:51,530
+المركب، ولا enantiomers، و they are
+
+117
+00:09:51,530 --> 00:09:54,650
+stereoisomers، ماذا نسميهما؟ diastereomers، واضح؟
+
+118
+00:09:54,650 --> 00:10:00,010
+وبذلك أخذنا أن diastereomers بكم كان،  نشاهدهم
+
+119
+00:10:00,010 --> 00:10:05,270
+بالكيمياء العضوية، بالـ cis trans أو Z E، وبالـ chiral
+
+120
+00:10:05,270 --> 00:10:11,460
+compounds أو بالـ stereochemistry لما يكون عندي
+
+121
+00:10:11,460 --> 00:10:15,680
+أكثر من chiral center، بشرط أن ننتبه لـ R و S
+
+122
+00:10:15,680 --> 00:10:21,440
+بالطريقة التي تكلمنا فيها، الآن طالما أن هذين لهما
+
+123
+00:10:21,440 --> 00:10:27,760
+إشارات مختلفة، كم مركباً عندي في 2,3-dichloropentene؟
+
+124
+00:10:27,760 --> 00:10:31,760
+أربعة، هي رموزها التي تريد أن تشتريها من
+
+125
+00:10:31,760 --> 00:10:36,180
+السوق، ستجدها أربعة مركبات، الآن قلنا ممكن
+
+126
+00:10:36,180 --> 00:10:39,800
+يكون العدد أقل، نأخذ مثالاً، هذا المثال 2,3-
+
+127
+00:10:39,800 --> 00:10:46,760
+dichlorobutane، قال: ذرة كربون واحدة، يعني لو أنا
+
+128
+00:10:46,760 --> 00:10:51,800
+رسمت، ها كربون، اثنان، ثلاثة، أربعة، إذا المركب الذي
+
+129
+00:10:51,800 --> 00:10:56,080
+عندي، ما هو؟ بيوتان، واضح؟ لاحظوا ما الذي يفرق كثيراً
+
+130
+00:10:56,080 --> 00:11:02,100
+بين البيوتان وبين البنتان؟ لو أنا مجرد كتابة مثل
+
+131
+00:11:02,100 --> 00:11:09,120
+CH<sub>3</sub>CHClCHClCH<sub>3</sub>، تعرفون ما الذي يفرق؟ لو جئت بين
+
+132
+00:11:09,120 --> 00:11:17,800
+هذين chiral centers، الكربونات التي
+
+133
+00:11:17,800 --> 00:11:20,840
+حاملة كلور، وجسمت المركب من المنتصف، تنظرون هنا ما
+
+134
+00:11:20,840 --> 00:11:26,760
+الذي موجود؟ كربون حاملة HCl ثم CH<sub>3</sub>، وهنا
+
+135
+00:11:26,760 --> 00:11:33,460
+كربون حاملة HCl ثم CH<sub>3</sub>، إذا هذا المركب أصبح
+
+136
+00:11:33,460 --> 00:11:39,240
+مركب متماثل، قبل قليل لما كنت... أو من هنا إلى هذا
+
+137
+00:11:39,240 --> 00:11:44,460
+الشكل، أجسّم مثل هذا، تنظرون كأعداد ذرات ماذا عندكم
+
+138
+00:11:44,460 --> 00:11:49,800
+هنا؟ كربون حاملة HCl و CH<sub>3</sub>، وهنا كربون حاملة HCl
+
+139
+00:11:49,800 --> 00:12:01,860
+و CH<sub>3</sub>، فعدد الذرات التي في هذا الاتجاه هو نفس عدد
+
+140
+00:12:01,860 --> 00:12:05,760
+الذرات التي في هذا الاتجاه، فهذا الكربون يحمل نوعاً
+
+141
+00:12:05,760 --> 00:12:10,380
+من التماثل، هذا الكلام في المثال السابق لم يكن موجوداً، لما
+
+142
+00:12:10,380 --> 00:12:16,160
+كنتم تحطون خطاً هنا بين الـ two chiral centers، عدّوا
+
+143
+00:12:16,160 --> 00:12:22,780
+كل الذرات التي حولها C و H و Cl و CH<sub>3</sub> وهنا CH و Cl
+
+144
+00:12:22,780 --> 00:12:29,460
+ثم CH<sub>2</sub>CH<sub>3</sub>، إذا هل هذا النص مثل هذا النص؟ لا، في
+
+145
+00:12:29,460 --> 00:12:34,910
+حالة البيوتان، ففي البيوتان تماثل داخلي بين الـ two
+
+146
+00:12:34,910 --> 00:12:39,790
+chiral centers، يعني المركب متماثل، الآن لو جئنا
+
+147
+00:12:39,790 --> 00:12:44,310
+جربنا نرسم الـ isomers بنفس الطريقة التي تعلمناها
+
+148
+00:12:44,310 --> 00:12:51,270
+سابقاً، يعني آتي وأضع اثنين كلور عكس بعض وصورتهما في
+
+149
+00:12:51,270 --> 00:12:54,810
+المرآة، واثنين كلور على جهة واحدة وصورتهما في
+
+150
+00:12:54,810 --> 00:13:02,210
+المرآة، ثم أحدد R و S، لاحظوا هذه الرسمة تماماً
+
+151
+00:13:02,210 --> 00:13:06,510
+هي نسخ ولصق من الرسمة السابقة، بس بدل ما كنا
+
+152
+00:13:06,510 --> 00:13:12,890
+كاتبون هنا إيثل كتبنا ميثل، واضح؟ ولذلك أنتم الآن
+
+153
+00:13:12,890 --> 00:13:20,310
+كم مركباً تشاهدون؟ ما زلتم تشاهدون أربعة مركبات
+
+154
+00:13:20,310 --> 00:13:26,150
+للوهلة الأولى، لكن لو نظرنا بعمق لهذين الأربعة
+
+155
+00:13:26,150 --> 00:13:32,130
+مركبات، سنلاحظ أن هذا 2R 3R وهذا 2S 3S،
+
+156
+00:13:34,300 --> 00:13:40,660
+عكس بعض، ستأتون وتستنتجون أنهم enantiomers، ليس هناك خلاف الآن، لما تأتون وتنظرون إلى المركبين الآخرين
+
+157
+00:13:40,660 --> 00:13:45,160
+ودعونا نقول... نقول الترقيم واحد اثنان ثلاثة
+
+158
+00:13:45,160 --> 00:13:49,140
+أربعة، واحد اثنان ثلاثة أربعة، وسنأخذ واحداً فقط
+
+159
+00:13:49,140 --> 00:13:55,720
+نؤكده، هي الـ Cl رقم واحد، وهذه الكربون الحاملة Cl<sub>2</sub>
+
+160
+00:13:55,720 --> 00:14:01,560
+و CH<sub>3</sub>، بين S كتبناها R، وهذه لو أردنا أن ننظر إليها 1 2
+
+161
+00:14:01,560 --> 00:14:09,860
+Cl ثم كربون حاملة Cl ثم CH<sub>3</sub>، Cl ثم
+
+223
+00:18:52,420 --> 00:18:56,880
+اللي بعده المتماثل لو أنا رقمته زي ما أنتم شايفين
+
+224
+00:18:56,880 --> 00:19:06,100
+بالأزرق صح، ولو أنا رقمته بالأحمر صح. طيب اللي رقمته
+
+225
+00:19:06,100 --> 00:19:12,660
+بالأزرق كتبت المركب 2R,3S-2,3- Dichlorobutane
+
+226
+00:19:12,660 --> 00:19:17,390
+طب واللي بده يرقم بالأحمر شو حتكتب؟ الـ 2 ما احنا
+
+227
+00:19:17,390 --> 00:19:21,950
+عارفين أن هذه R وهذه S بغض النظر عن الترقيم، حتكتب
+
+228
+00:19:21,950 --> 00:19:25,270
+2S,3R
+
+229
+00:19:25,270 --> 00:19:30,930
+الآن أي جواب اللي بدنا نعتبره صح؟ الجوابين صح، هذا
+
+230
+00:19:30,930 --> 00:19:36,610
+له اسمين، هذا له اسمين لأنه متماثل، وعشان هيك المدرس
+
+231
+00:19:36,610 --> 00:19:40,250
+اللي بده يصلح بيجيب لكم هذا المركب ويقول لكم أعطوه
+
+232
+00:19:40,250 --> 00:19:45,680
+اسمه. هذا الجواب يبدو يعتبره صح، وهذا الجواب يبدو
+
+233
+00:19:45,680 --> 00:19:49,600
+يعتبره صح لسبب بسيط أنه ما فيه فرق نهائي بين أنكم
+
+234
+00:19:49,600 --> 00:19:54,280
+ترقموه من هنا أو من هنا، الآن نفس الشيء في المركب
+
+235
+00:19:54,280 --> 00:19:58,900
+التاني. لما رقمناه بالأزرق واحد اثنين ثلاثة أربعة
+
+236
+00:19:58,900 --> 00:20:05,140
+طب لو واحدة عملت له ترقيم ثاني بالأحمر، إيش حتكتبه؟
+
+237
+00:20:05,140 --> 00:20:11,040
+2R,3S. الآن انظروا، هذا أحد أسماء 2S,
+
+238
+00:20:11,040 --> 00:20:19,770
+3R. هذا أحد أسمائه 2R,3S
+
+239
+00:20:19,770 --> 00:20:28,590
+وهذا 2R,3S لأن الجزء ببساطة متماثل، لأن هذا الجزء
+
+240
+00:20:28,590 --> 00:20:33,490
+ببساطة متماثل، بياخذ اسمين، وهذول الشكلين بيكونوا
+
+241
+00:20:33,490 --> 00:20:38,710
+مركب واحد، مش مركبين، واضح؟ مركب واحد وبتسمى
+
+242
+00:20:38,710 --> 00:20:42,110
+بطريقتين. الآن إذا اتفقنا أن هذول they are the
+
+243
+00:20:42,110 --> 00:20:46,250
+same compound، بأكثر من طريقة فرجيتكم، اللي بدأ من
+
+244
+00:20:46,250 --> 00:20:49,710
+خلال الإشارات، أنه يلهم نفس الإشارات، أيه؟ يلهم
+
+245
+00:20:49,710 --> 00:20:56,750
+نفس الإشارات ولا لأ؟ 2R, 3S .. 2S, 3R .. 2S, 3R .. 2S,
+
+246
+00:20:56,750 --> 00:21:04,650
+3R .. 2S, 3R .. 2S, 3R .. 2S, 3R .. 2S, 3R .. 2S, 3R ..
+
+247
+00:21:04,650 --> 00:21:05,570
+2S, 3R .. 2S, 3R .. 2S, 3R .. 2S, 3R .. 2S, 3R ..
+
+248
+00:21:05,570 --> 00:21:05,730
+.. 2S, 3R .. 2S, 3R .. 2S, 3R .. 2S, 3R .. 2S, 3R ..
+
+249
+00:21:05,730 --> 00:21:05,930
+2S, 3R .. 2S, 3R .. 2S, 3R .. 2S, 3R .. 2S, 3R ..
+
+250
+00:21:05,930 --> 00:21:06,830
+2S, 3R .. 2S, 3R .. 2S, 3R .. 2S, 3R .. 2S, 3R ..
+
+251
+00:21:06,830 --> 00:21:14,070
+2S, 3R .. 2S, 3R .. 2S, 3R .. 2S, 3R .. 2S, 3R ..
+
+252
+00:21:14,070 --> 00:21:21,840
+2S, 3R .. 2S, 3R. وغيرهم سواء سمّيته 2R,3S أو 2S,3R هو نفس
+
+253
+00:21:21,840 --> 00:21:26,100
+المركب، له اسمين، نفس المركب له اسمين، شو اللي عمله
+
+254
+00:21:26,100 --> 00:21:31,660
+الاسمين؟ التماثل. إذا لو أنا بأجي أسأل ببساطة لو
+
+255
+00:21:31,660 --> 00:21:35,480
+واحدة على طول بده تعرف أنه عندها أربعة مركبات ولا
+
+256
+00:21:35,480 --> 00:21:40,320
+ثلاثة؟ إيش أول ما بده تطلع عليه؟ في الجزء أنه هل يا
+
+257
+00:21:40,320 --> 00:21:44,460
+ترى هذا الجزء اللي عنده فيه تماثل ولا لا. إذا فيه
+
+258
+00:21:44,460 --> 00:21:49,620
+تماثل، على طول بده تحكي عن كم مركب؟ عن ثلاثة. ما فيش
+
+259
+00:21:49,620 --> 00:21:53,820
+تماثل، بده تحكي عن أربعة. يعني لو مثلاً سألكم هذا
+
+260
+00:21:53,820 --> 00:22:05,280
+السؤال CH3CHBrCHClCH3 كم chiral center فيه؟ هن،
+
+261
+00:22:05,280 --> 00:22:09,200
+هن قبل ما أرسم، ايزومرات، كم ايزومر
+
+262
+00:22:09,200 --> 00:22:14,480
+تتوقعوا له؟ أربعة، على طول أربعة، ليش؟ لأنه أنا لو جيت
+
+263
+00:22:14,480 --> 00:22:18,260
+بين هذول two chiral centers هذه الذرات مش هي هذه
+
+264
+00:22:18,260 --> 00:22:25,060
+الذرات هنا عندكم H وCl، هنا H .. خلاص انتهى، واضح؟
+
+265
+00:22:25,060 --> 00:22:31,600
+وهكذا، واضح. الآن هذا المركب اللي فيه تماثل داخلي،
+
+266
+00:22:31,600 --> 00:22:37,860
+لو أنتم بتتأملوا فيه بعمق شوية، بتحسوا أنه اللي
+
+267
+00:22:37,860 --> 00:22:44,250
+خلاه يصير نفس المركب، وأقدر أفهمه أنه أنا لو أنا
+
+268
+00:22:44,250 --> 00:22:48,650
+اتخيلت مرآة في نص المركب، هذا النص اللي فوق صورة
+
+269
+00:22:48,650 --> 00:22:52,770
+النص اللي تحت في المرآة ولا لأ؟ طلعوا معاكم هي الـCl
+
+270
+00:22:52,770 --> 00:23:00,790
+قابلها Cl، الـH، H، مثل مثل. إذا one half of the
+
+271
+00:23:00,790 --> 00:23:04,170
+molecule is the mirror image of the other half ولا
+
+272
+00:23:04,170 --> 00:23:10,660
+لأ؟ هذا النص هو صورة هذا النص في المرآة، واضح الكلام؟
+
+273
+00:23:10,660 --> 00:23:14,420
+زي الناس اللي بتطلعوا على كروت الشدة، إذا عمركم
+
+274
+00:23:14,420 --> 00:23:18,780
+شفتوها بتشوفوا الرسومات اللي فيها الإنسان هيك أو
+
+275
+00:23:18,780 --> 00:23:24,620
+بصورة هيك، بعدين هذا
+
+276
+00:23:24,620 --> 00:23:29,540
+زيه بالظبط .. هذا زيه بالظبط، أنه النص هذا .. صورة
+
+277
+00:23:29,540 --> 00:23:37,180
+النص هذا في المرآة، واضح؟ الآن هذا المركب كأنه حقيقة
+
+278
+00:23:37,180 --> 00:23:42,380
+يحتوي على مركبين، كأنه هذا مركب بإمكانكم تتخيلوه، و
+
+279
+00:23:42,380 --> 00:23:47,540
+هذا مركب ثاني، وهي هم بس متصلين في بعض، ومن البعض
+
+280
+00:23:47,540 --> 00:23:52,760
+لو أجيت بدأت أفكر بعمق شوية، هذا لو إنه حطيناه لوحده
+
+281
+00:23:52,760 --> 00:23:59,810
+في المرآة بيطلع كائنه وله rotation، وهذا لو حطّيته
+
+282
+00:23:59,810 --> 00:24:04,450
+لوحده في المرآة، كائنه له rotation. طيب لو أخدت
+
+283
+00:24:04,450 --> 00:24:09,530
+مليون جزء من المركب الكلي كده، يكون من هذا النص
+
+284
+00:24:09,530 --> 00:24:15,370
+مليون، ومن هذا النص مليون، والمليونين عكس بعض، صار
+
+285
+00:24:15,370 --> 00:24:21,750
+هذا بنفسه يشبه إيش؟ Racemic mixture اللي أخذناه
+
+286
+00:24:21,750 --> 00:24:25,510
+المرة الماضية لما كنا نقول لكم لو كان عندي خليط
+
+287
+00:24:25,510 --> 00:24:31,050
+متساوي من two isomers، شو سمّيناه؟ Racemic mixture
+
+288
+00:24:31,050 --> 00:24:35,850
+واحد منهم بيلف يمين، الثاني شمال، قديش بيكون
+
+289
+00:24:35,850 --> 00:24:41,240
+بالمجمل الـ rotation له؟ صفر. الـ Racemic mixture
+
+290
+00:24:41,240 --> 00:24:45,460
+بيكون optically active ولا inactive؟ optically
+
+291
+00:24:45,460 --> 00:24:48,880
+inactive. ليش optically inactive؟ لأنه فيه عدد
+
+292
+00:24:48,880 --> 00:24:54,240
+متساوي من الـ enantiomers بيلغوا بعض. الآن هذا تماماً
+
+293
+00:24:54,240 --> 00:24:58,700
+يشبه الـ racemic mixture، كأنه هاي نص وهاي نص، هذول
+
+294
+00:24:58,700 --> 00:25:04,040
+عكس بعض ولا لأ؟ واحد R وواحد S. الجزء الكبير لو
+
+295
+00:25:04,040 --> 00:25:09,210
+منه مليون، كده فيه من هذا؟ ومن هذا؟ إذا هذا
+
+296
+00:25:09,210 --> 00:25:13,330
+racemic mixture كأنه بامتياز، بس موجود في مركب واحد
+
+297
+00:25:13,330 --> 00:25:17,550
+فهذا المركب بالمجمل بيكون optically active ولا
+
+298
+00:25:17,550 --> 00:25:24,070
+inactive؟ هذا المركب العجيب هذا المتماثل اللي موجود الـ
+
+299
+00:25:24,070 --> 00:25:28,390
+configuration فيه لنصه عكس الثاني، اللي نصه صورة
+
+300
+00:25:28,390 --> 00:25:32,270
+بعض، أو صورة نص الثاني في المرآة، أخذ اسم في الـ
+
+301
+00:25:32,270 --> 00:25:36,910
+stereo chemistry، بيسمّيه meso compound أو
+
+302
+00:25:36,910 --> 00:25:42,570
+meso structure. لحظة، الآن لو بدنا نقرأ إيش تعريف الـ
+
+303
+00:25:42,570 --> 00:25:47,170
+meso compound، كل الكلام هذا معرف هنا، كل اللي حكينا
+
+304
+00:25:47,170 --> 00:25:53,050
+الـ meso compound is an achiral diastereomer of the
+
+305
+00:25:53,050 --> 00:25:56,450
+compound. achiral يعني optically inactive، شفنا ليش
+
+306
+00:25:56,450 --> 00:26:02,470
+أنه achiral، وليش أنه optically inactive، رغم أنه فيه
+
+307
+00:26:02,470 --> 00:26:06,750
+مركز استريوجينيك؟ كم مركز استريوجينيك فيه؟ اثنين
+
+308
+00:26:06,750 --> 00:26:11,630
+لكن هو بالمحصلة chiral ولا achiral؟ achiral.
+
+309
+00:26:11,630 --> 00:26:14,190
+optically inactive although it contains
+
+310
+00:26:14,190 --> 00:26:18,030
+stereogenic centers. الآن its stereogenic centers
+
+311
+00:26:18,030 --> 00:26:23,190
+have opposite configurations، يعني لازم واحد R
+
+312
+00:26:23,190 --> 00:26:26,970
+والثاني S. هذا اللي بيكون الـ meso compound، أو نفس
+
+313
+00:26:26,970 --> 00:26:32,470
+المركب one half of the molecule is the mirror image
+
+314
+00:26:32,470 --> 00:26:37,330
+of the other half. اللي في هذه المواصفات بنقول أنه
+
+315
+00:26:37,330 --> 00:26:43,520
+meso compound، بيكون مركب واحد، مش مركبين.
+
+316
+00:26:43,520 --> 00:26:46,160
+optically inactive، يعني لو جينا سألناكم في
+
+317
+00:26:46,160 --> 00:26:49,360
+الامتحان، meso compound is optically active or
+
+318
+00:26:49,360 --> 00:26:55,260
+inactive؟ inactive. الـ meso compound إذا مركب متماثل
+
+319
+00:26:55,260 --> 00:26:58,680
+لما أجي أرسم، عندي 2R,3R، 2S,3S، و
+
+320
+00:26:58,680 --> 00:27:02,880
+2R,3S، أو الثانية من اللي فيهم بتكون meso؟
+
+321
+00:27:02,880 --> 00:27:09,000
+اللي فيها هذول عكس بعض، يعني اللي بتكون RR أو SS، كل
+
+322
+00:27:09,000 --> 00:27:13,630
+واحدة منهم فردها individually، يعني هذه لو أخذتها لحالها
+
+323
+00:27:13,630 --> 00:27:19,130
+optically active. لو
+
+324
+00:27:19,130 --> 00:27:23,650
+عملت خليط متساوي من هذول الاثنين بيصير عندك racemic
+
+325
+00:27:24,520 --> 00:27:28,120
+mixture، بيصير optically inactive. لو أخدت من واحدة
+
+326
+00:27:28,120 --> 00:27:33,360
+أكثر من الثانية زي ما تعلمنا، بيصير الناتج نتاج
+
+327
+00:27:33,360 --> 00:27:38,600
+الاثنين. لكن هذا المركب، هذا المركب اللي بيميزه أنه
+
+328
+00:27:38,600 --> 00:27:43,100
+واحدة منه R والثانية S. إذا أنا لما بتعرف الـ meso
+
+329
+00:27:43,100 --> 00:27:47,380
+compound في المركب المتماثل اللي بيكون منه واحدة R
+
+330
+00:27:47,380 --> 00:27:53,360
+والثانية S، هذا الـ meso compound، والمجموع بيطلع
+
+331
+00:27:54,340 --> 00:27:59,240
+ثلاثة مركبات في النهاية. الآن لو أتيت سألت، طيب يا
+
+332
+00:27:59,240 --> 00:28:02,700
+دكتور، قولنا احنا أكيد بين هذا وهذا العلاقة they
+
+333
+00:28:02,700 --> 00:28:06,720
+are enantiomers. طب لو أي واحد من هذول الـ
+
+334
+00:28:06,720 --> 00:28:11,520
+enantiomers قرنته بالـ meso compound، اه طلعوا two
+
+335
+00:28:11,520 --> 00:28:18,320
+are نفس الشيء، هذول واضح نفس الشيء، وthree are
+
+336
+00:28:18,320 --> 00:28:24,870
+diastereomers عكس بعض، شيء نفسه، شيء عكسه. فين VR؟ ده
+
+337
+00:28:24,870 --> 00:28:30,950
+diastereomer. فين VR؟ ده diastereomer، بيتعلق بـليه؟
+
+338
+00:28:30,950 --> 00:28:35,490
+بيكفي على موضوع الـ two chiral centers. الآن في
+
+339
+00:28:35,490 --> 00:28:41,850
+عندكم مجموعة من الأسئلة، كيف توجدوا العلاقة بين
+
+340
+00:28:41,850 --> 00:28:47,080
+المركبين حتى لو رسمناهم بطرق مختلفة. لاحظوا هذه
+
+341
+00:28:47,080 --> 00:28:50,980
+المركبات مرسومة بطرق مختلفة تماماً، مرة الـH فوق
+
+342
+00:28:50,980 --> 00:28:54,820
+ومرة الـH على الجانب، لكنهم نفس المركب بالمناسبة
+
+343
+00:28:54,820 --> 00:29:00,060
+يعني من ناحية structure أو روابط، يعني الكربون
+
+344
+00:29:00,060 --> 00:29:04,280
+الأولى، حملة Br وCl، وبعدين CH3، وهاي الكربون
+
+345
+00:29:04,280 --> 00:29:07,680
+اللي هو حملة Br وCl وبعدين CH3. يعني لو هذا وهذا
+
+346
+00:29:07,680 --> 00:29:13,090
+كنت أبدأ أسمّيهم 1-bromo-1-chloro-ethane. مرة
+
+347
+00:29:13,090 --> 00:29:18,290
+ثانية، هاي carbon واحد، هاي اثنين، شو حتسمّوه؟ 1-
+
+348
+00:29:18,290 --> 00:29:25,500
+bromo-1-chloro-ethane.  هذول الاثنين اللي
+
+349
+00:29:25,500 --> 00:29:29,680
+مرسومين، بيدي العلاقة بينهم، مش مرسومين بطريقة اللي
+
+350
+00:29:29,680 --> 00:29:33,180
+بالعين المجردة أشوف أنهم بينهم مرسومين زي بعض أو
+
+351
+00:29:33,180 --> 00:29:37,000
+كل واحدة عكس الثانية، مرسومين بطرق مختلفة. إذا على
+
+352
+00:29:37,000 --> 00:29:42,200
+طول ما ليش حل إلا أحدد الـ configuration، أحددهم بضوء
+
+353
+00:29:42,200 --> 00:29:46,880
+هذا، طلع R وهذا R، then they are the same compound.
+
+354
+00:29:46,880 --> 00:29:53,920
+واضح؟ الآن جيبنا لكم مركبين ثانيين، لكم carbon هذا لو
+
+355
+00:29:53,920 --> 00:29:59,540
+بدكم تسمّوه؟ المركب هذا، أطول سلسلة فيه قديش؟ أربعة
+
+356
+00:29:59,540 --> 00:30:09,160
+واحد اثنين، أعلم على أطول سلسلة CH3CHCHCH3
+
+357
+00:30:09,160 --> 00:30:17,440
+إذا هذا المركب اللي عندي بيوتين، شو بيحمل؟ بيوتين؟ عـ
+
+358
+00:30:17,440 --> 00:30:21,920
+نمرة 2 بروم، عـ نمرة 3 كلور. ترقيم واحد عندي عشان
+
+359
+00:30:21,920 --> 00:30:26,340
+أخلي البروم أقل ما يمكن. 2-بروم-3-كلورو بيوتان
+
+360
+00:30:26,340 --> 00:30:27,620
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+361
+00:30:27,620 --> 00:30:29,600
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+362
+00:30:29,600 --> 00:30:36,300
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+363
+00:30:36,300 --> 00:30:44,220
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+364
+00:30:44,220 --> 00:30:50,050
+ثلاثة. أحدد R وS لما أعملهم بهدوء، بتعملهم في
+
+365
+00:30:50,050 --> 00:30:56,550
+البيت. هنا 2S, و2R. الاثنين عكس بعض، 3S,
+
+366
+00:30:56,550 --> 00:31:01,850
+و3R. the same, then they are diastereomers.
+
+367
+00:31:01,850 --> 00:31:05,730
+كذلك
+
+368
+00:31:05,730 --> 00:31:11,930
+الحال، هذا المركب، هي أطول سلسلة فيه، نطلع عليها واحد
+
+369
+00:31:11,930 --> 00:31:15,810
+اثنين ثلاثة أربعة. عـ اثنين بروم، وعـ ثلاثة كلور، وهذه
+
+370
+00:31:15,810 --> 00:31:20,350
+أطول السلسلة واحد اثنين ثلاثة أربعة. عـ اثنين بروم، وعـ
+
+371
+00:31:20,350 --> 00:31:28,710
+ثلاثة كلور. نحدد له R وS، 2S, 2R, 3S, 3
+
+372
+00:31:28,710 --> 00:31:37,170
+R. الترقيم من هناك، كل شيء عكس بعض. they are diastereomers.
+
+373
+00:31:37,170 --> 00:31:41,670
+اللي بعده نفس الشيء لو عملته بهدوء، the same
+
+374
+00:31:41,670 --> 00:31:46,270
+compound، واضح؟ the same compound. طبعاً أنتم بدكم
+
+375
+00:31:46,270 --> 00:31:51,970
+تحذروا بس بحالة واحدة، لما يكون المركب متماثل، و
+
+376
+00:31:51,970 --> 00:31:57,010
+يطلع عندكم 2R,3S، والتالية 2S,3R، بدكم ترجعوا
+
+377
+00:31:57,010 --> 00:32:00,770
+تفكروا بالإيش؟ بالـ meso compound اللي هو the same
+
+378
+00:32:00,770 --> 00:32:04,910
+compound. لو كان المركب متماثل، المثال هذا اللي
+
+379
+00:32:04,910 --> 00:32:09,350
+قدامكم مش متماثل، لأنه على جهة بروم وعلى جهة كلور.
+
+380
+00:32:09,350 --> 00:32:15,150
+دائماً التفكير وين بده يكون؟ قف وأفكر لما يكون فيه
+
+381
+00:32:15,150 --> 00:32:19,490
+تماثل داخلي. إذا في تماثل داخلي وطلع عندكم الـ
+
+382
+00:32:19,490 --> 00:32:26,150
+configurations في المتماثل، إذا طلع عندكم R وS، و
+
+383
+00:32:26,150 --> 00:32:31,390
+قبالها S وR، they are the same compound. هذا الحكي
+
+384
+00:32:31,390 --> 00:32:37,610
+وين بيكون؟ في المركبات المتماثلة، بيكون المركب فعلاً
+
+385
+00:32:37,610 --> 00:32:44,630
+meso. لما أحكي عن مركبين R,S وS,R، طلعوا معاكم
+
+386
+00:32:44,630 --> 00:32:51,270
+إذا مركب فيه تماثل داخلي، بنقول عنهم they are the
+
+387
+00:32:51,270 --> 00:32:56,130
+same compound، أو بنقول this is a meso
+
+445
+00:37:55,590 --> 00:38:00,410
+بترتفع في ذرة هيدروجين بيصيروا هدولة التلاتة
+
+446
+00:38:00,410 --> 00:38:06,520
+بلانر في مستوى واحد يعني لو أنا بدي أجِي أتخيلّها
+
+447
+00:38:06,520 --> 00:38:10,780
+تمّ التفاعل على الجهتين؟ لما تمّ التفاعل على
+
+448
+00:38:10,780 --> 00:38:18,200
+الجهتين؟ ممكن إيه بسرعة أريكُم باستعمال الـ models و
+
+449
+00:38:18,200 --> 00:38:27,360
+بأمل أنَّها الـ models بتخدمنا، تخيّلوا
+
+450
+00:38:27,360 --> 00:38:33,500
+معنا لو تخيّلنا أنَّ في عندنا CH3، الـ CH3 نتخيّلها ذرّة
+
+451
+00:38:33,500 --> 00:38:39,550
+كربون صمراء CH3، تمام؟ لما أشيل H بيبقى عندي كام
+
+452
+00:38:39,550 --> 00:38:44,650
+هيدروجين؟ واحدة، وإيش بيبقى عندي؟ مجموعة الـ methyl
+
+453
+00:38:44,650 --> 00:38:48,770
+لسه ما جبتش الـ chlorine، أنا بدي بهذه كيف بعمل
+
+454
+00:38:48,770 --> 00:38:52,830
+الإبدال؟ بشيل الهيدروجينة في الأول، وبعدين بحطّ
+
+455
+00:38:52,830 --> 00:38:57,250
+بدالها chlorine، فدولة كام رابطة حوالين الكربون؟
+
+456
+00:38:57,250 --> 00:38:58,910
+أربعة أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+457
+00:38:58,910 --> 00:38:59,790
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+458
+00:38:59,790 --> 00:39:06,750
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة
+
+459
+00:39:07,360 --> 00:39:13,760
+بمشي الحال، هاي هذا صار بهذا الشكل بالظبط، طلعوا في
+
+460
+00:39:13,760 --> 00:39:20,740
+مجموعة methyl و H و methyl و الـ H الأخيرة شيلناها
+
+461
+00:39:20,740 --> 00:39:24,240
+رفعناها، الآن بدنا نجيب الـ chlorine تتفاعل
+
+462
+00:39:26,450 --> 00:39:29,650
+هذه الـ Intermediate للحظة، رفعت الـ H الأولى
+
+463
+00:39:29,650 --> 00:39:33,330
+بلانر في مستوى واحد، الكلور بإمكانها تيجي تهاجم
+
+464
+00:39:33,330 --> 00:39:37,470
+عليها من هنا، وهدول بتعجوا حلو، من فوق أو من هنا
+
+465
+00:39:37,470 --> 00:39:43,910
+طالما أنَّها بلانر، في فرق أنَّ الكلور هي جاية من بعيد
+
+466
+00:39:43,910 --> 00:39:49,130
+بيفرق عندها أنَّها تمشي من هنا أو من هنا، اطلع معي
+
+467
+00:39:49,130 --> 00:39:52,670
+شايفين هدول الممرات اللي في القاعة؟ لو أنا بدي أروح
+
+468
+00:39:52,670 --> 00:39:59,700
+لآخر نقطة، بإمكاني أمشي من هنا ومن هنا بشكل متساوي
+
+469
+00:39:59,700 --> 00:40:04,520
+ولا لأ؟ ما عندي مشكلة، بدي أروح لآخر نقطة وهي عندي
+
+470
+00:40:04,520 --> 00:40:08,240
+مسارين متكافئين، كذلك الحال، هذا planar، بدي تيجي
+
+471
+00:40:08,240 --> 00:40:12,200
+الـ chlorine من برا تتفاعل عليه، ترد تعمل المجموعة
+
+472
+00:40:12,200 --> 00:40:16,180
+الرابعة، إذا أتيت من هنا عملت enantiomer، وإذا أتيت من
+
+473
+00:40:16,180 --> 00:40:20,660
+هنا عملت الثاني، الآن من ناحية الاحتمالات متساوية
+
+474
+00:40:20,660 --> 00:40:25,440
+تماماً، ولذلك يظهر عندي racemic mixture، يعني يظهر
+
+475
+00:40:25,440 --> 00:40:30,220
+الاثنين ويظهُران بنسب متساوية، يظهر الاثنين و
+
+476
+00:40:30,220 --> 00:40:34,100
+يظهُران بنسب متساوية، فبيصير المحصلة أنَّ الـ generation
+
+477
+00:40:34,100 --> 00:40:42,710
+of a chiral center produces racemic mixture، واضح؟ الـ
+
+478
+00:40:42,710 --> 00:40:46,690
+generation of a chiral center produces a racemic
+
+479
+00:40:46,690 --> 00:40:53,110
+mixture، الآن لو قلنا بدل racemic mixture، equal
+
+480
+00:40:53,110 --> 00:40:59,740
+number of enantiomers، أكيد صح.. أكيد صح، generation
+
+481
+00:40:59,740 --> 00:41:02,520
+of a chiral center produces racemic mixtures
+
+482
+00:41:02,520 --> 00:41:10,660
+لاحظوا هذه الجملة، بالنسبة للكيمياء، ما بين الكيمياء
+
+483
+00:41:10,660 --> 00:41:15,480
+اللي بيصنعوها البشر وما بين خلق الله سبحانه
+
+484
+00:41:15,480 --> 00:41:21,070
+وتعالى، بتعمل فرق كبير جداً، اليوم لما أنا بأجي في
+
+485
+00:41:21,070 --> 00:41:26,450
+المختبر بدي أحضر مركب وأعمل chiral center، أنا
+
+486
+00:41:26,450 --> 00:41:31,290
+ما بَتحكمش في الاحتمالات، بيطلع عندي خليط متساوي، و
+
+487
+00:41:31,290 --> 00:41:36,090
+بعدين أتعب وأفصله، وهذا السبب ربما في أنَّه في دواء
+
+488
+00:41:36,090 --> 00:41:41,360
+مثل الثاليدومايد كان بيطلع الخليط المتساوي الـ R والـ
+
+489
+00:41:41,360 --> 00:41:45,860
+الـ S، منهم واحد مفيد وواحد ضار، وعمل مشاكل كتير
+
+490
+00:41:45,860 --> 00:41:50,160
+كل ما بشغل في المختبر، المختبر بيطلع لي خليط من
+
+491
+00:41:50,160 --> 00:41:52,940
+المركّبين، إذا مش عندي chiral center أنا بدي أعمله
+
+492
+00:41:52,940 --> 00:41:57,460
+بيطلع لي.. بيطلع لي إيش؟ racemic mixture، الآن في
+
+493
+00:41:57,460 --> 00:42:02,570
+الطبيعة فيه إنزيمات، الإنزيمات كأنها بتأخذ بإيدي
+
+494
+00:42:02,570 --> 00:42:05,850
+المجموعة اللي جاية بالظبط بداخلها من جهة واحدة
+
+495
+00:42:05,850 --> 00:42:10,030
+ولذلك المنتجات الطبيعية بيطلع منها بس one in a
+
+496
+00:42:10,030 --> 00:42:16,750
+number، هذا خلقه، هذا خلق الله، يعني أنا لما شغلة بكون
+
+497
+00:42:16,750 --> 00:42:21,210
+بتحضّرها الإنزيمات وبتتّحضّر جوا الجسم بتلاقوا بيطلع
+
+498
+00:42:21,210 --> 00:42:26,330
+منها بس واحد، لما آجي أنا أعيد التفاعل بالمختبر، و
+
+499
+00:42:26,330 --> 00:42:30,110
+بدون إنزيمات وبكذا بيطلع عندي خليط متساوي من
+
+500
+00:42:30,110 --> 00:42:34,830
+الاثنين، ولذلك اللي بده مركبات نقية، يعني بده one in
+
+501
+00:42:34,830 --> 00:42:39,750
+one enantiomer، إيش أسهل طريقة يعملها؟ ياخذها من مصادرها
+
+502
+00:42:39,750 --> 00:42:44,590
+الطبيعية إذا كانت تُحضّر في الطبيعة، طبعاً إذا كانت لا
+
+503
+00:42:44,590 --> 00:42:51,850
+تُحضّر في الطبيعة، بده يجعب هذه المشكلة ويطلع عنده
+
+504
+00:42:51,850 --> 00:42:56,450
+خليط من الاثنين، عشان إيه كده في الكيمياء بيسموه إيش؟
+
+505
+00:42:56,450 --> 00:43:02,990
+Symmetric Synthesis، Symmetric Synthesis، إيش معنى
+
+506
+00:43:02,990 --> 00:43:08,350
+Symmetric؟ أنّه بيطلع خليط متماثل من الاثنين، جنب بعض، و
+
+507
+00:43:08,350 --> 00:43:15,290
+بعدين يقعد إيش؟ يعمِل يُفصل فيهم، الآن بدأوا من جديد
+
+508
+00:43:15,290 --> 00:43:21,030
+يستعملوا طرق حديثة في الـ synthesis ويضيفوا عوامل
+
+509
+00:43:21,030 --> 00:43:25,330
+حفّازة اللي تخلي واحد من هدول يطلع بنسبة أكثر من
+
+510
+00:43:25,330 --> 00:43:30,490
+الثانية، أو يكاد يكون يطلع نقيّ، وجدته، إذا طلعوا مش
+
+511
+00:43:30,490 --> 00:43:35,790
+متساويات، شو بدي اسم الـ synthesis؟ Asymmetric
+
+512
+00:43:35,790 --> 00:43:40,010
+synthesis، واضح؟ يعني الـ symmetric synthesis بتطلع
+
+513
+00:43:40,010 --> 00:43:44,810
+الخليط متساوي، الآن إذا صرت أضيف عوامل حفّازة بطرق
+
+514
+00:43:44,810 --> 00:43:49,290
+معينة، بتحذيرات، بصير أشتغل إيش؟ asymmetric
+
+515
+00:43:49,290 --> 00:43:52,910
+synthesis، اليوم اللي منكم بده يدرس كيمياء وبعدين
+
+516
+00:43:52,910 --> 00:43:57,120
+يقول أنا بدي آخذ جائزة نوبل في الكيمياء، Bye Bye
+
+517
+00:43:57,120 --> 00:44:01,260
+Asymmetric Synthesis، بده يشتغل على إيش؟ Asymmetric
+
+518
+00:44:01,260 --> 00:44:05,420
+Synthesis، تصير تتعلم كتير، تضيف عوامل حفّازة
+
+519
+00:44:05,420 --> 00:44:12,040
+بمواصفات معينة، تخلي التفاعل يطلع واحد ما يطلعش
+
+520
+00:44:12,040 --> 00:44:16,200
+الثاني، أو يطلع واحد مثلاً بنسبة 90% والثاني بنسبة
+
+521
+00:44:16,200 --> 00:44:20,800
+10% على سبيل المثال، وكل ما زادت، يطلع واحد تماماً و
+
+522
+00:44:20,800 --> 00:44:26,500
+تلغي الثاني، كل ما كانت تمثل إيش؟ نجاح كبير في الشغل
+
+523
+00:44:26,500 --> 00:44:31,720
+افهمنا، إذا المشكلة ما بين الطبيعة وما بين المختبر
+
+524
+00:44:31,720 --> 00:44:36,380
+المختبر هو وضع طبيعي بيطلع لي خليط، الطبيعة بوضعها
+
+525
+00:44:36,380 --> 00:44:42,120
+الطبيعي بيطلع واحد، الآن العالم بيسعوا نحو إيش؟ أن
+
+526
+00:44:42,120 --> 00:44:45,960
+يقتربوا من الطبيعة، أنهم يقدروا يطلعوا واحد ولو
+
+527
+00:44:45,960 --> 00:44:51,120
+بنسبة كبيرة، في ما يُسمى بالعلم إيش؟ asymmetric
+
+528
+00:44:51,120 --> 00:44:55,620
+synthesis، بس بالتأكيد هذا الموضوع كتير متطور
+
+529
+00:44:55,620 --> 00:44:59,860
+بالنسبة لطالب organic، يعني ما لم تتخصصوا كيمياء مش
+
+530
+00:44:59,860 --> 00:45:02,460
+هتشتغلوا فيه، بنكمل إن شاء الله في المرّات القادمة.
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/1TcAfdTqDds_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/1TcAfdTqDds_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..4753652e2218d0884eeb33c0ae73abc7219b9989
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/1TcAfdTqDds_postprocess.srt
@@ -0,0 +1,2120 @@
+1
+00:00:20,690 --> 00:00:24,750
+بسم الله الرحمن الرحيم في موضوع ال stereochemistry
+
+2
+00:00:24,750 --> 00:00:29,730
+ربما المرة الماضية نوّهنا من خلال أنفلة تطبيقية من
+
+3
+00:00:29,730 --> 00:00:36,970
+خلال أهمية فهم ال stereo isomers في الحياة العملية
+
+4
+00:00:36,970 --> 00:00:42,990
+أن هذا موضوع مهم ولذلك شوية بنظل نتوسع فيه بعد ما
+
+5
+00:00:42,990 --> 00:00:46,830
+أخدنا المركبات اللي فيها one chiral center قولنا
+
+6
+00:00:46,830 --> 00:00:51,610
+ال one chiral center بيعتق فقطtwo isomers بعد ذلك
+
+7
+00:00:51,610 --> 00:00:56,690
+إذا زاد العدد بيبدأوا يزيدوا ال isomers طبعا بيحكم
+
+8
+00:00:56,690 --> 00:01:00,890
+الأمر المعادلة two to the n لكن ال two to the n
+
+9
+00:01:00,890 --> 00:01:05,230
+هذا أقصى عدد ممكن من ال isomers في كل الأحوال ممكن
+
+10
+00:01:05,230 --> 00:01:10,290
+يكون العدد أقل من هيك وقلنا هنعطي مثال على العدد
+
+11
+00:01:10,290 --> 00:01:15,330
+الأقصى ومثال على وانتش العدد بيصير أقل في حالة ما
+
+12
+00:01:15,330 --> 00:01:20,620
+عندنا two chiral centersبدأنا في مثال كنا عادة
+
+13
+00:01:20,620 --> 00:01:25,140
+ناخده على أنه مثال بسيط يعني الفكره مركب واحد لما
+
+14
+00:01:25,140 --> 00:01:29,620
+نيجي نقول two three dichloro بنتين بالفكره مركب
+
+15
+00:01:29,620 --> 00:01:33,640
+واحد لكن لما بنيجي نتطلع على موقع اتنين وعلى موقع
+
+16
+00:01:33,640 --> 00:01:39,410
+تلاتةبنلاحظ ان الاتنين they are chiral centers
+
+17
+00:01:39,410 --> 00:01:42,750
+وبناء على ذلك بنبدأ نتوقع انه كام مركبة بيصير
+
+18
+00:01:42,750 --> 00:01:48,890
+عندنا اربع مركبات جربنا نرسمهم من خلال انه نتخيل
+
+19
+00:01:48,890 --> 00:01:52,010
+مثلا بدنا ناخد السلسلة الكربونية بهذا الشكل يعني
+
+20
+00:01:52,010 --> 00:01:56,970
+الخمس كربونات واحد اتنين تلاتة و الاثلاربعة خمسة
+
+21
+00:01:56,970 --> 00:02:01,390
+CH2 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+22
+00:02:01,390 --> 00:02:06,770
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+23
+00:02:06,770 --> 00:02:08,170
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+24
+00:02:08,170 --> 00:02:08,950
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+25
+00:02:08,950 --> 00:02:09,750
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+26
+00:02:09,750 --> 00:02:10,270
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+27
+00:02:10,270 --> 00:02:11,790
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+28
+00:02:11,790 --> 00:02:13,190
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+29
+00:02:13,190 --> 00:02:23,190
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+30
+00:02:23,190 --> 00:02:27,670
+CH3 CHيعني ال R عكسة S ال R عكسة S كلام منطقي الان
+
+31
+00:02:27,670 --> 00:02:32,110
+لو جينا نطلع على المركب الثاني two R three S هذا
+
+32
+00:02:32,110 --> 00:02:37,870
+عكسه ال R اقبلها S ال S اقبلها R لأنه دائما صورة
+
+33
+00:02:37,870 --> 00:02:43,590
+بعض في المرأة بتعني التعاكس التام فلو احنا سألنا
+
+34
+00:02:43,590 --> 00:02:48,170
+ايش العلاقة بين واحد و اتنين they are enantiomersو
+
+35
+00:02:48,170 --> 00:02:52,290
+بيصير مفهوم عندنا ان اي مركبة لما نقول عنهم in
+
+36
+00:02:52,290 --> 00:02:58,650
+anchors بدتكون اشاراتهم عكس بعض الان طبعا انتوا
+
+37
+00:02:58,650 --> 00:03:02,390
+بالنظر بتقولوا صورة بعض في المرأة غير متطابقة لكن
+
+38
+00:03:02,390 --> 00:03:08,390
+ماتنسوش شغلة ان انا بإمكاني ارسم
+
+39
+00:03:09,150 --> 00:03:13,850
+المُركّب بطرق مختلفة بحيث أنه انتوا بمجرد النظر
+
+40
+00:03:13,850 --> 00:03:18,430
+البسيط ما تقدروش تتاخدوا قرار من النظر وجهة القرار
+
+41
+00:03:18,430 --> 00:03:21,750
+الأكيد بتقدروا تتاخدوا من إيش في علاقة بين
+
+42
+00:03:21,750 --> 00:03:29,110
+المُركّبين من قيم A و S خليني أؤكد الفكرة هذه لو
+
+43
+00:03:29,110 --> 00:03:34,310
+فقط أنا بدي أشغل معكم على مُركّب في one chiral
+
+44
+00:03:34,310 --> 00:03:40,470
+centerلو رسمت منه شكلين شو الاحتمالات المتوقعين
+
+45
+00:03:40,470 --> 00:03:43,610
+لما يكون عندي one chiral center؟ يا بده يكون
+
+46
+00:03:43,610 --> 00:03:48,910
+المركب نفسه رسمه بطريقتين مختلفة يا بده يكون in
+
+47
+00:03:48,910 --> 00:03:51,410
+anchormers ماعندي احتمال تاني
+
+48
+00:03:53,870 --> 00:04:01,450
+أخذ بسرعة عشوائيا هاي مركّب CH3CLPR وهي مركّب كتبت
+
+49
+00:04:01,450 --> 00:04:08,010
+هنا ال PR وهنا ال H وهنا ال CL وهنا ال CH3 لاحظوا
+
+50
+00:04:08,010 --> 00:04:12,610
+هدول المركّبين لو سألتكم ما العلاقة بينهما اللي
+
+51
+00:04:12,610 --> 00:04:16,030
+بده تيجي تتطلع تشوف أي شيء بالنظر و المرايا و
+
+52
+00:04:16,030 --> 00:04:22,100
+بنطبقه و مابنطبقوش حتىمش هتقدر، لأنه أنا أرسمهم
+
+53
+00:04:22,100 --> 00:04:25,640
+بطرق مختلفة، ماحدش بيمنعني أرسمهم بطرق مختلفة،
+
+54
+00:04:25,640 --> 00:04:31,700
+الآن أسهل شيء أن أحدد لكل مركب R أو S، الآن إذا
+
+55
+00:04:31,700 --> 00:04:35,500
+هذا طلع R و هذا R، معنى ذلك نفس المركب مرسوم بطرق
+
+56
+00:04:35,500 --> 00:04:40,800
+مختلفة، S و S نفس المركبإذا هذا R و هذا S, they
+
+57
+00:04:40,800 --> 00:04:44,140
+are enantiomers إذا هذا S و هذا R, they are
+
+58
+00:04:44,140 --> 00:04:48,260
+enantiomers هيكا بيكون أسهل طريقة أن أعملهم ولذلك
+
+59
+00:04:48,260 --> 00:04:54,380
+لو بدي أجي أطلع لهذا أقل مجموع ال H ب RCLCH3 من
+
+60
+00:04:54,380 --> 00:05:00,660
+بين R S لأن هذا ال H للأمام الآن لو بدي أطلع
+
+61
+00:05:00,660 --> 00:05:12,780
+المركب الثاني ب R CL SCH3 بين R مرة تانية وبنخليها
+
+62
+00:05:12,780 --> 00:05:18,100
+R لأن ال H للخلف هدول الانشو مارس طالما واحد قسي
+
+63
+00:05:18,100 --> 00:05:21,380
+التاني R إذا we are in ancho mars فالانشو مارس
+
+64
+00:05:21,380 --> 00:05:25,040
+دايما عكس بعض الان لو عندكوا خمسة كايرة ال centers
+
+65
+00:05:25,040 --> 00:05:29,520
+مش واحدإيش بتكون في الخمسة يكونوا عشان يكونوا
+
+66
+00:05:29,520 --> 00:05:35,300
+مركبين انانشومارز؟ كل واحد عكس التاني زي أنا باجف
+
+67
+00:05:35,300 --> 00:05:38,420
+قدام المرايا، الإيدين عكس بعض، الوش عكس بعض، البطن
+
+68
+00:05:38,420 --> 00:05:42,060
+عكس بعض، الرجلين عكس بعض، كل شيء بيكون عكس التاني،
+
+69
+00:05:42,060 --> 00:05:45,120
+يعني لو عندي ان شاء الله عشرين Cairo Center في
+
+70
+00:05:45,120 --> 00:05:49,600
+مركب، الانانشومارز تبعه، العشرين المقابلات بيكونوا
+
+71
+00:05:49,600 --> 00:05:56,300
+عكسهم، لو واحدة منهم اختلتببطلوا in anchormers على
+
+72
+00:05:56,300 --> 00:05:59,840
+طول ببطلوا صورة بعض في المرآة إذا بطلوا صورة بعض
+
+73
+00:05:59,840 --> 00:06:04,700
+في المرآة، شو بدوا يصيروا؟ ديستيريومارز، تنسوش إن
+
+74
+00:06:04,700 --> 00:06:08,740
+احنا عرفنا الديستيريومارز، they are non-mirror
+
+75
+00:06:08,740 --> 00:06:12,580
+image in anchormers ولذلك لو أنا سألت العلاقة بين
+
+76
+00:06:12,580 --> 00:06:20,780
+هدول، خلّينا نوضحها باسم RS عكس بعضعكس بعض اذا
+
+77
+00:06:20,780 --> 00:06:24,580
+they are enansimals واضح؟ الان لو سئلت هدول
+
+78
+00:06:24,580 --> 00:06:33,560
+الاتنين RS SR عكس طلع عليهم R اقبلها S S اقبلها R
+
+79
+00:06:33,560 --> 00:06:39,320
+عكس بعض they are enansimals الان لو اجيت اخدت مثلا
+
+80
+00:06:39,320 --> 00:06:49,160
+المركب واحد مع تلاتة اتطلعوا R وRهدولا متل بعض و
+
+81
+00:06:49,160 --> 00:06:56,860
+are و us عكس بعض هل هدولا عكس بعض بالكامل؟ لأ
+
+82
+00:06:56,860 --> 00:07:01,500
+هدولا متل بعض بالكامل؟ لأ مالو كانوا عكس بعض
+
+83
+00:07:01,500 --> 00:07:04,560
+بالكامل يعني كل نقطة عكس التانية they are
+
+84
+00:07:04,560 --> 00:07:10,000
+enantiomers الان لو كل نقطة زي التانية they are
+
+85
+00:07:10,000 --> 00:07:14,600
+the same compoundلو كل نقطة زي التانية هو نفس
+
+86
+00:07:14,600 --> 00:07:20,760
+المُركّب الـ R إيش زي بعض و إيش عكس بعض بطلوا صورة
+
+87
+00:07:20,760 --> 00:07:24,400
+بعض في المرأة أو بطلوا نفس المُركّب إيش هيصفه؟ ده
+
+88
+00:07:24,400 --> 00:07:28,180
+الـ Stereomers إذا لما بنيجي نتطلع إنه بدنا نفهم
+
+89
+00:07:28,180 --> 00:07:32,260
+العلاقة بين مُركّبين من خلال الرموز هنقول إنه
+
+90
+00:07:32,260 --> 00:07:36,260
+عندنا تلت احتمالات في حالة ما عندي أكتر من chiral
+
+91
+00:07:36,260 --> 00:07:40,600
+center لحظة لما كان عندي one chiral centerبدون ما
+
+92
+00:07:40,600 --> 00:07:44,080
+أعمل R و S بقولكوا عندي احتمالين يا بدهم يكونوا
+
+93
+00:07:44,080 --> 00:07:50,120
+نفس المركب R R S S يا بدهم يكونوا Enansi و Mars S
+
+94
+00:07:50,120 --> 00:07:54,840
+R أو R S الان لو كان عندي more than one chiral
+
+95
+00:07:54,840 --> 00:07:57,960
+center عندي تلت احتمالات الاحتمال الاول بدهم
+
+96
+00:07:57,960 --> 00:08:03,440
+يكونوا Enansi و Mars كل شيء عكس بعض الاحتمال
+
+97
+00:08:03,440 --> 00:08:09,150
+التاني انهم يكونوا نفس المركب كل شيء نفسهزي بعض طب
+
+98
+00:08:09,150 --> 00:08:12,950
+لو طلع شيء عكس و شيء زي بعض وجدت دي R ده يستيريو
+
+99
+00:08:12,950 --> 00:08:18,370
+مارس لحظوا الآن لو اجيت على واحد و تلاتة R و S عكس
+
+100
+00:08:18,370 --> 00:08:23,670
+بعض R و R زي بعض اذا هدولة صورت بعض في المرقاة لأ
+
+101
+00:08:23,670 --> 00:08:28,530
+نفس المركب لأ ر ده يستيريو مارس اذا واحد و تلاتة
+
+102
+00:08:28,530 --> 00:08:31,970
+ده يستيريو مارس لو طبقته مرة تانية على واحد و
+
+103
+00:08:31,970 --> 00:08:39,700
+أربعة مثلا ما العلاقة بينهم Rو S عكس بعض، هم
+
+104
+00:08:39,700 --> 00:08:47,540
+لاحظين؟ R و R نفس بعض، they are diastereomers لو
+
+105
+00:08:47,540 --> 00:08:52,720
+إجينا اتطلعنا على اتنين و تلاتة،
+
+106
+00:08:52,720 --> 00:09:02,010
+لاحظوا؟ S و Rعكس بعض السؤاس زي بعض كذلك الحال لو
+
+107
+00:09:02,010 --> 00:09:08,070
+اتطلعت اتنين اربع السؤاس نفس الاشي السؤاد عكس بعض
+
+108
+00:09:08,070 --> 00:09:13,230
+they are diastereomers واضح؟صار عندى نوع تانى من
+
+109
+00:09:13,230 --> 00:09:17,590
+الدياستيريو مارز جاي من وين جاي من المركبات فيها
+
+110
+00:09:17,590 --> 00:09:20,910
+chiral centers يعني احنا اول ما أخدنا تعريف
+
+111
+00:09:20,910 --> 00:09:25,270
+الدياستيريو مارز قولنا كل شيء مش صورة بعض في
+
+112
+00:09:25,270 --> 00:09:29,500
+المرقاة they are diastereomarsالأمثلة الكيميائية
+
+113
+00:09:29,500 --> 00:09:33,820
+الأولى اللى أخدناها شو هي الـ Cis والـ Trans أو
+
+114
+00:09:33,820 --> 00:09:37,300
+الـ Z والـ E they are diastereomers الآن بيجينا
+
+115
+00:09:37,300 --> 00:09:40,900
+أمثلة تانية لما يكون عندى more than one chiral
+
+116
+00:09:40,900 --> 00:09:45,160
+center هذه الأمثلة بتقول القاتل انه لو كان في عندى
+
+117
+00:09:45,160 --> 00:09:51,530
+مركبين في الإشارات تبعتهممش زي بعض تماما، مش نفس
+
+118
+00:09:51,530 --> 00:09:54,650
+المُركّب، ولا Inansiomers و they are
+
+119
+00:09:54,650 --> 00:10:00,010
+stereoisomers، إيش هيصفهم؟ ديستيريو مارس، واضح؟
+
+120
+00:10:00,010 --> 00:10:05,270
+وبهيك أخدنا إن الديستيريو مارس بكم ما كان، بنشوفهم
+
+121
+00:10:05,270 --> 00:10:11,460
+بالكيميامكالين بال CC trans او ZE و بال chiral
+
+122
+00:10:11,460 --> 00:10:15,680
+compounds او بال stereo chemistry لما يكون عندى
+
+123
+00:10:15,680 --> 00:10:21,440
+اكتر من chiral center بشرط انه ننتبه ل ROS
+
+124
+00:10:21,440 --> 00:10:27,760
+بالطريقة اللى اتكلمنا فيها الان طالما ان هدولةالهم
+
+125
+00:10:27,760 --> 00:10:31,760
+إشارات مختلفة فى كام مركب عندى لتو ثري دايكلورو
+
+126
+00:10:31,760 --> 00:10:36,180
+بنتين أربعة هى رموزهم اللى بدى تروح تشتريهم من
+
+127
+00:10:36,180 --> 00:10:39,800
+السوق هتلاقيهم أربعة مركبات الآن احنا قولنا ممكن
+
+128
+00:10:39,800 --> 00:10:46,760
+يكون العدد أقل ناخد مثالهذا المثال 2,3
+
+129
+00:10:46,760 --> 00:10:51,800
+-dichlorobutane قال ذرة كربون واحدة يعني لو انا
+
+130
+00:10:51,800 --> 00:10:56,080
+رسمت هاي كربون تنتين تلاتة اربعة اذا المركب اللي
+
+131
+00:10:56,080 --> 00:11:02,100
+عندى ايش بيوتين واضح لاحظوا ايش بيفرق يعني كتير
+
+132
+00:11:02,100 --> 00:11:09,120
+لبيوتين عنالبنتين لو انا مجرد ان كتبت كتابة مثل
+
+133
+00:11:09,120 --> 00:11:17,800
+CH3 CHCl CHCl CH3 عارفين شو بيفرق؟ لو انا اتيت بين
+
+134
+00:11:17,800 --> 00:11:20,840
+هدولة الـ chiral centers التنين الكاربونز اللي
+
+135
+00:11:20,840 --> 00:11:26,760
+حاملة كلور و جسمت المركب من النصتطلعوا هنا إيش
+
+136
+00:11:26,760 --> 00:11:33,460
+اللي موجود Carbon حاملة HCl و بعدها CH3 و هنا
+
+137
+00:11:33,460 --> 00:11:39,240
+Carbon حاملة HCl و بعدها CH3 إذا هذا المركب صار
+
+138
+00:11:39,240 --> 00:11:44,460
+مركب متماثل قبل شوية لما كنت .. أو من هنا على هذا
+
+139
+00:11:44,460 --> 00:11:49,800
+الشكل أجسم زي هيك تطلعوا كأعداد ذراتماذا عندكم
+
+140
+00:11:49,800 --> 00:11:54,980
+هنا؟ كاربون حاملة HCl وCH3 وهنا كاربون حاملة HCl
+
+141
+00:11:54,980 --> 00:12:01,860
+وCH3 فعدد الذرات اللي بهذا الاتجاه هو نفسه عدد
+
+142
+00:12:01,860 --> 00:12:05,760
+الذرات اللي بهذا الاتجاه فهذا الكاربون بيحمل نوع
+
+143
+00:12:05,760 --> 00:12:10,380
+من التماثل هذا الكلام في المثال السابق ماكانش لما
+
+144
+00:12:10,380 --> 00:12:16,160
+كنتوا تحطوا خط هنابين ال two chiral centers عدولي
+
+145
+00:12:16,160 --> 00:12:22,780
+كل الذرات اللي هتشومها C وH وCL و CH3 و هنا CH وCL
+
+146
+00:12:22,780 --> 00:12:29,460
+و بعدها CH2 CH3 إذا هل هذا النص زي هذا النص لأ في
+
+147
+00:12:29,460 --> 00:12:34,910
+حالة البيوتينأ لبيوتين في تماثل داخلي بين ال two
+
+148
+00:12:34,910 --> 00:12:39,790
+chiral centers يعني المركب سيماتريك الآن لو إجينا
+
+149
+00:12:39,790 --> 00:12:44,310
+جربنا نرسم ال isomers بنفس الطريقة اللي اتعلمناها
+
+150
+00:12:44,310 --> 00:12:51,270
+سابقا يعني أجي أحط تنتين كلور عكس بعض و صورتهم في
+
+151
+00:12:51,270 --> 00:12:54,810
+المرأة و تنتين كلور على جهة واحدة و صورتهم في
+
+152
+00:12:54,810 --> 00:13:02,210
+المرأة و بعدين أحدد R و Sلاحظوا هذه الرسمة تماما
+
+153
+00:13:02,210 --> 00:13:06,510
+هي نسخ و لصق من الرسمة السابقة بس بدل ما كنا
+
+154
+00:13:06,510 --> 00:13:12,890
+كاتبين هنا اثل كتبنا مثل واضح؟ و لذلك انتوا الان
+
+155
+00:13:12,890 --> 00:13:20,310
+كام مركب بتشوفه؟مازالتوا بتشوفوا أربع مركبات
+
+156
+00:13:20,310 --> 00:13:26,150
+للوهلة الأولى لكن لو نظرنا بعمق لهدولة الأربع
+
+157
+00:13:26,150 --> 00:13:32,130
+مركبات هلاحظ ان هذا 2R3R و هذا 2S3S
+
+158
+00:13:34,300 --> 00:13:40,660
+عكس بعض هتيجوا تستنتجوا انهم انانشومارز فش اننا
+
+159
+00:13:40,660 --> 00:13:45,160
+خلاف الآن لما بتيجوا تطلع على المركبين التانيين
+
+160
+00:13:45,160 --> 00:13:49,140
+وخلونا نقول .. نقولنا الترقيم واحد اتنين تلاتة
+
+161
+00:13:49,140 --> 00:13:55,720
+اربعة واحد اتنين تلاتة اربعة و هيناخد واحدة بس
+
+162
+00:13:55,720 --> 00:14:01,560
+نأكد هي ال CL نمرة واحدوهذه ال carbon الحاملة Cl2
+
+163
+00:14:01,560 --> 00:14:09,860
+و CH3 بين S كتبناها R وهذه لو بدنا نتطلع عليها 1 2
+
+164
+00:14:09,860 --> 00:14:16,300
+Cl بعدين carbon حاملة Cl بعدين CH3 Cl بعدين carbon
+
+165
+00:14:16,300 --> 00:14:21,100
+حاملة Cl بعدين CH3 بين R كتبنا S إذا هيك مظبوطين
+
+166
+00:14:21,100 --> 00:14:25,900
+هدولة two R three Sلو اعملنا المركب التاني لجبانو
+
+167
+00:14:25,900 --> 00:14:30,260
+بين two as three are اي حد هيتطلع بهذا الشكل
+
+168
+00:14:30,260 --> 00:14:33,800
+البصير شو هيقول هدول العلاقة بينهم they are
+
+169
+00:14:33,800 --> 00:14:36,760
+enantiomers الان بنقول لأ they are the same
+
+170
+00:14:36,760 --> 00:14:42,420
+compound هتبدو يصير عندكم مشكلة ليش لأنه هتقولوا
+
+171
+00:14:42,420 --> 00:14:47,540
+انت لسه توت و التصوير شاهد علينا كمان بتقول انه
+
+172
+00:14:47,540 --> 00:14:55,020
+اذا كل شيء عكس بعضهthey are enantiomers هاي مثال و
+
+173
+00:14:55,020 --> 00:14:59,320
+فيها دول عكس بعض لكن أنا قاعد بقول عنهم they are
+
+174
+00:14:59,320 --> 00:15:05,060
+the same compound كيف هذا الكلام بيصير؟ هل يا ترى
+
+175
+00:15:05,060 --> 00:15:09,520
+الإنسان بناقض في الحكي ولا لأ؟ الحقيقة في سبب و
+
+176
+00:15:09,520 --> 00:15:15,240
+الأمر هنابحاجة إلى نظرة شوية متعمقة .. بحاجة إلى
+
+177
+00:15:15,240 --> 00:15:19,380
+نظرة شوية متعمقة بين هدول الصورتين تحديدا لو
+
+178
+00:15:19,380 --> 00:15:23,140
+اتخيلتوا انتوا .. لو اتخيلتوا ان انتوا حاطيتوا
+
+179
+00:15:23,140 --> 00:15:26,660
+دبوس هنا مسيكتوا هذا المركب بعدين لفتوه بهذا الشكل
+
+180
+00:15:26,660 --> 00:15:30,980
+طلعوا معايا مرة تانية كأنه هنا فيه محور و الف
+
+181
+00:15:30,980 --> 00:15:35,640
+المركب بهذا الشكل وين هتيجي هذه ال CH3 وين هتطلع
+
+182
+00:15:35,640 --> 00:15:41,720
+هذه ال CL تنتين وين هييجوا ال Hهيصيروا نفس هذا
+
+183
+00:15:41,720 --> 00:15:48,580
+المُركّب ولا لأ؟ نفس المُركّب واضح؟ بهذا الشكل
+
+184
+00:15:48,580 --> 00:15:54,420
+لفوه هاي الـ CLE جوهان و الـ H3 و الـ CH3 انعكسوا
+
+185
+00:15:54,420 --> 00:16:00,660
+ممكن واحدة تيجي تقولي ما كان لفت اللي قبله خليني
+
+186
+00:16:00,660 --> 00:16:05,680
+أرجع للي قبله اللي قبله ماكانش متمثل يعني لما ألف
+
+187
+00:16:05,680 --> 00:16:12,140
+شو بده ينزل هنا CH3 شو بده يطلع هنا؟صح لما انا هاد
+
+188
+00:16:12,140 --> 00:16:15,140
+و بدى ألف و هيك ال CL's و ال H's بيجوا مكان بعض
+
+189
+00:16:15,140 --> 00:16:19,940
+لكن محل ال Ethel شو بتيجي؟ محل ال Ethel مثل هذه
+
+190
+00:16:20,690 --> 00:16:26,010
+املاحظين يعني هذا لو لفته بينطبق على هذا لأ بينما
+
+191
+00:16:26,010 --> 00:16:30,910
+اللي بعده بينطبق ماسبب الانطباق في الحالة التالية
+
+192
+00:16:30,910 --> 00:16:34,390
+و عدم الانطباق في الحالة الأولى انه هذا في الحالة
+
+193
+00:16:34,390 --> 00:16:39,970
+هذه غير متماثل داخليا يعني هذه CH3 هذه اتل مش هذا
+
+194
+00:16:39,970 --> 00:16:47,410
+النص زي هذا بينما في المركب اللي بعده هذا متماثل
+
+195
+00:16:48,570 --> 00:16:51,090
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+196
+00:16:51,090 --> 00:16:58,750
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+197
+00:16:58,750 --> 00:16:59,530
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+198
+00:16:59,530 --> 00:17:00,070
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+199
+00:17:00,070 --> 00:17:00,090
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+200
+00:17:00,090 --> 00:17:00,210
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+201
+00:17:00,210 --> 00:17:00,910
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+202
+00:17:00,910 --> 00:17:00,950
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+203
+00:17:00,950 --> 00:17:01,730
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+204
+00:17:01,730 --> 00:17:13,310
+مثل مثل
+
+205
+00:17:13,310 --> 00:17:17,470
+مثل مثالـR و الـS اللي مبينين عكس بعض كيف بدنا نحل
+
+206
+00:17:17,470 --> 00:17:23,450
+مشكلتهم لأن احنا قلنا إذا كل شي عكس بعض لازم نصنف
+
+207
+00:17:23,450 --> 00:17:28,970
+المراكبات in anchors طب هي مبينين عكس بعض آه مديش
+
+208
+00:17:28,970 --> 00:17:33,990
+تنسوا شغلة هذا المراكب لو أنا جبته لكم في الامتحان
+
+209
+00:17:33,990 --> 00:17:39,610
+و قلتلكم سموهو إجت واحدة منكم اتطلعت فيه و حطت
+
+210
+00:17:39,610 --> 00:17:46,850
+ترقيم 1234 صار هذا موقع 2 و عملته لجته 2R هذا موقع
+
+211
+00:17:46,850 --> 00:17:53,050
+3 و عملته لجته 3S طيب لو واحدة تانية إجت و قالت
+
+212
+00:17:53,050 --> 00:18:00,930
+خليني أرقم من تحت ما هو متمثل هاي 1234 ع 23 أيضا
+
+213
+00:18:01,530 --> 00:18:06,510
+Echlor, إذا هذا بترقم من كام جهة؟ من الجهتين نفس
+
+214
+00:18:06,510 --> 00:18:11,230
+الشيء هذا بترقم من الجهتين نفس الشيء المركب اللي
+
+215
+00:18:11,230 --> 00:18:16,230
+جابي اللي بقدرش أعمل فيه هذا الكلام بدي أكو أتضالك
+
+216
+00:18:16,230 --> 00:18:22,490
+و أتقرره لو كنت بده أرقم من هنا هذه CH2 CH3 لحظة
+
+217
+00:18:22,490 --> 00:18:28,720
+واحد اتنين هيصيروا ال Echlorتلاتة اربعة واحد اتنين
+
+218
+00:18:28,720 --> 00:18:34,200
+تلاتة اذا هذا كام ترقيم يحتمل واحد فقط واحد اتنين
+
+219
+00:18:34,200 --> 00:18:37,920
+تلاتة عشان ال glory يكونوا اقل ترقيم من هنا واحد
+
+220
+00:18:37,920 --> 00:18:41,140
+اتنين تلاتة اربعة خمسة بيكون اتنين تلاتة من هنا
+
+221
+00:18:41,140 --> 00:18:45,640
+واحد اتنين تلاتة اربعة خمسة بيصير تلاتة اربعة اذا
+
+222
+00:18:45,640 --> 00:18:52,420
+هذا كام ترقيم يحتمليحتمل ترقيم واحد فقط لكن المركب
+
+223
+00:18:52,420 --> 00:18:56,880
+اللي بعده المتماثل لو انا رقمته زي ما انتوا شايفين
+
+224
+00:18:56,880 --> 00:19:06,100
+بالازرق صح و لو انا رقمته بالاحمر صح طيب اللي رقمت
+
+225
+00:19:06,100 --> 00:19:12,660
+بالازرق كتبت المركب 2R3S23Diclorobutane
+
+226
+00:19:12,660 --> 00:19:17,390
+طب و اللي بده ترقم بالاحمر شو هتكتب؟الـ 2 ما احنا
+
+227
+00:19:17,390 --> 00:19:21,950
+عارفين ان هذه R و هذه S بغض النظر عن الترقيم هتكتب
+
+228
+00:19:21,950 --> 00:19:25,270
+2S3R
+
+229
+00:19:25,270 --> 00:19:30,930
+الآن اي جواب اللي بدنا نعتبره صح الجوابين صح هذا
+
+230
+00:19:30,930 --> 00:19:36,610
+إله اسمين هذا إله اسمين لأنه متماثل وعشانك المدرس
+
+231
+00:19:36,610 --> 00:19:40,250
+اللي بده يصلح بيجيبلكوا هذا المركب ويقولكوا اعطوه
+
+232
+00:19:40,250 --> 00:19:45,680
+اسمهذا الجواب يبدو يعتبره صح وهذا الجواب يبدو
+
+233
+00:19:45,680 --> 00:19:49,600
+يعتبره صح لسبب بسيط انه مافيه فارق نهائي بين انكوا
+
+234
+00:19:49,600 --> 00:19:54,280
+ترقموه من هنا او من هنا الان نفس الشيء في المركب
+
+235
+00:19:54,280 --> 00:19:58,900
+التاني لما رقمناه بالازرق واحد اتنين تلاتة اربعة
+
+236
+00:19:58,900 --> 00:20:05,140
+طب لو واحدة عملتله ترقيم تاني بالاحمر ايش هتكتبوه؟
+
+237
+00:20:05,140 --> 00:20:11,040
+two R three S الان اتطلعوا هذا أحد أسماء two S
+
+238
+00:20:11,040 --> 00:20:19,770
+three Rهذا أحد أسمائه 2R3S
+
+239
+00:20:19,770 --> 00:20:28,590
+و هذا 2R3S لأن الجزء ببساطة متماثل لأن هذا الجزء
+
+240
+00:20:28,590 --> 00:20:33,490
+ببساطة متماثل بياخد اسمين و هدول الشكلين بيكونوا
+
+241
+00:20:33,490 --> 00:20:38,710
+مركب واحد مش مركبينواضح؟ مركّب واحد وبتسمى
+
+242
+00:20:38,710 --> 00:20:42,110
+بطريقتين، الآن إذا اتفقنا إن هدولة they are the
+
+243
+00:20:42,110 --> 00:20:46,250
+same compound، بأكتر من طريقة فرجيتكم، اللي بدأ من
+
+244
+00:20:46,250 --> 00:20:49,710
+خلال الإشارات، إنه يلهم نفس الإشارات، أيه؟ يلهم
+
+245
+00:20:49,710 --> 00:20:56,750
+نفس الإشارات ولا لأ؟2R 3S .. 2S 3R .. 2S 3R .. 2S
+
+246
+00:20:56,750 --> 00:21:04,650
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+247
+00:21:04,650 --> 00:21:05,570
+2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R
+
+248
+00:21:05,570 --> 00:21:05,730
+.. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S
+
+249
+00:21:05,730 --> 00:21:05,930
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+250
+00:21:05,930 --> 00:21:06,830
+2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R
+
+251
+00:21:06,830 --> 00:21:14,070
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+252
+00:21:14,070 --> 00:21:21,840
+2S 3R .. 2S 3Rوغيرهم سواء سمته 2R3S او 2S3R هو نفس
+
+253
+00:21:21,840 --> 00:21:26,100
+المركب له اسميننفس المركب له اسمين شو اللي عمله
+
+254
+00:21:26,100 --> 00:21:31,660
+الاسمين التماثل اذا لو انا بجاجي اسأل ببساطة لو
+
+255
+00:21:31,660 --> 00:21:35,480
+واحدة ع طول بده تعرف انه عندها اربع مركبات ولا
+
+256
+00:21:35,480 --> 00:21:40,320
+تلاتة ايش اول ما بده تطلع عليه في الجزء انه هل يا
+
+257
+00:21:40,320 --> 00:21:44,460
+ترى هذا الجزء اللي عنده فيه تماثل ولا لا اذا فيه
+
+258
+00:21:44,460 --> 00:21:49,620
+تماثل ع طول بده تحكي عن كام مركبعن تلاتة مافيش
+
+259
+00:21:49,620 --> 00:21:53,820
+تماثل بده تحكي عن أربع يعني لو مثلا سألكوا هذا
+
+260
+00:21:53,820 --> 00:22:05,280
+السؤال CH3 CHBR CHCL CH3 كام Cairo Center فيه؟هن و
+
+261
+00:22:05,280 --> 00:22:09,200
+هن قبل ما ارسم ايزو مارزو اتعب كام ايزو مارزو
+
+262
+00:22:09,200 --> 00:22:14,480
+تتوقعوا له اربعة عطول اربعة ليش لانه انا لو جسمت
+
+263
+00:22:14,480 --> 00:22:18,260
+بين هدولة two chiral centers هذي الظرات مش هى هذي
+
+264
+00:22:18,260 --> 00:22:25,060
+الظرات هنا عندكم H و CL هنا H .. خلاص انتهى واضح؟
+
+265
+00:22:25,060 --> 00:22:31,600
+و هكذاواضح، الان هذا المركب اللي فيه تماثل داخلي،
+
+266
+00:22:31,600 --> 00:22:37,860
+لو انتوا بتتأملوا فيه بعمق شوية، بتحسوا انه اللي
+
+267
+00:22:37,860 --> 00:22:44,250
+خلّاه يصيرنفس المركب و اقدر الفه انه انا لو اني
+
+268
+00:22:44,250 --> 00:22:48,650
+اتخيلت مرايا في نص المركب هذا النص اللى فوق صورة
+
+269
+00:22:48,650 --> 00:22:52,770
+النص اللى تحت فى المرأة ولا لأ طلعوا معاك هى ال CL
+
+270
+00:22:52,770 --> 00:23:00,790
+اقبالها CL ال H H ال مثل مثل اذا one half of the
+
+271
+00:23:00,790 --> 00:23:04,170
+molecule is the mirror image of the other half ولا
+
+272
+00:23:04,170 --> 00:23:10,660
+لأ هذا النص هو صورة هذا النص فى المرأةواضح الكلام؟
+
+273
+00:23:10,660 --> 00:23:14,420
+زي الناس اللي بتطلعوا على كروت الشدة إذا عمركوا
+
+274
+00:23:14,420 --> 00:23:18,780
+شفتوها بتشوفوا الرسومات اللي فيها البني آدم هيك او
+
+275
+00:23:18,780 --> 00:23:24,620
+بصر هيك بعدين هذا
+
+276
+00:23:24,620 --> 00:23:29,540
+زيه بالظبط .. هذا زيه بالظبط أنه النص هذا .. صورة
+
+277
+00:23:29,540 --> 00:23:37,180
+النص هذا في المرأةواضح؟ الان هذا المركب كأنه حقيقة
+
+278
+00:23:37,180 --> 00:23:42,380
+يحتوي على مركبين كأنه هذا مركب بإمكانكوا تتخيلوه و
+
+279
+00:23:42,380 --> 00:23:47,540
+هذا مركب تاني و هاي هم بس متصلين في بعض و من البعض
+
+280
+00:23:47,540 --> 00:23:52,760
+لو إجيت بديت أفكر بعمق شوية هذا لو إنه حطناه لوحده
+
+281
+00:23:52,760 --> 00:23:59,810
+في المرآة بيطلع كايران و إلهrotation وهذا لو حطيته
+
+282
+00:23:59,810 --> 00:24:04,450
+لوحده في المرأة كايرة له rotation طيب لو أخدت
+
+283
+00:24:04,450 --> 00:24:09,530
+مليون جزء من المركب الكلي كده يكون من هذا النص
+
+284
+00:24:09,530 --> 00:24:15,370
+مليون و من هذا النص مليون و المليونين عكس بعض صار
+
+285
+00:24:15,370 --> 00:24:21,750
+هذا بنفسه يشبه إيش؟Racemic mixture اللى أخدناه
+
+286
+00:24:21,750 --> 00:24:25,510
+المرة الماضية لما كنا نقولكوا لو كان عندى خليط
+
+287
+00:24:25,510 --> 00:24:31,050
+متساوي من two isomers شو سمناه؟ Racemic mixture
+
+288
+00:24:31,050 --> 00:24:35,850
+واحد منهم بيلف يمين التانى اشمال قداش بيكون
+
+289
+00:24:35,850 --> 00:24:41,240
+بالمجمل ال rotation له؟ سفرالـ Racemic mixture
+
+290
+00:24:41,240 --> 00:24:45,460
+بيكون optically active ولا inactive؟ optically
+
+291
+00:24:45,460 --> 00:24:48,880
+inactive ليش optically inactive؟ لأنه فيه عدد
+
+292
+00:24:48,880 --> 00:24:54,240
+متساوي من ال enantiomers بيلغوا بعض الان هذا تماما
+
+293
+00:24:54,240 --> 00:24:58,700
+يشبه الracemic mixture كأنه هاي نص و هاي نص هدول
+
+294
+00:24:58,700 --> 00:25:04,040
+عكس بعض ولا لا؟ واحد R و واحد S الجزء الكبير لو
+
+295
+00:25:04,040 --> 00:25:09,210
+منه مليون كدهش فيه من هذا؟ و من هذا؟أذا هذا
+
+296
+00:25:09,210 --> 00:25:13,330
+racemic mixture كأنه بامتياز بس موجود في مركب واحد
+
+297
+00:25:13,330 --> 00:25:17,550
+فهذا المركب بالمجمل بيكون optically active ولا
+
+298
+00:25:17,550 --> 00:25:24,070
+inactive هالمركب العجيب هذا المتماثل اللي موجود ال
+
+299
+00:25:24,070 --> 00:25:28,390
+configuration فيه لنصه عكس التاني اللي نصه صورة
+
+300
+00:25:28,390 --> 00:25:32,270
+بعض أو صورة نص التاني في المرآة أخد اسم في ال
+
+301
+00:25:32,270 --> 00:25:36,910
+stereo chemistry بيسميه meso compound أو
+
+302
+00:25:36,910 --> 00:25:42,570
+mesostructureلحظة الان لو بدنا نقرأ ايش تعريف ال
+
+303
+00:25:42,570 --> 00:25:47,170
+meso compound كل الكلام هذا معرف هنا كل اللي حكينا
+
+304
+00:25:47,170 --> 00:25:53,050
+ال meso compound is an achiral diastereomer of the
+
+305
+00:25:53,050 --> 00:25:56,450
+compound achiral يعني optically inactive شوفنا ليش
+
+306
+00:25:56,450 --> 00:26:02,470
+انه achiral و ليش انه optically inactiveرغم أنه في
+
+307
+00:26:02,470 --> 00:26:06,750
+مركز استيريوجينيك كم مركز استيريوجينيك فيه؟ اتنين
+
+308
+00:26:06,750 --> 00:26:11,630
+لكن هو بالمحصلة كايرال ولا اكايرال؟ اكايرال
+
+309
+00:26:11,630 --> 00:26:14,190
+optical and active although it contains
+
+310
+00:26:14,190 --> 00:26:18,030
+stereogenic centers الان its stereogenic centers
+
+311
+00:26:18,030 --> 00:26:23,190
+have opposite configurations يعني لازم واحد R
+
+312
+00:26:23,190 --> 00:26:26,970
+والتاني S هذا اللي بيكون ال mesocompound او نفس
+
+313
+00:26:26,970 --> 00:26:32,470
+المركب one half of the molecule isThe mirror image
+
+314
+00:26:32,470 --> 00:26:37,330
+of the other half اللي في هذه المواصفات بنقول انه
+
+315
+00:26:37,330 --> 00:26:43,520
+ميزو كومباوند بيكون مركب واحد مشمش مركبين
+
+316
+00:26:43,520 --> 00:26:46,160
+optically inactive يعني لو جينا سئلناكوا في
+
+317
+00:26:46,160 --> 00:26:49,360
+الامتحان ميزو كومباوند is optically active or
+
+318
+00:26:49,360 --> 00:26:55,260
+inactive؟ inactive الميزو كومباوند if مركب متماثل
+
+319
+00:26:55,260 --> 00:26:58,680
+لما اجي ارسم عندى two R three R two S three S و
+
+320
+00:26:58,680 --> 00:27:02,880
+two R three S او التانية من اللي فيهم بتكون ميزو؟
+
+321
+00:27:02,880 --> 00:27:09,000
+اللي فيها هدول عكس بعض يعني اللي بتكون RR او SS كل
+
+322
+00:27:09,000 --> 00:27:13,630
+واحدة منهم فردة in andيعني هذه لو أخدتها لحالها
+
+323
+00:27:13,630 --> 00:27:19,130
+optically active لو
+
+324
+00:27:19,130 --> 00:27:23,650
+عملت خليط متساوي من هدول الاتنين بيصير عند راسمك
+
+325
+00:27:24,520 --> 00:27:28,120
+mixture بيصير optical inactive لو أخدت من واحدة
+
+326
+00:27:28,120 --> 00:27:33,360
+اكتر من التانية زي ما اتعلمنا بيصير النتج نتاج
+
+327
+00:27:33,360 --> 00:27:38,600
+التنتين لكن هذا المركب هذا المركب اللي بيميزه انه
+
+328
+00:27:38,600 --> 00:27:43,100
+واحدة منه R والتانية S اذا انا لما بتعرف ال mezzo
+
+329
+00:27:43,100 --> 00:27:47,380
+compound في المركب المتماثل اللي بيكون منه واحدة R
+
+330
+00:27:47,380 --> 00:27:53,360
+والتانية S هذا ال mezzo compound والمجموع بيطلع
+
+331
+00:27:54,340 --> 00:27:59,240
+تلات مركبات في النهاية الان لو اتيت سألة طيب يا
+
+332
+00:27:59,240 --> 00:28:02,700
+تورا قولنا احنا اكيد بين هذا و هذا العلاقة they
+
+333
+00:28:02,700 --> 00:28:06,720
+are enantiomers طب لو اي واحد من هذول ال
+
+334
+00:28:06,720 --> 00:28:11,520
+enantiomers قرنته بال meso compound اه طلعوا two
+
+335
+00:28:11,520 --> 00:28:18,320
+are نفس الاشي هدوله واضح نفس الشي و three are
+
+336
+00:28:18,320 --> 00:28:24,870
+three asعكس بعض، اشي نفسه، اشي عكسه، فين VR؟ ده
+
+337
+00:28:24,870 --> 00:28:30,950
+يستيريو مارسي، فين VR؟ ده يستيريو مارسي بتايع ليه؟
+
+338
+00:28:30,950 --> 00:28:35,490
+بيكفي على موضوع ال two chiral centers الآن في
+
+339
+00:28:35,490 --> 00:28:41,850
+عندكم مجموعة من الأسئلة كيف توجدوا العلاقة بين
+
+340
+00:28:41,850 --> 00:28:47,080
+المركبين حتى لو رسمناهم بطرق مختلفةلاحظوا هذه
+
+341
+00:28:47,080 --> 00:28:50,980
+المُركّبات مرسومة بطرق مختلفة تماما مرة الـH لفوق
+
+342
+00:28:50,980 --> 00:28:54,820
+و مرة الـH على الجانب لكنهم نفس المُركّب بالمناسبة
+
+343
+00:28:54,820 --> 00:29:00,060
+يعني من ناحية structure أو روابط يعني كاربون
+
+344
+00:29:00,060 --> 00:29:04,280
+الأولى حملة PR و CL و بعدين CH3 و هاي الكاربون
+
+345
+00:29:04,280 --> 00:29:07,680
+اللي هو حملة PR و CL و بعدين CH3 يعني لو هذا و هذا
+
+346
+00:29:07,680 --> 00:29:13,090
+كنت بدأ أسميهم one-bromo one-chloro-ethaneمرة
+
+347
+00:29:13,090 --> 00:29:18,290
+تانية هاي carbon واحد هاي اتنين شو هتسموه وان
+
+348
+00:29:18,290 --> 00:29:25,500
+برومو وان كلوروإيه ثاني الار هدول الاتنين اللي
+
+349
+00:29:25,500 --> 00:29:29,680
+مرسومين بيدي العلاقة بينهم مش مرسومين بطريقة اللي
+
+350
+00:29:29,680 --> 00:29:33,180
+بالعين المجردة أشوف أنهم بينيهم مرسومين زي بعض أو
+
+351
+00:29:33,180 --> 00:29:37,000
+كل واحدة عكس التانية مرسومين بطرق مختلفة إذا على
+
+352
+00:29:37,000 --> 00:29:42,200
+طول ماليش حل إلا أحدد ال configuration أحددهم بضوء
+
+353
+00:29:42,200 --> 00:29:46,880
+هذا طلع R و هذا R then they are the same compound
+
+354
+00:29:46,880 --> 00:29:53,920
+واضح؟ الآن جيبنالكم مركبين تانينكم carbon هذا لو
+
+355
+00:29:53,920 --> 00:29:59,540
+بدكوا تسموه المركب هذا أطول سلسلة فيه قداش أربعة
+
+356
+00:29:59,540 --> 00:30:09,160
+واحد اتنين اعلم على أطول سلسلة CH3CCCH3
+
+357
+00:30:09,160 --> 00:30:17,440
+إذا هذا المركب اللي عندى بيوتين شو بيحمل بيوتين؟ع
+
+358
+00:30:17,440 --> 00:30:21,920
+نمره 2 برومه ع نمره 3 كلور ترقيب واحد عندي عشان
+
+359
+00:30:21,920 --> 00:30:26,340
+اخلي البروم اقل ما يمكن اتنين برومه ثلاثة ثلاثة
+
+360
+00:30:26,340 --> 00:30:27,620
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+361
+00:30:27,620 --> 00:30:29,600
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+362
+00:30:29,600 --> 00:30:36,300
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+363
+00:30:36,300 --> 00:30:44,220
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+364
+00:30:44,220 --> 00:30:50,050
+ثلاثة ثأحدد R و S لما أعملهم بهدوء بتعملهم في
+
+365
+00:30:50,050 --> 00:30:56,550
+البيت هنا two S and two R انبينين عكس بعض three S
+
+366
+00:30:56,550 --> 00:31:01,850
+and three R the same then they are diastereomers
+
+367
+00:31:01,850 --> 00:31:05,730
+كذلك
+
+368
+00:31:05,730 --> 00:31:11,930
+الحال هذا المركب هي أطول سلسلة فيهنطلع عليها واحد
+
+369
+00:31:11,930 --> 00:31:15,810
+اتنين تلاتة اربعة ع تنين برم وع تلاتة كلور وهذه
+
+370
+00:31:15,810 --> 00:31:20,350
+أطول السلسلة واحد اتنين تلاتة اربعة ع تنين برم وع
+
+371
+00:31:20,350 --> 00:31:28,710
+تلاتة كلور نحدد له R وS two S two R three S three
+
+372
+00:31:28,710 --> 00:31:37,170
+R الترقيم من هناك كل شيء عكس بعضين VR انانشومارز
+
+373
+00:31:37,170 --> 00:31:41,670
+اللي بعده نفس الشيء لو عملته بهدوءthe same
+
+374
+00:31:41,670 --> 00:31:46,270
+compound واضح؟ the same compound طبعا انتوا بدكوا
+
+375
+00:31:46,270 --> 00:31:51,970
+تحذروا بس بحالة واحدة لما يكون المركب متماثل و
+
+376
+00:31:51,970 --> 00:31:57,010
+يطلع عندكم 2R 3S و التالية 2S 3R بدكوا ترجعوا
+
+377
+00:31:57,010 --> 00:32:00,770
+تفكروا بالإيش بال meso compound اللي هو the same
+
+378
+00:32:00,770 --> 00:32:04,910
+compoundلو كان المراكب متماثل الأمثل هذا اللي
+
+379
+00:32:04,910 --> 00:32:09,350
+قدامكم مش متماثل لأنه على جهة بروم و على جهة كلور
+
+380
+00:32:09,350 --> 00:32:15,150
+دائما التفكير وين بده يكون قف و أفكر لما يكون فيه
+
+381
+00:32:15,150 --> 00:32:19,490
+تماثل داخلي إذا في تماثل داخلي و طلع عندكم ال
+
+382
+00:32:19,490 --> 00:32:26,150
+configurations في المتماثل إذا طلع عندكم R و S و
+
+383
+00:32:26,150 --> 00:32:31,390
+جبالها S و Rthey are the same compound هذا الحكي
+
+384
+00:32:31,390 --> 00:32:37,610
+وين بيكون في المركبات المتماثلة بيكون المركب فعلا
+
+385
+00:32:37,610 --> 00:32:44,630
+ميزو لما أحكي عن مركبين ر أس و أس و ر طلعوا معاكم
+
+386
+00:32:44,630 --> 00:32:51,270
+if مركب فيه تماثل داخلي بنقول عنهم they are the
+
+387
+00:32:51,270 --> 00:32:56,130
+same compound أو بنقول this is a mezzo compound
+
+388
+00:32:56,130 --> 00:33:01,530
+وبيكون طبعا opticallyinactive بيكون optically
+
+389
+00:33:01,530 --> 00:33:05,810
+inactive الان
+
+390
+00:33:05,810 --> 00:33:13,230
+لو اجينا لتفاعلات او التفاعلات المرتبطة بال stereo
+
+391
+00:33:13,230 --> 00:33:17,590
+chemistry في ال stereo chemistry في عندى اكتر من
+
+392
+00:33:17,590 --> 00:33:21,520
+نوع من التفاعلاتأحد هذه التفاعلات بنسميه
+
+393
+00:33:21,520 --> 00:33:25,720
+generation of a chiral center يعني انتوا بدأتوا
+
+394
+00:33:25,720 --> 00:33:30,320
+بمركب مش فيه ولا chiral center اعملتوا chiral
+
+395
+00:33:30,320 --> 00:33:35,740
+center خلينا ناخد مثال بسيط لو قلنا لكوا بدنا نعمل
+
+396
+00:33:35,740 --> 00:33:44,340
+chlorination للبيوتين بتذكرين البيوتين CH3 CH2 CH2
+
+397
+00:33:45,570 --> 00:33:50,510
+CH3 هل يترى هذا في أي كايرال سنتر؟ لا في كربون
+
+398
+00:33:50,510 --> 00:33:55,770
+بتحمل أربع مجموعات الآن بدنا نشيل هيدروجين يا من
+
+399
+00:33:55,770 --> 00:34:00,590
+موقع واحد يا من موقع اتنين يعني انا لما بعمل ال
+
+400
+00:34:00,590 --> 00:34:04,370
+chlorineation على البيوتين كام ناتج كنا متوقعين
+
+401
+00:34:04,370 --> 00:34:08,630
+اللي بيطلع عندنا اتنين المركب الأول اللي بيجيب ال
+
+402
+00:34:08,630 --> 00:34:13,150
+chlorine على موقع واحد هل صار في كايرال سنتر؟ لا
+
+403
+00:34:14,270 --> 00:34:18,910
+تخيلوا لو بدأ أضع الكلور على موقع واحد CH2CL
+
+404
+00:34:43,960 --> 00:34:47,500
+فى كل الأحوال بيصير عندى carol center يعني تخيل لو
+
+405
+00:34:47,500 --> 00:34:50,320
+أنا حاطيتها محل هذا الهيدروجين هيطلع هذا المُركّب
+
+406
+00:34:50,320 --> 00:34:55,040
+و لو حاطيتها محل هذا الهيدروجين هيطلع هذا المُركّب
+
+407
+00:34:55,040 --> 00:34:59,820
+اتطلعوا بينهم سواء كعلاقة أو لو حسبتولهم R و S
+
+408
+00:34:59,820 --> 00:35:07,910
+هتلاحظوا ان هدول الاتنين عكس بعض Rانانشو مارزي
+
+409
+00:35:07,910 --> 00:35:13,250
+يعني هاي ال H نفترض CL و بعدين اثلو مثل مبينة R
+
+410
+00:35:13,250 --> 00:35:18,650
+this is S وهي هذي ال H بنشطبها CL مبينة S هاي ال
+
+411
+00:35:18,650 --> 00:35:23,970
+configuration لهدول اذا انا وين اعملت chiral
+
+412
+00:35:23,970 --> 00:35:27,830
+center ع موقع واحد ولا ع موقع اتنين ع موقع اتنين
+
+413
+00:35:27,830 --> 00:35:31,870
+وين بعمل chiral center بطلع عندى خليط من two
+
+414
+00:35:31,870 --> 00:35:36,810
+انانشو مارزيبطلع عندى خليط من two enansimers اذا
+
+415
+00:35:36,810 --> 00:35:40,270
+لو اجيت انا سألتكوا الان سؤال بالمجمل
+
+416
+00:35:40,270 --> 00:35:46,110
+لchlorination of butane كم مركب بيعطينى تلاتة
+
+417
+00:35:46,110 --> 00:35:50,130
+تلاتة تنسوش انه انا في شغل مش كاتبة لأنه خارج
+
+418
+00:35:50,130 --> 00:35:57,190
+الإطار تبعنا انه لو فعلنا على هذا بيعطينا CH2CL
+
+419
+00:35:57,190 --> 00:36:00,450
+اللى هو ال one chlorobutane هذا مافيه chiral
+
+420
+00:36:00,450 --> 00:36:08,390
+centersهذا يبدو يجي الكلورة ع موقع واحد او ع موقع
+
+421
+00:36:08,390 --> 00:36:12,530
+اتنين ع موقع واحد عمل كايرال سنتر اذا هو مركب واحد
+
+422
+00:36:12,530 --> 00:36:16,490
+ع موقع اتنين عمل كايرال سنتر و ايه اللي بيصير
+
+423
+00:36:16,490 --> 00:36:20,790
+كايرال سنتر بيطلع عندى كام مركب اتنين اذا مجموع
+
+424
+00:36:20,790 --> 00:36:25,310
+المركبات قداشر تلاتة طب لو قولتلى واحدة سميلي
+
+425
+00:36:25,310 --> 00:36:27,890
+التلات نواتج اللى بيطلعوا من ال chlorineation و ال
+
+426
+00:36:27,890 --> 00:36:32,010
+butane شو هتقرأواحد كلورو بيوتين واحد كلورو بيوتين
+
+427
+00:36:32,010 --> 00:36:35,930
+ممتازة ارتو
+
+428
+00:36:35,930 --> 00:36:40,970
+كلورو بيوتين و استو كلورو بيوتين فبال total كام
+
+429
+00:36:40,970 --> 00:36:45,810
+مركب طلعوا تلاتة لكن لو كان السؤال كام structural
+
+430
+00:36:45,810 --> 00:36:50,610
+isomer بيطلع عنده من ال chlorineation اتنين لأن
+
+431
+00:36:50,610 --> 00:36:54,710
+معنى structural isomer مواقع الارتباط لكلور يا
+
+432
+00:36:54,710 --> 00:37:00,470
+بترتبط ع واحد يا بترتبط ع اتنينهدولة اتنين stereo
+
+433
+00:37:00,470 --> 00:37:05,390
+isomers ال R2 كلورو بيوتين و ال S2 كلورو بيوتين
+
+434
+00:37:05,390 --> 00:37:09,670
+they have the same bonding الارتباط فيه مع موقع
+
+435
+00:37:09,670 --> 00:37:13,870
+ايش اتنين but different arrangement in space هدولة
+
+436
+00:37:13,870 --> 00:37:18,010
+stereo isomers فبدكوا تنتبهوا لما بنسألكوا في
+
+437
+00:37:18,010 --> 00:37:21,550
+المنطقة لما نيجي نقولكم ال chlorineation في بيوتين
+
+438
+00:37:21,550 --> 00:37:26,670
+producesتو Structural Isomers، الـ Structural
+
+439
+00:37:26,670 --> 00:37:30,770
+مواقع، يا بتيجي الكلور على واحد، يا على اتنين،
+
+440
+00:37:30,770 --> 00:37:35,590
+الآن اللي على اتنين، في منها اتنين Stereoisomers،
+
+441
+00:37:35,590 --> 00:37:43,130
+اللي هم الـR والـS، واضح؟العلى اتنين في منها two
+
+442
+00:37:43,130 --> 00:37:47,750
+stereoisomers الار والاسم طبعا عادة بفسروا هذا
+
+443
+00:37:47,750 --> 00:37:50,870
+الكلام احنا مش اتنين ركزنا على ال mechanism of
+
+444
+00:37:50,870 --> 00:37:55,590
+reaction بفسروا انه هذا التفاعل اول ما بيبدأ
+
+445
+00:37:55,590 --> 00:38:00,410
+بترتفع في ذرة هيدروجين بيصيروا هدولة التلاتة
+
+446
+00:38:00,410 --> 00:38:06,520
+planner في مستوى واحد يعني لو انا بدي اجي اتخيلليش
+
+447
+00:38:06,520 --> 00:38:10,780
+تم التفاعل على الجهتين؟ لما تم التفاعل على
+
+448
+00:38:10,780 --> 00:38:18,200
+الجهتين؟ ممكن ايه بسرعة اريكم باستعمال ال models و
+
+449
+00:38:18,200 --> 00:38:27,360
+بأمل انها ال models بتخدمنا اتخيلوا
+
+450
+00:38:27,360 --> 00:38:33,500
+معنا لو اتخيلنا ان في عندنا CH3 ال CH3 نتخيلهاذرة
+
+451
+00:38:33,500 --> 00:38:39,550
+كربون صمرة CH3تمام؟ لما أشيل H بيبقى عندى كام
+
+452
+00:38:39,550 --> 00:38:44,650
+هيدروجين؟ واحدة و إيش بيبقى عندى؟ مجموعة ال إفل
+
+453
+00:38:44,650 --> 00:38:48,770
+لسه ماجيبتش ال chlorine أنا بدي بهذا كيف بعمل
+
+454
+00:38:48,770 --> 00:38:52,830
+الإبدال؟ بشيل الهيدروجينة في الأول و بعدين بحط
+
+455
+00:38:52,830 --> 00:38:57,250
+بدالها chlorine فدولة كام رابطة حوالين الكربون؟
+
+456
+00:38:57,250 --> 00:38:58,910
+أربعة أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+457
+00:38:58,910 --> 00:38:59,790
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+458
+00:38:59,790 --> 00:39:06,750
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة
+
+459
+00:39:07,360 --> 00:39:13,760
+بمشي الحال هاي هذا صار بهذا الشكل بالظبط طلعوا في
+
+460
+00:39:13,760 --> 00:39:20,740
+مجموعة مثل و H و إثل و ال H الأخيرة شيلناها
+
+461
+00:39:20,740 --> 00:39:24,240
+رفعناها الآن بدنا نجيب ال chlorine تتفاعل
+
+462
+00:39:26,450 --> 00:39:29,650
+هذه الـ Intermediate للحظة برفعت الـ H الأولى
+
+463
+00:39:29,650 --> 00:39:33,330
+بلانر في مستوى واحد الكلور بإمكانها تيجي تهاجم
+
+464
+00:39:33,330 --> 00:39:37,470
+عليها من هنا و هدولا بتعجوا حلو ميك او من هنا
+
+465
+00:39:37,470 --> 00:39:43,910
+طالما انها بلانر في فرق ان الكلور هي جاية من بعيد
+
+466
+00:39:43,910 --> 00:39:49,130
+بفرق عندها انها تمشي من هنا او من هنا اطلع معي
+
+467
+00:39:49,130 --> 00:39:52,670
+شايفين هدول الممرين اللي في القاعة لو انا بدي اروح
+
+468
+00:39:52,670 --> 00:39:59,700
+لاخر نقطةبإمكاني أمشي من هنا و من هنا بشكل متساوي
+
+469
+00:39:59,700 --> 00:40:04,520
+ولا لأ؟ ماعندي مشكلة، بدي أروح لآخر نقطة وهي عندي
+
+470
+00:40:04,520 --> 00:40:08,240
+مصارين متكافئت كذلك الحال، هذا planner بدي تيجي
+
+471
+00:40:08,240 --> 00:40:12,200
+اكلور من برا تتفاعل عليه، ترد تعمل المجموعة
+
+472
+00:40:12,200 --> 00:40:16,180
+الرابعةإذا أتيت من هنا عملة انانشومر و إذا أتيت من
+
+473
+00:40:16,180 --> 00:40:20,660
+هنا عملة التاني الان من ناحية الاحتمالات متساوية
+
+474
+00:40:20,660 --> 00:40:25,440
+تماما و لذلك يظهر عندي راسيمك ميكسشر يعني يظهر
+
+475
+00:40:25,440 --> 00:40:30,220
+الاتنين و يظهرون بنسب متساوية يظهر الاتنين و
+
+476
+00:40:30,220 --> 00:40:34,100
+يظهرون بنسب متساوية فبصير المحصلة ان ال generation
+
+477
+00:40:34,100 --> 00:40:42,710
+of a chiral center produces راسيمك ميكسشرواضح؟ ال
+
+478
+00:40:42,710 --> 00:40:46,690
+generation of a chiral center produces a racemic
+
+479
+00:40:46,690 --> 00:40:53,110
+mixture الان لو قلنا بدل racemic mixture equal
+
+480
+00:40:53,110 --> 00:40:59,740
+number of enantiomers أكيد صح .. أكيد صحgeneration
+
+481
+00:40:59,740 --> 00:41:02,520
+of a chiral center produces racemic mixtures
+
+482
+00:41:02,520 --> 00:41:10,660
+لاحظوا هذه الجملة بالنسبة للكيميا ما بين الكيميا
+
+483
+00:41:10,660 --> 00:41:15,480
+اللي بيصنعوها البشر و ما بين خلق الله سبحانه
+
+484
+00:41:15,480 --> 00:41:21,070
+وتعالى بتعمل فرق كبير جدااليوم لما انا باجي في
+
+485
+00:41:21,070 --> 00:41:26,450
+المختبر بده احضر مركب و اعمل chiral center انا
+
+486
+00:41:26,450 --> 00:41:31,290
+مابتحكمش في الاحتمالات بطلع عندى خليط متساوي و
+
+487
+00:41:31,290 --> 00:41:36,090
+بعدين اتعب و افصله و هذا السبب ربما في انه في دوة
+
+488
+00:41:36,090 --> 00:41:41,360
+مثل الثاليدواميد كان بيطلع الخليطالمتساوي ال R و
+
+489
+00:41:41,360 --> 00:41:45,860
+ال S لمنهم واحد مفيد و واحد ضار و عمل مشاكل كتير
+
+490
+00:41:45,860 --> 00:41:50,160
+كل ما بشغل في المختبر المختبر بطلعلي خليط من
+
+491
+00:41:50,160 --> 00:41:52,940
+المركبين اذا مش عندى chiral center انا بدي اعمله
+
+492
+00:41:52,940 --> 00:41:57,460
+بطلعلي .. بطلعلي ايش؟ racemic mixture الان في
+
+493
+00:41:57,460 --> 00:42:02,570
+الطبيعة فيه انزيماتالانزيمات كأنها بتاخد بإيدي
+
+494
+00:42:02,570 --> 00:42:05,850
+المجموعة اللي جاية بالظبط بداخلها من جهة واحدة
+
+495
+00:42:05,850 --> 00:42:10,030
+ولذلك المنتجات الطبيعية بيطلع منها بس one in a
+
+496
+00:42:10,030 --> 00:42:16,750
+number هذا خلقههذا خلق الله يعني انا لما شغلة كون
+
+497
+00:42:16,750 --> 00:42:21,210
+بتحضرها الانزيمات و بتتحضر جوا الجسم بتلاقوا بيطلع
+
+498
+00:42:21,210 --> 00:42:26,330
+منها بس واحد لما اجي انا اعيد التفاعل بالمختبر و
+
+499
+00:42:26,330 --> 00:42:30,110
+بدون انزيمات و بكذا بيطلع عندى خليط متساوي من
+
+500
+00:42:30,110 --> 00:42:34,830
+التنين ولذلك اللى بده مركبات نقية يعني بده one in
+
+501
+00:42:34,830 --> 00:42:39,750
+one شمر ايش اسهل طريقة يعملها؟ ياخدها من مصادرها
+
+502
+00:42:39,750 --> 00:42:44,590
+الطبيعية اذا كانت تحضر في الطبيعةطبعا إذا كانت لا
+
+503
+00:42:44,590 --> 00:42:51,850
+تحضر في الطبيعة بده يجعب هذه المشكلة و يطلع عنده
+
+504
+00:42:51,850 --> 00:42:56,450
+خليط من التنين عشان ايه كده في الكيميا بيسموه ايش
+
+505
+00:42:56,450 --> 00:43:02,990
+Symmetric Synthesis Symmetric Synthesis ايش معنى
+
+506
+00:43:02,990 --> 00:43:08,350
+Symmetric انه بيطلع خليط متمافل من التنين جد بعض و
+
+507
+00:43:08,350 --> 00:43:15,290
+بعدين يقعد ايش يعمليفصل فيهم الآن بدأوا من جديد
+
+508
+00:43:15,290 --> 00:43:21,030
+يستعملوا طرق حديثة في ال synthesis و يضيفوا عوامل
+
+509
+00:43:21,030 --> 00:43:25,330
+حفازة اللي تخلى واحد من هدول يطلع بنسبة اكتر من
+
+510
+00:43:25,330 --> 00:43:30,490
+التانية او يكاد يكون يطلع نقي وجدتها اذا طلعوا مش
+
+511
+00:43:30,490 --> 00:43:35,790
+متساويات شو بدى اسم ال synthesis Asymmetric
+
+512
+00:43:35,790 --> 00:43:40,010
+synthesisواضح؟ يعني الـ symmetric synthesis بتطلع
+
+513
+00:43:40,010 --> 00:43:44,810
+الخليط متساوي الآن إذا صرت أضيف عوامل حفازة بطرق
+
+514
+00:43:44,810 --> 00:43:49,290
+معينة بتحذيرات بصير أشتغل ايش؟ asymmetric
+
+515
+00:43:49,290 --> 00:43:52,910
+synthesis اليوم اللي منكم بده تدرس كيميا وبعدين
+
+516
+00:43:52,910 --> 00:43:57,120
+تقول أنا بدي أخد جائزة نوبل في الكيمياBye Bye
+
+517
+00:43:57,120 --> 00:44:01,260
+Asymmetric Synthesis بدا تشتغل على ايش؟ Asymmetric
+
+518
+00:44:01,260 --> 00:44:05,420
+Synthesis تصير تتعلم كتير تضيف عوامل حفازة
+
+519
+00:44:05,420 --> 00:44:12,040
+بمواصفات معينة تخلي التفاعل تطلع واحدمايطلعش
+
+520
+00:44:12,040 --> 00:44:16,200
+التاني او طلع واحد مثلا بنسبة 90% و التاني بنسبة
+
+521
+00:44:16,200 --> 00:44:20,800
+10% على سبيل المثال و كل ما جدت تطلع واحد تماما و
+
+522
+00:44:20,800 --> 00:44:26,500
+تلغي التاني كل ما كانت تمثل ايش نجاح كبير في الشغل
+
+523
+00:44:26,500 --> 00:44:31,720
+افهمنا اذا المشكلة ما بين الطبيعة و ما بين المختبر
+
+524
+00:44:31,720 --> 00:44:36,380
+المختبر هو وضع الطبيعيبطلّع لي خليط الطبيعة بوضعها
+
+525
+00:44:36,380 --> 00:44:42,120
+الطبيعي بطلّع واحد الان العالم بيسعوا نحو ايش؟ ان
+
+526
+00:44:42,120 --> 00:44:45,960
+يقتربوا من الطبيعة انهم يقدروا يطلعوا واحد و لو
+
+527
+00:44:45,960 --> 00:44:51,120
+بنسبة كبيرة في ما يسمى بالعلم ايش؟ asymmetric
+
+528
+00:44:51,120 --> 00:44:55,620
+synthesis بس بالتأكيد هذا الموضوع كتير متطور
+
+529
+00:44:55,620 --> 00:44:59,860
+بالنسبة لطالب organic يعني ما لم تتخصصوا كيميا مش
+
+530
+00:44:59,860 --> 00:45:02,460
+هتشتغلوا فيه بنكمل ان شاء الله في مرات
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/1TcAfdTqDds_raw.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/1TcAfdTqDds_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..864b835533104ec7e59ec3855116960bf3f85565
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/1TcAfdTqDds_raw.srt
@@ -0,0 +1,2128 @@
+1
+00:00:20,690 --> 00:00:24,750
+بسم الله الرحمن الرحيم في موضوع ال stereochemistry
+
+2
+00:00:24,750 --> 00:00:29,730
+ربما المرة الماضية نوّهنا من خلال أنفلة تطبيقية من
+
+3
+00:00:29,730 --> 00:00:36,970
+خلال أهمية فهم ال stereo isomers في الحياة العملية
+
+4
+00:00:36,970 --> 00:00:42,990
+أن هذا موضوع مهم ولذلك شوية بنظل نتوسع فيه بعد ما
+
+5
+00:00:42,990 --> 00:00:46,830
+أخدنا المركبات اللي فيها one chiral center قولنا
+
+6
+00:00:46,830 --> 00:00:51,610
+ال one chiral center بيعتق فقطtwo isomers بعد ذلك
+
+7
+00:00:51,610 --> 00:00:56,690
+إذا زاد العدد بيبدأوا يزيدوا ال isomers طبعا بيحكم
+
+8
+00:00:56,690 --> 00:01:00,890
+الأمر المعادلة two to the n لكن ال two to the n
+
+9
+00:01:00,890 --> 00:01:05,230
+هذا أقصى عدد ممكن من ال isomers في كل الأحوال ممكن
+
+10
+00:01:05,230 --> 00:01:10,290
+يكون العدد أقل من هيك وقلنا هنعطي مثال على العدد
+
+11
+00:01:10,290 --> 00:01:15,330
+الأقصى ومثال على وانتش العدد بيصير أقل في حالة ما
+
+12
+00:01:15,330 --> 00:01:20,620
+عندنا two chiral centersبدأنا في مثال كنا عادة
+
+13
+00:01:20,620 --> 00:01:25,140
+ناخده على أنه مثال بسيط يعني الفكره مركب واحد لما
+
+14
+00:01:25,140 --> 00:01:29,620
+نيجي نقول two three dichloro بنتين بالفكره مركب
+
+15
+00:01:29,620 --> 00:01:33,640
+واحد لكن لما بنيجي نتطلع على موقع اتنين وعلى موقع
+
+16
+00:01:33,640 --> 00:01:39,410
+تلاتةبنلاحظ ان الاتنين they are chiral centers
+
+17
+00:01:39,410 --> 00:01:42,750
+وبناء على ذلك بنبدأ نتوقع انه كام مركبة بيصير
+
+18
+00:01:42,750 --> 00:01:48,890
+عندنا اربع مركبات جربنا نرسمهم من خلال انه نتخيل
+
+19
+00:01:48,890 --> 00:01:52,010
+مثلا بدنا ناخد السلسلة الكربونية بهذا الشكل يعني
+
+20
+00:01:52,010 --> 00:01:56,970
+الخمس كربونات واحد اتنين تلاتة و الاثلاربعة خمسة
+
+21
+00:01:56,970 --> 00:02:01,390
+CH2 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+22
+00:02:01,390 --> 00:02:06,770
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+23
+00:02:06,770 --> 00:02:08,170
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+24
+00:02:08,170 --> 00:02:08,950
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+25
+00:02:08,950 --> 00:02:09,750
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+26
+00:02:09,750 --> 00:02:10,270
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+27
+00:02:10,270 --> 00:02:11,790
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+28
+00:02:11,790 --> 00:02:13,190
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+29
+00:02:13,190 --> 00:02:23,190
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+30
+00:02:23,190 --> 00:02:27,670
+CH3 CHيعني ال R عكسة S ال R عكسة S كلام منطقي الان
+
+31
+00:02:27,670 --> 00:02:32,110
+لو جينا نطلع على المركب الثاني two R three S هذا
+
+32
+00:02:32,110 --> 00:02:37,870
+عكسه ال R اقبلها S ال S اقبلها R لأنه دائما صورة
+
+33
+00:02:37,870 --> 00:02:43,590
+بعض في المرأة بتعني التعاكس التام فلو احنا سألنا
+
+34
+00:02:43,590 --> 00:02:48,170
+ايش العلاقة بين واحد و اتنين they are enantiomersو
+
+35
+00:02:48,170 --> 00:02:52,290
+بيصير مفهوم عندنا ان اي مركبة لما نقول عنهم in
+
+36
+00:02:52,290 --> 00:02:58,650
+anchors بدتكون اشاراتهم عكس بعض الان طبعا انتوا
+
+37
+00:02:58,650 --> 00:03:02,390
+بالنظر بتقولوا صورة بعض في المرأة غير متطابقة لكن
+
+38
+00:03:02,390 --> 00:03:08,390
+ماتنسوش شغلة ان انا بإمكاني ارسم
+
+39
+00:03:09,150 --> 00:03:13,850
+المُركّب بطرق مختلفة بحيث أنه انتوا بمجرد النظر
+
+40
+00:03:13,850 --> 00:03:18,430
+البسيط ما تقدروش تتاخدوا قرار من النظر وجهة القرار
+
+41
+00:03:18,430 --> 00:03:21,750
+الأكيد بتقدروا تتاخدوا من إيش في علاقة بين
+
+42
+00:03:21,750 --> 00:03:29,110
+المُركّبين من قيم A و S خليني أؤكد الفكرة هذه لو
+
+43
+00:03:29,110 --> 00:03:34,310
+فقط أنا بدي أشغل معكم على مُركّب في one chiral
+
+44
+00:03:34,310 --> 00:03:40,470
+centerلو رسمت منه شكلين شو الاحتمالات المتوقعين
+
+45
+00:03:40,470 --> 00:03:43,610
+لما يكون عندي one chiral center؟ يا بده يكون
+
+46
+00:03:43,610 --> 00:03:48,910
+المركب نفسه رسمه بطريقتين مختلفة يا بده يكون in
+
+47
+00:03:48,910 --> 00:03:51,410
+anchormers ماعندي احتمال تاني
+
+48
+00:03:53,870 --> 00:04:01,450
+أخذ بسرعة عشوائيا هاي مركّب CH3CLPR وهي مركّب كتبت
+
+49
+00:04:01,450 --> 00:04:08,010
+هنا ال PR وهنا ال H وهنا ال CL وهنا ال CH3 لاحظوا
+
+50
+00:04:08,010 --> 00:04:12,610
+هدول المركّبين لو سألتكم ما العلاقة بينهما اللي
+
+51
+00:04:12,610 --> 00:04:16,030
+بده تيجي تتطلع تشوف أي شيء بالنظر و المرايا و
+
+52
+00:04:16,030 --> 00:04:22,100
+بنطبقه و مابنطبقوش حتىمش هتقدر، لأنه أنا أرسمهم
+
+53
+00:04:22,100 --> 00:04:25,640
+بطرق مختلفة، ماحدش بيمنعني أرسمهم بطرق مختلفة،
+
+54
+00:04:25,640 --> 00:04:31,700
+الآن أسهل شيء أن أحدد لكل مركب R أو S، الآن إذا
+
+55
+00:04:31,700 --> 00:04:35,500
+هذا طلع R و هذا R، معنى ذلك نفس المركب مرسوم بطرق
+
+56
+00:04:35,500 --> 00:04:40,800
+مختلفة، S و S نفس المركبإذا هذا R و هذا S, they
+
+57
+00:04:40,800 --> 00:04:44,140
+are enantiomers إذا هذا S و هذا R, they are
+
+58
+00:04:44,140 --> 00:04:48,260
+enantiomers هيكا بيكون أسهل طريقة أن أعملهم ولذلك
+
+59
+00:04:48,260 --> 00:04:54,380
+لو بدي أجي أطلع لهذا أقل مجموع ال H ب RCLCH3 من
+
+60
+00:04:54,380 --> 00:05:00,660
+بين R S لأن هذا ال H للأمام الآن لو بدي أطلع
+
+61
+00:05:00,660 --> 00:05:12,780
+المركب الثاني ب R CL SCH3 بين R مرة تانية وبنخليها
+
+62
+00:05:12,780 --> 00:05:18,100
+R لأن ال H للخلف هدول الانشو مارس طالما واحد قسي
+
+63
+00:05:18,100 --> 00:05:21,380
+التاني R إذا we are in ancho mars فالانشو مارس
+
+64
+00:05:21,380 --> 00:05:25,040
+دايما عكس بعض الان لو عندكوا خمسة كايرة ال centers
+
+65
+00:05:25,040 --> 00:05:29,520
+مش واحدإيش بتكون في الخمسة يكونوا عشان يكونوا
+
+66
+00:05:29,520 --> 00:05:35,300
+مركبين انانشومارز؟ كل واحد عكس التاني زي أنا باجف
+
+67
+00:05:35,300 --> 00:05:38,420
+قدام المرايا، الإيدين عكس بعض، الوش عكس بعض، البطن
+
+68
+00:05:38,420 --> 00:05:42,060
+عكس بعض، الرجلين عكس بعض، كل شيء بيكون عكس التاني،
+
+69
+00:05:42,060 --> 00:05:45,120
+يعني لو عندي ان شاء الله عشرين Cairo Center في
+
+70
+00:05:45,120 --> 00:05:49,600
+مركب، الانانشومارز تبعه، العشرين المقابلات بيكونوا
+
+71
+00:05:49,600 --> 00:05:56,300
+عكسهم، لو واحدة منهم اختلتببطلوا in anchormers على
+
+72
+00:05:56,300 --> 00:05:59,840
+طول ببطلوا صورة بعض في المرآة إذا بطلوا صورة بعض
+
+73
+00:05:59,840 --> 00:06:04,700
+في المرآة، شو بدوا يصيروا؟ ديستيريومارز، تنسوش إن
+
+74
+00:06:04,700 --> 00:06:08,740
+احنا عرفنا الديستيريومارز، they are non-mirror
+
+75
+00:06:08,740 --> 00:06:12,580
+image in anchormers ولذلك لو أنا سألت العلاقة بين
+
+76
+00:06:12,580 --> 00:06:20,780
+هدول، خلّينا نوضحها باسم RS عكس بعضعكس بعض اذا
+
+77
+00:06:20,780 --> 00:06:24,580
+they are enansimals واضح؟ الان لو سئلت هدول
+
+78
+00:06:24,580 --> 00:06:33,560
+الاتنين RS SR عكس طلع عليهم R اقبلها S S اقبلها R
+
+79
+00:06:33,560 --> 00:06:39,320
+عكس بعض they are enansimals الان لو اجيت اخدت مثلا
+
+80
+00:06:39,320 --> 00:06:49,160
+المركب واحد مع تلاتة اتطلعوا R وRهدولا متل بعض و
+
+81
+00:06:49,160 --> 00:06:56,860
+are و us عكس بعض هل هدولا عكس بعض بالكامل؟ لأ
+
+82
+00:06:56,860 --> 00:07:01,500
+هدولا متل بعض بالكامل؟ لأ مالو كانوا عكس بعض
+
+83
+00:07:01,500 --> 00:07:04,560
+بالكامل يعني كل نقطة عكس التانية they are
+
+84
+00:07:04,560 --> 00:07:10,000
+enantiomers الان لو كل نقطة زي التانية they are
+
+85
+00:07:10,000 --> 00:07:14,600
+the same compoundلو كل نقطة زي التانية هو نفس
+
+86
+00:07:14,600 --> 00:07:20,760
+المُركّب الـ R إيش زي بعض و إيش عكس بعض بطلوا صورة
+
+87
+00:07:20,760 --> 00:07:24,400
+بعض في المرأة أو بطلوا نفس المُركّب إيش هيصفه؟ ده
+
+88
+00:07:24,400 --> 00:07:28,180
+الـ Stereomers إذا لما بنيجي نتطلع إنه بدنا نفهم
+
+89
+00:07:28,180 --> 00:07:32,260
+العلاقة بين مُركّبين من خلال الرموز هنقول إنه
+
+90
+00:07:32,260 --> 00:07:36,260
+عندنا تلت احتمالات في حالة ما عندي أكتر من chiral
+
+91
+00:07:36,260 --> 00:07:40,600
+center لحظة لما كان عندي one chiral centerبدون ما
+
+92
+00:07:40,600 --> 00:07:44,080
+أعمل R و S بقولكوا عندي احتمالين يا بدهم يكونوا
+
+93
+00:07:44,080 --> 00:07:50,120
+نفس المركب R R S S يا بدهم يكونوا Enansi و Mars S
+
+94
+00:07:50,120 --> 00:07:54,840
+R أو R S الان لو كان عندي more than one chiral
+
+95
+00:07:54,840 --> 00:07:57,960
+center عندي تلت احتمالات الاحتمال الاول بدهم
+
+96
+00:07:57,960 --> 00:08:03,440
+يكونوا Enansi و Mars كل شيء عكس بعض الاحتمال
+
+97
+00:08:03,440 --> 00:08:09,150
+التاني انهم يكونوا نفس المركب كل شيء نفسهزي بعض طب
+
+98
+00:08:09,150 --> 00:08:12,950
+لو طلع شيء عكس و شيء زي بعض وجدت دي R ده يستيريو
+
+99
+00:08:12,950 --> 00:08:18,370
+مارس لحظوا الآن لو اجيت على واحد و تلاتة R و S عكس
+
+100
+00:08:18,370 --> 00:08:23,670
+بعض R و R زي بعض اذا هدولة صورت بعض في المرقاة لأ
+
+101
+00:08:23,670 --> 00:08:28,530
+نفس المركب لأ ر ده يستيريو مارس اذا واحد و تلاتة
+
+102
+00:08:28,530 --> 00:08:31,970
+ده يستيريو مارس لو طبقته مرة تانية على واحد و
+
+103
+00:08:31,970 --> 00:08:39,700
+أربعة مثلا ما العلاقة بينهم Rو S عكس بعض، هم
+
+104
+00:08:39,700 --> 00:08:47,540
+لاحظين؟ R و R نفس بعض، they are diastereomers لو
+
+105
+00:08:47,540 --> 00:08:52,720
+إجينا اتطلعنا على اتنين و تلاتة،
+
+106
+00:08:52,720 --> 00:09:02,010
+لاحظوا؟ S و Rعكس بعض السؤاس زي بعض كذلك الحال لو
+
+107
+00:09:02,010 --> 00:09:08,070
+اتطلعت اتنين اربع السؤاس نفس الاشي السؤاد عكس بعض
+
+108
+00:09:08,070 --> 00:09:13,230
+they are diastereomers واضح؟صار عندى نوع تانى من
+
+109
+00:09:13,230 --> 00:09:17,590
+الدياستيريو مارز جاي من وين جاي من المركبات فيها
+
+110
+00:09:17,590 --> 00:09:20,910
+chiral centers يعني احنا اول ما أخدنا تعريف
+
+111
+00:09:20,910 --> 00:09:25,270
+الدياستيريو مارز قولنا كل شيء مش صورة بعض في
+
+112
+00:09:25,270 --> 00:09:29,500
+المرقاة they are diastereomarsالأمثلة الكيميائية
+
+113
+00:09:29,500 --> 00:09:33,820
+الأولى اللى أخدناها شو هي الـ Cis والـ Trans أو
+
+114
+00:09:33,820 --> 00:09:37,300
+الـ Z والـ E they are diastereomers الآن بيجينا
+
+115
+00:09:37,300 --> 00:09:40,900
+أمثلة تانية لما يكون عندى more than one chiral
+
+116
+00:09:40,900 --> 00:09:45,160
+center هذه الأمثلة بتقول القاتل انه لو كان في عندى
+
+117
+00:09:45,160 --> 00:09:51,530
+مركبين في الإشارات تبعتهممش زي بعض تماما، مش نفس
+
+118
+00:09:51,530 --> 00:09:54,650
+المُركّب، ولا Inansiomers و they are
+
+119
+00:09:54,650 --> 00:10:00,010
+stereoisomers، إيش هيصفهم؟ ديستيريو مارس، واضح؟
+
+120
+00:10:00,010 --> 00:10:05,270
+وبهيك أخدنا إن الديستيريو مارس بكم ما كان، بنشوفهم
+
+121
+00:10:05,270 --> 00:10:11,460
+بالكيميامكالين بال CC trans او ZE و بال chiral
+
+122
+00:10:11,460 --> 00:10:15,680
+compounds او بال stereo chemistry لما يكون عندى
+
+123
+00:10:15,680 --> 00:10:21,440
+اكتر من chiral center بشرط انه ننتبه ل ROS
+
+124
+00:10:21,440 --> 00:10:27,760
+بالطريقة اللى اتكلمنا فيها الان طالما ان هدولةالهم
+
+125
+00:10:27,760 --> 00:10:31,760
+إشارات مختلفة فى كام مركب عندى لتو ثري دايكلورو
+
+126
+00:10:31,760 --> 00:10:36,180
+بنتين أربعة هى رموزهم اللى بدى تروح تشتريهم من
+
+127
+00:10:36,180 --> 00:10:39,800
+السوق هتلاقيهم أربعة مركبات الآن احنا قولنا ممكن
+
+128
+00:10:39,800 --> 00:10:46,760
+يكون العدد أقل ناخد مثالهذا المثال 2,3
+
+129
+00:10:46,760 --> 00:10:51,800
+-dichlorobutane قال ذرة كربون واحدة يعني لو انا
+
+130
+00:10:51,800 --> 00:10:56,080
+رسمت هاي كربون تنتين تلاتة اربعة اذا المركب اللي
+
+131
+00:10:56,080 --> 00:11:02,100
+عندى ايش بيوتين واضح لاحظوا ايش بيفرق يعني كتير
+
+132
+00:11:02,100 --> 00:11:09,120
+لبيوتين عنالبنتين لو انا مجرد ان كتبت كتابة مثل
+
+133
+00:11:09,120 --> 00:11:17,800
+CH3 CHCl CHCl CH3 عارفين شو بيفرق؟ لو انا اتيت بين
+
+134
+00:11:17,800 --> 00:11:20,840
+هدولة الـ chiral centers التنين الكاربونز اللي
+
+135
+00:11:20,840 --> 00:11:26,760
+حاملة كلور و جسمت المركب من النصتطلعوا هنا إيش
+
+136
+00:11:26,760 --> 00:11:33,460
+اللي موجود Carbon حاملة HCl و بعدها CH3 و هنا
+
+137
+00:11:33,460 --> 00:11:39,240
+Carbon حاملة HCl و بعدها CH3 إذا هذا المركب صار
+
+138
+00:11:39,240 --> 00:11:44,460
+مركب متماثل قبل شوية لما كنت .. أو من هنا على هذا
+
+139
+00:11:44,460 --> 00:11:49,800
+الشكل أجسم زي هيك تطلعوا كأعداد ذراتماذا عندكم
+
+140
+00:11:49,800 --> 00:11:54,980
+هنا؟ كاربون حاملة HCl وCH3 وهنا كاربون حاملة HCl
+
+141
+00:11:54,980 --> 00:12:01,860
+وCH3 فعدد الذرات اللي بهذا الاتجاه هو نفسه عدد
+
+142
+00:12:01,860 --> 00:12:05,760
+الذرات اللي بهذا الاتجاه فهذا الكاربون بيحمل نوع
+
+143
+00:12:05,760 --> 00:12:10,380
+من التماثل هذا الكلام في المثال السابق ماكانش لما
+
+144
+00:12:10,380 --> 00:12:16,160
+كنتوا تحطوا خط هنابين ال two chiral centers عدولي
+
+145
+00:12:16,160 --> 00:12:22,780
+كل الذرات اللي هتشومها C وH وCL و CH3 و هنا CH وCL
+
+146
+00:12:22,780 --> 00:12:29,460
+و بعدها CH2 CH3 إذا هل هذا النص زي هذا النص لأ في
+
+147
+00:12:29,460 --> 00:12:34,910
+حالة البيوتينأ لبيوتين في تماثل داخلي بين ال two
+
+148
+00:12:34,910 --> 00:12:39,790
+chiral centers يعني المركب سيماتريك الآن لو إجينا
+
+149
+00:12:39,790 --> 00:12:44,310
+جربنا نرسم ال isomers بنفس الطريقة اللي اتعلمناها
+
+150
+00:12:44,310 --> 00:12:51,270
+سابقا يعني أجي أحط تنتين كلور عكس بعض و صورتهم في
+
+151
+00:12:51,270 --> 00:12:54,810
+المرأة و تنتين كلور على جهة واحدة و صورتهم في
+
+152
+00:12:54,810 --> 00:13:02,210
+المرأة و بعدين أحدد R و Sلاحظوا هذه الرسمة تماما
+
+153
+00:13:02,210 --> 00:13:06,510
+هي نسخ و لصق من الرسمة السابقة بس بدل ما كنا
+
+154
+00:13:06,510 --> 00:13:12,890
+كاتبين هنا اثل كتبنا مثل واضح؟ و لذلك انتوا الان
+
+155
+00:13:12,890 --> 00:13:20,310
+كام مركب بتشوفه؟مازالتوا بتشوفوا أربع مركبات
+
+156
+00:13:20,310 --> 00:13:26,150
+للوهلة الأولى لكن لو نظرنا بعمق لهدولة الأربع
+
+157
+00:13:26,150 --> 00:13:32,130
+مركبات هلاحظ ان هذا 2R3R و هذا 2S3S
+
+158
+00:13:34,300 --> 00:13:40,660
+عكس بعض هتيجوا تستنتجوا انهم انانشومارز فش اننا
+
+159
+00:13:40,660 --> 00:13:45,160
+خلاف الآن لما بتيجوا تطلع على المركبين التانيين
+
+160
+00:13:45,160 --> 00:13:49,140
+وخلونا نقول .. نقولنا الترقيم واحد اتنين تلاتة
+
+161
+00:13:49,140 --> 00:13:55,720
+اربعة واحد اتنين تلاتة اربعة و هيناخد واحدة بس
+
+162
+00:13:55,720 --> 00:14:01,560
+نأكد هي ال CL نمرة واحدوهذه ال carbon الحاملة Cl2
+
+163
+00:14:01,560 --> 00:14:09,860
+و CH3 بين S كتبناها R وهذه لو بدنا نتطلع عليها 1 2
+
+164
+00:14:09,860 --> 00:14:16,300
+Cl بعدين carbon حاملة Cl بعدين CH3 Cl بعدين carbon
+
+165
+00:14:16,300 --> 00:14:21,100
+حاملة Cl بعدين CH3 بين R كتبنا S إذا هيك مظبوطين
+
+166
+00:14:21,100 --> 00:14:25,900
+هدولة two R three Sلو اعملنا المركب التاني لجبانو
+
+167
+00:14:25,900 --> 00:14:30,260
+بين two as three are اي حد هيتطلع بهذا الشكل
+
+168
+00:14:30,260 --> 00:14:33,800
+البصير شو هيقول هدول العلاقة بينهم they are
+
+169
+00:14:33,800 --> 00:14:36,760
+enantiomers الان بنقول لأ they are the same
+
+170
+00:14:36,760 --> 00:14:42,420
+compound هتبدو يصير عندكم مشكلة ليش لأنه هتقولوا
+
+171
+00:14:42,420 --> 00:14:47,540
+انت لسه توت و التصوير شاهد علينا كمان بتقول انه
+
+172
+00:14:47,540 --> 00:14:55,020
+اذا كل شيء عكس بعضهthey are enantiomers هاي مثال و
+
+173
+00:14:55,020 --> 00:14:59,320
+فيها دول عكس بعض لكن أنا قاعد بقول عنهم they are
+
+174
+00:14:59,320 --> 00:15:05,060
+the same compound كيف هذا الكلام بيصير؟ هل يا ترى
+
+175
+00:15:05,060 --> 00:15:09,520
+الإنسان بناقض في الحكي ولا لأ؟ الحقيقة في سبب و
+
+176
+00:15:09,520 --> 00:15:15,240
+الأمر هنابحاجة إلى نظرة شوية متعمقة .. بحاجة إلى
+
+177
+00:15:15,240 --> 00:15:19,380
+نظرة شوية متعمقة بين هدول الصورتين تحديدا لو
+
+178
+00:15:19,380 --> 00:15:23,140
+اتخيلتوا انتوا .. لو اتخيلتوا ان انتوا حاطيتوا
+
+179
+00:15:23,140 --> 00:15:26,660
+دبوس هنا مسيكتوا هذا المركب بعدين لفتوه بهذا الشكل
+
+180
+00:15:26,660 --> 00:15:30,980
+طلعوا معايا مرة تانية كأنه هنا فيه محور و الف
+
+181
+00:15:30,980 --> 00:15:35,640
+المركب بهذا الشكل وين هتيجي هذه ال CH3 وين هتطلع
+
+182
+00:15:35,640 --> 00:15:41,720
+هذه ال CL تنتين وين هييجوا ال Hهيصيروا نفس هذا
+
+183
+00:15:41,720 --> 00:15:48,580
+المُركّب ولا لأ؟ نفس المُركّب واضح؟ بهذا الشكل
+
+184
+00:15:48,580 --> 00:15:54,420
+لفوه هاي الـ CLE جوهان و الـ H3 و الـ CH3 انعكسوا
+
+185
+00:15:54,420 --> 00:16:00,660
+ممكن واحدة تيجي تقولي ما كان لفت اللي قبله خليني
+
+186
+00:16:00,660 --> 00:16:05,680
+أرجع للي قبله اللي قبله ماكانش متمثل يعني لما ألف
+
+187
+00:16:05,680 --> 00:16:12,140
+شو بده ينزل هنا CH3 شو بده يطلع هنا؟صح لما انا هاد
+
+188
+00:16:12,140 --> 00:16:15,140
+و بدى ألف و هيك ال CL's و ال H's بيجوا مكان بعض
+
+189
+00:16:15,140 --> 00:16:19,940
+لكن محل ال Ethel شو بتيجي؟ محل ال Ethel مثل هذه
+
+190
+00:16:20,690 --> 00:16:26,010
+املاحظين يعني هذا لو لفته بينطبق على هذا لأ بينما
+
+191
+00:16:26,010 --> 00:16:30,910
+اللي بعده بينطبق ماسبب الانطباق في الحالة التالية
+
+192
+00:16:30,910 --> 00:16:34,390
+و عدم الانطباق في الحالة الأولى انه هذا في الحالة
+
+193
+00:16:34,390 --> 00:16:39,970
+هذه غير متماثل داخليا يعني هذه CH3 هذه اتل مش هذا
+
+194
+00:16:39,970 --> 00:16:47,410
+النص زي هذا بينما في المركب اللي بعده هذا متماثل
+
+195
+00:16:48,570 --> 00:16:51,090
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+196
+00:16:51,090 --> 00:16:58,750
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+197
+00:16:58,750 --> 00:16:59,530
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+198
+00:16:59,530 --> 00:17:00,070
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+199
+00:17:00,070 --> 00:17:00,090
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+200
+00:17:00,090 --> 00:17:00,210
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+201
+00:17:00,210 --> 00:17:00,910
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+202
+00:17:00,910 --> 00:17:00,950
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+203
+00:17:00,950 --> 00:17:01,730
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+204
+00:17:01,730 --> 00:17:13,310
+مثل مثل
+
+205
+00:17:13,310 --> 00:17:17,470
+مثل مثالـR و الـS اللي مبينين عكس بعض كيف بدنا نحل
+
+206
+00:17:17,470 --> 00:17:23,450
+مشكلتهم لأن احنا قلنا إذا كل شي عكس بعض لازم نصنف
+
+207
+00:17:23,450 --> 00:17:28,970
+المراكبات in anchors طب هي مبينين عكس بعض آه مديش
+
+208
+00:17:28,970 --> 00:17:33,990
+تنسوا شغلة هذا المراكب لو أنا جبته لكم في الامتحان
+
+209
+00:17:33,990 --> 00:17:39,610
+و قلتلكم سموهو إجت واحدة منكم اتطلعت فيه و حطت
+
+210
+00:17:39,610 --> 00:17:46,850
+ترقيم 1234 صار هذا موقع 2 و عملته لجته 2R هذا موقع
+
+211
+00:17:46,850 --> 00:17:53,050
+3 و عملته لجته 3S طيب لو واحدة تانية إجت و قالت
+
+212
+00:17:53,050 --> 00:18:00,930
+خليني أرقم من تحت ما هو متمثل هاي 1234 ع 23 أيضا
+
+213
+00:18:01,530 --> 00:18:06,510
+Echlor, إذا هذا بترقم من كام جهة؟ من الجهتين نفس
+
+214
+00:18:06,510 --> 00:18:11,230
+الشيء هذا بترقم من الجهتين نفس الشيء المركب اللي
+
+215
+00:18:11,230 --> 00:18:16,230
+جابي اللي بقدرش أعمل فيه هذا الكلام بدي أكو أتضالك
+
+216
+00:18:16,230 --> 00:18:22,490
+و أتقرره لو كنت بده أرقم من هنا هذه CH2 CH3 لحظة
+
+217
+00:18:22,490 --> 00:18:28,720
+واحد اتنين هيصيروا ال Echlorتلاتة اربعة واحد اتنين
+
+218
+00:18:28,720 --> 00:18:34,200
+تلاتة اذا هذا كام ترقيم يحتمل واحد فقط واحد اتنين
+
+219
+00:18:34,200 --> 00:18:37,920
+تلاتة عشان ال glory يكونوا اقل ترقيم من هنا واحد
+
+220
+00:18:37,920 --> 00:18:41,140
+اتنين تلاتة اربعة خمسة بيكون اتنين تلاتة من هنا
+
+221
+00:18:41,140 --> 00:18:45,640
+واحد اتنين تلاتة اربعة خمسة بيصير تلاتة اربعة اذا
+
+222
+00:18:45,640 --> 00:18:52,420
+هذا كام ترقيم يحتمليحتمل ترقيم واحد فقط لكن المركب
+
+223
+00:18:52,420 --> 00:18:56,880
+اللي بعده المتماثل لو انا رقمته زي ما انتوا شايفين
+
+224
+00:18:56,880 --> 00:19:06,100
+بالازرق صح و لو انا رقمته بالاحمر صح طيب اللي رقمت
+
+225
+00:19:06,100 --> 00:19:12,660
+بالازرق كتبت المركب 2R3S23Diclorobutane
+
+226
+00:19:12,660 --> 00:19:17,390
+طب و اللي بده ترقم بالاحمر شو هتكتب؟الـ 2 ما احنا
+
+227
+00:19:17,390 --> 00:19:21,950
+عارفين ان هذه R و هذه S بغض النظر عن الترقيم هتكتب
+
+228
+00:19:21,950 --> 00:19:25,270
+2S3R
+
+229
+00:19:25,270 --> 00:19:30,930
+الآن اي جواب اللي بدنا نعتبره صح الجوابين صح هذا
+
+230
+00:19:30,930 --> 00:19:36,610
+إله اسمين هذا إله اسمين لأنه متماثل وعشانك المدرس
+
+231
+00:19:36,610 --> 00:19:40,250
+اللي بده يصلح بيجيبلكوا هذا المركب ويقولكوا اعطوه
+
+232
+00:19:40,250 --> 00:19:45,680
+اسمهذا الجواب يبدو يعتبره صح وهذا الجواب يبدو
+
+233
+00:19:45,680 --> 00:19:49,600
+يعتبره صح لسبب بسيط انه مافيه فارق نهائي بين انكوا
+
+234
+00:19:49,600 --> 00:19:54,280
+ترقموه من هنا او من هنا الان نفس الشيء في المركب
+
+235
+00:19:54,280 --> 00:19:58,900
+التاني لما رقمناه بالازرق واحد اتنين تلاتة اربعة
+
+236
+00:19:58,900 --> 00:20:05,140
+طب لو واحدة عملتله ترقيم تاني بالاحمر ايش هتكتبوه؟
+
+237
+00:20:05,140 --> 00:20:11,040
+two R three S الان اتطلعوا هذا أحد أسماء two S
+
+238
+00:20:11,040 --> 00:20:19,770
+three Rهذا أحد أسمائه 2R3S
+
+239
+00:20:19,770 --> 00:20:28,590
+و هذا 2R3S لأن الجزء ببساطة متماثل لأن هذا الجزء
+
+240
+00:20:28,590 --> 00:20:33,490
+ببساطة متماثل بياخد اسمين و هدول الشكلين بيكونوا
+
+241
+00:20:33,490 --> 00:20:38,710
+مركب واحد مش مركبينواضح؟ مركّب واحد وبتسمى
+
+242
+00:20:38,710 --> 00:20:42,110
+بطريقتين، الآن إذا اتفقنا إن هدولة they are the
+
+243
+00:20:42,110 --> 00:20:46,250
+same compound، بأكتر من طريقة فرجيتكم، اللي بدأ من
+
+244
+00:20:46,250 --> 00:20:49,710
+خلال الإشارات، إنه يلهم نفس الإشارات، أيه؟ يلهم
+
+245
+00:20:49,710 --> 00:20:56,750
+نفس الإشارات ولا لأ؟2R 3S .. 2S 3R .. 2S 3R .. 2S
+
+246
+00:20:56,750 --> 00:21:04,650
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+247
+00:21:04,650 --> 00:21:05,570
+2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R
+
+248
+00:21:05,570 --> 00:21:05,730
+.. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S
+
+249
+00:21:05,730 --> 00:21:05,930
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+250
+00:21:05,930 --> 00:21:06,830
+2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R
+
+251
+00:21:06,830 --> 00:21:06,830
+.. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S
+
+252
+00:21:06,830 --> 00:21:14,070
+3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R .. 2S 3R ..
+
+253
+00:21:14,070 --> 00:21:21,840
+2S 3R .. 2S 3Rوغيرهم سواء سمته 2R3S او 2S3R هو نفس
+
+254
+00:21:21,840 --> 00:21:26,100
+المركب له اسميننفس المركب له اسمين شو اللي عمله
+
+255
+00:21:26,100 --> 00:21:31,660
+الاسمين التماثل اذا لو انا بجاجي اسأل ببساطة لو
+
+256
+00:21:31,660 --> 00:21:35,480
+واحدة ع طول بده تعرف انه عندها اربع مركبات ولا
+
+257
+00:21:35,480 --> 00:21:40,320
+تلاتة ايش اول ما بده تطلع عليه في الجزء انه هل يا
+
+258
+00:21:40,320 --> 00:21:44,460
+ترى هذا الجزء اللي عنده فيه تماثل ولا لا اذا فيه
+
+259
+00:21:44,460 --> 00:21:49,620
+تماثل ع طول بده تحكي عن كام مركبعن تلاتة مافيش
+
+260
+00:21:49,620 --> 00:21:53,820
+تماثل بده تحكي عن أربع يعني لو مثلا سألكوا هذا
+
+261
+00:21:53,820 --> 00:22:05,280
+السؤال CH3 CHBR CHCL CH3 كام Cairo Center فيه؟هن و
+
+262
+00:22:05,280 --> 00:22:09,200
+هن قبل ما ارسم ايزو مارزو اتعب كام ايزو مارزو
+
+263
+00:22:09,200 --> 00:22:14,480
+تتوقعوا له اربعة عطول اربعة ليش لانه انا لو جسمت
+
+264
+00:22:14,480 --> 00:22:18,260
+بين هدولة two chiral centers هذي الظرات مش هى هذي
+
+265
+00:22:18,260 --> 00:22:25,060
+الظرات هنا عندكم H و CL هنا H .. خلاص انتهى واضح؟
+
+266
+00:22:25,060 --> 00:22:31,600
+و هكذاواضح، الان هذا المركب اللي فيه تماثل داخلي،
+
+267
+00:22:31,600 --> 00:22:37,860
+لو انتوا بتتأملوا فيه بعمق شوية، بتحسوا انه اللي
+
+268
+00:22:37,860 --> 00:22:44,250
+خلّاه يصيرنفس المركب و اقدر الفه انه انا لو اني
+
+269
+00:22:44,250 --> 00:22:48,650
+اتخيلت مرايا في نص المركب هذا النص اللى فوق صورة
+
+270
+00:22:48,650 --> 00:22:52,770
+النص اللى تحت فى المرأة ولا لأ طلعوا معاك هى ال CL
+
+271
+00:22:52,770 --> 00:23:00,790
+اقبالها CL ال H H ال مثل مثل اذا one half of the
+
+272
+00:23:00,790 --> 00:23:04,170
+molecule is the mirror image of the other half ولا
+
+273
+00:23:04,170 --> 00:23:10,660
+لأ هذا النص هو صورة هذا النص فى المرأةواضح الكلام؟
+
+274
+00:23:10,660 --> 00:23:14,420
+زي الناس اللي بتطلعوا على كروت الشدة إذا عمركوا
+
+275
+00:23:14,420 --> 00:23:18,780
+شفتوها بتشوفوا الرسومات اللي فيها البني آدم هيك او
+
+276
+00:23:18,780 --> 00:23:24,620
+بصر هيك بعدين هذا
+
+277
+00:23:24,620 --> 00:23:29,540
+زيه بالظبط .. هذا زيه بالظبط أنه النص هذا .. صورة
+
+278
+00:23:29,540 --> 00:23:37,180
+النص هذا في المرأةواضح؟ الان هذا المركب كأنه حقيقة
+
+279
+00:23:37,180 --> 00:23:42,380
+يحتوي على مركبين كأنه هذا مركب بإمكانكوا تتخيلوه و
+
+280
+00:23:42,380 --> 00:23:47,540
+هذا مركب تاني و هاي هم بس متصلين في بعض و من البعض
+
+281
+00:23:47,540 --> 00:23:52,760
+لو إجيت بديت أفكر بعمق شوية هذا لو إنه حطناه لوحده
+
+282
+00:23:52,760 --> 00:23:59,810
+في المرآة بيطلع كايران و إلهrotation وهذا لو حطيته
+
+283
+00:23:59,810 --> 00:24:04,450
+لوحده في المرأة كايرة له rotation طيب لو أخدت
+
+284
+00:24:04,450 --> 00:24:09,530
+مليون جزء من المركب الكلي كده يكون من هذا النص
+
+285
+00:24:09,530 --> 00:24:15,370
+مليون و من هذا النص مليون و المليونين عكس بعض صار
+
+286
+00:24:15,370 --> 00:24:21,750
+هذا بنفسه يشبه إيش؟Racemic mixture اللى أخدناه
+
+287
+00:24:21,750 --> 00:24:25,510
+المرة الماضية لما كنا نقولكوا لو كان عندى خليط
+
+288
+00:24:25,510 --> 00:24:31,050
+متساوي من two isomers شو سمناه؟ Racemic mixture
+
+289
+00:24:31,050 --> 00:24:35,850
+واحد منهم بيلف يمين التانى اشمال قداش بيكون
+
+290
+00:24:35,850 --> 00:24:41,240
+بالمجمل ال rotation له؟ سفرالـ Racemic mixture
+
+291
+00:24:41,240 --> 00:24:45,460
+بيكون optically active ولا inactive؟ optically
+
+292
+00:24:45,460 --> 00:24:48,880
+inactive ليش optically inactive؟ لأنه فيه عدد
+
+293
+00:24:48,880 --> 00:24:54,240
+متساوي من ال enantiomers بيلغوا بعض الان هذا تماما
+
+294
+00:24:54,240 --> 00:24:58,700
+يشبه الracemic mixture كأنه هاي نص و هاي نص هدول
+
+295
+00:24:58,700 --> 00:25:04,040
+عكس بعض ولا لا؟ واحد R و واحد S الجزء الكبير لو
+
+296
+00:25:04,040 --> 00:25:09,210
+منه مليون كدهش فيه من هذا؟ و من هذا؟أذا هذا
+
+297
+00:25:09,210 --> 00:25:13,330
+racemic mixture كأنه بامتياز بس موجود في مركب واحد
+
+298
+00:25:13,330 --> 00:25:17,550
+فهذا المركب بالمجمل بيكون optically active ولا
+
+299
+00:25:17,550 --> 00:25:24,070
+inactive هالمركب العجيب هذا المتماثل اللي موجود ال
+
+300
+00:25:24,070 --> 00:25:28,390
+configuration فيه لنصه عكس التاني اللي نصه صورة
+
+301
+00:25:28,390 --> 00:25:32,270
+بعض أو صورة نص التاني في المرآة أخد اسم في ال
+
+302
+00:25:32,270 --> 00:25:36,910
+stereo chemistry بيسميه meso compound أو
+
+303
+00:25:36,910 --> 00:25:42,570
+mesostructureلحظة الان لو بدنا نقرأ ايش تعريف ال
+
+304
+00:25:42,570 --> 00:25:47,170
+meso compound كل الكلام هذا معرف هنا كل اللي حكينا
+
+305
+00:25:47,170 --> 00:25:53,050
+ال meso compound is an achiral diastereomer of the
+
+306
+00:25:53,050 --> 00:25:56,450
+compound achiral يعني optically inactive شوفنا ليش
+
+307
+00:25:56,450 --> 00:26:02,470
+انه achiral و ليش انه optically inactiveرغم أنه في
+
+308
+00:26:02,470 --> 00:26:06,750
+مركز استيريوجينيك كم مركز استيريوجينيك فيه؟ اتنين
+
+309
+00:26:06,750 --> 00:26:11,630
+لكن هو بالمحصلة كايرال ولا اكايرال؟ اكايرال
+
+310
+00:26:11,630 --> 00:26:14,190
+optical and active although it contains
+
+311
+00:26:14,190 --> 00:26:18,030
+stereogenic centers الان its stereogenic centers
+
+312
+00:26:18,030 --> 00:26:23,190
+have opposite configurations يعني لازم واحد R
+
+313
+00:26:23,190 --> 00:26:26,970
+والتاني S هذا اللي بيكون ال mesocompound او نفس
+
+314
+00:26:26,970 --> 00:26:32,470
+المركب one half of the molecule isThe mirror image
+
+315
+00:26:32,470 --> 00:26:37,330
+of the other half اللي في هذه المواصفات بنقول انه
+
+316
+00:26:37,330 --> 00:26:43,520
+ميزو كومباوند بيكون مركب واحد مشمش مركبين
+
+317
+00:26:43,520 --> 00:26:46,160
+optically inactive يعني لو جينا سئلناكوا في
+
+318
+00:26:46,160 --> 00:26:49,360
+الامتحان ميزو كومباوند is optically active or
+
+319
+00:26:49,360 --> 00:26:55,260
+inactive؟ inactive الميزو كومباوند if مركب متماثل
+
+320
+00:26:55,260 --> 00:26:58,680
+لما اجي ارسم عندى two R three R two S three S و
+
+321
+00:26:58,680 --> 00:27:02,880
+two R three S او التانية من اللي فيهم بتكون ميزو؟
+
+322
+00:27:02,880 --> 00:27:09,000
+اللي فيها هدول عكس بعض يعني اللي بتكون RR او SS كل
+
+323
+00:27:09,000 --> 00:27:13,630
+واحدة منهم فردة in andيعني هذه لو أخدتها لحالها
+
+324
+00:27:13,630 --> 00:27:19,130
+optically active لو
+
+325
+00:27:19,130 --> 00:27:23,650
+عملت خليط متساوي من هدول الاتنين بيصير عند راسمك
+
+326
+00:27:24,520 --> 00:27:28,120
+mixture بيصير optical inactive لو أخدت من واحدة
+
+327
+00:27:28,120 --> 00:27:33,360
+اكتر من التانية زي ما اتعلمنا بيصير النتج نتاج
+
+328
+00:27:33,360 --> 00:27:38,600
+التنتين لكن هذا المركب هذا المركب اللي بيميزه انه
+
+329
+00:27:38,600 --> 00:27:43,100
+واحدة منه R والتانية S اذا انا لما بتعرف ال mezzo
+
+330
+00:27:43,100 --> 00:27:47,380
+compound في المركب المتماثل اللي بيكون منه واحدة R
+
+331
+00:27:47,380 --> 00:27:53,360
+والتانية S هذا ال mezzo compound والمجموع بيطلع
+
+332
+00:27:54,340 --> 00:27:59,240
+تلات مركبات في النهاية الان لو اتيت سألة طيب يا
+
+333
+00:27:59,240 --> 00:28:02,700
+تورا قولنا احنا اكيد بين هذا و هذا العلاقة they
+
+334
+00:28:02,700 --> 00:28:06,720
+are enantiomers طب لو اي واحد من هذول ال
+
+335
+00:28:06,720 --> 00:28:11,520
+enantiomers قرنته بال meso compound اه طلعوا two
+
+336
+00:28:11,520 --> 00:28:18,320
+are نفس الاشي هدوله واضح نفس الشي و three are
+
+337
+00:28:18,320 --> 00:28:24,870
+three asعكس بعض، اشي نفسه، اشي عكسه، فين VR؟ ده
+
+338
+00:28:24,870 --> 00:28:30,950
+يستيريو مارسي، فين VR؟ ده يستيريو مارسي بتايع ليه؟
+
+339
+00:28:30,950 --> 00:28:35,490
+بيكفي على موضوع ال two chiral centers الآن في
+
+340
+00:28:35,490 --> 00:28:41,850
+عندكم مجموعة من الأسئلة كيف توجدوا العلاقة بين
+
+341
+00:28:41,850 --> 00:28:47,080
+المركبين حتى لو رسمناهم بطرق مختلفةلاحظوا هذه
+
+342
+00:28:47,080 --> 00:28:50,980
+المُركّبات مرسومة بطرق مختلفة تماما مرة الـH لفوق
+
+343
+00:28:50,980 --> 00:28:54,820
+و مرة الـH على الجانب لكنهم نفس المُركّب بالمناسبة
+
+344
+00:28:54,820 --> 00:29:00,060
+يعني من ناحية structure أو روابط يعني كاربون
+
+345
+00:29:00,060 --> 00:29:04,280
+الأولى حملة PR و CL و بعدين CH3 و هاي الكاربون
+
+346
+00:29:04,280 --> 00:29:07,680
+اللي هو حملة PR و CL و بعدين CH3 يعني لو هذا و هذا
+
+347
+00:29:07,680 --> 00:29:13,090
+كنت بدأ أسميهم one-bromo one-chloro-ethaneمرة
+
+348
+00:29:13,090 --> 00:29:18,290
+تانية هاي carbon واحد هاي اتنين شو هتسموه وان
+
+349
+00:29:18,290 --> 00:29:25,500
+برومو وان كلوروإيه ثاني الار هدول الاتنين اللي
+
+350
+00:29:25,500 --> 00:29:29,680
+مرسومين بيدي العلاقة بينهم مش مرسومين بطريقة اللي
+
+351
+00:29:29,680 --> 00:29:33,180
+بالعين المجردة أشوف أنهم بينيهم مرسومين زي بعض أو
+
+352
+00:29:33,180 --> 00:29:37,000
+كل واحدة عكس التانية مرسومين بطرق مختلفة إذا على
+
+353
+00:29:37,000 --> 00:29:42,200
+طول ماليش حل إلا أحدد ال configuration أحددهم بضوء
+
+354
+00:29:42,200 --> 00:29:46,880
+هذا طلع R و هذا R then they are the same compound
+
+355
+00:29:46,880 --> 00:29:53,920
+واضح؟ الآن جيبنالكم مركبين تانينكم carbon هذا لو
+
+356
+00:29:53,920 --> 00:29:59,540
+بدكوا تسموه المركب هذا أطول سلسلة فيه قداش أربعة
+
+357
+00:29:59,540 --> 00:30:09,160
+واحد اتنين اعلم على أطول سلسلة CH3CCCH3
+
+358
+00:30:09,160 --> 00:30:17,440
+إذا هذا المركب اللي عندى بيوتين شو بيحمل بيوتين؟ع
+
+359
+00:30:17,440 --> 00:30:21,920
+نمره 2 برومه ع نمره 3 كلور ترقيب واحد عندي عشان
+
+360
+00:30:21,920 --> 00:30:26,340
+اخلي البروم اقل ما يمكن اتنين برومه ثلاثة ثلاثة
+
+361
+00:30:26,340 --> 00:30:27,620
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+362
+00:30:27,620 --> 00:30:29,600
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+363
+00:30:29,600 --> 00:30:36,300
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+364
+00:30:36,300 --> 00:30:44,220
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+365
+00:30:44,220 --> 00:30:50,050
+ثلاثة ثأحدد R و S لما أعملهم بهدوء بتعملهم في
+
+366
+00:30:50,050 --> 00:30:56,550
+البيت هنا two S and two R انبينين عكس بعض three S
+
+367
+00:30:56,550 --> 00:31:01,850
+and three R the same then they are diastereomers
+
+368
+00:31:01,850 --> 00:31:05,730
+كذلك
+
+369
+00:31:05,730 --> 00:31:11,930
+الحال هذا المركب هي أطول سلسلة فيهنطلع عليها واحد
+
+370
+00:31:11,930 --> 00:31:15,810
+اتنين تلاتة اربعة ع تنين برم وع تلاتة كلور وهذه
+
+371
+00:31:15,810 --> 00:31:20,350
+أطول السلسلة واحد اتنين تلاتة اربعة ع تنين برم وع
+
+372
+00:31:20,350 --> 00:31:28,710
+تلاتة كلور نحدد له R وS two S two R three S three
+
+373
+00:31:28,710 --> 00:31:37,170
+R الترقيم من هناك كل شيء عكس بعضين VR انانشومارز
+
+374
+00:31:37,170 --> 00:31:41,670
+اللي بعده نفس الشيء لو عملته بهدوءthe same
+
+375
+00:31:41,670 --> 00:31:46,270
+compound واضح؟ the same compound طبعا انتوا بدكوا
+
+376
+00:31:46,270 --> 00:31:51,970
+تحذروا بس بحالة واحدة لما يكون المركب متماثل و
+
+377
+00:31:51,970 --> 00:31:57,010
+يطلع عندكم 2R 3S و التالية 2S 3R بدكوا ترجعوا
+
+378
+00:31:57,010 --> 00:32:00,770
+تفكروا بالإيش بال meso compound اللي هو the same
+
+379
+00:32:00,770 --> 00:32:04,910
+compoundلو كان المراكب متماثل الأمثل هذا اللي
+
+380
+00:32:04,910 --> 00:32:09,350
+قدامكم مش متماثل لأنه على جهة بروم و على جهة كلور
+
+381
+00:32:09,350 --> 00:32:15,150
+دائما التفكير وين بده يكون قف و أفكر لما يكون فيه
+
+382
+00:32:15,150 --> 00:32:19,490
+تماثل داخلي إذا في تماثل داخلي و طلع عندكم ال
+
+383
+00:32:19,490 --> 00:32:26,150
+configurations في المتماثل إذا طلع عندكم R و S و
+
+384
+00:32:26,150 --> 00:32:31,390
+جبالها S و Rthey are the same compound هذا الحكي
+
+385
+00:32:31,390 --> 00:32:37,610
+وين بيكون في المركبات المتماثلة بيكون المركب فعلا
+
+386
+00:32:37,610 --> 00:32:44,630
+ميزو لما أحكي عن مركبين ر أس و أس و ر طلعوا معاكم
+
+387
+00:32:44,630 --> 00:32:51,270
+if مركب فيه تماثل داخلي بنقول عنهم they are the
+
+388
+00:32:51,270 --> 00:32:56,130
+same compound أو بنقول this is a mezzo compound
+
+389
+00:32:56,130 --> 00:33:01,530
+وبيكون طبعا opticallyinactive بيكون optically
+
+390
+00:33:01,530 --> 00:33:05,810
+inactive الان
+
+391
+00:33:05,810 --> 00:33:13,230
+لو اجينا لتفاعلات او التفاعلات المرتبطة بال stereo
+
+392
+00:33:13,230 --> 00:33:17,590
+chemistry في ال stereo chemistry في عندى اكتر من
+
+393
+00:33:17,590 --> 00:33:21,520
+نوع من التفاعلاتأحد هذه التفاعلات بنسميه
+
+394
+00:33:21,520 --> 00:33:25,720
+generation of a chiral center يعني انتوا بدأتوا
+
+395
+00:33:25,720 --> 00:33:30,320
+بمركب مش فيه ولا chiral center اعملتوا chiral
+
+396
+00:33:30,320 --> 00:33:35,740
+center خلينا ناخد مثال بسيط لو قلنا لكوا بدنا نعمل
+
+397
+00:33:35,740 --> 00:33:44,340
+chlorination للبيوتين بتذكرين البيوتين CH3 CH2 CH2
+
+398
+00:33:45,570 --> 00:33:50,510
+CH3 هل يترى هذا في أي كايرال سنتر؟ لا في كربون
+
+399
+00:33:50,510 --> 00:33:55,770
+بتحمل أربع مجموعات الآن بدنا نشيل هيدروجين يا من
+
+400
+00:33:55,770 --> 00:34:00,590
+موقع واحد يا من موقع اتنين يعني انا لما بعمل ال
+
+401
+00:34:00,590 --> 00:34:04,370
+chlorineation على البيوتين كام ناتج كنا متوقعين
+
+402
+00:34:04,370 --> 00:34:08,630
+اللي بيطلع عندنا اتنين المركب الأول اللي بيجيب ال
+
+403
+00:34:08,630 --> 00:34:13,150
+chlorine على موقع واحد هل صار في كايرال سنتر؟ لا
+
+404
+00:34:14,270 --> 00:34:18,910
+تخيلوا لو بدأ أضع الكلور على موقع واحد CH2CL
+
+405
+00:34:43,960 --> 00:34:47,500
+فى كل الأحوال بيصير عندى carol center يعني تخيل لو
+
+406
+00:34:47,500 --> 00:34:50,320
+أنا حاطيتها محل هذا الهيدروجين هيطلع هذا المُركّب
+
+407
+00:34:50,320 --> 00:34:55,040
+و لو حاطيتها محل هذا الهيدروجين هيطلع هذا المُركّب
+
+408
+00:34:55,040 --> 00:34:59,820
+اتطلعوا بينهم سواء كعلاقة أو لو حسبتولهم R و S
+
+409
+00:34:59,820 --> 00:35:07,910
+هتلاحظوا ان هدول الاتنين عكس بعض Rانانشو مارزي
+
+410
+00:35:07,910 --> 00:35:13,250
+يعني هاي ال H نفترض CL و بعدين اثلو مثل مبينة R
+
+411
+00:35:13,250 --> 00:35:18,650
+this is S وهي هذي ال H بنشطبها CL مبينة S هاي ال
+
+412
+00:35:18,650 --> 00:35:23,970
+configuration لهدول اذا انا وين اعملت chiral
+
+413
+00:35:23,970 --> 00:35:27,830
+center ع موقع واحد ولا ع موقع اتنين ع موقع اتنين
+
+414
+00:35:27,830 --> 00:35:31,870
+وين بعمل chiral center بطلع عندى خليط من two
+
+415
+00:35:31,870 --> 00:35:36,810
+انانشو مارزيبطلع عندى خليط من two enansimers اذا
+
+416
+00:35:36,810 --> 00:35:40,270
+لو اجيت انا سألتكوا الان سؤال بالمجمل
+
+417
+00:35:40,270 --> 00:35:46,110
+لchlorination of butane كم مركب بيعطينى تلاتة
+
+418
+00:35:46,110 --> 00:35:50,130
+تلاتة تنسوش انه انا في شغل مش كاتبة لأنه خارج
+
+419
+00:35:50,130 --> 00:35:57,190
+الإطار تبعنا انه لو فعلنا على هذا بيعطينا CH2CL
+
+420
+00:35:57,190 --> 00:36:00,450
+اللى هو ال one chlorobutane هذا مافيه chiral
+
+421
+00:36:00,450 --> 00:36:08,390
+centersهذا يبدو يجي الكلورة ع موقع واحد او ع موقع
+
+422
+00:36:08,390 --> 00:36:12,530
+اتنين ع موقع واحد عمل كايرال سنتر اذا هو مركب واحد
+
+423
+00:36:12,530 --> 00:36:16,490
+ع موقع اتنين عمل كايرال سنتر و ايه اللي بيصير
+
+424
+00:36:16,490 --> 00:36:20,790
+كايرال سنتر بيطلع عندى كام مركب اتنين اذا مجموع
+
+425
+00:36:20,790 --> 00:36:25,310
+المركبات قداشر تلاتة طب لو قولتلى واحدة سميلي
+
+426
+00:36:25,310 --> 00:36:27,890
+التلات نواتج اللى بيطلعوا من ال chlorineation و ال
+
+427
+00:36:27,890 --> 00:36:32,010
+butane شو هتقرأواحد كلورو بيوتين واحد كلورو بيوتين
+
+428
+00:36:32,010 --> 00:36:35,930
+ممتازة ارتو
+
+429
+00:36:35,930 --> 00:36:40,970
+كلورو بيوتين و استو كلورو بيوتين فبال total كام
+
+430
+00:36:40,970 --> 00:36:45,810
+مركب طلعوا تلاتة لكن لو كان السؤال كام structural
+
+431
+00:36:45,810 --> 00:36:50,610
+isomer بيطلع عنده من ال chlorineation اتنين لأن
+
+432
+00:36:50,610 --> 00:36:54,710
+معنى structural isomer مواقع الارتباط لكلور يا
+
+433
+00:36:54,710 --> 00:37:00,470
+بترتبط ع واحد يا بترتبط ع اتنينهدولة اتنين stereo
+
+434
+00:37:00,470 --> 00:37:05,390
+isomers ال R2 كلورو بيوتين و ال S2 كلورو بيوتين
+
+435
+00:37:05,390 --> 00:37:09,670
+they have the same bonding الارتباط فيه مع موقع
+
+436
+00:37:09,670 --> 00:37:13,870
+ايش اتنين but different arrangement in space هدولة
+
+437
+00:37:13,870 --> 00:37:18,010
+stereo isomers فبدكوا تنتبهوا لما بنسألكوا في
+
+438
+00:37:18,010 --> 00:37:21,550
+المنطقة لما نيجي نقولكم ال chlorineation في بيوتين
+
+439
+00:37:21,550 --> 00:37:26,670
+producesتو Structural Isomers، الـ Structural
+
+440
+00:37:26,670 --> 00:37:30,770
+مواقع، يا بتيجي الكلور على واحد، يا على اتنين،
+
+441
+00:37:30,770 --> 00:37:35,590
+الآن اللي على اتنين، في منها اتنين Stereoisomers،
+
+442
+00:37:35,590 --> 00:37:43,130
+اللي هم الـR والـS، واضح؟العلى اتنين في منها two
+
+443
+00:37:43,130 --> 00:37:47,750
+stereoisomers الار والاسم طبعا عادة بفسروا هذا
+
+444
+00:37:47,750 --> 00:37:50,870
+الكلام احنا مش اتنين ركزنا على ال mechanism of
+
+445
+00:37:50,870 --> 00:37:55,590
+reaction بفسروا انه هذا التفاعل اول ما بيبدأ
+
+446
+00:37:55,590 --> 00:38:00,410
+بترتفع في ذرة هيدروجين بيصيروا هدولة التلاتة
+
+447
+00:38:00,410 --> 00:38:06,520
+planner في مستوى واحد يعني لو انا بدي اجي اتخيلليش
+
+448
+00:38:06,520 --> 00:38:10,780
+تم التفاعل على الجهتين؟ لما تم التفاعل على
+
+449
+00:38:10,780 --> 00:38:18,200
+الجهتين؟ ممكن ايه بسرعة اريكم باستعمال ال models و
+
+450
+00:38:18,200 --> 00:38:27,360
+بأمل انها ال models بتخدمنا اتخيلوا
+
+451
+00:38:27,360 --> 00:38:33,500
+معنا لو اتخيلنا ان في عندنا CH3 ال CH3 نتخيلهاذرة
+
+452
+00:38:33,500 --> 00:38:39,550
+كربون صمرة CH3تمام؟ لما أشيل H بيبقى عندى كام
+
+453
+00:38:39,550 --> 00:38:44,650
+هيدروجين؟ واحدة و إيش بيبقى عندى؟ مجموعة ال إفل
+
+454
+00:38:44,650 --> 00:38:48,770
+لسه ماجيبتش ال chlorine أنا بدي بهذا كيف بعمل
+
+455
+00:38:48,770 --> 00:38:52,830
+الإبدال؟ بشيل الهيدروجينة في الأول و بعدين بحط
+
+456
+00:38:52,830 --> 00:38:57,250
+بدالها chlorine فدولة كام رابطة حوالين الكربون؟
+
+457
+00:38:57,250 --> 00:38:58,910
+أربعة أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+458
+00:38:58,910 --> 00:38:59,790
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+459
+00:38:59,790 --> 00:38:59,790
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟
+
+460
+00:38:59,790 --> 00:39:06,750
+أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة؟ أربعة
+
+461
+00:39:07,360 --> 00:39:13,760
+بمشي الحال هاي هذا صار بهذا الشكل بالظبط طلعوا في
+
+462
+00:39:13,760 --> 00:39:20,740
+مجموعة مثل و H و إثل و ال H الأخيرة شيلناها
+
+463
+00:39:20,740 --> 00:39:24,240
+رفعناها الآن بدنا نجيب ال chlorine تتفاعل
+
+464
+00:39:26,450 --> 00:39:29,650
+هذه الـ Intermediate للحظة برفعت الـ H الأولى
+
+465
+00:39:29,650 --> 00:39:33,330
+بلانر في مستوى واحد الكلور بإمكانها تيجي تهاجم
+
+466
+00:39:33,330 --> 00:39:37,470
+عليها من هنا و هدولا بتعجوا حلو ميك او من هنا
+
+467
+00:39:37,470 --> 00:39:43,910
+طالما انها بلانر في فرق ان الكلور هي جاية من بعيد
+
+468
+00:39:43,910 --> 00:39:49,130
+بفرق عندها انها تمشي من هنا او من هنا اطلع معي
+
+469
+00:39:49,130 --> 00:39:52,670
+شايفين هدول الممرين اللي في القاعة لو انا بدي اروح
+
+470
+00:39:52,670 --> 00:39:59,700
+لاخر نقطةبإمكاني أمشي من هنا و من هنا بشكل متساوي
+
+471
+00:39:59,700 --> 00:40:04,520
+ولا لأ؟ ماعندي مشكلة، بدي أروح لآخر نقطة وهي عندي
+
+472
+00:40:04,520 --> 00:40:08,240
+مصارين متكافئت كذلك الحال، هذا planner بدي تيجي
+
+473
+00:40:08,240 --> 00:40:12,200
+اكلور من برا تتفاعل عليه، ترد تعمل المجموعة
+
+474
+00:40:12,200 --> 00:40:16,180
+الرابعةإذا أتيت من هنا عملة انانشومر و إذا أتيت من
+
+475
+00:40:16,180 --> 00:40:20,660
+هنا عملة التاني الان من ناحية الاحتمالات متساوية
+
+476
+00:40:20,660 --> 00:40:25,440
+تماما و لذلك يظهر عندي راسيمك ميكسشر يعني يظهر
+
+477
+00:40:25,440 --> 00:40:30,220
+الاتنين و يظهرون بنسب متساوية يظهر الاتنين و
+
+478
+00:40:30,220 --> 00:40:34,100
+يظهرون بنسب متساوية فبصير المحصلة ان ال generation
+
+479
+00:40:34,100 --> 00:40:42,710
+of a chiral center produces راسيمك ميكسشرواضح؟ ال
+
+480
+00:40:42,710 --> 00:40:46,690
+generation of a chiral center produces a racemic
+
+481
+00:40:46,690 --> 00:40:53,110
+mixture الان لو قلنا بدل racemic mixture equal
+
+482
+00:40:53,110 --> 00:40:59,740
+number of enantiomers أكيد صح .. أكيد صحgeneration
+
+483
+00:40:59,740 --> 00:41:02,520
+of a chiral center produces racemic mixtures
+
+484
+00:41:02,520 --> 00:41:10,660
+لاحظوا هذه الجملة بالنسبة للكيميا ما بين الكيميا
+
+485
+00:41:10,660 --> 00:41:15,480
+اللي بيصنعوها البشر و ما بين خلق الله سبحانه
+
+486
+00:41:15,480 --> 00:41:21,070
+وتعالى بتعمل فرق كبير جدااليوم لما انا باجي في
+
+487
+00:41:21,070 --> 00:41:26,450
+المختبر بده احضر مركب و اعمل chiral center انا
+
+488
+00:41:26,450 --> 00:41:31,290
+مابتحكمش في الاحتمالات بطلع عندى خليط متساوي و
+
+489
+00:41:31,290 --> 00:41:36,090
+بعدين اتعب و افصله و هذا السبب ربما في انه في دوة
+
+490
+00:41:36,090 --> 00:41:41,360
+مثل الثاليدواميد كان بيطلع الخليطالمتساوي ال R و
+
+491
+00:41:41,360 --> 00:41:45,860
+ال S لمنهم واحد مفيد و واحد ضار و عمل مشاكل كتير
+
+492
+00:41:45,860 --> 00:41:50,160
+كل ما بشغل في المختبر المختبر بطلعلي خليط من
+
+493
+00:41:50,160 --> 00:41:52,940
+المركبين اذا مش عندى chiral center انا بدي اعمله
+
+494
+00:41:52,940 --> 00:41:57,460
+بطلعلي .. بطلعلي ايش؟ racemic mixture الان في
+
+495
+00:41:57,460 --> 00:42:02,570
+الطبيعة فيه انزيماتالانزيمات كأنها بتاخد بإيدي
+
+496
+00:42:02,570 --> 00:42:05,850
+المجموعة اللي جاية بالظبط بداخلها من جهة واحدة
+
+497
+00:42:05,850 --> 00:42:10,030
+ولذلك المنتجات الطبيعية بيطلع منها بس one in a
+
+498
+00:42:10,030 --> 00:42:16,750
+number هذا خلقههذا خلق الله يعني انا لما شغلة كون
+
+499
+00:42:16,750 --> 00:42:21,210
+بتحضرها الانزيمات و بتتحضر جوا الجسم بتلاقوا بيطلع
+
+500
+00:42:21,210 --> 00:42:26,330
+منها بس واحد لما اجي انا اعيد التفاعل بالمختبر و
+
+501
+00:42:26,330 --> 00:42:30,110
+بدون انزيمات و بكذا بيطلع عندى خليط متساوي من
+
+502
+00:42:30,110 --> 00:42:34,830
+التنين ولذلك اللى بده مركبات نقية يعني بده one in
+
+503
+00:42:34,830 --> 00:42:39,750
+one شمر ايش اسهل طريقة يعملها؟ ياخدها من مصادرها
+
+504
+00:42:39,750 --> 00:42:44,590
+الطبيعية اذا كانت تحضر في الطبيعةطبعا إذا كانت لا
+
+505
+00:42:44,590 --> 00:42:51,850
+تحضر في الطبيعة بده يجعب هذه المشكلة و يطلع عنده
+
+506
+00:42:51,850 --> 00:42:56,450
+خليط من التنين عشان ايه كده في الكيميا بيسموه ايش
+
+507
+00:42:56,450 --> 00:43:02,990
+Symmetric Synthesis Symmetric Synthesis ايش معنى
+
+508
+00:43:02,990 --> 00:43:08,350
+Symmetric انه بيطلع خليط متمافل من التنين جد بعض و
+
+509
+00:43:08,350 --> 00:43:15,290
+بعدين يقعد ايش يعمليفصل فيهم الآن بدأوا من جديد
+
+510
+00:43:15,290 --> 00:43:21,030
+يستعملوا طرق حديثة في ال synthesis و يضيفوا عوامل
+
+511
+00:43:21,030 --> 00:43:25,330
+حفازة اللي تخلى واحد من هدول يطلع بنسبة اكتر من
+
+512
+00:43:25,330 --> 00:43:30,490
+التانية او يكاد يكون يطلع نقي وجدتها اذا طلعوا مش
+
+513
+00:43:30,490 --> 00:43:35,790
+متساويات شو بدى اسم ال synthesis Asymmetric
+
+514
+00:43:35,790 --> 00:43:40,010
+synthesisواضح؟ يعني الـ symmetric synthesis بتطلع
+
+515
+00:43:40,010 --> 00:43:44,810
+الخليط متساوي الآن إذا صرت أضيف عوامل حفازة بطرق
+
+516
+00:43:44,810 --> 00:43:49,290
+معينة بتحذيرات بصير أشتغل ايش؟ asymmetric
+
+517
+00:43:49,290 --> 00:43:52,910
+synthesis اليوم اللي منكم بده تدرس كيميا وبعدين
+
+518
+00:43:52,910 --> 00:43:57,120
+تقول أنا بدي أخد جائزة نوبل في الكيمياBye Bye
+
+519
+00:43:57,120 --> 00:44:01,260
+Asymmetric Synthesis بدا تشتغل على ايش؟ Asymmetric
+
+520
+00:44:01,260 --> 00:44:05,420
+Synthesis تصير تتعلم كتير تضيف عوامل حفازة
+
+521
+00:44:05,420 --> 00:44:12,040
+بمواصفات معينة تخلي التفاعل تطلع واحدمايطلعش
+
+522
+00:44:12,040 --> 00:44:16,200
+التاني او طلع واحد مثلا بنسبة 90% و التاني بنسبة
+
+523
+00:44:16,200 --> 00:44:20,800
+10% على سبيل المثال و كل ما جدت تطلع واحد تماما و
+
+524
+00:44:20,800 --> 00:44:26,500
+تلغي التاني كل ما كانت تمثل ايش نجاح كبير في الشغل
+
+525
+00:44:26,500 --> 00:44:31,720
+افهمنا اذا المشكلة ما بين الطبيعة و ما بين المختبر
+
+526
+00:44:31,720 --> 00:44:36,380
+المختبر هو وضع الطبيعيبطلّع لي خليط الطبيعة بوضعها
+
+527
+00:44:36,380 --> 00:44:42,120
+الطبيعي بطلّع واحد الان العالم بيسعوا نحو ايش؟ ان
+
+528
+00:44:42,120 --> 00:44:45,960
+يقتربوا من الطبيعة انهم يقدروا يطلعوا واحد و لو
+
+529
+00:44:45,960 --> 00:44:51,120
+بنسبة كبيرة في ما يسمى بالعلم ايش؟ asymmetric
+
+530
+00:44:51,120 --> 00:44:55,620
+synthesis بس بالتأكيد هذا الموضوع كتير متطور
+
+531
+00:44:55,620 --> 00:44:59,860
+بالنسبة لطالب organic يعني ما لم تتخصصوا كيميا مش
+
+532
+00:44:59,860 --> 00:45:02,460
+هتشتغلوا فيه بنكمل ان شاء الله في مرات
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/2vgDME64dpU_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/2vgDME64dpU_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..a5ae737f15baa5f3e34d6727b9022160a3112579
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/2vgDME64dpU_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2775, "start": 19.59, "end": 27.75, "text": "بسم الله الرحمن الرحيم في موضوع الفصل التاسع ال aldehydes و ال ketones اعطينا المرة الماضية", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 8978, 3714, 2407, 11242, 45367, 27188, 36520, 16712, 32277, 3615, 2423, 16798, 68, 3495, 14792, 4032, 2423, 14979, 2213, 1975, 3615, 9566, 1829, 8315, 9673, 25720, 9673, 46958, 10632], "avg_logprob": -0.12890624465086523, "compression_ratio": 1.3482142857142858, "no_speech_prob": 0.0, "words": [{"start": 19.59, "end": 20.09, "word": "بسم", "probability": 0.90380859375}, {"start": 20.09, "end": 20.25, "word": " الله", "probability": 0.9599609375}, {"start": 20.25, "end": 20.65, "word": " الرحمن", "probability": 0.9833984375}, {"start": 20.65, "end": 21.15, "word": " الرحيم", "probability": 0.9949544270833334}, {"start": 21.15, "end": 22.41, "word": " في", "probability": 0.477294921875}, {"start": 22.41, "end": 23.07, "word": " موضوع", "probability": 0.97216796875}, {"start": 23.07, "end": 23.69, "word": " الفصل", "probability": 0.906494140625}, {"start": 23.69, "end": 24.41, "word": " التاسع", "probability": 0.97998046875}, {"start": 24.41, "end": 24.93, "word": " ال", "probability": 0.8427734375}, {"start": 24.93, "end": 25.53, "word": " aldehydes", "probability": 0.780517578125}, {"start": 25.53, "end": 25.67, "word": " و", "probability": 0.5380859375}, {"start": 25.67, "end": 25.73, "word": " ال", "probability": 0.77587890625}, {"start": 25.73, "end": 26.29, "word": " ketones", "probability": 0.837158203125}, {"start": 26.29, "end": 26.83, "word": " اعطينا", "probability": 0.85595703125}, {"start": 26.83, "end": 27.17, "word": " المرة", "probability": 0.966552734375}, {"start": 27.17, "end": 27.75, "word": " الماضية", "probability": 0.9928385416666666}], "temperature": 1.0}, {"id": 2, "seek": 5267, "start": 29.13, "end": 52.67, "text": "مقدمة، إيش معناه ال carbonyl compounds؟ ليش قسمناهم لصنفين أساسيين؟ يعني ليش حاطينا ال aldehydes و ال ketones لحال و الأحماض و مشتقاتها لحال؟ السبب يعود لطبيعة التفاعل الكيميائي اللي هم ال aldehydes و ال ketones بتفاعلوا بالإضافة، الأحماض و مشتقاتها بتفاعلوا", "tokens": [2304, 28543, 46007, 12399, 11933, 1829, 8592, 20449, 8315, 3224, 2423, 12143, 2526, 75, 21810, 22807, 32239, 8592, 12174, 38251, 8315, 16095, 5296, 9381, 1863, 5172, 9957, 5551, 3794, 32277, 1829, 9957, 22807, 37495, 22653, 32239, 8592, 11331, 41193, 1829, 8315, 2423, 16798, 68, 3495, 14792, 4032, 2423, 14979, 2213, 5296, 5016, 6027, 4032, 16247, 35571, 46958, 4032, 37893, 2655, 4587, 9307, 11296, 5296, 5016, 6027, 22807, 21136, 3555, 3555, 37495, 23328, 5296, 9566, 21292, 27884, 16712, 5172, 995, 30241, 33251, 32640, 1829, 16373, 1829, 13672, 1829, 8032, 2304, 2423, 16798, 68, 3495, 14792, 4032, 2423, 14979, 2213, 39894, 5172, 995, 30241, 14407, 20666, 28814, 11242, 31845, 3660, 12399, 16247, 35571, 46958, 4032, 37893, 2655, 4587, 9307, 11296, 39894, 5172, 995, 30241, 14407], "avg_logprob": 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أسمي", "probability": 0.95947265625}, {"start": 133.43, "end": 134.01, "word": " واحد،", "probability": 0.7215983072916666}, {"start": 134.01, "end": 134.59, "word": " اتنين،", "probability": 0.94658203125}, {"start": 134.59, "end": 135.63, "word": " تلاتة،", "probability": 0.93955078125}, {"start": 135.63, "end": 135.77, "word": " شو", "probability": 0.884521484375}, {"start": 135.77, "end": 136.01, "word": " بدأ", "probability": 0.6846923828125}, {"start": 136.01, "end": 136.47, "word": " أسمي", "probability": 0.9208984375}, {"start": 136.47, "end": 136.71, "word": " هذا", "probability": 0.984375}, {"start": 136.71, "end": 136.91, "word": " الـ", "probability": 0.5689697265625}, {"start": 136.91, "end": 138.75, "word": " Ketone؟", "probability": 0.67926025390625}, {"start": 138.75, "end": 139.65, "word": " Iprobanone", "probability": 0.59674072265625}, {"start": 139.65, "end": 140.29, "word": " على", "probability": 0.6748046875}, {"start": 140.29, "end": 140.61, "word": " نمرة", 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"text": "الان لو كنا بنسمي فيه ال common nomenclature وبنعبر عن البروم هنا بنعبرش بنظام الترقيم هذا لأ بنيجي بنقول والله الموقع الأول بعد ال c double bond o بنعطيه alpha الموقع اللي بعده beta الموقع اللي بعده gamma و هكذا فلاحظوا ان الموقع alpha بالنسبة ل c double bond o هو موقع ايش", "tokens": [6027, 7649, 45164, 9122, 8315, 44945, 38251, 1829, 8978, 3224, 2423, 2689, 297, 4726, 3474, 1503, 46599, 1863, 3615, 3555, 2288, 18871, 2423, 26890, 20498, 34105, 44945, 3615, 3555, 2288, 8592, 44945, 19913, 10943, 16712, 2288, 4587, 32640, 23758, 5296, 10721, 44945, 1829, 7435, 1829, 44945, 39648, 16070, 43761, 9673, 30543, 3615, 16247, 12610, 39182, 2423, 269, 3834, 6086, 277, 44945, 3615, 9566, 1829, 3224, 8961, 9673, 30543, 3615, 13672, 1829, 39182, 3224, 9861, 9673, 30543, 3615, 13672, 1829, 39182, 3224, 15546, 4032, 8032, 4117, 15730, 6156, 15040, 5016, 19913, 14407, 16472, 9673, 30543, 3615, 8961, 20666, 1863, 35457, 3660, 5296, 269, 3834, 6086, 277, 31439, 3714, 30543, 3615, 1975, 1829, 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البروم", "probability": 0.58544921875}, {"start": 808.79, "end": 809.19, "word": " هنا", "probability": 0.83544921875}, {"start": 809.19, "end": 810.27, "word": " بنعبرش", "probability": 0.7341796875}, {"start": 810.27, "end": 810.79, "word": " بنظام", "probability": 0.9031575520833334}, {"start": 810.79, "end": 811.39, "word": " الترقيم", "probability": 0.9791259765625}, {"start": 811.39, "end": 811.65, "word": " هذا", "probability": 0.83935546875}, {"start": 811.65, "end": 811.85, "word": " لأ", "probability": 0.781005859375}, {"start": 811.85, "end": 812.25, "word": " بنيجي", "probability": 0.8148193359375}, {"start": 812.25, "end": 812.81, "word": " بنقول", "probability": 0.92578125}, {"start": 812.81, "end": 813.53, "word": " والله", "probability": 0.779541015625}, {"start": 813.53, "end": 814.83, "word": " الموقع", "probability": 0.9814453125}, {"start": 814.83, "end": 815.81, "word": " الأول", "probability": 0.86865234375}, {"start": 815.81, "end": 816.87, "word": " بعد", "probability": 0.92626953125}, {"start": 816.87, "end": 817.25, "word": " ال", "probability": 0.57861328125}, {"start": 817.25, "end": 817.39, "word": " c", "probability": 0.23779296875}, {"start": 817.39, "end": 817.59, "word": " double", "probability": 0.4384765625}, {"start": 817.59, "end": 817.95, "word": " bond", "probability": 0.89013671875}, {"start": 817.95, "end": 818.09, "word": " o", "probability": 0.76220703125}, {"start": 818.09, "end": 818.71, "word": " بنعطيه", "probability": 0.9353515625}, {"start": 818.71, "end": 819.15, "word": " alpha", "probability": 0.388427734375}, {"start": 819.15, "end": 820.03, "word": " الموقع", "probability": 0.9768880208333334}, {"start": 820.03, "end": 820.23, "word": " اللي", "probability": 0.9111328125}, {"start": 820.23, "end": 820.81, "word": " بعده", "probability": 0.9482421875}, {"start": 820.81, "end": 821.41, "word": " beta", "probability": 0.298095703125}, {"start": 821.41, "end": 821.87, "word": " الموقع", "probability": 0.9462890625}, {"start": 821.87, "end": 822.09, "word": " اللي", "probability": 0.987060546875}, {"start": 822.09, "end": 822.55, "word": " بعده", "probability": 0.953857421875}, {"start": 822.55, "end": 823.53, "word": " gamma", "probability": 0.7802734375}, {"start": 823.53, "end": 823.69, "word": " و", "probability": 0.65234375}, {"start": 823.69, "end": 824.19, "word": " هكذا", "probability": 0.7735188802083334}, {"start": 824.19, "end": 825.39, "word": " فلاحظوا", "probability": 0.98837890625}, {"start": 825.39, "end": 825.57, "word": " ان", "probability": 0.5830078125}, {"start": 825.57, "end": 826.29, "word": " الموقع", "probability": 0.9412434895833334}, {"start": 826.29, "end": 826.91, "word": " alpha", "probability": 0.383056640625}, {"start": 826.91, "end": 828.01, "word": " بالنسبة", "probability": 0.977294921875}, {"start": 828.01, "end": 828.13, "word": " ل", "probability": 0.65087890625}, {"start": 828.13, "end": 828.35, "word": " c", "probability": 0.495361328125}, {"start": 828.35, "end": 828.57, "word": " double", "probability": 0.90869140625}, {"start": 828.57, "end": 828.95, "word": " bond", "probability": 0.974609375}, {"start": 828.95, "end": 829.33, "word": " o", "probability": 0.93212890625}, {"start": 829.33, "end": 829.77, "word": " هو", "probability": 0.986328125}, {"start": 829.77, "end": 830.25, "word": " موقع", "probability": 0.9874674479166666}, {"start": 830.25, "end": 830.63, "word": " ايش", "probability": 0.8214518229166666}], "temperature": 1.0}, {"id": 36, "seek": 85310, "start": 831.36, "end": 853.1, "text": "إتنين فلو هذا أنا بدي أسميه butyraldehyde البرومو أين جاية عليه؟ على Alpha فأنا بدي أجي أقول عنه Alpha Bromo يعني البرومو جاية على موقع Alpha Butyraldehyde واضح الفكرة؟", "tokens": [28814, 2655, 1863, 9957, 6156, 1211, 2407, 23758, 41850, 4724, 16254, 5551, 38251, 1829, 3224, 457, 88, 2155, 1479, 3495, 1479, 2423, 26890, 20498, 2407, 5551, 9957, 10874, 995, 10632, 47356, 22807, 15844, 20588, 6156, 10721, 8315, 4724, 16254, 5551, 7435, 1829, 5551, 39648, 18871, 3224, 20588, 1603, 13395, 37495, 22653, 2423, 26890, 20498, 2407, 10874, 995, 10632, 15844, 3714, 30543, 3615, 20588, 583, 88, 2155, 1479, 3495, 1479, 4032, 46958, 5016, 27188, 4117, 25720, 22807], "avg_logprob": -0.2242288937816372, "compression_ratio": 1.5688622754491017, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 831.36, "end": 832.08, "word": "إتنين", "probability": 0.73944091796875}, {"start": 832.08, "end": 832.72, "word": " فلو", "probability": 0.8162434895833334}, {"start": 832.72, "end": 832.96, "word": " هذا", "probability": 0.92138671875}, {"start": 832.96, "end": 833.12, "word": " أنا", "probability": 0.5224609375}, {"start": 833.12, "end": 833.3, "word": " بدي", "probability": 0.5960693359375}, {"start": 833.3, "end": 833.7, "word": " أسميه", "probability": 0.852783203125}, {"start": 833.7, "end": 835.44, "word": " butyraldehyde", "probability": 0.8474527994791666}, {"start": 835.44, "end": 837.52, "word": " البرومو", "probability": 0.694580078125}, {"start": 837.52, "end": 837.7, "word": " أين", "probability": 0.7052001953125}, {"start": 837.7, "end": 838.08, "word": " جاية", "probability": 0.8527018229166666}, {"start": 838.08, "end": 839.32, "word": " عليه؟", "probability": 0.64306640625}, {"start": 839.32, "end": 839.54, "word": " على", "probability": 0.8720703125}, {"start": 839.54, "end": 840.02, "word": " Alpha", "probability": 0.3056640625}, {"start": 840.02, "end": 840.62, "word": " فأنا", "probability": 0.8470052083333334}, {"start": 840.62, "end": 840.88, "word": " بدي", "probability": 0.938720703125}, {"start": 840.88, "end": 841.12, "word": " أجي", "probability": 0.9147135416666666}, {"start": 841.12, "end": 841.44, "word": " أقول", "probability": 0.9052734375}, {"start": 841.44, "end": 841.82, "word": " عنه", "probability": 0.95361328125}, {"start": 841.82, "end": 842.48, "word": " Alpha", "probability": 0.87353515625}, {"start": 842.48, "end": 843.58, "word": " Bromo", "probability": 0.50775146484375}, {"start": 843.58, "end": 843.86, "word": " يعني", "probability": 0.919189453125}, {"start": 843.86, "end": 844.5, "word": " البرومو", "probability": 0.9652099609375}, {"start": 844.5, "end": 845.0, "word": " جاية", "probability": 0.9879557291666666}, {"start": 845.0, "end": 845.58, "word": " على", "probability": 0.96337890625}, {"start": 845.58, "end": 846.02, "word": " موقع", "probability": 0.9820963541666666}, {"start": 846.02, "end": 846.46, "word": " Alpha", "probability": 0.97265625}, {"start": 846.46, "end": 849.72, "word": " Butyraldehyde", "probability": 0.93017578125}, {"start": 849.72, "end": 852.18, "word": " واضح", "probability": 0.9552408854166666}, {"start": 852.18, "end": 853.1, "word": " الفكرة؟", "probability": 0.8848876953125}], "temperature": 1.0}, {"id": 37, "seek": 87984, "start": 853.62, "end": 879.84, "text": "فإذا استعملنا لوصف المواقع الجانب السيضة بالـ bond O Alpha و Beta و Gamma أو كان عندي أي شغل هان بقول هي بالنسبة للسيضة بال bond O بنظام ال أيوبك على موقع اتنين بنظام ال common موقع اتنين بيكون موقع Alpha مش Beta يعني مابنجيش نحط Alpha هان و Beta هان لأ ال Alpha هي موقع اتنين", "tokens": [5172, 28814, 15730, 44713, 25957, 1211, 8315, 5296, 2407, 9381, 5172, 9673, 14407, 4587, 3615, 25724, 7649, 3555, 21136, 1829, 11242, 3660, 20666, 39184, 6086, 422, 20588, 4032, 33286, 4032, 24723, 1696, 34051, 25961, 18871, 16254, 36632, 13412, 17082, 1211, 8032, 7649, 4724, 39648, 39896, 20666, 1863, 35457, 3660, 24976, 3794, 1829, 11242, 3660, 20666, 6086, 422, 44945, 19913, 10943, 2423, 36632, 37746, 4117, 15844, 3714, 30543, 3615, 1975, 2655, 1863, 9957, 44945, 19913, 10943, 2423, 2689, 3714, 30543, 3615, 1975, 2655, 1863, 9957, 4724, 1829, 30544, 3714, 30543, 3615, 20588, 37893, 33286, 37495, 22653, 3714, 16758, 1863, 7435, 1829, 8592, 8717, 5016, 9566, 20588, 8032, 7649, 4032, 33286, 8032, 7649, 5296, 10721, 2423, 20588, 39896, 3714, 30543, 3615, 1975, 2655, 1863, 9957], "avg_logprob": -0.18447580789366075, "compression_ratio": 1.893162393162393, "no_speech_prob": 0.0, "words": [{"start": 853.62, "end": 854.26, "word": "فإذا", "probability": 0.7569986979166666}, {"start": 854.26, "end": 855.22, "word": " استعملنا", "probability": 0.94482421875}, {"start": 855.22, "end": 855.92, "word": " لوصف", "probability": 0.8499755859375}, {"start": 855.92, "end": 856.62, "word": " المواقع", "probability": 0.98974609375}, {"start": 856.62, "end": 857.12, "word": " الجانب", "probability": 0.6393229166666666}, {"start": 857.12, "end": 857.56, "word": " السيضة", "probability": 0.63531494140625}, {"start": 857.56, "end": 857.76, "word": " بالـ", "probability": 0.587890625}, {"start": 857.76, "end": 857.98, "word": " bond", "probability": 0.38623046875}, {"start": 857.98, "end": 858.34, "word": " O", "probability": 0.58056640625}, {"start": 858.34, "end": 858.94, "word": " Alpha", "probability": 0.403564453125}, {"start": 858.94, "end": 859.2, "word": " و", "probability": 0.896484375}, {"start": 859.2, "end": 859.54, "word": " Beta", "probability": 0.69091796875}, {"start": 859.54, "end": 859.78, "word": " و", "probability": 0.98193359375}, {"start": 859.78, "end": 860.48, "word": " Gamma", "probability": 0.761962890625}, {"start": 860.48, "end": 860.62, "word": " أو", "probability": 0.7763671875}, {"start": 860.62, "end": 860.86, "word": " كان", "probability": 0.9716796875}, {"start": 860.86, "end": 861.1, "word": " عندي", "probability": 0.74658203125}, {"start": 861.1, "end": 861.3, "word": " أي", "probability": 0.83740234375}, {"start": 861.3, "end": 861.68, "word": " شغل", "probability": 0.95556640625}, {"start": 861.68, "end": 861.84, "word": " هان", "probability": 0.685791015625}, {"start": 861.84, "end": 862.2, "word": " بقول", "probability": 0.83203125}, {"start": 862.2, "end": 862.42, "word": " هي", "probability": 0.77783203125}, {"start": 862.42, "end": 862.98, "word": " بالنسبة", "probability": 0.9892578125}, {"start": 862.98, "end": 863.42, "word": " للسيضة", "probability": 0.88671875}, {"start": 863.42, "end": 863.54, "word": " بال", "probability": 0.96337890625}, {"start": 863.54, "end": 863.82, "word": " bond", "probability": 0.7431640625}, {"start": 863.82, "end": 864.22, "word": " O", "probability": 0.94873046875}, {"start": 864.22, "end": 865.24, "word": " بنظام", "probability": 0.9430338541666666}, {"start": 865.24, "end": 865.38, "word": " ال", "probability": 0.904296875}, {"start": 865.38, "end": 865.88, "word": " أيوبك", "probability": 0.6593424479166666}, {"start": 865.88, "end": 866.08, "word": " على", "probability": 0.8349609375}, {"start": 866.08, "end": 866.68, "word": " موقع", "probability": 0.9840494791666666}, {"start": 866.68, "end": 868.06, "word": " اتنين", "probability": 0.9053955078125}, {"start": 868.06, "end": 868.86, "word": " بنظام", "probability": 0.8841145833333334}, {"start": 868.86, "end": 869.02, "word": " ال", "probability": 0.95068359375}, {"start": 869.02, "end": 869.36, "word": " common", "probability": 0.93212890625}, {"start": 869.36, "end": 869.9, "word": " موقع", "probability": 0.9580078125}, {"start": 869.9, "end": 870.32, "word": " اتنين", "probability": 0.98828125}, {"start": 870.32, "end": 870.64, "word": " بيكون", "probability": 0.8834635416666666}, {"start": 870.64, "end": 871.1, "word": " موقع", "probability": 0.9619140625}, {"start": 871.1, "end": 872.26, "word": " Alpha", "probability": 0.485595703125}, {"start": 872.26, "end": 872.76, "word": " مش", "probability": 0.9189453125}, {"start": 872.76, "end": 873.9, "word": " Beta", "probability": 0.7451171875}, {"start": 873.9, "end": 874.56, "word": " يعني", "probability": 0.9326171875}, {"start": 874.56, "end": 875.1, "word": " مابنجيش", "probability": 0.9232584635416666}, {"start": 875.1, "end": 875.44, "word": " نحط", "probability": 0.8704427083333334}, {"start": 875.44, "end": 875.88, "word": " Alpha", "probability": 0.9443359375}, {"start": 875.88, "end": 876.42, "word": " هان", "probability": 0.80712890625}, {"start": 876.42, "end": 876.72, "word": " و", "probability": 0.96923828125}, {"start": 876.72, "end": 877.04, "word": " Beta", "probability": 0.79736328125}, {"start": 877.04, "end": 877.58, "word": " هان", "probability": 0.88916015625}, {"start": 877.58, "end": 877.98, "word": " لأ", "probability": 0.91796875}, {"start": 877.98, "end": 878.18, "word": " ال", "probability": 0.953125}, {"start": 878.18, "end": 878.66, "word": " Alpha", "probability": 0.84375}, {"start": 878.66, "end": 879.06, "word": " هي", "probability": 0.9013671875}, {"start": 879.06, "end": 879.46, "word": " موقع", "probability": 0.9949544270833334}, {"start": 879.46, "end": 879.84, "word": " اتنين", "probability": 0.98828125}], "temperature": 1.0}, {"id": 38, "seek": 89504, "start": 880.38, "end": 895.04, "text": "وبنمشي ولذلك هذا المركب مثلا واحد اتنين تلاتة حامل OH بال .. بال IUPAC Nomenclature three hydroxybutanol في اي مشكلة؟ three hydroxybutanol", "tokens": [37746, 1863, 2304, 8592, 1829, 4032, 1211, 8848, 23275, 23758, 9673, 31747, 3555, 50113, 15040, 36764, 24401, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 11331, 10943, 1211, 13931, 20666, 4386, 20666, 286, 22917, 4378, 426, 4726, 3474, 1503, 1045, 15435, 12876, 5955, 282, 401, 8978, 1975, 1829, 37893, 28820, 3660, 22807, 1045, 15435, 12876, 5955, 282, 401], "avg_logprob": -0.31514829195151894, "compression_ratio": 1.2564102564102564, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 880.38, "end": 881.18, "word": "وبنمشي", "probability": 0.79169921875}, {"start": 881.18, "end": 882.04, "word": " ولذلك", "probability": 0.70855712890625}, {"start": 882.04, "end": 882.36, "word": " هذا", "probability": 0.93896484375}, {"start": 882.36, "end": 883.08, "word": " المركب", "probability": 0.818359375}, {"start": 883.08, "end": 883.56, "word": " مثلا", "probability": 0.95458984375}, {"start": 883.56, "end": 884.02, "word": " واحد", "probability": 0.7386474609375}, {"start": 884.02, "end": 884.4, "word": " اتنين", "probability": 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{"start": 891.46, "end": 892.94, "word": " مشكلة؟", "probability": 0.86138916015625}, {"start": 892.94, "end": 893.76, "word": " three", "probability": 0.59423828125}, {"start": 893.76, "end": 895.04, "word": " hydroxybutanol", "probability": 0.95732421875}], "temperature": 1.0}, {"id": 39, "seek": 92567, "start": 896.75, "end": 925.67, "text": "لو كنا بدنا نسميه ايش هنسميه هى Alpha هى Beta Beta-hydroxybutyraldehyde لاحظوا هذه اللى كتبناها EY butyraldehyde Beta فموقع اتنين بيكون Alpha موقع تلاتة بيكون Beta لو حد قرأ هالشغلة في يوم من الأيام مايستغربش يعني مايفكرش ان واحد هيكون Alpha اتنين Beta زى ما انتوا فاهمين لأ هو موقع اتنين", "tokens": [1211, 2407, 9122, 8315, 47525, 8315, 8717, 38251, 1829, 3224, 1975, 1829, 8592, 8032, 1863, 38251, 1829, 3224, 8032, 7578, 20588, 8032, 7578, 33286, 33286, 12, 21591, 340, 12876, 5955, 88, 2155, 1479, 3495, 1479, 5296, 39319, 19913, 14407, 29538, 13672, 7578, 9122, 2655, 3555, 8315, 11296, 462, 56, 457, 88, 2155, 1479, 3495, 1479, 33286, 6156, 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سكندر بيوت الـ Cyclopropane طيب الآن هنا اعتبرنا الأساس إيش؟ الـ Cyclopropane هل يا تورا ممكن أننا نعتبر الأساس السلسلة؟ أكيد لما نعتبر الأساس السلسلة، شو هنقول؟ البيوتين على نمرأ اتنين من البيوتين، إيش عندكم؟ Cyclopropane", "tokens": [47283, 3215, 2655, 2407, 11296, 4724, 2407, 11242, 2407, 5016, 10874, 28259, 8608, 19452, 3215, 2288, 4724, 1829, 35473, 2423, 39184, 49173, 404, 1513, 1929, 23032, 1829, 3555, 6024, 48506, 34105, 1975, 34268, 26890, 8315, 16247, 3794, 32277, 11933, 1829, 8592, 22807, 2423, 39184, 49173, 404, 1513, 1929, 8032, 1211, 35186, 6055, 13063, 995, 3714, 43020, 14739, 8315, 8717, 34268, 26890, 16247, 3794, 32277, 21136, 1211, 3794, 37977, 22807, 5551, 4117, 25708, 5296, 15042, 8717, 34268, 26890, 16247, 3794, 32277, 21136, 1211, 3794, 37977, 12399, 13412, 2407, 8032, 1863, 39648, 22807, 2423, 21292, 35473, 9957, 15844, 8717, 29973, 10721, 1975, 2655, 1863, 9957, 9154, 2423, 21292, 35473, 9957, 12399, 11933, 1829, 8592, 43242, 24793, 22807, 49173, 404, 1513, 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1181.74, "word": " اعتبرنا", "probability": 0.9605712890625}, {"start": 1181.74, "end": 1182.38, "word": " الأساس", "probability": 0.9305013020833334}, {"start": 1182.38, "end": 1183.3, "word": " إيش؟", "probability": 0.74371337890625}, {"start": 1183.3, "end": 1183.5, "word": " الـ", "probability": 0.6083984375}, {"start": 1183.5, "end": 1185.02, "word": " Cyclopropane", "probability": 0.9427490234375}, {"start": 1185.02, "end": 1185.56, "word": " هل", "probability": 0.884765625}, {"start": 1185.56, "end": 1185.74, "word": " يا", "probability": 0.921875}, {"start": 1185.74, "end": 1186.16, "word": " تورا", "probability": 0.7688802083333334}, {"start": 1186.16, "end": 1186.86, "word": " ممكن", "probability": 0.975341796875}, {"start": 1186.86, "end": 1187.24, "word": " أننا", "probability": 0.5341796875}, {"start": 1187.24, "end": 1187.96, "word": " نعتبر", "probability": 0.9930013020833334}, {"start": 1187.96, "end": 1189.44, "word": " الأساس", "probability": 0.9537760416666666}, {"start": 1189.44, "end": 1191.28, "word": " السلسلة؟", "probability": 0.91728515625}, {"start": 1191.28, "end": 1192.2, "word": " أكيد", "probability": 0.9573567708333334}, {"start": 1192.2, "end": 1192.68, "word": " لما", "probability": 0.793212890625}, {"start": 1192.68, "end": 1193.22, "word": " نعتبر", "probability": 0.99462890625}, {"start": 1193.22, "end": 1193.74, "word": " الأساس", "probability": 0.9777018229166666}, {"start": 1193.74, "end": 1194.72, "word": " السلسلة،", "probability": 0.881640625}, {"start": 1194.72, "end": 1194.88, "word": " شو", "probability": 0.927978515625}, {"start": 1194.88, "end": 1196.04, "word": " هنقول؟", "probability": 0.94580078125}, {"start": 1196.04, "end": 1197.46, "word": " البيوتين", "probability": 0.82623291015625}, {"start": 1197.46, "end": 1199.28, "word": " على", "probability": 0.75634765625}, {"start": 1199.28, "end": 1199.9, "word": " نمرأ", "probability": 0.7703450520833334}, {"start": 1199.9, "end": 1200.66, "word": " اتنين", "probability": 0.8958740234375}, {"start": 1200.66, "end": 1200.9, "word": " من", "probability": 0.9951171875}, {"start": 1200.9, "end": 1201.8, "word": " البيوتين،", "probability": 0.9421875}, {"start": 1201.8, "end": 1202.0, "word": " إيش", "probability": 0.9363606770833334}, {"start": 1202.0, "end": 1202.76, "word": " عندكم؟", "probability": 0.982421875}, {"start": 1202.76, "end": 1204.02, "word": " Cyclopropane", "probability": 0.871826171875}], "temperature": 1.0}, {"id": 51, "seek": 122129, "start": 1204.89, "end": 1221.29, "text": "لحتى الآن مش عمال تقدروا تذكرواها بإنصيغة مجموعة بزام Cyclopropane لما يصير مجموعة شو هيصير؟ Cyclopropane اذا اتنين Cyclopropane", "tokens": [1211, 33753, 7578, 6024, 48506, 37893, 6225, 2304, 6027, 6055, 28543, 2288, 14407, 6055, 8848, 37983, 14407, 11296, 4724, 28814, 1863, 9381, 1829, 17082, 3660, 3714, 7435, 2304, 2407, 27884, 4724, 11622, 10943, 49173, 404, 1513, 1929, 5296, 15042, 7251, 9381, 13546, 3714, 7435, 2304, 2407, 27884, 13412, 2407, 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0.5826822916666666}, {"start": 1210.87, "end": 1212.23, "word": " Cyclopropane", "probability": 0.69671630859375}, {"start": 1212.23, "end": 1212.57, "word": " لما", "probability": 0.9267578125}, {"start": 1212.57, "end": 1212.95, "word": " يصير", "probability": 0.9778645833333334}, {"start": 1212.95, "end": 1213.65, "word": " مجموعة", "probability": 0.96708984375}, {"start": 1213.65, "end": 1213.87, "word": " شو", "probability": 0.83740234375}, {"start": 1213.87, "end": 1215.03, "word": " هيصير؟", "probability": 0.8182373046875}, {"start": 1215.03, "end": 1217.31, "word": " Cyclopropane", "probability": 0.88232421875}, {"start": 1217.31, "end": 1217.75, "word": " اذا", "probability": 0.43212890625}, {"start": 1217.75, "end": 1218.55, "word": " اتنين", "probability": 0.903076171875}, {"start": 1218.55, "end": 1221.29, "word": " Cyclopropane", "probability": 0.809326171875}], "temperature": 1.0}, {"id": 52, "seek": 124433, "start": 1223.62, "end": 1244.34, "text": "واضح؟ فالسكندري بيوت ال cyclopropane هو نفسه اتنين cyclopropyl butane يعني انا لما اجيت اسميه .. انا لما اجيت اسميه .. قولت يا تورا بدي اخلي مرجعيتي الحلقة ولا اخلي مرجعيتي ايش؟", "tokens": [2407, 46958, 5016, 22807, 6156, 6027, 3794, 19452, 3215, 2288, 1829, 4724, 1829, 35473, 2423, 19474, 404, 1513, 1929, 31439, 8717, 36178, 3224, 1975, 2655, 1863, 9957, 19474, 404, 1513, 5088, 457, 1929, 37495, 22653, 1975, 8315, 5296, 15042, 1975, 7435, 36081, 24525, 2304, 1829, 3224, 4386, 1975, 8315, 5296, 15042, 1975, 7435, 36081, 24525, 2304, 1829, 3224, 4386, 12174, 12610, 2655, 35186, 6055, 13063, 995, 4724, 16254, 1975, 9778, 20292, 3714, 47341, 3615, 1829, 31371, 21542, 1211, 28671, 49429, 1975, 9778, 20292, 3714, 47341, 3615, 1829, 31371, 1975, 1829, 8592, 22807], "avg_logprob": -0.19506048066641696, "compression_ratio": 1.7159763313609468, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1223.62, "end": 1224.54, "word": "واضح؟", "probability": 0.8824462890625}, {"start": 1224.54, "end": 1225.62, "word": " فالسكندري", "probability": 0.794677734375}, {"start": 1225.62, "end": 1226.02, "word": " بيوت", "probability": 0.8990885416666666}, {"start": 1226.02, "end": 1226.28, "word": " ال", "probability": 0.76318359375}, {"start": 1226.28, "end": 1228.22, "word": " cyclopropane", "probability": 0.72235107421875}, {"start": 1228.22, "end": 1228.74, "word": " هو", "probability": 0.98388671875}, {"start": 1228.74, "end": 1229.7, "word": " نفسه", "probability": 0.99609375}, {"start": 1229.7, "end": 1230.42, "word": " اتنين", "probability": 0.9351806640625}, {"start": 1230.42, "end": 1231.86, "word": " cyclopropyl", "probability": 0.758056640625}, {"start": 1231.86, "end": 1232.64, "word": " butane", "probability": 0.6990966796875}, {"start": 1232.64, "end": 1233.2, "word": " يعني", "probability": 0.869384765625}, {"start": 1233.2, "end": 1233.52, "word": " انا", "probability": 0.782470703125}, {"start": 1233.52, "end": 1233.76, "word": " لما", "probability": 0.934326171875}, {"start": 1233.76, "end": 1234.22, "word": " اجيت", "probability": 0.8492838541666666}, {"start": 1234.22, "end": 1235.22, "word": " اسميه", "probability": 0.8470458984375}, {"start": 1235.22, "end": 1235.22, "word": " ..", "probability": 0.6240234375}, {"start": 1235.22, "end": 1235.46, "word": " انا", "probability": 0.878662109375}, {"start": 1235.46, "end": 1235.64, "word": " لما", "probability": 0.989990234375}, {"start": 1235.64, "end": 1236.0, "word": " اجيت", "probability": 0.9856770833333334}, {"start": 1236.0, "end": 1236.88, "word": " اسميه", "probability": 0.9793701171875}, {"start": 1236.88, "end": 1236.98, "word": " ..", "probability": 0.432373046875}, {"start": 1236.98, "end": 1237.3, "word": " قولت", "probability": 0.8235677083333334}, {"start": 1237.3, "end": 1237.42, "word": " يا", "probability": 0.9130859375}, {"start": 1237.42, "end": 1237.76, "word": " تورا", "probability": 0.7556966145833334}, {"start": 1237.76, "end": 1238.2, "word": " بدي", "probability": 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0.8014322916666666}, {"start": 1391.67, "end": 1392.39, "word": " بيظل؟", "probability": 0.7947265625}], "temperature": 1.0}, {"id": 59, "seek": 141964, "start": 1394.34, "end": 1419.64, "text": "نذكرهم alphabetical نذكرهم alphabetical شوفتوا كيف بنسمي هذا النوع من المركبات إذا حيصير عندكم على سبيل المثال one bromine two cyclopropane three phenyl butane", "tokens": [1863, 8848, 37983, 16095, 23339, 804, 8717, 8848, 37983, 16095, 23339, 804, 13412, 38688, 2655, 14407, 9122, 33911, 44945, 38251, 1829, 23758, 28239, 45367, 9154, 9673, 31747, 3555, 9307, 11933, 15730, 11331, 1829, 9381, 13546, 43242, 24793, 15844, 8608, 21292, 1211, 9673, 12984, 6027, 472, 50134, 533, 732, 19474, 404, 1513, 1929, 1045, 7279, 5088, 457, 1929], "avg_logprob": -0.19733296822884988, "compression_ratio": 1.4049079754601228, "no_speech_prob": 0.0, "words": [{"start": 1394.3399999999997, "end": 1395.7199999999998, "word": "نذكرهم", "probability": 0.830322265625}, {"start": 1395.7199999999998, "end": 1397.1, 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1443.92, "text": "واضحت الفكرة تماما ولا فيها مشكلة الان طيب اذا هذا المثال دخل في ال behind او كيتون يعني افترض انه خلته زي هي", "tokens": [2407, 46958, 5016, 2655, 27188, 4117, 25720, 46811, 10943, 995, 49429, 8978, 11296, 37893, 28820, 3660, 2423, 7649, 23032, 1829, 3555, 1975, 15730, 23758, 9673, 12984, 6027, 11778, 9778, 1211, 8978, 2423, 2261, 1975, 2407, 9122, 36081, 11536, 37495, 22653, 1975, 5172, 2655, 43042, 16472, 3224, 16490, 1211, 47395, 30767, 1829, 39896], "avg_logprob": -0.22199292340368595, "compression_ratio": 1.4393939393939394, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1423.88, "end": 1424.38, "word": "واضحت", "probability": 0.7449951171875}, {"start": 1424.38, "end": 1424.82, "word": " الفكرة", "probability": 0.9915364583333334}, {"start": 1424.82, "end": 1429.06, "word": " تماما", "probability": 0.9905598958333334}, {"start": 1429.06, "end": 1430.12, "word": " ولا", "probability": 0.5673828125}, {"start": 1430.12, "end": 1430.38, "word": " 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"probability": 0.772705078125}, {"start": 2811.0, "end": 2811.14, "word": " و", "probability": 0.85546875}, {"start": 2811.14, "end": 2811.78, "word": " Sulphuric", "probability": 0.7913818359375}, {"start": 2811.78, "end": 2812.28, "word": " Acid", "probability": 0.754638671875}, {"start": 2812.28, "end": 2813.38, "word": " بيكسل", "probability": 0.747998046875}, {"start": 2813.38, "end": 2814.14, "word": " تفاعل", "probability": 0.85986328125}, {"start": 2814.14, "end": 2814.48, "word": " كتير", "probability": 0.9246419270833334}, {"start": 2814.48, "end": 2814.68, "word": " هذا", "probability": 0.5712890625}, {"start": 2814.68, "end": 2815.08, "word": " مهم", "probability": 0.9755859375}, {"start": 2815.08, "end": 2815.54, "word": " لسبب", "probability": 0.95947265625}, {"start": 2815.54, "end": 2815.9, "word": " بسيط", "probability": 0.9969482421875}, {"start": 2815.9, "end": 2816.1, "word": " انه", "probability": 0.73828125}, {"start": 2816.1, "end": 2816.5, "word": " بيعطي", 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"probability": 0.6563720703125}, {"start": 2822.52, "end": 2822.88, "word": " بتصير", "probability": 0.8719075520833334}, {"start": 2822.88, "end": 2823.68, "word": " CWO", "probability": 0.9293619791666666}, {"start": 2823.68, "end": 2824.42, "word": " الآن", "probability": 0.640380859375}, {"start": 2824.42, "end": 2824.78, "word": " هذا", "probability": 0.9267578125}, {"start": 2824.78, "end": 2825.24, "word": " الجزء", "probability": 0.98291015625}, {"start": 2825.24, "end": 2825.86, "word": " CH3", "probability": 0.95068359375}, {"start": 2825.86, "end": 2827.24, "word": " CH3", "probability": 0.72509765625}, {"start": 2827.24, "end": 2827.54, "word": " هو", "probability": 0.68115234375}, {"start": 2827.54, "end": 2828.04, "word": " ايش", "probability": 0.6817220052083334}, {"start": 2828.04, "end": 2828.84, "word": " ال", "probability": 0.78955078125}, {"start": 2828.84, "end": 2829.42, "word": " Acetone", "probability": 0.710205078125}, {"start": 2829.42, "end": 2829.88, "word": " هذا", "probability": 0.912109375}, {"start": 2829.88, "end": 2830.5, "word": " الجزء", "probability": 0.9931640625}, {"start": 2830.5, "end": 2831.9, "word": " بيحول", "probability": 0.9346923828125}, {"start": 2831.9, "end": 2832.5, "word": " الى", "probability": 0.614990234375}, {"start": 2832.5, "end": 2833.1, "word": " Enol", "probability": 0.6776123046875}, {"start": 2833.1, "end": 2833.66, "word": " بيصير", "probability": 0.8712158203125}, {"start": 2833.66, "end": 2834.46, "word": " Phenol", "probability": 0.9444986979166666}], "temperature": 1.0}, {"id": 119, "seek": 286387, "start": 2836.31, "end": 2863.87, "text": "فتفاعل الكيومين مع الأكسجين وحمض الكابريتيك إيش بيعطينا؟ Phenol and Acetone يعني لو بدنا نسألكوا reaction of الكيومين with أكسجين و presence of sulphuric acid بطريقة معينة produces Phenol and Acetone و هدولة المركبين إيش مالهم؟ مركبات مهمة جدا في ال organ الchemistry", "tokens": [5172, 2655, 5172, 995, 30241, 33251, 1829, 20498, 9957, 20449, 16247, 4117, 3794, 7435, 9957, 4032, 35571, 11242, 33251, 16758, 16572, 31371, 4117, 11933, 1829, 8592, 4724, 40228, 9566, 1829, 8315, 22807, 2623, 268, 401, 293, 5097, 302, 546, 37495, 22653, 45164, 47525, 8315, 8717, 3794, 10721, 23275, 14407, 5480, 295, 33251, 1829, 20498, 9957, 365, 5551, 4117, 3794, 7435, 9957, 4032, 6814, 295, 47286, 374, 299, 8258, 4724, 9566, 16572, 28671, 20449, 9957, 3660, 14725, 2623, 268, 401, 293, 5097, 302, 546, 4032, 8032, 3215, 12610, 3660, 9673, 31747, 3555, 9957, 11933, 1829, 8592, 3714, 6027, 16095, 22807, 3714, 31747, 3555, 9307, 3714, 16095, 3660, 10874, 28259, 8978, 2423, 1798, 2423, 48353], "avg_logprob": -0.2420504417335778, "compression_ratio": 1.597609561752988, "no_speech_prob": 0.0, "words": [{"start": 2836.3100000000004, "end": 2837.51, "word": "فتفاعل", "probability": 0.828515625}, {"start": 2837.51, "end": 2838.25, "word": " الكيومين", "probability": 0.8558349609375}, {"start": 2838.25, "end": 2838.45, "word": " مع", "probability": 0.95654296875}, {"start": 2838.45, "end": 2839.23, "word": " الأكسجين", "probability": 0.803759765625}, {"start": 2839.23, "end": 2839.79, "word": " وحمض", "probability": 0.912109375}, {"start": 2839.79, "end": 2840.73, "word": " الكابريتيك", "probability": 0.82587890625}, {"start": 2840.73, "end": 2841.15, "word": " إيش", "probability": 0.6745402018229166}, {"start": 2841.15, "end": 2842.63, "word": " بيعطينا؟", "probability": 0.8920084635416666}, {"start": 2842.63, "end": 2843.37, "word": " Phenol", "probability": 0.691650390625}, {"start": 2843.37, "end": 2844.11, "word": " and", "probability": 0.79931640625}, {"start": 2844.11, "end": 2844.73, "word": " Acetone", "probability": 0.7842610677083334}, {"start": 2844.73, "end": 2844.93, "word": " يعني", "probability": 0.7197265625}, {"start": 2844.93, "end": 2845.11, "word": " لو", "probability": 0.96630859375}, {"start": 2845.11, "end": 2845.37, "word": " بدنا", "probability": 0.8359375}, {"start": 2845.37, "end": 2846.25, "word": " نسألكوا", "probability": 0.86640625}, {"start": 2846.25, "end": 2846.97, "word": " reaction", "probability": 0.59375}, {"start": 2846.97, "end": 2847.41, "word": " of", "probability": 0.93212890625}, {"start": 2847.41, "end": 2848.01, "word": " الكيومين", "probability": 0.9510498046875}, {"start": 2848.01, "end": 2848.21, "word": " with", "probability": 0.77197265625}, {"start": 2848.21, "end": 2848.79, "word": " أكسجين", "probability": 0.89111328125}, {"start": 2848.79, "end": 2848.91, "word": " و", "probability": 0.196533203125}, {"start": 2848.91, "end": 2849.17, "word": " presence", "probability": 0.1864013671875}, {"start": 2849.17, "end": 2849.83, "word": " of", "probability": 0.95263671875}, {"start": 2849.83, "end": 2850.67, "word": " sulphuric", "probability": 0.7679850260416666}, {"start": 2850.67, "end": 2851.01, "word": " acid", "probability": 0.9619140625}, {"start": 2851.01, "end": 2851.53, "word": " بطريقة", "probability": 0.943603515625}, {"start": 2851.53, "end": 2852.33, "word": " معينة", "probability": 0.98876953125}, {"start": 2852.33, "end": 2854.13, "word": " produces", "probability": 0.73828125}, {"start": 2854.13, "end": 2856.37, "word": " Phenol", "probability": 0.8518880208333334}, {"start": 2856.37, "end": 2856.85, "word": " and", "probability": 0.9638671875}, {"start": 2856.85, "end": 2857.65, "word": " Acetone", "probability": 0.9430338541666666}, {"start": 2857.65, "end": 2857.73, "word": " و", "probability": 0.454833984375}, {"start": 2857.73, "end": 2858.13, "word": " هدولة", "probability": 0.7235107421875}, {"start": 2858.13, "end": 2858.85, "word": " المركبين", "probability": 0.85467529296875}, {"start": 2858.85, "end": 2859.11, "word": " إيش", "probability": 0.9733072916666666}, {"start": 2859.11, "end": 2860.05, "word": " مالهم؟", "probability": 0.8739013671875}, {"start": 2860.05, "end": 2860.89, "word": " مركبات", "probability": 0.9725341796875}, {"start": 2860.89, "end": 2861.97, "word": " مهمة", "probability": 0.9899088541666666}, {"start": 2861.97, "end": 2862.71, "word": " جدا", "probability": 0.975830078125}, {"start": 2862.71, "end": 2862.89, "word": " في", "probability": 0.89697265625}, {"start": 2862.89, "end": 2863.03, "word": " ال", "probability": 0.71728515625}, {"start": 2863.03, "end": 2863.31, "word": " organ", "probability": 0.47021484375}, {"start": 2863.31, "end": 2863.87, "word": " الchemistry", "probability": 0.36767578125}], "temperature": 1.0}, {"id": 120, "seek": 287049, "start": 2866.55, "end": 2870.49, "text": "لحد هنا بننهي اليوم ان شاء الله إلى اللقاء", "tokens": [1211, 24401, 34105, 44945, 1863, 3224, 1829, 45595, 20498, 16472, 13412, 16606, 21984, 30731, 13672, 4587, 16606], "avg_logprob": -0.2304687516556846, "compression_ratio": 1.1343283582089552, "no_speech_prob": 0.0, "words": [{"start": 2866.55, "end": 2867.07, "word": "لحد", "probability": 0.986328125}, {"start": 2867.07, "end": 2867.49, "word": " هنا", "probability": 0.9580078125}, {"start": 2867.49, "end": 2868.71, "word": " بننهي", "probability": 0.77838134765625}, {"start": 2868.71, "end": 2869.19, "word": " اليوم", "probability": 0.942626953125}, {"start": 2869.19, "end": 2869.37, "word": " ان", "probability": 0.6064453125}, {"start": 2869.37, "end": 2869.65, "word": " شاء", "probability": 0.982421875}, {"start": 2869.65, "end": 2869.79, "word": " الله", "probability": 0.9541015625}, {"start": 2869.79, "end": 2870.01, "word": " إلى", "probability": 0.332275390625}, {"start": 2870.01, "end": 2870.49, "word": " اللقاء", "probability": 0.827880859375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2871.1475, "duration_after_vad": 2750.8587499999935}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/3snjlIzta1E.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/3snjlIzta1E.srt
new file mode 100644
index 0000000000000000000000000000000000000000..7189f9e9e7e7e4f69cfe4226fca6e59bbafdd408
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/3snjlIzta1E.srt
@@ -0,0 +1,1461 @@
+1
+00:00:19,510 --> 00:00:24,470
+بسم الله الرحمن الرحيم. المرة الماضية بدأنا في
+
+2
+00:00:24,470 --> 00:00:28,170
+موضوع الليبيدات وال detergents بشكل أساسي، بدأنا
+
+3
+00:00:28,170 --> 00:00:33,130
+نتعرف على ال triglycerides، وقلنا أن
+
+4
+00:00:33,130 --> 00:00:39,410
+triglycerides من شغلتين: من جلسرول الذي يمثل
+
+5
+00:00:39,410 --> 00:00:44,310
+جزء الكحول و fatty acids. واضح؟ هدول لما بتحدوا مع
+
+6
+00:00:44,310 --> 00:00:49,490
+بعض، بيعملوا عندنا إيش؟ triglycerides. لو عملنا
+
+7
+00:00:49,490 --> 00:00:53,110
+hydrolysis (تكسير) ل triglycerides ب Sodium
+
+8
+00:00:53,110 --> 00:00:58,650
+hydroxide، بنحصل على جلسرين و fatty acids. الآن، ال
+
+9
+00:00:58,650 --> 00:01:03,790
+fatty acids عرفناهم أنهم carboxylic acids عادية،
+
+10
+00:01:03,790 --> 00:01:08,610
+يعني فيهم مجموعة COOH، لكن السلسلة الموجودة فيهم
+
+11
+00:01:08,610 --> 00:01:15,130
+بشكل عام سلسلة طويلة، وبذلك يغلب عليهم جانب ال non-
+
+12
+00:01:15,130 --> 00:01:21,410
+polarity، وبالتالي بيصيروا بيدوبوا في المذيبات
+
+13
+00:01:21,410 --> 00:01:27,910
+العضوية بشكل عام. الآن، لو بدنا نتعرف أكثر على ال
+
+14
+00:01:27,910 --> 00:01:32,130
+fatty acids، بنقول إن fatty acids في منهم fatty
+
+15
+00:01:32,130 --> 00:01:37,850
+acids saturated. واضح؟ معنى saturated أنه موجود
+
+16
+00:01:37,850 --> 00:01:41,330
+فيه ولا double bond، ما فيش فيه double bonds. وفي
+
+17
+00:01:41,330 --> 00:01:45,670
+unsaturated فيه double bond أو أكثر. واضح؟ فيه
+
+18
+00:01:45,670 --> 00:01:51,130
+double bond أو أكثر. الآن، بشكل عام، ال fatty acids
+
+19
+00:01:51,130 --> 00:01:55,630
+الموجودة في الزيوت وفي الدهون بيكون عدد ال
+
+20
+00:01:55,630 --> 00:02:01,190
+carbons الموجودة فيه عدد زوجي. يعني هتلاحظوا لما نتعرف
+
+21
+00:02:01,190 --> 00:02:08,450
+عليهم، هنبدأ من 12، 14، 16، 18، 20. مش هنحكي عن 13،
+
+22
+00:02:08,450 --> 00:02:14,010
+مش هنحكي عن 15. واضح؟ هذا يرجع في الحقيقة إلى فكرة
+
+23
+00:02:14,010 --> 00:02:17,630
+تحضيرهم في الجسم، أنه هي فكرة مضاعفات اثنين، يعني
+
+24
+00:02:17,630 --> 00:02:21,870
+بيكون في عندي اثنين، بيجي لهم كمان اثنين بيصيروا أربعة،
+
+25
+00:02:21,870 --> 00:02:24,730
+كمان اثنين بيصيروا ستة، كمان اثنين بيصيروا ثمانية،
+
+26
+00:02:24,730 --> 00:02:29,050
+فزيادة اثنين اثنين اثنين، ولذلك لو بدنا نقول إنه
+
+27
+00:02:29,050 --> 00:02:33,530
+عدد ال carbons في ال fatty acids فردي أم زوجي،
+
+28
+00:02:33,530 --> 00:02:40,970
+الجواب زوجي. واضح؟ الآن، المشهورين منهم... المشهورين
+
+29
+00:02:40,970 --> 00:02:47,970
+منهم اللوريك أسيد، بنسميه اللي فيه اثني عشر كربون. بعد
+
+30
+00:02:47,970 --> 00:02:54,670
+هيك ميريستيك أسيد، أربعة عشر كربون. بالميتيك أسيد، هذا
+
+31
+00:02:54,670 --> 00:03:00,210
+من النخيل يعني زيت أشجار النخيل. بالميتيك أسيد، ستة عشر،
+
+32
+00:03:00,210 --> 00:03:07,250
+ستيريك أسيد الذي هو حامض دهني. وثم arachidic
+
+33
+00:03:07,250 --> 00:03:12,830
+acid... arachidic acid الذي هو إيش؟ عشرين. يمكن لما
+
+34
+00:03:12,830 --> 00:03:19,110
+تسمعوا كلمة stearic، تظل في مخكم، تخربطوها مع كلمة
+
+35
+00:03:19,110 --> 00:03:27,970
+ثانية مع حمض ثاني: citric acid. مرات
+
+36
+00:03:27,970 --> 00:03:32,320
+اللي... اللي بيكون مش متعود على الكلام، بيخلطوا
+
+37
+00:03:32,320 --> 00:03:36,720
+الكلمتين: citric، ستيريك. بيصير خلط بينهم. citric acid
+
+38
+00:03:36,720 --> 00:03:45,100
+حمض الليمون، حمض الليمون، و citronel  (ليمون). واضح؟ الآن،
+
+39
+00:03:45,100 --> 00:03:49,940
+ستيريك حمض دهني. ال citric acid حمض ثاني بشكل معين،
+
+40
+00:03:49,940 --> 00:03:54,500
+فيه ثلاث مجموعات carboxylic acids، مش موضوعنا. فلما
+
+41
+00:03:54,500 --> 00:04:00,350
+نقول citric، غير عن stearic. ولذلك أنتم لما تكونوا
+
+42
+00:04:00,350 --> 00:04:05,110
+تقرأوا المكونات، حاولوا تفرّقوا بين الشغلتين عن بعض.
+
+43
+00:04:05,110 --> 00:04:12,250
+يعني لو بتقرأوا مثلاً في مادة دوائية، على سبيل المثال،
+
+44
+00:04:12,250 --> 00:04:18,710
+مع شوية drops للزور، لإشي زي هيك، يمكن تلاقوا citric
+
+45
+00:04:18,710 --> 00:04:24,570
+acid (حمض ليمون). لكن لو بتقرأوا في شامبوهات وغيرها،
+
+46
+00:04:24,570 --> 00:04:30,350
+وغيرها، يمكن تلاقوا stearic. ستيريك شيء، وستيريك شيء.
+
+47
+00:04:30,350 --> 00:04:35,190
+الستيريك أسيد is a fatty، is a saturated fatty acid،
+
+48
+00:04:35,190 --> 00:04:40,550
+in fact containing 18 carbon atoms. واضح الفكرة؟
+
+49
+00:04:40,550 --> 00:04:45,890
+الآن، لاحظوا لو أطلعتوا على ال melting point لهذه
+
+50
+00:04:45,890 --> 00:04:50,190
+المركبات: 44، 58، 63،
+
+51
+00:04:50,190 --> 00:04:55,170
+يعني كلهم إيش؟ solids in principle. الآن، لو انتقلنا
+
+52
+00:04:55,170 --> 00:05:01,440
+إلى ال unsaturated acids اللي فيه double bonds،
+
+53
+00:05:01,440 --> 00:05:06,360
+لاحظوا لو اجينا، في عندي double bond واحدة، بتبدأ
+
+54
+00:05:06,360 --> 00:05:11,060
+على الموقع تسعة، على carbon تسعة، بيصير الحامض اسمه
+
+55
+00:05:11,060 --> 00:05:18,380
+oleic acid. الآن، لو في عندي اثنتين double bonds، بعد
+
+56
+00:05:18,380 --> 00:05:23,750
+هيك لينوليك أسيد. لو في عندي ثلاث double bonds،
+
+57
+00:05:23,750 --> 00:05:29,910
+لينولينيك، لينولينيك، لينولينيك، لينولينيك، لينولينيك،
+
+58
+00:05:29,910 --> 00:05:34,630
+واضح؟ هنا double bond واحدة، اثنتين، ثلاث.
+
+59
+00:05:36,580 --> 00:05:40,760
+بالنظر إلى ال melting point لهذول المركبات، لاحظوا
+
+60
+00:05:40,760 --> 00:05:44,700
+معي اللي فيه... اللي ما فيه double bond، يعني
+
+61
+00:05:44,700 --> 00:05:50,460
+هدول كلهم 18 carbon atom: 18...18...18...و ال
+
+62
+00:05:50,460 --> 00:05:53,640
+stearic: 18...18...18...18...18...18...18...
+
+63
+00:05:53,640 --> 00:05:55,780
+18...18...18...18...18...18...18...18...18
+
+64
+00:05:55,780 --> 00:05:58,060
+...18...18...18...18...18...18...18...18...
+
+65
+00:05:58,060 --> 00:06:01,660
+18...18...18...18...18...18...18...18...18
+
+66
+00:06:01,660 --> 00:06:04,200
+...18...18...18...18...18...18...18...18...
+
+67
+00:06:04,200 --> 00:06:06,040
+18...18...18...18...18...18...18...18...18
+
+68
+00:06:06,040 --> 00:06:06,200
+18...18...18...18...18...18...18...18...18
+
+69
+00:06:06,710 --> 00:06:12,510
+إذن، خلصنا من السؤال. كل ما زاد عددها... كلهم ستيريك. الآن،
+
+70
+00:06:12,510 --> 00:06:18,390
+لاحظوا معي هنا، ما فيش عندي double points بعد هيك،
+
+71
+00:06:18,390 --> 00:06:23,590
+كانت ال melting point 70، بعدها صار عندي one
+
+72
+00:06:23,590 --> 00:06:28,720
+double point، نزلت لـ 13. صار عندي اثنتين double
+
+73
+00:06:28,720 --> 00:06:33,340
+points، نزلت لـ -5. صار عندي ثلاث double
+
+74
+00:06:33,340 --> 00:06:39,320
+points، نزلت لأقل من -11. إذن، بنقدر احنا
+
+75
+00:06:39,320 --> 00:06:45,180
+نستنتج أن كل ما يزيد عدد ال double points، أو as
+
+76
+00:06:45,180 --> 00:06:49,180
+the unsaturation increases، يعني كل ما يزيد عدم
+
+77
+00:06:49,180 --> 00:06:55,720
+التشبع، ال melting point بتصير أقل. كل ما يزيد عدم
+
+78
+00:06:55,720 --> 00:06:59,920
+التشبع، كل ما ال melting point لل fatty acid بتصير
+
+79
+00:06:59,920 --> 00:07:05,940
+إيش؟ أقل. طبعاً هذا الكلام بحاجة إلى تفسير، ليش ال
+
+80
+00:07:05,940 --> 00:07:09,900
+saturated fatty acids in general، اللي هو ال
+
+81
+00:07:09,900 --> 00:07:14,060
+melting point عالية، و unsaturated منخفضة. لاحظوا
+
+82
+00:07:14,060 --> 00:07:17,960
+هنا، الـ 70، معناه على حرارة غرفتنا نحن،
+
+83
+00:07:17,960 --> 00:07:22,740
+معدل حرارة الغرفة 25، 30، solid. الآن،
+
+84
+00:07:22,740 --> 00:07:28,960
+الـ 13 في الجو تبعنا اليوم هيكون سائل، لأن الحرارة
+
+85
+00:07:28,960 --> 00:07:32,580
+25 عندنا. فهو لما بنحكي عن الـ 13 إنه أنا
+
+86
+00:07:32,580 --> 00:07:36,180
+سائل، إن -5 أكيد سائل، إن -11 أكيد سائل،
+
+87
+00:07:36,180 --> 00:07:40,640
+يعني كأنه بنقدر نأخذ معلومة جديدة، إن ال
+
+88
+00:07:40,640 --> 00:07:48,350
+unsaturated، they are liquids. يعني انخفاض
+
+89
+00:07:48,350 --> 00:07:51,630
+نقطة الانصهار تبعهم يخليهم liquids. ال saturated
+
+90
+00:07:51,630 --> 00:07:59,770
+they are solids. الآن، إذن،
+
+91
+00:07:59,770 --> 00:08:05,690
+القصة جديرة أن نكون نحن متوقفين عندها، خلينا نأخذ
+
+92
+00:08:05,690 --> 00:08:10,920
+إذن، شوية معلومات تساعدنا نفسر هذا الكلام. أول شيء،
+
+93
+00:08:10,920 --> 00:08:14,600
+most fatty acids are unbranched. يعني ال fatty
+
+94
+00:08:14,600 --> 00:08:19,080
+acids سلاسل غير متفرعة، سلسلة طويلة واضحة، ما فيها
+
+95
+00:08:19,080 --> 00:08:24,690
+branching، and contain an even number of carbon
+
+96
+00:08:24,690 --> 00:08:29,890
+atoms. فيه عدد ال carbon atoms عدد إيش؟ زوجي. الآن،
+
+97
+00:08:29,890 --> 00:08:34,010
+ال unsaturated acids، أول ما أبدأ أقول double bond،
+
+98
+00:08:34,010 --> 00:08:39,410
+كلمة ال double bond ارتبطت في الذهن بـ cis و trans، أو Z
+
+99
+00:08:39,410 --> 00:08:46,090
+و E. اه، unsaturated acids usually have the cis or Z
+
+100
+00:08:46,090 --> 00:08:50,720
+configuration. ال unsaturated بيكون ال
+
+101
+00:08:50,720 --> 00:08:56,020
+configuration فيه إيش؟ Z. يعني ال... الـ Hs بيجوا
+
+102
+00:08:56,020 --> 00:09:01,420
+على جهة، و ال carbons على جهة ثانية. الآن، they
+
+103
+00:09:01,420 --> 00:09:03,720
+have lower boiling points than the corresponding
+
+104
+00:09:03,720 --> 00:09:08,260
+saturated ones. شفنا من خلال القيم، أن ال
+
+105
+00:09:08,260 --> 00:09:13,860
+unsaturated نقاط الانصهار تبعها أقل من إيش؟ أقل
+
+106
+00:09:13,860 --> 00:09:17,060
+من ال saturated. ممتاز.
+
+107
+00:09:20,030 --> 00:09:24,490
+الآن، بنجي للسؤال الأول: ليش هذول solids، و هذول
+
+108
+00:09:24,490 --> 00:09:31,420
+liquids؟ اتطلعوا معي، لو تخيلت أنا هذا شكل ال
+
+109
+00:09:31,420 --> 00:09:35,200
+triglycerides، يعني هذا الجزء الجلسرين، وهذا الشيء
+
+110
+00:09:35,200 --> 00:09:39,720
+الزهري هو ال oxygen، وبعد هيك في عندي ثلاث سلاسل
+
+111
+00:09:39,720 --> 00:09:45,560
+طويلة: سلسلة، اثنتين، ثلاث. الآن، هذه السلاسل لما تكون
+
+112
+00:09:45,560 --> 00:09:50,340
+مشبعة، لما تكون مشبعة بشكل عام، بنتخيلها بهذا الشكل
+
+113
+00:09:50,340 --> 00:09:55,820
+المستقيم. الآن، لاحظوا كيف شكل المركب، هو شكل منتظم،
+
+114
+00:09:56,070 --> 00:10:01,290
+لأن المركب، الشكل تبعه منتظم. معنى ذلك أن الجزيئات
+
+115
+00:10:01,290 --> 00:10:05,930
+بتيجي فوق بعضها بشكل جيد، تترتب فوق بعضها في الحالة
+
+116
+00:10:05,930 --> 00:10:10,450
+الصلبة، وهذا اللي بيخليها تكون إيش؟ solids. الآن،
+
+117
+00:10:10,450 --> 00:10:16,410
+لو فقط واحدة من هذول صار فيها double bond، يعني لو
+
+118
+00:10:16,410 --> 00:10:20,790
+كان عندي ال triglycerides، ما بدي أقول الثلاث، فيهم
+
+119
+00:10:20,790 --> 00:10:23,670
+double bonds. خليني أقول هذه saturated، وهذه
+
+120
+00:10:23,670 --> 00:10:28,530
+saturated. واحدة بس قولت يكون فيها double bond، و ال
+
+121
+00:10:28,530 --> 00:10:31,550
+double bond اللي بده تكون فيها إيش؟ بده تكون cis،
+
+122
+00:10:31,550 --> 00:10:35,990
+هتصير بهذا الشكل. اتطلعوا من عندها هاي ال cis اللي
+
+123
+00:10:35,990 --> 00:10:40,750
+موجودة فيها هاي ال double bond، وهذا الجزء، هاي أنا
+
+124
+00:10:40,750 --> 00:10:45,690
+carbon، وأنا carbon على نفس الجهة. هذا الشكل عمل
+
+125
+00:10:45,690 --> 00:10:53,030
+إيش فيها؟ انثناء. واضح؟ الآن، هذا الانثناء حافظ على
+
+126
+00:10:53,030 --> 00:10:58,750
+الشكل المنتظم للجزيء، ولا بطل الجزيء منتظم؟ بطل
+
+127
+00:10:58,750 --> 00:11:02,830
+الجزيء منتظم. ولذلك لما تيجي الجزيئات، بتنحط فوق بعض
+
+128
+00:11:02,830 --> 00:11:07,130
+في solid lattice، في الشبكة، عشان تكون المركب الصلب،
+
+129
+00:11:07,130 --> 00:11:11,450
+ما بتبعدش فوق بعض جيداً، ما بتكونش متراصة فوق بعض
+
+130
+00:11:11,450 --> 00:11:16,630
+البعض، فالمادة بتحول إلى إيش؟ إلى liquid، أو بتنخفض
+
+131
+00:11:16,630 --> 00:11:23,240
+نقاط انصهارها. ولذلك هنا نحن، أنا شفت ال space
+
+132
+00:11:23,240 --> 00:11:26,860
+filling and schematic model of glycerol. التسمية
+
+133
+00:11:26,860 --> 00:11:30,380
+بنأخذها tri-palmitate. هذا من ال palmitic acid، يعني
+
+134
+00:11:30,380 --> 00:11:35,380
+كم كربون؟ 16. اللي متذكرين هذا المشبع، إيش ماله؟
+
+135
+00:11:35,380 --> 00:11:41,520
+كان regular، كان منتظم. بينما، لاحظوا معي هنا هذا
+
+136
+00:11:41,520 --> 00:11:46,680
+اللي فيه بس واحد غير مشبع، فيه double bond، راح
+
+137
+00:11:46,680 --> 00:11:50,220
+الانتظام. الآن، اتخيلوا إنه لو أكثر من واحد فيه
+
+138
+00:11:50,220 --> 00:11:53,480
+double bonds، اتخيل لو هذا فيه أكثر من double
+
+139
+00:11:53,480 --> 00:11:58,200
+bond، وكل double bond فيهم صار أشبه بإيش؟
+
+140
+00:12:00,430 --> 00:12:05,610
+لا، صار أشبه في الحقيقة...صار أشبه في الحقيقة بالفكرة اللي
+
+141
+00:12:05,610 --> 00:12:11,730
+أخذناها لما درسنا ال alkanes، ال chain alkanes و
+
+142
+00:12:11,730 --> 00:12:15,610
+ال branched alkanes، وقلنا أن ال chain they have
+
+143
+00:12:15,610 --> 00:12:20,810
+higher boiling point و melting point than ال branched.
+
+144
+00:12:20,810 --> 00:12:25,610
+ليش؟ لأن ال branched أصبح شكلهم زي إيش؟ زي الكرة،
+
+145
+00:12:25,610 --> 00:12:30,510
+بطلوا منتظمين فوق بعضهم البعض. واضح؟ لما أخذنا،
+
+146
+00:12:30,510 --> 00:12:33,510
+قلنا مين، أيّهم ال boiling point أعلى، ال chain ولا
+
+147
+00:12:33,510 --> 00:12:39,770
+ال branched؟ لأن ال branched بطل شكله منتظم. الفكرة
+
+148
+00:12:39,770 --> 00:12:43,890
+بالانتظام. الآن، هذا اللي فيه double bonds نفس
+
+149
+00:12:43,890 --> 00:12:48,250
+الفكرة زي ال branched، يعني لاحظوا أنه لو كان هنا في
+
+150
+00:12:48,250 --> 00:12:52,990
+branch، مش هتعمل هيك، وتقضي على الانتظام اللي كان
+
+151
+00:12:52,990 --> 00:12:59,180
+موجود. الآن، هذا الكلام اللي عملته double bond. فال
+
+152
+00:12:59,180 --> 00:13:03,560
+branching بيقضي على الانتظام، ووجود ال cis double
+
+153
+00:13:03,560 --> 00:13:07,240
+bond بهذا الشكل أيضاً قضى على الانتظام. فالفكرة
+
+154
+00:13:07,240 --> 00:13:12,780
+العامة في الحالتين، لما نقول أن ال alkanes بشكل عام،
+
+155
+00:13:12,780 --> 00:13:16,060
+أن ال branched they have lower boiling points and
+
+156
+00:13:16,060 --> 00:13:20,150
+melting points because they are irregular. الآن هنا،
+
+157
+00:13:20,150 --> 00:13:24,550
+ال triglycerides that contain unsaturated fatty
+
+158
+00:13:24,550 --> 00:13:27,470
+acids، they have lower boiling point and melting
+
+159
+00:13:27,470 --> 00:13:31,990
+point because they are irregular. من وين اجت ال
+
+160
+00:13:31,990 --> 00:13:36,330
+irregularity اللي فيهم، عدم الانتظام، من وجود ال
+
+161
+00:13:36,330 --> 00:13:39,370
+double bond و ال cis configuration الموجودة
+
+162
+00:13:39,370 --> 00:13:44,450
+فيها. واضح؟ الآن، هذا الكلام بيفرّق عندي وين؟ بيفرّق
+
+163
+00:13:44,450 --> 00:13:49,870
+عندي وين؟ ال oil however are liquid. بيصير في عندي
+
+164
+00:13:49,870 --> 00:13:56,350
+شيء اسمه في المطبخ، خلينا نقول شغلتين: بيصير في عندكم
+
+165
+00:13:56,350 --> 00:14:01,010
+زيت: زيت الزيتون، زيت عباد الشمس، زيت الصويا اللي
+
+166
+00:14:01,010 --> 00:14:06,290
+بتسمّوه searage، هذا liquid، وبيصير في عندكم صلب:
+
+167
+00:14:06,290 --> 00:14:11,260
+السمنة والزبدة. ملاحظين أنتم هذول ماشي بيفرّقوا
+
+168
+00:14:11,260 --> 00:14:17,240
+ببعض. السمنة والزبدة saturated،
+
+169
+00:14:17,240 --> 00:14:21,650
+الزيت اللي فيه ال double bonds، الزيت اللي فيه ال
+
+170
+00:14:21,650 --> 00:14:25,130
+double bonds، عشان هيك صار liquid. Oils however are
+
+171
+00:14:25,130 --> 00:14:32,190
+liquids because they contain a higher percentage of
+
+172
+00:14:32,190 --> 00:14:35,2
+
+223
+00:18:46,130 --> 00:18:50,350
+الإنسان طبعا هياخد مع الأشياء المجلية زيوت كمان و
+
+224
+00:18:50,350 --> 00:18:56,550
+هذه الأشياء fatty acids، انتبهوا معي، fatty acids
+
+225
+00:18:56,550 --> 00:19:03,430
+with trans bonds are carcinogenic، مسارتمينو لذلك
+
+226
+00:19:03,430 --> 00:19:08,350
+يعني أكثر من مرة و تانية ما تجربوش تجلوه إنما أنه
+
+227
+00:19:08,350 --> 00:19:13,910
+الزيت بينجل فيه أيام وليالي كل هذا الكلام يعتبر
+
+228
+00:19:13,910 --> 00:19:18,430
+كلام إيش خاطره الآن لاحظوا معي أنه برضه عملية
+
+229
+00:19:18,430 --> 00:19:26,120
+الهدرجة برضه عملية، عملية كيميائية، بنحول
+
+230
+00:19:26,120 --> 00:19:32,420
+فيها إحنا نسبة كبيرة من الـ double bonds إلى single
+
+231
+00:19:32,420 --> 00:19:36,140
+bonds يعني جاعدين إحنا نحول double bond إلى single
+
+232
+00:19:36,140 --> 00:19:39,800
+bond هذه الـ double bond اللي إحنا بنحولها cis ولا
+
+233
+00:19:39,800 --> 00:19:44,680
+trans؟ cis الآن هذه الـ هدرجة لما بنحكي عن زيت مش زي
+
+234
+00:19:44,680 --> 00:19:49,440
+مركب كيميائي يعني مش عملية سهلة، عادة ما بتتمش على
+
+235
+00:19:49,440 --> 00:19:53,840
+كل الـ double bonds لكن بتعمل نسبة كبيرة منهم واضحة
+
+236
+00:19:53,840 --> 00:19:59,820
+الفكرة؟ الآن في هذه الأثناء بعض الـ cis double
+
+237
+00:19:59,820 --> 00:20:03,000
+bonds بيظلهم cis يعني ما بيصلهمش الدور أنهم إيش
+
+238
+00:20:03,000 --> 00:20:08,240
+أنه يصير لهم هدرجة وبعض الـ cis منهم بتحولوا إلى
+
+239
+00:20:08,240 --> 00:20:16,060
+trans وبالتالي بتصير الهدرجة أيضا عاملة مشكلة مش من
+
+240
+00:20:16,060 --> 00:20:20,040
+منطقة أن هي حولت الـ double bond إلى single bond
+
+241
+00:20:20,040 --> 00:20:25,580
+يعني لو أن هي بشكل نظيف ودقيق ومتقن حولت الـ double
+
+242
+00:20:25,580 --> 00:20:29,320
+bonds إلى single bonds يعني حولت الزيت إلى سمنة
+
+243
+00:20:29,320 --> 00:20:35,410
+مافيش مشكلة، لكن المشكلة أن هذه الهدرجة غالبا بتكون
+
+244
+00:20:35,410 --> 00:20:40,410
+غير كاملة، لحد معين بيضل شوية cis bonds ونتيجة
+
+245
+00:20:40,410 --> 00:20:45,750
+التفاعل الكيميائي بعض الـ cis bonds بيصيروا trans
+
+246
+00:20:45,750 --> 00:20:54,780
+واضح؟ ولذلك اليوم صار يعني في دول معينة يجبروا
+
+247
+00:20:54,780 --> 00:20:59,920
+الشركات المصنعة أن تعمل فحوصات وأن على نفس
+
+248
+00:20:59,920 --> 00:21:05,920
+الزبدة وعلى نفس السمنة تكتب قد إيش نسبة trans فيها
+
+249
+00:21:06,870 --> 00:21:10,710
+والمواطن لازم يعرف، أقل تقدير أنتم الآن كمتعلمين
+
+250
+00:21:10,710 --> 00:21:16,130
+أن كل ما نسبة الـ trans بتزيد كل ما المركب بيكون
+
+251
+00:21:16,130 --> 00:21:22,750
+أكثر خطورة، كل ما المركب بيكون carcinogenic واضح؟
+
+252
+00:21:22,750 --> 00:21:30,570
+الآن بنيجي لكيف يا ترى بنسمي الـ triglycerides
+
+253
+00:21:30,570 --> 00:21:37,170
+خلينا ننتبه لشغلة، إنهم لـ triglycerides عبارة عن
+
+254
+00:21:37,170 --> 00:21:44,870
+glycerol صح؟ حامل كام fatty acid؟ ثلاثة، الآن لـ
+
+255
+00:21:44,870 --> 00:21:49,570
+triglycerides نوعين،
+
+256
+00:21:49,570 --> 00:21:53,790
+على طول، أي واحدة بتقدر تقولي شو النوعين؟ انتظر،
+
+257
+00:21:53,790 --> 00:21:59,250
+ممكن يكونوا متماثلين، يعني فيهم نفس الـ fatty acid
+
+258
+00:22:00,450 --> 00:22:04,870
+واضح؟ يعني 14 14 14  مشابه أو 16
+
+259
+00:22:04,870 --> 00:22:10,890
+16 16 مشابه وممكن يكونوا غير متماثلين، صارت
+
+260
+00:22:10,890 --> 00:22:13,830
+الأفكار شبيهة بأشياء أخذتها زي لما أخدنا الـ ether
+
+261
+00:22:13,830 --> 00:22:18,250
+متماثل وغير متماثل، زي ما أخدنا الـ anhydride متماثل
+
+262
+00:22:18,250 --> 00:22:22,650
+وغير متماثل، كمان الـ triglycerides ممكن يكونوا
+
+263
+00:22:23,260 --> 00:22:28,120
+simple يعني متماثلين أو mixed، mixed يعني مخلطين
+
+264
+00:22:28,120 --> 00:22:32,680
+يعني يكون هذا 16 هذا 18 هذا 18 فيه double bond
+
+265
+00:22:32,680 --> 00:22:40,160
+واضح؟ الآن أكيد لما بدنا نسمي لو كانوا متماثلين
+
+266
+00:22:40,160 --> 00:22:46,220
+هنذكر اسم الـ fatty acid لمرة واحدة ولو كانوا غير
+
+267
+00:22:46,220 --> 00:22:51,530
+متماثلين بدنا نذكر إيش؟ الثلاث أسماء اللي موجودة، مش
+
+268
+00:22:51,530 --> 00:22:55,890
+هذه لازم تكون الفكرة العامة، الآن بشكل عام كـ common
+
+269
+00:22:55,890 --> 00:23:01,070
+name وخلينا نبدأ بالـ common name للمتماثلين، لو كان
+
+270
+00:23:01,070 --> 00:23:07,970
+الـ fatty acid الـ 12 اللي هو اللوريك أسيد تمام، بنسمي
+
+271
+00:23:07,970 --> 00:23:10,630
+المركب trilaurin
+
+272
+00:23:13,300 --> 00:23:19,580
+واضح؟ إذا من الـ acid lauryl بحط إيش؟ lauryl tri
+
+273
+00:23:19,580 --> 00:23:27,660
+-lauryl طيب لو كان stearic tri-stearic يعني لاحظوا
+
+274
+00:23:27,660 --> 00:23:35,300
+معي كان الـ acid الأصلي lauryl لما عملت منه الـ tri
+
+275
+00:23:35,300 --> 00:23:41,860
+-glyceride ضفت كلمة tri هذه إجت جديدة، اللوريك
+
+276
+00:23:41,860 --> 00:23:50,100
+خلّيت منها لور وحطيت لها إيش؟ حطيت لها in بدل ic
+
+277
+00:23:50,100 --> 00:23:58,260
+in الـ trilaurin طيب من الـ stearic المتماثل tri
+
+278
+00:23:58,260 --> 00:24:06,150
+stearin من الأوليك المتماثل triolein واضح؟
+
+279
+00:24:06,150 --> 00:24:10,870
+trilaurin ولاحظوا على طول طبعا هيبين معاكم كيف
+
+280
+00:24:10,870 --> 00:24:14,890
+لـ trilaurin مثلا الـ melting point له لأن كل الـ
+
+281
+00:24:14,890 --> 00:24:20,510
+fatty acids تبعته مشبعة 45 هذا
+
+282
+00:24:20,510 --> 00:24:27,490
+لـ tristearin 71 الآن لو سألت واحدة منكم لو
+
+283
+00:24:27,490 --> 00:24:31,650
+سألت واحدة منكم ليش لـ trilaurin 45 و
+
+284
+00:24:31,650 --> 00:24:37,120
+لـ tristearin 71؟ السلسلة أطول، الموليكولا
+
+285
+00:24:37,120 --> 00:24:41,400
+أثقل، الكلمتين صح، الاثنين مشبع، مشبع، بطل، التشبع
+
+286
+00:24:41,400 --> 00:24:47,300
+هو الفارق، فقط طول السلسلة، آه، لكن لما هنا أجيت
+
+287
+00:24:47,300 --> 00:24:53,430
+18 و 18 وحطيت ثلاثة double bonds يعني نقصان ستة
+
+288
+00:24:53,430 --> 00:24:56,410
+هيدروجينات، مش المشكلة فرق الـ molecular weight
+
+289
+00:24:56,410 --> 00:25:00,290
+يعني ستة وحدات في جزء كبير زي هذا في الـ molecular
+
+290
+00:25:00,290 --> 00:25:04,550
+weight ما أثرهمش فرق، لكن المشكلة حقيقة لما أنا
+
+291
+00:25:04,550 --> 00:25:11,450
+بنزل هذا 18 وهذا 18 قليل، الـ 18 فيه one double bond
+
+292
+00:25:11,450 --> 00:25:16,970
+لما بنزل من 71 لـ 4 هذا مش فرق التغير في الـ
+
+293
+00:25:16,970 --> 00:25:21,280
+molecular weight هذا نتيجة وجود الـ double bonds،
+
+294
+00:25:21,280 --> 00:25:24,300
+ليش؟ لأن وجدت، لو بدي أجي هنا، بدي أعمل هذه الـ
+
+295
+00:25:24,300 --> 00:25:26,840
+double bonds زي هيك و زي هيك، بعدين هذه زي هيك و
+
+296
+00:25:26,840 --> 00:25:34,010
+زي هيك، بعدين هذه، صار إيش؟ زي الكورة، الجزيء وجده
+
+297
+00:25:34,010 --> 00:25:39,090
+بده يصير زي كرة، كيف بده يكون منتظم في solid state
+
+298
+00:25:39,090 --> 00:25:44,550
+واضحة الفكرة؟ فلما بده أقول ليش الـ triolein لو بده
+
+299
+00:25:44,550 --> 00:25:49,710
+أجي أسألكم الـ triolein have lower melting point
+
+300
+00:25:49,710 --> 00:25:54,770
+than tristearin because of the presence of the
+
+301
+00:25:54,770 --> 00:26:00,230
+double bonds or because it is unsaturated واضحة
+
+302
+00:26:00,230 --> 00:26:05,250
+الفكرة؟ وهذا وجود الـ double bond أو الـ unsaturation
+
+303
+00:26:05,250 --> 00:26:09,790
+خلّاه regular ولا irregular؟ irregular، بطل منتظم
+
+304
+00:26:09,790 --> 00:26:14,070
+بطل زي .. زي حجارة الطوب المنتظمة كيف بتصفق بعض
+
+305
+00:26:14,070 --> 00:26:18,870
+بشكل قوي بينما حجارة مش منتظمة بتضل إيش؟ توجع أو
+
+306
+00:26:18,870 --> 00:26:26,600
+ألعاب الأطفال اللي بيسموها الـ Lego الآن موضوع
+
+307
+00:26:26,600 --> 00:26:30,780
+الهيدروجينيشن of vegetable oils حكينا قلنا أن
+
+308
+00:26:30,780 --> 00:26:36,420
+إحنا ممكن ناخد الـ oil ويصير زبدة أو سمنة
+
+309
+00:26:36,420 --> 00:26:40,120
+بالهيدروجينيشن، تحويل الـ double bond إلى single
+
+310
+00:26:40,120 --> 00:26:42,780
+bond هذا الكلام برفع الـ melting point بيحول الـ
+
+311
+00:26:42,780 --> 00:26:47,380
+liquid إلى solid، الهيدروجينيشن عادة بتنفي وجود
+
+312
+00:26:47,380 --> 00:26:52,360
+الهيدروجين و catalyst و heat لكن هناك خطورة
+
+313
+00:26:52,360 --> 00:26:54,420
+مصاحبة للهيدروجينيشن
+
+314
+00:26:56,690 --> 00:27:02,110
+تحويل بعض الـ cis bonds إلى trans يعني التحويل من
+
+315
+00:27:02,110 --> 00:27:05,630
+cis إلى saturated أو من double bond إلى saturated
+
+316
+00:27:05,630 --> 00:27:10,750
+هذا ما فيش فيه مشكلة لكن كتفاعل جانبي بعض الـ cis
+
+317
+00:27:10,750 --> 00:27:15,450
+بيصير trans هنا توجد المشكلة
+
+318
+00:27:16,590 --> 00:27:21,350
+الآن مرة تانية نرجع للـ simple and mixed
+
+319
+00:27:21,350 --> 00:27:25,210
+triglycerides اللي هي المتماثلة وغير المتماثلة
+
+320
+00:27:25,210 --> 00:27:32,490
+اتفقنا إحنا أن المتماثل بنعطي اسم common name
+
+321
+00:27:32,490 --> 00:27:38,470
+tristerin يعني هذا 18 إذا إيش الحمض تبعه؟ stearic
+
+322
+00:27:38,470 --> 00:27:44,190
+stearic stearic فالمركب tristerin طيب لو كنا بنسمي
+
+323
+00:27:44,190 --> 00:27:51,210
+IUPAC يعني triglycerides is a common name وأنا
+
+324
+00:27:51,210 --> 00:27:55,470
+مرات بجيب لكم سؤال في الامتحان .. بجيب لكم سؤال في
+
+325
+00:27:55,470 --> 00:28:00,810
+الامتحان، الـ triglycerides is also called .. or the
+
+326
+00:28:00,810 --> 00:28:06,830
+IUPAC name of triglycerides is .. الآن عشان
+
+327
+00:28:06,830 --> 00:28:11,650
+نجاوبه صح إحنا قلنا الـ triglycerides they are
+
+328
+00:28:11,650 --> 00:28:18,550
+esters esters صح ولا لأ؟ كيف أنا كنت أسمي الـ
+
+329
+00:28:18,550 --> 00:28:22,970
+esters؟ خليني أتذكر كيف أنا كنت أسمي الـ esters،
+
+330
+00:28:22,970 --> 00:28:29,370
+هيني بدي أكتب ester عشان واحدة تذكرني كيف،
+
+331
+00:28:29,370 --> 00:28:32,690
+هاي ester، شايفينه اللي على اللوح؟ واحدة تسميه
+
+332
+00:28:32,690 --> 00:28:37,370
+جزء الكحول في الأول
+
+333
+00:28:40,150 --> 00:28:49,150
+مثل هذا جزء الكحول وبعدين جزء الحمض أنتم بتكونوا
+
+334
+00:28:49,150 --> 00:28:52,910
+شايفيني ومن جلة دراستكم بنزوات أسيد الـ ester
+
+335
+00:28:52,910 --> 00:28:58,130
+بنتهي بـ benzoate مثل benzoate acetate، butanoate، آه هذا
+
+336
+00:28:58,130 --> 00:29:04,970
+مثل إيش؟ benzoate إذا تسمية الـ ester لعبوا لو أنكم
+
+337
+00:29:04,970 --> 00:29:09,030
+بتحاولوا تحفظوا الكيمياء كرموز بتتغلبوا، لو أنكم
+
+338
+00:29:09,030 --> 00:29:13,310
+حفظتوا الكيمياء أن تسمية الـ ester مجموعة الكحول
+
+339
+00:29:13,310 --> 00:29:18,690
+في الأول، بعدين الـ acid منتهي بـ ate مثل acetate
+
+340
+00:29:18,690 --> 00:29:24,730
+مثل benzoate، فين الـ butanoate صح ولا لأ؟ طيب الآن كويس
+
+341
+00:29:24,730 --> 00:29:31,770
+لو أجيت على هذا شو هو جزء الكحول فيه؟ الـ glycerol
+
+342
+00:29:32,770 --> 00:29:38,250
+وشو الأحماض؟ الـ stearic acid مش هذا الحمض وهذا
+
+343
+00:29:38,250 --> 00:29:44,590
+الكحول ولا لأ؟ إيش أول شيء بنذكره؟ جزء الكحول
+
+344
+00:29:44,590 --> 00:29:53,350
+glyceryl، glyceryl و الـ stearic acid، stearate لكن لأن
+
+345
+00:29:53,350 --> 00:29:58,330
+في عندي منه ثلاثة بقول glycerol tri stearate
+
+346
+00:29:58,330 --> 00:30:03,290
+إذا أنا نفس المنطقة هذه اسمها الـ ester، الكحول في
+
+347
+00:30:03,290 --> 00:30:09,070
+الأول وبعدين النهاية ate وحطيت tri لأن عندي كم
+
+348
+00:30:09,070 --> 00:30:16,160
+حمض؟ ثلاثة إذا هذه هي جزء الكحول اللي فيه، في واحدة
+
+349
+00:30:16,160 --> 00:30:19,140
+منكم مالكهومة كتير عشان الكحول مرسوم على اليمين مش
+
+350
+00:30:19,140 --> 00:30:22,660
+على الشمال المهم نذكر الكحول في الأول، كيف نرسمه مش
+
+351
+00:30:22,660 --> 00:30:28,360
+مشكلة واضحة الفكرة ولا لأ؟ واضحة؟ يعني هذا لو كنت
+
+352
+00:30:28,360 --> 00:30:35,540
+رسمته بالعكس إيش برضه هسميه؟ واضح؟ شايف هي كناس
+
+353
+00:30:35,540 --> 00:30:40,360
+مرات بهمش بيغرقوا بشوية ميه؟
+
+354
+00:30:43,590 --> 00:30:46,990
+يعني اتعودتوا أنتم أن هذا نعمله زي هيك أو يبدو
+
+355
+00:30:46,990 --> 00:30:53,130
+معكوس، لأن لما يرسم زي هيك وين جزء الكحول مثل وين
+
+356
+00:30:53,130 --> 00:30:57,250
+جزء الحمض؟ مثل benzoate مثل benzoate خلاص يعني الفكرة
+
+357
+00:30:57,250 --> 00:31:01,950
+مش أنه بدهم يبينوا هدول معكوسين دائما لأ لأ مش
+
+358
+00:31:01,950 --> 00:31:06,890
+هذه الفكرة، حسب طريقة الرسم يذكر جزء الكحول أولا ثم
+
+359
+00:31:06,890 --> 00:31:10,770
+جزء الحمض منتهي بالنهاية ate، ولذلك هذا هيك إيش
+
+360
+00:31:10,770 --> 00:31:14,780
+بدنا نسميه مثل؟ benzoate
+
+361
+00:31:18,100 --> 00:31:22,640
+أكيد أكيد طبعا آه ليش ما يجيكيش ارسمي نفسي كل هذا
+
+362
+00:31:22,640 --> 00:31:27,800
+الكربونات ترسم ترسم شو وراك أنتم دفعين رسوم
+
+363
+00:31:27,800 --> 00:31:32,760
+بتكونوا بتتعلموا واضحة تسمية الـ ester تسمية الـ
+
+364
+00:31:32,760 --> 00:31:37,840
+ester ببساطة أن تذكروا جزء الكحول بعدين جزء
+
+365
+00:31:37,840 --> 00:31:42,400
+الحمض، المساهي بالنهاية ate، هذا صار glycerol
+
+366
+00:31:42,400 --> 00:31:50,100
+tri stearate هذه فهمناها، طيب لو كانوا الأحماض الآن
+
+367
+00:31:50,100 --> 00:31:56,200
+مختلفين يعني صار عنده اللي أنا بسميه إيش؟ mixed
+
+368
+00:31:56,200 --> 00:32:02,760
+triglyceride مرة تانية هحط في الأول جزء الكحول، إذا
+
+369
+00:32:02,760 --> 00:32:09,450
+هنا هذا الجزء الكحول، هذا الجزء اللي جاي من الكحول مش
+
+370
+00:32:09,450 --> 00:32:16,310
+بيختلف عليه، الآن الأحماض بدي أذكرهم مرتبين، واحد،
+
+371
+00:32:16,310 --> 00:32:20,950
+اثنين، ثلاثة، طبعا هتقولولي إذا عرفنا واحد، بعده
+
+372
+00:32:20,950 --> 00:32:24,270
+بنقول اثنين، ثلاثة، يمكن تصير المشكلة عندكم أن هذا
+
+373
+00:32:24,270 --> 00:32:28,730
+واحد، بعدين اثنين، ثلاثة، ولا هذا واحد، بعدين
+
+374
+00:32:28,730 --> 00:32:33,800
+اثنين، ثلاثة واضح؟ يعني المشكلة أن أذكر واحد، بعد
+
+375
+00:32:33,800 --> 00:32:38,020
+ما أذكر واحد لازم أمشي فيهم إيش؟ مرتبين، الآن
+
+376
+00:32:38,020 --> 00:32:44,760
+ببساطة بنقول الأصغر والأكثر تشبعا هو اللي بنحطه
+
+377
+00:32:44,760 --> 00:32:49,940
+نمرة واحد، يعني لما أنا ببدأ أختار وين نمرة واحد،
+
+378
+00:32:49,940 --> 00:32:54,960
+ببدأ أختار الأصغر منهم والأكثر تشبعا يعني لو أجيت
+
+379
+00:32:54,960 --> 00:32:58,980
+هنا 16 وهنا 18 مشبعين الاثنين مين بدي
+
+380
+00:32:58,980 --> 00:33:05,540
+أحطهم؟ 16 الآن لو أجيت هنا 16 وهنا 18
+
+381
+00:33:05,540 --> 00:33:11,280
+وكمان هذا مشبع الـ 16 الآن بعد ما أحط الـ 16
+
+382
+00:33:11,280 --> 00:33:16,280
+مامشي فيهم بالترتيب واضح؟ ولذلك هدول لو أنا
+
+383
+00:33:16,280 --> 00:33:22,470
+أجيت أطلعت الـ 16 بالـ palmitic acid الـ 18 المشبع
+
+384
+00:33:22,470 --> 00:33:27,790
+stearic الـ 18 اللي فيه double bond oleic لما أنا
+
+385
+00:33:27,790 --> 00:33:32,150
+بدي أسميهم بقول glycerol بعدين بكتب palmito
+
+386
+00:33:32,150 --> 00:33:38,510
+palmito بعدين stearo stearate بعدين oleio
+
+387
+00:33:38,510 --> 00:33:45,490
+oleate بحط ate في النهاية لاحظوا معي أن الأوليك أن
+
+388
+00:33:45,490 --> 00:33:46,390
+الأوليك
+
+389
+00:33:50,390 --> 00:33:58,870
+الـ O تبعته عليها إيش؟ نقطتين طبعا على الكمبيوتر
+
+390
+00:33:58,870 --> 00:34:03,230
+ممكن تلاقوا الـ O اللي عليها نقطتين وممكن أنه
+
+391
+00:34:03,230 --> 00:34:06,430
+ما تلاقوهاش، الآن لو ما لاقيتوهاش الـ O اللي عليها
+
+392
+00:34:06,430 --> 00:34:08,870
+نقطتين اكتبها إيش؟
+
+393
+00:34:10,720 --> 00:34:17,820
+ونطقوها oe فهي O مائلة للكسر يعني بمنطق
+
+394
+00:34:17,820 --> 00:
+
+445
+00:38:44,950 --> 00:38:48,350
+بالميتو ستيرو أوليات، الثاني glycerol ستيرو
+
+446
+00:38:48,350 --> 00:38:51,150
+بالميتو أوليات، الآن هذول أخذوا different names
+
+447
+00:38:51,150 --> 00:38:54,230
+ولا لأ؟ طالما different names، إذاً they are
+
+448
+00:38:54,230 --> 00:38:59,470
+structural isomers، stereo isomers كانوا يأخذوا
+
+449
+00:38:59,470 --> 00:39:05,780
+نفس الاسم، يفرقوا بس في البادئة في enantiomers R
+
+450
+00:39:05,780 --> 00:39:11,680
+ولا S ولا كذا، وفي diastereomers S أو Trans أو Z
+
+451
+00:39:11,680 --> 00:39:16,340
+أو E، same name وكانوا يأخذوا different descriptive
+
+452
+00:39:16,340 --> 00:39:20,680
+البادئة التي تصف الشكل الفراغي، لم نسمها
+
+453
+00:39:20,680 --> 00:39:25,520
+descriptive، البادئة R أو S أو Z أو E
+
+454
+00:39:25,520 --> 00:39:30,460
+أو S أو Trans لكن لهم نفس الاسم
+
+455
+00:39:31,530 --> 00:39:35,470
+الآن لاحظوا معي، لو قلنا لكم draw this structure
+
+456
+00:39:35,470 --> 00:39:41,210
+for glyceryl trimyristate، اللي هو myristic acid
+
+457
+00:39:41,210 --> 00:39:48,210
+C14 موجود عندكم، بدكم تحطوه، ربما من الأخطاء التي
+
+458
+00:39:48,210 --> 00:39:50,450
+كثير الطلاب يخطئونها
+
+459
+00:40:19,820 --> 00:40:23,880
+تطلعوا كيف الشكل الصحيح، الـ O هنا، هذا جزء الكحول
+
+460
+00:40:23,880 --> 00:40:29,400
+هذا جزء الحامض، الـ glycerol هو المتصل بالـ O العادية
+
+461
+00:40:29,400 --> 00:40:33,400
+single bond، بعدين الـ C double bond O، ليس العكس، هذا
+
+462
+00:40:33,400 --> 00:40:36,340
+من الأخطاء الشائعة، عندما نقول للطلبة ارسموا لنا
+
+463
+00:40:36,340 --> 00:40:41,640
+triglyceride، يذهبون ويرسمونه معكوساً، واضح؟
+
+464
+00:40:44,360 --> 00:40:49,780
+على أي حال، هكذا تقريباً ننهي اليوم، غداً إجازة عيد
+
+465
+00:40:49,780 --> 00:40:54,740
+العمال، لا أعرف متى يكون عيد الطلاب، عيدنا يوم
+
+466
+00:40:54,740 --> 00:40:57,280
+نجاحنا
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/3snjlIzta1E_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/3snjlIzta1E_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..568d9416148a87b1e6d5323b09df9fe822cdbac8
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/3snjlIzta1E_postprocess.srt
@@ -0,0 +1,1864 @@
+1
+00:00:19,510 --> 00:00:24,470
+بسم الله الرحمن الرحيم المرة الماضية بدأنا في
+
+2
+00:00:24,470 --> 00:00:28,170
+موضوع ال libids و ال detergents بشكل أساسي بدأنا
+
+3
+00:00:28,170 --> 00:00:33,130
+نتعرف على ال triglycerides و قلنا أن ال
+
+4
+00:00:33,130 --> 00:00:39,410
+triglycerides من شغلتين من إجليسرول اللي هو بيمثل
+
+5
+00:00:39,410 --> 00:00:44,310
+جزء ال alcohol و fatty acidواضح هدول لما بتحدوا مع
+
+6
+00:00:44,310 --> 00:00:49,490
+بعض بيعملوا عندنا إيش لـ triglycerides لو عملنا
+
+7
+00:00:49,490 --> 00:00:53,110
+hydrolysis تكسير لـ triglycerides ب Sodium
+
+8
+00:00:53,110 --> 00:00:58,650
+hydroxide بنحصل على إجليسرين و fatty acids الآن ال
+
+9
+00:00:58,650 --> 00:01:03,790
+fatty acids عرفناهم إنهم carboxylic acids عادية
+
+10
+00:01:03,790 --> 00:01:08,610
+يعني فيهم مجموعة COOH لكن السلسلة اللي موجودة فيهم
+
+11
+00:01:08,610 --> 00:01:15,130
+بشكل عامسلسلة طويلة و بذلك بيغلب عليهم جانب ال non
+
+12
+00:01:15,130 --> 00:01:21,410
+-polarity و بالتالي بيصيروا بيدوبوا في المذيبات
+
+13
+00:01:21,410 --> 00:01:27,910
+العضوية بشكل عامالان لو بدنا نتعرف اكتر على ال
+
+14
+00:01:27,910 --> 00:01:32,130
+fatty acids، بنقول ال fatty acids في منهم fatty
+
+15
+00:01:32,130 --> 00:01:37,850
+acids saturated، واضح؟ معنى saturated انه موجود
+
+16
+00:01:37,850 --> 00:01:41,330
+فيهم ولا double bond، مافيش فيهم double bonds، وفي
+
+17
+00:01:41,330 --> 00:01:45,670
+unsaturated فيهم double bond او اكتر، واضح؟ فيهم
+
+18
+00:01:45,670 --> 00:01:51,130
+double bond او اكترالان بشكل عام ال fatty acids
+
+19
+00:01:51,130 --> 00:01:55,630
+اللي موجودين في الزيوت و في الدهون بيكونوا عدد ال
+
+20
+00:01:55,630 --> 00:02:01,190
+carbons اللي فيهم عدد زوجييعني هتلاحظوا لما نتعرف
+
+21
+00:02:01,190 --> 00:02:08,450
+عليهم هنبدأ من 12، 14، 16، 18، 20، مش هنحكي عن 13،
+
+22
+00:02:08,450 --> 00:02:14,010
+مش هنحكي عن 15، واضح؟ هذا بيرجع حقيقة إلى فكرة
+
+23
+00:02:14,010 --> 00:02:17,630
+تحضيرهم في الجسم أنه هي فكرة مضاعفات اتنين، يعني
+
+24
+00:02:17,630 --> 00:02:21,870
+بيكون في عندى اتنينبيجيهم كمان اتنين بيصيروا اربعة
+
+25
+00:02:21,870 --> 00:02:24,730
+كمان اتنين بيصيروا ستة كمان اتنين بيصيروا تمانية
+
+26
+00:02:24,730 --> 00:02:29,050
+فزيادة اتنين اتنين اتنين ولذلك لو بدنا نقول انه
+
+27
+00:02:29,050 --> 00:02:33,530
+عدد ال carbons في ال fatty acids odd ولا even
+
+28
+00:02:33,530 --> 00:02:40,970
+الجواب even واضح؟الان المشهورين منهم .. المشهورين
+
+29
+00:02:40,970 --> 00:02:47,970
+منهم اللوريك أسد بنسميه اللي فيه اتناشر كاربون بعد
+
+30
+00:02:47,970 --> 00:02:54,670
+هيك ميريستك أسد اربعة عشر كاربون بالميتك أسد هذا
+
+31
+00:02:54,670 --> 00:03:00,210
+من البلم يعني زيت الاش النخيل بالميتك أسد ستة عشر
+
+32
+00:03:00,210 --> 00:03:07,250
+استيرك أسداللي هو حامض ضهني تمنتعش و arachidic
+
+33
+00:03:07,250 --> 00:03:12,830
+acid .. arachidic acid اللي هو إيش؟ عشرين يمكن لما
+
+34
+00:03:12,830 --> 00:03:19,110
+تسمعوا كلمة stearic تظل في مخكم تخربطلها مع كلمة
+
+35
+00:03:19,110 --> 00:03:27,970
+تانية مع حمض تاني citric acid مرات
+
+36
+00:03:27,970 --> 00:03:32,320
+اللي ..اللي بيكون مش متعود ع الكلام بيخلطوا
+
+37
+00:03:32,320 --> 00:03:36,720
+الكلمتين citric استيرك بيصير خربطهم citric acid
+
+38
+00:03:36,720 --> 00:03:45,100
+حمض اللمون حمض اللمون و citronel لمون واضح؟ الآن
+
+39
+00:03:45,100 --> 00:03:49,940
+استيرك حمض دهني ال citric acid حامض تاني بشكل معين
+
+40
+00:03:49,940 --> 00:03:54,500
+فيه تلت مجموعات carboxylic acids مش موضوعنا فلما
+
+41
+00:03:54,500 --> 00:04:00,350
+نقول citric غير عنstearic ولذلك انتوا لما تكونوا
+
+42
+00:04:00,350 --> 00:04:05,110
+تقرأوا المكونات ضالكوا ميزوا عن الشغلتين عن بعض
+
+43
+00:04:05,110 --> 00:04:12,250
+يعني لو بتقرأوا مثلا في مادة أخذية على سبيل المثال
+
+44
+00:04:12,250 --> 00:04:18,710
+مع شوية drops للزور لإشي زي هيك يمكن تلاقوا citric
+
+45
+00:04:18,710 --> 00:04:24,570
+acid حمض لمون لكن لو بتقرأوا في شامبوهات وغيرها
+
+46
+00:04:24,570 --> 00:04:30,350
+وغيراتها يمكن تلاقوا stearicفستيرك شيء وستريك شيء
+
+47
+00:04:30,350 --> 00:04:35,190
+الاستيرك أسد is a fatty is a saturated fatty acid
+
+48
+00:04:35,190 --> 00:04:40,550
+in fact containing 18 carbon atoms واضح الفكرة
+
+49
+00:04:40,550 --> 00:04:45,890
+الان لاحظوا لو اطلعتوا على ال melting point لهذه
+
+50
+00:04:45,890 --> 00:04:50,190
+المركبات اربعة واربعين تمانية وخمسين تلاتة وستين
+
+51
+00:04:50,190 --> 00:04:55,170
+يعني كلهم ايش solids in principle الان لو انتقلنا
+
+52
+00:04:55,170 --> 00:05:01,440
+علىالـ unsaturated acids اللي فيهم double bonds
+
+53
+00:05:01,440 --> 00:05:06,360
+لاحظوا لو اجينا في عندي double bond واحدة بتبدأ
+
+54
+00:05:06,360 --> 00:05:11,060
+على الموقع تسعة على carbon تسعة بيصير الحامض اسمه
+
+55
+00:05:11,060 --> 00:05:18,380
+oleic acid الأن لو في عندي تنتين double bonds بعد
+
+56
+00:05:18,380 --> 00:05:23,750
+هيك لينوليك أسدلو في عندى تلاتة double bonds
+
+57
+00:05:23,750 --> 00:05:29,910
+لينولينيك لينولينيك لينولينيك لينولينيك لينولينيك
+
+58
+00:05:29,910 --> 00:05:34,630
+واضح هنا double bond واحدة تلتين تلاتة
+
+59
+00:05:36,580 --> 00:05:40,760
+بالنظر إلى ال melting point لهدول المركبات لاحظوا
+
+60
+00:05:40,760 --> 00:05:44,700
+معايا اللي فيه .. اللي فيش فيه double bond يعني
+
+61
+00:05:44,700 --> 00:05:50,460
+هدول كلهم 18 carbon atom 18 .. 18 .. 18 .. و ال
+
+62
+00:05:50,460 --> 00:05:53,640
+stearic 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 ..
+
+63
+00:05:53,640 --> 00:05:55,780
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+64
+00:05:55,780 --> 00:05:58,060
+.. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 ..
+
+65
+00:05:58,060 --> 00:06:01,660
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+66
+00:06:01,660 --> 00:06:04,200
+.. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 ..
+
+67
+00:06:04,200 --> 00:06:06,040
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+68
+00:06:06,040 --> 00:06:06,200
+18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18 .. 18
+
+69
+00:06:06,710 --> 00:06:12,510
+إذا خلصنا من السؤال كل ما زاد كلهم تمنتعش الآن
+
+70
+00:06:12,510 --> 00:06:18,390
+لاحظوا معاه هنا مافيش عندي double points بعد هيك
+
+71
+00:06:18,390 --> 00:06:23,590
+كانت ال melting point سبعين بعدك صار عندي one
+
+72
+00:06:23,590 --> 00:06:28,720
+double point نزلتلتلت عشر صار عندى تنتين double
+
+73
+00:06:28,720 --> 00:06:33,340
+points نزلت لناقص خمسة صار عندى تلاتة double
+
+74
+00:06:33,340 --> 00:06:39,320
+points نزلت لأكم لناقص احد عشر اذا بنقدر احنا
+
+75
+00:06:39,320 --> 00:06:45,180
+نستنتج انه كل ما بيزيدوا ال double points او as
+
+76
+00:06:45,180 --> 00:06:49,180
+the unsaturation increases يعني كل ما بيزيد عدم
+
+77
+00:06:49,180 --> 00:06:55,720
+التشبع ال melting point بتصير اقلكل ما بيزيد عدم
+
+78
+00:06:55,720 --> 00:06:59,920
+التشبع كل ما ال melting point لل fatty acid بتصير
+
+79
+00:06:59,920 --> 00:07:05,940
+ايش اقل طبعا هذا الكلام بحاجة الى تفسير ليش ال
+
+80
+00:07:05,940 --> 00:07:09,900
+saturated fatty acids in general اللي هو ال
+
+81
+00:07:09,900 --> 00:07:14,060
+melting point عالية ال unsaturated منخفضة لاحظوا
+
+82
+00:07:14,060 --> 00:07:17,960
+هنا السبعين معناه على حرارة الغرفة تبعتنا احنا
+
+83
+00:07:17,960 --> 00:07:22,740
+معدل حرارة الغرفة خمسة وعشرين تلاتين solidالان
+
+84
+00:07:22,740 --> 00:07:28,960
+التلتعش في الجو تبعنا اليوم هيكون سائل لأن الحرارة
+
+85
+00:07:28,960 --> 00:07:32,580
+خمسة و عشرين عندنا فهو لما بنصار عن التلتعش إن أنا
+
+86
+00:07:32,580 --> 00:07:36,180
+سائل، إن ناقص خمسة أكيد سائل، إن ناقص إحد أش سائل،
+
+87
+00:07:36,180 --> 00:07:40,640
+يعني كأنه بنقدر ناخد معلومة جديدة إن ال
+
+88
+00:07:40,640 --> 00:07:48,350
+unsaturated they are liquidsيعني انسهار أو انخفاض
+
+89
+00:07:48,350 --> 00:07:51,630
+نقطة الانسهار تبعهم تخلهم liquids ال saturated
+
+90
+00:07:51,630 --> 00:07:59,770
+they are solids الاناذي
+
+91
+00:07:59,770 --> 00:08:05,690
+القصة جديرة ان نكون احنا متوقفين عندها خلينا ناخد
+
+92
+00:08:05,690 --> 00:08:10,920
+اذا شوية معلومات تساعدنا نفسر هذا الكلامأول اشي
+
+93
+00:08:10,920 --> 00:08:14,600
+most fatty acids are unbranched يعني ال fatty
+
+94
+00:08:14,600 --> 00:08:19,080
+acids سلاسل غير متفرعة سلسلة طويلة واضحة مافيها
+
+95
+00:08:19,080 --> 00:08:24,690
+branchingand contain an even number of carbon
+
+96
+00:08:24,690 --> 00:08:29,890
+atoms فيهم عدد ال carbon atoms عدد إيش زوجة الان
+
+97
+00:08:29,890 --> 00:08:34,010
+ال unsaturated acids أول ما أبدأ أقول double bond
+
+98
+00:08:34,010 --> 00:08:39,410
+كلمة ال double bond ارتبطت الذهن بcis و trans او z
+
+99
+00:08:39,410 --> 00:08:46,090
+و e اه unsaturated acids usually have the cis or z
+
+100
+00:08:46,090 --> 00:08:50,720
+configurationالـ Unsaturated بيكون ال
+
+101
+00:08:50,720 --> 00:08:56,020
+configuration فيهم إيش زد يعني ال .. ال أتشز بيجوا
+
+102
+00:08:56,020 --> 00:09:01,420
+على جهة و ال carbons على جهة التانية الآن they
+
+103
+00:09:01,420 --> 00:09:03,720
+have lower boiling points than the corresponding
+
+104
+00:09:03,720 --> 00:09:08,260
+saturated ones شوفنا من خلال القيم أن ال
+
+105
+00:09:08,260 --> 00:09:13,860
+unsaturated نقاط الانسهار بتاعتهم أقل من إيش أقل
+
+106
+00:09:13,860 --> 00:09:17,060
+من ال saturated ممتاز
+
+107
+00:09:20,030 --> 00:09:24,490
+الان بنجي للسؤال الأول ليش هدولة solids والتانين
+
+108
+00:09:24,490 --> 00:09:31,420
+liquids اتطلعوا معايا لو اتخيلت انا هذا شكللـ
+
+109
+00:09:31,420 --> 00:09:35,200
+triglycerides يعني هذا الجزء الجليسرين و هذا الاشي
+
+110
+00:09:35,200 --> 00:09:39,720
+الزهري هو ال oxygen و بعد هيك في عندي تلت سلاسل
+
+111
+00:09:39,720 --> 00:09:45,560
+طويلة سلسلة تنتين تلاتة الان هذه السلاسل لما تكون
+
+112
+00:09:45,560 --> 00:09:50,340
+مشبعة لما تكون مشبعة بشكل عام بنتخيلها بهذا الشكل
+
+113
+00:09:50,340 --> 00:09:55,820
+المستقيم الان لاحظوا كيف شكل المركب هو شكل منتظم
+
+114
+00:09:56,070 --> 00:10:01,290
+قالم المركب الشكل تبعه منتظم معناه ذلك ان الجزيئات
+
+115
+00:10:01,290 --> 00:10:05,930
+بتيجي فوق بعضها بشكل جيد تترتب فوق بعضها في الحالة
+
+116
+00:10:05,930 --> 00:10:10,450
+الصلبة وهذا اللي بيخليها تكون ايه اش solids الان
+
+117
+00:10:10,450 --> 00:10:16,410
+لو فقط واحدة من هدولة صار فيها double bond يعني لو
+
+118
+00:10:16,410 --> 00:10:20,790
+كان عندى ال triglycerides مديش اقول التلاتة فيهم
+
+119
+00:10:20,790 --> 00:10:23,670
+double bonds خليني اقول هذه saturated و هذه
+
+120
+00:10:23,670 --> 00:10:28,530
+saturated واحدة بسقولت يكون فيها double bond و ال
+
+121
+00:10:28,530 --> 00:10:31,550
+double bond اللي بده تكون فيها إيش بده تكون sis
+
+122
+00:10:31,550 --> 00:10:35,990
+هتصير بهذا الشكل اتطلع من عندها هاي ال sis اللي
+
+123
+00:10:35,990 --> 00:10:40,750
+موجود فيها هاي ال double bond و هذا الجزء هاي أنا
+
+124
+00:10:40,750 --> 00:10:45,690
+carbon و أنا carbon على نفس الجهة هذا الشكل عمل
+
+125
+00:10:45,690 --> 00:10:53,030
+إيش فيها انتناقةواضح؟ الآن هذا الانفناق حافظ على
+
+126
+00:10:53,030 --> 00:10:58,750
+الشكل المنتظم للجزيء ولا بطل الجزيء منتظم؟ بطل
+
+127
+00:10:58,750 --> 00:11:02,830
+الجزيء منتظم ولذلك لما تيجي الجزيقات بتنحط فوق بعض
+
+128
+00:11:02,830 --> 00:11:07,130
+في solid lattice في الشبكة عشان تكون المركب الصلب
+
+129
+00:11:07,130 --> 00:11:11,450
+مابتبعدش فوق بعض جيدا، مابتكونش متراسة فوق بعض
+
+130
+00:11:11,450 --> 00:11:16,630
+البعض فالمادة بتحول إلى إيش؟ إلى liquid أو بتنخفض
+
+131
+00:11:16,630 --> 00:11:23,240
+نقاط انصحارهاولذلك هنا احنا انا شفنا ال space
+
+132
+00:11:23,240 --> 00:11:26,860
+filling and schematic model of glycerol التسمية
+
+133
+00:11:26,860 --> 00:11:30,380
+بناخدها tri-palmitate هذا من ال palmitic acid يعني
+
+134
+00:11:30,380 --> 00:11:35,380
+كام كربون؟ 16 اللي متذكرين هذا المشبع ايش ماله؟
+
+135
+00:11:35,380 --> 00:11:41,520
+كان regular كان منتظم بينما لاحظوا معي هنا هذا
+
+136
+00:11:41,520 --> 00:11:46,680
+اللي فيه بس واحدغير مشبع، في double bond، راح
+
+137
+00:11:46,680 --> 00:11:50,220
+الانتظام، الآن اتخيلوا انه لو اكثر من واحد في
+
+138
+00:11:50,220 --> 00:11:53,480
+double bonds، اتخيل لو هذا فيه اكثر من double
+
+139
+00:11:53,480 --> 00:11:58,200
+bond، وكل double bond فيهم صار أشبه بإيش؟
+
+140
+00:12:00,430 --> 00:12:05,610
+لأ صار أشبه حقيقة .. صار أشبه حقيقة بالفكرة اللي
+
+141
+00:12:05,610 --> 00:12:11,730
+أخدناها لما درسنا ال ال can's ال chain ال can's و
+
+142
+00:12:11,730 --> 00:12:15,610
+ال branch ال can's و قولنا أن ال chain they have
+
+143
+00:12:15,610 --> 00:12:20,810
+higherboiling point و melting point than ال branch
+
+144
+00:12:20,810 --> 00:12:25,610
+ليش؟ لأن ال branch أصبح شكلهم زي إيش؟ زي الكرة
+
+145
+00:12:25,610 --> 00:12:30,510
+بطلوا منتظمين فوق بعضهم البعض، واضح؟ لما أخدنا
+
+146
+00:12:30,510 --> 00:12:33,510
+قولنا مين، إله ال boiling point أعلى، ال chain ولا
+
+147
+00:12:33,510 --> 00:12:39,770
+ال branch؟لأن ال branch بطل شكله منتظم الفكرة
+
+148
+00:12:39,770 --> 00:12:43,890
+بالانتظام، الآن هذا اللي في double bonds نفس
+
+149
+00:12:43,890 --> 00:12:48,250
+الفكرة زي ال branch، يعني لاحظوا أنه لو كان هنا في
+
+150
+00:12:48,250 --> 00:12:52,990
+branch مش هتعمل هيك وتقضي على الانتظام اللي كان
+
+151
+00:12:52,990 --> 00:12:59,180
+موجود، الآن هذا الكلام اللي عملته double bondفال
+
+152
+00:12:59,180 --> 00:13:03,560
+branching بيقضي على الانتظام ووجود ال cyst double
+
+153
+00:13:03,560 --> 00:13:07,240
+bond بهذا الشكل ايضا قضى على الانتظام فالفكرة
+
+154
+00:13:07,240 --> 00:13:12,780
+العامة في الحالتين لما نقول ان ال kids بشكل عام
+
+155
+00:13:12,780 --> 00:13:16,060
+انه ال branch they have lower boiling points and
+
+156
+00:13:16,060 --> 00:13:20,150
+melting points because they are irregularالان هنا
+
+157
+00:13:20,150 --> 00:13:24,550
+الـ triglycerides that contain unsaturated fatty
+
+158
+00:13:24,550 --> 00:13:27,470
+acids they have lower boiling point and melting
+
+159
+00:13:27,470 --> 00:13:31,990
+point because they are irregular من وين اجت ال
+
+160
+00:13:31,990 --> 00:13:36,330
+irregularity اللي فيهم، عدم الانتظام من وجود ال
+
+161
+00:13:36,330 --> 00:13:39,370
+double bond و ال cis configuration اللي موجود
+
+162
+00:13:39,370 --> 00:13:44,450
+فيها، واضح؟ الان هذا الكلام بيفرق عندي وين؟ بيفرق
+
+163
+00:13:44,450 --> 00:13:49,870
+عندي وين؟ال oil however are liquid بيصير في عندى
+
+164
+00:13:49,870 --> 00:13:56,350
+اشي اسمه بالمطبخ خلينا نقول شغلتين بيصير في عندكم
+
+165
+00:13:56,350 --> 00:14:01,010
+زيت، زيت الجلي، زيت عباد الشمس، زيت الصوية اللي
+
+166
+00:14:01,010 --> 00:14:06,290
+بتسموه searage، هذا liquid و بيصير في عندكم صلب،
+
+167
+00:14:06,290 --> 00:14:11,260
+السمنة والزبدةملاحظين انتوا هدولة ماشي بيفرجوا
+
+168
+00:14:11,260 --> 00:14:17,240
+ببعض، السمنة والزبدة saturated،
+
+169
+00:14:17,240 --> 00:14:21,650
+الزيت اللي فيه ال double bondsالزيت اللي فيه ال
+
+170
+00:14:21,650 --> 00:14:25,130
+double bonds عشان هيك صار liquid, oils however are
+
+171
+00:14:25,130 --> 00:14:32,190
+liquids because they contain lower percentage of
+
+172
+00:14:32,190 --> 00:14:35,230
+unsaturated .. higher percentage عفوا .. higher
+
+173
+00:14:35,230 --> 00:14:38,490
+percentage of unsaturated fatty acids إذا لو
+
+174
+00:14:38,490 --> 00:14:43,310
+بيناقول مين اللي فيه ال double bonds؟ ال oil ولا
+
+175
+00:14:43,310 --> 00:14:48,010
+ال fat؟ السمنة والزبدة بيناقول عنهم fatsالزيت
+
+176
+00:14:48,010 --> 00:14:51,170
+والسيرش .. زيت الزتون والسيرش .. بنقول عنهم إيش؟
+
+177
+00:14:51,170 --> 00:14:54,830
+Oil .. ال oil هو اللي فيه ال double bonds .. و ال
+
+178
+00:14:54,830 --> 00:14:59,150
+double bonds هي اللي خفضت إيش نقطة انسهاره .. الآن
+
+179
+00:14:59,150 --> 00:15:03,050
+لاحظوا معاك ان انتوا اتعلمتوا كيميا .. ان انتوا
+
+180
+00:15:03,050 --> 00:15:08,300
+اتعلمتوا كيميااتعلمتوا ان ال double bond ممكن
+
+181
+00:15:08,300 --> 00:15:14,140
+نعملها ايش؟ hydrogenation نعملها single bond الان
+
+182
+00:15:14,140 --> 00:15:21,060
+لو اعملت لهذا المركب hydrogenation هذا زيت اعملت
+
+183
+00:15:21,060 --> 00:15:25,300
+هدرجة اللي هو شو بيصير؟ بيصير solid بيصير سمنة
+
+184
+00:15:25,300 --> 00:15:30,830
+فالسمنة تنتج من هدرجة الزيوتبس حطوا هنا هيدروجين و
+
+185
+00:15:30,830 --> 00:15:37,190
+هيدروجين، هذا صار saturated فحولت ال oil إلى fat،
+
+186
+00:15:37,190 --> 00:15:42,750
+سر السمنة والزبدة واضح اذا وين؟ بتيجي بالظبط فكرة
+
+187
+00:15:42,750 --> 00:15:49,070
+الهدرجة، الهدرجة بتحول السائل إلى صلب، في ناس
+
+188
+00:15:49,070 --> 00:15:52,030
+بيحبوا الشغلات الصلبة، يتعاملوا معها،
+
+189
+00:15:52,030 --> 00:15:57,540
+hydrogenationواضح؟ اتعلمنا ان ال hydrogenation على
+
+190
+00:15:57,540 --> 00:16:01,060
+ال double bond بيحول ال double bond إلى single
+
+191
+00:16:01,060 --> 00:16:05,620
+bond هاي ال unsaturated صار saturated معناه ذلك ال
+
+192
+00:16:05,620 --> 00:16:11,520
+liquid صار solid لأنه غير المنتظم بسبب ال double
+
+193
+00:16:11,520 --> 00:16:15,840
+bond سيصبح منتظم بعد أن تذهب ال double bond واضحة
+
+194
+00:16:15,840 --> 00:16:16,480
+الفكرة؟
+
+195
+00:16:18,930 --> 00:16:23,230
+ما بنعملش عملية عكسية العملية اللى موجودة ال هدرجة
+
+196
+00:16:23,230 --> 00:16:29,310
+مش العكسي السمنة لما بتكويها تصير سائل فاطوها على
+
+197
+00:16:29,310 --> 00:16:34,810
+النار سايحوها على النار هذا تسخين اسمه بس أنا بحكي
+
+198
+00:16:34,810 --> 00:16:41,230
+على هدرجة واضح؟ الآن هنا بتجيني مشكلة جديدة هنا
+
+199
+00:16:41,230 --> 00:16:46,630
+بتجيني مشكلة جديدة وانتبهوا لها جيدا انتبهوا لها
+
+200
+00:16:46,630 --> 00:16:52,820
+جيدا لأنها مشكلة خطيرةالان زي ما اتفقنا احنا ان
+
+201
+00:16:52,820 --> 00:16:57,480
+الزيوت بشكل عام فيها double bonds وال double bonds
+
+202
+00:16:57,480 --> 00:17:04,580
+ايش ال configuration فيها سيس الان لو يا ترىنتيجة
+
+203
+00:17:04,580 --> 00:17:09,440
+عمل كيميائي أو عمل إنساني أو تسخين زائد السس اتحول
+
+204
+00:17:09,440 --> 00:17:13,460
+ل Trans بالحرارة احنا قلنا بالوضع الطبيعي بتتحولش
+
+205
+00:17:13,460 --> 00:17:17,820
+يعني حرارة الغرفة بدون تفاعلات كيميائية بدون تسخين
+
+206
+00:17:17,820 --> 00:17:24,460
+السس Trans are not interconvertable easyب .. ب ..
+
+207
+00:17:24,460 --> 00:17:28,340
+ب .. ليش؟ لأن الدوران حوالين ال double bond صعب مش
+
+208
+00:17:28,340 --> 00:17:34,080
+سهل لكن بالتسخين أو بعوامل كيميائية ممكن تتم
+
+209
+00:17:34,080 --> 00:17:38,560
+العملية؟ ممكن، بالذات بالتسخين طب وين احنا بنسخن
+
+210
+00:17:38,560 --> 00:17:43,820
+اكتر اشيء؟ لما نجلي بال series الآن جاليا مرة
+
+211
+00:17:43,820 --> 00:17:49,210
+واحدةزي ما بتجلو بيضة مش مشكلة تحطوا زيت زاتون و
+
+212
+00:17:49,210 --> 00:17:53,670
+البيضة دقيقة وقال ماشي لكن الناس اللي بيجلو
+
+213
+00:17:53,670 --> 00:18:00,510
+بالسيرج عشر مرات البطاطا و الفلافل معناه ذلك ان
+
+214
+00:18:00,510 --> 00:18:05,090
+معها التسخين نسبة كبيرة جدا من ال ces ممكن تصير
+
+215
+00:18:05,090 --> 00:18:09,750
+ايش؟ Trans الان ال Trans compounds are
+
+216
+00:18:09,750 --> 00:18:15,660
+carcinogenic ال Trans مصارطنينهم لاحظين و لذلك
+
+217
+00:18:15,660 --> 00:18:22,820
+يحذر من القلي المتكرر في الزيوت يعني مش شطارة انه
+
+218
+00:18:22,820 --> 00:18:27,840
+رابط البيت والله بتجلي مرة مارتين تلاتة عشرة او
+
+219
+00:18:27,840 --> 00:18:32,700
+الناس اللي بيشتغلوا في الشوارع او المطاعم بيجلوا
+
+220
+00:18:32,700 --> 00:18:36,240
+عشر مرات ما هو كل ما احنا جاعدين بنسخن على السيرج
+
+221
+00:18:36,240 --> 00:18:40,520
+و كل ما بنجلي فيه بزيادة كل ما بنحول double bones
+
+222
+00:18:40,520 --> 00:18:46,130
+اكترنتيجة الحرارة من cis إلى trans كل ما بيصير
+
+223
+00:18:46,130 --> 00:18:50,350
+الإنسان طبعا هياخد مع الأشياء المجلية زيوت كمان و
+
+224
+00:18:50,350 --> 00:18:56,550
+هذه الأشياء fatty acids، انتبهوا معي، fatty acids
+
+225
+00:18:56,550 --> 00:19:03,430
+with trans bonds are carcinogenic، مسارتمينو لذلك
+
+226
+00:19:03,430 --> 00:19:08,350
+يعني اكثر من مرة و تانية ما اتجربوش تجلو انما انه
+
+227
+00:19:08,350 --> 00:19:13,910
+الزيت بينجل فيه ايام و ليالي كل هذا الكلام يعتبر
+
+228
+00:19:13,910 --> 00:19:18,430
+كلام إيش خاطر الآن لاحظوا معاك انه برضه عملية
+
+229
+00:19:18,430 --> 00:19:26,120
+الهدرجة برضه عملية الهدرجة عملية كيميائيةبنحول
+
+230
+00:19:26,120 --> 00:19:32,420
+فيها احنا نسبة كبيرة من ال double bonds إلى single
+
+231
+00:19:32,420 --> 00:19:36,140
+bonds يعني جاعدين احنا نحول double bond إلى single
+
+232
+00:19:36,140 --> 00:19:39,800
+bond هذه ال double bond اللي احنا بنحولها sis ولا
+
+233
+00:19:39,800 --> 00:19:44,680
+trans؟ sisالان هذه ال هدرجة لما بنحكي عن زيت مش زي
+
+234
+00:19:44,680 --> 00:19:49,440
+مركب كيميائي يعني مش عملية سهلة عادة ما بتتمش على
+
+235
+00:19:49,440 --> 00:19:53,840
+كل ال double bonds لكن بتعمل نسبة كبيرة منهم واضحة
+
+236
+00:19:53,840 --> 00:19:59,820
+الفكرة؟ الان في هذه الأثناء بعض ال six double
+
+237
+00:19:59,820 --> 00:20:03,000
+bonds بيظلهم six يعني ما بيصلهمش الدور انهم ايش
+
+238
+00:20:03,000 --> 00:20:08,240
+انه يصيرلهم هدرجة وبعض ال six منهم بتتحولوا إلى
+
+239
+00:20:08,240 --> 00:20:16,060
+transوبالتالي بتصير الهدرجة أيضا عاملة مشكلة مش من
+
+240
+00:20:16,060 --> 00:20:20,040
+منطقة ان هي حولت ال double bond إلى single bond
+
+241
+00:20:20,040 --> 00:20:25,580
+يعني لو ان هي بشكل نظيف ودقيق ومتقن حولت ال double
+
+242
+00:20:25,580 --> 00:20:29,320
+bonds إلى single bonds يعني حولت الزيت إلى سمنة
+
+243
+00:20:29,320 --> 00:20:35,410
+مافيش مشكلةلكن المشكلة ان هذه الهدرجة غالبا بتكون
+
+244
+00:20:35,410 --> 00:20:40,410
+غير كاملة لحد معين بيضل شوية SIS BONS ونتيجة
+
+245
+00:20:40,410 --> 00:20:45,750
+التفاعل الكيميائي بعض ال SISBONS بيصيروا Trans
+
+246
+00:20:45,750 --> 00:20:54,780
+واضح؟ ولذلك اليومصار يعني في دول معينة يجبروا
+
+247
+00:20:54,780 --> 00:20:59,920
+الشركات المصنعة انه تعمل فحوصات و انه على نفس
+
+248
+00:20:59,920 --> 00:21:05,920
+الزبدة و على نفس السمنة تكتب جداش نسبة لترانس فيها
+
+249
+00:21:06,870 --> 00:21:10,710
+والمواطن لازم يعرف اقل تقدير انتوا الان كمتعلمين
+
+250
+00:21:10,710 --> 00:21:16,130
+انه كل ما نسبة لل Trans بتزيد كل ما المركب بيكون
+
+251
+00:21:16,130 --> 00:21:22,750
+ايش اخطر كل ما المركب بيكون carcinogenic واضح؟
+
+252
+00:21:22,750 --> 00:21:30,570
+الان بنيجي لكيف يا ترى بنسمي ال triglycerides
+
+253
+00:21:30,570 --> 00:21:37,170
+خلينا ننتبه لشغلةإنهم لـ triglycerides عبارة عن
+
+254
+00:21:37,170 --> 00:21:44,870
+glycerol صح؟ حامل كام fatty acid؟ تلاتة، الآن لـ
+
+255
+00:21:44,870 --> 00:21:49,570
+triglycerides نوعين،
+
+256
+00:21:49,570 --> 00:21:53,790
+ع طول، أي واحدة بتقدر تقولي شو النوعين، انتظر،
+
+257
+00:21:53,790 --> 00:21:59,250
+ممكن يكونوا متماثلين، يعني فيهم نفس ال fatty acid
+
+258
+00:22:00,450 --> 00:22:04,870
+واضح؟ يعني اربعتاش اربعتاش اربعتاش مشبه او ستاش
+
+259
+00:22:04,870 --> 00:22:10,890
+ستاش ستاش مشبه وممكن يكونوا غير متماثلين صارت
+
+260
+00:22:10,890 --> 00:22:13,830
+الأفكار شبيهة بأشياء أخدتها زي لما أخدنا ال ether
+
+261
+00:22:13,830 --> 00:22:18,250
+متماثل وغير متماثل زي ما أخدنا ال anhydride متماثل
+
+262
+00:22:18,250 --> 00:22:22,650
+وغير متماثل كمان ال triglycerides ممكن يكونوا
+
+263
+00:22:23,260 --> 00:22:28,120
+Simple يعني متماثلين أو Mixed Mixed يعني مخلطين
+
+264
+00:22:28,120 --> 00:22:32,680
+يعني يكون هذا 16 هذا 18 هذا 18 فيه double bond
+
+265
+00:22:32,680 --> 00:22:40,160
+واضح؟ الآن أكيد لما بدنا نسمي لو كانوا متماثلين
+
+266
+00:22:40,160 --> 00:22:46,220
+هنذكر اسم الفاتئاسد لمرة واحدة و لو كانوا غير
+
+267
+00:22:46,220 --> 00:22:51,530
+متماثلين بدنا نذكر إيش؟الثلاث أسماء اللي موجودة مش
+
+268
+00:22:51,530 --> 00:22:55,890
+هذه لازم تكون الفكرة العامة الآن بشكل عام ك common
+
+269
+00:22:55,890 --> 00:23:01,070
+name وخلينا نبدأ بال common name للمتماثلين لو كان
+
+270
+00:23:01,070 --> 00:23:07,970
+ال fatty acid ال 12 اللي هو اللوريك أسد تمام بنسمي
+
+271
+00:23:07,970 --> 00:23:10,630
+المركب Trilaurin
+
+272
+00:23:13,300 --> 00:23:19,580
+واضح؟ إذا من ال acid lauryl بحط إيش؟ lauryl tri
+
+273
+00:23:19,580 --> 00:23:27,660
+-lauryl طيب لو كان stearic tri-stearic يعني لاحظوا
+
+274
+00:23:27,660 --> 00:23:35,300
+معي كان ال acid الأصلي lauryl لما عملت منه ال tri
+
+275
+00:23:35,300 --> 00:23:41,860
+-glyceride ضفت كلمة trialهذه إجت جديدة اللورك
+
+276
+00:23:41,860 --> 00:23:50,100
+خلّيت منها لور و حطيت لها إيش؟ حطيت لها in بدل اك
+
+277
+00:23:50,100 --> 00:23:58,260
+in ال try لورن طيب من ال steerك المتماثل try
+
+278
+00:23:58,260 --> 00:24:06,150
+steering من الأوليك المتماثل try أولينواضح؟
+
+279
+00:24:06,150 --> 00:24:10,870
+ترايقليا ولاحظوا على طول طبعا هيبين معاكم كيف
+
+280
+00:24:10,870 --> 00:24:14,890
+لتراي لاورين مثلا ال melting point له لأن كل ال
+
+281
+00:24:14,890 --> 00:24:20,510
+fatty acids تبعته مشبعة خمسة واربعين هذا
+
+282
+00:24:20,510 --> 00:24:27,490
+لترايستيرين واحد وسبعين الان لو سألت واحدة منكم لو
+
+283
+00:24:27,490 --> 00:24:31,650
+سألت واحدة منكم ليش لتراي لاورين خمسة واربعين و
+
+284
+00:24:31,650 --> 00:24:37,120
+لترايستيرين واحد وسبعينالسلسلة أطول، الموليكولا
+
+285
+00:24:37,120 --> 00:24:41,400
+رويت، الكلمتين صح، التنين مشبع، مشبع، بطل، التشبع
+
+286
+00:24:41,400 --> 00:24:47,300
+هو الفارق، فقط طول السلسلة، أه، لكن لما هنا أجيت
+
+287
+00:24:47,300 --> 00:24:53,430
+18 و 18و حطيت تلاتة double bonds يعني خصام ست
+
+288
+00:24:53,430 --> 00:24:56,410
+هيدروجينات مش المشكلة بفرق ال molecular weight
+
+289
+00:24:56,410 --> 00:25:00,290
+يعني ست وحدات في جزاء كبير زي هذا في ال molecular
+
+290
+00:25:00,290 --> 00:25:04,550
+weight ماسهمهم مش فرق لكن المشكلة حقيقة لما أنا
+
+291
+00:25:04,550 --> 00:25:11,450
+بنزل هذا 18 و هذا 18 قليل ال 18 في one double bond
+
+292
+00:25:11,450 --> 00:25:16,970
+لما بنزل من 71 ل 4 هذا مش فاتقش التغير في ال
+
+293
+00:25:16,970 --> 00:25:21,280
+molecular weightهذا نتيجة وجود ال double bonds،
+
+294
+00:25:21,280 --> 00:25:24,300
+ليش؟ لأن وجدت لو بدي أجي هنا، بدي أعمل هذه ال
+
+295
+00:25:24,300 --> 00:25:26,840
+double bonds زي هيك و زي هيك، بعدين هذه زي هيك و
+
+296
+00:25:26,840 --> 00:25:34,010
+زي هيك، بعدين هذه، صار إيش؟ زي الكرةالجزيق وجده
+
+297
+00:25:34,010 --> 00:25:39,090
+بده يصير زي كرة كيف بده يكون منتظم في solid state
+
+298
+00:25:39,090 --> 00:25:44,550
+واضح الفكرة فلما بده أقول ليش ال triolين لو بده
+
+299
+00:25:44,550 --> 00:25:49,710
+أجي أسألكم ال triolين have lower melting point
+
+300
+00:25:49,710 --> 00:25:54,770
+than tristerine because of the presence of the
+
+301
+00:25:54,770 --> 00:26:00,230
+double bonds or because it is unsaturated واضح
+
+302
+00:26:00,230 --> 00:26:05,250
+الفكرةو هذا وجود ال double bond أو ال unsaturation
+
+303
+00:26:05,250 --> 00:26:09,790
+خلّاه regular ولا irregular؟ irregular بطل منتظم
+
+304
+00:26:09,790 --> 00:26:14,070
+بطل زي .. زي حجار الطوب المنتظمة كيف بتصفق بعض
+
+305
+00:26:14,070 --> 00:26:18,870
+بشكل قوى بينما حجار مش منتظمة بتضل إيش؟ توجع أو
+
+306
+00:26:18,870 --> 00:26:26,600
+ألعاب الأطفال اللي بيسموها ال Legoالان موضوع
+
+307
+00:26:26,600 --> 00:26:30,780
+الهيدروجينيشن of vegetable oils حكينا قولنا ان
+
+308
+00:26:30,780 --> 00:26:36,420
+احنا ممكن ناخد ال oil ويصير زبدة او سمنة
+
+309
+00:26:36,420 --> 00:26:40,120
+بالهيدروجينيشن تحويل ال double bond الى single
+
+310
+00:26:40,120 --> 00:26:42,780
+bond هذا الكلام برفع ال melting point بيحول ال
+
+311
+00:26:42,780 --> 00:26:47,380
+liquid الى solid الهيدروجينيشن عادة بتنفي وجود
+
+312
+00:26:47,380 --> 00:26:52,360
+الهيدروجين و نكلكتاليست و heat لكن هناك خطورة
+
+313
+00:26:52,360 --> 00:26:54,420
+مصاحبة للهيدروجينيشن
+
+314
+00:26:56,690 --> 00:27:02,110
+تحويل بعض ال sis bonds إلى trans يعني التحويل من
+
+315
+00:27:02,110 --> 00:27:05,630
+sis إلى saturated أو من double bond إلى saturated
+
+316
+00:27:05,630 --> 00:27:10,750
+هذا مافيش فيه مشكلة لكن كتفاعل جانبي بعض ال sis
+
+317
+00:27:10,750 --> 00:27:15,450
+بصير trans هنا توجد المشكلة
+
+318
+00:27:16,590 --> 00:27:21,350
+الان مرة تانية نرجع لل simple and mixed
+
+319
+00:27:21,350 --> 00:27:25,210
+triglycerides اللي هي المتماثلة و غير المتماثلة
+
+320
+00:27:25,210 --> 00:27:32,490
+اتفقنا احنا ان المتماثل بنعطي اسم common name
+
+321
+00:27:32,490 --> 00:27:38,470
+trystyrian يعني هذا 18 اذا ايش الحامض تبعه؟ Styric
+
+322
+00:27:38,470 --> 00:27:44,190
+Styric Styric فالمركب trystyrian طيب لو كنا بنسمي
+
+323
+00:27:44,190 --> 00:27:51,210
+ايوبكيعني Triglycerides is a common name و أنا
+
+324
+00:27:51,210 --> 00:27:55,470
+مرات بجيبلكوا سؤال في الامتحان .. بجيبلكوا سؤال في
+
+325
+00:27:55,470 --> 00:28:00,810
+الامتحان ال Triglycerides is also called .. or the
+
+326
+00:28:00,810 --> 00:28:06,830
+Ayurvedic name of Triglycerides is .. الآن عشان
+
+327
+00:28:06,830 --> 00:28:11,650
+نجاوبه صح احنا قولنا ال Triglycerides they are
+
+328
+00:28:11,650 --> 00:28:18,550
+Easter'sEaster صح ولا لأ؟ كيف أنا كنت أسمي ال
+
+329
+00:28:18,550 --> 00:28:22,970
+Easter؟ خليني أتذكر كيف أنا كنت أسمي ال Easter،
+
+330
+00:28:22,970 --> 00:28:29,370
+هيني بدي أكتب Easter عشان واحدة تذكرني كيف،
+
+331
+00:28:29,370 --> 00:28:32,690
+هاي Easter، شايفينه اللي على اللوح؟ واحدة تسميه
+
+332
+00:28:32,690 --> 00:28:37,370
+جزء الكحول في الأول
+
+333
+00:28:40,150 --> 00:28:49,150
+مثل هاي جزء الكحول وبعدين جزء الحامض انتوا بتكونوا
+
+334
+00:28:49,150 --> 00:28:52,910
+شايفوني ومن جلة دراستكوا بنزويك أسد ال Easter
+
+335
+00:28:52,910 --> 00:28:58,130
+بنتهي بنزويت مثل بنزويت أسيتات بيوتانويت اه هذا
+
+336
+00:28:58,130 --> 00:29:04,970
+مثل ايش؟ بنزويت اذا تسمية ال Easterلعبوا لو أنكوا
+
+337
+00:29:04,970 --> 00:29:09,030
+بتحاولوا تحفظوا الكيميا كرموز بتتغلبوا لو أنكوا
+
+338
+00:29:09,030 --> 00:29:13,310
+حفظتوا الكيميا أنه تسمية ال Easter مجموعة الكحول
+
+339
+00:29:13,310 --> 00:29:18,690
+في الأول بعدين ال acid منتهي ب إيه؟ إثل أستيت مثل
+
+340
+00:29:18,690 --> 00:29:24,730
+بنزويت فين ال بيوتانويت صح ولا لأ؟ طيب الآن كويس
+
+341
+00:29:24,730 --> 00:29:31,770
+لو إجيت على هذا شو هو جزء الكحول فيه؟ ال glycerin
+
+342
+00:29:32,770 --> 00:29:38,250
+وشو الأحمض؟ الاستيرك أسد مش هذا الحامض و هذا
+
+343
+00:29:38,250 --> 00:29:44,590
+الكحول ولا لأ ايش اول اشي بنذكره؟ جزء الكحول
+
+344
+00:29:44,590 --> 00:29:53,350
+إجليسارين إجليساريل و الاستيرك أسدStraight لكن لأن
+
+345
+00:29:53,350 --> 00:29:58,330
+في عندي منه تلاتة بقول glycerol ال try straight
+
+346
+00:29:58,330 --> 00:30:03,290
+إذا أنا نفس المنطقة ده اسمها ال Easter الكحول في
+
+347
+00:30:03,290 --> 00:30:09,070
+الأول و بعدين النهاية eight و حطيت try لأن عندي كم
+
+348
+00:30:09,070 --> 00:30:16,160
+حامض تلاتةإذا هذا هي جزء الكحول اللي فيه في واحدة
+
+349
+00:30:16,160 --> 00:30:19,140
+منكم مالخومة كتير عشان الكحول مرسوم على اليمين مش
+
+350
+00:30:19,140 --> 00:30:22,660
+على الشمال المهم نذكر الكحول في الأول كيف نرسمه مش
+
+351
+00:30:22,660 --> 00:30:28,360
+مشكلة واضحة الفكرة ولا لأ؟ واضحات؟ يعني هذا لو كنت
+
+352
+00:30:28,360 --> 00:30:35,540
+راسمه بالعكس إيش برضه هسميه؟ واضح؟ شايف هي كناس
+
+353
+00:30:35,540 --> 00:30:40,360
+مرات بهمش بيغرجوا بشبهر ميه؟
+
+354
+00:30:43,590 --> 00:30:46,990
+يعني اتعودتوا انتوا انه هذا نعمله زي هيك او يبدو
+
+355
+00:30:46,990 --> 00:30:53,130
+معكوس لان لما يرسم زي هيك وين جزء الكحول مثل وين
+
+356
+00:30:53,130 --> 00:30:57,250
+جزء الاسد مثل بنزويت مثل بنزويت خلاص يعني الفكرة
+
+357
+00:30:57,250 --> 00:31:01,950
+مش انه بدهم يبينوا هدولة معكوسين دائما لأ لأ مش
+
+358
+00:31:01,950 --> 00:31:06,890
+هذه الفكرة حسب طريقة الرسم يذكر جزء الكحول اولا ثم
+
+359
+00:31:06,890 --> 00:31:10,770
+جزء الحامض منتهي بالنهاية ايه ولذلك هذا هيك ايش
+
+360
+00:31:10,770 --> 00:31:14,780
+بدنا نسميهمثل؟ بنزوية
+
+361
+00:31:18,100 --> 00:31:22,640
+أكيد اكيد طبعا اه ليش مايجيكيش ارسمي نفسي كل هذان
+
+362
+00:31:22,640 --> 00:31:27,800
+الكربونات بترسم ترسم شو وراكم انتوا دافعين رسوم
+
+363
+00:31:27,800 --> 00:31:32,760
+بتكونوا بتتعلموا واضح تسمية ال easter تسمية ال
+
+364
+00:31:32,760 --> 00:31:37,840
+easter ببساطة انه تذكروا جزء الكحول بعدين جزء
+
+365
+00:31:37,840 --> 00:31:42,400
+الحامض المساهي بالنهاية ايش ات فهذا صار glycerol
+
+366
+00:31:42,400 --> 00:31:50,100
+tryStirate هذه فهمناها طيب لو كانوا الأحماض الآن
+
+367
+00:31:50,100 --> 00:31:56,200
+مختلفين يعني صار عنده اللي أنا بسميه إيش mixed
+
+368
+00:31:56,200 --> 00:32:02,760
+triglyceride مرة تانية هحط في الأول جزء الكحول إذا
+
+369
+00:32:02,760 --> 00:32:09,450
+هنا هذا الجزء الكحول هي الجزء اللي جاي من الكحولمش
+
+370
+00:32:09,450 --> 00:32:16,310
+بختلف عليه، الآن الأحماض بدي أذكرهم مرتبين، واحد،
+
+371
+00:32:16,310 --> 00:32:20,950
+اتنين، تلاتة، طبعا هتقولولي إذا عرفنا واحد، بعده
+
+372
+00:32:20,950 --> 00:32:24,270
+بنقول اتنين، تلاتة، يمكن تصير المشكلة عندكم أن هذا
+
+373
+00:32:24,270 --> 00:32:28,730
+واحد، بعدين اتنين، تلاتة، ولا هذا واحد، بعدين
+
+374
+00:32:28,730 --> 00:32:33,800
+اتنين، تلاتةواضح؟ يعني المشكلة أن أذكر واحد، بعد
+
+375
+00:32:33,800 --> 00:32:38,020
+ما أذكر واحد لازم أمشي فيهم إيش، امرتبين، الآن
+
+376
+00:32:38,020 --> 00:32:44,760
+ببساطة بنقول الأصغر والأكثر تشبعا هو اللي بنحطه
+
+377
+00:32:44,760 --> 00:32:49,940
+نمرة واحد يعني لما أنا بدأ أختار وين نمرة واحد،
+
+378
+00:32:49,940 --> 00:32:54,960
+بدأ أختار الأصغر منهم والأكثر تشبعايعني لو لجيت
+
+379
+00:32:54,960 --> 00:32:58,980
+هنا ستة عشر وهنا تمانت عشر مشبعين التنين مين بدي
+
+380
+00:32:58,980 --> 00:33:05,540
+أحطهم؟ ستة عشر الان لو لجيت هنا ستة عشر وهنا تمانت
+
+381
+00:33:05,540 --> 00:33:11,280
+عشر وكمان هذا مشبع الستة عشر الآن بعد ما أحط الستة
+
+382
+00:33:11,280 --> 00:33:16,280
+عشر مامشي فيهم بالترتيب واضح؟ ولذلك هدولة لو انا
+
+383
+00:33:16,280 --> 00:33:22,470
+اجيت اطلعت الستة عشر بال methic acidالـ 18 المشبع
+
+384
+00:33:22,470 --> 00:33:27,790
+استيرك الـ 18 اللي فيه double bond أوليك لما أنا
+
+385
+00:33:27,790 --> 00:33:32,150
+بدي أسميهم بقول glycerin بعدين بجعل بالميتو
+
+386
+00:33:32,150 --> 00:33:38,510
+بالميتو بعدين الاستيرك استيره بعدين على الأوليك
+
+387
+00:33:38,510 --> 00:33:45,490
+أولييت بحط ات في النهاية لاحظوا معي أن الأوليك أن
+
+388
+00:33:45,490 --> 00:33:46,390
+الأوليك
+
+389
+00:33:50,390 --> 00:33:58,870
+الـ O تبعته عليها إيش؟ نجوطين طبعا على الكمبيوتر
+
+390
+00:33:58,870 --> 00:34:03,230
+ممكن تلاقوا الـ O اللي عليها نجوطين و ممكن أنه
+
+391
+00:34:03,230 --> 00:34:06,430
+ماتلاقوهاش، الآن لو مالاجيتوهاش الـ O اللي عليها
+
+392
+00:34:06,430 --> 00:34:08,870
+نجوطين اكتبوها إيش؟
+
+393
+00:34:10,720 --> 00:34:17,820
+والفظوها OE فهي O ممالة إلى الكسر يعني بمنطق
+
+394
+00:34:17,820 --> 00:34:24,480
+التجويد هي O ممالة للكسر و ال A اللي عليها نقطين A
+
+395
+00:34:24,480 --> 00:34:30,400
+ممالة للكسر و ال U اللي عليها نقطين ممالة للكسر
+
+396
+00:34:30,400 --> 00:34:38,300
+كمان ولذلك لما الألمان بيقرؤوا هذه الكلمة أول أول
+
+397
+00:34:39,500 --> 00:34:44,840
+لحظوا الفك كيف بنزل لتحت إمالة للكسر مار عليكم
+
+398
+00:34:44,840 --> 00:34:49,320
+الإمالات ولا لأ؟
+
+399
+00:34:49,320 --> 00:34:55,740
+ولا في عندنا ولا إمالة في القرآن الكريم برواية حفظ
+
+400
+00:34:55,740 --> 00:35:02,450
+عن عاصرهي إمالة واحدة لكن روحوا على روايات تانية
+
+401
+00:35:02,450 --> 00:35:08,870
+زي مثلا الكساء وغير وغيرات كله إمالات واضح؟ أه في
+
+402
+00:35:08,870 --> 00:35:14,550
+القرآن الكريم وقال اركبوا فيها بسم الله مجريها ما
+
+403
+00:35:14,550 --> 00:35:19,490
+تقولوش مجريها هادفرة كسر كامل هي ألف ممالة للكسر
+
+404
+00:35:19,490 --> 00:35:26,690
+بسم الله مجريها ومرساها طبعاعند غير حفظة عن عاصم
+
+405
+00:35:26,690 --> 00:35:32,110
+معظم بيقرأوا باسم الله مجراها بيرجعوها مجراها و
+
+406
+00:35:32,110 --> 00:35:36,530
+مرساها بيحطوهم زي ما .. فهذه قول هذه قوليك قوليك
+
+407
+00:35:36,530 --> 00:35:44,270
+الفك يكون ميل للكسر او تقرأوها ايش اوأو نقرأها OE
+
+408
+00:35:44,270 --> 00:35:50,130
+إذا سهلة تسمية بدي أحط glycerin وإذا كانوا زي بعض
+
+409
+00:35:50,130 --> 00:35:55,330
+بحط ال tri و الحمض eight وإذا كانوا مش زي بعض بدي
+
+410
+00:35:55,330 --> 00:35:58,770
+أذكر التلاتة هقول مين بدي أبدأ واحد و بعدين اتنين
+
+411
+00:35:58,770 --> 00:36:04,210
+تلاتة الواحد هو الأصغر و الأكتر تشبعانيعني لو
+
+412
+00:36:04,210 --> 00:36:07,990
+إجينا اتطلعنا على هذا المثال نتطلع فيه عندنا
+
+413
+00:36:07,990 --> 00:36:13,210
+هاناستيرك أسد وهانا بالميتك أسد وهانا أوليك أسد
+
+414
+00:36:13,210 --> 00:36:17,630
+الآن أنا بأتطلع على الأطراف أنا مقارنتني من أين
+
+415
+00:36:17,630 --> 00:36:21,350
+بدي أبدأ من هذا الطرف و لا من هذا الطرف واضحة
+
+416
+00:36:21,350 --> 00:36:28,690
+الفكرة؟ الآن اتطلعوا من هذا الطرف أوليك 18 غير
+
+417
+00:36:28,690 --> 00:36:34,880
+مشبعاستيرك تمانتعش مشبع تمانتعش و تمانتعش مشبع و
+
+418
+00:36:34,880 --> 00:36:41,320
+غير مشبع من وين بدي أبدأ تمانتعش مشبع تمانتعش مشبع
+
+419
+00:36:41,320 --> 00:36:49,500
+و لذلك هذا المركب لما أنا بدي أسميه إجليساريل
+
+420
+00:36:49,500 --> 00:36:53,720
+بعدين بسيب فراغ مشبولنا في ال Easter بنسيب فراغ زي
+
+421
+00:36:53,720 --> 00:36:59,640
+إتل فراغ أستيتل إجليساريل فراغ استيرو بالميتو
+
+422
+00:37:02,340 --> 00:37:10,300
+واضح؟ الار اتخيلوا لو اجاكم سؤال اجليساريل بالميتو
+
+423
+00:37:10,300 --> 00:37:15,340
+استيروا قليل واجليساريل استيروا بالميتو قليل يعني
+
+424
+00:37:15,340 --> 00:37:20,300
+عكس التانين فيهم حطيت فيهم التلاتة هذا بيبدأ
+
+425
+00:37:20,300 --> 00:37:24,440
+بالميتو بعدين استيره بعدين قليل هذا بيبدأ استيره
+
+426
+00:37:24,440 --> 00:37:30,300
+بعدين بالميتو قليل هدول اش بيكون العلاقة بينهم؟We
+
+427
+00:37:30,300 --> 00:37:37,280
+are surely isomers فش نقاش إنهم isomers الآن أي
+
+428
+00:37:37,280 --> 00:37:41,840
+نوع من ال isomers؟
+
+429
+00:37:41,840 --> 00:37:47,960
+الآن اطلعوا معي هايهم، تلاتة، واحدة تشوفهم ك ..
+
+430
+00:37:47,960 --> 00:37:50,820
+برا الكيميا، برا الكيميا مش هاي ال glycerol وهيو
+
+431
+00:37:50,820 --> 00:37:55,860
+حاملهم التلاتة، حاملهم التلاتة أزرق، أحمر، يعني
+
+432
+00:37:55,860 --> 00:38:01,600
+يجربوا بيصيروا زي أعلام فلسطينأزرق، أحمر، أصمر،
+
+433
+00:38:01,600 --> 00:38:11,200
+أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق،
+
+434
+00:38:11,200 --> 00:38:11,220
+أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر،
+
+435
+00:38:11,220 --> 00:38:11,240
+أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر،
+
+436
+00:38:11,240 --> 00:38:11,720
+أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق،
+
+437
+00:38:11,720 --> 00:38:13,520
+أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر، أحمر،
+
+438
+00:38:13,520 --> 00:38:16,920
+أزرق، أصمر، أحمر، أزرق، أصمر، أحمر، أزرق، أصمر،
+
+439
+00:38:16,920 --> 00:38:22,200
+أحمرمواقع الارتباط اتغيرت، هذا كان شابق في أول
+
+440
+00:38:22,200 --> 00:38:25,980
+كاربون الأزرق والأحمر في التانية، الأحمر صار في
+
+441
+00:38:25,980 --> 00:38:30,540
+الأولى والأزرق في التانية، different bonding، بزن
+
+442
+00:38:30,540 --> 00:38:35,820
+different bonding، اذا structural isomers،
+
+443
+00:38:35,820 --> 00:38:40,040
+different bonding تبعها كمان شغلة، different names
+
+444
+00:38:41,090 --> 00:38:44,950
+واضح؟ عشان ايك، لاحظوا واحد كان اسمه glycerol
+
+445
+00:38:44,950 --> 00:38:48,350
+بالميتو ستيرو أوليات، التاني glycerol ستيرو
+
+446
+00:38:48,350 --> 00:38:51,150
+بالميتو أوليات، الآن هذول أخدوا different names
+
+447
+00:38:51,150 --> 00:38:54,230
+ولا لأ؟ طالما different names، إذا they are
+
+448
+00:38:54,230 --> 00:38:59,470
+structural isomers، ال stereo isomers كانوا ياخدوا
+
+449
+00:38:59,470 --> 00:39:05,780
+نفس الاسميفرقوا بس في البادقة في الانانشو مارز R
+
+450
+00:39:05,780 --> 00:39:11,680
+ولا S ولا كذا وفي الدياستيريو مارز S أو Trans أو Z
+
+451
+00:39:11,680 --> 00:39:16,340
+أو E same name وكانوا ياخدوا different descriptive
+
+452
+00:39:16,340 --> 00:39:20,680
+البادقة اللي بتوصف الشكل الفراغي مش سميناها
+
+453
+00:39:20,680 --> 00:39:25,520
+descriptive البادقة ال R أو ال S أو ال Z أو ال E
+
+454
+00:39:25,520 --> 00:39:30,460
+أو ال S أو ال Trans لكن إلهم نفس الاش نفس الإسم
+
+455
+00:39:31,530 --> 00:39:35,470
+الان لاحظوا معاه لو قلنا لكم draw this structure
+
+456
+00:39:35,470 --> 00:39:41,210
+for glyceryl trimeristate اللي هو meristic acid ال
+
+457
+00:39:41,210 --> 00:39:48,210
+14 موجود عندكم بدكوا تحطوهربما من الأخطاء اللي
+
+458
+00:39:48,210 --> 00:39:50,450
+كتير الطلاب بيخطئوها
+
+459
+00:40:19,820 --> 00:40:23,880
+تطلعوا كيف الشكل الصحيح ال O هان هذا جزء الكحول
+
+460
+00:40:23,880 --> 00:40:29,400
+هذا جزء الحامض ال glycerin هو المتصل بال O العادية
+
+461
+00:40:29,400 --> 00:40:33,400
+single bond بعدين ال C double bond O مش العكس هذا
+
+462
+00:40:33,400 --> 00:40:36,340
+من الأخطاء الشائعة لما نقول للطلبة ارسمولنا
+
+463
+00:40:36,340 --> 00:40:41,640
+triglyceride بيروحوا بيرسموليا معكوس واضح؟
+
+464
+00:40:44,360 --> 00:40:49,780
+على أي حال، بهيك تقريبا بننهي اليوم بكرا إجازة عيد
+
+465
+00:40:49,780 --> 00:40:54,740
+العمال، ماعرفش وقتاش بيكون عيد الطلاب، عيدنا يوم
+
+466
+00:40:54,740 --> 00:40:57,280
+نجاحنا
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/6-G8b-zOS0Y.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/6-G8b-zOS0Y.srt
new file mode 100644
index 0000000000000000000000000000000000000000..58a91c948b4eff15b683eef9bd69e922bbb8dc2d
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/6-G8b-zOS0Y.srt
@@ -0,0 +1,1429 @@
+
+1
+00:00:19,520 --> 00:00:23,540
+بسم الله الرحمن الرحيم. المرة الماضية، اتكلمنا في
+
+2
+00:00:23,540 --> 00:00:28,820
+موضوع الـ acidity، وعرفنا بالضبط أيش معنى الأحماض و
+
+3
+00:00:28,820 --> 00:00:35,360
+وضحنا أنه مهم جدًا نعرف أيش معنى الـ pKa  والـ acidity
+
+4
+00:00:35,360 --> 00:00:39,820
+constant، وقلنا كلما الـ pKa قل، كلما الحامض
+
+5
+00:00:39,820 --> 00:00:45,000
+يكون أقوى. بعدها، طرحنا سؤالًا، وأعطينا عليه
+
+6
+00:00:45,000 --> 00:00:49,940
+إجابة عامة، بدون أن ندخل في تفاصيل دقيقة. كان السؤال
+
+7
+00:00:49,940 --> 00:00:54,540
+لماذا نقارن حامضًا مع حامض آخر، لنعرف الأقوى والأضعف؟ بدأً، نعتمد على أيش لما نقارن الأحماض في قوتها؟
+
+8
+00:00:54,540 --> 00:00:59,250
+لما نقارن الأحماض في قوتها.
+
+9
+00:00:59,250 --> 00:01:05,270
+بدي أنظر إلى الأيون السالب الذي يتكون نتيجة تحلل الحمض في الماء. هذا الأيون السالب، بدي الشحنة
+
+10
+00:01:05,270 --> 00:01:10,430
+تبعته تكون أقل ما يمكن. هذا ما نسميه الـ
+
+11
+00:01:10,430 --> 00:01:14,110
+stability للأيون السالب. معنى الـ stability أن
+
+12
+00:01:14,110 --> 00:01:18,470
+الشحنة تكون أقل ما يمكن. الآن، أيش الذي يقلل
+
+13
+00:01:18,470 --> 00:01:21,710
+الشحنة؟ ثلاث تأثيرات: حجم الذي يحمل الشحنة،
+
+14
+00:01:21,710 --> 00:01:27,060
+وممكن شيء نسميه الـ inductive effect، وهو تأثير
+
+15
+00:01:27,060 --> 00:01:30,920
+المساعدة، وممكن شيء نسميه الـ resonance effect.
+
+16
+00:01:30,920 --> 00:01:36,180
+أعطينا بعض الأمثلة، لكن خلينا نؤكد الآن. مثلًا، لو
+
+17
+00:01:36,180 --> 00:01:42,660
+أجينا نقارن الـ phenols مع الكحولات العادية،
+
+18
+00:01:42,660 --> 00:01:48,420
+الأليفاتية. الكحولات، بمعنى أني بدي أقارن ROH مع
+
+19
+00:01:48,420 --> 00:01:54,480
+فنول OH. لاحظوا النقطة الأولى: أنه لما يجي يعمل
+
+20
+00:01:54,480 --> 00:01:59,320
+المقارنة، ويفهم المقارنة، سبّاقًا هو من الحامض أيش كتب؟
+
+21
+00:01:59,320 --> 00:02:04,680
+الأيون السالب. يعني كتب: أنا RO-، و فنول O-.
+
+22
+00:02:04,680 --> 00:02:10,760
+الحكم هو الأيون السالب. الآن، هذا الـ RO-، الشحنة
+
+23
+00:02:10,760 --> 00:02:17,990
+الموجودة عليه ثابتة على الـ oxygen، ما فيش فيها حركة،
+
+24
+00:02:17,990 --> 00:02:22,450
+ما فيش فيها resonance. الـ oxygen ذرة صغيرة، يعني
+
+25
+00:02:22,450 --> 00:02:25,970
+بيقول it cannot carry the negative charge، صعب
+
+26
+00:02:25,970 --> 00:02:29,710
+عليها تحمل الـ negative charge، ولذلك الأيون كله
+
+27
+00:02:29,710 --> 00:02:33,250
+بيكون unstable. فلاحظوا الكلام، أن الـ charge is
+
+28
+00:02:33,250 --> 00:02:37,050
+localized، يعني محمولة على موقع واحد، مش متوزعة.
+
+29
+00:02:37,050 --> 00:02:43,570
+localized، متموضعة، محمولة في موضع واحد. عكسها أيش؟
+
+30
+00:02:43,570 --> 00:02:48,730
+delocalized. فبيصير عندي كلمتين: localized، شيء على
+
+31
+00:02:48,730 --> 00:02:57,550
+موضع واحد، delocalized، زي ما أنا آجي أحمل هيك،
+
+32
+00:02:57,550 --> 00:03:01,550
+بس من يد هذه فقط لا غير. هيك بيكون هذا الحمل
+
+33
+00:03:01,550 --> 00:03:07,590
+localized. الآن، لو كنت بوزعها، بيكون delocalized. واضح؟
+
+34
+00:03:07,590 --> 00:03:13,210
+فإذن نلاحظ أنه في الفينول، الشحنة السالبة في أحد
+
+35
+00:03:13,210 --> 00:03:16,350
+الـ resonance structures على الـ oxygen، لكن لو عملنا
+
+36
+00:03:16,350 --> 00:03:20,450
+حركة إلكترونات، زوج من الإلكترونات بهذا الشكل، و
+
+37
+00:03:20,450 --> 00:03:23,710
+حركنا الرابطة، هنلاحظ أنها ممكن تصير على الـ carbon
+
+38
+00:03:23,710 --> 00:03:26,510
+الموجودة هنا، بحركة ثانية على الـ carbon التي
+
+39
+00:03:26,510 --> 00:03:29,750
+موجودة هنا، بحركة ثالثة على الـ carbon. لاحظوا أنه
+
+40
+00:03:29,750 --> 00:03:34,460
+بطلت الشحنة محمولة على مكان واحد، بطلت localized،
+
+41
+00:03:34,460 --> 00:03:39,000
+صارت delocalized. هذا resonance. واضح، أو
+
+42
+00:03:39,000 --> 00:03:42,400
+delocalization. يعني بيستخدموا كلمة resonance أو
+
+43
+00:03:42,400 --> 00:03:46,900
+delocalization بنفس المعنى. واضح؟ فـ because of the
+
+44
+00:03:46,900 --> 00:03:52,360
+delocalization of the charge in phenoxide ion
+
+45
+00:03:52,360 --> 00:03:56,540
+أو anion. لاحظوا الـ phenyl O-، شو بنسميه؟
+
+46
+00:03:58,860 --> 00:04:02,960
+فينوكسايد. أنا يعني ممكن سبقًا حكينا لكم، هي اللي لو
+
+47
+00:04:02,960 --> 00:04:09,300
+كانت هذه مثل O-، ميثوكسايد، مثل O-، إيثوكسايد،
+
+48
+00:04:09,300 --> 00:04:16,880
+HO-، hydroxide، هيدروكسايد. هيدروكسايد.
+
+49
+00:04:16,880 --> 00:04:17,360
+هيدروكسايد. هيدروكسايد. هيدروكسايد. هيدروكسايد.
+
+50
+00:04:17,360 --> 00:04:20,000
+هيدروكسايد. هيدروكسايد. هيدروكسايد. هيدروكسايد.
+
+51
+00:04:20,000 --> 00:04:20,660
+هيدروكسايد. هيدروكسايد. هيدروكسايد. هيدروكسايد.
+
+52
+00:04:20,660 --> 00:04:22,780
+هيدروكسايد. هيدروكسايد. هيدروكسايد. هيدروكسايد.
+
+53
+00:04:22,780 --> 00:04:27,020
+هيدروكسايد. هيدروكسايد. هيدروكسايد. هيدروكسايد.
+
+54
+00:04:27,020 --> 00:04:30,260
+هيدروكسايد. هيدروكسايد. هيدروكسايد. هيدروكسايد.
+
+55
+00:04:30,260 --> 00:04:37,420
+هيدروكسايد. هيدروكسايد. هيدروكسايد. هيدروكسايد.
+
+56
+00:04:37,420 --> 00:04:43,720
+هيدروكسايد. هيدروكسايد. حوالي ستة عشر، خمسة عشر ونصف وخمسة
+
+57
+00:04:43,720 --> 00:04:47,340
+عشر وتسعة. فلما نجي نسأل: ليش الـ phenols are more
+
+58
+00:04:47,340 --> 00:04:51,140
+acidic than alcohols؟ الجواب: because of resonance،
+
+59
+00:04:51,140 --> 00:04:56,460
+أو because of delocalization of its charge. طبعًا، لو
+
+60
+00:04:56,460 --> 00:05:02,800
+صار عندي nitrophenol، الـ delocalization بيزيد. يعني
+
+61
+00:05:02,800 --> 00:05:07,600
+الشحنة السالبة، بالإضافة إلى أنها ممكن توجد على مواضع
+
+62
+00:05:07,600 --> 00:05:12,500
+كثيرة، كمان بصير بإمكانها توجد على ذرات الـ oxygen
+
+63
+00:05:12,500 --> 00:05:15,260
+بتاعة الـ nitro. فبيصير
+
+64
+00:05:17,450 --> 00:05:22,290
+الـ delocalization للـ negative charge، أيش ماله؟
+
+65
+00:05:22,290 --> 00:05:27,270
+أكثر. بيصير عندي more delocalization، يعني الشحنة
+
+66
+00:05:27,270 --> 00:05:31,350
+موزعة، زي حمل بيحملوا اثنين، ارتاحوا شويّة. طب لو
+
+67
+00:05:31,350 --> 00:05:36,630
+حملوا ثلاثة، أفضل. لو حملوا أربعة، أسهل. واضحة الفكرة؟
+
+68
+00:05:36,630 --> 00:05:42,650
+ففي النيتروفينول، عندي more delocalization، ولذلك نزل
+
+69
+00:05:42,650 --> 00:05:48,190
+الـ pKa للنيتروفينول لـ 7.2 من عشرة. إذًا،
+
+70
+00:05:48,190 --> 00:05:52,510
+which is more acidic؟ الـ nitrophenol is more acidic
+
+71
+00:05:52,510 --> 00:05:57,290
+لأنه فيه more resonance. طب لو صارت trinitrophenol،
+
+72
+00:05:57,290 --> 00:06:02,970
+more and more، بيصل لـ point 25. وبناءً على ذلك،
+
+73
+00:06:02,970 --> 00:06:08,670
+سمينا أيش إحنا؟ pKa لـ trinitrophenol. هذه كلها
+
+74
+00:06:08,670 --> 00:06:12,850
+أمثلة على الـ resonance effect. الآن، لو كنت بدي
+
+75
+00:06:12,850 --> 00:06:17,290
+أمثلة على الـ inductive effect، لو بدأت بالإيثانول،
+
+76
+00:06:17,290 --> 00:06:24,150
+فيه ثلاث مجموعات هيدروجين: CH2OH CH3. طيب، لو حطيت
+
+77
+00:06:24,150 --> 00:06:28,830
+واحدة من الهيدروجين، زي كلور، بتبدأ هذه الكلور تسحب
+
+78
+00:06:28,830 --> 00:06:30,210
+جزءًا من الشحنة.
+
+79
+00:06:32,900 --> 00:06:36,200
+افترضوا أن كلهم فيهم شحنة سالبة، قللت الشحنة
+
+80
+00:06:36,200 --> 00:06:41,580
+السالبة. هذا الـ effect، سحب الشحنة، with drawing of
+
+81
+00:06:41,580 --> 00:06:47,930
+the charge، أو إعطاء شحنة. أيش بنسميه إحنا؟ inductive
+
+82
+00:06:47,930 --> 00:06:51,050
+effect. فالـ inductive effect هو سحب الشحنة، أو
+
+83
+00:06:51,050 --> 00:06:55,470
+إعطاؤها، مش نقلها. الشحنة موجودة هنا، لكن افترض
+
+84
+00:06:55,470 --> 00:07:00,090
+الشحنة هنا عشر وحدات، سحبنا منها وحدتين، الـ Cl التي
+
+85
+00:07:00,090 --> 00:07:05,050
+أنا بتحب السالب، سحبت وحدتين. جديش صافي؟ بدل عشرة،
+
+86
+00:07:05,050 --> 00:07:11,820
+ثمانية. واضح؟ الآن، لو حطيت اثنين Cl، صار عندي more
+
+87
+00:07:11,820 --> 00:07:17,220
+and more with drawing. لو حطيت ثلاث Cl، كلهم
+
+88
+00:07:17,220 --> 00:07:22,160
+بيسحبوا الشحنة السالبة. بناءً على ذلك، الـ effect هنا،
+
+89
+00:07:22,160 --> 00:07:25,480
+لما أنا بقول أن الـ trichloroethanol is more acidic
+
+90
+00:07:25,480 --> 00:07:28,240
+than dichloroethanol، than chloroethanol، than
+
+91
+00:07:28,240 --> 00:07:32,340
+ethanol. هذا أيش اللي بنسميه إحنا؟ inductive effect.
+
+92
+00:07:32,340 --> 00:07:39,750
+واضح؟ لما قررنا الـ RSH و الـ ROH، مين اللي قلنا
+
+93
+00:07:39,750 --> 00:07:45,010
+فيهم أقوى حامضًا؟ RSH. طب الآن بنقول الـ RSH أقوى من
+
+94
+00:07:45,010 --> 00:07:51,310
+الـ ROH، why؟ because of the size. إذًا، هاي نعرفه.
+
+95
+00:07:51,310 --> 00:08:00,410
+طيب، لو بدي أقول الـ ArSH مع الـ ROH، مين أقوى؟
+
+96
+00:08:02,130 --> 00:08:06,990
+because of the size. لاحظوا الـ Ar هنا، والـ Ar هنا
+
+97
+00:08:06,990 --> 00:08:11,890
+فيهم resonance. فبطل الـ resonance هو السبب، يعني الـ
+
+98
+00:08:11,890 --> 00:08:16,150
+aromatic أو البنزين هنا، والبنزين هنا. فينول، و
+
+99
+00:08:16,150 --> 00:08:22,040
+ثيوفينول. الـ Ar عامل مشترك، اللي بيعمل resonance. بناءً
+
+100
+00:08:22,040 --> 00:08:25,900
+على ذلك، لو حد… لو بدنا نجيب سؤال: ArSH is more
+
+101
+00:08:25,900 --> 00:08:30,240
+acidic than ArOH due to resonance. غلط، لأنه هنا فيه
+
+102
+00:08:30,240 --> 00:08:33,680
+resonance، وهنا فيه resonance. طب أيش المختلف؟
+
+103
+00:08:33,680 --> 00:08:41,950
+sulfur و oxygen. إذًا، because of the size. لكن لو أجيت
+
+104
+00:08:41,950 --> 00:08:49,470
+قلت لكم، بدي أقارن ArSH و RSH. لاحظوا الـ sulfur،
+
+105
+00:08:49,470 --> 00:08:53,990
+sulfur the same size. إذًا، وين صار الفرق؟ Ar ولا
+
+106
+00:08:53,990 --> 00:09:00,310
+R؟ إذًا، why؟ because of resonance.
+
+107
+00:09:04,470 --> 00:09:11,150
+لو كنت بدي أقارن ArOH مع ROH، الـ O والـ O نفس
+
+108
+00:09:11,150 --> 00:09:16,870
+الـ size. اللي اختلف R و Ar. إذًا، مين أعلى؟ Ar،
+
+109
+00:09:16,870 --> 00:09:23,650
+because of resonance. واضحة الفكرة؟ لما بنعمل مقارنة،
+
+110
+00:09:23,650 --> 00:09:29,630
+الآن، لو أجيت على هدول كلهم، وقلت بدي أطبق كل
+
+111
+00:09:29,630 --> 00:09:37,500
+الكلام بلغة عربية بسيطة جدًا، بدي أقول: من الأقوى، ومن
+
+112
+00:09:37,500 --> 00:09:44,240
+الأضعف في الأربعة؟ الـ ArSH هو أقوى حاجة. الـ ArSH
+
+113
+00:09:44,240 --> 00:09:51,560
+هو الأقوى، the strongest. والـ ROH هو الأضعف.
+
+114
+00:09:54,370 --> 00:10:00,150
+يعني، لو بقارن الـ alcohols والـ thyols والـ phenols،
+
+115
+00:10:00,150 --> 00:10:04,330
+والـ thiophenols، أقوى واحد فيهم الـ thiophenol، وأضعف
+
+116
+00:10:04,330 --> 00:10:08,710
+واحد فيهم بالحمضية اللي هو أيش؟ الـ alcohol. هذا
+
+117
+00:10:08,710 --> 00:10:14,970
+الكلام بينعكس على التفاعلات الكيميائية. هذا الكلام
+
+118
+00:10:14,970 --> 00:10:19,170
+الآن، أن هذا الأضعف، بينعكس على التفاعلات الكيميائية.
+
+119
+00:10:19,170 --> 00:10:22,990
+وين بينعكس على التفاعلات الكيميائية؟ مش إحنا قاعدين
+
+120
+00:10:22,990 --> 00:10:28,010
+نقول هدول أحماض، مظبوط ولا لأ؟ طول عمرنا بنعرف
+
+121
+00:10:28,010 --> 00:10:35,170
+الجملة الشهيرة: حمض زائد قاعدة، ملح زائد ماء. بناءً على
+
+122
+00:10:35,170 --> 00:10:40,570
+ذلك، لو أجيت أفاعل هدول مثلًا مع قاعدة قوية زي الـ Na
+
+123
+00:10:40,570 --> 00:10:53,890
+OH، زائد NaOH، كلهم. مش هم زائد قاعدة. اه، هلاحظ أن
+
+124
+00:10:53,890 --> 00:10:57,670
+ثلاثة منهم بتفاعل، وبيعطوا ملح زائد ماء. واحد
+
+125
+00:10:57,670 --> 00:11:05,990
+ما بتفاعلش. هذا ما بتفاعلش. هذا بتفاعل. هذا بتفاعل.
+
+126
+00:11:05,990 --> 00:11:11,040
+بتفاعل. واضح؟ طبعًا، لو قلنا لكم اكتبوا المعادلة،
+
+127
+00:11:11,040 --> 00:11:17,080
+عندنا مثال. لو أخذنا هذا الـ ROH زائد NaOH، أيش
+
+128
+00:11:17,080 --> 00:11:24,600
+كتبنا؟ No reaction. لكن لو قلنا RSH زائد NaOH،
+
+129
+00:11:24,600 --> 00:11:29,770
+الـ H مع الـ OH، أيش بيعملوا؟ ماء. طول عمره، والـ RS-
+
+130
+00:11:29,770 --> 00:11:36,350
+مع الـ Na، Na+ RS-. وبنفس الطريقة،
+
+131
+00:11:36,350 --> 00:11:45,830
+بإمكانكم تكتبوا أيش كل الأشياء. RSH
+
+132
+00:11:45,830 --> 00:11:46,050
+مع
+
+133
+00:11:57,410 --> 00:12:03,230
+فاهم الآن؟ دائمًا، إذا وجد عندك مش سؤال، مش سؤالك هذا
+
+134
+00:12:03,230 --> 00:12:08,170
+الـ specific، مش سؤالك هذا الـ specific. لأ، إذا أي
+
+135
+00:12:08,170 --> 00:12:15,110
+شغلة حطيت فيها متغيرين، معناه ذلك مش هيكون عندك ثقة
+
+136
+00:12:15,110 --> 00:12:20,110
+كاملة أنك بتقدر تأخذ الجواب مباشرة إلا من التجربة،
+
+137
+00:12:20,110 --> 00:12:27,210
+وقيمة أيش بتطلع من التجربة؟ الـ pKa. إذا صار عندك
+
+138
+00:12:27,210 --> 00:12:31,910
+متغيرين في سؤالك، أنا بأعتبره جيد، أنه أنت غيرتِ هنا الـ
+
+139
+00:12:31,910 --> 00:12:37,970
+Ar و R، وهنا الـ O والـ S، وسألتِ: مين الأقوى فيهم؟
+
+140
+00:12:37,970 --> 00:12:44,250
+كم متغير عندك؟ اثنين. الحل: أنك تبحثي، تعملي التجربة، و
+
+141
+00:12:44,250 --> 00:12:48,550
+تشوفي الـ pKa لأجل هذا، والـ pKa لأجل هذا، وتعملي المقارنة.
+
+142
+00:12:48,550 --> 00:12:54,180
+ولذلك، في العلم، دائمًا لما بتعملوا المقارنة، بتثبتوا
+
+143
+00:12:54,180 --> 00:12:59,600
+جميع المتغيرات ما عدا متغير واحد. بيصير بإمكانكم
+
+144
+00:12:59,600 --> 00:13:03,420
+تعملوا له مقارنة، وتعملوا له قوانين. يمكن هذا الكلام
+
+145
+00:13:03,420 --> 00:13:08,780
+أكثر شيء مر عليكم في منطقة الغازات. ليش؟ لأن
+
+146
+00:13:08,780 --> 00:13:13,500
+الغازات لها أكثر من متغير: الضغط، والحجم، وعدد
+
+147
+00:13:13,500 --> 00:13:19,790
+المولات، ودرجة الحرارة. أربعة متغيرات في الغازات. واضح؟
+
+148
+00:13:19,790 --> 00:13:23,810
+الآن، الغازات في النهاية كانت بتُجمع بمعادلة: P في V
+
+149
+00:13:23,810 --> 00:13:28,570
+يساوي N في R في T. pressure في volume يساوي number
+
+150
+00:13:28,570 --> 00:13:32,610
+of moles في R، ثابت الغازات، في الـ temperature. الآن،
+
+151
+00:13:32,610 --> 00:13:36,770
+لما كنت قاعد أقول: بدي أقارن الـ volume مع الـ
+
+152
+00:13:36,770 --> 00:13:43,210
+temperature، كنت أحط لنفس الكمية من الغاز، عند نفس
+
+153
+00:13:43,210 --> 00:13:49,550
+الضغط. واضح؟ بعد ذلك، تصبح المقارنة أصعب، تعمل تجربة.
+
+154
+00:13:49,550 --> 00:13:55,930
+الآن، هنا الـ O والـ O مشتركات، الـ R والـ Ar مختلفات. سهل
+
+155
+00:13:55,930 --> 00:14:01,650
+أعطي جوابًا. واضحة الفكرة؟ لكن هنا الـ S أفضل من الـ
+
+156
+00:14:01,650 --> 00:14:07,940
+O، والـ Ar أفضل من الـ R. أيش النتيجة؟ التجربة،
+
+157
+00:14:07,940 --> 00:14:14,040
+المجموعة، التجربة. واضح؟ يعني ما فيش عندك جواب: هذي
+
+158
+00:14:14,040 --> 00:14:16,880
+أفضل من هذي، وهذي أفضل من هذي. طب هذي أفضل من هذي
+
+159
+00:14:16,880 --> 00:14:20,440
+بقديش؟ وهذي أفضل من هذي بقديش؟ عشان يطلع عندي جواب؟
+
+160
+00:14:20,440 --> 00:14:29,160
+لأ، بدك تعملي التجربة. واضح؟ سؤال جيد. الآن لاحظوا معي،
+
+161
+00:14:29,160 --> 00:14:32,340
+هل يا ترى الكيميائي
+
+162
+00:14:33,600 --> 00:14:38,120
+بيستسلم؟ لأ. يعني سبحان الله، زي ما بتقول آية كريمة،
+
+163
+00:14:38,120 --> 00:14:44,820
+وفوق كل ذي علم عليم. واضح؟ يعني إحنا قلنا الكحول
+
+164
+00:14:44,820 --> 00:14:52,580
+هذا زائد NaOH لا يتفاعل. طب الـ NaOH كان تصنيفه
+
+165
+00:14:52,580 --> 00:15:00,380
+strong base، قاعدة قوية. الآن، الـ NaOH is a strong
+
+16
+
+223
+00:20:12,940 --> 00:20:18,520
+كنت على البروبيلن أضيف الماء في وجود H⁺ وين كنت
+
+224
+00:20:18,520 --> 00:20:23,700
+أحط الهيدروجين هنا، الـ O-H هنا، يطلع البروبانول
+
+225
+00:20:23,700 --> 00:20:27,780
+أو بروبانول، أو إيزوبروبانول ما كان يطلع
+
+226
+00:20:27,780 --> 00:20:34,200
+هذا طيب، لو بدنا هذا شو كنا نعمل؟ Anti-Markovnikov
+
+227
+00:20:36,400 --> 00:20:40,420
+كنا نستعمل طريقة الـ boron، الـ BH₃ وتوابعها
+
+228
+00:20:40,420 --> 00:20:46,540
+بترجعوها، واضح؟ إذن الكحولات يمكن أن تُحضر، وأخذنا
+
+229
+00:20:46,540 --> 00:20:51,000
+هذا الكلام بالتفصيل من خلال إضافة الماء على الـ
+
+230
+00:20:51,000 --> 00:20:56,860
+alkenes. برضه طريقة ثانية أخذناها لتحضير الكحولات
+
+231
+00:20:56,860 --> 00:20:59,440
+مين يتذكرها؟
+
+232
+00:21:04,290 --> 00:21:10,270
+الـ RX زائد الماء، أو الـ OH⁻، مش كنا نأخذ هذه
+
+233
+00:21:10,270 --> 00:21:18,110
+المعادلة؟ RX زائد H₂O، in general R-OH، لنيكليوفيليك
+
+234
+00:21:18,110 --> 00:21:23,710
+سابستيتيوشن على الـ ألكيل هالايد، تشابتر ستة سواء كنا نفعله
+
+235
+00:21:23,710 --> 00:21:27,940
+مع نيوترال نيوكليوفايل أو مع charged nucleophile
+
+236
+00:21:27,940 --> 00:21:32,680
+واضح؟ الـ substitution، إذن الطرق العامة
+
+237
+00:21:32,680 --> 00:21:38,340
+لتحضير الكحولات، يا إما من الـ RX بالإبدال، يا إما من
+
+238
+00:21:38,340 --> 00:21:45,840
+الـ alkenes بتفاعل إيش بنسميه؟ الإضافة. ما هو مع
+
+239
+00:21:45,840 --> 00:21:53,100
+الماء؟ تفاعل إضافة (addition reaction). واضح الآن؟ لو
+
+240
+00:21:53,100 --> 00:22:00,470
+أجينا بعد هيك على تفاعلات الكحولات، تفاعلات الكحولات
+
+241
+00:22:00,470 --> 00:22:05,210
+طبعاً في زميلة لكم، بس عشان يعني ما نغمطهاش حقها إن
+
+242
+00:22:05,210 --> 00:22:10,530
+هي منتبهة، قالت من الـ epoxides، كلامها سليم، يعني لما
+
+243
+00:22:10,530 --> 00:22:14,950
+كان يكون عندكم الـ الكين، وأضيف عليه الـ oxygen، أعمل
+
+244
+00:22:14,950 --> 00:22:22,050
+منه epoxide، وبعد هيك لو عملنا ring opening
+
+245
+00:22:22,050 --> 00:22:28,320
+باستعمال الـ nucleophile، كنا نقول R-C-C-OH، ويجي
+
+246
+00:22:28,320 --> 00:22:32,640
+الـ نيوكليوفايل، this is an alcohol. كلامها سليم، ما كانش
+
+247
+00:22:32,640 --> 00:22:39,500
+فيه غلط، واضح؟ لكن منطلقنا إيش؟ الـ الكين، برضه منطلقنا
+
+248
+00:22:39,500 --> 00:22:43,860
+الـ الكين، عملنا إيبوك سايد، وعملنا ring opening. هذا
+
+249
+00:22:43,860 --> 00:22:48,780
+الكلام، ما كان إن شاء الله. الآن لو أجينا على موضوع الـ
+
+250
+00:22:48,780 --> 00:22:56,650
+reactions of alcohols، من تفاعلات الـ alcohols، تفاعل
+
+251
+00:22:56,650 --> 00:23:01,390
+الـ dehydration، معنى الـ dehydration، أو acidic
+
+252
+00:23:01,390 --> 00:23:08,500
+dehydration، نزع الماء في وجود الحمض. نزع الماء في
+
+253
+00:23:08,500 --> 00:23:12,660
+وجود الحمض، هذا إيش اسمه؟ dehydration، حذف الماء في
+
+254
+00:23:12,660 --> 00:23:17,280
+وجود الحمض. الآن بدنا ننتبه هنا لنقطة إنه احنا
+
+255
+00:23:17,280 --> 00:23:22,940
+ممكن نعمل هذا التفاعل بطريقتين تؤديان إلى ناتجين
+
+256
+00:23:22,940 --> 00:23:28,280
+مختلفين، ممكن من نفس الكحول، يعني لو أخذنا الإيثانول
+
+257
+00:23:28,280 --> 00:23:31,240
+كمثال، ننزع من هنا OH
+
+258
+00:23:34,460 --> 00:23:40,300
+OH من كربون مجاورة. هنا رفعنا إيش؟ ماء. لما بنشيل
+
+259
+00:23:40,300 --> 00:23:48,100
+OH مع H، شو ممكن نعمل؟ الألكين. الحد في عكس إيش؟
+
+260
+00:23:48,100 --> 00:23:53,400
+الإضافة. إضافة الماء على الألكين بتاعة الكحول. حد
+
+261
+00:23:53,400 --> 00:23:58,520
+في الـ... إضافة الماء على الألكين تعطي الكحول، وحذف
+
+262
+00:23:58,520 --> 00:24:03,620
+الماء من الكحول ممكن يعطي الألكين. هذا أحد النواتج
+
+263
+00:24:03,620 --> 00:24:09,120
+النتائج الثانية، إنه يتفاعل جزيئان من الكحول مع
+
+264
+00:24:09,120 --> 00:24:15,040
+بعض، واضح؟ يعملوا الإيثر. يعني هذا الإيثانول مع
+
+265
+00:24:15,040 --> 00:24:19,740
+إيثانول ثاني، CH₃CH₂OH
+
+266
+00:24:19,740 --> 00:24:24,020
+يعني طبعاً من، والإيثانول الثاني، ما أنا حاطط الـ
+
+267
+00:24:24,020 --> 00:24:29,380
+إيثانول ملايين الجزيئات، فجزيء بيتفاعل إيش؟ مع جزيء
+
+268
+00:24:29,380 --> 00:24:35,200
+لاحظوا لما يعمل الإيثر، CH₃CH₂OCH₂CH₃
+
+269
+00:24:35,200 --> 00:24:41,990
+إيش حذف من هذين الجزيئين؟ ماء. O-H من واحد، O-H من
+
+270
+00:24:41,990 --> 00:24:46,490
+واحد. يعني كأنه بالضبط اللي بده يصير هنا، إن هذه الـ
+
+271
+00:24:46,490 --> 00:24:51,630
+O بدها تهاجم هنا على الكربون، وتطرد الـ O-H. الآن، و
+
+272
+00:24:51,630 --> 00:24:53,230
+هذه الـ O شو حتخسر؟
+
+273
+00:24:57,940 --> 00:25:01,920
+هي لما هذه هاجمت من خلال الـ Oxygen كنوكليوفايل
+
+274
+00:25:01,920 --> 00:25:06,880
+طردت الـ OH، والنيوترال نيوكليوفايل دائماً بيخسر إيش؟
+
+275
+00:25:06,880 --> 00:25:11,740
+H، اتفقنا على هذا الكلام؟ هذه خسرت الـ H، والـ OH إيش
+
+276
+00:25:11,740 --> 00:25:19,280
+عملوا؟ H₂O. يعني هنا زائد H₂O، وهنا زائد H₂O، لكن هنا
+
+277
+00:25:19,280 --> 00:25:23,780
+ما حذف من جزء واحد، أعطى الألكين. لو حذف من
+
+278
+00:25:23,780 --> 00:25:31,820
+التفاعل بين جزيئين، بتعطي إيش؟ الـ إيثر، الـ R-O-R هو
+
+279
+00:25:31,820 --> 00:25:36,780
+الـ إيثر. طبعاً بيصير السؤال يا ترى أي التفاعلات
+
+280
+00:25:36,780 --> 00:25:42,640
+بيمشي؟ بيعتمد على عدة عوامل، من أهمها درجة الحرارة
+
+281
+00:25:42,640 --> 00:25:47,580
+زائد العوامل الحفازة اللي بيستعملوها للتفاعل. خلينا
+
+282
+00:25:47,580 --> 00:25:51,260
+نكون مركزين على درجة الحرارة. لو هذا التفاعل عملناه
+
+283
+00:25:51,260 --> 00:25:56,280
+عند ١٤٠ درجة مئوية، هيعطينا بشكل أساسي الإيثر، ولو
+
+284
+00:25:56,280 --> 00:26:00,740
+عملناها عند ١٨٠ درجة مئوية، هيعطينا بشكل أساسي
+
+285
+00:26:00,740 --> 00:26:06,220
+الألكين. لكن بقول لكم إن التفاعل صناعياً له شغلات
+
+286
+00:26:06,220 --> 00:26:11,300
+ثانية، وبستعملوا catalyst معينة، اللي مع الحرارة
+
+287
+00:26:11,300 --> 00:26:16,960
+تفضل هذا أو هذا. يعني بعض العوامل الحفازة مع حرارة
+
+288
+00:26:16,960 --> 00:26:21,760
+أعلى من ١٨٠، ٢٥٠، ممكن تخلي التفاعل يعطي بس الـ
+
+289
+00:26:21,760 --> 00:26:27,030
+ألكين، وبعض العوامل الحفازة على ١٤٠، ١٥٠، ممكن تخليه يعطي بس إيش؟ الإيثر. الآن بدناش
+
+290
+00:26:27,030 --> 00:26:34,050
+ندخل في التفاصيل المملة. احنا بنقول إنه تسخين
+
+291
+00:26:34,050 --> 00:26:37,510
+الإيثانول في وجود الحمض، ١٤٠ هيعطيني الإيثر، و١٨٠
+
+292
+00:26:37,510 --> 00:26:42,030
+هيعطيني الألكين. والقمر لما يصير في الصناعة أكيد
+
+293
+00:26:42,030 --> 00:26:47,950
+اللي بيشتغلوا فيه يعني عندهم انتباه لأشياء إضافية
+
+294
+00:26:47,950 --> 00:26:52,310
+ولعوامل حفازة اللي بيتحكموا بإيش الناتج اللي بيطلع
+
+295
+00:26:52,310 --> 00:26:56,290
+عندهم.
+
+296
+00:26:56,290 --> 00:26:56,670
+عندهم
+
+297
+00:26:59,310 --> 00:27:04,610
+الآن لو أخذنا مثال ثاني، لو أخذنا الـ tertiary butyl
+
+298
+00:27:04,610 --> 00:27:08,770
+alcohol، عارفينه، الـ tertiary butyl alcohol اللي هو
+
+299
+00:27:08,770 --> 00:27:12,470
+الكربون اللي حامل ثلاث مجموعات مثل، يعني لو رسمته
+
+300
+00:27:12,470 --> 00:27:22,330
+أنا OH، CH₃، CH₃، CH₃، وسخناه في وجود حمض، بالتأكيد
+
+301
+00:27:22,330 --> 00:27:31,490
+هيفقد الـ OH، وهيفقد معها H من كربون مجاورة. الآن
+
+302
+00:27:31,490 --> 00:27:35,770
+الثلاث ذرات اللي هنا متكافئات ولا لأ؟ والثلاث
+
+303
+00:27:35,770 --> 00:27:39,150
+هيدروجينات متكافئات. عشان إيه؟ لو بدأ أقول لكم هذا
+
+304
+00:27:39,150 --> 00:27:42,990
+الحذف، أو هذا الـ dehydration، يعني جاي لكم سؤال
+
+305
+00:27:42,990 --> 00:27:46,930
+dehydration of tertiary-butanol، أو tertiary-butyl
+
+306
+00:27:46,930 --> 00:27:51,770
+alcohol produces how many products؟ one. يعني لو
+
+307
+00:27:51,770 --> 00:27:55,970
+شال H من هنا زي هنا زي هنا، بدون ما ندخل في
+
+308
+00:27:55,970 --> 00:27:59,250
+الميكانيزم. لو رسمتوا double bond هنا، أو رسمتوها
+
+309
+00:27:59,250 --> 00:28:03,230
+هنا، أو رسمتوها هنا، هو إيش؟ نفس المركب. هنا مثلاً
+
+310
+00:28:03,230 --> 00:28:09,230
+رسمنا الـ OH هذه مع H من هدول، هي الناتج إيش اسمه؟
+
+311
+00:28:09,230 --> 00:28:15,840
+إيزوبيوتين.  مار عليكم إيزوبيوتين. أو لو بتسميتها بالـ
+
+312
+00:28:15,840 --> 00:28:22,300
+أيوباك، one two three، وعنمرة اثنين حامل إيش؟ مثل. إذا
+
+313
+00:28:22,300 --> 00:28:27,660
+٢-ميثيل بروبين، ٢-ميثيل بروبين هو نفس الإيزو
+
+314
+00:28:27,660 --> 00:28:32,300
+بيوتين. الآن لاحظوا معي إن أنتم صارت عندكم
+
+315
+00:28:32,300 --> 00:28:39,490
+الفكرة إنه بتحذف OH و Hydrogen مجاورة. لحسن الحظ في
+
+316
+00:28:39,490 --> 00:28:43,830
+الـ tertiary butanol، الثلاثة زي بعض، بيطلع عندي
+
+317
+00:28:43,830 --> 00:28:49,330
+كم ناتج؟ طيب لو الثلاثة مختلفات، هيعطيني كم ناتج؟
+
+318
+00:28:49,330 --> 00:28:55,080
+عملتوا مثال شبيه جداً، بس لما كنتوا بتحلفوا إيش مش الـ
+
+319
+00:28:55,080 --> 00:29:01,400
+H O H، الـ HCl، وسلّمته  home work. الحد في الميه زي
+
+320
+00:29:01,400 --> 00:29:06,420
+حد في الـ HCl. طيب حد في الـ HCl، متذكرين قاعدة
+
+321
+00:29:06,420 --> 00:29:14,280
+أخذتوها؟ عشان أقول لكم أي نواتج أفضل، الـ more
+
+322
+00:29:14,280 --> 00:29:18,740
+substituted، زي سايروف. ولذلك لو مثلاً أخذتم الـ ٢-
+
+323
+00:29:18,740 --> 00:29:25,870
+butanol، أكيد بدنا نحذف الـ OH، لكن يا ترى نحذف H من
+
+324
+00:29:25,870 --> 00:29:32,670
+هنا ولا H من هنا؟ إذا حذفنا هذه الـ H بنطلع هذا، و
+
+325
+00:29:32,670 --> 00:29:36,350
+إذا حذفنا هذه الـ H بنطلع هذا، which is more
+
+326
+00:29:36,350 --> 00:29:41,780
+substituted. في حد في الـ alkenes زيها تماماً، الـ
+
+327
+00:29:41,780 --> 00:29:45,020
+alcohols. هذا more substituted بيكون الـ major
+
+328
+00:29:45,020 --> 00:29:50,780
+product، الـ less substituted الـ minor product، واضح؟
+
+329
+00:29:50,780 --> 00:29:56,640
+كذلك الحالة بهذا المثال، هيبدأ أحذف الـ OH، تأكيد مش
+
+330
+00:29:56,640 --> 00:30:03,450
+فيها نقاش، بس بدي H مجاورة. هنا في H، وهذا المثل
+
+331
+00:30:03,450 --> 00:30:08,030
+كمان فيه H. لو حذفت هذا الـ H اللي هنا بيطلع
+
+332
+00:30:08,030 --> 00:30:12,110
+النتائج الثاني، ولو حذفت الـ H من هنا، أو H أو H
+
+333
+00:30:12,110 --> 00:30:17,050
+بيطلع هذا. نتطلع عليهم، which is more substituted؟
+
+334
+00:30:17,050 --> 00:30:21,470
+أكيد هذا more substituted، الـ major، الـ minor، نفس
+
+335
+00:30:21,470 --> 00:30:24,610
+الكلام، كنا نجيب السؤال، بس بدل ما نكون كاتبين OH
+
+336
+00:30:24,610 --> 00:30:31,410
+نكون كاتبين Cl أو Br. اللي عملناه لما كان هذا يكون Cl
+
+337
+00:30:31,410 --> 00:30:35,170
+أو Br، في chapter الـ elimination في الـ alkenes هو
+
+338
+00:30:35,170 --> 00:30:40,270
+نفسه بنطبقه على الـ alcohol، فالـ dehydration of
+
+339
+00:30:40,270 --> 00:30:46,530
+alcohol بيعطي نتائج موازية تماماً لـ الـ
+
+340
+00:30:46,530 --> 00:30:51,100
+dehydrohalogenation of alkyl halides. لاحظوا
+
+341
+00:30:51,100 --> 00:30:55,720
+في الـ alcohols، شو سمينا العملية؟ dehydration، نزع
+
+342
+00:30:55,720 --> 00:31:00,780
+الماء، O-H وH. طيب لو كانت هذه بـ R أو halogen، X وH
+
+343
+00:31:00,780 --> 00:31:05,380
+إيش قولنا عنها؟ dehydrohalogenation.
+
+344
+00:31:05,380 --> 00:31:11,600
+واضح؟ يعني لو هذه كانت X، hydro و halogen، فصارت
+
+345
+00:31:11,600 --> 00:31:15,280
+dehydrohalogenation.
+
+346
+00:31:15,280 --> 00:31:22,830
+لما H و O-H، dehydration، وسبق أن وضحت لكم إيش معناه
+
+347
+00:31:22,830 --> 00:31:26,710
+الإضافات والنزع، hydrogenation, dehydrogenation,
+
+348
+00:31:26,850 --> 00:31:30,290
+hydration, dehydration, hydrogenation,
+
+349
+00:31:30,410 --> 00:31:36,990
+dehydrogenation، هذه المصطلحات لازم تكون واضحة، لازم
+
+350
+00:31:36,990 --> 00:31:44,750
+تكون واضحة عندكم. من تفاعلات الـ alcohols، التفاعل مع
+
+351
+00:31:44,750 --> 00:31:49,670
+الـ hydrogen halides. الآن هذا التفاعل سبق إنّا
+
+352
+00:31:49,670 --> 00:31:54,870
+شرحناه، لكن بنعيد نؤكد عليه مرة ثانية، الـ alcohol مع
+
+353
+00:31:54,870 --> 00:32:00,370
+الـ hydrogen halide بيبدل الـ OH بـ X، بيعطيني RX زائد
+
+354
+00:32:00,370 --> 00:32:06,290
+H₂O. الآن لو أتيت أنا، أطلعت على الـ alcohol، إيش
+
+355
+00:32:06,290 --> 00:32:10,900
+ممكن يكون؟ الـ alcohol ممكن يكون tertiary و secondary
+
+356
+00:32:10,900 --> 00:32:14,800
+و primary. أفضل إيش هيتفاعل مع الـ tertiary، الـ
+
+357
+00:32:14,800 --> 00:32:24,040
+hydrogen halides. ممكن تكون يود وبروم وكلور، واضح؟
+
+358
+00:32:25,040 --> 00:32:28,740
+الـ hydrogen halides يا يود يا بروم يا كلور، مين
+
+359
+00:32:28,740 --> 00:32:32,420
+أحسن واحدة بتتفاعل؟ أفضل من البروم، أفضل من الكلور
+
+360
+00:32:32,420 --> 00:32:36,580
+والكحول tertiary أفضل من secondary، أفضل من إيش؟ الـ
+
+361
+00:32:36,580 --> 00:32:41,280
+primary. بناءً على ذلك، لو أنا أجي أتفاعلت أي كحول
+
+362
+00:32:41,280 --> 00:32:47,660
+من هدول مع يود أو بروم، يعني مع HI أو HBr، هيتفاعل
+
+363
+00:32:47,660 --> 00:32:53,360
+بدون مشاكل ويعمل إبدال. تصير المشكلة وين؟ لو بدأ
+
+364
+00:32:53,360 --> 00:32:59,060
+أضعف فاعل، الأضعف هنا مع الأضعف هنا، بتمشي التفاعل
+
+365
+00:33:00,250 --> 00:33:05,650
+بشكل عام. يعني لو أخذت الـ primary alkyl halide مع
+
+366
+00:33:05,650 --> 00:33:10,450
+HCl، مش هيعمل إبدال. يعني لو أخذت الإيثانول مع الـ
+
+367
+00:33:10,450 --> 00:33:16,090
+HCl، إيثانول مع HCl، بيعمل إبدال؟ إيثانول primary، HCl
+
+368
+00:33:16,090 --> 00:33:20,250
+للأضعف، ما بيعملش إبدال. بعد ذلك خذوا على سبيل المثال
+
+369
+00:33:20,250 --> 00:33:25,890
+a tertiary alkyl halide، ملاحظين أنتم؟ مع HCl
+
+370
+00:33:25,890 --> 00:33:29,070
+عمل
+
+371
+00:33:29,070 --> 00:33:34,250
+إبدال. Tertiary alkyl halide مع HCl عمل إبدال، اللي ما
+
+372
+00:33:34,250 --> 00:33:42,010
+بيعملش أي واحد الـ primary مع الـ HCl. يمكن هنا مرات
+
+373
+00:33:42,010 --> 00:33:45,270
+التفاعل بيكون إيش؟ قوي، زي التانين يعني حطوله
+
+374
+00:33:45,270 --> 00:33:50,670
+catalyst، zinc chloride، ما يضرّش، مش مشكلة، بس بيمشي
+
+375
+00:33:50,670 --> 00:33:57,220
+في الآخر، واضح؟ بيمشي. حتى لو أخذت secondary alcohol
+
+376
+00:33:57,220 --> 00:34:01,200
+ما يقعدش Cl، في وجود zinc chloride وشوية تسخين، بيمشي
+
+377
+00:34:01,200 --> 00:34:06,560
+لكن مين اللي فيه المشكلة؟ الـ primary؟ آه، مع الـ HCl
+
+378
+00:34:06,560 --> 00:34:12,580
+لاحظوا هنا، عشان هيك بنلاقي حلول بديلة لما يصير عند
+
+379
+00:34:12,580 --> 00:34:17,340
+primary. لو قلت لكم ما يقعدش Cl، إيش الجواب؟ نوريا
+
+380
+00:34:20,520 --> 00:34:24,140
+بدّه البني آدم هيك هيك، لازم يحوّل الـ OH لـ Cl
+
+381
+00:34:24,140 --> 00:34:28,180
+بيغير الـ reagent. يعني لو استعمل الـ primary مع الـ
+
+382
+00:34:28,180 --> 00:34:35,080
+PCl₃، فوسفورس تراي كلوريد، بيعمل تفاعل، واضح؟
+
+383
+00:34:35,080 --> 00:34:38,780
+يعني الـ primary الكحول مع فوسفورس تراي كلوريد
+
+384
+00:34:38,780 --> 00:34:43,080
+بتفاعل، بيبدّل الـ OH بـ Cl، لكن مع الـ HCl لأ، ما بتفاعل
+
+385
+00:34:43,080 --> 00:34:47,320
+وغير الفوسفورس تراي كلوريد، أخذنا كمان reagent
+
+386
+00:34:47,320 --> 00:34:56,800
+SOCl₂, هذا مشهور، بيسموه ثيونيل كلوريد، واضح؟ برضه
+
+387
+00:34:56,800 --> 00:35:02,920
+
+445
+00:40:22,090 --> 00:40:25,130
+من الـ OH هيدروجينة ومن الكربون اللي حامله
+
+446
+00:40:25,130 --> 00:40:27,850
+هيدروجينة، طب الكربون اللي حامله مش حامله هيدروجينة
+
+447
+00:40:28,820 --> 00:40:33,540
+إذا الأكسدة لا تتم مع إيش؟ مع الـ tertiary
+
+448
+00:40:33,540 --> 00:40:37,860
+alcohols، الآن مع الـ primary والـ secondary؟  تمام،
+
+449
+00:40:37,860 --> 00:40:44,160
+شو بدها تعطيني؟ ألديهايد أو كيتون، وقت إيش بتعطي
+
+450
+00:40:44,160 --> 00:40:49,760
+الديهايد؟ وقت إيش بتعطي كيتون؟ الـ primary ببساطة
+
+451
+00:40:49,760 --> 00:40:55,480
+بيعطي الديهايد، والـ secondary بيعطي كيتون، واضح؟
+
+452
+00:40:55,480 --> 00:40:59,380
+إذا كأنه لو الإنسان بده يلخص الكلام، أن الـ alcohol
+
+453
+00:40:59,380 --> 00:41:03,920
+في كم نوع؟ primary، secondary، و tertiary
+
+454
+00:41:03,920 --> 00:41:11,080
+الـ tertiary... كفى الله المؤمنين القتال...مش فيها كلمة شر
+
+455
+00:41:11,080 --> 00:41:17,300
+...وكفى الله المؤمنين القتال، الـ tertiary بتأكسدش
+
+456
+00:41:17,300 --> 00:41:22,400
+الـ primary لما يتأكسد شو هيعطيني؟  الـ aldehyde
+
+457
+00:41:22,400 --> 00:41:28,130
+الـ secondary لما يتأكسد شو هيعطيني؟ كيتون، لحظته هيك
+
+458
+00:41:28,130 --> 00:41:34,290
+بيصير العلم إيش ماله؟ سهل، أن الـ alcohols ثلاثة
+
+459
+00:41:34,290 --> 00:41:38,630
+الـ primary، أو الـ secondary، أو الـ tertiary، الـ primary
+
+460
+00:41:38,630 --> 00:41:44,560
+هيعطيني aldehyde، الـ secondary كيتون، الـ tertiary مش
+
+461
+00:41:44,560 --> 00:41:50,320
+حيتأكسد،  المرة الجاية بتجيجتين هنوضح إيش
+
+462
+00:41:50,320 --> 00:41:54,440
+العامل المؤكسد اللي بتتم فيه العملية، يعني نبدأ من
+
+463
+00:41:54,440 --> 00:41:58,820
+هذه بنشرحها بتجيجتين، وننتبه أن الـ الديهايد ممكن
+
+464
+00:41:58,820 --> 00:42:06,400
+بعدين يعمل تفاعل ثاني يصير أسيد، هذه زيادة، واضح؟ لكن
+
+465
+00:42:06,400 --> 00:42:12,560
+الأكسدة الأساسية الأولى، الـ primary شو بيصير؟ الـ
+
+466
+00:42:12,560 --> 00:42:17,640
+secondary، الـ tertiary لا يتأكسد، الآن الـ primary
+
+467
+00:42:17,640 --> 00:42:22,200
+بعد ما يصير الديهايد، ممكن لو العامل المؤكسد قوي
+
+468
+00:42:22,200 --> 00:42:28,660
+يمشي كمان مرحلة يصير أسيد، لو ضعيف بيظل زي ما هو، إذا
+
+469
+00:42:28,660 --> 00:42:32,340
+بتصير قصتنا إيش؟ العامل المؤكسد اللي استعملناه هنا، وهنا
+
+470
+00:42:32,340 --> 00:42:37,340
+هنا، من الأساس ما فيش أكسدة من هذه المرحلة، إن شاء
+
+471
+00:42:37,340 --> 00:42:40,120
+الله، بنبدأ المرة الجاية
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/6-G8b-zOS0Y_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/6-G8b-zOS0Y_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..fb6d6837eba461ceaaca22b71b32343165a6d781
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/6-G8b-zOS0Y_postprocess.srt
@@ -0,0 +1,1884 @@
+1
+00:00:19,520 --> 00:00:23,540
+بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في
+
+2
+00:00:23,540 --> 00:00:28,820
+موضوع ال acidity و عرفنا بالظبط ايش معنى الأحمار و
+
+3
+00:00:28,820 --> 00:00:35,360
+وضحنا انه مهم جدا نعرف ايش معنى ال BKAال acidity
+
+4
+00:00:35,360 --> 00:00:39,820
+constant و قولنا كل ما ال PKA قلة كل ما الحامض
+
+5
+00:00:39,820 --> 00:00:45,000
+بيكون ايش اقوى بعد هي طرحنا سؤال و أعطينا عليه
+
+6
+00:00:45,000 --> 00:00:49,940
+إجابة عامة بدون ما ندخل بأنفلة تفصيلية كان السؤال
+
+7
+00:00:49,940 --> 00:00:54,540
+لما بدأ قارن حامض مع حامض تاني من الأقوى و من
+
+8
+00:00:54,540 --> 00:00:59,250
+الأقل بدأ اعتمد على ايشلما بقارن الأحماض في قوتها
+
+9
+00:00:59,250 --> 00:01:05,270
+بدي أنظر لل أيون السالب اللي بتكون نتيجة اللي هو
+
+10
+00:01:05,270 --> 00:01:10,430
+تحلل الحمض بالماء هذا ال أيون السالب بدي الشحنة
+
+11
+00:01:10,430 --> 00:01:14,110
+تبعته تكون أقل ما يمكن هذا اللي بنسميه إيش احنا ال
+
+12
+00:01:14,110 --> 00:01:18,470
+stability ل ال negative أيون معنى ال stability أن
+
+13
+00:01:18,470 --> 00:01:21,710
+الشحنة تكون أقل ما يمكن الآن إيش اللي بيقلل
+
+14
+00:01:21,710 --> 00:01:27,060
+الشحنة؟تلات تأثيرات ممكن الحجم اللي بيحمل الشحنة
+
+15
+00:01:27,060 --> 00:01:30,920
+وممكن شيء نسميه ال inductive effect اللي هو تأثير
+
+16
+00:01:30,920 --> 00:01:36,180
+المساعدة وممكن شيء نسميه ال resonance effect
+
+17
+00:01:36,180 --> 00:01:42,660
+أعطينا بعض الأمثلة لكن خلينا نأكد الآن مثلا لو
+
+18
+00:01:42,660 --> 00:01:48,420
+أجينا نقارن ال phenolsمع الالكوهولز العادية
+
+19
+00:01:48,420 --> 00:01:54,480
+الاليفاتك الالكوهولز بمعنى انا بدي اقارن ROH مع
+
+20
+00:01:54,480 --> 00:01:59,320
+فنل OH لاحظوا المقطة الأولى انه لما ايجي يعمل
+
+21
+00:01:59,320 --> 00:02:04,680
+المقارنة ويفهم المقارنة سابه هو من الحامض ايش كتب؟
+
+22
+00:02:04,680 --> 00:02:10,760
+الايون السالد يعني كتب أنا R O minus وفنل O minus
+
+23
+00:02:10,760 --> 00:02:17,990
+فالحكم هوالـ Ion السالب الان هذا الـ RO- الشحن
+
+24
+00:02:17,990 --> 00:02:22,450
+اللي موجود عليه ثابت على ال oxygen مافيش فيها حركة
+
+25
+00:02:22,450 --> 00:02:25,970
+مافيش فيها resonance ال oxygen ذرة صغيرة يعني
+
+26
+00:02:25,970 --> 00:02:29,710
+بيقول it cannot carry the negative charge صعب
+
+27
+00:02:29,710 --> 00:02:33,250
+عليها تحمل ال negative charge ولذلك ال Ion كله
+
+28
+00:02:33,250 --> 00:02:37,050
+بيكون unstable فلاحظوا الكلام ان ال charge is
+
+29
+00:02:37,050 --> 00:02:43,570
+localized يعني محمولة على موقع واحد مش عملهاتتنجل
+
+30
+00:02:43,570 --> 00:02:48,730
+localized متموضعة محمولة في موضع واحد عكسها ايش؟
+
+31
+00:02:48,730 --> 00:02:53,410
+delocalized فبصير عندي كلمتين localized اشي على
+
+32
+00:02:53,410 --> 00:02:57,550
+موضع واحد delocalized زي ما انا اجي احمل هذا هيك
+
+33
+00:02:57,550 --> 00:03:01,550
+بس عن ايد هذه و فقط لا غير هيك بيكون هذا الحمل
+
+34
+00:03:01,550 --> 00:03:07,590
+localized الآن لو كنت بنجلهبيكون De-localized واضح
+
+35
+00:03:07,590 --> 00:03:13,210
+فإذا بنلاحظ أنه بالفينول الشحنة السالبة في أحد ال
+
+36
+00:03:13,210 --> 00:03:16,350
+resonance structures على ال oxygen لكن لو عملنا
+
+37
+00:03:16,350 --> 00:03:20,450
+حركة إلكترونات زوج من الإلكترونات بهذا الشكل و
+
+38
+00:03:20,450 --> 00:03:23,710
+حركنا ال bond هنلاحظ أنها ممكن تصير على ال carbon
+
+39
+00:03:23,710 --> 00:03:26,510
+اللي موجودة هنا بحركة تانية على ال carbon اللي
+
+40
+00:03:26,510 --> 00:03:29,750
+موجودة هنا بحركة تالتة على ال carbon لاحظوا أنه
+
+41
+00:03:29,750 --> 00:03:34,460
+بطلت الشحنةمحمولة على مكان واحد بطلت localized
+
+42
+00:03:34,460 --> 00:03:39,000
+صارت delocalized هذا resonance واضح او
+
+43
+00:03:39,000 --> 00:03:42,400
+delocalization يعني بيستعملوا كلمة resonance او
+
+44
+00:03:42,400 --> 00:03:46,900
+delocalization بنفس المعنى واضح ف because of the
+
+45
+00:03:46,900 --> 00:03:52,360
+delocalization of the charge in phenoxide and ion
+
+46
+00:03:52,360 --> 00:03:56,540
+or anion لحظوا ال phenyl O minus شو بنسميه
+
+47
+00:03:58,860 --> 00:04:02,960
+فينوكسايد انا يعني يمكن سابقا حكينالكم هي اللي لو
+
+48
+00:04:02,960 --> 00:04:09,300
+كانت هذه مثل O minus مثوكسايد مثل O minus إثوكسايد
+
+49
+00:04:09,300 --> 00:04:16,880
+HO minusHydroxide هيدروكسايد هيدروكسايد
+
+50
+00:04:16,880 --> 00:04:17,360
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+51
+00:04:17,360 --> 00:04:20,000
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+52
+00:04:20,000 --> 00:04:20,660
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+53
+00:04:20,660 --> 00:04:22,780
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+54
+00:04:22,780 --> 00:04:27,020
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+55
+00:04:27,020 --> 00:04:30,260
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+56
+00:04:30,260 --> 00:04:37,420
+هيدروكسايد هيدروكسايد هيدروكسايد هيدروكسايد
+
+57
+00:04:37,420 --> 00:04:43,720
+هيدروكسايد هيدروحوالي ست عشر، خمس عشر و نص و خمس
+
+58
+00:04:43,720 --> 00:04:47,340
+عشر و تسعة فلما نيجي نسأل ليش ال phenols are more
+
+59
+00:04:47,340 --> 00:04:51,140
+acidic than alcohols الجواب because of resonance
+
+60
+00:04:51,140 --> 00:04:56,460
+or because of delocalization of its chargeطبعا لو
+
+61
+00:04:56,460 --> 00:05:02,800
+صار عندى Nitrophenol ال delocalization بزيد يعني
+
+62
+00:05:02,800 --> 00:05:07,600
+الشحنة السالبة بالاضافة لإنها ممكن تنوجد على مواضع
+
+63
+00:05:07,600 --> 00:05:12,500
+كثيرة كمان بصير بإمكانها تنوجد على ذرات ال oxygen
+
+64
+00:05:12,500 --> 00:05:15,260
+بتاعون ال Nitro فبصير
+
+65
+00:05:17,450 --> 00:05:22,290
+الـ Delocalization للـ negative charge ايش ماله
+
+66
+00:05:22,290 --> 00:05:27,270
+اكتر بيصير عندي more delocalization يعني الشحنة
+
+67
+00:05:27,270 --> 00:05:31,350
+موزعة زي حمل بيحملوا اتنين اتريحوا شوية طب لو
+
+68
+00:05:31,350 --> 00:05:36,630
+حملوا تلاتة افضل لو حملوا اربعة أسهل واضح الفكرة
+
+69
+00:05:36,630 --> 00:05:42,650
+فبالنيتروفينول عندي more delocalization ولذلك نزل
+
+70
+00:05:42,650 --> 00:05:48,190
+النيتروفينول لقداشلسبعة و اتنين من عشرة ال BKA اذا
+
+71
+00:05:48,190 --> 00:05:52,510
+which is more acidic ال Nitrophenol is more acidic
+
+72
+00:05:52,510 --> 00:05:57,290
+لانه فيه more resonance طب لو صارت Trinitrophenol
+
+73
+00:05:57,290 --> 00:06:02,970
+more and more فهيصل ل point two five وبناء على ذلك
+
+74
+00:06:02,970 --> 00:06:08,670
+سمنا ايش احنا بكريك اسد ل Trinitrophenolهذه كلها
+
+75
+00:06:08,670 --> 00:06:12,850
+أمثلة على الـ Resonance Effect الآن لو كنت بدي
+
+76
+00:06:12,850 --> 00:06:17,290
+أمثلة على ال Inductive Effect لو بدأت بالإيثانول
+
+77
+00:06:17,290 --> 00:06:24,150
+فيه تلت مجموعات هيدروجين CH2OH CH3 طيب لو حطيت
+
+78
+00:06:24,150 --> 00:06:28,830
+واحدة من الهيدروجين زي كلور بتبدأ هذه الكلور تسحب
+
+79
+00:06:28,830 --> 00:06:30,210
+جزء من الشحنة
+
+80
+00:06:32,900 --> 00:06:36,200
+افترضوا ان كلهم فيهم شحنة سالبة قللت الشحنة
+
+81
+00:06:36,200 --> 00:06:41,580
+السالبة هذا ال effect سحب الشحنة with drawing of
+
+82
+00:06:41,580 --> 00:06:47,930
+the chargeأو إعطاء شحنة إيش بنسميه إحنا Inductive
+
+83
+00:06:47,930 --> 00:06:51,050
+Effect فال Inductive Effect هو سحب الشحنة أو
+
+84
+00:06:51,050 --> 00:06:55,470
+إعطائها مش نقلها لأ الشحنة موجودة هنا لكن افترض
+
+85
+00:06:55,470 --> 00:07:00,090
+الشحنة هنا عشر وحدات سحبنا منها واحدتين ال CL اللي
+
+86
+00:07:00,090 --> 00:07:05,050
+أنا بتحب السالب سحبت واحدتين جديش صفية بدل عشرة
+
+87
+00:07:05,050 --> 00:07:11,820
+تمانية واضح؟ الآن لو حطيت انتين CLصار عندى more
+
+88
+00:07:11,820 --> 00:07:17,220
+and more with the drawing لو حطيت تلاتة CL كلهم
+
+89
+00:07:17,220 --> 00:07:22,160
+بيسحبوا الشحنة السالبة بناء على ذلك ال effect هنا
+
+90
+00:07:22,160 --> 00:07:25,480
+لما انا بقول ان ال trichloroethanol is more acidic
+
+91
+00:07:25,480 --> 00:07:28,240
+than dichloroethanol than chloroethanol than
+
+92
+00:07:28,240 --> 00:07:32,340
+ethanol هذا ايش اللي بنسميه احنا inductive effect
+
+93
+00:07:32,340 --> 00:07:39,750
+واضح؟لمّا قررنا الـ RSH و الـ ROH مين اللي قلنا
+
+94
+00:07:39,750 --> 00:07:45,010
+فيهم أقوى كأسس؟ RSH طب الآن بنقول الـ RSH أقوى من
+
+95
+00:07:45,010 --> 00:07:51,310
+الـ ROH، why؟ because of the size، إذن هاي نعرفه
+
+96
+00:07:51,310 --> 00:08:00,410
+طيب، لو بدأجي أقول الـ ARSH مع الـ ROH، مين أقوى؟
+
+97
+00:08:02,130 --> 00:08:06,990
+because of the size لحظوا ال AR هنا و ال AR هنا
+
+98
+00:08:06,990 --> 00:08:11,890
+فيهم resonance فبطل ال resonance هو السبب يعني ال
+
+99
+00:08:11,890 --> 00:08:16,150
+aromatic او البنزينة هنا و البنزينة هنا فينول و
+
+100
+00:08:16,150 --> 00:08:22,040
+ثيوفينول ال AR عامل مشتركاللي بيعمل resonance بناء
+
+101
+00:08:22,040 --> 00:08:25,900
+على ذلك لو حد .. لو بدنا نجيب سؤال arsh is more
+
+102
+00:08:25,900 --> 00:08:30,240
+acidic than aroh due to resonance غلط لأنه هنا فيه
+
+103
+00:08:30,240 --> 00:08:33,680
+resonance و هنا فيه resonance طب هاش المختلف
+
+104
+00:08:33,680 --> 00:08:41,950
+sulfur و oxygen اذا because of the sizeلكن لو اجيت
+
+105
+00:08:41,950 --> 00:08:49,470
+قلتلكم بدأ اقارن ARSH و RSH، لاحظوا ال sulphur،
+
+106
+00:08:49,470 --> 00:08:53,990
+sulphur the same size، اذا وين صار الفرق؟ AR ولا
+
+107
+00:08:53,990 --> 00:09:00,310
+R؟ اذا why؟ because of resonance
+
+108
+00:09:04,470 --> 00:09:11,150
+لو كنت بدأ اقارن A R O H مع R O H ال O و ال O نفس
+
+109
+00:09:11,150 --> 00:09:16,870
+ال size اللي اتغير R و A R إذا مين أعلى؟ A R
+
+110
+00:09:16,870 --> 00:09:23,650
+because of resonance بضحك الفكرة لما بنعمل مقارنة
+
+111
+00:09:23,650 --> 00:09:29,630
+الآن لو إجيت على هدولة كلهم و قولت بدأ أسطب كل
+
+112
+00:09:29,630 --> 00:09:37,500
+الكلاموبلغة عربية بسيطة جدا بدي أقول من الأقوى ومن
+
+113
+00:09:37,500 --> 00:09:44,240
+الأضعف في الأربعة ال A R S H هو أقوى حاجة ال A R S
+
+114
+00:09:44,240 --> 00:09:51,560
+H هو الأقوى the strongest وال R O H هو الأضعف
+
+115
+00:09:54,370 --> 00:10:00,150
+يعني لو بقارن ال alcohols و ال thyols و ال phenols
+
+116
+00:10:00,150 --> 00:10:04,330
+و ال thyophenols أقوى واحد فيهم ال thyophenol و
+
+117
+00:10:04,330 --> 00:10:08,710
+أضعف واحد فيهم بالحمضية اللي هو إيش ال alcohol هذا
+
+118
+00:10:08,710 --> 00:10:14,970
+الكلام بينعكس على التفاعلات الكيميائيةهذا الكلام
+
+119
+00:10:14,970 --> 00:10:19,170
+الآن ان هذا الأضعف بنعكس على التفاعلات الكيميائية
+
+120
+00:10:19,170 --> 00:10:22,990
+وين بنعكس على التفاعلات الكيميائية مش احنا قاعدين
+
+121
+00:10:22,990 --> 00:10:28,010
+نقول هدولة أحماط مظبوط ولا لأ طول عمرنا بنعرف
+
+122
+00:10:28,010 --> 00:10:35,170
+الجملة الشهيرة حمض زاد قاعدة ملح زاد ماء بناء على
+
+123
+00:10:35,170 --> 00:10:40,570
+ذلك لو اجيت أفاعل هدولة مثلا مع قاعدة قوية زي ال N
+
+124
+00:10:40,570 --> 00:10:53,890
+A O Hزائد NaOH كلهم مش هم زائد قاعدة اه هلاحظ ان
+
+125
+00:10:53,890 --> 00:10:57,670
+تلاتة منهم بتفاعل وبيعطوا ملح زائد ماء واحد
+
+126
+00:10:57,670 --> 00:11:05,990
+مابتفعلش الا مابتفعلش هذا هذا بتفعل هذا بتفعل هذا
+
+127
+00:11:05,990 --> 00:11:11,040
+بتفعلواضح؟ طبعا لو قولنا لكم اكتبوا المعادلة،
+
+128
+00:11:11,040 --> 00:11:17,080
+عندنا مثال، لو أخدنا هذا ال R O H زي N A O H، إيش
+
+129
+00:11:17,080 --> 00:11:24,600
+كتبنا؟ No reaction لكن لو قولنا R S H زي N A O H،
+
+130
+00:11:24,600 --> 00:11:29,770
+ال H مع ال O H، إيش بيعملوا؟ ميّهطول عمره و ال RS
+
+131
+00:11:29,770 --> 00:11:36,350
+minus مع ال NA NA plus RS minus و بنفس الطريقة
+
+132
+00:11:36,350 --> 00:11:45,830
+بإمكانكم تكتبوا إيش كل الأشياء RSH
+
+133
+00:11:45,830 --> 00:11:46,050
+مع
+
+134
+00:11:57,410 --> 00:12:03,230
+فاهم الان دائما اذا وجد عندك مش سؤال مش سؤالك هذا
+
+135
+00:12:03,230 --> 00:12:08,170
+ال specific مش سؤالك هذا ال specific لأ اذا اي
+
+136
+00:12:08,170 --> 00:12:15,110
+شغلة حطيت فيها متغيرين معناه ذلك مش هيكون عندك ثقة
+
+137
+00:12:15,110 --> 00:12:20,110
+كاملة انك بتقدر تاخد الجواب مباشرة الا من التجربة
+
+138
+00:12:20,110 --> 00:12:27,210
+و من قيمة اش بتطلع التجربة ال BKAإذا صار عندك
+
+139
+00:12:27,210 --> 00:12:31,910
+متغيرين سؤالك انا بعتبره جيد انه انت غيرتي هنا ال
+
+140
+00:12:31,910 --> 00:12:37,970
+ar و r و هنا ال o و ال s و سألت مين الأقوى فيهم
+
+141
+00:12:37,970 --> 00:12:44,250
+كام متغير عندك اتنين الحل انك تبحثي تعمل التجربة و
+
+142
+00:12:44,250 --> 00:12:48,550
+تشوف ال bk ايه لهذا و ال bk لهذا و تعمل المقارنة
+
+143
+00:12:48,550 --> 00:12:54,180
+ولذلك في العلم دائما لما بتعملوا المقارنةبتثبتوا
+
+144
+00:12:54,180 --> 00:12:59,600
+جميع المتغيرات ما عدا متغير واحد بيصير بإمكانكوا
+
+145
+00:12:59,600 --> 00:13:03,420
+تعملوله مقارنة و تعملوله قوانين يمكن هذا الكلام
+
+146
+00:13:03,420 --> 00:13:08,780
+أكثر شيء مر عليكم في منطقة الغازات ليش؟ لأن
+
+147
+00:13:08,780 --> 00:13:13,500
+الغازات لها أكتر من متغير الضغط والحجم وعدد
+
+148
+00:13:13,500 --> 00:13:19,790
+المولات ودرجة الحرارةأربع متغيرات في الغازات واضح؟
+
+149
+00:13:19,790 --> 00:13:23,810
+الآن الغازات في النهاية كانت بتنجمع بمعادلة B في V
+
+150
+00:13:23,810 --> 00:13:28,570
+بساوي N في R في T pressure في volume بساوي number
+
+151
+00:13:28,570 --> 00:13:32,610
+of moles في R تابع الغازات في ال temperature الآن
+
+152
+00:13:32,610 --> 00:13:36,770
+لما كنت قادش أقول بدي أقارن ال volume مع ال
+
+153
+00:13:36,770 --> 00:13:43,210
+temperature كنت أحط لنفس الكمية من الغاز عندنفس
+
+154
+00:13:43,210 --> 00:13:49,550
+الضغط واضح بعد ذلك تصبح المقارنة أصعب تعمل تجربة
+
+155
+00:13:49,550 --> 00:13:55,930
+الان هنا ال O و O مشتركات ال R و AR مختلفات سهل
+
+156
+00:13:55,930 --> 00:14:01,650
+علي أعطي جواب واضح الفكرة؟ لكن هنا ال S أفضل من ال
+
+157
+00:14:01,650 --> 00:14:07,940
+O و ال AR أفضل من ال Rإيش النتيجة؟ التجربة
+
+158
+00:14:07,940 --> 00:14:14,040
+المجموعة التجربة واضح؟ يعني مافيش عندك جواب هذي
+
+159
+00:14:14,040 --> 00:14:16,880
+أفضل من هذي و هذي أفضل من هذي طب هذي أفضل من هذي
+
+160
+00:14:16,880 --> 00:14:20,440
+بقدش و هذي أفضل من هذي بقدش عشان يطلع عندي جواب؟
+
+161
+00:14:20,440 --> 00:14:29,160
+لأ بدك تعمل التجربة واضح؟ سؤال جيد الآن لاحظوا معي
+
+162
+00:14:29,160 --> 00:14:32,340
+هل يا ترى الكيميائي
+
+163
+00:14:33,600 --> 00:14:38,120
+بيستسلم؟ لأ، يعني سبحان الله زي ما بتقول آية كريمة
+
+164
+00:14:38,120 --> 00:14:44,820
+وفوق كل ذي علم عليم واضح؟ يعني احنا قولنا الكحول
+
+165
+00:14:44,820 --> 00:14:52,580
+هذا زائد N A O H لا يتفاعل طب ال N A O H كان تصنيف
+
+166
+00:14:52,580 --> 00:15:00,380
+strong baseقاعدة قوية الان ال N A O H is a strong
+
+167
+00:15:00,380 --> 00:15:05,360
+base مركب ايوني و قاعدة قوية طب حبيل غصب عنه
+
+168
+00:15:05,360 --> 00:15:11,000
+الكحول الفاعله ايش بنعمله بنجيبله very strong base
+
+169
+00:15:11,000 --> 00:15:16,460
+يعني بنجيبله قاعدة تكون اقوى من ال N A O H موجود
+
+170
+00:15:16,460 --> 00:15:20,860
+يعني بدل ما اجي افعله مع ال N A O H اللي strong
+
+171
+00:15:20,860 --> 00:15:26,490
+base ممكن افعله مع N A Hهذا المركب اسمه Sodium
+
+172
+00:15:26,490 --> 00:15:33,110
+Hydride الجزء القاعد فيه ايون H- الهيدرايد H-
+
+173
+00:15:33,110 --> 00:15:40,510
+واضح؟ ايش بنسمي هذا Sodium Hydride لاحظوا ال I
+
+174
+00:15:40,510 --> 00:15:47,390
+نهاية ايون سالف يعني هذا NA plus H- ويمكن كلكم
+
+175
+00:15:47,390 --> 00:15:54,470
+بتعرفوا او سبق مر عليكم ان ال H لهاتلت حلق ال H
+
+176
+00:15:54,470 --> 00:15:58,910
+ممكن تتخيلوها بتلت حلق ال H لحالها اللي فيها
+
+177
+00:15:58,910 --> 00:16:04,010
+إلكترون و ال H اللي فقدت الإلكترون و ال H لو
+
+178
+00:16:04,010 --> 00:16:09,010
+اكتسبت كمان إلكترون يعني ذرة الهيدروجين هي الذرة
+
+179
+00:16:09,010 --> 00:16:12,430
+اللي فيها إلكترون و بروتون فهذا ال H اللي فيها
+
+180
+00:16:12,430 --> 00:16:17,810
+إلكترون و بروتون هيدروجين أتم الآن لو فقدت
+
+181
+00:16:18,700 --> 00:16:25,900
+الإلكترون شو بنسميها بروتون بروتون ما انتوا تخيلوا
+
+182
+00:16:25,900 --> 00:16:31,020
+الذرة اتخيلوها بالذرة مش عندى نواة موجبة في كل
+
+183
+00:16:31,020 --> 00:16:38,060
+الأحوال و هالنواة الموجبة حواليهاالألكترون صارت
+
+184
+00:16:38,060 --> 00:16:41,660
+هيدروجين أتم الهيدروجين أتم نوال موجبة حوالها
+
+185
+00:16:41,660 --> 00:16:47,140
+إلكترون طيب لو صارت هيك وشيلنا الإلكترون شو الصفة
+
+186
+00:16:47,140 --> 00:16:55,280
+عندي النوال موجبة بس لبروتون واضح؟ الآن لو اكتسبت
+
+187
+00:16:55,280 --> 00:17:00,620
+كمان إلكترون تاني بتصير هيدرايد أنيون فهذه
+
+188
+00:17:00,620 --> 00:17:09,330
+هيدروجين أتمهذا البروتون وهذا الهيدرايد أنيون ال H
+
+189
+00:17:09,330 --> 00:17:14,810
+minus هيدرايد أنيون كتبنا هناك هيدرايد هذا دايما
+
+190
+00:17:14,810 --> 00:17:20,320
+البروتون اش بنسمي احنا او ال H plusبروتون ال H بلس
+
+191
+00:17:20,320 --> 00:17:25,400
+بروتون ولذلك الأحماض لما بنوصفها مثلا بنقول ال
+
+192
+00:17:25,400 --> 00:17:31,020
+HNO3 بنقول عنه في بروتون واحد monobrotic acid ال
+
+193
+00:17:31,020 --> 00:17:38,640
+H2SO4 بنقول dibrotic acid ال H3BO4 بنقول عنه
+
+194
+00:17:38,640 --> 00:17:43,100
+tribrotic acid واضح؟ اللي جابنا عن هالكلام كلمة
+
+195
+00:17:43,100 --> 00:17:51,800
+إيش؟السوديوم هايدرايد هو مصدر
+
+196
+00:17:51,800 --> 00:17:57,080
+قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى
+
+197
+00:17:57,080 --> 00:17:57,100
+قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى قوى
+
+198
+00:17:57,100 --> 00:18:01,200
+قوى قوى قوى قوى قوى قوى قوى
+
+199
+00:18:02,990 --> 00:18:06,750
+اللي هو لو كنا بناخده مع الاثانول مثلا Sodium
+
+200
+00:18:06,750 --> 00:18:11,870
+Ethoxide كذلك الحال لو فعلنا مع ال metal نفسه NA
+
+201
+00:18:11,870 --> 00:18:19,010
+Sodium Metal Sodium Metal كmetal لوحده أقوى كقاعدة
+
+202
+00:18:19,010 --> 00:18:24,350
+من ال NAOH يعني بإمكانه يتفاعل ال ROH مع ال NA
+
+203
+00:18:24,350 --> 00:18:29,290
+ويعطينا RO minus في الحالتين ال بيكتمل التفاعل انه
+
+204
+00:18:29,290 --> 00:18:35,630
+بيطلع غاز هيدروجينفصحيح ان ال R O H بتفعلش مع ال N
+
+205
+00:18:35,630 --> 00:18:40,290
+A O H ولكنه يتفاعل مع ال sodium hydrate او ال
+
+206
+00:18:40,290 --> 00:18:46,090
+sodium metal وبيعطينا ال R O minus N A plus واضح
+
+207
+00:18:46,090 --> 00:18:54,450
+هذه الفكرة لان هذه تعتبر كقواعد اقوى من ال N A O H
+
+208
+00:18:56,180 --> 00:19:01,080
+بهيك بيكفي في موضوع ال acidity لو اجينا على ال
+
+209
+00:19:01,080 --> 00:19:07,040
+preparation of alcohol الحقيقة هتلاحظ انه بشكل عام
+
+210
+00:19:07,040 --> 00:19:14,260
+ال preparation of alcohol مر معنا طب وين مر معنا؟
+
+211
+00:19:14,260 --> 00:19:21,040
+في مكانين المكان الأول لما كنا ناخد double bond و
+
+212
+00:19:21,040 --> 00:19:24,440
+نعمل عليها addition of water in presence of acid
+
+213
+00:19:25,200 --> 00:19:31,800
+إيش كانت الضيف؟ H و OH إذا إنها تيش كحول، واضح؟
+
+214
+00:19:31,800 --> 00:19:37,680
+فإضافة الماء للالكينز هذه الطريقة ولذلك الإثانول
+
+215
+00:19:37,680 --> 00:19:42,800
+مثلا بنحضره بإضافة الماء للإثيلين
+
+216
+00:19:44,070 --> 00:19:48,550
+طبعا إله شغل عملي و ال yield جليل لكن بيعيدوا
+
+217
+00:19:48,550 --> 00:19:51,810
+التفاعل أكتر من مرة لحد ما يمشوا التفاعل يعني
+
+218
+00:19:51,810 --> 00:19:57,110
+الفكرة العلمية أنه بتفاعل و بيضيف واضح صناعيا أكيد
+
+219
+00:19:57,110 --> 00:20:01,690
+إله أجهزة أو إله متابعة صناعية كذلك الحال اللي
+
+220
+00:20:01,690 --> 00:20:06,230
+بتذكر ال alkenes و إضافة الميه لازم يظلوا متذكر
+
+221
+00:20:06,230 --> 00:20:06,710
+إيش
+
+222
+00:20:09,640 --> 00:20:12,940
+Markovnikov وAntimarkovnikov addition يعني انا لما
+
+223
+00:20:12,940 --> 00:20:18,520
+كنت على البروبين اضيف الماء في وجود H بلس وين كنت
+
+224
+00:20:18,520 --> 00:20:23,700
+احط الهيدروجين هان ال O-H هان اطلع البروبان to all
+
+225
+00:20:23,700 --> 00:20:27,780
+او to probanol او ايزو برو بالالكول ماكانش يطلع
+
+226
+00:20:27,780 --> 00:20:34,200
+هذا طب لو بدنا هذا شو كنا نعمل Antimarkovnikov
+
+227
+00:20:36,400 --> 00:20:40,420
+كنا نستعمل طريقة ال boron ال bh3 و توابعها
+
+228
+00:20:40,420 --> 00:20:46,540
+بترجعوها واضح؟ إذا الكحولات يمكن أن تحضر و أخدنا
+
+229
+00:20:46,540 --> 00:20:51,000
+هذا الكلام بالتفصيل من خلال إضافة الماء على ال
+
+230
+00:20:51,000 --> 00:20:56,860
+alkyls برضه طريقة تانية أخدناها لتحضير الكحولات
+
+231
+00:20:56,860 --> 00:20:59,440
+مين اتذكرنا فيها؟
+
+232
+00:21:04,290 --> 00:21:10,270
+الـ RX زائد الماء أو الـ OH ماينوس مش كنا ناخد هذه
+
+233
+00:21:10,270 --> 00:21:18,110
+المعادلة RX زائد H2O in general R OH لنيوكليوفيليك
+
+234
+00:21:18,110 --> 00:21:23,710
+سبستيوشن على ال الكلهيلايت شبتر ستة سواء كنا نفعله
+
+235
+00:21:23,710 --> 00:21:27,940
+مع نيوترال نيوكليوفايل او معit charged the
+
+236
+00:21:27,940 --> 00:21:32,680
+nucleophile واضح ال substitution إذا الطرق العامة
+
+237
+00:21:32,680 --> 00:21:38,340
+لتحضير الكحولات يا إما من ال RX بالإبدال يا إما من
+
+238
+00:21:38,340 --> 00:21:45,840
+ال alkenes بتفاعل إيش بنسميه الإضافة ما هو مع
+
+239
+00:21:45,840 --> 00:21:53,100
+الميه تفاعل إضافة addition reaction واضح الآن لو
+
+240
+00:21:53,100 --> 00:22:00,470
+إجينا بعد هيك على تفاعلاتالكحولات تفاعلات الكحولات
+
+241
+00:22:00,470 --> 00:22:05,210
+طبعا في زميلة لكم بس عشان يعني ما نغمطهاش حقها ان
+
+242
+00:22:05,210 --> 00:22:10,530
+هي منتبهة جالت من ال evoxides كلامها سليم يعني لما
+
+243
+00:22:10,530 --> 00:22:14,950
+كان يكون عندكم الالكين و اضيف عليه ال oxygen أعمل
+
+244
+00:22:14,950 --> 00:22:22,050
+منه evoxide و بعد هيك لو عملنا ring opening
+
+245
+00:22:22,050 --> 00:22:28,320
+باستعمال ال nucleophile كنا نقول CCOH و يجي
+
+246
+00:22:28,320 --> 00:22:32,640
+لنكليوفايل this is an alcohol كلامها سليم ماكنش
+
+247
+00:22:32,640 --> 00:22:39,500
+فيه غلط واضح لكن منطلقوا ايش الالكين برضه منطلقنا
+
+248
+00:22:39,500 --> 00:22:43,860
+الالكين اعملنا ابوكسايد و عملنا ring opening هذا
+
+249
+00:22:43,860 --> 00:22:48,780
+الكلام ماكن ان شاء الله الان لو اجينا على موضوع ال
+
+250
+00:22:48,780 --> 00:22:56,650
+reactions of alcoholsمن تفاعلات ال alcohols تفاعل
+
+251
+00:22:56,650 --> 00:23:01,390
+ال dehydration معنى ال dehydration او acidic
+
+252
+00:23:01,390 --> 00:23:08,500
+dehydration نزع الماء في وجود الحامضنزع الماء في
+
+253
+00:23:08,500 --> 00:23:12,660
+وجود الحامض هذا ايش اسمه dehydration حدف الماء في
+
+254
+00:23:12,660 --> 00:23:17,280
+وجود الحامض الآن بدنا ننتبه هنا لنقطة انه احنا
+
+255
+00:23:17,280 --> 00:23:22,940
+ممكن نعمل هذا التفاعل بطريقتين تؤدي الى ناتجين
+
+256
+00:23:22,940 --> 00:23:28,280
+مختلفين ممكن من نفس الكحول يعني لو أخدنا الاثانول
+
+257
+00:23:28,280 --> 00:23:31,240
+كمثال ننزع من هنا OH
+
+258
+00:23:34,460 --> 00:23:40,300
+OH من carbon مجاورة هنا رفعنا ايش؟ مية لما بنشيل
+
+259
+00:23:40,300 --> 00:23:48,100
+OH مع اتش شو ممكن نعمل؟ الالكين الحد في عكس ايش؟
+
+260
+00:23:48,100 --> 00:23:53,400
+الاضافة اضافة الماء على الالكين بتاعة الالكول حد
+
+261
+00:23:53,400 --> 00:23:58,520
+في ال ..إضافة الماء على الالكين تعطي الالكول وحذف
+
+262
+00:23:58,520 --> 00:24:03,620
+الماء من الالكول ممكن يعطي الالكين هذا أحد النواتج
+
+263
+00:24:03,620 --> 00:24:09,120
+الناتج التاني انه يتفاعلوا جزيئين من الالكول مع
+
+264
+00:24:09,120 --> 00:24:15,040
+بعضواضح؟ يعملول ال ether يعني هذا ال ethanol مع
+
+265
+00:24:15,040 --> 00:24:19,740
+ethanol تاني CH3CH2OH
+
+266
+00:24:19,740 --> 00:24:24,020
+يعني طبعا من و ال ethanol التاني ما انا حاطط ال
+
+267
+00:24:24,020 --> 00:24:29,380
+ethanol ملايين الجزيئات فجزيئ بتفاعل ايش؟ مع جزيئ
+
+268
+00:24:29,380 --> 00:24:35,200
+لاحظوا لما يعمل ال ether CH3CH2OCH2CH3
+
+269
+00:24:35,200 --> 00:24:41,990
+ايش حُدف من هدول الجزيئين؟مية O H من واحد O H من
+
+270
+00:24:41,990 --> 00:24:46,490
+واحد يعني كأنه بالظبط اللي بده يصير هنا أن هذه ال
+
+271
+00:24:46,490 --> 00:24:51,630
+O بدها تهاجم هنا على الكربون وتترد ال O H الآن و
+
+272
+00:24:51,630 --> 00:24:53,230
+هذه ال O شو هتخسر؟
+
+273
+00:24:57,940 --> 00:25:01,920
+هي لما هذه هاجمت من خلال الـ Oxygen كان يوكليوفايل
+
+274
+00:25:01,920 --> 00:25:06,880
+طردت الـ OH والنيوترال يوكليوفايل دايما بيخسر ايش؟
+
+275
+00:25:06,880 --> 00:25:11,740
+H اتفقنا على هذا الكلام هذه خسرت الـ H والـ OH ايش
+
+276
+00:25:11,740 --> 00:25:19,280
+عملوه؟ H2O يعني هنا زائد H2O وهنا زائد H2O لكن هنا
+
+277
+00:25:19,280 --> 00:25:23,780
+ما حُدفت من جزء واحد اعطت الالكين لو حُدفت من
+
+278
+00:25:23,780 --> 00:25:31,820
+التفاعل بين جزيين بتعطي ايش؟الـ Ether الـ ROR هو
+
+279
+00:25:31,820 --> 00:25:36,780
+الـ Ether طبعاً بيصير السؤال يا ترى أي التفاعلات
+
+280
+00:25:36,780 --> 00:25:42,640
+بيمشي بيعتمد على عدة عوامل من أهمها درجة الحرارة
+
+281
+00:25:42,640 --> 00:25:47,580
+زائد العوامل الحفازة اللي بيستعملوها للتفاعل خلينا
+
+282
+00:25:47,580 --> 00:25:51,260
+نكون مركزين على درجة الحرارة لو هذا التفاعل عملناه
+
+283
+00:25:51,260 --> 00:25:56,280
+عند 140 درجة مئوية هيعطينا بشكل أساس الـ Etherو لو
+
+284
+00:25:56,280 --> 00:26:00,740
+عملناها عند 180 درجة مئوية هيعطينا بشكل أساسي
+
+285
+00:26:00,740 --> 00:26:06,220
+الالكيد لكن بقولكوا أن التفاعل صناعيا له شغلات
+
+286
+00:26:06,220 --> 00:26:11,300
+تانية و بيستعمله catalyst معينة اللي مع الحرارة
+
+287
+00:26:11,300 --> 00:26:16,960
+تفضل هذا أو هذا يعني بعض العوامل الحفازة مع حرارة
+
+288
+00:26:16,960 --> 00:26:21,760
+أعلى من 180 ع 250 ممكن تخلي التفاعل يعطي بس ال
+
+289
+00:26:21,760 --> 00:26:27,030
+الكيد و بعض العوامل الحفازةعلى مية و اربعين، مية و
+
+290
+00:26:27,030 --> 00:26:34,050
+خمسين، ممكن تخليه يعطي بس إيش؟الإيثر الآن بدناش
+
+291
+00:26:34,050 --> 00:26:37,510
+ندخل في التفصيل الممل احنا بنقول انه تسخين
+
+292
+00:26:37,510 --> 00:26:42,030
+الاثانول في وجود الحامض 140 هيعطيني ال ether و 180
+
+293
+00:26:42,030 --> 00:26:47,950
+هيعطيني ال alkene و القمر لما يصير في الصناعة اكيد
+
+294
+00:26:47,950 --> 00:26:52,310
+اللي بيشتغلوا فيه يعني عندهم انتباه لأشياء إضافية
+
+295
+00:26:52,310 --> 00:26:56,290
+و لعوامل حفازة اللي يتحكموا ايش الناتج اللي بيطلع
+
+296
+00:26:56,290 --> 00:26:56,670
+عندهم
+
+297
+00:26:59,310 --> 00:27:04,610
+الان لو أخدنا مثال تاني لو أخدنا ال tertiary butyl
+
+298
+00:27:04,610 --> 00:27:08,770
+alcohol عارفينه ال tertiary butyl alcohol اللي هو
+
+299
+00:27:08,770 --> 00:27:12,470
+ال carbon اللي حامله تلت مجموعات مثل يعني لو رسمته
+
+300
+00:27:12,470 --> 00:27:22,330
+انا OH CH3 CH3 CH3 و سخناه في وجود حامض بالتأكيد
+
+301
+00:27:22,330 --> 00:27:31,490
+هيفقدالـ OH و هيفقد معها H من كاربون مجاورة الآن
+
+302
+00:27:31,490 --> 00:27:35,770
+التلت ذرات اللي هنا متكافئات ولا لأ؟ والتسع
+
+303
+00:27:35,770 --> 00:27:39,150
+هيدروجينات متكافئات عشان ايه؟ لو بدأ أقولكوا هذا
+
+304
+00:27:39,150 --> 00:27:42,990
+الحذف أو هذا ال dehydrationيعني جيكوا اك سؤال
+
+305
+00:27:42,990 --> 00:27:46,930
+dehydration of tertiary-butanol او tertiary-butyl
+
+306
+00:27:46,930 --> 00:27:51,770
+alcohol produces how many products؟ one يعني لو
+
+307
+00:27:51,770 --> 00:27:55,970
+شال H من هان زي هان زي هان بدون ما ندخل في
+
+308
+00:27:55,970 --> 00:27:59,250
+الميكانيزم لو رسمتوا double bond هان او رسمتوها
+
+309
+00:27:59,250 --> 00:28:03,230
+هان او رسمتوها هان هو ايش؟ نفس المركب هنا مثلا
+
+310
+00:28:03,230 --> 00:28:09,230
+رسمنا الـOH هذه مع H من هدولة هي الناتج ايش اسمه؟
+
+311
+00:28:09,230 --> 00:28:15,840
+ISOبيوتين مار عليكم ايزو بيوتين او لو بتكوينها بال
+
+312
+00:28:15,840 --> 00:28:22,300
+ايوبك one two three وعنمرة اتنين حامل ايش مثل اذا
+
+313
+00:28:22,300 --> 00:28:27,660
+two مثل بروبين two مثل بروبين هو نفس ال ايزو
+
+314
+00:28:27,660 --> 00:28:32,300
+بيوتين الان لاحظوا معايا ان انتوا صارت عندكم
+
+315
+00:28:32,300 --> 00:28:39,490
+الفكرة انه بتحذف OHو Hydrogen مجاورة لحسن الحظ في
+
+316
+00:28:39,490 --> 00:28:43,830
+ال tertiary butanol التلاتة زي بعض طلع بيطلع عندى
+
+317
+00:28:43,830 --> 00:28:49,330
+كام ناتج طب لو التلاتة مختلفات هيعطينى كام ناتج
+
+318
+00:28:49,330 --> 00:28:55,080
+اعملتوا مثال شبيه جدا بس لما كنتوا تحلفوا ايشمش ال
+
+319
+00:28:55,080 --> 00:29:01,400
+H O H ال H C L و سلمتوه homeware الحد في الميه زي
+
+320
+00:29:01,400 --> 00:29:06,420
+حد في ال H C L طب حد في ال H C L متذاكرين قاعدة
+
+321
+00:29:06,420 --> 00:29:14,280
+أخدتوها عشان اتقولكوا أي نواتج أفضل ال more
+
+322
+00:29:14,280 --> 00:29:18,740
+substituted زي سفرول ولذلك لو مثلا أخدتوا ال two
+
+323
+00:29:18,740 --> 00:29:25,870
+butanol أكيد بدنا نحدفالـ OH لكن يا تراب نحذف H من
+
+324
+00:29:25,870 --> 00:29:32,670
+هنا و لا H من هنا إذا حذفنا هذه ال H بنطلع هذا و
+
+325
+00:29:32,670 --> 00:29:36,350
+إذا حذفنا هذه ال H بنطلع هذا which is more
+
+326
+00:29:36,350 --> 00:29:41,780
+substitutedفي حد في ال alkalites زيها تماما ال
+
+327
+00:29:41,780 --> 00:29:45,020
+alcohols هذا more substituted بيكون ال major
+
+328
+00:29:45,020 --> 00:29:50,780
+product ال less substituted ال minor product واضح؟
+
+329
+00:29:50,780 --> 00:29:56,640
+كذلك الحالة بهذا المثال هيبدأ احذف ال OH تأكيد مش
+
+330
+00:29:56,640 --> 00:30:03,450
+فيها نقاش بس بدي Hمجاورة هنا في اتش وهذا المثل
+
+331
+00:30:03,450 --> 00:30:08,030
+كمان فيها اتش لو حذفت هذا الاتش اللي هنا بيطلع
+
+332
+00:30:08,030 --> 00:30:12,110
+الناتج التاني و لو حذفت الاتش من هنا او اتش او اتش
+
+333
+00:30:12,110 --> 00:30:17,050
+بيطلع هذا نتطلع عليهم which is more substituted
+
+334
+00:30:17,050 --> 00:30:21,470
+اكيد هذا more substituted ال major ال minor نفس
+
+335
+00:30:21,470 --> 00:30:24,610
+الكلام كنا نجيب السؤال بس بدل ما نكون كاتبين OH
+
+336
+00:30:24,610 --> 00:30:31,410
+نكون كاتبين CL او PRاللي عملناه لما كان دا يكون CL
+
+337
+00:30:31,410 --> 00:30:35,170
+او PR في chapter ال elimination في ال alkalites هو
+
+338
+00:30:35,170 --> 00:30:40,270
+نفسه بنطبقه على ال alcohol ف ال dehydration of
+
+339
+00:30:40,270 --> 00:30:46,530
+alcohol بيعطي نتائج موازية تماما ل ال
+
+340
+00:30:46,530 --> 00:30:51,100
+dehydrohalogenation of alcoholAlkyl Halides لاحظوا
+
+341
+00:30:51,100 --> 00:30:55,720
+في ال alcohols شو سمينا العملية؟ dehydration نزع
+
+342
+00:30:55,720 --> 00:31:00,780
+الماء OH وH طب لو كانت هذه بيه R او halogen X وH
+
+343
+00:31:00,780 --> 00:31:05,380
+ايش قولنا عنها؟ dehydrohalogenation
+
+344
+00:31:05,380 --> 00:31:11,600
+واضح؟ يعني لو هذه كانت X, hydro و halogen فصارت
+
+345
+00:31:11,600 --> 00:31:15,280
+dehydrohalogenation
+
+346
+00:31:15,280 --> 00:31:22,830
+لما H و OHdehydration و سبق أن وضحت لكم إيش معناه
+
+347
+00:31:22,830 --> 00:31:26,710
+الإضافات و النزع hydrogenation, dehydrogenation,
+
+348
+00:31:26,850 --> 00:31:30,290
+hydration, dehydration, hydrogenation,
+
+349
+00:31:30,410 --> 00:31:36,990
+dehydrogenation هذه المصطلحات لازم تكون واضحة لازم
+
+350
+00:31:36,990 --> 00:31:44,750
+تكون واضحة عندكم من تفاعلات ال alcohols التفاعل مع
+
+351
+00:31:44,750 --> 00:31:49,670
+ال hydrogen halidesالان هذا التفاعل سبق اننا
+
+352
+00:31:49,670 --> 00:31:54,870
+شرحناه لكن بنعيد نأكد عليه مرة ثانية ال alcohol مع
+
+353
+00:31:54,870 --> 00:32:00,370
+ال hydrogen halide بيبدل ال OH ب X بيعطيني RX زائد
+
+354
+00:32:00,370 --> 00:32:06,290
+H2O الان لو اتيت انا اتطلعت على ال alcohol ايش
+
+355
+00:32:06,290 --> 00:32:10,900
+ممكن يكون ال alcohol ممكن يكون tertiaryو secondary
+
+356
+00:32:10,900 --> 00:32:14,800
+و primary افضل اش هيتفاعل مع ال tertiary ال
+
+357
+00:32:14,800 --> 00:32:24,040
+hydrogen halides ممكن تكون يود و بروم و كلور واضح؟
+
+358
+00:32:25,040 --> 00:32:28,740
+الـ hydrogen halides يا يود يا بروم يا كلور، مين
+
+359
+00:32:28,740 --> 00:32:32,420
+أحسن واحدة بتتفعل؟ أفضل من البروم، أفضل من الكلور
+
+360
+00:32:32,420 --> 00:32:36,580
+والالكهول تيرتشري أفضل من سكندريا، أفضل من إيش؟ ال
+
+361
+00:32:36,580 --> 00:32:41,280
+primary بناء على ذلك، لو أنا أجي اتفعلت أي ألكهول
+
+362
+00:32:41,280 --> 00:32:47,660
+من هدولة مع يود أو بروم، يعني مع HI أو HPR، هيتفعل
+
+363
+00:32:47,660 --> 00:32:53,360
+بدون مشاكل ويعمل إبدالهتصير المشكلة وين؟ لو بدأ
+
+364
+00:32:53,360 --> 00:32:59,060
+ضقة فاعل، الأضعف هان مع الأضعف هان، بتمشي التفاعل
+
+365
+00:33:00,250 --> 00:33:05,650
+بشكل عام يعني لو أخدت ال primary alkyl halide مع
+
+366
+00:33:05,650 --> 00:33:10,450
+HCl مش هيعمل إبدال يعني لو أخدت ال ethanol مع ال
+
+367
+00:33:10,450 --> 00:33:16,090
+HCl إيثانول مع HCl بيعمل إبدال إيثانول primary HCl
+
+368
+00:33:16,090 --> 00:33:20,250
+للأضعف بيعملش إبدال بعد ذلك خدوا على سبيل المثال
+
+369
+00:33:20,250 --> 00:33:25,890
+high tertiary alkyl halide ملاحظين انتوا؟ مع HCl
+
+370
+00:33:25,890 --> 00:33:29,070
+عمل
+
+371
+00:33:29,070 --> 00:33:34,250
+إبدالTertiary Alkylide مع HCl عمل إبدالة اللي ما
+
+372
+00:33:34,250 --> 00:33:42,010
+بيعملش أي واحد ال primary مع ال HCl يمكن هنا مرات
+
+373
+00:33:42,010 --> 00:33:45,270
+التفاعل بيكون إيش قوي زي التانين يعني حطوله
+
+374
+00:33:45,270 --> 00:33:50,670
+catalyst zinc chloride ما بضرش مش مشكلة بس بيمشي
+
+375
+00:33:50,670 --> 00:33:57,220
+في الآخر واضح؟ بيمشيحتى لو أخدت secondary alcohol
+
+376
+00:33:57,220 --> 00:34:01,200
+ماقعدش CL في وجود ذنك كلورادي و شوية تسخين بمشي
+
+377
+00:34:01,200 --> 00:34:06,560
+لكن مين اللي فيه المشكلة ال primary؟ اه مع ال FCL
+
+378
+00:34:06,560 --> 00:34:12,580
+لاحظوا هنا عشان هيك بنلاقي حلول بديلة لما يصير عند
+
+379
+00:34:12,580 --> 00:34:17,340
+primary لو قلتلكوا ماقعدش CL إيش الجواب؟ نوريا
+
+380
+00:34:20,520 --> 00:34:24,140
+بدّو البني آدم هيك هيك لازم يحوّل الـ OH لـCl
+
+381
+00:34:24,140 --> 00:34:28,180
+بيغير ال reagent يعني لو استعمل ال primary مع ال
+
+382
+00:34:28,180 --> 00:34:35,080
+BCL3 فوسفوراس الـ Trichloride بيعمل تفاعل واضح؟
+
+383
+00:34:35,080 --> 00:34:38,780
+يعني ال primary الكهول مع فوسفوراس ال Trichloride
+
+384
+00:34:38,780 --> 00:34:43,080
+بتفاعل بيبدّي ال OH بCL لكن مع ال HCL لأ بتفاعل
+
+385
+00:34:43,080 --> 00:34:47,320
+وغير الفوسفوراس ال Trichloride أخدنا كمان reagent
+
+386
+00:34:47,320 --> 00:34:56,800
+SOCL2 هذا مشهور بيسميه ثيونيليكلورايد واضح؟ برضه
+
+387
+00:34:56,800 --> 00:35:02,920
+هذا ايش بيعمل؟ بتفاعل و بيبدل ال OH ل ال primary
+
+388
+00:35:02,920 --> 00:35:08,880
+بCL فسواء استعملت الفوسفوراس ال trichloride او
+
+389
+00:35:08,880 --> 00:35:12,380
+الثيونيليكلورايد بقدر اعمل التفاعل لكن لو استعملت
+
+390
+00:35:12,380 --> 00:35:19,650
+ال HCl بمشيش التفاعلطبعا ما عدا ذلك مع اليود و مع
+
+391
+00:35:19,650 --> 00:35:23,730
+البروم بيمشي مع كله تيرتشاري .. سكندر .. برايماري
+
+392
+00:35:23,730 --> 00:35:29,370
+.. يعني المشكلة حقيقة بين ال primary و ال hcl في
+
+393
+00:35:29,370 --> 00:35:32,150
+حلول بديلة ولا لأ؟ كم حل؟
+
+394
+00:35:40,460 --> 00:35:46,160
+هي هنا على سبيل المثال ال primary مع ال SOCl2
+
+395
+00:35:46,160 --> 00:35:51,480
+بتفاعل مية في المية الان لاحظوا ان هذا التفاعل
+
+396
+00:35:51,480 --> 00:35:57,100
+تفاعل إبدال ال OH ب X خاص بال alcohol يعني ال
+
+397
+00:35:57,100 --> 00:36:03,950
+phenols لا يتم عليها إبداليعني لو قلنا لكوا ال A R
+
+398
+00:36:03,950 --> 00:36:16,610
+O H مع HBR مع HCL مع BCL3 مع SOCL2 بكل لغات الأرض
+
+399
+00:36:16,610 --> 00:36:25,460
+لا تتفاعل مافيش إبدال علىالاروماتيك كومباونز لإيش؟
+
+400
+00:36:25,460 --> 00:36:29,400
+لأنه أنا هنا بدي أجيب سالب الـ nucleophile سالب و
+
+401
+00:36:29,400 --> 00:36:32,740
+أخليه يهاجم على البنزينة و احنا من البداية اتفقنا
+
+402
+00:36:32,740 --> 00:36:36,080
+انه الإبدال اللي على البنزين Electrophilic
+
+403
+00:36:36,080 --> 00:36:39,460
+Substitution in general واضح؟ يعني انا لو اجيت
+
+404
+00:36:39,460 --> 00:36:43,740
+افعل مع هدولة في النهاية هاجيب PR minus او I minus
+
+405
+00:36:43,740 --> 00:36:47,960
+minus على minus بيصير و لذلك الإبدالات اللي هنا
+
+406
+00:36:47,960 --> 00:36:53,940
+كلها اللي أخدناها هي متعلقةبالكحولات بال R O H لكن
+
+407
+00:36:53,940 --> 00:36:58,440
+لو صارت A R O H بنزينة أو حملة O H و قلتلكوا
+
+408
+00:36:58,440 --> 00:37:03,740
+بدلوها ب C L و ب R لأواضح؟ هنا مافيش substitution
+
+409
+00:37:03,740 --> 00:37:07,840
+في ال aromatic compounds ال substitution في إيش؟
+
+410
+00:37:07,840 --> 00:37:12,200
+في ال aliphatic compounds تبوا هذا الكلام ممكن
+
+411
+00:37:12,200 --> 00:37:16,440
+نسألكوا يا صح و غلط aromatic alcohols undergo
+
+412
+00:37:16,440 --> 00:37:22,540
+substitution in uneasy manner مثلا ولا .. no they
+
+413
+00:37:22,540 --> 00:37:26,320
+don't undergo substitution
+
+414
+00:37:30,300 --> 00:37:34,040
+ما هو الـ Electrophilic Substitution بيبطل في هذه
+
+415
+00:37:34,040 --> 00:37:38,420
+الحالة للـ OH بيصير في مكان تاني على البنزينة
+
+416
+00:37:38,420 --> 00:37:44,520
+بيختلف التفاعل يعني زي ما تجيب فينول و بدك تعمل
+
+417
+00:37:44,520 --> 00:37:50,200
+مثلا مع الchlor FeCl3 على سبيل المثال أو تاخد O
+
+418
+00:37:50,200 --> 00:37:57,880
+Methyl بتصير تبدل هنا بتبدل Hydrogens مش بتبدلطبعا
+
+419
+00:37:57,880 --> 00:38:01,320
+المشكلة ان الفينول نفسه بعارض مع ال FEC الاتنين
+
+420
+00:38:01,320 --> 00:38:05,420
+افترض او مثل مثلا بتبدليش ال او مثل بتبدلي ايش
+
+421
+00:38:05,420 --> 00:38:11,540
+بتبدلي على الحلقة هيدروجينات بتبدلي هيدروجينات على
+
+422
+00:38:11,540 --> 00:38:20,140
+الحلقة الان ال alcohol من تفاعلاتها الشهيرة تفاعل
+
+423
+00:38:20,140 --> 00:38:25,720
+ال oxidation خليني اقول ايش معنى ال oxidationال
+
+424
+00:38:25,720 --> 00:38:29,920
+Oxidation بلغة الكيميا ما انا عارف ترجمتها انه
+
+425
+00:38:29,920 --> 00:38:34,900
+افقد ال H تبعت ال OH يعني لو انا اطلعت على المركب
+
+426
+00:38:34,900 --> 00:38:41,420
+CHOH زي هيك و ايش ما كان يكون عندى هنا ان افقد
+
+427
+00:38:41,420 --> 00:38:47,910
+جزئها هيدروجينأفقد الـ H اللي على الأكسجين و H على
+
+428
+00:38:47,910 --> 00:38:52,310
+الكربون المتسقة بها الأكسجين مباشرة الآن هدولة لو
+
+429
+00:38:52,310 --> 00:38:56,550
+فقدوا زي هيك على شكل جزء هيدروجين هذه إيش بنتيجة
+
+430
+00:38:56,550 --> 00:39:02,950
+تعمل هنا double bond طالما عملت double bond شو
+
+431
+00:39:02,950 --> 00:39:09,330
+هيصير النتج الديهايد أو كيتونباعتمد على هدول
+
+432
+00:39:09,330 --> 00:39:13,130
+المجموعتين خلّينا نكون في البداية فاهمين قصة
+
+433
+00:39:13,130 --> 00:39:18,950
+الأكسدة الأكسدة معناها ان ال COH بيصير C double
+
+434
+00:39:18,950 --> 00:39:24,090
+bond O طالما C double bond O صارت اذا صارت الجهاي
+
+435
+00:39:24,090 --> 00:39:29,870
+او كيتون هتفقد ال H تعطي ال OH OH عن الكربون اللي
+
+436
+00:39:29,870 --> 00:39:35,790
+هنا اول سؤال هيجيكم طب يا ترى لو فيش هنا H
+
+437
+00:39:38,560 --> 00:39:43,880
+يعني لو هذه كانت R و R و R فى عندي OH مستعدة تفقد
+
+438
+00:39:43,880 --> 00:39:48,860
+ال H بس فىش هنا H يعني صار إيش نوع ال alcohol?
+
+439
+00:39:50,620 --> 00:39:55,800
+tertiary واضحة؟ يعني افترضوا هذه كانت C وهذه C
+
+440
+00:39:55,800 --> 00:40:02,370
+وهذه C CH3 CH3 CH3 هنا فى H هنا مافيش Hبدوا يتم
+
+441
+00:40:02,370 --> 00:40:07,270
+الأكسدة؟ إذا على طول هنطلع قاعدة أن الـ tertiary
+
+442
+00:40:07,270 --> 00:40:11,070
+alcohols اللي مافيش عليهم هيدروجينة هنا بتأكسدوش
+
+443
+00:40:11,070 --> 00:40:17,150
+إذا التأكسد خاص بماذا؟ ال primary و ال secondary
+
+444
+00:40:17,150 --> 00:40:22,090
+التيرتشاري مابصله أكسدة ليش؟ لأن الأكسد بدأ أفقد
+
+445
+00:40:22,090 --> 00:40:25,130
+من ال OH هيدروجينة و من الكربون اللي حامله
+
+446
+00:40:25,130 --> 00:40:27,850
+هيدروجينة طب الكربون اللي حامله مش حامله هيدروجينة
+
+447
+00:40:28,820 --> 00:40:33,540
+إذا الأكسدة لا تتم مع إيش؟ مع ال tertiary
+
+448
+00:40:33,540 --> 00:40:37,860
+alcohols، الآن مع ال primary وال secondary؟ بالتم،
+
+449
+00:40:37,860 --> 00:40:44,160
+شو بدها تعطيني؟الديهايد او كيتون وقت ايش بتعطي
+
+450
+00:40:44,160 --> 00:40:49,760
+الديهايد و وقت ايش بتعطي كيتون ال primary ببساطة
+
+451
+00:40:49,760 --> 00:40:55,480
+بيعطي الديهايد و ال secondary بيعطي كيتون واضح؟
+
+452
+00:40:55,480 --> 00:40:59,380
+اذا كأنه لو الانسان بده يلخص الكلام ان ال alcohol
+
+453
+00:40:59,380 --> 00:41:03,920
+في كام نوع؟ primary secondary و tertiary ال
+
+454
+00:41:03,920 --> 00:41:11,080
+tertiaryكفى الله المؤمنين القتال ..مش فيها كلمة شر
+
+455
+00:41:11,080 --> 00:41:17,300
+..وكفى الله المؤمنين القتال ال tertiary بتأكسدش ال
+
+456
+00:41:17,300 --> 00:41:22,400
+primary لما يتأكسد شو هيعطيني ال dihyde ال
+
+457
+00:41:22,400 --> 00:41:28,130
+secondary لما يتأكسد شو هيعطيني كيتونلحظته هيك
+
+458
+00:41:28,130 --> 00:41:34,290
+بيصير العلم ايش ماله؟ سهل انه ال alcohols تلاتة ال
+
+459
+00:41:34,290 --> 00:41:38,630
+primary او ال secondary او ال tertiary ال primary
+
+460
+00:41:38,630 --> 00:41:44,560
+هيعطيني aldehyde ال secondary كيتون ال tertiaryمش
+
+461
+00:41:44,560 --> 00:41:50,320
+حيت أكسد الان المرة الجاية بتجيجتين هنوضح ايش
+
+462
+00:41:50,320 --> 00:41:54,440
+العامل المؤكسد اللي بتتم فيه العملية يعني نبدأ من
+
+463
+00:41:54,440 --> 00:41:58,820
+هذه بنشرحها بتجيجتين وننتبه ان ال الديهايد ممكن
+
+464
+00:41:58,820 --> 00:42:06,400
+بعدين يعمل تفاعل تاني يصير أسد هذه زيادة واضح؟ لكن
+
+465
+00:42:06,400 --> 00:42:12,560
+الأكسد الأساسية الأولى ال primary شو بيصير؟الـ
+
+466
+00:42:12,560 --> 00:42:17,640
+secondary الـ tertiary لا يتأكسد الان ال primary
+
+467
+00:42:17,640 --> 00:42:22,200
+بعد ما يصير الديهاي ممكن لو العامل المؤكسد قوي
+
+468
+00:42:22,200 --> 00:42:28,660
+يمشي كمان مرحلة يصير أسد لو ضعيف بيظل زي ما هو إذا
+
+469
+00:42:28,660 --> 00:42:32,340
+بتصير قصتنا إيش العامل المؤكسد اللي استعملنا هان و
+
+470
+00:42:32,340 --> 00:42:37,340
+هان هان من الأساس مافيش أكسدة من هذه المقطة ان شاء
+
+471
+00:42:37,340 --> 00:42:40,120
+الله بنبدأ المرة الجاية
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/6-G8b-zOS0Y_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/6-G8b-zOS0Y_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..6ae450446c2170e5564f2dbcfff8d6b0d1cb84a8
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/6-G8b-zOS0Y_raw.json
@@ -0,0 +1 @@
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{"start": 385.67, "end": 386.11, "word": " كلور", "probability": 0.6177978515625}, {"start": 386.11, "end": 387.01, "word": " بتبدأ", "probability": 0.85595703125}, {"start": 387.01, "end": 387.29, "word": " هذه", "probability": 0.6318359375}, {"start": 387.29, "end": 387.91, "word": " الكلور", "probability": 0.9015299479166666}, {"start": 387.91, "end": 388.83, "word": " تسحب", "probability": 0.940673828125}, {"start": 388.83, "end": 389.25, "word": " جزء", "probability": 0.99609375}, {"start": 389.25, "end": 389.51, "word": " من", "probability": 0.994140625}, {"start": 389.51, "end": 390.21, "word": " الشحنة", "probability": 0.98779296875}], "temperature": 1.0}, {"id": 17, "seek": 40230, "start": 392.9, "end": 402.3, "text": "افترضوا ان كلهم فيهم شحنة سالبة قللت الشحنة السالبة هذا ال effect سحب الشحنة with drawing of the charge", "tokens": [995, 5172, 2655, 43042, 14407, 16472, 28242, 16095, 8978, 16095, 13412, 5016, 1863, 3660, 8608, 6027, 49401, 12174, 1211, 1211, 2655, 25124, 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497.99, "word": " عامل", "probability": 0.9373372395833334}, {"start": 497.99, "end": 498.57, "word": " مشترك", "probability": 0.9637044270833334}], "temperature": 1.0}, {"id": 22, "seek": 51955, "start": 499.8, "end": 519.56, "text": "اللي بيعمل resonance بناء على ذلك لو حد .. لو بدنا نجيب سؤال arsh is more acidic than aroh due to resonance غلط لأنه هنا فيه resonance و هنا فيه resonance طب هاش المختلف sulfur و oxygen اذا because of the size", "tokens": [6027, 20292, 4724, 1829, 25957, 1211, 30944, 44945, 16606, 15844, 29910, 23275, 45164, 11331, 3215, 4386, 45164, 47525, 8315, 8717, 7435, 1829, 3555, 8608, 33604, 6027, 594, 2716, 307, 544, 39514, 813, 594, 1445, 3462, 281, 30944, 32771, 1211, 9566, 5296, 33456, 3224, 34105, 8978, 3224, 30944, 4032, 34105, 8978, 3224, 30944, 23032, 3555, 8032, 33599, 9673, 46456, 46538, 33831, 4032, 9169, 1975, 15730, 570, 295, 264, 2744], "avg_logprob": -0.2545289785965629, "compression_ratio": 1.4314720812182742, "no_speech_prob": 0.0, "words": 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"word": " سؤال", "probability": 0.9915364583333334}, {"start": 504.18, "end": 505.24, "word": " arsh", "probability": 0.4432373046875}, {"start": 505.24, "end": 505.5, "word": " is", "probability": 0.94091796875}, {"start": 505.5, "end": 505.9, "word": " more", "probability": 0.96044921875}, {"start": 505.9, "end": 506.44, "word": " acidic", "probability": 0.98583984375}, {"start": 506.44, "end": 506.72, "word": " than", "probability": 0.93798828125}, {"start": 506.72, "end": 507.44, "word": " aroh", "probability": 0.821044921875}, {"start": 507.44, "end": 507.9, "word": " due", "probability": 0.8759765625}, {"start": 507.9, "end": 508.12, "word": " to", "probability": 0.97119140625}, {"start": 508.12, "end": 508.72, "word": " resonance", "probability": 0.96826171875}, {"start": 508.72, "end": 509.4, "word": " غلط", "probability": 0.9322916666666666}, {"start": 509.4, "end": 509.72, "word": " لأنه", "probability": 0.6717122395833334}, {"start": 509.72, "end": 509.94, "word": " هنا", 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"end": 2209.3, "word": " أخدناها", "probability": 0.9638671875}, {"start": 2209.3, "end": 2209.72, "word": " هي", "probability": 0.861328125}, {"start": 2209.72, "end": 2210.64, "word": " متعلقة", "probability": 0.9806315104166666}], "temperature": 1.0}, {"id": 93, "seek": 222036, "start": 2211.92, "end": 2220.36, "text": "بالكحولات بال R O H لكن لو صارت A R O H بنزينة أو حملة O H و قلتلكوا بدلوها ب C L و ب R لأ", "tokens": [3555, 6027, 4117, 5016, 12610, 9307, 20666, 497, 422, 389, 44381, 45164, 20328, 9640, 2655, 316, 497, 422, 389, 44945, 11622, 9957, 3660, 34051, 11331, 2304, 37977, 422, 389, 4032, 12174, 1211, 2655, 23275, 14407, 47525, 1211, 2407, 11296, 4724, 383, 441, 4032, 4724, 497, 5296, 10721], "avg_logprob": -0.1974283792078495, "compression_ratio": 1.3271028037383177, "no_speech_prob": 0.0, "words": [{"start": 2211.92, "end": 2212.4, "word": "بالكحولات", "probability": 0.939697265625}, {"start": 2212.4, "end": 2212.64, "word": " بال", "probability": 0.41259765625}, {"start": 2212.64, "end": 2213.18, "word": " R", "probability": 0.52099609375}, {"start": 2213.18, "end": 2213.46, "word": " O", "probability": 0.368408203125}, {"start": 2213.46, "end": 2213.7, "word": " H", "probability": 0.9853515625}, {"start": 2213.7, "end": 2213.94, "word": " لكن", "probability": 0.724609375}, {"start": 2213.94, "end": 2214.18, "word": " لو", "probability": 0.98828125}, {"start": 2214.18, "end": 2214.66, "word": " صارت", "probability": 0.9677734375}, {"start": 2214.66, "end": 2214.9, "word": " A", "probability": 0.75244140625}, {"start": 2214.9, "end": 2215.4, "word": " R", "probability": 0.9091796875}, {"start": 2215.4, "end": 2215.66, "word": " O", "probability": 0.99365234375}, {"start": 2215.66, "end": 2216.12, "word": " H", "probability": 0.99462890625}, {"start": 2216.12, "end": 2217.16, "word": " بنزينة", "probability": 0.8310546875}, {"start": 2217.16, "end": 2217.26, "word": " أو", "probability": 0.5107421875}, {"start": 2217.26, "end": 2217.52, "word": " حملة", "probability": 0.9015299479166666}, {"start": 2217.52, "end": 2217.7, "word": " O", "probability": 0.796875}, {"start": 2217.7, "end": 2217.92, "word": " H", "probability": 0.966796875}, {"start": 2217.92, "end": 2218.02, "word": " و", "probability": 0.82763671875}, {"start": 2218.02, "end": 2218.44, "word": " قلتلكوا", "probability": 0.80126953125}, {"start": 2218.44, "end": 2218.84, "word": " بدلوها", "probability": 0.951904296875}, {"start": 2218.84, "end": 2218.94, "word": " ب", "probability": 0.9384765625}, {"start": 2218.94, "end": 2219.12, "word": " C", "probability": 0.69287109375}, {"start": 2219.12, "end": 2219.26, "word": " L", "probability": 0.91015625}, {"start": 2219.26, "end": 2219.38, "word": " و", "probability": 0.9267578125}, {"start": 2219.38, "end": 2219.5, "word": " ب", "probability": 0.8505859375}, {"start": 2219.5, "end": 2219.78, "word": " R", "probability": 0.50732421875}, {"start": 2219.78, "end": 2220.36, "word": " لأ", "probability": 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2228.2, "word": " ال", "probability": 0.984375}, {"start": 2228.2, "end": 2228.9, "word": " aliphatic", "probability": 0.7069498697916666}, {"start": 2228.9, "end": 2229.72, "word": " compounds", "probability": 0.947265625}, {"start": 2229.72, "end": 2230.76, "word": " تبوا", "probability": 0.8356119791666666}, {"start": 2230.76, "end": 2230.94, "word": " هذا", "probability": 0.9228515625}, {"start": 2230.94, "end": 2231.42, "word": " الكلام", "probability": 0.9519856770833334}, {"start": 2231.42, "end": 2232.2, "word": " ممكن", "probability": 0.893310546875}, {"start": 2232.2, "end": 2232.72, "word": " نسألكوا", "probability": 0.96494140625}, {"start": 2232.72, "end": 2232.86, "word": " يا", "probability": 0.640625}, {"start": 2232.86, "end": 2233.1, "word": " صح", "probability": 0.865478515625}, {"start": 2233.1, "end": 2233.22, "word": " و", "probability": 0.98583984375}, {"start": 2233.22, "end": 2233.56, "word": " غلط", "probability": 0.9493815104166666}, {"start": 2233.56, "end": 2234.32, "word": " aromatic", "probability": 0.6591796875}, {"start": 2234.32, "end": 2235.82, "word": " alcohols", "probability": 0.90478515625}, {"start": 2235.82, "end": 2236.44, "word": " undergo", "probability": 0.94287109375}, {"start": 2236.44, "end": 2237.6, "word": " substitution", "probability": 0.96875}, {"start": 2237.6, "end": 2239.48, "word": " in", "probability": 0.95166015625}, {"start": 2239.48, "end": 2239.88, "word": " uneasy", "probability": 0.669921875}, {"start": 2239.88, "end": 2240.32, "word": " manner", "probability": 0.9033203125}, {"start": 2240.32, "end": 2240.82, "word": " مثلا", "probability": 0.97314453125}, {"start": 2240.82, "end": 2241.06, "word": " ولا", "probability": 0.85546875}, {"start": 2241.06, "end": 2242.02, "word": " ..", "probability": 0.72998046875}, {"start": 2242.02, "end": 2242.3, "word": " no", "probability": 0.537109375}, {"start": 2242.3, "end": 2242.54, "word": " they", "probability": 0.74658203125}, {"start": 2242.54, "end": 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بنتيجة تعمل هنا double bond طالما عملت double bond شو هيصير النتج الديهايد أو كيتون", "tokens": [10721, 5172, 28543, 2423, 39184, 389, 13672, 1829, 15844, 16247, 4117, 3794, 7435, 9957, 4032, 389, 15844, 33251, 25513, 11536, 9673, 2655, 3794, 28671, 4724, 11296, 16247, 4117, 3794, 7435, 9957, 3714, 3555, 33599, 25720, 6024, 48506, 8032, 3215, 12610, 3660, 45164, 6156, 28543, 14407, 30767, 1829, 39896, 4117, 15844, 13412, 28820, 10874, 11622, 38207, 8032, 25708, 2288, 29245, 9957, 29538, 11933, 1829, 8592, 4724, 29399, 1829, 7435, 3660, 6055, 25957, 1211, 34105, 3834, 6086, 23032, 6027, 15042, 6225, 42213, 2655, 3834, 6086, 13412, 2407, 39896, 9381, 13546, 28239, 2655, 7435, 2423, 16254, 11296, 25708, 34051, 9122, 36081, 11536], "avg_logprob": -0.22515624672174453, "compression_ratio": 1.723809523809524, "no_speech_prob": 0.0, "words": [{"start": 2324.11, "end": 2324.79, "word": "أفقد", "probability": 0.830078125}, {"start": 2324.79, "end": 2325.45, "word": " الـ", "probability": 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2550.18, "word": " إيش", "probability": 0.82958984375}, {"start": 2550.18, "end": 2550.62, "word": " العامل", "probability": 0.99072265625}, {"start": 2550.62, "end": 2551.18, "word": " المؤكسد", "probability": 0.99365234375}, {"start": 2551.18, "end": 2551.3, "word": " اللي", "probability": 0.841064453125}, {"start": 2551.3, "end": 2551.82, "word": " استعملنا", "probability": 0.90625}, {"start": 2551.82, "end": 2552.14, "word": " هان", "probability": 0.5582275390625}, {"start": 2552.14, "end": 2552.34, "word": " و", "probability": 0.61865234375}, {"start": 2552.34, "end": 2552.66, "word": " هان", "probability": 0.84765625}, {"start": 2552.66, "end": 2553.12, "word": " هان", "probability": 0.6961669921875}, {"start": 2553.12, "end": 2553.28, "word": " من", "probability": 0.60791015625}, {"start": 2553.28, "end": 2553.88, "word": " الأساس", "probability": 0.98046875}, {"start": 2553.88, "end": 2555.28, "word": " مافيش", "probability": 0.9251302083333334}, {"start": 2555.28, "end": 2555.98, "word": " أكسدة", "probability": 0.713671875}, {"start": 2555.98, "end": 2556.36, "word": " من", "probability": 0.90966796875}, {"start": 2556.36, "end": 2556.6, "word": " هذه", "probability": 0.92822265625}, {"start": 2556.6, "end": 2557.0, "word": " المقطة", "probability": 0.771728515625}, {"start": 2557.0, "end": 2557.16, "word": " ان", "probability": 0.66455078125}, {"start": 2557.16, "end": 2557.34, "word": " شاء", "probability": 0.95654296875}, {"start": 2557.34, "end": 2557.44, "word": " الله", "probability": 0.9580078125}, {"start": 2557.44, "end": 2558.08, "word": " بنبدأ", "probability": 0.8997395833333334}, {"start": 2558.08, "end": 2558.54, "word": " المرة", "probability": 0.97509765625}, {"start": 2558.54, "end": 2560.12, "word": " الجاية", "probability": 0.7242838541666666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2560.92875, "duration_after_vad": 2451.335624999991}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/635vH7PE99A_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/635vH7PE99A_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..7be7452f0f81323e1dd5a708258e82498d9b65cb
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/635vH7PE99A_postprocess.srt
@@ -0,0 +1,1992 @@
+1
+00:00:20,330 --> 00:00:25,410
+بسم الله الرحمن الرحيم اليوم ان شاء الله درسنا مش
+
+2
+00:00:25,410 --> 00:00:30,670
+في موضوع معين لأ هو مراجعة شاملة من خلال حل
+
+3
+00:00:30,670 --> 00:00:36,320
+الامتحانات السابقة استعدادا للامتحانالنصفي ربما
+
+4
+00:00:36,320 --> 00:00:40,320
+أحيانا اتلاحظوا بعض الأسئلة لامتحان النصفي كان
+
+5
+00:00:40,320 --> 00:00:44,380
+للفصل السابع المرة هذه طلبنا منكوا للفصل السادس
+
+6
+00:00:44,380 --> 00:00:49,160
+فمش مشكلة يعني الإنسان بيقدر يعرف الأسئلة هتلاحظوا
+
+7
+00:00:49,160 --> 00:00:54,980
+ان في عندنا أسئلة متنوعة بشكل عام دائما ننصح
+
+8
+00:00:54,980 --> 00:01:01,250
+الطلاب انه يهتموابالأفكار الأساسية العامة يكونوا
+
+9
+00:01:01,250 --> 00:01:06,030
+فاهمينها بنسبة أكبر هذا بمنعش أنه في أشياء متخصصة
+
+10
+00:01:06,030 --> 00:01:09,730
+لكن دائما الطالب أول شيء يجب أن يكون عنده يعني
+
+11
+00:01:09,730 --> 00:01:14,190
+قناع أن هو فاهم الاشي الأفكار العامة ولذلك ربما
+
+12
+00:01:14,190 --> 00:01:19,110
+تلاحظوا أنه يعني لو أنا بدأ أصنف الأسئلة مش في هذا
+
+13
+00:01:19,110 --> 00:01:24,450
+الامتحان في معظم الامتحانات هنكتشف أنه هي عنوين
+
+14
+00:01:25,470 --> 00:01:30,250
+يعني هي عنوين لأشياء احنا درسناها خلينا نشوف هذا
+
+15
+00:01:30,250 --> 00:01:35,710
+الكلام من خلال التطبيق الآن في هذا الامتحان اللي
+
+16
+00:01:35,710 --> 00:01:41,350
+أمامنا في عندنا مجموعة من الجمال هذه المجموعة من
+
+17
+00:01:41,350 --> 00:01:46,450
+الجمال بدنا نكمل الفراغ فيها complete the
+
+18
+00:01:46,450 --> 00:01:50,450
+following السؤال أول مثلا بيسألنا الدياستيريو
+
+19
+00:01:50,450 --> 00:01:55,210
+مارزهاف و بيحكي عن ال physical propertiesالان كان
+
+20
+00:01:55,210 --> 00:01:58,970
+واضح تماما ان ال بيستيريو مارز هيف different
+
+21
+00:01:58,970 --> 00:02:02,390
+physical
+
+22
+00:02:02,390 --> 00:02:10,670
+properties واضح الان السؤال التاني addition of HBr
+
+23
+00:02:10,670 --> 00:02:17,410
+H plus to isobutene produces لاحظوا هنا السؤال هذا
+
+24
+00:02:17,410 --> 00:02:22,070
+في فكرتين ان الطالب لازم في الأول يعرف ايش هو ال
+
+25
+00:02:22,070 --> 00:02:28,970
+isobuteneهذا ال isobutene واضح بعد هيك إضافة ال
+
+26
+00:02:28,970 --> 00:02:35,930
+HBR H plus معناه ذلك هذه إضافة حسب Markov-Nikov
+
+27
+00:02:35,930 --> 00:02:40,670
+addition يعني هذه بدها تروح يجي عند هنا H و يجي
+
+28
+00:02:40,670 --> 00:02:44,070
+عند هنا CL او PR و بنحكي عن PR
+
+29
+00:02:47,350 --> 00:02:53,650
+الان هذا المركب اللى طلع عندى carbon حاملة CH3 CH3
+
+30
+00:02:53,650 --> 00:03:01,230
+CH3Br هذه مجموعة لها اسم ولا لأ تيرتشاري بيوتل
+
+31
+00:03:01,230 --> 00:03:09,310
+إبرومايد produces tertiary butyl bromide من تسمية
+
+32
+00:03:09,310 --> 00:03:16,810
+المجموعات produces tertiary butyl bromideالان فكرة
+
+33
+00:03:16,810 --> 00:03:20,890
+عامة قلنا ال branched alkanes اللي هم ال boiling
+
+34
+00:03:20,890 --> 00:03:23,930
+point و ال melting point lower than ال chain
+
+35
+00:03:23,930 --> 00:03:28,390
+alkanes الان ال branched alkanes هم اكيد هنا هتكون
+
+36
+00:03:28,390 --> 00:03:32,110
+higher او lower boiling point than the
+
+37
+00:03:32,110 --> 00:03:37,890
+corresponding chain lower ال
+
+38
+00:03:37,890 --> 00:03:44,850
+curved arrows قلنا عنهمالهم رأسين are used to
+
+39
+00:03:44,850 --> 00:03:53,830
+indicate the movement of two electrons ممتاز ال
+
+40
+00:03:53,830 --> 00:04:00,350
+reaction المهم من البنزين هو أي تحديد تحديد
+
+41
+00:04:00,350 --> 00:04:07,070
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+42
+00:04:07,070 --> 00:04:10,130
+الهواتف الهواتف
+
+43
+00:04:10,130 --> 00:04:10,910
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+44
+00:04:10,910 --> 00:04:11,090
+الهواتف الهواتف الهواتف الهواتف الهواتف الهواتف
+
+45
+00:04:11,810 --> 00:04:24,490
+الكلهيليتز اليوكليوفيليك اليوكليوفيليك
+
+46
+00:04:28,790 --> 00:04:33,570
+Dipromination of a Neopentane gives a total of ..
+
+47
+00:04:33,570 --> 00:04:38,110
+لاحظوا معي تكونوا عارفين لـ Neopentane يعني أنا
+
+48
+00:04:38,110 --> 00:04:41,950
+هنا باختبركم أن تكونوا عارفين هذا المُركّب لـ
+
+49
+00:04:41,950 --> 00:04:45,470
+Neopentane اللي هي الكربون اللي حاملة كام مثل؟
+
+50
+00:04:45,470 --> 00:04:49,910
+أربعة الأربعة الأربعة دي دي Dipromination
+
+51
+00:04:51,580 --> 00:04:57,320
+يعني احض ذرتين abroad كم ناتج بتوقع التنتين ممكن
+
+52
+00:04:57,320 --> 00:05:00,880
+ييجوا على نفس الذرع اذا اجوا تنتين هان زي هان زي
+
+53
+00:05:00,880 --> 00:05:08,060
+هان و ممكن ييجوا علىدرتين مختلفتين يعني ايه ييجي
+
+54
+00:05:08,060 --> 00:05:12,460
+هان و هان لحظوا هان و هان زي هذه و هذه زي هذه و
+
+55
+00:05:12,460 --> 00:05:15,860
+هذه زي هذه و هذه لأن المجموعات كلها ماخدة
+
+56
+00:05:15,860 --> 00:05:19,140
+tetrahedral arrangement متذكرين لما كنا نقول مافيش
+
+57
+00:05:19,140 --> 00:05:23,100
+اشي اسمه مجموعتين جان بعض و اشي اسمه مجموعتين قبال
+
+58
+00:05:23,100 --> 00:05:27,280
+بعض يعني تيجي طالبة تقول حط ال .. البروم هان و هان
+
+59
+00:05:27,280 --> 00:05:30,860
+بتختلف عن البروم هان و هان لأ هذه الزاوية PR, CPR
+
+60
+00:05:30,860 --> 00:05:37,280
+قداش مقدارهامية و تسعة و نص كربون حملة PR كربون كم
+
+61
+00:05:37,280 --> 00:05:40,640
+.. كربون حملة PR كدهش مقدارها؟ مية و تسعة و نص إذا
+
+62
+00:05:40,640 --> 00:05:45,260
+كم ناتج هنا؟ أربعة ليش أربعة؟ مش هو two bromine
+
+63
+00:05:45,260 --> 00:05:50,800
+atoms طيب انا .. انا حطيت two bromine atoms أو
+
+64
+00:05:50,800 --> 00:05:53,720
+حطيت وحدها وحدها هاي معناه die bromination طيب و
+
+65
+00:05:53,720 --> 00:05:57,100
+لو حطنا على ال carbon نفل نص ال carbon نفل نص
+
+66
+00:05:57,100 --> 00:05:58,540
+بيصير على خمس روابط؟
+
+67
+00:06:01,850 --> 00:06:05,670
+يا التنتين على هذه الذرة، يا التنتين كل واحدة على
+
+68
+00:06:05,670 --> 00:06:11,690
+ذرة، سواء كانت هان أو هان أو هان، إذا كان مركب two
+
+69
+00:06:11,690 --> 00:06:15,910
+isomers، structural isomers of course
+
+70
+00:06:18,990 --> 00:06:24,790
+The IUPAC name of allyl chloride لاحظوا كام سؤال
+
+71
+00:06:24,790 --> 00:06:28,970
+صار جايكم اؤكد انكوا تكونوا عارفين المجموعات
+
+72
+00:06:28,970 --> 00:06:32,150
+والمركبات الأساسية اللي أخدناها جيبنا ال tertiary
+
+73
+00:06:32,150 --> 00:06:38,430
+butyl هاي جيبنا ال allyl اللي هي CH2 CH double
+
+74
+00:06:38,430 --> 00:06:44,770
+bond CH2 Hanachlor وقولنا سابقا ان هذا بدو يتسمى
+
+75
+00:06:44,770 --> 00:06:53,810
+واحد اتنينتلاتة اذا three chloro one
+
+76
+00:06:53,810 --> 00:07:04,450
+propene three chloro one propene واضح؟
+
+77
+00:07:04,450 --> 00:07:09,150
+فحفظ المجموعات بين القليل ايزو بروبيل ايزو بيوتل
+
+78
+00:07:09,150 --> 00:07:13,250
+اساسي جداgeneration of the second chiral center
+
+79
+00:07:13,250 --> 00:07:19,290
+produces unequal mixture of diastereomers هذا أكمل
+
+80
+00:07:19,290 --> 00:07:26,470
+الجواب، هيك العنوان صح ولا لأ؟ unequal mixture of
+
+81
+00:07:26,470 --> 00:07:32,470
+diastereomers والfirst
+
+82
+00:07:32,470 --> 00:07:36,350
+chiral center شو كان بيعمل؟ racemic mixture of
+
+83
+00:07:36,350 --> 00:07:42,090
+enantiomers the meso compound is opticallyinactive
+
+84
+00:07:42,090 --> 00:07:47,630
+كان عنوان meso compounds are optically inactive
+
+85
+00:07:47,630 --> 00:07:54,790
+واضح هي دي مراجعة شاملة خلينا نقوله بعتقد جميلة
+
+86
+00:07:54,790 --> 00:07:59,930
+لمفاهيم أساسية أخدناها واضحة
+
+87
+00:08:12,680 --> 00:08:18,980
+الان بعد هيك ارسمولنا أشكال بعض المركبات
+
+88
+00:08:18,980 --> 00:08:22,000
+Cyclobentane
+
+89
+00:08:22,000 --> 00:08:26,500
+مين ما بيعرفوا ال Cyclobentane؟ هاي ال
+
+90
+00:08:26,500 --> 00:08:30,500
+Cyclobentane أسس على نمرة واحد و تلت يعني لو قولنا
+
+91
+00:08:30,500 --> 00:08:38,230
+هنا مثلا خلينا نحط إبروم للأمام وهنابروم هاي واحد
+
+92
+00:08:38,230 --> 00:08:43,990
+اتنين تلاتة وستعملنا
+
+93
+00:08:43,990 --> 00:08:51,070
+الشكل الفراغي عشان نبين انه مجموعتين للامام الان
+
+94
+00:08:51,070 --> 00:08:58,450
+Cyclohexane نعرف ال Cyclohexane هاي Cyclohexane
+
+95
+00:08:58,450 --> 00:09:03,980
+والترقيم بيكون واحدتنين و نستمر نمر عبر ال double
+
+96
+00:09:03,980 --> 00:09:09,280
+bond صح ولا لأ يعني واحد اتنين تلاتة اربعة خمسة
+
+97
+00:09:09,280 --> 00:09:12,280
+ستة الان على نمرة اتنين ايش في اندي في ال
+
+98
+00:09:12,280 --> 00:09:24,860
+Cyclohexane بروم وعلى نمرة تلاتة isopropyl for
+
+99
+00:09:24,860 --> 00:09:32,020
+nitroicumin اخدنا الاكيومين انه ال isopropylبنزين
+
+100
+00:09:32,020 --> 00:09:38,360
+قلنا ايزوبروب البنزين is كيومين لما بتحط على
+
+101
+00:09:38,360 --> 00:09:49,060
+الأربعة ن او اتو for نيترو كيومين الان المركب هذا
+
+102
+00:09:49,060 --> 00:09:54,420
+بدنا نسميه اين و اين ضايقين
+
+103
+00:09:55,420 --> 00:10:01,040
+لما بدنا ننتبه من وين بدنا نعمل الترقيم يعني واحد
+
+104
+00:10:01,040 --> 00:10:06,460
+اتنين تلاتة اربعة خمسة و هنا في كمان carbon ستة
+
+105
+00:10:06,460 --> 00:10:10,840
+طبعا لاحظوا انه انا لو برقم من هنا بيكون double
+
+106
+00:10:10,840 --> 00:10:16,120
+points عند اتنينوخمسة لو برقم هنا عند واحد اتنين
+
+107
+00:10:16,120 --> 00:10:19,860
+واحد واربعة لازم اسعى ان ال double poles يكونوا
+
+108
+00:10:19,860 --> 00:10:25,160
+اقل ترقيم اذا هذا هقول واحد اتنين تلاتة اربعة خمسة
+
+109
+00:10:25,160 --> 00:10:33,960
+ستة فهذا المركب هيكون one four hexadien
+
+110
+00:10:33,960 --> 00:10:41,370
+ايش بيحمل على نمرة تلاتة وعلى نمرة اربعةأه إذا هذا
+
+111
+00:10:41,370 --> 00:10:49,490
+كمان بدو ييجي عليه three four diapromo one four
+
+112
+00:10:49,490 --> 00:10:55,660
+الآن هذا double bondمافيش عليها مجموعات مختلفان و
+
+113
+00:10:55,660 --> 00:10:58,500
+.. يعني مافيش فيها ظاهرة ال sexual trance بس هذا
+
+114
+00:10:58,500 --> 00:11:02,700
+ال double bond فيها .. يعني هنا في عندى مثل و أتش،
+
+115
+00:11:02,700 --> 00:11:07,040
+لاحظوا كل رأس زي هذا يعتبر مثل، انتبهوله في العد و
+
+116
+00:11:07,040 --> 00:11:12,110
+انتبهوله لما تشتغلوا، المثل أعلى من الأتشالمثل
+
+117
+00:11:12,110 --> 00:11:17,350
+أعلى من الـ H هنا PR و Carbon أنا باطلع فقط على
+
+118
+00:11:17,350 --> 00:11:20,470
+الذرة الأولى و الأولى هذه PR وهذه Carbon الآن
+
+119
+00:11:20,470 --> 00:11:25,410
+هذولا المجمعتين على جهة واحدة إذا هذا المركب Z
+
+120
+00:11:25,410 --> 00:11:31,610
+فلما بدي تسمية كاملة Z three four dibromo one four
+
+121
+00:11:31,610 --> 00:11:33,050
+hexadien
+
+122
+00:11:35,670 --> 00:11:38,790
+واضح؟ ال double bond التانية مافيش فيها أي شيء
+
+123
+00:11:38,790 --> 00:11:42,490
+طبعا واضح أنه هنا في chiral center لكن طالما أنا
+
+124
+00:11:42,490 --> 00:11:47,010
+ماحطتوش على شكل صليب معناه ذلك أنا مش مركز أني
+
+125
+00:11:47,010 --> 00:11:54,470
+اتحددولي IR أو استركتو مفتوح هذا المركب مثلا في
+
+126
+00:11:54,470 --> 00:11:58,330
+chiral center وموضح أنه أنا طالب ال chiral center
+
+127
+00:11:58,330 --> 00:12:06,270
+هنا واضح؟ لو أتيت طلعت أطول سلسلةانعلمها بالاحمر
+
+128
+00:12:06,270 --> 00:12:14,430
+واحد اتنين تلاتة اربعة اذا هذا بيوتين ايش بيحمل
+
+129
+00:12:14,430 --> 00:12:19,450
+هذا البيوتين على البيوتين واحد اتنين تلاتة اربعة
+
+130
+00:12:19,450 --> 00:12:26,870
+على نمرة واحد اكلور وعلى نمرة تلاتة فنل والترقيم
+
+131
+00:12:26,870 --> 00:12:29,770
+منها لان لو رقمتي منها هيصيروا على اتنين واربعة
+
+132
+00:12:29,770 --> 00:12:38,510
+بدي ال lower numbering اذا هذاone chloro three
+
+133
+00:12:38,510 --> 00:12:47,330
+phenyl بيوتين الان في chiral center ال chiral
+
+134
+00:12:47,330 --> 00:12:53,370
+center هنا ال H أقل مجموعة أكيد البنزينة نمرة واحد
+
+135
+00:12:53,370 --> 00:13:00,310
+الكاربون هذه نمرة اتنين وال CH3 نمرة تلاتةواحد
+
+136
+00:13:00,310 --> 00:13:06,870
+اتنين تلاتة وهذه موجودة اذا هذا اس one chlorine
+
+137
+00:13:06,870 --> 00:13:08,750
+three phenyl butane
+
+138
+00:13:15,300 --> 00:13:19,960
+المُركّب اللي بعده aromatic فيه مجموعتين، معنا ذلك
+
+139
+00:13:19,960 --> 00:13:24,020
+السؤال إنه مين أعلى في الأولوية عشان أسمه إيه؟ ال
+
+140
+00:13:24,020 --> 00:13:27,600
+ketone ولا ال alcohol؟ ال ketone، الآن هذا
+
+141
+00:13:27,600 --> 00:13:32,320
+المُركّب إيش اسمه؟ أسيتوفينون، نكتب small letter
+
+142
+00:13:34,690 --> 00:13:40,030
+acetophenon ال O H بترجع على أصلها ال three one
+
+143
+00:13:40,030 --> 00:13:45,710
+two three ال three أو ميتا هيدروكسي الشغلتين صح ال
+
+144
+00:13:45,710 --> 00:13:50,470
+three هيدروكسي أسيتوفينون كلمة واحدة واضح ال three
+
+145
+00:13:50,470 --> 00:13:57,030
+هيدروكسي أسيتوفينون بتيعني كل هذه من ضمن الأفكار
+
+146
+00:13:57,030 --> 00:14:01,610
+العامة الأساسية اللي احنا درسناكم
+
+147
+00:14:18,380 --> 00:14:25,580
+الان بعد ذلك عندى اكمال معادلات هذا المركب مثل
+
+148
+00:14:25,580 --> 00:14:32,160
+Cyclopropane مثل Cyclopropane وحطينا لكوا بدنا
+
+149
+00:14:32,160 --> 00:14:37,020
+نشوف all structural isomers يعني مش مركز انا على
+
+150
+00:14:37,020 --> 00:14:40,720
+ال stereo isomers او اعمله monochlorination يعني
+
+151
+00:14:40,720 --> 00:14:46,860
+احط one chlorine atomواضح؟ وين بده احط هذه ال
+
+152
+00:14:46,860 --> 00:14:55,400
+chlorine طبعا هنبدأ نرسم اكثر من شكل مش عارف تلاتة
+
+153
+00:14:55,400 --> 00:14:59,900
+اربعة بنجرب احنا الان اكيد ال chlorine بإمكانها
+
+154
+00:14:59,900 --> 00:15:06,810
+تيجي هنا على المثلوأكيد ال chlorine بإمكانها تيجي
+
+155
+00:15:06,810 --> 00:15:11,250
+على هذا الموقع وأكيد ال chlorine بإمكانها تيجي على
+
+156
+00:15:11,250 --> 00:15:15,510
+هذا الموقع لأن هذا و هذا زي بعض، ضال عندكم إشي
+
+157
+00:15:15,510 --> 00:15:21,170
+تاني؟ خلاص وكل
+
+158
+00:15:21,170 --> 00:15:23,210
+واحد فيهم أكيد إله اسم مختلف
+
+159
+00:15:29,980 --> 00:15:35,600
+الان لاحظوا معي هذا المركب فيه double bond بنقول
+
+160
+00:15:35,600 --> 00:15:40,880
+في نمر واحد بدنا نضيف عليه pear acid ايش معناه
+
+161
+00:15:40,880 --> 00:15:48,260
+pear acid انه بده يلغي هذه و يعملي حلقة لكن انا
+
+162
+00:15:48,260 --> 00:15:53,160
+كمان بعد ما عملت هذه الحلقة بده اعمل ring opening
+
+163
+00:15:53,160 --> 00:15:59,920
+ضيفت ميهواضحة الفكرة؟ كيف هذي بتعمل ring opening؟
+
+164
+00:15:59,920 --> 00:16:07,240
+بيكونوا سن ولا أنتي؟ مجموعات ال OHS ال
+
+165
+00:16:07,240 --> 00:16:10,360
+ring opening من البرأس الانتي
+
+166
+00:16:12,610 --> 00:16:17,550
+هي الميه من وين بتيجي عكس هذه اللي كان يعمل sin
+
+167
+00:16:17,550 --> 00:16:22,350
+addition لمجموعتين OH الكيامان O4 والأزوميوم O4
+
+168
+00:16:22,350 --> 00:16:27,590
+أخدناهم بيعملوا sin addition لمجموعتين OH لكن بهذه
+
+169
+00:16:27,590 --> 00:16:31,890
+الطريقة بنطلع ال Anti product اللي كان واضح تماما
+
+170
+00:16:31,890 --> 00:16:37,350
+يعني بدكوا تحطوا OH على جهة و OH على الجهة التانية
+
+171
+00:16:37,350 --> 00:16:42,720
+بالتأكيد هنا هتكون هذه المجموعة هيكهيأجوا اشمالهم
+
+172
+00:16:42,720 --> 00:16:47,880
+انتي طبعا
+
+173
+00:16:47,880 --> 00:16:51,600
+اي واحدة متذاكرة جيدا مش ضروري تفكر تعمل زي هيك
+
+174
+00:16:51,600 --> 00:16:54,900
+خلاص هو ال bare acid و بعدين نعمل ring opening في
+
+175
+00:16:54,900 --> 00:17:00,660
+الميه هذا محصلته في الدماغ بيحط مجمعتين OH انتي
+
+176
+00:17:00,660 --> 00:17:09,120
+انتي طبعا الان لما نضيف H2 في وجود platinum
+
+177
+00:17:20,030 --> 00:17:25,790
+هذا المُركّب اللي فيه ال PR لحظة انا هنا حاططلكم
+
+178
+00:17:25,790 --> 00:17:29,290
+KOH و جايلكم ان انا بدي ال major elimination
+
+179
+00:17:29,290 --> 00:17:33,950
+product كأني بقول انو حطوا double bond هان او هان
+
+180
+00:17:33,950 --> 00:17:39,750
+واضح انه كتير ركزنا معاكم انه the more substituted
+
+181
+00:17:39,750 --> 00:17:44,710
+ال keenوالـ Form حسب قاعدة Zaitsev إذا هنا بدو
+
+182
+00:17:44,710 --> 00:17:52,170
+ييجي ال الـ K واضح؟ مش هتيجي ال PR مع هذه ال H لأن
+
+183
+00:17:52,170 --> 00:17:56,530
+هذا less substituted ال K هذا ال more substituted
+
+184
+00:17:56,530 --> 00:18:00,890
+الآن بعد هيك هذا المركب بدنا نضيف عليه ميا في وجود
+
+185
+00:18:00,890 --> 00:18:06,590
+H plus هذا إضافة Markovnikov لحظة هنا في carbon
+
+186
+00:18:06,590 --> 00:18:12,190
+تحمل H و هذه ال carbon لأ تحملش H إذالو حطينا
+
+187
+00:18:12,190 --> 00:18:19,390
+الشكل العام بس بتكون المشكلة وين أحط ال H وين أحط
+
+188
+00:18:19,390 --> 00:18:30,150
+ال OH حسب
+
+189
+00:18:30,150 --> 00:18:36,430
+قاعدة Markovnikov لأنه في الأساس هنا في عندكم H
+
+190
+00:18:36,430 --> 00:18:38,650
+اللي كانت متروكة فاضية
+
+191
+00:18:56,340 --> 00:19:03,760
+الان هنا بدنا نضيف HPR في وجود البروكسايد اذا هنا
+
+192
+00:19:03,760 --> 00:19:09,600
+الإضافة مع ولا عكس قاعدة Markovnikov عكس قاعدة
+
+193
+00:19:09,600 --> 00:19:15,520
+Markovnikov لاحظوا لما انا هنا بد اضيف H على هذه
+
+194
+00:19:15,520 --> 00:19:21,870
+الجهة و ال PR على اللي بتحمل Hانتبهوا معي ال H هنا
+
+195
+00:19:21,870 --> 00:19:26,350
+طالما عندكم مثل و مثل ماعملتش chiral center هنا
+
+196
+00:19:26,350 --> 00:19:30,390
+لأن هدول المجموعتين زي بعض يعني مافيش اد اربع
+
+197
+00:19:30,390 --> 00:19:35,850
+مجموعات مختلفة لكن هنا بدي يكون عندكم مثل و H و
+
+198
+00:19:35,850 --> 00:19:44,410
+هتيجيها ب Rهي مثل وهي H و إيش هيجي عندك PR في هذه
+
+199
+00:19:44,410 --> 00:19:50,450
+الحالة حيصير في كايرال سنتر على هذا الكربون الان
+
+200
+00:19:50,450 --> 00:19:56,410
+ال generation و في كايرال سنتر شو بيطلعلك رسمك
+
+201
+00:19:56,410 --> 00:20:01,550
+mixture كان هذا عنوان إذا انا لما بدي أجي أشتغل
+
+202
+00:20:01,550 --> 00:20:07,250
+الأصل بدي أشتغل بهذا الشكلهدولة بأي طريقة تكتبوها
+
+203
+00:20:07,250 --> 00:20:10,370
+مافيش فيها مشكلة إطلاقا لأنه مش chiral center في
+
+204
+00:20:10,370 --> 00:20:14,410
+النهاية يعني
+
+205
+00:20:14,410 --> 00:20:19,050
+لو كتبيه بأي طريقة مش مشكلة لكن هنا بدي أجي مثلا
+
+206
+00:20:19,050 --> 00:20:25,470
+أقول ال PR هان ال PR عكسها ممكن نكتب ال H و ال H و
+
+207
+00:20:25,470 --> 00:20:30,710
+نكتبالـ CH3 والـ CH3 أهم شيء نعمله .. أهم شيء
+
+208
+00:20:30,710 --> 00:20:38,610
+نعمله أن هذه المنطقة يكونوا هذولة أشملهم عكس بعض و
+
+209
+00:20:38,610 --> 00:20:42,330
+هذولة بيطلعوا ال 50 50 ratio
+
+210
+00:20:44,190 --> 00:20:47,510
+الان بأي طريقة تكتبوها مافيش مشكلة مش هيكون خلاف
+
+211
+00:20:47,510 --> 00:20:51,270
+يعني واحدة كتبت هنا PR و هنا CH3 و هنا H و عملت
+
+212
+00:20:51,270 --> 00:20:54,770
+صورتها مش مشكلة واحدة كتبت هنا CH3 و هنا H و هنا
+
+213
+00:20:54,770 --> 00:21:01,330
+PR مافيش مشكلة اهم يعني ارسموا التلاتة بأي شكل
+
+214
+00:21:01,330 --> 00:21:06,150
+بدكم إياه بس حطوا صورتهم في المرايا لو احنا نفس
+
+215
+00:21:06,150 --> 00:21:08,930
+الشكل بس شيلنا لابتا ثنائية و حاطينا ال PR هيك و
+
+216
+00:21:08,930 --> 00:21:10,770
+هيك وين تحط ال PR؟
+
+217
+00:21:25,670 --> 00:21:29,510
+الان السؤال اللي بعده draw all the possible
+
+218
+00:21:29,510 --> 00:21:34,870
+isomers having the formula C3H4
+
+219
+00:21:35,800 --> 00:21:41,180
+الان عندما تفكر في هذا الكلام تفكر في صيغة العامة
+
+220
+00:21:41,180 --> 00:21:52,320
+للمركبات الوضع الطبيعي ال C3 بتاخد HS في
+
+221
+00:21:52,320 --> 00:21:59,470
+الألكال اللي كله single bonds يعني ال C3H8 في
+
+222
+00:21:59,470 --> 00:22:07,170
+الالكينز صح؟ الان اذا شيلت منها هيدروجينتين صارت
+
+223
+00:22:07,170 --> 00:22:12,870
+C3H6 مقابل ان شيلتم يا عملت bubble bond يا حلقة
+
+224
+00:22:12,870 --> 00:22:17,910
+الان لسه انا مش بس هيدروجنتين بده اشيل كمان تنتين
+
+225
+00:22:17,910 --> 00:22:22,690
+يعني شيلت هيدروجنتين وكمان هيدروجنتين معنى ذلك
+
+226
+00:22:22,690 --> 00:22:27,870
+التفكير اللي بده يكون عندكم اما تنتين bubble bonds
+
+227
+00:22:28,750 --> 00:22:35,290
+أو تنتين حلقات او حلقة و double bond واضح؟ لأن كل
+
+228
+00:22:35,290 --> 00:22:39,130
+هيدروجينتين معناهم ان انت شيلتوا ايش؟ يا عملتوا
+
+229
+00:22:39,130 --> 00:22:42,810
+double bond يا عملتوا حلقة واضح؟ فانا شيلت
+
+230
+00:22:42,810 --> 00:22:46,310
+هيدروجين مرتين بين التمانية والاربعة اربع
+
+231
+00:22:46,310 --> 00:22:50,750
+هيدروجينات تنتين و تنتين الآن بدكوا تقولوا يا
+
+232
+00:22:50,750 --> 00:22:54,790
+تنتين double bonds يا تنتين حلقات يا double bond
+
+233
+00:22:54,790 --> 00:23:01,040
+وحلقة طبعا ال C3H4 ما بتحتملتلتين حلقات يعني كلها
+
+234
+00:23:01,040 --> 00:23:05,860
+كم ذرة هي تلاتة بناء على ذلك لو أنا فكرت أني بدأ
+
+235
+00:23:05,860 --> 00:23:10,220
+أعمل منهم حلقة حلقة واحدة لازم ألاحقها بكمان ايش
+
+236
+00:23:10,220 --> 00:23:14,760
+double bond لاحظوا لو هنا اتيتوا تكملوا ال
+
+237
+00:23:14,760 --> 00:23:20,420
+hydrogens هتطلع الفورموله صح اتش اتش اتش اتش اتش
+
+238
+00:23:20,420 --> 00:23:23,500
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+239
+00:23:26,930 --> 00:23:32,270
+هذا الاحتمال اللى فيه حلقات الان بعد هيك ممكن اعمل
+
+240
+00:23:32,270 --> 00:23:37,870
+التنتين bubble bonds اعتبرهم ال kind triple bond
+
+241
+00:23:37,870 --> 00:23:48,130
+يعني احط C triple bond C و هنا CH3 CH3
+
+242
+00:23:48,130 --> 00:23:55,510
+و هذه H هدولة بمثابة تنتين bubble bonds هاي CH3
+
+243
+00:23:57,130 --> 00:24:02,770
+ممكن احط تنتين double bonds جانب بعض carbon double
+
+244
+00:24:02,770 --> 00:24:07,490
+bond carbon double bond carbon وهنا بدو يكون عندكم
+
+245
+00:24:07,490 --> 00:24:14,490
+CH2 CH2
+
+246
+00:24:14,490 --> 00:24:15,910
+في غير هيك؟
+
+247
+00:24:19,310 --> 00:24:23,910
+أهم شيء اللى بنى عليها هذا السؤال انه نفهم احنا ان
+
+248
+00:24:23,910 --> 00:24:31,610
+الصيغة المشبعة تماما لل C3 هي H8 الان مقابل كل
+
+249
+00:24:31,610 --> 00:24:35,990
+هيدروجينتين بخصومهم بدي اعمل double bond او حلقة
+
+250
+00:24:35,990 --> 00:24:41,170
+واضح فخصمت هيدروجنتين على كام مرة امرتين اربعة
+
+251
+00:24:41,170 --> 00:24:44,730
+تقسيم اتنين اتنين فهنا عملت حلقة و double bond هنا
+
+252
+00:24:44,730 --> 00:24:47,370
+عملت تنتين by bonds هنا عملت تنتين double bonds
+
+253
+00:24:49,120 --> 00:24:53,720
+ولما تكملوا الشكل كيميائيا شكل سليم 100% ولا لأ؟
+
+254
+00:25:08,560 --> 00:25:13,280
+الان هذا السؤال نمشي أسرع على تفاعل ال الكاينز
+
+255
+00:25:13,280 --> 00:25:17,380
+قلنا ال terminal الكاينز are acidic يعني هذا شو
+
+256
+00:25:17,380 --> 00:25:23,400
+بده يعطينا فنل C triple bond C minus الان إذا
+
+257
+00:25:23,400 --> 00:25:31,440
+فعلتوا مع إيثالبروميد CH3 CH2Br بده يعمل عليها ال
+
+258
+00:25:31,440 --> 00:25:36,890
+eucleophilic substitution هذه الكربون اتهاجمهاتطرد
+
+259
+00:25:36,890 --> 00:25:43,610
+ال PR ما هو ذا نيوكليو 5 إذا النتيجة فينيل C
+
+260
+00:25:43,610 --> 00:25:55,130
+triple bond C وهنا هياتحدت مع CH2 CH3 طردت ال PR
+
+261
+00:25:55,130 --> 00:26:02,330
+إبدالي نيوكليو فينيل الان هذا المركب مع ال lithium
+
+262
+00:26:02,330 --> 00:26:07,730
+و ال ammonia شو بيعمل؟Double bond هو اكيد بيضيف
+
+263
+00:26:07,730 --> 00:26:16,630
+الهيدروجين عكس بعض لكن مافيش فارق بالنتيجة هايو
+
+264
+00:26:16,630 --> 00:26:20,910
+الهيدروجين اللي ضفته كيف اجوا عكس بعض لكن المراكب
+
+265
+00:26:20,910 --> 00:26:26,810
+لا فيه cis ولا trans لأن هدوله زي بعض الان بعد هيك
+
+266
+00:26:26,810 --> 00:26:30,450
+هذا المراكب بتعمله اوزونوليسيز شو ال اوزونوليسيز
+
+267
+00:26:30,450 --> 00:26:35,130
+نكسر ال double bond لتنتين
+
+268
+00:26:36,290 --> 00:26:42,030
+C double bond O إذا
+
+269
+00:26:42,030 --> 00:26:47,130
+انكوّننا الألكين وبعدين كسرنا لتنتين C double bond
+
+270
+00:26:47,130 --> 00:26:48,830
+O هذا ال ozoneolysis
+
+271
+00:27:03,880 --> 00:27:10,080
+بعد هيك السؤال كيف ممكن نحضر المراكبات الآتية سيس
+
+272
+00:27:10,080 --> 00:27:15,900
+وانتو سايكلو بنتين دايول يعني
+
+273
+00:27:15,900 --> 00:27:26,420
+هنا سايكلو بنتين و OH و OH على جهة واحدة الآن أي
+
+274
+00:27:26,420 --> 00:27:32,140
+واحدة فيكوا شاطرة هتقول السيس كيف كنت أجيبه ترجع
+
+275
+00:27:32,140 --> 00:27:41,640
+برجوعالألكين مع الكيامان او فور في ال basic medium
+
+276
+00:27:41,640 --> 00:27:48,440
+او اوزميام او فور الان انا كنت حاكي هنا مابديش
+
+277
+00:27:48,440 --> 00:27:51,820
+ابدأ من ال cyclopentane مابدي ابدأ من ال promo
+
+278
+00:27:51,820 --> 00:27:58,240
+cyclopentane يعني هنا في عند بي ار الان يا تورا
+
+279
+00:27:58,240 --> 00:28:06,550
+هذه ال بي ار فيش جنب هاتشها اكيدبقدر استعمل KOH
+
+280
+00:28:06,550 --> 00:28:20,150
+بتصير ألكيل والألكيل بضيف عليه الميه starting
+
+281
+00:28:20,150 --> 00:28:29,490
+from بنزين برا نيترو كيومين هيلي
+
+282
+00:28:29,490 --> 00:28:35,410
+كيومين وحملة نيترواللي متذكرة هذي بتودي على الميتا
+
+283
+00:28:35,410 --> 00:28:39,790
+هذي Orthobara ال الكلي جروبز كلهم ال R Orthobara
+
+284
+00:28:39,790 --> 00:28:44,610
+الآن الوضع اللي موجود عندك اذا اول اشي انا بدي
+
+285
+00:28:44,610 --> 00:28:54,250
+اعمله اني بدي احضر هذا المركب وبعدين اه الان بيضل
+
+286
+00:28:54,250 --> 00:28:56,350
+ايش ال reagents ايزوبروبليكلورايد
+
+287
+00:28:56,350 --> 00:29:02,740
+ايزوبروبليكلورايد معالألمنيوميكلورايد او whatever
+
+288
+00:29:02,740 --> 00:29:11,080
+وبعدين هنا بدي اعمل نيتريشن بيطلع
+
+289
+00:29:11,080 --> 00:29:19,680
+ال ortho زائد البارا product واضح؟
+
+290
+00:29:21,290 --> 00:29:26,590
+هي الامتحان كامل مع الشريح والتفصيل الممل اعملناه
+
+291
+00:29:26,590 --> 00:29:29,350
+معاكم بطول الساعة اكيد لما يجيكوا انتوا كطلاب
+
+292
+00:29:29,350 --> 00:29:34,430
+هتاخدوا عليه ساعة لكن السؤال في حرف منه خارج عن
+
+293
+00:29:34,430 --> 00:29:37,590
+اللي درسته؟ الحمد لله ربنا
+
+294
+00:29:48,970 --> 00:29:54,650
+خلّينا نكسب الوقت و نحل امتحان من باب المراجعة
+
+295
+00:29:54,650 --> 00:29:58,030
+الشاملة
+
+296
+00:29:58,030 --> 00:30:16,490
+هذا
+
+297
+00:30:16,490 --> 00:30:27,530
+الامتحانالنمط تبعه في سؤال صح و غلط خلينا
+
+298
+00:30:27,530 --> 00:30:31,930
+نشوفه there are four types of hydrogen and
+
+299
+00:30:31,930 --> 00:30:37,170
+isobentane هذا بيستلزم ان انا اعرف ايش ال
+
+300
+00:30:37,170 --> 00:30:43,070
+isobentaneالان هاي ال eyes وبينتين كام نوع عندى من
+
+301
+00:30:43,070 --> 00:30:49,890
+ال hydrogens خلينا نقول هدول ال hydrogens زى بعض و
+
+302
+00:30:49,890 --> 00:30:59,490
+هدى و هدى و هدى نفس ايش؟ كيف؟
+
+303
+00:31:01,530 --> 00:31:06,390
+رجاءً لما بجيبلكوا سؤال ما تفكروش أنه أنواع ال
+
+304
+00:31:06,390 --> 00:31:10,970
+hydrogens أنه primary و secondary و tertiary مش
+
+305
+00:31:10,970 --> 00:31:14,590
+هذا اللي علمتكوا إياه إطلاقا، يعني من ال primary
+
+306
+00:31:14,590 --> 00:31:20,200
+ممكن يكون عندهكذا مجموعة برايمر لكن كل واحدة تمثل
+
+307
+00:31:20,200 --> 00:31:25,060
+نوع في الهيدروجينز واضح؟ عمره ماكان السؤال حددولي
+
+308
+00:31:25,060 --> 00:31:28,540
+كام نوع هيدروجينز انكوا تفكروا بكلمة برايمر و
+
+309
+00:31:28,540 --> 00:31:31,700
+سكندر و تيرتشل ولا هذا اللي علمناكم إياه يعني على
+
+310
+00:31:31,700 --> 00:31:36,520
+سبيل المثال على سبيل المثال حتى نأكد المعلومة الآن
+
+311
+00:31:36,520 --> 00:31:45,540
+لو حطيت هذا المركب هي هذه CH3 وهي هذه CH3 هذه زي
+
+312
+00:31:45,540 --> 00:31:51,700
+هذه؟لو حطيت هنا كلور بدل H من هنا زي ما حطي بدل H
+
+313
+00:31:51,700 --> 00:31:57,120
+من هنا مش كل CH3 بدي أقول عنها زي بعض ولا كل CH2
+
+314
+00:31:57,120 --> 00:32:04,380
+زي بعض لأ واضح؟ ولذلك هذا المركب الآن كام هيدروجين
+
+315
+00:32:04,380 --> 00:32:08,580
+فيه هدول المجمعتين زي بعض هي كمان نوع هي كمان نوع
+
+316
+00:32:08,580 --> 00:32:15,260
+هي كمان نوع أربع أنواع من الهيدروجين واضح؟طيب
+
+317
+00:32:15,260 --> 00:32:20,480
+احبطت شوية اتجاوزجالبة تقولي في هذا كام نوع من
+
+318
+00:32:20,480 --> 00:32:26,860
+الهيدروجين عندك؟ يعني لو قولنا لكوا برائث التلوين
+
+319
+00:32:26,860 --> 00:32:34,280
+كام نوع من الهيدروجين؟ واحد هدولة تنتين زي بعض،
+
+320
+00:32:34,280 --> 00:32:41,860
+هدول زي بعض، هدول زي بعض، هدول زي بعض، هدول زي
+
+321
+00:32:41,860 --> 00:32:43,760
+بعض، هدول زي بعض، هدول زي بعض، هدول زي بعض، هدول
+
+322
+00:32:43,760 --> 00:32:45,480
+بعض، هدول زي بعض، هدول زي بعض، هدول زي بعهتنسيش ان
+
+323
+00:32:45,480 --> 00:32:52,860
+هذه double bond ان هذه الدويرة اصلا و هدولة مافيش
+
+324
+00:32:52,860 --> 00:32:58,000
+عليهم غير مجموعة واحدة يعني انا واحد اتنين تلاتة
+
+325
+00:32:58,000 --> 00:33:02,100
+اربعة مافيش انا hydrogen فلما نكون راسمين دائرة
+
+326
+00:33:02,100 --> 00:33:05,840
+ماحدش يفكر ان هوان و هوان فيها hydrogen واضحة
+
+327
+00:33:05,840 --> 00:33:09,240
+الفكرة؟ هي اللي بيوجع الانسان في الغلط ان انا مش
+
+328
+00:33:09,240 --> 00:33:13,220
+راسم ال double bonds ان انا عامل هيك بس هذه لها
+
+329
+00:33:13,220 --> 00:33:17,180
+معنى في الكيميافما تفكروش ان هنا وهنا يوجد
+
+330
+00:33:17,180 --> 00:33:23,500
+هيدروجينز في الشكل يا
+
+331
+00:33:23,500 --> 00:33:28,780
+ريتما ماحطتش الامتحان كان جيبتي الكويزمة اه there
+
+332
+00:33:28,780 --> 00:33:33,460
+are three possible stereoisomers of 1,2
+
+333
+00:33:33,460 --> 00:33:39,460
+-dichlorobrobane الان لاحظوا بالكتورث مش شكل
+
+334
+00:33:39,460 --> 00:33:46,160
+البروبين كام كاربونتلاتة على نمرة واحد و اتنين في
+
+335
+00:33:46,160 --> 00:33:50,120
+عندى chlorine يعني هذه حملة chlorine و هذه حملة
+
+336
+00:33:50,120 --> 00:33:54,780
+chlorine لو كملنا ال hydrogens الان هنا CH2 هنا
+
+337
+00:33:54,780 --> 00:34:04,140
+CH3 الان من هذا المركب كم isomer عندى اه
+
+338
+00:34:04,140 --> 00:34:09,580
+بديش انسى ان في عندى chiral center هنا مافيش هنا
+
+339
+00:34:09,580 --> 00:34:13,940
+في chiral centerطالما عندي chiral center إذا
+
+340
+00:34:13,940 --> 00:34:23,740
+المركب و صورته إذا كام stereo isomer عند هنا الصح؟
+
+341
+00:34:23,740 --> 00:34:30,220
+نان .. نان هذا واحد اللي موجود عندكم حقيقة هو ال S
+
+342
+00:34:30,220 --> 00:34:35,900
+بتقدر ترسم صورته في المرايا ال R اللي موجود هو ال
+
+343
+00:34:35,900 --> 00:34:40,200
+S بتقدر ترسم ال R إذا هذه الجملة غلط
+
+344
+00:34:46,280 --> 00:34:53,080
+Addition of HBr Peroxide to styrene produces two
+
+345
+00:34:53,080 --> 00:34:59,040
+stereoisomers طبعا اللي مش عارف ال styrene زنبها ع
+
+346
+00:34:59,040 --> 00:35:08,500
+جنبها CH double bond CH2 لاحظوا هذا سؤال جميل لو
+
+347
+00:35:08,500 --> 00:35:13,060
+انا كنت باضيف HBr في وجود H plus هضيفه حسب قاعدة
+
+348
+00:35:13,060 --> 00:35:18,780
+Markovnikov هحط هنا ال Hوهنا ال PR وجدت في هذه
+
+349
+00:35:18,780 --> 00:35:24,080
+الحالة هعمل chiral center هنا هيطلع عندى ناتجين لو
+
+350
+00:35:24,080 --> 00:35:28,460
+أنا بضيف ال HPR في وجود H Plus هنا ال H هنا ال PR
+
+351
+00:35:28,460 --> 00:35:32,920
+إذا انا عملت chiral center لأن لما بضيف في وجود ال
+
+352
+00:35:32,920 --> 00:35:37,780
+peroxide Anti Markovnikov's addition يعني بدي ألغى
+
+353
+00:35:37,780 --> 00:35:45,050
+هذا ال double bond و أحط هنا H و هنا PRبر فيها انا
+
+354
+00:35:45,050 --> 00:35:50,050
+كايرال سنتر فيها انا كايرال سنتر اذا الكم ايزو مار
+
+355
+00:35:50,050 --> 00:35:57,430
+طلع عني واحد مش اتنين لو كنا بنضيف hbr في وجود h
+
+356
+00:35:57,430 --> 00:35:58,550
+plus بطلع اتنين
+
+357
+00:36:08,270 --> 00:36:11,910
+هذا السؤال MAI reacts with ethyl chloride
+
+358
+00:36:11,910 --> 00:36:16,410
+producing ethyl iodide لاحظوا هنا إبدال أن اليود
+
+359
+00:36:16,410 --> 00:36:23,670
+بيحل محل كلور هذه المعلومة أخدناها ولا لأ اليود
+
+360
+00:36:23,670 --> 00:36:32,630
+بيحل محل كلور و العكس مش صحيح Cyclohexanol بتكون
+
+361
+00:36:32,630 --> 00:36:37,730
+تتذكروا بمخكوا ع طول ال Cyclohexanolركزنا عليه في
+
+362
+00:36:37,730 --> 00:36:43,130
+الرسم ولا لأ؟ اللي متصل ب OH لو عملتله أكسدة شو
+
+363
+00:36:43,130 --> 00:36:52,690
+هيعمل؟ هيحذف ال H و ال H هاي الأكسدة تبعته، هاي
+
+364
+00:36:52,690 --> 00:36:57,360
+أكسدته، إيش أعطاني؟عطاني كيتون أساسا
+
+365
+00:36:57,360 --> 00:37:00,680
+الـcyclohexanol is secondary alcohol secondary
+
+366
+00:37:00,680 --> 00:37:05,420
+alcohols are oxidized to ketones وهي بالرسمة بيعطي
+
+367
+00:37:05,420 --> 00:37:13,660
+كيتون أنا كاتبلكم غلط مش الديهيد كيتون dehydration
+
+368
+00:37:13,660 --> 00:37:18,180
+of secondary butyl alcohol مرة تانية رجعنا تكونوا
+
+369
+00:37:18,180 --> 00:37:23,060
+حافظين أسماء إيش المجموعات ال secondary butyl اللي
+
+370
+00:37:23,060 --> 00:37:30,120
+حاملة هناعلى هذا الموقع وهذا لما يحمل OH سكندر
+
+371
+00:37:30,120 --> 00:37:35,020
+بيوت الالكهول طبعا ال dehydration يا ال OH من هنا
+
+372
+00:37:35,020 --> 00:37:42,620
+او من هنا اخدنا انه حسب قاعدة زي سف الحذف و more
+
+373
+00:37:42,620 --> 00:37:47,320
+substituted product will form اذا ال one butane
+
+374
+00:37:47,320 --> 00:37:51,260
+ولا ال two butane انا كاتبينلكم بشكل أساسي one
+
+375
+00:37:51,260 --> 00:37:52,820
+butane اذا خطأ
+
+376
+00:38:10,810 --> 00:38:15,070
+dichlorination of cyclobutane gives a total of
+
+377
+00:38:15,070 --> 00:38:19,310
+لحظوا ال cyclobutane بهذا الشكل بدي أضع عليه
+
+378
+00:38:19,310 --> 00:38:25,830
+مجموعتين كلور كيف ممكن أضعهم على واحد و واحد أو
+
+379
+00:38:25,830 --> 00:38:29,150
+على واحد و اتنين على واحد و اتنين بيجي ال ces و ال
+
+380
+00:38:29,150 --> 00:38:29,810
+trans
+
+381
+00:38:39,260 --> 00:38:45,180
+cyclobutane ..cyclobutane ..انا متأسف okay ..الان
+
+382
+00:38:45,180 --> 00:38:48,500
+ال ..cyclobutane ..حطوا مجموعتين كلور على واحد
+
+383
+00:38:48,500 --> 00:38:53,980
+واحد ..هذا مركب ..بعدين ع واحد و اتنين .. six و
+
+384
+00:38:53,980 --> 00:38:57,860
+trance .. بعدين ع واحد و تلاتة .. six و trance ..
+
+385
+00:38:57,860 --> 00:39:02,300
+اذا قداش المجموعة؟ خمسة ..هي نفس فكرة ال
+
+386
+00:39:02,300 --> 00:39:07,200
+..cyclobrote .. بس على أوصةThe common name of two
+
+387
+00:39:07,200 --> 00:39:19,360
+propene one all يعني هاي CH2OH CH double bond CH2
+
+388
+00:39:19,360 --> 00:39:26,160
+لحظوا هذا two propene واحد اتنين تلاتة one all هنا
+
+389
+00:39:26,160 --> 00:39:30,340
+فسرناه الآن الناس اللي متذكرة شكل المجموعة شو هي
+
+390
+00:39:30,340 --> 00:39:32,400
+الالكول
+
+391
+00:39:34,300 --> 00:39:40,940
+قلل ألكول قلل ألكول إذا كان شوكارو مستعمل لإيصال
+
+392
+00:39:40,940 --> 00:39:45,440
+حركة محركة واحدة إلكترون واحدة إلكترون فالمثال لـ
+
+393
+00:39:45,440 --> 00:39:51,880
+Cyclic Alkenes هو CNH2N-2 لاحظوا الـ Cyclic بدأ
+
+394
+00:39:51,880 --> 00:39:55,660
+أقسم جبالها اتنين من الفورمولة الأصلية والـ E بدأ
+
+395
+00:39:55,660 --> 00:40:00,400
+أقسم اتنين إذا صارت زي formula of الكائنات يعني
+
+396
+00:40:00,400 --> 00:40:08,300
+CNHتو ان ماينوس تو وبتاعة اللي عملناها مركبة زيها
+
+397
+00:40:08,300 --> 00:40:14,260
+اوزونوليسيس او سيس اوري ترانس تو بيوتين خليني
+
+398
+00:40:14,260 --> 00:40:19,860
+اخد ال سيس تو بيوتين ارسمه هان هاي ال سيس تو
+
+399
+00:40:19,860 --> 00:40:23,880
+بيوتين بدي اكسره من هان C double bond O وهذه H
+
+400
+00:40:23,880 --> 00:40:30,660
+بالتأكيدهذا C double bond OH CH3 Acetaldehyde هذا
+
+401
+00:40:30,660 --> 00:40:38,400
+C double bond OH CH3 Acetaldehyde و لل Trans هاي
+
+402
+00:40:38,400 --> 00:40:47,640
+CH3H و هنا CH3H الان اكسروا هذا من هنا و اكسروا
+
+403
+00:40:47,640 --> 00:40:53,400
+هذا من هنا و حطوا ايش Oxygen Oxygen Oxygen Oxygen
+
+404
+00:40:53,980 --> 00:40:59,480
+كل النواتج ايش؟ أسيتلديهيد بيعطي نفس الناتج
+
+405
+00:40:59,480 --> 00:41:07,000
+produces only أسيتلديهيد أو إيثانال أسيتلديهيد
+
+406
+00:41:07,000 --> 00:41:14,960
+CH3SH is more acidic than CH3OH due to size
+
+407
+00:41:17,520 --> 00:41:22,560
+سلفر مع اكسجين ايش العامل المحدد في ال acidity ال
+
+408
+00:41:22,560 --> 00:41:27,820
+size ال due to size
+
+409
+00:41:27,820 --> 00:41:34,740
+الان
+
+410
+00:41:34,740 --> 00:41:40,660
+ارسموا المراكبات التالية بدي بيوتينيعني carbon
+
+411
+00:41:40,660 --> 00:41:46,820
+تنتين تلاتة أربعة على لمرة اتنين ايش موجود عندكم؟
+
+412
+00:41:46,820 --> 00:41:56,900
+فينوكسي يعني O phenyl OH OHANA CH3 CH2 CH3 الآن
+
+413
+00:41:56,900 --> 00:42:01,120
+انا برسم المركب بعدين بشوفه اذا طلع R كان بيها
+
+414
+00:42:01,120 --> 00:42:06,970
+ماطلعش Rبعكس اي مجموع تاني الا لو جيت تطلعت عليه
+
+415
+00:42:06,970 --> 00:42:11,890
+كيف مبين هذي واحد هذي اتنين هذي تلاتة مبين اس و
+
+416
+00:42:11,890 --> 00:42:18,590
+هذي على الجانب اذا هذا فعلا الار ايزو مار عندي
+
+417
+00:42:18,590 --> 00:42:24,770
+سايكلو بنتين هاي السايكلو بنتين خليني ارسمه بهذا
+
+418
+00:42:24,770 --> 00:42:30,530
+الشكلcyclopentane واحد اتنين تلاتة اربعة خمسة على
+
+419
+00:42:30,530 --> 00:42:38,950
+نمرة تلاتة واربعة شو بدي احط كلور وكلور بالزويك
+
+420
+00:42:38,950 --> 00:42:47,010
+أسد C double bond O OH وهنا ال formal C double
+
+421
+00:42:47,010 --> 00:42:57,620
+bond OH هذا ميتاميتا أو بارا هذا موضوع بسيط هذا
+
+422
+00:42:57,620 --> 00:43:01,020
+المركب
+
+423
+00:43:01,020 --> 00:43:10,120
+Cyclopentane شو هذه المجموعة؟ Isobutyl Isobutyl
+
+424
+00:43:10,120 --> 00:43:15,680
+Cyclopentane هذا
+
+425
+00:43:15,680 --> 00:43:22,160
+كحول ألكين من وين الترقيم؟ من عند الكحول يعني هذا
+
+426
+00:43:25,670 --> 00:43:36,290
+بيوتين بيوت two in one all و إيش بيحمل بعد هى two
+
+427
+00:43:36,290 --> 00:43:43,710
+bromo فيه زده E لحظوا هنا ال brom و هنا الميثل ال
+
+428
+00:43:43,710 --> 00:43:47,270
+brom أعلى من الكربون و الميثل أعلى من ال H إذا هذا
+
+429
+00:43:47,270 --> 00:43:51,750
+E هذا أسيتوفينون
+
+430
+00:44:14,250 --> 00:44:18,730
+مش كتير معنا وقت ان شاء الله بخمس دقائق نمشي أسرع
+
+431
+00:44:18,730 --> 00:44:21,270
+بدنا خمس دقائق نمشي أسرع شوية
+
+432
+00:44:24,120 --> 00:44:30,000
+هحاول امشي بشكل سريع الان هنا في ال HBr Peroxide
+
+433
+00:44:30,000 --> 00:44:35,140
+الفكرة الأساسية اللى بتكون تعمله شو هي انت
+
+434
+00:44:35,140 --> 00:44:43,000
+Markovnikov واضح فلو انتوا جيتوا واشتغلتوا H CH3
+
+435
+00:44:43,000 --> 00:44:51,740
+CH2 هنا H هنا H وين هتحطوا ال Br وهنا
+
+436
+00:44:51,740 --> 00:44:56,880
+ال Hهي الـ Antimark of Nikon واضح؟ الان هذا لو
+
+437
+00:44:56,880 --> 00:45:00,320
+فعلته مع ال Oethel minus Can you clear your file؟
+
+438
+00:45:00,320 --> 00:45:08,700
+شو بتعمل؟ بتحيل محل لبروم يعني بتحط كل الجزيء و
+
+439
+00:45:08,700 --> 00:45:18,540
+تكتبوا هنا Oethel و لو فعلته مع ال SH minus بدنا
+
+440
+00:45:18,540 --> 00:45:26,810
+نحط كل الجزيء مرة تانيةوبنحط هنا sh ابدال يعني هذا
+
+441
+00:45:26,810 --> 00:45:30,870
+البروم بتبدل هذا عنوان chapter 6 انه البروم بتبدل
+
+442
+00:45:30,870 --> 00:45:36,310
+بال او اثل او بال sh هنا بالكئمن او فور مع ال o h
+
+443
+00:45:36,310 --> 00:45:44,090
+minus شو بدها تحط مجمعتين o h على جهة واحدة بال
+
+444
+00:45:44,090 --> 00:45:50,730
+ozonolysis بدوا يعمل تلتين c double point o بتكمل
+
+445
+00:45:50,730 --> 00:45:58,340
+الجزيةبالميه هذه بتضيف حسب قاعدة Markovnikov
+
+446
+00:45:58,340 --> 00:46:03,220
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+447
+00:46:03,220 --> 00:46:07,800
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+448
+00:46:07,800 --> 00:46:07,980
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+449
+00:46:07,980 --> 00:46:09,020
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+450
+00:46:09,020 --> 00:46:09,960
+اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش اتش
+
+451
+00:46:09,960 --> 00:46:20,320
+اتش اتش اتش اتش اتش اتش اتش اتش
+
+452
+00:46:20,320 --> 00:46:22,320
+ات
+
+453
+00:46:33,790 --> 00:46:41,490
+أخر شغلة الأفكار الأساسية هنا إضافة ميه وبعدين
+
+454
+00:46:41,490 --> 00:46:47,110
+توتوميرزم متذاكرينها ال
+
+455
+00:46:47,110 --> 00:46:54,030
+ISOبنتين هي ال ISOبنتين اعملولها إكلوريناشن توي
+
+456
+00:46:54,030 --> 00:47:01,240
+حكينا كام موقع فيها؟واحد اتنين تلاتة اربعة لما
+
+457
+00:47:01,240 --> 00:47:05,440
+احطولكوا all possible monochlorination products
+
+458
+00:47:05,440 --> 00:47:10,700
+انتبهوا معي لما احط كلور هان و هان هذا ناتج و اذا
+
+459
+00:47:10,700 --> 00:47:13,740
+حطيت هان هذا ناتج هذا فيش فيه chiral center هذا
+
+460
+00:47:13,740 --> 00:47:17,500
+فيش فيه chiral center لو حطيت هان CH2Cl فيش فيه
+
+461
+00:47:17,500 --> 00:47:23,210
+chiral center لو حطيت هانأتش و CL في كايرالسنتر
+
+462
+00:47:23,210 --> 00:47:27,430
+هدا بده يطلع منه كام واحد اتنين اذا المجموع كده؟
+
+463
+00:47:27,430 --> 00:47:32,890
+خمسة product لما ادخل ال stereo isomers هذه النقطة
+
+464
+00:47:32,890 --> 00:47:38,510
+تحديدا بحط فيها ال H و ال CL يعني الناتجين اللي
+
+465
+00:47:38,510 --> 00:47:44,450
+بدهم يكونوا هنا لو رسمت الناتج و صورته في المرايا
+
+466
+00:47:44,450 --> 00:47:52,680
+بدكوا تكونوا حاطين هنا مثلاH و CH3 و CL وهنا تحطوا
+
+467
+00:47:52,680 --> 00:48:02,100
+CL و H و CH3 الناتج و صورته في المرأة واضح
+
+468
+00:48:02,100 --> 00:48:06,300
+الناتج و صورته في المرأة هذوله اتنين و بعدين
+
+469
+00:48:06,300 --> 00:48:09,920
+بتحطوا هن واحد و هن واحد و هن واحد المجموع كده؟
+
+470
+00:48:09,920 --> 00:48:17,300
+خمسة خمسة بقى لعنا اتنين صغار كتير
+
+471
+00:48:25,790 --> 00:48:29,490
+isopropylacetophenon الفكرة فقط انكوا تعرفوا مين
+
+472
+00:48:29,490 --> 00:48:34,550
+بده احطها في الأول انهي المجموعة اللي بتلحط نمرا
+
+473
+00:48:34,550 --> 00:48:42,090
+واحد ال isopropyl ال isopropyl orthopara ال
+
+474
+00:48:42,090 --> 00:48:46,290
+isopropyl orthopara directing و بعدين ال
+
+475
+00:48:46,290 --> 00:48:47,270
+acetophenon
+
+476
+00:48:49,330 --> 00:48:54,330
+Cl ألمنيوم كلورايد و هنا ايزو بروبل كلورايد
+
+477
+00:48:54,330 --> 00:49:02,530
+ألمنيوم كلورايد أخر سؤال سيث ثريهكسيني من ون
+
+478
+00:49:02,530 --> 00:49:07,430
+بيوتايل لاحظوا هذا ال ون بيوتايل بهذا الشكل CH3
+
+479
+00:49:07,430 --> 00:49:15,670
+CH2 C triple bond CH من أربعة بده أحضر ستة
+
+480
+00:49:15,670 --> 00:49:17,890
+ملاحظين؟
+
+481
+00:49:18,690 --> 00:49:24,670
+من الأربعة شو بده احضر؟ ستة كيف بده اعمل هذا
+
+482
+00:49:24,670 --> 00:49:31,470
+الكلام؟ اول اشي بده ازيد ذاتين carbon فانا لو فعلت
+
+483
+00:49:31,470 --> 00:49:38,380
+مع ال NANH2 نمرة واحد خلت هذه minusو بعدين نمرة
+
+484
+00:49:38,380 --> 00:49:44,540
+اتنين فعلتها مع إثيل بروميد CH3 CH2Br ال minus
+
+485
+00:49:44,540 --> 00:49:48,760
+اللي بيحجم على ال PR و أجتها بيصير عندي هذا ال
+
+486
+00:49:48,760 --> 00:49:56,140
+كائن CH3 CH2 C triple bond C وهي ال إثيل اللي أنا
+
+487
+00:49:56,140 --> 00:50:04,950
+حطيتها CH2 CH3 الان من هذه بدي أخليهاالكين
+
+488
+00:50:04,950 --> 00:50:09,090
+والالكين يكون إيش؟ SES كيف بحول ال triple bond
+
+489
+00:50:09,090 --> 00:50:18,610
+لالكين SES؟ H2 Lendlers Catalyst Lendlers Catalyst
+
+490
+00:50:18,610 --> 00:50:24,350
+إذا هذا السؤال فيه فكرتين أساسيات الفكرة الأولى أن
+
+491
+00:50:24,350 --> 00:50:28,010
+ال terminal alkyl بيصير نيوكليوفايل ممكن يعمل
+
+492
+00:50:28,010 --> 00:50:34,070
+إبدال علىالكالهلايد كبرت السلسلة و بعدين ل triple
+
+493
+00:50:34,070 --> 00:50:38,010
+bond ان اخليها cis او trans اخدته قولت انا ل
+
+494
+00:50:38,010 --> 00:50:43,470
+triple bond يا بخليها الكن يا cis الكن يا trans
+
+495
+00:50:43,470 --> 00:50:48,590
+الكن كل واحدة في إلها شروط معينة ابقى اك تقريبا
+
+496
+00:50:48,590 --> 00:50:53,810
+بنكون غطينا يعني باسئلة مختلفة معظم الأشياء اللي
+
+497
+00:50:53,810 --> 00:50:57,490
+درسناها و بنتمنالكوا ان شاء الله النجاح و التوفيق
+
+498
+00:50:57,490 --> 00:50:59,050
+في الامتحان اللي بدكنوا تقدموه
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/635vH7PE99A_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/635vH7PE99A_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..67527dfe5d9af8d0812dc642f87d8cc31dcf062e
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/635vH7PE99A_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3340, "start": 20.33, "end": 33.41, "text": "بسم الله الرحمن الرحيم اليوم ان شاء الله درسنا مش في موضوع معين لأ هو مراجعة شاملة من خلال حل الامتحانات السابقة استعدادا للامتحان", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 16472, 13412, 16606, 21984, 11778, 2288, 3794, 8315, 37893, 8978, 3714, 2407, 11242, 45367, 20449, 9957, 5296, 10721, 31439, 3714, 2288, 26108, 27884, 13412, 10943, 37977, 9154, 16490, 1211, 6027, 11331, 1211, 2423, 10943, 2655, 5016, 7649, 9307, 21136, 16758, 28671, 44713, 22488, 18513, 995, 24976, 10943, 2655, 5016, 7649], "avg_logprob": -0.08108618723288659, "compression_ratio": 1.7050359712230216, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 20.33, "end": 20.65, "word": "بسم", "probability": 0.871337890625}, {"start": 20.65, "end": 20.85, "word": " الله", "probability": 0.96923828125}, {"start": 20.85, "end": 21.31, "word": " الرحمن", "probability": 0.9736328125}, {"start": 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الأساسية العامة يكونوا فاهمينها بنسبة أكبر هذا بمنعش أنه في أشياء متخصصة لكن دائما الطالب أول شيء يجب أن يكون عنده يعني قناع أن هو فاهم الاشي الأفكار العامة ولذلك ربما تلاحظوا أنه يعني لو أنا بدأ أصنف الأسئلة مش في هذا الامتحان في معظم الامتحانات هنكتشف أنه هي عنوين", "tokens": [3555, 6027, 10721, 5172, 4117, 9640, 16247, 3794, 32277, 10632, 18863, 10943, 3660, 7251, 30544, 14407, 6156, 995, 16095, 9957, 11296, 44945, 35457, 3660, 5551, 4117, 26890, 23758, 4724, 27842, 3615, 8592, 14739, 3224, 8978, 5551, 8592, 1829, 16606, 44650, 9778, 9381, 9381, 3660, 44381, 11778, 16373, 15042, 41950, 6027, 3555, 5551, 12610, 44049, 38207, 7251, 7435, 3555, 14739, 7251, 30544, 43242, 3224, 37495, 22653, 12174, 8315, 3615, 14739, 31439, 6156, 995, 16095, 2423, 33599, 1829, 16247, 5172, 4117, 9640, 18863, 10943, 3660, 35525, 8848, 23275, 12602, 3555, 15042, 6055, 15040, 5016, 19913, 14407, 14739, 3224, 37495, 22653, 45164, 41850, 47525, 10721, 5551, 9381, 1863, 5172, 16247, 3794, 19986, 37977, 37893, 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{"start": 74.77, "end": 75.35, "word": " أنه", "probability": 0.863037109375}, {"start": 75.35, "end": 75.85, "word": " يعني", "probability": 0.980712890625}, {"start": 75.85, "end": 76.55, "word": " لو", "probability": 0.97265625}, {"start": 76.55, "end": 76.73, "word": " أنا", "probability": 0.720703125}, {"start": 76.73, "end": 76.97, "word": " بدأ", "probability": 0.7269287109375}, {"start": 76.97, "end": 77.65, "word": " أصنف", "probability": 0.954345703125}, {"start": 77.65, "end": 78.49, "word": " الأسئلة", "probability": 0.995849609375}, {"start": 78.49, "end": 78.71, "word": " مش", "probability": 0.9150390625}, {"start": 78.71, "end": 78.89, "word": " في", "probability": 0.94287109375}, {"start": 78.89, "end": 79.11, "word": " هذا", "probability": 0.95947265625}, {"start": 79.11, "end": 79.75, "word": " الامتحان", "probability": 0.962109375}, {"start": 79.75, "end": 80.17, "word": " في", "probability": 0.82373046875}, {"start": 80.17, "end": 80.63, "word": " معظم", "probability": 0.9871419270833334}, {"start": 80.63, "end": 81.65, "word": " الامتحانات", "probability": 0.9720865885416666}, {"start": 81.65, "end": 82.85, "word": " هنكتشف", "probability": 0.947265625}, {"start": 82.85, "end": 83.39, "word": " أنه", "probability": 0.833740234375}, {"start": 83.39, "end": 83.75, "word": " هي", "probability": 0.89453125}, {"start": 83.75, "end": 84.45, "word": " عنوين", "probability": 0.9423828125}], "temperature": 1.0}, {"id": 4, "seek": 11295, "start": 85.47, "end": 112.95, "text": "يعني هي عنوين لأشياء احنا درسناها خلينا نشوف هذا الكلام من خلال التطبيق الآن في هذا الامتحان اللي أمامنا في عندنا مجموعة من الجمال هذه المجموعة من الجمال بدنا نكمل الفراغ فيها complete the following السؤال أول مثلا بيسألنا الدياستيريو مارزهاف و بيحكي عن ال physical properties", "tokens": [40228, 22653, 39896, 18871, 2407, 9957, 5296, 10721, 8592, 1829, 16606, 1975, 5016, 8315, 11778, 2288, 3794, 8315, 11296, 16490, 1211, 9957, 995, 8717, 8592, 38688, 23758, 2423, 28820, 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"probability": 0.931640625}, {"start": 87.19, "end": 87.55, "word": " احنا", "probability": 0.8640950520833334}, {"start": 87.55, "end": 88.31, "word": " درسناها", "probability": 0.96259765625}, {"start": 88.31, "end": 89.49, "word": " خلينا", "probability": 0.8192138671875}, {"start": 89.49, "end": 90.03, "word": " نشوف", "probability": 0.99169921875}, {"start": 90.03, "end": 90.25, "word": " هذا", "probability": 0.97265625}, {"start": 90.25, "end": 90.73, "word": " الكلام", "probability": 0.9615885416666666}, {"start": 90.73, "end": 90.87, "word": " من", "probability": 0.9970703125}, {"start": 90.87, "end": 91.39, "word": " خلال", "probability": 0.9947916666666666}, {"start": 91.39, "end": 92.35, "word": " التطبيق", "probability": 0.980224609375}, {"start": 92.35, "end": 93.45, "word": " الآن", "probability": 0.6680908203125}, {"start": 93.45, "end": 94.47, "word": " في", "probability": 0.921875}, {"start": 94.47, "end": 94.79, "word": " هذا", "probability": 0.95556640625}, {"start": 94.79, "end": 95.51, "word": " الامتحان", "probability": 0.97373046875}, {"start": 95.51, "end": 95.71, "word": " اللي", "probability": 0.93798828125}, {"start": 95.71, "end": 96.43, "word": " أمامنا", "probability": 0.9483642578125}, {"start": 96.43, "end": 97.25, "word": " في", "probability": 0.57861328125}, {"start": 97.25, "end": 97.67, "word": " عندنا", "probability": 0.959716796875}, {"start": 97.67, "end": 98.33, "word": " مجموعة", "probability": 0.9568359375}, {"start": 98.33, "end": 98.69, "word": " من", "probability": 0.9892578125}, {"start": 98.69, "end": 99.83, "word": " الجمال", "probability": 0.7607421875}, {"start": 99.83, "end": 100.61, "word": " هذه", "probability": 0.65234375}, {"start": 100.61, "end": 101.19, "word": " المجموعة", "probability": 0.89345703125}, {"start": 101.19, "end": 101.35, "word": " من", "probability": 0.984375}, {"start": 101.35, "end": 101.87, "word": " الجمال", "probability": 0.9088541666666666}, {"start": 101.87, "end": 102.33, "word": " بدنا", "probability": 0.9365234375}, {"start": 102.33, "end": 103.05, "word": " نكمل", "probability": 0.9957682291666666}, {"start": 103.05, "end": 103.71, "word": " الفراغ", "probability": 0.985107421875}, {"start": 103.71, "end": 104.27, "word": " فيها", "probability": 0.9931640625}, {"start": 104.27, "end": 105.67, "word": " complete", "probability": 0.546875}, {"start": 105.67, "end": 106.45, "word": " the", "probability": 0.9130859375}, {"start": 106.45, "end": 107.15, "word": " following", "probability": 0.900390625}, {"start": 107.15, "end": 108.65, "word": " السؤال", "probability": 0.9835611979166666}, {"start": 108.65, "end": 108.91, "word": " أول", "probability": 0.806396484375}, {"start": 108.91, "end": 109.21, "word": " مثلا", "probability": 0.9794921875}, {"start": 109.21, "end": 109.67, "word": " بيسألنا", "probability": 0.956298828125}, {"start": 109.67, "end": 110.45, "word": " الدياستيريو", "probability": 0.7172502790178571}, {"start": 110.45, "end": 111.23, "word": " مارزهاف", "probability": 0.6673828125}, {"start": 111.23, "end": 111.41, "word": " و", "probability": 0.56201171875}, {"start": 111.41, "end": 111.73, "word": " بيحكي", "probability": 0.857958984375}, {"start": 111.73, "end": 111.87, "word": " عن", "probability": 0.98828125}, {"start": 111.87, "end": 111.97, "word": " ال", "probability": 0.935546875}, {"start": 111.97, "end": 112.29, "word": " physical", "probability": 0.8466796875}, {"start": 112.29, "end": 112.95, "word": " properties", "probability": 0.143798828125}], "temperature": 1.0}, {"id": 5, "seek": 14309, "start": 114.07, "end": 143.09, "text": "الان كان واضح تماما ان ال بيستيريو مارز هيف different physical properties واضح الان السؤال التاني addition of HBr H plus to isobutene produces لاحظوا هنا السؤال هذا في فكرتين ان الطالب لازم في الأول يعرف ايش هو ال isobutene", "tokens": [6027, 7649, 25961, 4032, 46958, 5016, 46811, 10943, 995, 16472, 2423, 4724, 1829, 14851, 13546, 1829, 2407, 3714, 9640, 11622, 8032, 33911, 819, 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"word": " بيستيريو", "probability": 0.6562906901041666}, {"start": 117.05, "end": 117.33, "word": " مارز", "probability": 0.806640625}, {"start": 117.33, "end": 117.91, "word": " هيف", "probability": 0.16851806640625}, {"start": 117.91, "end": 118.97, "word": " different", "probability": 0.318359375}, {"start": 118.97, "end": 122.39, "word": " physical", "probability": 0.38134765625}, {"start": 122.39, "end": 123.07, "word": " properties", "probability": 0.81689453125}, {"start": 123.07, "end": 124.43, "word": " واضح", "probability": 0.7909342447916666}, {"start": 124.43, "end": 127.39, "word": " الان", "probability": 0.6256103515625}, {"start": 127.39, "end": 128.23, "word": " السؤال", "probability": 0.9890950520833334}, {"start": 128.23, "end": 128.77, "word": " التاني", "probability": 0.9269205729166666}, {"start": 128.77, "end": 129.21, "word": " addition", "probability": 0.60009765625}, {"start": 129.21, "end": 129.55, "word": " of", "probability": 0.9794921875}, {"start": 129.55, "end": 130.67, "word": " HBr", "probability": 0.5208740234375}, {"start": 130.67, "end": 131.27, "word": " H", "probability": 0.398193359375}, {"start": 131.27, "end": 131.83, "word": " plus", "probability": 0.1407470703125}, {"start": 131.83, "end": 132.11, "word": " to", "probability": 0.8505859375}, {"start": 132.11, "end": 133.33, "word": " isobutene", "probability": 0.75128173828125}, {"start": 133.33, "end": 134.39, "word": " produces", "probability": 0.92919921875}, {"start": 134.39, "end": 135.69, "word": " لاحظوا", "probability": 0.95068359375}, {"start": 135.69, "end": 136.03, "word": " هنا", "probability": 0.97265625}, {"start": 136.03, "end": 137.11, "word": " السؤال", "probability": 0.9851888020833334}, {"start": 137.11, "end": 137.41, "word": " هذا", "probability": 0.90185546875}, {"start": 137.41, "end": 137.85, "word": " في", "probability": 0.90673828125}, {"start": 137.85, "end": 138.59, "word": " فكرتين", "probability": 0.8720703125}, {"start": 138.59, "end": 138.83, 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"probability": 0.959716796875}, {"start": 477.11, "end": 478.21, "word": " أخدناها", "probability": 0.97294921875}, {"start": 478.21, "end": 479.93, "word": " واضحة", "probability": 0.9425048828125}], "temperature": 1.0}, {"id": 20, "seek": 51594, "start": 492.68, "end": 515.94, "text": "الان بعد هيك ارسمولنا أشكال بعض المركبات Cyclobentane مين ما بيعرفوا ال Cyclobentane؟ هاي ال Cyclobentane أسس على نمرة واحد و تلت يعني لو قولنا هنا مثلا خلينا نحط إبروم للأمام وهنا", "tokens": [6027, 7649, 39182, 39896, 4117, 1975, 2288, 38251, 12610, 8315, 5551, 8592, 4117, 6027, 45030, 11242, 9673, 31747, 3555, 9307, 10295, 66, 752, 65, 317, 1929, 3714, 9957, 19446, 4724, 40228, 28480, 14407, 2423, 10295, 66, 752, 65, 317, 1929, 22807, 8032, 47302, 2423, 10295, 66, 752, 65, 317, 1929, 5551, 3794, 3794, 15844, 8717, 2304, 25720, 36764, 24401, 4032, 6055, 1211, 2655, 37495, 22653, 45164, 12174, 12610, 8315, 34105, 50113, 15040, 16490, 20292, 8315, 8717, 5016, 9566, 11933, 26890, 20498, 24976, 10721, 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"probability": 0.78515625}, {"start": 510.0, "end": 510.18, "word": " لو", "probability": 0.89501953125}, {"start": 510.18, "end": 510.5, "word": " قولنا", "probability": 0.8631184895833334}, {"start": 510.5, "end": 510.76, "word": " هنا", "probability": 0.90380859375}, {"start": 510.76, "end": 511.34, "word": " مثلا", "probability": 0.979736328125}, {"start": 511.34, "end": 512.18, "word": " خلينا", "probability": 0.8260091145833334}, {"start": 512.18, "end": 513.5, "word": " نحط", "probability": 0.9899088541666666}, {"start": 513.5, "end": 514.3, "word": " إبروم", "probability": 0.7054036458333334}, {"start": 514.3, "end": 515.48, "word": " للأمام", "probability": 0.9073486328125}, {"start": 515.48, "end": 515.94, "word": " وهنا", "probability": 0.7322998046875}], "temperature": 1.0}, {"id": 21, "seek": 54016, "start": 516.85, "end": 540.17, "text": "بروم هاي واحد اتنين تلاتة وستعملنا الشكل الفراغي عشان نبين انه مجموعتين للامام الان Cyclohexane نعرف ال Cyclohexane هاي Cyclohexane 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"word": " تلاتة", "probability": 0.8875732421875}, {"start": 519.21, "end": 523.99, "word": " وستعملنا", "probability": 0.6845458984375}, {"start": 523.99, "end": 524.49, "word": " الشكل", "probability": 0.7744140625}, {"start": 524.49, "end": 525.01, "word": " الفراغي", "probability": 0.898828125}, {"start": 525.01, "end": 525.31, "word": " عشان", "probability": 0.8282063802083334}, {"start": 525.31, "end": 525.69, "word": " نبين", "probability": 0.8165690104166666}, {"start": 525.69, "end": 525.95, "word": " انه", "probability": 0.705810546875}, {"start": 525.95, "end": 526.77, "word": " مجموعتين", "probability": 0.86083984375}, {"start": 526.77, "end": 528.23, "word": " للامام", "probability": 0.8780924479166666}, {"start": 528.23, "end": 531.07, "word": " الان", "probability": 0.60955810546875}, {"start": 531.07, "end": 533.01, "word": " Cyclohexane", "probability": 0.7933349609375}, {"start": 533.01, "end": 533.95, "word": " نعرف", "probability": 0.9208984375}, {"start": 533.95, 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"end": 1527.28, "word": " CH3", "probability": 0.935791015625}, {"start": 1527.28, "end": 1529.06, "word": " CH2Br", "probability": 0.640869140625}, {"start": 1529.06, "end": 1530.02, "word": " بده", "probability": 0.798095703125}, {"start": 1530.02, "end": 1530.34, "word": " يعمل", "probability": 0.9513346354166666}, {"start": 1530.34, "end": 1530.92, "word": " عليها", "probability": 0.98681640625}, {"start": 1530.92, "end": 1531.44, "word": " ال", "probability": 0.751953125}, {"start": 1531.44, "end": 1532.24, "word": " eucleophilic", "probability": 0.7880045572916666}, {"start": 1532.24, "end": 1532.9, "word": " substitution", "probability": 0.8779296875}, {"start": 1532.9, "end": 1533.2, "word": " هذه", "probability": 0.333251953125}, {"start": 1533.2, "end": 1533.76, "word": " الكربون", "probability": 0.8175455729166666}, {"start": 1533.76, "end": 1534.66, "word": " اتهاجمها", "probability": 0.82158203125}], "temperature": 1.0}, {"id": 61, "seek": 156459, "start": 1536.35, "end": 1564.59, "text": "تطرد ال PR ما هو ذا نيوكليو 5 إذا النتيجة فينيل C triple bond C وهنا هياتحدت مع CH2 CH3 طردت ال PR إبدالي نيوكليو فينيل الان هذا المركب مع ال lithium و ال ammonia شو بيعمل؟", "tokens": [2655, 9566, 2288, 3215, 2423, 11568, 19446, 31439, 29910, 995, 8717, 1829, 2407, 28820, 1829, 2407, 1025, 11933, 15730, 28239, 31371, 7435, 3660, 8978, 22653, 1211, 383, 15508, 6086, 383, 37037, 8315, 39896, 9307, 24401, 2655, 20449, 5995, 17, 5995, 18, 23032, 2288, 3215, 2655, 2423, 11568, 11933, 44510, 6027, 1829, 8717, 1829, 2407, 28820, 1829, 2407, 8978, 22653, 1211, 2423, 7649, 23758, 9673, 31747, 3555, 20449, 2423, 32180, 4032, 2423, 46833, 13412, 2407, 4724, 1829, 25957, 1211, 22807], "avg_logprob": -0.39824219793081284, "compression_ratio": 1.4728260869565217, "no_speech_prob": 0.0, "words": [{"start": 1536.35, "end": 1536.89, "word": "تطرد", "probability": 0.69158935546875}, {"start": 1536.89, "end": 1537.57, "word": " ال", "probability": 0.43408203125}, {"start": 1537.57, 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"text": "Double bond هو اكيد بيضيف الهيدروجين عكس بعض لكن مافيش فارق بالنتيجة هايو الهيدروجين اللي ضفته كيف اجوا عكس بعض لكن المراكب لا فيه cis ولا trans لأن هدوله زي بعض الان بعد هيك هذا المراكب بتعمله اوزونوليسيز شو ال اوزونوليسيز نكسر ال double bond لتنتين", "tokens": [35, 33147, 6086, 31439, 1975, 4117, 25708, 4724, 1829, 11242, 33911, 2423, 3224, 25708, 2288, 29245, 9957, 6225, 4117, 3794, 45030, 11242, 44381, 19446, 41185, 8592, 6156, 9640, 4587, 20666, 29399, 1829, 7435, 3660, 8032, 995, 1829, 2407, 2423, 3224, 25708, 2288, 29245, 9957, 13672, 1829, 48812, 5172, 47395, 9122, 33911, 1975, 7435, 14407, 6225, 4117, 3794, 45030, 11242, 44381, 9673, 23557, 4117, 3555, 20193, 8978, 3224, 37847, 49429, 1145, 5296, 33456, 8032, 3215, 12610, 3224, 30767, 1829, 45030, 11242, 2423, 7649, 39182, 39896, 4117, 23758, 9673, 23557, 4117, 3555, 39894, 25957, 43761, 1975, 2407, 11622, 11536, 12610, 1829, 3794, 1829, 11622, 13412, 2407, 2423, 1975, 2407, 11622, 11536, 12610, 1829, 3794, 1829, 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stereoisomers", "probability": 0.92431640625}, {"start": 2094.2, "end": 2094.98, "word": " طبعا", "probability": 0.927001953125}, {"start": 2094.98, "end": 2095.12, "word": " اللي", "probability": 0.71728515625}, {"start": 2095.12, "end": 2095.32, "word": " مش", "probability": 0.982421875}, {"start": 2095.32, "end": 2095.68, "word": " عارف", "probability": 0.9861653645833334}, {"start": 2095.68, "end": 2095.84, "word": " ال", "probability": 0.27587890625}, {"start": 2095.84, "end": 2096.66, "word": " styrene", "probability": 0.5850830078125}, {"start": 2096.66, "end": 2098.9, "word": " زنبها", "probability": 0.75238037109375}, {"start": 2098.9, "end": 2099.04, "word": " ع", "probability": 0.69384765625}, {"start": 2099.04, "end": 2099.6, "word": " جنبها", "probability": 0.9779052734375}, {"start": 2099.6, "end": 2101.9, "word": " CH", "probability": 0.82958984375}, {"start": 2101.9, "end": 2102.82, "word": " double", "probability": 0.31787109375}, {"start": 2102.82, "end": 2103.4, "word": " bond", "probability": 0.93505859375}, {"start": 2103.4, "end": 2105.4, "word": " CH2", "probability": 0.86767578125}, {"start": 2105.4, "end": 2106.36, "word": " لاحظوا", "probability": 0.809814453125}, {"start": 2106.36, "end": 2106.58, "word": " هذا", "probability": 0.80859375}, {"start": 2106.58, "end": 2107.22, "word": " سؤال", "probability": 0.8776041666666666}, {"start": 2107.22, "end": 2107.78, "word": " جميل", "probability": 0.9939778645833334}, {"start": 2107.78, "end": 2108.5, "word": " لو", "probability": 0.91845703125}, {"start": 2108.5, "end": 2108.92, "word": " انا", "probability": 0.716796875}, {"start": 2108.92, "end": 2109.48, "word": " كنت", "probability": 0.99072265625}, {"start": 2109.48, "end": 2110.0, "word": " باضيف", "probability": 0.819580078125}, {"start": 2110.0, "end": 2110.8, "word": " HBr", "probability": 0.879150390625}, {"start": 2110.8, "end": 2110.98, "word": " في", "probability": 0.94482421875}, {"start": 2110.98, "end": 2111.24, "word": " وجود", "probability": 0.9580078125}, {"start": 2111.24, "end": 2111.5, "word": " H", "probability": 0.95703125}, {"start": 2111.5, "end": 2111.82, "word": " plus", "probability": 0.125732421875}, {"start": 2111.82, "end": 2112.26, "word": " هضيفه", "probability": 0.8612060546875}, {"start": 2112.26, "end": 2112.58, "word": " حسب", "probability": 0.97412109375}, {"start": 2112.58, "end": 2113.06, "word": " قاعدة", "probability": 0.9708251953125}, {"start": 2113.06, "end": 2113.92, "word": " Markovnikov", "probability": 0.8685302734375}, {"start": 2113.92, "end": 2114.54, "word": " هحط", "probability": 0.9381510416666666}, {"start": 2114.54, "end": 2114.8, "word": " هنا", "probability": 0.9453125}, {"start": 2114.8, "end": 2115.04, "word": " ال", "probability": 0.919921875}, {"start": 2115.04, "end": 2115.34, "word": " H", "probability": 0.625}], "temperature": 1.0}, {"id": 82, "seek": 214330, "start": 2116.14, "end": 2143.3, "text": "وهنا ال PR وجدت في هذه الحالة هعمل chiral center هنا هيطلع عندى ناتجين لو أنا بضيف ال HPR في وجود H Plus هنا ال H هنا ال PR إذا انا عملت chiral center لأن لما بضيف في وجود ال peroxide Anti Markovnikov's addition يعني بدي ألغى هذا ال double bond و أحط هنا H و هنا PR", "tokens": [2407, 3224, 8315, 2423, 11568, 49610, 3215, 2655, 8978, 29538, 21542, 6027, 3660, 8032, 25957, 1211, 23782, 304, 3056, 34105, 8032, 1829, 9566, 1211, 3615, 43242, 7578, 8717, 9307, 7435, 9957, 45164, 41850, 4724, 11242, 33911, 2423, 12557, 49, 8978, 49610, 23328, 389, 7721, 34105, 2423, 389, 34105, 2423, 11568, 11933, 15730, 1975, 8315, 6225, 42213, 2655, 23782, 304, 3056, 5296, 33456, 5296, 15042, 4724, 11242, 33911, 8978, 49610, 23328, 2423, 4768, 34454, 27757, 3934, 5179, 13123, 5179, 311, 4500, 37495, 22653, 4724, 16254, 5551, 1211, 17082, 7578, 23758, 2423, 3834, 6086, 4032, 5551, 5016, 9566, 34105, 389, 4032, 34105, 11568], "avg_logprob": -0.30606618669687535, "compression_ratio": 1.6317991631799162, "no_speech_prob": 0.0, "words": [{"start": 2116.14, "end": 2116.66, "word": "وهنا", "probability": 0.5440266927083334}, {"start": 2116.66, "end": 2116.84, "word": " ال", "probability": 0.87890625}, {"start": 2116.84, "end": 2117.34, "word": " PR", "probability": 0.441650390625}, {"start": 2117.34, "end": 2118.52, "word": " وجدت", "probability": 0.6077473958333334}, {"start": 2118.52, "end": 2118.6, "word": " في", "probability": 0.7060546875}, {"start": 2118.6, "end": 2118.78, "word": " هذه", "probability": 0.93505859375}, {"start": 2118.78, "end": 2119.14, "word": " الحالة", "probability": 0.9698893229166666}, {"start": 2119.14, "end": 2119.56, "word": " هعمل", "probability": 0.8566080729166666}, {"start": 2119.56, "end": 2120.06, "word": " chiral", "probability": 0.6256103515625}, {"start": 2120.06, "end": 2120.54, "word": " center", "probability": 0.69775390625}, {"start": 2120.54, "end": 2120.74, "word": " هنا", "probability": 0.5078125}, {"start": 2120.74, "end": 2121.14, "word": " هيطلع", "probability": 0.70625}, {"start": 2121.14, "end": 2121.46, "word": " عندى", "probability": 0.595458984375}, {"start": 2121.46, "end": 2122.14, "word": " ناتجين", "probability": 0.95947265625}, {"start": 2122.14, "end": 2124.08, "word": " لو", "probability": 0.8095703125}, {"start": 2124.08, "end": 2124.3, "word": " أنا", "probability": 0.5625}, {"start": 2124.3, "end": 2124.66, "word": " بضيف", "probability": 0.8865559895833334}, {"start": 2124.66, "end": 2124.82, "word": " ال", "probability": 0.90771484375}, {"start": 2124.82, "end": 2125.38, "word": " HPR", "probability": 0.623779296875}, {"start": 2125.38, "end": 2125.52, "word": " في", "probability": 0.8232421875}, {"start": 2125.52, "end": 2125.78, "word": " وجود", "probability": 0.981201171875}, {"start": 2125.78, "end": 2126.02, "word": " H", "probability": 0.8388671875}, {"start": 2126.02, "end": 2126.46, "word": " Plus", "probability": 0.140625}, {"start": 2126.46, "end": 2127.0, "word": " هنا", "probability": 0.6162109375}, {"start": 2127.0, "end": 2127.18, "word": " ال", "probability": 0.94384765625}, {"start": 2127.18, "end": 2127.46, "word": " H", "probability": 0.93359375}, {"start": 2127.46, "end": 2127.9, "word": " هنا", "probability": 0.65576171875}, {"start": 2127.9, "end": 2128.08, "word": " ال", "probability": 0.97265625}, {"start": 2128.08, "end": 2128.46, "word": " PR", "probability": 0.97509765625}, {"start": 2128.46, "end": 2128.72, "word": " إذا", "probability": 0.731201171875}, {"start": 2128.72, "end": 2128.86, "word": " انا", "probability": 0.522705078125}, {"start": 2128.86, "end": 2129.16, "word": " عملت", "probability": 0.9806315104166666}, {"start": 2129.16, "end": 2129.52, "word": " chiral", "probability": 0.93896484375}, {"start": 2129.52, "end": 2129.94, "word": " center", "probability": 0.8916015625}, {"start": 2129.94, "end": 2130.52, "word": " لأن", "probability": 0.53759765625}, {"start": 2130.52, "end": 2130.7, "word": " لما", "probability": 0.7880859375}, {"start": 2130.7, "end": 2131.34, "word": " بضيف", "probability": 0.9007161458333334}, {"start": 2131.34, "end": 2132.3, "word": " في", "probability": 0.82080078125}, {"start": 2132.3, "end": 2132.76, "word": " وجود", "probability": 0.983154296875}, {"start": 2132.76, "end": 2132.92, "word": " ال", "probability": 0.93359375}, {"start": 2132.92, "end": 2133.7, "word": " peroxide", "probability": 0.72705078125}, {"start": 2133.7, "end": 2134.76, "word": " Anti", "probability": 0.21826171875}, {"start": 2134.76, "end": 2136.02, "word": " Markovnikov's", "probability": 0.81279296875}, {"start": 2136.02, "end": 2136.64, "word": " addition", "probability": 0.8271484375}, {"start": 2136.64, "end": 2137.14, "word": " يعني", "probability": 0.897705078125}, {"start": 2137.14, "end": 2137.34, "word": " بدي", "probability": 0.755615234375}, {"start": 2137.34, "end": 2137.78, "word": " ألغى", "probability": 0.9078369140625}, {"start": 2137.78, "end": 2138.08, "word": " هذا", "probability": 0.38427734375}, {"start": 2138.08, "end": 2138.2, "word": " ال", "probability": 0.7958984375}, {"start": 2138.2, "end": 2138.4, "word": " double", "probability": 0.84765625}, {"start": 2138.4, "end": 2138.94, "word": " bond", "probability": 0.962890625}, {"start": 2138.94, "end": 2139.54, "word": " و", "probability": 0.4765625}, {"start": 2139.54, "end": 2139.96, "word": " أحط", "probability": 0.8795572916666666}, {"start": 2139.96, "end": 2140.46, "word": " هنا", "probability": 0.97314453125}, {"start": 2140.46, "end": 2141.92, "word": " H", "probability": 0.9404296875}, {"start": 2141.92, "end": 2142.36, "word": " و", "probability": 0.71630859375}, {"start": 2142.36, "end": 2142.7, "word": " هنا", "probability": 0.92724609375}, {"start": 2142.7, "end": 2143.3, "word": " PR", "probability": 0.79296875}], "temperature": 1.0}, {"id": 83, "seek": 215855, "start": 2143.65, "end": 2158.55, "text": "بر فيها انا كايرال سنتر فيها انا كايرال سنتر اذا الكم ايزو مار طلع عني واحد مش اتنين لو كنا بنضيف hbr في وجود h plus بطلع اتنين", "tokens": [26890, 8978, 11296, 1975, 8315, 9122, 995, 13546, 6027, 8608, 29399, 2288, 8978, 11296, 1975, 8315, 9122, 995, 13546, 6027, 8608, 29399, 2288, 1975, 15730, 2423, 24793, 1975, 1829, 11622, 2407, 3714, 9640, 23032, 1211, 3615, 18871, 1829, 36764, 24401, 37893, 1975, 2655, 1863, 9957, 45164, 9122, 8315, 44945, 11242, 33911, 276, 1443, 8978, 49610, 23328, 276, 1804, 4724, 9566, 1211, 3615, 1975, 2655, 1863, 9957], "avg_logprob": -0.3393190218441522, "compression_ratio": 1.6846153846153846, "no_speech_prob": 0.0, "words": [{"start": 2143.65, "end": 2144.17, "word": "بر", "probability": 0.155029296875}, {"start": 2144.17, "end": 2144.85, "word": " فيها", "probability": 0.4710693359375}, {"start": 2144.85, "end": 2145.05, "word": " انا", "probability": 0.5621337890625}, {"start": 2145.05, "end": 2145.49, "word": " كايرال", "probability": 0.710205078125}, {"start": 2145.49, "end": 2146.11, "word": " سنتر", "probability": 0.6466471354166666}, {"start": 2146.11, "end": 2146.95, "word": " فيها", "probability": 0.568359375}, {"start": 2146.95, "end": 2147.11, "word": " انا", "probability": 0.930908203125}, {"start": 2147.11, "end": 2147.53, "word": " كايرال", "probability": 0.9683837890625}, {"start": 2147.53, "end": 2148.21, "word": " سنتر", "probability": 0.9733072916666666}, {"start": 2148.21, "end": 2149.09, "word": " اذا", "probability": 0.62255859375}, {"start": 2149.09, "end": 2149.41, "word": " الكم", "probability": 0.7509765625}, {"start": 2149.41, "end": 2149.87, "word": " ايزو", "probability": 0.50433349609375}, {"start": 2149.87, "end": 2150.05, "word": " مار", "probability": 0.7529296875}, {"start": 2150.05, "end": 2150.35, "word": " طلع", "probability": 0.7685546875}, {"start": 2150.35, "end": 2150.67, "word": " عني", "probability": 0.51593017578125}, {"start": 2150.67, "end": 2151.73, "word": " واحد", "probability": 0.796875}, {"start": 2151.73, "end": 2153.57, "word": " مش", "probability": 0.716796875}, {"start": 2153.57, "end": 2154.09, "word": " اتنين", "probability": 0.9622802734375}, {"start": 2154.09, "end": 2155.19, "word": " لو", "probability": 0.86474609375}, {"start": 2155.19, "end": 2155.43, "word": " كنا", "probability": 0.974365234375}, {"start": 2155.43, "end": 2155.99, "word": " بنضيف", "probability": 0.9661458333333334}, {"start": 2155.99, "end": 2156.81, "word": " hbr", "probability": 0.3773193359375}, {"start": 2156.81, "end": 2156.95, "word": " في", "probability": 0.9677734375}, {"start": 2156.95, "end": 2157.21, "word": " وجود", "probability": 0.972900390625}, {"start": 2157.21, "end": 2157.43, "word": " h", "probability": 0.8603515625}, {"start": 2157.43, "end": 2157.73, "word": " plus", "probability": 0.33935546875}, {"start": 2157.73, "end": 2158.11, "word": " بطلع", "probability": 0.8350830078125}, {"start": 2158.11, "end": 2158.55, "word": " اتنين", "probability": 0.9898681640625}], "temperature": 1.0}, {"id": 84, "seek": 219546, "start": 2168.27, "end": 2195.47, "text": "هذا السؤال MAI reacts with ethyl chloride producing ethyl iodide لاحظوا هنا إبدال أن اليود بيحل محل كلور هذه المعلومة أخدناها ولا لأ اليود بيحل محل كلور و العكس مش صحيح Cyclohexanol بتكون تتذكروا بمخكوا ع طول ال Cyclohexanol", "tokens": [3224, 15730, 21136, 33604, 6027, 376, 48698, 33305, 365, 1030, 3495, 75, 35434, 10501, 1030, 3495, 75, 44422, 482, 20193, 5016, 19913, 14407, 34105, 11933, 44510, 6027, 14739, 45595, 23328, 4724, 1829, 5016, 1211, 3714, 5016, 1211, 9122, 1211, 13063, 29538, 9673, 30241, 20498, 3660, 5551, 9778, 3215, 8315, 11296, 49429, 5296, 10721, 45595, 23328, 4724, 1829, 5016, 1211, 3714, 5016, 1211, 9122, 1211, 13063, 4032, 18863, 4117, 3794, 37893, 20328, 5016, 1829, 5016, 10295, 66, 752, 675, 87, 282, 401, 39894, 30544, 6055, 2655, 8848, 37983, 14407, 4724, 2304, 9778, 4117, 14407, 6225, 23032, 12610, 2423, 10295, 66, 752, 675, 87, 282, 401], "avg_logprob": -0.19657738549368722, "compression_ratio": 1.588785046728972, "no_speech_prob": 0.0, "words": [{"start": 2168.27, "end": 2168.71, "word": "هذا", "probability": 0.89892578125}, {"start": 2168.71, "end": 2169.33, "word": " السؤال", "probability": 0.99365234375}, {"start": 2169.33, "end": 2170.29, "word": " MAI", "probability": 0.424468994140625}, {"start": 2170.29, "end": 2170.83, "word": " reacts", "probability": 0.52001953125}, {"start": 2170.83, "end": 2171.11, "word": " with", "probability": 0.9033203125}, {"start": 2171.11, "end": 2171.49, "word": " ethyl", "probability": 0.908203125}, {"start": 2171.49, "end": 2171.91, "word": " chloride", "probability": 0.93701171875}, {"start": 2171.91, "end": 2172.67, "word": " producing", "probability": 0.6025390625}, {"start": 2172.67, "end": 2173.11, "word": " ethyl", "probability": 0.8805338541666666}, {"start": 2173.11, "end": 2173.77, "word": " iodide", "probability": 0.97705078125}, {"start": 2173.77, "end": 2174.41, "word": " لاحظوا", "probability": 0.8074951171875}, {"start": 2174.41, "end": 2174.61, "word": " هنا", "probability": 0.8154296875}, {"start": 2174.61, "end": 2175.11, "word": " إبدال", "probability": 0.70068359375}, {"start": 2175.11, "end": 2175.77, "word": " أن", "probability": 0.418701171875}, {"start": 2175.77, "end": 2176.41, "word": " اليود", "probability": 0.84423828125}, {"start": 2176.41, "end": 2177.01, "word": " بيحل", "probability": 0.76617431640625}, {"start": 2177.01, "end": 2177.45, "word": " محل", "probability": 0.89697265625}, {"start": 2177.45, "end": 2178.05, "word": " كلور", "probability": 0.8323567708333334}, {"start": 2178.05, "end": 2178.67, "word": " هذه", "probability": 0.615234375}, {"start": 2178.67, "end": 2179.25, "word": " المعلومة", "probability": 0.9912109375}, {"start": 2179.25, "end": 2179.87, "word": " أخدناها", "probability": 0.9578125}, {"start": 2179.87, "end": 2180.09, "word": " ولا", "probability": 0.7265625}, {"start": 2180.09, "end": 2180.53, "word": " لأ", "probability": 0.88525390625}, {"start": 2180.53, "end": 2183.67, "word": " اليود", "probability": 0.80859375}, {"start": 2183.67, "end": 2184.01, "word": " بيحل", "probability": 0.9925537109375}, {"start": 2184.01, "end": 2184.33, "word": " محل", "probability": 0.9903971354166666}, {"start": 2184.33, "end": 2184.65, "word": " كلور", "probability": 0.9563802083333334}, {"start": 2184.65, "end": 2184.75, "word": " و", "probability": 0.62548828125}, {"start": 2184.75, "end": 2185.05, "word": " العكس", "probability": 0.89599609375}, {"start": 2185.05, "end": 2185.19, "word": " مش", "probability": 0.953125}, {"start": 2185.19, "end": 2186.29, "word": " صحيح", "probability": 0.9954833984375}, {"start": 2186.29, "end": 2188.57, "word": " Cyclohexanol", "probability": 0.90576171875}, {"start": 2188.57, "end": 2192.63, "word": " بتكون", "probability": 0.5001220703125}, {"start": 2192.63, "end": 2193.29, "word": " تتذكروا", "probability": 0.92021484375}, {"start": 2193.29, "end": 2193.79, "word": " بمخكوا", "probability": 0.809423828125}, {"start": 2193.79, "end": 2193.93, "word": " ع", "probability": 0.412841796875}, {"start": 2193.93, "end": 2194.13, "word": " طول", "probability": 0.81640625}, {"start": 2194.13, "end": 2194.33, "word": " ال", "probability": 0.62548828125}, {"start": 2194.33, "end": 2195.47, "word": " Cyclohexanol", "probability": 0.9090401785714286}], "temperature": 1.0}, {"id": 85, "seek": 221467, "start": 2196.45, "end": 2214.67, "text": "ركزنا عليه في الرسم ولا لأ؟ اللي متصل ب OH لو عملتله أكسدة شو هيعمل؟ هيحذف ال H و ال H هاي الأكسدة تبعته، هاي أكسدته، إيش أعطاني؟", "tokens": [31747, 11622, 8315, 47356, 8978, 34892, 38251, 49429, 5296, 10721, 22807, 13672, 1829, 44650, 36520, 4724, 13931, 45164, 6225, 42213, 2655, 43761, 5551, 4117, 3794, 41891, 13412, 2407, 39896, 25957, 1211, 22807, 39896, 5016, 8848, 5172, 2423, 389, 4032, 2423, 389, 8032, 47302, 16247, 4117, 3794, 41891, 6055, 3555, 34268, 3224, 12399, 8032, 47302, 5551, 4117, 3794, 3215, 47395, 12399, 11933, 1829, 8592, 5551, 3615, 9566, 7649, 1829, 22807], "avg_logprob": -0.15424107504742487, "compression_ratio": 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"end": 2202.37, "word": " عملتله", "probability": 0.8868408203125}, {"start": 2202.37, "end": 2202.89, "word": " أكسدة", "probability": 0.8604736328125}, {"start": 2202.89, "end": 2203.13, "word": " شو", "probability": 0.859619140625}, {"start": 2203.13, "end": 2205.19, "word": " هيعمل؟", "probability": 0.9302978515625}, {"start": 2205.19, "end": 2206.27, "word": " هيحذف", "probability": 0.9146728515625}, {"start": 2206.27, "end": 2206.47, "word": " ال", "probability": 0.96630859375}, {"start": 2206.47, "end": 2206.75, "word": " H", "probability": 0.9375}, {"start": 2206.75, "end": 2206.93, "word": " و", "probability": 0.76220703125}, {"start": 2206.93, "end": 2207.03, "word": " ال", "probability": 0.58544921875}, {"start": 2207.03, "end": 2207.49, "word": " H", "probability": 0.94970703125}, {"start": 2207.49, "end": 2209.53, "word": " هاي", "probability": 0.723388671875}, {"start": 2209.53, "end": 2210.11, "word": " الأكسدة", "probability": 0.8931884765625}, {"start": 2210.11, "end": 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2410.04, "word": " اوري", "probability": 0.5952962239583334}, {"start": 2410.04, "end": 2410.42, "word": " ترانس", "probability": 0.8260498046875}, {"start": 2410.42, "end": 2410.62, "word": " تو", "probability": 0.572265625}, {"start": 2410.62, "end": 2411.24, "word": " بيوتين", "probability": 0.9364013671875}, {"start": 2411.24, "end": 2414.26, "word": " خليني", "probability": 0.582733154296875}, {"start": 2414.26, "end": 2414.66, "word": " اخد", "probability": 0.7508138020833334}, {"start": 2414.66, "end": 2414.84, "word": " ال", "probability": 0.810546875}, {"start": 2414.84, "end": 2415.14, "word": " سيس", "probability": 0.6696573893229166}, {"start": 2415.14, "end": 2415.38, "word": " تو", "probability": 0.7734375}, {"start": 2415.38, "end": 2415.98, "word": " بيوتين", "probability": 0.983642578125}, {"start": 2415.98, "end": 2417.9, "word": " ارسمه", "probability": 0.762939453125}, {"start": 2417.9, "end": 2418.28, "word": " هان", "probability": 0.66455078125}, {"start": 2418.28, "end": 2419.28, "word": " هاي", "probability": 0.5850830078125}, {"start": 2419.28, "end": 2419.44, "word": " ال", "probability": 0.85546875}, {"start": 2419.44, "end": 2419.62, "word": " سيس", "probability": 0.8143717447916666}, {"start": 2419.62, "end": 2419.86, "word": " تو", "probability": 0.90185546875}, {"start": 2419.86, "end": 2420.28, "word": " بيوتين", "probability": 0.990478515625}, {"start": 2420.28, "end": 2420.48, "word": " بدي", "probability": 0.613037109375}, {"start": 2420.48, "end": 2420.98, "word": " اكسره", "probability": 0.8626953125}, {"start": 2420.98, "end": 2421.12, "word": " من", "probability": 0.986328125}, {"start": 2421.12, "end": 2421.5, "word": " هان", "probability": 0.766845703125}, {"start": 2421.5, "end": 2422.16, "word": " C", "probability": 0.285888671875}, {"start": 2422.16, "end": 2422.36, "word": " double", "probability": 0.3046875}, {"start": 2422.36, "end": 2422.72, "word": " bond", "probability": 0.92626953125}, {"start": 2422.72, "end": 2423.08, "word": " O", "probability": 0.87255859375}, {"start": 2423.08, "end": 2423.56, "word": " وهذه", "probability": 0.4080810546875}, {"start": 2423.56, "end": 2423.88, "word": " H", "probability": 0.68701171875}, {"start": 2423.88, "end": 2424.64, "word": " بالتأكيد", "probability": 0.92607421875}], "temperature": 1.0}, {"id": 93, "seek": 245340, "start": 2426.66, "end": 2453.4, "text": "هذا C double bond OH CH3 Acetaldehyde هذا C double bond OH CH3 Acetaldehyde و لل Trans هاي CH3H و هنا CH3H الان اكسروا هذا من هنا و اكسروا هذا من هنا و حطوا ايش Oxygen Oxygen Oxygen Oxygen", "tokens": [3224, 15730, 383, 3834, 6086, 13931, 5995, 18, 5097, 302, 304, 1479, 3495, 1479, 23758, 383, 3834, 6086, 13931, 5995, 18, 5097, 302, 304, 1479, 3495, 1479, 4032, 24976, 6531, 8032, 47302, 5995, 18, 39, 4032, 34105, 5995, 18, 39, 2423, 7649, 1975, 4117, 3794, 2288, 14407, 23758, 9154, 34105, 4032, 1975, 4117, 3794, 2288, 14407, 23758, 9154, 34105, 4032, 11331, 9566, 14407, 1975, 1829, 8592, 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2431.56, "end": 2431.88, "word": " bond", "probability": 0.97021484375}, {"start": 2431.88, "end": 2432.3, "word": " OH", "probability": 0.96875}, {"start": 2432.3, "end": 2433.22, "word": " CH3", "probability": 0.971923828125}, {"start": 2433.22, "end": 2434.14, "word": " Acetaldehyde", "probability": 0.9671223958333334}, {"start": 2434.14, "end": 2434.5, "word": " و", "probability": 0.560546875}, {"start": 2434.5, "end": 2434.68, "word": " لل", "probability": 0.354736328125}, {"start": 2434.68, "end": 2435.22, "word": " Trans", "probability": 0.345947265625}, {"start": 2435.22, "end": 2438.4, "word": " هاي", "probability": 0.653564453125}, {"start": 2438.4, "end": 2439.94, "word": " CH3H", "probability": 0.9697265625}, {"start": 2439.94, "end": 2440.78, "word": " و", "probability": 0.78076171875}, {"start": 2440.78, "end": 2441.06, "word": " هنا", "probability": 0.77734375}, {"start": 2441.06, "end": 2443.38, "word": " CH3H", "probability": 0.9918619791666666}, {"start": 2443.38, "end": 2444.32, "word": " الان", "probability": 0.61572265625}, {"start": 2444.32, "end": 2445.04, "word": " اكسروا", "probability": 0.95634765625}, {"start": 2445.04, "end": 2445.32, "word": " هذا", "probability": 0.916015625}, {"start": 2445.32, "end": 2445.56, "word": " من", "probability": 0.9873046875}, {"start": 2445.56, "end": 2445.9, "word": " هنا", "probability": 0.93212890625}, {"start": 2445.9, "end": 2447.16, "word": " و", "probability": 0.55810546875}, {"start": 2447.16, "end": 2447.64, "word": " اكسروا", "probability": 0.9751953125}, {"start": 2447.64, "end": 2447.88, "word": " هذا", "probability": 0.9833984375}, {"start": 2447.88, "end": 2448.14, "word": " من", "probability": 0.9892578125}, {"start": 2448.14, "end": 2448.5, "word": " هنا", "probability": 0.9658203125}, {"start": 2448.5, "end": 2448.78, "word": " و", "probability": 0.9794921875}, {"start": 2448.78, "end": 2449.18, "word": " حطوا", "probability": 0.8522135416666666}, {"start": 2449.18, "end": 2449.52, "word": " ايش", "probability": 0.8619791666666666}, {"start": 2449.52, "end": 2451.12, "word": " Oxygen", "probability": 0.720703125}, {"start": 2451.12, "end": 2451.96, "word": " Oxygen", "probability": 0.81591796875}, {"start": 2451.96, "end": 2452.74, "word": " Oxygen", "probability": 0.95361328125}, {"start": 2452.74, "end": 2453.4, "word": " Oxygen", "probability": 0.972412109375}], "temperature": 1.0}, {"id": 94, "seek": 247496, "start": 2453.98, "end": 2474.96, "text": "كل النواتج ايش؟ أسيتلديهيد بيعطي نفس الناتج produces only أسيتلديهيد أو إيثانال أسيتلديهيد CH3SH is more acidic than CH3OH due to size", "tokens": [28820, 28239, 2407, 9307, 7435, 1975, 1829, 8592, 22807, 5551, 3794, 36081, 1211, 16254, 3224, 25708, 4724, 40228, 9566, 1829, 8717, 36178, 28239, 9307, 7435, 14725, 787, 5551, 3794, 36081, 1211, 16254, 3224, 25708, 34051, 11933, 1829, 12984, 7649, 6027, 5551, 3794, 36081, 1211, 16254, 3224, 25708, 5995, 18, 17308, 307, 544, 39514, 813, 5995, 18, 31187, 3462, 281, 2744], "avg_logprob": -0.25909324161341935, "compression_ratio": 1.3513513513513513, "no_speech_prob": 0.0, "words": [{"start": 2453.98, "end": 2454.34, "word": "كل", "probability": 0.771484375}, {"start": 2454.34, "end": 2455.02, "word": " النواتج", "probability": 0.8031005859375}, {"start": 2455.02, "end": 2455.5, "word": " ايش؟", "probability": 0.706787109375}, {"start": 2455.5, "end": 2457.06, "word": " أسيتلديهيد", "probability": 0.6798270089285714}, {"start": 2457.06, "end": 2458.52, "word": " بيعطي", "probability": 0.78363037109375}, {"start": 2458.52, "end": 2458.8, "word": " نفس", "probability": 0.989990234375}, {"start": 2458.8, "end": 2459.48, "word": " الناتج", "probability": 0.9140625}, {"start": 2459.48, "end": 2460.38, "word": " produces", "probability": 0.2047119140625}, {"start": 2460.38, "end": 2461.22, "word": " only", "probability": 0.83349609375}, {"start": 2461.22, "end": 2463.4, "word": " أسيتلديهيد", "probability": 0.9464285714285714}, {"start": 2463.4, "end": 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"seek": 249844, "start": 2477.52, "end": 2498.44, "text": "سلفر مع اكسجين ايش العامل المحدد في ال acidity ال size ال due to size الان ارسموا المراكبات التالية بدي بيوتين", "tokens": [3794, 46538, 2288, 20449, 1975, 4117, 3794, 7435, 9957, 1975, 1829, 8592, 18863, 10943, 1211, 9673, 24401, 3215, 8978, 2423, 8258, 507, 2423, 2744, 2423, 3462, 281, 2744, 2423, 7649, 1975, 2288, 38251, 14407, 9673, 23557, 4117, 3555, 9307, 16712, 6027, 10632, 4724, 16254, 4724, 1829, 35473, 9957], "avg_logprob": -0.35299744897959184, "compression_ratio": 1.3953488372093024, "no_speech_prob": 0.0, "words": [{"start": 2477.52, "end": 2478.28, "word": "سلفر", "probability": 0.5266520182291666}, {"start": 2478.28, "end": 2478.46, "word": " مع", "probability": 0.9072265625}, {"start": 2478.46, "end": 2479.22, "word": " اكسجين", "probability": 0.784765625}, {"start": 2479.22, "end": 2479.92, "word": " ايش", "probability": 0.456787109375}, {"start": 2479.92, "end": 2480.32, "word": " العامل", "probability": 0.8824869791666666}, {"start": 2480.32, "end": 2480.92, "word": " المحدد", "probability": 0.9825846354166666}, {"start": 2480.92, "end": 2481.04, "word": " في", "probability": 0.86865234375}, {"start": 2481.04, "end": 2481.14, "word": " ال", "probability": 0.89990234375}, {"start": 2481.14, "end": 2481.84, "word": " acidity", "probability": 0.7132568359375}, {"start": 2481.84, "end": 2482.56, "word": " ال", "probability": 0.333984375}, {"start": 2482.56, "end": 2483.04, "word": " size", "probability": 0.29345703125}, {"start": 2483.04, "end": 2483.74, "word": " ال", "probability": 0.5029296875}, {"start": 2483.74, "end": 2483.96, "word": " due", "probability": 0.54296875}, {"start": 2483.96, "end": 2484.24, "word": " to", "probability": 0.94580078125}, {"start": 2484.24, "end": 2487.82, "word": " size", "probability": 0.5068359375}, {"start": 2487.82, "end": 2494.74, "word": " الان", "probability": 0.684326171875}, {"start": 2494.74, "end": 2495.44, "word": " ارسموا", "probability": 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39182, 9957, 4724, 8592, 38688, 3224, 1975, 15730, 23032, 1211, 3615, 497, 25961, 4724, 1829, 11296, 19446, 9566, 1211, 3615, 8592, 497], "avg_logprob": -0.263338401186757, "compression_ratio": 1.4126984126984128, "no_speech_prob": 0.0, "words": [{"start": 2499.56, "end": 2499.96, "word": "يعني", "probability": 0.93994140625}, {"start": 2499.96, "end": 2500.66, "word": " carbon", "probability": 0.55859375}, {"start": 2500.66, "end": 2501.7, "word": " تنتين", "probability": 0.7813313802083334}, {"start": 2501.7, "end": 2502.56, "word": " تلاتة", "probability": 0.9219970703125}, {"start": 2502.56, "end": 2503.2, "word": " أربعة", "probability": 0.8445638020833334}, {"start": 2503.2, "end": 2503.8, "word": " على", "probability": 0.765625}, {"start": 2503.8, "end": 2504.18, "word": " لمرة", "probability": 0.6177978515625}, {"start": 2504.18, "end": 2504.82, "word": " اتنين", "probability": 0.824462890625}, {"start": 2504.82, "end": 2505.6, "word": " ايش", "probability": 0.7565104166666666}, {"start": 2505.6, "end": 2506.06, "word": " موجود", "probability": 0.9786783854166666}, {"start": 2506.06, "end": 2506.82, "word": " عندكم؟", "probability": 0.7901204427083334}, {"start": 2506.82, "end": 2508.24, "word": " فينوكسي", "probability": 0.751220703125}, {"start": 2508.24, "end": 2508.52, "word": " يعني", "probability": 0.76904296875}, {"start": 2508.52, "end": 2508.88, "word": " O", "probability": 0.595703125}, {"start": 2508.88, "end": 2509.58, "word": " phenyl", "probability": 0.5126953125}, {"start": 2509.58, "end": 2511.12, "word": " OH", "probability": 0.740234375}, {"start": 2511.12, "end": 2512.08, "word": " OHANA", "probability": 0.49072265625}, {"start": 2512.08, "end": 2513.62, "word": " CH3", "probability": 0.91162109375}, {"start": 2513.62, "end": 2514.68, "word": " CH2", "probability": 0.90185546875}, {"start": 2514.68, "end": 2515.82, "word": " CH3", "probability": 0.964111328125}, {"start": 2515.82, "end": 2516.9, "word": " الآن", 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"probability": 0.875}], "temperature": 1.0}, {"id": 97, "seek": 254529, "start": 2522.81, "end": 2545.29, "text": "بعكس اي مجموع تاني الا لو جيت تطلعت عليه كيف مبين هذي واحد هذي اتنين هذي تلاتة مبين اس و هذي على الجانب اذا هذا فعلا الار ايزو مار عندي سايكلو بنتين هاي السايكلو بنتين خليني ارسمه بهذا الشكل", "tokens": [3555, 3615, 4117, 3794, 1975, 1829, 3714, 7435, 2304, 45367, 6055, 7649, 1829, 42963, 45164, 10874, 36081, 6055, 9566, 1211, 34268, 47356, 9122, 33911, 3714, 3555, 9957, 8032, 8848, 1829, 36764, 24401, 8032, 8848, 1829, 1975, 2655, 1863, 9957, 8032, 8848, 1829, 6055, 1211, 9307, 3660, 3714, 3555, 9957, 24525, 4032, 8032, 8848, 1829, 15844, 25724, 7649, 3555, 1975, 15730, 23758, 6156, 3615, 15040, 2423, 9640, 1975, 1829, 11622, 2407, 3714, 9640, 18871, 16254, 8608, 47302, 28820, 2407, 4724, 29399, 9957, 8032, 47302, 21136, 47302, 28820, 2407, 4724, 29399, 9957, 16490, 1211, 9957, 1829, 1975, 2288, 38251, 3224, 39627, 15730, 25124, 28820], "avg_logprob": -0.307949022760669, 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بنتين", "probability": 0.9261067708333334}, {"start": 2543.43, "end": 2543.81, "word": " خليني", "probability": 0.8211669921875}, {"start": 2543.81, "end": 2544.31, "word": " ارسمه", "probability": 0.8828125}, {"start": 2544.31, "end": 2544.77, "word": " بهذا", "probability": 0.96826171875}, {"start": 2544.77, "end": 2545.29, "word": " الشكل", "probability": 0.989990234375}], "temperature": 1.0}, {"id": 98, "seek": 257217, "start": 2546.13, "end": 2572.17, "text": "cyclopentane واحد اتنين تلاتة اربعة خمسة على نمرة تلاتة واربعة شو بدي احط كلور وكلور بالزويك أسد C double bond O OH وهنا ال formal C double bond OH هذا ميتا", "tokens": [1344, 66, 752, 22786, 1929, 36764, 24401, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 1975, 25513, 27884, 16490, 2304, 3794, 3660, 15844, 8717, 2304, 25720, 6055, 1211, 9307, 3660, 4032, 9640, 3555, 27884, 13412, 2407, 4724, 16254, 1975, 5016, 9566, 9122, 1211, 13063, 4032, 28820, 13063, 20666, 11622, 45865, 4117, 5551, 3794, 3215, 383, 3834, 6086, 422, 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"word": " واربعة", "probability": 0.791748046875}, {"start": 2551.85, "end": 2552.03, "word": " شو", "probability": 0.877685546875}, {"start": 2552.03, "end": 2552.21, "word": " بدي", "probability": 0.7281494140625}, {"start": 2552.21, "end": 2552.63, "word": " احط", "probability": 0.9226888020833334}, {"start": 2552.63, "end": 2554.27, "word": " كلور", "probability": 0.6844889322916666}, {"start": 2554.27, "end": 2554.93, "word": " وكلور", "probability": 0.742919921875}, {"start": 2554.93, "end": 2558.95, "word": " بالزويك", "probability": 0.649169921875}, {"start": 2558.95, "end": 2559.91, "word": " أسد", "probability": 0.7569986979166666}, {"start": 2559.91, "end": 2562.09, "word": " C", "probability": 0.293701171875}, {"start": 2562.09, "end": 2562.35, "word": " double", "probability": 0.31201171875}, {"start": 2562.35, "end": 2562.69, "word": " bond", "probability": 0.92041015625}, {"start": 2562.69, "end": 2563.23, "word": " O", "probability": 0.88671875}, {"start": 2563.23, 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كحول ألكين من وين الترقيم؟ من عند الكحول يعني هذا", "tokens": [2304, 36081, 995, 34051, 4724, 9640, 995, 23758, 3714, 2407, 11242, 45367, 4724, 3794, 1829, 9566, 23758, 9673, 31747, 3555, 49173, 404, 317, 1929, 13412, 2407, 29538, 9673, 7435, 2304, 2407, 27884, 22807, 286, 539, 5955, 5088, 286, 539, 5955, 5088, 49173, 404, 317, 1929, 23758, 9122, 5016, 12610, 5551, 1211, 4117, 9957, 9154, 4032, 9957, 16712, 2288, 4587, 32640, 22807, 9154, 43242, 33251, 5016, 12610, 37495, 22653, 23758], "avg_logprob": -0.24575893240315574, "compression_ratio": 1.50625, "no_speech_prob": 0.0, "words": [{"start": 2573.4, "end": 2573.98, "word": "ميتا", "probability": 0.6168619791666666}, {"start": 2573.98, "end": 2574.14, "word": " أو", "probability": 0.76025390625}, {"start": 2574.14, "end": 2574.4, "word": " بارا", "probability": 0.9529622395833334}, {"start": 2574.4, "end": 2574.62, "word": " هذا", "probability": 0.74560546875}, {"start": 2574.62, "end": 2575.02, "word": " موضوع", "probability": 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"من الأربعة شو بده احضر؟ ستة كيف بده اعمل هذا الكلام؟ اول اشي بده ازيد ذاتين carbon فانا لو فعلت مع ال NANH2 نمرة واحد خلت هذه minus", "tokens": [27842, 16247, 25513, 27884, 13412, 2407, 47525, 3224, 1975, 5016, 11242, 2288, 22807, 8608, 2655, 3660, 9122, 33911, 47525, 3224, 1975, 25957, 1211, 23758, 2423, 28820, 10943, 22807, 1975, 12610, 1975, 8592, 1829, 47525, 3224, 1975, 11622, 25708, 29910, 9307, 9957, 5954, 6156, 7649, 995, 45164, 6156, 30241, 2655, 20449, 2423, 426, 1770, 39, 17, 8717, 2304, 25720, 36764, 24401, 16490, 1211, 2655, 29538, 3175], "avg_logprob": -0.2447916612480626, "compression_ratio": 1.36875, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2958.69, "end": 2958.97, "word": "من", "probability": 0.495361328125}, {"start": 2958.97, "end": 2959.45, "word": " الأربعة", "probability": 0.80908203125}, {"start": 2959.45, "end": 2959.61, "word": " شو", "probability": 0.647705078125}, {"start": 2959.61, "end": 2959.79, "word": " بده", "probability": 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3047.83, "word": " ابقى", "probability": 0.4733072916666667}, {"start": 3047.83, "end": 3047.95, "word": " اك", "probability": 0.5146484375}, {"start": 3047.95, "end": 3048.59, "word": " تقريبا", "probability": 0.98447265625}, {"start": 3048.59, "end": 3049.05, "word": " بنكون", "probability": 0.897216796875}, {"start": 3049.05, "end": 3049.73, "word": " غطينا", "probability": 0.9752197265625}, {"start": 3049.73, "end": 3050.69, "word": " يعني", "probability": 0.885009765625}, {"start": 3050.69, "end": 3051.31, "word": " باسئلة", "probability": 0.9498291015625}, {"start": 3051.31, "end": 3051.93, "word": " مختلفة", "probability": 0.9923095703125}, {"start": 3051.93, "end": 3052.33, "word": " معظم", "probability": 0.9803059895833334}, {"start": 3052.33, "end": 3053.13, "word": " الأشياء", "probability": 0.983642578125}, {"start": 3053.13, "end": 3053.81, "word": " اللي", "probability": 0.808837890625}, {"start": 3053.81, "end": 3054.73, "word": " درسناها", "probability": 0.9521484375}, {"start": 3054.73, "end": 3054.89, "word": " و", "probability": 0.8740234375}, {"start": 3054.89, "end": 3055.79, "word": " بنتمنالكوا", "probability": 0.677587890625}, {"start": 3055.79, "end": 3055.89, "word": " ان", "probability": 0.81103515625}, {"start": 3055.89, "end": 3056.07, "word": " شاء", "probability": 0.941162109375}, {"start": 3056.07, "end": 3056.17, "word": " الله", "probability": 0.94775390625}, {"start": 3056.17, "end": 3056.87, "word": " النجاح", "probability": 0.9656575520833334}, {"start": 3056.87, "end": 3057.01, "word": " و", "probability": 0.61474609375}, {"start": 3057.01, "end": 3057.49, "word": " التوفيق", "probability": 0.979736328125}, {"start": 3057.49, "end": 3057.63, "word": " في", "probability": 0.9033203125}, {"start": 3057.63, "end": 3058.11, "word": " الامتحان", "probability": 0.975}, {"start": 3058.11, "end": 3058.23, "word": " اللي", "probability": 0.8857421875}, {"start": 3058.23, "end": 3058.51, "word": " بدكنوا", "probability": 0.5111490885416666}, {"start": 3058.51, "end": 3059.05, "word": " تقدموه", "probability": 0.959765625}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 3059.972, "duration_after_vad": 2821.7949999999896}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/7aZWDTxPij4_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/7aZWDTxPij4_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e5bf93dcb8a75119f849750f6e18ea73977c01cd
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/7aZWDTxPij4_postprocess.srt
@@ -0,0 +1,1440 @@
+1
+00:00:21,240 --> 00:00:26,260
+بسم الله الرحمن الرحيم موضوعنا اليوم عن ال
+
+2
+00:00:26,260 --> 00:00:31,560
+stereochemistry ربما يعني انتوا اتشوقتوا اليها لان
+
+3
+00:00:31,560 --> 00:00:37,220
+احنا من اول محاضرة لما اتكلمنا عن المتشكلات او ال
+
+4
+00:00:37,220 --> 00:00:43,960
+isomers قسمناهم وقلنا هم نوعين اساسيين structural
+
+5
+00:00:43,960 --> 00:00:48,920
+isomers او constitutional isomers سمناهم و stereo
+
+6
+00:00:48,920 --> 00:00:54,250
+isomersالان هذا التصنيف اللى بنشوفه باللوحة
+
+7
+00:00:54,250 --> 00:01:01,030
+التصنيف العام ل .. خلينا نقول ال isomers أخدنا جزء
+
+8
+00:01:01,030 --> 00:01:06,510
+منه اللى هو إيش معنى isomers بشكل عام المركبات
+
+9
+00:01:06,510 --> 00:01:10,750
+اللى لها نفس الصيغة الجزائية ولكن بتختلف في الشكل
+
+10
+00:01:10,750 --> 00:01:16,070
+الان قسمت إلى نوعين النوع الأول ال structural
+
+11
+00:01:16,070 --> 00:01:21,770
+isomers المركباتاللي بتختلف في مواقع ارتباط الذرات
+
+12
+00:01:21,770 --> 00:01:25,310
+يعني فيها different bonding وقولنا هذا different
+
+13
+00:01:25,310 --> 00:01:29,350
+bonding بيقدر إلى انه يكون لها different names ولو
+
+14
+00:01:29,350 --> 00:01:33,430
+على اقل تقدير في الرقم اللي بيحدد مثلا Substituent
+
+15
+00:01:33,430 --> 00:01:37,470
+يعني على سبيل المثال لما نقول بروبين امكون من تلت
+
+16
+00:01:37,470 --> 00:01:41,750
+ذرات الآن على الموقع الأول Clor أو على الموقع
+
+17
+00:01:41,750 --> 00:01:45,430
+التاني Clorهذا صار different bonding يعني أي حد
+
+18
+00:01:45,430 --> 00:01:49,670
+يقول هدولة شو بيفرقوا على البعض، هيقول هذا بروبين
+
+19
+00:01:49,670 --> 00:01:52,990
+تلت ذرات على الموقع الأول كلور صار اسمه one
+
+20
+00:01:52,990 --> 00:01:57,190
+chloroborbine التاني على الموقع اتنين two
+
+21
+00:01:57,190 --> 00:02:03,100
+chloroborbine هدولة اسمين مختلفينالان الشيء التاني
+
+22
+00:02:03,100 --> 00:02:07,900
+في ال isomers اللى حتى ايضا بدنا فيه اللى هو ال
+
+23
+00:02:07,900 --> 00:02:12,900
+stereo isomers المركبات اللى بتكون لها نفس
+
+24
+00:02:12,900 --> 00:02:17,840
+الارتباط ولكن اختلاف في شكلها بالفراغ ولذلك احنا
+
+25
+00:02:17,840 --> 00:02:21,400
+قولنا ال stereo isomers ال atoms they have the
+
+26
+00:02:21,400 --> 00:02:26,970
+same constitutiondifferent arrangement in space
+
+27
+00:02:26,970 --> 00:02:31,590
+بدأنا فيهم الحقيقة لما احنا أخدنا مراكبات ال sis
+
+28
+00:02:31,590 --> 00:02:36,990
+والترانس يعني مثلا عندنا اثين على موقع واحد كلور
+
+29
+00:02:36,990 --> 00:02:40,890
+هاي اثين جزئي ب double bond على موقع واحد كلور
+
+30
+00:02:40,890 --> 00:02:45,030
+وعلى موقع اتنين كلور وبناء على ذلك شو هيصير اسمه
+
+31
+00:02:45,030 --> 00:02:51,130
+one two dichloro ethaneSame bondage الآن يا تورا
+
+32
+00:02:51,130 --> 00:02:57,650
+هدولة ذرتين لchlor جايين على جهة واحدة ولا جايين
+
+33
+00:02:57,650 --> 00:03:01,770
+على جهتين متعاكستين صيرنا نضيف ال prefix أو
+
+34
+00:03:01,770 --> 00:03:08,130
+البادئة اللي هي cis وtrans فالcis وtrans هنا ما
+
+35
+00:03:08,130 --> 00:03:13,470
+بتعني مواقع الذرات مواقع الذرات حدد one two ع ذرة
+
+36
+00:03:13,470 --> 00:03:18,420
+واحد وع ذرة اتنينSame bonding, same name المركب
+
+37
+00:03:18,420 --> 00:03:22,420
+اسمه one two dichloroethane لكن الفرق ال
+
+38
+00:03:22,420 --> 00:03:28,600
+arrangement in space مع بعض و لا ضد بعض و عرفنا ان
+
+39
+00:03:28,600 --> 00:03:34,040
+احنا بنستعمل كلمة cess او الأعام منها z للتعبير عن
+
+40
+00:03:34,040 --> 00:03:40,260
+معنى مع بعض و ال transاو ايه؟ ضد بعض واضح هذا
+
+41
+00:03:40,260 --> 00:03:43,860
+الكلام؟ الان لما أخذنا ال sis و ال trans قولنا
+
+42
+00:03:43,860 --> 00:03:47,840
+هدوله نوع او احد انواع ال stereo isomers اللي
+
+43
+00:03:47,840 --> 00:03:52,700
+سمناهم ايش؟ they are stereomersالان شو يعني
+
+44
+00:03:52,700 --> 00:03:56,980
+diastereomers ال diastereomers ببساطة قلنا عنهم
+
+45
+00:03:56,980 --> 00:04:00,660
+non mirror image stereoisomers يعني stereoisomers
+
+46
+00:04:00,660 --> 00:04:04,820
+لو حطيت واحد جبال التاني و تخيلت انه في امرأة
+
+47
+00:04:04,820 --> 00:04:09,460
+بينهم بيكونوا مش صورة بعض في المرأة non mirror
+
+48
+00:04:09,460 --> 00:04:14,500
+image stereoisomers الان موضوعنا في هذا الفصل على
+
+49
+00:04:14,500 --> 00:04:19,930
+النوع التاني يعني كل الكلام اللي اتكلمتهمقدمة لكن
+
+50
+00:04:19,930 --> 00:04:24,570
+موضوعنا على النوع التاني اللي اسمه enantiomers
+
+51
+00:04:24,570 --> 00:04:28,750
+النوع التاني اللي اسمه enantiomers ال enantiomers
+
+52
+00:04:28,750 --> 00:04:34,970
+قبل ما تكون ظاهرة موجودة في الكيميا و في ال stereo
+
+53
+00:04:34,970 --> 00:04:40,530
+isomers هي ظاهرة موجودة في الحياة ربما من تبهينها
+
+54
+00:04:40,530 --> 00:04:46,580
+الناس او لأالله أعلم لكن لما نذكرها و نفهمها
+
+55
+00:04:46,580 --> 00:04:51,200
+بالحياة بعد هيك بنقدر نفهمها بالكيميا يعني اللي
+
+56
+00:04:51,200 --> 00:04:56,280
+بده يفهم إيش معناه in and sumars بدوش يظن أن هذه
+
+57
+00:04:56,280 --> 00:05:00,840
+الكلمة هي كلمة كيميائية لأ كلمة in and sumars هي
+
+58
+00:05:00,840 --> 00:05:06,840
+كلمة حياتية يعني ممكن في الامتحان أرسمه to in and
+
+59
+00:05:06,840 --> 00:05:12,620
+sumarsمن الحياة لا بد يبين فيها روابط ولا بد يبين
+
+60
+00:05:12,620 --> 00:05:17,300
+فيها ذرات ولا جزيئات ولا ما يحزنون ال enantiomers
+
+61
+00:05:17,300 --> 00:05:22,700
+ظاهرة حياتية ايش اصل هذه الظاهرة اصل هذه الظاهرة
+
+62
+00:05:22,700 --> 00:05:29,710
+تنطلق من الإيدينلحظوا الإيد اليمين والإيد الشمال،
+
+63
+00:05:29,710 --> 00:05:34,930
+لو أنا حطيت هدول الاتين بهذا الشكل أقبال بعض،
+
+64
+00:05:34,930 --> 00:05:40,900
+هلاحظ أن هدول الاتين صورت بعض في المرقاةواضح؟ يعني
+
+65
+00:05:40,900 --> 00:05:44,920
+لو هنا في مراية بدل الإيد الشمال، إيش اللي هيبين
+
+66
+00:05:44,920 --> 00:05:49,960
+فيها؟ نفس هذه، لو كنت حاطط لشمال، لو في مراية، إيش
+
+67
+00:05:49,960 --> 00:05:54,160
+هيبين فيها نفس هذه؟ الآن صورة المرأة اللي احنا
+
+68
+00:05:54,160 --> 00:06:01,510
+سمناها mirror image سابقاإيش بتمتاز؟ إن كل نقطة
+
+69
+00:06:01,510 --> 00:06:06,910
+فيها عكس التاني عكس الأصل يعني أنا لما بحط الإيد
+
+70
+00:06:06,910 --> 00:06:12,290
+اتطلع على الكف اللي موجود عنده بأي اتجاه؟ بهذا
+
+71
+00:06:12,290 --> 00:06:17,830
+الاتجاه واضح؟ الآن هذا صورته في المرأة لوين؟
+
+72
+00:06:17,830 --> 00:06:21,710
+بالاتجاه المعاكس ولذلك لما الإنسان نفسه كمان بيقف
+
+73
+00:06:21,710 --> 00:06:27,710
+قدام المراية بشوف صورتهمعنى ذلك إن كل ما في المرأة
+
+74
+00:06:27,710 --> 00:06:32,450
+عكس الوضع اللي هو واقف الإنسان فيه، واضح؟ الآن إنه
+
+75
+00:06:32,450 --> 00:06:36,330
+ملقتين mirror image هذا أمر طبيعي، لأ وأمر طبيعي
+
+76
+00:06:36,330 --> 00:06:41,770
+أكثر إن كل شيء في الدنيا كل شيء في الدنيا له
+
+77
+00:06:41,770 --> 00:06:45,850
+mirror image، يعني هذا مش موضوع خلافي إطلاقا، يعني
+
+78
+00:06:45,850 --> 00:06:52,470
+لو جيبنا قدام المرايا حجرأو كرة أو أرنب أو بني آدم
+
+79
+00:06:52,470 --> 00:06:58,710
+أو ملك أو فقير وقفناه قدام المراية له mirror image
+
+80
+00:06:58,710 --> 00:07:03,470
+يعني بنقدر نصيغي الكلام for every object there is
+
+81
+00:07:03,470 --> 00:07:07,530
+a mirror imageكل جسم في الدنيا له mirror image
+
+82
+00:07:07,530 --> 00:07:11,890
+تمام؟ إذا بيصير وين الجديد؟ إذا كل إشي في الدنيا
+
+83
+00:07:11,890 --> 00:07:16,770
+له mirror image الآن بيجي الشيء الجديد اللي بينبني
+
+84
+00:07:16,770 --> 00:07:21,670
+عليه فهمنا لهذا ال chapter هل يا تورا الصورة في
+
+85
+00:07:21,670 --> 00:07:27,490
+المرآة تنطبق على الأصل ولا لأ؟يعني لو أنا إجيت
+
+86
+00:07:27,490 --> 00:07:32,170
+قولت ال .. ال tail هدولة they are mirror images هل
+
+87
+00:07:32,170 --> 00:07:37,430
+يا ترى هذه الإيد بتنطبق على هذه الإيد ولا لأ؟ معنى
+
+88
+00:07:37,430 --> 00:07:45,030
+تنطبق على super imposible super imposible
+
+89
+00:07:46,690 --> 00:07:51,710
+واضح؟ هل يا تورا الإيد اليمين و الإيد الشمال
+
+90
+00:07:51,710 --> 00:07:56,250
+بينطبقوا على بعض من بعض ولا لأ؟ إيش إنتوا رأيكم من
+
+91
+00:07:56,250 --> 00:08:03,770
+خبرتكوا الحياتية؟ كويس، الآن لاحظوا الشعب
+
+92
+00:08:03,770 --> 00:08:12,170
+الفلسطيني لأنه عاش طفولة صعبةلم يقدر له أن يستمتع
+
+93
+00:08:12,170 --> 00:08:19,410
+بطفولته ولذلك لم يستطع أن يجيب على سؤال بسيط مثل
+
+94
+00:08:19,410 --> 00:08:29,270
+هذا السؤال لو استمتعتنا بطفولتي كنا لعرفتنا إيش
+
+95
+00:08:29,270 --> 00:08:34,350
+أنه لما بنيجي نركب العروسة الصغيرة إلها التين
+
+96
+00:08:34,350 --> 00:08:40,380
+ماقدرش أحط هذه محل هذهالعروسة الصغيرة معمولة بتنفك
+
+97
+00:08:40,380 --> 00:08:44,940
+الاتين والرجلتين ولا لأ؟ لما بتيجوا تركبوها هذه
+
+98
+00:08:44,940 --> 00:08:48,220
+العروسة الصغيرة جسم اللي بيلعبوا فيها الأطفال
+
+99
+00:08:48,220 --> 00:08:53,900
+ويلها إيد وإيد ورجل ورجل هل يا تورا عمركوا جربتوا
+
+100
+00:08:53,900 --> 00:08:58,300
+وهي مفكوكة تركبوها تاني؟ هل بتيجي الإيد لشمال محل
+
+101
+00:08:58,300 --> 00:09:03,130
+اليمين؟ لأبالتأكيد لأ بنعكس الأصبع الآن تخيلوا أن
+
+102
+00:09:03,130 --> 00:09:06,950
+هذه الإيد اللي عندى اليمين لو أنا بدأ أحط الشمال
+
+103
+00:09:06,950 --> 00:09:10,790
+مكانها تماما و الكف لجوه بده يكون هاي بدأ أجيب
+
+104
+00:09:10,790 --> 00:09:15,270
+الشمال لحظوا هذا الأصبع وين رايح هذا الأصبع وين
+
+105
+00:09:15,270 --> 00:09:20,310
+رايح ولذلك لا يمكن لو إجيتوا تركبوا الرجلين محال
+
+106
+00:09:20,310 --> 00:09:26,130
+بعض هتلاحظوا أن رجل للأمام و رجل للخلف فالاتين
+
+107
+00:09:27,470 --> 00:09:31,670
+و كل كوا عندكم لسه ما زال من بقايا الطفولة شيء على
+
+108
+00:09:31,670 --> 00:09:38,280
+أرض الواقع أو في الذاكرة فجربوا .. فجربواالان ..
+
+109
+00:09:38,280 --> 00:09:43,500
+هذه الان بتصبح أساس لظاهرة .. بتصبح أساس لظاهرة
+
+110
+00:09:43,500 --> 00:09:50,020
+أنه في أحيانا الصورة في المرأة و الأصل يكونوا غير
+
+111
+00:09:50,020 --> 00:09:54,020
+متطابقين طبعا ممكن الصورة و الأصل تكون متطابقة
+
+112
+00:09:54,020 --> 00:10:00,380
+يعني لو إنسان مثلا جاب هذا القلمحطه هنا الصورة
+
+113
+00:10:00,380 --> 00:10:05,560
+تبعته جلم تاني هذه صورة هذا أصل ينطبق على بعض لو
+
+114
+00:10:05,560 --> 00:10:12,020
+الإنسان جاب كرةأيه كويس؟ حطها أمام المرآة، شو
+
+115
+00:10:12,020 --> 00:10:16,820
+هيشوف؟ كرة، الكورتين ينطبقوا مكان بعض، بمعنى آخر
+
+116
+00:10:16,820 --> 00:10:21,020
+لو كان فيه قالب محطوطة في الكورة هذه و قالب محطوطة
+
+117
+00:10:21,020 --> 00:10:23,800
+في الكورة الثانية، بقدر أحط هذه محل هذه و بقدر أحط
+
+118
+00:10:23,800 --> 00:10:29,000
+هذه محل هذه، لكن تخيلوا معي لو كان الإنسان بيشتري
+
+119
+00:10:29,000 --> 00:10:33,660
+عروسة صغيرة اللي بيلعبوا فيها، والاتنين محطوطين في
+
+120
+00:10:33,660 --> 00:10:39,730
+الجالب الكلكل المفحورهذه للإيد اليمين مفحورة جوا،
+
+121
+00:10:39,730 --> 00:10:44,410
+هذه للإيد التانية أرفع هذه الإيد، بيقدر يحط هذه
+
+122
+00:10:44,410 --> 00:10:48,690
+مكانها؟ مش ممكن، لحظوا هذه الفحر وين الأصبع جاي
+
+123
+00:10:48,690 --> 00:10:52,810
+فيها؟ بهذا الاتجاه، طبعا ما تحطوهاش بالعكس، معنى
+
+124
+00:10:52,810 --> 00:10:57,630
+التطابق أن كل نقطة تنطبق محل إيش؟ التانية، واضح؟
+
+125
+00:10:57,630 --> 00:11:02,060
+هل بنقدر نحط هذه محل هذه؟بنقدرش نحطهم محال بعض
+
+126
+00:11:02,060 --> 00:11:08,400
+الان هذه الظاهرة .. هذه الظاهرة لأنها أساس لأشياء
+
+127
+00:11:08,400 --> 00:11:12,980
+كتيرة أعطوها اسم في الكيميا سموها ظاهرة ايش ال
+
+128
+00:11:12,980 --> 00:11:21,380
+handedness ظاهرة ال handedness ظاهرة ال handedness
+
+129
+00:11:21,380 --> 00:11:28,200
+اللي هي عدم تطابق الأصل مع الصورة الان لو بدنا
+
+130
+00:11:28,200 --> 00:11:35,620
+أنصيهاباللغة الإنقليزية بدنا نقول بيكون عند non
+
+131
+00:11:35,620 --> 00:11:40,020
+-superimposable mirror image stereoisomers لاحظوا
+
+132
+00:11:40,020 --> 00:11:44,500
+معي non-superimposable غير متطابق non
+
+133
+00:11:44,500 --> 00:11:47,720
+-superimposable mirror image stereoisomers يعني
+
+134
+00:11:47,720 --> 00:11:53,760
+صور في المرأة غير متطابقة الأصل والصورة ايش ماله
+
+135
+00:11:53,760 --> 00:11:57,520
+غير متطابق non-superimposable غير متطابق mirror
+
+136
+00:11:57,520 --> 00:12:04,920
+imageصورة مع الأصل واضح الصورة لا تنطبق على الأصل
+
+137
+00:12:04,920 --> 00:12:12,060
+الان كل ما كان مثل الإيدين بنطبق عليه الظاهرة الان
+
+138
+00:12:12,060 --> 00:12:16,500
+كل شغلتين مثل الإيدين اعطوهم اسم سموهم enantiomers
+
+139
+00:12:16,500 --> 00:12:23,690
+فالاتين enantiomersواضح؟ فعلاقة الانانشومارز بلغة
+
+140
+00:12:23,690 --> 00:12:29,710
+بسيطة هي أصل وصورة في المرآة ولكنهم غير متطابقين
+
+141
+00:12:29,710 --> 00:12:33,790
+non superimposable mirror images أو mirror images
+
+142
+00:12:33,790 --> 00:12:40,350
+stereo isomers الآن أعطوني عد أمثلة من الحياة غير
+
+143
+00:12:40,350 --> 00:12:49,130
+الإتين الرجلتين صح الرجلتين برضه مش متطابقين وكمان
+
+144
+00:12:50,730 --> 00:12:54,870
+ابواب السيارة، لاحظوا لما بيخرب مثلا الباب الأمامي
+
+145
+00:12:54,870 --> 00:12:58,150
+في السيارة، الواحد بيروح باشتري باب، أول سؤال
+
+146
+00:12:58,150 --> 00:13:04,330
+بينسأله من البيبيع، بدك الباب شمال ولا يمين؟
+
+147
+00:13:04,330 --> 00:13:09,790
+كمان، إمريتين السيارة، الإمريات اللي على الجانب،
+
+148
+00:13:09,790 --> 00:13:12,870
+بيركبوا، في واحدة شمال، في واحدة يمين، مابيجيوش
+
+149
+00:13:12,870 --> 00:13:17,150
+التنتين محال بعض، كمان، لودان
+
+150
+00:13:18,370 --> 00:13:24,490
+واضح؟ كمان إذا شلحت هذه النضارة تخيلوا لو انت جزء
+
+151
+00:13:24,490 --> 00:13:29,200
+منكم درس بصريات طبية انت علوم صحة الآن صح؟هذه
+
+152
+00:13:29,200 --> 00:13:36,180
+النضارة مفكوكة هيكون عنده إيد و إيد و عدسة و عدسة
+
+153
+00:13:36,180 --> 00:13:41,000
+و هذا الجسم الصغير إله اسم انتعون النضارات تمام لو
+
+154
+00:13:41,000 --> 00:13:45,820
+فكتوهم و إجيتوا تركبوهم يعني بس بمفك صغير اشتغلتوا
+
+155
+00:13:45,820 --> 00:13:49,160
+على هذه النضارة هيصير عندكم من هذه قطعتين من هذه
+
+156
+00:13:49,160 --> 00:13:54,780
+قطعتين من هذه قطعتين تعالوا ركبوهم لو جربتوا تحطوا
+
+157
+00:13:54,780 --> 00:14:01,140
+هذه محل هذه و تركبوهم صح تطلع هذه لفوقواضح؟ و هاد
+
+158
+00:14:01,140 --> 00:14:04,600
+هتطلع على فوق، مش هيظبطه، لو جربتوا تحطوا العدسة
+
+159
+00:14:04,600 --> 00:14:08,580
+محل العدسة، مش هيظبط، لو جربتوا هاد محل هاد، مش
+
+160
+00:14:08,580 --> 00:14:13,400
+هيظبط، إذا كل هدولة، رغم إن أنا لو حطيت مرقابي هذا
+
+161
+00:14:13,400 --> 00:14:19,480
+الشكل، هذا الجزء و هذا الجزء، إيش معلهم؟صورة بعض
+
+162
+00:14:19,480 --> 00:14:23,660
+في المرأة صحيح صورة بعض في المرأة ولكنها غير
+
+163
+00:14:23,660 --> 00:14:28,820
+متطابقة إذا كل مكونات النضارة بيخضعوا لظاهرة إيش
+
+164
+00:14:28,820 --> 00:14:32,500
+ال handedness ال handedness كل مكونات النضارة in
+
+165
+00:14:32,500 --> 00:14:36,300
+anchomers يعني لو أنا جبتلكوا في الامتحان صورة إيد
+
+166
+00:14:36,300 --> 00:14:39,240
+النضارة هذه والإيد التانية وقلتلكوا ما العلاقة
+
+167
+00:14:39,240 --> 00:14:43,750
+بينهم بتقولولي they are anchomersواضح؟ they are
+
+168
+00:14:43,750 --> 00:14:49,850
+enantiomers الأحذية شو رأيكم فيهم؟ لاحظوا فكرة
+
+169
+00:14:49,850 --> 00:14:53,750
+الأحذية فكرة يعني مهمة عارفين ليش؟ لأن ال
+
+170
+00:14:53,750 --> 00:14:58,670
+enantiomers ببساطة للوهلة الأولى صعب أنكم تتميزوهم
+
+171
+00:14:58,670 --> 00:15:01,630
+وممكن تغلطوا فيهم أول ما بدنا أن تغلطوا في
+
+172
+00:15:01,630 --> 00:15:07,430
+الإيدين، مظبوط ولا لأ؟ الآن في المستقبل سواء
+
+173
+00:15:07,430 --> 00:15:10,750
+قابلته أو قابته
+
+174
+00:15:12,820 --> 00:15:17,720
+هتلاحظوا انه عشان الطفل الصغير اول ما بيبدأ يستعمل
+
+175
+00:15:17,720 --> 00:15:22,320
+الحذاء يفهم هذه الظاهرة بتضله حوالي اربع خمس ست
+
+176
+00:15:22,320 --> 00:15:24,540
+سنين لما هو بيجي يلبس الحذاء و انتوا قاعدينه
+
+177
+00:15:24,540 --> 00:15:28,600
+تقولوله شماله يمين طب هم اذا كانوا نفس الاشي ليش
+
+178
+00:15:28,600 --> 00:15:31,940
+مغلبين حالكوا و منشفين ريجها الطفل الصغير و
+
+179
+00:15:31,940 --> 00:15:39,080
+بتقولوله شماله يمين مؤمن الغلطان الطفل ولا انتوا
+
+180
+00:15:41,020 --> 00:15:45,120
+احنا بدنا نفهم الطفل لما بيجي بيلبس الحذاء مش ليه
+
+181
+00:15:45,120 --> 00:15:48,400
+لنهار الأب و الأم لأ هذي شمال، هذي يمين أول ما
+
+182
+00:15:48,400 --> 00:15:54,440
+بيبدأ؟ إذا عندكم قناعة أنه هذي و هذي مابيجوش مع
+
+183
+00:15:54,440 --> 00:16:02,740
+بعض، واضح؟ إذا الأحذية انان شمارز، الأحذية انان
+
+184
+00:16:02,740 --> 00:16:08,160
+شمارز أيضا، والجوارب انان شمارز، والشاطر اللي
+
+185
+00:16:08,160 --> 00:16:15,450
+بيعرف إيشيلبسهم صحي الظاهرة اشمالها كبيرة لاحظوا
+
+186
+00:16:15,450 --> 00:16:21,210
+معي وين بيبين اكثر اشي وين بيبين اكثر اشي ال
+
+187
+00:16:21,210 --> 00:16:26,970
+enantiomers عارفين وين لما ييجوا ال enantiomers
+
+188
+00:16:26,970 --> 00:16:31,430
+يتعاملوا مع enantiomers تاني وهذه فكرة كتير اساسية
+
+189
+00:16:31,430 --> 00:16:36,720
+في الكيميا يعني انتوا قلتوا القدمينEnhance
+
+190
+00:16:36,720 --> 00:16:40,440
+Shoemers يعني القدم اليمين و القدم الشمال صورة بعض
+
+191
+00:16:40,440 --> 00:16:44,960
+في المرأة ولكنها غير متطابقة صح ولا لأ؟ و الحذائن
+
+192
+00:16:44,960 --> 00:16:50,580
+Enhance Shoemers الآن أن الحذائن ممكن يستعملوا
+
+193
+00:16:50,580 --> 00:16:56,460
+استعمالات كتيرة مايفرجوش نهائيا يعني لو افترضنا
+
+194
+00:16:56,460 --> 00:17:01,100
+إنسان مثلا بيشتري خردة على الميزان بلاستيك عشان
+
+195
+00:17:01,100 --> 00:17:06,100
+يعملوا recyclingبيفرج معه إن هذا شمال ولا هذا
+
+196
+00:17:06,100 --> 00:17:13,800
+يمين؟ لأ، مظبوط ولا لأ؟ لو افترضنا إن إنسان بده
+
+197
+00:17:13,800 --> 00:17:20,440
+يستعمل الحذاء ليضرب به أعداء الله، صارت في
+
+198
+00:17:20,440 --> 00:17:25,440
+التاريخ، بيفرج معه إنه شمال ولا يمين؟ ولا جنب
+
+199
+00:17:25,440 --> 00:17:31,260
+الواجب؟جانب الواجب طيب السؤال عاد لو افترضنا انه
+
+200
+00:17:31,260 --> 00:17:36,480
+انسان بده يحط الرجلتين في الحذائل بيفرق معه ولا
+
+201
+00:17:36,480 --> 00:17:42,120
+لأ؟ وين افرقت؟ لما جبت انان شومارز مع انان شومارز
+
+202
+00:17:42,120 --> 00:17:45,960
+هذا الكلام بعد شوية وين هيجي يفرق معكم؟ لما ابدأ
+
+203
+00:17:45,960 --> 00:17:53,100
+انا اقول ان الجسم في أشياء مواد مستقبلات موجود
+
+204
+00:17:53,100 --> 00:17:59,210
+منها اتنينو الدواء موجود منه اتنين الان اذا اللي
+
+205
+00:17:59,210 --> 00:18:02,510
+في الجسم واحد هيجي على التنين اللي في الدواء اللي
+
+206
+00:18:02,510 --> 00:18:08,570
+هيتفق مع واحد و يختلف مع التاني هيكون اكثر تطبيق
+
+207
+00:18:08,570 --> 00:18:14,470
+لهذه المنطقة في ال biological system في الجسم لانه
+
+208
+00:18:14,470 --> 00:18:18,570
+هتبدو تلاحظوا ان الجزيئات الانزمات الكذا في منها
+
+209
+00:18:18,570 --> 00:18:23,390
+اتنينإنانشومارز والأدوية في منها إنانشومارز الآن
+
+210
+00:18:23,390 --> 00:18:28,790
+أي إنانشومارز أعطيه عشان يتفق مع اللي في الجسم هنا
+
+211
+00:18:28,790 --> 00:18:35,610
+بيصير إيش؟ بيصير الانتباه وأول ما الناس بتبدأ تغلط
+
+212
+00:18:35,610 --> 00:18:44,340
+مباشرة بتعمل إيش؟ مشكلة وصارت مشاكلضخمة جدا بل
+
+213
+00:18:44,340 --> 00:18:51,440
+مقاسي خليني في الأول أفرجيكم خلال فترة صغيرة كيف
+
+214
+00:18:51,440 --> 00:18:54,160
+هذه الظاهرة نفسها اللي قلنا ربع ساعة بنحكي عنها في
+
+215
+00:18:54,160 --> 00:18:57,900
+الحياة يمكن أن توجد في الكيميا وبعدين بنفرجيكم
+
+216
+00:18:57,900 --> 00:19:02,360
+المقاسي اللي موجودة من الخطأ في هذه الظاهرة في
+
+217
+00:19:02,360 --> 00:19:07,550
+المجال الطبي وغيرهالان هذه الظاهرة في الكيميا
+
+218
+00:19:07,550 --> 00:19:14,470
+بتوجد إذا كان في عندي جزيء في ذرة carbon تحمل أربع
+
+219
+00:19:14,470 --> 00:19:20,190
+مجموعات مختلفة واضح؟ يعني شرطها أن توجد carbon،
+
+220
+00:19:20,190 --> 00:19:25,730
+هاي ال carbon عندي تحمل كام مجموعة مختلفة؟ تحمل
+
+221
+00:19:25,730 --> 00:19:30,790
+أربع مجموعات مختلفة إذا وجدت، بعمل جزيء و صورته
+
+222
+00:19:30,790 --> 00:19:36,140
+خليني أتخيل، هاي carbonوبدي اعمل تحمل اربع مجموعات
+
+223
+00:19:36,140 --> 00:19:41,300
+مختلفة الان شايفينها بالالوان ولا لأ عشان نسهل على
+
+224
+00:19:41,300 --> 00:19:45,720
+حالنا و نفهم الموضوع ببساطة خليني اتخيل ان هذا
+
+225
+00:19:45,720 --> 00:19:52,200
+الكربون بتحمل يود ايش لون اليود في الدنيا ازرق و
+
+226
+00:19:52,200 --> 00:20:00,660
+كلور اخضر اخضر مصفر مظبوط ولا لأ و برومأحمر
+
+227
+00:20:00,660 --> 00:20:06,780
+بورتقالي أحمر بورتقالي إذا هذا الأزرق يود والأخضر
+
+228
+00:20:06,780 --> 00:20:11,920
+أكلور والأحمر إبروم اتخيلنا كأنا جزء الآن وهذا
+
+229
+00:20:11,920 --> 00:20:17,620
+هيدروجين طب الآن لو قلت لواحدة لو سمحت سمينا
+
+230
+00:20:17,620 --> 00:20:25,820
+المركب هذا اللي أنا ماسكه بإيدي شو هتسميه ذرد
+
+231
+00:20:25,820 --> 00:20:33,810
+كاربون واحدة بسرعةميتين؟ شو بتحمل؟مافيش غير الواحد
+
+232
+00:20:33,810 --> 00:20:41,350
+ما تقولوهوش إبرومو كلورو أيودو ميثيل و بنذكرهم
+
+233
+00:20:41,350 --> 00:20:45,530
+alphabetical مش هذي الف باقي التسمية يعني هذا
+
+234
+00:20:45,530 --> 00:20:50,690
+الجزيء لما تجيب الكياشو اسمه إبرومو كلورو أيودو
+
+235
+00:20:50,690 --> 00:20:55,550
+ميثيل في مشكلة لحد الآن؟ الآن لو عملت صورته في
+
+236
+00:20:55,550 --> 00:21:00,330
+المرقاة يعني مسكته زي هيك و جيبت كمان إبرومو
+
+237
+00:21:00,330 --> 00:21:01,170
+هيدروجيل
+
+238
+00:21:04,280 --> 00:21:09,440
+وعملت انتبهوا معي هدول التنين تماما صورة بعض في
+
+239
+00:21:09,440 --> 00:21:16,020
+المرأة ولا لأ واضح صورة بعض في المرأة مية في المية
+
+240
+00:21:16,020 --> 00:21:20,260
+طب لو قولنا له ده سميناها ده ده سميناها انت سميها
+
+241
+00:21:20,260 --> 00:21:21,320
+ده
+
+242
+00:21:26,260 --> 00:21:29,560
+برومو، كلورو، ايود وميثين برومو، كلورو، ايود
+
+243
+00:21:29,560 --> 00:21:33,660
+وميثين لاحظوا معي إجت الجملة العامة في تعريف ال
+
+244
+00:21:33,660 --> 00:21:36,900
+stereo isomers they have the same bonding يعني لو
+
+245
+00:21:36,900 --> 00:21:39,800
+واحدة هنا بتوصف هذا الجزء و واحدة هنا بتوصف هذا
+
+246
+00:21:39,800 --> 00:21:43,880
+الجزء هتقول carbon متصل في برومو، كلورو، يودو،
+
+247
+00:21:43,880 --> 00:21:48,490
+هيدروجين و اللي هناcarbon متصل فيه برومو كلورو
+
+248
+00:21:48,490 --> 00:21:53,250
+يودو هيدروجين اذا same bonding ولا لأ الان يا تورا
+
+249
+00:21:53,250 --> 00:21:57,550
+لو سألنا نفسنا السؤال هدول بينطبقوا على بعض ولا لأ
+
+250
+00:22:01,090 --> 00:22:08,270
+الخمسة درّات بدهم يجوا فوق بعض، الخمسة و لا في جنس
+
+251
+00:22:08,270 --> 00:22:11,130
+ال resonance، هذا وين ال resonance اللي فيه؟ ال
+
+252
+00:22:11,130 --> 00:22:15,270
+resonance حركة إلكترونات مافي أي resonance إطلاقا
+
+253
+00:22:16,410 --> 00:22:21,330
+الان معناه الانطباق انهم الخمس ذرات يجوا على بعض
+
+254
+00:22:21,330 --> 00:22:25,870
+خليني اجرب بده احط الكربون على الكربون زي هيك
+
+255
+00:22:25,870 --> 00:22:29,770
+خليني اجرب الان لاحظوا هاي الكربون اجت على الكربون
+
+256
+00:22:29,770 --> 00:22:39,510
+الكلور الهيدروجين اليو دولبروم شمالهم بالعكس اذا
+
+257
+00:22:39,510 --> 00:22:43,530
+لان مشكلتي باليو دولبروم بصلحها خليني اظبط اليو
+
+258
+00:22:43,530 --> 00:22:51,020
+دولبرومهيدروجين و هيدروجين هدولة
+
+259
+00:22:51,020 --> 00:22:54,220
+انطبقوا على بعض هدولة انطبقوا على بعض هدولة
+
+260
+00:22:54,220 --> 00:22:58,400
+انطبقوا على بعض صح؟ الان هدولة تنتيل كلورو
+
+261
+00:22:58,400 --> 00:23:06,920
+هيدروجين كلورو هيدروجين بينطبقوا؟ لا بينطبقواتمام؟
+
+262
+00:23:06,920 --> 00:23:11,060
+لو أعطناكم ياهم homework في البيت، هدول الجزيئين،
+
+263
+00:23:11,060 --> 00:23:15,780
+ضلينا نقولكوا معاكم عشر سنين، خليهم ينطبقوا على
+
+264
+00:23:15,780 --> 00:23:22,450
+بعض، لا ينطبقواواضح؟ إذا بدأت أكسر رابطتين و
+
+265
+00:23:22,450 --> 00:23:26,490
+أبدلهم هيصيروا نفس الجزء، هيبطلوا صورة بعض في
+
+266
+00:23:26,490 --> 00:23:31,370
+المرآة، هيصيروا نفس الجزء، واضح؟ لكن طالما هم صورة
+
+267
+00:23:31,370 --> 00:23:36,330
+بعض في المرآة، فغير متطابقين، إذا هذول أول مثال في
+
+268
+00:23:36,330 --> 00:23:40,110
+الكيميا على ال enantiomers و ال enantiomers بتوجد
+
+269
+00:23:40,110 --> 00:23:45,670
+لما يكون عند ذرة carbon تحمل أربع مجموعات مختلفة
+
+270
+00:23:46,540 --> 00:23:51,900
+واضح؟ إذا متى تصبح هذه الظاهرة موجودة في الكيمياء؟
+
+271
+00:23:51,900 --> 00:23:55,460
+إذا وجد عندي ذرّة كاربون تحمل أربع مجموعات مختلفة
+
+272
+00:23:55,460 --> 00:24:01,160
+الآن هذه الكاربون بنسميها كايرالكاربون إيش
+
+273
+00:24:01,160 --> 00:24:12,080
+بنسميها؟ كايرالكاربون أو stereogenic center أو
+
+274
+00:24:12,080 --> 00:24:19,630
+أحيانا كايرالسنتريعني هو يا مركز المشكلة أو مركز
+
+275
+00:24:19,630 --> 00:24:23,410
+الـ Stereochemistry بأي من هذه الأسماء شفتوها سواء
+
+276
+00:24:23,410 --> 00:24:26,910
+شفتوها chiral carbon أو chiral center أو
+
+277
+00:24:26,910 --> 00:24:33,290
+stereogenic center الفكرة فيها أن الكربون تحمل
+
+278
+00:24:33,290 --> 00:24:39,000
+أربع مجموعات مختلفةلحظة أنا بحبش أني أتعبكم في
+
+279
+00:24:39,000 --> 00:24:42,180
+صياغات لغوية the carbon carries four different
+
+280
+00:24:42,180 --> 00:24:46,780
+groups البفروض بس تفهموا كلمة إيش أربعة و بعدين زي
+
+281
+00:24:46,780 --> 00:24:51,340
+ما بيقول الشاعر و بكل لغات الأرض عبروا عنها المهم
+
+282
+00:24:51,340 --> 00:24:57,180
+إيش ذرة الكربون تحمل أربع مجموعات مختلفة فبصير
+
+283
+00:24:57,180 --> 00:25:02,620
+الشكل و صورته في المرأة غير متطابقين في هذه الحالة
+
+284
+00:25:02,620 --> 00:25:11,710
+صاروا إيشانانشومارز بدنا نميزهم عن بعض الان كل شيء
+
+285
+00:25:11,710 --> 00:25:18,910
+غير متطابق بلزم اننا ايش نميزه عن بعض بالمناسبة لو
+
+286
+00:25:18,910 --> 00:25:26,300
+انا سألت هذه ايش هتقولولي يدصح؟ وهذه يد، الان اليد
+
+287
+00:25:26,300 --> 00:25:33,880
+و اليد غير متطابقات، ايش ضفتلهم؟ كلمة يمنا و يسرا،
+
+288
+00:25:33,880 --> 00:25:40,110
+هذه عشان توضحهم بالفراغكيف بيجوا الان هذول
+
+289
+00:25:40,110 --> 00:25:47,090
+المركبين غير متطابقين اذا انا بحاجة لان اميزهم عن
+
+290
+00:25:47,090 --> 00:25:51,650
+بعضهم البعض يعني لو مجرد ان انا خربطته مع بعض كنت
+
+291
+00:25:51,650 --> 00:25:56,090
+حامل هذا المركب و خربطته مع بعض قلتلكوا اي مركب
+
+292
+00:25:56,090 --> 00:26:01,820
+كنت حامله باليمين و اي واحد بالاشمالهتعرفوه؟ اذا
+
+293
+00:26:01,820 --> 00:26:06,840
+لابد من طريقة لتمييزهم الان كيف بيميزوهم كيميائيا؟
+
+294
+00:26:06,840 --> 00:26:10,840
+بيقولوا تذكروا القواعد اللي أخدناها للأولويات في
+
+295
+00:26:10,840 --> 00:26:14,340
+المجموعات اللي أخدناها بالسلسة ال Trans ال يكان
+
+296
+00:26:14,340 --> 00:26:18,480
+انجلد بريلوج رولز اللي بتعتمد على ال atomic number
+
+297
+00:26:18,480 --> 00:26:21,500
+لما كنا نقول عند ال double bond مين أعلى؟ هذه ولا
+
+298
+00:26:21,500 --> 00:26:28,280
+هذه؟واضح الفكرة؟ الان صنف المجموعات اللى موجودة
+
+299
+00:26:28,280 --> 00:26:33,300
+حسب هذه القواعد من الأعلى للأقل في ال atomic
+
+300
+00:26:33,300 --> 00:26:39,320
+numbers الان تذكروا اللى عندي هيدروجين و كلور و
+
+301
+00:26:39,320 --> 00:26:45,440
+بروميود من أعلى واحدة؟بعدها البروم وبعدها الكلور
+
+302
+00:26:45,440 --> 00:26:49,400
+وبعدها الهيدروجين كلكوا متذكرين انه كان عنده ال
+
+303
+00:26:49,400 --> 00:26:53,300
+floriclor, البروم, اليود و الهيدروجين هان في
+
+304
+00:26:53,300 --> 00:26:55,880
+الجدول الدوري اذا اليود اعلى من البروم اعلى من
+
+305
+00:26:55,880 --> 00:27:00,760
+الكلور اعلى من الهيدروجين هذا في خلاف ولا لأ؟ لأ
+
+306
+00:27:00,760 --> 00:27:06,160
+الان بمسك الجزء بهذا الشكل بخلي المجموعة الأقل
+
+307
+00:27:06,160 --> 00:27:11,680
+الخلفالان انا هنا خلّيت المجموع الأقل للخلف منكم و
+
+308
+00:27:11,680 --> 00:27:16,840
+مني كمان ايش المجموع الأقل الهيدروجين خلوها للخلف
+
+309
+00:27:16,840 --> 00:27:28,460
+و اتحركوا من الأعلى للأقل للأقل واحدة تتحرك كيف
+
+310
+00:27:28,460 --> 00:27:35,820
+تكون الحركة مع قرب الساعة clockwise طب لو عملت
+
+311
+00:27:35,820 --> 00:27:41,800
+الكلام في الجزء التانييعني خلّيت أقل مجموعة
+
+312
+00:27:41,800 --> 00:27:49,780
+الهيدروجين للخلف و تحركوا يود .. عكس عقارة عكس
+
+313
+00:27:49,780 --> 00:27:58,660
+عقارة بالساعة صار في فرق بين التلات كيف؟
+
+314
+00:28:03,590 --> 00:28:11,830
+الان صار المطلوب يهدى ان هذا الجزء ابرومو كلورو
+
+315
+00:28:11,830 --> 00:28:17,630
+ايودو ميثين اللى معه قريب الساعةاتبهي معاك و هذا
+
+316
+00:28:17,630 --> 00:28:23,730
+الجزء برومو كلورو ايودو ميثين اللي ضد عقارب الساعة
+
+317
+00:28:23,730 --> 00:28:28,010
+الان شوف الكيميائيين جداش لطيفين و محترمين و سهلين
+
+318
+00:28:28,010 --> 00:28:32,910
+بدل ما ييجي يقولك كبشة كلامها الجد اجبال الاسم
+
+319
+00:28:32,910 --> 00:28:39,230
+اللي مع عقارب الساعة كام كلمة اربعة استبدالهم بحرف
+
+320
+00:28:39,230 --> 00:28:40,810
+جال اكتبله R
+
+321
+00:28:44,120 --> 00:28:50,200
+و هذا اللي ضد عقارب الساعة استبدله بحرف جال و
+
+322
+00:28:50,200 --> 00:28:54,280
+اكتبله S R
+
+323
+00:28:54,280 --> 00:29:03,400
+capital R و capital ايش S صار عندي R و S ال R
+
+324
+00:29:03,400 --> 00:29:10,200
+معناها clockwise و ال S counter clockwise
+
+325
+00:29:14,800 --> 00:29:20,020
+يعني مع و ضد عقارب الساعة هدول جايين من اللاتيني
+
+326
+00:29:20,020 --> 00:29:26,520
+rectus و sinister يعني أصل ال R من rectus
+
+327
+00:29:26,520 --> 00:29:31,380
+اللاتينية يعني يمين هيك مع عقارب و هذه sinister
+
+328
+00:29:31,380 --> 00:29:39,520
+يعني أصل الكلمة من إيش من اللاتيني الآن صار الإسم
+
+329
+00:29:39,520 --> 00:29:43,260
+الكامل لهذا لو جبته في الامتحان الإسم الكامل
+
+330
+00:29:43,260 --> 00:29:48,720
+الصحيحأي واحد في يوميك أخلطهم أخلطهم أنتوا مش
+
+331
+00:29:48,720 --> 00:29:52,640
+شايفين إشي و بعد ما خلطت و اتعبت قولتلها واحدة
+
+332
+00:29:52,640 --> 00:29:59,780
+سميلي هذا المركب طبعا هي عشان تاخد الأربع علامات
+
+333
+00:29:59,780 --> 00:30:02,460
+من خمسة في الأول بتجيب اسم الكيميا العادى
+
+334
+00:30:06,770 --> 00:30:09,690
+Ibromochloroiodomethane الان اخدت اربعة او تلاتة
+
+335
+00:30:09,690 --> 00:30:14,150
+من خمسة بعدين اربع مجموعات مختلفة اذا يجب مباشرة
+
+336
+00:30:14,150 --> 00:30:19,190
+انها تتحول على ال R و ال S اتطلع عليه سكنه اليود
+
+337
+00:30:19,190 --> 00:30:26,970
+Ibromichlor عكس اذا هذا صار اسمه الكامل S Ibrom و
+
+338
+00:30:26,970 --> 00:30:32,960
+هذا صار اسمه الكامل R فال S و ال Rهي بادئة لتوضيح
+
+339
+00:30:32,960 --> 00:30:37,800
+إيش؟ الشكل الفراغي تماما زي ما كان عندى في
+
+340
+00:30:37,800 --> 00:30:42,940
+الدياستيريو مارز إيش ال sis و ال trans و ال z و ال
+
+341
+00:30:42,940 --> 00:30:47,320
+E متذكرين لما احنا كنا نقول one two dichloroethane
+
+342
+00:30:47,320 --> 00:30:51,340
+و التاني نفس الاسم بدي أميزهم في الدياستيريو مارز
+
+343
+00:30:51,340 --> 00:31:00,320
+شو كنت بستعمل؟Sis و Trans او Z و E هذه البادئات
+
+344
+00:31:00,320 --> 00:31:07,340
+ايش بتوضح ليه؟ شكل فراغي الان في الانانشو مارز ROS
+
+345
+00:31:07,340 --> 00:31:14,980
+واضح؟ في الانانشو مارز ROS شوية في ال biochemistry
+
+346
+00:31:14,980 --> 00:31:18,900
+هيستعملوا مصطلحات تانية مبنية على نفس الفكرة
+
+347
+00:31:18,900 --> 00:31:21,180
+هتصيروا تشوفوا DOL
+
+348
+00:31:23,400 --> 00:31:28,660
+لما ابتصلوا لل biochemistry للبروتينات و الأشياء
+
+349
+00:31:28,660 --> 00:31:33,200
+اللي زي هيك هتلاحظوا و ال sugars بستعملوا D و L
+
+350
+00:31:33,200 --> 00:31:37,440
+بديل عن R و S تاريخيا لكن نفس الفكرة في حينه
+
+351
+00:31:37,440 --> 00:31:42,380
+بتدرسوها ف ال D و L أو ال R و ال S طبعا الأساس
+
+352
+00:31:42,380 --> 00:31:46,990
+الأعم و الأشمل و الأصل في الكيميا اللي هو إيش؟الـR
+
+353
+00:31:46,990 --> 00:31:49,170
+والـS يعني دي والأول استعمالات شويه في ال
+
+354
+00:31:49,170 --> 00:31:53,710
+biochemistry الـR والـS يستعملوا لتمييز ال
+
+355
+00:31:53,710 --> 00:31:57,910
+enantiomers عن بعضها البعض والعملية البسيطة
+
+356
+00:31:57,910 --> 00:32:04,900
+المجموعة الأقل أين توجدللخلف المجموع الأقل للخلف
+
+357
+00:32:04,900 --> 00:32:10,660
+وباقي المجموعات بنتحرك فيها من الأعلى للأقل حسب
+
+358
+00:32:10,660 --> 00:32:14,420
+قواعد الأولويات اللي أخدناها لإي اسمها Ken Ingold
+
+359
+00:32:14,420 --> 00:32:19,760
+Prelog Rules وبالتالي يحدد المركب هل هو R أو هو
+
+360
+00:32:19,760 --> 00:32:25,260
+إيش S وإلى لقاء آخر
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/D9wF84ICB3s.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/D9wF84ICB3s.srt
new file mode 100644
index 0000000000000000000000000000000000000000..59cd7406eb91c586f8b3fe5fc0db695e00e9dd72
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/D9wF84ICB3s.srt
@@ -0,0 +1,1490 @@
+1
+00:00:19,640 --> 00:00:24,180
+بسم الله الرحمن الرحيم موضوعنا اليوم عن عائلة
+
+2
+00:00:24,180 --> 00:00:28,620
+كيميائية جديدة، مجموعة وظيفية جديدة، اللي هي ال
+
+3
+00:00:28,620 --> 00:00:34,460
+ethers. طبعاً على طول عدد كبير منكم هيتذكر أن ال
+
+4
+00:00:34,460 --> 00:00:40,460
+ethers اللي هم الصيغة العامة ROR، يعني Oxygen
+
+5
+00:00:40,460 --> 00:00:47,150
+محصورة بين ذرتين، أو Oxygen بين مجموعتين R، وكلكم
+
+6
+00:00:47,150 --> 00:00:53,550
+تذكرون أن الـOxygen رابطتين، وزوجين إيش؟ إلكترونات
+
+7
+00:00:53,550 --> 00:00:59,950
+ولذلك احنا، غير الـethers، مر علينا شغلتين أبسط من
+
+8
+00:00:59,950 --> 00:01:04,390
+الـethers، مر علينا شغلتين أبسط من الـethers، شو هم
+
+9
+00:01:04,390 --> 00:01:11,100
+الآن؟ مين يذكرنا فيهم؟ الماء والكحول. الآن الماء
+
+10
+00:01:11,100 --> 00:01:16,260
+أكسوجين أيضاً، والكحول أكسوجين، والـether برضه
+
+11
+00:01:16,260 --> 00:01:21,080
+ذرة أكسوجين، وزوجين إلكترونات. هدول ما فيش مفرّ
+
+12
+00:01:21,080 --> 00:01:31,320
+منهم. لكن الميه كانت H H، الكحول R وH، يعني مازال
+
+13
+00:01:31,320 --> 00:01:37,840
+فيه H، الـether R وR. الآن لاحظوا بمنطق الـhydrogen
+
+14
+00:01:37,840 --> 00:01:43,740
+bonding. الآن الميه تنتين hydrogen bonding، الكحول
+
+15
+00:01:43,740 --> 00:01:48,080
+من جهة واحدة بتقدر تعمل hydrogen bonding، الـether
+
+16
+00:01:48,080 --> 00:01:52,660
+ما فيه hydrogen bonding. وبناء على ذلك، الآن لو بدنا
+
+17
+00:01:52,660 --> 00:01:57,660
+نحكي بمنطق الـpolarity، من أعلى polarity فيهم الميه،
+
+18
+00:01:57,660 --> 00:02:02,080
+بعدها الكحول، بعدها الـether. الآن الـpolarity
+
+19
+00:02:02,080 --> 00:02:07,340
+مباشرة بتنعكس على إيش؟ على أي خاصية فيزيائية؟ على
+
+20
+00:02:07,340 --> 00:02:11,460
+درجة الغليان. ولذلك، على الضغط العادي، الميه درجة
+
+21
+00:02:11,460 --> 00:02:17,640
+غليانها 100، الكحول 78، الـether لو افترضنا إيثل و
+
+22
+00:02:17,640 --> 00:02:22,080
+إيثل حوالي 37.
+
+23
+00:02:23,430 --> 00:02:30,190
+لاحظوا كيف تناسب نقاط الغليان مع القطبية. ولو كان
+
+24
+00:02:30,190 --> 00:02:33,950
+الـether diethyl ether، يعني مثل، أو مثل، بيصير غاز
+
+25
+00:02:33,950 --> 00:02:38,930
+يعني درجة غليانه أقل بكثير. ولذلك، على حرارة الغرفة
+
+26
+00:02:38,930 --> 00:02:45,510
+بيغلي وخلص، وصار إيش؟ موجود على شكل غاز. الآن ربما من
+
+27
+00:02:45,510 --> 00:02:48,790
+أشهر الـether هذا الـether، الـethyl o ethyl اللي
+
+28
+00:02:48,790 --> 00:02:53,670
+هو الـdiethyl ether. واضح؟ ليش هذا يستعمل كـsolvent
+
+29
+00:02:53,670 --> 00:02:58,670
+، مدير سابقاً استعمل في التخدير، لما كانوا مثلاً
+
+30
+00:02:58,670 --> 00:03:01,850
+بيخدروا حيوانات صغيرة، بيعملوا تجارب في المختبرات
+
+31
+00:03:01,850 --> 00:03:06,930
+فالـether they have been used as anesthetics. الآن
+
+32
+00:03:06,930 --> 00:03:11,720
+لو بدنا ننسى هدول الأشياء اللي احنا سبق أننا
+
+33
+00:03:11,720 --> 00:03:17,820
+أخذناهم، ونضل مركزين حالنا في الـaethers، وهي
+
+34
+00:03:17,820 --> 00:03:22,980
+المثال عنهم اللي هو diethyl ether، وممكن نسميه
+
+35
+00:03:22,980 --> 00:03:26,540
+ethyl ether. يعني لو لغينا كلمة die، بمشي
+
+36
+00:03:26,540 --> 00:03:32,140
+يعني diethyl ether وethyl ether نفس الشيء. لاحظوا
+
+37
+00:03:32,140 --> 00:03:36,440
+لما بنقول من خواصه much less polar than alcohols،
+
+38
+00:03:37,210 --> 00:03:40,210
+الكلام صحيح ولا لأ؟ ما فيه hydrogen bonding
+
+39
+00:03:40,210 --> 00:03:44,130
+بالمرة. لما نقول من خواصه not soluble in water،
+
+40
+00:03:44,130 --> 00:03:49,430
+ما فيه solubility، لأن هذه alkyl groups كلها ما فيه
+
+41
+00:03:49,430 --> 00:03:52,510
+فيه hydrogen bonding اللي يصير polar وlike،
+
+42
+00:03:52,510 --> 00:03:56,730
+dissolves like، له lower melting point وboiling
+
+43
+00:03:56,730 --> 00:04:01,130
+point، أو boiling temperatures than alcohol. أكيد صح.
+
+44
+00:04:03,220 --> 00:04:08,200
+كمان بضيف عليه شغلة، chemically inert، يعني خامل
+
+45
+00:04:08,200 --> 00:04:14,940
+كيميائياً، تفاعلاته قليلة جداً. ولذلك، إن شاء الله بأمل
+
+46
+00:04:14,940 --> 00:04:18,900
+كل أمل أن نخلص كل الـchapter اليوم، لأنه لما نحكي
+
+47
+00:04:18,900 --> 00:04:21,560
+عن الـalkenes والـalkynes بنحكي على عشرين تفاعل، على
+
+48
+00:04:21,560 --> 00:04:28,180
+الـethers بنحكي على تفاعل واحد. واضح؟ لأنه ما فيه من
+
+49
+00:04:28,180 --> 00:04:32,340
+خلال MH ولا OH ولا C double bond O ولا double
+
+50
+00:04:32,340 --> 00:04:35,760
+bond. هذه المجموعات اللي بنسميها active groups اللي
+
+51
+00:04:35,760 --> 00:04:39,460
+بتحصل عليها تفاعلات كثيرة. هذا الكلام مش متوفر وين؟
+
+52
+00:04:39,460 --> 00:04:44,380
+في الـethers. يضاف إلى ذلك، all are very flammable،
+
+53
+00:04:45,250 --> 00:04:50,010
+يعني بيشتعلوا بشكل سريع جداً، زي بنزين السيارات و
+
+54
+00:04:50,010 --> 00:04:54,950
+وقود السيارات، أو ربما كمان أكثر. ولذلك، ادمجوا
+
+55
+00:04:54,950 --> 00:05:00,090
+الشغلتين مع بعض، أن هو له نقطة غليان منخفضة، يعني
+
+56
+00:05:00,090 --> 00:05:07,230
+بيتبخر بسهولة، وقابل للاشتعال بشكل كبير. واضح؟ ولذلك
+
+57
+00:05:07,230 --> 00:05:11,770
+يمثل خطر في المختبر. يعني نفترض أن حد عنده بنزين
+
+58
+00:05:11,770 --> 00:05:15,630
+burner مولعة هنا، وقاعد بيشتغل، وهنا فيه وعاء فيه
+
+59
+00:05:15,630 --> 00:05:19,610
+ether مفتوح. الـether نفسه بيتبخر، سبعة وثلاثين، احنا
+
+60
+00:05:19,610 --> 00:05:23,170
+مرات في غزة الحرارة سبعة وثلاثين، طبعاً هو بيتبخر
+
+61
+00:05:23,170 --> 00:05:27,030
+على كل الدرجات، وكل ما ارتفعت الحرارة بتزيد التبخر،
+
+62
+00:05:27,030 --> 00:05:32,020
+ولذلك ممكن، والـether هنا، وفجأة نلاقي مكان تاني، it
+
+63
+00:05:32,020 --> 00:05:36,000
+can catch fire، زي ما بيسموه، يعني ممكن يشتعل ويعمل
+
+64
+00:05:36,000 --> 00:05:41,060
+حريق. فالتعامل مع الـether بحاجة إلى حذر، لأنه
+
+65
+00:05:41,060 --> 00:05:46,440
+very flammable، وله نقطة غليان منخفضة، يعني بينوجد،
+
+66
+00:05:46,440 --> 00:05:51,500
+بيتبخر. واضح؟ تماماً زي التعامل مع وقود السيارات،
+
+67
+00:05:51,500 --> 00:05:56,240
+أو مع التنر. هذه المركبات الكيميائية بحاجة إلى نوع
+
+68
+00:05:56,240 --> 00:06:04,050
+من الحذر الشديد. الآن كيف بنسمي الـethers؟ فيه إنّا
+
+69
+00:06:04,050 --> 00:06:08,670
+نظامين للتسمية، نظام الشائع، الـcommon nomenclature،
+
+70
+00:06:08,670 --> 00:06:12,710
+إنّي أذكر المجموعات، ودائماً المجموعة بتأخذ
+
+71
+00:06:12,710 --> 00:06:17,990
+النهاية yl. مثل، مثل، مثل، مثل، مثل، مثل، مثل، مثل،
+
+72
+00:06:17,990 --> 00:06:20,470
+مثل، مثل، مثل، مثل، مثل، مثل، مثل، مثل، مثل، مثل،
+
+73
+00:06:20,470 --> 00:06:26,330
+مثل، مثل، مثل، مثل، مثل،
+
+74
+00:06:26,330 --> 00:06:26,970
+مثل، مثل، مثل، مثل، مثل، مثل، مثل، مثل، مثل، مثل، مثل،
+
+75
+00:06:26,970 --> 00:06:30,750
+مثل، مثل، مثل، مثل، مثل، بقول diethyl ether، وممكن
+
+76
+00:06:30,750 --> 00:06:35,210
+تلاقوها ethyl ether. يعني تختصر الـdie. مثل و مثل،
+
+77
+00:06:35,210 --> 00:06:41,030
+die، مثل ether. فنيل وفنيل، diphenyl ether. الآن، طب لو
+
+78
+00:06:41,030 --> 00:06:44,450
+كان هذا الـether، اللاحظه اللي زي بعض، المجموعتين
+
+79
+00:06:44,450 --> 00:06:48,110
+يعني نتخيله زي هيك، هي هذه الـoxygen، وهنا
+
+80
+00:06:48,110 --> 00:06:53,920
+المجموعتين زي بعض. هذا بنسميه symmetric ether، متماثل.
+
+81
+00:06:53,920 --> 00:06:59,700
+طب لو يختلفوا؟ unsymmetric ether. الآن، واجهت، أذكر
+
+82
+00:06:59,700 --> 00:07:04,840
+المجموعتين alphabetically. يعني ether فيه إيثل وميثل،
+
+83
+00:07:04,840 --> 00:07:13,080
+إيش هسميه؟ إيثل ميثل إيثر. آيزو بروبيل مثلاً، وtert-butyl،
+
+84
+00:07:14,280 --> 00:07:27,560
+tert-butyl isopropyl ether. 
+
+85
+00:07:27,560 --> 00:07:28,240
+tert-butyl isopropyl ether. tert-butyl isopropyl ether.
+
+86
+00:07:28,240 --> 00:07:33,600
+tert-butyl isopropyl ether. tert-butyl isopropyl ether.
+
+87
+00:07:39,540 --> 00:07:45,680
+بتكونوا تعجزوا. الـether معناه ذرة أكسجين، طالع
+
+88
+00:07:45,680 --> 00:07:49,940
+منها رابطة لكل واحد. لكن الشطارة في اللي بيكون حفظ
+
+89
+00:07:49,940 --> 00:07:57,840
+المجموعات. الآن، الـtertiary butyl carbon عليها ثلاثة،
+
+90
+00:07:57,840 --> 00:08:04,700
+ميثيل، أخذناها، والـisopropyl carbon CH متصلة باتنين
+
+91
+00:08:04,700 --> 00:08:11,280
+ميثيل، زي هيك. المحافظة على هذه الشغلة من الأول، هذا
+
+92
+00:08:11,280 --> 00:08:18,320
+المدلول. واضح؟ فهي tertiary butyl isopropyl ether. احنا
+
+93
+00:08:18,320 --> 00:08:22,560
+قلنا tert-butyl بنعملها على حرف الـB، هذا لما
+
+94
+00:08:22,560 --> 00:08:27,140
+شرحنا المجموعات. إذا شفنا كيف بنعمل الـethers كذلك،
+
+95
+00:08:27,140 --> 00:08:31,380
+الحالة، لو قلنا الـphenyl مثلاً، إيش بدنا نحط؟ البنزين
+
+96
+00:08:31,380 --> 00:08:32,300
+المخصوم منه،
+
+97
+00:08:42,010 --> 00:08:47,110
+وهذه أمثلة. dimethyl ether، إيثل ميثل إيثر، زي ما
+
+98
+00:08:47,110 --> 00:08:50,810
+قلت، مرات بيحطّهم مش مرتّبين alphabetically، لكن الأصح
+
+99
+00:08:50,810 --> 00:08:55,090
+تحطّهم alphabetically. يعني زي هذا الأصح تكتبوه، إيثل
+
+100
+00:08:55,090 --> 00:09:00,110
+ميثل إيثر. خلّو الـE قبل الـM. هذا الـether، هذه الـ
+
+101
+00:09:00,110 --> 00:09:07,410
+CH2Cl، اسمها chloromethyl، CH2Cl، chloromethyl، وهنا إيثل إيثل،
+
+102
+00:09:07,410 --> 00:09:15,930
+ethyl ether، وهكذا. هذه التسمية هي الـcommon
+
+103
+00:09:15,930 --> 00:09:21,070
+nomenclature. الآن لاحظوا معايا شرط هذه التسمية، شرط
+
+104
+00:09:21,070 --> 00:09:24,730
+هذه التسمية أن المجموعة اللي هان، واللي هان يكون
+
+105
+00:09:24,730 --> 00:09:28,010
+لهم أسماء معروفة بالنسبة لنا، والمجموعات اللي
+
+106
+00:09:28,010 --> 00:09:31,810
+أخذناها: إيثيل، ميثيل، إيثيل، بروبيل، آيزوبروبيل، تيرت
+
+107
+00:09:31,810 --> 00:09:38,800
+بيوتل، اخذناها. أنا بكلوروميثيل، بنزيل مثلاً، ب...أقل
+
+108
+00:09:38,800 --> 00:09:46,290
+الـether، لو قلنا لكم اعملوه، يعني شغلات إيش؟ معروفة
+
+109
+00:09:46,290 --> 00:09:51,030
+طيب، الآن لو المركب كبر، وفيه إيثر، إيثر معناه
+
+110
+00:09:51,030 --> 00:09:55,610
+أكسوجين بين كربونتين. واجهتها، بدي أرجع اسم المركب
+
+111
+00:09:55,610 --> 00:10:02,770
+كأنه الـalkane عادي. ابحث عن أطول سلسلة، أطول سلسلة
+
+112
+00:10:02,770 --> 00:10:08,310
+ثلاثة مركب، بروبين، أربعة بيوتين، خمسة بنتين وهكذا.
+
+113
+00:10:08,310 --> 00:10:13,780
+طيب، بعد ما أطول أطول سلسلة، يعني هاي هذا مركب، لاحظوا
+
+114
+00:10:13,780 --> 00:10:17,180
+هنا في carbon تنتين، ثلاثة لبروبل، وهنا carbon
+
+115
+00:10:17,180 --> 00:10:21,920
+واحدة. إيش أطول السلسلة؟ لبروبل. الآن، تخيل لو هذا
+
+116
+00:10:21,920 --> 00:10:26,580
+الأزرق اللي هنا كانت Cl، كلور، اللي على موقع واحد،
+
+117
+00:10:26,580 --> 00:10:33,420
+إيش هتسمّوه المركب؟ 1-chloropropane. بدّكوا تحدّدوا
+
+118
+00:10:33,420 --> 00:10:38,620
+الرقم. الآن اللي على موقع واحد مش كلور، أو ميثيل، أو
+
+119
+00:10:38,620 --> 00:10:40,780
+ميثيل اللي لها اسم methoxy،
+
+120
+00:10:43,660 --> 00:10:52,760
+ميثيل، methoxy. طب لو كانت إيثل؟ ethoxy. لو كانت بروبيل؟
+
+121
+00:10:52,760 --> 00:10:57,660
+propyl، propoxy.
+
+122
+00:10:57,660 --> 00:11:04,080
+ميثيل، ethoxy، ethyl،
+
+123
+00:11:04,080 --> 00:11:10,420
+phenoxy، phenyl، phenoxy.
+
+124
+00:11:13,650 --> 00:11:22,270
+isopropyl، أو isopropoxy.  tert-butyl، أو tert-butoxy، and so on. واضح؟
+
+125
+00:11:22,270 --> 00:11:27,350
+فبنطول أطول سلسلة، وبعدين المجموعات بنسميها، يعني
+
+126
+00:11:27,350 --> 00:11:31,190
+مثلاً هذا المركب، هاي كربون تنتين، أطول سلسلة، إذاً
+
+127
+00:11:31,190 --> 00:11:37,540
+المركب إيش؟ إيثان. على نمرة واحد إيش عليه؟ ميثوكسي.
+
+128
+00:11:37,540 --> 00:11:43,040
+methoxy، وإيش عليه كمان؟ كلور. إذاً هذا 1-chloro-1-methoxy
+
+129
+00:11:43,040 --> 00:11:49,840
+ethane. هاي هذا المركب، carbon 2 3 4، بيوتان.
+
+130
+00:11:49,840 --> 00:11:56,560
+على نمرة إثنين إيش عليه؟ ثلاثة ذرات ميثيل، propoxy.
+
+131
+00:11:56,560 --> 00:12:02,810
+propoxy، ثلاثة ذرات ميثيل. هذا المركب، لاحظوا، إيثانول الـ
+
+132
+00:12:02,810 --> 00:12:07,230
+alcohol أقوى من الـether. هنقول عنه 1، 2،
+
+133
+00:12:07,230 --> 00:12:12,330
+3، 4. إذا هذا أي مركب؟ 3-ethoxy-butan-1-ol، ضالّ على
+
+134
+00:12:12,330 --> 00:12:17,990
+نمرة ثلاثة، شو المجموعة اللي حملها؟ مش ethoxy، كلور و
+
+135
+00:12:17,990 --> 00:12:23,730
+ethoxy. تمام، حملة كلور. الآن الكلور هذه محمولة على
+
+136
+00:12:23,730 --> 00:12:27,510
+الكربون هذه ولا هذه؟ العلماء الـorganic بيحطّوها بين
+
+137
+00:12:27,510 --> 00:12:31,550
+قوسين، وبيقولوا الكلور على الكربون رقم إثنين. لاحظوا،
+
+138
+00:12:31,550 --> 00:12:36,490
+إثنين، يعني كأنه كل هذه انحطّت إيش؟ بين قوسين. صار كام؟
+
+139
+00:12:36,490 --> 00:12:40,410
+نظام ترقيم عندي. نظامين، النظام الأصلي 1، 2،
+
+140
+00:12:40,410 --> 00:12:43,890
+3، 4، وهنا الكلور، لو إجيت أنا بدي أقول 1’
+
+141
+00:12:43,890 --> 00:12:49,570
+chloroethoxy. لو إجيت هنا 2’ chloroethoxy. و مرات بتلاحظون، ممكن يختصرّوا الـprime، لكن
+
+142
+00:12:49,570 --> 00:12:52,890
+الأحسن إذا الإنسان استعمل أكثر من نظام ترقيم، أنه
+
+143
+00:12:52,890 --> 00:12:59,190
+يحطّ إيش؟ prime. واضح؟ هذه الفكرة بدي أركز معاكوا
+
+144
+00:12:59,190 --> 00:13:05,070
+عليها. فكرة أن الإنسان يستعمل أكثر من نظام ترقيم في
+
+145
+00:13:05,070 --> 00:13:12,140
+نفس المركب. خلّيني أعطيكوا عليها مثالين، عند
+
+146
+00:13:12,140 --> 00:13:15,980
+اللزوم، ممكن مثال من موضوعنا الـethers، ومثال من
+
+147
+00:13:15,980 --> 00:13:20,460
+موضوع الـalcohols ثاني. يعني الترقيم ممكن نستعمل أكثر من
+
+148
+00:13:20,460 --> 00:13:27,920
+نظام ترقيم. لو يا جماعة أعطيتكم المركب هذا، و
+
+149
+00:13:27,920 --> 00:13:35,300
+كتبت هنا OH، وكتبت هنا Z، وحطينا هنا Br، نفترض هذا
+
+150
+00:13:35,300 --> 00:13:44,270
+المركب، جاينا سمي المركب التالي. الآن هذا أفضل شيء
+
+151
+00:13:44,270 --> 00:13:50,710
+أسميه الkane. واضح؟ أطول سلسلة، وأطول سلسلة حاملة
+
+152
+00:13:50,710 --> 00:13:57,590
+OH، إذا hexanol. الآن الـol عشان تكون أقل ترقيم 1، 2،
+
+153
+00:13:57,590 --> 00:14:06,330
+3، 4، 5، 6. إذا هذا لو ما كانش عليه هذه الإضافة اللي
+
+154
+00:14:06,330 --> 00:14:12,190
+موجودة هنا، إيش هتسمّوه؟ 2-hexanol. واضح؟ الآن الـ
+
+155
+00:14:12,190 --> 00:14:20,110
+2- تاب على ترقيم إيش؟ طب على ترقيم السلسلة. لو هذه
+
+156
+00:14:20,110 --> 00:14:27,310
+إجيت بنزين، كان كلّكوا شاطرين، 4-phenyl-2-hexanol.
+
+157
+00:14:27,310 --> 00:14:33,870
+مش هتتغلّبوا فيها. لو هذه بنزين، هي 4-phenyl-2-
+
+158
+00:14:33,870 --> 00:14:39,030
+hexanol. الآن إجيت عليها بروم، طبعاً هذه موجودة وين؟
+
+159
+00:14:39,030 --> 00:14:45,010
+على 4، وهي الـ4 هذا اللي هو الرقم اللي هنا،
+
+160
+00:14:45,010 --> 00:14:48,150
+لكن هي بالضبط، اعملوا ترقيم تاني، 3-
+
+161
+00:14:48,150 --> 00:14:57,370
+bromophenyl، صارت واضحة الفكرة؟ اه، 3-
+
+162
+00:14:57,370 --> 00:15:03,090
+bromophenyl،
+
+163
+00:15:03,090 --> 00:15:06,270
+3-
+
+164
+00:15:06,270 --> 00:15:09,470
+bromophenyl،
+
+165
+00:15:09,470 --> 00:15:14,580
+3-bromophenyl-2-hexanol. الآن، بهذا المثال كم نظام
+
+166
+00:15:14,580 --> 00:15:18,780
+ترقيم استعملت؟ حتى ممكن بالألوان تشايفينهم، كيف
+
+167
+00:15:18,780 --> 00:15:22,820
+صاروا واضحين. هذا الـ4 تبقى لهان، إن المجموعة
+
+168
+00:15:22,820 --> 00:15:26,300
+اللي
+
+223
+00:21:04,730 --> 00:21:09,810
+الآن بالنسبة للـ ethers استُعملت سابقاً كمواد مخدرة
+
+224
+00:21:09,810 --> 00:21:14,670
+anesthetics والآن بعض مشتقاتها مثل هذا المركب
+
+225
+00:21:14,670 --> 00:21:17,450
+الذي فيه ذرات fluoro و chloro  لنبقيه نحفظه اسمه
+
+226
+00:21:17,450 --> 00:21:20,790
+phenanthrene أو هذا الذي فيه fluoro و chloro
+
+227
+00:21:20,790 --> 00:21:25,810
+anthracene تستعمل في التخدير الطبي، الـ halogenated
+
+228
+00:21:25,810 --> 00:21:28,970
+ethers; they are common anesthetics.
+
+229
+00:21:28,970 --> 00:21:33,650
+يعني مواد تُستخدم في التخدير الطبي. ننتبه لنقطة
+
+230
+00:21:33,650 --> 00:21:37,830
+كثير مهمة، لن نفصل فيها، لكن الآن سنذكرها: أن
+
+231
+00:21:37,830 --> 00:21:42,410
+الـ ether إذا خُزِّن لفترة طويلة، خاصة بعد فتح
+
+232
+00:21:42,410 --> 00:21:49,650
+الـ bottle ويتعرض للأكسجين، يُكوّن مادة متفجرة، peroxide
+
+233
+00:21:49,650 --> 00:21:54,530
+وبالتالي، قد يحاول الشخص تسخينه، طبعاً ليس مباشرة
+
+234
+00:21:54,530 --> 00:21:59,950
+على سخان كهربائي مغلق، الذي نسميه tablet، ويكون فيه
+
+235
+00:21:59,950 --> 00:22:04,380
+المواد المتفجرة، فينفجر. الآن هذه المواد
+
+236
+00:22:04,380 --> 00:22:08,320
+المتفجرة، أشهر ether يُستخدم عادة هو
+
+237
+00:22:08,320 --> 00:22:13,800
+Diethyl Ether. الآن هذا، لو خُزّن لفترة طويلة، يتفاعل
+
+238
+00:22:13,800 --> 00:22:18,600
+مع الأكسجين، مُكوّناً مركباً مثل هذا، بيروكسايد. هذا
+
+239
+00:22:18,600 --> 00:22:23,680
+البيروكسايد، ماذا به؟ متفجر. الآن حسب كمية
+
+240
+00:22:23,680 --> 00:22:28,280
+التخزين، لو خُزّن كثيراً في جو سيء، قد يُكوّن peroxide
+
+241
+00:22:28,280 --> 00:22:32,640
+ويتّرسّب، وترونه بأعينكم في قعر الـ bottle  الـ ether
+
+242
+00:22:32,640 --> 00:22:37,260
+مادة صلبة، لو كانت بكمية صغيرة، قد تكون ذائبة ولا
+
+243
+00:22:37,260 --> 00:22:41,610
+تُرى بالعينين. في كل الأحوال، عندما تنتقلون إلى الجزء العملي
+
+244
+00:22:41,610 --> 00:22:44,650
+أو تأخذون في يوم من الأيام جزءاً عملياً، من المفروض
+
+245
+00:22:44,650 --> 00:22:48,530
+أن تتعرفوا على تفاصيل كيفية فحص الـ ether، كيف نتأكد منه قبل
+
+246
+00:22:48,530 --> 00:22:53,690
+أن نشتغل عليه. هذا الأمر ستتعلمونه. الآن، لو في المستقبل
+
+247
+00:22:54,160 --> 00:22:58,620
+أشتغلتُم بكالوريوس، ماجستير، باحثاً في ether، تسخين، في
+
+248
+00:22:58,620 --> 00:23:02,740
+هذه اللحظة، خذوا كلمة واحدة: أن الـ ether فيه خطر أن
+
+249
+00:23:02,740 --> 00:23:06,820
+يُكوّن مواد متفجرة. يوم ما يُطلب منكم حقاً أن تشتغلوا و
+
+250
+00:23:06,820 --> 00:23:10,820
+تسخّنوا ether، ارجعوا لهذه المعلومة. في كل كتب
+
+251
+00:23:10,820 --> 00:23:16,130
+العمل، ستجدون تفاصيل أكثر، كيف تتأكدون أن هذه المادة
+
+252
+00:23:16,130 --> 00:23:19,850
+موجودة أم لا، ولو موجودة، كيف تتخلصون منها، وكل
+
+253
+00:23:19,850 --> 00:23:23,350
+الأشياء التفصيلية هذه. لكن خذوا في بالكم أن الـ
+
+254
+00:23:23,350 --> 00:23:27,950
+ether، مع سوء التخزين، وبوجود الأكسجين، يُكوّن ماذا؟
+
+255
+00:23:27,950 --> 00:23:36,090
+explosive materials. الآن، كيف نحضّر الـ ethers؟ أخذنا
+
+256
+00:23:36,090 --> 00:23:42,310
+نحضر الـ ethers، عندما درسنا الـ alkenes والـ
+
+257
+00:23:42,310 --> 00:23:48,250
+alcohols، قلنا أن الـ alcohol، لو سخّناه عند 180 درجة
+
+258
+00:23:48,250 --> 00:23:54,460
+مئوية، يُكوّن حذف الماء ويُعطي الالكين. وعند 140
+
+259
+00:23:54,460 --> 00:23:59,520
+درجة مئوية، يُعطي الـ ether. تتذكرون هذه المعادلة
+
+260
+00:23:59,520 --> 00:24:03,300
+في كيمياء الـ alcohols؟ إذن الـ ethers, they can be
+
+261
+00:24:03,300 --> 00:24:07,000
+prepared from alcohols. طبعاً، عندما أتحدث عن ether
+
+262
+00:24:07,000 --> 00:24:11,450
+هنا، أتحدث عن الـ symmetrical ethers. ماذا؟ أن إيثانول
+
+263
+00:24:11,450 --> 00:24:15,450
+يُهاجم إيثانولاً آخر، ويفقد ماء. وهذه المعادلة سابقاً
+
+264
+00:24:15,450 --> 00:24:20,190
+وضحناها. إيثانول مع إيثانول، يفقدان ماء، يعني
+
+265
+00:24:20,190 --> 00:24:24,770
+هذه المعادلة، لو أردتها موزونة، ماذا أكتب هنا؟ H2O
+
+266
+00:24:24,770 --> 00:24:29,110
+واضح؟ جزء يُهاجم الآخر، ويُخرج ماء، ويكون
+
+267
+00:24:29,110 --> 00:24:34,880
+ether. الآن هذا الـ symmetrical ether، أن الإيثانول
+
+268
+00:24:34,880 --> 00:24:39,720
+تفاعل مع نفسه. طيب، الآن يأتي السؤال: لو
+
+269
+00:24:39,720 --> 00:24:45,320
+أردت unsymmetrical ether، يعني أريد ether فيه إيثيل و
+
+270
+00:24:45,320 --> 00:24:51,400
+مثل ماذا؟ أول شيء قد يخطر ببالكم، يعني لو أردت أنا
+
+271
+00:24:51,400 --> 00:24:56,000
+دائماً في الـ ether، ماذا أسخّن مع الحمض؟ ميثانول.
+
+272
+00:24:56,000 --> 00:24:59,760
+لو أردت Diethyl Ether، ماذا أسخّن مع الحمض؟
+
+273
+00:24:59,760 --> 00:25:05,540
+إيثانول. طيب، لو أردت Methyl Ethyl Ether، ماذا أسخّن مع
+
+274
+00:25:05,540 --> 00:25:09,500
+الحمض؟ واضحة
+
+275
+00:25:09,500 --> 0:25:17,160
+الفكرة: لو أردت Methyl Ethyl Ether أو Ethyl Methyl Ether، الآن
+
+276
+00:25:17,160 --> 00:25:22,520
+انتبهوا معي. أي واحد قد يبدأ بالتفكير في Methyl Ethyl
+
+277
+00:25:22,520 --> 00:25:28,400
+Ether، يقول: آخذ الـ two alcohols، يعني آخذ Methyl OH
+
+278
+00:25:28,400 --> 00:25:40,120
+زائد Ethyl OH، بده يطلع Methyl OH. ما رأيكم بهذا
+
+279
+00:25:40,120 --> 00:25:40,780
+الكلام؟
+
+280
+00:25:43,190 --> 00:25:47,830
+يُعطيني، لكن هنا مشكلة، أنني عندما أخلط، لا أخلط جزيئاً و
+
+281
+00:25:47,830 --> 00:25:52,030
+جزيئاً، أخلط عدداً كبيراً. يعني لو خلطت مول ومول، يعني
+
+282
+00:25:52,030 --> 00:25:55,990
+أنا خلطت 6×10<sup>23</sup> من هذا مع 6×10<sup>23</sup> من
+
+283
+00:25:55,990 --> 00:26:00,290
+هذا. الآن، كلهم موجودون. فلنعملها على النطاق
+
+284
+00:26:00,290 --> 00:26:06,110
+البسيط. لو على نطاق جزيئين، هذا الـ ethanol وهذا الـ
+
+285
+00:26:06,110 --> 00:26:09,600
+methanol، وخلطتهما، وقلت لهما: تعالوا، تفاعلوا. ماذا
+
+286
+00:26:09,600 --> 00:26:13,600
+الاحتمالات؟ هما يتفاعلان، أليس كذلك؟ الآن، قد يلتقي
+
+287
+00:26:13,600 --> 00:26:20,260
+الإيثيل مع الإيثيل، فيُكوّن Diethyl Ether. قد يلتقي الميثيل مع
+
+288
+00:26:20,260 --> 00:26:27,420
+الميثيل، فيكوّن Dimethyl Ether. قد يلتقي الإيثيل مع الميثيل، فيكوّن Methyl
+
+289
+00:26:27,420 --> 00:26:35,740
+Ethyl Ether. إذن، هنا، كم ناتج نتوقع؟ ثلاثة: Methyl، أو Methyl Ethyl، أو
+
+290
+00:26:35,740 --> 00:26:41,970
+Ethyl، أو Ethyl Methyl. يطلع، لكن مع اثنين آخرين، يعني
+
+291
+00:26:41,970 --> 00:26:46,310
+يطلع خليط من ثلاثة مركبات. هات وفصلهم! هل هذا
+
+292
+00:26:46,310 --> 00:26:51,890
+الكلام الكيميائي يُحبّه؟ إطلاقاً لا. ولذلك، أيّ أحد
+
+293
+00:26:51,890 --> 00:26:56,590
+يقول إن تحضير Methyl Ethyl Ether بخلط الكحولين، فهو
+
+294
+00:26:56,590 --> 00:27:00,530
+أعطى جواباً خاطئاً، لأنك أخرجت ثلاثة نواتج، وبعدين
+
+295
+00:27:00,530 --> 00:27:05,170
+تحتاج إلى فصل وتقطير، وهذه عملية ماذا بها؟
+
+296
+00:27:05,170 --> 00:27:09,610
+مُتعبة. ولذلك، ننتقل إلى طريقة أخرى في تحضير الـ
+
+297
+00:27:09,610 --> 00:27:15,160
+unsymmetrical ethers. أيضاً نبدأ من أين؟ من
+
+298
+00:27:15,160 --> 00:27:20,340
+الكحولات. الآن، الكحول، واحد منهما، وبشكل عام، الذي
+
+299
+00:27:20,340 --> 00:27:25,520
+يكون primary، نجعله chloride. يعني هذا، لو
+
+300
+00:27:25,520 --> 00:27:32,900
+فاعلناه مع SOCl<sub>2</sub>، ماذا سيصير؟ CH<sub>3</sub>CH<sub>2</sub>، بدلاً من OH،
+
+301
+00:27:32,900 --> 00:27:39,020
+Cl. حولته إلى chloride، والآخر نحوله إلى O<sup>−</sup>. كيف
+
+302
+00:27:39,020 --> 00:27:43,010
+الكحول يُصبح O<sup>−</sup>؟ بالتفاعل مع الصوديوم
+
+303
+00:27:43,010 --> 00:27:48,290
+هيدروكسيد؟ قلنا لا، بالتفاعل مع الصوديوم أو
+
+304
+00:27:48,290 --> 00:27:51,890
+الصوديوم هيدريد. هذان الاثنان، هما اللذان يُكوّنان، يعني
+
+305
+00:27:51,890 --> 00:27:57,750
+هذا لو فعلته مع الصوديوم، يُصبح Methyl O<sup>−</sup> and Na<sup>+</sup>.
+
+306
+00:27:57,750 --> 00:28:04,840
+هذا في فلاسكٍ بمفرده، وهذا في فلاسكٍ بمفرده، لم
+
+307
+00:28:04,840 --> 00:28:09,360
+أخلطهما بعد. يعني شخص يعطيك إيثانول وهذا
+
+308
+00:28:09,360 --> 00:28:13,420
+ميثانول، هذا في فلاسك، واحد منهما نجعله O<sup>−</sup>
+
+309
+00:28:13,420 --> 00:28:19,900
+والآخر chloride. بعدين نضيف الاثنين على بعض، بعدين
+
+310
+00:28:19,900 --> 00:28:23,600
+نضيف ماذا؟ الاثنين على بعض. لو أضفت هذا على هذا، هذا
+
+311
+00:28:23,600 --> 00:28:30,490
+الـ O<sup>−</sup>، أين سيُهاجم؟ وماذا سيُطرد؟ الـ Cl. تفاعل الإحلال
+
+312
+00:28:30,490 --> 00:28:37,590
+الذي أخذناه في Chapter 6. لاحظوا، ماذا الناتج؟ CH<sub>3</sub>CH<sub>2</sub>O
+
+313
+00:28:37,590 --> 00:28:45,960
+CH<sub>3</sub>. مركب واحد. إذن، عندما أريد الـ un
+
+314
+00:28:45,960 --> 00:28:51,060
+symmetrical ethers، لا أخلط الكحولين معاً، بل أحول واحد
+
+315
+00:28:51,060 --> 00:28:56,240
+منهما إلى O<sup>−</sup>، وواحد منهما إلى
+
+316
+00:28:56,240 --> 00:29:00,000
+chloride أو bromide، وبعدين نضيفهما معاً، يُعطينا
+
+317
+00:29:00,000 --> 00:29:04,780
+ناتجاً واحداً فقط. هذه الطريقة في التحضير، اسمها طريقة
+
+318
+00:29:04,780 --> 00:29:10,230
+Williamson's synthesis. William Williamson's synthesis.
+
+319
+00:29:10,230 --> 00:29:14,410
+Williamson's synthesis، موجودة عندكم في الـ slides، وسنُوضّحها
+
+320
+00:29:14,410 --> 00:29:18,770
+بطريقة أخرى، أن لا نخلط الكحولين مع بعض
+
+321
+00:29:18,770 --> 00:29:24,090
+إطلاقاً، إطلاقاً. هذا الكلام لا يكون. واضحة الفكرة؟
+
+322
+00:29:30,200 --> 00:29:34,580
+لنرَ مرة أخرى الـ Williamson's synthesis. هذه مثلاً
+
+323
+00:29:34,580 --> 00:29:40,500
+ROH مع Na ماذا؟ ماذا أعطاني؟ R O<sup>−</sup>. هذا الـ charged
+
+324
+00:29:40,500 --> 00:29:45,300
+nucleophile، وR X، كُوّنتها أساساً من الكحول. عندما أضيف
+
+325
+00:29:45,300 --> 00:29:50,800
+الـ R O<sup>−</sup> على الـ R X، أيّ تفاعل أقوم به؟ الإحلال.
+
+326
+00:29:50,800 --> 00:29:53,380
+ROR
+
+327
+00:29:54,350 --> 00:29:59,510
+الآن، تخيلوا لو أتيتم بـ: How can you prepare this
+
+328
+00:29:59,510 --> 00:30:09,870
+ether؟ Phenyl O CH<sub>2</sub>CH<sub>3</sub>. الفكرة أن واحداً منهما، أريده
+
+329
+00:30:09,870 --> 00:30:15,330
+يعني أنا أبدأ من Phenol OH و Ethyl OH. لكن أيّهما أريد
+
+330
+00:30:15,330 --> 00:30:20,830
+أن أجعله O<sup>−</sup>، وأيّهما أريد أن أجعله Cl؟ الآن، قلت: الذي
+
+331
+00:30:20,830 --> 00:30:25,610
+أجعله Cl، الـ primary أو الـ methyl. إذا وجد، ما هو
+
+332
+00:30:25,610 --> 00:30:28,790
+الأفضل: الـ methyl أفضل من الـ primary. الـ primary أو الـ methyl
+
+333
+00:30:28,790 --> 00:30:34,720
+وبناءً على ذلك، الـ Phenol OH، هذا نجعله ماذا مع الصوديوم
+
+334
+00:30:34,720 --> 00:30:37,980
+أو مع الصوديوم هيدروكسيد؟ ينفع أساساً، لأن الفينول
+
+335
+00:30:37,980 --> 00:30:41,800
+يتفاعل مع الصوديوم هيدروكسيد، فيُصبح Phenyl O<sup>−</sup>.
+
+336
+00:30:41,800 --> 00:30:48,620
+هذا هو الـ nucleophile، Phenyl O<sup>−</sup>، وهذا الـ ethanol
+
+337
+00:30:48,620 --> 00:30:55,540
+أستطيع أن أحوله من خلال التفاعل مع SOCl<sub>2</sub>، CH<sub>3</sub>
+
+338
+00:30:55,540 --> 00:31:03,380
+CH<sub>2</sub>Cl. أكيد. الآن، لو فعلت هذا الـ phenoxide هنا، يُطرد
+
+339
+00:31:03,380 --> 00:31:09,330
+الـ X، ويُعطينا المركب المطلوب. أليس كذلك؟ واضح؟ الفكرة
+
+340
+00:31:09,330 --> 00:31:13,150
+في هذا النوع... الفكرة في هذا النوع من الأسئلة، عندما
+
+341
+00:31:13,150 --> 00:31:17,150
+أعطيكم ether معين، وأقول لكم: كيف تُحضّروه؟ أنكم
+
+342
+00:31:17,150 --> 00:31:20,450
+تعرفوا أيّ منهما أريد أن أجعله O<sup>−</sup>، وأيّهما أريد
+
+343
+00:31:20,450 --> 00:31:24,270
+أن أجعله chloride. الآن، الذي أريد أن أجعله الـ chloride، يا
+
+344
+00:31:24,270 --> 00:31:29,630
+الـ methyl، يا الـ primary. هذه مسألة، هنا، شايفينها؟
+
+345
+00:31:29,630 --> 00:31:37,760
+tert-Butyl Propyl Ether. كيف يمكنك تحضيره، بدءاً من
+
+346
+00:31:37,760 --> 00:31:44,680
+الكحول؟ ارسموا أنتما الكحول. احفظوا أنتما ماذا
+
+347
+00:31:44,680 --> 00:31:52,260
+المطلوب؟ tert-Butyl Propyl Ether. يعني كأن معكم
+
+348
+00:31:52,260 --> 00:32:01,200
+أنتم معطى هذا الـ tert-Butyl وهذا الـ propanol.
+
+349
+00:32:01,200 --> 00:32:06,700
+هذا أنتما الكحول. الآن، طريقة التحضير: واحد منهما
+
+350
+00:32:06,700 --> 00:32:15,000
+O<sup>−</sup> والآخر Cl. أيّهما أريد أن أجعله Cl؟ الـ primary. هذا
+
+351
+00:32:15,000 --> 00:32:20,300
+الـ alcohol tertiary، هذا الـ alcohol primary. إذن
+
+352
+00:32:20,300 --> 00:32:27,880
+هذا نفاعله مع SOCl<sub>2</sub>، سيُصبح Cl. وهذا نفاعله مع Na
+
+353
+00:32:27,880 --> 00:32:36,510
+سيُصبح O<sup>−</sup>. الآن، أخلطوا هذين الاثنين معاً. ماذا
+
+354
+00:32:36,510 --> 00:32:40,910
+النتيجة؟
+
+355
+00:32:40,910 --> 00:32:47,640
+هذا سيُهاجم هنا، ويُطرد الـ Cl. المركب المطلوب. مرات
+
+356
+00:32:47,640 --> 00:32:51,860
+عندما يقولون المركب المطلوب، يُضعون رمز TM. مرّ عليكم
+
+357
+00:32:51,860 --> 00:32:55,620
+ماذا يعني الـ TM؟ مثلما في الهندسة، عندما تنهون العمل
+
+358
+00:32:55,620 --> 00:33:00,020
+تقولون: هو المطلوب إثباته. الآن TM تعني target
+
+359
+00:33:00,020 --> 00:33:05,020
+molecule، يعني الجزء المطلوب. target ماذا؟ target؟
+
+360
+00:33:05,020 --> 00:33:11,520
+molecule، الجزء المطلوب. يعني الـ TM، بلغة الكيمياء، هو
+
+361
+00:33:11,520 --> 00:33:15,820
+المطلوب. طبعاً سيكون هكذا: O، وهي 1، 2،
+
+362
+00:33:15,820 --> 00:33:21,100
+3. واضحة؟
+
+363
+00:33:21,100 --> 00:33:24,580
+الآن، لو واحدة عكست، صنعت هذا الـ chloride وهذا الـ O<sup>−</sup>
+
+364
+00:33:24,580 --> 00:33:29,760
+لا يُعطينا. يعني لو السؤال عليه عشر علامات،
+
+365
+00:33:29,760 --> 00:33:35,900
+مجاملَة، نضع لها ثلاثة أو اثنين، لأنه
+
+366
+00:33:35,900 --> 00:33:42,040
+عملياً لا يُصبح. واضح؟ عملياً لا يكون. فهمنا هذه
+
+367
+00:33:42,040 --> 00:33:59,680
+الفكرة؟ Williamson's synthesis. الآن،
+
+368
+00:33:59,680 --> 00:34:06,640
+الـ ethers تكونت. طيب، هل يمكن أن تنكسر؟ يمكن أن تتفاعل
+
+369
+00:34:06,640 --> 00:34:10,900
+إلا في تفاعل واحد فقط، وهو الـ cleavage of
+
+370
+00:34:10,900 --> 00:34:16,020
+ether. يعني يمكن أن ينكسر. كيف يتم الـ cleavage
+
+371
+00:34:16,020 --> 00:34:23,220
+of ether؟ باستعمال الحمض القوي HI. الـ HI يُهاجم
+
+372
+00:34:23,220 --> 00:34:30,020
+عادةً على اليود. وهذا سيذهب أين؟ إلى الـ C مع... لا، إلى الـ Carbon
+
+373
+00:34:30,020 --> 00:34:33,200
+الذي بجانب الـ O. الـ U السالب... الـ O السالب
+
+374
+00:34:33,200 --> 00:34:36,080
+على الـ Carbon من بين الموجبات الـ
+
+375
+00:34:36,080 --> 00:34:39,360
+principal. يعني هنا، هذه الـ Carbon الموجبة، وهذه
+
+376
+00:34:39,360 --> 00:34:43,860
+الموجبة، وهذه السالبة جزئياً. عندما يذهب... أين سيذهب؟
+
+377
+00:34:43,860 --> 00:34:47,880
+إلى الموجب. الآن لاحظوا معي، عندما يذهب
+
+378
+00:34:47,880 --> 00:34:52,820
+إلى الموجب، سيذهب إلى الموجب الأيمن أم
+
+379
+00:34:52,820 --> 00:34:58,480
+الموجب الأيسر؟ فهمتّم أين السؤال؟ الآن، على الـ
+
+380
+00:34:58,480 --> 00:35:05,900
+primary. هذا المحور. الآن، أين الـ primary هنا؟ أين الـ
+
+381
+00:35:05,900 --> 00:35:12,420
+primary هنا؟ ولذلك، عندما تظهر النتيجة، هذا الجزء الذي
+
+382
+00:35:12,420 --> 00:35:18,340
+يبقى معه الـ O، سيأخذ الـ H، سيصبح الـ O ماذا؟ H، سيأخذ
+
+383
+00:35:18,340 --> 00:35:25,180
+الـ H. وهذا الجزء CH<sub>3</sub>CH<sub>2</sub> سيصبح ماذا؟ Iodide. شفنا كيف
+
+384
+00:35:25,180 --> 00:35:29,780
+الـ cleavage. الآن، هذا يذهب هنا. ماذا هنا؟ سيُعطيني
+
+385
+00:35:29,780 --> 00:35:37
+
+445
+00:40:53,590 --> 00:40:58,650
+معين بيدخل بـ cavity معينة، أيون معين بيدخل بـ cavity
+
+446
+00:40:58,650 --> 00:41:03,730
+معينة، يعني مثلاً هذا المركب الـ 18 crown 6 لما جاسوا
+
+447
+00:41:03,730 --> 00:41:08,230
+حجم الـ cavity تبعته بين اتنين وستة من عشرة لتلاتة
+
+448
+00:41:08,230 --> 00:41:12,030
+واتنين من عشرة أنجستروم، طب حجم أيون الصوديوم واحد
+
+449
+00:41:12,030 --> 00:41:15,510
+و تسعة، واحد و تسعة، لو حطناه من هنا إيش بيعمل؟
+
+450
+00:41:15,510 --> 00:41:21,490
+الفتحة كبيرة عليه، بيخرج منها، الـ cesium تلاتة و
+
+451
+00:41:21,490 --> 00:41:27,550
+تلاتة أكبر من الفتحة، بيدخلش، مين اللي بتناسب معها؟
+
+452
+00:41:27,550 --> 00:41:31,990
+اتنين وستة وستين، وهذه اتنين وستة لتلاتة واتنين
+
+453
+00:41:32,930 --> 00:41:37,910
+البوتاسيوم، إذا لو حطينا الـ crown الآن وجبنا
+
+454
+00:41:37,910 --> 00:41:42,650
+التلات أيونات معادن، هو فيه cavity الآن، الـ cavity
+
+455
+00:41:42,650 --> 00:41:50,330
+واحد صغير بيدخل منها بيوقع، والتاني كبير ما بيجيش
+
+456
+00:41:50,330 --> 00:41:54,970
+والتالت المتناسب، مين اللي هيقعد في قلب الـ cavity؟
+
+457
+00:41:55,610 --> 00:42:01,130
+البوتاسيوم، إذا هذا الـ crown صار، لو حطينا له التلاتة
+
+458
+00:42:01,130 --> 00:42:05,390
+صاد منهم البوتاسيوم، وساب التانين، التانين عارفين
+
+459
+00:42:05,390 --> 00:42:09,990
+الفكرة زي إيش؟ زي الشبكة تبع صيادين السمك، صياد
+
+460
+00:42:09,990 --> 00:42:13,530
+السمك عنده أكتر من شبكة لكل موسم، كل شبكة فيها حجم
+
+461
+00:42:13,530 --> 00:42:19,110
+معين، لما بدو يصيد البوري عنده حجم معين بيمسك سمكة
+
+462
+00:42:19,110 --> 00:42:24,200
+البوري، طب والسردين؟ في شبكة البوري بيدخل ويطلع
+
+463
+00:42:24,200 --> 00:42:27,320
+قدامه، هو مش ناوي يصيده، بيدخل ويطلع، أو السمك
+
+464
+00:42:27,320 --> 00:42:30,460
+الصغير، لما بدو يصيد السردين شو بدو يستعمل الها؟
+
+465
+00:42:30,460 --> 00:42:35,000
+شبكة أصغر، فهمتوا إيش الفكرة هنا في الـ host والـ
+
+466
+00:42:35,000 --> 00:42:39,840
+guest؟ إنه الـ guest الضيف اللي بدو ييجي هنا اللي
+
+467
+00:42:39,840 --> 00:42:44,560
+هو المثل، هذا الـ guest لازم يكون حجمه متناسب مع
+
+468
+00:42:44,560 --> 00:42:51,240
+إيش؟ مع الـ cavity، وهذا الكلام له حتى تطبيقات في
+
+469
+00:42:51,240 --> 00:42:56,940
+وين؟ في المجال الطبي، في الأدوية، يعني آخر slide الآن
+
+470
+00:42:56,940 --> 00:43:03,220
+عندنا هاي، هذا المركب في نفس الفكرة بطريقة أو بأخرى
+
+471
+00:43:03,220 --> 00:43:10,380
+وفي cavity هنا، high cavity، هذه الـ cavity تبعته بتتسع
+
+472
+00:43:10,380 --> 00:43:16,300
+البوتاسيوم، يعني لما يكون فيه Na+ وK+
+
+473
+00:43:16,300 --> 00:43:20,980
+في جسم الإنسان، من اللي بيدخل في الـ cavity البوتاسيوم
+
+474
+00:43:20,980 --> 00:43:25,940
+الآن هذا المضاد الحيوي بدخل جوا الخلية، لما يدخل
+
+475
+00:43:25,940 --> 00:43:31,500
+بدخل بما يحمله، إذا إيش قادر يدخل جوا الخلية؟
+
+476
+00:43:32,150 --> 00:43:37,190
+البوتاسيوم، إيش صار برا الخلية؟ الصوديوم، بنسمي هذه
+
+477
+00:43:37,190 --> 00:43:43,630
+العملية إيش؟ selective transport، يعني هو دخل واحد
+
+478
+00:43:43,630 --> 00:43:50,770
+من اتنين، هي الخلية، هي جدارها، هذه هي الخلية، المضاد
+
+479
+00:43:50,770 --> 00:43:55,560
+بيقدر يدخل جلب الخلية، وبيقدر يحمل واحد من
+
+480
+00:43:55,560 --> 00:43:58,620
+الاتنين، مين اللي بيقدر يحمله؟ الـ potassium
+
+481
+00:43:58,620 --> 00:44:01,920
+المتناسب مع حجم الـ cavity، بناءً على ذلك هو في الأول
+
+482
+00:44:01,920 --> 00:44:05,500
+بيحمل الـ potassium، بعدين هو بما حمله بيدخل جوا
+
+483
+00:44:05,500 --> 00:44:11,000
+الخلية، وبذلك دخل، نقل الـ potassium من برا لجوا
+
+484
+00:44:11,700 --> 00:44:15,900
+فهمتوا أين الجمال بفكرة crown ethers؟ يعني بسرعة
+
+485
+00:44:15,900 --> 00:44:21,900
+انعكاس على واقع التطبيق الطبي، بهيك بنكون أنهينا هذا
+
+486
+00:44:21,900 --> 00:44:24,140
+الـ chapter اللي اسمه الـ ethers
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/D9wF84ICB3s_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/D9wF84ICB3s_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..3bed0200f45e90bb165e6da87325547b7cef2042
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/D9wF84ICB3s_postprocess.srt
@@ -0,0 +1,1944 @@
+1
+00:00:19,640 --> 00:00:24,180
+بسم الله الرحمن الرحيم موضوعنا اليوم عن عائلة
+
+2
+00:00:24,180 --> 00:00:28,620
+كيميائية جديدة مجموعة وظيفية جديدة اللي هي ال
+
+3
+00:00:28,620 --> 00:00:34,460
+aethers طبعا على طول عدد كبير منكم هيتذكر ان ال
+
+4
+00:00:34,460 --> 00:00:40,460
+aethers اللي هم الصيغة العامة ROR يعني Oxygen
+
+5
+00:00:40,460 --> 00:00:47,150
+محصورة بين ذرتينأو Oxygen بين مجموعتين R وكلكم
+
+6
+00:00:47,150 --> 00:00:53,550
+اتذكرين ان ال Oxygen رابطتين وزوجين إيش؟ إلكترونات
+
+7
+00:00:53,550 --> 00:00:59,950
+ولذلك احنا غير ال ethers مر علينا شغلتين أبسط من
+
+8
+00:00:59,950 --> 00:01:04,390
+ال ethers مر علينا شغلتين أبسط من ال ethers شو هم
+
+9
+00:01:04,390 --> 00:01:11,100
+الآن؟ مين يذكرنا فيهم؟ الماءوالكحول الان الماء
+
+10
+00:01:11,100 --> 00:01:16,260
+اكسوجينة ايضا و الكحول اكسوجينة و ال ether برضه
+
+11
+00:01:16,260 --> 00:01:21,080
+ذرة اكسوجين و زوجين الالكترونات هدوله مافيش مفار
+
+12
+00:01:21,080 --> 00:01:31,320
+منهم لكن الميه كانت H H H الكحول R و H يعني مازال
+
+13
+00:01:31,320 --> 00:01:37,840
+فيه H ال ether R و Rالان لاحظوا بمنطق ال hydrogen
+
+14
+00:01:37,840 --> 00:01:43,740
+bonding الان الميه تنتين hydrogen bonding الكحول
+
+15
+00:01:43,740 --> 00:01:48,080
+من جهة واحدة بتقدر تعمل hydrogen bonding ال ether
+
+16
+00:01:48,080 --> 00:01:52,660
+مافيش hydrogen bonding وبناء على ذلك الان لو بدنا
+
+17
+00:01:52,660 --> 00:01:57,660
+نحكي بمنطق ال polarity من اعلى polarity فيهم الميه
+
+18
+00:01:57,660 --> 00:02:02,080
+بعدها الكحول بعدها ال ether الان ال polarity
+
+19
+00:02:02,080 --> 00:02:07,340
+مباشرة بتنعكس على ايشعلى أي خاصية فيزيائية؟ على
+
+20
+00:02:07,340 --> 00:02:11,460
+درجة الغليان ولذلك على الضغط العادى الميه درجة
+
+21
+00:02:11,460 --> 00:02:17,640
+غليانها 100 الكحول 78 ال ether لو افترضنا اثل و
+
+22
+00:02:17,640 --> 00:02:22,080
+اثل حوالي 37
+
+23
+00:02:23,430 --> 00:02:30,190
+لاحظوا كيف تناسب نقاط الغليان مع القطبية و لو كان
+
+24
+00:02:30,190 --> 00:02:33,950
+ال ether die مثل ether يعني مثل او مثل بيصير غاز
+
+25
+00:02:33,950 --> 00:02:38,930
+يعني درجة غليانه أقل بكتير ولذلك على حرارة الغرفة
+
+26
+00:02:38,930 --> 00:02:45,510
+غلي و خلص وصار ايش موجود على شكلغاز الآن ربما من
+
+27
+00:02:45,510 --> 00:02:48,790
+أشهر ال ether هذا ال ether ال ethyl o ethyl اللي
+
+28
+00:02:48,790 --> 00:02:53,670
+هو ال diethyl ether واضح؟ ليش هذا يستعمل ك solvent
+
+29
+00:02:53,670 --> 00:02:58,670
+مدير سابقا استعمل في التخدير لما كانوا مثلا
+
+30
+00:02:58,670 --> 00:03:01,850
+بيخدروا حيوانات صغيرة بيعملوا تجارب في المختبرات
+
+31
+00:03:01,850 --> 00:03:06,930
+فال ether they have been used as anesthetics الآن
+
+32
+00:03:06,930 --> 00:03:11,720
+لوبدنا ننسى هدول الأشياء اللى احنا سبق اننا
+
+33
+00:03:11,720 --> 00:03:17,820
+أخدناهم ونضلنا امركزين حالنا في ال aethers وهى
+
+34
+00:03:17,820 --> 00:03:22,980
+المثال عنهم اللى هو diethyl ether وممكن نسميه
+
+35
+00:03:22,980 --> 00:03:26,540
+ethyl ether يعني لو لغينا كلمة ethyl، die، بمشي
+
+36
+00:03:26,540 --> 00:03:32,140
+يعني diethyl ether وethyl ether نفس الاشي لحظوا
+
+37
+00:03:32,140 --> 00:03:36,440
+لما بنقول من خواصه much less polar than alcohols
+
+38
+00:03:37,210 --> 00:03:40,210
+الكلام صحيح ولا لأ؟ مافيش فيه hydrogen bonding
+
+39
+00:03:40,210 --> 00:03:44,130
+بالمرة لما نقول من خواصه not soluble in water
+
+40
+00:03:44,130 --> 00:03:49,430
+مافيش فيه solubility لأن هذه are groups كلها مافيش
+
+41
+00:03:49,430 --> 00:03:52,510
+فيه hydrogen bonding اللي يصير polar و like،
+
+42
+00:03:52,510 --> 00:03:56,730
+dissolves، like، له lower melting point و boiling
+
+43
+00:03:56,730 --> 00:04:01,130
+point أو boiling temperatures than alcohol اكيد صح
+
+44
+00:04:03,220 --> 00:04:08,200
+كمان بضيف عليه شغلة chemically inert يعني خامل
+
+45
+00:04:08,200 --> 00:04:14,940
+كيميائيا تفاعلاته قليلة جدا ولذلك ان شاء الله بأمل
+
+46
+00:04:14,940 --> 00:04:18,900
+كل أمل ان نخلص كل ال chapter اليوم لانه لما نحكي
+
+47
+00:04:18,900 --> 00:04:21,560
+عن ال kings و ال quills بنحكي على عشرين تفاعل على
+
+48
+00:04:21,560 --> 00:04:28,180
+ال ethers بنحكي على تفاعل واحد واضح؟لأنه مافيش من
+
+49
+00:04:28,180 --> 00:04:32,340
+خلال MH و لا OH و لا C double bond O و لا double
+
+50
+00:04:32,340 --> 00:04:35,760
+bond هذي المجموعات اللي بنسميها active groups اللي
+
+51
+00:04:35,760 --> 00:04:39,460
+بتيم عليها تفاعلات كتيرة هذا الكلام مش متوفر وين
+
+52
+00:04:39,460 --> 00:04:44,380
+في الethers يضاف إلى ذلك all are very flammable
+
+53
+00:04:45,250 --> 00:04:50,010
+يعني باشتعلوا بشكل سريع جدا زي بنزين السيارات و
+
+54
+00:04:50,010 --> 00:04:54,950
+وقود السيارات أو ربما كمان اكثر ولذلك ادمجوا
+
+55
+00:04:54,950 --> 00:05:00,090
+الشغلتين مع بعض ان هو له نقطة غليان منخفضة يعني
+
+56
+00:05:00,090 --> 00:05:07,230
+بتبخر بسهولة و قابل الاشتعال بشكل كبيرواضح؟ و لذلك
+
+57
+00:05:07,230 --> 00:05:11,770
+يمثل خطر في المختبر يعني نفترض ان حد عنده بنزين
+
+58
+00:05:11,770 --> 00:05:15,630
+burner مولعه هنا و قاعد بيشتغل و هنا فيه وعاء فيه
+
+59
+00:05:15,630 --> 00:05:19,610
+ether مفتوح ال ether نفسه بتبخر سبعة و تلاتين احنا
+
+60
+00:05:19,610 --> 00:05:23,170
+مرات في غزة الحرارة سبعة و تلاتين طبعا هو بتبخر
+
+61
+00:05:23,170 --> 00:05:27,030
+على كل الدرجات و كل ما ارتفعت الحرارة بتزيد التبخر
+
+62
+00:05:27,030 --> 00:05:32,020
+و لذلك ممكن و ال ether هنا و فيناعرف مكان تانيit
+
+63
+00:05:32,020 --> 00:05:36,000
+can catch fire زي ما بيسموه يعني ممكن يشتعل و يعمل
+
+64
+00:05:36,000 --> 00:05:41,060
+حريقة فالتعامل مع ال ether بحاجة إلى حذر لأن هو
+
+65
+00:05:41,060 --> 00:05:46,440
+very flammable و له نقطة غليان منخفضة يعني بينوجد
+
+66
+00:05:46,440 --> 00:05:51,500
+.. بيتبخر واضح؟ تماما زي التعامل مع وقود السيارات
+
+67
+00:05:51,500 --> 00:05:56,240
+أو مع التنر هذه المراكبات الكيميائية بحاجة إلى نوع
+
+68
+00:05:56,240 --> 00:06:04,050
+من الحذر الشديدالان كيف بنسمي ال ethers؟ في إنا
+
+69
+00:06:04,050 --> 00:06:08,670
+نظامين للتسمية نظام الشائع ال common nomenclature
+
+70
+00:06:08,670 --> 00:06:12,710
+إن أنا أذكر المجموعات و دائما المجموعة بتاخد
+
+71
+00:06:12,710 --> 00:06:17,990
+النهاية YL مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+72
+00:06:17,990 --> 00:06:20,470
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+73
+00:06:20,470 --> 00:06:26,330
+مثل مثل مثل مثل مثل مثل
+
+74
+00:06:26,330 --> 00:06:26,970
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+75
+00:06:26,970 --> 00:06:30,750
+مثل مثل مثل مثل مثل مثبقول die ethyl ether وممكن
+
+76
+00:06:30,750 --> 00:06:35,210
+تلاقوها ethyl ether يعني تختصر ال die مثل و مثل،
+
+77
+00:06:35,210 --> 00:06:41,030
+die مثل ether فنل و فنل، die فنل ether الان طب لو
+
+78
+00:06:41,030 --> 00:06:44,450
+كان هذا ال ether اللاحظه اللي زي بعض المجموعتين
+
+79
+00:06:44,450 --> 00:06:48,110
+يعني نتخيله زي هيك هي هذه ال oxygena وهنا
+
+80
+00:06:48,110 --> 00:06:53,920
+المجموعتين زي بعضهذا بنسميه Symmetric Ether متماثل
+
+81
+00:06:53,920 --> 00:06:59,700
+طب لو يختلفوا Unsymmetric Ether الأن واجهت أذكر
+
+82
+00:06:59,700 --> 00:07:04,840
+المجموعتين alphabetically يعني Ether فيه إثل و مثل
+
+83
+00:07:04,840 --> 00:07:13,080
+إيش هسميه إثل مثل إثر إبروبل مثلا و تيرتشار بيوتل
+
+84
+00:07:14,280 --> 00:07:27,560
+ترتشير بيوتل بروبل إيثار ترتشير
+
+85
+00:07:27,560 --> 00:07:28,240
+بيوتل بروبل إيثار ترتشير بيوتل بروبل إيثار ترتشير
+
+86
+00:07:28,240 --> 00:07:33,600
+بيوتل بروبل إيثار ترتشير بيوتل بروبل إيثار
+
+87
+00:07:39,540 --> 00:07:45,680
+بتكونش تعجزوا ال ether معناه ذرّة أكسوجين طالع
+
+88
+00:07:45,680 --> 00:07:49,940
+منها رابطة تل لكن الشطارة في اللي بيكون حفظ
+
+89
+00:07:49,940 --> 00:07:57,840
+المجفوعات الآن ال tertiary butylcarbon عليها تلاتة
+
+90
+00:07:57,840 --> 00:08:04,700
+مثل أخذناها وال isopropyl carbon CH متصلة باتنين
+
+91
+00:08:04,700 --> 00:08:11,280
+مثل زي هيكالمحافظة على هذه الشغلة من الأول هذا
+
+92
+00:08:11,280 --> 00:08:18,320
+دلبو واضح فهي tertiary butyl isopropyl ether احنا
+
+93
+00:08:18,320 --> 00:08:22,560
+قلنا تيرتشاري بيوتل بنعملها على حرف ال بي هذا لما
+
+94
+00:08:22,560 --> 00:08:27,140
+شرحنا المجموعات اذا شفنا كيف بنعمل ال ethers كذلك
+
+95
+00:08:27,140 --> 00:08:31,380
+الحالة لو قلنا الكوفينيل مثلا ايش بدنا نحط البنزين
+
+96
+00:08:31,380 --> 00:08:32,300
+المخصوم منها
+
+97
+00:08:42,010 --> 00:08:47,110
+وهاي هذه أمثلة die methyl ether اثل مثل اثر زي ما
+
+98
+00:08:47,110 --> 00:08:50,810
+قولت مرات بيحطهم مش مرتبين alphabetical لكن الأصح
+
+99
+00:08:50,810 --> 00:08:55,090
+تحطهم alphabetical يعني زي هذا الأصح تكتبوه اثل
+
+100
+00:08:55,090 --> 00:09:00,110
+مثل اثر خلو ال E قبل ال M هذا ال ether هذه ال
+
+101
+00:09:00,110 --> 00:09:07,410
+CH2Cl اسمها كلوروميثل CH2Cl كلوروميثل وهنا اثل اثل
+
+102
+00:09:07,410 --> 00:09:15,930
+اثلEther وهكذا هذه التسمية هي ال common
+
+103
+00:09:15,930 --> 00:09:21,070
+nomenclature الان لاحظوا معاك شرط هذه التسمية شرط
+
+104
+00:09:21,070 --> 00:09:24,730
+هذه التسمية ان المجموع اللي هان و اللي هان يكون
+
+105
+00:09:24,730 --> 00:09:28,010
+لهم اسماء معروفة بالنسبة لنا و المجموعات اللي
+
+106
+00:09:28,010 --> 00:09:31,810
+أخدناها ايجليلا مثل ايثلبروبل ايزوبروبل تيرتشر
+
+107
+00:09:31,810 --> 00:09:38,800
+بيوتل لحجناها انا بكلورو مثل .. بنل مثلا ب ..أقل
+
+108
+00:09:38,800 --> 00:09:46,290
+ال ether لو قلنا لكم اعملوه يعني شغلات ايشمعروفة
+
+109
+00:09:46,290 --> 00:09:51,030
+طيب الان لو المركب كبر وفي ايثر ايثر معناه
+
+110
+00:09:51,030 --> 00:09:55,610
+اكسوجينة بين كربونتين واجيتها بدي ارجع اسم المركب
+
+111
+00:09:55,610 --> 00:10:02,770
+كأنه ال cane عادي ابحث عن اطول سلسلة اطول سلسلة
+
+112
+00:10:02,770 --> 00:10:08,310
+تلاتة مركبة بروبين اربعة بيوتين خمسة بنتين و هكذا
+
+113
+00:10:08,310 --> 00:10:13,780
+طيب بعد ما اطول اطول سلسلة يعني هاي هذا مركبلاحظوا
+
+114
+00:10:13,780 --> 00:10:17,180
+هنا في carbon تنتين تلاتة لبروبل و هنا carbon
+
+115
+00:10:17,180 --> 00:10:21,920
+واحدة ايش أطول السلسلة لبروبل الآن تخيل لو هذا
+
+116
+00:10:21,920 --> 00:10:26,580
+الأزرق اللي هنا كانت Cl لكلور اللي على موقع واحد
+
+117
+00:10:26,580 --> 00:10:33,420
+ايش هتسموه المركب وان كلورو بروبل بدكوا تحددوا
+
+118
+00:10:33,420 --> 00:10:38,620
+الرقم الان اللي على موقع واحد مش كلور او مثل ال او
+
+119
+00:10:38,620 --> 00:10:40,780
+مثل اللي لها اسم مثوكسي
+
+120
+00:10:43,660 --> 00:10:52,760
+مثل ا ا مثوكسي طب لو كانت ا اثل اثوكسي لو كانت ا
+
+121
+00:10:52,760 --> 00:10:57,660
+فنل مثوكسي
+
+122
+00:10:57,660 --> 00:11:04,080
+مثل ا اثوكسي اثل
+
+123
+00:11:04,080 --> 00:11:10,420
+افنوكسي فنل افروبوكسي
+
+124
+00:11:13,650 --> 00:11:22,270
+هيبروبيل او ابيوتكسي ابيوتل او and so on واضح
+
+125
+00:11:22,270 --> 00:11:27,350
+فبنطول أطول سلسلة وبعدين المجموعات بنسميها يعني
+
+126
+00:11:27,350 --> 00:11:31,190
+مثلا هذا المركب هاي كاربون تنتين أطول سلسلة إذا
+
+127
+00:11:31,190 --> 00:11:37,540
+المركب إيش إيثان على نمرة واحد إيش عليه؟أو مثل
+
+128
+00:11:37,540 --> 00:11:43,040
+مثوكسي و إيش عليه كمان اكلور إذا هذا one chloro
+
+129
+00:11:43,040 --> 00:11:49,840
+one methoxy اثان هاي هذا المركب carbon 234 بيوتين
+
+130
+00:11:49,840 --> 00:11:56,560
+على نمره اتنين إيش عليه تلت ذرات معه بروبوكسي
+
+131
+00:11:56,560 --> 00:12:02,810
+بروبوكسي تلت ذرات معه هذا المركبلاحظوا إيثانول ال
+
+132
+00:12:02,810 --> 00:12:07,230
+alcohol أقوى من ال ether هنقول عنه واحد اتنين
+
+133
+00:12:07,230 --> 00:12:12,330
+تلاتة أربعة إذا هذا أي مركب واند يوتانول ضال على
+
+134
+00:12:12,330 --> 00:12:17,990
+نمرة تلاتة شو المجموعة اللي حملها؟مش اتوكسي كلور و
+
+135
+00:12:17,990 --> 00:12:23,730
+اتوكسي تمام حملة كلور الان الكلور هذه محمولة على
+
+136
+00:12:23,730 --> 00:12:27,510
+الكربون هذه ولا هذه تعون ال organic بيحطوها بين
+
+137
+00:12:27,510 --> 00:12:31,550
+جسين و بيقولوا الكلور على الكربون رقم اتنين لاحظوا
+
+138
+00:12:31,550 --> 00:12:36,490
+اتنين يعني كأنه كل هذه انحطت ايش بين جسين صار كام
+
+139
+00:12:36,490 --> 00:12:40,410
+نظام ترقيم عندى نظامين النظام الاصلي واحد اتنين
+
+140
+00:12:40,410 --> 00:12:43,890
+تلاتة اربعة و هنا الكلور لو اجتها انا بدي اقول one
+
+141
+00:12:43,890 --> 00:12:49,570
+primeإكلورو إيثوكس لو إجت هنا two prime إكلورو
+
+142
+00:12:49,570 --> 00:12:52,890
+إيثوكس و مرات بتلاحظون ممكن يختصروا ال prime لكن
+
+143
+00:12:52,890 --> 00:12:59,190
+الأحسن إذا الإنسان استعمل أكثر من نظام ترقيم أنه
+
+144
+00:12:59,190 --> 00:13:05,070
+يحط إيش ل prime واضح هذه الفكرة بدي أركز معاكوا
+
+145
+00:13:05,070 --> 00:13:12,140
+عليها فكرة أن الإنسان يستعملأكثر من نظام ترقيم في
+
+146
+00:13:12,140 --> 00:13:15,980
+نفس المُركّب خلّيني أعطيكوا عليها مثالين عند
+
+147
+00:13:15,980 --> 00:13:20,460
+اللزوم ممكن مثال من موضوعنا الـEthers ومثال من
+
+148
+00:13:20,460 --> 00:13:27,920
+موضوع الـH تاني يعني الترقيم ممكن نستعمل أكثر من
+
+149
+00:13:27,920 --> 00:13:35,300
+نظام ترقيم لو يا تورا أعطيتكم المُركّب هذا و
+
+150
+00:13:35,300 --> 00:13:44,270
+كتبت هنا OH و كتبت هنا Zوحطينا هنا PR نفترض هذا
+
+151
+00:13:44,270 --> 00:13:50,710
+المركب جاينا سمى المركب التالي الآن هذا أفضل شيء
+
+152
+00:13:50,710 --> 00:13:57,590
+أسميه كالكين واضح؟ أطول سلسلة و أطول سلسلة حاملة
+
+153
+00:13:57,590 --> 00:14:06,330
+OHإذا هكسانول الان ال all عشان تكون أقل ترقيم 1,2
+
+154
+00:14:06,330 --> 00:14:12,190
+,3,4,5,6 إذا هذا لو ماكنش عليه هذه الإضافة اللي
+
+155
+00:14:12,190 --> 00:14:20,110
+موجودة هنا إيش هتسموه two hexanol واضح؟ الآن ال
+
+156
+00:14:20,110 --> 00:14:27,310
+two تاب على ترقيم إيش؟طب على ترقيم السلسلة لو هذه
+
+157
+00:14:27,310 --> 00:14:33,870
+إجت بنزينة كان كل كشاطرين four phenyl two hexanol
+
+158
+00:14:33,870 --> 00:14:39,030
+مش هتتغلبوا فيها لو هذه بنزينة هي four phenyl two
+
+159
+00:14:39,030 --> 00:14:45,010
+hexanol الآن إجت عليها بروم طبعا هذه موجودة وين؟
+
+160
+00:14:45,010 --> 00:14:48,150
+على four وهي ال four هذا اللي هو الرقم اللي هنا
+
+161
+00:14:48,150 --> 00:14:57,370
+لكن هي بالظبطاه اعملوا ترقيم تاني three
+
+162
+00:14:57,370 --> 00:15:03,090
+bromophenyl صارت واضحة الفكرة؟ اه three
+
+163
+00:15:03,090 --> 00:15:06,270
+bromophenyl
+
+164
+00:15:06,270 --> 00:15:09,470
+three
+
+165
+00:15:09,470 --> 00:15:14,580
+bromophenyl two hexanolالان بهذا المثال كم نظام
+
+166
+00:15:14,580 --> 00:15:18,780
+ترقيم استعملت حتى ممكن بالألوان تشايفينهم كيف
+
+167
+00:15:18,780 --> 00:15:22,820
+صاروا واضحين هذا ال four تبقى لهان ان المجموعة
+
+168
+00:15:22,820 --> 00:15:26,300
+اللتي بين القوسين موجودة على الموقع أربعة على
+
+169
+00:15:26,300 --> 00:15:32,460
+السنسلة لكن هذا ترقيم تاني عشان هيك الأنسب لهذا
+
+170
+00:15:32,460 --> 00:15:37,000
+الترقيم التاني اللي كنت كاتبه بالأزرقإن أحطله إيش
+
+171
+00:15:37,000 --> 00:15:44,720
+الـ prime طبعا هذا بيمنعش أنه بزام فيه تاني ممكن
+
+172
+00:15:44,720 --> 00:15:50,520
+يصير كمان تالت و باجيتها ممكن أحطله double prime
+
+173
+00:15:50,520 --> 00:15:56,720
+وارد بتصير الأمور أصعب لكن المبدأ بأمل أنه صار إيش
+
+174
+00:15:56,720 --> 00:15:58,440
+واضح عندكم
+
+175
+00:16:04,790 --> 00:16:11,250
+لو طلبنا منكم تسمولنا
+
+176
+00:16:11,250 --> 00:16:27,510
+هذا المركب على سبيل المثال جاكوا
+
+177
+00:16:27,510 --> 00:16:32,870
+هذا في الامتحان هو زيكك BJ الآن
+
+178
+00:16:32,870 --> 00:16:37,720
+هتفكروا بإيش؟بأطول سلسلة ما تشوفوش تفكروا بال إيثا
+
+179
+00:16:37,720 --> 00:16:41,220
+لإن لو قلت هذه مثل طب وش كلها المجموعة التانية؟
+
+180
+00:16:41,220 --> 00:16:44,320
+مالهاش اسم و لو قلت هذه فنل شو المجموعة التانية؟
+
+181
+00:16:44,320 --> 00:16:50,400
+مالهاش اسم لكن ان نقول في سلسلة و هذه يا مسهلها
+
+182
+00:16:50,400 --> 00:16:57,960
+مثوكسي و في سلسلة و هذه يا مسهلها فينوكسي القمر
+
+183
+00:16:57,960 --> 00:17:04,070
+بيكون إيش؟سهل الان اطول سلسلة فيها double bond اذا
+
+184
+00:17:04,070 --> 00:17:09,690
+المركبة ال keen ال keen واحد اتنين تلاتة اربعة
+
+185
+00:17:09,690 --> 00:17:19,310
+خمسة ستة سبعة two heptane واضح two heptane الان
+
+186
+00:17:19,310 --> 00:17:26,250
+عليه ع موقع تلاتة methoxy وع موقع ستة phenoxy
+
+187
+00:17:26,250 --> 00:17:34,940
+بالترتيبthree methoxy six phenoxy
+
+188
+00:17:34,940 --> 00:17:42,280
+two heptane وكفى
+
+189
+00:17:42,280 --> 00:17:45,740
+الله المؤمنين القتال بس اللى بتسمى زيك بنحطله
+
+190
+00:17:45,740 --> 00:17:54,320
+تمانية من عشرة لسه موصلناش للعشرة من عشرة ليش ضايل
+
+191
+00:17:54,320 --> 00:18:00,650
+في التسمية ماجيبتهوشDouble bond اول ما نشوف double
+
+192
+00:18:00,650 --> 00:18:05,370
+bond فاكره ب Z و E و S و Trans و اول ما نشوف
+
+193
+00:18:05,370 --> 00:18:08,890
+chiral center فاكره بال R و S الان ايه double bond
+
+194
+00:18:08,890 --> 00:18:13,350
+ايش عليها اتشوميثل مختلفتان و هذا ال double bond
+
+195
+00:18:13,350 --> 00:18:19,250
+ايش عليها اوميثل و carbon مختلفتان اذا هذا المركب
+
+196
+00:18:19,250 --> 00:18:23,310
+منه واحد ولا اتنين اتنين اتنين لو قلتلكوا ارسموا
+
+197
+00:18:23,310 --> 00:18:27,810
+العيزو مرة تانية ايش أسهل طريقةلأ خدوه نحط ال اتش
+
+198
+00:18:27,810 --> 00:18:34,190
+تحت و الميثل فوق الان اتش و ميثل من الأعلى الميثل
+
+199
+00:18:34,190 --> 00:18:38,770
+الميثل لحظه هذه اللي ماتروه كهيك ميثل مش اتش انا
+
+200
+00:18:38,770 --> 00:18:43,030
+متعمد اتروه كهيك عشان أبقوا منتبهين لها ميثل اه هي
+
+201
+00:18:43,030 --> 00:18:51,270
+هذه الأعلى O و Carbon من الأعلى الان الأعلى على
+
+202
+00:18:51,270 --> 00:19:00,660
+جهة واحدة اذا هذا المركب Zهذا الاسم الكامل هذا دخل
+
+203
+00:19:00,660 --> 00:19:04,640
+فيه جزء من ال الكينز وجزء من ال الكينز وجزء من ال
+
+204
+00:19:04,640 --> 00:19:09,660
+ethers وهكذا العلم يصبح تجميعي لكل شيء درسناه
+
+205
+00:19:09,660 --> 00:19:15,960
+واتعلمناه اذا Z ثريميثوكسي سيكس فينوكسي توهيبتين
+
+206
+00:19:15,960 --> 00:19:18,140
+بهذا الشكل بنسمي المركب
+
+207
+00:19:22,520 --> 00:19:25,900
+طبعا ممكن تكون chiral center على طول بلاحظ R ولا S
+
+208
+00:19:25,900 --> 00:19:30,640
+هنا في chiral center لكن انا مش مركز عليه دايما
+
+209
+00:19:30,640 --> 00:19:34,340
+يعني ال chiral center اذا رسمته زي هيك معناه ذلك
+
+210
+00:19:34,340 --> 00:19:40,300
+انا طالبه منكم بس هنا بالتأكيد في chiral center لو
+
+211
+00:19:40,300 --> 00:19:43,800
+بدى افترض ان هدول بهذا الشكل المبينين وجهته بتكون
+
+212
+00:19:43,800 --> 00:19:49,150
+حددهدائما الكايرال سنتر إذا رسمناه كيا زي الصليب
+
+213
+00:19:49,150 --> 00:19:53,210
+معنا ذلك إحنا مركزين عليه مع ذلك تركينه بس هو أكيد
+
+214
+00:19:53,210 --> 00:19:59,350
+يا R يا S بس معرفين كوا ان كوا اتجاوبوا واضحة
+
+215
+00:19:59,350 --> 00:20:03,270
+الفكرة يعني يوم ما بدي الكايرال سنتر لو كنت بدي
+
+216
+00:20:03,270 --> 00:20:07,690
+بالتأكيد الكايرال سنتر هنا هتلاقوني رسمت الكيا زي
+
+217
+00:20:07,690 --> 00:20:17,330
+هيك O فنل CH3 H ال Aهنا بالتأكيد في عندكم chiral
+
+218
+00:20:17,330 --> 00:20:20,990
+center و المفروض تقدروا تعملوه و تقدروا تقولوا انه
+
+219
+00:20:20,990 --> 00:20:26,570
+أقل حاجة ال H ال O أعلى اشي بعدين الكربون المتصلة
+
+220
+00:20:26,570 --> 00:20:33,990
+بكربونات بعدين هذه S إذا chiral center واحد بلزمش
+
+221
+00:20:33,990 --> 00:20:40,170
+أحط له رقم إذا أكثر ممكن أحدد وين موقعه واضح؟ كل
+
+222
+00:20:40,170 --> 00:20:42,210
+شيء ممكن أدخله في الاسم
+
+223
+00:21:04,730 --> 00:21:09,810
+الان بالنسبة لل ethers استعملوا سابقا كمواد مخدرة
+
+224
+00:21:09,810 --> 00:21:14,670
+anesthetics والان بعض المشتقات منها زي هذا المركب
+
+225
+00:21:14,670 --> 00:21:17,450
+اللي فيه ذرات floro و chloro بناهاش نحفظه اسمه
+
+226
+00:21:17,450 --> 00:21:20,790
+penanthrene او هذا اللي فيه floro و chloro
+
+227
+00:21:20,790 --> 00:21:25,810
+enanthrene تستعمل في التخدير الطبي ال halogenated
+
+228
+00:21:25,810 --> 00:21:28,970
+ethers they are common anesthetics anesthetics
+
+229
+00:21:28,970 --> 00:21:33,650
+يعني مواد تستخدم في التخدير الطبيبدنا ننتبه لنقطة
+
+230
+00:21:33,650 --> 00:21:37,830
+كتير مهمة مش هنفصل فيها لكن الآن بنحكيها اللي ال
+
+231
+00:21:37,830 --> 00:21:42,410
+ether إذا خزنا لفترة طويلة بالذات بعد ما نفتح ال
+
+232
+00:21:42,410 --> 00:21:49,650
+bottle و يتعرض لل oxygenبيعمل مادة متفجرة peroxide
+
+233
+00:21:49,650 --> 00:21:54,530
+وبالتالي ممكن الشخص يجي يسخله طبعا مش عليها مباشرة
+
+234
+00:21:54,530 --> 00:21:59,950
+على سخان كهربائي مغلق اللي بنسميه tablet يكون فيه
+
+235
+00:21:59,950 --> 00:22:04,380
+المواد المتفجرة يروح ينفجر فيهالان هذه المواد
+
+236
+00:22:04,380 --> 00:22:08,320
+المتفجرة أشهر إيثر عادة بيستخدم اللي هو الـ
+
+237
+00:22:08,320 --> 00:22:13,800
+Diethyl Ether الان هذا لو انخزن لفترة طويلة بتفعل
+
+238
+00:22:13,800 --> 00:22:18,600
+مع الأكسجين بيعمله مركب زي هذا بيروكسايد هذا
+
+239
+00:22:18,600 --> 00:22:23,680
+البروكسايد ايش ماله؟Explosive الآن حسب كمية
+
+240
+00:22:23,680 --> 00:22:28,280
+الخزانة لو اتخزن كتير في جو سيء ممكن يعمل peroxide
+
+241
+00:22:28,280 --> 00:22:32,640
+ويترسب و تشوفوا بعينكم ان في قلب البوتل ال ether
+
+242
+00:22:32,640 --> 00:22:37,260
+مادة صلبة لو كانت بكمية صغيرة ممكن تكون دايب وما
+
+243
+00:22:37,260 --> 00:22:41,610
+تشوفوش بالعينينفي كل الأحوال لما بتحولوا لجزء عملي
+
+244
+00:22:41,610 --> 00:22:44,650
+أو بتاخدوا في يوم من الأيام جزء عملي المفروض
+
+245
+00:22:44,650 --> 00:22:48,530
+تفاصيل كيف نفحص ال ether كيف نتأكد منه قبل ما
+
+246
+00:22:48,530 --> 00:22:53,690
+نشتغل عليه هذا الأمر بتتعلموه الان لو في المستقبل
+
+247
+00:22:54,160 --> 00:22:58,620
+أشتغلت بكالوريوس، ماجستير، باحث في إيثر تسخين، في
+
+248
+00:22:58,620 --> 00:23:02,740
+هذه اللحظة خدوا كلمة واحدة إن الإيثر في منه خطر أن
+
+249
+00:23:02,740 --> 00:23:06,820
+يكون مواد متفجرة يوم ما يطلب منكوا حقيقة تشتغلوا و
+
+250
+00:23:06,820 --> 00:23:10,820
+تسخنوا بالإيثر ارجعوا لهذه المعلومة في كل كتب
+
+251
+00:23:10,820 --> 00:23:16,130
+العمل بدلكم بتفاصيل أكتر كيف تتأكدواإنه هالمادة
+
+252
+00:23:16,130 --> 00:23:19,850
+موجودة ولا لأ و لو موجودة كيف تتخلصوا منها و كل
+
+253
+00:23:19,850 --> 00:23:23,350
+الأشياء التفصيلية هذه لكن خلوا في ذهنكوا ان ال
+
+254
+00:23:23,350 --> 00:23:27,950
+ether مع سوق التخزين و في وجود ال oxygen بيعمل إيش
+
+255
+00:23:27,950 --> 00:23:36,090
+explosivematerials الان كيف بنحضر ال ethers اخدنا
+
+256
+00:23:36,090 --> 00:23:42,310
+احنا تحضير لل ethers لما درسنا ال alkenes و ال
+
+257
+00:23:42,310 --> 00:23:48,250
+alcohols قولنا ان ال alcohol لو سخناه عند 180 درجة
+
+258
+00:23:48,250 --> 00:23:54,460
+مئوية كان يعمل حذف للميه و يعطيناالالكين و عند 140
+
+259
+00:23:54,460 --> 00:23:59,520
+درجة مئوية بيعطينا ال ether متذكرين هذه المعادلة
+
+260
+00:23:59,520 --> 00:24:03,300
+في كيمية ال alcohols اذا ال ethers they can be
+
+261
+00:24:03,300 --> 00:24:07,000
+prepared from alcohols طبعا انا لما بحكي عن ether
+
+262
+00:24:07,000 --> 00:24:11,450
+هنا بحكي عن ال symmetrical ethersماذا؟ إن إيثانول
+
+263
+00:24:11,450 --> 00:24:15,450
+يهاجم على إيثانول ويفقد ميّه وهذه المعادلة سابق
+
+264
+00:24:15,450 --> 00:24:20,190
+وضحتها إيها إيثانول زي إيثانول يخص منهم ميّه يعني
+
+265
+00:24:20,190 --> 00:24:24,770
+هذه المعادلة لو أريدها موزنة، ماذا أكتب هنا؟ H2O
+
+266
+00:24:24,770 --> 00:24:29,110
+واضح؟ جزء يهاجم على التانى ويطلع ميّه ويكون له
+
+267
+00:24:29,110 --> 00:24:34,880
+إيثرالان هذا الـ symmetrical ether ان الاثانول
+
+268
+00:24:34,880 --> 00:24:39,720
+اتفعل مع نفسه طيب يا تورا الان بيجيني السؤال لو
+
+269
+00:24:39,720 --> 00:24:45,320
+بدي un symmetrical ether يعني بدي ether في اثل و
+
+270
+00:24:45,320 --> 00:24:51,400
+مثل ايش اول شيء ممكن يخطر ع بالكم يعني لو بدي انا
+
+271
+00:24:51,400 --> 00:24:56,000
+دايم في ال ether شو اللي بسخنه مع الحامض؟ميثانول
+
+272
+00:24:56,000 --> 00:24:59,760
+لو بدى داي إثل إيثار شو اللى بسخنه مع الحامض
+
+273
+00:24:59,760 --> 00:25:05,540
+إثانول طيب لو بدى مثل إثل إيثار شو بدى أسخن مع
+
+274
+00:25:05,540 --> 00:25:09,500
+الحامض واضحة
+
+275
+00:25:09,500 --> 00:25:17,160
+الفكرة لو بدى مثل إثل إيثارأو إثل مثل إيثار الأن
+
+276
+00:25:17,160 --> 00:25:22,520
+انتبهوا معي أي واحدة ممكن تبدأ التفكير في مثل إثل
+
+277
+00:25:22,520 --> 00:25:28,400
+إيثار تقول باخد ال two alcohols يعني باخد مثل OH
+
+278
+00:25:28,400 --> 00:25:40,120
+زائد إثل OH بده يطلع لمثل OH إيش رأيكوا بهذا
+
+279
+00:25:40,120 --> 00:25:40,780
+الكلام؟
+
+280
+00:25:43,190 --> 00:25:47,830
+بطلع لكن هنا في مشكلة انه انا لما بخلط بخلطش جزئ و
+
+281
+00:25:47,830 --> 00:25:52,030
+جزئ بخلط عدد كبير يعني لو خلطت mall و mall يعني
+
+282
+00:25:52,030 --> 00:25:55,990
+انا خلطت 6 في 10 او 23 من هذا مع 6 في 10 او 23 من
+
+283
+00:25:55,990 --> 00:26:00,290
+هذا الان كلهم موجودين خليني اعملها على النطاق
+
+284
+00:26:00,290 --> 00:26:06,110
+البسيط لو على نطاق جزيئين هذا ال ethanol و هذا ال
+
+285
+00:26:06,110 --> 00:26:09,600
+methanol و خلطتهم و قلتلهم يلا اتفاعلواأيش
+
+286
+00:26:09,600 --> 00:26:13,600
+الاحتمالات؟ هم بتفعلوا، سمعين؟ الان ممكن يلتقي
+
+287
+00:26:13,600 --> 00:26:20,260
+الاثل مع الاثل بي اثل اثر ممكن يلتقي المثل مع
+
+288
+00:26:20,260 --> 00:26:27,420
+المثل بي مثل اثر ممكن يلتقي الاثل مع المثل اثر مثل
+
+289
+00:26:27,420 --> 00:26:35,740
+اثر اذا هنا كم ناتج نتوقع؟ تلاتة مثل او مثل اثل او
+
+290
+00:26:35,740 --> 00:26:41,970
+اثلأو إثل أو ميثل بيطلع لكن مع اتنين تانين يعني
+
+291
+00:26:41,970 --> 00:26:46,310
+بيطلع خليط من تلت مراكبات و هات وفصلهم هل هذا
+
+292
+00:26:46,310 --> 00:26:51,890
+الكلام الكيميائي بيحبه؟ اطلاقا لا ولذلك اي حد
+
+293
+00:26:51,890 --> 00:26:56,590
+بيقول انه تحضير الإثل مثل إيثر بخلط الكحولينوهي
+
+294
+00:26:56,590 --> 00:27:00,530
+طلع الجواب بنقوله غلط لأنك طلعت تلت نواتج وبعدين
+
+295
+00:27:00,530 --> 00:27:05,170
+بدنا نشتغل نعمل انفصل وتقطير، هذه عملية إيش مالها؟
+
+296
+00:27:05,170 --> 00:27:09,610
+متعبة ولذلك بنحول على طريقة تانية في تحضير الـ
+
+297
+00:27:09,610 --> 00:27:15,160
+Unsymmetrical ethos أيضا بنبتدأ فيها من وين؟من
+
+298
+00:27:15,160 --> 00:27:20,340
+الكحولات الان الكحولات واحد منهم وبشكل عام اللي
+
+299
+00:27:20,340 --> 00:27:25,520
+بيكون primary بنخليه يصير chloride يعني هذا لو
+
+300
+00:27:25,520 --> 00:27:32,900
+فعلناه مع ال BCl3 ايش هيصير CH3 CH2 بدل ما هو OH
+
+301
+00:27:32,900 --> 00:27:39,020
+Cl حولته ل chloride والتالي بحوله ل O minus كيف
+
+302
+00:27:39,020 --> 00:27:43,010
+الكحول بيصير O minus؟بالتفاعل مع السوديوم
+
+303
+00:27:43,010 --> 00:27:48,290
+هيدروكسايد؟ قلنا لأ بالتفاعل مع السوديوم أو
+
+304
+00:27:48,290 --> 00:27:51,890
+السوديوم هيدرايد هدولة التنين اللي بيصيروا يعني
+
+305
+00:27:51,890 --> 00:27:57,750
+هذا لو فعلته مع السوديوم بيصير مثل O minus and A
+
+306
+00:27:57,750 --> 00:28:04,840
+plusهيو ب فلاسك لحاله و هذا ب فلاسك لحاله لسه
+
+307
+00:28:04,840 --> 00:28:09,360
+ماخلطتهمش يعني إيجي إنسان أعطاكم هاي إيثانول و هاي
+
+308
+00:28:09,360 --> 00:28:13,420
+ميثانول هذا بالفلاسك واحد منهم بخليه ايش O minus
+
+309
+00:28:13,420 --> 00:28:19,900
+والتاني اكلورايد بعدين بضيف التانين على بعض بعدين
+
+310
+00:28:19,900 --> 00:28:23,600
+بضيف ايش التانين على بعض لو بضيف هذا على هذا هذا
+
+311
+00:28:23,600 --> 00:28:30,490
+ال O وين هتهاجم؟و إيش هتطرد؟ ال CL تفاعل الإقدال
+
+312
+00:28:30,490 --> 00:28:37,590
+اللي أخدناه ب chapter 6 لاحظوا إيش الناتج CH3 CH2O
+
+313
+00:28:37,590 --> 00:28:45,960
+مثل أو CH3 بس مركب واحدإذا أنا لما بدي ال un
+
+314
+00:28:45,960 --> 00:28:51,060
+symmetrical ethers لأخلط الكحولين مع بعض لأ واحد
+
+315
+00:28:51,060 --> 00:28:56,240
+منهم بحاوله ل O minus و واحد منهم بحاوله الى
+
+316
+00:28:56,240 --> 00:29:00,000
+chloride او bromide و بعدين بضيفهم مع بعض بطلعولي
+
+317
+00:29:00,000 --> 00:29:04,780
+فقط ناتج واحد هذه الطريقة في التحضير اسمها طريقة
+
+318
+00:29:04,780 --> 00:29:10,230
+السيد William Sun William Sun's synthesisWilliam
+
+319
+00:29:10,230 --> 00:29:14,410
+Sun's synthesis موجودة عندكم في ال slides وهين
+
+320
+00:29:14,410 --> 00:29:18,770
+وضحت بطريقة تانية انه مانخلطش الكحولين مع بعض
+
+321
+00:29:18,770 --> 00:29:24,090
+اطلاقا اطلاقا هذا الكلام مابيصيرش واضح الفكرة؟
+
+322
+00:29:30,200 --> 00:29:34,580
+نشوف مرة تانية الـ Williamson's synthesis هاي مثلا
+
+323
+00:29:34,580 --> 00:29:40,500
+ROH مع ن إيه؟ شو أعطاني؟ R O minus هذا الـ charged
+
+324
+00:29:40,500 --> 00:29:45,300
+nucleophile و R X كوّنتها أساسا من الكحول لما أضيف
+
+325
+00:29:45,300 --> 00:29:50,800
+الـ R O minus على الـ R X أي تفاعل بعمل؟ الإبدال
+
+326
+00:29:50,800 --> 00:29:53,380
+ROR
+
+327
+00:29:54,350 --> 00:29:59,510
+الان اتخيلوا لو اتيكم how can you prepare this
+
+328
+00:29:59,510 --> 00:30:09,870
+ether فنل O CH2 CH3 الفكرة ان واحد منهم بدي اخليه
+
+329
+00:30:09,870 --> 00:30:15,330
+يعني انا بدي ابدأ من فنل OH و F OHلكن مين منهم بدي
+
+330
+00:30:15,330 --> 00:30:20,830
+أخليه O- ومين منهم بدي أخليه CL الان أنا قولت اللي
+
+331
+00:30:20,830 --> 00:30:25,610
+باخليه CL ال primary أو ال مثل إذا وجدت ما هو ال
+
+332
+00:30:25,610 --> 00:30:28,790
+مثل أفضل من ال primary يا ال primary يا المثل
+
+333
+00:30:28,790 --> 00:30:34,720
+وبناء على ذلك الفن ال OHهذا بخليه ايش مع ال sodium
+
+334
+00:30:34,720 --> 00:30:37,980
+او مع ال sodium hydroxide بيمشي اساسا لان الفينول
+
+335
+00:30:37,980 --> 00:30:41,800
+بتفاعل مع ال sodium hydroxide بيصير فينيل O minus
+
+336
+00:30:41,800 --> 00:30:48,620
+هي ال nucleophile فينيل O minus وهذا ال ethanol
+
+337
+00:30:48,620 --> 00:30:55,540
+بقدر انا اخليه من خلال التفاعل مع ال BCL3 CH3
+
+338
+00:30:55,540 --> 00:31:03,380
+CH2CL اكيدالان لو فعلت هذا ال phenoxide هنا بيطرد
+
+339
+00:31:03,380 --> 00:31:09,330
+ال X و بيعطينا المركب المطلوب ولا لأ؟واضح؟ فالفكرة
+
+340
+00:31:09,330 --> 00:31:13,150
+في هذا النوع .. الفكرة في هذا النوع من الأسئلة لما
+
+341
+00:31:13,150 --> 00:31:17,150
+أجيبلكوا ether معين و أقولكوا كيف تحضروه أنكم
+
+342
+00:31:17,150 --> 00:31:20,450
+تعرفوا مين اللي بدي أخليه منه O minus مين اللي بدي
+
+343
+00:31:20,450 --> 00:31:24,270
+أخليه chloride الآن اللي بدي أخليه ال chloride يا
+
+344
+00:31:24,270 --> 00:31:29,630
+ال methyl يا ال primary هاي مسألة هنا شايفينها
+
+345
+00:31:29,630 --> 00:31:37,760
+تيرتشاريب بيوتلبروبل إيثار كيف يمكنك تجهيزه بدأ من
+
+346
+00:31:37,760 --> 00:31:44,680
+الكحول ارسم الانتوا الكحول احفظوا انتوا ايش
+
+347
+00:31:44,680 --> 00:31:52,260
+المطلوب تيرتشار بيوتل بروبل إيثار يعني كأنه عندكم
+
+348
+00:31:52,260 --> 00:32:01,200
+انتوا معطى هاي ال تيرتشار بيوتل وهاي البروبانول
+
+349
+00:32:01,200 --> 00:32:06,700
+هاي الانتوا الكحولالان ما طريقة التحضير واحد منهم
+
+350
+00:32:06,700 --> 00:32:15,000
+O- والتاني CL مين اللي بدي أخليه CL ال primary هذا
+
+351
+00:32:15,000 --> 00:32:20,300
+ال alcohol tertiary هذا ال alcohol ال primary إذا
+
+352
+00:32:20,300 --> 00:32:27,880
+هذا بعمله مع ال BCL3 هيوصار CL وهذا بعمله مع ال NA
+
+353
+00:32:27,880 --> 00:32:36,510
+هيوصار O-الان اخلطوا هادولا التانين مع بعض ايش
+
+354
+00:32:36,510 --> 00:32:40,910
+النتيجة؟
+
+355
+00:32:40,910 --> 00:32:47,640
+هادي هتهاجم هان و تطردالـ CL المُركّب المطلوب مرات
+
+356
+00:32:47,640 --> 00:32:51,860
+لما يقولوا المُركّب المطلوب بيحطوا رمز TM مر عليكم
+
+357
+00:32:51,860 --> 00:32:55,620
+إيش يعني الـTM؟ زي ما في الهندس لما بتخلصوا الشغلة
+
+358
+00:32:55,620 --> 00:33:00,020
+بتقولوا هو المطلوب إثباته الآن TM يعني ال target
+
+359
+00:33:00,020 --> 00:33:05,020
+molecule يعني الجزء المطلوب target إيش target؟
+
+360
+00:33:05,020 --> 00:33:11,520
+molecule الجزء المطلوب يعنييعني الـTM بلغة الكيميا
+
+361
+00:33:11,520 --> 00:33:15,820
+وهو المطلوب طبعاً هيكون زي هيك O وهي واحد، اتنين،
+
+362
+00:33:15,820 --> 00:33:21,100
+تلاتة واضحات؟
+
+363
+00:33:21,100 --> 00:33:24,580
+الان لو واحدة عكست عملت هذا ال chloride وهذا الـO
+
+364
+00:33:24,580 --> 00:33:29,760
+minus بطلعش عندها يعني لو السؤال عليه عشر علامات
+
+365
+00:33:29,760 --> 00:33:35,900
+مجاملة نحط لها تلاتة او تنين لأنه
+
+366
+00:33:35,900 --> 00:33:42,040
+عملياً مابصيرشواضح؟ عملياً ما بيصيرش افهمنا هذه
+
+367
+00:33:42,040 --> 00:33:59,680
+الفكرة بوليام سانس سينتيسيز الان
+
+368
+00:33:59,680 --> 00:34:06,640
+ال ethers اتكونت طيب يا تورا ممكن تنكسبممكن تتفاعل
+
+369
+00:34:06,640 --> 00:34:10,900
+إلا بس تفاعل واحد فقط اللي هو الـ cleavage of
+
+370
+00:34:10,900 --> 00:34:16,020
+ether يعني ممكن ينكسر نص سيلة كيف بتم ال cleavage
+
+371
+00:34:16,020 --> 00:34:23,220
+of ether باستعمال الحامض القوي HI الـ HI بيهاجم
+
+372
+00:34:23,220 --> 00:34:30,020
+عادة في اليود وهذا هيو ماشي وين بده يروحالـ W مع
+
+373
+00:34:30,020 --> 00:34:33,200
+.. لأ على الـ Carbon اللي جنب الـ O الـ U السالب
+
+374
+00:34:33,200 --> 00:34:36,080
+.. الـ O السالب على الـ Carbon من بين الموجبات الـ
+
+375
+00:34:36,080 --> 00:34:39,360
+principal يعني هنا هذه الـ Carbon الموجبة و هذه
+
+376
+00:34:39,360 --> 00:34:43,860
+الموجبة هذه السالبة جزئياً لما بده يروح .. وين بده
+
+377
+00:34:43,860 --> 00:34:47,880
+يروح؟ على الموجب .. الآن لاحظوا معي لما بده يروح
+
+378
+00:34:47,880 --> 00:34:52,820
+على الموجب هيو ماشي ورايح على الموجب اليمين و لا
+
+379
+00:34:52,820 --> 00:34:58,480
+الموجب الشمالي افهمتوا وين السؤال؟ الآن على الـ
+
+380
+00:34:58,480 --> 00:35:05,900
+Primaryهذا المحور الان وين ال primary هان؟ وين ال
+
+381
+00:35:05,900 --> 00:35:12,420
+primary هان؟ ولذلك لما تطلع النتيجة هذا الجزء اللي
+
+382
+00:35:12,420 --> 00:35:18,340
+بيبقى معه ال O هياخد ال H هيصير فين ال O؟ H هياخد
+
+383
+00:35:18,340 --> 00:35:25,180
+ال H وهذا الجزء CH3 CH2 هيصير ايش؟Iodide شوفنا كيف
+
+384
+00:35:25,180 --> 00:35:29,780
+الـ cleavage الان هذا ماشي هنا ايه هنا؟ هيعطيني
+
+385
+00:35:29,780 --> 00:35:37,660
+CH3 CH2 CH2 I هذا معلوم CH3 CH2 CH2 I و هذا اللي
+
+386
+00:35:37,660 --> 00:35:43,380
+ضلت معه ال O شو هيصير OH هذا اللي هو ال cleavage
+
+387
+00:35:43,380 --> 00:35:50,680
+of ether هذا اللي هو ال cleavage of ether
+
+388
+00:35:52,990 --> 00:35:58,330
+باستعمال الـ HI غير هيك مش مشهور تفاعلات لل إيثارز
+
+389
+00:35:58,330 --> 00:36:03,310
+يعني هو تفاعل واحد الـ cleavage الكسر الآن في
+
+390
+00:36:03,310 --> 00:36:08,450
+إيثارز حلقية اسمها الـ Epoxides أخدتها بالتفصيل هي
+
+391
+00:36:08,450 --> 00:36:12,990
+و تفاعلاتها ولا لأ لما أخدنا تفاعلات الالكين و
+
+392
+00:36:12,990 --> 00:36:16,990
+قلنا الكين مع pear acid Epoxides وأخدتوا كمان
+
+393
+00:36:16,990 --> 00:36:21,670
+الحلقة بتفتح هنا واضحة
+
+394
+00:36:21,670 --> 00:36:26,890
+الفكرةأخدتوا كيف الحلقة بتفتح و كل هذا الكلام كل
+
+395
+00:36:26,890 --> 00:36:32,530
+هذه ال slides نفسها أخدناها الآن بيجينا آخر slide
+
+396
+00:36:32,530 --> 00:36:37,090
+اليوم عندنا هل ال cyclic ethers بس الحلقات
+
+397
+00:36:37,090 --> 00:36:43,430
+الثلاثية لأ طبعا في cyclic ethers حلقات أكبر يعني
+
+398
+00:36:43,430 --> 00:36:49,540
+مثلا الحلقة الخماسية هذا ether ORRcyclic ether
+
+399
+00:36:49,540 --> 00:36:54,820
+اسمه tetrahydrofuran باختصار THF هذا solvent مشهور
+
+400
+00:36:54,820 --> 00:37:02,360
+طب هذه الحلقة اسمها tetrahydropyrene هذا في ether
+
+401
+00:37:02,360 --> 00:37:08,060
+و ether دي ether ORR و ORR اسمه ديوكسين مركب
+
+402
+00:37:08,060 --> 00:37:14,300
+كارسينوجينيك مركب كارسينوجينيك وسام في مركبات حلوة
+
+403
+00:37:14,300 --> 00:37:19,260
+طلع عليها منظرها حلو ولا لأو دايما الاشي المنظرة
+
+404
+00:37:19,260 --> 00:37:23,980
+حلو بيحاولوا يعطوا اسم ايش اسم حلو يعني العلماء
+
+405
+00:37:23,980 --> 00:37:28,160
+لما بيعملوا اختراع لشغل مرات بيعملوا مسابق مين
+
+406
+00:37:28,160 --> 00:37:32,640
+يخترعلها اسم حلو و لو بتفتشوا مثلا لما اكتشفوا
+
+407
+00:37:32,640 --> 00:37:39,640
+نايلون كشيء جميل ليش في النهاية سموه نايلون؟اسم
+
+408
+00:37:39,640 --> 00:37:44,360
+حلو عملوا مسابقات لحد ما حد اخترع لهم اسم جميل زي
+
+409
+00:37:44,360 --> 00:37:47,520
+اللي بده يفتح بوتيك ولا اشي مش بيحاول يلاجيله اسم
+
+410
+00:37:47,520 --> 00:37:52,380
+حلو هدول عشانهم حلوين شو صموهم ال crown ethers
+
+411
+00:37:52,380 --> 00:37:58,020
+هدول اكتشفوهم مش زمان يعني بعد ال 1980 تقريبا
+
+412
+00:37:58,020 --> 00:38:02,460
+واللي اكتشفوهم أخدوا عليهم جائزة نوبل في الكيميا
+
+413
+00:38:02,460 --> 00:38:09,600
+بال 1987 اسمهم ايش ال crown ethersإيش قصته ما دول
+
+414
+00:38:09,600 --> 00:38:15,220
+ال crown ethers؟ أكسجين بعدين CH2 CH2 بعدين أكسجين
+
+415
+00:38:15,220 --> 00:38:19,980
+CH2 CH2 بعدين أكسجين هم لاحظين أكثر من ether في
+
+416
+00:38:19,980 --> 00:38:23,820
+بعض طب لما بدهم يسموهم قالوا كيف بدنا نسميهم؟ هاي
+
+417
+00:38:23,820 --> 00:38:29,780
+واحدة و هادي أكبر و هادي أكبر قال بسيطة استعملوا
+
+418
+00:38:29,780 --> 00:38:34,140
+اسم ال crown okay crown قالوا قبل ال crown عدوا كل
+
+419
+00:38:34,140 --> 00:38:39,130
+الذرات المحيطة يعني لو بديت أعد من هنا واحدأتنين
+
+420
+00:38:39,130 --> 00:38:43,550
+تلاتة أربعة خمسة لفتهم كلهم بلاحظ انه العدد الكل
+
+421
+00:38:43,550 --> 00:38:48,390
+اتنائش فبروح بكتب ال twelve يعني العدد الكل قداش
+
+422
+00:38:48,390 --> 00:38:53,730
+اتنائش ال crown كام اكسوجينة عندكم اربعة twelve
+
+423
+00:38:53,730 --> 00:38:59,930
+crown four الان هذا العدد الكل خمس عشر خمس
+
+424
+00:38:59,930 --> 00:39:05,790
+اكسوجينات شو حيصير fifteen crown five هذا
+
+425
+00:39:10,900 --> 00:39:17,000
+واضح؟طيب فى ناس لسه مقتنعوش بيقولوا يعنى ليش أخدوا
+
+426
+00:39:17,000 --> 00:39:21,760
+جائزة نوبل على شغل زى هذه يعنى سويانا الان لاحظوا
+
+427
+00:39:21,760 --> 00:39:26,100
+هدولة فى اللهم تجويف هنا عارفين التجويف شو بيسموه
+
+428
+00:39:26,100 --> 00:39:31,160
+بالإنقليزي cavity ممتازين جدا اللهم cavity ال
+
+429
+00:39:31,160 --> 00:39:34,520
+cavity هذه ممكن يدخل ضيف عليها يعنى هم يكونوا
+
+430
+00:39:34,520 --> 00:39:40,390
+المضيف ايش معناه المضيف hostممكن ييجي guest يدخل
+
+431
+00:39:40,390 --> 00:39:44,290
+جوا زي ما البني آدم عنده قوضة لضيوف و بيجي ضيف
+
+432
+00:39:44,290 --> 00:39:48,010
+يدخل فيها طب لو بدنا نجيب ضيف يدخل هنا، إيش بده
+
+433
+00:39:48,010 --> 00:39:53,650
+يكون هذا الضيف؟ اطلعولي إن ال oxygen يحمل أزواج
+
+434
+00:39:53,650 --> 00:39:54,850
+إلكترونات
+
+435
+00:39:57,510 --> 00:40:00,990
+و بدو يجي يضيفي بوسط هالسحابة الإلكترونية، شو بدو
+
+436
+00:40:00,990 --> 00:40:07,330
+يكون؟ موجب، ايش أشهر الموجب؟ الـmetal ions، Sodium
+
+437
+00:40:07,330 --> 00:40:13,330
+Plus, Potassium Plus, Cesium Plus و هكذا، اذا هنا
+
+438
+00:40:13,330 --> 00:40:19,440
+لما بدو يدخل، ايش هيدخل؟ Metal Plusلأن الجو العام
+
+439
+00:40:19,440 --> 00:40:25,160
+كله سالب اللي بدو يجي يدخل إيش؟ معدن موجب طب الآن
+
+440
+00:40:25,160 --> 00:40:29,000
+اتطلعولي على ال cavities ال cavities هذه إلها
+
+441
+00:40:29,000 --> 00:40:33,320
+أحجام ولا كلها نفس الحجم؟ أحجام طب و آيونات
+
+442
+00:40:33,320 --> 00:40:40,860
+المعادن مش في الجدول الدوري عندكم ن إيه؟ بوتاسيوم؟
+
+443
+00:40:40,860 --> 00:40:47,450
+سيزيوم؟الان هذا حجمه صغير، هذا أكبر، هذا أكبر، إذا
+
+444
+00:40:47,450 --> 00:40:53,590
+هل كل Ion بيجي على كل cavity ولا فيه تناسو؟ Ion
+
+445
+00:40:53,590 --> 00:40:58,650
+معين بيدخل ب cavity معينة Ion معين بيدخل بcavity
+
+446
+00:40:58,650 --> 00:41:03,730
+معينة يعني مثلا هذا المركب ال 18 crown 6 لما جاسوا
+
+447
+00:41:03,730 --> 00:41:08,230
+حجم ال cavity تبعتهبين اتنين و ستة من عشرة لتلاتة
+
+448
+00:41:08,230 --> 00:41:12,030
+و اتنين من عشرة أنجسترون طب حجم ايون الصوديوم واحد
+
+449
+00:41:12,030 --> 00:41:15,510
+و تسعة واحد و تسعة لو حطناه من هنا إيش بيعمل
+
+450
+00:41:15,510 --> 00:41:21,490
+الفتحة كبيرة عليه بيجع منها ال cesium تلاتة و
+
+451
+00:41:21,490 --> 00:41:27,550
+تلاتة أكبر من الفتحة بيدخلش مين اللي بتناسب معها
+
+452
+00:41:27,550 --> 00:41:31,990
+اتنين و ستة و ستين وهذه اتنين و ستة لتلاتة و اتنين
+
+453
+00:41:32,930 --> 00:41:37,910
+البوتاسيوم إذا لو حطينا ال crown الآن و جيبنا
+
+454
+00:41:37,910 --> 00:41:42,650
+التلت أيونات معادن هو فيه cavity الان ال cavity
+
+455
+00:41:42,650 --> 00:41:50,330
+واحد صغير بيدخل منها بيوقع والتاني كبير ما بيجيش
+
+456
+00:41:50,330 --> 00:41:54,970
+والتالت المتناسب مين اللي هيقعد في قلب ال cavity؟
+
+457
+00:41:55,610 --> 00:42:01,130
+البوتاسيوم اذا هذا ال crown صار لو حطناله التلاتة
+
+458
+00:42:01,130 --> 00:42:05,390
+صاد منهم البوتاسيوم و ساب التانين التانين عارفين
+
+459
+00:42:05,390 --> 00:42:09,990
+الفكرة زي ايش؟ زي الشبكة تبعت صيادين السمك صياد
+
+460
+00:42:09,990 --> 00:42:13,530
+السمك عنده اكتر من شبكة لكل موسم كل شبكة فيها حجم
+
+461
+00:42:13,530 --> 00:42:19,110
+اليوم لما بدو يصيد البوري عنده حجم معين بيمسك سمكة
+
+462
+00:42:19,110 --> 00:42:24,200
+البوري طب و السردين؟في شبكة البوري بيدخل و بيطلع
+
+463
+00:42:24,200 --> 00:42:27,320
+قدامه هو مش ناوي يصيده بيدخل و بيطلع أو السمك
+
+464
+00:42:27,320 --> 00:42:30,460
+الصغير لما بديه يصيد السردين شو بديه يستعمل إلها؟
+
+465
+00:42:30,460 --> 00:42:35,000
+شبكة أصغر أفهمتوا إيش الفكرة هنا في ال host و ال
+
+466
+00:42:35,000 --> 00:42:39,840
+guest؟ إنه ال guest الضيف اللي بديه ييجي هنا اللي
+
+467
+00:42:39,840 --> 00:42:44,560
+هو المثل هذا ال guest لازم يكون حجمه متناسب مع
+
+468
+00:42:44,560 --> 00:42:51,240
+إيش؟ مع ال cavity وهذا الكلام له حتى تطبيقات في
+
+469
+00:42:51,240 --> 00:42:56,940
+وين؟في المجال الطبي في الأدوية يعني آخر slide الآن
+
+470
+00:42:56,940 --> 00:43:03,220
+عندنا هاي هذا المركب في نفس الفكرة بطريقة أو باخره
+
+471
+00:43:03,220 --> 00:43:10,380
+و في cavity هناhigh cavity هذه الكفتي تبعته افتسع
+
+472
+00:43:10,380 --> 00:43:16,300
+البوتاسيوم يعني لما يكون فيه نا بلس وبوتاسيوم بلس
+
+473
+00:43:16,300 --> 00:43:20,980
+في جسم الإنسان من اللي بيدخل في الكفتي البوتاسيوم
+
+474
+00:43:20,980 --> 00:43:25,940
+الآن هذا المضاد الحيوي بدخل جوا الخلية لما يدخل
+
+475
+00:43:25,940 --> 00:43:31,500
+بدخل بما حمل إذا إيش جدر يدخل جوا الخلية؟
+
+476
+00:43:32,150 --> 00:43:37,190
+البوتاسيوم ايش صاب برا الخلية الصوديوم بنسمي هذه
+
+477
+00:43:37,190 --> 00:43:43,630
+العملية ايش selective transport يعني هو دخل واحد
+
+478
+00:43:43,630 --> 00:43:50,770
+من اتنين هي الخلية هي جدارها هذه هي الخلية المضاد
+
+479
+00:43:50,770 --> 00:43:55,560
+بيقدر يدخل في جلب الخليةو بيقدر يحمل واحد من
+
+480
+00:43:55,560 --> 00:43:58,620
+الاتنين، مين اللي بيقدر يحمله؟ ال potassium
+
+481
+00:43:58,620 --> 00:44:01,920
+المتناسب مع حجم ال cavity بناء على ذلك هو في الأول
+
+482
+00:44:01,920 --> 00:44:05,500
+بيحمل ال potassium، بعدين هو بما حمله بيدخل جوا
+
+483
+00:44:05,500 --> 00:44:11,000
+الخلية بزامو دخل، نجل ال potassium من برا لجوا
+
+484
+00:44:11,700 --> 00:44:15,900
+فاهمتوا أين الجمال بفكرة crown ethers يعني بسرها
+
+485
+00:44:15,900 --> 00:44:21,900
+انعكاس على واقع التطبيق الطبي بهك بنكون أنهينا هذا
+
+486
+00:44:21,900 --> 00:44:24,140
+ال chapter اللي اسمه ال ethers
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/L036VR_7BVU_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/L036VR_7BVU_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..945958f6bb3e43700e703f3c6e821501612c9e3c
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/L036VR_7BVU_postprocess.srt
@@ -0,0 +1,1832 @@
+1
+00:00:21,210 --> 00:00:26,340
+بسم الله الرحمن الرحيمباقي عندنا في موضوع
+
+2
+00:00:26,340 --> 00:00:30,340
+التفاعلات او التفاعلات المرتبطة بال
+
+3
+00:00:30,340 --> 00:00:34,940
+stereochemistry شغلتين بسيطات احنا اتكلمنا في
+
+4
+00:00:34,940 --> 00:00:38,600
+الاول على نقطة كتير مهمة او على تفاعل كتير مهم
+
+5
+00:00:38,600 --> 00:00:43,740
+قولنا دائما في المختبر بالوضع الطبيعي لما نعمل
+
+6
+00:00:43,740 --> 00:00:47,560
+generation of a chiral center بيطلع عندى racemic
+
+7
+00:00:47,560 --> 00:00:50,400
+mixture equal mixture of enantiomers و هذا بده
+
+8
+00:00:50,400 --> 00:00:54,830
+غلبة و بده فصل و ما إلى ذلكوالان بيحاولوا انهم
+
+9
+00:00:54,830 --> 00:00:59,250
+يتغلبوا على هذا الكلام من خلال تقنيات حديثة في
+
+10
+00:00:59,250 --> 00:01:04,390
+التحضير بيسموها asymmetric synthesis هذا التفاعل
+
+11
+00:01:04,390 --> 00:01:10,030
+الأولالتفاعل التاني، لو أنا يا تورا بعمل تفاعل
+
+12
+00:01:10,030 --> 00:01:15,450
+بعيدا عن ال chiral center، الآن إيش معنى بعيدا عن
+
+13
+00:01:15,450 --> 00:01:21,310
+ال chiral center؟ بمعنى لأكسر رابطة متصلة بال
+
+14
+00:01:21,310 --> 00:01:25,330
+chiral center، يعني الأربع روابط المتصلين بال
+
+15
+00:01:25,330 --> 00:01:30,950
+chiral center بكسرهم مشكل ما بعد ذلك يعتبر ايش؟
+
+16
+00:01:30,950 --> 00:01:35,230
+تفاعل بعيد عن الـ Chiral Center واضح الفكرة؟ يعني
+
+17
+00:01:35,230 --> 00:01:39,110
+مثلا في هذا المركب، عندي هنا أنا Chiral Center
+
+18
+00:01:39,110 --> 00:01:45,010
+متصل بـ Methyl و بـ Ethyl و COH و بH، الآن هذا الـ
+
+19
+00:01:45,010 --> 00:01:50,240
+Chiral Center عليه كام رابطةأربع روابط لو أنا بدي
+
+20
+00:01:50,240 --> 00:01:55,460
+أبدل مجموعة ال O H هنا اللي هي ال acidic O H
+
+21
+00:01:55,460 --> 00:02:01,200
+مجموعة ال O H الحامضية هذه كلها بمجموعة O Ethyl
+
+22
+00:02:01,200 --> 00:02:06,420
+بمعنى في الكيميا هذا التفاعل هنتعلمه بنبدل فيه ال
+
+23
+00:02:06,420 --> 00:02:12,340
+acid ل E starباستعمال التفاعل مع الكحول شيلت الـ
+
+24
+00:02:12,340 --> 00:02:19,240
+OH و خلتها ايش؟ O Ethan الان هذه الأربع رواضة كسرت
+
+25
+00:02:19,240 --> 00:02:25,380
+جزء منها؟ لأ وبناء على ذلكالجيومتري حوالين
+
+26
+00:02:25,380 --> 00:02:28,640
+الكايرال كاربون الشكل اللذس حوالين الكايرال كاربون
+
+27
+00:02:28,640 --> 00:02:33,620
+بيضل زي ما هو فأنا كأن بعمل عملية ايش نسخ و لصق
+
+28
+00:02:33,620 --> 00:02:38,960
+بلغة الكمبيوتر يعني باجي بعمل نسخ لهذا بكل موابط و
+
+29
+00:02:38,960 --> 00:02:43,740
+لاحظوا ال H باتجاه ال CO باتجاه ال CH3 ال إثل بحطه
+
+30
+00:02:43,740 --> 00:02:48,120
+هنا و بعمل التغيير اللي عندهو بناء على ذلك بنقول
+
+31
+00:02:48,120 --> 00:02:52,740
+انه تم عنده retention of configuration يعني الشكل
+
+32
+00:02:52,740 --> 00:02:58,360
+ضل زي ما هو اتجاه الاربع روابط اللي محيطين بال
+
+33
+00:02:58,360 --> 00:03:03,440
+chiral center ضالهم ايش زي ما هو لو انا بدي اعطيكم
+
+34
+00:03:03,440 --> 00:03:07,700
+مثال يعني تخيلوا مثلا انا بهذا الشكل هينعمل chiral
+
+35
+00:03:07,700 --> 00:03:12,260
+center من اربع شغلاتوأتيت أعمل التفاعل هنا كان
+
+36
+00:03:12,260 --> 00:03:15,900
+مافيش في إيدي جلم امسكت جلم هل غيرت في اتجاه
+
+37
+00:03:15,900 --> 00:03:19,480
+الأربع روابط ولا في عند retention of configuration
+
+38
+00:03:19,480 --> 00:03:23,760
+في عند retention of configuration إذا التفاعل
+
+39
+00:03:23,760 --> 00:03:28,720
+بعيدا عن ال chiral center بتم في retention of
+
+40
+00:03:28,720 --> 00:03:31,660
+configuration معنى retention of configuration أن
+
+41
+00:03:31,660 --> 00:03:36,600
+اتجاهات الروابط الأربع تبقى كما هي لم نكسر شيء
+
+42
+00:03:36,600 --> 00:03:42,300
+حولهاكذلك الحال هنا احنا حاطين مثال تاني لو فعلنا
+
+43
+00:03:42,300 --> 00:03:47,740
+هذا المركب يعلن الكايرال سنتر بدلنا هذه ال O H
+
+44
+00:03:47,740 --> 00:03:51,740
+خلناها C double bond O باستعمال اكسدة ابعام
+
+45
+00:03:51,740 --> 00:03:53,620
+المؤكسل عادة بنسميه
+
+46
+00:03:56,470 --> 00:04:01,290
+الان هذول الاربع روابط صار عندهم تغيير و لا تغيير
+
+47
+00:04:01,290 --> 00:04:06,390
+بعد الكايرالسينفاق بعد اذا كل الاتجاهات تبقى كما
+
+48
+00:04:06,390 --> 00:04:13,840
+هي CLH CH2 CH3 الـC هادىالتغير بعدها ما كسرت روابط
+
+49
+00:04:13,840 --> 00:04:16,660
+بالتصيلة بال chiral center مرة تانية في عندي
+
+50
+00:04:16,660 --> 00:04:20,280
+retention of configuration إذا ال reaction away
+
+51
+00:04:20,280 --> 00:04:23,160
+from a chiral center results in retention of
+
+52
+00:04:23,160 --> 00:04:30,000
+configuration الآن بهمني أعطي بس ملاحظة خفيفةالـ
+
+53
+00:04:30,000 --> 00:04:34,600
+retention of configuration معناه أن الأربع روابط
+
+54
+00:04:34,600 --> 00:04:39,720
+تبقى في اتجاهاتها ليس له علاقة .. ليس له علاقة
+
+55
+00:04:39,720 --> 00:04:46,100
+بكلمة R و S أنا هنا و أنا بشتغل كتبت R ولا S ولا
+
+56
+00:04:46,100 --> 00:04:50,380
+شفت أن ال R دلت R ولا ال S دلت S؟ ماجبتش سيرة
+
+57
+00:04:50,380 --> 00:04:55,100
+هالكلام، ليش؟ لأنه أنا لما بغير مجموعة هنا أو هنا
+
+58
+00:04:55,100 --> 00:05:02,890
+ممكن الأولويات تتغير؟ أكيدأكيد حتى لو غيرت مجموعة
+
+59
+00:05:02,890 --> 00:05:06,790
+بعيد ممكن يصير فيه تغيير بالأولويات و لذلك ممكن R
+
+60
+00:05:06,790 --> 00:05:11,430
+عند الضل R ممكن R تصير S ممكن S تصير R ممكن S تظل
+
+61
+00:05:11,430 --> 00:05:16,370
+S أو تتقلب إلى R هذا موضوع ما درسته انا اطلاقا انا
+
+62
+00:05:16,370 --> 00:05:21,650
+بدرس الأربع روابط في اتجاهاتهم فيهم تغيير ولا لأ
+
+63
+00:05:21,650 --> 00:05:26,020
+هى معناه retention of configuration الان R و Sمن
+
+64
+00:05:26,020 --> 00:05:31,160
+أول و جديد في عندكم اشي اسمه قواعد ترتيب المجموعات
+
+65
+00:05:31,160 --> 00:05:36,320
+حسب الأولويات واحد اتنين تلاتة اربعة بنرتبهم ضلت
+
+66
+00:05:36,320 --> 00:05:41,460
+الارار صارت اسم مش مشيء بالنسبة الي واضح الفكرة
+
+67
+00:05:41,460 --> 00:05:47,200
+فكلمة retention of configurationلا تعني اطلاقا ..
+
+68
+00:05:47,200 --> 00:05:52,700
+لا تعني اطلاقا ان ال R دلت R او ال S دلت S لأ تعني
+
+69
+00:05:52,700 --> 00:05:58,520
+ان الأربع روابط ضالهم باتجاههم ال R و ال S اولويات
+
+70
+00:05:58,520 --> 00:06:01,420
+اللي بيحسب اولويات يشوف حسب المثال اللي عنده
+
+71
+00:06:01,420 --> 00:06:05,480
+هتلاقوا مثال بتم فيه تغيير مثال بتم مش فيه تغيير
+
+72
+00:06:05,480 --> 00:06:09,460
+حسب هالمجموعة اللي طلعت و المجموعة اللي اجت هذا
+
+73
+00:06:09,460 --> 00:06:15,200
+موضوع تاني واضح الفكرة؟وهذا كثير بنسألكم بمعناه
+
+74
+00:06:15,200 --> 00:06:19,280
+انه هالمعنى كلمة retention of configuration means
+
+75
+00:06:19,280 --> 00:06:24,420
+are must be are in the product لأ مش ضروري ممكن
+
+76
+00:06:24,420 --> 00:06:29,400
+تظل ممكن تتغير هذا موضوع و هذا موضوع تاني
+
+77
+00:06:33,710 --> 00:06:39,030
+هذه تفاعلات بناخدها بعدين بس بنعطيها كأمثلة يعني
+
+78
+00:06:39,030 --> 00:06:43,710
+هذا تأكسد كحول إلى aldehyde لما ندرس chapter
+
+79
+00:06:43,710 --> 00:06:49,410
+الكحولات ب chapter 7 بنشرحه الآن بديش أنا أسمي لا
+
+80
+00:06:49,410 --> 00:06:52,750
+كحول ولا aldehyde أنا قلت ال Canada دي CO single
+
+81
+00:06:52,750 --> 00:06:57,840
+bond صارت CO double bond غيرت هان ولا لأ؟تستعجلوش
+
+82
+00:06:57,840 --> 00:07:02,880
+العلم هذا تحول حامض إلى Easter بدلت ال OH ب Oethel
+
+83
+00:07:02,880 --> 00:07:08,140
+بدرسه ب Chapter 10 مش هو موضوعي غيرت بدي ألغي كل
+
+84
+00:07:08,140 --> 00:07:13,060
+اللي كاتبه و أكتب XY عشان اترايحيني أعصابي خلت XY
+
+85
+00:07:13,060 --> 00:07:14,980
+واضح؟
+
+86
+00:07:16,500 --> 00:07:21,120
+دائما تتعبوش أنفسكم في الفكرة غير الأساسية بدلت X
+
+87
+00:07:21,120 --> 00:07:26,760
+بY إيش التفاعل مش مشكلة مش X صارت Y تفاعل general
+
+88
+00:07:26,760 --> 00:07:31,520
+بدلته بعيدا عن ال chiral center إيش بيظل عنده
+
+89
+00:07:31,520 --> 00:07:37,960
+retention إنما هدولا التفاعلين كتفصيل بناخدهم في
+
+90
+00:07:37,960 --> 00:07:43,160
+chapter 7 أو chapter 10 لكن استعانا فيهم كأمثلة
+
+91
+00:07:45,090 --> 00:07:50,130
+التفاعل التالت generation of a second chiral
+
+92
+00:07:50,130 --> 00:07:54,370
+center يعني لاحظوا احنا اول مرة قولنا ماكنش لنا
+
+93
+00:07:54,370 --> 00:07:57,390
+chiral center نهائي و عملنا له generation، شو طلع
+
+94
+00:07:57,390 --> 00:08:04,840
+عندى؟ رسمic mixtureتاني تفاعل لما اعملت تفاعل بعيد
+
+95
+00:08:04,840 --> 00:08:08,320
+عن الكايرال سنتر شو صار عندى retention of
+
+96
+00:08:08,320 --> 00:08:13,880
+configuration طيب الآن لو كان في عندى كايرال سنتر
+
+97
+00:08:13,880 --> 00:08:19,160
+اول و بدى اعمل كايرال سنتر تاني شو بده يصير عندى؟
+
+98
+00:08:19,160 --> 00:08:25,120
+خلّينا نشوف مثال هذه مثال لو طلعنا على هذا المركب
+
+99
+00:08:25,120 --> 00:08:29,880
+الآن هذه الكاربون اللى موجودة هنا بتحمل مثل
+
+100
+00:08:29,880 --> 00:08:33,970
+وchloro Hو المجموعة اللي فيها double bond كايرال
+
+101
+00:08:33,970 --> 00:08:39,290
+سنتر ولا لأ كايرال سنتر انا مش موضوعي اطلاقا هذه
+
+102
+00:08:39,290 --> 00:08:42,770
+ال carbon بدي اعمل التفاعل على ال double bond يعني
+
+103
+00:08:42,770 --> 00:08:48,160
+على ال double bond بدي اجي اضيف hbr في وجودH plus
+
+104
+00:08:48,160 --> 00:08:53,940
+هذه أخدناها إضافة Markovnikov يعني بدأ أحط ال H
+
+105
+00:08:53,940 --> 00:09:00,080
+هنا في الأول أبدأ تفاعل بإضافة ال H هنا وبعدين
+
+106
+00:09:00,080 --> 00:09:06,260
+أكمل ال PR على هذا الموقع لاحظوا إيش اللي بدو يصير
+
+107
+00:09:06,260 --> 00:09:12,060
+عندي لما أضيف ال H على هذا الموقع كام رابط هيظل
+
+108
+00:09:12,060 --> 00:09:20,250
+على هذه النقطة تلت روابط تلت روابطحاولوا تستحضروا
+
+109
+00:09:20,250 --> 00:09:24,510
+الشكل مع الهيدروجين المحذوف مع الهيدروجين المحذوف
+
+110
+00:09:24,510 --> 00:09:30,210
+أعطيكم H هاي
+
+111
+00:09:30,210 --> 00:09:35,830
+الشكل الكامل واضح؟ لما أضيف هنا H هذا الكربون بدل
+
+112
+00:09:35,830 --> 00:09:41,630
+ما يكون CH2 ماذا سيحصل؟ CH3 سيحصل CH3 و ال double
+
+113
+00:09:41,630 --> 00:09:48,850
+bond هذه ستذهب علىأساس أنه هيجي يخجم عندي هنا PR
+
+114
+00:09:48,850 --> 00:09:53,270
+في الخطوة التالية الآن لاحظوا معي لو اتطلعنا على
+
+115
+00:09:53,270 --> 00:09:58,450
+هذا الجزء هذا الجزء يا ترى هل احنا بنشتغل قريب عنه
+
+116
+00:09:58,450 --> 00:10:04,430
+ولا بالنسبة له بنشتغل reaction away from a chiral
+
+117
+00:10:04,430 --> 00:10:08,290
+center away from a chiral center وعشانك بنحطه زي
+
+118
+00:10:08,290 --> 00:10:10,630
+ما هو لاحظوا إيش معناه retention of configuration
+
+119
+00:10:10,630 --> 00:10:14,750
+المثل اللي فوق ال CL على اليمين ال H على الشمالهذا
+
+120
+00:10:14,750 --> 00:10:19,010
+retention of configuration ولا لأ؟ الآن هذه النقطة
+
+121
+00:10:19,010 --> 00:10:27,690
+هي النقطة اللي هنا ال CH2 شو صارت؟ CH3 و هذه ما
+
+122
+00:10:27,690 --> 00:10:35,090
+زالت H و الآن أنا بانتظار ال PR لما نيجي نطلع
+
+123
+00:10:35,090 --> 00:10:38,130
+حوالين هذه ال carbon ايش الشكل؟
+
+124
+00:10:40,850 --> 00:10:46,950
+بناء على ذلك بنتوقع ان ال PR بإمكانها تهجم من
+
+125
+00:10:46,950 --> 00:10:51,010
+الجهتين زي ما أخذنا في أول مرة لما درسنا ال
+
+126
+00:10:51,010 --> 00:10:53,950
+generation of a chiral center بمعنى ال PR ممكن
+
+127
+00:10:53,950 --> 00:10:58,830
+تيجي من هنا و ال PR ممكن تيجي تهاجي من هنا إذا كام
+
+128
+00:10:58,830 --> 00:11:03,070
+ناتج بدو يطلع عندى هى ال PR إذا إجت من هذا الاتجاه
+
+129
+00:11:03,070 --> 00:11:09,380
+و هى ال PR إذا إجت من الاتجاه التالفزي لما درسنا
+
+130
+00:11:09,380 --> 00:11:12,600
+اول مرة الـ Chiral Center تقولنا عندنا بلانر
+
+131
+00:11:12,600 --> 00:11:18,100
+انترميديت تم التفاعل من ايه؟ من الجهتين الان هنا
+
+132
+00:11:18,100 --> 00:11:22,180
+في عند بلانر انترميديت اتكونت نتيجة انه ضفت اتش
+
+133
+00:11:22,180 --> 00:11:29,780
+لغية ال bubble bond التفاعل بإمكانه تم من الجهتينو
+
+134
+00:11:29,780 --> 00:11:35,340
+بناء على ذلك كام ناتج يطلع عنده؟ اتنين بيفرق عن
+
+135
+00:11:35,340 --> 00:11:40,880
+المثال الأول بشغل واحدة انه هل يترى الاحتمالات
+
+136
+00:11:40,880 --> 00:11:44,860
+متساوية ان هذا ييجي عن اليمين او عن الشمال في
+
+137
+00:11:44,860 --> 00:11:48,960
+generation of a first chiral center كنا نقول
+
+138
+00:11:48,960 --> 00:11:54,000
+الاحتمالات بتكون متساوية و بناء على ذلك يطلع عنده
+
+139
+00:11:55,740 --> 00:12:01,120
+الان بسبب وجود الكايرال سنتر الاول اللى بيخل
+
+140
+00:12:01,120 --> 00:12:06,400
+الفراغات حوالين هذا الكاربون غير متساوية مابيكونوش
+
+141
+00:12:06,400 --> 00:12:13,720
+الاحتمالين بنفس المقدار فبتم صحيح هجوم من الجهتين
+
+142
+00:12:13,720 --> 00:12:20,570
+ولكن ليسبنسب متساوية يعني مابيجيش 50% من التفاعل
+
+143
+00:12:20,570 --> 00:12:24,430
+من هنا و 50% من التفاعل من هنا ليش هذا الكلام
+
+144
+00:12:24,430 --> 00:12:30,240
+امتنع؟بسبب وجود ال chiral center اللي بيخلي جهة
+
+145
+00:12:30,240 --> 00:12:35,240
+أحيانا مغلقة أكتر من الجهة التانية بيصير فيه فرق
+
+146
+00:12:35,240 --> 00:12:40,180
+بالوسع زي إنسان كان عنده مسارين متساويين تماما
+
+147
+00:12:40,180 --> 00:12:44,520
+بيمكنه يمشي من هنا و من هنا الآن إجا شيء سكر جزء
+
+148
+00:12:44,520 --> 00:12:50,520
+من مسار معين بيضلوا يمشي بنفس النسبة ولا غالبا
+
+149
+00:12:50,520 --> 00:12:55,530
+بيروح على المسار الأكتر يعني ساعة و فراغواضح
+
+150
+00:12:55,530 --> 00:13:00,610
+الفكرة؟ الآن شو اللي خلّى عدم التساوي؟ الكايرال
+
+151
+00:13:00,610 --> 00:13:04,450
+سنتر الأول الكايرال سنتر الأول بيخلّى عدم تساوي
+
+152
+00:13:04,450 --> 00:13:08,890
+إذا لو أنا اتطلعت الآن على هدول الناتجين اللي
+
+153
+00:13:08,890 --> 00:13:13,610
+طلعوا بنسب متساوي ولا غير متساوية؟ غير متساوية غير
+
+154
+00:13:13,610 --> 00:13:17,690
+متساوية in unequal amounts وسألت يا تورا ما
+
+155
+00:13:17,690 --> 00:13:24,530
+العلاقة بين هدول المركبين اللي طلعوا عندهم؟لاحظوا
+
+156
+00:13:24,530 --> 00:13:30,570
+هذا الجزء و هذا الجزء ايش مالهم صورة بعض في المرأة
+
+157
+00:13:30,570 --> 00:13:36,450
+و متعاكسة طب و هذا و هذا نفس الشيء إذا المركب كله
+
+158
+00:13:36,450 --> 00:13:42,110
+صورة بعض و لا لأ إذا بدكم تعملوا باستعمال الرموز
+
+159
+00:13:42,110 --> 00:13:49,370
+بإمكانكم تعملوا R و S بمعنى نلغي هذه ال edge هعندي
+
+160
+00:13:49,370 --> 00:13:55,180
+واحد اتنين تلاتة هذه البيانة Rهذه S الانهان ما
+
+161
+00:13:55,180 --> 00:14:00,540
+اتغيرت ضلت زي ما هي هالكلور و بعدين كربون حملة
+
+162
+00:14:00,540 --> 00:14:06,460
+برون بعدين اذا هذه ايش S طيب لو اتيت و طلعت هنا
+
+163
+00:14:06,460 --> 00:14:09,900
+واحد
+
+164
+00:14:09,900 --> 00:14:14,640
+اتنين R
+
+165
+00:14:14,640 --> 00:14:21,860
+S هذه واحد اتنين R S
+
+166
+00:14:24,660 --> 00:14:31,600
+مكتوبها R رجعوهم بهدوء ال R شيء متعاكس وشيء متساوي
+
+167
+00:14:31,600 --> 00:14:37,740
+اذا هدوله ايش ديستريو مارس ف ال generation of a
+
+168
+00:14:37,740 --> 00:14:42,920
+second chiral center المحاصلة تبعته it results in
+
+169
+00:14:42,920 --> 00:14:46,560
+diastereomeric products at different rates بسرعة
+
+170
+00:14:46,560 --> 00:14:53,300
+مختلفة الأهم منها and inunequal amounts يعني لو
+
+171
+00:14:53,300 --> 00:14:56,520
+أنا باسألكوا سؤال صح و غلط generation of a second
+
+172
+00:14:56,520 --> 00:15:00,580
+chiral center results in the stereomeric mixture
+
+173
+00:15:00,580 --> 00:15:06,440
+or products in equal amounts and unequal amounts
+
+174
+00:15:06,590 --> 00:15:10,050
+طبعا ليش صار الـ unequal amount؟ because of the
+
+175
+00:15:10,050 --> 00:15:14,750
+presence of the first chiral center وجود ال chiral
+
+176
+00:15:14,750 --> 00:15:19,390
+center الأول خلّى احتمالات الهجوم من الجهتين غير
+
+177
+00:15:19,390 --> 00:15:22,770
+متساوي يعني الوسع اللي موجود من الجهة بختلف عن
+
+178
+00:15:22,770 --> 00:15:25,370
+الوسع اللي موجود من الجهة التانية الآن ذرة بدأت
+
+179
+00:15:25,370 --> 00:15:29,370
+تتفاعل التفاعل هو هجوم، ذرة ماشية و بدأت تيجي الآن
+
+180
+00:15:29,370 --> 00:15:31,850
+دايما اللي بدو يروح، يروح من المنطقة الواسعة ولا
+
+181
+00:15:31,850 --> 00:15:39,690
+الديقة؟ من المنطقة الواسعة، واضح؟هذا المحصلة
+
+182
+00:15:39,690 --> 00:15:44,370
+بالنسبة لعملية generation of a chiral center وزي
+
+183
+00:15:44,370 --> 00:15:48,650
+ما لاحظته ان هذا التفاعل بيدمج التفاعلين السابقين
+
+184
+00:15:48,650 --> 00:15:53,490
+يعني بالنسبة لهذا هو تفاعل بعيد عنه ولذلك هذا
+
+185
+00:15:53,490 --> 00:15:58,870
+الجزء ايش ماله؟ ضال في retention of configuration
+
+186
+00:15:58,870 --> 00:16:04,250
+وال generation of a chiral center تمهن ولكن بنسبة
+
+187
+00:16:04,250 --> 00:16:05,990
+غير متساوية
+
+188
+00:16:07,980 --> 00:16:11,920
+بهيك احنا بننتهي من chapter ال stereochemistry في
+
+189
+00:16:11,920 --> 00:16:15,120
+عندكم slide عن resolution of enantiomers اتكلمنا
+
+190
+00:16:15,120 --> 00:16:19,500
+عنها اللي هي فصل ال enantiomers لو حضرناهم كخليط
+
+191
+00:16:19,500 --> 00:16:24,060
+متساوي وقولنا ان هذه العملية بكل الأحوال مش عملية
+
+192
+00:16:24,060 --> 00:16:30,580
+سهلة يمكن ان تعمل بعدة طرق فنية في المختبرات لكن
+
+193
+00:16:30,580 --> 00:16:36,120
+بتاخد وقت ومش عملية سهلة والافضل من resolution of
+
+194
+00:16:36,120 --> 00:16:42,550
+enantiomersأما أن أخد المركب نقي من الطبيعة أو
+
+195
+00:16:42,550 --> 00:16:46,930
+الاحتمال التاني لو و لابد في المختبر ان اعمل
+
+196
+00:16:46,930 --> 00:16:51,710
+asymmetric synthesis انتبهوا معي لو بدأ اقول ايش
+
+197
+00:16:51,710 --> 00:16:58,110
+افضل اشي للوصول للمركبات النقية نمرة واحد من ال
+
+198
+00:16:58,110 --> 00:17:04,230
+nature الطبيعة بتعطينا مركبات نقية نمرة اتنين ان
+
+199
+00:17:04,230 --> 00:17:10,070
+اعملasymmetric synthesis يعني أعمل synthesis
+
+200
+00:17:10,070 --> 00:17:18,670
+يعطيني واحد أكتر من التاني نمرة تلاتة أن أعمل ال
+
+201
+00:17:18,670 --> 00:17:21,950
+synthesis اللي حكينا اللي بيطلعوا التنين متساويات
+
+202
+00:17:21,950 --> 00:17:26,890
+في اللي إيش اسمه symmetric synthesis لكن ال
+
+203
+00:17:26,890 --> 00:17:31,650
+symmetric synthesis إيش بدوا يتبعوه؟Symmetric
+
+204
+00:17:31,650 --> 00:17:36,050
+Synthesis هذا يجب ان يتبع Resolution لان افصلهم
+
+205
+00:17:36,050 --> 00:17:41,430
+بتجارب صعبة الانزيمات
+
+206
+00:17:41,430 --> 00:17:48,760
+في ال nature ال catalystsبمواصفات معينة عادة كيرال
+
+207
+00:17:48,760 --> 00:17:53,500
+كتاليست في الطريقة التانية يعني اللي بيساعد على ان
+
+208
+00:17:53,500 --> 00:17:57,920
+انا احصل على المركب النقي في ال nature اللي هو ال
+
+209
+00:17:57,920 --> 00:18:02,820
+enzymes الان اللي بيساعد على ان احصل على ال
+
+210
+00:18:02,820 --> 00:18:05,880
+asymmetric synthesis يعني يطلعوا مش بنسبة متساوية
+
+211
+00:18:05,880 --> 00:18:09,280
+واحد اكثر من التاني الى درجة اقترب من النقاوة
+
+212
+00:18:09,280 --> 00:18:14,360
+احيانا ان انا باستعملكتاليست والكتاليست بيكون
+
+213
+00:18:14,360 --> 00:18:21,260
+كايرة الكتاليست عادة واضح؟ الان هذه طرق وقاية ليش
+
+214
+00:18:21,260 --> 00:18:25,000
+بعملها؟ عشان ما اجعش انه طلع عندى خليطه اتغلب
+
+215
+00:18:25,000 --> 00:18:28,640
+بفاصله لو مامشيش بهذه الطريقة او بهذه الطريقة
+
+216
+00:18:28,640 --> 00:18:33,220
+اعملت symmetric synthesis خليط متساوي من الاتنين و
+
+217
+00:18:33,220 --> 00:18:37,980
+اجت بدأ اجع في مشكلة ايش؟فصل الخليط يعني الخليط
+
+218
+00:18:37,980 --> 00:18:42,560
+اللى عندى نفترض R و S بدأ ادخل على عملية الفصل شو
+
+219
+00:18:42,560 --> 00:18:47,640
+بنسميها الفصل resolution هذه يمكن أن تتم باكثر من
+
+220
+00:18:47,640 --> 00:18:52,720
+طريقة كيميائية لكن بكل الأوقات ما تفكروش أنها
+
+221
+00:18:52,720 --> 00:18:57,080
+طريقة سهلة طريقة صعبة يعني أحيانا انتوا بيكونوا
+
+222
+00:18:57,080 --> 00:19:02,860
+التخيل عندكمانه شغلة صعبة يعني بدي اخد مختبر بدل
+
+223
+00:19:02,860 --> 00:19:07,300
+ما يكون ساعتين يكون تلت ساعات وانتهي ان انا فصلت
+
+224
+00:19:07,300 --> 00:19:11,020
+المادة لأ لما انا بقول ال resolution of
+
+225
+00:19:11,020 --> 00:19:15,520
+enhancements عملية صعبة يعني واحد باحث بيشتغل وطلع
+
+226
+00:19:15,520 --> 00:19:20,340
+عنده mix chart و بده يبدأ يفصل فيه ممكن الأمور معه
+
+227
+00:19:20,340 --> 00:19:23,640
+اذا بدأ من نقطة الصفر وماعندهش اي فكرة على الموضوع
+
+228
+00:19:23,640 --> 00:19:28,770
+يبدأ تجارب تاخد سنةمش بحكي عن ساعتين و تلاتة و
+
+229
+00:19:28,770 --> 00:19:34,410
+أربعة لأ بحكي عن سنة و أكتر كمان من سنة ليست عملية
+
+230
+00:19:34,410 --> 00:19:50,430
+سهلة في الوضع الطبيعي ابهيك
+
+231
+00:19:50,430 --> 00:19:54,930
+بنكون طبعا خلصنا هذا ال chapter اللي اسمه
+
+232
+00:19:58,800 --> 00:20:04,620
+استيريو كيميستري وبننتقل
+
+233
+00:20:04,620 --> 00:20:11,960
+مباشرة الى فصل اخر هذا الفصل الاخر بدنا ناخده نوعا
+
+234
+00:20:11,960 --> 00:20:19,910
+ما باختصار .. نوعا ما باختصار عنوانه الكلهيلايزو
+
+235
+00:20:19,910 --> 00:20:24,950
+طبعا ال الكلهليتز المجموعة هذه من المركبات لها
+
+236
+00:20:24,950 --> 00:20:30,870
+تفاعلين substitution and elimination تفاعل الإبدال
+
+237
+00:20:30,870 --> 00:20:37,980
+وتفاعل الحدث بالنسبة ل الكلاعرفنا إيش يعني الكل؟
+
+238
+00:20:37,980 --> 00:20:44,860
+مجموعة الكل مثل و إثل و بربل و كل شيء مأخوذ من ال
+
+239
+00:20:44,860 --> 00:20:50,260
+الكلس سواء له اسم و لا مالوش اسم و الهيليدز متصل
+
+240
+00:20:50,260 --> 00:20:57,300
+بهالوجين كلور بروم يود فلور أحيانا فال الكلهيليدز
+
+241
+00:20:57,300 --> 00:21:03,750
+ببساطة هم ال الكلس المتصلين بهالوجينيعني لو اجينا
+
+242
+00:21:03,750 --> 00:21:08,130
+و قولنا هذا المركب يا تورا و كتبنا هنا PR عبارة عن
+
+243
+00:21:08,130 --> 00:21:14,170
+إيش الكل هيلايد لأن هذا الجزء الكن و هذا الجزء
+
+244
+00:21:14,170 --> 00:21:18,250
+الهالوجين و عشان ذلك مرات بيسموها أي معنى الكل
+
+245
+00:21:18,250 --> 00:21:22,030
+هيلايد في جزء الكن و جزء الهالوجين عشان ذلك مرات
+
+246
+00:21:22,030 --> 00:21:28,870
+بيسموهم الهالوجينو الكنز الكل هيلايد او الهالوجينو
+
+247
+00:21:28,870 --> 00:21:32,490
+الكنز نفس الفكرة تماما
+
+248
+00:21:38,950 --> 00:21:43,570
+الان زي ما حكيت ال الكلهيلايتز بيسموهم مرات
+
+249
+00:21:43,570 --> 00:21:48,410
+الهالوجينوالكينز او هالوالكينز فسواء قرأنا العنوان
+
+250
+00:21:48,410 --> 00:21:53,170
+الكلهيلايتز او هالوجينوالكينز او هالوالكينز هو ال
+
+251
+00:21:53,170 --> 00:21:58,300
+cane حاملالهالوجين البساطة مش مشكلة كبيرة فال
+
+252
+00:21:58,300 --> 00:22:02,040
+الهالوجين محتوى الهالوجين اتوم و الهالوجين اتوم
+
+253
+00:22:02,040 --> 00:22:06,020
+معروفين بالنسبة لنا فلورين و كلورين و برومين و
+
+254
+00:22:06,020 --> 00:22:08,620
+ايودين متصلين ب الهالوجروم
+
+255
+00:22:11,830 --> 00:22:16,410
+الالكالهيلايتز ممكن ان نصنفهم احنا الى primary و
+
+256
+00:22:16,410 --> 00:22:19,890
+secondary و tertiary الكلهيلايتز هذا المصطلح
+
+257
+00:22:19,890 --> 00:22:23,770
+بيفيدنا اثناء ما بنشرح عن الموضوع ايش بنقصد احنا
+
+258
+00:22:23,770 --> 00:22:27,490
+بال primary و ال secondary و ال tertiary او باللغة
+
+259
+00:22:27,490 --> 00:22:32,170
+العربية اولي و ثانوي و ثالثي ال primary و ال
+
+260
+00:22:32,170 --> 00:22:35,790
+secondary و ال tertiary الكلهيلايتز باجي انا على
+
+261
+00:22:35,790 --> 00:22:39,430
+ذرة الكربون اللى حاملة ال halogen يعني هذا الكربون
+
+262
+00:22:39,430 --> 00:22:45,830
+اللى حاملة ال halogenمتصلة بكم كاربون؟ اذا متصلة
+
+263
+00:22:45,830 --> 00:22:50,610
+بكاربون واحدة بقول عنها primary لحظة ايه الكاربون
+
+264
+00:22:50,610 --> 00:22:54,950
+اللي حاملة الهالوجين متصلة بكم كاربون واحدة اذا
+
+265
+00:22:54,950 --> 00:22:58,170
+بقول عنها primary طبعا الناس الشاطرين بيصيروا
+
+266
+00:22:58,170 --> 00:23:02,530
+يفهموها يعني بشكل سهل بيقولوا لو الكاربون اللي
+
+267
+00:23:02,530 --> 00:23:08,540
+حاملة الهالوجين كانت CH2لاحظوا CH2 و ال PR هي تلات
+
+268
+00:23:08,540 --> 00:23:13,000
+روابط إذا كده يظل متصلة مع واحدة هذا ال primary
+
+269
+00:23:13,000 --> 00:23:19,140
+فاللي بيميز ال primary وجود ال CH2 هالوجينالان ال
+
+270
+00:23:19,140 --> 00:23:24,540
+secondary الكربون اللى حامله ال halogen هى هى هذه
+
+271
+00:23:24,540 --> 00:23:27,380
+الكربون اللى حامله ال halogen متصلة بكم كربون؟
+
+272
+00:23:27,380 --> 00:23:31,000
+تنتين تنتين بقول عنها ال secondary الان ايش بيكون
+
+273
+00:23:31,000 --> 00:23:36,600
+موجود فيها؟ CH يعني كأنه ال primary CH2 halogen ال
+
+274
+00:23:36,600 --> 00:23:43,960
+secondary CH halogen لو اجيت على ال tertiaryC
+
+275
+00:23:43,960 --> 00:23:49,220
+متصلة بالهالوجين طب و التلاتة روابط التانية متصلين
+
+276
+00:23:49,220 --> 00:23:54,600
+بالكاربون هاي C متصلة بالهالوجين و بعد هيك رابطة
+
+277
+00:23:54,600 --> 00:23:58,120
+تنتين تلاتة متصلة بالكاربون هذا النوع من ال
+
+278
+00:23:58,120 --> 00:24:02,340
+الكلهيلايتش شو بسمي انا tertiary alkyl halides
+
+279
+00:24:02,340 --> 00:24:06,040
+فإذا قلنا او رسمنا اي الكلهيلايت و قلنا عنه
+
+280
+00:24:06,040 --> 00:24:09,400
+primary او secondary او tertiary بفترض ان هذه
+
+281
+00:24:09,400 --> 00:24:17,540
+الشغلة تكون واضحةعشان نفهم الـ Alkyl Halides محور
+
+282
+00:24:17,540 --> 00:24:22,220
+الـ Alkyl Halides هو رابطة الـ Carbon-Halogen يعني
+
+283
+00:24:22,220 --> 00:24:27,180
+بين الـ Carbon والـ X الـ Halogen في عنده رابطة
+
+284
+00:24:28,310 --> 00:24:32,150
+الان بدي افهم هذه الرابطة جيدا لان التفاعلات
+
+285
+00:24:32,150 --> 00:24:37,330
+هيعتمد على هذه الرابطة ال carbon halogen bond جزء
+
+286
+00:24:37,330 --> 00:24:41,990
+من فهم هذا الموضوع ان اشوف فرق السالبية هنا هل
+
+287
+00:24:41,990 --> 00:24:47,310
+يترى هذه الرابطة polar ولا non polar عشان اشوف
+
+288
+00:24:47,310 --> 00:24:53,550
+الرابطة جيدا بدي اشوف ايش السالبية للكربون الكربون
+
+289
+00:24:53,550 --> 00:24:58,350
+سالبيته اتنين ونصال carbon ايش السالبية تبعته
+
+290
+00:24:58,350 --> 00:25:05,330
+اتنين و نص الان ال halogens كم واحد اه لاحظوا
+
+291
+00:25:05,330 --> 00:25:16,670
+floor سالبيته قداش اربعة و بروم تلاتة floor
+
+292
+00:25:16,670 --> 00:25:19,750
+تلاتة
+
+293
+00:25:19,750 --> 00:25:21,590
+بروم
+
+294
+00:25:23,000 --> 00:25:29,680
+2.8 و اليود 2.5 لاحظوا اليود و الكربون فيهم فرق
+
+295
+00:25:29,680 --> 00:25:34,620
+سالبية إذا الرابطة بشكل عام non polar مافيش فرق
+
+296
+00:25:34,620 --> 00:25:40,320
+سالبية الكربون 2.5 و اليود 2.5 لكن بعد ذلك مع
+
+297
+00:25:40,320 --> 00:25:45,140
+البروم و الكلور و الفلور في فرق سالبية لمصلحة
+
+298
+00:25:45,140 --> 00:25:50,080
+الهالوجين إذا بشكل عام مع هذول الذرات كيف بنتوقع
+
+299
+00:25:50,080 --> 00:25:57,150
+ال polarity للرابطة تكونإن الكربون تكون موجبة
+
+300
+00:25:57,150 --> 00:26:05,090
+والهالوجين سالبة واضح؟ أكبر فرق وين موجود؟ مع ال
+
+301
+00:26:05,090 --> 00:26:11,910
+floor أقل فرق العدم مع اليود الأن لاحظوا معي كل ما
+
+302
+00:26:11,910 --> 00:26:16,390
+كان الفرق كبير كل ما جربت الرابط تشبه الرابط
+
+303
+00:26:16,390 --> 00:26:20,890
+الأيونية بمعنى أخر بتصير أقوىو بناء على ذلك لو انا
+
+304
+00:26:20,890 --> 00:26:25,270
+بدى اشوف قوة هذه الروابط اللى هى مع ال flour و ال
+
+305
+00:26:25,270 --> 00:26:29,330
+brom و ال chlor و ال iod هلاحظ انه و اقارنها بقوة
+
+306
+00:26:29,330 --> 00:26:32,750
+رابطة ال carbon-H اللى هى تعتبر بلغة الكيميا رابطة
+
+307
+00:26:32,750 --> 00:26:38,930
+قوية و مش سائل تنقصت ال carbon-H 413 كيلوجول لكل
+
+308
+00:26:38,930 --> 00:26:42,910
+مول بدى عشان اكسر هذه الرابطة الان ال carbon-flour
+
+309
+00:26:42,910 --> 00:26:48,150
+اقوى منهاليش؟ لأن فرق ال polarity عالي صارت تشبه
+
+310
+00:26:48,150 --> 00:26:52,990
+رابطة ايونية قوية ال carboniclor 346 ال
+
+311
+00:26:52,990 --> 00:26:59,910
+carboniclor 290 ال carboniclor 228 أقوى واحدة فيهم
+
+312
+00:26:59,910 --> 00:27:06,670
+مين؟ مع ال fluor الآن جزء أساسي في بناء الكيميا
+
+313
+00:27:06,670 --> 00:27:09,850
+تبع ال alkyl halides ان انا بدي أكسر الرابطة هذه
+
+314
+00:27:09,850 --> 00:27:15,000
+اللي بين ال carbon و ال halogenيعني سواء في تفاعل
+
+315
+00:27:15,000 --> 00:27:20,020
+الإبدال أو الحذف، هذه الرابطة بدها تنكسر طيب ال
+
+316
+00:27:20,020 --> 00:27:23,480
+floor رابطته قوية؟ صعب، صعب، صعب، صعب، صعب، صعب،
+
+317
+00:27:23,480 --> 00:27:24,200
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+318
+00:27:24,200 --> 00:27:24,620
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+319
+00:27:24,620 --> 00:27:24,820
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+320
+00:27:24,820 --> 00:27:33,340
+صعب، صعب، صعب، صعب، صعب، صعب،
+
+321
+00:27:33,340 --> 00:27:41,060
+صعب، صعب، صعب،
+
+322
+00:27:41,060 --> 00:27:45,880
+صوبناء على ذلك عندما أعمل إبدال و أخد أمثلة على
+
+323
+00:27:45,880 --> 00:27:50,360
+الإبدال و أعمل حذف و في التفاعلين الإبدال و الحذف
+
+324
+00:27:50,360 --> 00:27:56,800
+تكسر فيه رابطة الأمثلة اللي هشوفها كلور بروم يود
+
+325
+00:27:56,800 --> 00:28:01,880
+مش هشوف أمثلة على ال floor لأن ال floor رابطة قوية
+
+326
+00:28:01,880 --> 00:28:06,380
+صعب كسرها وبناء على ذلك تفاعلات الإبدال و الحذف
+
+327
+00:28:06,380 --> 00:28:11,010
+مرتبطة بدول التلاتة ال floor برا الموضوعواضح
+
+328
+00:28:11,010 --> 00:28:17,150
+الفكرة؟ الآن
+
+329
+00:28:17,150 --> 00:28:22,890
+طالما احنا بنقول بدنا نكسر الرابط مع ال halogen
+
+330
+00:28:22,890 --> 00:28:28,230
+أني أضعف رابط فيهم اليود بناء على ذلك لو انا بعمل
+
+331
+00:28:28,230 --> 00:28:33,530
+تفاعل مع اليود بيكون سهل ولا صعب؟ سهل جداالبروم
+
+332
+00:28:33,530 --> 00:28:37,350
+بقعده في السهولة الكلور بقعده وعشان هيك لو انا بدى
+
+333
+00:28:37,350 --> 00:28:40,990
+اشوف ال rate of reaction لو كنت بفعل يود وبروم
+
+334
+00:28:40,990 --> 00:28:46,270
+وكلور مقارنة بعض و بالبعض أسرع تفاعل مع اليود أسرع
+
+335
+00:28:46,270 --> 00:28:51,580
+من البروم أسرع من الكلورلكلور والسبب قوة الرابطة
+
+336
+00:28:51,580 --> 00:28:56,100
+لأن هنا في رابطة ضعيفة بتنكسر بسهولة واضح الرابطة
+
+337
+00:28:56,100 --> 00:29:00,340
+مع اليود رابطة ضعيفة بتنكسر بسهولة يمكن هذا الكلام
+
+338
+00:29:00,340 --> 00:29:04,100
+حتى في الحياة العملية بتلاحظوا حتى في الحياة
+
+339
+00:29:04,100 --> 00:29:09,320
+العملية بتلاحظوا كثير من الأدوية مثلا موجود مكون
+
+340
+00:29:09,320 --> 00:29:15,660
+أساسي منها اليود هذه الأدوية لو اتعرضت لشوية حرارة
+
+341
+00:29:15,660 --> 00:29:20,980
+بسيطة أو لضوء الشمسبتنكسر الرابطة اللي معاليه طبعا
+
+342
+00:29:20,980 --> 00:29:24,240
+كنا انكسرت الرابطة إذا الدواء كله إيش صار فيه؟ خير
+
+343
+00:29:24,240 --> 00:29:28,680
+وعشان هيك هنلاحظ أن هذا النوع من الأدوية بيحطوه في
+
+344
+00:29:28,680 --> 00:29:33,800
+جزايز غامقة لونها بني وغالبا بيحفظوه بعيدا عن
+
+345
+00:29:33,800 --> 00:29:38,930
+الضوء و الحرارة و أحيانا في حرارة باردةيعني شوف
+
+346
+00:29:38,930 --> 00:29:43,690
+كيف لما مراتب تقرأ على شيء معين يحفظ بعيدا عن
+
+347
+00:29:43,690 --> 00:29:46,730
+الضوء و الحرارة ليش؟ بيكون هذا الشيء المعين فيه
+
+348
+00:29:46,730 --> 00:29:52,790
+روابط ضعيفة حتى حرارة الجو حتى على ضو الشمس ممكن
+
+349
+00:29:52,790 --> 00:29:58,410
+تتكسر فبنصير نحط مثلا جزاز بن يمنع أنه يدخل الضوء
+
+350
+00:29:58,410 --> 00:30:02,030
+بشكل كبير بنقبل حطه بعيد عن الضوء و عن الحرارة
+
+351
+00:30:02,030 --> 00:30:06,870
+ممكن يحتفظ فيهبالتلاجة على سبيل المثال كل هذا
+
+352
+00:30:06,870 --> 00:30:12,670
+نتيجة فهم قوة الروابط الكيميائية و دائما انتوا
+
+353
+00:30:12,670 --> 00:30:16,630
+يعني جزء منكوا في علوم الصحة و جزء في غيرها لحتى
+
+354
+00:30:16,630 --> 00:30:20,190
+تتعاملوا مع أدوى او اشياء اول ما بدكوا تمسكوا اي
+
+355
+00:30:20,190 --> 00:30:28,090
+عبو الدواء شغلتين الشيء الاول صحتكماقرأوا الكلام
+
+356
+00:30:28,090 --> 00:30:33,550
+اللي عليها، ضار، سام، يجوز أن نشمه، لا يجوز، كل
+
+357
+00:30:33,550 --> 00:30:38,050
+هذا الكلام مكتوب على العبوة ويله إشارات معينة،
+
+358
+00:30:38,050 --> 00:30:42,230
+بيحرق كوروسف مثلا زي أحماض إذا انكبت على الإيد
+
+359
+00:30:42,230 --> 00:30:46,200
+بتحرقها، إذا انكبت على الملابس بتحرقهامنفعش
+
+360
+00:30:46,200 --> 00:30:49,400
+الإنسان يتعامل مع أشياء و هو مش عارفها يكون
+
+361
+00:30:49,400 --> 00:30:55,240
+بيتعامل مع سم و بيسيبه ينكب على إيده و مابيغسلش و
+
+362
+00:30:55,240 --> 00:31:00,040
+مابياخدش احتياطات ولا بيلبس gloves ولا أي شيء و
+
+363
+00:31:00,040 --> 00:31:06,940
+شغلت تانية بيكون مكتوب عندكم كلمة storeاحفظه وانت
+
+364
+00:31:06,940 --> 00:31:12,160
+احفظه طبعا شغل اضافية بيكون عندكوا expire date انه
+
+365
+00:31:12,160 --> 00:31:16,120
+هذا بعد فترة معينة ما تفتحوه بيخرب بالذات كتير
+
+366
+00:31:16,120 --> 00:31:20,800
+مركبات بيكون مسكر عليها بشكل محكم لكن لما تفتحوها
+
+367
+00:31:20,800 --> 00:31:26,970
+تتفعل مع oxygen الهواءممكن تتفاعل مع الهوى نفسه أو
+
+368
+00:31:26,970 --> 00:31:31,370
+تمتص رطوبة من الهوى وبناء على ذلك تخرب فهتلاحظوا
+
+369
+00:31:31,370 --> 00:31:35,990
+بعض المراكبات مكتوب عليها لا يستعمل بعد أسبوع أو
+
+370
+00:31:35,990 --> 00:31:41,050
+أسبوعين من فتح العبوة كل إنسان بدي يتعامل بأدوية
+
+371
+00:31:41,050 --> 00:31:45,050
+أو pre agents بدي يكون منتبه لهذه الأمور وإلا
+
+372
+00:31:45,050 --> 00:31:47,470
+بيجعل بإيش؟ بالغلط
+
+373
+00:31:51,720 --> 00:31:57,640
+الان لو اجينا على التفاعلات تبعت ال alkyl halides
+
+374
+00:31:57,640 --> 00:32:04,320
+ممكن البعض يقول طب احنا ما أعطيناش التسمية مشعلة
+
+375
+00:32:04,320 --> 00:32:09,760
+جديدة مرت عليكم لما أخدنا ال alkenes يعني لو انا
+
+376
+00:32:09,760 --> 00:32:15,600
+جبتلكوا هذا المركب هذا
+
+377
+00:32:15,600 --> 00:32:22,830
+ال alkyl halide مين تسميه؟احد اتنين تلاتة اربعة
+
+378
+00:32:22,830 --> 00:32:30,340
+خمسة بنتين اثنان كلورو اثنان مثل بنتينأخدنا
+
+379
+00:32:30,340 --> 00:32:36,180
+التسمية ولا لأ؟ أخدنا التسمية طيب واحدة بتقول ماشي
+
+380
+00:32:36,180 --> 00:32:40,800
+التسمية أخدناها طيب و ال preparation التحضير هو
+
+381
+00:32:40,800 --> 00:32:45,220
+احنا عادة لما بندرس عائلة كيميائية اول اشي بنتعرف
+
+382
+00:32:45,220 --> 00:32:49,420
+على العائلة بعدين بناخد ال nomenclature التسمية
+
+383
+00:32:49,420 --> 00:32:54,500
+بعدين التحضير بعدين التفاعلات احنا عمال جاعدين
+
+384
+00:32:54,500 --> 00:33:00,060
+بنفض جزءالتسمية وشوفنا أننا أخدناها طب و جزء
+
+385
+00:33:00,060 --> 00:33:04,800
+التحضير أخدناها
+
+386
+00:33:04,800 --> 00:33:09,420
+من أكثر من طريقة أخدناها بأكثر من طريقة لما كنا
+
+387
+00:33:09,420 --> 00:33:13,220
+نيجي نقولكم مثلا ابرو بيل و اعملوله chlorination
+
+388
+00:33:13,220 --> 00:33:20,960
+شو كنتوا تطلعوا؟One Chloro, Two Chloro مش هذي
+
+389
+00:33:20,960 --> 00:33:25,680
+Alkyl Halides إذا ال Direct Halogenation طريقة من
+
+390
+00:33:25,680 --> 00:33:30,500
+طرق التحضير ولا لأ و حلينا عليها أمثلة تأكيد ..
+
+391
+00:33:30,500 --> 00:33:36,120
+تأكيد لما كنا .. هاي أول طريقة ال Halogenation طب
+
+392
+00:33:36,120 --> 00:33:42,440
+لو أعطيناكوا هذا المركب و قولنا لكم ضيفوا عليه HBR
+
+393
+00:33:46,050 --> 00:33:50,770
+هتقولولي مع Markovnikov ولا أنت Markovnikov؟ إذا
+
+394
+00:33:50,770 --> 00:33:55,510
+Markovnikov بيجي H و PR to Bromo وإذا أنت
+
+395
+00:33:55,510 --> 00:34:01,390
+Markovnikov H و PR و لا Bromo هذه المركبات مش ال
+
+396
+00:34:01,390 --> 00:34:06,230
+الهيليتز اللي نتجت الطريقة إذا أخدناها فإيش طروب
+
+397
+00:34:06,230 --> 00:34:12,210
+تحضير ال الهيليتز؟ نمرة واحد ال halogenation of
+
+398
+00:34:12,210 --> 00:34:20,960
+alkenesالـ Halogenation طب نمره اتنين ال addition
+
+399
+00:34:20,960 --> 00:34:29,660
+of HX to الكيين أو الكايين كمان لما كنا نضيف على
+
+400
+00:34:29,660 --> 00:34:37,360
+الكاين مرتين واضح؟ في طرق تالتة أخدناها في طريق
+
+401
+00:34:37,360 --> 00:34:42,920
+تالت لو هنا إجينا ضفنا على نفس هذا المركب PR2
+
+402
+00:34:46,320 --> 00:34:50,940
+أيش كان يعطيني؟ كان يعمل لي إضافة two PR atoms
+
+403
+00:34:50,940 --> 00:34:56,800
+بسين ولا ب Anti-addition؟ Anti-addition هيعمل لي
+
+404
+00:34:56,800 --> 00:35:03,020
+dihalo compound هذه طريقة الإبوكسايد رينج لو
+
+405
+00:35:03,020 --> 00:35:07,020
+فتحناها برضه بتصير طريقة إذا إحنا أخدنا الحقيقة
+
+406
+00:35:07,020 --> 00:35:14,730
+أكثر من طريقة لتحضيرالـ Halo Compounds في طريقة
+
+407
+00:35:14,730 --> 00:35:17,890
+إضافية
+
+408
+00:35:17,890 --> 00:35:23,610
+غير التلات طرق هدول اللي هم ال ال ال ال ال ال ال
+
+409
+00:35:23,610 --> 00:35:24,970
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+410
+00:35:24,970 --> 00:35:25,010
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+411
+00:35:25,010 --> 00:35:28,170
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+412
+00:35:28,170 --> 00:35:28,990
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+413
+00:35:28,990 --> 00:35:29,570
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+414
+00:35:29,570 --> 00:35:29,610
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+415
+00:35:29,610 --> 00:35:33,550
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+416
+00:35:39,410 --> 00:35:46,970
+بتفاعلها ما عدش X أخليها RX يعني تحويل الكحول إلى
+
+417
+00:35:46,970 --> 00:35:51,810
+الكلهلايت هذه الطريقة لها تفاصيل كتير لما ندرس
+
+418
+00:35:51,810 --> 00:35:55,630
+chapter الكحولات بندرس كتفاعل على الكحول يعني
+
+419
+00:35:55,630 --> 00:36:00,290
+بإمكاننا ندرسها الأن كطريقة للتحضير و بإمكاننا
+
+420
+00:36:00,290 --> 00:36:05,900
+ندرسها في chapter الكحولات كتفاعل على الكحولواضح؟
+
+421
+00:36:05,900 --> 00:36:10,640
+هذا كحول، هذا الكلهلايت، بالنسبة للكحول هي تفاعل،
+
+422
+00:36:10,640 --> 00:36:14,980
+بالنسبة لالكلهلايت هي طريقة تحضير، لما ندرس
+
+423
+00:36:14,980 --> 00:36:19,720
+الكحولات و تفاعلاتها، هيكون عندنا تفاعل أساسي
+
+424
+00:36:19,720 --> 00:36:27,560
+تحويلالكحول إلى ال alkyl halides بمجموعة من
+
+425
+00:36:27,560 --> 00:36:31,440
+التفاصيل بندرسها بوقته، هاي بتصير كمان طريقة
+
+426
+00:36:31,440 --> 00:36:39,390
+إضافية لتحضير ال alkyl halidesكام طريقة؟ اربعة مين
+
+427
+00:36:39,390 --> 00:36:44,790
+تقول اليوم باختصار اتفضلي ال direct halogenation
+
+428
+00:36:44,790 --> 00:36:48,330
+في وجود الضوء او الحرارة لل ال alkenes اضافة ال X2
+
+429
+00:36:48,330 --> 00:36:56,190
+لل ال alkenes او اضافة ال HX
+
+430
+00:36:56,190 --> 00:37:01,620
+لل ال alkenes او لل ال alkynesو بعدين من الكحولات
+
+431
+00:37:01,620 --> 00:37:05,900
+في وجود HX او reagents تانية بندرسها في chapter
+
+432
+00:37:05,900 --> 00:37:10,860
+الكحولات هيصيرنا ذاكرينكوا كم طريقة اربع طرق
+
+433
+00:37:10,860 --> 00:37:15,380
+لتحضير ال alkyl halides تلاتة أخدتهم و طريقة
+
+434
+00:37:15,380 --> 00:37:24,180
+بندرسها في chapter الكحولات الآن التفاعل الأساسي
+
+435
+00:37:24,180 --> 00:37:30,380
+لل alkyl halides هو تفاعلالإبدال التفاعل الأساسي
+
+436
+00:37:30,380 --> 00:37:34,860
+لـ alkalites هو تفاعل الإبدال لو أنا أتي أتطلع طيب
+
+437
+00:37:34,860 --> 00:37:38,920
+إيش اللي بده أبدله؟ وكيف بده يتم الإبدال اللي
+
+438
+00:37:38,920 --> 00:37:44,480
+عندي؟ اتطلعوا هاي عندي carbon حاملة نفترض PR وهنا
+
+439
+00:37:44,480 --> 00:37:49,400
+في تلت روابط، بلاش نركز عليهم شو هما الآن إيش
+
+440
+00:37:49,400 --> 00:37:55,520
+اتفقنا على الرابط اللي موجود هنا؟قول لعنها بولا
+
+441
+00:37:55,520 --> 00:38:02,180
+يعني هذه موجبة وهذه سالبة بناء على ذلك هلاحظ أن
+
+442
+00:38:02,180 --> 00:38:06,720
+التفاعل الأساسي عندنا لما بناجي المرة الجاية اللي
+
+443
+00:38:06,720 --> 00:38:10,500
+اتكلم أنه بيجي نيوكليوفايل لإن نيوكليوفايل حامل
+
+444
+00:38:10,500 --> 00:38:15,840
+إلكترونات وين بيهاجم؟ على الكاربون الموجب يعني هذا
+
+445
+00:38:15,840 --> 00:38:22,560
+سالب للنيوكليوفايل سالب بيجي إيش بيطلعك باله؟ سالب
+
+446
+00:38:23,370 --> 00:38:27,830
+السالب هاجم على الكربون الموجب، طرد سالب إجا سالب،
+
+447
+00:38:27,830 --> 00:38:33,550
+طرد سالب، إجا موجب، طرد موجب أخدنا في البنزين
+
+448
+00:38:33,550 --> 00:38:38,190
+الإبدال إيش كان؟ موجب مكان موجب، سميناها
+
+449
+00:38:38,190 --> 00:38:41,950
+Electrophilic Substitution الآن هنا بدو ييجي سالب
+
+450
+00:38:41,950 --> 00:38:47,030
+مكان سالب، يعني إيش اللي بدو يطرد؟ ال X مع
+
+451
+00:38:47,030 --> 00:38:52,340
+إلكتروناته، شو اللي بدو يهاجم؟لنيوكليوفايل و بناء
+
+452
+00:38:52,340 --> 00:38:56,880
+على ذلك بيصير المفروض فينا نتذكر ايش معنى
+
+453
+00:38:56,880 --> 00:39:01,040
+النيوكليوفايل اللي بدو يهاجم هنا و يحل محل ال X
+
+454
+00:39:01,040 --> 00:39:06,220
+ولذلك المرة القادمة هنبدأ من كلمة ايش الـ
+
+455
+00:39:06,220 --> 00:39:11,190
+Eucleophilic Substitution يعني نبدأ نتعرف علىللـ
+
+456
+00:39:11,190 --> 00:39:14,950
+nucleophile اللي بده يهاجم ويبدأ التفاعل لأن الـ
+
+457
+00:39:14,950 --> 00:39:18,790
+nucleophile هو السالب اللي بده يهاجم ويحل محل
+
+458
+00:39:18,790 --> 00:39:23,630
+الهالوجين السالبة يعمل عملية الإبدال شكرا
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/L036VR_7BVU_raw.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/L036VR_7BVU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..54b2147223cfbe17d3c5218f6b768d83532d41d9
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/L036VR_7BVU_raw.srt
@@ -0,0 +1,1852 @@
+1
+00:00:21,210 --> 00:00:26,340
+بسم الله الرحمن الرحيمباقي عندنا في موضوع
+
+2
+00:00:26,340 --> 00:00:30,340
+التفاعلات او التفاعلات المرتبطة بال
+
+3
+00:00:30,340 --> 00:00:34,940
+stereochemistry شغلتين بسيطات احنا اتكلمنا في
+
+4
+00:00:34,940 --> 00:00:38,600
+الاول على نقطة كتير مهمة او على تفاعل كتير مهم
+
+5
+00:00:38,600 --> 00:00:43,740
+قولنا دائما في المختبر بالوضع الطبيعي لما نعمل
+
+6
+00:00:43,740 --> 00:00:47,560
+generation of a chiral center بيطلع عندى racemic
+
+7
+00:00:47,560 --> 00:00:50,400
+mixture equal mixture of enantiomers و هذا بده
+
+8
+00:00:50,400 --> 00:00:54,830
+غلبة و بده فصل و ما إلى ذلكوالان بيحاولوا انهم
+
+9
+00:00:54,830 --> 00:00:59,250
+يتغلبوا على هذا الكلام من خلال تقنيات حديثة في
+
+10
+00:00:59,250 --> 00:01:04,390
+التحضير بيسموها asymmetric synthesis هذا التفاعل
+
+11
+00:01:04,390 --> 00:01:10,030
+الأولالتفاعل التاني، لو أنا يا تورا بعمل تفاعل
+
+12
+00:01:10,030 --> 00:01:15,450
+بعيدا عن ال chiral center، الآن إيش معنى بعيدا عن
+
+13
+00:01:15,450 --> 00:01:21,310
+ال chiral center؟ بمعنى لأكسر رابطة متصلة بال
+
+14
+00:01:21,310 --> 00:01:25,330
+chiral center، يعني الأربع روابط المتصلين بال
+
+15
+00:01:25,330 --> 00:01:30,950
+chiral center بكسرهم مشكل ما بعد ذلك يعتبر ايش؟
+
+16
+00:01:30,950 --> 00:01:35,230
+تفاعل بعيد عن الـ Chiral Center واضح الفكرة؟ يعني
+
+17
+00:01:35,230 --> 00:01:39,110
+مثلا في هذا المركب، عندي هنا أنا Chiral Center
+
+18
+00:01:39,110 --> 00:01:45,010
+متصل بـ Methyl و بـ Ethyl و COH و بH، الآن هذا الـ
+
+19
+00:01:45,010 --> 00:01:50,240
+Chiral Center عليه كام رابطةأربع روابط لو أنا بدي
+
+20
+00:01:50,240 --> 00:01:55,460
+أبدل مجموعة ال O H هنا اللي هي ال acidic O H
+
+21
+00:01:55,460 --> 00:02:01,200
+مجموعة ال O H الحامضية هذه كلها بمجموعة O Ethyl
+
+22
+00:02:01,200 --> 00:02:06,420
+بمعنى في الكيميا هذا التفاعل هنتعلمه بنبدل فيه ال
+
+23
+00:02:06,420 --> 00:02:12,340
+acid ل E starباستعمال التفاعل مع الكحول شيلت الـ
+
+24
+00:02:12,340 --> 00:02:19,240
+OH و خلتها ايش؟ O Ethan الان هذه الأربع رواضة كسرت
+
+25
+00:02:19,240 --> 00:02:25,380
+جزء منها؟ لأ وبناء على ذلكالجيومتري حوالين
+
+26
+00:02:25,380 --> 00:02:28,640
+الكايرال كاربون الشكل اللذس حوالين الكايرال كاربون
+
+27
+00:02:28,640 --> 00:02:33,620
+بيضل زي ما هو فأنا كأن بعمل عملية ايش نسخ و لصق
+
+28
+00:02:33,620 --> 00:02:38,960
+بلغة الكمبيوتر يعني باجي بعمل نسخ لهذا بكل موابط و
+
+29
+00:02:38,960 --> 00:02:43,740
+لاحظوا ال H باتجاه ال CO باتجاه ال CH3 ال إثل بحطه
+
+30
+00:02:43,740 --> 00:02:48,120
+هنا و بعمل التغيير اللي عندهو بناء على ذلك بنقول
+
+31
+00:02:48,120 --> 00:02:52,740
+انه تم عنده retention of configuration يعني الشكل
+
+32
+00:02:52,740 --> 00:02:58,360
+ضل زي ما هو اتجاه الاربع روابط اللي محيطين بال
+
+33
+00:02:58,360 --> 00:03:03,440
+chiral center ضالهم ايش زي ما هو لو انا بدي اعطيكم
+
+34
+00:03:03,440 --> 00:03:07,700
+مثال يعني تخيلوا مثلا انا بهذا الشكل هينعمل chiral
+
+35
+00:03:07,700 --> 00:03:12,260
+center من اربع شغلاتوأتيت أعمل التفاعل هنا كان
+
+36
+00:03:12,260 --> 00:03:15,900
+مافيش في إيدي جلم امسكت جلم هل غيرت في اتجاه
+
+37
+00:03:15,900 --> 00:03:19,480
+الأربع روابط ولا في عند retention of configuration
+
+38
+00:03:19,480 --> 00:03:23,760
+في عند retention of configuration إذا التفاعل
+
+39
+00:03:23,760 --> 00:03:28,720
+بعيدا عن ال chiral center بتم في retention of
+
+40
+00:03:28,720 --> 00:03:31,660
+configuration معنى retention of configuration أن
+
+41
+00:03:31,660 --> 00:03:36,600
+اتجاهات الروابط الأربع تبقى كما هي لم نكسر شيء
+
+42
+00:03:36,600 --> 00:03:42,300
+حولهاكذلك الحال هنا احنا حاطين مثال تاني لو فعلنا
+
+43
+00:03:42,300 --> 00:03:47,740
+هذا المركب يعلن الكايرال سنتر بدلنا هذه ال O H
+
+44
+00:03:47,740 --> 00:03:51,740
+خلناها C double bond O باستعمال اكسدة ابعام
+
+45
+00:03:51,740 --> 00:03:53,620
+المؤكسل عادة بنسميه
+
+46
+00:03:56,470 --> 00:04:01,290
+الان هذول الاربع روابط صار عندهم تغيير و لا تغيير
+
+47
+00:04:01,290 --> 00:04:06,390
+بعد الكايرالسينفاق بعد اذا كل الاتجاهات تبقى كما
+
+48
+00:04:06,390 --> 00:04:13,840
+هي CLH CH2 CH3 الـC هادىالتغير بعدها ما كسرت روابط
+
+49
+00:04:13,840 --> 00:04:16,660
+بالتصيلة بال chiral center مرة تانية في عندي
+
+50
+00:04:16,660 --> 00:04:20,280
+retention of configuration إذا ال reaction away
+
+51
+00:04:20,280 --> 00:04:23,160
+from a chiral center results in retention of
+
+52
+00:04:23,160 --> 00:04:30,000
+configuration الآن بهمني أعطي بس ملاحظة خفيفةالـ
+
+53
+00:04:30,000 --> 00:04:34,600
+retention of configuration معناه أن الأربع روابط
+
+54
+00:04:34,600 --> 00:04:39,720
+تبقى في اتجاهاتها ليس له علاقة .. ليس له علاقة
+
+55
+00:04:39,720 --> 00:04:46,100
+بكلمة R و S أنا هنا و أنا بشتغل كتبت R ولا S ولا
+
+56
+00:04:46,100 --> 00:04:50,380
+شفت أن ال R دلت R ولا ال S دلت S؟ ماجبتش سيرة
+
+57
+00:04:50,380 --> 00:04:55,100
+هالكلام، ليش؟ لأنه أنا لما بغير مجموعة هنا أو هنا
+
+58
+00:04:55,100 --> 00:05:02,890
+ممكن الأولويات تتغير؟ أكيدأكيد حتى لو غيرت مجموعة
+
+59
+00:05:02,890 --> 00:05:06,790
+بعيد ممكن يصير فيه تغيير بالأولويات و لذلك ممكن R
+
+60
+00:05:06,790 --> 00:05:11,430
+عند الضل R ممكن R تصير S ممكن S تصير R ممكن S تظل
+
+61
+00:05:11,430 --> 00:05:16,370
+S أو تتقلب إلى R هذا موضوع ما درسته انا اطلاقا انا
+
+62
+00:05:16,370 --> 00:05:21,650
+بدرس الأربع روابط في اتجاهاتهم فيهم تغيير ولا لأ
+
+63
+00:05:21,650 --> 00:05:26,020
+هى معناه retention of configuration الان R و Sمن
+
+64
+00:05:26,020 --> 00:05:31,160
+أول و جديد في عندكم اشي اسمه قواعد ترتيب المجموعات
+
+65
+00:05:31,160 --> 00:05:36,320
+حسب الأولويات واحد اتنين تلاتة اربعة بنرتبهم ضلت
+
+66
+00:05:36,320 --> 00:05:41,460
+الارار صارت اسم مش مشيء بالنسبة الي واضح الفكرة
+
+67
+00:05:41,460 --> 00:05:47,200
+فكلمة retention of configurationلا تعني اطلاقا ..
+
+68
+00:05:47,200 --> 00:05:52,700
+لا تعني اطلاقا ان ال R دلت R او ال S دلت S لأ تعني
+
+69
+00:05:52,700 --> 00:05:58,520
+ان الأربع روابط ضالهم باتجاههم ال R و ال S اولويات
+
+70
+00:05:58,520 --> 00:06:01,420
+اللي بيحسب اولويات يشوف حسب المثال اللي عنده
+
+71
+00:06:01,420 --> 00:06:05,480
+هتلاقوا مثال بتم فيه تغيير مثال بتم مش فيه تغيير
+
+72
+00:06:05,480 --> 00:06:09,460
+حسب هالمجموعة اللي طلعت و المجموعة اللي اجت هذا
+
+73
+00:06:09,460 --> 00:06:15,200
+موضوع تاني واضح الفكرة؟وهذا كثير بنسألكم بمعناه
+
+74
+00:06:15,200 --> 00:06:19,280
+انه هالمعنى كلمة retention of configuration means
+
+75
+00:06:19,280 --> 00:06:24,420
+are must be are in the product لأ مش ضروري ممكن
+
+76
+00:06:24,420 --> 00:06:29,400
+تظل ممكن تتغير هذا موضوع و هذا موضوع تاني
+
+77
+00:06:33,710 --> 00:06:39,030
+هذه تفاعلات بناخدها بعدين بس بنعطيها كأمثلة يعني
+
+78
+00:06:39,030 --> 00:06:43,710
+هذا تأكسد كحول إلى aldehyde لما ندرس chapter
+
+79
+00:06:43,710 --> 00:06:49,410
+الكحولات ب chapter 7 بنشرحه الآن بديش أنا أسمي لا
+
+80
+00:06:49,410 --> 00:06:52,750
+كحول ولا aldehyde أنا قلت ال Canada دي CO single
+
+81
+00:06:52,750 --> 00:06:57,840
+bond صارت CO double bond غيرت هان ولا لأ؟تستعجلوش
+
+82
+00:06:57,840 --> 00:07:02,880
+العلم هذا تحول حامض إلى Easter بدلت ال OH ب Oethel
+
+83
+00:07:02,880 --> 00:07:08,140
+بدرسه ب Chapter 10 مش هو موضوعي غيرت بدي ألغي كل
+
+84
+00:07:08,140 --> 00:07:13,060
+اللي كاتبه و أكتب XY عشان اترايحيني أعصابي خلت XY
+
+85
+00:07:13,060 --> 00:07:14,980
+واضح؟
+
+86
+00:07:16,500 --> 00:07:21,120
+دائما تتعبوش أنفسكم في الفكرة غير الأساسية بدلت X
+
+87
+00:07:21,120 --> 00:07:26,760
+بY إيش التفاعل مش مشكلة مش X صارت Y تفاعل general
+
+88
+00:07:26,760 --> 00:07:31,520
+بدلته بعيدا عن ال chiral center إيش بيظل عنده
+
+89
+00:07:31,520 --> 00:07:37,960
+retention إنما هدولا التفاعلين كتفصيل بناخدهم في
+
+90
+00:07:37,960 --> 00:07:43,160
+chapter 7 أو chapter 10 لكن استعانا فيهم كأمثلة
+
+91
+00:07:45,090 --> 00:07:50,130
+التفاعل التالت generation of a second chiral
+
+92
+00:07:50,130 --> 00:07:54,370
+center يعني لاحظوا احنا اول مرة قولنا ماكنش لنا
+
+93
+00:07:54,370 --> 00:07:57,390
+chiral center نهائي و عملنا له generation، شو طلع
+
+94
+00:07:57,390 --> 00:08:04,840
+عندى؟ رسمic mixtureتاني تفاعل لما اعملت تفاعل بعيد
+
+95
+00:08:04,840 --> 00:08:08,320
+عن الكايرال سنتر شو صار عندى retention of
+
+96
+00:08:08,320 --> 00:08:13,880
+configuration طيب الآن لو كان في عندى كايرال سنتر
+
+97
+00:08:13,880 --> 00:08:19,160
+اول و بدى اعمل كايرال سنتر تاني شو بده يصير عندى؟
+
+98
+00:08:19,160 --> 00:08:25,120
+خلّينا نشوف مثال هذه مثال لو طلعنا على هذا المركب
+
+99
+00:08:25,120 --> 00:08:29,880
+الآن هذه الكاربون اللى موجودة هنا بتحمل مثل
+
+100
+00:08:29,880 --> 00:08:33,970
+وchloro Hو المجموعة اللي فيها double bond كايرال
+
+101
+00:08:33,970 --> 00:08:39,290
+سنتر ولا لأ كايرال سنتر انا مش موضوعي اطلاقا هذه
+
+102
+00:08:39,290 --> 00:08:42,770
+ال carbon بدي اعمل التفاعل على ال double bond يعني
+
+103
+00:08:42,770 --> 00:08:48,160
+على ال double bond بدي اجي اضيف hbr في وجودH plus
+
+104
+00:08:48,160 --> 00:08:53,940
+هذه أخدناها إضافة Markovnikov يعني بدأ أحط ال H
+
+105
+00:08:53,940 --> 00:09:00,080
+هنا في الأول أبدأ تفاعل بإضافة ال H هنا وبعدين
+
+106
+00:09:00,080 --> 00:09:06,260
+أكمل ال PR على هذا الموقع لاحظوا إيش اللي بدو يصير
+
+107
+00:09:06,260 --> 00:09:12,060
+عندي لما أضيف ال H على هذا الموقع كام رابط هيظل
+
+108
+00:09:12,060 --> 00:09:20,250
+على هذه النقطة تلت روابط تلت روابطحاولوا تستحضروا
+
+109
+00:09:20,250 --> 00:09:24,510
+الشكل مع الهيدروجين المحذوف مع الهيدروجين المحذوف
+
+110
+00:09:24,510 --> 00:09:30,210
+أعطيكم H هاي
+
+111
+00:09:30,210 --> 00:09:35,830
+الشكل الكامل واضح؟ لما أضيف هنا H هذا الكربون بدل
+
+112
+00:09:35,830 --> 00:09:41,630
+ما يكون CH2 ماذا سيحصل؟ CH3 سيحصل CH3 و ال double
+
+113
+00:09:41,630 --> 00:09:48,850
+bond هذه ستذهب علىأساس أنه هيجي يخجم عندي هنا PR
+
+114
+00:09:48,850 --> 00:09:53,270
+في الخطوة التالية الآن لاحظوا معي لو اتطلعنا على
+
+115
+00:09:53,270 --> 00:09:58,450
+هذا الجزء هذا الجزء يا ترى هل احنا بنشتغل قريب عنه
+
+116
+00:09:58,450 --> 00:10:04,430
+ولا بالنسبة له بنشتغل reaction away from a chiral
+
+117
+00:10:04,430 --> 00:10:08,290
+center away from a chiral center وعشانك بنحطه زي
+
+118
+00:10:08,290 --> 00:10:10,630
+ما هو لاحظوا إيش معناه retention of configuration
+
+119
+00:10:10,630 --> 00:10:14,750
+المثل اللي فوق ال CL على اليمين ال H على الشمالهذا
+
+120
+00:10:14,750 --> 00:10:19,010
+retention of configuration ولا لأ؟ الآن هذه النقطة
+
+121
+00:10:19,010 --> 00:10:27,690
+هي النقطة اللي هنا ال CH2 شو صارت؟ CH3 و هذه ما
+
+122
+00:10:27,690 --> 00:10:35,090
+زالت H و الآن أنا بانتظار ال PR لما نيجي نطلع
+
+123
+00:10:35,090 --> 00:10:38,130
+حوالين هذه ال carbon ايش الشكل؟
+
+124
+00:10:40,850 --> 00:10:46,950
+بناء على ذلك بنتوقع ان ال PR بإمكانها تهجم من
+
+125
+00:10:46,950 --> 00:10:51,010
+الجهتين زي ما أخذنا في أول مرة لما درسنا ال
+
+126
+00:10:51,010 --> 00:10:53,950
+generation of a chiral center بمعنى ال PR ممكن
+
+127
+00:10:53,950 --> 00:10:58,830
+تيجي من هنا و ال PR ممكن تيجي تهاجي من هنا إذا كام
+
+128
+00:10:58,830 --> 00:11:03,070
+ناتج بدو يطلع عندى هى ال PR إذا إجت من هذا الاتجاه
+
+129
+00:11:03,070 --> 00:11:09,380
+و هى ال PR إذا إجت من الاتجاه التالفزي لما درسنا
+
+130
+00:11:09,380 --> 00:11:12,600
+اول مرة الـ Chiral Center تقولنا عندنا بلانر
+
+131
+00:11:12,600 --> 00:11:18,100
+انترميديت تم التفاعل من ايه؟ من الجهتين الان هنا
+
+132
+00:11:18,100 --> 00:11:22,180
+في عند بلانر انترميديت اتكونت نتيجة انه ضفت اتش
+
+133
+00:11:22,180 --> 00:11:29,780
+لغية ال bubble bond التفاعل بإمكانه تم من الجهتينو
+
+134
+00:11:29,780 --> 00:11:35,340
+بناء على ذلك كام ناتج يطلع عنده؟ اتنين بيفرق عن
+
+135
+00:11:35,340 --> 00:11:40,880
+المثال الأول بشغل واحدة انه هل يترى الاحتمالات
+
+136
+00:11:40,880 --> 00:11:44,860
+متساوية ان هذا ييجي عن اليمين او عن الشمال في
+
+137
+00:11:44,860 --> 00:11:48,960
+generation of a first chiral center كنا نقول
+
+138
+00:11:48,960 --> 00:11:54,000
+الاحتمالات بتكون متساوية و بناء على ذلك يطلع عنده
+
+139
+00:11:55,740 --> 00:12:01,120
+الان بسبب وجود الكايرال سنتر الاول اللى بيخل
+
+140
+00:12:01,120 --> 00:12:06,400
+الفراغات حوالين هذا الكاربون غير متساوية مابيكونوش
+
+141
+00:12:06,400 --> 00:12:13,720
+الاحتمالين بنفس المقدار فبتم صحيح هجوم من الجهتين
+
+142
+00:12:13,720 --> 00:12:20,570
+ولكن ليسبنسب متساوية يعني مابيجيش 50% من التفاعل
+
+143
+00:12:20,570 --> 00:12:24,430
+من هنا و 50% من التفاعل من هنا ليش هذا الكلام
+
+144
+00:12:24,430 --> 00:12:30,240
+امتنع؟بسبب وجود ال chiral center اللي بيخلي جهة
+
+145
+00:12:30,240 --> 00:12:35,240
+أحيانا مغلقة أكتر من الجهة التانية بيصير فيه فرق
+
+146
+00:12:35,240 --> 00:12:40,180
+بالوسع زي إنسان كان عنده مسارين متساويين تماما
+
+147
+00:12:40,180 --> 00:12:44,520
+بيمكنه يمشي من هنا و من هنا الآن إجا شيء سكر جزء
+
+148
+00:12:44,520 --> 00:12:50,520
+من مسار معين بيضلوا يمشي بنفس النسبة ولا غالبا
+
+149
+00:12:50,520 --> 00:12:55,530
+بيروح على المسار الأكتر يعني ساعة و فراغواضح
+
+150
+00:12:55,530 --> 00:13:00,610
+الفكرة؟ الآن شو اللي خلّى عدم التساوي؟ الكايرال
+
+151
+00:13:00,610 --> 00:13:04,450
+سنتر الأول الكايرال سنتر الأول بيخلّى عدم تساوي
+
+152
+00:13:04,450 --> 00:13:08,890
+إذا لو أنا اتطلعت الآن على هدول الناتجين اللي
+
+153
+00:13:08,890 --> 00:13:13,610
+طلعوا بنسب متساوي ولا غير متساوية؟ غير متساوية غير
+
+154
+00:13:13,610 --> 00:13:17,690
+متساوية in unequal amounts وسألت يا تورا ما
+
+155
+00:13:17,690 --> 00:13:24,530
+العلاقة بين هدول المركبين اللي طلعوا عندهم؟لاحظوا
+
+156
+00:13:24,530 --> 00:13:30,570
+هذا الجزء و هذا الجزء ايش مالهم صورة بعض في المرأة
+
+157
+00:13:30,570 --> 00:13:36,450
+و متعاكسة طب و هذا و هذا نفس الشيء إذا المركب كله
+
+158
+00:13:36,450 --> 00:13:42,110
+صورة بعض و لا لأ إذا بدكم تعملوا باستعمال الرموز
+
+159
+00:13:42,110 --> 00:13:49,370
+بإمكانكم تعملوا R و S بمعنى نلغي هذه ال edge هعندي
+
+160
+00:13:49,370 --> 00:13:55,180
+واحد اتنين تلاتة هذه البيانة Rهذه S الانهان ما
+
+161
+00:13:55,180 --> 00:14:00,540
+اتغيرت ضلت زي ما هي هالكلور و بعدين كربون حملة
+
+162
+00:14:00,540 --> 00:14:06,460
+برون بعدين اذا هذه ايش S طيب لو اتيت و طلعت هنا
+
+163
+00:14:06,460 --> 00:14:09,900
+واحد
+
+164
+00:14:09,900 --> 00:14:14,640
+اتنين R
+
+165
+00:14:14,640 --> 00:14:21,860
+S هذه واحد اتنين R S
+
+166
+00:14:24,660 --> 00:14:31,600
+مكتوبها R رجعوهم بهدوء ال R شيء متعاكس وشيء متساوي
+
+167
+00:14:31,600 --> 00:14:37,740
+اذا هدوله ايش ديستريو مارس ف ال generation of a
+
+168
+00:14:37,740 --> 00:14:42,920
+second chiral center المحاصلة تبعته it results in
+
+169
+00:14:42,920 --> 00:14:46,560
+diastereomeric products at different rates بسرعة
+
+170
+00:14:46,560 --> 00:14:53,300
+مختلفة الأهم منها and inunequal amounts يعني لو
+
+171
+00:14:53,300 --> 00:14:56,520
+أنا باسألكوا سؤال صح و غلط generation of a second
+
+172
+00:14:56,520 --> 00:15:00,580
+chiral center results in the stereomeric mixture
+
+173
+00:15:00,580 --> 00:15:06,440
+or products in equal amounts and unequal amounts
+
+174
+00:15:06,590 --> 00:15:10,050
+طبعا ليش صار الـ unequal amount؟ because of the
+
+175
+00:15:10,050 --> 00:15:14,750
+presence of the first chiral center وجود ال chiral
+
+176
+00:15:14,750 --> 00:15:19,390
+center الأول خلّى احتمالات الهجوم من الجهتين غير
+
+177
+00:15:19,390 --> 00:15:22,770
+متساوي يعني الوسع اللي موجود من الجهة بختلف عن
+
+178
+00:15:22,770 --> 00:15:25,370
+الوسع اللي موجود من الجهة التانية الآن ذرة بدأت
+
+179
+00:15:25,370 --> 00:15:29,370
+تتفاعل التفاعل هو هجوم، ذرة ماشية و بدأت تيجي الآن
+
+180
+00:15:29,370 --> 00:15:31,850
+دايما اللي بدو يروح، يروح من المنطقة الواسعة ولا
+
+181
+00:15:31,850 --> 00:15:39,690
+الديقة؟ من المنطقة الواسعة، واضح؟هذا المحصلة
+
+182
+00:15:39,690 --> 00:15:44,370
+بالنسبة لعملية generation of a chiral center وزي
+
+183
+00:15:44,370 --> 00:15:48,650
+ما لاحظته ان هذا التفاعل بيدمج التفاعلين السابقين
+
+184
+00:15:48,650 --> 00:15:53,490
+يعني بالنسبة لهذا هو تفاعل بعيد عنه ولذلك هذا
+
+185
+00:15:53,490 --> 00:15:58,870
+الجزء ايش ماله؟ ضال في retention of configuration
+
+186
+00:15:58,870 --> 00:16:04,250
+وال generation of a chiral center تمهن ولكن بنسبة
+
+187
+00:16:04,250 --> 00:16:05,990
+غير متساوية
+
+188
+00:16:07,980 --> 00:16:11,920
+بهيك احنا بننتهي من chapter ال stereochemistry في
+
+189
+00:16:11,920 --> 00:16:15,120
+عندكم slide عن resolution of enantiomers اتكلمنا
+
+190
+00:16:15,120 --> 00:16:19,500
+عنها اللي هي فصل ال enantiomers لو حضرناهم كخليط
+
+191
+00:16:19,500 --> 00:16:24,060
+متساوي وقولنا ان هذه العملية بكل الأحوال مش عملية
+
+192
+00:16:24,060 --> 00:16:30,580
+سهلة يمكن ان تعمل بعدة طرق فنية في المختبرات لكن
+
+193
+00:16:30,580 --> 00:16:36,120
+بتاخد وقت ومش عملية سهلة والافضل من resolution of
+
+194
+00:16:36,120 --> 00:16:42,550
+enantiomersأما أن أخد المركب نقي من الطبيعة أو
+
+195
+00:16:42,550 --> 00:16:46,930
+الاحتمال التاني لو و لابد في المختبر ان اعمل
+
+196
+00:16:46,930 --> 00:16:51,710
+asymmetric synthesis انتبهوا معي لو بدأ اقول ايش
+
+197
+00:16:51,710 --> 00:16:58,110
+افضل اشي للوصول للمركبات النقية نمرة واحد من ال
+
+198
+00:16:58,110 --> 00:17:04,230
+nature الطبيعة بتعطينا مركبات نقية نمرة اتنين ان
+
+199
+00:17:04,230 --> 00:17:10,070
+اعملasymmetric synthesis يعني أعمل synthesis
+
+200
+00:17:10,070 --> 00:17:18,670
+يعطيني واحد أكتر من التاني نمرة تلاتة أن أعمل ال
+
+201
+00:17:18,670 --> 00:17:21,950
+synthesis اللي حكينا اللي بيطلعوا التنين متساويات
+
+202
+00:17:21,950 --> 00:17:26,890
+في اللي إيش اسمه symmetric synthesis لكن ال
+
+203
+00:17:26,890 --> 00:17:31,650
+symmetric synthesis إيش بدوا يتبعوه؟Symmetric
+
+204
+00:17:31,650 --> 00:17:36,050
+Synthesis هذا يجب ان يتبع Resolution لان افصلهم
+
+205
+00:17:36,050 --> 00:17:41,430
+بتجارب صعبة الانزيمات
+
+206
+00:17:41,430 --> 00:17:48,760
+في ال nature ال catalystsبمواصفات معينة عادة كيرال
+
+207
+00:17:48,760 --> 00:17:53,500
+كتاليست في الطريقة التانية يعني اللي بيساعد على ان
+
+208
+00:17:53,500 --> 00:17:57,920
+انا احصل على المركب النقي في ال nature اللي هو ال
+
+209
+00:17:57,920 --> 00:18:02,820
+enzymes الان اللي بيساعد على ان احصل على ال
+
+210
+00:18:02,820 --> 00:18:05,880
+asymmetric synthesis يعني يطلعوا مش بنسبة متساوية
+
+211
+00:18:05,880 --> 00:18:09,280
+واحد اكثر من التاني الى درجة اقترب من النقاوة
+
+212
+00:18:09,280 --> 00:18:14,360
+احيانا ان انا باستعملكتاليست والكتاليست بيكون
+
+213
+00:18:14,360 --> 00:18:21,260
+كايرة الكتاليست عادة واضح؟ الان هذه طرق وقاية ليش
+
+214
+00:18:21,260 --> 00:18:25,000
+بعملها؟ عشان ما اجعش انه طلع عندى خليطه اتغلب
+
+215
+00:18:25,000 --> 00:18:28,640
+بفاصله لو مامشيش بهذه الطريقة او بهذه الطريقة
+
+216
+00:18:28,640 --> 00:18:33,220
+اعملت symmetric synthesis خليط متساوي من الاتنين و
+
+217
+00:18:33,220 --> 00:18:37,980
+اجت بدأ اجع في مشكلة ايش؟فصل الخليط يعني الخليط
+
+218
+00:18:37,980 --> 00:18:42,560
+اللى عندى نفترض R و S بدأ ادخل على عملية الفصل شو
+
+219
+00:18:42,560 --> 00:18:47,640
+بنسميها الفصل resolution هذه يمكن أن تتم باكثر من
+
+220
+00:18:47,640 --> 00:18:52,720
+طريقة كيميائية لكن بكل الأوقات ما تفكروش أنها
+
+221
+00:18:52,720 --> 00:18:57,080
+طريقة سهلة طريقة صعبة يعني أحيانا انتوا بيكونوا
+
+222
+00:18:57,080 --> 00:19:02,860
+التخيل عندكمانه شغلة صعبة يعني بدي اخد مختبر بدل
+
+223
+00:19:02,860 --> 00:19:07,300
+ما يكون ساعتين يكون تلت ساعات وانتهي ان انا فصلت
+
+224
+00:19:07,300 --> 00:19:11,020
+المادة لأ لما انا بقول ال resolution of
+
+225
+00:19:11,020 --> 00:19:15,520
+enhancements عملية صعبة يعني واحد باحث بيشتغل وطلع
+
+226
+00:19:15,520 --> 00:19:20,340
+عنده mix chart و بده يبدأ يفصل فيه ممكن الأمور معه
+
+227
+00:19:20,340 --> 00:19:23,640
+اذا بدأ من نقطة الصفر وماعندهش اي فكرة على الموضوع
+
+228
+00:19:23,640 --> 00:19:28,770
+يبدأ تجارب تاخد سنةمش بحكي عن ساعتين و تلاتة و
+
+229
+00:19:28,770 --> 00:19:34,410
+أربعة لأ بحكي عن سنة و أكتر كمان من سنة ليست عملية
+
+230
+00:19:34,410 --> 00:19:50,430
+سهلة في الوضع الطبيعي ابهيك
+
+231
+00:19:50,430 --> 00:19:54,930
+بنكون طبعا خلصنا هذا ال chapter اللي اسمه
+
+232
+00:19:58,800 --> 00:20:04,620
+استيريو كيميستري وبننتقل
+
+233
+00:20:04,620 --> 00:20:11,960
+مباشرة الى فصل اخر هذا الفصل الاخر بدنا ناخده نوعا
+
+234
+00:20:11,960 --> 00:20:19,910
+ما باختصار .. نوعا ما باختصار عنوانه الكلهيلايزو
+
+235
+00:20:19,910 --> 00:20:24,950
+طبعا ال الكلهليتز المجموعة هذه من المركبات لها
+
+236
+00:20:24,950 --> 00:20:30,870
+تفاعلين substitution and elimination تفاعل الإبدال
+
+237
+00:20:30,870 --> 00:20:37,980
+وتفاعل الحدث بالنسبة ل الكلاعرفنا إيش يعني الكل؟
+
+238
+00:20:37,980 --> 00:20:44,860
+مجموعة الكل مثل و إثل و بربل و كل شيء مأخوذ من ال
+
+239
+00:20:44,860 --> 00:20:50,260
+الكلس سواء له اسم و لا مالوش اسم و الهيليدز متصل
+
+240
+00:20:50,260 --> 00:20:57,300
+بهالوجين كلور بروم يود فلور أحيانا فال الكلهيليدز
+
+241
+00:20:57,300 --> 00:21:03,750
+ببساطة هم ال الكلس المتصلين بهالوجينيعني لو اجينا
+
+242
+00:21:03,750 --> 00:21:08,130
+و قولنا هذا المركب يا تورا و كتبنا هنا PR عبارة عن
+
+243
+00:21:08,130 --> 00:21:14,170
+إيش الكل هيلايد لأن هذا الجزء الكن و هذا الجزء
+
+244
+00:21:14,170 --> 00:21:18,250
+الهالوجين و عشان ذلك مرات بيسموها أي معنى الكل
+
+245
+00:21:18,250 --> 00:21:22,030
+هيلايد في جزء الكن و جزء الهالوجين عشان ذلك مرات
+
+246
+00:21:22,030 --> 00:21:28,870
+بيسموهم الهالوجينو الكنز الكل هيلايد او الهالوجينو
+
+247
+00:21:28,870 --> 00:21:32,490
+الكنز نفس الفكرة تماما
+
+248
+00:21:38,950 --> 00:21:43,570
+الان زي ما حكيت ال الكلهيلايتز بيسموهم مرات
+
+249
+00:21:43,570 --> 00:21:48,410
+الهالوجينوالكينز او هالوالكينز فسواء قرأنا العنوان
+
+250
+00:21:48,410 --> 00:21:53,170
+الكلهيلايتز او هالوجينوالكينز او هالوالكينز هو ال
+
+251
+00:21:53,170 --> 00:21:58,300
+cane حاملالهالوجين البساطة مش مشكلة كبيرة فال
+
+252
+00:21:58,300 --> 00:22:02,040
+الهالوجين محتوى الهالوجين اتوم و الهالوجين اتوم
+
+253
+00:22:02,040 --> 00:22:06,020
+معروفين بالنسبة لنا فلورين و كلورين و برومين و
+
+254
+00:22:06,020 --> 00:22:08,620
+ايودين متصلين ب الهالوجروم
+
+255
+00:22:11,830 --> 00:22:16,410
+الالكالهيلايتز ممكن ان نصنفهم احنا الى primary و
+
+256
+00:22:16,410 --> 00:22:19,890
+secondary و tertiary الكلهيلايتز هذا المصطلح
+
+257
+00:22:19,890 --> 00:22:23,770
+بيفيدنا اثناء ما بنشرح عن الموضوع ايش بنقصد احنا
+
+258
+00:22:23,770 --> 00:22:27,490
+بال primary و ال secondary و ال tertiary او باللغة
+
+259
+00:22:27,490 --> 00:22:32,170
+العربية اولي و ثانوي و ثالثي ال primary و ال
+
+260
+00:22:32,170 --> 00:22:35,790
+secondary و ال tertiary الكلهيلايتز باجي انا على
+
+261
+00:22:35,790 --> 00:22:39,430
+ذرة الكربون اللى حاملة ال halogen يعني هذا الكربون
+
+262
+00:22:39,430 --> 00:22:45,830
+اللى حاملة ال halogenمتصلة بكم كاربون؟ اذا متصلة
+
+263
+00:22:45,830 --> 00:22:50,610
+بكاربون واحدة بقول عنها primary لحظة ايه الكاربون
+
+264
+00:22:50,610 --> 00:22:54,950
+اللي حاملة الهالوجين متصلة بكم كاربون واحدة اذا
+
+265
+00:22:54,950 --> 00:22:58,170
+بقول عنها primary طبعا الناس الشاطرين بيصيروا
+
+266
+00:22:58,170 --> 00:23:02,530
+يفهموها يعني بشكل سهل بيقولوا لو الكاربون اللي
+
+267
+00:23:02,530 --> 00:23:08,540
+حاملة الهالوجين كانت CH2لاحظوا CH2 و ال PR هي تلات
+
+268
+00:23:08,540 --> 00:23:13,000
+روابط إذا كده يظل متصلة مع واحدة هذا ال primary
+
+269
+00:23:13,000 --> 00:23:19,140
+فاللي بيميز ال primary وجود ال CH2 هالوجينالان ال
+
+270
+00:23:19,140 --> 00:23:24,540
+secondary الكربون اللى حامله ال halogen هى هى هذه
+
+271
+00:23:24,540 --> 00:23:27,380
+الكربون اللى حامله ال halogen متصلة بكم كربون؟
+
+272
+00:23:27,380 --> 00:23:31,000
+تنتين تنتين بقول عنها ال secondary الان ايش بيكون
+
+273
+00:23:31,000 --> 00:23:36,600
+موجود فيها؟ CH يعني كأنه ال primary CH2 halogen ال
+
+274
+00:23:36,600 --> 00:23:43,960
+secondary CH halogen لو اجيت على ال tertiaryC
+
+275
+00:23:43,960 --> 00:23:49,220
+متصلة بالهالوجين طب و التلاتة روابط التانية متصلين
+
+276
+00:23:49,220 --> 00:23:54,600
+بالكاربون هاي C متصلة بالهالوجين و بعد هيك رابطة
+
+277
+00:23:54,600 --> 00:23:58,120
+تنتين تلاتة متصلة بالكاربون هذا النوع من ال
+
+278
+00:23:58,120 --> 00:24:02,340
+الكلهيلايتش شو بسمي انا tertiary alkyl halides
+
+279
+00:24:02,340 --> 00:24:06,040
+فإذا قلنا او رسمنا اي الكلهيلايت و قلنا عنه
+
+280
+00:24:06,040 --> 00:24:09,400
+primary او secondary او tertiary بفترض ان هذه
+
+281
+00:24:09,400 --> 00:24:17,540
+الشغلة تكون واضحةعشان نفهم الـ Alkyl Halides محور
+
+282
+00:24:17,540 --> 00:24:22,220
+الـ Alkyl Halides هو رابطة الـ Carbon-Halogen يعني
+
+283
+00:24:22,220 --> 00:24:27,180
+بين الـ Carbon والـ X الـ Halogen في عنده رابطة
+
+284
+00:24:28,310 --> 00:24:32,150
+الان بدي افهم هذه الرابطة جيدا لان التفاعلات
+
+285
+00:24:32,150 --> 00:24:37,330
+هيعتمد على هذه الرابطة ال carbon halogen bond جزء
+
+286
+00:24:37,330 --> 00:24:41,990
+من فهم هذا الموضوع ان اشوف فرق السالبية هنا هل
+
+287
+00:24:41,990 --> 00:24:47,310
+يترى هذه الرابطة polar ولا non polar عشان اشوف
+
+288
+00:24:47,310 --> 00:24:53,550
+الرابطة جيدا بدي اشوف ايش السالبية للكربون الكربون
+
+289
+00:24:53,550 --> 00:24:58,350
+سالبيته اتنين ونصال carbon ايش السالبية تبعته
+
+290
+00:24:58,350 --> 00:25:05,330
+اتنين و نص الان ال halogens كم واحد اه لاحظوا
+
+291
+00:25:05,330 --> 00:25:16,670
+floor سالبيته قداش اربعة و بروم تلاتة floor
+
+292
+00:25:16,670 --> 00:25:19,750
+تلاتة
+
+293
+00:25:19,750 --> 00:25:21,590
+بروم
+
+294
+00:25:23,000 --> 00:25:29,680
+2.8 و اليود 2.5 لاحظوا اليود و الكربون فيهم فرق
+
+295
+00:25:29,680 --> 00:25:34,620
+سالبية إذا الرابطة بشكل عام non polar مافيش فرق
+
+296
+00:25:34,620 --> 00:25:40,320
+سالبية الكربون 2.5 و اليود 2.5 لكن بعد ذلك مع
+
+297
+00:25:40,320 --> 00:25:45,140
+البروم و الكلور و الفلور في فرق سالبية لمصلحة
+
+298
+00:25:45,140 --> 00:25:50,080
+الهالوجين إذا بشكل عام مع هذول الذرات كيف بنتوقع
+
+299
+00:25:50,080 --> 00:25:57,150
+ال polarity للرابطة تكونإن الكربون تكون موجبة
+
+300
+00:25:57,150 --> 00:26:05,090
+والهالوجين سالبة واضح؟ أكبر فرق وين موجود؟ مع ال
+
+301
+00:26:05,090 --> 00:26:11,910
+floor أقل فرق العدم مع اليود الأن لاحظوا معي كل ما
+
+302
+00:26:11,910 --> 00:26:16,390
+كان الفرق كبير كل ما جربت الرابط تشبه الرابط
+
+303
+00:26:16,390 --> 00:26:20,890
+الأيونية بمعنى أخر بتصير أقوىو بناء على ذلك لو انا
+
+304
+00:26:20,890 --> 00:26:25,270
+بدى اشوف قوة هذه الروابط اللى هى مع ال flour و ال
+
+305
+00:26:25,270 --> 00:26:29,330
+brom و ال chlor و ال iod هلاحظ انه و اقارنها بقوة
+
+306
+00:26:29,330 --> 00:26:32,750
+رابطة ال carbon-H اللى هى تعتبر بلغة الكيميا رابطة
+
+307
+00:26:32,750 --> 00:26:38,930
+قوية و مش سائل تنقصت ال carbon-H 413 كيلوجول لكل
+
+308
+00:26:38,930 --> 00:26:42,910
+مول بدى عشان اكسر هذه الرابطة الان ال carbon-flour
+
+309
+00:26:42,910 --> 00:26:48,150
+اقوى منهاليش؟ لأن فرق ال polarity عالي صارت تشبه
+
+310
+00:26:48,150 --> 00:26:52,990
+رابطة ايونية قوية ال carboniclor 346 ال
+
+311
+00:26:52,990 --> 00:26:59,910
+carboniclor 290 ال carboniclor 228 أقوى واحدة فيهم
+
+312
+00:26:59,910 --> 00:27:06,670
+مين؟ مع ال fluor الآن جزء أساسي في بناء الكيميا
+
+313
+00:27:06,670 --> 00:27:09,850
+تبع ال alkyl halides ان انا بدي أكسر الرابطة هذه
+
+314
+00:27:09,850 --> 00:27:15,000
+اللي بين ال carbon و ال halogenيعني سواء في تفاعل
+
+315
+00:27:15,000 --> 00:27:20,020
+الإبدال أو الحذف، هذه الرابطة بدها تنكسر طيب ال
+
+316
+00:27:20,020 --> 00:27:23,480
+floor رابطته قوية؟ صعب، صعب، صعب، صعب، صعب، صعب،
+
+317
+00:27:23,480 --> 00:27:24,200
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+318
+00:27:24,200 --> 00:27:24,620
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+319
+00:27:24,620 --> 00:27:24,820
+صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب، صعب،
+
+320
+00:27:24,820 --> 00:27:33,340
+صعب، صعب، صعب، صعب، صعب، صعب،
+
+321
+00:27:33,340 --> 00:27:41,060
+صعب، صعب، صعب،
+
+322
+00:27:41,060 --> 00:27:45,880
+صوبناء على ذلك عندما أعمل إبدال و أخد أمثلة على
+
+323
+00:27:45,880 --> 00:27:50,360
+الإبدال و أعمل حذف و في التفاعلين الإبدال و الحذف
+
+324
+00:27:50,360 --> 00:27:56,800
+تكسر فيه رابطة الأمثلة اللي هشوفها كلور بروم يود
+
+325
+00:27:56,800 --> 00:28:01,880
+مش هشوف أمثلة على ال floor لأن ال floor رابطة قوية
+
+326
+00:28:01,880 --> 00:28:06,380
+صعب كسرها وبناء على ذلك تفاعلات الإبدال و الحذف
+
+327
+00:28:06,380 --> 00:28:11,010
+مرتبطة بدول التلاتة ال floor برا الموضوعواضح
+
+328
+00:28:11,010 --> 00:28:17,150
+الفكرة؟ الآن
+
+329
+00:28:17,150 --> 00:28:22,890
+طالما احنا بنقول بدنا نكسر الرابط مع ال halogen
+
+330
+00:28:22,890 --> 00:28:28,230
+أني أضعف رابط فيهم اليود بناء على ذلك لو انا بعمل
+
+331
+00:28:28,230 --> 00:28:33,530
+تفاعل مع اليود بيكون سهل ولا صعب؟ سهل جداالبروم
+
+332
+00:28:33,530 --> 00:28:37,350
+بقعده في السهولة الكلور بقعده وعشان هيك لو انا بدى
+
+333
+00:28:37,350 --> 00:28:40,990
+اشوف ال rate of reaction لو كنت بفعل يود وبروم
+
+334
+00:28:40,990 --> 00:28:46,270
+وكلور مقارنة بعض و بالبعض أسرع تفاعل مع اليود أسرع
+
+335
+00:28:46,270 --> 00:28:51,580
+من البروم أسرع من الكلورلكلور والسبب قوة الرابطة
+
+336
+00:28:51,580 --> 00:28:56,100
+لأن هنا في رابطة ضعيفة بتنكسر بسهولة واضح الرابطة
+
+337
+00:28:56,100 --> 00:29:00,340
+مع اليود رابطة ضعيفة بتنكسر بسهولة يمكن هذا الكلام
+
+338
+00:29:00,340 --> 00:29:04,100
+حتى في الحياة العملية بتلاحظوا حتى في الحياة
+
+339
+00:29:04,100 --> 00:29:09,320
+العملية بتلاحظوا كثير من الأدوية مثلا موجود مكون
+
+340
+00:29:09,320 --> 00:29:15,660
+أساسي منها اليود هذه الأدوية لو اتعرضت لشوية حرارة
+
+341
+00:29:15,660 --> 00:29:20,980
+بسيطة أو لضوء الشمسبتنكسر الرابطة اللي معاليه طبعا
+
+342
+00:29:20,980 --> 00:29:24,240
+كنا انكسرت الرابطة إذا الدواء كله إيش صار فيه؟ خير
+
+343
+00:29:24,240 --> 00:29:28,680
+وعشان هيك هنلاحظ أن هذا النوع من الأدوية بيحطوه في
+
+344
+00:29:28,680 --> 00:29:33,800
+جزايز غامقة لونها بني وغالبا بيحفظوه بعيدا عن
+
+345
+00:29:33,800 --> 00:29:38,930
+الضوء و الحرارة و أحيانا في حرارة باردةيعني شوف
+
+346
+00:29:38,930 --> 00:29:43,690
+كيف لما مراتب تقرأ على شيء معين يحفظ بعيدا عن
+
+347
+00:29:43,690 --> 00:29:46,730
+الضوء و الحرارة ليش؟ بيكون هذا الشيء المعين فيه
+
+348
+00:29:46,730 --> 00:29:52,790
+روابط ضعيفة حتى حرارة الجو حتى على ضو الشمس ممكن
+
+349
+00:29:52,790 --> 00:29:58,410
+تتكسر فبنصير نحط مثلا جزاز بن يمنع أنه يدخل الضوء
+
+350
+00:29:58,410 --> 00:30:02,030
+بشكل كبير بنقبل حطه بعيد عن الضوء و عن الحرارة
+
+351
+00:30:02,030 --> 00:30:06,870
+ممكن يحتفظ فيهبالتلاجة على سبيل المثال كل هذا
+
+352
+00:30:06,870 --> 00:30:12,670
+نتيجة فهم قوة الروابط الكيميائية و دائما انتوا
+
+353
+00:30:12,670 --> 00:30:16,630
+يعني جزء منكوا في علوم الصحة و جزء في غيرها لحتى
+
+354
+00:30:16,630 --> 00:30:20,190
+تتعاملوا مع أدوى او اشياء اول ما بدكوا تمسكوا اي
+
+355
+00:30:20,190 --> 00:30:28,090
+عبو الدواء شغلتين الشيء الاول صحتكماقرأوا الكلام
+
+356
+00:30:28,090 --> 00:30:33,550
+اللي عليها، ضار، سام، يجوز أن نشمه، لا يجوز، كل
+
+357
+00:30:33,550 --> 00:30:38,050
+هذا الكلام مكتوب على العبوة ويله إشارات معينة،
+
+358
+00:30:38,050 --> 00:30:42,230
+بيحرق كوروسف مثلا زي أحماض إذا انكبت على الإيد
+
+359
+00:30:42,230 --> 00:30:46,200
+بتحرقها، إذا انكبت على الملابس بتحرقهامنفعش
+
+360
+00:30:46,200 --> 00:30:49,400
+الإنسان يتعامل مع أشياء و هو مش عارفها يكون
+
+361
+00:30:49,400 --> 00:30:55,240
+بيتعامل مع سم و بيسيبه ينكب على إيده و مابيغسلش و
+
+362
+00:30:55,240 --> 00:31:00,040
+مابياخدش احتياطات ولا بيلبس gloves ولا أي شيء و
+
+363
+00:31:00,040 --> 00:31:06,940
+شغلت تانية بيكون مكتوب عندكم كلمة storeاحفظه وانت
+
+364
+00:31:06,940 --> 00:31:12,160
+احفظه طبعا شغل اضافية بيكون عندكوا expire date انه
+
+365
+00:31:12,160 --> 00:31:16,120
+هذا بعد فترة معينة ما تفتحوه بيخرب بالذات كتير
+
+366
+00:31:16,120 --> 00:31:20,800
+مركبات بيكون مسكر عليها بشكل محكم لكن لما تفتحوها
+
+367
+00:31:20,800 --> 00:31:26,970
+تتفعل مع oxygen الهواءممكن تتفاعل مع الهوى نفسه أو
+
+368
+00:31:26,970 --> 00:31:31,370
+تمتص رطوبة من الهوى وبناء على ذلك تخرب فهتلاحظوا
+
+369
+00:31:31,370 --> 00:31:35,990
+بعض المراكبات مكتوب عليها لا يستعمل بعد أسبوع أو
+
+370
+00:31:35,990 --> 00:31:41,050
+أسبوعين من فتح العبوة كل إنسان بدي يتعامل بأدوية
+
+371
+00:31:41,050 --> 00:31:45,050
+أو pre agents بدي يكون منتبه لهذه الأمور وإلا
+
+372
+00:31:45,050 --> 00:31:47,470
+بيجعل بإيش؟ بالغلط
+
+373
+00:31:51,720 --> 00:31:57,640
+الان لو اجينا على التفاعلات تبعت ال alkyl halides
+
+374
+00:31:57,640 --> 00:32:04,320
+ممكن البعض يقول طب احنا ما أعطيناش التسمية مشعلة
+
+375
+00:32:04,320 --> 00:32:09,760
+جديدة مرت عليكم لما أخدنا ال alkenes يعني لو انا
+
+376
+00:32:09,760 --> 00:32:15,600
+جبتلكوا هذا المركب هذا
+
+377
+00:32:15,600 --> 00:32:22,830
+ال alkyl halide مين تسميه؟احد اتنين تلاتة اربعة
+
+378
+00:32:22,830 --> 00:32:30,340
+خمسة بنتين اثنان كلورو اثنان مثل بنتينأخدنا
+
+379
+00:32:30,340 --> 00:32:36,180
+التسمية ولا لأ؟ أخدنا التسمية طيب واحدة بتقول ماشي
+
+380
+00:32:36,180 --> 00:32:40,800
+التسمية أخدناها طيب و ال preparation التحضير هو
+
+381
+00:32:40,800 --> 00:32:45,220
+احنا عادة لما بندرس عائلة كيميائية اول اشي بنتعرف
+
+382
+00:32:45,220 --> 00:32:49,420
+على العائلة بعدين بناخد ال nomenclature التسمية
+
+383
+00:32:49,420 --> 00:32:54,500
+بعدين التحضير بعدين التفاعلات احنا عمال جاعدين
+
+384
+00:32:54,500 --> 00:33:00,060
+بنفض جزءالتسمية وشوفنا أننا أخدناها طب و جزء
+
+385
+00:33:00,060 --> 00:33:04,800
+التحضير أخدناها
+
+386
+00:33:04,800 --> 00:33:09,420
+من أكثر من طريقة أخدناها بأكثر من طريقة لما كنا
+
+387
+00:33:09,420 --> 00:33:13,220
+نيجي نقولكم مثلا ابرو بيل و اعملوله chlorination
+
+388
+00:33:13,220 --> 00:33:20,960
+شو كنتوا تطلعوا؟One Chloro, Two Chloro مش هذي
+
+389
+00:33:20,960 --> 00:33:25,680
+Alkyl Halides إذا ال Direct Halogenation طريقة من
+
+390
+00:33:25,680 --> 00:33:30,500
+طرق التحضير ولا لأ و حلينا عليها أمثلة تأكيد ..
+
+391
+00:33:30,500 --> 00:33:36,120
+تأكيد لما كنا .. هاي أول طريقة ال Halogenation طب
+
+392
+00:33:36,120 --> 00:33:42,440
+لو أعطيناكوا هذا المركب و قولنا لكم ضيفوا عليه HBR
+
+393
+00:33:46,050 --> 00:33:50,770
+هتقولولي مع Markovnikov ولا أنت Markovnikov؟ إذا
+
+394
+00:33:50,770 --> 00:33:55,510
+Markovnikov بيجي H و PR to Bromo وإذا أنت
+
+395
+00:33:55,510 --> 00:34:01,390
+Markovnikov H و PR و لا Bromo هذه المركبات مش ال
+
+396
+00:34:01,390 --> 00:34:06,230
+الهيليتز اللي نتجت الطريقة إذا أخدناها فإيش طروب
+
+397
+00:34:06,230 --> 00:34:12,210
+تحضير ال الهيليتز؟ نمرة واحد ال halogenation of
+
+398
+00:34:12,210 --> 00:34:20,960
+alkenesالـ Halogenation طب نمره اتنين ال addition
+
+399
+00:34:20,960 --> 00:34:29,660
+of HX to الكيين أو الكايين كمان لما كنا نضيف على
+
+400
+00:34:29,660 --> 00:34:37,360
+الكاين مرتين واضح؟ في طرق تالتة أخدناها في طريق
+
+401
+00:34:37,360 --> 00:34:42,920
+تالت لو هنا إجينا ضفنا على نفس هذا المركب PR2
+
+402
+00:34:46,320 --> 00:34:50,940
+أيش كان يعطيني؟ كان يعمل لي إضافة two PR atoms
+
+403
+00:34:50,940 --> 00:34:56,800
+بسين ولا ب Anti-addition؟ Anti-addition هيعمل لي
+
+404
+00:34:56,800 --> 00:35:03,020
+dihalo compound هذه طريقة الإبوكسايد رينج لو
+
+405
+00:35:03,020 --> 00:35:07,020
+فتحناها برضه بتصير طريقة إذا إحنا أخدنا الحقيقة
+
+406
+00:35:07,020 --> 00:35:14,730
+أكثر من طريقة لتحضيرالـ Halo Compounds في طريقة
+
+407
+00:35:14,730 --> 00:35:17,890
+إضافية
+
+408
+00:35:17,890 --> 00:35:23,610
+غير التلات طرق هدول اللي هم ال ال ال ال ال ال ال
+
+409
+00:35:23,610 --> 00:35:24,970
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+410
+00:35:24,970 --> 00:35:25,010
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+411
+00:35:25,010 --> 00:35:28,170
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+412
+00:35:28,170 --> 00:35:28,990
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+413
+00:35:28,990 --> 00:35:29,570
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+414
+00:35:29,570 --> 00:35:29,610
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+415
+00:35:29,610 --> 00:35:29,610
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+416
+00:35:29,610 --> 00:35:29,610
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+417
+00:35:29,610 --> 00:35:29,610
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+418
+00:35:29,610 --> 00:35:29,610
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+419
+00:35:29,610 --> 00:35:33,550
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+420
+00:35:33,550 --> 00:35:33,550
+ال ال
+
+421
+00:35:39,410 --> 00:35:46,970
+بتفاعلها ما عدش X أخليها RX يعني تحويل الكحول إلى
+
+422
+00:35:46,970 --> 00:35:51,810
+الكلهلايت هذه الطريقة لها تفاصيل كتير لما ندرس
+
+423
+00:35:51,810 --> 00:35:55,630
+chapter الكحولات بندرس كتفاعل على الكحول يعني
+
+424
+00:35:55,630 --> 00:36:00,290
+بإمكاننا ندرسها الأن كطريقة للتحضير و بإمكاننا
+
+425
+00:36:00,290 --> 00:36:05,900
+ندرسها في chapter الكحولات كتفاعل على الكحولواضح؟
+
+426
+00:36:05,900 --> 00:36:10,640
+هذا كحول، هذا الكلهلايت، بالنسبة للكحول هي تفاعل،
+
+427
+00:36:10,640 --> 00:36:14,980
+بالنسبة لالكلهلايت هي طريقة تحضير، لما ندرس
+
+428
+00:36:14,980 --> 00:36:19,720
+الكحولات و تفاعلاتها، هيكون عندنا تفاعل أساسي
+
+429
+00:36:19,720 --> 00:36:27,560
+تحويلالكحول إلى ال alkyl halides بمجموعة من
+
+430
+00:36:27,560 --> 00:36:31,440
+التفاصيل بندرسها بوقته، هاي بتصير كمان طريقة
+
+431
+00:36:31,440 --> 00:36:39,390
+إضافية لتحضير ال alkyl halidesكام طريقة؟ اربعة مين
+
+432
+00:36:39,390 --> 00:36:44,790
+تقول اليوم باختصار اتفضلي ال direct halogenation
+
+433
+00:36:44,790 --> 00:36:48,330
+في وجود الضوء او الحرارة لل ال alkenes اضافة ال X2
+
+434
+00:36:48,330 --> 00:36:56,190
+لل ال alkenes او اضافة ال HX
+
+435
+00:36:56,190 --> 00:37:01,620
+لل ال alkenes او لل ال alkynesو بعدين من الكحولات
+
+436
+00:37:01,620 --> 00:37:05,900
+في وجود HX او reagents تانية بندرسها في chapter
+
+437
+00:37:05,900 --> 00:37:10,860
+الكحولات هيصيرنا ذاكرينكوا كم طريقة اربع طرق
+
+438
+00:37:10,860 --> 00:37:15,380
+لتحضير ال alkyl halides تلاتة أخدتهم و طريقة
+
+439
+00:37:15,380 --> 00:37:24,180
+بندرسها في chapter الكحولات الآن التفاعل الأساسي
+
+440
+00:37:24,180 --> 00:37:30,380
+لل alkyl halides هو تفاعلالإبدال التفاعل الأساسي
+
+441
+00:37:30,380 --> 00:37:34,860
+لـ alkalites هو تفاعل الإبدال لو أنا أتي أتطلع طيب
+
+442
+00:37:34,860 --> 00:37:38,920
+إيش اللي بده أبدله؟ وكيف بده يتم الإبدال اللي
+
+443
+00:37:38,920 --> 00:37:44,480
+عندي؟ اتطلعوا هاي عندي carbon حاملة نفترض PR وهنا
+
+444
+00:37:44,480 --> 00:37:49,400
+في تلت روابط، بلاش نركز عليهم شو هما الآن إيش
+
+445
+00:37:49,400 --> 00:37:55,520
+اتفقنا على الرابط اللي موجود هنا؟قول لعنها بولا
+
+446
+00:37:55,520 --> 00:38:02,180
+يعني هذه موجبة وهذه سالبة بناء على ذلك هلاحظ أن
+
+447
+00:38:02,180 --> 00:38:06,720
+التفاعل الأساسي عندنا لما بناجي المرة الجاية اللي
+
+448
+00:38:06,720 --> 00:38:10,500
+اتكلم أنه بيجي نيوكليوفايل لإن نيوكليوفايل حامل
+
+449
+00:38:10,500 --> 00:38:15,840
+إلكترونات وين بيهاجم؟ على الكاربون الموجب يعني هذا
+
+450
+00:38:15,840 --> 00:38:22,560
+سالب للنيوكليوفايل سالب بيجي إيش بيطلعك باله؟ سالب
+
+451
+00:38:23,370 --> 00:38:27,830
+السالب هاجم على الكربون الموجب، طرد سالب إجا سالب،
+
+452
+00:38:27,830 --> 00:38:33,550
+طرد سالب، إجا موجب، طرد موجب أخدنا في البنزين
+
+453
+00:38:33,550 --> 00:38:38,190
+الإبدال إيش كان؟ موجب مكان موجب، سميناها
+
+454
+00:38:38,190 --> 00:38:41,950
+Electrophilic Substitution الآن هنا بدو ييجي سالب
+
+455
+00:38:41,950 --> 00:38:47,030
+مكان سالب، يعني إيش اللي بدو يطرد؟ ال X مع
+
+456
+00:38:47,030 --> 00:38:52,340
+إلكتروناته، شو اللي بدو يهاجم؟لنيوكليوفايل و بناء
+
+457
+00:38:52,340 --> 00:38:56,880
+على ذلك بيصير المفروض فينا نتذكر ايش معنى
+
+458
+00:38:56,880 --> 00:39:01,040
+النيوكليوفايل اللي بدو يهاجم هنا و يحل محل ال X
+
+459
+00:39:01,040 --> 00:39:06,220
+ولذلك المرة القادمة هنبدأ من كلمة ايش الـ
+
+460
+00:39:06,220 --> 00:39:11,190
+Eucleophilic Substitution يعني نبدأ نتعرف علىللـ
+
+461
+00:39:11,190 --> 00:39:14,950
+nucleophile اللي بده يهاجم ويبدأ التفاعل لأن الـ
+
+462
+00:39:14,950 --> 00:39:18,790
+nucleophile هو السالب اللي بده يهاجم ويحل محل
+
+463
+00:39:18,790 --> 00:39:23,630
+الهالوجين السالبة يعمل عملية الإبدال شكرا
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/Mr5OFkzyiYs_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/Mr5OFkzyiYs_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..4bf39b1db011da894261ebc4a8aa5e7acc88bb80
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/Mr5OFkzyiYs_postprocess.srt
@@ -0,0 +1,2140 @@
+1
+00:00:21,410 --> 00:00:26,010
+بسم الله الرحمن الرحيم بدأنا احنا في محاضرات ماضية
+
+2
+00:00:26,010 --> 00:00:31,390
+في تفاعلات ال alkanes ويمكن لاحظنا ان الأمر في هذه
+
+3
+00:00:31,390 --> 00:00:36,690
+المنطقة هو أمر سهل جدا مافيش فيه مشاكل الرابطة
+
+4
+00:00:36,690 --> 00:00:41,450
+الزوجية من خلال تفاعل الإضافة بتصير رابطة أحدية
+
+5
+00:00:42,020 --> 00:00:45,740
+الاشياء المتعلقة بهذا التفاعل اللى اتكلمنا عنها
+
+6
+00:00:45,740 --> 00:00:50,220
+كانت طبيعة ال الكين و طبيعة ال reagent هل ال الكين
+
+7
+00:00:50,220 --> 00:00:54,400
+symmetric هل ال reagent symmetric و هذا الكلام أدى
+
+8
+00:00:54,400 --> 00:00:58,140
+إلى انه مرات بيكون في عندنا اضافات حسب قاعدة
+
+9
+00:00:58,140 --> 00:01:01,760
+Markovnikov او عكس قاعدة Markovnikov حسب طبيعة
+
+10
+00:01:02,350 --> 00:01:05,850
+التفاعل اللى بنعمله اخر شغل انتهينا عنده في
+
+11
+00:01:05,850 --> 00:01:11,030
+المحاضرة الماضية انه احنا ايضا ممكن نضيف oxygen
+
+12
+00:01:11,030 --> 00:01:16,050
+على ال double bond من خلال تفاعل ال alkenes مع ال
+
+13
+00:01:16,050 --> 00:01:20,030
+bare acids بيعطونا ال epoxides اللى هى الحلقات
+
+14
+00:01:20,030 --> 00:01:25,510
+الثلاثية اتعلمنا تسميتها بطريقتين سواء ان نسميها
+
+15
+00:01:25,510 --> 00:01:30,300
+من خلال ان نقولالكين اكسايد نذكر اسم الالكين
+
+16
+00:01:30,300 --> 00:01:34,720
+الأصلي اللى نتجت منه او من خلال اننا نعتبر ال
+
+17
+00:01:34,720 --> 00:01:37,360
+parent ring يعني الحلقة الأساسية اللى كلها
+
+18
+00:01:37,360 --> 00:01:43,720
+هيدروجين اسمها oxirane و الرقم من عند ال oxygen و
+
+19
+00:01:43,720 --> 00:01:51,200
+نذكر أسماء ال substituents اللى موجودةأيضا ركزنا
+
+20
+00:01:51,200 --> 00:01:55,660
+على نقطة أن هذه الحلقة الثلاثية هي حلقة مضغوطة is
+
+21
+00:01:55,660 --> 00:02:00,560
+a strained ring ليش؟ لأن الزوايا فيها ضغطت إلى
+
+22
+00:02:00,560 --> 00:02:04,720
+الستين الوضع المريح لزاوية ال carbon carbon carbon
+
+23
+00:02:04,720 --> 00:02:10,020
+او ما شابه مية وتسعة و نص ولذلك أسهل تفاعل فيها
+
+24
+00:02:10,020 --> 00:02:14,440
+اللي هو تفاعل ال ring opening فاحنا صح بنكون
+
+25
+00:02:14,440 --> 00:02:20,350
+الحلقةلكن الحلقة strain فلما تتجه تعمل ring
+
+26
+00:02:20,350 --> 00:02:26,250
+-opening فكرة ال ring-opening كانت مبنية على انه
+
+27
+00:02:26,250 --> 00:02:31,670
+اذا اتذكرنا احنا ان الاكسجين electronegative اكثر
+
+28
+00:02:31,670 --> 00:02:35,830
+من الكربون يعني الاكسجين partially negative ال two
+
+29
+00:02:35,830 --> 00:02:42,210
+carbons هيكونوابارشالة positive فانا لو جبت اي شيء
+
+30
+00:02:42,210 --> 00:02:46,250
+بده يتفاعل مع الموجب والاصل يكون سالم سمينا
+
+31
+00:02:46,250 --> 00:02:51,230
+نيوكليوفايل هاجم هنا النتيجة انه هيكسر هذه الرابطة
+
+32
+00:02:51,230 --> 00:02:55,970
+مش هيصير عنده خمس روابط فلما ييجي اي نيوكليوفايل
+
+33
+00:02:57,150 --> 00:03:02,150
+هاجم على هذا الكرمون هتنكسر الرابط أزواج
+
+34
+00:03:02,150 --> 00:03:08,050
+الألكترونات هيكون مع الـ O O minus بياخد H غالبا
+
+35
+00:03:08,050 --> 00:03:12,890
+الـ H هذه بتكون مع الـ nucleophile فهيصف ايش O H
+
+36
+00:03:12,890 --> 00:03:17,230
+او احنا بنعمل catalysis للتفاعل بـ H plus يعني
+
+37
+00:03:17,230 --> 00:03:22,690
+مثلا الميه فيها جزء ايه لو تشوفوا محصلة التفاعل O
+
+38
+00:03:22,690 --> 00:03:31,120
+H اللي هي تمثللنكليوفاي و في اتش فهذا لنكليوفاي لو
+
+39
+00:03:31,120 --> 00:03:38,130
+اتفعل من هنا وصف في الآخر انه حط OHL شو ضال عندكH
+
+40
+00:03:38,130 --> 00:03:42,870
+هتيجي وين؟ على هذه الـ O أو لو أنا كنت عامل acid
+
+41
+00:03:42,870 --> 00:03:47,530
+catalysis الـ H تبعت ال acid في الأساس هي اللي
+
+42
+00:03:47,530 --> 00:03:52,410
+بتيجي و بيطلع بدلها H plus لكن كمحصلة كمعادلة
+
+43
+00:03:52,410 --> 00:03:57,370
+موزونة كمعادلة موزونة لو بتتطلع على هذا المركب لو
+
+44
+00:03:57,370 --> 00:04:02,580
+بتتطلع على هذا المركباللي أنا بادى فيه وهذا المركب
+
+45
+00:04:02,580 --> 00:04:07,140
+اللى طلع عندى هتلاحظوا هى ال OH اللى اجت من الميه
+
+46
+00:04:07,140 --> 00:04:12,700
+وهىالـ H هيصل في ميّه إذا المعادلة بهذا الشكل
+
+47
+00:04:12,700 --> 00:04:17,460
+موصولة ولا لأ تماما كاربون كاربون أكسوجين وإيجي
+
+48
+00:04:17,460 --> 00:04:23,800
+عنده من الميّه الـ OH والـ H في كل الأحوال تفاعل
+
+49
+00:04:23,800 --> 00:04:28,500
+ال ring opening سهل جدا أن نطبقه بدنا نقول أن هذه
+
+50
+00:04:28,500 --> 00:04:35,720
+الحلقة بدأ تصير CCOH بما تحملهيعني لو كانت هنا
+
+51
+00:04:35,720 --> 00:04:40,080
+بتحمل H2 وهنا H2، بيظلوا زي ما هما، H و مثل وهنا
+
+52
+00:04:40,080 --> 00:04:43,820
+H2، بيظلوا زي ما هما، إيش ما بتحمل هنا، هدولة مش
+
+53
+00:04:43,820 --> 00:04:47,760
+موقع تفاعل، ما بتغيروش، أيًا كانوا، إيش ما
+
+54
+00:04:47,760 --> 00:04:51,200
+بيكونوا، هدول المجموعات بتغيروش، اللي بيصير عنده C
+
+55
+00:04:53,120 --> 00:04:58,840
+OH وهنا بدو ييجي عنده لنيوكليوفايل طبعا إذا كان
+
+56
+00:04:58,840 --> 00:05:05,100
+المتفاعل الماء لنيوكليوفايل OH طب إذا المتفاعل HX
+
+57
+00:05:05,100 --> 00:05:13,240
+لنيوكليوفايل X إذا المتفاعل RO- هيكون RO وبتيجي H
+
+58
+00:05:13,240 --> 00:05:18,020
+من هنا بهذا الشكل إذا الشيء المشترك هنا الشيء
+
+59
+00:05:18,020 --> 00:05:22,580
+المشترك هنا أنه هتشوفوا هذه القطعة
+
+60
+00:05:25,740 --> 00:05:37,660
+CCOH CCOH CCOH CCOH CCOH
+
+61
+00:05:37,660 --> 00:05:44,900
+CCOH CCOH CCOH CCOH CCOH CCOH CCOH CCOH CCOH CCOH
+
+62
+00:05:44,900 --> 00:05:49,920
+CCOHأي مجموعات كانت موجودة عليهم اصلا يعني لو كنت
+
+63
+00:05:49,920 --> 00:05:53,760
+بدي انا في ال parent compound يعني هذه CH2 CH2
+
+64
+00:05:53,760 --> 00:06:01,540
+هتكون النتيجة OH CH2 CH2 OH لو هدولة C مثل 2 مثل 2
+
+65
+00:06:01,540 --> 00:06:09,100
+هيكون OH C مثل 2 C مثل 2 و هكذا واضح؟ بهذا الشكل
+
+66
+00:06:09,100 --> 00:06:15,230
+بتم التفاعد ولذلك مرات كتير لما بنشوف عندنالما
+
+67
+00:06:15,230 --> 00:06:20,510
+بنشوف إنه في تفاعلات موجود CH2 CH2 OH ممكن نفكر إن
+
+68
+00:06:20,510 --> 00:06:27,150
+هدولة إجوا من حلقة إيش Oxirane حلقة Oxirane CH2
+
+69
+00:06:27,150 --> 00:06:31,190
+CH2 OH اتفاعلت مع نيوكليوفايل بيضطر نيوكليوفايل
+
+70
+00:06:31,190 --> 00:06:39,600
+CH2 CH2واضح؟ طبعا في حالات ممكن المجموعات اللى
+
+71
+00:06:39,600 --> 00:06:43,480
+موجودة على ال carbon في هدولة النقطين تكون مختلفة
+
+72
+00:06:43,480 --> 00:06:49,780
+يعني ممكن مثلا تلاحظوا ان هذه تكونسي أتش تو وهنا
+
+73
+00:06:49,780 --> 00:06:53,700
+سي أتش و سي أتش ثري و بتكون تيجي تفعله الماء
+
+74
+00:06:53,700 --> 00:06:57,560
+لاحظوا هتصيروا متحيرين هل يا ترى النيوكليوفايل
+
+75
+00:06:57,560 --> 00:07:01,540
+هتخلوه يتفعل على هذا الكربون و لا على هذا الكربون
+
+76
+00:07:01,540 --> 00:07:04,600
+من ناحية المبدأ هذا موجبة و هذا موجبة دائما
+
+77
+00:07:04,600 --> 00:07:08,560
+النيوكليوفايل هتفعل على الكربون اللي بتحمل الكربون
+
+78
+00:07:08,560 --> 00:07:14,230
+أكثرتعرفوا تصنيفات ال carbon primary و secondary و
+
+79
+00:07:14,230 --> 00:07:18,090
+tertiary حسب ما بيحمل carbons فالتفاعل على ال
+
+80
+00:07:18,090 --> 00:07:21,930
+carbon اللي بتحمي ال carbons أكثر بيكون مفضل يعني
+
+81
+00:07:21,930 --> 00:07:25,090
+في هذه الحالة لو كنا بنفعل ميه هل يا ترى ال O
+
+82
+00:07:25,090 --> 00:07:28,550
+هتيجي تهاجم على هذا ال carbon ولا هذا ال carbon و
+
+83
+00:07:28,550 --> 00:07:35,650
+هنا هيصير أن ال O أتش هذا لو مر علينامثال بهذا
+
+84
+00:07:35,650 --> 00:07:41,150
+الشكل طبعا في كل الأحوال لأن هذه حلقة لأن هذه حلقة
+
+85
+00:07:41,150 --> 00:07:46,430
+هنلاحظ ان النيوكليوفايل هيجي من جهة و ال OH هتكون
+
+86
+00:07:46,430 --> 00:07:51,390
+من الجهة المعاكزة واضح ان هذا بيأثر على النواتج او
+
+87
+00:07:51,390 --> 00:07:56,510
+لا هذا موضوع ثاني لكن الإضافة هنا بتكون sin ولا
+
+88
+00:07:56,510 --> 00:08:02,550
+anti additionبتكون Anti-Addition الإضافة هنا بتكون
+
+89
+00:08:02,550 --> 00:08:05,750
+Anti-Addition يعني الـ Nucleophile بيجي من الجهة
+
+90
+00:08:05,750 --> 00:08:10,270
+المعاكسة لجهة تكوّن الـ OH ملاحظين منهم Anti
+
+91
+00:08:10,270 --> 00:08:13,690
+-Addition؟
+
+92
+00:08:13,690 --> 00:08:19,970
+الآن لاحظوا لو فكرنا مثلا أنه بدنا نضيف مجمعتين OH
+
+93
+00:08:21,270 --> 00:08:26,050
+من جهة واحدة يعني هذه الطريقة انه حولنا الالكين ل
+
+94
+00:08:26,050 --> 00:08:32,730
+ابوكسايد وفتحنا الحلقة اعطتنا مجموعتين OHمن جهتين
+
+95
+00:08:32,730 --> 00:08:37,370
+متعاكستين طب لو فكرنا انه بدنا نضيف المجموعتين من
+
+96
+00:08:37,370 --> 00:08:42,710
+جهة واحدة في عندنا تفاعل تاني ممكن نعمله مباشرة
+
+97
+00:08:42,710 --> 00:08:48,130
+على ال الكين و بضيف مجموعتين OH من جهة واحدة هذا
+
+98
+00:08:48,130 --> 00:08:54,170
+التفاعل ان نفعل ال الكين سواء مع مركب ال Osmium O4
+
+99
+00:08:54,170 --> 00:08:59,340
+في وجود هذه الأشياءكتاليست او مع مركب كيامان O4
+
+100
+00:08:59,340 --> 00:09:03,540
+بيرمانجانات البوتاسيوم سواء قلنا أزوميام الأزوميام
+
+101
+00:09:03,540 --> 00:09:08,320
+عنصر معدن ثقيل تقريبا هو أثقل العناصر يعني كثافته
+
+102
+00:09:08,320 --> 00:09:14,300
+أعلى حتى من الدهب واشي فوق العشرين جرام لكل سنتمتر
+
+103
+00:09:14,300 --> 00:09:21,180
+مكعبواضح؟ سواء قلنا Osmium O4 او KMnO4 انا بحكي عن
+
+104
+00:09:21,180 --> 00:09:27,520
+معدل مثل ال مثل Osmium او مانجانيز وهذا متصل بكم
+
+105
+00:09:27,520 --> 00:09:32,990
+مجموعة Oهيبقى أربعة، الآن لما بديجي يتفاعل مع
+
+106
+00:09:32,990 --> 00:09:36,310
+double bond لما بديجي يتفاعل مع double bond هي
+
+107
+00:09:36,310 --> 00:09:40,650
+double bond أكيد هيتفاعل من خلال أكسجنتين موجودات
+
+108
+00:09:40,650 --> 00:09:45,630
+على جهة واحدة و بعد هيك تنكسر هذه الرابطة مع
+
+109
+00:09:45,630 --> 00:09:51,530
+المعدنتم التفاعل بهذا الشكل هذي هتاخد من مجمل
+
+110
+00:09:51,530 --> 00:09:58,130
+التفاعل HOOH أكيد أجه من جهة واحدة فالتفاعل هذا
+
+111
+00:09:58,130 --> 00:10:02,150
+بتتم من جهة واحدة لأنه بإمكانكوا ببساطة تتخيلوا
+
+112
+00:10:02,150 --> 00:10:08,050
+الكيامان O4 زي هيك هاي .. هاي الأربع ذرات أكسوجين
+
+113
+00:10:08,050 --> 00:10:12,680
+اللي موجودين فيه الآن بدو يهاجم ع double bondبيقدر
+
+114
+00:10:12,680 --> 00:10:17,060
+يهاجم من جهتين؟ لأ بالتاكيد هيهاجم من هنا و من هنا
+
+115
+00:10:17,060 --> 00:10:22,500
+حذرتين أكسجين من جهة واحدة فإضافة مجموعات ال OH
+
+116
+00:10:22,500 --> 00:10:28,220
+باستعمال ال Osmium O4 أو الكيامان O4 في وجود طبعا
+
+117
+00:10:28,220 --> 00:10:32,000
+ما basic medium كل الأشياء اللي أمامكم هو عبارة عن
+
+118
+00:10:32,000 --> 00:10:37,040
+sin ولا anti addition؟ sin addition ابهيك بنذكر
+
+119
+00:10:37,040 --> 00:10:40,580
+إيش الأشياء اللي بتصيروا ماخدينها sin addition؟
+
+120
+00:10:42,290 --> 00:10:49,270
+إضافة الـ hydrogen و إضافة مجموعات ال OH باستعمال
+
+121
+00:10:49,270 --> 00:10:54,710
+ال Osmium O4 أو الكيامان O4 لما أخدنا إضافة ال PR2
+
+122
+00:10:54,710 --> 00:11:00,150
+أخدناها Anti addition لما أخدنا إضافة ال PR2
+
+123
+00:11:00,150 --> 00:11:06,290
+أخدناها Anti addition مش Sin addition واضح؟ ولذلك
+
+124
+00:11:06,290 --> 00:11:12,720
+لو مثلا جيبنا لكم مركب زي هذاخلنا ناخد مثال
+
+125
+00:11:12,720 --> 00:11:17,540
+Cyclopentane
+
+126
+00:11:17,540 --> 00:11:26,060
+طبعا ك Cyclopentane شو عليها؟H وH وسألناكم سؤال
+
+127
+00:11:26,060 --> 00:11:31,280
+قلنا لكم كيف ممكن تحضروا من هذا Cyclobentane
+
+128
+00:11:31,280 --> 00:11:37,540
+Cyclobentadiol يعني Cyclobentane شيلنا منه ال
+
+129
+00:11:37,540 --> 00:11:40,900
+double bond و حاطينا مجموعتين OH يعني بدل ال
+
+130
+00:11:40,900 --> 00:11:44,780
+double bond مجموعتين OH مرة يكونوا ال cis و مرة
+
+131
+00:11:44,780 --> 00:11:49,600
+يكونوا ال trans كأنه بيصير السؤال انه كيف بدي احضر
+
+132
+00:11:49,600 --> 00:11:59,490
+منههذا المُركّب اللي فيه مجموعتين الـ OH على جهة
+
+133
+00:11:59,490 --> 00:12:06,270
+واحدة و بدي أحضر منه أيضا المُركّب اللي فيه
+
+134
+00:12:06,270 --> 00:12:11,930
+مجموعتين الـ OH على جهتين متعاكستين اللي هم الـ
+
+135
+00:12:11,930 --> 00:12:13,330
+CIS والـ Trans
+
+136
+00:12:18,820 --> 00:12:21,820
+واضح؟ how can you prepare this is and
+
+137
+00:12:21,820 --> 00:12:27,060
+transcyclobentane diol starting from cyclobentene
+
+138
+00:12:27,060 --> 00:12:32,960
+الان في الحالة الأولى الجواب مباشر في الحالة
+
+139
+00:12:32,960 --> 00:12:37,040
+الأولى الجواب مباشر بدى استعمل اما طريقة ال
+
+140
+00:12:37,040 --> 00:12:41,760
+ozomium o4 او ال camon o4 نفس الشيء خلنا نقول مثلا
+
+141
+00:12:41,760 --> 00:12:49,610
+camon o4 فيباسيك ميديام في وجود الماء ألاحظوا
+
+142
+00:12:49,610 --> 00:12:54,210
+انتبهوا جيدا لو سمحتوا الكيامان اوفور عشان تعمل
+
+143
+00:12:54,210 --> 00:12:57,910
+هذا التفاعل و تضيف من جهتين بدا تكون في basic
+
+144
+00:12:57,910 --> 00:13:02,550
+medium في وجود OH- هذه بديكوا تركزوا عليها لسبب
+
+145
+00:13:02,550 --> 00:13:06,590
+بسيط انه في تفاعلات تانية سواء درسناها او
+
+146
+00:13:06,590 --> 00:13:10,850
+مادرسناهاش تفاعل الكيامان اوفور في acidic medium
+
+147
+00:13:10,850 --> 00:13:16,780
+بيعطيني أشياء تانيةواضح فركزوا ان هذا التفاعل بتم
+
+148
+00:13:16,780 --> 00:13:22,320
+في basic و medium الان لو قولنا المركب التاني كيف
+
+149
+00:13:22,320 --> 00:13:30,080
+بدنا نحضره على خطوتين اذا
+
+150
+00:13:30,080 --> 00:13:34,740
+انا في الاول بدي اجي اقول bare acid مثلا فينيل
+
+151
+00:13:34,740 --> 00:13:39,580
+COOOH و
+
+152
+00:13:39,580 --> 00:13:44,720
+استعمل و يعطيني ال ابوكسايدو بعدين بوجود ال ..
+
+153
+00:13:44,720 --> 00:13:49,480
+بساط حمضي مع .. هاي ال Evoxide واضح؟ أخدنا هذا
+
+154
+00:13:49,480 --> 00:13:54,440
+التفاعل بيصير Cyclopentene
+
+155
+00:13:54,440 --> 00:14:01,080
+Oxide و بعد هيك لما أجي أفعله مع ال H2O H plus
+
+156
+00:14:01,080 --> 00:14:05,300
+بيعمل ring opening O H بتيجي من هنا O Hواحدة من
+
+157
+00:14:05,300 --> 00:14:08,600
+التحت وواحدة من الفوق إذا هذا التفاعل بتتم على
+
+158
+00:14:08,600 --> 00:14:12,860
+خطوة ولا على خطوة إيه؟ على خطوة إيه؟ هذا التفاعل
+
+159
+00:14:12,860 --> 00:14:24,220
+على خطوة واحدة واضح
+
+160
+00:14:24,220 --> 00:14:24,960
+المثال؟
+
+161
+00:14:48,060 --> 00:14:52,220
+من التفاعلات اللى بدنا ندرسها ايضا لل Alkanes
+
+162
+00:14:52,220 --> 00:14:59,040
+تفاعل جديد الان مش تفاعل اضافة تفاعل bond cleavage
+
+163
+00:14:59,040 --> 00:15:03,480
+بمعنى بيكسر ال double bond نصين يعني اتطلعوا معاه
+
+164
+00:15:03,480 --> 00:15:07,000
+هذي ال double bond التفاعل اللى بدنا ندرسه الان
+
+165
+00:15:07,000 --> 00:15:11,800
+بدوش يضيف حوله من double ل single كل ما درسناه كان
+
+166
+00:15:11,800 --> 00:15:16,180
+addition reactions لحد الان كل ما درسناه كان
+
+167
+00:15:16,180 --> 00:15:19,970
+addition double bondتصير single bond الآن بدنا
+
+168
+00:15:19,970 --> 00:15:23,590
+ناخد نوع تاني من تفاعلات ال double bond اللي هو
+
+169
+00:15:23,590 --> 00:15:27,030
+cleavage reaction ان اجعل double bond و اكسرها
+
+170
+00:15:27,030 --> 00:15:32,950
+نصين هذا التفاعل بنسميه ozonolysis of alkenes وزي
+
+171
+00:15:32,950 --> 00:15:38,750
+ما قلت هو تفاعل ايشCleavage تفاعل كسر بيكسر ال
+
+172
+00:15:38,750 --> 00:15:43,010
+double bond نصين بتم هذا التفاعل من خلال التفاعل
+
+173
+00:15:43,010 --> 00:15:48,210
+مع ال ozone بتعرفوا ال ozone الأكسجل في الطبيعة O2
+
+174
+00:15:48,210 --> 00:15:52,810
+وإله ألوتروب بنسميها أو صورة تقاصلية تانية يعني
+
+175
+00:15:52,810 --> 00:15:58,070
+صورة فيزيائية تانية اسمها ايش ozone زي ما الكربون
+
+176
+00:15:58,070 --> 00:16:02,960
+في الطبيعة بنوجد على شكلGraphite و Diamond و
+
+177
+00:16:02,960 --> 00:16:09,080
+Carbon-60 او زي ما الفوسفور مثلا في الطبيعة فوسفور
+
+178
+00:16:09,080 --> 00:16:13,220
+أبيض فوسفور أحمد هذه صورة فيزيائية للمادة لنفس
+
+179
+00:16:13,220 --> 00:16:17,840
+المادة الآن ال Oxygen في الطبيعة ممكن ينوجد على
+
+180
+00:16:17,840 --> 00:16:22,860
+شكل Oxygen عادي O2 و ممكن ينوجد على شكل Ozone اللي
+
+181
+00:16:22,860 --> 00:16:27,540
+عادة موجود في الاطسفير في طبقات الجو العليا و
+
+182
+00:16:27,540 --> 00:16:33,380
+بعدينبتعرف مشكلة الأوزون لو فعلنا هذا المُركّب مع
+
+183
+00:16:33,380 --> 00:16:39,220
+الأوزون بداية وبعدين مع زنك في وجود حامض بيكوّنلنا
+
+184
+00:16:39,220 --> 00:16:42,440
+مُركّب وسيط مش كثير محتم أننا نحفظه أوزونويت
+
+185
+00:16:42,440 --> 00:16:48,260
+بنسميه هذه الأوزون التلاتة وبعد هيك بتكسر الرابطة
+
+186
+00:16:48,260 --> 00:16:53,710
+اللي هي بين الكاربون والكاربون هذهDouble bond
+
+187
+00:16:53,710 --> 00:16:57,470
+بتصير هنا C double bond O وهذه بتصير C double bond
+
+188
+00:16:57,470 --> 00:17:04,250
+O يعني الكسر من وين هيتملما نجي نفذ الناتج مش كل
+
+189
+00:17:04,250 --> 00:17:07,350
+مرة بدنا نكون عارفين ال intermediate ناخدها لمرة
+
+190
+00:17:07,350 --> 00:17:11,650
+واحدة لكن أنا بدي أنفذ أكتب الناتج بدي أجي أتخيل
+
+191
+00:17:11,650 --> 00:17:16,290
+أنه معي مساحة كسرت الرابطة من هنا هذه هتصير C
+
+192
+00:17:16,290 --> 00:17:22,690
+double bond O وهذه هتصير C double bond O هيعطيني
+
+193
+00:17:22,690 --> 00:17:25,570
+تنتين C double bond O لاحظوا الناتج هنا هذه
+
+194
+00:17:25,570 --> 00:17:32,150
+البنزينة وحملة CH وإيش صارتC double bond O وهنا
+
+195
+00:17:32,150 --> 00:17:38,270
+عندكم CH2 إيش صارت كمان C double bond O ولو مش
+
+196
+00:17:38,270 --> 00:17:45,930
+واضحين الروابط فببساطة تفاعل مع الأوزون و بعده
+
+197
+00:17:45,930 --> 00:17:51,830
+زنكمية هو حقيقة بيحول لل carbon carbon double bond
+
+198
+00:17:51,830 --> 00:17:57,800
+لتنتين C double bond O يعني بديكوا تتخيلوابهذا
+
+199
+00:17:57,800 --> 00:18:02,640
+الشكل كان عندكم carbons بغض النظر إيش موجود عندي
+
+200
+00:18:02,640 --> 00:18:08,460
+هنا ممكن اتش اتش اتش مثل فلل إيش مكان يكون بتخلوه
+
+201
+00:18:08,460 --> 00:18:12,400
+زي ما هو مش موضوعكم افترضوا قلنالكوا بدنا ناتج ال
+
+202
+00:18:12,400 --> 00:18:16,860
+ozonolesis لهذا التفاعل إيش أسهل طريقة عشان تنفذوا
+
+203
+00:18:16,860 --> 00:18:24,160
+الجواب تتخيلوا أنه كسرنا هذه الرابطة واضح؟ و هنا
+
+204
+00:18:24,160 --> 00:18:28,590
+حطينا O و هناأو نتيجة
+
+205
+00:18:31,420 --> 00:18:37,520
+هك انا بعمل ناتج ال ozoneolysis الان انه اكون عندى
+
+206
+00:18:37,520 --> 00:18:41,560
+اى مجموعة هنا مابفرقش عندى لكن بكل الاحوال لو
+
+207
+00:18:41,560 --> 00:18:45,920
+افترضت عندى carbon و carbon هيطلع عندى كيتون لو
+
+208
+00:18:45,920 --> 00:18:49,580
+افترضت عندى carbon و hydrogen او تنتين هيدروجين
+
+209
+00:18:49,580 --> 00:18:54,000
+هيطلع عندى الديهيد اذا هذا تفاعل ال ozoneolysis في
+
+210
+00:18:54,000 --> 00:18:59,340
+النهاية لو بدأ اقولكوا شو احتمالات نواتجهالديهيد
+
+211
+00:18:59,340 --> 00:19:04,280
+او كيتون او
+
+212
+00:19:04,280 --> 00:19:10,200
+كيتون
+
+213
+00:19:10,200 --> 00:19:12,040
+او كيتون او كيتون او كيتون او كيتون او كيتون او
+
+214
+00:19:12,040 --> 00:19:12,140
+او كيتون او كيتون او كيتون او كيتون او كيتون او
+
+215
+00:19:12,140 --> 00:19:12,600
+كيتون او كيتون او كيتون او كيتون او كيتون او كيتون
+
+216
+00:19:12,600 --> 00:19:13,180
+او كيتون او كيتون او كيتون او كيتون او كيتون او
+
+217
+00:19:13,180 --> 00:19:13,220
+كيتون او كيتون او كيتون او كيتون او كيتون او كيتون
+
+218
+00:19:13,220 --> 00:19:15,260
+او كيتون او كيتون او كيتون او كيتون او كيتون او
+
+219
+00:19:15,260 --> 00:19:21,580
+كيتون او كيتون او كيتون او كيتونأيضا الديهايد
+
+220
+00:19:21,580 --> 00:19:25,860
+الديهايد يعرف ب H واحدة و أبسط الديهايد في الدنيا
+
+221
+00:19:25,860 --> 00:19:29,660
+ال form الديهايد اللي فيه H و H تنتيل فوجود H
+
+222
+00:19:29,660 --> 00:19:34,320
+واحدة بيخل المركب إيش اسمه الديهايد الآن التانية
+
+223
+00:19:34,320 --> 00:19:38,120
+تكون H بيكون أبسط الديهايد التانية تكون مثل إثل
+
+224
+00:19:38,120 --> 00:19:43,820
+فنل بروبل أي مجموعة بيظلواالديهيد ايضا فنتج ال
+
+225
+00:19:43,820 --> 00:19:49,580
+اوزونوليسيس بيعطي الديهيد او كيتون باستخدام
+
+226
+00:19:49,580 --> 00:19:55,380
+الاشتراكات على الدبل بوند اعتمادا على الاشتراكات
+
+227
+00:19:55,380 --> 00:19:58,600
+على الدبل بوند الان هي هذا على طول لما واحدة بتطلع
+
+228
+00:19:58,600 --> 00:20:03,500
+هتلاحظ ايش اعطانا هنا الديهيد اكيد لان الدبل بوند
+
+229
+00:20:03,500 --> 00:20:08,910
+عليها اتش وهنا نور على نور الدبل بوند عليهاتنتين H
+
+230
+00:20:08,910 --> 00:20:13,670
+إذا أيضا بالتأكيد الديهايد وإن كان أبسط الديهايد
+
+231
+00:20:13,670 --> 00:20:17,890
+لكن لو أي طرف عليه تنتين كاربون من عند هذا الطرف
+
+232
+00:20:17,890 --> 00:20:25,070
+هيعطيه كيتون هاي أمثلة عندنا تطلع عليها في كل
+
+233
+00:20:25,070 --> 00:20:32,450
+الأحوال من أين ستكسر الرابط من
+
+234
+00:20:32,450 --> 00:20:38,340
+النص الرابط بنكسرها من النصبدون ما نتطلع على
+
+235
+00:20:38,340 --> 00:20:41,860
+الجواب لو إجينا سألنا هذا الناتج بيعطي إيش
+
+236
+00:20:41,860 --> 00:20:46,840
+الديهايد الكربون هذي حملة H at least و هذا
+
+237
+00:20:46,840 --> 00:20:53,920
+الديهايد و الديهايد هنا T ليش المخفي شو هو؟ بديش
+
+238
+00:20:53,920 --> 00:21:01,300
+أبقى أتعب معكم كل ما لم يكتب فهو H طيب إذا من هذه
+
+239
+00:21:01,300 --> 00:21:07,430
+الجهة شو بيعطيه؟ و من هذه الجهةكيتون هذه كل رأس
+
+240
+00:21:07,430 --> 00:21:12,850
+يعتبر carbon الان هذه بنكسرها ايضا من النص بتصير
+
+241
+00:21:12,850 --> 00:21:17,590
+هنا C double bond O وهنا C double bond O اكيد هذه
+
+242
+00:21:17,590 --> 00:21:23,170
+كيتون وهنا فيه H مخفية كيتون
+
+243
+00:21:23,170 --> 00:21:27,250
+والدايت لاحظوا هذا ماعطاش جزي ايه لكن كسر الرابط
+
+244
+00:21:27,250 --> 00:21:34,720
+بنفس المنطق هذا نفس الشي تماما لاحظوا هنا فيهأتش و
+
+245
+00:21:34,720 --> 00:21:38,160
+هنا فيه اتش خلو ادي سيضه بالبندقه و ادي سيضه
+
+246
+00:21:38,160 --> 00:21:42,200
+بالبندقه بس هو بعد هيك بدل ما الجزيئ يكتبوا عامل
+
+247
+00:21:42,200 --> 00:21:51,680
+زي هيك فرضه اعطاه نفس حرام يعني هذا بمش هو احنا
+
+248
+00:21:51,680 --> 00:21:54,940
+ليش بنعلمكوا ان الجزيئات بتتغير زي ما البني ادم
+
+249
+00:21:54,940 --> 00:21:58,340
+بياخد ميت صورة يعني هذا لو كان بدوا يكتبوا
+
+250
+00:21:58,340 --> 00:22:00,420
+بالطريقة اللي انتوا فاهمينها
+
+251
+00:22:03,590 --> 00:22:09,470
+عمل هيك و هيك زي هيك مبين سهل و اين كسرت الرابطة
+
+252
+00:22:09,470 --> 00:22:16,030
+الان بعد هيك انفرض زي ما الجنيل بيكون متكور في بطن
+
+253
+00:22:16,030 --> 00:22:25,570
+امه هذا هو هداك هذا المركب هو هذا المركب اليوم
+
+254
+00:22:25,570 --> 00:22:30,250
+انا باعطي ناتج تفاعل طالما الديهايد او كيتون موطعه
+
+255
+00:22:30,250 --> 00:22:35,750
+شبتر 9عشان أسميهم، مش اليوم، واضح؟ في طريقة
+
+256
+00:22:35,750 --> 00:22:44,970
+لتسميتهم ما سُكِت عنه يُصبر عليه، واضح؟
+
+257
+00:22:44,970 --> 00:22:51,710
+الآن
+
+258
+00:22:51,710 --> 00:22:58,890
+من أمثلة ومن تفاعلاتالالكينز أيضا تفاعل مهم جدا في
+
+259
+00:22:58,890 --> 00:23:02,110
+الحياة التطبيقية العملية وفي الحياة الصناعية
+
+260
+00:23:02,110 --> 00:23:06,190
+بنسميه احنا free radical polymerization of
+
+261
+00:23:06,190 --> 00:23:10,290
+ethylene ايش احنا اللي بنقصده في polymerization
+
+262
+00:23:10,290 --> 00:23:16,030
+بتعرف بيكون عندنا جزء واحد من المادة هذا الجزء
+
+263
+00:23:16,030 --> 00:23:23,180
+الواحد من المادة ممكن نسميه احنا monomerمونومر جزء
+
+264
+00:23:23,180 --> 00:23:29,500
+واحد الان لو عملت اتنين بيصير دايمر اتنين دايمر
+
+265
+00:23:29,500 --> 00:23:37,760
+تلاتة اترايمر اربعة تترامر تلت اربع مية تلت اربع
+
+266
+00:23:37,760 --> 00:23:45,410
+تلاف وقتها بوليمرطب مش من أولها polymer لأ إذا
+
+267
+00:23:45,410 --> 00:23:50,130
+إحنا لو كنا بنقول الجزء الواحد إيش بنقوله؟ monomer
+
+268
+00:23:50,130 --> 00:23:58,750
+اتنين دايمر تلاتة ترايمر أربعة تترامر
+
+269
+00:24:02,660 --> 00:24:08,120
+بوليمر يعني البوليمر بيكون تلت اربعميت جزيء خمسمية
+
+270
+00:24:08,120 --> 00:24:11,960
+احيانا تلت تلاف احيانا حسب طبيعة المواد خمسين الف
+
+271
+00:24:11,960 --> 00:24:15,680
+ميت الف بيكونوا كلهم مار بعض هذا اللي بنسميه
+
+272
+00:24:15,680 --> 00:24:20,420
+بوليمر مش تلاتة واربعة واضح فالواحد والاتنين
+
+273
+00:24:20,420 --> 00:24:24,770
+والتلاتة دول علهم أسماء لكن لما بيكون كبيربصير
+
+274
+00:24:24,770 --> 00:24:30,390
+عنده الـ Polymer الان إذا تخيلتوا ان هذا جزء
+
+275
+00:24:30,390 --> 00:24:36,310
+إيثالين إيثالين والإيثالين غاز و إجينا على هذا
+
+276
+00:24:36,310 --> 00:24:45,400
+الإيثالين و حطناه معبروكسايد تحت ضغط مرتفع جدا جدا
+
+277
+00:24:45,400 --> 00:24:51,160
+جدا الف أتمسفير عشان تخافوا من كلمة الف أتمسفير
+
+278
+00:24:51,160 --> 00:24:56,300
+يعني تقدروا تتخيلوا شوها الضغط الكبير بس تذكروا أن
+
+279
+00:24:56,300 --> 00:25:00,400
+طنجرة الضغط اللي بتطبخوا فيها و اللي بتكون تصفروا
+
+280
+00:25:00,400 --> 00:25:06,620
+و بتخوف الضغط فيها اتنين أتمسفير فقط
+
+281
+00:25:07,930 --> 00:25:12,510
+الضغط فيها دي طنجرة الضغط اتنين atmosphere فانا
+
+282
+00:25:12,510 --> 00:25:16,650
+لما بحكي عن الف atmosphere بيمكنكم تخيلوا الضغط
+
+283
+00:25:16,650 --> 00:25:21,410
+طبعا اكيد هذا التفاعل مابنعملش بجزاز ولا بحديد
+
+284
+00:25:21,410 --> 00:25:25,050
+بسيط بيكون عندكوا اوعية stainless steel الوعاء
+
+285
+00:25:25,050 --> 00:25:28,450
+يمكن عرضه اتنين تلاتة سانت stainless steel ومكابس
+
+286
+00:25:28,450 --> 00:25:34,820
+هيدروليكية هذا شغل صناعةمش شغل مختبر، الآن بيجيبوا
+
+287
+00:25:34,820 --> 00:25:42,310
+الغاز، بنحطه غاز، بنحط عليه ال ..البروكسايتز هذه
+
+288
+00:25:42,310 --> 00:25:46,030
+عند ألف أتمسفير وبنسخن عند مئة درجة مئوية بنضغط
+
+289
+00:25:46,030 --> 00:25:50,210
+الغاز بندخل جزيئات الغاز، لاحظوا غاز، بندخل
+
+290
+00:25:50,210 --> 00:25:55,970
+جزيئاته في بعضها طالما كبر المركب، هيتحول لإيش؟
+
+291
+00:25:55,970 --> 00:26:00,110
+لصلب، مش بزيادة ال molecular weight كنا نتحول من
+
+292
+00:26:00,110 --> 00:26:03,930
+غاز لسائل لصلب، هيتحول ل polymer، هذا ال polymer
+
+293
+00:26:03,930 --> 00:26:08,470
+هو plasticهو نوع من ال plastic اللي احنا بنستعمله
+
+294
+00:26:08,470 --> 00:26:14,410
+بنسميه polyethylene فال ethylene بكل هذه الشروط
+
+295
+00:26:14,410 --> 00:26:18,450
+بيصير CH2 CH2 to the N لحظة لغية ال double bond
+
+296
+00:26:18,450 --> 00:26:23,570
+خلتها single bond لغية ال double bond و خلتها
+
+297
+00:26:23,570 --> 00:26:30,530
+single bond في هذه الحالة صارالإيثالين بولي
+
+298
+00:26:30,530 --> 00:26:34,570
+إيثالين طبعا في ميكانيزم للتفاعل مش كتير بتفرج
+
+299
+00:26:34,570 --> 00:26:38,910
+عنده البولي إيثالين هو البلاستيك الأبيض إذا دخلتوا
+
+300
+00:26:38,910 --> 00:26:42,050
+على المختبرات بتلاحظوا في عندكم جلانات بنعب فيها
+
+301
+00:26:42,050 --> 00:26:46,330
+ميا ديستيلد ووتر wash bottles أشياء كل هذه عبارة
+
+302
+00:26:46,330 --> 00:26:49,490
+عن بولي إيثالين الأوعية اللى بنحط فيها هيدروكسيد
+
+303
+00:26:49,490 --> 00:26:53,050
+الصوديوم بتشوفوا ال .. ال bottle اللى بنكون معبينه
+
+304
+00:26:53,050 --> 00:27:00,100
+محلولا كل هذه عبارة عن إيش بولي إيثالينالان بنفس
+
+305
+00:27:00,100 --> 00:27:03,820
+المنطق، شوفوا كيف العلم بتطور، يعني أول ما بدأنا
+
+306
+00:27:03,820 --> 00:27:07,280
+عملنا Polymer عملنا إيش؟ الـ Ethylene و عملنا له
+
+307
+00:27:07,280 --> 00:27:12,200
+Polymerization إلى Polyethylene طيب هم قالوا لازم
+
+308
+00:27:12,200 --> 00:27:16,400
+هدول الأربعة يكونوا Hydrogen و Hydrogen يعني CH2
+
+309
+00:27:16,400 --> 00:27:22,400
+CH2 لو يا ترى بدلنا واحدة منهمبكلور هنا هنا شيلنا
+
+310
+00:27:22,400 --> 00:27:28,860
+واحدة بالغلط صار CH CH2CL وكان double bond وعملنا
+
+311
+00:27:28,860 --> 00:27:33,800
+منه ال polymer هتصير single bond طب هذا المركب
+
+312
+00:27:33,800 --> 00:27:42,680
+الأصلي CH2 double bond CHCL أخدنا اسمه vinyl
+
+313
+00:27:42,680 --> 00:27:47,480
+chloride هذه مجموعة ال vinylVinyl chloride اللي
+
+314
+00:27:47,480 --> 00:27:51,760
+قال لو اعملت منه بوليمار بنفس المنطق تبع الاثيلين
+
+315
+00:27:51,760 --> 00:27:58,640
+الغط بابل بوند و اكتبه to the end طالما هذا Vinyl
+
+316
+00:27:58,640 --> 00:28:03,960
+chloride Vinyl chloride شو هيصير البوليمار تبعه
+
+317
+00:28:03,960 --> 00:28:08,320
+بولي و Vinyl chloride اتخيلوا لو بدنا نختصر اسم
+
+318
+00:28:08,320 --> 00:28:14,300
+البوليمار تبعه BVC
+
+319
+00:28:15,850 --> 00:28:23,430
+مين ما بعرفش ال PVC؟ كل شناتكم PVC، كل بلاستيك
+
+320
+00:28:23,430 --> 00:28:27,310
+المحووتكم PVC، كل المواسير اللي بتشوفوها اللي
+
+321
+00:28:27,310 --> 00:28:30,810
+بنستعملها لتمديدات الصرف الصحي، المواسير
+
+322
+00:28:30,810 --> 00:28:35,750
+البردجانية والسكنية، لو جربت عليها، مكتوب عليها
+
+323
+00:28:35,750 --> 00:28:36,230
+PVC
+
+324
+00:28:39,480 --> 00:28:43,960
+Polyvinyl chloride اللي بيعملوها أرضيات أحيانا
+
+325
+00:28:43,960 --> 00:28:48,820
+بيغطوا فيها البلاط ممكن تشوفوها أحيانا في صالونات
+
+326
+00:28:48,820 --> 00:28:53,200
+لحلاجة في المستشفى أرضية بلاستيك و بيلزجوها فوق كل
+
+327
+00:28:53,200 --> 00:28:59,900
+بلاط الغرفة هذه PVC فال PVC موجود وبشكل كبير في
+
+328
+00:28:59,900 --> 00:29:05,640
+الحياة التطبيقيةزي وزي البولي إيثالين الآن لاحظوا
+
+329
+00:29:05,640 --> 00:29:09,540
+إذا صارت القصة إن أغير واحدة من الهيدروجين وحطيت
+
+330
+00:29:09,540 --> 00:29:14,960
+كلور لما كانت هيدروجين بولي إيثالين لما كانت كلور
+
+331
+00:29:14,960 --> 00:29:21,020
+PVC أو بولي فينيلي كلورايت طب لو خلناها بنزينة
+
+332
+00:29:22,360 --> 00:29:28,720
+المُركّب الأصلي سيكون CH2 double bond CH حملة
+
+333
+00:29:28,720 --> 00:29:34,920
+بنزينة أو phenyl اسمه styrene اسمه styrene لما
+
+334
+00:29:34,920 --> 00:29:41,130
+أعمل منه polymerإيش بده يصير؟ Polystyrene لما أعمل
+
+335
+00:29:41,130 --> 00:29:45,690
+منه polymer هيصير polystyrene إذا التفاعل مش بس
+
+336
+00:29:45,690 --> 00:29:50,390
+خاص بال إيثيلين لأ اتطور على مواد تانية و كل هذه
+
+337
+00:29:50,390 --> 00:29:54,310
+عبارة عن أنواع من ال plastic موجودة في السوق و
+
+338
+00:29:54,310 --> 00:29:59,950
+بتلباع و بتعامل فيها الناس و أفرجناكوا تطبيقيا وين
+
+339
+00:29:59,950 --> 00:30:02,430
+بتستعمل واضحة هذه الفكرة؟
+
+340
+00:30:05,100 --> 00:30:09,380
+إذا هاي كمان تفاعل تاني لل ال keys يعني كأنها
+
+341
+00:30:09,380 --> 00:30:14,560
+بنصير كتفاعلات أساسية أخدنا الإضافة أخدنا ال
+
+342
+00:30:14,560 --> 00:30:18,340
+cleavage اللي هو ال ozoneolysis و أخدنا ال
+
+343
+00:30:18,340 --> 00:30:24,690
+polymerization أنه بيعمل polymer كبيرطبعا الله
+
+344
+00:30:24,690 --> 00:30:29,510
+يعطيكوا العافية بالنسباله ال Alkenes طب لو انتقلنا
+
+345
+00:30:29,510 --> 00:30:35,130
+لل Alkynes هتلاحظوا أنه بشكل أساسي تفاعلات شبيهة
+
+346
+00:30:35,130 --> 00:30:41,710
+الأساس فيها الإضافة ولكن لاحظوا معي لما أبدأ أحكي
+
+347
+00:30:41,710 --> 00:30:47,590
+عن ال Alkynes ال Alkynes تلت روابط carbon ال
+
+348
+00:30:47,590 --> 00:30:52,230
+triple bond carbon إذا لو بده يبدأ يضيف إيش
+
+349
+00:30:52,230 --> 00:30:56,740
+هيتحول؟لـ carbon double bond carbon وكمان خطوة
+
+350
+00:30:56,740 --> 00:31:02,560
+carbon single bond carbon إذا الإضافة هنا يمكن أن
+
+351
+00:31:02,560 --> 00:31:07,820
+تتم على مراحل يعني ال triple bond تصير double bond
+
+352
+00:31:07,820 --> 00:31:12,020
+تصير single bond مرات حسب شروط التفاعل وهذا اللي
+
+353
+00:31:12,020 --> 00:31:15,820
+بتكون تنتبهوله ممكن نخل التفاعل يجف لهنا بنص
+
+354
+00:31:15,820 --> 00:31:19,700
+الطريق يعني ال triple تصير double و يجف التفاعل
+
+355
+00:31:19,700 --> 00:31:26,830
+مرات بيستمرمرات ما بنقدرش نفصل المركب اللي بالوسط
+
+356
+00:31:26,830 --> 00:31:31,150
+يعني مجرد ما نحط عليه المادة التانية بيصير double
+
+357
+00:31:31,150 --> 00:31:36,450
+bond و بسرعة كبيرة بيظلوا محول لإيش ل single bond
+
+358
+00:31:36,450 --> 00:31:40,070
+بعمل إضافة تانية طبعا هنا كام إضافة بيصير لو قلت
+
+359
+00:31:40,070 --> 00:31:46,750
+من triple ل single bond إضافتين إضافتين يعني لو
+
+360
+00:31:46,750 --> 00:31:53,720
+قعد بضيف HCl مش لغاية double bond شو حطيت؟ Hطب
+
+361
+00:31:53,720 --> 00:31:56,880
+هدولة كيف بدي أضيفهم؟ حسب قاعدة Markov Nikov ولا
+
+362
+00:31:56,880 --> 00:32:00,720
+ضد؟ إذا كانوا مع ال H Plus حسب قاعدة Markov Nikov
+
+363
+00:32:00,720 --> 00:32:06,340
+يعني اتخيلتوا هذه H وهذه CH3 وين هتيجي ال H؟ على
+
+364
+00:32:06,340 --> 00:32:13,940
+الحاملة ال H أكتر وين هتيجي التانية؟ واضح؟ أه بعد
+
+365
+00:32:13,940 --> 00:32:18,780
+هيك لو بدي أضيف كمان مرة سرادة ال K أخدنا كيف بضيف
+
+366
+00:32:18,780 --> 00:32:24,780
+ال K على هذا؟ هتيجي ال H هنا؟و ال CL هنا وجدت كأنه
+
+367
+00:32:24,780 --> 00:32:30,020
+ضفت التنتين هيدروجين على نفس الكربون وهي
+
+368
+00:32:30,020 --> 00:32:36,120
+الهيدروجين الأصلية والتنتين CL على نفس الكربون وهي
+
+369
+00:32:36,120 --> 00:32:42,660
+CH3 خلّينا الطول الأصلية إذا التفاعل هنا تم على
+
+370
+00:32:42,660 --> 00:32:48,600
+مرحلة ولا مرحلتين؟ ع مرحلتين كل مرحلة منهم تمت حسب
+
+371
+00:32:48,600 --> 00:32:54,750
+قاعدة Markov-Nikov لما أضيف HCL في وجودالـ H plus
+
+372
+00:32:54,750 --> 00:33:00,150
+واضح؟ كل مرحلة منهم بتتم حسب قاعدة ماركو بيه
+
+373
+00:33:00,150 --> 00:33:05,190
+خلّينا نشوف هذا الكلام بالتفصيل بعض الإضافات بعض
+
+374
+00:33:05,190 --> 00:33:09,850
+تفاؤلات الإضافة للالكينز لاحظوا هاي أول مثال
+
+375
+00:33:09,850 --> 00:33:18,490
+addition of HX to alkynes هاي عندي كاربون بتحمل H
+
+376
+00:33:18,490 --> 00:33:25,510
+وكاربون بتحمل إيش H وضفت ال HClضعفين كيف هيكون
+
+377
+00:33:25,510 --> 00:33:30,630
+الناتج الأخير انه هضيف مرتين ال H هنا و هنا و
+
+378
+00:33:30,630 --> 00:33:33,590
+مرتين ال CL هنا و هنا هذه الناتج الأخيرة بس
+
+379
+00:33:33,590 --> 00:33:39,030
+بالتأكيد اول ما بيبدأ اضيف الإضافة الأولى إجت هنا
+
+380
+00:33:39,030 --> 00:33:44,270
+H و إجت هنا CL و الإضافة التانية إجت هنا كمان H و
+
+381
+00:33:44,270 --> 00:33:52,640
+هنا كمان CL واضح فمرتين حسب قاعدةماركوف نيكوف
+
+382
+00:33:52,640 --> 00:33:56,380
+اديشن الان
+
+383
+00:33:56,380 --> 00:34:04,360
+لو كنت بدى اضيف لبروم لبروم بضيف Anti addition
+
+384
+00:34:04,360 --> 00:34:11,540
+المرة الأولى هين اضفت PR و PR عكس بعضه اعطانى
+
+385
+00:34:11,540 --> 00:34:18,660
+الالكيل كمان مرة يعني كأنه هى ال PR 2 الأول وهىالـ
+
+386
+00:34:18,660 --> 00:34:23,020
+PR2 التالي كمان مرة حديث من هنا و من هنا صار عندى
+
+387
+00:34:23,020 --> 00:34:27,420
+أربع ذرات إبروم فلاحظوا لو أنا كنت كاتب زيكوا و
+
+388
+00:34:27,420 --> 00:34:34,380
+كاتبلكوا 2PR2 شو ناتج النهاية اللى بدى أكتبه ال
+
+389
+00:34:34,380 --> 00:34:39,700
+كان أو ال كان ال كان ال كان بالإنجليزي ال كان
+
+390
+00:34:39,700 --> 00:34:45,890
+بالعربي ال كان بالإنجليزي ماختلفناهاش كتيرالان من
+
+391
+00:34:45,890 --> 00:34:52,230
+التفاعلات المهمة ايضا تفاعل اضافة الميه بس اضافة
+
+392
+00:34:52,230 --> 00:35:02,070
+الميه شوية في فكرة جديدة لو انا اجيت وضفت الميهH2O
+
+393
+00:35:02,070 --> 00:35:06,210
+في وجود H بلس يعني كأني بقول H3O plus و عادة
+
+394
+00:35:06,210 --> 00:35:14,230
+بنستعمل catalyst الذئبق ايون ذئبق HG2 plus فلما
+
+395
+00:35:14,230 --> 00:35:19,610
+بنعمل هذا الكلام بتضيف الميه حسب قاعدة Markovnikov
+
+396
+00:35:19,610 --> 00:35:24,210
+بمعنى هنا بدأ تيجي ال H وهنا بدأ تيجي ال OH هاي
+
+397
+00:35:24,210 --> 00:35:29,360
+الميه اللي ضفناهاهذه إضافة حسب قاعدة ماركوف نيكوف
+
+398
+00:35:29,360 --> 00:35:33,960
+و لا لأ الآن لاحظوا لو اتطلعت على المركب اللي
+
+399
+00:35:33,960 --> 00:35:39,880
+اتكون عندى هذا مركب يحتوي على مجموعتين وظيفيتين
+
+400
+00:35:39,880 --> 00:35:44,040
+المجموعة الوظيفة الوظيفية الأولى ال ال keen
+
+401
+00:35:45,140 --> 00:35:51,700
+والتانية ال alcohol all فهذا فيه in و فيه all
+
+402
+00:35:51,700 --> 00:35:55,920
+شايفينهم هذه ال double bond مش بتاخد نهاية in و
+
+403
+00:35:55,920 --> 00:36:02,620
+هذه all فهذا المركب بنسميه in all لأنه متكون من
+
+404
+00:36:02,620 --> 00:36:08,420
+هدول الشغلتين in all ال OH متصلة مباشرة جنب ال
+
+405
+00:36:08,420 --> 00:36:13,950
+double bond هذه المركباتللأسف الشديد انه في الوضع
+
+406
+00:36:13,950 --> 00:36:18,530
+الطبيعي في الاليفاتيك كومباونز they are unstable
+
+407
+00:36:18,530 --> 00:36:25,690
+مركبات غير ثابتة بتعمل تحول بتتحول هذه المركبات شو
+
+408
+00:36:25,690 --> 00:36:29,390
+التحول اللي بتعمله بتخلي ال double bond هذي تيجي
+
+409
+00:36:29,390 --> 00:36:33,030
+هنا تصير هذي C double bond O و ال H تنتقل هنا
+
+410
+00:36:33,030 --> 00:36:38,650
+لاحظوا تغيرين اللي بيصير فيها انتقال إلكترونات و
+
+411
+00:36:38,650 --> 00:36:46,940
+انتقالزرات لما نعمل هذا الكلام هذه ال C شو صارت؟ C
+
+412
+00:36:46,940 --> 00:36:54,740
+double bond O و هذه ال CH2 شو صارت؟ CH3 إذا إيش
+
+413
+00:36:54,740 --> 00:37:00,160
+انتقل عنده؟ فقط إلكترونات ولا إلكترونات و ذرات؟
+
+414
+00:37:00,160 --> 00:37:04,040
+إلكترونات و ذرات و الذرة تحديدا ذرة الهيدروجين هذه
+
+415
+00:37:04,040 --> 00:37:09,070
+العمليةاللي بتتم فيها انتقال إلكترونات و ذرات
+
+416
+00:37:09,070 --> 00:37:13,930
+بتختلف عن عملية ال resonance اللي كانت فقط انتقال
+
+417
+00:37:13,930 --> 00:37:20,310
+إلكترونات متذاكرين ال resonance؟ ال resonance لما
+
+418
+00:37:20,310 --> 00:37:26,150
+اتكلمنا عنه و أعطيناه أي سهم ال double headed
+
+419
+00:37:26,150 --> 00:37:29,930
+straight arrow كان ال resonance movement
+
+420
+00:37:33,520 --> 00:37:39,820
+movement of electrons only طب لو صارت ال movement
+
+421
+00:37:39,820 --> 00:37:47,940
+electrons زائد H هذه العملية بسميها Tautomerism
+
+422
+00:37:47,940 --> 00:37:54,620
+تختلف عن ال resonance بسميها Tautomerismالتوتو
+
+423
+00:37:54,620 --> 00:38:00,440
+ميريزم ليست فقط حركة إلكترونات حركة إلكترونات و
+
+424
+00:38:00,440 --> 00:38:04,040
+ذرات و الذرة تحديدا أو غالبا اللي هي ذرة ال إيش
+
+425
+00:38:04,040 --> 00:38:07,960
+الهيدروجين بيصير عندي توتو ميريزم الآن البعض هيقول
+
+426
+00:38:07,960 --> 00:38:13,660
+لي شو سهم التوتو ميريزم بنقول سهم التوتو ميريزم
+
+427
+00:38:13,660 --> 00:38:19,500
+سهم التوتو ميريزم هو سهم الإتزان بهذا الشكلانسى
+
+428
+00:38:19,500 --> 00:38:23,560
+السهم المرسوم هذا هو الشكل السليم سهم التوتوميرزم
+
+429
+00:38:23,560 --> 00:38:28,540
+هو سهم الاتزام اذا احنا بنقدر نقول الان لو كنا
+
+430
+00:38:28,540 --> 00:38:33,320
+بنسألكوا صح و غلط توتوميرزم is an equilibrium
+
+431
+00:38:33,320 --> 00:38:37,720
+reaction صح طالما equilibrium reaction في ال
+
+432
+00:38:37,720 --> 00:38:43,980
+equilibrium reaction ايش بينوجد الشغلتين بنسب
+
+433
+00:38:43,980 --> 00:38:51,040
+معينة الان هذا الشكل اللى اتكون كيتونهذا E0 عشان
+
+434
+00:38:51,040 --> 00:38:56,400
+هيك هذا التوتمريزم يسمونه كيتو E0 التوتمريزم
+
+435
+00:38:56,400 --> 00:39:00,660
+التنقل بين التنين لكن مين اللي ينجد بنسبة أكبر
+
+436
+00:39:00,660 --> 00:39:06,440
+الكيتو يعني لو افترضنا ان هذا كان 99.9% هذا بيكون
+
+437
+00:39:06,440 --> 00:39:13,050
+بس بنسبة 1.10%يعني في هذا التوتوميريزم ال keto
+
+438
+00:39:13,050 --> 00:39:17,090
+-enol توتوميريزم ال predominant عارفين كلمة
+
+439
+00:39:17,090 --> 00:39:23,690
+predominant؟ ال predominant
+
+440
+00:39:23,690 --> 00:39:27,610
+مين فيها؟ بيكون ال ketone ولا ال enol؟ ال ketone
+
+441
+00:39:27,610 --> 00:39:31,330
+هو اللي موجود بنسبة كبيرة و ال enol بيكون بنسبة
+
+442
+00:39:31,330 --> 00:39:35,930
+قليلة طبعا هذا في الaliphatic compoundsلما نيجي
+
+443
+00:39:35,930 --> 00:39:42,610
+نتعلم في ال aromatic compounds هتلاحظوا العكس في
+
+444
+00:39:42,610 --> 00:39:49,570
+ال aromatic اللي بينوجد بنسبة أكبر ال enol وعشان
+
+445
+00:39:49,570 --> 00:39:53,670
+هيك كل كلانة بتقدروا تتذكروا و تشوفوا كيف أصل
+
+446
+00:39:53,670 --> 00:39:59,190
+الإسم لو اطلعتوا على هذا المركب مين تسمينا إياه؟
+
+447
+00:39:59,190 --> 00:40:09,580
+Phenolفينول أنا بدي أسميه زي هيك في إين أول تطلعوا
+
+448
+00:40:09,580 --> 00:40:15,020
+معاه الفي لأنه عندي بنزينة الفنل الفنل البنزينة و
+
+449
+00:40:15,020 --> 00:40:20,880
+إين هي الإين و all هي
+
+450
+00:40:20,880 --> 00:40:25,980
+ال all هذا الشكل الثابت منه و بنقدر نعطيكوا
+
+451
+00:40:25,980 --> 00:40:29,240
+homework ان جولكوا ارسمونا ال ketone تبعه
+
+452
+00:40:42,070 --> 00:40:47,610
+ما هو الشكل الثابت في الاروماتيك كومباوتز الموجودة
+
+453
+00:40:47,610 --> 00:40:52,520
+بالنسبة أعلى؟الـ Enol في الالفاتيك كومباونز اللي
+
+454
+00:40:52,520 --> 00:40:57,200
+موجود بنسبة أعلى الـ Ketone وهذه التوتوماريزم زي
+
+455
+00:40:57,200 --> 00:41:01,320
+ما اتفقنا هي عبارة عن عملية equilibrium فالسهم
+
+456
+00:41:01,320 --> 00:41:08,350
+اللي بيستعمللهاأي سهم؟ الـ straight arrow او two
+
+457
+00:41:08,350 --> 00:41:12,270
+straight arrows with half heads اللي هو السهمين
+
+458
+00:41:12,270 --> 00:41:16,070
+اللي موجودين كل واحد بنصف رأس زي ما انتوا شايفينه
+
+459
+00:41:16,070 --> 00:41:20,610
+هنا واللي اتفقنا ان هذا يستعمل الاتزان وعملية
+
+460
+00:41:20,610 --> 00:41:25,830
+التوتوماريزم هي حقيقة عملية اتزان عملية
+
+461
+00:41:25,830 --> 00:41:29,490
+التوتوماريزم هي حقيقة عملية اتزان
+
+462
+00:41:34,870 --> 00:41:39,810
+التفاعلات أيضا لو كنت أنا بضيف الميه عكس قاعدة
+
+463
+00:41:39,810 --> 00:41:45,070
+Markov Nikov باستعمال ال boron لاحظوا هنا في عندكم
+
+464
+00:41:45,070 --> 00:41:50,310
+H هذا نفس المثال السابق بس في اللحظة الأولى اللي
+
+465
+00:41:50,310 --> 00:41:54,510
+حطيت فيها H و OH طالما بضيف باستعمال ال boron هل
+
+466
+00:41:54,510 --> 00:41:59,110
+هضيف حسب قاعدة Markov Nikov ولا عكسها عكسها بناء
+
+467
+00:41:59,110 --> 00:42:04,860
+على ذلك حطيت ال H على اللي حامله H أقلو ال O H على
+
+468
+00:42:04,860 --> 00:42:08,900
+اللي حامله H هذا إضافة عكس Markovnikov مرة تانية
+
+469
+00:42:08,900 --> 00:42:18,180
+صار عندى in all هذا ال in all بحوله إلى ال keto
+
+470
+00:42:18,180 --> 00:42:23,560
+form بمعنى هذا ال double bond تيجي هنا و ال H
+
+471
+00:42:23,560 --> 00:42:29,500
+تنتقل مكان ما إجت ال double bondكل هذا الكلام
+
+472
+00:42:29,500 --> 00:42:33,320
+طبقوا بإيدكم عشان تتدربوا عليه، إذا نفس
+
+473
+00:42:33,320 --> 00:42:37,380
+التوتوميرزم، لكن في هذه الحالة بدل ما أحصل على
+
+474
+00:42:37,380 --> 00:42:42,560
+كيتون حصلت على الديهايد، في المرة الأولى، ليش حصلت
+
+475
+00:42:42,560 --> 00:42:48,100
+على كيتون؟ لأن ال OH إجت على الكاربون الداخليةفلما
+
+476
+00:42:48,100 --> 00:42:51,380
+صارت C double bond O صفية متصلة بكاربون و بكاربون
+
+477
+00:42:51,380 --> 00:42:55,480
+كيتون في المرة التانية لما أضيف عكس قاعدة
+
+478
+00:42:55,480 --> 00:42:58,800
+Markovnikov و أعمل التوتوميرزم ال OH جت على
+
+479
+00:42:58,800 --> 00:43:04,720
+الكاربون الطرفية ولذلك حصلت على الديهيد اذا انا
+
+480
+00:43:04,720 --> 00:43:10,100
+ممكن احصل من هذا التفاعل على الديهيد او كيتون
+
+481
+00:43:10,100 --> 00:43:13,840
+اعتمادا على الطريقة اللي انا ببدأ فيها اذا ضفت
+
+482
+00:43:13,840 --> 00:43:19,760
+الماء بقاعدة Markovnikovبحصل على كيتون وإذا ضيفت
+
+483
+00:43:19,760 --> 00:43:24,300
+الماء عنتي ماركوفنيكوف بحصل على الديهايد وهذا
+
+484
+00:43:24,300 --> 00:43:27,360
+الكلام لما انتوا تتدربوا و تطبقوا بيدكم هتلاحظوا
+
+485
+00:43:27,360 --> 00:43:32,900
+انه بيطلع بشكل تلقائي النتيجة هذه تطلع معاكم بشكل
+
+486
+00:43:32,900 --> 00:43:42,700
+تلقائي تقريبا الشغلة الأخيرة في هذا الموضوع إضافة
+
+487
+00:43:42,700 --> 00:43:43,680
+الهيدروجين
+
+488
+00:43:45,820 --> 00:43:52,880
+أخرناها كثير إضافة الهيدروجين للـ triple bond لها
+
+489
+00:43:52,880 --> 00:43:57,780
+عدة حالاتإذا ضيفت الهيدروجين في وجود معدن زي
+
+490
+00:43:57,780 --> 00:44:02,380
+البلاديم والكربون أو مثلا ال nickel أو ال platinum
+
+491
+00:44:02,380 --> 00:44:08,060
+أي واحد من هدول بلاديم نيكل platinum عادة معدن
+
+492
+00:44:08,060 --> 00:44:13,680
+البلاديم بيكون مخلوط بكربون بودرة تمام فبتتحول لل
+
+493
+00:44:13,680 --> 00:44:18,820
+triple bond إلى single bond مباشرة بدون مأمورأو
+
+494
+00:44:18,820 --> 00:44:20,940
+بمر في الـ double bond بدون ما أفصل الـ double
+
+495
+00:44:20,940 --> 00:44:26,760
+bond يعني بضيف هيدروجين و كمان هيدروجين فالالكاين
+
+496
+00:44:26,760 --> 00:44:31,760
+إذا فعلنا مع الهيدروجين في وجود متل بيصير الكين
+
+497
+00:44:31,760 --> 00:44:35,340
+يعني لما نيجي نقولكم reaction of alkynes with
+
+498
+00:44:35,340 --> 00:44:40,270
+hydrogen in presence of metals شو بيعطيناالكينز
+
+499
+00:44:40,270 --> 00:44:46,010
+الان طيب لو جيبت الكاين زي هذا وفعلته مع هيدروجين
+
+500
+00:44:46,010 --> 00:44:51,030
+في وجود مادة اسمها لند لارز كتاليست يمكن بالكتابة
+
+501
+00:44:51,030 --> 00:44:55,170
+ناقص حرف ال L لند لارز كتاليست لند لارز كتاليست
+
+502
+00:44:55,170 --> 00:44:57,530
+لند لارز كتاليست لند لارز كتاليست لند لارز كتاليست
+
+503
+00:44:57,530 --> 00:45:02,890
+لند لارز كتاليست بضيف بهذه الحالة الهيدروجين من
+
+504
+00:45:02,890 --> 00:45:10,320
+جهة واحدة وبيعطينيالالكين بيجي في نص الطريق بس إيش
+
+505
+00:45:10,320 --> 00:45:17,260
+نوع إضافة الهيدروجين في وجود الليندلار
+
+506
+00:45:17,260 --> 00:45:18,700
+كاتاليست الهيدروجين الهيدروجين الهيدروجين
+
+507
+00:45:18,700 --> 00:45:20,760
+الهيدروجين الهيدروجين الهيدروجين الهيدروجين
+
+508
+00:45:20,760 --> 00:45:21,100
+الهيدروجين الهيدروجين الهيدروجين الهيدروجين
+
+509
+00:45:21,100 --> 00:45:21,420
+الهيدروجين الهيدروجين الهيدروجين الهيدروجين
+
+510
+00:45:21,420 --> 00:45:21,440
+الهيدروجين الهيدروجين الهيدروجين الهيدروجين
+
+511
+00:45:21,440 --> 00:45:24,080
+الهيدروجين الهيدروجين الهيدروجينسيس كومباوند في
+
+512
+00:45:24,080 --> 00:45:26,840
+حالة تانية ممكن لأ يعني لو كانت هذه قدش و قدش مش
+
+513
+00:45:26,840 --> 00:45:30,900
+هيقد لسيس كومباوند أهم شيء عندنا ان الهيدروجين
+
+514
+00:45:30,900 --> 00:45:36,100
+بيضيف بسين اديشن اذا كانت اضافته في وجود لندلار
+
+515
+00:45:36,100 --> 00:45:39,320
+كتاليست و بيقف عن نص الطريق بيقف في وين؟ عند
+
+516
+00:45:39,320 --> 00:45:44,500
+الألكيد طب يا تورا هل ممكن نضيف الهيدروجين انت
+
+517
+00:45:44,500 --> 00:45:51,300
+اديشن يعني على نفس هذا المركب و نطلعالهيدروجين
+
+518
+00:45:51,300 --> 00:45:55,020
+Anti-addition بمعنى إيصير عندي double bond أخلي
+
+519
+00:45:55,020 --> 00:46:03,960
+البنزنتين على جهتين والهيدروجين على جهتين هذا Anti
+
+520
+00:46:03,960 --> 00:46:09,880
+-addition واضح؟ ممكن لو أعملنا التفاعل في وجود
+
+521
+00:46:09,880 --> 00:46:19,310
+ليثيان مع liquid ammoniaواضح؟ اذا انا بإمكاني اضيف
+
+522
+00:46:19,310 --> 00:46:24,470
+الهيدروجين بطريقة معينة يعملي sin addition و
+
+523
+00:46:24,470 --> 00:46:29,630
+بطريقة تانية يعملي anti addition و ممكن اضيفه على
+
+524
+00:46:29,630 --> 00:46:36,970
+مرتين في وجود الهيدروجين و البلاديم او ال nickel
+
+525
+00:46:36,970 --> 00:46:41,990
+او ال platinum ثانية
+
+526
+00:46:41,990 --> 00:46:46,060
+بس لو سمحتواLindlar's catalyst هو عبارة عن خليط من
+
+527
+00:46:46,060 --> 00:46:49,800
+البلاديم مع الكالسيوم كربونيت مع ليد أسيتيت مع
+
+528
+00:46:49,800 --> 00:46:54,360
+كوينولين بهمنيش نحفظ شكله ماخد اسم، إيش اسمه؟
+
+529
+00:46:54,360 --> 00:46:57,000
+Lindlar's catalyst
+
+530
+00:47:00,060 --> 00:47:04,660
+في عندكم طبعا عدة أمثلة عشان انتوا تدرسوها هي
+
+531
+00:47:04,660 --> 00:47:10,100
+تطبيق مباشر على هذا الموضوع بيظل عندنا للمرة
+
+532
+00:47:10,100 --> 00:47:14,100
+الجاية فقط slide واحدة بنحكيها بدقيقتين في موضوع
+
+533
+00:47:14,100 --> 00:47:17,920
+ال kinds و بننتقل لل chapter الرابع اللي هو
+
+534
+00:47:17,920 --> 00:47:23,020
+chapter ال aromatic compounds يعني فقط ضايل عندنا
+
+535
+00:47:23,020 --> 00:47:26,780
+slide واحدة ان شاء الله المرة القادمة بنشرح
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/QEReWkHS3Uk_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/QEReWkHS3Uk_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..24512ba5f9584e23a80a691d856fcec6280af8bc
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/QEReWkHS3Uk_raw.json
@@ -0,0 +1 @@
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"text": "لأنها polar و like dissolves like الآن المركب اللي فيه مجموعتين OH بنسميه احنا إيثالين جليكول لو بدنا يابل ايو باك بزامتين تين OH بدل all دايول حيصير one two اثان دايول اللي فيه تلاتة OH هو ال glycerin", "tokens": [1211, 33456, 11296, 12367, 4032, 411, 15840, 977, 411, 6024, 48506, 9673, 31747, 3555, 13672, 1829, 8978, 3224, 3714, 7435, 2304, 45367, 2655, 9957, 13931, 44945, 38251, 1829, 3224, 1975, 5016, 8315, 11933, 1829, 12984, 6027, 9957, 10874, 20292, 4117, 12610, 45164, 47525, 8315, 7251, 16758, 1211, 1975, 1829, 2407, 4724, 995, 4117, 4724, 11622, 10943, 2655, 9957, 6055, 9957, 13931, 47525, 1211, 439, 11778, 47302, 12610, 11331, 1829, 9381, 13546, 472, 732, 1975, 12984, 7649, 11778, 47302, 12610, 13672, 1829, 8978, 3224, 6055, 1211, 9307, 3660, 13931, 31439, 2423, 22633, 1776, 259], "avg_logprob": -0.33809840615759507, "compression_ratio": 1.5637254901960784, "no_speech_prob": 0.0, "words": [{"start": 727.56, "end": 728.12, "word": "لأنها", "probability": 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تمت لكن تمت على إيش؟ على ال antioxidant مش على اللحوم وال antioxidant تحول إلى مادة غير ضارة وبالتالي ماصارش تأثير هذه فكرة بالظبط ال antioxidants الآن من المواد اللي بتستعمل antioxidants اللي هي ال phenols", "tokens": [5172, 3224, 1211, 35186, 6055, 2288, 7578, 6225, 42213, 10632, 2423, 20118, 64, 11778, 3224, 3714, 10859, 1863, 11082, 34268, 49429, 46811, 2655, 22807, 46811, 2655, 44381, 46811, 2655, 15844, 11933, 1829, 8592, 22807, 15844, 2423, 33369, 394, 37893, 15844, 13672, 5016, 20498, 16070, 33369, 394, 6055, 5016, 12610, 30731, 3714, 18513, 3660, 32771, 13546, 48812, 9640, 3660, 46599, 6027, 2655, 6027, 1829, 19446, 9381, 9640, 8592, 6055, 10721, 12984, 13546, 29538, 6156, 4117, 25720, 20666, 19913, 3555, 9566, 2423, 48767, 6024, 48506, 9154, 9673, 14407, 3215, 13672, 1829, 39894, 14851, 25957, 1211, 48767, 13672, 1829, 39896, 2423, 7279, 19385], "avg_logprob": -0.20157796616601473, "compression_ratio": 1.7882882882882882, "no_speech_prob": 0.0, "words": [{"start": 1270.13, 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search مثلا اكتبوا antioxidant بتلاقوه بيكمل الكوفينول و آلاف الأبحاث و المواد بعضها طبيعي و بعضها صناعي يعني مثلا هذا vitamin E لاحظوا فيه هنا مجموعة الفينول ولا لأ", "tokens": [40228, 22653, 45164, 39894, 30544, 6055, 49628, 12984, 14407, 8978, 20742, 3164, 50113, 15040, 1975, 4117, 2655, 3555, 14407, 33369, 394, 39894, 15040, 4587, 2407, 3224, 4724, 1829, 24793, 1211, 33251, 38688, 9957, 12610, 4032, 19753, 15040, 5172, 16247, 49628, 5718, 104, 4032, 9673, 14407, 3215, 45030, 11242, 11296, 23032, 21292, 3615, 1829, 4032, 45030, 11242, 11296, 20328, 8315, 3615, 1829, 37495, 22653, 50113, 15040, 23758, 17163, 462, 20193, 5016, 19913, 14407, 8978, 3224, 34105, 3714, 7435, 2304, 2407, 27884, 27188, 9957, 12610, 49429, 5296, 10721], "avg_logprob": -0.17708333675888763, "compression_ratio": 1.6515151515151516, "no_speech_prob": 0.0, "words": [{"start": 1295.07, "end": 1295.35, "word": "يعني", "probability": 0.681884765625}, {"start": 1295.35, "end": 1295.59, "word": " لو", "probability": 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{"start": 1384.97, "end": 1385.13, "word": " من", "probability": 0.9658203125}, {"start": 1385.13, "end": 1385.37, "word": " كام", "probability": 0.948974609375}, {"start": 1385.37, "end": 1385.67, "word": " قطعة", "probability": 0.9098307291666666}, {"start": 1385.67, "end": 1386.25, "word": " مكوّن", "probability": 0.7873046875}, {"start": 1386.25, "end": 1387.39, "word": " بيوتل", "probability": 0.716796875}, {"start": 1387.39, "end": 1387.51, "word": " و", "probability": 0.779296875}, {"start": 1387.51, "end": 1387.97, "word": " هيدروكسي", "probability": 0.8818359375}, {"start": 1387.97, "end": 1388.05, "word": " و", "probability": 0.9775390625}, {"start": 1388.05, "end": 1388.43, "word": " أنيزول", "probability": 0.93310546875}, {"start": 1388.43, "end": 1388.89, "word": " هاي", "probability": 0.6318359375}, {"start": 1388.89, "end": 1388.99, "word": " ال", "probability": 0.97119140625}, {"start": 1388.99, "end": 1389.53, "word": " butyl", "probability": 0.805419921875}, {"start": 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new file mode 100644
index 0000000000000000000000000000000000000000..35d1952504d76508b27c9af3437cc98bdbdbcfd4
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@@ -0,0 +1 @@
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{"start": 100.22, "end": 101.24, "word": " هيصير", "probability": 0.8878580729166666}, {"start": 101.24, "end": 101.84, "word": " amine", "probability": 0.6943359375}], "temperature": 1.0}, {"id": 5, "seek": 12881, "start": 102.09, "end": 128.81, "text": "ان اتش تو مثلا او ان اتش ار هيصير امين وهذا بيطلع على شكل حامض فزي ما بتلاحظوا انه دائما في عندى جزء معين بيطلع على شكل حامض وهذا الجزء اللى هجم عليه النيكليوفايل من الميه لنيكليوفايل OH من الكحول لنيكليوفايل OR من الأمونيا لنيكليوفايل NH2 وبالتالي ممكن ارجع", "tokens": [7649, 1975, 2655, 8592, 33427, 50113, 15040, 1975, 2407, 16472, 1975, 2655, 8592, 1975, 2288, 8032, 1829, 9381, 13546, 1975, 2304, 9957, 37037, 15730, 4724, 1829, 9566, 1211, 3615, 15844, 13412, 28820, 11331, 10943, 11242, 6156, 11622, 1829, 19446, 39894, 15040, 5016, 19913, 14407, 16472, 3224, 11778, 16373, 15042, 8978, 43242, 7578, 10874, 11622, 38207, 20449, 9957, 4724, 1829, 9566, 1211, 3615, 15844, 13412, 28820, 11331, 10943, 11242, 37037, 15730, 25724, 11622, 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"end": 140.85, "word": " الأسبيرين", "probability": 0.73468017578125}, {"start": 140.85, "end": 141.83, "word": " واضح؟", "probability": 0.86767578125}, {"start": 141.83, "end": 142.05, "word": " كيف", "probability": 0.837890625}, {"start": 142.05, "end": 142.49, "word": " نحضر", "probability": 0.996826171875}, {"start": 142.49, "end": 143.45, "word": " الأسبيرين", "probability": 0.986572265625}, {"start": 143.45, "end": 144.65, "word": " ربما", "probability": 0.955078125}, {"start": 144.65, "end": 145.21, "word": " سبق", "probability": 0.9903971354166666}, {"start": 145.21, "end": 145.49, "word": " مار", "probability": 0.7294921875}, {"start": 145.49, "end": 145.89, "word": " معنا", "probability": 0.8955078125}, {"start": 145.89, "end": 146.49, "word": " ان", "probability": 0.25048828125}, {"start": 146.49, "end": 146.79, "word": " احنا", "probability": 0.88671875}, {"start": 146.79, "end": 147.47, "word": " بننطلق", "probability": 0.87294921875}, {"start": 147.47, "end": 147.69, "word": " من", "probability": 0.99560546875}, {"start": 147.69, "end": 147.85, "word": " ال", "probability": 0.84326171875}, {"start": 147.85, "end": 148.63, "word": " salicylic", "probability": 0.9108072916666666}, {"start": 148.63, "end": 149.01, "word": " acid", "probability": 0.9609375}], "temperature": 1.0}, {"id": 7, "seek": 17501, "start": 149.75, "end": 175.01, "text": "الساليسليك أسد اللى هو الحامض ال بنزويك أسد اللى على موقع ألفا منه OH فهو على موقع أورثو منه OH فهو أورثو هيدروكسي بنزويك أسد واسمه ساليسليك أسد وزي ما اتفقنا لازم تكونوا عارفينه سواء قولنا أورثو هيدروكسي بنزويك أسد", "tokens": [6027, 3794, 6027, 1829, 3794, 20292, 4117, 5551, 3794, 3215, 13672, 7578, 31439, 21542, 10943, 11242, 2423, 44945, 11622, 45865, 4117, 5551, 3794, 3215, 13672, 7578, 15844, 3714, 30543, 3615, 5551, 46538, 995, 9154, 3224, 13931, 6156, 3224, 2407, 15844, 3714, 30543, 3615, 34051, 2288, 12984, 2407, 9154, 3224, 13931, 6156, 3224, 2407, 34051, 2288, 12984, 2407, 8032, 25708, 32887, 4117, 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" ما", "probability": 0.96044921875}, {"start": 166.53, "end": 166.97, "word": " اتفقنا", "probability": 0.97666015625}, {"start": 166.97, "end": 167.27, "word": " لازم", "probability": 0.91357421875}, {"start": 167.27, "end": 167.61, "word": " تكونوا", "probability": 0.9763997395833334}, {"start": 167.61, "end": 168.39, "word": " عارفينه", "probability": 0.98798828125}, {"start": 168.39, "end": 168.75, "word": " سواء", "probability": 0.9796549479166666}, {"start": 168.75, "end": 169.15, "word": " قولنا", "probability": 0.8655598958333334}, {"start": 169.15, "end": 170.97, "word": " أورثو", "probability": 0.9544677734375}, {"start": 170.97, "end": 172.59, "word": " هيدروكسي", "probability": 0.96142578125}, {"start": 172.59, "end": 174.51, "word": " بنزويك", "probability": 0.9788818359375}, {"start": 174.51, "end": 175.01, "word": " أسد", "probability": 0.98681640625}], "temperature": 1.0}, {"id": 8, "seek": 20020, "start": 176.36, "end": 200.2, "text": "هذا ال name ايوبك الان لو بدكم ال common name تبعه ايش salicylic acid الان هذا فيه OH اللي هي تعتبر الكهور من ناحية المبدأ هذا ال OH لما اتهاجل على ال acid anhydride عادة بيفعله مع ال acetic anhydride فهتكسر من هنا الحامض", "tokens": [3224, 15730, 2423, 1315, 1975, 1829, 37746, 4117, 2423, 7649, 45164, 47525, 24793, 2423, 2689, 1315, 6055, 3555, 3615, 3224, 1975, 1829, 8592, 1845, 2632, 1050, 8258, 2423, 7649, 23758, 8978, 3224, 13931, 13672, 1829, 39896, 6055, 34268, 26890, 33251, 3224, 13063, 9154, 8717, 39319, 10632, 9673, 44510, 10721, 23758, 2423, 13931, 5296, 15042, 1975, 47395, 26108, 1211, 15844, 2423, 8258, 18931, 6655, 25502, 6225, 18513, 3660, 4724, 33911, 30241, 3224, 20449, 2423, 696, 3532, 18931, 6655, 25502, 6156, 3224, 2655, 4117, 3794, 2288, 9154, 34105, 21542, 10943, 11242], "avg_logprob": -0.2878472199042638, "compression_ratio": 1.642512077294686, "no_speech_prob": 0.0, "words": [{"start": 176.36, "end": 176.82, "word": "هذا", "probability": 0.940673828125}, {"start": 176.82, "end": 177.08, 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0.7555338541666666}, {"start": 509.89, "end": 510.47, "word": " بيصير", "probability": 0.942138671875}, {"start": 510.47, "end": 511.05, "word": " تلت", "probability": 0.794921875}, {"start": 511.05, "end": 511.67, "word": " أنواع", "probability": 0.93798828125}], "temperature": 1.0}, {"id": 23, "seek": 53989, "start": 512.49, "end": 539.89, "text": "والأمد بيصير تعريفه العام C double bond O متصلة بإيش؟ بنيتروجين هالنيتروجين هذه تكون NH2 primary أمد NHR secondary أمد NR2 tertiary أمد واضح هذه الفكرة؟ الآن هذه الفكرة طالما احنا وقفنا عندها هتجيبنا لنقطة كتير مهمة", "tokens": [2407, 6027, 10721, 2304, 3215, 4724, 1829, 9381, 13546, 37279, 16572, 5172, 3224, 18863, 10943, 383, 3834, 6086, 422, 44650, 36520, 3660, 4724, 28814, 1829, 8592, 22807, 44945, 36081, 2288, 29245, 9957, 8032, 6027, 22653, 2655, 2288, 29245, 9957, 29538, 6055, 30544, 31118, 17, 6194, 5551, 2304, 3215, 31118, 49, 11396, 5551, 2304, 3215, 38399, 17, 38726, 29104, 5551, 2304, 3215, 4032, 46958, 5016, 29538, 27188, 4117, 25720, 22807, 6024, 48506, 29538, 27188, 4117, 25720, 23032, 6027, 15042, 1975, 5016, 8315, 4032, 4587, 5172, 8315, 43242, 11296, 8032, 2655, 7435, 1829, 3555, 8315, 5296, 1863, 47432, 3660, 9122, 2655, 13546, 3714, 16095, 3660], "avg_logprob": -0.24338941992475435, "compression_ratio": 1.5936073059360731, "no_speech_prob": 0.0, "words": [{"start": 512.49, "end": 513.19, "word": "والأمد", "probability": 0.719677734375}, {"start": 513.19, "end": 513.91, "word": " بيصير", "probability": 0.8560791015625}, {"start": 513.91, "end": 514.53, "word": " تعريفه", "probability": 0.9832763671875}, {"start": 514.53, "end": 515.03, "word": " العام", "probability": 0.88427734375}, {"start": 515.03, "end": 515.75, "word": " C", "probability": 0.5615234375}, {"start": 515.75, "end": 516.15, "word": " double", "probability": 0.2489013671875}, {"start": 516.15, "end": 516.63, "word": " bond", "probability": 0.9267578125}, {"start": 516.63, "end": 517.17, "word": " O", "probability": 0.81787109375}, {"start": 517.17, "end": 518.09, "word": " متصلة", "probability": 0.5978190104166666}, {"start": 518.09, "end": 518.69, "word": " بإيش؟", "probability": 0.75068359375}, {"start": 518.69, "end": 520.17, "word": " بنيتروجين", "probability": 0.7569580078125}, {"start": 520.17, "end": 521.19, "word": " هالنيتروجين", "probability": 0.7462855747767857}, {"start": 521.19, "end": 521.47, "word": " هذه", "probability": 0.368408203125}, {"start": 521.47, "end": 522.19, "word": " تكون", "probability": 0.871826171875}, {"start": 522.19, "end": 523.11, "word": " NH2", "probability": 0.77001953125}, {"start": 523.11, "end": 524.53, "word": " primary", "probability": 0.6767578125}, {"start": 524.53, "end": 524.93, "word": " أمد", "probability": 0.8046061197916666}, {"start": 524.93, "end": 526.13, "word": " NHR", "probability": 0.716064453125}, {"start": 526.13, "end": 527.35, "word": " secondary", "probability": 0.179931640625}, {"start": 527.35, "end": 527.69, "word": " أمد", "probability": 0.9137369791666666}, {"start": 527.69, "end": 528.87, "word": " NR2", "probability": 0.6392822265625}, {"start": 528.87, "end": 530.03, "word": " tertiary", "probability": 0.948974609375}, {"start": 530.03, "end": 530.65, "word": " أمد", "probability": 0.9404296875}, {"start": 530.65, "end": 530.93, "word": " واضح", "probability": 0.96728515625}, {"start": 530.93, "end": 531.15, "word": " هذه", "probability": 0.296875}, {"start": 531.15, "end": 532.97, "word": " الفكرة؟", "probability": 0.9107666015625}, {"start": 532.97, "end": 533.43, "word": " الآن", "probability": 0.7626953125}, {"start": 533.43, "end": 534.11, "word": " هذه", "probability": 0.87890625}, {"start": 534.11, "end": 534.63, "word": " الفكرة", "probability": 0.9954427083333334}, {"start": 534.63, "end": 535.13, "word": " طالما", "probability": 0.9840494791666666}, {"start": 535.13, "end": 535.63, "word": " احنا", "probability": 0.83642578125}, {"start": 535.63, "end": 536.07, "word": " وقفنا", "probability": 0.95703125}, {"start": 536.07, "end": 536.71, "word": " عندها", "probability": 0.9970703125}, {"start": 536.71, "end": 538.41, "word": " هتجيبنا", "probability": 0.9032389322916666}, {"start": 538.41, "end": 538.97, "word": " لنقطة", "probability": 0.961181640625}, {"start": 538.97, "end": 539.29, "word": " كتير", "probability": 0.9381510416666666}, {"start": 539.29, "end": 539.89, "word": " مهمة", "probability": 0.9951171875}], "temperature": 1.0}, {"id": 24, "seek": 56779, "start": 541.11, "end": 567.79, "text": "العمل ممكن يعمل hydrogen bonding وممكن مايعملش وممكن يعمل بشكل كبير وممكن يعمل بشكل اقل عارفين انتوا ال hydrogen bonding بيصير لما يكون عندى hydrogen متطابط يا بنيتروجين يا باكسوجين يا بفلورين الان لو اجيت على المركب اللى هو ال primary amine فيه MH", "tokens": [6027, 25957, 1211, 3714, 43020, 7251, 25957, 1211, 12697, 28824, 4032, 2304, 43020, 19446, 1829, 25957, 1211, 8592, 4032, 2304, 43020, 7251, 25957, 1211, 4724, 8592, 28820, 9122, 3555, 13546, 4032, 2304, 43020, 7251, 25957, 1211, 4724, 8592, 28820, 1975, 4587, 1211, 6225, 9640, 5172, 9957, 16472, 2655, 14407, 2423, 12697, 28824, 4724, 1829, 9381, 13546, 5296, 15042, 7251, 30544, 43242, 7578, 12697, 44650, 9566, 16758, 9566, 35186, 44945, 36081, 2288, 29245, 9957, 35186, 4724, 995, 4117, 3794, 29245, 9957, 35186, 4724, 5172, 1211, 13063, 9957, 2423, 7649, 45164, 1975, 7435, 36081, 15844, 9673, 31747, 3555, 13672, 7578, 31439, 2423, 6194, 669, 533, 8978, 3224, 34796], "avg_logprob": -0.2521904350441193, "compression_ratio": 1.9371980676328502, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 541.11, "end": 542.11, "word": "العمل", "probability": 0.6084798177083334}, {"start": 542.11, "end": 543.11, "word": " ممكن", "probability": 0.7283935546875}, {"start": 543.11, "end": 543.81, "word": " يعمل", "probability": 0.9749348958333334}, {"start": 543.81, "end": 544.89, "word": " hydrogen", "probability": 0.12384033203125}, {"start": 544.89, "end": 545.55, "word": " bonding", "probability": 0.92431640625}, {"start": 545.55, "end": 546.69, "word": " وممكن", "probability": 0.7965494791666666}, {"start": 546.69, "end": 548.87, "word": " مايعملش", "probability": 0.723828125}, {"start": 548.87, "end": 549.25, "word": " وممكن", "probability": 0.7495930989583334}, {"start": 549.25, "end": 549.59, "word": " يعمل", "probability": 0.9523111979166666}, {"start": 549.59, "end": 550.01, "word": " بشكل", "probability": 0.98046875}, {"start": 550.01, "end": 550.51, "word": " كبير", "probability": 0.9921875}, {"start": 550.51, "end": 551.21, "word": " وممكن", "probability": 0.93798828125}, {"start": 551.21, "end": 551.53, "word": " يعمل", "probability": 0.9724934895833334}, {"start": 551.53, "end": 551.93, "word": " بشكل", "probability": 0.9856770833333334}, {"start": 551.93, "end": 552.27, "word": " اقل", "probability": 0.7964680989583334}, {"start": 552.27, "end": 552.73, "word": " عارفين", "probability": 0.913330078125}, {"start": 552.73, "end": 552.97, "word": " انتوا", "probability": 0.7685546875}, {"start": 552.97, "end": 553.05, "word": " ال", "probability": 0.873046875}, {"start": 553.05, "end": 553.41, "word": " hydrogen", "probability": 0.74951171875}, {"start": 553.41, "end": 553.83, "word": " bonding", "probability": 0.95263671875}, {"start": 553.83, "end": 554.43, "word": " بيصير", "probability": 0.9171142578125}, {"start": 554.43, "end": 554.95, "word": " لما", "probability": 0.935302734375}, {"start": 554.95, "end": 555.19, "word": " يكون", "probability": 0.98046875}, {"start": 555.19, "end": 555.47, "word": " عندى", "probability": 0.823486328125}, {"start": 555.47, "end": 555.99, "word": " hydrogen", "probability": 0.6396484375}, {"start": 555.99, "end": 556.85, "word": " متطابط", "probability": 0.65985107421875}, {"start": 556.85, "end": 557.59, "word": " يا", "probability": 0.50341796875}, {"start": 557.59, "end": 558.37, "word": " بنيتروجين", "probability": 0.74775390625}, {"start": 558.37, "end": 558.55, "word": " يا", "probability": 0.80126953125}, {"start": 558.55, "end": 559.17, "word": " باكسوجين", "probability": 0.7635091145833334}, {"start": 559.17, "end": 559.45, "word": " يا", "probability": 0.9091796875}, {"start": 559.45, "end": 560.13, "word": " بفلورين", "probability": 0.96943359375}, {"start": 560.13, "end": 561.05, "word": " الان", "probability": 0.69775390625}, {"start": 561.05, "end": 561.49, "word": " لو", "probability": 0.9814453125}, {"start": 561.49, "end": 561.99, "word": " اجيت", "probability": 0.8299153645833334}, {"start": 561.99, "end": 562.37, "word": " على", "probability": 0.81494140625}, {"start": 562.37, "end": 563.73, "word": " المركب", "probability": 0.9254557291666666}, {"start": 563.73, "end": 563.87, "word": " اللى", "probability": 0.862548828125}, {"start": 563.87, "end": 564.05, "word": " هو", "probability": 0.89404296875}, {"start": 564.05, "end": 564.23, "word": " ال", "probability": 0.9453125}, {"start": 564.23, "end": 564.97, "word": " primary", "probability": 0.90234375}, {"start": 564.97, "end": 565.57, "word": " amine", "probability": 0.4388427734375}, {"start": 565.57, "end": 567.41, "word": " فيه", "probability": 0.649658203125}, {"start": 567.41, "end": 567.79, "word": " MH", "probability": 0.417236328125}], "temperature": 1.0}, {"id": 25, "seek": 59349, "start": 569.61, "end": 593.49, "text": "و تنتين مش واحدة تمام اذا ال primary amide ممكن يعمل hydrogen bonding ولا لأ و ممكن يعمل كام hydrogen bonding طالما فيه تنتين hydrogen ممكن يعمل two hydrogen bonding الان لو اجيت على ال secondary amide في كام هيدروجينة", "tokens": [2407, 6055, 29399, 9957, 37893, 36764, 24401, 3660, 46811, 10943, 1975, 15730, 2423, 6194, 669, 482, 3714, 43020, 7251, 25957, 1211, 12697, 28824, 49429, 5296, 10721, 4032, 3714, 43020, 7251, 25957, 1211, 9122, 10943, 12697, 28824, 23032, 6027, 15042, 8978, 3224, 6055, 29399, 9957, 12697, 3714, 43020, 7251, 25957, 1211, 732, 12697, 28824, 2423, 7649, 45164, 1975, 7435, 36081, 15844, 2423, 11396, 669, 482, 8978, 9122, 10943, 8032, 25708, 2288, 29245, 9957, 3660], "avg_logprob": -0.21072635598279335, "compression_ratio": 1.7796610169491525, "no_speech_prob": 0.0, "words": [{"start": 569.61, "end": 569.97, "word": "و", "probability": 0.53369140625}, {"start": 569.97, "end": 570.73, "word": " تنتين", "probability": 0.706787109375}, {"start": 570.73, "end": 570.95, "word": " مش", "probability": 0.55615234375}, {"start": 570.95, "end": 571.51, "word": " واحدة", "probability": 0.9397786458333334}, {"start": 571.51, "end": 572.41, "word": " تمام", "probability": 0.6875}, {"start": 572.41, "end": 573.15, "word": " اذا", "probability": 0.59442138671875}, {"start": 573.15, "end": 573.63, "word": " ال", "probability": 0.9345703125}, {"start": 573.63, "end": 574.27, "word": " primary", "probability": 0.82470703125}, {"start": 574.27, "end": 574.69, "word": " amide", "probability": 0.681640625}, {"start": 574.69, "end": 575.15, "word": " ممكن", "probability": 0.97216796875}, {"start": 575.15, "end": 575.77, "word": " يعمل", "probability": 0.9724934895833334}, {"start": 575.77, "end": 576.35, "word": " hydrogen", "probability": 0.84423828125}, {"start": 576.35, "end": 576.89, "word": " bonding", "probability": 0.95849609375}, {"start": 576.89, "end": 577.15, "word": " ولا", "probability": 0.7177734375}, {"start": 577.15, "end": 577.59, "word": " لأ", "probability": 0.84033203125}, {"start": 577.59, "end": 578.35, "word": " و", "probability": 0.43798828125}, {"start": 578.35, "end": 578.69, "word": " ممكن", "probability": 0.827392578125}, {"start": 578.69, "end": 579.07, "word": " يعمل", "probability": 0.9903971354166666}, {"start": 579.07, "end": 579.35, "word": " كام", "probability": 0.825927734375}, {"start": 579.35, "end": 579.87, "word": " hydrogen", "probability": 0.896484375}, {"start": 579.87, "end": 580.43, "word": " bonding", "probability": 0.96630859375}, {"start": 580.43, "end": 581.43, "word": " طالما", "probability": 0.96533203125}, {"start": 581.43, "end": 581.71, "word": " فيه", "probability": 0.6116943359375}, {"start": 581.71, "end": 582.11, "word": " تنتين", "probability": 0.98779296875}, {"start": 582.11, "end": 582.63, "word": " hydrogen", "probability": 0.6708984375}, {"start": 582.63, "end": 583.47, "word": " ممكن", "probability": 0.940185546875}, {"start": 583.47, "end": 583.85, "word": " يعمل", "probability": 0.9930013020833334}, {"start": 583.85, "end": 584.09, "word": " two", "probability": 0.8525390625}, {"start": 584.09, "end": 584.73, "word": " hydrogen", "probability": 0.94970703125}, {"start": 584.73, "end": 585.37, "word": " bonding", "probability": 0.96435546875}, {"start": 585.37, "end": 587.73, "word": " الان", "probability": 0.6328125}, {"start": 587.73, "end": 588.17, "word": " لو", "probability": 0.97705078125}, {"start": 588.17, "end": 588.59, "word": " اجيت", "probability": 0.8439127604166666}, {"start": 588.59, "end": 588.93, "word": " على", "probability": 0.8408203125}, {"start": 588.93, "end": 589.31, "word": " ال", "probability": 0.7880859375}, {"start": 589.31, "end": 589.95, "word": " secondary", "probability": 0.90185546875}, {"start": 589.95, "end": 590.65, "word": " amide", "probability": 0.935546875}, {"start": 590.65, "end": 592.23, "word": " في", "probability": 0.78466796875}, {"start": 592.23, "end": 592.55, "word": " كام", "probability": 0.938720703125}, {"start": 592.55, "end": 593.49, "word": " هيدروجينة", "probability": 0.8828125}], "temperature": 1.0}, {"id": 26, "seek": 61791, "start": 594.27, "end": 617.91, "text": "وحدة إذا ممكن يعمل one hydrogen bonding لو إجيت على ال tertiary amide مش فيه hydrogen إذا بيعملش hydrogen bonding واضحة الفكرة إذا لو أنا بدي أجي أشوف ال amides من ناحية ال hydrogen bonding مين أكثر واحد بيعمل hydrogen bonding بعده", "tokens": [2407, 24401, 3660, 11933, 15730, 3714, 43020, 7251, 25957, 1211, 472, 12697, 28824, 45164, 11933, 7435, 36081, 15844, 2423, 38726, 29104, 669, 482, 37893, 8978, 3224, 12697, 11933, 15730, 4724, 1829, 25957, 1211, 8592, 12697, 28824, 4032, 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خاصية على ال boiling point بناء على ذلك لما انا بدي اجي احكي عن ال boiling point مين هيكون اعلى boiling point ال primary اعلى من ال secondary اعلى من ال tertiary", "tokens": [3555, 22488, 3224, 38726, 29104, 6225, 23032, 12610, 3714, 3555, 33599, 25720, 2423, 12697, 28824, 44945, 3615, 4117, 3794, 15844, 36632, 16490, 33546, 10632, 15844, 2423, 16208, 935, 44945, 16606, 15844, 29910, 23275, 5296, 15042, 1975, 8315, 4724, 16254, 1975, 7435, 1829, 1975, 5016, 4117, 1829, 18871, 2423, 16208, 935, 3714, 9957, 39896, 30544, 1975, 3615, 23942, 16208, 935, 2423, 6194, 1975, 3615, 23942, 9154, 2423, 11396, 1975, 3615, 23942, 9154, 2423, 38726, 29104], "avg_logprob": -0.170625003973643, "compression_ratio": 1.7135135135135136, "no_speech_prob": 9.5367431640625e-07, "words": [{"start": 618.45, "end": 619.65, "word": "بعده", "probability": 0.7799479166666666}, {"start": 619.65, "end": 621.03, "word": " tertiary", "probability": 0.6678466796875}, {"start": 621.03, "end": 621.51, "word": " ع", 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احنا قلنا تقريبا تلت اسابيع اربعة بس بندرس ال Carbonyl groups ال C double bond O في ال aldehydes في ال ketones في ال acids في ال E stars very reactive واضح؟", "tokens": [2407, 2741, 65, 2526, 75, 383, 3834, 6086, 422, 2423, 7649, 20193, 5016, 19913, 14407, 20449, 995, 25528, 28242, 36764, 24401, 3660, 9154, 16095, 9154, 5172, 2288, 41891, 588, 28897, 37495, 22653, 2423, 2741, 65, 2526, 75, 1594, 45164, 24401, 11296, 588, 28897, 4032, 1975, 5016, 8315, 12174, 1211, 8315, 6055, 4587, 16572, 3555, 995, 6055, 1211, 2655, 24525, 16758, 40228, 1975, 25513, 27884, 4724, 3794, 44945, 3215, 2288, 3794, 2423, 2741, 65, 2526, 75, 3935, 2423, 383, 3834, 6086, 422, 8978, 2423, 16798, 68, 3495, 14792, 8978, 2423, 14979, 2213, 8978, 2423, 21667, 8978, 2423, 462, 6105, 588, 28897, 4032, 46958, 5016, 22807], "avg_logprob": -0.2385416689373198, "compression_ratio": 1.7880184331797235, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 1154.1, "end": 1154.32, "word": "و", "probability": 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" نيجي", "probability": 0.96435546875}, {"start": 2208.49, "end": 2208.85, "word": " نقول", "probability": 0.992431640625}, {"start": 2208.85, "end": 2209.91, "word": " تحضير", "probability": 0.9290771484375}, {"start": 2209.91, "end": 2210.77, "word": " الأمين", "probability": 0.9576822916666666}], "temperature": 1.0}, {"id": 98, "seek": 223779, "start": 2212.89, "end": 2237.79, "text": "بالـ reduction of amides شبيه بهذا التفاعل عشان تعملوا المقارنة انه كان ال Easter ال R سيضا بالبند OOR بالليثيام ألومنوم هيدرايد بال reduction شو كان يعطيني ال primary alcohol كان يعطيني RCH2OH لاحظوا المعادلتين هدولة", "tokens": [3555, 6027, 39184, 11004, 295, 669, 1875, 13412, 21292, 3224, 39627, 15730, 16712, 5172, 995, 30241, 6225, 8592, 7649, 6055, 25957, 1211, 14407, 9673, 4587, 9640, 1863, 3660, 16472, 3224, 25961, 2423, 9403, 2423, 497, 8608, 1829, 11242, 995, 20666, 3555, 41260, 422, 2483, 20666, 20292, 12984, 1829, 10943, 5551, 1211, 20498, 1863, 20498, 8032, 25708, 23557, 25708, 20666, 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"word": "طبعاً", "probability": 0.84755859375}, {"start": 2519.02, "end": 2519.1, "word": " في", "probability": 0.87060546875}, {"start": 2519.1, "end": 2519.56, "word": " أشياء", "probability": 0.938232421875}, {"start": 2519.56, "end": 2519.96, "word": " تانية", "probability": 0.9910481770833334}, {"start": 2519.96, "end": 2520.7, "word": " فرمونات", "probability": 0.7783203125}, {"start": 2520.7, "end": 2521.16, "word": " بنسميها", "probability": 0.930908203125}, {"start": 2521.16, "end": 2521.44, "word": " برضه", "probability": 0.7591959635416666}, {"start": 2521.44, "end": 2521.82, "word": " أشياء", "probability": 0.9576416015625}, {"start": 2521.82, "end": 2522.48, "word": " تطبيقية", "probability": 0.9779296875}, {"start": 2522.48, "end": 2522.86, "word": " على", "probability": 0.86572265625}, {"start": 2522.86, "end": 2523.52, "word": " ال", "probability": 0.91650390625}, {"start": 2523.52, "end": 2523.68, "word": " e", "probability": 0.2301025390625}, {"start": 2523.68, "end": 2523.98, "word": "-stars", "probability": 0.665771484375}, {"start": 2523.98, "end": 2524.18, "word": " و", "probability": 0.74853515625}, {"start": 2524.18, "end": 2524.26, "word": " ال", "probability": 0.908203125}, {"start": 2524.26, "end": 2524.64, "word": " emits", "probability": 0.37353515625}, {"start": 2524.64, "end": 2525.62, "word": " بهيك", "probability": 0.7246907552083334}, {"start": 2525.62, "end": 2526.72, "word": " بننهي", "probability": 0.935791015625}, {"start": 2526.72, "end": 2527.04, "word": " اليوم", "probability": 0.978271484375}, {"start": 2527.04, "end": 2527.18, "word": " و", "probability": 0.6171875}, {"start": 2527.18, "end": 2527.18, "word": " ان", "probability": 0.634765625}, {"start": 2527.18, "end": 2527.38, "word": " شاء", "probability": 0.98681640625}, {"start": 2527.38, "end": 2527.44, "word": " الله", "probability": 0.94384765625}, {"start": 2527.44, "end": 2527.76, "word": " المرة", "probability": 0.960205078125}, {"start": 2527.76, "end": 2528.22, 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/UZrkW5alTIE_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/UZrkW5alTIE_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d95dd93f77dde0b3faa58bc5545f755e70b8649f
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/UZrkW5alTIE_postprocess.srt
@@ -0,0 +1,1504 @@
+1
+00:00:19,940 --> 00:00:25,100
+بسم الله الرحمن الرحيم اليوم بنبتدأ في الفصل
+
+2
+00:00:25,100 --> 00:00:29,820
+المكمل خلينا نقول للالديهيدس والكيتونز اللي هو ال
+
+3
+00:00:29,820 --> 00:00:33,940
+carboxylic acids and their derivatives طبعا ليش
+
+4
+00:00:33,940 --> 00:00:38,900
+احنا قولنا الفصل المكمل لأن كل هذه المجموعة من
+
+5
+00:00:38,900 --> 00:00:42,240
+المركبات هي ال carbonyl containing compounds
+
+6
+00:00:42,240 --> 00:00:46,980
+المركبات يعني اللي فيها مجموعة السيضة بال bond O
+
+7
+00:00:47,750 --> 00:00:51,810
+صنفنا ال الديهيدز والكيتونز لوحدنا وقلنا هدولة
+
+8
+00:00:51,810 --> 00:00:56,810
+جماعة ال addition او الإضافة الآن بيجي عند
+
+9
+00:00:56,810 --> 00:01:01,330
+الكاربوكسيليك أسدوبنقول عن المراكبات التانية
+
+10
+00:01:01,330 --> 00:01:04,290
+derivatives of carboxylic acids مشتقة من ال
+
+11
+00:01:04,290 --> 00:01:08,770
+carboxylic acids بمعنى تبدل فيها مجموعة ال OH
+
+12
+00:01:08,770 --> 00:01:14,770
+بمجموعة تانية فإذا أبدلت ب OR بيصير Easter إذا
+
+13
+00:01:14,770 --> 00:01:20,190
+أبدلت ب NH2 و لا NHR بيصير Amid إذا أبدلت بCL أو
+
+14
+00:01:20,190 --> 00:01:24,310
+بR بيصير Acid Halide Acid chloride or bromide إذا
+
+15
+00:01:24,310 --> 00:01:27,490
+أبدلت بOC double bond O بيصير Acid anhydride
+
+16
+00:01:27,490 --> 00:01:34,570
+فبنقول إحناCarboxylic Acids and their derivatives
+
+17
+00:01:34,570 --> 00:01:40,630
+و لذلك لو أتينا مثلا سألناكوا السؤال E stars are
+
+18
+00:01:40,630 --> 00:01:45,450
+Carboxylic Acid derivatives صح Acid chlorides are
+
+19
+00:01:45,450 --> 00:01:48,070
+Carboxylic Acid derivatives صح لكن لو مثلا
+
+20
+00:01:48,070 --> 00:01:51,870
+قلنالكوا E stars are Carboxylic Acid derivatives
+
+21
+00:01:51,870 --> 00:01:57,050
+no aldehydes or ketones or alcohol واضح فاللي
+
+22
+00:01:57,050 --> 00:02:04,490
+بنقصده بال derivative كم نوعأربعة أستر أمد أسد
+
+23
+00:02:04,490 --> 00:02:12,370
+كلورايد و أسد أنهايدرايد الأسد
+
+24
+00:02:12,370 --> 00:02:15,950
+أنهايدرايد الأسد أنهايدرايد ماخد الصيغة العامة
+
+25
+00:02:15,950 --> 00:02:18,730
+الاتية R C double bond O
+
+26
+00:02:34,410 --> 00:02:35,810
+وووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووووو
+
+27
+00:02:50,150 --> 00:02:56,550
+طبعا دائما اول ما بنبدأ بنبدأ باش بتسمية العائلات
+
+28
+00:02:56,550 --> 00:03:01,890
+و احنا اتفقنا ان التسمية في النظام ال IUPAC تسمية
+
+29
+00:03:01,890 --> 00:03:07,630
+سهلة اهم فيها معرفة اطول سلسلة و نعرف ايش العائلة
+
+30
+00:03:07,630 --> 00:03:11,410
+بناء على الترتيبات اللي اتعلمناها سابقا الان لما
+
+31
+00:03:11,410 --> 00:03:17,230
+تكون العائلة الأحماض بنحط النهاية oic acid واضح
+
+32
+00:03:17,230 --> 00:03:22,830
+فالنهاية اللي بدنا نضيفها شو هيoic acid يعني لو
+
+33
+00:03:22,830 --> 00:03:29,270
+كان مع carbon واحدة إيش هنقول المركب مثال oic acid
+
+34
+00:03:29,270 --> 00:03:34,930
+carbon 2 إيثانويك أسد بروبانويك أسد بيوتانويك أسد
+
+35
+00:03:34,930 --> 00:03:39,730
+and so on ولذلك هذا المركب مثلا و العاد دائما
+
+36
+00:03:39,730 --> 00:03:43,730
+بيكون من عند ال acid ال acid دائما موجود على نمرة
+
+37
+00:03:43,730 --> 00:03:48,670
+واحد ولذلك مابنكتبش one oic acid لأ بس acid يعني
+
+38
+00:03:48,670 --> 00:03:54,420
+مثلا هذا المركبواحد، اتنين، تلاتة، اربعة، خمسة،
+
+39
+00:03:54,420 --> 00:03:58,900
+ستة دائما الحاجة اللي مكتوبة بين قسيل معناه انه
+
+40
+00:03:58,900 --> 00:04:03,860
+هذه معلجة واضح؟ يعني لما انا اكون هنا كاتب CH بين
+
+41
+00:04:03,860 --> 00:04:10,990
+قسيل CH3 معناه ذلك هذه ال CH3 معلجة هناواضح ايش
+
+42
+00:04:10,990 --> 00:04:14,050
+تفسيرها لما بكتبها بين قوسين بس لإن انا بكتب على
+
+43
+00:04:14,050 --> 00:04:19,410
+السطر بقدرش ا في برنامج الطباعة اطلع خط زي هيك و
+
+44
+00:04:19,410 --> 00:04:24,430
+ارسم زي هيك فبحط بين قوسين و بكتب CH3 فاللي موجودة
+
+45
+00:04:24,430 --> 00:04:27,910
+في داخل السلسلة بين قوسين يعني معلجة على المجموعة
+
+46
+00:04:27,910 --> 00:04:34,350
+اللي قبلها الان هذا المركب اكيد hexanoic acid على
+
+47
+00:04:34,350 --> 00:04:40,340
+نمرة تلاتة ال hexanoic acid شو بيحمل؟مثل فبصير
+
+48
+00:04:40,340 --> 00:04:44,040
+three methyl hexanoic acid
+
+49
+00:04:49,490 --> 00:04:54,850
+زي ما اتفقنا احنا ان الأحماض بالتدريج هتمشي مثانوك
+
+50
+00:04:54,850 --> 00:04:58,770
+ايثانوك بروبانوك بيوتانوك بنتانوك هكسانوك هبتانوك
+
+51
+00:04:58,770 --> 00:05:05,670
+اكتانوك نونا نوك ديكانوك ديكان يعني عشرة الان هذه
+
+52
+00:05:05,670 --> 00:05:10,910
+الأحماض لها أسماء شهرة هذه الأحماض لها أسماء شهرة
+
+53
+00:05:10,910 --> 00:05:15,890
+أقل تقدير نسمع فيها لمرة و نعرف أبسط اتنين او
+
+54
+00:05:15,890 --> 00:05:21,470
+تلاتة منهاالحمض اللي من كاربون واحدة formic acid
+
+55
+00:05:21,470 --> 00:05:27,310
+واضح؟ اللي من تنتين acidic acid اللي في مجموعة ال
+
+56
+00:05:27,310 --> 00:05:32,390
+acid اللي أخدناها تلاتة probionic بنقولش probionic
+
+57
+00:05:32,390 --> 00:05:38,470
+بروبانوك الاربعة بيوتانوك بيوتاريكبيوتاريك أسد
+
+58
+00:05:38,470 --> 00:05:42,390
+بعدين بيجي الخامسة Valeric و بعدين Caproic,
+
+59
+00:05:42,510 --> 00:05:46,950
+Enanthic, Caprylic, Pelargonic, Capric طبعا مش
+
+60
+00:05:46,950 --> 00:05:50,870
+ضرور نحفظها الأسماء لكن أقل تقدير يكون اسمعناها
+
+61
+00:05:50,870 --> 00:05:54,650
+مرة يعني لو في يوم من الأيام لجينا انه اخلط ال
+
+62
+00:05:54,650 --> 00:05:59,070
+Valeric acidنجي نتذكر شو ال valeric acid نفتح
+
+63
+00:05:59,070 --> 00:06:02,830
+الكتاب أو ال net نتذكر أن ال valeric acid هو ال
+
+64
+00:06:02,830 --> 00:06:06,730
+pentanoic acid واضح؟ بس أكيد أقل تقدير لما نقول
+
+65
+00:06:06,730 --> 00:06:11,850
+ethanoic acid هو ال acetic acid, methanoic acid هو
+
+66
+00:06:11,850 --> 00:06:15,630
+ال formic acid اللي أساسا جاي من وين ال formic
+
+67
+00:06:15,630 --> 00:06:20,930
+acid؟ من ال antsاللي هي باللاتيني formica يعني من
+
+68
+00:06:20,930 --> 00:06:25,770
+النمل هو الحمب اللي النملة لما بتجرس بتحطه بالإيد
+
+69
+00:06:25,770 --> 00:06:31,150
+عشان هيك القرص بيكون مؤلم واضح؟ يعني النملة لما
+
+70
+00:06:31,150 --> 00:06:37,170
+بتعمل قرص للبني آدم بتبخ شوية formic acid هذا اللي
+
+71
+00:06:37,170 --> 00:06:43,630
+بيسبب القلم عند الإنسان واضح؟
+
+72
+00:06:45,960 --> 00:06:49,860
+هذه أمثلة إضافية على تسمية ال assets واضح أنه
+
+73
+00:06:49,860 --> 00:06:53,960
+الأساس البحث عن أطول سلسة و الترقيم من عند ال c
+
+74
+00:06:53,960 --> 00:06:57,640
+double bond o يعني نمرة واحد هي إيش ال c double
+
+75
+00:06:57,640 --> 00:07:03,020
+bond o الآن انتبهوا لخطأ شائع بصره الطلاب جد ما
+
+76
+00:07:03,020 --> 00:07:06,420
+بتعد معهم إنهم يخطئوا فيه إنه أول ما يشوفوا c
+
+77
+00:07:06,420 --> 00:07:11,700
+double bond oبياخدوا هذا الجزء و بيقولوا CWO على
+
+78
+00:07:11,700 --> 00:07:16,040
+الطرف إذا هذا الديهايد و الديهايد على نمر واحد
+
+79
+00:07:16,040 --> 00:07:19,600
+حامل مجموعة هيدروكسي فبيجوا يقولون one
+
+80
+00:07:19,600 --> 00:07:26,660
+hydroxybutanol طبعا إذا التقت ال CWO مع ال OH خلاص
+
+81
+00:07:26,660 --> 00:07:33,030
+أصبحت المجموعة الوظيفية هي هذه كاملةو كلها كاملة
+
+82
+00:07:33,030 --> 00:07:37,170
+بتعطي نهاية ايش اوك اسد لما اجي اقول واحد اتنين
+
+83
+00:07:37,170 --> 00:07:40,250
+تلاتة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+84
+00:07:40,250 --> 00:07:46,130
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+85
+00:07:46,130 --> 00:07:51,210
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+86
+00:07:51,210 --> 00:07:52,450
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+87
+00:07:52,450 --> 00:07:53,030
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+88
+00:07:53,030 --> 00:07:53,550
+اربعة اربعة اربعة اربعة اربعة اربعة اربعة اربعة
+
+89
+00:07:53,550 --> 00:07:56,910
+اربعة اربعة اربعة اربعة اربعة اربعة اربEthyl to
+
+90
+00:07:56,910 --> 00:08:02,530
+Ethyl butanoic acid هنا مثلا بالزويك أسد حامل
+
+91
+00:08:02,530 --> 00:08:07,890
+الكلور علىال بارا position أو ال four position مر
+
+92
+00:08:07,890 --> 00:08:12,870
+علينا مثل هذا المركب لحظو هنا عندنا مجموعة وظيفية
+
+93
+00:08:12,870 --> 00:08:18,110
+واحدة اللي هي مجموعة الاش ال acid لكن لو انتقل ال
+
+94
+00:08:18,110 --> 00:08:21,430
+acid مع ال الديهايد او ال كيتون او كذا مين اللي
+
+95
+00:08:21,430 --> 00:08:25,630
+الاولوية ال acid اعلى من ال الديهايد اعلى من ال
+
+96
+00:08:25,630 --> 00:08:31,430
+كيتون اعلى من ال alcohol كل شيء هينسبلهالان لو يا
+
+97
+00:08:31,430 --> 00:08:37,270
+ترى كان عندى اكثر من acid لو كان عندى اكثر من acid
+
+98
+00:08:37,270 --> 00:08:41,790
+ممكن على السلسلة على الطرفين يكون على هذا الطرف
+
+99
+00:08:41,790 --> 00:08:46,230
+مجموعة acid وعلى هذا الطرف مجموعة acid واضح؟ ممكن
+
+100
+00:08:46,230 --> 00:08:52,770
+يكون اكثر من مجموعتين كمان اكيد لو كان عندى تفرعات
+
+101
+00:08:52,770 --> 00:08:57,590
+يعني لو كان عندى مثل هذا مثل هذه السلسلة ممكن
+
+102
+00:08:57,590 --> 00:09:04,870
+احطها لمجموعة acidc double bond o o h ممكن احط هنا
+
+103
+00:09:04,870 --> 00:09:11,170
+مجموعة acid ممكن احط هنا مجموعة acid واضح يعني
+
+104
+00:09:11,170 --> 00:09:16,150
+ممكن مجموعة مجموعتين تلاتة اربعة لو صار عندى
+
+105
+00:09:16,150 --> 00:09:20,550
+تفارعات كله وارد طب الآن لما بيصير عندى اكثر من
+
+106
+00:09:20,550 --> 00:09:26,750
+مجموعة ايش بدي اسمه بدل ما بدي اقول awake لما
+
+107
+00:09:26,750 --> 00:09:35,110
+يصيروا تنتين die awakeDioic acid فهنا لما يكونوا
+
+108
+00:09:35,110 --> 00:09:38,510
+carbon 2 هل ممكن ع carbon واحدة نحط two acids
+
+109
+00:09:38,510 --> 00:09:46,230
+مستحيل فأبسط حامض diacid هو اللي ع carbon 2 بيكون
+
+110
+00:09:46,230 --> 00:09:52,250
+اسمه ethanedioic acid ethanedioic acid هذا ماخد
+
+111
+00:09:52,250 --> 00:09:58,230
+اسم الشهرة oxalic acid لو صاروا تلاتةيعني هي ع
+
+112
+00:09:58,230 --> 00:10:03,710
+الطرف وع الطرف مجموعة حامض بيصير إيش بروبان ديويك
+
+113
+00:10:03,710 --> 00:10:08,690
+أسد ماخد اسم شورا مالونك أسد بعدين بيوتان ديويك
+
+114
+00:10:08,690 --> 00:10:14,940
+أسد ساكسينك بنتان هكسان هبتينDioic acid، glutaric،
+
+115
+00:10:14,940 --> 00:10:19,920
+adibic بملك، أسماء شهراء كثيرة موجودة، أقل تقدير
+
+116
+00:10:19,920 --> 00:10:23,980
+خلّينا نعرف ال aiobacnine، ال aiobacnine بستعمل
+
+117
+00:10:23,980 --> 00:10:30,960
+كلمة إيش؟ Dioic acid، بستعمل كلمة Dioic acid، و
+
+118
+00:10:30,960 --> 00:10:35,470
+أبسط Dioic acid زي ما قولنا إيش؟ال oxalic acid ..
+
+119
+00:10:35,470 --> 00:10:40,250
+ال oxalic acid كويس تعرفوه يعني طالما .. طالما
+
+120
+00:10:40,250 --> 00:10:47,010
+انتوا تحاليل طبية لما تبدأوا تدرسوا في ال urine في
+
+121
+00:10:47,010 --> 00:10:52,530
+ال bowl الأملاح وبعد هيك الأملاح هذه بدأت تعمل
+
+122
+00:10:52,530 --> 00:10:58,110
+حصوات في الكيليةهتلاحظوا ان جزء أساسي ان الحصوات
+
+123
+00:10:58,110 --> 00:11:03,550
+اما بده تكون صلبة جدا من ال oxalic acids او من ال
+
+124
+00:11:03,550 --> 00:11:08,850
+oxalic acid salts او من ال phosphates واضح فلما
+
+125
+00:11:08,850 --> 00:11:14,950
+نيجي نقول حصوات من ال oxalic acids او من ال salts
+
+126
+00:11:14,950 --> 00:11:21,180
+طبعا ال salt هيكون O minusالان هذه ال salts جزء من
+
+127
+00:11:21,180 --> 00:11:24,780
+أبيعمال حصواته و لذلك هتصيروا تقولوا oxalic acid
+
+128
+00:11:24,780 --> 00:11:29,760
+salts أملاح ال oxalic acid بتشوفوا بلوراتها تحت
+
+129
+00:11:29,760 --> 00:11:33,320
+الميكروسكوب فلما تكونوا تسمعوا oxalic acid و أنتوا
+
+130
+00:11:33,320 --> 00:11:37,160
+قاعدين بتحلله و بتحددوا شنوع الأملاح اللي عاملة
+
+131
+00:11:37,160 --> 00:11:42,100
+الحصوات و إشي أقل تقدير يضالوا في بالكوا انه مار
+
+132
+00:11:42,100 --> 00:11:49,980
+عليكم ال oxalic acid is a dyeواضح؟ من كم كربون؟ من
+
+133
+00:11:49,980 --> 00:11:56,060
+كربون تاني هنا
+
+134
+00:11:56,060 --> 00:12:01,260
+زى ما قلنا بيوتين ديويك أسد طيب لو صار عندى ال
+
+135
+00:12:01,260 --> 00:12:06,920
+triple bondلاحظوا هنا أصبح أكتر من مجموعة وظيفية
+
+136
+00:12:06,920 --> 00:12:12,120
+اويك أسد فى عندى منه تانين و triple bond اذا هنا
+
+137
+00:12:12,120 --> 00:12:17,640
+هنعد العدد لكل واحد اتنين تلاتة اربعة بيوتاين
+
+138
+00:12:17,640 --> 00:12:21,940
+دايويك أسد لاحظوا ان ال triple bond عبّرت عنها
+
+139
+00:12:21,940 --> 00:12:29,020
+بإيش ب I بيوتاين دايويك أسد طبعا لما بيكون عندى
+
+140
+00:12:29,020 --> 00:12:35,180
+triple bond مافيش عندى قصة إيشالسيس والترانس لانقص
+
+141
+00:12:35,180 --> 00:12:38,780
+السيس والترانس موجودة في ال double bonds او في
+
+142
+00:12:38,780 --> 00:12:44,740
+الحلقات وبناء على ذلك لو اتيت على بيوتين ديويك اسد
+
+143
+00:12:44,740 --> 00:12:50,120
+high carbon تنتين تلاتة اربعة اذا حطيت مجموعتين ال
+
+144
+00:12:50,120 --> 00:12:56,920
+acid على جهة واحدة هذا السيس واحد اتنين تلاتة
+
+145
+00:12:56,920 --> 00:13:02,180
+اربعة اتو بيوتين ديويك اسد ماخد اسم malic acid
+
+146
+00:13:02,830 --> 00:13:07,910
+ماليك لاحظوا ما بنقرأش مالك لأنه الملك أسد حامض
+
+147
+00:13:07,910 --> 00:13:19,010
+تاني بدون ال E ماليك هذه ال E تبعت ال الكيل ماليك
+
+148
+00:13:19,670 --> 00:13:24,190
+الـ E تبعت الالكيد الان لو هذول المجمعتين في ال
+
+149
+00:13:24,190 --> 00:13:28,790
+بيوتينويك أسد اجوا عكس بعض ال trans يعني كان
+
+150
+00:13:28,790 --> 00:13:31,830
+المركب واحد اتنين تلات اربع ال trans to
+
+151
+00:13:31,830 --> 00:13:37,370
+بيوتيندايويك أسد و اجت ايش بنسميه فيوماريك أسد
+
+152
+00:13:37,370 --> 00:13:41,890
+فيوماريك أسد هذه أحماض مشهورة المفروض تحفظوها يعني
+
+153
+00:13:41,890 --> 00:13:46,530
+لو قلنالكم ماليك أسد و فيوماريك أسد المفروض تكونوا
+
+154
+00:13:46,530 --> 00:13:51,620
+عارفين من فيهم السس الماليكمن ال Trans الفيومارك
+
+155
+00:13:51,620 --> 00:13:55,240
+واحد منهم بيجيبوه من التفاح والتاني بيجيبوه من
+
+156
+00:13:55,240 --> 00:14:01,140
+الحيوانات من الأغنام ويمكن عشان هيك لو بتطلعوا على
+
+157
+00:14:01,140 --> 00:14:07,080
+غلاف الكتاب غلاف كتاب heart بتلاحظوا في صورة تفاحة
+
+158
+00:14:07,080 --> 00:14:13,160
+خضرة اذا بعض الناس انتبهوا للغلاف هذا واحد من
+
+159
+00:14:13,160 --> 00:14:16,500
+الأحماض انسيت المليك او الفيومارك من التفاح
+
+160
+00:14:16,500 --> 00:14:22,180
+بتقولوا واضح؟الان لو يا ترى البنزينة كان عليها
+
+161
+00:14:22,180 --> 00:14:26,820
+اكثر من ascent يعني
+
+162
+00:14:26,820 --> 00:14:32,240
+die ascent كام احتمال ممكن يكون ممكن اتنين يكونوا
+
+163
+00:14:32,240 --> 00:14:36,460
+جانب بعض يعني one two die substituted بنزين ممكن
+
+164
+00:14:36,460 --> 00:14:39,820
+يكونوا واحد اتنين تلاتة وممكن يكونوا واحد اتنين
+
+165
+00:14:39,820 --> 00:14:44,200
+تلاتة اربعة اذا المجموعتين حامض على البنزينة ممكن
+
+166
+00:14:44,200 --> 00:14:49,390
+تكون علاقة بينهم one twoاو one three او one four
+
+167
+00:14:49,390 --> 00:14:54,970
+الان كل واحد من هدوله له اسم ال one two بنسميه
+
+168
+00:14:54,970 --> 00:14:59,450
+ifthalic acid و ال one three isophthalic acid و ال
+
+169
+00:14:59,450 --> 00:15:04,470
+one four teraphthalic acid اقل تقدير بدكوا تحفظه
+
+170
+00:15:04,470 --> 00:15:09,790
+لانه يعود يتكرر معنا ال ifthalic acidواضح؟ لأنه
+
+171
+00:15:09,790 --> 00:15:13,250
+منه هنعمل phthalic anhydride المليك أسد منه هنعمل
+
+172
+00:15:13,250 --> 00:15:17,530
+مليك أنهيدريد يعني هيعود مر معنى لما ندرس
+
+173
+00:15:17,530 --> 00:15:21,810
+الانهيدريد مليك أنهيدريد و phthalic anhydride
+
+174
+00:15:21,810 --> 00:15:26,570
+فالمليك أسد الأربعة اللي فيهم دابل بوند و سيس
+
+175
+00:15:26,570 --> 00:15:32,270
+الفثالك أسد داي أسد على البنزين أورثو جايين
+
+176
+00:15:32,270 --> 00:15:35,630
+المجموعتين to each other يعني العلاقة بينهم one
+
+177
+00:15:35,630 --> 00:15:42,670
+twoالان ال physical properties of carboxylic acids
+
+178
+00:15:42,670 --> 00:15:50,310
+الكلام يشبه الكحولات لكن خلنا نقول يعني في
+
+179
+00:15:50,310 --> 00:15:53,990
+hydrogen bonding في ال acids ال hydrogen bonding
+
+180
+00:15:53,990 --> 00:15:57,990
+في ال acids بيعمل solubility in water لكن بيضل
+
+181
+00:15:57,990 --> 00:16:05,090
+بشكل عام ان الحامض هو عبارة عن R وC double bond O
+
+182
+00:16:06,090 --> 00:16:12,950
+OH بمعنى زي ما كان الكحول ايش كان الكحول خلينا
+
+183
+00:16:12,950 --> 00:16:19,170
+نقول CH2OH الآن في الكحول اتفقنا انه في جزء polar
+
+184
+00:16:19,170 --> 00:16:24,990
+و في جزء non polar الآن الحامض نفس الاشي جزء polar
+
+185
+00:16:24,990 --> 00:16:31,760
+و جزء non polarnon-polar اللي هي ال R و لذلك لو
+
+186
+00:16:31,760 --> 00:16:35,600
+اجيلا نحكي عن ال solubility in water ال solubility
+
+187
+00:16:35,600 --> 00:16:39,160
+in water بنقول ان ال low alcohols are water
+
+188
+00:16:39,160 --> 00:16:43,260
+soluble كل ما ال R كبرت بتقلل ال solubility الان
+
+189
+00:16:43,260 --> 00:16:48,700
+نفس الجملة بنكررها ال low acids are water soluble
+
+190
+00:16:48,700 --> 00:16:51,620
+معناه low acids يعني اللي فيهم ال R صغيرة كربونا
+
+191
+00:16:51,620 --> 00:16:55,380
+تنتين تلاتة هدول بيدوبوا في الميه يعني مثلا ال
+
+192
+00:16:55,380 --> 00:17:00,290
+acetic acid كام كربونا بالمجملتلتين ال .. ال
+
+193
+00:17:00,290 --> 00:17:05,290
+acetic acid الخل بدوب في الميه عمرا واحد عملة مخلل
+
+194
+00:17:05,290 --> 00:17:11,310
+مش بتحطوا شوية خل عليها هو ال acetic acid حتى الخل
+
+195
+00:17:11,310 --> 00:17:14,870
+اللي بتشتريوه من السوق هو عبارة عن ال acetic acid
+
+196
+00:17:14,870 --> 00:17:20,710
+مدوب في الميه بنسبة بسيطة 4-5% واضح؟ فبنقول احنا
+
+197
+00:17:20,710 --> 00:17:25,610
+ان ال acids و ال alcohols both are polarو بناء على
+
+198
+00:17:25,610 --> 00:17:28,770
+ذلك الـ low acids and low alcohols are water
+
+199
+00:17:28,770 --> 00:17:32,850
+soluble كلما ال chain كبرت كلما ال solubility
+
+200
+00:17:32,850 --> 00:17:38,710
+اشمالها بتقل الان وجود ال OH بتعمل hydrogen
+
+201
+00:17:38,710 --> 00:17:43,630
+bonding وبناء على ذلك الأحماض والكحولات بشكل عام
+
+202
+00:17:43,630 --> 00:17:48,630
+نقاط غليانهم اشمالها مرتفعة لأن هان و هان في عنده
+
+203
+00:17:49,330 --> 00:17:53,990
+hydrogen bonding يعني تطلعوا انتوا مثلا ال acetic
+
+204
+00:17:53,990 --> 00:17:59,490
+acid كربونتين ال boiling point تبعته كده؟ مية و
+
+205
+00:17:59,490 --> 00:18:05,030
+تمانتاش عالية جدا ال ethanol كان تمانية و سبعين ال
+
+206
+00:18:05,030 --> 00:18:07,750
+probionic acid مية و واحد و اربعين ال butanoic
+
+207
+00:18:07,750 --> 00:18:11,290
+acid مية و اربعة و ستين بعد هيك الأحماض بتبدأ
+
+208
+00:18:11,290 --> 00:18:17,410
+تقترب تصير solidواضح الفكرة فالارتفاع في ال
+
+209
+00:18:17,410 --> 00:18:21,230
+boiling point النسبي و اكيد في ال melting point هو
+
+210
+00:18:21,230 --> 00:18:28,130
+سببه ال hydrogen bonding الان بتجينا صفة تانية
+
+211
+00:18:28,130 --> 00:18:34,050
+اللي هي ال acidity ال acidity متعلقة بإيش؟بال اتش
+
+212
+00:18:34,050 --> 00:18:38,190
+الموجودة على ال oxygen يعني هذه الاتش انها تفقد
+
+213
+00:18:38,190 --> 00:18:42,150
+ويتكون هنا عندي ايون سالم او تفقد هنا ويتكون عندي
+
+214
+00:18:42,150 --> 00:18:46,350
+هنا ايون سالم قلنا احنا ان ال alcohols they are in
+
+215
+00:18:46,350 --> 00:18:52,150
+general acidic و ال carboxylic acid acidic لكن جدش
+
+216
+00:18:52,150 --> 00:18:56,850
+ال bk ايه لل alcohol اذا انتم متذكرين تقريبا ال
+
+217
+00:18:56,850 --> 00:19:01,970
+alcohols العادية مثانول اثانولكانت خمس طائش، ست
+
+218
+00:19:01,970 --> 00:19:07,790
+طائش، الآن ال carboxylic acids أقوى كتير ال BKA
+
+219
+00:19:07,790 --> 00:19:12,770
+تبعتهم حوالي أربع على خمسة مين أقوى كتير ال
+
+220
+00:19:12,770 --> 00:19:16,430
+carboxylic acids ولا الكحولات المناظرة أو الكحولات
+
+221
+00:19:16,430 --> 00:19:22,410
+بشكل عام؟ ال carboxylic acids، إيش السبب؟ حكيناها
+
+222
+00:19:25,810 --> 00:19:29,770
+الـ H فقدت الله يرحمها، ضال الايون السالب لما
+
+223
+00:19:29,770 --> 00:19:33,710
+اتكلمنا عن ال acidity of acids قلنا بدنا ننظر
+
+224
+00:19:33,710 --> 00:19:39,510
+لثبات الايون السالب ال resonance هنا في resonance
+
+225
+00:19:39,510 --> 00:19:45,620
+مش هذا السالب ممكن يكون هناأه إذا ال acids they
+
+226
+00:19:45,620 --> 00:19:49,820
+are more acidic than alcohols or they have a lower
+
+227
+00:19:49,820 --> 00:19:55,460
+pka because of resonance ال charge in alcohol is
+
+228
+00:19:55,460 --> 00:20:01,940
+ايش وصفناها ثابتة في محلها مابتتنقلش حد يقوللي شو
+
+229
+00:20:01,940 --> 00:20:04,720
+الكلمة اللي استعملناها لهذه الشحنة اللي ثابتة في
+
+230
+00:20:04,720 --> 00:20:09,640
+محلها مابتتنقل لاحظوا اللي مابدرسوش مابحفظوش
+
+231
+00:20:09,640 --> 00:20:15,140
+المصطلحات localizedin its location ايش يعني
+
+232
+00:20:15,140 --> 00:20:20,420
+location في موقعها localized يعني ثابتة بموقعها
+
+233
+00:20:20,420 --> 00:20:26,470
+متمركزة localizedجاعدة بمحلة الانهاد اللي جاعدة
+
+234
+00:20:26,470 --> 00:20:31,970
+بتتنجل مرة هان و مرة هان و يعملالها resonance إيش
+
+235
+00:20:31,970 --> 00:20:39,450
+بنسميها؟ delocalized مرة هان و مرة هان و مرة هان و
+
+236
+00:20:39,450 --> 00:20:44,570
+مرة هان واضح؟ إذا وين ال charge localized و وين ال
+
+237
+00:20:44,570 --> 00:20:49,330
+delocalized؟localized في ال alcohols لأن مافيش
+
+238
+00:20:49,330 --> 00:20:53,570
+فيهم resonance delocalized قاعدة بتنقل شمال ويمين
+
+239
+00:20:53,570 --> 00:20:58,350
+في ال carboxylic acids لأن في جنبها C double bond
+
+240
+00:20:58,350 --> 00:21:04,130
+O فممكن يتم انتقال ال bond و الشحنة مرة بتكون هنا
+
+241
+00:21:04,130 --> 00:21:07,890
+و مرة بتكون هنا انا بتقول كل هذا ال resonance سبق
+
+242
+00:21:07,890 --> 00:21:12,130
+ان اوضحناه بشكل كامل لما حكينا ال alcohol بحاجة
+
+243
+00:21:12,130 --> 00:21:17,400
+لإنكم تتبعوه فال resonance هو سببالحمضية الزايدة
+
+244
+00:21:17,400 --> 00:21:22,700
+للاسدس ولذلك الكربوكسليك اسدس الآن بنقدرش نسيبهم
+
+245
+00:21:22,700 --> 00:21:27,920
+ينكبوا على أيدنا يعني الكحولات ال BKA بتاعتهم 15
+
+246
+00:21:27,920 --> 00:21:31,280
+-16 زي الميه مش مشكلة لو اجوا على أيدنا و غسلنا
+
+247
+00:21:31,280 --> 00:21:36,100
+فيهم و بيوتلوا البكتيريا بس ماحدش عمره يجرب يغسل
+
+248
+00:21:36,100 --> 00:21:41,160
+بمحلول حتى كربوكسليك اسدس و لو بنسميها weakيعني في
+
+249
+00:21:41,160 --> 00:21:46,200
+نهاية أحمار ضعيفة بالنسبة لل HCl وبالنسبة لل H2SO4
+
+250
+00:21:46,200 --> 00:21:52,120
+لكن بتظهر أقوى كتير من الكحولات وبتظهر تحرق
+
+251
+00:21:52,120 --> 00:21:57,700
+الإيدين واضح؟ طيب
+
+252
+00:22:04,580 --> 00:22:08,520
+كل موضوع ال acidity و كتاب الثابت ال acidity و ما
+
+253
+00:22:08,520 --> 00:22:12,800
+إلى ذلك اتعلمناه و اننا نتطلع على ال BKA لاحظوا
+
+254
+00:22:12,800 --> 00:22:17,100
+لما نتطلع على ال BKA اتطلعوا مثلا ال formic acid
+
+255
+00:22:17,100 --> 00:22:20,560
+تلاتة و ستة ال acetic acid اربعة و سبعة ال
+
+256
+00:22:20,560 --> 00:22:24,480
+probionic acid اربعة و تمانية زي ما حكينا تقريبا
+
+257
+00:22:24,480 --> 00:22:29,740
+معظم هدول ال acids في منطقة ال ايش التلاتة اربعة
+
+258
+00:22:29,740 --> 00:22:35,390
+خمسةواضح؟ معظم هدول ال acid في 3,4,5 لاحظوا ال
+
+259
+00:22:35,390 --> 00:22:41,950
+alcohol عمل مقارنة هنا هاي كل ال acid تتطلع عليها
+
+260
+00:22:41,950 --> 00:22:49,750
+ال PKA تعتها قليلة 3,4 لكن ال phenol عشرة واخدنا
+
+261
+00:22:49,750 --> 00:22:53,790
+ليش ال phenol كانت ال acidity شوية مرتفعة تبعته
+
+262
+00:22:53,790 --> 00:22:59,460
+بسبب ال resonanceيا ريتنا خلناه في الامتحان
+
+263
+00:22:59,460 --> 00:23:05,440
+chapter 7 سبب ال resonance ال ethanol والميه
+
+264
+00:23:05,440 --> 00:23:14,240
+تقريبا ال BKA تبعهم زي بعض 16 15.5 منخفض الان في
+
+265
+00:23:14,240 --> 00:23:18,820
+جوا الأحماض او في جوا الكحولات لما نيجي نقول حامض
+
+266
+00:23:18,820 --> 00:23:25,950
+اقوى من حامضوقلنا بنفتش على السبب كام سبب طرحناهم
+
+267
+00:23:25,950 --> 00:23:32,650
+تلاتة يا ال resonance يا ال size يا ال inductive
+
+268
+00:23:32,650 --> 00:23:36,030
+effect الان تطلعوا هنا بتلاقوا هاي حامض سبحان الله
+
+269
+00:23:36,030 --> 00:23:42,590
+صار إيش ماله قوى أقوى كتير وهذا مشتاق من ال acetic
+
+270
+00:23:42,590 --> 00:23:50,360
+acid خلينا نرسمه هناسي دبل بوند او اتش اتراي كلور
+
+271
+00:23:50,360 --> 00:23:55,800
+و أسيتك أسل اه هذا أسيتك أسل حامل تلت مجموعات كلور
+
+272
+00:23:55,800 --> 00:23:59,440
+تخيلوا
+
+273
+00:23:59,440 --> 00:24:06,870
+انه لما بيصير ال ionization بتصير هذه O minusماذا
+
+274
+00:24:06,870 --> 00:24:11,930
+يحدث لدي هنا اي effect؟ Inductive effect ان هذه
+
+275
+00:24:11,930 --> 00:24:16,930
+الكلور تسحب جزء من الشحنة السالبة وهذه تسحب جزء من
+
+276
+00:24:16,930 --> 00:24:18,610
+الشحنة السالبة وهذه تسحب جزء من الشحنة السالبة هذا
+
+277
+00:24:18,610 --> 00:24:23,090
+ال effect Inductive فال Trichloroacetic acid is
+
+278
+00:24:23,090 --> 00:24:28,830
+stronger than اكيد ال Dichloro لاحظوا ال Dichloro
+
+279
+00:24:28,830 --> 00:24:37,560
+في تن تل بيسحبوا ال Trichloro الكلور واحدةالاسيتك
+
+280
+00:24:37,560 --> 00:24:43,220
+أسد مفيش عشان هيك شوفوا التدريج الاسيتك أسد ال PKA
+
+281
+00:24:43,220 --> 00:24:51,480
+74% لو حطينا له وان كلورين صار كداش 82 لو حطينا
+
+282
+00:24:51,480 --> 00:24:56,870
+تنتينواحد و تلاتة من عشرة لو حطينا تلاتة point
+
+283
+00:24:56,870 --> 00:25:01,030
+seven الكلام منطقي ولا لأ inductive effect بيزيد
+
+284
+00:25:01,030 --> 00:25:04,930
+اعلى اشي بيصير لما يكونوا تلاتة اقل لو كانوا تلتين
+
+285
+00:25:04,930 --> 00:25:09,470
+اقل لو كانوا واحدة كل هذا الكلام في تفصيل ال
+
+286
+00:25:09,470 --> 00:25:14,050
+acidity الحقيقة موازي تماما للكلام اللي انا اخدناه
+
+287
+00:25:14,680 --> 00:25:18,540
+في الكحولات موازي تماما للكلام اللي أخدناه في
+
+288
+00:25:18,540 --> 00:25:22,480
+الكحولات ال resonance effect و ال inductive effect
+
+289
+00:25:22,480 --> 00:25:28,800
+و طبعا لأن ال BKA عالية في نهاية الأحماض بتتفاعل
+
+290
+00:25:28,800 --> 00:25:37,130
+مع ال NiOH حمض زي قاعدة ملح زي دماغ واضح؟هي الحامض
+
+291
+00:25:37,130 --> 00:25:41,090
+زاد الاني و اتش ال او اتش مع ال اتش هتعمل H2O و
+
+292
+00:25:41,090 --> 00:25:46,130
+هيصير عندى ملح الحامض و اتعلمنا الاصل كيف بنسميهم
+
+293
+00:25:46,130 --> 00:25:53,310
+يعني لو بدنا ناخد كمثال حقيقي ال acetic acid لو
+
+294
+00:25:53,310 --> 00:25:57,510
+بدنا ناخد كمثال حقيقي اللى عادة بتعملوله titration
+
+295
+00:25:57,510 --> 00:26:06,280
+فى التجارب العملية اللى هوC H 3 C O O H زائد N A O
+
+296
+00:26:06,280 --> 00:26:13,580
+H مين اتنجلنا شو بدي اكتب المعادلة وقتها C H 3 C O
+
+297
+00:26:13,580 --> 00:26:25,460
+O O خلينا نقول هيك N A Plus زائد H 2 O الآن هذا
+
+298
+00:26:25,460 --> 00:26:27,900
+الناتج لما بدي اسميه كيف بسميه
+
+299
+00:26:33,060 --> 00:26:38,000
+صوديوم والمجموع اللى جاى من ال acetic acid اذا من
+
+300
+00:26:38,000 --> 00:26:43,560
+ال formic acid فورميت اذا من ال probionic acid
+
+301
+00:26:43,560 --> 00:26:48,220
+بروبانويت من ال butanoic acid بيوتانويت اذا
+
+302
+00:26:48,220 --> 00:26:52,360
+النهاية ات زى ما كنتوا تقولوا صلفيت و كربونيت و
+
+303
+00:26:52,360 --> 00:26:59,010
+نيتريت نهاية ات هي نهاية ال acid اذا صوديومacetate
+
+304
+00:26:59,010 --> 00:27:05,770
+فانا شيلت ال اك او ال او اك اسد و حطيت بدلها ايش
+
+305
+00:27:05,770 --> 00:27:11,880
+ات فال ات هذهنهاية الايون السالب Sodium Acetate
+
+306
+00:27:11,880 --> 00:27:16,340
+وسبق ان وضحنا لكم ايش معنى ال Acetyl group و ال
+
+307
+00:27:16,340 --> 00:27:20,180
+Acetate group و ال Acetic Acid قولنا لكم ان هذه
+
+308
+00:27:20,180 --> 00:27:25,700
+المجموعة لحالة شو اسمها AC Acetate لو حطينا لل O
+
+309
+00:27:25,700 --> 00:27:32,030
+صارت Acetate لو حطينا لل Hأسيتك أسد فالأسيتك أسد
+
+310
+00:27:32,030 --> 00:27:41,030
+اختصارا a-c-o-h واضح أسيتل أسيتيت مع الأكسجين
+
+311
+00:27:41,030 --> 00:27:42,330
+أسيتك أسد
+
+312
+00:28:02,030 --> 00:28:03,610
+اشمع له الجهاز
+
+313
+00:28:28,050 --> 00:28:34,830
+كيف بنحضر ال carboxylic acids زي ما بتلاحظوا في
+
+314
+00:28:34,830 --> 00:28:40,830
+عندنا مجموعة كبيرة من الطرق لتحضير ال carboxylic
+
+315
+00:28:40,830 --> 00:28:46,910
+acids ممكن نبدأ نستعرض بعضها الحقيقة البعض منها مر
+
+316
+00:28:46,910 --> 00:28:53,000
+علينا البعض منها مر علينا وبعضهاعبارة عن أشياء
+
+317
+00:28:53,000 --> 00:28:57,720
+جديدة اليوم احنا بناخد الشغلتين الخفاف اللي مروا
+
+318
+00:28:57,720 --> 00:29:02,000
+علينا و الأشياء الجديدة بنسيبهم للمرة القادمة
+
+319
+00:29:02,000 --> 00:29:06,780
+الشغلتين اللي مروا علينا لما أخدنا أكسدة ال
+
+320
+00:29:06,780 --> 00:29:13,540
+primary alcohols مين تذكرني إياها بجملة بسيطة جدا؟
+
+321
+00:29:13,540 --> 00:29:19,870
+إيش حكينا في أكسدة ال primary alcohols؟قلنا اكسدت
+
+322
+00:29:19,870 --> 00:29:24,790
+ال primary alcohol بعمل مؤكسد خفيف بتعطيني ال
+
+323
+00:29:24,790 --> 00:29:30,330
+aldehyde واضح شو العمل المؤكسد الخفيف اللي بيحول
+
+324
+00:29:30,330 --> 00:29:36,310
+ال primary alcohol ل aldehyde بي سي سي الان طيب لو
+
+325
+00:29:36,310 --> 00:29:45,200
+ال primary alcohol استعملتله عامل مؤكسد قويبتحول ل
+
+326
+00:29:45,200 --> 00:29:48,540
+الديهايد و بيضلوا ماشي عدل ل ايش ل carboxylic
+
+327
+00:29:48,540 --> 00:29:52,420
+acids اذا ممكن انا اتحرك من ال primary alcohol ل
+
+328
+00:29:52,420 --> 00:29:57,960
+carboxylic acid باستعمال اي عامل مؤكسد كيامان او
+
+329
+00:29:57,960 --> 00:30:00,300
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+330
+00:30:00,300 --> 00:30:00,880
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+331
+00:30:00,880 --> 00:30:01,180
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+332
+00:30:01,180 --> 00:30:01,660
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+333
+00:30:01,660 --> 00:30:08,120
+فور و كيامان او فور و كيامان او فور و كيامان او
+
+334
+00:30:08,120 --> 00:30:14,380
+فور و كيامان او فور و كيامان ابيصيروا alcohol
+
+335
+00:30:14,380 --> 00:30:18,360
+مباشرة طبعا اكيد مرورا بال الديهيدز الان في شبطر
+
+336
+00:30:18,360 --> 00:30:23,960
+ال الديهيدز و ال ketones اخدنا ان ال الديهيدز ايضا
+
+337
+00:30:23,960 --> 00:30:32,190
+بتأكسد لاش ل acids و ال ketones بتأكسدوشواضح؟
+
+338
+00:30:32,190 --> 00:30:37,030
+لاحظوا الخطأ الشائع بهمش .. خلّي كل العالم يسمع
+
+339
+00:30:37,030 --> 00:30:40,930
+الخطأ الشائع عند الطلاب أنه يوما بلتهيوا بامتحان
+
+340
+00:30:40,930 --> 00:30:44,950
+بنسوا المواد التانية و لذلك بنصير إحنا نحكي معهم و
+
+341
+00:30:44,950 --> 00:30:49,970
+هم خارج ال rhythm تماما يعني أكسدت ال aldehydes ل
+
+342
+00:30:49,970 --> 00:30:53,010
+carboxylic acids في المحاضرة السابقة هذه من
+
+343
+00:30:53,010 --> 00:30:56,110
+الأخطاء الشائعة اللي بيرتكبوها الطلاب أنه بيضالوا
+
+344
+00:30:56,110 --> 00:31:01,240
+يحطوا شغلة بدل شغلة مافيش عندهم اتزانفي الدراسة من
+
+345
+00:31:01,240 --> 00:31:06,060
+البداية يعني بيموتوا مادة او مادتيلة مدة اسبوعين و
+
+346
+00:31:06,060 --> 00:31:09,920
+بيغيبوا عن محاضراتها و بيلتهيوا لمادة الامتحان
+
+347
+00:31:09,920 --> 00:31:13,300
+عملوها بيجوا بيلاجوا عندهم مشكلة في المادة التانية
+
+348
+00:31:13,300 --> 00:31:18,720
+و هكذا دائما حافظوا على انه تظلوا متزينين في جميع
+
+349
+00:31:18,720 --> 00:31:22,900
+المواد يعني بيزعل المدرس لما ييجي يحكيلكوا انه
+
+350
+00:31:22,900 --> 00:31:26,080
+اكسدت ال primary alcohols ل acids و اكسدت ال
+
+351
+00:31:26,080 --> 00:31:30,660
+aldehydes ل acidsو تعب كتير في الكلام و يلاقي أنكم
+
+352
+00:31:30,660 --> 00:31:35,760
+مش متفاعلين طبعا ليش أنا نوّهت لهذا الكلام لأن
+
+353
+00:31:35,760 --> 00:31:39,720
+انتوا في النهاية لسه سنة أولى طبيعة الحياة أنه
+
+354
+00:31:39,720 --> 00:31:46,960
+هيطلب منكم عشر شغلات في يوم واحد الآن مش ممكن أن
+
+355
+00:31:46,960 --> 00:31:52,430
+البني آدم يعيش و هو بيموت شغلة على حساب شغلةلازم
+
+356
+00:31:52,430 --> 00:31:56,590
+يعمل كل شيء يعني طبيعة الحياة بعد شوية أنه بده
+
+357
+00:31:56,590 --> 00:32:02,630
+يكون عندكم عمل بدكم تعمله طفل بدكم اتربيه بيت بدكم
+
+358
+00:32:02,630 --> 00:32:06,570
+تديروا بالك عليه زوج بدكم تديروا بالك عليه الآن
+
+359
+00:32:06,570 --> 00:32:10,550
+اتخيلوا لو واحدة من هذه الأربعة طغت على التانية
+
+360
+00:32:10,550 --> 00:32:14,370
+فقط فكرتوا بالعمل الولد الصغير بيسخن و بيموت و
+
+361
+00:32:14,370 --> 00:32:18,330
+أنتم مش دارين على حالكم فقط فكرتوا بالولد الصغير
+
+362
+00:32:19,120 --> 00:32:23,340
+الجوز بيبطل عنكوا وانتوا مش دارين عن حالكوا ولذلك
+
+363
+00:32:23,340 --> 00:32:28,320
+لما تكتر الأعمال عند الإنسان من الأخطاء الشائعة
+
+364
+00:32:28,320 --> 00:32:34,910
+جدا انه يقوم بعمل ويهمل تلت أعمالاليوم في الحياة
+
+365
+00:32:34,910 --> 00:32:40,870
+العملية الجواب لأ لازم تجوم بكل الأعمال و تقسم
+
+366
+00:32:40,870 --> 00:32:45,570
+وقتك على كل الأعمال و كذلك انتوا كطلاب لازم تدرسوا
+
+367
+00:32:45,570 --> 00:32:49,730
+لكل المواد مش اذا اجاكوا امتحان اتحدد بعد أسبوعين
+
+368
+00:32:49,730 --> 00:32:53,590
+ع مدى الأسبوعين بندرس للامتحان و بنغيب عن المواد و
+
+369
+00:32:53,590 --> 00:33:00,740
+مابنفتحاش و بتضل ايشيصير عندكم التراكم هذه نصيحة
+
+370
+00:33:00,740 --> 00:33:05,180
+جيد مش بس انتوا تسمعوها وكمان الناس اللي بيحضروا
+
+371
+00:33:05,180 --> 00:33:10,300
+المحاضرات حتى لو كانوا من خارج الجامعة يسمعوا هذا
+
+372
+00:33:10,300 --> 00:33:15,540
+الكلام انه الإنسان أعماله كثيرة لازم يوازن بين
+
+373
+00:33:15,540 --> 00:33:21,600
+أعماله بس مش صح اطلاقا انه يعمل عمل على حساب عمل
+
+374
+00:33:21,600 --> 00:33:27,400
+ابهيك بنكون أخدنا طريقتين لتحضيرالاحماد من
+
+375
+00:33:27,400 --> 00:33:30,980
+الكحولات و من ال الدي هايتز في طرق ثانية ان شاء
+
+376
+00:33:30,980 --> 00:33:34,840
+الله المرة القادمة بنكمل فيها و بننهي لحد ذلك
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/V8hlE7JcPsU.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/V8hlE7JcPsU.srt
new file mode 100644
index 0000000000000000000000000000000000000000..54c7671d5b11d4d0bfb2cf714d5440c71b992bde
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/V8hlE7JcPsU.srt
@@ -0,0 +1,1322 @@
+1
+00:00:18,360 --> 00:00:22,720
+بسم الله الرحمن الرحيم. المرة الماضية بدأنا نتكلم في
+
+2
+00:00:22,720 --> 00:00:29,780
+موضوع البروتينات، وكان الأساس أن نتعرف على الأحماض
+
+3
+00:00:29,780 --> 00:00:34,200
+الأمينية (amino acids). تعرّفنا عليهم، وتعرّفنا
+
+4
+00:00:34,200 --> 00:00:38,560
+طبعًا كيف يكونون في الوسط الحامضي أو القاعدي، كيف
+
+5
+00:00:38,560 --> 00:00:44,280
+بتتأثر شحنتهم بالـpH، وهذا الكلام يُؤدي
+
+6
+00:00:44,280 --> 00:00:49,560
+إلى طريقة عملية لفصلِهم عن بعضهم البعض، اعتمادًا على
+
+7
+00:00:49,560 --> 00:00:54,380
+اختلاف الـpH، وهي فكرة الـElectrophoresis.
+
+8
+00:00:54,380 --> 00:01:01,420
+الآن، إذا استمرّينا في الموضوع، لو أردنا نتكلم على
+
+9
+00:01:01,420 --> 00:01:07,460
+تفاعلات الأحماض الأمينية. طبعًا، إذا قلنا amino acids،
+
+10
+00:01:07,460 --> 00:01:13,680
+كلمتي amino، اللي هي الـAmines اللي أخذناهم في
+
+11
+00:01:13,680 --> 00:01:20,720
+الفصل/الشطر 11، و acids الأحماض اللي أخذناهم في الشطر
+
+12
+00:01:20,720 --> 00:01:26,640
+10. إذًا تفاعلاتهم هي تفاعلات الـAmines والأحماض.
+
+13
+00:01:26,640 --> 00:01:34,030
+يعني أي تفاعل كنا نأخذه للأمين في السابق في
+
+14
+00:01:34,030 --> 00:01:37,850
+الكيمياء العضوية العادية، سيتفاعل الـamino acids فيه من خلال
+
+15
+00:01:37,850 --> 00:01:42,820
+الـamino group. أي تفاعل كنا نأخذه للـacid، سيكون
+
+16
+00:01:42,820 --> 00:01:48,060
+نفس الشيء مع الـamino acids. يعني، مثلًا، عندكم جملة
+
+17
+00:01:48,060 --> 00:01:54,600
+عامة أن acid زائد alcohol، ماذا يعطينا؟ ester، بناءً
+
+18
+00:01:54,600 --> 00:01:59,420
+على ذلك، الـamino acids فيهم acids، حتى لو كانوا على
+
+19
+00:01:59,420 --> 00:02:04,180
+شكل الـsalt تبعهم، يظلون acids. هذا الـacid لو أجئت
+
+20
+00:02:04,180 --> 00:02:09,140
+فعلتَه مع alcohol، هذه جزئية الـacid، هذه الـalcohol،
+
+21
+00:02:10,310 --> 00:02:16,150
+ماذا سيعطيني؟ إيستر، سيصبح C=O OR أو
+
+22
+00:02:16,150 --> 00:02:22,830
+COOR. إذًا هذا مثال على أنه تفاعل كحامض:  حمض زائد
+
+23
+00:02:22,830 --> 00:02:28,430
+كحول، إيستر. ليس هناك شيء جديد. كذلك، الحالة لو
+
+24
+00:02:28,430 --> 00:02:32,110
+إحنا جئنا على الـamino group، حتى لو كنا كاتبينها
+
+25
+00:02:32,110 --> 00:02:36,590
+على شكل NH3+، إحنا بمجرّد ما نفعلها مع base، ترجع
+
+26
+00:02:36,590 --> 00:02:37,710
+نحو… نحو… نحو… نحو… نحو… نحو… نحو… نحو… نحو… نحو…
+
+27
+00:02:37,830 --> 00:02:41,930
+عادية. لو اتش هنا، قلنا هذا في النهاية NH2.
+
+28
+00:02:41,930 --> 00:02:46,970
+صفة. بدنا نفعلها مع acid chloride أو مع ester أو مع
+
+29
+00:02:46,970 --> 00:02:50,330
+acid anhydride. كيف كان الأمين يتفاعل مع الـacid
+
+30
+00:02:50,330 --> 00:02:57,310
+chloride؟ بالإحلال بهذا الشكل، ويعمل عملية إحلال في
+
+31
+00:02:57,310 --> 00:03:03,030
+هذه الحالة، سيعطيني amide. في هذه الحالة، سيعطيني amide.
+
+32
+00:03:03,030 --> 00:03:09,170
+واضح؟ هذه الـamide:  NHC=O، واضح؟ ففكرة
+
+33
+00:03:09,170 --> 00:03:14,510
+تفاعلات الـamino acids هي فكرة بسيطة لما فيهم
+
+34
+00:03:14,510 --> 00:03:18,830
+سابقًا تفاعلات الـamines، ولما فيهم سابقًا تفاعلات الـ
+
+35
+00:03:18,830 --> 00:03:24,410
+acids. يمكن أخذتم أنتم أن ammonia أو amine زائد
+
+36
+00:03:24,410 --> 00:03:31,370
+acid، ماذا كان يعطينا بشكل عام؟ amide. تمام؟ وبناءً على ذلك،
+
+37
+00:03:31,370 --> 00:03:37,690
+هذه الفكرة أيضًا ممكن نأخذها، لكن من خلال أن المتفاعلين
+
+38
+00:03:37,690 --> 00:03:44,640
+جزيئين من الـamino acids مع بعضهما البعض. من جزء نأخذ
+
+39
+00:03:44,640 --> 00:03:51,320
+منه، جزء نأخذ منه مجموعة الـnitrogen، الـNH2، وجزء
+
+40
+00:03:51,320 --> 00:03:56,860
+نأخذه من جزء الـacid، واضح؟ فلما نجي نقول NH2، زي الـ
+
+41
+00:03:56,860 --> 00:04:02,840
+acid، تفاعلوا، ماذا سيعطوني؟ amide. إذًا، two amino acids
+
+42
+00:04:02,840 --> 00:04:08,640
+react with each other to form amides. واضح؟ هذا
+
+43
+00:04:08,640 --> 00:04:13,510
+الكلام اللي موجود هنا. يعني لو أنا اطلعت على هذا
+
+44
+00:04:13,510 --> 00:04:18,770
+المركب اللي بيطلع عندي، هذا أصلًا كان NH2، Amino Acid،
+
+45
+00:04:18,770 --> 00:04:22,970
+وهذا الـAmino Acid الثاني، هذا Amino Acid، وهذا
+
+46
+00:04:22,970 --> 00:04:28,850
+Amino Acid كان ماذا؟ C=O OH. لما الـNH2
+
+47
+00:04:28,850 --> 00:04:36,760
+جاءت وتفاعلت هنا، ماذا فعلت؟ طردت الـOH، وانخصم من هنا
+
+48
+00:04:36,760 --> 00:04:43,800
+H، OH مع H، إذًا صافينا على هذا الشكل. هذه الـtwo amino
+
+49
+00:04:43,800 --> 00:04:49,500
+acids اتحدوا مع بعض، عملوا amide، C=O NH.
+
+50
+00:04:49,500 --> 00:04:53,520
+أين الرابطة الجديدة اللي تكونت بين الـtwo amino
+
+51
+00:04:53,520 --> 00:05:05,080
+acids؟ هذه. هذا كان نهاية الجزء الأول، NH2، وكان
+
+52
+00:05:05,080 --> 00:05:09,220
+هذا الجزء نهايته أيضًا بـC=O OH. الآن الـNH2
+
+53
+00:05:09,220 --> 00:05:12,220
+اتصلت بالـC=O OH. إذًا هذه الرابطة
+
+54
+00:05:12,220 --> 00:05:16,800
+اللي تكونت، اللي هي amide bond. الآن، لأنه هنا أنا
+
+55
+00:05:16,800 --> 00:05:21,820
+أبدأ أدمج amino acids مع بعضهم البعض لتكوين
+
+56
+00:05:21,820 --> 00:05:25,580
+بيبتيد، هذه رابطة هنا تكونت، ورابطة هنا تكونت، هذه
+
+57
+00:05:25,580 --> 00:05:30,860
+الـamide bond، نصير احنا نعطيها اسم peptide bond، واضح؟
+
+58
+00:05:30,860 --> 00:05:36,140
+فلما نقول الـpeptide bond، هي حقيقة الـamide bond.
+
+59
+00:05:36,140 --> 00:05:40,760
+واضح؟ لكن لأنه أنا لما بأفعل two amino acids أو
+
+60
+00:05:40,760 --> 00:05:46,680
+three amino acids، بكون ماذا؟ peptide. ولو كبروا
+
+61
+00:05:46,680 --> 00:05:52,080
+كثيرًا، بيصيروا ماذا؟ protein. واضح؟ فالـpeptides والـ
+
+62
+00:05:52,080 --> 00:05:57,060
+proteins فيهم الـamide bond، واضح؟ أو نسميها في هذه
+
+63
+00:05:57,060 --> 00:06:02,470
+الحالة، تحديدًا peptide bond. فلو قلنا مثلًا سؤال: peptide
+
+64
+00:06:02,470 --> 00:06:06,330
+bond is an amide bond، طبعًا هي amide، C=
+
+65
+00:06:06,330 --> 00:06:13,090
+O NH. طبعًا، سيكون فيها كل خواص الـamides، أن ستكون
+
+66
+00:06:13,090 --> 00:06:18,490
+هذه المنطقة amide، reactive أم unreactive؟
+
+67
+00:06:18,490 --> 00:06:23,850
+unreactive. إحنا قلنا الكلمة الأساسية المميزة
+
+68
+00:06:23,850 --> 00:06:29,670
+للـamides: they are unreactive. وبناءً على ذلك، حتى الـ
+
+69
+00:06:29,670 --> 00:06:34,830
+hydrolysis تبعهم، سيكون سهل أم صعب؟ صعب. ولذلك، بعد
+
+70
+00:06:34,830 --> 00:06:38,130
+شوية، لما تيجوا تأخذوا protein، على سبيل المثال،
+
+71
+00:06:38,130 --> 00:06:43,290
+مكون من amino acids، وأقول بدي أحلل هذا الـ
+
+72
+00:06:43,290 --> 00:06:49,490
+protein إلى مكوناته، سيكون الجواب: والله، أغليه
+
+73
+00:06:49,490 --> 00:06:56,110
+في وسط حامضي مركز، مثلًا، لمدة 24 ساعة وهو يغلي، عشان
+
+74
+00:06:56,110 --> 00:07:02,230
+تقدر تكسر الـماذا؟ الـamide bonds. هذه الشروط سهلة أم
+
+75
+00:07:02,230 --> 00:07:08,990
+صعبة؟ شروط صعبة. الآن، لما إحنا بنعمل اتحاد لـtwo
+
+76
+00:07:08,990 --> 00:07:13,490
+amino acids، بنكون الـpeptide bond. ممكن نحط كمان
+
+77
+00:07:13,490 --> 00:07:18,050
+amino acid، هذا بالتأكيد. ممكن كمان نستمر، نجيب مجموعة
+
+78
+00:07:18,050 --> 00:07:24,370
+amino acids، وهكذا. الآن، الـpeptide، عادةً لما إحنا بنكونه،
+
+79
+00:07:24,370 --> 00:07:32,070
+بنلاحظ أنه في شيء مشترك في هيكل عام:  NCC=O.
+
+80
+00:07:32,070 --> 00:07:37,540
+هذا الهيكل العام، ماذا به؟ متكرر. يعني، هذه عندي هنا
+
+81
+00:07:37,540 --> 00:07:44,780
+هنا NCC=O. بعد، ماذا سيأتي كمان
+
+82
+00:07:44,780 --> 00:07:53,670
+مرة؟ NCC=O. لو عملت كمان، ماذا سيأتي؟ NCC=O، وهكذا. واضحة هذه النقطة؟ فهذا شيء
+
+83
+00:07:53,670 --> 00:07:59,630
+مشترك في الـpeptides. الآن، اللي بيكون عادةً على
+
+84
+00:07:59,630 --> 00:08:04,910
+الجهة اليسرى بالنسبة لكم، نبدأ منه، نقول أن هذا
+
+85
+00:08:04,910 --> 00:08:10,890
+الجزء يمثل الـN-terminal of the peptide، يعني
+
+86
+00:08:10,890 --> 00:08:16,670
+الطرف اللي فيه نيتروجين من الـpeptide. نرسمه هكذا،
+
+87
+00:08:16,670 --> 00:08:21,290
+عشان الكل يفهم مع بعضه. وهذا الجزء الأخير، بيكون
+
+88
+00:08:21,290 --> 00:08:27,000
+أي: الـC-terminal. فأنا لما بدي أعمل
+
+89
+00:08:27,000 --> 00:08:33,700
+peptide، سواء مكون من واحد أو اثنين أو ثلاثة أو
+
+90
+00:08:33,700 --> 00:08:38,120
+أربعة أو خمسة amino acids، سهل جدًا عليّ، بدي أعمل N-
+
+91
+00:08:38,120 --> 00:08:44,800
+terminal وبدي أعمل C-terminal. الآن، ما الوحدة
+
+92
+00:08:44,800 --> 00:08:50,000
+المتكررة؟ ماذا المختلف؟ الـR. بناءً
+
+93
+00:08:50,000 --> 00:08:59,730
+على ذلك، لو أنا الآن آتي وأقول لكم: والله، أنا بدي
+
+94
+00:09:04,870 --> 00:09:12,740
+بيبتيد من أربعة amino acids، ارسموه لي. ممكن أجيب لكم
+
+95
+00:09:12,740 --> 00:09:16,520
+سؤال زي هذا في الامتحان: ارسموا لي الـpeptide اللي من
+
+96
+00:09:16,520 --> 00:09:22,560
+أربعة amino acids اللي هم مثلًا بهذا الشكل:  glycine،
+
+97
+00:09:22,560 --> 00:09:32,270
+alanine، cysteine، وphenylalanine. ستأتوا وتقولون: إحنا
+
+98
+00:09:32,270 --> 00:09:37,010
+بنكون حافظين هذول؟ إحنا اتفقنا معكم أن الـR group
+
+99
+00:09:37,010 --> 00:09:40,870
+في الـglycine H، تكون حفظتموها. وفي الـalanine، مثلًا،
+
+100
+00:09:40,870 --> 00:09:46,810
+تكون حفظتموها. وفي الـcysteine، CH2SH، تكون تعرفونها. بالـphenyl
+
+101
+00:09:46,810 --> 00:09:51,650
+alanine، CH2 phenyl. اللي بأعطيكم إياه، بأعطيكم الـR فقط. الآن،
+
+102
+00:09:51,650 --> 00:09:57,750
+لو كان الكلام: ارسم هذا الـpeptide، كيف بدي أرسم هذا
+
+103
+00:09:57,750 --> 00:10:03,090
+الـpeptide؟ بدي آجي أحط الهيكل تبع الـpeptide. الهيكل
+
+104
+00:10:03,090 --> 00:10:07,270
+تبع الـpeptide، أربع وحدات الآن، ستكون بهذا الشكل: N-
+
+105
+00:10:07,270 --> 00:10:14,270
+CC=O. هي أول وحدة amino acid. بعدين NCC=O.
+
+106
+00:10:14,270 --> 00:10:22,920
+بعدين NCC=O. بعدين NCC=O.
+
+107
+00:10:22,920 --> 00:10:27,040
+الآن، صار عندي أربع وحدات،
+
+108
+00:10:27,040 --> 00:10:36,060
+تتخيّلوهم: هذه وحدة، اثنتان، ثلاث، أربع. واضحة الفكرة؟
+
+109
+00:10:36,060 --> 00:10:43,100
+الآن، ماذا يبقى عندي؟ المجموعة الـR اللي بتجي من الـ
+
+110
+00:10:43,100 --> 00:10:48,160
+glycine H، و
+
+111
+00:10:48,160 --> 00:10:54,070
+ماذا الـR اللي من الـalanine؟ مثلًا، ماذا الـR اللي من
+
+112
+00:10:54,070 --> 00:11:01,770
+الـcysteine؟ CH2SH. و ماذا الـR اللي من الـphenylalanine؟
+
+113
+00:11:01,770 --> 00:11:08,730
+CH2 phenyl. واضح؟ لاحظوا، إذا أنا بمجرد معرفتي الهيكل،
+
+114
+00:11:08,730 --> 00:11:13,830
+أكرره. بعد هيك، أن أستكمل الكلام، إنه هذه مثلًا NH2،
+
+115
+00:11:13,830 --> 00:11:20,010
+إنه هذه CH، إنه هذه NH، إنه هذه CH، إنه هذه NH،
+
+116
+00:11:20,010 --> 00:11:25,760
+هذه CH، عشان يكتمل الشكل العام بتاع الـOH.
+
+117
+00:11:30,660 --> 00:11:35,880
+واضح؟ OH، C-terminal. لاحظوا، بهذا الشكل بإمكاني
+
+118
+00:11:35,880 --> 00:11:41,740
+أرسم أي peptide. فالـpeptide معروف فيه هيكل كربوني
+
+119
+00:11:41,740 --> 00:11:48,460
+متكرر. الهيكل الكربوني مع النيتروجين اللي هو NCCO.
+
+120
+00:11:48,460 --> 00:11:57,450
+NCCO NCCO NCCO. الاختلاف أين؟ بالـR groups طبعًا.
+
+121
+00:11:57,450 --> 00:12:02,570
+هذا الاختلاف بيخلي الـpeptides والـproteins
+
+122
+00:12:02,570 --> 00:12:09,050
+ما يكونوش polymers حقيقيين. لابد من معرفة ماذا؟ الـ
+
+123
+00:12:09,050 --> 00:12:14,070
+sequence لهم. لابد من معرفة الـsequence، ماذا؟ تسلسلهم.
+
+124
+00:12:14,070 --> 00:12:18,670
+الآن، لو اجئت وجبت لكم سؤال، مثلًا، قلت لكم: والله، هذا
+
+125
+00:12:18,670 --> 00:12:24,710
+الـpeptide: glycine، alanine، cysteine، phenylalanine. مع هذا
+
+126
+00:12:24,710 --> 00:12:31,490
+الـpeptide، جئت بأي شيء فيه alanine، glycine، cysteine،
+
+127
+00:12:31,490 --> 00:12:35,670
+phenylalanine. أين الـalanine؟ غيّرت أي شيء. ما العلاقة بينهم؟ They
+
+128
+00:12:35,670 --> 00:12:39,470
+are structural isomers. اختلفوا في مواقع الارتباط.
+
+129
+00:12:39,470 --> 00:12:44,810
+كانت هنا، مثلًا، اللي فيها الـmethyl أعلى، ثاني وحدة، صارت
+
+130
+00:12:44,810 --> 00:12:46,690
+اللي فيها الـmethyl على الأولى، واللي فيها الـH على
+
+131
+00:12:46,690 --> 00:12:51,670
+الثانية. هذا تغير في الارتباط أم لا؟ إذًا they are
+
+132
+00:12:51,670 --> 00:12:56,830
+structural isomers. واضح؟ They are structural
+
+133
+00:12:56,830 --> 00:13:08,190
+isomers. هذه الـ
+
+134
+00:13:08,190 --> 00:13:13,190
+N-terminal، وهذه الـC-terminal. كل peptide له
+
+135
+00:13:13,190 --> 00:13:18,250
+N-terminal وله C-terminal. لما أبدأ أكتب، أكتب بهذا
+
+136
+00:13:18,250 --> 00:13:23,350
+الشكل. واضح؟ إذا ذكرنا peptide بهذا الشكل، أي واحدة
+
+137
+00:13:23,350 --> 00:13:26,230
+كان بإمكانها أن تجعل C-terminal هنا وN-terminal هنا،
+
+138
+00:13:26,230 --> 00:13:29,290
+لكننا لسنا متعودين نشتغل هكذا في الـbiochemistry، عشان
+
+139
+00:13:29,290 --> 00:13:32,210
+الكل يفهم مع بعضه.
+
+140
+00:13:49,240 --> 00:13:54,780
+لاحظوا معي، هذا الكلام يعمل شغل كثير مهمة. لو أنا
+
+141
+00:13:54,780 --> 00:14:00,160
+مثلًا، جبت بس two amino acids وبدي أخليهم يتحدوا مع
+
+142
+00:14:00,160 --> 00:14:06,160
+بعض، يعني glycine وalanine، ممكن أخليهم يتحدوا يكون
+
+143
+00:14:06,160 --> 00:14:11,610
+الـglycine في الأول، والـalanine بعده. الـglycine اللي
+
+144
+00:14:11,610 --> 00:14:16,390
+فيه H، والـalanine اللي فيه methyl. أو أخلي الـalanine في
+
+145
+00:14:16,390 --> 00:14:20,790
+الأول، والـglycine بعده. في هذه الحالة، لو أنا بدي
+
+146
+00:14:20,790 --> 00:14:26,450
+أسمي الـpeptide بشكل دقيق، أقول: الأساس تبعه، الجزء
+
+147
+00:14:26,450 --> 00:14:31,630
+الأخير اللي هو الـalanine، متصل في ماذا؟ الـglycine.
+
+148
+00:14:31,630 --> 00:14:36,980
+أعتبره على شكل مجموعة، أسميه glycyl-alanine. مرات، هذه
+
+149
+00:14:36,980 --> 00:14:43,860
+التسمية بنختصرها، بنعملها بهذا الشكل:  Gly-Ala. خلاص،
+
+150
+00:14:43,860 --> 00:14:49,040
+نمشي، بنقبلها. لكن لو بدنا نحكي بشكل دقيق: glycyl-alanine.
+
+151
+00:14:49,040 --> 00:14:55,020
+أو Gly-Ala. الآن، هذا ماذا؟ أول شيء أبدأ فيه،
+
+152
+00:14:55,020 --> 00:15:02,930
+أبدأ هكذا وأبقى ماشي. alanine-glycine. سلف، لو بدي
+
+153
+00:15:02,930 --> 00:15:08,690
+أعمل اتحاد بين اثنين مختلفين، صار عندي مش peptide
+
+154
+00:15:08,690 --> 00:15:15,170
+واحد، صار عندي اثنين. هل يا ترى هذا glycyl-alanine
+
+155
+00:15:15,170 --> 00:15:23,270
+هو نفسه alanyl-glycine؟ تأملوا فيه، هنا مثلًا الـ
+
+156
+00:15:23,270 --> 00:15:29,270
+CH3 جنب مجموعة الحامض. هنا الـH جنب مجموعة الحامض،
+
+157
+00:15:29,270 --> 00:15:32,570
+هذا اختلاف في الـbonding أم لا؟ هنا الـH جنب
+
+158
+00:15:32,570 --> 00:15:37,770
+الأمين، هنا الـCH3 جنب الأمين. إذًا، هذول
+
+159
+00:15:37,770 --> 00:15:41,410
+المجموعتين، يعني لو كنا متخيلين أن هذه H، انعكسوا
+
+160
+00:15:41,410 --> 00:15:47,460
+أم لا؟ إذًا، هذول structural isomers. فلو أجينا
+
+161
+00:15:47,460 --> 00:15:47,960
+سئلنا
+
+162
+00:16:13,350 --> 00:16:23,530
+الـglycine. واضحة هذه النقطة؟ الآن، نرجع للقصة
+
+163
+00:16:23,530 --> 00:16:30,750
+القديمة تبعتنا. لو يا ترى أجينا وخلطنا
+
+164
+00:16:34,170 --> 00:16:39,470
+الجليسين مع الألانين، إحنا بنخلط جزء واحد أم عدد
+
+165
+00:16:39,470 --> 00:16:44,070
+كبير من الجزيئات؟ عدد كبير من الجزيئات، وقلنا لهم:
+
+166
+00:16:44,070 --> 00:16:48,610
+يلا، تفاعلوا مع بعض، واعملوا لنا peptides. كم ناتج
+
+167
+00:16:48,610 --> 00:16:49,810
+نتوقع؟
+
+168
+00:16:51,890 --> 00:16:56,790
+تذكروا لما كنا نخل
+
+223
+00:21:12,960 --> 00:21:17,750
+عاملينهم إحنا ميزّينهم: الـglycine أحمر، والـ
+
+224
+00:21:17,750 --> 00:21:22,410
+alanine أزرق. هذه جزيئات كثيرة ممكن تتحد عندي
+
+225
+00:21:22,410 --> 00:21:27,290
+glycine مع glycine يعطوني بيبتايد، بده يكون إيش هو؟
+
+226
+00:21:27,290 --> 00:21:35,270
+glycine glycine. هذه H، هذه H، NCC double bond O، NCC
+
+227
+00:21:35,270 --> 00:21:39,910
+double bond O، وH، وH. يعني glycine مع glycine ممكن
+
+228
+00:21:39,910 --> 00:21:48,260
+تتحد عندي. alanine مع alanine: NCCWO، NCCWO، مثل، و مثل
+
+229
+00:21:48,260 --> 00:21:54,040
+واضح. هذا يكون أي بيبتايد؟ ألانين ألانين. ممكن تتحد
+
+230
+00:21:54,040 --> 00:22:01,180
+الآن: glycine مع الـalanine بهذا الشكل: glycine alanine.
+
+231
+00:22:01,180 --> 00:22:10,550
+NCCWO، NCCWO، الهيكلة هذه: glycine H، هذا alanine. alan
+
+232
+00:22:10,550 --> 00:22:13,470
+الاتحاد يتم بطريقة ثانية.
+
+233
+00:22:20,780 --> 00:22:28,840
+يكون بهذا الشكل: NCCWO، NCCWO، CH3HANA، و N HANA. هذا
+
+234
+00:22:28,840 --> 00:22:34,860
+إيش بده يكون؟ alanine glycine. البيبتايد الآن، انظر
+
+235
+00:22:34,860 --> 00:22:40,840
+عليهم بتأمل، هل فيهم أشياء بتشبه بعض؟ طبعاً لو
+
+236
+00:22:40,840 --> 00:22:44,760
+سألتكم: ما العلاقة بين glycine glycine والـalanine؟
+
+237
+00:22:44,760 --> 00:22:50,520
+أنا الـalanine... they are... استعملوا كلمات كيميائية.
+
+238
+00:22:50,520 --> 00:22:56,040
+they are different compounds. مركبات مختلفة، لأنّ
+
+239
+00:22:56,040 --> 00:22:59,500
+أنا H و H، وأنا مثل، ومثلَها. هذه مركبات مختلفة.
+
+240
+00:22:59,500 --> 00:23:03,700
+glycine glycine، و alanine alanine: they are different
+
+241
+00:23:03,700 --> 00:23:07,620
+compounds. لو قلت لكم: ما العلاقة بين glycine
+
+242
+00:23:07,620 --> 00:23:11,950
+glycine و glycine alanine؟ they are different
+
+243
+00:23:11,950 --> 00:23:14,570
+compounds. هنا H وهنا H، وهنا H ومثل، صيغة
+
+244
+00:23:14,570 --> 00:23:18,850
+مختلفة. كذلك الحال لو بدأت أقول: الـalanine الـalanine، و
+
+245
+00:23:18,850 --> 00:23:19,950
+الـalanine الـalanine الـalanine الـalanine الـalanine
+
+246
+00:23:19,950 --> 00:23:20,490
+الـalanine الـalanine الـalanine الـalanine الـalanine
+
+247
+00:23:20,490 --> 00:23:22,850
+الـalanine الـalanine الـalanine الـalanine الـalanine
+
+248
+00:23:22,850 --> 00:23:25,270
+الـalanine الـalanine الـalanine الـalanine الـalanine
+
+249
+00:23:25,270 --> 00:23:29,230
+الـalanine الـalanine الـalanine الـalanine الـalanine
+
+250
+00:23:29,230 --> 00:23:30,250
+الـalanine الـalanine الـalanine الـalanine الـalanine
+
+251
+00:23:30,250 --> 00:23:30,610
+الـalanine الـalanine الـalanine الـalanine الـalanine
+
+252
+00:23:30,610 --> 00:23:36,470
+الـalanine الـalanine الـalanine الـalan
+
+253
+00:23:36,500 --> 00:23:40,040
+الذرات تماماً. يعني لو حسبنا على الكمبيوتر الـ
+
+254
+00:23:40,040 --> 00:23:43,420
+molecular weight لهذا، ولهذا: same number of atoms،
+
+255
+00:23:43,420 --> 00:23:46,980
+same molecular weight. بسّ الفكرة: الاختلاف أنّ هنا
+
+256
+00:23:46,980 --> 00:23:49,920
+أجت الـH، وهنا الـCH3. هنا أجت الـCH3، وهنا الـH.
+
+257
+00:23:49,920 --> 00:23:54,400
+واضح أنّ they are different compounds. يعني هذه الـH
+
+258
+00:23:54,400 --> 00:23:58,280
+محصورة بين C double bond O و NH2، والـCH3 بين
+
+259
+00:23:58,280 --> 00:24:04,700
+acid و NH. هنا الـH بين acid و NH. واضح الاختلاف.
+
+260
+00:24:04,700 --> 00:24:09,420
+بناءً على ذلك، لو سألنا: أنّ mixing two amino acids
+
+261
+00:24:09,420 --> 00:24:16,620
+together in fact will produce four products. تمام؟
+
+262
+00:24:16,620 --> 00:24:23,300
+هيعطي أربع نواتج. طبعاً، حتصير عندنا مشكلة، حتصير
+
+263
+00:24:23,300 --> 00:24:27,640
+عندنا مشكلة. يعني لو الناس كانوا بدهم glycine
+
+264
+00:24:27,640 --> 00:24:31,660
+glycine، حيسخّنوا الـglycine مع نفسه بظروف تفاعل، يتفاعل
+
+265
+00:24:31,660 --> 00:24:37,220
+بدي alanine alanine، نفس الفكرة. لكن لو كنت بدي أحضر
+
+266
+00:24:37,220 --> 00:24:44,260
+glycine alanine، بدّي طريقة معينة. الآن، هذه الطريقة مش
+
+267
+00:24:44,260 --> 00:24:48,380
+مقبولة كيميائياً. أصدقائي، بتقولوا: اخلطوهم وافصلوهم!
+
+268
+00:24:48,380 --> 00:24:52,460
+أول شيء: إذا خلطناهم، حنطلع مش ناتجين، أربعة. أربعة
+
+269
+00:24:52,460 --> 00:24:57,660
+الآن، في كيميائي بيحطّ حاله، يقعد يفصل أربعة
+
+270
+00:24:57,660 --> 00:25:01,240
+compounds عن بعض. اللي بيدخل المختبر وبيعرف غلبة
+
+271
+00:25:01,240 --> 00:25:05,420
+الشغل، لا يمكن يعملها، لا يمكن يعملها. وبناءً على ذلك،
+
+272
+00:25:05,420 --> 00:25:14,780
+أنا فعلاً فعلاً بدّي طريقة، أطلع لي ناتج واحد فقط. يعني
+
+273
+00:25:14,780 --> 00:25:22,380
+هذه المركبات... فكّروا معي، قدّيش الكيمياء منطقها هو
+
+274
+00:25:22,380 --> 00:25:28,260
+منطق إيش؟ هو منطق الحياة... منطق الحياة، شايفين؟ هذه
+
+275
+00:25:28,260 --> 00:25:32,040
+المركبات الأربعة، أنا أخلطهم، وافترضوا أخلط من هذا
+
+276
+00:25:32,040 --> 00:25:35,420
+مليون جزيئة، ومن هذا مليون جزيئة، بدّي أفعّلهم أي
+
+277
+00:25:35,420 --> 00:25:39,460
+واحد، اللي بدّكم إيّاه أنتم، يطلع glycine alanine، يعني
+
+278
+00:25:39,460 --> 00:25:45,380
+اللي زي هيك، وفقط، واضح؟ أنا بدّي أفرجيكم كيف بدّي
+
+279
+00:25:45,380 --> 00:25:52,120
+أعملها، كإنّها لعبة، برا. ما أحكي عن إيش؟ عن الكيمياء.
+
+280
+00:25:52,120 --> 00:25:56,980
+يعني أنا بدّي أتعامل معها كإنّها لعبة، بدّي أعطي لشخص
+
+281
+00:25:56,980 --> 00:26:00,680
+معيّن هذه، وأقول له: اخلط بحيث أنّه لما تيجي تشبّكهم في
+
+282
+00:26:00,680 --> 00:26:04,660
+بعض، ما يطلع إلاّ هذا المركّب اللي أنتم طلبتوه.
+
+283
+00:26:04,660 --> 00:26:09,440
+الأحمر والأزرق، تمام؟ كلّ هذا الكلام ممكن نعمله
+
+284
+00:26:09,440 --> 00:26:13,600
+بورقة كلينكس صغيرة، إيش رأيكم؟
+
+285
+00:26:16,190 --> 00:26:21,210
+ورقة كلينكس الصغيرة، إيش اللي بدّنا نعمله؟ إحنا بنيجي
+
+286
+00:26:21,210 --> 00:26:26,590
+هذا بنعمله protection، من هنا بنعمله حماية، من هنا
+
+287
+00:26:26,590 --> 00:26:30,910
+ممنوع أن تتفاعل. بدّنا إياه يتفاعل من الـnitrogen.
+
+288
+00:26:30,910 --> 00:26:34,090
+سكرنا مجموعة الحامض، عشان ما يجي هذا يتفاعل معه من
+
+289
+00:26:34,090 --> 00:26:39,510
+هنا. لاحظوا، هذا الغلبان جاي يتفاعل معه، راضي يتفاعل؟
+
+290
+00:26:39,510 --> 00:26:43,950
+شوفوا، قبل الـprotection، قبل الحماية، لو هذا يجي
+
+291
+00:26:43,950 --> 00:26:50,400
+يتفاعل، كان بتفاعل. الآن، بعد ما عملت الـprotection،
+
+292
+00:26:50,400 --> 00:26:57,800
+أجا يتفاعل، مش قادر يتفاعل، سكّرت هذا الجزء. إذاً، بجعل
+
+293
+00:26:57,800 --> 00:27:02,880
+كلّ هذه بعمل protection للـacid، بإضافة مجموعة
+
+294
+00:27:02,880 --> 00:27:07,460
+كيميائية، اتسَكّر هذا الجزء، هذا بطّل يتفاعل من هنا.
+
+295
+00:27:07,460 --> 00:27:13,820
+ممتاز. لسه عندي خوف أنّ هذه يتفاعلوا مع بعض، الآن
+
+296
+00:27:13,820 --> 00:27:18,800
+هذه، هدين يتفاعلوا مع بعض. أنا منعت نصّ المشكلة، الآن
+
+297
+00:27:18,800 --> 00:27:23,530
+هذا من وين بدّي أمنعه يتفاعل؟ من الـnitrogen، باجي
+
+298
+00:27:23,530 --> 00:27:27,350
+بعمله protection من الطرف الثاني، عشان ما يقدرش
+
+299
+00:27:27,350 --> 00:27:35,050
+يتفاعل منها. أنا بنعمله شوية protection برضه، هذه
+
+300
+00:27:35,050 --> 00:27:40,270
+بأمل أنّ تكون عملية الـprotection هذه ضبطت.
+
+301
+00:27:40,270 --> 00:27:41,670
+استعمل
+
+302
+00:27:46,120 --> 00:27:51,860
+بهمّش أنتم، في النهاية، تصلّكم الفكرة أنّ الكيميائي
+
+303
+00:27:51,860 --> 00:27:57,980
+والبني آدم، والطبيب، لما بده يفكّر بحالة، مشكلة، بده
+
+304
+00:27:57,980 --> 00:28:01,620
+يكون عنده أصول العلم، لكن بده يفكّر بمنطق الدنيا،
+
+305
+00:28:01,620 --> 00:28:06,320
+بمنطق الدنيا. يعني إليزاروف، إليزاروف، لما عمل
+
+306
+00:28:06,320 --> 00:28:11,040
+العملية الجراحية تبعته، اللي بطوّل فيها عظام الساق
+
+307
+00:28:11,040 --> 00:28:15,320
+للناس اللي عندهم ساق أطول من الثانية، اللي فكّر فيه
+
+308
+00:28:15,320 --> 00:28:20,420
+أنّه يجي على العظمة، يجسّرْها، ويحطّ حديد هنا وهنا، و
+
+309
+00:28:20,420 --> 00:28:25,040
+صار كل ساعتين يطوّل نصف مليمتر، نصف مليمتر، لأنّه ما يقدرش يسحب كلّ
+
+310
+00:28:25,040 --> 00:28:29,780
+شيء، عظامه، أعصابه، شيء مرة واحدة. عمداً، أسبوعين بيضلّوا
+
+311
+00:28:29,780 --> 00:28:34,020
+يسحب يسحب، أو بيطول العظمة كده؟ سبعة، ثمانية سنتي،
+
+312
+00:28:34,020 --> 00:28:40,840
+بيعمل مسافَر. عملية شهيرة جداً، الـإليزاروف. الآن،
+
+313
+00:28:40,840 --> 00:28:45,720
+الظروف، شابّ تبع البسكليتات، كيف بيشتغلوا، بعمل العجال،
+
+314
+00:28:45,720 --> 00:28:51,380
+وأخذ منه فكرة، كيف يعمل العملية. واضحة الفكرة؟ الآن
+
+315
+00:28:51,380 --> 00:28:58,120
+هذه، أنا عملت protection هنا للـacid part، وهنا للـ
+
+316
+00:28:58,120 --> 00:29:03,320
+amino part، أنّه مش قادر يتفاعل من عند الـnitrogen.
+
+317
+00:29:03,320 --> 00:29:09,740
+الآن بدّي أخلطهم، وأقول لهم: تفاعلوا زي ما بدّكم. هيجي
+
+318
+00:29:09,740 --> 00:29:14,060
+يتفاعلوا. أول شيء، هذا هيجي يتفاعل من هنا، هيلاجي إيش؟
+
+319
+00:29:14,060 --> 00:29:18,880
+أمسكّر الـnitrogen تبعته من هنا، أمسكّر الـnitrogen
+
+320
+00:29:18,880 --> 00:29:24,180
+هذا، هيجي يتفاعل مع هذا، أمسكّر الـCO. هذا يتفاعل مع
+
+321
+00:29:24,180 --> 00:29:29,620
+هذا، أمسكّر الـCO. لغاية كلّ هذه التفاعلات، الآن هذا
+
+322
+00:29:29,620 --> 00:29:36,820
+بيجي يتفاعل مع هذا، أمسكّر. هذا بيجي يتفاعل مع هذا،
+
+323
+00:29:38,200 --> 00:29:45,500
+طلعت one product، شوف كيف... هايوة، one product، هيك
+
+324
+00:29:45,500 --> 00:29:50,500
+ممكن... الآن هيك، مش ممكن اثنين أزرق، مش ممكن اثنين
+
+325
+00:29:50,500 --> 00:29:55,500
+حمر، مش ممكن. هذه الفكرة هي اللي عملوها. الآن، كلّ اللي
+
+326
+00:29:55,500 --> 00:29:59,500
+بدّنا نعمله، أنّ بدّنا نكتب في المعادلة، حطّوا هنا حرف
+
+327
+00:29:59,500 --> 00:30:04,520
+PG، إيش يعني PG؟ يعني protecting group. لما تكونوا
+
+328
+00:30:04,520 --> 00:30:08,000
+عملوا هذا protected، أو عملوا هذا protected، لما
+
+329
+00:30:08,000 --> 00:30:12,140
+تشوفوا الـPG، يعني من هنا ممنوع تتفاعل. مجموعة
+
+330
+00:30:12,140 --> 00:30:16,120
+كيميائية صغيرة، بنضيفها، بتخلي هذا مثبت، ما بتفعلش، مش
+
+331
+00:30:16,120 --> 00:30:21,980
+ندخل بتفاصيل أكثر من هي، وجدها، ما عندي إلاّ هذه
+
+332
+00:30:21,980 --> 00:30:25,780
+الإمكانية، نشتغل. هذا مش هيقدر يتفاعل مع نفسه، ولا هذا
+
+333
+00:30:25,780 --> 00:30:29,400
+حيتفاعل مع نفسه، هذا حيتفاعل مع هذا، بسّ one product.
+
+334
+00:30:29,400 --> 00:30:37,260
+طلعت الـglycine alanine. واضحة الفكرة؟ وهذا هو اللي
+
+335
+00:30:37,260 --> 00:30:38,220
+موجود، يمكن
+
+336
+00:30:40,820 --> 00:30:45,960
+في الـslide، يمكن متأخّرة عندكم، أربع، خمس slides.
+
+337
+00:30:45,960 --> 00:30:52,520
+لاحظوا، هذه جاب amino acid one، سماّه، وعمل protection
+
+338
+00:30:52,520 --> 00:30:58,740
+لمجموعة معيّنة، وجاب الـamino acid two، وعمل
+
+339
+00:30:58,740 --> 00:31:02,620
+protection لمجموعة ثانية. نفس الفكرة اللي إحنا
+
+340
+00:31:02,620 --> 00:31:06,280
+حكيناها، الآن هذا بطّل يتفاعل من هنا، هذا بتفاعلش من
+
+341
+00:31:06,280 --> 00:31:10,850
+هنا، ما فيش غير هذا الجزء مع هذا الجزء، بده يتفاعل.
+
+342
+00:31:10,850 --> 00:31:17,010
+فبدل ما أطلع four different compounds، بطلّع one.
+
+343
+00:31:17,010 --> 00:31:22,230
+طبعاً، في هذه الحالة، حين، طلعت بيبتايد. الآن، بعد ما
+
+344
+00:31:22,230 --> 00:31:26,090
+طلعته، بتفاعل كيميائي بسيط، بقدر أشيل هذا الـ
+
+345
+00:31:26,090 --> 00:31:30,730
+protection، أو هذا الـprotection. الآن، تخيّلوا لو كنا
+
+346
+00:31:30,730 --> 00:31:35,910
+بدّنا نطوّل الـpeptide، يعني مش بسّ اثنين، بدّي من هنا ما
+
+347
+00:31:35,910 --> 00:31:41,370
+يتفاعل، بشيل هذا الـprotection، بدّي من هنا يتفاعل.
+
+348
+00:31:41,370 --> 00:31:50,370
+بشيل هذا، وبجيب له amino acid، الـnitrogen تبعته not
+
+349
+00:31:50,370 --> 00:31:53,430
+protected، والـacid protected، عشان ما يتفاعلش مع
+
+350
+00:31:53,430 --> 00:31:58,150
+بعضه. اللي جاي جديد، بيجي يتفاعل هنا. واحد، اثنين، ثلاثة،
+
+351
+00:31:58,150 --> 00:32:03,270
+أربعة. ممكن في الآخر يتحضّروا خمسة عشر، وعشرين، و
+
+352
+00:32:03,270 --> 00:32:09,540
+ثلاثين، جدّ ما بدّكم، وبالترتيب، بالترتيب بتحضّروه، تمام؟
+
+353
+00:32:09,540 --> 00:32:13,220
+هذا
+
+354
+00:32:13,220 --> 00:32:20,160
+الكلام كلّه موجود. ثانية، أخدها، لحظوا
+
+355
+00:32:20,160 --> 00:32:27,460
+على سبيل المثال، هذه مركّب، تخيّلوا هذا عملوا له
+
+356
+00:32:27,460 --> 00:32:28,100
+sequencing.
+
+357
+00:32:31,070 --> 00:32:35,610
+عرفوا تفاصيله. حنشوف طبعاً كيف، بعد شوية، بنحلّل المركّب،
+
+358
+00:32:35,610 --> 00:32:39,050
+نعرف الـamino acids: glycine، leucine، valine،
+
+359
+00:32:39,050 --> 00:32:44,870
+glutamic acid، وهكذا. هذا الإنسولين، هذا الإنسولين
+
+360
+00:32:44,870 --> 00:32:51,030
+سلسلتين من إيش؟ الـpeptides. بيحلّلوه، بيعرفوه، واحد
+
+361
+00:32:51,030 --> 00:32:58,130
+واحد. لاحظوا، ما بنقدرش زي السكر، نعمل إيش شغلة، to the
+
+362
+00:32:58,130 --> 00:33:02,700
+end. لأ، في إيش اسمه؟ sequencing في الـ... peptides، وفي
+
+363
+00:33:02,700 --> 00:33:08,000
+الأنسولين. هذه، هذا المركّب، الراجل اللي حضّره، أخذ عليه
+
+364
+00:33:08,000 --> 00:33:13,600
+جائزة نوبل في الكيمياء، سنة الخمسة وخمسين. هذا
+
+365
+00:33:13,600 --> 00:33:22,780
+Vincent du Vigneaud، أخذ عليه جائزة نوبل. هذا هرمون من
+
+366
+00:33:22,780 --> 00:33:29,310
+تسعة أمينو أسيد، حضّرهم من مرتّبين. cysteine، tyrosine،
+
+367
+00:33:29,310 --> 00:33:33,030
+isoleucine، كذا، aspartic acid، cysteine، proline، leucine، glycine،
+
+368
+00:33:33,030 --> 00:33:37,750
+أعدّهم: واحد، اثنين، ثلاثة، أربعة، خمسة، ستة، سبعة، ثمانية،
+
+369
+00:33:37,750 --> 00:33:42,970
+تسعة. هنا في S و S، ارتبطوا مع بعض. مش موضوعنا، نأخذ
+
+370
+00:33:42,970 --> 00:33:46,630
+الـdisulfide bond، بسّ هذه كمّ أمينو أسيد في المحصلة؟
+
+371
+00:33:46,630 --> 00:33:52,590
+واحد، اثنين، ثلاثة، أربعة، خمسة، ستة، سبعة، ثمانية، تسعة.
+
+372
+00:33:52,590 --> 00:33:59,330
+حضّرهم من مرتّبين، بهذه الطريقة، واضح؟ هذا عبارة عن
+
+373
+00:33:59,330 --> 00:34:05,790
+هرمون اسمه oxytocin. ما مرّ عليكم؟ هرمون السعادة، الله
+
+374
+00:34:05,790 --> 00:34:11,380
+يسعدكم! الناس بيسمّوه هرمون السعادة، فعلاً، ليش؟ لأنّهم
+
+375
+00:34:11,380 --> 00:34:14,640
+اتّبعوا علم النفس، وغيره، بيقولوا هذا اللي بتحكّم
+
+376
+00:34:14,640 --> 00:34:19,440
+بالانفعالات، وقصص السعادة، والحب، وكلّ شيء، مرتبط بهذا
+
+377
+00:34:19,440 --> 00:34:24,160
+الهرمون. طبعاً، له تطبيقات ثانية... له تطبيقات
+
+378
+00:34:24,160 --> 00:34:28,720
+ثانية. هو في الأصل بيطلع من الـposterior pituitary
+
+379
+00:34:28,720 --> 00:34:33,060
+gland، يمكن بتسمّوها الغدّة النخامية، ولا إيش... هذا
+
+380
+00:34:33,060 --> 00:34:40,320
+بتحكّم في قبضات الرحم، في لحظة الولادة. it regulates
+
+381
+00:34:40,320 --> 00:34:46,560
+uterine contraction and lactation، وفي الرضاعة. may
+
+382
+00:34:46,560 --> 00:34:49,360
+be administered... إيش معنى administered في لغة
+
+383
+00:34:49,360 --> 00:34:54,800
+العلم الطبي؟ يُعطى كعلاج، أو يُوصف، واضح؟ when it is
+
+384
+00:34:54,800 --> 00:34:58,440
+necessary to induce labor at childbirth، يعني عشان
+
+385
+00:34:58,440 --> 00:35:03,75
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/V8hlE7JcPsU_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/V8hlE7JcPsU_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..24f87d661cfc52e7037ffd82aaf3ae6e0264bcb8
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/V8hlE7JcPsU_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4056, "start": 18.36, "end": 40.56, "text": "بسم الله الرحمن الرحيم المرة الماضية بدنا نتكلم في موضوع البروتينات وكان الأساس ان نتعرف على الأحماض الأمينية ال amino acids اتعرفنا عليهم و اتعرفنا طبعا كيف بيكونوا بالوسط الحامض أو القاعدى كيف بتتأثر الشحنة تبعتهم", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 47525, 8315, 8717, 2655, 4117, 19528, 8978, 3714, 2407, 11242, 45367, 2423, 26890, 35473, 9957, 9307, 4032, 41361, 16247, 3794, 32277, 16472, 8717, 2655, 3615, 28480, 15844, 16247, 35571, 46958, 16247, 2304, 9957, 10632, 2423, 24674, 21667, 1975, 2655, 3615, 28480, 8315, 25894, 16095, 4032, 1975, 2655, 3615, 28480, 8315, 23032, 3555, 3615, 995, 9122, 33911, 4724, 1829, 30544, 14407, 20666, 41779, 9566, 21542, 10943, 11242, 34051, 25062, 995, 22488, 7578, 9122, 33911, 39894, 2655, 10721, 49115, 25124, 5016, 1863, 3660, 6055, 3555, 34268, 16095], "avg_logprob": -0.09726562812924384, 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356.72, "end": 356.88, "word": " في", "probability": 0.8671875}, {"start": 356.88, "end": 357.06, "word": " هذه", "probability": 0.947265625}, {"start": 357.06, "end": 357.46, "word": " الحالة", "probability": 0.9890950520833334}, {"start": 357.46, "end": 358.32, "word": " تخصيصا", "probability": 0.9881184895833334}], "temperature": 1.0}, {"id": 15, "seek": 38717, "start": 359.05, "end": 387.17, "text": "ببتايت بوند فلو قلنا مثلا سؤال ببتايت بوند is an amide bond طبعا هي امد see double bond O and H طبعا هيكون فيها كل خواص الامدز انه هتكون هذه المنطقة كامد reactive ولا unreactive unreactive احنا قلنا الكلمة الأساسية المميزة للامدز they are unreactive", "tokens": [3555, 3555, 2655, 995, 36081, 4724, 11536, 3215, 6156, 1211, 2407, 12174, 1211, 8315, 50113, 15040, 8608, 33604, 6027, 4724, 3555, 2655, 995, 36081, 4724, 11536, 3215, 307, 364, 669, 482, 6086, 23032, 3555, 3615, 995, 39896, 1975, 2304, 3215, 536, 3834, 6086, 422, 293, 389, 23032, 3555, 3615, 995, 39896, 30544, 8978, 11296, 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المتكررة", "tokens": [2407, 3224, 15730, 25724, 11622, 38207, 16247, 9778, 13546, 4724, 1829, 30544, 1975, 1829, 14709, 2423, 5954, 14709, 6156, 7649, 995, 5296, 15042, 4724, 16254, 1975, 25957, 1211, 41781, 482, 8608, 2407, 16606, 3714, 30544, 9154, 36764, 24401, 1975, 2407, 1975, 2655, 1863, 9957, 1975, 2407, 6055, 1211, 9307, 3660, 1975, 2407, 1975, 25513, 27884, 1975, 2407, 16490, 2304, 3794, 3660, 24674, 21667, 8608, 3224, 1211, 10874, 28259, 11203, 25528, 4724, 16254, 1975, 25957, 1211, 426, 14709, 4032, 4724, 16254, 1975, 25957, 1211, 383, 14709, 2423, 7649, 19446, 2423, 2407, 24401, 3660, 9673, 2655, 37983, 25720], "avg_logprob": -0.18218427835051546, "compression_ratio": 1.7227722772277227, "no_speech_prob": 0.0, "words": [{"start": 504.22, "end": 504.9, "word": "وهذا", "probability": 0.7513020833333334}, {"start": 504.9, "end": 505.36, "word": " الجزء", "probability": 0.9718424479166666}, {"start": 505.36, "end": 505.86, "word": " الأخير", "probability": 0.81982421875}, 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"probability": 0.96240234375}, {"start": 648.6, "end": 648.8, "word": " R", "probability": 0.951171875}, {"start": 648.8, "end": 648.98, "word": " اللى", "probability": 0.968994140625}, {"start": 648.98, "end": 649.16, "word": " من", "probability": 0.99072265625}, {"start": 649.16, "end": 649.94, "word": " القلانين", "probability": 0.8160400390625}, {"start": 649.94, "end": 650.92, "word": " مثل", "probability": 0.97900390625}], "temperature": 1.0}, {"id": 28, "seek": 68089, "start": 652.55, "end": 680.89, "text": "و إيش ال R اللي من الستين؟ CH2SH و إيش ال R اللي من الفن الألانين؟ CH2 فنل واضح؟ لحظوا إذا أنا مجرد معرفتي الهيكل بكرره بعد هيك أن أستكمل الكلام إنه هذه مثلا NH2، إنه هذه CH إنه هذه NH1، إنه هذه CH، إنه هذه NH، هذه CH", "tokens": [2407, 11933, 1829, 8592, 2423, 497, 13672, 1829, 9154, 2423, 14851, 9957, 22807, 5995, 17, 17308, 4032, 11933, 1829, 8592, 2423, 497, 13672, 1829, 9154, 27188, 1863, 16247, 1211, 7649, 9957, 22807, 5995, 17, 6156, 1863, 1211, 4032, 46958, 5016, 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"end": 654.91, "word": " الستين؟", "probability": 0.57818603515625}, {"start": 654.91, "end": 657.77, "word": " CH2SH", "probability": 0.8053385416666666}, {"start": 657.77, "end": 658.53, "word": " و", "probability": 0.76220703125}, {"start": 658.53, "end": 658.81, "word": " إيش", "probability": 0.9129231770833334}, {"start": 658.81, "end": 658.97, "word": " ال", "probability": 0.96728515625}, {"start": 658.97, "end": 659.17, "word": " R", "probability": 0.97705078125}, {"start": 659.17, "end": 659.35, "word": " اللي", "probability": 0.97412109375}, {"start": 659.35, "end": 659.53, "word": " من", "probability": 0.9931640625}, {"start": 659.53, "end": 659.87, "word": " الفن", "probability": 0.85986328125}, {"start": 659.87, "end": 661.77, "word": " الألانين؟", "probability": 0.7559326171875}, {"start": 661.77, "end": 662.93, "word": " CH2", "probability": 0.97998046875}, {"start": 662.93, "end": 664.19, "word": " فنل", "probability": 0.6944580078125}, {"start": 664.19, "end": 665.77, "word": " واضح؟", "probability": 0.8427734375}, {"start": 665.77, "end": 666.47, "word": " لحظوا", "probability": 0.7430419921875}, {"start": 666.47, "end": 667.03, "word": " إذا", "probability": 0.6845703125}, {"start": 667.03, "end": 667.29, "word": " أنا", "probability": 0.85205078125}, {"start": 667.29, "end": 667.73, "word": " مجرد", "probability": 0.9912109375}, {"start": 667.73, "end": 668.21, "word": " معرفتي", "probability": 0.9220377604166666}, {"start": 668.21, "end": 668.73, "word": " الهيكل", "probability": 0.8974609375}, {"start": 668.73, "end": 669.41, "word": " بكرره", "probability": 0.92578125}, {"start": 669.41, "end": 669.97, "word": " بعد", "probability": 0.86962890625}, {"start": 669.97, "end": 670.31, "word": " هيك", "probability": 0.94921875}, {"start": 670.31, "end": 670.49, "word": " أن", "probability": 0.58056640625}, {"start": 670.49, "end": 671.21, "word": " أستكمل", "probability": 0.8914794921875}, {"start": 671.21, "end": 671.69, "word": " الكلام", "probability": 0.96337890625}, {"start": 671.69, "end": 671.93, "word": " إنه", "probability": 0.4627685546875}, {"start": 671.93, "end": 672.17, "word": " هذه", "probability": 0.50341796875}, {"start": 672.17, "end": 672.71, "word": " مثلا", "probability": 0.926513671875}, {"start": 672.71, "end": 673.83, "word": " NH2،", "probability": 0.5883382161458334}, {"start": 673.83, "end": 673.95, "word": " إنه", "probability": 0.813720703125}, {"start": 673.95, "end": 674.19, "word": " هذه", "probability": 0.80810546875}, {"start": 674.19, "end": 674.77, "word": " CH", "probability": 0.880859375}, {"start": 674.77, "end": 675.39, "word": " إنه", "probability": 0.6851806640625}, {"start": 675.39, "end": 675.61, "word": " هذه", "probability": 0.88525390625}, {"start": 675.61, "end": 676.85, "word": " NH1،", "probability": 0.8014322916666666}, {"start": 676.85, "end": 676.99, "word": " إنه", "probability": 0.942138671875}, {"start": 676.99, "end": 677.23, "word": " هذه", "probability": 0.9375}, {"start": 677.23, "end": 677.99, "word": " CH،", "probability": 0.9228515625}, {"start": 677.99, "end": 678.13, "word": " إنه", "probability": 0.947265625}, {"start": 678.13, "end": 678.33, "word": " هذه", "probability": 0.93408203125}, {"start": 678.33, "end": 680.01, "word": " NH،", "probability": 0.916015625}, {"start": 680.01, "end": 680.27, "word": " هذه", "probability": 0.446533203125}, {"start": 680.27, "end": 680.89, "word": " CH", "probability": 0.970703125}], "temperature": 1.0}, {"id": 29, "seek": 68576, "start": 681.26, "end": 685.76, "text": "عشان يكتمل الشكل العام بتاع الـ OH", "tokens": [3615, 8592, 7649, 7251, 4117, 39237, 1211, 25124, 28820, 18863, 10943, 39894, 45761, 2423, 39184, 13931], "avg_logprob": -0.35546875, "compression_ratio": 1.0169491525423728, "no_speech_prob": 0.0, "words": [{"start": 681.26, "end": 681.72, "word": "عشان", "probability": 0.9217122395833334}, {"start": 681.72, "end": 682.98, "word": " يكتمل", "probability": 0.8670654296875}, {"start": 682.98, "end": 684.58, "word": " الشكل", "probability": 0.9345703125}, {"start": 684.58, "end": 685.0, "word": " العام", "probability": 0.97900390625}, {"start": 685.0, "end": 685.26, "word": " بتاع", "probability": 0.7900390625}, {"start": 685.26, "end": 685.48, "word": " الـ", "probability": 0.44970703125}, {"start": 685.48, "end": 685.76, "word": " OH", "probability": 0.1915283203125}], "temperature": 1.0}, {"id": 30, "seek": 71494, "start": 690.66, "end": 714.94, "text": "واضح؟ OH أسد تيرمينال لاحظوا بهذا الشكل بإمكاني أرسم أي بيبتايد فالبيبتايد معروف فيه هيكل كربوني متكرر الهيكل الكربوني مع النيتروجين اللي هو NCCOO NCCOO NCCOO NCCOO الاختلاف وين؟", "tokens": [2407, 46958, 5016, 22807, 13931, 5551, 3794, 3215, 6055, 13546, 2304, 9957, 6027, 20193, 5016, 19913, 14407, 39627, 15730, 25124, 28820, 4724, 28814, 2304, 41361, 1829, 5551, 2288, 38251, 36632, 4724, 1829, 3555, 2655, 995, 25708, 6156, 6027, 21292, 3555, 2655, 995, 25708, 20449, 32887, 5172, 8978, 3224, 39896, 28820, 9122, 25513, 11536, 1829, 44650, 37983, 2288, 2423, 3224, 1829, 28820, 33251, 25513, 11536, 1829, 20449, 2423, 22653, 2655, 2288, 29245, 9957, 13672, 1829, 31439, 426, 11717, 46, 46, 426, 11717, 46, 46, 426, 11717, 46, 46, 426, 11717, 46, 46, 2423, 47283, 2655, 15040, 5172, 4032, 9957, 22807], "avg_logprob": -0.244687502682209, "compression_ratio": 1.7485714285714287, "no_speech_prob": 0.0, "words": [{"start": 690.66, "end": 691.6, "word": "واضح؟", "probability": 0.82049560546875}, {"start": 691.6, "end": 691.84, "word": " OH", "probability": 0.6298828125}, {"start": 691.84, "end": 692.36, "word": " أسد", "probability": 0.4862060546875}, {"start": 692.36, "end": 692.82, "word": " تيرمينال", "probability": 0.83564453125}, {"start": 692.82, "end": 693.68, "word": " لاحظوا", "probability": 0.7554931640625}, {"start": 693.68, "end": 694.46, "word": " بهذا", "probability": 0.944580078125}, {"start": 694.46, "end": 695.02, "word": " الشكل", "probability": 0.993896484375}, {"start": 695.02, "end": 695.88, "word": " بإمكاني", "probability": 0.97138671875}, {"start": 695.88, "end": 696.24, "word": " أرسم", "probability": 0.7589518229166666}, {"start": 696.24, "end": 696.46, "word": " أي", "probability": 0.6572265625}, {"start": 696.46, "end": 697.4, "word": " بيبتايد", "probability": 0.8871256510416666}, {"start": 697.4, "end": 698.66, "word": " فالبيبتايد", "probability": 0.8793247767857143}, {"start": 698.66, "end": 699.4, "word": " معروف", "probability": 0.98388671875}, {"start": 699.4, "end": 700.28, "word": " فيه", "probability": 0.56591796875}, {"start": 700.28, "end": 700.74, "word": " هيكل", "probability": 0.955078125}, {"start": 700.74, "end": 701.74, "word": " كربوني", "probability": 0.9619140625}, {"start": 701.74, "end": 703.04, "word": " متكرر", "probability": 0.9734700520833334}, {"start": 703.04, "end": 704.04, "word": " الهيكل", "probability": 0.8443603515625}, {"start": 704.04, "end": 704.7, "word": " الكربوني", "probability": 0.982177734375}, {"start": 704.7, "end": 704.84, "word": " مع", "probability": 0.99462890625}, {"start": 704.84, "end": 705.58, "word": " النيتروجين", "probability": 0.778564453125}, {"start": 705.58, "end": 705.72, "word": " اللي", "probability": 0.5888671875}, {"start": 705.72, "end": 705.96, "word": " هو", "probability": 0.9755859375}, {"start": 705.96, "end": 708.46, "word": " NCCOO", "probability": 0.4517822265625}, {"start": 708.46, "end": 710.2, "word": " NCCOO", "probability": 0.75567626953125}, {"start": 710.2, "end": 711.74, "word": " NCCOO", "probability": 0.863525390625}, {"start": 711.74, "end": 713.1, "word": " NCCOO", "probability": 0.82220458984375}, {"start": 713.1, "end": 714.34, "word": " الاختلاف", "probability": 0.871337890625}, {"start": 714.34, "end": 714.94, "word": " وين؟", "probability": 0.72412109375}], "temperature": 1.0}, {"id": 31, "seek": 74277, "start": 715.75, "end": 742.77, "text": "بال R groups طبعا هذا الاختلاف بيخلي ال peptides و ال proteins مايكونوش polymers حقيقيين لابد من معرفة إيش ال sequence لهم لابد من معرفة ال sequence إيش تسلسلهم الآن لو إجيت جبتلكوا سؤال مثلا قلتلكوا والله هذا ال peptide يجلسين قلانين سستين فين القلانين؟", "tokens": [3555, 6027, 497, 3935, 23032, 3555, 3615, 995, 23758, 2423, 47283, 2655, 15040, 5172, 4724, 1829, 9778, 20292, 2423, 41781, 1875, 4032, 2423, 15577, 19446, 1829, 30544, 2407, 8592, 6754, 18552, 11331, 38436, 38436, 9957, 5296, 16758, 3215, 9154, 20449, 28480, 3660, 11933, 1829, 8592, 2423, 8310, 5296, 16095, 5296, 16758, 3215, 9154, 20449, 28480, 3660, 2423, 8310, 11933, 1829, 8592, 6055, 3794, 1211, 3794, 1211, 16095, 6024, 48506, 45164, 11933, 7435, 36081, 10874, 3555, 2655, 23275, 14407, 8608, 33604, 6027, 50113, 15040, 12174, 1211, 2655, 23275, 14407, 16070, 43761, 23758, 2423, 41781, 482, 7251, 7435, 1211, 3794, 9957, 12174, 1211, 7649, 9957, 8608, 14851, 9957, 8978, 1863, 25062, 1211, 7649, 9957, 22807], "avg_logprob": -0.2150493367460736, "compression_ratio": 1.7521367521367521, "no_speech_prob": 0.0, "words": 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723.77, "word": " مايكونوش", "probability": 0.89765625}, {"start": 723.77, "end": 724.51, "word": " polymers", "probability": 0.7098388671875}, {"start": 724.51, "end": 725.51, "word": " حقيقيين", "probability": 0.9407958984375}, {"start": 725.51, "end": 726.47, "word": " لابد", "probability": 0.9158528645833334}, {"start": 726.47, "end": 726.67, "word": " من", "probability": 0.98974609375}, {"start": 726.67, "end": 727.29, "word": " معرفة", "probability": 0.99560546875}, {"start": 727.29, "end": 727.77, "word": " إيش", "probability": 0.7760416666666666}, {"start": 727.77, "end": 729.05, "word": " ال", "probability": 0.888671875}, {"start": 729.05, "end": 729.85, "word": " sequence", "probability": 0.97216796875}, {"start": 729.85, "end": 730.53, "word": " لهم", "probability": 0.7330322265625}, {"start": 730.53, "end": 731.43, "word": " لابد", "probability": 0.8655598958333334}, {"start": 731.43, "end": 731.57, "word": " من", "probability": 0.9921875}, {"start": 731.57, "end": 732.15, "word": " معرفة", "probability": 0.9967447916666666}, {"start": 732.15, "end": 732.57, "word": " ال", "probability": 0.78173828125}, {"start": 732.57, "end": 733.05, "word": " sequence", "probability": 0.98974609375}, {"start": 733.05, "end": 733.29, "word": " إيش", "probability": 0.93017578125}, {"start": 733.29, "end": 734.07, "word": " تسلسلهم", "probability": 0.951171875}, {"start": 734.07, "end": 734.89, "word": " الآن", "probability": 0.6968994140625}, {"start": 734.89, "end": 735.29, "word": " لو", "probability": 0.9677734375}, {"start": 735.29, "end": 735.59, "word": " إجيت", "probability": 0.6018880208333334}, {"start": 735.59, "end": 736.09, "word": " جبتلكوا", "probability": 0.88505859375}, {"start": 736.09, "end": 736.59, "word": " سؤال", "probability": 0.9881184895833334}, {"start": 736.59, "end": 737.13, "word": " مثلا", "probability": 0.99169921875}, {"start": 737.13, "end": 737.93, "word": " قلتلكوا", "probability": 0.8181640625}, {"start": 737.93, "end": 738.25, 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اللي فيها المثل على الأولى و اللي فيها الأتش على التانية", "tokens": [2304, 3615, 23758, 2423, 39184, 494, 662, 482, 10874, 46152, 2655, 36632, 44049, 38207, 8978, 3224, 5551, 1211, 7649, 9957, 11933, 1829, 7435, 20292, 3794, 9957, 8608, 1829, 14851, 9957, 8978, 1863, 16247, 1211, 7649, 9957, 22807, 32771, 13546, 2655, 36632, 44049, 38207, 19446, 18863, 15040, 28671, 49374, 16095, 22807, 436, 366, 15067, 307, 298, 433, 1975, 46456, 46538, 14407, 8978, 3714, 14407, 4587, 3615, 2423, 9640, 2655, 3555, 41193, 25961, 2655, 34105, 50113, 15040, 13672, 1829, 8978, 11296, 9673, 12984, 1211, 5551, 3615, 23942, 6055, 7649, 1829, 4032, 24401, 3660, 20328, 9640, 2655, 13672, 1829, 8978, 11296, 9673, 12984, 1211, 15844, 16247, 12610, 7578, 4032, 13672, 1829, 8978, 11296, 16247, 2655, 8592, 15844, 16712, 7649, 10632], "avg_logprob": -0.20934851278187866, "compression_ratio": 1.8855932203389831, "no_speech_prob": 0.0, "words": [{"start": 743.81, "end": 744.33, "word": "مع", "probability": 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وهنا اثل لان هدول متماثلات", "tokens": [34, 422, 422, 383, 422, 422, 6024, 48506, 8032, 3215, 12610, 9673, 7435, 2304, 34268, 9957, 13672, 1829, 8032, 2304, 47525, 2407, 7251, 1829, 7435, 1829, 10874, 1863, 3555, 16095, 50113, 1211, 1975, 2407, 1975, 12984, 1211, 4724, 5172, 2288, 4587, 8592, 1975, 15730, 1975, 1829, 7435, 2655, 34105, 50113, 1211, 37037, 8315, 1975, 12984, 1211, 1975, 2407, 34105, 50113, 1211, 37037, 8315, 1975, 12984, 1211, 5296, 7649, 8032, 3215, 12610, 44650, 2304, 5718, 104, 1211, 9307], "avg_logprob": -0.2542067426137435, "compression_ratio": 1.8203125, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1142.33, "end": 1142.85, "word": "C", "probability": 0.59814453125}, {"start": 1142.85, "end": 1143.37, "word": " O", "probability": 0.2763671875}, {"start": 1143.37, "end": 1145.07, "word": " O", "probability": 0.91796875}, {"start": 1145.07, "end": 1146.05, "word": " C", "probability": 0.77197265625}, {"start": 1146.05, "end": 1146.27, "word": " O", 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اثل", "probability": 0.9012044270833334}, {"start": 1153.95, "end": 1154.99, "word": " بفرقش", "probability": 0.7689453125}, {"start": 1154.99, "end": 1155.27, "word": " اذا", "probability": 0.556396484375}, {"start": 1155.27, "end": 1155.69, "word": " ايجت", "probability": 0.74884033203125}, {"start": 1155.69, "end": 1155.93, "word": " هنا", "probability": 0.9306640625}, {"start": 1155.93, "end": 1156.47, "word": " مثل", "probability": 0.865478515625}, {"start": 1156.47, "end": 1156.77, "word": " وهنا", "probability": 0.767578125}, {"start": 1156.77, "end": 1157.39, "word": " اثل", "probability": 0.9768880208333334}, {"start": 1157.39, "end": 1157.81, "word": " او", "probability": 0.955078125}, {"start": 1157.81, "end": 1158.07, "word": " هنا", "probability": 0.88818359375}, {"start": 1158.07, "end": 1158.51, "word": " مثل", "probability": 0.72607421875}, {"start": 1158.51, "end": 1158.77, "word": " وهنا", "probability": 0.824951171875}, {"start": 1158.77, "end": 1159.09, "word": " اثل", "probability": 0.9715169270833334}, {"start": 1159.09, "end": 1159.33, "word": " لان", "probability": 0.687744140625}, {"start": 1159.33, "end": 1159.61, "word": " هدول", "probability": 0.8917643229166666}, {"start": 1159.61, "end": 1160.75, "word": " متماثلات", "probability": 0.8643391927083334}], "temperature": 1.0}, {"id": 50, "seek": 118215, "start": 1161.91, "end": 1182.15, "text": "كذلك الحال في ال unhydrate لو حطيت هنا methyl وهنا phenyl يعني acidic بنزوك او حطيت هنا phenyl وهنا methyl نفس الاشي هذه المجموعة متماثلة فأي واحد احط يمين او شمال مابفرقش الان لو اجيت اعتبرت ان انا بدي اشتغل على الامد", "tokens": [4117, 8848, 23275, 21542, 6027, 8978, 2423, 517, 21591, 4404, 45164, 11331, 9566, 36081, 34105, 48441, 37037, 8315, 7279, 5088, 37495, 22653, 39514, 44945, 11622, 2407, 4117, 1975, 2407, 11331, 9566, 36081, 34105, 7279, 5088, 37037, 8315, 48441, 8717, 36178, 2423, 33599, 1829, 29538, 9673, 7435, 2304, 2407, 27884, 44650, 2304, 5718, 104, 37977, 6156, 10721, 1829, 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1200.54, "text": "و اشوف اللي هي ال peptide bond هل يا تورا في عندي تماثل ولا لأ لما باجي بشتغل اتذكروا ان احنا قولنا بنشتغل N C C double bond او و بعدها بنشتغل N C", "tokens": [2407, 1975, 8592, 38688, 13672, 1829, 39896, 2423, 41781, 482, 6086, 8032, 1211, 35186, 6055, 13063, 995, 8978, 18871, 16254, 46811, 5718, 104, 1211, 49429, 5296, 10721, 5296, 15042, 4724, 26108, 1829, 4724, 8592, 2655, 17082, 1211, 1975, 2655, 8848, 37983, 14407, 16472, 1975, 5016, 8315, 12174, 12610, 8315, 44945, 8592, 2655, 17082, 1211, 426, 383, 383, 3834, 6086, 1975, 2407, 4032, 39182, 11296, 44945, 8592, 2655, 17082, 1211, 426, 383], "avg_logprob": -0.23697916294137636, "compression_ratio": 1.4935897435897436, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1183.88, "end": 1184.08, "word": "و", "probability": 0.8310546875}, {"start": 1184.08, "end": 1184.78, "word": " اشوف", "probability": 0.745849609375}, {"start": 1184.78, "end": 1185.18, "word": " اللي", "probability": 0.633056640625}, 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"probability": 0.95068359375}], "temperature": 1.0}, {"id": 95, "seek": 228255, "start": 2257.89, "end": 2282.55, "text": "عشان هيك لما عدينا ال amino acids عديناهم تسعة، واحد، اتنين، تلات، اربع، خمس، ستة، سبعة، تمانية، تسعة بس الأول والسادس فيهم CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2SH CH2", "tokens": [3615, 8592, 7649, 39896, 4117, 5296, 15042, 6225, 16254, 8315, 2423, 24674, 21667, 6225, 16254, 8315, 16095, 6055, 3794, 27884, 12399, 36764, 24401, 12399, 1975, 2655, 1863, 9957, 12399, 6055, 1211, 9307, 12399, 1975, 25513, 3615, 12399, 16490, 2304, 3794, 12399, 8608, 2655, 3660, 12399, 8608, 3555, 27884, 12399, 46811, 7649, 10632, 12399, 6055, 3794, 27884, 4724, 3794, 16247, 12610, 16070, 3794, 18513, 3794, 8978, 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[{"start": 2257.89, "end": 2258.31, "word": "عشان", "probability": 0.95849609375}, {"start": 2258.31, "end": 2258.47, "word": " هيك", "probability": 0.627685546875}, {"start": 2258.47, "end": 2258.63, "word": " لما", "probability": 0.854248046875}, {"start": 2258.63, "end": 2259.03, "word": " عدينا", "probability": 0.9342447916666666}, {"start": 2259.03, "end": 2259.15, "word": " ال", "probability": 0.93603515625}, {"start": 2259.15, "end": 2259.45, "word": " amino", "probability": 0.39013671875}, {"start": 2259.45, "end": 2259.83, "word": " acids", "probability": 0.716796875}, {"start": 2259.83, "end": 2260.29, "word": " عديناهم", "probability": 0.92724609375}, {"start": 2260.29, "end": 2260.67, "word": " تسعة،", "probability": 0.693389892578125}, {"start": 2260.67, "end": 2260.93, "word": " واحد،", "probability": 0.8671875}, {"start": 2260.93, "end": 2261.25, "word": " اتنين،", "probability": 0.94833984375}, {"start": 2261.25, "end": 2261.59, "word": " تلات،", "probability": 0.86474609375}, {"start": 2261.59, "end": 2261.93, "word": " اربع،", "probability": 0.8895263671875}, {"start": 2261.93, "end": 2262.25, "word": " خمس،", "probability": 0.974853515625}, {"start": 2262.25, "end": 2262.69, "word": " ستة،", "probability": 0.9290771484375}, {"start": 2262.69, "end": 2263.01, "word": " سبعة،", "probability": 0.9012451171875}, {"start": 2263.01, "end": 2263.35, "word": " تمانية،", "probability": 0.9410400390625}, {"start": 2263.35, "end": 2263.55, "word": " تسعة", "probability": 0.95458984375}, {"start": 2263.55, "end": 2264.09, "word": " بس", "probability": 0.548919677734375}, {"start": 2264.09, "end": 2265.03, "word": " الأول", "probability": 0.83544921875}, {"start": 2265.03, "end": 2265.87, "word": " والسادس", "probability": 0.926513671875}, {"start": 2265.87, "end": 2266.33, "word": " فيهم", "probability": 0.968994140625}, {"start": 2266.33, "end": 2268.11, "word": " CH2SH", "probability": 0.8538411458333334}, {"start": 2268.11, "end": 2269.57, "word": " CH2SH", "probability": 0.8953450520833334}, {"start": 2269.57, "end": 2270.49, "word": " CH2SH", "probability": 0.6836751302083334}, {"start": 2270.49, "end": 2270.49, "word": " CH2SH", "probability": 0.8924153645833334}, {"start": 2270.49, "end": 2270.49, "word": " CH2SH", "probability": 0.9425455729166666}, {"start": 2270.49, "end": 2270.49, "word": " CH2SH", "probability": 0.9677734375}, {"start": 2270.49, "end": 2270.49, "word": " CH2SH", "probability": 0.9757486979166666}, {"start": 2270.49, "end": 2270.49, "word": " CH2SH", "probability": 0.9783528645833334}, {"start": 2270.49, "end": 2270.49, "word": " CH2SH", "probability": 0.9786783854166666}, {"start": 2270.49, "end": 2270.49, "word": " CH2SH", "probability": 0.978515625}, {"start": 2270.49, "end": 2270.49, "word": " CH2SH", "probability": 0.9778645833333334}, {"start": 2270.49, "end": 2270.49, "word": " CH2SH", "probability": 0.9786783854166666}, {"start": 2270.49, "end": 2270.49, "word": " CH2SH", "probability": 0.9786783854166666}, {"start": 2270.49, "end": 2270.49, "word": " CH2SH", "probability": 0.9793294270833334}, {"start": 2270.49, "end": 2270.49, "word": " CH2SH", "probability": 0.9803059895833334}, {"start": 2270.49, "end": 2270.81, "word": " CH2SH", "probability": 0.9814453125}, {"start": 2270.81, "end": 2271.53, "word": " CH2SH", "probability": 0.982421875}, {"start": 2271.53, "end": 2271.53, "word": " CH2SH", "probability": 0.9832356770833334}, {"start": 2271.53, "end": 2271.55, "word": " CH2SH", "probability": 0.9842122395833334}, {"start": 2271.55, "end": 2271.55, "word": " CH2SH", "probability": 0.9847005208333334}, {"start": 2271.55, "end": 2271.55, "word": " CH2SH", "probability": 0.9851888020833334}, {"start": 2271.55, "end": 2271.55, "word": " CH2SH", "probability": 0.98583984375}, {"start": 2271.55, "end": 2271.55, "word": " CH2SH", "probability": 0.9860026041666666}, {"start": 2271.55, "end": 2271.55, "word": " CH2SH", "probability": 0.986328125}, {"start": 2271.55, "end": 2271.55, "word": " CH2SH", "probability": 0.9866536458333334}, {"start": 2271.55, "end": 2271.55, "word": " CH2SH", "probability": 0.986328125}, {"start": 2271.55, "end": 2271.55, "word": " CH2SH", "probability": 0.9866536458333334}, {"start": 2271.55, "end": 2271.55, "word": " CH2SH", "probability": 0.9866536458333334}, {"start": 2271.55, "end": 2271.55, "word": " CH2SH", "probability": 0.9866536458333334}, {"start": 2271.55, "end": 2271.55, "word": " CH2SH", "probability": 0.9864908854166666}, {"start": 2271.55, "end": 2271.57, "word": " CH2SH", "probability": 0.9864908854166666}, {"start": 2271.57, "end": 2271.91, "word": " CH2SH", "probability": 0.986328125}, {"start": 2271.91, "end": 2272.25, "word": " CH2SH", "probability": 0.986328125}, {"start": 2272.25, "end": 2272.73, "word": " CH2SH", "probability": 0.9861653645833334}, {"start": 2272.73, "end": 2272.73, "word": " CH2SH", "probability": 0.9861653645833334}, {"start": 2272.73, "end": 2272.73, "word": " CH2SH", "probability": 0.986328125}, {"start": 2272.73, "end": 2272.73, "word": " CH2SH", "probability": 0.9861653645833334}, {"start": 2272.73, "end": 2272.73, "word": " CH2SH", "probability": 0.9860026041666666}, {"start": 2272.73, "end": 2272.73, "word": " CH2SH", "probability": 0.9860026041666666}, {"start": 2272.73, "end": 2272.75, "word": " CH2SH", "probability": 0.9860026041666666}, {"start": 2272.75, "end": 2272.75, "word": " CH2SH", "probability": 0.9860026041666666}, {"start": 2272.75, "end": 2272.99, "word": " CH2SH", "probability": 0.98583984375}, {"start": 2272.99, "end": 2272.99, "word": " CH2SH", "probability": 0.98583984375}, {"start": 2272.99, "end": 2273.93, "word": " CH2SH", "probability": 0.9860026041666666}, {"start": 2273.93, "end": 2274.93, "word": " CH2SH", "probability": 0.9861653645833334}, {"start": 2274.93, "end": 2275.95, "word": " CH2SH", "probability": 0.9860026041666666}, {"start": 2275.95, "end": 2276.31, "word": " CH2SH", "probability": 0.9861653645833334}, {"start": 2276.31, "end": 2278.11, "word": " CH2SH", "probability": 0.9864908854166666}, {"start": 2278.11, "end": 2279.51, "word": " CH2SH", "probability": 0.9864908854166666}, {"start": 2279.51, "end": 2280.09, "word": " CH2SH", "probability": 0.9864908854166666}, {"start": 2280.09, "end": 2280.75, "word": " CH2SH", "probability": 0.9873046875}, {"start": 2280.75, "end": 2282.55, "word": " CH2SH", "probability": 0.9864908854166666}, {"start": 2282.55, "end": 2282.55, "word": " CH2", "probability": 0.986572265625}], "temperature": 1.0}, {"id": 96, "seek": 231153, "start": 2283.07, "end": 2311.53, "text": "الان واضح تماما انه صعب في نهاية المحاضرة ان نبدأ نحكي عن ال protein وكيف نعمل ال sequence هيلزمنا ان شاء الله محاضرة إضافية نحكي فيها كيف نتعرف على ال sequence لل amino acids وإذا عرفنا ال sequence شوفنا كيف الآن بنحضرهم بعد هيك أشكال ال protein المختلفة فان شاء الله إلى لقاء", "tokens": [6027, 7649, 4032, 46958, 5016, 46811, 10943, 995, 16472, 3224, 20328, 3615, 3555, 8978, 8717, 11296, 10632, 9673, 5016, 46958, 25720, 16472, 8717, 44510, 10721, 8717, 5016, 4117, 1829, 18871, 2423, 7944, 4032, 4117, 33911, 8717, 25957, 1211, 2423, 8310, 8032, 26895, 11622, 2304, 8315, 16472, 13412, 16606, 21984, 3714, 5016, 46958, 25720, 11933, 11242, 31845, 10632, 8717, 5016, 4117, 1829, 8978, 11296, 9122, 33911, 8717, 2655, 3615, 28480, 15844, 2423, 8310, 24976, 24674, 21667, 4032, 28814, 15730, 6225, 28480, 8315, 2423, 8310, 13412, 38688, 8315, 9122, 33911, 6024, 48506, 44945, 5016, 11242, 2288, 16095, 39182, 39896, 4117, 5551, 8592, 4117, 6027, 2423, 7944, 9673, 46456, 46538, 3660, 6156, 7649, 13412, 16606, 21984, 30731, 5296, 4587, 16606], "avg_logprob": -0.08269332734457517, "compression_ratio": 1.8760330578512396, "no_speech_prob": 0.0, "words": [{"start": 2283.07, "end": 2283.63, "word": "الان", "probability": 0.879638671875}, {"start": 2283.63, "end": 2284.87, "word": " واضح", "probability": 0.9557291666666666}, {"start": 2284.87, "end": 2285.53, "word": " تماما", "probability": 0.9847005208333334}, {"start": 2285.53, "end": 2286.05, "word": " انه", "probability": 0.90869140625}, {"start": 2286.05, "end": 2286.59, "word": " صعب", "probability": 0.9908854166666666}, {"start": 2286.59, "end": 2286.75, "word": " في", "probability": 0.8720703125}, {"start": 2286.75, "end": 2287.09, "word": " نهاية", "probability": 0.9757486979166666}, {"start": 2287.09, "end": 2287.83, "word": " المحاضرة", "probability": 0.9814453125}, {"start": 2287.83, "end": 2288.45, "word": " ان", "probability": 0.7919921875}, {"start": 2288.45, "end": 2289.13, "word": " نبدأ", "probability": 0.85693359375}, {"start": 2289.13, "end": 2290.91, "word": " نحكي", "probability": 0.9771728515625}, {"start": 2290.91, "end": 2291.21, "word": " عن", "probability": 0.99169921875}, {"start": 2291.21, "end": 2291.83, "word": " ال", "probability": 0.96337890625}, {"start": 2291.83, "end": 2292.33, "word": " protein", "probability": 0.6005859375}, {"start": 2292.33, "end": 2292.85, "word": " وكيف", "probability": 0.8733723958333334}, {"start": 2292.85, "end": 2293.29, "word": " نعمل", "probability": 0.9890950520833334}, {"start": 2293.29, "end": 2293.51, "word": " ال", "probability": 0.9638671875}, {"start": 2293.51, "end": 2294.17, "word": " sequence", "probability": 0.9794921875}, {"start": 2294.17, "end": 2294.91, "word": " هيلزمنا", "probability": 0.83330078125}, {"start": 2294.91, "end": 2295.07, "word": " ان", "probability": 0.87353515625}, {"start": 2295.07, "end": 2295.27, "word": " شاء", "probability": 0.969482421875}, {"start": 2295.27, "end": 2295.37, "word": " الله", "probability": 0.93994140625}, {"start": 2295.37, "end": 2296.51, "word": " محاضرة", "probability": 0.9901123046875}, {"start": 2296.51, "end": 2297.47, "word": " إضافية", "probability": 0.90087890625}, {"start": 2297.47, "end": 2298.03, "word": " نحكي", "probability": 0.9771728515625}, {"start": 2298.03, "end": 2298.47, "word": " فيها", "probability": 0.989990234375}, {"start": 2298.47, "end": 2299.03, "word": " كيف", "probability": 0.962158203125}, {"start": 2299.03, "end": 2299.71, "word": " نتعرف", "probability": 0.989013671875}, {"start": 2299.71, "end": 2300.09, "word": " على", "probability": 0.89501953125}, {"start": 2300.09, "end": 2300.97, "word": " ال", "probability": 0.98388671875}, {"start": 2300.97, "end": 2301.71, "word": " sequence", "probability": 0.99267578125}, {"start": 2301.71, "end": 2302.57, "word": " لل", "probability": 0.87548828125}, {"start": 2302.57, "end": 2302.99, "word": " amino", "probability": 0.9404296875}, {"start": 2302.99, "end": 2303.57, "word": " acids", "probability": 0.76953125}, {"start": 2303.57, "end": 2303.91, "word": " وإذا", "probability": 0.833984375}, {"start": 2303.91, "end": 2304.25, "word": " عرفنا", "probability": 0.9933268229166666}, {"start": 2304.25, "end": 2304.39, "word": " ال", "probability": 0.9833984375}, {"start": 2304.39, "end": 2304.83, "word": " sequence", "probability": 0.9931640625}, {"start": 2304.83, "end": 2305.21, "word": " شوفنا", "probability": 0.9168294270833334}, {"start": 2305.21, "end": 2305.45, "word": " كيف", "probability": 0.96923828125}, {"start": 2305.45, "end": 2305.69, "word": " الآن", "probability": 0.71435546875}, {"start": 2305.69, "end": 2306.57, "word": " بنحضرهم", "probability": 0.98359375}, {"start": 2306.57, "end": 2307.17, "word": " بعد", "probability": 0.7998046875}, {"start": 2307.17, "end": 2307.81, "word": " هيك", "probability": 0.78759765625}, {"start": 2307.81, "end": 2308.49, "word": " أشكال", "probability": 0.9591064453125}, {"start": 2308.49, "end": 2308.81, "word": " ال", "probability": 0.98486328125}, {"start": 2308.81, "end": 2309.25, "word": " protein", "probability": 0.9736328125}, {"start": 2309.25, "end": 2310.17, "word": " المختلفة", "probability": 0.9945068359375}, {"start": 2310.17, "end": 2310.65, "word": " فان", "probability": 0.709228515625}, {"start": 2310.65, "end": 2310.77, "word": " شاء", "probability": 0.981689453125}, {"start": 2310.77, "end": 2310.85, "word": " الله", "probability": 0.93701171875}, {"start": 2310.85, "end": 2311.09, "word": " إلى", "probability": 0.865234375}, {"start": 2311.09, "end": 2311.53, "word": " لقاء", "probability": 0.9265950520833334}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2312.336, "duration_after_vad": 2219.2037499999915}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/VEV_j0BJLYk.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/VEV_j0BJLYk.srt
new file mode 100644
index 0000000000000000000000000000000000000000..246f67a065c5bb235cf4cd84b9066508d688f3d0
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/VEV_j0BJLYk.srt
@@ -0,0 +1,947 @@
+1
+00:00:19,460 --> 00:00:24,620
+بسم الله الرحمن الرحيم. بدأنا نحن المرة الماضية في
+
+2
+00:00:24,620 --> 00:00:28,220
+موضوع الأحماض الكربوكسيلية، الـ carboxylic acids.
+
+3
+00:00:28,220 --> 00:00:35,460
+واستعرضنا طبعًا تسميتها وحامضيتها، وبدأنا في
+
+4
+00:00:35,460 --> 00:00:40,840
+موضوع تحضير الـ carboxylic acids. قلنا طبعًا أن في
+
+5
+00:00:40,840 --> 00:00:47,130
+عندنا أكثر من طريقة لتحضير الـ carboxylic acids. لو
+
+6
+00:00:47,130 --> 00:00:53,190
+بدنا نحن نجيء ببساطة نتخيل هذه الطرق لتحضير الـ
+
+7
+00:00:53,190 --> 00:00:59,430
+carboxylic acids. بإمكانكم النظر إلى الأقلام التي
+
+8
+00:00:59,430 --> 00:01:04,590
+أنا حاملهم. هؤلاء كم قلم؟ ثلاثة... ثلاثة... ثلاثة
+
+9
+00:01:04,590 --> 00:01:05,090
+... ثلاثة... ثلاثة... ثلاثة... ثلاثة... ثلاثة...
+
+10
+00:01:05,090 --> 00:01:06,070
+ثلاثة... ثلاثة... ثلاثة... ثلاثة... ثلاثة... ثلاثة
+
+11
+00:01:06,070 --> 00:01:06,150
+... ثلاثة... ثلاثة... ثلاثة... ثلاثة... ثلاثة...
+
+12
+00:01:06,150 --> 00:01:12,410
+... ثلاثة... ثلاثة... ثلاثة... ثلاثة... ثلاثة
+
+13
+00:01:12,410 --> 00:01:19,640
+... ثلاثة... يعني أبدأ بثلاث ذرات. عند اللزوم، كحول
+
+14
+00:01:19,640 --> 00:01:24,020
+أو aldehyde، ويطلع عندي حمض من ثلاث ذرات، يعني
+
+15
+00:01:24,020 --> 00:01:28,520
+أبدأ بثلاث ويطلع عندي ثلاث، وكانت هذه الطريقة
+
+16
+00:01:28,520 --> 00:01:32,480
+طريقة التساوي، هي الطريقة الأولى التي بدأنا نشرحها
+
+17
+00:01:32,480 --> 00:01:36,180
+لما تحدثنا المرة الماضية عن الكحولات وعن الـ
+
+18
+00:01:36,180 --> 00:01:40,550
+aldehydes. لما تحدثنا المرة الماضية عن الكحولات و
+
+19
+00:01:40,550 --> 00:01:45,950
+عن الـ aldehydes. هذه الطريقة، طريقة إيش؟ تساوي، يعني
+
+20
+00:01:45,950 --> 00:01:52,330
+كم عندي عدد كربونات في الكحول أو في الـ
+
+21
+00:01:52,330 --> 00:01:56,290
+aldehyde؟ كم بيكونوا في الـ essence؟ يعني لو الكحول
+
+22
+00:01:56,290 --> 00:02:03,000
+كانوا ثلاث، معنى ذلك هيكون اسمه تبعه فيه propane، أو
+
+23
+00:02:03,000 --> 00:02:06,880
+الـ aldehyde كانوا ثلاث، الاسم تبعه برضه هيكون فيه
+
+24
+00:02:06,880 --> 00:02:12,760
+propan. ثلاث. الآن الـ acid اللي هيطلع برضه هيكون
+
+25
+00:02:12,760 --> 00:02:19,560
+ثلاث. لا هيزيد ولا هينقص. خلينا نشوف هذا الكلام.
+
+26
+00:02:19,560 --> 00:02:24,120
+يعني مثلًا لو أخذنا CH3 CH2
+
+27
+00:02:26,930 --> 00:02:35,710
+هذا إيش؟ كحول من كم كربونة؟ ثلاث. اسمه بروبان
+
+28
+00:02:35,710 --> 00:02:41,810
+الـ propanol. بتعبر عن العدد. الآن لو بدنا أكسدة
+
+29
+00:02:41,810 --> 00:02:49,430
+بسيطة في الـ BCC عند اللزوم، حيصير CH3 CH2 C double
+
+30
+00:02:49,430 --> 00:02:59,080
+bond OH. كم ذرة؟ ثلاث. هذا اللي اتكون، شو اسمه؟
+
+31
+00:03:02,720 --> 00:03:08,000
+propanol. إذًا هل تغير عدد الذرات؟ لا. لو مشينا في
+
+32
+00:03:08,000 --> 00:03:12,020
+الأكسدة بالـ KMnO4 عند اللزوم، أو من البداية
+
+33
+00:03:12,020 --> 00:03:20,960
+بدينا بالـ KMnO4، CH3 CH2 C double bond O OH. كم ذرة
+
+34
+00:03:20,960 --> 00:03:25,500
+كربون؟ ثلاث. هذا إيش بده يصير؟ propanol.
+
+35
+00:03:28,860 --> 00:03:35,200
+وبذلك بيصير واضح معه أن الأفكار المتعلقة بالأكسدة،
+
+36
+00:03:35,200 --> 00:03:40,920
+أكسدة الكحول، الـ aldehyde، الـ acid، لا تغير عدد ذرات
+
+37
+00:03:40,920 --> 00:03:46,350
+الكربون. واضحة الفكرة؟ ولذلك هذه الطريقة... طريقة إيش
+
+38
+00:03:46,350 --> 00:03:51,930
+بنسميها؟ طريقة تساوي... إنه أنا عندي ثلاث ذرات
+
+39
+00:03:51,930 --> 00:03:56,030
+carbon... إنه أنا عندي ثلاث ذرات carbon... هؤلاء
+
+40
+00:03:56,030 --> 00:03:58,570
+ثلاث ذرات carbon... كانوا ثلاث... ظلوا ثلاث...
+
+41
+00:03:58,570 --> 00:04:04,070
+ظلوا ثلاث... واضحة الفكرة؟ طبعًا للناس اللي بيحبوا
+
+42
+00:04:04,070 --> 00:04:07,890
+أن نزيد شويّة في الكلام وفي المعلومات... أنا ممكن
+
+43
+00:04:07,890 --> 00:04:12,990
+أبدأ من الثلاث بطريقة شويّة صغيرة مختلفة، يعني
+
+44
+00:04:12,990 --> 00:04:20,290
+ما أبدأ بالكحول. ما أبدأ بالكحول. يا ترى لو مثلًا بدأت
+
+45
+00:04:20,290 --> 00:04:27,810
+بها المركب. لو بدأت بهذا المركب CH3 CH double bond
+
+46
+00:04:27,810 --> 00:04:35,520
+CH2. جبت لكم سؤال. كيف من الـ propylene، برضه propylene، ملاحظين؟
+
+47
+00:04:35,520 --> 00:04:40,880
+ثلاث، propylene. How can you prepare propionic acid
+
+48
+00:04:40,880 --> 00:04:46,340
+starting from propylene؟ ثلاث، ثلاث، ثلاث، ثلاث، آه.
+
+49
+00:04:46,340 --> 00:04:51,720
+هتيجي واحدة تتذكر أن أنا هنا بدي أضيف الماء مع، ولا
+
+50
+00:04:51,720 --> 00:04:56,220
+عكس قاعدة Markovnikov، طبعًا عكس، عكس.
+
+51
+00:05:05,320 --> 00:05:10,460
+واضحة الفكرة؟ ثلاث، ما زالوا ثلاث، ما زالوا ثلاث.
+
+52
+00:05:10,460 --> 00:05:11,320
+ما زالوا ثلاث، ما زالوا ثلاث، ما زالوا ثلاث، ما
+
+53
+00:05:11,320 --> 00:05:11,500
+زالوا ثلاث، ما زالوا ثلاث، ما زالوا ثلاث، ما
+
+54
+00:05:11,500 --> 00:05:13,440
+زالوا ثلاث، ما زالوا ثلاث، ما زالوا ثلاث، ما زالوا
+
+55
+00:05:13,440 --> 00:05:15,280
+ثلاث، ما زالوا ثلاث، ما زالوا ثلاث، ما زالوا ثلاث
+
+56
+00:05:15,280 --> 00:05:19,440
+ما زالوا ثلاث، ما زالوا ثلاث، ما زالوا ثلاث، ما
+
+57
+00:05:19,440 --> 00:05:28,330
+زالوا ثلاث. ما زالوا.  يصبح acid. واضحة؟ الآن في هذه
+
+58
+00:05:28,330 --> 00:05:33,990
+الحالة، ما في عندي تغير في عدد ذرات الكربون. فالطرق
+
+59
+00:05:33,990 --> 00:05:39,310
+المنطلقة من الأكسدة هذه، ما في فيها تغير. بيكون بيوتان
+
+60
+00:05:39,310 --> 00:05:44,910
+بيوتانويك، بيوتانول، بيوتانال، لكن عدد ذرات الكربون
+
+61
+00:05:44,910 --> 00:05:48,430
+إيش ماله؟ ثابت. حتى لو قلت بيوتين كمان.
+
+62
+00:05:55,150 --> 00:06:03,190
+الآن في طرق ثانية... في طرق ثانية ممكن أن نتعامل
+
+63
+00:06:03,190 --> 00:06:09,570
+معها... ممكن نشتغل على طريقة اسمها طريقة النقص...
+
+64
+00:06:09,570 --> 00:06:16,000
+يعني أبدأ بثلاث وأكسر من الثلاث هؤلاء وأجد
+
+65
+00:06:16,000 --> 00:06:21,820
+أُطلع بإيش؟ نفترض بـ 2 وبـ 1. أكسر الثلاث، أو أبدأ بـ
+
+66
+00:06:21,820 --> 00:06:28,140
+4 وأكسر الأربعة لـ 2 و 2، أو لـ 3 و 1. هذه طريقة إيش؟
+
+67
+00:06:28,140 --> 00:06:33,400
+نقص. أنه أنا يكون عندي السلسلة الكلية، السلسلة الكلية
+
+68
+00:06:33,400 --> 00:06:39,040
+أربع كربونات، أطول منها 3 أو 2 أو 1، يعني أقل من إيش؟
+
+69
+00:06:39,560 --> 00:06:44,440
+أقل من الأربعة. صارت هذه الطريقة طريقة إيش؟ نقص، طبعًا.
+
+70
+00:06:44,440 --> 00:06:48,660
+إيش بيظل عندنا؟ أنه ممكن تكون طريقة زيادة، يعني
+
+71
+00:06:48,660 --> 00:06:53,920
+افترضوا أنه سلسلة عندي أربعة، وطلبت
+
+72
+00:06:53,920 --> 00:06:56,600
+منكم تحضروا لي حمض بخمس كربونات.
+
+73
+00:07:01,280 --> 00:07:08,760
+أنا قلت لكم ببساطة، مبتدئًا من البيوتانول، البيوتانول
+
+74
+00:07:08,760 --> 00:07:14,680
+كم كربونة؟ أربعة. حضروا لي pentanoic acid. الآن إذا
+
+75
+00:07:14,680 --> 00:07:19,720
+واحدة مش منتبهة، تقول "all oic acid"، تروح تعمل أكسدة
+
+76
+00:07:19,720 --> 00:07:26,520
+آه، بس البيوتانول بيصير بيوتانويك أسد. ما يزيدش كربونة.
+
+77
+00:07:26,520 --> 00:07:30,960
+الآن لو كنتُ بدي أسألكم والله من الـ butanol
+
+78
+00:07:30,960 --> 00:07:37,890
+حضروا لي pentanoic acid، زدتم كربونة. إذًا أنا بحاجة
+
+79
+00:07:37,890 --> 00:07:43,030
+إلى طريقة. وبناءً على ذلك، اللي بدوا يفهموا طرق تحضير
+
+80
+00:07:43,030 --> 00:07:47,130
+الأحماض بشكل عام، بنقول أن طرق تحضير الأحماض، بدكم
+
+81
+00:07:47,130 --> 00:07:51,870
+تنتبهوا تمامًا. ممكن تكون طريقة التساوي، وهذه موجودة
+
+82
+00:07:51,870 --> 00:07:55,130
+في شغل الأكسدة أو الكلام اللي شرحنا الآن. ممكن تكون
+
+83
+00:07:55,130 --> 00:08:01,250
+طريقة تكسير أو نقص، وممكن تكون طريقة إيش؟ زيادة.
+
+84
+00:08:01,250 --> 00:08:09,000
+واضحة الفكرة؟ الآن خلينا نجيء لطرق التكثير. خلينا
+
+85
+00:08:09,000 --> 00:08:15,340
+نيجيء لطرق التكثير بشكل عام. نسبة من طرق التكثير مرت
+
+86
+00:08:15,340 --> 00:08:19,980
+معنا بطريقة أو بأخرى. ليش؟ لأنه إحنا أخذنا الـ
+
+87
+00:08:19,980 --> 00:08:27,460
+ozonolysis. الـ ozonolysis عادة بيكسر المركب لإيش؟
+
+88
+00:08:28,390 --> 00:08:33,650
+لالdehyde أو ketone.  إيه، كويس. الـ aldehyde بعد ما
+
+89
+00:08:33,650 --> 00:08:38,370
+الـ ozonolysis. يعني هيك أنا بدي أقول: الألكين والألكاين.
+
+90
+00:08:38,370 --> 00:08:46,370
+مثل الألكين بالمناسبة. الألكين ممكن يعطيني إيش؟ ketone،
+
+91
+00:08:49,540 --> 00:08:53,540
+aldehyde. هذا الكلام تعلمناه ولا لأ؟ أن الألكين
+
+92
+00:08:53,540 --> 00:08:57,600
+بيصير ketone أو aldehyde. الآن الـ ketone تعلمناه أنه
+
+93
+00:08:57,600 --> 00:09:05,060
+لا يتأكسد أكسدة إضافية. لكن الـ aldehyde بتأكسد ولا
+
+94
+00:09:05,060 --> 00:09:09,860
+لا؟ الـ aldehyde بتأكسد أكسدة إضافية، بيصير إيش؟ acid.
+
+95
+00:09:09,860 --> 00:09:14,440
+الآن بكل الأحوال هذا الـ aldehyde هيكون أصغر من الـ
+
+96
+00:09:14,440 --> 00:09:20,010
+ألكين أو من الألكاين ولا لأ؟ بالتأكيد. هنا هيلزمني
+
+97
+00:09:20,010 --> 00:09:25,750
+كم عملية تتم وراء بعض؟ عمليتين. العملية الأولى الـ
+
+98
+00:09:25,750 --> 00:09:31,630
+ozonolysis، والعملية الثانية الـ oxidation. خليني
+
+99
+00:09:31,630 --> 00:09:35,990
+أعبّر عنها بـ O بين قوسين، Oxidation. عملية أكسدة، عادة
+
+100
+00:09:35,990 --> 00:09:41,430
+بيستعملونها H2O2، الهيدروجين بيروكسايد. هذه كمان
+
+101
+00:09:41,430 --> 00:09:49,310
+خلوها H2O2. إذًا ozonolysis followed by H2O2 يمكن
+
+102
+00:09:49,310 --> 00:09:55,050
+أن يؤدي إلى أحماض، لكن أكيد هتكون أصغر من إيش؟ أصغر
+
+103
+00:09:55,050 --> 00:10:02,090
+من الألكين اللي أنا ابتدأت فيه. الآن خلينا ناخد
+
+104
+00:10:02,090 --> 00:10:06,910
+مثالًا حقيقيًا. ناخد مثالًا حقيقيًا. لو يا ترى أخذنا هذا
+
+105
+00:10:06,910 --> 00:10:16,980
+الألكين، سواء قلنا عنه cis أو trans، CH3 CH3 H
+
+106
+00:10:16,980 --> 00:10:26,200
+CH3 H، وقلنا: نمرة واحد O3، ozonolysis، ونمرة
+
+107
+00:10:26,200 --> 00:10:31,060
+اثنين H2O2. H2O2، Hydrogen Peroxide، هو العامل
+
+108
+00:10:31,060 --> 00:10:39,210
+المؤكسد. الآن بدنا لما ننفذ، نفهم. الشغل الأول: كسر
+
+109
+00:10:39,210 --> 00:10:47,350
+يعني C double bond O H، و CH3، زائد C double bond O H
+
+110
+00:10:47,350 --> 00:10:55,750
+و CH3. هذا الـ ozonolysis. طب والـ acid هذا إيش؟
+
+111
+00:10:55,750 --> 00:11:00,830
+aldehyde. الآن هذا الـ aldehyde بالـ H2O2 اللي ضفناها
+
+112
+00:11:00,830 --> 00:11:08,760
+إيش حيصير؟ C double bond O OH CH3. وجدنا، حصلنا على
+
+113
+00:11:08,760 --> 00:11:14,980
+الأسيتيك أسد. الأسيتيك أسد. كده؟ كربون 2. يعني كأنه أنا
+
+114
+00:11:14,980 --> 00:11:18,820
+بالـ ozonolysis جيت كسرت الأربعة هؤلاء، اثنين و
+
+115
+00:11:18,820 --> 00:11:23,400
+اثنين. طلعوا عندي aldehyde. الآن كملت، أكسّدت الـ aldehyde
+
+116
+00:11:23,400 --> 00:11:29,060
+صار أسيتيك أسد. فمن الأربعة، حصلت على حمض من كم
+
+117
+00:11:29,060 --> 00:11:37,890
+كربون؟ اثنين. واضحة الفكرة؟ طبعًا. الآن اللي ممكن
+
+118
+00:11:37,890 --> 00:11:44,390
+يفكروا أن نتعمق معهم بمثل هذه الفكرة، ممكن نجيء
+
+119
+00:11:44,390 --> 00:11:49,910
+نسألهم، ما نقول لهم: مش مبتدئين من الـ 2-butene، لو
+
+120
+00:11:49,910 --> 00:11:55,930
+بدأت من الـ 1-butene، هيطلع عندي حمض واحد وثلاث
+
+121
+00:11:56,580 --> 00:12:00,520
+لأن هذه هتكسر كربونة وهؤلاء يكونوا ثلاث. لكن لو
+
+122
+00:12:00,520 --> 00:12:07,080
+أنا جئت وقلت لكم والله من مركب زي هذا CH3 CH2 CH
+
+123
+00:12:07,080 --> 00:12:15,560
+سواء حطيت هنا Cl أو OH. تخيلوا أن أنا أجي أقول لكم
+
+124
+00:12:15,560 --> 00:12:23,720
+من 2-chlorobutane، حضروا لي propionic acid. واضحة؟ أو
+
+125
+00:12:23,720 --> 00:12:28,880
+من 2-butanol، بتكون تعملوا elimination. الآن الـ Cl
+
+126
+00:12:28,880 --> 00:12:32,320
+والـ H بيروحوا وبيعطينا الـ more substituted
+
+127
+00:12:32,320 --> 00:12:37,280
+باستعمال إيش؟ طلع
+
+128
+00:12:37,280 --> 00:12:44,240
+أنا الـ alkyne، وبعدين كسرت الـ alkyne. هذه الطرق ومع
+
+129
+00:12:44,240 --> 00:12:47,020
+الـ triple bond، نفس الشيء زي الـ double bond. هذه
+
+130
+00:12:47,020 --> 00:12:52,180
+الطرق تعتبر طرق إيش؟ نقص. يعني كان عندي أربع
+
+131
+00:12:52,180 --> 00:12:56,720
+كربونات، عملت حمض من كربونتين، عملت حمض من ثلاث
+
+132
+00:12:56,720 --> 00:13:02,840
+كربونات، حسب موقع إيش؟ الـ double bond. بس بشرط أنه
+
+133
+00:13:02,840 --> 00:13:06,660
+يكون من نتائج الـ ozonolysis أنه بتكون aldehyde. ليش؟
+
+134
+00:13:06,660 --> 00:13:10,820
+لأن اللي بيكمل وبيتأكسد الـ aldehyde. الـ ketone، بنقول
+
+135
+00:13:10,820 --> 00:13:16,140
+فيه له أكسدة إضافية؟ لا. واضحة الفكرة؟ اللي بيكمل
+
+136
+00:13:16,140 --> 00:13:21,210
+وبيتأكسد هو مين؟ الـ aldehyde. وهذا الكلام أخذناه في
+
+137
+00:13:21,210 --> 00:13:24,090
+أكسدة الـ aldehyde والـ ketones. قلنا الـ aldehyde بتصير
+
+138
+00:13:24,090 --> 00:13:30,430
+حمض. الـ ketones لا تتأكسد أكسدة إضافية. واضحة الفكرة؟
+
+139
+00:13:30,430 --> 00:13:37,150
+طيب.
+
+140
+00:13:37,150 --> 00:13:45,300
+إذًا عرفنا طريقة المساواة وطريقة النقص، إيش ظل
+
+141
+00:13:45,300 --> 00:13:51,140
+عندنا؟ طريقة الزيادة. بمعنى لو أنا جئت وقلت لكم لو
+
+142
+00:13:51,140 --> 00:13:56,240
+سمحتم، من ثلاث كربونات بدي أحضر حمض من أربع
+
+143
+00:13:56,240 --> 00:14:03,000
+كربونات. عادة الزيادة اللي إحنا بنعملها زيادة سهلة.
+
+144
+00:14:03,480 --> 00:14:07,900
+ليش؟ كربونة واحدة هي اللي بتتم بسهولة. يعني الثلاث
+
+145
+00:14:07,900 --> 00:14:13,160
+يصيروا أربعة، الأربعة يصيروا خمسة، الخمسة يصيروا
+
+146
+00:14:13,160 --> 00:14:17,680
+ستة. كيف هذا الكلام... كيف هذا الكلام بتم؟ هذا
+
+147
+00:14:17,680 --> 00:14:26,500
+الكلام عادة بتتم، ننطلق فيه من الـ alkyl halide، من الـ
+
+148
+00:14:26,500 --> 00:14:33,040
+1-chloro compound. واضح؟ يعني بدي مركب سلسلة يكون
+
+149
+00:14:33,040 --> 00:14:39,300
+على موقع واحد فيها إيش؟ كلور. بدي سلسلة على موقع
+
+150
+00:14:39,300 --> 00:14:47,340
+واحد فيها كلور. يعني مثلًا زي ما أقول CH3 CH2 CH2
+
+151
+00:14:47,340 --> 00:14:56,390
+Cl. الآن الكلور هنا وين؟ على موقع واحد. هذا الكلور
+
+152
+00:14:56,390 --> 00:15:00,050
+مكانه، بدي أزيد كربونة اللي هي بده تكون حاملة
+
+153
+00:15:00,050 --> 00:15:06,320
+مجموعة الاسم. عدد الكربونات الكلي. يعني قد إيش؟ ثلاث. بدي
+
+154
+00:15:06,320 --> 00:15:11,720
+أحضر من هذا butanoic acid. يعني كم كربونة؟ أربعة.
+
+155
+00:15:11,720 --> 00:15:16,640
+في عندي طريقتين ممكنين. في عندي طريقتين ممكنين.
+
+156
+00:15:16,640 --> 00:15:22,920
+الطريقة الأولى، أنه أنا هذا أجي أفعله مع CN−.
+
+157
+00:15:22,920 --> 00:15:28,140
+والطريقة الثانية، أنه أنا هذا أفعله مع Grignard
+
+158
+00:15:28,140 --> 00:15:34,560
+reagent. ما عليكم، المغنيسيوم اللي بيعطي RMgX. طيب.
+
+159
+00:15:34,560 --> 00:15:38,720
+لو فعلنا مع الـ cyanide، شو بده يصير هذا؟ بده يصير
+
+160
+00:15:38,720 --> 00:15:49,220
+CH3 CH2 CH2، وهنا بده تيجي مجموعة الـ CN. لاحظوا هنا
+
+161
+00:15:49,220 --> 00:15:54,120
+بينت الكربون الرابعة ولا لأ؟ هيصيروا كم كربونة؟
+
+162
+00:15:55,060 --> 00:16:02,160
+أربعة بدل ثلاث. الآن الـ cyanide بشكل عام، لو عملت له
+
+163
+00:16:02,160 --> 00:16:11,340
+hydrolysis، يا إما بـ H3O+ بيمشي الحال، أو بـ NaOH
+
+164
+00:16:11,340 --> 00:16:15,840
+−OH وبعدين H+. يعني يا إما بهذا الـ reagent يا
+
+165
+00:16:15,840 --> 00:16:20,100
+إما بهذا الـ reagent، بأي واحد منهم بيمشي، بصير أسلوب.
+
+166
+00:16:20,870 --> 00:16:24,310
+يعني الـ cyanide بيعمل hydrolysis، الـ
+
+223
+00:22:02,490 --> 00:22:05,670
+صح؟
+
+224
+00:22:05,670 --> 00:22:13,890
+CH3 إيش ممكن كمان؟ الـ F البنزين CH2 CH3 إيش كمان؟
+
+225
+00:22:13,890 --> 00:22:26,110
+ممكن؟  الـ تولوين CH CH3 CH3 كل هذول بيحملوهم الكلّي
+
+226
+00:22:26,110 --> 00:22:29,950
+جروبس ممكن حد يفكر كمان بالـ تيرشياري بيوتيل بنزين
+
+227
+00:22:29,950 --> 00:22:36,610
+ممكن حد يفكر بالـ تيرشياري بيوتيل بنزين الآن بنقول
+
+228
+00:22:36,610 --> 00:22:43,230
+القاتل لو استعملنا عامل مؤكسد بشكل عام، الـ KMnO4
+
+229
+00:22:43,230 --> 00:22:48,710
+برمنجنات البوتاسيوم مع أي ألكيل بنزين، مع أي ألكيل
+
+230
+00:22:48,710 --> 00:22:54,480
+بنزين، بشرط أن الكربون المتصل على البنزين مباشرة
+
+231
+00:22:54,480 --> 00:22:59,040
+تحتوي على ذرة هيدروجين على الأقل. الآن هذه
+
+232
+00:22:59,040 --> 00:23:03,540
+الكربون.. كم هيدروجين بتحمل؟ تلاتة.. هذه.. هذه
+
+233
+00:23:03,540 --> 00:23:08,000
+.. هذه.. ولا واحدة.. إذا هذول التلاتة بيمشي
+
+234
+00:23:08,000 --> 00:23:14,540
+حالهم، أي واحدة من هذول بالأكسدة بـ KMnO4
+
+235
+00:23:14,540 --> 00:23:18,820
+بتعطينا بنزويك أسد. الآن انتبهوا معي لنقطة كتير
+
+236
+00:23:18,820 --> 00:23:26,100
+مهمة، أنه بغض النظر عن طول السلسلة، هنطلع بس بنزويك
+
+237
+00:23:26,100 --> 00:23:30,960
+أسد. يعني لو كان هنا مثل أو إيثل أو بروبيل أو بيوتيل
+
+238
+00:23:30,960 --> 00:23:34,760
+كربونة أو اثنتين أو تلاتة أو أربعة أو خمسة أو عشرة
+
+239
+00:23:35,740 --> 00:23:40,220
+بس هنطلع إيش؟ الـ benzoic acid. مرات كتير لما بنيجي
+
+240
+00:23:40,220 --> 00:23:44,620
+بنسأل الطلاب، بنقول لهم: اعملوا لنا أكسدة بنزين حامل
+
+241
+00:23:44,620 --> 00:23:47,340
+تلات كربونات، بيروحوا بيخلوا الكربونتين وبيعملوا
+
+242
+00:23:47,340 --> 00:23:51,640
+الأكسدة على التالتة. فهمتوا الغلطة اللي بحكيها ولا
+
+243
+00:23:51,640 --> 00:24:00,600
+أوضحها أكثر لما أجي أرسم لهم مركب زي هذا CH2 CH2
+
+244
+00:24:00,600 --> 00:24:07,120
+CH3 وأقول لهم بالـ KMnO4 الآن الغلطة اللي بيعملوها
+
+245
+00:24:07,120 --> 00:24:11,900
+بيعملوا الـ acid هنا وبيخلوا هذول. الجواب الصحيح
+
+246
+00:24:11,900 --> 00:24:15,620
+أنه سواء كانوا هذول واحدة أو اثنتين أو تلاتة أو
+
+247
+00:24:15,620 --> 00:24:20,720
+أربعة أو عشرة، بس بتكون عندنا مجموعة الـ acid
+
+248
+00:24:20,720 --> 00:24:27,240
+COOH بمعنى أنا ما بشرحش الميكانيزم، متفقين؟ أنه ما بدي أدخل
+
+249
+00:24:27,240 --> 00:24:31,180
+كتير بتفاصيل، يعني خليني في النتائج. بمعنى لو أنا
+
+250
+00:24:31,180 --> 00:24:38,120
+أجيت سألتكم وقلت لكم أنه تفاعل الطلوين والـ كيومين
+
+251
+00:24:38,120 --> 00:24:42,120
+آه، انتبهوا معي، الطلوين والكيومين مع الـ KMnO4
+
+252
+00:24:42,120 --> 00:24:47,990
+both produces benzoic acid، صح؟ بينما لو كان
+
+253
+00:24:47,990 --> 00:24:52,390
+السؤال: تفاعل الطلوين والـ tertiary بيوتيل بنزين
+
+254
+00:24:52,390 --> 00:24:56,490
+هذا لا، لأن هذا ما في عليه هيدروجين على الكربون
+
+255
+00:24:56,490 --> 00:25:03,190
+المتصلة مباشرة بالبنزين. واضحة الفكرة؟ فعشان هيك
+
+256
+00:25:03,190 --> 00:25:06,810
+هذا النوع من الأكسدة، هذا بنسميه oxidation of the
+
+257
+00:25:06,810 --> 00:25:12,290
+aliphatic side chain. مش هذه سلسلة معلقة على
+
+258
+00:25:12,290 --> 00:25:18,730
+البنزين. ولذلك هذا التفاعل اسمه أكسدة السلسلة
+
+259
+00:25:18,730 --> 00:25:24,110
+المعلقة على البنزين، مهما كبرت ومهما عظمت، إيش
+
+260
+00:25:24,110 --> 00:25:31,750
+بتعطيني؟ acid بس، بغض النظر عن طولها. واضح؟
+
+261
+00:25:31,750 --> 00:25:36,530
+Oxidation of the aliphatic side chain attached to
+
+262
+00:25:36,530 --> 00:25:41,330
+benzene. واضحة الفكرة؟ هذه طريقة لتحضير الـ benzoic
+
+263
+00:25:41,330 --> 00:25:46,570
+acid. طبعاً إحنا جبنا طريقة تانية باستعمال إيش؟ الـ
+
+264
+00:25:46,570 --> 00:25:54,040
+CN. إذا هي كم طريقة صرنا ذاكرين لكم؟ طريقة السيانيد
+
+265
+00:25:54,040 --> 00:26:00,060
+جبناها ولا لأ؟ طيب خلينا نمحو كل هالكلام ونقول لو
+
+266
+00:26:00,060 --> 00:26:05,320
+إجاكم السؤال في الامتحان: اذكر الطرق لتحضير الـ
+
+267
+00:26:05,320 --> 00:26:08,440
+benzoic acid. هتقولوا: الـ aliphatic side chain، هذه
+
+268
+00:26:08,440 --> 00:26:12,620
+كلها طريقة، حتى لو من البنزين بقول: بنزين، طلوين
+
+269
+00:26:13,730 --> 00:26:17,930
+بنزويك أسد. واضح؟ لما أقول لكم بدي بنزويك أسد من
+
+270
+00:26:17,930 --> 00:26:23,090
+البنزين، شو نمشي؟ بنزين، طلوين؟ بنزويك أسد.
+
+271
+00:26:23,090 --> 00:26:28,750
+صعبة؟ من السيانيد وبنزين؟ بنعملها. طب لو قلنا بدنا
+
+272
+00:26:28,750 --> 00:26:33,090
+طريقة تالتة من البنزين
+
+273
+00:26:39,040 --> 00:26:48,920
+طريقة تالتة، بدنا بنزويك أسد من البنزين. واضحة
+
+274
+00:26:48,920 --> 00:26:58,260
+الفكرة. هي بنزين بده يصير بنزويك أسد حسب ما اتعلمنا
+
+275
+00:26:58,260 --> 00:27:03,900
+لاحظوا ما بين البنزين
+
+276
+00:27:03,900 --> 00:27:09,650
+وبنزويك أسد زيادة كربونة. ولذلك.. ولذلك إحنا قلنا
+
+277
+00:27:09,650 --> 00:27:17,870
+بطريقة ما هذه، لما صارت سيانيد قدرنا
+
+278
+00:27:17,870 --> 00:27:21,330
+نحولها لـ acid، بس ما أخذناش الطريقة اللي بتخليها
+
+279
+00:27:21,330 --> 00:27:24,970
+سيانيد لحتى الآن. الآن، ما هي طريقة الزيادة الثانية
+
+280
+00:27:24,970 --> 00:27:34,830
+اللي تعلمناها؟ غرينيارد. إذا هذا يصير كلور بنزين.
+
+281
+00:27:34,830 --> 00:27:40,590
+هذه تعلمناها ولا لأ؟ الكلورو بنزين لو فعلناه مع
+
+282
+00:27:40,590 --> 00:27:47,050
+غرينيارد مع Mg، شو بيصير؟
+
+283
+00:27:47,050 --> 00:27:56,270
+MgCl. الـ MgCl بإيش بيزيد كربونة؟ بثاني أكسيد
+
+284
+00:27:56,270 --> 00:28:03,890
+الكربون. وحمد لله. إذا بنزين، كلور بنزين، طبعاً كلكم
+
+285
+00:28:03,890 --> 00:28:06,470
+عارفين الـ reaction اللي هو Cl2
+
+286
+00:28:13,200 --> 00:28:26,560
+بنزين بيصير بنزويك أسد، بنزين بيصير
+
+287
+00:28:26,560 --> 00:28:30,080
+طلوين
+
+288
+00:28:30,080 --> 00:28:36,360
+بنزويك أسد، وبعدين KMnO4، بالـ KMnO4، إذا
+
+289
+00:28:36,360 --> 00:28:40,460
+هي البنزويك أسد بثلاث طرق. اللي بده يحفظهم أول شيء
+
+290
+00:28:40,460 --> 00:28:47,160
+يقول: بنزين، طلوين، بنزويك أسد، بنزين سيانيد، بنزين
+
+291
+00:28:47,160 --> 00:28:52,720
+بنزويك أسد، بنزين كلور، بنزين غرينيارد، بنزويك
+
+292
+00:28:52,720 --> 00:28:57,180
+أسد. كل هذه طرق لتحضير البنزويك أسد، ولا لأ؟ كانت
+
+293
+00:28:57,180 --> 00:29:02,480
+ثلاث طرق. واضح؟ وبهيك بننهي اليوم.
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/VEV_j0BJLYk_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/VEV_j0BJLYk_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..428486a9f8fb99bdcb2377917d9f4e20ac18b1a3
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/VEV_j0BJLYk_postprocess.srt
@@ -0,0 +1,1172 @@
+1
+00:00:19,460 --> 00:00:24,620
+بسم الله الرحمن الرحيم بدأنا احنا المرة الماضية في
+
+2
+00:00:24,620 --> 00:00:28,220
+موضوع الأحماض الكربوكسيلية الـ carboxylic acids
+
+3
+00:00:28,220 --> 00:00:35,460
+واستعرضنا طبعا تسميتها و الحامضية لها و بدأنا في
+
+4
+00:00:35,460 --> 00:00:40,840
+موضوع تحضير الـ carboxylic acids قلنا طبعا ان في
+
+5
+00:00:40,840 --> 00:00:47,130
+عندنا اكثر من طريقة لتحضير الـ carboxylic acidsلو
+
+6
+00:00:47,130 --> 00:00:53,190
+بدنا احنا نيجي ببساطة نتخيل هالطرق هذه لتحضير ال
+
+7
+00:00:53,190 --> 00:00:59,430
+carboxylic acids بإمكانكوا تنظروا ل الأقلام اللي
+
+8
+00:00:59,430 --> 00:01:04,590
+أنا حاملهم هدولة كام قلم؟ تلاتة .. تلاتة .. تلاتة
+
+9
+00:01:04,590 --> 00:01:05,090
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة ..
+
+10
+00:01:05,090 --> 00:01:06,070
+تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة
+
+11
+00:01:06,070 --> 00:01:06,150
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة ..
+
+12
+00:01:06,150 --> 00:01:12,410
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة
+
+13
+00:01:12,410 --> 00:01:19,640
+.. تلاتة .. تيعني أبدأ بتلات ذرات عند اللزوم كحول
+
+14
+00:01:19,640 --> 00:01:24,020
+أو aldehyde و يطلع عندى حامض من تلات ذرات يعني
+
+15
+00:01:24,020 --> 00:01:28,520
+أبدأ بتلاته و يطلع عندى تلاته و كان هذه الطريقة
+
+16
+00:01:28,520 --> 00:01:32,480
+طريقة التساوي هي الطريقة الأولى اللى بدأنا نشرحها
+
+17
+00:01:32,480 --> 00:01:36,180
+لما اتكلمنا المرة الماضية عن الكحولات و عن ال
+
+18
+00:01:36,180 --> 00:01:40,550
+aldehydesلما اتكلمنا المرة الماضية عن الكحولات و
+
+19
+00:01:40,550 --> 00:01:45,950
+عن ال aldehydes هذه الطريقة طريقة ايش تساوي يعني
+
+20
+00:01:45,950 --> 00:01:52,330
+قداش في عندى عدد كربونات في الكحول او في ال
+
+21
+00:01:52,330 --> 00:01:56,290
+aldehyde قداش بيكونوا في ال essence يعني لو الكحول
+
+22
+00:01:56,290 --> 00:02:03,000
+كانوا تلاتة معنى ذلك هيكون اسم تبعه فيه propaneأو
+
+23
+00:02:03,000 --> 00:02:06,880
+ال الديهايد كانوا تلاتة الاسم تبعه برضه هيكون فيه
+
+24
+00:02:06,880 --> 00:02:12,760
+بروفان تلاتة الآن ال acid اللي هيطلع برضه هيكون
+
+25
+00:02:12,760 --> 00:02:19,560
+تلاتة لا هيزيد ولا هينقص خلينا نشوف هذا الكلام
+
+26
+00:02:19,560 --> 00:02:24,120
+يعني مثلا لو أخدنا CH3 CH2
+
+27
+00:02:26,930 --> 00:02:35,710
+هذا ايش؟ كحول من كام كربونة؟ ثلاثة اسمه بروبان
+
+28
+00:02:35,710 --> 00:02:41,810
+البروبان بتعبر عن العدد all الان لو بدنا اكسدة
+
+29
+00:02:41,810 --> 00:02:49,430
+بسيطة في ال BCC عند اللزوم حيصير CH3 CH2 C double
+
+30
+00:02:49,430 --> 00:02:59,080
+bond OH كام ذرة؟تلاتة هذا اللي اتكون شو اسمه?
+
+31
+00:03:02,720 --> 00:03:08,000
+Ibrobanol إذا هل تغير عدد الذرات؟ لأ لو امشينا في
+
+32
+00:03:08,000 --> 00:03:12,020
+الأكسدة بالكيامان O4 عند اللزوم أو من البداية
+
+33
+00:03:12,020 --> 00:03:20,960
+بدينا بالكيامان O4 CH3 CH2 Cضم البند O OH كم ذرة
+
+34
+00:03:20,960 --> 00:03:25,500
+كربون؟ اه هذا إيش بدو يصير؟ Ibrobanol
+
+35
+00:03:28,860 --> 00:03:35,200
+وبهيك بيصير واضح معاه أن الأفكار المتعلقة بالأكسد،
+
+36
+00:03:35,200 --> 00:03:40,920
+أكسدة الكحول، الالدهاي، الاسد، لتغير عدد درات
+
+37
+00:03:40,920 --> 00:03:46,350
+الكربونواضح الفكرة؟ ولذلك هذه الطريقة .. طريقة إيش
+
+38
+00:03:46,350 --> 00:03:51,930
+بنسميها؟ طريقة تساوي .. إنه أنا عندي تلت ذرات
+
+39
+00:03:51,930 --> 00:03:56,030
+carbon .. إنه أنا عندي تلت ذرات carbon .. هدولة
+
+40
+00:03:56,030 --> 00:03:58,570
+تلت ذرات carbon .. كانوا تلاتة .. ضالوا تلاتة ..
+
+41
+00:03:58,570 --> 00:04:04,070
+ضالوا تلاتة .. واضح الفكرة؟ طبعا للناس اللي بيحبوا
+
+42
+00:04:04,070 --> 00:04:07,890
+انزيد شوية في الكلام و في المعلومات .. أنا ممكن
+
+43
+00:04:07,890 --> 00:04:12,990
+أبدأ من التلاتةبطريقة شوية صغيرة مختلفة يعني
+
+44
+00:04:12,990 --> 00:04:20,290
+مابداش بالكحول مابداش بالكحول يا ترى لو مثلا بدأت
+
+45
+00:04:20,290 --> 00:04:27,810
+بهذا المركب لو بدأت بهذا المركب CH3 CH double bond
+
+46
+00:04:27,810 --> 00:04:35,520
+CH2جبتلكم سؤال كيف من الابروب برضه ابروب ملاحظين
+
+47
+00:04:35,520 --> 00:04:40,880
+تلاتة ابروبين how can you prepare aerobic acid
+
+48
+00:04:40,880 --> 00:04:46,340
+starting from aerobin تلاتة تلاتة تلاتة تلاتة اه
+
+49
+00:04:46,340 --> 00:04:51,720
+هتيجي واحدة تتذكر ان انا هنا بدي اضيف الميه مع ولا
+
+50
+00:04:51,720 --> 00:04:56,220
+عكس قاعدة Markovnikov طبعا عكس عكس
+
+51
+00:05:05,320 --> 00:05:10,460
+واضح الفكرة فتلاتة ما زالوا تلاتة ما زالوا تلاتة
+
+52
+00:05:10,460 --> 00:05:11,320
+ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما
+
+53
+00:05:11,320 --> 00:05:11,500
+ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما
+
+54
+00:05:11,500 --> 00:05:13,440
+زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا
+
+55
+00:05:13,440 --> 00:05:15,280
+تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة
+
+56
+00:05:15,280 --> 00:05:19,440
+ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما
+
+57
+00:05:19,440 --> 00:05:28,330
+زالوا تلاتة ما زالوا تبصير acid واضح؟ الأن في هذه
+
+58
+00:05:28,330 --> 00:05:33,990
+الحالة مافيش عندى تغير في عدد ذرات الكربون فالطرق
+
+59
+00:05:33,990 --> 00:05:39,310
+المنطلقة من الأكسة ده مافيش فيها تغير بيكون بيوتان
+
+60
+00:05:39,310 --> 00:05:44,910
+بيوتانوك بيوتانول بيوتانال لكن عدد ذرات الكربون
+
+61
+00:05:44,910 --> 00:05:48,430
+إيش ماله؟ ثابت حتى لو قلت بيوتين كمان
+
+62
+00:05:55,150 --> 00:06:03,190
+الان في طرق تانية .. في طرق تانية ممكن أنه نتعامل
+
+63
+00:06:03,190 --> 00:06:09,570
+معها .. ممكن نشتغل على طريقة اسمها طريقة النقص ..
+
+64
+00:06:09,570 --> 00:06:16,000
+يعني أبدأ بتلاتةو أكسر من التلاتة هدولة و أجد
+
+65
+00:06:16,000 --> 00:06:21,820
+أبطلع بإيش نفترض ب 2 و ب 1 أكسر التلاتة أو أبدأ ب
+
+66
+00:06:21,820 --> 00:06:28,140
+4 و أكسر الأربعة ل 2 و 2 أو ل 3 و 1 هذه طريقة إيش
+
+67
+00:06:28,140 --> 00:06:33,400
+نقص أنه أنا يكون عند السلسلة الكلية السلسلة الكلية
+
+68
+00:06:33,400 --> 00:06:39,040
+أربع كربونات أطول منها 3 أو 2 أو 1 يعني أقل من إيش
+
+69
+00:06:39,560 --> 00:06:44,440
+أقل من الأربعة صارت هذه الطريقة طريقة ايش نقص طبعا
+
+70
+00:06:44,440 --> 00:06:48,660
+ايش بيظل عندنا انه ممكن تكون طريقة زيادة يعني
+
+71
+00:06:48,660 --> 00:06:53,920
+افترضوا انه سلسلة عندى أربعة وطلبت
+
+72
+00:06:53,920 --> 00:06:56,600
+منكوا تحضروا لي حمض بخمس كربونات
+
+73
+00:07:01,280 --> 00:07:08,760
+أنا قلت لكم ببساطة مبتدئا من البيوتانول البيوتانول
+
+74
+00:07:08,760 --> 00:07:14,680
+كام كربونا؟ أربعة حضرولي بنتانوك أسد الآن إذا
+
+75
+00:07:14,680 --> 00:07:19,720
+واحدة مش منتبهة تقول all oic acid تروح تعمل أكسدة
+
+76
+00:07:19,720 --> 00:07:26,520
+أه بس البيوتانول بيصير بيوتانوك أسدبزيدش Carbona
+
+77
+00:07:26,520 --> 00:07:30,960
+الان لو كنت بداجي اسألكم والله من ال Butanol
+
+78
+00:07:30,960 --> 00:07:37,890
+حضرولي Pentanoic acid زدتوا Carbonaإذا أنا بحاجة
+
+79
+00:07:37,890 --> 00:07:43,030
+إلى طريقة وبناء على ذلك للي بدوا يفهم طرق تحضير
+
+80
+00:07:43,030 --> 00:07:47,130
+الأحماض بشكل عام بنقول أن طرق تحضير الأحماض بدكوا
+
+81
+00:07:47,130 --> 00:07:51,870
+تنتبهوا تماما ممكن تكون طريقة التساوي وهذه موجودة
+
+82
+00:07:51,870 --> 00:07:55,130
+في شغل الأكسد أو الكلام اللي شرحنا الآن ممكن تكون
+
+83
+00:07:55,130 --> 00:08:01,250
+طريقة تكسير أو نقص وممكن تكون طريقة إيش؟ زيادة
+
+84
+00:08:01,250 --> 00:08:09,000
+واضحة الفكرة؟ الآن خلينا نيجيلاطرق التكثير خلّينا
+
+85
+00:08:09,000 --> 00:08:15,340
+نيجي لطرق التكثير بشكل عام نسبة من طرق التكثير مرت
+
+86
+00:08:15,340 --> 00:08:19,980
+معنا بطريقة أو باخرى ليش؟ لأنه احنا أخدنا ال
+
+87
+00:08:19,980 --> 00:08:27,460
+ozoneolysis ال ozoneolysis عادة بيكسر المركب لإيش؟
+
+88
+00:08:28,390 --> 00:08:33,650
+لأldehyde او كيتون ايه كويس الال بعد ما
+
+89
+00:08:33,650 --> 00:08:38,370
+الأوزونوليس يعني هيك انا بده اقول الكين والالكاين
+
+90
+00:08:38,370 --> 00:08:46,370
+زي الالكين بالمناسبة الكين ممكن يعطيني ايش كيتون
+
+91
+00:08:49,540 --> 00:08:53,540
+الديهايد هذا الكلام اتعلمناه ولا لأ ان الالكين
+
+92
+00:08:53,540 --> 00:08:57,600
+بيصير كيتون او الديهايد الان الكيتون اتعلمناه انه
+
+93
+00:08:57,600 --> 00:09:05,060
+لا يتأكسد اكسدة اضافية لكن ال الديهايد بتأكسد ولا
+
+94
+00:09:05,060 --> 00:09:09,860
+لأ ال الديهايد بتأكسد اكسدة اضافية بيصير ايش acid
+
+95
+00:09:09,860 --> 00:09:14,440
+الان بكل الأحوال هذا ال الديهايد هيكون اصغر من ال
+
+96
+00:09:14,440 --> 00:09:20,010
+الكين او من ال الكاين ولا لأبالتأكيد هنا هيلزمني
+
+97
+00:09:20,010 --> 00:09:25,750
+كام عملية يتموا ورا بعض عمليتين العملية الأولى ال
+
+98
+00:09:25,750 --> 00:09:31,630
+ozoneolysis و العملية التانية ال oxidation خلّيني
+
+99
+00:09:31,630 --> 00:09:35,990
+أعبّر عنها ب O بين جثين Oxidation عملية أكسدة عادة
+
+100
+00:09:35,990 --> 00:09:41,430
+بيستعملونها H2O2 الهيدروجين بيروكسايد هذه كمان
+
+101
+00:09:41,430 --> 00:09:49,310
+خلّوها H2O2أذن اوزونوليسيز followed by H2O2 يمكن
+
+102
+00:09:49,310 --> 00:09:55,050
+أن يؤدي إلى أحماض لكن أكيد هتكون أصغر من إيش؟ أصغر
+
+103
+00:09:55,050 --> 00:10:02,090
+من الألكين اللي أنا ابتدأت فيه الآن خلينا ناخد
+
+104
+00:10:02,090 --> 00:10:06,910
+مثال حقيقي ناخد مثال حقيقي لو يا ترى أخدنا هذا
+
+105
+00:10:06,910 --> 00:10:16,980
+الألكينسواء قلنا عنه CES و لا TRANS CH3 CH3H
+
+106
+00:10:16,980 --> 00:10:26,200
+CH3H و قلنا اكمل نمر واحد O3 Ozonolysis و نمر
+
+107
+00:10:26,200 --> 00:10:31,060
+اتنين H2O2 H2O2 Hydrogen Peroxide هو العامل
+
+108
+00:10:31,060 --> 00:10:39,210
+المؤكسد الان بدنا لما ننفذ نفهم الشغل الاولىكسر
+
+109
+00:10:39,210 --> 00:10:47,350
+يعني C double bond O H و CH3 زائد C double bond OH
+
+110
+00:10:47,350 --> 00:10:55,750
+و CH3 هذا ال ozonolases طب و ال acid هذا إيش؟
+
+111
+00:10:55,750 --> 00:11:00,830
+الديهايد الآن هذا ال الديهايد بال H2O2 اللي ضفناها
+
+112
+00:11:00,830 --> 00:11:08,760
+إيش حيصير؟ C double bond O OHCH3 وجدت حصلنا على
+
+113
+00:11:08,760 --> 00:11:14,980
+الاسيتك أسد الاسيتك أسد كده؟ كربون 2 يعني كأنه انا
+
+114
+00:11:14,980 --> 00:11:18,820
+بال اوزونوليسيز اتيت كصرت الأربعة هدولة اتنين و
+
+115
+00:11:18,820 --> 00:11:23,400
+اتنين طلعوا عندي ألديهيد الآن كملت أكسدت الألديهيد
+
+116
+00:11:23,400 --> 00:11:29,060
+صار اسيتك أسد فمن الأربعة حصلت على حامض من كام
+
+117
+00:11:29,060 --> 00:11:37,890
+كربون؟ تنتين واضحة الفكرة؟ طبعا الآناللي ممكن
+
+118
+00:11:37,890 --> 00:11:44,390
+يفكروا انه نتعمق معهم بمثل هذه الفكرة ممكن نيجي
+
+119
+00:11:44,390 --> 00:11:49,910
+نسألهم، مانقول هم مش مبتدئان من ال 2 بيوتين، لو
+
+120
+00:11:49,910 --> 00:11:55,930
+بدأت من ال one بيوتين، هيطلع عند أحمد واحد و تلاتة
+
+121
+00:11:56,580 --> 00:12:00,520
+لأن هذه هتكسر كربونا و هدول يكونوا تلاتة لكن لو
+
+122
+00:12:00,520 --> 00:12:07,080
+انا اجيت و قولتلكم والله من مركب زي هذا CH3 CH2 CH
+
+123
+00:12:07,080 --> 00:12:15,560
+سواء حطيت هنا CL او OH اتخيلوا ان انا اجي اقولكم
+
+124
+00:12:15,560 --> 00:12:23,720
+من two chlorobutane حضروا لي acidic acid واضح او
+
+125
+00:12:23,720 --> 00:12:28,880
+من two butanolبتكون تعملوا elimination الان ال CL
+
+126
+00:12:28,880 --> 00:12:32,320
+و ال H بيروحوا و بيعطينا ال more substituted
+
+127
+00:12:32,320 --> 00:12:37,280
+باستعمال ايش طلعت
+
+128
+00:12:37,280 --> 00:12:44,240
+انا ال alkyd و بعدين كسرت ال alkyd هذه الطرق و مع
+
+129
+00:12:44,240 --> 00:12:47,020
+ال triple bond نفس الاشي زي ال double bond هذه
+
+130
+00:12:47,020 --> 00:12:52,180
+الطرق تعتبر طرق ايشانقاس يعني كان عندى اربع
+
+131
+00:12:52,180 --> 00:12:56,720
+كربونات اعملت حامض من كربونتين اعملت حامض من تلات
+
+132
+00:12:56,720 --> 00:13:02,840
+كربونات حسب موقع ايش ال bubble bond بس بشرط انه
+
+133
+00:13:02,840 --> 00:13:06,660
+يكون من نتائج ال ozonosis انه بتكون aldehyde ليش؟
+
+134
+00:13:06,660 --> 00:13:10,820
+لأن اللى بيكمل وبيتأكسد ال aldehyde الكيتون بقولنا
+
+135
+00:13:10,820 --> 00:13:16,140
+فيه إله أكسدة إضافية؟ لأ واضحة الفكرة؟ اللى بيكمل
+
+136
+00:13:16,140 --> 00:13:21,210
+وبيتأكسد هو مين؟الالديهايد وهذا الكلام أخدناه في
+
+137
+00:13:21,210 --> 00:13:24,090
+أكسدة الالديهايد والكيتونز قلنا الالديهايد بتصير
+
+138
+00:13:24,090 --> 00:13:30,430
+أحمار الكيتونز لاتت أكسد أكسدة إضافية واضحة الفكرة
+
+139
+00:13:30,430 --> 00:13:37,150
+طيب
+
+140
+00:13:37,150 --> 00:13:45,300
+إذا عرفنا طريقة المساواة وطريقةالنقص ايش ضال
+
+141
+00:13:45,300 --> 00:13:51,140
+عندنا؟ طريقة الزيادة بمعنى لو انا اجيت وقلتلكم لو
+
+142
+00:13:51,140 --> 00:13:56,240
+سمحتوا من تلت كربونات بدي احضر حامض من اربع
+
+143
+00:13:56,240 --> 00:14:03,000
+كربونات عادة الزيادة اللي احنا بنعملها زيادة سهلة
+
+144
+00:14:03,480 --> 00:14:07,900
+ليه؟ كربونة واحدة هي اللي بتتم بسهولة يعني التلاتة
+
+145
+00:14:07,900 --> 00:14:13,160
+يصيروا أربعة، الأربعة يصيروا خمسة، الخمسة يصيروا
+
+146
+00:14:13,160 --> 00:14:17,680
+ستة كيف هذا الكلام .. كيف هذا الكلام بتم؟ هذا
+
+147
+00:14:17,680 --> 00:14:26,500
+الكلام عادة بتتممنطلقين فيه من ال الكل هلاي من ال
+
+148
+00:14:26,500 --> 00:14:33,040
+one chloro compound واضح يعني بدي مركب سلسلة يكون
+
+149
+00:14:33,040 --> 00:14:39,300
+على موقع واحد فيها إيش إكلور بدي سلسلة على موقع
+
+150
+00:14:39,300 --> 00:14:47,340
+واحد فيها إكلور يعني مثلا زي ما اقول CH3 CH2 CH2
+
+151
+00:14:47,340 --> 00:14:56,390
+CLالان الكلور هانا وين؟ على موقع واحد هذا الكلور
+
+152
+00:14:56,390 --> 00:15:00,050
+مكانه بدي ازيد كربونا اللي هي بده تكون حاملة
+
+153
+00:15:00,050 --> 00:15:06,320
+مجموعة الاسم عدد الكربونات الكل يعني قداشتلاتة بدي
+
+154
+00:15:06,320 --> 00:15:11,720
+أحضر من هذا butanoic acid يعني كام كربونا؟ أربعة
+
+155
+00:15:11,720 --> 00:15:16,640
+في عندى طريقتين ممكنين في عندى طريقتين ممكنين
+
+156
+00:15:16,640 --> 00:15:22,920
+الطريقة الأولى أنه أنا هذا أجي أفعله مع CN minus
+
+157
+00:15:22,920 --> 00:15:28,140
+والطريقة التانية أنه أنا هذا أفعله مع green yard
+
+158
+00:15:28,140 --> 00:15:34,560
+reagentمار عليكم المغنيسيا من اللي بيعطي RMGX طيب
+
+159
+00:15:34,560 --> 00:15:38,720
+لو فعلنا مع ال cyanide شو بده يصير هذا؟ بده يصير
+
+160
+00:15:38,720 --> 00:15:49,220
+CH3 CH2 CH2 و هنا بده تيجي مجموعة ال CN لاحظوا هنا
+
+161
+00:15:49,220 --> 00:15:54,120
+بينت الكربون الرابعة ولا لأ هيصاروا كام كربونة؟
+
+162
+00:15:55,060 --> 00:16:02,160
+أربعة بدل تلاتة الان ال cyanide بشكل عام لو عملتله
+
+163
+00:16:02,160 --> 00:16:11,340
+hydrolysis يا إما ب H3O plus بيمشي الحال أو ب N-A
+
+164
+00:16:11,340 --> 00:16:15,840
+-O-H و بعدين H plus يعني يا إما بهذا ال reagent يا
+
+165
+00:16:15,840 --> 00:16:20,100
+إما بهذا ال reagent بأي واحد منهم بيمشي بصير أسلوب
+
+166
+00:16:20,870 --> 00:16:24,310
+يعني ال cyanide بيعملها hydrolysis ال acid و بعدها
+
+167
+00:16:24,310 --> 00:16:34,310
+شو هيصير CH3 CH2 CH2 و هذه ال C هي اللي ضالت هتصير
+
+168
+00:16:34,310 --> 00:16:41,610
+C double bond O OH اذا انا ال chlorine حولتها ل CN
+
+169
+00:16:41,610 --> 00:16:48,530
+و ال CN ع طول بتصير COOHهذه طريقة معروفة وجيدة
+
+170
+00:16:48,530 --> 00:16:53,750
+لعمل هذا المُركّب طيب الطريقة التانية .. بدأ أزيد
+
+171
+00:16:53,750 --> 00:16:58,310
+كربونا لسه .. أنا لو فعلت مع المغنيسيوم .. هذا إيش
+
+172
+00:16:58,310 --> 00:17:04,750
+هيعطيني؟ الـ Grignard Reagent .. كلكم اتذكرينه؟CH3
+
+173
+00:17:04,750 --> 00:17:13,470
+CH2 CH2 وقلنا هذه اهم اشي فيها MgCl هاي Green Yard
+
+174
+00:17:13,470 --> 00:17:18,630
+Ray Agent إبروبيل مغنيسيا ميكلورايد صح؟ الآن هذا
+
+175
+00:17:18,630 --> 00:17:25,330
+ال Green Yard Ray Agent بفعله مع نمرة واحد CO2
+
+176
+00:17:25,330 --> 00:17:28,250
+لاحظوا هاي ال C double bond O double bond O ثاني
+
+177
+00:17:28,250 --> 00:17:29,030
+أكسيد كربون
+
+178
+00:17:31,920 --> 00:17:38,840
+واضح؟ ونمر اتنين خليني ال CO2 ارسمه بالاحمر بفعله
+
+179
+00:17:38,840 --> 00:17:43,220
+مع ال CO2 يعني C double bond O double bond O ونمر
+
+180
+00:17:43,220 --> 00:17:49,000
+اتنين مع H بلس بيعطيني الحامض اللي هتقولولي من وين
+
+181
+00:17:49,000 --> 00:17:54,710
+اجت الكربونة؟هي من الـ CO2 مش الـ C حاملة انتن
+
+182
+00:17:54,710 --> 00:17:59,370
+أكسجين وهنا إيش زاد عندي؟ C double bond O OH
+
+183
+00:17:59,370 --> 00:18:06,590
+ببساطة هذا نيوكليوفايل بيهاجم هنا بيهاجم على
+
+184
+00:18:06,590 --> 00:18:09,990
+الكربون الموجبة مش الكربون بتاع تاني أكسيد الكربون
+
+185
+00:18:09,990 --> 00:18:15,050
+الموجبة لأنه جنبها مجموعتين سالبات لما يهاجم هذا
+
+186
+00:18:15,050 --> 00:18:20,250
+بتصير O minus ومن ال H plus بتاخد H إيش بتصير؟ OH
+
+187
+00:18:21,350 --> 00:18:27,040
+إذا هنا مصدر الكربونة الجديدة إيش بيكون؟الـ CO2
+
+188
+00:18:27,040 --> 00:18:31,720
+إذا أنا لما بدي أعمل الزيادة بدي مصدر للكربونة
+
+189
+00:18:31,720 --> 00:18:36,540
+الجديدة مصدر الكربونة الجديدة يا بدي يكون ال CN و
+
+190
+00:18:36,540 --> 00:18:39,340
+بعدين أعمل ال hydrolysis يا بعمل ال green yard
+
+191
+00:18:39,340 --> 00:18:43,280
+reagent و الكربونة الجديدة بجيبها من وين؟ من ال
+
+192
+00:18:43,280 --> 00:18:50,340
+CO2 واضح الفكرة؟ الآن مرة تانية مش ضروري تكون نقطة
+
+193
+00:18:50,340 --> 00:18:57,860
+البداية اللي عندى هي هذا المركب الكلوريممكن تكون
+
+194
+00:18:57,860 --> 00:19:02,180
+نقطة البداية الكحول الان الكحول بقدر اخليك low
+
+195
+00:19:02,180 --> 00:19:07,140
+right في الخطوة الأولى بالإبدال كحول مع O H minus
+
+196
+00:19:07,140 --> 00:19:17,960
+بيعمل إبدال ممكن تكون نقطة البداية الالكين هذه
+
+197
+00:19:17,960 --> 00:19:19,900
+الالكين بتلت كربونات
+
+198
+00:19:29,710 --> 00:19:35,570
+واضحة الفكرة فهذه
+
+199
+00:19:35,570 --> 00:19:41,830
+طرق الزيادة اللى عادة بنستعملها من خلال ال CN أو
+
+200
+00:19:41,830 --> 00:19:42,630
+ال CO2
+
+201
+00:19:52,800 --> 00:19:54,940
+هنا على السلسلة هذه
+
+202
+00:20:03,960 --> 00:20:08,640
+لأ لأ لأ لأ لأ ال chlorineation ال chlorineation
+
+203
+00:20:08,640 --> 00:20:13,260
+على السلسلة أخدناها ب CL2 في وجود ضوء أو حرارة أو
+
+204
+00:20:13,260 --> 00:20:16,560
+من خلال الإضافة ع ال double bond يعني ال chlorine
+
+205
+00:20:16,560 --> 00:20:20,600
+مع ال FeCl3 هذا على ال aromatic compounds هذا على
+
+206
+00:20:20,600 --> 00:20:28,580
+ال aromatic compounds تمام بضل في عندى ال benzoic
+
+207
+00:20:28,580 --> 00:20:35,710
+acidعارفين البنزويك أسد؟ كيف ممكن نحضر البنزويك
+
+208
+00:20:35,710 --> 00:20:40,970
+أسد؟ و مرات ممكن نسأل كيف ممكن تحضروا البنزويك أسد
+
+209
+00:20:40,970 --> 00:20:44,370
+من البنزين هاي البنزويك أسد
+
+210
+00:20:53,780 --> 00:20:59,240
+سهلة ان لو انا عندى cyanobenzene بصير benzoic acid
+
+211
+00:20:59,240 --> 00:21:05,480
+هذه الطريقة خلينى نقول ايش مالها سهلة CN اذا عندى
+
+212
+00:21:05,480 --> 00:21:11,740
+cyanobenzene في وجود H plus او NaOH نمرة واحد و
+
+213
+00:21:11,740 --> 00:21:15,320
+نمرة اتنين H plus زى ما حكينا قبل شوية ال
+
+214
+00:21:15,320 --> 00:21:21,420
+cyanobenzene بصير acid فيها مشكلةطبعا هيصير السؤال
+
+215
+00:21:21,420 --> 00:21:26,080
+كيف يتحضر السيانو بنزين .. سيانو بنزين في شبطر 11
+
+216
+00:21:26,080 --> 00:21:31,510
+بنتعلم تحضيرهبيجيش مباشر بقتش CN لأ اللي طريقة
+
+217
+00:21:31,510 --> 00:21:37,250
+التفافية ال CN و البنزين بيجيش بشكل مباشر بتحضرش
+
+218
+00:21:37,250 --> 00:21:41,630
+بشكل مباشر انه بنزين ماقتش CN ليش؟ لإن ال CN minus
+
+219
+00:21:41,630 --> 00:21:45,590
+و البنزين حاملة إلكترونات بيهاجمش minus على minus
+
+220
+00:21:45,590 --> 00:21:51,270
+طمام الطريقة التانية انه لو احنا أخدنا .. نخلص من
+
+221
+00:21:51,270 --> 00:21:56,770
+هذه الطريقة و نمحاها لو احنا أخدنا أي بنزين بيحمل
+
+222
+00:21:56,770 --> 00:22:02,490
+ال kilogramإيش في بنزين بيحمل الكل جروب؟ الطلوين
+
+223
+00:22:02,490 --> 00:22:05,670
+صح؟
+
+224
+00:22:05,670 --> 00:22:13,890
+CH3 إيش ممكن كمان؟ ال F البنزين CH2 CH3 إيش كمان
+
+225
+00:22:13,890 --> 00:22:26,110
+ممكن؟ القيومين CH CH3 CH3 كل هدولة بيحملوهالكلي
+
+226
+00:22:26,110 --> 00:22:29,950
+جروبز ممكن حد يفكر كمان بال تيرتشار بيوت البنزين
+
+227
+00:22:29,950 --> 00:22:36,610
+ممكن حد يفكر بال تيرتشار بيوت البنزين الآن بنقول
+
+228
+00:22:36,610 --> 00:22:43,230
+القاتل لو استعملنا عام المؤكسد بشكل عام ال KMnO4
+
+229
+00:22:43,230 --> 00:22:48,710
+برمجانات البوتاسيوم مع أي ألكل بنزين مع أي ألكل
+
+230
+00:22:48,710 --> 00:22:54,480
+بنزين بس بشرطالكربون المتصل على البنزين مباشرة
+
+231
+00:22:54,480 --> 00:22:59,040
+تحتوي على ذرة هيدروجين على اقل تقدير الان هذه
+
+232
+00:22:59,040 --> 00:23:03,540
+الكربون .. كم هيدروجين بتحمل؟ تلاتة .. هذه .. هذه
+
+233
+00:23:03,540 --> 00:23:08,000
+.. هذه .. ولا واحدة .. اذا هدولة التلاتة بيمشي
+
+234
+00:23:08,000 --> 00:23:14,540
+حالهمأى واحدة من هدول بالأكسدة بكامان of four
+
+235
+00:23:14,540 --> 00:23:18,820
+بتعطينا بنزويك أسل الان انتبهوا معي لنقطة كتير
+
+236
+00:23:18,820 --> 00:23:26,100
+مهمة انه بغض النظر عن طول السلسلة هنطلع بس بنزويك
+
+237
+00:23:26,100 --> 00:23:30,960
+أسل يعني لو كان هنا مثل او اثل او بروبل او بيوتل
+
+238
+00:23:30,960 --> 00:23:34,760
+كربونة او تنتين او تلاتة او اربعة او خمسة او عشرة
+
+239
+00:23:35,740 --> 00:23:40,220
+بس هطلعوا إيش ال benzoic acid مرات كتير لما بنيجي
+
+240
+00:23:40,220 --> 00:23:44,620
+بنسأل الطلاب بنقولهم الله أعملونا أكسدة بنزين حامل
+
+241
+00:23:44,620 --> 00:23:47,340
+تلت كربونات بيروحوا بيخلوا الكربونتين و بيعملوا
+
+242
+00:23:47,340 --> 00:23:51,640
+الأكسدة على التالتة افهمتوا الغلطة اللي بحكيها ولا
+
+243
+00:23:51,640 --> 00:24:00,600
+أوضحها أكتر لما أجي أرسملهم مركب زي هذا CH2 CH2
+
+244
+00:24:00,600 --> 00:24:07,120
+CH3 و أقولهم بالكمان O4الآن الغلطة اللي بيعملوه
+
+245
+00:24:07,120 --> 00:24:11,900
+بيعملوا ال acid هانا و بيخلوها دولة الجواب الصحيح
+
+246
+00:24:11,900 --> 00:24:15,620
+انه سواء كانوا دول واحدة او تنتين او تلاتة او
+
+247
+00:24:15,620 --> 00:24:20,720
+اربعة او عشرة بس بتكون عند هانا مجموعة ال acid
+
+248
+00:24:20,720 --> 00:24:27,240
+COOHبمعنى أنا بشرحش ميكانيزم متفق انه بدنيش ادخل
+
+249
+00:24:27,240 --> 00:24:31,180
+كتير بتفاصيل يعني خليني في النتائج بمعنى لو انا
+
+250
+00:24:31,180 --> 00:24:38,120
+اجيت سألتكم و قولتلكم انه تفاعل الطلوين والاكيومين
+
+251
+00:24:38,120 --> 00:24:42,120
+اه انتبهوا معاك الطلوين والاكيومين مع الكيامة ال
+
+252
+00:24:42,120 --> 00:24:47,990
+O4 both produces benzoic acid صحبينما لو كان
+
+253
+00:24:47,990 --> 00:24:52,390
+السؤال تفاعل الطلوين والـ tertiary بيوت البنزين
+
+254
+00:24:52,390 --> 00:24:56,490
+هذا لأ لأن هذا مافيش عليه هيدروجينة على الكاربون
+
+255
+00:24:56,490 --> 00:25:03,190
+المتصلة مباشرة بالبنزينة واضحة الفكرة؟ فعشان اتم
+
+256
+00:25:03,190 --> 00:25:06,810
+هذا النوع من الأكسدة هذا بنسميه oxidation of the
+
+257
+00:25:06,810 --> 00:25:12,290
+aliphatic sided chain مش هذه سلسلة معلقة على
+
+258
+00:25:12,290 --> 00:25:18,730
+البنزينولذلك هذا التفاعل اسمه أكسدت السلسلة
+
+259
+00:25:18,730 --> 00:25:24,110
+المعلقة على البنزين، مهما كبرت ومهما عظمت، ايش
+
+260
+00:25:24,110 --> 00:25:31,750
+بتعطيني؟ acid، بس، بغض النظر عن طولهاواضح؟
+
+261
+00:25:31,750 --> 00:25:36,530
+Oxidation of the aliphatic sided chain attached to
+
+262
+00:25:36,530 --> 00:25:41,330
+benzene واضحة الفكرة؟ هذه طريقة لتحضير ال benzoic
+
+263
+00:25:41,330 --> 00:25:46,570
+acid طبعا احنا جيبنا طريقة تانية باستعمال إيش؟ ال
+
+264
+00:25:46,570 --> 00:25:54,040
+CN إذا هي كام طريقة صيرنا ذاكرين لكم؟طريقة السيانة
+
+265
+00:25:54,040 --> 00:26:00,060
+جيبناها ولا لأ؟ طيب خلينا نمحا كل هالكلام ونقول لو
+
+266
+00:26:00,060 --> 00:26:05,320
+إجاكم السؤال في الامتحان ابتلى الطرق حضرولي ال
+
+267
+00:26:05,320 --> 00:26:08,440
+benzoic acid هتقولوا ال aliphatic side chain هذه
+
+268
+00:26:08,440 --> 00:26:12,620
+كلها طريقة حتى لو من البنزين بقول بنزين طلوين
+
+269
+00:26:13,730 --> 00:26:17,930
+بنزويك أسد واضح؟ لما أقولكوا بدي بنزويك أسد من
+
+270
+00:26:17,930 --> 00:26:23,090
+البنزين، شو هانمشي؟ بنزين طول وين؟ بنزويك أسد
+
+271
+00:26:23,090 --> 00:26:28,750
+صعبة؟ من السيان و بنزين؟ ابنعملها طب لو قولنا بدنا
+
+272
+00:26:28,750 --> 00:26:33,090
+طريقة تالتة من البنزين
+
+273
+00:26:39,040 --> 00:26:48,920
+طريقة تالتة بد بنزويك أسد من البنزين واضحة
+
+274
+00:26:48,920 --> 00:26:58,260
+الفكرة هي بنزين بد يصير بنزويك أسد حسب ما اتعلمنا
+
+275
+00:26:58,260 --> 00:27:03,900
+لاحظوا ما بين البنزين
+
+276
+00:27:03,900 --> 00:27:09,650
+و بنزويك أسد زيادة كربونةولذلك .. و لذلك احنا قلنا
+
+277
+00:27:09,650 --> 00:27:17,870
+بطريقة ما هذه لما صارت سيانو اقدرنا
+
+278
+00:27:17,870 --> 00:27:21,330
+نحولها ل acid بس مااخدناش الطريقة اللي بتخليها
+
+279
+00:27:21,330 --> 00:27:24,970
+سيانو لحتى الان الان ما طريقة الزيادة التانية
+
+280
+00:27:24,970 --> 00:27:34,830
+اللتي تعلمناها اغرينيا اذا هذا يصير اكلوروبنزين
+
+281
+00:27:34,830 --> 00:27:40,590
+هذه تعلمناها ولا لأالكلورو بنزين لو فعلناه معي
+
+282
+00:27:40,590 --> 00:27:47,050
+green yard مع Mg شو بيصير؟
+
+283
+00:27:47,050 --> 00:27:56,270
+MgCl ال MgCl بإيش بيزيد كربونا؟ بتاني أكسيد
+
+284
+00:27:56,270 --> 00:28:03,890
+الكربون وحمد إذا بنزين كلورو بنزين طبعا كلكوا
+
+285
+00:28:03,890 --> 00:28:06,470
+عارفين ال reaction اللي هو Cl2
+
+286
+00:28:13,200 --> 00:28:26,560
+بنزين بيصير بنزويك أسد بنزين بيصير
+
+287
+00:28:26,560 --> 00:28:30,080
+طلوين
+
+288
+00:28:30,080 --> 00:28:36,360
+بنزويك أسدو بعدين كيامان افور بالكيامان افور اذا
+
+289
+00:28:36,360 --> 00:28:40,460
+هى البنزويك اسد بتلات طرق اللى بده يحفظهم اول شى
+
+290
+00:28:40,460 --> 00:28:47,160
+يقول بنزين طلوين بنزويك اسد بنزين سيانو بنزين
+
+291
+00:28:47,160 --> 00:28:52,720
+بنزويك اسد بنزين كلورو بنزين بنزين جرينيارد بنزويك
+
+292
+00:28:52,720 --> 00:28:57,180
+اسد كل هذه طرق لتحضير البنزويك اسد ولا لأ كان
+
+293
+00:28:57,180 --> 00:29:02,480
+طريقة تلاتة واضح وبهيك بننهي اليوم
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/VEV_j0BJLYk_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/VEV_j0BJLYk_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..0c00532793b4d58cbd314874e035a70b891b579b
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/VEV_j0BJLYk_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4506, "start": 19.46, "end": 45.06, "text": "بسم الله الرحمن الرحيم بدأنا احنا المرة الماضية في موضوع الأحماض الكربوكسيلية الـ carboxylic acids واستعرضنا طبعا تسميتها و الحامضية لها و بدأنا في موضوع تحضير الـ carboxylic acids قلنا طبعا ان في عندنا اكثر من طريقة لتحضير الـ carboxylic acids", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 47525, 10721, 8315, 1975, 5016, 8315, 9673, 25720, 9673, 46958, 10632, 8978, 3714, 2407, 11242, 45367, 16247, 35571, 46958, 33251, 25513, 2407, 4117, 3794, 26895, 10632, 2423, 39184, 1032, 4995, 88, 1050, 21667, 36764, 14851, 3615, 43042, 8315, 23032, 3555, 3615, 995, 6055, 38251, 36081, 11296, 4032, 21542, 10943, 11242, 10632, 5296, 11296, 4032, 47525, 10721, 8315, 8978, 3714, 2407, 11242, 45367, 6055, 5016, 11242, 13546, 2423, 39184, 1032, 4995, 88, 1050, 21667, 12174, 1211, 8315, 23032, 3555, 3615, 995, 16472, 8978, 43242, 8315, 1975, 4117, 49115, 9154, 23032, 16572, 28671, 5296, 2655, 5016, 11242, 13546, 2423, 39184, 1032, 4995, 88, 1050, 21667], "avg_logprob": -0.1380669205589632, "compression_ratio": 2.045685279187817, "no_speech_prob": 6.556510925292969e-07, "words": [{"start": 19.46, "end": 20.04, "word": "بسم", "probability": 0.90185546875}, {"start": 20.04, "end": 20.24, "word": " الله", "probability": 0.96728515625}, {"start": 20.24, "end": 20.6, "word": " الرحمن", "probability": 0.9684244791666666}, {"start": 20.6, "end": 21.04, "word": " الرحيم", "probability": 0.994140625}, {"start": 21.04, "end": 23.26, "word": " بدأنا", "probability": 0.8909505208333334}, {"start": 23.26, "end": 23.56, "word": " احنا", "probability": 0.8318684895833334}, {"start": 23.56, "end": 24.04, "word": " المرة", "probability": 0.9599609375}, {"start": 24.04, "end": 24.5, "word": " الماضية", "probability": 0.9884440104166666}, {"start": 24.5, "end": 24.62, "word": " في", "probability": 0.7822265625}, {"start": 24.62, "end": 25.14, "word": " موضوع", "probability": 0.9805908203125}, {"start": 25.14, "end": 25.94, "word": " الأحماض", "probability": 0.8927408854166666}, {"start": 25.94, "end": 26.88, "word": " الكربوكسيلية", "probability": 0.9278041294642857}, {"start": 26.88, "end": 27.14, "word": " الـ", "probability": 0.3529052734375}, {"start": 27.14, "end": 27.68, "word": " carboxylic", "probability": 0.78570556640625}, {"start": 27.68, "end": 28.22, "word": " acids", "probability": 0.693359375}, {"start": 28.22, "end": 31.2, "word": " واستعرضنا", "probability": 0.861083984375}, {"start": 31.2, "end": 31.56, "word": " طبعا", "probability": 0.9111328125}, {"start": 31.56, "end": 32.44, "word": " تسميتها", "probability": 0.968017578125}, {"start": 32.44, "end": 32.58, "word": " و", "probability": 0.5390625}, {"start": 32.58, "end": 33.28, "word": " الحامضية", "probability": 0.8824462890625}, {"start": 33.28, "end": 33.78, "word": " لها", "probability": 0.735595703125}, {"start": 33.78, "end": 34.4, "word": " و", "probability": 0.71337890625}, {"start": 34.4, 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Ibrobanol إذا هل تغير عدد الذرات؟ لأ لو امشينا في الأكسدة بالكيامان O4 عند اللزوم أو من البداية بدينا بالكيامان O4 CH3 CH2 Cضم البند O OH كم ذرة كربون؟ اه هذا إيش بدو يصير؟ Ibrobanol", "tokens": [2655, 1211, 9307, 3660, 23758, 13672, 1829, 1975, 2655, 30544, 13412, 2407, 24525, 2304, 3224, 30, 286, 1443, 996, 282, 401, 11933, 15730, 8032, 1211, 6055, 17082, 13546, 6225, 3215, 3215, 32545, 2288, 9307, 22807, 5296, 10721, 45164, 1975, 2304, 8592, 1829, 8315, 8978, 16247, 4117, 3794, 41891, 20666, 4117, 1829, 10943, 7649, 422, 19, 43242, 13672, 11622, 20498, 34051, 9154, 29739, 28259, 10632, 47525, 1829, 8315, 20666, 4117, 1829, 10943, 7649, 422, 19, 5995, 18, 5995, 17, 383, 11242, 2304, 29739, 41260, 422, 13931, 9122, 2304, 29910, 25720, 9122, 25513, 11536, 22807, 1975, 3224, 23758, 11933, 1829, 8592, 47525, 2407, 7251, 9381, 13546, 22807, 286, 9120, 5144, 401], "avg_logprob": -0.27272727950052783, "compression_ratio": 1.6355140186915889, "no_speech_prob": 5.960464477539063e-08, "words": 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"word": " بدينا", "probability": 0.7841796875}, {"start": 192.34, "end": 192.82, "word": " بالكيامان", "probability": 0.96396484375}, {"start": 192.82, "end": 193.16, "word": " O4", "probability": 0.9443359375}, {"start": 193.16, "end": 194.42, "word": " CH3", "probability": 0.9365234375}, {"start": 194.42, "end": 196.36, "word": " CH2", "probability": 0.899169921875}, {"start": 196.36, "end": 197.32, "word": " Cضم", "probability": 0.5579427083333334}, {"start": 197.32, "end": 197.78, "word": " البند", "probability": 0.760498046875}, {"start": 197.78, "end": 198.28, "word": " O", "probability": 0.2213134765625}, {"start": 198.28, "end": 200.02, "word": " OH", "probability": 0.73681640625}, {"start": 200.02, "end": 200.66, "word": " كم", "probability": 0.708251953125}, {"start": 200.66, "end": 200.96, "word": " ذرة", "probability": 0.80126953125}, {"start": 200.96, "end": 201.78, "word": " كربون؟", "probability": 0.832275390625}, {"start": 201.78, "end": 202.56, "word": " اه", "probability": 0.5264892578125}, {"start": 202.56, "end": 202.9, "word": " هذا", "probability": 0.76611328125}, {"start": 202.9, "end": 203.1, "word": " إيش", "probability": 0.85986328125}, {"start": 203.1, "end": 203.32, "word": " بدو", "probability": 0.51513671875}, {"start": 203.32, "end": 203.92, "word": " يصير؟", "probability": 0.8642578125}, {"start": 203.92, "end": 205.5, "word": " Ibrobanol", "probability": 0.81396484375}], "temperature": 1.0}, {"id": 8, "seek": 22162, "start": 208.86, "end": 221.62, "text": "وبهيك بيصير واضح معاه أن الأفكار المتعلقة بالأكسد، أكسدة الكحول، الالدهاي، الاسد، لتغير عدد درات الكربون", "tokens": [37746, 3224, 1829, 4117, 4724, 1829, 9381, 13546, 4032, 46958, 5016, 20449, 40294, 14739, 16247, 5172, 4117, 9640, 9673, 2655, 30241, 28671, 20666, 10721, 4117, 3794, 3215, 12399, 5551, 4117, 3794, 41891, 33251, 5016, 12610, 12399, 2423, 6027, 3215, 3224, 47302, 12399, 2423, 32277, 3215, 12399, 5296, 2655, 17082, 13546, 6225, 3215, 3215, 11778, 2288, 9307, 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cyanobenzene بصير acid فيها مشكلة", "tokens": [3794, 3224, 37977, 16472, 45164, 1975, 8315, 43242, 7578, 47463, 996, 11368, 1450, 4724, 9381, 13546, 44335, 78, 299, 8258, 29538, 41950, 16572, 28671, 16490, 1211, 9957, 7578, 8717, 39648, 1975, 1829, 8592, 3714, 6027, 11296, 8608, 3224, 37977, 14589, 1975, 15730, 43242, 7578, 47463, 996, 11368, 1450, 8978, 49610, 23328, 389, 1804, 1975, 2407, 6056, 31187, 8717, 2304, 25720, 36764, 24401, 4032, 8717, 2304, 25720, 1975, 2655, 1863, 9957, 389, 1804, 30767, 7578, 19446, 11331, 4117, 1829, 8315, 12174, 36150, 13412, 2407, 10632, 2423, 47463, 996, 11368, 1450, 4724, 9381, 13546, 8258, 8978, 11296, 37893, 28820, 3660], "avg_logprob": -0.2035984836443506, "compression_ratio": 1.648780487804878, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1253.78, "end": 1254.52, "word": "سهلة", "probability": 0.8304036458333334}, {"start": 1254.52, "end": 1255.22, "word": " ان", "probability": 0.464599609375}, {"start": 1255.22, "end": 1255.46, 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"end": 1719.42, "word": " بده", "probability": 0.82958984375}, {"start": 1719.42, "end": 1719.94, "word": " يحفظهم", "probability": 0.87294921875}, {"start": 1719.94, "end": 1720.24, "word": " اول", "probability": 0.58251953125}, {"start": 1720.24, "end": 1720.46, "word": " شى", "probability": 0.44183349609375}, {"start": 1720.46, "end": 1720.86, "word": " يقول", "probability": 0.779296875}, {"start": 1720.86, "end": 1722.48, "word": " بنزين", "probability": 0.9358723958333334}, {"start": 1722.48, "end": 1723.14, "word": " طلوين", "probability": 0.81219482421875}, {"start": 1723.14, "end": 1724.76, "word": " بنزويك", "probability": 0.97119140625}, {"start": 1724.76, "end": 1725.18, "word": " اسد", "probability": 0.7816569010416666}, {"start": 1725.18, "end": 1726.0, "word": " بنزين", "probability": 0.962890625}, {"start": 1726.0, "end": 1726.5, "word": " سيانو", "probability": 0.9013671875}, {"start": 1726.5, "end": 1727.16, "word": " بنزين", "probability": 0.9755859375}, {"start": 1727.16, "end": 1728.54, "word": " بنزويك", "probability": 0.9837646484375}, {"start": 1728.54, "end": 1728.92, "word": " اسد", "probability": 0.8642578125}, {"start": 1728.92, "end": 1729.58, "word": " بنزين", "probability": 0.9822591145833334}, {"start": 1729.58, "end": 1730.0, "word": " كلورو", "probability": 0.8541259765625}, {"start": 1730.0, "end": 1730.44, "word": " بنزين", "probability": 0.97509765625}, {"start": 1730.44, "end": 1730.96, "word": " بنزين", "probability": 0.8070475260416666}, {"start": 1730.96, "end": 1731.9, "word": " جرينيارد", "probability": 0.801513671875}, {"start": 1731.9, "end": 1732.72, "word": " بنزويك", "probability": 0.9842529296875}, {"start": 1732.72, "end": 1733.1, "word": " اسد", "probability": 0.8470052083333334}, {"start": 1733.1, "end": 1733.42, "word": " كل", "probability": 0.8798828125}, {"start": 1733.42, "end": 1733.62, "word": " هذه", "probability": 0.6982421875}, {"start": 1733.62, "end": 1734.02, "word": " طرق", "probability": 0.9109700520833334}, {"start": 1734.02, "end": 1734.86, "word": " لتحضير", "probability": 0.97138671875}, {"start": 1734.86, "end": 1735.42, "word": " البنزويك", "probability": 0.96865234375}, {"start": 1735.42, "end": 1735.72, "word": " اسد", "probability": 0.8688151041666666}, {"start": 1735.72, "end": 1735.9, "word": " ولا", "probability": 0.8134765625}, {"start": 1735.9, "end": 1736.38, "word": " لأ", "probability": 0.90087890625}, {"start": 1736.38, "end": 1737.18, "word": " كان", "probability": 0.384521484375}, {"start": 1737.18, "end": 1737.86, "word": " طريقة", "probability": 0.9195963541666666}, {"start": 1737.86, "end": 1739.32, "word": " تلاتة", "probability": 0.9237060546875}, {"start": 1739.32, "end": 1739.88, "word": " واضح", "probability": 0.9405924479166666}, {"start": 1739.88, "end": 1740.92, "word": " وبهيك", "probability": 0.74310302734375}, {"start": 1740.92, "end": 1741.68, "word": " بننهي", "probability": 0.947021484375}, {"start": 1741.68, "end": 1742.48, "word": " اليوم", "probability": 0.94921875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 1742.680875, "duration_after_vad": 1658.0512499999968}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/VEV_j0BJLYk_raw.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/VEV_j0BJLYk_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..5a45e0f04000a7e67d6378c275e089dfdfedf37f
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/VEV_j0BJLYk_raw.srt
@@ -0,0 +1,1184 @@
+1
+00:00:19,460 --> 00:00:24,620
+بسم الله الرحمن الرحيم بدأنا احنا المرة الماضية في
+
+2
+00:00:24,620 --> 00:00:28,220
+موضوع الأحماض الكربوكسيلية الـ carboxylic acids
+
+3
+00:00:28,220 --> 00:00:35,460
+واستعرضنا طبعا تسميتها و الحامضية لها و بدأنا في
+
+4
+00:00:35,460 --> 00:00:40,840
+موضوع تحضير الـ carboxylic acids قلنا طبعا ان في
+
+5
+00:00:40,840 --> 00:00:47,130
+عندنا اكثر من طريقة لتحضير الـ carboxylic acidsلو
+
+6
+00:00:47,130 --> 00:00:53,190
+بدنا احنا نيجي ببساطة نتخيل هالطرق هذه لتحضير ال
+
+7
+00:00:53,190 --> 00:00:59,430
+carboxylic acids بإمكانكوا تنظروا ل الأقلام اللي
+
+8
+00:00:59,430 --> 00:01:04,590
+أنا حاملهم هدولة كام قلم؟ تلاتة .. تلاتة .. تلاتة
+
+9
+00:01:04,590 --> 00:01:05,090
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة ..
+
+10
+00:01:05,090 --> 00:01:06,070
+تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة
+
+11
+00:01:06,070 --> 00:01:06,150
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة ..
+
+12
+00:01:06,150 --> 00:01:06,150
+تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة
+
+13
+00:01:06,150 --> 00:01:12,410
+.. تلاتة .. تلاتة .. تلاتة .. تلاتة .. تلاتة
+
+14
+00:01:12,410 --> 00:01:19,640
+.. تلاتة .. تيعني أبدأ بتلات ذرات عند اللزوم كحول
+
+15
+00:01:19,640 --> 00:01:24,020
+أو aldehyde و يطلع عندى حامض من تلات ذرات يعني
+
+16
+00:01:24,020 --> 00:01:28,520
+أبدأ بتلاته و يطلع عندى تلاته و كان هذه الطريقة
+
+17
+00:01:28,520 --> 00:01:32,480
+طريقة التساوي هي الطريقة الأولى اللى بدأنا نشرحها
+
+18
+00:01:32,480 --> 00:01:36,180
+لما اتكلمنا المرة الماضية عن الكحولات و عن ال
+
+19
+00:01:36,180 --> 00:01:40,550
+aldehydesلما اتكلمنا المرة الماضية عن الكحولات و
+
+20
+00:01:40,550 --> 00:01:45,950
+عن ال aldehydes هذه الطريقة طريقة ايش تساوي يعني
+
+21
+00:01:45,950 --> 00:01:52,330
+قداش في عندى عدد كربونات في الكحول او في ال
+
+22
+00:01:52,330 --> 00:01:56,290
+aldehyde قداش بيكونوا في ال essence يعني لو الكحول
+
+23
+00:01:56,290 --> 00:02:03,000
+كانوا تلاتة معنى ذلك هيكون اسم تبعه فيه propaneأو
+
+24
+00:02:03,000 --> 00:02:06,880
+ال الديهايد كانوا تلاتة الاسم تبعه برضه هيكون فيه
+
+25
+00:02:06,880 --> 00:02:12,760
+بروفان تلاتة الآن ال acid اللي هيطلع برضه هيكون
+
+26
+00:02:12,760 --> 00:02:19,560
+تلاتة لا هيزيد ولا هينقص خلينا نشوف هذا الكلام
+
+27
+00:02:19,560 --> 00:02:24,120
+يعني مثلا لو أخدنا CH3 CH2
+
+28
+00:02:26,930 --> 00:02:35,710
+هذا ايش؟ كحول من كام كربونة؟ ثلاثة اسمه بروبان
+
+29
+00:02:35,710 --> 00:02:41,810
+البروبان بتعبر عن العدد all الان لو بدنا اكسدة
+
+30
+00:02:41,810 --> 00:02:49,430
+بسيطة في ال BCC عند اللزوم حيصير CH3 CH2 C double
+
+31
+00:02:49,430 --> 00:02:59,080
+bond OH كام ذرة؟تلاتة هذا اللي اتكون شو اسمه?
+
+32
+00:03:02,720 --> 00:03:08,000
+Ibrobanol إذا هل تغير عدد الذرات؟ لأ لو امشينا في
+
+33
+00:03:08,000 --> 00:03:12,020
+الأكسدة بالكيامان O4 عند اللزوم أو من البداية
+
+34
+00:03:12,020 --> 00:03:20,960
+بدينا بالكيامان O4 CH3 CH2 Cضم البند O OH كم ذرة
+
+35
+00:03:20,960 --> 00:03:25,500
+كربون؟ اه هذا إيش بدو يصير؟ Ibrobanol
+
+36
+00:03:28,860 --> 00:03:35,200
+وبهيك بيصير واضح معاه أن الأفكار المتعلقة بالأكسد،
+
+37
+00:03:35,200 --> 00:03:40,920
+أكسدة الكحول، الالدهاي، الاسد، لتغير عدد درات
+
+38
+00:03:40,920 --> 00:03:46,350
+الكربونواضح الفكرة؟ ولذلك هذه الطريقة .. طريقة إيش
+
+39
+00:03:46,350 --> 00:03:51,930
+بنسميها؟ طريقة تساوي .. إنه أنا عندي تلت ذرات
+
+40
+00:03:51,930 --> 00:03:56,030
+carbon .. إنه أنا عندي تلت ذرات carbon .. هدولة
+
+41
+00:03:56,030 --> 00:03:58,570
+تلت ذرات carbon .. كانوا تلاتة .. ضالوا تلاتة ..
+
+42
+00:03:58,570 --> 00:04:04,070
+ضالوا تلاتة .. واضح الفكرة؟ طبعا للناس اللي بيحبوا
+
+43
+00:04:04,070 --> 00:04:07,890
+انزيد شوية في الكلام و في المعلومات .. أنا ممكن
+
+44
+00:04:07,890 --> 00:04:12,990
+أبدأ من التلاتةبطريقة شوية صغيرة مختلفة يعني
+
+45
+00:04:12,990 --> 00:04:20,290
+مابداش بالكحول مابداش بالكحول يا ترى لو مثلا بدأت
+
+46
+00:04:20,290 --> 00:04:27,810
+بهذا المركب لو بدأت بهذا المركب CH3 CH double bond
+
+47
+00:04:27,810 --> 00:04:35,520
+CH2جبتلكم سؤال كيف من الابروب برضه ابروب ملاحظين
+
+48
+00:04:35,520 --> 00:04:40,880
+تلاتة ابروبين how can you prepare aerobic acid
+
+49
+00:04:40,880 --> 00:04:46,340
+starting from aerobin تلاتة تلاتة تلاتة تلاتة اه
+
+50
+00:04:46,340 --> 00:04:51,720
+هتيجي واحدة تتذكر ان انا هنا بدي اضيف الميه مع ولا
+
+51
+00:04:51,720 --> 00:04:56,220
+عكس قاعدة Markovnikov طبعا عكس عكس
+
+52
+00:05:05,320 --> 00:05:10,460
+واضح الفكرة فتلاتة ما زالوا تلاتة ما زالوا تلاتة
+
+53
+00:05:10,460 --> 00:05:11,320
+ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما
+
+54
+00:05:11,320 --> 00:05:11,320
+زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا
+
+55
+00:05:11,320 --> 00:05:11,320
+تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة
+
+56
+00:05:11,320 --> 00:05:11,500
+ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما
+
+57
+00:05:11,500 --> 00:05:13,440
+زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا
+
+58
+00:05:13,440 --> 00:05:15,280
+تلاتة ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة
+
+59
+00:05:15,280 --> 00:05:19,440
+ما زالوا تلاتة ما زالوا تلاتة ما زالوا تلاتة ما
+
+60
+00:05:19,440 --> 00:05:28,330
+زالوا تلاتة ما زالوا تبصير acid واضح؟ الأن في هذه
+
+61
+00:05:28,330 --> 00:05:33,990
+الحالة مافيش عندى تغير في عدد ذرات الكربون فالطرق
+
+62
+00:05:33,990 --> 00:05:39,310
+المنطلقة من الأكسة ده مافيش فيها تغير بيكون بيوتان
+
+63
+00:05:39,310 --> 00:05:44,910
+بيوتانوك بيوتانول بيوتانال لكن عدد ذرات الكربون
+
+64
+00:05:44,910 --> 00:05:48,430
+إيش ماله؟ ثابت حتى لو قلت بيوتين كمان
+
+65
+00:05:55,150 --> 00:06:03,190
+الان في طرق تانية .. في طرق تانية ممكن أنه نتعامل
+
+66
+00:06:03,190 --> 00:06:09,570
+معها .. ممكن نشتغل على طريقة اسمها طريقة النقص ..
+
+67
+00:06:09,570 --> 00:06:16,000
+يعني أبدأ بتلاتةو أكسر من التلاتة هدولة و أجد
+
+68
+00:06:16,000 --> 00:06:21,820
+أبطلع بإيش نفترض ب 2 و ب 1 أكسر التلاتة أو أبدأ ب
+
+69
+00:06:21,820 --> 00:06:28,140
+4 و أكسر الأربعة ل 2 و 2 أو ل 3 و 1 هذه طريقة إيش
+
+70
+00:06:28,140 --> 00:06:33,400
+نقص أنه أنا يكون عند السلسلة الكلية السلسلة الكلية
+
+71
+00:06:33,400 --> 00:06:39,040
+أربع كربونات أطول منها 3 أو 2 أو 1 يعني أقل من إيش
+
+72
+00:06:39,560 --> 00:06:44,440
+أقل من الأربعة صارت هذه الطريقة طريقة ايش نقص طبعا
+
+73
+00:06:44,440 --> 00:06:48,660
+ايش بيظل عندنا انه ممكن تكون طريقة زيادة يعني
+
+74
+00:06:48,660 --> 00:06:53,920
+افترضوا انه سلسلة عندى أربعة وطلبت
+
+75
+00:06:53,920 --> 00:06:56,600
+منكوا تحضروا لي حمض بخمس كربونات
+
+76
+00:07:01,280 --> 00:07:08,760
+أنا قلت لكم ببساطة مبتدئا من البيوتانول البيوتانول
+
+77
+00:07:08,760 --> 00:07:14,680
+كام كربونا؟ أربعة حضرولي بنتانوك أسد الآن إذا
+
+78
+00:07:14,680 --> 00:07:19,720
+واحدة مش منتبهة تقول all oic acid تروح تعمل أكسدة
+
+79
+00:07:19,720 --> 00:07:26,520
+أه بس البيوتانول بيصير بيوتانوك أسدبزيدش Carbona
+
+80
+00:07:26,520 --> 00:07:30,960
+الان لو كنت بداجي اسألكم والله من ال Butanol
+
+81
+00:07:30,960 --> 00:07:37,890
+حضرولي Pentanoic acid زدتوا Carbonaإذا أنا بحاجة
+
+82
+00:07:37,890 --> 00:07:43,030
+إلى طريقة وبناء على ذلك للي بدوا يفهم طرق تحضير
+
+83
+00:07:43,030 --> 00:07:47,130
+الأحماض بشكل عام بنقول أن طرق تحضير الأحماض بدكوا
+
+84
+00:07:47,130 --> 00:07:51,870
+تنتبهوا تماما ممكن تكون طريقة التساوي وهذه موجودة
+
+85
+00:07:51,870 --> 00:07:55,130
+في شغل الأكسد أو الكلام اللي شرحنا الآن ممكن تكون
+
+86
+00:07:55,130 --> 00:08:01,250
+طريقة تكسير أو نقص وممكن تكون طريقة إيش؟ زيادة
+
+87
+00:08:01,250 --> 00:08:09,000
+واضحة الفكرة؟ الآن خلينا نيجيلاطرق التكثير خلّينا
+
+88
+00:08:09,000 --> 00:08:15,340
+نيجي لطرق التكثير بشكل عام نسبة من طرق التكثير مرت
+
+89
+00:08:15,340 --> 00:08:19,980
+معنا بطريقة أو باخرى ليش؟ لأنه احنا أخدنا ال
+
+90
+00:08:19,980 --> 00:08:27,460
+ozoneolysis ال ozoneolysis عادة بيكسر المركب لإيش؟
+
+91
+00:08:28,390 --> 00:08:33,650
+لأldehyde او كيتون ايه كويس الال بعد ما
+
+92
+00:08:33,650 --> 00:08:38,370
+الأوزونوليس يعني هيك انا بده اقول الكين والالكاين
+
+93
+00:08:38,370 --> 00:08:46,370
+زي الالكين بالمناسبة الكين ممكن يعطيني ايش كيتون
+
+94
+00:08:49,540 --> 00:08:53,540
+الديهايد هذا الكلام اتعلمناه ولا لأ ان الالكين
+
+95
+00:08:53,540 --> 00:08:57,600
+بيصير كيتون او الديهايد الان الكيتون اتعلمناه انه
+
+96
+00:08:57,600 --> 00:09:05,060
+لا يتأكسد اكسدة اضافية لكن ال الديهايد بتأكسد ولا
+
+97
+00:09:05,060 --> 00:09:09,860
+لأ ال الديهايد بتأكسد اكسدة اضافية بيصير ايش acid
+
+98
+00:09:09,860 --> 00:09:14,440
+الان بكل الأحوال هذا ال الديهايد هيكون اصغر من ال
+
+99
+00:09:14,440 --> 00:09:20,010
+الكين او من ال الكاين ولا لأبالتأكيد هنا هيلزمني
+
+100
+00:09:20,010 --> 00:09:25,750
+كام عملية يتموا ورا بعض عمليتين العملية الأولى ال
+
+101
+00:09:25,750 --> 00:09:31,630
+ozoneolysis و العملية التانية ال oxidation خلّيني
+
+102
+00:09:31,630 --> 00:09:35,990
+أعبّر عنها ب O بين جثين Oxidation عملية أكسدة عادة
+
+103
+00:09:35,990 --> 00:09:41,430
+بيستعملونها H2O2 الهيدروجين بيروكسايد هذه كمان
+
+104
+00:09:41,430 --> 00:09:49,310
+خلّوها H2O2أذن اوزونوليسيز followed by H2O2 يمكن
+
+105
+00:09:49,310 --> 00:09:55,050
+أن يؤدي إلى أحماض لكن أكيد هتكون أصغر من إيش؟ أصغر
+
+106
+00:09:55,050 --> 00:10:02,090
+من الألكين اللي أنا ابتدأت فيه الآن خلينا ناخد
+
+107
+00:10:02,090 --> 00:10:06,910
+مثال حقيقي ناخد مثال حقيقي لو يا ترى أخدنا هذا
+
+108
+00:10:06,910 --> 00:10:16,980
+الألكينسواء قلنا عنه CES و لا TRANS CH3 CH3H
+
+109
+00:10:16,980 --> 00:10:26,200
+CH3H و قلنا اكمل نمر واحد O3 Ozonolysis و نمر
+
+110
+00:10:26,200 --> 00:10:31,060
+اتنين H2O2 H2O2 Hydrogen Peroxide هو العامل
+
+111
+00:10:31,060 --> 00:10:39,210
+المؤكسد الان بدنا لما ننفذ نفهم الشغل الاولىكسر
+
+112
+00:10:39,210 --> 00:10:47,350
+يعني C double bond O H و CH3 زائد C double bond OH
+
+113
+00:10:47,350 --> 00:10:55,750
+و CH3 هذا ال ozonolases طب و ال acid هذا إيش؟
+
+114
+00:10:55,750 --> 00:11:00,830
+الديهايد الآن هذا ال الديهايد بال H2O2 اللي ضفناها
+
+115
+00:11:00,830 --> 00:11:08,760
+إيش حيصير؟ C double bond O OHCH3 وجدت حصلنا على
+
+116
+00:11:08,760 --> 00:11:14,980
+الاسيتك أسد الاسيتك أسد كده؟ كربون 2 يعني كأنه انا
+
+117
+00:11:14,980 --> 00:11:18,820
+بال اوزونوليسيز اتيت كصرت الأربعة هدولة اتنين و
+
+118
+00:11:18,820 --> 00:11:23,400
+اتنين طلعوا عندي ألديهيد الآن كملت أكسدت الألديهيد
+
+119
+00:11:23,400 --> 00:11:29,060
+صار اسيتك أسد فمن الأربعة حصلت على حامض من كام
+
+120
+00:11:29,060 --> 00:11:37,890
+كربون؟ تنتين واضحة الفكرة؟ طبعا الآناللي ممكن
+
+121
+00:11:37,890 --> 00:11:44,390
+يفكروا انه نتعمق معهم بمثل هذه الفكرة ممكن نيجي
+
+122
+00:11:44,390 --> 00:11:49,910
+نسألهم، مانقول هم مش مبتدئان من ال 2 بيوتين، لو
+
+123
+00:11:49,910 --> 00:11:55,930
+بدأت من ال one بيوتين، هيطلع عند أحمد واحد و تلاتة
+
+124
+00:11:56,580 --> 00:12:00,520
+لأن هذه هتكسر كربونا و هدول يكونوا تلاتة لكن لو
+
+125
+00:12:00,520 --> 00:12:07,080
+انا اجيت و قولتلكم والله من مركب زي هذا CH3 CH2 CH
+
+126
+00:12:07,080 --> 00:12:15,560
+سواء حطيت هنا CL او OH اتخيلوا ان انا اجي اقولكم
+
+127
+00:12:15,560 --> 00:12:23,720
+من two chlorobutane حضروا لي acidic acid واضح او
+
+128
+00:12:23,720 --> 00:12:28,880
+من two butanolبتكون تعملوا elimination الان ال CL
+
+129
+00:12:28,880 --> 00:12:32,320
+و ال H بيروحوا و بيعطينا ال more substituted
+
+130
+00:12:32,320 --> 00:12:37,280
+باستعمال ايش طلعت
+
+131
+00:12:37,280 --> 00:12:44,240
+انا ال alkyd و بعدين كسرت ال alkyd هذه الطرق و مع
+
+132
+00:12:44,240 --> 00:12:47,020
+ال triple bond نفس الاشي زي ال double bond هذه
+
+133
+00:12:47,020 --> 00:12:52,180
+الطرق تعتبر طرق ايشانقاس يعني كان عندى اربع
+
+134
+00:12:52,180 --> 00:12:56,720
+كربونات اعملت حامض من كربونتين اعملت حامض من تلات
+
+135
+00:12:56,720 --> 00:13:02,840
+كربونات حسب موقع ايش ال bubble bond بس بشرط انه
+
+136
+00:13:02,840 --> 00:13:06,660
+يكون من نتائج ال ozonosis انه بتكون aldehyde ليش؟
+
+137
+00:13:06,660 --> 00:13:10,820
+لأن اللى بيكمل وبيتأكسد ال aldehyde الكيتون بقولنا
+
+138
+00:13:10,820 --> 00:13:16,140
+فيه إله أكسدة إضافية؟ لأ واضحة الفكرة؟ اللى بيكمل
+
+139
+00:13:16,140 --> 00:13:21,210
+وبيتأكسد هو مين؟الالديهايد وهذا الكلام أخدناه في
+
+140
+00:13:21,210 --> 00:13:24,090
+أكسدة الالديهايد والكيتونز قلنا الالديهايد بتصير
+
+141
+00:13:24,090 --> 00:13:30,430
+أحمار الكيتونز لاتت أكسد أكسدة إضافية واضحة الفكرة
+
+142
+00:13:30,430 --> 00:13:37,150
+طيب
+
+143
+00:13:37,150 --> 00:13:45,300
+إذا عرفنا طريقة المساواة وطريقةالنقص ايش ضال
+
+144
+00:13:45,300 --> 00:13:51,140
+عندنا؟ طريقة الزيادة بمعنى لو انا اجيت وقلتلكم لو
+
+145
+00:13:51,140 --> 00:13:56,240
+سمحتوا من تلت كربونات بدي احضر حامض من اربع
+
+146
+00:13:56,240 --> 00:14:03,000
+كربونات عادة الزيادة اللي احنا بنعملها زيادة سهلة
+
+147
+00:14:03,480 --> 00:14:07,900
+ليه؟ كربونة واحدة هي اللي بتتم بسهولة يعني التلاتة
+
+148
+00:14:07,900 --> 00:14:13,160
+يصيروا أربعة، الأربعة يصيروا خمسة، الخمسة يصيروا
+
+149
+00:14:13,160 --> 00:14:17,680
+ستة كيف هذا الكلام .. كيف هذا الكلام بتم؟ هذا
+
+150
+00:14:17,680 --> 00:14:26,500
+الكلام عادة بتتممنطلقين فيه من ال الكل هلاي من ال
+
+151
+00:14:26,500 --> 00:14:33,040
+one chloro compound واضح يعني بدي مركب سلسلة يكون
+
+152
+00:14:33,040 --> 00:14:39,300
+على موقع واحد فيها إيش إكلور بدي سلسلة على موقع
+
+153
+00:14:39,300 --> 00:14:47,340
+واحد فيها إكلور يعني مثلا زي ما اقول CH3 CH2 CH2
+
+154
+00:14:47,340 --> 00:14:56,390
+CLالان الكلور هانا وين؟ على موقع واحد هذا الكلور
+
+155
+00:14:56,390 --> 00:15:00,050
+مكانه بدي ازيد كربونا اللي هي بده تكون حاملة
+
+156
+00:15:00,050 --> 00:15:06,320
+مجموعة الاسم عدد الكربونات الكل يعني قداشتلاتة بدي
+
+157
+00:15:06,320 --> 00:15:11,720
+أحضر من هذا butanoic acid يعني كام كربونا؟ أربعة
+
+158
+00:15:11,720 --> 00:15:16,640
+في عندى طريقتين ممكنين في عندى طريقتين ممكنين
+
+159
+00:15:16,640 --> 00:15:22,920
+الطريقة الأولى أنه أنا هذا أجي أفعله مع CN minus
+
+160
+00:15:22,920 --> 00:15:28,140
+والطريقة التانية أنه أنا هذا أفعله مع green yard
+
+161
+00:15:28,140 --> 00:15:34,560
+reagentمار عليكم المغنيسيا من اللي بيعطي RMGX طيب
+
+162
+00:15:34,560 --> 00:15:38,720
+لو فعلنا مع ال cyanide شو بده يصير هذا؟ بده يصير
+
+163
+00:15:38,720 --> 00:15:49,220
+CH3 CH2 CH2 و هنا بده تيجي مجموعة ال CN لاحظوا هنا
+
+164
+00:15:49,220 --> 00:15:54,120
+بينت الكربون الرابعة ولا لأ هيصاروا كام كربونة؟
+
+165
+00:15:55,060 --> 00:16:02,160
+أربعة بدل تلاتة الان ال cyanide بشكل عام لو عملتله
+
+166
+00:16:02,160 --> 00:16:11,340
+hydrolysis يا إما ب H3O plus بيمشي الحال أو ب N-A
+
+167
+00:16:11,340 --> 00:16:15,840
+-O-H و بعدين H plus يعني يا إما بهذا ال reagent يا
+
+168
+00:16:15,840 --> 00:16:20,100
+إما بهذا ال reagent بأي واحد منهم بيمشي بصير أسلوب
+
+169
+00:16:20,870 --> 00:16:24,310
+يعني ال cyanide بيعملها hydrolysis ال acid و بعدها
+
+170
+00:16:24,310 --> 00:16:34,310
+شو هيصير CH3 CH2 CH2 و هذه ال C هي اللي ضالت هتصير
+
+171
+00:16:34,310 --> 00:16:41,610
+C double bond O OH اذا انا ال chlorine حولتها ل CN
+
+172
+00:16:41,610 --> 00:16:48,530
+و ال CN ع طول بتصير COOHهذه طريقة معروفة وجيدة
+
+173
+00:16:48,530 --> 00:16:53,750
+لعمل هذا المُركّب طيب الطريقة التانية .. بدأ أزيد
+
+174
+00:16:53,750 --> 00:16:58,310
+كربونا لسه .. أنا لو فعلت مع المغنيسيوم .. هذا إيش
+
+175
+00:16:58,310 --> 00:17:04,750
+هيعطيني؟ الـ Grignard Reagent .. كلكم اتذكرينه؟CH3
+
+176
+00:17:04,750 --> 00:17:13,470
+CH2 CH2 وقلنا هذه اهم اشي فيها MgCl هاي Green Yard
+
+177
+00:17:13,470 --> 00:17:18,630
+Ray Agent إبروبيل مغنيسيا ميكلورايد صح؟ الآن هذا
+
+178
+00:17:18,630 --> 00:17:25,330
+ال Green Yard Ray Agent بفعله مع نمرة واحد CO2
+
+179
+00:17:25,330 --> 00:17:28,250
+لاحظوا هاي ال C double bond O double bond O ثاني
+
+180
+00:17:28,250 --> 00:17:29,030
+أكسيد كربون
+
+181
+00:17:31,920 --> 00:17:38,840
+واضح؟ ونمر اتنين خليني ال CO2 ارسمه بالاحمر بفعله
+
+182
+00:17:38,840 --> 00:17:43,220
+مع ال CO2 يعني C double bond O double bond O ونمر
+
+183
+00:17:43,220 --> 00:17:49,000
+اتنين مع H بلس بيعطيني الحامض اللي هتقولولي من وين
+
+184
+00:17:49,000 --> 00:17:54,710
+اجت الكربونة؟هي من الـ CO2 مش الـ C حاملة انتن
+
+185
+00:17:54,710 --> 00:17:59,370
+أكسجين وهنا إيش زاد عندي؟ C double bond O OH
+
+186
+00:17:59,370 --> 00:18:06,590
+ببساطة هذا نيوكليوفايل بيهاجم هنا بيهاجم على
+
+187
+00:18:06,590 --> 00:18:09,990
+الكربون الموجبة مش الكربون بتاع تاني أكسيد الكربون
+
+188
+00:18:09,990 --> 00:18:15,050
+الموجبة لأنه جنبها مجموعتين سالبات لما يهاجم هذا
+
+189
+00:18:15,050 --> 00:18:20,250
+بتصير O minus ومن ال H plus بتاخد H إيش بتصير؟ OH
+
+190
+00:18:21,350 --> 00:18:27,040
+إذا هنا مصدر الكربونة الجديدة إيش بيكون؟الـ CO2
+
+191
+00:18:27,040 --> 00:18:31,720
+إذا أنا لما بدي أعمل الزيادة بدي مصدر للكربونة
+
+192
+00:18:31,720 --> 00:18:36,540
+الجديدة مصدر الكربونة الجديدة يا بدي يكون ال CN و
+
+193
+00:18:36,540 --> 00:18:39,340
+بعدين أعمل ال hydrolysis يا بعمل ال green yard
+
+194
+00:18:39,340 --> 00:18:43,280
+reagent و الكربونة الجديدة بجيبها من وين؟ من ال
+
+195
+00:18:43,280 --> 00:18:50,340
+CO2 واضح الفكرة؟ الآن مرة تانية مش ضروري تكون نقطة
+
+196
+00:18:50,340 --> 00:18:57,860
+البداية اللي عندى هي هذا المركب الكلوريممكن تكون
+
+197
+00:18:57,860 --> 00:19:02,180
+نقطة البداية الكحول الان الكحول بقدر اخليك low
+
+198
+00:19:02,180 --> 00:19:07,140
+right في الخطوة الأولى بالإبدال كحول مع O H minus
+
+199
+00:19:07,140 --> 00:19:17,960
+بيعمل إبدال ممكن تكون نقطة البداية الالكين هذه
+
+200
+00:19:17,960 --> 00:19:19,900
+الالكين بتلت كربونات
+
+201
+00:19:29,710 --> 00:19:35,570
+واضحة الفكرة فهذه
+
+202
+00:19:35,570 --> 00:19:41,830
+طرق الزيادة اللى عادة بنستعملها من خلال ال CN أو
+
+203
+00:19:41,830 --> 00:19:42,630
+ال CO2
+
+204
+00:19:52,800 --> 00:19:54,940
+هنا على السلسلة هذه
+
+205
+00:20:03,960 --> 00:20:08,640
+لأ لأ لأ لأ لأ ال chlorineation ال chlorineation
+
+206
+00:20:08,640 --> 00:20:13,260
+على السلسلة أخدناها ب CL2 في وجود ضوء أو حرارة أو
+
+207
+00:20:13,260 --> 00:20:16,560
+من خلال الإضافة ع ال double bond يعني ال chlorine
+
+208
+00:20:16,560 --> 00:20:20,600
+مع ال FeCl3 هذا على ال aromatic compounds هذا على
+
+209
+00:20:20,600 --> 00:20:28,580
+ال aromatic compounds تمام بضل في عندى ال benzoic
+
+210
+00:20:28,580 --> 00:20:35,710
+acidعارفين البنزويك أسد؟ كيف ممكن نحضر البنزويك
+
+211
+00:20:35,710 --> 00:20:40,970
+أسد؟ و مرات ممكن نسأل كيف ممكن تحضروا البنزويك أسد
+
+212
+00:20:40,970 --> 00:20:44,370
+من البنزين هاي البنزويك أسد
+
+213
+00:20:53,780 --> 00:20:59,240
+سهلة ان لو انا عندى cyanobenzene بصير benzoic acid
+
+214
+00:20:59,240 --> 00:21:05,480
+هذه الطريقة خلينى نقول ايش مالها سهلة CN اذا عندى
+
+215
+00:21:05,480 --> 00:21:11,740
+cyanobenzene في وجود H plus او NaOH نمرة واحد و
+
+216
+00:21:11,740 --> 00:21:15,320
+نمرة اتنين H plus زى ما حكينا قبل شوية ال
+
+217
+00:21:15,320 --> 00:21:21,420
+cyanobenzene بصير acid فيها مشكلةطبعا هيصير السؤال
+
+218
+00:21:21,420 --> 00:21:26,080
+كيف يتحضر السيانو بنزين .. سيانو بنزين في شبطر 11
+
+219
+00:21:26,080 --> 00:21:31,510
+بنتعلم تحضيرهبيجيش مباشر بقتش CN لأ اللي طريقة
+
+220
+00:21:31,510 --> 00:21:37,250
+التفافية ال CN و البنزين بيجيش بشكل مباشر بتحضرش
+
+221
+00:21:37,250 --> 00:21:41,630
+بشكل مباشر انه بنزين ماقتش CN ليش؟ لإن ال CN minus
+
+222
+00:21:41,630 --> 00:21:45,590
+و البنزين حاملة إلكترونات بيهاجمش minus على minus
+
+223
+00:21:45,590 --> 00:21:51,270
+طمام الطريقة التانية انه لو احنا أخدنا .. نخلص من
+
+224
+00:21:51,270 --> 00:21:56,770
+هذه الطريقة و نمحاها لو احنا أخدنا أي بنزين بيحمل
+
+225
+00:21:56,770 --> 00:22:02,490
+ال kilogramإيش في بنزين بيحمل الكل جروب؟ الطلوين
+
+226
+00:22:02,490 --> 00:22:05,670
+صح؟
+
+227
+00:22:05,670 --> 00:22:13,890
+CH3 إيش ممكن كمان؟ ال F البنزين CH2 CH3 إيش كمان
+
+228
+00:22:13,890 --> 00:22:26,110
+ممكن؟ القيومين CH CH3 CH3 كل هدولة بيحملوهالكلي
+
+229
+00:22:26,110 --> 00:22:29,950
+جروبز ممكن حد يفكر كمان بال تيرتشار بيوت البنزين
+
+230
+00:22:29,950 --> 00:22:36,610
+ممكن حد يفكر بال تيرتشار بيوت البنزين الآن بنقول
+
+231
+00:22:36,610 --> 00:22:43,230
+القاتل لو استعملنا عام المؤكسد بشكل عام ال KMnO4
+
+232
+00:22:43,230 --> 00:22:48,710
+برمجانات البوتاسيوم مع أي ألكل بنزين مع أي ألكل
+
+233
+00:22:48,710 --> 00:22:54,480
+بنزين بس بشرطالكربون المتصل على البنزين مباشرة
+
+234
+00:22:54,480 --> 00:22:59,040
+تحتوي على ذرة هيدروجين على اقل تقدير الان هذه
+
+235
+00:22:59,040 --> 00:23:03,540
+الكربون .. كم هيدروجين بتحمل؟ تلاتة .. هذه .. هذه
+
+236
+00:23:03,540 --> 00:23:08,000
+.. هذه .. ولا واحدة .. اذا هدولة التلاتة بيمشي
+
+237
+00:23:08,000 --> 00:23:14,540
+حالهمأى واحدة من هدول بالأكسدة بكامان of four
+
+238
+00:23:14,540 --> 00:23:18,820
+بتعطينا بنزويك أسل الان انتبهوا معي لنقطة كتير
+
+239
+00:23:18,820 --> 00:23:26,100
+مهمة انه بغض النظر عن طول السلسلة هنطلع بس بنزويك
+
+240
+00:23:26,100 --> 00:23:30,960
+أسل يعني لو كان هنا مثل او اثل او بروبل او بيوتل
+
+241
+00:23:30,960 --> 00:23:34,760
+كربونة او تنتين او تلاتة او اربعة او خمسة او عشرة
+
+242
+00:23:35,740 --> 00:23:40,220
+بس هطلعوا إيش ال benzoic acid مرات كتير لما بنيجي
+
+243
+00:23:40,220 --> 00:23:44,620
+بنسأل الطلاب بنقولهم الله أعملونا أكسدة بنزين حامل
+
+244
+00:23:44,620 --> 00:23:47,340
+تلت كربونات بيروحوا بيخلوا الكربونتين و بيعملوا
+
+245
+00:23:47,340 --> 00:23:51,640
+الأكسدة على التالتة افهمتوا الغلطة اللي بحكيها ولا
+
+246
+00:23:51,640 --> 00:24:00,600
+أوضحها أكتر لما أجي أرسملهم مركب زي هذا CH2 CH2
+
+247
+00:24:00,600 --> 00:24:07,120
+CH3 و أقولهم بالكمان O4الآن الغلطة اللي بيعملوه
+
+248
+00:24:07,120 --> 00:24:11,900
+بيعملوا ال acid هانا و بيخلوها دولة الجواب الصحيح
+
+249
+00:24:11,900 --> 00:24:15,620
+انه سواء كانوا دول واحدة او تنتين او تلاتة او
+
+250
+00:24:15,620 --> 00:24:20,720
+اربعة او عشرة بس بتكون عند هانا مجموعة ال acid
+
+251
+00:24:20,720 --> 00:24:27,240
+COOHبمعنى أنا بشرحش ميكانيزم متفق انه بدنيش ادخل
+
+252
+00:24:27,240 --> 00:24:31,180
+كتير بتفاصيل يعني خليني في النتائج بمعنى لو انا
+
+253
+00:24:31,180 --> 00:24:38,120
+اجيت سألتكم و قولتلكم انه تفاعل الطلوين والاكيومين
+
+254
+00:24:38,120 --> 00:24:42,120
+اه انتبهوا معاك الطلوين والاكيومين مع الكيامة ال
+
+255
+00:24:42,120 --> 00:24:47,990
+O4 both produces benzoic acid صحبينما لو كان
+
+256
+00:24:47,990 --> 00:24:52,390
+السؤال تفاعل الطلوين والـ tertiary بيوت البنزين
+
+257
+00:24:52,390 --> 00:24:56,490
+هذا لأ لأن هذا مافيش عليه هيدروجينة على الكاربون
+
+258
+00:24:56,490 --> 00:25:03,190
+المتصلة مباشرة بالبنزينة واضحة الفكرة؟ فعشان اتم
+
+259
+00:25:03,190 --> 00:25:06,810
+هذا النوع من الأكسدة هذا بنسميه oxidation of the
+
+260
+00:25:06,810 --> 00:25:12,290
+aliphatic sided chain مش هذه سلسلة معلقة على
+
+261
+00:25:12,290 --> 00:25:18,730
+البنزينولذلك هذا التفاعل اسمه أكسدت السلسلة
+
+262
+00:25:18,730 --> 00:25:24,110
+المعلقة على البنزين، مهما كبرت ومهما عظمت، ايش
+
+263
+00:25:24,110 --> 00:25:31,750
+بتعطيني؟ acid، بس، بغض النظر عن طولهاواضح؟
+
+264
+00:25:31,750 --> 00:25:36,530
+Oxidation of the aliphatic sided chain attached to
+
+265
+00:25:36,530 --> 00:25:41,330
+benzene واضحة الفكرة؟ هذه طريقة لتحضير ال benzoic
+
+266
+00:25:41,330 --> 00:25:46,570
+acid طبعا احنا جيبنا طريقة تانية باستعمال إيش؟ ال
+
+267
+00:25:46,570 --> 00:25:54,040
+CN إذا هي كام طريقة صيرنا ذاكرين لكم؟طريقة السيانة
+
+268
+00:25:54,040 --> 00:26:00,060
+جيبناها ولا لأ؟ طيب خلينا نمحا كل هالكلام ونقول لو
+
+269
+00:26:00,060 --> 00:26:05,320
+إجاكم السؤال في الامتحان ابتلى الطرق حضرولي ال
+
+270
+00:26:05,320 --> 00:26:08,440
+benzoic acid هتقولوا ال aliphatic side chain هذه
+
+271
+00:26:08,440 --> 00:26:12,620
+كلها طريقة حتى لو من البنزين بقول بنزين طلوين
+
+272
+00:26:13,730 --> 00:26:17,930
+بنزويك أسد واضح؟ لما أقولكوا بدي بنزويك أسد من
+
+273
+00:26:17,930 --> 00:26:23,090
+البنزين، شو هانمشي؟ بنزين طول وين؟ بنزويك أسد
+
+274
+00:26:23,090 --> 00:26:28,750
+صعبة؟ من السيان و بنزين؟ ابنعملها طب لو قولنا بدنا
+
+275
+00:26:28,750 --> 00:26:33,090
+طريقة تالتة من البنزين
+
+276
+00:26:39,040 --> 00:26:48,920
+طريقة تالتة بد بنزويك أسد من البنزين واضحة
+
+277
+00:26:48,920 --> 00:26:58,260
+الفكرة هي بنزين بد يصير بنزويك أسد حسب ما اتعلمنا
+
+278
+00:26:58,260 --> 00:27:03,900
+لاحظوا ما بين البنزين
+
+279
+00:27:03,900 --> 00:27:09,650
+و بنزويك أسد زيادة كربونةولذلك .. و لذلك احنا قلنا
+
+280
+00:27:09,650 --> 00:27:17,870
+بطريقة ما هذه لما صارت سيانو اقدرنا
+
+281
+00:27:17,870 --> 00:27:21,330
+نحولها ل acid بس مااخدناش الطريقة اللي بتخليها
+
+282
+00:27:21,330 --> 00:27:24,970
+سيانو لحتى الان الان ما طريقة الزيادة التانية
+
+283
+00:27:24,970 --> 00:27:34,830
+اللتي تعلمناها اغرينيا اذا هذا يصير اكلوروبنزين
+
+284
+00:27:34,830 --> 00:27:40,590
+هذه تعلمناها ولا لأالكلورو بنزين لو فعلناه معي
+
+285
+00:27:40,590 --> 00:27:47,050
+green yard مع Mg شو بيصير؟
+
+286
+00:27:47,050 --> 00:27:56,270
+MgCl ال MgCl بإيش بيزيد كربونا؟ بتاني أكسيد
+
+287
+00:27:56,270 --> 00:28:03,890
+الكربون وحمد إذا بنزين كلورو بنزين طبعا كلكوا
+
+288
+00:28:03,890 --> 00:28:06,470
+عارفين ال reaction اللي هو Cl2
+
+289
+00:28:13,200 --> 00:28:26,560
+بنزين بيصير بنزويك أسد بنزين بيصير
+
+290
+00:28:26,560 --> 00:28:30,080
+طلوين
+
+291
+00:28:30,080 --> 00:28:36,360
+بنزويك أسدو بعدين كيامان افور بالكيامان افور اذا
+
+292
+00:28:36,360 --> 00:28:40,460
+هى البنزويك اسد بتلات طرق اللى بده يحفظهم اول شى
+
+293
+00:28:40,460 --> 00:28:47,160
+يقول بنزين طلوين بنزويك اسد بنزين سيانو بنزين
+
+294
+00:28:47,160 --> 00:28:52,720
+بنزويك اسد بنزين كلورو بنزين بنزين جرينيارد بنزويك
+
+295
+00:28:52,720 --> 00:28:57,180
+اسد كل هذه طرق لتحضير البنزويك اسد ولا لأ كان
+
+296
+00:28:57,180 --> 00:29:02,480
+طريقة تلاتة واضح وبهيك بننهي اليوم
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/VF-0zNtg5Zg_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/VF-0zNtg5Zg_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d1090a3474a98c8683203dd61caabc5e96ad64d8
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/VF-0zNtg5Zg_postprocess.srt
@@ -0,0 +1,1904 @@
+1
+00:00:20,210 --> 00:00:23,950
+بسم الله الرحمن الرحيم بنبدأ اليوم بالفصل السابع
+
+2
+00:00:23,950 --> 00:00:30,470
+هتلاحظوا أنه يعني هنركز كعائلة أساسية فيه على
+
+3
+00:00:30,470 --> 00:00:35,650
+مركبات ال alcohols اللي بنسميها بالعربي الكحولات
+
+4
+00:00:35,650 --> 00:00:42,850
+الآن بعض الكتب اللي بتدرس باللغة العربية هتلاقوها
+
+5
+00:00:42,850 --> 00:00:49,720
+موجودة باسم الأغوالإذا مرت عليكم هذه الكلمة يعني
+
+6
+00:00:49,720 --> 00:00:52,920
+الناس اللي جاي من السعودية بدهم يدرسوا عن ال
+
+7
+00:00:52,920 --> 00:00:57,020
+alcohols الكحولات بدل ما يقولوا الكحولات بيقولوا
+
+8
+00:00:57,020 --> 00:01:03,200
+إيش الأغوال جامع غول و بيستندوا للنص القرآن لا
+
+9
+00:01:03,200 --> 00:01:08,760
+فيها غولولهم عنها ينزفون واضح الفكرة فإذا قرأتها
+
+10
+00:01:08,760 --> 00:01:14,800
+بكتاب عربي باسم الأغوال فهي الكحولات، الآن ككيميا
+
+11
+00:01:14,800 --> 00:01:23,080
+الكحولات هي المركبات اللي ماخدة صيغة Rواضح الان
+
+12
+00:01:23,080 --> 00:01:30,020
+بيجي معها ال phenols إذا كانت ال OH متصلة بحلقة
+
+13
+00:01:30,020 --> 00:01:35,020
+أروماتية البنزين حالة خاصة بيكون نفس ال phenol لكن
+
+14
+00:01:35,020 --> 00:01:42,920
+المجموعة العامة AR بشكل عام ال AR OH يعني كل
+
+15
+00:01:42,920 --> 00:01:47,580
+المركبات الأروماتية إذا اتصلت ب OH they are
+
+16
+00:01:47,580 --> 00:01:55,420
+phenolsموازي لل alcohols لكن بإبدال ال oxygen هادى
+
+17
+00:01:55,420 --> 00:02:01,200
+ب Sulphur بيصير المركب ثيول بيصير المركب ثيول يعني
+
+18
+00:02:01,200 --> 00:02:08,060
+ماخد الصيغة العامة R RSH ثيولز ماخد الصيغة العامة
+
+19
+00:02:08,060 --> 00:02:15,060
+RSH طبعا اكيد هتقولوا طيب في موازي لل phenol بمعنى
+
+20
+00:02:15,060 --> 00:02:16,580
+اخر ايش بدى يكون ماخد AR
+
+21
+00:02:19,820 --> 00:02:25,320
+SH موجود أيضا بنسميه Theophenol
+
+22
+00:02:27,210 --> 00:02:33,170
+واضح؟ فهذه العائلات اللي طبعا الأساس فيها عائلة
+
+23
+00:02:33,170 --> 00:02:37,390
+الكحولات يعني هيكون التركيز الأكبر على الكحولات
+
+24
+00:02:37,390 --> 00:02:41,030
+اللي هي المركبات اللي ماخدة الصيغة العامة ROH من
+
+25
+00:02:41,030 --> 00:02:47,210
+الطرق بشكل خفيف للphenols للthiols للthiophenols
+
+26
+00:02:47,210 --> 00:02:53,270
+كل هذه الأشياء ان شاء الله بنقشها في هذا الفصل
+
+27
+00:02:56,090 --> 00:03:00,990
+إذا بدأنا بالكحولات .. إذا بدأنا بالكحولات و أول
+
+28
+00:03:00,990 --> 00:03:06,430
+شغلة دايما بنبدأ فيها كيف نسمي المركبات عادة بنسمي
+
+29
+00:03:06,430 --> 00:03:12,190
+الكحولات بإضافة النهاية all لاحظوا أن نظام التسمية
+
+30
+00:03:12,190 --> 00:03:15,910
+.. نظام التسمية في ال organ chemistry للناس اللي
+
+31
+00:03:15,910 --> 00:03:22,120
+بيتقنوه هو نظامبسيط جدا يعني مئات إذا ما قلناش
+
+32
+00:03:22,120 --> 00:03:27,540
+ملايين المراكبات الإنسان بتعلم قواعد بسيطة جدا
+
+33
+00:03:27,540 --> 00:03:32,840
+للتسمية وبيقدر يسيطر عليها الآن المفروض مع هذا
+
+34
+00:03:32,840 --> 00:03:37,440
+الوقت أنه صار نظام التسمية بالنسبة لناواضح في
+
+35
+00:03:37,440 --> 00:03:42,560
+عندنا سلسلة كربونية بدنا ناخد العدد تبعها بالنهاية
+
+36
+00:03:42,560 --> 00:03:48,980
+ميثين إيثين بروبين بيوتين بيوتين هكسين هبتين هدوله
+
+37
+00:03:48,980 --> 00:03:53,300
+صرنا حافظينهم الآن هذا الكلام إذا كانت السلسلة
+
+38
+00:03:53,300 --> 00:03:56,840
+كلها روابط أحدية وقلنا الkins الآن إذا صرنا في
+
+39
+00:03:56,840 --> 00:04:02,900
+الروابط الثنائية بنغير بنحط in بدل ال in في
+
+40
+00:04:02,900 --> 00:04:09,610
+الروابط الثلاثيةI الآن في الكحولات بنحط نهاية all
+
+41
+00:04:09,610 --> 00:04:14,450
+بعد شوية هنتعلم في ال aldehydes بنحط نهاية L في ال
+
+42
+00:04:14,450 --> 00:04:19,430
+ketone بنحط نهاية on في الأحماض الكربوكسيلية بنحط
+
+43
+00:04:19,430 --> 00:04:24,390
+نهاية oic acid بمعنى لو أنا رسمت خمس درات كربون
+
+44
+00:04:24,390 --> 00:04:29,690
+بقدر اقول ان المركبات اللي منهم عند اللزوم مثيل
+
+45
+00:04:30,860 --> 00:04:39,680
+للألكين ميثين اعفوا بنتين I mean بنتين بنتين بنتين
+
+46
+00:04:39,680 --> 00:04:42,860
+طبعا بحدد وين موقع ال double bond ده قصة بسيطة
+
+47
+00:04:42,860 --> 00:04:50,580
+بنتاي بنتانول بنتانال لل الديهايد بنتانون لل كيتون
+
+48
+00:04:50,580 --> 00:04:56,970
+بنتانوك أسد فصارت القصة فقط هي نهايةبتتغير في
+
+49
+00:04:56,970 --> 00:05:01,750
+نهاية الاسم و بنقدر نسمي المراكبات انتبهوا جيدا ان
+
+50
+00:05:01,750 --> 00:05:05,870
+ال all اللي بنستعمله انه نهاية الكحولات مافيش فيها
+
+51
+00:05:05,870 --> 00:05:13,330
+E في الآخر يعني OL بدون E ليش هتوجهنا المراكبات
+
+52
+00:05:13,770 --> 00:05:20,050
+بتنتهي ب OLE هذه مركبات حلقية تحتوي على حلقات
+
+53
+00:05:20,050 --> 00:05:24,430
+خماسية خارج موضوع دراستنا زي لما تسمعوا عن بعض
+
+54
+00:05:24,430 --> 00:05:29,870
+الأدوية مثلا المضادة للفطريات الدكتازول
+
+55
+00:05:29,870 --> 00:05:33,690
+والفلوكانازول الناس اللي عندهم فطريات أحيانا بين
+
+56
+00:05:33,690 --> 00:05:39,560
+أصابع رجليهم بيشتريوامضاد للفطريات دكتازول مشهور
+
+57
+00:05:39,560 --> 00:05:45,040
+كتير في البلد flucanazole هدولة هتلاحظوا اسمهم OLE
+
+58
+00:05:45,040 --> 00:05:50,580
+OLE هذه عائلة ثانية عائلة مركبات بحلقات يشمالها
+
+59
+00:05:50,580 --> 00:05:56,980
+خماسية فالكحولات اللي عندنا نهايتهم all الان لو
+
+60
+00:05:56,980 --> 00:06:03,680
+اجينا بدنا نسمي ب carbon واحد هنقول مثان allو هكذا
+
+61
+00:06:03,680 --> 00:06:08,060
+الان لاحظوا ال common nomenclature و مرات كتير
+
+62
+00:06:08,060 --> 00:06:12,920
+بنقولكوا ايش الاسم الشائع للمركب ايضا لها بشكل عام
+
+63
+00:06:12,920 --> 00:06:19,800
+قاعدة القاعدة تبعتها ذكر المجموعة ال alkyl group و
+
+64
+00:06:19,800 --> 00:06:25,300
+بعدين بنحط نهاية يعني لو كان هذا المركب CH3Cl كنت
+
+65
+00:06:25,300 --> 00:06:28,800
+اقول ال common nomenclature له مثل ال chloride
+
+66
+00:06:28,800 --> 00:06:35,950
+الان لما بيصير CH3OHمثل و ال OH عائلة الألكوهول
+
+67
+00:06:35,950 --> 00:06:40,250
+فبصير مثل ألكوهول و هكذا ف ال common nomenclature
+
+68
+00:06:40,250 --> 00:06:48,750
+بشكل عام بتيجي بذكر المجموعة و بعدها العائلة واضح؟
+
+69
+00:06:48,750 --> 00:06:52,590
+نفس الاشي هتلاحظوا مثلا في ال aldehydes
+
+70
+00:06:52,590 --> 00:07:00,950
+بروبلالديهيد مثلا بروبل المجموعة الديهيدالعائلة و
+
+71
+00:07:00,950 --> 00:07:06,830
+بال كيتون و بال أسد و بال كلورايتس و بالبرومايتس
+
+72
+00:07:08,520 --> 00:07:13,980
+توجه عام الان لو اتيت هنا اتطلعت هذا إيثانول طبعا
+
+73
+00:07:13,980 --> 00:07:19,200
+المجموعة إيثل بناء على ذلك بيكون إيثل ألكول هذا
+
+74
+00:07:19,200 --> 00:07:23,700
+البروبانول الان لاحظوا البروبانول الالكول ممكن
+
+75
+00:07:23,700 --> 00:07:26,580
+تكون ال OH على الكاربون الأولى أو على الكاربون
+
+76
+00:07:26,580 --> 00:07:30,880
+الثانية ولذلك بلزم نوضح بالترقيم فبنقول one
+
+77
+00:07:30,880 --> 00:07:36,890
+probanol و two probanolواضح؟ ال alcohol من
+
+78
+00:07:36,890 --> 00:07:41,470
+المركبات زيها زي ال alkenes اللي مرات كتير لازم
+
+79
+00:07:41,470 --> 00:07:45,870
+نوضح موقع المجموعة الوظيفية باستعمال ايش؟ أرقام
+
+80
+00:07:45,870 --> 00:07:50,290
+طبعا هنا لما قلنا one probanol لو كنا بدنا نسميه
+
+81
+00:07:50,290 --> 00:07:54,070
+بالاسم الشائع ال common name المجموعة هذه probel
+
+82
+00:07:54,070 --> 00:08:00,370
+.. probel alcohol الآن هذا two probanolأيزو برو
+
+83
+00:08:00,370 --> 00:08:01,430
+بالالكهول
+
+84
+00:08:15,670 --> 00:08:19,770
+CH حملة تنتين CH3 و كمان كربونة يعني العدد الكلي
+
+85
+00:08:19,770 --> 00:08:25,310
+أربعة إذا هذا شو بدي أسميه Isobutyl يمكن ال I
+
+86
+00:08:25,310 --> 00:08:30,290
+رايحة Isobutyl alcohol طبعا لو بدي أسميه أيوبكنومي
+
+87
+00:08:30,290 --> 00:08:35,990
+كليتشار بدي أسميه بالترقيم و ال OH بدي أكون ماخدة
+
+88
+00:08:35,990 --> 00:08:40,290
+أقل ترقيم يعني بدي أقول واحد اتنين تلاتة إذا هذا
+
+89
+00:08:40,290 --> 00:08:45,440
+one-probanolوانبروبانول على نمر اتنين شو بيحمل
+
+90
+00:08:45,440 --> 00:08:51,200
+الوانبروبانول مثل هاي أطول سلسلة واحد اتنين تلاتة
+
+91
+00:08:51,200 --> 00:08:57,520
+two مثل وانبروبانول فلازم احدد موقع ال ايش ال OH
+
+92
+00:08:57,520 --> 00:09:02,800
+two مثل وانبروبانوللو بننظر لهذا المركب على سبيل
+
+93
+00:09:02,800 --> 00:09:06,460
+المثال كمجموعة لو كنت بدي ال common nomenclature
+
+94
+00:09:06,460 --> 00:09:11,080
+له كمجموعة معروفة tertiary butyl اذا tertiary
+
+95
+00:09:11,080 --> 00:09:14,640
+butyl alcohol طب لو بدي اسميه بال iubac
+
+96
+00:09:14,640 --> 00:09:18,360
+nomenclature مرة تانية بدي اطول سلسلة خليني افترض
+
+97
+00:09:18,360 --> 00:09:24,700
+هي اطول سلسلة واحد اتنين تلاتة اذا هذا a-probanol
+
+98
+00:09:25,770 --> 00:09:31,010
+تو بروبانول لأن ال OH طالعة من موقع اتنين و على
+
+99
+00:09:31,010 --> 00:09:34,730
+اتنين ايضا ايش في عندكم مثل اذا two methyl two
+
+100
+00:09:34,730 --> 00:09:37,370
+probanol is tertiary butyl alcohol
+
+101
+00:09:45,170 --> 00:09:48,790
+الـ Common Nomenclature هو الـ tertiary butyl
+
+102
+00:09:48,790 --> 00:09:52,950
+alcohol في الـ Common Nomenclature الآن هذا
+
+103
+00:09:52,950 --> 00:09:57,150
+المُركّب لو بدأ أطلع على المجموعة اللي فيه لما
+
+104
+00:09:57,150 --> 00:10:02,690
+درفنا ال الكينز أخدنا مجموعتين أخدنا الفينل والألل
+
+105
+00:10:02,690 --> 00:10:06,870
+قلنا الألل اللي هو البروبين اللي بنخص منه هيدروجين
+
+106
+00:10:06,870 --> 00:10:10,780
+من هذا الموقعكل هذا الكلام السكوت اللي بلاحظه على
+
+107
+00:10:10,780 --> 00:10:15,740
+بعض الوجوه اللي أنا مارجعتش كتير هذه مشكلتها واضح؟
+
+108
+00:10:15,740 --> 00:10:20,700
+بدكوا تكونوا متذاكرين هذه المجموعة أخدناها بهذا
+
+109
+00:10:20,700 --> 00:10:25,380
+الشكل اسمها إيش؟ ألل الآن إذا إجي عليها chlorine
+
+110
+00:10:26,360 --> 00:10:30,580
+ألل كلورايت إذا إتي عليها بروم ألل برومايت إذا إتي
+
+111
+00:10:30,580 --> 00:10:36,960
+عليها OH ألل Alcohol فمن ناحية ال Alcohol اعرفنا
+
+112
+00:10:36,960 --> 00:10:42,520
+الآن لو كنا هذا ال ال alcohol بدنا نسميه بال Iopac
+
+113
+00:10:42,520 --> 00:10:48,840
+Nomenclature هنلاحظ إن في عندنا مجمعتين وظيفيتين
+
+114
+00:10:48,840 --> 00:10:53,280
+بدنا ننتبهالان التقاء المجموعات الوظيفية في
+
+115
+00:10:53,280 --> 00:10:58,520
+المركبات هذه تماما زى التقاء المجموعات الوظيفية
+
+116
+00:10:58,520 --> 00:11:02,660
+لما درسنا ال aromatic compounds متذكرين؟ اه قولنا
+
+117
+00:11:02,660 --> 00:11:07,420
+أبسط إشي ال alkanes بعدين ال alkenes و ال alkynes
+
+118
+00:11:07,420 --> 00:11:13,460
+بعدين مثلا ال OH بعدين ال ketone بعدين ال aldehyde
+
+119
+00:11:13,460 --> 00:11:19,890
+بعدين ال acidOkay فلو أنا بدي أجي أطلع أنه عندي OH
+
+120
+00:11:19,890 --> 00:11:27,370
+وعندي ال keen مين بده تكون العائلة ال OH وبناء على
+
+121
+00:11:27,370 --> 00:11:33,050
+ذلك المركب اللي عنده لازم ياخد النهاية all لأن
+
+122
+00:11:33,050 --> 00:11:37,950
+الشيء بتسمى باسم عائلته بياخد النهاية all طبعا هذا
+
+123
+00:11:37,950 --> 00:11:41,490
+لو بدي أطلع عليه واحد و الترقيم من وين هيكون؟
+
+124
+00:11:41,710 --> 00:11:46,310
+بنعندى الالكول واحد اتنين تلاتة طبعا بينا نسميه
+
+125
+00:11:46,310 --> 00:11:51,950
+بروبان all هو فيه double bond فبدل ال a بروبين
+
+126
+00:11:51,950 --> 00:11:58,050
+بيصير بروبين ال يعني لو مافيش عند انا هذا double
+
+127
+00:11:58,050 --> 00:12:02,910
+bond ايش كنت استعمل حرف ال a الآن صار double bond
+
+128
+00:12:02,910 --> 00:12:10,150
+ال الكن صار الكن صار بروبين all واضح بروبين all
+
+129
+00:12:10,150 --> 00:12:18,000
+لاحظواالعائلة إيش؟ all و هو فيه ألكين، الآن ال all
+
+130
+00:12:18,000 --> 00:12:24,470
+لازم نحدد موقعها و ال ألكين لازم نحدد موقعهابتدخل
+
+131
+00:12:24,470 --> 00:12:29,550
+الأرقام ال all على أي موقع جاية على واحد فبنكتب
+
+132
+00:12:29,550 --> 00:12:34,830
+two prob in one all بمعنى أن ال in موجودة على موقع
+
+133
+00:12:34,830 --> 00:12:39,890
+اتنين وال all على موقع واحد مرات هذا ممكن تشوفوه
+
+134
+00:12:39,890 --> 00:12:45,670
+بطريقة تانية يعني يكتبوه a prob و بعدين in و بعدين
+
+135
+00:12:45,670 --> 00:12:52,100
+all و يحددوا أن ال in على أي موقع اتنينع اتنين و
+
+136
+00:12:52,100 --> 00:12:56,080
+ال all على اي موقع لاحظوا اختلاف بسيط هنا في
+
+137
+00:12:56,080 --> 00:13:00,160
+الكتاب يعني عملنا تقطيع في الاسم حددنا وين ال in و
+
+138
+00:13:00,160 --> 00:13:05,100
+وين ال all هنا نفس الاشي و فهمنا ضمنا ان اتنين
+
+139
+00:13:05,100 --> 00:13:11,180
+اللي كتبت برا هي تعنيموقع ال in و ال all جنبها ف
+
+140
+00:13:11,180 --> 00:13:16,000
+two probine one all او prob two in one all هو نفس
+
+141
+00:13:16,000 --> 00:13:20,560
+الاسم يعني طريقتين لكتابة نفس الاسم في كتير طلاب
+
+142
+00:13:20,560 --> 00:13:25,320
+بيحبوا يقولوا في الأول هذا كله probine all جنب ال
+
+143
+00:13:25,320 --> 00:13:30,140
+in بالظبط بيحطوا الرقم جنب ال all بالظبط بيحطوا
+
+144
+00:13:30,140 --> 00:13:32,140
+الرقم تبعها
+
+145
+00:13:35,230 --> 00:13:39,650
+فهذه الطريقة اللي احنا بنستعملها لما بلتقى عندنا
+
+146
+00:13:39,650 --> 00:13:44,370
+اكثر من مجموعة وظيفية لاحظوا بدي اجي مباشرة على
+
+147
+00:13:44,370 --> 00:13:50,650
+هذا المثال لانه على نفس الفكرة طلع هذا المثال ايش
+
+148
+00:13:50,650 --> 00:13:58,180
+العائلات اللي موجودة فيه؟ال all و ال I ال ال مين
+
+149
+00:13:58,180 --> 00:14:04,120
+أعلى في الأولوية ال all إذا لو عديت العدد لكل واحد
+
+150
+00:14:04,120 --> 00:14:11,880
+اتنين تلاتة أربعة خمسة إيش هيكون كمركب؟ بين two
+
+151
+00:14:11,880 --> 00:14:17,960
+all بين two all هيني ذكرت المجموعتين لما أنا أقول
+
+152
+00:14:17,960 --> 00:14:21,240
+بين I
+
+153
+00:14:22,480 --> 00:14:29,500
+all هذه المجموعتين في I و في all الآن بلزم أن احدد
+
+154
+00:14:29,500 --> 00:14:36,960
+موقعهم ال all على اي موقع و ال I على تلاتة بنت
+
+155
+00:14:36,960 --> 00:14:42,140
+اثري I one all او لو كتبت اثري بنتين بتفهم ان ال
+
+156
+00:14:42,140 --> 00:14:47,160
+three هذي بتحدد موقع ال I اثري بنتين one all او
+
+157
+00:14:47,160 --> 00:14:52,500
+بنت اثري I one all نفس الفكرة تماماواضح؟ نفس
+
+158
+00:14:52,500 --> 00:14:57,360
+المُركّب فهذا الكلام اللي بيصير عندنا لما بلتقي
+
+159
+00:14:57,360 --> 00:15:05,380
+أكثر من مجموعة وظيفية الان ممكن يكون عندي alcohol
+
+160
+00:15:05,380 --> 00:15:13,120
+على حلقات ال alcohol على الحلقة .. الحلقة مش زي
+
+161
+00:15:13,120 --> 00:15:18,620
+السلسلةالحلقة ما لهاش بداية و نهاية يعني لما يكون
+
+162
+00:15:18,620 --> 00:15:24,200
+عندي انا خمس درات كربون كسلسلة باجي بقول بضحوط ال
+
+163
+00:15:24,200 --> 00:15:31,460
+OH هنا بسميه one بنتانول هنا two بنتانول three
+
+164
+00:15:31,460 --> 00:15:35,760
+بنتانول برجع طبعا two بنتانول اذا في عندي في
+
+165
+00:15:35,760 --> 00:15:40,150
+السلسلةone pentanol و two pentanol و three
+
+166
+00:15:40,150 --> 00:15:46,600
+pentanol لكن لو هذه السلسلة صارت حلقة خماسيةالان
+
+167
+00:15:46,600 --> 00:15:50,420
+سواء كتبة ال او اتش هان او هان او هان او هان او
+
+168
+00:15:50,420 --> 00:15:54,220
+هان جميع المواقع متكافئة مافيش فيها موقع واحد يعني
+
+169
+00:15:54,220 --> 00:15:58,800
+مابيقدرش الإنسان الحلقة يقول وين بدايتها ولذلك هذا
+
+170
+00:15:58,800 --> 00:16:04,200
+بتسمى cyclopentanol بدون ما نحطله one أو two لأن
+
+171
+00:16:04,200 --> 00:16:11,240
+كل المواقع واحد واضح؟ cyclopentanol لكن وقتش بيلزم
+
+172
+00:16:11,240 --> 00:16:16,930
+ترقيملو كان عندى اكتر من مجموعة عشان اشوف انه هذه
+
+173
+00:16:16,930 --> 00:16:23,610
+المجموعات انه هذه المجموعات هل يا ترى واحد اتنين
+
+174
+00:16:23,610 --> 00:16:27,250
+ولا واحد تلاتة ايش العلاقة بينها يعني لو كان
+
+175
+00:16:27,250 --> 00:16:31,030
+المركب بهذا الشكل والمجموعتين على جهة واحدة هذا
+
+176
+00:16:31,030 --> 00:16:38,930
+ايش هسميه one two cyclopentane by all all و all
+
+177
+00:16:39,860 --> 00:16:44,680
+Diol واضح؟ one two cycle وبنتين ديول وحنقول إيش
+
+178
+00:16:44,680 --> 00:16:52,140
+مالهم؟ sis طبعا ممكن نتخيل مركب بهذا الشكل لو
+
+179
+00:16:52,140 --> 00:16:58,860
+افترضنا هنا في عندنا OH وهنا في عندنا CL وإيجا
+
+180
+00:16:58,860 --> 00:17:05,680
+بدنا نسميه الآن أكيد ال alcohol أساس أقوى من ال CL
+
+181
+00:17:05,680 --> 00:17:12,110
+إذا المركب إيش هيكون؟cyclopentanol بتخيلوا من وين
+
+182
+00:17:12,110 --> 00:17:17,070
+بيبدأ الترقيم؟ و
+
+183
+00:17:17,070 --> 00:17:23,270
+بناء على ذلك مثل هذا المركب هيصير three .. فيش
+
+184
+00:17:23,270 --> 00:17:31,050
+ميتة ميتة في البنزينة خلصنا منها بس في البنزينة مش
+
+185
+00:17:31,050 --> 00:17:37,190
+في الحلقات إذا هذا three chloro cyclopentanol
+
+186
+00:17:37,370 --> 00:17:44,590
+بنتانول مش بنتين Cyclopentanol خلاص مابنكتبش one
+
+187
+00:17:44,590 --> 00:17:48,150
+لأنه يفهم ضمنا أن الترقيم بدأ من عندها يعني
+
+188
+00:17:48,150 --> 00:17:52,770
+مابنكتبش three chloro cyclopentane one all أو one
+
+189
+00:17:52,770 --> 00:17:57,310
+cyclopentanol لأ three chloro cyclopentanol و هكذا
+
+190
+00:17:57,310 --> 00:17:58,110
+واضح؟
+
+191
+00:18:00,740 --> 00:18:06,080
+الان احيانا بلتقي عندى الجزء ال aliphatic مع ال
+
+192
+00:18:06,080 --> 00:18:10,320
+aromatic وسبق احنا لما أخدنا ال aromatic compounds
+
+193
+00:18:10,320 --> 00:18:16,020
+نوّهنا لهذه النقطة قولنا انه ممكن نسمي المركب بأحد
+
+194
+00:18:16,020 --> 00:18:21,560
+طريقين اما ان نعتبر الأساس بنزين و اكتشف نعتبر
+
+195
+00:18:21,560 --> 00:18:26,600
+الأساس بنزينإذا هذه المجموعة اللي موجودة سهلة ولها
+
+196
+00:18:26,600 --> 00:18:31,460
+اسم بسيط عارفينه طب إذا مش مجموعة سهلة وملاش اسم
+
+197
+00:18:31,460 --> 00:18:39,480
+بسيط بعتبر نفسي بتعامل مع المركب كالكين بتعامل مع
+
+198
+00:18:39,480 --> 00:18:45,620
+المركب كالكين هذا الالكين هيطول سلسلة فيه في نمرة
+
+199
+00:18:45,620 --> 00:18:50,780
+واحد اتنين ويحمل مجموعة ايش اسم هذه المجموعة فنل
+
+200
+00:18:51,570 --> 00:18:56,330
+البنزينة اللى خصمنا منها H كمجموعة شو بنسميها؟ فنل
+
+201
+00:18:56,330 --> 00:18:59,970
+طبعا لاحظوا المركب اللى فيه ذرتين كربون هو اي
+
+202
+00:18:59,970 --> 00:19:06,470
+مركب؟ الاثانول اذا هذا لو كنا بنسميه شو هنسميه؟
+
+203
+00:19:06,470 --> 00:19:08,790
+two phenyl اثانول
+
+204
+00:19:11,950 --> 00:19:16,070
+يفهم على طول مباشرة طالما كتبنا two أن الـ O على
+
+205
+00:19:16,070 --> 00:19:22,430
+واحد و هذا على اتنين لاحظوا لو مثلا جبنا مركب شبيه
+
+206
+00:19:22,430 --> 00:19:29,390
+فيه بهذا الشكل هاي ذارتين كربون و حطينا الـ OH هنا
+
+207
+00:19:29,390 --> 00:19:30,970
+و البنزينة هنا
+
+208
+00:19:35,020 --> 00:19:39,080
+لاحظوا هذا isomer .. structural isomer كربون تنتين
+
+209
+00:19:39,080 --> 00:19:42,140
+كانت ال O H على الكربون الأولى و البنزينة على
+
+210
+00:19:42,140 --> 00:19:45,080
+التانية حطينا ال O H على الأولى و البنزينة على
+
+211
+00:19:45,080 --> 00:19:53,120
+الأولى فلو بدنا نيجي نقول بدنا نسمي هذا one phenyl
+
+212
+00:19:53,120 --> 00:20:00,180
+one ethanol مواد هيك إيثانول
+
+213
+00:20:03,690 --> 00:20:10,650
+عشان نضع رقم وان فينيل وان إيثانول واضح؟ وان فينيل
+
+214
+00:20:10,650 --> 00:20:14,350
+وان إيثانول عشان التوضيح يعني دائما في موضوع
+
+215
+00:20:14,350 --> 00:20:19,430
+الأرقام إذا حسيت أن في شيء confusing لازمة أرقام
+
+216
+00:20:19,430 --> 00:20:25,250
+إضافية نضعها مش لازمة أرقام إضافية مافيش داعي أن
+
+217
+00:20:25,250 --> 00:20:29,470
+نضع الأرقام مايتضح بدون أرقام لا نستعمل له الأرقام
+
+218
+00:20:29,470 --> 00:20:35,310
+يعني هنابتمشي بدون أرقام بيبطل فيه لزوم ان اكتب
+
+219
+00:20:35,310 --> 00:20:39,490
+one على سبيل المثال one cyclopentanol خلاص
+
+220
+00:20:39,490 --> 00:20:45,030
+فالأرقام عندها غرض ايش الغرض تبعها التوضيح لما
+
+221
+00:20:45,030 --> 00:20:49,350
+بيصير في لبس معين بحتاج ان نحط الأرقام عشان نوضح
+
+222
+00:20:49,350 --> 00:20:56,350
+بنستعملها طبعا ال aromatic alcohol انجاز التعبير
+
+223
+00:20:56,350 --> 00:21:03,280
+الأساس فيهمالفينول مر علينا تسميته وقلنا لو ال OH
+
+224
+00:21:03,280 --> 00:21:08,480
+مع ال نيترو مين الأساس الفينول إذا هذا para-nitro
+
+225
+00:21:08,480 --> 00:21:14,260
+أو four-nitroفينول لكن بدكوا تنتبهوا لنقطة أن نفس
+
+226
+00:21:14,260 --> 00:21:21,020
+هذه الفينول لو انوجدت مع مجموعات أعلى منها هترجع
+
+227
+00:21:21,020 --> 00:21:26,620
+لأصلها يعني هذه حامض C double bond O OH acidو
+
+228
+00:21:26,620 --> 00:21:31,380
+Alcohol من الأعلى؟ ال acid ولذلك هذا المُركّب
+
+229
+00:21:31,380 --> 00:21:35,620
+Benzoic acid على موقع Ortho، إيش عندكم؟
+
+230
+00:21:39,360 --> 00:21:44,420
+Orthohydroxy benzoic acid أو two hydroxy benzoic
+
+231
+00:21:44,420 --> 00:21:51,020
+acid طبعا هذا ماخد اسم شهرة salicylic acid ماخد
+
+232
+00:21:51,020 --> 00:21:54,720
+اسم شهرة ايش؟ salicylic acid ال salicylic acid هو
+
+233
+00:21:54,720 --> 00:21:59,760
+الحامض اللي بيطلو عادة من شجر الصفصاف وهو أساس
+
+234
+00:21:59,760 --> 00:22:05,680
+تحضير الأسبيرين هو أساس تحضير الأسبيرينيعني
+
+235
+00:22:05,680 --> 00:22:11,960
+الأسبيرين عادة بيشتقوا من هذا الحامض بيبدلوا ال H
+
+236
+00:22:11,960 --> 00:22:16,400
+اللي موجودة هنا على ال OH شايفين هذه ال OH هذه ال
+
+237
+00:22:16,400 --> 00:22:20,140
+H بنبدلها و بنحط مكانها هذه المجموعة
+
+238
+00:22:23,720 --> 00:22:26,920
+الناس اللي حفظوا معنا هذه المجموعة أخدناها لجامن
+
+239
+00:22:26,920 --> 00:22:32,840
+الـ acetic acid أسيتل فبصير المركب بدل salicylic
+
+240
+00:22:32,840 --> 00:22:35,140
+acid أسيتو
+
+241
+00:22:37,400 --> 00:22:42,540
+acetosalicylic acid هو الاسبيرين واضح فالاسبيرين
+
+242
+00:22:42,540 --> 00:22:47,480
+هو ال salicylic acid لكن انا شيلت منه ال H وحطيت
+
+243
+00:22:47,480 --> 00:22:52,940
+مكانها C double bond O CH3 فبصير الاسم المشهور
+
+244
+00:22:52,940 --> 00:23:00,080
+للاسبيرين ايش acetosalicylic acidacetosalicylic
+
+245
+00:23:00,080 --> 00:23:04,860
+acid المثال الأخير اللي موجود في هذا ال slide هو
+
+246
+00:23:04,860 --> 00:23:10,280
+التقاء الديهايد مع الكهول لحظة متذكرين لما قلنا
+
+247
+00:23:10,280 --> 00:23:16,280
+الكهول الديهايدي ماكتبوش COH CHO وهذا لو كنا
+
+248
+00:23:16,280 --> 00:23:21,960
+بنفسرها بال structure كيف بنفسرها بنفسرها C double
+
+249
+00:23:21,960 --> 00:23:29,730
+bond OHهذه تفاصيلها C double bond OH لما بنكتبها
+
+250
+00:23:29,730 --> 00:23:34,750
+كتابة كيف بنكتبها CHO فهذه مجموعة ال الديهايد الان
+
+251
+00:23:34,750 --> 00:23:39,350
+ال الديهايد أعلى من الألكوهول ولذلك المركب اللي
+
+252
+00:23:39,350 --> 00:23:46,490
+عندي هنا بنز الديهايد على موقع متا هيدروكسي
+
+253
+00:23:46,490 --> 00:23:50,050
+متا هيدروكسي بنز الديهايد
+
+254
+00:23:54,320 --> 00:23:59,120
+هذا بشكل عام بالنسبة لتسمية الكحولات و ال phenols
+
+255
+00:23:59,120 --> 00:24:04,180
+لما نصل لل thyols اللي فيهم SH بناخد تسميتهم بشكل
+
+256
+00:24:04,180 --> 00:24:05,240
+منفصل
+
+257
+00:24:07,650 --> 00:24:14,410
+الان كنا عارفين شغلة ان الكحولات طالما فيهم OH إذا
+
+258
+00:24:14,410 --> 00:24:19,550
+اللي بيعملوا إيش هيدروجين bonding بيعملوا هيدروجين
+
+259
+00:24:19,550 --> 00:24:23,530
+bonding اللي مقصود بالهيدروجين bonding أن ذرة
+
+260
+00:24:23,530 --> 00:24:27,330
+الهيدروجين في الكحولات تحديدا بتكون محصورة بين
+
+261
+00:24:27,330 --> 00:24:32,400
+ذرتين أكسجينوبشكل عام إذا إنتوا متذكرين من المدارس
+
+262
+00:24:32,400 --> 00:24:37,380
+الـ hydrogen bonding بيكون إذا حصرت الهيدروجين بين
+
+263
+00:24:37,380 --> 00:24:43,440
+electronegative atoms محددة تلت ذرات شو هما؟
+
+264
+00:24:43,440 --> 00:24:48,680
+Oxygen و Nitrogen و Fluor سواء كان على اليمين أو
+
+265
+00:24:48,680 --> 00:24:52,360
+الشمال يعني بين تنتين Oxygen، بين تنتين Nitrogen،
+
+266
+00:24:52,360 --> 00:24:55,260
+بين تنتين Fluor، بين Oxygen وNitrogen، Oxygen و
+
+267
+00:24:55,260 --> 00:25:00,810
+Fluor الهيدروجين لما بتحصربين ذرتين
+
+268
+00:25:00,810 --> 00:25:05,130
+electronegative بهذا الشكل بتكون رابطة أساسية
+
+269
+00:25:05,130 --> 00:25:10,270
+رابطة أساسية مع ذرة و رابطة هيدروجينية مع الذرة
+
+270
+00:25:10,270 --> 00:25:15,130
+التانية يعني لو كنا بدنا نوضح بالظبط ال hydrogen
+
+271
+00:25:15,130 --> 00:25:20,670
+bonding في الألكوهول حتى ما نتغلب هيكون بهذا الشكل
+
+272
+00:25:20,670 --> 00:25:23,350
+ال hydrogen bonding في الألكوهول تخيلوا مثلا
+
+273
+00:25:23,350 --> 00:25:27,990
+الميثانول CH3O
+
+274
+00:25:29,040 --> 00:25:34,620
+H هذا الجزء و في كم زوج إلكتروناتها اتنين الان لو
+
+275
+00:25:34,620 --> 00:25:43,280
+بدى اجيب انا جزء كحول تاني CH3 OH وهي كمان زوجين
+
+276
+00:25:43,280 --> 00:25:53,130
+إلكترونات الان هذا جزء و هذاهذه الروابط الـ OH
+
+277
+00:25:53,130 --> 00:25:57,370
+اللي هنا رابطة أصلية Intramolecular bond و الـ OH
+
+278
+00:25:57,370 --> 00:26:01,510
+اللي هنا Intramolecular bond لو أنا إجيت أعملت بين
+
+279
+00:26:01,510 --> 00:26:07,070
+هذه الـ H و هذا زوج الإلكترونات رابطة هذا الرابطة
+
+280
+00:26:07,070 --> 00:26:13,230
+الهيدروجينية هذا الـ hydrogen bondهذا الهيدروجين
+
+281
+00:26:13,230 --> 00:26:18,630
+بوند الان لاحظوا معي ان الهيدروجين بوند ولا بحال
+
+282
+00:26:18,630 --> 00:26:23,090
+من الأحوال قوتها بتصل لقوة هذه الرابطة الأساسية
+
+283
+00:26:23,090 --> 00:26:27,450
+يعني هذه الهيدروجين بوند اللي بين الجزيئين قوتها
+
+284
+00:26:27,450 --> 00:26:32,070
+تقريبا بين خمسة لعشرة في المية من قوة الرابطة
+
+285
+00:26:32,070 --> 00:26:38,900
+الأصلية اللي هنا يعني هذه مقارنة بهذه خمسةالى 10%
+
+286
+00:26:38,900 --> 00:26:43,280
+من قوة الرابط الاصلية لهنا بناء على ذلك لو احنا
+
+287
+00:26:43,280 --> 00:26:49,460
+بدنا نعمل عملية تسخين او غليان نكسر روابط بالطاقة
+
+288
+00:26:49,460 --> 00:26:55,080
+اى رابط اللى بدأت نكسر هادي وبطير هذا الكحول لوحده
+
+289
+00:26:55,080 --> 00:26:59,840
+وبطير بتبخر هذا الكحول لوحدهبس ماحد بيقول اللي
+
+290
+00:26:59,840 --> 00:27:05,680
+بنكسر هذه الرابطة بالغليان، الغليان بيكسر الروابط
+
+291
+00:27:05,680 --> 00:27:10,040
+الـ Intermolecular forces، الروابط بين الجزيئات،
+
+292
+00:27:10,040 --> 00:27:14,080
+هذا جزيء و هذا جزيء بينهم رابطة ضعيفة هي اللي
+
+293
+00:27:14,080 --> 00:27:19,070
+بتتفكك و بتنكسر، بس بالتأكيدمش ال intramolecular
+
+294
+00:27:19,070 --> 00:27:22,330
+force الرابطة الأصلية اللي بتنكسر، لأ ال
+
+295
+00:27:22,330 --> 00:27:26,110
+intermolecular force يعني لو سخننا مثلا و بدنا
+
+296
+00:27:26,110 --> 00:27:30,110
+نعمل غليان أو كان بتبخر حتى مع ارتفاع الحرارة أي
+
+297
+00:27:30,110 --> 00:27:35,190
+رابطة اللي بتنكسر، هذه الرابطة بيصير كل جزء ينفصل
+
+298
+00:27:35,190 --> 00:27:41,000
+لإيش؟ لوحده، واضح؟طبعا انتبهوا معي وجود ال
+
+299
+00:27:41,000 --> 00:27:47,460
+hydrogen bond هادي بتخلي الكحول جزيئاته مترابطة
+
+300
+00:27:47,460 --> 00:27:52,040
+اذا نقطة غليانه نسبيا ايش بتكون عالية يعني هذا
+
+301
+00:27:52,040 --> 00:27:56,580
+الميثانول على سبيل المثال نقطة غليانه 65 درجة
+
+302
+00:27:56,580 --> 00:28:02,190
+مئويةمقارنة بمركبات مش فيها hydrogen bonding زي ال
+
+303
+00:28:02,190 --> 00:28:07,630
+الكنز تعتبر نقطة غليان عالية طيب لو قلنا بدنا
+
+304
+00:28:07,630 --> 00:28:13,610
+نقارن هذا الميثانول بالمية طب ليش؟ مع العلم أن
+
+305
+00:28:13,610 --> 00:28:20,130
+وزنها الجزائي أقل و
+
+306
+00:28:20,130 --> 00:28:24,800
+أنا هيدروجينيةعندى تلتين رابطين زى ما .. الميه
+
+307
+00:28:24,800 --> 00:28:29,020
+عندها الإمكانية بالظبط تعمل رابطتين هيدروجينيتين
+
+308
+00:28:29,020 --> 00:28:34,140
+مش رابط يعني الجزيئات بتترابط بشكل أقوى لما انتوا
+
+309
+00:28:34,140 --> 00:28:40,860
+بدكم تقولوا فى عندكم OHH نفترض الآن هذا الجزيئ لو
+
+310
+00:28:40,860 --> 00:28:47,560
+بدى أجيبله جزيئ تانى بهذا الشكل OHH وهنا كمان OHH
+
+311
+00:28:47,560 --> 00:28:49,740
+هى تلت جزيئات نفترض
+
+312
+00:28:52,840 --> 00:28:57,600
+الان هنا في عندي أزواج إلكترونات بيصير رابطة
+
+313
+00:28:57,600 --> 00:29:02,380
+هيدروجينية من هنا إذا أنا لو هذا بدي أفكه كام
+
+314
+00:29:02,380 --> 00:29:07,300
+رابطة هيدروجينية بدي أكسر؟ تنتين مش واحدة فالمي
+
+315
+00:29:07,300 --> 00:29:14,220
+لأنها H2 بيكون فيها روابط هيدروجينية إيش؟ أكتر من
+
+316
+00:29:14,220 --> 00:29:20,840
+الكحولاتلاحظوا يعني لو الإنسان بده يحكي شوية بمنطق
+
+317
+00:29:20,840 --> 00:29:27,440
+الفلسفة .. بمنطق الفلسفة الميه
+
+318
+00:29:27,440 --> 00:29:36,700
+يمكن مشروب لذيذ و أحل الحلال تمام؟ و الكحولات
+
+319
+00:29:36,700 --> 00:29:43,800
+بعضهاسام وبعضها خمر وبعضها مفيد يعني الكحولات
+
+320
+00:29:43,800 --> 00:29:50,300
+ماحدش يستعمل المصطلح الحديث إنه الكحولات بشكل عام
+
+321
+00:29:50,300 --> 00:29:57,460
+ضارة أو الكحولات محرمة لأ الكحولات عائلة عائلة
+
+322
+00:29:57,460 --> 00:30:04,440
+كبيرة هذه العائلة في منها مواد سامة في منها مواد
+
+323
+00:30:04,440 --> 00:30:11,100
+مسكرة في منها مواد مفيدةواضح؟ في منها مواد سامة
+
+324
+00:30:11,100 --> 00:30:16,420
+وفي مسكر وفي مفيد حسب طبيعة ال ايش ال R أو
+
+325
+00:30:16,420 --> 00:30:21,960
+المجموعة الان لو انا بدأ اتخيل ان الكحولات بنائها
+
+326
+00:30:21,960 --> 00:30:26,460
+الأساسي ال O H و اجي اقول أبسط الكحولات .. أبسط
+
+327
+00:30:26,460 --> 00:30:34,300
+الكحولات يعني هي عندي O H .. O H .. O H الان خليني
+
+328
+00:30:34,300 --> 00:30:43,510
+اجي احط هناقبل ال CH3 H أحط هنا CH3 و أحط هنا CH2
+
+329
+00:30:43,510 --> 00:30:51,780
+CH3لاحظوا أبسط مركّب هيكون الميّه طبعا الميّه ما
+
+330
+00:30:51,780 --> 00:30:55,980
+بنصنفهاش احنا مركّب عضوي لسبب بسيط ان مافيش فيها
+
+331
+00:30:55,980 --> 00:31:00,200
+carbon المركّب العضوي فيه carbon لكن لو الإنسان
+
+332
+00:31:00,200 --> 00:31:06,300
+بتأمل من ناحية الخواص الميّه كتير في خواصها بتشبه
+
+333
+00:31:06,300 --> 00:31:10,450
+الكحولاتكخواص كيميائية يعني لو بدأت أتكلم عن نقطة
+
+334
+00:31:10,450 --> 00:31:14,770
+غليان مرتفعة لو بدأ أتكلم عن تفاعل مع السوديوم لو
+
+335
+00:31:14,770 --> 00:31:19,490
+بدأ أتكلم بعد شوية لما أخد الحامضية هلاحظ أن
+
+336
+00:31:19,490 --> 00:31:24,310
+حامضية الماء زي حامضية الكحولات بالظبط يعني نفس
+
+337
+00:31:24,310 --> 00:31:29,630
+القوة الحامضية عشان هيك بنقول للبني آدم غسل بالمية
+
+338
+00:31:29,630 --> 00:31:34,350
+إيدك بنضره ولا لأ؟ بندرهش كلنا بنغسل بالمية طب
+
+339
+00:31:34,350 --> 00:31:39,160
+الكحولات؟بعد شوية لما تصيروا تعملوا مزارع بكتيريا
+
+340
+00:31:39,160 --> 00:31:41,840
+اللي بتخصصوا تحاليل طبية و إشي بعد ما يشتغلوا
+
+341
+00:31:41,840 --> 00:31:44,860
+بالبكتيريا بدهم يطهروا إيديهم بإيش بيغسلوا
+
+342
+00:31:44,860 --> 00:31:50,960
+بالإيثانول بالإيثانول اللي هو الكحول نفسه تبع
+
+343
+00:31:50,960 --> 00:31:56,420
+الخمر بيغسله فيه واضح؟ الآن لاحظوا أن الماء شراط
+
+344
+00:31:56,420 --> 00:32:04,660
+الميثانول poisonous الإيثانول
+
+345
+00:32:05,860 --> 00:32:10,060
+اللي هو الخمرة الاثانول
+
+346
+00:32:10,060 --> 00:32:13,760
+المكون الأساسي هو اللي بيسبب الاسكار في الخمر
+
+347
+00:32:13,760 --> 00:32:21,200
+والميه اللي هي أبسط مشروب فيهم الميه
+
+348
+00:32:21,200 --> 00:32:27,540
+مشروب جيد وممتاز هيجيكم كمان فكرة طالما ذكرنا هذا
+
+349
+00:32:27,540 --> 00:32:36,600
+الكلام هيجيكم كمان فكرة ان الاثانول في مشكلةإن هو
+
+350
+00:32:36,600 --> 00:32:42,540
+من أفضل المذيبات لإجراء التفاعلات الكيميائية ومطهر
+
+351
+00:32:42,540 --> 00:32:47,280
+يعني أنا بدي إياه يكون متوفر وبسعر رخيص يعني ال
+
+352
+00:32:47,280 --> 00:32:53,180
+letter يكون مثلا بتلاتة أربعة shekel بدولار واضح؟
+
+353
+00:32:58,850 --> 00:33:06,070
+بنغسل الأوان الذجاجية بالإيثانول بالإيثانول
+
+354
+00:33:06,070 --> 00:33:07,350
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+355
+00:33:07,350 --> 00:33:07,510
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+356
+00:33:07,510 --> 00:33:08,990
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+357
+00:33:08,990 --> 00:33:11,110
+بالإيثانول بالإيثانول بالإيثانول بالإيثانول
+
+358
+00:33:11,110 --> 00:33:14,620
+بالإيثانول بالإصناعة الخمور هذه بحث ذاتها علم يعني
+
+359
+00:33:14,620 --> 00:33:19,560
+ملايين الفدانات بتكون مزروعة عنب اللي بيعملوا منه
+
+360
+00:33:19,560 --> 00:33:23,440
+الخمر و بدهوا مياه تكون بسعر غالي و زجاجة النبيذ
+
+361
+00:33:23,440 --> 00:33:27,100
+بسعر معين طب هى الاساس اللى فيها اللى بيعمل كل
+
+362
+00:33:27,100 --> 00:33:32,400
+المشاكل مين ال Ethanol اذا ال Ethanol صار مطلوب
+
+363
+00:33:32,400 --> 00:33:36,380
+عند العلماء و عند الكيميائين و عند الصناعة انه
+
+364
+00:33:36,380 --> 00:33:42,680
+ينباع رخيصو ممكن يتحضروا ينباع رخيص ومطلوب عند
+
+365
+00:33:42,680 --> 00:33:49,920
+الناس اللي بيصنعوا الخمر انه ينباع ايش؟ غالب لأنه
+
+366
+00:33:49,920 --> 00:33:54,300
+هذه صناعة في العالم الغربي و بدها تربح طب ايش
+
+367
+00:33:54,300 --> 00:33:57,940
+الحل؟ العالم والكيميائي بيقول بدي ايه ايه ايه ايه
+
+368
+00:33:57,940 --> 00:33:58,840
+ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه
+
+369
+00:33:58,840 --> 00:34:06,690
+ايه ايه ايه ايه ايه ايه ايه ايه ايهجالوا بسيطة
+
+370
+00:34:06,690 --> 00:34:14,050
+للكيميائيين جالولهم بنبيعكم إيثانول رخيص بس بشرط
+
+371
+00:34:14,050 --> 00:34:21,280
+عارفين إيش الشرط انسموا اللي ما تشربوهوشيعني هم
+
+372
+00:34:21,280 --> 00:34:24,220
+بدوا ميثاق أنه اللي بده يشرب إيثانول و اللي بده
+
+373
+00:34:24,220 --> 00:34:28,180
+يشرب خمره بده يدفع كتير طب ييجي بني آدم بده يلحق
+
+374
+00:34:28,180 --> 00:34:32,340
+عليهم بالله بيعوني إيثانول أنا بدي أستعمله للصناعة
+
+375
+00:34:32,340 --> 00:34:38,000
+و يروح يشربه برخيص خسروا الجماعة فقالوا بنبيعكيا
+
+376
+00:34:38,000 --> 00:34:44,900
+للصناعة بس ما تشربوش في ثقة متبادلة أنه يلتزم طب
+
+377
+00:34:44,900 --> 00:34:51,240
+إيش عملوه؟ قالوا بنحط فيه شوية سماللي لو شربته
+
+378
+00:34:51,240 --> 00:34:56,780
+تموت، تبقوا معاه، يعني لو الواحد شرب الاثانول بتاع
+
+379
+00:34:56,780 --> 00:35:03,800
+المختبر، بده يموت، إذا الإنسان شرب اثانول المختبر،
+
+380
+00:35:03,800 --> 00:35:07,240
+شو بده يصير فيه؟ بده يموت، طب إيش السم اللي بدكوا
+
+381
+00:35:07,240 --> 00:35:11,920
+تحطوه في الاثانول؟ جالي شوية ميثانول صغيرة،
+
+382
+00:35:11,920 --> 00:35:18,250
+الميثانول سام، يا بيموت يا بيعمىواضح؟ فال Ethanol
+
+383
+00:35:18,250 --> 00:35:21,330
+اللي في المختبر .. ال Ethanol اللي في المختبر
+
+384
+00:35:21,330 --> 00:35:26,570
+مسموم ممنوع أن البني أدم يشربه مخلوط بشوية إيش؟
+
+385
+00:35:26,570 --> 00:35:31,470
+Methanol. الآن إذا إجا لا سمح الله واحد جاهل بده
+
+386
+00:35:31,470 --> 00:35:35,510
+يحضر خمرة للغلابة و الفجرة و جاب منها ال Ethanol
+
+387
+00:35:35,510 --> 00:35:40,090
+الارخيص و حط في جزايز و باع و يلا اشربه شو بده
+
+388
+00:35:40,090 --> 00:35:48,340
+يصير فيهم؟ بدهم يموتواواضح؟ شو بده يصير فيهم؟ بدهم
+
+389
+00:35:48,340 --> 00:36:00,480
+يموتوا ويعيادوا بالله على أي حال، هذا الحادث مش
+
+390
+00:36:00,480 --> 00:36:06,270
+زمان صارجابل سنتين بس في ال 2013 عملها واحد
+
+391
+00:36:06,270 --> 00:36:10,750
+بالليبيا اول ما الدنيا صارت فوضى هناك راح اعمل هذا
+
+392
+00:36:10,750 --> 00:36:15,830
+الكلام و اقرأ التقرير لان انا بفرجيكوا تقرير من
+
+393
+00:36:15,830 --> 00:36:25,630
+تقرير حديث يعني لو بتطلع التاريخ 13.03.2003 2013
+
+394
+00:36:25,630 --> 00:36:26,950
+بالظبط
+
+395
+00:36:28,750 --> 00:36:34,410
+قدرين تقرأوا العنوان؟ ارتفاع عدد الموتى بسبب الخمر
+
+396
+00:36:34,410 --> 00:36:41,610
+المغشوشة لستين و هذا الكلام بتلت عشر تلاتة تداولته
+
+397
+00:36:41,610 --> 00:36:47,510
+وكلات الأنباء و ليش وصلوا لستين حالة و أكتر من
+
+398
+00:36:47,510 --> 00:36:52,310
+سبعميت حالة تسمم لأنهم
+
+399
+00:36:53,460 --> 00:36:58,040
+التسمم نجب عن مادة نجمة عن مادة مشروب كحول محل
+
+400
+00:36:58,040 --> 00:37:03,500
+الصناع والميثانول الذي يستخدم ايضا كوقود يضاف
+
+401
+00:37:03,500 --> 00:37:05,420
+احيانا بكميات صغيرة
+
+402
+00:37:13,840 --> 00:37:18,100
+يضاف أحيانا بكميات صغيرة في المشروبات الكحولية
+
+403
+00:37:18,100 --> 00:37:23,820
+التي تنتج سرا هو مش لزيادة المفعول يضاف يضاف أساسا
+
+404
+00:37:23,820 --> 00:37:29,800
+كتسميم لإيش لل إيثانول عشان الناس مايشربوش، الآن
+
+405
+00:37:29,800 --> 00:37:34,880
+هذا جاب إيثانول من تبع الكيمويات حطه عم الخمرة
+
+406
+00:37:36,080 --> 00:37:40,080
+ماتوا الناس اللي شربوا بالإضافة للناس اللي اتسمموا
+
+407
+00:37:40,080 --> 00:37:44,540
+و اللي أصيبوا بالإيش؟ بالعمى .. بالعمى و لذلك حتى
+
+408
+00:37:44,540 --> 00:37:48,240
+و أنتم تشتغلوا في المختبر نفترض أنكم كنتوا بتسخنوا
+
+409
+00:37:48,240 --> 00:37:53,060
+شغلة فيها إيثانول ما تعرضوش أنفسكم كتير لبخار
+
+410
+00:37:53,060 --> 00:37:58,680
+الإيثانولاللي تتنفسوا إيثانول يدخل لجسمكم من خلال
+
+411
+00:37:58,680 --> 00:38:03,660
+الجهاز التنفسي و يصل لعينيكم واضح؟ مثل هذه التجارب
+
+412
+00:38:03,660 --> 00:38:08,060
+و الأشياء لازم كيف تنشغل بخزانة أبخرة تشفطها مش
+
+413
+00:38:08,060 --> 00:38:13,300
+بني آدم بيعمل تجربة و بيسخن إيثانول و بيشتغل بدون
+
+414
+00:38:13,300 --> 00:38:17,040
+ما يعرف اللي بيشتغل كيميا هذه الكيميائيات بيتعامل
+
+415
+00:38:17,040 --> 00:38:22,520
+معاها كيف؟بأسلوب ضمن التحذيرات قبل ما بيمسك المادة
+
+416
+00:38:22,520 --> 00:38:27,600
+الإنسان بيكون فهمها و قرأ التحذيرات اللي عليها طيب
+
+417
+00:38:27,600 --> 00:38:33,020
+كيف يأتي السام يعني و بغسك يديه ممكن طبعا يعني؟ هو
+
+418
+00:38:33,020 --> 00:38:38,550
+ما بيأثرش في التغسيلفي التغسيل بأثرش لما يتناول من
+
+419
+00:38:38,550 --> 00:38:42,190
+الفم و يمتص جوا الجسم يعني مابتصيرش نسبة
+
+420
+00:38:42,190 --> 00:38:46,030
+absorption كبيرة اللى يدخل على الجسم بالذات اللى
+
+421
+00:38:46,030 --> 00:38:50,510
+هو بنسبة جليلة لكن لما بيتاخد كمشروب كلها النسبة
+
+422
+00:38:50,510 --> 00:38:55,430
+الجليلة بتيجي بتدخل الجسم طبعا أفضل كتير لو كنا
+
+423
+00:38:55,430 --> 00:39:01,010
+كمان بنغسل بإيثانول ناقي اللى مايصيرشنسبة ال
+
+424
+00:39:01,010 --> 00:39:04,270
+absorption الخفيفة لكن الواقع اللي موجود ان ال
+
+425
+00:39:04,270 --> 00:39:10,730
+ethanol الطبي بالذات ال ethanol المختبرة و عشان
+
+426
+00:39:10,730 --> 00:39:15,550
+هيك لما مرات بيجيبوا ethanol معين لصناعة الأدويات
+
+427
+00:39:16,370 --> 00:39:20,230
+بيكتبوا ان هذا إيثانول بنفع لصناعة الأدوية بيكون
+
+428
+00:39:20,230 --> 00:39:24,630
+مش فيه سموم ممكن يدوبوا فيه أدوية والموضوع خلاف في
+
+429
+00:39:24,630 --> 00:39:28,350
+موضوع انه يجوز استعماله او لا وقدر الإمكان الإنسان
+
+430
+00:39:28,350 --> 00:39:33,330
+لازم يتجنب الدواء اللي مدوب بإيثانول ما لم يكن
+
+431
+00:39:33,330 --> 00:39:39,130
+هناك يعني ضرورة يعني شديدة جدا و البدائل كتيرة في
+
+432
+00:39:39,130 --> 00:39:41,550
+كل الأحوال واضح الفكرة؟
+
+433
+00:39:49,990 --> 00:39:54,530
+الان في موضوع الـ hydrogen bonding قولنا بيخلي
+
+434
+00:39:54,530 --> 00:39:58,250
+نقاط الغليان مرتفعة يعني لو انا بدأ اطلع على
+
+435
+00:39:58,250 --> 00:40:04,330
+الميثانول 65 زادت كربونا الإيثانول بيصير 78
+
+436
+00:40:04,330 --> 00:40:10,030
+البروبانول 97 طبعا هذا كلام منطقي كل ما بتكبر
+
+437
+00:40:10,030 --> 00:40:14,970
+السلسلة شو بيصيرها نقطة الغليان؟بتزيد الان لو
+
+438
+00:40:14,970 --> 00:40:20,210
+اجينا نقارن الموضوع بذائبية هذه المراكبات في الميه
+
+439
+00:40:20,210 --> 00:40:24,690
+هذه المراكبات تمتاز انها مكونا من جزئين الجزء
+
+440
+00:40:24,690 --> 00:40:29,610
+الاول ال O H خلينا نعلمها بالاحمر في كل المراكبات
+
+441
+00:40:29,610 --> 00:40:36,030
+هذا جزء ال O H جزء ايش بنقول عنه احنا polar الان
+
+442
+00:40:36,030 --> 00:40:37,650
+الجزء التاني
+
+443
+00:40:47,350 --> 00:40:52,590
+السلسلة طولت فانجزوا اللي بيزيد قاعد ال non polar
+
+444
+00:40:56,610 --> 00:41:02,210
+ربما نستطيع ان نقول ان هذا الجزء polar يعني الجزء
+
+445
+00:41:02,210 --> 00:41:06,450
+ال polar فيه متغلب لكن لما تكبر السلسلة كتير الجزء
+
+446
+00:41:06,450 --> 00:41:12,330
+بالمجمل شو بنعمله؟ non polar بناء على ذلك الميه ال
+
+447
+00:41:12,330 --> 00:41:19,850
+H2O polar رجاء نقوله polar مش بولر مش بنانا،
+
+448
+00:41:19,850 --> 00:41:22,930
+pencil اه polar
+
+449
+00:41:25,090 --> 00:41:31,840
+لاحظوا القاعدة ايش بتقول Likedissolves like الان
+
+450
+00:41:31,840 --> 00:41:36,080
+هذا اعتبرنا polar بدوب في الميه هذا زيه هذا زيه
+
+451
+00:41:36,080 --> 00:41:41,100
+هذا اعتبرنا ايش non polar بدوب في الميه لأ و بناء
+
+452
+00:41:41,100 --> 00:41:45,280
+على ذلك بنصير قادرين نتخيل ليش ال methanol و ال
+
+453
+00:41:45,280 --> 00:41:48,460
+ethanol و ال probanol اللي هي الكحولات الصغيرة
+
+454
+00:41:48,460 --> 00:41:52,900
+بتدوب في الميه هذه الكحولات اللي في أول السلسلة
+
+455
+00:41:52,900 --> 00:41:58,820
+بنسميها احنا ايش lower alcohol يعني الكحولات الاش
+
+456
+00:41:59,790 --> 00:42:05,010
+لصغيرة و هذه الكحولات اللى تحت شو بنسميها higher
+
+457
+00:42:05,010 --> 00:42:09,750
+alcohols الان مين اللى بيدوبوا في الميه ال lower
+
+458
+00:42:09,750 --> 00:42:13,930
+alcohols ولا ال higher alcohols ال lower alcohols
+
+459
+00:42:13,930 --> 00:42:18,330
+are water soluble because they are considered to
+
+460
+00:42:18,330 --> 00:42:25,460
+be polar however higher alcohols arenon-polar and
+
+461
+00:42:25,460 --> 00:42:30,540
+so they are water insoluble الان بيستعملوا بدل
+
+462
+00:42:30,540 --> 00:42:33,520
+soluble و insoluble كلمة تانية عارفين شو بيسموها
+
+463
+00:42:33,520 --> 00:42:39,120
+missable missable لما نحط سائلين مع بعض و ينخلطوا
+
+464
+00:42:39,120 --> 00:42:44,140
+مع بعض بنستعملها بين السوائلفلما نقول completely
+
+465
+00:42:44,140 --> 00:42:49,780
+miscible يعني زي سائلين نحطهم في بعض و يخلطوا 100%
+
+466
+00:42:49,780 --> 00:42:54,220
+مثلا لو عمنا حطينا الاسيتون مع الميه الاسيتون
+
+467
+00:42:54,220 --> 00:42:57,340
+بيدوب في الميه الاثانول مع الميه الميثانول مع
+
+468
+00:42:57,340 --> 00:43:02,190
+الميه they are miscible لكن لو حطينا ال oilمع
+
+469
+00:43:02,190 --> 00:43:08,190
+الميّه بيكونوا immiscible أو non miscible يعني ما
+
+470
+00:43:08,190 --> 00:43:11,850
+بيدوبوش في بعض ف miscible تستعمل التعبير عن
+
+471
+00:43:11,850 --> 00:43:16,410
+السوائل اللي بتخلق مع بعضها البعض واضح؟ زي
+
+472
+00:43:16,410 --> 00:43:22,650
+soluble, miscibleالـ Hydrogen Bonding حكيناه
+
+473
+00:43:22,650 --> 00:43:25,970
+ووضحناه الآن ال acidity of alcohols الحقيقة موضوع
+
+474
+00:43:25,970 --> 00:43:30,630
+كبير يعني ربما يحتاج محاضرة كاملة بنبدأ فيه المرة
+
+475
+00:43:30,630 --> 00:43:35,090
+القادمة حمضية الكحولات إذا كان بإمكانك تراجعوا
+
+476
+00:43:35,090 --> 00:43:39,530
+مفهوم الحمضية مما تعلمته سابقا بيكون جيد
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/YZU5twA1Dw4_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/YZU5twA1Dw4_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..cd9a7f815ca6f68d3936894f12a8434e2ec2fdab
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/YZU5twA1Dw4_raw.json
@@ -0,0 +1 @@
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"end": 229.34, "word": " لالديهيد", "probability": 0.881640625}, {"start": 229.34, "end": 229.54, "word": " من", "probability": 0.88916015625}, {"start": 229.54, "end": 230.2, "word": " كحول", "probability": 0.9661458333333334}, {"start": 230.2, "end": 230.64, "word": " الى", "probability": 0.630859375}, {"start": 230.64, "end": 231.18, "word": " كيتون", "probability": 0.9845377604166666}, {"start": 231.18, "end": 231.72, "word": " من", "probability": 0.92333984375}, {"start": 231.72, "end": 232.52, "word": " الكاين", "probability": 0.689453125}, {"start": 232.52, "end": 232.94, "word": " الى", "probability": 0.96728515625}, {"start": 232.94, "end": 233.52, "word": " كيتون", "probability": 0.9807942708333334}], "temperature": 1.0}, {"id": 10, "seek": 26258, "start": 233.77, "end": 262.59, "text": "الان طالما صار عندى مسميين طالما صار عندى مسميين اذا الشغل هتمر عندى مرتين يعني لما انا بقول ان انا عندى كحول بده يصير aldehyde او كيتون هتلاقوا انحنا نذكرها لما بنحكي عن ال alcohol كتفاعل و نذكرها لما بنحكي عن ال aldehydes و ال ketones كطريقة للتحضير بعد شوية هنيجي على ال aldehydes و ال ketones طالما هذه العملية أكسدة طب لو رجعنا فيها رجوع", "tokens": [6027, 7649, 23032, 6027, 15042, 20328, 9640, 43242, 7578, 3714, 38251, 1829, 9957, 23032, 6027, 15042, 20328, 9640, 43242, 7578, 3714, 38251, 1829, 9957, 1975, 15730, 25124, 17082, 1211, 8032, 39237, 2288, 43242, 7578, 3714, 43500, 9957, 37495, 22653, 5296, 15042, 1975, 8315, 4724, 39648, 16472, 1975, 8315, 43242, 7578, 9122, 5016, 12610, 47525, 3224, 7251, 9381, 13546, 16798, 68, 3495, 1479, 1975, 2407, 9122, 36081, 11536, 8032, 2655, 15040, 4587, 14407, 16472, 5016, 8315, 8717, 8848, 37983, 11296, 5296, 15042, 44945, 5016, 4117, 1829, 18871, 2423, 7658, 9122, 2655, 5172, 995, 30241, 4032, 8717, 8848, 37983, 11296, 5296, 15042, 44945, 5016, 4117, 1829, 18871, 2423, 16798, 68, 3495, 14792, 4032, 2423, 14979, 2213, 9122, 9566, 16572, 28671, 24976, 2655, 5016, 11242, 13546, 39182, 13412, 2407, 10632, 8032, 22653, 7435, 1829, 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{"start": 251.75, "end": 252.31, "word": " ketones", "probability": 0.822265625}, {"start": 252.31, "end": 253.41, "word": " كطريقة", "probability": 0.9796142578125}, {"start": 253.41, "end": 254.17, "word": " للتحضير", "probability": 0.90751953125}, {"start": 254.17, "end": 254.79, "word": " بعد", "probability": 0.90283203125}, {"start": 254.79, "end": 255.29, "word": " شوية", "probability": 0.9695638020833334}, {"start": 255.29, "end": 256.13, "word": " هنيجي", "probability": 0.72650146484375}, {"start": 256.13, "end": 256.31, "word": " على", "probability": 0.728515625}, {"start": 256.31, "end": 256.47, "word": " ال", "probability": 0.97412109375}, {"start": 256.47, "end": 257.01, "word": " aldehydes", "probability": 0.9190673828125}, {"start": 257.01, "end": 257.17, "word": " و", "probability": 0.974609375}, {"start": 257.17, "end": 257.29, "word": " ال", "probability": 0.8095703125}, {"start": 257.29, "end": 257.85, "word": " ketones", "probability": 0.914794921875}, {"start": 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{"start": 270.26, "end": 270.98, "word": " ايش؟", "probability": 0.688720703125}, {"start": 270.98, "end": 271.7, "word": " alcohol", "probability": 0.314697265625}, {"start": 271.7, "end": 273.22, "word": " فالعملية", "probability": 0.8892578125}, {"start": 273.22, "end": 273.82, "word": " عملية", "probability": 0.927734375}, {"start": 273.82, "end": 275.1, "word": " متعاكسة", "probability": 0.9303385416666666}, {"start": 275.1, "end": 275.38, "word": " وعشان", "probability": 0.90087890625}, {"start": 275.38, "end": 275.78, "word": " كده", "probability": 0.5987141927083334}, {"start": 275.78, "end": 276.46, "word": " الكلام", "probability": 0.94775390625}, {"start": 276.46, "end": 276.96, "word": " بنشوفه", "probability": 0.928466796875}, {"start": 276.96, "end": 277.4, "word": " باكثر", "probability": 0.7454833984375}, {"start": 277.4, "end": 277.62, "word": " من", "probability": 0.97705078125}, {"start": 277.62, "end": 278.08, "word": " مكان", "probability": 0.991455078125}, 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" معناه", "probability": 0.9059244791666666}, {"start": 316.08, "end": 316.5, "word": " ربوز", "probability": 0.7861328125}, {"start": 316.5, "end": 316.74, "word": " لكن", "probability": 0.84423828125}, {"start": 316.74, "end": 316.94, "word": " في", "probability": 0.943359375}, {"start": 316.94, "end": 317.36, "word": " النهاية", "probability": 0.9599609375}, {"start": 317.36, "end": 317.92, "word": " بواقع", "probability": 0.974365234375}, {"start": 317.92, "end": 318.74, "word": " الحياة", "probability": 0.9939778645833334}, {"start": 318.74, "end": 319.5, "word": " بتنتهي", "probability": 0.9490966796875}, {"start": 319.5, "end": 319.68, "word": " انها", "probability": 0.828125}, {"start": 319.68, "end": 320.58, "word": " مركبات", "probability": 0.9285888671875}], "temperature": 1.0}, {"id": 14, "seek": 33477, "start": 320.77, "end": 334.77, "text": "الها وجود في الحياة العملية، الها تطبيق على سبيل المثال ال Benzaldehyde هذا Aldehyde Benzaldehyde هذا هو عبارة عن ال oil of almonds هو زيت اللوز", "tokens": [6027, 11296, 49610, 23328, 8978, 21542, 25528, 3660, 18863, 42213, 10632, 12399, 2423, 11296, 6055, 9566, 21292, 4587, 15844, 8608, 21292, 1211, 9673, 12984, 6027, 2423, 3964, 89, 304, 1479, 3495, 1479, 23758, 24031, 68, 3495, 1479, 3964, 89, 304, 1479, 3495, 1479, 23758, 31439, 6225, 3555, 9640, 3660, 18871, 2423, 3184, 295, 40973, 31439, 30767, 36081, 13672, 2407, 11622], "avg_logprob": -0.19902663641288632, "compression_ratio": 1.4503311258278146, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 320.77, "end": 321.49, "word": "الها", "probability": 0.55517578125}, {"start": 321.49, "end": 322.29, "word": " وجود", "probability": 0.949951171875}, {"start": 322.29, "end": 322.41, "word": " في", "probability": 0.9013671875}, {"start": 322.41, "end": 322.77, "word": " الحياة", "probability": 0.9952799479166666}, {"start": 322.77, "end": 323.35, "word": " العملية،", "probability": 0.7989501953125}, {"start": 323.35, "end": 323.55, "word": " الها", 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عبارة", "probability": 0.99658203125}, {"start": 331.59, "end": 331.81, "word": " عن", "probability": 0.998046875}, {"start": 331.81, "end": 331.95, "word": " ال", "probability": 0.39697265625}, {"start": 331.95, "end": 332.25, "word": " oil", "probability": 0.900390625}, {"start": 332.25, "end": 332.47, "word": " of", "probability": 0.9755859375}, {"start": 332.47, "end": 333.09, "word": " almonds", "probability": 0.87548828125}, {"start": 333.09, "end": 333.67, "word": " هو", "probability": 0.6337890625}, {"start": 333.67, "end": 334.21, "word": " زيت", "probability": 0.950927734375}, {"start": 334.21, "end": 334.77, "word": " اللوز", "probability": 0.9705403645833334}], "temperature": 1.0}, {"id": 15, "seek": 36088, "start": 336.32, "end": 360.88, "text": "واضح؟ في زيت مشهور اسمه زيت اللوز لو أسرنا اللوز بيطلع منه زيت اللي هو ال benz aldehyde هذا ال aldehyde اللي شايفينه C double bond OH مع حلقة بنزين و double bond هذا مركب كامل هذا اسمه cinnamaldehyde cinnamaldehyde جاية من ال cinnamon cinnamon يعني جرفة", "tokens": [2407, 46958, 5016, 22807, 8978, 30767, 36081, 37893, 3224, 13063, 24525, 2304, 3224, 30767, 36081, 13672, 2407, 11622, 45164, 5551, 3794, 2288, 8315, 13672, 2407, 11622, 4724, 1829, 9566, 1211, 3615, 9154, 3224, 30767, 36081, 13672, 1829, 31439, 2423, 44335, 16798, 68, 3495, 1479, 23758, 2423, 16798, 68, 3495, 1479, 13672, 1829, 13412, 995, 33911, 9957, 3224, 383, 3834, 6086, 13931, 20449, 11331, 1211, 28671, 44945, 11622, 9957, 4032, 3834, 6086, 23758, 3714, 31747, 3555, 9122, 10943, 1211, 23758, 24525, 2304, 3224, 6539, 5378, 304, 1479, 3495, 1479, 6539, 5378, 304, 1479, 3495, 1479, 10874, 995, 10632, 9154, 2423, 6539, 5378, 266, 6539, 5378, 266, 37495, 22653, 10874, 28480, 3660], "avg_logprob": -0.16905967850942868, "compression_ratio": 1.7677725118483412, "no_speech_prob": 4.172325134277344e-07, "words": [{"start": 336.32, "end": 337.0, "word": "واضح؟", "probability": 0.6759033203125}, {"start": 337.0, "end": 337.24, "word": " في", 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{"start": 342.18, "end": 342.42, "word": " هو", "probability": 0.98193359375}, {"start": 342.42, "end": 342.54, "word": " ال", "probability": 0.8759765625}, {"start": 342.54, "end": 342.8, "word": " benz", "probability": 0.383056640625}, {"start": 342.8, "end": 343.74, "word": " aldehyde", "probability": 0.8021240234375}, {"start": 343.74, "end": 344.44, "word": " هذا", "probability": 0.91455078125}, {"start": 344.44, "end": 344.62, "word": " ال", "probability": 0.9697265625}, {"start": 344.62, "end": 345.52, "word": " aldehyde", "probability": 0.872802734375}, {"start": 345.52, "end": 345.78, "word": " اللي", "probability": 0.9345703125}, {"start": 345.78, "end": 346.46, "word": " شايفينه", "probability": 0.98837890625}, {"start": 346.46, "end": 347.44, "word": " C", "probability": 0.39208984375}, {"start": 347.44, "end": 347.7, "word": " double", "probability": 0.68359375}, {"start": 347.7, "end": 348.02, "word": " bond", "probability": 0.904296875}, {"start": 348.02, "end": 348.68, "word": " OH", "probability": 0.8203125}, {"start": 348.68, "end": 349.14, "word": " مع", "probability": 0.95263671875}, {"start": 349.14, "end": 349.58, "word": " حلقة", "probability": 0.9788411458333334}, {"start": 349.58, "end": 350.1, "word": " بنزين", "probability": 0.9778645833333334}, {"start": 350.1, "end": 350.2, "word": " و", "probability": 0.9482421875}, {"start": 350.2, "end": 350.44, "word": " double", "probability": 0.85693359375}, {"start": 350.44, "end": 350.82, "word": " bond", "probability": 0.94921875}, {"start": 350.82, "end": 351.1, "word": " هذا", "probability": 0.7900390625}, {"start": 351.1, "end": 351.64, "word": " مركب", "probability": 0.791015625}, {"start": 351.64, "end": 352.14, "word": " كامل", "probability": 0.98681640625}, {"start": 352.14, "end": 352.84, "word": " هذا", "probability": 0.91162109375}, {"start": 352.84, "end": 354.0, "word": " اسمه", "probability": 0.9710286458333334}, {"start": 354.0, "end": 355.48, "word": " cinnamaldehyde", "probability": 0.8230794270833334}, {"start": 355.48, "end": 356.88, "word": " cinnamaldehyde", "probability": 0.8623453776041666}, {"start": 356.88, "end": 357.42, "word": " جاية", "probability": 0.9456380208333334}, {"start": 357.42, "end": 357.82, "word": " من", "probability": 0.99267578125}, {"start": 357.82, "end": 358.12, "word": " ال", "probability": 0.53955078125}, {"start": 358.12, "end": 358.88, "word": " cinnamon", "probability": 0.5860188802083334}, {"start": 358.88, "end": 360.04, "word": " cinnamon", "probability": 0.8919270833333334}, {"start": 360.04, "end": 360.34, "word": " يعني", "probability": 0.94970703125}, {"start": 360.34, "end": 360.88, "word": " جرفة", "probability": 0.9215494791666666}], "temperature": 1.0}, {"id": 16, "seek": 37310, "start": 361.48, "end": 373.1, "text": "واضح؟ فهو المركب الأساسي اللي بيعطي الجرفة الريحة تبعتها لأن الجرفة اسمها cinnamon هو سموه إيش؟", "tokens": [2407, 46958, 5016, 22807, 6156, 3224, 2407, 9673, 31747, 3555, 16247, 3794, 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لأ؟ أكيد لأن high carbon حاملة OH", "tokens": [31187, 1975, 5016, 8315, 12174, 1211, 8315, 8978, 28242, 16247, 5016, 2407, 6027, 11778, 16373, 15042, 2423, 383, 3834, 6086, 422, 39894, 9381, 13546, 13931, 7251, 43020, 8978, 28242, 16247, 2304, 12984, 37977, 21136, 16758, 28671, 12602, 38251, 8315, 11296, 20666, 10721, 9778, 11242, 2288, 4032, 2423, 14962, 49242, 8032, 26108, 2304, 39627, 15730, 25124, 28820, 6024, 48506, 23758, 9673, 31747, 3555, 13672, 1829, 44650, 30544, 43242, 3224, 36632, 11242, 995, 8636, 326, 302, 304, 49429, 5296, 10721, 22807, 5551, 4117, 25708, 5296, 33456, 1090, 5954, 11331, 10943, 37977, 13931], "avg_logprob": -0.2529189580089443, "compression_ratio": 1.5304347826086957, "no_speech_prob": 0.0, "words": [{"start": 1633.01, "end": 1633.57, "word": "OH", "probability": 0.1492919921875}, {"start": 1633.57, "end": 1633.95, "word": " احنا", "probability": 0.7135416666666666}, {"start": 1633.95, "end": 1634.21, "word": " قلنا", "probability": 0.89453125}, {"start": 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قولنا oil of almond اللوز بالانجليزي بالالماني mandel ومن هنا استعمل mandilo nitral mandel من اللوز يعني كتير من ال common name علاقة في إيش", "tokens": [22396, 10720, 7411, 338, 20666, 45340, 7649, 1829, 37495, 22653, 5296, 2407, 11622, 16472, 2655, 14407, 39894, 15730, 37983, 9957, 12174, 36150, 13412, 2407, 10632, 5296, 15042, 5551, 9778, 3215, 8315, 2423, 44335, 304, 1479, 3495, 1479, 12174, 12610, 8315, 3184, 295, 29506, 2423, 1211, 2407, 11622, 20666, 7649, 7435, 20292, 11622, 1829, 20666, 45340, 7649, 1829, 7411, 338, 4032, 27842, 34105, 44713, 25957, 1211, 7411, 10720, 10900, 2155, 7411, 338, 9154, 13672, 2407, 11622, 37495, 22653, 9122, 2655, 13546, 9154, 2423, 2689, 1315, 11203, 995, 28671, 8978, 11933, 1829, 8592], "avg_logprob": -0.26222826734833093, "compression_ratio": 1.6748768472906403, "no_speech_prob": 0.0, "words": [{"start": 2314.29, "end": 2315.15, "word": "mandilo", "probability": 0.3641357421875}, {"start": 2315.15, "end": 2316.23, "word": " mandel", 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ال ايون شو هيصفاه minus عشان يطلع الجزية متعادلة بحطله lithium plus", "tokens": [1211, 5016, 19913, 14407, 9154, 2423, 3224, 25708, 23557, 36081, 11622, 13672, 1829, 37893, 3224, 13063, 3660, 10874, 28259, 23758, 9673, 31747, 11703, 3555, 2423, 20292, 12984, 1829, 10943, 16070, 10721, 19528, 22653, 20498, 13672, 1829, 44650, 36520, 4724, 1017, 39, 12, 5296, 5016, 19913, 14407, 16247, 19528, 22653, 20498, 4724, 2407, 11242, 3615, 3224, 41950, 21292, 3615, 1829, 4724, 1829, 30544, 1975, 1829, 8592, 6055, 1211, 9307, 3660, 3714, 29245, 3660, 11331, 9566, 14407, 47356, 1017, 39, 12, 28242, 2423, 1975, 1829, 11536, 13412, 2407, 39896, 9381, 5172, 40294, 3175, 6225, 8592, 7649, 7251, 9566, 1211, 3615, 25724, 11622, 10632, 44650, 3615, 18513, 37977, 4724, 5016, 9566, 43761, 32180, 1804], "avg_logprob": -0.29715402903301374, "compression_ratio": 1.669603524229075, "no_speech_prob": 0.0, "words": [{"start": 2520.92, "end": 2521.84, "word": "لحظوا", "probability": 0.6268310546875}, {"start": 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اه اذا هل جيتها بنصير نكتب reduction عشان تكون واضحة الأمور معاكم قبل الديهايدs produces primary alcohol", "tokens": [27375, 822, 7658, 1975, 15730, 16472, 2655, 3555, 3224, 14407, 20449, 1829, 10874, 25708, 995, 16472, 3224, 5296, 15042, 2423, 3224, 7435, 20498, 46811, 15844, 2423, 2423, 16254, 11296, 25708, 6225, 995, 16254, 1975, 2655, 4117, 12610, 1975, 3224, 1975, 15730, 8032, 1211, 10874, 36081, 11296, 44945, 9381, 13546, 8717, 4117, 2655, 3555, 11004, 6225, 8592, 7649, 6055, 30544, 4032, 46958, 5016, 3660, 16247, 2304, 13063, 20449, 995, 24793, 12174, 36150, 2423, 16254, 11296, 25708, 82, 14725, 6194, 7658], "avg_logprob": -0.24843748658895493, "compression_ratio": 1.5797872340425532, "no_speech_prob": 0.0, "words": [{"start": 2751.01, "end": 2751.83, "word": "secondary", "probability": 0.76318359375}, {"start": 2751.83, "end": 2752.37, "word": " alcohol", "probability": 0.869140625}, {"start": 2752.37, "end": 2752.87, "word": " اذا", "probability": 0.581787109375}, {"start": 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2835.21, "end": 2836.53, "word": " لما", "probability": 0.5748291015625}, {"start": 2836.53, "end": 2836.85, "word": " تشوفوا", "probability": 0.98876953125}, {"start": 2836.85, "end": 2837.21, "word": " الناتج", "probability": 0.8981119791666666}, {"start": 2837.21, "end": 2837.35, "word": " اللي", "probability": 0.991943359375}, {"start": 2837.35, "end": 2837.77, "word": " عندكم", "probability": 0.987060546875}, {"start": 2837.77, "end": 2838.59, "word": " secondary", "probability": 0.91748046875}, {"start": 2838.59, "end": 2839.43, "word": " alcohol", "probability": 0.86962890625}, {"start": 2839.43, "end": 2839.93, "word": " إذا", "probability": 0.96435546875}, {"start": 2839.93, "end": 2840.31, "word": " ممكن", "probability": 0.97998046875}, {"start": 2840.31, "end": 2840.55, "word": " يكون", "probability": 0.98291015625}, {"start": 2840.55, "end": 2840.85, "word": " إيجا", "probability": 0.976318359375}, {"start": 2840.85, "end": 2841.01, "word": " من", "probability": 0.9931640625}, {"start": 2841.01, "end": 2841.33, "word": " وين", "probability": 0.897216796875}, {"start": 2841.33, "end": 2842.47, "word": " من", "probability": 0.62744140625}, {"start": 2842.47, "end": 2843.11, "word": " كيتون", "probability": 0.695068359375}, {"start": 2843.11, "end": 2843.95, "word": " واضح", "probability": 0.9069010416666666}, {"start": 2843.95, "end": 2844.97, "word": " الفكرة؟", "probability": 0.8421630859375}, {"start": 2844.97, "end": 2845.43, "word": " بنقف", "probability": 0.80517578125}, {"start": 2845.43, "end": 2845.65, "word": " عند", "probability": 0.98291015625}, {"start": 2845.65, "end": 2845.87, "word": " هذه", "probability": 0.76318359375}, {"start": 2845.87, "end": 2846.33, "word": " النقطة", "probability": 0.984375}, {"start": 2846.33, "end": 2846.65, "word": " المرة", "probability": 0.892822265625}, {"start": 2846.65, "end": 2847.61, "word": " القادمة", "probability": 0.9892578125}, {"start": 2847.61, "end": 2847.79, "word": " إن", "probability": 0.432861328125}, {"start": 2847.79, "end": 2847.95, "word": " شاء", "probability": 0.96630859375}, {"start": 2847.95, "end": 2848.11, "word": " الله", "probability": 0.95751953125}, {"start": 2848.11, "end": 2849.21, "word": " بنحكي", "probability": 0.91943359375}, {"start": 2849.21, "end": 2849.51, "word": " عن", "probability": 0.98779296875}, {"start": 2849.51, "end": 2850.19, "word": " تفاعل", "probability": 0.9427490234375}, {"start": 2850.19, "end": 2850.83, "word": " الديهيدس", "probability": 0.658349609375}, {"start": 2850.83, "end": 2851.57, "word": " والكيتون", "probability": 0.8038330078125}, {"start": 2851.57, "end": 2852.23, "word": " مع", "probability": 0.759765625}, {"start": 2852.23, "end": 2853.23, "word": " متفاعل", "probability": 0.886474609375}, {"start": 2853.23, "end": 2853.87, "word": " اسمه", "probability": 0.9244791666666666}, {"start": 2853.87, "end": 2854.31, "word": " green", "probability": 0.364990234375}, {"start": 2854.31, "end": 2854.69, "word": " yard", "probability": 0.335693359375}, {"start": 2854.69, "end": 2855.27, "word": " reagent", "probability": 0.878662109375}, {"start": 2855.27, "end": 2855.67, "word": " عمرنا", "probability": 0.939453125}, {"start": 2855.67, "end": 2856.11, "word": " حكينا", "probability": 0.98974609375}, {"start": 2856.11, "end": 2856.69, "word": " عنه؟", "probability": 0.94287109375}], "temperature": 1.0}, {"id": 119, "seek": 286622, "start": 2857.32, "end": 2866.22, "text": "بنعرفه المرة الجاية وبنشوف كيف بتفاعل ال الديهيد والكيتون مع ال green yard reagent شكرا", "tokens": [3555, 1863, 3615, 28480, 3224, 9673, 25720, 25724, 995, 10632, 46599, 1863, 8592, 38688, 9122, 33911, 39894, 5172, 995, 30241, 2423, 2423, 16254, 3224, 25708, 16070, 4117, 36081, 11536, 20449, 2423, 3092, 11682, 26949, 317, 13412, 4117, 23557], "avg_logprob": -0.20592948565116295, "compression_ratio": 1.2743362831858407, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2857.32, "end": 2858.04, "word": "بنعرفه", "probability": 0.9056640625}, {"start": 2858.04, "end": 2858.34, "word": " المرة", "probability": 0.928466796875}, {"start": 2858.34, "end": 2858.92, "word": " الجاية", "probability": 0.94140625}, {"start": 2858.92, "end": 2859.74, "word": " وبنشوف", "probability": 0.84423828125}, {"start": 2859.74, "end": 2860.0, "word": " كيف", "probability": 0.96826171875}, {"start": 2860.0, "end": 2860.74, "word": " بتفاعل", "probability": 0.81536865234375}, {"start": 2860.74, "end": 2861.26, "word": " ال", "probability": 0.8857421875}, {"start": 2861.26, "end": 2861.86, "word": " الديهيد", "probability": 0.71221923828125}, {"start": 2861.86, "end": 2862.66, "word": " والكيتون", "probability": 0.7459716796875}, {"start": 2862.66, "end": 2863.3, "word": " مع", "probability": 0.93017578125}, {"start": 2863.3, "end": 2863.68, "word": " ال", "probability": 0.859375}, {"start": 2863.68, "end": 2864.04, "word": " green", "probability": 0.45703125}, {"start": 2864.04, "end": 2864.44, "word": " yard", "probability": 0.73681640625}, {"start": 2864.44, "end": 2865.48, "word": " reagent", "probability": 0.8505859375}, {"start": 2865.48, "end": 2866.22, "word": " شكرا", "probability": 0.92578125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2867.01425, "duration_after_vad": 2750.2293749999894}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/YZU5twA1Dw4_raw.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/YZU5twA1Dw4_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b0ab76fbc41eb0eb433ee7322cf3a1d9a5cd0846
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/YZU5twA1Dw4_raw.srt
@@ -0,0 +1,2140 @@
+1
+00:00:19,470 --> 00:00:24,730
+بسم الله الرحمن الرحيم بدأنا من محاضرة او محاضرتين
+
+2
+00:00:24,730 --> 00:00:28,470
+في موضوع ال الديهيدس والكيتونز اتعرفنا عليهم ليش
+
+3
+00:00:28,470 --> 00:00:34,430
+اتصنفوا مع بعض تسمية ال الديهيدس والكيتونز طرق
+
+4
+00:00:34,430 --> 00:00:38,690
+صناعية لتحضير اشهر ال الديهيدس والكيتونز كان اخر
+
+5
+00:00:38,690 --> 00:00:44,270
+شيء اتكلمنا عنه الان في المختبر الطرق العامة
+
+6
+00:00:44,270 --> 00:00:49,420
+لتحضير ال الديهيدس والكيتونزإذا بنستعرضها مع بعض
+
+7
+00:00:49,420 --> 00:00:53,560
+بنلاحظ أن هذه الأشياء مرت علينا الحقيقة يعني
+
+8
+00:00:53,560 --> 00:00:58,080
+الطريقة الأولى لتحضير ال aldehydes و ال ketones من
+
+9
+00:00:58,080 --> 00:01:03,300
+أجسدة الكحولات لما أخدنا ال alcohols قلنا أن ال
+
+10
+00:01:03,300 --> 00:01:06,880
+alcohols they are either primary, secondary or
+
+11
+00:01:06,880 --> 00:01:13,120
+tertiary وقلنا أن ال primaryبصيروا باستعمال ال BCC
+
+12
+00:01:13,120 --> 00:01:16,960
+الديهيدز و ممكن يمدوا اكتر لو كان العامل مؤاكسد
+
+13
+00:01:16,960 --> 00:01:20,660
+اقوى بصيروا acids هذا مش الموضوع هنا ال secondary
+
+14
+00:01:20,660 --> 00:01:26,500
+alcohol باستعمال كيامانو 4 او كيتو كروميون 2
+
+15
+00:01:27,340 --> 00:01:33,400
+برمجانات البوتاسيوم كيتو كروميوم 207 بوتاسيوم داي
+
+16
+00:01:33,400 --> 00:01:37,940
+كروميت أو كروميك أكسيد بيصيروا كيتون فهذا أكسد
+
+17
+00:01:37,940 --> 00:01:42,720
+بالالكوهولز هي طريقة في انها لتحضير ال الديهايد
+
+18
+00:01:42,720 --> 00:01:45,520
+والكيتون من ال primer بناخد ال الديهايد ومن
+
+19
+00:01:45,520 --> 00:01:50,730
+السكندر بناخدالكيتون هذه طريقة مرت علينا سابقا
+
+20
+00:01:50,730 --> 00:01:58,450
+الاروماتيك كيتون أخدناهم كنا انحضر الاسيتوفينون
+
+21
+00:01:58,450 --> 00:02:06,640
+مثلا من استعمال ال acid halidesR-C-O-C-L هذي C-O
+
+22
+00:02:06,640 --> 00:02:10,700
+معناها C double bond و C-L في وجود ألومنيوم
+
+23
+00:02:10,700 --> 00:02:14,400
+الكلورايد الألومنيوم الكلورايد بيسحب الكلور و
+
+24
+00:02:14,400 --> 00:02:18,280
+بيعمل عندنا الايون الموجب و بيصير Electrophilic
+
+25
+00:02:18,280 --> 00:02:22,920
+Substitution اللي سمناه Friedel Crafts Acylation
+
+26
+00:02:22,920 --> 00:02:26,700
+واضح سمناه Friedel Crafts Acylation أخدنا Friedel
+
+27
+00:02:26,700 --> 00:02:30,720
+Crafts Alkylation و Acylation في شبطر الاروماتيك
+
+28
+00:02:31,490 --> 00:02:38,470
+from alkynes اخدنا احنا ان ال alkynes بيضيفوا مية
+
+29
+00:02:38,470 --> 00:02:42,090
+المية اللى بيضيفوها ممكن تكون حسب قاعدة
+
+30
+00:02:42,090 --> 00:02:46,390
+Markovnikov يضيف HOO يصير اندي double bond او Anti
+
+31
+00:02:46,390 --> 00:02:51,070
+Markovnikov HOH و في كل الأحوال لما يصير اندي in
+
+32
+00:02:51,070 --> 00:02:55,810
+all يعني هذا ال alkyne لو ضفنا عليه HOOH بدو يصير
+
+33
+00:02:55,810 --> 00:03:03,290
+double bondInol أخدنا أن Inol يعمل توتوميريزم
+
+34
+00:03:03,290 --> 00:03:08,550
+لكيتون أو لالديهيد سمناها keto inol توتوميريزم
+
+35
+00:03:08,550 --> 00:03:12,050
+يعني بهذا المثال لما نضيف الميه في وجود الحامض
+
+36
+00:03:12,050 --> 00:03:17,090
+فالإضافة بمرحلتها الأولى Markov-Nikov addition لما
+
+37
+00:03:17,090 --> 00:03:21,850
+نعمل التوتوميريزم ال COH بتصير C double bond O
+
+38
+00:03:21,850 --> 00:03:25,830
+يعني هذا بنرجع في الفصل التالت هذا بنرجع في الفصل
+
+39
+00:03:25,830 --> 00:03:30,800
+الرابع هذا بنرجع في الفصلالسابق كل هذه طرق تحضير
+
+40
+00:03:30,800 --> 00:03:36,580
+الالديهيد والكيتون مرت معناه وهذه الميزة الحقيقة
+
+41
+00:03:36,580 --> 00:03:41,540
+موجودة في ال organ ال chemistry انه انا في اندي شي
+
+42
+00:03:41,540 --> 00:03:45,300
+اسمه functional group interconvergent يعني اتحول
+
+43
+00:03:45,300 --> 00:03:51,180
+من شغلة لشغلة من كحول لالديهيد من كحول الى كيتون
+
+44
+00:03:51,180 --> 00:03:57,130
+من الكاين الى كيتونالان طالما صار عندى مسميين
+
+45
+00:03:57,130 --> 00:04:01,670
+طالما صار عندى مسميين اذا الشغل هتمر عندى مرتين
+
+46
+00:04:01,670 --> 00:04:04,150
+يعني لما انا بقول ان انا عندى كحول بده يصير
+
+47
+00:04:04,150 --> 00:04:07,530
+aldehyde او كيتون هتلاقوا انحنا نذكرها لما بنحكي
+
+48
+00:04:07,530 --> 00:04:10,990
+عن ال alcohol كتفاعل و نذكرها لما بنحكي عن ال
+
+49
+00:04:10,990 --> 00:04:15,290
+aldehydes و ال ketones كطريقة للتحضير بعد شوية
+
+50
+00:04:15,290 --> 00:04:18,690
+هنيجي على ال aldehydes و ال ketones طالما هذه
+
+51
+00:04:18,690 --> 00:04:25,320
+العملية أكسدة طب لو رجعنا فيها رجوعهتصير تفاعل لل
+
+52
+00:04:25,320 --> 00:04:28,060
+الديهيد والكيتون هلاحظ ان ال reduction of
+
+53
+00:04:28,060 --> 00:04:31,700
+aldehydes and ketones produces ايش؟ alcohol
+
+54
+00:04:31,700 --> 00:04:36,960
+فالعملية عملية متعاكسة وعشان كده الكلام بنشوفه
+
+55
+00:04:36,960 --> 00:04:41,820
+باكثر من مكان alcohol صار الديهيد او كيتون بالاكسة
+
+56
+00:04:41,820 --> 00:04:48,000
+ده الآن طب الديهيد او كيتونبالاختصار هيرجع ايش؟
+
+57
+00:04:48,000 --> 00:04:53,740
+هيرجع لالكول وسبق احنا انه وضحنا معنى الأكسادة ان
+
+58
+00:04:53,740 --> 00:05:00,020
+هي في النهاية اما انها زيادة في المحتوى الاكسوجيني
+
+59
+00:05:00,020 --> 00:05:05,940
+او نقص في محتوى الهيدروجينيالان هذه ال aldehydes و
+
+60
+00:05:05,940 --> 00:05:10,920
+ال ketones خلينا نقول في النهاية هي و كل الكيميا
+
+61
+00:05:10,920 --> 00:05:15,680
+لازم نفهمها من منطق التطبيق العملي يعني هي بتبدأ
+
+62
+00:05:15,680 --> 00:05:19,680
+معناه ربوز لكن في النهاية بواقع الحياة بتنتهي انها
+
+63
+00:05:19,680 --> 00:05:25,170
+مركباتالها وجود في الحياة العملية، الها تطبيق على
+
+64
+00:05:25,170 --> 00:05:28,790
+سبيل المثال ال Benzaldehyde هذا Aldehyde
+
+65
+00:05:28,790 --> 00:05:33,670
+Benzaldehyde هذا هو عبارة عن ال oil of almonds هو
+
+66
+00:05:33,670 --> 00:05:39,600
+زيت اللوزواضح؟ في زيت مشهور اسمه زيت اللوز لو
+
+67
+00:05:39,600 --> 00:05:43,740
+أسرنا اللوز بيطلع منه زيت اللي هو ال benz aldehyde
+
+68
+00:05:43,740 --> 00:05:49,140
+هذا ال aldehyde اللي شايفينه C double bond OH مع
+
+69
+00:05:49,140 --> 00:05:54,000
+حلقة بنزين و double bond هذا مركب كامل هذا اسمه
+
+70
+00:05:54,000 --> 00:05:58,880
+cinnamaldehyde cinnamaldehyde جاية من ال cinnamon
+
+71
+00:05:58,880 --> 00:06:05,880
+cinnamon يعني جرفةواضح؟ فهو المركب الأساسي اللي
+
+72
+00:06:05,880 --> 00:06:10,360
+بيعطي الجرفة الريحة تبعتها لأن الجرفة اسمها
+
+73
+00:06:10,360 --> 00:06:16,560
+cinnamon هو سموه إيش؟cinnamaldehyde مثلا بالالماني
+
+74
+00:06:16,560 --> 00:06:22,480
+الجرفة اسمها zimt فبيسموه zimt aldehyde واضح zimt
+
+75
+00:06:22,480 --> 00:06:27,300
+aldehyde هنا cinnamon cinnamaldehyde واضح فهذه
+
+76
+00:06:27,300 --> 00:06:31,620
+الجرفة اللي احنا بنتناولها في النهاية هي aldehyde
+
+77
+00:06:31,620 --> 00:06:36,180
+مر علينا سابقا ان الفانيلة هي عبارة عن aromatic
+
+78
+00:06:36,180 --> 00:06:40,600
+aldehyde عليه مجموعة هيدروكسي وميثوكسي الفانيلين
+
+79
+00:06:41,300 --> 00:06:47,120
+الان كتير ناس بيحبوا زيت النعناع sperminate oil
+
+80
+00:06:47,120 --> 00:06:51,220
+اللى بدخل فى مشتقات كتيرة و لعلاج الزور هذا عبارة
+
+81
+00:06:51,220 --> 00:06:54,680
+عن كيتون هى فيه ال C double bond O اللى بنسميه
+
+82
+00:06:54,680 --> 00:06:59,960
+carbonالمركب الكيميائي carbon لكن هذا ال carbon هو
+
+83
+00:06:59,960 --> 00:07:05,500
+ال sperm in it oil هو زيت النعمة واضح هذا المركب
+
+84
+00:07:05,500 --> 00:07:08,960
+لاحظوا بتلاحظوه مركب كبير لكن انا بهمن المجموعة
+
+85
+00:07:08,960 --> 00:07:12,280
+الوظيفية في نهاية المجموعة الوظيفية ايش فيه C
+
+86
+00:07:12,280 --> 00:07:17,240
+double bond O كيتون finally كيتون هذا ال camphor
+
+87
+00:07:17,240 --> 00:07:21,720
+الكفور واضح اللي بيستعملوه لعلاج الرجلين و ما إلى
+
+88
+00:07:21,720 --> 00:07:28,840
+ذلك الآن مش ضايل عندنا غير مينغير البحتري عاد
+
+89
+00:07:28,840 --> 00:07:34,560
+الربيع الى الدنيا بموقبه فزينت واكتست بالسندس
+
+90
+00:07:34,560 --> 00:07:38,580
+الشجر اه الياسمين الياسمين خلال أسبوعين اللي عندهم
+
+91
+00:07:38,580 --> 00:07:44,570
+ياسمينة هيلاحظوا كل الياسمينة إيش تصيربيضة من إيش؟
+
+92
+00:07:44,570 --> 00:07:50,590
+أه هي الياسمون كيتو واضح؟ ملاحظين مركب معين هذا
+
+93
+00:07:50,590 --> 00:07:56,910
+اللي هو الياسمون من ال oil of ياسمين من زيت
+
+94
+00:07:56,910 --> 00:08:01,190
+الياسمين بنطول هذا المركب الأساسي اللي بيعطيها
+
+95
+00:08:01,190 --> 00:08:04,790
+الريحة الكويسة سواء عملنا منه أطور أو الناس حتى
+
+96
+00:08:04,790 --> 00:08:11,500
+بيشموها و هي على الشجر ريحة جيدةفهذه المراكبات
+
+97
+00:08:11,500 --> 00:08:16,860
+الحقيقة يعني إلها مجال كبير في التطبيق طبعا أكيد
+
+98
+00:08:16,860 --> 00:08:20,060
+إلها مجالات في أشياء كتيرة غير هيك في أدوية في
+
+99
+00:08:20,060 --> 00:08:24,280
+الصناعة ولذلك إحنا بندرسها بعنق و بنتعرف عليها
+
+100
+00:08:24,280 --> 00:08:31,560
+الآن لو بدنا نيجي بعد هيك لتفاعلات ال aldehydes و
+
+101
+00:08:31,560 --> 00:08:38,080
+ال ketones قلنا بشكل عام الأمر مختصر فيهكلمة واحدة
+
+102
+00:08:38,080 --> 00:08:43,900
+اللي هي addition واضح طبعا لو اجينا بدنا ندقق في
+
+103
+00:08:43,900 --> 00:08:48,540
+كلمة ال addition in eucleophilic addition بمعنى
+
+104
+00:08:48,540 --> 00:08:54,820
+المهاجم لازم يكون ايش؟اليوكليوفايل ليش المهاجم
+
+105
+00:08:54,820 --> 00:08:59,660
+لازم يكون اليوكليوفايل لأن الالدهايد والكيتون فيهم
+
+106
+00:08:59,660 --> 00:09:03,060
+السيضة بالبوند او اللي موجودة لو اتطلعنا علي اي
+
+107
+00:09:03,060 --> 00:09:07,040
+مكان ارسمها بشكل اوضح السيضة بالبوند او لو اتطلع
+
+108
+00:09:07,040 --> 00:09:10,420
+السلبية هذا الطرف partially positive هذا partially
+
+109
+00:09:10,420 --> 00:09:16,870
+negative الان اللي بدو يهاجم عادةاليوكليوفايل واضح
+
+110
+00:09:16,870 --> 00:09:21,210
+اللي بيهاجم عادة نيوكليوفايل لما يهاجم هنا زوج
+
+111
+00:09:21,210 --> 00:09:25,430
+الإلكترونات هذا بتتحرك بيصف النتيجة ان هي carbon
+
+112
+00:09:25,430 --> 00:09:33,470
+OH نيوكليوفايل الان في عند اصلا مجموعتين تانين هنا
+
+113
+00:09:33,470 --> 00:09:37,350
+مش رسموهم دولة مافيش عليهم أي تغيير
+
+114
+00:09:38,710 --> 00:09:42,830
+الخلاصة أن التفاعل الأساسي لـ aldehydes و لـ
+
+115
+00:09:42,830 --> 00:09:48,430
+ketones كان هناك double bond و أصبحت تنتين single
+
+116
+00:09:48,430 --> 00:09:53,550
+bond واحدة OH واحدة نيوكليوفايل بكل الأحوال هنا
+
+117
+00:09:53,550 --> 00:09:57,690
+عدد الروابط أربعة و هنا عدد الروابط أربعة فال
+
+118
+00:09:57,690 --> 00:10:04,000
+double bond O تصبحوبصير عنده رابطة جديدة مع ال
+
+119
+00:10:04,000 --> 00:10:09,580
+file واضح الفكرة هذا هو التفاعل اللي هيظل يتكرر
+
+120
+00:10:09,580 --> 00:10:17,260
+بناء على ذلك بصير الان كل هذه المحاضرةهتحكي شغلة
+
+121
+00:10:17,260 --> 00:10:21,260
+واحدة بسيطة اللي بيفهمها بيقدر إذا مستعجل يروح
+
+122
+00:10:21,260 --> 00:10:24,640
+يمشي إنه إيش أنواع الـ nucleophile اللي بتهاجم
+
+123
+00:10:24,640 --> 00:10:28,140
+أعطونا أمثلة بنقول نمروا واحد الميّه، نمروا اتنين
+
+124
+00:10:28,140 --> 00:10:31,260
+الكحول، نمروا تلاتة الـCr، نمروا أربعة الـH-,
+
+125
+00:10:31,260 --> 00:10:36,000
+نمروا خمسة كذا، نمروا ستة كذا فبكل المحاضرة هذه
+
+126
+00:10:36,000 --> 00:10:40,880
+فقط احنا بدنا نحتفظ بهذا ال frame إن هدول
+
+127
+00:10:40,880 --> 00:10:44,200
+المجموعتين في الأساس ماتغيروش الـC double bond O
+
+128
+00:10:44,200 --> 00:10:51,110
+صارت OHانغيّر هذه المجموعة واضحة الفكرة؟ بمعنى لو
+
+129
+00:10:51,110 --> 00:10:55,370
+انا الآن بقولكوا ان النيوكليوفايل كان ميّه ايش
+
+130
+00:10:55,370 --> 00:11:01,110
+هنحط هنا؟ OH بيصير عائلة اسمها الهيدريت اللي فيها
+
+131
+00:11:01,110 --> 00:11:04,010
+كاربون حاملة انت نواتش بحكي بالتفصيل ماتستعجلوش
+
+132
+00:11:04,010 --> 00:11:11,350
+الآن طب لو ضفنا كحول؟ OR بيصير عائلة جديدة اسمها
+
+133
+00:11:11,350 --> 00:11:15,570
+سيانهيدريل شوف كيف البساطة طب لو ضفنا CM؟
+
+134
+00:11:18,510 --> 00:11:26,090
+لحظة لو سمحتوا لو ضفنا OR بيصير عندنا عائلة اسمها
+
+135
+00:11:26,090 --> 00:11:29,570
+hemacetal انا قلت cyanohedrin hemacetal طيب لو
+
+136
+00:11:29,570 --> 00:11:37,070
+ضفنا CN cyanohedrin بيسموها لو ضفنا H minus هذه
+
+137
+00:11:37,070 --> 00:11:46,110
+عملية الاختزال H برجعلك كحول واضح؟ لو ضفنا Amin
+
+138
+00:11:46,860 --> 00:11:53,400
+أمونيا انا H2 متعودين انتوا لنيوترا ليوكليوفايل شو
+
+139
+00:11:53,400 --> 00:12:01,380
+هيصير هيفقد H و هكذا فكل الأمثلة اللي هنحكيها
+
+140
+00:12:01,380 --> 00:12:05,020
+هتكون ماخدة هذا الإطار العام كل الأمثلة اللي
+
+141
+00:12:05,020 --> 00:12:08,700
+هنحكيها هتاخد هذا الإطار العام البسيط
+
+142
+00:12:11,390 --> 00:12:18,850
+بفيد شغلة أن هذا التفاعل بشكل عام بتم له catalysis
+
+143
+00:12:18,850 --> 00:12:23,970
+يعني تسريع بإضافة H plus عشان هيك في معظم الحالات
+
+144
+00:12:23,970 --> 00:12:29,910
+هتلاحظوا على سهم التفاعل موجود عنده في وجود إيشأتش
+
+145
+00:12:29,910 --> 00:12:37,090
+بلس وظيفتها أن تعمل تسريع للتفاعل لاحظوا لو أنا
+
+146
+00:12:37,090 --> 00:12:40,710
+كان عندي الديهيد او كيتون وضفت عليه أتش بلس الأتش
+
+147
+00:12:40,710 --> 00:12:46,140
+بلس وين هتروح على الموجة ولا على الأكسجين السالبع
+
+148
+00:12:46,140 --> 00:12:51,580
+الأكسجل موجب على سالب هتصير بهذا الشكل و لو حركنا
+
+149
+00:12:51,580 --> 00:12:54,860
+زوج الألكترونات تعملنا resonance هلاحظ أنه أنا
+
+150
+00:12:54,860 --> 00:12:59,720
+بصير عند الكاربون موجبة full positive charge الآن
+
+151
+00:12:59,720 --> 00:13:03,880
+قبل شوية لما رسمنا احنا كنا نقول هنا إيش شحنة إيش
+
+152
+00:13:03,880 --> 00:13:11,060
+مالها partial charge ال acidلما اجى اضاف ال H plus
+
+153
+00:13:11,060 --> 00:13:16,060
+هنا خلى هذا ال carbon موجب كامل الان ال
+
+154
+00:13:16,060 --> 00:13:22,200
+nucleophile انه افضل له اهاجم على موجب جزء ولا على
+
+155
+00:13:22,200 --> 00:13:26,900
+موجب كامل اهاجم على موجب كامل التجادب ايش بيكون
+
+156
+00:13:26,900 --> 00:13:31,320
+اقوى والتفاعل اسرع هاي بالظبط اللي بيعملوا ال acid
+
+157
+00:13:31,320 --> 00:13:37,720
+الان الناتج النهائي مافيش فيه خلافالناتج النهائي
+
+158
+00:13:37,720 --> 00:13:42,280
+هو نفس الناتج لكن دائما لما بتقرأوا التفاعل
+
+159
+00:13:42,280 --> 00:13:45,840
+هتلاحظوا انه على السهم في عندكم ايش اتش بلس اتش
+
+160
+00:13:45,840 --> 00:13:50,520
+بلس هذه الاتش بلس عبارة عن catalyst بتسرع ايش
+
+161
+00:13:50,520 --> 00:13:57,040
+التفاعل بالطريقة اللي حكيناها الان لو بدأنا ناخد
+
+162
+00:13:57,040 --> 00:14:01,220
+امثلة هاي هذه ال carbon في ال aldehyde موجبة اجت
+
+163
+00:14:01,220 --> 00:14:07,400
+الميه تهاجمأول الـ Eucalyptus ناخد الميّه الـ C
+
+164
+00:14:07,400 --> 00:14:13,760
+double bond O شو بتصير؟ OH نحطها بالأخضر و الميّه
+
+165
+00:14:13,760 --> 00:14:16,280
+هتضيف
+
+166
+00:14:17,080 --> 00:14:23,100
+OH في النهاية واضح هاي صار عندنا استيظة بال bond O
+
+167
+00:14:23,100 --> 00:14:27,960
+صارت OH والمية كان يوكليوفال بتضيف OH الان هنا
+
+168
+00:14:27,960 --> 00:14:34,580
+اتكون عندى مركب على نفس ذرة الكربون تبعته كام OH؟
+
+169
+00:14:34,580 --> 00:14:40,480
+تلتين هذه المركبات اللى على نفس ذرة الكربون فيها
+
+170
+00:14:40,480 --> 00:14:47,840
+تلتين OH بنعطيها اسم hydratesواضح فال hydrate لو
+
+171
+00:14:47,840 --> 00:14:52,800
+قلتلكوا ارسمولي شكل عام لل hydrate معنى ذلك تحطوا
+
+172
+00:14:52,800 --> 00:14:59,420
+carbon على نفس ال carbon تنتين O H's يمكن انتوا
+
+173
+00:14:59,420 --> 00:15:05,340
+سابقا مر عليكم انه يكون عندى في المركب تنتين O H's
+
+174
+00:15:05,340 --> 00:15:12,440
+على ذرات متجاورة زي هيك هذا المركب لما انا كنت
+
+175
+00:15:12,440 --> 00:15:20,400
+اسميهماذا كنت أسميه؟ داي أول داي أول و لأنه
+
+176
+00:15:20,400 --> 00:15:29,620
+كربونتين اثان داي أولواضح إيثان دايول على نمرة
+
+177
+00:15:29,620 --> 00:15:32,360
+واحد وعن نمرة اتنين ممكن تكتبوا one two إيثان
+
+178
+00:15:32,360 --> 00:15:37,980
+دايول تمام لكن لما يكونوا مجموعتين ال OH على نفس
+
+179
+00:15:37,980 --> 00:15:41,860
+ال carbon بنسمي عائلة جديدة هذه العائلة إيش
+
+180
+00:15:41,860 --> 00:15:47,620
+بنسميها hydrate الان المركب نفسه بنسميه نسبة ال
+
+181
+00:15:47,620 --> 00:15:51,140
+aldehyde الأصلي يعني هذا ال aldehyde الأصلي الآن
+
+182
+00:15:51,140 --> 00:15:55,620
+formaldehydeبتذكروا لما قلنا ال formaldehyde غاز
+
+183
+00:15:55,620 --> 00:16:00,400
+ملدوبه في الميه عملية اذابته في الميه هي ان الميه
+
+184
+00:16:00,400 --> 00:16:04,880
+تتفاعل عليه تعمل هان OH و تخلص سيضا من البند OH
+
+185
+00:16:04,880 --> 00:16:11,560
+هذا ال formaldehyde هيدريت طب لو كان acetaldehyde
+
+186
+00:16:11,560 --> 00:16:16,700
+واحدة من دول ال حزب ده تصير CH3 و هكذا الان لاحظوا
+
+187
+00:16:16,700 --> 00:16:22,380
+معي ان ال hydrate تفاعل تكوينه متفاعل ايش
+
+188
+00:16:23,760 --> 00:16:28,200
+Equilibrium reaction يعني لا يتم بشكل كامل بيكون
+
+189
+00:16:28,200 --> 00:16:34,020
+موجود ال الديهيد مع الميه مع الهيدرين بنسبة معينة
+
+190
+00:16:34,020 --> 00:16:40,200
+الان في حالة ال formaldehyde بيصل لإن هذا يتفاعل
+
+191
+00:16:40,200 --> 00:16:45,550
+بنسبة 37% عشان ايه بيصير لكم الفورمالينهو نفس الـ
+
+192
+00:16:45,550 --> 00:16:48,910
+Formal Dehydrate الـ Formalin اللي أخدنا بنستعمله
+
+193
+00:16:48,910 --> 00:16:53,390
+لحفظ الأنسجة وغيرها هو نفسه ال Formal Dehydrate
+
+194
+00:16:53,390 --> 00:16:56,730
+اللي هو ال Formal Dehydrate اتدوب في الميه عمل هذا
+
+195
+00:16:56,730 --> 00:17:01,790
+الشكل ال Formalin واضح الفكرة؟ وهذا التفاعل زي ما
+
+196
+00:17:01,790 --> 00:17:07,950
+قلنا عنه تفاعل عكسي الآن هل يترا في كل ال ال
+
+197
+00:17:07,950 --> 00:17:12,300
+Dehydrates و ال Ketones ممكن يتكون هيدريتز؟من
+
+198
+00:17:12,300 --> 00:17:17,260
+ناحية نظرية بالورقة والقلم اه يعني انا بقدر
+
+199
+00:17:17,260 --> 00:17:21,260
+اقولكوا اي aldehyde في الدنيا ارسموله hydrate
+
+200
+00:17:21,260 --> 00:17:26,620
+الاصل انكم تعرفوا تعملوا hydrate له مثلا لو اجاكم
+
+201
+00:17:26,620 --> 00:17:32,020
+في الامتحان ارسمولنا benz aldehyde hydrate المنطلق
+
+202
+00:17:32,020 --> 00:17:38,630
+تبعكم لازم تكونوا عارفين ال benz aldehydeهي ال
+
+203
+00:17:38,630 --> 00:17:44,210
+benz aldehyde C double bond O H الان احنا اتفقنا
+
+204
+00:17:44,210 --> 00:17:49,230
+لما بدى يعمل hydrate هدول المجمعتين مافيش فيهم
+
+205
+00:17:49,230 --> 00:17:56,450
+تغيير طب ها شو بدى يصير ال C double bond O بتصير O
+
+206
+00:17:56,450 --> 00:18:05,030
+H والمية بتضيف O H هذا بتصير benz aldehyde hydrate
+
+207
+00:18:05,890 --> 00:18:11,750
+و هكذا يعني بنفس هذه الطريقة ممكن نرسم لأي ألديهيد
+
+208
+00:18:11,750 --> 00:18:15,850
+أو كيتون هيدريت لو قولنا أسيتون هيدريت أسيتالديهيد
+
+209
+00:18:15,850 --> 00:18:21,210
+هيدريت لكن الحقيقة معظم الهيدريت بشكل عام they are
+
+210
+00:18:21,210 --> 00:18:26,930
+unstable يعني في حالة الإتزان اللي بيوجد بشكل أكبر
+
+211
+00:18:26,930 --> 00:18:33,280
+كتير جدا هو الألديهيدو لذلك هذا التفاعل بيصير نوعا
+
+212
+00:18:33,280 --> 00:18:37,200
+ما تفاعل نظري مش تفاعل عملي يعني بيكون هذا ال
+
+213
+00:18:37,200 --> 00:18:42,160
+الديهيد او ال ketone موجود بالنسبة 99.9% و هذا
+
+214
+00:18:42,160 --> 00:18:46,780
+موجود بالنسبة قليلة جدا و لذلك معظم ال الديهيد و
+
+215
+00:18:46,780 --> 00:18:50,820
+ال ketones بيكون ال position of equilibrium اتجاه
+
+216
+00:18:50,820 --> 00:18:54,580
+الاتزان فيها هل هو باتجاه ال hydrate و لا باتجاه
+
+217
+00:18:54,580 --> 00:18:56,040
+ال الديهيد او ال ketone
+
+218
+00:18:58,860 --> 00:19:04,840
+واضح الفكرة؟ لكن نظريا كل شيء له hydrate الان مثلا
+
+219
+00:19:04,840 --> 00:19:10,420
+هذا المركب تطلع عليه carbon حملة تين و H إذا هذا
+
+220
+00:19:10,420 --> 00:19:15,120
+hydrate ولا لأ؟ Hydrate طب الآن لو قلت لواحدة
+
+221
+00:19:15,120 --> 00:19:22,520
+فيكوا هذا ال hydrate من أي الديهيد جاي كيف
+
+222
+00:19:22,520 --> 00:19:28,900
+بدى تعمل؟ بدى تخلي الرابطتين اللي موجودات ال Hو ال
+
+223
+00:19:28,900 --> 00:19:34,800
+C اللي حاملة تلاتة كلور يعني CCLCLCL و تحط هنا
+
+224
+00:19:34,800 --> 00:19:41,420
+double bond O هذا مركب موازل ال acetaldehyde لكن
+
+225
+00:19:41,420 --> 00:19:46,160
+ابدلت تلت ذرات الهيدروجين فيه بكلور فبصير اسمه ايش
+
+226
+00:19:46,160 --> 00:19:53,340
+اكلورال اكلورال لما اعمل من ال اكلورال هيدريت
+
+227
+00:19:53,340 --> 00:20:01,450
+باضافة الميهبيصير ايش اسمه اكلورال هايدريت فانا ال
+
+228
+00:20:01,450 --> 00:20:05,770
+الديهايدي اللي عندي اكلورال لما اعمله اضافة ميه
+
+229
+00:20:05,770 --> 00:20:10,950
+بيصير اكلورال هايدريت واضح لما اعمله اضافة ميه
+
+230
+00:20:10,950 --> 00:20:15,530
+بيصير اكلورال هايدريت هذا ال اكلورال هايدريت مادة
+
+231
+00:20:15,530 --> 00:20:19,650
+تستعمل في التخدير و عادة في التخدير في الطب
+
+232
+00:20:19,650 --> 00:20:24,090
+البيطري يعني لما يعملوا عمليات جراحية للحيوانات
+
+233
+00:20:24,090 --> 00:20:28,860
+الكبيرة الضخمةبيعطوها chloral hydrate كمخدر فيلو
+
+234
+00:20:28,860 --> 00:20:36,660
+ما إلى ذلك واضح؟ فهذا بالنسبة لل hydrate الأن كتير
+
+235
+00:20:36,660 --> 00:20:40,160
+مرات بنيجي بنقول للطالب في الامتحان النهار or some
+
+236
+00:20:40,160 --> 00:20:44,420
+general structure of hydrate بشكل عام شو بده يحط
+
+237
+00:20:44,420 --> 00:20:53,080
+الليه؟ carbon حاملة تنتلؤ أدشز واضح؟طيب لو اتينا ل
+
+238
+00:20:53,080 --> 00:20:59,680
+ال alcohol كيف بتتفاعل برضه إضافة الآن على طول
+
+239
+00:20:59,680 --> 00:21:05,140
+السيباب البندقوس شو هتصير OH و ال nucleophile اللي
+
+240
+00:21:05,140 --> 00:21:12,520
+هيهاجم OR لاحظوا هنا صار عندى ذرة carbon بتحمل مش
+
+241
+00:21:12,520 --> 00:21:21,470
+تنتين OHOH و OR يعني كأن هذا المركب هو عبارة عن
+
+242
+00:21:21,470 --> 00:21:28,230
+كحول و إيثر بنفس الوقت كاربون بتحمل OH هذا ألكوهول
+
+243
+00:21:28,960 --> 00:21:36,180
+و carbon OR هذا ether واضح فهذا المركب كأنه كحول و
+
+244
+00:21:36,180 --> 00:21:40,680
+ether و هذه العملية إضافة ليش إضافة هذه العملية
+
+245
+00:21:40,680 --> 00:21:44,200
+لأن ال double bond صارت single bond هذه الإضافة
+
+246
+00:21:44,200 --> 00:21:47,900
+ببساطة ال double bond single bond إضافة خلصنا الآن
+
+247
+00:21:47,900 --> 00:21:53,240
+هذا اللي فيه ال carbon بتحمل OH و OR بنسميه
+
+248
+00:21:53,240 --> 00:22:00,690
+hemiacetalيعني إيش؟ نص أسيتال مش أسيتال كامل، الآن
+
+249
+00:22:00,690 --> 00:22:06,190
+لما أي شغل نقول هذا نص أسيتال حيصير التفكير عندكم
+
+250
+00:22:06,190 --> 00:22:12,030
+طب هو إيش الأسيتال؟ الكامل، إذا في بالدنيا نص
+
+251
+00:22:12,030 --> 00:22:17,430
+أسيتال، إذا أكيد في الدنيا في إيش؟ أسيتال كامل،
+
+252
+00:22:17,430 --> 00:22:21,750
+hemacetal نص أسيتال، طب وإيش الأسيتال الكامل؟
+
+253
+00:22:24,180 --> 00:22:32,080
+إتنين إيثر لو هذا المركب نفسه الـ hemacetal فعلناه
+
+254
+00:22:32,080 --> 00:22:37,480
+مع زيادة من الكحول فعلناه مع زيادة من الكحول الآن
+
+255
+00:22:37,480 --> 00:22:41,960
+مرة تانية بيجي الكحول في هذه الحالة بيعمل تفاعل
+
+256
+00:22:41,960 --> 00:22:46,800
+تاني بيهاجم على الكربون الموجبة وبيطرد الـ OH الآن
+
+257
+00:22:46,800 --> 00:22:51,180
+هذا التفاعل مجموعة داخلة مجموعة طالعة شو بنسمي
+
+258
+00:22:51,180 --> 00:22:51,920
+احنا substitution
+
+259
+00:22:55,450 --> 00:22:58,630
+substitution هذا التفاعل double bond صارت single
+
+260
+00:22:58,630 --> 00:23:04,590
+bond شو كنا مسمينه addition الان بدلنا ال OH ب OR
+
+261
+00:23:04,590 --> 00:23:11,090
+شو صار موجود عندك على الكربون تنتين
+
+262
+00:23:11,090 --> 00:23:18,370
+OR داي إيثر هذا الأسيتال الكامل واضح هذا هو
+
+263
+00:23:18,370 --> 00:23:25,730
+الأسيتال الكامل اللي هو كربون بتحملTentenor و
+
+264
+00:23:25,730 --> 00:23:31,770
+التفاعل لتكوين الاسيتال يتم من خلال الهيمياسيتال
+
+265
+00:23:31,770 --> 00:23:36,870
+مع مزيد من الكحول فالتفاعل في هذه الحالة
+
+266
+00:23:36,870 --> 00:23:41,850
+substitution لاحظوا انا الان كم عائلة جديدة اتعرفت
+
+267
+00:23:41,850 --> 00:23:47,490
+عليها خدوهم بالتدريج Carbon Carbon Carbon Carbon
+
+268
+00:23:47,490 --> 00:23:48,990
+حاملة Tentenor
+
+269
+00:23:51,050 --> 00:23:57,350
+أه carbon حاملة OH و OR همي أسيتال carbon حاملة OR
+
+270
+00:23:57,350 --> 00:24:06,530
+و OR أسيتال شفتم كيف بالمقارنة hydrate أسيتال وهذا
+
+271
+00:24:06,530 --> 00:24:12,720
+اللي بين بينهيمي أسيتال هيدريت وهذا أسيتال وهذا
+
+272
+00:24:12,720 --> 00:24:18,320
+هيمي أسيتال الآن لو أجينا نسألكم الهيدريت كيف
+
+273
+00:24:18,320 --> 00:24:25,440
+بيتكون من إضافة الماء على ال الديهيد أو الكيتون
+
+274
+00:24:25,440 --> 00:24:29,300
+لحظوا الكلمات اللي باستعملها لما نفجر نسأل هيدريت
+
+275
+00:24:29,300 --> 00:24:30,260
+هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت
+
+276
+00:24:30,260 --> 00:24:31,960
+هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت
+
+277
+00:24:31,960 --> 00:24:32,140
+هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت
+
+278
+00:24:32,140 --> 00:24:32,140
+هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت هيدريت
+
+279
+00:24:32,140 --> 00:24:34,240
+هيدريت هيدريت هيدريت هيدريت هيدby addition
+
+280
+00:24:34,240 --> 00:24:40,000
+reaction الـ hemacetal is formed also by addition
+
+281
+00:24:40,000 --> 00:24:43,760
+reaction على ال الديهيد والكيتون ال acetal
+
+282
+00:24:43,760 --> 00:24:51,340
+substitution reaction على ال hemacetal واضح ال
+
+283
+00:24:51,340 --> 00:24:55,480
+acetal هو عبارة عن عملية إبدال ال OH اللي موجودة
+
+284
+00:24:55,480 --> 00:25:00,120
+في ال hemacetal واضح هذه التفاعلات والعائلات
+
+285
+00:25:00,120 --> 00:25:01,740
+الجديدة والمسميات
+
+286
+00:25:07,510 --> 00:25:14,790
+الان هذا الحقيقة تفاعل الاسيتال والهيمياسيتال
+
+287
+00:25:14,790 --> 00:25:22,070
+تفاعل مهم جدا ممكن ايضا طالما المكونات تبعته كحول
+
+288
+00:25:22,070 --> 00:25:27,670
+بيهاجم على ايش الديهايد او كيتون الان لو انا
+
+289
+00:25:27,670 --> 00:25:31,150
+اتخيلت هي الديهايد او كيتون كحول هاجم عليه شو
+
+290
+00:25:31,150 --> 00:25:36,710
+الناتج؟Hemiacetal طيب السؤال لو ال الديهايد و ال
+
+291
+00:25:36,710 --> 00:25:40,930
+alcohol بنفس الجزئ يعني تخيلنا هيك جزئ سلسلة على
+
+292
+00:25:40,930 --> 00:25:46,330
+أحد أطرافها الديهايد و على الطرف التاني OH و إجت
+
+293
+00:25:46,330 --> 00:25:52,170
+فاعل هذه هاجمتها و السيطة بالبندق شو صارت OH هذا
+
+294
+00:25:52,170 --> 00:25:56,370
+التفاعل بنسميه Intermolecular ولا Intramolecular
+
+295
+00:25:57,570 --> 00:26:00,950
+Intramolecular شو يعني Intramolecular تفاعل بين
+
+296
+00:26:00,950 --> 00:26:06,430
+جزئين مفصولين تماما هذا جزء و هذا جزء جاء الجزئين
+
+297
+00:26:06,430 --> 00:26:10,150
+المفصولين تماما يتفاعلوا مع بعض هذا Intermolecular
+
+298
+00:26:10,150 --> 00:26:15,510
+بين جزئين مفصولين الان لو هذا الجزء و هذا الجزء
+
+299
+00:26:15,510 --> 00:26:21,430
+ممسكين بنفس السلسلة زي هذا المثال لاحظوا هذه سلسلة
+
+300
+00:26:21,430 --> 00:26:28,570
+واضح على أحد أطرافهاالديهايد وعلى الطرف الثاني
+
+301
+00:26:28,570 --> 00:26:32,790
+كحول فالجزئين اللي بدهم يتفاعلوا موجودين بنفس
+
+302
+00:26:32,790 --> 00:26:36,830
+المركب مش بمركبين مختلفين في هذه الحالة إذا
+
+303
+00:26:36,830 --> 00:26:40,730
+الجزئين اللي بتفاعلوا بنفس المركب على طول التفاعل
+
+304
+00:26:40,730 --> 00:26:47,380
+إيش أنا بأوصفه Intramolecular reactionفالـ
+
+305
+00:26:47,380 --> 00:26:51,120
+Intramolecular معناه ذلك أن الجزئين اللي بتفعلوا
+
+306
+00:26:51,120 --> 00:26:55,860
+بنفس الجزئ لكن الـ Intermolecular لأ جزئين مفصلين
+
+307
+00:26:55,860 --> 00:27:00,780
+و بيجوا يتفعلوا مع بعض واضح؟ هذا الأمر موجود كتير
+
+308
+00:27:00,780 --> 00:27:05,620
+الآن خلّيت الكحول و الالدهايد بنفس الجزئ التفاعل
+
+309
+00:27:05,620 --> 00:27:10,540
+أكيد إضافة الكحول بده يهاجم هنا و هاد السيطة بالـ
+
+310
+00:27:10,540 --> 00:27:16,270
+Bond O شو بده تصيرOH احنا قلنا في كل الأحوال دائما
+
+311
+00:27:16,270 --> 00:27:20,310
+ال C double bond O بتصير OH يمكن في كل الأمثلة
+
+312
+00:27:20,310 --> 00:27:25,690
+السابقة رسمناها بالأخضر و ال nucleophile هاجم بهذا
+
+313
+00:27:25,690 --> 00:27:32,110
+الشكل الآن هذا المركب اللي متكون عنده أيضا
+
+314
+00:27:32,110 --> 00:27:37,370
+hemacetal ولا لأ؟ أكيد لأن high carbon حاملة OH
+
+315
+00:27:41,220 --> 00:27:45,560
+هذا Hemacetal لكن التفاعل بهذه الحالة
+
+316
+00:27:45,560 --> 00:27:52,000
+Intramolecular reaction الان هذا التفاعل جزء من
+
+317
+00:27:52,000 --> 00:27:58,390
+أهميته انه في ال biochemistryإذا عندكم فكرة خفيفة
+
+318
+00:27:58,390 --> 00:28:03,190
+أو هيمر عليكم لما بناخد السكريات ال sugars احنا
+
+319
+00:28:03,190 --> 00:28:08,150
+قولنا ال sugars they are polyhydroxy aldehydes او
+
+320
+00:28:08,150 --> 00:28:12,890
+كيتون هى عبارة عن الديهيد او كيتون مع مجموعات
+
+321
+00:28:12,890 --> 00:28:17,510
+اوقاتش كبيرة الديهيد لحاله بيعملش sugar ومجموعات
+
+322
+00:28:17,510 --> 00:28:21,490
+اوقاتش كتيرة لحالها بتعملش ايش sugar فال sugar
+
+323
+00:28:21,490 --> 00:28:26,130
+عبارة عن ايشموجود فيه يا الديهايد يا كيتون
+
+324
+00:28:26,130 --> 00:28:31,290
+ومجموعات OH's الآن طالما وجد فيه على جهة معينة
+
+325
+00:28:31,290 --> 00:28:34,950
+الديهايد او كيتون هي C double bond او نتخيل هيك وع
+
+326
+00:28:34,950 --> 00:28:40,980
+الجهة التانيةأو أتشز ممكن هذه ال أو أتشز تسكر على
+
+327
+00:28:40,980 --> 00:28:45,600
+ال الديهايد أو ال كيتون أكيد بتعمل في هذه الحالة
+
+328
+00:28:45,600 --> 00:28:49,520
+hemeacetal بس لما تسكر بدل ما ال sugar كان عامل
+
+329
+00:28:49,520 --> 00:28:54,480
+سلسلة بهذا الشكل ال chain بيصير إيش in the cyclic
+
+330
+00:28:54,480 --> 00:28:58,440
+form كل كمار عليكوا أن السكر بيكون في ال chain
+
+331
+00:28:58,440 --> 00:29:06,430
+formكسلسلة و بيكون بـ Cyclic Form كحلقة الآن عملية
+
+332
+00:29:06,430 --> 00:29:12,090
+إغلاق السكر هي عملية تفاعل Hemacetal Formation
+
+333
+00:29:12,090 --> 00:29:17,890
+Hemacetal Formation هاي السكر اللي مسكر الجلوكوز
+
+334
+00:29:17,890 --> 00:29:22,650
+هذا منظر الجلوكوز اللي مسكر لاحظوا هذه ال carbon
+
+335
+00:29:22,650 --> 00:29:32,570
+تحديدا اللي هنا هي فيها OHو OR اللى هو alcohol و
+
+336
+00:29:32,570 --> 00:29:36,910
+ether طب لو قولنا لأى حد اذكرنا كيف هذه كانت قبل
+
+337
+00:29:36,910 --> 00:29:43,250
+التفاعل قبل ما يسكر كانت هذه C double bond O وكانت
+
+338
+00:29:43,250 --> 00:29:52,240
+هذه OH وماكنش فيه رابطةكانت هذه C double bond O L
+
+339
+00:29:52,240 --> 00:29:57,780
+D I و هذه O H فهذه ال O H سكرت هنا و C double bond
+
+340
+00:29:57,780 --> 00:30:05,240
+O صارتOH بهذا الشكل فلو اجينا سألناكوا سؤال
+
+341
+00:30:05,240 --> 00:30:10,260
+وقلنالكم cyclic glucose انتبهوا معايا هاي ال
+
+342
+00:30:10,260 --> 00:30:14,480
+glucose اللي مسكرة تكونوا فاهمين العائلات كويسة
+
+343
+00:30:14,480 --> 00:30:20,420
+cyclic glucose is a hydrate يعني في تنتين OH على
+
+344
+00:30:20,420 --> 00:30:21,140
+الكربون
+
+345
+00:30:25,890 --> 00:30:30,950
+cyclic glucose is a hydrate no cyclic glucose is
+
+346
+00:30:30,950 --> 00:30:38,450
+an acetal في تنتين OR برضه false cyclic glucose is
+
+347
+00:30:38,450 --> 00:30:48,340
+a hemacetal في OH و OR واضحة الفكرةالان ممكن نسأل
+
+348
+00:30:48,340 --> 00:30:54,180
+السؤال بطريقة تانية Cyclic glucose is formed by a
+
+349
+00:30:54,180 --> 00:30:55,960
+substitution reaction
+
+350
+00:30:58,930 --> 00:31:03,610
+by an addition reaction شوف كيف اللي بيفهم شغلة
+
+351
+00:31:03,610 --> 00:31:07,770
+بيحس انه ممكن نسأل عن الشغلة بقالف طريق أنا مش
+
+352
+00:31:07,770 --> 00:31:10,610
+الفكرة ان اخوفكم من الأسئلة و الانتحانات بقدر ما
+
+353
+00:31:10,610 --> 00:31:16,130
+اني بركز المعلومة عندكم ان هذه فعلا كانت C double
+
+354
+00:31:16,130 --> 00:31:20,430
+bond O و هذه فعلا كانت OH هذا alcohol و هذا
+
+355
+00:31:20,430 --> 00:31:23,750
+aldehyde الآن ال alcohol و ال aldehyde بيتفاعلوا
+
+356
+00:31:23,750 --> 00:31:31,560
+تفاعل ايش اضافة بكونه hemiacetalواضح؟ الآن بعد ما
+
+357
+00:31:31,560 --> 00:31:37,160
+اتكون الـ hemacetal هذا وصار هنا في OR و OH ممكن
+
+358
+00:31:37,160 --> 00:31:44,040
+يصير تفاعل تاني تبدل في ال OH ل OR مع كحول تاني
+
+359
+00:31:44,040 --> 00:31:48,260
+خارجي يعني افترضوا ناس جابوا ميثانول وفعلوا مع هذا
+
+360
+00:31:48,260 --> 00:31:55,530
+شو هيعمل الميثانول؟هيشيل ال OH يخليها OR صار عندكم
+
+361
+00:31:55,530 --> 00:32:01,890
+OR OR أسيتال بس ب substitution reaction تاني واضح
+
+362
+00:32:01,890 --> 00:32:06,350
+انما ال cyclic glucose في نص الطريق هو عبارة عن
+
+363
+00:32:06,350 --> 00:32:11,500
+ايش؟Hemiacetal Cyclic Glucose is Hemiacetal ممكن
+
+364
+00:32:11,500 --> 00:32:15,920
+تحويله ل Acetal بالتفاعل مع الكحول أكيد لأن احنا
+
+365
+00:32:15,920 --> 00:32:20,820
+قلنا التفاعل ع مرحلتين إضافة ثم إبدال أنا لما وصلت
+
+366
+00:32:20,820 --> 00:32:24,900
+ل Hemacetal عملت الإضافة الآن إذا الإنسان بيجيب
+
+367
+00:32:24,900 --> 00:32:30,860
+كحول و حامض و بيسخنه ممكن يعمل إيش الإبدال و يحوله
+
+368
+00:32:30,860 --> 00:32:37,360
+إلى Acetal كاملهنا في عندى على هذه النقطة كمان
+
+369
+00:32:37,360 --> 00:32:46,320
+مثال جميل انه انا جبت ال Acetone كيتون مع Ethylene
+
+370
+00:32:46,320 --> 00:32:51,740
+Glycol او اللى سميناه Ethanediol هذا المركب كام OH
+
+371
+00:32:51,740 --> 00:32:58,200
+فيهTintin يعني كأنه هذا Dialcohol الان لما فعلنا
+
+372
+00:32:58,200 --> 00:33:03,200
+اعطانا هذا المركب المغلق يمكن واحدة تقول طب كيف تم
+
+373
+00:33:03,200 --> 00:33:08,600
+هذا التفاعل؟ بنقول بهدوء ممكن نفهم كيف تم الان
+
+374
+00:33:08,600 --> 00:33:13,540
+نتعامل مع هذا كيتون و مع هذا الكهول كيف الكهول
+
+375
+00:33:13,540 --> 00:33:17,700
+بتفاعل على الكيتون او على الديهايد بال addition
+
+376
+00:33:17,700 --> 00:33:24,310
+هذه بتيجي تضيف هنا و هذه بتصيرOH إذا لو قلنا شو
+
+377
+00:33:24,310 --> 00:33:32,770
+الناتج اللي في هذه الحالة بيصير C OH CH3 CH3 هذا
+
+378
+00:33:32,770 --> 00:33:37,590
+الجزء اللي كان أسيتون والجزء التاني هو عبارة عن O
+
+379
+00:33:37,590 --> 00:33:48,890
+CH2 CH2 OH هاي كحول اتفاعل مع كيتون ال C double
+
+380
+00:33:48,890 --> 00:33:54,500
+bond O صارتOH والكحول اتفاعل هنا الان الكحول نفسه
+
+381
+00:33:54,500 --> 00:34:00,220
+في داخله OH تاني يعني كأن الكحول كحولين في بعض في
+
+382
+00:34:00,220 --> 00:34:04,740
+مجموعتين OH هذا المركب اللي هنا carbon حاملة OH و
+
+383
+00:34:04,740 --> 00:34:10,660
+OR شو عبارة عن ايش Himacetal الان ممكن يعمل كمان
+
+384
+00:34:10,660 --> 00:34:16,680
+تفاعل ان هذه تهاجم هنا و تحل محل هذه ابدال
+
+385
+00:34:17,800 --> 00:34:21,920
+و انت بتطلع عندى هذا المركب لحظة هذا المركب carbon
+
+386
+00:34:21,920 --> 00:34:27,680
+حاملة OR و OR اذا هذا عبارة عن ايش
+
+387
+00:34:30,910 --> 00:34:36,990
+Hemiacetal لاحظوا هنا اعملت التفاعل على مرتين لكن
+
+388
+00:34:36,990 --> 00:34:42,970
+مش من كحولين مفصلين لأ الكحولين موجودين بإيش؟ بنفس
+
+389
+00:34:42,970 --> 00:34:47,330
+الجزء نفس الجزء فيه تن تن و اتش يعني كأنه الجزء زي
+
+390
+00:34:47,330 --> 00:34:53,410
+ما بيقولوا اليوم في الدعايات إيش؟ two in oneطالما
+
+391
+00:34:53,410 --> 00:34:58,470
+في اتنين OH اذا صار عبارة عن كحولين في نفس الجزء
+
+392
+00:34:58,470 --> 00:35:03,710
+طالما مجمعتين OH الكحول OH هذا في OH OH صار كحولين
+
+393
+00:35:03,710 --> 00:35:09,650
+اتفاعل في المرة الأولى بالاضافة و في المرة الثانية
+
+394
+00:35:09,650 --> 00:35:15,380
+بالابدالةشوفنا كيف ادول التفاعلين تموا addition
+
+395
+00:35:15,380 --> 00:35:19,640
+followed by substitution الان هذا المركب اتجه من
+
+396
+00:35:19,640 --> 00:35:23,360
+الاسيتون و من الاثيلين جليكول عشان يسموه اسيتون
+
+397
+00:35:23,360 --> 00:35:28,820
+اثيلين جليكول لاحظوا ايش استعمله اسيتال منطق
+
+398
+00:35:28,820 --> 00:35:32,480
+اسيتال لانه OR و OR اسيتال
+
+399
+00:35:42,600 --> 00:35:48,900
+الان من التفاعلات انه نستعمل نيكليوفايل مجموعة ال
+
+400
+00:35:48,900 --> 00:35:52,680
+CNI و بتذكروا احنا لما أخدنا ال CNI تقولنا بتتفاعل
+
+401
+00:35:52,680 --> 00:35:56,460
+من اي طرف من الكربون ولا من ال نيتروجين من الكربون
+
+402
+00:35:56,460 --> 00:36:01,200
+كل اللي مطلوب انه ال CN تهاجم هنا و الصيدة بال
+
+403
+00:36:01,200 --> 00:36:06,580
+bond O تصير OH الان صار عندى عائلة جديدة على
+
+404
+00:36:06,580 --> 00:36:13,040
+الكربون ايش المجمعتين اللي موجودين CNN و OHو OH
+
+405
+00:36:13,040 --> 00:36:20,700
+لاحظوا C و تلتين OH هيدريت OH و OR هيمي أسيتال OR
+
+406
+00:36:20,700 --> 00:36:27,340
+و OR أسيتال الان OH و CNN بسميها سيانو هيدرين
+
+407
+00:36:27,340 --> 00:36:37,760
+بسميها سيانو هيدرين واضح سيانو هيدرين الان
+
+408
+00:36:39,440 --> 00:36:43,880
+لو عملنا التفاعل مع الاسيتالديهيد هذا المركب شو
+
+409
+00:36:43,880 --> 00:36:51,320
+هسميه اسيتالديهيد سيانوهيدرين لو عملت التفاعل مع
+
+410
+00:36:51,320 --> 00:36:57,100
+الاسيتون هذا المركب ايش هسميه اسيتون هاي جزء
+
+411
+00:36:57,100 --> 00:37:05,520
+الاسيتون مش الاسيتون عبارة عن CH3CCH3 بدون ال
+
+412
+00:37:05,520 --> 00:37:10,950
+oxygen اسيتونCyanohedron لو عملتم مع الـ
+
+413
+00:37:10,950 --> 00:37:16,250
+Cyclohexanone هذي الـ C double bond O إيش هتصير؟
+
+414
+00:37:16,250 --> 00:37:21,650
+OH وهي الـ Cl شو هسميه؟ Cyclohexanone
+
+415
+00:37:21,650 --> 00:37:23,470
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+416
+00:37:23,470 --> 00:37:23,530
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+417
+00:37:23,530 --> 00:37:23,810
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+418
+00:37:23,810 --> 00:37:24,510
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+419
+00:37:24,510 --> 00:37:26,930
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+420
+00:37:26,930 --> 00:37:26,930
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+421
+00:37:26,930 --> 00:37:27,010
+Cyclohexanone Cyclohexanone Cyclohexanone
+
+422
+00:37:27,010 --> 00:37:31,690
+Cyclohexanone
+
+423
+00:37:31,690 --> 00:37:37,790
+Cyclohexanone Cyclohexanone
+
+424
+00:37:40,220 --> 00:37:47,620
+الدهايد بنزالدهايد سيانو هيدرل يعني لو قلنا لأي
+
+425
+00:37:47,620 --> 00:37:53,440
+واحدة أرسمينا بنزالدهايد سيانو هيدرل في الامتحان
+
+426
+00:37:53,440 --> 00:37:58,360
+بدا تيجي تفكر تتخيل بسهولة ماتاخدش وقت منكوا
+
+427
+00:37:58,360 --> 00:38:05,530
+ببساطة هاي ال بنزالدهايد صح ولا لألازم في الأصل
+
+428
+00:38:05,530 --> 00:38:09,390
+تكون عارفة الـ Benzaldehyde مجرد ما نقولها سيانو
+
+429
+00:38:09,390 --> 00:38:17,490
+هيدرين الـ C بابل بوند O OH OHIJNQCN مش عملية صعبة
+
+430
+00:38:17,490 --> 00:38:23,090
+Benzaldehyde cyanohydrin واضح الفكرة؟ لاحظوا أنا
+
+431
+00:38:23,090 --> 00:38:27,650
+كاتب له common name نفس
+
+432
+00:38:27,650 --> 00:38:30,830
+الـ Benzaldehyde cyanohydrin له common name
+
+433
+00:38:30,830 --> 00:38:33,330
+Manbilonitride
+
+434
+00:38:34,290 --> 00:38:42,750
+mandilo mandel بالالماني يعني لوز انتوا بتذاكرين
+
+435
+00:38:42,750 --> 00:38:46,750
+قبل شوية لما أخدنا ال benzaldehyde قولنا oil of
+
+436
+00:38:46,750 --> 00:38:54,170
+almond اللوز بالانجليزي بالالماني mandel ومن هنا
+
+437
+00:38:54,170 --> 00:38:58,950
+استعمل mandilo nitral mandel من اللوز يعني كتير من
+
+438
+00:38:58,950 --> 00:39:04,150
+ال common name علاقة في إيشفي أصل المركب من أي
+
+439
+00:39:04,150 --> 00:39:08,130
+منطقة نباتية اشتهر ان هذا المركب انفصل
+
+440
+00:39:08,130 --> 00:39:12,990
+فالمنديلونيترال هو ال benzaldehyde cyanohydrin
+
+441
+00:39:12,990 --> 00:39:14,370
+واضح الفكرة؟
+
+442
+00:39:20,340 --> 00:39:24,120
+اتخيلوا عاد كيف الطالب لما بيبعد عن الكلام احنا
+
+443
+00:39:24,120 --> 00:39:28,320
+مرة جيبناله سؤال في الامتحان ارسم العائلة العامة و
+
+444
+00:39:28,320 --> 00:39:33,940
+كتبناله Hydrate, Hemacetal, Acetal وCyanohydrin
+
+445
+00:39:33,940 --> 00:39:37,420
+انا بدي احط هدوله و هنا يعمل شرط اما يكتبليش اشي
+
+446
+00:39:37,420 --> 00:39:42,240
+يعني في مجبوعتين صعبة ولا سهلة؟ سهلة جدا .. سهلة
+
+447
+00:39:42,240 --> 00:39:45,020
+جدا .. الآن
+
+448
+00:39:46,660 --> 00:39:53,640
+بنجي لنيكليوفايل جديد هذا النيكليوفايل الجديد هو H
+
+449
+00:39:53,640 --> 00:40:01,080
+- متذكرين انتوا انه احنا لما حكينا عن الهيدروجين،
+
+450
+00:40:01,080 --> 00:40:07,580
+قولنا الهيدروجين بيدا تمر علينا بكم شكل؟ تلت أشكال
+
+451
+00:40:07,580 --> 00:40:10,700
+H plus وH
+
+452
+00:40:14,320 --> 00:40:19,580
+و أعطناهم أسماء الـ H بلس شو قلنا عنها البروتون
+
+453
+00:40:19,580 --> 00:40:25,480
+اللي بيفقد الحامض و الـ H هيدروجين أتم الـ H minus
+
+454
+00:40:25,480 --> 00:40:30,880
+هيدرايد أنيون الان مين في هدولة التلاتة
+
+455
+00:40:30,880 --> 00:40:38,080
+نيوكليوفاين الهيدرايد أنيون طيب انتهت الكلام طالما
+
+456
+00:40:38,080 --> 00:40:44,480
+الهيدرايد أنيوناليوكليوفايل لو أخدت الديهيد زي هذا
+
+457
+00:40:44,480 --> 00:40:48,040
+خلّيني أقول ال Acetaldehyde وهي ال H وحملة ال
+
+458
+00:40:48,040 --> 00:40:52,860
+minus وقلتلكوا أكمل المعادلة ال hydride بدو يتفعل
+
+459
+00:40:52,860 --> 00:40:59,320
+مع هذا شو هيعمل ال C double bond O هتصير O H هي
+
+460
+00:40:59,320 --> 00:41:03,480
+باللون الأخضر واليوكليوفايل بهذه الحالة هو عبارة
+
+461
+00:41:03,480 --> 00:41:12,270
+عن إيش ال Hما العائلة الجديدة اللتي تكونت هنا؟كحول
+
+462
+00:41:12,270 --> 00:41:17,650
+هذه عملية الاختزال الار بيصير السؤال هو بالدنيا
+
+463
+00:41:17,650 --> 00:41:23,870
+بينباع H- لحاله؟ لأ بينباع على شكل المراكبات
+
+464
+00:41:23,870 --> 00:41:29,970
+المراكبات اللي بتكون مصدر للhydride anion موجود
+
+465
+00:41:29,970 --> 00:41:33,930
+منها وتستعمل كعوامل مختزلة لحظوا هذه العملية
+
+466
+00:41:33,930 --> 00:41:38,410
+اختزال لأن C double bond O صارت OH واحدة نقص في
+
+467
+00:41:38,410 --> 00:41:44,610
+محتوىالأكسوجين وزيادة في محتوى الهيدروجين أنا زيدت
+
+468
+00:41:44,610 --> 00:41:49,430
+هنا H وزيدت هنا H هايهم تنتين هذا الاختزال بعينه
+
+469
+00:41:49,430 --> 00:41:54,690
+مظبوط ولا لأ الآن العوامل المختزلة عادة بتكون
+
+470
+00:41:54,690 --> 00:41:58,410
+هيدرايد أو ممكن الإنسان يعملها بإضافة الهيدروجين
+
+471
+00:41:58,410 --> 00:42:02,120
+هنا إحنا إيش اللي بنستعمله الهيدرايدلحظوا من
+
+472
+00:42:02,120 --> 00:42:06,320
+الهيدرايتز اللي مشهورة جدا هذا المركّب الليثيام
+
+473
+00:42:06,320 --> 00:42:12,340
+والألمنيوم اللي متصل ب 4H- لحظوا الألمنيوم بوضعه
+
+474
+00:42:12,340 --> 00:42:18,880
+الطبيعي بيكون ايش تلاتة موجة حطوا عليه 4H- كل ال
+
+475
+00:42:18,880 --> 00:42:23,920
+ايون شو هيصفاه minus عشان يطلع الجزية متعادلة
+
+476
+00:42:23,920 --> 00:42:31,420
+بحطله lithium plusهذا بيصير Lithium Tetrahydride
+
+477
+00:42:31,420 --> 00:42:39,180
+Aluminate طبعا الات هي نهاية إيش؟ الايون السالب مش
+
+478
+00:42:39,180 --> 00:42:43,440
+أخدنا احنا الايونات السالبة سولفات، كربونات،
+
+479
+00:42:43,440 --> 00:42:50,230
+نيترات، أسيتات، الآن هنا قولنا إيش؟ Aluminateكل
+
+480
+00:42:50,230 --> 00:42:57,290
+عمره بنقول سلفيت SO4 minus minus نيتريت NO3 minus
+
+481
+00:42:57,290 --> 00:43:03,170
+فال eight نهاية ال ايش ال ايون السالب الان هذا
+
+482
+00:43:03,170 --> 00:43:07,050
+الجزء متعادل لان عندي ليثيام plus والالمنيوم تلاتة
+
+483
+00:43:07,050 --> 00:43:12,770
+plus هاي أربعة موجب وال H أربعة minus صف الجزء كله
+
+484
+00:43:12,770 --> 00:43:18,190
+ايش ليثيام تترا هيدرايدو ألمينيت أو هذا من البورون
+
+485
+00:43:18,950 --> 00:43:26,130
+Sodium Tetrahydride من البرون بوريت مش من البروم
+
+486
+00:43:26,130 --> 00:43:31,350
+البرون لما تمشوا في أول الجدول الدوري العنصر
+
+487
+00:43:31,350 --> 00:43:35,890
+الخامس يعني تطلعوا على عناصر الجدول الدوري H بعدين
+
+488
+00:43:35,890 --> 00:43:41,590
+helium بعدين lithium بعدين beryllium بعدين boron
+
+489
+00:43:41,590 --> 00:43:48,520
+واضح؟ اه ال boronSodium tetrahydride borate الان
+
+490
+00:43:48,520 --> 00:43:52,160
+هذول الحقيقة بياخدوا كمان اسماء تانية لو سمعتهم
+
+491
+00:43:52,160 --> 00:43:55,700
+بأي اسمين هذول من أشهر العوامل المختز ل ال
+
+492
+00:43:55,700 --> 00:44:02,140
+hydrides هم ببساطة مصدر ل إيش ل H minus يعني احنا
+
+493
+00:44:02,140 --> 00:44:06,840
+بنفهمه مصدر ل H minus هذا بيسموه ال lithium
+
+494
+00:44:06,840 --> 00:44:13,460
+tetrahydride aluminate بيسموه lithium aluminum
+
+495
+00:44:13,460 --> 00:44:20,740
+hydrideالومينوم هايدرايد يعني نفسه ممكن تلاقوه تحت
+
+496
+00:44:20,740 --> 00:44:24,840
+اسم ليثيام ألومينوم هايدرايد أو ليثيام تيترا
+
+497
+00:44:24,840 --> 00:44:29,260
+هايدرايد و ألومينيت وهذا بيسموه صوديوم بورو
+
+498
+00:44:29,260 --> 00:44:35,230
+هايدرايد مش بورونBorohydride فإذا سمعتوا Sodium
+
+499
+00:44:35,230 --> 00:44:38,770
+Borohydride أو Sodium Tetrahydride و Borate نفس
+
+500
+00:44:38,770 --> 00:44:43,330
+الاسم Lithium Tetrahydride و Aluminate أو Lithium
+
+501
+00:44:43,330 --> 00:44:47,690
+Aluminum Hydride نفس الاسم و مرات كتير حتى الاسم
+
+502
+00:44:47,690 --> 00:44:52,530
+هذا Sodium Borohydride و عادة مش هيكونوا عاملينه
+
+503
+00:44:52,530 --> 00:44:57,310
+زيك هتلاعظوا على السهم مكتوب عندكم NABH4
+
+504
+00:44:58,940 --> 00:45:05,980
+وهنا هتلاحظوا Lithium Aluminum H4 اذا شفتوا هذا او
+
+505
+00:45:05,980 --> 00:45:09,780
+هذا هذا Sodium Borohydride Lithium Aluminum
+
+506
+00:45:09,780 --> 00:45:16,560
+Hydride شوفوا مثلها Sodium Borohydride Lithium
+
+507
+00:45:16,560 --> 00:45:21,220
+Aluminum Hydride هدوله الشرعوه المختزلة هم في
+
+508
+00:45:21,220 --> 00:45:27,990
+النهاية مصدر لإيش؟لل H- الان ال H- لما هاجم على ال
+
+509
+00:45:27,990 --> 00:45:34,850
+aldehyde عملوا ايش؟ كحول وهذه عملية الاختزال عكس
+
+510
+00:45:34,850 --> 00:45:40,150
+عملية ايش؟ الاكسادة هذه عملية الاختزال عكس عملية
+
+511
+00:45:40,150 --> 00:45:47,190
+الاكسادة هي reducing agents طبعا لو ال H- هاجم على
+
+512
+00:45:47,190 --> 00:45:53,490
+كيتون هيعملوا ايش؟secondary alcohol اذا انتبهوا
+
+513
+00:45:53,490 --> 00:45:59,030
+معي جيدا انه لما الهجوم تم على ال الديهايد عادي
+
+514
+00:45:59,030 --> 00:46:06,550
+اتكول اه اذا هل جيتها بنصير نكتب reduction عشان
+
+515
+00:46:06,550 --> 00:46:11,950
+تكون واضحة الأمور معاكم قبل الديهايدs produces
+
+516
+00:46:11,950 --> 00:46:19,070
+primary alcoholreduction of aldehydes produces
+
+517
+00:46:19,070 --> 00:46:23,950
+primary alcohols الان تحتها هيصير reduction of
+
+518
+00:46:23,950 --> 00:46:28,890
+كيتون ايش
+
+519
+00:46:28,890 --> 00:46:35,050
+produces secondary alcohols هو كل درسنا aldehydes
+
+520
+00:46:35,050 --> 00:46:40,240
+او كيتون ولا في غيرهم؟أذا بدنا نكون عارفين ان ال
+
+521
+00:46:40,240 --> 00:46:45,240
+الديهايد لما بنعمله reduction بالهيدرايد بده يصير
+
+522
+00:46:45,240 --> 00:46:50,080
+عنده primary alcohol و ال ketone لما بنعمله
+
+523
+00:46:50,080 --> 00:46:54,240
+reduction بال الديهايد بده يصير عنده secondary
+
+524
+00:46:54,240 --> 00:46:58,940
+alcohol لاحظوا هذا الكلام بفيدكم سواء بجمل صح و
+
+525
+00:46:58,940 --> 00:47:03,820
+غلط بأكمل معادلة او حتى لو احنا سألناكوا سؤال how
+
+526
+00:47:03,820 --> 00:47:09,210
+can you prepare the following compoundواضح؟ لما
+
+527
+00:47:09,210 --> 00:47:12,610
+تشوفوا أن الناتج اللي عندكم primary alcohol إذا
+
+528
+00:47:12,610 --> 00:47:16,530
+بتقدروا تفكروا أنه ممكن يكون إيجا من وين لما
+
+529
+00:47:16,530 --> 00:47:19,930
+تشوفوا الناتج اللي عندكم secondary alcohol إذا
+
+530
+00:47:19,930 --> 00:47:25,430
+ممكن يكون إيجا من وين من كيتون واضح الفكرة؟ بنقف
+
+531
+00:47:25,430 --> 00:47:29,510
+عند هذه النقطة المرة القادمة إن شاء الله بنحكي عن
+
+532
+00:47:29,510 --> 00:47:34,690
+تفاعل الديهيدس والكيتون مع متفاعل اسمه green yard
+
+533
+00:47:34,690 --> 00:47:39,740
+reagent عمرنا حكينا عنه؟بنعرفه المرة الجاية وبنشوف
+
+534
+00:47:39,740 --> 00:47:44,440
+كيف بتفاعل ال الديهيد والكيتون مع ال green yard
+
+535
+00:47:44,440 --> 00:47:46,220
+reagent شكرا
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/deKbe0lopF8_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/deKbe0lopF8_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..2d2500e2cf61da81dd0b1492154023e34a6e6059
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/deKbe0lopF8_postprocess.srt
@@ -0,0 +1,2056 @@
+1
+00:00:20,280 --> 00:00:26,570
+بسم الله الرحمن الرحيمفي موضوع ال alcohols اللى
+
+2
+00:00:26,570 --> 00:00:29,970
+بدأنا فيه المرة الماضية موضوع ال acidity of
+
+3
+00:00:29,970 --> 00:00:37,870
+alcohols او حمضية الكحولات هو موضوع مهم جدا الان
+
+4
+00:00:37,870 --> 00:00:43,130
+يمكن موضوع ال acidity كمان يمر علينا باكثر من موقع
+
+5
+00:00:43,130 --> 00:00:48,110
+في ال organ chemistry ربما بشكل أساسي في ال
+
+6
+00:00:48,110 --> 00:00:53,030
+carboxylic acids يمر علينا موضوع ال acidityربما
+
+7
+00:00:53,030 --> 00:00:57,330
+المشكلة اللى بتتواجهنا أكثر شيء في الموضوع إذا
+
+8
+00:00:57,330 --> 00:01:02,410
+الطلاب من الأساس .. إذا الطلاب من الأساس ماعندهمش
+
+9
+00:01:02,410 --> 00:01:08,670
+فكرة صحيحة وسليمة عن إيش معنى الحامضية بناء على
+
+10
+00:01:08,670 --> 00:01:13,010
+ذلك أي مفهوم متطور في الموضوع بده البني أدم يحكي
+
+11
+00:01:13,010 --> 00:01:20,150
+فيه بدون وجود الأصل عند الطالب هيكون بيمثلمشكلة
+
+12
+00:01:20,150 --> 00:01:25,570
+لأنه ماعندوش أصل يبني عليه ولذلك شوية بدأ أتجاوز
+
+13
+00:01:25,570 --> 00:01:32,170
+هذا ال slide أعطي نوعا ما مقدمة صغيرة تذكيرية في
+
+14
+00:01:32,170 --> 00:01:37,730
+الجزء المهم بالنسبة لنا في موضوع الحمضية في الجزء
+
+15
+00:01:37,730 --> 00:01:43,500
+المهم بالنسبة لنا في موضوع الحمضيةالنقطة الأولى
+
+16
+00:01:43,500 --> 00:01:48,380
+يمكن اللى بتواجهكم في موضوع الأحماض أنه مر عليكم
+
+17
+00:01:48,380 --> 00:01:55,770
+أكثرمن تعريف مار عليكم أكتر من تعريف للحمض شو هو
+
+18
+00:01:55,770 --> 00:02:01,510
+الحمض و شو القلوي ربما حسب التدرج اللي اتعلمته في
+
+19
+00:02:01,510 --> 00:02:05,830
+المدارس أول ما بيمر على الناس ال Arrhenius
+
+20
+00:02:05,830 --> 00:02:10,250
+definition تعريف Arrhenius للحمض و القلوي خلنا
+
+21
+00:02:10,250 --> 00:02:16,730
+نشوفه ال Arrhenius definition من خلال مثال
+
+22
+00:02:17,780 --> 00:02:23,240
+المثال المشهور جدا لو انا كنت باخد ال HCL زائد ال
+
+23
+00:02:23,240 --> 00:02:31,120
+NAOH و متعودين تكملوا المعادلة NACL
+
+24
+00:02:31,120 --> 00:02:37,240
+زائدH2O الآن ضمن هذا التعريف كان أرهينياس بيقول
+
+25
+00:02:37,240 --> 00:02:42,180
+الحامض ببساطة هو المادة اللي بتتأين و بتعطي H plus
+
+26
+00:02:42,180 --> 00:02:49,000
+والقاعدة هي المادة اللي بتتأين و بتعطي OH minus
+
+27
+00:02:49,000 --> 00:02:53,820
+واضح؟ هذه أول تعريف، إذا الحامض المادة اللي بتتأين
+
+28
+00:02:53,820 --> 00:02:57,000
+في الميّه بيبقى تعطيني H plus والقاعدة بيبقى
+
+29
+00:02:57,000 --> 00:03:04,640
+تعطيني OH minus هذا التعريف تعريف أرهينياسالان اجى
+
+30
+00:03:04,640 --> 00:03:13,060
+لوري برونستيد نظر للموضوع شوية من زاوية تانية يعني
+
+31
+00:03:13,060 --> 00:03:17,820
+لاحظوا هنا الحامض ايش بيطلع كل ال HCL القاعدة شو
+
+32
+00:03:17,820 --> 00:03:25,980
+بتطلع كل ال NaOH اذا خليني اعمل الحامض حسب تعريف
+
+33
+00:03:25,980 --> 00:03:32,200
+Arrhenius هحوطه بالازرع هي الحامض القاعدةهي
+
+34
+00:03:32,200 --> 00:03:38,160
+القاعدة الان لوري برونستيد نظر وممكن لنفس المعادلة
+
+35
+00:03:38,160 --> 00:03:45,060
+نظرة شوية فيها تخصص بمعنى وين المركز الفاعل وين
+
+36
+00:03:45,060 --> 00:03:50,580
+المركز الفاعل اللي موجود لكن للأسف يمكن نظر
+
+37
+00:03:50,580 --> 00:03:55,640
+للقاعدة فقط مانظرش للحمض فخلى تعريف الحامض خلى
+
+38
+00:03:55,640 --> 00:04:03,220
+تعريف الحامض هاي التعريف التاني لوري برونستيدخلّى
+
+39
+00:04:03,220 --> 00:04:07,960
+تعريف الحامض زى ما هو اللى بيعطى H بلس فى التأيون
+
+40
+00:04:07,960 --> 00:04:12,440
+واضح فالحامض عند لوري برويستن شو بيعطينى H بلس
+
+41
+00:04:12,440 --> 00:04:17,600
+وبناء على ذلك وين بده يكون الحمض الـHCl كله عنده
+
+42
+00:04:17,600 --> 00:04:23,820
+حامضالـ HCl كله عند لوري برونستيد ما زال حامض،
+
+43
+00:04:23,820 --> 00:04:29,520
+الآن إجا للقاعدة، قال هي القاعدة سرها في الـ NaOH
+
+44
+00:04:29,520 --> 00:04:33,740
+يعني لو افترضنا أنها كانت KOH مثلا، بوتاسيوم
+
+45
+00:04:33,740 --> 00:04:37,930
+هيدروكسايدأو كالسيوم هيدروكسايد أو ألمنيوم
+
+46
+00:04:37,930 --> 00:04:43,670
+هيدروكسايد إفراج كتير؟ لأ إذا سير قوة القاعدة مش
+
+47
+00:04:43,670 --> 00:04:48,950
+فيها كلها لأ في ال O H و بناء على ذلك خلى القاعدة
+
+48
+00:04:48,950 --> 00:04:54,910
+هي ال O H minus مش ال N A O H شوفتوا القاعدة إيش
+
+49
+00:04:54,910 --> 00:05:00,770
+صار فيها؟ اختلفت و قال الحامض بيعطي H plus القاعدة
+
+50
+00:05:00,770 --> 00:05:07,010
+بتكتسب H plusهذه لما بدأت اكتسب الـ OH-, الـ H بلس
+
+51
+00:05:07,010 --> 00:05:11,550
+اللي فقدت هنا هي اللي هتعطيني الميه طبعا الايونات
+
+52
+00:05:11,550 --> 00:05:16,910
+المرافقة بيبقى مرافقة فصار عندي شوية اختلاف في
+
+53
+00:05:16,910 --> 00:05:25,350
+التعريف صار بيعطي H بلس بيكتسبH plus و بناء على
+
+54
+00:05:25,350 --> 00:05:31,770
+ذلك سرنا أي مادة .. سرنا أي مادة يمكن أن تكتسب H
+
+55
+00:05:31,770 --> 00:05:36,930
+plus نقدر نعتبرها قاعدة يعني بطلت القاعدة بس بال O
+
+56
+00:05:36,930 --> 00:05:41,350
+H بال hydroxides يعني بمعنى لو انا اجيت فعلت مع ال
+
+57
+00:05:41,350 --> 00:05:44,530
+ammonia ما هي ال ammonia بتكتسب H plus بتعطينا
+
+58
+00:05:44,530 --> 00:05:49,240
+ايون ال ammonium برضه تعتبر baseفكل ما يكتسب ال H
+
+59
+00:05:49,240 --> 00:05:54,140
+plus يعتبره قاعدة و كل ما يعطي ال H plus يعتبره
+
+60
+00:05:54,140 --> 00:06:00,860
+base الان لاحظوا ان هو نظر هنا نظر هنا على ال N E
+
+61
+00:06:00,860 --> 00:06:04,880
+O H و جال مركز قوتها ايش ال O H ماله و مالي الان
+
+62
+00:06:04,880 --> 00:06:10,490
+ايه فصارت ال base عنده ال O H او اي شيء يكتسبH
+
+63
+00:06:10,490 --> 00:06:15,370
+Plus لكن ما إجهاش تطلع هنا بنظرة تفصيلية طب يا
+
+64
+00:06:15,370 --> 00:06:22,530
+تورا لو كان هذا مش HCL لو كان هذا HPR بيفرق ولا HI
+
+65
+00:06:22,530 --> 00:06:28,670
+إذا لو أنا بدأ أطلع كمان بنظرة تفصيلية أكتر وين
+
+66
+00:06:28,670 --> 00:06:34,610
+مركز القوة حقيقة في ال HCL هو ال H Plus وعشان هيك
+
+67
+00:06:34,610 --> 00:06:41,220
+إجى Lewis في تعريفهزي ما أتيت هنا وأخدت مركز القوة
+
+68
+00:06:41,220 --> 00:06:44,920
+هذا تعالي ناخد مركز القوة الـ H Plus
+
+69
+00:06:49,960 --> 00:06:55,420
+الـ OH- فكأنه أخلت من هذا الجزء الأساسي فيه ومن
+
+70
+00:06:55,420 --> 00:06:59,180
+هذا الجزء الأساسي فيه اللي هي حقيقة الـ net ionic
+
+71
+00:06:59,180 --> 00:07:02,220
+equation يعني هذه لو عملت لها net ionic equation
+
+72
+00:07:02,220 --> 00:07:06,120
+الـ Na والـ Cl كلهم من شطبه هي عبارة عن H بلس زائد
+
+73
+00:07:06,120 --> 00:07:13,860
+OH- بتعطينا H2O وبناء على ذلك ال acid عند Lewis هو
+
+74
+00:07:13,860 --> 00:07:20,530
+H بلسو الـ base عنده الـ OH- الان نظر طب ايش اللي
+
+75
+00:07:20,530 --> 00:07:26,290
+بيميز هدوله قال اه هو كل التفاعل انه هذه ال OH- لو
+
+76
+00:07:26,290 --> 00:07:32,710
+انا اعملتلها توزيع إلكتروني عليها هنا تلت أزواج من
+
+77
+00:07:32,710 --> 00:07:35,630
+الإلكترونات عشان هيك صارت minus هدفش عليه
+
+78
+00:07:35,630 --> 00:07:42,560
+إلكترونات هذا موجب و هذهسالبة الموجة بدي تفعل مع
+
+79
+00:07:42,560 --> 00:07:46,920
+السالب هذا بدي يعطي إلكترونات هنا وبناء على ذلك
+
+80
+00:07:46,920 --> 00:07:52,860
+جانب ال acid electron acceptor بده إلكترونات وال
+
+81
+00:07:52,860 --> 00:08:00,240
+base electron donorوصار هذا تعريف عام الآن أن أي
+
+82
+00:08:00,240 --> 00:08:06,440
+إش بيعطي إلكترونات base و أي إش بيكتسب إلكترونات
+
+83
+00:08:06,440 --> 00:08:11,100
+acid إذا صار حسب تعريف Lewis الموضوع مش متطلع إيش
+
+84
+00:08:11,100 --> 00:08:14,580
+تكون هذه و إيش تكون هذه يعني لو كتبت الآن بعيدا عن
+
+85
+00:08:14,580 --> 00:08:20,200
+ال H plus وعن ال OH minus لو كتبت A plus زائد مثلا
+
+86
+00:08:20,200 --> 00:08:21,580
+X minus
+
+87
+00:08:23,870 --> 00:08:26,950
+هذا بيعطي إلكترونات إذا هذا بيحصل هذا بيكتسب
+
+88
+00:08:26,950 --> 00:08:33,530
+إلكترونات إذا هذا أسد واضح و لذلك إذا بتذكروا لما
+
+89
+00:08:33,530 --> 00:08:37,390
+أخدنا على سبيل المثال في chapter ال aromatic
+
+90
+00:08:37,390 --> 00:08:43,950
+compounds مركب زي ال FECL3 قلنا إن ال FECL3 كام
+
+91
+00:08:43,950 --> 00:08:50,420
+إلكترون كان حوله6 electron sextant الوضع الطبيعي
+
+92
+00:08:50,420 --> 00:08:57,760
+كم يكون 8 و بناء على ذلك اعتبرنا Lewis acid فلما
+
+93
+00:08:57,760 --> 00:09:00,820
+نيجي نقول له ال aromatic compounds كيف كانوا
+
+94
+00:09:00,820 --> 00:09:07,760
+يتفاعلوا من خلال انه ييجي على سبيل المثال ال CL2
+
+95
+00:09:07,760 --> 00:09:12,530
+يتفاعل مع هذا الآن ال CL2 كان يعطيسيال مع
+
+96
+00:09:12,530 --> 00:09:16,930
+إلكتروناتها كأنه هذه ال base هو بيكتسب السيال مع
+
+97
+00:09:16,930 --> 00:09:21,290
+إلكتروناتها بيصير تمان إلكترونات حوله بدل ستة فهذا
+
+98
+00:09:21,290 --> 00:09:26,770
+acid وهذا الجزء كأنه تعامل ك base وعشان تقولنا أن
+
+99
+00:09:26,770 --> 00:09:31,270
+ال aromatic reactionsبتم في وجود ال FECL3 أو
+
+100
+00:09:31,270 --> 00:09:35,130
+الألمنيوم الكلوريد الآن الإنسان مابدوش يكتب FECL3
+
+101
+00:09:35,130 --> 00:09:38,870
+أو الألمنيوم الكلوريد بيقول ببساطة the
+
+102
+00:09:38,870 --> 00:09:43,230
+chlorination of aromatic compounds occurs by using
+
+103
+00:09:43,230 --> 00:09:49,770
+Cl2 with a Lewis acidسواء قولنا FECL3 ألمنيوم CL3
+
+104
+00:09:49,770 --> 00:09:54,590
+واطفر هو في النهاية Lewis acid يعني مش الفكرة فيه
+
+105
+00:09:54,590 --> 00:10:00,270
+بمسماك مركب لأ هي الفكرة فيه بمسماء النوعي أن هو
+
+106
+00:10:00,270 --> 00:10:08,350
+Lewis acid فصار كل شيء electron donor هو عبارة عن
+
+107
+00:10:08,350 --> 00:10:14,020
+base وكل شيء electron acceptorهو عبارة عن ايش؟
+
+108
+00:10:14,020 --> 00:10:21,680
+acid الان لاحظوا انا نفس المركبات طبقت عليها
+
+109
+00:10:21,680 --> 00:10:28,460
+التلات تعريفات ولكن هي نظرة اكثر تخصصية يعني هنا
+
+110
+00:10:28,460 --> 00:10:33,860
+كنت اطلع على المركب كلهأطلع على المُركّب كله و
+
+111
+00:10:33,860 --> 00:10:38,600
+أقول والله هذا المُركّب كله هو الحامض، الآن إجا
+
+112
+00:10:38,600 --> 00:10:42,000
+لوري برونز تدعم نفس الطريق، قالوا طب وين مركز
+
+113
+00:10:42,000 --> 00:10:45,980
+القوة في القاعدة؟ الـ OH خلّال الـ OH القاعدة، لكن
+
+114
+00:10:45,980 --> 00:10:50,320
+ماتطلعش على مركز القوة وين؟في الحمض ايه جالي ويس؟
+
+115
+00:10:50,320 --> 00:10:53,200
+جلطب هو مركز القوة زي ما انت شوفت انه هو مركز
+
+116
+00:10:53,200 --> 00:10:57,700
+القوة الـ OH شوف انه هو مركز القوة الـ H plus و
+
+117
+00:10:57,700 --> 00:11:01,380
+اعمل تعريفك عليه و بعدين نظرله من ناحية
+
+118
+00:11:01,380 --> 00:11:05,580
+الإلكترونات نظرله من ناحية الإلكترونات فواضح ان
+
+119
+00:11:05,580 --> 00:11:11,070
+التلات تعريف ليست متناقضةالتلات تعريف ليست متناقضة
+
+120
+00:11:11,070 --> 00:11:18,710
+ولكنها تمثل نظرة اكثر تخصصية نظرة اكثر ايش؟ تخصصية
+
+121
+00:11:18,710 --> 00:11:24,390
+واضح؟ هذا بالنسبة لتعريف الأحمد الآن لما انا بدي
+
+122
+00:11:24,390 --> 00:11:29,970
+اجي على قوة الحامض في المحليل اللي عندنا احنا عادة
+
+123
+00:11:29,970 --> 00:11:35,630
+بنستعملفي ال alcohols تحديدا و ال acids بنفضل
+
+124
+00:11:35,630 --> 00:11:38,590
+نستعمل اللوري برونس لدفنيشي لاحظوا الناس بيستعملوا
+
+125
+00:11:38,590 --> 00:11:44,370
+اي تعريف بما يخدم الغرض تبعهم الان لما بدي اجي
+
+126
+00:11:44,370 --> 00:11:48,570
+اقول ان انا بدي اتعرف على حامض كيف بيتأين و كيف
+
+127
+00:11:48,570 --> 00:11:54,200
+بيعطي ال ايونات خلينا نتخيل ان الحامض اللي عندناH
+
+128
+00:11:54,200 --> 00:12:00,500
+A هذا الـ H A عادة تأيّن كيف بتم في الميّه زائد H
+
+129
+00:12:00,500 --> 00:12:07,380
+2 O كلكم عارفين المعادلة H 3 O plus مثلا زائد A
+
+130
+00:12:07,380 --> 00:12:13,020
+minus لأن هذه المعادلة العامة و كل ما بيزيد
+
+131
+00:12:13,020 --> 00:12:16,660
+التأيّن الحامض أقوى لأن هذه المعادلة لها ثابت
+
+132
+00:12:16,660 --> 00:12:23,410
+اتزان لو احنا بدنا ثابت الاتزان تبعها ال Kهي ساوي
+
+133
+00:12:23,410 --> 00:12:34,730
+الـ H3O Plus في الـ A Minus على الـ HA في تركيز
+
+134
+00:12:34,730 --> 00:12:39,750
+الميّه النواتج
+
+135
+00:12:39,750 --> 00:12:43,070
+على
+
+136
+00:12:43,070 --> 00:12:50,300
+المتفائلات الان اعتادوا الناس ان اي تركيز ثابتما
+
+137
+00:12:50,300 --> 00:12:55,000
+يخلّوهاش شيء فالماء تركيزه ثابت الماء تركيزه ثابت
+
+138
+00:12:55,000 --> 00:13:00,760
+و لو أخدنا احنا جديش عادة في اللتر ميه الف جرام
+
+139
+00:13:00,760 --> 00:13:05,000
+قسمناه على ال molecular weight تبع ال .. تبع الميه
+
+140
+00:13:05,000 --> 00:13:08,240
+تمانتعش الف على تمانتعش بطلع لنا حوالي خمسة و
+
+141
+00:13:08,240 --> 00:13:12,100
+خمسين و كسر هذا موجود في اللتر و بناء على ذلك
+
+142
+00:13:12,100 --> 00:13:16,100
+التركيز الثابت للميه حوالي خمسة و خمسين و كسر الآن
+
+143
+00:13:16,100 --> 00:13:21,700
+طالما هذا التركيز ثابت و هذا ثابتبنضرب الثابتين في
+
+144
+00:13:21,700 --> 00:13:25,800
+بعضهم البعض بنضرب الثابتين في بعضهم البعض فبصير
+
+145
+00:13:25,800 --> 00:13:32,520
+عند K مضروب في تركيز ال H2O هدولة بعمللهم تعريف
+
+146
+00:13:32,520 --> 00:13:38,300
+جديد بقول هدولة سميهم K A فال K A مش هو ثابت
+
+147
+00:13:38,300 --> 00:13:43,620
+الإتزان واضح؟ ال K A شيء و ثابت الإتزان شيء هذا ال
+
+148
+00:13:43,620 --> 00:13:48,740
+K equilibrium constant هذا ال K A acidity constant
+
+149
+00:13:50,110 --> 00:13:53,330
+لحظوا ميزوا بينهم equilibrium constant is
+
+150
+00:13:53,330 --> 00:13:56,650
+something and acidity constant is another thing ال
+
+151
+00:13:56,650 --> 00:14:01,630
+K a هذه هي عبارة عن ثابت الاتزان مضروب في تركيز ال
+
+152
+00:14:01,630 --> 00:14:06,910
+H2O اللي ثابت الان لو اتيت على ال K a هيصير ربما
+
+153
+00:14:06,910 --> 00:14:12,250
+التعبير اللي حضرتكم بتعرفوه H3O plus في A minus
+
+154
+00:14:12,250 --> 00:14:22,130
+علىهذا تعبير إيش ال K A اللي بنسميه احنا acidity
+
+155
+00:14:22,130 --> 00:14:30,050
+constant يعني ثابت الحامض الآن ال acidity constant
+
+156
+00:14:31,960 --> 00:14:37,420
+و كل مكان أعلى كل مكان الحامض بتأيين أكثر والحامض
+
+157
+00:14:37,420 --> 00:14:41,740
+اللي بتأيين أكثر بالتعريف والحامض الاش الأقوى بناء
+
+158
+00:14:41,740 --> 00:14:46,780
+على ذلك لو أنا بدي أعمل مقارنة لحامضين مين اللي
+
+159
+00:14:46,780 --> 00:14:54,730
+بدي يكون أقوى اللي له K A أعلىإذا القاعدة بتقول as
+
+160
+00:14:54,730 --> 00:15:01,970
+KA increases as KA increases the acidity increases
+
+161
+00:15:01,970 --> 00:15:08,840
+كل ما زادت ال KA كل ما كان الحامض اشماله أقوىكل ما
+
+162
+00:15:08,840 --> 00:15:13,280
+الـ Ka بتكون أعلى في القيمة كل ما الحامض بيكون
+
+163
+00:15:13,280 --> 00:15:17,480
+أقوى فأنا لو أعطيتكم مثلا حامضين هي Ka لهذا وKa
+
+164
+00:15:17,480 --> 00:15:21,440
+لهذا بتقدروا على طول تقولولي مين الحامض الأقوى
+
+165
+00:15:21,440 --> 00:15:27,400
+فيهم اللي إله ال Ka أعلى خلينا نجرب نعمل هذا
+
+166
+00:15:27,400 --> 00:15:31,900
+الكلام خلينا نجرب نعمل هذا الكلام لو إجينا
+
+167
+00:15:31,900 --> 00:15:40,990
+أعطيناكم حامض HAو حامض HB وهي حامضين و خلّيني أقول
+
+168
+00:15:40,990 --> 00:15:48,170
+ال K A لهدول الحامضين يعني K A H A نفترض هنا 1.8
+
+169
+00:15:48,170 --> 00:15:55,910
+في 10 أقص ناقص خمسة و نفترض هنا 1.3 في 10 أقص ناقص
+
+170
+00:15:55,910 --> 00:16:04,140
+تلاتةمن الأقوى ال HB، ليش؟ لأن هذا المقدار أكبر من
+
+171
+00:16:04,140 --> 00:16:09,060
+هذا المقدار، إذا احنا هنا اتفقنا أن هذا الأقوى،
+
+172
+00:16:09,060 --> 00:16:13,360
+الآن لما اتفقنا أن هذا الأقوى، لو سألنا طالب، ليش
+
+173
+00:16:13,360 --> 00:16:20,180
+هذا أقوى؟هنتعبها مجرد .. مجرد الأمر تجميلي و ليس
+
+174
+00:16:20,180 --> 00:16:24,900
+أكثر هنتعبها في الحكي هتيجي تحكي و تفكر و تطلع
+
+175
+00:16:24,900 --> 00:16:28,460
+تاخدلها ثانيتين تفكير احنا بنختصر عليها ثانية بس
+
+176
+00:16:28,460 --> 00:16:32,900
+هتقول ال one point three في عشر أقص ناقص تلاتة
+
+177
+00:16:32,900 --> 00:16:36,900
+أكبر من ال one point eight في عشر أقص ناقص خمسة
+
+178
+00:16:36,900 --> 00:16:41,680
+وبناء على ذلك هذا كحمض أقوىأقولكوا أعطيتوا الجواب
+
+179
+00:16:41,680 --> 00:16:46,340
+الصحيح كلامكوا سليم 100% لكن أخذ منكم ثانية أو
+
+180
+00:16:46,340 --> 00:16:50,380
+ثانيتين تفكير الآن العلماء قالوا بنقدر نوفر على
+
+181
+00:16:50,380 --> 00:16:55,400
+طلابنا ثانية تفكير يعني لو الأمر بياخد منهم
+
+182
+00:16:55,400 --> 00:17:00,240
+ثانيتين تفكير عشان يقارنوا يتطلعوا على رقم كبير
+
+183
+00:17:00,240 --> 00:17:03,120
+مجرد معانكوا تكملوا جراية هذا و جراية هذا بتاخد
+
+184
+00:17:03,120 --> 00:17:07,200
+ثانيتين فالعلماء قالوا يا تورا بنقدر نختصر على
+
+185
+00:17:07,200 --> 00:17:13,080
+الطلاب ثانية من التفكيرقال و ممكن كيف؟ قال بدل ما
+
+186
+00:17:13,080 --> 00:17:17,640
+نتعامل مع الأرقام اللي مش حلوة خلينا نتعامل مع
+
+187
+00:17:17,640 --> 00:17:24,960
+أشياء أحلى نعرف مقدار جديد نقوله PKA و نقول ال PKA
+
+188
+00:17:24,960 --> 00:17:31,240
+بتساوي minus logarithm ال KA minus logarithm ال KA
+
+189
+00:17:32,640 --> 00:17:36,920
+الان لو انا جيبت ال calculator بدل ما تغلبوني قولت
+
+190
+00:17:36,920 --> 00:17:39,820
+one point eight في عشر أقص خمسة بال minus وال
+
+191
+00:17:39,820 --> 00:17:43,780
+logarithm تبعها لاحظ ناقص اربعة و سبعة اذا ال BKA
+
+192
+00:17:43,780 --> 00:17:51,660
+هنقاش اربعة و سبعة طيب لو اجيت اعملت للتاني قولت
+
+193
+00:17:51,660 --> 00:17:55,100
+one point three في عشر أقص تلاتة بال minus وال
+
+194
+00:17:55,100 --> 00:17:57,660
+logarithm تبعها اتنين وتسعة
+
+195
+00:18:02,040 --> 00:18:06,980
+أتنين وتسعة الان لاحظوا انا عارف الأقوى اللي اتيان
+
+196
+00:18:06,980 --> 00:18:11,940
+اكثر هذا طيب من ناحية ال BKA الحامض الأقوى شو
+
+197
+00:18:11,940 --> 00:18:18,820
+بتلاحظوا عليه اللي له BKA أقلواضح؟ اللي إله PKA
+
+198
+00:18:18,820 --> 00:18:23,700
+أقل إذا بدي أنا دائما .. الآن أنا هو أسهل للإنسان
+
+199
+00:18:23,700 --> 00:18:28,560
+لما يصير حافظ لغرض مقارنة الأحماط الأقل أقوى و
+
+200
+00:18:28,560 --> 00:18:33,060
+دائما أعطي قيم PKA جداش بياخد منكم .. لما أفرجيكم
+
+201
+00:18:33,060 --> 00:18:37,810
+رقمين زي هيك أقولكم مين الأقوىثانية لما أفرجيكوا
+
+202
+00:18:37,810 --> 00:18:42,110
+يفهموا زيكي بياخد ثانيتين إذا هذا ال BKA كل فكرتها
+
+203
+00:18:42,110 --> 00:18:48,530
+هي فكرة تجميلية لتسهيل النظر والتفكير بالنتيجة
+
+204
+00:18:48,530 --> 00:18:53,660
+والمقارنة لا تحمل معنى علمي جديدومدلها تماما
+
+205
+00:18:53,660 --> 00:18:58,860
+بالمناسبة الـ pH اللى بتتعرف minus logarithm تركيز
+
+206
+00:18:58,860 --> 00:19:01,700
+ال H plus طب هو لو الناس أخدوا تركيز ال H plus
+
+207
+00:19:01,700 --> 00:19:06,280
+وقارنوا بيقدروا يعني لو أنه في العلم ماعملوش
+
+208
+00:19:06,280 --> 00:19:12,100
+نهائيا تعريف ال pH و تعريف ال PKA كانوا بيقدروا
+
+209
+00:19:12,100 --> 00:19:16,180
+برضه يشرحوا كل العلم بدون مشاكل لإيش؟ بيقارنوا
+
+210
+00:19:16,180 --> 00:19:19,100
+اعتمادا على ال PA بس لما بيقارنوا بذكروا أرقام
+
+211
+00:19:19,100 --> 00:19:25,820
+شوية غلسةواضح؟ فكل فكرة ال BKA فلسفيا خلّيني أقول
+
+212
+00:19:25,820 --> 00:19:33,140
+على أقل تقدير هي تسهيل النظر للأرقام الآن لما باجي
+
+213
+00:19:33,140 --> 00:19:38,760
+انا بعطيكم جدول في قوة لكذا حامض اقولكوا من الأقوى
+
+214
+00:19:38,760 --> 00:19:43,460
+انتوا خلال الدقيقة راح تتطلعوا أقل واحد أقل BKA
+
+215
+00:19:46,600 --> 00:19:53,160
+أو لو أعطيتكواها بال .. بال Ka أعلى Ka هي الأقوى
+
+216
+00:19:53,160 --> 00:19:56,540
+لكن هنا عشان تشوفوا الأعلى عملية بتكون تطلع على
+
+217
+00:19:56,540 --> 00:20:03,500
+الكسر و على الأسل هنا بتبين ايش أسهل كتير هذه
+
+218
+00:20:03,500 --> 00:20:09,580
+العملية واضح فقط لغاية طبعا هنا هتيجيكوا مقارنة
+
+219
+00:20:09,580 --> 00:20:13,720
+دائما ضالكوا متذاكروها متذاكرينها ان ال strength
+
+220
+00:20:13,720 --> 00:20:21,750
+of acidلو سؤلنا عنه من ناحية ال K A و من ناحية ال
+
+221
+00:20:21,750 --> 00:20:29,350
+BKA من ناحية ال BK .. ال K A ال higher كل ما كانت
+
+222
+00:20:29,350 --> 00:20:34,230
+K A أعلى كل ما الحامض أقوى من ناحية ال BKA ال
+
+223
+00:20:34,230 --> 00:20:40,410
+lower كل ما كانت ال BKA أقل كل ما كان الحامض أقوى
+
+224
+00:20:40,410 --> 00:20:48,680
+واضح هذه المفاهيم؟الان هذه تقريبا مقدمة خلنا نقول
+
+225
+00:20:48,680 --> 00:20:55,520
+تذكير بشكل عام في مفاهيم الأحماض الان لما نيجي
+
+226
+00:20:55,520 --> 00:21:01,100
+نتكلم عن ال alcohols هل يا ترى الكحول ممكن يكون
+
+227
+00:21:01,100 --> 00:21:09,370
+حامض ولا لأ؟زي و زي الميه انا لما بدي اجي اقول رو
+
+228
+00:21:09,370 --> 00:21:14,410
+اتش عنده امكانية يفقد هذه الاتش المتصلة بالاكسجين
+
+229
+00:21:14,410 --> 00:21:19,850
+يعني نقول زائد اتش to او باتزان رو ماينوس
+
+230
+00:21:22,320 --> 00:21:29,240
+زائد H3O plus إذا هو يمكن أن يفقد هذه ال H وبناء
+
+231
+00:21:29,240 --> 00:21:34,940
+على ذلك ممكن أنه يكون حامض هي الميه نفسها ممكن
+
+232
+00:21:34,940 --> 00:21:40,140
+تكون حامض طبعا الميه لما كنا نقول عنها كحامض هي
+
+233
+00:21:40,140 --> 00:21:46,470
+مجرد HOHيعني لو أخدت نفس هذه المعادلة المية كحمض H
+
+234
+00:21:46,470 --> 00:21:50,410
+O H لاحظوا لما المرة الماضية قلتلكوا أن المية
+
+235
+00:21:50,410 --> 00:21:56,890
+فلسفيا ممكن اعتبرها كأن أبسط كحول هنا قلت H O R
+
+236
+00:21:56,890 --> 00:22:03,490
+وهنا H O H يعني كأن ال R هذه H عشان هي أبسط إيش
+
+237
+00:22:04,620 --> 00:22:10,680
+أبسط الكحولات فلسفيا زائد H2O هيعطينا HO minus
+
+238
+00:22:10,680 --> 00:22:20,720
+زائد H3O plus وهذا تفاعل اتزار معروف بالنسبة لنا
+
+239
+00:22:20,720 --> 00:22:25,260
+في كتب الكيميا اذا H2O كأن واحد منها اتعمل كحمض
+
+240
+00:22:25,260 --> 00:22:31,740
+فقد H plus التاني اتعمل ك base اكتسب H plus واضح
+
+241
+00:22:31,740 --> 00:22:36,400
+الفكرة؟و عشان هيك بنقول الميه حامض و الكحول حامض،
+
+242
+00:22:36,400 --> 00:22:41,660
+الآن طيب لو بدي أجي أقول مين أقوى كحامضية؟ هاد
+
+243
+00:22:41,660 --> 00:22:45,180
+السؤال كتير مهم، الكحول ولا الميه؟ لأنه بعد شوية
+
+244
+00:22:45,180 --> 00:22:52,040
+لما بنيجي نقول أن الكحول مطهربدنا نغسل إيدينا فيه
+
+245
+00:22:52,040 --> 00:22:56,520
+هل يا تورا إذا غسلنا إيدينا في الكحول بدهم ينشعتوا
+
+246
+00:22:56,520 --> 00:23:01,720
+وينحرجوا بالإيثانول ولا لأ الآن هذا الجواب بنشوفه
+
+247
+00:23:01,720 --> 00:23:07,520
+من وين احنا من قيم ال BKA اتطلعوا انتوا على الماء
+
+248
+00:23:07,520 --> 00:23:12,900
+كحمض ال BKA له خمس طعش وسبعة اتطلعوا على الميثانول
+
+249
+00:23:12,900 --> 00:23:17,700
+خمس طعش وخمسة اتطلعوا على الإيثانول خمس طعش وتسعة
+
+250
+00:23:18,410 --> 00:23:25,030
+الان كل هذه القيم من ناحية المبدأ تكاد تكون
+
+251
+00:23:25,030 --> 00:23:31,650
+متساوية اذا حمضية الكحول مثل حمضية الميه والميه
+
+252
+00:23:31,650 --> 00:23:35,810
+متعودين نقول عنها weak acid عشان هيك لما بتعملوا
+
+253
+00:23:35,810 --> 00:23:39,130
+في المستقبل مزرعة بكتيريا وصار على إيديكوا جراثيم
+
+254
+00:23:39,130 --> 00:23:44,910
+و بعدها بدكوا تغسلوا تطهروا إيديكم بالكحولاللي
+
+255
+00:23:44,910 --> 00:23:48,250
+موجود واتوكلوا على الله مش هيعمل فيكوا إشي ولا
+
+256
+00:23:48,250 --> 00:23:53,230
+تفكروا إنه هيحرجلكوا إيديكوا من ناحية ال acidity
+
+257
+00:23:53,230 --> 00:23:59,430
+ال ethanol زي و زي الميه الآن اتخيلوا لو كنتوا
+
+258
+00:23:59,430 --> 00:24:04,030
+بتتعاملوا مع phenol اللي هو ال aromatic alcohol
+
+259
+00:24:04,030 --> 00:24:12,340
+نزل لعشرات إذا صارحامض اكتر عشان هيك الفينول اذا
+
+260
+00:24:12,340 --> 00:24:20,000
+كب ع اديكو هيعلم هيعمل لون هيحرق الايد واضح طبعا
+
+261
+00:24:20,000 --> 00:24:24,420
+لو بدي اجي على مركب زي ال Nitro Phenol سبعة و
+
+262
+00:24:24,420 --> 00:24:29,900
+اتنين اقوى و اقوى طب لو اجيتلى مركب زي ال Tri
+
+263
+00:24:29,900 --> 00:24:36,320
+Nitro Phenol point two fiveقوي جدا لدرجة انه
+
+264
+00:24:36,320 --> 00:24:40,240
+بيغيروا اسمه بدل ما يسموه phenol اعطوه اسم acid
+
+265
+00:24:40,240 --> 00:24:45,260
+بيكريك أسد حامض أصفر غامق بيكريك أسد مرات
+
+266
+00:24:45,260 --> 00:24:49,040
+بتستعملوه في بعض التحاليل لاحظوا شو اللي خلاهم رغم
+
+267
+00:24:49,040 --> 00:24:52,900
+انه في مجموعة ال O H يعني من ناحية اللي متعودين
+
+268
+00:24:52,900 --> 00:24:57,820
+على ال acids بال organ ال chemistry C double bond
+
+269
+00:24:57,820 --> 00:25:04,020
+OOHمش بس هم ال acids هم لما بيفقدوا ال H plus
+
+270
+00:25:04,020 --> 00:25:07,320
+بيكونوا acids بالعكس ال acetic acid .. ال acetic
+
+271
+00:25:07,320 --> 00:25:13,880
+acid لو بتكن تتطلع عليه CH3COOOH
+
+272
+00:25:13,880 --> 00:25:20,530
+هذا ال BKA له أربعة وسبعة بالعشرةيعني اللي احنا
+
+273
+00:25:20,530 --> 00:25:24,750
+ماعطينه اسم acid أربعة أو سبعة من عشرة الآن لما
+
+274
+00:25:24,750 --> 00:25:27,850
+تقوله هذا أربعة أو سبعة من عشرة مقارنة ب point two
+
+275
+00:25:27,850 --> 00:25:32,510
+five لل بيكريك أسد مين أقوى ميت مرة و بيحرق الجلد
+
+276
+00:25:32,510 --> 00:25:37,990
+ميت مرة ال بيكريك أسد رغم أنه هذا alcohol in
+
+277
+00:25:37,990 --> 00:25:41,870
+principle أو فينول واضح؟ رغم أن هذا alcohol أو
+
+278
+00:25:41,870 --> 00:25:47,210
+فينول فالفكرة بقيم ال BKA مش في النهاية حتى بال
+
+279
+00:25:47,210 --> 00:25:52,610
+structure الكيميائيطبعا بيصير السؤال يا تورا لحظه
+
+280
+00:25:52,610 --> 00:25:55,550
+انا مثلا لو جينا اتطلعنا على مركب two two two
+
+281
+00:25:55,550 --> 00:26:00,790
+trifluoroethanol جداش ال acidity تبعته؟ ماعشه
+
+282
+00:26:00,790 --> 00:26:05,630
+اربعة اذا لو انا بالاثانول بدال ال تلت هيدروجينات
+
+283
+00:26:05,630 --> 00:26:12,440
+لflour الحمضية بتزيد ولا بتجيل؟ بتزيدبصير السؤال
+
+284
+00:26:12,440 --> 00:26:17,060
+عاد .. بصير السؤال اللي بدنا نفهمه ليش يا تورا ..
+
+285
+00:26:17,060 --> 00:26:23,600
+ليش يا تورا الفينول كحمض أقوى من الإيثانول؟ ليش يا
+
+286
+00:26:23,600 --> 00:26:28,980
+تورا ال acetic acid أقوى من الإيثانول بكتير؟ يعني
+
+287
+00:26:28,980 --> 00:26:33,260
+ال acetic acid لو حطيناه على إيدنا، بده يحرج إيدنا
+
+288
+00:26:34,380 --> 00:26:38,400
+واضح؟ احنا مراتب بنستعمل الخل و بنشرب، لكن هذا خل
+
+289
+00:26:38,400 --> 00:26:43,260
+مخفف بنسبة أقل من خمسة في المية، خفيف كتير، لكن لو
+
+290
+00:26:43,260 --> 00:26:49,130
+حد بده يحط الخل النقيالصافي مش المدوّب في الميّه
+
+291
+00:26:49,130 --> 00:26:53,430
+اللي بنباع في السوق ال vinegar هذا خل أقل من 5%
+
+292
+00:26:53,430 --> 00:26:57,490
+ممكن تفوته على السلطة ممكن تشرب معلجة منه أو تخففه
+
+293
+00:26:57,490 --> 00:27:01,150
+بميه و تشرب معلجة منه لكن الخل نفسه لو بده أخده
+
+294
+00:27:01,150 --> 00:27:05,530
+كحامق بدون ما يكون مخفف بالميه هيحرج الإيدانواضح؟
+
+295
+00:27:05,530 --> 00:27:09,070
+ليش الخل اقوى من الاثانول؟ ليش ال try
+
+296
+00:27:09,070 --> 00:27:13,150
+fluoroethanol اقوى من الاثانول؟ ليش الفينول اقوى
+
+297
+00:27:13,150 --> 00:27:17,690
+من الاثانول؟ ليش ال nitrophenol اقوى من الفينول؟
+
+298
+00:27:17,690 --> 00:27:22,290
+ليش ال try nitrophenol اقوى من ال nitrophenol؟
+
+299
+00:27:22,290 --> 00:27:29,730
+الان كل هذه دراساتمقارنة يعني لما بدأ اقارن حامضين
+
+300
+00:27:29,730 --> 00:27:34,610
+لما بدأ اقارن حامضين و اجي اقول ان في عندى حامض
+
+301
+00:27:34,610 --> 00:27:42,270
+اقوى من حامض السؤال ليش تمام خلينا نفهم الأمور
+
+302
+00:27:42,270 --> 00:27:50,470
+شوية بهدوء و بشكل خلينا اقول منطقي اللي يخدمني لكل
+
+303
+00:27:50,470 --> 00:27:55,430
+الحالات اللي موجودة كل حالة بالمناسبة لها سببيعني
+
+304
+00:27:55,430 --> 00:28:00,950
+هنا مش سبب واحد اللي موجود لأ هي أكتر من سبب فرعي
+
+305
+00:28:00,950 --> 00:28:05,390
+لكن اللي بديه يفهم الموضوع ناخد الموضوع بشكل عام
+
+306
+00:28:05,390 --> 00:28:09,790
+لو بدنا نحكي على مقارنة حامضين خليني أجي أتخيل أني
+
+307
+00:28:09,790 --> 00:28:18,080
+بدي أقارن ال HCL و ال HBRكأحمار تمام و اقول انا
+
+308
+00:28:18,080 --> 00:28:23,700
+انه hcl و استعمل aq عارفين aq؟ aqs يعني بمية هذا
+
+309
+00:28:23,700 --> 00:28:28,540
+الكلام بيصير عشان ما نتغلبش h plus aqs يعني كأنها
+
+310
+00:28:28,540 --> 00:28:36,160
+h3o زائد cl minus و لو انا اجيت قولت hbr aqs برضه
+
+311
+00:28:36,160 --> 00:28:45,330
+h plus aqs زائد br minus كل هذا الكلام ايش؟في
+
+312
+00:28:45,330 --> 00:28:51,270
+محلول معين كل هذا الكلام محلول معين الان ال HBR
+
+313
+00:28:51,270 --> 00:28:56,030
+بالتجربة اقوى من ال HCL ال HBR بالتجربة اقوى من ال
+
+314
+00:28:56,030 --> 00:29:00,750
+HCL لو انا بدي اجي اقول يا تورا ايش السبب لاحظوا
+
+315
+00:29:00,750 --> 00:29:06,270
+لو فكرنا بمنطقة ال H plus لو فكرنا بمنطقة ال H
+
+316
+00:29:06,270 --> 00:29:11,610
+plus هذا بيعطي H plus وهذا بيعطي H plus اذا الحكم
+
+317
+00:29:11,610 --> 00:29:17,570
+مش ال H plusالحكم مش الـ H plus المشترك عمره ما
+
+318
+00:29:17,570 --> 00:29:22,470
+بيفرق شغلتين اللي بيفرق هو إيش؟ المختلف بناء على
+
+319
+00:29:22,470 --> 00:29:30,020
+ذلك ال PR minus وال CL minus هم السبب هم السببفي
+
+320
+00:29:30,020 --> 00:29:34,300
+انه حامض اقوى من حامض هم السبب في انه حامض اقوى من
+
+321
+00:29:34,300 --> 00:29:39,240
+حامض الان احنا بنقول الايون السالب النظر اليه هو
+
+322
+00:29:39,240 --> 00:29:42,220
+محور التفكير يوم افدياليس اللي اش حامض اقوى من
+
+323
+00:29:42,220 --> 00:29:46,100
+حامض على ايش بدأ اطلع على الايون السالب لان كله
+
+324
+00:29:46,100 --> 00:29:52,360
+هياطلق اتش بلس بنقول كل ما كان الايون السالب اثبت
+
+325
+00:29:52,360 --> 00:29:58,140
+كل ما كان الحامض اقوى واضح؟يعني كل ما هذا الايون
+
+326
+00:29:58,140 --> 00:30:02,940
+السالب أثبت الحامض أقوى و ربما هذا الكلام يكون
+
+327
+00:30:02,940 --> 00:30:08,260
+بحاجة شوية إلى تفسير شو يعني ان الايون السالب أثبت
+
+328
+00:30:08,260 --> 00:30:18,910
+المقصود بالثبات أن يحمل شحنة أقلالثبات كلما زادت
+
+329
+00:30:18,910 --> 00:30:25,410
+الشحنة قل الثبات و كلما قلت الشحنة زاد الثبات إذا
+
+330
+00:30:25,410 --> 00:30:30,190
+الثبات مرتبط بإيش؟ بالشحنة لما بتزيد بيبطل فيه
+
+331
+00:30:30,190 --> 00:30:34,250
+ثبات لما بتقل بيصير فيه ثبات فاللي بده يثبت أي شغل
+
+332
+00:30:34,250 --> 00:30:38,650
+بده يقل شحنتها لاحظوا هذا الكلام مش خاص في الأحماط
+
+333
+00:30:38,650 --> 00:30:43,630
+بس حتى في البشر يعني على سبيل المثال الغضب ..
+
+334
+00:30:43,630 --> 00:30:51,830
+الغضب إيش تعريفه؟الغضب شُحنة وهذه الشُحنة تظهر حتى
+
+335
+00:30:51,830 --> 00:30:56,430
+على الطاقة ال energy تظهر حتى على وش الإنسان وعلى
+
+336
+00:30:56,430 --> 00:31:00,650
+خدوده تشوف كيف عينيه يطلعوا لبرا الإنسان الغضبان
+
+337
+00:31:00,650 --> 00:31:04,370
+وخدوده حمر الرسول عليه الصلاة والسلام ايش بيقول
+
+338
+00:31:04,370 --> 00:31:11,460
+أما رأيتم إلى انتفاخ أوداجه وحمرار عينيهليش؟ لأنه
+
+339
+00:31:11,460 --> 00:31:16,120
+بيحمل شحنة غضب كتيرة هذا الغضبان كتير بيكون stable
+
+340
+00:31:16,120 --> 00:31:20,740
+ولا unstable؟ بيكون unstable اليوم لاحظوا لما أنا
+
+341
+00:31:20,740 --> 00:31:25,020
+بدي أضيع الغضب منه عند اللزوم بغسله بالمية مش ممكن
+
+342
+00:31:25,020 --> 00:31:29,700
+جد ما يكون الإنسان غضبان مولّع نار لو حاطيته تحت
+
+343
+00:31:29,700 --> 00:31:36,160
+دوش مية هي energy طاقة المية الباردة هذه هتسحب ال
+
+344
+00:31:36,160 --> 00:31:43,300
+energy منه هيقلل الغضبكل ما قلت الشحنة كل ما اش
+
+345
+00:31:43,300 --> 00:31:47,860
+عندى صار زادى الثبات اذا انا لما بدى اقارن شغلة
+
+346
+00:31:47,860 --> 00:31:52,380
+اثبت من شغلة بدى اطلع على الشحنة السالبة و اشوف
+
+347
+00:31:52,380 --> 00:31:58,800
+ايش اللى بيخليها اقل بدى يصير الان سؤالنا ايش طرق
+
+348
+00:31:58,800 --> 00:32:05,620
+تقليل الشحنة السالبة كيف ممكن الشحنة السالبة تكون
+
+349
+00:32:05,620 --> 00:32:15,250
+ايش اقلواضح؟ كيف ممكن أقلل أنا الشحنة؟ بشكل عام،
+
+350
+00:32:15,250 --> 00:32:23,890
+الشحنة حمل إمصيبة، عدم ثبات، كيف بدي أقللها؟ أنا
+
+351
+00:32:23,890 --> 00:32:29,060
+بحبش الكيمياأنا الكيميا دي مابحبهاش بالمرة أنا بحب
+
+352
+00:32:29,060 --> 00:32:34,820
+نفهم الموضوع من الحياة نفهم الموضوع كيف من الحياة
+
+353
+00:32:34,820 --> 00:32:39,080
+انتبهوا معايا لو اتخيلتوا الآن لو اتخيلتوا الآن
+
+354
+00:32:39,080 --> 00:32:45,440
+انسان راح على السوقو حمل اشترى خمسة كيلو من شغلة
+
+355
+00:32:45,440 --> 00:32:51,460
+معينة هدول يمثلوا شحنة ولا حمل ولا لأ؟ و حملهم هذا
+
+356
+00:32:51,460 --> 00:32:56,400
+الإنسان حمل خمسة كيلو بمثله ثقل عليه وعدم ثبات ولا
+
+357
+00:32:56,400 --> 00:33:02,940
+لأ؟ الآن بدنا نساعد هذا البني آدم نقلل الحمل اللي
+
+358
+00:33:02,940 --> 00:33:08,670
+عليهفي عندى اكثر من طريقة الطريقة الاولى تخيلوا لو
+
+359
+00:33:08,670 --> 00:33:14,310
+الخمسة كيلو دولة حملهم طفل صغير عمره اربع سنين ولا
+
+360
+00:33:14,310 --> 00:33:19,410
+حملهم شاب عمره عشرين سنة مين بيكون اثبت ومتريح
+
+361
+00:33:19,410 --> 00:33:26,050
+اكتر اذا كل ما بيزيد الحجملما أحط عليه حمل معين،
+
+362
+00:33:26,050 --> 00:33:30,330
+نفس الحمل، الخمسة كيلو على ابن أربع سنين لصغير ولا
+
+363
+00:33:30,330 --> 00:33:34,770
+على ابن عشرين سنة، مين اللي بيحمل أكثر؟ إذا صار
+
+364
+00:33:34,770 --> 00:33:39,630
+عند أول تأثير ممكن نفكر فيه تأثير إيش؟ الحجم، إنه
+
+365
+00:33:39,630 --> 00:33:45,070
+كل ما الحجم كبر، الإش بنحمل أسهل وعشان هيك الشاب
+
+366
+00:33:45,070 --> 00:33:50,860
+الكبير بيحمل الخمسة كيلو أسهل من إشمن الولد الصغير
+
+367
+00:33:50,860 --> 00:33:56,060
+طب لو إجينا لشاب كبير و قولنا له هدولة الخمسة كيلو
+
+368
+00:33:56,060 --> 00:34:02,340
+كيف ممكن كمان أقلل الحمل عنده بييجي شخص تاني
+
+369
+00:34:02,340 --> 00:34:05,960
+بيقوله أساعد معاك الان لما الشخص التاني بيقوله
+
+370
+00:34:05,960 --> 00:34:10,900
+أساعد معاك نفترض أن هدولة الخمسة كيلو هاي هذا ماسك
+
+371
+00:34:10,900 --> 00:34:15,880
+من هنا والتاني ماسك معاه صار الحمل محمول من إيش؟
+
+372
+00:34:15,880 --> 00:34:24,270
+من طرفيناتوزع الحمل واضح؟ صار في شخص مساعد هذا
+
+373
+00:34:24,270 --> 00:34:28,570
+الكلام نفسه ممكن يتكرر في الكيميا بنسميه إيش احنا؟
+
+374
+00:34:28,570 --> 00:34:32,890
+inductive effect يعني تأثير المساعدة من شيء قريب
+
+375
+00:34:32,890 --> 00:34:37,770
+إنه حد يساعد معاك طيب نفترض في طريقه مافيش ولا حد
+
+376
+00:34:37,770 --> 00:34:44,930
+يساعد هذا الإنسان هو حامل الخمسة كيلو إيش هيعمل؟
+
+377
+00:34:45,770 --> 00:34:48,850
+هذه الإيد بتتعب بتلاحظوا لو صورته
+
+378
+00:34:52,190 --> 00:34:57,270
+بصير يعمل تبديل هذا التبديل إيش بنسميه resonance
+
+379
+00:34:57,270 --> 00:35:02,710
+إذا هو خفف عن نفسه الحمل بإيش بال resonance لحظو
+
+380
+00:35:02,710 --> 00:35:08,250
+كام طريقة الأن صرت أنا حاكي لتخفيف الحمل تلت طرق
+
+381
+00:35:08,250 --> 00:35:14,350
+الطريقة الأولى زيادة الحجم الطريقة التانية طريقة
+
+382
+00:35:14,350 --> 00:35:17,930
+ال inductive effect ليه المساعدة و الطريقة التالتة
+
+383
+00:35:17,930 --> 00:35:21,930
+طريقة ال resonanceهذه الطرق اللي من خلالها انا
+
+384
+00:35:21,930 --> 00:35:26,970
+ممكن اقلل الشحنة الان لو بدأنا نتطلع على زيادة
+
+385
+00:35:26,970 --> 00:35:33,010
+الحجم حسب الجدول الدوري مين اكبر لبروم ولا لكلور؟
+
+386
+00:35:33,010 --> 00:35:39,250
+لبروم اتطلع معنا لبروم تحت في الجدول الدوري يعني
+
+387
+00:35:39,250 --> 00:35:44,390
+كأنه هاي لبروم و كأنه هاي لكلور الان عليهم نفس
+
+388
+00:35:44,390 --> 00:35:50,320
+الحمل شحنة سالبة و شحنة سالبةمين اقدر على حمل
+
+389
+00:35:50,320 --> 00:35:54,640
+الشحنة السالبة؟ الحجم الكبير طبعا لو بدأ اقارن
+
+390
+00:35:54,640 --> 00:36:00,460
+اليود اكبر منهم كلهم الان عليهم نفس الشحنة السالبة
+
+391
+00:36:00,460 --> 00:36:05,400
+من الاقدر على حمل الشحنة؟ اليود وبناء على ذلك لما
+
+392
+00:36:05,400 --> 00:36:13,100
+انا بدأ اجي افسر ليش ال hi اقوى من ال hbr اقوى من
+
+393
+00:36:13,100 --> 00:36:20,720
+ال hcl بدأ اقول السبب هو ايش ال sizeالـ Sizeبكلمة
+
+394
+00:36:20,720 --> 00:36:24,460
+واحدة ال size انه الحجم الكبير بيقدر يحمل نفس
+
+395
+00:36:24,460 --> 00:36:30,300
+الشحنة السالبة واضح السبب هو ايش ال size الان هاي
+
+396
+00:36:30,300 --> 00:36:34,500
+فهمنا التأثير الاول طب نجيبله مثال من الأشياء اللي
+
+397
+00:36:34,500 --> 00:36:39,520
+بدنا ندرسها متذكرين ان احنا شبترنا ال alcohols و
+
+398
+00:36:39,520 --> 00:36:43,220
+الthiols و متذكرين اللي هو ال oxygen و ال sulfur
+
+399
+00:36:43,220 --> 00:36:51,610
+تحت بعض طب لو بدي اجي اقول roh ولا rshالاتنين
+
+400
+00:36:51,610 --> 00:36:57,370
+هيفقدوا ايش ال H أنا قولت بدها تطلع على السالب
+
+401
+00:36:57,370 --> 00:37:02,170
+اللي بده يقارن حمضية بده يطلع على السالب هذا فقد و
+
+402
+00:37:02,170 --> 00:37:07,150
+هيحمل سالب وهذا فقد و يحمل سالب هو مين أكبر ال O
+
+403
+00:37:07,150 --> 00:37:13,750
+ولا ال S؟ ال S وبناء على ذلك بيصير ال RSH أقوى من
+
+404
+00:37:13,750 --> 00:37:19,980
+ال R O attributeSize و كذلك الحالة لو كنت أقولكم
+
+405
+00:37:19,980 --> 00:37:28,600
+ARSH و AROH من الأقوى؟ ال ARSH يعني طالما أنا موحد
+
+406
+00:37:28,600 --> 00:37:31,840
+كل إشي بس مفرج ال sulfur و ال oxygen طب ما هي ال
+
+407
+00:37:31,840 --> 00:37:40,410
+sulfur؟أكبر من ال Oxygen فهي أكبر على حمل الشحنة
+
+408
+00:37:40,410 --> 00:37:46,110
+السلبية إذا هذا ال size فصّال لي ليش ال RSH أقوى
+
+409
+00:37:46,110 --> 00:37:56,410
+من ال ROH و ليش ال ARSH أقوى من ال AROH ال size
+
+410
+00:37:56,410 --> 00:38:01,560
+اللي فصّال ليها الحجمالحجم الكبير أقدر على حمل
+
+411
+00:38:01,560 --> 00:38:09,620
+الشحنة الحجم الكبير أقدر على حمل الشحنة الآن خليني
+
+412
+00:38:09,620 --> 00:38:14,500
+أجي لل resonance و بدي أقارن أنا الاثانول مع حمض
+
+413
+00:38:14,500 --> 00:38:24,010
+الخلق لاحظوا الاثانول إيش صيبته؟CH3 CH2 OH وحمض
+
+414
+00:38:24,010 --> 00:38:33,550
+الخلب CH3 C O OH الآن اتفقنا انه لما بدنا نقارن ال
+
+415
+00:38:33,550 --> 00:38:39,690
+H Plus مش لازماني بدي اشيلها و بده اقارن ال Ion
+
+416
+00:38:39,690 --> 00:38:45,650
+السالب و Ion السالب واضح؟
+
+417
+00:38:46,870 --> 00:38:51,470
+الان هتلاحظوا هنا ال ايون السالب هذا موجود على ال
+
+418
+00:38:51,470 --> 00:38:55,430
+oxygen مش قادر يتحرك يعني هذا أشبه البني ادم معه
+
+419
+00:38:55,430 --> 00:39:00,170
+حمل بس إيده التانية مقطوعة طول الطريق هيضله إيش؟
+
+420
+00:39:00,170 --> 00:39:05,670
+حامل الشحن السالب على هذا ال oxygen هذا لأ له اتين
+
+421
+00:39:06,690 --> 00:39:10,570
+بناء على ذلك هذا ممكن يعمل resonance بمعنى أن هذه
+
+422
+00:39:10,570 --> 00:39:15,050
+تتحرك هنا وهذه تيجي هنا لاحظوا هذا ال resonance
+
+423
+00:39:15,050 --> 00:39:21,670
+حركة الإلكترونات متذكرين لما أخدناها CH3 سيصبح CH3
+
+424
+00:39:21,670 --> 00:39:26,150
+وهذه تصبح double bond O وهنا ال O minus إذا ال
+
+425
+00:39:26,150 --> 00:39:31,850
+minus أين صارت محمولة مرة على ال oxygen هذه ومرة
+
+426
+00:39:31,850 --> 00:39:36,350
+على هذهعملة resonance وعشان هيك مرات بتلاقوهم
+
+427
+00:39:36,350 --> 00:39:43,950
+كتبوها بهذا الشكل للأيون CH3COO وعملوا
+
+428
+00:39:43,950 --> 00:39:48,310
+ال minus مشترك بينهم جاعت بتنجل هذا تأثير ايش
+
+429
+00:39:48,310 --> 00:39:53,510
+resonance هذا تأثير resonance عشان هيك ال acetic
+
+430
+00:39:53,510 --> 00:39:57,490
+acid لو بتكون قارنوه بالإيثانول اربعة وسبعة ال BKA
+
+431
+00:39:57,490 --> 00:40:03,880
+مقارنة بخمستاعش تسعةالملاحظين قديش ال acetic acid
+
+432
+00:40:03,880 --> 00:40:09,580
+أقوى من ال ethanol كتير جدا مافيش مقارنة بينهم و
+
+433
+00:40:09,580 --> 00:40:13,720
+السبب لما نقول ال acetic acid is stronger than
+
+434
+00:40:13,720 --> 00:40:19,990
+ethanol الجواب يوتوresonance due to resonance بعد
+
+435
+00:40:19,990 --> 00:40:24,470
+شوية هتلاحظوا انه لما اجي اقارن الفينول بالاثانول
+
+436
+00:40:24,470 --> 00:40:29,330
+تاومت زكريه لما قولنا الفينول عشرة والاثانول خمساش
+
+437
+00:40:29,330 --> 00:40:32,930
+ستاش هتلاحظوا ان الفينول بعمل resonance للاثانول
+
+438
+00:40:32,930 --> 00:40:33,270
+لأ
+
+439
+00:40:37,470 --> 00:40:43,210
+الفكرة العامة وصلت انه هذا التأثير هو تأثير ايش؟
+
+440
+00:40:43,210 --> 00:40:47,110
+resonance نيجي للتأثير التالت ال inductive effect
+
+441
+00:40:47,110 --> 00:40:51,190
+انه ييجي حد يساعد يقول خليني اساعد معاك يعني
+
+442
+00:40:51,190 --> 00:40:55,490
+الشحنة مكانها زي الحمل ما زال باليد هادى مانتجلش
+
+443
+00:40:55,490 --> 00:41:01,550
+لكن بيجي حد ايش؟ بساعد اضافى لو انا اجيت اطلعت على
+
+444
+00:41:01,550 --> 00:41:07,470
+ال ethanol مرة تانيةCH3 CH2 بدي أخد منه على طول بس
+
+445
+00:41:07,470 --> 00:41:12,110
+ال ion السالب هيو مسكين حامل شحنة سالبة متغلب فيها
+
+446
+00:41:12,110 --> 00:41:17,310
+ولا لأ؟ متغلب جدا عارفين ليش؟ لأن ال oxygen صغيرة
+
+447
+00:41:17,310 --> 00:41:21,670
+مش قدرت تحمل شحنة سالبة ال oxygen مش قادرة تحمل
+
+448
+00:41:21,670 --> 00:41:25,550
+الشحنة السالبة الآن هذا يا تورا لو كنت بدي أقارنه
+
+449
+00:41:25,550 --> 00:41:29,110
+بالمركب اللي فيه تلت ذرات floor بسم الله ما شاء
+
+450
+00:41:29,110 --> 00:41:29,330
+الله
+
+451
+00:41:32,590 --> 00:41:38,790
+و هاي ال O و هاي عليها ال minus لاحظوا
+
+452
+00:41:38,790 --> 00:41:43,910
+ال floor ايش ماله ال electronegative ال
+
+453
+00:41:43,910 --> 00:41:48,090
+electronegative شو بعمل في الشحنة السالبة بسحب جزء
+
+454
+00:41:48,090 --> 00:41:53,030
+منها بحمل جزء منها بناء على ذلك هذه الشحنة السالبة
+
+455
+00:41:53,030 --> 00:41:59,650
+فى ناس مساعدين يساعدوا بحملها لأ الآن هنا هاي ال
+
+456
+00:41:59,650 --> 00:42:05,290
+floorElectronegative بيسحق جزء و ال floor التاني
+
+457
+00:42:05,290 --> 00:42:09,510
+كمان جزء و ال floor التالت يعني كأنه حمل أكم واحد
+
+458
+00:42:09,510 --> 00:42:14,050
+إيجي يساعد بحمله كمان تلاتة زي ناس حاملين شغلة
+
+459
+00:42:14,050 --> 00:42:18,790
+كبيرة و إجوا كمان تلاتة يساعدوا بحملها مش بتحمل
+
+460
+00:42:18,790 --> 00:42:24,270
+أسهل لو إجوا اتنينأصعب شوية لو إيجي واحد إذا .. لو
+
+461
+00:42:24,270 --> 00:42:27,770
+أنا بدي أقارن مركّب عليه تلت ذرات floor مع مركّب
+
+462
+00:42:27,770 --> 00:42:30,930
+عليه تنتين مع مركّب عليه واحدة مين بدي يكون فيهم
+
+463
+00:42:30,930 --> 00:42:34,270
+الحامض الأقوى؟ اللي تلاتة لأن في تلاتة جاعدين
+
+464
+00:42:34,270 --> 00:42:39,610
+بيساعدوا بحمل الشحنة السالبة واضح؟ لحظوا هذه أفكار
+
+465
+00:42:39,610 --> 00:42:43,290
+.. هذا هو ال inductive effect هذا ال effect هو إيش
+
+466
+00:42:43,290 --> 00:42:46,890
+بنسميه إحنا؟ ال inductive effect يعني تأثير
+
+467
+00:42:46,890 --> 00:42:55,350
+المساعدةمن خلال مجموعات ساحبة للإلكترونات طبعا هذا
+
+468
+00:42:55,350 --> 00:42:59,930
+ممكن يصير بالنسبة لي سؤال بالصح والغلط أنه يا ترى
+
+469
+00:42:59,930 --> 00:43:04,810
+المجموعة الساحبة للإلكترونات ماذا تعمل بالشحنة
+
+470
+00:43:04,810 --> 00:43:10,690
+السالبة تنقصها إذا تزيد الثبات وتزيد الحامضية طب
+
+471
+00:43:10,690 --> 00:43:16,710
+تخيلوا بقدرة جادر لو بني آدم زي ما بيقول المثل إيه
+
+472
+00:43:16,710 --> 00:43:23,500
+جاي كحلهاعماها بدل ما يحط تلت مجموعات مساعدة تحمل
+
+473
+00:43:23,500 --> 00:43:28,100
+حط تلاتة تزيد الحمل عارفين زي إيش؟ زي الأم الصغيرة
+
+474
+00:43:28,100 --> 00:43:30,780
+اللي شارية شغلة من السوق الأم اللي شارية شغلة من
+
+475
+00:43:30,780 --> 00:43:34,380
+السوق وتعبانة بحملها ومعها تلت ولادة وكل ولد بيحط
+
+476
+00:43:34,380 --> 00:43:41,320
+تجله على إيدها بتصير مش جارة الشغلة الشغلة و التلت
+
+477
+00:43:41,320 --> 00:43:45,480
+ولادة بتشوفوا كيف مهدودة وجه تسار التأثير إيش
+
+478
+00:43:45,480 --> 00:43:52,360
+ماله؟ عكسييعني لو هذه المجموعة بطلت ساحبة صارت
+
+479
+00:43:52,360 --> 00:43:57,060
+مجموعة معطية للإلكترونات وجدت إيش بدها تعمل
+
+480
+00:43:57,060 --> 00:44:00,400
+بالشحنة السالبة؟ بدها تزيدها، شو بتتوقع يصير في
+
+481
+00:44:00,400 --> 00:44:05,420
+الحامضية؟ اتقل، عشان هيك لو اطلعت مثلا هذا المثال
+
+482
+00:44:05,420 --> 00:44:06,680
+اللي فيه CH3
+
+483
+00:44:09,570 --> 00:44:13,210
+CH3O- اللي جاي من ال tertiary butyl alcohol
+
+484
+00:44:13,210 --> 00:44:16,690
+اتطلعوا في الجدول كداش ال tertiary butyl alcohol
+
+485
+00:44:16,690 --> 00:44:27,270
+عندكم محتوى 18 اقل اقل في الحمضية ولا لأ ايش السبب
+
+486
+00:44:27,270 --> 00:44:34,680
+ان هذه المجموعاتبتعطي إلكترونات electron donating
+
+487
+00:44:34,680 --> 00:44:40,080
+مش electron with a drawing الكلور بسبب سليبيته
+
+488
+00:44:40,080 --> 00:44:48,280
+بيسحب إلكترونات واضح المثل بيعطي إلكترونات وعشان
+
+489
+00:44:48,280 --> 00:44:52,640
+هيك هذا المركب يعني خلينا نعمل مرجعيتنا الاثانول
+
+490
+00:44:52,640 --> 00:45:02,070
+مشجولة حوالي 15.9 هذا المركب 18 أضعف هذا المركب12
+
+491
+00:45:02,070 --> 00:45:09,070
+أقوى واضح كيف التأثير انه انا لو اجيت اقارن هذه
+
+492
+00:45:09,070 --> 00:45:13,630
+المركبات المتشابهة هنا عندي تقليل الشحنة السالبة
+
+493
+00:45:13,630 --> 00:45:19,650
+معناها زيادة حمضية هنا عندي تركيز او intensifying
+
+494
+00:45:19,650 --> 00:45:25,720
+او زيادة الشحنة السالبة معناهاتقليل حمضية هذا ال
+
+495
+00:45:25,720 --> 00:45:28,920
+inductive effect بوجهينه ما هو ايه؟ في ناس
+
+496
+00:45:28,920 --> 00:45:33,820
+بيساعدوا بالموجب و في ناس بيساعدوا بالسالب واضح؟
+
+497
+00:45:33,820 --> 00:45:36,320
+تماما زي المثال الحكيناه، ناس بيجوا بيساعدوه و
+
+498
+00:45:36,320 --> 00:45:40,760
+بيحملوا مع البني آدم و ناس .. جيبناك يا عبد المعين
+
+499
+00:45:40,760 --> 00:45:47,160
+اتعين لجناك بدك؟ معين واضح؟ هنا التأثير سلبي، هنا
+
+500
+00:45:47,160 --> 00:45:54,420
+التأثير إيجابيواضح الفكرة؟ اذا اخر شيء باختم اليوم
+
+501
+00:45:54,420 --> 00:45:57,660
+بعدك بتصير الأمثلة كل اللي في ال slides اللي
+
+502
+00:45:57,660 --> 00:46:02,960
+بنحكيه بتجيجتين خلاص فينا المبادئ مفهوم الحامضية
+
+503
+00:46:02,960 --> 00:46:06,600
+مرتبط بالشحنة السالبة إنها تجل الشحنة السالبة اللي
+
+504
+00:46:06,600 --> 00:46:12,500
+بيجللها تلت أشياء ال size الأكبر ال resonance
+
+505
+00:46:12,500 --> 00:46:19,240
+الأكتر وال inductive effect الساحبلاحظوا عند كلمة
+
+506
+00:46:19,240 --> 00:46:24,260
+ال inductive effect ال inductive effect نوعين فى
+
+507
+00:46:24,260 --> 00:46:28,200
+inductive effect ساحب و inductive effect معطى ال
+
+508
+00:46:28,200 --> 00:46:33,100
+inductive effect الساحب هو اللى بيزيد الحامضية ال
+
+509
+00:46:33,100 --> 00:46:37,760
+inductive effect المعطى هو اللى بيقلل الحامضية إذا
+
+510
+00:46:37,760 --> 00:46:42,040
+صار عندى electron إيش معنى ساحب بالإنقليزة with a
+
+511
+00:46:42,040 --> 00:46:49,840
+drawing يسحب و إيش معنى معطىdonating donation
+
+512
+00:46:49,840 --> 00:46:56,080
+اعطار أو releasing electron donating electron
+
+513
+00:46:56,080 --> 00:47:00,240
+releasing هذا بيقلل الحمضية electron withdrawing
+
+514
+00:47:00,240 --> 00:47:04,740
+بيزيد الحمضية بنختم عند هذه اللحظة
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/deKbe0lopF8_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/deKbe0lopF8_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..a06edd19fb44e491212b9dcf2d41eae9c2b33efe
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/deKbe0lopF8_raw.json
@@ -0,0 +1 @@
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"text": "زي ما أتيت هنا وأخدت مركز القوة هذا تعالي ناخد مركز القوة الـ H Plus", "tokens": [11622, 1829, 19446, 5551, 31371, 2655, 34105, 36725, 9778, 3215, 2655, 3714, 31747, 11622, 25062, 2407, 3660, 23758, 37279, 6027, 1829, 8717, 47283, 3215, 3714, 31747, 11622, 25062, 2407, 3660, 2423, 39184, 389, 7721], "avg_logprob": -0.3888392874172756, "compression_ratio": 1.2857142857142858, "no_speech_prob": 0.0, "words": [{"start": 397.76, "end": 398.74, "word": "زي", "probability": 0.621826171875}, {"start": 398.74, "end": 398.86, "word": " ما", "probability": 0.82080078125}, {"start": 398.86, "end": 399.34, "word": " أتيت", "probability": 0.589599609375}, {"start": 399.34, "end": 399.56, "word": " هنا", "probability": 0.7333984375}, {"start": 399.56, "end": 400.14, "word": " وأخدت", "probability": 0.7818603515625}, {"start": 400.14, "end": 400.66, "word": " مركز", "probability": 0.9484049479166666}, {"start": 400.66, "end": 401.22, "word": " القوة", "probability": 0.9742838541666666}, 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Lewis هو H بلس", "tokens": [6027, 39184, 13931, 12, 6156, 4117, 33456, 3224, 5551, 9778, 1211, 2655, 9154, 23758, 25724, 11622, 38207, 16247, 3794, 32277, 1829, 8978, 3224, 4032, 27842, 23758, 25724, 11622, 38207, 16247, 3794, 32277, 1829, 8978, 3224, 13672, 1829, 39896, 11331, 38436, 28671, 2423, 39184, 2533, 17437, 299, 5367, 37495, 22653, 29538, 45164, 6225, 42213, 2655, 5296, 11296, 2533, 17437, 299, 5367, 2423, 39184, 6056, 16070, 39184, 2033, 28242, 16095, 9154, 13412, 9566, 3555, 3224, 39896, 6225, 3555, 9640, 3660, 18871, 389, 4724, 1211, 3794, 30767, 16373, 3215, 13931, 12, 39894, 3615, 9566, 1829, 8315, 389, 17, 46, 46599, 1863, 16606, 15844, 29910, 23275, 2423, 8258, 43242, 17412, 31439, 389, 4724, 1211, 3794], "avg_logprob": -0.21372767670878343, "compression_ratio": 1.6722689075630253, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 409.96, "end": 410.28, "word": "الـ", "probability": 0.52587890625}, {"start": 410.28, "end": 410.44, "word": " OH", 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chlorination of aromatic compounds occurs by using Cl2 with a Lewis acid", "tokens": [3555, 39237, 8978, 49610, 23328, 2423, 479, 8140, 43, 18, 34051, 16247, 19528, 22653, 20498, 33251, 1211, 13063, 25708, 6024, 48506, 33688, 1863, 3794, 7649, 3714, 16758, 3215, 2407, 8592, 7251, 4117, 2655, 3555, 479, 8140, 43, 18, 34051, 16247, 19528, 22653, 20498, 33251, 1211, 13063, 25708, 4724, 1829, 39648, 4724, 3555, 3794, 41193, 3660, 264, 18178, 2486, 295, 45831, 21810, 11843, 538, 1228, 2033, 17, 365, 257, 17412, 8258], "avg_logprob": -0.2845510462640037, "compression_ratio": 1.4615384615384615, "no_speech_prob": 0.0, "words": [{"start": 568.23, "end": 568.67, "word": "بتم", "probability": 0.5018310546875}, {"start": 568.67, "end": 568.85, "word": " في", "probability": 0.90283203125}, {"start": 568.85, "end": 569.27, "word": " وجود", "probability": 0.986083984375}, {"start": 569.27, "end": 569.41, "word": " ال", "probability": 0.481201171875}, {"start": 569.41, "end": 570.67, "word": " 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{"id": 43, "seek": 97454, "start": 958.72, "end": 974.54, "text": "من الأقوى ال HB، ليش؟ لأن هذا المقدار أكبر من هذا المقدار، إذا احنا هنا اتفقنا أن هذا الأقوى، الآن لما اتفقنا أن هذا الأقوى، لو سألنا طالب، ليش هذا أقوى؟", "tokens": [27842, 16247, 4587, 2407, 7578, 2423, 389, 33, 12399, 32239, 8592, 22807, 5296, 33456, 23758, 9673, 28543, 9640, 5551, 4117, 26890, 9154, 23758, 9673, 28543, 9640, 12399, 11933, 15730, 1975, 5016, 8315, 34105, 1975, 2655, 5172, 4587, 8315, 14739, 23758, 16247, 4587, 2407, 7578, 12399, 6024, 48506, 5296, 15042, 1975, 2655, 5172, 4587, 8315, 14739, 23758, 16247, 4587, 2407, 7578, 12399, 45164, 8608, 10721, 1211, 8315, 23032, 6027, 3555, 12399, 32239, 8592, 23758, 5551, 4587, 2407, 7578, 22807], "avg_logprob": -0.16030458709861659, "compression_ratio": 2.044776119402985, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 958.72, "end": 959.1, "word": "من", "probability": 0.8720703125}, {"start": 959.1, "end": 959.78, "word": " الأقوى", 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ممكن اعتبرها كأن أبسط كحول هنا قلت H O R وهنا H O H يعني كأن ال R هذه H عشان هي أبسط إيش", "tokens": [40228, 22653, 45164, 5551, 9778, 3215, 2655, 8717, 36178, 29538, 9673, 3615, 18513, 37977, 9673, 10632, 9122, 35571, 11242, 389, 422, 389, 20193, 5016, 19913, 14407, 5296, 15042, 9673, 25720, 9673, 46958, 10632, 12174, 1211, 2655, 23275, 14407, 14739, 9673, 10632, 6156, 1211, 3794, 5172, 25528, 3714, 43020, 1975, 34268, 26890, 11296, 9122, 33456, 5551, 3555, 3794, 9566, 9122, 5016, 12610, 34105, 12174, 1211, 2655, 389, 422, 497, 37037, 8315, 389, 422, 389, 37495, 22653, 9122, 33456, 2423, 497, 29538, 389, 6225, 8592, 7649, 39896, 5551, 3555, 3794, 9566, 11933, 1829, 8592], "avg_logprob": -0.20010080388797227, "compression_ratio": 1.8, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1302.43, "end": 1302.83, "word": "يعني", "probability": 0.9208984375}, {"start": 1302.83, "end": 1302.93, "word": " لو", "probability": 0.6865234375}, {"start": 1302.93, "end": 1303.27, "word": 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1314.67, "word": " H", "probability": 0.8681640625}, {"start": 1314.67, "end": 1316.11, "word": " O", "probability": 0.63671875}, {"start": 1316.11, "end": 1316.89, "word": " R", "probability": 0.98681640625}, {"start": 1316.89, "end": 1317.65, "word": " وهنا", "probability": 0.7371826171875}, {"start": 1317.65, "end": 1318.13, "word": " H", "probability": 0.94140625}, {"start": 1318.13, "end": 1318.81, "word": " O", "probability": 0.96826171875}, {"start": 1318.81, "end": 1319.83, "word": " H", "probability": 0.953125}, {"start": 1319.83, "end": 1320.23, "word": " يعني", "probability": 0.936279296875}, {"start": 1320.23, "end": 1320.49, "word": " كأن", "probability": 0.98486328125}, {"start": 1320.49, "end": 1320.63, "word": " ال", "probability": 0.75244140625}, {"start": 1320.63, "end": 1320.85, "word": " R", "probability": 0.87353515625}, {"start": 1320.85, "end": 1321.29, "word": " هذه", "probability": 0.56591796875}, {"start": 1321.29, "end": 1322.03, "word": " H", "probability": 0.85400390625}, {"start": 1322.03, "end": 1322.35, "word": " عشان", "probability": 0.9378255208333334}, {"start": 1322.35, "end": 1322.51, "word": " هي", "probability": 0.51220703125}, {"start": 1322.51, "end": 1323.11, "word": " أبسط", "probability": 0.9749755859375}, {"start": 1323.11, "end": 1323.49, "word": " إيش", "probability": 0.8138020833333334}], "temperature": 1.0}, {"id": 59, "seek": 135238, "start": 1324.62, "end": 1352.38, "text": "أبسط الكحولات فلسفيا زائد H2O هيعطينا HO minus زائد H3O plus وهذا تفاعل اتزار معروف بالنسبة لنا في كتب الكيميا اذا H2O كأن واحد منها اتعمل كحمض فقد H plus التاني اتعمل ك base اكتسب H plus واضح الفكرة؟", "tokens": [10721, 3555, 3794, 9566, 33251, 5016, 12610, 9307, 6156, 1211, 3794, 5172, 25528, 30767, 16373, 3215, 389, 17, 46, 39896, 3615, 9566, 1829, 8315, 23097, 3175, 30767, 16373, 3215, 389, 18, 46, 1804, 37037, 15730, 6055, 5172, 995, 30241, 1975, 2655, 11622, 9640, 20449, 32887, 5172, 20666, 1863, 35457, 3660, 5296, 8315, 8978, 9122, 2655, 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"text": "الحجم الكبير أقدر على حمل الشحنة الحجم الكبير أقدر على حمل الشحنة الآن خليني أجي لل resonance و بدي أقارن أنا الاثانول مع حمض الخلق لاحظوا الاثانول إيش صيبته؟", "tokens": [6027, 5016, 7435, 2304, 33251, 3555, 13546, 5551, 28543, 2288, 15844, 11331, 42213, 25124, 5016, 1863, 3660, 21542, 7435, 2304, 33251, 3555, 13546, 5551, 28543, 2288, 15844, 11331, 42213, 25124, 5016, 1863, 3660, 6024, 48506, 16490, 1211, 9957, 1829, 5551, 7435, 1829, 24976, 30944, 4032, 4724, 16254, 5551, 4587, 9640, 1863, 41850, 2423, 5718, 104, 7649, 12610, 20449, 11331, 2304, 11242, 33962, 1211, 4587, 20193, 5016, 19913, 14407, 2423, 5718, 104, 7649, 12610, 11933, 1829, 8592, 20328, 1829, 3555, 47395, 22807], "avg_logprob": -0.19588413998121168, "compression_ratio": 1.8355263157894737, "no_speech_prob": 0.0, "words": [{"start": 2279.42, "end": 2280.0, "word": "الحجم", "probability": 0.974365234375}, {"start": 2280.0, "end": 2280.54, "word": " الكبير", "probability": 0.9860026041666666}, {"start": 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{"start": 2289.62, "end": 2290.06, "word": " أجي", "probability": 0.8321940104166666}, {"start": 2290.06, "end": 2290.4, "word": " لل", "probability": 0.89794921875}, {"start": 2290.4, "end": 2291.06, "word": " resonance", "probability": 0.740234375}, {"start": 2291.06, "end": 2292.28, "word": " و", "probability": 0.580078125}, {"start": 2292.28, "end": 2292.5, "word": " بدي", "probability": 0.5706787109375}, {"start": 2292.5, "end": 2293.04, "word": " أقارن", "probability": 0.9600830078125}, {"start": 2293.04, "end": 2293.3, "word": " أنا", "probability": 0.418212890625}, {"start": 2293.3, "end": 2293.96, "word": " الاثانول", "probability": 0.733056640625}, {"start": 2293.96, "end": 2294.22, "word": " مع", "probability": 0.372314453125}, {"start": 2294.22, "end": 2294.5, "word": " حمض", "probability": 0.88330078125}, {"start": 2294.5, "end": 2295.52, "word": " الخلق", "probability": 0.8802083333333334}, {"start": 2295.52, "end": 2296.26, "word": " لاحظوا", "probability": 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"compression_ratio": 1.5067567567567568, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2298.53, "end": 2299.77, "word": "CH3", "probability": 0.695068359375}, {"start": 2299.77, "end": 2301.55, "word": " CH2", "probability": 0.7470703125}, {"start": 2301.55, "end": 2303.17, "word": " OH", "probability": 0.890625}, {"start": 2303.17, "end": 2304.01, "word": " وحمض", "probability": 0.56396484375}, {"start": 2304.01, "end": 2304.51, "word": " الخلب", "probability": 0.7149658203125}, {"start": 2304.51, "end": 2306.49, "word": " CH3", "probability": 0.96240234375}, {"start": 2306.49, "end": 2307.29, "word": " C", "probability": 0.630859375}, {"start": 2307.29, "end": 2307.93, "word": " O", "probability": 0.047149658203125}, {"start": 2307.93, "end": 2309.97, "word": " OH", "probability": 0.51025390625}, {"start": 2309.97, "end": 2310.75, "word": " الآن", "probability": 0.5819091796875}, {"start": 2310.75, "end": 2311.63, "word": " اتفقنا", "probability": 0.93154296875}, {"start": 2311.63, "end": 2311.93, "word": " انه", "probability": 0.705810546875}, {"start": 2311.93, "end": 2312.09, "word": " لما", "probability": 0.929443359375}, {"start": 2312.09, "end": 2312.39, "word": " بدنا", "probability": 0.81591796875}, {"start": 2312.39, "end": 2312.97, "word": " نقارن", "probability": 0.9940185546875}, {"start": 2312.97, "end": 2313.55, "word": " ال", "probability": 0.76513671875}, {"start": 2313.55, "end": 2313.75, "word": " H", "probability": 0.90234375}, {"start": 2313.75, "end": 2314.27, "word": " Plus", "probability": 0.1453857421875}, {"start": 2314.27, "end": 2315.47, "word": " مش", "probability": 0.85205078125}, {"start": 2315.47, "end": 2316.29, "word": " لازماني", "probability": 0.84873046875}, {"start": 2316.29, "end": 2317.13, "word": " بدي", "probability": 0.59637451171875}, {"start": 2317.13, "end": 2317.85, "word": " اشيلها", "probability": 0.86456298828125}, {"start": 2317.85, "end": 2318.13, "word": " و", "probability": 0.73193359375}, {"start": 2318.13, "end": 2318.39, "word": " بده", "probability": 0.4178466796875}, {"start": 2318.39, "end": 2318.85, "word": " اقارن", "probability": 0.982421875}, {"start": 2318.85, "end": 2319.01, "word": " ال", "probability": 0.57177734375}, {"start": 2319.01, "end": 2319.69, "word": " Ion", "probability": 0.576171875}, {"start": 2319.69, "end": 2321.67, "word": " السالب", "probability": 0.8639322916666666}, {"start": 2321.67, "end": 2321.91, "word": " و", "probability": 0.7119140625}, {"start": 2321.91, "end": 2322.43, "word": " Ion", "probability": 0.90966796875}, {"start": 2322.43, "end": 2323.31, "word": " السالب", "probability": 0.9718424479166666}, {"start": 2323.31, "end": 2325.65, "word": " واضح؟", "probability": 0.88818359375}], "temperature": 1.0}, {"id": 102, "seek": 234567, "start": 2326.87, "end": 2345.67, "text": "الان هتلاحظوا هنا ال ايون السالب هذا موجود على ال oxygen مش قادر يتحرك يعني هذا أشبه البني ادم معه حمل بس إيده التانية مقطوعة طول الطريق هيضله إيش؟ حامل الشحن السالب على هذا ال oxygen هذا لأ له اتين", "tokens": [6027, 7649, 8032, 2655, 15040, 5016, 19913, 14407, 34105, 2423, 1975, 1829, 11536, 21136, 6027, 3555, 23758, 3714, 29245, 23328, 15844, 2423, 9169, 37893, 12174, 18513, 2288, 7251, 2655, 5016, 31747, 37495, 22653, 23758, 5551, 8592, 3555, 3224, 29739, 22653, 1975, 40448, 20449, 3224, 11331, 42213, 4724, 3794, 11933, 25708, 3224, 16712, 7649, 10632, 3714, 47432, 2407, 27884, 23032, 12610, 41950, 16572, 4587, 39896, 11242, 1211, 3224, 11933, 1829, 8592, 22807, 11331, 10943, 1211, 25124, 5016, 1863, 21136, 6027, 3555, 15844, 23758, 2423, 9169, 23758, 5296, 10721, 46740, 1975, 2655, 9957], "avg_logprob": -0.2131453870755175, "compression_ratio": 1.7692307692307692, "no_speech_prob": 0.0, "words": [{"start": 2326.8699999999994, "end": 2327.6299999999997, "word": "الان", "probability": 0.791015625}, {"start": 2327.6299999999997, "end": 2328.39, "word": " هتلاحظوا", "probability": 0.8361409505208334}, {"start": 2328.39, "end": 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"end": 2338.71, "word": " الطريق", "probability": 0.9830729166666666}, {"start": 2338.71, "end": 2339.19, "word": " هيضله", "probability": 0.5726318359375}, {"start": 2339.19, "end": 2340.17, "word": " إيش؟", "probability": 0.75799560546875}, {"start": 2340.17, "end": 2340.85, "word": " حامل", "probability": 0.9736328125}, {"start": 2340.85, "end": 2341.99, "word": " الشحن", "probability": 0.9637044270833334}, {"start": 2341.99, "end": 2342.49, "word": " السالب", "probability": 0.9305013020833334}, {"start": 2342.49, "end": 2342.71, "word": " على", "probability": 0.8896484375}, {"start": 2342.71, "end": 2342.97, "word": " هذا", "probability": 0.490966796875}, {"start": 2342.97, "end": 2343.09, "word": " ال", "probability": 0.84912109375}, {"start": 2343.09, "end": 2343.55, "word": " oxygen", "probability": 0.83154296875}, {"start": 2343.55, "end": 2344.51, "word": " هذا", "probability": 0.7841796875}, {"start": 2344.51, "end": 2344.79, "word": " لأ", "probability": 0.901611328125}, {"start": 2344.79, "end": 2345.09, "word": " له", "probability": 0.1824951171875}, {"start": 2345.09, "end": 2345.67, "word": " اتين", "probability": 0.7947591145833334}], "temperature": 1.0}, {"id": 103, "seek": 237259, "start": 2346.69, "end": 2372.59, "text": "بناء على ذلك هذا ممكن يعمل resonance بمعنى أن هذه تتحرك هنا وهذه تيجي هنا لاحظوا هذا ال resonance حركة الإلكترونات متذكرين لما أخدناها CH3 سيصبح CH3 وهذه تصبح double bond O وهنا ال O minus إذا ال minus أين صارت محمولة مرة على ال oxygen هذه ومرة على هذه", "tokens": [3555, 1863, 16606, 15844, 29910, 23275, 23758, 3714, 43020, 7251, 25957, 1211, 30944, 4724, 2304, 3615, 1863, 7578, 14739, 29538, 6055, 2655, 5016, 31747, 34105, 37037, 24192, 6055, 1829, 7435, 1829, 34105, 20193, 5016, 19913, 14407, 23758, 2423, 30944, 11331, 31747, 3660, 33688, 23275, 2655, 2288, 11536, 9307, 44650, 8848, 37983, 9957, 5296, 15042, 5551, 9778, 3215, 8315, 11296, 5995, 18, 8608, 1829, 9381, 49628, 5995, 18, 37037, 24192, 6055, 9381, 49628, 3834, 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2356.07, "end": 2356.83, "word": " الإلكترونات", "probability": 0.8289388020833334}, {"start": 2356.83, "end": 2357.39, "word": " متذكرين", "probability": 0.85107421875}, {"start": 2357.39, "end": 2357.53, "word": " لما", "probability": 0.7734375}, {"start": 2357.53, "end": 2358.21, "word": " أخدناها", "probability": 0.91455078125}, {"start": 2358.21, "end": 2360.47, "word": " CH3", "probability": 0.57440185546875}, {"start": 2360.47, "end": 2361.39, "word": " سيصبح", "probability": 0.667572021484375}, {"start": 2361.39, "end": 2361.67, "word": " CH3", "probability": 0.70361328125}, {"start": 2361.67, "end": 2362.05, "word": " وهذه", "probability": 0.5052490234375}, {"start": 2362.05, "end": 2362.47, "word": " تصبح", "probability": 0.68408203125}, {"start": 2362.47, "end": 2362.73, "word": " double", "probability": 0.4296875}, {"start": 2362.73, "end": 2363.09, "word": " bond", "probability": 0.9267578125}, {"start": 2363.09, "end": 2363.35, "word": " O", "probability": 0.857421875}, 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2794.92, "word": " المعطى", "probability": 0.9573974609375}, {"start": 2794.92, "end": 2795.44, "word": " هو", "probability": 0.96630859375}, {"start": 2795.44, "end": 2795.66, "word": " اللى", "probability": 0.979736328125}, {"start": 2795.66, "end": 2796.32, "word": " بيقلل", "probability": 0.89462890625}, {"start": 2796.32, "end": 2797.18, "word": " الحامضية", "probability": 0.98974609375}, {"start": 2797.18, "end": 2797.76, "word": " إذا", "probability": 0.722412109375}, {"start": 2797.76, "end": 2798.08, "word": " صار", "probability": 0.93505859375}, {"start": 2798.08, "end": 2798.54, "word": " عندى", "probability": 0.867919921875}, {"start": 2798.54, "end": 2799.26, "word": " electron", "probability": 0.80322265625}, {"start": 2799.26, "end": 2799.56, "word": " إيش", "probability": 0.77978515625}, {"start": 2799.56, "end": 2799.88, "word": " معنى", "probability": 0.8880208333333334}, {"start": 2799.88, "end": 2800.24, "word": " ساحب", "probability": 0.98681640625}, {"start": 2800.24, "end": 2801.0, "word": " بالإنقليزة", "probability": 0.8647809709821429}, {"start": 2801.0, "end": 2801.86, "word": " with", "probability": 0.43603515625}, {"start": 2801.86, "end": 2802.04, "word": " a", "probability": 0.884765625}, {"start": 2802.04, "end": 2802.88, "word": " drawing", "probability": 0.8740234375}, {"start": 2802.88, "end": 2805.08, "word": " يسحب", "probability": 0.957763671875}, {"start": 2805.08, "end": 2805.4, "word": " و", "probability": 0.794921875}, {"start": 2805.4, "end": 2805.62, "word": " إيش", "probability": 0.8766276041666666}, {"start": 2805.62, "end": 2805.92, "word": " معنى", "probability": 0.9723307291666666}, {"start": 2805.92, "end": 2806.44, "word": " معطى", "probability": 0.98974609375}], "temperature": 1.0}, {"id": 121, "seek": 282474, "start": 2807.24, "end": 2824.74, "text": "donating donation اعطار أو releasing electron donating electron releasing هذا بيقلل الحمضية electron withdrawing بيزيد الحمضية بنختم عند هذه اللحظة", "tokens": [13966, 990, 19724, 1975, 3615, 9566, 9640, 34051, 16327, 6084, 36686, 6084, 16327, 23758, 4724, 1829, 4587, 1211, 1211, 21542, 2304, 11242, 10632, 6084, 14999, 278, 4724, 1829, 11622, 25708, 21542, 2304, 11242, 10632, 44945, 9778, 39237, 43242, 29538, 13672, 5016, 19913, 3660], "avg_logprob": -0.2666903442957185, "compression_ratio": 1.4558823529411764, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2807.24, "end": 2808.36, "word": "donating", "probability": 0.3900146484375}, {"start": 2808.36, "end": 2809.84, "word": " donation", "probability": 0.1771240234375}, {"start": 2809.84, "end": 2810.76, "word": " اعطار", "probability": 0.80316162109375}, {"start": 2810.76, "end": 2812.9, "word": " أو", "probability": 0.359130859375}, {"start": 2812.9, "end": 2813.68, "word": " releasing", "probability": 0.78759765625}, {"start": 2813.68, "end": 2814.9, "word": " electron", "probability": 0.62548828125}, {"start": 2814.9, "end": 2815.56, "word": " donating", "probability": 0.79443359375}, {"start": 2815.56, "end": 2816.08, "word": " electron", "probability": 0.501953125}, {"start": 2816.08, "end": 2816.74, "word": " releasing", "probability": 0.9423828125}, {"start": 2816.74, "end": 2817.34, "word": " هذا", "probability": 0.80419921875}, {"start": 2817.34, "end": 2817.88, "word": " بيقلل", "probability": 0.888671875}, {"start": 2817.88, "end": 2818.42, "word": " الحمضية", "probability": 0.9051513671875}, {"start": 2818.42, "end": 2819.12, "word": " electron", "probability": 0.91357421875}, {"start": 2819.12, "end": 2820.24, "word": " withdrawing", "probability": 0.732177734375}, {"start": 2820.24, "end": 2821.5, "word": " بيزيد", "probability": 0.83758544921875}, {"start": 2821.5, "end": 2822.54, "word": " الحمضية", "probability": 0.9910888671875}, {"start": 2822.54, "end": 2823.46, "word": " بنختم", "probability": 0.7596028645833334}, {"start": 2823.46, "end": 2823.94, "word": " عند", "probability": 0.96630859375}, {"start": 2823.94, "end": 2824.16, "word": " هذه", "probability": 0.8291015625}, {"start": 2824.16, "end": 2824.74, "word": " اللحظة", "probability": 0.99072265625}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2825.1255, "duration_after_vad": 2728.468749999992}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/di-xbM-HbNU_raw.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/di-xbM-HbNU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..113e6db8580a7a6a78dd7c4cdb91328115f59e55
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/di-xbM-HbNU_raw.srt
@@ -0,0 +1,2096 @@
+1
+00:00:18,700 --> 00:00:22,900
+بسم الله الرحمن الرحيم، اليوم ان شاء الله هنبتدأ
+
+2
+00:00:22,900 --> 00:00:28,300
+الفصل الأخير في ال course اللي بأمل أن نكون يعني
+
+3
+00:00:28,300 --> 00:00:32,740
+استفدنا منه واستمتعنا فيه على مدى ثلاث أو أربع
+
+4
+00:00:32,740 --> 00:00:38,220
+شهور course الكيمياء الأضوية العامة والكيمياء يعني
+
+5
+00:00:38,220 --> 00:00:43,140
+مقدمة في الكيمياء الحيوية العامةالفصل هذا بعنوان
+
+6
+00:00:43,140 --> 00:00:49,360
+amino acids, peptides and proteins، طبعا هو مش تلت
+
+7
+00:00:49,360 --> 00:00:56,860
+عنوين، لأهي ال amino acids الأحماض الأمينية الوحدة
+
+8
+00:00:56,860 --> 00:01:02,640
+البسيطة إذا اتحد عندي عدد قليل من ال amino acids
+
+9
+00:01:02,640 --> 00:01:07,080
+بيعملوا ال peptides يعني أربعة، خمسة، عشرة، خمس،
+
+10
+00:01:07,080 --> 00:01:12,280
+تعش هدولة بيعملوا ال peptides الآن إذا صاروا بال
+
+11
+00:01:12,280 --> 00:01:17,880
+آلاف وأحيانا بعشرات الآلاف بصير الجزء كبير جدا
+
+12
+00:01:17,880 --> 00:01:23,530
+بنسمي إيش ال proteinفالبروتين الان كبير جدا لو بده
+
+13
+00:01:23,530 --> 00:01:28,690
+يتكسر بالعكس هيتكسر لpeptides و ال peptides لو
+
+14
+00:01:28,690 --> 00:01:34,670
+بدها تتكسر هتتكسر ل amino acids فالوحدة الأساسية
+
+15
+00:01:34,670 --> 00:01:42,480
+هتكون ال aminoو لذلك أمر طبيعي جدا ان نبدأ الفصل
+
+16
+00:01:42,480 --> 00:01:47,900
+هذا ان نتعرف على ال amino acids معنى amino acids
+
+17
+00:01:47,900 --> 00:01:54,220
+أحماض عضوية عادية لكن فيها مجموعة الأمين بشكل عام
+
+18
+00:01:54,220 --> 00:02:01,940
+مجموعة ال NH2 الآن من الناحية النظرية البحثة لو
+
+19
+00:02:01,940 --> 00:02:08,870
+انا بحكي عن حامض عضويوفي مجموعة امين معنا ذلك بقدر
+
+20
+00:02:08,870 --> 00:02:14,250
+اتوقع ان يكون عندى عدد لا نهائى من ال amino acids
+
+21
+00:02:14,250 --> 00:02:20,070
+واضح يعني لو بدى اقول قداش العدد النظري المتوقع من
+
+22
+00:02:20,070 --> 00:02:23,910
+ال amino acids لما انا اجي اقول هاي مجموعة الحامض
+
+23
+00:02:23,910 --> 00:02:29,470
+سيضة بال bond O OH و بعدين احط هنا carbons
+
+24
+00:02:31,380 --> 00:02:36,140
+الان حسب ما يكون في عندى و الله اذا في هنا مجموعة
+
+25
+00:02:36,140 --> 00:02:40,920
+amino ممكن يكون هنا مجموعة amino هنا هنا لاحظوا
+
+26
+00:02:40,920 --> 00:02:44,000
+معنى بتيجي نقطة كتير مهمه ان انا لما بحط amino
+
+27
+00:02:44,000 --> 00:02:50,200
+بكون في عندي كمان R groups واضح فنظريا ال amino
+
+28
+00:02:50,200 --> 00:02:56,730
+acids اكترالان بنجيب نتطلع وين مجموعة الأمين
+
+29
+00:02:56,730 --> 00:03:02,030
+مجموعة ال N H2 والله إذا كانت هذه مجموعة الأمين
+
+30
+00:03:02,030 --> 00:03:06,470
+على أول carbon بعد ال C double bond O احنا اتعلمنا
+
+31
+00:03:06,470 --> 00:03:11,090
+ان هذا ال carbon هي ال alpha carbon لكن بالتأكيد
+
+32
+00:03:11,090 --> 00:03:14,410
+ممكن ماتكونش على أول carbon ممكن تكون على ثاني
+
+33
+00:03:14,410 --> 00:03:20,940
+carbonوأجد عن إيش هنحكي؟ Beta Amino Acids على اللي
+
+34
+00:03:20,940 --> 00:03:26,940
+بعدها Gamma Delta فال Amino Acids ال Amino Acids
+
+35
+00:03:26,940 --> 00:03:33,780
+بهذا المنطق اكتار الآن اللي موجودين في البروتينات
+
+36
+00:03:41,580 --> 00:03:45,360
+اللي موجودين في البروتينات تحديدا هم ال alpha
+
+37
+00:03:45,360 --> 00:03:50,400
+amino acids يعني اللي فيهم مجموعة الأمين على ال
+
+38
+00:03:50,400 --> 00:03:54,000
+carbon alpha و احنا سبق عرفنا ال carbon alpha بال
+
+39
+00:03:54,000 --> 00:03:57,220
+acids و بال aldehydes و بال ketones قلنا هي ال
+
+40
+00:03:57,220 --> 00:04:01,400
+carbon المجاورة لل seed of the bond O لو كنا بنعد
+
+41
+00:04:01,400 --> 00:04:05,280
+بال ayobac بتكون ال alpha carbon هي ال carbon رقم
+
+42
+00:04:05,280 --> 00:04:09,320
+اتنين لأن احنا بنعد في ال ayobac من ال seed of the
+
+43
+00:04:09,320 --> 00:04:15,360
+bond Oيعني فال amino group موجودة على ال carbon
+
+44
+00:04:15,360 --> 00:04:19,800
+رقم اتنين او على ال carbon الفة هذا الكلام في وين؟
+
+45
+00:04:19,800 --> 00:04:23,940
+في ال amino acids اللي موجودين في البروتينات لكن
+
+46
+00:04:23,940 --> 00:04:30,660
+لو قلنا لطالب في الامتحان الدروق general structure
+
+47
+00:04:30,660 --> 00:04:37,620
+for a beta amino acidهذا جيبنا سؤال مرة اوكي هي
+
+48
+00:04:37,620 --> 00:04:43,080
+انها C double bond O OH بنمشي بهذا الشكل هي alpha
+
+49
+00:04:43,080 --> 00:04:50,820
+هي beta اذا نحط ال amino group على ال carbon beta
+
+50
+00:04:50,820 --> 00:04:54,740
+هذا beta amino acid لو قلنا لغاها مابدوا يحطوا على
+
+51
+00:04:54,740 --> 00:04:59,400
+اللي بعدها واضح لكن اللي موجودين في البروتينات اي
+
+52
+00:04:59,400 --> 00:05:05,440
+نوع ال alpha amino acidsواضح؟ زي ما حكينا احنا ان
+
+53
+00:05:05,440 --> 00:05:10,080
+ال peptides عدت amino acids مع بعض و ال proteins
+
+54
+00:05:10,080 --> 00:05:16,040
+many amino acids مع بعض الان لما نيجي نكسر ال
+
+55
+00:05:16,040 --> 00:05:18,740
+protein زي ما قلنا ممكن يعطينا peptide و ال
+
+56
+00:05:18,740 --> 00:05:22,720
+peptide ممكن يكسره الوحدات الاولية هنصف بال ايش؟
+
+57
+00:05:22,720 --> 00:05:26,700
+بال amino acids الان هذه ال amino acids ايش
+
+58
+00:05:26,700 --> 00:05:30,960
+مواصفاتها؟ المواصفة الاولى ان كلهم الف amino acids
+
+59
+00:05:31,860 --> 00:05:36,960
+الشغل التاني ان ال amino acids اللي بيطلعوا عندنا
+
+60
+00:05:36,960 --> 00:05:41,840
+they are optically active يعني فيهم chiral center
+
+61
+00:05:41,840 --> 00:05:46,140
+ما عدا واحد بيكونوا فيه المجموعتين زي بعض يعني
+
+62
+00:05:46,140 --> 00:05:50,480
+مافيش فيه أربع مجموعات مختلفة هذا الواحد اللي
+
+63
+00:05:50,480 --> 00:05:54,940
+هنتعرف عليه هو ال glycine فباقي ال amino acids
+
+64
+00:05:54,940 --> 00:05:59,880
+كلهم they areoptically active they contain chiral
+
+65
+00:05:59,880 --> 00:06:05,380
+centers فيهم chiral centers الآن بيجينا شغلة طالما
+
+66
+00:06:05,380 --> 00:06:09,380
+بدنا نقول chiral center متذكرين لما اتكلمنا عن ال
+
+67
+00:06:09,380 --> 00:06:13,620
+sugars واستبدلنا المصطلح يعني في ال biochemistry
+
+68
+00:06:13,620 --> 00:06:19,940
+ال R و ال S ب D و L فلما اتكلمنا عن ال sugars احنا
+
+69
+00:06:19,940 --> 00:06:25,630
+اتفقنا ان نحط اعلى مجموعة للأعلى اللي هي مجموعةالـ
+
+70
+00:06:25,630 --> 00:06:29,650
+aldehyde بعدين ال sugars بيميزها على الكربون اللى
+
+71
+00:06:29,650 --> 00:06:33,630
+باقى ده H و OH و بعدين بنحط rest of the molecule
+
+72
+00:06:33,630 --> 00:06:40,090
+الآن إذا حطينا ال OH على اليمين كنا نقول في عندنا
+
+73
+00:06:40,090 --> 00:06:45,150
+D و إذا حطينا على الشمال كنا نقول في عندنا L الآن
+
+74
+00:06:45,150 --> 00:06:49,450
+بنفس المنطق بنعمل ال amino acids لكن شو المجموعة
+
+75
+00:06:49,450 --> 00:06:55,600
+اللى بنحطها لأعلى؟بدل ال الديهايد مجموعة الحامض
+
+76
+00:06:55,600 --> 00:06:59,860
+يعني ال amino acids في حامض برسم المجموعة الحامض
+
+77
+00:06:59,860 --> 00:07:04,420
+هذه لأعلى الآن بعد مجموعة الحامض ال carbon Alpha
+
+78
+00:07:04,420 --> 00:07:11,080
+متصلة ب H و متصلة ب NH2 و متصلة ب R group تاني
+
+79
+00:07:11,080 --> 00:07:14,960
+يعني هي بتميز و بتخلي عدد ال amino acids infinity
+
+80
+00:07:14,960 --> 00:07:19,780
+ليش أنا بقول العدد infinity يعني هذا الجزء CO2 H
+
+81
+00:07:19,780 --> 00:07:25,700
+ثابتالـ H ثابتة، الآن الـ H2 ثابتة، الآن الـ Amino
+
+82
+00:07:25,700 --> 00:07:30,600
+acid عن التاني بتغيره بإيش؟ بالـ R طالما في عندي
+
+83
+00:07:30,600 --> 00:07:36,110
+متغيّد، الـ R ممكن تكون عدد لا نهائيواضح ال R ممكن
+
+84
+00:07:36,110 --> 00:07:40,210
+تكون عدد لا نهاية الان احنا بنيجي بنرسم بهذا الشكل
+
+85
+00:07:40,210 --> 00:07:44,470
+عشان الكل يفهم على بعضه اذا حطينا ال N H2 على
+
+86
+00:07:44,470 --> 00:07:49,230
+اليمين بنقول هذا D Amino Acid اذا حطينا ال N H2
+
+87
+00:07:49,230 --> 00:07:54,890
+على اليسار بنقول هذا ايش ال Amino Acids الان ال
+
+88
+00:07:54,890 --> 00:07:59,770
+Amino Acids اللي بيطلعوا من ال proteins كلهم L مش
+
+89
+00:07:59,770 --> 00:08:07,980
+D هذا خلق اللههك ربنا خلقهم يعني لاحظوا أنه لما
+
+90
+00:08:07,980 --> 00:08:11,020
+بنيجي الحل للبروتين بنلاحظ أنه كل ال amino acids
+
+91
+00:08:11,020 --> 00:08:14,600
+اللي طلع عندنا Alpha amino acids وكل ال amino
+
+92
+00:08:14,600 --> 00:08:20,080
+acids اللي طلع عندنا ال amino acids واضح؟ الآن
+
+93
+00:08:20,080 --> 00:08:28,500
+بنيجي لنقطة تانية أنه طالما أن هذا ال R متغير
+
+94
+00:08:29,120 --> 00:08:32,920
+ممكن تاخد أي إشي أتش مثل إثالبروبيل إيزوبروبيل و
+
+95
+00:08:32,920 --> 00:08:37,160
+كبرو زي ما بدكم معناه ذلك من الناحية النظرية كده
+
+96
+00:08:37,160 --> 00:08:44,680
+اندي أمينو أسيد حتى ألفةعدد لانهائي لكن بالواقع
+
+97
+00:08:44,680 --> 00:08:48,680
+التجريبي لما بيعملوا hydrolysis ل ال proteins
+
+98
+00:08:48,680 --> 00:08:53,380
+وبيفصلوا ال amino acids اللي نشأت من تميق ال
+
+99
+00:08:53,380 --> 00:08:57,200
+protein و تكسره لوحدته الأولية لاحظوا ان في عندنا
+
+100
+00:08:57,200 --> 00:09:02,620
+عشرين amino acid هذا الكلام بسهل الشغل علينا يعني
+
+101
+00:09:02,620 --> 00:09:06,980
+تخيل لو كانوا الف و كل واحد بده تشخيص مشكلة لكن
+
+102
+00:09:08,010 --> 00:09:13,070
+بشكل عام كل بروتينات ملفة حوالين ال 20 amino acids
+
+103
+00:09:13,070 --> 00:09:20,010
+هدولة اللي بشكل عام موجودين في البروتينات الان من
+
+104
+00:09:20,010 --> 00:09:24,450
+هدولة ال amino acids العشرينعلى خلاف بسيط من
+
+105
+00:09:24,450 --> 00:09:29,330
+العلماء مش مشكلة خلّيني أتزم بالكلام في 12 amino
+
+106
+00:09:29,330 --> 00:09:33,530
+acid ممكن يتحضروا في الجسم يعني الإنسان ممكن
+
+107
+00:09:33,530 --> 00:09:38,390
+يحضرهم من نقطة السفر وفي 8 amino acids الجسم
+
+108
+00:09:38,390 --> 00:09:43,450
+بيحضرهمش طب هدولة اللي بيحضرهمش الجسم لازم ياخدهم
+
+109
+00:09:43,450 --> 00:09:48,890
+جاهزين من برا من وين هياخدهم؟ من الغذابةأنواع من
+
+110
+00:09:48,890 --> 00:09:52,750
+الغذاء فيها هذه ال amino acids الآن هدولة التمانية
+
+111
+00:09:52,750 --> 00:09:56,790
+amino acids that cannot be synthesized in the body
+
+112
+00:09:56,790 --> 00:10:00,610
+they are called essential amino acids الأحماض
+
+113
+00:10:00,610 --> 00:10:05,350
+الأمينية الأساسية فلما نقول إيش معنى essential
+
+114
+00:10:05,350 --> 00:10:09,730
+amino acids the amino acids that cannot be
+
+115
+00:10:09,730 --> 00:10:13,830
+synthesized in the body and must be obtained from
+
+116
+00:10:13,830 --> 00:10:18,390
+the dietin the form of protein لازم ناخدها من
+
+117
+00:10:18,390 --> 00:10:22,290
+الغذاء على شكل البروتينات، الغذاء الحيواني اللي
+
+118
+00:10:22,290 --> 00:10:25,850
+بنتغدأه، والغذاء النباتي، بروتينات حيوانية أو
+
+119
+00:10:25,850 --> 00:10:32,460
+نباتيةهدول ال amino acids العشرين بدنا نتعرف عليهم
+
+120
+00:10:32,460 --> 00:10:37,440
+جيدا، طبعا كل واحد له اسم، و دائما الناس بيحبوا
+
+121
+00:10:37,440 --> 00:10:41,920
+إيش؟ يختصروا الأسماء، يعني هيمروا علينا glycine,
+
+122
+00:10:41,980 --> 00:10:46,880
+alanine, cysteine, tryptophan, saline, valineاكتار
+
+123
+00:10:46,880 --> 00:10:52,960
+واضح؟ الان فى لهم نوعين من الاختصار فى اختصار لهم
+
+124
+00:10:52,960 --> 00:10:58,240
+بتلت حروف وفى اختصار لهم بحرف واحد بنسميه three
+
+125
+00:10:58,240 --> 00:11:03,100
+letter abbreviation اختصار الاسم لتلت حروف وفى
+
+126
+00:11:03,100 --> 00:11:08,140
+اننا نختصره لحرف واحد one letter abbreviation بشكل
+
+127
+00:11:08,140 --> 00:11:13,830
+عام اذا انا كنتربما المحاضرة السابقة قلتلكوا مشكلة
+
+128
+00:11:13,830 --> 00:11:20,310
+البروتينات ان they are not polymers فلازم اعمللهم
+
+129
+00:11:20,310 --> 00:11:24,650
+ايش؟ sequence ترتيب مين جاي اول واحد التاني التالت
+
+130
+00:11:24,650 --> 00:11:30,070
+الرابع الان اذا انا بدي ارسم peptide صغير يعني ال
+
+131
+00:11:30,070 --> 00:11:34,470
+peptide بيكون عادة تمانية تسعة عشرة خمستاشر amino
+
+132
+00:11:34,470 --> 00:11:39,920
+acid بستعمل three letter abbreviation واضح؟وإذا
+
+133
+00:11:39,920 --> 00:11:43,660
+بدى استعمل البروتين لبروتين بالمئات اللي لم يكن
+
+134
+00:11:43,660 --> 00:11:47,460
+بالألاف بستعمل ال one letter abbreviation فاللي
+
+135
+00:11:47,460 --> 00:11:52,320
+بدى يرسم ببتايد عادة بيستعمل اختصار تلت حروف اللي
+
+136
+00:11:52,320 --> 00:11:59,080
+بدى يرسم البروتين بيستخدم اختصار الحرف الواحد الان
+
+137
+00:11:59,080 --> 00:12:05,320
+لو اجينا بدنا نتعرف على هدول ال amino acids لاحظوا
+
+138
+00:12:05,320 --> 00:12:12,100
+ان احنا اتفقنا ان ال amino acidsفيهم أكتر من شيء
+
+139
+00:12:12,100 --> 00:12:16,080
+مشترك يعني مجموعة ال acid مشتركة ال carbon اللي
+
+140
+00:12:16,080 --> 00:12:20,960
+جنبها مشتركة و غالبا بتحمل H و أنا H2 و يمكن معادة
+
+141
+00:12:20,960 --> 00:12:25,420
+أمينو أسد واحد بيظل عندنا الاختلاف وين؟ في ال R
+
+142
+00:12:25,420 --> 00:12:30,100
+group بيظل عندنا الاختلاف في ال R group الآن بنيجي
+
+143
+00:12:30,100 --> 00:12:33,300
+إذا كانت ال R أبسط شيء عندنا في ال organ ال
+
+144
+00:12:33,300 --> 00:12:38,350
+chemistry اللي هي ال Hتمام؟ ال amino acid بيكون هو
+
+145
+00:12:38,350 --> 00:12:44,670
+ال glycine واضح؟ بياخد اختصارين ال gly او ال j
+
+146
+00:12:44,670 --> 00:12:50,930
+واضح؟ الان لاحظوا معي ال glycine تحديدا لو طلعنا
+
+147
+00:12:50,930 --> 00:12:55,110
+على ال carbon اللي هنا هذا ال carbon
+
+148
+00:12:58,040 --> 00:13:03,760
+في H و H مافيش في عليه four different groups عشان
+
+149
+00:13:03,760 --> 00:13:08,020
+هيك ال glycine does not contain a chiral center so
+
+150
+00:13:08,020 --> 00:13:12,620
+it is not a chiral molecule مش chiral optically
+
+151
+00:13:12,620 --> 00:13:20,990
+inactive مع ده ال glycine كلهم هيكونواthey contain
+
+152
+00:13:20,990 --> 00:13:24,670
+chiral centers and they are optically active الآن
+
+153
+00:13:24,670 --> 00:13:30,450
+نمشي بسرعة لو بدنا نشوف الحامض الأميني لبعده اللي
+
+154
+00:13:30,450 --> 00:13:35,850
+في مجموعة المثل أبسط المجموعات المثل بيصير اسمه
+
+155
+00:13:35,850 --> 00:13:38,590
+الانين لاحظوا ما تقولوش أنين
+
+156
+00:13:41,140 --> 00:13:45,340
+حاجة تانية في الـ aromatic compounds الانين الانين
+
+157
+00:13:45,340 --> 00:13:51,120
+بياخد الاختصار ال أو ا في مجموعة المثل لو كان في
+
+158
+00:13:51,120 --> 00:13:56,480
+مجموعة ال isopropyl بيصير اسمه valine لو كان في
+
+159
+00:13:56,480 --> 00:14:01,820
+مجموعة ال isobutyl بيصير اسمه ليوسين طبعا هذا ايه
+
+160
+00:14:01,820 --> 00:14:06,900
+الاختصار value في ال EU إذا كان في مجموعة ال
+
+161
+00:14:06,900 --> 00:14:13,600
+secondary butyl بيصير اسمه isoleucineواضح؟ لاحظوا
+
+162
+00:14:13,600 --> 00:14:17,100
+كل هذه المجموعات in principle they are simple
+
+163
+00:14:17,100 --> 00:14:20,560
+alkyl groups يعني كلها مرت علينا لما أخدنا ال
+
+164
+00:14:20,560 --> 00:14:25,240
+alkyl groups مثل بروبل مثل ايزو بروبل ايزو بيوتل
+
+165
+00:14:25,240 --> 00:14:29,540
+سكندر بيوتل they are simple alkyl groups هذه
+
+166
+00:14:29,540 --> 00:14:34,970
+المجموعة الأولى من ال amino acidsالان بعد هيك في
+
+167
+00:14:34,970 --> 00:14:40,950
+عندي amino acids ال R تبعتهم بتحمل OH يعني غير ال
+
+168
+00:14:40,950 --> 00:14:48,000
+amino و غير ال acid فيهم alcohol واضح؟فيهم ال
+
+169
+00:14:48,000 --> 00:14:52,160
+amino أكيد موجودة وال acid أكيد موجود هذا لا خلاف
+
+170
+00:14:52,160 --> 00:14:56,600
+فيه لكن يضاف اللي هو منه على ال R group في عنده
+
+171
+00:14:56,600 --> 00:15:04,400
+إيش ال alcohol فمنهم السيرين CH2OH ومنهم الثريونين
+
+172
+00:15:04,400 --> 00:15:13,350
+CHOHCH3 تمام؟بعد هيك بيجيني مجموعات فيهم كبريت
+
+173
+00:15:13,350 --> 00:15:21,230
+sulfur فيهم كبريت منهم الستين CH2SH ومنهم
+
+174
+00:15:21,230 --> 00:15:26,570
+الميثيونين CH2CH2SCH3
+
+175
+00:15:26,570 --> 00:15:34,250
+طبعا هتقولوا هدولةاكتار هل يا تورا مطلوب نحفظ كلها
+
+176
+00:15:34,250 --> 00:15:39,850
+ال amino acids؟ لأ لكن انا بقدر اطلب منكم اي amino
+
+177
+00:15:39,850 --> 00:15:42,530
+acid يعني انا ممكن بعديك اجي اقولكوا ارسموا
+
+178
+00:15:42,530 --> 00:15:47,330
+بيبتايد من خمسة amino acids هنكون اتعلمنا انه في
+
+179
+00:15:47,330 --> 00:15:52,940
+هيكل مشترك و ان الاختلاف فقطفي الـ R group فلو
+
+180
+00:15:52,940 --> 00:15:57,740
+أتيت قلتلكوا مثلا الانين بين جثين الـR بتساوي مثل
+
+181
+00:15:57,740 --> 00:16:02,840
+خلاص ان عرف لإن الاختلاف بينهم بس بإيش بالمثل او
+
+182
+00:16:02,840 --> 00:16:09,660
+مثلا فالين R بتساوي isopropyl الأصل أنه يقدر
+
+183
+00:16:09,660 --> 00:16:14,960
+الإنسان يرسمه لكن على أقل تقدير على أقل تقدير بدنا
+
+184
+00:16:14,960 --> 00:16:21,130
+تكونوا بالتأكيد تعرفوا ال glycineالأول H الالانين
+
+185
+00:16:21,130 --> 00:16:31,050
+اللي هو المثل الستينالـ CH2SH الستين بالذات لأنه
+
+186
+00:16:31,050 --> 00:16:35,390
+بعد هيك هنلاحظ أنه له أهمية كبيرة في شكل البروتين
+
+187
+00:16:35,390 --> 00:16:39,610
+بيعمل داي سالفايد بونتز متذاكرين لما أخدنا الثيولز
+
+188
+00:16:39,610 --> 00:16:43,390
+كانوا يعملوا داي سالفايد بونتز الآن اللي مطلوبين
+
+189
+00:16:43,390 --> 00:16:47,530
+يعني ممكن أقولكوا أرسمولي ألانين سستين أو اعملولي
+
+190
+00:16:47,530 --> 00:16:51,290
+بيبتايد من السستين بدون ما أعطيكوا المجموعة خلاص
+
+191
+00:16:51,290 --> 00:16:54,030
+نكون عارفين أن السستين هو اللي فيه مجموعة
+
+192
+00:16:57,230 --> 00:17:05,070
+الألانين في مثل لجليسين في H ما عدا ذلك لو بدنا أي
+
+193
+00:17:05,070 --> 00:17:09,670
+شيء بس بنعطيكوا بين جثين ال R group بتقدروا تكملوا
+
+194
+00:17:09,670 --> 00:17:17,090
+رسم ال amino acidالآن بجينة حامض اسمه إبرولين هذا
+
+195
+00:17:17,090 --> 00:17:23,750
+شوية صغيرة بختلف عنهم انه مافيش فيه NH2 هو CH NH
+
+196
+00:17:23,750 --> 00:17:28,700
+ومسكر على ال NH2 يعني عامل حلقةيعني كل ال amino
+
+197
+00:17:28,700 --> 00:17:34,760
+acids لما ترسموهم هترسم مجموعة الحامض و بعدين CH و
+
+198
+00:17:34,760 --> 00:17:39,960
+NH2 مع ذا هذا البرولين بتكون ال NH مسكرة على باقى
+
+199
+00:17:39,960 --> 00:17:47,580
+الجزء بالشكل اللى موجود الان هذا البرولين ماخد
+
+200
+00:17:47,580 --> 00:17:51,860
+الاختصار برو او بي بجينة الفينلالانين
+
+201
+00:17:53,330 --> 00:17:58,250
+لاحظوا لو هذه كانت CH3، إيش اسم ال amino acid؟
+
+202
+00:17:58,250 --> 00:18:03,070
+الالانين، شيلنا منها H و حطينا فينل، صار فينل
+
+203
+00:18:03,070 --> 00:18:08,230
+الالانين، واضح؟ يعني برضه ال فينل الالانين، لإنه
+
+204
+00:18:08,230 --> 00:18:13,940
+مختصر من الالانين، بصير مطلوب منهانعرفه، ليش؟ لأن
+
+205
+00:18:13,940 --> 00:18:18,720
+اللي عرف الألانين أن الـR تبعته CH3 لما أنا أقول
+
+206
+00:18:18,720 --> 00:18:23,380
+له فنل ألانين، بشيل H و بحط مجموعة الفنل، صار
+
+207
+00:18:23,380 --> 00:18:27,440
+الفنل ألانين، فاللي عرف الألانين وعارف من الكيميا
+
+208
+00:18:27,440 --> 00:18:35,530
+العامة مجموعة الفنل، بقدر يعرف الفنل ألانينبيجينا
+
+209
+00:18:35,530 --> 00:18:39,310
+الـ Tyrosine في هذه المجموعة CH2 في الـ OH لـ
+
+210
+00:18:39,310 --> 00:18:44,950
+tryptophan في حلقة كبيرة بنسميها Endol مع CH2 مش
+
+211
+00:18:44,950 --> 00:18:53,640
+مطموض نحفظهم طبعا، الآن في مجموعة أحماض فيهممجموعة
+
+212
+00:18:53,640 --> 00:18:58,660
+حمب تانية يعني غير ال acid group و ال amino group
+
+213
+00:18:58,660 --> 00:19:02,400
+اللي هم أساسيات هدولة لاحظوا اللي رسمينهم بالأزرق
+
+214
+00:19:02,400 --> 00:19:06,600
+في كل الرسمات يعني هدولة مشتركين بيجي في ال R
+
+215
+00:19:06,600 --> 00:19:11,460
+group نفسها مجموعة حمب تانية يعني غير هذه CO2H
+
+216
+00:19:11,460 --> 00:19:15,080
+تبعت ال amino acid في هنا كمان مجموعة تانية يعني
+
+217
+00:19:15,080 --> 00:19:19,380
+صار CH2COOH فصار في another
+
+218
+00:19:22,610 --> 00:19:28,750
+هدولة منهم الحمض الأول CH2COH اسمه Aspartic Acid و
+
+219
+00:19:28,750 --> 00:19:34,900
+لو كان مجمعتين CH ورا بعض بيصير Glutamic Acidلو
+
+220
+00:19:34,900 --> 00:19:39,280
+كان مشتق من الأحماض تذكروا لما أخدنا الأحماض قولنا
+
+221
+00:19:39,280 --> 00:19:43,580
+assets and their derivatives و منها الأمد و ما إلى
+
+222
+00:19:43,580 --> 00:19:49,060
+ذلك فلو كان بهذا الشكل ماخد شكل الأمد بيكون اسمه
+
+223
+00:19:49,060 --> 00:19:55,460
+أسبارجين و لو كان أمد بزيادة CH2 يعني بيصير
+
+224
+00:19:55,460 --> 00:20:00,700
+glutamine بيصير glutamine لحظةبتقدروا تشوفوا ال
+
+225
+00:20:00,700 --> 00:20:05,160
+glutamic acid كربونتين CH2 CH2 وبعدين حامض ل
+
+226
+00:20:05,160 --> 00:20:10,080
+glutamine CH2 CH2 وبعدين الأمد تبعه لذلك إيش سموه
+
+227
+00:20:10,080 --> 00:20:16,680
+glutamine إله اختصار الآن في أحماض تانية فيهم غير
+
+228
+00:20:16,680 --> 00:20:23,230
+ال NH2 هذه مجموعة NH2 تانية مش أمد أمينلحظوا الـ
+
+229
+00:20:23,230 --> 00:20:27,650
+NH2 الأمد بتخلف عن الأمين يعني هذه أمد وقلنا عنها
+
+230
+00:20:27,650 --> 00:20:33,050
+unreactive group متذكرين لما أخدنا الأمد قلنا انه
+
+231
+00:20:33,050 --> 00:20:38,230
+unreactive لأ في بيكون فيهم أمين عادية NH2 تانية
+
+232
+00:20:38,230 --> 00:20:44,640
+منهم اللايسين بالشكل اللي موجود منهم الارجينينفيه
+
+233
+00:20:44,640 --> 00:20:49,380
+أكثر من NH ومنهم الهستيدين هي أنا بتلاحظوا برضه
+
+234
+00:20:49,380 --> 00:20:58,080
+فيه NH NH NH أو NH2 هذي كلها amino acids فزي ما
+
+235
+00:20:58,080 --> 00:21:02,680
+بتلاحظوا انه بتصنيف ال amino acids التركيز على
+
+236
+00:21:02,680 --> 00:21:06,220
+إيش؟ على ال R group يعني ال R ممكن تكون simple
+
+237
+00:21:06,220 --> 00:21:10,960
+alkyl groupممكن تحتوي على OH ممكن تحتوي على
+
+238
+00:21:10,960 --> 00:21:16,680
+مجموعات aromatic ممكن تحتوي على مجموعة حمضية تانية
+
+239
+00:21:16,680 --> 00:21:22,480
+ممكن تحتوي على مجموعة قاعدية تانية واضح هذا
+
+240
+00:21:22,480 --> 00:21:31,670
+بالنسبة للتعريف بال amino acids بشكل عامالان لو
+
+241
+00:21:31,670 --> 00:21:36,310
+اجينا بدينا في ال acid-base properties لل amino
+
+242
+00:21:36,310 --> 00:21:45,450
+acids ال amino acids هم خليط من حمض و قاعدة ماشي
+
+243
+00:21:45,450 --> 00:21:51,850
+ال amino group is a basic group لما درسناها و أبسط
+
+244
+00:21:51,850 --> 00:21:57,700
+basic group منها ال ammoniaتحمل زوج إلكترونات
+
+245
+00:21:57,700 --> 00:22:05,040
+وجاهز إنها تستقبل إيش بروتون والأحماض acids الآن
+
+246
+00:22:05,040 --> 00:22:12,340
+لو أنا بشكل منفصل إجيت قلتلكم حمض زائد قاعدة يعني
+
+247
+00:22:12,340 --> 00:22:20,860
+HCL زائد أمونيا أو acetic acid زائد أمونياماشي
+
+248
+00:22:20,860 --> 00:22:26,360
+الحمض مع القاعدة بتفاعل وش بيعطوني ملح و ماء ممتاز
+
+249
+00:22:26,360 --> 00:22:32,060
+جدا الان في ال amino acids الحمض و القاعدة نوجدوا
+
+250
+00:22:32,060 --> 00:22:39,960
+في جزء واحد واضح ال amino group basic و ال COOH
+
+251
+00:22:39,960 --> 00:22:48,510
+acidic ال amino group بتحب تكتسببروتون هاي معناه
+
+252
+00:22:48,510 --> 00:22:54,950
+base و COH بتفقد بروتون طب هدول اتنين انحطوا في
+
+253
+00:22:54,950 --> 00:23:02,350
+جزء واحد اذا بالوضع الطبيعي تلقائيا بيعملوا تفاعل
+
+254
+00:23:02,350 --> 00:23:06,870
+داخلي طالما انه انوجد ال acidic group و ال basic
+
+255
+00:23:06,870 --> 00:23:11,110
+group بنفس الجزء بيعملوا التفاعل بينهم و بين بعض
+
+256
+00:23:11,110 --> 00:23:17,010
+المجموعة الحامضية بتفقد ال H و مين بيكتسبهالقاعدة
+
+257
+00:23:17,010 --> 00:23:24,310
+و لذلك بالوضع الطبيعي هذا الحامض بدل ما يكون C
+
+258
+00:23:24,310 --> 00:23:30,930
+double bond O OH بيفقد ال H بيصير CO2 minus يعني C
+
+259
+00:23:30,930 --> 00:23:35,870
+double bond O O minus لأن ال H اللي فقدها هنا مين
+
+260
+00:23:35,870 --> 00:23:42,730
+بده يتسبها القاعدة بدل ما هي NH2 بتصير NH3 plus
+
+261
+00:23:43,440 --> 00:23:49,180
+واضح؟ وبناء على ذلك في الوضع الطبيعي المتعدل ال
+
+262
+00:23:49,180 --> 00:23:56,460
+amino acids ما برسموهش بهذا الشكل يعني RCHC
+
+263
+00:23:56,460 --> 00:24:03,800
+double bond O OH هنا ال N H2بنرسمه مش زيك، بنقول
+
+264
+00:24:03,800 --> 00:24:08,220
+هذا حامض بده يفقد، هذه قاعدة بده تكتسب، وقاعدين
+
+265
+00:24:08,220 --> 00:24:11,920
+جان بعض، شو اللي بيمنعهم يفقدوا ويكتسبوا؟ بناء على
+
+266
+00:24:11,920 --> 00:24:17,380
+ذلك، بيتم إنه هذه بتفقد منها، وبتيجي وين؟ على هذا
+
+267
+00:24:17,380 --> 00:24:21,560
+الوضع، ففي ال neutral form حقيقة ما بنوجدش ال
+
+268
+00:24:21,560 --> 00:24:25,720
+amino acids بهذا الشكل، لأ بنوجد بهذا الشكل، فقد
+
+269
+00:24:25,720 --> 00:24:31,940
+لبروتون منها، واكتسبته إيش؟الـ Base واضح؟ و الآن
+
+270
+00:24:31,940 --> 00:24:37,460
+هذا الشكل بنقول عنه احنا Dipolar Ionic Form يعني
+
+271
+00:24:37,460 --> 00:24:43,820
+شكل فيه قطبين و بياخد اسم تاني جاي من الألماني
+
+272
+00:24:43,820 --> 00:24:47,900
+Zwitter Ionic Zwitter اش يعني Zwitter؟
+
+273
+00:24:51,140 --> 00:24:57,060
+سفيتر ionic form هذا المصطلح بيمر معاكم كتير سفيتر
+
+274
+00:24:57,060 --> 00:25:04,310
+من svay svay بالالماني معناها إيش؟اتنين, zwei يعني
+
+275
+00:25:04,310 --> 00:25:08,630
+اتنين يعني لما احنا بنعد بالعرب ايش بنقول؟ واحد,
+
+276
+00:25:08,690 --> 00:25:12,970
+اتنين, تلاتة, اربعة و بالانجليزي one, two, three,
+
+277
+00:25:13,170 --> 00:25:17,870
+four بالالماني eins, zwei, drei, vier, fünf,
+
+278
+00:25:18,030 --> 00:25:22,690
+sechs, sieben, acht, neun, zehn ف zwei يعني اتنين
+
+279
+00:25:22,690 --> 00:25:29,300
+فمنها ايجاZwitter Ionic لحظة دي بتنقرق Z و هذه ال
+
+280
+00:25:29,300 --> 00:25:37,440
+W V مش Zwitter لأ Zwitter واضح ال W الألمان شو
+
+281
+00:25:37,440 --> 00:25:44,760
+بيقرؤوها V و ال V إيش بيقرؤوها F عشان هيك اللي
+
+282
+00:25:44,760 --> 00:25:47,760
+عندهم السيارة هذه ال Volkswagen
+
+283
+00:25:50,020 --> 00:25:53,000
+إذا بدهم يقرؤوها بلغة الإنجليز بدهم يقرؤوا
+
+284
+00:25:53,000 --> 00:25:59,240
+Volkswagen بس هي باللغة الألمانية Volkswagen ال V
+
+285
+00:25:59,240 --> 00:26:06,880
+تقرأ F و ال W V Volkswagen Volkswagen يعني سيارة و
+
+286
+00:26:06,880 --> 00:26:10,240
+Volkswagen شعب
+
+287
+00:26:10,240 --> 00:26:15,080
+يعني تاكس الشعب سيارة الشعب سيارة البسيطة عارفينهم
+
+288
+00:26:15,080 --> 00:26:19,870
+ال Volkswagen اللي منهم الباصات و ال ..هذه
+
+289
+00:26:19,870 --> 00:26:23,650
+السيارات الكتيرة Volkswagen هذي svitar ionic
+
+290
+00:26:23,650 --> 00:26:30,430
+structure فلو سألناكم ان ال amino acids are better
+
+291
+00:26:30,430 --> 00:26:35,710
+represented by a dipolar ion structure معناه
+
+292
+00:26:35,710 --> 00:26:39,970
+dipolar ion structure svitar ionic structure عرفنا
+
+293
+00:26:39,970 --> 00:26:43,610
+ايش معناه هذا المصطلح؟ بتكرر كتير معكم بالمناسبة
+
+294
+00:26:44,390 --> 00:26:49,590
+تمام هذا الوضع في الـ neutral form طيب لو اجينا ال
+
+295
+00:26:49,590 --> 00:26:54,550
+amino acid احنا حطينا عليه H plus يعني زدناله H
+
+296
+00:26:54,550 --> 00:27:00,050
+plus من الخارج يعني بدون ما نحطله لا H plus ولا OH
+
+297
+00:27:00,050 --> 00:27:05,510
+minus يعني نسيبه زي ما هو هو حل مشكلته لحاله فقد H
+
+298
+00:27:05,510 --> 00:27:10,170
+من جهة و حطه بجهة تانية واضح؟و هذا الكلام كله في
+
+299
+00:27:10,170 --> 00:27:13,190
+الـ neutral form ماضفناش عليه إش بالبرا طب لو ضفنا
+
+300
+00:27:13,190 --> 00:27:19,450
+له H plus إضافية وين هتروح الـ H plus؟ على ال O
+
+301
+00:27:19,450 --> 00:27:24,490
+minus و لذلك لو ضفنا H plus هيصير بهذا الشكل الآن
+
+302
+00:27:24,490 --> 00:27:29,250
+لاحظوا لما أنا ضفت له H plus هذا متعادل ليش؟ لأنه
+
+303
+00:27:29,250 --> 00:27:34,110
+في موجب و سالب جد بعض الآن متعادل زاد H plus
+
+304
+00:27:34,110 --> 00:27:40,700
+متعادل زاد موجبأيش المحصلة موجب فهي لما فعلنا إجت
+
+305
+00:27:40,700 --> 00:27:45,580
+ال H plus اللي ضفناها هنا H plus عدلة ال O minus
+
+306
+00:27:45,580 --> 00:27:51,640
+دلوا موجب فبال acidic form بيكون ال amino acids
+
+307
+00:27:52,780 --> 00:27:57,480
+موجبة إيش شحنتها موجبة لاحظوا هذه الأسئلة اللي
+
+308
+00:27:57,480 --> 00:28:00,980
+بتكونوا تسألوها انتوا بالصح و الغلط in acidic
+
+309
+00:28:00,980 --> 00:28:09,320
+medium the amino acids are positive واضح amino
+
+310
+00:28:09,320 --> 00:28:14,530
+acid at low pH ال low pH معناهاacidic ايش بيكونوا؟
+
+311
+00:28:14,530 --> 00:28:19,170
+positive الان لو افترضنا هذا ال amino acid بعد ما
+
+312
+00:28:19,170 --> 00:28:23,670
+حطينا عليه حامض بزيادة وصار موجب اجينا بدينا بدنا
+
+313
+00:28:23,670 --> 00:28:28,510
+نسحب منه ال Hات كيف بنسحبهم؟ شو اللي بيسحب ال H
+
+314
+00:28:28,510 --> 00:28:33,870
+plus؟ OH minus فلو فعلت أنا مع OH minus هتيجي تسحب
+
+315
+00:28:33,870 --> 00:28:39,950
+هذه اللي اجت OH minus مع ال H؟ هتعطيني H2O و هيرجع
+
+316
+00:28:39,950 --> 00:28:49,700
+للوضع؟المتعادل طب لو زته كمان OH minus هياخد هذه
+
+317
+00:28:50,900 --> 00:28:55,760
+هياخد القدش اللي زي دهانة، شو هيصير؟ سالب فبناء
+
+318
+00:28:55,760 --> 00:29:01,180
+على ذلك بيصير عند أنا قاعدة بسيطة كتير ان ال amino
+
+319
+00:29:01,180 --> 00:29:08,940
+acids في الوسط الحامضي بيكونوا مجابين، في الوسط
+
+320
+00:29:08,940 --> 00:29:17,250
+القاعدي بيكونوا سالبين، واضح؟ سالبو طبعا بدون ما
+
+321
+00:29:17,250 --> 00:29:21,550
+نضيف عليهم من برا لا حمض ولا قاعدة بيكونوا إيش؟
+
+322
+00:29:21,550 --> 00:29:30,150
+neutral بس في zwitterionic form واضح؟ في شكل ثنائي
+
+323
+00:29:30,150 --> 00:29:33,050
+القطبية، هاي معناه zwitterionic form
+
+324
+00:29:38,320 --> 00:29:43,320
+هي هنا كمان مثال تأكيدي تماما للمثال السابق هو
+
+325
+00:29:43,320 --> 00:29:50,620
+أعطاني amino acid موجة طبعا بدناش ننسا احنا شغلة
+
+326
+00:29:50,620 --> 00:29:54,440
+انه فيش اشي في الدنيا .. فيش اشي في الدنيا بنباع
+
+327
+00:29:55,130 --> 00:29:59,910
+موجب أو سالب يعني لما هنا كنا نقولكوا اضيفوا H
+
+328
+00:29:59,910 --> 00:30:04,390
+plus مافيش H plus بتنجب لحالها و بتلبعها عادة لما
+
+329
+00:30:04,390 --> 00:30:08,230
+نقول اضيف H plus من وين بنجيبها؟ من HCL يعني كان
+
+330
+00:30:08,230 --> 00:30:13,210
+في معاه CL minus وبناء على ذلك لما هذه عملة الايون
+
+331
+00:30:13,210 --> 00:30:20,210
+الموجب كل هذا الجزء الموجب كان فيله CL minus مرافق
+
+332
+00:30:21,300 --> 00:30:27,000
+واضح؟ لكن أنا كنت مختصر الـCl- كده لأن أنا مهتم
+
+333
+00:30:27,000 --> 00:30:30,860
+بجزء الـ amino acid مش بالجزء التاني، واضح؟ بس
+
+334
+00:30:30,860 --> 00:30:34,460
+مافيش H بلس في الكون بتلبع لحالها، يعني الـH بلس
+
+335
+00:30:34,460 --> 00:30:38,100
+جاية من وين؟ من acid، خلّيني أقول HCl، فلو كنت
+
+336
+00:30:38,100 --> 00:30:44,560
+أعطي الـHCl، حيكون هذا موجة ومعه Cl ثالث، الآن لو
+
+337
+00:30:44,560 --> 00:30:49,620
+أخدنا مثل، هاي الـ amino acid الالانينفى nh3 plus
+
+338
+00:30:49,620 --> 00:30:54,560
+cl minus لما نيجى نفعله مع ال N A O H شو اللى بدى
+
+339
+00:30:54,560 --> 00:31:03,480
+يصير ال O H minus بدى تاخد ال H شو عملت ليه H 2 O
+
+340
+00:31:03,480 --> 00:31:06,680
+ال N A plus مع ال C L minus
+
+341
+00:31:11,850 --> 00:31:20,330
+الحمض يبقى في وضعه نيوترال وليس جابوسالد الاسفتر
+
+342
+00:31:20,330 --> 00:31:25,170
+ايونيك نيوترال الان هذا نفسه نيوترال لو اجينا كمان
+
+343
+00:31:25,170 --> 00:31:34,480
+مرة زدناله NAOH شو حيصير ال OH- هتاخدوحدة من هدولة
+
+344
+00:31:34,480 --> 00:31:41,100
+ال H's هتعطيني H2O هيصير بناء على ذلك هذي أنا H2
+
+345
+00:31:41,100 --> 00:31:45,860
+متعادلة بس أنا في عندى minus ال minus بالزمعيون
+
+346
+00:31:45,860 --> 00:31:46,620
+مرافق
+
+347
+00:31:50,390 --> 00:31:54,910
+فهذه المعادلات الحقيقة بلزم انكوا تتدربوا عليها
+
+348
+00:31:54,910 --> 00:31:58,710
+كيف ان ال amino acid بيكتسب بروتون كيف بيفقد
+
+349
+00:31:58,710 --> 00:32:02,870
+بروتون من خلال التفاعل مع حامض بيكتسب بروتونات من
+
+350
+00:32:02,870 --> 00:32:07,070
+خلال التفاعل مع القاعدة بيفقد بروتونات ما لم
+
+351
+00:32:07,070 --> 00:32:10,670
+تكتبوا و تتدربوا بهدوء على هذه المعادلات مش
+
+352
+00:32:10,670 --> 00:32:14,830
+هتتقنوا يعني مرات بنجيبلكوا أكمل المعادلات زي هيك
+
+353
+00:32:14,830 --> 00:32:20,270
+حطيلكوا amino acidع شكل Salt يعني كنا ضايفينله
+
+354
+00:32:20,270 --> 00:32:26,030
+أساسا HCL فعلوه مع NUH مرة أو مرتين يعني بنسبة
+
+355
+00:32:26,030 --> 00:32:31,490
+واحد او بنسبة اتنين اول NUH بتواصلنا لهنا تاني
+
+356
+00:32:31,490 --> 00:32:38,510
+فاعل واضح هذا الكلام وظيفة الطالب انه يتدرب عليه
+
+357
+00:32:38,510 --> 00:32:46,720
+الانمن الكلام هذا كله هنيجي لمحصلة مهمة جدا
+
+358
+00:32:46,720 --> 00:32:50,640
+المحصلة المهمة جدا احنا قلنا انه في ال acidic
+
+359
+00:32:50,640 --> 00:32:54,440
+condition
+
+360
+00:32:54,440 --> 00:33:00,560
+يعني في موضع حامض ال amino acid شو بيكون موجب و في
+
+361
+00:33:00,560 --> 00:33:09,680
+basic condition سالب طبعا معنى acidic low pHالان
+
+362
+00:33:09,680 --> 00:33:15,940
+كون ال amino acid صار ممكن يكون موجود
+
+363
+00:33:17,410 --> 00:33:22,230
+متعادل الـ zwitterionic يعني فيه الموجب والسالب أو
+
+364
+00:33:22,230 --> 00:33:28,450
+بس فيه كأمينو أسد الموجب أو بس فيه كأمينو أسد
+
+365
+00:33:28,450 --> 00:33:34,790
+السالب هذا الكلام بيوفرلي تقنية لفصل إيش ال amino
+
+366
+00:33:34,790 --> 00:33:41,670
+acids قبل ما نصل لهذا الكلام خلينا نقول ان ال BH
+
+367
+00:33:45,180 --> 00:33:50,480
+اللي بيكون عندها ال amino acid neutral سبعة ..
+
+368
+00:33:50,480 --> 00:33:54,360
+بنسميها .. لأ مش سبعة مختلفة .. مختلفة لأن ال
+
+369
+00:33:54,360 --> 00:33:59,320
+amino acid نفسه في مجموعات بتخليه acidic و basic
+
+370
+00:33:59,320 --> 00:34:04,060
+إضافية ال BH اللي بيكون عندها neutral ال amino
+
+371
+00:34:04,060 --> 00:34:08,120
+acid خلينا نقول هيك ال BH اللي بيكون عندها ال
+
+372
+00:34:08,120 --> 00:34:13,390
+amino acid إيش؟الـ neutral بتقول عنها الـ
+
+373
+00:34:13,390 --> 00:34:18,830
+isoelectric point واضح فال isoelectric point اللي
+
+374
+00:34:18,830 --> 00:34:24,550
+هي ال pH اللي بيكون عندها ال amino acid متعدل
+
+375
+00:34:24,550 --> 00:34:30,990
+isoelectric point الان كل amino acid له
+
+376
+00:34:30,990 --> 00:34:37,130
+isoelectric point خاصة فيه لكل ال amino acids
+
+377
+00:34:38,900 --> 00:34:43,840
+هتلاحظوا ان الـ isoelectric point تبعتهم موجودة في
+
+378
+00:34:43,840 --> 00:34:50,100
+الجدوة المحطوطة بين جثين يعني اتطلعوا للجليسين وين
+
+379
+00:34:50,100 --> 00:34:54,840
+بيكون ال amino acid متعادل بالسفتر ايونك and BH؟
+
+380
+00:34:54,840 --> 00:35:01,320
+ستة للالانين ستة للفالين ستة للسيرين مثلا خمسة
+
+381
+00:35:01,320 --> 00:35:09,930
+وسبعة للستين خمسةمجيوسة الان لاحظوا لما يكون عند
+
+382
+00:35:09,930 --> 00:35:14,930
+انا بعض ال amino acids فيهم مجموعة حمضية تانية
+
+383
+00:35:14,930 --> 00:35:20,330
+بتصير ال isoelectric point منخفضة بتصير تلاتة يعني
+
+384
+00:35:20,330 --> 00:35:23,550
+بيقاتش تلاتة بيكونوا متعادلين لما يكون فيهم مجموعة
+
+385
+00:35:23,550 --> 00:35:27,350
+قاعدية تانية بتصير ال isoelectric point عقلهم عالي
+
+386
+00:35:27,350 --> 00:35:33,490
+عند تسعة وعند عشرة تقريبا واضح فكل amino acid الان
+
+387
+00:35:34,530 --> 00:35:39,990
+بنفهم ان هو له isoelectric point ال بي اتش اللى
+
+388
+00:35:39,990 --> 00:35:46,430
+بيكون عندها متعادل الان اقل من ال isoelectric
+
+389
+00:35:46,430 --> 00:35:54,210
+point هذه ال بي اتش ايش بيصير موجب اعلى منها سالب
+
+390
+00:35:54,210 --> 00:35:58,810
+يعني صار في عند انا ال isoelectric point لل amino
+
+391
+00:35:58,810 --> 00:36:08,130
+acid ال isoelectric pointالآن هذه neutral أقل منها
+
+392
+00:36:08,130 --> 00:36:17,310
+موجب أعلى منها سالف واضح؟ وبناء على ذلك لو أنا جيت
+
+393
+00:36:17,310 --> 00:36:22,750
+سألت مثلا للستين شو ال isoelectric point قبل شوية
+
+394
+00:36:22,750 --> 00:36:29,560
+حكيناها ستةلسستين ستة الان لو سألتكم و قولتلكم
+
+395
+00:36:29,560 --> 00:36:35,880
+السستين عند بي اتش اربعة شو بيكون موجب السستين عند
+
+396
+00:36:35,880 --> 00:36:41,620
+بي اتش تسعة او تمانية سالب واضحهذه معناه الكلام
+
+397
+00:36:41,620 --> 00:36:49,000
+يعني BH6 الستين ال neutral بيكون
+
+398
+00:36:49,000 --> 00:36:55,120
+موجب ال BH أعلى بيكون H سالب الآن هذا الموضوع أن
+
+399
+00:36:55,120 --> 00:37:00,200
+ال amino acid ممكن نتحكم فيه يعني الستين أنا
+
+400
+00:37:00,200 --> 00:37:05,620
+بتغيير ال BH قاعد بقدر أخليه مرة يكون موجب مرة
+
+401
+00:37:05,620 --> 00:37:10,240
+يكون متعادل مرة يكون سالب ولا لأأنا اللي بتحكم في
+
+402
+00:37:10,240 --> 00:37:13,400
+ال بي أتش كيف الواحد بتحكم في ال بي أتش بيحط حمض
+
+403
+00:37:13,400 --> 00:37:17,540
+أو قاعدة أو بزيدها أو بنجسها يعني قمر سهل عمليا
+
+404
+00:37:17,540 --> 00:37:24,940
+فكأنه ال بي أتش صار إلها إشي تابع إنه يكونموجب أو
+
+405
+00:37:24,940 --> 00:37:29,820
+سالب الآن جثة الموجب والسالب كتير بتفرج معناه ليش؟
+
+406
+00:37:29,820 --> 00:37:35,560
+لأنه أخدوا منها .. من فكرتها تقنية عامة لفصل ال
+
+407
+00:37:35,560 --> 00:37:41,380
+amino acids عن بعضهم البعض الموجبلو حطيته في مجال
+
+408
+00:37:41,380 --> 00:37:45,780
+كهربائي، في موجة بوسالب، هيروح وين؟ على السالب،
+
+409
+00:37:45,780 --> 00:37:51,400
+والسالب هيروح وين؟ على الموجب، وبناء على ذلك هذا
+
+410
+00:37:51,400 --> 00:37:55,500
+الكلام بيصير أساس لطريقة، لفصل
+
+411
+00:37:58,240 --> 00:38:01,600
+الأمينو أسد هي أنا تعريف ال isoelectric point بس
+
+412
+00:38:01,600 --> 00:38:06,220
+عشان تكونوا متذكرينها is the pH at which the amino
+
+413
+00:38:06,220 --> 00:38:09,520
+acid will be dipolar and have in it its charge
+
+414
+00:38:09,520 --> 00:38:14,780
+equal to zero الأن لما يكون ديبولر و شحنته سفر لو
+
+415
+00:38:14,780 --> 00:38:18,920
+حطيته بوسط كهربا يعني حاطيت قطبين كهربا موجب و
+
+416
+00:38:18,920 --> 00:38:23,710
+سالبو ال بي اتش تبعته ع ال isoelectric point يعني
+
+417
+00:38:23,710 --> 00:38:28,710
+هو متعادل بيروح يمين ولا شمال ولا بيقعد مكانه الان
+
+418
+00:38:28,710 --> 00:38:34,550
+لو كانت ال بي اتش قليلة بمعنى كان موجب و وجدت وين
+
+419
+00:38:34,550 --> 00:38:38,830
+هيروح الموجب؟ على السالب على ال cathode و لو كانت
+
+420
+00:38:38,830 --> 00:38:43,990
+ال بي اتش عالية كان سالب وين هيروح السالب؟ على ال
+
+421
+00:38:43,990 --> 00:38:49,960
+anode مش ال anode هو القطبالموجب والكثود هو القطب
+
+422
+00:38:49,960 --> 00:38:55,600
+السالق وبناء على ذلك بتصير هذه طريقة يمكن من
+
+423
+00:38:55,600 --> 00:39:01,120
+خلالها ان نفصل ال amino acids عن بعض بنسميها ال ال
+
+424
+00:39:01,120 --> 00:39:03,260
+Electrophoresis
+
+425
+00:39:04,140 --> 00:39:07,140
+و هذه طريقة أساسية للناس اللي بيشتغلوا في الكيميا
+
+426
+00:39:07,140 --> 00:39:10,780
+في البروتينات و في ال amino acids بفصلوا من خلالها
+
+427
+00:39:10,780 --> 00:39:15,880
+هي فصل ال amino acids و فصل لبروتينات كهربيا
+
+428
+00:39:15,880 --> 00:39:22,080
+اعتمادا على ايش على شحنتهم الان شحنتهم تعتمد على
+
+429
+00:39:22,080 --> 00:39:28,540
+ال BH اذا انا بقدر اقول هو فصل كهربي لل amino
+
+430
+00:39:28,540 --> 00:39:33,400
+acids او لبروتينات اعتمادا على ال BH في المحصلة
+
+431
+00:39:34,600 --> 00:39:38,380
+واضح؟ هو الفصل اعتمادا على الشحنة انه يروح اشمال
+
+432
+00:39:38,380 --> 00:39:47,160
+او يمين، لكن الشحنة معتمدة على الـ BH ناخد مثالهذا
+
+433
+00:39:47,160 --> 00:39:50,120
+اللي سمناه الـ Electrophoresis is a method for
+
+434
+00:39:50,120 --> 00:39:53,620
+separating amino acids and proteins based on their
+
+435
+00:39:53,620 --> 00:39:58,380
+charge differences طبعا الـ isoelectric point عادة
+
+436
+00:39:58,380 --> 00:40:02,980
+بيعتور رمز بي لو قلنا ال isoelectric point
+
+437
+00:40:02,980 --> 00:40:10,460
+للأسبارتك أسد تلاتة تمام؟ الآن دائما جربوا أنتوا
+
+438
+00:40:10,460 --> 00:40:17,020
+ارسموا زي خط الأعدادتمام؟ الآن هذه الـ isoelectric
+
+439
+00:40:17,020 --> 00:40:24,380
+point للأسبارتك أسد اللي تلاتة عند BH تلاتة شو
+
+440
+00:40:24,380 --> 00:40:29,380
+بيكون الأسبارتك أسد؟ neutral بناء على ذلك لو حطينا
+
+441
+00:40:29,380 --> 00:40:35,640
+الأسبارتك أسد على BH3 و في وسطكهربائي كسودوانوت
+
+442
+00:40:35,640 --> 00:40:40,880
+هيتحرك؟ لأ هو الان بيجي بيسألني بيقول يا تورا على
+
+443
+00:40:40,880 --> 00:40:47,360
+BH5 وين هيروح؟ على الموجة الان انتبهوا معاه إيش
+
+444
+00:40:47,360 --> 00:40:51,840
+اللي عملوا قال طيب لو مخلوط عندي حامضين أسبارتك
+
+445
+00:40:51,840 --> 00:40:57,240
+أسد خلينا هيك نقول هذا الأسبارتك أسد ال BH ال
+
+446
+00:40:57,240 --> 00:41:02,900
+isoelectric point تبعته تلاتة مخلوط مع الألانين
+
+447
+00:41:05,540 --> 00:41:09,620
+القلانين عارفينه القلانين؟ قداش للقلانين ال
+
+448
+00:41:09,620 --> 00:41:18,120
+isoelectric point؟ ستة من الجدول ستة واضح؟ شفتوها؟
+
+449
+00:41:19,750 --> 00:41:25,710
+الالانين عند ستة بيكون متعادل، بتفرج على حاله، صح؟
+
+450
+00:41:25,710 --> 00:41:31,530
+والاسبارتك أسد عند تلاتة بيكون متعادل، بتفرج على
+
+451
+00:41:31,530 --> 00:41:36,390
+حاله، الآن لو إجيت قلت أطلع الاسبارتك أسد لوحده،
+
+452
+00:41:36,390 --> 00:41:43,230
+فوق التلاتة، شو بيكون؟ سالد، تحت التلاتة؟ موجب، لو
+
+453
+00:41:43,230 --> 00:41:45,250
+إجيت على الالانين
+
+454
+00:41:49,340 --> 00:41:56,080
+لو إجيت على الأنانين تحت الستة موجب فوق الستة سالب
+
+455
+00:41:56,080 --> 00:42:01,580
+الآن لو إجيت هدول الاتنين بدي أفصلهم عن بعض بضلني
+
+456
+00:42:01,580 --> 00:42:09,040
+أغير ال bh تغيير ذكي خليني أقول وصلت ال bh لخمسة
+
+457
+00:42:09,040 --> 00:42:15,340
+صار كل المحلول ال bh تبعته خمسة الآن قولولي أنتوا
+
+458
+00:42:15,340 --> 00:42:21,310
+عند خمسة شو بده يكون ال aspartic acid؟سالب فوق
+
+459
+00:42:21,310 --> 00:42:29,710
+التلاتة سالب واضح هيك موجب و عند ستة شو بده يكون
+
+460
+00:42:29,710 --> 00:42:34,150
+القلانين متعادل
+
+461
+00:42:34,150 --> 00:42:39,950
+عند ستة أقل من ستة موجب أعلى من ستة سالب الآن لما
+
+462
+00:42:39,950 --> 00:42:47,400
+أجي أقولكوا عند الخمسة هناتطلعوا معي الألانين موجب
+
+463
+00:42:47,400 --> 00:42:52,300
+الأسبارتك أسد سالب بناء على ذلك هذا الخليط لو
+
+464
+00:42:52,300 --> 00:42:56,500
+اتحكمت في ال بي اتش تبعته خليتها خمسة و حطيت له
+
+465
+00:42:56,500 --> 00:43:01,580
+قطبين كهربا وين هيروح الأسبارتك أسد على قطب الموجب
+
+466
+00:43:01,580 --> 00:43:05,700
+وين هيروح الألانين على قطب السالب انفصلوا عن بعض
+
+467
+00:43:05,700 --> 00:43:12,460
+ولا لأبنفصله طالما طلع هنا مختلف إذا بينفصله طيب
+
+468
+00:43:12,460 --> 00:43:17,780
+الآن انتبهوا معي جيدا حتى نفهم الطريقة بالظبط طبعا
+
+469
+00:43:17,780 --> 00:43:20,460
+احنا قولنا ال aspartic acid فوق التلاتة إيه شو بده
+
+470
+00:43:20,460 --> 00:43:26,040
+يكون؟ تلاتة و ال alanine تحت الستة شو بده يكون؟
+
+471
+00:43:26,040 --> 00:43:32,160
+موجة موجة الآن الإنسان اللي مش ذكي و بده يفصل هدول
+
+472
+00:43:32,160 --> 00:43:42,040
+عن بعضبنقوله اخترنا بي اتش مناسبة للفصل اذا حد اجى
+
+473
+00:43:42,040 --> 00:43:46,600
+جال انا والله بدي اخلي ال بي اتش تبعتهم اتنين ايش
+
+474
+00:43:46,600 --> 00:43:51,020
+رأيكوا؟ اتطلعوا
+
+475
+00:43:51,020 --> 00:43:54,780
+عما عند التنين، التنين موجبين، مش هيفصلوا
+
+476
+00:43:57,210 --> 00:44:01,510
+الان لو اجه واحد قال لأ و الله انا بدي افصلهم عند
+
+477
+00:44:01,510 --> 00:44:07,370
+BH تمانية اتنين سالب اذا اللي بده يختار ال BH
+
+478
+00:44:07,370 --> 00:44:12,850
+المناسبة لفصلهم لازم يختارها بين إيش؟ في المنطقة
+
+479
+00:44:12,850 --> 00:44:16,620
+اللي بيختلفوا فيهاشفتوا كيف لما بنفصل two amino
+
+480
+00:44:16,620 --> 00:44:23,400
+acids عن بعض بحط خط الأعداد باجلة الأول بعمل موجب
+
+481
+00:44:23,400 --> 00:44:27,940
+أقل من ال isoelectric point سالب أكتر باجلة التاني
+
+482
+00:44:27,940 --> 00:44:32,700
+نفس الاشي هاي ال isoelectric point أقل منها موجب
+
+483
+00:44:32,700 --> 00:44:38,500
+أكتر منها سالب الآن ال BH اللي بتفصل اللي بيختلفوا
+
+484
+00:44:38,500 --> 00:44:45,010
+فيهايعني أي BH بين التلاتة والستة بيكون فيها هذا
+
+485
+00:44:45,010 --> 00:44:49,890
+سالب وبيكون فيها هذا موجب تصبح للفصل لكن لو قولت
+
+486
+00:44:49,890 --> 00:44:53,550
+أقل من التلاتة التانين موجبين لو قولت أعلى من
+
+487
+00:44:53,550 --> 00:44:59,590
+الستة التانين سالبين ولذلك لما نعطي مثال ونقول
+
+488
+00:44:59,590 --> 00:45:04,470
+choose the appropriate BH for separating this
+
+489
+00:45:04,470 --> 00:45:12,380
+mixtureبدي أرسم خط الأعداد بيصير الأمر سهل جدا،
+
+490
+00:45:12,380 --> 00:45:20,280
+واضح؟ خلّيني أخد مثال تاني، هذا المثال التاني قال
+
+491
+00:45:20,280 --> 00:45:27,840
+بدنا تفصلونا ل glycine و lycine، طبعا أنا أسهل إشي
+
+492
+00:45:27,840 --> 00:45:33,390
+عندىان اعمل خط الاعداد اتخيل اني بدي احط ال
+
+493
+00:45:33,390 --> 00:45:39,210
+glycine مثلا هنا وال glycine هنا الان هيلزمني من
+
+494
+00:45:39,210 --> 00:45:45,830
+الجداول جداش ال isoelectric point لل glycine احنا
+
+495
+00:45:45,830 --> 00:45:54,610
+احفظنا لل glycine 6 ممتاز طب لل glycine مين شفتلنا
+
+496
+00:45:54,610 --> 00:45:56,290
+إياها 9.7
+
+497
+00:46:00,380 --> 00:46:05,780
+هذه تسعة و سبعة واضح؟ ارسموا بهذا الشكل و تحلوا
+
+498
+00:46:05,780 --> 00:46:08,860
+المسألة معاكم سهولة هاي ال glycine له ال
+
+499
+00:46:08,860 --> 00:46:12,480
+isoelectric point ستة ال glycine تسعة و سبعة الآن
+
+500
+00:46:12,480 --> 00:46:18,780
+بعد هيك هذه النقطة اللي بيكون عندها neutral أقل
+
+501
+00:46:18,780 --> 00:46:26,500
+منها أعلى منها سالم واضح؟ الآن بالنسبة لل glycine
+
+502
+00:46:26,500 --> 00:46:30,750
+هذه النقطة اللي بيكون عندها neutralneutral اقل
+
+503
+00:46:30,750 --> 00:46:35,030
+منها موجب
+
+504
+00:46:35,030 --> 00:46:42,010
+اعلى منها سالم الان لما اجي انا اقول لو انا بدي
+
+505
+00:46:42,010 --> 00:46:48,390
+افصلهم اي BH بتنفع معاه السبعة ممتازة التمانية
+
+506
+00:46:48,390 --> 00:46:54,440
+ممتازة بين الستةو التسعة و سبعة بين ال isoelectric
+
+507
+00:46:54,440 --> 00:46:59,160
+points تبعتهم واضح لكن لو أخدت أقل من الستة
+
+508
+00:46:59,160 --> 00:47:03,020
+التانين في موجبين مش هيفصلوا التانين موجب يعني
+
+509
+00:47:03,020 --> 00:47:06,380
+التانين هيروحوا على ال cathode و لو أخدت أكتر من
+
+510
+00:47:06,380 --> 00:47:09,660
+التسعة و سبعة تانين سالم التانين هيروحوا على ال
+
+511
+00:47:09,660 --> 00:47:13,190
+anode مع بعض مش هيفصلوافانا بتطلع وين بيكونوا
+
+512
+00:47:13,190 --> 00:47:17,670
+مختلفين باخد I BH مناسبة عادة بياخدوها ال between
+
+513
+00:47:17,670 --> 00:47:21,850
+الناس اللي بيشتغلوا طبعا بهذه الطريقة ممكن نفصل
+
+514
+00:47:21,850 --> 00:47:26,400
+كمان مش بس اتنيناكتر من اتنين تلاتة او اربعة او
+
+515
+00:47:26,400 --> 00:47:31,740
+خمسة احيانا لما بيعملوا الفصل بيفصلوا واحد بيودوه
+
+516
+00:47:31,740 --> 00:47:34,980
+على السالب و اتنين مع بعض على الموجة بعد ذلك
+
+517
+00:47:34,980 --> 00:47:39,000
+الاتنين اللي ودوه مع الموجة يعيدوا الفصل انا مش
+
+518
+00:47:39,000 --> 00:47:43,120
+هنحول احنا الى ايش الى مختبر يعني احنا بيكفينا
+
+519
+00:47:43,120 --> 00:47:47,860
+الفكرة العامة بتاعة الفكرة العامة صارت واضحة شهو
+
+520
+00:47:47,860 --> 00:47:52,640
+ال ال Electrophoresis هو طريقة لفصل ال amino acids
+
+521
+00:47:52,640 --> 00:47:59,580
+و البروتيناتاعتمادا على ال بي اتش ال بي اتش هي
+
+522
+00:47:59,580 --> 00:48:07,020
+اللي بتغير ايش الشحنات و بتوجه كل واحد باتجاه مجال
+
+523
+00:48:07,020 --> 00:48:12,640
+كهربي محدد ابهيك بننهي المرة اللي جاي بنبدأ في
+
+524
+00:48:12,640 --> 00:48:14,880
+تفاعلات ال amino acids
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/fva5m01JkUs_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/fva5m01JkUs_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..ceb55e18286175388f27d17e343d2fabc5771085
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/fva5m01JkUs_postprocess.srt
@@ -0,0 +1,1836 @@
+1
+00:00:19,620 --> 00:00:25,000
+بسم الله الرحمن الرحيممازلنا احنا بنتكلم في موضوع
+
+2
+00:00:25,000 --> 00:00:28,880
+الأحماض ومشتقاتها المرة الماضية اتكلمنا عن ال E
+
+3
+00:00:28,880 --> 00:00:34,940
+-stars وطرق تحضيرهم وبدأنا في موضوع تفاعلات ال E
+
+4
+00:00:34,940 --> 00:00:40,040
+-stars قولنا أول شيء أن التفاعل الأساسي اللي
+
+5
+00:00:40,040 --> 00:00:44,520
+هيتكرر معنا في كل هذا الفصل للأحماض وجميع مشتقاتها
+
+6
+00:00:44,520 --> 00:00:49,020
+وتفاعل الإجدال فكان أول تفاعل أخدناه عن ال E-stars
+
+7
+00:00:49,020 --> 00:00:54,430
+ال ammonolysis يعني أن نبدل ال ORب نيتروجين
+
+8
+00:00:54,430 --> 00:01:00,210
+وبالتالي بيطلع عندنا أمد وشوفنا كيف مثلا اتكون ال
+
+9
+00:01:00,210 --> 00:01:03,870
+بنز أمد الأسيتامد ما إلى ذلك في نهاية
+
+10
+00:01:03,870 --> 00:01:09,210
+اليوكليوفيليك substitution الآن من التفاعلات
+
+11
+00:01:09,210 --> 00:01:15,190
+التانية من التفاعلات التانية لل E starsالريدكشن
+
+12
+00:01:15,190 --> 00:01:20,230
+الريدكشن بالليثيوم الومنوم هايدرايد سبق احنا
+
+13
+00:01:20,230 --> 00:01:24,810
+اتعرفنا حقيقة على الليثيوم الومنوم هايدرايد قولنا
+
+14
+00:01:24,810 --> 00:01:30,980
+الاساس اللي فيه الاساس اللي فيه هو ال H-يعني انا
+
+15
+00:01:30,980 --> 00:01:35,320
+اللى بدى استفيده من ال high drive H minus الان
+
+16
+00:01:35,320 --> 00:01:41,260
+بدكوا تتخيلوا ان ال H minus بدها تهاجم على هذا ال
+
+17
+00:01:41,260 --> 00:01:45,120
+Easter بدها تهاجم على هذا ال Easter شو بدها تعمل
+
+18
+00:01:45,120 --> 00:01:51,680
+ابدا مكان ال OR بناء على ذلك الناتج اللى بده يطلع
+
+19
+00:01:51,680 --> 00:01:57,460
+عندكم بالدرجة الأولى R C double bond O H
+
+20
+00:02:00,330 --> 00:02:06,850
+واضح؟ شيلنا ال OR و حطينا ال H طبعا إذا بتلاحظوا
+
+21
+00:02:06,850 --> 00:02:12,330
+هذا ال ناتج اللي اتكون عندى هو عبارة عن ال الديهيد
+
+22
+00:02:12,330 --> 00:02:17,570
+احنا أخدنا في chapter ال الديهيد و ال ketones ان
+
+23
+00:02:17,570 --> 00:02:22,310
+ال الديهيد و ال ketones بيتفاعلوا مع ال hydride
+
+24
+00:02:22,890 --> 00:02:27,170
+الالديهيدز بتعطيني ال primary alcohol و ال ketone
+
+25
+00:02:27,170 --> 00:02:30,890
+ال secondary alcohol بناء على ذلك هذا ال الديهيدز
+
+26
+00:02:30,890 --> 00:02:36,670
+اللي اتكون هنا مرة تانية لو اجت فاعل مع ال H minus
+
+27
+00:02:36,670 --> 00:02:42,290
+الان هذا كان E star ال E star ايش تفاعله المميز
+
+28
+00:02:42,290 --> 00:02:44,250
+Substitution
+
+29
+00:02:46,570 --> 00:02:50,930
+لما عملت substitution صار ال الديهايد ال الديهايد
+
+30
+00:02:50,930 --> 00:02:56,990
+شو تفاعله addition هم الكلمتين تحكوليش غيرهم فقط
+
+31
+00:02:56,990 --> 00:03:01,890
+بسمع هنا substitution وهنا بسمع addition طالما هذا
+
+32
+00:03:01,890 --> 00:03:06,770
+الديهايد addition طبعا هتيجي H و سيضة بال bond O
+
+33
+00:03:06,770 --> 00:03:11,090
+شو تصير O H هذا التفاعل سبق أخدنا الديهايد مع ال
+
+34
+00:03:11,090 --> 00:03:16,990
+hydride بيعمل addition والنتيجة هتكون إيشprimary
+
+35
+00:03:16,990 --> 00:03:22,810
+alcohol إذا لو أنا أخدت التفاعل بالمجمل تفاعل ال
+
+36
+00:03:22,810 --> 00:03:28,750
+eastern مع ال hydride بينتهي في النهاية ب primary
+
+37
+00:03:28,750 --> 00:03:33,090
+alcohol لكن ننتبه أنه مرورا بال aldehyde الآن هذا
+
+38
+00:03:33,090 --> 00:03:38,110
+ال aldehyde لا يفصلواضح؟ يعني بنفعل بتكون ال
+
+39
+00:03:38,110 --> 00:03:41,990
+الديهايد ع طول بلاجة اتش تانية يتفعل معاها بيصفى
+
+40
+00:03:41,990 --> 00:03:46,650
+primary alcohol عشان هيك هذا الكلام حتى نكون
+
+41
+00:03:46,650 --> 00:03:50,910
+فاهمين بالظبط إيش اللي صار معنا لكن بدل المرة ألف
+
+42
+00:03:50,910 --> 00:03:55,410
+بقول لو قلتلكوا أكمل المعادلة أكمل الفراغ بدي
+
+43
+00:03:55,410 --> 00:04:00,640
+Easterمع hydride في النهاية انا بده اشوف ال
+
+44
+00:04:00,640 --> 00:04:03,620
+primary alcohol ربما لهذا السبب انتوا شايفين
+
+45
+00:04:03,620 --> 00:04:07,580
+المعادلة في نهايتها ايش؟ primary alcohol لكن هي في
+
+46
+00:04:07,580 --> 00:04:13,440
+تفصيلها كام خطوة؟ خطوتين هي في تفصيلها خطوتين
+
+47
+00:04:13,440 --> 00:04:18,980
+إبدال كون ال aldehyde و بعدين إضافة كونت ال
+
+48
+00:04:18,980 --> 00:04:25,150
+primary alcohol واضحة الفكرة؟الان زى هذا التفاعل
+
+49
+00:04:25,150 --> 00:04:31,970
+تماما زى هذا التفاعل تماما لو يا تورا اجينا فعلنا
+
+50
+00:04:31,970 --> 00:04:35,890
+و هذا مش مكتوب عندكوا لكن بنضيفه عليكم لو اجينا
+
+51
+00:04:35,890 --> 00:04:42,590
+فعلنا ال Easter مش مع H minus مع R minus طبعا اللى
+
+52
+00:04:42,590 --> 00:04:47,890
+بنقصده في R بهدى الحالة ايش ال green yard reagent
+
+53
+00:04:47,890 --> 00:04:59,080
+ال Rمجي اكس مصدر لل R مينوس مظبوط ولا لأ هيحط R
+
+54
+00:04:59,080 --> 00:05:05,220
+مرتين فى المرة الأولى شو هيحط هنا R كوّن لك
+
+55
+00:05:05,220 --> 00:05:13,140
+الكيتون الان كمان مرة R تانية نشيل هدول ال chain
+
+56
+00:05:13,140 --> 00:05:18,820
+اللى كانوا من ال high drive نحط R وR
+
+57
+00:05:20,670 --> 00:05:26,770
+إذا في هذه الحالة التفاعل مع جرينيارد شو بيعطيني
+
+58
+00:05:26,770 --> 00:05:32,210
+تيرتشاري ألكول لأن R كانت أصلا من ال Easter وتنتين
+
+59
+00:05:32,210 --> 00:05:35,210
+متشابهات اتجوا من الجرينيارد يعني لو افترضنا مثلا
+
+60
+00:05:35,210 --> 00:05:39,990
+أن هذه كانت فنل وفعلت
+
+61
+00:05:39,990 --> 00:05:44,130
+مع إيثل ماجنيسيا مبروماي على مرتين أول مرة هيحق
+
+62
+00:05:44,130 --> 00:05:51,170
+إيثل و تاني مرة كمان إيثل إذا ال Easterفي المحصلة
+
+63
+00:05:51,170 --> 00:05:59,510
+مع الـ Greenyard reagent بدوا يعطيني تيرتشاريه
+
+64
+00:05:59,510 --> 00:06:05,710
+الكهول تماما نفس التفاعل اللي مع الهيدرايد لكن بدل
+
+65
+00:06:05,710 --> 00:06:10,210
+ما كنت بضيف H- مرتين يعني مرة بالإبدال و مرة
+
+66
+00:06:10,210 --> 00:06:21,410
+بالإضافة بحط R- مرتين واضح بحط ال R- مرتينلاحظوا
+
+67
+00:06:21,410 --> 00:06:27,030
+معي للناس اللي بيحاولوا يفهموا الأمور بصورتها
+
+68
+00:06:27,030 --> 00:06:31,730
+الكلية للناس اللي بيحاولوا يفهموا الأمور بصورتها
+
+69
+00:06:31,730 --> 00:06:38,410
+الكلية السهلة مش بالمسميات الضيقة الآن هذا Easter
+
+70
+00:06:38,410 --> 00:06:43,130
+اعملتله انا تفاعلين و اتعمت لما عرفتهم التفاعل
+
+71
+00:06:43,130 --> 00:06:43,670
+الأول
+
+72
+00:06:47,190 --> 00:06:51,550
+الـ Hydrides و أعطاني Primary Alcohols و التفاعل
+
+73
+00:06:51,550 --> 00:06:54,790
+التالي معي Green Yard Reagent و أعطاني Tertiary
+
+74
+00:06:54,790 --> 00:06:59,530
+Alcohol مرورا بالكيتون في هذه الحالة الآن هذه
+
+75
+00:06:59,530 --> 00:07:07,070
+المجموعة الـ OR مجموعة إيه شمالها؟مطرودة طردت جيبت
+
+76
+00:07:07,070 --> 00:07:14,170
+سيرتها لأ طيب يا تورا لو بعد شوية أخدنا ال acid
+
+77
+00:07:14,170 --> 00:07:19,090
+halides بمعنى ماكناش نبدأ ب E star و المجموعة
+
+78
+00:07:19,090 --> 00:07:23,670
+المطرودة OR كان عندنا acid halide كان تادي CL أو
+
+79
+00:07:23,670 --> 00:07:32,570
+PR و إجيت قولت تفاعل ال acid halide مع ال hydrides
+
+80
+00:07:32,570 --> 00:07:40,530
+شو هيعطيلي؟نفس الكلام تماماً لأنه طردت OR أو طردت
+
+81
+00:07:40,530 --> 00:07:45,310
+CL وباقي الناتج زي ما هو ال primary alcohol تفاعل
+
+82
+00:07:45,310 --> 00:07:50,170
+acid halide مع grignard reagent tertiary alcohol
+
+83
+00:07:50,170 --> 00:07:54,890
+واضح؟ شو بديفرق التفاعل إذا كانت المجموعة اللي
+
+84
+00:07:54,890 --> 00:07:59,810
+طردت OR و أخدت H طلعت على شكل alcohol ولا CL minus
+
+85
+00:07:59,810 --> 00:08:06,360
+و أخدت H طلعت على HCLواضح؟ وعشان هيك اللي بيعرف
+
+86
+00:08:06,360 --> 00:08:10,240
+أنه ال Easter بتفاعل مع ال hydrates ومع greenery
+
+87
+00:08:10,240 --> 00:08:15,880
+agent بطريقة معينة بنقوله كمان و ال acid chlorides
+
+88
+00:08:15,880 --> 00:08:21,970
+بتفاعلوا مع ال hydrates ومع greenery agentبنفس
+
+89
+00:08:21,970 --> 00:08:27,090
+الطريقة تماما مافرجش انه يكونش المجموعة المطرودة
+
+90
+00:08:27,090 --> 00:08:31,710
+هي OR ولا CL هذه مجموعة مطرودة لكن الجزء ال
+
+91
+00:08:31,710 --> 00:08:36,870
+organic اللي عندى جزء اشماله ثابت واضح الفكرة
+
+92
+00:08:49,670 --> 00:08:55,890
+الان بننتقل ل ال acid halides ال acid halides قلنا
+
+93
+00:08:55,890 --> 00:09:00,290
+عنهم مشتقات ايضا من الأحماض و لما اتكلمنا عن
+
+94
+00:09:00,290 --> 00:09:06,030
+تفاعلات الأحماض اتكلمنا عن تحضيرهم قلنا اذا أخدنا
+
+95
+00:09:06,030 --> 00:09:10,990
+ال organic acid مع ال phosphorus trichloride او ال
+
+96
+00:09:10,990 --> 00:09:20,920
+SOCl2 يهدي يهدي بيشيل ال OH و بيحطلهCL فال acid
+
+97
+00:09:20,920 --> 00:09:25,480
+بتحول الى acid chlorides طريقة التحضير طريقة ايش
+
+98
+00:09:25,480 --> 00:09:31,600
+سهلة الان لو اجينا للتسمية كيف بنسمي ال acid
+
+99
+00:09:31,600 --> 00:09:39,190
+halides احنا كان هنا في عندنا OECacid الآن بدنا
+
+100
+00:09:39,190 --> 00:09:44,930
+نغير كلمة acid بكلمة halide بدنا نغير كلمة acid
+
+101
+00:09:44,930 --> 00:09:49,790
+بكلمة halide و ال oic بنخليها oil يعني لو أخدنا
+
+102
+00:09:49,790 --> 00:09:56,510
+ethanoic acid اللي هو الحامض اللي من carbon 10 بدو
+
+103
+00:09:56,510 --> 00:10:02,350
+يصير ethanoic chloride لو هنا bromالبروميد لو
+
+104
+00:10:02,350 --> 00:10:07,770
+أخدنا ال common name تبعه acidic acid بس بنشيل ايش
+
+105
+00:10:07,770 --> 00:10:13,490
+كلمة acid و بنحط chloride فهذا المركب ايش بيصير
+
+106
+00:10:13,490 --> 00:10:19,750
+Acetyl لأ بنرجع للمجموعة YL Acetic منها Acetyl
+
+107
+00:10:19,750 --> 00:10:27,400
+واضح لأن هذه اتعرفنا عليها Acetylمتذكرينها؟ أسيتل
+
+108
+00:10:27,400 --> 00:10:33,560
+و بنكتب إيش؟ أكلورايد فالفكرة بدنا نشيل هذا جزء
+
+109
+00:10:33,560 --> 00:10:39,000
+الأسيتل و ننهب وي الهلايد أسيتل أكلورايد و منها
+
+110
+00:10:39,000 --> 00:10:43,380
+كمان سبق إن اتعرفنا على مجموعة ال بنزويل من وين
+
+111
+00:10:43,380 --> 00:10:48,920
+بنجيب ال بنزويل أكلورايد؟ لو أجينا سألناكم بنزويل
+
+112
+00:10:48,920 --> 00:10:54,300
+أكلورايد بدنا نجيبه من؟
+
+113
+00:10:55,720 --> 00:11:03,440
+البنزويك أسد C double bond O OH في ال BCL3 أو أي
+
+114
+00:11:03,440 --> 00:11:07,640
+حاجة C
+
+115
+00:11:07,640 --> 00:11:14,360
+double bond O Cl هذا إيش بده يصير بنزويل لإن هذه
+
+116
+00:11:14,360 --> 00:11:19,900
+مجموعة البنزويل فنل C double bond O بنزويل
+
+117
+00:11:19,900 --> 00:11:29,870
+إكلورايدوالبنزول كمجموعة مرات بتختصر بي زد هيك
+
+118
+00:11:29,870 --> 00:11:35,250
+بنزول إكلورايد فإذا قرأته كلمة بي زد هذا اختصار
+
+119
+00:11:35,250 --> 00:11:40,330
+إيش بنزول بنزول إكلورايد واللي علمكوا ال بنزول
+
+120
+00:11:40,330 --> 00:11:45,230
+جالكوا تذكروا أنه في إلها بنت عم بتشبهها في
+
+121
+00:11:45,230 --> 00:11:49,510
+الكتابة اللي هي بنزل إكلورايد بس ال بنزل إكلورايد
+
+122
+00:11:49,510 --> 00:11:57,190
+عبارة عنفين ال CH2 نفترض CH2 فين ال CH2 هذه مجموعة
+
+123
+00:11:57,190 --> 00:12:06,230
+البنزل مش بنزايل بنزل طبعا لو جيت سألكوا البنزل
+
+124
+00:12:06,230 --> 00:12:11,650
+كلورايد كهيلايد أي نوع من الهيلايد primary
+
+125
+00:12:11,650 --> 00:12:12,890
+alkalihilide
+
+126
+00:12:16,310 --> 00:12:21,030
+الكل واضح ماحدش ييجي يشوف هنا ال aromatic ويقول
+
+127
+00:12:21,030 --> 00:12:24,630
+عنه aromatic halide لأ هو ال aromatic halide لو
+
+128
+00:12:24,630 --> 00:12:29,370
+كانت ال CL متصلة مباشرة بالحلقة لكن طالما ال CL
+
+129
+00:12:29,370 --> 00:12:34,930
+متصلة ب CH2 إذا هذا الكل halide وبناء على ذلك بتيم
+
+130
+00:12:34,930 --> 00:12:37,970
+عليكوا التفاعلات الإبدال اللي درسناها في شبتر 6
+
+131
+00:12:37,970 --> 00:12:42,070
+ولا لأ اه فهذا بنزل chloride
+
+132
+00:12:43,690 --> 00:12:47,390
+فبفرق بنزل الكلورايد عن بنزول الكلورايد وبنزل الى
+
+133
+00:12:47,390 --> 00:12:52,650
+اختصار بيختصرها BN واضح
+
+134
+00:12:52,650 --> 00:13:01,050
+بيختصرها BN بنزل فننتبه لهدول المجموعتين هذا ال
+
+135
+00:13:01,050 --> 00:13:07,150
+بنزول الكلورايد يعني إذا بدنا نوصفه بنقول عنه انه
+
+136
+00:13:07,150 --> 00:13:16,970
+إيش انه لعينليش بنوصف بهذا الوصف القاسي؟ لأن هذا
+
+137
+00:13:16,970 --> 00:13:22,430
+اللي هو عادة يستعمل كغاز مسيل للدموع يعني بتعرفوا
+
+138
+00:13:22,430 --> 00:13:27,630
+الغازات اللي في المظاهرات وغيرها، الغازات المسيلة
+
+139
+00:13:27,630 --> 00:13:34,930
+للدموع، معظمها acid halides، ومن ضمنهاالبنزول
+
+140
+00:13:34,930 --> 00:13:40,230
+الكلورايد من ضمنها البنزول الكلورايد طبعا لو اجينا
+
+141
+00:13:40,230 --> 00:13:45,850
+نقول ايش السبب ايش السبب ان هذا البنزول الكلورايد
+
+142
+00:13:45,850 --> 00:13:53,110
+يستعمل كغاز مسيل للدموع ناخد احنا بشكل عام
+
+143
+00:13:53,110 --> 00:13:58,330
+الكلورايد و تفاعلاتها ناخد بشكل عام الكلورايد و
+
+144
+00:13:58,330 --> 00:14:03,550
+تفاعلاتها طبعا مرتان تفاعلات الكلورايد هي تفاعلات
+
+145
+00:14:05,010 --> 00:14:09,570
+الإبدال يعني ال acid chloride مجرد ما بديه يتعرض
+
+146
+00:14:09,570 --> 00:14:14,410
+للميه مجرد ما بديه يتعرض للميه بديه يفقد ال CL و
+
+147
+00:14:14,410 --> 00:14:21,470
+يحط ال OH رجع لإيش؟ لل carboxylic acid واضح؟من حد
+
+148
+00:14:21,470 --> 00:14:25,590
+ما يتعرض للميه برجع ل acid لو فعلنا مع ال ethanol
+
+149
+00:14:25,590 --> 00:14:32,050
+بدو يشيل ال CL ويحط O-ethyl برجع ل E-star لو فعلنا
+
+150
+00:14:32,050 --> 00:14:37,890
+مع ال ammonia بدو يشيل ال CL ويحط NH2 بصير أمل فزي
+
+151
+00:14:37,890 --> 00:14:41,770
+ما اتفقنا أنه من واحد بنحضر التاني الآن خلينا على
+
+152
+00:14:41,770 --> 00:14:47,480
+المعادلة الأولىخلّينا على المعادلة الأولى و نتخيل
+
+153
+00:14:47,480 --> 00:14:52,020
+مثلا أنه إحنا اللي بدين فيه ال benzoyl chloride
+
+154
+00:14:52,020 --> 00:14:54,920
+اللي هو إيش موجود فيه بدل ال acetyl chloride هنا
+
+155
+00:14:55,790 --> 00:15:00,610
+فنل سيبا بالبوند OCL هذا البيزويل الكلوري
+
+156
+00:15:00,610 --> 00:15:06,190
+بيستعملوه كغاز مصير للدموع الآن السؤال هل هو غاز
+
+157
+00:15:06,190 --> 00:15:13,310
+أصلا لأ هو مادة زيتية يعني مادة
+
+158
+00:15:15,850 --> 00:15:22,150
+بحرارة غليان فوق المية درجة مئوية لكن لما بيرموه
+
+159
+00:15:22,150 --> 00:15:27,130
+في الجو بيطلع على شكل .. بيطلع على شكل رذاذ صغير
+
+160
+00:15:27,130 --> 00:15:31,350
+فبييجي على الناس بيبدو الناس يشموه بييجي على وجههم
+
+161
+00:15:31,350 --> 00:15:37,250
+يعني عملية قذفهفي الجو بيخليه يطلع على شكل إيش؟
+
+162
+00:15:37,250 --> 00:15:42,470
+رذاذ، رذاذ صغير، الآن هذا الرذاذ الصغير اللي طلع
+
+163
+00:15:42,470 --> 00:15:49,750
+لو دخل على جسم الإنسان، هيدخل على الزور، هيجي على
+
+164
+00:15:49,750 --> 00:15:56,450
+العنين، شكل أساسي، الآن الزور و العنين فيهم مياه
+
+165
+00:15:57,990 --> 00:16:03,730
+إذا وجدت أنا هأعمل تفاعل البنزويلي كلوراي مع الميه
+
+166
+00:16:03,730 --> 00:16:09,590
+هطلع بنزويك أسد البنزويك أسد حمضه ضعيف مش منه
+
+167
+00:16:09,590 --> 00:16:16,350
+المشكلة لكن المشكلة أكتر من ال HCL ال HCL هو اللي
+
+168
+00:16:16,350 --> 00:16:22,950
+هيسبب الحرقان في العينين وفي الزور واضح ال HCL
+
+169
+00:16:22,950 --> 00:16:31,010
+الآن هذا نفسه لو إجه على الجلدمافيش منه مشكلة إذا
+
+170
+00:16:31,010 --> 00:16:34,350
+الجلد جافلكن بتعرفوا الناس اللي بيكونوا في
+
+171
+00:16:34,350 --> 00:16:39,010
+المظاهرات مرات بيكونوا عرقانين اه لو اجى معي العرق
+
+172
+00:16:39,010 --> 00:16:43,630
+و اجي اتعمل HCL بيصير الجلد يحرج لو افترضنا ان
+
+173
+00:16:43,630 --> 00:16:49,310
+البني ادم اللي كان في المظاهرة اجى عليه هو عبارة
+
+174
+00:16:49,310 --> 00:16:53,070
+عن سائل على الوجه على الجسم مافيش عنده مشكلة
+
+175
+00:16:53,070 --> 00:16:56,790
+ماحسشه مشاكل كتير غير في العنان و الزور لكن بعد
+
+176
+00:16:56,790 --> 00:17:02,630
+هيك لو راح يتوضى بالميةيغسل الإيدان و يغسل الوجه
+
+177
+00:17:02,630 --> 00:17:06,650
+بكمية ميه صغيرة بصير وشه و إيديه زي النار ليش؟ لإن
+
+178
+00:17:06,650 --> 00:17:14,530
+هو بحط ميه على رذاف بالزويل الكلورايفبتفعلوا بيطلع
+
+179
+00:17:14,530 --> 00:17:18,690
+إيش ال HCL و لذلك البني آدم اللي بده يمر بهذه
+
+180
+00:17:18,690 --> 00:17:24,670
+الظروف المفروض أنه بده يغير ملابسه بده يغسل بميه و
+
+181
+00:17:24,670 --> 00:17:29,870
+صابونة و كمية كبيرة جدا عشان يشيل هذه المادة ما
+
+182
+00:17:29,870 --> 00:17:34,450
+احنا قولنا مادة زيتية سائلة لو كان غاز كان اتبخر
+
+183
+00:17:34,450 --> 00:17:40,550
+في الهواء مع السلامة لكن هم بيرشوه و هم عارفينإنه
+
+184
+00:17:40,550 --> 00:17:43,850
+أنا بديش إياه يطير معي الهواء، إياه يظل ملزج في
+
+185
+00:17:43,850 --> 00:17:50,630
+الإنسان وفي الوجه ما هدوله اسمه فن إيش الإذاء اللي
+
+186
+00:17:50,630 --> 00:17:55,090
+بديه يرشي الغاز المسيل اللي قدوموه بديه يضر الناس
+
+187
+00:17:55,090 --> 00:17:59,790
+كذلك الحال بالمناسبة في موضوع غازات الأعصاب اللي
+
+188
+00:17:59,790 --> 00:18:06,700
+بتتدخل على الأعصاب أقوى الغازات أقلها تطيراهي كلها
+
+189
+00:18:06,700 --> 00:18:12,760
+سوائل بيسموها غازات تجاوزا، لكن ليش بيسموها غازات؟
+
+190
+00:18:12,760 --> 00:18:16,800
+لأنه بينشروها على شكل رذاذ زي الميه لما بتنشرها
+
+191
+00:18:16,800 --> 00:18:21,220
+على شكل رذاذ أو ال spray العطر لما بتنشره على شكل
+
+192
+00:18:21,220 --> 00:18:28,440
+رذاذ، واضح الفكرة؟أكثرها تبخرا، أقلها تبخرا، لأنها
+
+193
+00:18:28,440 --> 00:18:32,660
+تبقى ملازقة في الأواعي، ملازقة في الأرض، ملازقة
+
+194
+00:18:32,660 --> 00:18:36,880
+على الحيطان، على السيارات، على الشجر وبهدوء تتبخر
+
+195
+00:18:36,880 --> 00:18:42,960
+وبتطلع كميات الغاز وبتضر البني آدم، بينما أكثرها
+
+196
+00:18:42,960 --> 00:18:50,180
+تبخرابيجي الهواء بياخده، بالتالي خطورته إيش؟ بتخف،
+
+197
+00:18:50,180 --> 00:18:55,220
+فالغازات الأعصاب مشهور منها غاز A، غاز B، غاز
+
+198
+00:18:55,220 --> 00:19:04,890
+بيسموه C في Novichok في VX، مسميات كثيرةاختارها
+
+199
+00:19:04,890 --> 00:19:11,070
+اقلها ايش؟ تبخرا، بيسموها nerve gases هذه الغازات
+
+200
+00:19:11,070 --> 00:19:17,150
+تبعت الدموع شو بيسموها؟ tear gases، tear يعني دموع
+
+201
+00:19:18,030 --> 00:19:22,610
+Tear gases او لكريماتر لكريماتر الغاز المثيل
+
+202
+00:19:22,610 --> 00:19:28,490
+للدموع او tear gas فالبنزويل الكلورايد is لكريماتر
+
+203
+00:19:28,490 --> 00:19:33,950
+or is a tear gas الفكرة الأساسية منه ان هو بتطلع
+
+204
+00:19:33,950 --> 00:19:40,320
+hcl اللي بيسبب ايشالحرقان طبعا في المجتمع الدولي
+
+205
+00:19:40,320 --> 00:19:44,260
+اللي موجود اليوم المجتمع الشيطاني البنزويل
+
+206
+00:19:44,260 --> 00:19:51,060
+الكلورايد هو حقيقة أرحم ما يمكن أن يُقذَف على
+
+207
+00:19:51,060 --> 00:19:54,820
+الناس اليوم بيستعملوا غازات أعصاب و بيستعملوا
+
+208
+00:19:54,820 --> 00:20:00,520
+غازات دموع مخلوطة بغازات أعصاب بنسب قليلة و كلها
+
+209
+00:20:00,520 --> 00:20:05,440
+أشد تأثيرا من البنزويل الكلورايد يعني أشرف غازات
+
+210
+00:20:05,440 --> 00:20:12,460
+للمظاهراتالبنزوليكلوريد وما عداها أكثر شدة وأكثر
+
+211
+00:20:12,460 --> 00:20:16,960
+إجراما وعشان ذلك لاحظوا أننا لما حكينا على
+
+212
+00:20:16,960 --> 00:20:20,620
+الخواصلة ال acid helites in general قلنا noxious
+
+213
+00:20:20,620 --> 00:20:27,580
+يعني مهيجة irritating بتعمل إصابات أو جروح react
+
+214
+00:20:27,580 --> 00:20:33,660
+violently with water بتتفاعل بقوة مع الميه معطية
+
+215
+00:20:33,660 --> 00:20:41,830
+الحامض الأصلي زائدالـ HCL نيجي
+
+216
+00:20:41,830 --> 00:20:47,760
+للعائلة اللي بعدهامن ال derivatives اللي هي ال
+
+217
+00:20:47,760 --> 00:20:53,660
+acid anhydrides ال acid anhydrides بتيجي من تفاعل
+
+218
+00:20:53,660 --> 00:20:59,940
+جزيئين من الحامض مع بعضهم البعض لاحظوا في موضوع ال
+
+219
+00:20:59,940 --> 00:21:04,500
+acid anhydrides من ناحية المبدأ من ناحية المبدأ
+
+220
+00:21:04,500 --> 00:21:12,330
+هناك شبه الطالب المنتبه بموضوع ال etherبموضوع إيش
+
+221
+00:21:12,330 --> 00:21:17,470
+ال ether إذا بتتذكروا لما كنا نتكلم عن ال ether
+
+222
+00:21:17,470 --> 00:21:21,390
+قسمنا ال ethers إلى نوعين قلنا في عندنا
+
+223
+00:21:21,390 --> 00:21:28,510
+symmetrical ethers و unsymmetrical ethersإذا كانت
+
+224
+00:21:28,510 --> 00:21:33,090
+الـR و الـR زي بعض هذا سمنا إيش؟ symmetrical ether
+
+225
+00:21:33,090 --> 00:21:38,030
+و لذلك لما كنا مثلا بدنا نضاي إيثل إيثر كنا ناخد
+
+226
+00:21:38,030 --> 00:21:42,370
+الكحول مش الحامض في النهاية في OH اللي هو على سبيل
+
+227
+00:21:42,370 --> 00:21:50,450
+المثال لو أخدنا الإيثانول بنسبة 2 مع H plus هو نفس
+
+228
+00:21:50,450 --> 00:21:58,660
+الفكرة تماما إيش كان هذا يعطينا؟ إيثل أوDiethyl
+
+229
+00:21:58,660 --> 00:22:03,100
+ether من
+
+230
+00:22:03,100 --> 00:22:09,660
+الكحول و Diethyl ether is symmetrical ether رور
+
+231
+00:22:11,320 --> 00:22:14,800
+شوف نقاش ال symmetrical فالكحول بيتفاعل مع نفسه
+
+232
+00:22:14,800 --> 00:22:19,800
+جوزيق بيهاجم على التاني و بيطرده مية و بتفاعله
+
+233
+00:22:19,800 --> 00:22:25,960
+الان الكلام نفسه بتم مع ال unhydrates لكن في هذه
+
+234
+00:22:25,960 --> 00:22:32,280
+الحالة الحامض بيتفاعل مع نفسهواضح؟ في هذه الحالة
+
+235
+00:22:32,280 --> 00:22:36,680
+الحامض يتفاعل مع نفسه يعني احنا اليوم موضوعنا ال
+
+236
+00:22:36,680 --> 00:22:41,000
+unhydrates لو بدأ اركز اكثر عليها بدأ اقول تخيلوا
+
+237
+00:22:41,000 --> 00:22:47,120
+ان هذا جزيق حامض بدأ افعله مع ايش؟ مع جزيق تاني
+
+238
+00:22:47,120 --> 00:22:54,980
+اللي هو OH سيضة بال bond Oنفترض CH3 هاي Acetic
+
+239
+00:22:54,980 --> 00:23:00,040
+Acid جزئ و هاي Acetic Acid كمان جزئ هاي الجزئين
+
+240
+00:23:00,040 --> 00:23:04,740
+خلصنا واضح؟ الآن هذا بده ييجي من خلال الـ OH اللي
+
+241
+00:23:04,740 --> 00:23:10,620
+هي الـ nucleophile إهاجمها يطرد الـ OH هذا تفاعل
+
+242
+00:23:10,620 --> 00:23:15,380
+الإبدال ولا لأ؟ هذا تفاعل الإبدال بناء على ذلك لما
+
+243
+00:23:15,380 --> 00:23:18,920
+تطرد الـ OH من هنا مع الـ H هذه
+
+244
+00:23:21,660 --> 00:23:29,940
+الجزء الأول اللي مبين بالأسود هي CH3COO
+
+245
+00:23:29,940 --> 00:23:35,100
+والجزء التاني OCOO
+
+246
+00:23:36,520 --> 00:23:42,080
+CH3 هيتكون عندى الـ Symmetrical Anhydride اتكون
+
+247
+00:23:42,080 --> 00:23:46,840
+عندى الـ Symmetrical Anhydride لاحظوا انه مجموعة
+
+248
+00:23:46,840 --> 00:23:52,840
+الانهيدريد كمجموعة عبارة عن ايش C double bond O O
+
+249
+00:23:52,840 --> 00:23:57,580
+C double bond O يعني لو بدى اقول ال ether كانت O
+
+250
+00:23:57,580 --> 00:24:03,620
+متصلة بتنتين R طيب الانهيدريد هى
+
+251
+00:24:06,590 --> 00:24:13,350
+هذه ثابتة C double bond O O C double bond O هذه
+
+252
+00:24:13,350 --> 00:24:17,670
+مجموعة الانهيدريد الآن لما فعلت الحامض مع نفسه
+
+253
+00:24:17,670 --> 00:24:23,890
+صارت هذه ال R و هذه ال R زي بعض ولذلك سميت هذا
+
+254
+00:24:23,890 --> 00:24:28,530
+symmetrical anhydride الآن السؤال طب لو خلت هذه
+
+255
+00:24:28,530 --> 00:24:33,690
+مثل وهذه اثلبتصير Unsymmetrical لو خلّيت فينيل و
+
+256
+00:24:33,690 --> 00:24:40,130
+إثل Unsymmetrical طبعا بيلزمنا نسمي و نحضر ال
+
+257
+00:24:40,130 --> 00:24:43,210
+symmetrical anhydride و الunsymmetrical anhydride
+
+258
+00:24:43,210 --> 00:24:47,050
+تماما زي ما عملنا مع ال aether احنا قولنا ال
+
+259
+00:24:47,050 --> 00:24:49,870
+aether كان الكحول مع نفسه أعطاني symmetrical
+
+260
+00:24:49,870 --> 00:24:54,350
+aether الآن ال symmetrical anhydride الحامض مع
+
+261
+00:24:54,350 --> 00:24:57,350
+نفسه بنسخنه في وجود حمض
+
+262
+00:25:00,190 --> 00:25:06,170
+بش ان مش واضح بنسخنه في وجود حمض و طبعا بنتخلي
+
+263
+00:25:06,170 --> 00:25:09,610
+شروط التفاعل تسحب الميه للخارج ليش؟ لأن هذا
+
+264
+00:25:09,610 --> 00:25:13,510
+التفاعل ما عدا ذلك عكس بترد الميه تهاجمها و ترجع
+
+265
+00:25:13,510 --> 00:25:17,230
+لحمضين ولذلك اللي بيعمل unhydrate بيكون عنده طريقة
+
+266
+00:25:17,230 --> 00:25:22,160
+يسحب فيها الميه لوينل الخارج يتخلص منها طب الآن
+
+267
+00:25:22,160 --> 00:25:27,640
+هذا كيف بدي أسميه على اسم الحامض بشيل كلمة acid و
+
+268
+00:25:27,640 --> 00:25:32,880
+بكتب unhydrate يعني هذا لو سمناه ethanoic acid ال
+
+269
+00:25:32,880 --> 00:25:37,700
+unhydrate تبعه إيش بدي يصير ethanoic unhydrate طب
+
+270
+00:25:37,700 --> 00:25:43,820
+لو سمناه بال common name acetic acid إيش بدي يتسمى
+
+271
+00:25:44,770 --> 00:25:53,230
+acetic anhydride فالتسمية إن نشيل كلمة
+
+272
+00:25:53,230 --> 00:25:59,850
+acid ونحط anhydride واضح التسمية إن نشيل كلمة acid
+
+273
+00:25:59,850 --> 00:26:04,250
+ونحط إيش anhydride الحامض اللي فيه المثل هو
+
+274
+00:26:04,250 --> 00:26:12,990
+الaceticالان لو اجينا وقلنالكم لو سمحتوا ارسمولنا
+
+275
+00:26:12,990 --> 00:26:20,510
+المركب القاتل بنزوك unhydrate بنزوك
+
+276
+00:26:20,510 --> 00:26:29,870
+unhydrate اول اشي ع طول بدكم تحطولي ايش هي مجموعة
+
+277
+00:26:29,870 --> 00:26:35,670
+ال unhydrate مجموعة ال unhydrate C double bond O O
+
+278
+00:26:37,550 --> 00:26:42,130
+خلّينا نعملها هيك C double bond O تابع هذه مجموعة
+
+279
+00:26:42,130 --> 00:26:47,810
+الانهيدريد الآن إذا كانت بنزوك فنل معناه ذلك سأضع
+
+280
+00:26:47,810 --> 00:26:55,250
+على الجهتين مجموعة الفنل فنل و فنل هذه بنزوك
+
+281
+00:26:55,250 --> 00:27:00,350
+انهيدريد لما نقول أسيتك مثل و مثل المجموعة تبع
+
+282
+00:27:00,350 --> 00:27:02,550
+الأسيتك أسيتك بروبانوك
+
+283
+00:27:07,410 --> 00:27:12,490
+بدوا يكون المجموع تلاتة اه انتبهوا معاك خلصنا من
+
+284
+00:27:12,490 --> 00:27:20,310
+ال benzoic اه اه لو اتيتكن اتكتبلكم بروبانوك لأنه
+
+285
+00:27:20,310 --> 00:27:25,810
+مرات بيغلطوا الطلاب بهذه النقطة بروبانوك unhydrate
+
+286
+00:27:25,810 --> 00:27:33,950
+بدي الكربونات تلاتة هذه واحدة منهمهذه واحدة و لذلك
+
+287
+00:27:33,950 --> 00:27:38,310
+لما كان عند ال E ثانوك كنت بس حاطط ال CH3 المجموع
+
+288
+00:27:38,310 --> 00:27:45,430
+تنتين لما بدل بربانوك بدأ اكتب CH2 CH3 المجموع
+
+289
+00:27:45,430 --> 00:27:54,830
+تلاتة و هنا CH2 CH3 واضح فالمجموع تلاتة بربانوك و
+
+290
+00:27:54,830 --> 00:28:01,830
+مثلها بيوتانوك واضحةطيب الآن يا تورا الكلام شوفوا
+
+291
+00:28:01,830 --> 00:28:08,370
+كيف ما أسهل الكيميا ولا أمتعها بتفهم لحالها لو
+
+292
+00:28:08,370 --> 00:28:19,610
+إجيت و روحت كتبتلكم هنا CH3 و كتبتلكم هنا فنل و
+
+293
+00:28:19,610 --> 00:28:21,810
+قلتلكوا سموا هذا المركب
+
+294
+00:28:27,020 --> 00:28:34,240
+هذا مكون من كام حامض؟ هذا الحامض شو هو؟
+
+295
+00:28:42,280 --> 00:28:47,600
+جيد جيد هذا التردد .. هذا التردد بحل مشكلتك الناس
+
+296
+00:28:47,600 --> 00:28:50,380
+اللي سألوني عن الامتحان لأ في الامتحان مش عامليني
+
+297
+00:28:50,380 --> 00:28:55,120
+كويس لإن مصيرين ما تسمعوش نصيحتي إن إذا في الكيميا
+
+298
+00:28:55,120 --> 00:29:00,400
+ما طبقتوش و ما كتبتوش الجملة ألف مرة لن تتعلموا
+
+299
+00:29:00,400 --> 00:29:05,340
+كيميا تمام؟ لن تتعلموا كيميا هذا اللي فيه تنتين
+
+300
+00:29:05,340 --> 00:29:12,810
+اثانوك و بال common أسيتكمظبوط ولا لأ؟ هذا كحمد
+
+301
+00:29:12,810 --> 00:29:19,010
+CH3C double bond O إيش ماله؟ Acetic و هذا الفنل C
+
+302
+00:29:19,010 --> 00:29:23,430
+double bond O بنزوك و خلّيني أحطهم alphabetical
+
+303
+00:29:23,430 --> 00:29:28,190
+مين بيجي قبل ال Acetic ولا ال بنزوك؟ Acetic بنزوك
+
+304
+00:29:28,190 --> 00:29:29,850
+Unhydrate
+
+305
+00:29:31,620 --> 00:29:35,840
+واضح؟ بذكر اسم الحامضين و بحطه ممرتبين
+
+306
+00:29:35,840 --> 00:29:40,520
+alphabetically فبكون هيك اقدرت اسمي ال
+
+307
+00:29:40,520 --> 00:29:47,620
+unsymmetrical .. unhydrite .. واضح؟أسيتك بنزوك
+
+308
+00:29:47,620 --> 00:29:51,080
+أنهايدرايد طبعا واحدة ممكن تقول ممكن نسميه إيثانوك
+
+309
+00:29:51,080 --> 00:29:56,060
+ممكن موادة كاربون تنتيل إيثانوك و أجي تبدأ تكتب
+
+310
+00:29:56,060 --> 00:30:01,740
+بنزوك إيثانوك أنهايدرايد عشان تحط ال B قبل ال E
+
+311
+00:30:01,740 --> 00:30:06,920
+alphabeticalإذا إعرفنا كيف بنسمي الـ unsymmetrical
+
+312
+00:30:06,920 --> 00:30:12,680
+anhydride بذكر الحامضين alphabetically وإضافة
+
+313
+00:30:12,680 --> 00:30:18,860
+النهاية anhydride الآن إذا هذا الكلام إعرفنا كيف
+
+314
+00:30:18,860 --> 00:30:26,860
+نسميه، ضال كيف؟ انحضروه، ضال كيف انحضروه اللي
+
+315
+00:30:26,860 --> 00:30:34,400
+فاهمين الethers، إيش كنا نعمل فيهم؟نفس الفكرة
+
+316
+00:30:34,400 --> 00:30:39,520
+تماما اللي اتذكره William Sun William Sun's
+
+317
+00:30:39,520 --> 00:30:44,320
+synthesis of ethers هل يا تورا كنت بقدر انا اجي
+
+318
+00:30:44,320 --> 00:30:55,280
+اقول Methanol زائد Ethanol بالحرارة و الحامض هذا
+
+319
+00:30:55,280 --> 00:31:01,790
+كام مركب كام Ether كان يعطيليكان يعطيني تلاتة مثل
+
+320
+00:31:01,790 --> 00:31:11,130
+او مثل او اثل او اثل او مثل او اثل طب هتقول هذا ال
+
+321
+00:31:11,130 --> 00:31:16,610
+synthesis مقبول ولا لأ مرفوض في ال ethers مرفوض
+
+322
+00:31:16,610 --> 00:31:19,650
+لان انا بدي اطلع تلاتة و اقعد افصلهم طب كيف كنا
+
+323
+00:31:19,650 --> 00:31:24,810
+نعمل كنا نقول خلي واحد منهم يصير مثل او minus
+
+324
+00:31:24,810 --> 00:31:33,920
+التاني يصير اثل CLCH3 CH2 CL نبدل ال OH بCL مثلا
+
+325
+00:31:33,920 --> 00:31:39,000
+من PCL3 و بعدين نفعل هدول التنين مع بعض كانوا
+
+326
+00:31:39,000 --> 00:31:45,980
+بيعطوني بس المثل O Ethan واضح؟
+
+327
+00:31:45,980 --> 00:31:52,720
+واحد نخليه O minus والتاني نخليه CL و نخلطهم هيك
+
+328
+00:31:52,720 --> 00:32:00,300
+بيعطيني فقطناتج واحد لا غير بضحك الفكرة؟ هذه إيش
+
+329
+00:32:00,300 --> 00:32:06,500
+كان اسمها؟ طريقة William Sun لتحضير ال ether الآن
+
+330
+00:32:06,500 --> 00:32:13,220
+لما بدي أحضر ال un-symmetrical unhydride نفسها
+
+331
+00:32:13,220 --> 00:32:19,520
+تماما 100% لكن بدل ما أنا مبتدئ بكحول في ال
+
+332
+00:32:19,520 --> 00:32:25,140
+unhydride بدي أبتدئ من إيش؟من الـ Acid خلّيني أقول
+
+333
+00:32:25,140 --> 00:32:29,460
+بدي مثلا الـ Acetic Benzoic Anhydrate إذا إيش
+
+334
+00:32:29,460 --> 00:32:37,300
+الحامضين اللي بدي أبتدأ منهم Acetic Acid هاي CH3C
+
+335
+00:32:37,300 --> 00:32:44,280
+double bond O OH زائد Benzoic Acid Phenyl C double
+
+336
+00:32:44,280 --> 00:32:53,200
+bond O OH الآن لو خلطناهم بـ H Plus و Heatكم ناتج
+
+337
+00:32:53,200 --> 00:32:58,880
+الـ three products بنفع هذا الكلام مقبول اللي بعمل
+
+338
+00:32:58,880 --> 00:33:03,060
+زي هيك ايش بيكون بيشتغل غلط ال three products
+
+339
+00:33:03,060 --> 00:33:07,580
+موازية تماما لفكرة ال ethers الان واحد منهم بدنا
+
+340
+00:33:07,580 --> 00:33:11,220
+نخلي O minus نفترض هذا
+
+341
+00:33:13,840 --> 00:33:19,860
+CH3C double bond O O minus والتاني بدنا نخلي CL
+
+342
+00:33:19,860 --> 00:33:26,220
+فنل C double bond O CL هدولة لما نخلطهم بده يطلع
+
+343
+00:33:26,220 --> 00:33:33,700
+عندنا ناتج واحد فقط نرسمها CH3C double bond O O C
+
+344
+00:33:33,700 --> 00:33:41,680
+double bond O فنل على أساس أن هذه بتهاجمها و بتطرد
+
+345
+00:33:42,840 --> 00:33:48,240
+الـ Cl واضح؟ طبعا ممكن حد يقول كيف هذا بنحول ال
+
+346
+00:33:48,240 --> 00:33:54,840
+acid ال acid ل O minus بالتفاعل مع N A O H حمزاد
+
+347
+00:33:54,840 --> 00:33:55,680
+قاعدة
+
+348
+00:33:59,270 --> 00:34:03,890
+NA قدش كتير عليه دائما مستعمل أقل شغلة مع ال NA
+
+349
+00:34:03,890 --> 00:34:08,170
+هياعمل حريقة هيكون التفاعل violent مع ال NA و لا
+
+350
+00:34:08,170 --> 00:34:14,470
+مع ال NA او ال NA قدش كتير عليه هيعمل حريقةمع ال N
+
+351
+00:34:14,470 --> 00:34:17,470
+A و N A H ماشي الحمض يتفاعل مع ال N A و N A H
+
+352
+00:34:17,470 --> 00:34:21,570
+الكحول هداج زنبه ع جنبه مكانش يتفاعل مع ال N A و N
+
+353
+00:34:21,570 --> 00:34:26,970
+A H ولذلك استعملتله N A و N A H لكن الحمض بتفاعل
+
+354
+00:34:26,970 --> 00:34:31,670
+مع ال N A و N A H ولا لأ بتفاعل و هذا بي سي ال
+
+355
+00:34:31,670 --> 00:34:37,050
+اثنين اذا حامض طبعا واحدة ممكن تسأل انواع نخلي O
+
+356
+00:34:37,050 --> 00:34:42,970
+minus وانواع C L مش فارقفى ال ethers كان فارق ال
+
+357
+00:34:42,970 --> 00:34:48,330
+CL بنا نخليه ال primary هنا مش فارق واحد بخليه O
+
+358
+00:34:48,330 --> 00:34:55,210
+minus والتانى بخليه CL و بعدين بفعلهم هيطلع عندى
+
+359
+00:34:55,210 --> 00:35:01,650
+ال unsymmetrical anhydride
+
+360
+00:35:01,650 --> 00:35:10,810
+واضحة الفكرةوهي طريقة تحضير الـ Acidic Benzoic
+
+361
+00:35:10,810 --> 00:35:16,290
+Anhydride فيه أوضح من هيك؟ مرة جيبناها سؤال هذا
+
+362
+00:35:16,290 --> 00:35:20,230
+المركب، قولنا للطلاب سمي المركب التالي واذكر طريقة
+
+363
+00:35:20,230 --> 00:35:27,250
+تحضيره، ما جوابوش عشرة في المية، بتصدقوا؟ ليش؟لأنه
+
+364
+00:35:27,250 --> 00:35:31,370
+مابيطبقوش مابيعدوش الكتابة خمس مرات لحد ما إيدهم
+
+365
+00:35:31,370 --> 00:35:36,830
+تتعود على الكيميا ولذلك لو بدكوا تطلعوا على سبيل
+
+366
+00:35:36,830 --> 00:35:42,270
+المثال هذا الكلام جيد إنه الكل يسمعوا حتى الناس
+
+367
+00:35:42,270 --> 00:35:46,470
+اللي بيشاهدوا الفيديو الطالب اللي مابيكتب كيميا
+
+368
+00:35:46,470 --> 00:35:53,090
+كتيرما بيكتب كيميا كتير هذا فن بحاجة إلى تدريب
+
+369
+00:35:53,090 --> 00:36:00,310
+ولذلك قد تستغربوا انه لما جيبنالكم بنزين وقلنا
+
+370
+00:36:00,310 --> 00:36:06,890
+حطوا عليها بس مجموعة إثل زي هيك يعني كتبنا CH3
+
+371
+00:36:06,890 --> 00:36:15,070
+CH2Cl في وجود الـFeCl3 تمام؟
+
+372
+00:36:16,720 --> 00:36:24,060
+الآن بنسبة 70% منكم عندهم فهم ولكن عندهم خطأ في
+
+373
+00:36:24,060 --> 00:36:28,300
+التنفيذ لأنهم مادربوش إيديهم يكتبوا كان الجواب
+
+374
+00:36:28,300 --> 00:36:40,280
+اللي كتب بهذا الشكل الان
+
+375
+00:36:40,280 --> 00:36:44,720
+انتوا بتحكوا لكن انا عندى إحصائيةأنا بعمل إحصائية
+
+376
+00:36:44,720 --> 00:36:49,560
+كيف بتكتبوا، 70% منكم كتبوا بهذا الشكل، لا هذه ال
+
+377
+00:36:49,560 --> 00:36:53,780
+carbon أربع روابط ولا هذه أربع روابط ولا محل مكانة
+
+378
+00:36:53,780 --> 00:36:59,280
+ال CL عملوا التفاعل كل هذه الأشياء ليش؟ لأنه مافيش
+
+379
+00:36:59,280 --> 00:37:05,900
+تطبيق، الأصل أنه هنا نكون كاتبين CH2 CH3
+
+380
+00:37:07,280 --> 00:37:14,480
+الان لما جيبنالكم فاعله مع CH3CWOCL الاصل بدكوا
+
+381
+00:37:14,480 --> 00:37:23,960
+تحطه من هنا من محل ال CL يعني تحطه CWOCL
+
+382
+00:37:23,960 --> 00:37:31,560
+ربما خمسين في المية منكم حطوا هنا CWO وحطوا هنا
+
+383
+00:37:31,560 --> 00:37:40,360
+CH3 بهذا الشكل بهذا الشكللا تحزروا روسكو و إلا
+
+384
+00:37:40,360 --> 00:37:44,380
+بجيب الورق و بفرجيكوا إياه ليش؟ لأنه ماصارش عندكم
+
+385
+00:37:44,380 --> 00:37:49,140
+تطبيق اللي بيدخل على كلية علمية جامعية بده يتعب و
+
+386
+00:37:49,140 --> 00:37:54,980
+هو بيطبق و يكتب كتير و يتعب كتير عشان يشتغل صح لكن
+
+387
+00:37:54,980 --> 00:37:59,020
+هذا الكلام خمسين في المية يمكن كتبوه من الطالبات و
+
+388
+00:37:59,020 --> 00:38:02,440
+هذا الكلام اللي كان تول سبعين في المية من الطالبات
+
+389
+00:38:02,440 --> 00:38:07,760
+كتبوه ليش؟ لأنهم بدهم يقرؤوا ال organic قراءة
+
+390
+00:38:08,820 --> 00:38:14,640
+أدبيات الرافعي الرافعي يقرأ استلقاء و ال organic
+
+391
+00:38:14,640 --> 00:38:28,580
+تقرأ كتابة و تطبيقا واضحة الفكرة هاي
+
+392
+00:38:28,580 --> 00:38:36,210
+ال acid anhydride الان لاحظوا من الأحماضاللي
+
+393
+00:38:36,210 --> 00:38:42,090
+درسناها ال die acids يعني يكون عندى حامضين في نفس
+
+394
+00:38:42,090 --> 00:38:49,250
+الجزء أخدنا لما يكون عندى أربع ذرات كربون الحامض
+
+395
+00:38:49,250 --> 00:38:53,750
+اللى بيكون بال sis form اسمه malic acid و اللى بال
+
+396
+00:38:53,750 --> 00:39:01,690
+transform يهودا ايوة اللى بال transform زى هذا شو
+
+397
+00:39:01,690 --> 00:39:02,450
+اسمه؟
+
+398
+00:39:15,400 --> 00:39:21,740
+لاحظوا أفضل واحدة فيكم برضه نتيجة عدم التطبيق جابت
+
+399
+00:39:21,740 --> 00:39:26,200
+زرع من الإسم وأكيد لو كانت متحة هيكون خطأ جالت
+
+400
+00:39:26,200 --> 00:39:31,680
+فورمك لكن تأكيدا والمحاضرات ابتشرت عليكم اسمه
+
+401
+00:39:31,680 --> 00:39:39,850
+fumaric acidmalic acid و fumaric acid شوفتوا كيف
+
+402
+00:39:39,850 --> 00:39:44,830
+التطبيق بيفرق عندنا أكيد لو ارجعنا أول ما أخدنا ال
+
+403
+00:39:44,830 --> 00:39:49,130
+die acids حكيناهم و قولنا واحد بناخده من التفاح و
+
+404
+00:39:49,130 --> 00:39:54,650
+التاني من الأغنام و كل هذا الكلام لكن كم مرة كتبت
+
+405
+00:39:54,650 --> 00:39:58,990
+أنا شكل ال malic acid و ال fumaric acid ولا مرة
+
+406
+00:39:58,990 --> 00:40:05,280
+كيف بدي أتذكرهممش هتذكرهم الان لاحظوا معي المالية
+
+407
+00:40:05,280 --> 00:40:12,040
+كان SIS الفيومارك كانت Trans يعني كان في مجمعتين
+
+408
+00:40:12,040 --> 00:40:18,810
+ال OHSمجمعتين ال acid بعاد عن بعض الان هذا مركب ال
+
+409
+00:40:18,810 --> 00:40:24,370
+cess لو سخنته انا عند 135 حامض بتفعلها حامض هذه
+
+410
+00:40:24,370 --> 00:40:29,210
+بتيجي هان و بتطرد ال OH بتعطيني unhydrate لما بدي
+
+411
+00:40:29,210 --> 00:40:34,930
+اسميه شو هسميه مليك unhydrate مليك قولنا كمان و
+
+412
+00:40:34,930 --> 00:40:38,410
+أكدنا انه بنستعمل ال E اللي هي تعبير على ال alkyl
+
+413
+00:40:38,410 --> 00:40:45,220
+وقولنا الملكحمض تاني بدون ال E حامض تاني ملك acid
+
+414
+00:40:45,220 --> 00:40:52,660
+موجود ومليك acid موجود واضح؟ الان لو اجت واحدة
+
+415
+00:40:52,660 --> 00:40:59,880
+سخنت هذا الحامض بالحرارة ايش رأيكوا هيصير؟ هيعمل
+
+416
+00:40:59,880 --> 00:41:04,540
+unhydrate مع نفسه؟
+
+417
+00:41:04,540 --> 00:41:09,720
+يعني هذه تهاجم هنا؟ ليش؟
+
+418
+00:41:10,730 --> 00:41:16,310
+لأن هم بعاد .. لأن هم بعاد .. طيب بتقولون ما بتلف
+
+419
+00:41:16,310 --> 00:41:21,030
+حوالين ال double bond .. الدوران حوالين ال double
+
+420
+00:41:21,030 --> 00:41:28,300
+bond .. ممنوع .. ولذلك تسخين الماليك أسدبيعمل
+
+421
+00:41:28,300 --> 00:41:33,920
+unhydrate تسخين لثيوميرك أسد بيعملش unhydrate فلو
+
+422
+00:41:33,920 --> 00:41:37,920
+انتوا اتطلعتوا في كاتالوجي الكيميا بتلاقوا مركب
+
+423
+00:41:37,920 --> 00:41:42,580
+اسمه مليك unhydrate بس بتلاقوش مركب اسمه ثيوميرك
+
+424
+00:41:42,580 --> 00:41:49,100
+unhydrate لأن مجمعتين ال OHS ابعاد عن بعضهم البعض
+
+425
+00:41:49,100 --> 00:41:54,890
+واضح فمش هيصل يتفاعلوا مع بعضهم البعضالان نفس
+
+426
+00:41:54,890 --> 00:42:01,430
+الفكرة تماما لو اجيت على مجموعتين acid موجودات على
+
+427
+00:42:01,430 --> 00:42:09,450
+بنزينة قولت هدول المجموعتين كيف يمكن ان يوجدوا يا
+
+428
+00:42:09,450 --> 00:42:16,170
+اما واحد اتنين اورثو يا واحد تلاتة ميتا يا واحد
+
+429
+00:42:16,170 --> 00:42:21,520
+اربعة باراتمام يعني غير هذا اللي موجود المجموعتين
+
+430
+00:42:21,520 --> 00:42:26,580
+على واحد اتنين ايضا موجود انه يكونوا مجموعتين ال
+
+431
+00:42:26,580 --> 00:42:34,900
+acid COOH و COOH على نمرة واحد واحد اتنين تلاتة
+
+432
+00:42:34,900 --> 00:42:40,860
+وموجود كمان انهم يكونوا على نمرة واحد واربعة COOH
+
+433
+00:42:40,860 --> 00:42:48,750
+مثلا و COOH واحد اتنين تلاتة اربعةهدولة التلت
+
+434
+00:42:48,750 --> 00:42:54,170
+أحماض موجودين و سمناهم اللي على ال Ortho سمناه
+
+435
+00:42:54,170 --> 00:43:00,950
+Phthalic Acid و اللي على ال NETA Isophthalic Acid
+
+436
+00:43:00,950 --> 00:43:05,910
+و اللي على البارا Terephthalic Acid و قولنالكوا
+
+437
+00:43:05,910 --> 00:43:11,010
+احفظوهم الآن لو يا ترى إجينا نسخن هدولة التلاتة
+
+438
+00:43:11,010 --> 00:43:17,070
+مين فكركوا منهم اللي ممكن يعمل Unhydrate؟الأورثو
+
+439
+00:43:17,070 --> 00:43:22,990
+ولا النيتا ولا البارا بس الأورثو لأن هدول بعاد عن
+
+440
+00:43:22,990 --> 00:43:29,090
+بعض مابيجوش فهذا بيعملش أنهيدريد ال isothelic acid
+
+441
+00:43:29,090 --> 00:43:33,010
+و ال teraphthalic acid بيعملش أنهيدريد هذا بيعمل
+
+442
+00:43:33,010 --> 00:43:39,150
+أنهيدريد لو قلنالكوا أرسم الانهيدريد الناتجهي
+
+443
+00:43:39,150 --> 00:43:45,690
+البنزينة عندى C double bond O و هنا C double bond
+
+444
+00:43:45,690 --> 00:43:52,570
+O و بينهم O هى مجموعة الانهيدريد C double bond O O
+
+445
+00:43:52,570 --> 00:43:58,850
+C double bond O و هذا بيصير ايش اسمه افثالك
+
+446
+00:43:58,850 --> 00:44:01,810
+انهيدريد
+
+447
+00:44:04,120 --> 00:44:12,560
+أفثالك أنهايدرايد واضح طبعا
+
+448
+00:44:12,560 --> 00:44:16,960
+هذه ال mix انهايدرايد حكينا عنها كيف بتتحضر واحد O
+
+449
+00:44:16,960 --> 00:44:20,520
+minus والتاني CL وهي تسميتهم acidic benzoic
+
+450
+00:44:20,520 --> 00:44:22,060
+anhydride حكينا عنه
+
+451
+00:44:29,520 --> 00:44:36,740
+طبعا لو كنا بدنا ندرس تفاعلات الانهيدريد واحدة
+
+452
+00:44:36,740 --> 00:44:40,340
+تختصر تفاعلات الانهيدريد بكلمة شو هتقول عنهم
+
+453
+00:44:40,340 --> 00:44:47,660
+substitution reaction طبعا ال substitution بده يتم
+
+454
+00:44:47,660 --> 00:44:56,020
+هان و نطرد كل هذه المجموعة بتخرج على شكل إيشحمض مع
+
+455
+00:44:56,020 --> 00:45:00,360
+الأموليا بيعطيني أمد مثلا مع الكحول بيعطيني Easter
+
+456
+00:45:00,360 --> 00:45:05,240
+مع الميه بيعطيني ال acid التاني و هكذا من هذه
+
+457
+00:45:05,240 --> 00:45:09,960
+النقطة ان شاء الله المرة القادمة بنبدأ بنأكد عليها
+
+458
+00:45:09,960 --> 00:45:14,960
+بس بتكونوا تدربتوا عليها تفاعلات ال acid
+
+459
+00:45:14,960 --> 00:45:18,000
+anhydrides بال substitution بالإبدال
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/fva5m01JkUs_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/fva5m01JkUs_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..8a06adf79a4985df8d654ffe7d661b3938145a66
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/fva5m01JkUs_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2102, "start": 19.62, "end": 21.02, "text": "بسم الله الرحمن الرحيم", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640], "avg_logprob": -0.03342285230755806, "compression_ratio": 1.0789473684210527, "no_speech_prob": 0.0, "words": [{"start": 19.62, "end": 20.02, "word": "بسم", "probability": 0.91259765625}, {"start": 20.02, "end": 20.22, "word": " الله", "probability": 0.9716796875}, {"start": 20.22, "end": 20.58, "word": " الرحمن", "probability": 0.9777018229166666}, {"start": 20.58, "end": 21.02, "word": " الرحيم", "probability": 0.99365234375}], "temperature": 1.0}, {"id": 2, "seek": 5184, "start": 22.74, "end": 51.84, "text": "مازلنا احنا بنتكلم في موضوع الأحماض ومشتقاتها المرة الماضية اتكلمنا عن ال E-stars وطرق تحضيرهم وبدأنا في موضوع تفاعلات ال E-stars قولنا أول شيء أن التفاعل الأساسي اللي هيتكرر معنا في كل هذا الفصل للأحماض وجميع مشتقاتها وتفاعل الإجدال فكان أول تفاعل أخدناه عن ال E-stars ال ammonolysis يعني أن نبدل ال OR", 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"end": 1244.39, "text": "الـ HCL نيجي للعائلة اللي بعدها", "tokens": [6027, 39184, 389, 22458, 8717, 1829, 7435, 1829, 24976, 3615, 16373, 37977, 13672, 1829, 45030, 3215, 11296], "avg_logprob": -0.2879774272441864, "compression_ratio": 0.9310344827586207, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1236.29, "end": 1236.69, "word": "الـ", "probability": 0.8759765625}, {"start": 1236.69, "end": 1237.25, "word": " HCL", "probability": 0.5880126953125}, {"start": 1237.25, "end": 1241.83, "word": " نيجي", "probability": 0.77044677734375}, {"start": 1241.83, "end": 1243.55, "word": " للعائلة", "probability": 0.8154296875}, {"start": 1243.55, "end": 1243.75, "word": " اللي", "probability": 0.858642578125}, {"start": 1243.75, "end": 1244.39, "word": " بعدها", "probability": 0.7568359375}], "temperature": 1.0}, {"id": 54, "seek": 127032, "start": 1245.2, "end": 1270.32, "text": "من ال derivatives اللي هي ال acid anhydrides ال acid anhydrides بتيجي من تفاعل جزيئين من الحامض مع بعضهم البعض لاحظوا في موضوع ال acid anhydrides من ناحية المبدأ من ناحية المبدأ هناك شبه الطالب المنتبه بموضوع ال ether", "tokens": [27842, 2423, 33733, 13672, 1829, 39896, 2423, 8258, 18931, 6655, 81, 1875, 2423, 8258, 18931, 6655, 81, 1875, 39894, 1829, 7435, 1829, 9154, 6055, 5172, 995, 30241, 10874, 11622, 1829, 19986, 9957, 9154, 21542, 10943, 11242, 20449, 45030, 11242, 16095, 29739, 3615, 11242, 20193, 5016, 19913, 14407, 8978, 3714, 2407, 11242, 45367, 2423, 8258, 18931, 6655, 81, 1875, 9154, 8717, 39319, 10632, 9673, 44510, 10721, 9154, 8717, 39319, 10632, 9673, 44510, 10721, 34105, 4117, 13412, 3555, 3224, 41950, 6027, 3555, 9673, 29399, 3555, 3224, 4724, 2304, 2407, 11242, 45367, 2423, 37096], "avg_logprob": -0.10011888773221037, "compression_ratio": 1.9096045197740112, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1245.2, "end": 1245.62, "word": "من", "probability": 0.7158203125}, {"start": 1245.62, "end": 1246.48, "word": " ال", "probability": 0.73974609375}, 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"text": "نفترض CH3 هاي Acetic Acid جزئ و هاي Acetic Acid كمان جزئ هاي الجزئين خلصنا واضح؟ الآن هذا بده ييجي من خلال الـ OH اللي هي الـ nucleophile إهاجمها يطرد الـ OH هذا تفاعل الإبدال ولا لأ؟ هذا تفاعل الإبدال بناء على ذلك لما تطرد الـ OH من هنا مع الـ H هذه", "tokens": [1863, 5172, 2655, 43042, 5995, 18, 8032, 47302, 5097, 3532, 5097, 327, 10874, 11622, 19986, 4032, 8032, 47302, 5097, 3532, 5097, 327, 9122, 2304, 7649, 10874, 11622, 19986, 8032, 47302, 25724, 11622, 19986, 9957, 16490, 1211, 9381, 8315, 4032, 46958, 5016, 22807, 6024, 48506, 23758, 47525, 3224, 7251, 1829, 7435, 1829, 9154, 16490, 1211, 6027, 2423, 39184, 13931, 13672, 1829, 39896, 2423, 39184, 14962, 49242, 11933, 3224, 26108, 2304, 11296, 7251, 9566, 2288, 3215, 2423, 39184, 13931, 23758, 6055, 5172, 995, 30241, 33688, 44510, 6027, 49429, 5296, 10721, 22807, 23758, 6055, 5172, 995, 30241, 33688, 44510, 6027, 44945, 16606, 15844, 29910, 23275, 5296, 15042, 6055, 9566, 2288, 3215, 2423, 39184, 13931, 9154, 34105, 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7.152557373046875e-07, "words": [{"start": 1401.6599999999999, "end": 1403.06, "word": "الجزء", "probability": 0.79730224609375}, {"start": 1403.06, "end": 1403.72, "word": " الأول", "probability": 0.93359375}, {"start": 1403.72, "end": 1404.92, "word": " اللي", "probability": 0.63671875}, {"start": 1404.92, "end": 1405.28, "word": " مبين", "probability": 0.8155924479166666}, {"start": 1405.28, "end": 1406.0, "word": " بالأسود", "probability": 0.9364013671875}, {"start": 1406.0, "end": 1406.32, "word": " هي", "probability": 0.4404296875}, {"start": 1406.32, "end": 1409.94, "word": " CH3COO", "probability": 0.70458984375}, {"start": 1409.94, "end": 1411.46, "word": " والجزء", "probability": 0.832763671875}, {"start": 1411.46, "end": 1412.1, "word": " التاني", "probability": 0.9554036458333334}, {"start": 1412.1, "end": 1415.1, "word": " OCOO", "probability": 0.6630045572916666}], "temperature": 1.0}, {"id": 62, "seek": 144362, "start": 1416.52, "end": 1443.62, "text": "CH3 هيتكون عندى الـ Symmetrical Anhydride اتكون عندى الـ Symmetrical Anhydride لاحظوا انه مجموعة الانهيدريد كمجموعة عبارة عن ايش C double bond O O C double bond O يعني لو بدى اقول ال ether كانت O متصلة بتنتين R طيب الانهيدريد هى", "tokens": [5462, 18, 39896, 2655, 30544, 43242, 7578, 2423, 39184, 3902, 2174, 32283, 1107, 21591, 25502, 1975, 2655, 30544, 43242, 7578, 2423, 39184, 3902, 2174, 32283, 23574, 6655, 25502, 20193, 5016, 19913, 14407, 16472, 3224, 3714, 7435, 2304, 2407, 27884, 2423, 7649, 3224, 25708, 2288, 25708, 9122, 2304, 7435, 2304, 2407, 27884, 6225, 3555, 9640, 3660, 18871, 1975, 1829, 8592, 383, 3834, 6086, 422, 422, 383, 3834, 6086, 422, 37495, 22653, 45164, 47525, 7578, 1975, 39648, 2423, 37096, 25961, 2655, 422, 44650, 36520, 3660, 39894, 29399, 9957, 497, 23032, 1829, 3555, 2423, 7649, 3224, 25708, 2288, 25708, 8032, 7578], "avg_logprob": -0.2877209662186979, "compression_ratio": 1.7085427135678393, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1416.52, "end": 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"probability": 0.568359375}, {"start": 1432.84, "end": 1433.32, "word": " C", "probability": 0.81884765625}, {"start": 1433.32, "end": 1433.56, "word": " double", "probability": 0.90771484375}, {"start": 1433.56, "end": 1433.96, "word": " bond", "probability": 0.982421875}, {"start": 1433.96, "end": 1434.34, "word": " O", "probability": 0.97705078125}, {"start": 1434.34, "end": 1434.98, "word": " يعني", "probability": 0.874267578125}, {"start": 1434.98, "end": 1435.06, "word": " لو", "probability": 0.82568359375}, {"start": 1435.06, "end": 1435.26, "word": " بدى", "probability": 0.69677734375}, {"start": 1435.26, "end": 1435.48, "word": " اقول", "probability": 0.8994140625}, {"start": 1435.48, "end": 1436.04, "word": " ال", "probability": 0.89306640625}, {"start": 1436.04, "end": 1436.48, "word": " ether", "probability": 0.426513671875}, {"start": 1436.48, "end": 1437.42, "word": " كانت", "probability": 0.967529296875}, {"start": 1437.42, "end": 1437.58, "word": " O", "probability": 0.8623046875}, {"start": 1437.58, "end": 1438.26, "word": " متصلة", "probability": 0.9563802083333334}, {"start": 1438.26, "end": 1438.8, "word": " بتنتين", "probability": 0.7216796875}, {"start": 1438.8, "end": 1439.12, "word": " R", "probability": 0.94189453125}, {"start": 1439.12, "end": 1439.62, "word": " طيب", "probability": 0.771484375}, {"start": 1439.62, "end": 1440.86, "word": " الانهيدريد", "probability": 0.8788248697916666}, {"start": 1440.86, "end": 1443.62, "word": " هى", "probability": 0.6357421875}], "temperature": 1.0}, {"id": 63, "seek": 147015, "start": 1446.59, "end": 1470.15, "text": "هذه ثابتة C double bond O O C double bond O هذه مجموعة الانهيدريد الآن لما فعلت الحامض مع نفسه صارت هذه ال R و هذه ال R زي بعض ولذلك سميت هذا symmetrical anhydride الآن السؤال طب لو خلت هذه مثل وهذه اثل", "tokens": [3224, 24192, 38637, 16758, 2655, 3660, 383, 3834, 6086, 422, 422, 383, 3834, 6086, 422, 29538, 3714, 7435, 2304, 2407, 27884, 2423, 7649, 3224, 25708, 2288, 25708, 6024, 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"end": 2186.48, "word": " إيديهم", "probability": 0.8028564453125}, {"start": 2186.48, "end": 2187.12, "word": " يكتبوا", "probability": 0.97509765625}, {"start": 2187.12, "end": 2187.62, "word": " كان", "probability": 0.818359375}, {"start": 2187.62, "end": 2188.3, "word": " الجواب", "probability": 0.9669596354166666}, {"start": 2188.3, "end": 2188.5, "word": " اللي", "probability": 0.9296875}, {"start": 2188.5, "end": 2189.04, "word": " كتب", "probability": 0.9007161458333334}, {"start": 2189.04, "end": 2189.84, "word": " بهذا", "probability": 0.973876953125}, {"start": 2189.84, "end": 2190.42, "word": " الشكل", "probability": 0.98828125}, {"start": 2190.42, "end": 2200.28, "word": " الان", "probability": 0.375}, {"start": 2200.28, "end": 2200.6, "word": " انتوا", "probability": 0.6898600260416666}, {"start": 2200.6, "end": 2201.06, "word": " بتحكوا", "probability": 0.954833984375}, {"start": 2201.06, "end": 2201.3, "word": " لكن", "probability": 0.8310546875}, {"start": 2201.3, 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الأورثو لأن هدول بعاد عن بعض مابيجوش فهذا بيعملش أنهيدريد ال isothelic acid و ال teraphthalic acid بيعملش أنهيدريد هذا بيعمل أنهيدريد لو قلنالكوا أرسم الانهيدريد الناتج", "tokens": [6027, 10721, 13063, 12984, 2407, 49429, 2423, 22653, 2655, 995, 49429, 29739, 9640, 995, 4724, 3794, 16247, 13063, 12984, 2407, 5296, 33456, 8032, 3215, 12610, 45030, 18513, 18871, 45030, 11242, 3714, 16758, 1829, 7435, 2407, 8592, 6156, 3224, 15730, 4724, 1829, 25957, 1211, 8592, 14739, 3224, 25708, 2288, 25708, 2423, 307, 900, 338, 299, 8258, 4032, 2423, 1796, 569, 49123, 299, 8258, 4724, 1829, 25957, 1211, 8592, 14739, 3224, 25708, 2288, 25708, 23758, 4724, 1829, 25957, 1211, 14739, 3224, 25708, 2288, 25708, 45164, 12174, 1211, 8315, 23275, 14407, 5551, 2288, 38251, 2423, 7649, 3224, 25708, 2288, 25708, 2423, 8315, 2655, 7435], "avg_logprob": -0.24433210419089185, "compression_ratio": 1.9157303370786516, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2596.03, "end": 2597.07, "word": "الأورثو", "probability": 0.756494140625}, {"start": 2597.07, "end": 2597.67, "word": " ولا", "probability": 0.751953125}, {"start": 2597.67, "end": 2598.45, "word": " النيتا", "probability": 0.711273193359375}, {"start": 2598.45, "end": 2598.83, "word": " ولا", "probability": 0.95703125}, {"start": 2598.83, "end": 2599.35, "word": " البارا", "probability": 0.83349609375}, {"start": 2599.35, "end": 2600.69, "word": " بس", "probability": 0.809326171875}, {"start": 2600.69, "end": 2601.39, "word": " الأورثو", "probability": 0.8792724609375}, {"start": 2601.39, "end": 2601.81, "word": " لأن", "probability": 0.746826171875}, {"start": 2601.81, "end": 2602.15, "word": " هدول", "probability": 0.87451171875}, {"start": 2602.15, "end": 2602.77, "word": " بعاد", "probability": 0.90576171875}, {"start": 2602.77, "end": 2602.99, "word": " عن", "probability": 0.98876953125}, {"start": 2602.99, "end": 2603.57, "word": " بعض", "probability": 0.989013671875}, {"start": 2603.57, "end": 2604.61, "word": " مابيجوش", "probability": 0.843017578125}, {"start": 2604.61, "end": 2605.37, "word": " فهذا", "probability": 0.80810546875}, {"start": 2605.37, "end": 2606.09, "word": " بيعملش", "probability": 0.94716796875}, {"start": 2606.09, "end": 2607.07, "word": " أنهيدريد", "probability": 0.6462890625}, {"start": 2607.07, "end": 2607.61, "word": " ال", "probability": 0.73681640625}, {"start": 2607.61, "end": 2608.65, "word": " isothelic", "probability": 0.6292724609375}, {"start": 2608.65, "end": 2609.09, "word": " acid", "probability": 0.92919921875}, {"start": 2609.09, "end": 2609.53, "word": " و", "probability": 0.66357421875}, {"start": 2609.53, "end": 2609.69, "word": " ال", "probability": 0.6005859375}, {"start": 2609.69, "end": 2610.55, "word": " teraphthalic", "probability": 0.549346923828125}, {"start": 2610.55, "end": 2610.83, "word": " acid", "probability": 0.97021484375}, {"start": 2610.83, "end": 2611.37, "word": " بيعملش", "probability": 0.9291015625}, {"start": 2611.37, 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"tokens": [3224, 1829, 29739, 1863, 11622, 9957, 3660, 43242, 7578, 383, 3834, 6086, 422, 4032, 34105, 383, 3834, 6086, 422, 4032, 49374, 16095, 422, 8032, 7578, 3714, 7435, 2304, 2407, 27884, 2423, 7649, 3224, 25708, 2288, 25708, 383, 3834, 6086, 422, 422, 383, 3834, 6086, 422, 4032, 23758, 4724, 1829, 9381, 13546, 1975, 1829, 8592, 24525, 2304, 3224, 1975, 5172, 12984, 6027, 4117, 16472, 3224, 25708, 2288, 25708], "avg_logprob": -0.26976103554753694, "compression_ratio": 1.7014925373134329, "no_speech_prob": 0.0, "words": [{"start": 2618.85, "end": 2619.15, "word": "هي", "probability": 0.6114501953125}, {"start": 2619.15, "end": 2620.01, "word": " البنزينة", "probability": 0.9486328125}, {"start": 2620.01, "end": 2621.29, "word": " عندى", "probability": 0.5865478515625}, {"start": 2621.29, "end": 2621.77, "word": " C", "probability": 0.265625}, {"start": 2621.77, "end": 2622.03, "word": " double", "probability": 0.427490234375}, {"start": 2622.03, "end": 2622.47, "word": " bond", 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"word": " عنها", "probability": 0.98388671875}, {"start": 2654.64, "end": 2654.86, "word": " كيف", "probability": 0.94921875}, {"start": 2654.86, "end": 2655.72, "word": " بتتحضر", "probability": 0.848974609375}, {"start": 2655.72, "end": 2656.76, "word": " واحد", "probability": 0.854736328125}, {"start": 2656.76, "end": 2656.96, "word": " O", "probability": 0.357177734375}, {"start": 2656.96, "end": 2657.36, "word": " minus", "probability": 0.23291015625}, {"start": 2657.36, "end": 2657.88, "word": " والتاني", "probability": 0.77734375}, {"start": 2657.88, "end": 2658.2, "word": " CL", "probability": 0.462158203125}, {"start": 2658.2, "end": 2658.72, "word": " وهي", "probability": 0.5098876953125}, {"start": 2658.72, "end": 2659.44, "word": " تسميتهم", "probability": 0.8685302734375}, {"start": 2659.44, "end": 2659.9, "word": " acidic", "probability": 0.476318359375}, {"start": 2659.9, "end": 2660.52, "word": " benzoic", "probability": 0.6573893229166666}, {"start": 2660.52, "end": 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diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/gPDsINexngk_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/gPDsINexngk_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..029ffdf816eca3c352289ce77f625d396a1992f9
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/gPDsINexngk_raw.json
@@ -0,0 +1 @@
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" و", "probability": 0.90869140625}, {"start": 518.99, "end": 519.29, "word": " نمرة", "probability": 0.6041666666666666}, {"start": 519.29, "end": 519.63, "word": " اتنين", "probability": 0.84521484375}, {"start": 519.63, "end": 519.97, "word": " يمكن", "probability": 0.9794921875}, {"start": 519.97, "end": 520.15, "word": " أن", "probability": 0.8759765625}, {"start": 520.15, "end": 520.61, "word": " تنشأ", "probability": 0.9906005859375}, {"start": 520.61, "end": 520.95, "word": " عن", "probability": 0.9951171875}, {"start": 520.95, "end": 521.89, "word": " ال", "probability": 0.97021484375}, {"start": 521.89, "end": 522.33, "word": " rotation", "probability": 0.984375}, {"start": 522.33, "end": 523.15, "word": " الدوران", "probability": 0.8660481770833334}], "temperature": 1.0}, {"id": 22, "seek": 52779, "start": 524.27, "end": 527.79, "text": "فيكون المُركّب مُركّب واحد", "tokens": [41185, 30544, 9673, 10859, 31747, 11703, 3555, 3714, 10859, 31747, 11703, 3555, 36764, 24401], "avg_logprob": -0.21575520237286885, "compression_ratio": 1.065217391304348, "no_speech_prob": 0.0, "words": [{"start": 524.27, "end": 525.17, "word": "فيكون", "probability": 0.5936279296875}, {"start": 525.17, "end": 526.47, "word": " المُركّب", "probability": 0.8205078125}, {"start": 526.47, "end": 527.13, "word": " مُركّب", "probability": 0.95498046875}, {"start": 527.13, "end": 527.79, "word": " واحد", "probability": 0.9736328125}], "temperature": 1.0}, {"id": 23, "seek": 55423, "start": 528.73, "end": 554.23, "text": "بشكل واحد وبهيئات كثيرة مختلفة ولذلك ال one two dichloroethane هو مركب واحد فقط بهيئات مختلفة وهو في حالة دوران أبدي يعني ربنا خالجه زي ما بتقول الآية الكريمة وكل في فلك يسبحون بالنسبة لعلم الكيميا هذا دوران لا يتوقف", "tokens": [3555, 8592, 28820, 36764, 24401, 46599, 3224, 1829, 19986, 9307, 9122, 12984, 48923, 3714, 46456, 46538, 3660, 35525, 8848, 23275, 2423, 472, 732, 10390, 6746, 78, 3293, 1929, 31439, 3714, 31747, 3555, 36764, 24401, 6156, 47432, 39627, 1829, 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534.55, "word": " ولذلك", "probability": 0.8470052083333334}, {"start": 534.55, "end": 535.39, "word": " ال", "probability": 0.97314453125}, {"start": 535.39, "end": 535.61, "word": " one", "probability": 0.302734375}, {"start": 535.61, "end": 536.17, "word": " two", "probability": 0.65283203125}, {"start": 536.17, "end": 537.85, "word": " dichloroethane", "probability": 0.86748046875}, {"start": 537.85, "end": 538.05, "word": " هو", "probability": 0.94140625}, {"start": 538.05, "end": 538.71, "word": " مركب", "probability": 0.8466796875}, {"start": 538.71, "end": 539.25, "word": " واحد", "probability": 0.99267578125}, {"start": 539.25, "end": 539.81, "word": " فقط", "probability": 0.9775390625}, {"start": 539.81, "end": 540.63, "word": " بهيئات", "probability": 0.919677734375}, {"start": 540.63, "end": 541.47, "word": " مختلفة", "probability": 0.9959716796875}, {"start": 541.47, "end": 541.99, "word": " وهو", "probability": 0.828369140625}, {"start": 541.99, "end": 542.17, "word": " في", "probability": 0.91162109375}, {"start": 542.17, "end": 542.59, "word": " حالة", "probability": 0.9236653645833334}, {"start": 542.59, "end": 543.09, "word": " دوران", "probability": 0.9798177083333334}, {"start": 543.09, "end": 543.69, "word": " أبدي", "probability": 0.8971354166666666}, {"start": 543.69, "end": 544.61, "word": " يعني", "probability": 0.856201171875}, {"start": 544.61, "end": 545.03, "word": " ربنا", "probability": 0.9830729166666666}, {"start": 545.03, "end": 545.69, "word": " خالجه", "probability": 0.9783935546875}, {"start": 545.69, "end": 546.43, "word": " زي", "probability": 0.871826171875}, {"start": 546.43, "end": 546.49, "word": " ما", "probability": 0.97509765625}, {"start": 546.49, "end": 546.83, "word": " بتقول", "probability": 0.93115234375}, {"start": 546.83, "end": 547.17, "word": " الآية", "probability": 0.7777506510416666}, {"start": 547.17, "end": 547.75, "word": " الكريمة", "probability": 0.9754231770833334}, {"start": 547.75, "end": 548.41, "word": " وكل", "probability": 0.7705078125}, {"start": 548.41, "end": 548.73, "word": " في", "probability": 0.66796875}, {"start": 548.73, "end": 549.19, "word": " فلك", "probability": 0.920166015625}, {"start": 549.19, "end": 550.05, "word": " يسبحون", "probability": 0.955810546875}, {"start": 550.05, "end": 551.27, "word": " بالنسبة", "probability": 0.9791259765625}, {"start": 551.27, "end": 551.61, "word": " لعلم", "probability": 0.8351236979166666}, {"start": 551.61, "end": 552.13, "word": " الكيميا", "probability": 0.9152018229166666}, {"start": 552.13, "end": 552.47, "word": " هذا", "probability": 0.9326171875}, {"start": 552.47, "end": 553.09, "word": " دوران", "probability": 0.9879557291666666}, {"start": 553.09, "end": 553.27, "word": " لا", "probability": 0.93017578125}, {"start": 553.27, "end": 554.23, "word": " يتوقف", "probability": 0.985595703125}], "temperature": 1.0}, {"id": 24, "seek": 56560, "start": 554.7, "end": 565.6, "text": "الدوران حول الرابطة الأوحادية تماما زى المروحة اللى بالسجف لما بتلوف بنقولش عنها مروحة كتيرة بتكون بهذا الشكل بعد شوية بتزيد زوايا كمان", "tokens": [6027, 3215, 13063, 7649, 11331, 12610, 34892, 16758, 9566, 3660, 16247, 2407, 5016, 18513, 10632, 46811, 10943, 995, 30767, 7578, 9673, 32887, 5016, 3660, 13672, 7578, 20666, 3794, 7435, 5172, 5296, 15042, 39894, 1211, 38688, 44945, 39648, 8592, 18871, 11296, 3714, 32887, 5016, 3660, 9122, 2655, 48923, 39894, 30544, 39627, 15730, 25124, 28820, 39182, 13412, 2407, 10632, 39894, 11622, 25708, 30767, 14407, 25528, 9122, 2304, 7649], "avg_logprob": -0.22446361451006647, "compression_ratio": 1.6870748299319729, "no_speech_prob": 1.9073486328125e-06, "words": [{"start": 554.7, "end": 555.46, "word": "الدوران", "probability": 0.7742919921875}, {"start": 555.46, "end": 555.74, "word": " حول", "probability": 0.919677734375}, {"start": 555.74, "end": 556.28, "word": " الرابطة", "probability": 0.86669921875}, {"start": 556.28, "end": 556.8, "word": " الأوحادية", "probability": 0.750537109375}, {"start": 556.8, "end": 557.56, "word": " تماما", "probability": 0.947265625}, {"start": 557.56, "end": 557.8, "word": " زى", "probability": 0.63427734375}, {"start": 557.8, "end": 558.66, "word": " المروحة", "probability": 0.958740234375}, {"start": 558.66, "end": 559.08, "word": " اللى", "probability": 0.975830078125}, {"start": 559.08, "end": 559.58, "word": " بالسجف", "probability": 0.7642822265625}, {"start": 559.58, "end": 559.82, "word": " لما", "probability": 0.927734375}, {"start": 559.82, "end": 560.44, "word": " بتلوف", "probability": 0.7586263020833334}, {"start": 560.44, "end": 561.78, "word": " بنقولش", "probability": 0.6898193359375}, {"start": 561.78, "end": 562.02, "word": " عنها", "probability": 0.980224609375}, {"start": 562.02, "end": 562.6, "word": " مروحة", "probability": 0.78570556640625}, {"start": 562.6, "end": 562.88, "word": " كتيرة", "probability": 0.8912760416666666}, {"start": 562.88, "end": 563.52, "word": " بتكون", "probability": 0.859619140625}, {"start": 563.52, "end": 563.8, "word": " بهذا", "probability": 0.6285400390625}, {"start": 563.8, "end": 564.1, "word": " الشكل", "probability": 0.993896484375}, {"start": 564.1, "end": 564.32, "word": " بعد", "probability": 0.7314453125}, {"start": 564.32, "end": 564.58, "word": " شوية", "probability": 0.9638671875}, {"start": 564.58, "end": 564.94, "word": " بتزيد", "probability": 0.9235026041666666}, {"start": 564.94, "end": 565.26, "word": " زوايا", "probability": 0.616455078125}, {"start": 565.26, "end": 565.6, "word": " كمان", "probability": 0.9759114583333334}], "temperature": 1.0}, {"id": 25, "seek": 59301, "start": 566.59, "end": 593.01, "text": "و هي في حالة دوران أبدي لكنها تبقى مروحة الان هذا الـ dichloroethane في حالة دوران أبدي بهيئات كثيرة ولكنه يبقى مركبا واحد فلو واحدة بدت تشتري dichloroethane هتلاقي انه عندها ايش مركب واحد السبب ال free rotation الان خلينا نحول للالكين", "tokens": [2407, 39896, 8978, 11331, 6027, 3660, 11778, 13063, 7649, 5551, 3555, 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"word": " bond،", "probability": 0.783203125}, {"start": 871.18, "end": 871.64, "word": " لاحظوا", "probability": 0.84478759765625}, {"start": 871.64, "end": 871.84, "word": " هنا", "probability": 0.59375}, {"start": 871.84, "end": 872.0, "word": " ال", "probability": 0.841796875}, {"start": 872.0, "end": 872.22, "word": " double", "probability": 0.95703125}, {"start": 872.22, "end": 872.56, "word": " bond", "probability": 0.95751953125}, {"start": 872.56, "end": 873.74, "word": " بدايتها", "probability": 0.960693359375}, {"start": 873.74, "end": 874.6, "word": " وين؟", "probability": 0.76513671875}, {"start": 874.6, "end": 875.36, "word": " اتنين،", "probability": 0.8759765625}, {"start": 875.36, "end": 875.48, "word": " لو", "probability": 0.96826171875}, {"start": 875.48, "end": 875.96, "word": " برقم", "probability": 0.933349609375}, {"start": 875.96, "end": 876.1, "word": " من", "probability": 0.6484375}, {"start": 876.1, "end": 876.2, "word": " هنا", "probability": 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"word": " بنتين", "probability": 0.7654622395833334}, {"start": 892.21, "end": 893.51, "word": " بنتين", "probability": 0.7906087239583334}, {"start": 893.51, "end": 895.45, "word": " يلتهي", "probability": 0.5423126220703125}, {"start": 895.45, "end": 896.79, "word": " بين", "probability": 0.32177734375}, {"start": 896.79, "end": 896.97, "word": " في", "probability": 0.611328125}, {"start": 896.97, "end": 897.27, "word": " double", "probability": 0.75048828125}, {"start": 897.27, "end": 897.63, "word": " bond", "probability": 0.9375}, {"start": 897.63, "end": 898.47, "word": " الآن", "probability": 0.6180419921875}, {"start": 898.47, "end": 898.99, "word": " الين", "probability": 0.5718994140625}, {"start": 898.99, "end": 899.39, "word": " هذه", "probability": 0.572265625}, {"start": 899.39, "end": 899.53, "word": " اللي", "probability": 0.9013671875}, {"start": 899.53, "end": 899.73, "word": " هي", "probability": 0.87255859375}, {"start": 899.73, "end": 899.87, "word": " ال", 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سميت الآن هذه two مثل و four promo طب لو عديت من هنا two مثل و four promo لو قلت واحد اتنين تلاتة اربعة خمسة two مثل و four promo نفس الأشياء طالما عندك مجموعتين مثل على نفس ال carbon ابدأ من أي واحدة مافيش عندك مشكلة", "tokens": [2407, 8032, 1829, 28543, 2288, 14407, 5296, 1863, 36178, 2423, 32277, 2304, 45164, 12174, 1211, 2655, 8608, 1211, 3794, 37977, 36764, 24401, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 1975, 25513, 27884, 16490, 2304, 3794, 3660, 4032, 45164, 8608, 2304, 36081, 6024, 48506, 29538, 732, 50113, 1211, 4032, 1451, 26750, 23032, 3555, 45164, 6225, 16254, 2655, 9154, 34105, 732, 50113, 1211, 4032, 1451, 26750, 45164, 12174, 1211, 2655, 36764, 24401, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 1975, 25513, 27884, 16490, 2304, 3794, 3660, 732, 50113, 1211, 4032, 1451, 26750, 8717, 36178, 16247, 8592, 1829, 16606, 23032, 6027, 15042, 43242, 4117, 3714, 7435, 2304, 45367, 2655, 9957, 50113, 1211, 15844, 8717, 36178, 2423, 5954, 1975, 44510, 10721, 9154, 36632, 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{"start": 1208.74, "end": 1209.36, "word": " مجموعة", "probability": 0.9619140625}, {"start": 1209.36, "end": 1209.7, "word": " و", "probability": 0.61181640625}, {"start": 1209.7, "end": 1210.32, "word": " التنتين", "probability": 0.90673828125}, {"start": 1210.32, "end": 1211.24, "word": " موجودات", "probability": 0.942626953125}, {"start": 1211.24, "end": 1213.48, "word": " كجزء", "probability": 0.97265625}, {"start": 1213.48, "end": 1213.68, "word": " من", "probability": 0.99462890625}, {"start": 1213.68, "end": 1214.14, "word": " أطول", "probability": 0.9879557291666666}, {"start": 1214.14, "end": 1215.0, "word": " سلسلة", "probability": 0.993408203125}, {"start": 1215.0, "end": 1216.22, "word": " واضحة", "probability": 0.78662109375}, {"start": 1216.22, "end": 1216.88, "word": " الفكرة؟", "probability": 0.94091796875}], "temperature": 1.0}, {"id": 53, "seek": 125941, "start": 1236.77, "end": 1259.41, "text": "وعشان هيك لا بأس ان اعطيكم مسألة تانية تفكروا فيها تعملوها homework على هذا الموضوع تحديدا مسألة جميلة جدا", "tokens": [45367, 8592, 7649, 39896, 4117, 20193, 4724, 10721, 3794, 16472, 1975, 3615, 9566, 1829, 24793, 47524, 10721, 37977, 6055, 7649, 10632, 6055, 5172, 37983, 14407, 8978, 11296, 6055, 25957, 1211, 2407, 11296, 14578, 15844, 23758, 9673, 2407, 11242, 45367, 6055, 5016, 16254, 28259, 47524, 10721, 37977, 10874, 2304, 26895, 3660, 10874, 28259], "avg_logprob": -0.10333136736222033, "compression_ratio": 1.4090909090909092, "no_speech_prob": 0.0, "words": [{"start": 1236.77, "end": 1237.33, "word": "وعشان", "probability": 0.8126627604166666}, {"start": 1237.33, "end": 1237.99, "word": " هيك", "probability": 0.982666015625}, {"start": 1237.99, "end": 1238.27, "word": " لا", "probability": 0.6318359375}, {"start": 1238.27, "end": 1238.81, "word": " بأس", "probability": 0.9664713541666666}, {"start": 1238.81, "end": 1239.05, "word": " ان", "probability": 0.4375}, {"start": 1239.05, "end": 1239.93, "word": " اعطيكم", "probability": 0.97041015625}, 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بقول فينل في حرف ال V هذه فينل فلو حملت ال chlorine بتصير vinyl chloride ليش رفضنا؟", "tokens": [28814, 11622, 42213, 2655, 4117, 14407, 4724, 43042, 3224, 8608, 2304, 34268, 22653, 9122, 19528, 3660, 37893, 3714, 19913, 3555, 2407, 9566, 3660, 10874, 6027, 2655, 8978, 1863, 1211, 41850, 4724, 39648, 8978, 1863, 1211, 8978, 11331, 28480, 2423, 691, 29538, 8978, 1863, 1211, 6156, 1211, 2407, 11331, 42213, 2655, 2423, 39888, 39894, 9381, 13546, 25226, 35434, 32239, 8592, 12602, 5172, 11242, 8315, 22807], "avg_logprob": -0.28076923076923077, "compression_ratio": 1.4038461538461537, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 1359.08, "end": 1359.94, "word": "إزملتكوا", "probability": 0.6207682291666666}, {"start": 1359.94, "end": 1360.26, "word": " برضه", "probability": 0.9493815104166666}, {"start": 1360.26, "end": 1360.96, "word": " سمعتني", "probability": 0.814697265625}, {"start": 1360.96, "end": 1361.34, "word": " كلمة", "probability": 0.904296875}, {"start": 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هيكون عنده من أربع ذرّات كربون أنا هنا ماسك التلاتة ممكن واحدة تقول بسيطة حطوا هنا الكربون هنا", "tokens": [5172, 37983, 14407, 20449, 1863, 7578, 5551, 9957, 3714, 43020, 8717, 5016, 9566, 33251, 25513, 11536, 33688, 11242, 31845, 10632, 4724, 2304, 3615, 1863, 7578, 9122, 2304, 3714, 31747, 11703, 3555, 2423, 39184, 42, 2030, 8032, 1829, 30544, 43242, 3224, 9154, 5551, 25513, 3615, 29910, 2288, 11703, 9307, 9122, 25513, 11536, 41850, 34105, 19446, 3794, 4117, 16712, 1211, 9307, 3660, 3714, 43020, 36764, 24401, 3660, 6055, 39648, 4724, 3794, 1829, 9566, 3660, 11331, 9566, 14407, 34105, 33251, 25513, 11536, 34105], "avg_logprob": -0.2824073956336504, "compression_ratio": 1.7048192771084338, "no_speech_prob": 0.0, "words": [{"start": 1834.53, "end": 1835.15, "word": "فكروا", "probability": 0.8717447916666666}, {"start": 1835.15, "end": 1835.57, "word": " معنى", "probability": 0.7037760416666666}, {"start": 1835.57, "end": 1835.73, "word": " أين", "probability": 0.64404296875}, {"start": 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"probability": 0.85693359375}, {"start": 2034.66, "end": 2035.04, "word": " هذه", "probability": 0.88671875}, {"start": 2035.04, "end": 2035.18, "word": " و", "probability": 0.99267578125}, {"start": 2035.18, "end": 2035.72, "word": " حطينا", "probability": 0.94140625}, {"start": 2035.72, "end": 2036.04, "word": " مثل", "probability": 0.98583984375}, {"start": 2036.04, "end": 2039.2, "word": " هنطلع", "probability": 0.7451904296875}, {"start": 2039.2, "end": 2039.36, "word": " في", "probability": 0.931640625}, {"start": 2039.36, "end": 2039.98, "word": " المركب", "probability": 0.9332682291666666}, {"start": 2039.98, "end": 2041.5, "word": " المتفرع", "probability": 0.97939453125}, {"start": 2041.5, "end": 2046.68, "word": " اتطلع", "probability": 0.749609375}, {"start": 2046.68, "end": 2046.92, "word": " على", "probability": 0.89599609375}, {"start": 2046.92, "end": 2047.54, "word": " شكله", "probability": 0.99072265625}, {"start": 2047.54, "end": 2048.42, "word": " بدأ", "probability": 0.682861328125}, {"start": 2048.42, "end": 2048.96, "word": " يغلبني", "probability": 0.965576171875}], "temperature": 1.0}, {"id": 88, "seek": 207567, "start": 2053.2, "end": 2075.68, "text": "الثلاثة اللي اتفرع منهم واحد واحد اتنين تلاتة اتفرع لما كان في ال ال كيرز ال double bond سمينا ايزو بيوتين هنا ايش هنسميه ايزو بيوتين ايزو بيوتين طب لو قلت لو واحد اسميه بال ايو باكنيم هايوا قدام عينيكم اطول سلسلة فيه", "tokens": [6027, 12984, 1211, 5718, 104, 3660, 13672, 1829, 1975, 2655, 5172, 2288, 3615, 9154, 16095, 36764, 24401, 36764, 24401, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 1975, 2655, 5172, 2288, 3615, 5296, 15042, 25961, 8978, 2423, 2423, 9122, 13546, 11622, 2423, 3834, 6086, 8608, 2304, 1829, 8315, 1975, 1829, 11622, 2407, 4724, 1829, 35473, 9957, 34105, 1975, 1829, 8592, 8032, 1863, 38251, 1829, 3224, 1975, 1829, 11622, 2407, 4724, 1829, 35473, 9957, 1975, 1829, 11622, 2407, 4724, 1829, 35473, 9957, 23032, 3555, 45164, 12174, 1211, 2655, 45164, 36764, 24401, 1975, 38251, 1829, 3224, 20666, 1975, 1829, 2407, 4724, 995, 19452, 32640, 8032, 47302, 14407, 12174, 3215, 10943, 6225, 9957, 1829, 24793, 1975, 9566, 12610, 8608, 1211, 3794, 37977, 8978, 3224], "avg_logprob": -0.22694672790707135, "compression_ratio": 1.9792746113989637, "no_speech_prob": 0.0, "words": [{"start": 2053.2, "end": 2053.94, "word": "الثلاثة", "probability": 0.8320719401041666}, {"start": 2053.94, "end": 2054.04, "word": " اللي", "probability": 0.76220703125}, {"start": 2054.04, "end": 2054.5, "word": " اتفرع", "probability": 0.896875}, {"start": 2054.5, "end": 2054.9, "word": " منهم", "probability": 0.97314453125}, {"start": 2054.9, "end": 2055.32, "word": " واحد", "probability": 0.90869140625}, {"start": 2055.32, "end": 2055.7, "word": " واحد", "probability": 0.771240234375}, {"start": 2055.7, "end": 2056.02, "word": " اتنين", "probability": 0.97412109375}, {"start": 2056.02, "end": 2056.44, "word": " تلاتة", "probability": 0.8773193359375}, {"start": 2056.44, "end": 2056.98, "word": " اتفرع", "probability": 0.98017578125}, {"start": 2056.98, "end": 2057.9, "word": " لما", "probability": 0.87939453125}, {"start": 2057.9, "end": 2058.12, "word": " كان", "probability": 0.990234375}, {"start": 2058.12, "end": 2058.28, "word": " في", "probability": 0.89697265625}, {"start": 2058.28, "end": 2058.4, "word": " ال", "probability": 0.8974609375}, {"start": 2058.4, "end": 2058.56, "word": " ال", "probability": 0.44873046875}, {"start": 2058.56, "end": 2058.92, "word": " كيرز", "probability": 0.48455810546875}, {"start": 2058.92, "end": 2059.04, "word": " ال", "probability": 0.3935546875}, {"start": 2059.04, "end": 2059.22, "word": " double", "probability": 0.47265625}, {"start": 2059.22, "end": 2059.48, "word": " bond", "probability": 0.65380859375}, {"start": 2059.48, "end": 2059.88, "word": " سمينا", "probability": 0.8243408203125}, {"start": 2059.88, "end": 2060.34, "word": " ايزو", "probability": 0.75579833984375}, {"start": 2060.34, "end": 2061.04, "word": " بيوتين", "probability": 0.88623046875}, {"start": 2061.04, "end": 2061.82, "word": " هنا", "probability": 0.386474609375}, {"start": 2061.82, "end": 2062.1, "word": " ايش", "probability": 0.8857421875}, {"start": 2062.1, "end": 2062.86, "word": " هنسميه", "probability": 0.912109375}, {"start": 2062.86, "end": 2064.02, "word": " ايزو", "probability": 0.87646484375}, {"start": 2064.02, "end": 2065.18, "word": " بيوتين", "probability": 0.9627685546875}, {"start": 2065.18, "end": 2065.86, "word": " ايزو", "probability": 0.9227294921875}, {"start": 2065.86, "end": 2066.38, "word": " بيوتين", "probability": 0.9891357421875}, {"start": 2066.38, "end": 2066.86, "word": " طب", "probability": 0.86767578125}, {"start": 2066.86, "end": 2067.04, "word": " لو", "probability": 0.9892578125}, {"start": 2067.04, "end": 2067.34, "word": " قلت", "probability": 0.6685384114583334}, {"start": 2067.34, "end": 2067.48, "word": " لو", "probability": 0.87109375}, {"start": 2067.48, "end": 2067.66, "word": " واحد", "probability": 0.6591796875}, {"start": 2067.66, "end": 2068.18, "word": " اسميه", "probability": 0.83203125}, {"start": 2068.18, "end": 2068.34, "word": " بال", "probability": 0.7568359375}, {"start": 2068.34, "end": 2068.82, "word": " ايو", "probability": 0.5703938802083334}, {"start": 2068.82, "end": 2069.64, "word": " باكنيم", "probability": 0.830322265625}, {"start": 2069.64, "end": 2071.68, "word": " هايوا", "probability": 0.5369466145833334}, {"start": 2071.68, "end": 2072.0, "word": " قدام", "probability": 0.8684895833333334}, {"start": 2072.0, "end": 2072.64, "word": " عينيكم", "probability": 0.9266357421875}, {"start": 2072.64, "end": 2074.72, "word": " اطول", "probability": 0.8465169270833334}, {"start": 2074.72, "end": 2075.3, "word": " سلسلة", "probability": 0.982177734375}, {"start": 2075.3, "end": 2075.68, "word": " فيه", "probability": 0.9814453125}], "temperature": 1.0}, {"id": 89, "seek": 210596, "start": 2077.6, "end": 2105.96, "text": "One Ibropine وعن إمرأتين يحمل مثل إذا ال isobutene اسمه two مثل و one ibropine بناء على ذلك هذه الصيغة العامة C4H8 كم ألكين منها؟ C4H8 كم ألكين؟", "tokens": [15426, 40790, 1513, 533, 4032, 3615, 1863, 11933, 29973, 10721, 2655, 9957, 7251, 35571, 1211, 50113, 1211, 11933, 15730, 2423, 307, 996, 325, 1450, 24525, 2304, 3224, 732, 50113, 1211, 4032, 472, 39073, 1513, 533, 44945, 16606, 15844, 29910, 23275, 29538, 31767, 1829, 17082, 3660, 18863, 10943, 3660, 383, 19, 39, 23, 9122, 2304, 5551, 1211, 4117, 9957, 9154, 11296, 22807, 383, 19, 39, 23, 9122, 2304, 5551, 1211, 4117, 9957, 22807], "avg_logprob": -0.29708905415992215, "compression_ratio": 1.3773584905660377, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2077.6, "end": 2078.04, "word": "One", "probability": 0.07373046875}, {"start": 2078.04, "end": 2078.86, "word": " Ibropine", "probability": 0.5654296875}, {"start": 2078.86, "end": 2081.12, "word": " وعن", "probability": 0.6410319010416666}, {"start": 2081.12, "end": 2081.62, "word": " إمرأتين", "probability": 0.71552734375}, {"start": 2081.62, "end": 2082.2, "word": " يحمل", "probability": 0.97705078125}, {"start": 2082.2, "end": 2083.5, "word": " مثل", "probability": 0.86767578125}, {"start": 2083.5, "end": 2084.3, "word": " إذا", "probability": 0.681884765625}, {"start": 2084.3, "end": 2085.14, "word": " ال", "probability": 0.544921875}, {"start": 2085.14, "end": 2086.6, "word": " isobutene", "probability": 0.72686767578125}, {"start": 2086.6, "end": 2087.28, "word": " اسمه", "probability": 0.9554036458333334}, {"start": 2087.28, "end": 2088.18, "word": " two", "probability": 0.368408203125}, {"start": 2088.18, "end": 2088.7, "word": " مثل", "probability": 0.870361328125}, {"start": 2088.7, "end": 2089.0, "word": " و", "probability": 0.493896484375}, {"start": 2089.0, "end": 2089.14, "word": " one", "probability": 0.4853515625}, {"start": 2089.14, "end": 2089.72, "word": " ibropine", "probability": 0.7479654947916666}, {"start": 2089.72, "end": 2090.7, "word": " بناء", "probability": 0.932861328125}, {"start": 2090.7, "end": 2091.02, "word": " على", "probability": 0.8544921875}, {"start": 2091.02, "end": 2091.76, "word": " ذلك", "probability": 0.9921875}, {"start": 2091.76, "end": 2092.9, "word": " هذه", "probability": 0.57958984375}, {"start": 2092.9, "end": 2093.4, "word": " الصيغة", "probability": 0.97802734375}, {"start": 2093.4, "end": 2094.04, "word": " العامة", "probability": 0.99169921875}, {"start": 2094.04, "end": 2096.56, "word": " C4H8", "probability": 0.786834716796875}, {"start": 2096.56, "end": 2098.48, "word": " كم", "probability": 0.838623046875}, {"start": 2098.48, "end": 2099.14, "word": " ألكين", "probability": 0.765869140625}, {"start": 2099.14, "end": 2100.48, "word": " منها؟", "probability": 0.7765299479166666}, {"start": 2100.48, "end": 2104.48, "word": " C4H8", "probability": 0.9195556640625}, {"start": 2104.48, "end": 2105.2, "word": " كم", "probability": 0.888427734375}, {"start": 2105.2, "end": 2105.96, "word": " ألكين؟", "probability": 0.93447265625}], "temperature": 1.0}, {"id": 90, "seek": 213164, "start": 2108.36, "end": 2131.64, "text": "عدوهم أربعة أربعة شفتهم يعني لو بدى يكون عندكوا سؤال draw all the possible alkenes that have the formula C4H8 one butane, cistobutane, trans-tobutane, isobutane إذا كام ألكين؟ أربعة الآن انتبهوا معي سؤال دقيق جدا", "tokens": [3615, 3215, 2407, 16095, 5551, 25513, 27884, 5551, 25513, 27884, 13412, 5172, 2655, 16095, 37495, 22653, 45164, 47525, 7578, 7251, 30544, 43242, 4117, 14407, 8608, 33604, 6027, 2642, 439, 264, 1944, 37688, 25973, 300, 362, 264, 8513, 383, 19, 39, 23, 472, 457, 1929, 11, 269, 468, 996, 325, 1929, 11, 1145, 12, 83, 996, 325, 1929, 11, 307, 996, 325, 1929, 11933, 15730, 9122, 10943, 5551, 1211, 4117, 9957, 22807, 5551, 25513, 27884, 6024, 48506, 16472, 2655, 3555, 3224, 14407, 20449, 1829, 8608, 33604, 6027, 11778, 38436, 4587, 10874, 28259], "avg_logprob": -0.28311821267656656, "compression_ratio": 1.400943396226415, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2108.36, "end": 2108.88, "word": "عدوهم", "probability": 0.78662109375}, {"start": 2108.88, "end": 2109.68, "word": " أربعة", "probability": 0.6930745442708334}, {"start": 2109.68, "end": 2110.26, "word": " أربعة", "probability": 0.7486165364583334}, {"start": 2110.26, "end": 2111.9, "word": " شفتهم", "probability": 0.73388671875}, {"start": 2111.9, "end": 2113.12, "word": " يعني", "probability": 0.7333984375}, {"start": 2113.12, "end": 2113.2, "word": " لو", "probability": 0.912109375}, {"start": 2113.2, "end": 2113.36, "word": " بدى", "probability": 0.5087890625}, {"start": 2113.36, "end": 2113.52, "word": " يكون", "probability": 0.943603515625}, {"start": 2113.52, "end": 2113.84, "word": " عندكوا", "probability": 0.7902018229166666}, {"start": 2113.84, "end": 2114.34, "word": " سؤال", "probability": 0.9866536458333334}, {"start": 2114.34, "end": 2114.96, "word": " draw", "probability": 0.56201171875}, {"start": 2114.96, "end": 2115.78, "word": " all", "probability": 0.92333984375}, {"start": 2115.78, "end": 2116.04, "word": " the", "probability": 0.7451171875}, {"start": 2116.04, "end": 2116.52, "word": " possible", "probability": 0.94384765625}, {"start": 2116.52, "end": 2117.28, "word": " alkenes", "probability": 0.641357421875}, {"start": 2117.28, "end": 2117.6, "word": " that", "probability": 0.92041015625}, {"start": 2117.6, "end": 2117.88, "word": " have", "probability": 0.94482421875}, {"start": 2117.88, "end": 2118.06, "word": " the", "probability": 0.65869140625}, {"start": 2118.06, "end": 2118.52, "word": " formula", "probability": 0.89306640625}, {"start": 2118.52, "end": 2119.74, "word": " C4H8", "probability": 0.93408203125}, {"start": 2119.74, "end": 2120.22, "word": " one", "probability": 0.51123046875}, {"start": 2120.22, "end": 2120.82, "word": " butane,", "probability": 0.70654296875}, {"start": 2121.22, "end": 2122.16, "word": " cistobutane,", "probability": 0.68994140625}, {"start": 2122.46, "end": 2122.82, "word": " trans", "probability": 0.36376953125}, {"start": 2122.82, "end": 2123.56, "word": "-tobutane,", "probability": 0.7286865234375}, {"start": 2124.18, "end": 2125.08, "word": " isobutane", "probability": 0.9412841796875}, {"start": 2125.08, "end": 2125.32, "word": " إذا", "probability": 0.556640625}, {"start": 2125.32, "end": 2125.6, "word": " كام", "probability": 0.727294921875}, {"start": 2125.6, "end": 2126.58, "word": " ألكين؟", "probability": 0.74921875}, {"start": 2126.58, "end": 2127.48, "word": " أربعة", "probability": 0.9640299479166666}, {"start": 2127.48, "end": 2128.52, "word": " الآن", "probability": 0.54608154296875}, {"start": 2128.52, "end": 2129.08, "word": " انتبهوا", "probability": 0.95830078125}, {"start": 2129.08, "end": 2129.94, "word": " معي", "probability": 0.929931640625}, {"start": 2129.94, "end": 2130.76, "word": " سؤال", "probability": 0.9451497395833334}, {"start": 2130.76, "end": 2131.22, "word": " دقيق", "probability": 0.9964192708333334}, {"start": 2131.22, "end": 2131.64, "word": " جدا", "probability": 0.991455078125}], "temperature": 1.0}, {"id": 91, "seek": 215686, "start": 2133.12, "end": 2156.86, "text": "لو أنا سألتكم draw all the possible compounds المركبات أنا قولت ال keys انتبهوا جيدا draw all the possible compounds كل المركبات that have the formula C4H8 كيف بدكوا تبدأوا تفكروا تفضلي", "tokens": [1211, 2407, 41850, 8608, 10721, 1211, 2655, 24793, 2642, 439, 264, 1944, 21810, 9673, 31747, 3555, 9307, 41850, 12174, 12610, 2655, 2423, 9317, 16472, 2655, 3555, 3224, 14407, 10874, 25708, 995, 2642, 439, 264, 1944, 21810, 28242, 9673, 31747, 3555, 9307, 300, 362, 264, 8513, 383, 19, 39, 23, 9122, 33911, 47525, 4117, 14407, 6055, 44510, 10721, 14407, 6055, 5172, 37983, 14407, 6055, 5172, 11242, 20292], "avg_logprob": -0.2237639956509889, "compression_ratio": 1.5146198830409356, "no_speech_prob": 0.0, "words": [{"start": 2133.12, "end": 2133.4, "word": "لو", "probability": 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0.07635498046875}, {"start": 2142.22, "end": 2142.96, "word": " انتبهوا", "probability": 0.823681640625}, {"start": 2142.96, "end": 2143.64, "word": " جيدا", "probability": 0.98583984375}, {"start": 2143.64, "end": 2144.34, "word": " draw", "probability": 0.4375}, {"start": 2144.34, "end": 2144.74, "word": " all", "probability": 0.955078125}, {"start": 2144.74, "end": 2145.0, "word": " the", "probability": 0.84619140625}, {"start": 2145.0, "end": 2145.38, "word": " possible", "probability": 0.92724609375}, {"start": 2145.38, "end": 2146.12, "word": " compounds", "probability": 0.90576171875}, {"start": 2146.12, "end": 2146.6, "word": " كل", "probability": 0.7841796875}, {"start": 2146.6, "end": 2147.92, "word": " المركبات", "probability": 0.9730224609375}, {"start": 2147.92, "end": 2148.54, "word": " that", "probability": 0.830078125}, {"start": 2148.54, "end": 2148.98, "word": " have", "probability": 0.9541015625}, {"start": 2148.98, "end": 2149.24, "word": " the", "probability": 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{"start": 2434.27, "end": 2434.63, "word": " واحد،", "probability": 0.7989908854166666}, {"start": 2434.63, "end": 2434.99, "word": " اتنين", "probability": 0.9344482421875}, {"start": 2434.99, "end": 2435.59, "word": " إجت", "probability": 0.72509765625}, {"start": 2435.59, "end": 2435.75, "word": " ال", "probability": 0.53857421875}, {"start": 2435.75, "end": 2436.03, "word": " مثل", "probability": 0.953369140625}, {"start": 2436.03, "end": 2436.19, "word": " الآن", "probability": 0.6629638671875}, {"start": 2436.19, "end": 2436.39, "word": " على", "probability": 0.9453125}, {"start": 2436.39, "end": 2436.95, "word": " أكم؟", "probability": 0.7727864583333334}], "temperature": 1.0}, {"id": 103, "seek": 245523, "start": 2437.41, "end": 2455.23, "text": "تلاتة لو واحدة رقمت من هنا واحد اتنين هتقول تلاتة اربعة هتخل ال مثل على خمسة ان هو الأصحى اذا من هنا برقم واحد اتنين تلاتة اربعة خمسة ال three مثل Cyclopentane المركب اللي بعده", "tokens": [2655, 1211, 9307, 3660, 45164, 36764, 24401, 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"probability": 0.95458984375}, {"start": 2501.43, "end": 2501.55, "word": " و", "probability": 0.849609375}, {"start": 2501.55, "end": 2501.67, "word": " هذا", "probability": 0.95458984375}, {"start": 2501.67, "end": 2501.85, "word": " one", "probability": 0.92138671875}, {"start": 2501.85, "end": 2502.29, "word": " three", "probability": 0.96142578125}, {"start": 2502.29, "end": 2503.07, "word": " لكن", "probability": 0.84033203125}, {"start": 2503.07, "end": 2504.45, "word": " هذا", "probability": 0.953125}, {"start": 2504.45, "end": 2504.59, "word": " ال", "probability": 0.91796875}, {"start": 2504.59, "end": 2504.73, "word": " one", "probability": 0.88232421875}, {"start": 2504.73, "end": 2505.13, "word": " three", "probability": 0.94921875}, {"start": 2505.13, "end": 2505.85, "word": " four", "probability": 0.63330078125}, {"start": 2505.85, "end": 2506.37, "word": " five", "probability": 0.92626953125}, {"start": 2506.37, "end": 2506.77, "word": " six", "probability": 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"probability": 0.99560546875}, {"start": 2515.29, "end": 2516.27, "word": " five", "probability": 0.2958984375}, {"start": 2516.27, "end": 2516.65, "word": " brom", "probability": 0.191650390625}, {"start": 2516.65, "end": 2516.89, "word": " one", "probability": 0.265869140625}, {"start": 2516.89, "end": 2517.19, "word": " three", "probability": 0.92041015625}, {"start": 2517.19, "end": 2520.09, "word": " cyclohexadiene", "probability": 0.6335042317708334}, {"start": 2520.09, "end": 2520.83, "word": " لو", "probability": 0.64794921875}, {"start": 2520.83, "end": 2521.43, "word": " تلاتة", "probability": 0.947265625}, {"start": 2521.43, "end": 2521.67, "word": " double", "probability": 0.787109375}, {"start": 2521.67, "end": 2522.23, "word": " bonds", "probability": 0.75146484375}, {"start": 2522.23, "end": 2524.29, "word": " تريين", "probability": 0.5240071614583334}, {"start": 2524.29, "end": 2524.91, "word": " تلاتة", "probability": 0.88916015625}, {"start": 2524.91, "end": 2525.53, "word": " تريين", "probability": 0.8313802083333334}, {"start": 2525.53, "end": 2525.61, "word": " و", "probability": 0.5263671875}, {"start": 2525.61, "end": 2526.57, "word": " بتحطوا", "probability": 0.865966796875}, {"start": 2526.57, "end": 2528.99, "word": " الأرقام", "probability": 0.947265625}, {"start": 2528.99, "end": 2529.13, "word": " و", "probability": 0.8125}, {"start": 2529.13, "end": 2529.99, "word": " بتنتبهولها", "probability": 0.898193359375}, {"start": 2529.99, "end": 2530.47, "word": " لو", "probability": 0.607421875}, {"start": 2530.47, "end": 2531.03, "word": " أربعة", "probability": 0.9026692708333334}, {"start": 2531.03, "end": 2531.33, "word": " double", "probability": 0.923828125}, {"start": 2531.33, "end": 2531.77, "word": " bonds", "probability": 0.923828125}], "temperature": 1.0}, {"id": 107, "seek": 255437, "start": 2533.63, "end": 2554.37, "text": "تتراين و هكذا واضح؟ لكن هنا يجب أن ننوح لأمر لحظة ال Cyclohexane هذا ايش اسمه؟ Cyclohexane هذا تنتين", 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"probability": 0.85107421875}, {"start": 2590.63, "end": 2590.83, "word": " double", "probability": 0.7890625}, {"start": 2590.83, "end": 2591.17, "word": " bond", "probability": 0.90771484375}, {"start": 2591.17, "end": 2591.41, "word": " هاي", "probability": 0.744873046875}, {"start": 2591.41, "end": 2591.77, "word": " بداية", "probability": 0.97900390625}, {"start": 2591.77, "end": 2592.01, "word": " اللي", "probability": 0.971923828125}, {"start": 2592.01, "end": 2592.33, "word": " بعدها", "probability": 0.725341796875}, {"start": 2592.33, "end": 2592.45, "word": " هاي", "probability": 0.6475830078125}, {"start": 2592.45, "end": 2592.75, "word": " بداية", "probability": 0.98193359375}, {"start": 2592.75, "end": 2592.97, "word": " اللي", "probability": 0.99609375}, {"start": 2592.97, "end": 2593.53, "word": " بعدها", "probability": 0.889404296875}, {"start": 2593.53, "end": 2593.97, "word": " و", "probability": 0.58349609375}, {"start": 2593.97, "end": 2594.29, "word": " تروح", "probability": 0.9860026041666666}, {"start": 2594.29, "end": 2595.25, "word": " تسميه", "probability": 0.98486328125}, {"start": 2595.25, "end": 2596.99, "word": " one", "probability": 0.6455078125}, {"start": 2596.99, "end": 2598.17, "word": " three", "probability": 0.81494140625}, {"start": 2598.17, "end": 2599.49, "word": " five", "probability": 0.9130859375}, {"start": 2599.49, "end": 2603.95, "word": " cyclohexatriene", "probability": 0.8004557291666666}, {"start": 2603.95, "end": 2604.53, "word": " هذا", "probability": 0.86572265625}, {"start": 2604.53, "end": 2605.27, "word": " الاسم", "probability": 0.8330078125}, {"start": 2605.27, "end": 2606.67, "word": " غير", "probability": 0.99609375}, {"start": 2606.67, "end": 2607.19, "word": " مقبول", "probability": 0.9794921875}], "temperature": 1.0}, {"id": 110, "seek": 263601, "start": 2607.91, "end": 2636.01, "text": "هذا المركب أخد اسم شهرة عبر التاريخ من ايام ما فصلوا العالم فرده في ال .. يمكن الف وتمنمية ولا اشي زي هيك، خمسة و عشرين زمان، قبل متين سنة، أخد اسم بنزين فما بنسميه إطلاقا Cyclohexatriene ف Cyclohexatriene is not a correct name، شو ال correct name؟ بنزين", "tokens": [3224, 15730, 9673, 31747, 3555, 5551, 9778, 3215, 24525, 2304, 13412, 3224, 25720, 6225, 26890, 16712, 9640, 1829, 9778, 9154, 1975, 1829, 10943, 19446, 6156, 36520, 14407, 18863, 45340, 6156, 2288, 3215, 3224, 8978, 2423, 4386, 7251, 43020, 27188, 34683, 27842, 2304, 10632, 49429, 1975, 8592, 1829, 30767, 1829, 39896, 4117, 12399, 16490, 2304, 3794, 3660, 4032, 6225, 46309, 9957, 30767, 2304, 7649, 12399, 12174, 36150, 44650, 9957, 8608, 1863, 3660, 12399, 5551, 9778, 3215, 24525, 2304, 44945, 11622, 9957, 6156, 15042, 44945, 38251, 1829, 3224, 11933, 9566, 15040, 4587, 995, 10295, 66, 752, 675, 87, 31674, 1450, 6156, 10295, 66, 752, 675, 87, 31674, 1450, 307, 406, 257, 3006, 1315, 12399, 13412, 2407, 2423, 3006, 1315, 22807, 44945, 11622, 9957], "avg_logprob": -0.1790471243076637, "compression_ratio": 1.639344262295082, "no_speech_prob": 0.0, "words": [{"start": 2607.91, "end": 2608.29, "word": "هذا", "probability": 0.982666015625}, {"start": 2608.29, "end": 2608.87, "word": " المركب", "probability": 0.8401692708333334}, {"start": 2608.87, "end": 2609.21, "word": " أخد", "probability": 0.8680013020833334}, {"start": 2609.21, "end": 2609.49, "word": " اسم", "probability": 0.915283203125}, {"start": 2609.49, "end": 2610.01, "word": " شهرة", "probability": 0.9788411458333334}, {"start": 2610.01, "end": 2610.63, "word": " عبر", "probability": 0.985107421875}, {"start": 2610.63, "end": 2611.39, "word": " التاريخ", "probability": 0.9959716796875}, {"start": 2611.39, "end": 2611.85, "word": " من", "probability": 0.97314453125}, {"start": 2611.85, "end": 2612.39, "word": " ايام", "probability": 0.723388671875}, {"start": 2612.39, "end": 2612.57, "word": " ما", "probability": 0.9638671875}, {"start": 2612.57, "end": 2613.21, "word": " فصلوا", "probability": 0.8404947916666666}, {"start": 2613.21, "end": 2613.93, "word": " العالم", "probability": 0.98974609375}, {"start": 2613.93, "end": 2614.59, "word": " فرده", "probability": 0.8001708984375}, {"start": 2614.59, "end": 2614.75, "word": " في", "probability": 0.83837890625}, {"start": 2614.75, "end": 2615.11, "word": " ال", "probability": 0.7392578125}, {"start": 2615.11, "end": 2615.57, "word": " ..", "probability": 0.59521484375}, {"start": 2615.57, "end": 2616.39, "word": " يمكن", "probability": 0.88525390625}, {"start": 2616.39, "end": 2616.65, "word": " الف", "probability": 0.384033203125}, {"start": 2616.65, "end": 2617.37, "word": " وتمنمية", "probability": 0.78857421875}, {"start": 2617.37, "end": 2617.61, "word": " ولا", "probability": 0.5712890625}, {"start": 2617.61, "end": 2617.91, "word": " اشي", "probability": 0.74462890625}, {"start": 2617.91, "end": 2618.15, "word": " زي", "probability": 0.96728515625}, {"start": 2618.15, "end": 2619.05, "word": " هيك،", "probability": 0.7305501302083334}, {"start": 2619.05, "end": 2619.43, "word": " خمسة", "probability": 0.87548828125}, {"start": 2619.43, "end": 2619.51, "word": " و", "probability": 0.9833984375}, {"start": 2619.51, "end": 2619.97, "word": " عشرين", "probability": 0.87109375}, {"start": 2619.97, "end": 2621.55, "word": " زمان،", "probability": 0.8133544921875}, {"start": 2621.55, "end": 2621.75, "word": " قبل", "probability": 0.7191162109375}, {"start": 2621.75, "end": 2622.09, "word": " متين", "probability": 0.787353515625}, {"start": 2622.09, "end": 2622.71, "word": " سنة،", "probability": 0.86553955078125}, {"start": 2622.71, "end": 2623.57, "word": " أخد", "probability": 0.9306640625}, {"start": 2623.57, "end": 2623.83, "word": " اسم", "probability": 0.984130859375}, {"start": 2623.83, "end": 2624.33, "word": " بنزين", "probability": 0.9485677083333334}, {"start": 2624.33, "end": 2626.33, "word": " فما", "probability": 0.8349609375}, {"start": 2626.33, "end": 2627.01, "word": " بنسميه", "probability": 0.962158203125}, {"start": 2627.01, "end": 2627.77, "word": " إطلاقا", "probability": 0.87421875}, {"start": 2627.77, "end": 2630.97, "word": " Cyclohexatriene", "probability": 0.7723214285714286}, {"start": 2630.97, "end": 2631.41, "word": " ف", "probability": 0.72412109375}, {"start": 2631.41, "end": 2632.51, "word": " Cyclohexatriene", "probability": 0.93701171875}, {"start": 2632.51, "end": 2632.75, "word": " is", "probability": 0.85400390625}, {"start": 2632.75, "end": 2633.17, "word": " not", "probability": 0.96533203125}, {"start": 2633.17, "end": 2633.45, "word": " a", "probability": 0.93603515625}, {"start": 2633.45, "end": 2633.75, "word": " correct", "probability": 0.951171875}, {"start": 2633.75, "end": 2634.03, "word": " name،", "probability": 0.6805419921875}, {"start": 2634.03, "end": 2634.13, "word": " شو", "probability": 0.85595703125}, {"start": 2634.13, "end": 2634.25, "word": " ال", "probability": 0.67578125}, {"start": 2634.25, "end": 2634.53, "word": " correct", "probability": 0.96337890625}, {"start": 2634.53, "end": 2635.03, "word": " name؟", "probability": 0.942626953125}, {"start": 2635.03, "end": 2636.01, "word": " بنزين", "probability": 0.853515625}], "temperature": 1.0}, {"id": 111, "seek": 263856, "start": 2636.72, "end": 2638.56, "text": "وبهيك بننهي اليوم ان شاء الله", "tokens": [37746, 3224, 1829, 4117, 44945, 1863, 3224, 1829, 45595, 20498, 16472, 13412, 16606, 21984], "avg_logprob": -0.16653645237286885, "compression_ratio": 1.0392156862745099, "no_speech_prob": 0.0, "words": [{"start": 2636.7200000000003, "end": 2637.26, "word": "وبهيك", "probability": 0.8765869140625}, {"start": 2637.26, "end": 2637.8, "word": " بننهي", "probability": 0.79705810546875}, {"start": 2637.8, "end": 2638.08, "word": " اليوم", "probability": 0.973876953125}, {"start": 2638.08, "end": 2638.18, "word": " ان", "probability": 0.60791015625}, {"start": 2638.18, "end": 2638.44, "word": " شاء", "probability": 0.98779296875}, {"start": 2638.44, "end": 2638.56, "word": " الله", "probability": 0.95458984375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2639.45875, "duration_after_vad": 2497.617499999992}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hJ0uUjaPUvk.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hJ0uUjaPUvk.srt
new file mode 100644
index 0000000000000000000000000000000000000000..6446194d71a92ad00170bb6ea5777f27337bf576
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hJ0uUjaPUvk.srt
@@ -0,0 +1,1440 @@
+
+1
+00:00:20,180 --> 00:00:26,240
+بسم الله الرحمن الرحيم الفصل التاسع موضوعه ال
+
+2
+00:00:26,240 --> 00:00:31,480
+aldehydes and ketones طبعا الـ aldehydes and
+
+3
+00:00:31,480 --> 00:00:36,420
+ketones ربما أنتم لاحظتم أنه عائلتان، مش عائلة
+
+4
+00:00:36,420 --> 00:00:41,000
+واحدة. لو اطلعنا هنلاقي أن الـ aldehydes و الـ
+
+5
+00:00:41,000 --> 00:00:47,000
+ketones هم جزء من عائلة أكبر، جزء من عائلة أكبر
+
+6
+00:00:47,000 --> 00:00:53,230
+اسمها الكربونيل containing compounds، يعني المركبات
+
+7
+00:00:53,230 --> 00:00:56,870
+التي بتحتوي على مجموعة الكربونيل. الآن، أيش مجموعة
+
+8
+00:00:56,870 --> 00:01:02,490
+الكربونيل؟ مجموعة الكربونيل هي الـ C double bond O.
+
+9
+00:01:02,490 --> 00:01:08,130
+واضح؟ الـ C double bond O هي المجموعة التي اسمها أيش؟
+
+10
+00:01:08,130 --> 00:01:15,110
+كربونيل. الآن، كثير في مركبات... كثير في مركبات
+
+11
+00:01:15,110 --> 00:01:19,530
+فيهم هذه المجموعة الـ C double bond O. يعني من هذول
+
+12
+00:01:19,530 --> 00:01:23,910
+المركبات، الـ aldehydes لما يكون عند الـ C double
+
+13
+00:01:23,910 --> 00:01:28,970
+bond O مجموعة R و H على الجهة الثانية منهم، الـ
+
+14
+00:01:28,970 --> 00:01:32,110
+ketones لما تكون الـ C double bond O محشورة بين
+
+15
+00:01:32,110 --> 00:01:36,990
+مجموعتين R. منهم الـ Carboxylic Acids، الـ C double
+
+16
+00:01:36,990 --> 00:01:41,750
+bond O متصلة بـ OH. الآن، المركبات التي ضايلة
+
+17
+00:01:41,750 --> 00:01:46,030
+بنسميها مشتقات من الـ Carboxylic Acids، منها الـ esters: C double bond O OR، منها الأميدات: C double bond O
+
+18
+00:01:46,030 --> 00:01:49,970
+NH2، منها الـ acid chlorides: C double bond O Cl، وفي كمان مركب
+
+19
+00:01:49,970 --> 00:01:57,970
+آخر موجود ومشهور، ولو مش مكتوب هنا: R C double bond
+
+20
+00:01:57,970 --> 00:02:03,030
+O O C double bond O R ثانية. هذا بنسميه acid
+
+21
+00:02:03,030 --> 00:02:09,150
+anhydride، بنسميه acid anhydride.
+
+22
+00:02:09,150 --> 00:02:15,610
+الآن، اللي بتطلع على هذه العائلة الكبيرة كثير، خلينا
+
+23
+00:02:17,770 --> 00:02:23,130
+نسميه عائلة الكربونيل compounds.  هيلحظ أنه إحنا
+
+24
+00:02:23,130 --> 00:02:27,630
+صار لنا بنحكي عن عائلات فرعية موجودة فيها. واحد، اثنين،
+
+25
+00:02:27,630 --> 00:02:31,890
+ثلاثة، أربعة، خمسة، ستة، سبعة، يعني عدد كبير من العائلات
+
+26
+00:02:31,890 --> 00:02:38,890
+الفرعية جوا العائلة العاملة، هي عائلة الـ carbonyl
+
+27
+00:02:38,890 --> 00:02:42,710
+compounds، المركبات التي بتحتوي على مجموعة
+
+28
+00:02:42,710 --> 00:02:46,390
+الـ C double bond O. لحسن الحظ أن هدول العائلات
+
+29
+00:02:46,390 --> 00:02:53,690
+بيقسموا أو بيجمعوا إلى عائلتين:  الـ aldehydes و الـ ketones.
+
+30
+00:02:54,350 --> 00:03:01,030
+في كل كتب الكيمياء العضوية بتلاقوهم محطوطين مع بعض
+
+31
+00:03:01,030 --> 00:03:04,790
+في chapter واحد، والأحماض ومشتقاتها بنسميها acids and
+
+32
+00:03:04,790 --> 00:03:11,170
+their derivatives، الـ acid derivatives. يعني هدول
+
+33
+00:03:11,170 --> 00:03:15,710
+derivatives للـ acids، مشتقات. derivative يعني أيش؟
+
+34
+00:03:15,710 --> 00:03:19,290
+الـ acid derivatives. لو قلنا لكم شو هم؟ الـ esters، الأميدات،
+
+35
+00:03:19,970 --> 00:03:25,510
+الـ acid halides، و الـ acid anhydride. هدول الخمسة بنحطهم
+
+36
+00:03:25,510 --> 00:03:32,190
+بعائلة واحدة. لاحظوا صار عندي تقسيم. بدل ما هو لسبع
+
+37
+00:03:32,190 --> 00:03:38,330
+عائلات كلها مختلفة، حطيناهم بإيش؟ بعائلتين فقط:
+
+38
+00:03:38,330 --> 00:03:43,370
+الـ aldehydes و الـ ketones، عائلة الـ acids و مشتقاتها. كلهم دول
+
+39
+00:03:43,370 --> 00:03:48,850
+عائلة واحدة. ولذلك، عادة في الكيمياء العضوية، في غالب الكتب
+
+40
+00:03:48,850 --> 00:03:53,290
+هتلاقي أنه بنعمل عن كل هذه المركبات chapter، يعني
+
+41
+00:03:53,290 --> 00:03:56,630
+فاصلين. هدول بنحطهم بفصل لحالهم، وهدول بنحطهم بفصل
+
+42
+00:04:01,490 --> 00:04:02,710
+لحالهم.
+
+44
+00:04:05,560 --> 00:04:10,240
+لسه بإمكاننا نبسط الموضوع، بإمكاننا نبسط الموضوع
+
+45
+00:04:10,240 --> 00:04:16,230
+أكثر كثير من هيك. نقول ليش هذه التقسيمة، وكيف أنا
+
+46
+00:04:16,230 --> 00:04:20,450
+الشيء الكثير بدي أسهل التعامل معه. بنقول هذه
+
+47
+00:04:20,450 --> 00:04:26,050
+التقسيمة قائمة على كلمتين فقط. كلمتين، اللي بيفهم
+
+48
+00:04:26,050 --> 00:04:31,150
+هدول الكلمتين، بنقدر نقول عنه أنه فيهم ست إلى سبع
+
+49
+00:04:31,150 --> 00:04:36,090
+محاضرات للأمام، هنضلنا نعيد ونزيد فيهم بنفس
+
+50
+00:04:36,090 --> 00:04:42,790
+الكلمتين. واضح؟ صعب على البني آدم يفهم كلمتين. كان
+
+51
+00:04:42,790 --> 00:04:48,130
+زمان برنامج بالتلفزيون، بالإذاعة، اسمه كلمتين وبس.
+
+52
+00:04:48,130 --> 00:04:52,630
+خلوه ميرك معاكم. مين اللي كان يقدم هذا البرنامج
+
+53
+00:04:52,630 --> 00:04:58,330
+زمان؟ أسألة الآباء والأجداد. المهم، أيش الكلمتين
+
+54
+00:04:58,330 --> 00:05:06,290
+المرتبطتين بكل هذه العائلات؟ الكلمة الأولى خاصة بأهم
+
+55
+00:05:06,290 --> 00:05:12,070
+تفاعل أساسي لهذول المركبات، اللي هم الـ aldehydes و
+
+56
+00:05:12,070 --> 00:05:19,630
+الـ ketones. بيتفاعلوا تفاعل الـ addition، الإضافة. الـ
+
+57
+00:05:19,630 --> 00:05:24,730
+addition. والكلمة الثانية لهذول الخمسة اللي ضايلين
+
+58
+00:05:24,730 --> 00:05:29,750
+معهم، الـ unhydrated اللي شطبناه، بيتفاعلوا تفاعل الـ
+
+59
+00:05:29,750 --> 00:05:32,930
+substitution، الإبدال. تمام؟
+
+60
+00:05:37,060 --> 00:05:43,120
+إذن، سبب تقسيم هدول السبعة مركبات إلى عائلات، يعني
+
+61
+00:05:43,120 --> 00:05:46,440
+أحيانًا الإنسان كان ممكن يسأل: إذا السبعة بدنا
+
+62
+00:05:46,440 --> 00:05:50,180
+نعملهم عائلتين أو chapterين، كان خلينا أربعة في chapter
+
+63
+00:05:50,180 --> 00:05:56,620
+وثلاثة في chapter ثاني. ليش خلينا اثنين وخمسة؟ تمام؟ لأ،
+
+64
+00:05:56,620 --> 00:06:03,470
+التقسيم مش تقسيم عددي، التقسيم تقسيم وظيفي. بمعنى أيش؟
+
+65
+00:06:03,470 --> 00:06:10,370
+التفاعل الأساسي لهذه العائلة هو تفاعل الإضافة؟ أيش
+
+66
+00:06:10,370 --> 00:06:16,450
+التفاعل الأساسي لهذه العائلة هو تفاعل الإبدال؟
+
+67
+00:06:16,450 --> 00:06:21,310
+ولذلك، لو أي طالب organic chemistry بده يدخل مقابل
+
+68
+00:06:21,310 --> 00:06:25,510
+التوظيف، ما ينفعش يمسك ورق وجلم ويكتب، لكن أبسط
+
+69
+00:06:25,510 --> 00:06:29,510
+سؤال بده يسأله ببساطة: أيش التفاعل الأساسي
+
+70
+00:06:29,510 --> 00:06:33,660
+للـ aldehydes و الـ ketones؟ ما يعرفش يجاوب. أيش التفاعل
+
+71
+00:06:33,660 --> 00:06:38,720
+الأساسي للـ acids ومشتقاتها؟ ما يعرفش يجاوب. نراكم في
+
+72
+00:06:38,720 --> 00:06:43,750
+السنة القادمة. بالله مش يكون دراسة organic. واضح؟ اهتموا
+
+73
+00:06:43,750 --> 00:06:48,950
+كثير بهذول الكلمتين. اللي بيفهموهم جيدًا بيكونوا
+
+74
+00:06:48,950 --> 00:06:53,530
+فاهمين سبع عائلات. اللي بيفهموا هذول الكلمتين جيدًا
+
+75
+00:06:53,530 --> 00:06:58,350
+بيكونوا فاهمين أيش؟ سبع عائلات. ولذلك، خلينا نتعمق
+
+76
+00:06:58,350 --> 00:07:03,070
+أكثر بفهم هدول الكلمتين. خلينا نتعمق أكثر بفهم هدول
+
+77
+00:07:03,070 --> 00:07:07,280
+الكلمتين. الآن، إحنا قلنا أيش الـ carbonyl group؟ الـ
+
+78
+00:07:07,280 --> 00:07:11,960
+C double bond O. طب لو كتبنا تحت الكربونيل C double
+
+79
+00:07:11,960 --> 00:07:17,120
+bond O، ورجعنا للكلام اللي بنعرفه بخصوص السالبية
+
+80
+00:07:17,120 --> 00:07:22,640
+الكهربية. مين أكثر سالبية؟ الـ oxygen. مين أقل سالبية؟ الـ
+
+81
+00:07:22,640 --> 00:07:26,880
+carbon. إذًا هذه الـ carbon partially positive، وهذه
+
+82
+00:07:26,880 --> 00:07:32,180
+الـ oxygen partially negative. واضح؟ الآن، المحور
+
+83
+00:07:32,180 --> 00:07:36,410
+الأساسي في فهم الكيمياء كاملة بتاعت السبع عائلات
+
+84
+00:07:36,410 --> 00:07:43,210
+هدول، بينطلق من أنه الـ carbon موجبة، يعني يمكن أهم
+
+85
+00:07:43,210 --> 00:07:49,530
+كلمة في فهم هذه العائلات السبعة كلها مجتمعة، يعني
+
+86
+00:07:49,530 --> 00:07:54,250
+في فهم الـ two chapters، أن نقول أن هذا الـ carbon
+
+87
+00:07:54,250 --> 00:07:59,030
+هاي، بدنا نعلمها فيهم كلهم باللون الأحمر، إشارة أنها
+
+88
+00:07:59,030 --> 00:08:07,920
+موجبة. الآن، من باب تحصيل الحاصل، الموجب لما يتفاعل...
+
+89
+00:08:07,920 --> 00:08:14,280
+بنفتح بس على واحدة منهم، الموجب لما يتفاعل، أيش بده؟
+
+90
+00:08:14,280 --> 00:08:20,460
+بلغة الكيمياء، الـ electrophile. الموجب لما يتفاعل بده
+
+91
+00:08:20,460 --> 00:08:24,980
+سالب، بده nucleophile. بناء على ذلك، طالما جميعهم
+
+92
+00:08:24,980 --> 00:08:29,260
+عندهم الـ carbon الموجبة، إذًا جميعهم تفاعلهم الأساسي
+
+93
+00:08:29,260 --> 00:08:33,580
+بيستنوا nucleophile. واضح؟ يعني بدي أجيب أن
+
+94
+00:08:33,580 --> 00:08:40,360
+nucleophile، وهذا عليه زوج من الإلكترونات زي ما
+
+95
+00:08:40,360 --> 00:08:43,500
+أنتوا عارفين، سواء كان مشحون أو متعادل، مش موضوعنا
+
+96
+00:08:43,500 --> 00:08:47,480
+... وين بده يروح؟ يجري يهاجم. الـ nucleophile على الـ
+
+97
+00:08:47,480 --> 00:08:52,420
+carbon. نفس الـ nucleophile... نفس الـ nucleophile
+
+98
+00:08:52,420 --> 00:08:59,670
+على الـ carbon. الآن، هذا الـ nucleophile لما بيهاجم
+
+99
+00:08:59,670 --> 00:09:04,370
+على الكربون، مرة هيعمل تفاعل إضافة، في الحالتين
+
+100
+00:09:04,370 --> 00:09:08,870
+الأولانيات، وفي باقي الحالات هيعمل تفاعل إبدال. إذًا
+
+101
+00:09:08,870 --> 00:09:13,530
+لو جينا سألناكم، قلنا لكم الـ aldehydes بيعملوا
+
+102
+00:09:13,530 --> 00:09:19,150
+addition، بتقولوا صح. الـ acids ومشتقاتها بيعملوا
+
+103
+00:09:19,150 --> 00:09:24,510
+substitution، صح. لو سألنا: هل يا ترى الـ nucleophilic
+
+104
+00:09:24,510 --> 00:09:27,850
+addition و الـ nucleophilic substitution، ولا الـ
+
+105
+00:09:27,850 --> 00:09:30,630
+electrophilic addition و الـ electrophilic
+
+106
+00:09:30,630 --> 00:09:35,440
+substitution؟ الـ nucleophilic. إذًا الآن، بنقدر نزيد
+
+107
+00:09:35,440 --> 00:09:40,440
+كلمة: إن الـ aldehydes تفاعلهم الأساسي اللي بدي إياه
+
+108
+00:09:40,440 --> 00:09:45,340
+بالضبط، الـ nucleophilic addition. وفهمنا ليش؟ الـ
+
+109
+00:09:45,340 --> 00:09:50,460
+nucleophilic addition. والأحماض ومشتقاتها تفاعلهم
+
+110
+00:09:50,460 --> 00:09:56,390
+الأساسي، الـ nucleophilic substitution. واضح؟ لحد الآن
+
+111
+00:09:56,390 --> 00:10:02,230
+تمام. الآن، بيصير أيش الناتج اللي بده يتكون عندي؟ أيش
+
+112
+00:10:02,230 --> 00:10:06,510
+النتاج اللي بده يتكون في حالة ما كنا بنحكي عن الـ
+
+113
+00:10:06,510 --> 00:10:10,870
+aldehydes و الـ ketones، addition معناه أن الـ C
+
+114
+00:10:10,870 --> 00:10:15,070
+double bond O أو الـ double bond بتصير single bond. مش
+
+115
+00:10:15,070 --> 00:10:18,050
+هيك؟ إحنا قلنا الـ addition يعني مجرد ماذا؟ الـ
+
+116
+00:10:18,050 --> 00:10:21,830
+nucleophile يهاجم هنا ويعمل رابطة. هل معقول يصير
+
+117
+00:10:21,830 --> 00:10:26,290
+عندي خمس روابط؟ لأ، إذًا هذه الرابطة بتتحرك، بتصبح O
+
+118
+00:10:26,290 --> 00:10:31,470
+minus، بتصفح OH، بتاخد H من اللي الـ nucleophile أو
+
+119
+00:10:31,470 --> 00:10:36,310
+من الـ solvent. إذًا الناتج اللي هيصير عندي، ناتج الـ
+
+120
+00:10:36,310 --> 00:10:40,310
+addition، ببساطة إنه الـ C double bond O تبعت الـ ketone
+
+121
+00:10:40,310 --> 00:10:43,830
+أو تبعت الـ aldehyde، شو بده تصير؟ OH.
+
+122
+00:10:46,820 --> 00:10:50,500
+شوفت وين الـ addition؟ هنا تم الـ addition، double
+
+123
+00:10:50,500 --> 00:10:56,980
+single. إضافة. شو هو الـ addition؟ تحويل الـ double
+
+124
+00:10:56,980 --> 00:11:00,520
+bond إلى single bond. إذًا في الـ aldehydes و الـ
+
+125
+00:11:00,520 --> 00:11:05,060
+ketones، الـ C double bond O هتصير OH. طبّاق
+
+126
+00:11:05,060 --> 00:11:12,240
+المجموعات R زي ما هي، H أو R زي ما هي، واللي إجه
+
+127
+00:11:12,240 --> 00:11:14,900
+هنا الـ nucleophile.
+
+128
+00:11:17,240 --> 00:11:20,840
+مشهور الـ nucleophile اللي هاجمه، عام الرابطة. إذًا
+
+129
+00:11:20,840 --> 00:11:26,440
+هذا الشكل العام تبع نتيجة تفاعل الـ aldehydes أو الـ
+
+130
+00:11:26,440 --> 00:11:30,400
+ketones. يعني لو إجينا قلنا مثلًا للـ nucleophile
+
+131
+00:11:30,400 --> 00:11:32,900
+H2O،
+
+132
+00:11:35,400 --> 00:11:39,820
+ماذا سيحصل؟ هذه في كل الأحوال ستصبح OH مع كل أنواع
+
+133
+00:11:39,820 --> 00:11:44,040
+الـ nucleophiles. لكن الـ H2O ماذا تضع هنا؟ OH
+
+134
+00:11:44,040 --> 00:11:48,140
+دائمًا الـ nucleophile المتعدد سنخصه من OH. ولو قلنا
+
+135
+00:11:48,140 --> 00:11:53,420
+لـ nucleophile OH−، سيضع أيضًا OH. وبعد ذلك نضع
+
+136
+00:11:53,420 --> 00:11:57,880
+acid، ستصبح هذه OH. إذًا لو لـ nucleophile H2O أو OH−،
+
+137
+00:11:57,880 --> 00:12:02,700
+سيصبح عندكم على الكربون OH من الألديهايد الأصلي و
+
+138
+00:12:02,700 --> 00:12:10,190
+OH المهاجمة. لو النيوكليوفايل كحول، شوف دي جاهزة، OR.
+
+139
+00:12:10,190 --> 00:12:17,210
+هذه OH لا خلافة فيها، ثابتة. هذه ثابتة، اللي هي الـ C
+
+140
+00:12:17,210 --> 00:12:20,290
+double bond O. لكن أنا بقول: النيوكليوفايل المية
+
+141
+00:12:20,290 --> 00:12:29,950
+بتحط OH، الكحول بيحط OR، الـ HCl بيحط Cl، وهكذا. واضحة
+
+142
+00:12:29,950 --> 00:12:36,010
+الفكرة؟ هي هذا الشكل العام تبع تفاعل إضافة، وهو الذي
+
+143
+00:12:36,010 --> 00:12:41,130
+يميز جميع تفاعلات الـ aldehydes و الـ ketones. وهناخد
+
+144
+00:12:41,130 --> 00:12:46,210
+أمثلة، بتصير كلها تكرار. نضل نعيد نقول: بيعمل إضافة، و
+
+145
+00:12:46,210 --> 00:12:52,290
+بس في كل الأمثلة اللي بناخدها، أيش بتصير القصة؟ هنا
+
+146
+00:12:52,290 --> 00:12:55,470
+نقول: إيه؟ شو هو الـ nucleophile؟ إذا كان الـ nucleophile
+
+147
+00:12:55,470 --> 00:12:58,450
+ماء، فهذه كذا. إذا كان كحول، هذه كذا. إذا كان
+
+148
+00:12:58,450 --> 00:13:02,870
+سيانيد، كذا. إذا كان هيدريد، هذه كذا. يعني فقط هذا
+
+149
+00:13:02,870 --> 00:13:07,450
+المتغير الوحيد، حيصفي عندكم شو هو؟ الـ nucleophile.
+
+150
+00:13:07,450 --> 00:13:13,950
+واضح؟ الآن، لو إجينا وقلنا: نفس الـ nucleophile بده
+
+151
+00:13:13,950 --> 00:13:20,770
+يهاجم على الكيتون، على الكربون الحمراء، عفوًا، على
+
+152
+00:13:20,770 --> 00:13:24,870
+الـ acid. لأ، ما هو الكيتون زي الألديهايد. خلصنا منه، على
+
+153
+00:13:24,870 --> 00:13:31,630
+الـ acid أو مشتقاته، أيش بيكون التفاعل؟ هذا بيجي هنا و
+
+154
+00:13:31,630 --> 00:13:38,020
+بيطرد المجموعة هذه. واضح؟ طبعًا OH− لما تتطرد
+
+155
+00:13:38,020 --> 00:13:43,920
+بتاخد H من برة، شو هتصير؟ OR− لما تتطرد بتاخد H،
+
+156
+00:13:43,920 --> 00:13:51,460
+ROH كحول، NH2 لما تتطرد NH3، Cl− لما تتطرد
+
+157
+00:13:51,460 --> 00:13:57,140
+Cl. إذًا صار عندي هذه المجموعة هي التي تستبدل اللي
+
+158
+00:13:57,140 --> 00:14:03,380
+جنب أيش؟ اللي جنب الـ C double bond O. بناء على ذلك،
+
+159
+00:14:03,380 --> 00:14:09,940
+النتاج أيش هيكون؟ RC double bond O. هذه ما زالت زي
+
+160
+00:14:09,940 --> 00:14:15,140
+ما هي، لكن بدل الـ OH أو الـ OR أو الـ NH2، whatever
+
+161
+00:14:15,140 --> 00:14:21,120
+whatever، صار إبدال. nucleophile. نيو، ن، أ، صوديوم
+
+162
+00:14:21,120 --> 00:14:25,480
+nucleophile. واضح؟ يعني شلنا هذه المجموعة وحطينا
+
+163
+00:14:25,480 --> 00:14:29,880
+مكانها أيش؟ nucleophile. هذا substitution ولا لأ؟
+
+164
+00:14:29,880 --> 00:14:35,430
+مجموعة جاية، مجموعة طالعة. واضح؟ الفكرة، والجزء اللي
+
+165
+00:14:35,430 --> 00:14:39,390
+طلع بياخد H، بيطلع على شكل ماء، على شكل أمونيا، على
+
+166
+00:14:39,390 --> 00:14:45,380
+شكل كحول، على شكل HCl. هذا الكلام بتلاقوه بيتكرر في كل
+
+167
+00:14:45,380 --> 00:14:50,660
+عائلات الأحماض ومشتقاتها. إذًا، لو إحنا كنا حتى
+
+168
+00:14:50,660 --> 00:14:55,280
+chapter 9 هذا اللي بدنا نبدأ فيه، بدنا نعطيه عنوان
+
+169
+00:14:55,280 --> 
+
+223
+00:19:41,970 --> 00:19:46,350
+مرتبطة بالقطبية، بس هذه القيم خليني أقول تقريبية
+
+224
+00:19:46,350 --> 00:19:51,190
+ممكن مرة ثانية نجيب القيم الدقيقة، واضحة الفكرة؟
+
+225
+00:19:51,190 --> 00:19:57,930
+الـ polarity أطول إلى انعكاس علىالقطبية الآن، طيب، و
+
+226
+00:19:57,930 --> 00:20:03,370
+الآن، انعكس على شغل ثاني، الـ polar شو هي الذائبية، و
+
+227
+00:20:03,370 --> 00:20:09,470
+القاعدة العامة في الموضوع، أيش؟ like dissolves like
+
+228
+00:20:09,470 --> 00:20:15,950
+الآن، أكثر حاجة فيها قطبية، أيش؟ الكحولات اللي فيها O
+
+229
+00:20:15,950 --> 00:20:20,190
+H's، و بتذكروا حتى لما قلنا عن الكحولات، قلنا
+
+230
+00:20:20,190 --> 00:20:26,280
+ما بدنا ننسى أن الكحول في المجمعتين، في الجزء القطبي،
+
+231
+00:20:26,280 --> 00:20:33,200
+الـ R والجزء القطبي الـ OH، والجزء غير القطبي الـ R
+
+232
+00:20:33,200 --> 00:20:37,020
+وبناء على ذلك، الـ lower alcohols كانت water soluble
+
+233
+00:20:37,020 --> 00:20:42,000
+والـ higher alcohols  لم تكن water soluble، تذكرين هذه
+
+234
+00:20:42,000 --> 00:20:46,180
+المعلومة؟ الكلام نفسه بيتكرر وين؟ في الـ ketones
+
+235
+00:20:46,180 --> 00:20:50,400
+برضه الـ ketones فيهم جزء قطبي الـ C double bond O، و
+
+236
+00:20:50,400 --> 00:20:54,780
+فيهم الـ R، لما تصير الـ R هذه كبيرة، بيبطلوا يدوبوا
+
+237
+00:20:54,780 --> 00:20:57,840
+في المية، بس R صغيرة، يعني مثل، و مثل، بيصير الـ
+
+238
+00:20:57,840 --> 00:21:03,660
+acetone، الـ acetone بدوب في المية، لكن خلوها إيثيل، و
+
+239
+00:21:03,660 --> 00:21:07,760
+إيثيل، إيزوبروبيل، و إيزوبروبيل، فينيل، و إيثيل، كبرت، بتبطل
+
+240
+00:21:07,760 --> 00:21:12,140
+الدوبان في المياه، واضح؟ فالـ lower molecular weight
+
+241
+00:21:12,140 --> 00:21:14,540
+species، يعني الأشياء اللي الـ molecular weight
+
+242
+00:21:14,540 --> 00:21:18,560
+فيها قليل في الألدهيدات والكيتونات، بتكون أيش؟ water
+
+243
+00:21:18,560 --> 00:21:23,320
+soluble، كل ما الـ R كبرت، بتبطل، يعني زي، زي أيش؟
+
+244
+00:21:23,320 --> 00:21:27,720
+الكحولات، فمن الـ الديهيدات اللي بتدوب في المية بشكل
+
+245
+00:21:27,720 --> 00:21:30,600
+عام، الـ formaldehyde بتدوب في المية، بيعطي الـ
+
+246
+00:21:30,600 --> 00:21:34,340
+formalin، الـ acetaldehyde نسبياً بتدوب، بعد هيك بتبطل
+
+247
+00:21:34,340 --> 00:21:38,000
+تدوب، من الـ ketones، الـ acetone بتدوب في المية، بعد
+
+248
+00:21:38,000 --> 00:21:43,270
+هيك، كل ما يكبروا بيبتلوا يدوبوا، واضح؟ فالـ low molecular
+
+249
+00:21:43,270 --> 00:21:45,830
+weight species are soluble in water and the
+
+250
+00:21:45,830 --> 00:21:50,270
+solubility decreases، بتنقص، as the R chain gets
+
+251
+00:21:50,270 --> 00:21:54,570
+longer، كل ما كبرت الـ R كل ما قلت الذائبية، وهذا
+
+252
+00:21:54,570 --> 00:21:58,710
+الكلام أيضاً في الكحولات لاحظناه، واضحة الفكرة هذا؟
+
+253
+00:21:58,710 --> 00:22:02,710
+الكلام أيضاً لاحظناه في الكحولات
+
+254
+00:22:06,830 --> 00:22:09,910
+طيب، كيف بنسمي الـ الديهيدات و الـ ketones؟ احنا قلنا
+
+255
+00:22:09,910 --> 00:22:14,510
+أساساً، كل نظام التسمية في الكيمياء العضوية نظام سهل
+
+256
+00:22:14,510 --> 00:22:20,230
+ليش سهل؟ لأنه مبني على ذكر طول السلسلة، منتهي برمز
+
+257
+00:22:20,230 --> 00:22:28,770
+للمجموعة الوظيفية، الـ  الـ K نهايته  -AL  للـ  ألديهيد، الـ
+
+258
+00:22:28,770 --> 00:22:35,330
+-OL للكحول، الـ -ONE للـ ketone، و لذلك الـ الديهيد
+
+259
+00:22:35,330 --> 00:22:40,670
+اللي متكون من كربونة واحدة، بنقول مثانال، مثانال،
+
+260
+00:22:40,670 --> 00:22:45,130
+ماخوذ common name formaldehyde، الآن لو صاروا
+
+261
+00:22:45,130 --> 00:22:51,120
+كربونتين، أيه؟ إيثانال؟ أسيتالديهيد، الكومون نيم، لو
+
+262
+00:22:51,120 --> 00:22:56,400
+صاروا ثلاث بروبانال، بروبيونالديهيد، لو صاروا أربعة
+
+263
+00:22:56,400 --> 00:23:01,860
+بيوتانال، بيوتيرالديهيد، بيوتيرالديهيد، الآن لاحظوا
+
+264
+00:23:01,860 --> 00:23:07,320
+هتلاحظوا الفرق بين الـ aldehydes و الكحولات، يعني في
+
+265
+00:23:07,320 --> 00:23:11,520
+الكحول كنا نقول ethanol, methanol, ethanol,
+
+266
+00:23:11,620 --> 00:23:15,320
+propanol, butanol، وهنا بنقول methanol, ethanol,
+
+267
+00:23:15,440 --> 00:23:20,740
+propanol, butanol، وين الفرق؟ لأ، فيه فرق ثاني أنا
+
+268
+00:23:20,740 --> 00:23:24,760
+عارف الـ -al و الـ -ol، هذه الفرق، لكن فيه فرق ثاني
+
+269
+00:23:24,760 --> 00:23:32,360
+الاسم الكامل هنا في الكحولات، لما أجي أقول بروبانول
+
+270
+00:23:32,360 --> 00:23:36,440
+بكفي؟
+
+271
+00:23:36,440 --> 00:23:42,640
+آه، الكحول ثلاث ذرات كربون، الآن هل يجي الـ OH فيه
+
+272
+00:23:42,640 --> 00:23:47,480
+على واحد؟ one propanol، ولا على اثنين؟ two
+
+273
+00:23:47,480 --> 00:23:52,360
+propanol، واضح؟ إذا البروبانول في الكحولات منه
+
+274
+00:23:52,360 --> 00:23:59,290
+اثنين، والبيوتانول كمان، لو صارت هذه أربع كربونات، هل
+
+275
+00:23:59,290 --> 00:24:05,490
+الكحول هنا one بيوتانول،
+
+276
+00:24:05,490 --> 00:24:10,050
+ولا two بيوتانول، ولا two بيوتانول، من هنا مش ثلاثة
+
+277
+00:24:10,050 --> 00:24:18,590
+البيوتانول منه كم كحول، واضح؟ للتشين المتسلسل،
+
+278
+00:24:18,590 --> 00:24:23,430
+يعني لو جاءكوا سؤال في الامتحان، أنه للتشين بيوتانول
+
+279
+00:24:23,430 --> 00:24:30,280
+اللي زي هيك، كم كحول بالمجموع منه؟ اثنين،  هتكّون
+
+280
+00:24:30,280 --> 00:24:34,660
+إجابته غلط، واضح؟
+
+281
+00:24:34,660 --> 00:24:41,060
+ليش؟ مين تقول لي ليش الغلط؟
+
+282
+00:24:41,060 --> 00:24:47,860
+لحظة، أنا قلت المتسلسل، بعرف أنه فيه iso و فيه
+
+283
+00:24:47,860 --> 00:24:53,750
+tertiary، هذه قصة ثانية، ما بدكم تظلوا تركزوا، اه الـ
+
+284
+00:24:53,750 --> 00:24:55,910
+chiral center، مش الـ cis و الـ trans، الـ cis و الـ
+
+285
+00:24:55,910 --> 00:24:58,910
+trans كلها علاقة بالضبط بالجسور و بالحلقات، الـ
+
+286
+00:24:58,910 --> 00:25:03,870
+chiral center لما بيصير هذا هنا، و بحط OH و H ع
+
+287
+00:25:03,870 --> 00:25:08,510
+طول، صار عندي ROS من الـ two butanol، الـ two butanol
+
+288
+00:25:08,510 --> 00:25:12,390
+منه ROS، الـ one butanol ما فيه chiral center، one
+
+289
+00:25:12,390 --> 00:25:18,170
+butanol، واضح؟ طبعاً ما بننسى أنه فيه isobutanol و
+
+290
+00:25:18,170 --> 00:25:22,790
+tertiary butanol، كل هدول الأشياء لازم تكونوا
+
+291
+00:25:22,790 --> 00:25:27,470
+عارفينها، الآن الـ aldehydes اللي جابنا للكلام الـ
+
+292
+00:25:27,470 --> 00:25:32,190
+aldehydes، لأ، ما فيه منها واحد واثنين، لأن مجموعة الـ
+
+293
+00:25:32,190 --> 00:25:36,730
+aldehydes لا تكون إلا على رقم واحد، و لأنها لا
+
+294
+00:25:36,730 --> 00:25:41,310
+تكون إلا على رقم واحد، بنحط الرقم، يعني ما
+
+295
+00:25:41,310 --> 00:25:46,110
+اجيناش كتبنا إيثانال، بروبانال، بيوتانال،
+
+296
+00:25:46,110 --> 00:25:49,510
+لأنها لا تكون إلا على واحد، فالأشياء اللي
+
+297
+00:25:49,510 --> 00:25:54,830
+معروف، ضلنا ما نلزّم نكتبه، واضح؟ ومثل الـ الديهيد
+
+298
+00:25:54,830 --> 00:25:59,210
+بالمناسبة، اللي ما بيكون إلا على رقم واحد وفقط
+
+299
+00:25:59,210 --> 00:26:07,770
+على واحد، الـ acid، الحامض، الحامض ما بيكون إلا على
+
+300
+00:26:07,770 --> 00:26:09,370
+الطرف
+
+301
+00:26:11,040 --> 00:26:15,620
+هيك، هيك، ولا ممكن يكون C double bond O OH في
+
+302
+00:26:15,620 --> 00:26:21,440
+النص، مستحيل، طيب، الحامض لو أجيت رقمّت من هنا واحد،
+
+303
+00:26:21,440 --> 00:26:25,500
+اثنين، ثلاثة، أربعة، و بدي اسميه، طبعاً هقول أكيد
+
+304
+00:26:25,500 --> 00:26:30,580
+بيوتان، ما فيه لقاش، هتقولي اللي هو الحامض أيش؟
+
+305
+00:26:30,580 --> 00:26:39,300
+نهايته oic acid، oic acid، بيوتانويك أسد، الآن هل يا ترى
+
+306
+00:26:39,300 --> 00:26:44,360
+بنحط بيوتان-1-oic acid؟ لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ
+
+307
+00:26:44,360 --> 00:26:45,200
+لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ،
+
+308
+00:26:45,200 --> 00:26:46,700
+لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ
+
+309
+00:26:46,700 --> 00:26:47,880
+لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ
+
+310
+00:26:47,880 --> 00:26:48,340
+لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ
+
+311
+00:26:48,340 --> 00:26:52,440
+لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، لأ، ل
+
+312
+00:26:55,860 --> 00:27:00,100
+لأ، ممكن يكون على موقع اثنين أو ثلاثة أو أكثر، يعني
+
+313
+00:27:00,100 --> 00:27:03,900
+في الـ ketone بعد شوية هتلاحظوا لو كان عندنا خمس
+
+314
+00:27:03,900 --> 00:27:11,720
+ذرات كربون أو ستة، كم ذرة اللي رسمناهم؟ واحد،
+
+315
+00:27:11,720 --> 00:27:17,200
+اثنين، ثلاثة، أربعة، خمسة، ستة، سبعة، و أجينا قلنا من
+
+316
+00:27:17,200 --> 00:27:24,440
+هذا المركب كسلسلة، كم ketone بقدر أطلّع له؟ قولت كم
+
+317
+00:27:24,440 --> 00:27:29,620
+الديهيد بقدر أعمل منه؟ واحد، اسمه Heptanal، و الـ C
+
+318
+00:27:29,620 --> 00:27:33,140
+double bond هو Hannah و Jamal، لو قولت كم Acid
+
+319
+00:27:33,140 --> 00:27:39,020
+بقدر أطلع؟ Acid، واحد، Heptanoic Acid، لو قولت كم
+
+320
+00:27:39,020 --> 00:27:43,500
+كيتون؟ إذا أجت Hannah، two Heptanone، وإذا أجت
+
+321
+00:27:43,500 --> 00:27:47,880
+Hannah، three Heptanone، وإذا أجت Hannah، four
+
+322
+00:27:47,880 --> 00:27:56,330
+Heptanone، one, two، عفواً واحد، اثنين، ثلاث، عفواً two
+
+323
+00:27:56,330 --> 00:28:01,070
+و three و four، إذا صار عندي two هيبّتانون و three
+
+324
+00:28:01,070 --> 00:28:05,490
+هيبّتانون و four هيبّتانون، إلا لو أجت هنا، بتصير three
+
+325
+00:28:05,490 --> 00:28:08,470
+هيبّتانون من الجهة الثانية، أو لو أجت هنا، two هيبّتانون
+
+326
+00:28:08,470 --> 00:28:12,490
+من الجهة الثانية، إذا من هذا صار عندي أكثر من كيتون،
+
+327
+00:28:12,490 --> 00:28:16,930
+فالـ ketone يحتاج إلى ترقيم لما بيلزم، بينما الـ
+
+328
+00:28:16,930 --> 00:28:22,270
+الديهيد لا يكون إلا على موقع واحد، واضحة الفكرة؟
+
+329
+00:28:22,270 --> 00:28:27,970
+ومثل الديهيد الـ acid، ومثل الـ ketone، الـ alcohol، إذا
+
+330
+00:28:27,970 --> 00:28:32,990
+الأشياء اللي احنا بنسميها لازم نحط لها أرقام، اللي أنا
+
+331
+00:28:32,990 --> 00:28:35,750
+خذتوها كلها، مين يذكرنا في الأشياء اللي بتلزمها
+
+332
+00:28:35,750 --> 00:28:42,450
+أرقام؟ الأشياء اللي ما بتلزمهاش أرقام، الـ alkene بتلزم أرقام،
+
+333
+00:28:42,450 --> 00:28:47,310
+انتبهوا معايا، هاي سبع كربونات، لو كنت بعمل الكيل
+
+334
+00:28:47,310 --> 00:28:52,670
+ممكن يكون هنا أو هنا أو هنا، إذا الـ alkene بتلزم
+
+335
+00:28:52,670 --> 00:28:59,370
+أرقام، الـ alkyne، one-heptane, two-heptane, three
+
+336
+00:28:59,370 --> 00:29:05,030
+-heptane، بتلزم أرقام، الـ alcohol، one-heptanol, two
+
+337
+00:29:05,030 --> 00:29:08,690
+-heptanol, three-heptanol, four-heptanol، بتلزم
+
+338
+00:29:08,690 --> 00:29:14,920
+أرقام، الكيتون، two-heptanone، three-heptanone، four
+
+339
+00:29:14,920 --> 00:29:20,340
+-heptanone، بتلزم أرقام، إذا الـ الكين والـ الكاين
+
+340
+00:29:20,340 --> 00:29:25,760
+والكحول والكيتون، هدول بتلزمهم أرقام، لكن لو كنت
+
+341
+00:29:25,760 --> 00:29:30,960
+بحكي عن الديهيد، لأ، هيبّتانال فقط، عن امرأة واحدة
+
+342
+00:29:31,450 --> 00:29:36,250
+acid, heptanoic acid، فالـ الديهيد والـ أسيد ما بيكونوا
+
+343
+00:29:36,250 --> 00:29:54,710
+غير على موقع واحد، واضحة ثانية الفكرة؟ حابين
+
+344
+00:29:54,710 --> 00:30:02,640
+تسمعوا الجواب؟ لا بأس، السؤال اللي سألته زميلتكم أنه
+
+345
+00:30:02,640 --> 00:30:07,460
+لو كان في عندها رابطة ثلاثية و رابطة ثنائية، كيف
+
+346
+00:30:07,460 --> 00:30:12,600
+بدي أسمّي المركب؟ تمام؟ لو عندي رابطة ثلاثية و رابطة
+
+347
+00:30:12,600 --> 00:30:16,800
+ثنائية، كيف بدي أسمّي المركب؟ المركب بدي يكون فيه الـ
+
+348
+00:30:16,800 --> 00:30:23,190
+ene و الـ yne، الآن، alphabetically، الـ E قبل الـ Y،
+
+349
+00:30:23,190 --> 00:30:26,570
+يعني لو كان بسبع ذرات، فيه double bond و triple
+
+350
+00:30:26,570 --> 00:30:32,170
+bond، أيش هيتسمّى؟ هيبّتين-اين، يعني بتكونوا تتخيّلوا،
+
+351
+00:30:32,170 --> 00:30:37,410
+سبع ذرات بهذا الشكل، بتأكدوا حيكون لأنه سبعة، جاب
+
+352
+00:30:37,410 --> 00:30:43,720
+كلمة أيش؟ هيبّت، سبع ذرات، أيش هيجيبه؟ hept، لما يكون فيه
+
+353
+00:30:43,720 --> 00:30:48,960
+double bond، الـ double bond أيش هيجيبه؟ ene، لما يكون
+
+354
+00:30:48,960 --> 00:30:56,120
+فيه triple bond، الـ triple bond أيش هيجيبه؟ yne، زي
+
+355
+00:30:56,120 --> 00:31:01,490
+هيك، لازم اسمه يبين حاجة، بتعبّر عن العدد، بعدين عن
+
+356
+00:31:01,490 --> 00:31:05,650
+الألكين، بعدين عن الألكاين، هذا الكلام، هذا الكلام
+
+357
+00:31:05,650 --> 00:31:12,530
+كتابة اسم و ذكر مجموعات، لكن بيجي سؤال، لما بدي
+
+358
+00:31:12,530 --> 00:31:19,920
+أرقّم، أحدد وين موقع الـ ene وين موقع الـ yne، هذه لها قصة
+
+359
+00:31:19,920 --> 00:31:25,080
+ثانية، وموقع الـ ene و موقع الـ yne هذه لها قصة
+
+360
+00:31:25,080 --> 00:31:28,680
+ثانية، الآن، القصة بتقول، القاعدة، يعني خليني أعمل سبعة،
+
+361
+00:31:28,680 --> 00:31:35,560
+واحد، اثنين، ثلاثة، أربعة، خمسة، ستة، سبعة، وحطيت هذه زي
+
+362
+00:31:35,560 --> 00:31:37,300
+هيك، وحطيت هنا triple bond
+
+363
+00:31:40,170 --> 00:31:44,050
+هذا hept-yne، الآن، من واحد، بده يرقّمه من هنا ولا
+
+364
+00:31:44,050 --> 00:31:50,230
+من هناك؟ بنقول بنرقّمه من الأقرب لأحد الأطراف، يعني
+
+365
+00:31:50,230 --> 00:31:53,430
+تكون سواء double أو triple، الأقرب، يعني هنا لو عدّيت
+
+366
+00:31:53,430 --> 00:31:56,130
+واحد، اثنين، أول multiple point بتقابلني هنا، عن
+
+367
+00:31:56,130 --> 00:31:59,930
+رقم كم؟ ثلاثة، أول واحدة بتقابلني عن رقم أيش؟
+
+368
+00:31:59,930 --> 00:32:04,110
+واحد، وبناء على ذلك، هرقّم واحد، اثنين، ثلاثة، أربعة،
+
+369
+00:32:04,110 --> 00:32:14,600
+خمسة، ستة، سبعة، فهذا هيكون hept-yne-3-ene، hept
+
+370
+00:32:14,600 --> 00:32:23,520
+-ene-3-yne، واضح؟ طبعاً لو انعكس، سجلوا هذا الشغل بثانية،
+
+371
+00:32:23,520 --> 00:32:31,160
+بقول، برقم من الأقرب لأحد الأطراف، الأقرب
+
+372
+00:32:31,160 --> 00:32:35,760
+بشتغل عليه، تمام؟ يعني هذا المركب... بصوا برضه ثانية
+
+373
+00:32:35,760 --> 00:32:41,500
+يا جماعة، يعني هذا المركب نفسه، الآن لو كان زي هيك، أيش
+
+374
+00:32:41,500 --> 00:32:45,740
+رأيكم؟ هيضلوا على نفس الترقيم؟ اه... اه... اه...
+
+375
+00:32:45,740 --> 00:32:45,840
+اه... اه... اه... اه... اه... اه... اه... اه... اه
+
+376
+00:32:45,840 --> 00:32:46,020
+...اه... اه... اه... اه... اه... اه... اه... اه...
+
+377
+00:32:46,020 --> 00:32:47,260
+اه... اه... اه... اه... اه... اه... اه... اه... اه
+
+378
+00:32:47,260 --> 00:32:47,540
+...اه... اه... اه... اه... اه... اه... اه... اه...
+
+379
+00:32:47,540 --> 00:32:48,040
+اه... اه... اه... اه... اه... اه... اه... اه... اه
+
+380
+00:32:48,040 --> 00:32:48,460
+...اه... اه... اه... اه... اه... اه... اه... اه...
+
+381
+00:32:48,460 --> 00:32:52,340
+اه... اه... اه... اه... اه... اه... اه... اه... ا
+
+382
+00:32:53,210 --> 00:32:58,710
+يعني ما فيه تسمية نهائية تكون  ene-yne، هذه ضد الـ
+
+383
+00:32:58,710 --> 00:33:01,910
+alphabetical، دائماً، الترتيب الـ double و الـ triple
+
+384
+00:33:01,910 --> 00:33:06,210
+bond يجب أن تكون أيش؟ ene-yne، ما فيه شيء
+
+445
+00:38:53,320 --> 00:38:57,620
+هذي بإيش؟ بـ Carbon ولذلك هذا لما بدنا نسميه
+
+446
+00:38:57,620 --> 00:39:02,560
+Cyclopentanol
+
+447
+00:39:02,560 --> 00:39:08,340
+و بنضيف النهاية تبعته All Cyclopentanol خلصنا
+
+448
+00:39:08,340 --> 00:39:16,050
+هذا لما بدنا نسميه نفس الفكرة Cycloبنتان وبنحط له
+
+449
+00:39:16,050 --> 00:39:23,250
+نهاية الـ ketone بنتانون وخلصنا هذا لما بدي اسميه
+
+450
+00:39:23,250 --> 00:39:30,330
+.. لأ ما بسميهوش cycle بالتنالليش؟ لأنه إجي عليه
+
+451
+00:39:30,330 --> 00:39:33,690
+مجموعة كاملة خارجية، إجي عليه كمان carbon، C
+
+452
+00:39:33,690 --> 00:39:39,350
+double bond OH، بنسميه Cyclopenten-carbaldehyde
+
+453
+00:39:39,350 --> 00:39:43,410
+لأنه إجت carbon زيادة عن اللي جابله، ولذلك هذا إيش
+
+454
+00:39:43,410 --> 00:39:50,910
+بده يتسمى؟ Cyclopenten-carbaldehyde
+
+455
+00:39:53,820 --> 00:39:58,780
+ملاحظين الفرق بينهم؟ أنه أنا ما بقدرش أشبك أكسوجين
+
+456
+00:39:58,780 --> 00:40:02,560
+الالديهايد مباشرة بالحلقة إلا من خلال ذرة كربون
+
+457
+00:40:02,560 --> 00:40:07,620
+ولذلك بنسميه Cyclopentane Carbaldehyde شفتوا الفرق
+
+458
+00:40:07,620 --> 00:40:11,500
+بين الكحول والكيتون والالديهايد لو يجي على حلقة؟
+
+459
+00:40:12,310 --> 00:40:16,630
+الآن لو واحدة فيكم شاطرة بعد ما نختم المحاضرة بذكر
+
+460
+00:40:16,630 --> 00:40:20,210
+الله تقولي كمان آخر مثال عشان نسكر هذه النقطة
+
+461
+00:40:20,210 --> 00:40:26,510
+المفروض يلحق هدول كلهم إيش هيكون الـ acid الـ acid
+
+462
+00:40:26,510 --> 00:40:32,070
+لو بده ييجي على الحلقة كيف بده ييجي زي الـ aldehyde
+
+463
+00:40:32,070 --> 00:40:37,150
+الـ acid لو بده ييجي على الحلقة بده ييجي كله معلّق
+
+464
+00:40:37,150 --> 00:40:38,010
+على الحلقة
+
+465
+00:40:42,740 --> 00:40:46,200
+ما أقدرش أحطه على نفس الحلقة الأكسجينة المتصلة ولذلك
+
+466
+00:40:46,200 --> 00:40:49,820
+لما بدي أسميه بدي أسميه بشكل موازن لنظام الـ
+
+467
+00:40:49,820 --> 00:40:57,680
+الديهايد إيش وجدت حاجة أقول عنه؟ Cyclo .. بنتين ..
+
+468
+00:40:57,680 --> 00:41:03,300
+Carboxylic acid كمان Carboxylic acid
+
+469
+00:41:05,250 --> 00:41:09,150
+شوفتوا كيف مقارنة الأمور بتيجي الكحول والكيتون
+
+470
+00:41:09,150 --> 00:41:11,750
+بيجوا مباشرة على الحلقة فبنقول cyclopentanol
+
+471
+00:41:11,750 --> 00:41:16,090
+و cyclopentanol الـ aldehyde لأ cyclopentane وcarb
+
+472
+00:41:16,090 --> 00:41:20,670
+aldehyde الـ acid cyclopentane وcarboxylic acid
+
+473
+00:41:20,670 --> 00:41:26,650
+واضحة الفكرة وبهيك بننهي المحاضرة اليوم، المرة اللي
+
+474
+00:41:26,650 --> 00:41:29,970
+جاي بنستمر في موضوع التسمية وموضوع الـ aldehydes
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hJ0uUjaPUvk_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hJ0uUjaPUvk_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b2e90e18512e8133626ac5ab048d29f286e7ee34
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hJ0uUjaPUvk_postprocess.srt
@@ -0,0 +1,1896 @@
+1
+00:00:20,180 --> 00:00:26,240
+بسم الله الرحمن الرحيم الفصل التاسع موضوعه ال
+
+2
+00:00:26,240 --> 00:00:31,480
+aldehydes and ketones طبعا ال aldehydes and
+
+3
+00:00:31,480 --> 00:00:36,420
+ketones ربما انتوا اتلاحظوا انه عائلتين مش عائلة
+
+4
+00:00:36,420 --> 00:00:41,000
+واحدة لو اطلعنا هنلاقي ان ال aldehydes و ال
+
+5
+00:00:41,000 --> 00:00:47,000
+ketones هم جزء من عائلة اكبر جزء من عائلة اكبر
+
+6
+00:00:47,000 --> 00:00:53,230
+اسمهاالكربونيل containing compounds يعني المركبات
+
+7
+00:00:53,230 --> 00:00:56,870
+اللى بتحتوي على مجموعة الكربونيل الان ايش مجموعة
+
+8
+00:00:56,870 --> 00:01:02,490
+الكربونيل مجموعة الكربونيل هي ال C double bond O
+
+9
+00:01:02,490 --> 00:01:08,130
+واضح ال C double bond O هي المجموعة اللى اسمها ايش
+
+10
+00:01:08,130 --> 00:01:15,110
+كربونيلالان كتير في مراكبات .. كتير في مراكبات
+
+11
+00:01:15,110 --> 00:01:19,530
+فيهم هذه المجموعة الـ C double bond O يعني من هدول
+
+12
+00:01:19,530 --> 00:01:23,910
+المراكبات الـ aldehydes لما يكون عند الـ C double
+
+13
+00:01:23,910 --> 00:01:28,970
+bond O مجموعة R وH على الجهة التانية منهم الـ
+
+14
+00:01:28,970 --> 00:01:32,110
+ketones لما تكون الـ C double bond O محشورة بين
+
+15
+00:01:32,110 --> 00:01:36,990
+مجمعتين Rمنهم الـ Carboxylic Acids الـ C double
+
+16
+00:01:36,990 --> 00:01:41,750
+bond O متصلة بـ OH الان المراكبات اللي ضايلة
+
+17
+00:01:41,750 --> 00:01:46,030
+بنسميها مشتقات من الـ Carboxylic Acids منها الـ E
+
+18
+00:01:46,030 --> 00:01:49,970
+star C double bond O OR منها الامد C double bond O
+
+19
+00:01:49,970 --> 00:01:57,970
+NH2 منها ال Acid C double bond OCL وفي كمان مركب
+
+20
+00:01:57,970 --> 00:02:03,030
+أيضا موجود ومشهور ولو مش مكتوب هنا R C double bond
+
+21
+00:02:03,030 --> 00:02:09,150
+O O C double bond O R تانية هذا بنسميه acid
+
+22
+00:02:09,150 --> 00:02:15,610
+anhydride بنسميه acid anhydride
+
+23
+00:02:17,770 --> 00:02:23,130
+الان اللى بتطلع على هذه العائلة الكبيرة كتير خلينا
+
+24
+00:02:23,130 --> 00:02:27,630
+نسميه عائلة ال carbonyl compounds هيلحظ انه احنا
+
+25
+00:02:27,630 --> 00:02:31,890
+صارنا بنحكي عن عائلات فرعية موجودة فيها واحد اتنين
+
+26
+00:02:31,890 --> 00:02:38,890
+تلاتة اربع خمسة ستةسبعة يعني عدد كبير من العائلات
+
+27
+00:02:38,890 --> 00:02:42,710
+الفرعية جوا العائلة العاملة هي عائلة الاش ال
+
+28
+00:02:42,710 --> 00:02:46,390
+carbonyl compounds المركبات اللي بتحتوي على مجموعة
+
+29
+00:02:46,390 --> 00:02:53,690
+ال C double bond O لحسن الحظ ان هدول العائلات
+
+30
+00:02:54,350 --> 00:03:01,030
+يقسموا أو يجمعوا إلى عائلتين ال الديهيدس والكيتونز
+
+31
+00:03:01,030 --> 00:03:04,790
+في كل كتب الكيميا العضوية بتلاقوهم محطوطين مع بعض
+
+32
+00:03:04,790 --> 00:03:11,170
+في شبتر واحد والأحماض ومشتقاتها بنسميها assets and
+
+33
+00:03:11,170 --> 00:03:15,710
+their derivatives ال acid derivatives يعني هدولة
+
+34
+00:03:15,710 --> 00:03:19,290
+derivatives لل acid مشتقات derivative يعني إيش؟
+
+35
+00:03:19,970 --> 00:03:25,510
+الاسد ديريفاتيف لو قلنا لكم شو هم الاستر الامد
+
+36
+00:03:25,510 --> 00:03:32,190
+الاسد هيلايد والاسد انهيدريد هدولة الخمسة بنحط
+
+37
+00:03:32,190 --> 00:03:38,330
+بعيلة واحدةلاحظوا صار عندى تقسيم بدل ما هو ل سبع
+
+38
+00:03:38,330 --> 00:03:43,370
+عائلات كلها مختلفة حاطناهم بإيش؟ بعائلتين فقط
+
+39
+00:03:43,370 --> 00:03:48,850
+الهيتز و الفيتون عائلة الاسيتز و مصادرهم كلهم دول
+
+40
+00:03:48,850 --> 00:03:53,290
+عائلة و لذلك عادة في الكيميا العضوية في غالب الكتب
+
+41
+00:03:53,290 --> 00:03:56,630
+هتلاقي انه بنعمل عن كل هذه المركبات chapter يعني
+
+42
+00:03:56,630 --> 00:04:01,490
+فاصلين هدول بنحطه بفصل لحالهم و هدول بنحطه بفصل
+
+43
+00:04:01,490 --> 00:04:02,710
+لحالهم
+
+44
+00:04:05,560 --> 00:04:10,240
+لسه بإمكاننا نبسط الموضوع بإمكاننا نبسط الموضوع
+
+45
+00:04:10,240 --> 00:04:16,230
+أكثر كثير من هيكنقول ليش هذه التقسيمة و كيف أنا
+
+46
+00:04:16,230 --> 00:04:20,450
+الاشي الكتير بدي أسهل التعامل معه بنقول هذه
+
+47
+00:04:20,450 --> 00:04:26,050
+التقسيمة قائمة على كلمتين فقط كلمتين اللي بيفهم
+
+48
+00:04:26,050 --> 00:04:31,150
+دول الكلمتين بنقدر نقول عنه أنه فيهم ست إلى سبع
+
+49
+00:04:31,150 --> 00:04:36,090
+محاضرات للأمام هنضلنا نعيد و نزيد فيهم بنفس
+
+50
+00:04:36,090 --> 00:04:42,790
+الكلمتينواضح؟ صعب على البني آدم يفهم كلمتين كان
+
+51
+00:04:42,790 --> 00:04:48,130
+زمان برنامج بالتلفزيون بالإذاعة اسمه كلمتين و بس
+
+52
+00:04:48,130 --> 00:04:52,630
+خلوه و ميرك معاكم مين اللي كان يقدم هذا البرنامج
+
+53
+00:04:52,630 --> 00:04:58,330
+زمان اسأله الآباء والأجداد المهم ايش الكلمتين
+
+54
+00:04:58,330 --> 00:05:06,290
+المرتبطات بكل هذه العائلات الكلمة الأولىخاصة بأهم
+
+55
+00:05:06,290 --> 00:05:12,070
+تفاعل أساسي لهدول المركبات اللي هم ال aldehydes و
+
+56
+00:05:12,070 --> 00:05:19,630
+ال ketones بيتفاعلوا تفاعل ال addition الإضافة ال
+
+57
+00:05:19,630 --> 00:05:24,730
+addition و الكلمة التانية لهدول الخمسة اللي ضايقين
+
+58
+00:05:24,730 --> 00:05:29,750
+معهم ال unhydrate اللي شطبناه بتفاعلوا تفاعل ال
+
+59
+00:05:29,750 --> 00:05:32,930
+substitution الإبدال تمام؟
+
+60
+00:05:37,060 --> 00:05:43,120
+إذن سبب تقسيم هدول السبع مركبات إلى عائلات يعني
+
+61
+00:05:43,120 --> 00:05:46,440
+أحيانا الإنسان كان ممكن يسأل إذا السبعة بدنا
+
+62
+00:05:46,440 --> 00:05:50,180
+نعملهم عيلتين أو شبترين كان خلينا أربعة في شبتر
+
+63
+00:05:50,180 --> 00:05:56,620
+وتلاتة في شبتر تاني ليش خلينا اتنين وخمسة تمام؟ لأ
+
+64
+00:05:56,620 --> 00:06:03,470
+التقسيم مش تقسيم عددي التقسيم تقسيم وظيفي بمعنىإيش
+
+65
+00:06:03,470 --> 00:06:10,370
+التفاعل الأساسي لهذه العائلة هو تفاعل الإضافة؟ إيش
+
+66
+00:06:10,370 --> 00:06:16,450
+التفاعل الأساسي لهذه العائلة هو تفاعل الإبدال؟
+
+67
+00:06:16,450 --> 00:06:21,310
+ولذلك لو أي طالب organic chemistry بده يدخل مقابل
+
+68
+00:06:21,310 --> 00:06:25,510
+التوظيف، مانعش يمسك ورق و جلم و يكتب، لكن أبسط
+
+69
+00:06:25,510 --> 00:06:29,510
+سؤال بده يسأله ببساطة إيش التفاعل الأساسي
+
+70
+00:06:29,510 --> 00:06:33,660
+للالدهايتز والكيتونز؟ماعرفش يجاوب ايش التفاعل
+
+71
+00:06:33,660 --> 00:06:38,720
+الأساسي لل assets ومش رقاتها ماعرفش يجاوب نراكم في
+
+72
+00:06:38,720 --> 00:06:43,750
+السنة القادمةبالزمش يكون دراسة organic واضح اهتموا
+
+73
+00:06:43,750 --> 00:06:48,950
+كتير بهدول الكلمتين اللي بيفهموهم جيدا بيكونوا
+
+74
+00:06:48,950 --> 00:06:53,530
+فاهموا سبع عائلات اللي بيفهموا دول الكلمتين جيدا
+
+75
+00:06:53,530 --> 00:06:58,350
+بيكونوا فاهموا ايش سبع عائلات ولذلك خلينا نتعمق
+
+76
+00:06:58,350 --> 00:07:03,070
+اكتر بفهم هدول الكلمتين خلينا نتعمق اكتر بفهم هدول
+
+77
+00:07:03,070 --> 00:07:07,280
+الكلمتين الان احنا قولنا ايش ال carbonyl groupالـ
+
+78
+00:07:07,280 --> 00:07:11,960
+C double bond O طب لو كتبنا تحت الكربونيل C double
+
+79
+00:07:11,960 --> 00:07:17,120
+bond O ورجعنا للكلام اللي بنعرفه بخصوص السالبية
+
+80
+00:07:17,120 --> 00:07:22,640
+مين أكثر سالبية؟ ال oxygen مين أقل سالبية؟ ال
+
+81
+00:07:22,640 --> 00:07:26,880
+carbon إذا هذه ال carbon partially positive و هذه
+
+82
+00:07:26,880 --> 00:07:32,180
+ال oxygen partially negative واضح؟ الآن المحور
+
+83
+00:07:32,180 --> 00:07:36,410
+الأساسيفي فهم الكيميا كاملة تبعتي السبع عائلات
+
+84
+00:07:36,410 --> 00:07:43,210
+هدولة بينطلق من انه ال carbon موجبة يعني يمكن أهم
+
+85
+00:07:43,210 --> 00:07:49,530
+كلمة في فهم هذه العائلات السبعة كلها مجتمعة يعني
+
+86
+00:07:49,530 --> 00:07:54,250
+في فهم ال two chapters ان نقول ان هذا ال carbon
+
+87
+00:07:54,250 --> 00:07:59,030
+هاي بدنا نعلمها فيهم كلهم باللون الأحمر اشمالها
+
+88
+00:07:59,030 --> 00:08:07,920
+موجبةالان من باب تحصيل الحاصل الموجب لما يتفاعل ..
+
+89
+00:08:07,920 --> 00:08:14,280
+بنفتح بس على واحدة منهم الموجب لما يتفاعل ايش بده؟
+
+90
+00:08:14,280 --> 00:08:20,460
+بلغة الكيميا ال يوكليوفالالموجب لما يتفاعل بده
+
+91
+00:08:20,460 --> 00:08:24,980
+سالب بده نيوكليوفايل بناء على ذلك طالما جميعهم
+
+92
+00:08:24,980 --> 00:08:29,260
+عندهم ال carbon الموجبة إذا جميعهم تفاعلهم الأساسي
+
+93
+00:08:29,260 --> 00:08:33,580
+بيستنوا نيوكليوفايل واضح؟ يعني بدي أجيب ان
+
+94
+00:08:33,580 --> 00:08:40,360
+نيوكليوفايل و هذا عليه زوجمن الالكترونات زي ما
+
+95
+00:08:40,360 --> 00:08:43,500
+انتوا عارفين سواء كان مشحون او متعادل مش موضوعنا
+
+96
+00:08:43,500 --> 00:08:47,480
+.. وين بده يروح يجري يهاجم ال nucleophile على ال
+
+97
+00:08:47,480 --> 00:08:52,420
+carbon نفس ال nucleophile .. نفس ال nucleophile
+
+98
+00:08:52,420 --> 00:08:59,670
+على ال carbonالان هذا الـ nucleophile لما بيهاجم
+
+99
+00:08:59,670 --> 00:09:04,370
+على الكربون مرة هيعمل تفاعل إضافة في الحالتين
+
+100
+00:09:04,370 --> 00:09:08,870
+الأولانيات و في باقى الحالات هيعمل تفاعل إبدال إذا
+
+101
+00:09:08,870 --> 00:09:13,530
+لو جينا سألناكم قولنا لكم ال aldehydes بيعملوا
+
+102
+00:09:13,530 --> 00:09:19,150
+addition بتقولوا صحو ال acids و المشتقاتة بيعملوا
+
+103
+00:09:19,150 --> 00:09:24,510
+substitution صح لو سألنا هل يا ترى ال eucleophilic
+
+104
+00:09:24,510 --> 00:09:27,850
+addition و ال eucleophilic substitution ولا ال
+
+105
+00:09:27,850 --> 00:09:30,630
+electrophilic addition و ال electrophilic
+
+106
+00:09:30,630 --> 00:09:35,440
+substitution؟ ال eucleophilicإذن الآن بنقدر نزيد
+
+107
+00:09:35,440 --> 00:09:40,440
+كلمة إن ال الديهايدز تفاعلهم الأساسي اللي بديها
+
+108
+00:09:40,440 --> 00:09:45,340
+بالظبط الـ Eucleophilic addition وفهمنا ليش؟ ال
+
+109
+00:09:45,340 --> 00:09:50,460
+Eucleophilic addition و الأحماض و مشتقاتها تفاعلهم
+
+110
+00:09:50,460 --> 00:09:56,390
+الأساسي ال Eucleophilic substitution واضح؟لحد الآن
+
+111
+00:09:56,390 --> 00:10:02,230
+تمام الان بيصير ايش الناتج اللى بده يتكون عندى ايش
+
+112
+00:10:02,230 --> 00:10:06,510
+الناتج اللى بده يتكون في حالة ما كنا بنحكي عن ال
+
+113
+00:10:06,510 --> 00:10:10,870
+aldehydes و ال ketones addition معناه ان ال C
+
+114
+00:10:10,870 --> 00:10:15,070
+double bond O او ال double bond تصير single bondمش
+
+115
+00:10:15,070 --> 00:10:18,050
+هيك احنا قولنا ال addition يعني مجرد ماذا ال
+
+116
+00:10:18,050 --> 00:10:21,830
+nucleophile يهاجم هنا ويعمل رابطة هل معقول يصير
+
+117
+00:10:21,830 --> 00:10:26,290
+عندي خمس روابط؟ لأ، إذا هذه الرابطة بتتحرك تصبح O
+
+118
+00:10:26,290 --> 00:10:31,470
+minus بتصفح OH بتاخد H من اللي ال nucleophile أو
+
+119
+00:10:31,470 --> 00:10:36,310
+من ال solvent إذا الناتج اللي هيصير عندي ناتج ال
+
+120
+00:10:36,310 --> 00:10:40,310
+addition ببساطة إنه سيضة بال bond O تبعت ال ketone
+
+121
+00:10:40,310 --> 00:10:43,830
+أو تبعت ال aldehyde شو بده تصير؟ OH
+
+122
+00:10:46,820 --> 00:10:50,500
+شوفت وين ال addition هنا تم ال addition double
+
+123
+00:10:50,500 --> 00:10:56,980
+single إضافة شو هو ال addition تحويل ال double
+
+124
+00:10:56,980 --> 00:11:00,520
+bond إلى single bond إذا في ال aldehydes و ال
+
+125
+00:11:00,520 --> 00:11:05,060
+ketones ال C double bond O هتصير OH طبّاق
+
+126
+00:11:05,060 --> 00:11:12,240
+المجموعات R زي ما هي H أو R زي ما هي و اللي إجه
+
+127
+00:11:12,240 --> 00:11:14,900
+هنا ال nucleophile
+
+128
+00:11:17,240 --> 00:11:20,840
+مشهور الـ nucleophile اللي هاجمه عام الرابط إذا
+
+129
+00:11:20,840 --> 00:11:26,440
+هذا الشكل العام تبع نتيجة تفاعل ال الديهيد أو ال
+
+130
+00:11:26,440 --> 00:11:30,400
+ketones يعني لو إجينا قولنا مثلا لل nucleophile
+
+131
+00:11:30,400 --> 00:11:32,900
+H2O
+
+132
+00:11:35,400 --> 00:11:39,820
+ماذا سيحصل؟ هذه في كل الأحوال ستصبح OH مع كل أنواع
+
+133
+00:11:39,820 --> 00:11:44,040
+الـ nucleophiles لكن الـ H2O ماذا تضع هنا؟ OH
+
+134
+00:11:44,040 --> 00:11:48,140
+دائما الـ nucleophile المتعدد سنخصه من OH ولو قلنا
+
+135
+00:11:48,140 --> 00:11:53,420
+لـ nucleophile OH-, سيضع أيضًا OH و بعد ذلك نضع
+
+136
+00:11:53,420 --> 00:11:57,880
+acid ستصبح هذه OH إذا لو لـ nucleophile H2O أو H-,
+
+137
+00:11:57,880 --> 00:12:02,700
+سيصبح عندكم على الكربون OH من الألديهيد الأصلي و
+
+138
+00:12:02,700 --> 00:12:10,190
+OHالمهاجمة لو النيوكليوفايل الكهول شوف دي جهانة OR
+
+139
+00:12:10,190 --> 00:12:17,210
+هذه OH لا خلافة فيها ثابتة هذه ثابتة اللي هي ال C
+
+140
+00:12:17,210 --> 00:12:20,290
+double bond O لكن أنا بقول النيوكليوفايل الميا
+
+141
+00:12:20,290 --> 00:12:29,950
+بتحط OH الكحول بيحط OR ال HCl بيحط Cl و هكذا واضحة
+
+142
+00:12:29,950 --> 00:12:36,010
+الفكرة؟هي هذا الشكل العام تبع تفاعل إضافة وهو الذي
+
+143
+00:12:36,010 --> 00:12:41,130
+يميز جميع تفاعلات ال device و ال ketones و هناخد
+
+144
+00:12:41,130 --> 00:12:46,210
+أمثلة تصير كلها تكرار نضل نعيد يقول بيعمل إضافة و
+
+145
+00:12:46,210 --> 00:12:52,290
+بس في كل الأمثلة اللي بناخدها إيش بتصير القصة؟هنا
+
+146
+00:12:52,290 --> 00:12:55,470
+نقول ايه شو هو لليوكليوفايل؟ اذا كان ليوكليوفايل
+
+147
+00:12:55,470 --> 00:12:58,450
+ماء فهذه كذا، اذا كان الكول هذه كذا، اذا كان
+
+148
+00:12:58,450 --> 00:13:02,870
+سياناد كذا، اذا كان هايدرايد هذه كذا، يعني فقط هذا
+
+149
+00:13:02,870 --> 00:13:07,450
+المتغير الوحيد حيصفى عندكم شو هو ليوكليوفايل؟
+
+150
+00:13:07,450 --> 00:13:13,950
+واضح؟ الان لو اجينا وقلنا نفس ليوكليوفايل بده
+
+151
+00:13:13,950 --> 00:13:20,770
+يهاجم علىالكيتون على الكربون الحمراء عفوا على
+
+152
+00:13:20,770 --> 00:13:24,870
+الاسد لأ ما هو الكيتون زي الألدياد خلصنا منه على
+
+153
+00:13:24,870 --> 00:13:31,630
+الاسد أو مشتقاته إيش بيكون التفاعل؟ هذا بيجي هنا و
+
+154
+00:13:31,630 --> 00:13:38,020
+يطرد المجموعة هذهواضح؟ طبعا O H minus لما تترد
+
+155
+00:13:38,020 --> 00:13:43,920
+تاخد H من برا شو هتصير؟ O R minus لما تترد تاخد H
+
+156
+00:13:43,920 --> 00:13:51,460
+R O H كحول N H 2 لما تترد N H 3 C L minus لما يترد
+
+157
+00:13:51,460 --> 00:13:57,140
+C L اذا صار عندى هذه المجموعة هي اللتي تستبدل اللى
+
+158
+00:13:57,140 --> 00:14:03,380
+جنب ايش اللى جنب الصيغة بال bond O بناء على ذلك
+
+159
+00:14:03,380 --> 00:14:09,940
+الناتج ايش هيكون؟R C double bond O هذه ما زالت زي
+
+160
+00:14:09,940 --> 00:14:15,140
+ما هي لكن بدل ال OH او ال OR او ال NH2 whatever
+
+161
+00:14:15,140 --> 00:14:21,120
+whatever صار إبدال enucleophile نيو ن أيه صوديوم
+
+162
+00:14:21,120 --> 00:14:25,480
+نيوكليوفايل واضح يعني شيلنا هذه المجموعة و حطينا
+
+163
+00:14:25,480 --> 00:14:29,880
+مكانها إيش نيوكليوفايل هذا substitution ولا لأ
+
+164
+00:14:29,880 --> 00:14:35,430
+مجموعة جاية مجموعة طالعةواضحك الفكرة و الجزء اللي
+
+165
+00:14:35,430 --> 00:14:39,390
+طلع بياخد H بطلع على شكل ماء على شكل أمونيا على
+
+166
+00:14:39,390 --> 00:14:45,380
+شكل كحول على شكل HClهذا الكلام بتلاقوه بتكرر في كل
+
+167
+00:14:45,380 --> 00:14:50,660
+عائلات الأحماض ومشتقاتها إذا لو احنا كنا حتى
+
+168
+00:14:50,660 --> 00:14:55,280
+chapter 9 هذا اللي بدنا نبدأ فيه بدنا نعطيه عنوان
+
+169
+00:14:55,280 --> 00:14:59,820
+جديد ال dehydes and ketones بين قصين إيش بدنا نكتب
+
+170
+00:14:59,820 --> 00:15:04,300
+ال eucleophilic addition لو كنا في chapter 10 بدنا
+
+171
+00:15:04,300 --> 00:15:08,460
+نقول acids and their derivatives بين قصين ال
+
+172
+00:15:08,460 --> 00:15:12,910
+eucleophilic substitutionاللي فهموا هدولا الكلمتين
+
+173
+00:15:12,910 --> 00:15:19,430
+جيدا واتدربوا عليهم بيقدروا يتريحوا أربع أو خمس
+
+174
+00:15:19,430 --> 00:15:24,370
+محاضرات جاية خلاص بيصيروا بس بتذكروا الكلام اللي
+
+175
+00:15:24,370 --> 00:15:29,230
+قاله الشاعر الجاهلي ما ترانا نقوله إلا معادا من
+
+176
+00:15:29,230 --> 00:15:36,720
+قولنا .. إيش؟ مكرورةبس بنبقى بنقول addition of
+
+177
+00:15:36,720 --> 00:15:42,640
+chapter يعني هتشبعه من كلمة addition of chapter
+
+178
+00:15:43,830 --> 00:15:47,630
+وتشبعوا من كلمة substitution in chapter واضحة
+
+179
+00:15:47,630 --> 00:15:53,230
+الفكرة ما عدا ذلك بيصير كله بالنسبة لنا رتوش بسيطة
+
+180
+00:15:53,230 --> 00:15:56,390
+يعني كيف نسمي ال aldehydes ال ketones إيش أشهر ما
+
+181
+00:15:56,390 --> 00:16:00,590
+هو موجود فيها إيش تطبيقاتها كله تعتبر أشياء بسيطة
+
+182
+00:16:00,590 --> 00:16:06,110
+الفكرة الأساسية لعبلة التصنيف هي متعلقة بطبيعة
+
+183
+00:16:06,110 --> 00:16:13,100
+التفاعل الأساسي لكل عائلة واضحة هذه الفكرةالان لو
+
+184
+00:16:13,100 --> 00:16:18,580
+اتينا مثلا لخواص ال aldehydes و ال ketones بشكل
+
+185
+00:16:18,580 --> 00:16:24,580
+عام لاحظوا كتب عنهم moderately polar يعني متوسطي
+
+186
+00:16:24,580 --> 00:16:30,840
+القطبية الان هو يقارن بين ايش؟ بين شغلتين بين ال R
+
+187
+00:16:30,840 --> 00:16:35,140
+اللي هي ال alkanes لحالها اللي فيها ال London
+
+188
+00:16:35,140 --> 00:16:44,180
+forces و بين ال alcohols اللي فيها ال OHواضح؟ ال
+
+189
+00:16:44,180 --> 00:16:48,480
+alcohols اللي فيها ال OH هيدروجين bonding واضحة
+
+190
+00:16:48,480 --> 00:16:53,080
+الفكرة؟ هنا إيش نوع ال bonding؟ هيدروجين bonding
+
+191
+00:16:53,080 --> 00:17:01,480
+ممتاز وفي ال alkanes لندن forces طب في الألدهات و
+
+192
+00:17:01,480 --> 00:17:03,780
+ال ketones اللي إلها partial positive و partial
+
+193
+00:17:03,780 --> 00:17:08,280
+negative Dipole-dipole attraction اللي تيجي in
+
+194
+00:17:08,280 --> 00:17:16,870
+between Dipole-dipole اللي هيبالظبطواللي ال
+
+195
+00:17:16,870 --> 00:17:20,510
+hydrogen bonding أقوى أنواعها وبناء على ذلك هم
+
+196
+00:17:20,510 --> 00:17:24,610
+أصبحوا moderately polar الان كونهم moderately
+
+197
+00:17:24,610 --> 00:17:28,890
+polar هذا الكلام على طول بنعكس على ايش؟ على نقطة
+
+198
+00:17:28,890 --> 00:17:34,290
+الغليان على نقطة الغليان يعني مثلا لو احنا بدنا
+
+199
+00:17:34,290 --> 00:17:39,270
+نيجي نعمل مقارنة بدنا نيجي نعمل مقارنة بين أشياء
+
+200
+00:17:39,270 --> 00:17:46,320
+شبه متساوية شبه متساوية في الوزن الجزائييعني خدوا
+
+201
+00:17:46,320 --> 00:17:55,400
+على سبيل المثال الميثانول ايش صيغته العامة CH3OH
+
+202
+00:17:55,400 --> 00:18:07,020
+خدوا على سبيل المثال ال formaldehyde CH3OH
+
+203
+00:18:07,020 --> 00:18:08,000
+CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH
+
+204
+00:18:08,000 --> 00:18:11,180
+CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH
+
+205
+00:18:11,180 --> 00:18:12,160
+CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH
+
+206
+00:18:12,160 --> 00:18:12,260
+CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH CH3OH
+
+207
+00:18:12,260 --> 00:18:18,210
+CH3OH CH3OH CH3CH3 CH3 هدول التلت مركبات يكاف
+
+208
+00:18:18,210 --> 00:18:22,910
+يكونوا متساويين في إيش؟ في الوزن الجزية لو حسبته
+
+209
+00:18:22,910 --> 00:18:29,330
+هنا اتناش و تلاتة خمستاش و ستاش و ستاش، كدش هنا
+
+210
+00:18:29,330 --> 00:18:34,170
+الوزن؟ اتنين و تلاتين لو أجينا على ال formaldehyde
+
+211
+00:18:34,170 --> 00:18:42,130
+ستاش و اتناش و اتنينتلاتين لو اجينا على هذا خمستعش
+
+212
+00:18:42,130 --> 00:18:46,430
+خمستعش تلاتين يعني يكاد يكون ال molecular weight
+
+213
+00:18:46,430 --> 00:18:54,350
+لهم ايش ماله متساوي لكن لو اجينا لو اجينا ل .. ال
+
+214
+00:18:54,350 --> 00:18:58,570
+boiling point لهم التلاتة مين اعلى واحد هيكون
+
+215
+00:18:58,570 --> 00:19:05,490
+الكحول الكحول boiling point خمسة وستينالميثانول
+
+216
+00:19:05,490 --> 00:19:14,670
+هذا الاثانول بيعلق بيصير قداش تقريبا 78 اه الان لو
+
+217
+00:19:14,670 --> 00:19:19,750
+اجينا على ال formaldehyde ال formaldehyde غاز لكن
+
+218
+00:19:19,750 --> 00:19:23,710
+مش كتير منخفضة نقطة غليانه يعني قوله مثلا ناقص
+
+219
+00:19:23,710 --> 00:19:27,370
+عشرين انا مش متأكد بإمكانكوا تبحثوا عنها او نجيبها
+
+220
+00:19:27,370 --> 00:19:32,290
+مرة تانية تعالوا على الاثانهتلاقو ناجس 100 ولا
+
+221
+00:19:32,290 --> 00:19:38,130
+ناجس 120 تقريبا هانا بحثوا تطلعوا كيف ال boiling
+
+222
+00:19:38,130 --> 00:19:41,970
+point بتتغير إذا ال boiling point مرتبطة بإيش
+
+223
+00:19:41,970 --> 00:19:46,350
+مرتبطة بالقطبية بس هذه القيم خليني أقول تقريبية
+
+224
+00:19:46,350 --> 00:19:51,190
+ممكن مرة تانية نجيب القيم الدقيقة واضحة الفكرة ف
+
+225
+00:19:51,190 --> 00:19:57,930
+ال polarity أطول إلى انعكاس علىالقطبية الان طيب و
+
+226
+00:19:57,930 --> 00:20:03,370
+الان عكس على شغل تاني البولاريكي شو هي الذائبية و
+
+227
+00:20:03,370 --> 00:20:09,470
+القاعدة العامة في الموضوع ايش like dissolves like
+
+228
+00:20:09,470 --> 00:20:15,950
+الان اكتر حاجة فيها قطبية ايش الكحولات اللي فيها O
+
+229
+00:20:15,950 --> 00:20:20,190
+H's و بتذكروا حتى لما قلنا عن الكحولات قلنا
+
+230
+00:20:20,190 --> 00:20:26,280
+مابدناش ننسى ان الكحولفي المجمعتين في الجزء القطبي
+
+231
+00:20:26,280 --> 00:20:33,200
+ال R والجزء القطبي ال OH والجزء غير القطبي ال R
+
+232
+00:20:33,200 --> 00:20:37,020
+وبناء على ذلك ال lower alcohols كانت water soluble
+
+233
+00:20:37,020 --> 00:20:42,000
+وال higher alcohols كانت water solubleتذكرين هذه
+
+234
+00:20:42,000 --> 00:20:46,180
+المعلومة؟ الكلام نفسه بتكرر وين؟ في ال ketones
+
+235
+00:20:46,180 --> 00:20:50,400
+برضه ال ketones فيهم جزء قطبة ال C double bond O و
+
+236
+00:20:50,400 --> 00:20:54,780
+فيهم ال R لما تصير ال R هذه كبيرة بيبطلوا يدوبوا
+
+237
+00:20:54,780 --> 00:20:57,840
+في الميه بس R صغيرة يعني مثل و مثل بيصير ال
+
+238
+00:20:57,840 --> 00:21:03,660
+acetone ال acetone بدوب في الميهلكن خلوها إثل و
+
+239
+00:21:03,660 --> 00:21:07,760
+إثل، إبروبل و إبروبل، فينل و إثل، كبرت، بتبطل
+
+240
+00:21:07,760 --> 00:21:12,140
+الدوب في المياه، واضح؟ فال lower molecular weight
+
+241
+00:21:12,140 --> 00:21:14,540
+species، يعني الأشياء اللي ال molecular weight
+
+242
+00:21:14,540 --> 00:21:18,560
+فيها إجليل في الأذيهات والكيتونز، بتكون إيش؟ water
+
+243
+00:21:18,560 --> 00:21:23,320
+soluble، كل ما ال R كبرت، بتبطل، يعني زي زي إيش؟
+
+244
+00:21:23,320 --> 00:21:27,720
+الكحولاتفمن ال الديهيدس اللي بيدوبوا في الميا بشكل
+
+245
+00:21:27,720 --> 00:21:30,600
+عام ال formaldehyde بيدوب في الميا بيعطي ال
+
+246
+00:21:30,600 --> 00:21:34,340
+formalin ال acetaldehyde نسبيا بيدوب بعد هيك بيبطل
+
+247
+00:21:34,340 --> 00:21:38,000
+يدوب من ال ketones ال acetone بيدوب في الميا بعد
+
+248
+00:21:38,000 --> 00:21:43,270
+هيكلما يكبروا ببطله يدوبوا واضح فال low molecular
+
+249
+00:21:43,270 --> 00:21:45,830
+weight species are soluble in water and the
+
+250
+00:21:45,830 --> 00:21:50,270
+solubility decreases بتنقص as the R chain gets
+
+251
+00:21:50,270 --> 00:21:54,570
+longer كل ما كبرت ال R كل ما قلت التأبية وهذا
+
+252
+00:21:54,570 --> 00:21:58,710
+الكلام أيضا في الكحولات لاحظنا واضح الفكرة هذا
+
+253
+00:21:58,710 --> 00:22:02,710
+الكلام أيضا لاحظنا في الكحولات
+
+254
+00:22:06,830 --> 00:22:09,910
+طيب كيف بنسمي ال الديهايد و ال ketones؟ احنا قولنا
+
+255
+00:22:09,910 --> 00:22:14,510
+أساسا كل نظام التسمية في الكيميا العضوية نظام سهل
+
+256
+00:22:14,510 --> 00:22:20,230
+ليش سهل؟ لأنه مبني على ذكر طول السلسلة منتهي برمز
+
+257
+00:22:20,230 --> 00:22:28,770
+للمجموعة الوظيفية ال ال K نهايته L E I O للكحول ال
+
+258
+00:22:28,770 --> 00:22:35,330
+L ل ال الديهايد L و ل ال ketone Oوالذلك ال الديهيد
+
+259
+00:22:35,330 --> 00:22:40,670
+اللى متكون من كربونة واحدة بنقول مثانال مثانال
+
+260
+00:22:40,670 --> 00:22:45,130
+ماخد common name formaldehyde الان لو صاروا
+
+261
+00:22:45,130 --> 00:22:51,120
+كربونتينإيه ثانال؟ أسيتالديهيد الكمونومتينام لو
+
+262
+00:22:51,120 --> 00:22:56,400
+صاروا تلاتة بروبانال بروبيونالديهيد لو صاروا أربعة
+
+263
+00:22:56,400 --> 00:23:01,860
+بيوتانال بيوتيرالديهيد بيوتيرالديهيد الآن لاحظوا
+
+264
+00:23:01,860 --> 00:23:07,320
+هتلاحظوا الفرقبين ال aldehydes و الكحولات يعني في
+
+265
+00:23:07,320 --> 00:23:11,520
+الكحول كنا نقول ethanol, methanol, ethanol,
+
+266
+00:23:11,620 --> 00:23:15,320
+propanol, butanol وهنا بنقول methanol, ethanol,
+
+267
+00:23:15,440 --> 00:23:20,740
+propanol, butanol وين الفرق؟ لأ في فرق تاني أنا
+
+268
+00:23:20,740 --> 00:23:24,760
+عارف ال all و ال al هذه الفرق لكن في فرق تاني
+
+269
+00:23:24,760 --> 00:23:32,360
+الاسم كامل هنافي الكحولات لما أجي أقول بروبانول
+
+270
+00:23:32,360 --> 00:23:36,440
+بكفي؟
+
+271
+00:23:36,440 --> 00:23:42,640
+آه الكحول تلت ذرات كربون الآن هل يتر الأو اتش فيه
+
+272
+00:23:42,640 --> 00:23:47,480
+على واحد؟ one probanol و لا على اتنين؟ two
+
+273
+00:23:47,480 --> 00:23:52,360
+probanol واضح؟ إذا البروبانول في الكحولات منه
+
+274
+00:23:52,360 --> 00:23:59,290
+اتنين و البيوتانول كمان لو صار هذه اربع كربوناتهل
+
+275
+00:23:59,290 --> 00:24:05,490
+الكحول هنا one بيوتانول
+
+276
+00:24:05,490 --> 00:24:10,050
+ولا two بيوتانول ولا two بيوتانول من هنا مش تلاتة
+
+277
+00:24:10,050 --> 00:24:18,590
+ال بيوتانول منه كم الكحول واضح؟ لتشين المتسلسل
+
+278
+00:24:18,590 --> 00:24:23,430
+يعني لو اجاكوا سؤال في الامتحان انه لتشين بيوتانول
+
+279
+00:24:23,430 --> 00:24:30,280
+اللي زي هيك كم كحول بالمجمل منه اتنينهك هتكون
+
+280
+00:24:30,280 --> 00:24:34,660
+جوابته غلط واضح؟
+
+281
+00:24:34,660 --> 00:24:41,060
+ليش؟ مين تقول لي ليش الغلط؟
+
+282
+00:24:41,060 --> 00:24:47,860
+لحظة أنا قلت المتسلسل، بعرف أنه في ISO و في
+
+283
+00:24:47,860 --> 00:24:53,750
+tertiary، هذه قصة تانيةما بدكوا تظلوا تعودوا اه ال
+
+284
+00:24:53,750 --> 00:24:55,910
+chiral center مش ال cis و ال trans ال cis و ال
+
+285
+00:24:55,910 --> 00:24:58,910
+trans كل ما يلي علاقة بالضبط بالبونس و بالحلقات ال
+
+286
+00:24:58,910 --> 00:25:03,870
+chiral center لما بيصير هذا هنا و بحط O H و H ع
+
+287
+00:25:03,870 --> 00:25:08,510
+طول صار عندى ROS من ال two butanol ال two butanol
+
+288
+00:25:08,510 --> 00:25:12,390
+منه ROS ال one butanol مافيش فيه chiral center one
+
+289
+00:25:12,390 --> 00:25:18,170
+butanolواضح؟ طبعا ما بننساش أنه فيه isobutanol و
+
+290
+00:25:18,170 --> 00:25:22,790
+tertiarybutanol كل هدول الأشياء لازم تكونوا
+
+291
+00:25:22,790 --> 00:25:27,470
+عارفينها الان ال aldehydes اللي جابنا للكلام ال
+
+292
+00:25:27,470 --> 00:25:32,190
+aldehydes لأ مافيش منها واحد و اتنين لأن مجموعة ال
+
+293
+00:25:32,190 --> 00:25:36,730
+aldehydes لا تكون الا على نمرة واحد و لانها لا
+
+294
+00:25:36,730 --> 00:25:41,310
+تكون الا على نمرة واحد بنحط ال hash رقميعني ما
+
+295
+00:25:41,310 --> 00:25:46,110
+إجيناش كتبنا إيثان وان قالب روبان وان قالب يوتان
+
+296
+00:25:46,110 --> 00:25:49,510
+وان قالب لأنها لا تكون إلا على واحد فالاشي اللي
+
+297
+00:25:49,510 --> 00:25:54,830
+معروف ضلنا بلزم نكتبه واضح؟ ومثل ال الديهايد
+
+298
+00:25:54,830 --> 00:25:59,210
+بالمناسبة اللي ما بيكونش إلا على نمرة واحد وفقط
+
+299
+00:25:59,210 --> 00:26:07,770
+على واحد ال acid الحامض الحامض ما بيكون إلا على
+
+300
+00:26:07,770 --> 00:26:09,370
+الطرف
+
+301
+00:26:11,040 --> 00:26:15,620
+هيو زي هيو ولا ممكن يكون c double bond o o h في
+
+302
+00:26:15,620 --> 00:26:21,440
+النص مستحيل طب الحامض لو اجيت رقمت من هنا واحد
+
+303
+00:26:21,440 --> 00:26:25,500
+اتنين تلاتة اربعة و بدي اسميه طبعا هقول اكيد
+
+304
+00:26:25,500 --> 00:26:30,580
+بيوتان مافيش فيها لقاش هتقولي اللي هو الحامض ايش
+
+305
+00:26:30,580 --> 00:26:39,300
+نهايته اوك اسدأوك أسد بيوتانووك أسد الان هل يا ترى
+
+306
+00:26:39,300 --> 00:26:44,360
+بنحط بيوتان وان أوك أسد لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+307
+00:26:44,360 --> 00:26:45,200
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+308
+00:26:45,200 --> 00:26:46,700
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+309
+00:26:46,700 --> 00:26:47,880
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+310
+00:26:47,880 --> 00:26:48,340
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ
+
+311
+00:26:48,340 --> 00:26:52,440
+لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ لأ ل
+
+312
+00:26:55,860 --> 00:27:00,100
+لأ ممكن يكون على موقع اتنين او تلاتة او اكتر يعني
+
+313
+00:27:00,100 --> 00:27:03,900
+في ال ketone بعد شوية هتلاحظوا لو كان عندنا خمس
+
+314
+00:27:03,900 --> 00:27:11,720
+ذرات كربون او ستة كم ذرة اللي رسمناهم واحد
+
+315
+00:27:11,720 --> 00:27:17,200
+اتنين تلاتة اربعة خمسة ستة سبعة و اجينا قولنا من
+
+316
+00:27:17,200 --> 00:27:24,440
+هذا المركب كسلسلة كم ketone بقدر اطلعلو قولت كام
+
+317
+00:27:24,440 --> 00:27:29,620
+الديهايد بقدر أعمل منه؟ واحد اسمه Heptanal و الـ C
+
+318
+00:27:29,620 --> 00:27:33,140
+double bond هو Hannah و Jamal لو قولت كام Acid
+
+319
+00:27:33,140 --> 00:27:39,020
+بقدر أطلع؟ Acid، واحد Heptanoic Acid لو قولت كام
+
+320
+00:27:39,020 --> 00:27:43,500
+كيتون؟ إذا إجت Hannah، two Heptanon وإذا إجت
+
+321
+00:27:43,500 --> 00:27:47,880
+Hannah، three Heptanon وإذا إجت Hannah، four
+
+322
+00:27:47,880 --> 00:27:56,330
+Heptanon one, twotwo عفوا واحد اتنين تلات عفوا two
+
+323
+00:27:56,330 --> 00:28:01,070
+و three و four اذا صار عندى two هبتانون و three
+
+324
+00:28:01,070 --> 00:28:05,490
+هبتانون و four هبتانون الا لو اجت هنا بتصير three
+
+325
+00:28:05,490 --> 00:28:08,470
+هبتانون من الجهة التانية او لو اجت هنا two هبتانون
+
+326
+00:28:08,470 --> 00:28:12,490
+من الجهة التانية اذا من هذا صار عندى اكتر من كيتون
+
+327
+00:28:12,490 --> 00:28:16,930
+فالكيتون يحتاج الى ترقيم لما بيلزم بينما ال
+
+328
+00:28:16,930 --> 00:28:22,270
+الديهايد لا يكون الا على موقع واحدوأبعد الفكرة
+
+329
+00:28:22,270 --> 00:28:27,970
+ومثل الديهيد ال acid ومثل ال ketone ال alcohol إذا
+
+330
+00:28:27,970 --> 00:28:32,990
+الأشياء اللي احنا بنسمي بلزم نحطلها أرقام اللي أنا
+
+331
+00:28:32,990 --> 00:28:35,750
+خدوها كلها مين يذكرنا في الأشياء اللي بلزمها
+
+332
+00:28:35,750 --> 00:28:42,450
+أرقامه الأشياء اللي مابلزمها ال alkeneيلزموا أرقام
+
+333
+00:28:42,450 --> 00:28:47,310
+انتبهوا معايا هاي سبع كاربونات لو كنت بعمل الكيل
+
+334
+00:28:47,310 --> 00:28:52,670
+ممكن يكون هنا او هنا او هنا اذا ال الكيل بيلزموا
+
+335
+00:28:52,670 --> 00:28:59,370
+أرقام ال الكاين one-heptane, two-heptane, three
+
+336
+00:28:59,370 --> 00:29:05,030
+-heptane يلزموا أرقام ال alcohol one-heptanol, two
+
+337
+00:29:05,030 --> 00:29:08,690
+-heptanol, three-heptanol, four-heptanol يلزموا
+
+338
+00:29:08,690 --> 00:29:14,920
+أرقامالكيتون two-heptanone، three-heptanone، four
+
+339
+00:29:14,920 --> 00:29:20,340
+-heptanone يلزم أرقام، إذا الالكيل والالكايد
+
+340
+00:29:20,340 --> 00:29:25,760
+والالكول والكيتون هدولة بلزمهم أرقام، لكن لو كنت
+
+341
+00:29:25,760 --> 00:29:30,960
+بحكي عن الديهيد، لأ، هبتنال فقط عن إمرأة واحدة
+
+342
+00:29:31,450 --> 00:29:36,250
+acid, heptanoic acid فالالدهاد والاسد ما بيكونوا
+
+343
+00:29:36,250 --> 00:29:54,710
+غير على موقع واحد واضحة تاني الفكرة حابين
+
+344
+00:29:54,710 --> 00:30:02,640
+تسمعوا الجوابلا بأس السؤال اللي سألته زملتكم أنه
+
+345
+00:30:02,640 --> 00:30:07,460
+لو كان في عندها رابطة ثلاثية و رابطة ثنائية كيف
+
+346
+00:30:07,460 --> 00:30:12,600
+بدي أسم المركب؟ تمام؟ لو عندي رابطة ثلاثية و رابطة
+
+347
+00:30:12,600 --> 00:30:16,800
+ثنائية كيف بدي أسم المركب؟ المركب بدي يكون في ال
+
+348
+00:30:16,800 --> 00:30:23,190
+keen و ال kind، الآن alphabeticalال E قبل ال I،
+
+349
+00:30:23,190 --> 00:30:26,570
+يعني لو كان بسبع ذرات، في double bond و triple
+
+350
+00:30:26,570 --> 00:30:32,170
+bond، إيش هيتسمى؟ هبتين I، يعني بتكونوا تتخيلوه،
+
+351
+00:30:32,170 --> 00:30:37,410
+سبع ذرات بهذا الشكل، بتأكدوا حيكون لإنه سبعة جاب
+
+352
+00:30:37,410 --> 00:30:43,720
+كلمة إيش؟ هبتسبع ذرات إيش هيجيبه؟ Hept لما يكون في
+
+353
+00:30:43,720 --> 00:30:48,960
+double bond ال double bond إيش هيجيبه؟ En لما يكون
+
+354
+00:30:48,960 --> 00:30:56,120
+في triple bond ل triple bond إيش هيجيبه؟ Ein زي
+
+355
+00:30:56,120 --> 00:31:01,490
+هيك لازم اسمه يبينحاجة بتعبر عن العدد بعدين عن
+
+356
+00:31:01,490 --> 00:31:05,650
+الألكين بعدين عن الألكاين هذا الكلام هذا الكلام
+
+357
+00:31:05,650 --> 00:31:12,530
+ككتابة اسم و كذكر مجموعات لكن بيجي سؤال لما بدي
+
+358
+00:31:12,530 --> 00:31:19,920
+أرقم أحدد وين موقع ال E وين موقع ال Iهذه لها جثة
+
+359
+00:31:19,920 --> 00:31:25,080
+تانية و الموقع ال ال و الموقع ال I هذه لها جثة
+
+360
+00:31:25,080 --> 00:31:28,680
+تانية الآن القصة بتقول القات يعني خليني أعمل سبعة
+
+361
+00:31:28,680 --> 00:31:35,560
+واحد اتنين تلاتة اربع خمسة ستة سبعة و حطيت هذه زي
+
+362
+00:31:35,560 --> 00:31:37,300
+هيك و حطيت هنا triple bond
+
+363
+00:31:40,170 --> 00:31:44,050
+هذا heaped in I الان من وان بده ارقمه من هنا ولا
+
+364
+00:31:44,050 --> 00:31:50,230
+من هناك بنقول بنرقمه من الأقرب لأحد الأطراف يعني
+
+365
+00:31:50,230 --> 00:31:53,430
+تكون سواء double او triple اقرب يعني هنا لو عديت
+
+366
+00:31:53,430 --> 00:31:56,130
+واحد اتنين اول multiple point بتقابلني هنا عن
+
+367
+00:31:56,130 --> 00:31:59,930
+امرأة كم؟ تلاتة اول واحدة بتقابلني عن امرأة ايش؟
+
+368
+00:31:59,930 --> 00:32:04,110
+واحد وبناء على ذلك هرقم واحد اتنين تلاتة اربعة
+
+369
+00:32:04,110 --> 00:32:14,600
+خمسة ستة سبعة فهذا هيكون heapedone in أربعة I هبت
+
+370
+00:32:14,600 --> 00:32:23,520
+one in four I واضح طبعا لو انعكس سجلوا هذا الشغل ب
+
+371
+00:32:23,520 --> 00:32:31,160
+ثانية بقول برقم من الأقرب لأحد الأطراف الأقرب
+
+372
+00:32:31,160 --> 00:32:35,760
+بشتغل عليه تمام يعني هذا المركب .. بصوا بري ثانية
+
+373
+00:32:35,760 --> 00:32:41,500
+يا هودايعني هذا المركب نفسه الآن لو كان زي هيك ايش
+
+374
+00:32:41,500 --> 00:32:45,740
+رأيكم؟ هيظلوا على نفس الترقيم؟ اه .. اه .. اه ..
+
+375
+00:32:45,740 --> 00:32:45,840
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه
+
+376
+00:32:45,840 --> 00:32:46,020
+.. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه ..
+
+377
+00:32:46,020 --> 00:32:47,260
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه
+
+378
+00:32:47,260 --> 00:32:47,540
+.. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه ..
+
+379
+00:32:47,540 --> 00:32:48,040
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه
+
+380
+00:32:48,040 --> 00:32:48,460
+.. اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه ..
+
+381
+00:32:48,460 --> 00:32:52,340
+اه .. اه .. اه .. اه .. اه .. اه .. اه .. اه .. ا
+
+382
+00:32:53,210 --> 00:32:58,710
+يعني مافيش تسمية نهائية تكون I'm in هذه ضد ال
+
+383
+00:32:58,710 --> 00:33:01,910
+alphabetical دائما الاتقاء ال double و ال triple
+
+384
+00:33:01,910 --> 00:33:06,210
+bond يجب أن تكون إيش؟ in I'm مافيش إشي في الكون
+
+385
+00:33:06,210 --> 00:33:11,990
+اسمه I'm in ضد ال alphabetical واضح؟ الآن الترقيم
+
+386
+00:33:11,990 --> 00:33:16,190
+هلجيته؟ هذي جاي ع نمره واحد لو بتعد من هنا بتجي ع
+
+387
+00:33:16,190 --> 00:33:19,770
+نمره واحد اتنين تلاتة إذا هذا الترقيم الصح وجدت
+
+388
+00:33:19,770 --> 00:33:22,470
+هذا المركب لما بده يتسمى مرة تانية
+
+389
+00:33:26,270 --> 00:33:34,090
+لاحظوا in و i عشان يتقارنوا المركبين الان هذا ال
+
+390
+00:33:34,090 --> 00:33:40,250
+in تبع وين اربعة و ال i تبع واحد خلصنا من المركب
+
+391
+00:33:40,250 --> 00:33:46,310
+اللي قبله ماناش فيه هذا بيصير اسمه four in one i
+
+392
+00:33:46,310 --> 00:33:51,450
+فتسمية ال double و ال triple bond إذا التقوا مع
+
+393
+00:33:51,450 --> 00:33:57,650
+بعضيجب أن يُذكروا in I ويجب أن يكون الترقيم من
+
+394
+00:33:57,650 --> 00:34:01,910
+الأقرب إلى أحد الأطراف الآن بيجوا الناس الاش
+
+395
+00:34:01,910 --> 00:34:09,090
+الملولوين عارفين هم؟ اه دول تعون لو بيقولوا طيب يا
+
+396
+00:34:09,090 --> 00:34:14,470
+تورا لو كانوا التنتين على نفس البعد يعني لو حطيت
+
+397
+00:34:14,470 --> 00:34:20,920
+هنا نشطب هدول احنا الآن مش عارفينأه لو كانوا
+
+398
+00:34:20,920 --> 00:34:25,600
+التنتين على نفس البعد حطيتها الرابطة و هالرابطة
+
+399
+00:34:25,600 --> 00:34:30,900
+جيت هنا عديت واحد هاي أول ما بلجي واحدة منه مع
+
+400
+00:34:30,900 --> 00:34:36,320
+نمرقاش اتنين و هنا واحد اتنين على اليمين اتنين و
+
+401
+00:34:36,320 --> 00:34:39,300
+على الشمال اتنين و أكتب نعطي الأولوية لا إيش في
+
+402
+00:34:39,300 --> 00:34:43,880
+الترخيم للتنائية إذا تساوإذا تساوى الأولوي
+
+403
+00:34:43,880 --> 00:34:48,900
+للثنائية فمثل هذا المركب برضه هيكون hip و in و I
+
+404
+00:34:48,900 --> 00:34:53,160
+ان هذا مما لا خلافة فيه كلمة in و I الآن الترقيم
+
+405
+00:34:53,160 --> 00:34:59,180
+لأ بنخليه إذا تساوى المرور على الرابطة الثنائية
+
+406
+00:34:59,180 --> 00:35:08,100
+قبل الرابطة الثلاثية إذا هذا بيكون two in five
+
+407
+00:35:08,100 --> 00:35:15,930
+I واضح الفكرةفهذا الكلام لو انتقى رابطة ثنائية أو
+
+408
+00:35:15,930 --> 00:35:22,750
+ثلاثية يذكره قولا واحدا in I الترقيم من الأقرب
+
+409
+00:35:22,750 --> 00:35:26,610
+لأحد الأطراف بغض النظر كرابطة زوجية أو ثنائية إلا
+
+410
+00:35:26,610 --> 00:35:32,130
+إذا تساووا فالأفضلية هتكون لإيش ال in بتكون مفضلة
+
+411
+00:35:32,130 --> 00:35:37,070
+على ال I احنا هذه المعلومة كنا مختصرينها طالما
+
+412
+00:35:37,070 --> 00:35:40,410
+سألت زمنكوا فيها فصرنا ضايفينها
+
+413
+00:35:44,460 --> 00:35:48,380
+لاحظوا معي ال الديهايد لما تيجي على ال aromatic
+
+414
+00:35:48,380 --> 00:35:54,960
+compounds أخدنا تسميتها يعني هذا benzaldehyde هنا
+
+415
+00:35:54,960 --> 00:35:59,520
+التقاء الديهايد مع الكهول ال الديهايد أقوى من
+
+416
+00:35:59,520 --> 00:36:08,220
+الكهول وعشان هيصير two-hydroxy benzaldehyde
+
+417
+00:36:08,220 --> 00:36:09,540
+شوف الحرف ال بيه رايح
+
+418
+00:36:12,860 --> 00:36:17,280
+2-hydroxybenzaldehyde اللي هو اسمه salicyldehyde
+
+419
+00:36:17,280 --> 00:36:20,720
+يمكن مار عليك انتوا salicylic acid لما تكون هذه OH
+
+420
+00:36:20,720 --> 00:36:25,560
+و هذا acid لو كان الديهايد salicyldehyde مثلا هذا
+
+421
+00:36:25,560 --> 00:36:29,940
+المركب في الديهايد و OH او مثل من اعلى واحدة ال
+
+422
+00:36:29,940 --> 00:36:36,840
+الديهايد اذا مركبي كله هذا اسمهبنزالدهيد ايش بيحمل
+
+423
+00:36:36,840 --> 00:36:42,320
+على نمرة أربعة؟ هيدروكسي وع نمرة تلاتة؟ ميثوكسي
+
+424
+00:36:42,320 --> 00:36:46,860
+إذا هذا لو بدأ أسميه اسم كامل، إيش هقول؟ four
+
+425
+00:36:46,860 --> 00:36:55,780
+-hydroxy three-methoxy، بنستعمل بهرة وميتا؟ four
+
+426
+00:36:55,780 --> 00:37:01,280
+-hydroxy، three-methoxy، benzaldehyde، اللي هو
+
+427
+00:37:01,280 --> 00:37:08,950
+مركب إيش؟الفانيلا يعني الفانيلا هي نفس الاسم تبعها
+
+428
+00:37:08,950 --> 00:37:16,070
+4-hydroxy-3-methoxy-benzaldehyde الآن أخر شغلة بدي
+
+429
+00:37:16,070 --> 00:37:23,250
+أحكيها لو يا ترى إجا الكحول أو الالديهايد أو
+
+430
+00:37:23,250 --> 00:37:29,710
+الكيتون على حلقة لاحظوا معي بدي أخد دراسة مقارنة
+
+431
+00:37:29,710 --> 00:37:38,320
+للثلاثة كحولالديهاي كيتون ييجوا على حلقة نفترض على
+
+432
+00:37:38,320 --> 00:37:46,280
+سايكلوبنتين خلّينا نتطلع بالشكل القاتل هنعمل هنعمل
+
+433
+00:37:46,280 --> 00:37:51,220
+تلت مرات الكلام الآن هي السايكلوبنتين عملناها مرة
+
+434
+00:37:51,220 --> 00:38:02,620
+مرتين تلاتة في مرة حطينا عليها إيش مجموعة OH هذا
+
+435
+00:38:02,620 --> 00:38:08,930
+إيشكحول و في المرة حاطينا عليها C double bond O
+
+436
+00:38:08,930 --> 00:38:13,730
+هذا كيتون في المرة التالتة اجينا نحط عليهم
+
+437
+00:38:13,730 --> 00:38:18,170
+الديهايد ال الديهايد شو هو كيف بقدر احط انا هنا
+
+438
+00:38:18,170 --> 00:38:23,920
+الديهايد جربوامافيش غير ان كل مجموعة ال الديهايد
+
+439
+00:38:23,920 --> 00:38:29,900
+اطلعها برا يعني اطلع برا C double bond O H شوفتوا
+
+440
+00:38:29,900 --> 00:38:33,660
+الفرق بينهم كيف ان انا هنا حطيت O مشبوكة مباشرة
+
+441
+00:38:33,660 --> 00:38:37,680
+بالحلقة هنا حطيت C double bond O مشبوكة مباشرة
+
+442
+00:38:37,680 --> 00:38:41,960
+بالحلقة هنا مافيش طريقة ان اطلع الديهايد ال oxygen
+
+443
+00:38:41,960 --> 00:38:46,100
+فيه مشبوكة مباشرة بالحلقة فبطلع كل مجموعة ال
+
+444
+00:38:46,100 --> 00:38:53,320
+الديهايد براواضح؟ اللي هي مع Carbon هذي زادت عن
+
+445
+00:38:53,320 --> 00:38:57,620
+هذي بإيش؟ ب Carbon ولذلك هذا لما بدنا نسميه
+
+446
+00:38:57,620 --> 00:39:02,560
+Cyclopentanol
+
+447
+00:39:02,560 --> 00:39:08,340
+تان و بنضيف النهاية تبعته All Cyclopentanol خلصنا
+
+448
+00:39:08,340 --> 00:39:16,050
+هذا لما بدنا نسميه نفس الفكرة Cycloبنتان وبنحطله
+
+449
+00:39:16,050 --> 00:39:23,250
+نهاية ال ketone بنتانون وخلصنا هذا لما بدي اسميه
+
+450
+00:39:23,250 --> 00:39:30,330
+.. لأ بسميهوش cycle بالتنالليش؟ لأنه إجي عليه
+
+451
+00:39:30,330 --> 00:39:33,690
+مجموعة كاملة خارجية، إجي عليه كمان carbon، C
+
+452
+00:39:33,690 --> 00:39:39,350
+double bond OH، بنسميه Cyclopenten-carb-aldehyde
+
+453
+00:39:39,350 --> 00:39:43,410
+لأنه إجت carbon زيادة عن اللي جابله، ولذلك هذا إيش
+
+454
+00:39:43,410 --> 00:39:50,910
+بده يتسمى؟ Cyclopenten-carb-aldehyde
+
+455
+00:39:53,820 --> 00:39:58,780
+ملاحظين الفرق بينهم؟ أنه أنا مابقدرش أشبك أكسوجين
+
+456
+00:39:58,780 --> 00:40:02,560
+الالديهايد مباشرة بالحلقة إلا من خلال ذرة كربون
+
+457
+00:40:02,560 --> 00:40:07,620
+ولذلك بنسميه Cyclopentane Carbaldehyde شفتوا الفرق
+
+458
+00:40:07,620 --> 00:40:11,500
+بين الكحول والكيتون والالديهايد لو يجي على حلقة؟
+
+459
+00:40:12,310 --> 00:40:16,630
+الان لو واحدة فيكم شاطرة بعد ما نختم المحاضرة بذكر
+
+460
+00:40:16,630 --> 00:40:20,210
+الله اتقولي كمان اخر مثال عشان نسكر هذه النقطة
+
+461
+00:40:20,210 --> 00:40:26,510
+المفروض يلحق هدولة كلهم ايش هيكون ال acid ال acid
+
+462
+00:40:26,510 --> 00:40:32,070
+لو بده ييجي على الحلقة كيف بده ييجي زي ال aldehyde
+
+463
+00:40:32,070 --> 00:40:37,150
+ال acid لو بده ييجي على الحلقة بده ييجي كله معلج
+
+464
+00:40:37,150 --> 00:40:38,010
+على الحلقة
+
+465
+00:40:42,740 --> 00:40:46,200
+ماقدرش أحطه على نفس الحلقة الأكسجينة المتصلة ولذلك
+
+466
+00:40:46,200 --> 00:40:49,820
+لما بدي أسميه بدي أسميه بشكل موازن لنظام ال
+
+467
+00:40:49,820 --> 00:40:57,680
+الديهايد إيش وجدت حاجة أقول عنه؟ Cyclo .. بنتين ..
+
+468
+00:40:57,680 --> 00:41:03,300
+Carboxylic acid كمان Carboxylic acid
+
+469
+00:41:05,250 --> 00:41:09,150
+شوفتوا كيف مقارنة الأمور بتيجي الكحول والكيتون
+
+470
+00:41:09,150 --> 00:41:11,750
+بيجيوا مباشرة على الحلقة فبنقول cyclopentanol
+
+471
+00:41:11,750 --> 00:41:16,090
+وcyclopentanol ال aldehyde لأ cyclopentane وcarb
+
+472
+00:41:16,090 --> 00:41:20,670
+aldehyde ال acid cyclopentane وcarboxylic acid
+
+473
+00:41:20,670 --> 00:41:26,650
+واضحة الفكرة وبهيك بننهي المحاضرة اليوم المرة اللي
+
+474
+00:41:26,650 --> 00:41:29,970
+جاي بنستمر في موضوع التسمية وموضوع ال aldehydes
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hJ0uUjaPUvk_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hJ0uUjaPUvk_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..cb50ad256d4a4255679a2ff2158f2b7afb875bbd
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hJ0uUjaPUvk_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4782, "start": 20.18, "end": 47.82, "text": "بسم الله الرحمن الرحيم الفصل التاسع موضوعه ال aldehydes and ketones طبعا ال aldehydes and ketones ربما انتوا اتلاحظوا انه عائلتين مش عائلة واحدة لو اطلعنا هنلاقي ان ال aldehydes و ال ketones هم جزء من عائلة اكبر جزء من عائلة اكبر اسمها", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 27188, 36520, 16712, 32277, 3615, 3714, 2407, 11242, 45367, 3224, 2423, 16798, 68, 3495, 14792, 293, 14979, 2213, 23032, 3555, 3615, 995, 2423, 16798, 68, 3495, 14792, 293, 14979, 2213, 12602, 3555, 15042, 16472, 2655, 14407, 1975, 2655, 15040, 5016, 19913, 14407, 16472, 3224, 6225, 16373, 1211, 2655, 9957, 37893, 6225, 16373, 37977, 36764, 24401, 3660, 45164, 1975, 9566, 1211, 3615, 8315, 8032, 1863, 15040, 38436, 16472, 2423, 16798, 68, 3495, 14792, 4032, 2423, 14979, 2213, 8032, 2304, 10874, 11622, 38207, 9154, 6225, 16373, 37977, 1975, 4117, 26890, 10874, 11622, 38207, 9154, 6225, 16373, 37977, 1975, 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{"start": 546.41, "end": 546.87, "word": " تفاعل", "probability": 0.8958740234375}, {"start": 546.87, "end": 548.33, "word": " إبدال", "probability": 0.6611328125}, {"start": 548.33, "end": 548.87, "word": " إذا", "probability": 0.8486328125}, {"start": 548.87, "end": 549.81, "word": " لو", "probability": 0.90869140625}, {"start": 549.81, "end": 550.19, "word": " جينا", "probability": 0.7456868489583334}, {"start": 550.19, "end": 551.05, "word": " سألناكم", "probability": 0.9033203125}, {"start": 551.05, "end": 551.53, "word": " قولنا", "probability": 0.7770182291666666}, {"start": 551.53, "end": 551.79, "word": " لكم", "probability": 0.816162109375}, {"start": 551.79, "end": 551.97, "word": " ال", "probability": 0.9091796875}, {"start": 551.97, "end": 552.89, "word": " aldehydes", "probability": 0.6158447265625}, {"start": 552.89, "end": 553.53, "word": " بيعملوا", "probability": 0.93828125}, {"start": 553.53, "end": 553.93, "word": " addition", "probability": 0.94775390625}, {"start": 553.93, "end": 554.61, "word": " بتقولوا", "probability": 0.687744140625}, {"start": 554.61, "end": 554.91, "word": " صح", "probability": 0.99072265625}], "temperature": 1.0}, {"id": 25, "seek": 57297, "start": 555.91, "end": 572.97, "text": "و ال acids و المشتقاتة بيعملوا substitution صح لو سألنا هل يا ترى ال eucleophilic addition و ال eucleophilic substitution ولا ال electrophilic addition و ال electrophilic substitution؟ ال eucleophilic", "tokens": [2407, 2423, 21667, 4032, 9673, 8592, 2655, 4587, 9307, 3660, 4724, 1829, 25957, 1211, 14407, 35827, 20328, 5016, 45164, 8608, 10721, 1211, 8315, 8032, 1211, 35186, 6055, 2288, 7578, 2423, 308, 1311, 306, 5317, 388, 299, 4500, 4032, 2423, 308, 1311, 306, 5317, 388, 299, 35827, 49429, 2423, 16717, 950, 388, 299, 4500, 4032, 2423, 16717, 950, 388, 299, 35827, 22807, 2423, 308, 1311, 306, 5317, 388, 299], "avg_logprob": -0.23369565476541934, "compression_ratio": 1.75, "no_speech_prob": 0.0, "words": [{"start": 555.91, "end": 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قلنا", "probability": 0.9327799479166666}, {"start": 1220.19, "end": 1220.59, "word": " مابدناش", "probability": 0.71015625}, {"start": 1220.59, "end": 1221.13, "word": " ننسى", "probability": 0.9478759765625}, {"start": 1221.13, "end": 1221.27, "word": " ان", "probability": 0.81201171875}, {"start": 1221.27, "end": 1222.03, "word": " الكحول", "probability": 0.9923502604166666}], "temperature": 1.0}, {"id": 53, "seek": 124050, "start": 1223.28, "end": 1240.5, "text": "في المجمعتين في الجزء القطبي ال R والجزء القطبي ال OH والجزء غير القطبي ال R وبناء على ذلك ال lower alcohols كانت water soluble وال higher alcohols كانت water soluble", "tokens": [41185, 9673, 7435, 2304, 34268, 9957, 8978, 25724, 11622, 38207, 25062, 9566, 21292, 2423, 497, 16070, 7435, 11622, 38207, 25062, 9566, 21292, 2423, 13931, 16070, 7435, 11622, 38207, 32771, 13546, 25062, 9566, 21292, 2423, 497, 46599, 1863, 16606, 15844, 29910, 23275, 2423, 3126, 7658, 82, 25961, 2655, 1281, 24807, 638, 16070, 2946, 7658, 82, 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{"start": 1230.96, "end": 1231.38, "word": " OH", "probability": 0.68505859375}, {"start": 1231.38, "end": 1231.88, "word": " والجزء", "probability": 0.9534912109375}, {"start": 1231.88, "end": 1232.22, "word": " غير", "probability": 0.971923828125}, {"start": 1232.22, "end": 1232.7, "word": " القطبي", "probability": 0.94287109375}, {"start": 1232.7, "end": 1232.86, "word": " ال", "probability": 0.92138671875}, {"start": 1232.86, "end": 1233.2, "word": " R", "probability": 0.8828125}, {"start": 1233.2, "end": 1233.9, "word": " وبناء", "probability": 0.81298828125}, {"start": 1233.9, "end": 1234.14, "word": " على", "probability": 0.82763671875}, {"start": 1234.14, "end": 1234.56, "word": " ذلك", "probability": 0.991455078125}, {"start": 1234.56, "end": 1234.76, "word": " ال", "probability": 0.65771484375}, {"start": 1234.76, "end": 1235.04, "word": " lower", "probability": 0.61083984375}, {"start": 1235.04, "end": 1235.82, "word": " alcohols", "probability": 0.699951171875}, {"start": 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بس R صغيرة يعني مثل و مثل بيصير ال acetone ال acetone بدوب في الميه", "tokens": [2655, 8848, 37983, 9957, 29538, 9673, 30241, 20498, 3660, 22807, 2423, 28820, 10943, 8717, 36178, 3224, 39894, 37983, 2288, 4032, 9957, 22807, 8978, 2423, 14979, 2213, 4724, 43042, 3224, 2423, 14979, 2213, 8978, 16095, 10874, 11622, 38207, 12174, 9566, 49401, 2423, 383, 3834, 6086, 422, 4032, 8978, 16095, 2423, 497, 5296, 15042, 6055, 9381, 13546, 2423, 497, 29538, 9122, 3555, 48923, 4724, 1829, 3555, 9566, 1211, 14407, 7251, 3215, 37746, 14407, 8978, 9673, 1829, 3224, 4724, 3794, 497, 20328, 17082, 48923, 37495, 22653, 50113, 1211, 4032, 50113, 1211, 4724, 1829, 9381, 13546, 2423, 37848, 546, 2423, 37848, 546, 47525, 37746, 8978, 9673, 1829, 3224], "avg_logprob": -0.15476190476190477, "compression_ratio": 1.7904761904761906, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1241.22, "end": 1241.86, "word": "تذكرين", "probability": 0.73095703125}, {"start": 1241.86, "end": 1242.0, "word": " 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{"start": 1276.36, "end": 1277.08, "word": " والكيتونز،", "probability": 0.674072265625}, {"start": 1277.08, "end": 1277.38, "word": " بتكون", "probability": 0.97412109375}, {"start": 1277.38, "end": 1278.16, "word": " إيش؟", "probability": 0.8450927734375}, {"start": 1278.16, "end": 1278.56, "word": " water", "probability": 0.7607421875}, {"start": 1278.56, "end": 1279.88, "word": " soluble،", "probability": 0.6961263020833334}, {"start": 1279.88, "end": 1280.04, "word": " كل", "probability": 0.97314453125}, {"start": 1280.04, "end": 1280.18, "word": " ما", "probability": 0.734375}, {"start": 1280.18, "end": 1280.3, "word": " ال", "probability": 0.91259765625}, {"start": 1280.3, "end": 1280.48, "word": " R", "probability": 0.6513671875}, {"start": 1280.48, "end": 1280.98, "word": " كبرت،", "probability": 0.8643798828125}, {"start": 1280.98, "end": 1281.52, "word": " بتبطل،", "probability": 0.94892578125}, {"start": 1281.52, "end": 1281.66, "word": " يعني", "probability": 0.97265625}, 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اللي", "probability": 0.807861328125}, {"start": 1463.71, "end": 1463.95, "word": " زي", "probability": 0.974365234375}, {"start": 1463.95, "end": 1464.29, "word": " هيك", "probability": 0.93408203125}, {"start": 1464.29, "end": 1464.75, "word": " كم", "probability": 0.91455078125}, {"start": 1464.75, "end": 1465.53, "word": " كحول", "probability": 0.9908854166666666}, {"start": 1465.53, "end": 1466.57, "word": " بالمجمل", "probability": 0.9259033203125}, {"start": 1466.57, "end": 1467.23, "word": " منه", "probability": 0.991943359375}, {"start": 1467.23, "end": 1467.79, "word": " اتنين", "probability": 0.80499267578125}], "temperature": 1.0}, {"id": 64, "seek": 149028, "start": 1469.42, "end": 1490.28, "text": "هك هتكون جوابته غلط واضح؟ ليش؟ مين تقول لي ليش الغلط؟ لحظة أنا قلت المتسلسل، بعرف أنه في ISO و في tertiary، هذه قصة تانية", "tokens": [3224, 4117, 8032, 2655, 30544, 10874, 14407, 3555, 47395, 32771, 1211, 9566, 4032, 46958, 5016, 22807, 32239, 8592, 22807, 3714, 9957, 6055, 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"2-hydroxybenzaldehyde اللي هو اسمه salicyldehyde يمكن مار عليك انتوا salicylic acid لما تكون هذه OH و هذا acid لو كان الديهايد salicyldehyde مثلا هذا المركب في الديهايد و OH او مثل من اعلى واحدة ال الديهايد اذا مركبي كله هذا اسمه", "tokens": [17, 12, 21591, 340, 12876, 1799, 89, 304, 1479, 3495, 1479, 13672, 1829, 31439, 24525, 2304, 3224, 1845, 2632, 348, 68, 3495, 1479, 7251, 43020, 3714, 9640, 25894, 4117, 16472, 2655, 14407, 1845, 2632, 1050, 8258, 5296, 15042, 6055, 30544, 29538, 13931, 4032, 23758, 8258, 45164, 25961, 2423, 16254, 11296, 25708, 1845, 2632, 348, 68, 3495, 1479, 50113, 15040, 23758, 9673, 31747, 3555, 8978, 2423, 16254, 11296, 25708, 4032, 13931, 1975, 2407, 50113, 1211, 9154, 1975, 3615, 23942, 36764, 24401, 3660, 2423, 2423, 16254, 11296, 25708, 1975, 15730, 3714, 31747, 21292, 28242, 3224, 23758, 24525, 2304, 3224], "avg_logprob": -0.3147321413366162, "compression_ratio": 1.7676767676767677, "no_speech_prob": 0.0, "words": [{"start": 2172.8600000000006, "end": 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2314.92, "word": " هنا", "probability": 0.63916015625}, {"start": 2314.92, "end": 2315.48, "word": " حطيت", "probability": 0.8513997395833334}, {"start": 2315.48, "end": 2315.92, "word": " C", "probability": 0.94677734375}, {"start": 2315.92, "end": 2316.1, "word": " double", "probability": 0.8974609375}, {"start": 2316.1, "end": 2316.38, "word": " bond", "probability": 0.96826171875}, {"start": 2316.38, "end": 2316.54, "word": " O", "probability": 0.98291015625}, {"start": 2316.54, "end": 2317.06, "word": " مشبوكة", "probability": 0.978125}, {"start": 2317.06, "end": 2317.68, "word": " مباشرة", "probability": 0.9910888671875}, {"start": 2317.68, "end": 2318.26, "word": " بالحلقة", "probability": 0.989501953125}, {"start": 2318.26, "end": 2318.86, "word": " هنا", "probability": 0.912109375}, {"start": 2318.86, "end": 2319.24, "word": " مافيش", "probability": 0.96484375}, {"start": 2319.24, "end": 2319.84, "word": " طريقة", "probability": 0.99267578125}, {"start": 2319.84, "end": 2320.46, "word": " ان", "probability": 0.89697265625}, {"start": 2320.46, "end": 2320.84, "word": " اطلع", "probability": 0.983154296875}, {"start": 2320.84, "end": 2321.42, "word": " الديهايد", "probability": 0.91748046875}, {"start": 2321.42, "end": 2321.56, "word": " ال", "probability": 0.83251953125}, {"start": 2321.56, "end": 2321.96, "word": " oxygen", "probability": 0.53173828125}, {"start": 2321.96, "end": 2322.26, "word": " فيه", "probability": 0.83056640625}, {"start": 2322.26, "end": 2322.76, "word": " مشبوكة", "probability": 0.9736328125}, {"start": 2322.76, "end": 2323.3, "word": " مباشرة", "probability": 0.992919921875}, {"start": 2323.3, "end": 2323.96, "word": " بالحلقة", "probability": 0.9912109375}, {"start": 2323.96, "end": 2324.92, "word": " فبطلع", "probability": 0.97568359375}, {"start": 2324.92, "end": 2325.26, "word": " كل", "probability": 0.98486328125}, {"start": 2325.26, "end": 2325.92, "word": " مجموعة", "probability": 0.976171875}, {"start": 2325.92, "end": 2326.1, "word": " ال", "probability": 0.99462890625}, {"start": 2326.1, "end": 2326.74, "word": " الديهايد", "probability": 0.9635009765625}, {"start": 2326.74, "end": 2327.12, "word": " برا", "probability": 0.97509765625}], "temperature": 1.0}, {"id": 98, "seek": 235223, "start": 2328.5, "end": 2352.24, "text": "واضح؟ اللي هي مع Carbon هذي زادت عن هذي بإيش؟ ب Carbon ولذلك هذا لما بدنا نسميه Cyclopentanol تان و بنضيف النهاية تبعته All Cyclopentanol خلصنا هذا لما بدنا نسميه نفس الفكرة Cyclo", "tokens": [2407, 46958, 5016, 22807, 13672, 1829, 39896, 20449, 31453, 8032, 8848, 1829, 30767, 18513, 2655, 18871, 8032, 8848, 1829, 4724, 28814, 1829, 8592, 22807, 4724, 31453, 35525, 8848, 23275, 23758, 5296, 15042, 47525, 8315, 8717, 38251, 1829, 3224, 10295, 3474, 404, 317, 282, 401, 6055, 7649, 4032, 44945, 11242, 33911, 28239, 11296, 10632, 6055, 3555, 34268, 3224, 1057, 10295, 3474, 404, 317, 282, 401, 16490, 1211, 9381, 8315, 23758, 5296, 15042, 47525, 8315, 8717, 38251, 1829, 3224, 8717, 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0.804248046875}, {"start": 2334.1, "end": 2334.1, "word": " ب", "probability": 0.82958984375}, {"start": 2334.1, "end": 2335.12, "word": " Carbon", "probability": 0.57470703125}, {"start": 2335.12, "end": 2336.06, "word": " ولذلك", "probability": 0.77783203125}, {"start": 2336.06, "end": 2336.32, "word": " هذا", "probability": 0.80517578125}, {"start": 2336.32, "end": 2336.48, "word": " لما", "probability": 0.9462890625}, {"start": 2336.48, "end": 2336.74, "word": " بدنا", "probability": 0.771484375}, {"start": 2336.74, "end": 2337.62, "word": " نسميه", "probability": 0.9814453125}, {"start": 2337.62, "end": 2342.56, "word": " Cyclopentanol", "probability": 0.66326904296875}, {"start": 2342.56, "end": 2343.26, "word": " تان", "probability": 0.594482421875}, {"start": 2343.26, "end": 2344.12, "word": " و", "probability": 0.393798828125}, {"start": 2344.12, "end": 2344.58, "word": " بنضيف", "probability": 0.9031575520833334}, {"start": 2344.58, "end": 2345.02, "word": " النهاية", "probability": 0.90869140625}, {"start": 2345.02, "end": 2345.7, "word": " تبعته", "probability": 0.90283203125}, {"start": 2345.7, "end": 2346.34, "word": " All", "probability": 0.57421875}, {"start": 2346.34, "end": 2347.66, "word": " Cyclopentanol", "probability": 0.8075968424479166}, {"start": 2347.66, "end": 2348.34, "word": " خلصنا", "probability": 0.9267578125}, {"start": 2348.34, "end": 2349.08, "word": " هذا", "probability": 0.794921875}, {"start": 2349.08, "end": 2349.3, "word": " لما", "probability": 0.980712890625}, {"start": 2349.3, "end": 2349.56, "word": " بدنا", "probability": 0.632080078125}, {"start": 2349.56, "end": 2350.06, "word": " نسميه", "probability": 0.9368896484375}, {"start": 2350.06, "end": 2350.3, "word": " نفس", "probability": 0.983154296875}, {"start": 2350.3, "end": 2350.88, "word": " الفكرة", "probability": 0.99462890625}, {"start": 2350.88, "end": 2352.24, "word": " Cyclo", "probability": 0.81298828125}], "temperature": 1.0}, {"id": 99, "seek": 236698, "start": 2353.23, "end": 2366.99, "text": "بنتان وبنحطله نهاية ال ketone بنتانون وخلصنا هذا لما بدي اسميه .. لأ بسميهوش cycle بالتنال", "tokens": [3555, 29399, 7649, 46599, 1863, 5016, 9566, 43761, 8717, 11296, 10632, 2423, 14979, 546, 4724, 29399, 7649, 11536, 4032, 9778, 1211, 9381, 8315, 23758, 5296, 15042, 4724, 16254, 24525, 2304, 1829, 3224, 4386, 5296, 10721, 4724, 38251, 1829, 3224, 2407, 8592, 6586, 20666, 2655, 1863, 6027], "avg_logprob": -0.3500664842889664, "compression_ratio": 1.2991452991452992, "no_speech_prob": 0.0, "words": [{"start": 2353.23, "end": 2354.57, "word": "بنتان", "probability": 0.8035481770833334}, {"start": 2354.57, "end": 2356.05, "word": " وبنحطله", "probability": 0.631201171875}, {"start": 2356.05, "end": 2356.47, "word": " نهاية", "probability": 0.9469401041666666}, {"start": 2356.47, "end": 2356.67, "word": " ال", "probability": 0.8837890625}, {"start": 2356.67, "end": 2357.23, "word": " ketone", "probability": 0.6370849609375}, {"start": 2357.23, "end": 2358.53, "word": " بنتانون", "probability": 0.783721923828125}, {"start": 2358.53, "end": 2360.07, "word": " وخلصنا", "probability": 0.91884765625}, {"start": 2360.07, "end": 2361.17, "word": " هذا", "probability": 0.7060546875}, {"start": 2361.17, "end": 2361.41, "word": " لما", "probability": 0.920654296875}, {"start": 2361.41, "end": 2361.73, "word": " بدي", "probability": 0.6876220703125}, {"start": 2361.73, "end": 2363.25, "word": " اسميه", "probability": 0.774658203125}, {"start": 2363.25, "end": 2364.21, "word": " ..", "probability": 0.3115234375}, {"start": 2364.21, "end": 2364.81, "word": " لأ", "probability": 0.833251953125}, {"start": 2364.81, "end": 2365.89, "word": " بسميهوش", "probability": 0.6991373697916666}, {"start": 2365.89, "end": 2366.23, "word": " cycle", "probability": 0.1968994140625}, {"start": 2366.23, "end": 2366.99, "word": " بالتنال", "probability": 0.7021484375}], "temperature": 1.0}, {"id": 100, "seek": 239091, "start": 2368.17, "end": 2390.91, "text": "ليش؟ لأنه إجي عليه مجموعة كاملة خارجية، إجي عليه كمان carbon، C double bond OH، بنسميه Cyclopenten-carb-aldehyde لأنه إجت carbon زيادة عن اللي جابله، ولذلك هذا إيش بده يتسمى؟ Cyclopenten-carb-aldehyde", "tokens": [20292, 8592, 22807, 5296, 33456, 3224, 11933, 7435, 1829, 47356, 3714, 7435, 2304, 2407, 27884, 9122, 10943, 37977, 16490, 9640, 7435, 10632, 12399, 11933, 7435, 1829, 47356, 9122, 2304, 7649, 5954, 12399, 383, 3834, 6086, 13931, 12399, 44945, 38251, 1829, 3224, 10295, 3474, 404, 317, 268, 12, 6166, 65, 12, 304, 1479, 3495, 1479, 5296, 33456, 3224, 11933, 7435, 2655, 5954, 30767, 1829, 18513, 3660, 18871, 13672, 1829, 10874, 16758, 43761, 12399, 35525, 8848, 23275, 23758, 11933, 1829, 8592, 47525, 3224, 7251, 2655, 38251, 7578, 22807, 49173, 404, 317, 268, 12, 6166, 65, 12, 304, 1479, 3495, 1479], "avg_logprob": -0.21227904612367804, "compression_ratio": 1.5416666666666667, "no_speech_prob": 0.0, "words": [{"start": 2368.17, "end": 2368.91, "word": "ليش؟", "probability": 0.7708333333333334}, {"start": 2368.91, "end": 2369.35, "word": " لأنه", "probability": 0.8404947916666666}, {"start": 2369.35, "end": 2370.07, "word": " إجي", "probability": 0.5015462239583334}, {"start": 2370.07, "end": 2370.33, "word": " عليه", "probability": 0.93017578125}, {"start": 2370.33, "end": 2370.91, "word": " مجموعة", "probability": 0.95}, {"start": 2370.91, "end": 2371.45, "word": " كاملة", "probability": 0.99169921875}, {"start": 2371.45, "end": 2372.19, "word": " خارجية،", "probability": 0.859765625}, {"start": 2372.19, "end": 2372.37, "word": " إجي", "probability": 0.8707682291666666}, {"start": 2372.37, "end": 2372.57, "word": " عليه", "probability": 0.99169921875}, {"start": 2372.57, "end": 2372.93, "word": " كمان", "probability": 0.9944661458333334}, {"start": 2372.93, "end": 2373.55, "word": " carbon،", "probability": 0.67822265625}, {"start": 2373.55, "end": 2373.69, "word": " C", "probability": 0.419677734375}, {"start": 2373.69, "end": 2373.89, "word": " double", "probability": 0.5537109375}, {"start": 2373.89, "end": 2374.13, "word": " bond", "probability": 0.82861328125}, {"start": 2374.13, "end": 2374.67, "word": " OH،", "probability": 0.60791015625}, {"start": 2374.67, "end": 2375.81, "word": " بنسميه", "probability": 0.968994140625}, {"start": 2375.81, "end": 2377.51, "word": " Cyclopenten", "probability": 0.5794921875}, {"start": 2377.51, "end": 2378.41, "word": "-carb", "probability": 0.5738118489583334}, {"start": 2378.41, "end": 2379.35, "word": "-aldehyde", "probability": 0.8953125}, {"start": 2379.35, "end": 2380.07, "word": " لأنه", "probability": 0.7151692708333334}, {"start": 2380.07, "end": 2380.53, "word": " إجت", "probability": 0.91357421875}, {"start": 2380.53, "end": 2381.03, "word": " carbon", "probability": 0.83447265625}, {"start": 2381.03, "end": 2381.51, "word": " زيادة", "probability": 0.8902587890625}, {"start": 2381.51, "end": 2381.69, "word": " عن", "probability": 0.94580078125}, {"start": 2381.69, "end": 2381.83, "word": " اللي", "probability": 0.959716796875}, {"start": 2381.83, "end": 2382.47, "word": " جابله،", "probability": 0.82373046875}, {"start": 2382.47, "end": 2382.97, "word": " ولذلك", "probability": 0.90869140625}, {"start": 2382.97, "end": 2383.21, "word": " هذا", "probability": 0.826171875}, {"start": 2383.21, "end": 2383.41, "word": " إيش", "probability": 0.958984375}, {"start": 2383.41, "end": 2383.59, "word": " بده", "probability": 0.71826171875}, {"start": 2383.59, "end": 2385.01, "word": " يتسمى؟", "probability": 0.9421875}, {"start": 2385.01, "end": 2387.05, "word": " Cyclopenten", "probability": 0.8248291015625}, {"start": 2387.05, "end": 2389.99, "word": "-carb", "probability": 0.9484049479166666}, {"start": 2389.99, "end": 2390.91, "word": "-aldehyde", "probability": 0.9697265625}], "temperature": 1.0}, {"id": 101, "seek": 241150, "start": 2393.82, "end": 2411.5, "text": "ملاحظين الفرق بينهم؟ أنه أنا مابقدرش أشبك أكسوجين الالديهايد مباشرة بالحلقة إلا من خلال ذرة كربون ولذلك بنسميه Cyclopentane Carbaldehyde شفتوا الفرق بين الكحول والكيتون والالديهايد لو يجي على حلقة؟", "tokens": [2304, 15040, 5016, 19913, 9957, 27188, 2288, 4587, 49374, 16095, 22807, 14739, 3224, 41850, 3714, 16758, 28543, 2288, 8592, 5551, 8592, 3555, 4117, 5551, 4117, 3794, 29245, 9957, 2423, 6027, 16254, 11296, 25708, 3714, 3555, 33599, 25720, 20666, 5016, 1211, 28671, 11933, 15040, 9154, 16490, 1211, 6027, 29910, 25720, 9122, 25513, 11536, 35525, 8848, 23275, 44945, 38251, 1829, 3224, 10295, 3474, 404, 317, 1929, 2741, 2645, 1479, 3495, 1479, 13412, 5172, 2655, 14407, 27188, 2288, 4587, 49374, 33251, 5016, 12610, 16070, 4117, 36081, 11536, 16070, 6027, 16254, 11296, 25708, 45164, 7251, 7435, 1829, 15844, 11331, 1211, 28671, 22807], "avg_logprob": -0.22253788330338217, "compression_ratio": 1.6715686274509804, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2393.82, "end": 2394.4, "word": "ملاحظين", "probability": 0.8228515625}, {"start": 2394.4, "end": 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2401.32, "end": 2401.62, "word": " خلال", "probability": 0.9930013020833334}, {"start": 2401.62, "end": 2401.92, "word": " ذرة", "probability": 0.808837890625}, {"start": 2401.92, "end": 2402.56, "word": " كربون", "probability": 0.9208984375}, {"start": 2402.56, "end": 2403.48, "word": " ولذلك", "probability": 0.7819010416666666}, {"start": 2403.48, "end": 2403.98, "word": " بنسميه", "probability": 0.9423828125}, {"start": 2403.98, "end": 2404.86, "word": " Cyclopentane", "probability": 0.6794189453125}, {"start": 2404.86, "end": 2406.38, "word": " Carbaldehyde", "probability": 0.76806640625}, {"start": 2406.38, "end": 2407.32, "word": " شفتوا", "probability": 0.71234130859375}, {"start": 2407.32, "end": 2407.62, "word": " الفرق", "probability": 0.99169921875}, {"start": 2407.62, "end": 2407.82, "word": " بين", "probability": 0.97998046875}, {"start": 2407.82, "end": 2408.48, "word": " الكحول", "probability": 0.9943033854166666}, {"start": 2408.48, "end": 2409.52, "word": " والكيتون", "probability": 0.7589111328125}, {"start": 2409.52, "end": 2410.4, "word": " والالديهايد", "probability": 0.93720703125}, {"start": 2410.4, "end": 2410.56, "word": " لو", "probability": 0.94482421875}, {"start": 2410.56, "end": 2410.76, "word": " يجي", "probability": 0.6888834635416666}, {"start": 2410.76, "end": 2410.86, "word": " على", "probability": 0.6025390625}, {"start": 2410.86, "end": 2411.5, "word": " حلقة؟", "probability": 0.9688720703125}], "temperature": 1.0}, {"id": 102, "seek": 243801, "start": 2412.31, "end": 2438.01, "text": "الان لو واحدة فيكم شاطرة بعد ما نختم المحاضرة بذكر الله اتقولي كمان اخر مثال عشان نسكر هذه النقطة المفروض يلحق هدولة كلهم ايش هيكون ال acid ال acid لو بده ييجي على الحلقة كيف بده ييجي زي ال aldehyde ال acid لو بده ييجي على الحلقة بده ييجي كله معلج على الحلقة", "tokens": [6027, 7649, 45164, 36764, 24401, 3660, 8978, 24793, 13412, 41193, 25720, 39182, 19446, 8717, 9778, 39237, 9673, 5016, 46958, 25720, 4724, 8848, 37983, 21984, 1975, 2655, 39648, 1829, 9122, 2304, 7649, 1975, 34740, 50113, 6027, 6225, 8592, 7649, 8717, 3794, 37983, 29538, 28239, 47432, 3660, 9673, 5172, 32887, 11242, 7251, 1211, 5016, 4587, 8032, 3215, 12610, 3660, 28242, 16095, 1975, 1829, 8592, 39896, 30544, 2423, 8258, 2423, 8258, 45164, 47525, 3224, 7251, 1829, 7435, 1829, 15844, 21542, 1211, 28671, 9122, 33911, 47525, 3224, 7251, 1829, 7435, 1829, 30767, 1829, 2423, 16798, 68, 3495, 1479, 2423, 8258, 45164, 47525, 3224, 7251, 1829, 7435, 1829, 15844, 21542, 1211, 28671, 47525, 3224, 7251, 1829, 7435, 1829, 28242, 3224, 20449, 1211, 7435, 15844, 21542, 1211, 28671], "avg_logprob": -0.1361788620309132, "compression_ratio": 2.036697247706422, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2412.31, "end": 2412.75, "word": "الان", "probability": 0.725341796875}, {"start": 2412.75, "end": 2413.15, "word": " لو", "probability": 0.95849609375}, {"start": 2413.15, "end": 2413.49, "word": " واحدة", "probability": 0.9757486979166666}, {"start": 2413.49, "end": 2413.81, "word": " فيكم", "probability": 0.887451171875}, {"start": 2413.81, "end": 2414.47, "word": " شاطرة", "probability": 0.984375}, {"start": 2414.47, "end": 2415.19, "word": " بعد", "probability": 0.88330078125}, {"start": 2415.19, "end": 2415.35, "word": " ما", "probability": 0.91455078125}, {"start": 2415.35, "end": 2415.69, "word": " نختم", "probability": 0.8992513020833334}, {"start": 2415.69, "end": 2416.25, "word": " المحاضرة", "probability": 0.9774169921875}, {"start": 2416.25, "end": 2416.63, "word": " بذكر", "probability": 0.8800455729166666}, {"start": 2416.63, "end": 2416.91, "word": " الله", "probability": 0.8037109375}, {"start": 2416.91, "end": 2417.63, "word": " اتقولي", "probability": 0.6436767578125}, {"start": 2417.63, "end": 2417.95, "word": " كمان", "probability": 0.87451171875}, {"start": 2417.95, "end": 2418.35, "word": " اخر", "probability": 0.864501953125}, {"start": 2418.35, "end": 2418.81, "word": " مثال", "probability": 0.91552734375}, {"start": 2418.81, "end": 2419.13, "word": " عشان", "probability": 0.9689127604166666}, {"start": 2419.13, "end": 2419.57, "word": " نسكر", "probability": 0.93896484375}, {"start": 2419.57, "end": 2419.81, "word": " هذه", "probability": 0.7734375}, {"start": 2419.81, "end": 2420.21, "word": " النقطة", "probability": 0.9586588541666666}, {"start": 2420.21, "end": 2420.63, "word": " المفروض", "probability": 0.984375}, {"start": 2420.63, "end": 2421.01, "word": " يلحق", "probability": 0.9754638671875}, {"start": 2421.01, "end": 2421.47, "word": " هدولة", "probability": 0.7933349609375}, {"start": 2421.47, "end": 2421.97, "word": " كلهم", "probability": 0.977294921875}, {"start": 2421.97, "end": 2422.59, "word": " ايش", "probability": 0.7472330729166666}, {"start": 2422.59, "end": 2423.11, "word": " هيكون", "probability": 0.877685546875}, {"start": 2423.11, "end": 2424.45, "word": " ال", "probability": 0.82861328125}, {"start": 2424.45, "end": 2424.93, "word": " acid", "probability": 0.79345703125}, {"start": 2424.93, "end": 2425.95, "word": " ال", "probability": 0.791015625}, {"start": 2425.95, "end": 2426.51, "word": " acid", "probability": 0.98779296875}, {"start": 2426.51, "end": 2426.95, "word": " لو", "probability": 0.98388671875}, {"start": 2426.95, "end": 2427.23, "word": " بده", "probability": 0.844970703125}, {"start": 2427.23, "end": 2427.45, "word": " ييجي", "probability": 0.9410400390625}, {"start": 2427.45, "end": 2427.65, "word": " على", "probability": 0.75}, {"start": 2427.65, "end": 2428.29, "word": " الحلقة", "probability": 0.97705078125}, {"start": 2428.29, "end": 2428.69, "word": " كيف", "probability": 0.953125}, {"start": 2428.69, "end": 2428.93, "word": " بده", "probability": 0.951171875}, {"start": 2428.93, "end": 2429.45, "word": " ييجي", "probability": 0.9849853515625}, {"start": 2429.45, "end": 2431.13, "word": " زي", "probability": 0.869384765625}, {"start": 2431.13, "end": 2431.27, "word": " ال", "probability": 0.978515625}, {"start": 2431.27, "end": 2432.07, "word": " aldehyde", "probability": 0.7794189453125}, {"start": 2432.07, "end": 2434.53, "word": " ال", "probability": 0.95947265625}, {"start": 2434.53, "end": 2434.95, "word": " acid", "probability": 0.986328125}, {"start": 2434.95, "end": 2435.17, "word": " لو", "probability": 0.9921875}, {"start": 2435.17, "end": 2435.39, "word": " بده", "probability": 0.966796875}, {"start": 2435.39, "end": 2435.55, "word": " ييجي", "probability": 0.908203125}, {"start": 2435.55, "end": 2435.67, "word": " على", "probability": 0.8935546875}, {"start": 2435.67, "end": 2436.01, "word": " الحلقة", "probability": 0.9874674479166666}, {"start": 2436.01, "end": 2436.23, "word": " بده", "probability": 0.9013671875}, {"start": 2436.23, "end": 2436.37, "word": " ييجي", "probability": 0.947998046875}, {"start": 2436.37, "end": 2436.67, "word": " كله", "probability": 0.856201171875}, {"start": 2436.67, "end": 2437.15, "word": " معلج", "probability": 0.8224283854166666}, {"start": 2437.15, "end": 2437.35, "word": " على", "probability": 0.8994140625}, {"start": 2437.35, "end": 2438.01, "word": " الحلقة", "probability": 0.9869791666666666}], "temperature": 1.0}, {"id": 103, "seek": 246330, "start": 2442.74, "end": 2463.3, "text": "ماقدرش أحطه على نفس الحلقة الأكسجينة المتصلة ولذلك لما بدي أسميه بدي أسميه بشكل موازن لنظام ال الديهايد إيش وجدت حاجة أقول عنه؟ Cyclo .. بنتين .. Carboxylic acid كمان Carboxylic acid", "tokens": [15042, 28543, 2288, 8592, 5551, 5016, 9566, 3224, 15844, 8717, 36178, 21542, 1211, 28671, 16247, 4117, 3794, 7435, 9957, 3660, 9673, 2655, 36520, 3660, 35525, 8848, 23275, 5296, 15042, 4724, 16254, 5551, 38251, 1829, 3224, 4724, 16254, 5551, 38251, 1829, 3224, 4724, 8592, 28820, 3714, 2407, 31377, 1863, 5296, 1863, 19913, 10943, 2423, 2423, 16254, 11296, 25708, 11933, 1829, 8592, 49610, 3215, 2655, 11331, 26108, 3660, 5551, 39648, 18871, 3224, 22807, 10295, 66, 752, 4386, 4724, 29399, 9957, 4386, 2741, 4995, 88, 1050, 8258, 9122, 2304, 7649, 2741, 4995, 88, 1050, 8258], "avg_logprob": -0.23655914234858688, "compression_ratio": 1.5336787564766838, "no_speech_prob": 0.0, "words": [{"start": 2442.74, "end": 2443.26, "word": "ماقدرش", "probability": 0.74261474609375}, {"start": 2443.26, "end": 2443.6, "word": " أحطه", "probability": 0.8751220703125}, {"start": 2443.6, "end": 2443.74, "word": " على", "probability": 0.822265625}, {"start": 2443.74, "end": 2443.94, "word": " نفس", "probability": 0.9306640625}, {"start": 2443.94, "end": 2444.4, "word": " الحلقة", "probability": 0.9851888020833334}, {"start": 2444.4, "end": 2444.96, "word": " الأكسجينة", "probability": 0.8336588541666666}, {"start": 2444.96, "end": 2445.5, "word": " المتصلة", "probability": 0.9127197265625}, {"start": 2445.5, "end": 2446.2, "word": " ولذلك", "probability": 0.8663736979166666}, {"start": 2446.2, "end": 2446.4, "word": " لما", "probability": 0.915771484375}, {"start": 2446.4, "end": 2446.62, "word": " بدي", "probability": 0.752197265625}, {"start": 2446.62, "end": 2447.28, "word": " أسميه", "probability": 0.92822265625}, {"start": 2447.28, "end": 2447.66, "word": " بدي", "probability": 0.7734375}, {"start": 2447.66, "end": 2448.14, "word": " أسميه", "probability": 0.9786376953125}, {"start": 2448.14, "end": 2448.64, "word": " بشكل", "probability": 0.99169921875}, {"start": 2448.64, "end": 2449.18, "word": " موازن", "probability": 0.93212890625}, {"start": 2449.18, "end": 2449.68, "word": " لنظام", "probability": 0.882568359375}, {"start": 2449.68, "end": 2449.82, "word": " ال", "probability": 0.70947265625}, {"start": 2449.82, "end": 2451.24, "word": " الديهايد", "probability": 0.6644287109375}, {"start": 2451.24, "end": 2452.4, "word": " إيش", "probability": 0.7183430989583334}, {"start": 2452.4, "end": 2452.72, "word": " وجدت", "probability": 0.6455078125}, {"start": 2452.72, "end": 2452.9, "word": " حاجة", "probability": 0.7081705729166666}, {"start": 2452.9, "end": 2453.0, "word": " أقول", "probability": 0.876953125}, {"start": 2453.0, "end": 2453.62, "word": " عنه؟", "probability": 0.8536783854166666}, {"start": 2453.62, "end": 2455.08, "word": " Cyclo", "probability": 0.6306966145833334}, {"start": 2455.08, "end": 2455.4, "word": " ..", "probability": 0.1573486328125}, {"start": 2455.4, "end": 2456.7, "word": " بنتين", "probability": 0.799072265625}, {"start": 2456.7, "end": 2457.68, "word": " ..", "probability": 0.59912109375}, {"start": 2457.68, "end": 2458.66, "word": " Carboxylic", "probability": 0.7337646484375}, {"start": 2458.66, "end": 2459.04, "word": " acid", "probability": 0.56201171875}, {"start": 2459.04, "end": 2459.46, "word": " كمان", "probability": 0.9578450520833334}, {"start": 2459.46, "end": 2461.76, "word": " Carboxylic", "probability": 0.8741455078125}, {"start": 2461.76, "end": 2463.3, "word": " acid", "probability": 0.822265625}], "temperature": 1.0}, {"id": 104, "seek": 248996, "start": 2465.25, "end": 2489.97, "text": "شوفتوا كيف مقارنة الأمور بتيجي الكحول والكيتون بيجيوا مباشرة على الحلقة فبنقول cyclopentanol وcyclopentanol ال aldehyde لأ cyclopentane وcarb aldehyde ال acid cyclopentane وcarboxylic acid واضحة الفكرة وبهيك بننهي المحاضرة اليوم المرة اللي جاي بنستمر في موضوع التسمية وموضوع ال aldehydes", "tokens": [8592, 38688, 2655, 14407, 9122, 33911, 3714, 4587, 9640, 1863, 3660, 16247, 2304, 13063, 39894, 1829, 7435, 1829, 33251, 5016, 12610, 16070, 4117, 36081, 11536, 4724, 1829, 7435, 1829, 14407, 3714, 3555, 33599, 25720, 15844, 21542, 1211, 28671, 6156, 3555, 1863, 39648, 19474, 404, 317, 282, 401, 4032, 34080, 404, 317, 282, 401, 2423, 16798, 68, 3495, 1479, 5296, 10721, 19474, 404, 317, 1929, 4032, 6166, 65, 16798, 68, 3495, 1479, 2423, 8258, 19474, 404, 317, 1929, 4032, 6166, 4995, 88, 1050, 8258, 4032, 46958, 5016, 3660, 27188, 4117, 25720, 46599, 3224, 1829, 4117, 44945, 1863, 3224, 1829, 9673, 5016, 46958, 25720, 45595, 20498, 9673, 25720, 13672, 1829, 10874, 47302, 44945, 14851, 29973, 8978, 3714, 2407, 11242, 45367, 16712, 38251, 10632, 4032, 2304, 2407, 11242, 45367, 2423, 16798, 68, 3495, 14792], "avg_logprob": -0.23283617729038902, "compression_ratio": 1.8675213675213675, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2465.25, "end": 2465.73, "word": "شوفتوا", "probability": 0.5811767578125}, {"start": 2465.73, "end": 2465.93, "word": " كيف", "probability": 0.919677734375}, {"start": 2465.93, "end": 2466.67, "word": " مقارنة", "probability": 0.94794921875}, {"start": 2466.67, "end": 2467.19, "word": " الأمور", "probability": 0.91455078125}, {"start": 2467.19, "end": 2467.73, "word": " بتيجي", "probability": 0.8502197265625}, {"start": 2467.73, "end": 2468.63, "word": " الكحول", "probability": 0.8728841145833334}, {"start": 2468.63, "end": 2469.15, "word": " والكيتون", "probability": 0.744384765625}, {"start": 2469.15, "end": 2469.43, "word": " بيجيوا", "probability": 0.856640625}, {"start": 2469.43, "end": 2469.95, "word": " مباشرة", "probability": 0.9830322265625}, {"start": 2469.95, "end": 2470.07, "word": " على", "probability": 0.66748046875}, {"start": 2470.07, "end": 2470.47, "word": " الحلقة", "probability": 0.9856770833333334}, {"start": 2470.47, "end": 2470.87, "word": " فبنقول", "probability": 0.7342529296875}, {"start": 2470.87, "end": 2471.75, "word": " cyclopentanol", "probability": 0.75693359375}, {"start": 2471.75, "end": 2472.69, "word": " وcyclopentanol", "probability": 0.7860107421875}, {"start": 2472.69, "end": 2473.21, "word": " ال", "probability": 0.52197265625}, {"start": 2473.21, "end": 2473.69, "word": " aldehyde", "probability": 0.6895751953125}, {"start": 2473.69, "end": 2473.93, "word": " لأ", "probability": 0.951904296875}, {"start": 2473.93, "end": 2475.25, "word": " cyclopentane", "probability": 0.845947265625}, {"start": 2475.25, "end": 2476.09, "word": " وcarb", "probability": 0.3960774739583333}, {"start": 2476.09, "end": 2476.59, "word": " aldehyde", "probability": 0.83599853515625}, {"start": 2476.59, "end": 2476.95, "word": " ال", "probability": 0.826171875}, {"start": 2476.95, "end": 2477.29, "word": " acid", "probability": 0.89404296875}, {"start": 2477.29, "end": 2478.63, "word": " cyclopentane", "probability": 0.9287109375}, {"start": 2478.63, "end": 2480.01, "word": " وcarboxylic", "probability": 0.72568359375}, {"start": 2480.01, "end": 2480.67, "word": " acid", "probability": 0.96826171875}, {"start": 2480.67, "end": 2481.81, "word": " واضحة", "probability": 0.8563232421875}, {"start": 2481.81, "end": 2482.27, "word": " الفكرة", "probability": 0.98974609375}, {"start": 2482.27, "end": 2484.77, "word": " وبهيك", "probability": 0.730621337890625}, {"start": 2484.77, "end": 2485.47, "word": " بننهي", "probability": 0.71240234375}, {"start": 2485.47, "end": 2485.99, "word": " المحاضرة", "probability": 0.9737548828125}, {"start": 2485.99, "end": 2486.23, "word": " اليوم", "probability": 0.912109375}, {"start": 2486.23, "end": 2486.53, "word": " المرة", "probability": 0.919921875}, {"start": 2486.53, "end": 2486.65, "word": " اللي", "probability": 0.677490234375}, {"start": 2486.65, "end": 2486.81, "word": " جاي", "probability": 0.8671875}, {"start": 2486.81, "end": 2487.35, "word": " بنستمر", "probability": 0.89306640625}, {"start": 2487.35, "end": 2487.51, "word": " في", "probability": 0.9072265625}, {"start": 2487.51, "end": 2487.85, "word": " موضوع", "probability": 0.9644775390625}, {"start": 2487.85, "end": 2488.57, "word": " التسمية", "probability": 0.9708658854166666}, {"start": 2488.57, "end": 2489.35, "word": " وموضوع", "probability": 0.97548828125}, {"start": 2489.35, "end": 2489.47, "word": " ال", "probability": 0.96728515625}, {"start": 2489.47, "end": 2489.97, "word": " aldehydes", "probability": 0.8426513671875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2490.8045, "duration_after_vad": 2386.49187499999}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hQvSO3g5Za4.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hQvSO3g5Za4.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b69ac9a550ada58b74cccb6f541e7fe2d8e9dcb9
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hQvSO3g5Za4.srt
@@ -0,0 +1,1487 @@
+1
+00:00:19,490 --> 00:00:24,290
+بسم الله الرحمن الرحيم، المرة الماضية بدأنا في
+
+2
+00:00:24,290 --> 00:00:28,130
+موضوع الكاربوهيدرات، بدأنا في موضوع الكاربوهيدرات
+
+3
+00:00:28,130 --> 00:00:34,450
+وقلنا أنه مكون من الكربون و
+
+4
+00:00:34,450 --> 00:00:41,130
+... وبعدين طبعًا بدأنا في السكريات، قلنا السكريات
+
+5
+00:00:41,130 --> 00:00:45,030
+في النهاية هي ألدهيدات أو كيتونات لكن فيها
+
+6
+00:00:45,030 --> 00:00:48,670
+مجموعات هيدروكسيل كثيرة، بوليهيدروكسي ألدهيدات أو
+
+7
+00:00:48,670 --> 00:00:55,050
+بوليهيدروكسي كيتونات، طبعًا بسبب وجود المراكز الكيرالية
+
+8
+00:00:55,050 --> 00:01:00,910
+يصبح عندنا عدد الأيزومرات للصيغة الواحدة
+
+9
+00:01:00,910 --> 00:01:06,330
+كثير، وتدرّجنا طبعًا من أبسط مركب في مركز كيرالي واحد
+
+10
+00:01:06,330 --> 00:01:11,690
+الذي هو الغليسرول ألدهيد، ورسمناه بطرق
+
+11
+00:01:11,690 --> 00:01:22,940
+مختلفة، شفنا كيف المركبات هذه ممكن تكون D أو L في
+
+12
+00:01:22,940 --> 00:01:25,300
+المرحلة الأولى، ولو قلنا لو عندنا مركز كيرالي واحد
+
+13
+00:01:25,300 --> 00:01:30,540
+يصبح في عندنا مركّبين، بعد هيك قصة الـ D والـ L
+
+14
+00:01:30,540 --> 00:01:34,580
+بتستمر بزيادة المراكز الكيرالية و يبدأ العدد يزيد
+
+15
+00:01:34,580 --> 00:01:43,040
+فبناءً على ذلك، بناءً على ذلك، ففي موضوع
+
+16
+00:01:43,040 --> 00:01:46,140
+الـسكريات
+
+17
+00:01:47,420 --> 00:01:52,440
+قلنا أساسي جدًا أن نتطلع على المراكز الكيرالية ونتذكر
+
+18
+00:01:52,440 --> 00:01:55,620
+كل الكلام اللي حكيناه في المراكز الكيرالية في الفصل
+
+19
+00:01:55,620 --> 00:01:59,460
+الرابع، إذا عندنا مركز كيرالي واحد نتوقع مركّبين، مركزين كيراليين
+
+20
+00:01:59,460 --> 00:02:04,480
+نتوقع أربعة، وهكذا بدأنا بالتدريج
+
+21
+00:02:04,480 --> 00:02:09,980
+وآخر شيء انتهينا عنده احنا لما كان في عندنا ست
+
+22
+00:02:09,980 --> 00:02:17,870
+ذرات كربون، طبعًا لما يكون عندي ست ذرات كربون، على
+
+23
+00:02:17,870 --> 00:02:22,090
+حسب ما بنرسم إحنا السكر بالطريقة اللي اتعلّمناها،
+
+24
+00:02:22,090 --> 00:02:27,370
+الذرة الأولى من فوق ألدهيد، وبناءً على ذلك هذا ليس
+
+25
+00:02:27,370 --> 00:02:32,550
+مركزًا كيراليًا، والذرة الأخيرة من تحت CH2OH ليست
+
+26
+00:02:32,550 --> 00:02:36,970
+مركزًا كيراليًا، وإذا رسمنا الشكل اللي بنسميه
+
+27
+00:02:36,970 --> 00:02:42,950
+البنية اللا دورية، بيكون فيه كم أيزومر؟ كم
+
+28
+00:02:42,950 --> 00:02:50,800
+مركزًا كيراليًا؟ أربعة، بيقدروا إلى الآن، طالما أن السكر
+
+29
+00:02:50,800 --> 00:02:55,840
+عبارة عن كحول وألدهيد، لو جربنا نجعل الكحول
+
+30
+00:02:55,840 --> 00:03:00,640
+يسكر على الألدهيد، هيعمل مركزًا كيراليًا جديدًا، هيصير
+
+31
+00:03:00,640 --> 00:03:07,080
+عندنا خمسة مراكز كيرالية، وجدنا نتوقع أن سكرًا مكونًا
+
+32
+00:03:07,080 --> 00:03:11,460
+من ست ذرات كربون بهذا الشكل يكون عنده اثنين وثلاثين
+
+33
+00:03:11,460 --> 00:03:17,320
+أيزومرًا، طبعًا لما تمت عملية الإغلاق، لما تمت
+
+34
+00:03:17,320 --> 00:03:23,040
+عملية إغلاق الكحول على الألدهيد، بهذا الشكل
+
+35
+00:03:23,040 --> 00:03:28,100
+يكون عندي هنا المركز الكيرالي الجديد، وقلنا
+
+36
+00:03:28,100 --> 00:03:30,920
+الكربون هذه التي تعمل المركز الكيرالي الجديد، شو
+
+37
+00:03:30,920 --> 00:03:35,460
+بنسميها إحنا؟ كربون أنومري، الآن معنى مركز كيرالي
+
+38
+00:03:35,460 --> 00:03:40,060
+جديد أن الـ OH هذه بنسميها إما لأعلى وإما لأسفل
+
+39
+00:03:40,060 --> 00:03:44,460
+وقلنا إذا كانت لأسفل بنقول هذا ألفا، compound
+
+40
+00:03:44,460 --> 00:03:48,740
+وإذا كانت لأعلى بنقول هذا بيتا، الآن طالما أنه في
+
+41
+00:03:48,740 --> 00:03:52,560
+أربعة مراكز كيرالية كان عنده 16 مركب، كل واحد فيهم
+
+42
+00:03:52,560 --> 00:03:55,840
+لما بده يسكر بده يقسم ألفا بيتا، ألفا بيتا، معنا
+
+43
+00:03:55,840 --> 00:04:01,820
+ذلك المجموع صار إيش؟ 32 مركبًا، هذا تقريبًا آخر شيء
+
+44
+00:04:01,820 --> 00:04:08,390
+انتهينا فيه، الآن اللي بدي أنبه له، طيب الآن قلنا في
+
+45
+00:04:08,390 --> 00:04:15,210
+عندنا الشكل اللا دوري، وأشكال دورية،  لذا هذا السكر اللا
+
+46
+00:04:15,210 --> 00:04:21,450
+دوري، يترى بنسبة أي موجود عادة في المحلول، والـ
+
+47
+00:04:21,450 --> 00:04:26,860
+الدورية بنسبة أي موجودين في المحلول؟ الصحيح أن الـ
+
+48
+00:04:26,860 --> 00:04:33,080
+اللا دوري في محلول مائي يوجد بنسبة قليلة جدًا جدًا جدًا
+
+49
+00:04:33,080 --> 00:04:37,000
+يعني معظم السكر بينوجد على شكل حلقة، النسبة التي
+
+50
+00:04:37,000 --> 00:04:43,460
+بينوجد فيها اللا دوري في محلول مائي هي 0.003
+
+51
+00:04:43,460 --> 00:04:50,780
+ثلاثة من ألف، يعني أكاد يكون غير موجود، إذا
+
+52
+00:04:50,780 --> 00:04:57,310
+كأنه كل السكر، السكر واضح، كأنه كل السكر بيسكر، لما
+
+53
+00:04:57,310 --> 00:05:01,290
+نقول هذه النسبة قليلة جدًا التي يوجد فيها اللا دوري،
+
+54
+00:05:01,290 --> 00:05:05,630
+طيب، كل السكر بيسكر، بيسكر على إيش؟ ألفا و
+
+55
+00:05:05,630 --> 00:05:10,550
+بيتا، هل بيكونون بنفس النسبة؟ اتعودنا أو حكينا أنه
+
+56
+00:05:10,550 --> 00:05:16,930
+لا، بيكون البيتا بالمعدل حوالي 64%، والألفا حوالي 36%
+
+57
+00:05:16,930 --> 00:05:24,030
+أو هنا 35.5، يمكن هناك 64.5، وهنا 35.5، لو بدنا نسيب
+
+58
+00:05:24,030 --> 00:05:31,860
+شوية دقيقة، واضح؟ يمكن البعض يقول: طيب كيف قدرًا يفصلوا
+
+59
+00:05:31,860 --> 00:05:36,080
+هذا لوحده؟ يعني طالما أن هذا اتزان ما بين الألفا
+
+60
+00:05:36,080 --> 00:05:40,540
+والبيتا، يعني دائمًا المخلوط موجود فيه الاثنين، كيف
+
+61
+00:05:40,540 --> 00:05:43,940
+يتعرفوا على الألفا لحاله؟ إذا أنا بحط في المحلول
+
+62
+00:05:43,940 --> 00:05:48,560
+المائي، بينوجد الاثنان، الجواب: نعم، في المحلول المائي
+
+63
+00:05:48,560 --> 00:05:53,160
+بينوجدان الاثنان، فعلاً، لكن لو عملنا للمركب
+
+64
+00:05:53,160 --> 00:05:59,460
+بلورة من محلول الميثانول فقط، بيطلع
+
+65
+00:05:59,460 --> 00:06:04,300
+عند الألفا نقي، يعني أنا في غير الماء أقدر أحصل
+
+66
+00:06:04,300 --> 00:06:10,400
+على الألفا نقي، الألفا النقي، أين أشوفه؟
+
+67
+00:06:10,400 --> 00:06:15,440
+بمحلول إيش؟ الميثانول، فلو عملنا بلورة
+
+68
+00:06:15,440 --> 00:06:19,180
+للسكر هذا الجلوكوز بمحلول الميثانول، آخذ الألفا
+
+69
+00:06:19,180 --> 00:06:23,320
+لوحده، واضحة الفكرة؟ الآن لو عملت
+
+70
+00:06:23,320 --> 00:06:30,020
+بلورة بالحمض الخليك، أحصل على البيتا
+
+71
+00:06:30,020 --> 00:06:38,760
+لوحده، فقط، إيش؟ البيتا النقي، واضح؟ الآن لو
+
+72
+00:06:38,760 --> 00:06:42,760
+أجيت أخذت، أنا صار في عندي ألفا نقي، يعني صار في
+
+73
+00:06:42,760 --> 00:06:47,100
+عندي زجاجة في ألفا نقي، زجاجة ثانية في بيتا نقي، الألفا
+
+74
+00:06:47,100 --> 00:06:51,590
+النقي من أين آخذه؟ من خلال الميثانول، البيتا
+
+75
+00:06:51,590 --> 00:06:55,910
+النقي من الحمض الخليك، الآن لو جبت الألفا النقي
+
+76
+00:06:55,910 --> 00:07:01,750
+حطيته في الماء، في محلول الماء، بيصير يعمل التحول
+
+77
+00:07:01,750 --> 00:07:05,730
+للا دوري ويرجع يسكر ألفا بيتا إلى أن يصل إلى
+
+78
+00:07:05,730 --> 00:07:10,410
+الاتزان الذي اتفقنا عليه، 36% و64%، فهذا الاتزان
+
+79
+00:07:10,410 --> 00:07:16,370
+أين يكون موجودًا؟ في المحلول المائي،
+
+80
+00:07:16,370 --> 00:07:21,370
+المائي، لو بدأت بالألفا النقي سيصل لهذا الاتزان، و
+
+81
+00:07:21,370 --> 00:07:26,730
+لو بدأت بالبيتا النقي أيضًا سيصل لهذا الاتزان، واضح؟
+
+82
+00:07:26,730 --> 00:07:31,510
+إذا بالإمكان أن أنا أفصل ألفا نقي بمذيب غير
+
+83
+00:07:31,510 --> 00:07:35,870
+الماء، وبيتا نقي بمذيب غير الماء، لكن في الماء
+
+84
+00:07:35,870 --> 00:07:41,270
+لو بدأت بأي واحد، فسيحصل الاتزان الذي هو بين ألفا
+
+85
+00:07:41,270 --> 00:07:48,250
+وبيتا بنسبة 36 إلى 64، هذا الكلام يعني شغلة، يعني أن
+
+86
+00:07:48,250 --> 00:07:53,770
+أيّ منهما أكثر ثباتًا؟ الألفا أم البيتا؟ البيتا،
+
+87
+00:07:53,770 --> 00:07:58,870
+الذي يوجد بنسبة أكبر هو الذي يكون أكثر ثباتًا،
+
+88
+00:07:58,870 --> 00:08:01,490
+واضحة هذه الفكرة؟
+
+89
+00:08:05,630 --> 00:08:10,350
+بعد هيك بدنا ننتبه لنقطة أنه لما يتم الإغلاق، الـ
+
+90
+00:08:10,350 --> 00:08:15,130
+ألدهيد، مجموعة واحدة، ليس موضوع خلاف، لكن الـ OHs
+
+91
+00:08:17,200 --> 00:08:25,520
+الأخرى، زي ما تكلمنا، هذه الـ OH ممكن تسكرها، وإغلاق
+
+92
+00:08:25,520 --> 00:08:29,580
+أي OH يعطي حلقة بحجم مختلف، يعني لو أغلقت من هنا
+
+93
+00:08:29,580 --> 00:08:35,060
+ستكون حلقة ثلاثية، لو هيك سكرت رباعية، لو هذه سكرت
+
+94
+00:08:35,060 --> 00:08:40,980
+خماسية، هذه التي سُكرت سداسية، هذه سبعية، هل يترى
+
+95
+00:08:40,980 --> 00:08:47,530
+ممكن أن يتم إغلاقات لغير الحلقة السداسية؟ الذي
+
+96
+00:08:47,530 --> 00:08:53,130
+مشهور، حقيقة، أنه يتم إغلاق من الـ OH الموجودة هنا
+
+97
+00:08:53,130 --> 00:08:59,730
+ويعطيني حلقة خماسية، لكن كم نسبة السكر التي
+
+98
+00:08:59,730 --> 00:09:05,970
+يكون كحلقة خماسية؟ 1%، يعني لاحظوا لو
+
+99
+00:09:05,970 --> 00:09:09,930
+أنا بدي آجي على المحلول بالمجمل، أقول في عندي 1%
+
+100
+00:09:09,930 --> 00:09:15,870
+حلقة خماسية، في عندي 0.3% إيش؟
+
+101
+00:09:15,870 --> 00:09:23,200
+لادوري، والباقي حلقة سداسية، بتكون النسبة بين
+
+102
+00:09:23,200 --> 00:09:31,200
+مكوناتها 64% إلى 36%، واضح؟ فالمحلول سيكون فيه أكثر من
+
+103
+00:09:31,200 --> 00:09:36,100
+شغلة، سيكون فيه محلول الجلوكوز اللا دوري بنسبة
+
+104
+00:09:36,770 --> 00:09:43,010
+3/1000، المسكر على حلقة خماسية بيكون بنسبة
+
+105
+00:09:43,010 --> 00:09:46,370
+1%، الآن الباقي، الذي هو 99%
+
+106
+00:09:46,370 --> 00:09:51,050
+كيف بتكون مقسومة؟ 64% منها بيتا، 36% منها ألفا، واضحة الفكرة؟
+
+107
+00:09:51,050 --> 00:09:55,410
+بيتا، 36% منها ألفا، واضحة الفكرة؟
+
+108
+00:10:01,460 --> 00:10:06,660
+طبعًا إحنا قلنا كلمة، ووضحناها المرة الماضية، أن الـ
+
+109
+00:10:06,660 --> 00:10:10,860
+بيتا أكثر ثباتًا من الألفا، لأن لو رسمنا
+
+110
+00:10:10,860 --> 00:10:14,920
+الحلقة السداسية على الشكل الذي عادةً بتكون موجودة
+
+111
+00:10:14,920 --> 00:10:18,420
+فيه، ويمكن مر علينا لما أخذنا الحلقات السداسية
+
+112
+00:10:18,420 --> 00:10:21,140
+نقطتين، يوجد على شكل "both"
+
+113
+00:10:23,360 --> 00:10:27,920
+أو كرسي، والذي هو أكثر ثباتًا،  تشكيل كرسي
+
+114
+00:10:27,920 --> 00:10:31,620
+الآن لو حطيتها على هيئة الكرسي، في التشكل الكرسي
+
+115
+00:10:31,620 --> 00:10:37,480
+ممكن أن تكون الـ OH بشكل أفقي بهذا الشكل
+
+116
+00:10:37,480 --> 00:10:43,460
+بنقول عنها استوائية، استوائية، يعني بشكل أفقي،
+
+117
+00:10:43,460 --> 00:10:48,040
+يعني لما نتخيل أن الشكل العام للحلقات بهذا الشكل
+
+118
+00:10:48,040 --> 00:10:55,070
+هي بتكون زي هيك، هذه استوائية، الآن ممكن تكون في
+
+119
+00:10:55,070 --> 00:11:01,830
+شكل آخر، محوري، رأسي عمودي، هيك استوائية، هيك محوري
+
+120
+00:11:01,830 --> 00:11:09,740
+الآن بهذا الشكل بتكون إيش؟ محورية، طبعًا الـ
+
+121
+00:11:09,740 --> 00:11:13,820
+استوائية، الفراغ المحيط بها أفضل من الفراغ المحيط
+
+122
+00:11:13,820 --> 00:11:18,180
+بالمحورية، المحورية مكتظة، لاحظوا فيها
+
+123
+00:11:18,180 --> 00:11:21,600
+عائق فراغي، ليست واسعة،
+
+124
+00:11:21,600 --> 00:11:26,840
+واضح؟ الاستوائية مترايحة أكثر، ولذلك هذا الشكل الـ
+
+125
+00:11:26,840 --> 00:11:31,200
+استوائي هو البيتا، هذا الشكل المحوري هو الـ
+
+126
+00:11:31,200 --> 00:11:35,900
+ألفا، لذلك البيتا يكون أكثر ثباتًا لأن الـ OH
+
+127
+00:11:35,900 --> 00:11:39,820
+الموجودة فيه، الكربون الأنمري،
+
+128
+00:11:39,820 --> 00:11:43,860
+تكون مترايحة من الناحية الفراغية، ما في حد مضايقها
+
+129
+00:11:43,860 --> 00:11:48,440
+واضح؟ لاحظوا هذه الـ OH الجديدة التي تكونت عندي، الآن
+
+130
+00:11:48,440 --> 00:11:52,740
+في الشكل الاستوائي هي مترايحة، في الشكل المحوري
+
+131
+00:11:52,740 --> 00:11:57,160
+ليست مترايحة، في جنبها مجموعات أخرى تعمل ازدحامًا
+
+132
+00:11:57,160 --> 00:12:02,240
+فراغيًا، فلما نكون بدنا نفسر لماذا البيتا موجودة أكثر
+
+133
+00:12:02,240 --> 00:12:08,020
+من الألفا، نقول: لأن البيتا OH توجد في
+
+134
+00:12:08,020 --> 00:12:13,140
+الموضع الاستوائي، لأنها موجودة في الـ
+
+135
+00:12:13,140 --> 00:12:16,960
+استوائي،  الاستوائي ليس موضعًا مكتظًا
+
+136
+00:12:17,870 --> 00:12:24,070
+واضح؟ فسبب الثبات للبيتا أن الـ OH الجديدة هذه
+
+137
+00:12:24,070 --> 00:12:28,650
+التي تكونت عندي هنا لو رسمت الشكل على هيئة الكرسي
+
+138
+00:12:28,650 --> 00:12:32,330
+تكون موجودة أين؟ في المحوري أم في الـ
+
+139
+00:12:32,330 --> 00:12:36,070
+استوائي؟ في الاستوائي، الاستوائي ليس
+
+140
+00:12:36,070 --> 00:12:39,350
+جزيءًا معوقًا فراغيًا،
+
+141
+00:12:41,870 --> 00:12:44,730
+طبعًا التغير في الدوران، حكينا عنه أيضًا المرة
+
+142
+00:12:44,730 --> 00:12:49,450
+الماضية، قلنا لو بدأنا من أي واحد، سيصل لإيش؟
+
+143
+00:12:49,450 --> 00:12:50,310
+للاتزان،
+
+144
+00:12:52,690 --> 00:12:57,850
+البيورانوز والفيورانوز، البنية بسيطة
+
+145
+00:12:57,850 --> 00:13:02,650
+فيها أن إحنا قلنا السكر أشهر إغلاقات تبعه إما
+
+146
+00:13:02,650 --> 00:13:08,630
+على حلقة سداسية أو على حلقة خماسية، الآن في الـ
+
+147
+00:13:08,630 --> 00:13:12,610
+كيمياء الدورات غير المتجانسة، الحلقة السداسية التي فيها
+
+148
+00:13:12,610 --> 00:13:18,190
+الأكسجين بهذا الشكل اسمها بيوران، واضح؟ هذه الحلقة
+
+149
+00:13:18,190 --> 00:13:22,910
+التي فيها الأكسجين اسمها بيوران، والحلقة الخماسية
+
+150
+00:13:22,910 --> 00:13:28,290
+التي فيها الأكسجين اسمها إيش؟ فيوران، بناءً على ذلك
+
+151
+00:13:28,290 --> 00:13:33,530
+السكر لما بيسكر على حلقة سداسية صاروا ينسبوا للـ
+
+152
+00:13:33,530 --> 00:13:37,290
+بيوران، فكل السكريات التي مسكرة على حلقة سداسية
+
+153
+00:13:37,290 --> 00:13:42,190
+بيصيروا يقولوا عنها بيورانوزات، بيورانوزات يعني مسكر
+
+154
+00:13:42,190 --> 00:13:46,210
+على حلقة سداسية، لما بيشوف بيوران، بدي أقول أن الحلقة
+
+155
+00:13:46,740 --> 00:13:53,340
+لو كانت مسكرة على حلقة خماسية، نسبةً للفيوران
+
+156
+00:13:53,340 --> 00:13:58,360
+الخماسي أقول عنه إيش؟ فيرانوز، فبنصير من الآن
+
+157
+00:13:58,360 --> 00:14:01,700
+نستعمل كلمتين جديدتين، أنه لما نحكي عن الحلقة
+
+158
+00:14:01,700 --> 00:14:07,020
+السداسية نستعمل كلمة بيورانوز، فالجلوكوز الذي
+
+159
+00:14:07,020 --> 00:14:12,620
+مسكر على حلقة سداسية الآن بيقولوا عنه جلوكوبيرانوز
+
+160
+00:14:13,420 --> 00:14:17,300
+معنى جلوكوبيرانوز أنه جلوكوز مسكر على حلقة
+
+161
+00:14:17,300 --> 00:14:23,400
+سداسية، طب لو سكر على حلقة خماسية جلوكوفورانوز، فمن
+
+162
+00:14:23,400 --> 00:14:28,200
+الآن وطالع، سنصير نشوف اسمين: جلوكوبيرانوز و
+
+163
+00:14:28,200 --> 00:14:32,320
+جلوكوفورانوز، لما نقول لشخص إيش يعني جلوكوبيرانوز؟
+
+164
+00:14:33,530 --> 00:14:40,490
+جلوكوز مسكر على حلقة سداسية، إيش معناه؟ جلوكوز
+
+165
+00:14:40,490 --> 00:14:42,830
+مسكر على حلقة خماسية، جلوكوز مسكر على حلقة خماسية،
+
+166
+00:14:42,830 --> 00:14:42,870
+جلوكوز مسكر على حلقة خماسية، جلوكوز مسكر على حلقة
+
+167
+00:14:42,870 --> 00:14:43,730
+خماسية، جلوكوز مسكر على حلقة خماسية، جلوكوز مسكر
+
+168
+00:14:43,730 --> 00:14:44,790
+على حلقة خماسية، جلوكوز مسكر على
+
+223
+00:19:37,060 --> 00:19:43,280
+alcohol with anhydrides produces كلمة واحدة: أستر
+
+224
+00:19:43,280 --> 00:19:50,340
+أستر الناس اللي بيدرسوا الكيمياء ينتبهوا، كلمة سهلة جدا لما
+
+225
+00:19:50,340 --> 00:19:54,580
+أخدنا تفاعل الكحول مع الـ acids بيعطينا أستر، مع الـ
+
+226
+00:19:54,580 --> 00:19:59,690
+acid chloride بيعطينا أستر، مع الـ anhydride بيعطينا
+
+227
+00:19:59,690 --> 00:20:03,310
+إستر، مظبوط ولا لأ؟ طب لو بدنا نفعل الكحول مع الـ
+
+228
+00:20:03,310 --> 00:20:08,510
+إستر، شو بيعطينا؟
+
+229
+00:20:08,510 --> 00:20:15,450
+كحول
+
+230
+00:20:15,450 --> 00:20:20,330
+مع إستر كحول
+
+231
+00:20:20,330 --> 00:20:30,950
+مع إستر إيش رأيكم؟ إستر طبعاً يبدأ من جديد، من
+
+232
+00:20:30,950 --> 00:20:34,710
+الـ سير الإنسان في العملية transesterification لأن
+
+233
+00:20:34,710 --> 00:20:41,750
+متابعتكم ضعيفة شوية في الموضوع اللي أخدناه سابقاً، و
+
+234
+00:20:41,750 --> 00:20:47,210
+اللي إحنا محتاجينه، مضطر إني أعمل شوية، إيش شوية
+
+235
+00:20:47,210 --> 00:20:48,250
+مراجعة معكم
+
+236
+00:20:50,980 --> 00:20:59,460
+نعمل شوية مراجعة، هي نحط كحول ميثانول كويس، و
+
+237
+00:20:59,460 --> 00:21:01,320
+نعمله بأي لون الميثانول
+
+238
+00:21:04,970 --> 00:21:11,590
+CH3OH زائد نفّعلوه مع أيّ حمض؟ إيه صيغة الحمض؟ أي حمض
+
+239
+00:21:11,590 --> 00:21:17,070
+ناخد الـ بنزويك أسيد، الـ بنزويك أسيد، فنول C=O
+
+240
+00:21:17,070 --> 00:21:23,330
+OH نفّعلوه مع الـ بنزويل كلوريد، الحمض كلوريد فنول
+
+241
+00:21:23,330 --> 00:21:31,340
+C=O Cl نفّعلوه مع الـ بنزويك أنهيدرايد
+
+242
+00:21:31,340 --> 00:21:38,900
+فنول C=O O C=O فنول نفّعلوه
+
+243
+00:21:38,900 --> 00:21:46,680
+كمان مع الإيثيل بنزوآت، فنول C=O O إيثيلي
+
+244
+00:21:46,680 --> 00:21:50,860
+الكحول بتفعل مع الحمض أو مع الـ acid chloride أو مع الـ
+
+245
+00:21:50,860 --> 00:21:55,600
+acid anhydride أو حتى مع الـ Ester، الهدف بده
+
+246
+00:21:55,600 --> 00:22:01,340
+يعطيني في كل الأحوال هو تفاعل واحد إحلال، هذه بده
+
+247
+00:22:01,340 --> 00:22:09,200
+تخرج، يجي بدالها مثل هذه، لين يفعل اللي بده يهاجمه، و
+
+248
+00:22:09,200 --> 00:22:16,980
+هذه تخرج، هذه بده تخرج، هذه بده تخرج، بناءً على ذلك
+
+249
+00:22:16,980 --> 00:22:23,660
+الناتج من كل هدول هيكون نفس الإستر اللي هو
+
+250
+00:22:23,660 --> 00:22:30,220
+Phenyl C=O O Methyl بدل المجموعة
+
+251
+00:22:30,220 --> 00:22:34,440
+المغادرة هذه، الآن بعد ذلك أنه هنا بيطلع H مع الـ OH
+
+252
+00:22:34,440 --> 00:22:39,340
+زائد ماء زائد HCl زائد Benzoic acid زائد Ethanol
+
+253
+00:22:39,340 --> 00:22:45,200
+مش مشكلة، تفاعل الكحول مع أي واحد من الأحماض
+
+254
+00:22:45,200 --> 00:22:50,040
+ومشتقاتها بيعطيني إيش؟ إستر، كحول مع حمض، كحول مع
+
+255
+00:22:50,040 --> 00:22:53,600
+حمض كلوريد، كحول مع أنهيدرايد، كحول مع إستر،
+
+256
+00:22:53,600 --> 00:22:59,050
+يمكن أنا أقول لكم، يا الله، إستر أعطى إستر ثاني، آه
+
+257
+00:22:59,050 --> 00:23:04,630
+بس هذا الإستر كان Phenyl C=O O Ethyl
+
+258
+00:23:04,630 --> 00:23:11,370
+صار Phenyl C=O O Methyl، إذا بدّلنا الإستر
+
+259
+00:23:11,370 --> 00:23:17,010
+ولا لأ؟ عشان هيك بنسميه الـ Transesterification، إيش
+
+260
+00:23:17,010 --> 00:23:22,610
+يعني الـ Trans؟ تحويل، بتعرفوا Trans الكهرباء كيف
+
+261
+00:23:22,610 --> 00:23:27,910
+بيحول؟ بتعرفوا معناه Transformation؟ بتعرفوا كلمة
+
+262
+00:23:27,910 --> 00:23:33,390
+Transport، أنه بنقل البني… آه، فـ Trans لما
+
+263
+00:23:33,390 --> 00:23:37,550
+بتيجي لكم في أول الكلام، شو معناها؟ تحويل، الآن كان
+
+264
+00:23:37,550 --> 00:23:42,210
+الإستر، C=O، O-ethyl، خلى الإستر،
+
+265
+00:23:42,210 --> 00:23:47,930
+C=O، O-methyl، فالكحول مع إستر بيبدّل،
+
+266
+00:23:47,930 --> 00:23:52,270
+بيعمل Transesterification، بدل ما كان O-ethyl صار O
+
+267
+00:23:52,270 --> 00:23:55,250
+-methyl، هذه العملية شو بنسميها اللي هنا؟
+
+268
+00:24:02,320 --> 00:24:05,640
+Transesterification، واضحة الفكرة؟ إذا ما بدّكم
+
+269
+00:24:05,640 --> 00:24:10,000
+تتغلّبوني، لما أقول لكم الكحول مع الـ acid chloride، و
+
+270
+00:24:10,000 --> 00:24:14,040
+لا مع الـ anhydride، شو بده يعطيني؟ شو بده يعطي
+
+271
+00:24:14,040 --> 00:24:19,880
+الكحول مع الـ anhydride؟ إستر، واضح؟ و مع الـ
+
+272
+00:24:19,880 --> 00:24:25,230
+chloride إستر؟ مع كلّهم إستر… الآن إذا الكلام
+
+273
+00:24:25,230 --> 00:24:31,790
+هذا كله صار واضح عندكم، بدّي أجي أرجع للسكر، السكر
+
+274
+00:24:31,790 --> 00:24:40,010
+اللي مسكّر، عبارة عن كحول، الـ sugar عبارة عن كحول، هذا
+
+275
+00:24:40,010 --> 00:24:45,230
+الكحول لو فعلته مع الـ anhydride شو هيعطيني؟ إستر
+
+276
+00:24:45,230 --> 00:24:54,480
+كل OH بده تصير… هذه الـ OH تهاجم هنا، O CH3، اعمل
+
+277
+00:24:54,480 --> 00:25:00,260
+واحدة منهم، واضحة، O CH3، الآن الـ C=O
+
+278
+00:25:00,260 --> 00:25:05,680
+CH3، شو أخدنا اسمها؟ الـ Acetyl group، فالخمسة OH
+
+279
+00:25:05,680 --> 00:25:10,140
+بيصيروا كلهم O Acetyl، طبعاً تطلعوا معي، هذا إستر
+
+280
+00:25:10,140 --> 00:25:19,280
+ولا لأ؟ R C=O OR، إستر، فالسكر مع الـ
+
+281
+00:25:19,280 --> 00:25:24,100
+أنهيدرايد بيعطيني إستر، طيب لو جبنالكم السؤال
+
+282
+00:25:24,100 --> 00:25:26,940
+قلنا لكم، طب لو فعلنا الـ sugar مع الـ acid
+
+283
+00:25:26,940 --> 00:25:31,060
+chloride، برضه إستر، برضه إستر، المهم أنه في…
+
+284
+00:25:31,060 --> 00:25:37,820
+…طب لو فعلنا مع الـ… مع إستر، برضه إستر ثاني،
+
+285
+00:25:38,910 --> 00:25:42,570
+نفس المثال اللي هناك، هذا الكلام إذا ما بتتدرّبوا عليه
+
+286
+00:25:42,570 --> 00:25:47,430
+ما بتقنوه، الخمسة OHs كلهم اللي موجودين
+
+287
+00:25:47,430 --> 00:25:52,790
+بيصيروا إستر، اثنين، ثلاثة، أربعة، خمسة، فتفاعل الـ
+
+288
+00:25:52,790 --> 00:25:58,070
+sugar مع الـ acid anhydride بيعطيني إستر، خلّصنا
+
+289
+00:25:58,070 --> 00:26:04,170
+من هذه النقطة؟ كويس، لاحظوا كده، بتفيدني الكيمياء
+
+290
+00:26:04,170 --> 00:26:10,900
+العادية وهي مقدمة إيش؟ الـ biochemistry، يعني مش ممكن
+
+291
+00:26:10,900 --> 00:26:14,100
+حد يجي يدرس biochemistry ونشرح له هذا التفاعل وهو
+
+292
+00:26:14,100 --> 00:26:17,500
+مش عارف الكحول، و الـ anhydride، و الـ ester، و كيف
+
+293
+00:26:17,500 --> 00:26:21,500
+بتفاعلوا مع بعض ومع بعض، فكل تفاعل بيمرّ بمرحلة
+
+294
+00:26:21,500 --> 00:26:27,930
+عشان تفهمه بسهولة، لازم يكون المخ يرجع وين؟ للـ
+
+295
+00:26:27,930 --> 00:26:31,630
+Organic Chemistry العادية اللي إستعملته فيها هو
+
+296
+00:26:31,630 --> 00:26:35,910
+اللي بيرجع يمرّ علينا هنا، يعني لو مثلاً أخدنا هذا
+
+297
+00:26:35,910 --> 00:26:49,170
+التفاعل ROH زائد CH3I، هاي التفاعل العادي Alkyl
+
+298
+00:26:49,170 --> 00:26:49,790
+Halide
+
+299
+00:26:52,600 --> 00:26:55,880
+النيوكليوفيل إيش بيعمل؟ النيوكليوفيل بالـ alkyl
+
+300
+00:26:55,880 --> 00:27:04,160
+الهاليد؟ هذا الجزء إيش؟ بيهاجر، بيحل محلّ و
+
+301
+00:27:04,160 --> 00:27:08,460
+النيوترال، النيوكليوفيل اللي بيفقد؟ H، إذا هنا إيش
+
+302
+00:27:08,460 --> 00:27:16,980
+بده يصير عندكم؟ ROCH3، إذا كحول مع الـ alkyl
+
+303
+00:27:16,980 --> 00:27:19,500
+الهاليد، شو بيعطيني؟ إيثر
+
+304
+00:27:22,220 --> 00:27:30,660
+ROR، Ether، الآن الـ sugar عبارة عن كحول ولا خمس
+
+305
+00:27:30,660 --> 00:27:34,940
+كحولات في بعض؟ خمس كحولات، نفّعلوه مع الميثيل Iodide
+
+306
+00:27:35,670 --> 00:27:41,650
+هيعطيني كم إيثر؟ خمس إيثرات، ميثيل أو كربون، ميثيل أو
+
+307
+00:27:41,650 --> 00:27:45,070
+كربون، ميثيل أو كربون، ميثيل أو كربون، ميثيل أو كربون،
+
+308
+00:27:45,070 --> 00:27:49,570
+واضحة الفكرة؟ هو نفس هذا التفاعل البسيط، أن الكحول
+
+309
+00:27:49,570 --> 00:27:55,450
+بيحل محل اليود، ولذلك ملخّص هدول الاثنين أن الكحول
+
+310
+00:27:55,450 --> 00:28:00,950
+مع الأنهايدريد بيعطيني إستر للسكر، والكحول مع الميثيل
+
+311
+00:28:00,950 --> 00:28:07,890
+أيودايد بيعطيني إيثر للسكر، وطالما أنه موجود من
+
+312
+00:28:07,890 --> 00:28:12,230
+الكحول خمس مجموعات، إذا كم إستر وكم إيثر هيتكون
+
+313
+00:28:12,230 --> 00:28:20,020
+عندي؟ إذا بعد ما أخدنا تفاعل السكر بصفته Alcohol مع الـ
+
+314
+00:28:20,020 --> 00:28:23,620
+anhydride، قلنا بيعطي إستر، مع الـ alkyl halide
+
+315
+00:28:23,620 --> 00:28:27,800
+زي الميثيل iodide، قلنا بيعطي إيثر، بدنا ناخد
+
+316
+00:28:27,800 --> 00:28:33,380
+تفاعل ثاني للسكر أيضاً، مرّ علينا هذا التفاعل، لو
+
+317
+00:28:33,380 --> 00:28:38,500
+إجينا بدنا نعمل Reduction للسكر، هنحتاج جملة من
+
+318
+00:28:38,500 --> 00:28:43,420
+الكيمياء القديمة، نقول Reduction of aldehyde
+
+319
+00:28:43,420 --> 00:28:49,910
+produces إيش؟ primary alcohol، تمام؟ هتقولوا هو الـ
+
+320
+00:28:49,910 --> 00:28:55,390
+sugar، الـ aldehyde، إحنا بنقول الـ sugar موجود أساساً
+
+321
+00:28:55,390 --> 00:29:03,790
+بشكل acyclic أو بشكل cyclic، وبينهم اتزان، أنه هو
+
+322
+00:29:03,790 --> 00:29:08,390
+اللي موجود بنسبة أكبر الـ cyclic ولا الـ acyclic؟ الـ
+
+323
+00:29:08,390 --> 00:29:13,310
+cyclic، هذا موجود بنسبة قليلة جداً، قلنا بنسبة إيش؟
+
+324
+00:29:13,310 --> 00:29:19,430
+ثلاثة بالألف، نسبة قليلة جداً، المهم هذا الشكل في
+
+325
+00:29:19,430 --> 00:29:23,390
+الـ aldehyde، لو جيت أعمل له Reduction بالهيدروجين في وجود
+
+326
+00:29:23,390 --> 00:29:28,130
+كاتاليست، الـ aldehyde شو بده يصير؟ الـ primary alcohol
+
+327
+00:29:28,130 --> 00:29:34,270
+طبعاً الآن بيصير السؤال، Reduction of sugars
+
+328
+00:29:34,270 --> 00:29:38,650
+produces primary alcohol، طبعاً طالما كل هدول أساساً
+
+329
+00:29:38,650 --> 00:29:44,940
+OH كانت في aldehyde واحدة وصارت OH، صار Polyhydroxy
+
+330
+00:29:44,940 --> 00:29:49,740
+Alcohol، اللي هو مرّ عليكم، الـ Sorbitol، اللي فيه ست
+
+331
+00:29:49,740 --> 00:29:54,060
+مجموعات OH، بطل في الـ aldehyde، هو كان خمسة OH و
+
+332
+00:29:54,060 --> 00:29:55,840
+واحدة الـ aldehyde، وواحدة الـ
+
+333
+00:29:55,840 --> 00:29:56,120
+aldehyde، وواحدة الـ
+
+334
+00:29:56,120 --> 00:29:57,620
+aldehyde، وواحدة الـ aldehyde، وواحدة الـ
+
+335
+00:29:57,620 --> 00:29:57,880
+aldehyde، وواحدة الـ aldehyde، وواحدة الـ
+
+336
+00:29:57,880 --> 00:29:59,140
+aldehyde، وواحدة الـ aldehyde، وواحدة الـ
+
+337
+00:29:59,140 --> 00:30:01,540
+aldehyde، وواحدة الـ aldehyde، وواحدة الـ
+
+338
+00:30:01,540 --> 00:30:05,260
+aldehyde، وواحدة الـ aldehyde، وواحدة الـ
+
+339
+00:30:05,260 --> 00:30:11,460
+aldehyde، وواحدة الـ aldehyde، وواحدة الـ
+
+340
+00:30:13,000 --> 00:30:19,980
+أُخذت وتحوّلت وأصبحت كحول، طب واللي باقي هنا إيش
+
+341
+00:30:19,980 --> 00:30:20,680
+رأيكم فيه؟
+
+342
+00:30:24,980 --> 00:30:29,960
+كل ما هذا جزء منه صار Alcohol، بيُعوّض جزء من هذا
+
+343
+00:30:29,960 --> 00:30:34,760
+بيعمل ring opening في نهاية التفاعل، إيش بتتوقعوا
+
+344
+00:30:34,760 --> 00:30:40,960
+نشوف أن هذا كله هينتهي، يعني كل ما هذا بيتحوّل، بيروح
+
+345
+00:30:40,960 --> 00:30:45,780
+السكر بيفتح، كل ما هذا بيتحوّل، السكر بيفتح، هذه
+
+346
+00:30:45,780 --> 00:30:50,200
+القاعدة في الاتزان، أذكرونا، إيش اسمها؟ مرّت عليكم
+
+347
+00:30:52,610 --> 00:30:56,330
+إعادة الاتزان، أنه الاتزان يرجع لوضعه الطبيعي،
+
+348
+00:30:56,330 --> 00:31:01,290
+يعني دول الاثنين في اتزان، سحبنا هذا، فعلناه،
+
+349
+00:31:01,290 --> 00:31:04,710
+بيردّ هذا يعمل اتزان من الأول لجديد، سحبنا هذا،
+
+350
+00:31:04,710 --> 00:31:11,850
+بيردّ هذا يفتح، لتشكّل principal، واضح؟ وبناءً على
+
+351
+00:31:11,850 --> 00:31:17,210
+ذلك، لو إحنا جِبنالكم سؤال في الامتحان، قلنا هذا و
+
+352
+00:31:17,210 --> 00:31:22,150
+هذا في حالة اتزان، أكملوا المعادلة، هتكملونها، طيب
+
+353
+00:31:22,150 --> 00:31:26,930
+يا ترى لو إجينا سألناكم، ما حطيناش هذا من الأساس،
+
+354
+00:31:26,930 --> 00:31:32,710
+كتبنالكم بس هذا و Reduction، إيش هتعملون؟ هتقولوا
+
+355
+00:31:32,710 --> 00:31:39,630
+مفهوم ضمني، أن هذا متزن مع المفتوح، وبناءً على ذلك
+
+356
+00:31:39,630 --> 00:31:43,710
+هيعمل Reduction ويعطي هذا، يعني لو رسمت أنا بس هذا
+
+357
+00:31:43,710 --> 00:31:49,070
+وقلت لكم H2 و Catalyst، في نهاية هذا الجواب، لكن للفهم
+
+358
+00:31:49,070 --> 00:31:53,250
+كيف هذا الكلام بيصير؟ بيقول الـ… الـ cyclic صار إيش؟
+
+359
+00:31:53,250 --> 00:31:57,350
+الـ cyclic؟ وصار له Reduction، وكل ما هذا صار له
+
+360
+00:31:57,350 --> 00:32:02,450
+Reduction، كل ما الـ cyclic من أول وجديد بيفتح إلى
+
+361
+00:32:02,450 --> 00:32:08,840
+أن يتحول كل الـ cyclic اللي موجود هنا إلى… إلى الكحول
+
+362
+00:32:08,840 --> 00:32:13,320
+اللي هو Sorbitol، واضح؟ لاحظوا معنا، إحنا الآن
+
+363
+00:32:13,320 --> 00:32:20,360
+إستفدنا من إيش؟ من مجموعة الـ aldehyde، الناس
+
+364
+00:32:20,360 --> 00:32:24,280
+اللي متذكرين كويس معنا لما شرحنا الـ aldehyde، قلنا
+
+365
+00:32:24,280 --> 00:32:28,180
+الـ aldehyde واقف على نص السلم، إيش يعني الـ aldehyde
+
+366
+00:32:28,180 --> 00:32:34,900
+واقف على نص السلم أو في نص الطريق، aldehyde ممكن
+
+367
+00:32:34,900 --> 00:32:42,320
+ينزل لكحول زي ما عملت هنا بالـ Reduction، وبنفس
+
+368
+00:32:42,320 --> 00:32:52,120
+الوقت ممكن يطلع فوق لـ acid بالـ Oxidation، واضح؟
+
+369
+00:32:52,120 --> 00:32:58,320
+ماشي، الترتيب اللي عندي، الـ alcohol، aldehyde،
+
+370
+00:32:59,060 --> 00:33:06,000
+acid، أكسدة الكحول تعطي aldehyde، أكسدة الـ aldehyde
+
+371
+00:33:06,000 --> 00:33:11,020
+تعطي acid، اختزال الكحول بيصير alcohol، اختزال
+
+372
+00:33:11,020 --> 00:33:15,520
+الـ aldehyde بيصير alcohol، أكسدة الـ aldehyde بيصير acid
+
+373
+00:33:15,520 --> 00:33:19,820
+الآن إحنا التفاعل اللي موجود عندنا، اختزال الـ aldehyde
+
+374
+00:33:19,820 --> 00:33:25,990
+رجع لإيش؟ للكحول، طب لو عملنا أكسدة للـ aldehyde، هيصير
+
+375
+00:33:25,990 --> 00:33:30,990
+acid، واضحة الفكرة؟ المشكلة في الموضوع كالتالي، أنه
+
+376
+00:33:30,990 --> 00:33:35,470
+إحنا قلنا أكسدة الـ aldehyde بالـ Oxidation بيصير
+
+377
+00:33:35,470 --> 00:33:40,150
+acid، وأكسدة الكحول بعامل مؤكسد قوي برضه بيصير إيش؟
+
+378
+00:33:40,150 --> 00:33:44,410
+acid، متذكرين لما أخدنا Oxidation وفي primary
+
+379
+00:33:44,410 --> 00:33:50,330
+alcohol، حسب نوع المؤكسد، تمام؟ طيب هذا الـ sugar إيش
+
+380
+00:33:50,330 --> 00:33:57,020
+موجود فيه؟ فيه aldehyde وفي كحولات، بالذات الـ primary
+
+381
+00:33:57,020 --> 00:34:01,540
+alcohol، بناءً على ذلك هتلاحظوا لما نيجي ندرس الـ
+
+382
+00:34:01,540 --> 00:34:05,900
+acid ده، أنه هيمرّ بمرحلتين، ممكن عامل مؤكسد
+
+383
+00:34:05,900 --> 00:34:10,560
+نستخدمه فقط لـ acid، الـ aldehyde لـ acid، يعني يصير عندي
+
+384
+00:34:10,560 --> 00:34:15,240
+على الطرف هذا إيش؟ acid، عامل مؤكسد ثاني أقوى منه بـ
+
+385
+00:34:15,240 --> 00:34:19,400
+يُؤكسد الـ aldehyde و يُؤكسد الـ primary alcohol بيصير
+
+386
+00:34:19,400 --> 00:34:23,780
+عندي إيش؟ diacid، نشوف هذا الكلام
+
+387
+00:34:26,870 --> 00:34:31,270
+لو أخدنا Sugar مع عامل مؤكسد، خلّينا نقول ضعيف
+
+388
+00:34:31,270 --> 00:34:36,330
+زي Bromine water أو فضة مع نحاس، خلّينا نركز Bromine
+
+389
+00:34:36,330 --> 00:34:41,670
+water، بيؤكسد الـ aldehyde، بدل ما هو CHO بيصير CO
+
+445
+00:39:31,220 --> 00:39:36,080
+anomeric carbon، بنقول عنها glycosides، هذه الرابطة
+
+446
+00:39:36,080 --> 00:39:38,720
+اللي بين ال anomeric carbon و ال oxygen اللي هي
+
+447
+00:39:38,720 --> 00:39:43,760
+carbon-O مثل أو carbon-OR، بنسميها glycosidic bond
+
+448
+00:39:43,760 --> 00:39:49,740
+هذه الرابطة الجديدة اللي كانت متصلة مع الـ OH، صارت
+
+449
+00:39:49,740 --> 00:39:55,840
+متصلة مع إيش؟ مع الـ OR، شو بنسميها؟ Glycosidic bond
+
+450
+00:39:55,840 --> 00:40:03,080
+موجودة و لها أهمية جزء كبير من أهمية هذه المنطقة
+
+451
+00:40:03,080 --> 00:40:07,660
+أنه لما السكريات بدهم يبدأوا يعملوا dimers مع
+
+452
+00:40:07,660 --> 00:40:11,560
+بعض، يتحدوا، هنلاحظ فائدة هذه الـ glycosidic bond
+
+453
+00:40:11,560 --> 00:40:15,000
+لأنه بيربطوا من خلالها، واضح؟ يربطوا مع بعض من
+
+454
+00:40:15,000 --> 00:40:22,700
+خلالها. لو إجينا رسمنا لكم مركب، هذا sugar من
+
+455
+00:40:22,700 --> 00:40:27,900
+الجلوكوز، هل هذا يا تُرى فيه glycosidic bond ولا
+
+456
+00:40:27,900 --> 00:40:38,380
+لا؟ تطلع عليه، هاي carbon-O، carbon-OR، إذا هذا المركب
+
+457
+00:40:38,380 --> 00:40:43,600
+اللي اسمه ساليسين من شجر الصفصاف، لما كانوا بيغلو
+
+458
+00:40:43,600 --> 00:40:47,140
+شجر الصفصاف، بيطلع هذا المركب، كانوا ياخذوه للصداع
+
+459
+00:40:47,140 --> 00:40:52,440
+الناس زمان، فيه glycosidic bond، لاحظوا اللي
+
+460
+00:40:52,440 --> 00:40:58,900
+بتأملوا فيه بشكل قوي، هتلاحظوا أن هذا بيشبه إيش؟
+
+461
+00:40:58,900 --> 00:41:02,040
+الأسبرين
+
+462
+00:41:03,920 --> 00:41:10,960
+تذكروا الأسبرين كان بنزين و COOH و CH₂O، و بعدين
+
+463
+00:41:10,960 --> 00:41:15,500
+OH نعملها OCOC(=O) acetyl يعني
+
+464
+00:41:15,500 --> 00:41:20,020
+وجود البنزين و الـ orthoposition، هذا بيشبه أي دواء؟
+
+465
+00:41:20,020 --> 00:41:25,580
+بيشبه الأسبرين، هذا مثلاً منتج طبيعي فيه glycosidic
+
+466
+00:41:25,580 --> 00:41:30,170
+bond ولا لأ؟ هي، لما تكون هذه الرابطة اللي هنا مش
+
+467
+00:41:30,170 --> 00:41:36,350
+OH، OR، بنقول هذا إيش المركب؟ glycoside، و الـ bond إيش
+
+468
+00:41:36,350 --> 00:41:43,650
+بنوصفها؟ بنقول عنها glycosidic bond، الآن زي ما
+
+469
+00:41:43,650 --> 00:41:48,330
+اتفقنا أن الـ glycosides وين بيفيدوني كتير أنا؟ لما
+
+470
+00:41:48,330 --> 00:41:53,550
+بدي أدمج سكريات مع بعض، لما بدي أدمج سكريات مع بعض
+
+471
+00:41:53,550 --> 00:41:57,390
+هاجي على هذه الـ oxygen و أصرّ أربط من خلالها، الآن
+
+472
+00:41:57,390 --> 00:42:01,410
+دمج سكريات مع بعض، قصة طويلة، إيش السكريات و إيش
+
+473
+00:42:01,410 --> 00:42:06,370
+السُّكّر المُنتَج اللي بده يطلع عندي، هو ملتوز، سكرّوز، سيللو
+
+474
+00:42:06,370 --> 00:42:11,490
+بيوز، كذا كذا، موضوع كبير، بحاجة إلى أن نُفرد له إن شاء
+
+475
+00:42:11,490 --> 00:42:17,580
+الله محاضرة كاملة، بس لاحظوا، مباشرةً هتلاحظوا أنه أول
+
+476
+00:42:17,580 --> 00:42:22,580
+ما بدي أحكي عن سكريات دمجتهم، هاي الرابطة، هانا تطلعوا
+
+477
+00:42:22,580 --> 00:42:27,980
+عليها، carbon-O، carbon-OR، الـ glycosidic bond ولا لأ؟
+
+478
+00:42:27,980 --> 00:42:33,520
+عشان هيك احنا أخذنا الـ glycosides، لأنه في الـ
+
+479
+00:42:33,520 --> 00:42:37,620
+disaccharides هتلاقوا عندي الـ glycosidic bond طبعاً
+
+480
+00:42:37,620 --> 00:42:41,760
+إيش السكريات اللي بيندمجوا، وإيش السكر الناتج اللي
+
+481
+00:42:41,760 --> 00:42:46,920
+بيطلع، هذا بيكون موضوع المحاضرة القادمة إن شاء الله
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hQvSO3g5Za4_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hQvSO3g5Za4_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..4a075348eece73c87e077b423cbeb4fa63de7f1f
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hQvSO3g5Za4_postprocess.srt
@@ -0,0 +1,1924 @@
+1
+00:00:19,490 --> 00:00:24,290
+بسم الله الرحمن الرحيم المرة الماضية بدينا في
+
+2
+00:00:24,290 --> 00:00:28,130
+موضوع ال carbohydrates بدينا في موضوع ال
+
+3
+00:00:28,130 --> 00:00:34,450
+carbohydrates وقولنا انه امكوانين من carbon و ما
+
+4
+00:00:34,450 --> 00:00:41,130
+.. و بعدين طبعا بدينا في ال sugarsقولنا ال sugars
+
+5
+00:00:41,130 --> 00:00:45,030
+في النهاية هما ال الديهيدز او كيتونز لكن فيهم
+
+6
+00:00:45,030 --> 00:00:48,670
+مجموعات اوقاتش كثيرة بوليهيدروكسي الديهيدز او
+
+7
+00:00:48,670 --> 00:00:55,050
+بوليهيدروكسي كيتونز طبعا بسبب وجود ال chiral
+
+8
+00:00:55,050 --> 00:01:00,910
+centersبصير عندنا عدد ال isomers للصيغة الواحدة
+
+9
+00:01:00,910 --> 00:01:06,330
+كتير و اتدرجنا طبعا من أبسط مركب في one chiral
+
+10
+00:01:06,330 --> 00:01:11,690
+center اللي هو ال glycerol dihyde و رسمنا بطرق
+
+11
+00:01:11,690 --> 00:01:22,940
+مختلفة شوفنا كيف المركبات هذه ممكن تكونD أو L في
+
+12
+00:01:22,940 --> 00:01:25,300
+المرحلة الأولى و لو قلنا لو عندنا one chiral
+
+13
+00:01:25,300 --> 00:01:30,540
+center بيصير في عندنا مركبين بعد هيك قصة ال D و L
+
+14
+00:01:30,540 --> 00:01:34,580
+بتستمر بزيادة ال chiral center و بيبدأ العدد يزيد
+
+15
+00:01:34,580 --> 00:01:43,040
+فبناء على ذلك بناء على ذلك فبموضوع
+
+16
+00:01:43,040 --> 00:01:46,140
+ال sugars
+
+17
+00:01:47,420 --> 00:01:52,440
+قلنا أساسي جدا نتطلع على ال chiral centers و نتذكر
+
+18
+00:01:52,440 --> 00:01:55,620
+كل الكلام اللي حكيناه في chiral centers في chapter
+
+19
+00:01:55,620 --> 00:01:59,460
+4 إذا عندنا one chiral center بنتوقع مركبين two
+
+20
+00:01:59,460 --> 00:02:04,480
+chiral centers بنتوقع أربعة و هكذا بدأنا بالتدريج
+
+21
+00:02:04,480 --> 00:02:09,980
+و أخر شيء انتهينا عنده احنا لما كان في عندنا ست
+
+22
+00:02:09,980 --> 00:02:17,870
+ذرات كربون طبعا لما بيكون عندى ست ذرات كربونعلى
+
+23
+00:02:17,870 --> 00:02:22,090
+حسب ما بنرسم احنا ال sugar بالطريقة اللي اتعلمناها
+
+24
+00:02:22,090 --> 00:02:27,370
+الذرة الأولى من فوق الديهايد وبناء على ذلك هذا مش
+
+25
+00:02:27,370 --> 00:02:32,550
+chiral center والذرة الأخيرة من تحت CH2OH مش
+
+26
+00:02:32,550 --> 00:02:36,970
+chiral center واجتها لو رسمنا الشكل اللي بنسميه
+
+27
+00:02:36,970 --> 00:02:42,950
+الacyclic structure بيكون فينا كام isomer كام
+
+28
+00:02:42,950 --> 00:02:50,800
+chiral center أربعة بيقدروا إلىالان طالما ان السكر
+
+29
+00:02:50,800 --> 00:02:55,840
+عبارة عن الكهول و الديهايد لو جربنا نجعل الكهول
+
+30
+00:02:55,840 --> 00:03:00,640
+يسكر على الديهايد هيعمل a new chiral center هيصير
+
+31
+00:03:00,640 --> 00:03:07,080
+اندفعخمسة كايرال سنترز وجدت بنتوقع انه لسكر مكون
+
+32
+00:03:07,080 --> 00:03:11,460
+من ست ذرات كربون بهذا الشكل يكون عنده اتنين و
+
+33
+00:03:11,460 --> 00:03:17,320
+تلاتين ايزومات طبعا لما تمت عملية الاغلاق لما تمت
+
+34
+00:03:17,320 --> 00:03:23,040
+عملية اغلاق الالكول على ال الديهايدبهذا الشكل
+
+35
+00:03:23,040 --> 00:03:28,100
+اتكون عندى هنا ال new chiral center وقولنا
+
+36
+00:03:28,100 --> 00:03:30,920
+الكاربون هذه اللى بتعمل ال new chiral center شو
+
+37
+00:03:30,920 --> 00:03:35,460
+بنسميها احنا انوميرك كاربون الان معنى new chiral
+
+38
+00:03:35,460 --> 00:03:40,060
+center ان هو ال OH هذى بنسميها اما لأعلىوإما لأسفل
+
+39
+00:03:40,060 --> 00:03:44,460
+وقلنا إذا بتكون لأسفل بنقول هذا Alpha compound
+
+40
+00:03:44,460 --> 00:03:48,740
+وإذا بتكون لأعلى بيقول هذا Beta الآن طالما أنه في
+
+41
+00:03:48,740 --> 00:03:52,560
+أربعة chiral centers كان عنده 16 مركب كل واحد فيهم
+
+42
+00:03:52,560 --> 00:03:55,840
+لما بده يسكر بده يقسم Alpha Beta Alpha Beta معنا
+
+43
+00:03:55,840 --> 00:04:01,820
+ذلك المجموع صار إيش 32 مركب هذا تقريبا أخر شيء
+
+44
+00:04:01,820 --> 00:04:08,390
+انتهينا فيه الآن اللي بدي أنبهلهطيب الآن قلنا في
+
+45
+00:04:08,390 --> 00:04:15,210
+عندنا شكل a cyclic و أشكال cyclic لأ هذا السكر ال
+
+46
+00:04:15,210 --> 00:04:21,450
+a cyclic يترى بأي نسبة عادة موجود في المحلول و ال
+
+47
+00:04:21,450 --> 00:04:26,860
+cyclic بأي نسبة موجودين في المحلولالصحيح أن الـ
+
+48
+00:04:26,860 --> 00:04:33,080
+acyclic في محلول مائي يوجد بنسبة قليلة جدا جدا جدا
+
+49
+00:04:33,080 --> 00:04:37,000
+يعني معظم السكر بينوجد على شكل الحلقة النسبة اللي
+
+50
+00:04:37,000 --> 00:04:43,460
+بينوجد فيها ال acyclic في محلول مائي هي 0.003
+
+51
+00:04:43,460 --> 00:04:50,780
+بيرزة تلاتة من ألف يعني أكاد يكون مش موجود إذا
+
+52
+00:04:50,780 --> 00:04:57,310
+كأنه كل السكربسكر واضح كأنه كل السكر بيسكر لما
+
+53
+00:04:57,310 --> 00:05:01,290
+نقول هذه النسبة قليلة جدا اللى بينوجد فيها الـA
+
+54
+00:05:01,290 --> 00:05:05,630
+Cycle طيب كل السكر بيسكر بيسكر على ايش Alpha و
+
+55
+00:05:05,630 --> 00:05:10,550
+Beta هل بيكونوا بنفس النسبة اتعودنا او حكينا انه
+
+56
+00:05:10,550 --> 00:05:16,930
+لأ بيكون ال Beta بالمعدل حوالي 64والألف حوالي 36
+
+57
+00:05:16,930 --> 00:05:24,030
+او هنا 35.5 يمكن هناك 64.5 و هنا 35.5 لو بدنا نسيب
+
+58
+00:05:24,030 --> 00:05:31,860
+شوية دقيقة واضح يمكن البعض يقولطب كيف جدروا يفصلوا
+
+59
+00:05:31,860 --> 00:05:36,080
+هذا لوحده يعني طالما انه هذا اتزان ما بين ال alpha
+
+60
+00:05:36,080 --> 00:05:40,540
+و ال beta يعني دايما المخلوط موجود فيه التنين كيف
+
+61
+00:05:40,540 --> 00:05:43,940
+يتعرفوا على ال alpha لحاله اذا انا بحط في المحلول
+
+62
+00:05:43,940 --> 00:05:48,560
+المائي بينوجدوا التنين الجواب اه في المحلول المائي
+
+63
+00:05:48,560 --> 00:05:53,160
+بينوجدوا التنين فعلالكن لو اعملنا للمركب
+
+64
+00:05:53,160 --> 00:05:59,460
+crystallization تبلر من محلول Methanol فقط بيطلع
+
+65
+00:05:59,460 --> 00:06:04,300
+عند ال alpha نقي يعني انا في غير الميه بقدر احصل
+
+66
+00:06:04,300 --> 00:06:10,400
+ال alpha نقي ال alpha ال pure alpha وين بشوفه
+
+67
+00:06:10,400 --> 00:06:15,440
+بمحلول ايش؟الميثانول فلو عملنا crystallization
+
+68
+00:06:15,440 --> 00:06:19,180
+للسكر هذا ال جولوكوز بمحلول الميثانول باخد ال
+
+69
+00:06:19,180 --> 00:06:23,320
+alpha لوحده واضح الفكرة؟ الان لو عملت
+
+70
+00:06:23,320 --> 00:06:30,020
+crystallization بال acidic acid بحصل على ال beta
+
+71
+00:06:30,020 --> 00:06:38,760
+لوحده فقط ايش؟ ال beta ال pure betaواضح؟ الان لو
+
+72
+00:06:38,760 --> 00:06:42,760
+اجيت اخدت انا صار في عندى alpha pure يعني صار في
+
+73
+00:06:42,760 --> 00:06:47,100
+عندى بوتل في alpha pure بوتل تاني في beta pure ال
+
+74
+00:06:47,100 --> 00:06:51,590
+alpha pure من وين باخده؟من خلال الميثانول ال beta
+
+75
+00:06:51,590 --> 00:06:55,910
+pure من ال acetic acid الآن لو جبت ال alpha pure
+
+76
+00:06:55,910 --> 00:07:01,750
+حطيته في الميه في محلول الميه بيصير يعمل التحول
+
+77
+00:07:01,750 --> 00:07:05,730
+لacyclic و برد سكر alpha beta إلى أن يصل إلى
+
+78
+00:07:05,730 --> 00:07:10,410
+الاتزان اللى اتفقنا عليه ال 36 و64 فهذا الاتزان
+
+79
+00:07:10,410 --> 00:07:16,370
+وين بيكون موجود في ال aqueous solutionفي المحلول
+
+80
+00:07:16,370 --> 00:07:21,370
+المائي لو بدأت بالألفة النقي هيصل لهذا الاتزان و
+
+81
+00:07:21,370 --> 00:07:26,730
+لو بدأت بالبيتا النقي أيضا هيصل لهذا الاتزان واضح؟
+
+82
+00:07:26,730 --> 00:07:31,510
+إذا بالإمكان إن أنا أفصل ألفة نقي ب solvent غير
+
+83
+00:07:31,510 --> 00:07:35,870
+الميه وبيتا نقي ب solvent غير الميه لكن في الميه
+
+84
+00:07:35,870 --> 00:07:41,270
+لو بدأت بأي واحد فهيحصل الاتزان اللي هو بين ألفة
+
+85
+00:07:41,270 --> 00:07:48,250
+وبيتابنسبة 36 ل 64 هذا الكلام بيعني شغلة بيعني ان
+
+86
+00:07:48,250 --> 00:07:53,770
+which is more stable ال alpha ولا ال beta ال beta
+
+87
+00:07:53,770 --> 00:07:58,870
+اللي موجود بنسبة اكبر هو اللي بيكون more stable
+
+88
+00:07:58,870 --> 00:08:01,490
+واضح هذه الفكرة
+
+89
+00:08:05,630 --> 00:08:10,350
+بعد هيك بدنا ننتبه لنقطة أنه لما بتم الإغلاق ال
+
+90
+00:08:10,350 --> 00:08:15,130
+الديهايد مجموعة واحدة مش موضوع خلافي لكن ال OHS
+
+91
+00:08:17,200 --> 00:08:25,520
+أكتار زي ما اتكلمنا هذه OH ممكن تسكرها و إغلاق
+
+92
+00:08:25,520 --> 00:08:29,580
+أي OH يعطي حلقة بحجم مختلف يعني لو أغلقت من هنا
+
+93
+00:08:29,580 --> 00:08:35,060
+ستكون حلقة ثلاثية لو هيك سكرت ربعية لو هذه سكرت
+
+94
+00:08:35,060 --> 00:08:40,980
+خمسية هذه اللي سكرت السداسية هذه سبعية هل يترا
+
+95
+00:08:40,980 --> 00:08:47,530
+ممكن أن يتم إغلاقات لغير الحلقة السداسية؟اللي
+
+96
+00:08:47,530 --> 00:08:53,130
+مشهور حقيقة انه بتم اغلاق من ال OH اللي موجودة هنا
+
+97
+00:08:53,130 --> 00:08:59,730
+وبيعطيني حلقة خماسية لكن قداش نسبة السكر اللي
+
+98
+00:08:59,730 --> 00:09:05,970
+بيكون كحلقة خماسية واحد في المية يعني لاحظوا لو
+
+99
+00:09:05,970 --> 00:09:09,930
+انا بدي اجي على المحلول بالمجمل هقول في عندي واحد
+
+100
+00:09:09,930 --> 00:09:15,870
+في المية حلقة خماسية في عندي تلاتة بالألف إيه
+
+101
+00:09:15,870 --> 00:09:23,200
+صايفلك؟فاتح والباقي حلقة سداسية بتكون النسبة بين
+
+102
+00:09:23,200 --> 00:09:31,200
+مكوناتها 64 إلى 36 واضح فالمحلول هيكون فيه اكثر من
+
+103
+00:09:31,200 --> 00:09:36,100
+شغلة هيكون فيه محلول الجولوكوز الacyclic بنسبة
+
+104
+00:09:36,770 --> 00:09:43,010
+تلاتة في الألف المسكّر على حلقة خماسية بيكون بنسبة
+
+105
+00:09:43,010 --> 00:09:46,370
+واحد في المية الاناليبيكي اللي هو التسعة وتسعين في
+
+106
+00:09:46,370 --> 00:09:51,050
+المية كيف بتكون مقصومة اربعة وستين في المية منها
+
+107
+00:09:51,050 --> 00:09:55,410
+بيتا ستة و تلاتين في المية منها الفة واضح الفكرة
+
+108
+00:10:01,460 --> 00:10:06,660
+طبعا احنا قولنا كلمة و وضحناها المرة الماضية ان ال
+
+109
+00:10:06,660 --> 00:10:10,860
+beta is more stable than the alpha لان لو رسمنا
+
+110
+00:10:10,860 --> 00:10:14,920
+الحلقة السوداسية على الشكل اللى عادة بتكون موجودة
+
+111
+00:10:14,920 --> 00:10:18,420
+فيه و يمكن مار علينا لما أخدنا الحلقات السوداسية
+
+112
+00:10:18,420 --> 00:10:21,140
+نقطين وجد على شكل both
+
+113
+00:10:23,360 --> 00:10:27,920
+أو chair which is more stable chair conformation
+
+114
+00:10:27,920 --> 00:10:31,620
+الان لو حطيتها على هيئة الكرسي في ال chair
+
+115
+00:10:31,620 --> 00:10:37,480
+conformation ال OH ممكن تكون بشكل أفقي بهذا الشكل
+
+116
+00:10:37,480 --> 00:10:43,460
+بنقول عنها equatorial equatorial يعني بشكل أفقي
+
+117
+00:10:43,460 --> 00:10:48,040
+يعني لما نتخيل أنه الشكل العام للحلقات بهذا الشكل
+
+118
+00:10:48,040 --> 00:10:55,070
+هي بتكون زي هيكهذه equatorial الان ممكن تكون في
+
+119
+00:10:55,070 --> 00:11:01,830
+شكل تاني axial رأس عمودي هيك equatorial هيك axial
+
+120
+00:11:01,830 --> 00:11:09,740
+الان بالشكل هذا بتكون ايش؟أكسيال طبعا ال
+
+121
+00:11:09,740 --> 00:11:13,820
+equatorial الفراغ اللي حواليها أفضل من الفراغ اللي
+
+122
+00:11:13,820 --> 00:11:18,180
+حواليه الأكسيال الأكسيال crowded لاحظوا فيها
+
+123
+00:11:18,180 --> 00:11:21,600
+steric hindrance فيها ممانعة فراغية مالهاش واسعة
+
+124
+00:11:21,600 --> 00:11:26,840
+واضحالـ equatorial مترايحة أكثر ولذلك هذا الشكل ال
+
+125
+00:11:26,840 --> 00:11:31,200
+equatorial هو ال beta هذا الشكل ال axial هو ال
+
+126
+00:11:31,200 --> 00:11:35,900
+alpha عشان هيك ال beta بيكون more stable لأن ال OH
+
+127
+00:11:35,900 --> 00:11:39,820
+اللي موجودة فيه ال new chiral center لأنميرك كربون
+
+128
+00:11:39,820 --> 00:11:43,860
+بتكون مترايحة من الناحية الفرغية مافيش حد مضايقها
+
+129
+00:11:43,860 --> 00:11:48,440
+واضح؟ لحظوا هذه ال OH الجديدة اللي اتكونت عندىالان
+
+130
+00:11:48,440 --> 00:11:52,740
+في ال equatorial form هي مترايحة في ال axial form
+
+131
+00:11:52,740 --> 00:11:57,160
+مش مترايحة في جنبها مجموعات تانية بتعمل ازدحام
+
+132
+00:11:57,160 --> 00:12:02,240
+فراغي فلما نكون بدنا نفسر ليش ال beta موجودة اكثر
+
+133
+00:12:02,240 --> 00:12:08,020
+من ال alpha بنقول because the beta o h is found in
+
+134
+00:12:08,020 --> 00:12:13,140
+the equatorial position لان موجودة في ال
+
+135
+00:12:13,140 --> 00:12:16,960
+equatorial ال equatorial is not a crowded position
+
+136
+00:12:17,870 --> 00:12:24,070
+واضح فسبب الثبات ل ال beta ان ال OH الجديدة هذه
+
+137
+00:12:24,070 --> 00:12:28,650
+اللي اتكونت عندي هنا لو رسمت الشكل على هيئة الكرسي
+
+138
+00:12:28,650 --> 00:12:32,330
+بتكون موجودة وين؟ في ال axial ولا في ال
+
+139
+00:12:32,330 --> 00:12:36,070
+equatorial؟ في ال equatorial ال equatorial is not
+
+140
+00:12:36,070 --> 00:12:39,350
+a sterically hindered molecule
+
+141
+00:12:41,870 --> 00:12:44,730
+طبعا الـ mutarotation حكينا عنه برضه المرة
+
+142
+00:12:44,730 --> 00:12:49,450
+الماضية، قلنا لو بدنا من أي واحد، حيصل لإيش؟
+
+143
+00:12:49,450 --> 00:12:50,310
+للإتزان
+
+144
+00:12:52,690 --> 00:12:57,850
+ال بيرانوز and فيرانوز structures الموضوع بسيط
+
+145
+00:12:57,850 --> 00:13:02,650
+فيهم انه احنا قلنا السكر اشهر الإغلاقات تبعته اما
+
+146
+00:13:02,650 --> 00:13:08,630
+على حلقة سداسية او على حلقة خماسية الان في ال
+
+147
+00:13:08,630 --> 00:13:12,610
+heterocyclic chemistry الحلقة السداسية اللى فيها
+
+148
+00:13:12,610 --> 00:13:18,190
+ال oxygen بهذا الشكل اسمها بيرينواضح؟ هذه الحلقة
+
+149
+00:13:18,190 --> 00:13:22,910
+اللي فيها ال oxygen اسمها بيرين والحلقة الخماسية
+
+150
+00:13:22,910 --> 00:13:28,290
+اللي فيها ال oxygen اسمها إيش؟ فيوران بناء على ذلك
+
+151
+00:13:28,290 --> 00:13:33,530
+السكر لما بيسكر على حلقة سداسية صاروا ينسبوا لل
+
+152
+00:13:33,530 --> 00:13:37,290
+بيرين فكل السكريات اللي مسكرة على حلقة سداسية
+
+153
+00:13:37,290 --> 00:13:42,190
+بيصيروا يقولوا عنها بيرانوزز بيرانوزز يعني مسكر
+
+154
+00:13:42,190 --> 00:13:46,210
+على حلقة سداسية لما بيشوف بيرين بدي أقول أن الحلقة
+
+155
+00:13:46,740 --> 00:13:53,340
+لو كان مسكر على حلقة خماسية نسبة إلى الفيوران
+
+156
+00:13:53,340 --> 00:13:58,360
+الخماسي بقول عنه ايش؟ فيرانوز فبنصير من الآن
+
+157
+00:13:58,360 --> 00:14:01,700
+نستعمل كلمتين اجداد انه لما نحكي عن الحلقة
+
+158
+00:14:01,700 --> 00:14:07,020
+السوداسية بنستعمل كلمة بيرانوز فالجولوكوز اللى
+
+159
+00:14:07,020 --> 00:14:12,620
+مسكر على حلقة سوداسية الآن بيقول عنه جلوكو بيرانوز
+
+160
+00:14:13,420 --> 00:14:17,300
+معنى Glucopyranose أنه جولوكوز مسكّر على حلقة
+
+161
+00:14:17,300 --> 00:14:23,400
+سدسية طب لو سكّر على حلقة خماسية Glucofuranose فمن
+
+162
+00:14:23,400 --> 00:14:28,200
+الآن و طالع هنصير نشوف اسمين Glucopyranose و
+
+163
+00:14:28,200 --> 00:14:32,320
+Glucofuranose لما نقول لحد إيش يعني Glucopyranose؟
+
+164
+00:14:33,530 --> 00:14:40,490
+جولوكوز مسكر على حلقة صداسية إيش معناه؟ جولوكوز
+
+165
+00:14:40,490 --> 00:14:42,830
+مسكر على حلقة خمسية، جولوكوز مسكر على حلقة خمسية،
+
+166
+00:14:42,830 --> 00:14:42,870
+جولوكوز مسكر على حلقة خمسية، جولوكوز مسكر على حلقة
+
+167
+00:14:42,870 --> 00:14:43,730
+خمسية، جولوكوز مسكر على حلقة خمسية، جولوكوز مسكر
+
+168
+00:14:43,730 --> 00:14:44,790
+على حلقة خمسية، جولوكوز مسكر على حلقة خمسية،
+
+169
+00:14:44,790 --> 00:14:49,350
+جولوكوز مسكر على حلقة خمسية، جولوكوز مسكر على حلقة
+
+170
+00:14:49,350 --> 00:14:57,390
+خمسية، جولوكوز مسكر على حلقة خمسية، جولوكوز
+
+171
+00:14:57,390 --> 00:15:04,480
+مسكر على حلقة خمسية، جولوكوز مسكر على حلقة خممرتبط
+
+172
+00:15:04,480 --> 00:15:09,620
+فيها اسم Byronose واسم Furanose عشان نعرف هو مسكر
+
+173
+00:15:09,620 --> 00:15:13,840
+على أي نوع من الحلقات هتبدأوا الآن لما تشوفوا
+
+174
+00:15:13,840 --> 00:15:19,900
+الأسماء تقرؤوا هذا الكلام لاحظوا مثلا لفراكتوز لو
+
+175
+00:15:19,900 --> 00:15:25,200
+سكر على حلقة خمسية شو بدي أسميه فراكتوفيرانوز
+
+176
+00:15:25,200 --> 00:15:29,260
+فيرانوز عفوا فراكتوفيرانوز هي هذا شكل لفراكتوز
+
+177
+00:15:29,260 --> 00:15:34,340
+لفراكتوز نتذكر أن هو keto sugarالفراكتوز سكر
+
+178
+00:15:34,340 --> 00:15:38,060
+العناب بتكون السيضة بالبندقوفي ع موقع اتنين هو
+
+179
+00:15:38,060 --> 00:15:42,060
+كيتون مش الديهايد فلما تيجي هذه ال O H تسكر هنا
+
+180
+00:15:42,060 --> 00:15:48,580
+وتعمل chiral center هنا يعني تصير ال Ketone هذه O
+
+181
+00:15:48,580 --> 00:15:55,480
+H يا بده تكون ال O H لفوق يا بده تكون ال O H لتحت
+
+182
+00:15:55,480 --> 00:16:01,060
+إذا كانت لفوق معنا ذلك أنا بوصفهبيتا وإذا كانت
+
+183
+00:16:01,060 --> 00:16:07,240
+لاتحت أنا بوصفه ألفة الآن وصفنا كل الكلام وحسب ما
+
+184
+00:16:07,240 --> 00:16:11,340
+هو اسمه افراكتوز لأنه سكر على حلقة خمسية شو بدي
+
+185
+00:16:11,340 --> 00:16:16,880
+أقول عنه افراكتو فيورانوسو ال D و ال Alpha فاهمين
+
+186
+00:16:16,880 --> 00:16:20,940
+هو ال D من ال Stereochemistry لباقي المجموعات
+
+187
+00:16:20,940 --> 00:16:26,100
+تحديدا للمجموعة اللي قبل الأخيرة، واضح؟ فلما نقرأ
+
+188
+00:16:26,100 --> 00:16:29,740
+هذه الأسماء ما نستغرب عشان نكون عارفين معنى كل
+
+189
+00:16:29,740 --> 00:16:33,600
+مفردة بالمفردات يعني لما بتيجوا تقرؤوا اسم Sugar
+
+190
+00:16:33,600 --> 00:16:41,100
+هتلاقوا حالكوا بتقرؤوا بيتا دي إجلوكو بيرانوسالان
+
+191
+00:16:41,100 --> 00:16:47,260
+لما نيجي نسأل اي واحدة فيكم ايش يعني بيتا و دي و
+
+192
+00:16:47,260 --> 00:16:51,400
+جلوكو و بيرانوز كل هذا الكلام معناه اي هذا مركب
+
+193
+00:16:51,400 --> 00:16:59,320
+مثلا بيتا دي جلوكو بيرانوز البيتا معنا ذلك لما سكر
+
+194
+00:16:59,320 --> 00:17:06,020
+السكر كانت ال OH لفوق ولا لتحت لفوق ال Dلما نرسم
+
+195
+00:17:06,020 --> 00:17:11,060
+ال acyclic structure ال O H اللي قبل الأخيرة اللي
+
+196
+00:17:11,060 --> 00:17:17,680
+هي بتكون على اليمين طبعا لما نعمله بشكل حلقي بتكون
+
+197
+00:17:17,680 --> 00:17:22,280
+مرسومة بشكل معين ال glucose السكر اللي عندى
+
+198
+00:17:22,280 --> 00:17:29,460
+جولوكوز بيرانوز نسكر على حلقة سداسية واضح الفكرة؟
+
+199
+00:17:30,180 --> 00:17:35,240
+فكل هذه المفردات الحقيقة بتلزمنا الان لو اجينا
+
+200
+00:17:35,240 --> 00:17:42,600
+بدنا نحكي عن تفاعلات ال sugars الان في المحصلة
+
+201
+00:17:42,600 --> 00:17:49,840
+السكر ايش هو تعريفه البسيط polyhydroxy
+
+202
+00:17:49,840 --> 00:17:54,880
+aldehyde او كيتولhydroxy يعني الكهول الديهايد او
+
+203
+00:17:54,880 --> 00:17:59,040
+كيتون معروف بناء على ذلك لما انا بدي اخد تفاعلات
+
+204
+00:17:59,040 --> 00:18:04,540
+ال sugars معنى ذلك هي تفاعلات الكحولات وتفاعلات
+
+205
+00:18:04,540 --> 00:18:10,800
+الكيتونات يا بدي افعله على الكحول يا على ال C
+
+206
+00:18:10,800 --> 00:18:15,900
+double bond O تبع ال الديهايد او الكيتون خلينا
+
+207
+00:18:15,900 --> 00:18:22,180
+ناخد مثال لو اخدنا مثلا السكر المسكراللي قلنا عنه
+
+208
+00:18:22,180 --> 00:18:27,000
+بيتا دي جلوكو بيرانوز وين رسمينه على هيئة الكرسي
+
+209
+00:18:27,000 --> 00:18:33,300
+هل هذا لما سكر لما صار بيرانوز ضال فيه الديهايد؟
+
+210
+00:18:33,780 --> 00:18:38,000
+ولا اتحولت ل New Cairo Center اتحولت ل New Cairo
+
+211
+00:18:38,000 --> 00:18:43,880
+Center اذا انا اول ما بدي اقرأ اسم Byranose او
+
+212
+00:18:43,880 --> 00:18:48,160
+اقرأ اسم Furanose لو بدي اخده لوحده بدون الاتزان
+
+213
+00:18:48,160 --> 00:18:52,380
+مافيش فيه Aldehyde لكن لو بدي اخده ضمن ان هو في
+
+214
+00:18:52,380 --> 00:18:56,620
+اتزان مع الفاتح الفاتح فيه Aldehyde واضح؟ خلينا
+
+215
+00:18:56,620 --> 00:19:00,380
+ناخد ال glucobyranose لوحده مجموعة ال aldehyde
+
+216
+00:19:00,380 --> 00:19:04,090
+اللي كانت فيه سارةأو أتش يعني هنا في أو أتش تنتين
+
+217
+00:19:04,090 --> 00:19:09,490
+تلاتة أربعة خمسة يعني هذا بدل ما يكون كحول هو
+
+218
+00:19:09,490 --> 00:19:15,650
+عبارة عن خمس كحولات مش في خمس أو أتش كل أو أتش
+
+219
+00:19:15,650 --> 00:19:21,810
+عبارة عن كحول الآن لو إجيت قلتلكوا بدي أفاعل كحول
+
+220
+00:19:21,810 --> 00:19:29,390
+مع unhydrate شو بيعطيني من الكيميا العادية كحول
+
+221
+00:19:29,390 --> 00:19:30,730
+زاد unhydrate
+
+222
+00:19:33,300 --> 00:19:37,060
+يعني نجيبلكوا سؤال أكمل الفرق ال reaction of
+
+223
+00:19:37,060 --> 00:19:43,280
+alcohol with anhydrides produces كلمة واحدة أستر
+
+224
+00:19:43,280 --> 00:19:50,340
+أستر الناس اللي بيدرسوا بنتبهوا كلمة سهلة جدا لما
+
+225
+00:19:50,340 --> 00:19:54,580
+أخدنا تفاعل الكحول مع ال acids بيعطينا أستر مع ال
+
+226
+00:19:54,580 --> 00:19:59,690
+acid chloride بيعطينا أستر مع ال anhydrideبيعطينا
+
+227
+00:19:59,690 --> 00:20:03,310
+Easter، مظبوط ولا لأ؟ طب لو بدنا نفعل الكحول مع ال
+
+228
+00:20:03,310 --> 00:20:08,510
+Easter، شو بيعطينا؟
+
+229
+00:20:08,510 --> 00:20:15,450
+كحول
+
+230
+00:20:15,450 --> 00:20:20,330
+مع Easter كحول
+
+231
+00:20:20,330 --> 00:20:30,950
+مع Easter إيش رأيكوا؟ Easterطبعا ي start تاني من
+
+232
+00:20:30,950 --> 00:20:34,710
+سير الإنسان بالعملية trans esterification لأن
+
+233
+00:20:34,710 --> 00:20:41,750
+متابعتك اضعيفة شوية في الموضوع اللي أخدناه سابقا و
+
+234
+00:20:41,750 --> 00:20:47,210
+اللي احنا محتاجينه مضطر ان اعمل شوية ايش شوية
+
+235
+00:20:47,210 --> 00:20:48,250
+مراجعة معكم
+
+236
+00:20:50,980 --> 00:20:59,460
+نعمل شوية المراجعة هى نحط كحول ميثانول كويس و
+
+237
+00:20:59,460 --> 00:21:01,320
+نعمله بأى لون الميثانول
+
+238
+00:21:04,970 --> 00:21:11,590
+CH3OH زائد فعلوه مع الاسد ايه صيغة الاسد اي اسد
+
+239
+00:21:11,590 --> 00:21:17,070
+ناخد ال بنزويك اسد ال بنزويك اسد فنل C double bond
+
+240
+00:21:17,070 --> 00:21:23,330
+O OH فعلوه مع ال بنزويل كلورايد الاسد كلورايد فنل
+
+241
+00:21:23,330 --> 00:21:31,340
+C double bond O Cl فعلوه معالبنزويت كان هيدرايد
+
+242
+00:21:31,340 --> 00:21:38,900
+فانل C double bond O O C double bond O فانل فعلوه
+
+243
+00:21:38,900 --> 00:21:46,680
+كمان مع الاثل بنزويت فانل C double bond O O اثلهي
+
+244
+00:21:46,680 --> 00:21:50,860
+الكحول بتفعل مع الحمض أو مع ال acid chloride أو مع
+
+245
+00:21:50,860 --> 00:21:55,600
+ال acid anhydride أو حتى مع ال E star الألم بده
+
+246
+00:21:55,600 --> 00:22:01,340
+يعطيني في كل الأحوال هو تفاعل واحد إبدال هذي بده
+
+247
+00:22:01,340 --> 00:22:09,200
+تخرج ييجي بدالها مثل هذي لين يفعل اللي بده يهاجم و
+
+248
+00:22:09,200 --> 00:22:16,980
+هذي تخرج هذي بده تخرج هذي بده تخرجو بناء على ذلك
+
+249
+00:22:16,980 --> 00:22:23,660
+الناتج من كل هدولة هيكون نفس ال Easter اللي هو
+
+250
+00:22:23,660 --> 00:22:30,220
+Phenyl C double bond O O Methyl بدل المجموعة
+
+251
+00:22:30,220 --> 00:22:34,440
+المغادرة هذه الآن بعد ذلك أنه هنا بطلع H مع ال OH
+
+252
+00:22:34,440 --> 00:22:39,340
+زائد ميه زائد HCl زائد Benzoic acid زائد Ethanol
+
+253
+00:22:39,340 --> 00:22:45,200
+مش مشكلةفتفاعل الكحول مع أي واحد من الأحماض
+
+254
+00:22:45,200 --> 00:22:50,040
+ومشتقاتها بيعطيني إيه؟ Easter كحول مع أسد، كحول مع
+
+255
+00:22:50,040 --> 00:22:53,600
+أسد كلورايت، كحول مع أنهايدرايت، كحول مع Easter،
+
+256
+00:22:53,600 --> 00:22:59,050
+يمكن أنا تقوله يا الله Easter أعطىEaster تاني اه
+
+257
+00:22:59,050 --> 00:23:04,630
+بس هذا ال Easter كان فنل C double bond O او اثل
+
+258
+00:23:04,630 --> 00:23:11,370
+صار فنل C double bond O او مثل اذا بدلت ال Easter
+
+259
+00:23:11,370 --> 00:23:17,010
+ولا لأ عشان هيك بنسميه ال Transesterification ايش
+
+260
+00:23:17,010 --> 00:23:22,610
+يعني ال Trans تحويل بتعرفوا Trans الكهربا كيف
+
+261
+00:23:22,610 --> 00:23:27,910
+بيحول بتعرفوا معناه Transformationبتعرفوا كلمة
+
+262
+00:23:27,910 --> 00:23:33,390
+Transport انه بننجل البني .. اه ف Trans لما
+
+263
+00:23:33,390 --> 00:23:37,550
+بتيجيكوا في أول الكلام شو معناها؟ تحويل، الآن كان
+
+264
+00:23:37,550 --> 00:23:42,210
+ال Easter، C double bond O، O-ethyl خلت ال Easter،
+
+265
+00:23:42,210 --> 00:23:47,930
+C double bond O، O-methyl فالكحول مع Easter بيبدل،
+
+266
+00:23:47,930 --> 00:23:52,270
+بيعمل Transesterification بدل ما كان O-ethyl صار O
+
+267
+00:23:52,270 --> 00:23:55,250
+-methyl هذه العملية شو بنسميها اللي هنا؟
+
+268
+00:24:02,320 --> 00:24:05,640
+transesterification واضح الفكرة؟ إذا مابدوش
+
+269
+00:24:05,640 --> 00:24:10,000
+يتغلبوني لما أقولكوا الكحول مع ال acid chloride و
+
+270
+00:24:10,000 --> 00:24:14,040
+لا مع ال anhydride، شو بده يعطيني؟ شو بده يعطي
+
+271
+00:24:14,040 --> 00:24:19,880
+الكحول مع ال anhydride؟ إيستر واضح؟ و مع ال
+
+272
+00:24:19,880 --> 00:24:25,230
+chloride إيستر؟ مع كلهم إيسترو .. الآن إذا الكلام
+
+273
+00:24:25,230 --> 00:24:31,790
+هذا كله صار واضح عندكم بدي أجي أرجع للسكر السكر
+
+274
+00:24:31,790 --> 00:24:40,010
+اللي مسكر عبارة عن كحول ال sugar عبارة عن كحول هذا
+
+275
+00:24:40,010 --> 00:24:45,230
+الكحول لو فعلته مع ال unhydrate شو هيعطيلي Easter
+
+276
+00:24:45,230 --> 00:24:54,480
+كل OH بده تصيرهذه الـ O H تهاجم هنا O CH3 أعمل
+
+277
+00:24:54,480 --> 00:25:00,260
+واحدة منهم واضحة O CH3 الآن الـ C double bond O
+
+278
+00:25:00,260 --> 00:25:05,680
+CH3 شو أخدنا اسمها الـ Acetyl group فالخمسة O H
+
+279
+00:25:05,680 --> 00:25:10,140
+بيصيروا كلهم O Acetyl طبعا تطلعوا معي هذا Easter
+
+280
+00:25:10,140 --> 00:25:19,280
+ولا لأ R C double bond O OR Easterفالسكر مع
+
+281
+00:25:19,280 --> 00:25:24,100
+الانهيدريد بيعطيني Easter طيب لو جبنالكوا السؤال
+
+282
+00:25:24,100 --> 00:25:26,940
+قولنا لكوا طب لو فعلنا ال sugar مع ال acid
+
+283
+00:25:26,940 --> 00:25:31,060
+chloride برضه Easter برضه Easter المهم انه في ما
+
+284
+00:25:31,060 --> 00:25:37,820
+.. طب لو فعلنا مع ال .. مع Easter برضه Easter تاني
+
+285
+00:25:38,910 --> 00:25:42,570
+نفس المثال اللي هناك هذا الكلام إذا ما بتتدربوش
+
+286
+00:25:42,570 --> 00:25:47,430
+عليه ما بتتقنوه الخمسة OHS كلهم اللي موجودين
+
+287
+00:25:47,430 --> 00:25:52,790
+بيصيروا Easter اتنين تلاتة اربعة خمسة فتفاعل ال
+
+288
+00:25:52,790 --> 00:25:58,070
+sugar مع ال acid unhydrated بيعطيني Easter خلصنا
+
+289
+00:25:58,070 --> 00:26:04,170
+من هذه النقطة؟ كويس لاحظوا كده بتفيدني الكيميا
+
+290
+00:26:04,170 --> 00:26:10,900
+العاديةوهي مقدمة ايش؟ ال biochemistry يعني مش ممكن
+
+291
+00:26:10,900 --> 00:26:14,100
+حد يجي يدرس biochemistry و نشرحله هذا التفاعل هو
+
+292
+00:26:14,100 --> 00:26:17,500
+مش عارف الكحول و ال anhydride و الaster و كيف
+
+293
+00:26:17,500 --> 00:26:21,500
+بتفاعلوا مع بعض و مع البعض فكل تفاعل بمر معنها
+
+294
+00:26:21,500 --> 00:26:27,930
+عشان تفهمه بسهولة لازم يكون المخ يرجع وين؟للـ
+
+295
+00:26:27,930 --> 00:26:31,630
+Organic Chemistry العادية اللي استعلمته فيها هو
+
+296
+00:26:31,630 --> 00:26:35,910
+اللي بيرجع يمر علينا هنا يعني لو مثلا أخدنا هذا
+
+297
+00:26:35,910 --> 00:26:49,170
+التفاعل R O H زائد CH3I هاي التفاعل العادي Alkyl
+
+298
+00:26:49,170 --> 00:26:49,790
+Halide
+
+299
+00:26:52,600 --> 00:26:55,880
+النيوكليوفايل ايش بيعمل النيوكليوفايل بالالكي
+
+300
+00:26:55,880 --> 00:27:04,160
+الهيلايد؟ هذا الشبطر ايش؟ ستة بيهاجر، بيحل محل و
+
+301
+00:27:04,160 --> 00:27:08,460
+النيوترال نيوكليوفايل اللي بيفقد؟ H إذا هنا إيش
+
+302
+00:27:08,460 --> 00:27:16,980
+بده يصير عندكم؟ R O CH3 إذا كحول مع الالكي
+
+303
+00:27:16,980 --> 00:27:19,500
+الهيلايد، شو بيعطيني؟ إيثر
+
+304
+00:27:22,220 --> 00:27:30,660
+ROR Ether الآن ال sugar عبارة عن كحول ولا خمس
+
+305
+00:27:30,660 --> 00:27:34,940
+كحولات في بعض؟ خمس كحولات فعلوه مع المثل Iodide
+
+306
+00:27:35,670 --> 00:27:41,650
+هيعطيني كم إيثر؟ خمس إيثرات مثل او كاربون مثل او
+
+307
+00:27:41,650 --> 00:27:45,070
+كاربون مثل او كاربون مثل او كاربون مثل او كاربون
+
+308
+00:27:45,070 --> 00:27:49,570
+واضح الفكرة؟ هو نفس هذا التفاعل البسيط أن الكحول
+
+309
+00:27:49,570 --> 00:27:55,450
+بيحل محل اليود ولذلك ملخص هدول التنتين أن الكحول
+
+310
+00:27:55,450 --> 00:28:00,950
+مع الانهيدريد بيعطيني إيثر للشجر والكحول مع ال مثل
+
+311
+00:28:00,950 --> 00:28:07,890
+أيودايد بيعطيني إيثرلل sugar و طالما انه موجود من
+
+312
+00:28:07,890 --> 00:28:12,230
+الكحول خمس مجموعات اذا كم Easter و كم Ether هيتكون
+
+313
+00:28:12,230 --> 00:28:20,020
+عندى اذا بعد ما أخدنا تفاعلالشجر بصفته alcohol مع
+
+314
+00:28:20,020 --> 00:28:23,620
+ال unhydrate قولنا بيعطي ether مع ال alkyl halide
+
+315
+00:28:23,620 --> 00:28:27,800
+زي ال methyl iodide قولنا بيعطي ether بدنا ناخد
+
+316
+00:28:27,800 --> 00:28:33,380
+تفاعل تاني للشجر أيضا مر علينا هذا التفاعل لو
+
+317
+00:28:33,380 --> 00:28:38,500
+أجينا بدنا نعمل reduction للشجر هنحتاج جملة من
+
+318
+00:28:38,500 --> 00:28:43,420
+الكيميا القديمة نقول reduction of aldehyde
+
+319
+00:28:43,420 --> 00:28:49,910
+produces ايشprimary الكوكبوس تمام هتقول هو ال
+
+320
+00:28:49,910 --> 00:28:55,390
+sugar ال dehyde احنا بنقول ال sugar موجود أساسا
+
+321
+00:28:55,390 --> 00:29:03,790
+بشكل acyclic او بشكل cyclic و بينهم اتزان ان هو
+
+322
+00:29:03,790 --> 00:29:08,390
+اللي موجود بنسبة أكبر ال cyclic ولا ال acyclic ال
+
+323
+00:29:08,390 --> 00:29:13,310
+cyclic هذا موجود بنسبة قليلة جدا قولنا بنسبة ايش
+
+324
+00:29:13,310 --> 00:29:19,430
+تلاتة بال ألفنسبة قليلة جدا المهم هذا الشكل في
+
+325
+00:29:19,430 --> 00:29:23,390
+الديهيد لو جيت اعمله reduction بالهيدروجين في وجود
+
+326
+00:29:23,390 --> 00:29:28,130
+كتاليست ال الديهيد شو بده يصير ال primary alcohol
+
+327
+00:29:28,130 --> 00:29:34,270
+طبعا الان بيصير السؤال reduction of sugars
+
+328
+00:29:34,270 --> 00:29:38,650
+produces primary alcohol طبعا طالما كل هدولة أساسا
+
+329
+00:29:38,650 --> 00:29:44,940
+OH كان في الديهيد واحدة وصارت OHصار Polyhydroxy
+
+330
+00:29:44,940 --> 00:29:49,740
+Alcohol اللي هو مار عليكم الـ Sorbitol اللي فيه ست
+
+331
+00:29:49,740 --> 00:29:54,060
+مجموعات OH بطل في ال الديهيد هو كان خمسة OH و
+
+332
+00:29:54,060 --> 00:29:55,840
+واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال
+
+333
+00:29:55,840 --> 00:29:56,120
+الديهيد و واحدة ال الديهيد و واحدة ال الديهيد و
+
+334
+00:29:56,120 --> 00:29:57,620
+واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال
+
+335
+00:29:57,620 --> 00:29:57,880
+الديهيد و واحدة ال الديهيد و واحدة ال الديهيد و
+
+336
+00:29:57,880 --> 00:29:59,140
+واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال
+
+337
+00:29:59,140 --> 00:30:01,540
+الديهيد و واحدة ال الديهيد و واحدة ال الديهيد و
+
+338
+00:30:01,540 --> 00:30:05,260
+واحدة ال الديهيد و واحدة ال الديهيد و واحدة ال
+
+339
+00:30:05,260 --> 00:30:11,460
+الديهيد و واحدة ال الديهيد و واحدة ال ال
+
+340
+00:30:13,000 --> 00:30:19,980
+أمنا و اتحول و أصار الكهول طب و اللي ضايل هنا إيش
+
+341
+00:30:19,980 --> 00:30:20,680
+رأيكوا فيه؟
+
+342
+00:30:24,980 --> 00:30:29,960
+كل ما هذا جزء منه صار alcohol بعوضه جزء من هذا
+
+343
+00:30:29,960 --> 00:30:34,760
+بيعمل ring opening في نهاية التفاعل ايش بتتوقعوا
+
+344
+00:30:34,760 --> 00:30:40,960
+نشوف ان هذا كله هينتهي يعني كل ما هذا بتحول بيروح
+
+345
+00:30:40,960 --> 00:30:45,780
+المسكر بيفتح كل ما هذا بتحول المسكر بيفتح هذه
+
+346
+00:30:45,780 --> 00:30:50,200
+القاعدة في الاتزان من اذكرنا ايش اسمها مرت عليكم
+
+347
+00:30:52,610 --> 00:30:56,330
+إعادة الإتزان، إنه الإتزان يعود إلى وضعه الطبيعي،
+
+348
+00:30:56,330 --> 00:31:01,290
+يعني دول الاتنين في اتزان، سحبنا هذا، فعلناه،
+
+349
+00:31:01,290 --> 00:31:04,710
+بيرود هذا يعمل اتزان من أول لجديد، سحبنا هذا،
+
+350
+00:31:04,710 --> 00:31:11,850
+بيرود هذا يفتح، لتشكله principalواضح؟ وبناء على
+
+351
+00:31:11,850 --> 00:31:17,210
+ذلك لو احنا جيبنالكوا سؤال في الامتحان قولنا هذا و
+
+352
+00:31:17,210 --> 00:31:22,150
+هذا في حالة اتزان اكملوا المعادلة هتكملونهان طيب
+
+353
+00:31:22,150 --> 00:31:26,930
+يا ترى لو اجينا سألناكوا ماحطيناش هذا من الأساس
+
+354
+00:31:26,930 --> 00:31:32,710
+كتبنالكوا بس هذا و reduction ايش هتعملونه؟ هتقولوا
+
+355
+00:31:32,710 --> 00:31:39,630
+مفهوم ضمنهإن هذا متزل مع الفاتح وبناء على ذلك
+
+356
+00:31:39,630 --> 00:31:43,710
+سيعمل reduction ويعطي هذا يعني لو رسمت أنا بس هذا
+
+357
+00:31:43,710 --> 00:31:49,070
+وقلت لكم H2و Catalyst في نهاية هذه الجوابلكن للفهم
+
+358
+00:31:49,070 --> 00:31:53,250
+كيف هذا الكلام بيصير بيقول ال .. ال cyclic صار إيه
+
+359
+00:31:53,250 --> 00:31:57,350
+ال cyclic؟ وصار إله reduction وكل ما هذا صار إله
+
+360
+00:31:57,350 --> 00:32:02,450
+reduction كل ما ال cyclic من أول و جديد بيفتح إلى
+
+361
+00:32:02,450 --> 00:32:08,840
+أن يتحول كل ال cyclic اللي موجود هنا إلىالى الكحول
+
+362
+00:32:08,840 --> 00:32:13,320
+اللى هو sorbitol واضح؟ لاحظوا معنا احنا الان
+
+363
+00:32:13,320 --> 00:32:20,360
+استفدنا من ايش؟ من مجموعة ال aldehyde الناس
+
+364
+00:32:20,360 --> 00:32:24,280
+اللى متذكرين كويس معنا لما شرحنا ال aldehyde قولنا
+
+365
+00:32:24,280 --> 00:32:28,180
+ال aldehyde واقف على نص السلم ايش يعني ال aldehyde
+
+366
+00:32:28,180 --> 00:32:34,900
+واقف على نص السلم او في نص الطريقالديهايد ممكن
+
+367
+00:32:34,900 --> 00:32:42,320
+تنزل لالكهول زي ما عملت هنا بال reduction و بنفس
+
+368
+00:32:42,320 --> 00:32:52,120
+الوقت ممكن تطلع فوق ل acid بال oxidation واضح؟
+
+369
+00:32:52,120 --> 00:32:58,320
+ماشي الترتيب اللي عندى ال alcohol الديهايد
+
+370
+00:32:59,060 --> 00:33:06,000
+acid أكسدة الكحول تعطي الديهايد أكسدة الديهايد
+
+371
+00:33:06,000 --> 00:33:11,020
+تعطي acid اختزال الكحول بيصير alcohol اختزال
+
+372
+00:33:11,020 --> 00:33:15,520
+الديهايد بيصير alcohol أكسدة الديهايد بيصير acid
+
+373
+00:33:15,520 --> 00:33:19,820
+الآن احنا التفاعل اللي موجود عندنا اختزال الديهايد
+
+374
+00:33:19,820 --> 00:33:25,990
+رجع لإيش؟ لالكحول طب لو عملنا أكسدة للديهايدهيصير
+
+375
+00:33:25,990 --> 00:33:30,990
+acid واضح الفكرة المشكلة في الموضوع كالقاتل انه
+
+376
+00:33:30,990 --> 00:33:35,470
+احنا قولنا اكسدة ال الديهيد بال oxidation بيصير
+
+377
+00:33:35,470 --> 00:33:40,150
+acid و اكسدة الكحول بعمل مؤكسد قوي برضه بيصير ايش
+
+378
+00:33:40,150 --> 00:33:44,410
+acid متذكرين لما أخدنا oxidation و في primary
+
+379
+00:33:44,410 --> 00:33:50,330
+alcohol حسب نوع المؤكسد تمام طيب هذا ال sugar ايش
+
+380
+00:33:50,330 --> 00:33:57,020
+موجود فيه في الديهيدو في كحولات بالذات ال primary
+
+381
+00:33:57,020 --> 00:34:01,540
+alcohol بناء على ذلك هتلاحظوا لما نيجي ندرس ال
+
+382
+00:34:01,540 --> 00:34:05,900
+acid ده انه هيمروا معناه حالتين ممكن عامل مؤكسد
+
+383
+00:34:05,900 --> 00:34:10,560
+نستعمله فقط acid ال aldehyde ل acid يعني يصير عندى
+
+384
+00:34:10,560 --> 00:34:15,240
+على الطرف هذا ايش acid عامل مؤكسد تاني اقوى منه ب
+
+385
+00:34:15,240 --> 00:34:19,400
+acid ال aldehyde و ب acid ال primary alcohol بيصير
+
+386
+00:34:19,400 --> 00:34:23,780
+عندى ايش dye acid انشوف هذا الكلام
+
+387
+00:34:26,870 --> 00:34:31,270
+لو أخدنا Sugar مع عامل مؤكسد خلّينا نقول ضعيف
+
+388
+00:34:31,270 --> 00:34:36,330
+لبرومين ميّه أو فضّه مع انحاس خلّينا نركز برومين
+
+389
+00:34:36,330 --> 00:34:41,670
+ووتر ب أكسد ال الديهايد بدل ما هو CHO بصير سيضه
+
+390
+00:34:41,670 --> 00:34:46,490
+بالموند OOH صار أسد، إذا لبرومين ووتر كام أكسدة
+
+391
+00:34:46,490 --> 00:34:51,010
+عمل عندى؟ أكسدة واحدة، بس أكسد ال الديهايد خلّاه
+
+392
+00:34:51,010 --> 00:34:55,250
+أيش أسد؟ الآن وقت الديجلوكوز بنقول عنه بصير
+
+393
+00:34:55,250 --> 00:35:00,030
+gluconic acidفال gluconic acid يحتوي على كام
+
+394
+00:35:00,030 --> 00:35:05,630
+مجموعة حمضية؟ واحدة عشانك لو انا اجيت سألتكم
+
+395
+00:35:05,630 --> 00:35:12,150
+gluconic acids contain one ولا two acidic groups؟
+
+396
+00:35:12,150 --> 00:35:20,130
+oneone الان نفس هذا المركب لو جبتله عامل مؤكسد قوي
+
+397
+00:35:20,130 --> 00:35:25,890
+أقوى من هذا بيروح ب أكسد الألديهيد والألكوهول وجدت
+
+398
+00:35:25,890 --> 00:35:32,790
+بده يعطيني كام أسد اتنين بيصير اتنين هذه الأكسدات
+
+399
+00:35:32,790 --> 00:35:36,730
+اللي بتصير الان ايش العامل المؤكسد الأقوى ال
+
+400
+00:35:36,730 --> 00:35:41,170
+nitric acid الألديهيد بيصير أسد وال primary
+
+401
+00:35:41,170 --> 00:35:47,740
+alcohol بتصير أسدصار عنده ايش؟ داي أسد وجدتها الدي
+
+402
+00:35:47,740 --> 00:35:53,080
+جلوكوز بيصير دي جلوكارك أسد لاحظوا الأول ايش كان
+
+403
+00:35:53,080 --> 00:35:58,580
+اسمه؟ جلوكونك جلوكونك يعني في one acidic group
+
+404
+00:35:58,580 --> 00:36:05,540
+جلوكارك يعني في two acidic groups أكسدنا في جزء ال
+
+405
+00:36:05,540 --> 00:36:10,950
+الديهايد وأكسدنا في جزء الكحولفبناء على العامل
+
+406
+00:36:10,950 --> 00:36:15,990
+المؤكسد ممكن نعمل أكسدة لجزء واحد بيصير عنده
+
+407
+00:36:15,990 --> 00:36:20,010
+glucanic acid اللي بأكسد جزء واحد هو ال bromine
+
+408
+00:36:20,010 --> 00:36:26,410
+water إذا استعملت نيترك أسد بأكسد ال aldehyde و
+
+409
+00:36:26,410 --> 00:36:31,550
+بأكسد ال primary alcohol بيصير عنده داي أسد
+
+410
+00:36:35,990 --> 00:36:41,490
+لأ في التجربة هي اللي بتأكسده واضح؟ هدول هو نظريا
+
+411
+00:36:41,490 --> 00:36:45,370
+لو بدى تأكسد حصير كيتون لأنه secondary alcohol بس
+
+412
+00:36:45,370 --> 00:36:50,550
+بالتجربة هدول اللي بتأكسده أخر
+
+413
+00:36:50,550 --> 00:36:59,330
+تفاعل ممكن امر علينا لو فعلناهذا الكحول تحديدا مع
+
+414
+00:36:59,330 --> 00:37:05,190
+.. أو هذا ال sugar عفوا Beta D-Glucobiranose مع
+
+415
+00:37:05,190 --> 00:37:10,210
+الميثانولاحنا فعلنا مع ال acid anhydride أعطانا
+
+416
+00:37:10,210 --> 00:37:14,470
+ester فعلنا مع ال acid halide أعطانا ether فعلنا
+
+417
+00:37:14,470 --> 00:37:17,830
+مع ال bromine أعطانا acid واحد فعلنا مع ال nitric
+
+418
+00:37:17,830 --> 00:37:22,370
+acid أعطانا two acids لو فعلنا مع الكحول في وجود
+
+419
+00:37:22,370 --> 00:37:27,830
+الميه شو بيعمل؟ بيشيل واحدة من ال OHS بنتقيها
+
+420
+00:37:27,830 --> 00:37:31,610
+انتقاءطبعا في ميكانيزم تفسر على الكلام لكن مش
+
+421
+00:37:31,610 --> 00:37:35,390
+موضوعنا و بيحل محلها ال o-methyl يعني بيشيل ال OH
+
+422
+00:37:35,390 --> 00:37:40,090
+و بيحط مكانها ايش o-methyl الان اي OH اللي بدو
+
+423
+00:37:40,090 --> 00:37:43,770
+يشيلها ال OH الجديدة اللي ع ال anomeric carbon
+
+424
+00:37:43,770 --> 00:37:47,110
+متذاكرين هذه اللي كانت مش chiral سمنها anomeric
+
+425
+00:37:47,110 --> 00:37:51,530
+carbon فالتفاعل مع الكحول زي ال methanol بيشيل هذه
+
+426
+00:37:51,530 --> 00:37:57,970
+ال OH بيشيل هذه ال OH و بيحط بدالها ايش o-methyl
+
+427
+00:37:58,410 --> 00:38:01,650
+طبعا هل يا ترى بيحط ال O مثل على ال Alpha ولا على
+
+428
+00:38:01,650 --> 00:38:05,370
+ال Beta؟ هيعمل خليط .. هيعمل خليط من الاتنين، احنا
+
+429
+00:38:05,370 --> 00:38:09,170
+راسمين واحد منهم واضح بيحطوا على ال Alpha و ال
+
+430
+00:38:09,170 --> 00:38:13,410
+Beta لما تكون ال O مثل ال A4، هذا Beta، لو كانت
+
+431
+00:38:13,410 --> 00:38:19,070
+لتحت Alpha الآن هذه المركبات اللي بدل ما كانت ال
+
+432
+00:38:19,070 --> 00:38:25,110
+Oxygen على ال Anomeric Carbon OH صارت OR بنسميها
+
+433
+00:38:25,110 --> 00:38:31,310
+احنا ايش؟ Glycosidesفلو إجينا سألنا شو هم ال
+
+434
+00:38:31,310 --> 00:38:37,230
+glycosides؟ ال glycosides هم السكريات اللي قبدلت
+
+435
+00:38:37,230 --> 00:38:45,850
+فيهم ال OH صارت OR واضح؟بدل ما كانت او متصلة ب اتش
+
+436
+00:38:45,850 --> 00:38:52,390
+صارت او متصلة بار بنسميهم glycosides طبعا في أمثلة
+
+437
+00:38:52,390 --> 00:38:55,930
+هتمروا معاكم بعدين في أماكن تانية أنه يا تورا لو
+
+438
+00:38:55,930 --> 00:39:01,690
+حطينا هنا ال متصلة باربنصير نقول عنها
+
+439
+00:39:01,690 --> 00:39:06,150
+anoglycosides يعني غلايكو سايتس بس من خلال ذرة إيش
+
+440
+00:39:06,150 --> 00:39:11,130
+نيتروجين بس إذا قولنا كلمة غلايكو سايتس عادية معنى
+
+441
+00:39:11,130 --> 00:39:15,750
+ذلك أنا بدي سكر و مرسوم عليه على هذا الموقع تحديدا
+
+442
+00:39:15,750 --> 00:39:20,670
+OR لاحظوا أن التفاعل مع الميثانول ما بيغير هدول ال
+
+443
+00:39:20,670 --> 00:39:26,420
+OHSفقط بيغير ال OH اللي ع ال anomeric carbon
+
+444
+00:39:26,420 --> 00:39:31,220
+بيخليها ايش OR والمركبات اللي فيها OR ع ال
+
+445
+00:39:31,220 --> 00:39:36,080
+anomeric carbon بنقول عنها glycosides هذه الرابطة
+
+446
+00:39:36,080 --> 00:39:38,720
+اللي بين ال anomeric carbon و ال oxygen اللي هي
+
+447
+00:39:38,720 --> 00:39:43,760
+carbon O مثل او carbon OR بنسميها glycosidic bond
+
+448
+00:39:43,760 --> 00:39:49,740
+هذه الرابطة الجديدة اللي كانت متصلةمع ال OH صارت
+
+449
+00:39:49,740 --> 00:39:55,840
+متصلة مع ايش؟ مع ال OR شو بنسميها؟ Glycosidic bond
+
+450
+00:39:55,840 --> 00:40:03,080
+موجودة ويلها أهمية جزء كبير من أهمية هذه المنطقة
+
+451
+00:40:03,080 --> 00:40:07,660
+أنه لما بعدك السكريات بدهم يبدوا يعملوا dimers مع
+
+452
+00:40:07,660 --> 00:40:11,560
+بعض يتحدوا هنلاحظ فائدة هذه ال glycosidic bond
+
+453
+00:40:11,560 --> 00:40:15,000
+لأنه بربطوا من خلالها واضح؟ يربطوا مع بعض من
+
+454
+00:40:15,000 --> 00:40:22,700
+خلالهالو اجينا رسمنالكم مركب هذا sugar من
+
+455
+00:40:22,700 --> 00:40:27,900
+الجولوكوز هل هذا يا تورا فيه glycosidic bond ولا
+
+456
+00:40:27,900 --> 00:40:38,380
+لأ تطلع عليه هاي carbon اوCarbon اذا هذا المركب
+
+457
+00:40:38,380 --> 00:40:43,600
+اللى اسمه ساليسين من شجر الصفصاف لما كانوا بيغلو
+
+458
+00:40:43,600 --> 00:40:47,140
+شجر الصفصاف بيطلع هذا المركب كانوا ياخدوله الصداع
+
+459
+00:40:47,140 --> 00:40:52,440
+الناس الزمان فيه glycosidic bond لاحظوا اللى
+
+460
+00:40:52,440 --> 00:40:58,900
+بتتأمل فيه بشكل بشكل قوى هتلاحظ ان هذا بيشبه ايش
+
+461
+00:40:58,900 --> 00:41:02,040
+الاسميرين
+
+462
+00:41:03,920 --> 00:41:10,960
+تذكروا الاسبيرين كان بنزينة و COOH و CH2O و بعدين
+
+463
+00:41:10,960 --> 00:41:15,500
+أوهانة OH نخليها OCOC double bond Oacetyl يعني
+
+464
+00:41:15,500 --> 00:41:20,020
+وجود البنزينة و ال orthoposition هذا بشبه أي دوة؟
+
+465
+00:41:20,020 --> 00:41:25,580
+بشبه الاسبيرين هذا مثلا منتج طبيعي فيه glycosidic
+
+466
+00:41:25,580 --> 00:41:30,170
+bond ولا لأ؟ هيهالما تكون هذه الرابطة اللي هنا مش
+
+467
+00:41:30,170 --> 00:41:36,350
+OH OR بنقول هذا إيش المركب glycoside و ال bond إيش
+
+468
+00:41:36,350 --> 00:41:43,650
+بنوصفها؟ بنقول عنها glycosidic bond الآن زي ما
+
+469
+00:41:43,650 --> 00:41:48,330
+اتفقنا أن ال glycosides وين بيفيدوني كتير أنا؟لما
+
+470
+00:41:48,330 --> 00:41:53,550
+بدى ادمج سكارين مع بعض لما بدى ادمج سكارين مع بعض
+
+471
+00:41:53,550 --> 00:41:57,390
+هاجي على هذه ال oxygen و اصير اربط من خلالها الان
+
+472
+00:41:57,390 --> 00:42:01,410
+دمج سكارين مع بعض قصة طويلة اش السكارين و اش
+
+473
+00:42:01,410 --> 00:42:06,370
+السكارتونة اللى بده يطلع عندى هو ملتوز سكاروز سيلو
+
+474
+00:42:06,370 --> 00:42:11,490
+بيوز كذا كذا موضوع كبير بحاجة الى ان نفردله ان شاء
+
+475
+00:42:11,490 --> 00:42:17,580
+الله محاضرة كاملة بس لاحظوا مباشرةهتلاحظوا أنه أول
+
+476
+00:42:17,580 --> 00:42:22,580
+ما بدي أحكي عن سكارين دمجتهم هاي رابط هانا تطلعوا
+
+477
+00:42:22,580 --> 00:42:27,980
+عليها carbon او carbon ال glycosidic bond ولا لأ
+
+478
+00:42:27,980 --> 00:42:33,520
+عشانك احنا أخدنا ال glycosides لأنه في ال
+
+479
+00:42:33,520 --> 00:42:37,620
+disaccharides هتلاقوا عندي ال glycosidic bond طبعا
+
+480
+00:42:37,620 --> 00:42:41,760
+إيش السكارين اللي بيندمجوا و إيش السكر ثناء اللي
+
+481
+00:42:41,760 --> 00:42:46,920
+بيطلع هذا بيكون موضوعالمحاضرة القادمة ان شاء الله
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hQvSO3g5Za4_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hQvSO3g5Za4_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..4c342af0b63b9b65c1322fa5acc09dd6d0cbd7da
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/hQvSO3g5Za4_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3925, "start": 19.49, "end": 39.25, "text": "بسم الله الرحمن الرحيم المرة الماضية بدينا في موضوع ال carbohydrates بدينا في موضوع ال carbohydrates وقولنا انه امكوانين من carbon و ما .. و بعدين طبعا بدينا في ال sugars", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 47525, 1829, 8315, 8978, 3714, 2407, 11242, 45367, 2423, 36817, 47525, 1829, 8315, 8978, 3714, 2407, 11242, 45367, 2423, 36817, 4032, 39648, 8315, 16472, 3224, 1975, 2304, 4117, 2407, 7649, 9957, 9154, 5954, 4032, 19446, 4386, 4032, 39182, 9957, 23032, 3555, 3615, 995, 47525, 1829, 8315, 8978, 2423, 37551], "avg_logprob": -0.14636230375617743, "compression_ratio": 1.8243243243243243, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 19.49, "end": 19.83, "word": "بسم", "probability": 0.929931640625}, {"start": 19.83, "end": 19.97, "word": " الله", "probability": 0.9697265625}, {"start": 19.97, "end": 20.31, "word": " الرحمن", 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"text": "خمسة كايرال سنترز وجدت بنتوقع انه لسكر مكون من ست ذرات كربون بهذا الشكل يكون عنده اتنين و تلاتين ايزومات طبعا لما تمت عملية الاغلاق لما تمت عملية اغلاق الالكول على ال الديهايد", "tokens": [9778, 2304, 3794, 3660, 9122, 995, 13546, 6027, 8608, 29399, 2288, 11622, 49610, 3215, 2655, 4724, 29399, 30543, 3615, 16472, 3224, 5296, 3794, 37983, 3714, 4117, 2407, 1863, 9154, 8608, 2655, 29910, 2288, 9307, 9122, 25513, 11536, 39627, 15730, 25124, 28820, 7251, 30544, 43242, 3224, 1975, 2655, 1863, 9957, 4032, 6055, 1211, 9307, 9957, 1975, 1829, 11622, 20498, 9307, 23032, 3555, 3615, 995, 5296, 15042, 46811, 2655, 6225, 42213, 10632, 2423, 5718, 118, 15040, 4587, 5296, 15042, 46811, 2655, 6225, 42213, 10632, 1975, 17082, 15040, 4587, 2423, 6027, 4117, 12610, 15844, 2423, 2423, 16254, 11296, 25708], "avg_logprob": -0.2453286033315757, "compression_ratio": 1.8705882352941177, "no_speech_prob": 0.0, "words": [{"start": 181.62, "end": 182.26, "word": "خمسة", "probability": 0.8182373046875}, {"start": 182.26, "end": 182.74, "word": " كايرال", "probability": 0.626220703125}, {"start": 182.74, "end": 183.32, "word": " سنترز", "probability": 0.6751708984375}, {"start": 183.32, "end": 183.7, "word": " وجدت", "probability": 0.601318359375}, {"start": 183.7, "end": 184.42, "word": " بنتوقع", "probability": 0.7833251953125}, {"start": 184.42, "end": 185.04, "word": " انه", "probability": 0.609619140625}, {"start": 185.04, "end": 186.58, "word": " لسكر", "probability": 0.8326822916666666}, {"start": 186.58, "end": 187.08, "word": " مكون", "probability": 0.6051025390625}, {"start": 187.08, "end": 187.28, "word": " من", "probability": 0.98779296875}, {"start": 187.28, "end": 187.56, "word": " ست", "probability": 0.81298828125}, {"start": 187.56, "end": 188.0, "word": " ذرات", "probability": 0.81591796875}, {"start": 188.0, "end": 188.48, "word": " كربون", "probability": 0.953125}, {"start": 188.48, "end": 188.94, "word": " بهذا", "probability": 0.794189453125}, {"start": 188.94, "end": 189.46, "word": " الشكل", "probability": 0.9921875}, {"start": 189.46, "end": 190.14, "word": " يكون", "probability": 0.9326171875}, {"start": 190.14, "end": 190.82, "word": " عنده", "probability": 0.904541015625}, {"start": 190.82, "end": 191.36, "word": " اتنين", "probability": 0.86572265625}, {"start": 191.36, "end": 191.46, "word": " و", "probability": 0.736328125}, {"start": 191.46, "end": 192.14, "word": " تلاتين", "probability": 0.947265625}, {"start": 192.14, "end": 193.36, "word": " ايزومات", "probability": 0.68916015625}, {"start": 193.36, "end": 194.16, "word": " طبعا", "probability": 0.9464111328125}, {"start": 194.16, "end": 194.62, "word": " لما", "probability": 0.879638671875}, {"start": 194.62, "end": 195.08, "word": " تمت", "probability": 0.983154296875}, {"start": 195.08, "end": 195.6, "word": " عملية", "probability": 0.986328125}, {"start": 195.6, "end": 196.48, "word": " الاغلاق", "probability": 0.781884765625}, {"start": 196.48, "end": 196.9, "word": " لما", "probability": 0.73291015625}, {"start": 196.9, "end": 197.32, "word": " تمت", "probability": 0.983154296875}, {"start": 197.32, "end": 197.76, "word": " عملية", "probability": 0.9754231770833334}, {"start": 197.76, "end": 198.3, "word": " اغلاق", "probability": 0.984130859375}, {"start": 198.3, "end": 199.2, "word": " الالكول", "probability": 0.7208251953125}, {"start": 199.2, "end": 200.24, "word": " على", "probability": 0.86669921875}, {"start": 200.24, "end": 200.58, "word": " ال", "probability": 0.9501953125}, {"start": 200.58, "end": 201.54, "word": " الديهايد", "probability": 0.703857421875}], "temperature": 1.0}, {"id": 9, "seek": 21844, "start": 201.96, "end": 218.44, "text": "بهذا الشكل اتكون عندى هنا ال new chiral center وقولنا الكاربون هذه اللى بتعمل ال new chiral center شو بنسميها احنا انوميرك كاربون الان معنى new chiral center ان هو ال OH هذى بنسميها اما لأعلى", "tokens": [3555, 3224, 15730, 25124, 28820, 1975, 2655, 30544, 43242, 7578, 34105, 2423, 777, 23782, 304, 3056, 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0.86181640625}, {"start": 661.83, "end": 662.61, "word": " الان", "probability": 0.763916015625}, {"start": 662.61, "end": 663.33, "word": " بالشكل", "probability": 0.89013671875}, {"start": 663.33, "end": 663.83, "word": " هذا", "probability": 0.93994140625}, {"start": 663.83, "end": 665.27, "word": " بتكون", "probability": 0.899169921875}, {"start": 665.27, "end": 665.99, "word": " ايش؟", "probability": 0.835205078125}], "temperature": 1.0}, {"id": 30, "seek": 68234, "start": 667.32, "end": 682.34, "text": "أكسيال طبعا ال equatorial الفراغ اللي حواليها أفضل من الفراغ اللي حواليه الأكسيال الأكسيال crowded لاحظوا فيها steric hindrance فيها ممانعة فراغية مالهاش واسعة واضح", "tokens": [10721, 4117, 3794, 1829, 6027, 23032, 3555, 3615, 995, 2423, 45544, 831, 27188, 2288, 5718, 118, 13672, 1829, 11331, 2407, 6027, 1829, 11296, 5551, 5172, 11242, 1211, 9154, 27188, 2288, 5718, 118, 13672, 1829, 11331, 2407, 6027, 1829, 3224, 16247, 4117, 3794, 1829, 6027, 16247, 4117, 3794, 1829, 6027, 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{"start": 673.14, "end": 673.3, "word": " من", "probability": 0.9912109375}, {"start": 673.3, "end": 673.7, "word": " الفراغ", "probability": 0.989501953125}, {"start": 673.7, "end": 673.82, "word": " اللي", "probability": 0.981689453125}, {"start": 673.82, "end": 674.22, "word": " حواليه", "probability": 0.90224609375}, {"start": 674.22, "end": 674.7, "word": " الأكسيال", "probability": 0.8065185546875}, {"start": 674.7, "end": 675.6, "word": " الأكسيال", "probability": 0.82236328125}, {"start": 675.6, "end": 677.3, "word": " crowded", "probability": 0.431884765625}, {"start": 677.3, "end": 677.96, "word": " لاحظوا", "probability": 0.89306640625}, {"start": 677.96, "end": 678.18, "word": " فيها", "probability": 0.93603515625}, {"start": 678.18, "end": 678.76, "word": " steric", "probability": 0.61932373046875}, {"start": 678.76, "end": 679.34, "word": " hindrance", "probability": 0.89306640625}, {"start": 679.34, "end": 679.68, "word": " فيها", "probability": 0.806640625}, {"start": 679.68, "end": 680.18, "word": " ممانعة", "probability": 0.9671630859375}, {"start": 680.18, "end": 680.64, "word": " فراغية", "probability": 0.91748046875}, {"start": 680.64, "end": 681.02, "word": " مالهاش", "probability": 0.79315185546875}, {"start": 681.02, "end": 681.6, "word": " واسعة", "probability": 0.8448893229166666}, {"start": 681.6, "end": 682.34, "word": " واضح", "probability": 0.9150390625}], "temperature": 1.0}, {"id": 31, "seek": 70760, "start": 682.56, "end": 707.6, "text": "الـ equatorial مترايحة أكثر ولذلك هذا الشكل ال equatorial هو ال beta هذا الشكل ال axial هو ال alpha عشان هيك ال beta بيكون more stable لأن ال OH اللي موجودة فيه ال new chiral center لأنميرك كربون بتكون مترايحة من الناحية الفرغية مافيش حد مضايقها واضح؟ لحظوا هذه ال OH الجديدة اللي اتكونت عندى", "tokens": [6027, 39184, 45544, 831, 44650, 23557, 1829, 5016, 3660, 5551, 4117, 49115, 35525, 8848, 23275, 23758, 25124, 28820, 2423, 45544, 831, 31439, 2423, 9861, 23758, 25124, 28820, 2423, 46851, 31439, 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{"start": 701.28, "end": 701.66, "word": " الناحية", "probability": 0.8551025390625}, {"start": 701.66, "end": 702.16, "word": " الفرغية", "probability": 0.80841064453125}, {"start": 702.16, "end": 702.66, "word": " مافيش", "probability": 0.7388509114583334}, {"start": 702.66, "end": 702.98, "word": " حد", "probability": 0.98388671875}, {"start": 702.98, "end": 703.86, "word": " مضايقها", "probability": 0.81220703125}, {"start": 703.86, "end": 704.82, "word": " واضح؟", "probability": 0.74761962890625}, {"start": 704.82, "end": 705.2, "word": " لحظوا", "probability": 0.8824462890625}, {"start": 705.2, "end": 705.36, "word": " هذه", "probability": 0.7958984375}, {"start": 705.36, "end": 705.5, "word": " ال", "probability": 0.9736328125}, {"start": 705.5, "end": 705.84, "word": " OH", "probability": 0.6865234375}, {"start": 705.84, "end": 706.46, "word": " الجديدة", "probability": 0.94140625}, {"start": 706.46, "end": 706.62, "word": " اللي", "probability": 0.8955078125}, {"start": 706.62, "end": 707.14, "word": " اتكونت", "probability": 0.9078369140625}, {"start": 707.14, "end": 707.6, "word": " عندى", "probability": 0.851318359375}], "temperature": 1.0}, {"id": 32, "seek": 73696, "start": 708.02, "end": 736.96, "text": "الان في ال equatorial form هي مترايحة في ال axial form مش مترايحة في جنبها مجموعات تانية بتعمل ازدحام فراغي فلما نكون بدنا نفسر ليش ال beta موجودة اكثر من ال alpha بنقول because the beta o h is found in the equatorial position لان موجودة في ال equatorial ال equatorial is not a crowded position", "tokens": [6027, 7649, 8978, 2423, 45544, 831, 1254, 39896, 44650, 23557, 1829, 5016, 3660, 8978, 2423, 46851, 1254, 37893, 44650, 23557, 1829, 5016, 3660, 8978, 10874, 1863, 3555, 11296, 3714, 7435, 2304, 45367, 9307, 6055, 7649, 10632, 39894, 25957, 1211, 1975, 11622, 3215, 5016, 10943, 6156, 2288, 5718, 118, 1829, 6156, 1211, 15042, 8717, 30544, 47525, 8315, 8717, 36178, 2288, 32239, 8592, 2423, 9861, 3714, 29245, 23328, 3660, 1975, 4117, 49115, 9154, 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{"start": 1094.0, "end": 1094.88, "word": " الكيتون", "probability": 0.8707682291666666}, {"start": 1094.88, "end": 1095.9, "word": " خلينا", "probability": 0.7647705078125}, {"start": 1095.9, "end": 1096.28, "word": " ناخد", "probability": 0.99072265625}, {"start": 1096.28, "end": 1096.82, "word": " مثال", "probability": 0.88525390625}, {"start": 1096.82, "end": 1097.32, "word": " لو", "probability": 0.8994140625}, {"start": 1097.32, "end": 1097.88, "word": " اخدنا", "probability": 0.857177734375}, {"start": 1097.88, "end": 1098.38, "word": " مثلا", "probability": 0.94775390625}, {"start": 1098.38, "end": 1099.1, "word": " السكر", "probability": 0.9443359375}, {"start": 1099.1, "end": 1100.04, "word": " المسكر", "probability": 0.8473307291666666}], "temperature": 1.0}, {"id": 48, "seek": 111330, "start": 1101.06, "end": 1113.3, "text": "اللي قلنا عنه بيتا دي جلوكو بيرانوز وين رسمينه على هيئة الكرسي هل هذا لما سكر لما صار بيرانوز ضال فيه الديهايد؟", "tokens": [6027, 20292, 12174, 1211, 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"end": 1104.08, "word": " بيرانوز", "probability": 0.8859375}, {"start": 1104.08, "end": 1104.32, "word": " وين", "probability": 0.5067138671875}, {"start": 1104.32, "end": 1105.0, "word": " رسمينه", "probability": 0.73553466796875}, {"start": 1105.0, "end": 1105.46, "word": " على", "probability": 0.88916015625}, {"start": 1105.46, "end": 1105.92, "word": " هيئة", "probability": 0.88330078125}, {"start": 1105.92, "end": 1107.0, "word": " الكرسي", "probability": 0.939453125}, {"start": 1107.0, "end": 1107.46, "word": " هل", "probability": 0.7030029296875}, {"start": 1107.46, "end": 1107.8, "word": " هذا", "probability": 0.90869140625}, {"start": 1107.8, "end": 1108.46, "word": " لما", "probability": 0.85498046875}, {"start": 1108.46, "end": 1109.08, "word": " سكر", "probability": 0.800537109375}, {"start": 1109.08, "end": 1109.42, "word": " لما", "probability": 0.797607421875}, {"start": 1109.42, "end": 1109.72, "word": " صار", "probability": 0.918212890625}, {"start": 1109.72, "end": 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هذا التفاعل البسيط أن الكحول بيحل محل اليود ولذلك ملخص هدول التنتين أن الكحول مع الانهيدريد بيعطيني إيثر للشجر والكحول مع ال مثل أيودايد بيعطيني إيثر", "tokens": [3224, 1829, 3615, 9566, 1829, 22653, 9122, 2304, 11933, 1829, 49115, 22807, 16490, 2304, 3794, 11933, 1829, 12984, 2288, 9307, 50113, 1211, 1975, 2407, 9122, 9640, 3555, 11536, 50113, 1211, 1975, 2407, 9122, 9640, 3555, 11536, 50113, 1211, 1975, 2407, 9122, 9640, 3555, 11536, 50113, 1211, 1975, 2407, 9122, 9640, 3555, 11536, 50113, 1211, 1975, 2407, 9122, 9640, 3555, 11536, 4032, 46958, 5016, 27188, 4117, 25720, 22807, 31439, 8717, 36178, 23758, 16712, 5172, 995, 30241, 29739, 3794, 1829, 9566, 14739, 33251, 5016, 12610, 4724, 1829, 5016, 1211, 3714, 5016, 1211, 45595, 23328, 35525, 8848, 23275, 3714, 1211, 9778, 9381, 8032, 3215, 12610, 16712, 29399, 9957, 14739, 33251, 5016, 12610, 20449, 2423, 7649, 3224, 25708, 2288, 25708, 4724, 40228, 9566, 1829, 22653, 11933, 1829, 49115, 24976, 8592, 7435, 2288, 16070, 4117, 5016, 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بنسميها؟ Glycosidic bond موجودة ويلها أهمية جزء كبير من أهمية هذه المنطقة أنه لما بعدك السكريات بدهم يبدوا يعملوا dimers مع بعض يتحدوا هنلاحظ فائدة هذه ال glycosidic bond لأنه بربطوا من خلالها واضح؟ يربطوا مع بعض من خلالها", "tokens": [2304, 3615, 2423, 13931, 20328, 9640, 2655, 44650, 36520, 3660, 20449, 1975, 1829, 8592, 22807, 20449, 2423, 19654, 13412, 2407, 44945, 38251, 1829, 11296, 22807, 460, 356, 6877, 327, 299, 6086, 3714, 29245, 23328, 3660, 4032, 26895, 11296, 5551, 16095, 10632, 10874, 11622, 38207, 9122, 3555, 13546, 9154, 5551, 16095, 10632, 29538, 9673, 1863, 9566, 28671, 14739, 3224, 5296, 15042, 39182, 4117, 21136, 4117, 16572, 9307, 47525, 16095, 7251, 44510, 14407, 7251, 25957, 1211, 14407, 5013, 433, 20449, 45030, 11242, 7251, 2655, 24401, 14407, 8032, 1863, 15040, 5016, 19913, 6156, 16373, 41891, 29538, 2423, 22633, 6877, 327, 299, 6086, 5296, 33456, 3224, 4724, 25513, 9566, 14407, 9154, 16490, 1211, 6027, 11296, 4032, 46958, 5016, 22807, 7251, 25513, 9566, 14407, 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"probability": 0.9151611328125}, {"start": 2408.7, "end": 2409.54, "word": " هنلاحظ", "probability": 0.9154296875}, {"start": 2409.54, "end": 2410.14, "word": " فائدة", "probability": 0.9817708333333334}, {"start": 2410.14, "end": 2410.48, "word": " هذه", "probability": 0.3974609375}, {"start": 2410.48, "end": 2410.58, "word": " ال", "probability": 0.8076171875}, {"start": 2410.58, "end": 2411.42, "word": " glycosidic", "probability": 0.8731689453125}, {"start": 2411.42, "end": 2411.56, "word": " bond", "probability": 0.95166015625}, {"start": 2411.56, "end": 2411.88, "word": " لأنه", "probability": 0.8401692708333334}, {"start": 2411.88, "end": 2412.26, "word": " بربطوا", "probability": 0.8045654296875}, {"start": 2412.26, "end": 2412.42, "word": " من", "probability": 0.99560546875}, {"start": 2412.42, "end": 2413.02, "word": " خلالها", "probability": 0.9967041015625}, {"start": 2413.02, "end": 2414.08, "word": " واضح؟", "probability": 0.921142578125}, {"start": 2414.08, "end": 2414.52, "word": " يربطوا", "probability": 0.925537109375}, {"start": 2414.52, "end": 2414.62, "word": " مع", "probability": 0.99072265625}, {"start": 2414.62, "end": 2414.86, "word": " بعض", "probability": 0.998291015625}, {"start": 2414.86, "end": 2415.0, "word": " من", "probability": 0.998046875}, {"start": 2415.0, "end": 2415.44, "word": " خلالها", "probability": 0.9954833984375}], "temperature": 1.0}, {"id": 103, "seek": 243448, "start": 2417.16, "end": 2434.48, "text": "لو اجينا رسمنالكم مركب هذا sugar من الجولوكوز هل هذا يا تورا فيه glycosidic bond ولا لأ تطلع عليه هاي carbon او", "tokens": [1211, 2407, 1975, 7435, 1829, 8315, 12602, 38251, 8315, 23275, 2304, 3714, 31747, 3555, 23758, 5076, 9154, 25724, 12610, 2407, 4117, 2407, 11622, 8032, 1211, 23758, 35186, 6055, 13063, 995, 8978, 3224, 22633, 6877, 327, 299, 6086, 49429, 5296, 10721, 6055, 9566, 1211, 3615, 47356, 8032, 47302, 5954, 1975, 2407], "avg_logprob": -0.321997556031919, "compression_ratio": 1.2941176470588236, 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الصفصاف لما كانوا بيغلو شجر الصفصاف بيطلع هذا المركب كانوا ياخدوله الصداع الناس الزمان فيه glycosidic bond لاحظوا اللى بتتأمل فيه بشكل بشكل قوى هتلاحظ ان هذا بيشبه ايش الاسميرين", "tokens": [24437, 4351, 1975, 15730, 23758, 9673, 31747, 3555, 13672, 7578, 24525, 2304, 3224, 8608, 6027, 1829, 3794, 9957, 9154, 13412, 7435, 2288, 31767, 5172, 9381, 31845, 5296, 15042, 25961, 14407, 4724, 1829, 17082, 1211, 2407, 13412, 7435, 2288, 31767, 5172, 9381, 31845, 4724, 1829, 9566, 1211, 3615, 23758, 9673, 31747, 3555, 25961, 14407, 7251, 47283, 3215, 12610, 3224, 31767, 28259, 3615, 2423, 8315, 3794, 6024, 110, 2304, 7649, 8978, 3224, 22633, 6877, 327, 299, 6086, 20193, 5016, 19913, 14407, 13672, 7578, 39894, 2655, 10721, 42213, 8978, 3224, 4724, 8592, 28820, 4724, 8592, 28820, 12174, 2407, 7578, 8032, 2655, 15040, 5016, 19913, 16472, 23758, 4724, 1829, 8592, 3555, 3224, 1975, 1829, 8592, 2423, 32277, 2304, 13546, 9957], "avg_logprob": -0.19070512616736257, "compression_ratio": 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"probability": 0.922607421875}, {"start": 2523.33, "end": 2523.73, "word": " هو", "probability": 0.919921875}, {"start": 2523.73, "end": 2524.39, "word": " ملتوز", "probability": 0.810546875}, {"start": 2524.39, "end": 2525.51, "word": " سكاروز", "probability": 0.7541015625}, {"start": 2525.51, "end": 2526.37, "word": " سيلو", "probability": 0.7128092447916666}, {"start": 2526.37, "end": 2526.83, "word": " بيوز", "probability": 0.8289794921875}, {"start": 2526.83, "end": 2527.13, "word": " كذا", "probability": 0.856689453125}, {"start": 2527.13, "end": 2527.53, "word": " كذا", "probability": 0.952880859375}, {"start": 2527.53, "end": 2528.49, "word": " موضوع", "probability": 0.98388671875}, {"start": 2528.49, "end": 2528.99, "word": " كبير", "probability": 0.9970703125}, {"start": 2528.99, "end": 2529.59, "word": " بحاجة", "probability": 0.989501953125}, {"start": 2529.59, "end": 2529.87, "word": " الى", "probability": 0.673095703125}, {"start": 2529.87, "end": 2530.07, "word": " ان", "probability": 0.75537109375}, {"start": 2530.07, "end": 2531.13, "word": " نفردله", "probability": 0.749365234375}, {"start": 2531.13, "end": 2531.29, "word": " ان", "probability": 0.80322265625}, {"start": 2531.29, "end": 2531.49, "word": " شاء", "probability": 0.961181640625}, {"start": 2531.49, "end": 2531.63, "word": " الله", "probability": 0.9521484375}, {"start": 2531.63, "end": 2532.67, "word": " محاضرة", "probability": 0.9832763671875}, {"start": 2532.67, "end": 2533.53, "word": " كاملة", "probability": 0.9851888020833334}, {"start": 2533.53, "end": 2533.99, "word": " بس", "probability": 0.937255859375}, {"start": 2533.99, "end": 2534.33, "word": " لاحظوا", "probability": 0.85211181640625}, {"start": 2534.33, "end": 2535.19, "word": " مباشرة", "probability": 0.9921875}], "temperature": 1.0}, {"id": 108, "seek": 256382, "start": 2536.4, "end": 2563.82, "text": "هتلاحظوا أنه أول ما بدي أحكي عن سكارين دمجتهم هاي رابط هانا تطلعوا عليها carbon او carbon ال glycosidic bond ولا لأ عشانك احنا أخدنا ال glycosides لأنه في ال disaccharides هتلاقوا عندي ال glycosidic bond طبعا إيش السكارين اللي بيندمجوا و إيش السكر ثناء اللي بيطلع هذا بيكون موضوع", "tokens": [3224, 2655, 15040, 5016, 19913, 14407, 14739, 3224, 5551, 12610, 19446, 4724, 16254, 5551, 5016, 4117, 1829, 18871, 8608, 4117, 9640, 9957, 11778, 2304, 7435, 2655, 16095, 8032, 47302, 12602, 16758, 9566, 8032, 7649, 995, 6055, 9566, 1211, 3615, 14407, 25894, 11296, 5954, 1975, 2407, 5954, 2423, 22633, 6877, 327, 299, 6086, 49429, 5296, 10721, 6225, 8592, 7649, 4117, 1975, 5016, 8315, 5551, 9778, 3215, 8315, 2423, 22633, 6877, 1875, 5296, 33456, 3224, 8978, 2423, 717, 326, 7374, 1875, 8032, 2655, 15040, 4587, 14407, 43242, 1829, 2423, 22633, 6877, 327, 299, 6086, 23032, 3555, 3615, 995, 11933, 1829, 8592, 21136, 4117, 9640, 9957, 13672, 1829, 49374, 40448, 7435, 14407, 4032, 11933, 1829, 8592, 21136, 37983, 38637, 1863, 16606, 13672, 1829, 4724, 1829, 9566, 1211, 3615, 23758, 4724, 1829, 30544, 3714, 2407, 11242, 45367], "avg_logprob": -0.23052704545544156, "compression_ratio": 1.8278688524590163, "no_speech_prob": 0.0, "words": [{"start": 2536.4, "end": 2537.14, "word": "هتلاحظوا", "probability": 0.9366861979166666}, {"start": 2537.14, "end": 2537.38, "word": " أنه", "probability": 0.46435546875}, {"start": 2537.38, "end": 2537.58, "word": " أول", "probability": 0.8916015625}, {"start": 2537.58, "end": 2537.7, "word": " ما", "probability": 0.9423828125}, {"start": 2537.7, "end": 2537.92, "word": " بدي", "probability": 0.6517333984375}, {"start": 2537.92, "end": 2538.16, "word": " أحكي", "probability": 0.9415283203125}, {"start": 2538.16, "end": 2538.32, "word": " عن", "probability": 0.97802734375}, {"start": 2538.32, "end": 2538.82, "word": " سكارين", "probability": 0.70526123046875}, {"start": 2538.82, "end": 2539.68, "word": " دمجتهم", "probability": 0.9412109375}, {"start": 2539.68, "end": 2541.56, "word": " هاي", "probability": 0.586181640625}, {"start": 2541.56, "end": 2541.94, "word": " رابط", "probability": 0.9915364583333334}, {"start": 2541.94, "end": 2542.26, "word": " هانا", "probability": 0.4105224609375}, {"start": 2542.26, "end": 2542.58, "word": " تطلعوا", "probability": 0.7849609375}, {"start": 2542.58, "end": 2543.34, "word": " عليها", "probability": 0.99462890625}, {"start": 2543.34, "end": 2544.64, "word": " carbon", "probability": 0.5322265625}, {"start": 2544.64, "end": 2545.22, "word": " او", "probability": 0.6650390625}, {"start": 2545.22, "end": 2546.08, "word": " carbon", "probability": 0.8818359375}, {"start": 2546.08, "end": 2546.38, "word": " ال", "probability": 0.0518798828125}, {"start": 2546.38, "end": 2547.16, "word": " glycosidic", "probability": 0.8140869140625}, {"start": 2547.16, "end": 2547.4, "word": " bond", "probability": 0.904296875}, {"start": 2547.4, "end": 2547.62, "word": " ولا", "probability": 0.69970703125}, {"start": 2547.62, "end": 2547.98, "word": " لأ", "probability": 0.9072265625}, {"start": 2547.98, "end": 2548.8, "word": " عشانك", "probability": 0.7452392578125}, {"start": 2548.8, "end": 2549.06, "word": " احنا", "probability": 0.8231608072916666}, {"start": 2549.06, "end": 2549.44, "word": " أخدنا", "probability": 0.9404296875}, {"start": 2549.44, "end": 2549.56, "word": " ال", "probability": 0.91552734375}, {"start": 2549.56, "end": 2550.42, "word": " glycosides", "probability": 0.9576822916666666}, {"start": 2550.42, "end": 2552.44, "word": " لأنه", "probability": 0.8230794270833334}, {"start": 2552.44, "end": 2553.22, "word": " في", "probability": 0.9716796875}, {"start": 2553.22, "end": 2553.52, "word": " ال", "probability": 0.95556640625}, {"start": 2553.52, "end": 2554.52, "word": " disaccharides", "probability": 0.76617431640625}, {"start": 2554.52, "end": 2555.2, "word": " هتلاقوا", "probability": 0.9125}, {"start": 2555.2, "end": 2555.46, "word": " عندي", "probability": 0.669189453125}, {"start": 2555.46, "end": 2555.56, "word": " ال", "probability": 0.93505859375}, {"start": 2555.56, "end": 2556.5, "word": " glycosidic", "probability": 0.9827880859375}, {"start": 2556.5, "end": 2556.74, "word": " bond", "probability": 0.74267578125}, {"start": 2556.74, "end": 2557.62, "word": " طبعا", "probability": 0.9827880859375}, {"start": 2557.62, "end": 2557.86, "word": " إيش", "probability": 0.7534993489583334}, {"start": 2557.86, "end": 2558.66, "word": " السكارين", "probability": 0.9288330078125}, {"start": 2558.66, "end": 2558.92, "word": " اللي", "probability": 0.96484375}, {"start": 2558.92, "end": 2559.9, "word": " بيندمجوا", "probability": 0.863525390625}, {"start": 2559.9, "end": 2560.44, "word": " و", "probability": 0.68408203125}, {"start": 2560.44, "end": 2560.7, "word": " إيش", "probability": 0.8388671875}, {"start": 2560.7, "end": 2561.2, "word": " السكر", "probability": 0.752197265625}, {"start": 2561.2, "end": 2561.6, "word": " ثناء", "probability": 0.6199544270833334}, {"start": 2561.6, "end": 2561.76, "word": " اللي", "probability": 0.986572265625}, {"start": 2561.76, "end": 2562.36, "word": " بيطلع", "probability": 0.96513671875}, {"start": 2562.36, "end": 2563.02, "word": " هذا", "probability": 0.8974609375}, {"start": 2563.02, "end": 2563.32, "word": " بيكون", "probability": 0.9593098958333334}, {"start": 2563.32, "end": 2563.82, "word": " موضوع", "probability": 0.979736328125}], "temperature": 1.0}, {"id": 109, "seek": 256692, "start": 2565.64, "end": 2566.92, "text": "المحاضرة القادمة ان شاء الله", "tokens": [45340, 5016, 46958, 25720, 25062, 18513, 46007, 16472, 13412, 16606, 21984], "avg_logprob": -0.07800292658309142, "compression_ratio": 1.0612244897959184, "no_speech_prob": 0.0, "words": [{"start": 2565.64, "end": 2566.04, "word": "المحاضرة", "probability": 0.965087890625}, {"start": 2566.04, "end": 2566.44, "word": " القادمة", "probability": 0.9913736979166666}, {"start": 2566.44, "end": 2566.6, "word": " ان", "probability": 0.58837890625}, {"start": 2566.6, "end": 2566.8, "word": " شاء", "probability": 0.9873046875}, {"start": 2566.8, "end": 2566.92, "word": " الله", "probability": 0.95654296875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2567.61625, "duration_after_vad": 2471.4118749999902}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/kc7SLz2Zt8E.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/kc7SLz2Zt8E.srt
new file mode 100644
index 0000000000000000000000000000000000000000..4afe73d7cb26eac52fa07a470bd0df6543b6f24a
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/kc7SLz2Zt8E.srt
@@ -0,0 +1,1444 @@
+1
+00:00:20,790 --> 00:00:24,970
+بسم الله الرحمن الرحيم، اليوم إن شاء الله في
+
+2
+00:00:24,970 --> 00:00:30,390
+المحاضرة الأخيرة، بدنا نحاول نراجع بعض الامتحانات
+
+3
+00:00:30,390 --> 00:00:35,430
+نشوف كيف بتيجي الصورة الكلية في الامتحانات على هذه
+
+4
+00:00:35,430 --> 00:00:39,630
+المادة. في عندنا هذا الامتحان، هذا الامتحان كان في
+
+5
+00:00:39,630 --> 00:00:45,330
+الفصل الأول الماضي لطلاب السنة الأولى في كلية الطب.
+
+6
+00:00:45,910 --> 00:00:50,190
+نحاول مع بعض نمر عليه، بنلاحظ أن الأسئلة طبعاً
+
+7
+00:00:50,190 --> 00:00:55,750
+منوعة، في أسئلة صح و غلط، أكمل الفراغ، سم المركب،
+
+8
+00:00:55,750 --> 00:01:01,760
+كيف تحضر مركب، أكمل المعادلة، كل هذه الأشياء. نشوف
+
+9
+00:01:01,760 --> 00:01:07,800
+الأشياء بالترتيب. في أسئلة الصح والغلط بيسألنا سؤال
+
+10
+00:01:07,800 --> 00:01:13,160
+بيقول لنا الـpeptide لجليسين ألانين ألانين و
+
+11
+00:01:13,160 --> 00:01:16,380
+الـpeptide ألانين جليسين جليسين are structural
+
+12
+00:01:16,380 --> 00:01:20,920
+isomers. إيش رأيكم؟ They are not isomers لأن الـ
+
+13
+00:01:20,920 --> 00:01:26,140
+isomers لازم يكونوا مكونين من نفس الأشياء. يعني هذا
+
+14
+00:01:26,140 --> 00:01:29,120
+اثنين ألانين واحد جليسين، هذا اثنين جليسين واحد
+
+15
+00:01:29,120 --> 00:01:32,700
+ألانين. They are not isomers; they are different
+
+16
+00:01:32,700 --> 00:01:43,140
+compounds. A glucofuranose is an aldopentose. واضح؟
+
+17
+00:01:43,140 --> 00:01:49,340
+إيش رأيكم؟
+
+18
+00:01:49,340 --> 00:01:54,760
+الفيورانوز خمسة
+
+19
+00:01:54,760 --> 00:02:01,200
+لكن الجلوكوز ستة. الجلوكوز
+
+20
+00:02:04,860 --> 00:02:11,080
+لأ، لما نقول جلوكوز، الجلوكوز مر علينا وين؟ في
+
+21
+00:02:11,080 --> 00:02:16,500
+الـaldhexoses؟
+
+22
+00:02:16,500 --> 00:02:17,700
+لأ، هذا wrong.
+
+23
+00:02:29,910 --> 00:02:36,410
+الجلوكوز نفسه ست كربونات ولا خمسة؟ ستة. الآن لما
+
+24
+00:02:36,410 --> 00:02:41,470
+أنا هنا بقول خمسة، إذا هذا الكلام صح ولا غلط؟ غلط،
+
+25
+00:02:41,470 --> 00:02:46,810
+لأنه الجلوكوز ستة مش خمسة. واضحة الفكرة؟ الجلوكوز
+
+26
+00:02:46,810 --> 00:02:50,910
+ستة ذرات كربون، مش خمسة. The peptide bond is longer
+
+27
+00:02:50,910 --> 00:02:57,830
+than a normal C=N or C-N double bond.
+
+28
+00:02:57,830 --> 00:03:03,110
+إيش رأيكم؟ هل الـpeptide أطول من الـC=N
+
+29
+00:03:03,110 --> 00:03:06,190
+(double bond) N؟ طبعاً أنتم بتكونوا تتذكروا أن الـamide bond
+
+30
+00:03:06,190 --> 00:03:11,990
+الـamide bond اللي هي الـC-N كأنها رابطة ونصف مع
+
+31
+00:03:11,990 --> 00:03:15,850
+الـresonance. ليش؟ لأنه أنا في الـamide bond عندي C
+
+32
+00:03:15,850 --> 00:03:20,590
+=O هذه single bond في الوضع الطبيعي.
+
+33
+00:03:20,590 --> 00:03:27,510
+الآن لو صارت هنا C=N وهنا الـO⁻
+
+34
+00:03:27,510 --> 00:03:28,530
+صارت
+
+35
+00:03:30,900 --> 00:03:35,480
+double bond. فهل الـpeptide أو الـamide double ولا
+
+36
+00:03:35,480 --> 00:03:42,220
+single؟ لأ هي واحد ونصف في النهاية. مش إحنا حكينا في
+
+37
+00:03:42,220 --> 00:03:46,880
+عندنا amide resonance، الـamide بيعمل resonance. معنى
+
+38
+00:03:46,880 --> 00:03:51,580
+resonance هذه اللي بتكون مرة double، مرة single bond في
+
+39
+00:03:51,580 --> 00:03:54,800
+المرة الثانية. شو بتكون؟ double bond. شو متوسط الـ
+
+40
+00:03:54,800 --> 00:03:58,640
+double والـsingle؟ واحد ونصف. الآن الواحد ونصف
+
+41
+00:03:58,640 --> 00:04:03,600
+كرابطة، الواحد ونصف كرابطة، مقارنة بالواحد، أيه أطول؟
+
+42
+00:04:03,600 --> 00:04:09,920
+رابطة. الواحد، الـsingle الأقصر، الـdouble والـ
+
+43
+00:04:09,920 --> 00:04:16,160
+واحد ونصف بينهم، فهي أقصر من الـsingle وأطول من الـ
+
+44
+00:04:16,160 --> 00:04:21,140
+double. واضحة؟ الرابطة لما تكون بـresonance يعني
+
+45
+00:04:21,140 --> 00:04:24,240
+كأنها واحد ونصف، هي أقصر من الـsingle bond وأطول
+
+46
+00:04:24,240 --> 00:04:29,460
+من الـdouble bond. إحنا إيش كاتبين؟ Is longer than C
+
+47
+00:04:29,460 --> 00:04:35,250
+double bond. and. إذا هذه الجملة صحيحة. واضحة الفكرة؟ هذه
+
+48
+00:04:35,250 --> 00:04:38,630
+بتعتمد على فهمكم لـamide resonance. بتعتمد على
+
+49
+00:04:38,630 --> 00:04:42,130
+فهمكم لـamide resonance. Hydrolysis of starch
+
+50
+00:04:42,130 --> 00:04:49,350
+produces only β-glucopyranose. الـstarch من أي
+
+51
+00:04:49,350 --> 00:04:53,110
+سكة؟
+
+52
+00:04:53,110 --> 00:05:00,710
+من؟ كويس. من أي ديساكرايد؟ ملتوز. الملتوز من إيش؟
+
+53
+00:05:02,010 --> 00:05:08,890
+أي جلوكوز؟ ألفا أو بيتا؟ ألفا أو بيتا. الآن هنا إيش
+
+54
+00:05:08,890 --> 00:05:16,130
+كاتبين إحنا؟ Only بيتا. لأن الملتوز ألفا وبيتا.
+
+55
+00:05:16,130 --> 00:05:19,950
+ملتوز ألفا وبيتا. The OH of the anomeric carbon
+
+56
+00:05:19,950 --> 00:05:23,690
+of β-glucopyranose is found in the equatorial
+
+57
+00:05:23,690 --> 00:05:29,870
+position. هذه أخذناها صحيحة.
+
+58
+00:05:31,370 --> 00:05:36,890
+مش قولنا إنه ليش بيكون الـβ نسبته أعلى من الـ
+
+59
+00:05:36,890 --> 00:05:40,270
+α؟ لأنه الـβ في الـequatorial position ما فيش
+
+60
+00:05:40,270 --> 00:05:45,650
+عليها steric hindrance. Diterpenes are composed of
+
+61
+00:05:45,650 --> 00:05:52,710
+twenty carbon atoms. الآن الـmonoterpene كم isoprene
+
+62
+00:05:52,710 --> 00:05:57,110
+unit؟ اثنين. الـditerpene كم isoprene unit؟
+
+63
+00:05:57,110 --> 00:05:58,910
+أربعة. أربعة في خمسة
+
+64
+00:06:02,460 --> 00:06:09,860
+Hydrogenation of oils is a saponification reaction.
+
+65
+00:06:09,860 --> 00:06:12,880
+هدرجة
+
+66
+00:06:12,880 --> 00:06:18,280
+الزيوت بتحول الـdouble bond إلى single bond. بتحول
+
+67
+00:06:18,280 --> 00:06:22,820
+الـoil إلى fat. الـsaponification reaction بيعمل
+
+68
+00:06:22,820 --> 00:06:29,770
+hydrolysis. فهدرجة الزيوت مش تفاعل saponification.
+
+69
+00:06:29,770 --> 00:06:34,250
+الـsaponification إنك تأخذ الـtriglyceride تحوله إلى
+
+70
+00:06:34,250 --> 00:06:41,190
+soap، إلى salt of the fatty acid. واضح؟ إنك تحول الزيت
+
+71
+00:06:41,190 --> 00:06:45,690
+إلى صابون، إنك تعمل hydrolysis. الآن هل الـ
+
+72
+00:06:45,690 --> 00:06:48,970
+hydrogenation عمل hydrolysis ولا تحويل double bond
+
+73
+00:06:48,970 --> 00:06:52,610
+إلى single bond؟ آه. إذا الـhydrogenation is
+
+74
+00:06:52,610 --> 00:06:58,270
+a saponification reaction غلط. الهيدروجينيشن تحويل double
+
+75
+00:06:58,270 --> 00:07:03,710
+bond إلى single bond، مش تحويل ester إلى ملح. The polar R
+
+76
+00:07:03,710 --> 00:07:08,990
+groups in hair proteins. طبعاً الـhair fibrous
+
+77
+00:07:08,990 --> 00:07:15,750
+protein are located outside. الفيبرس
+
+78
+00:07:15,750 --> 00:07:22,450
+وين موجودة الـR groups تبعتهم؟ جوا مش برا. الـfibrous
+
+79
+00:07:22,450 --> 00:07:27,350
+proteins. الـR groups تبعتهم موجودة للداخل، ولذلك
+
+80
+00:07:27,350 --> 00:07:34,390
+هذه الجملة غلط. واضح؟ الآن complete the following
+
+81
+00:07:34,390 --> 00:07:38,450
+statements. نرفع شوية
+
+82
+00:07:45,750 --> 00:07:49,630
+الديستيريومرز الذين يختلفون فقط في مركز واحد كيرال
+
+83
+00:07:49,630 --> 00:08:02,610
+يسمون epimers. Epimers. اسم الكيميائي للاسبرين: أسيتيل
+
+84
+00:08:02,610 --> 00:08:07,130
+ساليسيليك
+
+85
+00:08:07,130 --> 00:08:12,830
+أسيد. الباراسيتامول
+
+86
+00:08:12,830 --> 00:08:14,170
+أيضاً يسمون
+
+87
+00:08:18,000 --> 00:08:24,020
+أسيتامينوفين. متذكرين هذا الكلام؟ أسيتامينوفين.
+
+88
+00:08:24,020 --> 00:08:30,000
+Disulfide bonds in proteins result from oxidation of
+
+89
+00:08:30,000 --> 00:08:35,520
+أي amino acid اللي بيعمل disulfide bond؟ سيستين.
+
+90
+00:08:44,950 --> 00:08:49,250
+أكسدة الجلوكوز باستخدام حمض النتريك تنتج
+
+91
+00:08:49,250 --> 00:08:58,410
+حمض الميزوكساليك. حمض الميزوكساليك، اللي هو يعني فيه مجموعتين
+
+92
+00:08:58,410 --> 00:09:08,350
+حمض. حمض الميزوكساليك، حمض الميزوكساليك. التغيير
+
+93
+00:09:08,350 --> 00:09:11,870
+في حركة العيون بسبب التعاون بين الحيوانات
+
+94
+00:09:11,870 --> 00:09:18,880
+والموصلات العصبية. Myota rotation.
+
+95
+00:09:18,880 --> 00:09:24,080
+البروجيستيرون
+
+96
+00:09:24,080 --> 00:09:33,800
+هي ستة هرمونات مع مصادر استيرويدية. استيرويدية
+
+97
+00:09:33,800 --> 00:09:38,360
+مصادر استيرويدية تقوم بالتقليل من الشُغْر
+
+98
+00:09:43,220 --> 00:09:49,820
+السكريات المختزلة بيصير لها oxidation reactions.
+
+99
+00:09:49,820 --> 00:09:59,420
+واضح؟ Oxidation، لأنه هي aldehyde بيصير لها أكسدة.
+
+100
+00:09:59,420 --> 00:10:05,540
+واضح؟ Reducing sugars undergo oxidation reactions.
+
+101
+00:10:13,590 --> 00:10:19,570
+Name the following compounds. أول مركب إيش شايفين؟
+
+102
+00:10:19,570 --> 00:10:25,010
+فيه؟ مجموعات وظيفية: aldehyde، ketone، وdouble bond.
+
+103
+00:10:25,010 --> 00:10:29,530
+شو لازم يصير؟ الـaldehyde أعلى. أو لو يالا الـaldehyde.
+
+104
+00:10:29,530 --> 00:10:34,630
+واحد، اثنين، ثلاثة، أربعة، خمسة. إذا هذا هيكون
+
+105
+00:10:56,440 --> 00:10:59,240
+توبنتينال. توبنتينال.
+
+106
+00:11:02,160 --> 00:11:06,800
+واضح؟ الآن نطلع على المركب اللي بعده. أهم شغل تعرفه
+
+107
+00:11:06,800 --> 00:11:13,440
+المجموعة الوظيفية تبع المركب: الـacid. الـacid. الـ
+
+108
+00:11:13,440 --> 00:11:21,160
+acid. إذا هقول أنا واحد، اثنين، ثلاثة، أربعة. هاي الجزء
+
+109
+00:11:21,160 --> 00:11:27,620
+الأساسي في المركب. الآن هذا الجزء شو اسمه؟ بيوتانويك
+
+110
+00:11:27,620 --> 00:11:30,660
+بيوتانويك
+
+111
+00:11:31,760 --> 00:11:40,640
+acid. إيش بيحمل على نمرة ثلاثة؟ 3-cyclopentyl
+
+112
+00:11:40,640 --> 00:11:50,520
+وشو بيحمل على نمرة أربعة؟ 4-dimethylamino
+
+113
+00:11:50,520 --> 00:11:55,560
+3-cyclopentyl
+
+114
+00:11:55,560 --> 00:12:00,380
+4-dimethylamino butanoic acid. واضح؟
+
+115
+00:12:02,250 --> 00:12:07,430
+3-cyclopentyl-4-dimethylamino-butanoic acid. آخر
+
+116
+00:12:07,430 --> 00:12:14,490
+مركب، شو مجموعته الوظيفية؟ amide. من
+
+117
+00:12:14,490 --> 00:12:22,450
+كم كربون مكوّن بالأساس؟ يعني جاي من أي حمض؟ من الـ
+
+118
+00:12:22,450 --> 00:12:31,330
+acetic acid. إذا هذا acetamide، أو لو قلنا إيثانو
+
+119
+00:12:31,330 --> 00:12:31,810
+اميد
+
+120
+00:12:35,670 --> 00:12:43,650
+الآن إيش بيحمل هذا على نمرة اثنين؟ فنيل. فنيل. فنيل. فنيل.
+
+121
+00:12:43,650 --> 00:12:48,190
+فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل
+
+122
+00:12:48,190 --> 00:12:48,470
+فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل
+
+123
+00:12:48,470 --> 00:12:51,550
+فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل
+
+124
+00:12:51,550 --> 00:12:51,670
+فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل. فنيل
+
+125
+00:12:51,670 --> 00:13:02,030
+فنيل. فنيل. فنيل. فنيل.
+
+126
+00:13:02,030 --> 00:13:02,570
+فن
+
+127
+00:13:08,520 --> 00:13:13,160
+الآن هنا بدنا إياكم ترسمون لبعض المركبات بأشكالها
+
+128
+00:13:13,160 --> 00:13:17,340
+العامة. لو قلنا أسيتوفينون، مين ما بتعرفش
+
+129
+00:13:17,340 --> 00:13:21,440
+الأسيتوفينون؟ CH₃
+
+130
+00:13:21,440 --> 00:13:29,480
+Phenyl C=O. الآن لما بدي hydrazone، بدو
+
+131
+00:13:29,480 --> 00:13:34,110
+يصير C=N-NH. إحنا إيش حاطين على
+
+132
+00:13:34,110 --> 00:13:39,890
+الـhydrazone؟ أسيتيل. لو كانت مثل، بنحط مثل. فينيل. فينيل
+
+133
+00:13:39,890 --> 00:13:44,950
+أسيتيل. C
+
+134
+00:13:44,950 --> 00:13:53,750
+=O CH₃. أسيتوفينون هيدرازون أسيتيل.
+
+135
+00:13:53,750 --> 00:13:57,960
+هيدرازون. أسيتوفينون. لو فينيل، كان قلنا فينيل
+
+136
+00:13:57,960 --> 00:14:01,600
+هيدرازون. مثل، مثل هيدرازون، إيثيل هيدرازون، أسيت
+
+137
+00:14:01,600 --> 00:14:08,860
+الهيدرازون. الـglyceraldehyde. الـglyceraldehyde في
+
+138
+00:14:08,860 --> 00:14:18,560
+هنا aldehyde وبعدين chiral center واحد. شوفي هنا
+
+139
+00:14:18,560 --> 00:14:19,740
+الكيرال سنتر
+
+140
+00:14:22,340 --> 00:14:31,660
+H وOH وأنا هاي
+
+141
+00:14:31,660 --> 00:14:39,620
+الـglycerol دي، ولو كان دي ناقص بنزل to بيوتان
+
+142
+00:14:39,620 --> 00:14:45,160
+دول، بنخلص
+
+143
+00:14:45,160 --> 00:14:47,020
+هدول خلصناهم.
+
+144
+00:14:49,020 --> 00:14:54,540
+الآن طبعاً بنبدأ الرسم من الآخر. معناه أ و ات يعني
+
+145
+00:14:54,540 --> 00:15:00,480
+عندي P-stop، يعني عندي C=O-O⁻. الآن شو
+
+146
+00:15:00,480 --> 00:15:09,180
+الجزء الـalcohol اللي هنا؟ بنزل شو؟ بنزل CH₂
+
+147
+00:15:09,180 --> 00:15:15,960
+Phenyl. CH₂Phenyl. هي الـbenzyl. بنزل butyne. و ات هي كربونة
+
+148
+00:15:15,960 --> 00:15:17,340
+كم كربون بضل عندي؟
+
+149
+00:15:26,230 --> 00:15:32,970
+أربعة. الآن في عندي الـtriple bond على نمرة اثنين.
+
+150
+00:15:32,970 --> 00:15:42,690
+إذا واحد، اثنين، ثلاثة، وهذه شو بخليها؟ CH₃، وهذه
+
+151
+00:15:42,690 --> 00:15:51,050
+رقم واحد. يعني لحظة، بنزل Phenyl، CH₂، بنزل الـester، C=
+
+152
+00:15:51,050 --> 00:15:55,870
+O-OR. واضح؟ Butyne واحد، اثنين، ثلاثة، أربعة، two
+
+153
+00:15:55,870 --> 00:16:02,170
+butyne. واثنين. هذا المركب بهدوء بنمشي فيه خطوة
+
+154
+00:16:02,170 --> 00:16:07,330
+خطوة بنرسمه. Cyclopentane. كيف الـcyclopentane؟ في
+
+155
+00:16:07,330 --> 00:16:14,590
+حد بعرفهوش؟ بدنا نعمل فيه aldehyde. cyclopentene
+
+156
+00:16:14,590 --> 00:16:21,070
+carboxaldehyde. كيف الـcarboxaldehyde؟ C=O-H. هاي
+
+157
+00:16:21,070 --> 00:16:26,090
+الـcyclopentene carboxaldehyde. هذا الـcyclopentene
+
+158
+00:16:26,090 --> 00:16:30,910
+carboxaldehyde. الآن لما بتعمل oxime، بدي أشيل الـO
+
+159
+00:16:30,910 --> 00:16:35,670
+أخليها N-OH.
+
+160
+00:16:38,800 --> 00:16:43,560
+حوّلت الـaldehyde إلى oxime. cyclopentene carboxaldehyde
+
+161
+00:16:43,560 --> 00:16:49,820
+oxime. β
+
+162
+00:16:49,820 --> 00:16:57,100
+to deoxyfuranose. متذكرين الـfuranose؟ بده general
+
+163
+00:16:57,100 --> 00:17:05,120
+structure له. أهم شيء إنه على موقع اثنين في عنده
+
+164
+00:17:07,970 --> 00:17:14,750
+بهمّنّيش الـOH، بهمّنّي الـ2-deoxy هنا في oxygen
+
+165
+00:17:14,750 --> 00:17:25,410
+والموقع اثنين هنا هذا
+
+166
+00:17:25,410 --> 00:17:29,550
+الموقع. واضح؟ ما عليكم ولا نفرجيكم معاه
+
+167
+00:17:40,850 --> 00:17:47,390
+نذكركم فيه لو سمحتوا في الـ… في الـ
+
+168
+00:17:47,390 --> 00:17:54,990
+carbohydrates. هذا الـcarbohydrates؟ لأ.
+
+169
+00:18:08,950 --> 00:18:12,190
+Clothes Clothes Clothes Clothes Clothes Clothes
+
+170
+00:18:12,190 --> 00:18:18,910
+Clothes Clothes
+
+171
+00:18:18,910 --> 00:18:19,190
+Clothes Clothes Clothes Clothes Clothes Clothes
+
+172
+00:18:19,190 --> 00:18:19,210
+Clothes Clothes Clothes Clothes Clothes Clothes
+
+173
+00:18:19,210 --> 00:18:19,390
+Clothes Clothes Clothes Clothes Clothes Clothes
+
+174
+00:18:19,390 --> 00:18:19,510
+Clothes Clothes Clothes Clothes Clothes Clothes
+
+175
+00:18:19,510 --> 00:18:19,830
+Clothes Clothes Clothes Clothes Clothes Clothes
+
+176
+00:18:19,830 --> 00:18:20,630
+Clothes Clothes Clothes Clothes Clothes Clothes
+
+177
+00:18:20,630 --> 00:18:20,750
+Clothes Clothes
+
+178
+00:18:33,500 --> 00:18:36,800
+Oxygen. ديش هيكوا تحفظوا الـOHs، لوين بس أهم شيء
+
+17
+
+223
+00:23:18,550 --> 00:23:24,890
+الكلام الفكرة خلصت الآن كحول مع الديهايد، hemicetal
+
+224
+00:23:24,890 --> 00:23:31,410
+الديهايد بالاختزال كحول، الديهايد بالأكسدة حمض
+
+225
+00:23:31,410 --> 00:23:37,710
+زاد قاعدة، ملح حمض، زاد ثيونيل كلوريد، أسيل كلوريد
+
+226
+00:23:37,710 --> 00:23:43,790
+الديهايد مع السيانوهيدرين، الديهايد مع الإيثيلين جليكول
+
+227
+00:23:43,790 --> 00:23:49,110
+إيثيلين جليكول أسيتال، وبعدين بيصير إنه قد إيش الإنسان متدرب
+
+228
+00:23:49,110 --> 00:23:51,430
+يكتب ويطبق هذا الكلام
+
+229
+00:24:07,890 --> 00:24:14,030
+الآن، هي في عندنا سؤال ثاني، إيش المنطلق اللي عندنا؟
+
+230
+00:24:14,030 --> 00:24:17,970
+فيه أسيل كلوريد، أسيل كلوريد بتكون، تتذكروا كيمياء
+
+231
+00:24:17,970 --> 00:24:24,910
+الأسيل كلوريد، أسيل كلوريد مع كحول، إستر، إستر، كل شيء
+
+232
+00:24:24,910 --> 00:24:29,610
+بخليه زي ما هو وبحطّها، نقوّي أسيل، إستر، ممتاز، أسيل
+
+233
+00:24:29,610 --> 00:24:36,730
+كلوريد مع أمين، أميد، أميد، unmatched
+
+234
+00:24:36,730 --> 00:24:46,530
+الآن، Acid chloride مع Grignard reagent، ثالثي
+
+235
+00:24:46,530 --> 00:24:52,510
+ثالثي الكحول، هاي الـC، هاي هاي هاي بتصير OH، يجيني
+
+236
+00:24:54,100 --> 00:24:58,100
+مجموعة فنول على مرتين، هيتفاعل أول شيء بيعطيني الـ
+
+237
+00:24:58,100 --> 00:25:01,800
+كيتون، أول ما تاجم الفينول هنا محل الـCl بيعطيني الـ
+
+238
+00:25:01,800 --> 00:25:06,480
+كيتون، وبكمل لـ tertiary alcohol، أخذنا الـ ester والـ
+
+239
+00:25:06,480 --> 00:25:10,580
+الـ acid chloride مع Grignard شو بيعطوني؟ tertiary
+
+240
+00:25:10,580 --> 00:25:16,200
+alcohol، وبالاختزال؟ primary alcohol، الآن
+
+241
+00:25:21,250 --> 00:25:25,850
+هذا الـ acid chloride مع sodium benzoate، بدنا
+
+242
+00:25:25,850 --> 00:25:31,190
+واحدة شاطرة تقول لنا كيف شكل sodium benzoate، فنول، C
+
+243
+00:25:31,190 --> 00:25:38,410
+رابطة ثنائية O، O ناقص، Na موجب، لاحظوا هنا لما قلت
+
+244
+00:25:38,410 --> 00:25:44,730
+O ناقص وهذا acid chloride، صار تحضير إيش الـ
+
+245
+00:25:44,730 --> 00:25:49,930
+unsymmetrical anhydride، إن هذه تهاجم هذا
+
+246
+00:25:49,930 --> 00:25:55,350
+نيوكليوفيل، يترد الـCl، أيه، هاجمه، يترد الـCl
+
+247
+00:25:55,350 --> 00:25:58,810
+عشان هيصير هذا تحضير الـ unsymmetrical anhydride
+
+248
+00:25:58,810 --> 00:26:05,670
+هاي هذا الجزء والجزء الثاني O، C رابطة ثنائية O
+
+249
+00:26:05,670 --> 00:26:11,170
+فينيل، فعلاً هذا anhydride ولا لأ؟ C رابطة ثنائية O
+
+250
+00:26:11,170 --> 00:26:18,440
+O، C رابطة ثنائية O، anhydride، هاي احنا أخذنا أربع
+
+251
+00:26:18,440 --> 00:26:22,780
+تفاعلات للـ acid chloride، باختصار، acid chloride مع
+
+252
+00:26:22,780 --> 00:26:27,300
+كحول، ester، acid chloride مع أمونيا، amide، acid
+
+253
+00:26:27,300 --> 00:26:31,000
+chloride مع Grignard، tertiary alcohol، acid
+
+254
+00:26:31,000 --> 00:26:37,160
+chloride مع أنيون، anhydride، unsymmetrical
+
+255
+00:26:37,160 --> 00:26:40,020
+anhydride، طريقة تحضير الـ unsymmetrical anhydride
+
+256
+00:26:40,020 --> 00:26:44,560
+الآن، دول خلّصناهم، صار في عندي ester، بدي آخذ للـ
+
+257
+00:26:44,560 --> 00:26:49,240
+ester كم تفاعل؟ تفاعلين، وصار في عندي amide، بتاخذ
+
+258
+00:26:49,240 --> 00:26:53,420
+للـ amide كم تفاعل؟ تفاعلين، هو احنا كل اللي اتعلمناهم
+
+259
+00:26:53,420 --> 00:27:01,100
+للـ amide كم تفاعل؟ يا تحليل مائي، يعني هذا يصير acid
+
+260
+00:27:01,100 --> 00:27:13,240
+بهذا الشكل، يا إما اختزال، إن هذا يصير CH2
+
+261
+00:27:14,120 --> 00:27:22,280
+NH2، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد
+
+262
+00:27:22,280 --> 00:27:25,100
+أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد
+
+263
+00:27:25,100 --> 00:27:25,980
+أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد
+
+264
+00:27:25,980 --> 00:27:30,000
+أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد
+
+265
+00:27:30,000 --> 00:27:31,420
+أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد
+
+266
+00:27:31,420 --> 00:27:31,460
+أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد، أميد
+
+267
+00:27:31,460 --> 00:27:39,960
+أميد، أميد، 
+
+268
+00:27:43,000 --> 00:27:47,720
+الإستر بالاختزال، الأسيل كلوريد والإستر
+
+269
+00:27:47,720 --> 00:27:51,240
+بالاختزال، شو بيصيروا؟ primary alcohol، يعني هذه
+
+270
+00:27:51,240 --> 00:27:56,400
+بيصير CH2OH
+
+271
+00:27:56,400 --> 00:28:04,700
+والجزء هذا نفسه، طيب، الإستر مع الهيدرازين، يمكن
+
+272
+00:28:04,700 --> 00:28:10,790
+ما مرّش عليكم هذا التفاعل، تفاعل خاص، لكن لما تقولوا
+
+273
+00:28:10,790 --> 00:28:16,190
+الهيدرازين نيوكليوفيل، شو بده يعمل؟ بده يهاجم هنا
+
+274
+00:28:16,190 --> 00:28:22,410
+ويطرد الـ O-ethyl، حطّوا الناتج بهذا الشكل، إذا
+
+275
+00:28:22,410 --> 00:28:30,510
+حاسين عندكم؟ C رابطة ثنائية O، وهنا إيش بده يصير؟ NH
+
+276
+00:28:30,510 --> 00:28:35,630
+NH2، هيدرازيد
+
+277
+00:28:35,630 --> 00:28:42,800
+بيسمّوه، زي تفاعل الأميد، زي لو كنتوا بِتفعلوه مع نيوكليوفيل
+
+278
+00:28:42,800 --> 00:28:48,460
+ثالثي، مش كان تيجي نيوكليوفيل ثالثي تحلّ محلّ هادي، واضح؟ نفس
+
+279
+00:28:48,460 --> 00:28:53,900
+الفكرة تماماً،
+
+280
+00:28:53,900 --> 00:28:54,620
+واضحة؟
+
+281
+00:29:13,900 --> 00:29:19,260
+لاحظوا، بسؤال بسيط، راجعنا كم كيمياء الـ acid halides
+
+282
+00:29:19,260 --> 00:29:25,720
+والـ esters والـ amides والأحماض، هذا
+
+283
+00:29:25,720 --> 00:29:34,430
+الجزء، في عندكم مجموعة النيترو ومجموعة السيانو على
+
+284
+00:29:34,430 --> 00:29:43,070
+بنزين، الآن، النيترو بالاختزال شو بتصير؟ NH
+
+285
+00:29:43,070 --> 00:29:47,670
+2، أنيلين، أنيلين، مشقول، إن هذه طريقة تحضير
+
+286
+00:29:47,670 --> 00:29:53,970
+الأنيلين، يعني هذه تصير NH2، هنا سيان
+
+287
+00:29:56,170 --> 00:30:02,250
+اختزال، بيشتغل الـ nitro، تصير NH2، الآن السيانو
+
+288
+00:30:02,250 --> 00:30:06,470
+أخذنا بالتحليل المائي في تحضير الأحماض، شو بتصير؟
+
+289
+00:30:06,470 --> 00:30:12,030
+حمض، إذن هنا، بدي أسيب الـ nitro زي ما هي،
+
+290
+00:30:12,030 --> 00:30:20,810
+وهذه إيش بتصير؟ C رابطة ثنائية O، تفاعل
+
+291
+00:30:20,810 --> 00:30:26,980
+السيانو لحمض، مرّ معنا ولا لأ؟ وتفاعل الـ nitro هي
+
+292
+00:30:26,980 --> 00:30:32,060
+مصدر الأنيلين، مرّ معنا ولا لأ؟ أفتح دي للأمين؟ بس هم
+
+293
+00:30:32,060 --> 00:30:38,640
+راحوا دخلوش في بعض، في هنا الـ Na، الـ O2 بتحوّلها إلى
+
+294
+00:30:38,640 --> 00:30:45,260
+الـ oxime، اه، هنا أول فكرة، الـ H2، بهمش، انتبهوا شوية، الـ H2
+
+295
+00:30:45,260 --> 00:30:49,640
+مع البلاتينيوم بيعطيني الأنيلين، الآن إذا بعد هيك
+
+296
+00:30:49,640 --> 00:30:54,880
+فعلناها مع sodium nitrite وH3O موجب، بيصير إيش؟
+
+297
+00:30:55,940 --> 00:31:00,660
+الفينول، مرّ علينا، طريقة تحضير الفينول، يعني أنا كان
+
+298
+00:31:00,660 --> 00:31:06,060
+جوابي بس للجزء الأول، إذا بعده فعلته مع الصوديوم
+
+299
+00:31:06,060 --> 00:31:08,640
+نايتريت، حامل دايازونيوم سولت، ماعدش، three of plus
+
+300
+00:31:08,640 --> 00:31:15,280
+بيصير فينول، يعني لو جينا بس لحدها أنيلين
+
+301
+00:31:15,280 --> 00:31:22,520
+لو كملنا، الأنيلين بنحوّله إلى فينول حسب ما يجي
+
+302
+00:31:22,520 --> 00:31:25,980
+السؤال، يعني لحد الاختزال، أنيلين، زدنا عن الـ
+
+303
+00:31:25,980 --> 00:31:33,480
+اختزال، فينول، ممتازة
+
+304
+00:31:33,480 --> 00:31:34,020
+الآن
+
+305
+00:31:45,510 --> 00:31:50,110
+جينا سؤال، كيف بدنا نحضر الـ acetic acid، بتعرفوا الـ
+
+306
+00:31:50,110 --> 00:31:56,750
+acetic acid؟ CH3COOH
+
+307
+00:31:56,750 --> 00:32:02,870
+من إيش بدنا نحضّره؟ من الـ two-butanone، واحد اثنين، هاي
+
+308
+00:32:02,870 --> 00:32:07,530
+two-butanone، طبعاً
+
+309
+00:32:07,530 --> 00:32:14,580
+الكلام يبدو شوية غريب جداً، لكن لو أي حد بيفكّر شوية
+
+310
+00:32:14,580 --> 00:32:20,720
+بعمق، بيفكّر شوية بعمق، الـ acetic acid كربونتين والـ
+
+311
+00:32:20,720 --> 00:32:30,460
+two-butanone أربعة، يعني الأربعة لو كسّروا، لو كسّروا
+
+312
+00:32:30,460 --> 00:32:34,360
+بيصيروا اثنين واثنين، إذا أنا لو كنت بدي آجي برجوع
+
+313
+00:32:34,360 --> 00:32:36,540
+من وراء هذا، إيش ممكن يكون؟
+
+314
+00:32:39,320 --> 00:32:47,400
+الألكين هذا، نمرة واحد، O3، نمرة اثنين، H2O2، كان
+
+315
+00:32:47,400 --> 00:32:53,300
+بيعطيني زي هيك ولا لأ؟
+
+316
+00:32:53,300 --> 00:32:58,660
+أنا كملت بالأكسدة الإضافية، أوزون وبعدين أكسدة
+
+317
+00:32:58,660 --> 00:33:07,580
+بيصير حمض، أوزون وبعدين أكسدة بيصير حمض، واضح؟ الآن
+
+318
+00:33:07,580 --> 00:33:13,140
+هذا من إيش ممكن ييجي؟ من كحول، يعني خلينا هيك
+
+319
+00:33:13,140 --> 00:33:19,540
+نتخيّل هي OH، الآن أنا ما عنديش كحول عشان أعمل حدث
+
+320
+00:33:19,540 --> 00:33:24,380
+باستعمال الـ KOH بيعطينا alkene، بس أنا ما عنديش كحول
+
+321
+00:33:24,380 --> 00:33:33,360
+أنا عندي ketone، الـ ketone يختزل، آه
+
+322
+00:33:33,960 --> 00:33:41,740
+إذا كيتون، كحول، ألكين، وأوزونوليزيس، اتبع أكسدة، أو
+
+323
+00:33:41,740 --> 00:33:46,960
+ممكن تستعمل كمان KMnO4، برضه H موجب بتعمل نفس
+
+324
+00:33:46,960 --> 00:33:52,700
+الشيء، واضح، هذا في طريقة تحضير الأحماض، لما قلنا كيف
+
+325
+00:33:52,700 --> 00:33:57,200
+بنكسر الـ double bond أو الـ triple bond، كمان ممكن
+
+326
+00:33:57,200 --> 00:34:00,700
+نكسرها، وإيش تعطينا؟ حمض
+
+327
+00:34:02,030 --> 00:34:06,050
+طبعاً، لأن هنا في عندي H وهنا H، أول ما بيكسر، زي ما
+
+328
+00:34:06,050 --> 00:34:09,470
+حكت زميلتكم، فعلاً، الـ 1,2-dialdehydes، الـ 1,2-dialdehydes
+
+329
+00:34:09,470 --> 00:34:17,010
+بتأكسدوا لإيش؟ لـ acetic acid، 1,2-dialdehydes بتأكسدوا
+
+330
+00:34:17,010 --> 00:34:24,610
+لـ acetic acid، آخر
+
+331
+00:34:24,610 --> 00:34:29,770
+سؤال، كان: draw the structure of the peptide alanine
+
+332
+00:34:29,770 --> 00:34:35,490
+cysteine، الآن بدي alanine، cysteine، هو البيبتيد، إيش
+
+333
+00:34:35,490 --> 00:34:44,710
+NCCO وكمان NCCO، الآن، هاي بيبتيد من شغلتين
+
+334
+00:34:44,710 --> 00:34:49,910
+الـ alanine، شو المجموعة اللي هنا؟ CH3، وهي الـ amino
+
+335
+00:34:49,910 --> 00:34:55,650
+terminal، وهنا بدو يكون عندكم NH، الـ cysteine، شو المجموعة؟
+
+336
+00:34:55,650 --> 00:34:59,930
+CH2SH
+
+337
+00:34:59,930 --> 00:35:05,970
+وهنا بدو يكون الـ acid terminal، فلاحظوا البيبتيد
+
+338
+00:35:05,970 --> 00:35:10,190
+لما بدي أرسم، بدي أبدأ بالهيكل تبعه، N C C رابطة ثنائية
+
+339
+00:35:10,190 --> 00:35:14,770
+bond O، و N C C رابطة ثنائية bond O، الآن إذا بحكي عن
+
+340
+00:35:14,770 --> 00:35:22,150
+الأنين بدي أحطّ، مثل، بحكي عن سيستين بدي أحطّ CH2SH
+
+341
+00:35:23,240 --> 00:35:26,540
+واضح الفكرة؟ هي صار عندي بيبتيد وamino
+
+342
+00:35:26,540 --> 00:35:32,260
+terminal وacid terminal، الآن بدنا نيجي بعد هيك
+
+343
+00:35:32,260 --> 00:35:40,180
+نقول هذا البيبتيد، خلينا نفعّله مع الميثانول وH
+
+344
+00:35:40,180 --> 00:35:44,220
+موجب، لاحظوا
+
+345
+00:35:44,220 --> 00:35:49,980
+البيبتيد إله acid terminal ولا لأ؟ acid.. acid
+
+346
+00:35:49,980 --> 00:35:51,320
+زاد كحول
+
+347
+00:35:53,810 --> 00:35:59,050
+حمض زائد كحول، إستر، إذا أنا بدي أجيب كل هذا
+
+348
+00:35:59,050 --> 00:36:02,970
+بلاّش نقعد نوضّح فيه ونقول C رابطة ثنائية O ومن
+
+349
+00:36:02,970 --> 00:36:09,110
+الميثانول شو حيّحطّ؟ وميثيل، كل البيبتيد زي ما هو
+
+350
+00:36:09,110 --> 00:36:12,530
+كاملة، C رابطة ثنائية O، وميثيل
+
+351
+00:36:18,040 --> 00:36:22,160
+الآن، البيبتيد مع الـ 2,4-dinitrofluorobenzene
+
+352
+00:36:22,160 --> 00:36:29,680
+هذا اللي أخذناه وسمّيناه إيش؟ Sanger
+
+353
+00:36:29,680 --> 00:36:39,340
+method، وان أو اتو، وان أو اتو، إيش بيعمل بالتحت مكان الـ
+
+354
+00:36:39,340 --> 00:36:45,360
+فلور؟ إذا أنا هيكون عندي NH والبيبتيد كله و
+
+355
+00:36:45,360 --> 00:36:56,410
+بعدين هنا بنزين، بنيترو ونيترو، كل البيبتيد يتحد
+
+356
+00:36:56,410 --> 00:37:05,110
+من عند الـ N، الآن
+
+357
+00:37:05,110 --> 00:37:12,030
+لو جينا فعلنا هذا مع الـ ethyl acetate، OH سالب، الـ
+
+358
+00:37:12,030 --> 00:37:19,040
+ethyl acetate، إستر، بنقدر نرسمه CH3 C رابطة ثنائية O O
+
+359
+00:37:19,040 --> 00:37:26,040
+-ethyl، إيش اللي بنتوقع؟ ميثيل، بيبتيد موجود، الـ amino
+
+360
+00:37:26,040 --> 00:37:33,640
+group، النيوكليوفيل وين ممكن يهاجم؟ يطرد
+
+361
+00:37:33,640 --> 00:37:41,160
+الـ O-ethyl، إذا هيكون الناتج اللي عندي الـ N-H مع كل
+
+362
+00:37:41,160 --> 00:37:50,600
+البيبتيد وإيش حيّحطّ عندي هنا؟ C رابطة ثنائية O CH3
+
+363
+00:37:50,600 --> 00:37:56,320
+الأمين
+
+364
+00:37:56,320 --> 00:38:00,080
+بتفاعل مع الإستر مش الحمض، بتفاعل مع الإستر
+
+365
+00:38:00,080 --> 00:38:11,130
+أمين زائد إستر، أميد، أمين زائد إستر، أميد، مش هذه
+
+366
+00:38:11,130 --> 00:38:18,410
+المعادلة العامة، هذه أمين وهذا إستر، أمين زائد إستر
+
+367
+00:38:18,410 --> 00:38:28,950
+بيعطينا إيش؟ أميد، الآن، طيب، الـ HCl بدو يتحلل، آه
+
+368
+00:38:28,950 --> 00:38:32,930
+بالأساس، مش بنعمل تحليل مائي احنا للبيبتايدز يعني
+
+369
+00:38:32,930 --> 00:38:43,130
+بدو يعطينا NH2، CH، C رابطة ثنائية O، OH، زائد طبعاً NH2
+
+370
+00:38:43,130 --> 00:38:50,470
+كمان NH2، CH3، CH2SH، مشغولة، بيعملوا تحليل مائي، الـ
+
+371
+00:38:50,470 --> 00:38:58,230
+peptides، واضح؟ تحليل مائي، peptide hydrolysis، بدو
+
+372
+00:38:58,230 --> 00:39:02,530
+يتكسّر، ضاغط الأشياء؟
+
+373
+00:39:22,160 --> 00:39:25,980
+نشوف الامتحان الثاني، حاولوا تشوفوا اللي بدكم إياه، لو
+
+374
+00:39:25,980 --> 00:39:26,600
+سمحتوا
+
+375
+00:39:55,080 --> 00:40:10,380
+هذا الامتحان الثاني اللي عندكم، بمشي
+
+376
+00:40:10,380 --> 00:40:15,860
+نمشي فيه أسرع شوية، نمشي
+
+377
+00:40:15,860 --> 00:40:20,280
+فيه أسرع شوية، يعني الحل بدون شرح، وبتقلّق، الآن الـ
+
+378
+00:40:20,280 --> 00:40:23,220
+carboxylic acids، نكبّر هذه بس
+
+379
+00:40:27,990 --> 00:40:32,070
+خلّيكم معايا، carboxylic acids react with aniline
+
+380
+00:40:32,070 --> 00:40:36,070
+producing amides، حمض زائد أمين، أميد، هذه الجملة صح
+
+381
+00:40:36,070 --> 00:40:43,210
+glyceryl tristerate is a simple triglyceride، صح
+
+382
+00:40:45,730 --> 00:40:50,250
+A large percentage of unsaturated acids، غلط، of
+
+383
+00:40:50,250 --> 00:40:54,630
+saturated، reaction of hemicetals with alcohol is a
+
+384
+00:40:54,630 --> 00:40:58,290
+substitution reaction، hemicetal مع الكحول
+
+385
+00:40:58,290 --> 00:41:02,870
+substitution، صحيحة، Epimers are enantiomers that
+
+386
+00:41:02,870 --> 00:41:06,230
+differ only in one chiral center، لأ، epimers are
+
+387
+00:41:06,230 --> 00:41:10,600
+diastereomers، الغلط إيجاء من كلمة enantiomers، الـ
+
+388
+0
+
+445
+00:47:09,280 --> 00:47:13,420
+سم المركبات التالية. هذا إيش مجموعته الوظيفية؟ إيه؟
+
+446
+00:47:13,420 --> 00:47:19,180
+إيه، استر. إذا لازم أحط في الأول إيثل، وفي الآخر واحد
+
+447
+00:47:19,180 --> 00:47:28,360
+اتنين، تلاتة، أربعة، خمسة. بنتين، و ويت الـ E وين موقعها؟
+
+448
+00:47:28,360 --> 00:47:34,700
+إيثل توبنتين ويت. إيش ده؟ الحامل. هذا المركب four
+
+449
+00:47:34,700 --> 00:47:35,120
+hydroxy
+
+450
+00:47:37,970 --> 00:47:44,350
+إذا هذا صار إيثل فور هيدروكسي توبنتينويت. إيثل فور
+
+451
+00:47:44,350 --> 00:47:51,350
+هيدروكسي توبنتينويت. واضح؟ نسمي آخر اتنين ونخلص بعد
+
+452
+00:47:51,350 --> 00:47:56,750
+عشر ثواني. هذا المركب اللي شايفينه عبارة عن إيش؟
+
+453
+00:47:56,750 --> 00:48:03,810
+كيتون. واحد، اتنين، تلاتة، أربعة، خمسة، ستة. إذا هذا
+
+454
+00:48:03,810 --> 00:48:10,520
+عبارة عن 3-هكسانون. شو بيحمل الـ 3-هكسانون؟
+
+455
+00:48:10,520 --> 00:48:17,940
+ميثل ودايميثل. بيحط مواقعهم، يعني 2-ميثل و6-
+
+456
+00:48:17,940 --> 00:48:23,020
+دايميثيل أمينو. هذي إيش اسمها الآن؟ ميثل، ميثل، 6-
+
+457
+00:48:23,020 --> 00:48:28,140
+دايميثيل أمينو. المركب الأخير هذا مر علينا في الـ
+
+458
+00:48:28,140 --> 00:48:36,240
+أنهيدريد. افتكر أنهيدريد.
+
+459
+00:48:37,520 --> 00:48:42,140
+على أي حال، بيكفي لهذا الجزء. الباقي عبارة عن
+
+460
+00:48:42,140 --> 00:48:46,860
+معادلات شبيهة بالأمثلة الثانية. بننهي الآن، و
+
+461
+00:48:46,860 --> 00:48:48,720
+بنتمنى لكم التوفيق.
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/kc7SLz2Zt8E_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/kc7SLz2Zt8E_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..b5357d128cf3182a46feaf57b85ed601ef8bab6d
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/kc7SLz2Zt8E_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4533, "start": 20.79, "end": 45.33, "text": "بسم الله الرحمن الرحيم اليوم ان شاء الله في المحاضرة الأخيرة بدنا نحاول نراجع بعض الامتحانات نشوف كيف بتيجي الصورة الكلية في الامتحانات على هذه المادة في عندنا هذا الامتحان هذا الامتحان كان في الفصل الأول الماضي لطلاب السنة الأولى في كلية الطب", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 16472, 13412, 16606, 21984, 8978, 9673, 5016, 46958, 25720, 16247, 9778, 48923, 47525, 8315, 8717, 5016, 995, 12610, 8717, 2288, 26108, 3615, 45030, 11242, 2423, 10943, 2655, 5016, 7649, 9307, 8717, 8592, 38688, 9122, 33911, 4724, 31371, 7435, 1829, 31767, 13063, 3660, 33251, 1211, 10632, 8978, 2423, 10943, 2655, 5016, 7649, 9307, 15844, 29538, 9673, 18513, 3660, 8978, 43242, 8315, 23758, 2423, 10943, 2655, 5016, 7649, 23758, 2423, 10943, 2655, 5016, 7649, 25961, 8978, 27188, 36520, 16247, 12610, 9673, 46958, 1829, 5296, 9566, 15040, 3555, 21136, 1863, 3660, 16247, 12610, 7578, 8978, 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الفيورانوز", "probability": 0.8079020182291666}, {"start": 111.74, "end": 114.76, "word": " خمسة", "probability": 0.9283447265625}, {"start": 114.76, "end": 116.34, "word": " لكن", "probability": 0.78662109375}, {"start": 116.34, "end": 118.18, "word": " الجلوكوز", "probability": 0.8878580729166666}, {"start": 118.18, "end": 119.48, "word": " ستة", "probability": 0.9658203125}, {"start": 119.48, "end": 121.2, "word": " الجلوكوز", "probability": 0.9183756510416666}], "temperature": 1.0}, {"id": 5, "seek": 13769, "start": 124.86, "end": 137.7, "text": "لأ لما نقول جولوكوز، الجولوكوز مر علينا وين؟ في الالدوهيكسوزز؟ لأ هذا world", "tokens": [1211, 10721, 5296, 15042, 8717, 39648, 10874, 12610, 2407, 4117, 2407, 11622, 12399, 25724, 12610, 2407, 4117, 2407, 11622, 3714, 2288, 25894, 8315, 4032, 9957, 22807, 8978, 2423, 6027, 3215, 2407, 3224, 1829, 4117, 3794, 2407, 11622, 11622, 22807, 5296, 10721, 23758, 1002], "avg_logprob": -0.22514205087314954, "compression_ratio": 1.303921568627451, 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ما تاجم الفنل هنا محل ال CL بيعطيني ال ketone و بكمل ل tertiary alcohol أخدنا ال Easter و ال acid chloride مع Greenyard شو بيعطوني؟ tertiary alcohol و بال reduction؟ primary alcohol الان", "tokens": [2304, 7435, 2304, 34268, 9957, 6156, 1863, 1211, 15844, 3714, 43500, 9957, 8032, 36081, 5172, 995, 30241, 5551, 12610, 1975, 8592, 1829, 4724, 40228, 9566, 1829, 22653, 2423, 14979, 546, 5551, 12610, 19446, 6055, 26108, 2304, 27188, 1863, 1211, 34105, 3714, 5016, 1211, 2423, 12855, 4724, 40228, 9566, 1829, 22653, 2423, 14979, 546, 4032, 4724, 24793, 1211, 5296, 38726, 29104, 7658, 5551, 9778, 3215, 8315, 2423, 9403, 4032, 2423, 8258, 35434, 20449, 6969, 13862, 13412, 2407, 4724, 40228, 9566, 11536, 1829, 22807, 38726, 29104, 7658, 4032, 20666, 11004, 22807, 6194, 7658, 2423, 7649], "avg_logprob": -0.2588098442300837, "compression_ratio": 1.6619718309859155, "no_speech_prob": 0.0, "words": [{"start": 1494.1, "end": 1495.02, "word": "مجمعتين", "probability": 0.87568359375}, {"start": 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قلانين الستين هو ال بيبتايد ايش NCCO وكمان NCCO الان هاي بيبتايد من شغلتين القلانين شو المجموعة اللي هنا CH3 وهي ال amino terminal وهنا بدو يكون عندكم NH الستين شو المجموعة CH2SH وهنا بدو يكون", "tokens": [6027, 7649, 4724, 16254, 12174, 1211, 7649, 9957, 2423, 14851, 9957, 31439, 2423, 4724, 1829, 3555, 2655, 995, 25708, 1975, 1829, 8592, 426, 11717, 46, 4032, 24793, 7649, 426, 11717, 46, 2423, 7649, 8032, 47302, 4724, 1829, 3555, 2655, 995, 25708, 9154, 13412, 17082, 1211, 2655, 9957, 25062, 1211, 7649, 9957, 13412, 2407, 9673, 7435, 2304, 2407, 27884, 13672, 1829, 34105, 5995, 18, 37037, 1829, 2423, 24674, 14709, 37037, 8315, 47525, 2407, 7251, 30544, 43242, 24793, 31118, 2423, 14851, 9957, 13412, 2407, 9673, 7435, 2304, 2407, 27884, 5995, 17, 17308, 37037, 8315, 47525, 2407, 7251, 30544], "avg_logprob": -0.28237756748789367, "compression_ratio": 1.8764044943820224, "no_speech_prob": 0.0, "words": [{"start": 2072.05, "end": 2072.43, "word": "الان", "probability": 0.848876953125}, 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amino", "probability": 0.4775390625}, {"start": 2089.91, "end": 2090.91, "word": " terminal", "probability": 0.8671875}, {"start": 2090.91, "end": 2091.79, "word": " وهنا", "probability": 0.77490234375}, {"start": 2091.79, "end": 2092.01, "word": " بدو", "probability": 0.561767578125}, {"start": 2092.01, "end": 2092.23, "word": " يكون", "probability": 0.967041015625}, {"start": 2092.23, "end": 2092.81, "word": " عندكم", "probability": 0.96044921875}, {"start": 2092.81, "end": 2093.87, "word": " NH", "probability": 0.716796875}, {"start": 2093.87, "end": 2094.61, "word": " الستين", "probability": 0.85302734375}, {"start": 2094.61, "end": 2094.81, "word": " شو", "probability": 0.988037109375}, {"start": 2094.81, "end": 2095.65, "word": " المجموعة", "probability": 0.95791015625}, {"start": 2095.65, "end": 2099.93, "word": " CH2SH", "probability": 0.8977864583333334}, {"start": 2099.93, "end": 2100.43, "word": " وهنا", "probability": 0.86376953125}, {"start": 2100.43, "end": 2100.67, 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بيعملوا hydrolysis ال peptides واضح؟ hydrolysis peptide hydrolysis بدو يتكسر ضايق الاشياء؟", "tokens": [11622, 16373, 3215, 23032, 3555, 3615, 995, 6245, 17, 9122, 2304, 7649, 6245, 17, 5995, 6866, 5995, 17, 17308, 37893, 17082, 12610, 995, 4724, 1829, 25957, 1211, 14407, 15435, 356, 17122, 2423, 41781, 1875, 4032, 46958, 5016, 22807, 15435, 356, 17122, 41781, 482, 15435, 356, 17122, 47525, 2407, 7251, 2655, 4117, 3794, 2288, 48812, 47302, 4587, 2423, 33599, 1829, 16606, 22807], "avg_logprob": -0.2971270247813194, "compression_ratio": 1.2448979591836735, "no_speech_prob": 0.0, "words": [{"start": 2320.13, "end": 2320.97, "word": "زائد", "probability": 0.8069661458333334}, {"start": 2320.97, "end": 2322.31, "word": " طبعا", "probability": 0.8304443359375}, {"start": 2322.31, "end": 2323.13, "word": " nh2", "probability": 0.6480712890625}, {"start": 2323.13, "end": 2323.59, "word": " كمان", "probability": 0.7496744791666666}, {"start": 2323.59, "end": 2324.47, "word": " nh2", 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22807, 9122, 36081, 11536, 36764, 24401, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 1975, 25513, 27884, 16490, 2304, 3794, 3660, 8608, 2655, 3660, 1975, 15730, 23758, 6225, 3555, 9640, 3660, 18871, 1045], "avg_logprob": -0.19631410307354397, "compression_ratio": 2.0108108108108107, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2857.97, "end": 2858.35, "word": "اذا", "probability": 0.52386474609375}, {"start": 2858.35, "end": 2858.69, "word": " هذا", "probability": 0.8564453125}, {"start": 2858.69, "end": 2859.21, "word": " صار", "probability": 0.6585693359375}, {"start": 2859.21, "end": 2860.03, "word": " اثل", "probability": 0.599853515625}, {"start": 2860.03, "end": 2860.45, "word": " فور", "probability": 0.5694580078125}, {"start": 2860.45, "end": 2861.49, "word": " هيدروكسي", "probability": 0.84912109375}, {"start": 2861.49, "end": 2863.11, "word": " توبنتينويت", "probability": 0.60546875}, {"start": 2863.11, "end": 2863.77, "word": " اثل", "probability": 0.8426106770833334}, {"start": 2863.77, "end": 2864.35, "word": " فور", "probability": 0.977294921875}, {"start": 2864.35, "end": 2865.45, "word": " هيدروكسي", "probability": 0.9449055989583334}, {"start": 2865.45, "end": 2867.33, "word": " توبنتينويت", "probability": 0.9547526041666666}, {"start": 2867.33, "end": 2869.05, "word": " واضح؟", "probability": 0.778564453125}, {"start": 2869.05, "end": 2869.95, "word": " نسمي", "probability": 0.76416015625}, {"start": 2869.95, "end": 2870.23, "word": " اخر", "probability": 0.6876220703125}, {"start": 2870.23, "end": 2870.55, "word": " اتنين", "probability": 0.947998046875}, {"start": 2870.55, "end": 2871.09, "word": " ونخلص", "probability": 0.90859375}, {"start": 2871.09, "end": 2871.35, "word": " بعد", "probability": 0.9306640625}, {"start": 2871.35, "end": 2871.69, "word": " عشر", "probability": 0.95751953125}, {"start": 2871.69, "end": 2872.41, "word": " ثواني", "probability": 0.8763427734375}, {"start": 2872.41, "end": 2873.53, "word": " هذا", "probability": 0.94287109375}, {"start": 2873.53, "end": 2874.39, "word": " المركب", "probability": 0.9033203125}, {"start": 2874.39, "end": 2874.73, "word": " اللي", "probability": 0.8759765625}, {"start": 2874.73, "end": 2875.29, "word": " شايفينه", "probability": 0.97265625}, {"start": 2875.29, "end": 2875.63, "word": " عبارة", "probability": 0.9921875}, {"start": 2875.63, "end": 2875.85, "word": " عن", "probability": 0.98681640625}, {"start": 2875.85, "end": 2876.75, "word": " ايش؟", "probability": 0.8048095703125}, {"start": 2876.75, "end": 2877.67, "word": " كيتون", "probability": 0.8427734375}, {"start": 2877.67, "end": 2878.75, "word": " واحد", "probability": 0.784423828125}, {"start": 2878.75, "end": 2879.33, "word": " اتنين", "probability": 0.965087890625}, {"start": 2879.33, "end": 2879.99, "word": " تلاتة", "probability": 0.9134521484375}, {"start": 2879.99, "end": 2880.51, "word": " اربعة", "probability": 0.8971354166666666}, {"start": 2880.51, "end": 2881.53, "word": " خمسة", "probability": 0.975830078125}, {"start": 2881.53, "end": 2883.05, "word": " ستة", "probability": 0.9718424479166666}, {"start": 2883.05, "end": 2883.49, "word": " اذا", "probability": 0.811767578125}, {"start": 2883.49, "end": 2883.81, "word": " هذا", "probability": 0.8388671875}, {"start": 2883.81, "end": 2884.25, "word": " عبارة", "probability": 0.9952392578125}, {"start": 2884.25, "end": 2884.59, "word": " عن", "probability": 0.9921875}, {"start": 2884.59, "end": 2886.09, "word": " three", "probability": 0.26220703125}], "temperature": 1.0}, {"id": 105, "seek": 291624, "start": 2887.34, "end": 2916.24, "text": "هكسانون شو بيحمل ال three hexanone مثل و دايمثل بيحط مواقعهم يعني two مثل و six daimethylamino هذي إيش اسمها الآن مثل مثل six daimethylamino المركب الأخير هذا مر علينا في ال unhydrate افتلك unhydrate", "tokens": [3224, 4117, 3794, 7649, 11536, 13412, 2407, 4724, 1829, 35571, 1211, 2423, 1045, 23291, 282, 546, 50113, 1211, 4032, 11778, 995, 32640, 12984, 1211, 4724, 1829, 5016, 9566, 3714, 14407, 4587, 3615, 16095, 37495, 22653, 732, 50113, 1211, 4032, 2309, 1120, 332, 3293, 88, 4326, 2982, 8032, 8848, 1829, 11933, 1829, 8592, 24525, 2304, 11296, 6024, 48506, 50113, 1211, 50113, 1211, 2309, 1120, 332, 3293, 88, 4326, 2982, 9673, 31747, 3555, 16247, 9778, 13546, 23758, 3714, 2288, 25894, 8315, 8978, 2423, 517, 21591, 4404, 1975, 5172, 2655, 23275, 517, 21591, 4404], "avg_logprob": -0.2922894096244936, "compression_ratio": 1.574468085106383, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2887.34, "end": 2888.54, "word": "هكسانون", "probability": 0.7371337890625}, {"start": 2888.54, "end": 2889.04, "word": " شو", "probability": 0.6885986328125}, {"start": 2889.04, "end": 2889.5, "word": " بيحمل", "probability": 0.9808349609375}, {"start": 2889.5, "end": 2889.64, "word": " ال", "probability": 0.75927734375}, {"start": 2889.64, "end": 2889.78, "word": " three", "probability": 0.43603515625}, {"start": 2889.78, "end": 2890.52, "word": " hexanone", "probability": 0.7060546875}, {"start": 2890.52, "end": 2891.12, "word": " مثل", "probability": 0.9208984375}, {"start": 2891.12, "end": 2892.46, "word": " و", "probability": 0.88525390625}, {"start": 2892.46, "end": 2893.14, "word": " دايمثل", "probability": 0.75419921875}, {"start": 2893.14, "end": 2893.8, "word": " بيحط", "probability": 0.66534423828125}, {"start": 2893.8, "end": 2894.72, "word": " مواقعهم", "probability": 0.9640625}, {"start": 2894.72, "end": 2895.8, "word": " يعني", "probability": 0.817138671875}, {"start": 2895.8, "end": 2896.08, "word": " two", "probability": 0.85595703125}, {"start": 2896.08, "end": 2896.96, "word": " مثل", "probability": 0.839599609375}, {"start": 2896.96, "end": 2897.42, "word": " و", "probability": 0.875}, {"start": 2897.42, "end": 2897.94, "word": " six", "probability": 0.8408203125}, {"start": 2897.94, "end": 2899.54, "word": " daimethylamino", "probability": 0.6846516927083334}, {"start": 2899.54, "end": 2900.2, "word": " هذي", "probability": 0.5343017578125}, {"start": 2900.2, "end": 2900.32, "word": " إيش", "probability": 0.8035481770833334}, {"start": 2900.32, "end": 2900.7, "word": " اسمها", "probability": 0.8504231770833334}, {"start": 2900.7, "end": 2900.92, "word": " الآن", "probability": 0.652587890625}, {"start": 2900.92, "end": 2901.3, "word": " مثل", "probability": 0.956787109375}, {"start": 2901.3, "end": 2901.72, "word": " مثل", "probability": 0.9912109375}, {"start": 2901.72, "end": 2903.02, "word": " six", "probability": 0.33837890625}, {"start": 2903.02, "end": 2904.32, "word": " daimethylamino", "probability": 0.9130859375}, {"start": 2904.32, "end": 2906.0, "word": " المركب", "probability": 0.8948567708333334}, {"start": 2906.0, "end": 2906.8, "word": " الأخير", "probability": 0.9173177083333334}, {"start": 2906.8, "end": 2907.2, "word": " هذا", "probability": 0.623046875}, {"start": 2907.2, "end": 2907.5, "word": " مر", "probability": 0.897705078125}, {"start": 2907.5, "end": 2907.84, "word": " علينا", "probability": 0.947265625}, {"start": 2907.84, "end": 2908.0, "word": " في", "probability": 0.86328125}, {"start": 2908.0, "end": 2908.14, "word": " ال", "probability": 0.9541015625}, {"start": 2908.14, "end": 2909.12, "word": " unhydrate", "probability": 0.58984375}, {"start": 2909.12, "end": 2910.5, "word": " افتلك", "probability": 0.79425048828125}, {"start": 2910.5, "end": 2916.24, "word": " unhydrate", "probability": 0.6554361979166666}], "temperature": 1.0}, {"id": 106, "seek": 292872, "start": 2917.52, "end": 2928.72, "text": "على اي حال بيكفي لهذا الجزء الباقي عبارة عن معادلات شبيهة بالامثلة التانية، بننهي الآن و بنتمنى لكم التوفيق", "tokens": [3615, 23942, 1975, 1829, 11331, 6027, 4724, 1829, 4117, 41185, 46740, 15730, 25724, 11622, 38207, 29739, 995, 38436, 6225, 3555, 9640, 3660, 18871, 20449, 18513, 1211, 9307, 13412, 21292, 3224, 3660, 20666, 10943, 12984, 37977, 16712, 7649, 10632, 12399, 44945, 1863, 3224, 1829, 6024, 48506, 4032, 4724, 29399, 27842, 7578, 5296, 24793, 16712, 38688, 1829, 4587], "avg_logprob": -0.16529605890575208, "compression_ratio": 1.5193798449612403, "no_speech_prob": 0.0, "words": [{"start": 2917.52, "end": 2917.8, "word": "على", "probability": 0.916748046875}, {"start": 2917.8, "end": 2918.0, "word": " اي", "probability": 0.68017578125}, {"start": 2918.0, "end": 2918.28, "word": " حال", "probability": 0.99755859375}, {"start": 2918.28, "end": 2919.46, "word": " بيكفي", "probability": 0.72076416015625}, {"start": 2919.46, "end": 2920.4, "word": " لهذا", "probability": 0.92529296875}, {"start": 2920.4, "end": 2920.82, "word": " الجزء", "probability": 0.96484375}, {"start": 2920.82, "end": 2921.36, "word": " الباقي", "probability": 0.96728515625}, {"start": 2921.36, "end": 2921.98, "word": " عبارة", "probability": 0.9600830078125}, {"start": 2921.98, "end": 2922.14, "word": " عن", "probability": 0.9873046875}, {"start": 2922.14, "end": 2922.92, "word": " معادلات", "probability": 0.9893798828125}, {"start": 2922.92, "end": 2923.52, "word": " شبيهة", "probability": 0.8448486328125}, {"start": 2923.52, "end": 2924.08, "word": " بالامثلة", "probability": 0.890625}, {"start": 2924.08, "end": 2925.16, "word": " التانية،", "probability": 0.7880859375}, {"start": 2925.16, "end": 2925.86, "word": " بننهي", "probability": 0.846435546875}, {"start": 2925.86, "end": 2926.32, "word": " الآن", "probability": 0.7890625}, {"start": 2926.32, "end": 2926.86, "word": " و", "probability": 0.607421875}, {"start": 2926.86, "end": 2927.46, "word": " بنتمنى", "probability": 0.75970458984375}, {"start": 2927.46, "end": 2927.82, "word": " لكم", "probability": 0.90380859375}, {"start": 2927.82, "end": 2928.72, "word": " التوفيق", "probability": 0.9820556640625}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2929.476, "duration_after_vad": 2695.5443749999886}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/pFcXHJf6vU8.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/pFcXHJf6vU8.srt
new file mode 100644
index 0000000000000000000000000000000000000000..6c6838494e3d9e25014d3428edc8dd042c4479c9
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/pFcXHJf6vU8.srt
@@ -0,0 +1,1451 @@
+1
+00:00:21,450 --> 00:00:26,690
+بسم الله الرحمن الرحيم طبعا سعداء أن نلتقي
+
+2
+00:00:26,690 --> 00:00:31,710
+بكم في المحاضرة الأولى في هذا المساق، هذا مساق
+
+3
+00:00:31,710 --> 00:00:38,510
+كيمياء عضوية أو كيمياء عضوية وحيوية يدرس عادة بأرقام
+
+4
+00:00:38,510 --> 00:00:43,510
+مختلفة في الجامعة لأكثر من تخصص، يعني لطلبة العلوم
+
+5
+00:00:43,510 --> 00:00:49,690
+الصحية. نحن ندرسه بالرقم Bioc 1301 لطلبة كلية
+
+6
+00:00:49,690 --> 00:00:55,770
+الطب، ندرسه بالرقم Medic 1310، ولطلبة العلوم
+
+7
+00:00:55,770 --> 00:00:59,390
+الحياتية، البيولوجيا والبيئة وما إلى ذلك، أيضا
+
+8
+00:00:59,390 --> 00:01:07,060
+ندرسه برقم Chem 2311. فكل هؤلاء الطلبة، بإذن الله
+
+9
+00:01:07,060 --> 00:01:10,700
+يستطيعون أن يستفيدوا من هذا المساق، والذي يعني
+
+10
+00:01:10,700 --> 00:01:15,900
+إن شاء الله سيكون مسجلا، حتى يمكنكم تدارك أي
+
+11
+00:01:15,900 --> 00:01:19,760
+معلومات نقصت عليكم أثناء سماع المحاضرة
+
+12
+00:01:19,760 --> 00:01:24,960
+الأصلية. مسموح طبعا أن يكون هناك نقاش علمي هادف، و
+
+13
+00:01:24,960 --> 00:01:29,280
+يظهر في التصوير. أنتم كلكم أيضا واضحون أمام
+
+14
+00:01:29,280 --> 00:01:35,120
+الكاميرات، ومناقشاتكم ستكون مثمرة لتدريس هذا
+
+15
+00:01:35,120 --> 00:01:40,020
+المساق، إن شاء الله. الكتاب
+
+16
+00:01:40,020 --> 00:01:45,600
+المقرر هو كتاب مشهور جدا في مجاله، كتاب Organic
+
+17
+00:01:45,600 --> 00:01:50,540
+Chemistry للمؤلف Hart and Hart. هذا الكتاب طبعا
+
+18
+00:01:50,540 --> 00:01:55,700
+مع المحتويات الإلكترونية كلها متوفرة لكم، إن شاء
+
+19
+00:01:55,700 --> 00:02:01,560
+الله. الجزء الأول من المساق الذي سندرسه، مقدمة في
+
+20
+00:02:01,560 --> 00:02:06,220
+الكيمياء العضوية، نتعرف جيدا على المجموعات الوظيفية
+
+21
+00:02:06,220 --> 00:02:10,420
+وأنواع المركبات العضوية. هذه المقدمة في الكيمياء
+
+22
+00:02:10,420 --> 00:02:16,400
+العضوية حوالي 11 فصلا. لما تصبح موجودة عندنا بشكل
+
+23
+00:02:16,400 --> 00:02:21,960
+جيد، يصبح بإمكاننا أن نعطي بعدها مقدمة في الكيمياء
+
+24
+00:02:21,960 --> 00:02:28,080
+الحيوية بأربعة فصول، إن شاء الله. بهذه الطريقة يكون يعني الـ
+
+25
+00:02:28,080 --> 00:02:32,660
+Course اكتملت مكوناته، مقدمة في الكيمياء العضوية، و
+
+26
+00:02:32,660 --> 00:02:36,220
+بعد ذلك الجزء الثاني من الـ Course، مقدمة في
+
+27
+00:02:36,220 --> 00:02:43,110
+الكيمياء الحيوية. طبعا، سنبدأ مباشرة، لنضيع وقتا.
+
+28
+00:02:43,110 --> 00:02:47,830
+الفصل الأول في المقدمة في الكيمياء العضوية، مفاهيم
+
+29
+00:02:47,830 --> 00:02:51,750
+عامة، خاصة أنكم أخذتم شيئين، أخذتم
+
+30
+00:02:51,750 --> 00:02:56,730
+كيمياء عامة في الجامعة، وأخذتم أشياء مختلفة من
+
+31
+00:02:56,730 --> 00:03:02,090
+الكيمياء في المدارس، بعضها أحيانا، أو جزء خفيف في
+
+32
+00:03:02,090 --> 00:03:06,830
+الكيمياء العضوية. هذه المبادئ الأساسية،
+
+33
+00:03:06,830 --> 00:03:11,710
+تساعدكم في أن تتعاملوا مع مساق الكيمياء العضوية.
+
+34
+00:03:11,710 --> 00:03:19,130
+هذا الفصل في المقدمة، سنتحدث فيه عن الارتباط
+
+35
+00:03:19,130 --> 00:03:22,990
+والتشكل (bonding and isomerism). يعني، طالما أننا
+
+36
+00:03:22,990 --> 00:03:28,650
+نتحدث عن مركبات في الكيمياء العضوية، أكيد ذرات معينة
+
+37
+00:03:28,650 --> 00:03:34,950
+ستتّصل، تُعطي مركبا (bonding). الآن، هذه الذرات التي
+
+38
+00:03:34,950 --> 00:03:40,550
+تتّصل، يمكن أن تتّصل بطرق مختلفة، وبالتالي يمكن أن
+
+39
+00:03:40,550 --> 00:03:46,910
+تعطي أكثر من مركب، أكثر من شكل، أو متشكل، تماما كما
+
+40
+00:03:46,910 --> 00:03:51,360
+أنا أتعامل مع هذه الأقلام. هنا، أستطيع عمل ارتباط
+
+41
+00:03:51,360 --> 00:03:54,920
+بينها، كأنني عملت مركبا. يعني، لو تخيّلتم أن هذه
+
+42
+00:03:54,920 --> 00:03:58,840
+ثلاث ذرات، مثلا Carbon, Hydrogen, Oxygen، عملوا
+
+43
+00:03:58,840 --> 00:04:03,820
+مركبا بطريقة معينة. الآن، لو غيرت ترتيب هذه الذرات،
+
+44
+00:04:04,600 --> 00:04:10,560
+أكون قد عملت مركبا آخر. واضح؟ لو غيّرت هذه
+
+45
+00:04:10,560 --> 00:04:14,760
+الذرات، أكون قد عملت مركبا آخر. الآن، المركب الأول، و
+
+46
+00:04:14,760 --> 00:04:19,540
+المركب الثاني، ما العلاقة بينهما؟ هذين المركبين،
+
+47
+00:04:19,540 --> 00:04:25,180
+نسميهما ماذا؟ isomers. يعني، لما نقول المركب A، و
+
+48
+00:04:25,180 --> 00:04:31,360
+المركب B، they are isomers، متشكلات. الآن، الظاهرة كلها
+
+49
+00:04:31,360 --> 00:04:37,980
+ماذا نسميها؟ isomerism، ظاهرة التشكل، وسنتعمق في
+
+50
+00:04:37,980 --> 00:04:43,280
+هذا الموضوع بالتأكيد أثناء دراستنا، سنتعمق في هذا
+
+51
+00:04:43,280 --> 00:04:48,510
+الموضوع أثناء دراستنا. الآن، إذا أردنا أن نبدأ في موضوع
+
+52
+00:04:48,510 --> 00:04:53,950
+الـ bonding، طبعا مرّ عليكم أنواع الروابط، مرّ عليكم
+
+53
+00:04:53,950 --> 00:04:57,770
+أنواع الروابط التي تتكون داخل الجزيئة. أرجو
+
+54
+00:04:57,770 --> 00:05:01,390
+أن تنتبهوا لما أقصده أنا في الـ bonding، الذي
+
+55
+00:05:01,390 --> 00:05:06,270
+أقصده في الـ bonding، ليس الروابط بين الجزيئات، التي
+
+56
+00:05:06,270 --> 00:05:11,070
+اسمها Intermolecular forces. لا، الروابط داخل
+
+57
+00:05:11,070 --> 00:05:16,720
+الجزيئة. الروابط داخل الجزيء، يعني، في روابط بين
+
+58
+00:05:16,720 --> 00:05:22,520
+الجزيئات، ليست هي المقصودة هنا. يعني، افترضوا مثلا جزيء
+
+59
+00:05:22,520 --> 00:05:31,420
+الماء H2O. الآن، هذا جزيء، هذه جزيء ماء آخر H2O.
+
+60
+00:05:33,470 --> 00:05:38,730
+الآن، هذه الروابط التي داخل الجزيء، هي التي أنا
+
+61
+00:05:38,730 --> 00:05:44,650
+أقصدها. في الكيمياء، نعطيها اسما، نقول عنها Intra-
+
+62
+00:05:44,650 --> 00:05:49,650
+molecular bonds، يعني، روابط within the molecule، داخل
+
+63
+00:05:49,650 --> 00:05:54,030
+الجزيء. يعني، هذه الروابط، ماذا نقول عنها؟ Intra-
+
+64
+00:05:56,090 --> 00:06:01,750
+molecular bonds. Intra-، يعني روابط داخل الجزيء. الآن،
+
+65
+00:06:01,750 --> 00:06:04,550
+إذا جئت بعد ذلك، قلت مثلا، في عندي روابط
+
+66
+00:06:04,550 --> 00:06:09,620
+هيدروجينية بين الأكسجين والهيدروجين، هذه روابط بين
+
+67
+00:06:09,620 --> 00:06:15,160
+الجزيئات، Intermolecular forces. فميّزوا الكلمتين،
+
+68
+00:06:15,160 --> 00:06:20,940
+Intramolecular، التي هي الروابط الأصلية القوية التي
+
+69
+00:06:20,940 --> 00:06:25,720
+داخل الجزيء، بينما الروابط بين الجزيئات، between
+
+70
+00:06:25,720 --> 00:06:31,070
+molecules، ماذا أسميها أنا؟ Intermolecular forces.
+
+71
+00:06:31,070 --> 00:06:37,790
+الأقوى نوعا في الـ Intermolecular forces، هذه قوتها
+
+72
+00:06:37,790 --> 00:06:42,230
+لا تصل إلى خمسة إلى عشرة في المئة من قوة هذه الروابط.
+
+73
+00:06:42,230 --> 00:06:47,250
+بمعنى، لو أنا أريد أن أكسر الروابط، من السهل أني
+
+74
+00:06:47,250 --> 00:06:53,210
+أكسر الـ Intermolecular forces، تماما كما نتخيل
+
+75
+00:06:53,210 --> 00:06:59,070
+اثنين يأتيان، يُسلّمان على بعضهما، في رابطة أصلية، رابطة
+
+76
+00:06:59,070 --> 00:07:04,750
+هذه الكف مع الجسم، هذه Intramolecular، وفي رابطة
+
+77
+00:07:04,750 --> 00:07:08,010
+بين الاثنين اللذين يُسلّمان على بعضهما، هذه
+
+78
+00:07:08,010 --> 00:07:13,110
+Intermolecular. الآن، لو ولدان صغيران سلّما على بعضهما، و
+
+79
+00:07:13,110 --> 00:07:16,550
+الأم، كل واحدة تريد أن تسحب ابنها وتمشي في طريقها،
+
+80
+00:07:16,550 --> 00:07:22,030
+تسحب الولد، هي التي تنكسر، هذه الرابطة، أم
+
+81
+00:07:22,030 --> 00:07:26,400
+هذه الرابطة؟ هذه الرابطة، الـ Intermolecular Forces.
+
+82
+00:07:26,400 --> 00:07:29,500
+فالـ Intermolecular Forces، منها الـ London
+
+83
+00:07:29,500 --> 00:07:32,740
+Forces، والـ Dipole-Dipole Attractions، والـ
+
+84
+00:07:32,740 --> 00:07:37,780
+Hydrogen Bonding. هذه روابط ضعيفة بين الجزيئات،
+
+85
+00:07:37,780 --> 00:07:41,500
+تأثر بشكل كبير على الخواص الفيزيائية، لكن لما أنا
+
+86
+00:07:41,500 --> 00:07:46,600
+أبدأ أدرس تفاعلات، وأقول أن التفاعل الكيميائي بعد
+
+87
+00:07:46,600 --> 00:07:52,500
+قليل، كسر وتكوين روابط، أنا لا أتحدث اطلاقا عن هذه
+
+88
+00:07:52,500 --> 00:07:57,340
+الروابط. أنا أتحدث عن الروابط within the molecule،
+
+89
+00:07:57,340 --> 00:08:02,640
+الـ Intramolecular forces. ولما الآن نصنّف أنواع
+
+90
+00:08:02,640 --> 00:08:07,860
+هذه الروابط، ونتحدث عن Ionic bonds، و Covalent bonds، و
+
+91
+00:08:07,860 --> 00:08:11,680
+Coordinate covalent bonds، نكون نتحدث عن الروابط
+
+92
+00:08:11,680 --> 00:08:18,580
+التي داخل الجزيء، الـ Intramolecular. واضح؟ التي
+
+93
+00:08:18,580 --> 00:08:24,020
+تكون الجزيء نفسه. الآن، من هذه الروابط، كما سبق
+
+94
+00:08:24,020 --> 00:08:27,540
+أن تعلمتم، من هذه الروابط، كما سبق أن
+
+95
+00:08:27,540 --> 00:08:33,020
+تعلمتم، الـ Ionic bonds. الـ Ionic bonds تنشأ عندما
+
+96
+00:08:33,020 --> 00:08:37,680
+يتكون عند أيونات، في عناصر معينة، عندها إلكترونات
+
+97
+00:08:37,680 --> 00:08:42,080
+زيادة، عادة تكون موجودة في أول الجدول الدوري، على
+
+98
+00:08:42,080 --> 00:08:47,840
+اليسار. نسميها electropositive atoms، مثل الصوديوم
+
+99
+00:08:47,840 --> 00:08:51,240
+على سبيل المثال، وكلكم تعرفون تركيبه الإلكتروني،
+
+100
+00:08:51,240 --> 00:08:57,780
+1s2 2s2 2p6 3s1، لأنه عنده إلكترون زيادة. لو فقده،
+
+101
+00:08:57,780 --> 00:09:02,600
+يصل إلى الـ octet structure. واضح؟ لكن لما يفقد، سيصبح
+
+102
+00:09:02,600 --> 00:09:08,580
+عبارة عن أيون موجب. في عند ذرات نقول عنها electro-
+
+103
+00:09:08,580 --> 00:09:13,000
+negative atoms. هؤلاء ينقصهم إلكترون ليصلوا إلى
+
+104
+00:09:13,000 --> 00:09:18,480
+الـ octet structures. هؤلاء، لو اكتسبوا، لو اكتسبوا هذا
+
+105
+00:09:18,480 --> 00:09:25,500
+الإلكترون، يصبحون أيونات سالبة، مثل الكلور مثلا، 1s2
+
+106
+00:09:25,500 --> 00:09:32,320
+2s2 2p6، بعد ذلك يصبح عنده 3s2 3p5. هذا الـ 3p5 ما زال
+
+107
+00:09:32,320 --> 00:09:37,660
+عنده مساحة لإلكترون واحد. لو اكتسب هذا الإلكترون،
+
+108
+00:09:37,660 --> 00:09:42,890
+طبعا سيُكتسب من الصوديوم. سيصبح الكلور
+
+109
+00:09:42,890 --> 00:09:47,990
+سالبا. إذا، هنا أصبح عندك صوديوم موجب، وأصبح عندك
+
+110
+00:09:47,990 --> 00:09:51,490
+كلور سالب. هذين الأيونين، لما يُحدثان الـ attraction
+
+111
+00:09:51,490 --> 00:09:57,690
+مع بعض، يكونان الـ ionic bond. واضح؟ طبعا، ممكن
+
+112
+00:09:57,690 --> 00:10:02,250
+بعض العناصر التي في المجموعة الثانية، تفقد
+
+113
+00:10:02,250 --> 00:10:07,880
+إلكترونين، وتصبح أيونات موجبة ثنائية. ممكن تفقد
+
+114
+00:10:07,880 --> 00:10:11,240
+ثلاثا، مثلا، مثل الألمنيوم، موجب ثلاثة. كل هذا الكلام
+
+115
+00:10:11,240 --> 00:10:16,360
+تعلمتموه، وكيف نكتب صيغة مركب أيوني، هذا
+
+116
+00:10:16,360 --> 00:10:20,720
+الكلام كله مرّ عليكم في الكيمياء العامة.
+
+117
+00:10:20,720 --> 00:10:29,460
+بالنسبة إلى الـ covalent compounds، يختلفون بشيء أن
+
+118
+00:10:30,790 --> 00:10:35,610
+الروابط التي تتكون، تتكون نتيجة مشاركة في
+
+119
+00:10:35,610 --> 00:10:39,210
+الإلكترونات. يعني، هذه عندها إلكترونات معينة، هذه
+
+120
+00:10:39,210 --> 00:10:43,990
+عندها إلكترونات، يُحدثان مشاركة للإلكترون، فكل ذرة
+
+121
+00:10:43,990 --> 00:10:48,370
+تصل إلى التركيب الذي هو المستقر. إذا كنا نتحدث عن
+
+122
+00:10:48,370 --> 00:10:51,710
+هيدروجين، كل ذرة تصبح اثنين، اثنين، مثل ما
+
+123
+00:10:51,710 --> 00:10:56,330
+نتخيل هيدروجين فيه إلكترون، وهذا هيدروجين
+
+124
+00:10:56,330 --> 00:11:00,050
+فيه إلكترون، سيُحدثان جزيء الهيدروجين، كأنه الآن كل
+
+125
+00:11:00,050 --> 00:11:03,590
+ذرة هيدروجين عندها كم إلكترون؟ اثنين. هذا التركيب
+
+126
+00:11:03,590 --> 00:11:09,840
+ثابت. أو الكلور مثلا، مداره الأخير فيه سبع إلكترونات،
+
+127
+00:11:09,840 --> 00:11:14,460
+الـ valence shell، الموجود فيه. الآن، لما أنا أحكي
+
+128
+00:11:14,460 --> 00:11:18,940
+عن سبع إلكترونات، لو صارت مشاركة في هذه الإلكترونات،
+
+129
+00:11:18,940 --> 00:11:23,780
+صارت كل ذرة كلور، كم إلكترون حولها؟ ثمانية. إذا
+
+130
+00:11:23,780 --> 00:11:29,240
+عملنا covalent compound. كذلك، لو أردت أخذ H مع Cl،
+
+131
+00:11:29,240 --> 00:11:36,830
+أيضا، الرابطة ماذا ستكون؟ covalent bond. الـ bonds هذه،
+
+132
+00:11:36,830 --> 00:11:42,130
+الـ bonds هذه، لها شيء نسميه bond energy. هذا
+
+133
+00:11:42,130 --> 00:11:47,530
+تعبير عن قوة الروابط. الـ bond energy، هي الطاقة
+
+134
+00:11:47,530 --> 00:11:54,570
+اللازمة لكسر روابط مول واحد من الروابط. مول واحد،
+
+135
+00:11:54,570 --> 00:11:59,410
+عرفناه، عدد أفوجادرو، 6.022 × 10^23، تقريبا.
+
+136
+00:11:59,410 --> 00:12:04,030
+لآن، عشان أكسر هذه الروابط، هذه
+
+137
+00:12:04,030 --> 00:12:08,590
+رابطة، لما أقول أريد أن أكسر الرابطة، ماذا أريد؟ أريد
+
+138
+00:12:08,590 --> 00:12:14,870
+طاقة. دائما معروف عندنا أن كسر الرابطة، عملية تحتاج
+
+139
+00:12:14,870 --> 00:12:21,590
+إلى طاقة، نقول عنها endothermic process، بينما تكوين
+
+140
+00:12:21,590 --> 00:12:26,810
+الرابطة، عملية طاردة للطاقة، نقول عنها exothermic
+
+141
+00:12:26,810 --> 00:12:31,930
+process. فالـ bond energy، هي الطاقة اللازمة لكسر
+
+142
+00:12:31,930 --> 00:12:36,170
+روابط، أو مول واحد من الروابط، من الـ covalent bonds.
+
+143
+00:12:36,170 --> 00:12:41,180
+كذلك، في عندي ماذا؟ الـ bond length. الـ bond length
+
+144
+00:12:41,180 --> 00:12:48,660
+هو المسافة المتوسطة بين ذرتين. لماذا مسافة متوسطة؟
+
+145
+00:12:48,660 --> 00:12:54,420
+لأن الرابطة هي عبارة عن مسافة في الفراغ، ليست ثابتة.
+
+146
+00:12:54,420 --> 00:12:58,260
+يعني، ذرتان بينهما مسافة معينة في الفراغ، نقول هذان
+
+147
+00:12:58,260 --> 00:13:03,240
+الذرتان بينهما ماذا؟ رابطة. الآن، هذه المسافة تزيد
+
+148
+00:13:03,240 --> 00:13:08,500
+وتقصر، ليست ثابتة تماما، ولذلك نحن نأخذ المسافة
+
+149
+00:13:08,500 --> 00:13:12,000
+المتوسطة، فيصبح عندنا الـ bond length. الآن، الـ bond
+
+150
+00:13:12,000 --> 00:13:17,660
+length يُقاس عادة بالـ angstrom، الذي هو 1 × 10^-10 متر، أو نقيسه بالـ picometer،
+
+151
+00:13:17,660 --> 00:13:22,300
+الذي هو 1 × 10^-12 متر. واضح؟
+
+152
+00:13:22,300 --> 00:13:28,140
+طبعا، لما نقيس الـ bond length بالـ picometer، ستظهر
+
+153
+00:13:28,140 --> 00:13:34,010
+أطوال الروابط عندنا سهلة الملاحظة وسهلة الحفظ. يعني،
+
+154
+00:13:34,010 --> 00:13:39,330
+دعوني أُريكُم كيف هي. أنا أعطيكم مقارنة بين الرابطة
+
+155
+00:13:39,330 --> 00:13:44,630
+الأحادية، هذه الرابطة التي أقصدها، الأحادية،
+
+156
+00:13:44,630 --> 00:13:49,590
+والثنائية، والرابطة
+
+157
+00:13:49,590 --> 00:13:52,890
+الثلاثية. الآن، لاحظوا أن عدد الروابط يزيد، أحادية،
+
+158
+00:13:54,550 --> 00:14:01,830
+ثنائية، ثلاثية. هذا، نحن نسميه الـ bond order.  ما هو الـ
+
+159
+00:14:01,830 --> 00:14:07,970
+bond order؟ الـ bond order is the number of chemical
+
+160
+00:14:07,970 --> 00:14:11,490
+bonds between a pair of atoms. عدد الروابط بين
+
+161
+00:14:11,490 --> 00:14:15,850
+ذرتين. هل هذه الروابط، منها ذرتان، أحادية، ثنائية،
+
+162
+00:14:15,850 --> 00:14:22,270
+ثلاثية؟ ما أسمي أنا الـ bond order؟ الآن، انتبهوا معي،
+
+163
+00:14:22,270 --> 00:14:28,490
+as the bond order increases، يعني، كلما زاد من
+
+164
+00:14:28,490 --> 00:14:31,970
+الرابط، أحادية، لا، ثنائية، لا، ثلاثية، نقول the bond
+
+165
+00:14:31,970 --> 00:14:36,150
+will be stronger and shorter، تصبح أقوى وأقصر.
+
+166
+00:14:36,150 --> 00:14:43,810
+لماذا؟ لأن الرابطة الأحادية هي عبارة عن sigma bond،
+
+167
+00:14:43,810 --> 00:14:48,270
+الرابطة الثلاثية هي عبارة عن سيجما و باي، ولذلك
+
+168
+00:14:49,600 --> 00:14:56,440
+أصبحت أقوى.
+169
+00:14:56,440 --> 00:14:57,900
+أصبحت أقوى.
+
+170
+00:15:06,370 -->
+
+223
+00:20:03,330 --> 00:20:07,890
+بيعملوا رابطة واحدة و بيبقى عليهم كام زوج من
+
+224
+00:20:07,890 --> 00:20:13,190
+الإلكترونات؟ ثلاث أزواج، واضح؟ الآن أنا راسم
+
+225
+00:20:13,190 --> 00:20:20,730
+مركب كبير. لو بتتطلع عليه، كل رأس في هذا المركب
+
+226
+00:20:20,730 --> 00:20:25,770
+يمثل ذرة كربون. إذا لاقيتوا شيء ناقص في أعداد
+
+227
+00:20:25,770 --> 00:20:30,270
+الروابط، معناه أن هذا الشيء الناقص هو عبارة عن
+
+228
+00:20:30,270 --> 00:20:34,910
+هيدروجين، مُختصر في الكتابة لأننا عندنا شيء
+
+229
+00:20:34,910 --> 00:20:38,530
+بنسميه abbreviated structure، اللي هو شكل مختصر.
+
+230
+00:20:38,530 --> 00:20:43,590
+يعني ما الذي يُفهم ضمنه مرات لا نكتبه، واضح؟ الذي
+
+231
+00:20:43,590 --> 00:20:47,930
+يُفهم ضمنه مرات لا نكتبه. فلاحظوا مثلاً هذه الذرات
+
+232
+00:20:47,930 --> 00:20:53,830
+carbon، هذه carbon، هذه carbon، carbon، كل هذه
+
+233
+00:20:53,830 --> 00:20:59,630
+الذرات، كل رأس هنا في الرسم يعتبر ذرة carbon، و هذه
+
+234
+00:20:59,630 --> 00:21:04,470
+كمان carbon. لو بنطلع عليهم كلهم، كلهم عليهم أربع
+
+235
+00:21:04,470 --> 00:21:08,610
+روابط. إذا في شيء مبين أقل، معناه أن هذا فيه
+
+236
+00:21:08,610 --> 00:21:15,600
+هيدروجين، مُختصر الكتابة. يعني هذه CH3، مبينين أربع
+
+237
+00:21:15,600 --> 00:21:19,720
+روابط هنا. يمكن تطلع كربون متصلة بكربون وكربون. إذا
+
+238
+00:21:19,720 --> 00:21:24,240
+ما هو المختصر هنا؟ ذرتين هيدروجين، بتكونوا تفهموهم. يعني
+
+239
+00:21:24,240 --> 00:21:27,600
+لما نقول اقرأوا ايش فيه هنا؟ بتقولوا هذه عبارة عن
+
+240
+00:21:27,600 --> 00:21:33,180
+CH2، مختصر من hydrogen و hydrogen، الكتابة. هذه من بين
+
+241
+00:21:33,180 --> 00:21:37,380
+أربع روابط، هذه من بين أربعة، هذه carbon، رابطتين
+
+242
+00:21:37,380 --> 00:21:41,480
+ورابطتين مع الـoxygen. سليمة. الـoxygen كم رابطة
+
+243
+00:21:41,480 --> 00:21:48,000
+تعمل؟ رابطتين. الـoxygen هنا بطريقة ثانية، رابطتين، بمعنى أن
+
+244
+00:21:48,000 --> 00:21:51,600
+ممكن يكونوا رابطة ثنائية في النهاية، رابطتين، أو
+
+245
+00:21:51,600 --> 00:21:56,540
+رابطتين أحاديتين، ما فيش مشكلة. كذلك مع الـcarbon، ممكن
+
+246
+00:21:56,540 --> 00:22:01,580
+يكونوا أربع روابط أحادية، ممكن يكون رابطة ثنائية و
+
+247
+00:22:01,580 --> 00:22:07,200
+رابطتين أحاديتين، ممكن ثلاث روابط، يعني رابطة ثلاثية و
+
+248
+00:22:07,200 --> 00:22:10,360
+رابطة أحادية، المهم المجموع يكون في النهاية ايش؟
+
+249
+00:22:10,360 --> 00:22:13,900
+أربعة. المهم المجموع يكون في النهاية أربعة. لاحظوا
+
+250
+00:22:13,900 --> 00:22:19,500
+الـhalogen هنا، رابطة واحدة، بيكون أكيد عليه أزواج
+
+251
+00:22:19,500 --> 00:22:23,580
+إلكترونات. لو كنا محتاجينها لفهم تفاعل بنكتبها، مش
+
+252
+00:22:23,580 --> 00:22:28,240
+محتاجينها عادة ما نكتبهاش. يعني لو كنت بدي أكمل أزواج
+
+253
+00:22:28,240 --> 00:22:33,000
+الإلكترونات هنا، أكيد الـoxygen عليه زوجين، أكيد الـ
+
+254
+00:22:33,000 --> 00:22:36,100
+nitrogen عليه زوج، أكيد الـhalogen عليه ثلاثة.
+
+255
+00:22:36,100 --> 00:22:42,740
+بالمناسبة، بالنسبة لموضوع الروابط، رسم الأشكال زي ما
+
+256
+00:22:42,740 --> 00:22:47,440
+هتلاحظوا ربما بعد two or three slides، أننا
+
+257
+00:22:47,440 --> 00:22:54,900
+بنرسم الأشكال بأكثر من طريقة، بمعنى ممكن نحن نرسم
+
+258
+00:22:54,900 --> 00:23:01,620
+شكل مركب بتفصيل كامل، يعني نبين فيه كل ذرة من
+
+259
+00:23:01,620 --> 00:23:05,500
+الذرات، ممكن نبين في المركبات كل ذرة من الذرات زي ما
+
+260
+00:23:05,500 --> 00:23:14,600
+نحن رسمنا هنا. CH3 CH2 CH2 OH، هذا قواعد الروابط
+
+261
+00:23:14,600 --> 00:23:18,740
+كلها بتنطبق عليه، سليم. الآن، لو هذا كنت بدي أكتبه
+
+262
+00:23:18,740 --> 00:23:26,880
+بطريقة الكتابة العادية، حاكتبه CH3 CH2 CH2 OH. لو بدي
+
+263
+00:23:26,880 --> 00:23:32,540
+أختصره باستعمال برامج الرسم، هارسمه بهذا الشكل: واحد،
+
+264
+00:23:32,540 --> 00:23:36,860
+اثنين، ثلاثة. الآن، هؤلاء ايش يُفهموا؟ كل رأس يُفهم
+
+265
+00:23:37,630 --> 00:23:44,750
+carbon. كل رأس يُفهم carbon. فأنا لو شفت هذا المركب و
+
+266
+00:23:44,750 --> 00:23:51,110
+قلت لطالبة: اقرأي هذا الشكل، المفروض هي تقرأه CH3 CH2
+
+267
+00:23:51,110 --> 00:23:58,260
+CH2 OH. أو مثلاً لو شفت مركب زي هذا، كل رأس carbon.
+
+268
+00:23:58,260 --> 00:24:03,060
+يعني كم carbon عندي في هذا المركب؟ خمس ذرات carbon.
+
+269
+00:24:03,060 --> 00:24:09,500
+فيقرأ CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+270
+00:24:09,500 --> 00:24:09,800
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+271
+00:24:09,800 --> 00:24:10,480
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+272
+00:24:10,480 --> 00:24:10,520
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+273
+00:24:10,520 --> 00:24:14,220
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+274
+00:24:14,220 --> 00:24:14,280
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+275
+00:24:14,280 --> 00:24:15,020
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+276
+00:24:15,020 --> 00:24:21,380
+CH2 CH2 CH2. بدنا نكون متعودين على معرفة الصيغة
+
+277
+00:24:21,380 --> 00:24:27,240
+الجزئية للمركبات، وحسابها، والروابط المختصرة، على
+
+278
+00:24:27,240 --> 00:24:33,120
+طول ما نحن في مخنا ايش نعمل؟ نجيبها ونحطها. خليني
+
+279
+00:24:33,120 --> 00:24:40,450
+أعطيكم، خليني أعطيكم مثال إضافي، أعطيكم مثال إضافي.
+
+280
+00:24:40,450 --> 00:24:49,190
+يعني لو على السريع جربنا مثلاً أن نرسم جزيء زي هيك
+
+281
+00:24:49,190 --> 00:25:02,150
+وهذا الجزيء عملنا فيه، ناخد
+
+282
+00:25:02,150 --> 00:25:03,990
+ثانية في الرسم، مش مشكلة.
+
+283
+00:25:25,060 --> 00:25:30,720
+الآن يا جماعة، هي عندكم جزيء، وخلينا نكبره عشان
+
+284
+00:25:30,720 --> 00:25:36,720
+أنتم كلكم تشوفوه. لو سألنا: هذا الجزيء الموجود
+
+285
+00:25:36,720 --> 00:25:41,380
+قدامكم، ايش صيغته الجزئية؟ ايش المبين؟ ايش
+
+286
+00:25:41,380 --> 00:25:46,250
+المختصر فيه؟ واحدة تقول لنا ايش صيغته الجزئية،
+
+287
+00:25:46,250 --> 00:25:54,630
+يعني كم carbon يوجد عندي في هذا الجزء؟ carbon؟
+
+288
+00:25:54,630 --> 00:25:57,270
+كل رأس بالنسبة له carbon؟
+
+289
+00:26:00,180 --> 00:26:05,660
+هذا اللي هنا Carbon، إذاً هذه صيغته الجزئية C5،
+
+290
+00:26:05,660 --> 00:26:12,800
+الآن الأصعب شوية: كم هيدروجين عندي في هذا الجزء؟
+
+291
+00:26:16,380 --> 00:26:21,680
+كل شيء بتكون تكمله حسب ما اتفقنا: الكربون لأربع
+
+292
+00:26:21,680 --> 00:26:28,320
+روابط، النيتروجين لثلاثة، الأكسجين لرابطتين. كل ما هو
+
+293
+00:26:28,320 --> 00:26:36,020
+ناقص عبارة عن هيدروجين، يعني هنا موجود عندي
+
+294
+00:26:36,020 --> 00:26:43,670
+هيدروجين، هنا هيدروجين، هنا هيدروجين، اثنين
+
+295
+00:26:43,670 --> 00:26:47,530
+هيدروجين هنا، عشان يصير الكربون أربعة. هذه
+
+296
+00:26:47,530 --> 00:26:52,010
+النيتروجين كم رابطة عليها؟ اثنين، اثنين، اذا
+
+297
+00:26:52,010 --> 00:27:04,070
+ينقصها عشان تصير ثلاث روابط. هذه الكربون، عدوهم:
+
+298
+00:27:04,070 --> 00:27:10,460
+واحد، اثنين. أنا أكيد بقول للناس اللي بيقولوا رقم
+
+299
+00:27:10,460 --> 00:27:15,700
+مفرد، هم الكلام الصح، وقدوا أنتم: أربعة، ستة، ثمانية،
+
+300
+00:27:15,700 --> 00:27:26,900
+عشرة، أحد عشر، إذاً أحد عشر، واضح؟ هي عدد الروابط، وبالمناسبة،
+
+301
+00:27:26,900 --> 00:27:30,920
+برنامج الرسم بإمكانه يحسب أن الصيغة تبع هذا
+
+302
+00:27:30,920 --> 00:27:34,780
+المركب، يعني لو علمناه: chemist, calculate molecular
+
+303
+00:27:34,780 --> 00:27:39,460
+values، وcalculate، وقلنا له: حُسب لنا إياهم، هاي
+
+304
+00:27:39,460 --> 00:27:46,920
+الصيغة، ايش حسب البرنامج؟ اقرأوا: C5H11NO.
+
+305
+00:27:46,920 --> 00:27:52,010
+زي ما نحن كتبناها ولا لأ؟ زي ما نحن كتبناها، واضح؟
+
+306
+00:27:52,010 --> 00:27:57,110
+فعندكم أنتم برنامج الرسم موجود، بإمكانكم ترسموا
+
+307
+00:27:57,110 --> 00:28:02,770
+جزيئات زي ما بدكم، بإمكانكم ترسموا جزيئات زي ما
+
+308
+00:28:02,770 --> 00:28:08,110
+بدكم، والبرنامج بحسبها، وبالتالي بتقدروا تراجعوا
+
+309
+00:28:08,110 --> 00:28:12,110
+لنفسكم، يعني حتى لو اجت طالبة قالت: أنا بدي، بدل ما
+
+310
+00:28:12,110 --> 00:28:16,690
+هذه هيدروجين تكون زي هيك، الآن هذه ايش تصبح؟ carbon.
+
+311
+00:28:20,260 --> 00:28:25,990
+هذا الآن تصبح carbon، كل رأس اسمه carbon. هذه من
+
+312
+00:28:25,990 --> 00:28:29,530
+الأخطاء الشائعة جداً، نراجعها، نتبه لها، أننا لما
+
+313
+00:28:29,530 --> 00:28:32,550
+بنحط رأس زي هيك، زي هذا، أو زي هذا، بتيجي الطالبة
+
+314
+00:28:32,550 --> 00:28:36,630
+بتكتب عليه hydrogen، لأ، هذا الرأس يُفهم على أنه
+
+315
+00:28:36,630 --> 00:28:41,370
+carbon مش hydrogen، وبالمناسبة، لو بدكم تغلطوا،
+
+316
+00:28:41,370 --> 00:28:46,570
+برامج الرسم عادة شاطرة وبتفهمكم، يعني لو اجيتم
+
+317
+00:28:46,570 --> 00:28:49,470
+تحطوا هنا على الـoxygen رابطة ثالثة، يعني هذه
+
+318
+00:28:49,470 --> 00:28:54,070
+الرابطة، نعملها عصا ونحط كمان رابطة، لاحظوا ايش كتب لكم
+
+319
+00:28:54,070 --> 00:28:59,650
+جملة؟ Valence exceeded on atoms، زاد الارتباط على
+
+320
+00:28:59,650 --> 00:29:04,390
+الذرات، ليش؟ لأنه أنا قاعد أبدأ أحط رابطتين هنا و
+
+321
+00:29:04,390 --> 00:29:09,690
+رابطة، قد ايش المجموع بيصير على الـoxygen؟ ثلاثة.
+
+322
+00:29:10,240 --> 00:29:15,300
+بالفعل، ولذلك أعطاني إشارة تنبيه أن عدد الارتباط
+
+323
+00:29:15,300 --> 00:29:19,960
+زاد. فأنتوا في البيت، اتعودوا أن عندكم برامج رسم
+
+324
+00:29:19,960 --> 00:29:24,480
+معينة، أو هذا البرنامج أيضاً موجود عندكم، بترسموا فيه،
+
+325
+00:29:24,480 --> 00:29:28,700
+بتتدربوا، كل ما رسمتم أكثر، تعبتوا أكثر، تتدربوا
+
+326
+00:29:28,700 --> 00:29:33,600
+أكثر على أنكم تفهموا الأشكال بالشكل السليم، وهذه
+
+327
+00:29:33,600 --> 00:29:38,460
+مشكلة لمن لا يتدرب ويتعب من البداية، يتغلب
+
+328
+00:29:38,460 --> 00:29:41,020
+أثناء دراسته للمادة.
+
+329
+00:29:50,540 --> 00:29:55,560
+هذا بالنسبة للأشكال وكيف نرسمها بأكثر من طريقة، ونحن
+
+330
+00:29:55,560 --> 00:30:00,800
+نحن دائماً في الكيمياء نفضل أي طرق؟ الطريقة
+
+331
+00:30:00,800 --> 00:30:08,170
+المختصرة، وأنتم بتكملوا الحساب في اللي ينكم. الآن
+
+332
+00:30:08,170 --> 00:30:14,050
+بيجينا أيضاً من المراجعات شيء متعلق في قطبية
+
+333
+00:30:14,050 --> 00:30:19,890
+الروابط، متى تكون الرابطة قطبية، ومتى يكون الجزيء
+
+334
+00:30:19,890 --> 00:30:25,870
+قطبياً؟ الرابطة بتكون قطبية، يعني لها قطب موجب وقطب
+
+335
+00:30:25,870 --> 00:30:31,210
+سالب، إذا اختلفت السالبية الـelectronegativity بين
+
+336
+00:30:31,210 --> 00:30:36,450
+الذرتين،  اللتين تكونان الرابطة. طبعاً الذرة الأكثر سالبية تصبح
+
+337
+00:30:36,450 --> 00:30:42,290
+كأنها طرف سالب، والأقل سالبية تصبح كأنها طرف موجب.
+
+338
+00:30:42,290 --> 00:30:48,770
+ونعبر عن هذا الكلام بوضع إشارة الشحنة الجزئية،
+
+339
+00:30:48,770 --> 00:30:52,930
+الجزئية، partial positive أو partial negative، في
+
+340
+00:30:52,930 --> 00:30:57,110
+عندنا نحن جدول للسالبية، أعلى السالبية اللي هي
+
+341
+00:30:57,110 --> 00:31:02,290
+سالبيّة الفلور، أربعة. فمثلاً لو كان عندكم رابطة
+
+342
+00:31:02,290 --> 00:31:08,530
+بين الكربون والفلور بهذا الشكل: هي كربون، فلور.
+
+343
+00:31:09,820 --> 00:31:14,040
+مين اللي سالبيته أعلى؟ الـFluorine، الـFluorine. إذا أي
+
+344
+00:31:14,040 --> 00:31:17,760
+طرف هيكون سالب؟ الـFluorine. أي طرف هيكون موجب؟
+
+345
+00:31:17,760 --> 00:31:23,060
+الـCarbon. وقتها بنحط إشارة القطبية إما بهذا الشكل،
+
+346
+00:31:23,060 --> 00:31:28,140
+يفهم أن هذا هو الطرف السالب، وهذا هو الطرف الموجب،
+
+347
+00:31:28,140 --> 00:31:33,820
+أو بنحطها بإشارة أن الـFluorine بنقول عنه partially
+
+348
+00:31:33,820 --> 00:31:40,020
+negative، والـCarbon partially positive. هذا بالنسبة
+
+349
+00:31:40,020 --> 00:31:43,820
+لقطبية الروابط، the polarity of bonds, it depends on
+
+350
+00:31:43,820 --> 00:31:46,820
+the electronegativity difference of the atoms
+
+351
+00:31:46,820 --> 00:31:52,560
+forming this bond. بيعتمد على فرق السالبية. لكن لو
+
+352
+00:31:52,560 --> 00:32:00,860
+مثلاً قلنا جزيء مثل البروم، يا ترى هذا الجزيء... هذا
+
+353
+00:32:00,860 --> 00:32:05,900
+الرابط، عفواً، بين البروم والبروم بتكون قطبية؟ ليش؟
+
+354
+00:32:05,900 --> 00:32:09,780
+لأنّ سالبيته زي سالبيته، فما بيكون فيه قطبية
+
+355
+00:32:09,780 --> 00:32:17,650
+بين ذرتين مثل بعضهم تماماً. وهاي أمثلة كثيرة،
+
+356
+00:32:17,650 --> 00:32:22,010
+بين الهيدروجين والكلور قطبية، تُعبر عنها بهذا الشكل،
+
+357
+00:32:22,010 --> 00:32:25,250
+أو بهذا، أو بهذا. الـcarbon والـnitrogen، الـcarbon
+
+358
+00:32:25,250 --> 00:32:29,370
+والـoxygen، كل هذه أمثلة بإمكانكم ترجعوا لها. واضح أن
+
+359
+00:32:29,370 --> 00:32:34,630
+الذرتين المكونتين للرابطة مختلفتان، واحدة سالبيتها أكثر،
+
+360
+00:32:34,630 --> 00:32:38,490
+حتكون هي الطرف السالب، والثانية أقل، حتكون هي الطرف
+
+361
+00:32:38,490 --> 00:32:44,270
+الموجب. هذا الكلام بينقلنا لقطبية الجزيء، الجزيء
+
+362
+00:32:44,270 --> 00:32:49,310
+يتكون من عدة روابط، هل الجزيء بمجمله يكون قطبي ولا
+
+363
+00:32:49,310 --> 00:32:55,030
+لأ؟ هذا الكلام بيعتمد على أن نجد المحصلة لهذه
+
+364
+00:32:55,030 --> 00:33:01,210
+الروابط. طبعاً أي إنسان بده يجد محصلة، لازم يفهم
+
+365
+00:33:01,210 --> 00:33:05,950
+الشكل. يعني لو أنا قلت لكم هذه الطاولة بيؤثر عليها
+
+366
+00:33:05,950 --> 00:33:12,210
+قوتان، ما المحصلة؟ حتقولوا لي مباشرة: أحكيلنا كيف شكل
+
+367
+00:33:12,210 --> 00:33:15,610
+القوتين. والله إذا القوتان كانتا من هذه الجهة
+
+368
+00:33:15,610 --> 00:33:20,690
+بيضغطوا، الطاولة حتتحرك، حتنجمع القوة الأولى مع
+
+369
+00:33:20,690 --> 00:33:24,150
+القوة الثانية. لو القوتان واحدة بهذا الشكل، واحدة
+
+370
+00:33:24,150 --> 00:33:29,930
+من اتجاه معاكس، حيُسْطِبا بعض. إذاً لكي أعرف المحصلة،
+
+371
+00:33:29,930 --> 00:33:34,130
+لابد إلا أن أعرف الشكل الهندسي. والأصل أن هذا موضوع
+
+372
+00:33:34,130 --> 00:33:38,530
+بتتعلموه في الكيمياء العامة، مش مجالنا الآن أننا
+
+373
+00:33:38,530 --> 00:33:42,350
+ناخد الـgeometrical structures. لكن خليني آخذ عدة
+
+374
+00:33:42,350 --> 00:33:46,990
+أمثلة. مثلاً درسنا نحن أن الشكل الهندسي لثاني أكسيد
+
+375
+00:33:46,990 --> 00:33:51,810
+الكربون خطي. الآن الأكسجين عنده قطبية أكثر من
+
+376
+00:33:51,810 --> 00:33:56,260
+الكربون. بناءً على ذلك، لو بدأنا نحكي عن carbon oxygen
+
+377
+00:33:56,260 --> 00:34:01,840
+bond، لها قطبية بهذا الشكل، وهذه كمان قطبية بهذا
+
+378
+00:34:01,840 --> 00:34:05,800
+الشكل. ايش بتعملوا في القطبيتين؟ بيشطبوا بعض، فالجزيء
+
+379
+00:34:05,800 --> 00:34:09,860
+صار non-polar، الـcarbon dioxide، يصبح non-polar.
+
+380
+00:34:09,860 --> 00:34:14,460
+بينما لو اجيت للمياه، المياه الشكل تبعها ايش ماله؟ V-
+
+381
+00:34:14,460 --> 00:34:19,120
+shaped، أو bent، منثني. الآن فيه انحراف قطبية
+
+382
+00:34:19,120 --> 00:34:23,900
+بهذا الشكل، وبهذا الشكل. هذول قوتين جايين بزاوية.
+
+383
+00:34:23,900 --> 00:34:31,010
+المحصلة تبعتهم وين بتكون؟ بينهم، زي هيك، حيصير محصلة
+
+384
+00:34:31,010 --> 00:34:39,000
+الجزيء. فجزيء الماء يصبح جزيء قطبي، واضح؟ لو أخذنا
+
+385
+00:34:39,000 --> 00:34:43,200
+جزيء الميثان، اللي مكون من أربع روابط، وهناخذ تفصيل
+
+386
+00:34:43,200 --> 00:34:47,420
+الشكل تبعه، اللي هو tetrahedral structure، بإمكاننا
+
+38
+
+445
+00:39:50,760 --> 00:39:55,840
+different bonding, different names. طالما الارتباط
+
+446
+00:39:55,840 --> 00:40:01,060
+اختلف، إذًا كمان الأسماء هتصير إيش؟ مختلفة. فَأول ما
+
+447
+00:40:01,060 --> 00:40:05,800
+بنقول احنا structural isomers، بدنا نتذكر أن هدول
+
+448
+00:40:05,800 --> 00:40:11,850
+فيهم ارتباط مختلف ولهم أسماء مختلفة. النوع الثاني من
+
+449
+00:40:11,850 --> 00:40:17,450
+الـ isomers نوع أصعب شوية، ولذلك بندرسه احنا بـ
+
+450
+00:40:17,450 --> 00:40:21,730
+chapter منفصل، اللي هو الفصل الخامس من المادة هذه.
+
+451
+00:40:21,730 --> 00:40:27,130
+بنسميه stereo isomers. الـ stereo isomers، الذرات
+
+452
+00:40:27,130 --> 00:40:31,790
+بتكون لها نفس الارتباط. يعني هنا أنا قُلت same
+
+453
+00:40:31,790 --> 00:40:35,270
+different bonding. في الـ stereo isomers على طول
+
+454
+00:40:35,270 --> 00:40:40,850
+بقول same constitution أو same bonding، نفس الارتباط.
+
+455
+00:40:40,850 --> 00:40:46,410
+طب نفس الارتباط، فَهُوَين بيختلفوا؟ بالشكل، بالفراغ، ممكن
+
+456
+00:40:46,410 --> 00:40:51,410
+أشياء يكون لها نفس الارتباط وتختلف بالشكل، بالفراغ.
+
+457
+00:40:51,410 --> 00:40:55,690
+الجواب أهو، بدي أعطيكم مثال من برا الكيمياء، لما
+
+458
+00:40:55,690 --> 00:41:00,430
+الطلاب في المدرسة بيقفوا بـطابور الصبح. هي إيد وجسمه
+
+459
+00:41:00,430 --> 00:41:06,270
+إيد. هذا الارتباط إيش هو؟ إيد وجسم وإيد. طب لو عملوا
+
+460
+00:41:06,270 --> 00:41:12,350
+هيك، هذا الشكل، لو عملوا هيك، هذا الشكل، الآن هل
+
+461
+00:41:12,350 --> 00:41:16,630
+تغير شيء في الارتباط؟ إيد وجسم إيد.
+
+462
+00:41:19,410 --> 00:41:22,950
+لو عملوا هيك، طب هدول الأشكال التلاتة، لو أخدت
+
+463
+00:41:22,950 --> 00:41:27,910
+ثلاث صور وحطيتهم قدام الطالب وسألته: ما العلاقة
+
+464
+00:41:27,910 --> 00:41:31,990
+بين هدول الثلاث صور؟ هيقول لي: الـ same bonding،
+
+465
+00:41:31,990 --> 00:41:36,150
+ما انفكتش ولا إيد من إيدين البني آدم، نفس الارتباط،
+
+466
+00:41:36,150 --> 00:41:40,720
+طب أين الاختلاف؟ بالشكل الفراغي. إذًا اللي بيميز الـ
+
+467
+00:41:40,720 --> 00:41:45,060
+stereo isomers: الـ atoms have the same bonding, the
+
+468
+00:41:45,060 --> 00:41:48,400
+same constitution, but different arrangement in
+
+469
+00:41:48,400 --> 00:41:52,320
+space. لكن شكلهم بالفراغ بيختلف. طبعًا هنتوسع فيهم
+
+470
+00:41:52,320 --> 00:41:56,220
+ونلاحظ أنه في منهم نوع اسمه انانشيومرز، ونوع اسمه
+
+471
+00:41:56,220 --> 00:42:01,340
+ستيريو آيزومرز. كل هذا التوسع بيكون بفصل كامل، اللي هو
+
+472
+00:42:01,340 --> 00:42:07,570
+الفصل الخامس. أُبهيك أنهي اليوم وإلى لقاء آخر إن
+
+473
+00:42:07,570 --> 00:42:07,950
+شاء الله.
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/pdzlULxzAp0_postprocess.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/pdzlULxzAp0_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..66f7c165203597f427c94457ea613da8b2ab0469
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/pdzlULxzAp0_postprocess.srt
@@ -0,0 +1,2200 @@
+1
+00:00:20,770 --> 00:00:26,070
+بسم الله الرحمن الرحيم المرة الماضية بدأنا معكم في
+
+2
+00:00:26,070 --> 00:00:30,810
+الفصل الثاني بونوان ال alkanes and cycloalkanes
+
+3
+00:00:30,810 --> 00:00:37,130
+ربما حكينا فكرة في البداية عن تصنيفات ال alkanes
+
+4
+00:00:37,130 --> 00:00:41,350
+أو ال hydrocarbons ل saturated alkanes بقولنا
+
+5
+00:00:41,350 --> 00:00:46,350
+هدولة نوعين اللي همالالكينز والسايكلوالكينز و
+
+6
+00:00:46,350 --> 00:00:50,110
+unsaturated hydrocarbons اللي منها المراكبات اللي
+
+7
+00:00:50,110 --> 00:00:52,470
+فيها double bond و triple bond في الالكينز
+
+8
+00:00:52,470 --> 00:00:59,290
+والالكاينز بدنا نتعرف على الالكينز وقلنا هذه سلاسل
+
+9
+00:00:59,290 --> 00:01:05,200
+وممكن أن تكون مراكباتمتفرعة وهذا يؤدي الى تكون عدد
+
+10
+00:01:05,200 --> 00:01:11,340
+كبير جدا من ال isomers او المتشكلات ال isomers زى
+
+11
+00:01:11,340 --> 00:01:16,780
+ما اتفقنا فى ال alkanes بتبدأ تظهر وقتاش لما بنصل
+
+12
+00:01:16,780 --> 00:01:20,080
+لاربع ذرات كربون يعنى لو عندنا ذرة كربون واحدة
+
+13
+00:01:20,080 --> 00:01:24,480
+عندنا مركب واحد فقط ميثين بعدين ايثين بروبين هذا
+
+14
+00:01:24,480 --> 00:01:28,900
+منه مركب واحد لكن لما ابدي اجى احط اربع ذرات كربون
+
+15
+00:01:28,900 --> 00:01:34,130
+ارتبهمصار في عنده احتمالين لترتيبهم اما ان يرتبوا
+
+16
+00:01:34,130 --> 00:01:39,850
+بشكل متسلسل chain structure و بيكون اسم المركب
+
+17
+00:01:39,850 --> 00:01:45,210
+بيوتين او بشكل branch و بيكون اسم المركب ايزو
+
+18
+00:01:45,210 --> 00:01:48,770
+بيوتين و اتكلمنا بعد هيك عن البنتين انه بيكون
+
+19
+00:01:48,770 --> 00:01:53,930
+تلاتة isomers و بعد ذلك اعطيناكم واجب انكوا تجربوا
+
+20
+00:01:53,930 --> 00:02:00,170
+انتوا تتعبوا و ترسموا الخمسةstructures of hexane
+
+21
+00:02:00,170 --> 00:02:06,010
+والمفروض يكون الأمر بالنسبة لكم مش صعب كثير انه
+
+22
+00:02:06,010 --> 00:02:10,830
+تجيبوا 6 ذرات كربون تجربوا ما لم تعملوا هذا الأمر
+
+23
+00:02:10,830 --> 00:02:14,230
+بالإيد و بالجلم لرصاص و بالورق و تتعبوا فيه كثير
+
+24
+00:02:14,230 --> 00:02:20,770
+مابفيدش ان انا اعمله بكل الأحوال هذه وجفنا
+
+25
+00:02:20,770 --> 00:02:26,630
+اخر شي عند ال structure ofميثين وقولنا ان الميثين
+
+26
+00:02:26,630 --> 00:02:32,290
+ماخد الـ tetrahedral structure اللي له أربعة أوجه
+
+27
+00:02:32,290 --> 00:02:38,390
+وهذا أفضل شئ نتعامل معه نرسمه بسهولة اننا نعمله
+
+28
+00:02:38,390 --> 00:02:41,810
+بالشكل اللي موجود بين اديكم تخيل انه عندنا مستويين
+
+29
+00:02:41,960 --> 00:02:48,200
+مستوى أفقي للأمام ومستوى متعامد عليه للخلف هذا
+
+30
+00:02:48,200 --> 00:02:51,960
+المستوى الأفقي للأمام بيكون فيه ذارتين هيدروجين في
+
+31
+00:02:51,960 --> 00:02:56,880
+زاوية 109.5 والمستوى الخلفي أيضا في ذارتين
+
+32
+00:02:56,880 --> 00:03:02,320
+هيدروجينبزاوية 109.5، الآن باقي الزاوية أيضًا 109
+
+33
+00:03:02,320 --> 00:03:05,940
+.5، يعني لو واحد .. لو واحدة بدأ تاخد بين هذه
+
+34
+00:03:05,940 --> 00:03:08,260
+الهيدروجين اللي في المستوى الأمامي و اللي في
+
+35
+00:03:08,260 --> 00:03:14,100
+المستوى الخلفي و انقيس الزاوية 109.5اللي اتوقفنا
+
+36
+00:03:14,100 --> 00:03:19,020
+عنده كيف يرسم هذا الشكل بالفراغ كيف يرسم هذا الشكل
+
+37
+00:03:19,020 --> 00:03:23,860
+بالفراغ قولنا أفضل شيء أنه نرسمه بهذه الطريقة
+
+38
+00:03:23,860 --> 00:03:29,920
+نستعمل ال wedges أو الأسافير بحيث أنه الأشياء اللي
+
+39
+00:03:29,920 --> 00:03:34,400
+للأمام عادة بنعملها ب solid wedge و الأشياء اللي
+
+40
+00:03:34,400 --> 00:03:39,360
+للخلف عادة بنعملها ب dashed wedgeواضح؟ وهذا اللي
+
+41
+00:03:39,360 --> 00:03:43,860
+موجود عندنا الان اذا احنا بندقيق شوية في هذا الشكل
+
+42
+00:03:43,860 --> 00:03:49,360
+هنلاحظ ان الوجه له رأس head و له base قاعدة
+
+43
+00:03:49,360 --> 00:03:56,250
+القاعدة اللي هي عريضة زي هذه و الرأساللي بيكون
+
+44
+00:03:56,250 --> 00:04:02,030
+رفيع هل يا ترى هناك معنى لما انا اجي ارسم مثلا هذا
+
+45
+00:04:02,030 --> 00:04:07,370
+solid wedge تكون القاعدة فيه على جهة الهيدروجين و
+
+46
+00:04:07,370 --> 00:04:11,650
+الرأس على جهة الكاربون لما اجي ارسم ورا ال dashed
+
+47
+00:04:11,650 --> 00:04:16,690
+wedge تكون القاعدة على جهة الكاربون و الرأس على
+
+48
+00:04:16,690 --> 00:04:22,210
+جهة الهيدروجين هذا الكلام بالتأكيد له معنى شو
+
+49
+00:04:22,210 --> 00:04:27,730
+معنى؟ هذا تعبير عنالرسم في الفراغ دائما احنا
+
+50
+00:04:27,730 --> 00:04:32,070
+متعودين .. دائما احنا متعودين ان الشغلة اللى بتكون
+
+51
+00:04:32,070 --> 00:04:37,590
+قريبة علينا كبيرة بتبين كل ما بعدت عننا بتبين ايش
+
+52
+00:04:37,590 --> 00:04:41,150
+صغيرة يعني الناس اللى بيشوفوا الطائرة في المطار
+
+53
+00:04:41,150 --> 00:04:46,710
+طيارة كبيرة بتاخد خمسمية راكب واضح؟ لما بتبعد كتير
+
+54
+00:04:46,710 --> 00:04:53,610
+في السماء بتشوفوا الطائرة نقطة فكل شيء قريب علينا
+
+55
+00:04:54,670 --> 00:05:00,010
+كبير كلما بقعد صغر حتى لو انتوا بترسموا شارع مثلا
+
+56
+00:05:00,010 --> 00:05:02,950
+متعودين انكوا تقولوا هاي الإنسان هنا اللي بترسم
+
+57
+00:05:02,950 --> 00:05:09,970
+الشارع يبدأ الشارع عريض و كل ما بيبعد بيصير إيش؟
+
+58
+00:05:10,790 --> 00:05:16,210
+يصغر الان هذه الأشياء أيضا تعبير عن هذا الأمر يعني
+
+59
+00:05:16,210 --> 00:05:20,590
+لو انا امسكت هذا الشكل زي هيك هاي اللي موجودين في
+
+60
+00:05:20,590 --> 00:05:25,670
+المستوى الأفقي الان ايش القريب عليكم ذرات
+
+61
+00:05:25,670 --> 00:05:31,710
+الهيدروجين و كل ما بتروحوا على الكاربون بتبتعدوا
+
+62
+00:05:32,390 --> 00:05:38,870
+واضح و لذلك الوجه لما رسمناه خلناه عريض من عند
+
+63
+00:05:38,870 --> 00:05:43,430
+الهيدروجين و كل ما راح الكربون بيبعد بيصير ماخد
+
+64
+00:05:43,430 --> 00:05:49,690
+ايش؟ رأس المثلث فلاحظوا قريب و بيبعد عشان هيك
+
+65
+00:05:49,690 --> 00:05:55,830
+رسمناه عريض و بيصغر لو اجيت على الهيدروجين اللي في
+
+66
+00:05:55,830 --> 00:06:01,480
+الخلفأيش القريب عليكم اكثر ال carbon ولا ال
+
+67
+00:06:01,480 --> 00:06:05,580
+hydrogen؟ ال carbon و كل ما بتروحوا باتجاه ال
+
+68
+00:06:05,580 --> 00:06:12,000
+hydrogen بتبعدوا و لذلك هذا قريب بيبتعد، اذا ال
+
+69
+00:06:12,000 --> 00:06:18,780
+wedge تبعه سيبدأ كبيرامن عند الكربون و يصغر فلو
+
+70
+00:06:18,780 --> 00:06:23,900
+رسمت هذا بشكل معاكس بتكونوا بتعملوا غلط وهذا بيصير
+
+71
+00:06:23,900 --> 00:06:28,120
+جزء لما بترسموا أشكال دائما الشيء القريب عليكم
+
+72
+00:06:28,120 --> 00:06:32,280
+اعملوا الوجه تبعه قاعدته باتجاهكم و كل ما بيبعد
+
+73
+00:06:32,280 --> 00:06:39,000
+بيصغر واضح هذه الفكرة فهذا أمر يجب ان ينتبه له شكل
+
+74
+00:06:39,000 --> 00:06:44,200
+الوجه اللي للأمام و اللي للخلف الان ابتيجي نقطة
+
+75
+00:06:44,200 --> 00:06:50,590
+كثير مهمةلما احنا اضطرنا اضطرارا نرسم الشكل بهذه
+
+76
+00:06:50,590 --> 00:06:55,830
+الطريقة ليش؟ لأنه في اللوح مافيش إمكانية لشيء
+
+77
+00:06:55,830 --> 00:07:00,490
+الفراغي يعني مافيش عندي إمكانية أطلع هدول للأمام و
+
+78
+00:07:00,490 --> 00:07:06,090
+أرجع هدول للخلف فهذه الرسمة غير حقيقية الآن لما
+
+79
+00:07:06,090 --> 00:07:10,310
+باجي بقولكوا بدي أقيس الزوايا مابتكونش تقيسوا
+
+80
+00:07:10,310 --> 00:07:15,560
+الزوايا على أساس الشكلاللي مبين عندكم تقيسوها على
+
+81
+00:07:15,560 --> 00:07:20,120
+أساس الشكل الفراغي اللي موجود في ذهنكم ولذلك لما
+
+82
+00:07:20,120 --> 00:07:25,420
+أقول الزاوية بين الهيدروجين والكاربون والهيدروجين
+
+83
+00:07:25,420 --> 00:07:36,470
+على الرسمة مبينة 180180 لكن هي حقيقة جديش 109.5
+
+84
+00:07:36,470 --> 00:07:40,990
+كذلك الحال لو جيت قلتلكوا بدي الزاوية بين
+
+85
+00:07:40,990 --> 00:07:46,430
+الهيدروجين والكاربون والهيدروجين الآن على الرسمة
+
+86
+00:07:47,810 --> 00:07:54,230
+الزاوية كانت 180 لكنها حقيقة 109.5 فلو كنت معلم
+
+87
+00:07:54,230 --> 00:07:59,870
+بالأزرق و قلت له اكتبوا الزاوية ستكتبوها 109.5 مش
+
+88
+00:07:59,870 --> 00:08:06,040
+180 مابناش نخلط هذه الغلطةلو تخيلنا القاعدة ايضا
+
+89
+00:08:06,040 --> 00:08:11,680
+لو انا اجيت قلتلكم بدي الزاوية بين هذه الهيدروجين
+
+90
+00:08:11,680 --> 00:08:15,440
+اللي في المستوى الأفقي وهذه الهيدروجين الخلفية
+
+91
+00:08:15,440 --> 00:08:22,980
+الان هدولة هنا انبينين تسعين لكن هم حقيقة مية
+
+92
+00:08:22,980 --> 00:08:28,000
+وتسعة و نص ايضا واضح؟
+
+93
+00:08:29,450 --> 00:08:35,470
+فيجب الانتباه لهذا الأمر أن هذا الشكل ليس في مستوى
+
+94
+00:08:35,470 --> 00:08:40,630
+واحد وانما شكل في الفراغ وعندما تحدد الزوايا تبعته
+
+95
+00:08:40,630 --> 00:08:44,790
+يجب أن تحدد من الذهن تبعكه اللي اتعلم ان جميع
+
+96
+00:08:44,790 --> 00:08:50,970
+زوايا الـ tetrahedral structure قيمتها 109.5 كل
+
+97
+00:08:50,970 --> 00:08:55,970
+ذرة بعيدة عن التانيةمن خلال الكربون بزاوية 109.5
+
+98
+00:08:55,970 --> 00:09:03,410
+لا في زاوية شكل الميثين 90 ولا في زاوية 180 جميع
+
+99
+00:09:03,410 --> 00:09:07,510
+زاوية هيدروجين كربون هيدروجين من أي جهة بتاخدوها
+
+100
+00:09:07,510 --> 00:09:15,430
+قيمتها 109.5 هذا
+
+101
+00:09:15,430 --> 00:09:22,950
+بالنسبة لشكل الميثينإذا رجعنا لهذه ال slide اللي
+
+102
+00:09:22,950 --> 00:09:26,150
+اتكلمنا فيها عن ال الكانز بالتفصيل المميل قلنا
+
+103
+00:09:26,150 --> 00:09:30,690
+عندنا ميثين إيثين بروبين لحد البيوتين صار في عندنا
+
+104
+00:09:30,690 --> 00:09:36,330
+كام مركب اتنين الآن هدول بنسميهم الكانز من ال
+
+105
+00:09:36,330 --> 00:09:41,350
+الكانز بنطلع شغلة بنقولها ال kilogram لو يا ترى
+
+106
+00:09:41,350 --> 00:09:45,730
+احنا في نيتنا أنه بدنا نعمل تفاعل لما بدنا نعمل
+
+107
+00:09:45,730 --> 00:09:51,350
+التفاعل أول شيء أول شيء بدنا نعملهإنه بدنا نشيل
+
+108
+00:09:51,350 --> 00:09:58,870
+ذرة هيدروجين مثلا عشان نحط مكانها ذرة كلور الآن
+
+109
+00:09:58,870 --> 00:10:02,990
+لما أنا بشيل هيدروجين من الألكان يعني بدل ما
+
+110
+00:10:02,990 --> 00:10:12,030
+الميثين مثلا CH4 شو بده يصير CH3 وفي مكان سترتبط
+
+111
+00:10:12,030 --> 00:10:15,670
+به الذرة الجديدة نفترض اللي هي ذرة الكلور ممكن
+
+112
+00:10:15,670 --> 00:10:21,400
+نتخيل أنه لونها أخضرالان الالكين ناقص الهيدروجين
+
+113
+00:10:21,400 --> 00:10:27,180
+بسميه الكل جروب دائما الالكين ناقص الهيدروجين الكل
+
+114
+00:10:27,180 --> 00:10:32,520
+جروب فمن الميثين بطول مجموعة بسميها ايش مثل يعني
+
+115
+00:10:32,520 --> 00:10:40,940
+بستبدل ال N ب Y L بدل مثل N بصير مثل جروب دائما كل
+
+116
+00:10:41,530 --> 00:10:46,570
+نهاية اسم او شغلة فيها ال YL فانا بحكي عن الكلجروب
+
+117
+00:10:46,570 --> 00:10:52,330
+يعني ال cane مخصوم منه ذرة هيدروجين واضح؟ الان
+
+118
+00:10:52,330 --> 00:10:57,450
+لاحظوا لو هذه الذرة اتيت اعمل مركب طبعا المثل
+
+119
+00:10:57,450 --> 00:11:02,730
+مجموعة لكن لا تكون مركب يعني انا لما اخص منها
+
+120
+00:11:02,730 --> 00:11:07,290
+هيدروجينمباشرة مكانها الهيدروجين شو هتيجي تحط
+
+121
+00:11:07,290 --> 00:11:12,550
+اكلور نفترض الان لو كونت هذا المركب و بدي اعطيه
+
+122
+00:11:12,550 --> 00:11:19,010
+اسم باجي بسأل هذه المجموعة شو اسمها مثل وفي عند
+
+123
+00:11:19,010 --> 00:11:24,910
+اكلور فبقول المركب مثل اكلورايدبصير في ال common
+
+124
+00:11:24,910 --> 00:11:29,510
+nomenclature يعني التسمية المشهورة انه انا لو هنا
+
+125
+00:11:29,510 --> 00:11:34,110
+شيلت hydrogen و افترض و حطيت chlorine ايش هاسم
+
+126
+00:11:34,110 --> 00:11:41,070
+المركب اللي عندى مثل chloride هذه التسميةبنقول
+
+127
+00:11:41,070 --> 00:11:44,890
+عنها احنا ايش common nomenclature، ايش يعني
+
+128
+00:11:44,890 --> 00:11:49,350
+common؟ تسمية مشهورة، مش تسمية حسب القواعد، هناخد
+
+129
+00:11:49,350 --> 00:11:52,890
+نوعين من التسمية، في تسمية بنسميها IUPAC
+
+130
+00:11:52,890 --> 00:11:56,820
+Nomenclatureالتسمية لحسب القواعد اللي بنتعلمها
+
+131
+00:11:56,820 --> 00:12:00,620
+الآن وفيكم ال nomenclature التسمية المشهورة الان
+
+132
+00:12:00,620 --> 00:12:05,620
+التسمية المشهورة في مثل هذه المراكبات كيف بتتم من
+
+133
+00:12:05,620 --> 00:12:11,140
+خلال ذكر اسم المجموعة و بعد هيك بذكر اسم الهالوجين
+
+134
+00:12:11,140 --> 00:12:15,480
+فمن ال مثل لما شيلت هيدروجين صارت مثل حطيت بدلها
+
+135
+00:12:15,480 --> 00:12:20,380
+كلوه بيصير المراكب مثل كلورايد لو حطيت بدلها بروم
+
+136
+00:12:21,110 --> 00:12:27,190
+مثل البروميد و هكذا واضح؟ الان بنفس المنطق لو اجيت
+
+137
+00:12:27,190 --> 00:12:32,770
+على الاثين كام هيدروجين في الاثين بالمجمل؟ ستة
+
+138
+00:12:32,770 --> 00:12:37,170
+لاحظوا الست ذرات هيدروجين اللي في الاثين كلهم زي
+
+139
+00:12:37,170 --> 00:12:40,990
+بعض متكافئات يعني لو شيلت اي واحدة منهم هعمل
+
+140
+00:12:40,990 --> 00:12:47,670
+مجموعة شو هسميها؟ اثل زي ما انا شيلت من الميثين من
+
+141
+00:12:47,670 --> 00:12:53,840
+الأربع المتكافئات هدولةهيدروجينة وسميت المجموعة
+
+142
+00:12:53,840 --> 00:12:58,860
+مثل بقدر انا من ال اثين ايضا اشيل هيدروجينة الست
+
+143
+00:12:58,860 --> 00:13:01,880
+هيدروجينات زي بعض اي واحدة بنشيلها بتعطينا نفس
+
+144
+00:13:01,880 --> 00:13:07,080
+المجموعة هنكون مجموعة اثل لو افترضنا هذه المجموعة
+
+145
+00:13:07,080 --> 00:13:10,740
+مكان الهيدروجين اللي شيلناها حطينا كلور شو هيصير
+
+146
+00:13:10,740 --> 00:13:18,440
+مثلا مركبة اثل كلورايد و هكذا طيب لو اجينا بعد هيك
+
+147
+00:13:18,440 --> 00:13:24,620
+للبروبينوقلنا من مركب البروبين بدنا نشيل هيدروجين
+
+148
+00:13:24,620 --> 00:13:32,000
+ونعمل مجموعة بروبين مثل مثل اثان اثل بروبين بروبين
+
+149
+00:13:32,000 --> 00:13:39,000
+بيوتين بيوتل هتلاحظوا انه هيبدأ يصير عندى مشكلة
+
+150
+00:13:39,000 --> 00:13:46,610
+صغيرة انهالبروبين في كام هيدروجين؟ تمانية هي تلاتة
+
+151
+00:13:46,610 --> 00:13:50,870
+و تلاتة زي بعض وفي هنا الهيدروجينتين اللي اتفقنا
+
+152
+00:13:50,870 --> 00:13:56,470
+انه اختصرناهم في الكتابة اذا شكله العام CH3 CH2
+
+153
+00:13:56,470 --> 00:14:02,830
+CH3 تمان هيدروجينات هذولة تمان هيدروجينات كام نوع؟
+
+154
+00:14:04,020 --> 00:14:07,900
+عبارة عن نوعين التلاتة هذول والتلاتة هذول اللي على
+
+155
+00:14:07,900 --> 00:14:12,400
+الطرف زي بعض وهذه اللي موجودين في النص زي بعض فال
+
+156
+00:14:12,400 --> 00:14:16,960
+تمان هيدروجينات تعون لبروبين نوعين ستة زي بعض
+
+157
+00:14:16,960 --> 00:14:21,800
+وتنتين زي بعض لو شيلت أي واحدة من هان او من هان
+
+158
+00:14:21,800 --> 00:14:26,640
+هعمل مجموعة ولو شيلت واحدة من هان هعمل مجموعة
+
+159
+00:14:26,640 --> 00:14:30,880
+ولذلك بتلاحظوا انه لما باجي بشيل هيدروجين من
+
+160
+00:14:30,880 --> 00:14:35,460
+البروبين بعمل مجموعتيناذا شيلت من الطرف وهي جاهز
+
+161
+00:14:35,460 --> 00:14:39,420
+انه يشبك من هنا من هنا خصمة الهيدروجين هذه معناه
+
+162
+00:14:39,420 --> 00:14:44,140
+الكلام هذا بسميها مجموعة البروبيل ولو بدي اشيل من
+
+163
+00:14:44,140 --> 00:14:50,220
+النص بدي تصير ايزو بروبيل فلاحظوا معي لو بعد هيك
+
+164
+00:14:50,220 --> 00:14:56,360
+اجينا نعمل مركب نضيف كلور ممكن ناس يقولوا حطلي
+
+165
+00:14:56,360 --> 00:15:02,420
+كلور هانأو محل الهيدروجين اللي شلتها في الحالة
+
+166
+00:15:02,420 --> 00:15:06,600
+الأولى شو هيصير اسم المُركّب؟ Isopropyl chloride
+
+167
+00:15:06,600 --> 00:15:11,240
+في الحالة التانية إيش هيصير اسم المُركّب؟
+
+168
+00:15:11,240 --> 00:15:13,020
+Isopropyl chloride
+
+169
+00:15:15,840 --> 00:15:20,340
+واضح؟ و لذلك بدكوا تكونوا منتبهين أن التلات
+
+170
+00:15:20,340 --> 00:15:27,720
+كربونات كم ألكين منهم؟ واحد .. كم ألكين؟ واحد اسمه
+
+171
+00:15:27,720 --> 00:15:33,900
+بروبيل .. كم ألكي لجروب؟ تنتين .. اسمهم بروبيل و
+
+172
+00:15:33,900 --> 00:15:38,660
+ايزو بروبيل .. واضح؟هذا الكلام أكيد بحاجة إلى
+
+173
+00:15:38,660 --> 00:15:44,120
+تدريب وحفظ بعد شوية بنجي على أربع ذرات كربون هنقول
+
+174
+00:15:44,120 --> 00:15:50,960
+الأربع ذرات كربون أساسا منهم كم مركب اتنين بيوتين
+
+175
+00:15:50,960 --> 00:15:57,500
+و ايزو بيوتين طب كم الكل جروب منهم؟ بدي أجي أطلع
+
+176
+00:15:57,500 --> 00:16:05,510
+هنا كم هيدروجين عندى؟في البيوتين العادى عشرة تلاتة
+
+177
+00:16:05,510 --> 00:16:10,950
+و اتنين و اتنين و تلاتة الان هدولة المختصرين لو
+
+178
+00:16:10,950 --> 00:16:18,270
+بيناهم بالاحمر وسألنا العشرة هيدروجين هدولة كام
+
+179
+00:16:18,270 --> 00:16:27,350
+نوع كام نوع هدول العشر هيدروجين نوعين كام نوع كداش
+
+180
+00:16:27,350 --> 00:16:34,450
+و كداشستة زي بعض اللي على الطرف والاربعة هدول زي
+
+181
+00:16:34,450 --> 00:16:38,410
+بعض يعني لو شيلت hydrogen من هان او هان او هان او
+
+182
+00:16:38,410 --> 00:16:44,130
+هدول نفس الاشي هيعطيني مجموعة اش اسمها الـbutyl
+
+183
+00:16:44,130 --> 00:16:48,190
+ولو شيلت اي واحدة من هدول الاربعة هادي او هادي او
+
+184
+00:16:48,190 --> 00:16:52,030
+هادي او هادي كأن بكون شيلت عن موقع اتنين يعني من
+
+185
+00:16:52,030 --> 00:16:55,490
+هان او من هان بشيل عن موقع واحد من هان او من هان
+
+186
+00:16:55,490 --> 00:17:02,320
+بشيل عن موقع اتنينصار عندى من نفس البيوتين العادى
+
+187
+00:17:02,320 --> 00:17:08,340
+كام مجموعة؟ تنتين واحدة بسميها butyl واحدة بسميها
+
+188
+00:17:08,340 --> 00:17:12,060
+secondary butyl secondary اللى احنا شيلنا فيها
+
+189
+00:17:12,060 --> 00:17:16,410
+الهيدروجين من carbon 2الـ Butyl اللي شيلنا فيها
+
+190
+00:17:16,410 --> 00:17:21,910
+الهيدروجين من Carbon-1 مرات كتيرة هتلاحظوا إضافة و
+
+191
+00:17:21,910 --> 00:17:26,270
+ممكن تقرؤوها في بعض الكتب أن هذا الـ Butane بيروح
+
+192
+00:17:26,270 --> 00:17:32,850
+و بيحطه قدام حرف الـ N معناه بيوتين عادي المتسلسل
+
+193
+00:17:32,850 --> 00:17:37,530
+فالـ N هذي جاية من كلمة إيش؟ Normal لـ Butane
+
+194
+00:17:37,530 --> 00:17:41,270
+العادي و المجموعة تبعته هتلاحظوا مرات بيحطوا
+
+195
+00:17:41,270 --> 00:17:46,390
+قدامها حرف الـ Nفإذا قرأنا بيوتين هو نفسه
+
+196
+00:17:46,390 --> 00:17:51,270
+الانبيوتين المتسلسل وإذا قرأنا المجموعة بيوتين هي
+
+197
+00:17:51,270 --> 00:17:55,770
+نفسها الانبيوتين يعني البيوتين العادية اللي من نمر
+
+198
+00:17:55,770 --> 00:18:01,690
+واحد منها شيلنا ذرة إيش الهيدروجين الآن لو حطينا
+
+199
+00:18:01,690 --> 00:18:06,300
+هنا كلور شو هتسمي المركب؟Butylic chloride طب لو
+
+200
+00:18:06,300 --> 00:18:11,440
+حطينا هنا secondary butylic chloride الان لو اجينا
+
+201
+00:18:11,440 --> 00:18:15,120
+على ال isomers التانى اللى من اربع كربونات اللى
+
+202
+00:18:15,120 --> 00:18:21,640
+اسمه ايش ايزو بيوتين و سألنا كام هيدروجين فيه اكيد
+
+203
+00:18:21,640 --> 00:18:27,900
+عشرة لأنه التنين C4H10 طيب اللى مبينين تسعة وين
+
+204
+00:18:27,900 --> 00:18:34,190
+العاشرةالمختصرة هنا عشان يكتمل الشكل الان هدول
+
+205
+00:18:34,190 --> 00:18:41,090
+العشر هيدروجينات كام نوع؟ إذا بتطلع عليهم ممتازة
+
+206
+00:18:41,090 --> 00:18:49,180
+نوعين التسعة هدول زي بعضوهذا الهيدروجين نوع تاني
+
+207
+00:18:49,180 --> 00:18:52,680
+لأن هذا على الطرف وهذا على الطرف وهذا على الطرف
+
+208
+00:18:52,680 --> 00:18:57,020
+وهذا جاء في قلب الجزء فهذه نوع و هذول التسعة زي
+
+209
+00:18:57,020 --> 00:19:01,440
+بعض بناء على ذلك لو شيلنا أي واحدة من هذول هنعمل
+
+210
+00:19:01,440 --> 00:19:09,160
+مجموعةماذا نسمي المجموعة؟ انظروا معي هنا CH3 CH
+
+211
+00:19:09,160 --> 00:19:12,920
+CH3 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+212
+00:19:12,920 --> 00:19:13,020
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+213
+00:19:13,020 --> 00:19:13,200
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+214
+00:19:13,200 --> 00:19:13,560
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+215
+00:19:13,560 --> 00:19:15,980
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+216
+00:19:15,980 --> 00:19:20,860
+CH2 CH2 CH2 CH2 CH2والعدد كله أربعة إذا هذه
+
+217
+00:19:20,860 --> 00:19:27,200
+المجموعة إيش اسمها Isobutyl هذه المجموعة اسمها
+
+218
+00:19:27,200 --> 00:19:30,680
+Isobutyl اللي شيلنا فيها هيدروجين سواء من هنا أو
+
+219
+00:19:30,680 --> 00:19:36,160
+من هنا أو من هنا هي Iso هذا الشكل بيعني Iso هذا
+
+220
+00:19:36,160 --> 00:19:40,120
+التفرع كاربون طالع منها مجموعتين مثل Iso لاحظوا
+
+221
+00:19:40,120 --> 00:19:46,290
+هنا كان عندكم تقريبا نفس الاشي انتبهوا معيcarbon
+
+222
+00:19:46,290 --> 00:19:50,190
+منها مجموعتين مثل شو قلنا ايزو العدد الكلي لل
+
+223
+00:19:50,190 --> 00:19:56,810
+carbons كم كان تلاتة ولذلك سمناها ايزو بروبل الان
+
+224
+00:19:56,810 --> 00:20:01,790
+carbon طالع منها مجموعتين مثل ايزو و العدد الكلي
+
+225
+00:20:01,790 --> 00:20:08,630
+اربعة اذا صارت ايزوبيوتل لو الان بدى اقولها واحدة
+
+226
+00:20:08,630 --> 00:20:13,050
+طيب ال ISO pentel مثلا او ال ISO hexel بتقدر
+
+227
+00:20:13,050 --> 00:20:21,410
+ترسمها اه ع طول بقول هي ال ISO CH3 CH3
+
+228
+00:20:21,410 --> 00:20:26,290
+CH3 الان هكذا صار عندى ISO لو قولت ISO pentel جداش
+
+229
+00:20:26,290 --> 00:20:33,220
+بدى يكون عندى خمسة خمسة اذا بدي كمان هنا CH2CH2 و
+
+230
+00:20:33,220 --> 00:20:37,100
+من هنا شيلت الهيدروجين خليني هادي مثلا لو حطيت
+
+231
+00:20:37,100 --> 00:20:41,720
+كلور هنا كل
+
+232
+00:20:41,720 --> 00:20:51,680
+المركب ايش حيصير ايزو اربعة خمسة بنتل اكلورايد لو
+
+233
+00:20:51,680 --> 00:20:59,960
+حطيت الكلور هنا ايزو بيتل اكلورايد واضح بهذا الشكل
+
+234
+00:20:59,960 --> 00:21:00,300
+بيكون
+
+235
+00:21:03,730 --> 00:21:08,510
+جزء ال ISO التلاتة هدول، الآن إذا بس صفيت عليهم
+
+236
+00:21:08,510 --> 00:21:13,470
+بقول ISO Propyl، زيدت Carbon؟ ISO Butyl، زيدت
+
+237
+00:21:13,470 --> 00:21:17,810
+Carbon؟ ISO Bentyl، الآن هنا بدكوا تنتبهوا، إذا
+
+238
+00:21:17,810 --> 00:21:23,250
+كان عندي شئ بينتهي بالنهاية YL، بحكي عن مجموعة،
+
+239
+00:21:23,250 --> 00:21:28,110
+إذا كان عندي شئ بينتهي بالنهاية N؟بحكي عن ال cane
+
+240
+00:21:28,110 --> 00:21:34,110
+يعني مثلا لو قلنا لطالبة بدنا رسمة ال ISO أكتين
+
+241
+00:21:34,110 --> 00:21:42,950
+اتخيلوا أجاكوا في الامتحان بدي ISO أكتين بتغلبش
+
+242
+00:21:42,950 --> 00:21:49,970
+مباشرة ال ISO كيف شكلها CH3 CH3
+
+243
+00:21:50,800 --> 00:21:56,600
+الان هى صار عندى جزء ال ISO بدي اكمل ل ألكين كم
+
+244
+00:21:56,600 --> 00:22:01,280
+carbon بدى يصير المجموع الكله تمانية اذا هى تلاتة
+
+245
+00:22:01,280 --> 00:22:09,160
+اربعة خمسة ستة سبعة تمانية وهنا بكتب ايش CH3 مش
+
+246
+00:22:09,160 --> 00:22:15,190
+شايل ولا هيدروجينه منه ليش لأنه نهاية N الكينلكن
+
+247
+00:22:15,190 --> 00:22:19,130
+لو كنت بدي الـ iso-octal group من وين هشيل
+
+248
+00:22:19,130 --> 00:22:25,890
+الهيدروجينة؟ من هذه الأخيرة واضح؟ الآن إذا هاي تسع
+
+249
+00:22:25,890 --> 00:22:28,410
+هيدروجينات زي بعض لو شيلت منهم هيدروجينة بطلّق
+
+250
+00:22:28,410 --> 00:22:33,370
+مجموعة isobutyl طب لو شيلت هيدروجين من النص بطلّق
+
+251
+00:22:33,370 --> 00:22:38,270
+مجموعة فيها ذرة الكاربون هذه متصلة بتلت مجموعات
+
+252
+00:22:38,270 --> 00:22:46,250
+CH3 بنسميها tertiarybutylTertiarybutyl مرات
+
+253
+00:22:46,250 --> 00:22:51,210
+بيكتبوا ترت اختصارا و مرات بيحطوا T يعني ممكن
+
+254
+00:22:51,210 --> 00:22:59,700
+تلاقوا Tبيوتل أو تيرت بيوتل تيرتشار بيوتل في كل
+
+255
+00:22:59,700 --> 00:23:04,080
+الأحوال لما نحتاج نشوف هذه الأشياء من ناحية
+
+256
+00:23:04,080 --> 00:23:08,680
+alphabetical أي حرف اللي بنعتمده لأنه بعد شوية لما
+
+257
+00:23:08,680 --> 00:23:13,500
+نسمي المراكبات يلزمنا الترتيب ال alphabetical
+
+258
+00:23:13,500 --> 00:23:19,200
+لبيوتل حتى لو كنتي بتاعة بيوتل هي حرف إيشالـ
+
+259
+00:23:19,200 --> 00:23:23,400
+secondary butyl حرف بيه، ال tertiary butyl حرف
+
+260
+00:23:23,400 --> 00:23:30,960
+بيه، ال isobutyl حرف I، ال isobutyl حرف I مش حرف
+
+261
+00:23:30,960 --> 00:23:36,520
+بيهواضح ال isobutyl لو قلتلكوا alphabetically ايش
+
+262
+00:23:36,520 --> 00:23:40,760
+اول اشي باعتمدوا فيها I لكن tertiary butyl باهمل
+
+263
+00:23:40,760 --> 00:23:45,340
+ال T وتعامل على انه حرف الأول B من ناحية
+
+264
+00:23:45,340 --> 00:23:50,720
+alphabetical و لو حطينا هنا Chlor في شغلات مرات مش
+
+265
+00:23:50,720 --> 00:23:55,780
+بحاجة لفهم بحاجة انكم تحفظوها زي هيك تمام يعني مش
+
+266
+00:23:55,780 --> 00:23:58,600
+قصة tertiary butyl alphabetically
+
+267
+00:24:00,680 --> 00:24:09,180
+B Isobutyl خلصنا واضح؟
+
+268
+00:24:09,180 --> 00:24:13,220
+مرات كتير في التسمية في ناس بصروا على ان بعض
+
+269
+00:24:13,220 --> 00:24:17,180
+الأشياء بدهم يفهموها مش كل شيء في التسمية مش كل
+
+270
+00:24:17,180 --> 00:24:22,020
+شيء في التسمية بيفهم يعني لما اجي اقول والله انت
+
+271
+00:24:22,020 --> 00:24:29,660
+اسمك هدا ليش سموكي هدا خلاص هدا خلاصواحدة تيجي
+
+272
+00:24:29,660 --> 00:24:36,640
+تقولي طب ليش سموه بروبين؟ كان سموه نوبا كلين، ليش
+
+273
+00:24:36,640 --> 00:24:43,120
+سموه بروبين؟مش كل شيء في التسمية بالذات أحيانا
+
+274
+00:24:43,120 --> 00:24:46,900
+بتلاقوا إله منطق وقاعدة زي ما أنتوا أهلكوا سموكم
+
+275
+00:24:46,900 --> 00:24:52,280
+واضح؟ زي ما أهلكوا سموكم كان في شيء معين خلهم
+
+276
+00:24:52,280 --> 00:24:58,620
+يسموا مركب معين بنزين كان في شيء معين حادث صديق
+
+277
+00:24:58,620 --> 00:25:04,780
+اللي بيرجع لتاريخ العلوم أحيانا ممكن بلحظة من
+
+278
+00:25:04,780 --> 00:25:11,700
+اللحظات يلاقي هذا الأصلواللي بيرجع لتاريخ الأسماء
+
+279
+00:25:11,700 --> 00:25:16,280
+اللي بيرجع لتاريخ الأسماء ممكن يلاقي أصل لأسماءكم
+
+280
+00:25:16,280 --> 00:25:22,460
+حتى لو أنتم مش عارفينه يعني ممكن لمن ولدتوا كان
+
+281
+00:25:22,460 --> 00:25:26,860
+متوفي عامة إلكم اسمها هودا إكراما إليها سموكوا
+
+282
+00:25:26,860 --> 00:25:30,940
+هودا الآن أنا بالنسبة إيه هذه المعلومة؟ مابعرفاش
+
+283
+00:25:30,940 --> 00:25:35,220
+ولذلك خدوا تسمية العناصر مرة بتلاقي العنصر بيقوله
+
+284
+00:25:35,220 --> 00:25:41,090
+مسمى على اسم مدينةمر على اسم بني آدم اللي اكتشفه،
+
+285
+00:25:41,090 --> 00:25:46,550
+مر على اسم كذا، فأصل الاسم قد لا نعرفه، قد يكون له
+
+286
+00:25:46,550 --> 00:25:52,930
+أصل، لكن احنا ايش؟ ما بنعرفوش، الأن بالنسبة لنا
+
+287
+00:25:52,930 --> 00:25:58,990
+هذه سيارة مرسيدس، اسم، لكن يا تورا لو أعطيتكوا
+
+288
+00:25:58,990 --> 00:26:02,170
+واجب، ليش سموا ال مرسيدس مرسيدس؟
+
+289
+00:26:05,190 --> 00:26:10,310
+فتشوا عليه و هتقولي الجواب المرة الجاية هتلاحظوا
+
+290
+00:26:10,310 --> 00:26:15,530
+إنه إله اسم ومسمى على اسم واحدة وكذا إله أصل بس مش
+
+291
+00:26:15,530 --> 00:26:18,150
+كتير بهمن الأصل في لحظة من لحظات بلاش نضيع وقت
+
+292
+00:26:18,150 --> 00:26:24,610
+كتير الآن هذه المجموعات يجب أن تتدربوا عليها يجب
+
+293
+00:26:24,610 --> 00:26:29,810
+أنكم تحفظوها بشكل جيد هذا الكلام كيف بيجي بالتدريب
+
+294
+00:26:29,810 --> 00:26:33,490
+كيف بيجي بالتدريب الآن
+
+295
+00:26:34,940 --> 00:26:39,940
+بعد ما أخدنا ال الكانز البسيطة و ال alkyl groups
+
+296
+00:26:39,940 --> 00:26:45,120
+البسيطة بدنا ناخد تسمية ال الكانز بال IUPAC system
+
+297
+00:26:45,120 --> 00:26:50,360
+حتى لو كبرت و صارت متفرعة واضح؟ يعني تسمية ال
+
+298
+00:26:50,360 --> 00:26:54,340
+الكانز الكبيرة اللي مامرتش علينا بال IUPAC system
+
+299
+00:26:54,730 --> 00:27:00,050
+ال ايوبك سيستم بيعتمد على ان نبحث عن اطول سلسلة
+
+300
+00:27:00,050 --> 00:27:05,330
+كربونية و اسم عليها يعني لو اطول سلسلة تلاتة نهاية
+
+301
+00:27:05,330 --> 00:27:11,110
+الاسم عندى ابروبين لو اربعة بيوتين تمانية اكتيل
+
+302
+00:27:12,590 --> 00:27:17,830
+فالشيء الأول بيقولنا choose the largest continuous
+
+303
+00:27:17,830 --> 00:27:23,090
+chain الان رجاء ماحدش يفهم السلسلة أن انتوا
+
+304
+00:27:23,090 --> 00:27:28,550
+بتكونوا تشوفوها مرسومة عدل بشكل أفقي أو بشكل عمودي
+
+305
+00:27:28,550 --> 00:27:33,350
+هذا الشيء ليس له معنى أنها تكون أفقي أو عمودي أو
+
+306
+00:27:33,350 --> 00:27:38,740
+مائلة معنى سلسلةذرات كربون ورا بعض بأي طريقة انا
+
+307
+00:27:38,740 --> 00:27:43,180
+ارسمهم هذا الكلام لا معنى له كله ممكن يعني لو بدأ
+
+308
+00:27:43,180 --> 00:27:48,920
+احكي مثلا عن خمسة لو بدأ احكي عن خمسة هذه سلسلة من
+
+309
+00:27:48,920 --> 00:27:59,380
+خمسة تمام وهذه سلسلة من خمسة وممكن ناخد كمان هذه
+
+310
+00:27:59,380 --> 00:28:05,360
+بهذا الشكلسلسلة من الخمسة و ممكن نرسمها بطريقة
+
+311
+00:28:05,360 --> 00:28:12,440
+تانيةسلسلة من خمسة فمعنى سلسلة ذرات متتالية وليس
+
+312
+00:28:12,440 --> 00:28:15,740
+الطريقة المرسومة بعض الناس بيقول سلسلة يعني بيشوفه
+
+313
+00:28:15,740 --> 00:28:21,800
+هيك حسب نظره أفقي أو عمودي لأ لأ معنى سلسلة كام
+
+314
+00:28:21,800 --> 00:28:25,360
+ذرة كربون متتالية فاهمنا إيش معنى سلسلة فلو قولت
+
+315
+00:28:25,360 --> 00:28:29,220
+هنا أما أطول سلسلة واحد اتنين تلاتة أربعة خمسة
+
+316
+00:28:29,220 --> 00:28:33,060
+واحد اتنين تلاتة أربعة خمسة واحد اتنين تلاتة أربعة
+
+317
+00:28:33,060 --> 00:28:36,580
+خمسة واحد اتنين تلاتة أربعة خمسة ابلاحظين مرسومين
+
+318
+00:28:36,580 --> 00:28:43,470
+بطرقمختلفة لكن بالنسبة لي معنى أطول سلسلة أطول عدد
+
+319
+00:28:43,470 --> 00:28:47,870
+متتالي من ذرات الكربون كيف يرتسموا مش مشكلة واضح و
+
+320
+00:28:47,870 --> 00:28:52,010
+لذلك بعد شوية اشوفوا مثلا هذا المركب هين اتكلمت عن
+
+321
+00:28:52,010 --> 00:28:58,190
+سلسلة اللي ماعطيها اللون الأحمر ولو مش مبينة بشكل
+
+322
+00:28:58,190 --> 00:29:04,370
+مستقيم بالنسبة لكم هذا شيء ما لهش معنى الآنحسب
+
+323
+00:29:04,370 --> 00:29:08,130
+أطول سلسلة بيكون اسم المُركّب لو كان عندنا تلاتة
+
+324
+00:29:08,130 --> 00:29:13,050
+نهاية المُركّب ابرو بين خمسة بينتين و هكذا طيب لما
+
+325
+00:29:13,050 --> 00:29:17,370
+بيصير في عندي سلسلة هذه السلسلة أكيد بيتفرع منها
+
+326
+00:29:17,370 --> 00:29:23,010
+شغلات هذه بسميها أنا الأشياء المتفرعة من السلسلة
+
+327
+00:29:23,010 --> 00:29:26,870
+اللي طالعة من أطول سلسلة carbon بقول عنها
+
+328
+00:29:26,870 --> 00:29:31,980
+substituent هذه كلمة هتصير اتمر عليكمكثير
+
+329
+00:29:31,980 --> 00:29:38,040
+Substituents اللي هي الأشياء المبدلة الان كام
+
+330
+00:29:38,040 --> 00:29:43,460
+Substituents على هذا المركب متفرع منه؟ اتنين هدولة
+
+331
+00:29:43,460 --> 00:29:48,920
+ال Substituents لازم انا اوضحهم او اوضح من اي نقطة
+
+332
+00:29:48,920 --> 00:29:53,060
+تفرعوا من اي مكان تفرعوا طب لما هذي بدي اعطيها اسم
+
+333
+00:29:53,060 --> 00:29:57,820
+هعطيها Chloro لما هذي بدي اعطيها اسم هعطيها Abromo
+
+334
+00:29:57,820 --> 00:30:02,830
+بعدين بدي اقول لك Chloro من وين اتفرعت؟من أي موقع
+
+335
+00:30:02,830 --> 00:30:08,690
+لبرومو من وين اتفرعت اذا بالزمن ترقيم لهالسلسلة
+
+336
+00:30:08,690 --> 00:30:12,950
+طالما بحكي سلسلة إذا عندي احتمالين ترقيم ممكن أبدأ
+
+337
+00:30:12,950 --> 00:30:17,770
+من هنا واحد اتنين تلاتة أربعة خمسة أو من هنا واحد
+
+338
+00:30:17,770 --> 00:30:23,130
+اتنين تلاتة أربعة خمسة من أي جهة بدي أبدأ الجهة
+
+339
+00:30:23,130 --> 00:30:26,910
+اللي بتخلي ال substituents أرقامهم أقل ما يمكن
+
+340
+00:30:26,910 --> 00:30:30,230
+يعني لو بدأت من هنا زي ما احنا عاملين ال chlorine
+
+341
+00:30:30,230 --> 00:30:34,280
+على اتنين و ال brom على تلاتة اتنين و تلاتةخمسة لو
+
+342
+00:30:34,280 --> 00:30:38,600
+بدأت منها ان واحد اتنين تلاتة اربعة صارت هذه على
+
+343
+00:30:38,600 --> 00:30:43,840
+تلاتة وهذه على اربعة تلاتة واربعة اذا ماهو اقل
+
+344
+00:30:43,840 --> 00:30:50,900
+ترقيم هذا ولذلك لما بدي ارقم دائما عند احتمالين
+
+345
+00:30:50,900 --> 00:30:56,220
+الاحتمال اللي بدي اختارهالـ lowest possible
+
+346
+00:30:56,220 --> 00:31:00,780
+numbering أقل احتمال بيعطي الـ substituents أرقام
+
+347
+00:31:00,780 --> 00:31:05,640
+طب اعرفنا الأرقام و اعرفنا الآن انه صار عندنا على
+
+348
+00:31:05,640 --> 00:31:13,800
+موقع اتنين ذرة اكلورو مظبوط ولا لأ اكلورو وع موقع
+
+349
+00:31:13,800 --> 00:31:20,410
+تلاتة ذرة ابروموبدي اكتب الاسم كامل الاسم عادة
+
+350
+00:31:20,410 --> 00:31:26,130
+بنبدأ في كتابته من الخلف للامام اول كلمة في الاسم
+
+351
+00:31:26,130 --> 00:31:30,970
+انه عندي خمسة اذا مركبه بنتين يعني اول شي بدي ابدأ
+
+352
+00:31:30,970 --> 00:31:36,070
+اكتبه بنتين هذا البنتين الان بيحمل برومو و كلورو
+
+353
+00:31:36,070 --> 00:31:41,630
+مين بدي اذكره في الاول ال alphabetical اللي بيظهر
+
+354
+00:31:41,630 --> 00:31:47,510
+اولا مين بيجي قبل ال B ولا ال Cالـ B A B C D
+
+355
+00:31:47,510 --> 00:31:51,090
+شوفتوا قبل شوية ليش أنا نبهت كل ال alphabetical في
+
+356
+00:31:51,090 --> 00:31:58,010
+المجموعات أه إذا هذا هيكون three bromo two
+
+357
+00:31:58,010 --> 00:32:03,430
+chlorobentain واضح؟ لأن أنا عندي كام substituent؟
+
+358
+00:32:03,430 --> 00:32:10,670
+هذه و هذه كيف بأذكرهم؟list substituents
+
+359
+00:32:10,670 --> 00:32:15,830
+alphabetically أذكرهم alphabetically أذكر ال B قبل
+
+360
+00:32:15,830 --> 00:32:22,650
+ال C قبل ال D قبل ال E و هكذا طبعا هنا اجتمل الاسم
+
+361
+00:32:22,650 --> 00:32:26,930
+بضيف معلومة أنه لو من مجموعة معينة كان في عندي
+
+362
+00:32:26,930 --> 00:32:33,400
+تنتينبدي أستعمل لمضاي، لو كان في عندي تلاتة ا try،
+
+363
+00:32:33,400 --> 00:32:38,700
+لو عندي أربعة تترى، و هكذا، واضح؟ انشوف أمثلة
+
+364
+00:32:38,700 --> 00:32:46,820
+إضافية، انشوفأمثلة إضافية مثلا هاي مثال أصعب شغلة
+
+365
+00:32:46,820 --> 00:32:52,220
+أنه فعلا طول أطول سلسلة يعني لو إجيت بدي أطول
+
+366
+00:32:52,220 --> 00:32:57,460
+سلسلة ممكن أعد واحد اتنين تلاتة واحد اتنين تلاتة
+
+367
+00:32:57,460 --> 00:33:03,340
+أربعة خمسة واحد اتنين تلاتة أربعة خمسة احتمالات
+
+368
+00:33:03,340 --> 00:33:07,780
+كتيرة بدي أضلني أجرب لحد ما فعلا ألاقي أطول سلسلة
+
+369
+00:33:07,780 --> 00:33:14,930
+واحد اتنين تلاتة أربعة خمسة ستة سبعةإذا مركّب إيش؟
+
+370
+00:33:14,930 --> 00:33:15,730
+هبتين
+
+371
+00:33:23,230 --> 00:33:37,450
+مثل مثل مثل مثل مثل مثل مثل مثل
+
+372
+00:33:46,950 --> 00:33:51,550
+إذا من هنا لازم أرقم فالمثلز اللي عندي وين موجودين
+
+373
+00:33:51,550 --> 00:33:57,350
+على اتنين واربعة هيصير مركبة two four dimethyl
+
+374
+00:33:57,350 --> 00:34:02,850
+heptane two four dimethyl heptane الان هاي مركب
+
+375
+00:34:02,850 --> 00:34:10,610
+تاني بتجارب كتير هتكتشف ان هاي أطول سلسلة سبعة ايش
+
+376
+00:34:10,610 --> 00:34:11,750
+بيتفرع منها
+
+377
+00:34:14,510 --> 00:34:24,070
+هذه المجموعة اللي مرت علينا ايزو بروبل و مثل الان
+
+378
+00:34:24,070 --> 00:34:30,410
+ايزو بروبل حرف I و المثل حرف M و المركب هبتين و I
+
+379
+00:34:30,410 --> 00:34:36,870
+قبل ال M اذا حيصير اسم المركب for aizobrobel انها
+
+380
+00:34:36,870 --> 00:34:38,530
+موجودة على موقع اربعة
+
+381
+00:34:41,630 --> 00:34:46,510
+لاحظوا في كل التسمية لو تطبعوا على الكمبيوتر في أي
+
+382
+00:34:46,510 --> 00:34:54,490
+فراغولا فراغ دائما قبل الرقم وبعد الرقم بتحطه شرطة
+
+383
+00:34:54,490 --> 00:34:58,330
+ما عدا إذا كنا بنحط في أول الإسم بتكون الشرطة فقط
+
+384
+00:34:58,330 --> 00:35:04,170
+بعد الرقم بدون أي فراغات يعني هذا كله متصل بعض
+
+385
+00:35:04,170 --> 00:35:08,830
+كتابة من هنا لهنا مافيش عندي فراغات لو بكتب اسم
+
+386
+00:35:08,830 --> 00:35:14,550
+هذا المركب على الكمبيوتر قبل الرقم شرطة وبعده شرطة
+
+387
+00:35:14,550 --> 00:35:21,380
+ما لم يكن الرقمفي الأول فبس بيكون فيه بعده شرطة
+
+388
+00:35:22,430 --> 00:35:27,630
+الان في عندكم امثلة كتير بإمكانكوا تتدربوا عليها
+
+389
+00:35:27,630 --> 00:35:31,250
+ماعطيكوا انا في الواجبات بالذات في الامتحانات
+
+390
+00:35:31,250 --> 00:35:35,270
+السابقة اللي موجودة عندكم كل امتحان بتلاقي عليه
+
+391
+00:35:35,270 --> 00:35:40,310
+اربع خمس مركبات كيف تسموهم مالم تتدربوا على حفظ
+
+392
+00:35:40,310 --> 00:35:44,890
+أسماء ال الkins على حفظ المجموعات على كيف تسموا
+
+393
+00:35:44,890 --> 00:35:48,970
+مركب مش هتقدروا تطبقوا يعني لازم لو واحد كنتوا
+
+394
+00:35:48,970 --> 00:35:50,210
+تدرسوا و تتدربوا أكثر
+
+395
+00:35:54,510 --> 00:35:58,250
+لأ لأ اعتمدي على اللي احنا بنشرحه بشكل اكبر
+
+396
+00:35:58,250 --> 00:36:02,370
+واعتمدي على الامتحانات الكتيرة اللي موجودة عندكم
+
+397
+00:36:02,370 --> 00:36:08,470
+بتعطيكي اسئلة وافية في الموضوع الآن بنيجي لنقطة
+
+398
+00:36:08,470 --> 00:36:14,350
+خاصة صغيرة بنضيفها في هذا الموضوع أحيانا بنيجي
+
+399
+00:36:14,350 --> 00:36:20,410
+نبحث عن أطول سلسلة بنلاحظ أنه بيطلع عندنا احتمالين
+
+400
+00:36:20,410 --> 00:36:27,520
+مش احتمال واحدمثلا هذا المركب هو نفسه هذا المركب
+
+401
+00:36:27,520 --> 00:36:31,440
+تماما لو بتتطلع عليه يعني احنا رسمنا المركب هذا
+
+402
+00:36:31,440 --> 00:36:36,460
+عملنا له نسخ و لاصق هنا لما نيجي نبحث عن أطول
+
+403
+00:36:36,460 --> 00:36:41,680
+سلسلة عدنا كتير هيقولنا واحد اتنين تلاتة اربعة
+
+404
+00:36:41,680 --> 00:36:47,800
+خمسة ستة سبعة اجت طالبة تانية عدت من هنا واحد
+
+405
+00:36:47,800 --> 00:36:55,600
+اتنين تلاتة اربعة خمسة ستة سبعةطب يا تورا بدي
+
+406
+00:36:55,600 --> 00:37:00,820
+أختار هذه السلسلة و لا بدي أختار هذه السلسلة طلع
+
+407
+00:37:00,820 --> 00:37:05,780
+عندك أكتر من سلسلة سبعة في عندنا قاعدة بتقول if
+
+408
+00:37:05,780 --> 00:37:09,760
+there are two equal along continuous chains يعني
+
+409
+00:37:09,760 --> 00:37:13,180
+لو في عندكوا سلسلتين متساويات في الطول في
+
+410
+00:37:13,180 --> 00:37:16,780
+الاحتمالات ا choose the one with most branches
+
+411
+00:37:16,780 --> 00:37:21,820
+اختار السلسلة اللي فيها تفرعات أكتريعني لو اتطلعت
+
+412
+00:37:21,820 --> 00:37:28,340
+على السلسلة هذه، كم تفرع طالع منها؟ اتنين، شغلتين
+
+413
+00:37:28,340 --> 00:37:31,540
+طالعين منها، لو اتطلعت على السلسلة هذه، كم تفرع
+
+414
+00:37:31,540 --> 00:37:37,980
+طالع منها؟ مجموعة واحدة، واضح؟ هذه طالع منها فقط
+
+415
+00:37:37,980 --> 00:37:42,240
+تفرع واحد، هيو، هنا طالع تفرعين، ابن اختار اللي
+
+416
+00:37:42,240 --> 00:37:47,000
+فيهاتفرعين طبعا لما نختار او ناخد ال lower
+
+417
+00:37:47,000 --> 00:37:51,640
+numbering على نمرة تلاتة في عندي مجموعة CH2 CH3
+
+418
+00:37:51,640 --> 00:37:55,600
+هذه اللي بيقول عنها إثل وعن نمرة اتنين المثل three
+
+419
+00:37:55,600 --> 00:38:00,300
+ethyl two methyl heptane بينما لو واحدة اختارت هذه
+
+420
+00:38:00,300 --> 00:38:04,220
+هتقول heptane على نمرة تلاتة هذه المجموعة
+
+421
+00:38:04,220 --> 00:38:09,520
+isopropyl فهذا الاسم three isopropyl heptane is
+
+422
+00:38:09,520 --> 00:38:14,650
+not a correct nameممكن واحدة في الامتحان تعمله،
+
+423
+00:38:14,650 --> 00:38:18,230
+تعتقد أنها عملت جيدا، في الآخر تتفاجأ أنه غلط
+
+424
+00:38:18,230 --> 00:38:22,670
+بالكامل، ليش؟ لأنها مانتبهتش أنه عندها سلسلتين،
+
+425
+00:38:22,670 --> 00:38:26,690
+ممكن يكونوا سبعة، وأنه لو أخدت من هنا، اللي هي هذه
+
+426
+00:38:26,690 --> 00:38:30,130
+السلسلة، هذه فيها ال most branches، فيها التفرعات
+
+427
+00:38:30,130 --> 00:38:34,390
+الأكثرولذلك اللي بده يشتغل في التسمية بده يكون
+
+428
+00:38:34,390 --> 00:38:39,610
+منتبه أنه فعلا لجأ أطول سلسلة واتأكد أنه مافيش
+
+429
+00:38:39,610 --> 00:38:45,150
+غيرها، لو لجأت إنتين بنفس الطول، بده يختار الأكثر
+
+430
+00:38:45,150 --> 00:38:52,310
+تفرعا، بده يختار السلسلة الأكثر تفرعا، واضح هذا
+
+431
+00:38:52,310 --> 00:39:00,220
+الكلام؟ ممكن نجرب ما أعطيكممثال حتى نشوف انكم
+
+432
+00:39:00,220 --> 00:39:18,060
+أتقنتوا هذا الكلام ولا لا هذا
+
+433
+00:39:18,060 --> 00:39:23,040
+مركب ابدأوا
+
+434
+00:39:23,040 --> 00:39:24,780
+فاكروا فيه وشوفوا
+
+435
+00:39:27,090 --> 00:39:33,530
+أيش أطول سلسلة موجودة فيه و
+
+436
+00:39:33,530 --> 00:39:38,610
+أول ما نعملها بأنصح اكون معاكم قلم فوسفور اتعلموا
+
+437
+00:39:38,610 --> 00:39:44,350
+عليها عشان تقدروا تشوفوا كل ما يتفرع منها واضح؟
+
+438
+00:39:44,350 --> 00:39:49,650
+الآن أكيد هتبدو تعدوا أنتوا واحد تنين تلاتة أربعة
+
+439
+00:39:49,650 --> 00:39:53,310
+أكيد لو قلتوا تلاتة تلاتة أربعة تلاتة أربعة نفس
+
+440
+00:39:53,310 --> 00:40:02,770
+الأشي أوواحد اتنين تلاتة او واحد اتنين تلاتة اربعة
+
+441
+00:40:02,770 --> 00:40:11,370
+خمسة ستة ايش رأيكوا او اي واحدة من هدول هادي زي
+
+442
+00:40:11,370 --> 00:40:14,650
+هادي زي هادي ماهم تلات اطراف واحد اتنين واحد اتنين
+
+443
+00:40:14,650 --> 00:40:22,090
+واحد اتنين اي واحدة بتاخدوها مافيش فيه مشكلة منها
+
+444
+00:40:23,210 --> 00:40:27,150
+أي واحدة من هدولة بيمشي تكون المرة واحدة لأنها
+
+445
+00:40:27,150 --> 00:40:33,650
+وادي وادي زي بعض واحد تانين تلاتة أربعة خمسة ستة
+
+446
+00:40:33,650 --> 00:40:39,630
+سبعة اه الآن هي أطول سلسلة خليني أعلمها و بأنصحكوا
+
+447
+00:40:39,630 --> 00:40:44,630
+لو عندكم طلم فسفور أسفر اتعلموها هي أطول سلسلة
+
+448
+00:40:44,630 --> 00:40:51,050
+عشان نقدر نشوف كام تفرع طالع منها هذه السلسلةاربع
+
+449
+00:40:51,050 --> 00:41:01,330
+انا مع الكلور هذه CH3 وهذه CH3 وهذه CH3 وهنا
+
+450
+00:41:01,330 --> 00:41:06,010
+الكلور اربع تفرعات طالع منها طب لو بدى اعطيها اقل
+
+451
+00:41:06,010 --> 00:41:16,080
+ترقيم من فضل من فضل اكيد واحدتلاتة اربعة خمسة ستة
+
+452
+00:41:16,080 --> 00:41:21,160
+سبعة الان لو بدنا نكتب الاسم كاملا كيف بدنا نبدأ
+
+453
+00:41:21,160 --> 00:41:27,880
+نكتب الاسم؟ من الخلف للامام ايش مركب طالما سبعة؟
+
+454
+00:41:27,880 --> 00:41:35,360
+هبتين الان هذا الهبتين كم نوع من المجموعات يحمل؟
+
+455
+00:41:35,360 --> 00:41:44,910
+نوعين اكلوروومثل ومثل ومثل اتراي مثل اذا هذا حقيقة
+
+456
+00:41:44,910 --> 00:41:54,550
+الـ C في الأول الكلورو اتراي مثل الان الكلورو وين
+
+457
+00:41:54,550 --> 00:42:01,870
+موقعها على نمرة أربعة four شرطة كلورو ال اتراي مثل
+
+458
+00:42:01,870 --> 00:42:10,930
+وين موجودين على اتنينو اتنين و تلاتة لازم احدد
+
+459
+00:42:10,930 --> 00:42:15,330
+تلات ارقام طالما try مثل لازم التلات ارقام بينه
+
+460
+00:42:15,330 --> 00:42:21,090
+اذا هنا فعلا بدي اكتب شرطة اتنين اتنين تلاتة هدف
+
+461
+00:42:21,090 --> 00:42:27,650
+هذا الموقع ان انا اكتبها صح هتكون اتنين اتنين
+
+462
+00:42:27,650 --> 00:42:32,090
+تلاتة try مثل
+
+463
+00:42:37,340 --> 00:42:47,340
+4-chloro-2-2-3-trimethylheptane
+
+464
+00:42:52,160 --> 00:42:56,040
+ماحدش يغلط .. مرات كتير بعض الناس اللي بيحفظوا
+
+465
+00:42:56,040 --> 00:42:59,400
+مجموعات شو الغلط اللي بيجعوا فيه، مابيبحثوش عن
+
+466
+00:42:59,400 --> 00:43:02,480
+أطول سلسلة، بيجوا و بيقولوا اه هذه ال carbon اللي
+
+467
+00:43:02,480 --> 00:43:06,300
+حملة تلت مجموعات tertiary-butyl وهذه السلسلة
+
+468
+00:43:07,580 --> 00:43:11,460
+وبالتالي بيسموه hexane وحمل على نمرة 2 tertiary
+
+469
+00:43:11,460 --> 00:43:16,920
+butyl بالفعش أنا مابخدش أسماء المجموعات إلا بعد ما
+
+470
+00:43:16,920 --> 00:43:23,700
+أحدد أطول سلسلة دائما نمرة واحد حدده أطول سلسلة
+
+471
+00:43:23,700 --> 00:43:28,340
+بعض الناس بيغلط بيجي بيقول لأ هذه تعتبر مجموعة في
+
+472
+00:43:28,340 --> 00:43:32,830
+البداية يعني لو أنا هنا كنت كاتب CH3بروح و بقول
+
+473
+00:43:32,830 --> 00:43:36,210
+ادي مجموعة مثل لأ دي جزء من السلسلة بنفعش اسميها
+
+474
+00:43:36,210 --> 00:43:41,110
+مجموعة هذه من الأخطاء الشائع لبعض الناس بيجي بعمل
+
+475
+00:43:41,110 --> 00:43:44,650
+الترقيم من هان و بعدين بيقول على نمر واحد في عندي
+
+476
+00:43:44,650 --> 00:43:50,950
+try مثل .. لأ مش هيك تأخذه لازم أفتش عليه أطول
+
+477
+00:43:50,950 --> 00:43:54,630
+سلسلة و بعدين أشوف إيش في عندي مجموعات حسب ما
+
+478
+00:43:54,630 --> 00:43:59,010
+اتعلمت بأعمل التسمية تبعي
+
+479
+00:44:04,700 --> 00:44:10,980
+هذه تقريبا فكرة عن ال الكنز بشكل عام لو اتكلمنا عن
+
+480
+00:44:10,980 --> 00:44:15,960
+ال physical properties of الكنز هنلاحظ القاتل اول
+
+481
+00:44:15,960 --> 00:44:23,940
+شئ ال الكنز هم water insoluble ليش؟ لان دائما ال
+
+482
+00:44:23,940 --> 00:44:31,440
+الكنز تتذكر انهم non polar والمية polar حسب قاعدة
+
+483
+00:44:31,440 --> 00:44:36,250
+like dissolves likeالالكينز لا يدوبون في المياه
+
+484
+00:44:36,250 --> 00:44:40,590
+ولذلك من هؤلاء الالكينز على سبيل المثال البنزين
+
+485
+00:44:40,590 --> 00:44:44,890
+اللي هو أقود السيارات واضح هل يا تورا هذا بيدوب في
+
+486
+00:44:44,890 --> 00:44:49,090
+المياه ولا بيعمل طبقة تانية بيعمل طبقة تانية هنا
+
+487
+00:44:49,090 --> 00:44:54,810
+خليني أنبه لنقطة خطأ شائعلأنه احنا باللغة العربية
+
+488
+00:44:54,810 --> 00:44:59,330
+بنستعمل كلمة بنزين لما بنعب السيارة بنقول بنزين
+
+489
+00:44:59,330 --> 00:45:05,310
+فناس كتير بيخطئوا و بيفكروا انه احنا بنعب السيارة
+
+490
+00:45:05,310 --> 00:45:09,150
+البنزين هذا اللي مار عليكم اللي هو البنزين العطري
+
+491
+00:45:09,150 --> 00:45:16,230
+هذا الكلام خطأ طب ايش اسم هو بالانجليزي وقود
+
+492
+00:45:16,230 --> 00:45:23,650
+السيارات ال fuel اسمه جازولينأحنا بالعربي هذا
+
+493
+00:45:23,650 --> 00:45:29,390
+الجازولين بنقول عنه بنزين لكن هو حقيقة خليط من
+
+494
+00:45:29,390 --> 00:45:35,870
+الالكينز بشكل أساسي مركبين من الالكينز هو خليط من
+
+495
+00:45:35,870 --> 00:45:40,190
+الهيبتين والايزو
+
+496
+00:45:40,190 --> 00:45:40,710
+أكتين
+
+497
+00:45:43,660 --> 00:45:48,340
+فالجازولين اللي هو وقود السيارات اللي احنا بنعبيه
+
+498
+00:45:48,340 --> 00:45:52,180
+باللغة العربية متعودين نقول عنه بنزين مالوش هذا ال
+
+499
+00:45:52,180 --> 00:45:56,020
+structure ولا له علاقة بهذا ال structure لأ
+
+500
+00:45:56,020 --> 00:46:02,000
+gasoline is a mixture of alkanes الجازولين وقود
+
+501
+00:46:02,000 --> 00:46:05,780
+السيارات اللي بنعبيه هو خليط من ال alkanes شو ما
+
+502
+00:46:05,780 --> 00:46:10,480
+دول ال alkanes؟الهبتين وال ايزو اكتين و بتهيألي
+
+503
+00:46:10,480 --> 00:46:15,020
+اليوم احنا رسمنا شكل الهبتين سبع كربونات و رسمنا
+
+504
+00:46:15,020 --> 00:46:18,900
+شكل ال ايزو اكتين اللي فيه مجموعة ال ايزو و بنكمل
+
+505
+00:46:18,900 --> 00:46:24,500
+لكم كربونات تمانية الان هدولة الكنز لو أخدنا هذا
+
+506
+00:46:24,500 --> 00:46:29,880
+الجازولين وقود السيارات و حطناه فوق ميهبيخلط
+
+507
+00:46:29,880 --> 00:46:34,640
+معاها، بيدوب فيها؟ لأ، فإذا الالكينز they are
+
+508
+00:46:34,640 --> 00:46:39,880
+water insoluble، ليش؟ لأن هدول المركبات، القوة
+
+509
+00:46:39,880 --> 00:46:46,010
+اللي فيهم، London forces، بينما الميهالهيدروجين
+
+510
+00:46:46,010 --> 00:46:52,810
+بوندنج فيها الميّه بولر والالكينز نان بولر فالبولر
+
+511
+00:46:52,810 --> 00:46:57,370
+والنان بولر بخلطوش مع بعض are water insoluble طبعا
+
+512
+00:46:57,370 --> 00:47:02,000
+كونوا القوة اللي موجودة فيهم ضعيفةاللي هي أضعف نوع
+
+513
+00:47:02,000 --> 00:47:05,440
+من القوة الـ London Forces معناه ذلك الجزيئات
+
+514
+00:47:05,440 --> 00:47:10,880
+بتاعتهم ممسوقة ببعضها بقوة ولا بقوة ضعيفة؟ بقوة
+
+515
+00:47:10,880 --> 00:47:16,160
+ضعيفة، هذا بيقدر إلى إنها بتتبخر بشكل سريع وإلى أن
+
+516
+00:47:16,160 --> 00:47:22,000
+نقطة الغليان تبعتها أيضا منخفضة جدا ولذلك لو أنا
+
+517
+00:47:22,000 --> 00:47:25,380
+إجيت اتطلعت على ال canes اللي في الجدول هلاحظ ال
+
+518
+00:47:25,380 --> 00:47:32,540
+methane غازالإيثين غاز، البروبين غاز، البيوتين
+
+519
+00:47:32,540 --> 00:47:36,600
+غاز، اللي هو الغاز المنزلي، غاز الطهي المنزلي، هو
+
+520
+00:47:36,600 --> 00:47:41,740
+البيوتين البنتين بيبدأ يصير سائل بنقطة غليان حوالي
+
+521
+00:47:41,740 --> 00:47:46,500
+36 درجة مؤوية، نقطة غليان منخفضة البنزين نفسه نقطة
+
+522
+00:47:46,500 --> 00:47:49,920
+غليانه منخفضة، ولذلك بيتبقر بسرعة وبيعمل حرائق
+
+523
+00:47:49,920 --> 00:47:56,570
+بسرعةواضح؟ كل هذا الكلام لأن القوة الترابط اللي
+
+524
+00:47:56,570 --> 00:48:01,070
+موجودة فيه هي ال London forces اللي هي أضعف أنواع
+
+525
+00:48:01,070 --> 00:48:05,550
+قوة الترابط فالجزيئات غير مترابطة بقوة و من هنا
+
+526
+00:48:05,550 --> 00:48:10,910
+بيكون ال alkanes لهم low boiling points بالتأكيد
+
+527
+00:48:10,910 --> 00:48:15,720
+ال cane من ذرةنقطة غليانه اقل من ذرتين اقل من
+
+528
+00:48:15,720 --> 00:48:20,460
+تلاتة وكل ما يبدو يزيدوا عدد ذرات الالكين ايش
+
+529
+00:48:20,460 --> 00:48:26,020
+بيصيلا نقطة الغليان بتزيد واضح؟أخر نقطة اليوم
+
+530
+00:48:26,020 --> 00:48:31,560
+بنحكيها أن الالكينز لنفس المركب يعني لنفس العدد
+
+531
+00:48:31,560 --> 00:48:36,580
+الخمسة مثلا ممكن تكون chain متسلسلة و ممكن تكون
+
+532
+00:48:36,580 --> 00:48:39,900
+branched معناة chain مرة تانية أن الخمسة ورا بعض
+
+533
+00:48:39,900 --> 00:48:44,020
+branched هي عندي واحد اتنين تلاتة مثلا في البنتين
+
+534
+00:48:44,020 --> 00:48:49,800
+و من موقع اتنين اعملت تفرعينهنا خمس ذرات وهنا خمس
+
+535
+00:48:49,800 --> 00:48:53,560
+ذرات الخمس هذول جايين إيش؟ ورا بعض بقول عنهم chain
+
+536
+00:48:53,560 --> 00:49:00,140
+compounds هذول برانش دائما بنقول برانش الكنز have
+
+537
+00:49:00,140 --> 00:49:02,840
+lower boiling points than the corresponding long
+
+538
+00:49:02,840 --> 00:49:10,620
+chain of kens يعني هذا و هذا له نفس الصيغة C5H12
+
+539
+00:49:10,620 --> 00:49:17,970
+لكن مين له نقطة غليان أعلى؟الـ Chain أقل ال branch
+
+540
+00:49:17,970 --> 00:49:23,330
+ليش؟ لأن ال branch بيكون عامل زي الكورة الآن
+
+541
+00:49:23,330 --> 00:49:27,990
+تخيلوا لو حطيتوا أنتوا نفسكم تلت كورات هيك فوق بعض
+
+542
+00:49:27,990 --> 00:49:33,130
+بهذا الشكل هل يتورا بينهم مسافات ارتباط قوية كتير؟
+
+543
+00:49:33,130 --> 00:49:37,620
+هاي بس سطح الارتباطواضحة الفكرة؟ فالجزء اللي
+
+544
+00:49:37,620 --> 00:49:42,220
+branched بصير أعمل زي الكورة، الآن الكورات بحطها
+
+545
+00:49:42,220 --> 00:49:45,880
+بشكل تستقر فوق بعض، يعني أنا بقدر أحطها دولة تلاتة
+
+546
+00:49:45,880 --> 00:49:51,610
+فوق بعض ويثبتوا؟ لأليش؟ لأنه مافيش سطح التقاء كبير
+
+547
+00:49:51,610 --> 00:49:55,730
+بينهم ولذلك الـbranched alkanes they have lower
+
+548
+00:49:55,730 --> 00:49:59,170
+boiling points than the corresponding long chain
+
+549
+00:49:59,170 --> 00:50:03,210
+alkanes هذه مبادئ عامة بال physical properties
+
+550
+00:50:03,210 --> 00:50:06,090
+للالكنز وبهيك بننهي اليوم ان شاء الله
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/pdzlULxzAp0_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/pdzlULxzAp0_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..0bc2fc225acaaa5ba7d8b247a9640a6c2c15948f
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/pdzlULxzAp0_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4313, "start": 20.77, "end": 43.13, "text": "بسم الله الرحمن الرحيم المرة الماضية بدأنا معكم في الفصل الثاني بونوان ال alkanes and cycloalkanes ربما حكينا فكرة في البداية عن تصنيفات ال alkanes أو ال hydrocarbons ل saturated alkanes بقولنا هدولة نوعين اللي هم", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 47525, 10721, 8315, 20449, 24793, 8978, 27188, 36520, 6024, 104, 7649, 1829, 4724, 2407, 1863, 2407, 7649, 2423, 419, 5225, 279, 293, 38154, 752, 667, 12779, 12602, 3555, 15042, 11331, 4117, 1829, 8315, 6156, 4117, 25720, 8978, 29739, 28259, 10632, 18871, 6055, 9381, 22653, 5172, 9307, 2423, 419, 5225, 279, 34051, 2423, 15435, 6166, 33568, 5296, 25408, 419, 5225, 279, 4724, 39648, 8315, 8032, 3215, 12610, 3660, 8717, 45367, 9957, 13672, 1829, 8032, 2304], "avg_logprob": -0.16573034109694235, "compression_ratio": 1.7040816326530612, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 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1033.7, "text": "صار عندى من نفس البيوتين العادى كام مجموعة؟ تنتين واحدة بسميها butyl واحدة بسميها secondary butyl secondary اللى احنا شيلنا فيها الهيدروجين من carbon 2", "tokens": [9381, 9640, 43242, 7578, 9154, 8717, 36178, 2423, 21292, 35473, 9957, 18863, 18513, 7578, 9122, 10943, 3714, 7435, 2304, 2407, 27884, 22807, 6055, 29399, 9957, 36764, 24401, 3660, 4724, 38251, 1829, 11296, 457, 5088, 36764, 24401, 3660, 4724, 38251, 1829, 11296, 11396, 457, 5088, 11396, 13672, 7578, 1975, 5016, 8315, 13412, 26895, 8315, 8978, 11296, 2423, 3224, 25708, 2288, 29245, 9957, 9154, 5954, 568], "avg_logprob": -0.20252403846153846, "compression_ratio": 1.528301886792453, "no_speech_prob": 0.0, "words": [{"start": 1018.22, "end": 1018.76, "word": "صار", "probability": 0.65234375}, {"start": 1018.76, "end": 1019.64, "word": " عندى", "probability": 0.82666015625}, {"start": 1019.64, "end": 1019.9, "word": " من", "probability": 0.91455078125}, {"start": 1019.9, "end": 1020.38, "word": " نفس", 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{"start": 1050.93, "end": 1051.47, "word": " عادي", "probability": 0.9152018229166666}, {"start": 1051.47, "end": 1052.85, "word": " المتسلسل", "probability": 0.951904296875}, {"start": 1052.85, "end": 1053.53, "word": " فالـ", "probability": 0.81787109375}, {"start": 1053.53, "end": 1053.67, "word": " N", "probability": 0.8642578125}, {"start": 1053.67, "end": 1053.99, "word": " هذي", "probability": 0.6044921875}, {"start": 1053.99, "end": 1054.25, "word": " جاية", "probability": 0.8958333333333334}, {"start": 1054.25, "end": 1054.41, "word": " من", "probability": 0.9775390625}, {"start": 1054.41, "end": 1054.85, "word": " كلمة", "probability": 0.9866536458333334}, {"start": 1054.85, "end": 1055.59, "word": " إيش؟", "probability": 0.70220947265625}, {"start": 1055.59, "end": 1056.31, "word": " Normal", "probability": 0.6435546875}, {"start": 1056.31, "end": 1057.07, "word": " لـ", "probability": 0.378662109375}, {"start": 1057.07, "end": 1057.53, "word": " Butane", "probability": 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{"start": 1077.47, "end": 1078.93, "word": " ذرة", "probability": 0.81787109375}, {"start": 1078.93, "end": 1079.41, "word": " إيش", "probability": 0.8738606770833334}, {"start": 1079.41, "end": 1080.59, "word": " الهيدروجين", "probability": 0.8826497395833334}, {"start": 1080.59, "end": 1081.13, "word": " الآن", "probability": 0.5479736328125}, {"start": 1081.13, "end": 1081.27, "word": " لو", "probability": 0.96435546875}, {"start": 1081.27, "end": 1081.69, "word": " حطينا", "probability": 0.816162109375}, {"start": 1081.69, "end": 1081.91, "word": " هنا", "probability": 0.67626953125}, {"start": 1081.91, "end": 1082.27, "word": " كلور", "probability": 0.6287841796875}, {"start": 1082.27, "end": 1082.47, "word": " شو", "probability": 0.679443359375}, {"start": 1082.47, "end": 1082.83, "word": " هتسمي", "probability": 0.78253173828125}, {"start": 1082.83, "end": 1083.73, "word": " المركب؟", "probability": 0.8721923828125}], "temperature": 1.0}, {"id": 47, "seek": 110852, "start": 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هشيل الهيدروجينة؟ من هذه الأخيرة واضح؟ الآن إذا هاي تسع هيدروجينات زي بعض لو شيلت منهم هيدروجينة بطلّق مجموعة isobutyl طب لو شيلت هيدروجين من النص بطلّق مجموعة فيها ذرة الكاربون هذه متصلة بتلت مجموعات CH3 بنسميها tertiarybutyl", "tokens": [1211, 19452, 45164, 9122, 29399, 4724, 16254, 2423, 39184, 307, 78, 12, 78, 349, 304, 1594, 9154, 4032, 9957, 8032, 8592, 26895, 2423, 3224, 25708, 2288, 29245, 9957, 3660, 22807, 9154, 29538, 16247, 9778, 48923, 4032, 46958, 5016, 22807, 6024, 48506, 11933, 15730, 8032, 47302, 6055, 3794, 3615, 8032, 25708, 2288, 29245, 9957, 9307, 30767, 1829, 45030, 11242, 45164, 13412, 26895, 2655, 9154, 16095, 8032, 25708, 2288, 29245, 9957, 3660, 4724, 9566, 1211, 11703, 4587, 3714, 7435, 2304, 2407, 27884, 307, 996, 325, 5088, 23032, 3555, 45164, 13412, 26895, 2655, 8032, 25708, 2288, 29245, 9957, 9154, 28239, 9381, 4724, 9566, 1211, 11703, 4587, 3714, 7435, 2304, 2407, 27884, 8978, 11296, 29910, 25720, 33251, 9640, 3555, 11536, 29538, 44650, 36520, 3660, 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"probability": 0.9646484375}, {"start": 1358.27, "end": 1359.15, "word": " CH3", "probability": 0.96484375}, {"start": 1359.15, "end": 1361.29, "word": " بنسميها", "probability": 0.9158935546875}, {"start": 1361.29, "end": 1363.35, "word": " tertiarybutyl", "probability": 0.7918701171875}], "temperature": 1.0}, {"id": 59, "seek": 137289, "start": 1364.11, "end": 1372.89, "text": "Tertiarybutyl مرات بيكتبوا ترت اختصارا و مرات بيحطوا T يعني ممكن تلاقوا T", "tokens": [51, 911, 29104, 5955, 5088, 3714, 2288, 9307, 4724, 1829, 4117, 2655, 3555, 14407, 6055, 43500, 1975, 46456, 9381, 9640, 995, 4032, 3714, 2288, 9307, 4724, 1829, 5016, 9566, 14407, 314, 37495, 22653, 3714, 43020, 6055, 15040, 4587, 14407, 314], "avg_logprob": -0.2705792682926829, "compression_ratio": 1.202020202020202, "no_speech_prob": 0.0, "words": [{"start": 1364.11, "end": 1365.55, "word": "Tertiarybutyl", "probability": 0.5654296875}, {"start": 1365.55, "end": 1366.25, "word": " مرات", "probability": 0.73974609375}, {"start": 1366.25, "end": 1366.87, "word": " بيكتبوا", "probability": 0.8538411458333334}, {"start": 1366.87, "end": 1367.37, "word": " ترت", "probability": 0.58935546875}, {"start": 1367.37, "end": 1369.13, "word": " اختصارا", "probability": 0.92109375}, {"start": 1369.13, "end": 1369.21, "word": " و", "probability": 0.9169921875}, {"start": 1369.21, "end": 1369.51, "word": " مرات", "probability": 0.9010416666666666}, {"start": 1369.51, "end": 1369.99, "word": " بيحطوا", "probability": 0.79814453125}, {"start": 1369.99, "end": 1370.21, "word": " T", "probability": 0.5380859375}, {"start": 1370.21, "end": 1370.89, "word": " يعني", "probability": 0.859619140625}, {"start": 1370.89, "end": 1371.21, "word": " ممكن", "probability": 0.9736328125}, {"start": 1371.21, "end": 1372.25, "word": " تلاقوا", "probability": 0.8638916015625}, {"start": 1372.25, "end": 1372.89, "word": " T", "probability": 0.7119140625}], "temperature": 1.0}, {"id": 60, "seek": 139772, "start": 1374.5, "end": 1397.72, "text": "بيوتل أو تيرت بيوتل تيرتشار بيوتل في كل الأحوال لما نحتاج نشوف هذه الأشياء من ناحية alphabetical أي حرف اللي بنعتمده لأنه بعد شوية لما نسمي المراكبات يلزمنا الترتيب ال alphabetical لبيوتل حتى لو كنتي بتاعة بيوتل هي حرف إيش", "tokens": [3555, 1829, 35473, 1211, 34051, 6055, 13546, 2655, 4724, 1829, 35473, 1211, 6055, 13546, 2655, 8592, 9640, 4724, 1829, 35473, 1211, 8978, 28242, 16247, 5016, 2407, 6027, 5296, 15042, 8717, 33753, 26108, 8717, 8592, 38688, 29538, 16247, 8592, 1829, 16606, 9154, 8717, 39319, 10632, 23339, 804, 36632, 11331, 28480, 13672, 1829, 44945, 34268, 2304, 3215, 3224, 5296, 33456, 3224, 39182, 13412, 2407, 10632, 5296, 15042, 8717, 38251, 1829, 9673, 23557, 4117, 3555, 9307, 7251, 1211, 11622, 2304, 8315, 16712, 2288, 31371, 3555, 2423, 23339, 804, 5296, 21292, 35473, 1211, 11331, 49975, 45164, 9122, 29399, 1829, 39894, 995, 27884, 4724, 1829, 35473, 1211, 39896, 11331, 28480, 11933, 1829, 8592], "avg_logprob": -0.20541857688798817, "compression_ratio": 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"end": 1382.16, "word": " نشوف", "probability": 0.9606119791666666}, {"start": 1382.16, "end": 1382.64, "word": " هذه", "probability": 0.8740234375}, {"start": 1382.64, "end": 1383.26, "word": " الأشياء", "probability": 0.9921875}, {"start": 1383.26, "end": 1383.62, "word": " من", "probability": 0.98779296875}, {"start": 1383.62, "end": 1384.08, "word": " ناحية", "probability": 0.9835611979166666}, {"start": 1384.08, "end": 1385.16, "word": " alphabetical", "probability": 0.767578125}, {"start": 1385.16, "end": 1385.72, "word": " أي", "probability": 0.71826171875}, {"start": 1385.72, "end": 1386.08, "word": " حرف", "probability": 0.996337890625}, {"start": 1386.08, "end": 1386.26, "word": " اللي", "probability": 0.91357421875}, {"start": 1386.26, "end": 1387.34, "word": " بنعتمده", "probability": 0.9494140625}, {"start": 1387.34, "end": 1388.04, "word": " لأنه", "probability": 0.7615559895833334}, {"start": 1388.04, "end": 1388.2, "word": " بعد", "probability": 0.87841796875}, {"start": 1388.2, "end": 1388.48, "word": " شوية", "probability": 0.9475911458333334}, {"start": 1388.48, "end": 1388.68, "word": " لما", "probability": 0.974609375}, {"start": 1388.68, "end": 1389.04, "word": " نسمي", "probability": 0.9025065104166666}, {"start": 1389.04, "end": 1389.78, "word": " المراكبات", "probability": 0.848828125}, {"start": 1389.78, "end": 1391.98, "word": " يلزمنا", "probability": 0.87216796875}, {"start": 1391.98, "end": 1392.48, "word": " الترتيب", "probability": 0.9267578125}, {"start": 1392.48, "end": 1392.6, "word": " ال", "probability": 0.876953125}, {"start": 1392.6, "end": 1393.5, "word": " alphabetical", "probability": 0.92724609375}, {"start": 1393.5, "end": 1394.78, "word": " لبيوتل", "probability": 0.834228515625}, {"start": 1394.78, "end": 1395.66, "word": " حتى", "probability": 0.87451171875}, {"start": 1395.66, "end": 1395.84, "word": " لو", "probability": 0.99267578125}, {"start": 1395.84, "end": 1396.14, "word": " كنتي", "probability": 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1405.0, "word": " isobutyl", "probability": 0.72674560546875}, {"start": 1405.0, "end": 1405.58, "word": " حرف", "probability": 0.98681640625}, {"start": 1405.58, "end": 1407.4, "word": " I،", "probability": 0.616943359375}, {"start": 1407.4, "end": 1407.8, "word": " ال", "probability": 0.77392578125}, {"start": 1407.8, "end": 1408.8, "word": " isobutyl", "probability": 0.968994140625}, {"start": 1408.8, "end": 1409.18, "word": " حرف", "probability": 0.98974609375}, {"start": 1409.18, "end": 1409.62, "word": " I", "probability": 0.990234375}, {"start": 1409.62, "end": 1410.58, "word": " مش", "probability": 0.482421875}, {"start": 1410.58, "end": 1410.96, "word": " حرف", "probability": 0.84033203125}, {"start": 1410.96, "end": 1411.36, "word": " بيه", "probability": 0.8932291666666666}], "temperature": 1.0}, {"id": 62, "seek": 143860, "start": 1412.18, "end": 1438.6, "text": "واضح ال isobutyl لو قلتلكوا alphabetically ايش اول اشي باعتمدوا فيها I لكن tertiary butyl باهمل ال T وتعامل على انه حرف الأول B من ناحية alphabetical و لو حطينا هنا Chlor في شغلات مرات مش بحاجة لفهم بحاجة انكم تحفظوها زي هيك تمام يعني مش قصة tertiary butyl alphabetically", "tokens": [2407, 46958, 5016, 2423, 307, 996, 325, 5088, 45164, 12174, 1211, 2655, 23275, 14407, 23339, 984, 1975, 1829, 8592, 1975, 12610, 1975, 8592, 1829, 4724, 995, 34268, 2304, 3215, 14407, 8978, 11296, 286, 44381, 38726, 29104, 457, 5088, 4724, 995, 16095, 1211, 2423, 314, 34683, 3615, 10943, 1211, 15844, 16472, 3224, 11331, 28480, 16247, 12610, 363, 9154, 8717, 39319, 10632, 23339, 804, 4032, 45164, 11331, 9566, 1829, 8315, 34105, 761, 6746, 8978, 13412, 17082, 1211, 9307, 3714, 2288, 9307, 37893, 4724, 5016, 26108, 3660, 5296, 5172, 16095, 4724, 5016, 26108, 3660, 16472, 24793, 6055, 5016, 5172, 19913, 2407, 11296, 30767, 1829, 39896, 4117, 6055, 15042, 2304, 37495, 22653, 37893, 12174, 9381, 3660, 38726, 29104, 457, 5088, 23339, 984], "avg_logprob": -0.20824579331053406, "compression_ratio": 1.6374501992031874, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1412.18, "end": 1412.72, "word": "واضح", "probability": 0.9381510416666666}, {"start": 1412.72, "end": 1413.4, "word": " ال", "probability": 0.38037109375}, {"start": 1413.4, "end": 1414.44, "word": " isobutyl", "probability": 0.6898193359375}, {"start": 1414.44, "end": 1414.82, "word": " لو", "probability": 0.71533203125}, {"start": 1414.82, "end": 1415.34, "word": " قلتلكوا", "probability": 0.8015625}, {"start": 1415.34, "end": 1416.3, "word": " alphabetically", "probability": 0.888671875}, {"start": 1416.3, "end": 1416.52, "word": " ايش", "probability": 0.8338216145833334}, {"start": 1416.52, "end": 1416.8, "word": " اول", "probability": 0.860107421875}, {"start": 1416.8, "end": 1417.06, "word": " اشي", "probability": 0.8984375}, {"start": 1417.06, "end": 1417.68, "word": " باعتمدوا", "probability": 0.8527018229166666}, {"start": 1417.68, "end": 1418.1, "word": " فيها", "probability": 0.977783203125}, {"start": 1418.1, 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"word": " مش", "probability": 0.9873046875}, {"start": 1430.72, "end": 1431.26, "word": " بحاجة", "probability": 0.9935302734375}, {"start": 1431.26, "end": 1431.64, "word": " لفهم", "probability": 0.9163411458333334}, {"start": 1431.64, "end": 1432.08, "word": " بحاجة", "probability": 0.9334716796875}, {"start": 1432.08, "end": 1432.3, "word": " انكم", "probability": 0.546630859375}, {"start": 1432.3, "end": 1433.22, "word": " تحفظوها", "probability": 0.8865559895833334}, {"start": 1433.22, "end": 1433.52, "word": " زي", "probability": 0.94921875}, {"start": 1433.52, "end": 1434.04, "word": " هيك", "probability": 0.94970703125}, {"start": 1434.04, "end": 1435.24, "word": " تمام", "probability": 0.7560221354166666}, {"start": 1435.24, "end": 1435.58, "word": " يعني", "probability": 0.6561279296875}, {"start": 1435.58, "end": 1435.78, "word": " مش", "probability": 0.90283203125}, {"start": 1435.78, "end": 1436.18, "word": " قصة", "probability": 0.8986002604166666}, {"start": 1436.18, "end": 1436.92, "word": " tertiary", "probability": 0.90625}, {"start": 1436.92, "end": 1437.42, "word": " butyl", "probability": 0.91259765625}, {"start": 1437.42, "end": 1438.6, "word": " alphabetically", "probability": 0.9404296875}], "temperature": 1.0}, {"id": 63, "seek": 146818, "start": 1440.68, "end": 1468.18, "text": "B Isobutyl خلصنا واضح؟ مرات كتير في التسمية في ناس بصروا على ان بعض الأشياء بدهم يفهموها مش كل شيء في التسمية مش كل شيء في التسمية بيفهم يعني لما اجي اقول والله انت اسمك هدا ليش سموكي هدا خلاص هدا خلاص", "tokens": [33, 286, 539, 5955, 5088, 16490, 1211, 9381, 8315, 4032, 46958, 5016, 22807, 3714, 2288, 9307, 9122, 2655, 13546, 8978, 16712, 38251, 10632, 8978, 8717, 32277, 4724, 9381, 2288, 14407, 15844, 16472, 45030, 11242, 16247, 8592, 1829, 16606, 47525, 16095, 7251, 5172, 16095, 2407, 11296, 37893, 28242, 44049, 38207, 8978, 16712, 38251, 10632, 37893, 28242, 44049, 38207, 8978, 16712, 38251, 10632, 4724, 33911, 16095, 37495, 22653, 5296, 15042, 1975, 7435, 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بروبين؟", "tokens": [14407, 24401, 3660, 6055, 1829, 7435, 1829, 6055, 39648, 1829, 23032, 3555, 32239, 8592, 8608, 2304, 2407, 3224, 4724, 32887, 3555, 9957, 22807, 25961, 8608, 2304, 2407, 3224, 8717, 37746, 995, 28242, 9957, 12399, 32239, 8592, 8608, 2304, 2407, 3224, 4724, 32887, 3555, 9957, 22807], "avg_logprob": -0.21484374676061713, "compression_ratio": 1.5647058823529412, "no_speech_prob": 0.0, "words": [{"start": 1469.0, "end": 1469.46, "word": "واحدة", "probability": 0.7802734375}, {"start": 1469.46, "end": 1469.66, "word": " تيجي", "probability": 0.9635009765625}, {"start": 1469.66, "end": 1470.1, "word": " تقولي", "probability": 0.8821614583333334}, {"start": 1470.1, "end": 1470.52, "word": " طب", "probability": 0.785400390625}, {"start": 1470.52, "end": 1470.78, "word": " ليش", "probability": 0.962646484375}, {"start": 1470.78, "end": 1471.2, "word": " سموه", "probability": 0.9208984375}, {"start": 1471.2, "end": 1473.42, "word": " بروبين؟", "probability": 0.658251953125}, 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يختار السلسلة الأكثر تفرعا، واضح هذا الكلام؟ ممكن نجرب ما أعطيكم", "tokens": [12610, 8848, 23275, 13672, 1829, 47525, 3224, 7251, 8592, 2655, 17082, 1211, 8978, 16712, 38251, 10632, 47525, 3224, 7251, 30544, 9154, 2655, 3555, 3224, 14739, 3224, 6156, 3615, 15040, 5296, 7435, 10721, 5551, 9566, 12610, 8608, 1211, 3794, 37977, 4032, 9307, 10721, 4117, 3215, 14739, 3224, 19446, 41185, 8592, 32771, 13546, 11296, 12399, 45164, 5296, 7435, 10721, 2655, 11933, 29399, 9957, 44945, 36178, 41950, 12610, 12399, 47525, 3224, 7251, 46456, 9640, 16247, 4117, 49115, 6055, 5172, 2288, 3615, 995, 12399, 47525, 3224, 7251, 46456, 9640, 21136, 1211, 3794, 37977, 16247, 4117, 49115, 6055, 5172, 2288, 3615, 995, 12399, 4032, 46958, 5016, 23758, 2423, 28820, 10943, 22807, 3714, 43020, 8717, 7435, 25513, 19446, 5551, 3615, 9566, 1829, 24793], "avg_logprob": -0.14036016481912741, "compression_ratio": 1.9207920792079207, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2311.99, "end": 2312.69, 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ضعيفة", "tokens": [6027, 3224, 25708, 2288, 29245, 9957, 4724, 2407, 1863, 3215, 1863, 7435, 8978, 11296, 9673, 1829, 11703, 3224, 4724, 12610, 2288, 16070, 6027, 4117, 9957, 11622, 8717, 7649, 4724, 12610, 2288, 6156, 6027, 3555, 12610, 2288, 16070, 1863, 7649, 4724, 12610, 2288, 4724, 9778, 1211, 9566, 2407, 8592, 20449, 45030, 11242, 366, 1281, 1028, 39754, 638, 23032, 3555, 3615, 995, 9122, 11536, 14407, 25062, 2407, 3660, 13672, 1829, 3714, 29245, 23328, 3660, 8978, 16095, 48812, 3615, 33911, 3660], "avg_logprob": -0.33662974608095386, "compression_ratio": 1.5679012345679013, "no_speech_prob": 0.0, "words": [{"start": 2805.09, "end": 2806.01, "word": "الهيدروجين", "probability": 0.7965494791666666}, {"start": 2806.01, "end": 2806.51, "word": " بوندنج", "probability": 0.5445556640625}, {"start": 2806.51, "end": 2806.79, "word": " فيها", "probability": 0.633056640625}, {"start": 2806.79, "end": 2807.17, "word": " الميّه", "probability": 0.65655517578125}, {"start": 2807.17, "end": 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"probability": 0.87958984375}, {"start": 2977.5, "end": 2977.62, "word": " اللي", "probability": 0.5662841796875}, {"start": 2977.62, "end": 2978.14, "word": " branched", "probability": 0.727294921875}, {"start": 2978.14, "end": 2978.58, "word": " بصير", "probability": 0.7815755208333334}, {"start": 2978.58, "end": 2979.0, "word": " أعمل", "probability": 0.7941080729166666}, {"start": 2979.0, "end": 2979.28, "word": " زي", "probability": 0.96337890625}, {"start": 2979.28, "end": 2980.08, "word": " الكورة،", "probability": 0.8494873046875}, {"start": 2980.08, "end": 2980.54, "word": " الآن", "probability": 0.7017822265625}, {"start": 2980.54, "end": 2981.48, "word": " الكورات", "probability": 0.97412109375}, {"start": 2981.48, "end": 2982.22, "word": " بحطها", "probability": 0.971435546875}, {"start": 2982.22, "end": 2982.84, "word": " بشكل", "probability": 0.9215494791666666}, {"start": 2982.84, "end": 2983.64, "word": " تستقر", "probability": 0.8663330078125}, {"start": 2983.64, 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"temperature": 1.0}, {"id": 130, "seek": 300609, "start": 2989.13, "end": 3006.09, "text": "ليش؟ لأنه مافيش سطح التقاء كبير بينهم ولذلك الـbranched alkanes they have lower boiling points than the corresponding long chain alkanes هذه مبادئ عامة بال physical properties للالكنز وبهيك بننهي اليوم ان شاء الله", "tokens": [20292, 8592, 22807, 5296, 33456, 3224, 19446, 41185, 8592, 8608, 9566, 5016, 16712, 4587, 16606, 9122, 3555, 13546, 49374, 16095, 35525, 8848, 23275, 2423, 39184, 1443, 4778, 292, 419, 5225, 279, 436, 362, 3126, 16208, 2793, 813, 264, 11760, 938, 5021, 419, 5225, 279, 29538, 3714, 3555, 18513, 19986, 6225, 10943, 3660, 20666, 4001, 7221, 24976, 6027, 19452, 11622, 46599, 3224, 1829, 4117, 44945, 1863, 3224, 1829, 45595, 20498, 16472, 13412, 16606, 21984], "avg_logprob": -0.26520269062068014, "compression_ratio": 1.360730593607306, "no_speech_prob": 0.0, "words": [{"start": 2989.13, "end": 2989.59, "word": "ليش؟", "probability": 0.6493326822916666}, {"start": 2989.59, "end": 2989.77, "word": " لأنه", "probability": 0.7687174479166666}, {"start": 2989.77, "end": 2990.13, "word": " مافيش", "probability": 0.9306640625}, {"start": 2990.13, "end": 2990.55, "word": " سطح", "probability": 0.9645182291666666}, {"start": 2990.55, "end": 2991.13, "word": " التقاء", "probability": 0.7957356770833334}, {"start": 2991.13, "end": 2991.61, "word": " كبير", "probability": 0.9837239583333334}, {"start": 2991.61, "end": 2992.19, "word": " بينهم", "probability": 0.968994140625}, {"start": 2992.19, "end": 2993.21, "word": " ولذلك", "probability": 0.8274739583333334}, {"start": 2993.21, "end": 2994.25, "word": " الـbranched", "probability": 0.65712890625}, {"start": 2994.25, "end": 2994.83, "word": " alkanes", "probability": 0.655029296875}, {"start": 2994.83, "end": 2995.11, "word": " they", "probability": 0.1942138671875}, {"start": 2995.11, "end": 2995.37, "word": " have", "probability": 0.9599609375}, {"start": 2995.37, "end": 2995.73, "word": " lower", "probability": 0.84814453125}, {"start": 2995.73, "end": 2996.11, "word": " boiling", "probability": 0.9599609375}, {"start": 2996.11, "end": 2996.53, "word": " points", "probability": 0.85791015625}, {"start": 2996.53, "end": 2996.75, "word": " than", "probability": 0.935546875}, {"start": 2996.75, "end": 2996.95, "word": " the", "probability": 0.86474609375}, {"start": 2996.95, "end": 2997.79, "word": " corresponding", "probability": 0.67919921875}, {"start": 2997.79, "end": 2998.65, "word": " long", "probability": 0.456298828125}, {"start": 2998.65, "end": 2999.17, "word": " chain", "probability": 0.84375}, {"start": 2999.17, "end": 3000.07, "word": " alkanes", "probability": 0.8976236979166666}, {"start": 3000.07, "end": 3000.61, "word": " هذه", "probability": 0.6943359375}, {"start": 3000.61, "end": 3001.73, "word": " مبادئ", "probability": 0.951904296875}, {"start": 3001.73, "end": 3002.11, "word": " عامة", "probability": 0.9959309895833334}, {"start": 3002.11, "end": 3002.23, "word": " بال", "probability": 0.70556640625}, {"start": 3002.23, "end": 3002.63, "word": " physical", "probability": 0.463134765625}, {"start": 3002.63, "end": 3003.21, "word": " properties", "probability": 0.69189453125}, {"start": 3003.21, "end": 3004.15, "word": " للالكنز", "probability": 0.555908203125}, {"start": 3004.15, "end": 3004.93, "word": " وبهيك", "probability": 0.8045654296875}, {"start": 3004.93, "end": 3005.31, "word": " بننهي", "probability": 0.928466796875}, {"start": 3005.31, "end": 3005.59, "word": " اليوم", "probability": 0.968017578125}, {"start": 3005.59, "end": 3005.73, "word": " ان", "probability": 0.51904296875}, {"start": 3005.73, "end": 3005.99, "word": " شاء", "probability": 0.9736328125}, {"start": 3005.99, "end": 3006.09, "word": " الله", "probability": 0.9453125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 3006.89125, "duration_after_vad": 2900.3418749999923}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/pdzlULxzAp0_raw.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/pdzlULxzAp0_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..c8c4d934a7f4dc8383bcc7c8870547450df2cb4a
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/pdzlULxzAp0_raw.srt
@@ -0,0 +1,2212 @@
+1
+00:00:20,770 --> 00:00:26,070
+بسم الله الرحمن الرحيم المرة الماضية بدأنا معكم في
+
+2
+00:00:26,070 --> 00:00:30,810
+الفصل الثاني بونوان ال alkanes and cycloalkanes
+
+3
+00:00:30,810 --> 00:00:37,130
+ربما حكينا فكرة في البداية عن تصنيفات ال alkanes
+
+4
+00:00:37,130 --> 00:00:41,350
+أو ال hydrocarbons ل saturated alkanes بقولنا
+
+5
+00:00:41,350 --> 00:00:46,350
+هدولة نوعين اللي همالالكينز والسايكلوالكينز و
+
+6
+00:00:46,350 --> 00:00:50,110
+unsaturated hydrocarbons اللي منها المراكبات اللي
+
+7
+00:00:50,110 --> 00:00:52,470
+فيها double bond و triple bond في الالكينز
+
+8
+00:00:52,470 --> 00:00:59,290
+والالكاينز بدنا نتعرف على الالكينز وقلنا هذه سلاسل
+
+9
+00:00:59,290 --> 00:01:05,200
+وممكن أن تكون مراكباتمتفرعة وهذا يؤدي الى تكون عدد
+
+10
+00:01:05,200 --> 00:01:11,340
+كبير جدا من ال isomers او المتشكلات ال isomers زى
+
+11
+00:01:11,340 --> 00:01:16,780
+ما اتفقنا فى ال alkanes بتبدأ تظهر وقتاش لما بنصل
+
+12
+00:01:16,780 --> 00:01:20,080
+لاربع ذرات كربون يعنى لو عندنا ذرة كربون واحدة
+
+13
+00:01:20,080 --> 00:01:24,480
+عندنا مركب واحد فقط ميثين بعدين ايثين بروبين هذا
+
+14
+00:01:24,480 --> 00:01:28,900
+منه مركب واحد لكن لما ابدي اجى احط اربع ذرات كربون
+
+15
+00:01:28,900 --> 00:01:34,130
+ارتبهمصار في عنده احتمالين لترتيبهم اما ان يرتبوا
+
+16
+00:01:34,130 --> 00:01:39,850
+بشكل متسلسل chain structure و بيكون اسم المركب
+
+17
+00:01:39,850 --> 00:01:45,210
+بيوتين او بشكل branch و بيكون اسم المركب ايزو
+
+18
+00:01:45,210 --> 00:01:48,770
+بيوتين و اتكلمنا بعد هيك عن البنتين انه بيكون
+
+19
+00:01:48,770 --> 00:01:53,930
+تلاتة isomers و بعد ذلك اعطيناكم واجب انكوا تجربوا
+
+20
+00:01:53,930 --> 00:02:00,170
+انتوا تتعبوا و ترسموا الخمسةstructures of hexane
+
+21
+00:02:00,170 --> 00:02:06,010
+والمفروض يكون الأمر بالنسبة لكم مش صعب كثير انه
+
+22
+00:02:06,010 --> 00:02:10,830
+تجيبوا 6 ذرات كربون تجربوا ما لم تعملوا هذا الأمر
+
+23
+00:02:10,830 --> 00:02:14,230
+بالإيد و بالجلم لرصاص و بالورق و تتعبوا فيه كثير
+
+24
+00:02:14,230 --> 00:02:20,770
+مابفيدش ان انا اعمله بكل الأحوال هذه وجفنا
+
+25
+00:02:20,770 --> 00:02:26,630
+اخر شي عند ال structure ofميثين وقولنا ان الميثين
+
+26
+00:02:26,630 --> 00:02:32,290
+ماخد الـ tetrahedral structure اللي له أربعة أوجه
+
+27
+00:02:32,290 --> 00:02:38,390
+وهذا أفضل شئ نتعامل معه نرسمه بسهولة اننا نعمله
+
+28
+00:02:38,390 --> 00:02:41,810
+بالشكل اللي موجود بين اديكم تخيل انه عندنا مستويين
+
+29
+00:02:41,960 --> 00:02:48,200
+مستوى أفقي للأمام ومستوى متعامد عليه للخلف هذا
+
+30
+00:02:48,200 --> 00:02:51,960
+المستوى الأفقي للأمام بيكون فيه ذارتين هيدروجين في
+
+31
+00:02:51,960 --> 00:02:56,880
+زاوية 109.5 والمستوى الخلفي أيضا في ذارتين
+
+32
+00:02:56,880 --> 00:03:02,320
+هيدروجينبزاوية 109.5، الآن باقي الزاوية أيضًا 109
+
+33
+00:03:02,320 --> 00:03:05,940
+.5، يعني لو واحد .. لو واحدة بدأ تاخد بين هذه
+
+34
+00:03:05,940 --> 00:03:08,260
+الهيدروجين اللي في المستوى الأمامي و اللي في
+
+35
+00:03:08,260 --> 00:03:14,100
+المستوى الخلفي و انقيس الزاوية 109.5اللي اتوقفنا
+
+36
+00:03:14,100 --> 00:03:19,020
+عنده كيف يرسم هذا الشكل بالفراغ كيف يرسم هذا الشكل
+
+37
+00:03:19,020 --> 00:03:23,860
+بالفراغ قولنا أفضل شيء أنه نرسمه بهذه الطريقة
+
+38
+00:03:23,860 --> 00:03:29,920
+نستعمل ال wedges أو الأسافير بحيث أنه الأشياء اللي
+
+39
+00:03:29,920 --> 00:03:34,400
+للأمام عادة بنعملها ب solid wedge و الأشياء اللي
+
+40
+00:03:34,400 --> 00:03:39,360
+للخلف عادة بنعملها ب dashed wedgeواضح؟ وهذا اللي
+
+41
+00:03:39,360 --> 00:03:43,860
+موجود عندنا الان اذا احنا بندقيق شوية في هذا الشكل
+
+42
+00:03:43,860 --> 00:03:49,360
+هنلاحظ ان الوجه له رأس head و له base قاعدة
+
+43
+00:03:49,360 --> 00:03:56,250
+القاعدة اللي هي عريضة زي هذه و الرأساللي بيكون
+
+44
+00:03:56,250 --> 00:04:02,030
+رفيع هل يا ترى هناك معنى لما انا اجي ارسم مثلا هذا
+
+45
+00:04:02,030 --> 00:04:07,370
+solid wedge تكون القاعدة فيه على جهة الهيدروجين و
+
+46
+00:04:07,370 --> 00:04:11,650
+الرأس على جهة الكاربون لما اجي ارسم ورا ال dashed
+
+47
+00:04:11,650 --> 00:04:16,690
+wedge تكون القاعدة على جهة الكاربون و الرأس على
+
+48
+00:04:16,690 --> 00:04:22,210
+جهة الهيدروجين هذا الكلام بالتأكيد له معنى شو
+
+49
+00:04:22,210 --> 00:04:27,730
+معنى؟ هذا تعبير عنالرسم في الفراغ دائما احنا
+
+50
+00:04:27,730 --> 00:04:32,070
+متعودين .. دائما احنا متعودين ان الشغلة اللى بتكون
+
+51
+00:04:32,070 --> 00:04:37,590
+قريبة علينا كبيرة بتبين كل ما بعدت عننا بتبين ايش
+
+52
+00:04:37,590 --> 00:04:41,150
+صغيرة يعني الناس اللى بيشوفوا الطائرة في المطار
+
+53
+00:04:41,150 --> 00:04:46,710
+طيارة كبيرة بتاخد خمسمية راكب واضح؟ لما بتبعد كتير
+
+54
+00:04:46,710 --> 00:04:53,610
+في السماء بتشوفوا الطائرة نقطة فكل شيء قريب علينا
+
+55
+00:04:54,670 --> 00:05:00,010
+كبير كلما بقعد صغر حتى لو انتوا بترسموا شارع مثلا
+
+56
+00:05:00,010 --> 00:05:02,950
+متعودين انكوا تقولوا هاي الإنسان هنا اللي بترسم
+
+57
+00:05:02,950 --> 00:05:09,970
+الشارع يبدأ الشارع عريض و كل ما بيبعد بيصير إيش؟
+
+58
+00:05:10,790 --> 00:05:16,210
+يصغر الان هذه الأشياء أيضا تعبير عن هذا الأمر يعني
+
+59
+00:05:16,210 --> 00:05:20,590
+لو انا امسكت هذا الشكل زي هيك هاي اللي موجودين في
+
+60
+00:05:20,590 --> 00:05:25,670
+المستوى الأفقي الان ايش القريب عليكم ذرات
+
+61
+00:05:25,670 --> 00:05:31,710
+الهيدروجين و كل ما بتروحوا على الكاربون بتبتعدوا
+
+62
+00:05:32,390 --> 00:05:38,870
+واضح و لذلك الوجه لما رسمناه خلناه عريض من عند
+
+63
+00:05:38,870 --> 00:05:43,430
+الهيدروجين و كل ما راح الكربون بيبعد بيصير ماخد
+
+64
+00:05:43,430 --> 00:05:49,690
+ايش؟ رأس المثلث فلاحظوا قريب و بيبعد عشان هيك
+
+65
+00:05:49,690 --> 00:05:55,830
+رسمناه عريض و بيصغر لو اجيت على الهيدروجين اللي في
+
+66
+00:05:55,830 --> 00:06:01,480
+الخلفأيش القريب عليكم اكثر ال carbon ولا ال
+
+67
+00:06:01,480 --> 00:06:05,580
+hydrogen؟ ال carbon و كل ما بتروحوا باتجاه ال
+
+68
+00:06:05,580 --> 00:06:12,000
+hydrogen بتبعدوا و لذلك هذا قريب بيبتعد، اذا ال
+
+69
+00:06:12,000 --> 00:06:18,780
+wedge تبعه سيبدأ كبيرامن عند الكربون و يصغر فلو
+
+70
+00:06:18,780 --> 00:06:23,900
+رسمت هذا بشكل معاكس بتكونوا بتعملوا غلط وهذا بيصير
+
+71
+00:06:23,900 --> 00:06:28,120
+جزء لما بترسموا أشكال دائما الشيء القريب عليكم
+
+72
+00:06:28,120 --> 00:06:32,280
+اعملوا الوجه تبعه قاعدته باتجاهكم و كل ما بيبعد
+
+73
+00:06:32,280 --> 00:06:39,000
+بيصغر واضح هذه الفكرة فهذا أمر يجب ان ينتبه له شكل
+
+74
+00:06:39,000 --> 00:06:44,200
+الوجه اللي للأمام و اللي للخلف الان ابتيجي نقطة
+
+75
+00:06:44,200 --> 00:06:50,590
+كثير مهمةلما احنا اضطرنا اضطرارا نرسم الشكل بهذه
+
+76
+00:06:50,590 --> 00:06:55,830
+الطريقة ليش؟ لأنه في اللوح مافيش إمكانية لشيء
+
+77
+00:06:55,830 --> 00:07:00,490
+الفراغي يعني مافيش عندي إمكانية أطلع هدول للأمام و
+
+78
+00:07:00,490 --> 00:07:06,090
+أرجع هدول للخلف فهذه الرسمة غير حقيقية الآن لما
+
+79
+00:07:06,090 --> 00:07:10,310
+باجي بقولكوا بدي أقيس الزوايا مابتكونش تقيسوا
+
+80
+00:07:10,310 --> 00:07:15,560
+الزوايا على أساس الشكلاللي مبين عندكم تقيسوها على
+
+81
+00:07:15,560 --> 00:07:20,120
+أساس الشكل الفراغي اللي موجود في ذهنكم ولذلك لما
+
+82
+00:07:20,120 --> 00:07:25,420
+أقول الزاوية بين الهيدروجين والكاربون والهيدروجين
+
+83
+00:07:25,420 --> 00:07:36,470
+على الرسمة مبينة 180180 لكن هي حقيقة جديش 109.5
+
+84
+00:07:36,470 --> 00:07:40,990
+كذلك الحال لو جيت قلتلكوا بدي الزاوية بين
+
+85
+00:07:40,990 --> 00:07:46,430
+الهيدروجين والكاربون والهيدروجين الآن على الرسمة
+
+86
+00:07:47,810 --> 00:07:54,230
+الزاوية كانت 180 لكنها حقيقة 109.5 فلو كنت معلم
+
+87
+00:07:54,230 --> 00:07:59,870
+بالأزرق و قلت له اكتبوا الزاوية ستكتبوها 109.5 مش
+
+88
+00:07:59,870 --> 00:08:06,040
+180 مابناش نخلط هذه الغلطةلو تخيلنا القاعدة ايضا
+
+89
+00:08:06,040 --> 00:08:11,680
+لو انا اجيت قلتلكم بدي الزاوية بين هذه الهيدروجين
+
+90
+00:08:11,680 --> 00:08:15,440
+اللي في المستوى الأفقي وهذه الهيدروجين الخلفية
+
+91
+00:08:15,440 --> 00:08:22,980
+الان هدولة هنا انبينين تسعين لكن هم حقيقة مية
+
+92
+00:08:22,980 --> 00:08:28,000
+وتسعة و نص ايضا واضح؟
+
+93
+00:08:29,450 --> 00:08:35,470
+فيجب الانتباه لهذا الأمر أن هذا الشكل ليس في مستوى
+
+94
+00:08:35,470 --> 00:08:40,630
+واحد وانما شكل في الفراغ وعندما تحدد الزوايا تبعته
+
+95
+00:08:40,630 --> 00:08:44,790
+يجب أن تحدد من الذهن تبعكه اللي اتعلم ان جميع
+
+96
+00:08:44,790 --> 00:08:50,970
+زوايا الـ tetrahedral structure قيمتها 109.5 كل
+
+97
+00:08:50,970 --> 00:08:55,970
+ذرة بعيدة عن التانيةمن خلال الكربون بزاوية 109.5
+
+98
+00:08:55,970 --> 00:09:03,410
+لا في زاوية شكل الميثين 90 ولا في زاوية 180 جميع
+
+99
+00:09:03,410 --> 00:09:07,510
+زاوية هيدروجين كربون هيدروجين من أي جهة بتاخدوها
+
+100
+00:09:07,510 --> 00:09:15,430
+قيمتها 109.5 هذا
+
+101
+00:09:15,430 --> 00:09:22,950
+بالنسبة لشكل الميثينإذا رجعنا لهذه ال slide اللي
+
+102
+00:09:22,950 --> 00:09:26,150
+اتكلمنا فيها عن ال الكانز بالتفصيل المميل قلنا
+
+103
+00:09:26,150 --> 00:09:30,690
+عندنا ميثين إيثين بروبين لحد البيوتين صار في عندنا
+
+104
+00:09:30,690 --> 00:09:36,330
+كام مركب اتنين الآن هدول بنسميهم الكانز من ال
+
+105
+00:09:36,330 --> 00:09:41,350
+الكانز بنطلع شغلة بنقولها ال kilogram لو يا ترى
+
+106
+00:09:41,350 --> 00:09:45,730
+احنا في نيتنا أنه بدنا نعمل تفاعل لما بدنا نعمل
+
+107
+00:09:45,730 --> 00:09:51,350
+التفاعل أول شيء أول شيء بدنا نعملهإنه بدنا نشيل
+
+108
+00:09:51,350 --> 00:09:58,870
+ذرة هيدروجين مثلا عشان نحط مكانها ذرة كلور الآن
+
+109
+00:09:58,870 --> 00:10:02,990
+لما أنا بشيل هيدروجين من الألكان يعني بدل ما
+
+110
+00:10:02,990 --> 00:10:12,030
+الميثين مثلا CH4 شو بده يصير CH3 وفي مكان سترتبط
+
+111
+00:10:12,030 --> 00:10:15,670
+به الذرة الجديدة نفترض اللي هي ذرة الكلور ممكن
+
+112
+00:10:15,670 --> 00:10:21,400
+نتخيل أنه لونها أخضرالان الالكين ناقص الهيدروجين
+
+113
+00:10:21,400 --> 00:10:27,180
+بسميه الكل جروب دائما الالكين ناقص الهيدروجين الكل
+
+114
+00:10:27,180 --> 00:10:32,520
+جروب فمن الميثين بطول مجموعة بسميها ايش مثل يعني
+
+115
+00:10:32,520 --> 00:10:40,940
+بستبدل ال N ب Y L بدل مثل N بصير مثل جروب دائما كل
+
+116
+00:10:41,530 --> 00:10:46,570
+نهاية اسم او شغلة فيها ال YL فانا بحكي عن الكلجروب
+
+117
+00:10:46,570 --> 00:10:52,330
+يعني ال cane مخصوم منه ذرة هيدروجين واضح؟ الان
+
+118
+00:10:52,330 --> 00:10:57,450
+لاحظوا لو هذه الذرة اتيت اعمل مركب طبعا المثل
+
+119
+00:10:57,450 --> 00:11:02,730
+مجموعة لكن لا تكون مركب يعني انا لما اخص منها
+
+120
+00:11:02,730 --> 00:11:07,290
+هيدروجينمباشرة مكانها الهيدروجين شو هتيجي تحط
+
+121
+00:11:07,290 --> 00:11:12,550
+اكلور نفترض الان لو كونت هذا المركب و بدي اعطيه
+
+122
+00:11:12,550 --> 00:11:19,010
+اسم باجي بسأل هذه المجموعة شو اسمها مثل وفي عند
+
+123
+00:11:19,010 --> 00:11:24,910
+اكلور فبقول المركب مثل اكلورايدبصير في ال common
+
+124
+00:11:24,910 --> 00:11:29,510
+nomenclature يعني التسمية المشهورة انه انا لو هنا
+
+125
+00:11:29,510 --> 00:11:34,110
+شيلت hydrogen و افترض و حطيت chlorine ايش هاسم
+
+126
+00:11:34,110 --> 00:11:41,070
+المركب اللي عندى مثل chloride هذه التسميةبنقول
+
+127
+00:11:41,070 --> 00:11:44,890
+عنها احنا ايش common nomenclature، ايش يعني
+
+128
+00:11:44,890 --> 00:11:49,350
+common؟ تسمية مشهورة، مش تسمية حسب القواعد، هناخد
+
+129
+00:11:49,350 --> 00:11:52,890
+نوعين من التسمية، في تسمية بنسميها IUPAC
+
+130
+00:11:52,890 --> 00:11:56,820
+Nomenclatureالتسمية لحسب القواعد اللي بنتعلمها
+
+131
+00:11:56,820 --> 00:12:00,620
+الآن وفيكم ال nomenclature التسمية المشهورة الان
+
+132
+00:12:00,620 --> 00:12:05,620
+التسمية المشهورة في مثل هذه المراكبات كيف بتتم من
+
+133
+00:12:05,620 --> 00:12:11,140
+خلال ذكر اسم المجموعة و بعد هيك بذكر اسم الهالوجين
+
+134
+00:12:11,140 --> 00:12:15,480
+فمن ال مثل لما شيلت هيدروجين صارت مثل حطيت بدلها
+
+135
+00:12:15,480 --> 00:12:20,380
+كلوه بيصير المراكب مثل كلورايد لو حطيت بدلها بروم
+
+136
+00:12:21,110 --> 00:12:27,190
+مثل البروميد و هكذا واضح؟ الان بنفس المنطق لو اجيت
+
+137
+00:12:27,190 --> 00:12:32,770
+على الاثين كام هيدروجين في الاثين بالمجمل؟ ستة
+
+138
+00:12:32,770 --> 00:12:37,170
+لاحظوا الست ذرات هيدروجين اللي في الاثين كلهم زي
+
+139
+00:12:37,170 --> 00:12:40,990
+بعض متكافئات يعني لو شيلت اي واحدة منهم هعمل
+
+140
+00:12:40,990 --> 00:12:47,670
+مجموعة شو هسميها؟ اثل زي ما انا شيلت من الميثين من
+
+141
+00:12:47,670 --> 00:12:53,840
+الأربع المتكافئات هدولةهيدروجينة وسميت المجموعة
+
+142
+00:12:53,840 --> 00:12:58,860
+مثل بقدر انا من ال اثين ايضا اشيل هيدروجينة الست
+
+143
+00:12:58,860 --> 00:13:01,880
+هيدروجينات زي بعض اي واحدة بنشيلها بتعطينا نفس
+
+144
+00:13:01,880 --> 00:13:07,080
+المجموعة هنكون مجموعة اثل لو افترضنا هذه المجموعة
+
+145
+00:13:07,080 --> 00:13:10,740
+مكان الهيدروجين اللي شيلناها حطينا كلور شو هيصير
+
+146
+00:13:10,740 --> 00:13:18,440
+مثلا مركبة اثل كلورايد و هكذا طيب لو اجينا بعد هيك
+
+147
+00:13:18,440 --> 00:13:24,620
+للبروبينوقلنا من مركب البروبين بدنا نشيل هيدروجين
+
+148
+00:13:24,620 --> 00:13:32,000
+ونعمل مجموعة بروبين مثل مثل اثان اثل بروبين بروبين
+
+149
+00:13:32,000 --> 00:13:39,000
+بيوتين بيوتل هتلاحظوا انه هيبدأ يصير عندى مشكلة
+
+150
+00:13:39,000 --> 00:13:46,610
+صغيرة انهالبروبين في كام هيدروجين؟ تمانية هي تلاتة
+
+151
+00:13:46,610 --> 00:13:50,870
+و تلاتة زي بعض وفي هنا الهيدروجينتين اللي اتفقنا
+
+152
+00:13:50,870 --> 00:13:56,470
+انه اختصرناهم في الكتابة اذا شكله العام CH3 CH2
+
+153
+00:13:56,470 --> 00:14:02,830
+CH3 تمان هيدروجينات هذولة تمان هيدروجينات كام نوع؟
+
+154
+00:14:04,020 --> 00:14:07,900
+عبارة عن نوعين التلاتة هذول والتلاتة هذول اللي على
+
+155
+00:14:07,900 --> 00:14:12,400
+الطرف زي بعض وهذه اللي موجودين في النص زي بعض فال
+
+156
+00:14:12,400 --> 00:14:16,960
+تمان هيدروجينات تعون لبروبين نوعين ستة زي بعض
+
+157
+00:14:16,960 --> 00:14:21,800
+وتنتين زي بعض لو شيلت أي واحدة من هان او من هان
+
+158
+00:14:21,800 --> 00:14:26,640
+هعمل مجموعة ولو شيلت واحدة من هان هعمل مجموعة
+
+159
+00:14:26,640 --> 00:14:30,880
+ولذلك بتلاحظوا انه لما باجي بشيل هيدروجين من
+
+160
+00:14:30,880 --> 00:14:35,460
+البروبين بعمل مجموعتيناذا شيلت من الطرف وهي جاهز
+
+161
+00:14:35,460 --> 00:14:39,420
+انه يشبك من هنا من هنا خصمة الهيدروجين هذه معناه
+
+162
+00:14:39,420 --> 00:14:44,140
+الكلام هذا بسميها مجموعة البروبيل ولو بدي اشيل من
+
+163
+00:14:44,140 --> 00:14:50,220
+النص بدي تصير ايزو بروبيل فلاحظوا معي لو بعد هيك
+
+164
+00:14:50,220 --> 00:14:56,360
+اجينا نعمل مركب نضيف كلور ممكن ناس يقولوا حطلي
+
+165
+00:14:56,360 --> 00:15:02,420
+كلور هانأو محل الهيدروجين اللي شلتها في الحالة
+
+166
+00:15:02,420 --> 00:15:06,600
+الأولى شو هيصير اسم المُركّب؟ Isopropyl chloride
+
+167
+00:15:06,600 --> 00:15:11,240
+في الحالة التانية إيش هيصير اسم المُركّب؟
+
+168
+00:15:11,240 --> 00:15:13,020
+Isopropyl chloride
+
+169
+00:15:15,840 --> 00:15:20,340
+واضح؟ و لذلك بدكوا تكونوا منتبهين أن التلات
+
+170
+00:15:20,340 --> 00:15:27,720
+كربونات كم ألكين منهم؟ واحد .. كم ألكين؟ واحد اسمه
+
+171
+00:15:27,720 --> 00:15:33,900
+بروبيل .. كم ألكي لجروب؟ تنتين .. اسمهم بروبيل و
+
+172
+00:15:33,900 --> 00:15:38,660
+ايزو بروبيل .. واضح؟هذا الكلام أكيد بحاجة إلى
+
+173
+00:15:38,660 --> 00:15:44,120
+تدريب وحفظ بعد شوية بنجي على أربع ذرات كربون هنقول
+
+174
+00:15:44,120 --> 00:15:50,960
+الأربع ذرات كربون أساسا منهم كم مركب اتنين بيوتين
+
+175
+00:15:50,960 --> 00:15:57,500
+و ايزو بيوتين طب كم الكل جروب منهم؟ بدي أجي أطلع
+
+176
+00:15:57,500 --> 00:16:05,510
+هنا كم هيدروجين عندى؟في البيوتين العادى عشرة تلاتة
+
+177
+00:16:05,510 --> 00:16:10,950
+و اتنين و اتنين و تلاتة الان هدولة المختصرين لو
+
+178
+00:16:10,950 --> 00:16:18,270
+بيناهم بالاحمر وسألنا العشرة هيدروجين هدولة كام
+
+179
+00:16:18,270 --> 00:16:27,350
+نوع كام نوع هدول العشر هيدروجين نوعين كام نوع كداش
+
+180
+00:16:27,350 --> 00:16:34,450
+و كداشستة زي بعض اللي على الطرف والاربعة هدول زي
+
+181
+00:16:34,450 --> 00:16:38,410
+بعض يعني لو شيلت hydrogen من هان او هان او هان او
+
+182
+00:16:38,410 --> 00:16:44,130
+هدول نفس الاشي هيعطيني مجموعة اش اسمها الـbutyl
+
+183
+00:16:44,130 --> 00:16:48,190
+ولو شيلت اي واحدة من هدول الاربعة هادي او هادي او
+
+184
+00:16:48,190 --> 00:16:52,030
+هادي او هادي كأن بكون شيلت عن موقع اتنين يعني من
+
+185
+00:16:52,030 --> 00:16:55,490
+هان او من هان بشيل عن موقع واحد من هان او من هان
+
+186
+00:16:55,490 --> 00:17:02,320
+بشيل عن موقع اتنينصار عندى من نفس البيوتين العادى
+
+187
+00:17:02,320 --> 00:17:08,340
+كام مجموعة؟ تنتين واحدة بسميها butyl واحدة بسميها
+
+188
+00:17:08,340 --> 00:17:12,060
+secondary butyl secondary اللى احنا شيلنا فيها
+
+189
+00:17:12,060 --> 00:17:16,410
+الهيدروجين من carbon 2الـ Butyl اللي شيلنا فيها
+
+190
+00:17:16,410 --> 00:17:21,910
+الهيدروجين من Carbon-1 مرات كتيرة هتلاحظوا إضافة و
+
+191
+00:17:21,910 --> 00:17:26,270
+ممكن تقرؤوها في بعض الكتب أن هذا الـ Butane بيروح
+
+192
+00:17:26,270 --> 00:17:32,850
+و بيحطه قدام حرف الـ N معناه بيوتين عادي المتسلسل
+
+193
+00:17:32,850 --> 00:17:37,530
+فالـ N هذي جاية من كلمة إيش؟ Normal لـ Butane
+
+194
+00:17:37,530 --> 00:17:41,270
+العادي و المجموعة تبعته هتلاحظوا مرات بيحطوا
+
+195
+00:17:41,270 --> 00:17:46,390
+قدامها حرف الـ Nفإذا قرأنا بيوتين هو نفسه
+
+196
+00:17:46,390 --> 00:17:51,270
+الانبيوتين المتسلسل وإذا قرأنا المجموعة بيوتين هي
+
+197
+00:17:51,270 --> 00:17:55,770
+نفسها الانبيوتين يعني البيوتين العادية اللي من نمر
+
+198
+00:17:55,770 --> 00:18:01,690
+واحد منها شيلنا ذرة إيش الهيدروجين الآن لو حطينا
+
+199
+00:18:01,690 --> 00:18:06,300
+هنا كلور شو هتسمي المركب؟Butylic chloride طب لو
+
+200
+00:18:06,300 --> 00:18:11,440
+حطينا هنا secondary butylic chloride الان لو اجينا
+
+201
+00:18:11,440 --> 00:18:15,120
+على ال isomers التانى اللى من اربع كربونات اللى
+
+202
+00:18:15,120 --> 00:18:21,640
+اسمه ايش ايزو بيوتين و سألنا كام هيدروجين فيه اكيد
+
+203
+00:18:21,640 --> 00:18:27,900
+عشرة لأنه التنين C4H10 طيب اللى مبينين تسعة وين
+
+204
+00:18:27,900 --> 00:18:34,190
+العاشرةالمختصرة هنا عشان يكتمل الشكل الان هدول
+
+205
+00:18:34,190 --> 00:18:41,090
+العشر هيدروجينات كام نوع؟ إذا بتطلع عليهم ممتازة
+
+206
+00:18:41,090 --> 00:18:49,180
+نوعين التسعة هدول زي بعضوهذا الهيدروجين نوع تاني
+
+207
+00:18:49,180 --> 00:18:52,680
+لأن هذا على الطرف وهذا على الطرف وهذا على الطرف
+
+208
+00:18:52,680 --> 00:18:57,020
+وهذا جاء في قلب الجزء فهذه نوع و هذول التسعة زي
+
+209
+00:18:57,020 --> 00:19:01,440
+بعض بناء على ذلك لو شيلنا أي واحدة من هذول هنعمل
+
+210
+00:19:01,440 --> 00:19:09,160
+مجموعةماذا نسمي المجموعة؟ انظروا معي هنا CH3 CH
+
+211
+00:19:09,160 --> 00:19:12,920
+CH3 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+212
+00:19:12,920 --> 00:19:12,920
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+213
+00:19:12,920 --> 00:19:13,020
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+214
+00:19:13,020 --> 00:19:13,200
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+215
+00:19:13,200 --> 00:19:13,560
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+216
+00:19:13,560 --> 00:19:13,560
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+217
+00:19:13,560 --> 00:19:13,560
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+218
+00:19:13,560 --> 00:19:15,980
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+219
+00:19:15,980 --> 00:19:20,860
+CH2 CH2 CH2 CH2 CH2والعدد كله أربعة إذا هذه
+
+220
+00:19:20,860 --> 00:19:27,200
+المجموعة إيش اسمها Isobutyl هذه المجموعة اسمها
+
+221
+00:19:27,200 --> 00:19:30,680
+Isobutyl اللي شيلنا فيها هيدروجين سواء من هنا أو
+
+222
+00:19:30,680 --> 00:19:36,160
+من هنا أو من هنا هي Iso هذا الشكل بيعني Iso هذا
+
+223
+00:19:36,160 --> 00:19:40,120
+التفرع كاربون طالع منها مجموعتين مثل Iso لاحظوا
+
+224
+00:19:40,120 --> 00:19:46,290
+هنا كان عندكم تقريبا نفس الاشي انتبهوا معيcarbon
+
+225
+00:19:46,290 --> 00:19:50,190
+منها مجموعتين مثل شو قلنا ايزو العدد الكلي لل
+
+226
+00:19:50,190 --> 00:19:56,810
+carbons كم كان تلاتة ولذلك سمناها ايزو بروبل الان
+
+227
+00:19:56,810 --> 00:20:01,790
+carbon طالع منها مجموعتين مثل ايزو و العدد الكلي
+
+228
+00:20:01,790 --> 00:20:08,630
+اربعة اذا صارت ايزوبيوتل لو الان بدى اقولها واحدة
+
+229
+00:20:08,630 --> 00:20:13,050
+طيب ال ISO pentel مثلا او ال ISO hexel بتقدر
+
+230
+00:20:13,050 --> 00:20:21,410
+ترسمها اه ع طول بقول هي ال ISO CH3 CH3
+
+231
+00:20:21,410 --> 00:20:26,290
+CH3 الان هكذا صار عندى ISO لو قولت ISO pentel جداش
+
+232
+00:20:26,290 --> 00:20:33,220
+بدى يكون عندى خمسة خمسة اذا بدي كمان هنا CH2CH2 و
+
+233
+00:20:33,220 --> 00:20:37,100
+من هنا شيلت الهيدروجين خليني هادي مثلا لو حطيت
+
+234
+00:20:37,100 --> 00:20:41,720
+كلور هنا كل
+
+235
+00:20:41,720 --> 00:20:51,680
+المركب ايش حيصير ايزو اربعة خمسة بنتل اكلورايد لو
+
+236
+00:20:51,680 --> 00:20:59,960
+حطيت الكلور هنا ايزو بيتل اكلورايد واضح بهذا الشكل
+
+237
+00:20:59,960 --> 00:21:00,300
+بيكون
+
+238
+00:21:03,730 --> 00:21:08,510
+جزء ال ISO التلاتة هدول، الآن إذا بس صفيت عليهم
+
+239
+00:21:08,510 --> 00:21:13,470
+بقول ISO Propyl، زيدت Carbon؟ ISO Butyl، زيدت
+
+240
+00:21:13,470 --> 00:21:17,810
+Carbon؟ ISO Bentyl، الآن هنا بدكوا تنتبهوا، إذا
+
+241
+00:21:17,810 --> 00:21:23,250
+كان عندي شئ بينتهي بالنهاية YL، بحكي عن مجموعة،
+
+242
+00:21:23,250 --> 00:21:28,110
+إذا كان عندي شئ بينتهي بالنهاية N؟بحكي عن ال cane
+
+243
+00:21:28,110 --> 00:21:34,110
+يعني مثلا لو قلنا لطالبة بدنا رسمة ال ISO أكتين
+
+244
+00:21:34,110 --> 00:21:42,950
+اتخيلوا أجاكوا في الامتحان بدي ISO أكتين بتغلبش
+
+245
+00:21:42,950 --> 00:21:49,970
+مباشرة ال ISO كيف شكلها CH3 CH3
+
+246
+00:21:50,800 --> 00:21:56,600
+الان هى صار عندى جزء ال ISO بدي اكمل ل ألكين كم
+
+247
+00:21:56,600 --> 00:22:01,280
+carbon بدى يصير المجموع الكله تمانية اذا هى تلاتة
+
+248
+00:22:01,280 --> 00:22:09,160
+اربعة خمسة ستة سبعة تمانية وهنا بكتب ايش CH3 مش
+
+249
+00:22:09,160 --> 00:22:15,190
+شايل ولا هيدروجينه منه ليش لأنه نهاية N الكينلكن
+
+250
+00:22:15,190 --> 00:22:19,130
+لو كنت بدي الـ iso-octal group من وين هشيل
+
+251
+00:22:19,130 --> 00:22:25,890
+الهيدروجينة؟ من هذه الأخيرة واضح؟ الآن إذا هاي تسع
+
+252
+00:22:25,890 --> 00:22:28,410
+هيدروجينات زي بعض لو شيلت منهم هيدروجينة بطلّق
+
+253
+00:22:28,410 --> 00:22:33,370
+مجموعة isobutyl طب لو شيلت هيدروجين من النص بطلّق
+
+254
+00:22:33,370 --> 00:22:38,270
+مجموعة فيها ذرة الكاربون هذه متصلة بتلت مجموعات
+
+255
+00:22:38,270 --> 00:22:46,250
+CH3 بنسميها tertiarybutylTertiarybutyl مرات
+
+256
+00:22:46,250 --> 00:22:51,210
+بيكتبوا ترت اختصارا و مرات بيحطوا T يعني ممكن
+
+257
+00:22:51,210 --> 00:22:59,700
+تلاقوا Tبيوتل أو تيرت بيوتل تيرتشار بيوتل في كل
+
+258
+00:22:59,700 --> 00:23:04,080
+الأحوال لما نحتاج نشوف هذه الأشياء من ناحية
+
+259
+00:23:04,080 --> 00:23:08,680
+alphabetical أي حرف اللي بنعتمده لأنه بعد شوية لما
+
+260
+00:23:08,680 --> 00:23:13,500
+نسمي المراكبات يلزمنا الترتيب ال alphabetical
+
+261
+00:23:13,500 --> 00:23:19,200
+لبيوتل حتى لو كنتي بتاعة بيوتل هي حرف إيشالـ
+
+262
+00:23:19,200 --> 00:23:23,400
+secondary butyl حرف بيه، ال tertiary butyl حرف
+
+263
+00:23:23,400 --> 00:23:30,960
+بيه، ال isobutyl حرف I، ال isobutyl حرف I مش حرف
+
+264
+00:23:30,960 --> 00:23:36,520
+بيهواضح ال isobutyl لو قلتلكوا alphabetically ايش
+
+265
+00:23:36,520 --> 00:23:40,760
+اول اشي باعتمدوا فيها I لكن tertiary butyl باهمل
+
+266
+00:23:40,760 --> 00:23:45,340
+ال T وتعامل على انه حرف الأول B من ناحية
+
+267
+00:23:45,340 --> 00:23:50,720
+alphabetical و لو حطينا هنا Chlor في شغلات مرات مش
+
+268
+00:23:50,720 --> 00:23:55,780
+بحاجة لفهم بحاجة انكم تحفظوها زي هيك تمام يعني مش
+
+269
+00:23:55,780 --> 00:23:58,600
+قصة tertiary butyl alphabetically
+
+270
+00:24:00,680 --> 00:24:09,180
+B Isobutyl خلصنا واضح؟
+
+271
+00:24:09,180 --> 00:24:13,220
+مرات كتير في التسمية في ناس بصروا على ان بعض
+
+272
+00:24:13,220 --> 00:24:17,180
+الأشياء بدهم يفهموها مش كل شيء في التسمية مش كل
+
+273
+00:24:17,180 --> 00:24:22,020
+شيء في التسمية بيفهم يعني لما اجي اقول والله انت
+
+274
+00:24:22,020 --> 00:24:29,660
+اسمك هدا ليش سموكي هدا خلاص هدا خلاصواحدة تيجي
+
+275
+00:24:29,660 --> 00:24:36,640
+تقولي طب ليش سموه بروبين؟ كان سموه نوبا كلين، ليش
+
+276
+00:24:36,640 --> 00:24:43,120
+سموه بروبين؟مش كل شيء في التسمية بالذات أحيانا
+
+277
+00:24:43,120 --> 00:24:46,900
+بتلاقوا إله منطق وقاعدة زي ما أنتوا أهلكوا سموكم
+
+278
+00:24:46,900 --> 00:24:52,280
+واضح؟ زي ما أهلكوا سموكم كان في شيء معين خلهم
+
+279
+00:24:52,280 --> 00:24:58,620
+يسموا مركب معين بنزين كان في شيء معين حادث صديق
+
+280
+00:24:58,620 --> 00:25:04,780
+اللي بيرجع لتاريخ العلوم أحيانا ممكن بلحظة من
+
+281
+00:25:04,780 --> 00:25:11,700
+اللحظات يلاقي هذا الأصلواللي بيرجع لتاريخ الأسماء
+
+282
+00:25:11,700 --> 00:25:16,280
+اللي بيرجع لتاريخ الأسماء ممكن يلاقي أصل لأسماءكم
+
+283
+00:25:16,280 --> 00:25:22,460
+حتى لو أنتم مش عارفينه يعني ممكن لمن ولدتوا كان
+
+284
+00:25:22,460 --> 00:25:26,860
+متوفي عامة إلكم اسمها هودا إكراما إليها سموكوا
+
+285
+00:25:26,860 --> 00:25:30,940
+هودا الآن أنا بالنسبة إيه هذه المعلومة؟ مابعرفاش
+
+286
+00:25:30,940 --> 00:25:35,220
+ولذلك خدوا تسمية العناصر مرة بتلاقي العنصر بيقوله
+
+287
+00:25:35,220 --> 00:25:41,090
+مسمى على اسم مدينةمر على اسم بني آدم اللي اكتشفه،
+
+288
+00:25:41,090 --> 00:25:46,550
+مر على اسم كذا، فأصل الاسم قد لا نعرفه، قد يكون له
+
+289
+00:25:46,550 --> 00:25:52,930
+أصل، لكن احنا ايش؟ ما بنعرفوش، الأن بالنسبة لنا
+
+290
+00:25:52,930 --> 00:25:58,990
+هذه سيارة مرسيدس، اسم، لكن يا تورا لو أعطيتكوا
+
+291
+00:25:58,990 --> 00:26:02,170
+واجب، ليش سموا ال مرسيدس مرسيدس؟
+
+292
+00:26:05,190 --> 00:26:10,310
+فتشوا عليه و هتقولي الجواب المرة الجاية هتلاحظوا
+
+293
+00:26:10,310 --> 00:26:15,530
+إنه إله اسم ومسمى على اسم واحدة وكذا إله أصل بس مش
+
+294
+00:26:15,530 --> 00:26:18,150
+كتير بهمن الأصل في لحظة من لحظات بلاش نضيع وقت
+
+295
+00:26:18,150 --> 00:26:24,610
+كتير الآن هذه المجموعات يجب أن تتدربوا عليها يجب
+
+296
+00:26:24,610 --> 00:26:29,810
+أنكم تحفظوها بشكل جيد هذا الكلام كيف بيجي بالتدريب
+
+297
+00:26:29,810 --> 00:26:33,490
+كيف بيجي بالتدريب الآن
+
+298
+00:26:34,940 --> 00:26:39,940
+بعد ما أخدنا ال الكانز البسيطة و ال alkyl groups
+
+299
+00:26:39,940 --> 00:26:45,120
+البسيطة بدنا ناخد تسمية ال الكانز بال IUPAC system
+
+300
+00:26:45,120 --> 00:26:50,360
+حتى لو كبرت و صارت متفرعة واضح؟ يعني تسمية ال
+
+301
+00:26:50,360 --> 00:26:54,340
+الكانز الكبيرة اللي مامرتش علينا بال IUPAC system
+
+302
+00:26:54,730 --> 00:27:00,050
+ال ايوبك سيستم بيعتمد على ان نبحث عن اطول سلسلة
+
+303
+00:27:00,050 --> 00:27:05,330
+كربونية و اسم عليها يعني لو اطول سلسلة تلاتة نهاية
+
+304
+00:27:05,330 --> 00:27:11,110
+الاسم عندى ابروبين لو اربعة بيوتين تمانية اكتيل
+
+305
+00:27:12,590 --> 00:27:17,830
+فالشيء الأول بيقولنا choose the largest continuous
+
+306
+00:27:17,830 --> 00:27:23,090
+chain الان رجاء ماحدش يفهم السلسلة أن انتوا
+
+307
+00:27:23,090 --> 00:27:28,550
+بتكونوا تشوفوها مرسومة عدل بشكل أفقي أو بشكل عمودي
+
+308
+00:27:28,550 --> 00:27:33,350
+هذا الشيء ليس له معنى أنها تكون أفقي أو عمودي أو
+
+309
+00:27:33,350 --> 00:27:38,740
+مائلة معنى سلسلةذرات كربون ورا بعض بأي طريقة انا
+
+310
+00:27:38,740 --> 00:27:43,180
+ارسمهم هذا الكلام لا معنى له كله ممكن يعني لو بدأ
+
+311
+00:27:43,180 --> 00:27:48,920
+احكي مثلا عن خمسة لو بدأ احكي عن خمسة هذه سلسلة من
+
+312
+00:27:48,920 --> 00:27:59,380
+خمسة تمام وهذه سلسلة من خمسة وممكن ناخد كمان هذه
+
+313
+00:27:59,380 --> 00:28:05,360
+بهذا الشكلسلسلة من الخمسة و ممكن نرسمها بطريقة
+
+314
+00:28:05,360 --> 00:28:12,440
+تانيةسلسلة من خمسة فمعنى سلسلة ذرات متتالية وليس
+
+315
+00:28:12,440 --> 00:28:15,740
+الطريقة المرسومة بعض الناس بيقول سلسلة يعني بيشوفه
+
+316
+00:28:15,740 --> 00:28:21,800
+هيك حسب نظره أفقي أو عمودي لأ لأ معنى سلسلة كام
+
+317
+00:28:21,800 --> 00:28:25,360
+ذرة كربون متتالية فاهمنا إيش معنى سلسلة فلو قولت
+
+318
+00:28:25,360 --> 00:28:29,220
+هنا أما أطول سلسلة واحد اتنين تلاتة أربعة خمسة
+
+319
+00:28:29,220 --> 00:28:33,060
+واحد اتنين تلاتة أربعة خمسة واحد اتنين تلاتة أربعة
+
+320
+00:28:33,060 --> 00:28:36,580
+خمسة واحد اتنين تلاتة أربعة خمسة ابلاحظين مرسومين
+
+321
+00:28:36,580 --> 00:28:43,470
+بطرقمختلفة لكن بالنسبة لي معنى أطول سلسلة أطول عدد
+
+322
+00:28:43,470 --> 00:28:47,870
+متتالي من ذرات الكربون كيف يرتسموا مش مشكلة واضح و
+
+323
+00:28:47,870 --> 00:28:52,010
+لذلك بعد شوية اشوفوا مثلا هذا المركب هين اتكلمت عن
+
+324
+00:28:52,010 --> 00:28:58,190
+سلسلة اللي ماعطيها اللون الأحمر ولو مش مبينة بشكل
+
+325
+00:28:58,190 --> 00:29:04,370
+مستقيم بالنسبة لكم هذا شيء ما لهش معنى الآنحسب
+
+326
+00:29:04,370 --> 00:29:08,130
+أطول سلسلة بيكون اسم المُركّب لو كان عندنا تلاتة
+
+327
+00:29:08,130 --> 00:29:13,050
+نهاية المُركّب ابرو بين خمسة بينتين و هكذا طيب لما
+
+328
+00:29:13,050 --> 00:29:17,370
+بيصير في عندي سلسلة هذه السلسلة أكيد بيتفرع منها
+
+329
+00:29:17,370 --> 00:29:23,010
+شغلات هذه بسميها أنا الأشياء المتفرعة من السلسلة
+
+330
+00:29:23,010 --> 00:29:26,870
+اللي طالعة من أطول سلسلة carbon بقول عنها
+
+331
+00:29:26,870 --> 00:29:31,980
+substituent هذه كلمة هتصير اتمر عليكمكثير
+
+332
+00:29:31,980 --> 00:29:38,040
+Substituents اللي هي الأشياء المبدلة الان كام
+
+333
+00:29:38,040 --> 00:29:43,460
+Substituents على هذا المركب متفرع منه؟ اتنين هدولة
+
+334
+00:29:43,460 --> 00:29:48,920
+ال Substituents لازم انا اوضحهم او اوضح من اي نقطة
+
+335
+00:29:48,920 --> 00:29:53,060
+تفرعوا من اي مكان تفرعوا طب لما هذي بدي اعطيها اسم
+
+336
+00:29:53,060 --> 00:29:57,820
+هعطيها Chloro لما هذي بدي اعطيها اسم هعطيها Abromo
+
+337
+00:29:57,820 --> 00:30:02,830
+بعدين بدي اقول لك Chloro من وين اتفرعت؟من أي موقع
+
+338
+00:30:02,830 --> 00:30:08,690
+لبرومو من وين اتفرعت اذا بالزمن ترقيم لهالسلسلة
+
+339
+00:30:08,690 --> 00:30:12,950
+طالما بحكي سلسلة إذا عندي احتمالين ترقيم ممكن أبدأ
+
+340
+00:30:12,950 --> 00:30:17,770
+من هنا واحد اتنين تلاتة أربعة خمسة أو من هنا واحد
+
+341
+00:30:17,770 --> 00:30:23,130
+اتنين تلاتة أربعة خمسة من أي جهة بدي أبدأ الجهة
+
+342
+00:30:23,130 --> 00:30:26,910
+اللي بتخلي ال substituents أرقامهم أقل ما يمكن
+
+343
+00:30:26,910 --> 00:30:30,230
+يعني لو بدأت من هنا زي ما احنا عاملين ال chlorine
+
+344
+00:30:30,230 --> 00:30:34,280
+على اتنين و ال brom على تلاتة اتنين و تلاتةخمسة لو
+
+345
+00:30:34,280 --> 00:30:38,600
+بدأت منها ان واحد اتنين تلاتة اربعة صارت هذه على
+
+346
+00:30:38,600 --> 00:30:43,840
+تلاتة وهذه على اربعة تلاتة واربعة اذا ماهو اقل
+
+347
+00:30:43,840 --> 00:30:50,900
+ترقيم هذا ولذلك لما بدي ارقم دائما عند احتمالين
+
+348
+00:30:50,900 --> 00:30:56,220
+الاحتمال اللي بدي اختارهالـ lowest possible
+
+349
+00:30:56,220 --> 00:31:00,780
+numbering أقل احتمال بيعطي الـ substituents أرقام
+
+350
+00:31:00,780 --> 00:31:05,640
+طب اعرفنا الأرقام و اعرفنا الآن انه صار عندنا على
+
+351
+00:31:05,640 --> 00:31:13,800
+موقع اتنين ذرة اكلورو مظبوط ولا لأ اكلورو وع موقع
+
+352
+00:31:13,800 --> 00:31:20,410
+تلاتة ذرة ابروموبدي اكتب الاسم كامل الاسم عادة
+
+353
+00:31:20,410 --> 00:31:26,130
+بنبدأ في كتابته من الخلف للامام اول كلمة في الاسم
+
+354
+00:31:26,130 --> 00:31:30,970
+انه عندي خمسة اذا مركبه بنتين يعني اول شي بدي ابدأ
+
+355
+00:31:30,970 --> 00:31:36,070
+اكتبه بنتين هذا البنتين الان بيحمل برومو و كلورو
+
+356
+00:31:36,070 --> 00:31:41,630
+مين بدي اذكره في الاول ال alphabetical اللي بيظهر
+
+357
+00:31:41,630 --> 00:31:47,510
+اولا مين بيجي قبل ال B ولا ال Cالـ B A B C D
+
+358
+00:31:47,510 --> 00:31:51,090
+شوفتوا قبل شوية ليش أنا نبهت كل ال alphabetical في
+
+359
+00:31:51,090 --> 00:31:58,010
+المجموعات أه إذا هذا هيكون three bromo two
+
+360
+00:31:58,010 --> 00:32:03,430
+chlorobentain واضح؟ لأن أنا عندي كام substituent؟
+
+361
+00:32:03,430 --> 00:32:10,670
+هذه و هذه كيف بأذكرهم؟list substituents
+
+362
+00:32:10,670 --> 00:32:15,830
+alphabetically أذكرهم alphabetically أذكر ال B قبل
+
+363
+00:32:15,830 --> 00:32:22,650
+ال C قبل ال D قبل ال E و هكذا طبعا هنا اجتمل الاسم
+
+364
+00:32:22,650 --> 00:32:26,930
+بضيف معلومة أنه لو من مجموعة معينة كان في عندي
+
+365
+00:32:26,930 --> 00:32:33,400
+تنتينبدي أستعمل لمضاي، لو كان في عندي تلاتة ا try،
+
+366
+00:32:33,400 --> 00:32:38,700
+لو عندي أربعة تترى، و هكذا، واضح؟ انشوف أمثلة
+
+367
+00:32:38,700 --> 00:32:46,820
+إضافية، انشوفأمثلة إضافية مثلا هاي مثال أصعب شغلة
+
+368
+00:32:46,820 --> 00:32:52,220
+أنه فعلا طول أطول سلسلة يعني لو إجيت بدي أطول
+
+369
+00:32:52,220 --> 00:32:57,460
+سلسلة ممكن أعد واحد اتنين تلاتة واحد اتنين تلاتة
+
+370
+00:32:57,460 --> 00:33:03,340
+أربعة خمسة واحد اتنين تلاتة أربعة خمسة احتمالات
+
+371
+00:33:03,340 --> 00:33:07,780
+كتيرة بدي أضلني أجرب لحد ما فعلا ألاقي أطول سلسلة
+
+372
+00:33:07,780 --> 00:33:14,930
+واحد اتنين تلاتة أربعة خمسة ستة سبعةإذا مركّب إيش؟
+
+373
+00:33:14,930 --> 00:33:15,730
+هبتين
+
+374
+00:33:23,230 --> 00:33:37,450
+مثل مثل مثل مثل مثل مثل مثل مثل
+
+375
+00:33:46,950 --> 00:33:51,550
+إذا من هنا لازم أرقم فالمثلز اللي عندي وين موجودين
+
+376
+00:33:51,550 --> 00:33:57,350
+على اتنين واربعة هيصير مركبة two four dimethyl
+
+377
+00:33:57,350 --> 00:34:02,850
+heptane two four dimethyl heptane الان هاي مركب
+
+378
+00:34:02,850 --> 00:34:10,610
+تاني بتجارب كتير هتكتشف ان هاي أطول سلسلة سبعة ايش
+
+379
+00:34:10,610 --> 00:34:11,750
+بيتفرع منها
+
+380
+00:34:14,510 --> 00:34:24,070
+هذه المجموعة اللي مرت علينا ايزو بروبل و مثل الان
+
+381
+00:34:24,070 --> 00:34:30,410
+ايزو بروبل حرف I و المثل حرف M و المركب هبتين و I
+
+382
+00:34:30,410 --> 00:34:36,870
+قبل ال M اذا حيصير اسم المركب for aizobrobel انها
+
+383
+00:34:36,870 --> 00:34:38,530
+موجودة على موقع اربعة
+
+384
+00:34:41,630 --> 00:34:46,510
+لاحظوا في كل التسمية لو تطبعوا على الكمبيوتر في أي
+
+385
+00:34:46,510 --> 00:34:54,490
+فراغولا فراغ دائما قبل الرقم وبعد الرقم بتحطه شرطة
+
+386
+00:34:54,490 --> 00:34:58,330
+ما عدا إذا كنا بنحط في أول الإسم بتكون الشرطة فقط
+
+387
+00:34:58,330 --> 00:35:04,170
+بعد الرقم بدون أي فراغات يعني هذا كله متصل بعض
+
+388
+00:35:04,170 --> 00:35:08,830
+كتابة من هنا لهنا مافيش عندي فراغات لو بكتب اسم
+
+389
+00:35:08,830 --> 00:35:14,550
+هذا المركب على الكمبيوتر قبل الرقم شرطة وبعده شرطة
+
+390
+00:35:14,550 --> 00:35:21,380
+ما لم يكن الرقمفي الأول فبس بيكون فيه بعده شرطة
+
+391
+00:35:22,430 --> 00:35:27,630
+الان في عندكم امثلة كتير بإمكانكوا تتدربوا عليها
+
+392
+00:35:27,630 --> 00:35:31,250
+ماعطيكوا انا في الواجبات بالذات في الامتحانات
+
+393
+00:35:31,250 --> 00:35:35,270
+السابقة اللي موجودة عندكم كل امتحان بتلاقي عليه
+
+394
+00:35:35,270 --> 00:35:40,310
+اربع خمس مركبات كيف تسموهم مالم تتدربوا على حفظ
+
+395
+00:35:40,310 --> 00:35:44,890
+أسماء ال الkins على حفظ المجموعات على كيف تسموا
+
+396
+00:35:44,890 --> 00:35:48,970
+مركب مش هتقدروا تطبقوا يعني لازم لو واحد كنتوا
+
+397
+00:35:48,970 --> 00:35:50,210
+تدرسوا و تتدربوا أكثر
+
+398
+00:35:54,510 --> 00:35:58,250
+لأ لأ اعتمدي على اللي احنا بنشرحه بشكل اكبر
+
+399
+00:35:58,250 --> 00:36:02,370
+واعتمدي على الامتحانات الكتيرة اللي موجودة عندكم
+
+400
+00:36:02,370 --> 00:36:08,470
+بتعطيكي اسئلة وافية في الموضوع الآن بنيجي لنقطة
+
+401
+00:36:08,470 --> 00:36:14,350
+خاصة صغيرة بنضيفها في هذا الموضوع أحيانا بنيجي
+
+402
+00:36:14,350 --> 00:36:20,410
+نبحث عن أطول سلسلة بنلاحظ أنه بيطلع عندنا احتمالين
+
+403
+00:36:20,410 --> 00:36:27,520
+مش احتمال واحدمثلا هذا المركب هو نفسه هذا المركب
+
+404
+00:36:27,520 --> 00:36:31,440
+تماما لو بتتطلع عليه يعني احنا رسمنا المركب هذا
+
+405
+00:36:31,440 --> 00:36:36,460
+عملنا له نسخ و لاصق هنا لما نيجي نبحث عن أطول
+
+406
+00:36:36,460 --> 00:36:41,680
+سلسلة عدنا كتير هيقولنا واحد اتنين تلاتة اربعة
+
+407
+00:36:41,680 --> 00:36:47,800
+خمسة ستة سبعة اجت طالبة تانية عدت من هنا واحد
+
+408
+00:36:47,800 --> 00:36:55,600
+اتنين تلاتة اربعة خمسة ستة سبعةطب يا تورا بدي
+
+409
+00:36:55,600 --> 00:37:00,820
+أختار هذه السلسلة و لا بدي أختار هذه السلسلة طلع
+
+410
+00:37:00,820 --> 00:37:05,780
+عندك أكتر من سلسلة سبعة في عندنا قاعدة بتقول if
+
+411
+00:37:05,780 --> 00:37:09,760
+there are two equal along continuous chains يعني
+
+412
+00:37:09,760 --> 00:37:13,180
+لو في عندكوا سلسلتين متساويات في الطول في
+
+413
+00:37:13,180 --> 00:37:16,780
+الاحتمالات ا choose the one with most branches
+
+414
+00:37:16,780 --> 00:37:21,820
+اختار السلسلة اللي فيها تفرعات أكتريعني لو اتطلعت
+
+415
+00:37:21,820 --> 00:37:28,340
+على السلسلة هذه، كم تفرع طالع منها؟ اتنين، شغلتين
+
+416
+00:37:28,340 --> 00:37:31,540
+طالعين منها، لو اتطلعت على السلسلة هذه، كم تفرع
+
+417
+00:37:31,540 --> 00:37:37,980
+طالع منها؟ مجموعة واحدة، واضح؟ هذه طالع منها فقط
+
+418
+00:37:37,980 --> 00:37:42,240
+تفرع واحد، هيو، هنا طالع تفرعين، ابن اختار اللي
+
+419
+00:37:42,240 --> 00:37:47,000
+فيهاتفرعين طبعا لما نختار او ناخد ال lower
+
+420
+00:37:47,000 --> 00:37:51,640
+numbering على نمرة تلاتة في عندي مجموعة CH2 CH3
+
+421
+00:37:51,640 --> 00:37:55,600
+هذه اللي بيقول عنها إثل وعن نمرة اتنين المثل three
+
+422
+00:37:55,600 --> 00:38:00,300
+ethyl two methyl heptane بينما لو واحدة اختارت هذه
+
+423
+00:38:00,300 --> 00:38:04,220
+هتقول heptane على نمرة تلاتة هذه المجموعة
+
+424
+00:38:04,220 --> 00:38:09,520
+isopropyl فهذا الاسم three isopropyl heptane is
+
+425
+00:38:09,520 --> 00:38:14,650
+not a correct nameممكن واحدة في الامتحان تعمله،
+
+426
+00:38:14,650 --> 00:38:18,230
+تعتقد أنها عملت جيدا، في الآخر تتفاجأ أنه غلط
+
+427
+00:38:18,230 --> 00:38:22,670
+بالكامل، ليش؟ لأنها مانتبهتش أنه عندها سلسلتين،
+
+428
+00:38:22,670 --> 00:38:26,690
+ممكن يكونوا سبعة، وأنه لو أخدت من هنا، اللي هي هذه
+
+429
+00:38:26,690 --> 00:38:30,130
+السلسلة، هذه فيها ال most branches، فيها التفرعات
+
+430
+00:38:30,130 --> 00:38:34,390
+الأكثرولذلك اللي بده يشتغل في التسمية بده يكون
+
+431
+00:38:34,390 --> 00:38:39,610
+منتبه أنه فعلا لجأ أطول سلسلة واتأكد أنه مافيش
+
+432
+00:38:39,610 --> 00:38:45,150
+غيرها، لو لجأت إنتين بنفس الطول، بده يختار الأكثر
+
+433
+00:38:45,150 --> 00:38:52,310
+تفرعا، بده يختار السلسلة الأكثر تفرعا، واضح هذا
+
+434
+00:38:52,310 --> 00:39:00,220
+الكلام؟ ممكن نجرب ما أعطيكممثال حتى نشوف انكم
+
+435
+00:39:00,220 --> 00:39:18,060
+أتقنتوا هذا الكلام ولا لا هذا
+
+436
+00:39:18,060 --> 00:39:23,040
+مركب ابدأوا
+
+437
+00:39:23,040 --> 00:39:24,780
+فاكروا فيه وشوفوا
+
+438
+00:39:27,090 --> 00:39:33,530
+أيش أطول سلسلة موجودة فيه و
+
+439
+00:39:33,530 --> 00:39:38,610
+أول ما نعملها بأنصح اكون معاكم قلم فوسفور اتعلموا
+
+440
+00:39:38,610 --> 00:39:44,350
+عليها عشان تقدروا تشوفوا كل ما يتفرع منها واضح؟
+
+441
+00:39:44,350 --> 00:39:49,650
+الآن أكيد هتبدو تعدوا أنتوا واحد تنين تلاتة أربعة
+
+442
+00:39:49,650 --> 00:39:53,310
+أكيد لو قلتوا تلاتة تلاتة أربعة تلاتة أربعة نفس
+
+443
+00:39:53,310 --> 00:40:02,770
+الأشي أوواحد اتنين تلاتة او واحد اتنين تلاتة اربعة
+
+444
+00:40:02,770 --> 00:40:11,370
+خمسة ستة ايش رأيكوا او اي واحدة من هدول هادي زي
+
+445
+00:40:11,370 --> 00:40:14,650
+هادي زي هادي ماهم تلات اطراف واحد اتنين واحد اتنين
+
+446
+00:40:14,650 --> 00:40:22,090
+واحد اتنين اي واحدة بتاخدوها مافيش فيه مشكلة منها
+
+447
+00:40:23,210 --> 00:40:27,150
+أي واحدة من هدولة بيمشي تكون المرة واحدة لأنها
+
+448
+00:40:27,150 --> 00:40:33,650
+وادي وادي زي بعض واحد تانين تلاتة أربعة خمسة ستة
+
+449
+00:40:33,650 --> 00:40:39,630
+سبعة اه الآن هي أطول سلسلة خليني أعلمها و بأنصحكوا
+
+450
+00:40:39,630 --> 00:40:44,630
+لو عندكم طلم فسفور أسفر اتعلموها هي أطول سلسلة
+
+451
+00:40:44,630 --> 00:40:51,050
+عشان نقدر نشوف كام تفرع طالع منها هذه السلسلةاربع
+
+452
+00:40:51,050 --> 00:41:01,330
+انا مع الكلور هذه CH3 وهذه CH3 وهذه CH3 وهنا
+
+453
+00:41:01,330 --> 00:41:06,010
+الكلور اربع تفرعات طالع منها طب لو بدى اعطيها اقل
+
+454
+00:41:06,010 --> 00:41:16,080
+ترقيم من فضل من فضل اكيد واحدتلاتة اربعة خمسة ستة
+
+455
+00:41:16,080 --> 00:41:21,160
+سبعة الان لو بدنا نكتب الاسم كاملا كيف بدنا نبدأ
+
+456
+00:41:21,160 --> 00:41:27,880
+نكتب الاسم؟ من الخلف للامام ايش مركب طالما سبعة؟
+
+457
+00:41:27,880 --> 00:41:35,360
+هبتين الان هذا الهبتين كم نوع من المجموعات يحمل؟
+
+458
+00:41:35,360 --> 00:41:44,910
+نوعين اكلوروومثل ومثل ومثل اتراي مثل اذا هذا حقيقة
+
+459
+00:41:44,910 --> 00:41:54,550
+الـ C في الأول الكلورو اتراي مثل الان الكلورو وين
+
+460
+00:41:54,550 --> 00:42:01,870
+موقعها على نمرة أربعة four شرطة كلورو ال اتراي مثل
+
+461
+00:42:01,870 --> 00:42:10,930
+وين موجودين على اتنينو اتنين و تلاتة لازم احدد
+
+462
+00:42:10,930 --> 00:42:15,330
+تلات ارقام طالما try مثل لازم التلات ارقام بينه
+
+463
+00:42:15,330 --> 00:42:21,090
+اذا هنا فعلا بدي اكتب شرطة اتنين اتنين تلاتة هدف
+
+464
+00:42:21,090 --> 00:42:27,650
+هذا الموقع ان انا اكتبها صح هتكون اتنين اتنين
+
+465
+00:42:27,650 --> 00:42:32,090
+تلاتة try مثل
+
+466
+00:42:37,340 --> 00:42:47,340
+4-chloro-2-2-3-trimethylheptane
+
+467
+00:42:52,160 --> 00:42:56,040
+ماحدش يغلط .. مرات كتير بعض الناس اللي بيحفظوا
+
+468
+00:42:56,040 --> 00:42:59,400
+مجموعات شو الغلط اللي بيجعوا فيه، مابيبحثوش عن
+
+469
+00:42:59,400 --> 00:43:02,480
+أطول سلسلة، بيجوا و بيقولوا اه هذه ال carbon اللي
+
+470
+00:43:02,480 --> 00:43:06,300
+حملة تلت مجموعات tertiary-butyl وهذه السلسلة
+
+471
+00:43:07,580 --> 00:43:11,460
+وبالتالي بيسموه hexane وحمل على نمرة 2 tertiary
+
+472
+00:43:11,460 --> 00:43:16,920
+butyl بالفعش أنا مابخدش أسماء المجموعات إلا بعد ما
+
+473
+00:43:16,920 --> 00:43:23,700
+أحدد أطول سلسلة دائما نمرة واحد حدده أطول سلسلة
+
+474
+00:43:23,700 --> 00:43:28,340
+بعض الناس بيغلط بيجي بيقول لأ هذه تعتبر مجموعة في
+
+475
+00:43:28,340 --> 00:43:32,830
+البداية يعني لو أنا هنا كنت كاتب CH3بروح و بقول
+
+476
+00:43:32,830 --> 00:43:36,210
+ادي مجموعة مثل لأ دي جزء من السلسلة بنفعش اسميها
+
+477
+00:43:36,210 --> 00:43:41,110
+مجموعة هذه من الأخطاء الشائع لبعض الناس بيجي بعمل
+
+478
+00:43:41,110 --> 00:43:44,650
+الترقيم من هان و بعدين بيقول على نمر واحد في عندي
+
+479
+00:43:44,650 --> 00:43:50,950
+try مثل .. لأ مش هيك تأخذه لازم أفتش عليه أطول
+
+480
+00:43:50,950 --> 00:43:54,630
+سلسلة و بعدين أشوف إيش في عندي مجموعات حسب ما
+
+481
+00:43:54,630 --> 00:43:59,010
+اتعلمت بأعمل التسمية تبعي
+
+482
+00:44:04,700 --> 00:44:10,980
+هذه تقريبا فكرة عن ال الكنز بشكل عام لو اتكلمنا عن
+
+483
+00:44:10,980 --> 00:44:15,960
+ال physical properties of الكنز هنلاحظ القاتل اول
+
+484
+00:44:15,960 --> 00:44:23,940
+شئ ال الكنز هم water insoluble ليش؟ لان دائما ال
+
+485
+00:44:23,940 --> 00:44:31,440
+الكنز تتذكر انهم non polar والمية polar حسب قاعدة
+
+486
+00:44:31,440 --> 00:44:36,250
+like dissolves likeالالكينز لا يدوبون في المياه
+
+487
+00:44:36,250 --> 00:44:40,590
+ولذلك من هؤلاء الالكينز على سبيل المثال البنزين
+
+488
+00:44:40,590 --> 00:44:44,890
+اللي هو أقود السيارات واضح هل يا تورا هذا بيدوب في
+
+489
+00:44:44,890 --> 00:44:49,090
+المياه ولا بيعمل طبقة تانية بيعمل طبقة تانية هنا
+
+490
+00:44:49,090 --> 00:44:54,810
+خليني أنبه لنقطة خطأ شائعلأنه احنا باللغة العربية
+
+491
+00:44:54,810 --> 00:44:59,330
+بنستعمل كلمة بنزين لما بنعب السيارة بنقول بنزين
+
+492
+00:44:59,330 --> 00:45:05,310
+فناس كتير بيخطئوا و بيفكروا انه احنا بنعب السيارة
+
+493
+00:45:05,310 --> 00:45:09,150
+البنزين هذا اللي مار عليكم اللي هو البنزين العطري
+
+494
+00:45:09,150 --> 00:45:16,230
+هذا الكلام خطأ طب ايش اسم هو بالانجليزي وقود
+
+495
+00:45:16,230 --> 00:45:23,650
+السيارات ال fuel اسمه جازولينأحنا بالعربي هذا
+
+496
+00:45:23,650 --> 00:45:29,390
+الجازولين بنقول عنه بنزين لكن هو حقيقة خليط من
+
+497
+00:45:29,390 --> 00:45:35,870
+الالكينز بشكل أساسي مركبين من الالكينز هو خليط من
+
+498
+00:45:35,870 --> 00:45:40,190
+الهيبتين والايزو
+
+499
+00:45:40,190 --> 00:45:40,710
+أكتين
+
+500
+00:45:43,660 --> 00:45:48,340
+فالجازولين اللي هو وقود السيارات اللي احنا بنعبيه
+
+501
+00:45:48,340 --> 00:45:52,180
+باللغة العربية متعودين نقول عنه بنزين مالوش هذا ال
+
+502
+00:45:52,180 --> 00:45:56,020
+structure ولا له علاقة بهذا ال structure لأ
+
+503
+00:45:56,020 --> 00:46:02,000
+gasoline is a mixture of alkanes الجازولين وقود
+
+504
+00:46:02,000 --> 00:46:05,780
+السيارات اللي بنعبيه هو خليط من ال alkanes شو ما
+
+505
+00:46:05,780 --> 00:46:10,480
+دول ال alkanes؟الهبتين وال ايزو اكتين و بتهيألي
+
+506
+00:46:10,480 --> 00:46:15,020
+اليوم احنا رسمنا شكل الهبتين سبع كربونات و رسمنا
+
+507
+00:46:15,020 --> 00:46:18,900
+شكل ال ايزو اكتين اللي فيه مجموعة ال ايزو و بنكمل
+
+508
+00:46:18,900 --> 00:46:24,500
+لكم كربونات تمانية الان هدولة الكنز لو أخدنا هذا
+
+509
+00:46:24,500 --> 00:46:29,880
+الجازولين وقود السيارات و حطناه فوق ميهبيخلط
+
+510
+00:46:29,880 --> 00:46:34,640
+معاها، بيدوب فيها؟ لأ، فإذا الالكينز they are
+
+511
+00:46:34,640 --> 00:46:39,880
+water insoluble، ليش؟ لأن هدول المركبات، القوة
+
+512
+00:46:39,880 --> 00:46:46,010
+اللي فيهم، London forces، بينما الميهالهيدروجين
+
+513
+00:46:46,010 --> 00:46:52,810
+بوندنج فيها الميّه بولر والالكينز نان بولر فالبولر
+
+514
+00:46:52,810 --> 00:46:57,370
+والنان بولر بخلطوش مع بعض are water insoluble طبعا
+
+515
+00:46:57,370 --> 00:47:02,000
+كونوا القوة اللي موجودة فيهم ضعيفةاللي هي أضعف نوع
+
+516
+00:47:02,000 --> 00:47:05,440
+من القوة الـ London Forces معناه ذلك الجزيئات
+
+517
+00:47:05,440 --> 00:47:10,880
+بتاعتهم ممسوقة ببعضها بقوة ولا بقوة ضعيفة؟ بقوة
+
+518
+00:47:10,880 --> 00:47:16,160
+ضعيفة، هذا بيقدر إلى إنها بتتبخر بشكل سريع وإلى أن
+
+519
+00:47:16,160 --> 00:47:22,000
+نقطة الغليان تبعتها أيضا منخفضة جدا ولذلك لو أنا
+
+520
+00:47:22,000 --> 00:47:25,380
+إجيت اتطلعت على ال canes اللي في الجدول هلاحظ ال
+
+521
+00:47:25,380 --> 00:47:32,540
+methane غازالإيثين غاز، البروبين غاز، البيوتين
+
+522
+00:47:32,540 --> 00:47:36,600
+غاز، اللي هو الغاز المنزلي، غاز الطهي المنزلي، هو
+
+523
+00:47:36,600 --> 00:47:41,740
+البيوتين البنتين بيبدأ يصير سائل بنقطة غليان حوالي
+
+524
+00:47:41,740 --> 00:47:46,500
+36 درجة مؤوية، نقطة غليان منخفضة البنزين نفسه نقطة
+
+525
+00:47:46,500 --> 00:47:49,920
+غليانه منخفضة، ولذلك بيتبقر بسرعة وبيعمل حرائق
+
+526
+00:47:49,920 --> 00:47:56,570
+بسرعةواضح؟ كل هذا الكلام لأن القوة الترابط اللي
+
+527
+00:47:56,570 --> 00:48:01,070
+موجودة فيه هي ال London forces اللي هي أضعف أنواع
+
+528
+00:48:01,070 --> 00:48:05,550
+قوة الترابط فالجزيئات غير مترابطة بقوة و من هنا
+
+529
+00:48:05,550 --> 00:48:10,910
+بيكون ال alkanes لهم low boiling points بالتأكيد
+
+530
+00:48:10,910 --> 00:48:15,720
+ال cane من ذرةنقطة غليانه اقل من ذرتين اقل من
+
+531
+00:48:15,720 --> 00:48:20,460
+تلاتة وكل ما يبدو يزيدوا عدد ذرات الالكين ايش
+
+532
+00:48:20,460 --> 00:48:26,020
+بيصيلا نقطة الغليان بتزيد واضح؟أخر نقطة اليوم
+
+533
+00:48:26,020 --> 00:48:31,560
+بنحكيها أن الالكينز لنفس المركب يعني لنفس العدد
+
+534
+00:48:31,560 --> 00:48:36,580
+الخمسة مثلا ممكن تكون chain متسلسلة و ممكن تكون
+
+535
+00:48:36,580 --> 00:48:39,900
+branched معناة chain مرة تانية أن الخمسة ورا بعض
+
+536
+00:48:39,900 --> 00:48:44,020
+branched هي عندي واحد اتنين تلاتة مثلا في البنتين
+
+537
+00:48:44,020 --> 00:48:49,800
+و من موقع اتنين اعملت تفرعينهنا خمس ذرات وهنا خمس
+
+538
+00:48:49,800 --> 00:48:53,560
+ذرات الخمس هذول جايين إيش؟ ورا بعض بقول عنهم chain
+
+539
+00:48:53,560 --> 00:49:00,140
+compounds هذول برانش دائما بنقول برانش الكنز have
+
+540
+00:49:00,140 --> 00:49:02,840
+lower boiling points than the corresponding long
+
+541
+00:49:02,840 --> 00:49:10,620
+chain of kens يعني هذا و هذا له نفس الصيغة C5H12
+
+542
+00:49:10,620 --> 00:49:17,970
+لكن مين له نقطة غليان أعلى؟الـ Chain أقل ال branch
+
+543
+00:49:17,970 --> 00:49:23,330
+ليش؟ لأن ال branch بيكون عامل زي الكورة الآن
+
+544
+00:49:23,330 --> 00:49:27,990
+تخيلوا لو حطيتوا أنتوا نفسكم تلت كورات هيك فوق بعض
+
+545
+00:49:27,990 --> 00:49:33,130
+بهذا الشكل هل يتورا بينهم مسافات ارتباط قوية كتير؟
+
+546
+00:49:33,130 --> 00:49:37,620
+هاي بس سطح الارتباطواضحة الفكرة؟ فالجزء اللي
+
+547
+00:49:37,620 --> 00:49:42,220
+branched بصير أعمل زي الكورة، الآن الكورات بحطها
+
+548
+00:49:42,220 --> 00:49:45,880
+بشكل تستقر فوق بعض، يعني أنا بقدر أحطها دولة تلاتة
+
+549
+00:49:45,880 --> 00:49:51,610
+فوق بعض ويثبتوا؟ لأليش؟ لأنه مافيش سطح التقاء كبير
+
+550
+00:49:51,610 --> 00:49:55,730
+بينهم ولذلك الـbranched alkanes they have lower
+
+551
+00:49:55,730 --> 00:49:59,170
+boiling points than the corresponding long chain
+
+552
+00:49:59,170 --> 00:50:03,210
+alkanes هذه مبادئ عامة بال physical properties
+
+553
+00:50:03,210 --> 00:50:06,090
+للالكنز وبهيك بننهي اليوم ان شاء الله
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/qMxA2LgN_Fc.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/qMxA2LgN_Fc.srt
new file mode 100644
index 0000000000000000000000000000000000000000..7b40b7d1ebeaf3b80a2ae08b1b9ff670fc640477
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/qMxA2LgN_Fc.srt
@@ -0,0 +1,1782 @@
+
+1
+00:00:19,570 --> 00:00:26,370
+بسم الله الرحمن الرحيم اليوم ضَيّعنا أشياء بسيطة في
+
+2
+00:00:26,370 --> 00:00:30,890
+موضوع الأمينات قبل ما ننتقل لجزء الـ biochemistry
+
+3
+00:00:30,890 --> 00:00:36,850
+طبعًا اتفقنا المرة الماضية أن الأمينات هي مركبات
+
+4
+00:00:36,850 --> 00:00:43,470
+الـ nitrogen من أهم الأشياء اللي بتميزهم هو وجود
+
+5
+00:00:43,470 --> 00:00:47,730
+إيش؟ الـ lone pair of electrons اللي موجودة على الـ
+
+6
+00:00:47,730 --> 00:00:52,910
+Nitrogens طالما في عليهم lone pair of electrons و
+
+7
+00:00:52,910 --> 00:00:56,150
+الـ base is electron donor يعني الـ base هي اللي
+
+8
+00:00:56,150 --> 00:01:02,370
+بتعطي إلكترونات، فالـ amines are bases، واضح سبب أنه
+
+9
+00:01:02,370 --> 00:01:06,730
+بالأمينات قواعد هو وجود أزواج الإلكترونات، فهم
+
+10
+00:01:06,730 --> 00:01:11,010
+كقاعدة بيعطوا أزواج إلكترونات، هذا ضمن تعريف إيش؟
+
+11
+00:01:11,010 --> 00:01:19,710
+Lewis definition الآن لو إجى لهم H+، عندي زوج
+
+12
+00:01:19,710 --> 00:01:23,270
+إلكترونات والـ H+ مش حاملة إلكترونات، شو هيعملوا
+
+13
+00:01:23,270 --> 00:01:28,420
+فيها؟ هيتفاعلوا معها، هتصير الرابطة المتكونة
+
+14
+00:01:28,420 --> 00:01:31,840
+Coordinated Covalent bond، بمعنى أن زوجين
+
+15
+00:01:31,840 --> 00:01:37,940
+الإلكترونات من النيتروجين والـ H+ لما تتفاعل
+
+16
+00:01:37,940 --> 00:01:43,340
+معها بتكون مش حاملة الإلكترونات، ولذلك مثلًا هنا
+
+17
+00:01:43,340 --> 00:01:48,380
+أرسم لكم كيف الأمونيا لو تفاعلت مع H+، لاحظوا
+
+18
+00:01:48,380 --> 00:01:52,990
+الأمونيا NH3، أساسًا الـNitrogen في مداره
+
+19
+00:01:52,990 --> 00:01:57,070
+الخارجي خمس إلكترونات، فلو تخيلتم اللي كانوا
+
+20
+00:01:57,070 --> 00:02:00,470
+باللون الأزرق، ثلاثة منهم عملوا روابط مع
+
+21
+00:02:00,470 --> 00:02:03,670
+الـHydrogen، فهذه الرابطة مع الـHydrogen في
+
+22
+00:02:03,670 --> 00:02:07,510
+الأمونيا أصلاً، إلكترون من الـNitrogen وإلكترون من
+
+23
+00:02:07,510 --> 00:02:11,040
+الـHydrogen، اللي بيانه بالأخضر، كذلك الرابطة الثانية
+
+24
+00:02:11,040 --> 00:02:15,520
+والرابطة الثالثة، بقى عندي زوج إلكترونات، إجى H+ من
+
+25
+00:02:15,520 --> 00:02:21,180
+الخارج، الـH+ إجت بدون إلكترونات، بناءً على ذلك الرابطة
+
+26
+00:02:21,180 --> 00:02:24,560
+اللي هنا إيش بده تصير؟ Coordinate Covalent bond،
+
+27
+00:02:24,560 --> 00:02:29,460
+بمعنى أصلها أنه two electrons from the nitrogen
+
+28
+00:02:29,460 --> 00:02:35,300
+and no electron from hydrogen، طبعًا هذا بيخلي برضه
+
+29
+00:02:35,300 --> 00:02:41,700
+الأمينات bases بمفهوم لوري برونستيد definition،
+
+30
+00:02:41,700 --> 00:02:47,240
+ليش؟ لأنه بمفهومه أن الحامض هو اللي بيعطي H+،
+
+31
+00:02:47,240 --> 00:02:53,180
+والـ base هي اللي بتكتسب H+، الآن هذه اكتسبت H+
+
+32
+00:02:53,180 --> 00:02:57,600
+ولا لأ؟ إذا أيضًا ضمن تعريف لوري برونستيد
+
+33
+00:02:57,600 --> 00:03:03,860
+definition بتكون هذه base، لكن لاحظوا ضمن تعريف
+
+34
+00:03:03,860 --> 00:03:09,080
+Arrhenius أن الـ base لازم يكون فيها OH-، الأمونيا
+
+35
+00:03:09,080 --> 00:03:13,420
+ما انحسبتش base، ولذلك تدرّجت تعريفية الأحماض
+
+36
+00:03:13,420 --> 00:03:17,740
+يعني كان أقدم تعريف Arrhenius definition كان حاصر
+
+37
+00:03:17,740 --> 00:03:22,280
+الـ bases في المواد الـ hydroxides اللي بيعطوا الـ OH-،
+
+38
+00:03:22,280 --> 00:03:29,060
+بعدين قلنا لأ، هو كل حاجة بتكتسب H+ يمكن
+
+39
+00:03:29,060 --> 00:03:33,960
+أننا نعتبرها base، أساسًا الـ OH- كانت بتكتسب H+ و
+
+40
+00:03:33,960 --> 00:03:39,160
+بتعمل ماء، واضح؟ طب ما الآن NH4+ كمان بتكتسب جزيء H+،
+
+41
+00:03:39,160 --> 00:03:47,280
+واضح الفكرة؟ وإجى اللي هو Lewis definition أكثَر
+
+42
+00:03:47,280 --> 00:03:51,440
+تخصيصًا، وقال أن الـ base اللي فيه أزواج إلكترونات،
+
+43
+00:03:51,440 --> 00:03:55,340
+مافيش تناقض ما بين التعريفات، لكن فيه نظرة أكثَر
+
+44
+00:03:55,340 --> 00:04:00,790
+تخصيصية، الآن عشانكم لو حطينا الأمونيا مع الماء،
+
+45
+00:04:00,790 --> 00:04:05,510
+طبعًا الماء هنا حاطين الـ H3O+، كلكم عارفين أن
+
+46
+00:04:05,510 --> 00:04:11,070
+الماء إيش هو أساسًا؟ H2O، لكن هو اتخيل نسبة التأين
+
+47
+00:04:11,070 --> 00:04:17,430
+اللي هي بسيطة جدًا، اللي درستوها في الماء أن H2O زائد
+
+48
+00:04:17,430 --> 00:04:23,450
+H2O بتفاعل اتزان بيطلع نسبة بسيطة جدًا من H3O+
+
+49
+00:04:23,450 --> 00:04:30,600
+زائد OH-، عشان هيك هو لما هنا بيكتب H3O+،
+
+50
+00:04:30,600 --> 00:04:36,820
+هذي النسبة البسيطة جدًا اللي اتكونت من يعني تفاعل
+
+51
+00:04:36,820 --> 00:04:41,950
+الماء مع بعضها، إذا هنا إيش بيفترض أنه موجود؟ هو H+
+
+52
+00:04:41,950 --> 00:04:46,770
+وOH- كمان، ولذلك لما تيجي الأمونيا من الماء هتاخد الـ
+
+53
+00:04:46,770 --> 00:04:52,590
+H3O+ تاخد الـ H+ تعمل NH4+ زائد H2O، هو
+
+54
+00:04:52,590 --> 00:04:57,370
+أساسًا فيه أيون موجب، بكل حاله، لأ، الموجب كان معاه
+
+55
+00:04:57,370 --> 00:05:02,330
+سالب، الآن لما صارت الأمونيوم أيون، هنا موجب، إيش
+
+56
+00:05:02,330 --> 00:05:07,500
+صار معاه؟ سالب، ولذلك إحنا سنقول أن الأمونيا لما
+
+57
+00:05:07,500 --> 00:05:14,600
+ندوبها في الماء بتعطي أمونيوم هيدروكسيد، واضح؟ الكل
+
+58
+00:05:14,600 --> 00:05:19,220
+بيعرف أن إحنا بندوب الأمونيا في الماء بتعطي إيش؟
+
+59
+00:05:19,220 --> 00:05:23,750
+أمونيوم هيدروكسيد، كذلك الحالة لو دوبنا الأمونيا
+
+60
+00:05:23,750 --> 00:05:29,390
+مثلًا في الـ HCl، الأمونيا هتاخد H+ من هنا، هصير عندي
+
+61
+00:05:29,390 --> 00:05:34,510
+ammonium ion مع الـ Cl-، ammonium chloride، يمكن
+
+62
+00:05:34,510 --> 00:05:39,130
+هذا ما معاكم في المدرسة، أنه بإمكاننا إحنا نجيب
+
+63
+00:05:39,130 --> 00:05:44,180
+نقطة من الأمونيا من محلول الأمونيا نحطها هنا،
+
+64
+00:05:44,180 --> 00:05:49,760
+نقطة من الـ HCl نحطه هنا ونسيبهم جانب بعض، بتتبخر
+
+65
+00:05:49,760 --> 00:05:53,860
+... بتتبخر الأمونيا، بتتبخر الـ HCl، لما يلتقوا مع
+
+66
+00:05:53,860 --> 00:05:57,620
+بعض، الأمونيا مع الـ HCl شو هيعملوا؟ ammonium
+
+67
+00:05:57,620 --> 00:06:02,660
+chloride، الـ ammonium chloride إيش لونه؟
+
+68
+00:06:02,660 --> 00:06:08,310
+تذكروا شغل المدرسة؟ أبيض، ولذلك كنا نقول أنه الـ
+
+69
+00:06:08,310 --> 00:06:12,810
+ammonia مع الـ HCl بيعطوا سحب بيضاء من الـ ammonium
+
+70
+00:06:12,810 --> 00:06:18,820
+chloride، هذا النص مرّ عليكم في المدرسة ولا لأ؟ سحب
+
+71
+00:06:18,820 --> 00:06:23,780
+... سحب بيضاء أو بقعة بيضاء، هم عادة بيعملوها... عادة
+
+72
+00:06:23,780 --> 00:06:28,660
+بيعملوا هذه الشغلة كتجربة... كتجربة بيجيبوا أنبوبة
+
+73
+00:06:28,660 --> 00:06:32,500
+بهذا الشكل، بيجيبوا أنبوبة زجاجية مفتوحة الطرفين،
+
+74
+00:06:32,500 --> 00:06:38,270
+بهذا الشكل، بيحطوا هنا نقطة أمونيا، وبيحطوا هنا طبعًا
+
+75
+00:06:38,270 --> 00:06:41,090
+أمونيا، البعض هيقول لي غاز أمونيا، مدور باب ماء،
+
+76
+00:06:41,090 --> 00:06:44,970
+أمونيا ميكروفلز، بيطلع أمونيا، واضح؟ وبيحطوا هنا
+
+77
+00:06:44,970 --> 00:06:49,430
+HCl، الآن بيمشوا، بتبخر الغازين، هذا بيتبخر وهذا
+
+78
+00:06:49,430 --> 00:06:53,570
+بيتبخر، وسرعته بتعتمد على الـ molecular weight تبعه،
+
+79
+00:06:53,570 --> 00:06:58,050
+اللي الـ molecular weight تبعه الأقل بيمشي إيش؟ بطيء،
+
+80
+00:06:58,050 --> 00:07:00,890
+فهذا بيمشي له شوية هنا، هذا بيمشي له شوية هنا، لما
+
+81
+00:07:00,890 --> 00:07:05,280
+بيلتقوا إيش بدهم يعملوا؟ أمونيوم كلوريد، فجأة
+
+82
+00:07:05,280 --> 00:07:09,640
+بيصيروا الناس يشوفوا هنا إيش؟ أبخرة بيضاء، واضح؟
+
+83
+00:07:09,640 --> 00:07:15,310
+بيصيروا يشوفوا أبخرة بيضاء، هذه الأبخرة هي الأمونيوم
+
+84
+00:07:15,310 --> 00:07:19,250
+كلوريد، لو أنتم بتاخدوا معمل general chemistry
+
+85
+00:07:19,250 --> 00:07:22,410
+بتكون تجربة بتعملوها، بتجيبوا الأنبوبة وبتحطوهم،
+
+86
+00:07:22,410 --> 00:07:27,450
+بتشوفوا بعينكم، وعشان دائمًا بنقول التعليم الجامعي
+
+87
+00:07:27,450 --> 00:07:32,150
+لا يجب أن ينفصل بأي حال من الأحوال، اللي عملي عن
+
+88
+00:07:32,150 --> 00:07:36,290
+الجزء النظري في أي خطة تدريسية،
+
+89
+00:07:40,010 --> 00:07:45,710
+طالما قلنا أن الأمينات are bases، معناه ذلك زي ما
+
+90
+00:07:45,710 --> 00:07:50,130
+الأحماض كنا نقول عنهم acids ولهم pKa، الأمينات
+
+91
+00:07:50,130 --> 00:07:57,350
+بيكون لهم pKb، واضح؟ pKb، وقلنا كل ما كانت في الـ
+
+92
+00:07:57,350 --> 00:08:02,150
+acids الـ pKa أقل كل ما كان الحامض أقوى، الآن في الـ
+
+93
+00:08:02,150 --> 00:08:07,530
+bases بنقول كل ما الـ pKb بتكون أقل كل ما القاعدة
+
+94
+00:08:07,530 --> 00:08:12,460
+أيضًا بتكون أقوى، واضح؟ الجدول اللي موجود عندنا حقيقة
+
+95
+00:08:12,460 --> 00:08:22,240
+مش كاتب لنا الـ pKb، كاتب الـ pKa للـ conjugate acid،
+
+96
+00:08:22,240 --> 00:08:26,700
+conjugate acid يعني الحمض المرافق، عادة بين الـ acid
+
+97
+00:08:26,700 --> 00:08:32,620
+والـ base المرافقة بيكون الفرق إيش؟ هيدروجين، يعني
+
+98
+00:08:32,620 --> 00:08:38,560
+أنا لما بدي أقول NH4+، هذا الـ conjugate acid،
+
+99
+00:08:38,560 --> 00:08:45,500
+للقاعدة المرافقة NH3 وهكذا، بناءً على ذلك هدول اللي بيكونوا
+
+100
+00:08:45,500 --> 00:08:53,100
+pKa و pKb، كلنا عارفين أن pKa زائد الـ pKb
+
+101
+00:08:53,100 --> 00:08:59,420
+بيساوي 14، بناءً على ذلك لو إحنا كنا لهذه المجموعة من
+
+102
+00:08:59,420 --> 00:09:07,300
+الأمينات بدنا نشوف الـ pKb، بدنا نطرح من 14، يعني
+
+103
+00:09:07,300 --> 00:09:13,900
+مثلًا للأمونيا الـ pKb 4.7، للميثيل أمين
+
+104
+00:09:15,270 --> 00:09:21,390
+3.4، نفترض للدايف مثل أميل 3.4،
+
+105
+00:09:21,390 --> 00:09:25,870
+وللأنيلين مثلًا 9.4، لو إجينا مقارنة مثلًا مع الأنيلين
+
+106
+00:09:25,870 --> 00:09:34,290
+حوالي 9.4، الآن لو إجينا للإنيلين مثلًا
+
+107
+00:09:34,290 --> 00:09:40,410
+الأليل أمين أيضًا حوالي 9.2، الآن
+
+108
+00:09:40,410 --> 00:09:46,010
+لاحظوا، على طول ملاحظة، الأمينات اللي في الأول مثل أمين
+
+109
+00:09:46,010 --> 00:09:51,890
+داي مثل أمين ولحد الأليل هنا صار عندي تغير كثير،
+
+110
+00:09:51,890 --> 00:09:57,550
+يعني لحد هدول كلهم كانت الـ pKb قليلة، 3،
+
+111
+00:09:57,550 --> 00:10:03,130
+3، 4، لما صرت في الأنيلين والتوابع صرت 9،
+
+112
+00:10:03,130 --> 00:10:09,030
+الآن هدول إيش بيفرقوا عن بعض؟ لحد هذا الخط، هدول
+
+113
+00:10:09,030 --> 00:10:14,510
+اللي فوق aliphatic amines، اللي تحت aromatic amines،
+
+114
+00:10:14,510 --> 00:10:22,190
+واضح؟ إذا هذه منطقة الـ aliphatic amines، هذه منطقة الـ
+
+115
+00:10:22,190 --> 00:10:27,870
+aromatic amines، لو إجينا سألنا مين بيكونوا كـ bases
+
+116
+00:10:27,870 --> 00:10:33,430
+أقوى؟ الـ aliphatic amines ولا الـ aromatic amines؟
+
+117
+00:10:33,430 --> 00:10:40,000
+الـ aliphatic amines، ليش؟ لأنه كل ما الـ pKb بتكون أقل كل
+
+118
+00:10:40,000 --> 00:10:45,500
+ما كانت القاعدة أقوى، إذا الـ aliphatic amines are
+
+119
+00:10:45,500 --> 00:10:50,460
+stronger bases than aromatic amines، يعني لما نجيب
+
+120
+00:10:50,460 --> 00:10:54,740
+الـ QA، سؤال صح و غلط، الـ aliphatic amines are فراغ
+
+121
+00:10:54,740 --> 00:11:00,120
+bases than aromatic amines، they are stronger bases،
+
+122
+00:11:00,120 --> 00:11:05,660
+هذا عرفناها، الآن بعد كمان ممكن نكمل لكم، نقول لكم
+
+123
+00:11:05,660 --> 00:11:14,120
+إيش الـ due to، بسبب إيش؟ ليش بدنا نحكي صح؟ بدنا
+
+124
+00:11:14,120 --> 00:11:19,180
+نحكي لماذا الـ aliphatic amines
+
+125
+00:11:22,420 --> 00:11:27,220
+أقوى كقواعد من الـ aromatic amines؟ بهمش بدي أعلق
+
+126
+00:11:27,220 --> 00:11:32,260
+على الخطأ اللي عملته، بدي أعلق على الخطأ اللي عملته
+
+127
+00:11:32,260 --> 00:11:38,140
+عشان ما تكرروهوش رجاءً، أنا لما بقول أنه بسبب، واحدة
+
+128
+00:11:38,140 --> 00:11:44,020
+جاءت وقالت لي على طول بسبب الـ pKb، هذا الكلام غير مقبول منكم،
+
+129
+00:11:44,020 --> 00:11:48,400
+أنا لما قرأت الـ pKb،
+
+130
+00:11:50,390 --> 00:11:54,430
+لقيت هذه قليلة وهذه عالية، قلت الـ aromatic amines
+
+131
+00:11:54,430 --> 00:12:00,510
+أقوى من الـ aromatic amines، زي ما أجي على اثنين بني
+
+132
+00:12:00,510 --> 00:12:04,830
+أدم، أطفال، against طولهم، هذا طوله متر وهذا طوله
+
+133
+00:12:04,830 --> 00:12:10,750
+سبعين، الآن اللي طوله متر بقول عنه أطول من اللي
+
+134
+00:12:10,750 --> 00:12:15,230
+طوله سبعين، الآن لما أقول لكم ليش، ما حدش يقول لي أنه
+
+135
+00:12:15,230 --> 00:12:20,930
+طوله متر، this is nonsense، ممكن تقولوا لي لأنه في
+
+136
+00:12:20,930 --> 00:12:25,730
+العمر أكبر، يمكن يكون هذا السبب، هذا بيصير سبب لو
+
+137
+00:12:25,730 --> 00:12:29,670
+اثنين بنفس العمر، ممكن تقولوا لي وراثيًا، هذا كل أسرة
+
+138
+00:12:29,670 --> 00:12:33,750
+بتطول، هذا أسرة... هيك بيصير سبب، بس إن أجيب قياسه
+
+139
+00:12:33,750 --> 00:12:38,410
+وأقول عنه سبب، بسبب الـ pKb، لو أنا أساسًا استنتجت أن
+
+140
+00:12:38,410 --> 00:12:43,790
+هذا أقوى من هذا لأن الـ pKb هنا أقل من هنا، إذا هذا
+
+141
+00:12:43,790 --> 00:12:44,270
+أقوى،
+
+142
+00:12:47,630 --> 00:12:55,650
+بدي كلام إيش؟ بدي كلام كيمياء، طبعًا معنى base أنه
+
+143
+00:12:55,650 --> 00:12:59,650
+بتعطي إلكترونات، إذا السبب شيء يمنع من إعطاء
+
+144
+00:12:59,650 --> 00:13:06,400
+الإلكترونات أو يقلل إعطاء الإلكترونات، واضح؟ السبب
+
+145
+00:13:06,400 --> 00:13:10,740
+شيء يمنع أو يقلل من إعطاء الإلكترونات، هذا السبب
+
+146
+00:13:10,740 --> 00:13:14,400
+فعلاً ممكن يكون inductive effect، وفعلاً ممكن يكون
+
+147
+00:13:14,400 --> 00:13:18,980
+resonance effect، في حالة الـ aliphatic amines وهي
+
+148
+00:13:18,980 --> 00:13:23,820
+بالقاري، المركبين بيشابهوا بعض، القليل، مثلًا الـ pKa
+
+149
+00:13:23,820 --> 00:13:27,740
+تبع الحامض المرافق له 4.6، يعني الـ pKb
+
+150
+00:13:27,740 --> 00:13:33,980
+تبعته 9.4، هنا للـ ... للـ Cyclohexyl
+
+151
+00:13:33,980 --> 00:13:39,400
+الأمين، هذا ألفتك، ما في double bonds، Cyclic
+
+152
+00:13:39,400 --> 00:13:43,700
+alkanes are ألفتك، هذا كده إيش؟ 9.2، مين
+
+153
+00:13:43,700 --> 00:13:48,730
+كقاعدة أقوى؟ الـ Cyclohexyl الأمين ولا الأليل أمين؟ الـ
+
+154
+00:13:48,730 --> 00:13:53,770
+Cyclohexyl الأمين أقوى، الآن السبب أن هذا زوج
+
+155
+00:13:53,770 --> 00:13:58,830
+الإلكترونات بدل ما يكون جاهز يطلع برة ويتفاعل برة،
+
+156
+00:13:58,830 --> 00:14:04,310
+قاعد بيعمل resonance جوا الجزء، هذا زوج الإلكترونات
+
+157
+00:14:04,310 --> 00:14:09,660
+بيطلع للخارج جاهز إنه يُعطى للخارج، والـ base هي
+
+158
+00:14:09,660 --> 00:14:15,220
+اللي بتعطي إيش؟ إلكترونات، فهذا بدل ما يروح للخارج و
+
+159
+00:14:15,220 --> 00:14:20,640
+يظهر قوة المركب كـ base، قاعد بيجي بيلوف هنا وبيعمل
+
+160
+00:14:20,640 --> 00:14:24,360
+resonance... resonance ثاني، بيصير مرة - على الـ
+
+161
+00:14:24,360 --> 00:14:26,420
+carbon، مرة على الـ carbon الثاني، مرة على الـ carbon
+
+162
+00:14:26,420 --> 00:14:32,020
+الثالثة، إذا هو قاعد المجهود تبعه وين؟ جوا الجزء،
+
+163
+00:14:32,020 --> 00:14:37,990
+فبالنسبة للخارج هو لا يعطي إلكترونات، هو قاعد بيعمل
+
+164
+00:14:37,990 --> 00:14:41,990
+resonance جوا الجزئ، فما بيعطي إلكترونات للخارج، الـ
+
+165
+00:14:41,990 --> 00:14:46,870
+basic اللي بتعطي إلكترونات لمن؟ للخارج، هذا إذا
+
+166
+00:14:46,870 --> 00:14:51,650
+بيكون سبب... هذا بيكون سبب اللي هو ليش الـ aliphatic
+
+167
+00:14:51,650 --> 00:14:54,850
+amines are more basic than aromatic amines because
+
+168
+00:14:54,850 --> 00:15:01,71
+
+223
+00:19:44,130 --> 00:19:51,430
+الإلكترونات؟ في الميثيلانيلين، بعده الانيلين، بعده
+
+224
+00:19:51,430 --> 00:19:57,870
+النيترو، فـ basis الميثيلانيلين أعلى من الانيلين،
+
+225
+00:19:57,870 --> 00:20:02,350
+أعلى من النيترو أنيلين، الآن هنا لما أبدأ أقول شو
+
+226
+00:20:02,350 --> 00:20:10,330
+السبب؟  الـ inductive effect طبعاً بشكل عام كلهم
+
+227
+00:20:10,330 --> 00:20:17,630
+يعتبروا ضعاف، ليش؟ لأن كلهم فيهم resonance، كلهم
+
+228
+00:20:17,630 --> 00:20:21,050
+يعتبروا كـ basis ضعاف، لكن واحد أضعف من الثاني أضعف
+
+229
+00:20:21,050 --> 00:20:26,610
+من الثالث، الآن فرق الضعف اللي بين الضعاف أساساً
+
+230
+00:20:26,610 --> 00:20:31,670
+بسبب إيش؟ الـ inductive effect لكن لو أنا باجي
+
+231
+00:20:31,670 --> 00:20:38,370
+بسألكم والله بشكل عام، الـ nitroaniline is a weak
+
+232
+00:20:38,370 --> 00:20:45,560
+base، ليش؟ هتقولولي الـ resonance مصيبة؟ والحاجات
+
+233
+00:20:45,560 --> 00:20:50,980
+هم صيبة ثانية، الـ nitro يعني صار سبب ضعفه شغل فيه
+
+234
+00:20:50,980 --> 00:20:55,280
+الـ resonance و الـ inductive effect لكن لو كنت بدأت
+
+235
+00:20:55,280 --> 00:20:58,500
+أقارنه مثلاً مع الـ methylaniline لأ، بقول ما هو الـ
+
+236
+00:20:58,500 --> 00:21:01,720
+resonance و الـ resonance هم عامل مشترك، بطل هو اللي
+
+237
+00:21:01,720 --> 00:21:07,920
+مفرق، صار إيش اللي مفرق؟ بشكل أساسي الـ inductive
+
+238
+00:21:07,920 --> 00:21:09,940
+effect، واضحة الفكرة؟
+
+239
+00:21:17,860 --> 00:21:23,620
+آخر شغلة في هذا الفصل، لو قلنا تفاعلات الـ Amines،
+
+240
+00:21:23,620 --> 00:21:28,240
+تفاعلات الـ Amines مرت علينا بدل المرّة ألف طالما
+
+241
+00:21:28,240 --> 00:21:33,140
+في زوج إلكترونات، إذا الـ Amines بيعملوا as الـ
+
+242
+00:21:33,140 --> 00:21:39,880
+nucleophiles، واضح؟ إذا بدكم تحكوا عن الكحولات،
+
+243
+00:21:39,880 --> 00:21:44,120
+بتفعلوا كنواة محبة، إذا بدكم تحكوا عن الديهيد
+
+244
+00:21:44,120 --> 00:21:48,260
+وكيتون، بتفعلوا كنواة محبة، إذا بدكم تحكوا عن
+
+245
+00:21:48,260 --> 00:21:52,660
+كاربوكسيلية أسيدز ومشتقاتها، بتفعلوا كنواة محبة،
+
+246
+00:21:52,660 --> 00:21:56,280
+وكل الأمثلة مرت علينا، الآن مع الكحولات
+
+247
+00:21:56,280 --> 00:22:00,700
+بيعملوا النوكليوفيليك سبستيتيوشن، مع الديهيدز وكيتون
+
+248
+00:22:01,680 --> 00:22:06,140
+بيعملوا الـ nucleophilic addition مع الإسترز
+
+249
+00:22:06,140 --> 00:22:10,340
+ومشتقاتها بيعملوا مرة ثانية الـ nucleophilic
+
+250
+00:22:10,340 --> 00:22:14,900
+substitution، يعني هذه نشوف عدة أمثلة، هذه أمين
+
+251
+00:22:14,900 --> 00:22:20,260
+RNH2 مع أسيل كلوريد، هذه الـ nucleophile هاجم وطرد
+
+252
+00:22:20,260 --> 00:22:24,360
+الـ Cl، هذا عبارة عن إيش؟ الـ nucleophilic
+
+253
+00:22:24,360 --> 00:22:29,520
+substitution على أسيل كلوريد، هذا primary أمين، طب
+
+254
+00:22:29,520 --> 00:22:33,230
+لو secondary أمين، برضه الـ nucleophilic
+
+255
+00:22:33,230 --> 00:22:38,230
+substitution على أسيل كلوريد ما فيش فيها شيء، لو
+
+256
+00:22:38,230 --> 00:22:41,710
+شفناه مركب ثاني برضه، هذا secondary أمين مع أسيل
+
+257
+00:22:41,710 --> 00:22:46,590
+كلوريد، الـ nucleophilic substitution، لو شفنا
+
+258
+00:22:46,590 --> 00:22:51,150
+أنيلين مع أسيل أنيدريد بده يهاجمها، نطرد هذه
+
+259
+00:22:51,150 --> 00:22:55,850
+الـ nucleophilic substitution، واضح؟ كل هذه
+
+260
+00:22:55,850 --> 00:22:59,250
+التفاعلات حقيقة سبع
+
+261
+00:23:00,470 --> 00:23:07,030
+ومرت علينا في أي منطقة لما اتكلمنا على الأحماض
+
+262
+00:23:07,030 --> 00:23:13,130
+ومشتقاتها، ربما البعض يقول طيب ذكرنا بأمثلة على الـ
+
+263
+00:23:13,130 --> 00:23:16,630
+(Repeated "ال" – Removed)
+
+264
+00:23:16,630 --> 00:23:17,190
+(Repeated "ال" – Removed)
+
+265
+00:23:17,190 --> 00:23:17,570
+(Repeated "ال" – Removed)
+
+266
+00:23:17,570 --> 00:23:24,530
+(Repeated "ال" – Removed)
+
+267
+00:23:24,530 --> 00:23:29,470
+(Repeated "ال" – Removed)
+
+268
+00:23:29,470 --> 00:23:29,490
+(Repeated "ال" – Removed)
+
+269
+00:23:31,660 --> 00:23:42,460
+CH3CH2NH2 هذا primary أمين زائد هذا المركب و
+
+270
+00:23:42,460 --> 00:23:49,980
+حامل هنا بـ R، هذا يعتبر إيش؟ كحول، هذا في
+
+271
+00:23:49,980 --> 00:23:53,520
+النهاية كحول ولو حلقة خماسية كيف هتعملوا
+
+272
+00:23:56,960 --> 00:24:03,400
+واضح؟ وطالما الـ nucleophile neutral، كمحصلة لإيش
+
+273
+00:24:03,400 --> 00:24:11,020
+هيكون؟ يفقد CH3CH2 أكيد الـ H اللي فقدها مع الـ PR
+
+274
+00:24:11,020 --> 00:24:17,940
+إيش هتعمل؟ HPR هذا من chapter 6، الـ nucleophilic
+
+275
+00:24:17,940 --> 00:24:22,820
+substitution of Alkyl Halides، (Repeated "الوثيقة" – Removed)
+
+276
+00:24:22,820 --> 00:24:27,820
+(Repeated "الوثيقة" – Removed)
+
+277
+00:24:27,820 --> 00:24:30,180
+(Repeated "الوثيقة" – Removed)
+
+278
+00:24:30,180 --> 00:24:31,120
+(Repeated "الوثيقة" – Removed)
+
+279
+00:24:31,120 --> 00:24:31,460
+(Repeated "الوثيقة" – Removed)
+
+280
+00:24:31,460 --> 00:24:36,880
+(Repeated "الوثيقة" – Removed)
+
+281
+00:24:36,880 --> 00:24:41,160
+(Repeated "الوثيقة" – Removed)
+
+282
+00:24:41,160 --> 00:24:45,820
+(Repeated "الوثيقة" – Removed)
+
+283
+00:24:45,820 --> 00:24:47,480
+(Repeated "الوثيقة" – Removed)
+
+284
+00:24:47,480 --> 00:24:49,140
+(Repeated "الوثيقة" – Removed) ناخد كمان مثال
+
+285
+00:24:49,140 --> 00:24:53,960
+سايكليك كيتون أو الديهيد، هي C=O، C
+
+286
+00:24:53,960 --> 00:25:01,580
+=O زائد CH3CH2
+
+287
+00:25:01,580 --> 00:25:08,720
+NH2، تخيلوا إجتكم أكملوا هذه المعادلة، كيف هتكملوها؟
+
+288
+00:25:08,720 --> 00:25:12,260
+آه، بدكم تهاجموها على الـ الديهيد أو الـ كيتون و
+
+289
+00:25:12,260 --> 00:25:16,540
+هذه تصير OH، إذا الناتج اللي عندي
+
+290
+00:25:22,140 --> 00:25:30,100
+بصير عندي OH، OH، NH
+
+291
+00:25:30,100 --> 00:25:39,120
+CH2CH3، مش هذا اللي بدي يصير، لكن الطالب الشاطر
+
+292
+00:25:39,120 --> 00:25:45,900
+اتعلم كمان شغلة أن هذا هو تفاعل الـ nucleophilic
+
+293
+00:25:45,900 --> 00:25:46,780
+addition
+
+294
+00:25:49,140 --> 00:25:54,660
+هذا هو تفاعل الـ nucleophilic addition، الآن مع الـ
+
+295
+00:25:54,660 --> 00:25:58,600
+amines لما تكون الـ H و الـ OH جانب بعض، إيش
+
+296
+00:25:58,600 --> 00:26:05,460
+اتعلمنا؟ بيروح و بيفقد جزء ماء و بعمل double bond
+
+297
+00:26:08,450 --> 00:26:12,470
+قلنا إحنا كل NH2 مع C=O ما يصيرها
+
+298
+00:26:12,470 --> 00:26:17,130
+النهائي C=O، الديهيد أو كيتون تصير C
+
+299
+00:26:17,130 --> 00:26:23,790
+=NCH2CH3، بصير الـ shift base، وقلنا
+
+300
+00:26:23,790 --> 00:26:27,590
+أن التفاعل بهذه الحالة إيش بنقول عنه؟ addition
+
+301
+00:26:27,590 --> 00:26:30,370
+elimination
+
+302
+00:26:31,670 --> 00:26:35,830
+نسيته، تفاعل تكوين الأكسيمات والهيدرازونات والسمي
+
+303
+00:26:35,830 --> 00:26:39,570
+كاربازونات، كل الـ NH2 مع الـ C=O
+
+304
+00:26:39,570 --> 00:26:43,410
+الديهيدوكيتون كانت تعمل C=N على خطوتين
+
+305
+00:26:43,410 --> 00:26:51,100
+لكن في الأساس أن الأمين تفاعل كـ إيش؟ كان nucleophile وعمل
+
+306
+00:26:51,100 --> 00:26:54,760
+addition، الآن بعد هيك أن الـ addition اتبع الـ
+
+307
+00:26:54,760 --> 00:26:58,960
+elimination، هذا أمر إيش ثاني؟ هذا المحصلة النهائية
+
+308
+00:26:58,960 --> 00:27:03,480
+لكن الـ addition addition والـ nucleophile  الـ nucleophile فالـ
+
+309
+00:27:03,480 --> 00:27:09,240
+amines تفاعلهم الأساسي بنقول هو إيش؟ they react as
+
+310
+00:27:09,240 --> 00:27:14,480
+nucleophiles as nucleophiles، واضح؟
+
+311
+00:27:16,420 --> 00:27:20,000
+لكن لو جئنا سألناكم، الـ reaction of amines with
+
+312
+00:27:20,000 --> 00:27:25,120
+aldehydes and ketones is a nucleophilic addition
+
+313
+00:27:25,120 --> 00:27:30,600
+reaction، واضح؟ أنه بعدها followed by
+
+314
+00:27:30,600 --> 00:27:34,700
+elimination، على أنه رأسا، مرة تبسيط، واضح؟ with
+
+315
+00:27:34,700 --> 00:27:39,920
+acids and their derivatives، a nucleophilic
+
+316
+00:27:39,920 --> 00:27:44,620
+substitution، with alkyl halides، برضه nucleophilic
+
+317
+00:27:44,620 --> 00:27:45,840
+substitution
+
+318
+00:27:56,390 --> 00:28:01,410
+بهيك بنكون خلصنا الفكرة أو الكلام المختصر اللي
+
+319
+00:28:01,410 --> 00:28:07,510
+بنشرحه عن الـ amines و
+
+320
+00:28:07,510 --> 00:28:11,670
+ننتقل مباشرة
+
+321
+00:28:11,670 --> 00:28:15,970
+إلى فصل
+
+322
+00:28:15,970 --> 00:28:22,850
+الخامس عشر اللي هو يعتبر بداية الـ general
+
+323
+00:28:22,850 --> 00:28:28,890
+biochemistry اللي بنحكي عنها، Lipids and detergents
+
+324
+00:28:28,890 --> 00:28:37,110
+Lipids and detergents، الآن الـ Lipids معناها
+
+325
+00:28:37,110 --> 00:28:41,190
+بالعربي الدهون، إيش
+
+326
+00:28:41,190 --> 00:28:50,630
+اللي تلغيها، الـ Lipids، اسمها الـ Lipids، دهون، آه في
+
+327
+00:28:50,630 --> 00:28:55,570
+مشكلة عندكوا في الورق؟ أنا عند الـ slides خلص وأنتَ
+
+328
+00:28:55,570 --> 00:29:07,090
+عندك شيء؟ من وين صورتها؟ أي شرائح؟ مالغيين
+
+329
+00:29:07,090 --> 00:29:13,300
+هدول، مشمولين عن .. مش موجودين في المنهج، لأ لأ
+
+330
+00:29:13,300 --> 00:29:18,440
+هدول الـ slides اللي معكم، زيادة فيهم بس كلمة واحدة
+
+331
+00:29:18,440 --> 00:29:22,940
+إحنا شرحناها كتابة، How to prepare phenol، هي اللي
+
+332
+00:29:22,940 --> 00:29:27,740
+كنا مهتمين فيها، متذاكرينها المرة الماضية، قلنا لكم
+
+333
+00:29:27,740 --> 00:29:32,240
+كيف تحضروا الـ phenol، فقط لحد هنا وبنخلص، ما فيش أي شيء
+
+334
+00:29:32,240 --> 00:29:37,420
+أنا عن الـ computer، الآن ننتقل للفصل الخامس عشر
+
+335
+00:29:37,420 --> 00:29:42,280
+Lipids and detergents، الـ Lipids الدهون، الـ
+
+336
+00:29:42,280 --> 00:29:48,420
+detergents، المنظفات الصناعية، المنظفات الصناعية،
+
+337
+00:29:48,420 --> 00:29:51,400
+الصوابين والأشياء اللي بتكون في الشامبو وغيرها و
+
+338
+00:29:51,400 --> 00:29:57,520
+غيراتها، وهتلاحظوا أنه في علاقة بين الدهون وبين الـ
+
+339
+00:29:57,520 --> 00:30:03,160
+detergents، وربما كلكم بتذكروا أساساً أن الصابون
+
+340
+00:30:03,160 --> 00:30:08,220
+عادةً من وين كانوا بيجيبوها؟ من زيت الزيتون، زيت
+
+341
+00:30:08,220 --> 00:30:14,650
+الزيتون، دهون، والصابون منظف، طبعاً soap، الآن صاروا
+
+342
+00:30:14,650 --> 00:30:19,070
+يعملوا أشياء صناعية بنسميها synthetic detergents
+
+343
+00:30:19,070 --> 00:30:23,590
+يعني منظفات صناعية، كل هذا الكلام هيكون جزء من
+
+344
+00:30:23,590 --> 00:30:30,270
+الكلام اللي هنناقشه في هذا الفصل، الآن لو جئنا و
+
+345
+00:30:30,270 --> 00:30:38,380
+قلنا إيش هم الـ lipids، إيش هم الدهون،لاحظوا أنه
+
+346
+00:30:38,380 --> 00:30:42,140
+الآن بنبدأ شوية نختلف عن الـ organic chemistry، يعني
+
+347
+00:30:42,140 --> 00:30:45,760
+في الـ organic chemistry، كل chapter لما كنا نجيب
+
+348
+00:30:45,760 --> 00:30:50,080
+عائلة، كنا نميز العائلة بالمجموعة الوظيفية اللي
+
+349
+00:30:50,080 --> 00:30:54,780
+موجودة فيها، يعني نقول الـ alcohols OH، الـ aldehydes
+
+350
+00:30:54,780 --> 00:31:00,490
+أيضاً بالبُنْض OC=O، of R، of R، الأسيد C
+
+351
+00:31:00,490 --> 00:31:04,830
+=O، OH، هناك كان التصنيف اعتماداً على إيش؟
+
+352
+00:31:04,830 --> 00:31:11,010
+المجموعة الوظيفية، الآن لما باجي بقول الـ lipids هل
+
+353
+00:31:11,010 --> 00:31:16,790
+يا ترى الـ lipids كعائلة تحكمها مجموعة وظيفية واحدة
+
+354
+00:31:16,790 --> 00:31:19,870
+يعني في الآخر الواحدة تيجي تقولي C=
+
+355
+00:31:19,870 --> 00:31:26,780
+O، NH4، C=O، SH، هل تصنيف الـ lipids منطلق من
+
+356
+00:31:26,780 --> 00:31:29,980
+الـ functional groups، من المجموعات الوظيفية
+
+357
+00:31:29,980 --> 00:31:35,710
+فقط؟ الـ Lipids هي عائلة من المنتجات الطبيعية
+
+358
+00:31:35,710 --> 00:31:41,070
+بشكل عام، Natural Products، عائلة كبيرة جداً وينضوي
+
+359
+00:31:41,070 --> 00:31:47,030
+تحتها تفرعات كثيرة، هدول بيمتازوا بشكل عام ..
+
+360
+00:31:47,030 --> 00:31:51,490
+بيمتازوا بشكل عام، المركبات المنتجة طبيعياً أنّه
+
+361
+00:31:51,490 --> 00:31:56,230
+بتدوب في الـ organic solvents زي الـ ether،
+
+362
+00:31:56,450 --> 00:32:00,330
+chloroform، الأسيتون، البنزين، وبشكل عام ما بتدوبش في
+
+363
+00:32:00,330 --> 00:32:05,710
+الماء، إذا هنا اللي ميزهم كعائلة إنهم منتجات
+
+364
+00:32:05,710 --> 00:32:12,190
+طبيعية، وشغلة ثانية، soluble in organic solvents، يعني
+
+365
+00:32:12,190 --> 00:32:19,870
+أنا بدي أقول إن they are natural و soluble in non-polar
+
+366
+00:32:19,870 --> 00:32:24,370
+organic solvents، insoluble in water
+
+367
+00:32:27,950 --> 00:32:31,530
+اللي أنا بدي أقوله عن الـ lipids، they are natural
+
+368
+00:32:31,530 --> 00:32:37,510
+compounds، soluble in non-polar organic solvents
+
+369
+00:32:37,510 --> 00:32:43,050
+insoluble in water، طبعاً طالما كانوا soluble in non
+
+370
+00:32:43,050 --> 00:32:46,090
+-polar organic solvents، إذا أنتم هتستنتجوا أنهم
+
+371
+00:32:46,090 --> 00:32:51,790
+non-polar، ليش؟ لأنه like dissolves like، واضح؟ إذا هما non
+
+372
+00:32:51,790 --> 00:32:55,910
+polar و بتدوبوا فيه الـ non-polar solvents، الآن
+
+373
+00:32:55,910 --> 00:33:00,370
+بيندرج تحتهم الحقيقة مجموعة كبيرة من المركبات، منهم
+
+374
+00:33:00,370 --> 00:33:05,090
+اللي بنسميه الـ fatty acids، الأحماض الدهنية، بنشوف
+
+375
+00:33:05,090 --> 00:33:08,510
+شو هي الـ fatty acids، منهم الـ soaps and detergents
+
+376
+00:33:08,510 --> 00:33:13,370
+الصوابين والمنظفات، منهم الـ fats and oils، الدهون و
+
+377
+00:33:13,370 --> 00:33:18,770
+الزيوت، منهم الـ waxes، الشموع، منهم الـ Phospholipids
+
+378
+00:33:18,770 --> 00:33:23,330
+بنسميها phospholipids، منهم الـ Icosanoids، مركبات
+
+379
+00:33:23,330 --> 00:33:28,590
+بتكون من عشرين ذرة كربون، منهم terpenes، مجموعة
+
+380
+00:33:28,590 --> 00:33:34,590
+مركبات بتتميز بصفة معينة، بنشوفها، وجود isoprene unit
+
+381
+00:33:34,590 --> 00:33:40,400
+منهم الستيرويدات، مركبات بتتميز بوجود أربع حلقات، منهم
+
+382
+00:33:40,400 --> 00:33:45,620
+بعض الـ vitamins، أشياء متنوعة، ما فيش قاسم مشترك بينها
+
+383
+00:33:45,620 --> 00:33:50,980
+كل هدول من ناحية المبدأ natural products، soluble
+
+384
+00:33:50,980 --> 00:33:54,940
+in organic solvents and insoluble in water are
+
+385
+00:33:54,940 --> 00:33:57,580
+classified as lipids
+
+386
+00:34:20,310 --> 00:34:24,990
+يعني الثلاث أشياء بنفهمهم مع بعض، واضح؟ يعني اللي
+
+387
+00:34:24,990 --> 00:34:28,150
+بده يفهم الـ fatty acids، بده يفهم الـ fats، اللي
+
+388
+00:34:28,150 --> 00:34:30,890
+بده يفهم الـ fats، بده يفهم الـ oils، اللي بده يفهم
+
+389
+00:34:30,890 --> 00:34:33,110
+الـ fats و الـ oils، بده يفهم الـ soaps و الـ
+
+390
+00:34:33,110 --> 00:34:38,310
+detergents، الثلاث هتلاحظوا أن فيهم إيش؟ قاسم
+
+391
+00:34:38,310 --> 00:34:45,240
+مشترك، الثلاث هتلاحظوا أن فيهم قاسم مشترك، وعشان
+
+392
+00:34:45,240 --> 00:34:51,440
+هيك خلينا نبدأ بالـ fats and oils، الآن بشكل عام
+
+393
+00:34:51,440 --> 00:34:57,640
+الدهون والزيوت، أشهر شيء موجودين فيه على شكل اللي
+
+394
+00:34:57,640 --> 00:35:04,700
+بنسميه triglycerides، إيش هما الـ triglycerides؟ الـ
+
+395
+00:35:04,700 --> 00:35:13,120
+triglycerides ببساطة عبارة عن إسترز لـ الـ ..
+
+396
+00:35:14,640 --> 00:35:20,620
+للغليسرول، طبعاً كلكم بتذكروا إني إحنا إيش أخذنا
+
+397
+00
+
+445
+00:39:55,280 --> 00:40:02,420
+بحصل؟ بحصل على الـ glycerin أو الـ glycerol و الـ
+
+446
+00:40:02,420 --> 00:40:10,380
+fatty acids بحصل على الـ glycerol و الـ fatty acids
+
+447
+00:40:10,380 --> 00:40:17,060
+واضح الفكرة؟ إذا الـ fatty acids هما في الأساس جزء
+
+448
+00:40:17,060 --> 00:40:22,280
+من الـ tri glycerides بالتكسير بحصل على glycerin و
+
+449
+00:40:22,280 --> 00:40:27,600
+بحصل على fatty acid واضح الفكرة؟
+
+450
+00:40:29,710 --> 00:40:34,910
+خلّينا شوية صغيرة نخرج عن السياق خلّينا شوية صغيرة
+
+451
+00:40:34,910 --> 00:40:41,870
+نخرج عن السياق الآن. جزء الـ alkanes نرجع للـ alkanes
+
+452
+00:40:41,870 --> 00:40:48,790
+مش هذا الجزء الأحمر هو عبارة عن الـ alkanes؟ طيب أول
+
+453
+00:40:48,790 --> 00:40:54,150
+chapter أخدناه في الكيميا العضوية شو كان؟ alkanes،
+
+454
+00:40:54,150 --> 00:41:02,530
+وإيش أهم تفاعلات الـ alkanes اللي إحنا أخدناها؟ أن
+
+455
+00:41:02,530 --> 00:41:08,710
+الـ alkanes بنحرقهم في وجود الـ oxygen، بيعطونا ثاني
+
+456
+00:41:08,710 --> 00:41:15,970
+أكسيد الكربون وماء وحرارة. طيب هذه المركبات اللي
+
+457
+00:41:15,970 --> 00:41:20,090
+قال فيها alkanes. واحدة منكم ما كنتِش تتخيلي القاتل أنه
+
+458
+00:41:20,090 --> 00:41:25,970
+حطينا السيرج على النار، بدنا نولّع السيرج، حد بيمنعنا؟
+
+459
+00:41:25,970 --> 00:41:36,930
+يعني سيرج زائد Oxygen شو هيعطيني؟ CO2 زائد H2O زائد
+
+460
+00:41:36,930 --> 00:41:43,730
+Heat. مش هذه الـ aliphatic compounds  بتنحرج
+
+461
+00:41:43,730 --> 00:41:48,730
+وبتعطيني ثاني أكسيد كربون وميه وحرارة؟ إذا الـ
+
+462
+00:41:48,730 --> 00:41:53,790
+searege ممكن ينحرق ويعطيني ثاني أكسيد كربون وميه
+
+463
+00:41:53,790 --> 00:41:59,530
+وحرارة؟ ولا مش ممكن؟ بتشوفوه بنحرقه في الدار و
+
+464
+00:41:59,530 --> 00:42:04,530
+بتكونوا بتنتبهوا لما بتشتغلوا؟ طيب كويس. الآن لو واحد
+
+465
+00:42:04,530 --> 00:42:11,060
+مخه مش مرتاح أو الحصار مش مرتاح، وجطعوا البنزين..
+
+466
+00:42:11,060 --> 00:42:15,720
+جطعوا السولار عن البلد، وإيجي حطّ في سيارة الـ Mercedes
+
+467
+00:42:15,720 --> 00:42:18,920
+تبعته اللي بتمشي على السولار ولا في الـ bus؟ searge
+
+468
+00:42:18,920 --> 00:42:25,740
+.. searge ومشي.. بيمشي ولا لأ؟ بيمشي.. بيمشي..
+
+469
+00:42:25,740 --> 00:42:32,920
+بيمشي. وعشان هيك في غزة في ظروف الحصار لما عدم
+
+470
+00:42:32,920 --> 00:42:38,270
+الوقود، وكانوا بعض الباصات والسيارات الـ Mercedes مضطرة
+
+471
+00:42:38,270 --> 00:42:45,030
+تمشي، حطّوا searage في السيارة واشتغلت ومشيت، صح؟ لكن
+
+472
+00:42:45,030 --> 00:42:54,350
+كان عندكم مشكلة، الشيء إنه طلعت رائحة فظيعة جدا و
+
+473
+00:42:54,350 --> 00:42:58,850
+الناس كانت بتتنخنق. مظبوط ولا لأ؟ طيب، هم الناس
+
+474
+00:42:58,850 --> 00:43:02,030
+ما بتتنخنقوش من الـ solar العادي ومن البنزين يعني،
+
+475
+00:43:02,030 --> 00:43:05,990
+يقولوا تأثيرات سلبية، لكن ما بتوصلش لإن الناس
+
+476
+00:43:05,990 --> 00:43:11,650
+تتنخنق. إيش اللي صار إذا لما إحنا ولّعنا السيرج؟
+
+477
+00:43:11,650 --> 00:43:16,210
+اه، اللي صار لما ولّعنا السيرج، إنه السيرج جزءين،
+
+478
+00:43:16,210 --> 00:43:22,310
+هذا الجزء هو اللي عمل كوقود. هذا الجزء التابع للـ
+
+479
+00:43:22,310 --> 00:43:28,990
+glycerin راح يعمل مصيبة. هذا بالحرق بيعطي مركب ثاني
+
+480
+00:43:28,990 --> 00:43:36,990
+CH2=CH-CHO بنسميه acrolein ولا
+
+481
+00:43:36,990 --> 00:43:42,450
+acraldehyde. هذا المركب هو اللي ريحته كانت سيئة و
+
+482
+00:43:42,450 --> 00:43:49,350
+انبعث في الشوارع وغيره، وخنق الناس. واضحة
+
+483
+00:43:49,350 --> 00:43:55,130
+الفكرة؟ فالغلطة اللي كانت إن الناس لما اجوا يحرقوا
+
+484
+00:43:55,130 --> 00:44:01,330
+الـ searge في موتورات السيارات، حرقوا إيش؟ الجزء اللي
+
+485
+00:44:01,330 --> 00:44:06,110
+عادة بيعطيه الطاقة والجزء الجيد زائد الجزء إيش؟
+
+486
+00:44:06,110 --> 00:44:12,470
+السام، والنتيجة طلعت عندهم حرارة ومشيت السيارة وكل
+
+487
+00:44:12,470 --> 00:44:16,810
+شيء، لكن طلع عندهم كمان هذا المركب، انتشر في الجو
+
+488
+00:44:16,810 --> 00:44:24,620
+وخنق الناس. واضحة الفكرة؟ طيب، الآن لو في ناس بيفكروا
+
+489
+00:44:24,620 --> 00:44:31,940
+جيدا وقالوا يا ترى بدنا نحلّ المشكلة، نطلع وقود من
+
+490
+00:44:31,940 --> 00:44:40,080
+الزيت ومن السيرج، بيقدروا يعملوا هيك؟ لو إنهم في الأول
+
+491
+00:44:40,850 --> 00:44:46,750
+عملوا القاتل، فصلوا هدول المركبين عن بعض، يعني جابوا
+
+492
+00:44:46,750 --> 00:44:51,630
+الـ searge قبل ما يحطوه كله في موتور السيارة، قبل
+
+493
+00:44:51,630 --> 00:44:57,410
+ما يحطوه كله في موتور السيارة، كسّروه نصين. الآن هذا
+
+494
+00:44:57,410 --> 00:45:04,480
+النص المفيد، هذا الـ fuel، هذا الوقود، وهذا إيش؟
+
+495
+00:45:04,480 --> 00:45:08,860
+الجليسيرين. الآن أنا لما أكسّره بداية، قبل ما أحطه في
+
+496
+00:45:08,860 --> 00:45:13,340
+موتور السيارة، الجليسيرين صار على جانب، بفصله ولا
+
+497
+00:45:13,340 --> 00:45:17,600
+ما بفصله؟ بفصله، بأخذه وبستفيد منه كمان، بعمل منه
+
+498
+00:45:17,600 --> 00:45:21,220
+كريمات، مش كل الكريمات، وشامبوهات فيها جليسيرين، عشان
+
+499
+00:45:21,220 --> 00:45:27,850
+ترطيب الإيدين. يعني أنا مش بس تخلصت من ضرر حرقه، أنا
+
+500
+00:45:27,850 --> 00:45:32,470
+أخذته واستفدت منه. وهذا الجزء عادة بفصّلوه على شكل
+
+501
+00:45:32,470 --> 00:45:39,650
+ester أو ethyl ester  واضح؟
+
+502
+00:45:39,650 --> 00:45:43,250
+يعني لما يعملوا التكسير، بيفصلوه على شكل ester. هذا
+
+503
+00:45:43,250 --> 00:45:50,610
+بناخذه كوقود اليوم. هذا الوقود اللي أخدنا إيش
+
+504
+00:45:50,610 --> 00:45:57,770
+بيسمّوه؟ بيوديزل. بيوديزل إيش يعني؟ بيوديزل يعني
+
+505
+00:45:57,770 --> 00:46:03,910
+الديزل الحيوي اللي جاي من الزيوت. هتقولولي في ديزل
+
+506
+00:46:03,910 --> 00:46:11,610
+بالكامل من الزيت؟ الجواب آه. اليوم طائرات وسيارات
+
+507
+00:46:11,610 --> 00:46:17,370
+طائرات كاملة بتمشي على بيوديزل بالكامل من الزيوت.
+
+508
+00:46:17,960 --> 00:46:23,540
+طبعا هالايام احنا ملاقين زيت ناكله، searge وزيت
+
+509
+00:46:23,540 --> 00:46:29,620
+ناكله. لما نحوّلوه لوقود؟ الجواب آه. كيف؟ الزيوت مش بس
+
+510
+00:46:29,620 --> 00:46:34,760
+كلها مأكولة (edible)، مأكول. في زيوت inedible، زيوت لا
+
+511
+00:46:34,760 --> 00:46:40,480
+تؤكل، تمام؟ بيزرعوها في أماكن كبيرة في الهند وفي
+
+512
+00:46:40,480 --> 00:46:44,580
+غيرها، وفي غيرها، مثل مثلا زيت الجاتروفة وزيت
+
+513
+00:46:44,580 --> 00:46:49,520
+الكاميلينا وزيت كذا. في زيوت تؤكل وزيوت لا تؤكل.
+
+514
+00:46:49,520 --> 00:46:54,800
+الزيوت التي لا تؤكل هي اللي بيحضّروا منها المنظفات
+
+515
+00:46:54,800 --> 00:47:00,740
+وهي اللي بيحوّلوها لإيش؟ لـ bio diesel. وأشهرها زيت
+
+516
+00:47:00,740 --> 00:47:08,350
+اسمه الجاتروفة (Jatropha Oil). أشرب هذه الزيوت.. زيت
+
+517
+00:47:08,350 --> 00:47:13,010
+بنسميه إيش؟ زيت الجاتروفا. فلاحظوا أنتم كيف منطق
+
+518
+00:47:13,010 --> 00:47:17,350
+التفكير ومنطق حلّ المشكلة في العلم، أنه أنا فهمت
+
+519
+00:47:17,350 --> 00:47:22,450
+بداية.. أنه أنا فهمت بداية إن الحرارة بتجيني من
+
+520
+00:47:22,450 --> 00:47:29,170
+حرق هذا. واضح؟ الحرارة بتجيني من حرق هذا، لكن هذا
+
+521
+00:47:29,170 --> 00:47:34,090
+موجود مع مركب ثاني سام. لما فصلته من ضمنه، صار
+
+522
+00:47:34,090 --> 00:47:37,370
+بإمكاني أخد هذا وأسميه biodiesel وأحرقه ولا لأ؟
+
+523
+00:47:37,370 --> 00:47:44,590
+الآن ضايل لي عشرين ثانية أحكيهم، عارفين شو هم؟
+
+524
+00:47:44,590 --> 00:47:52,180
+العشرين ثانية اللي بدنا نحكيهم ونخلص. العشرين ثانية
+
+525
+00:47:52,180 --> 00:47:56,160
+اللي بنحكيهم وبنخلص. القاتل، تخيّلوا لو أخذتم هذا
+
+526
+00:47:56,160 --> 00:48:03,780
+الـ ester وحطّيتم هنا سلسلة طويلة وحطّيتم هنا
+
+527
+00:48:03,780 --> 00:48:11,850
+كمان سلسلة طويلة. هذه السلاسل إيش بتعمل؟ بتولّع مع الـ
+
+528
+00:48:11,850 --> 00:48:17,110
+Oxygen وبتعطي حرارة وإضاءة وإشي. هذه المركبات الـ
+
+529
+00:48:17,110 --> 00:48:22,090
+esters اللي فيها سلسلة طويلة يمين وسلسلة طويلة
+
+530
+00:48:22,090 --> 00:48:30,910
+الشمال، عارفين هي إيش؟ هي الشمع (wax). الآن أنا لما
+
+531
+00:48:30,910 --> 00:48:37,390
+بولّع الشمع، حقيقة إيش بولّع؟ السلاسل الأليفاتية.
+
+532
+00:48:40,000 --> 00:48:45,380
+وبهيك بيكون عرفنا إيش هو الشمع. الشمع هو ester، لكن
+
+533
+00:48:45,380 --> 00:48:50,160
+هذا الـ ester بسلسلتين كبار. وهنا إحنا عرفنا إنه
+
+534
+00:48:50,160 --> 00:48:55,180
+هذه السلاسل لما بتولّع هي اللي بتعطينا شوية الحرارة
+
+535
+00:48:55,180 --> 00:48:57,880
+وثاني أكسيد الكربون والميه، مش مهمين، أهم شيء
+
+536
+00:48:57,880 --> 00:49:02,720
+الحرارة والإضاءة. واضح؟ فلو قلنا لكم إيش الـ wax
+
+537
+00:49:02,720 --> 00:49:12,010
+بالضبط، الـ wax are أو الواكس هم esters مع سلاسل
+
+538
+00:49:12,010 --> 00:49:16,370
+طويلة، أو سلاسل أليفاتية طويلة. يعني اللي بيميزهم
+
+539
+00:49:16,370 --> 00:49:21,530
+السلاسل الطويلة، السلاسل الأليفاتية. وكلنا عارفين
+
+540
+00:49:21,530 --> 00:49:25,810
+الآن السلاسل الأليفاتية إيش بنعمل فيها؟ هي اللي
+
+541
+00:49:25,810 --> 00:49:30,250
+بنولّعها وبتعطينا الطاقة. هي اللي بنولّعها وبتعطينا
+
+542
+00:49:30,250 --> 00:49:34,850
+الطاقة. فبيكون هذا هو إيش؟ الشمع. فلاحظوا كيف أنا
+
+543
+00:49:34,850 --> 00:49:41,570
+استفدت من الـ searge كوقود، كيف أنا استفدت كمان من
+
+544
+00:49:41,570 --> 00:49:46,710
+الـ wax أنه أوّلعه ويطلع لي حرارة، من خلال إنه أنا
+
+545
+00:49:46,710 --> 00:49:50,110
+بستفيد من التفاعل الأصلي اللي أخذته في chapter واحد
+
+546
+00:49:50,110 --> 00:49:55,350
+إنّه الـ alkanes بتتفاعل مع الـ oxygen في combustion
+
+547
+00:49:55,350 --> 00:49:58,630
+يطلع ثاني أكسيد الكربون وميه وحرارة.
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/qMxA2LgN_Fc_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/qMxA2LgN_Fc_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..14e63a092d27f7f869641d58d03fe8277da43831
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/qMxA2LgN_Fc_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4389, "start": 19.57, "end": 43.89, "text": "بسم الله الرحمن الرحيم اليوم ضيلنا أشياء بسيطة في موضوع ال amines قبل ما ننتقل لجزء ال biochemistry طبعا اتفقنا المرة الماضية أن ال amines هم مراكبات ال nitrogen من أهم الأشياء اللي بتميزهم هو وجود إيش", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 48812, 26895, 8315, 5551, 8592, 1829, 16606, 4724, 3794, 1829, 9566, 3660, 8978, 3714, 2407, 11242, 45367, 2423, 669, 1652, 12174, 36150, 19446, 8717, 29399, 4587, 1211, 5296, 7435, 11622, 38207, 2423, 12198, 48353, 23032, 3555, 3615, 995, 1975, 2655, 5172, 4587, 8315, 9673, 25720, 9673, 46958, 10632, 14739, 2423, 669, 1652, 8032, 2304, 3714, 23557, 4117, 3555, 9307, 2423, 17903, 9154, 5551, 16095, 16247, 8592, 1829, 16606, 13672, 1829, 39894, 2304, 1829, 11622, 16095, 31439, 49610, 23328, 11933, 1829, 8592], "avg_logprob": -0.07627688011815471, "compression_ratio": 1.6372549019607843, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 19.57, "end": 19.87, "word": "بسم", "probability": 0.939208984375}, {"start": 19.87, "end": 20.03, "word": " الله", "probability": 0.97509765625}, {"start": 20.03, "end": 20.39, "word": " الرحمن", "probability": 0.9645182291666666}, {"start": 20.39, "end": 20.77, "word": " الرحيم", "probability": 0.9925130208333334}, {"start": 20.77, "end": 23.29, "word": " اليوم", "probability": 0.88525390625}, {"start": 23.29, "end": 23.91, "word": " ضيلنا", "probability": 0.724365234375}, {"start": 23.91, "end": 25.17, "word": " أشياء", "probability": 0.9493408203125}, {"start": 25.17, "end": 25.99, "word": " بسيطة", "probability": 0.99306640625}, {"start": 25.99, "end": 26.37, "word": " في", "probability": 0.93701171875}, {"start": 26.37, "end": 26.87, "word": " موضوع", "probability": 0.99560546875}, {"start": 26.87, "end": 27.05, "word": " ال", "probability": 0.91552734375}, {"start": 27.05, "end": 27.67, "word": " amines", "probability": 0.6875}, {"start": 27.67, "end": 28.29, "word": " قبل", "probability": 0.9931640625}, {"start": 28.29, "end": 28.41, "word": " ما", "probability": 0.85888671875}, {"start": 28.41, "end": 29.03, "word": " ننتقل", "probability": 0.97265625}, {"start": 29.03, "end": 29.53, "word": " لجزء", "probability": 0.9742431640625}, {"start": 29.53, "end": 30.03, "word": " ال", "probability": 0.94921875}, {"start": 30.03, "end": 30.89, "word": " biochemistry", "probability": 0.9296875}, {"start": 30.89, "end": 32.63, "word": " طبعا", "probability": 0.9918212890625}, {"start": 32.63, "end": 33.49, "word": " اتفقنا", "probability": 0.9751953125}, {"start": 33.49, "end": 33.85, "word": " المرة", "probability": 0.947265625}, {"start": 33.85, "end": 34.49, "word": " الماضية", "probability": 0.994140625}, {"start": 34.49, "end": 35.27, "word": " أن", "probability": 0.59912109375}, {"start": 35.27, "end": 35.43, "word": " ال", "probability": 0.8994140625}, {"start": 35.43, "end": 35.91, "word": " amines", "probability": 0.907958984375}, {"start": 35.91, "end": 36.15, "word": " هم", "probability": 0.870361328125}, {"start": 36.15, "end": 36.85, "word": " مراكبات", "probability": 0.96513671875}, {"start": 36.85, "end": 36.97, "word": " ال", "probability": 0.9091796875}, {"start": 36.97, "end": 37.63, "word": " nitrogen", "probability": 0.90283203125}, {"start": 37.63, "end": 39.65, "word": " من", "probability": 0.90380859375}, {"start": 39.65, "end": 40.09, "word": " أهم", "probability": 0.985595703125}, {"start": 40.09, "end": 40.83, "word": " الأشياء", "probability": 0.9962158203125}, {"start": 40.83, "end": 40.97, "word": " اللي", "probability": 0.935546875}, {"start": 40.97, "end": 42.03, "word": " بتميزهم", "probability": 0.93447265625}, {"start": 42.03, "end": 42.89, "word": " هو", "probability": 0.9453125}, {"start": 42.89, "end": 43.47, "word": " وجود", "probability": 0.9833984375}, {"start": 43.47, "end": 43.89, "word": " إيش", "probability": 0.8291015625}], "temperature": 1.0}, {"id": 2, "seek": 5867, "start": 44.43, "end": 58.67, "text": "الـ lone pair of electrons اللي موجودة على الـ Nitrogens طالما في عليهم lone pair of electrons و ال base is electron donor يعني ال base هي اللي بتعطي إلكترونات فال amines are", "tokens": [6027, 39184, 35314, 6119, 295, 14265, 13672, 1829, 3714, 29245, 23328, 3660, 15844, 2423, 39184, 37942, 6675, 694, 23032, 6027, 15042, 8978, 25894, 16095, 35314, 6119, 295, 14265, 4032, 2423, 3096, 307, 6084, 25493, 37495, 22653, 2423, 3096, 39896, 13672, 1829, 39894, 3615, 9566, 1829, 11933, 23275, 2655, 2288, 11536, 9307, 6156, 6027, 669, 1652, 366], "avg_logprob": -0.2787829072851884, "compression_ratio": 1.5, "no_speech_prob": 1.0728836059570312e-06, "words": [{"start": 44.43, "end": 44.97, "word": "الـ", "probability": 0.32574462890625}, {"start": 44.97, "end": 45.13, "word": " lone", "probability": 0.447998046875}, {"start": 45.13, "end": 45.45, "word": " pair", "probability": 0.8017578125}, {"start": 45.45, "end": 45.69, "word": " of", "probability": 0.94873046875}, {"start": 45.69, "end": 46.41, "word": " electrons", "probability": 0.83837890625}, {"start": 46.41, "end": 46.79, "word": " اللي", "probability": 0.805419921875}, {"start": 46.79, "end": 47.29, "word": " موجودة", "probability": 0.9027099609375}, {"start": 47.29, "end": 47.43, "word": " على", "probability": 0.8203125}, {"start": 47.43, "end": 47.73, "word": " الـ", "probability": 0.6025390625}, {"start": 47.73, "end": 48.39, "word": " Nitrogens", "probability": 0.6005045572916666}, {"start": 48.39, "end": 49.47, "word": " طالما", "probability": 0.9576822916666666}, {"start": 49.47, "end": 49.83, "word": " في", "probability": 0.79150390625}, {"start": 49.83, "end": 50.31, "word": " عليهم", "probability": 0.96923828125}, {"start": 50.31, "end": 50.57, "word": " lone", "probability": 0.9521484375}, {"start": 50.57, "end": 50.89, "word": " pair", "probability": 0.8779296875}, {"start": 50.89, "end": 51.11, "word": " of", "probability": 0.97998046875}, {"start": 51.11, "end": 51.99, "word": " electrons", "probability": 0.8046875}, {"start": 51.99, "end": 52.91, "word": " و", "probability": 0.5185546875}, {"start": 52.91, "end": 53.05, "word": " ال", "probability": 0.8876953125}, {"start": 53.05, "end": 53.45, "word": " base", "probability": 0.7763671875}, {"start": 53.45, "end": 53.81, "word": " is", "probability": 0.89501953125}, {"start": 53.81, "end": 54.49, "word": " electron", "probability": 0.94921875}, {"start": 54.49, "end": 55.05, "word": " donor", "probability": 0.9765625}, {"start": 55.05, "end": 55.41, "word": " يعني", "probability": 0.900390625}, {"start": 55.41, "end": 55.57, "word": " ال", "probability": 0.8935546875}, {"start": 55.57, "end": 55.81, "word": " base", "probability": 0.86474609375}, {"start": 55.81, "end": 55.97, "word": " هي", "probability": 0.896484375}, {"start": 55.97, "end": 56.15, "word": " اللي", "probability": 0.957275390625}, {"start": 56.15, "end": 56.65, "word": " بتعطي", "probability": 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الـNitrogen في مداره الخارجي خمس إلكترونات، فلو تخيلتم اللي كانوا باللون الأزرق، تلاتة منهم عملوا روابط مع الـHydrogen، فهذه الرابطة مع الـHydrogen في الأمونيا أصلاً، إلكترون من الـNitrogen وإلكترون من الـHydrogen، اللي بيانه بالأخضر", "tokens": [10721, 3794, 32277, 995, 14111, 2423, 39184, 45, 270, 7747, 8978, 3714, 3215, 9640, 3224, 33962, 9640, 7435, 1829, 16490, 2304, 3794, 11933, 23275, 2655, 2288, 11536, 9307, 12399, 6156, 1211, 2407, 6055, 9778, 26895, 39237, 13672, 1829, 25961, 14407, 20666, 1211, 11536, 16247, 11622, 2288, 4587, 12399, 6055, 1211, 9307, 3660, 9154, 16095, 6225, 42213, 14407, 12602, 14407, 3555, 9566, 20449, 2423, 39184, 39, 6655, 7747, 12399, 6156, 3224, 24192, 34892, 16758, 9566, 3660, 20449, 2423, 39184, 39, 6655, 7747, 8978, 16247, 2304, 11536, 25528, 5551, 9381, 15040, 14111, 12399, 11933, 23275, 2655, 2288, 11536, 9154, 2423, 39184, 45, 270, 7747, 4032, 28814, 23275, 2655, 2288, 11536, 9154, 2423, 39184, 39, 6655, 7747, 12399, 13672, 1829, 4724, 1829, 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الحالة لو دوبنا ال ammonia مثلا في ال HCl ال ammonia هتاخد H من هنا هصير عندى ammonium ion مع ال Cl minus ammonium chloride يمكن هذا ما معاكم في المدرسة انه بإمكاننا احنا نجيب نقطة", "tokens": [4117, 8848, 23275, 21542, 6027, 3660, 45164, 11778, 37746, 8315, 2423, 46833, 50113, 15040, 8978, 2423, 389, 9966, 2423, 46833, 8032, 2655, 47283, 3215, 389, 9154, 34105, 8032, 9381, 13546, 43242, 7578, 36431, 2197, 17437, 20449, 2423, 2033, 3175, 36431, 2197, 35434, 7251, 43020, 23758, 19446, 20449, 995, 24793, 8978, 9673, 3215, 2288, 3794, 3660, 16472, 3224, 4724, 28814, 2304, 41361, 8315, 1975, 5016, 8315, 8717, 7435, 1829, 3555, 8717, 47432, 3660], "avg_logprob": -0.2669092498413504, "compression_ratio": 1.540983606557377, "no_speech_prob": 0.0, "words": [{"start": 321.55, "end": 322.09, "word": "كذلك", "probability": 0.7384440104166666}, {"start": 322.09, "end": 322.51, "word": " الحالة", "probability": 0.569091796875}, {"start": 322.51, "end": 322.59, "word": " لو", "probability": 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مش كاتبنا ال BKB كاتب ال BKA ل ال conjugate acid conjugate acid يعني الحمض المرافق عادة بين ال acid و ال base المرافقة بيكون الفرق إيش؟", "tokens": [6027, 7435, 3215, 12610, 13672, 7578, 3714, 29245, 23328, 43242, 8315, 11331, 38436, 28671, 37893, 9122, 9307, 3555, 8315, 2423, 363, 42, 33, 9122, 9307, 3555, 2423, 363, 16135, 5296, 2423, 45064, 8258, 45064, 8258, 37495, 22653, 21542, 2304, 11242, 9673, 23557, 5172, 4587, 6225, 18513, 3660, 49374, 2423, 8258, 4032, 2423, 3096, 9673, 23557, 5172, 28671, 4724, 1829, 30544, 27188, 2288, 4587, 11933, 1829, 8592, 22807], "avg_logprob": -0.20094209032900193, "compression_ratio": 1.5987654320987654, "no_speech_prob": 0.0, "words": [{"start": 489.96, "end": 490.86, "word": "الجدول", "probability": 0.9677734375}, {"start": 490.86, "end": 491.02, "word": " اللى", "probability": 0.791015625}, {"start": 491.02, "end": 491.44, "word": " موجود", "probability": 0.9871419270833334}, {"start": 491.44, "end": 491.82, "word": " عندنا", "probability": 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"word": " اتنين", "probability": 0.88916015625}, {"start": 578.57, "end": 579.35, "word": " بالعشرة", "probability": 0.9630126953125}, {"start": 579.35, "end": 580.41, "word": " الان", "probability": 0.6466064453125}, {"start": 580.41, "end": 581.33, "word": " لاحظوا", "probability": 0.9603271484375}, {"start": 581.33, "end": 581.63, "word": " ع", "probability": 0.29931640625}, {"start": 581.63, "end": 581.93, "word": " طول", "probability": 0.8466796875}, {"start": 581.93, "end": 582.93, "word": " ملاحظة", "probability": 0.98837890625}, {"start": 582.93, "end": 583.83, "word": " الأمينز", "probability": 0.80572509765625}, {"start": 583.83, "end": 583.97, "word": " اللي", "probability": 0.802978515625}, {"start": 583.97, "end": 584.09, "word": " في", "probability": 0.85498046875}, {"start": 584.09, "end": 584.63, "word": " الأول", "probability": 0.92431640625}, {"start": 584.63, "end": 585.41, "word": " مثل", "probability": 0.97900390625}, {"start": 585.41, "end": 586.01, "word": " أمين", "probability": 0.9059244791666666}, {"start": 586.01, "end": 586.31, "word": " ضاي", "probability": 0.41021728515625}, {"start": 586.31, "end": 586.71, "word": " مثل", "probability": 0.989013671875}, {"start": 586.71, "end": 587.21, "word": " أمين", "probability": 0.9833984375}, {"start": 587.21, "end": 587.65, "word": " و", "probability": 0.68359375}, {"start": 587.65, "end": 588.09, "word": " لحد", "probability": 0.97900390625}, {"start": 588.09, "end": 589.07, "word": " الأللين", "probability": 0.9385986328125}, {"start": 589.07, "end": 589.53, "word": " هنا", "probability": 0.92333984375}, {"start": 589.53, "end": 590.55, "word": " صار", "probability": 0.93896484375}, {"start": 590.55, "end": 590.89, "word": " عندى", "probability": 0.775634765625}, {"start": 590.89, "end": 591.37, "word": " تغير", "probability": 0.97216796875}, {"start": 591.37, "end": 591.89, "word": " كتير", "probability": 0.98876953125}, {"start": 591.89, "end": 592.15, "word": " يعني", "probability": 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{"start": 605.03, "end": 605.21, "word": " عن", "probability": 0.9833984375}, {"start": 605.21, "end": 605.79, "word": " بعض", "probability": 0.994384765625}, {"start": 605.79, "end": 607.25, "word": " لحد", "probability": 0.898681640625}, {"start": 607.25, "end": 607.55, "word": " هذا", "probability": 0.89599609375}, {"start": 607.55, "end": 608.05, "word": " الخط", "probability": 0.9833984375}, {"start": 608.05, "end": 609.03, "word": " هدول", "probability": 0.9462890625}, {"start": 609.03, "end": 609.23, "word": " اللي", "probability": 0.90625}, {"start": 609.23, "end": 609.67, "word": " فوق", "probability": 0.990478515625}, {"start": 609.67, "end": 610.61, "word": " aliphatic", "probability": 0.5916341145833334}, {"start": 610.61, "end": 611.35, "word": " amines", "probability": 0.81640625}, {"start": 611.35, "end": 611.97, "word": " اللي", "probability": 0.944580078125}, {"start": 611.97, "end": 612.45, "word": " تحت", "probability": 0.98046875}, {"start": 612.45, "end": 613.67, "word": " aromatic", "probability": 0.84814453125}, {"start": 613.67, "end": 614.51, "word": " amines", "probability": 0.917724609375}, {"start": 614.51, "end": 615.43, "word": " واضح؟", "probability": 0.79620361328125}, {"start": 615.43, "end": 616.05, "word": " اذا", "probability": 0.73193359375}, {"start": 616.05, "end": 616.65, "word": " هذه", "probability": 0.82958984375}, {"start": 616.65, "end": 617.41, "word": " منطقات", "probability": 0.7760009765625}], "temperature": 1.0}, {"id": 28, "seek": 63491, "start": 618.35, "end": 634.91, "text": "الالفاتك أمين هذي منطقة ال aromatic amines لو إجينا سألنا مين بيكونوا ك basis أقوى الالفاتك أمين ولا ال aromatic amines؟ الالفاتك أمين", "tokens": [6027, 6027, 5172, 9307, 4117, 5551, 2304, 9957, 8032, 8848, 1829, 9154, 9566, 28671, 2423, 45831, 669, 1652, 45164, 11933, 7435, 1829, 8315, 8608, 10721, 1211, 8315, 3714, 9957, 4724, 1829, 30544, 14407, 9122, 5143, 5551, 4587, 2407, 7578, 2423, 6027, 5172, 9307, 4117, 5551, 2304, 9957, 49429, 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متعادلة", "probability": 0.8828125}, {"start": 1179.95, "end": 1180.61, "word": " الـ", "probability": 0.923095703125}, {"start": 1180.61, "end": 1181.13, "word": " Nitro", "probability": 0.8037109375}], "temperature": 1.0}, {"id": 50, "seek": 120591, "start": 1182.01, "end": 1205.91, "text": "بتسحب، إذا وين أعلى الإلكترونات؟ في الميثلانيلين، بعده الانيلين، بعده النيترو، فك basis الميثلانيلين أعلى من الانيلين، أعلى من النيتروانيلين، الآن هنا لما ابدأ أقول شو السبب؟ ال inductive effect", "tokens": [3555, 2655, 3794, 5016, 3555, 12399, 11933, 15730, 4032, 9957, 5551, 3615, 23942, 33688, 23275, 2655, 32887, 8315, 2655, 22807, 8978, 9673, 1829, 12984, 1211, 7649, 26895, 9957, 12399, 39182, 3224, 2423, 7649, 26895, 9957, 12399, 39182, 3224, 2423, 22653, 2655, 32887, 12399, 6156, 4117, 5143, 9673, 1829, 12984, 1211, 7649, 26895, 9957, 5551, 3615, 23942, 9154, 2423, 7649, 26895, 9957, 12399, 5551, 3615, 23942, 9154, 2423, 22653, 2655, 2288, 2407, 7649, 26895, 9957, 12399, 6024, 48506, 34105, 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الضعف اللي بين لضعاف أساساً بسبب إيش؟ ال inductive effect", "tokens": [9566, 3555, 3615, 995, 14111, 4724, 8592, 28820, 6225, 10943, 28242, 16095, 7251, 34268, 26890, 14407, 48812, 3615, 31845, 12399, 32239, 8592, 22807, 5296, 33456, 28242, 16095, 8978, 16095, 30944, 12399, 28242, 16095, 7251, 34268, 26890, 14407, 9122, 5143, 48812, 3615, 31845, 12399, 44381, 36764, 24401, 5551, 11242, 3615, 5172, 9154, 16712, 7649, 1829, 5551, 11242, 3615, 5172, 9154, 16712, 6027, 2655, 12399, 16247, 1863, 6156, 2288, 4587, 6024, 114, 3615, 5172, 13672, 1829, 49374, 5296, 11242, 3615, 31845, 5551, 3794, 32277, 995, 14111, 4724, 35457, 3555, 11933, 1829, 8592, 22807, 2423, 31612, 488, 1802], "avg_logprob": -0.15315754882370433, "compression_ratio": 1.7837837837837838, "no_speech_prob": 0.0, "words": [{"start": 1207.81, "end": 1208.39, "word": "طبعاً", "probability": 0.788671875}, {"start": 1208.39, "end": 1209.01, "word": " بشكل", "probability": 0.9324544270833334}, {"start": 1209.01, "end": 1209.51, 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1223.25, "word": " الضعف", "probability": 0.947998046875}, {"start": 1223.25, "end": 1223.61, "word": " اللي", "probability": 0.938720703125}, {"start": 1223.61, "end": 1223.85, "word": " بين", "probability": 0.99560546875}, {"start": 1223.85, "end": 1224.79, "word": " لضعاف", "probability": 0.754364013671875}, {"start": 1224.79, "end": 1226.61, "word": " أساساً", "probability": 0.86328125}, {"start": 1226.61, "end": 1227.31, "word": " بسبب", "probability": 0.9254557291666666}, {"start": 1227.31, "end": 1228.43, "word": " إيش؟", "probability": 0.8580322265625}, {"start": 1228.43, "end": 1228.55, "word": " ال", "probability": 0.9033203125}, {"start": 1228.55, "end": 1229.21, "word": " inductive", "probability": 0.888671875}, {"start": 1229.21, "end": 1229.71, "word": " effect", "probability": 0.95068359375}], "temperature": 1.0}, {"id": 52, "seek": 124415, "start": 1230.49, "end": 1244.15, "text": "لكن لو أنا باجي بسألكم والله بشكل عام ال nitroaniline is a weak base، ليش؟ هتقولولي ال resonance مصيبة؟", "tokens": [1211, 19452, 45164, 41850, 4724, 26108, 1829, 4724, 3794, 10721, 23275, 2304, 16070, 43761, 4724, 8592, 28820, 6225, 10943, 2423, 10900, 340, 282, 388, 533, 307, 257, 5336, 3096, 12399, 32239, 8592, 22807, 8032, 2655, 39648, 12610, 1829, 2423, 30944, 3714, 9381, 1829, 49401, 22807], "avg_logprob": -0.1842730945867041, "compression_ratio": 1.2, "no_speech_prob": 0.0, "words": [{"start": 1230.49, "end": 1230.91, "word": "لكن", "probability": 0.8544921875}, {"start": 1230.91, "end": 1231.09, "word": " لو", "probability": 0.966796875}, {"start": 1231.09, "end": 1231.33, "word": " أنا", "probability": 0.58935546875}, {"start": 1231.33, "end": 1231.67, "word": " باجي", "probability": 0.9404296875}, {"start": 1231.67, "end": 1232.45, "word": " بسألكم", "probability": 0.8916015625}, {"start": 1232.45, "end": 1233.13, "word": " والله", "probability": 0.75}, {"start": 1233.13, "end": 1233.77, "word": " بشكل", "probability": 0.9752604166666666}, {"start": 1233.77, 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1.0}, {"id": 53, "seek": 126994, "start": 1244.88, "end": 1269.94, "text": "و الحاجات هم صيبة تانية ال nitro يعني صار سبب ضعفه شغل فيه ال resonance و ال inductive effect لكن لو كنت بدأ اقارنه مثلا مع ال methyl aniline لأ بقول ما هو ال resonance و ال resonance هم عامل مشترك بطل هو اللي مفرج صار إيش اللي مفرج؟ شكل أساسي ال inductive effect واضحة الفكرة؟", "tokens": [2407, 21542, 26108, 9307, 8032, 2304, 20328, 1829, 49401, 6055, 7649, 10632, 2423, 10900, 340, 37495, 22653, 20328, 9640, 8608, 3555, 3555, 48812, 3615, 5172, 3224, 13412, 17082, 1211, 8978, 3224, 2423, 30944, 4032, 2423, 31612, 488, 1802, 44381, 45164, 9122, 29399, 47525, 10721, 1975, 4587, 9640, 1863, 3224, 50113, 15040, 20449, 2423, 48441, 364, 388, 533, 5296, 10721, 4724, 39648, 19446, 31439, 2423, 30944, 4032, 2423, 30944, 8032, 2304, 6225, 10943, 1211, 37893, 2655, 31747, 4724, 9566, 1211, 31439, 13672, 1829, 3714, 5172, 47341, 20328, 9640, 11933, 1829, 8592, 13672, 1829, 3714, 5172, 47341, 22807, 13412, 28820, 5551, 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"probability": 0.9775390625}, {"start": 1258.5, "end": 1259.02, "word": " resonance", "probability": 0.982421875}, {"start": 1259.02, "end": 1259.24, "word": " و", "probability": 0.837890625}, {"start": 1259.24, "end": 1259.34, "word": " ال", "probability": 0.953125}, {"start": 1259.34, "end": 1259.7, "word": " resonance", "probability": 0.978515625}, {"start": 1259.7, "end": 1260.06, "word": " هم", "probability": 0.5208740234375}, {"start": 1260.06, "end": 1260.38, "word": " عامل", "probability": 0.9934895833333334}, {"start": 1260.38, "end": 1260.9, "word": " مشترك", "probability": 0.96630859375}, {"start": 1260.9, "end": 1261.34, "word": " بطل", "probability": 0.9083658854166666}, {"start": 1261.34, "end": 1261.5, "word": " هو", "probability": 0.978515625}, {"start": 1261.5, "end": 1261.72, "word": " اللي", "probability": 0.9306640625}, {"start": 1261.72, "end": 1262.22, "word": " مفرج", "probability": 0.826171875}, {"start": 1262.22, "end": 1262.98, "word": " صار", "probability": 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{"id": 56, "seek": 135076, "start": 1321.68, "end": 1350.76, "text": "بيعملوه الـ Eucleophilic addition مع الـ E stars ومشتقاتها بيعملوه مرة تانية الـ Eucleophilic substitution يعني هاي نشوف عدة أمثلة هاي هذا أمين RNH2 مع أسد الكلورايد هاي الـ Eucleophile هاجم طرد الـ Cl هذا عبارة عن إيش الـ Eucleophilic substitution على أسد الكلورايد هذا primary أمين طب لو secondary أمين", "tokens": [21292, 25957, 1211, 2407, 3224, 2423, 39184, 462, 1311, 306, 5317, 388, 299, 4500, 20449, 2423, 39184, 462, 6105, 4032, 2304, 8592, 2655, 4587, 9307, 11296, 4724, 1829, 25957, 1211, 2407, 3224, 3714, 25720, 6055, 7649, 10632, 2423, 39184, 462, 1311, 306, 5317, 388, 299, 35827, 37495, 22653, 8032, 47302, 8717, 8592, 38688, 6225, 41891, 5551, 2304, 12984, 37977, 8032, 47302, 23758, 5551, 2304, 9957, 45702, 39, 17, 20449, 5551, 3794, 3215, 33251, 1211, 13063, 995, 25708, 8032, 47302, 2423, 39184, 462, 1311, 306, 49242, 8032, 26108, 2304, 23032, 2288, 3215, 2423, 39184, 2033, 23758, 6225, 3555, 9640, 3660, 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"temperature": 1.0}, {"id": 62, "seek": 151654, "start": 1487.92, "end": 1516.54, "text": "ناخد كمان مرنو سايكليك كيتون او الديهايد هى C double bond O C double bond O زائد CH3 CH2 NH2 تخيلوا اجتكوا اكمل هذه المعادلة كيف هتكملوها؟ اه بدكم اتهاجموها على ال الديهايد او ال كيتون و هذه تصير OH اذا للناتج اللى عندى", "tokens": [1863, 47283, 3215, 9122, 2304, 7649, 3714, 2288, 1863, 2407, 8608, 47302, 4117, 20292, 4117, 9122, 36081, 11536, 1975, 2407, 2423, 16254, 11296, 25708, 8032, 7578, 383, 3834, 6086, 422, 383, 3834, 6086, 422, 30767, 16373, 3215, 5995, 18, 5995, 17, 31118, 17, 6055, 9778, 26895, 14407, 1975, 7435, 2655, 4117, 14407, 1975, 24793, 1211, 29538, 9673, 3615, 18513, 37977, 9122, 33911, 8032, 2655, 24793, 1211, 2407, 11296, 22807, 1975, 3224, 47525, 24793, 1975, 47395, 26108, 2304, 2407, 11296, 15844, 2423, 2423, 16254, 11296, 25708, 1975, 2407, 2423, 9122, 36081, 11536, 4032, 29538, 6055, 9381, 13546, 13931, 1975, 15730, 24976, 8315, 2655, 7435, 13672, 7578, 43242, 7578], 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0.9713541666666666}, {"start": 1504.44, "end": 1504.76, "word": " هذه", "probability": 0.765625}, {"start": 1504.76, "end": 1505.6, "word": " المعادلة", "probability": 0.9935302734375}, {"start": 1505.6, "end": 1506.5, "word": " كيف", "probability": 0.943115234375}, {"start": 1506.5, "end": 1508.72, "word": " هتكملوها؟", "probability": 0.8579450334821429}, {"start": 1508.72, "end": 1509.08, "word": " اه", "probability": 0.5167236328125}, {"start": 1509.08, "end": 1509.44, "word": " بدكم", "probability": 0.58758544921875}, {"start": 1509.44, "end": 1510.26, "word": " اتهاجموها", "probability": 0.8130696614583334}, {"start": 1510.26, "end": 1510.68, "word": " على", "probability": 0.8359375}, {"start": 1510.68, "end": 1510.9, "word": " ال", "probability": 0.9765625}, {"start": 1510.9, "end": 1511.44, "word": " الديهايد", "probability": 0.84442138671875}, {"start": 1511.44, "end": 1511.62, "word": " او", "probability": 0.96728515625}, {"start": 1511.62, "end": 1511.78, "word": " ال", "probability": 0.475341796875}, {"start": 1511.78, "end": 1512.16, "word": " كيتون", "probability": 0.8174641927083334}, {"start": 1512.16, "end": 1512.26, "word": " و", "probability": 0.341064453125}, {"start": 1512.26, "end": 1512.56, "word": " هذه", "probability": 0.302490234375}, {"start": 1512.56, "end": 1513.78, "word": " تصير", "probability": 0.8787434895833334}, {"start": 1513.78, "end": 1514.38, "word": " OH", "probability": 0.85693359375}, {"start": 1514.38, "end": 1515.0, "word": " اذا", "probability": 0.7171630859375}, {"start": 1515.0, "end": 1515.82, "word": " للناتج", "probability": 0.730224609375}, {"start": 1515.82, "end": 1516.06, "word": " اللى", "probability": 0.959716796875}, {"start": 1516.06, "end": 1516.54, "word": " عندى", "probability": 0.794921875}], "temperature": 1.0}, {"id": 63, "seek": 154678, "start": 1522.14, "end": 1546.78, "text": "بدي يصير عندى OH OHANA NH CH2 CH3 مش هذا اللي بدي يصير لكن الطالب الشاطر اتعلمت كمان شغلة ان هذا هو تفاعل ل nucleophilic addition", "tokens": [3555, 16254, 7251, 9381, 13546, 43242, 7578, 13931, 13931, 21429, 31118, 5995, 17, 5995, 18, 37893, 23758, 13672, 1829, 4724, 16254, 7251, 9381, 13546, 44381, 41950, 6027, 3555, 25124, 41193, 2288, 1975, 2655, 3615, 19528, 2655, 9122, 2304, 7649, 13412, 17082, 37977, 16472, 23758, 31439, 6055, 5172, 995, 30241, 5296, 3822, 2160, 5317, 388, 299, 4500], "avg_logprob": -0.24013158522154154, "compression_ratio": 1.32, "no_speech_prob": 0.0, "words": [{"start": 1522.14, "end": 1522.48, "word": "بدي", "probability": 0.4013671875}, {"start": 1522.48, "end": 1522.76, "word": " يصير", "probability": 0.721923828125}, {"start": 1522.76, "end": 1523.56, "word": " عندى", "probability": 0.81787109375}, {"start": 1523.56, "end": 1525.06, "word": " OH", "probability": 0.5595703125}, {"start": 1525.06, "end": 1526.38, "word": " OHANA", "probability": 0.364501953125}, {"start": 1526.38, "end": 1530.1, "word": " NH", "probability": 0.6787109375}, {"start": 1530.1, "end": 1532.42, "word": " CH2", "probability": 0.84521484375}, {"start": 1532.42, "end": 1534.44, "word": " CH3", "probability": 0.870849609375}, {"start": 1534.44, "end": 1535.18, "word": " مش", "probability": 0.8388671875}, {"start": 1535.18, "end": 1535.36, "word": " هذا", "probability": 0.82958984375}, {"start": 1535.36, "end": 1535.5, "word": " اللي", "probability": 0.8759765625}, {"start": 1535.5, "end": 1535.64, "word": " بدي", "probability": 0.876708984375}, {"start": 1535.64, "end": 1536.08, "word": " يصير", "probability": 0.9856770833333334}, {"start": 1536.08, "end": 1537.4, "word": " لكن", "probability": 0.7578125}, {"start": 1537.4, "end": 1538.66, "word": " الطالب", "probability": 0.9763997395833334}, {"start": 1538.66, "end": 1539.12, "word": " الشاطر", "probability": 0.9441731770833334}, {"start": 1539.12, "end": 1539.82, "word": " اتعلمت", "probability": 0.93505859375}, {"start": 1539.82, "end": 1540.36, "word": " كمان", "probability": 0.9796549479166666}, {"start": 1540.36, "end": 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{"start": 1554.02, "end": 1554.44, "word": " مع", "probability": 0.89404296875}, {"start": 1554.44, "end": 1554.66, "word": " ال", "probability": 0.8984375}, {"start": 1554.66, "end": 1555.36, "word": " amines", "probability": 0.5557861328125}, {"start": 1555.36, "end": 1555.64, "word": " لما", "probability": 0.789794921875}, {"start": 1555.64, "end": 1555.98, "word": " تكون", "probability": 0.987548828125}, {"start": 1555.98, "end": 1556.14, "word": " ال", "probability": 0.93603515625}, {"start": 1556.14, "end": 1556.38, "word": " H", "probability": 0.75244140625}, {"start": 1556.38, "end": 1556.54, "word": " و", "probability": 0.77099609375}, {"start": 1556.54, "end": 1556.66, "word": " ال", "probability": 0.5771484375}, {"start": 1556.66, "end": 1557.06, "word": " OH", "probability": 0.83544921875}, {"start": 1557.06, "end": 1557.6, "word": " جانب", "probability": 0.8758138020833334}, {"start": 1557.6, "end": 1557.96, "word": " بعض،", "probability": 0.7942708333333334}, {"start": 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"قولنا احنا كل N H2 مع C double bond O ماصيرها النهائي C double bond O الديهيد او كيتون تصير C double bond N CH2 CH3 بصير ال shift basis وقولنا ان التفاعل بهذه الحالة ايش بنقول عنه addition elimination", "tokens": [39648, 8315, 1975, 5016, 8315, 28242, 426, 389, 17, 20449, 383, 3834, 6086, 422, 19446, 9381, 13546, 11296, 28239, 3224, 16373, 1829, 383, 3834, 6086, 422, 2423, 16254, 3224, 25708, 1975, 2407, 9122, 36081, 11536, 6055, 9381, 13546, 383, 3834, 6086, 426, 5995, 17, 5995, 18, 4724, 9381, 13546, 2423, 5513, 5143, 4032, 39648, 8315, 16472, 16712, 5172, 995, 30241, 39627, 24192, 21542, 6027, 3660, 1975, 1829, 8592, 44945, 39648, 18871, 3224, 4500, 29224], "avg_logprob": -0.32937499205271403, "compression_ratio": 1.559782608695652, "no_speech_prob": 0.0, "words": [{"start": 1568.45, "end": 1568.93, "word": "قولنا", "probability": 0.53009033203125}, {"start": 1568.93, "end": 1569.19, "word": " احنا", "probability": 0.7599283854166666}, {"start": 1569.19, "end": 1569.47, "word": " 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0.67626953125}, {"start": 1581.63, "end": 1581.81, "word": " ال", "probability": 0.1715087890625}, {"start": 1581.81, "end": 1582.13, "word": " shift", "probability": 0.37890625}, {"start": 1582.13, "end": 1582.75, "word": " basis", "probability": 0.5732421875}, {"start": 1582.75, "end": 1583.79, "word": " وقولنا", "probability": 0.8548177083333334}, {"start": 1583.79, "end": 1583.93, "word": " ان", "probability": 0.76171875}, {"start": 1583.93, "end": 1584.59, "word": " التفاعل", "probability": 0.924072265625}, {"start": 1584.59, "end": 1584.95, "word": " بهذه", "probability": 0.571044921875}, {"start": 1584.95, "end": 1585.37, "word": " الحالة", "probability": 0.95654296875}, {"start": 1585.37, "end": 1585.57, "word": " ايش", "probability": 0.818359375}, {"start": 1585.57, "end": 1586.01, "word": " بنقول", "probability": 0.847412109375}, {"start": 1586.01, "end": 1586.51, "word": " عنه", "probability": 0.970703125}, {"start": 1586.51, "end": 1587.59, "word": " addition", "probability": 0.72607421875}, {"start": 1587.59, "end": 1590.37, "word": " elimination", "probability": 0.45068359375}], "temperature": 1.0}, {"id": 66, "seek": 160815, "start": 1591.67, "end": 1608.15, "text": "نسيته تفاعل تكوين الأكزينز والهيدرازونز والسمي كربازونز كل ال N-H2 مع ال C double bond O الديهيدوكيتون كانت تعمل C double bond N على خطوتين لكن في الأساس أن الأمين تفاعل كإيش؟", "tokens": [1863, 3794, 36081, 3224, 6055, 5172, 995, 30241, 6055, 4117, 2407, 9957, 16247, 4117, 11622, 9957, 11622, 16070, 3224, 25708, 2288, 31377, 11536, 11622, 16070, 38251, 1829, 9122, 25513, 31377, 11536, 11622, 28242, 2423, 426, 12, 39, 17, 20449, 2423, 383, 3834, 6086, 422, 2423, 16254, 3224, 25708, 2407, 4117, 36081, 11536, 25961, 2655, 6055, 25957, 1211, 383, 3834, 6086, 426, 15844, 16490, 9566, 35473, 9957, 44381, 8978, 16247, 3794, 32277, 14739, 16247, 2304, 9957, 6055, 5172, 995, 30241, 9122, 28814, 1829, 8592, 22807], "avg_logprob": -0.2680147142971263, "compression_ratio": 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{"start": 1598.03, "end": 1598.31, "word": " مع", "probability": 0.97119140625}, {"start": 1598.31, "end": 1598.53, "word": " ال", "probability": 0.82666015625}, {"start": 1598.53, "end": 1598.67, "word": " C", "probability": 0.28955078125}, {"start": 1598.67, "end": 1598.85, "word": " double", "probability": 0.446533203125}, {"start": 1598.85, "end": 1599.25, "word": " bond", "probability": 0.93896484375}, {"start": 1599.25, "end": 1599.57, "word": " O", "probability": 0.95263671875}, {"start": 1599.57, "end": 1600.69, "word": " الديهيدوكيتون", "probability": 0.676910400390625}, {"start": 1600.69, "end": 1601.27, "word": " كانت", "probability": 0.937255859375}, {"start": 1601.27, "end": 1601.59, "word": " تعمل", "probability": 0.9816080729166666}, {"start": 1601.59, "end": 1601.81, "word": " C", "probability": 0.76806640625}, {"start": 1601.81, "end": 1601.99, "word": " double", "probability": 0.91455078125}, {"start": 1601.99, "end": 1602.37, "word": " bond", "probability": 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اتبع ال elimination هذا امر ايش تاني هذا المحصلة النهائية لكن ال addition ادشن و ال uqlu5 ال uqlu5 فال amines تفاعلهم الأساسي بنقول هو ايش they react as uqlu5 as uqlu5 واضح؟", "tokens": [41361, 344, 80, 2781, 20, 4032, 25957, 1211, 4500, 2423, 7649, 39182, 39896, 4117, 16472, 2423, 4500, 1975, 2655, 3555, 3615, 2423, 29224, 23758, 1975, 29973, 1975, 1829, 8592, 6055, 7649, 1829, 23758, 9673, 5016, 36520, 3660, 28239, 3224, 16373, 10632, 44381, 2423, 4500, 1975, 3215, 8592, 1863, 4032, 2423, 344, 80, 2781, 20, 2423, 344, 80, 2781, 20, 6156, 6027, 669, 1652, 6055, 5172, 995, 30241, 16095, 16247, 3794, 32277, 1829, 44945, 39648, 31439, 1975, 1829, 8592, 436, 4515, 382, 344, 80, 2781, 20, 382, 344, 80, 2781, 20, 4032, 46958, 5016, 22807], "avg_logprob": -0.2791118521439402, "compression_ratio": 1.6785714285714286, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1608.98, "end": 1609.28, "word": "كان", "probability": 0.80810546875}, {"start": 1609.28, "end": 1610.44, "word": " 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"probability": 0.437744140625}, {"start": 1620.98, "end": 1621.72, "word": " uqlu5", "probability": 0.9527587890625}, {"start": 1621.72, "end": 1621.88, "word": " ال", "probability": 0.705078125}, {"start": 1621.88, "end": 1622.78, "word": " uqlu5", "probability": 0.9798583984375}, {"start": 1622.78, "end": 1623.48, "word": " فال", "probability": 0.868408203125}, {"start": 1623.48, "end": 1624.1, "word": " amines", "probability": 0.5814208984375}, {"start": 1624.1, "end": 1624.84, "word": " تفاعلهم", "probability": 0.8880859375}, {"start": 1624.84, "end": 1625.52, "word": " الأساسي", "probability": 0.81939697265625}, {"start": 1625.52, "end": 1625.8, "word": " بنقول", "probability": 0.789794921875}, {"start": 1625.8, "end": 1625.98, "word": " هو", "probability": 0.82421875}, {"start": 1625.98, "end": 1627.3, "word": " ايش", "probability": 0.8304036458333334}, {"start": 1627.3, "end": 1627.58, "word": " they", "probability": 0.52392578125}, {"start": 1627.58, "end": 1628.46, "word": " react", "probability": 0.92041015625}, {"start": 1628.46, "end": 1629.24, "word": " as", "probability": 0.97802734375}, {"start": 1629.24, "end": 1630.84, "word": " uqlu5", "probability": 0.82696533203125}, {"start": 1630.84, "end": 1632.24, "word": " as", "probability": 0.55859375}, {"start": 1632.24, "end": 1633.2, "word": " uqlu5", "probability": 0.968017578125}, {"start": 1633.2, "end": 1634.48, "word": " واضح؟", "probability": 0.8817138671875}], "temperature": 1.0}, {"id": 68, "seek": 166584, "start": 1636.42, "end": 1665.84, "text": "لكن لو جينا سألناكم ال reaction of amines with aldehydes and ketones is a nucleophilic addition in a brain cell واضح؟ انه بعدك followed by elimination على أنه الرأس مرة تبسيط واضح؟ with acids and their derivatives a nucleophilic substitution with alkyl halides برضه nucleophilic substitution", "tokens": [1211, 19452, 45164, 10874, 1829, 8315, 8608, 10721, 1211, 8315, 24793, 2423, 5480, 295, 669, 1652, 365, 16798, 68, 3495, 14792, 293, 14979, 2213, 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"probability": 0.84228515625}, {"start": 1645.52, "end": 1645.84, "word": " brain", "probability": 0.4638671875}, {"start": 1645.84, "end": 1646.08, "word": " cell", "probability": 0.464111328125}, {"start": 1646.08, "end": 1648.3, "word": " واضح؟", "probability": 0.7476806640625}, {"start": 1648.3, "end": 1649.48, "word": " انه", "probability": 0.828857421875}, {"start": 1649.48, "end": 1649.94, "word": " بعدك", "probability": 0.6220703125}, {"start": 1649.94, "end": 1650.26, "word": " followed", "probability": 0.83154296875}, {"start": 1650.26, "end": 1650.6, "word": " by", "probability": 0.9873046875}, {"start": 1650.6, "end": 1651.4, "word": " elimination", "probability": 0.96875}, {"start": 1651.4, "end": 1651.84, "word": " على", "probability": 0.6943359375}, {"start": 1651.84, "end": 1652.1, "word": " أنه", "probability": 0.4769287109375}, {"start": 1652.1, "end": 1652.38, "word": " الرأس", "probability": 0.78173828125}, {"start": 1652.38, "end": 1652.62, "word": " مرة", "probability": 0.491455078125}, {"start": 1652.62, "end": 1653.22, "word": " تبسيط", "probability": 0.66416015625}, {"start": 1653.22, "end": 1654.32, "word": " واضح؟", "probability": 0.9058837890625}, {"start": 1654.32, "end": 1654.7, "word": " with", "probability": 0.7744140625}, {"start": 1654.7, "end": 1655.82, "word": " acids", "probability": 0.76318359375}, {"start": 1655.82, "end": 1656.2, "word": " and", "probability": 0.9599609375}, {"start": 1656.2, "end": 1656.44, "word": " their", "probability": 0.89208984375}, {"start": 1656.44, "end": 1657.18, "word": " derivatives", "probability": 0.94384765625}, {"start": 1657.18, "end": 1658.9, "word": " a", "probability": 0.301025390625}, {"start": 1658.9, "end": 1659.92, "word": " nucleophilic", "probability": 0.948974609375}, {"start": 1659.92, "end": 1660.72, "word": " substitution", "probability": 0.93115234375}, {"start": 1660.72, "end": 1661.08, "word": " with", "probability": 0.80322265625}, {"start": 1661.08, "end": 1661.56, 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"end": 2183.76, "word": " هذه", "probability": 0.73193359375}, {"start": 2183.76, "end": 2184.58, "word": " المركبات", "probability": 0.84661865234375}, {"start": 2184.58, "end": 2185.62, "word": " التمتاز", "probability": 0.94384765625}, {"start": 2185.62, "end": 2186.14, "word": " ان", "probability": 0.69140625}, {"start": 2186.14, "end": 2186.58, "word": " فيها", "probability": 0.916259765625}, {"start": 2186.58, "end": 2187.18, "word": " طرف", "probability": 0.996337890625}, {"start": 2187.18, "end": 2189.48, "word": " polar", "probability": 0.91796875}, {"start": 2189.48, "end": 2191.8, "word": " و", "probability": 0.94189453125}, {"start": 2191.8, "end": 2192.3, "word": " طرف", "probability": 0.8984375}, {"start": 2192.3, "end": 2193.5, "word": " non", "probability": 0.97119140625}, {"start": 2193.5, "end": 2193.98, "word": " polar", "probability": 0.51318359375}], "temperature": 1.0}, {"id": 91, "seek": 220282, "start": 2195.86, "end": 2202.82, "text": "الـ R في الـ fatty acids الـ non-polar الكبير، خلّينا نقول من عشرة و فوق", "tokens": [6027, 39184, 497, 8978, 2423, 39184, 24898, 21667, 2423, 39184, 2107, 12, 12892, 289, 33251, 3555, 13546, 12399, 16490, 1211, 11703, 9957, 995, 8717, 39648, 9154, 6225, 8592, 25720, 4032, 6156, 30543], "avg_logprob": -0.27296401515151514, "compression_ratio": 1.0679611650485437, "no_speech_prob": 0.0, "words": [{"start": 2195.86, "end": 2196.3, "word": "الـ", "probability": 0.703857421875}, {"start": 2196.3, "end": 2196.62, "word": " R", "probability": 0.64453125}, {"start": 2196.62, "end": 2197.52, "word": " في", "probability": 0.8154296875}, {"start": 2197.52, "end": 2197.76, "word": " الـ", "probability": 0.5850830078125}, {"start": 2197.76, "end": 2198.04, "word": " fatty", "probability": 0.344482421875}, {"start": 2198.04, "end": 2198.72, "word": " acids", "probability": 0.6494140625}, {"start": 2198.72, "end": 2199.26, "word": " الـ", "probability": 0.7666015625}, {"start": 2199.26, "end": 2199.4, "word": " non", "probability": 0.64794921875}, {"start": 2199.4, "end": 2199.8, "word": "-polar", "probability": 0.8408203125}, {"start": 2199.8, "end": 2200.82, "word": " الكبير،", "probability": 0.8463134765625}, {"start": 2200.82, "end": 2201.48, "word": " خلّينا", "probability": 0.80966796875}, {"start": 2201.48, "end": 2201.68, "word": " نقول", "probability": 0.994140625}, {"start": 2201.68, "end": 2201.84, "word": " من", "probability": 0.9462890625}, {"start": 2201.84, "end": 2202.28, "word": " عشرة", "probability": 0.87451171875}, {"start": 2202.28, "end": 2202.42, "word": " و", "probability": 0.97021484375}, {"start": 2202.42, "end": 2202.82, "word": " فوق", "probability": 0.6522216796875}], "temperature": 1.0}, {"id": 92, "seek": 222888, "start": 2204.38, "end": 2228.88, "text": "وبناء على ذلك الجزيء بمجمله يغلب عليه الـ non-polar part فبصير water soluble ولا insoluble؟ بصير non-polar طالما صار non-polar صار water insoluble بصير دوب في ال organic solvent إذا هذه الجزيئات اللي فيها القاري الكبيرة هي اللي بنسميها الـ fatty acids", "tokens": [37746, 1863, 16606, 15844, 29910, 23275, 25724, 11622, 1829, 38207, 4724, 2304, 7435, 42213, 3224, 7251, 17082, 46152, 47356, 2423, 39184, 2107, 12, 12892, 289, 644, 6156, 3555, 9381, 13546, 1281, 24807, 638, 49429, 1028, 39754, 638, 22807, 4724, 9381, 13546, 2107, 12, 12892, 289, 23032, 6027, 15042, 20328, 9640, 2107, 12, 12892, 289, 20328, 9640, 1281, 1028, 39754, 638, 4724, 9381, 13546, 11778, 37746, 8978, 2423, 10220, 33575, 11933, 15730, 29538, 25724, 11622, 1829, 19986, 9307, 13672, 1829, 8978, 11296, 25062, 9640, 1829, 33251, 3555, 48923, 39896, 13672, 1829, 44945, 38251, 1829, 11296, 2423, 39184, 24898, 21667], "avg_logprob": -0.2788825865947839, "compression_ratio": 1.6415929203539823, "no_speech_prob": 0.0, "words": [{"start": 2204.38, "end": 2205.06, "word": "وبناء", "probability": 0.794921875}, {"start": 2205.06, "end": 2205.48, "word": " على", "probability": 0.751953125}, {"start": 2205.48, "end": 2206.18, "word": " 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"end": 2221.2, "word": " بصير", "probability": 0.7610677083333334}, {"start": 2221.2, "end": 2221.42, "word": " دوب", "probability": 0.78857421875}, {"start": 2221.42, "end": 2221.58, "word": " في", "probability": 0.92333984375}, {"start": 2221.58, "end": 2221.68, "word": " ال", "probability": 0.71728515625}, {"start": 2221.68, "end": 2222.16, "word": " organic", "probability": 0.83154296875}, {"start": 2222.16, "end": 2222.8, "word": " solvent", "probability": 0.763671875}, {"start": 2222.8, "end": 2223.48, "word": " إذا", "probability": 0.600341796875}, {"start": 2223.48, "end": 2224.54, "word": " هذه", "probability": 0.84130859375}, {"start": 2224.54, "end": 2225.54, "word": " الجزيئات", "probability": 0.95869140625}, {"start": 2225.54, "end": 2225.74, "word": " اللي", "probability": 0.784423828125}, {"start": 2225.74, "end": 2226.12, "word": " فيها", "probability": 0.979248046875}, {"start": 2226.12, "end": 2226.64, "word": " القاري", "probability": 0.6139322916666666}, {"start": 2226.64, "end": 2227.02, "word": " الكبيرة", "probability": 0.8592122395833334}, {"start": 2227.02, "end": 2227.22, "word": " هي", "probability": 0.92138671875}, {"start": 2227.22, "end": 2227.38, "word": " اللي", "probability": 0.96435546875}, {"start": 2227.38, "end": 2227.92, "word": " بنسميها", "probability": 0.8916015625}, {"start": 2227.92, "end": 2228.14, "word": " الـ", "probability": 0.5306396484375}, {"start": 2228.14, "end": 2228.38, "word": " fatty", "probability": 0.8544921875}, {"start": 2228.38, "end": 2228.88, "word": " acids", "probability": 0.80126953125}], "temperature": 1.0}, {"id": 93, "seek": 224219, "start": 2229.49, "end": 2242.19, "text": "فال fatty acids ببساطة هي أحماض كربوكسيلية بسلسلة طويلة وبناء على ذلك أصبحت هذه الأحماض non polar", "tokens": [5172, 6027, 24898, 21667, 4724, 3555, 3794, 41193, 3660, 39896, 5551, 35571, 46958, 9122, 25513, 2407, 4117, 3794, 26895, 10632, 4724, 3794, 1211, 3794, 37977, 23032, 2407, 26895, 3660, 46599, 1863, 16606, 15844, 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"end": 2997.53, "word": " كربون", "probability": 0.9375}, {"start": 2997.53, "end": 2997.65, "word": " و", "probability": 0.98876953125}, {"start": 2997.65, "end": 2997.97, "word": " ميه", "probability": 0.71630859375}, {"start": 2997.97, "end": 2998.15, "word": " و", "probability": 0.9931640625}, {"start": 2998.15, "end": 2998.63, "word": " حرارة", "probability": 0.980712890625}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2999.693, "duration_after_vad": 2875.9274999999875}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/qMxA2LgN_Fc_raw.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/qMxA2LgN_Fc_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d63786d546ffad1946dfdf895f0101f76e774594
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/qMxA2LgN_Fc_raw.srt
@@ -0,0 +1,2208 @@
+1
+00:00:19,570 --> 00:00:26,370
+بسم الله الرحمن الرحيم اليوم ضيلنا أشياء بسيطة في
+
+2
+00:00:26,370 --> 00:00:30,890
+موضوع ال amines قبل ما ننتقل لجزء ال biochemistry
+
+3
+00:00:30,890 --> 00:00:36,850
+طبعا اتفقنا المرة الماضية أن ال amines هم مراكبات
+
+4
+00:00:36,850 --> 00:00:43,470
+ال nitrogen من أهم الأشياء اللي بتميزهم هو وجود
+
+5
+00:00:43,470 --> 00:00:47,730
+إيشالـ lone pair of electrons اللي موجودة على الـ
+
+6
+00:00:47,730 --> 00:00:52,910
+Nitrogens طالما في عليهم lone pair of electrons و
+
+7
+00:00:52,910 --> 00:00:56,150
+ال base is electron donor يعني ال base هي اللي
+
+8
+00:00:56,150 --> 00:01:02,370
+بتعطي إلكترونات فال amines arebasis واضح سبب أنه
+
+9
+00:01:02,370 --> 00:01:06,730
+بالأمينز قواعد هو وجود أزواج الإلكترونات فهم
+
+10
+00:01:06,730 --> 00:01:11,010
+كقاعدة بيعطوا أزواج إلكترونات هذا ضمن تعريف إيش
+
+11
+00:01:11,010 --> 00:01:19,710
+Lewis definition الآن لو إجالهم H plus عندي زوج
+
+12
+00:01:19,710 --> 00:01:23,270
+إلكترونات والـ H مش حاملة إلكترونات شو هيعملوا
+
+13
+00:01:23,270 --> 00:01:28,420
+فيها؟هيتفاعلوا معها هتصير الرابط المتكونة
+
+14
+00:01:28,420 --> 00:01:31,840
+Coordinated Covalent bond بمعنى ان زوجين
+
+15
+00:01:31,840 --> 00:01:37,940
+الالكترونات من النيتروجين والـ H بلس لما تتفاعل
+
+16
+00:01:37,940 --> 00:01:43,340
+معها بتكون مش حاملة الالكترونات ولذلك مثلا هنا
+
+17
+00:01:43,340 --> 00:01:48,380
+ارسملكوا كيف الأمونيا لو اتفاعل معها H بلس لاحظوا
+
+18
+00:01:48,380 --> 00:01:52,990
+الأمونيا الأن H3أساساً الـNitrogen في مداره
+
+19
+00:01:52,990 --> 00:01:57,070
+الخارجي خمس إلكترونات، فلو تخيلتم اللي كانوا
+
+20
+00:01:57,070 --> 00:02:00,470
+باللون الأزرق، تلاتة منهم عملوا روابط مع
+
+21
+00:02:00,470 --> 00:02:03,670
+الـHydrogen، فهذه الرابطة مع الـHydrogen في
+
+22
+00:02:03,670 --> 00:02:07,510
+الأمونيا أصلاً، إلكترون من الـNitrogen وإلكترون من
+
+23
+00:02:07,510 --> 00:02:11,040
+الـHydrogen، اللي بيانه بالأخضركذلك الرابط الثاني
+
+24
+00:02:11,040 --> 00:02:15,520
+والرابط الثالثة بقى عندي زوج إلكترونات إجاله H من
+
+25
+00:02:15,520 --> 00:02:21,180
+الخارج الـH إجت بدون إلكترونات بناء على ذلك الرابط
+
+26
+00:02:21,180 --> 00:02:24,560
+اللي هنا إيش بده تصير Coordinate Covalent bond
+
+27
+00:02:24,560 --> 00:02:29,460
+بمعنى أصلها أنه two electrons from the nitrogen
+
+28
+00:02:29,460 --> 00:02:35,300
+and no electron from hydrogen طبعا هذا بيخلي برضه
+
+29
+00:02:35,300 --> 00:02:41,700
+ال aminesباسيز بمفهوم لوري برونستيد definition
+
+30
+00:02:41,700 --> 00:02:47,240
+ليش؟ لأنه بمفهومه إن الحامض هو اللي بيعطي H plus
+
+31
+00:02:47,240 --> 00:02:53,180
+والباس هي اللي بتكتسب H plus الآن هذه اكتسبت H
+
+32
+00:02:53,180 --> 00:02:57,600
+plus ولا لأ؟ إذا أيضا ضمن تعريف لوري برونستيد
+
+33
+00:02:57,600 --> 00:03:03,860
+definition بتكون هذه base لكن لاحظوا ضمن تعريف
+
+34
+00:03:03,860 --> 00:03:09,080
+Arrheniusإن الـ base لازم يكون فيها OH- الأمونية
+
+35
+00:03:09,080 --> 00:03:13,420
+ما انحسبتش base و لذلك اتدرجوا في تعريفية الأحماض
+
+36
+00:03:13,420 --> 00:03:17,740
+يعني كان أقدم تعريف Arrhenius depression كان حاصر
+
+37
+00:03:17,740 --> 00:03:22,280
+ال bases في المواد ال hydroxides اللي بيعطوا ال OH
+
+38
+00:03:22,280 --> 00:03:29,060
+- بعد إكسرنا نقول لأ هو كل حاجة بتكتسب H plus يمكن
+
+39
+00:03:29,060 --> 00:03:33,960
+أننا نعتبرها base أساسا ال OH- كانت تكتسب H plus و
+
+40
+00:03:33,960 --> 00:03:39,160
+تعمل ميهواضح طب ما الأن H3 كمان بتكتسب جعب H plus
+
+41
+00:03:39,160 --> 00:03:47,280
+واضح الفكرة وإجا اللي هو Lewis definition أكتر
+
+42
+00:03:47,280 --> 00:03:51,440
+تخصيصا وقال أن ال base اللي فيه أزواج إلكترونات
+
+43
+00:03:51,440 --> 00:03:55,340
+مافيش تناقض ما بين التعريفات لكن فيه نظرة أكتر
+
+44
+00:03:55,340 --> 00:04:00,790
+تخصيصيةالان عشانك لو حطينا ال ammonia مع الميه
+
+45
+00:04:00,790 --> 00:04:05,510
+طبعا الميه هنا حاطين ال H3O plus كلكوا عارفين ان
+
+46
+00:04:05,510 --> 00:04:11,070
+الميه ايش هي أساسا H2O لكن هو اتخيل نسبة التأيون
+
+47
+00:04:11,070 --> 00:04:17,430
+اللي هي بسيطة جدا اللي درستها في الميه ان H2O زائد
+
+48
+00:04:17,430 --> 00:04:23,450
+H2O بتفاعل اتزان بطلع نسبة بسيطة جدا من H3O plus
+
+49
+00:04:23,450 --> 00:04:30,600
+زائد OH minusعشان يك هو لما هنا بيكتب h3o plus
+
+50
+00:04:30,600 --> 00:04:36,820
+هالنسبة البسيطة جدا اللي اتكونت من يعني تفاعل
+
+51
+00:04:36,820 --> 00:04:41,950
+الميه مع بعضها، اذا هنا ايش بتفترض انه موجود؟هو H
+
+52
+00:04:41,950 --> 00:04:46,770
+minus كمان ولذلك لما تيجي الأمونيا من الميه هدم ال
+
+53
+00:04:46,770 --> 00:04:52,590
+H3O plus تاخد ال H plus تعمل ان H4 plus زاد H2O هو
+
+54
+00:04:52,590 --> 00:04:57,370
+أساسا في ايون موجب بكل حاله لأ هو الموجب كان معاه
+
+55
+00:04:57,370 --> 00:05:02,330
+سالب الآن لما صارت الأمونيوم ايون هانا موجب ايش
+
+56
+00:05:02,330 --> 00:05:07,500
+صار معاه؟سالم و لذلك احنا سنقول ان الامونيا لما
+
+57
+00:05:07,500 --> 00:05:14,600
+ندوبها في الميه بتعطي امونيوم هيدروكسيد واضح؟ الكل
+
+58
+00:05:14,600 --> 00:05:19,220
+بيعرف ان احنا بندوب الامونيا في الميه بتعطي ايش؟
+
+59
+00:05:19,220 --> 00:05:23,750
+امونيوم هيدروكسيدكذلك الحالة لو دوبنا ال ammonia
+
+60
+00:05:23,750 --> 00:05:29,390
+مثلا في ال HCl ال ammonia هتاخد H من هنا هصير عندى
+
+61
+00:05:29,390 --> 00:05:34,510
+ammonium ion مع ال Cl minus ammonium chloride يمكن
+
+62
+00:05:34,510 --> 00:05:39,130
+هذا ما معاكم في المدرسة انه بإمكاننا احنا نجيب
+
+63
+00:05:39,130 --> 00:05:44,180
+نقطةمن ال ammonia من محلول ال ammonia نحطها هنا
+
+64
+00:05:44,180 --> 00:05:49,760
+نقطة من ال HCl نحطه هنا و نسيبهم جانب بعض بتتبخر
+
+65
+00:05:49,760 --> 00:05:53,860
+.. بتتبخر ال ammonia بتتبخر ال HCl لما يلتجوا مع
+
+66
+00:05:53,860 --> 00:05:57,620
+بعض ال ammonia مع ال HCl شو هيعملوا؟ ammonium
+
+67
+00:05:57,620 --> 00:06:02,660
+chloride ال ammonium chloride إيش لونه؟
+
+68
+00:06:02,660 --> 00:06:08,310
+تذكروا شغل المدرسة؟أبيض و لذلك كنا نقول أنه ال
+
+69
+00:06:08,310 --> 00:06:12,810
+ammonia مع ال HCl بيعطوا سحب بيضاء من ال ammonium
+
+70
+00:06:12,810 --> 00:06:18,820
+chloride بهذا النص مرت عليكم في المدرسة ولا لأ؟سحب
+
+71
+00:06:18,820 --> 00:06:23,780
+.. سحب بيضاء أو بقعة بيضة هم عادة بيعملوها .. عادة
+
+72
+00:06:23,780 --> 00:06:28,660
+بيعملوا هذه الشغلة كتجربة .. كتجربة بيجيبوا انبوبة
+
+73
+00:06:28,660 --> 00:06:32,500
+بهذا الشكل بيجيبوا انبوبة زجاجية مفتوحة الطرفين
+
+74
+00:06:32,500 --> 00:06:38,270
+بهذا الشكل بيحطوا هنا نقطة أمونياو بيحطوا هان طبعا
+
+75
+00:06:38,270 --> 00:06:41,090
+أمونيا البعض هيقوللي غاز أمونيا مدور باب ميه
+
+76
+00:06:41,090 --> 00:06:44,970
+أمونيا ميكروفسيت بيطلع أمونيا واضح؟ و بيحطوا هنا
+
+77
+00:06:44,970 --> 00:06:49,430
+HCl الآن بيمشوا بتبخر الغازين هذا بتبخر و هذا
+
+78
+00:06:49,430 --> 00:06:53,570
+بتبخر و سرعته بتعتمد على ال molecular weight تبعه
+
+79
+00:06:53,570 --> 00:06:58,050
+اللي ال molecular weight تبعه الجيل بيمشي إيش بطيء
+
+80
+00:06:58,050 --> 00:07:00,890
+فهذا بيمشي له شوية هنا هذا بيمشي له شوية هنا لما
+
+81
+00:07:00,890 --> 00:07:05,280
+بيلتقواإيش بدهم يعملوه اموريو ميكلورايت فجأة
+
+82
+00:07:05,280 --> 00:07:09,640
+بيصيروا الناس يشوفوا هنا إيش ابخرة بيضاء واضح
+
+83
+00:07:09,640 --> 00:07:15,310
+بيصيروا يشوفوا ابخرة بيضاء هذه الأبخرة هيالأمونيوم
+
+84
+00:07:15,310 --> 00:07:19,250
+كلورايت لو انتوا بتاخدوا معمل general chemistry
+
+85
+00:07:19,250 --> 00:07:22,410
+بتكون تجربة بتعملواها بتجيبوا الأنبوبة و بتحطوهم
+
+86
+00:07:22,410 --> 00:07:27,450
+بتشوفوا بعينكم و عشان دائما بنقول التعليم الجامعي
+
+87
+00:07:27,450 --> 00:07:32,150
+لا يجب أن ينفصل بحال من الأحوال اللي عاملة عن
+
+88
+00:07:32,150 --> 00:07:36,290
+الجزء النظري في أي خطة تدريسية
+
+89
+00:07:40,010 --> 00:07:45,710
+طالما قلنا ان ال amines are bases معناه ذلك زي ما
+
+90
+00:07:45,710 --> 00:07:50,130
+ال acids كنا نقول عنهم acids ويلهم BKA ال amines
+
+91
+00:07:50,130 --> 00:07:57,350
+بيكونيلهم BKB واضح؟ BKB وقلنا كل ما كانت في ال
+
+92
+00:07:57,350 --> 00:08:02,150
+acids ال BKA أقل كل ما كان الحامض أقوى الآن في ال
+
+93
+00:08:02,150 --> 00:08:07,530
+bases بنقول كل ما ال BKB بتكون أقل كل ما القاعدة
+
+94
+00:08:07,530 --> 00:08:12,460
+أيضا بتكون أقوى واضح؟الجدول اللى موجود عندنا حقيقة
+
+95
+00:08:12,460 --> 00:08:22,240
+مش كاتبنا ال BKB كاتب ال BKA ل ال conjugate acid
+
+96
+00:08:22,240 --> 00:08:26,700
+conjugate acid يعني الحمض المرافق عادة بين ال acid
+
+97
+00:08:26,700 --> 00:08:32,620
+و ال base المرافقة بيكون الفرق إيش؟هيدروجين يعني
+
+98
+00:08:32,620 --> 00:08:38,560
+انا لما بدي اقول nh4 plus هذا الاسل ال base
+
+99
+00:08:38,560 --> 00:08:45,500
+المرافقة nh3 و هكذا بناء على ذلك هدولة اللي بيكي
+
+100
+00:08:45,500 --> 00:08:53,100
+ايه و بيكي بيه كلنا عارفين ان بيكي ايهزائد ال BKB
+
+101
+00:08:53,100 --> 00:08:59,420
+بساوي 14 بناء على ذلك لو احنا كنا لهذه المجموعة من
+
+102
+00:08:59,420 --> 00:09:07,300
+ال Amines بدنا نشوف ال BKB بدنا نطرح من 14 يعني
+
+103
+00:09:07,300 --> 00:09:13,900
+مثلا لل Ammonia ال BKB أربعة و سبعة للميث الأمين
+
+104
+00:09:15,270 --> 00:09:21,390
+تلاتة و أربعة بالعشرة نفترض للضايف مثل أميل تلاتة
+
+105
+00:09:21,390 --> 00:09:25,870
+و تلاتة بالعشرة لو أجينا مقارنة مثلا مع الأنليل
+
+106
+00:09:25,870 --> 00:09:34,290
+حوالي تسعة و أربعة بالعشرةالان لو اجينا للان مثل
+
+107
+00:09:34,290 --> 00:09:40,410
+الأللين ايضا حوالي تسعة و اتنين بالعشرة الان
+
+108
+00:09:40,410 --> 00:09:46,010
+لاحظوا ع طول ملاحظة الأمينز اللي في الأول مثل أمين
+
+109
+00:09:46,010 --> 00:09:51,890
+ضاي مثل أمين و لحد الأللين هنا صار عندى تغير كتير
+
+110
+00:09:51,890 --> 00:09:57,550
+يعني لحد هدولة كلهمكانت ال بي كي بي قليلة تلاتة
+
+111
+00:09:57,550 --> 00:10:03,130
+تلاتة أربعة لما صرت فيه الانليل و التوابع صرت تسعة
+
+112
+00:10:03,130 --> 00:10:09,030
+الان هدول ايش بيفرقوا عن بعض لحد هذا الخط هدول
+
+113
+00:10:09,030 --> 00:10:14,510
+اللي فوق aliphatic amines اللي تحت aromatic amines
+
+114
+00:10:14,510 --> 00:10:22,190
+واضح؟ اذا هذه منطقاتالالفاتك أمين هذي منطقة ال
+
+115
+00:10:22,190 --> 00:10:27,870
+aromatic amines لو إجينا سألنا مين بيكونوا ك basis
+
+116
+00:10:27,870 --> 00:10:33,430
+أقوى الالفاتك أمين ولا ال aromatic amines؟
+
+117
+00:10:33,430 --> 00:10:40,000
+الالفاتك أمينليش؟ لأنه كل ما ال BKB بتكون أقل كل
+
+118
+00:10:40,000 --> 00:10:45,500
+ما كانت القاعدة أقوى، إذا ال aliphatic amines are
+
+119
+00:10:45,500 --> 00:10:50,460
+stronger bases than aromatic amines، يعني لما نجيب
+
+120
+00:10:50,460 --> 00:10:54,740
+ال QA سؤال صح و غلط ال aliphatic amines are فراغ
+
+121
+00:10:54,740 --> 00:11:00,120
+bases than aromatic amines، they arestronger basis
+
+122
+00:11:00,120 --> 00:11:05,660
+هذا عرفناها، الآن بعد كمان ممكن نكمل لكم، نقولكم
+
+123
+00:11:05,660 --> 00:11:14,120
+إيش ال due to بسبب إيش؟ ليش بدنا نحكي غلط؟ بدنا
+
+124
+00:11:14,120 --> 00:11:19,180
+نحكي غلط؟ ليش ال aliphatic a means
+
+125
+00:11:22,420 --> 00:11:27,220
+أقوى كقواعد من ال aromatic amines بهمش بدي أعلق
+
+126
+00:11:27,220 --> 00:11:32,260
+على الخطأ اللي عملته بدي أعلق على الخطأ اللي عملته
+
+127
+00:11:32,260 --> 00:11:38,140
+عشان ما تكرروهش رجاء انا لما بقول انه بسبب فواحدة
+
+128
+00:11:38,140 --> 00:11:44,020
+جالتلي ع طول بسبب ال BKB هذا الكلام غير بقبول منكم
+
+129
+00:11:44,020 --> 00:11:48,400
+انا لما قرأت ال BKB
+
+130
+00:11:50,390 --> 00:11:54,430
+لقيت هذه جليلة و هذه عالية قولت ال aromatic amines
+
+131
+00:11:54,430 --> 00:12:00,510
+أقوى من ال aromatic amines زي ما أجي على اتنين بني
+
+132
+00:12:00,510 --> 00:12:04,830
+أدمين أطفال against طولهم هذا طوله متر و هذا طوله
+
+133
+00:12:04,830 --> 00:12:10,750
+سبعين الآن اللي طوله متر بقول عنه أطول من اللي
+
+134
+00:12:10,750 --> 00:12:15,230
+طوله سبعين الان لما أقولكم ليش ماحدش يقوللي أنه
+
+135
+00:12:15,230 --> 00:12:20,930
+طوله مترthis is nonsense ممكن تقولولي لأنه في
+
+136
+00:12:20,930 --> 00:12:25,730
+العمر أكبر يمكن يكون هذا السبب هذا بيصير سبب لو
+
+137
+00:12:25,730 --> 00:12:29,670
+اتنين بنفس العمر ممكن تقولولي وراثيا هذا كل أسر
+
+138
+00:12:29,670 --> 00:12:33,750
+تطويل هذا أسر .. هيك بيصير سبب بس إن أجيب لقياسه
+
+139
+00:12:33,750 --> 00:12:38,410
+وأقول عنه سبب بسبب ال BKB لو أنا أساسا استنتجت أن
+
+140
+00:12:38,410 --> 00:12:43,790
+هذا أقوى من هذا لأن ال BKB هنا أقل من هنا إذا هذا
+
+141
+00:12:43,790 --> 00:12:44,270
+أقوى
+
+142
+00:12:47,630 --> 00:12:55,650
+بدي كلام إيش؟ بدي كلام كيمية طبعا معنى بيس إنه
+
+143
+00:12:55,650 --> 00:12:59,650
+بتعطي إلكترونات إذا للسبب شيء يمنع من إعطاء
+
+144
+00:12:59,650 --> 00:13:06,400
+الإلكترونات أو يقلل إعطاء الإلكترونات، واضح؟السبب
+
+145
+00:13:06,400 --> 00:13:10,740
+شيء يمنع أو يقلل من إعطاء الإلكترونات هذا السبب
+
+146
+00:13:10,740 --> 00:13:14,400
+فعلا ممكن يكون inductive effect و فعلا ممكن يكون
+
+147
+00:13:14,400 --> 00:13:18,980
+resonance effect في حالة ال aliphatic amines وهي
+
+148
+00:13:18,980 --> 00:13:23,820
+بالقاري المركبين بيشيبوا بعض القليلين مثلا ال BKA
+
+149
+00:13:23,820 --> 00:13:27,740
+تبعت الحامض المرافق له أربعة و ستة يعني ال BKB
+
+150
+00:13:27,740 --> 00:13:33,980
+تبعته جداشتسعة وأربعة هانا لل .. لل Cyclohex
+
+151
+00:13:33,980 --> 00:13:39,400
+الأمين، هذا ألفتك، مافي double bonds، Cyclic
+
+152
+00:13:39,400 --> 00:13:43,700
+alkanes are ألفتك، هذا كدهش؟ أربعة واتنين، مين
+
+153
+00:13:43,700 --> 00:13:48,730
+كباس أقوى؟ ال Cyclohex الأمين ولا الألليين؟الـ
+
+154
+00:13:48,730 --> 00:13:53,770
+Cyclohexane الأمين أقوى الآن السبب أن هذا زوج
+
+155
+00:13:53,770 --> 00:13:58,830
+الإلكترونات بدل ما يكون جاهز يطلع برا و يتفاعل برا
+
+156
+00:13:58,830 --> 00:14:04,310
+قاعد بيعمل resonance جوا الجزء هذا زوج الإلكترونات
+
+157
+00:14:04,310 --> 00:14:09,660
+بيطلع للخارججاهز إنه يُعطى للخارج و ال base هي
+
+158
+00:14:09,660 --> 00:14:15,220
+اللي بتعطي إيش إلكترونات فهذا بدل ما يروح للخارج و
+
+159
+00:14:15,220 --> 00:14:20,640
+يظهر قوة المركب ك base قاعد بيجي بلوف هنا و بيعمل
+
+160
+00:14:20,640 --> 00:14:24,360
+resonance .. resonance تاني بيصير مرة minus على ال
+
+161
+00:14:24,360 --> 00:14:26,420
+carbon مرة على ال carbon التاني مرة على ال carbon
+
+162
+00:14:26,420 --> 00:14:32,020
+التالتة إذا هو قاعد المجهود تبع وين؟ جوا الجزء
+
+163
+00:14:32,020 --> 00:14:37,990
+فبالنسبة للخارجهو لا يعطي إلكترونات هو قاعد بيعمل
+
+164
+00:14:37,990 --> 00:14:41,990
+resonance جوا الجزئ فما بيعطي إلكترونات للخارج ال
+
+165
+00:14:41,990 --> 00:14:46,870
+basic اللي بتعطي إلكترونات لمن؟ للخارج هذا إذا
+
+166
+00:14:46,870 --> 00:14:51,650
+بيكون سبب .. هذا بيكون سبب اللي هو ليش ال alphatic
+
+167
+00:14:51,650 --> 00:14:54,850
+amines are more basic than aromatic amines because
+
+168
+00:14:54,850 --> 00:15:01,710
+of resonance تمام؟ الآن البعض منكم اتكلم كلمة جيدة
+
+169
+00:15:01,710 --> 00:15:08,080
+قال ال inductive effectممكن يكون في مكان تاني غير
+
+170
+00:15:08,080 --> 00:15:12,840
+هذا الان حتى نفهم ال inductive effect حتى نفهم ال
+
+171
+00:15:12,840 --> 00:15:18,200
+inductive effect جيدا انتوا بتكونوا تتخيلوا
+
+172
+00:15:18,200 --> 00:15:26,720
+نيتروجين و عليها زوج إلكترونات و تلت روابط تمام؟
+
+173
+00:15:26,720 --> 00:15:32,040
+إيش اللي ممكن يزيد القاعدية تبعتها و إيش اللي ممكن
+
+174
+00:15:32,040 --> 00:15:41,510
+ينجس؟أي مجموعة تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+175
+00:15:41,510 --> 00:15:48,750
+تقدر تقدر تقدر
+
+176
+00:15:48,750 --> 00:15:49,430
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+177
+00:15:49,430 --> 00:15:49,450
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+178
+00:15:49,450 --> 00:15:49,570
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+179
+00:15:49,570 --> 00:15:49,690
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+180
+00:15:49,690 --> 00:15:49,710
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+181
+00:15:49,710 --> 00:15:53,850
+تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر تقدر
+
+182
+00:15:53,850 --> 00:16:02,860
+تقدر تقدر تincreases basicity لأنه زدت كمية
+
+183
+00:16:02,860 --> 00:16:12,420
+الإلكترونات increases او increase basicity الان لو
+
+184
+00:16:12,420 --> 00:16:18,380
+كان عندى electron with drawing groups with drawing
+
+185
+00:16:18,380 --> 00:16:24,220
+مجموعات ساحبة للإلكترونات يعني إذا أنا عندى كمية
+
+186
+00:16:24,220 --> 00:16:28,740
+الإلكترونات إجت أشياء ساحبتهاإيش هيعمله في ال
+
+187
+00:16:28,740 --> 00:16:37,240
+basicity؟ decrease basicity واضحة الفكرة المجموعات
+
+188
+00:16:37,240 --> 00:16:41,300
+المعطية للإلكترونات بتزيد كمية الإلكترونات بتزيد
+
+189
+00:16:41,300 --> 00:16:46,080
+الإعقاء بتزيد القاعدية المجموعات الساحبة تقلل كمية
+
+190
+00:16:46,080 --> 00:16:50,640
+الإلكترونات تقلل ما يُعطى للخارج وبالتالي تقلل
+
+191
+00:16:50,640 --> 00:16:55,480
+إيش؟ القاعدية واضحة هذه الفكرة؟ واضحة؟
+
+192
+00:17:01,610 --> 00:17:06,190
+طبعا هتلاحظوا القمر هنا عكس ايش ال acidity للناس
+
+193
+00:17:06,190 --> 00:17:12,530
+اللي بدهم ينتبهوا ويعملوا مقارنة خلينا نعطي مثال
+
+194
+00:17:12,530 --> 00:17:21,590
+لو اجيت انا اعطيت هدولة المثالين F الأمين لاحظوا
+
+195
+00:17:21,590 --> 00:17:27,020
+هاي ال F الأمين وين زوج ال electronic اللي عليهعلى
+
+196
+00:17:27,020 --> 00:17:35,580
+الـ Nitrogen و أعطيت Chloroethelamine هاي
+
+197
+00:17:35,580 --> 00:17:41,040
+أنا فيه الاتنين Aliphatic واضح بطلت الفكرة
+
+198
+00:17:41,040 --> 00:17:44,800
+Aliphatic و Aromatic الاتنين إيش مالهم؟ Aliphatic
+
+199
+00:17:44,800 --> 00:17:50,160
+مين بدو يكون stronger base بالتجربة الـ Ethelamine
+
+200
+00:17:50,160 --> 00:17:57,430
+أقوى من الchloroethelamine الآن إيش السبب؟اه هنا
+
+201
+00:17:57,430 --> 00:18:03,010
+في عندى CL، إيش بتعمل ال CL في الإلكترونات؟ بتسحب
+
+202
+00:18:03,010 --> 00:18:06,810
+الإلكترونات، يعني لو افترضتوا كانت كمية
+
+203
+00:18:06,810 --> 00:18:10,870
+الإلكترونات كرقم عشوائي، هنا عشرة، ال CL سحبت إلى
+
+204
+00:18:10,870 --> 00:18:14,190
+منهم اتنين، صف يوجد إيش؟ تمانية، إذا وين
+
+205
+00:18:14,190 --> 00:18:20,630
+الإلكترونات أكثر؟أه بينما لاحظ لو إجيت أنا حطيت
+
+206
+00:18:20,630 --> 00:18:24,730
+مثل و مثل بيعطوا إلكترونات شو بده يصير لل BCCT؟
+
+207
+00:18:24,730 --> 00:18:31,290
+بده يزيد إذا المجموعات الساحبة تقلل القاعدية
+
+208
+00:18:31,290 --> 00:18:36,530
+والمجموعات المعطية تزيد القاعدية طبعا بشرط إنكوا
+
+209
+00:18:36,530 --> 00:18:40,550
+لما تعملوا المقارنات قارنوا أشياء متحدة من جوانب
+
+210
+00:18:40,550 --> 00:18:44,210
+أخرى يعني أنا لما عملت هذه المقارنة ساحب ومعطي
+
+211
+00:18:44,210 --> 00:18:49,850
+قارنت ألفتكممكن اكرر العملية اقارن aromatic مع
+
+212
+00:18:49,850 --> 00:18:56,350
+aromatic يعني لو اخدت الانيلين والنيتروانيلين
+
+213
+00:18:56,350 --> 00:19:02,830
+والميثلانيلين اللي هو البراتوليدين اسمه الآن هدول
+
+214
+00:19:02,830 --> 00:19:06,150
+التلاتة فيهم resonance إذا ال resonance مش هيكون
+
+215
+00:19:06,150 --> 00:19:10,030
+هو السبب وهدول التلاتة القاعدية تبعتهم من ناحية
+
+216
+00:19:10,030 --> 00:19:12,550
+المبدأ قليلة
+
+217
+00:19:13,930 --> 00:19:17,630
+ليش؟ لأنه فيهم resonance لكن في القاعدية القليلة
+
+218
+00:19:17,630 --> 00:19:20,850
+واحد منهم أقل من التاني أقل من التالت يعني التلاتة
+
+219
+00:19:20,850 --> 00:19:27,310
+ك basis إضعاف لكن في واحد أفضل من التاني أفضل من
+
+220
+00:19:27,310 --> 00:19:31,970
+التالت الآن خلّينا نيجي نتطلع المثل كمجموعة شو
+
+221
+00:19:31,970 --> 00:19:37,890
+بتعمل؟ بتعطي إلكترونات إذا معنا الإلكترونات بـ 0
+
+222
+00:19:37,890 --> 00:19:44,130
+الـ H نعتبرها متعادلة الـ Nitroبتسحب، إذا وين أعلى
+
+223
+00:19:44,130 --> 00:19:51,430
+الإلكترونات؟ في الميثلانيلين، بعده الانيلين، بعده
+
+224
+00:19:51,430 --> 00:19:57,870
+النيترو، فك basis الميثلانيلين أعلى من الانيلين،
+
+225
+00:19:57,870 --> 00:20:02,350
+أعلى من النيتروانيلين، الآن هنا لما ابدأ أقول شو
+
+226
+00:20:02,350 --> 00:20:10,330
+السبب؟ ال inductive effectطبعاً بشكل عام كلهم
+
+227
+00:20:10,330 --> 00:20:17,630
+يعتبروا ضعاف، ليش؟ لأن كلهم فيهم resonance، كلهم
+
+228
+00:20:17,630 --> 00:20:21,050
+يعتبروا ك basis ضعاف، لكن واحد أضعف من التاني أضعف
+
+229
+00:20:21,050 --> 00:20:26,610
+من التالت، الأن فرق الضعف اللي بين لضعاف أساساً
+
+230
+00:20:26,610 --> 00:20:31,670
+بسبب إيش؟ ال inductive effectلكن لو أنا باجي
+
+231
+00:20:31,670 --> 00:20:38,370
+بسألكم والله بشكل عام ال nitroaniline is a weak
+
+232
+00:20:38,370 --> 00:20:45,560
+base، ليش؟ هتقولولي ال resonance مصيبة؟و الحاجات
+
+233
+00:20:45,560 --> 00:20:50,980
+هم صيبة تانية ال nitro يعني صار سبب ضعفه شغل فيه
+
+234
+00:20:50,980 --> 00:20:55,280
+ال resonance و ال inductive effect لكن لو كنت بدأ
+
+235
+00:20:55,280 --> 00:20:58,500
+اقارنه مثلا مع ال methyl aniline لأ بقول ما هو ال
+
+236
+00:20:58,500 --> 00:21:01,720
+resonance و ال resonance هم عامل مشترك بطل هو اللي
+
+237
+00:21:01,720 --> 00:21:07,920
+مفرج صار إيش اللي مفرج؟ شكل أساسي ال inductive
+
+238
+00:21:07,920 --> 00:21:09,940
+effect واضحة الفكرة؟
+
+239
+00:21:17,860 --> 00:21:23,620
+أخر شغلة في هذا الفصل، لو قلنا تفاعلات الـ Amines،
+
+240
+00:21:23,620 --> 00:21:28,240
+تفاعلات الـ Amines مروا علينا بدل المر ألف طالما
+
+241
+00:21:28,240 --> 00:21:33,140
+في زوج إلكترونات، إذا الـ Amines بيعملوا as الـ
+
+242
+00:21:33,140 --> 00:21:39,880
+Eucleophiles، واضح؟إذا بدكم تحكوا عن الكليهيليتز،
+
+243
+00:21:39,880 --> 00:21:44,120
+بتفعلوا كنيكليوفييل، إذا بدكم تحكوا عن الديهيد
+
+244
+00:21:44,120 --> 00:21:48,260
+وكيتون، بتفعلوا كنيكليوفييل، إذا بدكم تحكوا عن
+
+245
+00:21:48,260 --> 00:21:52,660
+كاربوكسيليك أسيتس ومشتقاتها، بتفعلوا كنيكليوفييل،
+
+246
+00:21:52,660 --> 00:21:56,280
+وكل الأمثلة مرت علينا، الآن مع الالكليهيليتز
+
+247
+00:21:56,280 --> 00:22:00,700
+بيعملوا النيكليوفيليك سبستيوشن، مع الديهيدس وكيتون
+
+248
+00:22:01,680 --> 00:22:06,140
+بيعملوه الـ Eucleophilic addition مع الـ E stars
+
+249
+00:22:06,140 --> 00:22:10,340
+ومشتقاتها بيعملوه مرة تانية الـ Eucleophilic
+
+250
+00:22:10,340 --> 00:22:14,900
+substitution يعني هاي نشوف عدة أمثلة هاي هذا أمين
+
+251
+00:22:14,900 --> 00:22:20,260
+RNH2 مع أسد الكلورايد هاي الـ Eucleophile هاجم طرد
+
+252
+00:22:20,260 --> 00:22:24,360
+الـ Cl هذا عبارة عن إيش الـ Eucleophilic
+
+253
+00:22:24,360 --> 00:22:29,520
+substitution على أسد الكلورايد هذا primary أمين طب
+
+254
+00:22:29,520 --> 00:22:33,230
+لو secondary أمينبرضه الـ Eucleophilic
+
+255
+00:22:33,230 --> 00:22:38,230
+Substitution على أسد إكلورايد مافيش فيها إشي لو
+
+256
+00:22:38,230 --> 00:22:41,710
+شوفناه مُركّب تاني برضه هذا سكندريامين مع أسد
+
+257
+00:22:41,710 --> 00:22:46,590
+إكلورايد الـ Eucleophilic Substitution لو شوفنا
+
+258
+00:22:46,590 --> 00:22:51,150
+أنيلين مع أسد أنهيدرايد بده يهاجمها نطوط رد هادي
+
+259
+00:22:51,150 --> 00:22:55,850
+الـ Eucleophilic Substitution واضح؟ كل هذه
+
+260
+00:22:55,850 --> 00:22:59,250
+التفاعلات حقيقة سبع
+
+261
+00:23:00,470 --> 00:23:07,030
+ومرت علينا في أي منطقة لما اتكلمنا على الأحماط
+
+262
+00:23:07,030 --> 00:23:13,130
+ومشتقاتها ربما البعض يقول طيب ذكرنا بأمثلة على ال
+
+263
+00:23:13,130 --> 00:23:16,630
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+264
+00:23:16,630 --> 00:23:17,190
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+265
+00:23:17,190 --> 00:23:17,190
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+266
+00:23:17,190 --> 00:23:17,570
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+267
+00:23:17,570 --> 00:23:24,530
+ال ال ال ال ال
+
+268
+00:23:24,530 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+269
+00:23:29,470 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+270
+00:23:29,470 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+271
+00:23:29,470 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+272
+00:23:29,470 --> 00:23:29,470
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+273
+00:23:29,470 --> 00:23:29,490
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+274
+00:23:31,660 --> 00:23:42,460
+CH3 CH2 NH2 هذا primary امين زائد هذا المركب و
+
+275
+00:23:42,460 --> 00:23:49,980
+حامل هنا ب R هذا يعتبر ايش الكلهيلايت هذا في
+
+276
+00:23:49,980 --> 00:23:53,520
+النهاية الكلهيلايت و لو حلقة خمسية كيف هتعملوا
+
+277
+00:23:56,960 --> 00:24:03,400
+واضح؟ وطالما الـ nucleophile neutral كمحص لإيش
+
+278
+00:24:03,400 --> 00:24:11,020
+هيكون؟ يفقد CH2 CH3 أكيد الـ H اللي فقدها مع ال PR
+
+279
+00:24:11,020 --> 00:24:17,940
+إيش هتعمل؟ HPR هذا من chapter 6 الـ nucleophilic
+
+280
+00:24:17,940 --> 00:24:22,820
+substitution ofAlkyl Halides الوثيقة الوثيقة
+
+281
+00:24:22,820 --> 00:24:27,820
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+282
+00:24:27,820 --> 00:24:30,180
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+283
+00:24:30,180 --> 00:24:31,120
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+284
+00:24:31,120 --> 00:24:31,460
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+285
+00:24:31,460 --> 00:24:36,880
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+286
+00:24:36,880 --> 00:24:41,160
+الوثيقة
+
+287
+00:24:41,160 --> 00:24:45,820
+الوثيقة
+
+288
+00:24:45,820 --> 00:24:47,480
+الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة الوثيقة
+
+289
+00:24:47,480 --> 00:24:49,140
+الوثيقة الوثيقة الوثيقة الوثيناخد كمان مرنو
+
+290
+00:24:49,140 --> 00:24:53,960
+سايكليك كيتون او الديهايد هى C double bond O C
+
+291
+00:24:53,960 --> 00:25:01,580
+double bond O زائد CH3 CH2
+
+292
+00:25:01,580 --> 00:25:08,720
+NH2 تخيلوا اجتكوا اكمل هذه المعادلة كيف هتكملوها؟
+
+293
+00:25:08,720 --> 00:25:12,260
+اه بدكم اتهاجموها على ال الديهايد او ال كيتون و
+
+294
+00:25:12,260 --> 00:25:16,540
+هذه تصير OH اذا للناتج اللى عندى
+
+295
+00:25:22,140 --> 00:25:30,100
+بدي يصير عندى OH OHANA NH
+
+296
+00:25:30,100 --> 00:25:39,120
+CH2 CH3 مش هذا اللي بدي يصير لكن الطالب الشاطر
+
+297
+00:25:39,120 --> 00:25:45,900
+اتعلمت كمان شغلة ان هذا هو تفاعل ل nucleophilic
+
+298
+00:25:45,900 --> 00:25:46,780
+addition
+
+299
+00:25:49,140 --> 00:25:54,660
+هذا هو تفاعل الـ Eucleophilic addition الآن مع ال
+
+300
+00:25:54,660 --> 00:25:58,600
+amines لما تكون ال H و ال OH جانب بعض، ايش
+
+301
+00:25:58,600 --> 00:26:05,460
+اتعلمنا؟ بيروح و بيفقد جزء ماء و بعمل double bond
+
+302
+00:26:08,450 --> 00:26:12,470
+قولنا احنا كل N H2 مع C double bond O ماصيرها
+
+303
+00:26:12,470 --> 00:26:17,130
+النهائي C double bond O الديهيد او كيتون تصير C
+
+304
+00:26:17,130 --> 00:26:23,790
+double bond N CH2 CH3 بصير ال shift basis وقولنا
+
+305
+00:26:23,790 --> 00:26:27,590
+ان التفاعل بهذه الحالة ايش بنقول عنه addition
+
+306
+00:26:27,590 --> 00:26:30,370
+elimination
+
+307
+00:26:31,670 --> 00:26:35,830
+نسيته تفاعل تكوين الأكزينز والهيدرازونز والسمي
+
+308
+00:26:35,830 --> 00:26:39,570
+كربازونز كل ال N-H2 مع ال C double bond O
+
+309
+00:26:39,570 --> 00:26:43,410
+الديهيدوكيتون كانت تعمل C double bond N على خطوتين
+
+310
+00:26:43,410 --> 00:26:51,100
+لكن في الأساس أن الأمين تفاعل كإيش؟كان uqlu5 وعمل
+
+311
+00:26:51,100 --> 00:26:54,760
+addition الان بعد هيك ان ال addition اتبع ال
+
+312
+00:26:54,760 --> 00:26:58,960
+elimination هذا امر ايش تاني هذا المحصلة النهائية
+
+313
+00:26:58,960 --> 00:27:03,480
+لكن ال addition ادشن و ال uqlu5 ال uqlu5 فال
+
+314
+00:27:03,480 --> 00:27:09,240
+amines تفاعلهم الأساسي بنقول هو ايش they react as
+
+315
+00:27:09,240 --> 00:27:14,480
+uqlu5 as uqlu5 واضح؟
+
+316
+00:27:16,420 --> 00:27:20,000
+لكن لو جينا سألناكم ال reaction of amines with
+
+317
+00:27:20,000 --> 00:27:25,120
+aldehydes and ketones is a nucleophilic addition
+
+318
+00:27:25,120 --> 00:27:30,600
+in a brain cell واضح؟ انه بعدك followed by
+
+319
+00:27:30,600 --> 00:27:34,700
+elimination على أنه الرأس مرة تبسيط واضح؟ with
+
+320
+00:27:34,700 --> 00:27:39,920
+acids and their derivatives a nucleophilic
+
+321
+00:27:39,920 --> 00:27:44,620
+substitution with alkyl halides برضه nucleophilic
+
+322
+00:27:44,620 --> 00:27:45,840
+substitution
+
+323
+00:27:56,390 --> 00:28:01,410
+بهيك بنكون خلصنا الفكرة أو الكلام المختصر اللى
+
+324
+00:28:01,410 --> 00:28:07,510
+بنشرحه عن ال amines و
+
+325
+00:28:07,510 --> 00:28:11,670
+بنلتقل مباشرة
+
+326
+00:28:11,670 --> 00:28:15,970
+لفصل
+
+327
+00:28:15,970 --> 00:28:22,850
+الخامس عشر اللى هو يعتبر بداية ال general
+
+328
+00:28:22,850 --> 00:28:28,890
+biochemistry اللى بنحكي عنهاlimits and detergents
+
+329
+00:28:28,890 --> 00:28:37,110
+limits and detergents الان ال limits معناها
+
+330
+00:28:37,110 --> 00:28:41,190
+بالعربي الدهون اش
+
+331
+00:28:41,190 --> 00:28:50,630
+اللي تلغيه ال libidab اسمها ال libidab دهون اه في
+
+332
+00:28:50,630 --> 00:28:55,570
+مشكلة عندكوا في الورق؟أنا عند ال slides خلص و أنت
+
+333
+00:28:55,570 --> 00:29:07,090
+عندك إشي؟ من وين صورته؟ أي شباته؟ مالغيين
+
+334
+00:29:07,090 --> 00:29:13,300
+هدولة، مشيولين عن .. مش موجودين في الزمالةلأ لأ
+
+335
+00:29:13,300 --> 00:29:18,440
+هدولة ال slides اللي معكم زيادة فيهم بس كلمة واحدة
+
+336
+00:29:18,440 --> 00:29:22,940
+احنا شرحناها كتابة how to prepare phenol هي اللي
+
+337
+00:29:22,940 --> 00:29:27,740
+كنا مهتمين فيها متذاكرين المرة الماضية قولنالكم
+
+338
+00:29:27,740 --> 00:29:32,240
+كيف تحضروا ال phenol فقط لحد هنا وبنخلص مافيش اندي
+
+339
+00:29:32,240 --> 00:29:37,420
+انا عن ال computer الان ننتقل للفصل الخامس عشر
+
+340
+00:29:37,420 --> 00:29:42,280
+limits and detergentsالـ Libids الدهون الـ
+
+341
+00:29:42,280 --> 00:29:48,420
+detergents المنظفات الصناعية المنظفات الصناعية
+
+342
+00:29:48,420 --> 00:29:51,400
+الصوابين و الأشياء اللي بتكون في الشنب و غيرها و
+
+343
+00:29:51,400 --> 00:29:57,520
+غيراتها و هتلاحظوا انه في علاقة بين الدهون و بينال
+
+344
+00:29:57,520 --> 00:30:03,160
+detergents و ربما كلكم اتذكرين اساسا ان الصابون
+
+345
+00:30:03,160 --> 00:30:08,220
+عادة من وين كانوا بيجيبوها؟ من زيت الزتون .. زيت
+
+346
+00:30:08,220 --> 00:30:14,650
+الزتون، دهون والصابونمنظف طبعا soap الآن صاروا
+
+347
+00:30:14,650 --> 00:30:19,070
+يعملوا أشياء صناعية بنسميها synthetic detergents
+
+348
+00:30:19,070 --> 00:30:23,590
+يعني منظفات صناعية كل هذا الكلام هيكون جزء من
+
+349
+00:30:23,590 --> 00:30:30,270
+الكلام اللي هنناقشه في هذا الشركة الآن لو إجينا و
+
+350
+00:30:30,270 --> 00:30:38,380
+قولنا إيش هم ال livids إيش هم الدهونلاحظوا أنه
+
+351
+00:30:38,380 --> 00:30:42,140
+الأن بنبدأ شوية نختلف عن ال organic chemistry يعني
+
+352
+00:30:42,140 --> 00:30:45,760
+في ال organic chemistry كل chapter لما كنا نجيب
+
+353
+00:30:45,760 --> 00:30:50,080
+عائلة كنا نميز العائلة بالمجموعة الوظيفية اللي
+
+354
+00:30:50,080 --> 00:30:54,780
+موجودة فيها يعني نقول ال alcohols OH ال aldehydes
+
+355
+00:30:54,780 --> 00:31:00,490
+يضا بالبنض OC double bond O of R of R الاسد C
+
+356
+00:31:00,490 --> 00:31:04,830
+double bond O O H هناك كان التصنيف اعتمادا على ايش
+
+357
+00:31:04,830 --> 00:31:11,010
+المجموعة الوظيفية الان لما باجي بقول ال libids هل
+
+358
+00:31:11,010 --> 00:31:16,790
+يا ترى ال libids كعائلة تحكمها مجموعة وظيفية واحدة
+
+359
+00:31:16,790 --> 00:31:19,870
+يعني في الآخر الواحدة تيجي تقولي C double bond
+
+360
+00:31:19,870 --> 00:31:26,780
+ONH4 C double bond OSHهل تصنيف ال limits منطلق من
+
+361
+00:31:26,780 --> 00:31:29,980
+ال functional groups من المجموعات الوظيفية
+
+362
+00:31:29,980 --> 00:31:35,710
+الجوانب؟الـ Libids هي عائلة من المنتجات الطبيعية
+
+363
+00:31:35,710 --> 00:31:41,070
+بشكل عام Natural Products عائلة كبيرة جدا و ينضوي
+
+364
+00:31:41,070 --> 00:31:47,030
+تحتها تفرعات كتيرة هدولة بيمتازوا بشكل عام ..
+
+365
+00:31:47,030 --> 00:31:51,490
+بيمتازوا بشكل عام المراكبات المنتجة طبيعيا انه
+
+366
+00:31:51,490 --> 00:31:56,230
+بتدوب في ال organic solvents زي ال ether,
+
+367
+00:31:56,450 --> 00:32:00,330
+chloroform, أسيتون, بنزين وبشكل عام بدوبوش في
+
+368
+00:32:00,330 --> 00:32:05,710
+الميهإذا هنا اللي ميزهم كعائلة إن هما منتجات
+
+369
+00:32:05,710 --> 00:32:12,190
+طبيعية وشغل تانية soluble in organic solvents يعني
+
+370
+00:32:12,190 --> 00:32:19,870
+أنا بدي إن they are natural و soluble in non-polar
+
+371
+00:32:19,870 --> 00:32:24,370
+organic solvents insoluble in water
+
+372
+00:32:27,950 --> 00:32:31,530
+اللي أنا بدياهم عن ال limits they are natural
+
+373
+00:32:31,530 --> 00:32:37,510
+compounds soluble in non-polar organic solvents
+
+374
+00:32:37,510 --> 00:32:43,050
+insoluble in water طبعا طالما كانوا soluble in non
+
+375
+00:32:43,050 --> 00:32:46,090
+-polar organic solvents إذا انتوا هتستنتجوا ان هم
+
+376
+00:32:46,090 --> 00:32:51,790
+non-polar ليش؟ لأنه likelike واضح إذا هما non
+
+377
+00:32:51,790 --> 00:32:55,910
+polar و بدوبوا فيه ال non polar solvents الانب
+
+378
+00:32:55,910 --> 00:33:00,370
+يندرج تحتهم الحقيقة مجموعة كبيرة من المراكبات منهم
+
+379
+00:33:00,370 --> 00:33:05,090
+اللي بنسميه ال fatty acids الأحماض الدهنية بنشوف
+
+380
+00:33:05,090 --> 00:33:08,510
+شو هي ال fatty acids منهم ال soaps and detergents
+
+381
+00:33:08,510 --> 00:33:13,370
+الصوابين و المنظفات منهم ال fats and oils الدهون و
+
+382
+00:33:13,370 --> 00:33:18,770
+الزيون منهم ال waxes الشموةمنهم الـ Phospholipids
+
+383
+00:33:18,770 --> 00:33:23,330
+بنسميها Phospholipids منهم الـ Icosanoids مركبات
+
+384
+00:33:23,330 --> 00:33:28,590
+انكونا من عشرين ذرة كربون منهم Terbenes مجموعة
+
+385
+00:33:28,590 --> 00:33:34,590
+مركبات بتحده بصفة معينة بنشوفها وجود isoprene unit
+
+386
+00:33:34,590 --> 00:33:40,400
+منهم الستيرويد مركبات ممتازة وجود أربع حلقاتمنهم
+
+387
+00:33:40,400 --> 00:33:45,620
+بعض ال vitamins أشياء منوعة مافيش خاسم مشترك بينها
+
+388
+00:33:45,620 --> 00:33:50,980
+كل هدولة من ناحية المبدأ natural productsSoluble
+
+389
+00:33:50,980 --> 00:33:54,940
+in organic solvents and soluble in water are
+
+390
+00:33:54,940 --> 00:33:57,580
+classified as lipids
+
+391
+00:34:20,310 --> 00:34:24,990
+يعني التلات أشياء بنفهموا مع بعض، واضح؟ يعني اللي
+
+392
+00:34:24,990 --> 00:34:28,150
+بده يفهم ال fatty acids، بده يفهم ال fats، اللي
+
+393
+00:34:28,150 --> 00:34:30,890
+بده يفهم ال fats، بده يفهم ال oils، اللي بده يفهم
+
+394
+00:34:30,890 --> 00:34:33,110
+ال fats و ال oils، بده يفهم ال soaps و ال
+
+395
+00:34:33,110 --> 00:34:38,310
+detergents، التلاتة هتلاحظوا أن فيهم إيش؟ قاسم
+
+396
+00:34:38,310 --> 00:34:45,240
+مشترك، التلاتة هتلاحظوا أن فيهم قاسم مشتركوعشان
+
+397
+00:34:45,240 --> 00:34:51,440
+هيك خلّينا نبدأ بال fats and oils الآن بشكل عام
+
+398
+00:34:51,440 --> 00:34:57,640
+الدهون والزيوت أشهر شيء موجودين فيه على شكل اللي
+
+399
+00:34:57,640 --> 00:35:04,700
+بنسميه triglycerides إيش هما ال triglycerides؟ ال
+
+400
+00:35:04,700 --> 00:35:13,120
+triglycerides ببساطة عبارة عن إيسترز ل .. ال ..
+
+401
+00:35:14,640 --> 00:35:20,620
+للجليسارين طبعا كلكم اتذكرين انه احنا ايش اخدنا
+
+402
+00:35:20,620 --> 00:35:27,380
+الجليسارين سابقا قلنا تلات ذرات كربون تلات ذرات
+
+403
+00:35:27,380 --> 00:35:34,660
+كربون فيهم OH OH OH عشانك الجليسارول one two three
+
+404
+00:35:34,660 --> 00:35:41,880
+بروبان الترايول مظبوط ولا لأ one two three بروبان
+
+405
+00:35:41,880 --> 00:35:48,090
+الترايولهذا ال glycerin في الأساس اتفاعل مع أشياء
+
+406
+00:35:48,090 --> 00:35:53,850
+بنسميها fatty acids هتيجي تقولون احنا اتعلمنا ال
+
+407
+00:35:53,850 --> 00:35:58,370
+carboxylic acids اللي صيغتهم العامة C double bond
+
+408
+00:35:58,370 --> 00:36:04,570
+O OH متصلين في R بنقول ال fatty acids هم نفسهم
+
+409
+00:36:04,570 --> 00:36:14,080
+ولكن ال R تبعتهم كبيرةيعني بتكون عشر كربونات،
+
+410
+00:36:14,080 --> 00:36:17,220
+اتنائش، اربعة عاشر، ستة عاشر، تمانة عاشر، اشرين
+
+411
+00:36:17,220 --> 00:36:22,780
+الآن كلكم اتذكرين انه في ال alcohol و في ال acids
+
+412
+00:36:22,780 --> 00:36:32,300
+قولنا هذه المركبات التمتاز ان فيها طرف polar و طرف
+
+413
+00:36:32,300 --> 00:36:39,800
+non polarالـ R في الـ fatty acids الـ non-polar
+
+414
+00:36:39,800 --> 00:36:46,180
+الكبير، خلّينا نقول من عشرة و فوقوبناء على ذلك
+
+415
+00:36:46,180 --> 00:36:52,280
+الجزيء بمجمله يغلب عليه الـ non-polar part فبصير
+
+416
+00:36:52,280 --> 00:36:56,480
+water soluble ولا insoluble؟ بصير non-polar طالما
+
+417
+00:36:56,480 --> 00:37:01,680
+صار non-polar صار water insoluble بصير دوب في ال
+
+418
+00:37:01,680 --> 00:37:06,640
+organic solvent إذا هذه الجزيئات اللي فيها القاري
+
+419
+00:37:06,640 --> 00:37:10,190
+الكبيرة هي اللي بنسميها الـ fatty acidsفال fatty
+
+420
+00:37:10,190 --> 00:37:17,150
+acids ببساطة هي أحماض كربوكسيلية بسلسلة طويلة
+
+421
+00:37:17,150 --> 00:37:24,080
+وبناء على ذلك أصبحت هذه الأحماض non polarما بتدوبش
+
+422
+00:37:24,080 --> 00:37:27,220
+في الميه وعشان هيك بتدوبش في الميه بتدوب في
+
+423
+00:37:27,220 --> 00:37:33,500
+المراكبات العضوية عشان هيك سمنها مواد ايش؟ دهنية
+
+424
+00:37:33,500 --> 00:37:38,620
+او احماض دهنية فهما الأحماض الدهنية مجموعتهم
+
+425
+00:37:38,620 --> 00:37:42,600
+الأساسية زي ال carboxylic acids COOH هما
+
+426
+00:37:42,600 --> 00:37:49,330
+carboxylic acids اكبرواضح؟ هم ببساطة كربوكسيلك
+
+427
+00:37:49,330 --> 00:37:55,190
+أسنس كبار، الآن لو أجينا و قولنا كحول زائد حمض، شو
+
+428
+00:37:55,190 --> 00:38:04,910
+بيعطيني؟ إيستر، لو أخدنا أي كحول زائد حمض، إيستر،
+
+429
+00:38:04,910 --> 00:38:08,410
+هذا أخدنا التفاعل، الآن هاي كحول في الجليسرين و
+
+430
+00:38:08,410 --> 00:38:13,690
+هاي حمض، خليهم يتفاعلواهذه الكحولة اتفاعل، ماذا
+
+431
+00:38:13,690 --> 00:38:21,550
+سيعطينا؟ CH2O C double bond OR هذا Easter ولا لا؟
+
+432
+00:38:21,550 --> 00:38:28,430
+و هذا؟ Easter تاني على الكحولة و هذا؟يستار تالت،
+
+433
+00:38:28,430 --> 00:38:33,570
+إذا كم إيستار عمل لجليسارين؟ لأنه فيه تلاتة أواتشز
+
+434
+00:38:33,570 --> 00:38:40,410
+عمل تلاتة إيستار الآن هذه المركبات بنسميها احنا
+
+435
+00:38:40,410 --> 00:38:46,410
+الـ triglycerides الـ tri لأنهم تلاتة، الجليساريدز
+
+436
+00:38:46,410 --> 00:38:49,150
+لأنهم إيستارز of جليسارين
+
+437
+00:38:51,280 --> 00:38:55,480
+اعرفنا إذا ليش الـ triglycerides؟ لأنه there are E
+
+438
+00:38:55,480 --> 00:39:02,700
+stars of glycerin وكم E star؟ هان و هان و هان، إذا
+
+439
+00:39:02,700 --> 00:39:08,690
+هذه الـ triglycerides هي عبارة عن الفات والـ oilهي
+
+440
+00:39:08,690 --> 00:39:12,230
+عبارة عن الزيت و الذهن و الزبدة و السمنة و زيت
+
+441
+00:39:12,230 --> 00:39:16,270
+الزتون و زيت عباد الشمس هو عبارة عن الـ
+
+442
+00:39:16,270 --> 00:39:19,310
+Triglycerides الميزة الأساسية اللي بتبقى بالكم
+
+443
+00:39:19,310 --> 00:39:26,230
+متذاكرينها فيه ان القعر هذه طويلة لأن القعر طويلة
+
+444
+00:39:26,230 --> 00:39:31,030
+كله water soluble ولا insoluble عشان هيك الزيت
+
+445
+00:39:31,030 --> 00:39:39,160
+الزيرج زيت الزتون بخلط مع الميه لأ واضح ف ..لاحظوا
+
+446
+00:39:39,160 --> 00:39:43,600
+اللي فهم هذا الكلام، بلاحظ العلاقة ما بين الـ
+
+447
+00:39:43,600 --> 00:39:46,800
+triglycerides و الـ fatty acids، انه انا لو عملت
+
+448
+00:39:46,800 --> 00:39:51,200
+هيدروليسيز، لو كسرت الـ triglycerides، سخنتهم
+
+449
+00:39:51,200 --> 00:39:55,280
+بالسوديوم هيدروكسيد و ضفت عليهم بعدين حامض، عاش
+
+450
+00:39:55,280 --> 00:40:02,420
+بحصل؟ بحصل على ال glycerin أو ال glycerol و ال
+
+451
+00:40:02,420 --> 00:40:10,380
+fatty acidsبحصل على ال glycerol و ال fatty acids
+
+452
+00:40:10,380 --> 00:40:17,060
+واضح الفكرة؟ اذا ال fatty acids هما في الأساس جزء
+
+453
+00:40:17,060 --> 00:40:22,280
+من ال tri glycerides بالتكسير بحصل على glycerin و
+
+454
+00:40:22,280 --> 00:40:27,600
+بحصل على fatty acid واضح الفكرة؟
+
+455
+00:40:29,710 --> 00:40:34,910
+خلّينا شوية صغيرة نخرج عن السياق خلّينا شوية صغيرة
+
+456
+00:40:34,910 --> 00:40:41,870
+نخرج عن السياق الان جزء ال الكانز نرجع لل الكانز
+
+457
+00:40:41,870 --> 00:40:48,790
+مش هذا الجزء الأحمر هو عبارة عن الكانز طيب أول
+
+458
+00:40:48,790 --> 00:40:54,150
+chapter أخدناه في الكيميا العضوية شو كان؟الكينز،
+
+459
+00:40:54,150 --> 00:41:02,530
+وإيش أهم تفاعلات ال الكينز اللي احنا أخدناها؟ ان
+
+460
+00:41:02,530 --> 00:41:08,710
+ال الكينز بنحرقهم في وجود ال oxygen، بيعطونا ثاني
+
+461
+00:41:08,710 --> 00:41:15,970
+أكسيد الكربون وماء وحرارةطيب هذه المراكبات اللي
+
+462
+00:41:15,970 --> 00:41:20,090
+قال فيها Alkanes واحدة مين كنتيش تتخيل القاتل انه
+
+463
+00:41:20,090 --> 00:41:25,970
+حطينا السيرج على النار بدنا نولع السيرج حد بيمنعنا
+
+464
+00:41:25,970 --> 00:41:36,930
+يعني سيرج زائد Oxygen شو هيعطيني CO2 زائد H2O زائد
+
+465
+00:41:36,930 --> 00:41:43,730
+Heatمش هذه الـ aliphatic compounds الحمرة بتنحرج
+
+466
+00:41:43,730 --> 00:41:48,730
+وبتعطيني ثانو أكسيد كربون وميه وحرارة؟ إذا الـ
+
+467
+00:41:48,730 --> 00:41:53,790
+seerage ممكن ينحرج ويعطيني ثانو أكسيد كربون وميه
+
+468
+00:41:53,790 --> 00:41:59,530
+وحرارة؟ ولا مش ممكن؟ بتشوفوه بنحرج في الدار و
+
+469
+00:41:59,530 --> 00:42:04,530
+بتكونوا تنتبهوا لما بتشتغلوا؟ طب كويس الآن لو واحد
+
+470
+00:42:04,530 --> 00:42:11,060
+مخه مش مريحه أو الحصار مش مريحهوجطعوا البنزين ..
+
+471
+00:42:11,060 --> 00:42:15,720
+جطعوا السولار عن البلد وإيجى حط في سيارة ال مرسيدس
+
+472
+00:42:15,720 --> 00:42:18,920
+تبعته اللي بتمشي على السولار ولا في ال bus؟ سيرج
+
+473
+00:42:18,920 --> 00:42:25,740
+.. سيرج ومشى .. بيمشي ولا لأ؟ بيمشي .. بيمشي ..
+
+474
+00:42:25,740 --> 00:42:32,920
+بيمشي وعشان هيك في غزة في ظروف الحصار لما عدم
+
+475
+00:42:32,920 --> 00:42:38,270
+الوقودوكانوا بعض الباصات والسيارات المرسيدس مضطرة
+
+476
+00:42:38,270 --> 00:42:45,030
+تمشي حطوا searage في السيارة واشتغلت ومشيت صح لكن
+
+477
+00:42:45,030 --> 00:42:54,350
+كان عندكم مشكلة الشيء انه طلعت رائحة فظيعة جدا و
+
+478
+00:42:54,350 --> 00:42:58,850
+الناس كانت بتنخنيهمظبوط ولا لأ؟ طب هم الناس
+
+479
+00:42:58,850 --> 00:43:02,030
+مانخنجوش من ال solar العادى و من البنزين يعنى،
+
+480
+00:43:02,030 --> 00:43:05,990
+يقولوا تأثيرات سلبية، لكن مابتصلش لإنه الناس
+
+481
+00:43:05,990 --> 00:43:11,650
+ينخنجوا، إيش اللي صار إذا لما احنا ولّعنا السيرج؟
+
+482
+00:43:11,650 --> 00:43:16,210
+اه، اللي صار لما ولّعنا السيرج، إنه السيرج جزءين،
+
+483
+00:43:16,210 --> 00:43:22,310
+هذا الجزء هو اللي عمل كوقودهذا الجزء التابع لـ
+
+484
+00:43:22,310 --> 00:43:28,990
+Glycerin راح يعمل مصيبة هذا بالحرق بيعطي مركب تاني
+
+485
+00:43:28,990 --> 00:43:36,990
+CH ضب البند OH CH ضب البند CH2 بنسميه أكرولين و لا
+
+486
+00:43:36,990 --> 00:43:42,450
+أكرالدهايد هذا المركب هو اللي ريحته كانت سيئة و
+
+487
+00:43:42,450 --> 00:43:49,350
+يطلع على الشوارع و غيره و غيراته و خنج الناسواضحة
+
+488
+00:43:49,350 --> 00:43:55,130
+الفكرة؟ فالغلطة اللى كانت ان الناس لما اجوا يحرقوا
+
+489
+00:43:55,130 --> 00:44:01,330
+ال series في متورات السيارات حرقوا ايش؟ الجزء اللى
+
+490
+00:44:01,330 --> 00:44:06,110
+عادة بيعطيه الطاقة والجزء الجيد زائد الجزء ايش؟
+
+491
+00:44:06,110 --> 00:44:12,470
+السام والدار فطلعت عندهم حرارة ومشيت السيارة وكل
+
+492
+00:44:12,470 --> 00:44:16,810
+اشي لكن طلع عندهم كمان هذا المركب انتشر في الجو
+
+493
+00:44:16,810 --> 00:44:24,620
+خلق الناسواضحة الفكرة؟ طيب الآن لو في ناس بيفكروا
+
+494
+00:44:24,620 --> 00:44:31,940
+جيدا وقالوا يا تورا بدنا نحل المشكلة نطلع وقود من
+
+495
+00:44:31,940 --> 00:44:40,080
+الزيت ومن السيرج بيقدروا يعمله؟ لو إنهم في الأول
+
+496
+00:44:40,850 --> 00:44:46,750
+عملوا القاتل فصلوا هدول المركبين عن بعض يعني جابوا
+
+497
+00:44:46,750 --> 00:44:51,630
+ال searage قبل ما يحطوا كله في ماتور السيارة قبل
+
+498
+00:44:51,630 --> 00:44:57,410
+ما يحطوا كله في ماتور السيارة كسروا نصين الأن هذا
+
+499
+00:44:57,410 --> 00:45:04,480
+النصالمفيد هذا ال fuel هذا الوقود وهذا إيش؟
+
+500
+00:45:04,480 --> 00:45:08,860
+الجليسيرين الآن أنا لما أكسره بداية قبل ما أحطه في
+
+501
+00:45:08,860 --> 00:45:13,340
+موتور السيارة الجليسيرين صار على جانب بفصله ولا
+
+502
+00:45:13,340 --> 00:45:17,600
+مابفصلوش بفصله باخده و باستفيد منه كمان بعمل منه
+
+503
+00:45:17,600 --> 00:45:21,220
+كريمات مش كل كريمات و شامبوات فيها جليسيرين عشان
+
+504
+00:45:21,220 --> 00:45:27,850
+نعمة الإيدين يعني أنا مش بس اتخلصت من ضرر حرقهأنا
+
+505
+00:45:27,850 --> 00:45:32,470
+أخدته واستفادت منه وهذا الجزء عادة بيفصله على شكل
+
+506
+00:45:32,470 --> 00:45:39,650
+E star أو إثل أو إثل أو إثل واضح؟
+
+507
+00:45:39,650 --> 00:45:43,250
+يعني لما يعملوا التكسير بيفصلوا على شكل E star هذا
+
+508
+00:45:43,250 --> 00:45:50,610
+بناخده كوقود اليوم هذا الوقود اللي أخدنا إيش
+
+509
+00:45:50,610 --> 00:45:57,770
+بيسموه؟بيو ديزل بيو ديزل إيش يعني بيو ديزل يعني
+
+510
+00:45:57,770 --> 00:46:03,910
+الديزل الحيو اللي جاي من الزيوت هتقولولي في ديزل
+
+511
+00:46:03,910 --> 00:46:11,610
+بالطول من الزيت الجواب آه اليوم طائرات وسيارات
+
+512
+00:46:11,610 --> 00:46:17,370
+طائرات كاملة بتمشي على بيو ديزل بطوله من الزيوت
+
+513
+00:46:17,960 --> 00:46:23,540
+طبعا هالياطورة احنا ملاقين زيت ناكله سيرج و زيت
+
+514
+00:46:23,540 --> 00:46:29,620
+ناكله لما نحوله لوخود؟ الجواب اه كيف؟ الزيوت مش بس
+
+515
+00:46:29,620 --> 00:46:34,760
+كله مأكولة edible مأكول في زيوت inedibleزيوت لا
+
+516
+00:46:34,760 --> 00:46:40,480
+تؤكل تمام؟ بيزرعوها في أماكن كبيرة في الهند و في
+
+517
+00:46:40,480 --> 00:46:44,580
+غيرها و في غيراتها مثل مثلا زيت الجاتروفة و زيت
+
+518
+00:46:44,580 --> 00:46:49,520
+الكامليانة و زيت كذا في زيوت تؤكل و زيوت لا تؤكل
+
+519
+00:46:49,520 --> 00:46:54,800
+الزيوت اللتي لا تؤكل هي اللي بيحضروا منها المنظفات
+
+520
+00:46:54,800 --> 00:47:00,740
+و هي اللي بيحولوها لإيش؟ ل bio diesel و أشهرها زيت
+
+521
+00:47:00,740 --> 00:47:08,350
+اسمه الجاتروفةGatrofa Oil أشرب هذه الزيوت .. زيت
+
+522
+00:47:08,350 --> 00:47:13,010
+بنسميه إيش؟ زيت الجاتروفا فلاحظوا أنتوا كيف منطق
+
+523
+00:47:13,010 --> 00:47:17,350
+التفكير و منطق حل المشكلة في العلم أنه أنا فهمت
+
+524
+00:47:17,350 --> 00:47:22,450
+بداية .. أنه أنا فهمت بداية أن الحرارة بتجيني من
+
+525
+00:47:22,450 --> 00:47:29,170
+حرق هذا واضح؟الحرارة بتجيني من حرق هذا لكن هذا
+
+526
+00:47:29,170 --> 00:47:34,090
+موجود مع مركب تاني سام لما فصلته من الصين صار
+
+527
+00:47:34,090 --> 00:47:37,370
+بإمكاني أخد هذا و أسميه biodiesel و أحرب ولا لأ
+
+528
+00:47:37,370 --> 00:47:44,590
+الآن ضايقلي عشرين ثانية أحكيهم عارفين شو هم؟
+
+529
+00:47:44,590 --> 00:47:52,180
+العشرين ثانية اللي بدنا نحكيهم و نخلصالعشرين ثانية
+
+530
+00:47:52,180 --> 00:47:56,160
+اللي بنحكيهم و بنخلص القاتل اتخيلوا لو أخدتوا هذا
+
+531
+00:47:56,160 --> 00:48:03,780
+ال Easter و حطيتوا هنا سلسلة طويلة و حطيتوا هنا
+
+532
+00:48:03,780 --> 00:48:11,850
+كمان سلسلة طويلة هذه السلاسل ايش بتعمل؟بتولع مع ال
+
+533
+00:48:11,850 --> 00:48:17,110
+Oxygen و بتعطي حرارة و إضاءة و إشي هذه المركبات ال
+
+534
+00:48:17,110 --> 00:48:22,090
+E Stars اللي فيها سلسلة طويلة يمين و سلسلة طويلة
+
+535
+00:48:22,090 --> 00:48:30,910
+الشمال عارفين هي إيش؟ هي الشمع ال wax الآن أنا لما
+
+536
+00:48:30,910 --> 00:48:37,390
+بولع الشمع حقيقة إيش بولع؟ السلاسل الألفاتية
+
+537
+00:48:40,000 --> 00:48:45,380
+وبهك بيكون يعرفنا إيش هو الشمع الشمع هو Easter لكن
+
+538
+00:48:45,380 --> 00:48:50,160
+هذا ال Easter بسلسلتين كبار هانا وإحنا عرفنا إنه
+
+539
+00:48:50,160 --> 00:48:55,180
+هذه السلاسل لما بتولع هي اللي بتعطينا شوية الحرارة
+
+540
+00:48:55,180 --> 00:48:57,880
+و ثاني أكسيد الكربون و الميه مش مهمين أهم شيء
+
+541
+00:48:57,880 --> 00:49:02,720
+الحرارة و الإضاءة واضح؟ فلو قلنا لكم إيش ال wax
+
+542
+00:49:02,720 --> 00:49:12,010
+بالظبط ال wax areأو الواكس هم أسطارين مع شبكات
+
+543
+00:49:12,010 --> 00:49:16,370
+طويلة أو شبكات ألفاتية طويلة يعني اللي بيميزهم
+
+544
+00:49:16,370 --> 00:49:21,530
+الشبكات الطويلة الشبكات الألفاتية وكلنا عارفين
+
+545
+00:49:21,530 --> 00:49:25,810
+الأن الشبكات الألفاتية إيش بنعمل فيها هي اللي
+
+546
+00:49:25,810 --> 00:49:30,250
+بنولعها و بتعطينا الطاقة هي اللي بنولعها و بتعطينا
+
+547
+00:49:30,250 --> 00:49:34,850
+الطاقةفبكون هذا هو إيش الشمال فلاحظوا كيف أنا
+
+548
+00:49:34,850 --> 00:49:41,570
+استفدت من ال sealage كوقود كيف أنا استفدت كمان من
+
+549
+00:49:41,570 --> 00:49:46,710
+ال wax أنه أولعه و يطلعلي حرارة من خلال أنه أنا
+
+550
+00:49:46,710 --> 00:49:50,110
+بستفيد من التفاعل الأصلي اللي أخدته في شبتر واحد
+
+551
+00:49:50,110 --> 00:49:55,350
+أنه الألكيز بتحض مع ال oxygen و ال combustion
+
+552
+00:49:55,350 --> 00:49:58,630
+طلعوا ثانو أكسيد كربون و ميه و حرارة
+
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/rNQZEu2DPCw_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/rNQZEu2DPCw_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..b82ab429e41de0c2ceb099747487e0382ce76e7b
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/rNQZEu2DPCw_raw.json
@@ -0,0 +1 @@
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double headed straight arrows are used for structures with different arrangements of atoms and electrons", "tokens": [4520, 44513, 365, 819, 22435, 295, 14265, 3714, 2288, 9307, 44945, 1829, 7435, 1829, 8717, 3794, 10721, 1211, 41950, 15040, 3555, 44945, 39648, 16095, 341, 11610, 420, 3834, 12798, 2997, 19669, 366, 1143, 337, 9227, 365, 819, 22435, 295, 16871, 293, 14265], "avg_logprob": -0.20076308693996694, "compression_ratio": 1.455128205128205, "no_speech_prob": 0.0, "words": [{"start": 1020.3299999999999, "end": 1021.29, "word": "Structures", "probability": 0.4573974609375}, {"start": 1021.29, "end": 1021.67, "word": " with", "probability": 0.9189453125}, {"start": 1021.67, "end": 1022.27, "word": " different", "probability": 0.9130859375}, {"start": 1022.27, "end": 1023.41, "word": " arrangements", "probability": 0.8740234375}, {"start": 1023.41, "end": 1024.27, "word": " of", "probability": 0.97119140625}, {"start": 1024.27, "end": 1025.23, "word": " electrons", "probability": 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حركة زوج من الإلكترونات بوضح في الرأسين هدول", "tokens": [41185, 33688, 23275, 2655, 2288, 11536, 9307, 6156, 47432, 4032, 46958, 5016, 23758, 2423, 28820, 10943, 5296, 31377, 2304, 7251, 30544, 4032, 46958, 5016, 4724, 9778, 9381, 2407, 9381, 2423, 30944, 9154, 16247, 3794, 16095, 9122, 8848, 23275, 23758, 21136, 16095, 9673, 1863, 5016, 22653, 4724, 38251, 1829, 24991, 11610, 7251, 14851, 25957, 1211, 5296, 2655, 2407, 11242, 1829, 5016, 11331, 31747, 3660, 30767, 29245, 9154, 33688, 23275, 2655, 2288, 11536, 9307, 4032, 3615, 8592, 7649, 31439, 7251, 14851, 25957, 1211, 5296, 2655, 2407, 11242, 1829, 5016, 11331, 31747, 3660, 30767, 29245, 9154, 33688, 23275, 2655, 2288, 11536, 9307, 4724, 2407, 11242, 5016, 8978, 34892, 10721, 3794, 9957, 8032, 3215, 12610], "avg_logprob": -0.10456193963597928, "compression_ratio": 1.9898477157360406, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1065.2, "end": 1065.9, "word": "في", "probability": 0.326171875}, {"start": 1065.9, 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"Curved Arrow فالـ Curved Arrow is used to indicate the movement of a pair of electrons، two electrons، واضح؟", "tokens": [34, 374, 937, 40269, 6156, 6027, 39184, 7907, 937, 40269, 307, 1143, 281, 13330, 264, 3963, 295, 257, 6119, 295, 14265, 12399, 732, 14265, 12399, 4032, 46958, 5016, 22807], "avg_logprob": -0.3377604047457377, "compression_ratio": 1.1782178217821782, "no_speech_prob": 0.0, "words": [{"start": 1113.63, "end": 1114.31, "word": "Curved", "probability": 0.678955078125}, {"start": 1114.31, "end": 1114.67, "word": " Arrow", "probability": 0.5986328125}, {"start": 1114.67, "end": 1115.33, "word": " فالـ", "probability": 0.5243326822916666}, {"start": 1115.33, "end": 1115.71, "word": " Curved", "probability": 0.748779296875}, {"start": 1115.71, "end": 1116.05, "word": " Arrow", "probability": 0.99072265625}, {"start": 1116.05, "end": 1116.53, "word": " is", "probability": 0.5869140625}, {"start": 1116.53, "end": 1117.61, "word": " used", "probability": 0.62255859375}, 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يستعمل", "probability": 0.99462890625}, {"start": 1310.84, "end": 1311.96, "word": " هذا", "probability": 0.9619140625}, {"start": 1311.96, "end": 1312.4, "word": " السهم", "probability": 0.984375}, {"start": 1312.4, "end": 1315.52, "word": " اخر", "probability": 0.7705078125}, {"start": 1315.52, "end": 1316.1, "word": " شغلة", "probability": 0.9407552083333334}, {"start": 1316.1, "end": 1316.44, "word": " في", "probability": 0.95849609375}, {"start": 1316.44, "end": 1316.84, "word": " هذا", "probability": 0.982421875}, {"start": 1316.84, "end": 1317.76, "word": " الفصل", "probability": 0.971923828125}], "temperature": 1.0}, {"id": 57, "seek": 133388, "start": 1319.24, "end": 1333.88, "text": "الكيميا العضوية قبل قليل خفتوا و الأن نقطع الخوف و ننزل الخوف لماذا خفنا من الكيميا العضوية لأن الكيميا العضوية عشرين مليون مركب", "tokens": [6027, 4117, 32640, 25528, 18863, 11242, 2407, 10632, 12174, 36150, 12174, 20292, 1211, 16490, 5172, 2655, 14407, 4032, 16247, 1863, 8717, 47432, 3615, 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Isobutane هاي ال carbon الجديدة كان عندي تلاتة CH3 CH .. 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"seek": 40384, "start": 375.32, "end": 403.84, "text": "بكون Optically Active ولا Inactive؟ Inactive لو انا حطيت مثلا Dichloromethane CH2 Cl2 بكون Optically Active ولا Inactive؟ Inactive لأنه عشان يبدأ يصير أحد ال enantiomers في وجود chiral center واحد المفروض يكون عندى أربع مجموعات مختلفة فخلينا نقول انه نسبة كبيرة جدا من المراكبات العضوية أساسا", "tokens": [3555, 30544, 21455, 984, 26635, 49429, 682, 12596, 22807, 682, 12596, 45164, 1975, 8315, 11331, 9566, 36081, 50113, 15040, 413, 480, 6746, 649, 71, 1929, 5995, 17, 2033, 17, 4724, 30544, 21455, 984, 26635, 49429, 682, 12596, 22807, 682, 12596, 5296, 33456, 3224, 6225, 8592, 7649, 7251, 44510, 10721, 7251, 9381, 13546, 5551, 24401, 2423, 465, 11520, 298, 433, 8978, 49610, 23328, 23782, 304, 3056, 36764, 24401, 9673, 5172, 32887, 11242, 7251, 30544, 43242, 7578, 5551, 25513, 3615, 3714, 7435, 2304, 45367, 9307, 3714, 46456, 46538, 3660, 6156, 9778, 1211, 9957, 995, 8717, 39648, 16472, 3224, 8717, 35457, 3660, 9122, 3555, 48923, 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"word": " يبدأ", "probability": 0.9899088541666666}, {"start": 390.46, "end": 390.8, "word": " يصير", "probability": 0.98876953125}, {"start": 390.8, "end": 391.2, "word": " أحد", "probability": 0.78125}, {"start": 391.2, "end": 391.38, "word": " ال", "probability": 0.9501953125}, {"start": 391.38, "end": 392.4, "word": " enantiomers", "probability": 0.7257080078125}, {"start": 392.4, "end": 392.82, "word": " في", "probability": 0.92578125}, {"start": 392.82, "end": 393.18, "word": " وجود", "probability": 0.966064453125}, {"start": 393.18, "end": 393.62, "word": " chiral", "probability": 0.685546875}, {"start": 393.62, "end": 393.92, "word": " center", "probability": 0.80908203125}, {"start": 393.92, "end": 394.34, "word": " واحد", "probability": 0.85546875}, {"start": 394.34, "end": 395.18, "word": " المفروض", "probability": 0.989013671875}, {"start": 395.18, "end": 395.4, "word": " يكون", "probability": 0.977294921875}, {"start": 395.4, "end": 395.68, "word": " عندى", "probability": 0.67578125}, {"start": 395.68, "end": 395.94, "word": " أربع", "probability": 0.8128255208333334}, {"start": 395.94, "end": 396.46, "word": " مجموعات", "probability": 0.97568359375}, {"start": 396.46, "end": 397.08, "word": " مختلفة", "probability": 0.994140625}, {"start": 397.08, "end": 397.96, "word": " فخلينا", "probability": 0.761279296875}, {"start": 397.96, "end": 398.36, "word": " نقول", "probability": 0.99462890625}, {"start": 398.36, "end": 399.3, "word": " انه", "probability": 0.553466796875}, {"start": 399.3, "end": 400.0, "word": " نسبة", "probability": 0.99462890625}, {"start": 400.0, "end": 400.52, "word": " كبيرة", "probability": 0.9913736979166666}, {"start": 400.52, "end": 401.14, "word": " جدا", "probability": 0.989013671875}, {"start": 401.14, "end": 401.66, "word": " من", "probability": 0.98681640625}, {"start": 401.66, "end": 402.46, "word": " المراكبات", "probability": 0.906640625}, {"start": 402.46, "end": 403.06, "word": " العضوية", "probability": 0.995361328125}, {"start": 403.06, "end": 403.84, "word": " أساسا", "probability": 0.9737548828125}], "temperature": 1.0}, {"id": 18, "seek": 41522, "start": 404.94, "end": 415.22, "text": "بتكون A chiral لاحظوا معاه هنا بنيجي لنقطة كتير مهمة لما وصفنا مركب انه chiral بمعنى هو أحد", "tokens": [3555, 2655, 30544, 316, 23782, 304, 20193, 5016, 19913, 14407, 20449, 40294, 34105, 44945, 1829, 7435, 1829, 5296, 1863, 47432, 3660, 9122, 2655, 13546, 3714, 16095, 3660, 5296, 15042, 4032, 9381, 5172, 8315, 3714, 31747, 3555, 16472, 3224, 23782, 304, 4724, 2304, 3615, 1863, 7578, 31439, 5551, 24401], "avg_logprob": -0.19786351554247797, "compression_ratio": 1.2459016393442623, "no_speech_prob": 8.940696716308594e-07, "words": [{"start": 404.94, "end": 405.94, "word": "بتكون", "probability": 0.7762858072916666}, {"start": 405.94, "end": 406.58, "word": " A", "probability": 0.2119140625}, {"start": 406.58, "end": 407.32, "word": " chiral", "probability": 0.59783935546875}, {"start": 407.32, "end": 408.2, "word": " لاحظوا", "probability": 0.8719482421875}, {"start": 408.2, "end": 408.64, "word": " معاه", "probability": 0.937255859375}, {"start": 408.64, "end": 409.14, "word": " هنا", "probability": 0.5673828125}, {"start": 409.14, "end": 409.56, "word": " بنيجي", "probability": 0.819580078125}, {"start": 409.56, "end": 410.04, "word": " لنقطة", "probability": 0.9378662109375}, {"start": 410.04, "end": 410.3, "word": " كتير", "probability": 0.8981119791666666}, {"start": 410.3, "end": 410.94, "word": " مهمة", "probability": 0.9920247395833334}, {"start": 410.94, "end": 411.4, "word": " لما", "probability": 0.875244140625}, {"start": 411.4, "end": 411.88, "word": " وصفنا", "probability": 0.98681640625}, {"start": 411.88, "end": 412.38, "word": " مركب", "probability": 0.9080403645833334}, {"start": 412.38, "end": 412.7, "word": " انه", "probability": 0.85791015625}, {"start": 412.7, "end": 413.36, "word": " chiral", "probability": 0.84423828125}, {"start": 413.36, "end": 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427.39, "end": 427.99, "word": " بزاوية", "probability": 0.94541015625}, {"start": 427.99, "end": 429.03, "word": " معينة", "probability": 0.9752604166666666}, {"start": 429.03, "end": 429.77, "word": " الآن", "probability": 0.6673583984375}, {"start": 429.77, "end": 430.65, "word": " ال", "probability": 0.88037109375}, {"start": 430.65, "end": 431.27, "word": " enanchomar", "probability": 0.6666259765625}, {"start": 431.27, "end": 431.67, "word": " التاني", "probability": 0.7858072916666666}, {"start": 431.67, "end": 431.83, "word": " لو", "probability": 0.97509765625}, {"start": 431.83, "end": 432.41, "word": " حاطيته", "probability": 0.986083984375}, {"start": 432.41, "end": 432.51, "word": " في", "probability": 0.87890625}, {"start": 432.51, "end": 432.61, "word": " ال", "probability": 0.7392578125}, {"start": 432.61, "end": 434.09, "word": " polarimeter", "probability": 0.5748291015625}, {"start": 434.09, "end": 434.53, "word": " برضه", "probability": 0.78369140625}, {"start": 434.53, "end": 435.21, "word": " chiral", "probability": 0.925048828125}, {"start": 435.21, "end": 436.23, "word": " بنسميه", "probability": 0.94140625}, {"start": 436.23, "end": 436.85, "word": " بلف", "probability": 0.870849609375}, {"start": 436.85, "end": 437.19, "word": " الضوء", "probability": 0.98583984375}, {"start": 437.19, "end": 437.63, "word": " ولكن", "probability": 0.879638671875}, {"start": 437.63, "end": 438.35, "word": " باتجاه", "probability": 0.9117431640625}], "temperature": 1.0}, {"id": 20, "seek": 46718, "start": 439.42, "end": 467.18, "text": "معاكس إذا صار عندى مركب chiral و مركب chiral طيب لو حطيت مركب من الأساس مافيه chiral center بلفش الضوء وجدت إيش بدى أسمي هذا المركب A chiral هنا ال A بتصير أداة نفي لاحظوا معناه .. لاحظوا معناه بتكونوا فاهمين شوية باللغة الإنجليزية أدوات النكرة و أدوات المعرفة يعني المركب هنا .. المركب هنا", "tokens": [2304, 3615, 995, 4117, 3794, 11933, 15730, 20328, 9640, 43242, 7578, 3714, 31747, 3555, 23782, 304, 4032, 3714, 31747, 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optically active ولا optically inactive؟ optically inactive طبعا هنا ممكن يجيني السؤال طب يا تورا لو كان عندي خليط بنسب غير متساوية", "tokens": [6027, 9778, 20292, 9566, 23782, 304, 49429, 2800, 35083, 28242, 3224, 2427, 984, 4967, 49429, 2427, 984, 294, 12596, 22807, 2427, 984, 294, 12596, 23032, 3555, 3615, 995, 34105, 3714, 43020, 7251, 7435, 9957, 1829, 21136, 33604, 6027, 23032, 3555, 35186, 6055, 13063, 995, 45164, 25961, 18871, 16254, 16490, 20292, 9566, 44945, 35457, 32771, 13546, 44650, 3794, 995, 2407, 10632], "avg_logprob": -0.13524590457072022, "compression_ratio": 1.5096774193548388, "no_speech_prob": 0.0, "words": [{"start": 610.32, "end": 611.56, "word": "الخليط", "probability": 0.9085693359375}, {"start": 611.56, "end": 612.72, "word": " chiral", "probability": 0.865478515625}, {"start": 612.72, "end": 613.04, "word": " ولا", "probability": 0.720703125}, {"start": 613.04, "end": 614.26, "word": " achiral", "probability": 0.789306640625}, {"start": 614.26, "end": 615.12, "word": " كله", "probability": 0.789794921875}, {"start": 615.12, "end": 615.82, "word": " optically", "probability": 0.79833984375}, {"start": 615.82, "end": 616.48, "word": " active", "probability": 0.97119140625}, {"start": 616.48, "end": 616.78, "word": " ولا", "probability": 0.931640625}, {"start": 616.78, "end": 617.36, "word": " optically", "probability": 0.94189453125}, {"start": 617.36, "end": 618.58, "word": " inactive؟", "probability": 0.7327473958333334}, {"start": 618.58, "end": 619.14, "word": " optically", "probability": 0.878173828125}, {"start": 619.14, "end": 619.66, "word": " inactive", "probability": 0.9453125}, {"start": 619.66, "end": 620.3, "word": " طبعا", "probability": 0.986083984375}, {"start": 620.3, "end": 620.48, "word": " هنا", "probability": 0.87939453125}, {"start": 620.48, "end": 620.9, "word": " ممكن", "probability": 0.869384765625}, {"start": 620.9, "end": 621.38, "word": " يجيني", "probability": 0.8980712890625}, {"start": 621.38, "end": 621.94, "word": " السؤال", "probability": 0.9949544270833334}, {"start": 621.94, "end": 622.96, "word": " طب", "probability": 0.813720703125}, {"start": 622.96, "end": 623.26, "word": " يا", "probability": 0.90478515625}, {"start": 623.26, "end": 623.72, "word": " تورا", "probability": 0.7278645833333334}, {"start": 623.72, "end": 624.08, "word": " لو", "probability": 0.98095703125}, {"start": 624.08, "end": 624.36, "word": " كان", "probability": 0.978515625}, {"start": 624.36, "end": 624.66, "word": " عندي", "probability": 0.765869140625}, {"start": 624.66, "end": 626.02, "word": " خليط", "probability": 0.9505208333333334}, {"start": 626.02, "end": 626.74, "word": " بنسب", "probability": 0.949462890625}, {"start": 626.74, "end": 627.2, "word": " غير", "probability": 0.99560546875}, {"start": 627.2, "end": 628.3, "word": " متساوية", "probability": 0.9580078125}], "temperature": 1.0}, {"id": 28, "seek": 64211, "start": 630.33, "end": 642.11, "text": "يعني مثلا خلطت من ال isomer الموجب نسبة 70% من ال isomer السالب نسبة 30% هذا الخليط", "tokens": [40228, 22653, 50113, 15040, 16490, 1211, 9566, 2655, 9154, 2423, 307, 14301, 9673, 29245, 3555, 8717, 35457, 3660, 5285, 4, 9154, 2423, 307, 14301, 21136, 6027, 3555, 8717, 35457, 3660, 2217, 4, 23758, 33962, 20292, 9566], "avg_logprob": -0.17535895431363904, "compression_ratio": 1.346938775510204, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 630.33, "end": 630.89, "word": "يعني", "probability": 0.672119140625}, {"start": 630.89, "end": 631.67, "word": " مثلا", "probability": 0.908447265625}, {"start": 631.67, "end": 632.31, "word": " خلطت", "probability": 0.94921875}, {"start": 632.31, "end": 632.49, "word": " من", "probability": 0.984375}, {"start": 632.49, "end": 632.67, "word": " ال", "probability": 0.8330078125}, {"start": 632.67, "end": 633.27, "word": " isomer", "probability": 0.43499755859375}, {"start": 633.27, "end": 634.07, "word": " الموجب", "probability": 0.8400065104166666}, {"start": 634.07, "end": 634.65, "word": " نسبة", "probability": 0.9817708333333334}, {"start": 634.65, "end": 635.15, "word": " 70", "probability": 0.587890625}, {"start": 635.15, "end": 635.75, "word": "%", "probability": 0.859375}, {"start": 635.75, "end": 636.65, "word": " من", "probability": 0.84228515625}, {"start": 636.65, "end": 636.83, "word": " ال", "probability": 0.90771484375}, {"start": 636.83, "end": 637.33, "word": " isomer", "probability": 0.926513671875}, {"start": 637.33, "end": 637.93, "word": " السالب", "probability": 0.9690755208333334}, {"start": 637.93, "end": 638.69, "word": " نسبة", "probability": 0.9630533854166666}, {"start": 638.69, "end": 639.51, "word": " 30", "probability": 0.947265625}, {"start": 639.51, "end": 640.29, "word": "%", "probability": 0.9521484375}, {"start": 640.29, "end": 641.31, "word": " هذا", "probability": 0.802734375}, {"start": 641.31, "end": 642.11, "word": " الخليط", "probability": 0.95703125}], "temperature": 1.0}, {"id": 29, "seek": 66344, "start": 644.42, "end": 663.44, "text": "هيكون optically active هذا الخليط هيكون optically active ولكن بشكل ايش؟ جزئي بشكل جزئي تماما زي ما بنيجي نقول مثلا بني ادم الله ربح سبعين كذا خسر تلاتين كدهش في النهاية؟", "tokens": [3224, 1829, 30544, 2427, 984, 4967, 23758, 33962, 20292, 9566, 39896, 30544, 2427, 984, 4967, 35525, 19452, 4724, 8592, 28820, 1975, 1829, 8592, 22807, 10874, 11622, 19986, 1829, 4724, 8592, 28820, 10874, 11622, 19986, 1829, 46811, 10943, 995, 30767, 1829, 19446, 44945, 1829, 7435, 1829, 8717, 39648, 50113, 15040, 4724, 22653, 1975, 40448, 21984, 12602, 49628, 8608, 3555, 3615, 9957, 9122, 15730, 16490, 3794, 2288, 6055, 1211, 9307, 9957, 9122, 3215, 3224, 8592, 8978, 28239, 11296, 10632, 22807], "avg_logprob": -0.18552215831189217, "compression_ratio": 1.606936416184971, "no_speech_prob": 8.940696716308594e-07, "words": [{"start": 644.42, "end": 645.54, "word": "هيكون", "probability": 0.8170572916666666}, {"start": 645.54, "end": 646.66, "word": " optically", "probability": 0.732666015625}, {"start": 646.66, "end": 648.34, "word": " active", "probability": 0.97021484375}, {"start": 648.34, "end": 648.68, "word": " هذا", "probability": 0.58935546875}, {"start": 648.68, "end": 649.28, "word": " الخليط", "probability": 0.8631184895833334}, {"start": 649.28, "end": 649.7, "word": " هيكون", "probability": 0.6485595703125}, {"start": 649.7, "end": 650.4, "word": " optically", "probability": 0.886962890625}, {"start": 650.4, "end": 651.32, "word": " active", "probability": 0.97021484375}, {"start": 651.32, "end": 652.34, "word": " ولكن", "probability": 0.81494140625}, {"start": 652.34, "end": 652.96, "word": " بشكل", "probability": 0.9921875}, {"start": 652.96, "end": 654.02, "word": " ايش؟", "probability": 0.73284912109375}, {"start": 654.02, "end": 654.74, "word": " جزئي", "probability": 0.74267578125}, {"start": 654.74, "end": 655.48, "word": " بشكل", "probability": 0.8370768229166666}, {"start": 655.48, "end": 656.44, "word": " جزئي", "probability": 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"probability": 0.916748046875}, {"start": 674.26, "end": 674.98, "word": " المركب", "probability": 0.8846028645833334}, {"start": 674.98, "end": 675.46, "word": " النقي", "probability": 0.9326171875}, {"start": 675.46, "end": 676.5, "word": " زاويته", "probability": 0.9291015625}, {"start": 676.5, "end": 677.14, "word": " 20", "probability": 0.70849609375}, {"start": 677.14, "end": 678.32, "word": " هذه", "probability": 0.64404296875}, {"start": 678.32, "end": 678.78, "word": " العشرين", "probability": 0.75146484375}, {"start": 678.78, "end": 679.52, "word": " للمركب", "probability": 0.9173583984375}, {"start": 679.52, "end": 680.02, "word": " الاش", "probability": 0.554931640625}, {"start": 680.02, "end": 681.54, "word": " النقي", "probability": 0.658447265625}, {"start": 681.54, "end": 681.72, "word": " لو", "probability": 0.978515625}, {"start": 681.72, "end": 682.28, "word": " وضعته", "probability": 0.9644775390625}, {"start": 682.28, "end": 682.58, "word": " زي", "probability": 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المريض بيروح على المستشفى لما المريض بيروح على المستشفى و بيقولوا بدنا نعطيه محلول سكر بتعرفوا بيعطيه واحد من الاتنين و تلاتين", "tokens": [2655, 9778, 26895, 14407, 14739, 3224, 47525, 8315, 8717, 2655, 3615, 19528, 5296, 15042, 8717, 1829, 7435, 1829, 8717, 47283, 3215, 21136, 37983, 21136, 3215, 32277, 1829, 9673, 47283, 3215, 31767, 1829, 17082, 3660, 18863, 10943, 3660, 383, 21, 39, 4762, 46, 21, 47525, 8315, 8717, 2288, 38251, 37893, 3714, 31747, 3555, 36764, 24401, 1975, 2655, 1863, 9957, 4032, 6055, 1211, 9307, 9957, 3714, 31747, 3555, 4032, 8717, 3615, 28480, 16095, 4032, 8717, 2304, 1829, 11622, 16095, 20666, 32277, 2304, 2423, 7649, 5296, 15042, 9673, 16572, 11242, 4724, 13546, 2407, 5016, 15844, 9673, 14851, 8592, 5172, 7578, 5296, 15042, 9673, 16572, 11242, 4724, 13546, 2407, 5016, 15844, 9673, 14851, 8592, 5172, 7578, 4032, 4724, 1829, 39648, 14407, 47525, 8315, 8717, 3615, 9566, 1829, 3224, 3714, 5016, 1211, 12610, 8608, 37983, 39894, 3615, 28480, 14407, 4724, 40228, 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0.96923828125}, {"start": 2277.25, "end": 2277.85, "word": " منه", "probability": 0.985595703125}, {"start": 2277.85, "end": 2278.47, "word": " اتنين", "probability": 0.918212890625}, {"start": 2278.47, "end": 2279.03, "word": " ممكن", "probability": 0.987060546875}, {"start": 2279.03, "end": 2279.51, "word": " تحطه", "probability": 0.87451171875}, {"start": 2279.51, "end": 2279.87, "word": " هان", "probability": 0.974609375}, {"start": 2279.87, "end": 2280.17, "word": " و", "probability": 0.97119140625}, {"start": 2280.17, "end": 2280.55, "word": " هان", "probability": 0.969970703125}, {"start": 2280.55, "end": 2282.15, "word": " بيصير", "probability": 0.9833984375}, {"start": 2282.15, "end": 2282.59, "word": " برضه", "probability": 0.8201497395833334}, {"start": 2282.59, "end": 2283.09, "word": " عندكم", "probability": 0.9697265625}, {"start": 2283.09, "end": 2283.81, "word": " one", "probability": 0.96533203125}, {"start": 2283.81, "end": 2284.33, "word": " chiral", "probability": 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تخيلوا لما تحطوا هنا CL ما زال عندكم CH2 مش chiral و CH2 و CH2 و CH2 و هنا CH2CL مش chiral اذا لو انا جبتلكوا سؤال ال one five dichlorobentane has two stereoisomers طلعوا معاه هي كلور هي كلور", "tokens": [3555, 43042, 3224, 43242, 24793, 472, 23782, 304, 3056, 6156, 7578, 9154, 3224, 1975, 2655, 1863, 9957, 3714, 43020, 6055, 5016, 9566, 14407, 34105, 4032, 34105, 6055, 9778, 26895, 14407, 5296, 15042, 6055, 5016, 9566, 14407, 34105, 12855, 19446, 30767, 6027, 43242, 24793, 5995, 17, 37893, 23782, 304, 4032, 5995, 17, 4032, 5995, 17, 4032, 5995, 17, 4032, 34105, 5995, 17, 22458, 37893, 23782, 304, 1975, 15730, 45164, 1975, 8315, 10874, 3555, 2655, 23275, 14407, 8608, 33604, 6027, 2423, 472, 1732, 274, 480, 6746, 996, 317, 1929, 575, 732, 12730, 7376, 298, 433, 23032, 1211, 3615, 14407, 20449, 40294, 39896, 28242, 13063, 39896, 28242, 13063], "avg_logprob": -0.2069575459046184, "compression_ratio": 1.6772727272727272, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 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2294.98, "end": 2295.22, "word": " هنا", "probability": 0.96826171875}, {"start": 2295.22, "end": 2295.9, "word": " تخيلوا", "probability": 0.958984375}, {"start": 2295.9, "end": 2296.24, "word": " لما", "probability": 0.801513671875}, {"start": 2296.24, "end": 2296.56, "word": " تحطوا", "probability": 0.9793701171875}, {"start": 2296.56, "end": 2296.7, "word": " هنا", "probability": 0.9150390625}, {"start": 2296.7, "end": 2297.04, "word": " CL", "probability": 0.34716796875}, {"start": 2297.04, "end": 2297.44, "word": " ما", "probability": 0.59521484375}, {"start": 2297.44, "end": 2297.66, "word": " زال", "probability": 0.917236328125}, {"start": 2297.66, "end": 2298.04, "word": " عندكم", "probability": 0.9765625}, {"start": 2298.04, "end": 2298.88, "word": " CH2", "probability": 0.9775390625}, {"start": 2298.88, "end": 2299.34, "word": " مش", "probability": 0.896484375}, {"start": 2299.34, "end": 2299.84, "word": " chiral", "probability": 0.9384765625}, {"start": 2299.84, "end": 2300.48, "word": " و", "probability": 0.8525390625}, {"start": 2300.48, "end": 2301.1, "word": " CH2", "probability": 0.9443359375}, {"start": 2301.1, "end": 2301.24, "word": " و", "probability": 0.96630859375}, {"start": 2301.24, "end": 2301.74, "word": " CH2", "probability": 0.95849609375}, {"start": 2301.74, "end": 2301.86, "word": " و", "probability": 0.98388671875}, {"start": 2301.86, "end": 2302.36, "word": " CH2", "probability": 0.966552734375}, {"start": 2302.36, "end": 2302.68, "word": " و", "probability": 0.95751953125}, {"start": 2302.68, "end": 2302.96, "word": " هنا", "probability": 0.91162109375}, {"start": 2302.96, "end": 2304.3, "word": " CH2CL", "probability": 0.7925618489583334}, {"start": 2304.3, "end": 2305.06, "word": " مش", "probability": 0.9599609375}, {"start": 2305.06, "end": 2305.5, "word": " chiral", "probability": 0.963623046875}, {"start": 2305.5, "end": 2306.22, "word": " اذا", "probability": 0.77685546875}, {"start": 2306.22, "end": 2306.64, "word": " 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new file mode 100644
index 0000000000000000000000000000000000000000..4e5643e2f5e21775c49780820dec063cd21b9776
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/tRXl66rgvqA_raw.json
@@ -0,0 +1 @@
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الآن", "probability": 0.56365966796875}, {"start": 225.34, "end": 225.72, "word": " لو", "probability": 0.818359375}, {"start": 225.72, "end": 226.08, "word": " أقل", "probability": 0.9705403645833334}, {"start": 226.08, "end": 226.6, "word": " مجموعة", "probability": 0.93408203125}, {"start": 226.6, "end": 227.16, "word": " وجدت", "probability": 0.8968098958333334}, {"start": 227.16, "end": 227.3, "word": " على", "probability": 0.7744140625}, {"start": 227.3, "end": 227.98, "word": " الجنبين", "probability": 0.82208251953125}, {"start": 227.98, "end": 228.5, "word": " فهي", "probability": 0.9798177083333334}, {"start": 228.5, "end": 229.2, "word": " للأمام", "probability": 0.926513671875}, {"start": 229.2, "end": 230.14, "word": " يعني", "probability": 0.913330078125}, {"start": 230.14, "end": 230.76, "word": " نتيجتها", "probability": 0.94560546875}, {"start": 230.76, "end": 231.4, "word": " هتطلع", "probability": 0.95244140625}, {"start": 231.4, "end": 232.66, "word": " معكوسة", 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0.94091796875}, {"start": 239.12, "end": 239.62, "word": " بيطلع", "probability": 0.98046875}, {"start": 239.62, "end": 240.0, "word": " معاه", "probability": 0.77880859375}, {"start": 240.0, "end": 240.58, "word": " عشان", "probability": 0.9816080729166666}, {"start": 240.58, "end": 241.28, "word": " أصحح", "probability": 0.899658203125}, {"start": 241.28, "end": 241.5, "word": " أن", "probability": 0.4423828125}, {"start": 241.5, "end": 241.8, "word": " هذه", "probability": 0.82763671875}, {"start": 241.8, "end": 242.42, "word": " المجموعة", "probability": 0.92392578125}, {"start": 242.42, "end": 243.12, "word": " أساسا", "probability": 0.9443359375}, {"start": 243.12, "end": 243.94, "word": " مرسومة", "probability": 0.9408203125}, {"start": 243.94, "end": 244.44, "word": " للأمام", "probability": 0.956298828125}], "temperature": 1.0}, {"id": 10, "seek": 25967, "start": 244.95, "end": 259.67, "text": "لو افترضنا نعمل مثال ان أكد فيه هذه الفكرة خلّينا نبدأ مثلا بمجموعة اقل مجموعة تكون هنا يعني لو قولنا HPRCH3 مثلا floor okay", "tokens": [1211, 2407, 1975, 5172, 2655, 43042, 8315, 8717, 25957, 1211, 50113, 6027, 16472, 5551, 4117, 3215, 8978, 3224, 29538, 27188, 4117, 25720, 16490, 1211, 11703, 9957, 995, 8717, 44510, 10721, 50113, 15040, 4724, 2304, 7435, 2304, 2407, 27884, 1975, 4587, 1211, 3714, 7435, 2304, 2407, 27884, 6055, 30544, 34105, 37495, 22653, 45164, 12174, 12610, 8315, 389, 15958, 5462, 18, 50113, 15040, 4123, 1392], "avg_logprob": -0.2365722726099193, "compression_ratio": 1.3548387096774193, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 244.95, "end": 245.45, "word": "لو", "probability": 0.7061767578125}, {"start": 245.45, "end": 246.25, "word": " افترضنا", "probability": 0.91923828125}, {"start": 246.25, "end": 246.85, "word": " نعمل", "probability": 0.873046875}, {"start": 246.85, "end": 247.47, "word": " مثال", "probability": 0.982177734375}, {"start": 247.47, "end": 247.71, "word": " ان", "probability": 0.2152099609375}, {"start": 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الذرات", "probability": 0.8728841145833334}, {"start": 275.2, "end": 275.32, "word": " و", "probability": 0.5986328125}, {"start": 275.32, "end": 275.68, "word": " أطول", "probability": 0.9119466145833334}, {"start": 275.68, "end": 276.52, "word": " سلسلة", "probability": 0.971923828125}, {"start": 276.52, "end": 276.76, "word": " و", "probability": 0.97265625}, {"start": 276.76, "end": 278.44, "word": " مواقع", "probability": 0.82037353515625}, {"start": 278.44, "end": 279.16, "word": " الذرات", "probability": 0.9669596354166666}, {"start": 279.16, "end": 279.58, "word": " هذا", "probability": 0.87109375}, {"start": 279.58, "end": 279.98, "word": " انكون", "probability": 0.462890625}, {"start": 279.98, "end": 280.14, "word": " من", "probability": 0.98974609375}, {"start": 280.14, "end": 280.4, "word": " كام", "probability": 0.893310546875}, {"start": 280.4, "end": 281.14, "word": " carbon؟", "probability": 0.65087890625}, {"start": 281.14, "end": 282.44, "word": " واحد", "probability": 0.6884765625}, {"start": 282.44, "end": 283.22, "word": " اتنين", "probability": 0.8719482421875}, {"start": 283.22, "end": 283.66, "word": " على", "probability": 0.5576171875}, {"start": 283.66, "end": 283.98, "word": " نمرة", "probability": 0.8367513020833334}, {"start": 283.98, "end": 284.36, "word": " واحد", "probability": 0.991943359375}, {"start": 284.36, "end": 285.06, "word": " عندى", "probability": 0.6455078125}, {"start": 285.06, "end": 286.1, "word": " بروم", "probability": 0.6083577473958334}, {"start": 286.1, "end": 286.78, "word": " و", "probability": 0.95751953125}, {"start": 286.78, "end": 287.26, "word": " floor", "probability": 0.31591796875}, {"start": 287.26, "end": 287.8, "word": " إذا", "probability": 0.7587890625}, {"start": 287.8, "end": 288.14, "word": " هذا", "probability": 0.90087890625}, {"start": 288.14, "end": 288.98, "word": " كمركب", "probability": 0.8948974609375}, {"start": 288.98, "end": 289.94, "word": " وانبرومه", "probability": 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طول السلسلة من chapter ال alkanes جيبنا ال double bond و مكانها من chapter ال alkanes جيبنا ترتيب الأولويات من chapter ال alkanes جيبنا ال R و ال S من chapter خمسة", "tokens": [4587, 16254, 46007, 33251, 32640, 25528, 3714, 3555, 1863, 10632, 15844, 45030, 11242, 37495, 22653, 8978, 23758, 9673, 12984, 6027, 10874, 1829, 3555, 8315, 23032, 12610, 21136, 1211, 3794, 37977, 9154, 7187, 2423, 419, 5225, 279, 10874, 1829, 3555, 8315, 2423, 3834, 6086, 4032, 3714, 41361, 11296, 9154, 7187, 2423, 419, 5225, 279, 10874, 1829, 3555, 8315, 6055, 2288, 31371, 3555, 16247, 12610, 45865, 9307, 9154, 7187, 2423, 419, 5225, 279, 10874, 1829, 3555, 8315, 2423, 497, 4032, 2423, 318, 9154, 7187, 16490, 2304, 3794, 3660], "avg_logprob": -0.18929597153060737, "compression_ratio": 1.9186046511627908, "no_speech_prob": 6.4373016357421875e-06, "words": [{"start": 685.25, "end": 685.89, "word": "قديمة", "probability": 0.7010091145833334}, {"start": 685.89, "end": 686.53, "word": " الكيميا", "probability": 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هذول المركبين كايرال هذول المركبين لو كان عندكم carbon تنتين تلاتة أربعة وهي carbon تنتين تلاتة أربعة لو حطيت هنا chlorine", "tokens": [2304, 4117, 2655, 37746, 43242, 24793, 497, 4032, 7435, 1863, 3555, 11296, 8717, 5172, 2655, 43042, 1804, 2217, 3714, 43020, 7251, 30544, 497, 3175, 2217, 6024, 48506, 8608, 2407, 25528, 1975, 8315, 1975, 3615, 9566, 1829, 24793, 14578, 1975, 3215, 9778, 1211, 14407, 15844, 2423, 24793, 21292, 35473, 2288, 4032, 1975, 4117, 2655, 3555, 14407, 24525, 2304, 3714, 31747, 3555, 9957, 8032, 8848, 12610, 9673, 31747, 3555, 9957, 9122, 995, 13546, 6027, 8032, 8848, 12610, 9673, 31747, 3555, 9957, 45164, 25961, 43242, 24793, 5954, 6055, 29399, 9957, 6055, 1211, 9307, 3660, 5551, 25513, 27884, 37037, 1829, 5954, 6055, 29399, 9957, 6055, 1211, 9307, 3660, 5551, 25513, 27884, 45164, 11331, 9566, 36081, 34105, 39888], "avg_logprob": -0.19380482233930052, "compression_ratio": 1.771551724137931, "no_speech_prob": 0.0, "words": [{"start": 2369.91, "end": 2370.45, 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2548.49, "end": 2550.07, "word": " بالتجربة", "probability": 0.901953125}, {"start": 2550.07, "end": 2550.89, "word": " باستعمال", "probability": 0.96494140625}, {"start": 2550.89, "end": 2551.59, "word": " جهاز", "probability": 0.9752604166666666}, {"start": 2551.59, "end": 2552.85, "word": " البولاري", "probability": 0.7064208984375}, {"start": 2552.85, "end": 2553.27, "word": " ميتر", "probability": 0.7228190104166666}, {"start": 2553.27, "end": 2554.67, "word": " وبهيك", "probability": 0.8487548828125}, {"start": 2554.67, "end": 2555.43, "word": " بننهي", "probability": 0.912353515625}, {"start": 2555.43, "end": 2555.79, "word": " اليوم", "probability": 0.962890625}, {"start": 2555.79, "end": 2555.93, "word": " ان", "probability": 0.224365234375}, {"start": 2555.93, "end": 2556.13, "word": " شاء", "probability": 0.966064453125}, {"start": 2556.13, "end": 2556.19, "word": " الله", "probability": 0.955078125}, {"start": 2556.19, "end": 2556.29, "word": " و", "probability": 0.74853515625}, {"start": 2556.29, "end": 2556.73, "word": " بنكمل", "probability": 0.8419596354166666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2557.562, "duration_after_vad": 2469.1349999999925}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/xernIeM-sgU.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/xernIeM-sgU.srt
new file mode 100644
index 0000000000000000000000000000000000000000..2ce7ebc9a8613c1bd52967c4d19e08d293517ee1
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/xernIeM-sgU.srt
@@ -0,0 +1,1418 @@
+
+1
+00:00:20,990 --> 00:00:24,950
+بسم الله الرحمن الرحيم. المرة الماضية، اتكلمنا في
+
+2
+00:00:24,950 --> 00:00:29,290
+تفاعلات الـ alkenes وقلنا أن من ينظر للموضوع نظرة
+
+3
+00:00:29,290 --> 00:00:34,610
+كلية، الموضوع بسيط. الموضوع أن الـ double bond هي
+
+4
+00:00:34,610 --> 00:00:40,230
+رابطتين، بالإضافة، بتصير single bond. هذه العملية، ماذا
+
+5
+00:00:40,230 --> 00:00:46,110
+نسميها؟ عملية addition. عملية addition، واتفقنا أن
+
+6
+00:00:46,110 --> 00:00:48,810
+في الـ addition، في عندنا مكونات للـ addition، في
+
+7
+00:00:48,810 --> 00:00:52,730
+عندنا الـ alkene، وفي عندنا الـ reagent. وهذا ممكن
+
+8
+00:00:52,730 --> 00:00:56,610
+يكون symmetric أو unsymmetric. وهذا نفس الشيء، و
+
+9
+00:00:56,610 --> 00:00:59,610
+دائماً قلنا، بدنا ننتبه لو كان في عندنا
+
+10
+00:00:59,610 --> 00:01:03,550
+unsymmetrical alkene مع unsymmetrical reagent،
+
+11
+00:01:03,550 --> 00:01:09,070
+بنتوقع أنه بيكون عندنا two products. الآن، هنبدأ
+
+12
+00:01:09,070 --> 00:01:13,510
+ناخذ أمثلة على هذا الموضوع تحديدا. لو بدنا نتكلم
+
+13
+00:01:13,510 --> 00:01:18,580
+على إضافة الماء. إضافة الماء، الماء يضيف جزء أيّه؟
+
+14
+00:01:18,580 --> 00:01:25,940
+يضيف H و OH. هذه العملية نسميها hydration. لاحظوا
+
+15
+00:01:25,940 --> 00:01:30,780
+أنه عمليات الإضافة حسب الـ reagent. يعني المرة
+
+16
+00:01:30,780 --> 00:01:35,840
+الماضية، إحنا لما أضفنا الـ hydrogen، عملية إضافة الـ
+
+17
+00:01:35,840 --> 00:01:42,940
+hydrogen، hydrogenation. اسمها واضح؟ عملية إضافة
+
+18
+00:01:42,940 --> 00:01:49,120
+الهيدروجين. الآن، ممكن نضيف الهالوجين بشكل عام،
+
+19
+00:01:49,120 --> 00:01:57,020
+نسميها halogenation. طبعاً، بشكل خاص، chlorination،
+
+20
+00:01:57,020 --> 00:02:05,100
+bromination، وهكذا. ممكن نضيف الميه، نسميها hydration.
+
+21
+00:02:05,100 --> 00:02:14,210
+إضافة الميه، Hydration. واضح؟ ممكن نضيف HX. خلينا
+
+22
+00:02:14,210 --> 00:02:22,530
+نقول HBr أو HCL على طرفي الرابطة. HX نسميها
+
+23
+00:02:22,530 --> 00:02:27,530
+Hydro لأنها فيها Hydrogen، Hydro و Halogen.
+
+24
+00:02:27,530 --> 00:02:34,730
+Halogenation، Hydrohalogenation. كل هذه العمليات هي
+
+25
+00:02:34,730 --> 00:02:40,670
+عمليات إيش؟ إضافة. إذاً، لها أسماء: hydrogenation،
+
+26
+00:02:40,750 --> 00:02:44,430
+halogenation, hydration, hydrohalogenation.
+
+27
+00:02:44,430 --> 00:02:49,010
+بتفاعلات ثانية سنتعلمها بعدين، و ستلاحظون أنه في
+
+28
+00:02:49,010 --> 00:02:53,430
+الكيمياء العضوية دائماً عندكم الأشياء المتعاكسة.
+
+29
+00:02:53,430 --> 00:02:57,770
+بمعنى أن الـ double bond، لما أضيف عليها reagent،
+
+30
+00:02:57,770 --> 00:03:01,370
+بتصير single bond. يعني لو افترضنا أن هذه double
+
+31
+00:03:01,370 --> 00:03:06,030
+bond، أضفت عليها reagent، الناتج single bond. الآن، لو
+
+32
+00:03:06,030 --> 00:03:11,470
+هذه الـ single bond، بتفاعل ثاني، رفعت منها شيئين،
+
+33
+00:03:11,470 --> 00:03:16,510
+هتصير double bond. إذاً، أنا ممكن أعمل إضافة، وممكن
+
+34
+00:03:16,510 --> 00:03:22,760
+أعمل حذف. واضح؟ الـ elimination نسميه. فزي ما في عند
+
+35
+00:03:22,760 --> 00:03:28,840
+addition، في عندنا أيضاً عكسه، elimination. هذه عمليات
+
+36
+00:03:28,840 --> 00:03:34,860
+الـ elimination، أيضاً لها أسماء. بمعنى لو كنا نحذف
+
+37
+00:03:34,860 --> 00:03:39,240
+ذرتين هيدروجين، ونعمل double bond ثانية، هنسمي
+
+38
+00:03:39,240 --> 00:03:44,880
+العملية dehydrogenation. سأستخدم الـ prefix دي، هذا
+
+39
+00:03:44,880 --> 00:03:51,360
+للنفي، D. فأقول dehydrogenation. لو كنت أرفع ذرتين
+
+40
+00:03:51,360 --> 00:03:58,300
+كلور أو بروم، dehalogenation. لو كنت أرفع HOH،
+
+41
+00:03:58,300 --> 00:04:03,900
+dehydration. هذه الكلمة الشهيرة، نزع الماء.
+
+42
+00:04:03,900 --> 00:04:07,520
+Dehydration.
+
+43
+00:04:08,520 --> 00:04:12,700
+لو كنا نرفع الـ ... الـ hydrogen والـ halogen،
+
+44
+00:04:12,700 --> 00:04:17,120
+dehydrohalogenation. واضح؟ dehydrohalogenation.
+
+45
+00:04:17,120 --> 00:04:21,640
+ولذلك، تلاقون هذه الكلمة، انتبهوا لها جيداً، واحفظوها.
+
+46
+00:04:21,640 --> 00:04:26,460
+أنتم في المستقبل، ستصيرون أمهات. dehydration لما
+
+47
+00:04:26,460 --> 00:04:30,620
+الأطفال الصغار يمرضون، يذهبون بهم إلى المستشفيات،
+
+48
+00:04:30,620 --> 00:04:35,630
+يكون... عندهم جفاف. فالطبيب، ماذا يقول عنه؟ عنده
+
+49
+00:04:35,630 --> 00:04:40,070
+dehydration. يعني فقد الماء، الذي عنده، صار عنده جفاف،
+
+50
+00:04:40,070 --> 00:04:44,350
+فبُسمّيها بالانجليزية، إيش الجفاف؟ dehydration. يعني
+
+51
+00:04:44,350 --> 00:04:48,370
+إذا سمعتُم عن طفل عنده dehydration، لازم تعطوه
+
+52
+00:04:48,370 --> 00:04:53,830
+ماذا؟ محاليل. الآن، أول شيء بدنا نبدأ فيه، الـ hydration،
+
+53
+00:04:53,830 --> 00:04:57,750
+إضافة الماء. الآن، إضافة الماء على طرفي الرابطة
+
+54
+00:04:57,750 --> 00:05:05,860
+الزوجية، ماذا سيضع عندها؟ H و OH. واضح القصة؟ طبعاً، في كل
+
+55
+00:05:05,860 --> 00:05:09,920
+شيء، في تفاصيل كثيرة، لكن إحنا أحياناً نتجاوزها في الـ
+
+56
+00:05:09,920 --> 00:05:12,880
+course العام. يعني كيف نضيفه، ليست مشكلة. المهم أن الـ
+
+57
+00:05:12,880 --> 00:05:17,600
+double bond راحت. الـ bi bond ألغيت، صارت two new
+
+58
+00:05:17,600 --> 00:05:24,160
+sigma bonds. واحدة H، واحدة OH. هذا التفاعل بشكل عام.
+
+59
+00:05:24,160 --> 00:05:31,000
+الآن، لو أتيت للتفاعل بحالة خاصة، أطلعت على هذا الـ
+
+60
+00:05:31,000 --> 00:05:35,620
+alkene، اللي هو الـ Isobutyl. الآن، لو أطلعت على هذا
+
+61
+00:05:35,620 --> 00:05:40,380
+الـ Isobutyl، ستلاحظون أنه unsymmetrical alkene. بمعنى،
+
+62
+00:05:40,380 --> 00:05:43,860
+لو أتيت في نصف الـ double bond، تخيلت أني أبدأ أجسم
+
+63
+00:05:43,860 --> 00:05:50,680
+نصفين. هذه C، ماذا تحمل؟ H و H، اختصارات. وهنا C تحمل
+
+64
+00:05:50,680 --> 00:05:57,620
+CH3 و CH3. طيب، لما أنا بدي أضيف الميه، نتخيل الميه،
+
+65
+00:05:57,620 --> 00:06:02,560
+هذين الجزئين، الأزرق والأحمر. بدي أضيف الميه، هل يا
+
+66
+00:06:02,560 --> 00:06:07,620
+ترى، الـ H نعتبرها الزرقاء، نعتبر الـ H الزرقاء، والـ OH
+
+67
+00:06:07,620 --> 00:06:12,980
+الحمراء. هل يا ترى، بدي أحط هنا الـ H وهنا الـ OH، ولا
+
+68
+00:06:12,980 --> 00:06:15,200
+هنا الـ H وهنا الـ OH؟
+
+69
+00:06:19,900 --> 00:06:24,640
+من الناحية النظرية البحتة، من ناحية النظرية،
+
+70
+00:06:24,640 --> 00:06:29,560
+البحتة، لو إحنا بنقول لطفل صغير، تعال شيل هذه وحط
+
+71
+00:06:29,560 --> 00:06:36,060
+الاثنين، ممكن يعمل هكذا، وممكن يعمل هكذا. من ناحية
+
+72
+00:06:36,060 --> 00:06:41,000
+النظرية البحتة، الأمرين ممكنين، ما فيش فيهم ولا
+
+73
+00:06:41,000 --> 00:06:47,280
+مشكلة. الآن، هذين الأمرين، إحنا أعطيناهم أسماء. قلنا،
+
+74
+00:06:47,280 --> 00:06:53,500
+إذا بنضيف الهيدروجين على الكربون التي تحمل
+
+75
+00:06:53,500 --> 00:06:57,520
+هيدروجين أكثر، هذه، الآن لو فصلناها بشكل كامل، هي
+
+76
+00:06:57,520 --> 00:07:03,850
+عبارة عن C تحمل H وH، تمام؟ هذه C لا تحمل أش ولا
+
+77
+00:07:03,850 --> 00:07:08,950
+اتش. لو ضفنا الهيدروجين على الكربون التي تحمل
+
+78
+00:07:08,950 --> 00:07:13,630
+هيدروجين أكثر، نقول هذه الإضافة حسب قواعد
+
+79
+00:07:13,630 --> 00:07:17,650
+Markovnikov، أو حسب قاعدة Markovnikov. وقتها، أروح
+
+80
+00:07:17,650 --> 00:07:22,190
+أحط الـ H هنا، نفترض باللون الأزرق، والـ OH هنا، و
+
+81
+00:07:22,190 --> 00:07:28,710
+يُطلع عندي ناتج، واضح؟ أن جَرّب نعمل الجواب، لو جَرّبنا،
+
+82
+00:07:28,710 --> 00:07:36,900
+سنحط CCH3 CH3، وهذه ستصبح single bond CH2. هذا ما
+
+83
+00:07:36,900 --> 00:07:46,540
+كان موجود أصلاً، كله ما جاء عليه H و OH. الآن، بهذا
+
+84
+00:07:46,540 --> 00:07:50,560
+الشكل، الهيدروجين جاء على أي كربون؟ على التي حملة
+
+85
+00:07:50,560 --> 00:07:56,940
+هيدروجين أكثر. وهذه الإضافة، نسميها إضافة حسب قاعدة
+
+86
+00:07:56,940 --> 00:07:58,140
+Markovnikov.
+
+87
+00:08:05,760 --> 00:08:11,760
+Markovnikov addition. إضافة Markovnikov. إضافة
+
+88
+00:08:11,760 --> 00:08:12,480
+Markovnikov. إضافة Markovnikov. إضافة Markovnikov.
+
+89
+00:08:12,480 --> 00:08:14,080
+إضافة Markovnikov. إضافة Markovnikov. إضافة Markovnikov.
+
+90
+00:08:14,080 --> 00:08:14,240
+إضافة Markovnikov. إضافة Markovnikov. إضافة
+
+91
+00:08:14,240 --> 00:08:14,300
+Markovnikov. إضافة Markovnikov. إضافة Markovnikov.
+
+92
+00:08:14,300 --> 00:08:15,260
+إضافة Markovnikov. إضافة Markovnikov. إضافة Markovnikov.
+
+93
+00:08:15,260 --> 00:08:19,420
+إضافة Markovnikov. إضافة Markovnikov. إضافة
+
+94
+00:08:19,420 --> 00:08:26,320
+Markovnikov. إضافة CH3 CH3، وسأُخلّي هذه single bond
+
+95
+00:08:26,320 --> 00:08:31,380
+CH2. هذا الالكين الأصلي، وأحطهُ بالعكس. يعني الـ H
+
+96
+00:08:31,380 --> 00:08:41,120
+هنا، والـ OH هنا. ماذا
+
+97
+00:08:41,120 --> 00:08:49,170
+المانع؟ ليس مانع. هذه إضافة ماء، وهذه إضافة ماء. هذه
+
+98
+00:08:49,170 --> 00:08:54,330
+الإضافة، نُعطيها اسماً، نقول لها Anti-Markovnikov
+
+99
+00:08:54,330 --> 00:08:58,650
+addition. إضافة عكس قاعدة Markovnikov.
+
+100
+00:09:03,760 --> 00:09:07,420
+Markovnikov addition. إذاً، يمكن أن تكون الإضافة هكذا،
+
+101
+00:09:07,420 --> 00:09:10,380
+ويمكن أن تكون هكذا. ستقولون، طب وإحنا ماذا سيعرفنا
+
+102
+00:09:10,380 --> 00:09:16,380
+كيف نعمل الإضافة؟ نقول، آه، حسب الـ reagent المُستعمل.
+
+103
+00:09:16,380 --> 00:09:22,200
+الماء يمكن أن يضيف بهذا الشكل، وينتج المركب الذي
+
+104
+00:09:22,200 --> 00:09:25,960
+أمامنا هنا على الجهة اليمنى، ويمكن أنه يضيف بالشكل
+
+105
+00:09:25,960 --> 00:09:31,500
+الثاني، وينتج مركب ثاني. ممكن يعطي ناتج إضافة حسب
+
+106
+00:09:31,500 --> 00:09:35,480
+قاعدة Markovnikov، وممكن يعطي عكسها. ستقولون لنا، طب
+
+107
+00:09:35,480 --> 00:09:39,440
+متى يفعل هكذا، ومتى يفعل هكذا؟ الجواب بسيط.
+
+108
+00:09:39,440 --> 00:09:42,680
+لأ، وإحنا نحكي الصورة الكلية التي تُفهم من خلالها.
+
+109
+00:09:42,680 --> 00:09:46,440
+إذا كانت إضافة الماء، يعني هنا على السهم، كتبنا
+
+110
+00:09:46,440 --> 00:09:51,980
+الماء في وجود الحامض، H plus، فإنه يضيف حسب قاعدة
+
+111
+00:09:51,980 --> 00:09:57,190
+Markovnikov. إذا عرفنا ما الشرط الذي من خلاله تتم
+
+112
+00:09:57,190 --> 00:10:02,570
+الإضافة حسب قاعدة Markovnikov، أن نضيف الماء في
+
+113
+00:10:02,570 --> 00:10:08,950
+وجود كمية قليلة من الحامض، وجدناها، نضيف حسب قاعدة
+
+114
+00:10:08,950 --> 00:10:17,600
+Markovnikov. الآن، طب كيف أضيف عكس قاعدة Markovnikov؟
+
+115
+00:10:17,600 --> 00:10:21,200
+إذا
+
+116
+00:10:21,200 --> 00:10:28,020
+ضفنا الماء باستعمال reagent مختلف، طبعاً، ظروف كاملة
+
+117
+00:10:28,020 --> 00:10:34,520
+مختلفة، باستعمال مركب الـ borane، الذي نقوله BH3. طبعاً،
+
+118
+00:10:34,520 --> 00:10:39,660
+بعد ذلك، الـ borane، نضع عليه H2O2، hydrogen peroxide،
+
+119
+00:10:39,660 --> 00:10:46,180
+لو ضفنا في وجود هذه المتفاعلات، نضيف عكس قاعدة
+
+120
+00:10:46,180 --> 00:10:52,160
+Markovnikov. طبعاً، ربما الآن بدأت الصورة تتضح لكم،
+
+121
+00:10:52,160 --> 00:10:56,980
+لأنني أشعر بالصمت عندكم، لأنكم تعلمتم نصف
+
+122
+00:10:56,980 --> 00:11:01,180
+المعلومة بالثانوية، أن الإضافة فقط حسب قاعدة
+
+123
+00:11:01,180 --> 00:11:05,560
+Markovnikov، حسب قاعدة Markovnikov ضمن هذا الشرط،
+
+124
+00:11:05,560 --> 00:11:11,480
+غير الشرط، تحصل على إضافة عكس قاعدة Markovnikov. إذاً،
+
+125
+00:11:11,480 --> 00:11:17,710
+الأمران ممكنان. واضح؟ الذي تعلمتموه بالثانوية، نصف
+
+126
+00:11:17,710 --> 00:11:23,030
+القصة، ليست كل القصة، واضح؟ الذي تعلمتموه بالثانوية،
+
+127
+00:11:23,030 --> 00:11:29,390
+نصف هذه القصة، ليست كلها فقط. الآن، إحنا استكملنا
+
+128
+00:11:29,390 --> 00:11:32,850
+القصة لكم، أن نقول لكم: لأ، والله، يا الميه، بتضيف
+
+129
+00:11:34,860 --> 00:11:39,160
+المياه بتضيف بالطريقتين. هذا الكلام، بعد قليل،
+
+130
+00:11:39,160 --> 00:11:43,520
+ستلاحظونه. ليس اسمع المياه. هذا الكلام، بعد قليل،
+
+131
+00:11:43,520 --> 00:11:49,200
+ستلاحظونه. ليس اسمع المياه. ستلاحظونه حتى مع الـ HBr، على
+
+132
+00:11:49,200 --> 00:11:52,920
+سبيل المثال. يعني لو أخذنا نفس الـ alkene الذي كان
+
+133
+00:11:52,920 --> 00:11:56,820
+عندنا هنا، نعرفه، الـ C double bond C،
+
+134
+00:11:59,940 --> 00:12:08,040
+CH3 و CH3، وقلنا بدنا نكمله باتجاهين، مع الـ HBr، و
+
+135
+00:12:08,040 --> 00:12:13,520
+هنا أيضاً، كتبنا HBr. لو قلنا بدنا نكمل التفاعل مع
+
+136
+00:12:13,520 --> 00:12:20,460
+HBr في وجود H Plus، سيضيف حسب قاعدة Markovnikov، و
+
+137
+00:12:20,460 --> 00:12:24,520
+لو قلنا بدنا نكمل التفاعل مع الـ HBr في وجود
+
+138
+00:12:24,520 --> 00:12:30,160
+بيروكسايد، سيضيف عكس قاعدة Markovnikov. الناتج،
+
+139
+00:12:30,160 --> 00:12:33,340
+ببساطة، نفس الذي موجود عندكم، بدل كلمة OH التي
+
+140
+00:12:33,340 --> 00:12:34,660
+بالأحمر، ماذا ستضع؟
+
+141
+00:12:41,060 --> 00:12:46,580
+إذاً، إضافة الماء، أو إضافة الـ HBr، يمكن أن تتم
+
+142
+00:12:46,580 --> 00:12:51,360
+بطريقة، أو بطريقتين. وهنا يصبح مهماً عندي جداً أن
+
+143
+00:12:51,360 --> 00:12:55,460
+أنتبه للـ reactant، للمتفاعل. يعني لو إحنا مرات بدنا
+
+144
+00:12:55,460 --> 00:12:59,840
+نسألكم عن هذا الموضوع، ممكن نجيب لكم الـ reactant،
+
+145
+00:12:59,840 --> 00:13:03,100
+مع هذا، نقول لكم، اكتبوا النتيجة. ممكن نجيب هذا الـ
+
+146
+00:13:03,100 --> 00:13:06,300
+reactant، والـ product، ونقول لكم، ماذا استعملتم
+
+147
+00:13:06,300 --> 00:13:11,620
+كمُتفاعل؟ اكتبوا الـ reactant الذي على السهم. واضح؟
+
+148
+00:13:11,620 --> 00:13:16,680
+الصورة؟ طبعاً، لو جئنا سألنا، هذه النواتج، الـ
+
+149
+00:13:16,680 --> 00:13:20,100
+Markovnikov product، هذا يُسمى Markovnikov product،
+
+150
+00:13:20,100 --> 00:13:26,020
+والـ antimarkovnikov product. ما العلاقة بينهما؟
+
+151
+00:13:26,020 --> 00:13:30,000
+Isomers.
+
+152
+00:13:30,000 --> 00:13:32,540
+أي نوع من الـ isomers؟ هذا ما أقصده.
+
+153
+00:13:36,070 --> 00:13:40,470
+الـ Markovnikov's product والـ Antimarkovnikov's
+
+154
+00:13:40,470 --> 00:13:45,250
+product. They are isomers. لماذا؟ لأنه نفس الذرات،
+
+155
+00:13:45,250 --> 00:13:50,610
+وضعت H و OH، وضعت الـ H والـ OH، في نفس المواقع، أم
+
+156
+00:13:50,610 --> 00:13:57,670
+في مواقع مختلفة؟ طالما مواقع مختلفة، Different bonding،
+
+157
+00:13:57,670 --> 00:14:04,290
+عطول، الجواب: Structural isomers. They are structural
+
+158
+00:14:04,290 --> 00:14:09,910
+isomers. ليس فيها نقاش. لم ترتبط الذرات من مواقع
+
+159
+00:14:09,910 --> 00:14:13,210
+مختلفة. هنا الهيدروجين على الأولى، والـ OH على
+
+160
+00:14:13,210 --> 00:14:17,470
+الثانية. هنا الـ OH على الأولى، والـ H على الثانية. صح،
+
+161
+00:14:17,470 --> 00:14:20,570
+أم لا؟ Different bonding، different names،
+
+162
+00:14:20,570 --> 00:14:27,490
+structural isomers. واضح؟ إذاً، فكرة إضافة الـ
+
+163
+00:14:27,490 --> 00:14:33,850
+unsymmetrical agents، ممكن تضيف بطريقتين. Markovnikov،
+
+164
+00:14:33,850 --> 00:14:37,450
+وانتي Markovnikov، حسب ظروف التفاعل. ما الأمثلة
+
+165
+00:14:37,450 --> 00:14:43,840
+المطلوب مني أن أعرفها؟ الماء، والـ HBr، بدون تفاصيل
+
+166
+00:14:43,840 --> 00:14:47,600
+الميكانيزم، التي أحياناً ممكن تلاقوها موجودة عندكم.
+
+167
+00:14:47,600 --> 00:14:50,920
+يعني أنا في النهاية، الـ course، general organic،
+
+168
+00:14:50,920 --> 00:14:56,340
+course، يهمني أن تصلوا فيه للنتيجة بشكل عام. ولذلك، على
+
+169
+00:14:56,340 --> 00:14:59,960
+طول الآن، ممكن نأخذ أمثلة إضافية، وتشوفوا كيف
+
+170
+00:14:59,960 --> 00:15:04,520
+الأمثلة الإضافية، نُكملها بدون ما ندخل بتفاصيل كيف
+
+171
+00:15:04,520 --> 00:15:08,260
+تمت العملية، المهم عندي الناتج.
+
+172
+00:15:19,100 --> 00:15
+
+223
+00:19:27,380 --> 00:19:33,680
+بعد أنا بحكي عن الاتصال المباشر مش موراء، ما بعد
+
+224
+00:19:33,680 --> 00:19:38,460
+بعد حيفا شو مالي وماله هذا؟ اه هنا هيدروجين ثاني
+
+225
+00:19:38,460 --> 00:19:42,400
+مباشر هنا هيدروجين وكربون، مين عليها هيدروجين أكثر؟
+
+226
+00:19:42,400 --> 00:19:48,780
+هذه بناءً على ذلك، لما أنا بقول بدي أضيف HPR في وجود
+
+227
+00:19:48,780 --> 00:19:53,320
+H Plus، وين اجت الهيدروجين؟ بهذا الشكل، وين اجت ال
+
+228
+00:19:53,320 --> 00:20:02,760
+PR؟ بهذا الشكل، واضح؟ هي اللي بدي إياها دلوقت بتيجي
+
+229
+00:20:02,760 --> 00:20:09,060
+بالجهتين، من فوق ومن تحت، قليلاً بس شوية، هذه
+
+230
+00:20:09,060 --> 00:20:14,000
+الفكرة متطورة أكثر من أن أشرح فيها بقى، بتيجي من
+
+231
+00:20:14,000 --> 00:20:17,260
+فوق ومن تحت يعني، بس مش موضوعنا لإنه علاقة
+
+232
+00:20:17,260 --> 00:20:22,410
+بالستيل والكيمستري، الآن هاي مركب ثانية عندكم
+
+233
+00:20:22,410 --> 00:20:27,170
+double bond، وين الطرفين الـ double bond؟ هيدي وهيدي،
+
+234
+00:20:27,170 --> 00:20:33,570
+الآن هنا في شيء مش مرسوم، ولا لأ؟ أكيد الـ H، الأكيد
+
+235
+00:20:33,570 --> 00:20:35,150
+الـ H، الأكيد الـ H، الأكيد الـ H، الأكيد الـ
+
+236
+00:20:35,150 --> 00:20:35,390
+H، الأكيد الـ H، الأكيد الـ H، الأكيد الـ H
+
+237
+00:20:35,390 --> 00:20:35,870
+الأكيد الـ H، الأكيد الـ H، الأكيد الـ H
+
+238
+00:20:35,870 --> 00:20:35,890
+الأكيد الـ H، الأكيد الـ H، الأكيد الـ H
+
+239
+00:20:35,890 --> 00:20:36,110
+الأكيد الـ H، الأكيد الـ H، الأكيد الـ H
+
+240
+00:20:36,110 --> 00:20:36,610
+الأكيد الـ H، الأكيد الـ H، الأكيد الـ H
+
+241
+00:20:36,610 --> 00:20:39,010
+الأكيد الـ H، الأكيد الـ H، الأكيد الـ H
+
+242
+00:20:39,010 --> 00:20:44,980
+الأكيد الـ H، الأكيد الـ H، إذا لو أنا كنت بدي
+
+243
+00:20:44,980 --> 00:20:51,000
+أكمل HPR في وجود H Plus، كيف سأكتب الناتج؟ يعني لو
+
+244
+00:20:51,000 --> 00:20:57,060
+أنه أكمل المعادلة HPR، H Plus، بدي أحط الهيدروجين على
+
+245
+00:20:57,060 --> 00:21:02,360
+اللي حاملة هيدروجين أكثر، يعني بدي أحطها هناسيه H3
+
+246
+00:21:02,360 --> 00:21:12,340
+وH، هدول اللي كانوا أصلاً موجودات، بدي أحط الـ H تحت الـ
+
+247
+00:21:12,340 --> 00:21:18,800
+PR على هذا الكربون، هذه إضافة ماركوفنيكوف، الآن لما
+
+248
+00:21:18,800 --> 00:21:24,560
+نيجي نعطيكم، كملوا المعادلة HPR في وجود البروكسايد،
+
+249
+00:21:24,560 --> 00:21:29,300
+بدي أحط بالعكس، بدي أحط بالعكس، ولذلك لو بتيجي
+
+250
+00:21:29,300 --> 00:21:33,080
+تتطلعوا هنا، وين الـ PR موجودة على أي كربون؟
+
+251
+00:21:35,850 --> 00:21:39,270
+هيها، طبعاً هو ورا، السهم مرة لتحت ومرة لفوق، هذا
+
+252
+00:21:39,270 --> 00:21:43,710
+السؤال الذكي اللي سألته زميلتكم، بس بدناش نطول فيه،
+
+253
+00:21:43,710 --> 00:21:46,830
+بيجعل
+
+254
+00:21:46,830 --> 00:21:51,550
+جهتين، مش فيها مشكلة، بس في كل الأحوال على أي carbon
+
+255
+00:21:51,550 --> 00:21:56,560
+اجت الـ PR على حاملة الهيدروجين، على أي كربون اجت
+
+256
+00:21:56,560 --> 00:22:00,840
+الهيدروجين؟ على اللي أقل، هذي Markovnikov ولا أنتِ
+
+257
+00:22:00,840 --> 00:22:05,680
+Markovnikov؟ أنا ما بديش آكلتوها، في الشكل فوق و
+
+258
+00:22:05,680 --> 00:22:11,140
+تحت، حطوهم بس بالموقع الصح، وغلط ومكفي، واضح؟
+
+259
+00:22:11,140 --> 00:22:15,140
+يعني لما بنكمل هذه المعادلة، ببساطة إيش يكون
+
+260
+00:22:15,140 --> 00:22:24,560
+الجواب؟ هنا الـ H وهنا الـ PR، هيك الناتج بدون ما يصير أكثر
+
+261
+00:22:24,560 --> 00:22:29,580
+من هيك تفصيل، ما بيلزمني، هذه مع أو عكس Markovnikov
+
+262
+00:22:29,580 --> 00:22:33,700
+لما يكون هيك، جوابه، لغير الـ double bond، عكس
+
+263
+00:22:33,700 --> 00:22:38,500
+Markovnikov، هنا الـ H، هنا الـ PR، مع Markovnikov
+
+264
+00:22:38,500 --> 00:22:39,200
+فاهمين؟
+
+265
+00:22:50,600 --> 00:22:58,020
+بيجينا بعد هذه الإضافة، إضافة جديدة، هذه الإضافة
+
+266
+00:22:58,020 --> 00:22:59,980
+الجديدة
+
+267
+00:23:01,170 --> 00:23:07,110
+إن برضه إحنا بنلغي فيها الـ double bond وبنعمل two
+
+268
+00:23:07,110 --> 00:23:11,010
+new sigma bonds، لكن هدول الـ two new sigma bonds
+
+269
+00:23:11,010 --> 00:23:15,450
+بيكونوا على نفس ذرة الأكسجين، ولذلك بيعطوني حلقة
+
+270
+00:23:15,450 --> 00:23:19,250
+ثلاثية، لاحظوا هذا الكلام كيف، هي عندكم carbon
+
+271
+00:23:19,250 --> 00:23:24,450
+carbon double bond، صح ولا لأ؟ الآن لو فعلناها مع
+
+272
+00:23:24,450 --> 00:23:31,330
+per acid، per بادئة معناها فوق، يعني فيه زيادة
+
+273
+00:23:31,330 --> 00:23:40,170
+الحامض العضوي، كم أكسجين فيه عادة الـ acid؟ تلت
+
+274
+00:23:40,170 --> 00:23:44,570
+ثلاث روابط مع الأكسجين، يعني الـ acid شكله العام
+
+275
+00:23:44,570 --> 00:23:55,300
+بهذا الشكل، R C double bond O OH، مش RCOOH
+
+276
+00:23:55,300 --> 00:23:59,640
+لو كانت هذه CH3 بيكون الأسيتيك أسد، لو كانت فنل
+
+277
+00:23:59,640 --> 00:24:05,260
+بيكون البنزويك أسد، الآن لو اجينا جنب الـ COH
+
+278
+00:24:05,260 --> 00:24:12,400
+هتضيف لنا كمان O، يعني خلينا COOH زي هذا المركب اللي
+
+279
+00:24:12,400 --> 00:24:17,700
+هنا RCOOH
+
+280
+00:24:17,700 --> 00:24:24,640
+هذا زاد عندي بإيش؟ بأكسجينة، صار فيه ثلاث أكسجينات
+
+281
+00:24:24,640 --> 00:24:28,640
+هذا كم أكسجين فيه؟ ثلاث، الآن هذا المركب اللي
+
+282
+00:24:28,640 --> 00:24:34,920
+صار شكله العام R C double bond O O OH، بنسميه per
+
+283
+00:24:34,920 --> 00:24:41,230
+acid، فوق حامض، يعني زاد فيه الأكسجين بمقدار
+
+284
+00:24:41,230 --> 00:24:46,310
+بي عرفنا إيش معنى per acid، ولما نسميه بنسميه على
+
+285
+00:24:46,310 --> 00:24:49,570
+اسم الحامض الأصلي اللي كان موجود، يعني لو افترضنا
+
+286
+00:24:49,570 --> 00:24:54,810
+الحامض الأصلي أسيتيك أسد، بصير اللي فيه أكسجينة
+
+287
+00:24:54,810 --> 00:25:01,350
+زيادة بير أسيتيك أسد، بنزويك أسد، بير بنزويك أسد،
+
+288
+00:25:01,350 --> 00:25:06,930
+يعني نفس الحامض تماماً بس بنزيد عليه إيش؟ بير، يمكن
+
+289
+00:25:06,930 --> 00:25:12,590
+مرت عليكم لما أخذتو أحماض الكلور مع الأكسجين، لما
+
+290
+00:25:12,590 --> 00:25:18,510
+أخذتو البيركلوريك أسد، مش كان عندكم ClO3 لكلوريك
+
+291
+00:25:18,510 --> 00:25:25,530
+أسد، لما صار ClO4، زاد أكسجينة، بيركلوريك أسد، واضح؟
+
+292
+00:25:25,530 --> 00:25:31,230
+فـ per هنا بمعنى إيش؟ الزيادة، لو فعلنا الألكين مع
+
+293
+00:25:31,230 --> 00:25:36,480
+الـ per acid مرة ثانية، بتنكسر الـ double bond وبتعمل
+
+294
+00:25:36,480 --> 00:25:40,900
+رابطتين sigma لكن مع نفس ذرة الأكسجين، إذا هذه
+
+295
+00:25:40,900 --> 00:25:48,220
+العملية أيضاً عملية إيش؟ إضافة، تحويل الـ pi bond إلى
+
+296
+00:25:48,220 --> 00:25:54,080
+two new sigma bonds، إضافة ولا مش إضافة؟ إضافة، لكن
+
+297
+00:25:54,080 --> 00:25:56,880
+الآن الـ two new sigma bonds على نفس الأكسجين،
+
+298
+00:25:56,880 --> 00:26:04,040
+فالناتج حلقة ثلاثية، الناتج حلقة ثلاثية، هذه الحلقة
+
+299
+00:26:04,040 --> 00:26:10,460
+الثلاثية من ذرتين كربون ومن أكسجين، حلقة ثلاثية،
+
+300
+00:26:10,460 --> 00:26:14,560
+ذرتين كربون وأكسجين، هذه الثلاث ذرات،  تعرفوها الآن،
+
+301
+00:26:14,560 --> 00:26:21,140
+هذه الحلقة الثلاثية كعائلة بنسميها إيبوك سايد، يعني
+
+302
+00:26:21,140 --> 00:26:25,380
+لو قلت لكم ما هي عائلة الإيبوك سايد؟ لاحظوا family في
+
+303
+00:26:25,380 --> 00:26:29,660
+عندنا family وفي عندنا جوا الـ family إيش؟ أفراد
+
+304
+00:26:30,500 --> 00:26:33,720
+هيك بتكونوا تفهموا الكيمياء، إن في عائلة عامة زي الـ
+
+305
+00:26:33,720 --> 00:26:40,800
+ketones، الـ ketone family عائلة، الآن جواتها acetone
+
+306
+00:26:40,800 --> 00:26:46,740
+و cyclohexanone وكذا وكذا، الـ alkenes عائلة، جواتها
+
+307
+00:26:46,740 --> 00:26:53,910
+إيثين، بروبين، الآن الإيبوك سايدز عائلة أيضاً، مش
+
+308
+00:26:53,910 --> 00:26:59,130
+اسم مركب، الإيبوك سايد عائلة، الآن طيب إيش في جوا هذه
+
+309
+00:26:59,130 --> 00:27:05,730
+العائلة مركبات؟ كربون ثنين وأكسجين، وين بدو يصير
+
+310
+00:27:05,730 --> 00:27:10,630
+الاختلاف؟ بدو يصير الاختلاف في هدول المجموعات، هل هدول
+
+311
+00:27:10,630 --> 00:27:14,130
+الأربعة هيدروجينات؟ هل واحدة فيهم مثيل؟ هل اثنتين
+
+312
+00:27:14,130 --> 00:27:16,910
+مثل؟ هل الثلاث مثل؟ هل الأربع مثل؟ هل واحدة إيثيل؟
+
+313
+00:27:16,910 --> 00:27:23,540
+هل واحدة بروبيل؟ وجدناها، بيصير لكل مركب اسم، طيب كيف
+
+314
+00:27:23,540 --> 00:27:28,760
+بنسمي كل مركب؟ العملية سهلة، بنيجي بنسأل نفسنا إيش
+
+315
+00:27:28,760 --> 00:27:36,160
+اسم الألكين الأصلي تبعه اللي كونه؟ والناتج لما
+
+316
+00:27:36,160 --> 00:27:39,900
+نعمله بنسميه باسم الألكين، بنضيف عليه oxide، يعني
+
+317
+00:27:39,900 --> 00:27:46,200
+مثلاً لو كان الألكين اللي عندكم CH2 double bond CH2
+
+318
+00:27:46,200 --> 00:27:53,580
+هينتج لنا مركب محدد، هذا إيش اسمه؟ إيثيلين أو إثيل
+
+319
+00:27:53,580 --> 00:27:59,300
+إيثيلين، الآن فعلناها مع الـ per acid هذا اللي موجود
+
+320
+00:27:59,300 --> 00:28:05,840
+عندنا، بتلغي هذه الـ pi bond وبتعطيني أكسجينة، صار
+
+321
+00:28:05,840 --> 00:28:11,480
+عندي CH2، خليني نخلي الهيدروجين يخلع برا، مرسومين
+
+322
+00:28:11,480 --> 00:28:14,620
+CH2
+
+323
+00:28:14,620 --> 00:28:23,280
+CH2 وهنا أكسجين، الآن هذا من أي مركب نتاج؟ من
+
+324
+00:28:23,280 --> 00:28:30,910
+الإيثيلين، شو بدي اسميه؟ إيثيلين أكسيد، نسبة للأصل، إذا
+
+325
+00:28:30,910 --> 00:28:35,970
+تسمية هذه المركبات، تسمية هذه المركبات، كل فرد
+
+326
+00:28:35,970 --> 00:28:42,350
+منها كيف بسميه؟ باسم الألكين الأصلي مضاف إليه كلمة
+
+327
+00:28:42,350 --> 00:28:49,350
+أكسايد، إيثيلين أكسيد، واضحة الفكرة ولا لأ؟ ماشي
+
+328
+00:28:49,350 --> 00:28:53,410
+أتأكد أنها واضحة ولا لأ؟ الآن لو إني جبت هذا
+
+329
+00:28:53,410 --> 00:28:58,310
+المركب في الامتحان وقلت لكم، لو سمحتوا سمولي هذا
+
+330
+00:28:58,310 --> 00:29:04,760
+المركب، زي هيك، هذا جايكم في الامتحان وأنا قلت لكم
+
+331
+00:29:04,760 --> 00:29:11,860
+سموه، واحدة
+
+332
+00:29:11,860 --> 00:29:15,960
+بس Cyclohexane
+
+333
+00:29:15,960 --> 00:29:22,210
+Oxide، بتكونوا تقولوا هذا إيش كان أصله؟ اللي شيلت
+
+334
+00:29:22,210 --> 00:29:26,990
+هذه… هذا أصلاً كان هيك، لما ضفت عليه شيلت الـ
+
+335
+00:29:26,990 --> 00:29:30,910
+double bond وحطيت الأكسجين، طيب زي هيك إيش اسمه؟
+
+336
+00:29:30,910 --> 00:29:41,120
+Cyclohexane، شلنا هذه، صار Cyclohexane oxide، واضح؟
+
+337
+00:29:41,120 --> 00:29:48,940
+إذا هذه المركبات كأفراد تسمى باسم الألكين الأصلي
+
+338
+00:29:48,940 --> 00:29:55,160
+باسم الألكين الأصلي مضاف إليه كلمة Oxide، واضحة ولا
+
+339
+00:29:55,160 --> 00:30:04,340
+ما واضحة؟ واضحة تماماً، الآن إلها تسمية ثانية كتير
+
+340
+00:30:04,340 --> 00:30:10,260
+في ناس بياخدوا أكثر من اسم، إلها تسمية ثانية، أبسط
+
+341
+00:30:10,260 --> 00:30:15,340
+مركب في هذه العائلة كلها، أي واحد؟ الـ ethylene
+
+342
+00:30:15,340 --> 00:30:22,620
+oxide، ليش؟ لأنه هنا O CH2 CH2، هذا المركب
+
+343
+00:30:22,620 --> 00:30:27,980
+الأبسط فيهم، هذا المركب الأبسط ماخد اسم، اسمه
+
+344
+00:30:27,980 --> 00:30:37,990
+Oxirane، Oxirane تمام؟ Oxirane بنحفظ اسمه كويس، الآن
+
+345
+00:30:37,990 --> 00:30:43,270
+هذا الـ Oxirane بنتخيله ثلاث مواقع، بنبدأ ترقيمه من
+
+346
+00:30:43,270 --> 00:30:50,170
+الأكسجين، بنقول واحد، اثنين، ثلاثة، بنسميه الـ parent
+
+347
+00:30:50,170 --> 00:30:55,410
+compound، عمرنا قلنا كلمة parent، المركب الأبسط
+
+348
+00:30:55,410 --> 00:30:59,310
+دائماً بنقول عنه الـ parent compound، الآن هذا الـ
+
+349
+00:30:59,310 --> 00:31:02,610
+parent compound، لو يا ترى شيلنا من هدول الـ
+
+350
+00:31:02,610 --> 00:31:10,870
+hydrogen، الـ hydrogen واحدة وحطينا بدلها CH3 واحدة،
+
+351
+00:31:10,870 --> 00:31:12,610
+تقولوا إيش بدها تسمية وقتها؟
+
+352
+00:31:15,250 --> 00:31:20,130
+أوكسيرين، المركب الأصلي، على موقع اثنين إيش إجاله؟
+
+353
+00:31:20,130 --> 00:31:30,210
+مثيل، إذا هذا بيصير two methyl oxirane، أنا اعتبرت الـ
+
+354
+00:31:30,210 --> 00:31:34,990
+أوكسيرين اللي فيه أربعة هيدروجين، شيلت منه واحدة،
+
+355
+00:31:34,990 --> 00:31:39,630
+محل ما شلت بكتب اسم المجموعة، لو كانت كلور، two chloro
+
+356
+00:31:39,630 --> 00:31:44,780
+أوكسيرين، لو كانت إيثيل، two ethyl oxirane، عرفنا كيف
+
+357
+00:31:44,780 --> 00:31:49,800
+هذا بنسميه؟ الآن هي تسمية هذا المركب اللي أمامكم
+
+358
+00:31:49,800 --> 00:31:54,360
+بطريقة الـ Oxirane، طيب لو واحد بدأ يسميه بطريقة الـ
+
+359
+00:31:54,360 --> 00:32:02,200
+alkyl oxide، شو هتسميه؟ بروبيل أكسيد، بروبيل
+
+360
+00:32:02,200 --> 00:32:04,780
+أكسيد، بروبيل أكسيد، بروبيل أكسيد، بروبيل أكسيد،
+
+361
+00:32:04,780 --> 00:32:05,560
+بروبول أكسيد، بروبيل أكسيد، بروبيل أكسيد، بروبيل
+
+362
+00:32:05,560 --> 00:32:06,080
+أكسيد، بروبيل أكسيد، بروبيل أكسيد، بروبيل أكسيد،
+
+363
+00:32:06,080 --> 00:32:08,440
+بروبول أكسيد، بروبيل أكسيد، بروبيل أكسيد، بروبيل
+
+364
+00:32:08,440 --> 00:32:16,320
+أكسيد، بروبيل أكسيد، هذا الألكين؟ واحد CH2 double
+
+365
+00:32:16,320 --> 00:32:22,300
+bond CH CH3، هذا البروبيل، ولذلك بيصير بروبيل
+
+366
+00:32:22,300 --> 00:32:27,900
+أكسيد، فلو جبنالكم مثلاً سؤال، بروبيل أكسيد is also
+
+367
+00:32:27,900 --> 00:32:32,780
+called، وقتها بتقولوا 2-methyl oxirane، 2-methyl
+
+368
+00:32:32,780 --> 00:32:38,900
+oxirane is also called propyl oxide، طبعاً الـ Oxirane
+
+369
+00:32:38,900 --> 00:32:42,760
+هذه في الكيمياء الحلقية غير المتجانسة، بنستعملها
+
+370
+00:32:42,760 --> 00:32:46,480
+أكثر في الكيمياء العادية، المشهورة أكثر يكون يسموها
+
+371
+00:32:46,480 --> 00:32:54,720
+نسبة للألكين وتحطوا إيش؟ Oxide، الإسمين بتلاقوهم، إذا
+
+372
+00:32:54,720 --> 00:33:01,620
+شفنا هذه المركبات كيف بنحضرها وكيف بنسميها، كيف
+
+373
+00:33:01,620 --> 00:33:05,560
+بنحضرها وكيف بنسميها،  عساريًا، مينيندسيا، هل هذه
+
+374
+00:33:05,560 --> 00:33:08,800
+التسمية تسميتها IUPAC ولا IUPAC؟ لأ لأ، هي
+
+375
+00:33:08,800 --> 00:33:14,240
+التسمية اللي هي الـ oxirane، نظام تسمية بنسموه Hans
+
+376
+00:33:14,240 --> 00:33:18,550
+Wiedemann system of nomenclature، يستعمل عن طلاب
+
+377
+00:33:18,550 --> 00:33:23,570
+الكيمياء للـ heterocyclic compounds، واضح؟ hence
+
+378
+00:33:23,570 --> 00:33:26,570
+Wiedemann system of nomenclature، الآن خلينا ناخد
+
+379
+00:33:26,570 --> 00:33:32,050
+أمثلة، نسهل الموضوع، هي كذا مثال، جيبنا أكمل مع per
+
+380
+00:33:32,050 --> 00:33:36,950
+acid، شو عرفني per acid؟ ثلاث أكسجينات في كل
+
+381
+00:33:36,950 --> 00:33:42,370
+الأحوال، شو اللي بدي أعمله؟ أشيل الـ double bond؟ أحط
+
+382
+00:33:42,370 --> 00:33:48,510
+مكانها أكسجين، أشيل الـ double bond أحط أكسجين، أشيل
+
+383
+00:33:48,510 --> 00:33:52,630
+الـ double bond أحط أكسجين، إذا الأمر سهل وبسيط ولا
+
+384
+00:33:52,630 --> 00:33:57,110
+لأ، الألكين مع الـ per acid، أشيل الـ double bond، أحط
+
+385
+00:33:57,110 --> 00:34:02,350
+أكسجين في حلقة ثلاثية، كل هذه، لو إجا شخص من برة و
+
+386
+00:34:02,350 --> 00:34:07,070
+يتطلع على السبورة ويقول له شو هذه المركبات؟ شو بدي
+
+387
+00:34:07,070 --> 00:34:14,200
+يجاوبنا؟ epoxides، مش عائلة الإيبوك سايدز، فلو يوم من
+
+388
+0
+
+445
+00:39:09,790 --> 00:39:16,470
+electrophile شيء موجب يحب السالب لأن nucleophile شيء
+
+446
+00:39:16,470 --> 00:39:20,350
+سالب يحب الموجب، هدول شغلتين بتفاعلوا مع بعض يعني
+
+447
+00:39:20,350 --> 00:39:24,090
+كأنه ببساطة، ممكن واحدة اللي مش كتير حابة
+
+448
+00:39:24,090 --> 00:39:28,050
+هالمصطلحين، لأول مرة واحدة تقول يعني موجب وسالب، اه
+
+449
+00:39:28,050 --> 00:39:32,110
+ببساطة يعني موجب وسالب، لكن احنا من اليوم وطالع في
+
+450
+00:39:32,110 --> 00:39:34,750
+الـorganic chemistry الموجب إيش هنسميه؟
+
+451
+00:39:35,390 --> 00:39:40,390
+electrophile والسالب إيش هنسميه؟ nucleophile الآن
+
+452
+00:39:40,390 --> 00:39:47,510
+هنقول إنّ nucleophile بيهاجم على الـelectrophile
+
+453
+00:39:47,510 --> 00:39:52,390
+بيعمل رابطة، ممكن الـnucleophile يكون OH جاية من
+
+454
+00:39:52,390 --> 00:39:56,030
+المياه أو تيجي من الماء، فلما ييجي هذا الـOH
+
+455
+00:39:56,030 --> 00:40:00,470
+هنهيجم، معقول يصيروا خمس روابط؟ ولا هتكسر هذه
+
+456
+00:40:00,470 --> 00:40:10,140
+الرابطة، تكسر وتفتح، هتتحول الـO هذه إلى OH الآن بهذه
+
+457
+00:40:10,140 --> 00:40:13,220
+المنطقة، راجعوا المرة اللي جايه الـroad map نبدأ من عند
+
+458
+00:40:13,220 --> 00:40:16,400
+هذه النقطة، لكن بتكونوا تدربتوا أكثر، وبنشرح كل
+
+459
+00:40:16,400 --> 00:40:20,940
+الأمثلة، إيش معنى electrophile؟ إيش معنى nucleophile؟
+
+460
+00:40:20,940 --> 00:40:24,680
+ها بتتدربوا عليها، بنشوف كيف الـring opening بيصير
+
+461
+00:40:24,680 --> 00:40:26,600
+بأكثر من مثل
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/xernIeM-sgU_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/xernIeM-sgU_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..ab5049a9c1ee46e3f328ab2e7517035a38f7572b
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/xernIeM-sgU_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 5005, "start": 20.99, "end": 50.05, "text": "بسم الله الرحمن الرحيم المرة الماضية اتكلمنا في تفاعلات ال alkenes وقلنا اللى بينظر للموضوع نظرة كلية الموضوع بسيط الموضوع انه double bond هيوم رابطتين بالاضافة بتصير single bond هذه العملية شو بنسميها عملية addition عملية addition واتفقنا ان في ال addition فى عندنا مكونات لل addition فى عندنا ال alkene", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 1975, 2655, 4117, 19528, 8315, 8978, 6055, 5172, 995, 30241, 9307, 2423, 419, 2653, 279, 4032, 4587, 1211, 8315, 13672, 7578, 4724, 9957, 19913, 2288, 5296, 19528, 2407, 11242, 45367, 8717, 19913, 25720, 28242, 10632, 9673, 2407, 11242, 45367, 4724, 3794, 1829, 9566, 9673, 2407, 11242, 45367, 16472, 3224, 3834, 6086, 8032, 1829, 20498, 12602, 16758, 9566, 2655, 9957, 20666, 46958, 31845, 3660, 39894, 9381, 13546, 2167, 6086, 29538, 18863, 42213, 10632, 13412, 2407, 44945, 38251, 1829, 11296, 6225, 42213, 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"probability": 0.998779296875}, {"start": 776.88, "end": 777.92, "word": " ممكن", "probability": 0.9912109375}, {"start": 777.92, "end": 778.68, "word": " نجيبلكوا", "probability": 0.9183756510416666}, {"start": 778.68, "end": 779.2, "word": " ال", "probability": 0.9453125}, {"start": 779.2, "end": 779.84, "word": " reactant", "probability": 0.98291015625}, {"start": 779.84, "end": 780.08, "word": " مع", "probability": 0.99560546875}, {"start": 780.08, "end": 780.32, "word": " هذا", "probability": 0.98291015625}, {"start": 780.32, "end": 780.68, "word": " نقولكوا", "probability": 0.83038330078125}, {"start": 780.68, "end": 781.02, "word": " اكتبوا", "probability": 0.9337890625}, {"start": 781.02, "end": 781.62, "word": " النتيجة", "probability": 0.9661865234375}, {"start": 781.62, "end": 782.3, "word": " ممكن", "probability": 0.976318359375}, {"start": 782.3, "end": 782.68, "word": " نجيب", "probability": 0.9957275390625}, {"start": 782.68, "end": 782.98, "word": " هذا", "probability": 0.98095703125}, {"start": 782.98, "end": 783.1, "word": " ال", "probability": 0.96484375}, {"start": 783.1, "end": 783.64, "word": " reactant", "probability": 0.990478515625}, {"start": 783.64, "end": 783.8, "word": " و", "probability": 0.8603515625}, {"start": 783.8, "end": 783.9, "word": " ال", "probability": 0.8935546875}, {"start": 783.9, "end": 784.36, "word": " product", "probability": 0.96435546875}, {"start": 784.36, "end": 784.72, "word": " و", "probability": 0.9814453125}, {"start": 784.72, "end": 785.08, "word": " نقولكوا", "probability": 0.9239501953125}, {"start": 785.08, "end": 785.26, "word": " شو", "probability": 0.93994140625}, {"start": 785.26, "end": 785.4, "word": " اللي", "probability": 0.9482421875}, {"start": 785.4, "end": 786.3, "word": " استعملته", "probability": 0.9451904296875}, {"start": 786.3, "end": 787.36, "word": " كمتفاعل", "probability": 0.8946126302083334}, {"start": 787.36, "end": 789.04, "word": " كتبولي", "probability": 0.68095703125}, {"start": 789.04, "end": 789.14, "word": " ال", "probability": 0.939453125}, {"start": 789.14, "end": 789.7, "word": " reactant", "probability": 0.986572265625}, {"start": 789.7, "end": 789.88, "word": " اللي", "probability": 0.96337890625}, {"start": 789.88, "end": 790.0, "word": " على", "probability": 0.72509765625}, {"start": 790.0, "end": 790.34, "word": " السهل", "probability": 0.5555013020833334}], "temperature": 1.0}, {"id": 33, "seek": 81254, "start": 791.08, "end": 812.54, "text": "واضحك الصورة؟ طبعا لو إجينا سألنا هذه النواتج ال markovnikov product هذا بيسموه markovnikov product و ال antimarkovnikov product ما العلاقة بينهما؟ isomers أي نوع من ال isomers هذا اللي بقصدي", "tokens": [2407, 46958, 5016, 4117, 31767, 13063, 3660, 22807, 23032, 3555, 3615, 995, 45164, 11933, 7435, 1829, 8315, 8608, 10721, 1211, 8315, 29538, 28239, 2407, 9307, 7435, 2423, 1491, 5179, 13123, 5179, 1674, 23758, 4724, 1829, 38251, 2407, 3224, 1491, 5179, 13123, 5179, 1674, 4032, 2423, 46141, 809, 5179, 13123, 5179, 1674, 19446, 18863, 15040, 28671, 49374, 3224, 15042, 22807, 307, 298, 433, 36632, 8717, 45367, 9154, 2423, 307, 298, 433, 23758, 13672, 1829, 4724, 4587, 9381, 16254], "avg_logprob": -0.21314102831559303, "compression_ratio": 1.6091954022988506, "no_speech_prob": 0.0, "words": [{"start": 791.08, "end": 791.62, "word": "واضحك", "probability": 0.8958740234375}, {"start": 791.62, "end": 792.86, "word": " الصورة؟", "probability": 0.870361328125}, {"start": 792.86, "end": 793.3, "word": " طبعا", "probability": 0.962646484375}, {"start": 793.3, "end": 793.62, "word": " لو", "probability": 0.88330078125}, {"start": 793.62, "end": 794.02, "word": " إجينا", "probability": 0.746337890625}, {"start": 794.02, "end": 794.64, "word": " سألنا", "probability": 0.8466796875}, {"start": 794.64, "end": 795.26, "word": " هذه", "probability": 0.66943359375}, {"start": 795.26, "end": 796.22, "word": " النواتج", "probability": 0.89404296875}, {"start": 796.22, "end": 796.68, "word": " ال", "probability": 0.5185546875}, {"start": 796.68, "end": 797.64, "word": " markovnikov", "probability": 0.68328857421875}, {"start": 797.64, "end": 798.18, "word": " product", "probability": 0.79443359375}, {"start": 798.18, "end": 798.5, "word": " هذا", "probability": 0.669921875}, {"start": 798.5, "end": 798.92, "word": " بيسموه", "probability": 0.87177734375}, {"start": 798.92, "end": 799.6, "word": " markovnikov", "probability": 0.898681640625}, {"start": 799.6, "end": 800.1, "word": " product", "probability": 0.955078125}, {"start": 800.1, "end": 800.5, "word": " و", "probability": 0.59814453125}, {"start": 800.5, "end": 800.66, "word": " ال", "probability": 0.8779296875}, {"start": 800.66, "end": 801.7, "word": " antimarkovnikov", "probability": 0.843994140625}, {"start": 801.7, "end": 802.22, "word": " product", "probability": 0.9638671875}, {"start": 802.22, "end": 802.36, "word": " ما", "probability": 0.68017578125}, {"start": 802.36, "end": 802.92, "word": " العلاقة", "probability": 0.9606119791666666}, {"start": 802.92, "end": 806.02, "word": " بينهما؟", "probability": 0.78436279296875}, {"start": 806.02, "end": 810.0, "word": " isomers", "probability": 0.738525390625}, {"start": 810.0, "end": 810.32, "word": " أي", "probability": 0.53466796875}, {"start": 810.32, "end": 810.68, "word": " نوع", "probability": 0.996826171875}, {"start": 810.68, "end": 810.9, "word": " من", "probability": 0.99609375}, {"start": 810.9, "end": 811.06, "word": " ال", "probability": 0.95654296875}, {"start": 811.06, "end": 811.7, "word": " isomers", "probability": 0.958984375}, {"start": 811.7, "end": 811.92, "word": " هذا", "probability": 0.7802734375}, {"start": 811.92, "end": 812.06, "word": " اللي", "probability": 0.97705078125}, {"start": 812.06, "end": 812.54, "word": " بقصدي", "probability": 0.86279296875}], "temperature": 1.0}, {"id": 34, "seek": 84521, "start": 816.07, "end": 845.21, "text": "الـ Markovnikov's product والـ Antimarkovnikov's product They are isomers ليش؟ لأنه نفس الذرات وحطيت H و OH حطيت ال H و OH بنفس المواقع ولا بمواقع مختلفة طالما مواقع مختلفة Different bonding عطول الجواب Structural isomers They are structural isomers", "tokens": [6027, 39184, 3934, 5179, 13123, 5179, 311, 1674, 16070, 39184, 5130, 332, 809, 5179, 13123, 5179, 311, 1674, 814, 366, 307, 298, 433, 32239, 8592, 22807, 5296, 33456, 3224, 8717, 36178, 32545, 2288, 9307, 4032, 5016, 9566, 36081, 389, 4032, 13931, 11331, 9566, 36081, 2423, 389, 4032, 13931, 4724, 1863, 36178, 9673, 14407, 4587, 3615, 49429, 4724, 2304, 14407, 4587, 3615, 3714, 46456, 46538, 3660, 23032, 6027, 15042, 3714, 14407, 4587, 3615, 3714, 46456, 46538, 3660, 20825, 28824, 6225, 9566, 12610, 25724, 14407, 3555, 745, 1757, 1807, 307, 298, 433, 814, 366, 15067, 307, 298, 433], "avg_logprob": -0.2139175208573489, "compression_ratio": 1.6650246305418719, "no_speech_prob": 0.0, "words": [{"start": 816.07, "end": 816.47, "word": "الـ", "probability": 0.435791015625}, {"start": 816.47, "end": 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825.25, "end": 826.05, "word": " وحطيت", "probability": 0.886474609375}, {"start": 826.05, "end": 826.35, "word": " H", "probability": 0.826171875}, {"start": 826.35, "end": 826.55, "word": " و", "probability": 0.87939453125}, {"start": 826.55, "end": 826.91, "word": " OH", "probability": 0.421875}, {"start": 826.91, "end": 827.67, "word": " حطيت", "probability": 0.8572591145833334}, {"start": 827.67, "end": 827.83, "word": " ال", "probability": 0.9208984375}, {"start": 827.83, "end": 828.05, "word": " H", "probability": 0.6318359375}, {"start": 828.05, "end": 828.25, "word": " و", "probability": 0.9892578125}, {"start": 828.25, "end": 828.43, "word": " OH", "probability": 0.83349609375}, {"start": 828.43, "end": 829.61, "word": " بنفس", "probability": 0.770751953125}, {"start": 829.61, "end": 830.39, "word": " المواقع", "probability": 0.9937744140625}, {"start": 830.39, "end": 830.61, "word": " ولا", "probability": 0.7607421875}, {"start": 830.61, "end": 831.25, "word": " بمواقع", "probability": 0.9884765625}, {"start": 831.25, "end": 832.25, "word": " مختلفة", "probability": 0.992919921875}, {"start": 832.25, "end": 833.97, "word": " طالما", "probability": 0.9108072916666666}, {"start": 833.97, "end": 834.77, "word": " مواقع", "probability": 0.9820556640625}, {"start": 834.77, "end": 835.71, "word": " مختلفة", "probability": 0.991455078125}, {"start": 835.71, "end": 836.41, "word": " Different", "probability": 0.349365234375}, {"start": 836.41, "end": 837.67, "word": " bonding", "probability": 0.83349609375}, {"start": 837.67, "end": 838.25, "word": " عطول", "probability": 0.6844889322916666}, {"start": 838.25, "end": 839.17, "word": " الجواب", "probability": 0.9793294270833334}, {"start": 839.17, "end": 840.91, "word": " Structural", "probability": 0.91748046875}, {"start": 840.91, "end": 842.89, "word": " isomers", "probability": 0.9661458333333334}, {"start": 842.89, "end": 843.47, "word": " They", "probability": 0.7275390625}, {"start": 843.47, "end": 843.65, "word": " are", "probability": 0.9521484375}, {"start": 843.65, "end": 844.29, "word": " structural", "probability": 0.87158203125}, {"start": 844.29, "end": 845.21, "word": " isomers", "probability": 0.9884440104166666}], "temperature": 1.0}, {"id": 35, "seek": 87125, "start": 845.79, "end": 871.25, "text": "مش فيها نقاش مش ارتبطوا الذرات من مواقع مختلفة هنا الهيدروجين على الأولى و ال OH على التانية هنا ال OH على الأولى و ال H على التانية صح ولا لأ different bonding different names structural isomers واضح إذا فكرة إضافة ال unsymmetrical agents ممكن تضيف", "tokens": [2304, 8592, 8978, 11296, 8717, 4587, 33599, 37893, 1975, 43500, 3555, 9566, 14407, 32545, 2288, 9307, 9154, 3714, 14407, 4587, 3615, 3714, 46456, 46538, 3660, 34105, 2423, 3224, 25708, 2288, 29245, 9957, 15844, 16247, 12610, 7578, 4032, 2423, 13931, 15844, 16712, 7649, 10632, 34105, 2423, 13931, 15844, 16247, 12610, 7578, 4032, 2423, 389, 15844, 16712, 7649, 10632, 20328, 5016, 49429, 5296, 10721, 819, 28824, 819, 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هيدروجين أكتر يعني بدى أحطها ناسيه H3 وH هدولة اللي كانوا أصلا وجدت بدى أحط ال H تحت", "tokens": [28814, 15730, 45164, 41850, 9122, 29399, 47525, 7578, 5551, 24793, 1211, 389, 15958, 8978, 49610, 23328, 389, 7721, 9122, 33911, 8608, 10721, 4117, 2655, 3555, 2423, 8315, 2655, 7435, 22807, 37495, 22653, 45164, 14739, 3224, 5551, 24793, 1211, 9673, 3615, 18513, 37977, 389, 15958, 389, 7721, 47525, 7578, 5551, 5016, 9566, 2423, 3224, 25708, 2288, 29245, 9957, 6225, 13672, 1829, 11331, 10943, 37977, 8032, 25708, 2288, 29245, 9957, 5551, 4117, 2655, 2288, 37495, 22653, 47525, 7578, 5551, 5016, 9566, 11296, 8717, 32277, 1829, 3224, 389, 18, 4032, 39, 8032, 3215, 12610, 3660, 13672, 1829, 25961, 14407, 5551, 9381, 15040, 49610, 3215, 2655, 47525, 7578, 5551, 5016, 9566, 2423, 389, 6055, 33753], "avg_logprob": -0.28348215110599995, "compression_ratio": 1.815, "no_speech_prob": 0.0, "words": [{"start": 1242.86, "end": 1243.32, "word": "إذا", "probability": 0.5987548828125}, {"start": 1243.32, 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"word": " ع", "probability": 0.30615234375}, {"start": 1257.06, "end": 1257.24, "word": " اللي", "probability": 0.6650390625}, {"start": 1257.24, "end": 1257.76, "word": " حاملة", "probability": 0.9236653645833334}, {"start": 1257.76, "end": 1259.4, "word": " هيدروجين", "probability": 0.7998046875}, {"start": 1259.4, "end": 1260.02, "word": " أكتر", "probability": 0.9267578125}, {"start": 1260.02, "end": 1260.7, "word": " يعني", "probability": 0.76708984375}, {"start": 1260.7, "end": 1260.88, "word": " بدى", "probability": 0.743408203125}, {"start": 1260.88, "end": 1261.22, "word": " أحطها", "probability": 0.954833984375}, {"start": 1261.22, "end": 1261.64, "word": " ناسيه", "probability": 0.63702392578125}, {"start": 1261.64, "end": 1262.36, "word": " H3", "probability": 0.5589599609375}, {"start": 1262.36, "end": 1264.06, "word": " وH", "probability": 0.74853515625}, {"start": 1264.06, "end": 1264.52, "word": " هدولة", "probability": 0.7674560546875}, {"start": 1264.52, "end": 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الذكي اللي سألته زملتكوا بس بدناش نطول فيه بيجعل جهتين مش فيها مشكلة بس في كل الأحوال على أي carbon إجت ال PR", "tokens": [3224, 1829, 11296, 23032, 3555, 3615, 995, 31439, 4032, 23557, 21136, 2304, 16606, 3714, 25720, 5296, 2655, 33753, 4032, 3714, 25720, 5296, 5172, 30543, 23758, 21136, 33604, 6027, 32545, 4117, 1829, 13672, 1829, 8608, 10721, 1211, 47395, 30767, 42213, 2655, 4117, 14407, 4724, 3794, 47525, 8315, 8592, 8717, 9566, 12610, 8978, 3224, 4724, 1829, 7435, 30241, 10874, 3224, 2655, 9957, 37893, 8978, 11296, 37893, 28820, 3660, 4724, 3794, 8978, 28242, 16247, 5016, 2407, 6027, 15844, 36632, 5954, 11933, 7435, 2655, 2423, 11568], "avg_logprob": -0.2016189823667687, "compression_ratio": 1.5888888888888888, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1295.85, "end": 1296.35, "word": "هيها", "probability": 0.6433919270833334}, {"start": 1296.35, "end": 1297.15, "word": " طبعا", "probability": 0.896728515625}, {"start": 1297.15, "end": 1297.25, "word": " هو", 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" في", "probability": 0.9169921875}, {"start": 1308.61, "end": 1308.79, "word": " كل", "probability": 0.9833984375}, {"start": 1308.79, "end": 1309.29, "word": " الأحوال", "probability": 0.987060546875}, {"start": 1309.29, "end": 1309.55, "word": " على", "probability": 0.81640625}, {"start": 1309.55, "end": 1309.95, "word": " أي", "probability": 0.8505859375}, {"start": 1309.95, "end": 1311.55, "word": " carbon", "probability": 0.58837890625}, {"start": 1311.55, "end": 1311.99, "word": " إجت", "probability": 0.7303059895833334}, {"start": 1311.99, "end": 1312.15, "word": " ال", "probability": 0.97216796875}, {"start": 1312.15, "end": 1312.47, "word": " PR", "probability": 0.61474609375}], "temperature": 1.0}, {"id": 55, "seek": 134122, "start": 1313.46, "end": 1341.22, "text": "على حملة الهيدروجين على أي كاربون إجت الهيدروجين على اللي أقل هذي Markov Nikov ولا أنت Markov Nikov؟ أنا مابديش ياكلتوه في الشكل فوق و تحت، حطوهم بس بالموقع الصح و غلط و مكفي، واضح؟ يعني لما بنكمل هذه المعادلة، 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الجديدة", "tokens": [21292, 7435, 1829, 8315, 39182, 29538, 33688, 11242, 31845, 3660, 11933, 11242, 31845, 3660, 10874, 16254, 41891, 29538, 33688, 11242, 31845, 3660, 25724, 16254, 41891], "avg_logprob": -0.19501201235331023, "compression_ratio": 1.4705882352941178, "no_speech_prob": 0.0, "words": [{"start": 1370.6, "end": 1371.48, "word": "بيجينا", "probability": 0.7560577392578125}, {"start": 1371.48, "end": 1372.8, "word": " بعد", "probability": 0.857421875}, {"start": 1372.8, "end": 1373.16, "word": " هذه", "probability": 0.8193359375}, {"start": 1373.16, "end": 1373.92, "word": " الإضافة", "probability": 0.9510498046875}, {"start": 1373.92, "end": 1374.66, "word": " إضافة", "probability": 0.9124755859375}, {"start": 1374.66, "end": 1375.34, "word": " جديدة", "probability": 0.98779296875}, {"start": 1375.34, "end": 1377.0, "word": " هذه", "probability": 0.3662109375}, {"start": 1377.0, "end": 1378.02, "word": " الإضافة", "probability": 0.98779296875}, {"start": 1378.02, "end": 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"start": 1761.43, "end": 1779.61, "text": "هي اللي شيلت هذه .. هذا أصلا كان هيك لما ضيفت عليه شيلت ال double bond و حطيت ال oxygen طب زي هيك إيش اسمه؟ Cyclohexane شيلنا هذه صار Cyclohexane oxide", "tokens": [3224, 1829, 13672, 1829, 13412, 26895, 2655, 29538, 4386, 23758, 5551, 9381, 15040, 25961, 39896, 4117, 5296, 15042, 48812, 33911, 2655, 47356, 13412, 26895, 2655, 2423, 3834, 6086, 4032, 11331, 9566, 36081, 2423, 9169, 23032, 3555, 30767, 1829, 39896, 4117, 11933, 1829, 8592, 24525, 2304, 3224, 22807, 10295, 66, 752, 675, 87, 1929, 13412, 26895, 8315, 29538, 20328, 9640, 10295, 66, 752, 675, 87, 1929, 28421], "avg_logprob": -0.21874999688632452, "compression_ratio": 1.3841463414634145, "no_speech_prob": 0.0, "words": [{"start": 1761.43, "end": 1761.75, "word": "هي", "probability": 0.43853759765625}, {"start": 1761.75, "end": 1761.85, "word": " اللي", "probability": 0.50347900390625}, {"start": 1761.85, "end": 1762.21, "word": " شيلت", "probability": 0.9285481770833334}, {"start": 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carbon موجب بناء على ذلك لو جبت من برا اش سالب يتفاعل وين هيروح يهجم على ال carbon هذا الاش السالب اللي انا بجيبه و بسميه ال eucleophile اكيد شيء عليه أزواج الإلكترونات هي سبب السالب", "tokens": [3224, 24192, 8717, 47432, 3660, 9122, 2655, 13546, 3714, 16095, 3660, 1975, 15730, 1975, 8315, 4724, 28543, 2288, 1975, 2655, 9778, 26895, 2423, 7649, 29538, 16472, 29538, 8608, 6027, 49401, 4032, 1975, 8315, 18871, 16254, 15844, 2423, 5954, 3714, 29245, 3555, 4032, 15844, 2423, 5954, 3714, 29245, 3555, 44945, 16606, 15844, 29910, 23275, 45164, 10874, 3555, 2655, 9154, 4724, 23557, 1975, 8592, 8608, 6027, 3555, 7251, 2655, 5172, 995, 30241, 4032, 9957, 39896, 32887, 5016, 7251, 3224, 7435, 2304, 15844, 2423, 5954, 23758, 2423, 33599, 21136, 6027, 3555, 13672, 1829, 1975, 8315, 4724, 7435, 1829, 3555, 3224, 4032, 4724, 38251, 1829, 3224, 2423, 2228, 2160, 49242, 1975, 4117, 25708, 44049, 38207, 47356, 5551, 11622, 2407, 26108, 33688, 23275, 2655, 2288, 11536, 9307, 39896, 8608, 3555, 3555, 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"start": 2375.39, "end": 2404.53, "text": "Electrophile والسالب ايش هنسميه النيوكليوفايل الان هنقول انه النيوكليوفايل بيهاجم على ال Electrophile بيعمل رابطة ممكن النيوكليوفايل يكون OH جاية من الميه او تيجي من الميه فلما ييجي هذا ال OH هنهيهاجم معقول يصيروا خمس روابط ولا هتكسر هذه الرابطة تكسر وتفتح هتتحول ال O هذه", "tokens": [36, 1809, 11741, 794, 16070, 3794, 6027, 3555, 1975, 1829, 8592, 8032, 1863, 38251, 1829, 3224, 2423, 22653, 2407, 28820, 1829, 38688, 995, 26895, 2423, 7649, 8032, 1863, 39648, 16472, 3224, 2423, 22653, 2407, 28820, 1829, 38688, 995, 26895, 4724, 1829, 3224, 26108, 2304, 15844, 2423, 12575, 11741, 794, 4724, 1829, 25957, 1211, 12602, 16758, 9566, 3660, 3714, 43020, 2423, 22653, 2407, 28820, 1829, 38688, 995, 26895, 7251, 30544, 13931, 10874, 995, 10632, 9154, 9673, 1829, 3224, 1975, 2407, 6055, 1829, 7435, 1829, 9154, 9673, 1829, 3224, 6156, 1211, 15042, 7251, 1829, 7435, 1829, 23758, 2423, 13931, 8032, 1863, 3224, 1829, 3224, 26108, 2304, 20449, 39648, 7251, 9381, 13546, 14407, 16490, 2304, 3794, 12602, 14407, 3555, 9566, 49429, 8032, 2655, 4117, 3794, 2288, 29538, 34892, 16758, 9566, 3660, 6055, 4117, 3794, 2288, 34683, 5172, 2655, 5016, 8032, 2655, 2655, 5016, 12610, 2423, 422, 29538], "avg_logprob": -0.1613146502396156, "compression_ratio": 2.1171171171171173, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2375.39, "end": 2376.67, "word": "Electrophile", "probability": 0.80718994140625}, {"start": 2376.67, "end": 2377.53, "word": " والسالب", "probability": 0.65399169921875}, {"start": 2377.53, "end": 2377.71, "word": " ايش", "probability": 0.6219889322916666}, {"start": 2377.71, "end": 2378.45, "word": " هنسميه", "probability": 0.89873046875}, {"start": 2378.45, "end": 2379.93, "word": " النيوكليوفايل", "probability": 0.69091796875}, {"start": 2379.93, "end": 2380.39, "word": " الان", "probability": 0.7252197265625}, {"start": 2380.39, "end": 2380.91, "word": " هنقول", "probability": 0.9612630208333334}, {"start": 2380.91, "end": 2381.55, "word": " انه", "probability": 0.741455078125}, {"start": 2381.55, "end": 2383.33, "word": " النيوكليوفايل", "probability": 0.9539794921875}, {"start": 2383.33, "end": 2384.71, "word": " بيهاجم", "probability": 0.946484375}, {"start": 2384.71, "end": 2385.23, "word": " على", "probability": 0.7705078125}, {"start": 2385.23, "end": 2386.23, "word": " ال", "probability": 0.96826171875}, {"start": 2386.23, "end": 2387.51, "word": " Electrophile", "probability": 0.724853515625}, {"start": 2387.51, "end": 2388.29, "word": " بيعمل", "probability": 0.924072265625}, {"start": 2388.29, "end": 2388.81, "word": " رابطة", "probability": 0.9307861328125}, {"start": 2388.81, "end": 2389.29, "word": " ممكن", "probability": 0.920166015625}, {"start": 2389.29, "end": 2390.17, "word": " النيوكليوفايل", "probability": 0.9556884765625}, {"start": 2390.17, "end": 2390.55, "word": " يكون", "probability": 0.974609375}, {"start": 2390.55, "end": 2391.49, "word": " OH", "probability": 0.7451171875}, {"start": 2391.49, "end": 2392.19, "word": " جاية", "probability": 0.9090169270833334}, {"start": 2392.19, "end": 2392.39, "word": " من", "probability": 0.9931640625}, {"start": 2392.39, "end": 2393.43, "word": " الميه", "probability": 0.8517252604166666}, {"start": 2393.43, "end": 2393.65, "word": " او", "probability": 0.896240234375}, {"start": 2393.65, "end": 2393.93, "word": " تيجي", "probability": 0.973876953125}, {"start": 2393.93, "end": 2394.09, "word": " من", "probability": 0.99365234375}, {"start": 2394.09, "end": 2394.53, "word": " الميه", "probability": 0.9908854166666666}, {"start": 2394.53, "end": 2395.13, "word": " فلما", "probability": 0.8282877604166666}, {"start": 2395.13, "end": 2395.47, "word": " ييجي", "probability": 0.8807373046875}, {"start": 2395.47, "end": 2395.65, "word": " هذا", "probability": 0.955078125}, {"start": 2395.65, "end": 2395.77, "word": " ال", "probability": 0.9833984375}, {"start": 2395.77, "end": 2396.03, "word": " OH", "probability": 0.50390625}, {"start": 2396.03, "end": 2397.45, "word": " هنهيهاجم", "probability": 0.8070591517857143}, {"start": 2397.45, "end": 2398.23, "word": " معقول", "probability": 0.80712890625}, {"start": 2398.23, "end": 2398.61, "word": " يصيروا", "probability": 0.967529296875}, {"start": 2398.61, "end": 2398.93, "word": " خمس", "probability": 0.9568684895833334}, {"start": 2398.93, "end": 2399.39, "word": " روابط", "probability": 0.96142578125}, {"start": 2399.39, "end": 2399.55, "word": " ولا", "probability": 0.8310546875}, {"start": 2399.55, "end": 2400.17, "word": " هتكسر", "probability": 0.98271484375}, {"start": 2400.17, "end": 2400.47, "word": " هذه", "probability": 0.8876953125}, {"start": 2400.47, "end": 2401.27, "word": " الرابطة", "probability": 0.8612060546875}, {"start": 2401.27, "end": 2401.99, "word": " تكسر", "probability": 0.9351806640625}, {"start": 2401.99, "end": 2402.55, "word": " وتفتح", "probability": 0.914794921875}, {"start": 2402.55, "end": 2403.75, "word": " هتتحول", "probability": 0.974609375}, {"start": 2403.75, "end": 2403.95, "word": " ال", "probability": 0.96630859375}, {"start": 2403.95, "end": 2404.13, "word": " O", "probability": 0.65283203125}, {"start": 2404.13, "end": 2404.53, "word": " هذه", "probability": 0.6845703125}], "temperature": 1.0}, {"id": 100, "seek": 242660, "start": 2405.38, "end": 2426.6, "text": "الى OH الان بهذه المنطقة راجعوا المرة اللى جايب ال road نبدأ من عند هذه النقطة لكن بتكونوا اتدربتوا اكتر و بنشرح كل الأمثلة ايش معنى Electrophile ايش معنى Nucleophile هات بتتدربوا عليها بنشوف كيف ال ring opening بيصير باكثر من مثل", "tokens": [6027, 7578, 13931, 2423, 7649, 4724, 3224, 24192, 9673, 1863, 9566, 28671, 12602, 26108, 3615, 14407, 9673, 25720, 13672, 7578, 10874, 47302, 3555, 2423, 3060, 8717, 44510, 10721, 9154, 43242, 29538, 28239, 47432, 3660, 44381, 39894, 30544, 14407, 1975, 2655, 3215, 25513, 2655, 14407, 1975, 4117, 2655, 2288, 4032, 44945, 46309, 5016, 28242, 16247, 2304, 12984, 37977, 1975, 1829, 8592, 20449, 1863, 7578, 12575, 11741, 794, 1975, 1829, 8592, 20449, 1863, 7578, 13612, 2160, 49242, 8032, 9307, 39894, 2655, 3215, 25513, 14407, 25894, 11296, 44945, 8592, 38688, 9122, 33911, 2423, 4875, 5193, 4724, 1829, 9381, 13546, 4724, 995, 4117, 49115, 9154, 50113, 1211], "avg_logprob": -0.26111779648524064, "compression_ratio": 1.7072072072072073, "no_speech_prob": 1.4901161193847656e-06, "words": [{"start": 2405.38, "end": 2405.86, "word": "الى", "probability": 0.254119873046875}, {"start": 2405.86, "end": 2407.12, "word": " OH", "probability": 0.63720703125}, {"start": 2407.12, "end": 2409.0, "word": " الان", "probability": 0.68798828125}, {"start": 2409.0, "end": 2410.14, "word": " بهذه", "probability": 0.4222819010416667}, {"start": 2410.14, "end": 2410.7, "word": " المنطقة", "probability": 0.9739990234375}, {"start": 2410.7, "end": 2411.42, "word": " راجعوا", "probability": 0.798095703125}, {"start": 2411.42, "end": 2411.84, "word": " المرة", "probability": 0.743896484375}, {"start": 2411.84, "end": 2411.98, "word": " اللى", "probability": 0.721923828125}, {"start": 2411.98, "end": 2412.22, "word": " جايب", "probability": 0.7332356770833334}, {"start": 2412.22, "end": 2412.3, "word": " ال", "probability": 0.85009765625}, {"start": 2412.3, "end": 2412.46, "word": " road", "probability": 0.2403564453125}, {"start": 2412.46, "end": 2412.82, "word": " نبدأ", "probability": 0.9303385416666666}, {"start": 2412.82, "end": 2412.96, "word": " من", "probability": 0.94677734375}, {"start": 2412.96, "end": 2413.22, "word": " عند", "probability": 0.8466796875}, {"start": 2413.22, "end": 2413.46, "word": " هذه", "probability": 0.59033203125}, {"start": 2413.46, "end": 2413.86, "word": " النقطة", "probability": 0.9736328125}, {"start": 2413.86, "end": 2414.1, "word": " لكن", "probability": 0.71630859375}, {"start": 2414.1, "end": 2414.64, "word": " بتكونوا", "probability": 0.8151041666666666}, {"start": 2414.64, "end": 2415.16, "word": " اتدربتوا", "probability": 0.87109375}, {"start": 2415.16, "end": 2415.6, "word": " اكتر", "probability": 0.9320068359375}, {"start": 2415.6, "end": 2415.78, "word": " و", "probability": 0.78564453125}, {"start": 2415.78, "end": 2416.18, "word": " بنشرح", "probability": 0.90478515625}, {"start": 2416.18, "end": 2416.4, "word": " كل", "probability": 0.9423828125}, {"start": 2416.4, "end": 2416.96, "word": " الأمثلة", "probability": 0.923583984375}, {"start": 2416.96, "end": 2417.52, "word": " ايش", "probability": 0.7747395833333334}, {"start": 2417.52, "end": 2418.04, "word": " معنى", "probability": 0.8243815104166666}, {"start": 2418.04, "end": 2419.78, "word": " Electrophile", "probability": 0.6597493489583334}, {"start": 2419.78, "end": 2420.06, "word": " ايش", "probability": 0.9158528645833334}, {"start": 2420.06, "end": 2420.34, "word": " معنى", "probability": 0.97705078125}, {"start": 2420.34, "end": 2420.94, "word": " Nucleophile", "probability": 0.68310546875}, {"start": 2420.94, "end": 2421.12, "word": " هات", "probability": 0.3155517578125}, {"start": 2421.12, "end": 2421.64, "word": " بتتدربوا", "probability": 0.861865234375}, {"start": 2421.64, "end": 2422.04, "word": " عليها", "probability": 0.985595703125}, {"start": 2422.04, "end": 2422.84, "word": " بنشوف", "probability": 0.9505208333333334}, {"start": 2422.84, "end": 2423.12, "word": " كيف", "probability": 0.96435546875}, {"start": 2423.12, "end": 2423.24, "word": " ال", "probability": 0.95751953125}, {"start": 2423.24, "end": 2423.48, "word": " ring", "probability": 0.8955078125}, {"start": 2423.48, "end": 2423.98, "word": " opening", "probability": 0.84375}, {"start": 2423.98, "end": 2424.68, "word": " بيصير", "probability": 0.964599609375}, {"start": 2424.68, "end": 2425.9, "word": " باكثر", "probability": 0.825927734375}, {"start": 2425.9, "end": 2426.1, "word": " من", "probability": 0.99169921875}, {"start": 2426.1, "end": 2426.6, "word": " مثل", "probability": 0.7705078125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2427.7855, "duration_after_vad": 2323.9356249999914}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/z4_9i2lZ2eY.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/z4_9i2lZ2eY.srt
new file mode 100644
index 0000000000000000000000000000000000000000..be70d2826b3d6e1c444ea39e30b2781acf31453f
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/z4_9i2lZ2eY.srt
@@ -0,0 +1,1613 @@
+1
+00:00:21,140 --> 00:00:26,480
+بسم الله الرحمن الرحيم. المرة الماضية بدأنا في
+
+2
+00:00:26,480 --> 00:00:32,300
+الفصل الثالث في الكيمياء العضوية، اللي هو بعنوان الـ
+
+3
+00:00:32,300 --> 00:00:37,500
+alkenes and alkynes. طبعاً بشكل أساسي، تعرّفنا على
+
+4
+00:00:37,500 --> 00:00:42,020
+خواص الروابط الأحادية، الثنائية، والثلاثية، وأخذنا
+
+5
+00:00:42,020 --> 00:00:46,840
+تسمية الـ alkenes والـ alkynes، وركزنا على فكرة
+
+6
+00:00:47,640 --> 00:00:53,300
+موجودة كثيراً في هذا المجال، هي فكرة وجود الـ stereo
+
+7
+00:00:53,300 --> 00:00:57,700
+isomers، تحديدا الـ cis والـ trans، اللي قلنا عنهم
+
+8
+00:00:57,700 --> 00:01:00,780
+هدول عبارة عن diastereomers.
+
+9
+00:01:03,880 --> 00:01:08,860
+كمُتداد بسيط فقط لفكرة الـ cis والـ trans، احنا قلنا
+
+10
+00:01:08,860 --> 00:01:12,940
+بيكون عندنا موجود cis أو trans سواء حول الـ double
+
+11
+00:01:12,940 --> 00:01:17,340
+bond أو حول الـ single bond في حلقة، إذا كان في عندي
+
+12
+00:01:17,340 --> 00:01:21,380
+على كل ذرة كربون من الذرات المعنية، مجموعتين
+
+13
+00:01:21,380 --> 00:01:26,500
+مختلفتين، بقدر أقول cis و trans، يعني المركب بيكون
+
+14
+00:01:26,500 --> 00:01:33,310
+فيه منه اثنين. الآن، لو أخذنا مثالاً جديداً، هذا
+
+15
+00:01:33,310 --> 00:01:39,310
+المثال، هي double bond وهي carbon وهي carbon، هل هنا
+
+16
+00:01:39,310 --> 00:01:43,250
+في عندي مجموعتين مختلفتين ولا لأ؟ عندي مجموعتين
+
+17
+00:01:43,250 --> 00:01:47,910
+مختلفتين، هل هنا في عندي مجموعتين مختلفتين ولا لأ؟
+
+18
+00:01:47,910 --> 00:01:52,230
+في عندي مجموعتين مختلفتين، إذا هذا المركب فيه منه
+
+19
+00:01:52,230 --> 00:01:57,130
+مركب واحد ولا اثنين؟ فيه منه مركبين. لو بدي المركب
+
+20
+00:01:57,130 --> 00:02:02,650
+الثاني، بثبت إحداهما، وبعكس الثانية. يعني
+
+21
+00:02:02,650 --> 00:02:06,990
+لاحظوا هذا المركب نفسه، رسمناها، خلينا على سبيل
+
+22
+00:02:06,990 --> 00:02:12,190
+المثال اليود والكلور زي ما هما، عكسنا مجموعة الميثيل
+
+23
+00:02:12,190 --> 00:02:16,170
+لتحت، الـ Br لفوق، خلينا الـ Br لتحت، الميثيل لفوق. هاي
+
+24
+00:02:16,170 --> 00:02:22,320
+المركب الثاني، واضح؟ ولو هذا المركب، احنا بدنا نسميه،
+
+25
+00:02:22,320 --> 00:02:28,540
+مش صعب علينا نسميه، كمواقع ذرات، كمواقع ذرات carbon
+
+26
+00:02:28,540 --> 00:02:34,400
+اثنين، ثلاثة، أطول سلسلة، إذا هذا المركب، أي مركب
+
+27
+00:02:34,400 --> 00:02:44,250
+بروبان. هذا المركب حامل يود وبروم وكلور، بدنا
+
+28
+00:02:44,250 --> 00:02:47,990
+نذكرهم alphabetically. لاحظوا ما أحد يقول إنه حامل
+
+29
+00:02:47,990 --> 00:02:53,430
+ميثيل، الميثيل جزء من السلسلة الطويلة، هو حامل ثلاثة
+
+30
+00:02:53,430 --> 00:02:56,410
+substituents، يود وبروم وكلور، لما نذكرهم
+
+31
+00:02:56,410 --> 00:03:00,870
+alphabetically، two bromo, one chloro, one iodo,
+
+32
+00:03:01,090 --> 00:03:06,750
+one propane. لكن، ضلت المشكلة، هل يا ترى هذا المركب
+
+33
+00:03:06,750 --> 00:03:12,470
+cis ولا trans؟ اللي بتيجي تفكر بالعلم البسيط اللي
+
+34
+00:03:12,470 --> 00:03:18,050
+اتعلمته، هتفكر بالغلط، إنه احنا قلنا إذا في عندي
+
+35
+00:03:18,050 --> 00:03:21,430
+مثلاً مجموعتين زي بعض، كنا نقول كلور وكلور،  عجية
+
+36
+00:03:21,430 --> 00:03:26,130
+واحدة cis،  مجموعتين متعاكسات trans. لكن الحمد لله، هذا
+
+37
+00:03:26,130 --> 00:03:33,460
+المركب فيه أربع مجموعات مختلفة، وبناءً على ذلك، رغم أن
+
+38
+00:03:33,460 --> 00:03:36,580
+انتم قادرين تقولوا إنه منه two compounds، two
+
+39
+00:03:36,580 --> 00:03:39,720
+stereoisomers، بس ولا واحدة قادرة تقول cis ولا
+
+40
+00:03:39,720 --> 00:03:44,900
+trans، تمام؟ الحقيقة الظاهرة هنا شوية أكبر من الـ cis
+
+41
+00:03:44,900 --> 00:03:49,660
+والـ trans، لما نيجي نحلها، بنحلها بالشكل التالي،
+
+42
+00:03:49,660 --> 00:03:53,980
+بنسأل أنفسنا، بنقول بدنا نقارن هذه الذرة وهذه
+
+43
+00:03:53,980 --> 00:04:00,320
+الذرة، يود وكلور، هدول مختلفتان، مين فيهم لها
+
+44
+00:04:00,320 --> 00:04:05,880
+atomic number أعلى؟ واضح؟ طبعاً ما بدي أحد يقول مرة
+
+45
+00:04:05,880 --> 00:04:08,840
+ثانية، مش حافظ الجدول الدوري، أنا ما بدي الـ atomic
+
+46
+00:04:08,840 --> 00:04:15,380
+number، أنا بدي مقارنة، والمقارنة الأصلية معروفة، معروفة
+
+47
+00:04:15,380 --> 00:04:18,740
+جزء من الجدول الدوري، مئة مرة حكينا اللي فيه carbon,
+
+48
+00:04:18,960 --> 00:04:22,160
+nitrogen, oxygen, fluorine, chlorine, bromine,
+
+49
+00:04:22,160 --> 00:04:26,200
+iodine, sulfur. هذه أعلى من هذه، أعلى من هذه، أعلى من
+
+50
+00:04:26,200 --> 00:04:30,350
+هذه، أعلى من هذه، أعلى من هذه، أعلى من هذه، واضح؟ هذا
+
+51
+00:04:30,350 --> 00:04:34,670
+الكلام معروف. إذا لما أنا بدي أقارن يود مع كلور، مين
+
+52
+00:04:34,670 --> 00:04:39,890
+الأعلى؟ اليود، ممتازة، في الـ atomic number. لما بدي
+
+53
+00:04:39,890 --> 00:04:45,150
+أقارن بروم مع كربون، اطلع ذرة بذرة، ما بدي أقول مع الـ
+
+54
+00:04:45,150 --> 00:04:48,550
+CH3، لأ، مع الذرة المتصلة مباشرة، مع أي ذرة متصلة
+
+55
+00:04:48,550 --> 00:04:53,090
+مباشرة بالـ double bond، كربون، الذرة هنا بروم، مين
+
+56
+00:04:53,090 --> 00:04:58,510
+أعلى؟ بروم ولا كربون؟ أكيد البروم، الآن هذه الأعلى، و
+
+57
+00:04:58,510 --> 00:05:03,350
+هذه الأعلى، اجوا على جهة واحدة، في هذه الحالة كأني
+
+58
+00:05:03,350 --> 00:05:09,210
+بتخيل إنه المركب إيش؟ cis، لو إجيت هنا يود وكلور،
+
+59
+00:05:09,210 --> 00:05:17,270
+اليود أعلى، بروم وكربون، البروم أعلى، بناءً على ذلك
+
+60
+00:05:17,270 --> 00:05:23,790
+المجموعات الأعلى أتوا على جهتين متعاكستين، كأن هذا
+
+61
+00:05:23,790 --> 00:05:30,070
+المركب trans. لكن الحقيقة هنا، جرت العادة أننا
+
+62
+00:05:30,070 --> 00:05:37,150
+ما نستعملش مصطلح cis و trans، لأ، بنستعمل بديلاً له،
+
+63
+00:05:37,150 --> 00:05:43,510
+الـ cis والـ trans، عادة تُستعمل للمركبات البسيطة
+
+64
+00:05:43,510 --> 00:05:50,170
+الواضحة، اللي عمل هذه القواعد إنسان لغته، لغته
+
+65
+00:05:50,170 --> 00:05:55,170
+ألمانية، احنا بالعربي كنا نستعمل بدل cis و trans
+
+66
+00:05:55,170 --> 00:06:04,930
+مع وضد. الإنجليز cis و trans، الآن هو ألماني، مش أقل
+
+67
+00:06:04,930 --> 00:06:09,680
+منه، قال لأ أنا بدي أجيب من اللغة الألمانية، إيش معنى
+
+68
+00:06:09,680 --> 00:06:14,400
+مع، وإيش معنى ضد؟ يعني البادئة، تبقى... البادئة
+
+69
+00:06:14,400 --> 00:06:17,960
+بأخذها من اللغة الألمانية، فباللغة الألمانية مع،
+
+70
+00:06:17,960 --> 00:06:25,940
+اللي هي together، it's zusammen، zusammen، بالـ z و
+
+71
+00:06:25,940 --> 00:06:31,600
+zusammen. الآن جال من zusammen، بدي آخذ حرف الـ Z، فالـ Z
+
+72
+00:06:31,600 --> 00:06:38,080
+هذه صارت موازية للـ cis اللي بالإنجليزية، ولكلمة مع
+
+73
+00:06:38,080 --> 00:06:46,480
+اللي احنا بنستعملها بالعربي، واضح؟ فـ Z بمعنى cis من
+
+74
+00:06:46,480 --> 00:06:51,940
+ناحية المعنى، أو مع. الآن إيش معنى ضد؟ برضه راح
+
+75
+00:06:51,940 --> 00:06:59,280
+على اللغة تبعته،  entgegen. entgegen، أخذ منها حرف إيش؟
+
+76
+00:07:00,080 --> 00:07:06,360
+entgegen، أخذ منها حرف الـ E، فالـ E هذه صارت بمعنى
+
+77
+00:07:06,360 --> 00:07:12,040
+trans، أو بمعنى ضد، للناس اللي بيكتبوا باللغة
+
+78
+00:07:12,040 --> 00:07:17,620
+العربية، واضح؟ طبعاً البعض هيقول، طب احنا وقتاش نكتب
+
+79
+00:07:17,620 --> 00:07:23,580
+cis و trans، ووقتاش نكتب Z و E؟ بنقول في المركبات
+
+80
+00:07:23,580 --> 00:07:30,440
+البسيطة الواضحة بنكتب cis و trans، في المركبات
+
+81
+00:07:30,440 --> 00:07:34,680
+اللي فيها أكثر من مجموعة، وبنتغلب ونحسب الـ atomic
+
+82
+00:07:34,680 --> 00:07:41,520
+number، بنكتب Z و E. بالمناسبة، هل هذه القواعد اللي
+
+83
+00:07:41,520 --> 00:07:47,160
+هي ترتيب المجموعات حسب الـ atomic number جديدة؟ لأ.
+
+84
+00:07:47,160 --> 00:07:51,020
+يعني لو أنا أخذت نفس المركب البسيط اللي كنت
+
+85
+00:07:51,020 --> 00:07:59,810
+أحكيه، Cl Cl H H، هذا المركب عارفينه ولا لأ؟ واضح؟
+
+86
+00:07:59,810 --> 00:08:04,230
+الآن، لو أتيت، سؤالك Cl أو H؟ مين أعلى في الـ atomic
+
+87
+00:08:04,230 --> 00:08:10,650
+number؟ Cl، Cl و H، هاي مختلفتان، وهاي مختلفتان، مين
+
+88
+00:08:10,650 --> 00:08:13,550
+أعلى في الـ atomic number؟ اللي أعلى في الـ atomic
+
+89
+00:08:13,550 --> 00:08:19,270
+number على جهة واحدة، إذا هذا المركب Z، بس لأنه بسيط
+
+90
+00:08:19,270 --> 00:08:24,530
+ومبين بالنظر، استعمالنا له مصطلح إيش؟ cis، واضح؟ و
+
+91
+00:08:24,530 --> 00:08:30,310
+لذلك مش غلط كبير إنه مرات بتلاقوا بعض الناس بدل
+
+92
+00:08:30,310 --> 00:08:35,840
+كلمة cis بيكتبوا Z، أو بدل Z بيكتبوا cis. يعني، لكن
+
+93
+00:08:35,840 --> 00:08:39,540
+لما أنتم بدكم شبه قاعدة عامة، بنقول إذا المركبات
+
+94
+00:08:39,540 --> 00:08:42,980
+بسيطة، في الغالب هتلاقوا الكتب كاتبة معها مصطلحات
+
+95
+00:08:42,980 --> 00:08:48,080
+cis و trans. إذا شوية أصعب، هتلاقوا الكتب كاتبة معها
+
+96
+00:08:48,080 --> 00:08:53,360
+مصطلحات Z و E، واضح؟ فقط لغاية
+
+97
+00:08:57,330 --> 00:09:03,570
+الآن، هذه القواعد عادة بيسموها Cahn–Ingold–Prelog
+
+98
+00:09:03,570 --> 00:09:08,050
+Rules، اللي هي قواعد ترتيب المجموعات حسب الأعلى في
+
+99
+00:09:08,050 --> 00:09:11,610
+الـ atomic number، هتعود تلزمنا في الـ stereo
+
+100
+00:09:11,610 --> 00:09:16,430
+chemistry، وبنكتب اسمها الآن، مش مستعجلين عليه، خلينا
+
+101
+00:09:16,430 --> 00:09:22,090
+ناخذها ببساطة، قواعد ترتيب المجموعات حسب الـ atomic
+
+102
+00:09:22,090 --> 00:09:27,030
+number. أحياناً بيجي نحل مشكلتنا، نشوف مين
+
+103
+00:09:27,030 --> 00:09:31,190
+أعلى في الـ atomic number، هنا سهل جداً، يود ولا Cl؟
+
+104
+00:09:31,190 --> 00:09:37,910
+يود. أحياناً بيلاقوا الذرتين زي بعض، وجدتها
+
+105
+00:09:37,910 --> 00:09:44,390
+بيروح للذرة اللي بعدهم،  لو هي زي بعض، بنروح للبعدها،
+
+106
+00:09:44,390 --> 00:09:49,610
+لحد ما نصل لأول اختلاف، بيخلي مجموعة أعلى من
+
+107
+00:09:49,610 --> 00:09:54,090
+الثانية، واضح؟ يعني مثلاً هذا المركب، لو كنتوا بتطلعوا
+
+108
+00:09:54,090 --> 00:09:59,950
+عليه، هاي كربون، شو المجموعات اللي عليها؟ CH3، CH2،
+
+109
+00:09:59,950 --> 00:10:06,530
+CH3، لو إجينا نسأل مين أعلى؟ هدول مختلفات، هنا كربون،
+
+110
+00:10:07,430 --> 00:10:14,550
+وهنا كربون، زي بعض، وقتها أروح للذرة الثانية، لو بدكم
+
+111
+00:10:14,550 --> 00:10:20,430
+بالتفصيل الممل، أكيد هتقولوا أن هنا في عندي H و H، و
+
+112
+00:10:20,430 --> 00:10:31,390
+بعدها كربون، هذه H و H، وبعدها H، فلو إجيتوا تقارنوا
+
+113
+00:10:31,390 --> 00:10:38,490
+C وحاملة كل هذا زي بعضه، C وحاملة، وين أول اختلاف؟ نمرّة
+
+114
+00:10:38,490 --> 00:10:43,810
+اثنين كربون، نمرّة اثنين H، إذا من المجموعة الأعلى
+
+115
+00:10:43,810 --> 00:10:50,010
+صفّيات؟ فأنا لما بمشي بالمجموعات بالترتيب، يعني
+
+116
+00:10:50,010 --> 00:10:53,090
+الذرة الأولى ما حلتش المشكلة عند ما قالت لي مين
+
+117
+00:10:53,090 --> 00:10:57,330
+أعلى في الـ atomic number، بروح لإيش؟ للي بعدها، أول
+
+118
+00:10:57,330 --> 00:11:01,370
+ذرة بتعمل الفرق، هي اللي بتحدد هل هذه المجموعة أعلى
+
+119
+00:11:01,370 --> 00:11:05,050
+وهذه. مع الخبرة، بيصير سهل عليكم إنه لو بتشوفوا زي
+
+120
+00:11:05,050 --> 00:11:09,090
+إيثيل وميثيل، إنه بتلقائي تقولوا الإيثيل بدون ما تقعدوا
+
+121
+00:11:09,090 --> 00:11:14,110
+تعملوا كل هالتحليل، لكن القاعدة العامة ذرة بذرة
+
+122
+00:11:14,110 --> 00:11:14,950
+بنكون ماشيين.
+
+123
+00:11:17,660 --> 00:11:24,700
+إنجليزي، حالك صعب أني أعيد كتاب، واضح؟ ولذلك، هذه
+
+124
+00:11:24,700 --> 00:11:30,040
+الإيثيل صارت أعلى من الميثيل. الآن، هنحطّين مركب أو
+
+125
+00:11:30,040 --> 00:11:37,260
+مجموعتين شوية كبار، لاحظوا كربون وكربون، زي بعض، هذه
+
+126
+00:11:37,260 --> 00:11:42,740
+كربون، وهذه الذرة كربون. الآن هذه الكربون متصلة
+
+127
+00:11:42,740 --> 00:11:47,700
+بـ CH3، وهذه الكربون متصلة بـ CH3، كل ما هو مشترك
+
+128
+00:11:47,700 --> 00:11:51,480
+لن يحدد الفرق، شو اللي بده يحدد الفرق؟ شيء مختلف.
+
+129
+00:11:51,480 --> 00:11:57,440
+الآن، بعد هيك، هذه متصلة برابطة واحدة مع الـ O، هذه
+
+130
+00:11:57,440 --> 00:12:02,190
+متصلة بكم رابطة مع الـ O؟ برابطة ثانية. يعني كأنه هذه
+
+131
+00:12:02,190 --> 00:12:06,910
+متصلة بـ O، وهذه متصلة بـ O، اتفقنا؟ طب الرابطة الرابعة
+
+132
+00:12:06,910 --> 00:12:14,480
+هنا H، هنا O، اكتبوا معي، عاملوا هذه كإنها رابطتين مع
+
+133
+00:12:14,480 --> 00:12:18,080
+O، وهذه كإنها رابطة واحدة، يعني لو جيت سألت الأربع روابط
+
+134
+00:12:18,080 --> 00:12:24,980
+اللي على الكربون، واحدة مع CH3، مع CH3، مع O، مع O
+
+135
+00:12:24,980 --> 00:12:29,640
+مع الكربون هذه، مع الكربون هذه، إيش ضال؟ الرابعة
+
+136
+00:12:29,640 --> 00:12:36,620
+مع H، الرابعة مع O، الرابطة الثانية، أنه أعلى، ولذلك
+
+137
+00:12:36,620 --> 00:12:41,900
+كل المجموعة هذه صارت أعلى، واضح؟ فأنا بالتدريج بقدر
+
+138
+00:12:41,900 --> 00:12:45,300
+أحل المشاكل. الآن هذولا المجموعتين العليا على جهة
+
+139
+00:12:45,300 --> 00:12:52,100
+واحدة، إذا هذا المركب إيش؟ Z، واضح؟ هاي مركب ثالث،
+
+140
+00:12:52,100 --> 00:12:58,940
+هاي عندكم يود وكلور، هذه الحالة السهلة، من أعلى الـ
+
+141
+00:12:58,940 --> 00:13:05,040
+يود أعلى من الكلور، okay. الآن هنا عندك كربون و
+
+142
+00:13:05,040 --> 00:13:07,100
+كربون.
+
+143
+00:13:09,230 --> 00:13:13,670
+الذرتين زي بعض، طالما زي بعض، بتطلع على الذرات اللي
+
+144
+00:13:13,670 --> 00:13:18,610
+بعدهم، هذه الكربون متصلة بكربون، الرابطة الأولى،
+
+145
+00:13:18,610 --> 00:13:24,090
+والرابطة الثانية بكربون، والثالثة بـ H، يعني لو
+
+146
+00:13:24,090 --> 00:13:29,570
+جيتوا للتلات روابط بتوعها، كربون كربون H، تعالوا
+
+147
+00:13:29,570 --> 00:13:36,410
+على هذه، كربون كربون كربون. إذا مين أعلى؟ شوفنا
+
+148
+00:13:36,410 --> 00:13:40,490
+واحدة، افرجتهم، فبيصير كل هذه المجموعة أعلى، ولذلك هذا
+
+149
+00:13:40,490 --> 00:13:46,770
+المركب Z. الآن بالتدريب، بإمكانكم تتعودوا من خلال
+
+150
+00:13:46,770 --> 00:13:51,030
+حل أسئلة امتحانات سابقة، أو أمثلة، تلاحظوا وتميزوا
+
+151
+00:13:51,030 --> 00:13:54,570
+المركبات اللي فيها Z و E. لكن في كل الأحوال، إذا
+
+152
+00:13:54,570 --> 00:13:59,630
+إجاكم تسمية الـ alkene، إذا إجاكم تسمية الـ alkene، بتكونوا
+
+153
+00:13:59,630 --> 00:14:03,170
+تتطلعوا على أطراف الـ double bond اللي موجودة فيه،
+
+154
+00:14:03,170 --> 00:14:06,990
+إذا عليها مجموعات مختلفة، ومجموعات مختلفة، يجب أن
+
+155
+00:14:06,990 --> 00:14:12,950
+يوجد في التسمية Z أو E، وإذا كان الأمر بسيط جداً،
+
+156
+00:14:12,950 --> 00:14:18,650
+ممكن تكتبوا cis و trans، واضح؟ ممكن تكتبوا cis
+
+157
+00:14:18,650 --> 00:14:23,630
+و trans، هذا بالنسبة لاستعمال البادئة Z و E.
+
+158
+00:14:26,930 --> 00:14:32,890
+الآن بننتقل لموضوع جديد، اللي هو تفاعلات الـ alkenes.
+
+159
+00:14:32,890 --> 00:14:39,090
+الـ alkenes، اللي هم تفاعل أساسي، هتلاحظوا إنه بيتكرر
+
+160
+00:14:39,090 --> 00:14:44,470
+عندي كثيراً، هذا التفاعل الأساسي اللي للـ alkenes، بسميه أنا
+
+161
+00:14:44,470 --> 00:14:50,450
+addition reaction، addition، تفاعل إيش؟ الإضافة.
+
+162
+00:14:50,860 --> 00:14:55,580
+إيش هو باختصار تفاعل الإضافة؟ باختصار إنه بيكون
+
+163
+00:14:55,580 --> 00:15:00,650
+عندي carbon، double bond، carbon، هاي الـ double bond
+
+164
+00:15:00,650 --> 00:15:05,250
+يعني بركز تفاعلي وين؟ على الـ double bond. لما آجي أضيف
+
+165
+00:15:05,250 --> 00:15:10,250
+عليها أي reagent، زي خلينا هيك نأخذه بشكل عام، HX،
+
+166
+00:15:10,250 --> 00:15:14,810
+بيصير carbon، single bond، carbon. لاحظوا الـ double
+
+167
+
+223
+00:20:46,720 --> 00:20:55,920
+ناتجين، معدّ ذلك، فيطلع عندي ناتج واحد. خلينا نبدأ
+
+224
+00:20:55,920 --> 00:21:02,300
+نشوف أمثلة على الحالات اللي بنضيف فيها أحد الأطراف
+
+225
+00:21:02,300 --> 00:21:06,820
+symmetric، قد إيش هيطلع عندنا؟ ناتج واحد، بعدها
+
+226
+00:21:06,820 --> 00:21:12,020
+بننتقل إلى unsymmetric مع unsymmetric وبنشوف
+
+227
+00:21:12,020 --> 00:21:15,740
+ناتجين، نمشي الآن مع الـ slides
+
+228
+00:21:26,510 --> 00:21:32,170
+هذه أول تفاعل لو إحنا يا ترى بدنا نضيف الهيدروجين
+
+229
+00:21:32,170 --> 00:21:37,110
+الهيدروجين symmetric ولا unsymmetric؟ symmetric، إذًا كم
+
+230
+00:21:37,110 --> 00:21:41,410
+ناتج بتوقع يطلع عندنا؟ ناتج واحد، أيًا كان الـ alkene
+
+231
+00:21:41,410 --> 00:21:44,570
+سواء كان هذا الـ alkene symmetric أو unsymmetric، طالما
+
+232
+00:21:44,570 --> 00:21:50,450
+الهيدروجين متماثل، إذًا اللي هيطلع عندنا ناتج واحد
+
+233
+00:21:50,450 --> 00:21:54,930
+الآن لو بدنا نكتب هذا الناتج، بدنا نضيف هيدروجين
+
+234
+00:21:54,930 --> 00:22:02,870
+وهيدروجين، واضح؟ انتهى الجواب، هذا الـ alkene ضفنا عليه جزء
+
+235
+00:22:02,870 --> 00:22:07,010
+الهيدروجين، حط هيدروجين هنا وهيدروجين هنا، صار الـ alkene
+
+236
+00:22:07,960 --> 00:22:13,200
+الـ alkene بإضافة الهيدروجين صار عبارة عن ألكان
+
+237
+00:22:13,200 --> 00:22:16,460
+الهيدروجين
+
+238
+00:22:16,460 --> 00:22:22,080
+هنا بنضيف معلومة صغيرة أنه لما بيضيف، بيضيف من جهة
+
+239
+00:22:22,080 --> 00:22:25,980
+واحدة، يعني ما بتيجي ذرة هيدروجين من فوق وذرة
+
+240
+00:22:25,980 --> 00:22:30,190
+هيدروجين من تحت، لا، الذرتين الهيدروجين بيجوا من
+
+241
+00:22:30,190 --> 00:22:34,610
+جهة واحدة، يعني بهذا الشكل، زي ما تتخيلوا أنه أنا
+
+242
+00:22:34,610 --> 00:22:38,710
+الآن ماسك جزء الهيدروجين هذا، قاعد بضيفه نفترض هنا
+
+243
+00:22:38,710 --> 00:22:44,370
+double bond، الذرتين اجوا على الجهة هذه، ما بيجوش من جهات
+
+244
+00:22:44,370 --> 00:22:48,990
+متعاكسة، الآن هذه الإضافة اللي من جهة واحدة أنا
+
+245
+00:22:48,990 --> 00:22:53,630
+بسميها syn addition، لو كان بضيف من جهتين عكس بعض
+
+246
+00:22:53,630 --> 00:22:57,890
+بسميها إيش؟ anti addition، فالـهيدروجين هنا إيش نوع
+
+247
+00:22:57,890 --> 00:23:03,230
+الإضافة اللي بعملها؟ syn addition، معنى syn addition
+
+248
+00:23:03,230 --> 00:23:09,360
+أنه بضيف من جهة واحدة، واضح؟ معنى syn addition أنه
+
+249
+00:23:09,360 --> 00:23:15,160
+بيضيف من جهة واحدة، ممكن نعطي تفسير سريع ليش
+
+250
+00:23:15,160 --> 00:23:19,360
+الهيدروجين بيضيف من جهة واحدة، لو بتطلعوا بالانتباه
+
+251
+00:23:19,360 --> 00:23:25,260
+هذا التفاعل بتم من خلال إضافة غاز الهيدروجين في
+
+252
+00:23:25,260 --> 00:23:30,660
+وجود معدن، هذا المعدن غالبًا بنستعمل بلاتين، قطع من
+
+253
+00:23:30,660 --> 00:23:37,380
+المعدن الصغيرة، بلاتين، ممكن نستعمل معدن ثاني، ممكن
+
+254
+00:23:37,380 --> 00:23:42,820
+نستعمل بلاديوم، ممكن نستعمل nickel، وعشان هيك مرات
+
+255
+00:23:42,820 --> 00:23:48,340
+بتلاحظوا مكتوب عندكم إيش؟ M، إيش يعني M هنا؟ metal
+
+256
+00:23:48,340 --> 00:23:55,460
+في وجود metal catalyst، هذا عامل حفاز، catalyst، M
+
+257
+00:23:55,460 --> 00:24:01,940
+يعني metal catalyst، إيش catalyst؟ عامل حفاز، عامل حفاز
+
+258
+00:24:01,940 --> 00:24:06,100
+الآن هذا الـ catalyst ممكن يكون platinum، ممكن يكون
+
+259
+00:24:06,100 --> 00:24:11,140
+palladium، ممكن يكون nickel، واضح؟ هذا بيخلي التفاعل
+
+260
+00:24:11,140 --> 00:24:16,860
+يمشي بشكل سريع، طيب إيش بيعمل هذا الـ catalyst؟ هذا
+
+261
+00:24:16,860 --> 00:24:21,180
+الـ catalyst يلتصق بالهيدروجين على سطحه، يعني تخيلوا
+
+262
+00:24:21,180 --> 00:24:27,310
+هذا هو الـ catalyst، هذا سطح معدن، هو الـ catalyst، الآن
+
+263
+00:24:27,310 --> 00:24:32,030
+الهيدروجين كجزء بيجي يلتصق على سطح الـ catalyst
+
+264
+00:24:32,030 --> 00:24:37,870
+طالما يلتصق على سطح الـ catalyst بهذا الشكل، لما
+
+265
+00:24:37,870 --> 00:24:42,370
+بيجي يضيف على double bond، هاي double bond شايفينها؟
+
+266
+00:24:42,370 --> 00:24:47,170
+هل ممكن وهو ملتصق أنه يضيف من جهتين؟ لأ، بيجي زي هيك
+
+267
+00:24:47,170 --> 00:24:56,280
+زي هيك، وبيترك، الـ metal كان ممسوك بالـ metal جزء الهيدروجين
+
+268
+00:25:00,170 --> 00:25:05,170
+ضاف بهذا الشكل، وبناءً على ذلك ضاف من جهة واحدة
+
+269
+00:25:05,170 --> 00:25:11,170
+فبنقول إحنا أن الـ hydrogen gas adsorbs to the
+
+270
+00:25:11,170 --> 00:25:15,510
+metal surface، لاحظوا، تتذكروا معنا كلمة adsorption؟
+
+271
+00:25:15,510 --> 00:25:22,070
+adsorption شو معناها؟ التصاق على السطح، ما بدي أسمع
+
+272
+00:25:22,070 --> 00:25:29,510
+كلمة امتصاص، كلمة امتصاص absorption بالعربي شو
+
+273
+00:25:29,510 --> 00:25:33,830
+بنقولها؟ absorption، أدمصاص
+
+274
+00:25:33,830 --> 00:25:39,170
+بالدلالة، لاحظوا عندكم مصطلحين، عندكم مصطلحين، يعني
+
+275
+00:25:39,170 --> 00:25:44,070
+تخيلوا high metal surface، و high metal surface بده
+
+276
+00:25:44,070 --> 00:25:49,290
+أحط شيء عليه، إذا الشيء هذا التصق هنا، التصق على
+
+277
+00:25:49,290 --> 00:25:54,110
+السطح الخارجي، هذا بسميه adsorption
+
+278
+00:25:58,830 --> 00:26:06,610
+adsorption، وإذا هذا الشيء دخل جوا الـ metal تمامًا زي
+
+279
+00:26:06,610 --> 00:26:09,430
+ما الإنسان أحيانًا بياخد مرهم بيحطه على الإيد
+
+280
+00:26:09,430 --> 00:26:14,770
+بيَدْخُل جوا الإيد، هذه العملية إيش بنسميها؟ absorption
+
+281
+00:26:14,770 --> 00:26:21,630
+absorption، هذول مصطلحين باللغة العربية بنسميه
+
+282
+00:26:21,630 --> 00:26:30,690
+adsorption أدمصاص، و absorption امتصاص، واضح؟ فالـ
+
+283
+00:26:30,690 --> 00:26:35,030
+adsorption عادةً بيكون at the surface، على السطح، الـ
+
+284
+00:26:35,030 --> 00:26:41,780
+absorption جوا، واضح الفكرة؟ بالمصطلحين، الآن الغاز
+
+285
+00:26:41,780 --> 00:26:46,680
+يا ترى بقدر يدخل جوا المعدن؟ إذا إيش بيصير له؟
+
+286
+00:26:46,680 --> 00:26:53,580
+absorption، تمامًا زي مثلًا الفحم، ما بيمتص الغازات
+
+287
+00:26:53,580 --> 00:26:57,300
+عشان هيك يستعمل في الأقنعة اللي بيستعملوها في
+
+288
+00:26:57,300 --> 00:27:01,780
+الحروب وما إلى ذلك، بيخلوا الفحم باودر على أساس
+
+289
+00:27:01,780 --> 00:27:06,760
+يصير له surface كبير، الغاز وين بيجي بيلتصق؟ على
+
+290
+00:27:06,760 --> 00:27:12,080
+السطح الخارجي لبودرة الفحم، ولذلك القناع أو الكمامة
+
+291
+00:27:12,080 --> 00:27:17,700
+تبع الحرب بتكون مليانة إيش؟ فحم، لأن الغازات بيصير
+
+292
+00:27:17,700 --> 00:27:22,420
+الالتصاق على سطح الفحم، يمكن إحنا الفكرة بنستعملها
+
+293
+00:27:22,420 --> 00:27:27,240
+شوية تطبيقيًا، لما الناس مرات بيسافروا وبدهُم يسيبوا
+
+294
+00:27:27,240 --> 00:27:31,220
+التلاجة بتاعتهم لفترة مش شغالة، بيجيبوا خمس ست
+
+295
+00:27:31,220 --> 00:27:36,790
+فحمات وبيحطوهم بالفريزر عشان ما يبوظوش، واضح الفكرة؟
+
+296
+00:27:36,790 --> 00:27:41,350
+الآن هذا الفحم بيلتصق عليه الغاز، كذلك الـ metal
+
+297
+00:27:41,350 --> 00:27:46,250
+هنا بيلتصق وين؟ الهيدروجين بيلتصق على الـ metal،
+
+298
+00:27:46,250 --> 00:27:49,730
+الآن هذا الهيدروجين اللي ملتصق على الـ metal لما
+
+299
+00:27:49,730 --> 00:27:54,310
+يلاقي الـ double bond، هيضيف عليها من جهة واحدة،
+
+300
+00:27:54,310 --> 00:28:00,640
+يعمل عندنا إيش؟ syn addition، يعني هاي مثال ثاني، هاي
+
+301
+00:28:00,640 --> 00:28:04,440
+double bond، الهيدروجين ملتصق على سطح المعدن، هاي
+
+302
+00:28:04,440 --> 00:28:08,640
+المعدن، هي ملتصق، لما ضاف، ضاف من جهة واحدة ولا من
+
+303
+00:28:08,640 --> 00:28:13,260
+جهتين؟ من جهة واحدة، فما نوع الإضافة هنا؟ syn
+
+304
+00:28:13,260 --> 00:28:19,200
+addition، الآن، هل يا ترى الـ syn addition تؤدي
+
+305
+00:28:19,200 --> 00:28:24,750
+لتكوين مركب cis أو trans أو لا؟ هذا موضوع ثاني، بتكون
+
+306
+00:28:24,750 --> 00:28:30,090
+تميزه بين شغلتين، بين شيء اسمه كيف تمت الإضافة،
+
+307
+00:28:30,090 --> 00:28:33,910
+بنقول قولًا واحدًا: تمت الإضافة من جهة واحدة، the
+
+308
+00:28:33,910 --> 00:28:38,730
+same addition، الآن الناتج، هل يا ترى الناتج اللي
+
+309
+00:28:38,730 --> 00:28:43,090
+موجود عندي، cis ولا trans؟ كلمة cis و trans تعتمد
+
+310
+00:28:43,090 --> 00:28:46,730
+على المجموعات اللي موجودة، يعني هنا بعد ما تمت
+
+311
+00:28:46,730 --> 00:28:51,670
+الإضافة، وتمت من اتجاه واحد، باجي بسأل يا ترى،
+
+312
+00:28:51,670 --> 00:28:57,910
+هذا فيه cis و trans؟ بقول: H و H متشابهتان، و
+
+313
+00:28:57,910 --> 00:29:01,090
+H مثل مختلفتان، ما فيش ظاهرة الـ cis والـ trans
+
+314
+00:29:02,120 --> 00:29:08,160
+لكن الإضافة تمت من جهة واحدة دائمًا، الآن إن الإضافة
+
+315
+00:29:08,160 --> 00:29:11,480
+اللي من جهة واحدة اللي هي الـ syn addition هل
+
+316
+00:29:11,480 --> 00:29:16,080
+إجباري إنها تطلع cis و trans؟ لأ، cis و trans
+
+317
+00:29:16,080 --> 00:29:21,760
+بتعتمد على المجموعات الموجودة، ولذلك نفس هذا المثال
+
+318
+00:29:21,760 --> 00:29:30,330
+لو طلعته هنا، هاي double bond عليها مجموعتين متل
+
+319
+00:29:30,330 --> 00:29:35,830
+بدنا نضيف عليها هيدروجين، كيف هنضيف الهيدروجين؟ من
+
+320
+00:29:35,830 --> 00:29:40,110
+جهة واحدة، هينضاف لنا الهيدروجين والهيدروجين من جهة
+
+321
+00:29:40,110 --> 00:29:44,750
+واحدة لتحت، يعني صار عندي الحلقة الخماسية فيها
+
+322
+00:29:44,750 --> 00:29:49,880
+مجموعتين methyl على جهة واحدة، والهيدروجينز على جهة
+
+323
+00:29:49,880 --> 00:29:54,760
+واحدة، الآن هذا المركب فيه cis و trans؟ اطلعوا، كربون
+
+324
+00:29:54,760 --> 00:29:59,840
+حاملة methyl و H مختلفتان، كربون حاملة methyl و H
+
+325
+00:29:59,840 --> 00:30:04,280
+مختلفتان، الـ methyl والـ methyl على جهة واحدة، إذًا هذا المركب
+
+326
+00:30:04,280 --> 00:30:09,760
+cis، لاحظوا هنا صار عندي syn addition أدّى لتكوين
+
+327
+00:30:09,760 --> 00:30:15,460
+المركب الـ cis، في المثال السابق، صار عندي syn
+
+328
+00:30:15,460 --> 00:30:22,670
+addition ما أدّى لشىء، فالـ syn addition دائمًا موجود
+
+329
+00:30:22,670 --> 00:30:26,590
+يؤدي لـ cis أو trans أو ما يكونش موجود، هذا بيعتمد
+
+330
+00:30:26,590 --> 00:30:32,790
+على طبيعة المجموعات اللي موجودة، وين؟ على الـ alkene
+
+331
+00:30:32,790 --> 00:30:39,270
+هذا بالنسبة للجزء الأول اللي هو إضافة الهيدروجين
+
+332
+00:30:39,270 --> 00:30:45,400
+لاحظوا، يمكن بيظل عندي كلمة موجودة في العنوان ولازم
+
+333
+00:30:45,400 --> 00:30:52,060
+نجي عندها، سمّينا العملية reduction of alkenes، هو الـ
+
+334
+00:30:52,060 --> 00:31:05,760
+alkene هنا، شو صار؟ الـ alkene صار الـ......
+
+335
+00:31:05,760 --> 00:31:05,840
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+336
+00:31:05,840 --> 00:31:05,920
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+337
+00:31:05,920 --> 00:31:06,060
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+338
+00:31:06,060 --> 00:31:10,590
+ال الآن إحنا في الـ organic chemistry، في عندنا
+
+339
+00:31:10,590 --> 00:31:15,270
+قاعدة، لما المركبات بتتحول من عائلة لعائلة لعائلة
+
+340
+00:31:15,270 --> 00:31:19,450
+لعائلة، إذا تحولت باتجاه معين، بقول هذه العملية
+
+341
+00:31:19,450 --> 00:31:24,430
+oxidation، وإذا تحولت باتجاه آخر، بقول هذه العملية
+
+342
+00:31:24,430 --> 00:31:31,090
+reduction، فأنا لو بدي أعطيكم مُختصر لهذا الأمر بقول
+
+343
+00:31:31,090 --> 00:31:40,850
+أبسط الأشياء: الـ alkanes، تمام؟ بعدها الـ alkenes، بعد
+
+344
+00:31:40,850 --> 00:31:46,030
+هيك ربما عند الـ alcohols، الـ RCH2OH
+
+345
+00:31:46,030 --> 00:31:52,350
+بعد هيك في عندك الـ ketones والـ aldehydes اللي
+
+346
+00:31:52,350 --> 00:31:59,130
+فيهم C=O، بعدهم الأحماض، C=O
+
+347
+00:31:59,130 --> 00:32:06,780
+OH، وأعلى مرتبة في الأكسدة: ثاني أكسيد الكربون اللي
+
+348
+00:32:06,780 --> 00:32:11,420
+متصل بأربع روابط أكسجين، الآن إذا تحولنا من ألكان
+
+349
+00:32:11,420 --> 00:32:16,880
+لألكين، فالعملية أكسدة، من ألكان لألكين، بعد شوية كمان
+
+350
+00:32:16,880 --> 00:32:22,320
+أكسدة لكحول، أكسدة لألدهيد، أكسدة، لاحظوا أنا
+
+351
+00:32:22,320 --> 00:32:26,620
+عندي رابطة أحادية مع الأكسجين هنا، رابطتين في
+
+352
+00:32:26,620 --> 00:32:31,110
+الـ ketone هنا، ثلاث في اللي بدهم يفهموا الأكسدة، حتى من
+
+353
+00:32:31,110 --> 00:32:37,410
+ناحية الـ oxygen هنا، أربعة، الآن إذا مشينا بالعكس
+
+354
+00:32:37,410 --> 00:32:42,370
+بنقول العملية reduction، عشان هيك لما ندرس الكيمياء
+
+355
+00:32:42,370 --> 00:32:46,190
+بعد شوية، نحول كحول لألدهيد أو كيتون، شو هنسمي
+
+356
+00:32:46,190 --> 00:32:50,870
+العملية؟ أكسدة، يعني لما ندرس chapter الـ alcohol و
+
+357
+00:32:50,870 --> 00:32:55,170
+بنقول alcohol تحول لألدهيد أو كيتون، هنسمي
+
+358
+00:32:55,170 --> 00:33:02,560
+العملية أكسدة، كيتون يرجع لألكين، reduction، ألكين صار
+
+359
+00:33:02,560 --> 00:33:09,140
+ألكين، oxidation، ألكين رجع لألكان، reduction، واضح؟
+
+360
+00:33:09,140 --> 00:33:17,560
+ضمن هالسلسلة بنقدر نفهم... ضمن هالسلسلة بنقدر
+
+361
+00:33:17,560 --> 00:33:22,860
+نفهم اللي إحنا بنعنيه بالأكسدة والاختزال، هذه كلها
+
+362
+00:33:22,860 --> 00:33:28,020
+أمثلة بتوضح كيف ضفنا الـ hydrogen، الآن التفاعل
+
+363
+00:33:28,020 --> 00:33:33,440
+الثاني، إضافة بروم، مرة ثانية بروم، symmetric ولا
+
+364
+00:33:33,440 --> 00:33:39,180
+unsymmetric؟ symmetric reagent، لكن بالتجربة...
+
+365
+00:33:39,180 --> 00:33:43,400
+بالدليل التجريبي، مش كل شيء بالنظريّة فيه، اللي لاحظوا
+
+366
+00:33:43,400 --> 00:33:48,660
+أن البروم لما بيضيف... بيضيف anti addition، من جهتين
+
+367
+00:33:48,660 --> 00:33:54,320
+متعاكستين، يعني ما بيضيفش من نفس الجهة، لاحظوا هاي
+
+368
+00:33:54,320 --> 00:33:59,680
+الـ alkene، ضفنا عليه برومين، أعطانا syn ولا anti
+
+369
+00:33:59,680 --> 00:34:04,700
+addition؟ anti addition، إذًا الهيدروجين كأول
+
+370
+00:34:04,700 --> 00:34:09,360
+symmetric reagent ضاف من جهة واحدة، البروم، يعني
+
+371
+00:34:09,360 --> 00:34:12,460
+لو تخيلت أن هذا جزء برومين وجاي يضيف على double
+
+372
+00:34:12,460 --> 00:34:19,650
+bond، هنا بيضيف من جهتين مختلفتين، الآن مرة ثانية
+
+373
+00:34:19,650 --> 00:34:25,570
+البروم، دائمًا anti-addition، يعطي cis أو trans؟ لأ،
+
+374
+00:34:25,570 --> 00:34:32,610
+حسب الجزئ اللي موجود عنده، حسب المجموعات اللي
+
+375
+00:34:32,610 --> 00:34:36,310
+موجودة على الجزئ عنده، ممكن يعطي cis، ممكن يعطي
+
+376
+00:34:36,310 --> 00:34:41,190
+trans، ممكن ما يعطيش شيء، واضح؟ يعني في حالة زي هذه
+
+377
+00:34:41,190 --> 00:34:46,260
+لما بيضيف، لو افترضنا أن هذول كلهم hydrogens، لأ،
+
+378
+00:34:46,260 --> 00:34:54,520
+طبعًا لأ، أكيد أكيد لأ، لو افترضنا أن البروم بيضيف
+
+379
+00:34:54,520 --> 00:35:00,060
+على الهيدروجين، كل هذول الذرات الأربع ما زالوا
+
+380
+00:35:00,060 --> 00:35:06,320
+هيدروجين، الآن لاحظوا زملائكم على طول غلطة، غلطة
+
+381
+00:35:06,320 --> 00:35:14,060
+كبيرة جدًا، البحر، ليش؟ لأنه قلنا ظاهرة الـ cis والـ trans
+
+382
+00:35:14,060 --> 00:35:18,780
+أساسًا كظاهرة يا بتنوجد حوالين الـ double bond، يا
+
+383
+00:35:18,780 --> 00:35:24,500
+حوالين الـ single bond في الحلقة، في منها؟ لأ، وحكينا
+
+384
+00:35:24,500 --> 00:35:29,280
+أن هذا، طالما single bond، في حالة دوران دائم، أبديّة،
+
+385
+00:35:29,280 --> 00:35:36,560
+هو في لحظة الإضافة بيبقى زي هيك، لكن بعد ثانية بيلف
+
+386
+00:35:38,450 --> 00:35:40,690
+ما فيه كل ظاهرة الـ cis والـ trans، الرابطة
+
+387
+00:35:40,690 --> 00:35:44,970
+الوحيدة فيها ظاهرة الـ cis والـ trans، لا، ما فيش
+
+388
+00:35:44,970 --> 00:35:49,070
+فيها ظاهرة الـ cis والـ trans، لكن الإضافة في لحظة
+
+389
+00:35:49,070 --> 00:35:54,270
+الإضافة كيف ض
+
+445
+00:41:28,510 --> 00:41:35,470
+ومجموعة ثانية CH3 هَنبينَهم باللون الأصفر الآن
+
+446
+00:41:35,470 --> 00:41:40,310
+لاحظوا هذول المجموعتين في مستوى الحلقة أم لا؟
+
+447
+00:41:40,310 --> 00:41:46,380
+مستوى الحلقة الآن. باقي الكربونات، ماذا عليها؟ كلّ
+
+448
+00:41:46,380 --> 00:41:50,260
+واحدة اثنتين CH2، العلم الجديد الذي تعلمناه، واحدة
+
+449
+00:41:50,260 --> 00:41:58,100
+لفوق، واحدة لتحت. هنا عند اثنتين CH2 لفوق وللتحت هنا
+
+450
+00:41:58,100 --> 00:42:02,440
+في عند اثنتين
+
+451
+00:42:02,440 --> 00:42:03,260
+هيدروجين
+
+452
+00:42:05,710 --> 00:42:09,730
+لا فوق ولا تحت. هذا هو الجزء الموجود عندكم الآن
+
+453
+00:42:09,730 --> 00:42:14,090
+لاحظوا أن هؤلاء في مستوى واحد carbon carbon carbon
+
+454
+00:42:14,090 --> 00:42:19,550
+carbon carbon carbon. واضح؟ بناءً على ذلك، هؤلاء في
+
+455
+00:42:19,550 --> 00:42:23,970
+البداية كان السؤال: هم أساسًا مثل الـ cis أم الـ
+
+456
+00:42:23,970 --> 00:42:29,470
+trans؟ لا، في الحلقة يكونوا على نفس المستوى، ما فيش
+
+457
+00:42:29,470 --> 00:42:32,930
+فيه cis و trans.  الـ cis والـ trans أن في فوق وتحت
+
+458
+00:42:32,930 --> 00:42:35,810
+حول الـ single bond في الحلقة، مش حول الـ
+
+459
+00:42:35,810 --> 00:42:41,110
+double bond في الحلقة، إنما هؤلاء جايين على جهة
+
+460
+00:42:41,110 --> 00:42:46,030
+واحدة،  الذي يحتمل أن يكونوا فوق أو تحت الحلقة. لا، لما
+
+461
+00:42:46,030 --> 00:42:51,890
+أنا أعمل الإضافة، خليني أفترض أن أنا بدي أضيف بروم
+
+462
+00:42:51,890 --> 00:42:59,330
+وخليني أعطي للبروم مجموعتين زرقاء أو للهيدروجين
+
+463
+00:42:59,330 --> 00:43:05,670
+ونوضحهم بروابط كبيرة. قلنا
+
+464
+00:43:05,670 --> 00:43:12,550
+عملية الإضافة هي عملية ماذا؟ كسر رابطة زوجية الآن
+
+465
+00:43:12,550 --> 00:43:20,410
+هي نكسِرُها ونحط بدالها two new sigma bonds. الآن لو
+
+466
+00:43:20,410 --> 00:43:24,270
+كنت أضيف الهيدروجين، هذول حيصيروا على جهة واحدة
+
+467
+00:43:25,230 --> 00:43:30,450
+ومثلهم على جهة واحدة. هذه هي الـ syn Addition التي
+
+468
+00:43:30,450 --> 00:43:38,690
+قدّتُ لـ syn مرة ثانية. لو رجعت وكنتُ أبدأ أضيف بروم
+
+469
+00:43:38,690 --> 00:43:42,550
+وقتها
+
+470
+00:43:42,550 --> 00:43:49,510
+لما أبدأ أكسر الرابطة، بدّو هؤلاء يتحركوا بهذا الشكل
+
+471
+00:43:56,030 --> 00:44:00,630
+واضح الفكرة؟ أنا كسرت الروابط لأنهم مرتبطين، بس هم
+
+472
+00:44:00,630 --> 00:44:06,710
+في النهاية فراغات، يعني، بالتالي سهل يتحركوا، واضح؟
+
+473
+00:44:06,710 --> 00:44:10,850
+يعني أنا عشان أعمل لكم الشكل، اضطريت أن تشوفوني
+
+474
+00:44:10,850 --> 00:44:14,870
+أكسر الرابطة، لكن في كل الأحوال، بدكم تكونوا
+
+475
+00:44:14,870 --> 00:44:19,390
+فاهمين من الأساس أنتم، لاحظوا الكيمياء ما هي كلّ
+
+476
+00:44:19,390 --> 00:44:24,630
+كلمة مبنية على الثانية. اللحظة ما كنا بنحكي عن تعريف
+
+477
+00:44:24,630 --> 00:44:31,110
+الرابطة، ماذا قلنا هي الرابطة؟ هي مسافة في الفراغ
+
+478
+00:44:31,110 --> 00:44:37,990
+يعني هذه وهذه بالضبط
+
+479
+00:44:37,990 --> 00:44:48,790
+فراغات
+
+480
+00:44:48,790 --> 00:44:55,120
+...يعني هذه المفاهيم تعبير عن خبرة في الكيمياء الآن
+
+481
+00:44:55,120 --> 00:45:01,480
+هذه وهذه مسافات في الفراغ، واضح؟ ليست روابط جامدة
+
+482
+00:45:01,480 --> 00:45:07,380
+وبالتالي أنا لما أجيب بروم من جهتين، وهذه مسافة
+
+483
+00:45:07,380 --> 00:45:11,280
+في الفراغ، وهذه مسافة في الفراغ، ستأتي بروم من فوق هذه
+
+484
+00:45:11,280 --> 00:45:16,750
+تنزل لتحت. ستأتي بروم من تحت هذه تطلع لفوق، واضح؟ لما
+
+485
+00:45:16,750 --> 00:45:20,750
+أجيب الهيدروجين، سيأتي الهيدروجين والهيدروجين بهذا
+
+486
+00:45:20,750 --> 00:45:25,430
+الشكل، ممسكين على سطح المعدن. هذه وهذه سينزلان
+
+487
+00:45:25,430 --> 00:45:31,050
+لتحت. الآن، لما أنا أشتغل بروابط صلبة في الهيدروجين
+
+488
+00:45:31,050 --> 00:45:37,790
+كان سهل أن أوضح لكم هذا بالموديل، صح؟ في البروم لما
+
+489
+00:45:37,790 --> 00:45:41,810
+كسرت الرابطة، اضطريت أن أبين كأني أكسر الرابطة، لكن
+
+490
+00:45:41,810 --> 00:45:47,050
+هي حقيقة، لما تكونوا متخيلين مسافة في الفراغ، ما كسرت
+
+491
+00:45:47,050 --> 00:45:52,710
+رابطة، فقط هذه اتحركت لأعلى، جاء البروم من جهة وهنا
+
+492
+00:45:52,710 --> 00:45:57,850
+جاء البروم من جهة ثانية، حول الـ single bond، ممكن
+
+493
+00:45:57,850 --> 00:46:01,590
+cis و trans، طالما مختلفتان، هذا المركب
+
+494
+00:46:01,590 --> 00:46:06,950
+الذي طلع عندي، ماذا؟ trans، واضح؟ نحن في كل الأحوال
+
+495
+00:46:06,950 --> 00:46:13,170
+الذي نركز عليه أن إضافة الـ hydrogen syn إضافة
+
+496
+00:46:13,170 --> 00:46:17,910
+البروم، الآن النتيجة، سلسلة الـ trans تعتمد على
+
+497
+00:46:17,910 --> 00:46:23,570
+طبيعة الجزء: هل الجزء جزء حلقي؟ جزء غير حلقي؟ هل
+
+498
+00:46:23,570 --> 00:46:29,630
+المجموعات التي فيه، ماذا نوعها؟ واضح؟ يعني خليني
+
+499
+00:46:29,630 --> 00:46:34,290
+بثانية أستأذنكم وأستأذن الأستاذ أيضًا لأننا خلّصنا
+
+500
+00:46:34,290 --> 00:46:41,010
+لو كنا نضيف هيدروجين على هذا الجزء الذي في الأساس
+
+501
+00:46:41,010 --> 00:46:47,970
+كان عليه اثنتين هيدروجين، يعني هذا الجزء كان بهذا
+
+502
+00:46:47,970 --> 00:46:54,730
+الشكل، وكنا قاعدين نضيف عليه هذه الـ double bond
+
+503
+00:46:54,730 --> 00:47:01,030
+في الحلقة، وكنا قاعدين نضيف عليها هيدروجين، حيصير
+
+504
+00:47:01,030 --> 00:47:07,470
+H لتحت وهذه لتحت، وH جديدة لفوق، وH جديدة لفوق. طلعت
+
+505
+00:47:07,470 --> 00:47:11,730
+كل ظاهرة الـ cis والـ trans؟ لا، تعتمد على الـ
+
+506
+00:47:11,730 --> 00:47:15,350
+substituents. يعني لما كانت المجموعتان متشابهتان، طلع
+
+507
+00:47:15,350 --> 00:47:20,140
+المركب cis، لكن لو افترضنا المجموعتان H، ما فيش كلّ
+
+508
+00:47:20,140 --> 00:47:23,380
+الظاهرة. بس في كل الأحوال، أنا لما أضفت الـ hydrogen
+
+509
+00:47:23,380 --> 00:47:28,740
+من جهة واحدة، لما أضفت الـ brom، عرفنا ماذا معنى syn
+
+510
+00:47:28,740 --> 00:47:32,920
+addition، ولذلك عملية الإضافة أسميها mode of
+
+511
+00:47:32,920 --> 00:47:37,300
+addition. The product depends on the nature of the
+
+512
+00:47:37,300 --> 00:47:41,240
+molecule. على طبيعة الجزيء، على المجموعات التي
+
+513
+00:47:41,240 --> 00:47:45,760
+موجودة أساسًا على أطراف الكربون. هل الجزيء حلقة؟ مش
+
+514
+00:47:45,760 --> 00:47:49,780
+حلقة؟ ما إلى ذلك. ونكتفي بهذا القدر.
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/z4_9i2lZ2eY_raw.json b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/z4_9i2lZ2eY_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..df46dbd5c82e689d8f267438dc1e0288ba3f7524
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/z4_9i2lZ2eY_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4684, "start": 21.14, "end": 46.84, "text": "بسم الله الرحمن الرحيم المرة الماضية بدأنا في الفصل الثالث في الكيميا العضوية اللي هو بعنوان ال alkenes and alkynes طبعا بشكل أساسي اتعرفنا على خواص الروابط الأوحدية الثنائية الثلاثية واخدنا تسمية ال alkenes و ال alkynes وركزنا على فكرة", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 47525, 10721, 8315, 8978, 27188, 36520, 6024, 104, 6027, 12984, 8978, 33251, 32640, 25528, 18863, 11242, 2407, 10632, 13672, 1829, 31439, 45030, 1863, 2407, 7649, 2423, 419, 2653, 279, 293, 419, 4133, 4081, 23032, 3555, 3615, 995, 4724, 8592, 28820, 5551, 3794, 32277, 1829, 1975, 2655, 3615, 28480, 8315, 15844, 16490, 14407, 9381, 34892, 14407, 3555, 9566, 16247, 2407, 24401, 10632, 6024, 104, 1863, 16373, 10632, 6024, 104, 1211, 5718, 104, 10632, 4032, 47283, 3215, 8315, 6055, 38251, 10632, 2423, 419, 2653, 279, 4032, 2423, 419, 4133, 4081, 4032, 31747, 11622, 8315, 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بيروح للذرة اللي بعدهم", "tokens": [6027, 39184, 22275, 1230, 5551, 5016, 1829, 7649, 995, 4724, 1829, 7435, 1829, 8717, 5016, 1211, 37893, 28820, 2655, 8315, 8717, 8592, 38688, 3714, 9957, 5551, 3615, 23942, 8978, 2423, 22275, 1230, 34105, 8608, 3224, 1211, 10874, 28259, 7251, 23328, 49429, 12855, 7251, 23328, 48127, 2655, 12984, 7649, 10632, 5551, 5016, 1829, 7649, 995, 4724, 1829, 15040, 38436, 32545, 2288, 2655, 9957, 30767, 1829, 45030, 11242, 49610, 3215, 2655, 11296, 4724, 13546, 2407, 5016, 24976, 8848, 25720, 13672, 1829, 45030, 3215, 16095], "avg_logprob": -0.2850150681403746, "compression_ratio": 1.5810055865921788, "no_speech_prob": 8.344650268554688e-07, "words": [{"start": 561.73, "end": 562.09, "word": "الـ", "probability": 0.2738037109375}, {"start": 562.09, "end": 562.41, "word": " atomic", "probability": 0.49462890625}, {"start": 562.41, "end": 563.07, "word": " number", "probability": 0.9765625}, {"start": 563.07, "end": 564.51, "word": " أحيانا", "probability": 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" بيروح", "probability": 0.906494140625}, {"start": 578.69, "end": 579.29, "word": " للذرة", "probability": 0.6210123697916666}, {"start": 579.29, "end": 580.33, "word": " اللي", "probability": 0.931640625}, {"start": 580.33, "end": 580.91, "word": " بعدهم", "probability": 0.6730143229166666}], "temperature": 1.0}, {"id": 25, "seek": 60653, "start": 581.75, "end": 606.53, "text": "بالهم زي بعض بنروح للبعدها لحد ما نصل لأول اختلاف بيخلي مجموعة أعلى من التانية واضح يعني مثلا هذا المركب لو كنتوا بتطلع عليه هاي carbon شو المجموعات اللي عليها CH3 CH2 CH3 لو أجينا نسأل مين أعلى هدول مختلفات هنا carbon", "tokens": [3555, 6027, 16095, 30767, 1829, 45030, 11242, 44945, 32887, 5016, 24976, 3555, 22488, 11296, 5296, 24401, 19446, 8717, 36520, 5296, 10721, 12610, 1975, 46456, 15040, 5172, 4724, 1829, 9778, 20292, 3714, 7435, 2304, 2407, 27884, 5551, 3615, 23942, 9154, 16712, 7649, 10632, 4032, 46958, 5016, 37495, 22653, 50113, 15040, 23758, 9673, 31747, 3555, 45164, 9122, 29399, 14407, 39894, 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CH2", "probability": 0.90576171875}, {"start": 599.95, "end": 600.81, "word": " CH3", "probability": 0.936279296875}, {"start": 600.81, "end": 601.39, "word": " لو", "probability": 0.95263671875}, {"start": 601.39, "end": 601.79, "word": " أجينا", "probability": 0.80560302734375}, {"start": 601.79, "end": 602.51, "word": " نسأل", "probability": 0.9871826171875}, {"start": 602.51, "end": 602.95, "word": " مين", "probability": 0.95166015625}, {"start": 602.95, "end": 603.43, "word": " أعلى", "probability": 0.9609375}, {"start": 603.43, "end": 603.79, "word": " هدول", "probability": 0.7659505208333334}, {"start": 603.79, "end": 604.71, "word": " مختلفات", "probability": 0.9412841796875}, {"start": 604.71, "end": 605.85, "word": " هنا", "probability": 0.61865234375}, {"start": 605.85, "end": 606.53, "word": " carbon", "probability": 0.87158203125}], "temperature": 1.0}, {"id": 26, "seek": 63547, "start": 607.43, "end": 635.47, "text": "وهنا carbon زي بعض وقت أروح للذرة التانية لو بدكوا بالتفصيل الممل أكيد هتقولوا أن هنا في عندي H وH و بعدها carbon هذه H وH و بعدها H فلو إجيتوا تقارنوا C وحملة كل هذا زي بعضه C وحملة", "tokens": [2407, 3224, 8315, 5954, 30767, 1829, 45030, 11242, 4032, 38149, 5551, 32887, 5016, 24976, 8848, 25720, 16712, 7649, 10632, 45164, 47525, 4117, 14407, 20666, 2655, 5172, 9381, 26895, 9673, 42213, 5551, 4117, 25708, 8032, 2655, 39648, 14407, 14739, 34105, 8978, 43242, 1829, 389, 4032, 39, 4032, 39182, 11296, 5954, 29538, 389, 4032, 39, 4032, 39182, 11296, 389, 6156, 1211, 2407, 11933, 7435, 36081, 14407, 6055, 4587, 9640, 1863, 14407, 383, 4032, 35571, 37977, 28242, 23758, 30767, 1829, 45030, 11242, 3224, 383, 4032, 35571, 37977], "avg_logprob": -0.25698528570287366, "compression_ratio": 1.6906077348066297, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 607.43, "end": 607.99, "word": "وهنا", "probability": 0.6519368489583334}, {"start": 607.99, "end": 609.27, "word": " carbon", "probability": 0.38134765625}, {"start": 609.27, 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"word": " أن", "probability": 0.398681640625}, {"start": 617.11, "end": 617.39, "word": " هنا", "probability": 0.7607421875}, {"start": 617.39, "end": 617.55, "word": " في", "probability": 0.81787109375}, {"start": 617.55, "end": 617.95, "word": " عندي", "probability": 0.463623046875}, {"start": 617.95, "end": 618.37, "word": " H", "probability": 0.83544921875}, {"start": 618.37, "end": 620.01, "word": " وH", "probability": 0.707763671875}, {"start": 620.01, "end": 620.43, "word": " و", "probability": 0.775390625}, {"start": 620.43, "end": 620.99, "word": " بعدها", "probability": 0.848876953125}, {"start": 620.99, "end": 622.03, "word": " carbon", "probability": 0.712890625}, {"start": 622.03, "end": 622.67, "word": " هذه", "probability": 0.449462890625}, {"start": 622.67, "end": 624.67, "word": " H", "probability": 0.86083984375}, {"start": 624.67, "end": 626.13, "word": " وH", "probability": 0.8671875}, {"start": 626.13, "end": 627.69, "word": " و", "probability": 0.9306640625}, {"start": 627.69, "end": 628.05, "word": " بعدها", "probability": 0.8564453125}, {"start": 628.05, "end": 628.45, "word": " H", "probability": 0.9833984375}, {"start": 628.45, "end": 629.71, "word": " فلو", "probability": 0.98681640625}, {"start": 629.71, "end": 630.15, "word": " إجيتوا", "probability": 0.78839111328125}, {"start": 630.15, "end": 631.39, "word": " تقارنوا", "probability": 0.95908203125}, {"start": 631.39, "end": 631.91, "word": " C", "probability": 0.771484375}, {"start": 631.91, "end": 632.67, "word": " وحملة", "probability": 0.888671875}, {"start": 632.67, "end": 633.11, "word": " كل", "probability": 0.1553955078125}, {"start": 633.11, "end": 633.41, "word": " هذا", "probability": 0.77587890625}, {"start": 633.41, "end": 633.73, "word": " زي", "probability": 0.990234375}, {"start": 633.73, "end": 634.19, "word": " بعضه", "probability": 0.9392903645833334}, {"start": 634.19, "end": 634.85, "word": " C", "probability": 0.86376953125}, {"start": 634.85, "end": 635.47, "word": " وحملة", "probability": 0.9744466145833334}], "temperature": 1.0}, {"id": 27, "seek": 64823, "start": 636.27, "end": 648.23, "text": "وين أول اختلاف؟ نمر اتنين carbon، نمر اتنين H، اذا من المجموعة الأعلى صفيات؟ فانا لما بمشي في المجموعات", "tokens": [2407, 9957, 5551, 12610, 1975, 46456, 15040, 5172, 22807, 8717, 29973, 1975, 2655, 1863, 9957, 5954, 12399, 8717, 29973, 1975, 2655, 1863, 9957, 389, 12399, 1975, 15730, 9154, 9673, 7435, 2304, 2407, 27884, 16247, 3615, 23942, 20328, 41185, 9307, 22807, 6156, 7649, 995, 5296, 15042, 4724, 2304, 8592, 1829, 8978, 9673, 7435, 2304, 45367, 9307], "avg_logprob": -0.25530134460755755, "compression_ratio": 1.4596774193548387, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 636.27, "end": 636.61, "word": "وين", "probability": 0.441162109375}, {"start": 636.61, "end": 636.91, "word": " أول", "probability": 0.7646484375}, {"start": 636.91, "end": 637.97, "word": " اختلاف؟", "probability": 0.8576171875}, {"start": 637.97, 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{"start": 931.81, "end": 932.53, "word": " انضافوا", "probability": 0.866455078125}, {"start": 932.53, "end": 933.15, "word": " واضح", "probability": 0.84130859375}, {"start": 933.15, "end": 933.77, "word": " طبعا", "probability": 0.9207763671875}, {"start": 933.77, "end": 933.99, "word": " هنا", "probability": 0.94677734375}, {"start": 933.99, "end": 934.17, "word": " في", "probability": 0.8662109375}, {"start": 934.17, "end": 935.67, "word": " عنده", "probability": 0.8486328125}, {"start": 935.67, "end": 936.53, "word": " أشياء", "probability": 0.902587890625}, {"start": 936.53, "end": 936.93, "word": " تانية", "probability": 0.9384765625}, {"start": 936.93, "end": 937.31, "word": " كانت", "probability": 0.98828125}, {"start": 937.31, "end": 937.77, "word": " موجودة", "probability": 0.9908447265625}, {"start": 937.77, "end": 938.09, "word": " بتظل", "probability": 0.5555826822916666}, {"start": 938.09, "end": 938.29, "word": " زي", "probability": 0.986328125}, {"start": 938.29, 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{"start": 957.85, "end": 958.05, "word": " ال", "probability": 0.9189453125}, {"start": 958.05, "end": 958.41, "word": " by", "probability": 0.286376953125}, {"start": 958.41, "end": 958.83, "word": " bond", "probability": 0.88232421875}, {"start": 958.83, "end": 959.69, "word": " اتحولت", "probability": 0.90126953125}, {"start": 959.69, "end": 960.35, "word": " لإيش", "probability": 0.8148193359375}], "temperature": 1.0}, {"id": 42, "seek": 97758, "start": 961.18, "end": 977.58, "text": "لـ two new sigma bonds يعني تفاعل الـ addition لو بدي تعريف له بدي أقول تحويل ال buy bond هذه الى two new sigma bonds", "tokens": [1211, 39184, 732, 777, 12771, 14713, 37495, 22653, 6055, 5172, 995, 30241, 2423, 39184, 4500, 45164, 4724, 16254, 37279, 16572, 5172, 46740, 4724, 16254, 5551, 39648, 6055, 5016, 2407, 26895, 2423, 2256, 6086, 29538, 2423, 7578, 732, 777, 12771, 14713], "avg_logprob": -0.3509908478434493, "compression_ratio": 1.3252032520325203, "no_speech_prob": 0.0, "words": [{"start": 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له", "probability": 0.4033203125}, {"start": 967.92, "end": 968.52, "word": " بدي", "probability": 0.572998046875}, {"start": 968.52, "end": 968.98, "word": " أقول", "probability": 0.775146484375}, {"start": 968.98, "end": 969.9, "word": " تحويل", "probability": 0.9705810546875}, {"start": 969.9, "end": 970.66, "word": " ال", "probability": 0.94677734375}, {"start": 970.66, "end": 971.16, "word": " buy", "probability": 0.171142578125}, {"start": 971.16, "end": 971.62, "word": " bond", "probability": 0.92822265625}, {"start": 971.62, "end": 972.22, "word": " هذه", "probability": 0.497314453125}, {"start": 972.22, "end": 974.34, "word": " الى", "probability": 0.6405029296875}, {"start": 974.34, "end": 974.56, "word": " two", "probability": 0.8994140625}, {"start": 974.56, "end": 975.26, "word": " new", "probability": 0.90673828125}, {"start": 975.26, "end": 976.92, "word": " sigma", "probability": 0.9033203125}, {"start": 976.92, "end": 977.58, "word": " bonds", "probability": 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"text": "واضح؟ هدولة في نفس المستوى تبع الحلقة لما بيجي البروم اضيف بيخلي واحدة لتحت واحدة لفوق و البروم بنعكس لو اجي الهيدروجين اضيف بيخلي تنتين لتحت و الهيدروجين بيجي لفوق طبعا ما عدا ما عدا ال double bond بيكون انا في عندى كام ذرة هيدروجين في الجزء؟ تنتين", "tokens": [2407, 46958, 5016, 22807, 8032, 3215, 12610, 3660, 8978, 8717, 36178, 9673, 14851, 2407, 7578, 6055, 3555, 3615, 21542, 1211, 28671, 5296, 15042, 4724, 1829, 7435, 1829, 2423, 26890, 20498, 1975, 11242, 33911, 4724, 1829, 9778, 20292, 36764, 24401, 3660, 5296, 2655, 33753, 36764, 24401, 3660, 5296, 5172, 30543, 4032, 2423, 26890, 20498, 44945, 3615, 4117, 3794, 45164, 1975, 7435, 1829, 2423, 3224, 25708, 2288, 29245, 9957, 1975, 11242, 33911, 4724, 1829, 9778, 20292, 6055, 29399, 9957, 5296, 2655, 33753, 4032, 2423, 3224, 25708, 2288, 29245, 9957, 4724, 1829, 7435, 1829, 5296, 5172, 30543, 23032, 3555, 3615, 995, 19446, 6225, 28259, 19446, 6225, 28259, 2423, 3834, 6086, 4724, 1829, 30544, 1975, 8315, 8978, 43242, 7578, 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/z4_9i2lZ2eY_raw.srt b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/z4_9i2lZ2eY_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..06221a431179ca47bac4a540fef3cdf8472859e0
--- /dev/null
+++ b/PL9fwy3NUQKwaHZss7X68e0gpAlWqz-tlA/z4_9i2lZ2eY_raw.srt
@@ -0,0 +1,2084 @@
+1
+00:00:21,140 --> 00:00:26,480
+بسم الله الرحمن الرحيم المرة الماضية بدأنا في
+
+2
+00:00:26,480 --> 00:00:32,300
+الفصل الثالث في الكيميا العضوية اللي هو بعنوان ال
+
+3
+00:00:32,300 --> 00:00:37,500
+alkenes and alkynes طبعا بشكل أساسي اتعرفنا على
+
+4
+00:00:37,500 --> 00:00:42,020
+خواص الروابط الأوحدية الثنائية الثلاثية واخدنا
+
+5
+00:00:42,020 --> 00:00:46,840
+تسمية ال alkenes و ال alkynes وركزنا على فكرة
+
+6
+00:00:47,640 --> 00:00:53,300
+موجودة كثير في هذا المجال هي فكرة وجود ال stereo
+
+7
+00:00:53,300 --> 00:00:57,700
+isomers تحديدا ال cis و ال trans اللي قولنا عنهم
+
+8
+00:00:57,700 --> 00:01:00,780
+هدول عبارة عن diastereomers
+
+9
+00:01:03,880 --> 00:01:08,860
+كامتداد بسيط فقط لفكرة ال sis و ال trans احنا قلنا
+
+10
+00:01:08,860 --> 00:01:12,940
+بيكون عندنا موجود sis او trans سواء حول ال double
+
+11
+00:01:12,940 --> 00:01:17,340
+bond او حول ال single bond في حلقة اذا كان في عندى
+
+12
+00:01:17,340 --> 00:01:21,380
+على كل ذرة كربون من الذرات المعنية مجمعتين
+
+13
+00:01:21,380 --> 00:01:26,500
+مختلفتين بقدر اقول sis و trans يعني المركب بيكون
+
+14
+00:01:26,500 --> 00:01:33,310
+في منه اتنين الان لو يا ترى أخدنا مثال جديدهذا
+
+15
+00:01:33,310 --> 00:01:39,310
+المثال هي double bond وهي carbon وهي carbon هل هنا
+
+16
+00:01:39,310 --> 00:01:43,250
+في عندي مجموعتين مختلفتين ولا لأ؟ عندي مجموعتين
+
+17
+00:01:43,250 --> 00:01:47,910
+مختلفتين هل هنا في عندي مجموعتين مختلفتين ولا لأ؟
+
+18
+00:01:47,910 --> 00:01:52,230
+في عندي مجموعتين مختلفتين إذا هذا المركب في منه
+
+19
+00:01:52,230 --> 00:01:57,130
+مركب واحد ولا اتنين؟في منه مراكبين لو بده المراكب
+
+20
+00:01:57,130 --> 00:02:02,650
+التاني بثبت اي تنتين وبعكس التنتين التانية يعني
+
+21
+00:02:02,650 --> 00:02:06,990
+لاحظوا هذا المراكب نفسه رسمناها تخلينا على سبيل
+
+22
+00:02:06,990 --> 00:02:12,190
+المثال اليود والكلور زي ما هما عكسنا مجموعة المثل
+
+23
+00:02:12,190 --> 00:02:16,170
+لتحت ال PR لفوق تخلينا ال PR لتحت المثل لفوق هاي
+
+24
+00:02:16,170 --> 00:02:22,320
+المراكب التانيواضح؟ ولو هذا المركب احنا بدنا نسميه
+
+25
+00:02:22,320 --> 00:02:28,540
+مش صعب علينا نسميه كمواقع ذرات كمواقع ذرات carbon
+
+26
+00:02:28,540 --> 00:02:34,400
+تنتين تلاتة أطول سلسلة اذا هذا المركب اي مركب
+
+27
+00:02:34,400 --> 00:02:44,250
+بروبيل بروبيل هذا المركب حامل يود وبروم وكلوربدنا
+
+28
+00:02:44,250 --> 00:02:47,990
+نذكرهم alphabetically، لاحظوا ما حد يقول إنه حامل
+
+29
+00:02:47,990 --> 00:02:53,430
+مثل، المثل جزء من السلسلات الطويلة، هو حامل تلاتة
+
+30
+00:02:53,430 --> 00:02:56,410
+substituents، يود و بروم و كلور، لما نذكرهم
+
+31
+00:02:56,410 --> 00:03:00,870
+alphabetically، two bromo, one cloro, one iodo,
+
+32
+00:03:01,090 --> 00:03:06,750
+one probine لكن، ضالت المشكلة، هل يترى هذا المركب
+
+33
+00:03:06,750 --> 00:03:12,470
+cis ولا trans؟اللي بتيجي تفكر بالعلم البسيط اللي
+
+34
+00:03:12,470 --> 00:03:18,050
+اتعلمته هتفكر بالقاتل انه احنا قولنا اذا في عندى
+
+35
+00:03:18,050 --> 00:03:21,430
+مثلا مجموعتين زي بعض كنا نقول كلور و كلور عجية
+
+36
+00:03:21,430 --> 00:03:26,130
+واحدة سس عجيتين متعاكسات Trans لكن الحمد لله هذا
+
+37
+00:03:26,130 --> 00:03:33,460
+المركب فيه اربع مجموعات مختلفة وبناء على ذلكرغم ان
+
+38
+00:03:33,460 --> 00:03:36,580
+انتوا قادرين تقولوا انه منه two compounds، two
+
+39
+00:03:36,580 --> 00:03:39,720
+stereoisomers، بس ولا واحدة قادرة تقول سيس ولا
+
+40
+00:03:39,720 --> 00:03:44,900
+ترانس تمام؟ الحقيقة الظاهرة هنا شوية اكبر من السيس
+
+41
+00:03:44,900 --> 00:03:49,660
+والترانس لما نيجي نحلها، بنحلها بالشكل القاتل،
+
+42
+00:03:49,660 --> 00:03:53,980
+بنسأل نفسنا، بنقول بدنا نقارن هذه الذرة وهذه
+
+43
+00:03:53,980 --> 00:04:00,320
+الذرة، يود وكلور، هدول مختلفتان، مين فيهم إلها
+
+44
+00:04:00,320 --> 00:04:05,880
+atomic number أعلى؟واضح؟ طبعا مابديش حد يقول مرة
+
+45
+00:04:05,880 --> 00:04:08,840
+تانية مش حافظ الجدول الدوري انا مابديش ال atomic
+
+46
+00:04:08,840 --> 00:04:15,380
+number انا بدي مقارنة والمقارنة الأصل معروفة معروف
+
+47
+00:04:15,380 --> 00:04:18,740
+جزء الجدول الدوري مائة مرة حكينا اللي فيه carbon,
+
+48
+00:04:18,960 --> 00:04:22,160
+nitrogen, oxygen, fluorine, chlorine, bromine,
+
+49
+00:04:22,160 --> 00:04:26,200
+iodine, sulfur هذي أعلى من هذه أعلى من هذه أعلى من
+
+50
+00:04:26,200 --> 00:04:30,350
+هذه أعلى من هذه أعلى من هذه أعلى من هذه واضح؟هذا
+
+51
+00:04:30,350 --> 00:04:34,670
+الكلام معروف اذا لما انا بدي اقارن يود مع كلور مين
+
+52
+00:04:34,670 --> 00:04:39,890
+الأعلى ال يود ممتازة في ال atomic number لما بدي
+
+53
+00:04:39,890 --> 00:04:45,150
+اقارن بروم مع كاربون اطلع ذرة ذرة مديش اقول مع ال
+
+54
+00:04:45,150 --> 00:04:48,550
+CH3 لأ مع الذرة المتصلة مباشرة مع اي ذرة المتصلة
+
+55
+00:04:48,550 --> 00:04:53,090
+مباشرة بال double bond كاربون الذرة هنا بروم مين
+
+56
+00:04:53,090 --> 00:04:58,510
+أعلى بروم ولا كاربونأكيد لبروم، الآن هذه الأعلى و
+
+57
+00:04:58,510 --> 00:05:03,350
+هذه الأعلى إجوا على جهة واحدة، في هذه الحالة كإني
+
+58
+00:05:03,350 --> 00:05:09,210
+بتخيل إنه المركب إيش؟ سس، لو إجيت هنا يود و كلور،
+
+59
+00:05:09,210 --> 00:05:17,270
+اليود أعلىبروم و Carbon البروم أعلى بناء على ذلك
+
+60
+00:05:17,270 --> 00:05:23,790
+المجموعات الأعلى أتوا على جهتين متعاكستين كأن هذا
+
+61
+00:05:23,790 --> 00:05:30,070
+المركب Trans لكن الحقيقة هنا جرت العادة أننا
+
+62
+00:05:30,070 --> 00:05:37,150
+مانستعملش مصطلح زد Trans و Cis لأ بنستعمل بديل له
+
+63
+00:05:37,150 --> 00:05:43,510
+ال Cis و ال Trans عادةتستعمل للمراكبات البسيطة
+
+64
+00:05:43,510 --> 00:05:50,170
+الواضحة اللي عمل هذه القواعد إنسان معتزب لغته لغته
+
+65
+00:05:50,170 --> 00:05:55,170
+ألمانية احنا في العربي كنا نستعمل بدل cis و trans
+
+66
+00:05:55,170 --> 00:06:04,930
+مع و ضد الإنجليز cis و trans الآن هو ألماني مش أقل
+
+67
+00:06:04,930 --> 00:06:09,680
+منه قال لأ أنا بدي أجيب من اللغة الألمانيةإيش معنى
+
+68
+00:06:09,680 --> 00:06:14,400
+مع وإيش معنى ضد، يعني البادئة تبقى .. البادئة
+
+69
+00:06:14,400 --> 00:06:17,960
+بديها من اللغة الألمانية، فباللغة الألمانية مع
+
+70
+00:06:17,960 --> 00:06:25,940
+اللي هي together، it's zusammen، zusammen بالزدسو
+
+71
+00:06:25,940 --> 00:06:31,600
+زامن الآن جال من سو زامن بدي أخد حرف ال Z فال Z
+
+72
+00:06:31,600 --> 00:06:38,080
+هذه صارت موازية لل سس اللي بالإنقليزي و لكلمة مع
+
+73
+00:06:38,080 --> 00:06:46,480
+اللي احنا بنستعملها بالعربي واضح ف Z بمعنى سس من
+
+74
+00:06:46,480 --> 00:06:51,940
+ناحية المعنى او مع الان اتيه ايش معنى ضد برضه راح
+
+75
+00:06:51,940 --> 00:06:59,280
+على اللغة تبعتهانت جاجل انت جاجل اخد منها حرف ايش؟
+
+76
+00:07:00,080 --> 00:07:06,360
+انت جي جن اخد منها حرف ال E فال E هذه صارت بمعنى
+
+77
+00:07:06,360 --> 00:07:12,040
+Trans او بمعنى ضد للناس اللي بيكتبوا باللغة
+
+78
+00:07:12,040 --> 00:07:17,620
+العربية واضح طبعا البعض هيقول طب احنا وقتاش نكتب
+
+79
+00:07:17,620 --> 00:07:23,580
+Sis و Trans و وقتاش نكتب Z و E بنقول في المراكبات
+
+80
+00:07:23,580 --> 00:07:30,440
+البسيطة الواضحة بنكتب Sis و Transفي المُركّبات
+
+81
+00:07:30,440 --> 00:07:34,680
+اللي فيها أكتر من مجموعة و بنتغلب و نحسب ال atomic
+
+82
+00:07:34,680 --> 00:07:41,520
+number بنكتب Z to E بالمناسبة هل هذه القواعد اللي
+
+83
+00:07:41,520 --> 00:07:47,160
+هي ترتيب المجموعات حسب ال atomic number جديدة؟ لأ
+
+84
+00:07:47,160 --> 00:07:51,020
+يعني لو أنا أخدت نفس المُركّب البسيط اللي كنت
+
+85
+00:07:51,020 --> 00:07:59,810
+أحكيه CL CL H H هذا المُركّب عارفينه ولا لأ؟واضح؟
+
+86
+00:07:59,810 --> 00:08:04,230
+الان لو اتيت سؤالك CL او H؟ مين اعلى في ال atomic
+
+87
+00:08:04,230 --> 00:08:10,650
+number؟ CLCl وH هاي مختلفتان و هاي مختلفتان مين
+
+88
+00:08:10,650 --> 00:08:13,550
+أعلى في ال atomic number اللي أعلى في ال atomic
+
+89
+00:08:13,550 --> 00:08:19,270
+number على جهة واحدة إذا هذا المركب Z بس لأنه بسيط
+
+90
+00:08:19,270 --> 00:08:24,530
+و مبين بالنظر استعمالنا له مصطلح إيش SIS واضح و
+
+91
+00:08:24,530 --> 00:08:30,310
+لذلك مش غلط كبير إنه مرات بتلاقوا بعض الناس بدل
+
+92
+00:08:30,310 --> 00:08:35,840
+كلمة SIS بيكتبوا Z أو بدل Z بيكتبوا SIS يعنيلكن
+
+93
+00:08:35,840 --> 00:08:39,540
+لما انتوا بدكم شبه قاعدة عامة بنقول إذا المركبات
+
+94
+00:08:39,540 --> 00:08:42,980
+بسيطة في الغالب هتلاقي الكتب كاتبة معها مصطلحات
+
+95
+00:08:42,980 --> 00:08:48,080
+SIS وTRANS إذا شوية أصعب هتلاقي الكتب كاتبة معها
+
+96
+00:08:48,080 --> 00:08:53,360
+مصطلحات Z وE واضح فقط لغاية
+
+97
+00:08:57,330 --> 00:09:03,570
+الان هذه القواعد عادة بيسموها Can Engel de Brelog
+
+98
+00:09:03,570 --> 00:09:08,050
+Rules اللي هي قواعد ترتيب المجموعات حسب الأعلى في
+
+99
+00:09:08,050 --> 00:09:11,610
+ال atomic number هتعود تلزمنا في ال stereo
+
+100
+00:09:11,610 --> 00:09:16,430
+chemistry و بنكتب اسم الآن مش مستعجلين عليه خلينا
+
+101
+00:09:16,430 --> 00:09:22,090
+ناخدها ببساطة قواعد ترتيب المجموعات حسب الاشالـ
+
+102
+00:09:22,090 --> 00:09:27,030
+atomic number أحيانا بيجي نحل مشكلتنا نشوف مين
+
+103
+00:09:27,030 --> 00:09:31,190
+أعلى في ال atomic number هنا سهل جدا يود ولا CL
+
+104
+00:09:31,190 --> 00:09:37,910
+يود ابتثانية أحيانا بيلاقي الذرتين زي بعض وجدتها
+
+105
+00:09:37,910 --> 00:09:44,390
+بيروح للذرة اللي بعدهمبالهم زي بعض بنروح للبعدها
+
+106
+00:09:44,390 --> 00:09:49,610
+لحد ما نصل لأول اختلاف بيخلي مجموعة أعلى من
+
+107
+00:09:49,610 --> 00:09:54,090
+التانية واضح يعني مثلا هذا المركب لو كنتوا بتطلع
+
+108
+00:09:54,090 --> 00:09:59,950
+عليه هاي carbon شو المجموعات اللي عليها CH3 CH2
+
+109
+00:09:59,950 --> 00:10:06,530
+CH3 لو أجينا نسأل مين أعلى هدول مختلفات هنا carbon
+
+110
+00:10:07,430 --> 00:10:14,550
+وهنا carbon زي بعض وقت أروح للذرة التانية لو بدكوا
+
+111
+00:10:14,550 --> 00:10:20,430
+بالتفصيل الممل أكيد هتقولوا أن هنا في عندي H وH و
+
+112
+00:10:20,430 --> 00:10:31,390
+بعدها carbon هذه H وH و بعدها H فلو إجيتوا تقارنوا
+
+113
+00:10:31,390 --> 00:10:38,490
+C وحملة كل هذا زي بعضه C وحملةوين أول اختلاف؟ نمر
+
+114
+00:10:38,490 --> 00:10:43,810
+اتنين carbon، نمر اتنين H، اذا من المجموعة الأعلى
+
+115
+00:10:43,810 --> 00:10:50,010
+صفيات؟ فانا لما بمشي في المجموعاتبالترتيب يعني
+
+116
+00:10:50,010 --> 00:10:53,090
+الذرة الأولى ماحلتش المشكلة عند ما قالتليش مين
+
+117
+00:10:53,090 --> 00:10:57,330
+أعلى في ال atomic number بروح لا إيش للي بعدها أول
+
+118
+00:10:57,330 --> 00:11:01,370
+ذرة بتعمل الفرق هي اللي بتحدد هل هذه المجموعة أعلى
+
+119
+00:11:01,370 --> 00:11:05,050
+و هدى مع الخبرة بيصير سهل عليكم أنه لو بتشوفوا زي
+
+120
+00:11:05,050 --> 00:11:09,090
+إثل و مثل أنه بتاني تقولوا ال إثل بدون ما تقعدوا
+
+121
+00:11:09,090 --> 00:11:14,110
+تعملوا كل هالتحليل لكن القاعدة العامة ذرة ذرة
+
+122
+00:11:14,110 --> 00:11:14,950
+بنكون ماشيين
+
+123
+00:11:17,660 --> 00:11:24,700
+انجلي حالك صعب ان انا اعيد كتاب واضح و لذلك هذه
+
+124
+00:11:24,700 --> 00:11:30,040
+الاثل صارت اعلى من المثل الان هنحطين مركب او
+
+125
+00:11:30,040 --> 00:11:37,260
+مجمعتين شويه كبار لاحظوا carbon و carbonزي بعض هذه
+
+126
+00:11:37,260 --> 00:11:42,740
+carbon و هذه الذرة carbon الان هذه ال carbon متصلة
+
+127
+00:11:42,740 --> 00:11:47,700
+ب CH3 و هذه ال carbon متصلة ب CH3 كل ما هو مشترك
+
+128
+00:11:47,700 --> 00:11:51,480
+لن يحدد الفرق شو اللي بده يحدد الفرق؟ شي مختلف
+
+129
+00:11:51,480 --> 00:11:57,440
+الان بعد هيك هذه متصلة برابطة واحدة مع ال O هذه
+
+130
+00:11:57,440 --> 00:12:02,190
+متصلة بكم رابطة مع ال O؟ برابطة تانيةيعني كأنه هذه
+
+131
+00:12:02,190 --> 00:12:06,910
+متصلة بـ O وهذه متصلة بـ O اتفقنا طب الرابط الرابع
+
+132
+00:12:06,910 --> 00:12:14,480
+هنا H هنا Oابتبوا معي عاملوا هذه كإنها رابطتين مع
+
+133
+00:12:14,480 --> 00:12:18,080
+O و هذه كإنها رابطة يعني لو جيت سألت الأربع روابط
+
+134
+00:12:18,080 --> 00:12:24,980
+اللي على ال carbon واحدة مع CH3 مع CH3 مع O مع O
+
+135
+00:12:24,980 --> 00:12:29,640
+مع ال carbon هذه مع ال carbon هذه إيش ضال؟ الرابعة
+
+136
+00:12:29,640 --> 00:12:36,620
+مع H الرابعة مع O رابطة التانية، أنه أعلى و لذلك
+
+137
+00:12:36,620 --> 00:12:41,900
+كل المجموعة هذه صارت أعلىواضح؟ فأنا بالتدريج بقدر
+
+138
+00:12:41,900 --> 00:12:45,300
+أحل المشاكل الآن هذولا المجمعتين العليا على جهة
+
+139
+00:12:45,300 --> 00:12:52,100
+واحدة إذا هذا المركب إيش؟ Z واضح؟ هاي مركب تالت
+
+140
+00:12:52,100 --> 00:12:58,940
+هاي عندكم يود و كلور هذه الحالة السهلة من أعلى ال
+
+141
+00:12:58,940 --> 00:13:05,040
+يود أعلى من الكلور okay الآن هنا عندك carbon و
+
+142
+00:13:05,040 --> 00:13:07,100
+carbon
+
+143
+00:13:09,230 --> 00:13:13,670
+الذرتين زي بعض طالما زي بعض بتطلع على الذرات اللي
+
+144
+00:13:13,670 --> 00:13:18,610
+بعضهم هذه ال carbon متصلة ب carbon الرابطة الأولى
+
+145
+00:13:18,610 --> 00:13:24,090
+و الرابطة الثانية ب carbon و التالتة ب H يعني لو
+
+146
+00:13:24,090 --> 00:13:29,570
+جيتوا التلت روا بتاعونها carbon carbon H تعالوا
+
+147
+00:13:29,570 --> 00:13:36,410
+على هذه carbon carbon carbon اذا مين أعلى شوفت
+
+148
+00:13:36,410 --> 00:13:40,490
+واحدة افرجتهمفبصير كل هذه المجموعة على و لذلك هذا
+
+149
+00:13:40,490 --> 00:13:46,770
+المُركّب Z الآن بالتدريب بإمكانكم تتعودوا من خلال
+
+150
+00:13:46,770 --> 00:13:51,030
+حل أسئلة امتحانات سابقة او اشهر تلاحظوا و تميزوا
+
+151
+00:13:51,030 --> 00:13:54,570
+المُركّبات اللي فيها Z و E لكن في كل الأحوال إذا
+
+152
+00:13:54,570 --> 00:13:59,630
+إجاكوا تسمية ال keenإذا إجاكوا تسمية ال keen بتكون
+
+153
+00:13:59,630 --> 00:14:03,170
+تتطلعوا على أطراف ال double bond اللي موجودة فيه
+
+154
+00:14:03,170 --> 00:14:06,990
+إذا عليها مجموعات مختلفة ومجموعات مختلفة يجب أن
+
+155
+00:14:06,990 --> 00:14:12,950
+يوجد في التسمية z أو e وإذا كان الأمر بسيط جدا
+
+156
+00:14:12,950 --> 00:14:18,650
+ممكن تكتبوا cis وtrans واضح؟ ممكن تكتبوا cis
+
+157
+00:14:18,650 --> 00:14:23,630
+وtrans هذا بالنسبة لاستعمال البادئة z وe
+
+158
+00:14:26,930 --> 00:14:32,890
+الان بننتقل لموضوع جديد اللي هو تفاعلات ال الكنز
+
+159
+00:14:32,890 --> 00:14:39,090
+ال الكنز اللي هم تفاعل أساسي هتلاحظوا انه بتكرر
+
+160
+00:14:39,090 --> 00:14:44,470
+عندى كثير هذا التفاعل الأساسي اللي لل الكنز بسميه
+
+161
+00:14:44,470 --> 00:14:50,450
+انا addition reaction addition تفاعل إيش الإضافة
+
+162
+00:14:50,860 --> 00:14:55,580
+إيش هو باختصار تفاعل الإضافة؟ باختصار إنه بيكون
+
+163
+00:14:55,580 --> 00:15:00,650
+عندي carbonDouble bond carbon هاي ال double bond
+
+164
+00:15:00,650 --> 00:15:05,250
+يعني بركز تفاعل وين؟ ع ال double bond لما أجي أضيف
+
+165
+00:15:05,250 --> 00:15:10,250
+عليها أي reagent زي خلينا هيك ناخده بشكل عام HX
+
+166
+00:15:10,250 --> 00:15:14,810
+بيصير carbon single bond carbon لاحظوا ال double
+
+167
+00:15:14,810 --> 00:15:21,910
+bond صارت single bond ال bi bond هادي اتحولت لإيش؟
+
+168
+00:15:21,910 --> 00:15:31,810
+انضاف رابطتين بدالها هنا Hو X اتش و X اتش و X اللي
+
+169
+00:15:31,810 --> 00:15:37,310
+انضافوا واضح طبعا هنا في عنده أشياء تانية كانت
+
+170
+00:15:37,310 --> 00:15:42,770
+موجودة بتظل زي ما هيأي ما كانت تكون يعني هذا
+
+171
+00:15:42,770 --> 00:15:46,170
+المركب شكله الكامل carbon عليها رابطات المتصلات
+
+172
+00:15:46,170 --> 00:15:49,830
+بإيش ما كان مش موضوعي وهذه نفس الاشياء أنا تركيزي
+
+173
+00:15:49,830 --> 00:15:55,770
+على carbon double bond carbon بخليها carbon single
+
+174
+00:15:55,770 --> 00:16:02,040
+bond carbon الآن هذه ال by bond اتحولت لإيشلـ two
+
+175
+00:16:02,040 --> 00:16:06,840
+new sigma bonds يعني تفاعل الـ addition لو بدي
+
+176
+00:16:06,840 --> 00:16:14,560
+تعريف له بدي أقول تحويل ال buy bond هذه الى two
+
+177
+00:16:14,560 --> 00:16:24,210
+new sigma bondsواضح تحويل ال buy bond ل two new
+
+178
+00:16:24,210 --> 00:16:28,990
+sigma bonds او ال double bond صارت single bond هذا
+
+179
+00:16:28,990 --> 00:16:33,510
+هو التفاعل الأساسي في ال ال keys تفاعل ال addition
+
+180
+00:16:33,510 --> 00:16:39,050
+ان احول انا ال double bond ل single bond واضح الان
+
+181
+00:16:39,050 --> 00:16:45,210
+لو بدنا نتطلع على مكونات هذا التفاعل هلاحظ ان هذا
+
+182
+00:16:45,210 --> 00:16:52,150
+التفاعل بتكون من شغلتينبتكون من الكين اللى بتم
+
+183
+00:16:52,150 --> 00:16:57,250
+عليه التفاعل والمادة المتفاعلة بسميها reagent واضح
+
+184
+00:16:57,250 --> 00:17:04,610
+فالكين هيكم شايفينه ال الكين بتفاعل مع ال reagent
+
+185
+00:17:04,610 --> 00:17:11,620
+اللى انا بدي اضيفه بيعمل additionمكونات عملية
+
+186
+00:17:11,620 --> 00:17:17,540
+الإضافة الكينورياجين الان لو بدى أطلع على أحوال
+
+187
+00:17:17,540 --> 00:17:21,260
+الألكين اللى موجود عندى هذا الألكين اللى موجود
+
+188
+00:17:21,260 --> 00:17:26,900
+عندى يمكن أن يكون ألكين متماثل ويمكن أن يكون ألكين
+
+189
+00:17:26,900 --> 00:17:34,660
+غير متماثل يعنى الألكين ممكن يكون symmetric متماثل
+
+190
+00:17:34,660 --> 00:17:38,000
+أو متشابه أو unsymmetric
+
+191
+00:17:40,420 --> 00:17:44,840
+خلّينا نعطيكم مثال على كل واحد، إيش يعني symmetry؟
+
+192
+00:17:44,840 --> 00:17:49,200
+لو افترضت الألكين اللي عندى إيثيلين أبسط واحد،
+
+193
+00:17:49,200 --> 00:17:59,040
+يعني C double bond C وهنا H اتنين تلاتة أربعةهذا
+
+194
+00:17:59,040 --> 00:18:02,280
+متماثل ولا لأ؟ يعني لو اتخيلت ان هنا في مرايا
+
+195
+00:18:02,280 --> 00:18:06,460
+carbon CH2 و carbon CH2 هذا symmetric alkene ولا
+
+196
+00:18:06,460 --> 00:18:11,580
+لأ؟ أكيد الآن ممكن ناخد unsymmetric alkene لو
+
+197
+00:18:11,580 --> 00:18:16,980
+افترضت انه عند البروبين C double bond C حطيت هنا H
+
+198
+00:18:16,980 --> 00:18:25,720
+OH و هنا H و هنا CH3 البروبينهل يا ترى هذا الالكين
+
+199
+00:18:25,720 --> 00:18:32,180
+متماثل؟ هذا متماثل
+
+200
+00:18:32,180 --> 00:18:42,280
+CH2 CH2 هذا CH2 CH3 إذا الالكين ممكن يكون
+
+201
+00:18:42,280 --> 00:18:49,080
+symmetric وممكن يكون unsymmetric واضح الفكرة؟ الآن
+
+202
+00:18:49,080 --> 00:18:54,230
+لو جيت لل reagent اللي بدي أضيفهنفس الاشي كمان
+
+203
+00:18:54,230 --> 00:18:58,210
+ممكن يكون symmetric يعني الشغلتين زي بعض او
+
+204
+00:18:58,210 --> 00:19:03,270
+unsymmetric ناخد أنفلة بسيطة مثلا لو ناس بيضيفوا
+
+205
+00:19:03,270 --> 00:19:10,390
+الهيدروجين الهيدروجين عبارة عن ايش H وH هله
+
+206
+00:19:10,390 --> 00:19:14,730
+symmetric ولا لأ symmetric لو ناس بيضيفوا برومين
+
+207
+00:19:14,730 --> 00:19:17,470
+PR PR
+
+208
+00:19:19,970 --> 00:19:23,850
+Symmetric ولا لأ؟ Symmetric طب لو بدي أشوف الـ
+
+209
+00:19:23,850 --> 00:19:33,350
+Unsymmetric لو ناس بيضيفوا ميّه H و OH زي هي كي
+
+210
+00:19:33,350 --> 00:19:40,550
+بنعتبرها قطعة تانية H و OH لو بيضيفوا HBR او HCL
+
+211
+00:19:40,550 --> 00:19:48,840
+هاي HCL او HBR واضح ف ..اللي بنلاحظه لما بنعمل هذه
+
+212
+00:19:48,840 --> 00:19:52,280
+العملية ان ال الكين ممكن يكون symmetric او
+
+213
+00:19:52,280 --> 00:19:55,200
+unsymmetric و ال reagent ممكن يكون symmetric او
+
+214
+00:19:55,200 --> 00:20:01,800
+unsymmetric طيب عملية الإضافة كام ناتج بتطلع؟عملية
+
+215
+00:20:01,800 --> 00:20:08,040
+الإضافة في حالة واحدة بتطلع ناتجين بدنا نكون
+
+216
+00:20:08,040 --> 00:20:12,000
+منتبهين لها تماما، بعد ذلك بتطلع عندي ناتج واحد
+
+217
+00:20:12,000 --> 00:20:18,840
+إذا ضفت Unsymmetric reagent على Unsymmetric alkene
+
+218
+00:20:18,840 --> 00:20:27,500
+بتوقع ناتجين الآن بنرسمهم و بنوضحهممعد ذلك لو ضيفت
+
+219
+00:20:27,500 --> 00:20:29,940
+symmetric على symmetric أو symmetric على
+
+220
+00:20:29,940 --> 00:20:36,700
+unsymmetric ناتج واحد إذا متى يتوقع ناتجين؟ إذا
+
+221
+00:20:36,700 --> 00:20:41,980
+أنا بضيف unsymmetric alkene على unsymmetric
+
+222
+00:20:41,980 --> 00:20:46,720
+reagent هذه الحالة على طول يتوقع فيها كم ناتج؟
+
+223
+00:20:46,720 --> 00:20:55,920
+ناتجين معد ذلك فيطلع عندى ناتج واحدخلّينا نبدأ
+
+224
+00:20:55,920 --> 00:21:02,300
+نشوف أمثلة على الحالات اللي بنضيف فيها أحد الأطراف
+
+225
+00:21:02,300 --> 00:21:06,820
+symmetric، قدش هيطلع عندنا؟ ناتج واحدة، بعدها
+
+226
+00:21:06,820 --> 00:21:12,020
+بننتقل لـ unsymmetric مع unsymmetric و بنشوف
+
+227
+00:21:12,020 --> 00:21:15,740
+ناتجين، نمشي الآن مع ال slides
+
+228
+00:21:26,510 --> 00:21:32,170
+هذه أول تفاعل لو احنا يا تورا بدنا نضيف الهيدروجين
+
+229
+00:21:32,170 --> 00:21:37,110
+الهيدروجين سيمتريك ولا انسيمتريك؟ سيمتريك إذا كام
+
+230
+00:21:37,110 --> 00:21:41,410
+ناتج بتوقع يطلع عنده؟ ناتج واحد أي أن كان الالكيد
+
+231
+00:21:41,410 --> 00:21:44,570
+سواء كان هذا الالكيد سيمتريك أو انسيمتريك طالما
+
+232
+00:21:44,570 --> 00:21:50,450
+الهيدروجين متماثل إذا اللي هيطلع عنده ناتج واحد
+
+233
+00:21:50,450 --> 00:21:54,930
+الآن لو بدنا نكتب هذا الناتج بدنا نضيف هيدروجين
+
+234
+00:21:54,930 --> 00:22:02,870
+وهيدروجينواضح؟ انتهى الجواب هذا الكن ضفنا عليه جزء
+
+235
+00:22:02,870 --> 00:22:07,010
+الهيدروجين حط هيدروجين هان وهيدروجين هان صار الكن
+
+236
+00:22:07,960 --> 00:22:13,200
+الالكيل باضافة الهيدروجين صار عبارة عن الكل
+
+237
+00:22:13,200 --> 00:22:16,460
+الهيدروجين
+
+238
+00:22:16,460 --> 00:22:22,080
+هنا بنضيف معلومة صغيرة انه لما بيضيف بيضيف من جهة
+
+239
+00:22:22,080 --> 00:22:25,980
+واحدة يعني مابتيجيش ذرة هيدروجين من فوق و ذرة
+
+240
+00:22:25,980 --> 00:22:30,190
+هيدروجين من التحت لأ الذرتين الهيدروجين بيجوامن
+
+241
+00:22:30,190 --> 00:22:34,610
+جهة واحدة يعني بهذا الشكل زي ما تتخيلوا انه انا
+
+242
+00:22:34,610 --> 00:22:38,710
+الان ماسك جزء الهيدروجين هذا قاعد بضيفه نفترض هان
+
+243
+00:22:38,710 --> 00:22:44,370
+دابل بوند الذرتين اجوا على الجهة هذه ما بيجيشبجهات
+
+244
+00:22:44,370 --> 00:22:48,990
+متعاكسة الان هذه الإضافة اللى من جهة واحدة انا
+
+245
+00:22:48,990 --> 00:22:53,630
+بسميها sin addition لو كان بضيف من جهتين عكس بعض
+
+246
+00:22:53,630 --> 00:22:57,890
+بسميها ايش Anti addition فالهيدروجين هنا ايش نوع
+
+247
+00:22:57,890 --> 00:23:03,230
+الإضافة اللى بعملها sin addition معنى sin addition
+
+248
+00:23:03,230 --> 00:23:09,360
+انه بضيف من جهة واحدةواضح؟ معنى sin addition انه
+
+249
+00:23:09,360 --> 00:23:15,160
+بيضيف من جهة واحدة ممكن نعطي تفسير سريع ليش
+
+250
+00:23:15,160 --> 00:23:19,360
+الهيدروجين بيضيف من جهة واحدة لو بتطلعوا بالاتباه
+
+251
+00:23:19,360 --> 00:23:25,260
+هذا التفاعل بتم من خلال إضافة غاز الهيدروجين في
+
+252
+00:23:25,260 --> 00:23:30,660
+وجود معدن هذا المعدن غالبا بنستعمل بلاتين قطع من
+
+253
+00:23:30,660 --> 00:23:37,380
+المعدن الصغيرةبلاتين ممكن نستعمل معدن تاني ممكن
+
+254
+00:23:37,380 --> 00:23:42,820
+نستعمل بلاديم ممكن نستعمل nickel وعشانك مرات
+
+255
+00:23:42,820 --> 00:23:48,340
+بتلاحظوا مكتوب عندكم ايش ام ايش يعني ام هنا metal
+
+256
+00:23:48,340 --> 00:23:55,460
+في وجود metal catalyst هذا عامل حفاز catalyst ام
+
+257
+00:23:55,460 --> 00:24:01,940
+يعني metalكتاليست ايش كتاليست؟ أعمل حفاظ أعمل حفاظ
+
+258
+00:24:01,940 --> 00:24:06,100
+الآن هذا ال كتاليست ممكن يكون platinum ممكن يكون
+
+259
+00:24:06,100 --> 00:24:11,140
+palladium ممكن يكون nickel واضح هذا بيخلي التفاعل
+
+260
+00:24:11,140 --> 00:24:16,860
+يمشي بشكل سريع طب إيش بيعمل هذا الكتاليست؟ هذا
+
+261
+00:24:16,860 --> 00:24:21,180
+الكتاليست يلتصق الهيدروجين على سطحه يعني تخيلوا
+
+262
+00:24:21,180 --> 00:24:27,310
+هذا هو الكتاليستهذا سطح معدن هو الـ catalyst الان
+
+263
+00:24:27,310 --> 00:24:32,030
+الهيدروجين كجزء بيجي يلتصق على سطح ال catalyst
+
+264
+00:24:32,030 --> 00:24:37,870
+طالما يلتصق على سطح ال catalyst بهذا الشكل لما
+
+265
+00:24:37,870 --> 00:24:42,370
+بيجي يضيف ع double bond هاي double bond شايفينهم؟
+
+266
+00:24:42,370 --> 00:24:47,170
+هل ممكن هو ملتصق انه يضيف من جهتين؟ لأ بيجي زي هيك
+
+267
+00:24:47,170 --> 00:24:56,280
+زي هيكوترك الميتل كان ممسوك بالميتل جزء الهيدروجين
+
+268
+00:25:00,170 --> 00:25:05,170
+ضاف بهذا الشكل وبناء على ذلك ضاف من جهة واحدة
+
+269
+00:25:05,170 --> 00:25:11,170
+فبنقول احنا ان ال hydrogen gas adsorbs to the
+
+270
+00:25:11,170 --> 00:25:15,510
+metal surface لاحظوا تتذكروا معنا كلمة adsorption
+
+271
+00:25:15,510 --> 00:25:22,070
+adsorption شو معناها التصاق على السطح بديش اسمع
+
+272
+00:25:22,070 --> 00:25:29,510
+كلمة امتصاص كلمة امتصاصabsorption بالعربي شو
+
+273
+00:25:29,510 --> 00:25:33,830
+بنقولها absorption ادمصاص
+
+274
+00:25:33,830 --> 00:25:39,170
+بالدالة لاحظوا عندكم مصطلحين عندكم مصطلحين يعني
+
+275
+00:25:39,170 --> 00:25:44,070
+تخيلوا high metal surface و high metal surface بده
+
+276
+00:25:44,070 --> 00:25:49,290
+احط شيء عليه إذا الشيء هذا التسق هنا التساق على
+
+277
+00:25:49,290 --> 00:25:54,110
+السطح الخارجي هذا بسميه absorption
+
+278
+00:25:58,830 --> 00:26:06,610
+absorption وإذا هذا الشيء دخل جوا المتل تماما زي
+
+279
+00:26:06,610 --> 00:26:09,430
+ما الإنسان أحيانا بياخد برهام بيحطه على الإيد
+
+280
+00:26:09,430 --> 00:26:14,770
+بيدخل جوا الإيد هذه العملية إيش بنسميها absorption
+
+281
+00:26:14,770 --> 00:26:21,630
+absorption هدولة مصطلحين باللغة العربية بنسميه
+
+282
+00:26:21,630 --> 00:26:30,690
+absorptionادمصاص وال absorption امتصاص واضح فال
+
+283
+00:26:30,690 --> 00:26:35,030
+absorption عادة بيكون at the surface على السطح ال
+
+284
+00:26:35,030 --> 00:26:41,780
+absorption جواواضح الفكرة؟ بالمصطلحين الآن الغاز
+
+285
+00:26:41,780 --> 00:26:46,680
+يا ترى بقدر يدخل جوا المعدن إذا إيش بيصيرله؟
+
+286
+00:26:46,680 --> 00:26:53,580
+absorption تماما زي مثلا الفحم ما بيمطص الغازاته
+
+287
+00:26:53,580 --> 00:26:57,300
+عشان هيك يستعمل في الأقنعة اللي بيستعملوها في
+
+288
+00:26:57,300 --> 00:27:01,780
+الحروب وما إلى ذلك بيخلوا الفحم باودر على أساس
+
+289
+00:27:01,780 --> 00:27:06,760
+يصيرله surface كبير الغاز وين بيجي بيلتصق؟على
+
+290
+00:27:06,760 --> 00:27:12,080
+السطح الخارجي لبودرة الفحم ولذلك القناع أو الكمامة
+
+291
+00:27:12,080 --> 00:27:17,700
+تبع الحرب بتكون ملانا ايش؟ فحم لأن الغازات بيصير
+
+292
+00:27:17,700 --> 00:27:22,420
+الالتصاق على سطح الفحم يمكن احنا الفكرة بنستعملها
+
+293
+00:27:22,420 --> 00:27:27,240
+شوية تطبيقيا لما الناس مرات بيسافروا و بدهم يسيبوا
+
+294
+00:27:27,240 --> 00:27:31,220
+التلاجة بتاعتهم لفترة مش شغالة بيجيبوا خمس ست
+
+295
+00:27:31,220 --> 00:27:36,790
+فحمات و بيحطوهم بالفريزر عشان مايصلوشواضح الفكرة؟
+
+296
+00:27:36,790 --> 00:27:41,350
+الآن هذا الفحم بيلتصق عليه الغاز، كذلك الـmetal
+
+297
+00:27:41,350 --> 00:27:46,250
+هنا بيلتصق وين؟ الهيدروجين بيلتصق على الـmetal،
+
+298
+00:27:46,250 --> 00:27:49,730
+الآن هذا الهيدروجين اللي ملتصق على الـmetal لما
+
+299
+00:27:49,730 --> 00:27:54,310
+يلاقي الـdouble bond، هيضيف عليها من جهة واحدة،
+
+300
+00:27:54,310 --> 00:28:00,640
+يعمل عند إيش؟Sin addition يعني هاي مثال تاني هاي
+
+301
+00:28:00,640 --> 00:28:04,440
+double bond الهيدروجين ملتصق على سطح المعدن، هاي
+
+302
+00:28:04,440 --> 00:28:08,640
+المعدن هي ملتصق لما ضاف، ضاف من جهة واحدة ولا من
+
+303
+00:28:08,640 --> 00:28:13,260
+جهتين؟ من جهة واحدة فما نوع الإضافة هنا؟ Sin
+
+304
+00:28:13,260 --> 00:28:19,200
+addition الآن، هل يا ترى الـ Sin addition تؤدي
+
+305
+00:28:19,200 --> 00:28:24,750
+لتكون مركب cis أو trans أو لأ؟ هذا موضوع تانيبتكون
+
+306
+00:28:24,750 --> 00:28:30,090
+تميزه بين شغلتين، بين شيء اسمه كيف تمت الإضافة،
+
+307
+00:28:30,090 --> 00:28:33,910
+بنقول قولا واحدا تمت الإضافة من جهة واحدة، the
+
+308
+00:28:33,910 --> 00:28:38,730
+same addition، الآن الناتج، هل يا تورا الناتج اللي
+
+309
+00:28:38,730 --> 00:28:43,090
+موجود عندي، cis ولا trans؟كلمة Sis و Trans تعتمد
+
+310
+00:28:43,090 --> 00:28:46,730
+على المجموعات اللي موجودة، يعني هنا بعد ما تمت
+
+311
+00:28:46,730 --> 00:28:51,670
+الإضافة، و تمت من اتجاه واحد، باجي بسأل يا ترى،
+
+312
+00:28:51,670 --> 00:28:57,910
+هذا في Sis و Trans؟ بقول أتش و أتش متشابهتان، و
+
+313
+00:28:57,910 --> 00:29:01,090
+أتش مثل مختلفتان، مافيش ظاهرة الـ Sis و الـ Trans
+
+314
+00:29:02,120 --> 00:29:08,160
+لكن الإضافة تمت من جهة واحدة دائما الآن إن الإضافة
+
+315
+00:29:08,160 --> 00:29:11,480
+اللي من جهة واحدة اللي هي الـ Sin addition هل
+
+316
+00:29:11,480 --> 00:29:16,080
+إجباري إنها تطلع Sis و Trans؟ لأ Sis و Trans
+
+317
+00:29:16,080 --> 00:29:21,760
+بتعتمد على المجموعات الموجودة ولذلك نفس هذا المثال
+
+318
+00:29:21,760 --> 00:29:30,330
+لو طلعته هنا هاي Double bond عليها مجموعتين مثلو
+
+319
+00:29:30,330 --> 00:29:35,830
+بدنا نضيف عليها هيدروجين كيف هنضيف الهيدروجين؟ من
+
+320
+00:29:35,830 --> 00:29:40,110
+جهة واحدة هينضفنا الهيدروجين و الهيدروجين من جهة
+
+321
+00:29:40,110 --> 00:29:44,750
+واحدة لتحت يعني صار عندى الحلقة الخماسية فيها
+
+322
+00:29:44,750 --> 00:29:49,880
+مجموعتين الميثلعلى جهة واحدة والهيدروجينز على جهة
+
+323
+00:29:49,880 --> 00:29:54,760
+واحدة الان هذا المركب في سيس وترانز اطلعوا كاربون
+
+324
+00:29:54,760 --> 00:29:59,840
+حاملة مثل و اتش مختلفتان كاربون حاملة مثل و اتش
+
+325
+00:29:59,840 --> 00:30:04,280
+مختلفتان المثل والمثل على جهة واحدة اذا هذا المركب
+
+326
+00:30:04,280 --> 00:30:09,760
+سيس لاحظوا هنا صار عندي sin addition ادى لتكون
+
+327
+00:30:09,760 --> 00:30:15,460
+المركب الـSYS في المثال السابق صار عندي sin
+
+328
+00:30:15,460 --> 00:30:22,670
+additionما اداش لأشي ف ال sim addition دائما موجود
+
+329
+00:30:22,670 --> 00:30:26,590
+يؤدي ل sis او trans او مايكونش موجود هذا بيعتمد
+
+330
+00:30:26,590 --> 00:30:32,790
+على طبيعة المجموعات اللي موجودة وين على الalkene
+
+331
+00:30:32,790 --> 00:30:39,270
+هذا بالنسبة للجزء الأول اللي هو إضافة الهيدروجين
+
+332
+00:30:39,270 --> 00:30:45,400
+لاحظوا يمكن بيظل عندى كلمةموجودة في العنوان و لازم
+
+333
+00:30:45,400 --> 00:30:52,060
+نجف عندها سمى العملية reduction of alkenes هو ال
+
+334
+00:30:52,060 --> 00:31:05,760
+alkene هنا، شو صار؟ ال alkene صار ال ال ال ال ال
+
+335
+00:31:05,760 --> 00:31:05,840
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+336
+00:31:05,840 --> 00:31:05,840
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+337
+00:31:05,840 --> 00:31:05,920
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+338
+00:31:05,920 --> 00:31:06,060
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+339
+00:31:06,060 --> 00:31:06,060
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+340
+00:31:06,060 --> 00:31:06,060
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+341
+00:31:06,060 --> 00:31:06,060
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+342
+00:31:06,060 --> 00:31:06,060
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+343
+00:31:06,060 --> 00:31:06,060
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+344
+00:31:06,060 --> 00:31:06,060
+ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال ال
+
+345
+00:31:06,060 --> 00:31:10,590
+ال الالان احنا في ال organ ال chemistry في عندنا
+
+346
+00:31:10,590 --> 00:31:15,270
+قاعدة لما المركبات بتتحول من عائلة لعائلة لعائلة
+
+347
+00:31:15,270 --> 00:31:19,450
+لعائلة إذا تحولت باتجاه معين بقول هذه العملية
+
+348
+00:31:19,450 --> 00:31:24,430
+oxidation وإذا تحولت باتجاه آخر بقول هذه العملية
+
+349
+00:31:24,430 --> 00:31:31,090
+reduction فانا لو بدأ أعطيكم مختصر لهذا الأمر بقول
+
+350
+00:31:31,090 --> 00:31:40,850
+أبسط الأشياء ال alkanesتمام بعدها ال الكيلز بعد
+
+351
+00:31:40,850 --> 00:31:46,030
+هيك ربما عند ال alcohols ال RCH2OH
+
+352
+00:31:46,030 --> 00:31:52,350
+بعد هيك في عندك ال ketones و ال aldehydes اللي
+
+353
+00:31:52,350 --> 00:31:59,130
+فيهم C double bond O بعدهم الأحمار C double bond O
+
+354
+00:31:59,130 --> 00:32:06,780
+OH و أعلى مرتبة في الأكسدةتاني اكسيد الكربون اللى
+
+355
+00:32:06,780 --> 00:32:11,420
+متصل باربع روابط اكسجين الان اذا اتحولنا من الكن
+
+356
+00:32:11,420 --> 00:32:16,880
+لالكين فالعملية اكسدة من الكن لالكاي بعد شوية كمان
+
+357
+00:32:16,880 --> 00:32:22,320
+اكسدة لالكهول اكسدة لالديهايد اكسدة لاحظوا انا
+
+358
+00:32:22,320 --> 00:32:26,620
+عندى رابطة احدية مع الاكسجين هنا رابطتين في
+
+359
+00:32:26,620 --> 00:32:31,110
+الكيتون هناتلاتة للي بدهم يفهموا الأكسدا حتى من
+
+360
+00:32:31,110 --> 00:32:37,410
+ناحية ال Oxygen هنا أربعة الآن إذا مشينا بالعكس
+
+361
+00:32:37,410 --> 00:32:42,370
+بنقول العملية reduction عشان هيك لما ندرس الكيميا
+
+362
+00:32:42,370 --> 00:32:46,190
+بعد شوية نحول الكحول لالديهايد أو كيتون شو هنسمي
+
+363
+00:32:46,190 --> 00:32:50,870
+العملية؟ أكسدا يعني لما ندرس شapter ال alcohol و
+
+364
+00:32:50,870 --> 00:32:55,170
+بنقول alcohol اتحول لالديهايد أو كيتون هنسمي
+
+365
+00:32:55,170 --> 00:33:02,560
+العملية أكسدا كيتونرجع لالكهن Reduction الكن صار
+
+366
+00:33:02,560 --> 00:33:09,140
+الكن Oxidation الكن رجع ل الكن Reduction واضح؟
+
+367
+00:33:09,140 --> 00:33:17,560
+فضمن هالسلسلة بنقدر نفهم .. ضمن هالسلسلة بنقدر
+
+368
+00:33:17,560 --> 00:33:22,860
+نفهم اللي احنا بنعنيه بالأكسدة والاختزال هذه كلها
+
+369
+00:33:22,860 --> 00:33:28,020
+أمثلة بتوضح كيف ضفنا ال hydrogenالان التفاعل
+
+370
+00:33:28,020 --> 00:33:33,440
+التاني إضافة لبروم مرة تانية لبروم Symmetric ولا
+
+371
+00:33:33,440 --> 00:33:39,180
+Unsymmetric؟ Symmetric Reagent لكن بالتجربة ..
+
+372
+00:33:39,180 --> 00:33:43,400
+بالدليل التجريبي مش كل شيء بالفصل فيه اللي لاحظوا
+
+373
+00:33:43,400 --> 00:33:48,660
+أن لبروم لما بيضيف .. بيضيف Anti addition من جهتين
+
+374
+00:33:48,660 --> 00:33:54,320
+متعاكستينيعني ما بيضيفش من نفس الجهة، لاحظوا هاي
+
+375
+00:33:54,320 --> 00:33:59,680
+الكين ضفنا عليه برومين أعطانا sin ولا anti
+
+376
+00:33:59,680 --> 00:34:04,700
+addition؟ Anti addition إذا الهيدروجين كأول
+
+377
+00:34:04,700 --> 00:34:09,360
+symmetric reagent ضاف من جهة واحدة لبرومين، يعني
+
+378
+00:34:09,360 --> 00:34:12,460
+لو تخيلت أن هذا جزء لبرومين و جاي يضيف على double
+
+379
+00:34:12,460 --> 00:34:19,650
+bond هنابيضيف من جهتين مختلفتين الآن مرة تانية
+
+380
+00:34:19,650 --> 00:34:25,570
+لبرومين دائما Anti-addition يعطي cis أو trans لأ
+
+381
+00:34:25,570 --> 00:34:32,610
+حسب الجزاء اللي موجود عنده حسب المجموعات اللي
+
+382
+00:34:32,610 --> 00:34:36,310
+موجودة على الجزاء عنده ممكن يعطي cis ممكن يعطي
+
+383
+00:34:36,310 --> 00:34:41,190
+trans ممكن مايعطيش إشي واضح؟ يعني في حالة زي هذه
+
+384
+00:34:41,190 --> 00:34:46,260
+لما بيضيف لو افترضنا ان هدولة كلهم Hydrogensلأ
+
+385
+00:34:46,260 --> 00:34:54,520
+طبعا لأ اكيد اكيد لأ لو افترضنا ان البروميل بيضيف
+
+386
+00:34:54,520 --> 00:35:00,060
+على الهيدروجين كل هدول الذرات الأربعة ما زالوا
+
+387
+00:35:00,060 --> 00:35:06,320
+هيدروجين الان لاحظوا زملتكم على طول غلطة، غلطة
+
+388
+00:35:06,320 --> 00:35:14,060
+كبيرة جد البحر ليش؟لأنه قلنا ظاهرة الـcis والترانس
+
+389
+00:35:14,060 --> 00:35:18,780
+أساسا كظاهرة يا بتنوجد حوالين ال double bond يا
+
+390
+00:35:18,780 --> 00:35:24,500
+حوالين ال single bond في الحلقة في منها؟ لأ وحكينا
+
+391
+00:35:24,500 --> 00:35:29,280
+أن هذا طالما single bond في حالة دوران دائم أبدت
+
+392
+00:35:29,280 --> 00:35:36,560
+هو في لحظة الإضافة بدى زي هيك لكن بعد ثانية بلوف
+
+393
+00:35:38,450 --> 00:35:40,690
+مافيش فيه كل ظاهرة الـcis و الـtrans الرابطة
+
+394
+00:35:40,690 --> 00:35:44,970
+الوحيدية فيها ظاهرة الـcis و الـtrans لا مافيش
+
+395
+00:35:44,970 --> 00:35:49,070
+فيها ظاهرة الـcis و الـtrans لكن الإضافة في لحظة
+
+396
+00:35:49,070 --> 00:35:54,270
+الإضافة كيف ضافوا إن فكوا الظارتين عن بعض إجت
+
+397
+00:35:54,270 --> 00:35:56,710
+واحدة من الأمام واحدة من الخلف هي معنى Anti
+
+398
+00:35:56,710 --> 00:36:02,190
+-addition إذا لو واحدة بتفكر في أي وقت بده يظهر
+
+399
+00:36:02,190 --> 00:36:07,720
+عند الـcis و الـtrans في الحلقاتفي الحلقات لأن
+
+400
+00:36:07,720 --> 00:36:14,000
+الحلقات هم الوحيدين اللي فيهم رابطة أحدية و فيهم
+
+401
+00:36:14,000 --> 00:36:18,360
+دائرة ال cis و ال trans انما في المناطق اللي زي
+
+402
+00:36:18,360 --> 00:36:23,460
+هذه مابطلعش عنده cis و trans بطلع غالبا في الحلقات
+
+403
+00:36:25,730 --> 00:36:30,370
+بدون ما نفصل ليش تم هذا الكلام تم بالتأكيد على
+
+404
+00:36:30,370 --> 00:36:33,970
+خطوطين يعني ضافة ذرة بروم وبعدين كملت البروم الجهة
+
+405
+00:36:33,970 --> 00:36:39,570
+التانية مش كثير مهتم بهذا ال ميكانيزم لكن خليني
+
+406
+00:36:39,570 --> 00:36:43,090
+أرجع مثلا على هذا المثال اللي ضيفنا فيه الهيدروجين
+
+407
+00:36:43,090 --> 00:36:49,050
+لو كنا جايبينه في الامتحان وقلنالكم أكمل وهينضيفنا
+
+408
+00:36:49,050 --> 00:36:53,390
+الهيدروجين بهذا الاتجاه وبالاتجاه التاني قلنا لكم
+
+409
+00:36:54,740 --> 00:37:00,080
+ضيفنا الـ PR 2 كيف
+
+410
+00:37:00,080 --> 00:37:06,760
+فجأة هكمل؟ هرسم
+
+411
+00:37:06,760 --> 00:37:13,500
+نفس الحلقة هذه بعدين
+
+412
+00:37:13,500 --> 00:37:24,380
+أخلي مجموعة مثل لفوق و مجموعة لتحت و ال PR لفوق
+
+413
+00:37:30,400 --> 00:37:38,660
+هذه لفوق وهذه PR وين بتصير؟ لتحت ال .. واضح؟ ربما
+
+414
+00:37:38,660 --> 00:37:45,240
+لو كانت الحلقة مرسومة بهذا الشكل يكون أسهل لكم نفس
+
+415
+00:37:45,240 --> 00:37:49,240
+الحلقة كأنه بتكون .. تتخيلوا بهذا الشكل كأنه عندكم
+
+416
+00:37:49,240 --> 00:37:59,400
+CH3 و CH3 بيصيروا عكس بعض و PR عكس بعض انتي ولا
+
+417
+00:37:59,400 --> 00:38:07,680
+لأ؟الان هدولة SES ولا TRANS هذا المُركّب TRANS هاي
+
+418
+00:38:07,680 --> 00:38:15,740
+ال PR و PR عكس بعض و مثل و مثل لأ هو انا .. بدل ..
+
+419
+00:38:15,740 --> 00:38:19,740
+لو النتج كان H2و بتكون تخلوا مجمعتين ال مثل ع جهة
+
+420
+00:38:19,740 --> 00:38:23,340
+واحدة مجمعتين ال H ع جهة واحدة بتكون تعملوا SEND
+
+421
+00:38:23,340 --> 00:38:26,500
+ADDITION واضح؟
+
+422
+00:38:33,560 --> 00:38:40,620
+لأ لأ لأ ال CH3 ال CH3 لو كان عندنا model هذا
+
+423
+00:38:40,620 --> 00:38:45,620
+المركب بيكونوا في نفس مستوى الحلقة مش عكس بعض
+
+424
+00:38:45,620 --> 00:38:51,580
+تنسوش أحيانا في معلومات مبنية على بعض لما أخدنا
+
+425
+00:38:51,580 --> 00:38:58,300
+الشكل الهندسي حوالين ال double bondقلنا ان حوالين
+
+426
+00:38:58,300 --> 00:39:03,900
+ال double bond الشكل بلانر بزاوية 120 يعني هذه
+
+427
+00:39:03,900 --> 00:39:11,240
+الزاوية 120 وهذه 120 وهذه 120 هدولة في مستوى واحد
+
+428
+00:39:11,240 --> 00:39:15,820
+لو انا بدي افرجيكم بشكل عام كيف منظرهم باخد ملزمة
+
+429
+00:39:15,820 --> 00:39:21,850
+من هنازي هيك بتكون تتخيلوا الحلقة لما بيكون عند
+
+430
+00:39:21,850 --> 00:39:26,490
+هنا double bond لو تخيلتوا هاي مجمعتين ال CH3 هدول
+
+431
+00:39:26,490 --> 00:39:31,170
+ناخدهم
+
+432
+00:39:31,170 --> 00:39:36,010
+باللون الأسمر بيكونوا في نفس مستوى الحلقة ليش لأن
+
+433
+00:39:36,010 --> 00:39:40,190
+هنا في عند double bond لما هنا بيكون عند double
+
+434
+00:39:40,190 --> 00:39:46,590
+bond هدولة في نفس المستوى تبع الحلقةواضح؟ هدولة في
+
+435
+00:39:46,590 --> 00:39:51,510
+نفس المستوى تبع الحلقة لما بيجي البروم اضيف بيخلي
+
+436
+00:39:51,510 --> 00:39:55,570
+واحدة لتحت واحدة لفوق و البروم بنعكس لو اجي
+
+437
+00:39:55,570 --> 00:40:01,090
+الهيدروجين اضيف بيخلي تنتين لتحت و الهيدروجين بيجي
+
+438
+00:40:01,090 --> 00:40:07,770
+لفوق طبعا ما عدا ما عدا ال double bond بيكون انا
+
+439
+00:40:07,770 --> 00:40:13,050
+في عندى كام ذرة هيدروجين في الجزء؟ تنتينهنا في
+
+440
+00:40:13,050 --> 00:40:15,550
+واحدة لفوق واحدة لتحت هنا واحدة لفوق واحدة لتحت
+
+441
+00:40:15,550 --> 00:40:20,090
+هنا واحدة لفوق واحدة لتحت لكن هذه وهذه في مستوى
+
+442
+00:40:20,090 --> 00:40:25,070
+الجزء هذه وهذه في مستوى الجزء شوية بنحس ان الموضوع
+
+443
+00:40:25,070 --> 00:40:38,210
+صعب مافيش مشكلة بالمرة ناخد دقيقة و نعمل لكم model
+
+444
+00:40:38,210 --> 00:40:39,970
+هتفهموا
+
+445
+00:40:42,640 --> 00:40:47,920
+هتفهموا الموضوع بشكل جيد عشان هي احنا بنقول ال
+
+446
+00:40:47,920 --> 00:40:56,080
+models مرات كتير بتساعد لاحظوا
+
+447
+00:40:56,080 --> 00:41:00,580
+هاي عندى حلقة خماسية طبعا هي قولنا مش planner شوية
+
+448
+00:41:00,580 --> 00:41:06,040
+فيها زى ال envelope مش مشكلة كبيرة هذه الان لما
+
+449
+00:41:06,040 --> 00:41:13,610
+بدي اجي اعمل لما بدي اجي اعمل double bondعلى جهة
+
+450
+00:41:13,610 --> 00:41:17,850
+من الجهات هانا بدى اعمل double bond واحدة فيها
+
+451
+00:41:17,850 --> 00:41:28,510
+هينعمل ال double bond تمام شو تبقى عندى مجموعة CH3
+
+452
+00:41:28,510 --> 00:41:35,470
+ومجموعة تانية CH3 هين بيانتهم باللون الأصمر الان
+
+453
+00:41:35,470 --> 00:41:40,310
+لاحظوا هدول المجمعتين في مستوى الحلقة ولا لأ في
+
+454
+00:41:40,310 --> 00:41:46,380
+مستوى الحلقةالان باقي الكربونات ايش عليهم؟ كل
+
+455
+00:41:46,380 --> 00:41:50,260
+واحدة تنتين CH2 العلم الجديد اللي اتعلمناه واحدة
+
+456
+00:41:50,260 --> 00:41:58,100
+لفوق واحدة لتحت هنا عند تنتين CH2 لفوق و لتحت هنا
+
+457
+00:41:58,100 --> 00:42:02,440
+في عند تنتين
+
+458
+00:42:02,440 --> 00:42:03,260
+هيدروجين
+
+459
+00:42:05,710 --> 00:42:09,730
+لا فوق ولا تحت هذا هو الجزء اللي موجود عندكم الان
+
+460
+00:42:09,730 --> 00:42:14,090
+لاحظوا ان هدولة في مستوى واحد carbon carbon carbon
+
+461
+00:42:14,090 --> 00:42:19,550
+carbon carbon carbon واضح فبناء على ذلك هدولة في
+
+462
+00:42:19,550 --> 00:42:23,970
+البداية كان السؤال هم أساسا مثل ال sex ولا ال
+
+463
+00:42:23,970 --> 00:42:29,470
+transلأ في الحلقة بيكونوا على نفس المستوى مافيش
+
+464
+00:42:29,470 --> 00:42:32,930
+فيه sis و trans ال sis و ال trans انه في فوق و تحت
+
+465
+00:42:32,930 --> 00:42:35,810
+حوالين ال single bond في الحلقة مش حوالين ال
+
+466
+00:42:35,810 --> 00:42:41,110
+double bond في الحلقة انما هدولة جايين على جهة
+
+467
+00:42:41,110 --> 00:42:46,030
+واحدة اللي محتمال يكونوا فوق او تحت الحلقة لأ لما
+
+468
+00:42:46,030 --> 00:42:51,890
+انا بعمل الاضافة خليني افترض ان انا بدي اضيف لبروم
+
+469
+00:42:51,890 --> 00:42:59,330
+و خليني اعطي لبروممجمعتين زرق او للهيدروجين
+
+470
+00:42:59,330 --> 00:43:05,670
+ونوضحهم بروابط كبيرة قلنا
+
+471
+00:43:05,670 --> 00:43:12,550
+عملية الإضافة هي عملية ايش؟ كسر رابطة زوجية الان
+
+472
+00:43:12,550 --> 00:43:20,410
+هي نكسرتها ونحط بدالها two new sigma bonds الان لو
+
+473
+00:43:20,410 --> 00:43:24,270
+كنت بضيف الهيدروجين هدول هيصيروا على جهة واحدة
+
+474
+00:43:25,230 --> 00:43:30,450
+والمثل على جهة واحدة هذه هي الـ Sin Addition اللي
+
+475
+00:43:30,450 --> 00:43:38,690
+قدّت لـ SIS مرة تانية لو رجعت و كنت بدأ أضيف لبروم
+
+476
+00:43:38,690 --> 00:43:42,550
+وقتها
+
+477
+00:43:42,550 --> 00:43:49,510
+لما بدأ أكسر الرابطة بدّو هدولة يتحركوا بهذا الشكل
+
+478
+00:43:56,030 --> 00:44:00,630
+واضح الفكرة؟ انا كسرت الروابط لأنهم مربطين، بس هم
+
+479
+00:44:00,630 --> 00:44:06,710
+في النهاية فراغات يعني، بالتالي سهل يتحركوا، واضح؟
+
+480
+00:44:06,710 --> 00:44:10,850
+يعني انا عشان اعملكوا الشكل اضطريتوا ان تشوفوني
+
+481
+00:44:10,850 --> 00:44:14,870
+بكسر الرابطة، لكن في كل الأحوال، بدكم تكونوا
+
+482
+00:44:14,870 --> 00:44:19,390
+فاهمين من الأساس انتوا، لاحظوا الكيميا ما هي كل
+
+483
+00:44:19,390 --> 00:44:24,630
+كلمة مبنية على الثانيةلحظة ما كنا بنحكي عن تعريف
+
+484
+00:44:24,630 --> 00:44:31,110
+الرابطة إيش قولنا هي الرابطة؟ هي مسافة في الفراغ
+
+485
+00:44:31,110 --> 00:44:37,990
+يعني هذه وهذه بالظبط
+
+486
+00:44:37,990 --> 00:44:48,790
+برات
+
+487
+00:44:48,790 --> 00:44:55,120
+..يعني هذه المفاهيم تعبير عن خبرة في الكيميا الآن
+
+488
+00:44:55,120 --> 00:45:01,480
+هذه و هذه مسافات في الفراغ واضح ليست روابط جامدة
+
+489
+00:45:01,480 --> 00:45:07,380
+وبالتالي انا لما اجيب برم من جهتين وهذه مسافة
+
+490
+00:45:07,380 --> 00:45:11,280
+بالفراغ وهذه مسافة بالفراغ هتيجي برم من فوق هذه
+
+491
+00:45:11,280 --> 00:45:16,750
+تنزل لتحت هتيجي برم من تحت هذه تطلع لفوقواضح؟ لما
+
+492
+00:45:16,750 --> 00:45:20,750
+اجيب الهيدروجين حيجي الهيدروجين و الهيدروجين بهذا
+
+493
+00:45:20,750 --> 00:45:25,430
+الشكل ممسكين على سطح الميتال هذه و هذه هينزلوا
+
+494
+00:45:25,430 --> 00:45:31,050
+لتحت الان لما انا بشتغل بروابط صلبة في الهيدروجين
+
+495
+00:45:31,050 --> 00:45:37,790
+كان سهل ان اوضحلكوا هذا بالموديل صح؟في البروم لما
+
+496
+00:45:37,790 --> 00:45:41,810
+كسرت الرابطة اضطريت ان ابين كاني بكس الرابطة لكن
+
+497
+00:45:41,810 --> 00:45:47,050
+هي حقيقة لما تكونوا متخيلين مسافة بالفراغ ما كسرت
+
+498
+00:45:47,050 --> 00:45:52,710
+رابطة فقط هذه اتحركت لأعلى اجت البروم من جهة وهنا
+
+499
+00:45:52,710 --> 00:45:57,850
+اجت البروم من جهة تانية حوالين ال single bond ممكن
+
+500
+00:45:57,850 --> 00:46:01,590
+sis و trans طالما مختلفتان مختلفتان هذا المركب
+
+501
+00:46:01,590 --> 00:46:06,950
+اللي طلع عندي ايشtrans واضح؟ احنا في كل الأحوال
+
+502
+00:46:06,950 --> 00:46:13,170
+اللي بنركز عليه أنه إضافة الـhydrogen سن إضافة
+
+503
+00:46:13,170 --> 00:46:17,910
+البروم أنت الآن النتيجة سلسة الـtrans تعتمد على
+
+504
+00:46:17,910 --> 00:46:23,570
+طبيعة الجزء هل الجزء جزء حلقي جزء غير حلقي هل
+
+505
+00:46:23,570 --> 00:46:29,630
+المجموعات اللي فيه إيش نوعهاواضح؟ يعني خلّيني
+
+506
+00:46:29,630 --> 00:46:34,290
+بثانية أستأذنكم وأستاذن الأستاذ كمان لأننا خلّصنا
+
+507
+00:46:34,290 --> 00:46:41,010
+لو كنا بنضيف هيدروجين على هذا الجزء اللي في الأساس
+
+508
+00:46:41,010 --> 00:46:47,970
+كان عليه تنتين هيدروجين يعني هذا الجزء كان بهذا
+
+509
+00:46:47,970 --> 00:46:54,730
+الشكل وكنا جاعدين بنضيف عليههذه الـ double bundle
+
+510
+00:46:54,730 --> 00:47:01,030
+في الحلقة وكنا قاعدين بنضيف عليها هيدروجينز هيصير
+
+511
+00:47:01,030 --> 00:47:07,470
+H لتحت وهذه لتحت وH جديدة لفوق وH جديدة لفوق طلعت
+
+512
+00:47:07,470 --> 00:47:11,730
+كل ظاهرة الـ cis والترانس؟ لأ تعتمد على ال
+
+513
+00:47:11,730 --> 00:47:15,350
+substituents يعني لما كانوا المجموعتين مثل طلع
+
+514
+00:47:15,350 --> 00:47:20,140
+المركب cis لكن لو افترضنا المجموعتين Hمافيش كل
+
+515
+00:47:20,140 --> 00:47:23,380
+الظاهرة بس في كل الأحوال انا لما ضيفت ال hydrogen
+
+516
+00:47:23,380 --> 00:47:28,740
+من جهة واحدة لما ضيفت ال brom عرفنا ايش معنى سنه
+
+517
+00:47:28,740 --> 00:47:32,920
+addition و لذلك عملية الإضافة بسميها mood of
+
+518
+00:47:32,920 --> 00:47:37,300
+addition ال product depends on the nature of the
+
+519
+00:47:37,300 --> 00:47:41,240
+molecule على طبيعة الجزيء على المجموعات اللي
+
+520
+00:47:41,240 --> 00:47:45,760
+موجودة أساسا على أطراف الكربون هل الجزيء حلقة مش
+
+521
+00:47:45,760 --> 00:47:49,780
+حلقة ما إلى ذلكو منكتفي بهذا القدر
+